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HomeMy WebLinkAbout1107_Buncombe_MSWLF_CDLF_April2021GW_FID1596441_20210812REPORT OF WATER QUALITY SAMPLING AND ANALYSIS 1st SEMI—ANNUAL EVENT 2021 BUNCOMBE COUNTY LANDFILL ALEXANDER, NORTH CAROLINA Permit No. 1107-MSWLF-1996 Permit No. 1107-CDLF-1998 Prepared For: Buncombe County BLE Project Number J21-9378-23 August 4, 2021 N CAR $� Q OLaQ�F�t_�Q�I r11lfftlil� IM BUNNELL M LAMMEINS ENGINEERING 6004 Ponders Court I Greenville, SC 29615 864-288.1265 A 864,286.4330 0 info@hle[orp.com BLECQRMOM DEN R USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR I IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Bunnell-Lammons Engineering, Inc. (consultant) Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Andrew W. Alexander, PG RSM E-mail: andy.alexander@blecorp.com Phone: (864)288-1265 NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) 1107-MSWLF 1 Panther Branch Road -1996 .1600 Buncombe County Landfill Alexander, NC, 28701 April 23-28, 2021 1107-CDLF .0500 -1998 0 Environmental Status: (Check all that apply) Initial/Background Monitoring 0 Detection Monitoring Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells El Leachate monitoring data El water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. El Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Andrew W. Alexander, PG RSM Consulting Hydrogeologist (864) 288-1265 Facility Representative Name (Print) Title (Area Code) Telephone Number �� w a• �E,o•,....=.. ®e,•o.owm, 08-04-2021 Signature Date 6004 Ponders Court, Greenville, SC, 29615 Facility Representative Address C-284 & C-1538 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 Affix NC Licensed/ Professional Geologist Seal QZN CARNS Ot • ,so9�a�oLo6\,P�o�,`: WAS W A 'liftoff trt11�tl � CANNONS ENGINEERING August 4, 2021 Buncombe County Solid Waste Department 81 Panther Branch Road Alexander, North Carolina 28701 Attention: Ms. Kristy Smith Subject: Report of Water Quality Sampling and Analysis 1" Semi -Annual Event 2021 Buncombe County Landfill Alexander, North Carolina Permit Nos. 1107-MSWLF-1996 & 1107-CDLF-1 BLE Project Number J21-9378-23 Dear Ms. Smith: Pursuant to authorization of Bunnell-Lammons Engineering, Inc. (BLE) Proposal Number J21-9378-23, dated January 15, 2021, BLE has prepared this report of the groundwater, surface water, and leachate monitoring for the 1st semi-annual sampling event of 2021 at the Buncombe County Landfill. Consistent with the North Carolina Division of Waste Management (DWM) — Solid Waste Section (SWS) approved monitoring program, sampling and analysis will be conducted twice in 2021. This report contains the information required to document the sampling and analysis activities for the first event of 2021 in the SWS permanent project record. Sincerely, BUNNELL LAMMONS ENGINEERING INC. Blais, G.I. . Staff Hydrogeologist cc: Ms. Jaclynne Drummond — DWM-ARO �./ W / A �� Andrew W. Ale der, P.G., RSM Consulting Hydrogeologist Registered, NC #1475 Ilblegvlfsl Isolidwasteprojectsl buncombe county active lf, nc19378-23 spring 2021 semi repor605 repor6draft active bclf 1107-mswlf-1996 lst 2021 semi-annual 9378-23. docx 6004 Ponders Court, Greenville, SC 29615 ILH64.288.1265 1`4864.288.4430 P—Minfo@hleeorp.rom BLECORP.COM 1s 1m 1i Buncombe County Landfill —Alexander, North Carolina August 4, 2021 Report of Water Quality Sampling and Analysis — Is' Semi -Annual Event 2021 BLE Project No. J21-9378-23 TABLE OF CONTENTS 1.0 PROJECT INFORMATION........................................................................................................1 2.0 FIELD ACTIVITIES, SAMPLING, AND ANALYSIS.............................................................1 3.0 GROUNDWATER FLOW........................................................................................................... 2 4.0 RESULTS....................................................................................................................................... 2 4.1 Groundwater.................................................................................................................................... 2 4.2 Surface Water.................................................................................................................................. 3 4.3 Leak Detectors and Leachate Samples............................................................................................. 4 5.0 CONCLUSIONS AND RECOMMENDATIONS....................................................................... 5 6.0 QUALIFICATIONS OF REPORT.............................................................................................. 5 7.0 CLOSING.......................................................................................................................................5 Tables Table 1 Well Construction and Monitoring Well Data Table 2 Groundwater VOCs Table 3 Groundwater Field Parameters, Geochemical Parameters, and Total Metals Table 4 Surface Water VOCs Table 5 Surface Water Field Parameters and Total Metals Table 6 Leak Detector and Leachate VOCs Table 7 Leak Detector and Leachate Field Parameters and Total Metals Figures Figure 1 Site Location Map Figure 2 Groundwater Elevation Contour Map — April 23, 2021 Appendices Appendix A Field Sampling Logs — Pace Analytical Services, LLC. Appendix B Laboratory Analytical Data — Pace Analytical Services, LLC. iofi 1s 1m 1i Buncombe County Landfill —Alexander, North Carolina August 4, 2021 Report of Water Quality Sampling and Analysis — I' Semi -Annual Event 2021 BLE Project No. J21-9378-23 1.0 PROJECT INFORMATION The subject 654-acre landfill site is located in Buncombe County, North Carolina, approximately nine miles north of the city of Asheville with a physical address of 81 Panther Branch Road in Alexander, North Carolina (Figure 1). Buncombe County owns and operates a Subtitle D MSWLF which includes Cell 1 through Cell 6 and a CDLF consisting of Phase 1 through Phase 6. Currently Cell 6 of the MSWLF and Phase 6 of the CDLF are the active waste units. MSWLF Cell 7 has been permitted for construction and MSWLF Cells 8 through 10 are planned (but not permitted) for future expansion. A Water Quality Monitoring Plan (WQMP) dated February 19, 2021 was finalized by BLE and submitted to the North Carolina Solid Waste Section (SWS). The WQMP was approved on April 16, 2021 (FID 1576846). The facility requires semi-annual groundwater, surface water, and leachate monitoring and reporting in accordance with the WQMP. Semi-annual sampling is typically conducted each April and October and those events are designated "Spring" and "Fall," respectively. This report represents the 1st semi-annual (Spring) sampling event of 2021. The existing groundwater monitoring network for the Buncombe County Landfill consists of two (2) upgradient (background) wells (MW-1 and MW-113) and twenty-five (25) downgradient (compliance) wells (MW-2, MW-213, MW-3R, MW-4, MW-4D, MW-5, MW-5D, MW-6, MW-7, MW-8, MW-813, MW-10, MW-IOD, MW-11, MW-11D, MW-12, MW-12D, MW-13, MW-13D, MW-14, MW-14D, MW-15, MW- 15D, MW-17R, and MW-17DR). Wells MW-17 and MW-17D were abandoned September 14, 2020 and replaced by MW-17R and MW-17DR respectively (Figure 2). In accordance with Rule .0602 and Rule .0544(c), eight (8) surface water monitoring locations have been established for the facility to monitor surface water quality surrounding the existing waste footprint. The existing surface water locations consist of one (1) upstream (background) point (SW-1) and seven (7) downstream (compliance) points (SW-2 through SW-8). In accordance with Rule .1626(12)(c), eight (8) active leachate sampling locations have been established for the facility. The locations include six (6) existing leak detection sampling locations associated with each MSWLF cell (Cells 1 through 6) designated LD-1 through LD-6, one (1) leachate leak detection sampling location near the leachate pond designated Leachate LD, and the Leachate Pond itself. 2.0 FIELD ACTIVITIES, SAMPLING, AND ANALYSIS Groundwater, surface water, and leachate samples were collected during the 1' semi-annual sampling event by personnel from Pace Analytical Services, LLC. (Pace) of Asheville, North Carolina between April 23-28, 2021. Groundwater samples were collected from all of the active groundwater monitoring well locations located on the site. The eight (8) surface water locations were sampled during the event. Additionally, the seven (7) leak detection and one (1) leachate pond locations were sampled. The groundwater, surface water, and leachate samples were delivered and analyzed in Pace's Columbia, South Carolina laboratory (former Shealy Environmental) for the constituents in the approved WQMP. The field parameters of dissolved oxygen, pH, redox potential, specific conductance, turbidity, and temperature were measured in the field by Pace. A copy of the Pace field sampling logs is included in Appendix A. A copy of the laboratory analytical data is included in Appendix B. 1 of 2 1s 1M 1i Buncombe County Landfill —Alexander, North Carolina August 4, 2021 Report of Water Quality Sampling and Analysis — Is' Semi -Annual Event 2021 BLE Project No. J21-9378-23 3.0 GROUNDWATER FLOW The water level data collected during the groundwater sampling event on April 23, 2021 is presented in Table 1. A groundwater elevation contour map is presented as Figure 2 which includes generalized groundwater flow directions. 4.0 RESULTS 4.1 Groundwater The results of the groundwater field and laboratory analyses are summarized on Tables 2 and 3 and the laboratory analytical data is included in Appendix B. VOC detections during the current sampling event included: • acetone (4 wells); • benzene (1 well); • 1,1-dichloroethane (1 well); • 1,2-dichloroethane (1 well); • cis-1,2-dichloroethene (3 wells); • 2-butanone (4 wells); • vinyl chloride (1 well); • tetrahydrofuran (4 wells); and • 1,4-dioxane (4 wells). Geochemical and field parameter water quality detections during the current sampling event included: • alkalinity (10 wells); • TDS (10 wells); • chloride (10 wells); • iron II (10 wells); and • sulfate (10 wells). Total metals detections during the current sampling event included: • total antimony (2 wells); • total barium (27 wells); • total beryllium (1 well); • total cadmium (1 well); • total chromium (13 wells); • total cobalt (10 wells); • total copper (7 wells); • total lead (3 wells); • total manganese (9 wells); • total nickel (22 wells); • total vanadium (6 wells); and • total zinc (16 wells). 2 of 3 1s 1M 1i Buncombe County Landfill —Alexander, North Carolina August 4, 2021 Report of Water Quality Sampling and Analysis — I sr Semi -Annual Event 2021 BLE Project No. J21-9378-23 Please refer to Tables 2 and 3 for a summary of which groundwater constituents exceeded North Carolina Groundwater Quality Standards (NC2L) maximum contaminant levels' (MCLs). Field parameters measured in the groundwater included pH, specific conductance, turbidity, and temperature. The field parameter of pH was below its NC2L standard in nineteen (19) wells. However, previous semi- annual reports for the subject site indicate that pH frequently varies between values both below and within the NC2L standards in the majority of the wells on site. No other field parameters were outside their NC2L standard limits for groundwater, if established. 4.2 Surface Water The results of the surface water field and laboratory analyses are summarized on Tables 4 and 5 and the laboratory analytical data is included in Appendix B. VOC detections during the current sampling event included: • acetone (2 locations); • 2-butanone (1 location); • tetrahydrofuran (1 location); and • 1,4-dioxane (5 locations). Total metal detections during the current sampling event included: • total antimony (1 location); • total arsenic (2 locations); • total barium (8 locations); • total chromium (7 locations); • total cobalt (5 locations); • total copper (5 locations); • total lead (4 locations); • total nickel (7 locations); • total selenium (1 location); • total vanadium (4 locations); and • total zinc (5 locations). Please refer to Table 4 and 5 for a summary of which surface water constituents exceeded their established North Carolina Surface Water Quality Standards (NC2B)2 standard limits. Field parameters measured in the surface water included dissolved oxygen, pH, redox potential, specific conductance, turbidity, and temperature. The field parameter of turbidity was above the NC2B limit at two surface water locations (SW- 7 and SW-8). None of the other sampled field parameters were outside their NC2B standard limits for surface water, if established. 'North Carolina Department of Environmental Quality, Classifications of Water Quality Standards, Section 15A NCAC 2L.202, April 1, 2013; IMACs dated June 30, 2021. 2 North Carolina Department of Environmental Quality, Surface Waters and Wetlands Standards, Section 15A NCAC 02B workbook dated June 10, 2019. 3 of 4 1s 1M 1i Buncombe County Landfill —Alexander, North Carolina August 4, 2021 Report of Water Quality Sampling and Analysis — Is' Semi -Annual Event 2021 BLE Project No. J21-9378-23 4.3 Leak Detectors and Leachate Samples The results of the leak detector field and laboratory analyses are summarized on Tables 6 and 7 and the laboratory analytical data is included in Appendix B. VOC detections during the current sampling event included: • acetone (2 locations); • benzene (2 locations); • chlorobenzene (1 location); • chloroethane (1 location); • 1,4-dichlorobenzene (2 locations); • 1, 1 -dichloroethane (3 locations); • cis-1,2-dichloroethene (1 location); • 2-butanone (1 location); • toluene (1 location); • vinyl chloride (1 locations); and • total xylenes (1 location). Geochemical and field parameter water quality detections during the current sampling event included: • BOD (1 location); • COD (1 location); • Nitrates (1 location); • sulfates (1 location); and • phosphates (1 location). Total metals detections during the current sampling event included: • total antimony (2 locations); • total arsenic (2 locations); • total barium (all locations); • total beryllium (3 locations); • total cadmium (1 location); • total chromium (5 locations); • total cobalt (all locations); • total copper (5 locations); • total lead (3 locations); • total nickel (all locations); • total selenium (4 locations); • total thallium (1 location); • total vanadium (4 locations); and • total zinc (all locations). Please refer to Tables 6 and 7 for a summary of which leak detector and leachate constituents exceeded North Carolina Groundwater Quality Standards (NC2L) maximum contaminant levels' (MCLs). 4 of 5 1s 1m 1i Buncombe County Landfill —Alexander, North Carolina August 4, 2021 Report of Water Quality Sampling and Analysis — I' Semi -Annual Event 2021 BLE Project No. J21-9378-23 Field parameters measured in the groundwater included pH, specific conductance, turbidity, and temperature. The field parameter of pH was beneath its NC2L standard at three (3) locations. It is our understanding that in the past, semi-annual reports by others have not included the pH of samples collected from these locations, therefore we only have three semi-annual reports prepared by BLE including pH and no historical basis to conclude whether these results are typical. No other field parameters were outside their NC2L standard limits for groundwater, if established. 5.0 CONCLUSIONS AND RECOMMENDATIONS Semi-annual assessment monitoring was performed during the l' semi-annual event of 2021 in general accordance with the approved WQMP. Detected constituents which exceed their respective groundwater and surface water standards are identified on the summary tables. We recommend that semi-annual sampling continue in accordance the approved WQMP. Groundwater compliance issues identified in this report for the MW-151 MW-15D well pair were addressed in BLE's report and plan titled Report of Groundwater Compliance Assessment and Plan to Replace the MW- 151MW-15D Well Pair (FID 1595066) dated July 28, 2021 (BLE Project No, J21-9378-23). The report and plan requested replacement of the MW-151 MW-15D well pair with piezometer B-620 (renamed to MW-18). The SWS approved the plan in a letter dated August 3, 2021 (FID 1595460). The changes to the monitoring plan will be effective starting with the Fall 2021 sampling event. 6.0 QUALIFICATIONS OF REPORT The activities and evaluative approaches used in this assessment are consistent with those normally employed in hydrogeological and environmental assessments of this type. Our evaluation of site conditions has been based on our understanding of the site and project information and the data provided to BLE. This report has been prepared on behalf of and exclusively for the use of Buncombe County, North Carolina. This report and the findings contained herein shall not, in whole or in part, be used or relied upon by any other party (excluding the DWM) without BLE's prior written consent. 7.0 CLOSING We appreciate the opportunity to be of service to Buncombe County, North Carolina. Please contact us at (864) 288-1265 if you have any questions or comments. 5 of 5 TABLES Table 1 Well Construction and Monitoring Well Data Buncombe County Landfill Alexander, North Carolina BLE Project Number J21-9378-23 Permit No. 1107-CDLF-1998 Permit No. 1107-MSWLF-1996 Monitoring Point MSW or C&D Northing Easting1 TOC Elevation (ft)1 Ground Surface Elevation (ft)1 Depth to GW (ft) April 23, 2021 Groundwater Elevation (ft) Well Depth (ft)1 Screen Depth (below GS)1 Waste Unit Monitored Installation Date Geology Monitored) Well Status/Purpose Well Diameter (in)1 MW-1 Facility 737,383.3 923,481.5 2021.22 2019.28 63.49 1957.73 76 61.0 - 76.0 Facility 1990's Saprolite/PWR Background 2.0 MW-ID Facility 737,371.0 923,468.7 2021.57 2019.97 65.04 1956.53 200 85.0 - 95.0 Facility 1990's Bedrock Background 2.0 MW-2 MSW 739,569.6 921,033.3 1920.86 1918.54 7.80 1913.06 20 5.0 - 20.0 Cell 1990's Saprolite/PWR Compliance 2.0 MW-2D MSW 739,565.7 921,027.7 1920.51 1918.63 8.40 1912.11 55 45.0 - 55.0 Cell 1990's Bedrock Compliance 2.0 MW-3R MSW 739,499.1 920,384.3 1973.18 1975.67 51.81 1921.37 55 45.0 - 55.0 Cell 7/28/2014 MR Compliance 2.0 MW-4 MSW 739,263.0 920,192.1 1944.35 1942.48 12.17 1932.18 25 9.0 - 24.0 Cell 1011011996 Saprolite/PWR Compliance 2.0 MW-4D MSW 739,261.0 920,177.3 1944.64 1942.79 12.49 1932.15 55 45.0 - 55.0 Cell 1011111996 Bedrock Compliance 2.0 MW-5 MSW 739,111.5 920,246.7 1977.12 1975.39 33.42 1943.70 50 35.0 - 50.0 Cell 101911996 Saprolite/PWR Compliance 2.0 MW-5D MSW 739,103.6 920,242.3 1976.92 1975.31 35.06 1941.86 81 71.0 - 81.0 Cell 1011011996 Bedrock Compliance 2.0 MW-6 MSW 738,767.9 920,223.6 1987.34 1985.39 24.38 1962.96 50 35.0 - 50.0 Cell 101811996 Saprolite/PWR Compliance 2.0 MW-7 MSW 738,286.3 920,586.8 2022.83 2020.72 41.00 1981.83 61 42.0 - 61.0 Cell 101411996 Saprolite/PWR Compliance 2.0 MW-8 MSW 738,102.0 920,801.7 1962.06 1959.85 28.00 1934.06 70 55.0 - 70.0 Cell 1990's Saprolite/PWR Compliance 2.0 MW-8D MSW 738,116.7 920,812.0 1962.47 1960.57 27.00 1935.47 95 85.0 - 95.0 Cell 1990's Bedrock Compliance 2.0 MW-10 MSW 739,324.0 921,597.0 2010.54 2007.50 67.42 1943.12 73 58.0 - 73.0 Cell 3/6/2002 Saprolite/PWR Compliance 2.0 MW-10D MSW 739,324.0 921,590.8 2010.56 2007.50 67.16 1943.40 117 102.0 - 117.0 Cell 3/6/2002 Bedrock Compliance 2.0 MW-11 MSW 738,169.2 921,422.1 1966.71 1963.70 30.57 1936.14 50 35.0 - 50.0 Cell 3/6/2002 Bedrock Compliance 2.0 MW-11D MSW 738,154.0 921,406.0 1966.15 1963.20 31.87 1934.28 70 60.0 - 70.0 Cell 3/6/2002 Bedrock Compliance 2.0 MW-12 C&D 738,703.7 919,192.4 1947.39 1944.70 10.31 1937.08 17 7.0 - 17.0 Phases 1 - 5 6/25/2002 Saprolite/PWR/Bedrock Compliance 2.0 MW-12D C&D 739,489.5 921,966.6 1947.10 1944.30 9.64 1937.46 37 27.0 - 37.0 Phases 1 - 5 6/25/2002 Bedrock Compliance 2.0 MW-13 MSW 739,489.5 921,966.6 1953.92 1951.30 2.81 1951.11 16 6.0 - 16.0 Cell 612412005 Bedrock Compliance 2.0 MW-13D MSW 738,761.6 919,055.7 1953.82 1951.40 5.82 1948.00 44 39.0 - 44.0 Cell 6/23/2005 Bedrock Compliance 2.0 MW-14 C&D 738,782.5 919,037.1 1952.77 1949.80 28.25 1924.52 49 39.0 - 49.0 Phases 1 - 5 4/5/2006 Bedrock Compliance 2.0 MW-14D C&D 738,703.7 919,192.4 1 1953.76 1950.70 28.70 1 1925.06 88 78.0 - 88.0 Phases 1 - 5 1 4/6/2006 Bedrock Compliance 2.0 MW-15 C&D 739,143.4 1 919,829.3 1973.29 1 1970.21 1 22.40 1950.89 1 26 16.0 - 26.0 Phases 1 - 5 6/7/2012 Saprolite/PWR Compliance 2.0 MW-15D C&D 739,143.4 919,829.3 1973.51 1970.25 24.98 1948.53 1 43 33.0 - 43.0 Phases 1 - 5 6/7/2012 Bedrock Compliance 2.0 MW-17 Abandoned - September 14, 2020 MW-17D Abandoned - September 14, 2020 MW-17R C&D 738,579.7 918,662.0 1891.61 1888.96 15.02 1876.59___4 23.5 1 8.5 - 23.5 Phase 6 9/3/2020 Bedrock Compliance 2.0 MW-17DR C&D 738,569.7 918,659.3 1891.70 1889.14 13.72 1877.98 39 1 34.0 - 39.0 Phase 6 9/2/2020 Bedrock Compliance 2.0 ' - Data from Table 3, Well Construction, New Buncombe County Landfill, Buncombe County, North Carolina, provided by SCS Engineers. 2 - Based on visual observation of Sheet No I Groundwater and Methane Monitoring Well Locations by CDM Smith dated August 2014. Some well installation dates appear inconsistent with water level records and may not be accurate. Changes to some dates (italics) made based on water level records and dates from SHR and DHR documents by CDM. The top of casing and ground surface elevations for MW-3R are a probable error (reversed) based on April 2016 water levels in the SCS Engineers report. The top of casing and ground surface elevations for MW-14 and MW-14D do not match those in the SHR and DHR documents by CDM. The well construction and survey data for MW-17R and MW-17DR are from a report by SCS dated October 13, 2020 TOC - Top of Casing. GS - Ground Surface. All depth measurments in feet -- All elevations in feet above an arbitrary site datum. 9378-23 GW Tables (Completion, water levels, detections) Prepared by: RLB T1 (4-23-21) MW Points Checked by: IAI Table 2 Groundwater VOCs Buncombe County Landfill Alexander, North Carolina BLE Project Number J21-9378-23 Permit No. 1107-CDLF-1998 Permit No. 1107-MSWLF-1996 Sam led by Pace Anal tical Services, LLC. April 26-28, 2021 TEST UNITS LOQ DL MCL MW-1 MW-1D MW-2 MW-2D MW-311 MW-4 MW-41) MW-5 MW-51) MW-6 MW-7 MW-8 MW-81) MW-10 MW-lOD MW-11 MW-11D MW-12 MW-12D MW-13 MW-13D MW-14 MW-14D MW-15 MW-15D MW-17R MW-17DR EQUIP' BLANK Acetone µM 20 5.0 6,000 8.2 J <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 5.3 J <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 6.7 J <5.0 7.6 J <5.0 <5.0 <5.0 Acrylonitrile µg/1 20 0.8 NE <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 Benzene µM 1.0 0.4 1.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 0.54 J <0.4 <0.4 <0.4 Bromochloromethane µg/1 1.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromodichloromethane µM 1.0 0.4 0.6 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromoform µg/1 1.0 0.4 4.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Carbon Disulfide µM 1.0 0.4 700 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromomethane (Methylbromide) µg/1 2.0 0.4 10.0 (i) <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Carbon tetrachloride µM 1.0 0.4 0.3 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chlorobenzene (mono) µg/l 1.0 0.4 50.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloroethane µg/1 2.0 0.4 3,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloroform µg/1 1.0 0.4 70.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloromethane (Methylchloride) µM 1.0 0.5 3.0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 Dibromochloromethane µg/1 1.0 0.4 0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dibromo-3-chloropropane; DBCP µM 1.0 0.4 0.04 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dibromoethane; Ethylene dibromide µg/1 1.0 0.4 0.02 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Dibromomethane µM 1.0 0.4 70.0 (i) <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichlorobenzene µg/l 1.0 0.4 20.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,4-Dichlorobenzene µg/1 1.0 0.4 6.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,4-Dichloro-2-butene µg/1 2.0 0.5 NE <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 1,1-Dichloroethane µg/1 1.0 0.4 6.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 0.68 J <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichloroethane µg/1 1.0 0.4 0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 0.57 J <0.4 <0.4 <0.4 1, 1 -Dichloroethene (-ethylene) µg/1 1.0 0.4 350.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 cis-1,2-Dichloroethene (-ethylene) µg/1 1.0 0.4 70.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 0.42 J <0.4 <0.4 <0.4 0.55 J <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 0.53 J <0.4 <0.4 <0.4 trans-1,2-Dichloroethene (-ylene) µg/1 1.0 0.4 100 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichloropmpane µg/l 1.0 0.4 0.6 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 cis-1,3-Dichloropropene (-propylene) µg/1 1.0 0.4 0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,3-Dichloropropene (-propylene) µg/1 1.0 0.4 0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Ethylbenzene µg/1 1.0 0.4 600 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 2-Hexanone µg/1 10 2.0 40.0 (i) <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Iodomethane µg/1 5.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Dichloromethane (Methylene chloride) µg/1 1.0 0.4 5.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 2-Butanone (Methyl ethyl ketone) µg/1 10 2.0 4000 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 5.1 J 2.6 J 3.2 J <2.0 <2.0 3.4 J <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 2.3 J 4-Methyl-2-Pentanone µg/1 10 2.0 NE <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Styrene µg/1 1.0 0.4 70.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1, 1, 1,2-Tetrachloroethane µg/1 1.0 0.4 1.0 (i) 1 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1,2,2-Tetrachloroethane µg/1 1.0 0.4 0.2 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Tetrachloroethee (-ethylene) µg/1 1.0 0.4 0.7 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Toluene µg/1 1.0 0.4 600 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1, 1, 1 -Trichloroethane µg/1 1.0 0.4 200 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1,2-Trichloroethane µg/1 1.0 0.4 0.6 (i) <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Trichloroethene (-ethylene) µg/1 1.0 0.4 3.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Trichlorofluoromethane µg/1 1.0 0.4 2,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2,3-Trichloropropane µg/1 1.0 0.4 0.005 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Vinyl acetate µg/1 5.0 1.2 88.0 (i) <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 Vinyl chloride µg/1 1.0 0.4 0.03 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 2.6 <0.4 <0.4 <0.4 Total Xylenes µg/1 1.0 0.4 500 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Tetrahydrofuran µ, 5.0 1.0 2,000 (i) <1.0 <1.0 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT 6.1 1.4 J NT NT <1.0 <1.0 1.9 J 3.1 J <1.0 <1.0 <1.0 1,4-Dioxane µ 3.0 1.0 3.0 NT NT NT NT NT <1.0 <1.0 NT NT NT NT NT NT <1.0 <1.0 NT NT 2.6 J 1.2 J NT NT NT NT 9.4 36 <1.0 <1.0 <1.0 Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable to Groundwaters of North Carolina, Section 15A NCAC 2L .0202. Amended Eff. April 1, 2013 2. (i) = hiterim Maximum Allowable Concentrations (lMACs). Updated June 30, 2021 3. Shaded cells indicate exceedances of IMACs 4. Shaded cells indicated exceedances of MCLs 5. NE = Not Established; North Carolina has not established a MCL 6. LOQ = Limit of Quantitation 7. DL = method Detection Limit 8. NT = Not Tested 9. "J"-flagged data (i.e., values estimated between the DL and the LOQ) are presented on this spreadsheet. 9378-23 GW Tables (Completion, water levels, detections) T2 (4-28-21) VOC Prepared by: RLB Checked by: IAI/ AWA Table 3 Groundwater Field Parameters, Geochemical Parameters, and Total Metals Buncombe County Landfill Alexander, North Carolina BLE Project Number J21-9378-23 Permit No. 1107-CDLF-1998 Permit No. 1107-MSWLF-1996 Sam led b Pace Analytical Services, LLC. April 26-28, 2021 TEST UNITS LOQ DL MCL AM-1 MW-1D AM-2 MW-2D MW-3R MW-4 MW41) MW-5 MW-51) MW-6 MW-7 MW-8 MW-81) MW-10 MW-IOD MW-11 MW-11D MW-12 MW-12D MW-13 MW-13D MW-14 MW-14D MW-15 MW-15D MW-17R MW-17DR EQUIP. BLANK pH s.u. <6.5; >8.5 6.50 7.40 6.10 6.30 5.93 6.01 6.47 6.20 6.20 6.10 6.40 6.10 6.20 5.85 6.17 6.50 6.10 6.30 6.90 6.70 6.40 6.00 7.20 6.10 5.90 6.60 7.20 NT Specific Conductance µmhos/cm NE 185.3 254.6 479.3 266.4 77.6 250.0 333.8 226.3 222.4 148.5 737.0 392.4 431.3 322.8 386.2 451.2 435.4 1,083 491.5 373.2 412.6 184.6 338.0 667.0 1,070 227.1 288.7 NT Temperature °C NE 23.7 18.0 12.9 14.3 14.8 15 16.3 22.3 16.1 18.9 21.4 18.2 22.2 19.2 18 22.5 21.8 18 17.7 14.8 16.9 17.5 20.0 16.5 22.3 17.4 18.7 NT Turbidity NTU NE 2.3 8.4 9.7 0.1 8.13 3.22 7.32 8.8 3.9 2.2 3.8 8.4 7.6 5.49 6.38 8.5 3.2 2.4 2.1 4.9 0.4 1 0.8 5.7 0.7 1.3 1.1 NT Alkalinity mg/1 20 20 NE 62 81 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT 270 190 NT NT 62 140 300 360 72 120 NT Total Dissolved Solids (TDS) mg/1 25 25 500 150 170 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT 820 320 NT NT 140 210 380 750 140 190 NT Iron H (Fe 2+) µg/1 50 13 300 130 480 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT 770 630 NT NT 91 200 70,000 1,700 160 320 NT Sulfate mg/1 1.0 0.25 250 18 42 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT 330 68 NT NT 22 31 34 140 33 24 NT Chloride mg/1 1.0 0.25 1 250 6.4 2.5 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT 44 13 NT NT 2.8 4 27 86 3 4.1 NT Total Antimony (Sb) µg/1 2.0 0.5 7 1.0 0) <0.5 0.77 J <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 0.63 J <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 Total Arsenic (As) µg/1 2.0 1.3 10.0 <1.3 <1.3 <1.3 <1.3 <L3 <1.3 <L3 <1.3 <L3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <L3 <1.3 Total Barium (Ba) µg/1 5.0 1.3 700 150 33 190 110 45 80 51 130 77 56 170 150 180 110 26 97 74 120 49 190 220 50 5.2 240 140 63 66 <1.3 Total Beryllium (Be) µg/1 0.4 0.15 4.0 (i) <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.28 J <0.2 <0.2 <0.2 Total Cadmium (Cd) µg/1 0.5 0.13 2.0 <0.1 <0.1 0.13 J <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 Total Chromium (Cr) µg/1 5.0 1.3 10.0 2.1 J 33 <1.3 1.8 J 4.1 J <1.3 <L3 19 1.4 J 1.3 J <1.3 4.6 J 2.8 J 1.5 J 1.5 J <1.3 <1.3 3.5 J 1.4 J <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <L3 <1.3 Total Cobalt (Co) µg/1 5.0 1.3 1.0 (i) <1.3 <1.3 10 <1.3 <L3 <1.3 <L3 <1.3 <L3 <1.3 1.4 J <1.3 <1.3 2.9 J <1.3 3.2 J <1.3 38 3.9 J 28 1 18 <1.3 <1.3 79 4.7 J <1.3 <1.3 <1.3 Total Copper (Cu) µg/1 5.0 1.3 1000 <1.3 1.8 J <1.3 <1.3 <L3 <1.3 <L3 <1.3 <L3 <1.3 <1.3 1.7 J <1.3 3.2 J <1.3 2.9 J 1.3 J 4.4 J <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 2.1 J <1.3 <1.3 Total Lead (Pb) µg/1 1.0 0.25 1 15.0 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 0.32 J 0.5 J <03 <0.3 0.55 J <0.3 <03 <0.3 <03 <0.3 <0.3 <0.3 <03 <0.3 <0.3 <0.3 <0.3 Total Manganese (Mn) µg/1 5.0 1.3 50.0 2.5 J 14 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT 3,300 860 NT NT <1.3 5.2 11,000 1,300 25 38 NT Total Mercury (Hg) µg/1 0.20 0.091 1.0 <0.1 <0.1 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT <0.1 <0.1 NT NT <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 NT Total Nickel (Ni) µg/1 5.0 1.3 100.0 <1.3 19 33 1.4 J 3.4 J 5 <L3 24 4.0 J <1.3 9.7 4.1 J 4.4 J 8 11 44 4.6 J 37 4.4 J 7.6 8.8 1.8 J <1.3 10 44 11 <1.3 <1.3 Total Selenium (Se) µg/1 5.0 1.3 20.0 <1.3 <1.3 <L3 <1.3 <L3 <1.3 <L3 <1.3 <L3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <L3 <1.3 Total Silver (Ag) µg/1 1.0 0.25 20.0 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 Total Thallium (Tl) µg/1 0.5 0.15 0.2 (i) <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 < . I <0.2 < . 1 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 Total Vanadium (V) µg/1 5.0 2.5 0.3 (i) 3.1 J <2.5 <2.5 2.5 J 3.6 J <2.5 3.0 J 2.6 J <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 2.5 J <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 Total Zinc (Zn) µg/1 10 2.5 1000.0 6.4 J 3.0 J 8.8 J <2.5 5.4 J 5.9 J <2.5 3.1 J <2.5 <2.5 <2.5 3.8 J 5.3 J 4.2 J <2.5 6.2 J 12 4.0 J <2.5 <2.5 <2.5 <2.5 2.8 J 3.3 J 9.6 J 3.2 J 1 <2.5 <2.5 Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable to Groundwaters of North Carolina, Section 15A NCAC 2L .0202. Amended Eff. April 1, 2013 2. (i) = Interim Maximum Allowable Concentrations (IMACs). Updated July 30, 2021 3. Shaded cells indicate exceedances of IMACs 4. Shaded cells indicated exceedances of MCLs 5. NE = Not Established; North Carolina has not established a MCL 6. LOQ = Limit of Quantitation 7. DL = method Detection Limit 8. NT = Not Tested 9. "J"-flagged data (i.e., values estimated between the DL and the LOQ) are presented on this spreadsheet. 9378-23 GW Tables (Completion, water levels, detections) Prepared by: RLB T3 (4-28-21) Metals Checked by: IAI/ AWA Table 4 Surface Water VOCs Buncombe County Landfill Alexander, North Carolina BLE Project Number J21-9378-23 Permit No. 1107-CDLF-1998 Permit No. 1107-MSWLF-1996 Sampled by Pace Anal tical Services, LLC. April 26-27, 2021 TEST UNITS LOQ DL NC2B SW-1 SW-2 SW-3 SW-4 SW-5 SW-6 SW-7 SW-8 Acetone µg/l 20 5.0 2,000 15.0 <5.0 <5.0 <5.0 5.1 J <5.0 35 J <5.0 Acrylonitrile µ9/1 20 0.8 420.0 10.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 Benzene µg/l 1.0 0.4 51.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromochlommethane µg/1 1.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromodichloromethane µg/1 1.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromoform µg/l 1.0 0.4 120 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Carbon Disulfide µg/1 1.0 0.4 100 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromomethane (Methylbromide) µg/I 2.0 0.4 0.04 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Carbon tetrachloride µ9/1 1.0 0.4 1.6 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chlorobenzene (mono) µg/I 1.0 0.4 800 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloroethane µg/1 2.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloroform µg/I 1.0 0.4 2,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloromethane (Methylehlonde) µ9/1 1.0 0.5 96 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 Dibromochloromethane µ9/1 1.0 0.4 21 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0,4 <0.4 1,2-Dibromo-3-chloropmpane; DBCP µ9/1 1.0 0.4 0.13 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dibromoethane; Ethylene dibromide µ9/1 1.0 0.4 0.1 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Dibromomethane µg/l 1.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichlorobenzene µg/I 1.0 0.4 3,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,4-Dichlorobenzene µg/1 1.0 0.4 900 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,4-Dichloro-2butene µ9/1 2.0 0.5 NE <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 l,l-Dichloroethane µg/I 1.0 0.4 100 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichloroethane µg/I 1.0 0.4 650 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1-Dichloroethene(-ethylene) µg/1 1.0 0.4 20,000 10.4 <0.4 10.4 <0.4 10.4 <0.4 <0.4 <0.4 cis- 1,2-Dichloroethene(-ethylene) µ9/1 1.0 0.4 720 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,2-Dichloroethene (-ylene) µg/1 1.0 0.4 4,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichloropropane µ9/1 1.0 0.4 31.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 cis-1,3-Dichloropropene (-propylene) µg/1 1.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,3-Dichloropropene (-propylene) µ9/1 1.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Ethylbenzene µg/1 1.0 0.4 97 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 2-flexanone µg/I 10 2.0 NE <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Iodomethane µg/1 5.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Dichloromethane (Methylene chloride) µg/l 1.0 0.4 11000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 2-Butanone (Methyl ethyl ketone) µg/1 10.0 2.0 26,000 <2.0 <2.0 4.1 J <2.0 <2.0 <2.0 <2.0 <2.0 4-Methyl-2-Pentanone µ9/1 10.0 2.0 26000 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Styrene µg/I 1.0 0.41 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1, 1, 1,2-Tetrachloroethane µ9/1 1.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1, 1,2,2-Tetrachloroethane µg/l 1.0 0.4 4.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Tetrachlomethene (-ethylene) µg/1 1.0 0.4 3.3 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Toluene µg/1 1.0 0.4 11.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1,1-Trichlormhane µg/I 1.0 0.4 200,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1,2-Trichloroethane µg/1 1.0 0.4 8.9 10.4 <0.4 10.4 <0.4 <0.4 <0.4 <0.4 <0.4 Trlchlormhene (-ethylene) µg/l 1.0 0.4 30.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Trichlorofluoromethane µg/l 1.0 0.4 67,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2,3-Trichloropropane µg/1 1.0 0.4 0.001 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Vinyl acetate µg/1 5.0 1.2 NE <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 Vinyl chloride µ9/1 1.0 0.4 2.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Total Xylenes µg/I 1.0 0.4 670 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Tetrahydrofuran µg/I 5.0 1.0 110,000 NT NT NT NT 1.4 J <LO NT <LO 1,4-Dioxane µ 3.0 1.0 80.0 <1.0 <1.0 14 <1.0 6.1 10 7.2 J 1.8 J Notes• 1. NC213 - North Carolina Surface Water Standards for Class C freshwater under Title 15A Subchapter 213. 5. LOQ - Limit of Quantitation per NC DWR Surface Water Quality Standards, Criteria, & In -Stream Target Values (Workbook Dated 6-10-2019) 6. DL = method Detection Limit 2. NE - Not Established; North Carolina has not established a MCL 7. NT = Not Tested 3. "J"-flagged data (i.e., values estimated between the DL and the LOQ) are presented on this spreadsheet. 8. DNA = Data Not Available 4. Shaded cells indicated exceedances of MCLs 9378-23 SW Tables Prepared by: RLB T4 SW VOC (4-27-21) Checked by: IAl1 AWA Table 5 Surface Water Field Parameters and Total Metals Buncombe County Landfill Alexander, North Carolina BLE Project Number J21-9378-23 Permit No. 1107-CDLF-1998 Permit No. 1107-MSWLF-1996 Sampled by Pace Analytical Services, LLC. April 26-27, 2021 TEST UNITS LOQ DL NC211 SW-1 NC211 SW-2 NC211 SW-3 NC211 SW-4 NC2B SW-5 NC2B SW-6 NC211 SW-7 NC2B SW-8 PH s.u. (on -site) - - <6.0; >9.0 6.8 <6.0; >9.0 7.9 <6.0; >9.0 8.1 <6.0; >9.0 7.7 <6.0; >9.0 8 <6.0; >9.0 8.40 <6.0; >9.0 8.5 <6.0; >9.0 7.8 Specific Conductance µmhos/cm (on -site) - - NE 103 NE 164.8 NE 999 NE 335 NE 2,185 NE 732 NE 5,190 NE 359 Temperature °C (on -site) - - 29.0 9.3 29.0 10 29.0 21.2 29.0 16.6 29.0 13.7 29.0 11.3 29.0 9 29.0 10.0 Turbidity NTU (on -site) - - 50.0 4.6 50.0 8.5 50.0 49 50.0 43 50.0 6 50.0 14.8 50.0 128.7 50.0 53.3 Hardness mg/1 10 2.0 NE NT NE NT NE NT NE NT NE NT NE NT NE NT NE NT Total Antimony (Sb) µg/1 2.0 0.5 640 <0.5 640 <0.5 640 <0.5 640 <0.5 640 <0.5 640 <0.5 640 2.9 J 640 <0.5 Total Arsenic (As) µg/1 2.0 1.3 10 <1.3 10 <1.3 10 <1.3 10 <1.3 10 <1.3 10 <1.3 10 21 10 2.6 Total Barium (Ba) µg/1 5.0 1.3 21,000 79 21,000 57 21,000 250 21,000 120 21,000 110 21,000 110 21,000 300 21,000 110 Total Beryllium (Be) µg/1 0.4 0.15 65 <0.2 65 <0.2 65 <0.2 65 <0.2 65 <0.2 65 <0.2 65 <0.2 65 <0.2 Total Cadmium (Cd) µg/1 0.5 0.13 0.79 <0.1 1.6 <0.1 3.7 <0.1 3.9 <0.1 17 <0.1 5.0 <0.1 52 <0.1 4.6 <0.1 Total Chromium (Cr) µg/1 5.0 1.3 177 <1.3 344 1.5 J 751 3.8 J 794 2.8 J 3,160 8.6 1,005 3.8 J 9,235 120 922 8.1 Total Cobalt (Co) µg/1 5.0 1.3 16 <1.3 16 <1.3 16 16 2.6 J 16 12 16 <1.3 16 66 16 2.5 J Total Copper (Cu) µg/1 5.0 1.3 3.5 <1.3 33 <1.3 18 2.8 J 20 3.1 J 96 2.2 J 26 <1.3 331 28 23 4.3 J Total Lead (Pb) µg/1 1.0 0.25 13 <0.3 1.3 <0.3 93 0.39 J 100 0.49 J 569 <0.3 136 <0.3 1,831 5.9 122 0.80 J Total Nickel (Ni) µg/1 5.0 1.3 140 <1.3 278 1.7 J 622 19 660 5.5 2,748 17 842 4.7 8,320 110 770 7.3 Total Selenium (Se) µg/1 5.0 1.3 5.0 <1.3 5.0 <1.3 5.0 <1.3 5.0 <1.3 5.0 2.0 J 5.0 <1.3 5.0 <1.3 5.0 <1.3 Total Silver (Ag) µg/1 1.0 0.25 0.28 <0.3 1.1 <0.3 5.7 <0.3 6.5 <0.3 117 <0.3 11 <0.3 1,117 <0.3 8.8 <0.3 Total Thallium (Tl) µg/1 0.5 0.15 NE <0.2 NE <0.2 NE <0.2 NE <0.2 NE <0.2 NE <0.2 NE <0.2 NE <0.2 Total Vanadium (V) µg/1 5.0 2.5 NE <2.5 NE <2.5 NE 4.4 J NE 3.8 J NE <2.5 NE <2.5 NE 59 NE 9.2 Total Zinc (Zn) µg/1 10 2.5 35 <2.5 70 <2.5 156 7.8 J 165 20 695 17 211 <2.5 2,091 110 193 9.3 Notes: 1. NC213 = North Carolina Surface Water Standards for Class C freshwater under Title 15A Subchapter 213. per NC DWR Surface Water Quality Standards, Criteria, & In -Stream Target Values (Workbook Dated 6-10-2019) Measured values of hardness were utilized to calculate an acute standard at each surface water location for metals highlighted in green. Hardness values were reported in Report of Water Quality Sampling and Analysis 1st Semi -Annual Event 2020 Buncombe County Landfill Alexander, North Carolina prepared by BLE, dated July 13, 2020. 2. NE = Not Established; North Carolina has not established a standard 3. "J"-flagged data (i.e., values estimated between the DL and the LOQ) are presented on this spreadsheet. 4. Shaded cells indicated exceedances of MCLs 9378-23 SW Tables T5 SW Metals (4-27-21) 5. LOQ = Limit of Quantitation 6. DL = method Detection Limit 7. NT = Not Tested 8. DNA = Data Not Available Prepared by: RLB Checked by: IAI/ AWA Table 6 Leak Detector and Leachate VOCs Buncombe County Landfill Alexander, North Carolina BLE Project Number J21-9378-23 Permit No. 1107-CDLF-1998 Permit No. 1107-MSWLF-1996 Sam led by Pace Anal tical Services, LLC. April 26, 2021 TEST UNITS LOQ DL MCL LD-1 LD-2 LD-3 LD4 LD-5 LD-6 Leachate LD Leachate Pond Acetone µg/1 25.0 5.0 6,000 <5.0 15.0 <5.0 5.1 J <5.0 <5.0 <5.0 46 J Acrylonitrile µg/1 10.0 0.8 NE <0.8 <0.8 <0.8 <0.8 10.8 <0.8 <0.8 <0.8 Benzene µg/1 LO 0.4 1.0 1.8 <0.4 10.4 1.8 <0.4 <0.4 <0.4 <0.4 Bromochloromethane 99/1 LO 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromodichloromethane 99/1 LO 0.4 0.6 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromofomi µg/1 LO 0.4 4.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Carbon Disulfide µg/1 2.0 0.4 700 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromomethane (Methylbromide) µg/1 2.0 0.4 10.0 (i) <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Carbon tetrachloride 99/1 LO 0.4 0.3 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 10.4 <0.4 Chlorobenzene (mono) µg/1 LO 0.4 50.0 0.53 J <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloroethane µg/1 LO 0.4 3,000 0.59 J <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloroform µg/1 LO 0.4 70.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloromethane (Methylchloride) µg/1 LO 0.5 3.0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 Dibromochloromethane µg/l LO 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dibromo-3-chloropropane; DBCP µg/1 2.0 0.4 0.04 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dibromoethane; Ethylene dibromide µg/l LO 0.4 0.02 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Dibromomethane µg/1 LO 0.4 70.0 (1) <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichlombenzene µg/1 LO 0.4 20.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,4-Dichlorobenzene 99/1 LO 0.4 6.0 1.1 <0.4 0.58 J <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,4-Dichloro-2butene 99/1 LO 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1-Dichloroethane 99/1 LO 0.5 6.0 0.85 J 1.2 <0.5 0.53 J <0.5 <0.5 <0.5 <0.5 1,2-Dichloroethane 99/1 LO 0.4 0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1-Dichloroethene(-ethylene) µg/1 LO 0.4 7.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 cis-1,2-Dichloroethene (-ethylene) µg/l LO 0.4 70.0 0.63 J <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 trams- l,2-Dichloroethene(-ylene) µg/l LO 0.4 too <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichloropropane µg/l LO 0.4 0.6 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 cis-1,3-Dichloropropene (-propylene) µg/1 LO 0.4 0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,3-Dichloropropene (-propylene) µg/1 LO 0.4 0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Ethylbenzene µg/1 LO 0.4 600 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 2-Hexanone µg/1 5.0 2.0 40.0 (1) <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 lodomethane µg/1 5.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Dichlomanothane (Methylene chloride) µg/l 2.0 0.4 5.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 2-Butanone (Methyl ethyl ketone) 99/1 5.0 2.0 4000 14 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 4-Methyl-2-Peatanone µg/l 5.0 2.0 NE <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Styrene µg/1 LO 0.4 70.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1,1,2-Tenachloroethane 99/1 LO 0.4 1.0 (i) <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1,2,2-Tetrachlomethane 99/1 LO 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Tetrachloroethene (-ethylene) µg/1 LO 0.4 0.7 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Toluene µg/1 LO 0.4 600 <0.4 <0.4 <0.4 0.55 J <0.4 <0.4 <0.4 <0.4 1,1,1-Trichloroethane 99/1 LO 0.4 200 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1,2-Trlchloroethane 99/1 LO 0.4 0.6 (i) <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Trichloroethene (-ethylene) µg/l LO 0.4 3.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Trlchlorofluoromethane 99/1 LO 0.4 2,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2,3-Trichloropropane 99/1 LO 0.4 0.005 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Vinyl acetate µg/1 2.0 1.2 88.0 (1) <12 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 Vinyl chloride 99/1 LO 0.4 0.03 <0.4 <0.4 <0.4 1.2 <0.4 <0.4 <0.4 <0.4 Total Xylenes 99/1 2.0 0.4 500 <0.4 <0.4 <0.4 0.40 J <0.4 <0.4 <0.4 <0.4 1,4-Dioxane ggll 2.0 1.0 3.0 NT NT NT NT NT NT NT NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable to Groundwaters of North Carolina, Section 15A NCAC 2L .0202. Amended Eff. April 1, 2013 2. (i) = Interim Maximum Allowable Concentrations (EVACs). Updated June 30, 2021 3. Shaded cells indicate exceedances of IMACs 4. Shaded cells indicated exceedances of MCLs 5. NE = Not Established; North Carolina has not established a MC 6. LOQ = Limit of Quantitation 7. DL= method Detection Limit 8. NT - Not Tested 9. "J"-flagged data (i.e., values estimated between the DL and the LOQ) are presented on this spreadsheet. 