9202_Wake_EastWake_MSWLF_May21GW_FID1587025_20210624

East Wake Landfill
Facility Permit No. 9202-
MSWLF-1981
Semi -Annual Sampling Report
(May 2021 Sampling Event)
Wake County
Report
Prepared June 2021
WAKE
COUNTY
NORTH CAROLI NA

R USE ONLY: QPaper Repon Elaechnnic Data - Email CD (dale boded' Yes t No) DodEvent #'
NC DENR Environmental Monitoring
Division of Waste Management -Solid Waste Repo
Notice: This form and any information attached to it am'Public Records' as tlefinatl in NC Gerneral Stabrle 132-1. As such, Mere domr Reporting Forth n[s are
available far inspection and examination by any person upon request (NC General Stable 132E).
Instructions:
• Prepare one form for each individually mombered unit
Please type or print legibly.
• Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The ratification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -she source, preexisting
condition, etc.).
Atach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 138 A629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable Rx Compliance Unit, NCDENR-DWM, said Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699=1646,
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consulGM, facility owner):
Consultant - CDM Smith Inc.
Contact for Ruesdom about data formatting. Include dale pmpamr's more, telephone number and Email address:
Name: Mathew F. Colon Phone: [phone]
E-mail: colon onfOodmamith com
NC Laro fill Rule: Actual sampling tables (e.g.,
Facilty name: Facility Address: Facility Permit# (.0500m.1600) Ocbber 20-24, 2006)
East Wake Landfill - Rigs bee
Property
Three Sisters Road
KngMtlale, North Carolina 27545
9202-MSWLF
1981
1600
May 14, 2021
Environmental Status: (Check all that apply)
❑ InitialBackgrountl Monitoring ❑x Detection Monitoring Assessment Monitoring Corrective Action
T,,,YYYpppeee of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑ Methane gas monitoring data
Groundwater monitoring data from private water supply wells ❑ Corrective action data (specify)
Leachate monitoring data Surface water monitoring data ❑ Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
x Yes, a notification of values exceeding a groundwater or surface water standard is ahachetl. It includes a list of groundwater and surface water
monitoring points, dabs, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
value and explosive methane gas limits.
Certification
To the best of nay knowledge, the information reported and statements made on this data submittal and attachments am true and cored.
Furthermore, I her atached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
am significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Mathew F. Colon Consultant [phone]
Fagl' fle,N/a�J (Print TRle (Area Cade)TNeplwn N beIo,,,;�.�:,�_
' �"l `/2/Z.2( Affix NCU ryV^^^�P,rG loge seat
Signature Date a .t
k,
5400 Glenwood Avenue, Suite 400 Raleigh North Carolina 27612 Facility Representative Address c� c<, �
NC PE Fare Ucene Number (f applicable effective May 1, 2009) r
Revised 6)2009

Smith
5400 Glenwood Avenue, Suite 400
Raleigh, North Carolina 27612
tel: [phone]
fax: [phone]
June 24, 2021
Ms. Jaclynne Drummond
North Carolina Department of Environmental Quality
Division of Waste Management
Solid Waste Section
2090 U.S. 70 Highway
Swannanoa, North Carolina 28778
Subject: May 2021 (Spring) Semi -Annual Groundwater Sampling Report
East Wake Landfill - Rigsbee Property
Facility Permit No. 9202-MSWLF-1981
Dear Ms. Drummond:
CDM Smith Inc. (CDM Smith), on behalf of Wake County (County), is submitting an electronic copy of
the May 2021 semi-annual sampling event report for the East Wake Landfill - Rigsbee Property (Site).
This letter report presents the results of the most recent semi-annual sampling event and constitutes
the first semi-annual sampling event for 2021. The approved groundwater monitoring network
consists of one background well (i.e., MW-01), and five downgradient monitoring wells (i.e., MW-02,
-03, -04S, -04D, and -07). Field activities and sampling results are discussed below.
Background
The Site is located on two parcels. One of the parcels as shown on Figure 1 is owned by Carolyn
Properties, LLC and contains approximately 27 acres of waste. This parcel is referred to as the J.T.
Knott property and is currently part of the North Carolina Department of Environmental Quality's
Inactive Hazardous Sites Pre -Regulatory Landfill program. The background monitoring well for the
portion of the landfill located on the James Ervin Rigsbee (Rigsbee) property, MW-01, is located on
this parcel along with a private airport and several businesses.
The parcel owned by Mr. Rigsbee contains approximately 46 acres of waste located in two separate
areas as shown on Figure 1. This parcel borders the J.T. Knott property to the south and west. A large
portion of the parcel is used for cattle pasture and includes an explosive storage company and
associated storage and office trailers, a home with a detached garage and two barns, and a storage
area for abandoned automobiles. All monitoring wells for the Site, except for the background well, are
located on this parcel. This portion of the Site operated under Permit Number 92-02 until the two
waste disposal areas ceased operations in 1983 (Area C) and 1985 (Area D).
The two areas of waste located on the Rigsbee property are known as Areas C and D as shown on
Figure 1. Groundwater assessment for Area C is being conducted under the supervision of the Inactive
tD
WATER + ENVIRONMENT +TRANSPORTATION + ENERGY + FACILITIES

Smith
Ms. Jaclynne Drummond
June 24, 2021
Page 2
Hazardous Sites Pre -Regulatory Landfill Unit after this area of waste was determined to be eligible for
the program in the fall of 2012.
Since 2012, the County has voluntarily collected groundwater samples semi-annually from the Area C
monitoring wells (i.e., MW-5, -6, -8, -9, and -10). On September 13, 2018, the Solid Waste Section
(SWS) approved the discontinuation of the groundwater monitoring of Area C, beginning with the fall
2018 sampling event.
Field Activities
Groundwater samples were collected on May 14, 2021, by use of disposable, laboratory
decontaminated bailers. Monitoring well sampling locations are presented on Figure 1. Well
construction details are provided in Table 1.
Groundwater elevations were measured at each well on May 13, 2021, prior to sampling and are
presented in Table 2. These groundwater elevations were used to construct potentiometric contours
for this sampling event and are presented on Figure 1. The groundwater elevations and
potentiometric contours were used to estimate the groundwater velocity at each well. Groundwater
velocity values are provided in Table 3.
After depth to groundwater was determined, three well volumes of water were removed from each
well prior to sampling to provide fresh formation water within the well water column. Each well
volume was measured for pH, conductivity, temperature, turbidity, dissolved oxygen, and
oxidation-reduction potential using a YSI-556 multi -parameter water quality meter and a HANNA HI
98703 turbidity meter. Wells with elevated turbidity were allowed to stabilize prior to sample
collection. The water quality parameters at the time of sampling are presented in Table 2.
Alternate Source Demonstration
On August 17, 2020, CDM Smith submitted an Alternate Source Demonstration (ASD) for the Site on
behalf of the County. The purpose of the ASD was to demonstrate that metals exceeding the 15A
NCAC 02L .0202 (NC 2L) Groundwater Standards or Interim Maximum Allowable Concentrations
(IMAC) are naturally occurring and not related to a release from the landfill. The ASD was prepared
using analytical data from the background monitoring well, MW-01, that was collected on a quarterly
basis from January 2018 to February 2020 to develop upper tolerance limits (UTLs) for specific
analytes that historically exceeded their respective NC 2L Groundwater Standard or IMAC. Based on
statistical analysis, a UTL of 2.82 parts per billion (ppb) was proposed for cobalt and a UTL of 2 ppb
was proposed for vanadium. The SWS approved these proposed UTLs on August 20, 2020.
0

