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HomeMy WebLinkAbout14044_Biller Property_PH II_20150821Brownfields Phase II Site Assessment Report City of Greensboro and Greensboro Housing Authority Parcels 1005, 1015, and 1201 South Eugene Street Greensboro, North Carolina Prepared by: Hart & Hickman, PC Prepared for: Piedmont Triad Regional Council Kernersville, North Carolina Agreement Number: BF-OOD12113-0 H&H Job No. PTR-001 August 21, 2015 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS 2923 South Tryon Street, Suite 100 3334 Hillsborough Street Charlotte, NC 28203 Raleigh, NC 27607 www.harthickman.com 704.586.0007 main 919.847.4241 main Brownfields Phase II Site Assessment Report 4005,1015 & 1204 S. Eugene St. Greensboro, North Carolina Table of Contents 1.0 Introduction and Background........................................................................................................1 2.0 General Summary of Phase II Assessment Activities.................................................................6 3.0 Soil Assessment.................................................................................................................................7 3.1 Soil Sampling Methods........................................................................................................... 7 3.2 Quality Control (QC) Soil Sample Collection....................................................................... 8 3.3 Soil Assessment Results......................................................................................................... 9 4.0 Groundwater Assessment.............................................................................................................11 4.1 Temporary Monitoring Well Construction...........................................................................11 4.2 Groundwater Occurrence.......................................................................................................11 4.3 Low Flow Well Purging and Sampling Methods.................................................................12 4.4 Ground Water Sampling........................................................................................................12 4.5 QC Ground Water Sample Collection..................................................................................12 4.6 Groundwater Analytical Results...........................................................................................13 5.0 Asbestos and Lead -Based Paint Survey......................................................................................16 5.1 Asbestos Survey....................................................................................................................16 5.2 Lead -Based Paint Survey......................................................................................................17 6.0 Data Review, Verification, and Validation................................................................................18 7.0 Data Evaluation Summary and Conclusions............................................................................20 S:\AAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Phase 11 Assessment\Reporffinal Greensboro Phase II Report.docx hart L _ `h ickman SMAMR ENV_I RONM ENrAL SOLLMONS T Ic+ of r�bjl c Table 1 Summary of Soil Analytical Data Table 2 Temporary Monitoring Well Construction Summary Table 3 Summary of Groundwater Analytical Data List of Figures Figure 1 Site Location Map Figure 2A/2B Site Map Figure 3A/3B Sample Location Map Figure 4A/4B Groundwater Elevation Map List of Appendices Appendix A Boring Logs and Well Construction Diagrams Appendix B Laboratory Analytical Data Appendix C Groundwater Sampling Records Appendix D ACM and Lead -Based Paint Survey Reports ii 44 SAAAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Phase II Assessment\Report\Einal Greensboro Phase II Report.docx hart � h i ek ma n SMARTER ENVIRONMENTAL SOLUTIONS Brownfields Phase II Site Assessment Report 1005,1015 & 1201 S. Eugene St. Greensboro, North Carolina 1.0 Introduction and Background Hart & Hickman, PC (H&H) has completed Brownfields Phase II site assessment activities at 1005, 1015, and 1201 South Eugene Street in Greensboro, Guilford County, North Carolina. The 1015, and 1201 South Eugene Street properties are owned by City of Greensboro (City) and the 1005 South Eugene Street property is owned by the Greensboro Housing Authority (GHA). It is anticipated this area will be redeveloped for mixed use including commercial, multi -family residential, and open space, potentially used as recreational. A site location map and detailed site layouts are included as Figure 1 and Figure 2A/2B, respectively. The Brownfields Phase II assessment was performed for the Piedmont Triad Regional Council (PTRC) under U.S. Environmental Protection Agency (EPA) Brownfields Assessment Grant BF-OOD 12113-0. Phase I Environmental Site Assessments (ESAs) were completed in 2014 on these properties by H&H using grant funds. These reports provide historic information and identifies the Recognized Environmental Conditions (RECs) associated with the subject property. A brief site description and summary of historic uses are provided below: Site Description The site is comprised of three parcels totaling 6.76 acres with an approximate 12,500 square foot (ft2) office/warehouse/maintenance building, loading docks, canopies, storage buildings, and parking lots located on the northern end of the property. Property Ownership The City of Greensboro and the GHA currently own the site. The GHA facilities described above were vacated in approximately 2006. Both the City of Greensboro and GHA signed access agreements allowing the Phase II Environmental Site Assessment (ESA) activities on the property. 