9378-23 Leachate Tables Prepared by: RLB T6 LD VOC (4-26-21) Checked by: IAA AWA Table 7 Leak Detector and Leachate Field Parameters and Total Metals Buncombe County Landfill Alexander, North Carolina BLE Project Number J21-9378-23 Permit No. 1107-CDLF-1998 Permit No. 1107-MSWLF-1996 Sam led by Pace Analytical Services, LLC. April 26, 2021 TEST UNITS LOQ DL MCL LD-1 LD-2 LD-3 LD-4 LD-5 LD-6 Leachate LD Leachate Pond PH s.u. units (on -site) <6.5; >8.5 6.4 6.0 6.8 6.6 6.8 6.5 4.6 8.3 Specific Conductance µmhos/cm (on -site) NE 1,509 416 591 3,345 769 524.3 585.8 5,459 Temperature °C (on -site) NE 19.5 14.7 23.9 22.1 19.8 21 16 29.7 Turbidity NTU (on -site) NE 146.7 151.4 382.1 7.8 2.1 43.5 1.2 NT Biologic Oxygen Demand (BOD) mg/1 2.0 - NE NT NT NT NT NT NT NT <12 Chemical Oxygen Demand (COD) 1119/1 80 80 NE NT NT NT NT NT NT NT 650 Nitrates mg/1 0.04 - 10 NT NT NT NT NT NT NT 0.072 J Sulfates m9/1 1.0 - 250 NT NT NT NT NT NT NT 100 Phosphates mg/1 0.05 0.02 NE NT NT NT NT NT NT NT 1.8 Total Antimony (Sb) µg/1 2.0 0.5 1.0 (i) <0.5 <0.5 <0.5 1.1 J <0.5 <0.5 <0.5 11 Total Arsenic (As) µg/l 2.0 1.3 10 <1.3 <1.3 <1.3 4.4 <1.3 <1.3 <1.3 31 Total Barium (Ba) µg/1 5.0 1.3 700 830 260 240 470 97 410 28 340 Total Beryllium (Be) µg/1 0.4 0.15 4.0 (i) 0.30 J 0.23 J <0.2 <0.2 <0.2 <0.2 0.66 J <0.2 Total Cadmium (Cd) µg/l 0.5 0.13 2.0 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.28 J <0.1 Total Chromium (Cr) µg/1 5.0 1.3 10 1.3 J 19 V 1.4 J 270 <1.3 <1.3 <1.3 61 Total Cobalt (Co) µg/l 5.0 1.3 1.0 (i) 360 76 4.1 J 15 50 75 52 15 Total Copper (Cu) µg/1 5.0 1.3 1,000 <1.3 10 90 21 <1.3 <1.3 14 1.3 J Total Lead (Pb) µg/1 5.0 0.25 15.0 <0.3 1.8 0.43 J <0.3 <0.3 <0.3 <0.3 0.37 J Total Mercury (Hg) µg/l NT NT 1.0 NT NT NT NT NT NT NT NT Total Nickel (Ni) µg/1 5.0 1.3 100 53 28 3.6 J 100 16 3.8 J 440 65 Total Selenium (Se) µg/1 10 1.3 20 3.0 J <1.3 <1.3 4.5 J <1.3 <1.3 2.8 J 5.7 Total Silver (Ag) µg/l 1.0 0.25 20 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 Total Thallium (Tl) µg/1 0.5 0.15 0.2 (i) 0.22 J <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 Total Vanadium (V) µg/l 5.0 2.5 0.3 (i) 3.5 J 20 <2.5 11 <2.5 <2.5 <2.5 24 Total Zinc (Zn) µg/1 10 2.5 1,000 6.4 J 33 5.0 J 8.1 J 2.8 J 10 200 6.3 J Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable to Groundwaters of North Carolina, Section 15A NCAC 2L .0202. Amended Eff. April 1, 2013 2. (i) = Interim Maximum Allowable Concentrations (IMACs). Updated June 30, 2021 3. Shaded cells indicate exceedances of IMACs 4. Shaded cells indicated exceedances of MCLs 9378-23 Leachate Tables T7 LD Metals (4-26-21) 5. NE = Not Established; North Carolina has not established a MCL 6. LOQ = Limit of Quantitation 7. DL = method Detection Limit 8. NT = Not Tested 9. "J"-flagged data (i.e., values estimated between the DL and the LOQ) are presented on this spreadsheet. Prepared by: RLB Checked by: IAI/ AWA FIGURES 70 0 T vy. o � 1750 Z ti z-- 141 D O J 01 D a 1 gg '9A ti ,s�J " \ 0 R � 251 y p, , RD 2oG o Al ° Alexander 2000 1000 0 2000 4000 APPROXIMATE SCALE IN FEET DRAWN: KLW DATE: 5-21-21 ' IM I BUNNELL � LAMMONS CHECKED: RLB I CAD: BCLF23-SLM ENGINEERING 6004 Ponders Court, Greenville, SC 29615 APPROVED: JOB NO: J21-9378-23 Phone: (864) 288-1265 Fax: (864] 288-4430 REFERENCE: USGS TOPOGRAPHIC MAP, 7.5 MINUTE SERIES, LEICESTER AND WEAVERVILLE, N.C. QUADRANGLES, PHOTOREMSED 2017 AND PHOTOREMSED 2017. SITE LOCATION MAP I BUNCOMBE COUNTY LANDFILL ALEXANDER, NORTH CAROLINA FIGURE ♦/ N N / CONVE IE CE CENTER LANDFILL OFFICE BUILDING � F lot OO N Q, - -BL_ *0. i FLOC✓) ral0- ",�/ it _ .L WELL ��SW 2 / 1913,06 HOUSE = MW-2 SW-6,� �/ SCALE HOUSE MW-2D �� / �IVIW-31R 1921.37 1912,11 PANTHER BRANCH �� 1943�12�MW-10D� �� MW-10 �1932,18�� --L) �Lu_4 1943.40 MW-4 / JkSW-8 ♦ // MW-4D)Kel .01 I ---19 3 2.1_5 j 1_9 41 , 8 6 ♦_ V A I MW-5D�- - \ _---- - \ �1950,89 MW-5 1943,70 \ INACTIVE BMW 15 \,SW-3 \ \ INACTIVE ,�� MW-15D� '� \ CELL 3 _ \ I 1 1948,53 \-- I - CELL 4 ..INACTIVE. ............. CELL 1 / 1924,52 SW 5 cc** ca w I 0 0o o 00cn I 0 Goo � I n c Tj 'I MW -17I R CD�(1876,5 9) MW-17DR I 798 o MW-17 MW-17D ® �r (AB) (AB) �� • 1 V 90AWA MW-13D* 1951 —LD 6A NMW-14� ! I I / f--••... \ ` I I � `®M W -14 D 19 2 5 , 0 6 M �,� - 6 I -------------•------------ i r — — — — — — — MW-12 1937.08 1962.961 I — BMW-12D)K 1937.46 / /♦ I BUNCOMBE COUNTY , EMERGENCY SERVICES , INACTIVE RADIO TOWER \ �� ,� CELL 2 INACTIVE\ ,�` �� ��` �� ♦ , CELL 5 EXISTING �p MW-7 p � LLD - PHASE 1-5 / Ui 1981,83/ - �• C&D AREA \ I M-2 /-CACHATE* — _ .� �\ �� /� ,/ ID I / ` PHASE PERMITT6 D C&D AREA 00 4. �'2 g0� 10000, M W 8 \ 1934,06 MW-11 �e93 MW-8D)K 1936.14 • 1935,47 � / E EMPLOYEE E / , I LEACHATE TRAILER GARAGE �� POND - o (KAAIN1TFNIANIrF RI III fIIN(:i — ! _\X i SW-4 1 \/ ,9,° ?,20 7950 \ 1 3°\ 1 > ti 1 ° 2050 79,0 1 ?°sO 7 89 0 1 2030 2o,o 1 199° 1 �950 1850 - 1 1810 — 177 lmlit, � 1 7j6n � �,50 TOW too '�► �, �S� a FRENCH BROAD RIVER ♦� 19S0 V MW-16��MW-16D NOT NOT PRESENT PRESENT -------�-- ------------------ — - --�` PERMITTED FUTURE CELL 7 � i ACTIVE �� CELL 6 1957,73 1960 MW-1 MW-1D* 1956.53 �1950 LEGEND —1980 TOPOGRAPHIC CONTOUR — — — — — WASTE UNIT BOUNDARY FACILITY BOUNDARY MW-10 EXISTING GROUNDWATER MONITORING WELL �MW- 16 PERMITTED FUTURE GROUNDWATER MONITORING WELL EXISTING SURFACE WATER SW-2 MONITORING LOCATION * LD-1 LEAK DETECTOR * LD-7 PERMITTED FUTURE LEAK DETECTOR 0 M-3 EXISTING LANDFILL GAS MONITORING WELL \ O M-5 PERMITTED FUTURE LANDFILL GAS MONITORING WE REFERENCES: 1) SHEET NO. 1 GROUNDWATER AND METHANE MONITORING WELL EXISTING STRUCTURE MONITORED FOR LOCATIONS, CDM SMITH, PROJECT IN 6447-105257. FILE: SITEMAP ■ LANDFILL GAS 2014.DWG. M-8 2) SURFACE WATER LOCATIONS FROM SHEET NO. 1 GROUNDWATER 1950 POTENTIOMETRIC ELEVATION CONTOUR (FEET AND METHANE MONITORING WELL LOCATION MAP, CDM SMITH, MSL) CONTOUR INTERVAL = 10 FEET NOVEMBER 2012 PROJECT NO. 6447-93318. FILE: SITEMAP. DWG. 3) PHASE 6 C&D BOUNDARY PROVIDED BY MCGILL. _ GROUNDWATER FLOW DIRECTION 4) SHEET NO. OP-1 EXISTING CONDITIONS, CDM SMITH, PROJECT NO. 6447-97693. FILE: OP-1.DWG. * DEEP WELL NOT USED FOR CONTOURING PURPOSES 5) FIGURE NO. 3-1 WATER QUALITY MONITORING PLAN CELL 6 AREA, CDM, PROJECT NO. 6447, DATED NOVEMBER 2004. (AB) ABANDONED 6) SURVEY DATA FOR MW-17R, MW-17DR AND M-12R IN SCS REPORT DATED OCTOBER 13, 2020 ,16111*� LOCATION ACCURACY OF THE FEATURES SHOWN IS LIMITED BY THE REFERENCES THEMSELVES. 200 100 0 200 400 APPROXIMATE SCALE IN FEET REVISIONS No. DESCRIPTION BY DRAWN: RLB CHECKED: APPROVED: DATE: 5-13-21 CAD FILE: BCLF 9378-23WMT042321 JOB NO: J21-9378-23 is 1IM I BUNNELL BUNNELL ENGINEERING 6004 Ponders Court, Greenville, SC 29615 Phone; (864) 288-1265 Fax; (864) 288-4430 GROUNDWATER ELEVATION CONTOUR MAP-APRIL 23, 2021 BUNCOMBE COUNTY LANDFILL ALEXANDER, NORTH CAROLINA FIGURE N0. APPENDIX A FIELD SAMPLING LOGS PACE ANALYTICAL SERVICES, LLC. (aceAnalj6cald` PACE ANALYTICAL SERVICES, LLC 106 Vantage Point Drive - West Columbia, SC 29172 Telephone No. 803-791-9700 Fax No. 803-791-9111 www.pacelabs.com Number I -L EPI '_ S -3 Client Report to Contact Telephone No. / E-mail Quote No. Address Samplers Signature X Analysis (Attach list if more space is needed) Page of City. State Zip Code 7 Lot Bar Code (lab use only) Printed Name Project Name f. Project No. P.O. No. sl N 8. matrix No of Containersers by Preservative Type Sample ID Description (Containers for each ssfy�pfe maybe combined an one Mo.) Collection Date(s) Colection Time (MIfflary) it Remarks Cooler I.D. 7 tU r Turn Around Time Required (Pner lab approval required larevedded TAT) E Standard - Rush (Specify) Sample Disposal 0 Return to Client DDisposal tyLab Possible Hazard Identification ENon-Hazard OFlanimable OSkin Irritant OPoison DUnknown OC Require -ants (Specify) 1. Relinquished by' Date Time Y. Received by Date Time 2. Relinquished by Date Time 2 Received by Date Time 3. Relinquished by Date Time 3. Received by Date Time 4. Relinquished by Date Time 4. Laboratory received by Date Time Note: All samples are retained for four weeks from receipt unless other arrangements are made. LAB USE ONLY Received on ice (Circle) Yes No Ice Pack Receipt Tenna_"C Temp Blank El Y EJ N DISTRIBUTION: WHITE & YELLOW -Return to laboratory with Sample(s): PINK-Pieta/Client Copy Document Number. ME003N2-01 5?eAnalyfical- PACE ANALYTICAL SERVICES, LLC 106 Vantage Point Drive - West Columbia, SC 29172 Telephone No. 803-791-9700 Fax No. 803-791-9111 www.pacelabs.com Number I 1 0 '� Client Report to Contact Telephone No. / E-mail Quote No. Address Sampler's -Signature Ana"is (Attach list if more space is needed) Page of City State Zip Code Lot # Bar Code Printed Name ' 7 (lab use only) Project Name Project No. P.O. No. Matrix No of Cornsin by Preservative "Zype Sample ID Description cosectlon Collection T'Me (Container; foreabli simple mybecombinedon ariefine.) Date(s) Wflnarv) a < �w�- Remarks/Cooler La x n . . H Tum Around Time Requited (Prior lab approval required foreWsifted TAT) SampleDIsposal Possible Hazard Ideriblimlion QC Requirements (Specify) E -Standard ` Rush (Specify) J Return toClient G Disposal tyLab 11 Non -Hoard F1 Flammable CI Skin Irritant P Poison IJ Unknown 1. Relinquished by. Date T11 1. Received by Date Time v- 2. Relinquished by Date Tons, 2. Received by Date Time 3. Relinquished by Date Time 3. Received by Date Time 4. Relinquished by Date Time 4. Laboratory received by Date Time Note: All samples are retained for four weeks from receipt LAB USE ONLY T Temp Blank ❑ Y [j N unless other arrangements are made. Received on ice (Circle) Yes No Ice Pack Receiptrpt Temp DISTRIBUTION. WHITE & YELLOW -Return to laboratory with Samplia(s), PINK-Reld,01hant Copy Document Number. ME0031,12-01 ZeAnaljdicale PACE ANALYTICAL SERVICES, LLC 106 Vantage Point Drive - West Columbia, SC 29172 Telephone No. 803-791-9700 Fax No. 803-791-9111 www.pacelabs.com Number 01 Client Report to Contact Telephone No. f E-mail Quote No. Address Sampler's Signalling-, Analysis (Attach list if more space is needed) 1 '7 Page --of City State Zp Code Lot # Bar Code Printed Name (lab use only) Project Name + c. Project No. P.O. No. Matrix No of Containers by Preservative Type v Sample ID Description Collection Cailledion rime 17 7RIeds Cooler La (Commineis threach simple maybe combinedon online.) oiitels) (Military) n: al r ir it it Turn Around Time Required (Print lab approval required for evedfled TAT) Sample Disposal Possible Hazard identification QC Requirements (Specify) 1] Standard r , I Rush.fSpeclify) --, I F1 Return to Client I Disposal by Lab D Non -Hazard 0 Flammable FJ Sklin Irritant F1 El Poison ❑Unknown 1. Relinquished by', Date Time 1. Received by Date Time 2. Relinquished by Date Time 2. Received by Date Time 3. Relinquished by Date Time 3- Received by Date Time 4. Relinquished by Date Time 4. Laboratory received by Date Time I Note: All samples are retained for four weeks from receipt LAB USE ONLY Tamp Blank 'Y 13 N I unless other arrangements are made. Received on ice (Circle) Yes No Ice Pack Receipt Temp. _°C DISTRIBUTION: WHITE & YELLOW -Return to laboratory with Sample(s), PINK-Field/Client Copy Document Number. ME003N2-01 ace Analytical@ PACE ANALYTICAL SERVICES, LLC 106 Vantage Point Drive - West Columbia, SC 29172 Telephone No. 803-791-9700 FaxNo.803-791-9111 www.paGelabs.com Number 1-1' 8-91 Client Report to Contact Telephone No. / E-mail Owls No. �7) L Address Sampler's Signature Analysis (Attach list Amore space is needed) X Page of City State Zip Code Lot#BarCode Printed Name y (lab use mly) Project Name P. Project No. -Z P.O. No. matrix No of Consmeri by Preservative Type Q v Sample ID Description Catterion 0011est1. Time sa RemarkslCorilerLD (Containers; for each sample maybe combined on one fine.) Date (S) (Military) z Turn Around Time Required (Prior lab approval required for eiWited TAT.) Sample Disposal Possible Hazard Identification QC Requirements (Specify) 5- Standard _� Rush (Spinuily) El Return to Client El Disposal by Lab E]Non-Hazard ElFlammable LISkin irrCant OPoisan ElUmmown 1. Relinquished by Date 7 Time rt I- Received by Date Time 6- 2. Relinquished by Date Time 2. Received by Date Time a Relinquished by Date Time 3. Received by Date Time 4. Relinquished by Date Time 4. Laboratory received by Date Time Note: All samples are retained for four weeks from receipt LAB USE ONLY Temp Blank/Y D N I unless other arrangements are made. � Received on ice (Circle) Yes No Ice Pack Receipt Temp.—C I- — DISTRIBUTION." WHITE & YELLOW -Return to laboratory with Sample(s); PINK-Feld/client Copy Document Number-, ME003N2-01 BrhnH/YNCaI g ]::Document Document Name: Field date Sheet Page: 1 f a Date Issued: March 8, 2019 o - Number: F-CAR-FLD-001-rev.03 Issuing Authority: Pate Huntersville Quality Office . G Name and Affiliation (Sampler(s):_ M6 l QCIC Name and Affiliation (Inspector): N6 Well Information Well ID• /141 WellLocked: u Well Diameter: a Construction: Total Well Depth: (it �T,-7(o ft Static Water Level: (0 J - 5 `J--ft Height of Water Column: Data Sheet Review: Date: o tl n-x NO / Fluslunount ) Steel) Multi Factor*: a / 63 p �r(Radius/12)2 x 3.14 7.48]. Casing Volume: 0, 7 gallons Ca1.3 Volumes: gallons Pump Intake: G 5 r a ft 14 Purge Information p / ` Date Purged/ X"' e2) Start: i�'� S Finish: 1330 Purge Rate: In M�- mo Purging Method:Yi /"/1917Soor7 Total Volume Purged: (gallons, tl 'L) Sampling Information _ Date Collected: Y /00/ c2_f Time Collected: 133 {� (am® 11 Sampling Equipment Used: 1N2 1"1✓"7'00'g Instrument ID:_�#bac, ruvv%�(V s Bottle Type Preservatimn Analysis Required 3- q0 mL Glass H C 1 App-7 V'oc, 07950 ML U kAr. (.idlfa s CA lbride. 50u, Alkstff�i- f 7f7S. Field Measuremerits/Observations Sample Temp (eC): a3` 7 Time: �J357 Turbidity (ntu): a'� Time: Digs Oxy (mg/L): (D, 7 Time: Fe 2+ mg/L: Timer Specific Cond. (uS): $S 3 Time: Res. Cl (mg/L)/(µg/L): Time:. Sample pH (sx.): Cy, Sq Time: Odor: NP, Time: ReDox (mV): (� t Time: Appearance: df kr Time: ReDox (EH value):YSI ProPlus +200mV 3110 9 Other: Time: General/Weather Observations: Sampler Signature Stabilization Test '-o 2 6e o2 Time Temp. Dies Oxy. Spec. Cond. pH (s.u.) ReDox Turbidity Volume removed Water Other Purged (C) (mg/L) (us) (mV) (ntu) (gallons/ s L level (ft) (30o a1-c) ?_ a ($y .c (0- S (f 7133 Ix'46 evi 'D . O a I-64•6 S 8H 2 �c�o L�.B . 13C�5 )I• ( T ( 1154,41(0.t ,C) I S,® 1 &7 13�p a,3 ,6 I 1. G.5- 73..B 1 'i 165a &3.S5 00 [p•� J&� `i-1a 2lvo 103.zro Document Name: Document Issued: March 8,: 2019 1 / rlceAaalyica/' Field Data Sheet Page dof Qi Document Number: Issuemg Authority: i F-CAR-Fl,D-001.rev.03 Pace Huntersville Quality Office Client; Location: Wondtw� Project;. BLkACD11-6- Colk(d LF Well ID: Mai — Reviewed Date and By: Oka Stabilization Test 1Nrail Diameter Multiplication Factor" 1 , 0.0408 1.2 0.0918 1.625 0.1080 2 0.1630 3 0.3670 4 0.6330 6 1.4630 s 2.6100 Time Purged g Temp. u (C) DissOxy. (mg/L} Spec. Cond. (US) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume Removed (gallons/mis/L) circle one Water level (ft) Other l3ao 93.0 . (O 165,57 s o$- a-- 3..0 asses 3.gs 1325- 03. 1 q 1lss- S lor, 9 '3. goo (a3.85 I330 23,(o SS•0 (0-t 1 110. a,3 3y50 G3, zl5 C8A'llafyflEal- Document Name: Field data Sheet Date Issued: March 8, 2019 Page: 1 ofLa Document Number. P•CAR-FLD-001-rev.03 - Issuing Authority; Pace Huntersvilie Quality, O(fice . Field Data Sheet &x-w LF 1�^d Via/ Name and Affiliation (Sampler(s):_ QN& `("c-- Name and Affiliation (Inspector): IVA Well Information WellM: M — I% Well Diameter: c? " Total Well Depth: 7a 5% ft Static Water Level: 6s;or'ft Height of Water Column: ft Well Locked: Construction: Data Sheet Review: Date; oKla$'a( / Flushmount ) stainless Steel) Multi Factor*: / f7J l"(Radius/12)2 x 3.14 is 7.48]. Casing Volume: 5,3 gallons. Cal. 3 Volumes: ' ) 5 - 9 gallons Pump Intake: t ' Iq 5-. 0 ft Purge Information ' 1 Date Purged: y / �(o ./ .o?( Start: il�00 Finish: W 10 Purge Rate: EM41 Mon Purging Method hmo MQW &im Total Volume Purged: 1700 (gallons/OL) Samvlina Information Date Collecfed:j_/&/ a Time Collected: 1 0) 1 (aq m) Sampling Equipment Used: l]/l&z56orl Instrument ID: Ysj' P(0r�M O--Wk 196 Bottle Type Preservation Analysis Required 3- 40mL Aet VOC s Ta•}�Are-Pum, I- D50mL_ 4103 Apex ft-w$ C75— ) ML I./FlOi�5, �In1 (ae� 77IItQ)illi .i%b�j Field Measurements/Observations Sample Temp (°C): . OO Time: Turbidity (ntu): 3, q Time: Digs Oxy (mg/L): k I Time: Fe 2+ mg/L: Time: Specific Cond. (uS): Q JAL(, G Time: Res. Cl (mg/L)/(µg/L): `= Thne:. Sample pH (s.u.): 7- Time: _ Odor: N� T' e: ReDox (mV): �� Time: Appearance: Clear o1 b T es ReDox (EH value):YSI ProPlus +200mV Other: Time: General/Weather Observations: . (srfrm cloudy/rrainy) Temp.(°F) Wind&:�5—(mph) Sampler Signature: Date: I /0) a Stabilization Test Time Temp. u Diss Oxy. Spec. Cond. pH (s.u.) ReDox Turbidity oume removed Water Other Purged, (C) (mg/L) (us) (mV) (ntu) (gallons 5m / level (ft) L t)s- Ism 0, (o affl + `6. 0 &7 al >'7 SCDS • 91 50av as V51 QAP a�n•1 g,o GT3 dq, Ds s.91 1(..'5 0.(9 fo, , d7,,) 1 5'100 1, L26.)I l Id ► .N 0,s v. 11 'T9 3, & loo,`) I lace-,$ Document Name: Document Issued: March 8; 2019 Field Data Sheet Page9of gZ E�ceAnatyticr�l' Document Number: Issueing Authority ( F-CAR-Ff.D-00l.rev.03 Pace Huntersville Quality Office Client: SLE Location: Wood-f fh . PC t� t� Project; Idncom�r �r lVC(Ai Lr Well ID: /" tW -- Reviewed Date and By: CJu a��a-1 Stabilization Test tV'ell Diameter Multiplication Factor'° 1 0.0408 1.2 0.0913 1.623 O.10S0 2 0.1630 3 0.3670 4 0.6530 6 1.4680 8 2.6100 Time .' • • • '-�• Turbidit JI • • •a circle one Document Name Geld'data Sheet Date Issued:. March &, 20191 acCA1h?iytiCaF Pape: 1 of Document Number P-CAR-PI..q-001-rey.i39 Issuing Authority: Pace Huntersville Quality I Office Field Data Sheet Client;�LE-P�.._nc a, Location:/iS�unllo�/ Name and Affiliation (Sampler(s):S51-Vc« Anai� cw� Name and Affiliation (Inspector'): nsl l� Well Information Well ID: Mw _-x Well Diameter: Total Well Depth: T3 , _ 6 ft Static Water Level: �4,0@ ft Height of Water Column:15 3 L ft Well Locked: Data Sheet Review: Date: l(-a$-al Construction: /Steel/Stainless Steel) Multi Factor*: c06 1*(Radius/12)2xa14x7.gal Casing Volume: 'c)S Q gallons Cal. 3 Volumes: gallons BY: BAC, PuQmft Puree Information Date Purged: ccc1 / 1 f l Start: l a'O Flaush:) I0 Purge Rate:) aQ MLI c" rl Purging Method ?_cAs -o h i ( � ,L f Total Volume Purged: \ 7-0C)Q (gallons m L) Sampling Information Date Collected:_( / a l Time Collected; LF A pro) 'DtOa ( Sampling Equipment Used: 1�Er5 (Hc psA j nstrumentID:�S ��in )kkOaQ6�mtCt�fi�w 3Q� Bottle Type Preservation Analysis Required I'a�oMl, �lrti5. �IvCla __ t�C /ket�= t�atiL� .. �i LtQcnl vtrnt5 11C.0 niC A.npLJ0C Field Measurements/Observations Sample Temp (°C). 1' � I� �Tinlec ) l (� Turbidity (ntu) C l .� Time: 1' t l S Diss Oxy (mg/L): O Time: I `1 (V Fe 2+ mg/L — Tune: — Specific Cond. (uS): LA Time: Res. Cl (mg/L)/(ltg/L): Time: Sample pH (s.u.)a b ' 1 . Time: I l (� Odor: m. _.j LA ReDox (mV): 4, Time: Appearance: Gem Time: I K t Y_ ReDox (EH value):YSI ProPlus +2bpmV Other: " Time: General/Weather Observations: r� (uru1 /cloudy/rainy) Temp. {°P) tNind-_—(mph)- Sampler Signature Stabilization Test Time Purged Temp. ° { C) Diss Oxy. (mgJL) Spec' Cond. (US) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons lls L Water level (ft) Other a 1L, Q'z Wiz, 6.a �t c•s b 8: �R 1K, 98, 6. t1�•� 1L16.a {" 1 IM40 K•a 1 0.6 411. , 4CIQ 7.L13 I a 4an. 6• a, ti 3 -_ r7CG',4fTr'7ij/i%Cr1% Document Name: Field Data Sheet. Mcunrent Issued: March N, 2019. Page -of a Document Numbor: Issucing Authority:. F-CAR-FLD 001.rev.03. Pace Huntersville Quality Office'. Client: 1 E - jr) � r- . Cc, Location: A-z>lw,,, (, Nc-- Project? &nr.. C. Aar._e. LE Al?I'ao21 MUD: Reviewed Date and By: ri'ag-N l3R(> Stabilization Test (Nall Diameter Multiplication Factor" 1 _.....-_ 0.0403 1.2 0.0918 1.625 0.1080 2 0.16:30 3 0.3670 4 0.6530 6 1.4680 s 2.6100 �. , circle one • - � uI1 - NEWTITI • �� Document Name Field data Sheet Date Issued: March S, 2019 8Ce/lnplyl%Qal' Page: 1 of t)pcument Number F CAR-Gl..l7-0Ol rev:03 Issuiul;Authority: Pace Huntersville Quality _ Office Field Data Sheet LgApr,(ao'Ak Name and Affiliation (Sampler(s): 5R - a (—* f Ml� , Ce \ Name and Affiliation (Inspector): tJ1 A Well Information Well ID: Well Diameter: Total Well Depth; 5-3.0 S It Static Water Level: X - LA aL e2ft Height of Water Colum t:tA— b ft Well Locked: Construction: Data Sheet Review: Date: L- aa-ai By: 64e- Steel) Multi FFactoe: 13' Wf r(Rad us/12)2 x 3.I4 x 7.A&j Casing Volume; gallons gallons Cal.3 Volumes: a� gallons Pump Intake: , Q O ft Purge' Information Date Purged: QL / a� % .k Start: t "-,10 Finish; Purge Rake: O L) M` n Purging Method:_ 17( rSVcAA L Vamp Total Volume Purged: ``i QQ (gallons/ n L) Sampling Information Date Collected: _/'k-�/ 'a -I Tune Collected; (am f to Sampling Equipment Used: �!-a�Instrument ID: �l 3� 0 n(nny i' na06 (ht c-coTp 1 30 Bottle Type Field Measurements/Observations Preservation Analysis Required 2C-App2vaC Sample Temp (eC): 3 Time: � ` t `t ___Turbidity (ntu): Q A Time: Diss Oxy (mg/L): 3.0 Time: k `140 Fe 2+ mg/L: _ Time: Specific Cond. (uS): a66,11 Time: ILA tO Res. CI(mg/L)&g/L): ' Time: — Sample pH (s.u.): ,3 .___.......... Time:. 14-tO Odor:_.,.. ./ _ D __._. Time:....1 ReDox (mV): --Ib -q Time: I A L10 Appearance: GIQ'\(- Time: 1,11 110 ReDox (EH value):YSI ProPIUs +200mV Zab Other: Time: General/Weather Observations; Wind4 (Mph) Sampler Signature Stabilization Test Time Purged Temp. CC) (C) Diss Oxy, (mg/L) Spec (us) pH (s:u.} ReDox {ntV) Turbidity (ntu) Volume. removed (gallon nn / L Water level (ft) Other boo J '6.66. b :3 16.E 1ti 3 3.l 6 , aa. 6. 6 • a l G.Q7 &,1&JdN.Ja( Dale Issueuavovenw=. �•• ... Document Name: Field data Sheet Page Iof .� Issuing Authority. Pace HunilletersvQuality D°cument Numbex: F-CAR-FLD-001-rev.02 office p Fiel/dd Data Sheet d ✓V',(ym," i rvc.. Project#'. `PVC JL � Location: Client: � Name and Affiliation (Sampler(s): Field Data Sheet Review: Name and Affiliation (Inspector): Date: () I _ , vv Well Information Well ID: M V/ ' Well Locked: / NO) Well Diameter. ( Construction: { Ateel/Stainless Steel) Total Well De the 1 5, 9 Ft Multi Factor*:_ %b3 [*(Radius/12)2x3a9x7,48] Static Water Level: S / 69 t ft Casing Volume: 1 ' gallons Height of Water Column: ft Cal. 3 Volumes: ) .R s6 D 1 gallons ' Pump Intake: ff- J ft Puree Itiformatio'm Date Purged:_ / / Start: f 0 3 0 Finish: Purge Rate:. �/' Purging Method: (n ear,x PYJ,,� Total Volume Purged: L{ L�'Q 0(g�o� '� Sampling information Date Collected: / d6 / s / Time Collected: 3 J a/pm) '` nR.v �c�S sGtF7G Sampling Equipment Used: 41B 6 0,— All Instrument ID: y 1 Bottle Type Preservation Analysis Required MnJ Field Measurements Observations / �( I Sample Temp (°C): � 1 Time: l 1 j Turbidity (ntu): 2 f IJ Time: / 3 L fb'/ k _ Diss Oxy (mg/L) Cv r Tone: I � i J Fe 2+ mg/L: rme: Specific Cond. (uS): 7' ` Time: I f Res. Cl (mg/L)/(µg/L): ime: S , 1J 3 Odor: Time: Sample pH (s.u.): > Time: ReDox (mV): �Lty Time: � � J Appearance: U a ^ Tmre: __.. ReDox(EHvalue):YSIP,oPluS+200mv 9tf; J Other: General/Weather Temp. -$ d ("F) Wind-0 --o— (mph) Sampler Signature: � l Date: V ,IIA-0 � / y fry 1 r'Y&� Stabilization Test Temp. Spec. Cond. pH(s.u.) ReDox Turbidity Volume removed Water Other level (ft) Time Purged (°C) (m /L)Oxy (mg/L) (uSl (MV) (n ) (gal onns mis OT'J jy.V �. J 7 •l.� -3l',�/ W4'li ( ��� Document Name: Document Issued: November 27, 2018 �+ Field Data Sheet PageZof 'a -Document Number: Issueing Authority: _ 11-CAR-PLD-00I.rev.02 Pace Huntersvilte Quality Office Client: �/Q�L Location: 6VWC Project: e Vr- L � Well ID: 4n/A • / '' 7 RAJ - Reviewed Date and -- Stabilization Best .. ' irgien E1tsme&Z a1` hs3.+aemx+.�a:tmc , i. INS 1.? CIMB 1,625 ii`.1tia U' D 1v,�tT 9. V 15 0i 4 AY-60 5, 1.46 :,l Time Purged Te.m p (°C) DissOx . Y (mg/L) -Spec. Cond. (US) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume Removed (gallons/mis) circle one water level (�) - Other II1�' it 6,3� 2LI zr f> Date Issued: November 27, 2018 Document Name: Field data Sheet Page: 1 oft �,. dCB10 t foa( Issuing Authority: Pace IIuntersville Quality Document Number: F-CAR-FLD-001-rev.02 Office Field Data Sheet r Lr -7/a'vti/ Name and Affiliation (Sampler(s): /bC S P17 ;D:ate: Sheet Review: Name and Affiliation (Inspector):- By: Well Information laIWell ID: %�✓ Well Locked:NO) Well Diameter: Construction: (&/Steel/Stainless Steel) Total Well Depth: ft Multi Factor*:[*(Radius/12)2x3.14x7461 Static Water Level: �` S ft Casing Volume: / 9 gallons Height of Water Column:_ S � lft Cal. 3 Volumes: )S gallons Pump Intake: % 0, S fS ft Purge Information _ Date Purged: `� / / / Start: T � ° Finish: (� `f : Purge Rate: too"" ti Purging Method: �e 2,u /f% i- Total Volume Purged: (gallorll(F` Sampling Information Date Collected:_/ �y h / Time Collected: I ��P � (a / m Sampling Equipment Used: 1i —Instrument ID: Y S % &0 Bottle Tyke 4 PLq, 3 Viy�) Preservation C L' Analysis Required �J lt� �i�F9�r Field Measurements/Observations 'r, Y' W' l Sample Temp (eq: Time: / I -F Turbidity (ntu): �' ?� Time: 1A Diss bzy (mg/L): I' `•� � Time: �A1 Fe 2+ mg/L: Ime: _ Specific Cond. (uS): aSo, Time: Res. Cl (mg/L)/(µg/L Sample pH (s.u.): � , O / Time: / 1 So Odor: /✓°..e Time: ReDox (mV): Time: 1 L a` ' Appearance: ReDox(EH value):YSIProPlus+200mV >,v' Other: rme: General/Weather Observations: — S ✓,. y sunn /cloudy/rainy) Temp.60 CF) Wind—D-j�—(mph) Sampler Signaturd St ir•1 tionTest a a rza Time Temp. D ss Oxy. Spec. Cone,S)H P ) ReDox ( s.u. Turbidity Volume removed Water Other Purged (C) (mg/L) (mV) (nta) (gremo allons mis level (ft) a>o (s.� /•'S aso.� Ito-K `'d.0 rd./�� coop lt.x� >To IiLr�L" )JE)0D ryes y.�1 I,Y> ISO, C,q� > fo If.2 l,js dSt.� r •ero., ,>e,�+'uvlYer gal" Document Name: Field data Sheet Document Number: F-CAR-FLD-001-xev.02 Field Data Sheet Tncatinn� ✓� c Q 11,44 M. Name and Affiliation (Sampler(s): /f'1 P 1 1� J L Name and Affiliation (Inspector):_ Well information Well ID: W ' 4-b WellLocked: Well Diameter: 21 Construction: Total Well Depth: S 9� It StariicWater Level: f h • 6 it. Height of Water Column'' ' i —If Field Data Sheet Review: Date: NO) jr,7Steel/Stainless Steel) Multi Factor: r /6i [(Radius/12)2x3.14x7.481 Casing Volume: �, i�L' i gallons Cal.3 Volumes: a 2, IS E sggallons - Pump Intake: -5 A- 'A' It Office ( i( ✓e L11- Purge Information Date Purged: L(- 1 t / � 11 _Start: f 5 0 L) Finish: /31,) PuxgeRate: Purging Method:. toc+-1r4, e. Total Volume Purged: 11000 (gallolis/(S) [b ) Sam�lan� ireforsnation Date Collected: LC / ��/ 3 1 Time Collected: / 3 3" Sampling Equipment Used al T rc Instrument ID: �S� `� �G Pa- �' ` Bottle Type Preservation Analysis RequiTed �Vt F{r_S �I GIi Jib t�72<4 .ter r Field Measurements/Observations t1q'j1-L4, 5J� 7 ai 3 f- Sample Temp ( q: %Time: Turbidity (ntu): i Time: 13 Diss Oxy (mg/L): d S `f Time: a3 ° Fe 2+ mg/L: T u ei Specific Cond. (uS): 31�, t� Time: / 33 f Res. CI (mg/L)/(µg/L): e: Sample pH (s.u.): LO Time: JS3, Odor: Time: _. .- _ ReDox(mV): ��1 L Time: Jt'j° Appearance: Tme: ReDox (EH value):YSI ProPlus+200mV 2 "1 I • L Other: Tim GeneraVWeathe3rObservations• SIN✓" (4g/cloudy/rainy) Temp.?7a CF) Wind-0- (mph) Sampler Signature: Y �' L ( Date: tf'-' i 6 " } 1 Std"Mkd YUU i CM me4Teinpiss Oxy. SpecaReDoxTurbidity Cond. pH (s.u.)removed Volume WaterT level (ft)2,7 OtherPurged(mg/L) (uS) allonsJra�15) - '�18.1 6.� a,bra �1,70F)ve�.%5 319,0 Ss IS>�©6 36,3 6,�700L) a �6,s 531c �, ~7`F� �, s 0 A, ao �3$O_ TT,- 0.S3 6, 7�,� 7,J2 %oo� IVdI Document Name: Field data Sheet Date Issued: March 8, 2019 4/ulfyFlcaJ' Page: 1 of a, Document Number: F-CAR-FLD-001-cev.03 Issuing Authority: Pace Huntersviffe Quality. t . Office Name and Affiliation Name and Affiliation (Inspector): N0 Well Information Well ID: Mw - J5 Well Diameter: Total Well Depth: 5�• J�3 ft Static Water Level: �3• �l7 ft Height of Water Column: (9 °j(x ft t Well Locked: Data Sheet Review: Date: NO / Flushmount ) Construction: (Steel/Stainless Steel) Multi Factor*: r(Radius/12)2 x 3.14 x 7.48). Casing Volume: 3- , % gallons Cal. 3 Volumes: /,.-3 gallons Pump Intake: �- go ft Ahw �FAP,Y1ao4 'J' Purge Information I� Date Purged: q / 24 / al Start : I T O Finish: (6;0 Purge Rate: ( oO m L°M f Purging Method: da MVa5,z,,,,, Total Volume Purged: < - ��L (gallon mis L) Sampling Information �� Date Collected: / ��/ �1 Time Collected: (am m) Sampling Equipment Used: ME,5 a MCV750*t, Instrument ID: 3X gM 0 0ft'1i c (a � �0 5— Bottle Type 37 gOIkL 61a53. 1— a50ML Q112SJrC Preservation Rc I HNO3 Analysis Required z V0 Field Measurements/Observations Sample Temp (aC): �a' .3 Time: 1Das Turbidity (ntu): '3, S Time: �a Diss Oxy (mg/L):_0, _ Time: Fe 2+ mg/L: Time: Specific Cond. (uS): 036'3 Time: Res. CI (mg/L)/(µg/L): "Time:. Sample pH (s.u.): te. a . Time: Odor: N 0 Tixne: ReDox (mV): Time: Appearance: C;r Time: ReDox (EH value):YSI ProPlus +200mV '3 L%* C6 Other: Time: General/Weather Observations: �(sC'nn�/cloudy/rainy) Temp. c & (°F) Wind 5 -/O (mph) Sampler Signature Stabilization Test Time Temp. Diss Oxy. Spec. CondS) PH (s:u.) ReDox Turbidity o ume removed Water Other Purged CC) (mg/L) (mV) (ntu) (gallons/ ls' level (ft) 515 29'5- 0: -�a5,9 (�,a 3 - t- 3y,G IGd 'pL& ,5 i 0,7 DQS , (D, a 111, 37, a CO 3q-rol 1 a© 0• i . D 1 9 ig, 3 top y 4 >, 153C) I do 0,3 1 aa5•6 I Co. ;it I JoS.0 S 3aCC) 35-448 151-o a3.y (o •o (o.a I t fo, 3 3S•3c, Mm Wool �zceAfkllytical Document Name: Field Data Sheet Document Issued: Match S, 2a19 Pageo of fi Document Number: Issueing Authority; t F CAR-FI.D4M re.v.03 Pace Huntersvitle Quality Office. Client: 6L E Location:Wm&) uc }� �-- 1t,- Project; IJf/InCoM1C 1� Co. Akki LF /Ift Well ID: MW '5- Reviewed Date and ByI�% Stabilization Test lVell-Diameter Multiplication Factor" 1 0.0403 1.2 0.0419 1.625 0.1030 2 0.1630 3 0.3670 4 0.6530 6 1,4680 3 2.6100 . �. • �eceAnaljfta' t Document Name: Field data Sheet Date Issued: March 8, 2019 - - Page: 1 of j .Document plumber. F-CAR-FLD-0o1-rev.03 Issuing Authority: Pace Hunteraville Quality Office Name and Affiliation Name and Affiliation We11 Information Well ID: /" l bi - S� Well Diameter: a - Total Well Depth: 8),4 6 ft Static Water Level: 35, 1 ft Height of Water Column: 46`3 ( ft #: bycorn6c 6, New LF ao a/ - ram- (Field Data Sheet Review: Date: ()L�I-� Well Locked: CZ NO / Flushmount ) Construction: (V' C' Steel/Stainless Steel) Multi Factor*: s 16 3 (*(Radius/12)2 x 3.14 z 7.481. Casing Volume: 7, 5-- gallons Cal. 3 Volumes: 'oDoZ S gallons Pump Intake: -%(eft By: Purge Information Date Purged:/ Start: Finish: IODC) Purge Rate: ML M(/I Purging MethoMego M0/')--'CCqottIVolume'Purged: COO (gallons�QL) Samuline Information Date Collected: Y /" a 1 Time Collected: dS (am pm) Sampling Equipment Used: Mea0. M� Ch5ca\ Instrument ID:- Y5Z g2 u Bottle Type Preservatim'n Analysis Required 3- 44OML G6S,5 k0 AeQ-T7 yoc I - ,;fit"-�Um� plas✓rz Nr\I0� 1��p2' Me�u(5 Field Measurements/Observations Sample Temp (°C): (0• Time: 10 oL5 Turbidity (ntu): Time: IO Dias Oxy (mg/L): O� Time: Fe 2+ mg/L: Time: Specific Cond. (uS): a3, Time: Res. Cl (mg/L)/(µg/L): �Time:. Sample pH (s.u.): Time: Odor: K> Time: ReDox(mV):_ ��•� Time: Appearance: GIe4r Time: ReDox (EH value):YSI ProPlus +200mV -�59. O Other: Time: GeneraVWeather Observations: Wind 0-5- (mph) Sampler Signature: 2&14 292� Date: Stabilization Test Time Temp. Dias Oxy. Spec. pH (s'II') ReDox Turbidity Volume removed Water Other Purged (°C) (mg/L) fond' (mV) (ntu) (gallons is level (ft) L oas l5 7 1. c) (S . a 5, + 1 500 3 ; 70 M� P� Is.7 I -co 1.7 3 156-3 .�` LA 5Cp 3s.7o o6 IL O.9 I -oat), ;z 1 15 . `9 a I I 00b 1 35.70 I ,co 0- asa.o ,a 5-7,c� 0I5 3S-7o load .0 O, Dag-,3(gz 5 1 Is , 'i-1 I QQ0 I 3S-70 OCBArn7tytical { Document Name: Field data Sheet Date Issued: March 8; 2019. Page: 10 f l Document Number P-CAR-PL,[�-001-cev.Q3 lssurrig. Authority: Face }ftnttersvltle Quahty Office LF aoa/ Name and Affiliation Name and Affiliation (Inspector): 06 Well Information Well ID: MW -G Well Locked: Well Diameter: Total Well Depth: 50's / It Static Water Level: aq 37 Ft Height of Water Column:t101/ It Data Sheet Review: Date: aLl � n-lat NO Construction: il!D/Steel/Stainless Steel) Multi Factor*: . 16:� (*(Radius/12)2 x 314 x 7,481 Casing Volume: .3p gallons Cal. 3 Volumes; la. / gallons Pump Intake- _t It M. PUW Information / DatePurgedi—LI—/—,�7/ -2( Start: M5 Finish: (130 Purge Rate: 106MLA (n Purging Methodrk::�x75• 04±iG_� Total Volume Purged: 500 (gallonsal.') I,) Samvline Information Date Collected: Ll_/Z2/ Time Collected: 3 =-�pm) //_... ` Sampling Equipment Used: Pt?k`i5tnj�i< PLAMD InstrumentID: yS�Bc$µ5 1o7/Mxro/`nGJa<Is�S Battle Type Preservation Analysis Required �{0N(- t4d i - a o rvtc HAP9 A& _ Sample Temp (aC): Turbidity (ntu) a. ° Time: k 3 J Diss Oxy (mg/L): 07.5 'Time: Fe 2+ mg/Li Thne: SpecificCond: (uS): L %.S T'inie: Res. Cl (mg/L)/(µg/L): 'rime: Sample laH(sat.): (o.�Titne:. Odor:�_____[J ReDox (mV): Time: Appearance: OC(0.-r rime:_ ReDox (EH value);YSI ProPius +200mV Other: ITime: General/Weather Wind 0-5- (mph) Sampler Signature Stabilization Test Spec. Volume Time Temp. Diss Oxy. Cond. pH (s.u.) ReDox Turbidity removed Water Other Purged (eC) (mgfL) (us) (mV) (ntu) (gallons/ tl level (ft) L (g, o a.B 50O.c�6 Wk! 1y6. ' S y.l 000 (08 GeAn,Tlyfiaal Document Name: Field data Sheet Date Issued: March 81 2019 Page:. 1 of Document Number P-CAR-FLD-001-rev.0$ hisuing Authority: Pace Huntecsvil]e Quality Office t tr adai Name and Affiliation (Sampler(s): PY& Nance and Affiliation (Inspector):, 40 Well Information Well ID: MW _7 Well Diameter:. a" Total Well Depth: �$°5� ft Static Water Level: WO,�� ft Height of Water Column:17'.(00 ft Well Locked: Data Sheet Review: Date: Q(-k� al �21 Construction: PVll/Steel/Stainless Steel) Multi Factor*: , 6/(3 I (Radius/12)2 x 3.1h x 7A81 Casing Volume: �io7 gallons Cal.3 Volumes: o• 7 gallons Pump Intake: 55 5- It Purge Information % Date Purge& q a7 / at Start: cil 15 Finish:, IaLiP PurgeRate: to MLrMf(\ Purging Method:_ "�I0. %lonstsan Total Volume Purged: a60 (gallons m1 L) Sampling information Date Collected: i / a2/aL_ Tune Collected:_( � __ ( am P m � -. Sampling Equipment Used: I RA Mgf 5bon Instrument ID: 1 517 (u S �7Aktn Bottle Type 3-q,DrvIL CT(vss — aS>M[, P[asfif Preservation Hu NNo� Analy/ssis/Required V(7..,................ ...... ....___._. Aws Mel/ Field Measurements/Observations ` _ Sample Temp (°C):, �)•� Tiine: ldLi Turbidity �•� Time: ,f Diss Oxy (mg/L): ©• a Time: —1_ Fe 2+ mg/L: Time: i Specific Cond. (uS): Time 11 Sample H (s.u.): , k0' __._..._ -Time: ReDox (mV): —I -;L Time: ReDox (EH value):YSI ProPlus +200n1V_ General/Weather Observations: Sampler Signature:_ �ifE9 Stabilization Test Odor:_ _. Appearance: Clear Time:_ Other: Time: IN Wind O-'S (mph) Spec' Volume Time Purged Temp.Diss (eC) Ozy. (tog/L) Cond. n . pH (s.u•) ReDox (mV) Turbidity (ntu) removed (gallons0r Water level (ft) Other L ao I .7 OS- 6 -69•3 CO W- zo 1 0"30 3 —%S.O $. ( �- I Da@ a_ 3 1. -114•� , ►a`lu at"A 0a d i3`7 (,o, `\ -IoG,b 5-,0 3400 q3-cd- Document NamField date Sheet Date issued: March 8, 2019e: C@+4/laly!lEal•- - page: 1 of Number. F-CAR-FLD-001-rev.03 Issuing Authority: Pace Huntersville Quality. l 1 .Document Office Field Data Sheet c0. r....... Al Name and Affiliation (Sampler(s): Ski -1�ac e An .l, k cra,( Naute and Affiliation (Inspector): n) I A Well Information WellID: f A(,J Well Diameter: a u Total Well Depth: Static Water Level: Height of Water Column:.!:!", 5LA ft Well Locked: Construction: L€ /i-Prr1'doa) Field Data Sheet Review: Date: By:�2Cs / NO / Flushmount ) '/Steel/Stainless Steel) Multi Factor": U � 163 [•(Radius/12)2 x 3.14 is 7.481. Casing Volume: �A , 36 gallons. Cal. 3 Volumes: �1''F� gallons Pump Intake: � n ' QQ ft Purge Information Date Purged: O-1 -�l Start: 09 ',7�n Finish: 0 '1 S Q Purge Rate:) Q 0 mL Mt Purging Method: M g� r n o G1SO O n Total Volume Purged: (gallons/L) Sampling Information Date Collected: Q-k. /-;,'g/:�)=k Time Collected: ci 5 al /pm) Sampling Equipment Used: M Lp m O n5 Q ®e1 Instrument ID:_ Y ST7o ccQ(NS tb0 a0 61 (YI ( cc pT wtf 30-71 Bottle Type -asz�Mt nicks —f'IQM� virn(5. Preservatipn A-) Analysis Required Nr- AQqSMnfe-ls 1L A0� zyOC. Field Measuretnents/Observations Sample Temp (oq: 1$ Time: QQ fi� Turbidity (ntu):'9 , LA Time: n 5 ST` Diss Oxy (mg/L): O S Time: Fe 2+ mg/L: — Time: Specific Cond. (uS): 3G a Time: , c»' � Res. Cl (mg/LY(µg/L): _ Time:. Sample pH (s.u.): 16 1 Time: �S�Odor: n.)D Time: 011 S ReDox (mV): 3 k .3 Time: oei S"�- Appearance: Glee -wl fF.-os Time: Q 951' ReDox (EH value):YSI ProPlus +200mV a7i" 3i Other: Time: General/Weather Observations:. _ unn / ou /rainy) Temp. 6" (°F) Wind () (r. n Sampler Signature Stabilization Test Time Temp. (oC) Dins Oxy. (mg/L) Spec. (uS)Cond PH (s.u.)V) jReDox Turbidity (ntu) oume removed (gallons/&/ WaterPurged level (ft)Other �. L 1.3R J.S- 6 •1 Ha 'S , q• i q r 1'g S I , Q "�fiR • b , Lt l • � � a O � ; '�. cxtso 1$•Lt 1'Q �a�l,q 6>t -9 '8'S 3Q<10 J� �rAftlk?�yflCel.• Document Name: Field data Sheet Date Issued: March 8, 2019 - Page: 1 •. of Number: P-CAR-FLD-001-rev.03 Issuing Authority: Pace Huntersville Quality, .Document Office Field Data Sheet Name and Affiliation (Sampter(s):-1%.— i�ct,R Ano L -t coi� Field Data Sheet Review: Name and Affiliation (Inspector): N 1 q Date:1 Well Information Well 11): (\OW -''7 Well Locked: / NO / Flushmount ) Well Diameter: -Y Construction OC/Steel/Stainless Steel) Total Well Depth: q-q 143 ft Multi Factor*: Q d(.3 r(Radius/12)2 x 3.14 x 2.481. Static Water Level: a G Casing Volume: I I ' Q gallons. Height of Water Colurrml- 9 ) it Cal. 3 Volumes: 34, 5) gallons Pump httake: '15 , 00 ft By: dA(� Purge Information Date Purged: emu\ / / a \ Start :1 O 10 Finishes Purge Rate: Q cn l M n Purging Method: 1peris�,kk�c.- P,�Total VolumePurged: 1ac,o (gallons/p/L) Sampling information Date Collected:D.� /2j/ lam_ Time Collected, (QS<- am pm) Sampling Equipment Used: PA i S E rA l Er t P P Instrument ID: V SZ e c•ooLu'A D -oq 6 i-Ku 0vwv*-`Sc� Bottle Type I�asn�n� vh 3-`iQnL N,G,ls Preservation k�t-93 Analysis Required NC A(2, T- Y y,6eAr n.rc AQQ-7 kd:�s_ Field Measuremerits/Observations Sample Temp (aC): as Time:Tuxbidity(ntu): Time: I03� Dias Oxy (mg/L): Q �> Time: Q Fe 2+ mg/L: Time: Specific Cond. (uS): L131 •3 Time: I C� S';-- Res. Cl (mg/L)/(µg/L): Time:. Sample pH (s.u.): 17,a Time: 10'YS . Odor: NU Time: 1 O 3 ReDox (mV): Time: 1 n`3 Appearance: Q eo,r Time: I o 3S ReDox (EH value):YSI ProPlus +200irLV ,� Other: Time: General/Weather Observations: sunn / lou0/rainy) Temp`l'(*F) Wind D (mph) Sampler Signature Stabilization Test Time Purged Temp. (oC) Diss Oxy, (mg/L) Spec SUS) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons ml L Water level (ft) Other �a,� 1• t-1a3 6�a 3�,,0 6-- Q� `a6a8 , t-raG _D 1 (0. a :F> 6 6 0 ID6.Q$ 4aq. a 3 a.G,9B q'�O aa.a Q 141.1 1 -) D-6 .q d •'`,.t�ae�TrzaFy<rrttf., Document Name: Field data Sheet Dacumem Number: F-CAR-FLD-001-rev.02 We Usuea. ivuveu Page: 1 c Issuing Au� Pace 11 office Client: 0 L r Location: Rawco Name and Affiliation (Sampler(s): C%- -4 Name and Affiliation (Inspector): - Well Infformation Well ID: M k/ ' / 0 Well Locked: A � Well Diameter: i Construction: Total Well Depth: �I'� ° ft Static Water Level: i> ,) L it . Height of Water Column: �D 5q, ft M64 C wf'-Protect #:__. r %. ✓e. L Field Data Sheet Review: Date: Q,.) I �1 By: / NO) Multi Factor*: `/ 6 S - V(Radius/12)20.14x7.481 Casing Volume: �` �� gallows Cal.3Volumes: ' gallows Pump Intake: ft Purge Information Date Purged:/ � � / �! Stait: l T Q _0 Finish: (S Purge Rate, � 00 Purging Method: Mai M S o aN Total Volume Purged: 3v ' C (gallonml Sam. ling Information Date C011ected:—#--/ }6/ h! Time Collected: Sampling Equipment Used: i� 1G /' �� s mA/ Ins rument ID: %1 = tic cF? 6 a-1 Bottle'Type Preservation Analysis Required ff 3tr,a.f l�c� ✓aL f _ it Cam- 1-/�FPr0�c Field Measurements/observations Sample Temp ( q Time: • `f-'D Turbidity (ntu): ' Time: Diss Oxy (mg/L): p , P •, Time: / 2� Y^-O Fe 21 mg/L: Time Specific Cond. (uS): 3 1.2 Time: ) `r� Res. CI Sample pH (s.u.): -S7 • Z Time: ) ' �� Odor: ltJo t Time: ! a _ _._ .. ... ReD_ox (mV): �/,t% , Time: ) J 'f� A ppearance: ReDox(EH value):YSI ProPlus +200mV d / / v Other: T me• General/WeatherObservationS �v✓Ni G li B_r�—_ ( (nny cloudy/rainy) Temp? J ("F) Wind' (mph) mks LfaNz, /I �� Date: ' A 6 " ! Sampler Signature, ` Time Temp. Diss Oxy. Spec. Cond. pH (s.u.) Volume ReDox Turbidity remove (mV) (ntu) Watex level (ft) Other Purged ( q (mg/L) (US) (gallons ono, 7. s d, 6 b 3 Q.� 31a, 1 ,a S5t? D 'f J. iel LA A du Document Name: Field data Sheet J. Pager 1 of _ dwEAt�adyffl,`i3f Issufig Authority. Pace Huntersvill Document Number: F-CAR-FLD-001-rev.02 Office Field Data Sheet Client. Location: Py�C o 8 P , -� _ Project #: C r / /e Name and Affiliation (Sampler(s):/ PJ P Q J L ;Field Data Sheet1Feview:Name and Affiliation (Inspector): —Date: BYWeil inforanationQ .�al a lWell ID: W ! 0 ,7 Well Locked:NO) i/ Well Diameter: Total WellDepth://a-0 ft Static Water Level: it Height of Water ColumnL L, wft anf ti®n Construction: V�'Steel/Stainless Steel) Multi Factor: a �0 V(Radius/12)2x3.14x7.48l Casing Volume: ID • � 364 gallons Cal.3 Volumes: %V9 el --gallons Pump Intake: (� ft —„ ajib f Pure ®xma .. - Date Purged: - J b / ! Stait : l's �F n sh: J 6 Il ° Purge Rate: l M '/� Purging Method:. ��� M,,/MW Total Volume Purged: Samplan lnfc oration 16 q- j Date Collected: / �� / ' l Time Collected: Sampling Equipment Used: Mc 4 MaaJ'), v InsirumentID: ys Bottle Type t r•c'e a `'r t 3l/lA�l 3-V,,a�1 Preservation ff L Analysis Required e141 l J U.� l Field Measurements/Observations / Sample Temp (°C): _ / 2 • .) Time: f 6 Turbidity (ntu): / Time: Diss OXY (g/) m L: _B 12 Time: JbCF� Fe2+mg/L: - Specific Cond. (US): 3 ZC ' ! Time: 6 � Res. Cl � lb °i6 Sample pH (s.u.): ! 7 Time: �6�� Odor: AA, ,c- Time: - ReDox (mV): r �' cr Time: 6�Appearance: Cy Time: ( � ReDox(Ellvalue):YSIProPlus+200mV 133 ( Other: Time: GenerayWeather ry A/ Sampler Signature: Su.. A.49d.. 44— Tnc4 %°( F) Wind ' (mph) ,.,..... Time .._. __ . Temp. . D ss O xY" Spec. Cond. pH (s.u.) ReDox Volume Turbidity removed Water Other Purged (°C) (mg/L) (US) ( mV) ru ( n) (gallons/ level ft () 35 L6 1 4,15 16 ro ja,� 0 3 lIQ L f LL(--6 L� 1 .3P 0 Document Name: Document Issued: November 27, 2e18 Field Data sheet pageaf _� Document Number: Issecing Authority: F-CAR.FLD-001sev.02 Pace Huntersville Quality Office nn � Client: U� Location: - 611,`C Project: '/ /t/c Well ID: tv Reviewed Date and By: StabillaailonTest -N— rc�F 4 A Time Purged Te.m p (°C) Diss Ox . y (mg/L) - Spec' Cond. (US) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume Removed (gallons/misl circle one Water level (ft) - - Other l6 �, xz r>` �s2 a T-0 0, fi./ /oo ZIT, 326.Z 6,1d 65", � G, �- &D 7b.3 - /6s:; Document Nance. Field data Sheet Date Issued: March 8, 2019: Page:: 7 GC$k11)rflCal of Document Number F-CAR-Ff.I7-p07-rev.63 Issuing Authority: Pace Huntersville Quality r Office �I Field Data Sheet Client: CO p � Locatione&5'a r-- Nameand Affiliation (Sampler(s): Z"0�- 7 A cA XnaItiH cal Name and Affiliation (Inspector):, n (q Well Information Well ID: (-Y) Well Diameter: a-" Total Well Depth: S-1-ca it Static Water Level: 30 •-'Z It Height of Water Column: d \ • 1 !� It Data Sheet Review: Date: +A-a1 By:8RQ- Well Locked: ((E/ NO / Flushmount )' Construction: (Vl' ( /Steel/Stainless Steel) Multi Factor*: Q,%3 r(Radiu9/72)2 x 3:14 x 7.481 Casing Volume: 31"\5 gallons Cal.3 Volumes; 1 '3S gallons Pump Intake: 1� `1 b It Puree Information Date Purged:-Q,1 /4 / -,),1 Start: I 0 Finish: PurgeItate: 1t IOrn1 lcvtn Purging Method: 00 c Total Volume Purged: 29A ClO (gallons/ 71 f L) Sampling Information Date Collected:Q�/:al/ Tune COIlected:_L3 Q._ _ (am/to Ae�,t 13 ait Sampling Equipment Used: Meat M n (),Sc) o n instrument ID:_ Y5:r p�(�(v s C1ag6 /CY i cc �iTQ rr Bottle Type Preservation Analysis Required ej c. A Field Measurements/Observations Sample Temp (°C): Titne:- ISID Turbidity (ntu): 2,'S- Time: 13 C)Q piss Oxy (mg/L): 0 • JL Time: 1300 Fe 2+ mg/L: Time: Specific Cond. (uS): '\S\•a Time: I :;00 Res. Cl (rng/L)f(gg/L): `Titne: —' Sample pH (s.u.): ___ .Tune: t3QQ Odor:N1�.____--_Trme:..._I300 ReDox (mV): Time: (300, Appearance: C1tcc rime: t300 ReDox (EH value):YSI ProPlus +200mV 2 -t`�l 1- Other: Time: General/Weather Observations: Sampler Signature Stabilization Test Spec. Volume Time Diss Oxy. Conti. pH (s.u.) ReDox Turbidity removed WaterOther Purged (mg/L) (uS) (mV) (ntu)' (gallons/ 7 s level (ft) 6emi, L4S,4 (,." 6a.� O •a 31 •1,o S6. 6.L4 (.o f Q.� k-li SS,S t,� 1 3i,bo \ Imo, 6 451-aI C, 57,0 I go3i. VI Aa on e \\a �a�Anatytleal' Document Name: Field Data Sheet Document Issued: March 8,.2019 Pageaof?" Document Number: Issueing: Authority: ( F-CAR-FLD-001.rev.03 Pace Huntersville Quality Office Client: BLS ' �3�(1c Cq Location: As -a4 ,o 6 _ /J c Project: C\c • Co . A 6-N e. OF fi Q rs T-Z- o wh-z4, Well ID: M lnl l \ Reviewed 'Date and By: Stabilization Test t=Vell Diameter 'Multiplication Factoe 1 0.0 i08 1.2 0.0415 1.625 0.1030 2 0.1630 8 0.3670 4 0.6530 6 1,4630 8 2.6100 Time Purged Temp. o (G) Diss Oxy. (mgJL) Spec. Cond: (US) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume Removed (gallons/ JL) circle one Water level (0) Other .� 4 ,, &L4 is-3,"3 aq.a o 0 11 cq ai o• yse.r 6,L� S7-i. D-a.a I -5 o LIIlo o.L os Lt .3 LL4 I S-i.o aa: 3). o at.1, 0, Liw,L t. a 5 t } F A o mLI e-I-J 0 o_ �a.� o• 4sS'.cA 6-LA 411 o o 3�•-{q la LI, 0•� 4S6•"� LDS, 16,�- . a a, bs 31 1 Q -.L -s ILA I;:'6IS 1 4y.g 1 layo IaIs o.s Lv�,a "SIT 74 I 50 ",131L•( LAS11 i-S 'AA-�i 11 vm 83 �j1. f 5 aaa b _ 4sa• 6 - y IF, --A I z6 o — jW e7CBMk7lyfiCi:/' Document Name: Field data5hcet. Date Issued! March &, 2074 Page:. 1 of s� Document Number F-CAR-PI..I)-OOl-revA3 Issuing Authority: Pace Huntersville Quality Office t Name and Affiliation (Sampler(s);StS$ -Pace A, Nrl, co l Name and Affiliation (Inspector):_f j � A Well Information Well ID: M Well Diameter: �µ Total Well Depth: 71 �T 9 It Static Water Level: .- •� ft Height of Water Column:Ii0 ,-Xft Well Locked: Construction: Data Sheet Review: Date: q-2s'3( Steel) Multi Pactar*; Q0 b3 p(Radius/12)2x314 x Rd8j Casing'Volume: gallons Cal.3Volumes: gallons, Pump Intake:_ 6-9 .O C ft By: BP,6- Purge Information Date Purged: C t-t Jam/ 1 1 Start : ( Fnush; j S� Purge Rate:aQ m l - Purging Method; (V tag M o nS o n n Total Volume Purged: (gallons nl /L) Sampling Information Date Collected:—D-\,�,_/43:/ �, Time ColIeeted: 1=_ _ (am to Sampling Equipment Used: cvzern n n 5q q Instrument ID: \1 S 1 nip fylLS 44 C�...�,( tt zcSpt� 30� of i� � m Bottle Type Preservation Analysis Required 3-o{Qrnl vr� Is 1 f 1 &Y.Ap,p -.r llo( Field Measurements/Observations Sample Temp (1q: a(� Timer _ Turbidity (ntu): 3. � Time: ISM Diss Oxy (mg/L), T Q Time: 3 _ Fe 2+ mg/Li Time: -- SpecificCond. (uS): 3S Time: I Res. CI (mg/L)/(µg/L): — rune: Sample pH (s,u.); _�..._ Tirne: Ij _Odor:_._0 C ReDox (mV); Time: JST� Appearance: Cle-el Time: ReDox (EH value):YSI ProPlus +200mV Other: �— Time: General/Weather Observations: Temp. (°F) Wind_(mph) Sampler Signature Stabilization Test Spec. Volume Time Temp. o Diss Oxy. Cond. pH (s.u.) ReDox Turbidity removed Water Other Purged (C) (mg/L } (us) (InV} (ntu) (gallons/ ils level (Et} L S 14.6 4. 6 A � �,A 1R.6 43 6,1 `1 4• n 1• 7 0 3 ,05 S a 1 S,B I �O � l� 4 i . I, 43,F 6 _ AtiiljYilCs4% Document Name: Field' Data Sheet Doawnent Issued: March. 8, 2019 Pugea of� Document Number: Issucing. Authority: i F-CAR-FI::D-0O1.rcv.M Pace Huntersville Quality Office Client: B E - Vuc1cctiM)Dc Co Location: A -DV ,�I e, /o(- Project: Co, A(, ,- Li- Aa{ l aQa\ Well ID: MW-IUD Reviewed Date and By: 4, A-;)l 6('� Stabilization Test Well Diameter Multiplication Factoe 1 0.0408 1.2 0.0919 1.625 0.1030 2 0.1630 8 0.3620 4 0.6530 6 1.4680 8 2.6100 Time Purged g Temp. (C) DissQxy. (mg/L) Spec. Cond. (US) pH (s.u.) ReDox (MV) Turbidity (ntu) Volume Removed (gallons/r@l, /l) circle one Water level {0j Other i a� 3 ,o'S 6 I aD ,D 3t Y,2 I - alLk 3, Document Name: Field data Skeet -'� Date Issued: March 8, 2019 � Page: 7- / Analytical Hume Issuing Authority; Pale Huntersville Quality. f/ .Document Number: P•CAR-FLD-001-rev.03 Office . Field Data Sheet Name and Affiliation (Sampler(s): CW3 - rC Cam_ Name and Affiliation (Inspector): AZA- Well Information Well ID: M W -1 Z Well Diameter: 2 Total Well Depth: 2-0. 9 5 ft Static Water Level: (1 A0 ft Height of Water Column:q 65 ft Well Locked: Construction: Field Data Sheet Review: Date: p�('1�1a1 By:7(J� E / NO / Flushmount ) -/Steel/Stainless Steel) Multi Factor*:Q. 163 r(Radius/12)2 x 3.14 x 7.481. Casing Volume: I > 5� gallons. Cal. 3 Volumes:, o gallons 1 Pump Intake: 1 I - D I ft Purge Information ,, Date Purged:_/na / ota St t: �. i� Finish: 1 Si% �i Purge Rate:,^d0 t-f r Purging Method: Pex:s�kyc- Total Volume Purged: 70'0e (gallons�L) Sampling Information Date Collected:0,j / / 2W-1 Time Collected: 15IO (am/0 Sampling Equipment Used: efYS&4iC V Instrument ID:YS'1;j;e 3c1/TP1^3At9®23 Bottle Type Preservation Analysis Required KQ M(_ //,'c. ZXko Mt v,^o. ) WISO mt- Ortso. ML IPlas7t�% I )r2So r" t- PjAs,^c. Field Measurements/Observations Sample Temp (oq: 1 %• 0 t/G I NNo2 Un reS Ufi r4' I.r- tXtOls �� avPLVaC i'TGifwk��RlFu�a+'1 f t Ll D %pXaw? � So,) A 14- TD5 1 510 Turbidity (ntu): 2-4 Time: IS 10 Digs Oxy (mg/L): V' ' 5 Time: 15(0 Fe 2+mg/L: '-- Time: Specific Cond. (uS): 1013 Time: I S 10 Res. Cl (mg/L)/(µg/L): Time:. Sample pH (s.u.): 6-3 . Time: 1 S 10 Odor: I ows:k,Time: 15 ReDox (mV): 69.9 Time: 151& Appearance: CteiP r Tune: 15 1 0 ReDox (EH value):YSI ProPlus +200mV Other: — Time: — General/Weather Observations: POLW..-12 - Bunn cloudy/rainy) Temp. ('F) Wind�(mph) Sampler Signature Stabilization Test Time Temp. Digs Oxy. Spec. PH (s.u.) ReDox Turbidity Volume removed Water Other Purged (oC) (mg/L) (S) (mV) (ntu) (gallons/�' level (ft) M3 1$, I I939 6.3 66. f ,3 1000 11.3�K g, t l,7, a �- 3 u.i — — I tiU tg, 7 8•'3 .oao n 1 10 17.1 CI �b -Z 7,6 1 JMM 1� Document Issued: March 8, 2019 Document Name: Sheet rageZ—,of?,- Field Data 11-11�alc e AA71Y11Ga Document Number:Issueing F-CAR-FLD-ODI.rev.03 Authority: Pace Huntersville Quality Office Client: 6 , - eunc, Co. 69 -2-7-,A I Location: ^x Project: &10(- Co. Well ID: Mw - ) 7, Reviewed Date and By: Stabilization Test 1625 01,080 2 01650 G.3.6770 4 0.6530 1.468,13 2.6100 Turbidity (ntu) (gallonsOL)• circle one ffm®"Vp M.° r Fs M.