Smith
Ms. Jaclynne Drummond
June 24, 2021
Page 3
Sampling Results
Pace Analytical Services, LLC, located in West Columbia, South Carolina, analyzed the groundwater
samples for the North Carolina Appendix I volatile organic compounds and Appendix I metals. In a
letter dated May 29, 2018, the SWS stated that all groundwater and surface water samples collected
from landfills be analyzed for 1,4-dioxane after July 1, 2018. On June 26, 2019, the SWS approved the
removal of 1,4-dioxane from the sampling program for all monitoring wells, with the exceptions of
MW-03, -045, and -4D, due to two consecutive non -detect events (October 2018 and April 2019).
Samples were collected from the wells requiring the 1,4-dioxane analysis during the May 2021 semi-
annual sampling event. Sample results are provided below.
The analytical results were reported to the laboratory specific method detection limit (MDL) and are
quantifiable at or below the laboratory limit of quantitation (LOQ). All monitoring wells for the Site
had detections of analytes above the MDL but below the LOQ that were qualified as estimated or "J"
flags.
The following list indicates the analytes detected above the LOQ at each sampling location. No "J" flag
detections are provided. Underlined analytes exceeded the NC 2L Groundwater Standard, IMAC, or
UTL. A complete summary of all detected and estimated concentrations for the May 2021 sampling
event and previous sampling events is provided in Table 4. The laboratory analytical data report is
provided in Appendix A.
MW-01 (Background)
Metals:
Volatile Organic Compounds:
AREA D
MW-02
Metals:
Volatile Organic Compounds
MW-03
Metals:
Volatile Organic Compounds
MW-04S
Metals:
Barium, Beryllium, Copper, Lead, Vanadium, Zinc
None Detected
Barium, Beryllium, Chromium, Copper, Lead, Vanadium, Zinc
None Detected
Barium, Copper, Lead, Nickel, Zinc
Chlorobenzene, 1,4-Dichlorobenzene, 1,4-Dioxane
Barium, Cobalt, Copper, Lead, Nickel, Zinc
Volatile Organic Compounds: Acetone, Benzene, Chlorobenzene, 1,4-Dichlorobenzene, 1,1-
Dichloroethane, 1.4-Dioxane
0

Smith
Ms. Jaclynne Drummond
June 24, 2021
Page 4
MW-04D
Metals: Arsenic, Barium, Beryllium, Cobalt, Copper, Lead, Nickel, Vanadium,
Zinc
Volatile Organic Compounds: Acetone, Chloroethane, 1,4-Dichlorobenzene, 1,4-Dioxane
MW-07
Metals: Barium, Beryllium, Cadmium, Copper, Lead, Zinc
Volatile Organic Compounds: None Detected
"J" flags were not included in the previous list, but several locations had "J" flag detections that
exceeded the standards. The "J" flag constituents above the standards along with their locations are
listed below.
Cobalt: MW-02
Thallium: MW-01 and -02
Vanadium: MW-03, -04S, and -07
An equipment blank, trip blank, and duplicate sample were analyzed for quality control. Acetone was
detected as an estimated concentration in the equipment blank below its NC 2L Standard. No analytes
were detected in the equipment or trip blanks above the MDL. The duplicate sample, identified as
DUP, was collected from MW-07 and had similar analyte concentrations as those detected in MW-07.
Table 5 presents a summary of all parameters detected during the May 2021 sampling event that
exceeded the NC 2L Groundwater Standards, IMACs, or UTLs.
Additional metals samples were collected from all monitoring wells during the May 2021 sampling
event for the laboratory to filter and analyze due to elevated turbidity (i.e., greater than 10
Nephelometric Turbidity Units). Total metals that exceeded the NC 2L Groundwater Standards, IMACs,
or UTLs were analyzed for dissolved metals to determine if turbidity was a contributing factor to total
reported metals.
Cobalt was detected in the dissolved metal samples collected from MW-04S, -04D, and -07 above its
UTL. Barium was also detected above its NC 2L Groundwater Standard in the dissolved metal sample
collected from MW-04D. This detection of barium had a "D" flag, indicating that the sample was
analyzed at a dilution greater than one. Additionally, cadmium was detected above its NC 2L
Groundwater Standard in the dissolved metal sample collected from MW-07. There were no other
dissolved metal exceedances. Dissolved metal sample results are provided in Table 4 and the
laboratory report is provided in Appendix A.
The County will continue with the semi-annual groundwater monitoring program for Area D. The
concentration of 1,4-dioxane will continue to be monitored in MW-03, -045, and -04D. The next
sampling event will be completed in the fall of 2021.
0

Smith
Ms. Jaclynne Drummond
June 24, 2021
Page 5
If you have any questions or require further explanation, do not hesitate to call me at [phone].
Very truly yours,
Mathew F. Colone, P.G.
CDM Smith Inc.
cc: John Roberson, WCSWM
Elliott Cornell, WCSWM
0

Table 1
Well Construction Summary
East Wake - Area D
Permit Number 9202-MSWLF-1981
Notes:
1. bgs - Below Ground Surface
2. AMSL - Above Mean Sea Level
TOC - Top of Casing
4. Latitude and longitude - World Geodetic System 1984
Smith Page 1 of 1 June 2021

Table 2
Water Quality Parameters
May 2021 Semi -Annual Sampling Event
East Wake Landfill - Area D
Permit Number 9202-MSWLF-1981
Facility Permit
Monitoring
Number
Well
Water Quality Parameters
Code pH Conductivity Temperature Turbidity DO ORP
(S.U.) (µS/cm) (deg. C) (NTUs) (mg/L) (mVs)
Groundwater Elevations - Measured
Depth to
TOC Elevation
Groundwater
5/13/2021
Groundwater
Elevation
(feet AMSL) (feet bgs)
(feet AMSL)
..
Notes:
1. Water levels and water quality measurements were collected on May 13-14, 2021.
2. AMSL - Above Mean Sea Level
3. TOC -
Top of Casing
4. bgs -
Below Ground Surface
5. µS/cm - Microsiemens per centimeter
6. mg/L
- Milligrams per liter
7. ORP -
Oxidation -Reduction Potential
8. NTUs
- Nephelometric Turbidity Units
9. mvs -
Millivolts
10. S.U.
- Standard Units
11. DO - Dissolved Oxygen
12. Monitoring wells with high turbidity were allowed to settle prior to sampling; turbidity shown in table was recorded at the time of sampling.
Smith Page 1 of 1 June 2021

Table 3
Summary of Calculated Groundwater Flow Velocities
May 2021 Semi -Annual Sampling Event
East Wake Landfill - Area D
Permit Number 9202-MSWLF-1981
Facility Permit
Number
9202-MSWLF-1981
Monitoring
Well Code
MW-01
Hydraulic Conductivity
(feet/day)
0.4927
Gradient
0.0207
Effective
Porosity
0.3
Average Linear Velocity
(feet/day)
3.40E-02
9202-MSWLF-1981
MW-02
0.4927
0.0256
0.3
4.20E-02
9202-MSWLF-1981
MW-03
0.4927
0.0244
0.3
4.00E-02
9202-MSWLF-1981
MW-04S
0.4927
0.0203
0.3
3.34E-02
9202-MSWLF-1981
MW-04D
0.4927
0.0202
0.3
3.32E-02
9202-MSWLF-1981
MW-07
1 0.4927
1 0.0131
1 0.3
1 2.15E-02
Notes:
1. Hydraulic conductivity and porosity are values from HDR's 2014 Fall Semi -Annual Report.
2. Hydraulic gradient was calculated using MW-1.
Smith Page 1 of 1 June 2021