1 44 SAAAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Phase II Assessment\Report\Einal Greensboro Phase II Report.docx hart � h i ck ma n SMARTER ENVIRONMENTAL SOLUTIONS Proposed Future Reuse/Redevelopment Plans for the Property It is anticipated this area will be redeveloped for mixed use including commercial, multi -family residential, and open space, potentially used as recreational. Historic Site Use The 1005 S. Eugene Street Property was historically occupied by a church and numerous residences since prior to the late 1800s/early 1900s. The church and residences were removed in the late 1960s, and the GHA maintenance facility was constructed in the mid- to late 1970s. The maintenance facility has been vacant since approximately 2006. The 1015 and 1201 S. Eugene Street Properties were historically occupied by numerous residences since the early 1900s. The residences were removed in the early 1970s, and multi -family apartments were constructed on the subject site. The apartment buildings were removed in 2005, and the subject site is currently vacant land. West Bragg Street, which historically ran from west to east across the central portion of the site, was closed to traffic and converted to a City of Greensboro greenway several years ago. Adjacent Prope . Uses The surrounding properties have historically been residential or commercial, with residences primarily north, south, and west of the subject site and commercial properties east of the subject site. The Pintsch Compressing Company Manufactured Gas Plant (MGP) facility was constructed on the property adjacent and east of the 1201 S. Eugene Street parcel in the early 1900s. It was removed at some point between 1925 and 1950. Several coal supply companies operated on the properties east/northeast of the subject site from the early 1900s until approximately the 1980s or 1990s. Gasoline stations and automotive repair facilities have been located north/northwest of the subject site since the 1920s to 1930s. Many of the residences surrounding the subject site were removed and the GHA facility constructed north of the subject site by the mid-1970s. Known or Likely Chemicals/Contaminants of Concern H&H reviewed previous Phase I ESAs and other assessment reports for the site and identified the following areas of concern: 2 44 SAAAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Phase II Assessment\Report\Final Greensboro Phase II Report.docx hart � h i ck ma n SMARTER ENVIRONMENTAL SOLUTIONS • The former South Eugene Cleaners dry-cleaning facility located approximately 200 ft north and topographically upgradient of the 1005 S. Eugene Street parcel. During investigations by another party at the former dry cleaner property in August 2004, tetrachloroethylene (PCE) was identified in groundwater at a concentration of 53.2 micrograms per liter (µg/L), which is above the North Carolina Administrative Code (NCAC) 2L Groundwater Quality Standard (2L Standard) of 0.7 µg/L. Additional assessment work conducted in January 2005, including the installation and sampling of three temporary groundwater monitoring wells, identified elevated PCE concentrations (10.2 µg/L and 177 µg/L) in groundwater. The groundwater flow direction at the dry cleaner property was determined to be southerly toward the subject site. It does not appear additional assessment or remediation work has been conducted at the dry cleaner property since 2005. • A sump is located within each of the two bays of the paint/storage building on the GHA- owned portion of the subject site. Site contacts did not believe painting activities had ever been conducted in the building, and that the building had only been used for general storage (i.e., no chemical storage). Several inches of water were observed in the sumps during Phase I ESA activities. It is unknown if the sumps had ever been pumped out. • Gas stations located adjacent to the west and northwest of the subject site historically exhibited the presence of light non -aqueous phase liquid (LNAPL, i.e. free product). Elevated groundwater concentrations of methyl tert-butyl ether (MTBE) have been detected at the west adjacent facility; however, the release incident was closed in December 2005. The northwest adjacent facility incident is still open. The groundwater flow direction is toward the subject site, creating the potential for petroleum -related VOC impacts to the subject site. • The Pintsch Compressing Company MGP facility is located adjacent, east, and topographically cross -gradient to downgradient of the subject site. Four I0,000-gallon coal tar underground storage tanks (USTs) were identified and removed from the property in early 2011. Three of the USTs were located on the eastern portion of the property and one UST was located on the northwestern portion of the property. It appears some or all of the 3 44 SAAAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Phase II Assessment\Report\Einal Greensboro Phase II Report.docx hart � h i ck ma n SMARTER ENVIRONMENTAL SOLUTIONS northwestern UST was located on the subject site. Soil samples collected from the northern and eastern walls of the northwestern UST excavation indicated elevated concentrations of polynuclear aromatic hydrocarbons (PAHs) and total petroleum hydrocarbons as diesel - range organics (TPH-DRO). A groundwater sample collected from a monitoring well located approximately 40 ft east of the subject site indicated concentrations of benzene and naphthalene significantly above 2L Standards. • During 2010 Brownfields Phase II assessment activities, an approximately 0.5 ft to 1 ft thick layer of coal and coal byproducts was identified in soil borings throughout the 1015 S. Eugene Street Property at depths ranging from 0.25 ft to 6.5 ft below ground surface (bgs). The coal is likely from various former coal supply companies located east/northeast of the subject site and the former Pintsch Compressing Company MGP facility. Various PAHs and metals likely associated with the coal and coal byproducts were identified in soil at concentrations above regulatory levels. The 1201 S. Eugene Street Property of the property was not assessed for coal and coal byproducts. • The 1201 S. Eugene Street Property was historically occupied by numerous residences since the early 1900s. The residences were removed in the early 1970s, at which point apartments were constructed on the southern portion of the subject site. The heating source for the residences is believed to have been coal. • There is a potential for asbestos -containing materials (ACM) and lead -based paint (LBP) to be located within the GHA buildings based on its construction date (mid- to late 1970s). Phase II Quality Assurance Project Plans As part of H&H's Brownfields Phase II assessment planning, H&H prepared a Generic Quality Assurance Project Plan (Generic QAPP) for Piedmont Triad Regional Council Brownfield Phase II ESAs. In addition, a Site -Specific QAPP (SSQAPP) was completed specifically for the City and GHA sites. These QAPPs outlined specific procedures to be implemented to assure and control the quality and integrity of sample collection and analysis during the course of the assessment. These procedures were followed as prescribed, unless noted otherwise in this report. 