� Document Name: Field data Sheet Date Issued: March 8, 2019 .-s'aeBAnaij,NCal' Page: 3of Document Number: F-CAR-FLD-001-rev.03 Issuing Authority: Pace Huntersville Quality. Office Name and Affiliation Name and Affiliation (Inspector): NA Well Information Well ID: Well Diameter: Total Well Depth: 39 3e ft Static Water Level: 5 • b I ft Height of Water Column:�� ft Field Data Sheet Well Locked: Field Data Sheet Review: Date: By: ,2/ NO / Flushmount ) Construction: �(I ( '/�Steel/Stainless Steel) Multi Factor*:�/7�11y [*(Radius/12)2 x 3.14 x 7.48] Casing Volume: 11. �'� gallons. Cal. 3 Volumes: 14 - 7- gallons Pump Intake: 7� q- „ ©1 ft Puree Information Date Purged: ©41/ 02 / I Start: 1 S 7 S Finish. 1 S L1 G Purge Rate: Z00 in c-/ /h r Purging Method: Y'U ISIR I} o C /&Mp Total Volume Purged: 300-0 (gallons/GL) Samoline Information Date Collected: Oq-/ /2Y/;1021_ ifne 'ollected: 15 y S (am� . Sampling Equipment Used: P(fS / tC NY4d/ Instrument ID: /Ttw ,?&Z3 Bottle Type Preservation Analysis Required ?,k/ 410 rnI ✓-a NC apayo c a iel�. L.yo7/o Q 1.� 2 So w+(, ?I0,wc A/00 AX VO r- Mtn" 15 1- h12S0 .wt: PIaS.),"G 1)17PAf- C/. Sbu: q1k I�. LSa rwti f k o 24, c UVO)t 5 Field Measurements/Observations Sample Temp (°C): .Time: 15�15. Turbidity (ntu): Time: Digs Oxy (mg/L): G . K Time: Fe 2+ mg/L: -- Time: '— Specific Cond. (uS): Time:. 15 t15 Res. Cl (mg/L)/(µg/L): — Time:. --- Sample pH (s.u.): G • q Time: Odor: !.J D Time: I Sq 5 ReDox (mV): ao , I Time: . 1541 Appearance: C le, _ Time: 1 Girl ReDox (EH value):YSI ProPlus +200mV 22:0 - Other: — Time: General/Weather Sampler Signature, Stabilization Test -t2 _( unn /cloudy/rainy) Temp. Si-i (°F) Wind 2 L'(mph) Time Purged Temp. CC) Diss Oxy. (mg/L) Spec. 8) pH (s.u.) ReDox (mV) Turbidity (ntu) oume removed (gallons mis Water level (ft) Other 1530 0. 5 y -5 6 LL t000 y,3 Z. 0.5 '1 A4 361of Z.Z lS35 0,5 99?, b -4 1 11'z Z 1-- u00 °I. I N I c7q0 R. 6 0. 6 L11 6.1 P.2. 2 .2 300 11- 9 _ TQBa7Nl'y17Cf Document Name Field Shret. Uate Issued; March 8, 2019 Pal,e:. lof Document Number. F CAR-FTp 001-rev.0$ Issating Authduty' Pace Huntersvil A Qualfty Office j Field Data Sheet LEI B(Ar)Com6PCo. r ll)n"_W. AK: Name and Affiliation (Sampler(s): MO' - r'ACB Name and Affiliation (Inspector): nili Well Information Well ID: MI/J'- (3 Well Locked: Well Diameter: M. Total Well Depth: 15, 3`b It Static Water Level: Cfk Height of Water Column; la, 5 5-ft Data Sheet Review: Date: q4�Z}��� RED Construction: ('V 1/Steet/Stainless Steel) Multi Factor*: • [*(Radius/12)2 x 3.14 x 7:48] Casing Volume: off• I gallons Cal.3 Volumes; 60 gallons Pump Intake: t (3, 5 ft Un fUCkfLF acza/ Purge Information _ 150L Date Purged:_/�/ 31 pstart : i iJ Q0 Finish: 15 �� Purge Rate: M mid Purging Method:_�Pri ak \ t,�•M Total Volume Purged: ` (gallons/ n /I.) Sampling Information t Date Collected:_/-7/ pa) p,p Time Collected;_. I_`I J (am1­1 m Sampling Equipment Used: Pen5QA,c_ t�tAMO InstiumentID:_�� Vn-p" -*0107lnc�c7PtuXi Sash Battle Type Preservation Analysis Required -gD MI, c�g�� HC( __z Voc _ _.... i- aSnlvt( P(�s�k klNn� - Ts Field Measurements/Observations y Sample Temp (aC):.�) . Time: 1,5 q_5-Turbidity (ntu): • / Time: 1SuIS Diss Oxy (mg/L):..(-,_I Time: _ Fe 2+ mg/ L: Time: _ Specific Cond. (us): 3 ] i•� Time: Res. Cl (mg/L)/(tsg/L): Time: Sample pH (s.u.): �_- Time: Odor:_.-_ }.7D y _ __Tane:......_ __..-- ReDox (mV). ((Li • Time: Appearance: 24r W ', IV�ime: ReDox (EH value):XSI ProPlus +2pilmV ?55 . o� Other: Time: General/Weather Observations: rainy) Sampler Signature Stabilization Test Wind 0-5 (mph) Time Pinged Temp. a (C) Diss Oxy. (trig/I } Spec. Cond. (us) pH (s.u.) ReDox (mV) Turbidity Onto} Volume remove (gallons/ 1Ts L Water level (ft) Other 50 a• ►M M aIq 10o. 3•Z-3 , ` 5,,y ,0 '7 0 0,9fo EO0 0,1 ��.1 y. 01' 1 1-312,A -11y.1 I A. I J000 LhField data Sheet Date Issued:March 8, 2019xumentNnme. aBeAr7alyllca! Palle: ruf'7 l�eKument. Number F-CAR-FI..n-06l-rev.03 Issuing Authority: Face Himtenville Quality Office t Field �Data Sheet uncy#A� l,neatinn: WOadPin AlC Name and Affiliation (Sampler(s): 91ONV ^ CL ce Name and Affiliation (Inspector): %U/ Well Information Well ID: MW'\31? Well Diameter: a�, Total Well Depth: q(0.5-3 It Static Water Level; S •$c� It Height of Water Column: y0, 73 ft Data Sheet Review: Date: ()L�l )-� II A Well Locked: ES / NO / Flushmount ) Construction: pV Steel/Stainless Steel) Multi Factor`: e l (075 r(Radius/12)2x 3rt x z.a8j Casing Volume: (0• (o gallons Cal. 3 Volumes: 19' b gallons Pump lntake: �3' 5- If 1 Purge Information // Date Purged: q / d7 J ai Start: ao Finish:l565 Purge Rate:�DALIMiiI Purging Method' _�ri5ia(+i c �ur✓� Total Volume Purged: yS-00 (gallons mis L) LT aoa, Sampling Information Date Collected: t / a7/ )-k Time Collected:._ I'D (b(ail fIn Sampling Equipment Used: 1%is%z, t� (f/r C `,!—' Instrument ID: Y Bottle Type — PAC, f�iass I- �sor,[, Piask Field Measurements/Observations Preservation H C( - H M02 Analysis Required tA�t ;ZMe><af� Sample Temp (°C): i Time: j j l Turbidity (ntu): ©Y _ Time: Diss Oxy (mg/L): 'rime: Fe 2+ mg/L: Time: Specific Cond. (uS): �a Time: Res. Cl (mg/L)((ltg/L): —' Time: Sample Fri (s.u.): _ �. _. _ Time: - —Time:.__ ReDox (mV): - I Lf-3 Tune: Appearance; Clear w 4"le- 'Time: ReDox (EH value):YSI I?roPlus.+200mV I�5,7 Other: Time: General/Weather Observations: Temp. g( (7) Wind d`s (mph) Sampler Signature Stabilization Test Time Temp. ° Diss Oxy. Spec. Cond. pH (s.u.) ReDox Turbidity volume. removed Water Other Purged (C) (mg/T) (us) (mV) (ntu) (gallpns/o/ level (ft) L Was N I6, ( .7 Li 6.9 /fc of --411,$ fa -7 3 Soa �- Yy 435 (a• 0 5 qk5-,g ..DL 3 15-00 19`40 ,$ H,t 2a� lob Document Name: Document Issued: March: 8, 2019 Field Data Sheet page aof a e1CG'Afk7�j/(IGc4 Document Number: Issuemg Authority: I F CAR-FI::D-001.rev.03 Pace Huntersvitte Quality Office Client; B`E/ 6u.Icombc co, Location: Wacct& A4 Project R1A r0mk, %c, pew Well ID: J4k) - Reviewed Date and By: Stabilization Test lVell Diameter XTultiplieation Factor- 1 0.0403 1.2 0.0913 1.625 0.1030 2 0.1630 5 1 0.3670 4 & 0.6530 6 1,4630 3 2.6100 1111mm Turbidity moo Document Name: Field data Sheet Date issued: March 8, 2019 ceRngfyNraT" .. Fa e: 'of, Document Number: F-CAR-FLD-001-rev.03 Issuing Authority: Pace Huntersville Quality. ,.. Office Field Data Sheet Name and Affiliation (Sampler(s): a(%$ -PACs, Name and Affiliation (Inspector): Al R Well Information Well ID: m rW U Well Diameter: 2 Total Well Depth: 5 2.83 ft Static Water Level: ')-S,36 ft Height of Water Column: � L1 • LI -j ft Well Locked: Data Sheet Review: Date:zj.ag ?) NO / Flushmount ) Construction: PV Steel/Stainless Steel) Multi Factor*: O b r(Radius/ 12)2 x 3.14 x 7.48]. Casing Volume: 3• 9,F gallons, Cal. 3 Volumes: 1{ • gallons Pump Intake: 60 •y ft Lf� W"LS By: Q2Cr-- Purge Information Date Purged:Q(,( / 2-3 /0 Start : 9 Finish: /0o S Purge Rate:��L t-21%' Purging Method: ReJ72Ak Total Volume Purged: � (gallons/ t�i's'L) Sampling Information Date Collected: q / Z$/ 2024 Tim ollected: (o ld a®Jpm) Sampling Equipment Used: P— l- Instrument ID: IK7 33�'i7P1 Q'�Z� Bottle Type 14eservati4m Analysis Required AIG 61,v .Vocr Te±fah lro umr`. IXZSo mac- HS+A- HNo� AIC Apjl�r- Mtlm,IS+H%;Fp MA. OQ50 V i. Q(e.Si,`c Ur(h^2S. CIF-fO� . Alk tx tMgo rv.L_ Plo.�.y,�....... Field easureI X8/O servation9 unere s. Sample Temp (o(Q): . 1 /Z -Cj Time: /0/0 Turbidity (ntu): I . O Time:f lC Digs Oxy (Mg/4 . • % Time: (0(.0 Fe 2+ mg/L: '-- Time: Specific Cond. (uS): I SPf - 6 Time: f o I o Res. Cl (mg/L)/(µg/L): -� Time:. Sample pH (s.u.): b • o . Time: /0/0 ' . Odor: ND Tune: /0/0 ReDox(mV): I001-q Time: Colo Appearance: Cteo.r Time: 1010 ReDox (EH value):YSI ProPlus +200mV �09- 4 Other: — Time: General/Weather __C(sunn�y- cj9)ady/rainy) Temp._ (°F) Wind-L2—(mph) Sampler Signature Stabilization Test Time Temp. Digs Oxy. Spec. PH (s.u.) ReDox Turbidity Volume removed Water Other Purged (aC) (mg/L) bus) (mV) (ntu) (gallons/l t�l / level (ft) b�Sa I �I 6 %-9 6.o )I).5" r,, ti oo tr. 4 0. 6 5- — 054 16.9 -Z 04-1 6.0 n)-o 3.1 1 'M U9.95 100, l 6.0 lilt.. Z I 1. 5 1 ►too PC 11 100S 1 . 1-1.3 1 6.0 .2- 11.6 1 1600 V-9 Document Name: Field data Sheet Date Issued: March 8, 2019 race Anal tk,W' Page: 1 of Document Number: F-CAR-FLD-001-rev.03 Issuing Authority Pace Huntersville Quality. �; Office Field Data Sheet Client ocation: Urt Name and Affiliation (Sampler(s): IDS ' FO-Ce, Name and Affiliation (Inspector): /VPf --- Well Information Well ID: MW 1 �l Well Diameter: Total WellDepth: r?I.•So ft Static Water Level: Height of Water Column: G 2 - 59 ft Data Sheet Review: Date: By: b%6- Well Locked: (ZTV NO / Flushmount ) Construction: Steel/Stainless Steel) Multi Factor":.163. r(Radius/12)2 x 3.14 x 7.481. Casing Volume: 10.2-0 gallons Cal. 3 Volumes: 3o 61 gallons Pump Intake: D f . C) ft Purge Information Date Purged: 01-1 / 02 0 Start: 10t'16 Finish: f0 SS' Purge Rate: 4Omult )A Purging Method: -p'@Ci `I+r 1�w.�_TotalVolume 'Purged: ya (gallons/63?L.) Sampling Information Date Collected:Qq-/2S/ 2021 'me Collected: It 00 (Opm) Sampling Equipment UseAU; s-i-r- L Instrument ID: 115-CWM 17-fWi} c?023 Bottle Type Preservation Analysis Required L r U-6tL S 3,1(1410mc- E►P�� pro rTeka 1„�dro�u� I x l- 0 07t 1p� HA)0� A ,ApQL ft%C&jS f-liya, Fej Man 1k15o ty.n._ PI-If-Z Unfres- U.TS054 .Alk T /X ZSo, tvy_ Plo-Sf z u4ings. 116 Field Measurements/Observations Sample Temp (oC): 0 •O Timer &0 Turbidity (ntu): b o8 Time: 110E Dias Oxy (mg/L): 336, 2•�Time: 110 ®. Fe 2+ mg/L: Time: x� Specific Cond. (uS): � Time:. 00-0 Res. Cl (mg/L)/(µg/L): — Time:. Sample pH (s.u.): 7 • ),. Time: 1100 , Odor: tU f% Time. (1 d O ReDox (mV): )01,0 Time: 1100 Appearance: —Time: I 10 0 ReDox (EH value):YSI ProPlus +200mV 301. 1 Other: Time: General/Weather Observations: Myo - I H O. (sum clou /rainy) Temp. -40 (OF) Wmd-Q-:-5-(mph) Stabilization Test Time Temp. Digs Oxy. Spec. pH (s.u.) ReDox Turbidity Volume removed Water Other Purged (oC) (mg/L) (us)' (mV) (ntu) (gallons/®/ level (ft) L 046 I - 2.9 33 1-Z to?-Z 1.1 160 29-50 Na� E — 0Ina-y Io h 110.0 13 -1,1 1 IDI -q I 0_??- 1�Iso g, �tr Document Name: Field data Sheet - -.. Date Issued: March 8, 2019 1 . Page: Z �AM/jft • 1 of Document Number: F-CAR-FLD-001-rev.03 Issuing Authority: Pace Huntersville Quality. Office Name and Affiliation (Sampler(s): JUS' JC0.GC'_ Field Data Sheet Review: Name and Affiliation (Inspector): /010r 's Well Information �S -Z7-ZI Date: p�la$I-.�I Well ID: IA W ' I S Well Locked: ( / NO / Flushmount ) Well Diameter: Consttuction: t1;1R%Steel/Stainless Steel) Total Well Depth: 2 - 06 ft Multi Factor":! , l 63 [`(Radius/12)2 x 3.14 x 7.481. Static Water Level: 2 Li- ft Casing Volume: I •2 q gallons. Height of Water Column-7- 6 ( it Cal. 3 Volumes: 3 . Z gallons Pump Intake: 2 g- ft By: Puree Information r�� Date Purged:Oq / R -T ./Start: (.Z.IU' Finish:112.0 Purge Rate: NO ML/M:A Purging Method: P"" fy, 1+h� Total Volume Purged: (gallons lQL) Sampling Information Date Collected:0a-/P/ W1 Yin Collected: 13;5 (am/ n Sampling Equipment Used: f4 1h�C6yne Instrument ID:y5r.3CW9/TPW$Ob-z3 Bottle Type Preservation Analysis Required 3X'10 Ml- v?w.1 nVcApPzyoc-r►e yolMPFU14kY1 2Xwo mf. V. a 1 Hr, ( l I -I D idXav�e, M SO nnl- V[c S+,X 14AJ roc � , + Ha : Ge, AMA il(Z50 mt- PloaS x VAP(LeS. GI 50 All WISO rttt PIaSfiY unPres. 5 Field Measurements/Observations Sample Temp (ac): ib . 5 Time: 133-5 Turbidity (ntu): 5. Time: 1325 Digs Oxy (mg/L): • 5 Time: 13a5 Fe 2+ mg/L: Time: Specific Cond. (uS): 6 Time: tZ2-6 Res. CI (mg/L)/(µg/L): — Time:. — Sample pH (s.u.): 6 - Time: 13 D25 . Odor: AXS) Time: 13; 5 ReDox(mV): P) Time: Y32 5 Appearance: line: 1'3;,-r ReDox (EH value):YSI ProPlus +200mV UD Time: General/Weather Observations: tMW - 1 S e 5 2q 1 t TA dl Mt^' 1 r7 S WIN unn cloudy/rainy) Temp.Z(OF) Wind 5-/G (mph) Sampler Signature: Date: CK4 - 2.1- 5LC/)J Stabilization Test Time Purged Temp. (oC) Digs Oxy. (mg/L) Spec. Cond. pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons mi / Water level (ft) Other (US) I215 16-2 1-z SZ6.9 6.0 -9.5 115.4 --;60 Z1.fl0 D r +e 16. 1 . Z r270-9 6. 0 -q-i9 Ed.) — tAo 1 16. I 1 1.Z 572.0 6.1 -4 _ I % .1 I oo 2l•if$� 171.0 1 0.9 1.67,7-016.0 - el -N 1 67.o I xxdo ZZ-0 .1,16A 11tio 16. 0,% IM,11 6,0 — •5 3 \ . 4200 ;U. f Document Name: Document Issued: Marcb 8, 2019 * Field Data Sbeet Page% of"L Document Number: Ismeing Autbority: +F-CAR-FLD-001.rev.03 Pace Huntersville Quality Office Client: QL� QunG Go ON-2'2� Location: 0eyyy-I NG Project: BW)C• GO PcC�`7� lS �SQe�'t•2'►'� Well ID: Reviewed Date and By: Q`A Stabilization Test 'i�lsell � _. aEacn FaeEzu" Y..fizS a�_7tx�o D.5670 4 0+ 6530 6 1 6,aG 2.6100 Spec. (US) Turbidity circle one Water level Yam• ���� � � � Y t, i ®- rim Document Name: Field data Sheet Date Issued: March 8, 2019 aCeA nalyFfeal' PaLe, 1of) Document Numbbr: F-CAR-FLD-001-rev.03 Issuing Authority: Pace Huntersville Quality. Y. i . Office Field Data Sheet Name and Affiliation Name and Affiliation (Inspector): AIA- Well Information Well ID: W - [ rJ li Well Locked: Well Diameter: 2 Construction: Field Data Sheet Review: Date:()uO By:?/U f / NO / Flushmount ) Steel/Stainless Steel) Total Well Depth: ti 5 •t13 ft Multi Factor*A 1 3 ["(Radius/12)2 x 3.14 is 7.481. Static Water Level: 25 .0.2 ft Casing Volume: 3, 33 gallons Height of Water Column: W M I ft Cal. 3 Volumes:. 9 9 4t gallons Pump Intake: '-1 Z , 0 ft Purge Information Date Purged:09 /o'LI-/1l L/ (Start: 1T45 Finish: /1 Purge Rate: SOML MIA Purging Method:. PP.CifiMo -Ik POMP Total Volume Purged: 1-10b (gallons/(nl 1,) Samulina Information Date Collected: _q /�Tj ao;_1 nTime Collected: I�ob in(am/ Sampling Equipment Used: PU S}o �i i C YV 02 Instrument ID: S±' 14 / 7116) *90Z7I Bottle Type Preservation 7 Analysis Required 3Xt-I:o mt, V1'.60 HG1 A7c ARP tvoc+Te,+ru,hy-0A*-an lyn rA 1, VNd, i 1-I L j 1� L1 Waxar e— /n mu via"516'r- HA/0A hx APPs pyAb,1sa-w mot,. 1XZ50 in c I f Sc��� Alk 1 2 So nn t_ p (a 5trf t.- U wP� TDS Field Measurements/Observations Sample Temp (eC): . 2 � - 3 Time: 110 Turbidity (ntu): 0-7 Time: 9 S Digs Oxy (mg/L): 0.9 Time: i �0 5 Fe 2+ mg/L: — Time: '— Specific Cond. (uS): WM Time: I 0 Res. Cl (mg/L)/(µg/L): s Time:. Sample pH (s.u.): 6a 9 Time: I 5. Odor: Foy I Time: (to Ci ReDox (mV): 60, 0 Time: 110 Appearance: C I ee.r Time: [ 105; ReDox (EH value):YSI ProPlus +200mV :5 O - 0 Other: Time: — General/Wieather Observations: v%w I r p, . Q j ( unn cloudy/rainy) Temp. 31 (OF) Wind 6 11 (mph) Sampler Signature Stabilization Test Time Purged Temp. (C) Digs Oxy. (mg/L) Spec. Cond. (US) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/6-S) Water level (ft) Other 13 22_1 0. 06g 579 60- 2-7, 96_ lei 17, 1 0- S- l + SA 50, . Z-Z -- 13ss zl- 0. 51 50. r b T" gi; 1 OU ZZ 3 0.3 10 o I 5.9 160, 1 10. 6 IWO 1213 G9RYtAlylfLtll Document Name: Field data Sheet _ Date Issued: March 8, 2079 Pap:. 1 of a Document Number F-CAR-FI..13-061-rev,03 issuingAuthority:Pace Huntersv'ille Quality' it Office Field Data Sheet Ca. T ,..; lii--- IG A Name and Affiliation(Sampler(s): I��scc Name and Affiliation (Inspector): Well Information Well ID: M W —17 9 Well Diameter: r?" Total Well Depth: a�. qg- ft Static Water Level: Fleight of Water Column: /d 35 ft Well Locked: Data Sheet Review: Date: 0�(�a3�a1 By' NO / Flushmount ) Construction:��/ Sheet/Stainless Steel) Multi Factor*: 43 r(R'adius/12)2x3,14x7.481 Casing volume: 9 gallons Cal, 3 Volumes; % gallons d4,o Pump Intake: ft luev i L.F ad-' / Purge Information Date Purged:_�4_JyA_/ a( .Start: 0949 .Finish: /0:)5' Purge Rate: %OI'%`Min Purging Method:_{ i.$.�g,�$5`P` un�p Total Volume Purged: •3af �0 (gallons/ n1 i.,) Samvline Information Date Collected:q/_A/ a( Time Collected: 103. Ott_._, �pm) Sampling Equipment Used: PC � c. TttrhJ3 Instrument ID: lafivWW07 �i'_(_ra]J°W #kI3�5— 6Pwat Bottle Type Preservation Analysis Required s - MtnML rHassHCi _M .J1.�4 'Dox� SOmLG$(e$�sme _��iC, O�dN &I WIS Field Measurements/Observations Sample Temp ('C): _ 17 q Time:-___�930 Turbidity (ntu): /,13 Time: 030 Diss Oxy (mg/L): 3. S Time: Fe 2+ mg/L; Time: Specific Cond. (uS): aa-��r""I Tints: Res. Ct (mg/L)/(lcg/L). Time: Sample pH (s,tt.): ReDox (mV): 115t, c Time: Appearance: Cleor Time: ReDox (EH value):YSI ProPtus +200mV 35'/• a Other: Time: Sampler Signature Stabilization Test —a Wind f —.57- ) Time Tenrp. a Diss Ozy. Spec. Cozad. pH (s.u.) Rspox Turbidity Volume removed Water Other Purged (G} (mg/L) (us) (mV) (ntu) (gallons ni level (ft) L 0� MR5 .3I•�I 5,Oo IS(00 o EP . a- as �'(04.3 as . ' ens <1 a 3 a• 1 is.�S �oM M; �(-a9 •ai Document Name: Document Issued: March: 8, 2ing aceAnatytical Field Data Sheet Pageji-of 6L. Document Number: Issueing. Authority: f i P CAR-FI:D-UQl.rev.03 Pace Hunteisville Quality Office Client: L E/ Bt N-xY,6 l A Location: UWo)hn. /,3C --1 Project: n'rm (o New L/ Well ID: MW Reviewed Date and By: O Stabilization Test' (%real Diameter Multiplication Factor" 1 0.0408 1.2 0.0918 1.625 0.1080 2 0.1630 3 0.3670 4 0.6530 6 1.4680 S 2.6100 e •Turbidity .CC$k7l)EflC1/ Document Name Field data Sheet. Date Issued: March 8, 2019 Page:. 1 of a Document Number F-CAR-FL.d-0Q2-cev.63 Issuing Authority: Pace Huntersville Quality Office 1...- t be - Field Data Sheet kr,d6h, ,NC Name and Affiliation (Sanipler(s): 6R& — (�'� Name and Affiliation (Inspector): IVA Well Information Well ID: MW -P1-,R Well Diameter: a n Total Well Depth: �ta, / f ft Static Water Level: .- ft Height of Water Column: d9 • at ft Well Locked: Project #: C044be _ i4/ew LF Id Data Sheet Review: Date: Q`ry JWS �I By: NO / Flushmount ) Construction: (// E/Steel/Stainless Steel) Multi Factor*: '/(a 3 r(Radius/12)2 x3A x7,481 Casing Volume: gallons Cal, 3 Volumes; I3` $ gallons Pump Intake: 't 39 ft Purge Information / Date Purged: q f�/ O' f al Start: 00 Finish; jfu 5- purge Rate: 1300"`�'l�r'�` Purging Method: 1 e6 S1Akk1 c Pca,7z� _ Total Volume Purged: Sampling Information { Date Collected., _/ a� f �I Time Collected;_ / ( nl pro) Sampling Equipment Used: E:CJ 5A eC4,V instrument ID: Y� �p�53 +i/lt "771W Bottle Type Preservation Analysis Required NCO ML Qd.S5 pip 4K, L(nOdaS l art ae'� SO ecA,tiAj (— )Sj� AAL C, "S HMO, Field Measurements/Observations Sample Temp (°C): ,_ 1$• / Time:_J (5-0 _Turbidity (ntu); Time; C (5�0 Diss Oxy (mg/L), d • 7 Thne. Fe 2+ mg/Li Time: Specific Cond. (uS): oZ$ $. Time: Res. Cl (ring/L)/(ltg/L): Tune: Sample pFt (s.u.): Za__ Time: Odor:___. ReDox (mV): a Tune: Appearance C(0gf - Irene ReDox (EH value):YSI ProPlus +200mV Older: ® Time General/WeatherObservations: Temp.,_67_,(°F) Sampler Signature Stabilization Test Spec. Volume Time Purged Temp. Q (C) Diss Oxy. (mgfT..} Cond. pl-I (s.u.) ReDox (mV) Turbidity (ntu) removed (gallons/ 1�/ Water level (ft) Other (US) L flly (�6,.0 o 'J 3 l I L( 5-av Waa too tw R, f8•o .0 t a-S S00 hl.aaa a r " , 1o4. 1. 7 q.at, ( Oil7,2 1 7.a $. ©. ]Nxmnent Name: Document Issued: March H, 2019 r {� Field Data Sheet Phgeeiafa Document Number: F-CAR-FLD-001.rev.03 Issueing Authority; Pace Huntersvitte Quality office Client: �/ r Location; V0011, MG Project: BQ O com1 c Co. Afe-Ly LF Well ID: _Mw— ) / DR Reviewed Date and By: 4 Stabilization Test Well Diameter Multiplication Factor" 1 0.0408 1.2 0,0918 1.625 DIM 2 0.1630 3 0.3670 d 0.653...- 0 6 1A680 8 2.6100 Time Purged Temp.Di u (C) Ox . Y (mg/L) Spec. Cond. (us) pH (s.u.) ReDox (mV) Turbidity' (t nu) Volume Re ved (gallons /L circle one ) Water level (ft) Other 35 IS, L4 g, Lf 7,2 $ /. 95a6 11130 INri 1%, 3 0,'7 0.5 7-t ,3 1,3 3000 M-33 000 !�'ZeAnalyfical@ PACE ANALYTICAL SERVICES, LLC 106 Vantage Point Drive - West Columbia, SC 29172 Telephone No. 803-791-9700 Fax No. 803-791-9111 www.pacelabs.com Number c(fan" Report to Contact Telephone No. / E-maul Quote No. Address Sampler's Signature Analysis (Attach list it more space is needed) X Page_of City State Zip Code Lot#BarCode Printed Name fish use only) Project Name PrQfect No. P.Q.y. No. a Matrix No of coniamem Ag by Preservative Type Sample to/Description caltection Collection time Remarks /Cooler I.D. foreach simple maybe combined on we final Date(e) (Military)(Containers C < Turn Around Time Required (Pruirlab approval required fareApediled TAT) Sample Disposal Possible Hazard Identification QC Requirements (Specify) 12 Standard — Rush (Specify) El Return to Client El Oisposal by Lab 0 Non -Huard 0 Flammable 0 Skin Irritant 0 Poison FJ Unknown 1. Relinquished by Date Time I- Received by Date Time 2. Relinquished by Date Time 2- Received by Date Time 3. Relinquished by Date Time 3. Received by Date Time 4. Relinquished by Date Time 4. Laboratory received by Date Time Note: All samples are retained for four weeks from receipt LAB USE ONLY Temp Blank _1 Y 0 N Unless other arrangements are made. Received on ice (Circle) Yes No Ice Pack � Receipt Temp.—'C DISTRIBUTION." WHITE & YELLOW -Return to laboratory with Sample(s), PINK-Field/Client Copy Document Number ME003N2-01 � Document Name: Field data Sheet Date Issued: March 8, 2019 /:.f'aceRrkzgrEFEaiL Pa e: 1 of Document Number: F-CAR-FLD-001-rev.03 - Issuing Authority: Pace Huntersville Quality. rr�_ Office Field Data Sheet Name and Affiliation Data Sheet Review: Name and Affiliation (Inspector): /J I Date: I f q 8 - a / Well information Well ID: -S L'i b Welllocki vFc i 0 r F > � Well Diameter: Total Well Depth: Static Water Level: ft Height of Water Column: ft Co ee a ee Multi Factor*: - (*(Radius/12)2 x 3.14 x 7.481. Casing Volume: gallons Cal. 3 Volumes: gallons Pump Intake: ft Purge Information Date Purged: / - ./ . Start: ' Finish: Purge Rate: Lk= S- ., i By: DQC Purging Method: V Total Volume Purged: (gallons/mis/L) Sampling Information Date Collected:.0'-1 /D -i- k Time Collected:. t i I (,� 4�vpm) Sampling Equipment Used: Instrument ID;y sz �c5 itsicco i Pw €G �Q yn� Bottle Type Preservation Analysis Required Ix)l,mCnL34CA A P,T (" FU cC y 3Yijor nl vta(5 (Ac AJC /P0Z r21 rt1 y& °fv`on D-xcl(1rnLvlaaXa,.0— Field Measurements/Observations Sample Temp (oC): 1 1 3 Time: l Q Turbidity (ntu): ( L4 � Time: f) I Q Digs Oxy (mg/L): ) i Time: NQ_ Fe 2+ mg/L: Time: Specific Cond. (uS): 3a Time: (__Res. Cl (mg/L)/(µg/L): -' Time:. Sample pH (sx.): g ' Time: (11 Odor: N-r) Time: It ReDox (mV): Time: (l1 Appearance: -I w r Time: t. tt n ReDox (EH value):YSI ProPlus +200mV aSQ- ( Other: � Time: -� General/WeatherObservations kLPS : 3 i-Ia23g9n � 'Y'l, 64 o301 ai0 ( i y/cloudy/rainy) Temp. 7X (°F) Wind (mph) Sampler Signature Stabilization Test Time Purged Temp. (C) Digs Oxy. (mg/L) Spec. Cond. (US) pH (s.u.) ReDox (mV) Turbidity (ntu) volume removed (gallons/mis/ Water level (ft) Other [hxumm�t Namc. Field data Sheet. Date lsauedi March 8, 2019 ...-8CEA1871}RiCa( Page: 1 of 1 nitcament Number F CAR-FL.D-001-rev.03 Issain Authoru Pace Htmtersville ualit 8 9 Y ?` Office Field Data Sheet 51-9- Name and Affiliation (Sampler(s): r)D5 - r G2_ Name and Affiliation (Inspector): A) Well Information Well ID: Well Diameter: Total Well Depth: ft Static Water Level ft Height of Water Column: ft Purge information Well Locked: Data Sheet Reviews Date: gllag�al Construction: (PYJZASteel/StaiulessSteel) Multi Factor*: r*(Radius/12)2x3.140.481 Casing Volume: gallons Cal.3 Volumes: — gallons Pump lni<1ke: ft Date Purged. Start:Finish: — Purge Rate: Purging' Method:_ Total Volume Purged: (gallons/mis/L) Sarnpling_Hiformation I o 15 Date Collectec :0'/ /A/:2D2 % Time Collected:, _ ( n `irn) Sampling Equipment Used: (r fo lam- JS etl_Z6..Lt Instrument ID: t 5 3.9 710 }&Z-5 Bottle Type Preservation Analysis Required I X 2 So r PIaS+ ! AIA) 0 j 3 XI-/e) /-K I-✓` _Nc n.)c o c ZXYo ML_ ✓;o I HC I (1 (4 ;oxo.r•e_ Field Measurements/Observations QQ Sample Temp (°C): ___(. 3_Time: ILI 1 7..__Turbidity (ntu): �� • -6 Time: 1015 Digs Oxy (mg/L): • d Time: 10 1 5 Fe 2+ mg/L: — Time: ��qg Specific Cond. (uS):102. 0 Time: (01 5 Res. Cl (n1g/L)&g/ L): —Time: Sample pH (s.u.)< 6 . �, Tit ie: _ l n i 5 Odor:IO I S N.._P.... ._—Time: __. ._...._ ReDox (mV): Thne: ( d 1 5 Appearance: clew lime: 10 1 f ReDox (EH value):YSI ProPlus +20gmV A O-1 •1 Other: Time: — General/Weather Observations_ SW 1 e G (7S-- 35.2 3 Z9 9% - YZ . 6 Z6 22,6 _ (s t�nl>�¢cloudy/rainy) Temp.i5 CF) Wind 2-6 (mph) Sampler Signature:, __,_Date: 0:ZO-XI Stabilization Test F 5L0 Time Purged Temp. (C) Digs Oxy. (mg/L) Spec. Cond. (us) pH (s.u.) ;ReDox (mV) Turbidity (ntu) Volume removed (gallons/mis/ WaterQ level (ft) Other -3 .0. — — Document Name: Field data Sheet Date Issued: March 8, 2019 Page, 1 CBfVIaII?fEef� of Number: F-CAR-FLD-001-rev.03 Issuing Authority: Pace Hunterwille Quality. ;` i .Document Office Field Data Sheet Client: DLC- UU/1G- two Location: LvmProject #:OU0 Name and Affiliation (Sampler(s): l D S - 604C2 _ Field Data Sheet Review: Name and Affiliation (Inspector): Al Well Information Date: Q`2 Ia I Well ID: W - Well Lacked: (*96 }ashmmrrttj Well Diameter: Construction: (P'v CrteelTStaatiess 6teel) Total Well Depth: ft Static Water Level: :�ft Height of Water Column: —ft Multi Factor*: - r(Radius/12)2x3.14a7.48]. Casing Volume: gallons.-. Cal. 3 Volumes: — gallons Pump Intake: ft By: Purge Information Date Purged: / . Start: Finish: Purge Rate: Purging Method: Total Volume Purged: (gallons/mis/L) Sampling Information Date Collected: Of—/ /%�/ _� Time Collected: 1105 t�Opm) Sampling Equipment Used: G—ro.� Instrument ID: ,c�3°/ 1/r-gs) -40`Z 3- LF 9 L j Bottle Type Preservati6n Analysis Required IJ/ZScs rv,.L_ A/lJOa NG Inge=*, -,A JSo�t-,�6 zl ?i X *'I o Yh- t. V ; o. l f{ G I n/ �J m I/oc +-�bF. ylf ►'#=w+.rt}- 2xyo MU vib-I fac I i,ti o;oxo Field Measurements/Observations Sample Temp (°C): .le' - 0 Time: 1105 Turbidity (ntu): g ' S Time: Diss Oxy (mg/L): 11.4 Time: 1 1 O 5 Fe 2+ mg/L: '— Timer Specific Cond. (uS): 169 • Time:. 11 0 5 Res. 0 (mg/L)/(µg/L): Time:. Sample pH (s.u.): _,� _q Time: 0 0 5 Odor: ^j O Time: I l 0 5 ReDox(mV): 6305 -Tim e:1l05 Appearance: CtTime: ll05 ReDox (EH value):YSI ProPlus + 0 mV 2 Other: Time: General/Weather Observations:W� V. . %P_S Sampler Signature Stabilization Test ,rainy) Temp. 6 U ff) Wind - Z 6 Za'Z I Time Purged Temp. Cq Diss Oxy. (mg/L) Spec. (us' • pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/mis/ Water level (ft) Other a iv. d 11.q Document Name: Field data Sheet Date Issued: March 8, 2019 /per C efd�a . Page: 1 of t - Number: F•CAR-FLD-001-rev.03 - Issuing Authority: Pace Huntersvilte Quality / 1 .Document Office Name and Affiliation Data Sheet Review: Name and Affiliation (Inspector): A) iO� Date: p tta8 �a\ Well Information Well ID: S W - 3 WellLocked: ( YES-/-N& j-Fivstmm= j- Well Diameter: -- --- Construction: ( ee a ) Total Well Depth: Static Water Level: ft Height of Water Column: — ft Purge Information Multi Factor": [*(Radius/12)2 x 3.14 x 7.481 Casing Volume: gallons Cal. 3 Volumes: gallons Pump Intake: ft 0 At44NA(- L 9= 5l,� Date Purge Start: ruti fi Purge Rate: Purging Method: ---� Total Volume Purged: (gallons/mis/L) Sampling Information Date Collecfed:p� / 4 Time Collected: ('-D 5 (am/In Sampling Equipment Used:Instrument ID: f/ 3 `��?�.l) Ui2sk Bottle T e 3�tom L v.�r~ l 'LY qO 07 L J,, Field Measurements/Observations Preservation HC1 Analysis Required Sample Temp Cq: .21 . Z Time: t ZO S Turbidity (ntu): 49. O Time: l Z 037 Digs Oxy (mg/L): U 3 Time: 1205 Fe 2+ mg/L: Time: Specific Cond. (uS): Time: t 2®. g' Res. Cl (mg/L)/(µg/L): ® Time:. Sample pH (s.u.): $ • ' Time: I ZO Odor: Zee.Gb.aIff Time: 12 6 5 ReDox(mV): %7-3 Time: 1205 Appearance: Gte Time: 120 ReDox(EH value):YSIProPlus+200mV Zr6yZ.'� Other: Time: General/Weather Observations: S (A) -!It Sampler Signature. Stabilization Test -z-6-Z Wind 5-1 b (mph) Time Purged Temp. o (C) Digs Oxy. (mg/L) Spec. Cond. (US) pH (s.u.) (mV) Turbidity (ntu) Volume removed (gallons/mis/ L Water level (ft) Other lcR I.1� 6 1000 8'. K. - `1 ` - L1 / ..�aCerNwfyNeal"- t Document Name: Field data Sheet Date Issued: March 8, 2019 Pa : 1 of� .Document NumbAr: F-CAR-FL0.001-rev.03 Issuing Authority: Pace Huntersville Quality. Office . Field Data Sheet silent: yr G - vunt - t -,0 - Location: WP aU Name and Affiliation (Sampler(s): � os - PcLGC_ Name and Affiliation (Inspector): N A Well Information Well ID: S Well Diameter: Total Well Depth: Static Water Level: Et Height of Water Column: ft Purge Information Data Sheet Review: Date: pKla-g l-�, l By: Well Locked: ( t ) Construction: (PVC-/Eited/9taia}ess Steel) Multi Factor": ["(Radius/12)2 x 3.14 x 7.48] Casing Volume: gallons Cal. 3 Volumes: gallons Pump Intake: ft Date Purged Start: "— Finish: --Purge Rate: _ Purging Method: Tot al VolumePurged: (gallons/cols/L) Samuline information Date Collected-C!SL46/ -r2Cak Time Collected: 13/0 (am/to Sampling Equipment Used: &COD Instrument ID:_ 39 Zrft »#foZ3 Bottle Type Preservati4m Analysis Required /.Jt-2 S a mG lVG Pt e"4260, 1S 2x'40 M 4 ✓ A 1 `I c I ftj Field Measurements/Observations Sample Temp (°C):. l b - b Time: f310 Turbidity (ntu): L13 . Time: (3 ) 0 Dins Oxy (mg/L): ( Time: 1310 Fe 2+ mg/L: -: Time: Specific Cond. (uS): 33S • d Time: 1310 Res. Cl (mg/L)/(µg/L): `�Time:. Sample pH (s.u.): • % Time: (310 Odor: A V S Time: 1316 ReDox(mV): Time: 131d Appearance: C(ov Time: 1310 ReDox (EH value):YSI ProPlus +200mV 1/09, Z. Other: Time: — General/Weather Observations: S. (Al - L[ e r P$ . 3 $. -7- ZZy ( 1 sunnyZcloudy/rainy) Temp. (°F) Wind 5 "1d (mph) Sampler Signature, Stabilization Test LP XQ Time Purged Temp. (oq Dies Oxy. (mg/L) Spy' � S) • pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/mis/ L Water level (ft) Other DA.c Ib- 6 67, 1 3 :� 1 3. 0 `— Document Name: Field data Sheet Date Issued: March 8, 2019 Pa : 1 a, .� aCt3r'I/la/,yfisAl-y Document Number. F-CAR-FLD-001-rev.03 Issuing Authority: Pace Huntersville Quality, Office . Client: Qr-b - L7uoL-- L4, Location:k0mv..ttt i1 Project#:Kin C Go A-Gi Name and Affiliation (Sampler(s):i PaC.2— Field Data Sheet Review: Name and Affiliation (Inspector): N(4— — ^— ` Date:` �$I a By: Well Information Well ID: S w - WellLocked: (YES-7LP9 Fltisknl nt ) Well Diameter: Construction: (PdC-/ 67e Stainless Steel) Total Well Depth: ft MultiFactor": [•(Radius/12)2 x 3.14 x 7.48] Static Water Level: _ ft Casing Volume: gallons. Height of Water Column: ft Cal. 3 Volumes: — gallons Pump Intake: ft Purge Information Date Purged:-4.--7�Start : — Finish: — Purge Rate. Purging Method: Total Volume Purged: (gallons/mis/L) Saurviine Information (-F S t.0 Date Collected:2f /Rk6/Time Collected: t1-40 (am/o Sampling Equipment Used: 6t'a.-6 Instrument ID: t/ 37IA� Bottle Type Preservation Analysis Required /Ywm m L e/,k 57 t- </n)01 "C— AP4� AQta,1 S 3a'Yc� r t L 1/,`-, l K C( ^k APP1- ✓ottrt+rai�yr� ++ten )-Kctoyr1L Vial H(, l lacl D;,Nx-ahx Field Measurements/Observations Sample Temp (oq: . 1 3.3 Time: I No Turbidity (ntu): Time: Diss Oxy (mg/L): T _ 51 Time: (Z�Fe 2+mg/L: Time: Specific Cond. (uS):A1 156 Time: (20 Res. CI (mg/LY(µg/L): '—�Time:. �— Sample pH (s.u.): 15.0 Time: l�Odor: LP.e./i( P4L, Time: 1zq6 ReDox (mV): Time: ] jq0 Appearance: _ 4&�� Time: ZLJ d ReDox (EH value):YSI ProPlus +200mV Other: Time: General/Weather Observations: s w - sums loudy/rainy) Temp. 1 (°F) Wind 5-to (mph) Sampler Signature Stabilization Test Time Purged Temp. (C) Dias Oxy. (mg/L) Spec. Cond. (u5) pH (s.u.) ReDox (mV) Turbidity (ntu) volume removed (gallons/mis/ Water level (ft) Other '1_ b. � Document Name: Field data Sheet Date Issued: March 8, 2019 /:.f'aceRrkzgrEFEaiL Pa e: 1 of Document Number: F-CAR-FLD-001-rev.03 - Issuing Authority: Pace Huntersville Quality. rr�_ Office Field Data Sheet Name and Affiliation Data Sheet Review: Name and Affiliation (Inspector): /J I Date: I f q 8 - a / Well information Well ID: -S L'i b Welllocki vFc i 0 r F > � Well Diameter: Total Well Depth: Static Water Level: ft Height of Water Column: ft Co ee a ee Multi Factor*: - (*(Radius/12)2 x 3.14 x 7.481. Casing Volume: gallons Cal. 3 Volumes: gallons Pump Intake: ft Purge Information Date Purged: / - ./ . Start: ' Finish: Purge Rate: Lk= S- ., i By: DQC Purging Method: V Total Volume Purged: (gallons/mis/L) Sampling Information Date Collected:.0'-1 /D -i- k Time Collected:. t i I (,� 4�vpm) Sampling Equipment Used: Instrument ID;y sz �c5 itsicco i Pw €G �Q yn� Bottle Type Preservation Analysis Required Ix)l,mCnL34CA A P,T (" FU cC y 3Yijor nl vta(5 (Ac AJC /P0Z r21 rt1 y& °fv`on D-xcl(1rnLvlaaXa,.0— Field Measurements/Observations Sample Temp (oC): 1 1 3 Time: l Q Turbidity (ntu): ( L4 � Time: f) I Q Digs Oxy (mg/L): ) i Time: NQ_ Fe 2+ mg/L: Time: Specific Cond. (uS): 3a Time: (__Res. Cl (mg/L)/(µg/L): -' Time:. Sample pH (sx.): g ' Time: (11 Odor: N-r) Time: It ReDox (mV): Time: (l1 Appearance: -I w r Time: t. tt n ReDox (EH value):YSI ProPlus +200mV aSQ- ( Other: � Time: -� General/WeatherObservations kLPS : 3 i-Ia23g9n � 'Y'l, 64 o301 ai0 ( i y/cloudy/rainy) Temp. 7X (°F) Wind (mph) Sampler Signature Stabilization Test Time Purged Temp. (C) Digs Oxy. (mg/L) Spec. Cond. (US) pH (s.u.) ReDox (mV) Turbidity (ntu) volume removed (gallons/mis/ Water level (ft) Other Document Name: Field data Sheet Date Issued: March 8, 2019 rA/tAEyElCal'� '• `V Page: I . Document Number: F-CAR-FLD-001-cev.03 Issuing Authority: Pace Huntersvilte Quality. Olfice Yield 17ata Sheet Name and Affiliation (Sampler(s):_ JDS- PAee, Name and Affiliation (Inspector): NPV Well Information Well ID: S W Well Diameter: Total Well Depth: Static Water Level: ft Height of Water Column: ft AC+-.`ve, LF SW Field Data Sheet Review: Date: Q`lla1 BY qc�)— Well Locked: ( YES NQ ,1 at. et.. 1) Construction (PVC-t9teuVStaadess6twZ Multi Factor": r(Radius/l2)2 x 3.14 x 7.48]. Casing Volume: gallons. Cal. 3 Volumes: gallons Pump Intake: ft Purge Information Date Purged: / art : `- Finish: Purge Rate: Purging Method: �— Total VolumePurged: (gallons/mis/L) Samulin¢ Information Date Collected:0�/;Lb/_49V Time Collected: 11 Z T_ Qpm) Sampling Equipment Used: Cr- rm;.� Instrument ID: 3 i AP63 Bottle Type Preservatigm Analysis Required Ix-, so fnc_ Pf0 s�zc- H00 3)ON M L V.a NGl j�/GFl T m N L(G Yk t, Vi`a H ( ( Field Measurements/Observations Sample reutp (oq: . r'l - 8 Time: 11 Z 5 Turbidity (ntu): 1 2g Time: 1► 2 5 Dias Oxy (mg/L): 1 - "4 Time: 11 Fe 2+ mg/L: Time: Specific Cond.(uS): (3 Time:, 1125 Res. CI(mg/L)/(µg/L): : Tfine:. Sample pH (s.u.): g• 5 Time: 1 1 Z$. Odor: pp Time: 11 7-5 ReDox (mV)-. I Q 6 • ( Time: 11 Z 5 Appearance: 1JB w Time: I I Zi ReDox (EH value):YSI ProPlus +200mV 3Q6 • Other: s Time: General/Weather Observations: L49W -Fla t^2- (_r $ Zis, 7g 091 _ g2- 6 333 clacl unn cloudy/rainy) Temp. 6 3 (°F) Wind 3�L(mph) Sampler Signature Stabilization Test Time Purged Temp. (°C) Diss Oxy, (mg/L) Spec. Cond.PH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/mis/ Water level (ft) Other DU :CA _rJ 3, 7 sl9 s_ ► z�. riBBlle7Rfy#ICi1 Document Name Fidd data Sleet Hate Issued: March S, 2019. Page: I of Document Number F CRR-FI..D-001-ecv.03 Issuing Authority: Pace Huntersville Quality' Office Field Data Sheet l� Client; 6LC—`�ltil.. CO. Location. WGetyP�4�l Ne Projectt#;QtnG GO Rest%" F Name and Affiliation (Sampler(s): ,;)iD s - PQ C2 Field Data Sheet Review: Name and Affiliation (Inspector): N/-lc Date: nyh�)al By: L Well Information Well ID: W - Well Locked; (YBS- -NeY j-Pfushrammt Well Diameter: — Construction: ( el)+ Total Well Depth: It Multi Factor*: '— ['(Radius/12)2 x 314 xa.a8] Static Water Level• `— ft Casing Volume: gallons Height of Water Column: = ft Cal 3 Volumes: gallons Pump Intake: "— ft Purge Information Date Purged: I Start : Finish: Purge Rate: Purging Method: Total Volume Purged: (gallons f n11sfl) Sampling Information Date Collected:':�'yfZb/ za?-1 Time Collectedjd`1CJ..___(Gpm) Sampling Equipment Used: G tab Instrument ID: V 93:44FO 3e/ %-ffW 023 Bottle Type Preservation Analysis Required p p #irt5t7 ,�L P�4]11'C �lNoa Nc A 3,Y�10 f4CA17MVoL -r4�raWdrojZreyi 2( KO in V)t H C I11 �►o:o�lat.� Field Measurements/observations Sample Temp (°C): } O. 0 Time:: 10' 1 O _ Turbidlty (ntu): 6 3. 3 Time: 10 a 0- Diss Oxy (mg/L): 6 Time: 10 tl 0 Fe 2+ mgf L: Time: Specific Cond. (uS): 3501- 0 Time: (0 H 0 Res. CI (ing/L)&g/L)- 'rime: _ Sample pH (s.u,); _ ___ _ Time: I p q 0 Odor:---....-" line: O y 0 _ ReDox (mV): Z -) Time: 10!f O Appearance: _ C f o u 0fJe Time: (OLIO ReDox (EH vatue):YS# ProPlus +200mV 211.1 Other: '— Time: General/WeatherObservations_$w - L G-Ps: 3G.1U159S. ,-VZ. 6442354 rainy) Sampler Signature Stabilization Test Wind 5' ll (mph) Time Purged Temp. (IC) Diss Oxy. (mg/1) Spec. Cond.PI1(s.u.} ReDox (mV) Turbidity (ntu) Volume removed (gallons/mis/ L Water level (ft) Other ZeAnalyticalo` PACE ANALYTICAL SERVICES, LLC 106 Vantage Point Drive - West Columbia, SC 29172 Telephone No. 803-791-9700 Fax No. 803-791-9111 www.pacelabs.com Number 0 C!7� Client Report to Contact Telephone No. /E-maif Quote No. k Address Samplers Signature Analysis (Attach list if more space is needed) X Page_ ' of City State ZIP Code Lot # Bar Code Printed Name (tab So only) PMjectName Project No. P.O. No. malrb, No of Comainam by Preservative Type Sample ID Description Collection Collection Time g :2 Z3 'a (Contamers; breach sample maybe combirred on me fine.) Dale(S) Remarks Cooler I.D. iI - i4 t�11. Turn Around Time Required (Prior lab approval required larinWedded TAT) Sample Disposal Possible Hazard Identification QC Requirements (Specily E Standard - Rush (S)Vcily)- 1:1 Return to Client ;-3 Disposal by Lab Lj Non -Hazard D Flammable El Skin Irritant 0 Poison 0 Unknown 1. Relinquished by Date Time 1. Received by Date Time 2. Relinquished by Date Time 2. Received by Date Time S. Relinquished by Date Time 3. Received by Date Time 4- Relinquished by Date Time 4. Laboratory received by Date Time Note: All samples are retained for four weeks from receipt LAB USE ONLY Tania Blank El Y [IN unless other arrangements are made. Received on ice (Circle) yea No Ice Pack Receipt Temp.- °C I DISTRIBUTION: WHITE & YELLOW -Return to laboratory with Sample(s); PINK-Field/Client-Copy Document Number. ME0031\12-01 ace Anai(Xical PACE ANALYTICAL SERVICES, LLC 106 Vantage Point Drive - West Columbia, SC 29172 Telephone No. 803-791-9700 Fax No. 803-791-9111 www-pacelabs.com ' Number I Client Report to Contact Telephone No. I E-mail Quote No. Address Sampler's Signatures. ------ x Analysis (Attach list Amore space is needed) Pageof city State y✓Printed Zip Code 7? 1 Lot#BarCode (lab use only) Name Project Name Project No. P.O. No. m Matrix No of Containers by Preservative Type Sample ID Description (Contsimes for each sample maybe combinedon me hns) Collection 0.1hictian Date(s) time (Military)Q 23 Remarks Couter 1. D. Turn Around Time Required (Prior lab approval required for expedited TAT) E Standard = Rush (Specify) El Sample Disposal Return to Client El Disposal lyLab Possible Hazard Identification El Non -Hazard El Flammable 0 Skin Irritant 0 Poison 0 Unknown OC Requirements (Specify) 1. Relinquished by, Date Time 1. Received by Date 7une 2. Relinquished by Date Time 2. Received by Date Time 3. Relinquished by Date Time 3. Received by Date Time 4. Relinquished by Date Time 4. Laboratory received by Date Time Note: All samples are retained for four weeks from receipt unless other arrangements are made. LAB USE ONLY Received on ice (Circle) Yes No Ice Pack Receipt Temp. C Temp Blank n Y 0 N , i DISTRIBU770N. WHITE & YELLOW -Return to laboratory with Sample(s), PINK-Field/Client Copy Document Number ME003N2-01 Document Name: Field data Sheet Date Issued: March 9, 2019 E@A/h7lyl±C,2l Page:. 1 oft Drcument Number: F-CAR-P[.,T7-001-cgv:Q3 lasuiag Authority: Pace Rtmtersville Quality _ Office Name and Affiliation (Sampler(s): �O5 (�. Name and Affiliation (Inspector): IV A Well Information Wen iD: L D Well Diameter: Total Well Depth: It Static Water Level: Height of Water Column: �ft Purgelnformation, Date Purged:% Start Field Data Sheet Field Data Sheet Review: / Date: Q,,, �� t By: O Well Locked: (F, 4)' Construction: (R ee a e., el) Multi Factor*; r(Radius/12)2 x 3.14 x 7.481 Casing Volume: gallons CaL 3 Volumes; gallons Pump Intake: ft Finish: — - Purge Rate: Purging Method: Total Volume Purged: (gallons/tnls/1;) Sampling Information Date Collected: 04 Time Collected:_ 1 5 3U_' ,_ (am Sampling Equipment Used: Instrument ID:5r- W033c? / -reW,49OZ3 Bottle Type 1X250 rnL- Plosf c. 3xyo m t_ Preservation _AlAA0 3 NG / Analysis Required. _ vim Rpt-�=_ rvte)t5" S Field Measurements/Qbservations 2 Sample Temp (°C) 0 - 6 Time:. (S 30_ Turbidity (ntu) NI 6 - T Time: 15 3m piss Oxy (mg/4 H - I Time: 15 3 O Fe 2+ mg/L: Inc:T SpecificCond. (uS): �J09 Time 1 530 Res. C1,(mg/L)/(ltg/L): Time: Sample pH (sat.): �� �'�, . Time: 1530 ReDox (mV): Time: ( 5 -50 Appearance: � vdc Oran dime: t 5 3O ReDox (EH value):YSI ProPlus +2OOmV_FI'W'f-0 Other: Time: General/Weather Observations: LD - 1 . L D I Qom. Jc *nz7 Sampler Signature Stabilization Test Temp.-*" i" CF) Oq-26 -7-e21 Time Purged(C) Temp. CC) Diss Oxy. (nlgfl,) Sped. Cond. (u5j pH (s.u.) ReDox (,,IV) Turbidity (ntu) Volume removed (gaT1ons/mTs/ L Water ..level (ft) Other Do '%a f •5 9-2 1501 -Z1-o q6- — Document Name: Field data Sheet Date Issued: March 8, 2014" aceAnatylica! Page;. 1 of i Document Number. F CAR-FI.D-001-rev.03 Issubrg. Authouty: Pace Huntersviite Quality t Office Field Data Sheet Name and Affiliation (Sampler(s): S QS - 6-C� Name and Affiliation (Inspector): /VP Well Information Well ID: I- D - Z Well Locked: Well Diameter: Total Well Depth: ft Static Water Level: _ ft Height of Water Column: ft Data Sheet Review: Date: q (�BIal Construction: ( e teel) Multi Factor`: -[•(Radius/12)2x3.14x7.48] Casing Volume: gallons CaL 3 Volumes: gallons Pump Intake, 1t Purge Information Date Purged: Start : Finish: Purge Rate: ,(-4tcv - • Purging Method: Total Volume Purged: (gallons/n11s/L) Sampling Information Date Coilected.CeY /.4/_ alPM) lrTime Collected: 5 CI _ _ (m IA Sampling Equipment Used: � A Instrument ID: �� 39 / ice ?,7,� Bottle Type Preservation Analysis Required Field Measurements/Observations Sample Temp (°C): ��Tin1e: 15 (5,__Turbidity (ntu} � y 1- Time: 1 5 167 Diss Oxy (mg/L): S , 5 Time: 1 5 15 Fe 2+ mg/L: I Time: Specific Cond. (uS): 91&.0 Time: t 5 15 Res. Cl (m'g'/"L))&g/L): —Time: Sample pH(s,u.): 6.0_ Time: 1515 Odor: _ v! war`�� L__ Time: l 515 ReDox (mV); Time: 1516 Appearance: ��U t 'iime: 1515 ReDox (EH value):YSI ProPlus +200mV Other: — Time: General/Weather Observations: "D a . umt Ioudy/rainy) Temp. 77 (°F) Wind 5'10 (mph) Sampler Signature:� - 2 _Date: ( �— Stabilization Test Time Purgers Temp. (C) Diss Oxy. (mg/L) Spec. Cond. (u) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/m1s/ L Water level (ft) Other Document Name: Field data Sheet Date lssued:March 8, 2019Page. 2 j aCaAtkllyB6a1 of Document Number. FLAR-CAR-007-eev.QS� Issuing Authmnty: Pace Huntersville Quality Office Name and Affiliation Name and Affiliation (Inspector): IV P>�— -- Well Information Well ID: �,- Well Diameter: Total Well Depth: Static Water Level: ft Height of Water Column: ft Data Sheet Review: Date: 9-) ail>i Well Locked: Construction: (PVCjSfeMlstainless-Steel) Multi Factor*: ("(Radius/12)2x3:14x7.481 Casing Volume: —� gallons CaL 3 Volumes; '-- gallons Pump Intake- ft PurgeInformation Date Purged:TT — StartFinish; — Purge Rite: �— Purging Method: r-- Total Volume Purged: �- (gallons/mis/L) Sampling Information Date Collected:oey /26/2epJ Time Collected:_1610 _ . _ (am/pm Sampling Equipment Used: aI Instrument ID:_ Bottle Type Preservation Analysis Required J XZ S© m L_ b9%103 _ _L/L. A�� .,....W`4u, 3x�lc rn L r/-r� ( yc I AIG 6P4uo c Field Measurements/Observations /{ Sample Tem� p(°C):�5 Time,ij_1,0_ Turbidity(ntu): Tiure: 16(� Diss Oxy (mg/L): 3 O Time: 10 Fe 2+ mg/L: Time: �— Specific Cond. (uS): 5`� I Time: 16 (0 Res. Cl'(mg/L)/(µg/L): 'rime: Sample pH (s.u.): _ �_ Time: l C2 Odor:__ ReDox (mV): g 1 Time: It'? Appearance: ReDox (EH value):YSI ProPlus +200mv_,J 1 % . R Other: -- Time: General/Weather Observations• L D - 3 , Sampler Signature Stabilization Test 'rainy) -7L. F LD Time Purged Temp. (°C) Diss Oxy. (mg/L) Spec,. Cond. PH (s.u.) ReDox (mV) Turbidity (ntu) oume removed (gallons/cols/ L Water level (£t)(us Other V. 1 7 Document Name: Field data Shcet. Date Issued: March 8, 2014. Page: OGBAfi<?I}�17Cr1f 1 of 17ocument lVumher E CAR-F•I,.n-06l-rev:03 Issuing Authority: Pace Huntersville Quality ..,.. I Office t('� Field Data Sheet Client; 8�' O u tl C - CO Location: Ved.v, fy + tltt —Project ii: Bun e • ce) Name and Affiliation (Sampler(s): PC. CP Field Data Sheet Review: Name and Affiliation (Inspector): WellInformation Date.O�1By. Well ID: L. D — 4 Well Lockett: ( us t-) Well Diameter: Construction: (PY4"� ' , Steel) Total Well Depth: ft Multi Factor*c ("(Radiva/12)20.14x7.481 Static Water Level: '— 'ft Casing Volume. gallons Heightof Water Column: � ft Cai.3 Volumes: gallons Pump Intake: ft Purge Inforrmation Date Purged• tart: Finish: Purge Rate: Purging Method: Total Volume Purged: (gallons/mis/L) Sampling Information Date Collected:C" /4/02 Time Collected: Sampling Equipment Used: 8a: le X Instrument ID: Bottle Type Preservation Analysis Required Field Measurements/Observations Sample Temp (aC):�Time: �b _..___Turbidity (ntu): Time: �(> Diss Oxy (mg/L): �`` Time: (b 3 0 Fe 2+ mg/L �- Time: Specific Cond. (uS): 33C� J Time: 't 30 Res. CI (mg/L)/(µg/L): Trine: Sample pH (s.u.): 6 Time: 1630 Odor:_ . _ Tune: _._ f b 30 ReDox (mV): i Time: 1610 0 Appearance: CleAK � O�mte: f i 30 ReDox (EH value):YSI ProPlus +20QmV t47 , G Other: Time: --- Oeneral/WeatherObservations: Liz—" U Sampler Signature Stabilization Test -U-Zo2 / Wind 6 —11 (mph) Time Purged Temp. Q (C) Diss Oxy. (mg/L) Spec. Cond. (us) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/mts/ L Water level (ft) Other ►.L) a_b -- Document Name: Field data Sheet Date Issued: March 8, 2019 aceAnalyFieal' - Page, 1 of i Document Number: F-CAR-FLD-001-rev.03 ��8 Authority: Pace Huntersville Quality. ., . Office Field Data Sheet Name and Affiliation (Sampler(s): ab S • Pa Q Name and Affiliation (Inspector): IV A Well Information WelltD: . LD Well Diameter: Total Well Depth: ft Static Water Level: ft Height of Water Column: � ft Data Sheet Review: Date: q�By: Well Locked: (4rs ra-/-M 7-F ul s ftoo ) Construction: (UVjC46Me1fStain1ess-&teal) Multi Factor*: [*(Radius/12)2 x 3.14 it 7A8]. Casing Volume: gallons Cal. 3 Volumes: — gallons Pump Intake: ft Purge Information Date Purged Start : Finish: — Purge Rate: Purging Method: Total Volume Purged: (gallons/mis/L) Ye-LF Lb Sampling Information Date Collected: t! / r9 jTime Collected: r� r) (am/ m) Sampling Equipment Used: R ck 4e _r Instrument ID:y SZ 33q I-TFLO *qoz3 Bottle Type /)4 C) M L PJ4Si C_. Preservation "Nov, t/GI Analysis Required C NC PrAf = VC Field Measurements/Observations Sample Temp (°C): I I p Time:�Turbidity (ntu): '7 Time: f NI Diss Oxy (mg/L): - 11 Time: 1J b Fe 2+ mg/L: Time:. Specific Cond. (uS): _ Time I © Res. Cl (mg/L)&g/L): Time:: Sample pH (s.u.): 6 . `� Time: tJ d . Odor: P-(Time: jq10 ReDox (mV): I. j 3: 3 Time: 11) 0 Appearance: C I Peo,�7 Time: I fI I d ReDox (EH value):YSI ProPlus +200mV Other: Time: General/Weather Observations: L () S. _4 yncicudy/rainy) Temp. �4k (OF) Wind 6-I1 (mph) Sampler Signature, Stabilization Test Time Purged Temp. (°C) Dtss Oxy. (mg/L) Spec. Cond. pH (s.u.)ntu) ;eDbidity Volume removed (gallons/mis/ Water level (ft)Other 1 . . J - Document Name! Field data Sheet Date Issued: March g, 2019 Page: 1 of 1 aceArkTtyNc7f Document Number. F-CAR-FI:i7-p01-eev.63 Issuing Authority: Face Huntersville Quality Office Field Data Sheef Client:01 1-- - 1[Su(IC, (_O Location: -We, tsw Name and Affiliation (Sampler(s): 4X S - Paa.ce_ Name and Affiliation (Inspector): Al,( Well Information Well ID: LD - 1b Well Locked: Well Diameter: Total Well Depth: _ ft Static Water Level: ft Height of Water Column: =:::� ft Field Data Sheet Review: Date: ��t l �B t By: SM - Construction: (P*C , e am ess Steel) Multi Factor*: — 1(Aadius/12)2z3.14x7.4el Casing Volume: gallons Cal. 3 Volumes: '— gallons I'ump Intake: I ft Purge' Information Date Purged-.---,!'--- / Start : Finish: Purge Rate: Purging Method: Total. Volume Purged: _ (gallons/cols/L) Sampling Information Date Collected: Cq! f `L�bf Oct - Sampling Equipment Used: k .%A Bottle Type lX2Sa rn I- I'laSi, L 3,Yyo v»La 1 Field Measurements/Observations Time Collected: A6 l S (an pr InstrumentlD t/S:3-.-W053`l �l`Rnl Preservation Analysis Required _ Aalo Z O&C Sample Temp (°C); Time; Ib �l _ Turbidity (ntu): 3. �i Time: Diss Oxy (mg/L): 5 Time: I ti Fe 2+ mg/ Li Time: '— Specific'Cond. (uS): Time: lb' l 5 Res. CI(mg/L)/(ltg/I:) 'rime: Sample pH (sat.): 0.5 , Time: 16 Odor,.