Table 4
Detected Groundwater Constituents
May 2021 Semi -Annual Sampling Event
East Wake Landfill - Area D
Permit Number 9202-MSWLF-1981
Monitoring.
Parameter Result Qualifier
Code IMAC, or UTL
Barium 160 700
1.3
µg/L
Beryllium 2.6 4*
0.15
µg/L
Chromium 3.3 J 10
1.3
µg/L
Cobalt 2.4 J 2.82**
1.3
µg/L
Copper 9.0 1,000
1.3
µg/L
Lead 2.8 15
0.25
µg/L
MW-01 Nickel 1.3 J 100
1.3
µg/L
Thallium 0.20 J 0.2*
0.15
µg/L
Thallium (dissolved) 0.2*
0.15
µg/L
Vanadium 8.5 2**
2.5
µg/L
Vanadium (dissolved) 2**
2.5
µg/L
Zinc 25 1,000
2.5
µg/L
Acetone 5.2 J 6,000
4.0
µg/L
Barium
80
700
1.3
µg/L
Beryllium
1.7
4*
0.15
µg/L
Chromium
6.0
10
1.3
µg/L
Cobalt
3.2
J
2.82**
1.3
µg/L
Cobalt (dissolved)
2.82**
1.3
µg/L
Copper
12
1,000
1.3
µg/L
MW-02
Lead
25
15
0.25
µg/L
Lead (dissolved)
15
0.25
µg/L
Nickel
3.2
J
100
1.3
µg/L
Thallium
0.24
J
0.2*
0.15
µg/L
Thallium (dissolved)
0.2*
0.15
µg/L
Vanadium
11
2**
2.5
µg/L
Vanadium (dissolved)
2**
2.5
µg/L
Zinc
56
1
1,000
2.5
µg/L
Barium
390
700
1.3
µg/L
Beryllium
0.28
J
4*
0.15
µg/L
Chromium
3.5
J
10
1.3
µg/L
Cobalt
1.5
J
2.82**
1.3
µg/L
Copper
24
1,000
1.3
µg/L
Lead
8.0
15
0.25
µg/L
MW-03
Nickel
6.4
100
1.3
µg/L
Vanadium
4.9
J
2**
2.5
µg/L
Vanadium (dissolved)
2**
2.5
µg/L
Zinc
14.0
1,000
2.5
µg/L
Acetone
7.1
J
6,000
4.0
µg/L
Chlorobenzene
3.5
50
0.40
µg/L
1,4-Dichlorobenzene
0.84
6
0.40
µg/L
1,4-Dioxane
1 14
1
1 3
1 1.0
1 lig/L
CDM Page 1 of 3 June 2021
smith

Table 4
Detected Groundwater Constituents
May 2021 Semi -Annual Sampling Event
East Wake Landfill - Area D
Permit Number 9202-MSWLF-1981
Monitoring.
Parameter Result Qualifier
Code IMAC, or UTL
Arsenic 1.6 J 10
0.50
µg/L
Barium 930 700
1.3
µg/L
Barium (dissolved) 700
1.3
µg/L
Beryllium 0.31 J 4*
0.15
µg/L
Cadmium 0.26 J 2
0.50
µg/L
Cobalt 32 2.82**
1.3
µg/L
Cobalt (dissolved) 29 2.82**
1.3
µg/L
Copper 21 1,000
1.3
µg/L
Lead 1.8 15
0.25
µg/L
Nickel 18 100
1.3
µg/L
MW-04S Selenium 3.5 J 20
1.3
µg/L
Thallium 0.16 J 0.2*
0.15
µg/L
Vanadium 3.9 J 2**
2.5
µg/L
Vanadium (dissolved) 2**
2.5
µg/L
Zinc 16 1,000
2.5
µg/L
Acetone 11 6,000
4.0
µg/L
Benzene 0.71 1
0.40
µg/L
Chlorobenzene 7.0 50
0.40
µg/L
1,4-Dichlorobenzene 1.5 6
0.40
µg/L
1,1-Dichloroethane 0.59 6
0.40
µg/L
1,4-Dioxane 42 3
1.0
µg/L
Antimony
0.64
J
1
0.50
µg/L
Arsenic
3.1
10
0.50
µg/L
Barium
1,100
700
1.3
µg/L
Barium (dissolved)
650
D
700
1.3
µg/L
Beryllium
0.40
4*
0.15
µg/L
Chromium
2.5
J
10
1.3
µg/L
Cobalt
22
2.82**
1.3
µg/L
Cobalt (dissolved)
18
2.82**
1.3
µg/L
Copper
16
1,000
1.3
µg/L
MW-04D
Lead
2.7
15
0.25
µg/L
Nickel
16
100
1.3
µg/L
Selenium
3.2
J
20
1.3
µg/L
Vanadium
7.5
2**
2.5
µg/L
Vanadium (dissolved)
2**
2.5
µg/L
Zinc
20
1,000
2.5
µg/L
Acetone
10
6,000
4.0
µg/L
Chlorobenzene
3.1
50
0.40
µg/L
1,4-Dichlorobenzene
0.80
6
0.40
µg/L
1,4-Dioxane
21
3
1.0
µg/L
CDM
Smith Page 2 of 3 June 2021

Table 4
Detected Groundwater Constituents
May 2021 Semi -Annual Sampling Event
East Wake Landfill - Area D
Permit Number 9202-MSWLF-1981
Monitoring.
Parameter Result Qualifier
Code IMAC, or UTL
Barium 100 700
1.30
µg/L
Beryllium 1.1 4*
0.15
µg/L
Cadmium 9.4 2
0.13
µg/L
Cadmium (dissolved) 2.4 2
0.13
µg/L
Chromium 3.1 J 10
1.3
µg/L
Cobalt 1.8 J 2.82**
1.3
µg/L
MW-07 Copper 5.5 1,000
1.3
µg/L
Lead 2.6 15
0.25
µg/L
Nickel 2.0 J 100
1.3
µg/L
Vanadium 3.6 J 2**
2.5
µg/L
Vanadium (dissolved) 2**
2.5
µg/L
Zinc 250 1,000
2.5
µg/L
Acetone 4.4 J 6,000
4.0
1 µg/L
Barium
91
700
1.30
µg/L
Beryllium
1.1
4*
0.15
µg/L
Cadmium
6.0
2
0.13
µg/L
Cadmium (dissolved)
2
0.13
µg/L
Chromium
2.9
J
10
1.3
µg/L
Cobalt
1.7
J
2.82**
1.3
µg/L
MW-07 (dup)
Copper
3.6
J
1,000
1.3
µg/L
Lead
1.9
15
0.25
µg/L
Nickel
1.6
J
100
1.3
µg/L
Vanadium
2.9
J
2**
2.5
µg/L
Vanadium (dissolved)
2**
2.5
µg/L
Zinc
160
1,000
2.5
µg/L
Acetone
4.7
J
6,000
1 4.0
1 µg/L
Notes:
1. All units are in micrograms per liter (parts per billion, µg/L).
2. Samples were collected on May 14, 2021.
3. * - Interim Maximum Allowable Concentration (IMAC)
4. ** - The Upper Tolerance Limits (UTL) were calculated as part of the East Wake Alternate Source Demonstration
and were approved by the Solid Waste Section on August 20, 2020.
5. MDL - Method Detection Limit
6. dup - Duplicate Sample
7. J - Indicates the analytical result is an estimated concentration between the method detection limit and the limit
of quantitation.
8. D - Indicates the analyte was analyzed at a dilution greater than 1.
9. Dissolved metals samples were collected to evaluate the influence of turbidity on total metal concentrations.
10. ( ) Indicates the result is below the detection limit.
Concentration exceeds the 15A NCAC 02L .0202 (North Carolina 2L), IMAC, or UTL.
CDM
Smith Page 3 of 3 June 2021

Table 5
Constituents Detected Above Standards
May 2021 Semi -Annual Sampling Event
East Wake Landfill - Area D
Permit Number 9202-MSWLF-1981
Facility Permit May 2021 Constituents Exceeding the
Code North Carolina 2L, Interim Maximum Allowable Concentration,
UpperNumber Monitoring Well
9202-MSWLF-1981 MW-01 Thallium*, Vanadium**
9202-MSWLF-1981
MW-02
Cobalt**, Lead, Thallium*, Vanadium**
9202-MSWLF-1981
MW-03
Vanadium**, 1,4-Dioxane
9202-MSWLF-1981
MW-04S
Barium, Cobalt**, Vanadium**, 1,4-Dioxane
9202-MSWLF-1981
MW-04D
Barium, Cobalt**, Vanadium**, 1,4-Dioxane
9202-MSWLF-1981
MW-07
Cadmium, Vanadium**
Notes:
1. * - Interim Maximum Allowable Concentration
2. ** - The Upper Tolerance Limits were calculated as part of the East Wake Alternate Source Demonstration approved by
the Solid Waste Section on August 20, 2020.
3. Bold - Indicates a "J" flag detection in which the analytical result is an estimated concentration between the laboratory method
detection limit and the laboratory limit of quantitation.
Smith Page 1 of 1 June 2021