4 44 SAAAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Phase II Assessment\Report\Einal Greensboro Phase II Report.docx hart � h i ck ma n SMARTER ENVIRONMENTAL SOLUTIONS Results of the Brownfields site assessment activities are presented in this report. D 44 SAAAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Phase II Assessment\Report\Einal Greensboro Phase II Report.docx hart � h i ck ma n SMARTER ENVIRONMENTAL SOLUTIONS 2.0 General Summary of Phase II Assessment Activities Phase 11 assessment activities were conducted by H&H from July 6 to July 9, 2015. Field activities consisted of the following: 1) Completion of 23 soil borings using direct push technology (DPT) methods and collection of six soil samples where potential impacts were observed for laboratory analysis. 2) Installation of seven temporary monitoring wells using DPT methods and collection of eight groundwater samples for laboratory analysis. 3) Completion of a lead -based paint (LBP) and asbestos containing material (ACM) surveys of the GHA buildings. The LBP survey work was conducted by Get The Lead Out under contract to H&H. 4) Surveying by a registered land surveyor (Regional Land Surveyors) to determine the horizontal and vertical coordinates of all sample locations and top of casing elevations of temporary monitoring wells using a global positioning system (GPS). 6 44 SAAAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Phase II Assessment\Report\Einal Greensboro Phase II Report.docx hart � h i ck ma n SMARTER ENVIRONMENTAL SOLUTIONS 3.0 Soil Assessment 3.1 Soil Sampling Methods Carolina Soil Investigations (CEI), a North Carolina licensed well driller, was subcontracted to complete the drilling, well installation and well abandonment tasks. A H&H field geologist directed, oversaw, and documented these tasks. Twenty three (23) borings (SB-1 through SB-23) were advanced using a Geoprobe 6610DT (DPT) rig. CSI utilized a hand auger to advance the first 5 feet (ft) of each boring to clear subsurface utilities. The soil boring locations are depicted on Figures 3A/3B. Boring logs are included in Appendix A. Soil borings SB-1 through SB-5 were advanced to a targeted depth of 15 ft below ground surface (bgs) and soil borings SB-6 through SB-23 were advanced to a maximum depth of 10 ft bgs unless obvious soil impacts extended deeper. Continuous soil cores were collected with a MacroCore® sampler within an acetate sleeve at five-foot intervals during the advancement of each soil boring. Soils were described for lithology, visually inspected, and field -screened for the presence of organic vapors with a calibrated photo -ionization detector (PID). There was no field evidence of impacts in soil borings SB-3 through SB-15 and SB-17 through SB-23. Soil borings SB-1 and SB-2 were completed to evaluate potential releases from the two sumps in the paint shed located on the GHA property. During the advancement of soil boring SB-1, the soil exhibited black staining and slightly elevated PID readings were detected. The highest PID reading was 2.1 parts per million (ppm) at the 2 to 4-ft depth interval. In accordance with the SSQAPP, a sample was collected at the 2 to 4 ft depth interval to assess soil that exhibited the greatest evidence of impacts. During the advancement of the soil boring SB-2, elevated PID readings were measured in the shallow soil. PID readings ranged from 0.0 ppm below a depth of 10 ft to 74.1 ppm at the 0 to 2- ft depth interval. A sample was collected at the 0 to 2-ft depth interval to assess soil that exhibited the greatest evidence of impacts. 7 44 SAAAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Phase 11 Assessment\Report\Einal Greensboro Phase II Report.docx hart � h i ck ma n SMARTER ENVIRONMENTAL SOLUTIONS During the advancement of the soil borings SB-3 through SB-23 on the City of Greensboro property (1201 S. Eugene Street), only SB-16 had field evidence of potential contamination. A slight odor and black staining was observed at the 8 to 10-ft depth interval in SB-16. The PID reading at this interval was measured at 1.9 ppm. In accordance with the SSQAPP, the soil boring was advanced to a total depth of 15 ft. No staining and a lower PID reading was observed, suggesting that the potential impacts did not extend below 10 ft. A soil sample was collected from the 8 to 10-ft depth interval. Soil samples were submitted for laboratory analysis of volatile organic compounds (VOCs) by EPA Method 826013, and semi -volatile organic compounds (SVOCs) by EPA Method 8270D. Soil samples collected from SB-I, SB-2, and SB-16 were also submitted for RCRA metals by EPA Method 6010C and 7471B. Soil borings were abandoned by filling with bentonite. Prism Laboratories (Prism) conducted laboratory analyses of soil samples. Prism is certified by the National Environmental Laboratory Accreditation Program (NELAP) to perform the requested laboratory analyses for the project. The State of North Carolina has approved the NELAP accreditation. A chain -of -custody (COC) record was completed for samples collected. The completed COC record was signed by H&H sampling personnel prior to placement in an iced cooler and transferred to a Prism Labs courier for delivery to the analytical laboratory in Charlotte, NC. The laboratory analytical data reports and COC records are provided in Appendix B. 3.2 Quality Control (QC) Soil Sample Collection A blind duplicate sample was submitted to the laboratory as a measure of laboratory repeatability. The duplicate sample results are included in Table 1 and in the laboratory analytical data report in Appendix B. • Dup-1 analyzed for VOCs, SVOCs, and RCRA metals collected from SB-2 at the 0 to 2 ft depth interval The matrix spike/matrix spike duplicate (MS/MSD) soil sample listed below was collected and submitted to the analytical laboratory. 8 44 SAAAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Phase II Assessment\Report\Final Greensboro Phase II Report.docx hart � h i ck ma n SMARTER ENVIRONMENTAL SOLUTIONS • MS/MSD analyzed for VOCs, SVOCs, and RCRA metals collected from SB-2 at the 0 to 2 ft depth interval. 