___ Akv $_ _ _Tune:.9 _ ReDox (mV): - �) . a Time: 16 t16 Appearance: N( f� . rime: ) 6 fi 7r ReDox (EH value):YSI ProPlus +200mV 115: `d Other: Time: General/Weather Observations: L. D - 4:> e Sampler Signature:_,, V - �v _Date: I"( - `z6 ` Stabilization Test I-F 1-0 Time Purged Temp. ( C) DissOxy. (mg/L) Spec Cond. (US) pI-I(s.u.) ReDox (Inv) Turbidity (ntu) Volume removed (gallons/mis/ L Water level (ft) Other e ,` 1,0 - -43,ti��- ?CEAf7FtlyliCAtr Document Field data Sheet. pate Issued: March &, 2Rt9 Page: I of ihxument Number:F-CAR-fI..b-0pl rev:03 Issuing Authority: Pace Huntersville uali g. P Office tY pp Field Data Sheet ClienFclJLe- k�ttxC �. Locations Wf.je..uK..fV l6 Name and Affiliation (Sampler(s): c»S ' Pr^-C2_: Name and Affiliation (Inspector): N {4---- Well Information Well ID: Ob Well Locked: ( Y4 Well Diameter: _ Total Well Depth: ft Static Water Level:---ft Height of Water Column; =ft field Data Sheet Review: Date:: Q`-l�a--3 )) � Construction: _ ', _et) Multi Factor`: — — — — — — 'i"(Radius/12)2 x 114 x 7,481 Casing Volume; gallons Cal. 3 Volumes: gallons Pump Intake: It Purge Information Date Purged: - - - Start: Finish: Purge Rite: In Purging Method. -------- Total Volume Purged: I(gallons/m1sjL) Sampling Information Date Collected:e �j 'rime Collected: KS __ _ (am pm) Sampling Equipment Used: (roo, b Instrument ID: A-C +o-zj b , Bottle Type Preservation Analysis Required (k ZS o r" t F6v-HNo,, --«P'—�.PU,7(5,ls Field Measurements/Observations Sample Temp CC): J& Time: S S _ Turbidity (mm): 1. Z Time: l Y iS Diss Oxy (mg/L): 6,6 Time: f Lt 5 S Fe 2+ mg/L: r Time: Specific Cond. (uS); 5%6•'X Time: f5_Res. Cl(mg/L)/(leg/L)r "— Time: Sample pH (s.u.): H -6 __ . Time: f ZI S S Odor:_ N -D ___Time:. /'/ SS ReDox (mV): 106 - 1 Time: I S 5 Appearance: Cl2 d 'Time: ReDox (EH value):YSI ProPlus +200niV 30b - I Other: Time: General/Weather Observations; 1,(!�1; 5-6o-- LDe Sampler Signature Stabilization Test y) Temp. R �('F) Wind Ll .ZO? / Time Purged. Temp. a (C) Diss Oxy. (mg/I,) Spec.Volume Cond. Coared . (US) pH {s.u.} ReDox (mV) Turbidity (ntu) removed (gallons/mis/ L Water ,Level (ft) Other i5. '-I• b b. 3 I. Z Document Name: Field data Shoet bate Issued: March 8, 2R19; (tCEFUTr?!} [(t11 Page:. 1 oil Document Numher. F CAR-PI.A7-RR1 rev.R3 lssumg,Authaaty: Pace Htmtersvitle Quality Office Field Data Shee€ 4lcent: 16 L L— v V n t Locationn:y tAAe Name and Affiliation (Samplers) ) bS - Pd:, P Name and Affiliation (Inspector);_ Al A - Well Information Well ID: LQ0,611a 2 01W Well Locked; Well Diameter: Total Well Depth: ft Static Water Level: £t Height of Water Column; � ft ald Data Sheet Review: Date:C1h b 3 b4 Construction: ("fir+ _ ;''_aidessSteel} Multi Factor*:: ("(Radius/12)2x3.14x7.48] Casing Volume. gallons Cal. 3 Volumes; gallons By: ve Pump Intake: ft Purge Information _ Date Purged: : � Start: Finish- Purge Rate: Purging Method: Total Volume Purged: (gallons/oils/ L) Sampling Information Date Collecked:CC /.26/ iil__ Time Collected: /4130(am/� JS a v-z 4 --z) Sampling Equipment Used: G-(AJ Instrument ID:4/S'T :4VTV) BGl Bottle Type / I Preservation r� p �AnaIysis Required 3— YZ) M (_ oss N C t. I - (950 4— Ptg3 rc, m Nn/0a I — I89a ML PlasF Unpres. 7 D U,wre'5 I - d5V ML Pfask- Field Measurements/Observations /I I �� Copt P0.l Sample Temp (,q: ai.7 Thne:_f�aO__Turbicilty(ntu); Time: Diss Oxy (mg/L): Time: — Fe 2+ mg/L: ^ —Time: Specific Cond. (uS): 54V Time: y_� 3a Res. Cl (mg/L)/(pg/L): 'lime: ' Sample pH(s:u.): $•3 _ _Time: ,`�.30 Odor:__ LeacAak Time::11136_ ReDox (mV): —' Time: Appearance: F"wr1 Time: _ 14 36 ReDox (EH value):YST ProPlus +200tuV — Other: Time: Wind 7 - I L(mph) Sampler Signature Stabilization Test 1 i.ewckod2., Time Purged Temp. (C) Diss Oxy. (mg/L) Spec. Cond. (US) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/mis/ L Water level (ft) Other APPENDIX B LABORATORY ANALYTICAL DATA - PACE ANALYTICAL SERVICES, LLC. 0 aceAnalytical Report of Analysis Bunnell-Lammons Engineering, Inc. 6004 Ponders Court Greenville, SC 29615 Attention: Andy Alexander Project Name: Active Buncombe County Landfill Wells Project Number: J21-9378-23 Lot Number:WD28014 Date Completed:05/11/2021 05/11 /2021 3:25 PM Approved and released by: Project Manager II: Lucas Odom PCCRF� 24rA SOA / ANSI National Accreditation Board A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 166 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Bunnell-Lammons Engineering, Inc. Lot Number: WD28014 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 whw.pacelabs.com Page 2 of 166 PACE ANALYTICAL SERVICES, LLC Sample Summary Bunnell-Lammons Engineering, Inc. Lot Number: WD28014 Sample Number Sample ID Matrix Date Sampled Date Received 001 MW-1 Aqueous 04/26/20211335 04/27/2021 002 MW-1D Aqueous 04/26/20211215 04/27/2021 003 MW-3R Aqueous 04/26/20211130 04/27/2021 004 MW-4 Aqueous 04/26/20211250 04/27/2021 005 MW-4D Aqueous 04/26/20211535 04/27/2021 006 MW-5 Aqueous 04/26/20211625 04/27/2021 007 MW-10 Aqueous 04/26/20211540 04/27/2021 008 MW-1OD Aqueous 04/26/20211640 04/27/2021 009 MW-2 Aqueous 04/27/20211415 04/28/2021 010 MW-21D Aqueous 04/27/20211440 04/28/2021 011 MW-51D Aqueous 04/27/20211025 04/28/2021 012 MW-6 Aqueous 04/27/20211135 04/28/2021 013 MW-7 Aqueous 04/27/20211245 04/28/2021 014 MW-12 Aqueous 04/27/20211510 04/28/2021 015 MW-12D Aqueous 04/27/20211545 04/28/2021 016 MW-13 Aqueous 04/27/20211545 04/28/2021 017 MW-13D Aqueous 04/27/20211510 04/28/2021 018 MW-11D Aqueous 04/27/20211555 04/28/2021 019 MW-15 Aqueous 04/27/20211325 04/28/2021 020 MW-15D Aqueous 04/27/20211409 04/28/2021 021 Trip Blank Aqueous 04/27/2021 04/28/2021 022 MW-8 Aqueous 04/28/20210955 04/29/2021 023 MW-8D Aqueous 04/28/20211035 04/29/2021 024 MW-11 Aqueous 04/28/20211300 04/29/2021 025 MW-14 Aqueous 04/28/20211010 04/29/2021 026 MW-14D Aqueous 04/28/20211100 04/29/2021 027 MW-17R Aqueous 04/28/20211030 04/29/2021 028 MW-17DR Aqueous 04/28/20211150 04/29/2021 029 Field Blank Aqueous 04/28/2021 1200 04/29/2021 (29 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 166 PACE ANALYTICAL SERVICES, LLC Detection Summary Bunnell-Lammons Engineering, Inc. Lot Number: WD28014 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 MW-1 Aqueous Alkalinity @ pH 4.5 su SM 232013- 62 mg CaCO3/L 9 001 MW-1 Aqueous Chloride 9056A 6.4 mg/L 9 001 MW-1 Aqueous Sulfate 9056A 18 mg/L 9 001 MW-1 Aqueous TDS SM 2540C- 150 mg/L 9 001 MW-1 Aqueous Acetone 8260D 8.2 J ug/L 9 001 MW-1 Aqueous Barium 6020B 150 ug/L 11 001 MW-1 Aqueous Chromium 6020B 2.1 J ug/L 11 001 MW-1 Aqueous Iron 6020B 130 ug/L 11 001 MW-1 Aqueous Manganese 6020B 2.5 J ug/L 11 001 MW-1 Aqueous Vanadium 6020B 3.1 J ug/L 11 001 MW-1 Aqueous Zinc 6020B 6.4 J ug/L 11 002 MW-1 D Aqueous Alkalinity @ pH 4.5 su SM 232013- 81 mg CaCO3/1- 12 002 MW-1D Aqueous Chloride 9056A 2.5 mg/L 12 002 MW-1D Aqueous Sulfate 9056A 42 mg/L 12 002 MW-1D Aqueous TDS SM 2540C- 170 mg/L 12 002 MW-1D Aqueous Antimony 6020B 0.77 J ug/L 14 002 MW-1D Aqueous Barium 6020B 33 ug/L 14 002 MW-1D Aqueous Chromium 6020B 33 ug/L 14 002 MW-1D Aqueous Copper 6020B 1.8 J ug/L 14 002 MW-1D Aqueous Iron 6020B 480 ug/L 14 002 MW-1D Aqueous Manganese 6020B 14 ug/L 14 002 MW-1D Aqueous Nickel 6020B 19 ug/L 14 002 MW-1D Aqueous Zinc 6020B 3.0 J ug/L 14 003 MW-3R Aqueous Barium 6020B 45 ug/L 16 003 MW-3R Aqueous Chromium 6020B 4.1 J ug/L 16 003 MW-3R Aqueous Nickel 6020B 3.4 J ug/L 16 003 MW-3R Aqueous Vanadium 6020B 3.6 J ug/L 16 003 MW-3R Aqueous Zinc 6020B 5.4 J ug/L 16 004 MW-4 Aqueous Barium 6020B 80 ug/L 18 004 MW-4 Aqueous Nickel 6020B 5.0 ug/L 18 004 MW-4 Aqueous Zinc 6020B 5.9 J ug/L 19 005 MW-41D Aqueous Barium 6020B 51 ug/L 21 005 MW-41D Aqueous Vanadium 6020B 3.0 J ug/L 22 006 MW-5 Aqueous Barium 6020B 130 ug/L 24 006 MW-5 Aqueous Chromium 6020B 19 ug/L 24 006 MW-5 Aqueous Nickel 6020B 24 ug/L 24 006 MW-5 Aqueous Vanadium 6020B 2.6 J ug/L 24 006 MW-5 Aqueous Zinc 6020B 3.1 J ug/L 24 007 MW-10 Aqueous Barium 6020B 110 ug/L 26 007 MW-10 Aqueous Chromium 6020B 1.5 J ug/L 26 007 MW-10 Aqueous Cobalt 6020B 2.9 J ug/L 26 007 MW-10 Aqueous Copper 6020B 3.2 J ug/L 26 007 MW-10 Aqueous Nickel 6020B 8.0 ug/L 26 007 MW-10 Aqueous Zinc 6020B 4.2 J ug/L 27 008 MW-1OD Aqueous 1,1-Dichloroethane 8260D 0.68 J ug/L 28 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 166 Detection Summary (Continued) Lot Number: WD28014 Sample Sample ID Matrix Parameter Method Result Q Units Page 008 MW-1OD Aqueous cis- 1,2-Dichloroethene 8260D 0.55 J ug/L 28 008 MW-1OD Aqueous Barium 6020B 26 ug/L 29 008 MW-1OD Aqueous Chromium 6020B 1.5 J ug/L 29 008 MW-1OD Aqueous Nickel 6020B 11 ug/L 29 008 MW-1OD Aqueous Vanadium 6020B 2.5 J ug/L 30 009 MW-2 Aqueous Barium 6020B 190 ug/L 32 009 MW-2 Aqueous Cadmium 6020B 0.13 J ug/L 32 009 MW-2 Aqueous Cobalt 6020B 10 ug/L 32 009 MW-2 Aqueous Nickel 6020B 33 ug/L 32 009 MW-2 Aqueous Zinc 6020B 8.8 J ug/L 32 010 MW-21) Aqueous Barium 6020B 110 ug/L 34 010 MW-21D Aqueous Chromium 6020B 1.8 J ug/L 34 010 MW-21D Aqueous Nickel 6020B 1.4 J ug/L 34 010 MW-21D Aqueous Vanadium 6020B 2.5 J ug/L 34 011 MW-51) Aqueous Barium 6020B 77 ug/L 36 011 MW-51D Aqueous Chromium 6020B 1.4 J ug/L 36 011 MW-51D Aqueous Nickel 6020B 4.0 J ug/L 36 012 MW-6 Aqueous Barium 6020B 56 ug/L 38 012 MW-6 Aqueous Chromium 6020B 1.3 J ug/L 38 013 MW-7 Aqueous Acetone 8260D 5.3 J ug/L 39 013 MW-7 Aqueous 2-Butanone (MEK) 8260D 5.1 J ug/L 39 013 MW-7 Aqueous cis- 1,2-Dichloroethene 8260D 0.42 J ug/L 39 013 MW-7 Aqueous Barium 6020B 170 ug/L 40 013 MW-7 Aqueous Cobalt 6020B 1.4 J ug/L 40 013 MW-7 Aqueous Nickel 6020B 9.7 ug/L 40 014 MW-12 Aqueous Alkalinity @ pH 4.5 su SM 232013- 270 mg CaCO3/1- 41 014 MW-12 Aqueous Chloride 9056A 44 mg/L 41 014 MW-12 Aqueous Sulfate 9056A 330 mg/L 41 014 MW-12 Aqueous TDS SM 2540C- 820 mg/L 41 014 MW-12 Aqueous 1,4-Dioxane 8260D (SIM) 2.6 J ug/L 41 014 MW-12 Aqueous Tetrahydrofuran 8260D 6.1 ug/L 42 014 MW-12 Aqueous Barium 6020B 120 ug/L 43 014 MW-12 Aqueous Chromium 6020B 3.5 J ug/L 43 014 MW-12 Aqueous Cobalt 6020B 38 ug/L 43 014 MW-12 Aqueous Copper 6020B 4.4 J ug/L 43 014 MW-12 Aqueous Iron 6020B 770 ug/L 43 014 MW-12 Aqueous Manganese 6020B 3300 ug/L 43 014 MW-12 Aqueous Nickel 6020B 37 ug/L 43 014 MW-12 Aqueous Zinc 6020B 4.0 J ug/L 43 015 MW-12D Aqueous Alkalinity @ pH 4.5 su SM 232013- 190 mg CaCO3/1- 44 015 MW-12D Aqueous Chloride 9056A 13 mg/L 44 015 MW-12D Aqueous Sulfate 9056A 68 mg/L 44 015 MW-12D Aqueous TDS SM 2540C- 320 mg/L 44 015 MW-12D Aqueous 1,4-Dioxane 8260D (SIM) 1.2 J ug/L 44 015 MW-12D Aqueous Tetrahydrofuran 8260D 1.4 J ug/L 45 015 MW-12D Aqueous Barium 6020B 49 ug/L 46 015 MW-12D Aqueous Chromium 6020B 1.4 J ug/L 46 015 MW-12D Aqueous Cobalt 6020B 3.9 J ug/L 46 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 166 Detection Summary (Continued) Lot Number: WD28014 Sample Sample ID Matrix Parameter Method Result Q Units Page 015 MW-12D Aqueous Iron 6020B 630 ug/L 46 015 MW-12D Aqueous Manganese 6020B 860 ug/L 46 015 MW-12D Aqueous Nickel 6020B 4.4 J ug/L 46 016 MW-13 Aqueous Barium 6020B 190 ug/L 48 016 MW-13 Aqueous Cobalt 6020B 28 ug/L 48 016 MW-13 Aqueous Nickel 6020B 7.6 ug/L 48 017 MW-13D Aqueous Barium 6020B 220 ug/L 50 017 MW-13D Aqueous Cobalt 6020B 18 ug/L 50 017 MW-13D Aqueous Nickel 6020B 8.8 ug/L 50 018 MW-11D Aqueous Barium 6020B 74 ug/L 52 018 MW-11D Aqueous Copper 6020B 1.3 J ug/L 52 018 MW-11D Aqueous Nickel 6020B 4.6 J ug/L 52 018 MW-11D Aqueous Zinc 6020B 12 ug/L 52 019 MW-15 Aqueous Alkalinity @ pH 4.5 su SM 232013- 300 mg CaCO3/1- 53 019 MW-15 Aqueous Chloride 9056A 27 mg/L 53 019 MW-15 Aqueous Sulfate 9056A 34 mg/L 53 019 MW-15 Aqueous TDS SM 2540C- 380 mg/L 53 019 MW-15 Aqueous 1,4-Dioxane 8260D (SIM) 9.4 ug/L 53 019 MW-15 Aqueous Tetrahydrofuran 8260D 1.9 J ug/L 54 019 MW-15 Aqueous Barium 6020B 240 ug/L 55 019 MW-15 Aqueous Cobalt 6020B 79 ug/L 55 019 MW-15 Aqueous Iron 6020B 70000 ug/L 55 019 MW-15 Aqueous Manganese 6020B 11000 ug/L 55 019 MW-15 Aqueous Nickel 6020B 10 ug/L 55 019 MW-15 Aqueous Zinc 6020B 3.3 J ug/L 55 020 MW-15D Aqueous Alkalinity @ pH 4.5 su SM 232013- 360 mg CaCO3/1- 56 020 MW-15D Aqueous Chloride 9056A 86 mg/L 56 020 MW-15D Aqueous Sulfate 9056A 140 mg/L 56 020 MW-15D Aqueous TDS SM 2540C- 750 mg/L 56 020 MW-15D Aqueous 1,4-Dioxane 8260D (SIM) 36 ug/L 56 020 MW-15D Aqueous Acetone 8260D 7.6 J ug/L 56 020 MW-15D Aqueous Benzene 8260D 0.54 J ug/L 56 020 MW-15D Aqueous 1,2-Dichloroethane 8260D 0.57 J ug/L 57 020 MW-15D Aqueous cis- 1,2-Dichloroethene 8260D 0.53 J ug/L 57 020 MW-15D Aqueous Tetrahydrofuran 8260D 3.1 J ug/L 57 020 MW-15D Aqueous Vinyl chloride 8260D 2.6 ug/L 57 020 MW-15D Aqueous Barium 6020B 140 ug/L 58 020 MW-15D Aqueous Beryllium 6020B 0.28 J ug/L 58 020 MW-15D Aqueous Cobalt 6020B 4.7 J ug/L 58 020 MW-15D Aqueous Iron 6020B 1700 ug/L 58 020 MW-15D Aqueous Manganese 6020B 1300 ug/L 58 020 MW-15D Aqueous Nickel 6020B 44 ug/L 58 020 MW-15D Aqueous Zinc 6020B 9.6 J ug/L 58 022 MW-8 Aqueous 2-Butanone (MEK) 8260D 2.6 J ug/L 61 022 MW-8 Aqueous Barium 6020B 150 ug/L 62 022 MW-8 Aqueous Chromium 6020B 4.6 J ug/L 62 022 MW-8 Aqueous Copper 6020B 1.7 J ug/L 62 022 MW-8 Aqueous Lead 6020B 0.32 J ug/L 62 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 166 Detection Summary (Continued) Lot Number: WD28014 Sample Sample ID Matrix Parameter Method Result Q Units Page 022 MW-8 Aqueous Nickel 6020B 4.1 J ug/L 62 022 MW-8 Aqueous Zinc 6020B 3.8 J ug/L 62 023 MW-81D Aqueous 2-Butanone (MEK) 8260D 3.2 J ug/L 63 023 MW-81D Aqueous Antimony 6020B 0.63 J ug/L 64 023 MW-81D Aqueous Barium 6020B 180 ug/L 64 023 MW-81D Aqueous Chromium 6020B 2.8 J ug/L 64 023 MW-81D Aqueous Lead 6020B 0.50 J ug/L 64 023 MW-81D Aqueous Nickel 6020B 4.4 J ug/L 64 023 MW-81D Aqueous Zinc 6020B 5.3 J ug/L 64 024 MW-11 Aqueous 2-Butanone (MEK) 8260D 3.4 J ug/L 65 024 MW-11 Aqueous Barium 6020B 97 ug/L 66 024 MW-11 Aqueous Cobalt 6020B 3.2 J ug/L 66 024 MW-11 Aqueous Copper 6020B 2.9 J ug/L 66 024 MW-11 Aqueous Lead 6020B 0.55 J ug/L 66 024 MW-11 Aqueous Nickel 6020B 44 ug/L 66 024 MW-11 Aqueous Zinc 6020B 6.2 J ug/L 66 025 MW-14 Aqueous Alkalinity @ pH 4.5 su SM 232013- 62 mg CaCO3/1- 67 025 MW-14 Aqueous Chloride 9056A 2.8 mg/L 67 025 MW-14 Aqueous Sulfate 9056A 22 mg/L 67 025 MW-14 Aqueous TDS SM 2540C- 140 mg/L 67 025 MW-14 Aqueous Barium 6020B 50 ug/L 69 025 MW-14 Aqueous Iron 6020B 91 ug/L 69 025 MW-14 Aqueous Nickel 6020B 1.8 J ug/L 69 026 MW-14D Aqueous Alkalinity @ pH 4.5 su SM 232013- 140 mg CaCO3/1- 70 026 MW-14D Aqueous Chloride 9056A 4.0 mg/L 70 026 MW-14D Aqueous Sulfate 9056A 31 mg/L 70 026 MW-14D Aqueous TDS SM 2540C- 210 mg/L 70 026 MW-14D Aqueous Acetone 8260D 6.7 J ug/L 70 026 MW-14D Aqueous Barium 6020B 5.2 ug/L 72 026 MW-14D Aqueous Iron 6020B 200 ug/L 72 026 MW-14D Aqueous Manganese 6020B 5.2 ug/L 72 026 MW-14D Aqueous Zinc 6020B 2.8 J ug/L 72 027 MW-17R Aqueous Alkalinity @ pH 4.5 su SM 232013- 72 mg CaCO3/1- 73 027 MW-17R Aqueous Chloride 9056A 3.0 mg/L 73 027 MW-17R Aqueous Sulfate 9056A 33 mg/L 73 027 MW-17R Aqueous TDS SM 2540C- 140 mg/L 73 027 MW-17R Aqueous Barium 6020B 63 ug/L 75 027 MW-17R Aqueous Copper 6020B 2.1 J ug/L 75 027 MW-17R Aqueous Iron 6020B 160 ug/L 75 027 MW-17R Aqueous Manganese 6020B 25 ug/L 75 027 MW-17R Aqueous Nickel 6020B 11 ug/L 75 027 MW-17R Aqueous Zinc 6020B 3.2 J ug/L 75 028 MW-17DR Aqueous Alkalinity @ pH 4.5 su SM 232013- 120 mg CaCO3/1- 76 028 MW-17DR Aqueous Chloride 9056A 4.1 mg/L 76 028 MW-17DR Aqueous Sulfate 9056A 24 mg/L 76 028 MW-17DR Aqueous TDS SM 2540C- 190 mg/L 76 028 MW-17DR Aqueous 2-Butanone (MEK) 8260D 2.3 J ug/L 76 028 MW-17DR Aqueous Barium 6020B 66 ug/L 78 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 166 Detection Summary (Continued) Lot Number: WD28014 Sample Sample ID Matrix Parameter Method Result Q Units Page 028 MW-17DR Aqueous Iron 6020B 320 ug/L 78 028 MW-17DR Aqueous Manganese 6020B 38 ug/L 78 (191 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-001 Description: MW-1 Matrix: Aqueous Date Sampled:04/26/2021 1335 )ate Received:04/27/2021 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 04/29/2021 2103 DAK 90721 1 (Chloride) 9056A 1 05/01/2021 0441 AMR 91006 1 (Sulfate) 9056A 1 05/01/2021 0441 AMR 91005 1 (TDS) SM 2540C-2011 1 05/02/2021 1747 MOM 90916 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 62 20 20 mg CaCO3/L 1 Chloride 9056A 6.4 1.0 0.25 mg/L 1 Sulfate 9056A 18 1.0 0.25 mg/L 1 TDS SM 254OC-2011 150 25 25 mg/L 1 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20210159 CJL2 91468 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 8.2 J 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-001 Description: MW-1 Matrix: Aqueous Date Sampled:04/26/2021 1335 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20210159 CJL2 91468 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 103 70-130 1,2-Dichloroethane-d4 105 70-130 Toluene-d8 108 70-130 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 05/05/2021 0709 JAB2 05/04/2021 0602 91048 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-001 Description: MW-1 Matrix: Aqueous Date Sampled:04/26/2021 1335 Date Received:04/27/2021 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2021 2157 BNW 04/29/2021 0948 90580 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 150 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 2.1 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 130 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 2.5 J 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 3.1 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 6.4 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-002 Description: MW-1D Matrix: Aqueous Date Sampled:04/26/2021 1215 )ate Received:04/27/2021 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 04/29/2021 2110 DAK 90721 1 (Chloride) 9056A 1 05/01/2021 0501 AMR 91006 1 (Sulfate) 9056A 1 05/01/2021 0501 AMR 91005 1 (TDS) SM 2540C-2011 1 05/02/2021 1747 MOM 90916 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 81 20 20 mg CaCO3/L 1 Chloride 9056A 2.5 1.0 0.25 mg/L 1 Sulfate 9056A 42 1.0 0.25 mg/L 1 TDS SM 254OC-2011 170 25 25 mg/L 1 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20210223 CJL2 91468 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-002 Description: MW-1D Matrix: Aqueous Date Sampled:04/26/2021 1215 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20210223 CJL2 91468 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 103 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 108 70-130 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 05/05/2021 0711 JAB2 05/04/2021 0602 91048 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-002 Description: MW-1D Matrix: Aqueous Date Sampled:04/26/2021 1215 Date Received:04/27/2021 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2021 2203 BNW 04/29/2021 0948 90580 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 0.77 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 33 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 33 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.8 J 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 480 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 14 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B 19 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.0 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-003 Description: MW-3R Matrix: Aqueous Date Sampled:04/26/2021 1130 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20210246 CJL2 91468 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-003 Description: MW-3R Matrix: Aqueous Date Sampled:04/26/2021 1130 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20210246 CJL2 91468 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 105 70-130 1,2-Dichloroethane-d4 105 70-130 Toluene-d8 109 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2021 2209 BNW 04/29/2021 0948 90580 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 45 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 4.1 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 3.4 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 3.6 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 5.4 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 16 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-004 Description: MW-4 Matrix: Aqueous Date Sampled:04/26/2021 1250 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/30/2021 0011 JDF 90730 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 95 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20210310 CJL2 91468 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 17 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-004 Description: MW-4 Matrix: Aqueous Date Sampled:04/26/2021 1250 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20210310 CJL2 91468 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 103 70-130 1,2-Dichloroethane-d4 105 70-130 Toluene-d8 108 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2021 2215 BNW 04/29/2021 0948 90580 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 80 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 5.0 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 18 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-004 Description: MW-4 Matrix: Aqueous Date Sampled:04/26/2021 1250 Date Received:04/27/2021 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2021 2215 BNW 04/29/2021 0948 90580 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 Silver 7440-22-4 Thallium 7440-28-0 Vanadium 7440-62-2 Zinc 7440-66-6 6020B ND 5.0 1.3 ug/L 1 6020B ND 1.0 0.25 ug/L 1 6020B ND 0.50 0.15 ug/L 1 6020B ND 5.0 2.5 ug/L 1 6020B 5.9 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 19 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-005 Description: MW-4D Matrix: Aqueous Date Sampled:04/26/2021 1535 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/30/2021 0036 JDF 90730 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 94 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20211051 BWS 91517 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 20 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-005 Description: MW-4D Matrix: Aqueous Date Sampled:04/26/2021 1535 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20211051 BWS 91517 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 100 70-130 1,2-Dichloroethane-d4 103 70-130 Toluene-d8 106 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2021 2221 BNW 04/29/2021 0948 90580 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 51 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 21 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-005 Description: MW-4D Matrix: Aqueous Date Sampled:04/26/2021 1535 Date Received:04/27/2021 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2021 2221 BNW 04/29/2021 0948 90580 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 3.0 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 22 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-006 Description: MW-5 Matrix: Aqueous Date Sampled:04/26/2021 1625 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20211115 BWS 91517 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 23 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-006 Description: MW-5 Matrix: Aqueous Date Sampled:04/26/2021 1625 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20211115 BWS 91517 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 103 70-130 1,2-Dichloroethane-d4 105 70-130 Toluene-d8 108 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2021 2227 BNW 04/29/2021 0948 90580 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 130 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 19 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 24 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 2.6 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.1 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 24 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-007 Description: MW-10 Matrix: Aqueous Date Sampled:04/26/2021 1540 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/30/2021 0101 JDF 90730 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 93 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20211140 BWS 91517 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 25 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-007 Description: MW-10 Matrix: Aqueous Date Sampled:04/26/2021 1540 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20211140 BWS 91517 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 101 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 108 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2021 2233 BNW 04/29/2021 0948 90580 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 110 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.5 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 2.9 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 3.2 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 8.0 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 26 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-007 Description: MW-10 Matrix: Aqueous Date Sampled:04/26/2021 1540 Date Received:04/27/2021 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2021 2233 BNW 04/29/2021 0948 90580 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 Silver 7440-22-4 Thallium 7440-28-0 Vanadium 7440-62-2 Zinc 7440-66-6 6020B ND 5.0 1.3 ug/L 1 6020B ND 1.0 0.25 ug/L 1 6020B ND 0.50 0.15 ug/L 1 6020B ND 5.0 2.5 ug/L 1 6020B 4.2 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 27 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-008 Description: MW-10D Matrix: Aqueous Date Sampled:04/26/2021 1640 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/03/2021 1339 TML 90981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 88 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20211205 BWS 91517 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.68 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 0.55 J 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 28 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-008 Description: MW-10D Matrix: Aqueous Date Sampled:04/26/2021 1640 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20211205 BWS 91517 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 105 70-130 1,2-Dichloroethane-d4 106 70-130 Toluene-d8 110 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2021 2239 BNW 04/29/2021 0948 90580 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 26 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.5 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 11 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 29 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-008 Description: MW-10D Matrix: Aqueous Date Sampled:04/26/2021 1640 Date Received:04/27/2021 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2021 2239 BNW 04/29/2021 0948 90580 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 2.5 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 30 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-009 Description: MW-2 Matrix: Aqueous Date Sampled:04/27/2021 1415 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/20212110 BWS 91625 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 31 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-009 Description: MW-2 Matrix: Aqueous Date Sampled:04/27/2021 1415 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/20212110 BWS 91625 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 103 70-130 1,2-Dichloroethane-d4 96 70-130 Toluene-d8 99 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2021 1414 BNW 04/30/2021 0355 90649 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 190 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.13 J 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 10 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 33 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 8.8 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 32 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-010 Description: MW-2D Matrix: Aqueous Date Sampled:04/27/2021 1440 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/20212132 BWS 91625 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 33 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-010 Description: MW-2D Matrix: Aqueous Date Sampled:04/27/2021 1440 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/20212132 BWS 91625 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 94 70-130 1,2-Dichloroethane-d4 96 70-130 Toluene-d8 97 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2021 1456 BNW 04/30/2021 0355 90649 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 110 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.8 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 1.4 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 2.5 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 34 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-011 Description: MW-5D Matrix: Aqueous Date Sampled:04/27/2021 1025 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/20212155 BWS 91625 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 35 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-011 Description: MW-5D Matrix: Aqueous Date Sampled:04/27/2021 1025 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/20212155 BWS 91625 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 98 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2021 1502 BNW 04/30/2021 0355 90649 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 77 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.4 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 4.0 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 36 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-012 Description: MW-6 Matrix: Aqueous Date Sampled:04/27/2021 1135 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/20212217 BWS 91625 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 37 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-012 Description: MW-6 Matrix: Aqueous Date Sampled:04/27/2021 1135 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/20212217 BWS 91625 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 101 70-130 1,2-Dichloroethane-d4 96 70-130 Toluene-d8 98 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2021 1508 BNW 04/30/2021 0355 90649 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 56 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.3 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 38 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-013 Description: MW-7 Matrix: Aqueous Date Sampled:04/27/2021 1245 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/20212239 BWS 91625 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 5.3 J 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D 5.1 J 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1, 1 -Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis-1,2-Dichloroethene 156-59-2 8260D 0.42 J 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 39 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-013 Description: MW-7 Matrix: Aqueous Date Sampled:04/27/2021 1245 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/20212239 BWS 91625 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 92 70-130 1,2-Dichloroethane-d4 95 70-130 Toluene-d8 96 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2021 1514 BNW 04/30/2021 0355 90649 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 170 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 1.4 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 9.7 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 40 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-014 Description: MW-12 Matrix: Aqueous Date Sampled:04/27/2021 1510 Date Received:04/28/2021 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 04/29/2021 2152 DAK 90722 1 (Chloride) 9056A 5 05/01/2021 0521 AMR 91006 1 (Sulfate) 9056A 5 05/01/2021 0521 AMR 91005 1 (TDS) SM 2540C-2011 1 05/02/2021 1747 MOM 90916 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 270 20 20 mg CaCO3/L 1 Chloride 9056A 44 5.0 1.3 mg/L 1 Sulfate 9056A 330 5.0 1.3 mg/L 1 TDS SM 2540C-2011 820 25 25 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/30/2021 0125 JDF 90730 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 2.6 J 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 93 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/20212302 BWS 91625 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 41 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-014 Description: MW-12 Matrix: Aqueous Date Sampled:04/27/2021 1510 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/20212302 BWS 91625 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 6.1 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 93 70-130 1,2-Dichloroethane-d4 97 70-130 Toluene-d8 94 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 42 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-014 Description: MW-12 Matrix: Aqueous Date Sampled:04/27/2021 1510 Date Received:04/28/2021 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 05/05/2021 0719 JAB2 05/04/2021 0602 91048 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2021 1520 BNW 04/30/2021 0355 90649 2 3005A 6020B 10 05/03/2021 2122 BNW 04/30/2021 0355 90649 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 120 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 3.5 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 38 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 4.4 J 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 770 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 3300 50 13 ug/L 2 Nickel 7440-02-0 6020B 37 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 4.0 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 43 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-015 Description: MW-12D Matrix: Aqueous Date Sampled:04/27/2021 1545 Date Received:04/28/2021 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 04/29/2021 2200 DAK 90722 1 (Chloride) 9056A 1 05/03/2021 1603 AMR 91067 1 (Sulfate) 9056A 1 05/03/2021 1603 AMR 91063 1 (TDS) SM 2540C-2011 1 05/02/2021 1747 MOM 90916 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 190 20 20 mg CaCO3/L 1 Chloride 9056A 13 1.0 0.25 mg/L 1 Sulfate 9056A 68 1.0 0.25 mg/L 1 TDS SM 254OC-2011 320 25 25 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/30/2021 0150 JDF 90730 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 1.2 J 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 93 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/20212325 BWS 91625 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 44 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-015 Description: MW-12D Matrix: Aqueous Date Sampled:04/27/2021 1545 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/20212325 BWS 91625 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 1.4 J 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 96 70-130 Toluene-d8 97 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 45 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-015 Description: MW-12D Matrix: Aqueous Date Sampled:04/27/2021 1545 Date Received:04/28/2021 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 05/05/2021 0722 JAB2 05/04/2021 0602 91048 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2021 1526 BNW 04/30/2021 0355 90649 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 49 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.4 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 3.9 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 630 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 860 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B 4.4 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 46 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-016 Description: MW-13 Matrix: Aqueous Date Sampled:04/27/2021 1545 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/20212347 BWS 91625 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 47 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-016 Description: MW-13 Matrix: Aqueous Date Sampled:04/27/2021 1545 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/20212347 BWS 91625 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 99 70-130 1,2-Dichloroethane-d4 95 70-130 Toluene-d8 97 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2021 1533 BNW 04/30/2021 0355 90649 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 190 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 28 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 7.6 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 48 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-017 Description: MW-13D Matrix: Aqueous Date Sampled:04/27/2021 1510 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/20210009 BWS 91625 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 49 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-017 Description: MW-13D Matrix: Aqueous Date Sampled:04/27/2021 1510 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/20210009 BWS 91625 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 94 70-130 1,2-Dichloroethane-d4 95 70-130 Toluene-d8 98 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2021 1539 BNW 04/30/2021 0355 90649 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 220 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 18 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 8.8 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 50 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-018 Description: MW-11D Matrix: Aqueous Date Sampled:04/27/2021 1555 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/20211251 TML 91650 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 51 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-018 Description: MW-11D Matrix: Aqueous Date Sampled:04/27/2021 1555 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/20211251 TML 91650 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 99 70-130 1,2-Dichloroethane-d4 96 70-130 Toluene-d8 96 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2021 1545 BNW 04/30/2021 0355 90649 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 74 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.3 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 4.6 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 12 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 52 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-019 Description: MW-15 Matrix: Aqueous Date Sampled:04/27/2021 1325 Date Received:04/28/2021 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 04/29/2021 2214 DAK 90722 1 (Chloride) 9056A 5 05/03/2021 1623 AMR 91067 1 (Sulfate) 9056A 5 05/03/2021 1623 AMR 91063 1 (TDS) SM 2540C-2011 1 05/02/2021 1747 MOM 90916 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 300 20 20 mg CaCO3/L 1 Chloride 9056A 27 5.0 1.3 mg/L 1 Sulfate 9056A 34 5.0 1.3 mg/L 1 TDS SM 2540C-2011 380 25 25 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/30/2021 0215 JDF 90730 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 9.4 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 92 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/20211313 TML 91650 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 53 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-019 Description: MW-15 Matrix: Aqueous Date Sampled:04/27/2021 1325 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/20211313 TML 91650 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 1.9 J 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 101 70-130 1,2-Dichloroethane-d4 96 70-130 Toluene-d8 99 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 54 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-019 Description: MW-15 Matrix: Aqueous Date Sampled:04/27/2021 1325 Date Received:04/28/2021 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 05/05/2021 0725 JAB2 05/04/2021 0602 91048 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2021 1551 BNW 04/30/2021 0355 90649 2 3005A 6020B 10 05/03/2021 2128 BNW 04/30/2021 0355 90649 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 240 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 79 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 70000 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 11000 50 13 ug/L 2 Nickel 7440-02-0 6020B 10 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.3 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 55 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-020 Description: MW-15D Matrix: Aqueous Date Sampled:04/27/2021 1409 Date Received:04/28/2021 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 04/29/2021 2222 DAK 90722 1 (Chloride) 9056A 5 05/03/2021 1643 AMR 91067 1 (Sulfate) 9056A 5 05/03/2021 1643 AMR 91063 1 (TDS) SM 2540C-2011 1 05/02/2021 1747 MOM 90916 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 360 20 20 mg CaCO3/L 1 Chloride 9056A 86 5.0 1.3 mg/L 1 Sulfate 9056A 140 5.0 1.3 mg/L 1 TDS SM 2540C-2011 750 25 25 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 5030B 8260D (SIM) 1 05/03/2021 1250 TML 90981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 36 3.0 1.0 ug/L 2 Run 2 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 93 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/20211337 TML 91650 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 7.6 J 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 0.54 J 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 56 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-020 Description: MW-15D Matrix: Aqueous Date Sampled:04/27/2021 1409 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/20211337 TML 91650 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.57 J 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 0.53 J 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 3.1 J 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 2.6 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 89 70-130 Toluene-d8 100 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 57 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-020 Description: MW-15D Matrix: Aqueous Date Sampled:04/27/2021 1409 Date Received:04/28/2021 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 05/05/2021 0733 JA132 05/04/2021 0602 91048 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2021 1609 BNW 04/30/2021 0355 90649 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 140 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.28 J 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 4.7 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 1700 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 1300 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B 44 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 9.6 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 58 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-021 Description: Trip Blank Matrix: Aqueous Date Sampled:04/27/2021 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/20211228 TML 91650 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 59 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-021 Description: Trip Blank Matrix: Aqueous Date Sampled:04/27/2021 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/20211228 TML 91650 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 96 70-130 99 70-130 98 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 60 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-022 Description: MW-8 Matrix: Aqueous Date Sampled:04/28/2021 0955 Date Received:04/29/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/20211400 TML 91650 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D 2.6 J 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 61 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-022 Description: MW-8 Matrix: Aqueous Date Sampled:04/28/2021 0955 Date Received:04/29/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/20211400 TML 91650 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 95 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2021 1627 BNW 05/03/2021 0426 90835 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 150 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 4.6 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.7 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.32 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 4.1 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.8 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 62 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-023 Description: MW-8D Matrix: Aqueous Date Sampled:04/28/2021 1035 Date Received:04/29/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/20212339 CJL2 91673 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D 3.2 J 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 63 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-023 Description: MW-8D Matrix: Aqueous Date Sampled:04/28/2021 1035 Date Received:04/29/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/20212339 CJL2 91673 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 102 70-130 1,2-Dichloroethane-d4 108 70-130 Toluene-d8 106 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2021 1657 BNW 05/03/2021 0426 90835 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 0.63 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 180 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 2.8 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.50 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 4.4 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 5.3 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 64 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-024 Description: MW-11 Matrix: Aqueous Date Sampled:04/28/2021 1300 Date Received:04/29/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/10/20210004 CJL2 91673 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D 3.4 J 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 65 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-024 Description: MW-11 Matrix: Aqueous Date Sampled:04/28/2021 1300 Date Received:04/29/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/10/20210004 CJL2 91673 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 101 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 108 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2021 1703 BNW 05/03/2021 0426 90835 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 97 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 3.2 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 2.9 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.55 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 44 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 6.2 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 66 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-025 Description: MW-14 Matrix: Aqueous Date Sampled:04/28/2021 1010 )ate Received:04/29/2021 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 05/01/2021 1425 DAK 90903 1 (Chloride) 9056A 1 05/03/2021 1702 AMR 91067 1 (Sulfate) 9056A 1 05/03/2021 1702 AMR 91063 1 (TDS) SM 2540C-2011 1 05/02/2021 1747 MOM 90916 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 62 20 20 mg CaCO3/L 1 Chloride 9056A 2.8 1.0 0.25 mg/L 1 Sulfate 9056A 22 1.0 0.25 mg/L 1 TDS SM 254OC-2011 140 25 25 mg/L 1 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/10/20210029 CJL2 91673 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 67 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-025 Description: MW-14 Matrix: Aqueous Date Sampled:04/28/2021 1010 Date Received:04/29/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/10/20210029 CJL2 91673 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 100 70-130 1,2-Dichloroethane-d4 108 70-130 Toluene-d8 107 70-130 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 05/05/2021 0736 JAB2 05/04/2021 0602 91048 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 68 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-025 Description: MW-14 Matrix: Aqueous Date Sampled:04/28/2021 1010 Date Received:04/29/2021 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2021 1721 BNW 05/03/2021 0426 90835 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 50 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 91 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B ND 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B 1.8 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 69 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-026 Description: MW-14D Matrix: Aqueous Date Sampled:04/28/2021 1100 )ate Received:04/29/2021 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 