91S 64 flusiness
T, M.F'r
70
MW-02
241.51
MW-03 P_
231.19
�4rea Dr'
'..*MW-04S
228.04 '
MW-04D
228.38 r
o r r ( P v� i �1
Carolyn Properties LLC
r _ J.T. Knott Pro ert
y, MW-07 j
249.24
Facility
Entrance "`QrP_a C LEGEND
Notes:
1. Groundwater elevations were measured on M1y
2. Potentiometric contours are derived from previl
and adjusted based on the recent groundwater i
Map Data Source: August 2017 Aerial Photograph,
Groundwater Monitoring Well
iii 243.52 Groundwater Elevation
Potentiometric Contour
"• 240 — Contour Interval = 10 feet
(dashed where inferred)
nvestigations _--- Property Line
s.
ounty, North Carolina OneMap.

Appendix A
Analytical Data

aceAnalytical
Report of Analysis
CDM Smith
5400 Glenwood Avenue
Suite 400
Raleigh, NC 27612
Attention: Mathew Colone
Project Name: East Wake Landfill
Lot Number:WE17049
Date Completed:06/21/2021
Revision Date: 06/15/2021
06/21/2021 11:25 PM
Approved and released by:
Project Manager II: Cathy S. Dover
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Page 1 of 67

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
CDM Smith
Lot Number: WE17049
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or
discussed below.
This PDF report has been revised in order to report the dissolved metals that were taken off -hold
for analysis. All other sample results are as reported in the original PDF report. This report
supersedes and replaces any prior reports issued under this lot number.
1,4 Dioxane SIM 8260D
Due to limited volume an LCS/LCSD was run in lieu of an MS/MSD for batch 92789 & 93359.
If you have any questions regarding this report please contact the Pace Project Manager listed on the
cover page.
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Page 2 of 67

PACE ANALYTICAL SERVICES, LLC
Sample Summary
CDM Smith
Lot Number: WE17049
Project Name: East Wake Landfill
Project Number:
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
MW-01
Aqueous
05/14/20211135
05/17/2021
002
MW-02
Aqueous
05/14/20210950
05/17/2021
003
MW-03
Aqueous
05/14/20211015
05/17/2021
004
MW-04S
Aqueous
05/14/20211045
05/17/2021
005
MW-04D
Aqueous
05/14/20211030
05/17/2021
006
MW-07
Aqueous
05/14/20211100
05/17/2021
007
DUP
Aqueous
05/14/20210800
05/17/2021
008
EQ BLANK
Aqueous
05/14/2021 1200
05/17/2021
009
TRIP BLANK
Aqueous
05/14/2021
05/17/2021
(9 samples)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 67

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WE17049-001
Description: MW-01 Matrix: Aqueous
Date Sampled:05/14/2021 1135 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 05/19/20211455 TML
92791
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
5.2
J
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 67

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WE17049-001
Description: MW-01 Matrix: Aqueous
Date Sampled:05/14/2021 1135 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 05/19/20211455 TML 92791
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
103 70-130
92 70-130
100 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 67

ICP-MS Metals
Client:CDM Smith Laboratory ID:WE17049-001
Description: MW-01 Matrix: Aqueous
Date Sampled:05/14/2021 1135 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 05/19/2021 1641 BNW
Prep Date Batch
05/19/2021 0400 92743
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
160
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
2.6
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
3.3
J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
2.4
J
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
9.0
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
2.8
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
1.3
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.20
J
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
8.5
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
25
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 67

ICP-MS
Client:CDM Smith Laboratory ID:WE17049-001
Description: MW-01 Matrix: Aqueous
Date Sampled:05/14/2021 1135 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 06/18/2021 2135 BPK 06/18/2021 0932 95956
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved Thallium 7440-28-0
Dissolved Vanadium 7440-62-2
6020B 0.50 U 0.50 0.15 ug/L 1
6020B 5.0 U 5.0 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 67

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WE17049-002
Description: MW-02 Matrix: Aqueous
Date Sampled:05/14/2021 0950 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 05/19/20211518 TML
92791
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 67

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WE17049-002
Description: MW-02 Matrix: Aqueous
Date Sampled:05/14/2021 0950 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 05/19/20211518 TML 92791
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
96 70-130
94 70-130
102 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 67

ICP-MS Metals
Client:CDM Smith Laboratory ID:WE17049-002
Description: MW-02 Matrix: Aqueous
Date Sampled:05/14/2021 0950 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 05/19/2021 1711 BNW
Prep Date Batch
05/19/2021 0400 92743
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
80
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
1.7
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
6.0
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
3.2
J
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
12
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
25
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
3.2
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.24
J
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
11
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
56
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 67

ICP-MS
Client:CDM Smith Laboratory ID:WE17049-002
Description: MW-02 Matrix: Aqueous
Date Sampled:05/14/2021 0950 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 06/18/2021 2142 BPK 06/18/2021 0932 95956
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved Cobalt
Dissolved Thallium
Dissolved Vanadium
7440-48-4 6020B 5.0 U 5.0 1.3 ug/L 1
7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1
7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 67

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WE17049-003
Description: MW-03 Matrix: Aqueous
Date Sampled:05/14/2021 1015 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 05/19/20211540 TML
92791
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
7.1
J
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
3.5
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.84
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 12 of 67

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WE17049-003
Description: MW-03 Matrix: Aqueous
Date Sampled:05/14/2021 1015 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 05/19/20211540 TML 92791
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
97 70-130
90 70-130
99 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 13 of 67

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:WE17049-003
Description: MW-03 Matrix: Aqueous
Date Sampled:05/14/2021 1015 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 05/19/2021 1520 JM1 92789
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 14 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
108 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 14 of 67

ICP-MS Metals
Client:CDM Smith Laboratory ID:WE17049-003
Description: MW-03 Matrix: Aqueous
Date Sampled:05/14/2021 1015 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 05/19/2021 1716 BNW
Prep Date Batch
05/19/2021 0400 92743
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
390
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.28
J
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
3.5
J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
1.5
J
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
24
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
8.0
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
6.4
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
4.9
J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
14
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 15 of 67

ICP-MS
Client:CDM Smith Laboratory ID:WE17049-003
Description: MW-03 Matrix: Aqueous
Date Sampled:05/14/2021 1015 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 06/18/2021 2149 BPK 06/18/2021 0932 95956
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved Vanadium
7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 16 of 67

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WE17049-004
Description: MW-04S Matrix: Aqueous
Date Sampled:05/14/2021 1045 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 05/19/20211603 TML
92791
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
11
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.71
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
7.0
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
1.5
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.59
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 17 of 67

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WE17049-004
Description: MW-04S Matrix: Aqueous
Date Sampled:05/14/2021 1045 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 05/19/20211603 TML 92791
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
99 70-130
92 70-130
100 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 18 of 67

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:WE17049-004
Description: MW-04S Matrix: Aqueous
Date Sampled:05/14/2021 1045 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 05/19/2021 1544 JM1 92789
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 42 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
111 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 19 of 67

ICP-MS Metals
Client:CDM Smith Laboratory ID:WE17049-004
Description: MW-04S Matrix: Aqueous
Date Sampled:05/14/2021 1045 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 05/19/2021 1722 BNW
Prep Date Batch
05/19/2021 0400 92743
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
1.6
J
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
930
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.31
J
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.26
J
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
32
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
21
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.8
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
18
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
3.5
J
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.16
J
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
3.9
J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
16
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 20 of 67