3.3 Soil Assessment Results The soil analytical results are summarized in Table 1. The soil analytical results were compared to the current DENR Inactive Hazardous Site Branch (IHSB) Preliminary Health Based Soil Remediation Goals (PSRGs). The PSRGs are conservative preliminary screening concentrations, adapted from the USEPA Regional Screening Tables, and not regulated standards. DENR allows calculation of site -specific cleanup criteria. The levels may be adjusted based on the individual contaminant's health effects and the number of contaminants present at the site. When using the site -specific data, and the calculation procedures provided in the DENR REC Program Guidance which is also applicable to the North Carolina Brownfield Program, the final site -specific health - based cleanup goals for the contaminants detected in site soils is shown on Table 1. Metal results were also compared to the two times the average regional background metal concentrations. Background metal concentrations were obtained from published sources as documented on Table 1. The soil analytical data is discussed below for each area of concern: Paint Shop Sumps The VOC acetone was detected at a concentration of 0.070 milligrams per kilogram (mg/kg) in soil sample SB-1 (2 to 4 ft bgs) which is well below its respective Industrial or Residential PSRGs. Several SVOCs were detected at concentrations above laboratory reporting limits; however, none were detected above their respective site -specific health -based cleanup goals. The RCRA metals barium, cadmium, chromium, lead and mercury were also detected below their respective Industrial and Residential PSRGs. Arsenic was detected at 77 mg/kg, which is above the site - specific cleanup goals and greater than two times the average background concentration. The SVOCs dibenzo(a,h)anthracene and pyrene were detected below their respective PSRGs in the shallow soil sample (0 to 2 ft bgs) at SB-2; however, benzo(a)pyrene was detected at a concentration that exceeds the residential site -specific cleanup goal (Table 2). Several other 9 44 SAAAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Phase II Assessment\Report\Einal Greensboro Phase II Report.docx hart � h i ck ma n SMARTER ENVIRONMENTAL SOLUTIONS SVOCs were detected above laboratory reporting limits in the duplicate sample, but were not detected in the normal sample. A reason why these SVOCs were detected in the duplicate sample but not the normal sample is most likely due to the variability of SVOCs in soils and the low concentrations as indicated by the concentrations detected in the duplicate sample. Concentrations of barium, chromium, lead, and mercury were detected above laboratory reporting limits, but did not exceed their respective PSRGs. Arsenic (4.8 mg/kg in the normal sample and 4.4 mg/kg in the duplicate sample) did not exceed the site -specific cleanup goals. The concentrations of metals detected are also consistent with naturally occurring concentrations. Coal Tar UST Shallow soil samples (0 to 2 ft bgs) were collected from SB-3 through SB-5 to assess the soil conditions at the north, west, and south sides of the former coal tar UST excavation of the 1201 S. Eugene Street Property. Only the VOC acetone was detected in the shallow soil samples (0 to 2 ft bgs) at SB-3 (0.096 mg/kg) and SB-4 (0.089 mg/kg), which was well below the Industrial and Residential PSRGs. No SVOCs were detected above laboratory reporting limits in the soil samples collected near the coal tar UST. 1201 S. Eugene Property During the advancement of the soil borings SB-6 through SB-23 on the City of Greensboro 1201 S. Eugene Street property, only SB-16 had field evidence of potential contamination. Therefore, a sample was collected from SB-16 at the 8 to 10 ft depth interval for laboratory analysis. No VOCs were detected above laboratory limits in the sample. Several SVOCs were detected above laboratory reporting limits; however, only dibenz(a,h)anthracene (0.39 mg/kg) was detected above the residential site -specific cleanup goal of 0.19 mg/kg. Concentrations of barium, chromium, lead, and mercury were detected above laboratory reporting limits, but did not exceed their respective PSRGs. Arsenic (3.4 mg/kg) did not exceed the site -specific cleanup goals. 10 44 SAAAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Phase II Assessment\Report\Einal Greensboro Phase II Report.docx hart � h i ck ma n SMARTER ENVIRONMENTAL SOLUTIONS 4.0 Groundwater Assessment 4.1 Temporary Monitoring Well Construction As outlined in the approved SSQAPP, seven temporary groundwater monitoring wells (TMW-1 through TMW-7) were installed by CSI on July 6 and July 7, 2015. These wells were installed for groundwater monitoring to assess for potential impacts from: • an upgradient former dry cleaner; • potential releases from the upgradient auto repair shop and gas station; • documented release from the current gas station at 1000 South Eugene Street; • downgradient of the paint storage building and carpentry shop; • around the former northwest coal tar UST excavation; and • beneath the eastern area of the 1201 S. Eugene Street Property. The surveyed temporary monitoring well locations are depicted on Figure 3A/313. Each well was installed using DPT. Soil in the first —5 ft of each temporary monitoring well was collected with a hand auger. Soil below 5 ft of each temporary monitoring well was collected with a MacroCore® sampler within an acetate sleeve at five-foot intervals until reaching the target depth or DPT refusal. The wells were constructed with a 10-ft length of 1-inch pre -packed PVC well screen to bracket the water table along with 1-inch PVC riser pipe. Following construction, the temporary wells were developed in accordance with the SSQAPP. Well construction details are included on Table 2 and the boring logs/well construction logs are included in Appendix A. 4.2 Groundwater Occurrence Prior to temporary monitoring well sampling, the depth -to -water in each monitoring well was obtained using an electronic water level meter. Groundwater was encountered at depths ranging from 8.19 to 13.43 ft bgs (Table 2). The groundwater elevations are shown on Figure 4A/4B. 11 44 SAAAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Phase II Assessment\Report\Einal Greensboro Phase II Report.docx hart � h i ck ma n SMARTER ENVIRONMENTAL SOLUTIONS Determining the true static water table elevation based upon temporary wells is at times difficult due to potential inaccuracies resulting from temporary well construction and varying geologic conditions. When looking solely at the groundwater elevation data, the implied groundwater flow direction would be to the southeast. This appears to be consistent with the topographic gradient for the site. 4.3 Low Flow Well Purging and Sampling Methods Each well was purged by low flow methods using dedicated tubing and a peristaltic pump. During well purging, measurements of dissolved oxygen, pH, conductivity, temperature, and turbidity were collected using a water quality meter. Each well was purged until field parameters stabilized or the well went dry. Appropriate efforts were made to achieve optimal turbidity measurements of <10 nephelometric turbidity units (NTUs); however, turbidity levels remained elevated in several wells due to the fine-grained lithology and temporary well construction. Groundwater samples were then collected from each well for laboratory analysis as described below. Groundwater sampling records are provided in Appendix C. 4.4 Ground Water Sampling In accordance with the SSQAPP, temporary monitoring wells TMW-1 through TMW-7 were sampled for VOCs by EPA Method 8260 and SVOCs by EPA Method 8270. Additionally, temporary monitoring wells TMW-4 through TMW-7 were sampled for RCRA metals by EPA 6010 and 7470. Laboratory analyses were conducted by Prism Laboratories. A COC record was completed and signed by H&H sampling personnel prior to placement in an iced cooler and delivered to Prism Laboratories by H&H sampling personnel. 