05/01/2021 1432 DAK 90903 1 (Chloride) 9056A 1 05/03/2021 1722 AMR 91067 1 (Sulfate) 9056A 1 05/03/2021 1722 AMR 91063 1 (TDS) SM 2540C-2011 1 05/02/2021 1747 MOM 90916 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 140 20 20 mg CaCO3/L 1 Chloride 9056A 4.0 1.0 0.25 mg/L 1 Sulfate 9056A 31 1.0 0.25 mg/L 1 TDS SM 254OC-2011 210 25 25 mg/L 1 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/10/20210054 CJL2 91673 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 6.7 J 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 70 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-026 Description: MW-14D Matrix: Aqueous Date Sampled:04/28/2021 1100 Date Received:04/29/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/10/20210054 CJL2 91673 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 101 70-130 1,2-Dichloroethane-d4 107 70-130 Toluene-d8 106 70-130 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 05/05/2021 0738 JAB2 05/04/2021 0602 91048 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 71 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-026 Description: MW-14D Matrix: Aqueous Date Sampled:04/28/2021 1100 Date Received:04/29/2021 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2021 1727 BNW 05/03/2021 0426 90835 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 5.2 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 200 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 5.2 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 2.8 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 72 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-027 Description: MW-17R Matrix: Aqueous Date Sampled:04/28/2021 1030 Date Received:04/29/2021 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 05/01/2021 1439 DAK 90903 1 (Chloride) 9056A 1 05/03/2021 1742 AMR 91067 1 (Sulfate) 9056A 1 05/03/2021 1742 AMR 91063 1 (TDS) SM 2540C-2011 1 05/02/2021 1747 MOM 90916 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 72 20 20 mg CaCO3/L 1 Chloride 9056A 3.0 1.0 0.25 mg/L 1 Sulfate 9056A 33 1.0 0.25 mg/L 1 TDS SM 254OC-2011 140 25 25 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/03/2021 2352 CJL2 91037 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 95 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/10/20210119 CJL2 91673 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 73 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-027 Description: MW-17R Matrix: Aqueous Date Sampled:04/28/2021 1030 Date Received:04/29/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/10/20210119 CJL2 91673 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 102 70-130 1,2-Dichloroethane-d4 108 70-130 Toluene-d8 107 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 74 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-027 Description: MW-17R Matrix: Aqueous Date Sampled:04/28/2021 1030 Date Received:04/29/2021 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 05/05/2021 0741 JAB2 05/04/2021 0602 91048 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2021 1733 BNW 05/03/2021 0426 90835 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 63 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 2.1 J 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 160 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 25 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B 11 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.2 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 75 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-028 Description: MW-17DR Matrix: Aqueous Date Sampled:04/28/2021 1150 Date Received:04/29/2021 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 05/01/2021 1446 DAK 90903 1 (Chloride) 9056A 1 05/03/2021 1802 AMR 91067 1 (Sulfate) 9056A 1 05/03/2021 1802 AMR 91063 1 (TDS) SM 2540C-2011 1 05/02/2021 1747 MOM 90916 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 120 20 20 mg CaCO3/L 1 Chloride 9056A 4.1 1.0 0.25 mg/L 1 Sulfate 9056A 24 1.0 0.25 mg/L 1 TDS SM 254OC-2011 190 25 25 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/04/2021 0017 CJL2 91037 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 95 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/10/20210144 CJL2 91673 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 2.3 J 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 76 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-028 Description: MW-17DR Matrix: Aqueous Date Sampled:04/28/2021 1150 Date Received:04/29/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/10/20210144 CJL2 91673 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 100 70-130 1,2-Dichloroethane-d4 106 70-130 Toluene-d8 108 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 77 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-028 Description: MW-17DR Matrix: Aqueous Date Sampled:04/28/2021 1150 Date Received:04/29/2021 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 05/05/2021 0744 JAB2 05/04/2021 0602 91048 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2021 1739 BNW 05/03/2021 0426 90835 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 66 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 320 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 38 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 78 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-029 Description: Field Blank Matrix: Aqueous Date Sampled:04/28/2021 1200 Date Received:04/29/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/20211955 CJL2 91673 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 79 of 166 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:WD28014-029 Description: Field Blank Matrix: Aqueous Date Sampled:04/28/2021 1200 Date Received:04/29/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/20211955 CJL2 91673 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 101 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 108 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2021 1745 BNW 05/03/2021 0426 90835 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B ND 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 80 of 166 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 81 of 166 Inorganic non-metals - LCS Sample ID: WQ90721-002 Matrix: Aqueous Batch: 90721 Analytical Method: SM 2320B-2011 Spike Amount Result %Rec Parameter (mg CaCO3/L) (mg CaCO3/L) Q Dil % Rec Limit Analysis Date Alkalinity @ pH 4.5 su 100 100 1 104 90-110 04/29/2021 2005 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 82 of 166 Inorganic non-metals - LCS Sample ID: WQ90722-002 Matrix: Aqueous Batch: 90722 Analytical Method: SM 2320B-2011 Spike Amount Result %Rec Parameter (mg CaCO3/L) (mg CaCO3/L) Q Dil % Rec Limit Analysis Date Alkalinity @ pH 4.5 su 100 100 1 105 90-110 04/29/2021 2145 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 83 of 166 Inorganic non-metals - Duplicate Sample ID: WD28014-015DU Matrix: Aqueous Batch: 90722 Analytical Method: SM 2320B-2011 Sample Amount Result %RPD Parameter (mg CaCO3/L) (mg CaCO3/L) 0 Dil % RPD Limit Analysis Date Alkalinity @ pH 4.5 su 190 190 1 1.4 20 04/29/2021 2207 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 84 of 166 Inorganic non-metals - LCS Sample ID: WQ90903-002 Matrix: Aqueous Batch: 90903 Analytical Method: SM 2320B-2011 Spike Amount Result %Rec Parameter (mg CaCO3/L) (mg CaCO3/L) Q Dil % Rec Limit Analysis Date Alkalinity @ pH 4.5 su 100 100 1 100 90-110 05/01/2021 1419 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 85 of 166 Inorganic non-metals - MB Sample ID: WQ90916-001 Matrix: Aqueous Batch: 90916 Analytical Method: SM 2540C-2011 Parameter Result Q Dil LOQ DL Units Analysis Date TDS ND 1 25 25 mg/L 05/02/2021 1747 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 86 of 166 Inorganic non-metals - LCS Sample ID: WQ90916-002 Matrix: Aqueous Batch: 90916 Analytical Method: SM 2540C-2011 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date TDS 1500 1500 1 99 90-110 05/02/2021 1747 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 87 of 166 Inorganic non-metals - MB Sample ID: WQ91005-001 Matrix: Aqueous Batch: 91005 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Sulfate ND 1 1.0 0.25 mg/L 04/30/2021 1923 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 88 of 166 Inorganic non-metals - LCS Sample ID: WQ91005-002 Matrix: Aqueous Batch: 91005 Analytical Method: 9056A Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 20 20 1 102 80-120 04/30/2021 2003 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 89 of 166 Inorganic non-metals - MB Sample ID: WQ91006-001 Matrix: Aqueous Batch: 91006 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Chloride ND 1 1.0 0.25 mg/L 04/30/2021 1923 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 90 of 166 Inorganic non-metals - LCS Sample ID: WQ91006-002 Matrix: Aqueous Batch: 91006 Analytical Method: 9056A Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Chloride 20 21 1 103 80-120 04/30/2021 2003 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 91 of 166 Inorganic non-metals - MB Sample ID: WQ91063-001 Matrix: Aqueous Batch: 91063 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Sulfate ND 1 1.0 0.25 mg/L 05/03/2021 1503 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 92 of 166 Inorganic non-metals - LCS Sample ID: WQ91063-002 Matrix: Aqueous Batch: 91063 Analytical Method: 9056A Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 20 20 1 102 80-120 05/03/2021 1543 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 93 of 166 Inorganic non-metals - MS Sample ID: WD28014-O28MS Matrix: Aqueous Batch: 91063 Analytical Method: 9056A Sample Spike Amount Amount Result %Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 24 10 33 1 99 80-120 05/03/2021 1822 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 94 of 166 Inorganic non-metals - MSD Sample ID: WD28014-O28MD Matrix: Aqueous Batch: 91063 Analytical Method: 9056A Sample Spike Amount Amount Result %Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Sulfate 24 10 33 1 96 1.0 80-120 20 05/03/2021 1922 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 95 of 166 Inorganic non-metals - MB Sample ID: WQ91067-001 Matrix: Aqueous Batch: 91067 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Chloride ND 1 1.0 0.25 mg/L 05/03/2021 1503 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 96 of 166 Inorganic non-metals - LCS Sample ID: WQ91067-002 Matrix: Aqueous Batch: 91067 Analytical Method: 9056A Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Chloride 20 21 1 103 80-120 05/03/2021 1543 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 97 of 166 Inorganic non-metals - MS Sample ID: WD28014-O28MS Matrix: Aqueous Batch: 91067 Analytical Method: 9056A Sample Spike Amount Amount Result %Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Chloride 4.1 10 14 1 104 80-120 05/03/2021 1822 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 98 of 166 Inorganic non-metals - MSD Sample ID: WD28014-O28MD Matrix: Aqueous Batch: 91067 Analytical Method: 9056A Sample Spike Amount Amount Result %Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Chloride 4.1 10 14 1 101 2.0 80-120 20 05/03/2021 1922 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 99 of 166 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: WQ90730-001 Matrix: Aqueous Batch: 90730 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 04/29/2021 1950 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 95 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 100 of 166 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: WQ90730-002 Matrix: Aqueous Batch: 90730 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 47 1 94 70-130 04/29/2021 1900 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 95 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 101 of 166 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: WQ90981-001 Matrix: Aqueous Batch: 90981 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 05/03/2021 1103 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 91 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 102 of 166 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: WQ90981-002 Matrix: Aqueous Batch: 90981 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 47 1 95 70-130 05/03/2021 1004 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 97 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 103 of 166 Volatile Organic Compounds by GC/MS (SIM) - Duplicate Sample ID: WD28014-008DU Matrix: Aqueous Batch: 90981 Prep Method: 5030E Analytical Method: 8260D (SIM) Sample Amount Result %RPD Parameter (ug/L) (ug/L) Q Dil % RPD Limit Analysis Date 1,4-Dioxane ND ND 1 0.00 20 05/03/2021 2038 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 88 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 104 of 166 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: WQ91037-001 Matrix: Aqueous Batch: 91037 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 05/03/2021 2257 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 93 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 105 of 166 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: WQ91037-002 Matrix: Aqueous Batch: 91037 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 46 1 93 70-130 05/03/2021 2155 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 96 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 106 of 166 Volatile Organic Compounds by GC/MS (SIM) - Duplicate Sample ID: WD28014-027DU Matrix: Aqueous Batch: 91037 Prep Method: 5030E Analytical Method: 8260D (SIM) Sample Amount Result %RPD Parameter (ug/L) (ug/L) Q Dil % RPD Limit Analysis Date 1,4-Dioxane ND ND 1 0.00 20 05/04/2021 0805 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 100 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 107 of 166 Volatile Organic Compounds by GC/MS (SIM) - MS Sample ID: WD28014-028MS Matrix: Aqueous Batch: 91037 Prep Method: 5030E Analytical Method: 8260D (SIM) Sample Spike Amount Amount Result %Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane ND 50 47 1 94 70-130 05/04/2021 0830 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 103 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 108 of 166 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91468-001 Matrix: Aqueous Batch: 91468 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 05/06/2021 2133 Acrylonitrile ND 1 20 0.80 ug/L 05/06/2021 2133 Benzene ND 1 1.0 0.40 ug/L 05/06/2021 2133 Bromochloromethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 Bromodichloromethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 Bromoform ND 1 1.0 0.40 ug/L 05/06/2021 2133 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 05/06/2021 2133 2-Butanone (MEK) ND 1 10 2.0 ug/L 05/06/2021 2133 Carbon disulfide ND 1 1.0 0.40 ug/L 05/06/2021 2133 Carbon tetrachloride ND 1 1.0 0.40 ug/L 05/06/2021 2133 Chlorobenzene ND 1 1.0 0.40 ug/L 05/06/2021 2133 Chloroethane ND 1 2.0 0.40 ug/L 05/06/2021 2133 Chloroform ND 1 1.0 0.40 ug/L 05/06/2021 2133 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 05/06/2021 2133 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 05/06/2021 2133 Dibromochloromethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 05/06/2021 2133 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 05/06/2021 2133 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 05/06/2021 2133 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 2133 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 2133 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 05/06/2021 2133 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/06/2021 2133 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/06/2021 2133 Ethylbenzene ND 1 1.0 0.40 ug/L 05/06/2021 2133 2-Hexanone ND 1 10 2.0 ug/L 05/06/2021 2133 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 05/06/2021 2133 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 05/06/2021 2133 Methylene chloride ND 1 1.0 0.40 ug/L 05/06/2021 2133 Styrene ND 1 1.0 0.41 ug/L 05/06/2021 2133 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 Tetrachloroethene ND 1 1.0 0.40 ug/L 05/06/2021 2133 Toluene ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 Trichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 2133 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 05/06/2021 2133 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 109 of 166 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91468-001 Matrix: Aqueous Batch: 91468 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 05/06/2021 2133 Vinyl chloride ND 1 1.0 0.40 ug/L 05/06/2021 2133 Xylenes (total) ND 1 1.0 0.40 ug/L 05/06/2021 2133 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 105 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 107 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 110 of 166 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91468-002 Matrix: Aqueous Batch: 91468 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 96 1 96 60-140 05/06/2021 2012 Acrylonitrile 100 98 1 98 70-130 05/06/2021 2012 Benzene 50 49 1 97 70-130 05/06/2021 2012 Bromochloromethane 50 49 1 98 70-130 05/06/2021 2012 Bromodichloromethane 50 50 1 101 70-130 05/06/2021 2012 Bromoform 50 51 1 103 70-130 05/06/2021 2012 Bromomethane (Methyl bromide) 50 50 1 100 70-130 05/06/2021 2012 2-Butanone (MEK) 100 110 1 108 70-130 05/06/2021 2012 Carbon disulfide 50 50 1 101 70-130 05/06/2021 2012 Carbon tetrachloride 50 48 1 96 70-130 05/06/2021 2012 Chlorobenzene 50 49 1 97 70-130 05/06/2021 2012 Chloroethane 50 50 1 99 70-130 05/06/2021 2012 Chloroform 50 48 1 96 70-130 05/06/2021 2012 Chloromethane (Methyl chloride) 50 46 1 92 60-140 05/06/2021 2012 1,2-Dibromo-3-chloropropane (DBCP) 50 51 1 103 70-130 05/06/2021 2012 Dibromochloromethane 50 51 1 101 70-130 05/06/2021 2012 1,2-Dibromoethane (EDB) 50 50 1 100 70-130 05/06/2021 2012 Dibromomethane (Methylene bromide) 50 49 1 99 70-130 05/06/2021 2012 trans- 1,4-Dichloro-2-butene 50 53 1 106 70-130 05/06/2021 2012 1,2-Dichlorobenzene 50 50 1 99 70-130 05/06/2021 2012 1,4-Dichlorobenzene 50 49 1 98 70-130 05/06/2021 2012 1,1-Dichloroethane 50 48 1 96 70-130 05/06/2021 2012 1,2-Dichloroethane 50 48 1 96 70-130 05/06/2021 2012 1,1-Dichloroethene 50 49 1 99 70-130 05/06/2021 2012 cis- 1,2-Dichloroethene 50 51 1 101 70-130 05/06/2021 2012 trans- 1,2-Dichloroethene 50 50 1 101 70-130 05/06/2021 2012 1,2-Dichloropropane 50 49 1 97 70-130 05/06/2021 2012 cis- 1,3-Dichloropropene 50 54 1 107 70-130 05/06/2021 2012 trans- 1,3-Dichloropropene 50 54 1 108 70-130 05/06/2021 2012 Ethylbenzene 50 52 1 103 70-130 05/06/2021 2012 2-Hexanone 100 100 1 102 70-130 05/06/2021 2012 Methyl iodide (lodomethane) 50 50 1 101 70-130 05/06/2021 2012 4-Methyl-2-pentanone 100 100 1 103 70-130 05/06/2021 2012 Methylene chloride 50 49 1 98 70-130 05/06/2021 2012 Styrene 50 53 1 107 70-130 05/06/2021 2012 1,1,1,2-Tetrachloroethane 50 49 1 98 70-130 05/06/2021 2012 1,1,2,2-Tetrachloroethane 50 48 1 96 70-130 05/06/2021 2012 Tetrachloroethene 50 49 1 98 70-130 05/06/2021 2012 Toluene 50 51 1 102 70-130 05/06/2021 2012 1,1,1-Trichloroethane 50 48 1 96 70-130 05/06/2021 2012 1,1,2-Trichloroethane 50 48 1 96 70-130 05/06/2021 2012 Trichloroethene 50 50 1 100 70-130 05/06/2021 2012 Trichlorofluoromethane 50 48 1 96 70-130 05/06/2021 2012 1,2,3-Trichloropropane 50 49 1 99 70-130 05/06/2021 2012 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 111 of 166 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91468-002 Matrix: Aqueous Batch: 91468 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 49 1 98 60-140 05/06/2021 2012 Vinyl chloride 50 48 1 96 70-130 05/06/2021 2012 Xylenes (total) 100 100 1 105 70-130 05/06/2021 2012 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 103 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 102 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 112 of 166 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91468-001 Matrix: Aqueous Batch: 91468 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 05/06/2021 2133 Acrylonitrile ND 1 20 0.80 ug/L 05/06/2021 2133 Benzene ND 1 1.0 0.40 ug/L 05/06/2021 2133 Bromochloromethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 Bromodichloromethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 Bromoform ND 1 1.0 0.40 ug/L 05/06/2021 2133 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 05/06/2021 2133 2-Butanone (MEK) ND 1 10 2.0 ug/L 05/06/2021 2133 Carbon disulfide ND 1 1.0 0.40 ug/L 05/06/2021 2133 Carbon tetrachloride ND 1 1.0 0.40 ug/L 05/06/2021 2133 Chlorobenzene ND 1 1.0 0.40 ug/L 05/06/2021 2133 Chloroethane ND 1 2.0 0.40 ug/L 05/06/2021 2133 Chloroform ND 1 1.0 0.40 ug/L 05/06/2021 2133 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 05/06/2021 2133 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 05/06/2021 2133 Dibromochloromethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 05/06/2021 2133 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 05/06/2021 2133 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 05/06/2021 2133 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 2133 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 2133 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 05/06/2021 2133 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/06/2021 2133 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/06/2021 2133 Ethylbenzene ND 1 1.0 0.40 ug/L 05/06/2021 2133 2-Hexanone ND 1 10 2.0 ug/L 05/06/2021 2133 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 05/06/2021 2133 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 05/06/2021 2133 Methylene chloride ND 1 1.0 0.40 ug/L 05/06/2021 2133 Styrene ND 1 1.0 0.41 ug/L 05/06/2021 2133 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 Tetrachloroethene ND 1 1.0 0.40 ug/L 05/06/2021 2133 Tetrahydrofuran ND 1 5.0 1.0 ug/L 05/06/2021 2133 Toluene ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 Trichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 2133 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 113 of 166 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91468-001 Matrix: Aqueous Batch: 91468 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 05/06/2021 2133 Vinyl acetate ND 1 5.0 1.2 ug/L 05/06/2021 2133 Vinyl chloride ND 1 1.0 0.40 ug/L 05/06/2021 2133 Xylenes (total) ND 1 1.0 0.40 ug/L 05/06/2021 2133 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 105 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 107 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 114 of 166 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91468-002 Matrix: Aqueous Batch: 91468 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 96 1 96 60-140 05/06/2021 2012 Acrylonitrile 100 98 1 98 70-130 05/06/2021 2012 Benzene 50 49 1 97 70-130 05/06/2021 2012 Bromochloromethane 50 49 1 98 70-130 05/06/2021 2012 Bromodichloromethane 50 50 1 101 70-130 05/06/2021 2012 Bromoform 50 51 1 103 70-130 05/06/2021 2012 Bromomethane (Methyl bromide) 50 50 1 100 70-130 05/06/2021 2012 2-Butanone (MEK) 100 110 1 108 70-130 05/06/2021 2012 Carbon disulfide 50 50 1 101 70-130 05/06/2021 2012 Carbon tetrachloride 50 48 1 96 70-130 05/06/2021 2012 Chlorobenzene 50 49 1 97 70-130 05/06/2021 2012 Chloroethane 50 50 1 99 70-130 05/06/2021 2012 Chloroform 50 48 1 96 70-130 05/06/2021 2012 Chloromethane (Methyl chloride) 50 46 1 92 60-140 05/06/2021 2012 1,2-Dibromo-3-chloropropane (DBCP) 50 51 1 103 70-130 05/06/2021 2012 Dibromochloromethane 50 51 1 101 70-130 05/06/2021 2012 1,2-Dibromoethane (EDB) 50 50 1 100 70-130 05/06/2021 2012 Dibromomethane (Methylene bromide) 50 49 1 99 70-130 05/06/2021 2012 trans- 1,4-Dichloro-2-butene 50 53 1 106 70-130 05/06/2021 2012 1,2-Dichlorobenzene 50 50 1 99 70-130 05/06/2021 2012 1,4-Dichlorobenzene 50 49 1 98 70-130 05/06/2021 2012 1,1-Dichloroethane 50 48 1 96 70-130 05/06/2021 2012 1,2-Dichloroethane 50 48 1 96 70-130 05/06/2021 2012 1,1-Dichloroethene 50 49 1 99 70-130 05/06/2021 2012 cis- 1,2-Dichloroethene 50 51 1 101 70-130 05/06/2021 2012 trans- 1,2-Dichloroethene 50 50 1 101 70-130 05/06/2021 2012 1,2-Dichloropropane 50 49 1 97 70-130 05/06/2021 2012 cis- 1,3-Dichloropropene 50 54 1 107 70-130 05/06/2021 2012 trans- 1,3-Dichloropropene 50 54 1 108 70-130 05/06/2021 2012 Ethylbenzene 50 52 1 103 70-130 05/06/2021 2012 2-Hexanone 100 100 1 102 70-130 05/06/2021 2012 Methyl iodide (lodomethane) 50 50 1 101 70-130 05/06/2021 2012 4-Methyl-2-pentanone 100 100 1 103 70-130 05/06/2021 2012 Methylene chloride 50 49 1 98 70-130 05/06/2021 2012 Styrene 50 53 1 107 70-130 05/06/2021 2012 1,1,1,2-Tetrachloroethane 50 49 1 98 70-130 05/06/2021 2012 1,1,2,2-Tetrachloroethane 50 48 1 96 70-130 05/06/2021 2012 Tetrachloroethene 50 49 1 98 70-130 05/06/2021 2012 Tetrahydrofuran 50 47 1 95 70-130 05/06/2021 2012 Toluene 50 51 1 102 70-130 05/06/2021 2012 1,1,1-Trichloroethane 50 48 1 96 70-130 05/06/2021 2012 1,1,2-Trichloroethane 50 48 1 96 70-130 05/06/2021 2012 Trichloroethene 50 50 1 100 70-130 05/06/2021 2012 Trichlorofluoromethane 50 48 1 96 70-130 05/06/2021 2012 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 115 of 166 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91468-002 Matrix: Aqueous Batch: 91468 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,2,3-Trichloropropane 50 49 1 99 70-130 05/06/2021 2012 Vinyl acetate 50 49 1 98 60-140 05/06/2021 2012 Vinyl chloride 50 48 1 96 70-130 05/06/2021 2012 Xylenes (total) 100 100 1 105 70-130 05/06/2021 2012 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 103 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 102 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 116 of 166 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91517-001 Matrix: Aqueous Batch: 91517 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 05/07/2021 0953 Acrylonitrile ND 1 20 0.80 ug/L 05/07/2021 0953 Benzene ND 1 1.0 0.40 ug/L 05/07/2021 0953 Bromochloromethane ND 1 1.0 0.40 ug/L 05/07/2021 0953 Bromodichloromethane ND 1 1.0 0.40 ug/L 05/07/2021 0953 Bromoform ND 1 1.0 0.40 ug/L 05/07/2021 0953 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 05/07/2021 0953 2-Butanone (MEK) ND 1 10 2.0 ug/L 05/07/2021 0953 Carbon disulfide ND 1 1.0 0.40 ug/L 05/07/2021 0953 Carbon tetrachloride ND 1 1.0 0.40 ug/L 05/07/2021 0953 Chlorobenzene ND 1 1.0 0.40 ug/L 05/07/2021 0953 Chloroethane ND 1 2.0 0.40 ug/L 05/07/2021 0953 Chloroform ND 1 1.0 0.40 ug/L 05/07/2021 0953 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 05/07/2021 0953 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 05/07/2021 0953 Dibromochloromethane ND 1 1.0 0.40 ug/L 05/07/2021 0953 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 05/07/2021 0953 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 05/07/2021 0953 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 05/07/2021 0953 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/07/2021 0953 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/07/2021 0953 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 05/07/2021 0953 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 05/07/2021 0953 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 05/07/2021 0953 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/07/2021 0953 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/07/2021 0953 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 05/07/2021 0953 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/07/2021 0953 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/07/2021 0953 Ethylbenzene ND 1 1.0 0.40 ug/L 05/07/2021 0953 2-Hexanone ND 1 10 2.0 ug/L 05/07/2021 0953 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 05/07/2021 0953 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 05/07/2021 0953 Methylene chloride ND 1 1.0 0.40 ug/L 05/07/2021 0953 Styrene ND 1 1.0 0.41 ug/L 05/07/2021 0953 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/07/2021 0953 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/07/2021 0953 Tetrachloroethene ND 1 1.0 0.40 ug/L 05/07/2021 0953 Toluene ND 1 1.0 0.40 ug/L 05/07/2021 0953 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 05/07/2021 0953 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 05/07/2021 0953 Trichloroethene ND 1 1.0 0.40 ug/L 05/07/2021 0953 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 05/07/2021 0953 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 05/07/2021 0953 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 117 of 166 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91517-001 Matrix: Aqueous Batch: 91517 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 05/07/2021 0953 Vinyl chloride ND 1 1.0 0.40 ug/L 05/07/2021 0953 Xylenes (total) ND 1 1.0 0.40 ug/L 05/07/2021 0953 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 100 70-130 1,2-Dichloroethane-d4 103 70-130 Toluene-d8 107 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 118 of 166 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91517-002 Matrix: Aqueous Batch: 91517 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 120 1 122 60-140 05/07/2021 0851 Acrylonitrile 100 100 1 103 70-130 05/07/2021 0851 Benzene 50 50 1 101 70-130 05/07/2021 0851 Bromochloromethane 50 50 1 101 70-130 05/07/2021 0851 Bromodichloromethane 50 51 1 102 70-130 05/07/2021 0851 Bromoform 50 48 1 95 70-130 05/07/2021 0851 Bromomethane (Methyl bromide) 50 46 1 92 70-130 05/07/2021 0851 2-Butanone (MEK) 100 110 1 111 70-130 05/07/2021 0851 Carbon disulfide 50 52 1 104 70-130 05/07/2021 0851 Carbon tetrachloride 50 49 1 99 70-130 05/07/2021 0851 Chlorobenzene 50 50 1 100 70-130 05/07/2021 0851 Chloroethane 50 45 1 90 70-130 05/07/2021 0851 Chloroform 50 47 1 94 70-130 05/07/2021 0851 Chloromethane (Methyl chloride) 50 45 1 90 60-140 05/07/2021 0851 1,2-Dibromo-3-chloropropane (DBCP) 50 46 1 91 70-130 05/07/2021 0851 Dibromochloromethane 50 55 1 109 70-130 05/07/2021 0851 1,2-Dibromoethane (EDB) 50 52 1 105 70-130 05/07/2021 0851 Dibromomethane (Methylene bromide) 50 49 1 99 70-130 05/07/2021 0851 trans- 1,4-Dichloro-2-butene 50 51 1 103 70-130 05/07/2021 0851 1,2-Dichlorobenzene 50 49 1 99 70-130 05/07/2021 0851 1,4-Dichlorobenzene 50 49 1 98 70-130 05/07/2021 0851 1,1-Dichloroethane 50 49 1 98 70-130 05/07/2021 0851 1,2-Dichloroethane 50 48 1 95 70-130 05/07/2021 0851 1,1-Dichloroethene 50 53 1 105 70-130 05/07/2021 0851 cis- 1,2-Dichloroethene 50 48 1 95 70-130 05/07/2021 0851 trans- 1,2-Dichloroethene 50 51 1 102 70-130 05/07/2021 0851 1,2-Dichloropropane 50 50 1 99 70-130 05/07/2021 0851 cis- 1,3-Dichloropropene 50 56 1 112 70-130 05/07/2021 0851 trans- 1,3-Dichloropropene 50 50 1 99 70-130 05/07/2021 0851 Ethylbenzene 50 52 1 104 70-130 05/07/2021 0851 2-Hexanone 100 99 1 99 70-130 05/07/2021 0851 Methyl iodide (lodomethane) 50 54 1 108 70-130 05/07/2021 0851 4-Methyl-2-pentanone 100 110 1 106 70-130 05/07/2021 0851 Methylene chloride 50 50 1 100 70-130 05/07/2021 0851 Styrene 50 56 1 112 70-130 05/07/2021 0851 1,1,1,2-Tetrachloroethane 50 51 1 102 70-130 05/07/2021 0851 1,1,2,2-Tetrachloroethane 50 51 1 101 70-130 05/07/2021 0851 Tetrachloroethene 50 51 1 103 70-130 05/07/2021 0851 Toluene 50 51 1 102 70-130 05/07/2021 0851 1,1,1-Trichloroethane 50 53 1 105 70-130 05/07/2021 0851 1,1,2-Trichloroethane 50 52 1 104 70-130 05/07/2021 0851 Trichloroethene 50 52 1 103 70-130 05/07/2021 0851 Trichlorofluoromethane 50 44 1 89 70-130 05/07/2021 0851 1,2,3-Trichloropropane 50 50 1 100 70-130 05/07/2021 0851 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 119 of 166 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91517-002 Matrix: Aqueous Batch: 91517 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 49 1 98 60-140 05/07/2021 0851 Vinyl chloride 50 44 1 87 70-130 05/07/2021 0851 Xylenes (total) 100 110 1 105 70-130 05/07/2021 0851 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 94 70-130 Toluene-d8 103 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 120 of 166 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91625-001 Matrix: Aqueous Batch: 91625 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 05/08/2021 1712 Acrylonitrile ND 1 20 0.80 ug/L 05/08/2021 1712 Benzene ND 1 1.0 0.40 ug/L 05/08/2021 1712 Bromochloromethane ND 1 1.0 0.40 ug/L 05/08/2021 1712 Bromodichloromethane ND 1 1.0 0.40 ug/L 05/08/2021 1712 Bromoform ND 1 1.0 0.40 ug/L 05/08/2021 1712 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 05/08/2021 1712 2-Butanone (MEK) ND 1 10 2.0 ug/L 05/08/2021 1712 Carbon disulfide ND 1 1.0 0.40 ug/L 05/08/2021 1712 Carbon tetrachloride ND 1 1.0 0.40 ug/L 05/08/2021 1712 Chlorobenzene ND 1 1.0 0.40 ug/L 05/08/2021 1712 Chloroethane ND 1 2.0 0.40 ug/L 05/08/2021 1712 Chloroform ND 1 1.0 0.40 ug/L 05/08/2021 1712 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 05/08/2021 1712 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 05/08/2021 1712 Dibromochloromethane ND 1 1.0 0.40 ug/L 05/08/2021 1712 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 05/08/2021 1712 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 05/08/2021 1712 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 05/08/2021 1712 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/08/2021 1712 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/08/2021 1712 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 05/08/2021 1712 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 05/08/2021 1712 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 05/08/2021 1712 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/08/2021 1712 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/08/2021 1712 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 05/08/2021 1712 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/08/2021 1712 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/08/2021 1712 Ethylbenzene ND 1 1.0 0.40 ug/L 05/08/2021 1712 2-Hexanone ND 1 10 2.0 ug/L 05/08/2021 1712 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 05/08/2021 1712 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 05/08/2021 1712 Methylene chloride ND 1 1.0 0.40 ug/L 05/08/2021 1712 Styrene ND 1 1.0 0.41 ug/L 05/08/2021 1712 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/08/2021 1712 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/08/2021 1712 Tetrachloroethene ND 1 1.0 0.40 ug/L 05/08/2021 1712 Toluene ND 1 1.0 0.40 ug/L 05/08/2021 1712 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 05/08/2021 1712 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 05/08/2021 1712 Trichloroethene ND 1 1.0 0.40 ug/L 05/08/2021 1712 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 05/08/2021 1712 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 05/08/2021 1712 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 121 of 166 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91625-001 Matrix: Aqueous Batch: 91625 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 05/08/2021 1712 Vinyl chloride ND 1 1.0 0.40 ug/L 05/08/2021 1712 Xylenes (total) ND 1 1.0 0.40 ug/L 05/08/2021 1712 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 101 70-130 Toluene-d8 97 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 122 of 166 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91625-002 Matrix: Aqueous Batch: 91625 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 130 1 130 60-140 05/08/2021 1542 Acrylonitrile 100 120 1 121 70-130 05/08/2021 1542 Benzene 50 55 1 ill 70-130 05/08/2021 1542 Bromochloromethane 50 53 1 107 70-130 05/08/2021 1542 Bromodichloromethane 50 54 1 107 70-130 05/08/2021 1542 Bromoform 50 58 1 115 70-130 05/08/2021 1542 Bromomethane (Methyl bromide) 50 51 1 101 70-130 05/08/2021 1542 2-Butanone (MEK) 100 110 1 114 70-130 05/08/2021 1542 Carbon disulfide 50 59 1 117 70-130 05/08/2021 1542 Carbon tetrachloride 50 56 1 112 70-130 05/08/2021 1542 Chlorobenzene 50 54 1 108 70-130 05/08/2021 1542 Chloroethane 50 50 1 100 70-130 05/08/2021 1542 Chloroform 50 52 1 105 70-130 05/08/2021 1542 Chloromethane (Methyl chloride) 50 49 1 99 60-140 05/08/2021 1542 1,2-Dibromo-3-chloropropane (DBCP) 50 55 1 110 70-130 05/08/2021 1542 Dibromochloromethane 50 58 1 115 70-130 05/08/2021 1542 1,2-Dibromoethane (EDB) 50 54 1 109 70-130 05/08/2021 1542 Dibromomethane (Methylene bromide) 50 54 1 108 70-130 05/08/2021 1542 trans- 1,4-Dichloro-2-butene 50 51 1 102 70-130 05/08/2021 1542 1,2-Dichlorobenzene 50 55 1 109 70-130 05/08/2021 1542 1,4-Dichlorobenzene 50 55 1 110 70-130 05/08/2021 1542 1,1-Dichloroethane 50 55 1 111 70-130 05/08/2021 1542 1,2-Dichloroethane 50 53 1 106 70-130 05/08/2021 1542 1,1-Dichloroethene 50 55 1 110 70-130 05/08/2021 1542 cis- 1,2-Dichloroethene 50 55 1 109 70-130 05/08/2021 1542 trans- 1,2-Dichloroethene 50 56 1 111 70-130 05/08/2021 1542 1,2-Dichloropropane 50 54 1 107 70-130 05/08/2021 1542 cis- 1,3-Dichloropropene 50 56 1 113 70-130 05/08/2021 1542 trans- 1,3-Dichloropropene 50 58 1 116 70-130 05/08/2021 1542 Ethylbenzene 50 55 1 110 70-130 05/08/2021 1542 2-Hexanone 100 110 1 110 70-130 05/08/2021 1542 Methyl iodide (lodomethane) 50 54 1 109 70-130 05/08/2021 1542 4-Methyl-2-pentanone 100 110 1 111 70-130 05/08/2021 1542 Methylene chloride 50 52 1 104 70-130 05/08/2021 1542 Styrene 50 56 1 112 70-130 05/08/2021 1542 1,1,1,2-Tetrachloroethane 50 55 1 110 70-130 05/08/2021 1542 1,1,2,2-Tetrachloroethane 50 54 1 109 70-130 05/08/2021 1542 Tetrachloroethene 50 52 1 104 70-130 05/08/2021 1542 Toluene 50 56 1 112 70-130 05/08/2021 1542 1,1,1-Trichloroethane 50 56 1 111 70-130 05/08/2021 1542 1,1,2-Trichloroethane 50 53 1 105 70-130 05/08/2021 1542 Trichloroethene 50 55 1 109 70-130 05/08/2021 1542 Trichlorofluoromethane 50 48 1 96 70-130 05/08/2021 1542 1,2,3-Trichloropropane 50 52 1 105 70-130 05/08/2021 1542 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 123 of 166 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91625-002 Matrix: Aqueous Batch: 91625 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 57 1 115 60-140 05/08/2021 1542 Vinyl chloride 50 46 1 93 70-130 05/08/2021 1542 Xylenes (total) 100 110 1 110 70-130 05/08/2021 1542 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 94 70-130 Toluene-d8 96 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 124 of 166 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91625-001 Matrix: Aqueous Batch: 91625 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 05/08/2021 1712 Acrylonitrile ND 1 20 0.80 ug/L 05/08/2021 1712 Benzene ND 1 1.0 0.40 ug/L 05/08/2021 1712 Bromochloromethane ND 1 1.0 0.40 ug/L 05/08/2021 1712 Bromodichloromethane ND 1 1.0 0.40 ug/L 05/08/2021 1712 Bromoform ND 1 1.0 0.40 ug/L 05/08/2021 1712 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 05/08/2021 1712 2-Butanone (MEK) ND 1 10 2.0 ug/L 05/08/2021 1712 Carbon disulfide ND 1 1.0 0.40 ug/L 05/08/2021 1712 Carbon tetrachloride ND 1 1.0 0.40 ug/L 05/08/2021 1712 Chlorobenzene ND 1 1.0 0.40 ug/L 05/08/2021 1712 Chloroethane ND 1 2.0 0.40 ug/L 05/08/2021 1712 Chloroform ND 1 1.0 0.40 ug/L 05/08/2021 1712 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 05/08/2021 1712 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 05/08/2021 1712 Dibromochloromethane ND 1 1.0 0.40 ug/L 05/08/2021 1712 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 05/08/2021 1712 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 05/08/2021 1712 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 05/08/2021 1712 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/08/2021 1712 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/08/2021 1712 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 05/08/2021 1712 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 05/08/2021 1712 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 05/08/2021 1712 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/08/2021 1712 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/08/2021 1712 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 05/08/2021 1712 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/08/2021 1712 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/08/2021 1712 Ethylbenzene ND 1 1.0 0.40 ug/L 05/08/2021 1712 2-Hexanone ND 1 10 2.0 ug/L 05/08/2021 1712 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 05/08/2021 1712 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 05/08/2021 1712 Methylene chloride ND 1 1.0 0.40 ug/L 05/08/2021 1712 Styrene ND 1 1.0 0.41 ug/L 05/08/2021 1712 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/08/2021 1712 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/08/2021 1712 Tetrachloroethene ND 1 1.0 0.40 ug/L 05/08/2021 1712 Tetrahydrofuran ND 1 5.0 1.0 ug/L 05/08/2021 1712 Toluene ND 1 1.0 0.40 ug/L 05/08/2021 1712 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 05/08/2021 1712 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 05/08/2021 1712 Trichloroethene ND 1 1.0 0.40 ug/L 05/08/2021 1712 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 05/08/2021 1712 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 125 of 166 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91625-001 Matrix: Aqueous Batch: 91625 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 05/08/2021 1712 Vinyl acetate ND 1 5.0 1.2 ug/L 05/08/2021 1712 Vinyl chloride ND 1 1.0 0.40 ug/L 05/08/2021 1712 Xylenes (total) ND 1 1.0 0.40 ug/L 05/08/2021 1712 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 101 70-130 Toluene-d8 97 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 126 of 166 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91625-002 Matrix: Aqueous Batch: 91625 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 130 1 130 60-140 05/08/2021 1542 Acrylonitrile 100 120 1 121 70-130 05/08/2021 1542 Benzene 50 55 1 ill 70-130 05/08/2021 1542 Bromochloromethane 50 53 1 107 70-130 05/08/2021 1542 Bromodichloromethane 50 54 1 107 70-130 05/08/2021 1542 Bromoform 50 58 1 115 70-130 05/08/2021 1542 Bromomethane (Methyl bromide) 50 51 1 101 70-130 05/08/2021 1542 2-Butanone (MEK) 100 110 1 114 70-130 05/08/2021 1542 Carbon disulfide 50 59 1 117 70-130 05/08/2021 1542 Carbon tetrachloride 50 56 1 112 70-130 05/08/2021 1542 Chlorobenzene 50 54 1 108 70-130 05/08/2021 1542 Chloroethane 50 50 1 100 70-130 05/08/2021 1542 Chloroform 50 52 1 105 70-130 05/08/2021 1542 Chloromethane (Methyl chloride) 50 49 1 99 60-140 05/08/2021 1542 1,2-Dibromo-3-chloropropane (DBCP) 50 55 1 110 70-130 05/08/2021 1542 Dibromochloromethane 50 58 1 115 70-130 05/08/2021 1542 1,2-Dibromoethane (EDB) 50 54 1 109 70-130 05/08/2021 1542 Dibromomethane (Methylene bromide) 50 54 1 108 70-130 05/08/2021 1542 trans- 1,4-Dichloro-2-butene 50 51 1 102 70-130 05/08/2021 1542 1,2-Dichlorobenzene 50 55 1 109 70-130 05/08/2021 1542 1,4-Dichlorobenzene 50 55 1 110 70-130 05/08/2021 1542 1,1-Dichloroethane 50 55 1 111 70-130 05/08/2021 1542 1,2-Dichloroethane 50 53 1 106 70-130 05/08/2021 1542 1,1-Dichloroethene 50 55 1 110 70-130 05/08/2021 1542 cis- 1,2-Dichloroethene 50 55 1 109 70-130 05/08/2021 1542 trans- 1,2-Dichloroethene 50 56 1 111 70-130 05/08/2021 1542 1,2-Dichloropropane 50 54 1 107 70-130 05/08/2021 1542 cis- 1,3-Dichloropropene 50 56 1 113 70-130 05/08/2021 1542 trans- 1,3-Dichloropropene 50 58 1 116 70-130 05/08/2021 1542 Ethylbenzene 50 55 1 110 70-130 05/08/2021 1542 2-Hexanone 100 110 1 110 70-130 05/08/2021 1542 Methyl iodide (lodomethane) 50 54 1 109 70-130 05/08/2021 1542 4-Methyl-2-pentanone 100 110 1 111 70-130 05/08/2021 1542 Methylene chloride 50 52 1 104 70-130 05/08/2021 1542 Styrene 50 56 1 112 70-130 05/08/2021 1542 1,1,1,2-Tetrachloroethane 50 55 1 110 70-130 05/08/2021 1542 1,1,2,2-Tetrachloroethane 50 54 1 109 70-130 05/08/2021 1542 Tetrachloroethene 50 52 1 104 70-130 05/08/2021 1542 Tetrahydrofuran 50 50 1 101 70-130 05/08/2021 1542 Toluene 50 56 1 112 70-130 05/08/2021 1542 1,1,1-Trichloroethane 50 56 1 111 70-130 05/08/2021 1542 1,1,2-Trichloroethane 50 53 1 105 70-130 05/08/2021 1542 Trichloroethene 50 55 1 109 70-130 05/08/2021 1542 Trichlorofluoromethane 50 48 1 96 70-130 05/08/2021 1542 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 127 of 166 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91625-002 Matrix: Aqueous Batch: 91625 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,2,3-Trichloropropane 50 52 1 105 70-130 05/08/2021 1542 Vinyl acetate 50 57 1 115 60-140 05/08/2021 1542 Vinyl chloride 50 46 1 93 70-130 05/08/2021 1542 Xylenes (total) 100 110 1 110 70-130 05/08/2021 1542 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 94 70-130 Toluene-d8 96 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 128 of 166 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91650-001 Matrix: Aqueous Batch: 91650 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 05/09/2021 1154 Acrylonitrile ND 1 20 0.80 ug/L 05/09/2021 1154 Benzene ND 1 1.0 0.40 ug/L 05/09/2021 1154 Bromochloromethane ND 1 1.0 0.40 ug/L 05/09/2021 1154 Bromodichloromethane ND 1 1.0 0.40 ug/L 05/09/2021 1154 Bromoform ND 1 1.0 0.40 ug/L 05/09/2021 1154 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 05/09/2021 1154 2-Butanone (MEK) ND 1 10 2.0 ug/L 05/09/2021 1154 Carbon disulfide ND 1 1.0 0.40 ug/L 05/09/2021 1154 Carbon tetrachloride ND 1 1.0 0.40 ug/L 05/09/2021 1154 Chlorobenzene ND 1 1.0 0.40 ug/L 05/09/2021 1154 Chloroethane ND 1 2.0 0.40 ug/L 05/09/2021 1154 Chloroform ND 1 1.0 0.40 ug/L 05/09/2021 1154 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 05/09/2021 1154 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 05/09/2021 1154 Dibromochloromethane ND 1 1.0 0.40 ug/L 05/09/2021 1154 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 05/09/2021 1154 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 05/09/2021 1154 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 05/09/2021 1154 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/09/2021 1154 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/09/2021 1154 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1154 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1154 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 05/09/2021 1154 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/09/2021 1154 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/09/2021 1154 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 05/09/2021 1154 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/09/2021 1154 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/09/2021 1154 Ethylbenzene ND 1 1.0 0.40 ug/L 05/09/2021 1154 2-Hexanone ND 1 10 2.0 ug/L 05/09/2021 1154 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 05/09/2021 1154 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 05/09/2021 1154 Methylene chloride ND 1 1.0 0.40 ug/L 05/09/2021 1154 Styrene ND 1 1.0 0.41 ug/L 05/09/2021 1154 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1154 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1154 Tetrachloroethene ND 1 1.0 0.40 ug/L 05/09/2021 1154 Toluene ND 1 1.0 0.40 ug/L 05/09/2021 1154 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1154 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1154 Trichloroethene ND 1 1.0 0.40 ug/L 05/09/2021 1154 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 05/09/2021 1154 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 05/09/2021 1154 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 129 of 166 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91650-001 Matrix: Aqueous Batch: 91650 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 05/09/2021 1154 Vinyl chloride ND 1 1.0 0.40 ug/L 05/09/2021 1154 Xylenes (total) ND 1 1.0 0.40 ug/L 05/09/2021 1154 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 95 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 130 of 166 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91650-002 Matrix: Aqueous Batch: 91650 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 110 1 112 60-140 05/09/2021 1033 Acrylonitrile 100 97 1 97 70-130 05/09/2021 1033 Benzene 50 50 1 101 70-130 05/09/2021 1033 Bromochloromethane 50 47 1 94 70-130 05/09/2021 1033 Bromodichloromethane 50 49 1 99 70-130 05/09/2021 1033 Bromoform 50 52 1 104 70-130 05/09/2021 1033 Bromomethane (Methyl bromide) 50 44 1 89 70-130 05/09/2021 1033 2-Butanone (MEK) 100 110 1 109 70-130 05/09/2021 1033 Carbon disulfide 50 52 1 103 70-130 05/09/2021 1033 Carbon tetrachloride 50 52 1 104 70-130 05/09/2021 1033 Chlorobenzene 50 50 1 101 70-130 05/09/2021 1033 Chloroethane 50 43 1 86 70-130 05/09/2021 1033 Chloroform 50 47 1 94 70-130 05/09/2021 1033 Chloromethane (Methyl chloride) 50 44 1 88 60-140 05/09/2021 1033 1,2-Dibromo-3-chloropropane (DBCP) 50 50 1 101 70-130 05/09/2021 1033 Dibromochloromethane 50 52 1 104 70-130 05/09/2021 1033 