ICP-MS
Client:CDM Smith Laboratory ID:WE17049-004
Description: MW-04S Matrix: Aqueous
Date Sampled:05/14/2021 1045 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 06/18/2021 2157 BPK 06/18/2021 0932 95956
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved Cobalt 7440-48-4
Dissolved Vanadium 7440-62-2
6020B 29 5.0 1.3 ug/L 1
6020B 5.0 U 5.0 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 21 of 67

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WE17049-005
Description: MW-04D Matrix: Aqueous
Date Sampled:05/14/2021 1030 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 05/19/20211445
BWS
92788
2 5030B 8260D
1 05/21/20210052 CJL2
93004
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
10
4.0
ug/L
2
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
3.1
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.80
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 22 of 67

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WE17049-005
Description: MW-04D Matrix: Aqueous
Date Sampled:05/14/2021 1030 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run
Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1
5030B
8260D
1 05/19/20211445 BWS
92788
2
5030B
8260D
1 05/21/20210052 CJL2
93004
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Run 2
Acceptance
Surrogate
Q % Recovery Limits
Q % Recovery
Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
100 70-130 98 70-130
109 70-130 108 70-130
106 70-130 107 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 23 of 67

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:WE17049-005
Description: MW-04D Matrix: Aqueous
Date Sampled:05/14/2021 1030 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 05/19/2021 1609 JM1 92789
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 21 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
111 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 24 of 67

ICP-MS Metals
Client:CDM Smith Laboratory ID:WE17049-005
Description: MW-04D Matrix: Aqueous
Date Sampled:05/14/2021 1030 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 05/19/2021 1740 BNW
Prep Date Batch
05/19/2021 0400 92743
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
0.64
J
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
3.1
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
1100
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
2.5
J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
22
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
16
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
2.7
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
16
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
3.2
J
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
7.5
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
20
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 25 of 67

ICP-MS
Client:CDM Smith Laboratory ID:WE17049-005
Description: MW-04D Matrix: Aqueous
Date Sampled:05/14/2021 1030 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run
Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
3005A
6020B
1
06/18/2021 2204 BPK
06/18/2021 0932 95956
2
3005A
6020B
10
06/21/2021 1400 BPK
06/18/2021 0932 95956
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved Barium
Dissolved Cobalt
Dissolved Vanadium
7440-39-3 6020B 650 D 50 13 ug/L 2
7440-48-4 6020B 18 5.0 1.3 ug/L 1
7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 26 of 67

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WE17049-006
Description: MW-07 Matrix: Aqueous
Date Sampled:05/14/2021 1100 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 05/19/20211510 BWS
92788
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
4.4
J
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 27 of 67

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WE17049-006
Description: MW-07 Matrix: Aqueous
Date Sampled:05/14/2021 1100 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 05/19/20211510 BWS 92788
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
97 70-130
109 70-130
108 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 28 of 67

ICP-MS Metals
Client:CDM Smith Laboratory ID:WE17049-006
Description: MW-07 Matrix: Aqueous
Date Sampled:05/14/2021 1100 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 05/19/2021 1746 BNW
Prep Date Batch
05/19/2021 0400 92743
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
100
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
1.1
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
9.4
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
3.1
J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
1.8
J
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.5
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
2.6
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
2.0
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
3.6
J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
250
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 29 of 67

ICP-MS
Client:CDM Smith Laboratory ID:WE17049-006
Description: MW-07 Matrix: Aqueous
Date Sampled:05/14/2021 1100 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 06/18/2021 2211 BPK 06/18/2021 0932 95956
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved Cadmium 7440-43-9
Dissolved Vanadium 7440-62-2
6020B 2.4 0.50 0.13 ug/L 1
6020B 5.0 U 5.0 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 30 of 67

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WE17049-007
Description: DUP Matrix: Aqueous
Date Sampled:05/14/2021 0800 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 05/19/20211535 BWS
92788
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
4.7
J
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 31 of 67

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WE17049-007
Description: DUP Matrix: Aqueous
Date Sampled:05/14/2021 0800 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 05/19/20211535 BWS 92788
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
100 70-130
108 70-130
110 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 32 of 67

ICP-MS Metals
Client:CDM Smith Laboratory ID:WE17049-007
Description: DUP Matrix: Aqueous
Date Sampled:05/14/2021 0800 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 05/19/2021 1752 BNW
Prep Date Batch
05/19/2021 0400 92743
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
91
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
1.1
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
6.0
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
2.9
J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
1.7
J
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
3.6
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.9
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
1.6
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
2.9
J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
160
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 33 of 67

ICP-MS
Client:CDM Smith Laboratory ID:WE17049-007
Description: DUP Matrix: Aqueous
Date Sampled:05/14/2021 0800 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 06/18/2021 2219 BPK 06/18/2021 0932 95956
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved Vanadium
7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 34 of 67

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WE17049-008
Description: EQ BLANK Matrix: Aqueous
Date Sampled:05/14/2021 1200 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 05/19/20211215 BWS
92788
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 35 of 67

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WE17049-008
Description: EQ BLANK Matrix: Aqueous
Date Sampled:05/14/2021 1200 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 05/19/20211215 BWS 92788
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
102 70-130
110 70-130
106 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 36 of 67

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:WE17049-008
Description: EQ BLANK Matrix: Aqueous
Date Sampled:05/14/2021 1200 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 05/19/2021 1634 JM1 92789
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
112 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 37 of 67

ICP-MS Metals
Client:CDM Smith Laboratory ID:WE17049-008
Description: EQ BLANK Matrix: Aqueous
Date Sampled:05/14/2021 1200 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 05/19/2021 1757 BNW
Prep Date Batch
05/19/2021 0400 92743
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
5.0
U
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0
U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10
U
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 38 of 67

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WE17049-009
Description: TRIP BLANK Matrix: Aqueous
Date Sampled:05/14/2021 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 05/19/20211241 BWS
92788
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 39 of 67

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WE17049-009
Description: TRIP BLANK Matrix: Aqueous
Date Sampled:05/14/2021 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 05/19/20211241 BWS 92788
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
99 70-130
111 70-130
107 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 40 of 67

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:WE17049-009
Description: TRIP BLANK Matrix: Aqueous
Date Sampled:05/14/2021 Project Name: East Wake Landfill
Date Received:05/17/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 05/25/2021 1258 JM1 93359
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
105 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 41 of 67

QC Summary
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WE17049
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 42 of 67

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ92788-001 Matrix: Aqueous
Batch: 92788 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
10
U
1
10
4.0
ug/L
05/19/2021 0959
Acrylonitrile
5.0
U
1
5.0
0.80
ug/L
05/19/2021 0959
Benzene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
Bromochloromethane
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
Bromodichloromethane
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
Bromoform
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
Bromomethane (Methyl bromide)
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
2-Butanone (MEK)
10
U
1
10
2.0
ug/L
05/19/2021 0959
Carbon disulfide
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
Carbon tetrachloride
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
Chlorobenzene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
Chloroethane
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
Chloroform
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
Chloromethane (Methyl chloride)
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
1,2-Dibromo-3-chloropropane (DBCP)
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
Dibromochloromethane
0.50
u
1
0.50
0.40
ug/L
05/19/2021 0959
1,2-Dibromoethane (EDB)
0.50
u
1
0.50
0.40
ug/L
05/19/2021 0959
Dibromomethane (Methylene bromide)
0.50
u
1
0.50
0.40
ug/L
05/19/2021 0959
trans- 1,4-Dichloro-2-butene
2.0
u
1
2.0
0.40
ug/L
05/19/2021 0959
1,2-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
05/19/2021 0959
1,4-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
05/19/2021 0959
1,1-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
05/19/2021 0959
1,2-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
05/19/2021 0959
1,1-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
cis- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
trans- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
1,2-Dichloropropane
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
1,3-Dichloropropane
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
cis- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
trans- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
Ethylbenzene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
2-Hexanone
10
U
1
10
2.0
ug/L
05/19/2021 0959
Methyl iodide (lodomethane)
5.0
U
1
5.0
0.40
ug/L
05/19/2021 0959
4-Methyl-2-pentanone
10
U
1
10
2.0
ug/L
05/19/2021 0959
Methylene chloride
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
Styrene
0.50
U
1
0.50
0.41
ug/L
05/19/2021 0959
1,1,1,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
1,1,2,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
Tetrachloroethene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
Toluene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
1,1,1-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
1,1,2-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
Trichloroethene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
Trichlorofluoromethane
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 43 of 67
QC Data for Lot Number: WE17049