4.5 QC Ground Water Sample Collection The blind duplicate sample listed below was submitted to the laboratory as a measure of laboratory repeatability. Dup-1 for VOCs and SVOCs collected from TMW-1 12 44 SAAAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Phase II Assessment\Report\Einal Greensboro Phase II Report.docx hart � h i ck ma n SMARTER ENVIRONMENTAL SOLUTIONS • Dup-2 for RCRA metals collected from TMW-7 The MS/MSD groundwater sample listed below was collected and submitted to the analytical laboratory. • MS/MSD for VOCs and SVOCs from TMW-1 • MS/MSD for RCRA metals collected from TMW-4 Additionally, a trip blank accompanied the groundwater samples during delivery to the laboratory and was analyzed for VOCs. 4.6 Groundwater Analytical Results The groundwater data were compared to DENR Title 15A NCAC 2L Standards (2L Standards) and the DENR Division of Waste Management (DWM) Non -Residential and Residential Vapor Intrusion Screening Levels (VISLs). Groundwater analytical results as compared to the screening criteria are summarized in Table 3. The analytical laboratory data reports are provided in Appendix B. Off-site/Upgradient Former Dry Cleaner and Historic Gas Station/Auto Repair Shop Groundwater samples were collected from TMW-1 and TMW-2 to assess for potential impacts from the upgradient former dry cleaner and historic gas station/auto repair shop have migrated toward the 1005 S. Eugene Street parcel. The chlorinated VOC tetrachlorethlyene (PCE) was detected in TMW-1 at a concentration of 290 microgram per liter (µg/L), which exceeds the 2L Standard (0.7 µg/L) and the Residential (12 µg/L) and Non -Residential (48 µg/L) VISLs. Trichloroethylene (TCE) was detected at concentrations of 3.4 µg/L, exceeding the 2L Standard and Residential VISL of 3 and 1.04 µg/L, respectively. The concentration of 1,1-dichloroethane (1,1-DCA, 11 µg/L) also exceeded the 2L Standard of 6 µg/L. Other VOCs were detected in TWM-1 but did not exceed screening criteria. No SVOCs were detected in TMW-1. 13 44 SAAAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Phase II Assessment\Report\Einal Greensboro Phase II Report.docx hart � h i ck ma n SMARTER ENVIRONMENTAL SOLUTIONS PCE was detected at a concentration of 25 µg/L in TMW-2, exceeding the 2L Standard and Residential VISL. The concentration of naphthalene (28 µg/L) also exceeded the 2L Standard of 6 µg/L. The constituents detected in TMW-1 and TMW-2 are indicative of a typical dry cleaning solvent release. PCE has historically been used in the dry cleaning industry. PCE breakdown/daughter products include TCE and 1,1-DCA. Northwestern Property Boundary A groundwater sample was collected from TMW-3 to assess if the documented release from the current gas station at 1000 South Eugene Street has migrated beneath the subject property. The chlorinated VOC PCE was detected at a concentration of 5.4 µg/L, which exceeds the 2L Standard. The presence of PCE is likely due to the upgradient former dry cleaner and not the current gas station. Chloroform was also detected above laboratory reporting limits, but did not exceed any of the screening criteria. No SVOCs were detected in TMW-3. Paint/Carpentry Shop A groundwater sample was collected from TMW-4 to assess groundwater conditions downgradient of the paint and carpentry shop located on the GHA property. The chlorinated VOC PCE (15 µg/L) was detected above the 2L Standard and Residential VISL. TCE, 1,1-DCA and 1,1- dichlorothylene (1,1-DCE) were detected above laboratory reporting limits but did not exceed their respective screening criteria. The RCRA metal barium was detected at a concentration of 190 µg/L, which is below the 2L Standard of 700 µg/L. No SVOCs were detected above laboratory reporting limits in TMW-5. Cnnl Tar TTRT A groundwater sample was collected from TMW-5 to assess groundwater conditions cross to downgradient of the coal tar UST. No VOCs or SVOCs were detected above laboratory reporting limits in TMW-6. Barium was detected at 94 µg/L, below the 2L Standard. 14 44 SAAAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Phase II Assessment\Report\Einal Greensboro Phase II Report.docx hart � h i ck ma n SMARTER ENVIRONMENTAL SOLUTIONS 1201 S. Eugene Street Property. Groundwater samples were collected from TMW-6 and TMW-7 to monitor overall groundwater quality beneath the eastern area of the 1201 S. Eugene Street Property. In TMW-7, the VOCs acetone (54 µg/L) and methyl ethyl ketone (12 µg/L) were detected a concentrations well below their respective 2L Standard and VISLs (Table 3). Barium was detected at a concentration of 520 µg/L in TMW-6 and 250 µg/L in TMW-7, below the 2L Standard. No SVOCs were detected in TMW-6 and TMW-7. 15 44 SAAAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Phase II Assessment\Report\Final Greensboro Phase II Report.docx hart � h i ck ma n SMARTER ENVIRONMENTAL SOLUTIONS 5.0 Asbestos and Lead -Based Paint Survey Complete reports for the Asbestos Containing Material (ACM) and Lead -Based Paint Surveys are provided in Appendix C. Below is a summary of the report: 5.1 Asbestos Survey On February 24, 2015, Mr. Gabe Steil of H&H conducted an asbestos survey of the site buildings. Mr. Steil is trained and licensed as a North Carolina Health Hazard Control Unit (HHCU) asbestos inspector (#12879). The asbestos survey was conducted in general accordance with the HHCU guidelines for asbestos building inspections. The objectives of the asbestos survey were to: • Identify and assess the condition and friability of suspect asbestos -containing materials, on the interior and exterior of the building, including the roof system; • Collect samples from a representative number of random locations in accordance with the Asbestos Hazard Emergency Response Act (AHERA) guidelines; and • Prepare a written report detailing findings of the inspection. Samples collected from the suspect ACMs within the project area were submitted to Carolina Environmental Inc. (CEI) Labs of Cary, NC. CEI is a National Voluntary Laboratory Accreditation Program (NVLAP) certified laboratory. Based on the AHERA guidelines, 56 samples were analyzed from 20 