1,2-Dibromoethane (EDB) 50 49 1 98 70-130 05/09/2021 1033 Dibromomethane (Methylene bromide) 50 48 1 97 70-130 05/09/2021 1033 trans- 1,4-Dichloro-2-butene 50 42 1 84 70-130 05/09/2021 1033 1,2-Dichlorobenzene 50 51 1 103 70-130 05/09/2021 1033 1,4-Dichlorobenzene 50 50 1 100 70-130 05/09/2021 1033 1,1-Dichloroethane 50 50 1 99 70-130 05/09/2021 1033 1,2-Dichloroethane 50 49 1 98 70-130 05/09/2021 1033 1,1-Dichloroethene 50 50 1 100 70-130 05/09/2021 1033 cis- 1,2-Dichloroethene 50 48 1 95 70-130 05/09/2021 1033 trans- 1,2-Dichloroethene 50 51 1 102 70-130 05/09/2021 1033 1,2-Dichloropropane 50 49 1 98 70-130 05/09/2021 1033 cis- 1,3-Dichloropropene 50 51 1 103 70-130 05/09/2021 1033 trans- 1,3-Dichloropropene 50 52 1 105 70-130 05/09/2021 1033 Ethylbenzene 50 51 1 103 70-130 05/09/2021 1033 2-Hexanone 100 100 1 103 70-130 05/09/2021 1033 Methyl iodide (lodomethane) 50 48 1 96 70-130 05/09/2021 1033 4-Methyl-2-pentanone 100 100 1 100 70-130 05/09/2021 1033 Methylene chloride 50 46 1 92 70-130 05/09/2021 1033 Styrene 50 52 1 104 70-130 05/09/2021 1033 1,1,1,2-Tetrachloroethane 50 52 1 104 70-130 05/09/2021 1033 1,1,2,2-Tetrachloroethane 50 48 1 96 70-130 05/09/2021 1033 Tetrachloroethene 50 47 1 95 70-130 05/09/2021 1033 Toluene 50 51 1 102 70-130 05/09/2021 1033 1,1,1-Trichloroethane 50 51 1 102 70-130 05/09/2021 1033 1,1,2-Trichloroethane 50 48 1 96 70-130 05/09/2021 1033 Trichloroethene 50 50 1 99 70-130 05/09/2021 1033 Trichlorofluoromethane 50 41 1 82 70-130 05/09/2021 1033 1,2,3-Trichloropropane 50 46 1 93 70-130 05/09/2021 1033 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 131 of 166 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91650-002 Matrix: Aqueous Batch: 91650 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 51 1 101 60-140 05/09/2021 1033 Vinyl chloride 50 40 1 80 70-130 05/09/2021 1033 Xylenes (total) 100 100 1 102 70-130 05/09/2021 1033 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 91 70-130 1,2-Dichloroethane-d4 85 70-130 Toluene-d8 86 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 132 of 166 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91650-001 Matrix: Aqueous Batch: 91650 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 05/09/2021 1154 Acrylonitrile ND 1 20 0.80 ug/L 05/09/2021 1154 Benzene ND 1 1.0 0.40 ug/L 05/09/2021 1154 Bromochloromethane ND 1 1.0 0.40 ug/L 05/09/2021 1154 Bromodichloromethane ND 1 1.0 0.40 ug/L 05/09/2021 1154 Bromoform ND 1 1.0 0.40 ug/L 05/09/2021 1154 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 05/09/2021 1154 2-Butanone (MEK) ND 1 10 2.0 ug/L 05/09/2021 1154 Carbon disulfide ND 1 1.0 0.40 ug/L 05/09/2021 1154 Carbon tetrachloride ND 1 1.0 0.40 ug/L 05/09/2021 1154 Chlorobenzene ND 1 1.0 0.40 ug/L 05/09/2021 1154 Chloroethane ND 1 2.0 0.40 ug/L 05/09/2021 1154 Chloroform ND 1 1.0 0.40 ug/L 05/09/2021 1154 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 05/09/2021 1154 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 05/09/2021 1154 Dibromochloromethane ND 1 1.0 0.40 ug/L 05/09/2021 1154 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 05/09/2021 1154 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 05/09/2021 1154 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 05/09/2021 1154 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/09/2021 1154 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/09/2021 1154 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1154 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1154 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 05/09/2021 1154 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/09/2021 1154 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/09/2021 1154 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 05/09/2021 1154 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/09/2021 1154 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/09/2021 1154 Ethylbenzene ND 1 1.0 0.40 ug/L 05/09/2021 1154 2-Hexanone ND 1 10 2.0 ug/L 05/09/2021 1154 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 05/09/2021 1154 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 05/09/2021 1154 Methylene chloride ND 1 1.0 0.40 ug/L 05/09/2021 1154 Styrene ND 1 1.0 0.41 ug/L 05/09/2021 1154 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1154 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1154 Tetrachloroethene ND 1 1.0 0.40 ug/L 05/09/2021 1154 Tetrahydrofuran ND 1 5.0 1.0 ug/L 05/09/2021 1154 Toluene ND 1 1.0 0.40 ug/L 05/09/2021 1154 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1154 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1154 Trichloroethene ND 1 1.0 0.40 ug/L 05/09/2021 1154 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 05/09/2021 1154 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 133 of 166 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91650-001 Matrix: Aqueous Batch: 91650 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 05/09/2021 1154 Vinyl acetate ND 1 5.0 1.2 ug/L 05/09/2021 1154 Vinyl chloride ND 1 1.0 0.40 ug/L 05/09/2021 1154 Xylenes (total) ND 1 1.0 0.40 ug/L 05/09/2021 1154 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 95 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 134 of 166 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91650-002 Matrix: Aqueous Batch: 91650 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 110 1 112 60-140 05/09/2021 1033 Acrylonitrile 100 97 1 97 70-130 05/09/2021 1033 Benzene 50 50 1 101 70-130 05/09/2021 1033 Bromochloromethane 50 47 1 94 70-130 05/09/2021 1033 Bromodichloromethane 50 49 1 99 70-130 05/09/2021 1033 Bromoform 50 52 1 104 70-130 05/09/2021 1033 Bromomethane (Methyl bromide) 50 44 1 89 70-130 05/09/2021 1033 2-Butanone (MEK) 100 110 1 109 70-130 05/09/2021 1033 Carbon disulfide 50 52 1 103 70-130 05/09/2021 1033 Carbon tetrachloride 50 52 1 104 70-130 05/09/2021 1033 Chlorobenzene 50 50 1 101 70-130 05/09/2021 1033 Chloroethane 50 43 1 86 70-130 05/09/2021 1033 Chloroform 50 47 1 94 70-130 05/09/2021 1033 Chloromethane (Methyl chloride) 50 44 1 88 60-140 05/09/2021 1033 1,2-Dibromo-3-chloropropane (DBCP) 50 50 1 101 70-130 05/09/2021 1033 Dibromochloromethane 50 52 1 104 70-130 05/09/2021 1033 1,2-Dibromoethane (EDB) 50 49 1 98 70-130 05/09/2021 1033 Dibromomethane (Methylene bromide) 50 48 1 97 70-130 05/09/2021 1033 trans- 1,4-Dichloro-2-butene 50 42 1 84 70-130 05/09/2021 1033 1,2-Dichlorobenzene 50 51 1 103 70-130 05/09/2021 1033 1,4-Dichlorobenzene 50 50 1 100 70-130 05/09/2021 1033 1,1-Dichloroethane 50 50 1 99 70-130 05/09/2021 1033 1,2-Dichloroethane 50 49 1 98 70-130 05/09/2021 1033 1,1-Dichloroethene 50 50 1 100 70-130 05/09/2021 1033 cis- 1,2-Dichloroethene 50 48 1 95 70-130 05/09/2021 1033 trans- 1,2-Dichloroethene 50 51 1 102 70-130 05/09/2021 1033 1,2-Dichloropropane 50 49 1 98 70-130 05/09/2021 1033 cis- 1,3-Dichloropropene 50 51 1 103 70-130 05/09/2021 1033 trans- 1,3-Dichloropropene 50 52 1 105 70-130 05/09/2021 1033 Ethylbenzene 50 51 1 103 70-130 05/09/2021 1033 2-Hexanone 100 100 1 103 70-130 05/09/2021 1033 Methyl iodide (lodomethane) 50 48 1 96 70-130 05/09/2021 1033 4-Methyl-2-pentanone 100 100 1 100 70-130 05/09/2021 1033 Methylene chloride 50 46 1 92 70-130 05/09/2021 1033 Styrene 50 52 1 104 70-130 05/09/2021 1033 1,1,1,2-Tetrachloroethane 50 52 1 104 70-130 05/09/2021 1033 1,1,2,2-Tetrachloroethane 50 48 1 96 70-130 05/09/2021 1033 Tetrachloroethene 50 47 1 95 70-130 05/09/2021 1033 Tetrahydrofuran 50 48 1 96 70-130 05/09/2021 1033 Toluene 50 51 1 102 70-130 05/09/2021 1033 1,1,1-Trichloroethane 50 51 1 102 70-130 05/09/2021 1033 1,1,2-Trichloroethane 50 48 1 96 70-130 05/09/2021 1033 Trichloroethene 50 50 1 99 70-130 05/09/2021 1033 Trichlorofluoromethane 50 41 1 82 70-130 05/09/2021 1033 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 135 of 166 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91650-002 Matrix: Aqueous Batch: 91650 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,2,3-Trichloropropane 50 46 1 93 70-130 05/09/2021 1033 Vinyl acetate 50 51 1 101 60-140 05/09/2021 1033 Vinyl chloride 50 40 1 80 70-130 05/09/2021 1033 Xylenes (total) 100 100 1 102 70-130 05/09/2021 1033 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 91 70-130 1,2-Dichloroethane-d4 85 70-130 Toluene-d8 86 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 136 of 166 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91673-001 Matrix: Aqueous Batch: 91673 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 05/09/2021 1820 Acrylonitrile ND 1 20 0.80 ug/L 05/09/2021 1820 Benzene ND 1 1.0 0.40 ug/L 05/09/2021 1820 Bromochloromethane ND 1 1.0 0.40 ug/L 05/09/2021 1820 Bromodichloromethane ND 1 1.0 0.40 ug/L 05/09/2021 1820 Bromoform ND 1 1.0 0.40 ug/L 05/09/2021 1820 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 05/09/2021 1820 2-Butanone (MEK) ND 1 10 2.0 ug/L 05/09/2021 1820 Carbon disulfide ND 1 1.0 0.40 ug/L 05/09/2021 1820 Carbon tetrachloride ND 1 1.0 0.40 ug/L 05/09/2021 1820 Chlorobenzene ND 1 1.0 0.40 ug/L 05/09/2021 1820 Chloroethane ND 1 2.0 0.40 ug/L 05/09/2021 1820 Chloroform ND 1 1.0 0.40 ug/L 05/09/2021 1820 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 05/09/2021 1820 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 05/09/2021 1820 Dibromochloromethane ND 1 1.0 0.40 ug/L 05/09/2021 1820 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 05/09/2021 1820 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 05/09/2021 1820 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 05/09/2021 1820 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/09/2021 1820 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/09/2021 1820 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1820 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1820 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 05/09/2021 1820 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/09/2021 1820 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/09/2021 1820 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 05/09/2021 1820 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/09/2021 1820 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/09/2021 1820 Ethylbenzene ND 1 1.0 0.40 ug/L 05/09/2021 1820 2-Hexanone ND 1 10 2.0 ug/L 05/09/2021 1820 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 05/09/2021 1820 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 05/09/2021 1820 Methylene chloride ND 1 1.0 0.40 ug/L 05/09/2021 1820 Styrene ND 1 1.0 0.41 ug/L 05/09/2021 1820 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1820 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1820 Tetrachloroethene ND 1 1.0 0.40 ug/L 05/09/2021 1820 Toluene ND 1 1.0 0.40 ug/L 05/09/2021 1820 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1820 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1820 Trichloroethene ND 1 1.0 0.40 ug/L 05/09/2021 1820 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 05/09/2021 1820 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 05/09/2021 1820 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 137 of 166 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91673-001 Matrix: Aqueous Batch: 91673 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 05/09/2021 1820 Vinyl chloride ND 1 1.0 0.40 ug/L 05/09/2021 1820 Xylenes (total) ND 1 1.0 0.40 ug/L 05/09/2021 1820 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 104 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 109 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 138 of 166 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91673-002 Matrix: Aqueous Batch: 91673 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 93 1 93 60-140 05/09/2021 1702 Acrylonitrile 100 99 1 99 70-130 05/09/2021 1702 Benzene 50 50 1 100 70-130 05/09/2021 1702 Bromochloromethane 50 49 1 98 70-130 05/09/2021 1702 Bromodichloromethane 50 52 1 103 70-130 05/09/2021 1702 Bromoform 50 49 1 98 70-130 05/09/2021 1702 Bromomethane (Methyl bromide) 50 47 1 95 70-130 05/09/2021 1702 2-Butanone (MEK) 100 100 1 102 70-130 05/09/2021 1702 Carbon disulfide 50 49 1 99 70-130 05/09/2021 1702 Carbon tetrachloride 50 52 1 103 70-130 05/09/2021 1702 Chlorobenzene 50 50 1 100 70-130 05/09/2021 1702 Chloroethane 50 47 1 93 70-130 05/09/2021 1702 Chloroform 50 47 1 94 70-130 05/09/2021 1702 Chloromethane (Methyl chloride) 50 48 1 97 60-140 05/09/2021 1702 1,2-Dibromo-3-chloropropane (DBCP) 50 43 1 87 70-130 05/09/2021 1702 Dibromochloromethane 50 56 1 111 70-130 05/09/2021 1702 1,2-Dibromoethane (EDB) 50 52 1 105 70-130 05/09/2021 1702 Dibromomethane (Methylene bromide) 50 49 1 98 70-130 05/09/2021 1702 trans- 1,4-Dichloro-2-butene 50 50 1 101 70-130 05/09/2021 1702 1,2-Dichlorobenzene 50 49 1 97 70-130 05/09/2021 1702 1,4-Dichlorobenzene 50 49 1 97 70-130 05/09/2021 1702 1,1-Dichloroethane 50 48 1 97 70-130 05/09/2021 1702 1,2-Dichloroethane 50 47 1 94 70-130 05/09/2021 1702 1,1-Dichloroethene 50 50 1 100 70-130 05/09/2021 1702 cis- 1,2-Dichloroethene 50 47 1 94 70-130 05/09/2021 1702 trans- 1,2-Dichloroethene 50 51 1 101 70-130 05/09/2021 1702 1,2-Dichloropropane 50 49 1 98 70-130 05/09/2021 1702 cis- 1,3-Dichloropropene 50 56 1 111 70-130 05/09/2021 1702 trans- 1,3-Dichloropropene 50 49 1 99 70-130 05/09/2021 1702 Ethylbenzene 50 52 1 103 70-130 05/09/2021 1702 2-Hexanone 100 96 1 96 70-130 05/09/2021 1702 Methyl iodide (lodomethane) 50 51 1 102 70-130 05/09/2021 1702 4-Methyl-2-pentanone 100 100 1 101 70-130 05/09/2021 1702 Methylene chloride 50 47 1 94 70-130 05/09/2021 1702 Styrene 50 56 1 112 70-130 05/09/2021 1702 1,1,1,2-Tetrachloroethane 50 51 1 101 70-130 05/09/2021 1702 1,1,2,2-Tetrachloroethane 50 50 1 100 70-130 05/09/2021 1702 Tetrachloroethene 50 52 1 105 70-130 05/09/2021 1702 Toluene 50 52 1 103 70-130 05/09/2021 1702 1,1,1-Trichloroethane 50 51 1 103 70-130 05/09/2021 1702 1,1,2-Trichloroethane 50 52 1 104 70-130 05/09/2021 1702 Trichloroethene 50 51 1 103 70-130 05/09/2021 1702 Trichlorofluoromethane 50 48 1 96 70-130 05/09/2021 1702 1,2,3-Trichloropropane 50 49 1 99 70-130 05/09/2021 1702 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 139 of 166 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91673-002 Matrix: Aqueous Batch: 91673 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 48 1 97 60-140 05/09/2021 1702 Vinyl chloride 50 48 1 96 70-130 05/09/2021 1702 Xylenes (total) 100 100 1 104 70-130 05/09/2021 1702 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 92 70-130 Toluene-d8 100 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 140 of 166 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91673-001 Matrix: Aqueous Batch: 91673 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 05/09/2021 1820 Acrylonitrile ND 1 20 0.80 ug/L 05/09/2021 1820 Benzene ND 1 1.0 0.40 ug/L 05/09/2021 1820 Bromochloromethane ND 1 1.0 0.40 ug/L 05/09/2021 1820 Bromodichloromethane ND 1 1.0 0.40 ug/L 05/09/2021 1820 Bromoform ND 1 1.0 0.40 ug/L 05/09/2021 1820 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 05/09/2021 1820 2-Butanone (MEK) ND 1 10 2.0 ug/L 05/09/2021 1820 Carbon disulfide ND 1 1.0 0.40 ug/L 05/09/2021 1820 Carbon tetrachloride ND 1 1.0 0.40 ug/L 05/09/2021 1820 Chlorobenzene ND 1 1.0 0.40 ug/L 05/09/2021 1820 Chloroethane ND 1 2.0 0.40 ug/L 05/09/2021 1820 Chloroform ND 1 1.0 0.40 ug/L 05/09/2021 1820 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 05/09/2021 1820 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 05/09/2021 1820 Dibromochloromethane ND 1 1.0 0.40 ug/L 05/09/2021 1820 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 05/09/2021 1820 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 05/09/2021 1820 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 05/09/2021 1820 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/09/2021 1820 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/09/2021 1820 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1820 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1820 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 05/09/2021 1820 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/09/2021 1820 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/09/2021 1820 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 05/09/2021 1820 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/09/2021 1820 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/09/2021 1820 Ethylbenzene ND 1 1.0 0.40 ug/L 05/09/2021 1820 2-Hexanone ND 1 10 2.0 ug/L 05/09/2021 1820 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 05/09/2021 1820 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 05/09/2021 1820 Methylene chloride ND 1 1.0 0.40 ug/L 05/09/2021 1820 Styrene ND 1 1.0 0.41 ug/L 05/09/2021 1820 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1820 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1820 Tetrachloroethene ND 1 1.0 0.40 ug/L 05/09/2021 1820 Tetrahydrofuran ND 1 5.0 1.0 ug/L 05/09/2021 1820 Toluene ND 1 1.0 0.40 ug/L 05/09/2021 1820 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1820 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 05/09/2021 1820 Trichloroethene ND 1 1.0 0.40 ug/L 05/09/2021 1820 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 05/09/2021 1820 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 141 of 166 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91673-001 Matrix: Aqueous Batch: 91673 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 05/09/2021 1820 Vinyl acetate ND 1 5.0 1.2 ug/L 05/09/2021 1820 Vinyl chloride ND 1 1.0 0.40 ug/L 05/09/2021 1820 Xylenes (total) ND 1 1.0 0.40 ug/L 05/09/2021 1820 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 104 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 109 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 142 of 166 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91673-002 Matrix: Aqueous Batch: 91673 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 93 1 93 60-140 05/09/2021 1702 Acrylonitrile 100 99 1 99 70-130 05/09/2021 1702 Benzene 50 50 1 100 70-130 05/09/2021 1702 Bromochloromethane 50 49 1 98 70-130 05/09/2021 1702 Bromodichloromethane 50 52 1 103 70-130 05/09/2021 1702 Bromoform 50 49 1 98 70-130 05/09/2021 1702 Bromomethane (Methyl bromide) 50 47 1 95 70-130 05/09/2021 1702 2-Butanone (MEK) 100 100 1 102 70-130 05/09/2021 1702 Carbon disulfide 50 49 1 99 70-130 05/09/2021 1702 Carbon tetrachloride 50 52 1 103 70-130 05/09/2021 1702 Chlorobenzene 50 50 1 100 70-130 05/09/2021 1702 Chloroethane 50 47 1 93 70-130 05/09/2021 1702 Chloroform 50 47 1 94 70-130 05/09/2021 1702 Chloromethane (Methyl chloride) 50 48 1 97 60-140 05/09/2021 1702 1,2-Dibromo-3-chloropropane (DBCP) 50 43 1 87 70-130 05/09/2021 1702 Dibromochloromethane 50 56 1 111 70-130 05/09/2021 1702 1,2-Dibromoethane (EDB) 50 52 1 105 70-130 05/09/2021 1702 Dibromomethane (Methylene bromide) 50 49 1 98 70-130 05/09/2021 1702 trans- 1,4-Dichloro-2-butene 50 50 1 101 70-130 05/09/2021 1702 1,2-Dichlorobenzene 50 49 1 97 70-130 05/09/2021 1702 1,4-Dichlorobenzene 50 49 1 97 70-130 05/09/2021 1702 1,1-Dichloroethane 50 48 1 97 70-130 05/09/2021 1702 1,2-Dichloroethane 50 47 1 94 70-130 05/09/2021 1702 1,1-Dichloroethene 50 50 1 100 70-130 05/09/2021 1702 cis- 1,2-Dichloroethene 50 47 1 94 70-130 05/09/2021 1702 trans- 1,2-Dichloroethene 50 51 1 101 70-130 05/09/2021 1702 1,2-Dichloropropane 50 49 1 98 70-130 05/09/2021 1702 cis- 1,3-Dichloropropene 50 56 1 111 70-130 05/09/2021 1702 trans- 1,3-Dichloropropene 50 49 1 99 70-130 05/09/2021 1702 Ethylbenzene 50 52 1 103 70-130 05/09/2021 1702 2-Hexanone 100 96 1 96 70-130 05/09/2021 1702 Methyl iodide (lodomethane) 50 51 1 102 70-130 05/09/2021 1702 4-Methyl-2-pentanone 100 100 1 101 70-130 05/09/2021 1702 Methylene chloride 50 47 1 94 70-130 05/09/2021 1702 Styrene 50 56 1 112 70-130 05/09/2021 1702 1,1,1,2-Tetrachloroethane 50 51 1 101 70-130 05/09/2021 1702 1,1,2,2-Tetrachloroethane 50 50 1 100 70-130 05/09/2021 1702 Tetrachloroethene 50 52 1 105 70-130 05/09/2021 1702 Tetrahydrofuran 50 45 1 90 70-130 05/09/2021 1702 Toluene 50 52 1 103 70-130 05/09/2021 1702 1,1,1-Trichloroethane 50 51 1 103 70-130 05/09/2021 1702 1,1,2-Trichloroethane 50 52 1 104 70-130 05/09/2021 1702 Trichloroethene 50 51 1 103 70-130 05/09/2021 1702 Trichlorofluoromethane 50 48 1 96 70-130 05/09/2021 1702 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 143 of 166 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91673-002 Matrix: Aqueous Batch: 91673 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,2,3-Trichloropropane 50 49 1 99 70-130 05/09/2021 1702 Vinyl acetate 50 48 1 97 60-140 05/09/2021 1702 Vinyl chloride 50 48 1 96 70-130 05/09/2021 1702 Xylenes (total) 100 100 1 104 70-130 05/09/2021 1702 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 92 70-130 Toluene-d8 100 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 144 of 166 ICP-MS Metals - MB Sample ID: WQ90580-001 Matrix: Aqueous Batch: 90580 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/29/2021 0948 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 04/29/2021 2008 Arsenic ND 1 2.0 1.3 ug/L 04/29/2021 2008 Barium ND 1 5.0 1.3 ug/L 04/29/2021 2008 Beryllium ND 1 0.40 0.15 ug/L 04/29/2021 2008 Cadmium ND 1 0.50 0.13 ug/L 04/29/2021 2008 Chromium ND 1 5.0 1.3 ug/L 04/29/2021 2008 Cobalt ND 1 5.0 1.3 ug/L 04/29/2021 2008 Copper ND 1 5.0 1.3 ug/L 04/29/2021 2008 Iron ND 1 50 13 ug/L 04/29/2021 2008 Lead ND 1 1.0 0.25 ug/L 04/29/2021 2008 Manganese ND 1 5.0 1.3 ug/L 04/29/2021 2008 Nickel ND 1 5.0 1.3 ug/L 04/29/2021 2008 Selenium ND 1 5.0 1.3 ug/L 04/29/2021 2008 Silver ND 1 1.0 0.25 ug/L 04/29/2021 2008 Thallium ND 1 0.50 0.15 ug/L 04/29/2021 2008 Vanadium ND 1 5.0 2.5 ug/L 04/29/2021 2008 Zinc ND 1 10 2.5 ug/L 04/29/2021 2008 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 145 of 166 ICP-MS Metals - LCS Sample ID: WQ90580-002 Matrix: Aqueous Batch: 90580 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/29/2021 0948 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 100 1 101 80-120 04/29/2021 2014 Arsenic 100 100 1 102 80-120 04/29/2021 2014 Barium 100 100 1 102 80-120 04/29/2021 2014 Beryllium 100 100 1 102 80-120 04/29/2021 2014 Cadmium 100 100 1 103 80-120 04/29/2021 2014 Chromium 100 100 1 100 80-120 04/29/2021 2014 Cobalt 100 100 1 100 80-120 04/29/2021 2014 Copper 100 100 1 103 80-120 04/29/2021 2014 Iron 1000 990 1 99 80-120 04/29/2021 2014 Lead 100 95 1 95 80-120 04/29/2021 2014 Manganese 100 100 1 100 80-120 04/29/2021 2014 Nickel 100 100 1 101 80-120 04/29/2021 2014 Selenium 100 96 1 96 80-120 04/29/2021 2014 Silver 100 100 1 101 80-120 04/29/2021 2014 Thallium 100 96 1 96 80-120 04/29/2021 2014 Vanadium 100 100 1 100 80-120 04/29/2021 2014 Zinc 100 94 1 94 80-120 04/29/2021 2014 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 146 of 166 ICP-MS Metals - MB Sample ID: WQ90649-001 Matrix: Aqueous Batch: 90649 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/30/2021 0355 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 05/03/2021 1402 Arsenic ND 1 2.0 1.3 ug/L 05/03/2021 1402 Barium ND 1 5.0 1.3 ug/L 05/03/2021 1402 Beryllium ND 1 0.40 0.15 ug/L 05/03/2021 1402 Cadmium ND 1 0.50 0.13 ug/L 05/03/2021 1402 Chromium ND 1 5.0 1.3 ug/L 05/03/2021 1402 Cobalt ND 1 5.0 1.3 ug/L 05/03/2021 1402 Copper ND 1 5.0 1.3 ug/L 05/03/2021 1402 Iron ND 1 50 13 ug/L 05/03/2021 1402 Lead ND 1 1.0 0.25 ug/L 05/03/2021 1402 Manganese ND 1 5.0 1.3 ug/L 05/03/2021 1402 Nickel ND 1 5.0 1.3 ug/L 05/03/2021 1402 Selenium ND 1 5.0 1.3 ug/L 05/03/2021 1402 Silver ND 1 1.0 0.25 ug/L 05/03/2021 1402 Thallium ND 1 0.50 0.15 ug/L 05/03/2021 1402 Vanadium ND 1 5.0 2.5 ug/L 05/03/2021 1402 Zinc ND 1 10 2.5 ug/L 05/03/2021 1402 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 147 of 166 ICP-MS Metals - LCS Sample ID: WQ90649-002 Matrix: Aqueous Batch: 90649 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/30/2021 0355 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 100 1 104 80-120 05/03/2021 1356 Arsenic 100 99 1 99 80-120 05/03/2021 1356 Barium 100 100 1 103 80-120 05/03/2021 1356 Beryllium 100 110 1 112 80-120 05/03/2021 1356 Cadmium 100 95 1 95 80-120 05/03/2021 1356 Chromium 100 100 1 100 80-120 05/03/2021 1356 Cobalt 100 99 1 99 80-120 05/03/2021 1356 Copper 100 100 1 101 80-120 05/03/2021 1356 Iron 1000 1000 1 105 80-120 05/03/2021 1356 Lead 100 110 1 107 80-120 05/03/2021 1356 Manganese 100 98 1 98 80-120 05/03/2021 1356 Nickel 100 100 1 100 80-120 05/03/2021 1356 Selenium 100 89 1 89 80-120 05/03/2021 1356 Silver 100 110 1 106 80-120 05/03/2021 1356 Thallium 100 100 1 105 80-120 05/03/2021 1356 Vanadium 100 98 1 98 80-120 05/03/2021 1356 Zinc 100 94 1 94 80-120 05/03/2021 1356 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 148 of 166 ICP-MS Metals - MS Sample ID: WD28014-009MS Matrix: Aqueous Batch: 90649 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/30/2021 0355 Sample Spike Amount Amount Result %Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony ND 100 110 1 108 75-125 05/03/2021 1420 Arsenic ND 100 100 1 102 75-125 05/03/2021 1420 Barium 190 100 290 1 102 75-125 05/03/2021 1420 Beryllium ND 100 120 1 118 75-125 05/03/2021 1420 Cadmium 0.13 100 96 1 96 75-125 05/03/2021 1420 Chromium ND 100 100 1 101 75-125 05/03/2021 1420 Cobalt 10 100 110 1 95 75-125 05/03/2021 1420 Copper ND 100 98 1 98 75-125 05/03/2021 1420 Lead ND 100 100 1 103 75-125 05/03/2021 1420 Nickel 33 100 130 1 93 75-125 05/03/2021 1420 Selenium ND 100 94 1 94 75-125 05/03/2021 1420 Silver ND 100 100 1 102 75-125 05/03/2021 1420 Thallium ND 100 100 1 102 75-125 05/03/2021 1420 Vanadium ND 100 100 1 102 75-125 05/03/2021 1420 Zinc 8.8 100 100 1 94 75-125 05/03/2021 1420 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 149 of 166 ICP-MS Metals - MSD Sample ID: WD28014-009MD Matrix: Aqueous Batch: 90649 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/30/2021 0355 Sample Spike Amount Amount Result %Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Antimony ND 100 110 1 108 0.37 75-125 20 05/03/2021 1426 Arsenic ND 100 100 1 102 0.00 75-125 20 05/03/2021 1426 Barium 190 100 290 1 106 1.3 75-125 20 05/03/2021 1426 Beryllium ND 100 120 1 118 0.17 75-125 20 05/03/2021 1426 Cadmium 0.13 100 98 1 98 1.8 75-125 20 05/03/2021 1426 Chromium ND 100 100 1 100 1.4 75-125 20 05/03/2021 1426 Cobalt 10 100 110 1 96 0.95 75-125 20 05/03/2021 1426 Copper ND 100 98 1 98 0.47 75-125 20 05/03/2021 1426 Lead ND 100 110 1 106 2.0 75-125 20 05/03/2021 1426 Nickel 33 100 130 1 96 2.2 75-125 20 05/03/2021 1426 Selenium ND 100 94 1 94 0.42 75-125 20 05/03/2021 1426 Silver ND 100 100 1 103 0.58 75-125 20 05/03/2021 1426 Thallium ND 100 100 1 104 2.2 75-125 20 05/03/2021 1426 Vanadium ND 100 100 1 103 0.68 75-125 20 05/03/2021 1426 Zinc 8.8 100 100 1 94 0.20 75-125 20 05/03/2021 1426 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 150 of 166 ICP-MS Metals - MB Sample ID: WQ90835-001 Matrix: Aqueous Batch: 90835 Prep Method: 3005A Analytical Method: 6020B Prep Date: 05/03/2021 0426 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 05/03/2021 1615 Arsenic ND 1 2.0 1.3 ug/L 05/03/2021 1615 Barium ND 1 5.0 1.3 ug/L 05/03/2021 1615 Beryllium ND 1 0.40 0.15 ug/L 05/03/2021 1615 Cadmium ND 1 0.50 0.13 ug/L 05/03/2021 1615 Chromium ND 1 5.0 1.3 ug/L 05/03/2021 1615 Cobalt ND 1 5.0 1.3 ug/L 05/03/2021 1615 Copper ND 1 5.0 1.3 ug/L 05/03/2021 1615 Iron ND 1 50 13 ug/L 05/03/2021 1615 Lead ND 1 1.0 0.25 ug/L 05/03/2021 1615 Manganese ND 1 5.0 1.3 ug/L 05/03/2021 1615 Nickel ND 1 5.0 1.3 ug/L 05/03/2021 1615 Selenium ND 1 5.0 1.3 ug/L 05/03/2021 1615 Silver ND 1 1.0 0.25 ug/L 05/03/2021 1615 Thallium ND 1 0.50 0.15 ug/L 05/03/2021 1615 Vanadium ND 1 5.0 2.5 ug/L 05/03/2021 1615 Zinc ND 1 10 2.5 ug/L 05/03/2021 1615 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 151 of 166 ICP-MS Metals - LCS Sample ID: WQ90835-002 Matrix: Aqueous Batch: 90835 Prep Method: 3005A Analytical Method: 6020B Prep Date: 05/03/2021 0426 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 100 1 102 80-120 05/03/2021 1621 Arsenic 100 98 1 98 80-120 05/03/2021 1621 Barium 100 100 1 101 80-120 05/03/2021 1621 Beryllium 100 110 1 114 80-120 05/03/2021 1621 Cadmium 100 94 1 94 80-120 05/03/2021 1621 Chromium 100 96 1 96 80-120 05/03/2021 1621 Cobalt 100 95 1 95 80-120 05/03/2021 1621 Copper 100 99 1 99 80-120 05/03/2021 1621 Iron 1000 1000 1 102 80-120 05/03/2021 1621 Lead 100 100 1 103 80-120 05/03/2021 1621 Manganese 100 96 1 96 80-120 05/03/2021 1621 Nickel 100 97 1 97 80-120 05/03/2021 1621 Selenium 100 85 1 85 80-120 05/03/2021 1621 Silver 100 100 1 102 80-120 05/03/2021 1621 Thallium 100 100 1 101 80-120 05/03/2021 1621 Vanadium 100 96 1 96 80-120 05/03/2021 1621 Zinc 100 88 1 88 80-120 05/03/2021 1621 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 152 of 166 ICP-MS Metals - MS Sample ID: WD28014-022MS Matrix: Aqueous Batch: 90835 Prep Method: 3005A Analytical Method: 6020B Prep Date: 05/03/2021 0426 Sample Spike Amount Amount Result %Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony ND 100 110 1 106 75-125 05/03/2021 1633 Arsenic ND 100 98 1 98 75-125 05/03/2021 1633 Barium 150 100 260 1 105 75-125 05/03/2021 1633 Beryllium ND 100 120 1 116 75-125 05/03/2021 1633 Cadmium ND 100 92 1 92 75-125 05/03/2021 1633 Chromium 4.6 100 100 1 96 75-125 05/03/2021 1633 Cobalt ND 100 91 1 91 75-125 05/03/2021 1633 Copper 1.7 100 96 1 94 75-125 05/03/2021 1633 Lead 0.32 100 100 1 102 75-125 05/03/2021 1633 Nickel 4.1 100 96 1 91 75-125 05/03/2021 1633 Selenium ND 100 89 1 89 75-125 05/03/2021 1633 Silver ND 100 100 1 101 75-125 05/03/2021 1633 Thallium ND 100 100 1 101 75-125 05/03/2021 1633 Vanadium ND 100 98 1 98 75-125 05/03/2021 1633 Zinc 3.8 100 92 1 89 75-125 05/03/2021 1633 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 153 of 166 ICP-MS Metals - MSD Sample ID: WD28014-022MD Matrix: Aqueous Batch: 90835 Prep Method: 3005A Analytical Method: 6020B Prep Date: 05/03/2021 0426 Sample Spike Amount Amount Result %Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Antimony ND 100 100 1 105 0.86 75-125 20 05/03/2021 1639 Arsenic ND 100 97 1 97 1.1 75-125 20 05/03/2021 1639 Barium 150 100 250 1 101 1.5 75-125 20 05/03/2021 1639 Beryllium ND 100 110 1 115 0.78 75-125 20 05/03/2021 1639 Cadmium ND 100 90 1 90 1.8 75-125 20 05/03/2021 1639 Chromium 4.6 100 100 1 96 0.70 75-125 20 05/03/2021 1639 Cobalt ND 100 91 1 91 0.66 75-125 20 05/03/2021 1639 Copper 1.7 100 94 1 92 1.7 75-125 20 05/03/2021 1639 Lead 0.32 100 100 1 101 0.98 75-125 20 05/03/2021 1639 Nickel 4.1 100 95 1 91 0.88 75-125 20 05/03/2021 1639 Selenium ND 100 90 1 90 1.5 75-125 20 05/03/2021 1639 Silver ND 100 100 1 100 1.0 75-125 20 05/03/2021 1639 Thallium ND 100 100 1 101 0.099 75-125 20 05/03/2021 1639 Vanadium ND 100 97 1 97 1.4 75-125 20 05/03/2021 1639 Zinc 3.8 100 90 1 86 2.3 75-125 20 05/03/2021 1639 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 154 of 166 CVAA -MB Sample ID: WQ91048-001 Matrix: Aqueous Batch: 91048 Prep Method: Analytical Method: 7470A Prep Date: 05/04/2021 0602 Parameter Result Q Dil LOQ DL Units Analysis Date Mercury ND 1 0.00020 0.000091 mg/L 05/05/2021 0703 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 155 of 166 CVAA - LCS Sample ID: WQ91048-002 Matrix: Aqueous Batch: 91048 Prep Method: Analytical Method: 7470A Prep Date: 05/04/2021 0602 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Mercury 0.0020 0.0019 1 95 80-120 05/05/2021 0706 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 156 of 166 CVAA - MS Sample ID: WD28014-002MS Matrix: Aqueous Batch: 91048 Prep Method: Analytical Method: 7470A Prep Date: 05/04/2021 0602 Sample Spike Amount Amount Result %Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Mercury ND 0.0020 0.0020 1 101 80-120 05/05/2021 0714 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 157 of 166 CVAA - MSD Sample ID: WD28014-002MD Matrix: Aqueous Batch: 91048 Prep Method: Analytical Method: 7470A Prep Date: 05/04/2021 0602 Sample Spike Amount Amount Result %Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Mercury ND 0.0020 0.0021 1 103 1.4 80-120 20 05/05/2021 0717 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 158 of 166 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 159 of 166 �0 <" m D vv m 0 m v� COD � r co n 0 o c m 3 �co 1 3 CD V C N 0 W CD � V � O y CD -4 V 0 O CD O y T z3 N n X �- co O w V n O E3 ACE= ANA`IYT-I AL"S'ER1VI r=L _ IOIJ vunCage Point L)rira , west c-wumbta. 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Wej-e all €arrples 1• Civcd within � [hr, hoiding ti.m or 48 }lours, kr Ac[ieyw_r q.vmles I'trst7 l5+�r , Were sarnrim cor-tajun m(cirlcle 0110sainpiesNo' lisSfd or1Coc? ❑> 16, Fur VC)A ap-d RSK.175 Samples, wcre bt,buJe; present>-0°pea-,, nk ari. of the VOA v:aL31 ('}�"Or Gmrr in diameoer) v J1ti. 17, Wem all I)]li[ y c ;5/r_kLLri�nt�4eivedatapIIOf,..�2? h]r 18. V11Cre all uyeni& MMJplL..j rrxe'ved a: a p1-I > 12 and suiFcin s rL,rrlCL received ai n� Ye?�N n pI I 78a miler,frCC a ❑yaq: ❑No D111:q 20- W:ro client real&&-slrEgUC9ts U-c, rcquecled dilutions [�1SfMS,�dosigntltiaur'roc"-•) corrtx by transcribe) from the COC into tfLe 013M rnt 3eckJon Ill F.]MS? _ `es No �I- WRS the LOLL. uu-nber il5tcd art tlw enrttaineY label? Tf r,� �NA]' 40te 3arnplc PreservHtian (MLS-1 bL• completed faranymmPle(s) irlemoPtl 5 pceL1 etl or wily ,tcadspac,e.) Sartrplt(sj wcsc t-erxived incorrectly Fremv--d inert vrere adjL SLed aCCO"ding[y in saMpic Jtceivmg with "A --nL of circle awe; Hn04, HN 03. PC:I, NaOH using SR # w I'bre of Pft-NMMtiu9 if nitlrr than une pre;c-rvat:vu is neetlad, [a]L Asa Latta in the caLUrncn#s haiow, Sz,mp,e(S) N� ~were rece:vrid t4�i@I bubbles >& Ili rq in di arnster, S�lrple-v(s) F+^ _wcLreLeivaativitF 7RCQ,SrnL{[f>ki9 isuajsnduerc acjus[xl accordin[;ly insalrLplr: recelviB9WjLhsodKlnt [i1JUSLLJfi1'e Fh1fx O'a} With S;se€il,r 1D. NA SK bare6de bbVIs apt I i c d=hy;J�R _ L1a4e: C.0L-li`Tne lk= COL[,EC'r[On' rAllt ACIDT(ME 7A1cCNf PRi)KI CX)lATAINF,145 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 161 of 166 E3 Av"19 PACE ANALYnCAL SERVICES, LLC c F7 IffC? 1 rx} VRr4age Poirit Diivc' r Vdebi Colijmbea, 9C �9-7 dumber T¢19ph0.� No. B0-T£7-�7Q¢=8xN0.803•'?91-9717 v��nu.pae�3abs,cam Twophaw M0. r E, ,..T JLM i51D_ k J } - Ir. r` $�J7e'IffJr� .�gy�'i'p �idLil 421 � tih�r9 r.}�rrr. ae F'PR4�{� fad' x�ar 'AjC-02 C �+ ari,�Lr:r,4arrta !'+ Prri,rrs�d ,547ma -- -Qrl 15 illilill 1 yy L.7 $,�(q fUf [apf.'vr Gu1,cY4rr - oraci4n T.I.Wo P {.j 6 v rlr7feiuriiCfaxh�ngtlaT9jtJL•JII�'I_S�NI+v�J?*y liftfli i7hkift) '► �{ f m?r.+s,v aE ra. b ig 40 j&c:ll 1 r f t1 3 3 1 � - It I 4 ._. _ 'OBI IV -A r ' _ 4�K - a7 P4FNa cr He raid k-ftd �' M-r DNrn-+Zua LI:4rrrrk*l; CSFi.il.-rlut--POL+ar1 GUliluiatim ]bm Aimrd Tj" PoW hand lf3FldD aporeret fYf v1 -V.YJ f., w4 W TAr. .:-ISfana" E:Pua 1 r SampJC A�ppsa' -7rfernlnLrhrt_:,4kCae.wLfrm - Q ; rie�r rrrtr ynrs (SpaerJ}r1 f a. ,"quuslrt7dL — 0115e ry ry Jim& 1. RCc�rLcdbF nay c Kdtrl s F?6aLi4WYby D" Tkh} 2. F7a8z7r rreo by a ffi�r'.'iphr8iooby 4 1'rH4 DO! TA-62 RIM i agre UTi9 fYJg TAM" Ylg.l1711 i' tcl J z __ d. L&e A kxy roDS -g T"- NoLe, AW sarr ara fP�a�r re[! # r fvUr Lwsks tron recho L.lS VSE CALY Tarn H�,x U iv un-la " s whor ni!ngernores 8Y9 Jae PsrJt flavour RavEnved zw ee f CtC Pia i ) fiacrfrr'irrr..__ 'G' LfS1H)VUrIOJY KWO—I-A 1�LON &IL'.r(rIDLWXoiY4ywd.46xn mj%1FAW-FizhgC.Y oropy roc„itir.:riMurl.r:r-iAF7pfi1c�-0? " D m D D n cn m 0 m cn r r 0 �0 <CD m D vv CD C - 0 0 m o co N � r r N 00 ccD vy 1 � CD V C N 0 � CDo� V � y CD V ci o b o� CD X rn cs o V 0 E3 r7eAria{y ical i eNcru Ian ; Y (L�a,,�,:ga fa' aac4 savy� r.�a}' dN nmlanup oa crs5tsl RACE ANALYTICAL SERVICES, LL 109 VEn1[ qe Pohl Ddwa r Nest G_luribia, W 29172 Teleshcm-;� NO. 803-79147c1❑ Fax NCL803.701-9111 ,^vf. PaC9161b5,00ln Repeat ru cr,r�acr e Wrnfec{I.'amc !aL 6�.,v� s ,wady .,��rr�.,•r<;n�r� fia4�nitira C<4T6C1'Ora }rme � � � � � narn.gj r.�ryF 22 TeteP&W NO, {g.rnSW Number 119891 QUOM AU r7Ck I liffi ,U5 W028014 �aa T I - nL-n A -und 1-w r ROW red (Pmww-PA ra"FRl,Uyrd WL-Aj& cAg W., J Ssn. A.? ]:errr. f Fbsswe Haza c i0er,rnSr jams riC' fieG� rdRrf C. Go y� ❑ Siarrabrd 7 Rij [ti�teify) I:J,ia±� nMIVF ht U �ksyrxlb}tap C r&r�d r Fbrgag iC U S" Incei{ ;j] Ptr.Eon I : unF wmii f.F,cJrbQ&arePny Us2a Twm! i s_ F4,,r"by 2. Ri4hCuis4edby ,7sfa TM J7NGY� 6dQy }are Tnc ' - .i. dirl?GCN9hed$p M1 F,4rre 3. ftbsei y 4Yl�€ rfmc '�-- $ fde� qurxhodtl L ! y d, daoa'sfcr re iV:�p TMw AW&_'A�1,�•gr�Vkp sartn_,taAaeJky-;uurWiimi�fr fr4801Fr�lr 7urrcarrrrnk _. Y LN ~- — rmL-ssolhor %ar.*reffi ntsar&rT7 de. r3e u,nav(F,4c,'el }e3 Nn ber�ack +3rrg�7rT§ Mi'Rr8lJ7 ON t%ftTc $ r'E LIGVFW4, m t2 fad Ore Wr wa:.7. 7,PLS�13)-PIPOW rkf&,c s,-f eit :nrrw.4 Vum46Y'biE04 fJ 01 PACE ANALYTICAL SERVICES, LLC Samples ReceipC {hftkll`M (SRC) (MEU03-K-15) RVAS°d:9129f2020 ° r 7'S � 15�;1i11R.Autihorityr Pate Er,IV Yrcc L. Page vF 1 a11 Ple RMCiPf Chtc1dist (SRC). C lierk; P�} C'OLNlr lnsprr#ed b}','talc: -]k4,1 1 0dP_3i2021 W'fi}S0l•1 v]Flk i}f rrc•-Lpr'I Nice }liunr lips - redrx- YeS � �10 1, ydQL'2 CLlylp[)� SC218 refiertt OLl die txlVCr� �. Yes I JNold 1hTA 17.- If cusfedv s als were-,rese%, v;cn they iniMt and wil�rukcn'? pH I*irip 0= xa-27i2 {7L:orirse trip ]a. 0lasoed by: JR original tempefaturo upon receip. f Uerived (Ctan=cd) temperature uprrn nxeipt VO 01id Srnap-.Up ID_ r<A DNA ,C NFL [till }c 1qA /-AA 'C Method: E[I'i; tperawm Bank ❑8.gainst 13otC:cs lRGlin ID; IR GoII C'nneC[iot5 Factor: � Ic Method 41'coolant: IEJ w-el [c: Q Ice Palcl4,w ❑ 1?1 Icc ❑ hTilnr. — ❑ Yes ❑;U ❑, N4;' ]f L�Inprraarel'�ny +aaler exe+xled 6-0°C. Maas J'roiect ]�ALiAger 1{L}ti,�ed2 d by_ phone i emai i ,' faaa to-flvxx; (eincle one). Yes Ma �J.4 4- Al eDurier's ps;cl:iltgslip alfachpd rta t[,is form?Vr Y Nn {. ady procedurun (eaIh1 lisl10Vreccivad) fg!lgwV Msamp1c1DL,;li6tcdonrheC0C?._ Yc6 N{I 6ed on the C0C7 ✓ Ycw No 7, Were sample JJ]s IisWd anal] sampJc contaioers7 Y:s No 8, Was Miccton dne & tune [i sted an the CQC° ❑ycs Nu 9, Was call ection 6LC & Iime listed 9n all Ran,plecontaiimi-s des ❑ Nv 10, Did all 00RIaliitt label information (ID, datu, time} abrce v.'i#11 the Ci}C9 Ycs_J N, I1- Wwc tests to be FcrfOrtnod listed on thaCm Q Yw ❑ No T2, Did all sarrlples ar'riw: in talc prGT,crc.4rrm mrs for egc?h test ardlor ni go0d rondi'[on (Lrnbr42&Xrr, ]ids on, T W35 aclegLlr,lcVAmplevolUmg available?Wcwe a]I-+4 Plcs received vridLn is Lhc tnJdill gtulle014S 11111L1r3, whidner comes first's Yr + NO 15. W= any samples cop-tainers ntissin 'excess (cin le onc) samples ll9t lister] an COCF ❑ Y No ❑?+]A 16. For vnA snd RSK-175 szmp]es, were i�eL �bl� present -_"pea•si e" f'"or 6inm in d raE�saterj _ in any of it r, VO/, vjai 4? UYTNL3 NA 17- Were ail DRt}imcmisliutricnt sampl�h reccivaLE at iL pH of�. �� TN-� IS. Wcrc all cyan:du samples recai wex[ at a p14 > 12 arA suitido sample; rr.=ived at a p H : 4? samples frc p- 'ere al appliCSL c N ] IfT3' ..: erla Il ii ,11 8.3 ns c: of ❑ Yes El No NA -} (' U.� n r sldaa[ chTfwinp'i 6+L } sap ❑ Y ❑ No ❑J NA 20, 'Wcne cli-L-rlr mn rksir�gkle= (i-t;, -vquwed aihltion� N &NISD rle:c=Ematio-ts. + vrrect,y Iransp'lbed frurl `.he CDC into the r6m Lrtcnt sect on in LI NIS? .Yes LJNz E21, Was Lhc uucfte. ri,,-nber lister on the cmtAi- _,ar 136e1? 1f vcR, uotw tl atx,a Sample 11'resen•ation (Must be coinp]eteri Car any sartplC(S} i€Lcarre�tl} presarvcd o- w=t1�=L4hry1-'sPace.) arnple(5]."^ �vcrereceivod incurrcclly -;v�e:y� auk ncrc Adjnsted ncoardiL:g9y ]rl san7111e r�eivin�, witfl 1`1A mL 9fcirc]oana:1���{�1,11I4D3, HC], l�'a{iH u.xin+� Sf1_# �'� ime orpresen-atlon VA Ifn0M t[taa uu0 mzerwative is naecle,J, please nplC i l the commci;3 belLrY, SampRe(s)' urc rCt!ired w_tll bubbles5 rrlrn in dip,-rstcr. Samalss(s) NAwere rccY:vcd with TRC r 0-5 mLJrL Of �19 is no) and were djn3red xccarlingly in sample receivi-lg with sodium thi0;ultorc:(1�i1a 5�C }witF '�Jicnly ID: NA H lz mWQ Jakb. npp lied by: JR02 l7at,,: 04��9,"2ti21 Cori wnwasz Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 164 of 166 �0 <CD �> ;v v CD C - 0 0 °� rn m o m N � r C� 0 o� ;_ CD 3 �Co 1 3 0CD V C N 0 zs W CD � V � �C CD V 0 O CD oy b q X 0 E3 Pa"ceAi u! freak {r M fZ�2 _ AX- P ,scf 1io P p f;v. A+zhir h'a a1 QGf fkS d x lGJn �Ribfu&rY Lr.lkj P,ii �'T �r4ak.'neySe#a�kgadan rror':m) eakf�J (rx FACE ANALYMAL SERYfCE$, LLC 1 % Ventage FOIfrt Ddvo - West Colurnbla. 3C 29172 TA,ep�cneNu. FR9-79f47ci) Fax too-aQ3-J51.9177 x4wur.�.aaelahs. Qom %rreArpWid TL7rc c1 ^vrr!(P r�yBPPMQre�rrr5� furxgr l!5d7P bl-di� Fk1h (sP&-A,oY) Y- by a MM'Mrufahedby FSEMN M=1 S-P:a L?r#+r+.o K..Ti lfu ++4irafd;drnrrKgf�Sxxr u Re."MJIK*.nr L LUPMf 'Jab r• Nl.,hrWaxd r r1 mlr7Lla ° i Min IrIiIaTI LI FC12on LI immxm Dam i. Ft r I? [� 1i S. F7Ew'Y %W!aY !?;,q asJnecr Gy rR!a iR71a 4. Lsborera} ri7cafkar7 bj - Nvsrf , AP a& _ 1 f are ret�ir rJ for 14eWr W ehs rr�m roo�w t d as r o+ r rin other r7enis sr r r, dE _ �ac,�t a m� e � 1a*� Ab 4---p PacxV 815TFlIHlJTJUJ'f: Wrl A YE-CCOW- A9YlAT Vqh $WPAkif6L PbVK F, ie171 GW l Number ilSV2 GV(4v Na. 43 + i a� —I LofjFRvGbce fw6w MW §m�,'rEelbpEr�+ryr' oa:e Tvw f .7 5 e)L Damp TV T-qy .'A k Y ON in adramenf N/fuApr; f7itiN'-l�r D m Z D n D 0 m cn r 0 PACE ANALYTICAL SERVICES, LLC Samples Re 1pt Checkplst l (MEODISC-151 .2Ce 4, Jytrc.�l 15suling All harli l; Pace &W - blrl ample Receipt Cheil ( RQ Ciserr� B]„� [wi ohs Jlt5 _ eut 00_er 'I n. 21 s1012021 Lot �: W13290'4 UPS - YLn w' H o edEO I , Warr Cusltl seals p: Lsl the QuaCcr? Yes Tin J NA 2_ TCcustnri se7Js vrcre Ont. 1nQrC ey intact artd Ltnbril !! StripID27-271� = _.. _ Chlorine "itrip Ip; Tester' ll — OriginHf telrlperature upon rl i Derived (('arre0l WMJ)l upon rcreipl Sojid 5l in: Nor 4-2 14.2 cC IVA j yA 1C NA ' KA v NA I l oC — l+i[edlad: E TMpoualure 13Jallk al 201.Ek�s ER Our] JD; e: K1etil"KI V l _ lk G',:i Co-rultian Factor- Qt Ll Wet doe Yes � 10 oeEjNone ,I]NA I-_ T`tenpGrature c►iany conic vxcreded 6,OOC, wars PrCajoct hriaaa ei No[iiieri? — PM was Notl by, pfill f email! faze-To-fbCe (c1:wiC olio). Yc�l No , NA 4, J,s 11l CommAl etwl Twkin;_al:uislp altaoJfeJ Lu this fQrm 7 1 Yes NG 5. WwQ �Z7�rPi' Cl pril dLlY[;4 (i'2 [in it df q rl fa [iawad? { Yc�s NO Cr_ Ill samp,e IDS [isted cv, the fiGC? Yee ,Jar' 7, Wcrc satnplo ID,; ] i.s;ed -w all saropl a rontaffil Yes No R, Wa, solJecti4n dp19 a time ]rsl,r] L)n the MC9 Yes Ne 9, Was Collaciis*rl date & tiu,c listed on all alampie Containvil J YIll NO Hri co -Lim[ rlJ infon,tatiorl {Ili, Llate, time) t3�r4� }with the Cli'S 1VD 1 !. lV-'rc xsts tt, be p4'rf'amed [isle[] M tilt; COC 'vJ Y,�9 IVo 12, Did a] I Sam pies an'1vu in E1,� proper won ,finery far eaa�t, tell unLL'or in good conditinh (unhmker4 lids on, ctc_)? Cw'S�d:��'7�}f2024 L�Uyeyj I-_IAo 13.'6 aclecluate',;Ml lc "[Ltrrlpavailnbl ? YC 14. Were a[1 sompli~s rC eiMetJ Will itl'A lbe holding time n1 48 h airs, w liche�vx comes sL7 Y No 15. Wcrccry gaIII p]rw Col,lal missin exc y{circle one}sam iws No: lis, o„ C 1] Yes ONG LJNA 16. T[lr' ,C)A ap_d RS-175.4ampies,,* l bc[lhies prrZcnt>"P-,a-ti-3ac" (3��'a� 6mrn in Ili �n hi any of: le �,C)A v:als7 J Yes No NA 17, kVerC �Il DRt3hue�stislntl lriantsumpies tCCtivcd at a pH of � Y� i�3a V. IS V�l aJ[ cynnidn yarn !e: rcce 114at: I pi I } I? n_td sLLItltla samJaJCs rr ,CiVct1 rit a pH 9? Yes C1 T„I NA J9. WeIC a aJ-1 livable FIB "-NICw11,I,e}F lefJQr6'ti'2.5_T $.? l O,Srng;[.) samples l t -Ra. a.,ai �.1.._.__� ?i] Yc: [j N ]NA 2fl. U0eue eliCnt remai-kwyaquesfs ae_ rc9'le50ad diLrGionS, 14]SII I I] c4rte ly lranscL7bod frlfm tf�C Cl mta t1iS: cmmn,t uCdrrn in LIM E �,aliOns, cic, L/ No 21. -aJ fhe pots number Ii kqd on-- the �untaineT [ai�el? ff' c5, Litrle g NA — 5&mtrle F1 gervs�ti0u (Mu.%j. ore COrnpieied for ur_v €arrrple(s) incorrCC#I 3 1 ^e= 'vcd t1r witlt I'Mds e ampIl A � itl MM91ore�ivin With rxrl were "Waived itleOJrctitiy "Served and Wccc d sun recta rn1, cf GirS;le lire: H2SO4, HN0 3 ii I 'AE?T1 usirL R t# A Ln1L'.4F1}r Scr4'At]Mt NA I€ruure ttl�n ot:e — •— pr'eservativc fs uaed�d, prase riots in #Itio tiammenls l,ek�w. 5pinplL:(s) �� — wem revolved wi(h bu 3bJ� >6 in di{l SampleS(s) _ _ 1�rere received n�itft TRC> f),5 m&iL jf:q-q �# 120 } ,d dlusted accL repEsg13 is sarrtF:e rOcoivfng with scdl thioxulPal S,0 with S[tlly ID: (filar _ �) ftiA SR baratt,la laf�_.s applied by; ]lxt:x 0113U+2t721 _ Late; _ CQmtutx,tg! , — nagiy Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 166 of 166 0 aceAnalytical Report of Analysis Bunnell-Lammons Engineering, Inc. 6004 Ponders Court Greenville, SC 29615 Attention: Andy Alexander Project Name: Active Buncombe County Landfill Surface Waters Project Number: J21-9378-23 Lot Number:WD28006 Date Completed:05/07/2021 N N NO � � J 05/11 /2021 3:15 PM Approved and released by: Project Manager II: Lucas Odom PCCRF� 24rA SOA / ANSI National Accreditation Board A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 57 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Bunnell-Lammons Engineering, Inc. Lot Number: WD28006 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. VOCs by GC/MS The following sample was diluted due to the nature of the sample matrix for SIM analysis of 1,4-Dioxane: WD28006-006. The LOQ has been elevated to reflect the dilution. The third run from a headspace vial has been reported as run one had a detection due to suspected carry-over and run two failed internal standards below method criteria. The following sample was diluted for VOC analysis due to the nature of the sample matrix: WD28006- 006. The LOQ has been elevated to reflect the dilution. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 whw.pacelabs.com Page 2 of 57 PACE ANALYTICAL SERVICES, LLC Sample Summary Bunnell-Lammons Engineering, Inc. Lot Number: WD28006 Sample Number Sample ID Matrix Date Sampled Date Received 001 SW-1 Aqueous 04/26/20211015 04/27/2021 002 SW-2 Aqueous 04/26/20211105 04/27/2021 003 SW-3 Aqueous 04/26/20211205 04/27/2021 004 SW-4 Aqueous 04/26/20211310 04/27/2021 005 SW-5 Aqueous 04/26/20211240 04/27/2021 006 SW-7 Aqueous 04/26/20211125 04/27/2021 007 SW-8 Aqueous 04/26/20211040 04/27/2021 008 Trip Blank Aqueous 04/26/2021 04/27/2021 009 SW-6 Aqueous 04/27/20211110 04/28/2021 (9 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 57 PACE ANALYTICAL SERVICES, LLC Detection Summary Bunnell-Lammons Engineering, Inc. Lot Number: WD28006 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 SW-1 Aqueous Barium 6020B 79 ug/L 7 002 SW-2 Aqueous Barium 6020B 57 ug/L 10 002 SW-2 Aqueous Chromium 6020B 1.5 J ug/L 10 002 SW-2 Aqueous Nickel 6020B 1.7 J ug/L 10 003 SW-3 Aqueous 1,4-Dioxane 8260D (SIM) 14 ug/L 12 003 SW-3 Aqueous 2-Butanone (MEK) 8260D 4.1 J ug/L 12 003 SW-3 Aqueous Barium 6020B 250 ug/L 13 003 SW-3 Aqueous Chromium 6020B 3.8 J ug/L 13 003 SW-3 Aqueous Cobalt 6020B 42 ug/L 13 003 SW-3 Aqueous Copper 6020B 2.8 J ug/L 13 003 SW-3 Aqueous Lead 6020B 0.39 J ug/L 13 003 SW-3 Aqueous Nickel 6020B 19 ug/L 13 003 SW-3 Aqueous Vanadium 6020B 4.4 J ug/L 14 003 SW-3 Aqueous Zinc 6020B 7.8 J ug/L 14 004 SW-4 Aqueous Barium 6020B 120 ug/L 16 004 SW-4 Aqueous Chromium 6020B 2.8 J ug/L 16 004 SW-4 Aqueous Cobalt 6020B 2.6 J ug/L 16 004 SW-4 Aqueous Copper 6020B 3.1 J ug/L 16 004 SW-4 Aqueous Lead 6020B 0.49 J ug/L 16 004 SW-4 Aqueous Nickel 6020B 5.5 ug/L 16 004 SW-4 Aqueous Vanadium 6020B 3.8 J ug/L 17 004 SW-4 Aqueous Zinc 6020B 20 ug/L 17 005 SW-5 Aqueous 1,4-Dioxane 8260D (SIM) 6.1 ug/L 18 005 SW-5 Aqueous Acetone 8260D 5.1 J ug/L 18 005 SW-5 Aqueous Tetrahydrofuran 8260D 1.4 J ug/L 19 005 SW-5 Aqueous Barium 6020B 110 ug/L 19 005 SW-5 Aqueous Chromium 6020B 8.6 ug/L 19 005 SW-5 Aqueous Cobalt 6020B 12 ug/L 19 005 SW-5 Aqueous Copper 6020B 2.2 J ug/L 19 005 SW-5 Aqueous Nickel 6020B 17 ug/L 20 005 SW-5 Aqueous Selenium 6020B 2.0 J ug/L 20 005 SW-5 Aqueous Zinc 6020B 17 ug/L 20 006 SW-7 Aqueous 1,4-Dioxane 8260D (SIM) 7.2 J ug/L 21 006 SW-7 Aqueous Acetone 8260D 35 J ug/L 21 006 SW-7 Aqueous Antimony 6020B 2.9 J ug/L 22 006 SW-7 Aqueous Arsenic 6020B 21 ug/L 22 006 SW-7 Aqueous Barium 6020B 300 ug/L 22 006 SW-7 Aqueous Chromium 6020B 120 ug/L 22 006 SW-7 Aqueous Cobalt 6020B 66 ug/L 22 006 SW-7 Aqueous Copper 6020B 28 ug/L 22 006 SW-7 Aqueous Lead 6020B 5.9 ug/L 22 006 SW-7 Aqueous Nickel 6020B 110 ug/L 22 006 SW-7 Aqueous Vanadium 6020B 59 ug/L 23 006 SW-7 Aqueous Zinc 6020B 110 ug/L 23 007 SW-8 Aqueous 1,4-Dioxane 8260D (SIM) 1.8 J ug/L 24 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 57 Detection Summary (Continued) Lot Number: WD28006 Sample Sample ID Matrix Parameter Method Result Q Units Page 007 SW-8 Aqueous Arsenic 6020B 2.6 ug/L 25 007 SW-8 Aqueous Barium 6020B 110 ug/L 25 007 SW-8 Aqueous Chromium 6020B 8.1 ug/L 25 007 SW-8 Aqueous Cobalt 6020B 2.5 J ug/L 25 007 SW-8 Aqueous Copper 6020B 4.3 J ug/L 25 007 SW-8 Aqueous Lead 6020B 0.80 J ug/L 25 007 SW-8 Aqueous Nickel 6020B 7.3 ug/L 26 007 SW-8 Aqueous Vanadium 6020B 9.2 ug/L 26 007 SW-8 Aqueous Zinc 6020B 9.3 J ug/L 26 009 SW-6 Aqueous 1,4-Dioxane 8260D (SIM) 10 ug/L 29 009 SW-6 Aqueous Barium 6020B 110 ug/L 30 009 SW-6 Aqueous Chromium 6020B 3.8 J ug/L 30 009 SW-6 Aqueous Nickel 6020B 4.7 J ug/L 31 (58 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-001 Description: SW-1 Matrix: Aqueous Date Sampled:04/26/2021 1015 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/29/2021 2143 JDF 90730 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 93 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20211350 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-001 Description: SW-1 Matrix: Aqueous Date Sampled:04/26/2021 1015 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20211350 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 106 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 105 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2021 2351 BNW 04/29/2021 0948 90579 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 79 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-001 Description: SW-1 Matrix: Aqueous Date Sampled:04/26/2021 1015 Date Received:04/27/2021 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2021 2351 BNW 04/29/2021 0948 90579 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-002 Description: SW-2 Matrix: Aqueous Date Sampled:04/26/2021 1105 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/29/2021 2207 JDF 90730 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 93 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20211414 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-002 Description: SW-2 Matrix: Aqueous Date Sampled:04/26/2021 1105 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20211414 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 107 70-130 1,2-Dichloroethane-d4 100 70-130 Toluene-d8 108 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2021 2357 BNW 04/29/2021 0948 90579 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 57 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.5 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 1.7 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-002 Description: SW-2 Matrix: Aqueous Date Sampled:04/26/2021 1105 Date Received:04/27/2021 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2021 2357 BNW 04/29/2021 0948 90579 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-003 Description: SW-3 Matrix: Aqueous Date Sampled:04/26/2021 1205 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/29/2021 2232 JDF 90730 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 14 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 94 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20211438 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 4.1 J 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-003 Description: SW-3 Matrix: Aqueous Date Sampled:04/26/2021 1205 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20211438 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 106 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 108 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/30/2021 0040 BNW 04/29/2021 0948 90579 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 250 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 3.8 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 42 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 2.8 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.39 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 19 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-003 Description: SW-3 Matrix: Aqueous Date Sampled:04/26/2021 1205 Date Received:04/27/2021 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/30/2021 0040 BNW 04/29/2021 0948 90579 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 4.4 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 7.8 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-004 Description: SW-4 Matrix: Aqueous Date Sampled:04/26/2021 1310 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/29/2021 2257 JDF 90730 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 94 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20211502 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-004 Description: SW-4 Matrix: Aqueous Date Sampled:04/26/2021 1310 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20211502 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 107 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 107 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/30/2021 0046 BNW 04/29/2021 0948 90579 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 120 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 2.8 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 2.6 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 3.1 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.49 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 5.5 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 16 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-004 Description: SW-4 Matrix: Aqueous Date Sampled:04/26/2021 1310 Date Received:04/27/2021 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/30/2021 0046 BNW 04/29/2021 0948 90579 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 3.8 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 20 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 17 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-005 Description: SW-5 Matrix: Aqueous Date Sampled:04/26/2021 1240 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 5030B 8260D (SIM) 1 05/03/2021 1225 TML 90981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 6.1 3.0 1.0 ug/L 2 Run 2 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 89 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20211525 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 5.1 J 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 18 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-005 Description: SW-5 Matrix: Aqueous Date Sampled:04/26/2021 1240 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20211525 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 1.4 J 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 104 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 107 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/30/2021 0052 BNW 04/29/2021 0948 90579 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 110 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 8.6 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 12 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 2.2 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 19 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-005 Description: SW-5 Matrix: Aqueous Date Sampled:04/26/2021 1240 Date Received:04/27/2021 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/30/2021 0052 BNW 04/29/2021 0948 90579 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Nickel 7440-02-0 6020B 17 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 2.0 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 17 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 20 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-006 Description: SW-7 Matrix: Aqueous Date Sampled:04/26/2021 1125 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 3 5030B 8260D (SIM) 5 05/05/2021 2022 JDF 91318 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 7.2 J 15 5.0 ug/L 3 Run 3 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 101 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 5 05/06/20211700 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 35 J 100 25 ug/L 1 Acrylonitrile 107-13-1 8260D ND 100 4.0 ug/L 1 Benzene 71-43-2 8260D ND 5.0 2.0 ug/L 1 Bromochloromethane 74-97-5 8260D ND 5.0 2.0 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 5.0 2.0 ug/L 1 Bromoform 75-25-2 8260D ND 5.0 2.0 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 10 2.0 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 50 10 ug/L 1 Carbon disulfide 75-15-0 8260D ND 5.0 2.0 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 5.0 2.0 ug/L 1 Chlorobenzene 108-90-7 8260D ND 5.0 2.0 ug/L 1 Chloroethane 75-00-3 8260D ND 10 2.0 ug/L 1 Chloroform 67-66-3 8260D ND 5.0 2.0 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 5.0 2.5 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 5.0 2.0 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 5.0 2.0 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 5.0 2.0 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 5.0 2.0 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 10 2.5 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 5.0 2.0 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 5.0 2.0 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 5.0 2.0 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 5.0 2.0 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 5.0 2.0 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 5.0 2.0 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 5.0 2.0 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 5.0 2.0 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 5.0 2.0 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 5.0 2.0 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 21 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-006 Description: SW-7 Matrix: Aqueous Date Sampled:04/26/2021 1125 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 5 05/06/20211700 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 5.0 2.0 ug/L 1 2-Hexanone 591-78-6 8260D ND 50 10 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 25 2.0 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 50 10 ug/L 1 Methylene chloride 75-09-2 8260D ND 5.0 2.0 ug/L 1 Styrene 100-42-5 8260D ND 5.0 2.1 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 5.0 2.0 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 5.0 2.0 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 5.0 2.0 ug/L 1 Toluene 108-88-3 8260D ND 5.0 2.0 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 5.0 2.0 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 5.0 2.0 ug/L 1 Trichloroethene 79-01-6 8260D ND 5.0 2.0 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 5.0 2.0 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 5.0 2.0 ug/L 1 Vinyl acetate 108-05-4 8260D ND 25 5.8 ug/L 1 Vinyl chloride 75-01-4 8260D ND 5.0 2.0 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 5.0 2.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 105 70-130 1,2-Dichloroethane-d4 101 70-130 Toluene-d8 97 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 5 04/30/2021 0058 BNW 04/29/2021 0948 90579 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.9 J 10 2.5 ug/L 1 Arsenic 7440-38-2 6020B 21 10 6.3 ug/L 1 Barium 7440-39-3 6020B 300 25 6.3 ug/L 1 Beryllium 7440-41-7 6020B ND 2.0 0.75 ug/L 1 Cadmium 7440-43-9 6020B ND 2.5 0.63 ug/L 1 Chromium 7440-47-3 6020B 120 25 6.3 ug/L 1 Cobalt 7440-48-4 6020B 66 25 6.3 ug/L 1 Copper 7440-50-8 6020B 28 25 6.3 ug/L 1 Lead 7439-92-1 6020B 5.9 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B 110 25 6.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 22 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-006 Description: SW-7 Matrix: Aqueous Date Sampled:04/26/2021 1125 Date Received:04/27/2021 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 5 04/30/2021 0058 BNW 04/29/2021 0948 90579 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 25 6.3 ug/L 1 Silver 7440-22-4 6020B ND 5.0 1.3 ug/L 1 Thallium 7440-28-0 6020B ND 2.5 0.75 ug/L 1 Vanadium 7440-62-2 6020B 59 25 13 ug/L 1 Zinc 7440-66-6 6020B 110 50 13 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 23 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-007 Description: SW-8 Matrix: Aqueous Date Sampled:04/26/2021 1040 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/29/2021 2347 JDF 90730 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 1.8 J 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 94 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20211549 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 24 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-007 Description: SW-8 Matrix: Aqueous Date Sampled:04/26/2021 1040 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20211549 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 105 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 107 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/30/2021 0104 BNW 04/29/2021 0948 90579 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.6 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 110 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 8.1 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 2.5 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 4.3 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.80 J 1.0 0.25 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 25 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-007 Description: SW-8 Matrix: Aqueous Date Sampled:04/26/2021 1040 Date Received:04/27/2021 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/30/2021 0104 BNW 04/29/2021 0948 90579 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Nickel 7440-02-0 Selenium 7782-49-2 Silver 7440-22-4 Thallium 7440-28-0 Vanadium 7440-62-2 Zinc 7440-66-6 6020B 7.3 5.0 1.3 ug/L 1 6020B ND 5.0 1.3 ug/L 1 6020B ND 1.0 0.25 ug/L 1 6020B ND 0.50 0.15 ug/L 1 6020B 9.2 5.0 2.5 ug/L 1 6020B 9.3 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 26 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: WD28006-008 Description: Trip Blank Matrix: Aqueous Date Sampled:04/26/2021 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20211128 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 27 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: WD28006-008 Description: Trip Blank Matrix: Aqueous Date Sampled:04/26/2021 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20211128 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 100 70-130 104 70-130 108 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 28 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-009 Description: SW-6 Matrix: Aqueous Date Sampled:04/27/2021 1110 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/03/2021 1315 TML 90981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 10 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 91 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20211613 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 29 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-009 Description: SW-6 Matrix: Aqueous Date Sampled:04/27/2021 1110 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20211613 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 107 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 109 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2021 1408 BNW 04/30/2021 0355 90649 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 110 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 3.8 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 30 of 57 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28006-009 Description: SW-6 Matrix: Aqueous Date Sampled:04/27/2021 1110 Date Received:04/28/2021 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2021 1408 BNW 04/30/2021 0355 90649 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Nickel 7440-02-0 6020B 4.7 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 31 of 57 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 32 of 57 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: WQ90730-001 Matrix: Aqueous Batch: 90730 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 04/29/2021 1950 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 95 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 33 of 57 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: WQ90730-002 Matrix: Aqueous Batch: 90730 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 47 1 94 70-130 04/29/2021 1900 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 95 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 34 of 57 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: WQ90981-001 Matrix: Aqueous Batch: 90981 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 05/03/2021 1103 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 91 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 35 of 57 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: WQ90981-002 Matrix: Aqueous Batch: 90981 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 47 1 95 70-130 05/03/2021 1004 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 97 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 36 of 57 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: WQ91318-001 Matrix: Aqueous Batch: 91318 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 05/05/2021 1901 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 99 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 37 of 57 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: WQ91318-002 Matrix: Aqueous Batch: 91318 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 51 1 102 70-130 05/05/2021 1812 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 108 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 38 of 57 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91358-001 Matrix: Aqueous Batch: 91358 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 05/06/2021 0917 Acrylonitrile ND 1 20 0.80 ug/L 05/06/2021 0917 Benzene ND 1 1.0 0.40 ug/L 05/06/2021 0917 Bromochloromethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 Bromodichloromethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 Bromoform ND 1 1.0 0.40 ug/L 05/06/2021 0917 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 05/06/2021 0917 2-Butanone (MEK) ND 1 10 2.0 ug/L 05/06/2021 0917 Carbon disulfide ND 1 1.0 0.40 ug/L 05/06/2021 0917 Carbon tetrachloride ND 1 1.0 0.40 ug/L 05/06/2021 0917 Chlorobenzene ND 1 1.0 0.40 ug/L 05/06/2021 0917 Chloroethane ND 1 2.0 0.40 ug/L 05/06/2021 0917 Chloroform ND 1 1.0 0.40 ug/L 05/06/2021 0917 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 05/06/2021 0917 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 05/06/2021 0917 Dibromochloromethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 05/06/2021 0917 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 05/06/2021 0917 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 05/06/2021 0917 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 0917 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 0917 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 05/06/2021 0917 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/06/2021 0917 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/06/2021 0917 Ethylbenzene ND 1 1.0 0.40 ug/L 05/06/2021 0917 2-Hexanone ND 1 10 2.0 ug/L 05/06/2021 0917 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 05/06/2021 0917 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 05/06/2021 0917 Methylene chloride ND 1 1.0 0.40 ug/L 05/06/2021 0917 Styrene ND 1 1.0 0.41 ug/L 05/06/2021 0917 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 Tetrachloroethene ND 1 1.0 0.40 ug/L 05/06/2021 0917 Toluene ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 Trichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 0917 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 05/06/2021 0917 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 39 of 57 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91358-001 Matrix: Aqueous Batch: 91358 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 05/06/2021 0917 Vinyl chloride ND 1 1.0 0.40 ug/L 05/06/2021 0917 Xylenes (total) ND 1 1.0 0.40 ug/L 05/06/2021 0917 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 100 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 107 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 40 of 57 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91358-002 Matrix: Aqueous Batch: 91358 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 92 1 92 60-140 05/06/2021 0755 Acrylonitrile 100 98 1 98 70-130 05/06/2021 0755 Benzene 50 49 1 99 70-130 05/06/2021 0755 Bromochloromethane 50 50 1 101 70-130 05/06/2021 0755 Bromodichloromethane 50 50 1 99 70-130 05/06/2021 0755 Bromoform 50 52 1 104 70-130 05/06/2021 0755 Bromomethane (Methyl bromide) 50 52 1 105 70-130 05/06/2021 0755 2-Butanone (MEK) 100 100 1 103 70-130 05/06/2021 0755 Carbon disulfide 50 54 1 108 70-130 05/06/2021 0755 Carbon tetrachloride 50 51 1 101 70-130 05/06/2021 0755 Chlorobenzene 50 49 1 97 70-130 05/06/2021 0755 Chloroethane 50 53 1 105 70-130 05/06/2021 0755 Chloroform 50 49 1 98 70-130 05/06/2021 0755 Chloromethane (Methyl chloride) 50 48 1 96 60-140 05/06/2021 0755 1,2-Dibromo-3-chloropropane (DBCP) 50 50 1 100 70-130 05/06/2021 0755 Dibromochloromethane 50 51 1 102 70-130 05/06/2021 0755 1,2-Dibromoethane (EDB) 50 50 1 101 70-130 05/06/2021 0755 Dibromomethane (Methylene bromide) 50 50 1 99 70-130 05/06/2021 0755 trans- 1,4-Dichloro-2-butene 50 55 1 109 70-130 05/06/2021 0755 1,2-Dichlorobenzene 50 49 1 99 70-130 05/06/2021 0755 1,4-Dichlorobenzene 50 49 1 97 70-130 05/06/2021 0755 1,1-Dichloroethane 50 50 1 100 70-130 05/06/2021 0755 1,2-Dichloroethane 50 49 1 97 70-130 05/06/2021 0755 1,1-Dichloroethene 50 53 1 107 70-130 05/06/2021 0755 cis- 1,2-Dichloroethene 50 50 1 101 70-130 05/06/2021 0755 trans- 1,2-Dichloroethene 50 51 1 102 70-130 05/06/2021 0755 1,2-Dichloropropane 50 50 1 99 70-130 05/06/2021 0755 cis- 1,3-Dichloropropene 50 53 1 106 70-130 05/06/2021 0755 trans- 1,3-Dichloropropene 50 53 1 106 70-130 05/06/2021 0755 Ethylbenzene 50 52 1 104 70-130 05/06/2021 0755 2-Hexanone 100 110 1 107 70-130 05/06/2021 0755 Methyl iodide (lodomethane) 50 51 1 103 70-130 05/06/2021 0755 4-Methyl-2-pentanone 100 100 1 105 70-130 05/06/2021 0755 Methylene chloride 50 50 1 101 70-130 05/06/2021 0755 Styrene 50 54 1 108 70-130 05/06/2021 0755 1,1,1,2-Tetrachloroethane 50 49 1 98 70-130 05/06/2021 0755 1,1,2,2-Tetrachloroethane 50 48 1 96 70-130 05/06/2021 0755 Tetrachloroethene 50 50 1 101 70-130 05/06/2021 0755 Toluene 50 51 1 102 70-130 05/06/2021 0755 1,1,1-Trichloroethane 50 50 1 100 70-130 05/06/2021 0755 1,1,2-Trichloroethane 50 49 1 98 70-130 05/06/2021 0755 Trichloroethene 50 49 1 98 70-130 05/06/2021 0755 Trichlorofluoromethane 50 52 1 104 70-130 05/06/2021 0755 1,2,3-Trichloropropane 50 49 1 98 70-130 05/06/2021 0755 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 41 of 57 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91358-002 Matrix: Aqueous Batch: 91358 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 49 1 98 60-140 05/06/2021 0755 Vinyl chloride 50 52 1 103 70-130 05/06/2021 0755 Xylenes (total) 100 110 1 106 70-130 05/06/2021 0755 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 104 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 103 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 42 of 57 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91358-001 Matrix: Aqueous Batch: 91358 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 05/06/2021 0917 Acrylonitrile ND 1 20 0.80 ug/L 05/06/2021 0917 Benzene ND 1 1.0 0.40 ug/L 05/06/2021 0917 Bromochloromethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 Bromodichloromethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 Bromoform ND 1 1.0 0.40 ug/L 05/06/2021 0917 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 05/06/2021 0917 2-Butanone (MEK) ND 1 10 2.0 ug/L 05/06/2021 0917 Carbon disulfide ND 1 1.0 0.40 ug/L 05/06/2021 0917 Carbon tetrachloride ND 1 1.0 0.40 ug/L 05/06/2021 0917 Chlorobenzene ND 1 1.0 0.40 ug/L 05/06/2021 0917 Chloroethane ND 1 2.0 0.40 ug/L 05/06/2021 0917 Chloroform ND 1 1.0 0.40 ug/L 05/06/2021 0917 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 05/06/2021 0917 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 05/06/2021 0917 Dibromochloromethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 05/06/2021 0917 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 05/06/2021 0917 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 05/06/2021 0917 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 0917 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 0917 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 05/06/2021 0917 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/06/2021 0917 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/06/2021 0917 Ethylbenzene ND 1 1.0 0.40 ug/L 05/06/2021 0917 2-Hexanone ND 1 10 2.0 ug/L 05/06/2021 0917 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 05/06/2021 0917 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 05/06/2021 0917 Methylene chloride ND 1 1.0 0.40 ug/L 05/06/2021 0917 Styrene ND 1 1.0 0.41 ug/L 05/06/2021 0917 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 Tetrachloroethene ND 1 1.0 0.40 ug/L 05/06/2021 0917 Tetrahydrofuran ND 1 5.0 1.0 ug/L 05/06/2021 0917 Toluene ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 Trichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 0917 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 43 of 57 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91358-001 Matrix: Aqueous Batch: 91358 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 05/06/2021 0917 Vinyl acetate ND 1 5.0 1.2 ug/L 05/06/2021 0917 Vinyl chloride ND 1 1.0 0.40 ug/L 05/06/2021 0917 Xylenes (total) ND 1 1.0 0.40 ug/L 05/06/2021 0917 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 100 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 107 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 44 of 57 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91358-002 Matrix: Aqueous Batch: 91358 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 92 1 92 60-140 05/06/2021 0755 Acrylonitrile 100 98 1 98 70-130 05/06/2021 0755 Benzene 50 49 1 99 70-130 05/06/2021 0755 Bromochloromethane 50 50 1 101 70-130 05/06/2021 0755 Bromodichloromethane 50 50 1 99 70-130 05/06/2021 0755 Bromoform 50 52 1 104 70-130 05/06/2021 0755 Bromomethane (Methyl bromide) 50 52 1 105 70-130 05/06/2021 0755 2-Butanone (MEK) 100 100 1 103 70-130 05/06/2021 0755 Carbon disulfide 50 54 1 108 70-130 05/06/2021 0755 Carbon tetrachloride 50 51 1 101 70-130 05/06/2021 0755 Chlorobenzene 50 49 1 97 70-130 05/06/2021 0755 Chloroethane 50 53 1 105 70-130 05/06/2021 0755 Chloroform 50 49 1 98 70-130 05/06/2021 0755 Chloromethane (Methyl chloride) 50 48 1 96 60-140 05/06/2021 0755 1,2-Dibromo-3-chloropropane (DBCP) 50 50 1 100 70-130 05/06/2021 0755 Dibromochloromethane 50 51 1 102 70-130 05/06/2021 0755 1,2-Dibromoethane (EDB) 50 50 1 101 70-130 05/06/2021 0755 Dibromomethane (Methylene bromide) 50 50 1 99 70-130 05/06/2021 0755 trans- 1,4-Dichloro-2-butene 50 55 1 109 70-130 05/06/2021 0755 1,2-Dichlorobenzene 50 49 1 99 70-130 05/06/2021 0755 1,4-Dichlorobenzene 50 49 1 97 70-130 05/06/2021 0755 1,1-Dichloroethane 50 50 1 100 70-130 05/06/2021 0755 1,2-Dichloroethane 50 49 1 97 70-130 05/06/2021 0755 1,1-Dichloroethene 50 53 1 107 70-130 05/06/2021 0755 cis- 1,2-Dichloroethene 50 50 1 101 70-130 05/06/2021 0755 trans- 1,2-Dichloroethene 50 51 1 102 70-130 05/06/2021 0755 1,2-Dichloropropane 50 50 1 99 70-130 05/06/2021 0755 cis- 1,3-Dichloropropene 50 53 1 106 70-130 05/06/2021 0755 trans- 1,3-Dichloropropene 50 53 1 106 70-130 05/06/2021 0755 Ethylbenzene 50 52 1 104 70-130 05/06/2021 0755 2-Hexanone 100 110 1 107 70-130 05/06/2021 0755 Methyl iodide (lodomethane) 50 51 1 103 70-130 05/06/2021 0755 4-Methyl-2-pentanone 100 100 1 105 70-130 05/06/2021 0755 Methylene chloride 50 50 1 101 70-130 05/06/2021 0755 Styrene 50 54 1 108 70-130 05/06/2021 0755 1,1,1,2-Tetrachloroethane 50 49 1 98 70-130 05/06/2021 0755 1,1,2,2-Tetrachloroethane 50 48 1 96 70-130 05/06/2021 0755 Tetrachloroethene 50 50 1 101 70-130 05/06/2021 0755 Tetrahydrofuran 50 50 1 100 70-130 05/06/2021 0755 Toluene 50 51 1 102 70-130 05/06/2021 0755 1,1,1-Trichloroethane 50 50 1 100 70-130 05/06/2021 0755 1,1,2-Trichloroethane 50 49 1 98 70-130 05/06/2021 0755 Trichloroethene 50 49 1 98 70-130 05/06/2021 0755 Trichlorofluoromethane 50 52 1 104 70-130 05/06/2021 0755 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 45 of 57 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91358-002 Matrix: Aqueous Batch: 91358 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,2,3-Trichloropropane 50 49 1 98 70-130 05/06/2021 0755 Vinyl acetate 50 49 1 98 60-140 05/06/2021 0755 Vinyl chloride 50 52 1 103 70-130 05/06/2021 0755 Xylenes (total) 100 110 1 106 70-130 05/06/2021 0755 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 104 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 103 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 46 of 57 ICP-MS Metals - MB Sample ID: WQ90579-001 Matrix: Aqueous Batch: 90579 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/29/2021 0948 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 04/29/2021 2245 Arsenic ND 1 2.0 1.3 ug/L 04/29/2021 2245 Barium ND 1 5.0 1.3 ug/L 04/29/2021 2245 Beryllium ND 1 0.40 0.15 ug/L 04/29/2021 2245 Cadmium ND 1 0.50 0.13 ug/L 04/29/2021 2245 Chromium ND 1 5.0 1.3 ug/L 04/29/2021 2245 Cobalt ND 1 5.0 1.3 ug/L 04/29/2021 2245 Copper ND 1 5.0 1.3 ug/L 04/29/2021 2245 Lead ND 1 1.0 0.25 ug/L 04/29/2021 2245 Nickel ND 1 5.0 1.3 ug/L 04/29/2021 2245 Selenium ND 1 5.0 1.3 ug/L 04/29/2021 2245 Silver ND 1 1.0 0.25 ug/L 04/29/2021 2245 Thallium ND 1 0.50 0.15 ug/L 04/29/2021 2245 Vanadium ND 1 5.0 2.5 ug/L 04/29/2021 2245 Zinc ND 1 10 2.5 ug/L 04/29/2021 2245 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 47 of 57 ICP-MS Metals - LCS Sample ID: WQ90579-002 Matrix: Aqueous Batch: 90579 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/29/2021 0948 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 100 1 103 80-120 04/29/2021 2303 Arsenic 100 110 1 105 80-120 04/29/2021 2303 Barium 100 100 1 103 80-120 04/29/2021 2303 Beryllium 100 110 1 109 80-120 04/29/2021 2303 Cadmium 100 100 1 102 80-120 04/29/2021 2303 Chromium 100 100 1 103 80-120 04/29/2021 2303 Cobalt 100 100 1 103 80-120 04/29/2021 2303 Copper 100 100 1 103 80-120 04/29/2021 2303 Lead 100 96 1 96 80-120 04/29/2021 2303 Nickel 100 100 1 103 80-120 04/29/2021 2303 Selenium 100 100 1 103 80-120 04/29/2021 2303 Silver 100 100 1 101 80-120 04/29/2021 2303 Thallium 100 97 1 97 80-120 04/29/2021 2303 Vanadium 100 100 1 103 80-120 04/29/2021 2303 Zinc 100 99 1 99 80-120 04/29/2021 2303 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 48 of 57 ICP-MS Metals - MS Sample ID: WD28006-002MS Matrix: Aqueous Batch: 90579 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/29/2021 0948 Sample Spike Amount Amount Result %Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony ND 100 110 1 105 75-125 04/30/2021 0015 Arsenic ND 100 110 1 106 75-125 04/30/2021 0015 Barium 57 100 160 1 104 75-125 04/30/2021 0015 Beryllium ND 100 110 1 111 75-125 04/30/2021 0015 Cadmium ND 100 99 1 99 75-125 04/30/2021 0015 Chromium 1.5 100 100 1 101 75-125 04/30/2021 0015 Cobalt ND 100 100 1 101 75-125 04/30/2021 0015 Copper ND 100 100 1 104 75-125 04/30/2021 0015 Lead ND 100 97 1 97 75-125 04/30/2021 0015 Nickel 1.7 100 100 1 100 75-125 04/30/2021 0015 Selenium ND 100 100 1 103 75-125 04/30/2021 0015 Silver ND 100 99 1 99 75-125 04/30/2021 0015 Thallium ND 100 99 1 99 75-125 04/30/2021 0015 Vanadium ND 100 100 1 104 75-125 04/30/2021 0015 Zinc ND 100 100 1 102 75-125 04/30/2021 0015 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 49 of 57 ICP-MS Metals - MSD Sample ID: WD28006-002MD Matrix: Aqueous Batch: 90579 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/29/2021 0948 Sample Spike Amount Amount Result %Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Antimony ND 100 100 1 104 1.3 75-125 20 04/30/2021 0021 Arsenic ND 100 100 1 104 1.6 75-125 20 04/30/2021 0021 Barium 57 100 160 1 103 0.75 75-125 20 04/30/2021 0021 Beryllium ND 100 110 1 113 1.4 75-125 20 04/30/2021 0021 Cadmium ND 100 97 1 97 2.8 75-125 20 04/30/2021 0021 Chromium 1.5 100 100 1 99 2.5 75-125 20 04/30/2021 0021 Cobalt ND 100 100 1 100 0.56 75-125 20 04/30/2021 0021 Copper ND 100 100 1 102 1.8 75-125 20 04/30/2021 0021 Lead ND 100 97 1 97 0.78 75-125 20 04/30/2021 0021 Nickel 1.7 100 100 1 101 0.49 75-125 20 04/30/2021 0021 Selenium ND 100 100 1 101 1.8 75-125 20 04/30/2021 0021 Silver ND 100 98 1 98 0.76 75-125 20 04/30/2021 0021 Thallium ND 100 99 1 99 0.14 75-125 20 04/30/2021 0021 Vanadium ND 100 100 1 101 3.4 75-125 20 04/30/2021 0021 Zinc ND 100 100 1 100 1.7 75-125 20 04/30/2021 0021 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 50 of 57 ICP-MS Metals - MB Sample ID: WQ90649-001 Matrix: Aqueous Batch: 90649 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/30/2021 0355 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 05/03/2021 1402 Arsenic ND 1 2.0 1.3 ug/L 05/03/2021 1402 Barium ND 1 5.0 1.3 ug/L 05/03/2021 1402 Beryllium ND 1 0.40 0.15 ug/L 05/03/2021 1402 Cadmium ND 1 0.50 0.13 ug/L 05/03/2021 1402 Chromium ND 1 5.0 1.3 ug/L 05/03/2021 1402 Cobalt ND 1 5.0 1.3 ug/L 05/03/2021 1402 Copper ND 1 5.0 1.3 ug/L 05/03/2021 1402 Lead ND 1 1.0 0.25 ug/L 05/03/2021 1402 Nickel ND 1 5.0 1.3 ug/L 05/03/2021 1402 Selenium ND 1 5.0 1.3 ug/L 05/03/2021 1402 Silver ND 1 1.0 0.25 ug/L 05/03/2021 1402 Thallium ND 1 0.50 0.15 ug/L 05/03/2021 1402 Vanadium ND 1 5.0 2.5 ug/L 05/03/2021 1402 Zinc ND 1 10 2.5 ug/L 05/03/2021 1402 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 51 of 57 ICP-MS Metals - LCS Sample ID: WQ90649-002 Matrix: Aqueous Batch: 90649 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/30/2021 0355 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 100 1 104 80-120 05/03/2021 1356 Arsenic 100 99 1 99 80-120 05/03/2021 1356 Barium 100 100 1 103 80-120 05/03/2021 1356 Beryllium 100 110 1 112 80-120 05/03/2021 1356 Cadmium 100 95 1 95 80-120 05/03/2021 1356 Chromium 100 100 1 100 80-120 05/03/2021 1356 Cobalt 100 99 1 99 80-120 05/03/2021 1356 Copper 100 100 1 101 80-120 05/03/2021 1356 Lead 100 110 1 107 80-120 05/03/2021 1356 Nickel 100 100 1 100 80-120 05/03/2021 1356 Selenium 100 89 1 89 80-120 05/03/2021 1356 Silver 100 110 1 106 80-120 05/03/2021 1356 Thallium 100 100 1 105 80-120 05/03/2021 1356 Vanadium 100 98 1 98 80-120 05/03/2021 1356 Zinc 100 94 1 94 80-120 05/03/2021 1356 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 52 of 57 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 53 of 57 �0 <" m D ;v v CD C 0 0 C m v� o m N �r m n 0 ° c CD a— �CD n d �M V <, N 0 7 W N o� v coU) CD V O W �6 O N m w 0 E3 . r ceAf aP t'fCal RACE A YT'I CAL S ERVIGES; LLC..... 1 GA Varaacie Floiitt Dive - 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HM;Lw—vi PACE ANALYTICAL SERVICES, LLC 5arnpias RaeeiRt CFretWlst�SRC) (mEllr)agC-I3} APvisF-,:9%23f2D20 A h^a1 Issulrle At1hol Pace ENV - WCCIL Page 1 0l 1 Sample Receipt Checklist (SRC CI 131,ii _ ConlerInspected 13vJjqt!3- EH J O-Q2M(21 w[738uc Lot*: P5: receipt. ,r P.c� CJit ;;1'8 FedEhfn ], 'r custtrrly.smIs 'r�crit uet�le Na J NA'If ct.stn '"als "t'¢rc rrsenl', WCU ale •-ntltor and unhrDken? 2ariI2 C'illorine S[�p ILI, w'TcRlcrl bY: aaL[�erttpe Wilre ni50.15 rarielPt 1 Dc-wed (Cr,,rmc.ted) [empCradlrc ujpn re�ceipl.°J65r}leri 5J>$p up Il]•; aC. NA jir-lA, QC+ IN }HA !A o r f ' U i4tetllod: cJll rafvrn i3laltic E i i nst Btles ot1FC OU' n IF), I& Guts Colreclirin Factor_ 0 `+C Mc;lu of coolant- w,rt Iva ❑ Icr Packs ❑ Dry ice None ' ❑ Yes L7 No ,/ � IfMlipnro-3'iir-3 -of $ny cooler exceeded 6,llwas Project MarlagCrTlodAcd? ❑ N.'4 P`V teas N tiliFied by. phaae f email I ta�tv4r re (cird a one), jLj q❑ * I.4 Is do6J111nert tAl kO1JNtir'a PHrtkiu slip aCtiO}led to [hip form J YEU Tro 5_ ['rnre forup cus[ndy ProcedarCs (reltnGll slled'rea�-i�'c7d fo[lowa& v Vies ND _ G. Were !m le IDa !rated m the -C-Ol D Yes ❑ Vo 7. Wen arul:ple Ms Iisx,! on rJl sadliplc con [ainors.? . yes NO 9. Was; w lectnan datq &, tirnG listed cn the MC? Ll Yes -+Ia 4, w., collectioil cJ:dlls,# time Iistad oieJill saunpitmjaircrs? Yes No 10. Did r,l- ronta-rt�r label inform.Lvior. (ID, dalr, ffine) agl witli [fir CSC? yeJs No 1 ] . Were tests to be Cotmcd J i ed Dart, tF a COC? Yes [� t la I . Did all samples aniW- ill i lire prlpEt containarx f(w oach tt s; and{a- i n goo[! ixarr['.I#:Ori (unkbmllx;l on, ctc_p Yes Na 13. Was adcquate SArrlple voGamr: availabtc? l iI Yes L1 N'o 14. Were ail sarl nc6iwd witJliIt Vt the liolr I time: or 48 hou16,10 Ui ver comes first? Yam, Tip 15, W" arty sale -e eon iners nus5ingfcxcess (Girale oils) samples Not Iislud one -Coe? 0 Yrs ONl ❑NA l6, f'r,r Y au�1 ]Sic-1?5 salrplcs, we a b[lbbles prLsent=>°{pea-si ee" (r:"or�rmm in diameter} In any o�`the VOA Vim? J YeK NU NA 17. Weil ad I l7RQ}rletaJ� nr�Frient aaa,ples re;oei k'ed at Yes h10 'A IS, Were all cyanic sanrpins recei%,Ud UL a PH > 12 and Sulfide garnt�,ntples 2st pH> 99 Ycr ❑Teo ONA Wgre �!: applicahlo 2VFl�rT;��.cyarri }risena 625.I}G 3U8 (<0.5me if ❑ Yes ❑lye Qtyq }. Were aheig fcmffk3frerytlBSts {i.c. ragnesled dilu'ions, 1++1;�%ISD d lignatiops, etc_ correctly transtribcd From the CDC' in€a I eolslm��G section in LIMS? yeS Nr, 21. Fins tlse quote nurll listed 4n Zite C nEain er ]a be]" if x•CS (7unec .� Ample P"ftlIV8'ipn {liltlfi` L c�nlplcEed for Wiry ;ample s) incc.al,ecll}' pr st~rvpd m' itfr hcadspac .j altipJr(s VA. ti4Cru received incorfectl rascrved wit] were �dj%3Md auw dl:rg;y lsa,ripiC receivitiZwith rElL ofctrcrlu>•e Jc: Ha y p 0�#, Hi`'1C13, HC I, idaO�T using SF~< ff NA isle ofPMenStion NA If'urclrq; lltarl One pre9en'ative is Weeder!, PJease note of the c matt ils below, mple(s) +� were received ViAb bubbles >6 haulm rin dia, np1:3(s) ~_ were rewiued with 'TRC = 0.5 in JL [If I �} is n j and wcec �4lcd accordingly in salrplt: rccelvdtg wit sa.dil Ih OW1fttlr. ("a�S2Q,) will, Shealy ID-z NA h—+1e labels applivd by: JRG2 !]ate; oW!' + 121 COmrller.rs_ Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 55 of 57 �0 CD CD ;v :v C ro 0 °� rn m v� o m N r N 0 ° 3CD �U) n d �m V <, N 0 7 W N O = co fn t CD CDR V 0 CD N b -n w v Vo x v o a w O v tA M O ro 0 E3 FACE ANALTMAL SERVICES, LLC c3ceAn is f 106 YamTc Reim Dlivc • West C:alumbia, SG 29V2 NL M bGr 119889 Telephone No_ 803-791-9700 Fax No. W3.791-9111 wtivvr,pacaisbs.com brL] i mia! Tr jJukr fL4x if-rri?a Gmh-N^_ 4 Adae s S 16 % '�Lr&' Amiyek(AYechAs[Iowrie p Gt?a sneadsoj +}iaocr 3 k / ! 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Jr}r� U Man-HmW F.l flammable 1 Shln hri= m PmLmn r_l uFfknurm ?_.�i55ce�'na�b� �a� ixre air br DIR!I Tne a Ascerfflffbr i1a!e 'I me fARdrPrAJIY _� i f Twrjr4Cuik Arc oer�m�aP na�an.�f.x�arx�c � PACE ANALYTICAL SERVICES, LLC Samples Rer:eipt Cheeklist (SRC} (ME00'18C-1's) �Ar l t�ea1' Is.suingAuthority; Face ENV-'NCOL .Umpje ReVejpt C bee klist 1( Q ClirAll: HLE Cool•-r lrmpK tcd by,'datc- J r2 CA12W . I Ln[ # W3ML'06 ReViSed;LI 291202D P2ge I of 1 hlcOns aftrixCipt- 0Psce Dclient L r'S { FedEx O Jier -- .Fjy(wl,! N❑ 1-Vde�eCufi<{ril sEs :resenlonC:iccurrt�r7 F]'Yesl LLNcj2LtjA ?. if cusrady sewls �yprt' present, were t1�ey itrracT and mrror�,&w,t? -'pH Strip ID: � ��� - _ C1110.1i l B+j:IrID: NA Tasted by:rnG-x _ ---- ir]&iill t1"InpC�-Tat-H'X Upon MCeipt f bCdVl`d (001ECClted) lei 1pocaturc u13e3:1 e yip; '/D3Q.id SWIP-CUP ID: NA 4-7 14.7 eC NA I NA :C NA r NP: or h'A ; NA oC MethcrI- DTemferaWrr, kiLank Okpinst Bo-tlus I Uun ID- ICE Can Correction F'Pxuu.-. ° °C McAh0c[ 4)rOL'01 I; a Wc: Ice © 'ce Packs ❑ Dry Ice None n - ❑Yes ❑ No NA ' If tertlperature of any cooler excel 5:0`C, was project Mantq,cr Na#ifigd'2 PM Was Noti8cd by: phi no f enrai If face to ace {circle one}- Ya, N❑ NA 4. Is tFc Mnnlercial nuurirr's parking slip attachod to Ellis fom]F ,r Yes No P. WL-re proper custody -ondures (reliiiqui h-Oreccived) fullunt,'cd? J alas N u ti_ i viw sum plc 11Jf I istcd on the WC? I Yea No 7. Were 5ampic Il)s listcd on al1 sample containers? I Q Yea; N ❑ S. Wan wll�,.ii on dam &. tim a Ji.5tad on the CDC' Y N , 9. Wns 0011v Lion date & time Jist-d an all sam�Ie oorttai-IMi? ,� yC5 ❑ No 10. Did all container label informa[ian (ID, daw. Lune;) egrtm wilb the COC? 11. VVrM tests to tre pertbrr_ted listed on the DOS'? GS N ry Ely. L ❑ N u 12. Did ail sampl as arrive In the rire'pler contaiMrs for each mat aiWor in good ualditi0r3 (imbrukxi, lids on. ctc.)'x ED 'ec- Nr, 13- Waitadequabes�rttplevol irri Nvailabin? L7' V' -s No 14- Were all 9arl:Plgs roocivW within'. tho halding time or 49 hours, whichever comes first? ❑ YCS r Yes } u +L No 15, 'N-cm any sam k% cOntainers miss:r Skxeess i:ircls one FYr Snples Not ,listed on b- For VOA goad RSK-175 samples, were bubbles presert >"pr4-si7." ('W'Or b7l:n in di�tnletel•', ir1 any of tfan VOA vial ❑ Noi ❑NA 777 yul L1 No LJNA 17. Wcre all DRUB nemis?nutrient sam fe; I'ecelvcd at A pH of ¢ V Lj Yes: iNa N A l 8. Wel`C al l can ide mlr, 6s stt a pH ? 12 and s-jlflde samples reCe iti ce a[ a r)A > 4" f Yes I❑ M0 ONA l - Were appllcahle N143+TKN,'tymnitWpFr.noV62 l,'G48.J (<0.5ineprL) sairrpres free of 11-6�iOurtl' CFjQrirlc? Yes ❑Nr1 QNA 20. WereeJicr.trcrnarks'rcgva3ts (i.e. requested dilutiom. MVh>w designations, ex—) curroctl�r transcribt:d from tE=e C:Ut.:rrta lire cr3mment seGtlOn ir. L[i�rl�7 M Yed Ll No 171. Was the Lquare number lisie.:i on the-0001.aiTker I8W' " ?; 3TS Q1.10te f 2'3U amp1c YreservaJun (Musr be completed tiorany samiple(-) imi)rreetfv preni'vo'd or WLth :Icad5paG0.) 