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ92788-001 Matrix: Aqueous
Batch: 92788 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
1,2,3-Trichloropropane
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
1,2,4-Trimethylbenzene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
1,3,5-Trimethylbenzene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
Vinyl acetate
5.0
U
1
5.0
1.2
ug/L
05/19/2021 0959
Vinyl chloride
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0959
Xylenes (total)
1.0
U
1
1.0
0.40
ug/L
05/19/2021 0959
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 101 70-130
1,2-Dichloroethane-d4 105 70-130
Toluene-d8 107 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WE17049
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 44 of 67

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ92788-002 Matrix: Aqueous
Batch: 92788 Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Acetone
100
140
1
137
60-140
05/19/2021 0858
Acrylonitrile
100
110
1
106
70-130
05/19/2021 0858
Benzene
50
52
1
103
70-130
05/19/2021 0858
Bromochloromethane
50
52
1
103
70-130
05/19/2021 0858
Bromodichloromethane
50
51
1
103
70-130
05/19/2021 0858
Bromoform
50
48
1
96
70-130
05/19/2021 0858
Bromomethane (Methyl bromide)
50
57
1
114
70-130
05/19/2021 0858
2-Butanone (MEK)
100
120
1
121
70-130
05/19/2021 0858
Carbon disulfide
50
56
1
111
70-130
05/19/2021 0858
Carbon tetrachloride
50
51
1
103
70-130
05/19/2021 0858
Chlorobenzene
50
51
1
102
70-130
05/19/2021 0858
Chloroethane
50
53
1
105
70-130
05/19/2021 0858
Chloroform
50
50
1
100
70-130
05/19/2021 0858
Chloromethane (Methyl chloride)
50
58
1
115
60-140
05/19/2021 0858
1,2-Dibromo-3-chloropropane (DBCP)
50
48
1
97
70-130
05/19/2021 0858
Dibromochloromethane
50
50
1
101
70-130
05/19/2021 0858
1,2-Dibromoethane (EDB)
50
52
1
104
70-130
05/19/2021 0858
Dibromomethane (Methylene bromide)
50
50
1
100
70-130
05/19/2021 0858
trans- 1,4-Dichloro-2-butene
50
49
1
97
70-130
05/19/2021 0858
1,2-Dichlorobenzene
50
53
1
106
70-130
05/19/2021 0858
1,4-Dichlorobenzene
50
51
1
102
70-130
05/19/2021 0858
1,1-Dichloroethane
50
50
1
100
70-130
05/19/2021 0858
1,2-Dichloroethane
50
47
1
93
70-130
05/19/2021 0858
1,1-Dichloroethene
50
56
1
111
70-130
05/19/2021 0858
cis- 1,2-Dichloroethene
50
49
1
98
70-130
05/19/2021 0858
trans- 1,2-Dichloroethene
50
54
1
108
70-130
05/19/2021 0858
1,2-Dichloropropane
50
49
1
97
70-130
05/19/2021 0858
1,3-Dichloropropane
50
49
1
98
70-130
05/19/2021 0858
cis- 1,3-Dichloropropene
50
54
1
109
70-130
05/19/2021 0858
trans- 1,3-Dichloropropene
50
47
1
94
70-130
05/19/2021 0858
Ethylbenzene
50
53
1
106
70-130
05/19/2021 0858
2-Hexanone
100
100
1
104
70-130
05/19/2021 0858
Methyl iodide (lodomethane)
50
56
1
112
70-130
05/19/2021 0858
4-Methyl-2-pentanone
100
110
1
108
70-130
05/19/2021 0858
Methylene chloride
50
51
1
102
70-130
05/19/2021 0858
Styrene
50
57
1
115
70-130
05/19/2021 0858
1,1,1,2-Tetrachloroethane
50
56
1
112
70-130
05/19/2021 0858
1,1,2,2-Tetrachloroethane
50
54
1
108
70-130
05/19/2021 0858
Tetrachloroethene
50
51
1
103
70-130
05/19/2021 0858
Toluene
50
51
1
103
70-130
05/19/2021 0858
1,1,1-Trichloroethane
50
54
1
108
70-130
05/19/2021 0858
1,1,2-Trichloroethane
50
53
1
107
70-130
05/19/2021 0858
Trichloroethene
50
48
1
95
70-130
05/19/2021 0858
Trichlorofluoromethane
50
52
1
104
70-130
05/19/2021 0858
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 45 of 67
QC Data for Lot Number: WE17049

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ92788-002
Matrix: Aqueous
Batch: 92788
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil
% Rec
Limit
Analysis Date
1,2,3-Trichloropropane
50
49
1
97
70-130
05/19/2021 0858
1,2,4-Trimethylbenzene
50
57
1
113
70-130
05/19/2021 0858
1,3,5-Trimethylbenzene
50
57
1
114
70-130
05/19/2021 0858
Vinyl acetate
50
49
1
99
60-140
05/19/2021 0858
Vinyl chloride
50
58
1
115
70-130
05/19/2021 0858
Xylenes (total)
100
110
1
108
70-130
05/19/2021 0858
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 100 70-130
1,2-Dichloroethane-d4 99 70-130
Toluene-d8 102 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WE17049
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 46 of 67

Volatile Organic Compounds by GC/MS (SIM) - MB
Sample ID: WQ92789-001 Matrix: Aqueous
Batch: 92789 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Parameter Result Q Dil LOQ DL Units Analysis Date
1,4-Dioxane 3.0 U 1 3.0 1.0 ug/L 05/19/2021 1008
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
99 40-170
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 47 of 67
QC Data for Lot Number: WE17049

Volatile Organic Compounds by GC/MS (SIM) - LCS
Sample ID: WQ92789-002 Matrix: Aqueous
Batch: 92789 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
1,4-Dioxane 50 45 1 91 70-130 05/19/2021 0919
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
100 40-170
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 48 of 67
QC Data for Lot Number: WE17049

Volatile Organic Compounds by GC/MS (SIM) - LCSD
Sample ID: WQ92789-003 Matrix: Aqueous
Batch: 92789 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Spike
Amount Result %Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
1,4-Dioxane 50 47 1 93 3.1 70-130 20 05/19/2021 0943
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
102 40-170
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 49 of 67
QC Data for Lot Number: WE17049