homogenous materials associated with the building. H&H instructed the laboratory to stop analysis of samples from a homogeneous area if a sample from the area contained greater than 1% asbestos. The laboratory results indicated that ACM is present. By EPA's definition, the following material is an ACM: • floor tile (white with gray gashes — 12"xl2", approximately 1,900 square ft.) and associated mastic (black) located in the main hallway, northern hallway and in the men's and women's restrooms contains 2% and 10% Chrysotile asbestos, respectively (Sample 001); 16 44 SAAAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Phase II Assessment\Report\Einal Greensboro Phase II Report.docx hart � h i ck ma n SMARTER ENVIRONMENTAL SOLUTIONS • floor tile (white with red gashes — 12"x12", approximately 3 square ft.) and associated mastic (black) located in the main hallway entrance to the electrical room contains 3% and 5% Chrysotile asbestos, respectively (Sample 004); • mastic (black — approximately 20 square ft.) associated with the non -asbestos containing floor tile (dark brown — 9"x9") located in the warehouse toilet area contains 5% Chrysotile asbestos (Sample 013); • roofing (tar and fiber — approximately 2,700 square ft.) located on the eastern section of the canopy roof contains 10% Chrysotile asbestos (Sample 019). The complete ACM Report can be found in Appendix D. 5.2 Lead -Based Paint Survey H&H contracted with Get The Lead Out, a certified North Carolina Lead Risk Assessor, to conduct a LBP survey on July 7, 2015. Get The Lead Out did not identify LBP in the GHA buildings. The results of the survey are documented in the report Lead Paint Survey Report 1005 Eugene Street dated July 8, 2015 by Get The Lead Out (Appendix D). 17 44 SAAAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Phase II Assessment\Report\Einal Greensboro Phase II Report.docx hart � h i ck ma n SMARTER ENVIRONMENTAL SOLUTIONS 6.0 Data Review, Verification, and Validation In accordance with the Generic QAPP and Site -Specific QAPP Addendum, the field and laboratory analytical data were subjected to review, verification, and validation to ensure that the quality and validity of the data were acceptable for the stated Data Quality Objectives (DQOs). The laboratory quality assurance data are provided in the laboratory analytical report in Appendix B. The final data review was conducted by John Reuscher, P.G. of H&H, Project QA/QC Officer. The following is a summary of the data review, verification, and validation: Field Data • The proper laboratory analyses were requested for each sample. • Sample chain -of -custody protocols were properly followed. • The field procedures for decontamination, calibration, etc. were followed in accordance with the Generic QAPP and Site -Specific QAPP Addendum procedures. Field activities were appropriately documented in the field log book and groundwater sampling records. • Although efforts were made to minimize turbidity of temporary monitoring well samples to collect representative ground water samples for metals analyses, measured turbidities prior to sample collection were higher than the optimal <10 NTUs in the groundwater sample collected from TMW-1 and TMW-7. However, based on the groundwater analytical results, the elevated sample turbidity did not impact the usability of the corresponding analytical data. Laboratory Data • The requested laboratory analyses were performed by the laboratory on each sample. All samples were properly preserved. • The laboratory analyses were conducted within the method holding times. • The soil and groundwater samples were received at the laboratory in good condition, within the proper temperature range, and were properly preserved. 18 44 SAAAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Phase II Assessment\Report\Einal Greensboro Phase II Report.docx hart � h i ck ma n SMARTER ENVIRONMENTAL SOLUTIONS • The analytical results for the groundwater duplicate samples indicated good repeatability in the laboratory analysis. The analytical results for VOCs and RCRA metals for the soil duplicate sample indicated good repeatability in the laboratory analysis. As for the SVOCs, several SVOCs were detected at higher concentrations in the duplicate sample than the normal sample. A reason why these SVOCs were detected in the duplicate sample but not the normal sample is most likely due to the variability of SVOCs in soils and the low concentrations as indicated by the concentrations detected in the duplicate sample. This variability does not affect the conclusions of the findings in this assessment due to the low concentrations of the SVOCs detected in the duplicate sample. • No compounds were detected in the field trip blanks that accompanied the samples for analysis of VOCs. • Laboratory reporting limits (LRLs) for several VOCs, SVOCs, and metals and method detection limits (MDLs) for several metals were slightly higher than those summarized in Table 3 of the Site -Specific QAPP Addendum. However, the elevated LRLs and MDLs should not impact the usability of the corresponding laboratory data considering the analytical sensitivity and project criteria. Data Review Conclusions The conclusions of the data review are that field and laboratory data generally meet QA objectives and are usable for the intended purpose. 19 44 SAAAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Phase II Assessment\Report\Final Greensboro Phase II Report.docx hart � h i ck ma n SMARTER ENVIRONMENTAL SOLUTIONS 7.0 Data Evaluation Summary and Conclusions This Phase II Brownfield Environmental Site Assessment was completed to evaluate, through the collection and analysis of various samples, the areas of concern outlined in the SSQAPP. The primary purpose of the Phase II assessment was to determine if these concerns represent actual environmental impacts and pose a potential environmental risk for future site redevelopment and use. Based on the results from this investigation, it appears there's environmental impacts associated with the former upgradient dry cleaner and on -site paint shop. Below is a summary of the assessment findings coupled with some conclusions which should be considered when assessing site risk and evaluating redevelopment plans. Soil Based upon the findings of this investigation, site soils in general do not present a problem/risk for the site to be redeveloped. Soil data collected from the paint shop area indicate low levels SVOCs. The concentrations of benzo(a)pyrene exceed the residential site -specific cleanup goal of 0.19 mg/kg at SB-2. Arsenic was detected at concentrations above the residential and industrial site - specific cleanup goals and is greater than two times the average background concentration at SB- 1. Dibenz(a,h)anthracene was detected at a concentration that exceeds the site -specific cleanup goals; however, the sample was collected at the 8 to 10 ft depth interval. Groundwater Several chlorinated VOCs, namely PCE, were detected in groundwater samples collected from TMW-1, TMW-2, TMW-3, and TMW-4. Concentrations of PCE exceed the 2L Standard and VISLs in all four wells. The PCE plume source is most likely from the upgradient former dry cleaner. Also, naphthalene exceeds the 2L Standard but did not exceed VISLs in TMW-2. Groundwater analytical results collected from temporary monitoring wells (TMW-5, TMW-6, and TMW-7) installed on the 1201 S. Eugene property did not indicate concentrations of VOCs, SVOCs, or RCRA metals above applicable screening criteria. 