'arnple(S) "A wim received incorrectly pro3crvcd and were adjusted accordingly insampleraceiwing)-4i'1h Nn mLofcireLeante: 142SD4,14NO3,14CI,NaOHusingSRN T'A 1'irnoOfPrc lvation NA _ IfJtr0re ILai i uuGprGsxrviAivtf i4 rre j4wj� pJtru:c ryu in Lbommnents below. ample } NA were reecived with bubbIcs--Gmm in diameter. Samples(s) NA wum r=dvad with' IUCs > 4.5 Tn&OL (If .Y 19 is no) and WOO adjusted = orcingly in sample rm6ving with sodiLini thiasulfate �NaxS203) wills IL3hpaLy ID, twn 4R barcade iabetsa{xplied hy: iK6'2 r1dIC; 04f2R12021 Cnm[nenLs: Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 57 of 57 0 aceAnalytical Report of Analysis Bunnell-Lammons Engineering, Inc. 6004 Ponders Court Greenville, SC 29615 Attention: Andy Alexander Project Name: Active Buncombe County Landfill Leak Detectors Project Number: J21-9378-23 Lot Number:WD28012 Date Completed:05/07/2021 N N NO � � J 05/11 /2021 3:22 PM Approved and released by: Project Manager II: Lucas Odom PCCRF� 24rA SOA / ANSI National Accreditation Board A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 35 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Bunnell-Lammons Engineering, Inc. Lot Number: WD28012 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 whw.pacelabs.com Page 2 of 35 PACE ANALYTICAL SERVICES, LLC Sample Summary Bunnell-Lammons Engineering, Inc. Lot Number: WD28012 Sample Number Sample ID Matrix Date Sampled Date Received 001 LD-1 Aqueous 04/26/20211530 04/28/2021 002 LD-2 Aqueous 04/26/20211515 04/28/2021 003 LD-3 Aqueous 04/26/20211610 04/28/2021 004 LD-4 Aqueous 04/26/20211630 04/28/2021 005 LD-5 Aqueous 04/26/20211410 04/28/2021 006 LD-6 Aqueous 04/26/20211645 04/28/2021 007 Leachate LID Aqueous 04/26/2021 1455 04/28/2021 (7 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 35 PACE ANALYTICAL SERVICES, LLC Detection Summary Bunnell-Lammons Engineering, Inc. Lot Number: WD28012 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 LD-1 Aqueous Benzene 8260D 1.8 ug/L 6 001 LD-1 Aqueous 2-Butanone (MEK) 8260D 14 ug/L 6 001 LID-1 Aqueous Chlorobenzene 8260D 0.53 J ug/L 6 001 LD-1 Aqueous Chloroethane 8260D 0.59 J ug/L 6 001 LD-1 Aqueous 1,4-Dichlorobenzene 8260D 1.1 ug/L 6 001 LD-1 Aqueous 1,1-Dichloroethane 8260D 0.85 J ug/L 6 001 LID-1 Aqueous cis- 1,2-Dichloroethene 8260D 0.63 J ug/L 6 001 LD-1 Aqueous Barium 6020B 830 ug/L 7 001 LD-1 Aqueous Beryllium 6020B 0.30 J ug/L 7 001 LD-1 Aqueous Chromium 6020B 1.3 J ug/L 7 001 LD-1 Aqueous Cobalt 6020B 360 ug/L 7 001 LID-1 Aqueous Nickel 6020B 53 ug/L 7 001 LD-1 Aqueous Selenium 6020B 3.0 J ug/L 7 001 LD-1 Aqueous Thallium 6020B 0.22 J ug/L 7 001 LD-1 Aqueous Vanadium 6020B 3.5 J ug/L 7 001 LD-1 Aqueous Zinc 6020B 6.4 J ug/L 7 002 LD-2 Aqueous 1,1-Dichloroethane 8260D 1.2 ug/L 8 002 LD-2 Aqueous Barium 6020B 260 ug/L 9 002 LD-2 Aqueous Beryllium 6020B 0.23 J ug/L 9 002 LD-2 Aqueous Chromium 6020B 19 ug/L 9 002 LD-2 Aqueous Cobalt 6020B 76 ug/L 9 002 LD-2 Aqueous Copper 6020B 10 ug/L 9 002 LD-2 Aqueous Lead 6020B 1.8 ug/L 9 002 LD-2 Aqueous Nickel 6020B 28 ug/L 9 002 LD-2 Aqueous Vanadium 6020B 20 ug/L 9 002 LD-2 Aqueous Zinc 6020B 33 ug/L 9 003 LD-3 Aqueous 1,4-Dichlorobenzene 8260D 0.58 J ug/L 10 003 LD-3 Aqueous Barium 6020B 240 ug/L 11 003 LD-3 Aqueous Chromium 6020B 1.4 J ug/L 11 003 LD-3 Aqueous Cobalt 6020B 4.1 J ug/L 11 003 LD-3 Aqueous Copper 6020B 9.0 ug/L 11 003 LD-3 Aqueous Lead 6020B 0.43 J ug/L 11 003 LD-3 Aqueous Nickel 6020B 3.6 J ug/L 11 003 LD-3 Aqueous Zinc 6020B 5.0 J ug/L 11 004 LD-4 Aqueous Acetone 8260D 5.1 J ug/L 12 004 LD-4 Aqueous Benzene 8260D 1.8 ug/L 12 004 LD-4 Aqueous 1,1-Dichloroethane 8260D 0.53 J ug/L 12 004 LD-4 Aqueous Toluene 8260D 0.55 J ug/L 12 004 LD-4 Aqueous Vinyl chloride 8260D 1.2 ug/L 13 004 LD-4 Aqueous Xylenes (total) 8260D 0.40 J ug/L 13 004 LD-4 Aqueous Antimony 6020B 1.1 J ug/L 13 004 LD-4 Aqueous Arsenic 6020B 4.4 ug/L 13 004 LD-4 Aqueous Barium 6020B 470 ug/L 13 004 LD-4 Aqueous Chromium 6020B 270 ug/L 13 004 LD-4 Aqueous Cobalt 6020B 15 ug/L 13 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 35 Detection Summary (Continued) Lot Number: WD28012 Sample Sample ID Matrix Parameter Method Result Q Units Page 004 LD-4 Aqueous Copper 6020B 21 ug/L 13 004 LD-4 Aqueous Nickel 6020B 100 ug/L 13 004 LD-4 Aqueous Selenium 6020B 4.5 J ug/L 13 004 LD-4 Aqueous Vanadium 6020B 11 ug/L 13 004 LD-4 Aqueous Zinc 6020B 8.1 J ug/L 13 005 LD-5 Aqueous Barium 6020B 97 ug/L 15 005 LD-5 Aqueous Cobalt 6020B 50 ug/L 15 005 LD-5 Aqueous Nickel 6020B 16 ug/L 15 005 LD-5 Aqueous Zinc 6020B 2.8 J ug/L 15 006 LD-6 Aqueous Barium 6020B 410 ug/L 17 006 LD-6 Aqueous Cobalt 6020B 75 ug/L 17 006 LD-6 Aqueous Nickel 6020B 3.8 J ug/L 17 006 LD-6 Aqueous Zinc 6020B 10 ug/L 17 007 Leachate LID Aqueous Barium 6020B 28 ug/L 19 007 Leachate LID Aqueous Beryllium 6020B 0.66 ug/L 19 007 Leachate LID Aqueous Cadmium 6020B 0.28 J ug/L 19 007 Leachate LID Aqueous Cobalt 6020B 52 ug/L 19 007 Leachate LID Aqueous Copper 6020B 14 ug/L 19 007 Leachate LID Aqueous Nickel 6020B 440 ug/L 19 007 Leachate LID Aqueous Selenium 6020B 2.8 J ug/L 19 007 Leachate LID Aqueous Zinc 6020B 200 ug/L 19 (66 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 35 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28012-001 Description: LD-1 Matrix: Aqueous Date Sampled:04/26/2021 1530 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20211636 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D 1.8 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D 14 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D 0.53 J 1.0 0.40 ug/L Chloroethane 75-00-3 8260D 0.59 J 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D 1.1 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D 0.85 J 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis-1,2-Dichloroethene 156-59-2 8260D 0.63 J 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 35 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28012-001 Description: LD-1 Matrix: Aqueous Date Sampled:04/26/2021 1530 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20211636 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 105 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 107 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2021 2020 BNW 04/29/2021 0948 90580 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 830 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.30 J 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.3 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 360 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 53 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 3.0 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.22 J 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 3.5 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 6.4 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 35 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28012-002 Description: LD-2 Matrix: Aqueous Date Sampled:04/26/2021 1515 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20212358 CJL2 91468 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D 1.2 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 35 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28012-002 Description: LD-2 Matrix: Aqueous Date Sampled:04/26/2021 1515 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20212358 CJL2 91468 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 104 70-130 1,2-Dichloroethane-d4 102 70-130 Toluene-d8 108 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2021 2039 BNW 04/29/2021 0948 90580 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 260 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.23 J 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 19 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 76 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 10 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.8 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 28 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 20 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 33 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 35 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28012-003 Description: LD-3 Matrix: Aqueous Date Sampled:04/26/2021 1610 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20210022 CJL2 91468 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D 0.58 J 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 35 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28012-003 Description: LD-3 Matrix: Aqueous Date Sampled:04/26/2021 1610 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20210022 CJL2 91468 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 103 70-130 1,2-Dichloroethane-d4 103 70-130 Toluene-d8 107 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2021 2109 BNW 04/29/2021 0948 90580 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 240 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.4 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 4.1 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 9.0 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.43 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 3.6 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 5.0 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 35 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28012-004 Description: LD-4 Matrix: Aqueous Date Sampled:04/26/2021 1630 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20210046 CJL2 91468 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 5.1 J 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D 1.8 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D 0.53 J 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D 0.55 J 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 35 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28012-004 Description: LD-4 Matrix: Aqueous Date Sampled:04/26/2021 1630 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20210046 CJL2 91468 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 1.2 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 0.40 J 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 103 70-130 1,2-Dichloroethane-d4 102 70-130 Toluene-d8 109 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2021 2115 BNW 04/29/2021 0948 90580 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 1.1 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 4.4 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 470 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 270 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 15 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 21 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 100 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 4.5 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 11 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 8.1 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 35 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28012-005 Description: LD-5 Matrix: Aqueous Date Sampled:04/26/2021 1410 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20210109 CJL2 91468 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 35 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28012-005 Description: LD-5 Matrix: Aqueous Date Sampled:04/26/2021 1410 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20210109 CJL2 91468 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 102 70-130 1,2-Dichloroethane-d4 102 70-130 Toluene-d8 108 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2021 2121 BNW 04/29/2021 0948 90580 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 97 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 50 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 16 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 2.8 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of 35 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28012-006 Description: LD-6 Matrix: Aqueous Date Sampled:04/26/2021 1645 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20210135 CJL2 91468 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 16 of 35 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: WD28012-006 Description: LD-6 Matrix: Aqueous Date Sampled:04/26/2021 1645 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20210135 CJL2 91468 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 103 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 108 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2021 2127 BNW 04/29/2021 0948 90580 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 410 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 75 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 3.8 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 10 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 17 of 35 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: WD28012-007 Description: Leachate LD Matrix: Aqueous Date Sampled:04/26/2021 1455 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20210422 CJL2 91468 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 18 of 35 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: WD28012-007 Description: Leachate LD Matrix: Aqueous Date Sampled:04/26/2021 1455 Date Received:04/28/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/20210422 CJL2 91468 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 101 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 106 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2021 2151 BNW 04/29/2021 0948 90580 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 28 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.66 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.28 J 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 52 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 14 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 440 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 2.8 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 200 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 19 of 35 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 20 of 35 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91358-001 Matrix: Aqueous Batch: 91358 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 05/06/2021 0917 Acrylonitrile ND 1 20 0.80 ug/L 05/06/2021 0917 Benzene ND 1 1.0 0.40 ug/L 05/06/2021 0917 Bromochloromethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 Bromodichloromethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 Bromoform ND 1 1.0 0.40 ug/L 05/06/2021 0917 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 05/06/2021 0917 2-Butanone (MEK) ND 1 10 2.0 ug/L 05/06/2021 0917 Carbon disulfide ND 1 1.0 0.40 ug/L 05/06/2021 0917 Carbon tetrachloride ND 1 1.0 0.40 ug/L 05/06/2021 0917 Chlorobenzene ND 1 1.0 0.40 ug/L 05/06/2021 0917 Chloroethane ND 1 2.0 0.40 ug/L 05/06/2021 0917 Chloroform ND 1 1.0 0.40 ug/L 05/06/2021 0917 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 05/06/2021 0917 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 05/06/2021 0917 Dibromochloromethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 05/06/2021 0917 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 05/06/2021 0917 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 05/06/2021 0917 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 0917 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 0917 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 05/06/2021 0917 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/06/2021 0917 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/06/2021 0917 Ethylbenzene ND 1 1.0 0.40 ug/L 05/06/2021 0917 2-Hexanone ND 1 10 2.0 ug/L 05/06/2021 0917 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 05/06/2021 0917 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 05/06/2021 0917 Methylene chloride ND 1 1.0 0.40 ug/L 05/06/2021 0917 Styrene ND 1 1.0 0.41 ug/L 05/06/2021 0917 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 Tetrachloroethene ND 1 1.0 0.40 ug/L 05/06/2021 0917 Toluene ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 Trichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 0917 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 05/06/2021 0917 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 21 of 35 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91358-001 Matrix: Aqueous Batch: 91358 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 05/06/2021 0917 Vinyl chloride ND 1 1.0 0.40 ug/L 05/06/2021 0917 Xylenes (total) ND 1 1.0 0.40 ug/L 05/06/2021 0917 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 100 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 107 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 22 of 35 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91358-002 Matrix: Aqueous Batch: 91358 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 92 1 92 60-140 05/06/2021 0755 Acrylonitrile 100 98 1 98 70-130 05/06/2021 0755 Benzene 50 49 1 99 70-130 05/06/2021 0755 Bromochloromethane 50 50 1 101 70-130 05/06/2021 0755 Bromodichloromethane 50 50 1 99 70-130 05/06/2021 0755 Bromoform 50 52 1 104 70-130 05/06/2021 0755 Bromomethane (Methyl bromide) 50 52 1 105 70-130 05/06/2021 0755 2-Butanone (MEK) 100 100 1 103 70-130 05/06/2021 0755 Carbon disulfide 50 54 1 108 70-130 05/06/2021 0755 Carbon tetrachloride 50 51 1 101 70-130 05/06/2021 0755 Chlorobenzene 50 49 1 97 70-130 05/06/2021 0755 Chloroethane 50 53 1 105 70-130 05/06/2021 0755 Chloroform 50 49 1 98 70-130 05/06/2021 0755 Chloromethane (Methyl chloride) 50 48 1 96 60-140 05/06/2021 0755 1,2-Dibromo-3-chloropropane (DBCP) 50 50 1 100 70-130 05/06/2021 0755 Dibromochloromethane 50 51 1 102 70-130 05/06/2021 0755 1,2-Dibromoethane (EDB) 50 50 1 101 70-130 05/06/2021 0755 Dibromomethane (Methylene bromide) 50 50 1 99 70-130 05/06/2021 0755 trans- 1,4-Dichloro-2-butene 50 55 1 109 70-130 05/06/2021 0755 1,2-Dichlorobenzene 50 49 1 99 70-130 05/06/2021 0755 1,4-Dichlorobenzene 50 49 1 97 70-130 05/06/2021 0755 1,1-Dichloroethane 50 50 1 100 70-130 05/06/2021 0755 1,2-Dichloroethane 50 49 1 97 70-130 05/06/2021 0755 1,1-Dichloroethene 50 53 1 107 70-130 05/06/2021 0755 cis- 1,2-Dichloroethene 50 50 1 101 70-130 05/06/2021 0755 trans- 1,2-Dichloroethene 50 51 1 102 70-130 05/06/2021 0755 1,2-Dichloropropane 50 50 1 99 70-130 05/06/2021 0755 cis- 1,3-Dichloropropene 50 53 1 106 70-130 05/06/2021 0755 trans- 1,3-Dichloropropene 50 53 1 106 70-130 05/06/2021 0755 Ethylbenzene 50 52 1 104 70-130 05/06/2021 0755 2-Hexanone 100 110 1 107 70-130 05/06/2021 0755 Methyl iodide (lodomethane) 50 51 1 103 70-130 05/06/2021 0755 4-Methyl-2-pentanone 100 100 1 105 70-130 05/06/2021 0755 Methylene chloride 50 50 1 101 70-130 05/06/2021 0755 Styrene 50 54 1 108 70-130 05/06/2021 0755 1,1,1,2-Tetrachloroethane 50 49 1 98 70-130 05/06/2021 0755 1,1,2,2-Tetrachloroethane 50 48 1 96 70-130 05/06/2021 0755 Tetrachloroethene 50 50 1 101 70-130 05/06/2021 0755 Toluene 50 51 1 102 70-130 05/06/2021 0755 1,1,1-Trichloroethane 50 50 1 100 70-130 05/06/2021 0755 1,1,2-Trichloroethane 50 49 1 98 70-130 05/06/2021 0755 Trichloroethene 50 49 1 98 70-130 05/06/2021 0755 Trichlorofluoromethane 50 52 1 104 70-130 05/06/2021 0755 1,2,3-Trichloropropane 50 49 1 98 70-130 05/06/2021 0755 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 23 of 35 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91358-002 Matrix: Aqueous Batch: 91358 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 49 1 98 60-140 05/06/2021 0755 Vinyl chloride 50 52 1 103 70-130 05/06/2021 0755 Xylenes (total) 100 110 1 106 70-130 05/06/2021 0755 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 104 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 103 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 24 of 35 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91468-001 Matrix: Aqueous Batch: 91468 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 05/06/2021 2133 Acrylonitrile ND 1 20 0.80 ug/L 05/06/2021 2133 Benzene ND 1 1.0 0.40 ug/L 05/06/2021 2133 Bromochloromethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 Bromodichloromethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 Bromoform ND 1 1.0 0.40 ug/L 05/06/2021 2133 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 05/06/2021 2133 2-Butanone (MEK) ND 1 10 2.0 ug/L 05/06/2021 2133 Carbon disulfide ND 1 1.0 0.40 ug/L 05/06/2021 2133 Carbon tetrachloride ND 1 1.0 0.40 ug/L 05/06/2021 2133 Chlorobenzene ND 1 1.0 0.40 ug/L 05/06/2021 2133 Chloroethane ND 1 2.0 0.40 ug/L 05/06/2021 2133 Chloroform ND 1 1.0 0.40 ug/L 05/06/2021 2133 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 05/06/2021 2133 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 05/06/2021 2133 Dibromochloromethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 05/06/2021 2133 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 05/06/2021 2133 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 05/06/2021 2133 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 2133 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 2133 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 05/06/2021 2133 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/06/2021 2133 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/06/2021 2133 Ethylbenzene ND 1 1.0 0.40 ug/L 05/06/2021 2133 2-Hexanone ND 1 10 2.0 ug/L 05/06/2021 2133 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 05/06/2021 2133 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 05/06/2021 2133 Methylene chloride ND 1 1.0 0.40 ug/L 05/06/2021 2133 Styrene ND 1 1.0 0.41 ug/L 05/06/2021 2133 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 Tetrachloroethene ND 1 1.0 0.40 ug/L 05/06/2021 2133 Toluene ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 Trichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 2133 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 05/06/2021 2133 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 05/06/2021 2133 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 25 of 35 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91468-001 Matrix: Aqueous Batch: 91468 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 05/06/2021 2133 Vinyl chloride ND 1 1.0 0.40 ug/L 05/06/2021 2133 Xylenes (total) ND 1 1.0 0.40 ug/L 05/06/2021 2133 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 105 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 107 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 26 of 35 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91468-002 Matrix: Aqueous Batch: 91468 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 96 1 96 60-140 05/06/2021 2012 Acrylonitrile 100 98 1 98 70-130 05/06/2021 2012 Benzene 50 49 1 97 70-130 05/06/2021 2012 Bromochloromethane 50 49 1 98 70-130 05/06/2021 2012 Bromodichloromethane 50 50 1 101 70-130 05/06/2021 2012 Bromoform 50 51 1 103 70-130 05/06/2021 2012 Bromomethane (Methyl bromide) 50 50 1 100 70-130 05/06/2021 2012 2-Butanone (MEK) 100 110 1 108 70-130 05/06/2021 2012 Carbon disulfide 50 50 1 101 70-130 05/06/2021 2012 Carbon tetrachloride 50 48 1 96 70-130 05/06/2021 2012 Chlorobenzene 50 49 1 97 70-130 05/06/2021 2012 Chloroethane 50 50 1 99 70-130 05/06/2021 2012 Chloroform 50 48 1 96 70-130 05/06/2021 2012 Chloromethane (Methyl chloride) 50 46 1 92 60-140 05/06/2021 2012 1,2-Dibromo-3-chloropropane (DBCP) 50 51 1 103 70-130 05/06/2021 2012 Dibromochloromethane 50 51 1 101 70-130 05/06/2021 2012 1,2-Dibromoethane (EDB) 50 50 1 100 70-130 05/06/2021 2012 Dibromomethane (Methylene bromide) 50 49 1 99 70-130 05/06/2021 2012 trans- 1,4-Dichloro-2-butene 50 53 1 106 70-130 05/06/2021 2012 1,2-Dichlorobenzene 50 50 1 99 70-130 05/06/2021 2012 1,4-Dichlorobenzene 50 49 1 98 70-130 05/06/2021 2012 1,1-Dichloroethane 50 48 1 96 70-130 05/06/2021 2012 1,2-Dichloroethane 50 48 1 96 70-130 05/06/2021 2012 1,1-Dichloroethene 50 49 1 99 70-130 05/06/2021 2012 cis- 1,2-Dichloroethene 50 51 1 101 70-130 05/06/2021 2012 trans- 1,2-Dichloroethene 50 50 1 101 70-130 05/06/2021 2012 1,2-Dichloropropane 50 49 1 97 70-130 05/06/2021 2012 cis- 1,3-Dichloropropene 50 54 1 107 70-130 05/06/2021 2012 trans- 1,3-Dichloropropene 50 54 1 108 70-130 05/06/2021 2012 Ethylbenzene 50 52 1 103 70-130 05/06/2021 2012 2-Hexanone 100 100 1 102 70-130 05/06/2021 2012 Methyl iodide (lodomethane) 50 50 1 101 70-130 05/06/2021 2012 4-Methyl-2-pentanone 100 100 1 103 70-130 05/06/2021 2012 Methylene chloride 50 49 1 98 70-130 05/06/2021 2012 Styrene 50 53 1 107 70-130 05/06/2021 2012 1,1,1,2-Tetrachloroethane 50 49 1 98 70-130 05/06/2021 2012 1,1,2,2-Tetrachloroethane 50 48 1 96 70-130 05/06/2021 2012 Tetrachloroethene 50 49 1 98 70-130 05/06/2021 2012 Toluene 50 51 1 102 70-130 05/06/2021 2012 1,1,1-Trichloroethane 50 48 1 96 70-130 05/06/2021 2012 1,1,2-Trichloroethane 50 48 1 96 70-130 05/06/2021 2012 Trichloroethene 50 50 1 100 70-130 05/06/2021 2012 Trichlorofluoromethane 50 48 1 96 70-130 05/06/2021 2012 1,2,3-Trichloropropane 50 49 1 99 70-130 05/06/2021 2012 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 27 of 35 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91468-002 Matrix: Aqueous Batch: 91468 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 49 1 98 60-140 05/06/2021 2012 Vinyl chloride 50 48 1 96 70-130 05/06/2021 2012 Xylenes (total) 100 100 1 105 70-130 05/06/2021 2012 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 103 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 102 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 28 of 35 ICP-MS Metals - MB Sample ID: WQ90580-001 Matrix: Aqueous Batch: 90580 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/29/2021 0948 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 04/29/2021 2008 Arsenic ND 1 2.0 1.3 ug/L 04/29/2021 2008 Barium ND 1 5.0 1.3 ug/L 04/29/2021 2008 Beryllium ND 1 0.40 0.15 ug/L 04/29/2021 2008 Cadmium ND 1 0.50 0.13 ug/L 04/29/2021 2008 Chromium ND 1 5.0 1.3 ug/L 04/29/2021 2008 Cobalt ND 1 5.0 1.3 ug/L 04/29/2021 2008 Copper ND 1 5.0 1.3 ug/L 04/29/2021 2008 Lead ND 1 1.0 0.25 ug/L 04/29/2021 2008 Nickel ND 1 5.0 1.3 ug/L 04/29/2021 2008 Selenium ND 1 5.0 1.3 ug/L 04/29/2021 2008 Silver ND 1 1.0 0.25 ug/L 04/29/2021 2008 Thallium ND 1 0.50 0.15 ug/L 04/29/2021 2008 Vanadium ND 1 5.0 2.5 ug/L 04/29/2021 2008 Zinc ND 1 10 2.5 ug/L 04/29/2021 2008 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 29 of 35 ICP-MS Metals - LCS Sample ID: WQ90580-002 Matrix: Aqueous Batch: 90580 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/29/2021 0948 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 100 1 101 80-120 04/29/2021 2014 Arsenic 100 100 1 102 80-120 04/29/2021 2014 Barium 100 100 1 102 80-120 04/29/2021 2014 Beryllium 100 100 1 102 80-120 04/29/2021 2014 Cadmium 100 100 1 103 80-120 04/29/2021 2014 Chromium 100 100 1 100 80-120 04/29/2021 2014 Cobalt 100 100 1 100 80-120 04/29/2021 2014 Copper 100 100 1 103 80-120 04/29/2021 2014 Lead 100 95 1 95 80-120 04/29/2021 2014 Nickel 100 100 1 101 80-120 04/29/2021 2014 Selenium 100 96 1 96 80-120 04/29/2021 2014 Silver 100 100 1 101 80-120 04/29/2021 2014 Thallium 100 96 1 96 80-120 04/29/2021 2014 Vanadium 100 100 1 100 80-120 04/29/2021 2014 Zinc 100 94 1 94 80-120 04/29/2021 2014 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 30 of 35 ICP-MS Metals - MS Sample ID: WD28012-002MS Matrix: Aqueous Batch: 90580 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/29/2021 0948 Sample Spike Amount Amount Result %Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony ND 100 100 1 102 75-125 04/29/2021 2045 Arsenic ND 100 100 1 100 75-125 04/29/2021 2045 Barium 260 100 370 1 115 75-125 04/29/2021 2045 Beryllium 0.23 100 98 1 98 75-125 04/29/2021 2045 Cadmium ND 100 100 1 100 75-125 04/29/2021 2045 Chromium 19 100 120 1 103 75-125 04/29/2021 2045 Cobalt 76 100 170 1 95 75-125 04/29/2021 2045 Copper 10 100 110 1 98 75-125 04/29/2021 2045 Lead 1.8 100 99 1 97 75-125 04/29/2021 2045 Nickel 28 100 130 1 98 75-125 04/29/2021 2045 Selenium ND 100 95 1 95 75-125 04/29/2021 2045 Silver ND 100 100 1 101 75-125 04/29/2021 2045 Thallium ND 100 99 1 99 75-125 04/29/2021 2045 Vanadium 20 100 120 1 105 75-125 04/29/2021 2045 Zinc 33 100 130 1 95 75-125 04/29/2021 2045 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 31 of 35 ICP-MS Metals - MSD Sample ID: WD28012-002MD Matrix: Aqueous Batch: 90580 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/29/2021 0948 Sample Spike Amount Amount Result %Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Antimony ND 100 100 1 103 0.78 75-125 20 04/29/2021 2051 Arsenic ND 100 98 1 98 1.8 75-125 20 04/29/2021 2051 Barium 260 100 380 1 122 2.0 75-125 20 04/29/2021 2051 Beryllium 0.23 100 100 1 102 4.2 75-125 20 04/29/2021 2051 Cadmium ND 100 98 1 98 2.0 75-125 20 04/29/2021 2051 Chromium 19 100 120 1 102 0.49 75-125 20 04/29/2021 2051 Cobalt 76 100 170 1 89 3.7 75-125 20 04/29/2021 2051 Copper 10 100 110 1 98 0.46 75-125 20 04/29/2021 2051 Lead 1.8 100 98 1 97 0.26 75-125 20 04/29/2021 2051 Nickel 28 100 120 1 97 1.1 75-125 20 04/29/2021 2051 Selenium ND 100 93 1 93 2.1 75-125 20 04/29/2021 2051 Silver ND 100 100 1 101 0.099 75-125 20 04/29/2021 2051 Thallium ND 100 97 1 97 1.7 75-125 20 04/29/2021 2051 Vanadium 20 100 120 1 104 0.88 75-125 20 04/29/2021 2051 Zinc 33 100 130 1 98 2.2 75-125 20 04/29/2021 2051 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 32 of 35 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 33 of 35 �0 <CD m D >v v CD C - 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AnaPIl cal '106 Vantage O'air7l nretiJS , 1+sres' ColurriM'a, 80 PFJ117P Toltiphone No, 800-7: i-9700 Fax No, 843-T91-9111 www-paaelabs.carr. CHY A.1�,.�p i S�YFdr9 I TV.Cua< .-rQLeC! hfb. 21 f0w8>EratoarrhiauR%VmQrbrm&* mdionhFwj I. p i S D —q — - re,wrr b owifsa P..;.,LU "IM le �aew1 �4 rJ. i::1- $� 114�}rra' I FA if frrJ.h'Inrx �yl''ti rrse i CmerCd, 7kW- i I I r `rcI icy I K30 } 1 Turn AMUAiTimeAug uireeffPd.!lab RADWa7jrQU 0106CCdeOAid.`#M1pll9L7i9J11625� f l 6h-ffrdard —, Ruar ifyj i_ p2w b fdr. tWw ._j bTWOif h Y- r7rnkr�a:,f,K7 Jry - UNA9 ki' 10 Re51x}u�, dby io rirl S ,hls.',rqurshs4 _r'�' .f- r7elvrGl. &Ml?d by Gate Frr�e Notq, M samples ara retnl wd !Or fog r weckr fiorr rcW UFKC-_s3ottrerarTq,:aerrWrlt3 are rrQdc. M;MRVMWi 4Wk TF.S Y.cr1.9W,%Awa eotbmz?l -r V47 CnPY rebAhona Na- r C-ftw 3Y 7 V Number ULM" Na. f��ot 4 Sri?. — I AM.Luf /CaoMerl.L7. P,Ks geRazzidOCAegukemsnrsiSteuryl O Nan -Fa d r 1 F2wmt?T - $kirk innan !.' Parson _ rP17v- O -- M. RELMOi d by re � J e --- z, a R6,:&M4 ty LAW TV" Mi' 7 _....- LAB USE O&Yr R£C+cavdd oP ,�70 ierl� S4rnk - '=n' �c�flnm� ivun>�a�, xr�a�l. PACE ANALYTICAL SERVICES, LLC Samples Receipt CherM-1st (SRC) (h'lE00f 15) Revlsed:9129/20-2rf a eAr�rlY�x 1 Issui r'.g AutfLarity: Pace CNV - WCOL Paga 1 of i Sample Rectipt hmkclW (SRC.) Clint_ Bf_E Cankr In:ipLTtaxl hy1dn#F;; MEH / 0412W021 L.vt. k WID2012 .bf-Llwrt tofreceipr: Pace LIClient 0 UPS 0 FAEx Otha', Yes ZNcjI. Wom vuswdy scats prescnr on the cooler? Lj YeSj Lj Tvc, d WA 2_ If eu.;tsd y fieals urge nre.5rnt„ wera they intact and wibroken? — - - PH strip LD; 7�1712 Chlorinc Strip ID: NA `frskrxi by; M _ Vrigirual tcmpcamreupon n2ceipl. r De,-fve[I (Corrccicd) Lcmpimalure upon L%zceipt %S❑lid Rnap-Uup IF]_ J'4A 7.5 .12.5 -C NA j14A {C HA I A QC NA INN DC - Metliad: ❑d Tem}m--r7t-mrc Flunk; Ekgninst Buttes I Gun 1D. F1 I Gun Correction Factor' 0 °C Mohod ol"coolam: ❑d Wet 1" ❑ lochacks ❑ DLV [I;e ❑ N011 : ❑Yes ❑ No ❑NA -- 3. IfRorpwdurc trr'any anciler rxrrcxlr�t G, a'C, was P1'ojea Man arerM LIf`i;;d : PM was Notified Isy, phnme f email e' Face to -face (circ.le one). Yea f 0 No A ArA 14. Is the calmuercllil cauriues RKckinx s[iii attached tD this farm? JZ Yes Lj No 5, Were 11'.2per eLstody prux:-durc5 (Min ishegrewl"ed) fall �wcd? V Yos No. 16. Were sample ID.s Iis;cd oLl ncc COL~? — +{ Y4s ❑Na; .-'I. VW -um samgfe Mr, listed orL all sample coiitainea^s? �$, Yes Ala W s ealIettiolt d;lw & Lime -istad on the CgDC? Yus LJNo 9. was collecdon. Ue & fame .iste-d on all saniCin nonlsiners? ve Yca ONO 10_ Did all c wAakw laaal informattou fID, date:, :fate) ngTwe witb the CO(:? Yes Flo l l_ Wem ur;�jrs lu'aD perfcrmed listed on toe COM. Y-M ❑ N. 12- Did al sample: arrive :a the proper roritaine,s for each LO$L pr XCW in good condition, <,uabrok&i, ltds an, utuJ7 __ ❑ Yts Na 13. Was adeyuatc sanrpl❑ volkunc mrailahle? - -- L v(n Nio Id. Wem ull 9wa)p1cs r;ccived 1ti kWn the holding Iime or 48 hooks. whichevorcomcs first° Ye; No la, %Vcrc any samples cminimr5 missin 'excess CiMll1 one) 581Tp les Not [is[et3 on f:0C7 ❑Yts F6—No ❑NALIG. For VOAand1R:K-175s�jrrLpl4s,wembu'jblespmwt>"pcasixe"(VJ'or6lnrtrindirrnctcr) in ary of tha V0A vials? Y)esr Nu L 1A 1.7, Were a]I DR0 mrLaly*trient samples recei"d at AH of <2? Y esi No ✓ 1�tA 18. Wcrc all cyanide camp, 0S r=tved at a H > 12 and su lndc same leg mreived ar a pH > 97 �Yies ❑T�o �l�h I9, li7= a apptic* q- NH1 [:yanid�.+pttanol162S, IrdM$,3 ,5ir_g ) wrlp.es free of - — residual chlorine? ❑ Yes l_es I ❑ No M 1 r, �fvA 20. Weye;.lie-nt remarksirer uests (i_K. rmrluustad dilutions, MSfMSD desigoatiors�ew...) ilprreuly tmusaribed fratm Lhe C'M intD thL, continent smliaai in UMS'2 2, Was the quate number Ii.sfarl Cal tie Centail7er LAW. Ifycs, Quote # wA �amplt CreBerY$iion (Must be completed itrc ariv 8vmpiq[) inca_-realy prose ry cd or with Ifeadspaco, j Sa[tipl (s) _-.'- -- wort �cocivcd invorractly preserved ;uId we:,�, adjuk[cal Ar. q-dots in 9EunFla rraeiving with rilL;ofcircle one: 142504, HNO'j, HU Na0lI using SR q 1"A Time of prsselVati0n +� If mare than onf±prti'Ar-vazve is needed, plouse gate in [lie corimtrtts be] Dw- Saul fi NA E .e{) _. were received with bubbles >6 intr_ [rr dia:nrrcr, Srmples(S) .KA - were received Wish TRC > 15 Ing1L ([f # 19 fS n-o) and were ad.jimec accordingly in sample mneiirin with sodium thiosulfate rN222 ,00 with Shealy ID. NA Sid barcoda labels applied kty: IRG2 Date, P'f JKgWl T Comments: Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 35 of 35 0 aceAnalytical Report of Analysis Bunnell-Lammons Engineering, Inc. 6004 Ponders Court Greenville, SC 29615 Attention: Andy Alexander Project Name: Active Buncombe County Landfill Leachate Project Number: J21-9378-23 Lot Number:WD27050 Date Completed:05/07/2021 N N NO � � J 05/11 /2021 3:04 PM Approved and released by: Project Manager II: Lucas Odom PCCRF� 24rA SOA / ANSI National Accreditation Board A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 31 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Bunnell-Lammons Engineering, Inc. Lot Number: WD27050 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. Inorganic Non -Metals Sample -001 required multiple runs for Nitrate analysis due to matrix interferences. The third run was reported from a dilution outside of the 48 hour hold time. The LOQ has been elevated to reflect the dilution. No sample dilutions resulted in a depletion of at least 2.0 mg/L for sample -001. The reported BOD was computed using the lowest BOD value that can be calculated with the available data. The data have been 6-flagged accordingly. VOCs by GC/MS The following sample was diluted due to the nature of the sample matrix: WD27050-001. The LOQ has been elevated to reflect the dilution. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 whw.pacelabs.com Page 2 of 31 PACE ANALYTICAL SERVICES, LLC Sample Summary Bunnell-Lammons Engineering, Inc. Lot Number: WD27050 Sample Number Sample ID Matrix Date Sampled Date Received 001 Leachate Pond Aqueous 04/26/2021 1430 04/27/2021 002 Trip Blank Aqueous 04/26/2021 1430 04/27/2021 (2 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 31 PACE ANALYTICAL SERVICES, LLC Detection Summary Bunnell-Lammons Engineering, Inc. Lot Number: WD27050 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 Leachate Pond Aqueous BOD, 5 day SM 5210B- <12 6 mg/L 5 001 Leachate Pond Aqueous COD SM 5220D- 650 mg/L 5 001 Leachate Pond Aqueous Nitrate - N 9056A 0.072 HJ mg/L 5 001 Leachate Pond Aqueous Phosphorus 365.1 1.8 mg/L 5 001 Leachate Pond Aqueous Sulfate 9056A 100 mg/L 5 001 Leachate Pond Aqueous Acetone 8260D 46 J ug/L 5 001 Leachate Pond Aqueous Antimony 6020B 11 ug/L 6 001 Leachate Pond Aqueous Arsenic 6020B 31 ug/L 6 001 Leachate Pond Aqueous Barium 6020B 340 ug/L 6 001 Leachate Pond Aqueous Chromium 6020B 61 ug/L 7 001 Leachate Pond Aqueous Cobalt 6020B 15 ug/L 7 001 Leachate Pond Aqueous Copper 6020B 1.3 J ug/L 7 001 Leachate Pond Aqueous Lead 6020B 0.37 J ug/L 7 001 Leachate Pond Aqueous Nickel 6020B 65 ug/L 7 001 Leachate Pond Aqueous Selenium 6020B 5.7 ug/L 7 001 Leachate Pond Aqueous Vanadium 6020B 24 ug/L 7 001 Leachate Pond Aqueous Zinc 6020B 6.3 J ug/L 7 (17 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 31 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: WD27050-001 Description: Leachate Pond Matrix: Aqueous Date Sampled:04/26/2021 1430 Date Received:04/27/2021 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (BOD, 5 day) SM 521OB-2011 1 05/02/2021 1529 MOM 04/27/2021 1944 90384 1 (COD) SM 5220D-2011 4 04/29/2021 1700 AMR 90689 3 (Nitrate - N) 9056A 10 05/01/2021 0526 AMR 90988 1 (Phosphorus) 365.1 2 04/28/2021 2040 DMA 90500 1 (Sulfate) 9056A 5 04/28/2021 1041 AMR 90653 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run BOD, 5 day SM 521OB-2011 <12 6 2.0 0.18 mg/L 1 COD SM 5220D-2011 650 80 80 mg/L 1 Nitrate - N 9056A 0.072 HJ 0.20 0.050 mg/L 3 Phosphorus 7723-14-0 365.1 1.8 0.10 0.040 mg/L 1 Sulfate 9056A 100 5.0 1.3 mg/L 1 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 5 05/06/20211724 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 46 J 100 25 ug/L 1 Acrylonitrile 107-13-1 8260D ND 100 4.0 ug/L 1 Benzene 71-43-2 8260D ND 5.0 2.0 ug/L 1 Bromochloromethane 74-97-5 8260D ND 5.0 2.0 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 5.0 2.0 ug/L 1 Bromoform 75-25-2 8260D ND 5.0 2.0 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 10 2.0 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 50 10 ug/L 1 Carbon disulfide 75-15-0 8260D ND 5.0 2.0 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 5.0 2.0 ug/L 1 Chlorobenzene 108-90-7 8260D ND 5.0 2.0 ug/L 1 Chloroethane 75-00-3 8260D ND 10 2.0 ug/L 1 Chloroform 67-66-3 8260D ND 5.0 2.0 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 5.0 2.5 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 5.0 2.0 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 5.0 2.0 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 5.0 2.0 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 5.0 2.0 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 10 2.5 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 5.0 2.0 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 5.0 2.0 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 5.0 2.0 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 5.0 2.0 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 5.0 2.0 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 31 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: WD27050-001 Description: Leachate Pond Matrix: Aqueous Date Sampled:04/26/2021 1430 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 5 05/06/20211724 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run cis- 1,2-Dichloroethene 156-59-2 8260D ND 5.0 2.0 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 5.0 2.0 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 5.0 2.0 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 5.0 2.0 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 5.0 2.0 ug/L Ethylbenzene 100-41-4 8260D ND 5.0 2.0 ug/L 2-Hexanone 591-78-6 8260D ND 50 10 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 25 2.0 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 50 10 ug/L Methylene chloride 75-09-2 8260D ND 5.0 2.0 ug/L Styrene 100-42-5 8260D ND 5.0 2.1 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 5.0 2.0 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 5.0 2.0 ug/L Tetrachloroethene 127-18-4 8260D ND 5.0 2.0 ug/L Toluene 108-88-3 8260D ND 5.0 2.0 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 5.0 2.0 ug/L 1,1,2-Trichloroethane 79-00-5 8260D ND 5.0 2.0 ug/L Trichloroethene 79-01-6 8260D ND 5.0 2.0 ug/L Trichlorofluoromethane 75-69-4 8260D ND 5.0 2.0 ug/L 1,2,3-Trichloropropane 96-18-4 8260D ND 5.0 2.0 ug/L Vinyl acetate 108-05-4 8260D ND 25 5.8 ug/L Vinyl chloride 75-01-4 8260D ND 5.0 2.0 ug/L Xylenes (total) 1330-20-7 8260D ND 5.0 2.0 ug/L Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 105 70-130 1,2-Dichloroethane-d4 100 70-130 Toluene-d8 106 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/28/2021 1328 BNW 04/28/2021 0449 90432 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 11 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 31 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 340 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 31 Client: Bun nell-Lammons Engineering, Inc. Laboratory ID: WD27050-001 Description: Leachate Pond Matrix: Aqueous Date Sampled:04/26/2021 1430 Date Received:04/27/2021 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/28/2021 1328 BNW 04/28/2021 0449 90432 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chromium 7440-47-3 6020B 61 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 15 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.3 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.37 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 65 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.7 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 24 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 6.3 J 10 2.5 ug/L 1 Footnote(s): 6-D.O. depletion < 2.00 mg/L LOCI = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 31 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: WD27050-002 Description: Trip Blank Matrix: Aqueous Date Sampled:04/26/2021 1430 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20211104 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 31 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: WD27050-002 Description: Trip Blank Matrix: Aqueous Date Sampled:04/26/2021 1430 Date Received:04/27/2021 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20211104 TML 91358 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 100 70-130 106 70-130 107 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 31 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 31 Inorganic non-metals - BOD Blank and GGA Matrix: Aqueous Batch: 90384 SCF: 0.7 Analytical Method: SM 521 OB-2011 SCF Range: 0.6 - 1.0 Result Avg. Result Sample ID Depl Avg. Depl (mg/L) (mg/L) Q Limit Prep Date Analysis Date WQ90384-041 (Blank) -0.02 0.2 04/27/2021 1817 05/02/2021 1411 WQ90384-141 (Blank) 0.08 0.2 04/27/2021 1817 05/02/2021 1410 WQ90384-241 (Blank) 0.03 0.03 0.2 04/27/2021 1817 05/02/2021 1411 WQ90384-035 (GGA) 160.1 1 167.5-228.5 04/27/2021 1825 05/02/2021 1415 WQ90384-135 (GGA) 187.6 167.5-228.5 04/27/2021 1824 05/02/2021 1414 WQ90384-235 (GGA) 198.6 182.1 167.5-228.5 04/27/2021 1825 05/02/2021 1414 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 31 Inorganic non-metals - Duplicate Sample ID: WD27050-001DU Matrix: Aqueous Batch: 90384 Analytical Method: SM 521OB-2011 Sample Amount Result %RPD Parameter (mg/L) (mg/L) Q Dil % RPD Limit Analysis Date BOD, 5 day <12 <16 + 1 28 20 05/02/2021 1529 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 31 Inorganic non-metals - MB Sample ID: WQ90500-001 Matrix: Aqueous Batch: 90500 Analytical Method: 365.1 Parameter Result Q Dil LOQ DL Units Analysis Date Phosphorus ND 1 0.050 0.020 mg/L 04/28/2021 1431 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 31 Inorganic non-metals - LCS Sample ID: WQ90500-002 Matrix: Aqueous Batch: 90500 Analytical Method: 365.1 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Phosphorus 1.0 0.97 1 97 90-110 04/28/2021 1435 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 31 Inorganic non-metals - Duplicate Sample ID: WD27050-001DU Matrix: Aqueous Batch: 90500 Analytical Method: 365.1 Sample Amount Result %RPD Parameter (mg/L) (mg/L) Q Dil % RPD Limit Analysis Date Phosphorus 1.8 1.9 1 3.3 20 04/28/2021 2010 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of 31 Inorganic non-metals - MB Sample ID: WQ90653-001 Matrix: Aqueous Batch: 90653 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Sulfate ND 1 1.0 0.25 mg/L 04/28/2021 0921 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 16 of 31 Inorganic non-metals - LCS Sample ID: WQ90653-002 Matrix: Aqueous Batch: 90653 Analytical Method: 9056A Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 20 21 1 103 80-120 04/28/2021 1001 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 17 of 31 Inorganic non-metals - LCSD Sample ID: WQ90653-003 Matrix: Aqueous Batch: 90653 Analytical Method: 9056A Spike Amount Result %Rec % RPD Parameter (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Sulfate 20 21 1 103 0.048 80-120 20 04/28/2021 1021 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 18 of 31 Inorganic non-metals - MB Sample ID: WQ90689-001 Matrix: Aqueous Batch: 90689 Analytical Method: SM 5220D-2011 Parameter Result Q Dil LOQ DL Units Analysis Date COD ND 1 20 20 mg/L 04/29/2021 1654 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 19 of 31 Inorganic non-metals - LCS Sample ID: WQ90689-002 Matrix: Aqueous Batch: 90689 Analytical Method: SM 5220D-2011 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date COD 400 410 1 103 95-105 04/29/2021 1654 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 20 of 31 Inorganic non-metals - MB Sample ID: WQ90988-001 Matrix: Aqueous Batch: 90988 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Nitrate - N ND 1 0.020 0.0050 mg/L 04/30/2021 2028 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 21 of 31 Inorganic non-metals - LCS Sample ID: WQ90988-002 Matrix: Aqueous Batch: 90988 Analytical Method: 9056A Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Nitrate - N 0.80 0.81 1 102 80-120 04/30/2021 2008 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 22 of 31 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91358-001 Matrix: Aqueous Batch: 91358 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 05/06/2021 0917 Acrylonitrile ND 1 20 0.80 ug/L 05/06/2021 0917 Benzene ND 1 1.0 0.40 ug/L 05/06/2021 0917 Bromochloromethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 Bromodichloromethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 Bromoform ND 1 1.0 0.40 ug/L 05/06/2021 0917 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 05/06/2021 0917 2-Butanone (MEK) ND 1 10 2.0 ug/L 05/06/2021 0917 Carbon disulfide ND 1 1.0 0.40 ug/L 05/06/2021 0917 Carbon tetrachloride ND 1 1.0 0.40 ug/L 05/06/2021 0917 Chlorobenzene ND 1 1.0 0.40 ug/L 05/06/2021 0917 Chloroethane ND 1 2.0 0.40 ug/L 05/06/2021 0917 Chloroform ND 1 1.0 0.40 ug/L 05/06/2021 0917 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 05/06/2021 0917 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 05/06/2021 0917 Dibromochloromethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 05/06/2021 0917 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 05/06/2021 0917 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 05/06/2021 0917 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 0917 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 0917 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 05/06/2021 0917 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/06/2021 0917 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/06/2021 0917 Ethylbenzene ND 1 1.0 0.40 ug/L 05/06/2021 0917 2-Hexanone ND 1 10 2.0 ug/L 05/06/2021 0917 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 05/06/2021 0917 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 05/06/2021 0917 Methylene chloride ND 1 1.0 0.40 ug/L 05/06/2021 0917 Styrene ND 1 1.0 0.41 ug/L 05/06/2021 0917 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 Tetrachloroethene ND 1 1.0 0.40 ug/L 05/06/2021 0917 Toluene ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 Trichloroethene ND 1 1.0 0.40 ug/L 05/06/2021 0917 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 05/06/2021 0917 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 05/06/2021 0917 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 23 of 31 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ91358-001 Matrix: Aqueous Batch: 91358 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 05/06/2021 0917 Vinyl chloride ND 1 1.0 0.40 ug/L 05/06/2021 0917 Xylenes (total) ND 1 1.0 0.40 ug/L 05/06/2021 0917 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 100 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 107 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 24 of 31 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91358-002 Matrix: Aqueous Batch: 91358 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 92 1 92 60-140 05/06/2021 0755 Acrylonitrile 100 98 1 98 70-130 05/06/2021 0755 Benzene 50 49 1 99 70-130 05/06/2021 0755 Bromochloromethane 50 50 1 101 70-130 05/06/2021 0755 Bromodichloromethane 50 50 1 99 70-130 05/06/2021 0755 Bromoform 50 52 1 104 70-130 05/06/2021 0755 Bromomethane (Methyl bromide) 50 52 1 105 70-130 05/06/2021 0755 2-Butanone (MEK) 100 100 1 103 70-130 05/06/2021 0755 Carbon disulfide 50 54 1 108 70-130 05/06/2021 0755 Carbon tetrachloride 50 51 1 101 70-130 05/06/2021 0755 Chlorobenzene 50 49 1 97 70-130 05/06/2021 0755 Chloroethane 50 53 1 105 70-130 05/06/2021 0755 Chloroform 50 49 1 98 70-130 05/06/2021 0755 Chloromethane (Methyl chloride) 50 48 1 96 60-140 05/06/2021 0755 1,2-Dibromo-3-chloropropane (DBCP) 50 50 1 100 70-130 05/06/2021 0755 Dibromochloromethane 50 51 1 102 70-130 05/06/2021 0755 1,2-Dibromoethane (EDB) 50 50 1 101 70-130 05/06/2021 0755 Dibromomethane (Methylene bromide) 50 50 1 99 70-130 05/06/2021 0755 trans- 1,4-Dichloro-2-butene 50 55 1 109 70-130 05/06/2021 0755 1,2-Dichlorobenzene 50 49 1 99 70-130 05/06/2021 0755 1,4-Dichlorobenzene 50 49 1 97 70-130 05/06/2021 0755 1,1-Dichloroethane 50 50 1 100 70-130 05/06/2021 0755 1,2-Dichloroethane 50 49 1 97 70-130 05/06/2021 0755 1,1-Dichloroethene 50 53 1 107 70-130 05/06/2021 0755 cis- 1,2-Dichloroethene 50 50 1 101 70-130 05/06/2021 0755 trans- 1,2-Dichloroethene 50 51 1 102 70-130 05/06/2021 0755 1,2-Dichloropropane 50 50 1 99 70-130 05/06/2021 0755 cis- 1,3-Dichloropropene 50 53 1 106 70-130 05/06/2021 0755 trans- 1,3-Dichloropropene 50 53 1 106 70-130 05/06/2021 0755 Ethylbenzene 50 52 1 104 70-130 05/06/2021 0755 2-Hexanone 100 110 1 107 70-130 05/06/2021 0755 Methyl iodide (lodomethane) 50 51 1 103 70-130 05/06/2021 0755 4-Methyl-2-pentanone 100 100 1 105 70-130 05/06/2021 0755 Methylene chloride 50 50 1 101 70-130 05/06/2021 0755 Styrene 50 54 1 108 70-130 05/06/2021 0755 1,1,1,2-Tetrachloroethane 50 49 1 98 70-130 05/06/2021 0755 1,1,2,2-Tetrachloroethane 50 48 1 96 70-130 05/06/2021 0755 Tetrachloroethene 50 50 1 101 70-130 05/06/2021 0755 Toluene 50 51 1 102 70-130 05/06/2021 0755 1,1,1-Trichloroethane 50 50 1 100 70-130 05/06/2021 0755 1,1,2-Trichloroethane 50 49 1 98 70-130 05/06/2021 0755 Trichloroethene 50 49 1 98 70-130 05/06/2021 0755 Trichlorofluoromethane 50 52 1 104 70-130 05/06/2021 0755 1,2,3-Trichloropropane 50 49 1 98 70-130 05/06/2021 0755 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 25 of 31 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ91358-002 Matrix: Aqueous Batch: 91358 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 49 1 98 60-140 05/06/2021 0755 Vinyl chloride 50 52 1 103 70-130 05/06/2021 0755 Xylenes (total) 100 110 1 106 70-130 05/06/2021 0755 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 104 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 103 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 26 of 31 ICP-MS Metals - MB Sample ID: WQ90432-001 Matrix: Aqueous Batch: 90432 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/28/2021 0449 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 04/28/2021 1151 Arsenic ND 1 2.0 1.3 ug/L 04/28/2021 1151 Barium ND 1 5.0 1.3 ug/L 04/28/2021 1151 Beryllium ND 1 0.40 0.15 ug/L 04/28/2021 1151 Cadmium ND 1 0.50 0.13 ug/L 04/28/2021 1151 Chromium ND 1 5.0 1.3 ug/L 04/28/2021 1151 Cobalt ND 1 5.0 1.3 ug/L 04/28/2021 1151 Copper ND 1 5.0 1.3 ug/L 04/28/2021 1151 Lead ND 1 1.0 0.25 ug/L 04/28/2021 1151 Nickel ND 1 5.0 1.3 ug/L 04/28/2021 1151 Selenium ND 1 5.0 1.3 ug/L 04/28/2021 1151 Silver ND 1 1.0 0.25 ug/L 04/28/2021 1151 Thallium ND 1 0.50 0.15 ug/L 04/28/2021 1151 Vanadium ND 1 5.0 2.5 ug/L 04/28/2021 1151 Zinc ND 1 10 2.5 ug/L 04/28/2021 1151 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 27 of 31 ICP-MS Metals - LCS Sample ID: WQ90432-002 Matrix: Aqueous Batch: 90432 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/28/2021 0449 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 100 1 101 80-120 04/28/2021 1157 Arsenic 100 100 1 102 80-120 04/28/2021 1157 Barium 100 100 1 102 80-120 04/28/2021 1157 Beryllium 100 100 1 101 80-120 04/28/2021 1157 Cadmium 100 100 1 100 80-120 04/28/2021 1157 Chromium 100 100 1 102 80-120 04/28/2021 1157 Cobalt 100 99 1 99 80-120 04/28/2021 1157 Copper 100 100 1 101 80-120 04/28/2021 1157 Lead 100 100 1 102 80-120 04/28/2021 1157 Nickel 100 100 1 103 80-120 04/28/2021 1157 Selenium 100 95 1 95 80-120 04/28/2021 1157 Silver 100 100 1 100 80-120 04/28/2021 1157 Thallium 100 100 1 100 80-120 04/28/2021 1157 Vanadium 100 100 1 101 80-120 04/28/2021 1157 Zinc 100 95 1 95 80-120 04/28/2021 1157 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 28 of 31 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 29 of 31 �0 <CD m D ;v v CD C - 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If lcm;Icrsturle oFauy tioo[e; =c oded 6,0°C, was Project Manager Notified? J'M was Noliflrd by_ plrDnc J CMZJ[ r WZ-to face (uirile one). ✓ NA 4 L the MYIMerciu! courier's packing slip attachod to d,Ls form? Vereopw etst4dyproscduls(rnainquishedhcctived) 6. W=n stlmpJe I& 1i trxf on the C:O "' 7. were s6rm�la I :iatod an al.1 1TI[e corrtainer�' d Y sLINO 8. was cell [action dare & tilitt� 16 tad on zte COC? 1 Ye1 N{, 9. Was Go]IcLAton dam & lame lisW gn a]I sample conta=tern? - ,{ Ycs - El No 1.0. [lid al] C&I'ItAinel' iabel k6grmatinn (TT}, date, iirrc) ttgrea with the Coca Yes t 'o 1 I _ Were lr;ts lsr be performed ]]sted cm the [:Ott ? _VM ] NEI i2. Did rl]l ampLt nrtive in I=te proper containers fa^ rac;r tcsf zIWOr i, tTod condiIinn (un�rroleer7, IiciS tra, irtC.�? -- +' Yes hta !3, W23 adOq't[atr Snmpd a volurse av;alahle? Yos + ]!0 14_ Were a]I tiarnples nceived wi[a]n 'Js the Iwidin tir11c or d8 ar�crR# whichever s vo�es firfit^ Nn 15. 131Gro unv sa rlpfcs oontaineru misain_ye_�c�.La (circle rmc) in1 1m ; cot listed un C(N ❑ Yrs O NQ L-:] N A 16. 1{or VOA and RL9K-175 sampleii, were buL b n present ,� Wa-sine" {'1'°or GICIM ill ciFlmctW) in any ofthe V0A viaEO Y4 No hIA 17_ W= all DR[]Jnrkc[a;I3'nttl'Wnt samples mewi`� mewed at a pH a2? - yos No weNA I l $. Wurc ail cyan ide sar"A s M%xivcd at a pH> I2 acid rfide nmples receivcE 011 > 9;"4;' W!Ycsl ❑+Nal nNA ElT A e, 2U.1'�e�ecliCntrernxrksrrrr.tte lS (i,roqueated(jilutiolrs, MS1%Dde0 natiDL1s, atr;,,,) c-orrectly Lnmscribsd ±rota the WC: anta tha comment sell-vrt in L[MS? O'10 21_ Was the IMl the Coll 2_;rerLabel? lfym, IQuora� implePr crvatfott (Must becornpleted far stay Earrp]r(s) incarractly pmwrvecJorivith hemispam.) Inple{9) _r.'cr received incorrectly ptc:. ed wid weTeadlristedaccordingly samplcruci�'in Wltlt5_rrrLOfcircle aG;iU5O4_HNO3,[-[Cl,_faO[-[ur.inU,�K0NA _ nip ofpmsci ration H Jf]nM lbxm one Fes vativ+e is rirvded, please note 'n die comments below. s)NA_ were received '&kh buhbley s 6 MITI in dirmeter_ ks) Rrk _ were r2eeivcd with TRC > Q5 n 61. Of V I9 is nu) and "Tre dccondiaig[,' in satnpltl recaiv;u Wit.7 so:iium thiowJfaw (ht12L Beal) Willi Shealy TT)! NA SR �MOOde labels applied by.. MEH Date 04n7r2la2l Cgmments: Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 31 of 31