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ92791-001 Matrix: Aqueous
Batch: 92791 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
10
U
1
10
4.0
ug/L
05/19/2021 0944
Acrylonitrile
5.0
U
1
5.0
0.80
ug/L
05/19/2021 0944
Benzene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
Bromochloromethane
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
Bromodichloromethane
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
Bromoform
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
Bromomethane (Methyl bromide)
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
2-Butanone (MEK)
10
U
1
10
2.0
ug/L
05/19/2021 0944
Carbon disulfide
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
Carbon tetrachloride
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
Chlorobenzene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
Chloroethane
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
Chloroform
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
Chloromethane (Methyl chloride)
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
1,2-Dibromo-3-chloropropane (DBCP)
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
Dibromochloromethane
0.50
u
1
0.50
0.40
ug/L
05/19/2021 0944
1,2-Dibromoethane (EDB)
0.50
u
1
0.50
0.40
ug/L
05/19/2021 0944
Dibromomethane (Methylene bromide)
0.50
u
1
0.50
0.40
ug/L
05/19/2021 0944
trans- 1,4-Dichloro-2-butene
2.0
u
1
2.0
0.40
ug/L
05/19/2021 0944
1,2-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
05/19/2021 0944
1,4-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
05/19/2021 0944
1,1-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
05/19/2021 0944
1,2-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
05/19/2021 0944
1,1-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
cis- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
trans- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
1,2-Dichloropropane
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
1,3-Dichloropropane
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
cis- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
trans- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
Ethylbenzene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
2-Hexanone
10
U
1
10
2.0
ug/L
05/19/2021 0944
Methyl iodide (lodomethane)
5.0
U
1
5.0
0.40
ug/L
05/19/2021 0944
4-Methyl-2-pentanone
10
U
1
10
2.0
ug/L
05/19/2021 0944
Methylene chloride
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
Styrene
0.50
U
1
0.50
0.41
ug/L
05/19/2021 0944
1,1,1,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
1,1,2,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
Tetrachloroethene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
Toluene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
1,1,1-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
1,1,2-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
Trichloroethene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
Trichlorofluoromethane
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 50 of 67
QC Data for Lot Number: WE17049

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ92791-001 Matrix: Aqueous
Batch: 92791 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
1,2,3-Trichloropropane
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
1,2,4-Trimethylbenzene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
1,3,5-Trimethylbenzene
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
Vinyl acetate
5.0
U
1
5.0
1.2
ug/L
05/19/2021 0944
Vinyl chloride
0.50
U
1
0.50
0.40
ug/L
05/19/2021 0944
Xylenes (total)
1.0
U
1
1.0
0.40
ug/L
05/19/2021 0944
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 98 70-130
1,2-Dichloroethane-d4 93 70-130
Toluene-d8 97 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WE17049
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 51 of 67

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ92791-002 Matrix: Aqueous
Batch: 92791 Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Acetone
100
110
1
111
60-140
05/19/2021 0816
Acrylonitrile
100
97
1
97
70-130
05/19/2021 0816
Benzene
50
51
1
101
70-130
05/19/2021 0816
Bromochloromethane
50
45
1
89
70-130
05/19/2021 0816
Bromodichloromethane
50
46
1
92
70-130
05/19/2021 0816
Bromoform
50
50
1
100
70-130
05/19/2021 0816
Bromomethane (Methyl bromide)
50
45
1
90
70-130
05/19/2021 0816
2-Butanone (MEK)
100
100
1
102
70-130
05/19/2021 0816
Carbon disulfide
50
54
1
108
70-130
05/19/2021 0816
Carbon tetrachloride
50
48
1
95
70-130
05/19/2021 0816
Chlorobenzene
50
51
1
101
70-130
05/19/2021 0816
Chloroethane
50
46
1
91
70-130
05/19/2021 0816
Chloroform
50
45
1
90
70-130
05/19/2021 0816
Chloromethane (Methyl chloride)
50
45
1
89
60-140
05/19/2021 0816
1,2-Dibromo-3-chloropropane (DBCP)
50
47
1
93
70-130
05/19/2021 0816
Dibromochloromethane
50
46
1
93
70-130
05/19/2021 0816
1,2-Dibromoethane (EDB)
50
50
1
100
70-130
05/19/2021 0816
Dibromomethane (Methylene bromide)
50
46
1
91
70-130
05/19/2021 0816
trans- 1,4-Dichloro-2-butene
50
39
1
78
70-130
05/19/2021 0816
1,2-Dichlorobenzene
50
54
1
109
70-130
05/19/2021 0816
1,4-Dichlorobenzene
50
52
1
105
70-130
05/19/2021 0816
1,1-Dichloroethane
50
47
1
94
70-130
05/19/2021 0816
1,2-Dichloroethane
50
42
1
83
70-130
05/19/2021 0816
1,1-Dichloroethene
50
50
1
100
70-130
05/19/2021 0816
cis- 1,2-Dichloroethene
50
48
1
97
70-130
05/19/2021 0816
trans- 1,2-Dichloroethene
50
51
1
102
70-130
05/19/2021 0816
1,2-Dichloropropane
50
47
1
94
70-130
05/19/2021 0816
1,3-Dichloropropane
50
48
1
95
70-130
05/19/2021 0816
cis- 1,3-Dichloropropene
50
49
1
98
70-130
05/19/2021 0816
trans- 1,3-Dichloropropene
50
50
1
99
70-130
05/19/2021 0816
Ethylbenzene
50
53
1
106
70-130
05/19/2021 0816
2-Hexanone
100
96
1
96
70-130
05/19/2021 0816
Methyl iodide (lodomethane)
50
49
1
98
70-130
05/19/2021 0816
4-Methyl-2-pentanone
100
97
1
97
70-130
05/19/2021 0816
Methylene chloride
50
45
1
89
70-130
05/19/2021 0816
Styrene
50
53
1
106
70-130
05/19/2021 0816
1,1,1,2-Tetrachloroethane
50
52
1
104
70-130
05/19/2021 0816
1,1,2,2-Tetrachloroethane
50
54
1
107
70-130
05/19/2021 0816
Tetrachloroethene
50
48
1
97
70-130
05/19/2021 0816
Toluene
50
52
1
104
70-130
05/19/2021 0816
1,1,1-Trichloroethane
50
47
1
95
70-130
05/19/2021 0816
1,1,2-Trichloroethane
50
49
1
99
70-130
05/19/2021 0816
Trichloroethene
50
45
1
91
70-130
05/19/2021 0816
Trichlorofluoromethane
50
43
1
87
70-130
05/19/2021 0816
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 52 of 67
QC Data for Lot Number: WE17049

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ92791-002
Matrix: Aqueous
Batch: 92791
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil
% Rec
Limit
Analysis Date
1,2,3-Trichloropropane
50
44
1
88
70-130
05/19/2021 0816
1,2,4-Trimethylbenzene
50
55
1
110
70-130
05/19/2021 0816
1,3,5-Trimethylbenzene
50
57
1
113
70-130
05/19/2021 0816
Vinyl acetate
50
46
1
92
60-140
05/19/2021 0816
Vinyl chloride
50
44
1
88
70-130
05/19/2021 0816
Xylenes (total)
100
110
1
105
70-130
05/19/2021 0816
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 96 70-130
1,2-Dichloroethane-d4 82 70-130
Toluene-d8 95 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WE17049
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 53 of 67

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ93004-001 Matrix: Aqueous
Batch: 93004 Prep Method: 5030E
Analytical Method: 8260D
Parameter Result Q Dil LOQ DL Units Analysis Date
Acetone 10 U 1 10 4.0 ug/L 05/20/2021 2056
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 99 70-130
1,2-Dichloroethane-d4 105 70-130
Toluene-d8 108 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WE17049
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 54 of 67

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ93004-002
Matrix: Aqueous
Batch: 93004
Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec Limit Analysis Date
Acetone
100
120
1 120 60-140 05/20/2021 1852
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 101 70-130
1,2-Dichloroethane-d4 101 70-130
Toluene-d8 104 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WE17049
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 55 of 67

Volatile Organic Compounds by GC/MS (SIM) - MB
Sample ID: WQ93359-001 Matrix: Aqueous
Batch: 93359 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Parameter Result Q Dil LOQ DL Units Analysis Date
1,4-Dioxane 3.0 U 1 3.0 1.0 ug/L 05/25/2021 1030
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
110 40-170
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 56 of 67
QC Data for Lot Number: WE17049

Volatile Organic Compounds by GC/MS (SIM) - LCS
Sample ID: WQ93359-002 Matrix: Aqueous
Batch: 93359 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
1,4-Dioxane 50 44 1 88 70-130 05/25/2021 0941
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
100 40-170
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 57 of 67
QC Data for Lot Number: WE17049