20 44 SAAAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Phase II Assessment\Report\Final Greensboro Phase II Report.docx hart � h i ck ma n SMARTER ENVIRONMENTAL SOLUTIONS Asbestos and Lead Based Paint ACM was detected in various building material in the GHA building; however, and LBP was not detected. Conclusions Based upon the results of this investigation, impacted groundwater on the 1005 S. Eugene property may pose an exposure risk to construction workers and/or future site occupants via direct contact or inhalation of organic vapors (i.e. vapor intrusion). VI sampling was not conducted during this assessment. Based on the results of the groundwater samples collected on this property, additional evaluation of potential vapor intrusion may be necessary, depending upon the final redevelopment plans. Shallow soil impacts found during this investigation appear to be isolated near the paint shop on the 1005 S. Eugene property. Depending upon the final redevelopment plan, mitigation of these soils may be necessary to prevent exposure of elevated arsenic concentrations to construction workers and/or future site occupants via direct contact. Prior to demolition, ACM abatement should be conducted at the main GHA building. 21 44 SAAAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Phase II Assessment\Report\Final Greensboro Phase II Report.docx hart � h i ck ma n SMARTER ENVIRONMENTAL SOLUTIONS + J r i. -: - v cr1 ._ -- IJ - � .• Ucs�c, •V. r f Imo• '�� . { -- ..1_ OAT�rLi i-117 W�yCt;k4�iac� t - _��• r,�n �r I �I1I P. I.rr r. r .,i•t +I L - t - L1- ` ' � - t � .f rl '. _I -- _�_� y � � ` _- •t rchai_ su • J sYRBC>�T T - . • C �� 1 l J:. I` I � 1 SITE Js L; �r 4' 1I ' �[• T l Soh, J •1 1 l kkI� r roy .. III-. ... 6- � .Win go I APPROXIMATE TITLE SITE LOCATION MAP N 0 2000 4000 PROJECT CITY OF GREENSBORO AND SCALE IN FEET GHA PARCELS 1005, 1015, & 1201 S. EUGENE STREET U.S.G.S. QUADRANGLE MAP GREENSBORO, NORTH CAROLINA hart � h i c k m a n 3334 Hillsborough Street GREENSBORO, NC 1994 Raleigh, North Carolina27607 919-847-4241 (p) 919-847-4261 (f) SMARTER ENV}RONMENTAL SOLUTIONS QUADRANGLE DATE: 4/01/2015 REVISION NO: 0 7.5 MINUTE SERIES (TOPOGRAPHIC) JOB NO: PTR-001 FIGURE NO: 1 r MEDICAL OFFICE `t (1002 S. EUGENE STREET) t 4 w GREENWAY 010 S. EUGENE S- 1t RESIDENCE (800 BILBRO STREET) ;SHILOH BAPTIST CHURCH (1210 S. EUGENE STREET) I 1005 S. EUGENE STREET CONCRETE DEBRIS CONCRETE 1015 S. EUGENE STREET FORMER CONCRETE PAD • VACANT LAND/FORMER WORTH PROPERTY (728 S. ELM STREET) 'L • VACANT LAND/FORMER%fA* GATECO PROPERTY (734 S. ELM STREET) -SIw�+-..1� GREENW(FORMER W. BRAGG STREET) . FORMER MGP BUILDING MRAY _ I I FORMER ' i 'I FUEL HOUSE l q mrwgr JU FORMER 10,000-GALLON \ FORME0,0COAL TAR USTs FORMER law, TAR 00-GALLON UST APARTMENTS (WITH APPROXIMATE EXCAVATION LIMITS) � FORMER NORTH STATE * MILLING COMPANY FORMER GAS (816 S. ELM STREET) HOLDER 1201 S. EUGENE STREET VACANT LAND/FORMER MGP FACILITY (107 W. BRAGG STREET) FORMER APARTMENTS _ COMMUNICATIONS TOWER (1219 S. EUGENE STREET) LEGEND SITE BOUNDARY PROPERTY PARCEL FORMER FEATURE (;'USt FORMER 10,000-GALLON COAL TAR UST ESTIMATED EXTENT OF SUBSURFACE COAL AND COAL BYPRODUCT LAYER (BASED ON 2010 BROWNFIELDS ASSESSMENT ACTIVITIES) APARTMENTS (1229 S. EUGENE STREET) idIJ RESIDENCES (828 & 836 S. ELM STREET) - IF I� COMMERCIAL BUILDING/FORMER DRY-CLEANING FACILITY (840 S. ELM STREET) h _ I 1 1 + APPROXIMATE 0 80 160 SCALE IN FEET TI- SITE MAP PROJECT CITY OF GREENSBORO & GHA PARCELS 1005, 1015, & 1201 S. EUGENE STREET GREENSBORO, NORTH CAROLINA reet hart hickman 33leigh, brthCaorough Stna Raleigh, North Carolina 27607 919-847-4241(p) 919-847-4261(f) SMARTER ENVIRONMENTAL SOLUTIONS License # C-1269 / #C-245 Geology DATE: 08-05-15 REVISION NO. 0 JOB NO. PTR-001 I FIGURE NO. 2B VACANT/FORMER J� GAS STATION ' (300 W. LEE ST) 1 r � � 1 VACANTLAND (609 S. EUGENE ST) ' AUTO REPAIR PF (200 W. LEE ST) I w 1 r COMMERCIAL (620 S. ELM ST) T • • � w Es ET 1 Mb TMW-2 GAS STATION (1000 S. EUGENE ST) TMW-1 TMW-3 VACANT LAND `may (125 W. LEE ST) 1005 S. EUGENE ST i # w - W OFFICES ® 0 W (p j VEHICLE W AINTENANCE MEDICAL OFFICE BAY VACANT LAND/FORMER WORTH PROPERTY (1002-1010 S. EUGENE ST) • (728 S. ELM ST) SB-1 WAREHOUSE SB_2 PAINTING/ TMW-4 STORAGE BUILDING CANOPY CARPENTRY • SHOP 1�Ik 1 CITY OF GREENSBORO GREENWAY 1015 S. EUGENE ST (1010 S. EUGENE ST) VACANT LAND/FORMER GATECO PROPERTY (734 S. ELM ST) I11 � LEGEND SITE BOUNDARY PROPERTY PARCEL TEMPORARY MONITORING WELL SOIL BORING ® FLOOR DRAIN ® SUMP 0 60 160 SCALE IN FEET TI- SAMPLE LOCATION MAP PROJECT CITY OF GREENSBORO & GHA PARCELS 1005, 1015, & 1201 S. EUGENE STREET GREENSBORO, NORTH CAROLINA 14 Street hart hickman 33leigh, Hillsborough Ca Slim Raleigh, North Carolina 27607 919-847-4241(p) 919-847-4261(0 SMARTER ENVIRONMENTAL SOLUTIONS License # C-1269 / #C-245 Geology DATE: 08-05-15 REVISION NO. 0 JOB NO. PTR-001 FIGURE NO. 3A I — • � . 1005 S. EUGENE STREET SB-1 MEDICAL OFFICE `t SB-2 (1002 S. EUGENE STREET) - • ♦ - � CONCRETE DEBRIS 1 , CONCRETE PAD M" CITY OF GREENSBORO GREENWAY 1015 S. EUGENE STREET (1010 S. EUGENE STREET) FORMER CONCRETE PAD fill RESIDENCE (800 BILBRO STREET) SHILOH BAPTIST CHURCH (1210 S. EUGENE STREET) NGG STRT) .4 FORMER MGP /i EE ft K \ FORMER 10,000-GALLON :APARTMENTMS RMERCOAL TAR UST (WITH APPROXIMATE EXCAVATION LIMITS) VACANT LAND/FORMER WORTH PROPERTY (728 S. ELM STREET) VACANT LAND/FORMER ` 1 • 1 GATECO PROPERTY (734 S. ELM STREET) —Svw't-. i �+1 =HOUSE FUEL t FORMER q W FORMER NORTH STATE MILLING COMPANY FORMER GAS (816 S. ELM STREET) HOLDER 1201 S. EUGENE STREET VACANT LAND/FORMER MGP FACILITY (107 W. BRAGG STREET) COMMUNICATIONS TOWER (1219 S. EUGENE STREET) LEGEND SITE BOUNDARY PROPERTY PARCEL FORMER FEATURE TEMPORARY MONITORING WELL • SOIL BORING /,0(7,5'h FORMER 10,000-GALLON COAL TAR UST ESTIMATED EXTENT OF SUBSURFACE COAL AND COAL BYPRODUCT LAYER (BASED ON 2010 BROWNFIELDS ASSESSMENT ACTIVITIES) FORMER APARTMENTS APARTMENTS (1229 S. EUGENE STREET) id1J w •I RESIDENCES (828 & 836 S. ELM STREET) - IF I� COMMERCIAL BUILDING/FORMER Y-CLEANING FACILITY 840 S. ELM STREET) i h _ I 8 APPROXIMATE NOTES 0 80 160 1. LOCATIONS OF FORMER FEATURES ARE SCALE IN FEET APPROXIMATE. 