Volatile Organic Compounds by GC/MS (SIM) - LCSD
Sample ID: WQ93359-003 Matrix: Aqueous
Batch: 93359 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Spike
Amount Result %Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
1,4-Dioxane 50 44 1 89 0.64 70-130 20 05/25/2021 1005
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
97 40-170
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 58 of 67
QC Data for Lot Number: WE17049

ICP-MS Metals - MB
Sample ID: WQ92743-001 Matrix: Aqueous
Batch: 92743 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 05/19/2021 0400
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Antimony
2.0
U
1
2.0
0.50
ug/L
05/19/2021 1630
Arsenic
2.0
U
1
2.0
1.3
ug/L
05/19/2021 1630
Barium
5.0
U
1
5.0
1.3
ug/L
05/19/2021 1630
Beryllium
0.40
U
1
0.40
0.15
ug/L
05/19/2021 1630
Cadmium
0.50
U
1
0.50
0.13
ug/L
05/19/2021 1630
Chromium
5.0
U
1
5.0
1.3
ug/L
05/19/2021 1630
Cobalt
5.0
U
1
5.0
1.3
ug/L
05/19/2021 1630
Copper
5.0
U
1
5.0
1.3
ug/L
05/19/2021 1630
Lead
1.0
U
1
1.0
0.25
ug/L
05/19/2021 1630
Nickel
5.0
U
1
5.0
1.3
ug/L
05/19/2021 1630
Selenium
5.0
U
1
5.0
1.3
ug/L
05/19/2021 1630
Silver
1.0
U
1
1.0
0.25
ug/L
05/19/2021 1630
Thallium
0.50
U
1
0.50
0.15
ug/L
05/19/2021 1630
Vanadium
5.0
U
1
5.0
2.5
ug/L
05/19/2021 1630
Zinc
10
U
1
10
2.5
ug/L
05/19/2021 1630
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 59 of 67
QC Data for Lot Number: WE17049

ICP-MS Metals - LCS
Sample ID: WQ92743-002 Matrix: Aqueous
Batch: 92743 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 05/19/2021 0400
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Antimony
100
96
1
96
80-120
05/19/2021 1636
Arsenic
100
100
1
100
80-120
05/19/2021 1636
Barium
100
98
1
98
80-120
05/19/2021 1636
Beryllium
100
110
1
108
80-120
05/19/2021 1636
Cadmium
100
97
1
97
80-120
05/19/2021 1636
Chromium
100
99
1
99
80-120
05/19/2021 1636
Cobalt
100
97
1
97
80-120
05/19/2021 1636
Copper
100
98
1
98
80-120
05/19/2021 1636
Lead
100
100
1
104
80-120
05/19/2021 1636
Nickel
100
100
1
102
80-120
05/19/2021 1636
Selenium
100
93
1
93
80-120
05/19/2021 1636
Silver
100
98
1
98
80-120
05/19/2021 1636
Thallium
100
100
1
103
80-120
05/19/2021 1636
Vanadium
100
97
1
97
80-120
05/19/2021 1636
Zinc
100
92
1
92
80-120
05/19/2021 1636
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 60 of 67
QC Data for Lot Number: WE17049

ICP-MS Metals - MS
Sample ID: WE1 7049-001 MS
Matrix: Aqueous
Batch: 92743
Prep Method:
3005A
Analytical Method: 6020B
Prep Date:
05/19/2021
0400
Sample
Spike
Amount
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
(ug/L)
Q
Dil
% Rec
Limit
Analysis Date
Antimony
0.0
100
100
1
100
75-125
05/19/2021 1647
Arsenic
0.0
100
100
1
100
75-125
05/19/2021 1647
Barium
160
100
270
1
110
75-125
05/19/2021 1647
Beryllium
2.6
100
110
1
104
75-125
05/19/2021 1647
Cadmium
0.0
100
100
1
100
75-125
05/19/2021 1647
Chromium
3.3
100
100
1
97
75-125
05/19/2021 1647
Cobalt
2.4
100
99
1
97
75-125
05/19/2021 1647
Copper
9.0
100
120
1
107
75-125
05/19/2021 1647
Lead
2.8
100
110
1
102
75-125
05/19/2021 1647
Nickel
1.3
100
99
1
98
75-125
05/19/2021 1647
Selenium
0.0
100
98
1
98
75-125
05/19/2021 1647
Silver
0.0
100
100
1
100
75-125
05/19/2021 1647
Thallium
0.20
100
100
1
101
75-125
05/19/2021 1647
Vanadium
8.5
100
110
1
98
75-125
05/19/2021 1647
Zinc
25
100
130
1
102
75-125
05/19/2021 1647
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 61 of 67
QC Data for Lot Number: WE17049

ICP-MS Metals - MSD
Sample ID: WE17049-001MID
Matrix: Aqueous
Batch: 92743
Prep Method:
3005A
Analytical Method: 6020B
Prep Date:
05/19/2021 0400
Sample
Spike
Amount
Amount
Result
%Rec
% RPD
Parameter
(ug/L)
(ug/L)
(ug/L)
Q Dil
% Rec % RPD
Limit
Limit
Analysis Date
Antimony
0.0
100
99
1
99
0.83
75-125
20
05/19/2021 1653
Arsenic
0.0
100
100
1
101
0.40
75-125
20
05/19/2021 1653
Barium
160
100
270
1
108
0.71
75-125
20
05/19/2021 1653
Beryllium
2.6
100
110
1
110
4.9
75-125
20
05/19/2021 1653
Cadmium
0.0
100
100
1
101
0.20
75-125
20
05/19/2021 1653
Chromium
3.3
100
100
1
99
1.9
75-125
20
05/19/2021 1653
Cobalt
2.4
100
100
1
98
0.65
75-125
20
05/19/2021 1653
Copper
9.0
100
110
1
105
1.3
75-125
20
05/19/2021 1653
Lead
2.8
100
100
1
101
1.5
75-125
20
05/19/2021 1653
Nickel
1.3
100
100
1
99
1.5
75-125
20
05/19/2021 1653
Selenium
0.0
100
100
1
103
5.4
75-125
20
05/19/2021 1653
Silver
0.0
100
99
1
99
1.5
75-125
20
05/19/2021 1653
Thallium
0.20
100
98
1
97
3.7
75-125
20
05/19/2021 1653
Vanadium
8.5
100
110
1
99
1.2
75-125
20
05/19/2021 1653
Zinc
25
100
130
1
102
0.24
75-125
20
05/19/2021 1653
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 62 of 67
QC Data for Lot Number: WE17049

ICP-MS - MB
Sample ID: WQ95956-001 Matrix: Aqueous
Batch: 95956 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 06/18/2021 0932
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Dissolved Barium
5.0
U
1
5.0
1.3
ug/L
06/18/2021 2120
Dissolved Cadmium
0.50
U
1
0.50
0.13
ug/L
06/18/2021 2120
Dissolved Cobalt
5.0
U
1
5.0
1.3
ug/L
06/18/2021 2120
Dissolved Thallium
0.50
U
1
0.50
0.15
ug/L
06/18/2021 2120
Dissolved Vanadium
5.0
U
1
5.0
2.5
ug/L
06/18/2021 2120
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 63 of 67
QC Data for Lot Number: WE17049

ICP-MS - LCS
Sample ID: WQ95956-002 Matrix: Aqueous
Batch: 95956 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 06/18/2021 0932
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Dissolved Barium
100
97
1
97
80-120
06/18/2021 2127
Dissolved Cadmium
100
94
1
94
80-120
06/18/2021 2127
Dissolved Cobalt
100
99
1
99
80-120
06/18/2021 2127
Dissolved Thallium
100
100
1
105
80-120
06/18/2021 2127
Dissolved Vanadium
100
99
1
99
80-120
06/18/2021 2127
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 64 of 67
QC Data for Lot Number: WE17049

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 65 of 67

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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 66 of 67

PACE ANALYTICAL SERVICES, LLC
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C;ommenr�,
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 67 of 67