2. TEMPORARY WELL TMW-8 IS NOT SHOWN BECAUSE 717LE ITS LOCATION IS DEPENDANT ON FIELD SCREENING SAMPLE LOCATION MAP IF SOIL BORINGS SB-6 THROUGH SB-23. PROJECT CITY OF GREENSBORO & GHA PARCELS 1005, 1015, & 1201 S. EUGENE STREET GREENSBORO, NORTH CAROLINA treet hart hickman 33leigh,sbrthCaorough olina Raleigh, North Carolina 27607 919-847-4241(p) 919-847-4261(f) SMARTER ENVIRONMENTAL SOLUTIONS License # C-1269 / #C-245 Geo: DATE: 08-05-15 REVISION NO. 0 JOB NO. PTR-001 FIGURE NO. 3B r MEDICAL OFFICE `t (1002 S. EUGENE STREET) t 4 GREENWAY 010 S. EUGENE S- 1t RESIDENCE (800 BILBRO STREET) ;SHILOH BAPTIST CHURCH (1210 S. EUGENE STREET) I 1005 S. EUGENE STREET CONCRETE DEBRIS CONCRETE 1015 S. EUGENE STREET FORMER CONCRETE PAD • VACANT LAND/FORMER WORTH PROPERTY (728 S. ELM STREET) 'L NGG STRENow ET) .0/ 4 FORMER MGP /i BULr ILDING FORMER 10,000-GALLO FORMER COAL TAR UST APARTMENTS (WITH APPROXIMATE EXCAVATION LIMITS) • VACANT LAND/FORMER%fA* GATECO PROPERTY (734 S. ELM STREET) -51w�+-..1� i+1 FORMER FUEL HOUSE t FORMER q .10,000-GALLON \ COAL TAR USTs FORMER NORTH STATE i * MILLING COMPANY FORMER GAS (816 S. ELM STREET) HOLDER 1201 S. EUGE E STREET VACANT LAND/FORMER MGP FACILITY (107 W. BRAGG STREET) TMW-6 (815.01) FORMER COMMUNICATIONS TOWER (1219 S. EUGENE STREET) LEGEND SITE BOUNDARY PROPERTY PARCEL FORMER FEATURE TEMPORARY MONITORING WELL ioUS7) FORMER 10,000-GALLON COAL TAR UST ESTIMATED EXTENT OF SUBSURFACE COAL AND COAL BYPRODUCT LAYER (BASED ON 2010 BROWNFIELDS ASSESSMENT ACTIVITIES) (6imb) GROUNDWATER ELEVATION (FT MSL) $,� O _ GROUNDWATER ELEVATION CONTOUR (FT MSL) (DASHED WHERE INFERRED) INFERRED GROUNDWATER FLOW DIRECTION APARTMENTS (1229 S. EUGENE STREET) id1J RESIDENCES (828 & 836 S. ELM STREET) - IF I� COMMERCIAL BUILDING/FORMER DRY-CLEANING FACILITY (840 S. ELM STREET) h _ I 1 1 + APPROXIMATE 0 80 160 SCALE IN FEET GROUNDWATER ELEVATION MAP PROJECT CITY OF GREENSBORO & GHA PARCELS 1005, 1015, & 1201 S. EUGENE STREET GREENSBORO, NORTH CAROLINA hart hickman 33leigh, HillsboroughStreet Raleigh, North Carolina 27607 919-847-4241(p) 919-847-4261(f) SMARTER ENVIRONMENTAL SOLUTIONS License # C-1269 / #C-245 Geology DATE: 08-05-15 REVISION NO. 0 JOB NO. PTR-001 I FIGURE NO. 46 Appendix A Boring and Well Construction Logs hart hickman SMARTER ENVIRONMENTAL SOLLMONS n Sheet of & Hickman C a3South orrh rolin-Suice 100 3 Charlotte, 24orch Carolina ?f;2fULOG OF BORING: A P........N CORPORATION 704-586-0007(p) 7(A-556-0373(0 Project: Job No: Location: y., U a a a o (D 0 .0 C 0 C� E U) Q) O yo _ v O a`i _n. E V) Q cc { TI bo w o LO Cn 0 T. 5_ Surface Elev: Top of Casing Elev: Drilling Rig/Method: Sampling Method: E MATERIAL DESCRIPTION SPT, Blow Counts v WELL DIAGRAM stratification lines represent approximate faries. The transition may be gradual.} } 0 O m VV) 1 �6tVWk e t-hl $ I I 0•fl 0.0 �.0 orb 0,0 �-- 5ie �,, ot 47r� s; I .sin 7PRrp�� cAii�sz� bCrc� �� —Well ",6-Q4 Iv � 22 f Completion Depth: Remarks: Date Boring Started: —7/i/t r Date Boring Completed: , ! Engineer/Geologist: Drilling Contractor: „,1 Revision DrownBy Date I Checked lApproved 100 Sheet of IIjn an Char South Tryon arobnaStreet-282 3 �t Charlotte, North Carolina 28203LOG OF BORING: A PPOrEs$IONAL Co­.­704-586-0007(p) 704-586-0373(o Project: ff-V ot— 14 Surface Elev: Job No: Top of Casing Elev: pp A ( Location: U E� P/'S�jON let �/ Drilling Rig/Method: Sampling Method: o va G o o o " >, a) MATERIAL DESCRIPTION SPT, Blow Counts v WELL DIAGRAM v ID (The stratification lines represent approximate _. boundaries. The transition -aL U may be gradual.) > O W 0 � � Y m 0 ?(an C IVWA 6.0 0:0 5 p 0 G,o 10 d, D 15 t 20 25 or bit Cb 1iG�tc 30 35 40 5 0 Completion Depth: V , Date Boring Started: •••7/` Remarks: Date Boring Completed: ! � ) t, Engineer/Geologist: �{�+� S 6" enct IDrawnBy Drilling Contractor: C Revision Date Checked Approved ft%ut& IIjca 2923 South Tryon arohnStreet-suite 100 3Sheet of Charlotte, Notth Carolina 28203LOG OF ROVE381ONnL CORPORATION 704-58G-0007(p) 704-58G-0373(o BORING: / ✓ Project: 00 " '34 Job No: Location: C,t At6IV C, y W _ N CL O 0 Oa I✓ Surface Elev: Top of Casing Elev: Drilling Rig/Method: Sampling Method: C 0 a) MATERIAL DESCRIPTION o p 0- N 0 (The stratification lines represent approximate U- e3 - boundaries: The transition" may be gradual.) to O :3 to 0 t 51 5 vxa jor� �gl�EUrt Sr I Ci�� 0 E SPT, Blow Counts a WELL DIAGRAM > � O Q m N 16-0 -C� 1 kd 6v Completion Depth: Remarks: Date Boring Started: '' (0 j/ S Date- Boring Completed: Engineer/Geologist: Drilling Contractor: �J,Y. kRevisionlDrownBylDate Checked Approved 2923 South Tryon Street -Suite 100 Sheet of Hickman Charlotte, North Carolina 28203 P ......... — c— ...... 704-586-OW7(p) 704-586-0373(o LOG OF BORING: Project: ?TV01) Surface Elev: Job No: Top Of Casing Elev: Location: Drilling Rig/Method: Sampling Method: rn (D o E z a) > MATERIAL DESCRIPTION SPT, Blow Counts a WELL DIAGRAM o 0. Q) 'CL Cf) 0 0 0) (The stratification lines represent approximate boundaries. The w0) E ce transition may be gradual) CL LU 0 0 U) M < m to C ot -10- ... ....... . -------- aaf�� 15 T4k .0 0 6.0 �4 0 IN �om 1 �Y4 �C4� -20- -25- -30- -35- -40- -45- 0-1 Completion Depth: Remarks: Dote Boring Started: Date Boring Completed: Engineer/Geologist: Drilling Contractor: Revision Dr..nByl Date I Checked Approved 100 Sheet of ryfl & f r an Char Stet,SoutNorth Stolina 2 2 3 (� �, t Charlotte, North Carolina 28203LOG OF BORING: �.�, A PROFESSIONAL Cottrowwnav 704-586-0007(p) 704-586-0373(0 Project: t' I F-•u— Surface Elev: Job No: Top of Casing Elev: Location: EJpj S; ��=ic ,T ,�- Drilling Rig/Method: 1 kC(oo� Sampling Method: N 4- N -C a .L) o .�^. E o a) MATERIAL DESCRIPTION SPT, Blow Counts WELL DIAGRAM o a a� 0 (The stratification_ lines represent approximate " V boundaries. The transition may be gradual.) W O � Y � m {l p 5 Red ti fVrf)k AAA � t t`�d ! E+tD 0.0 10 u f `j e r�tr % r 6y,� q .t7 ©.0 a��9e �eA XAitA�y C�oty 15 a'9 Sel- the flo lr! /a' o P(C p1T,A Completion Depth: I $- f Remarks: Date Boring Started: -711 Sr Date Boring Completed: -7J Engineer/Geologist: j Drilling Contractor: C,S—T. Revision DrawnByl Date ICheckedlApproved Sheet of af} & g ckmtu Char South Tryon Street -Suite 100 3 (,�,i (, � Charlotte, North Carolina 28203LOG OF BORING: A PwfJFES��ONA� Cawaowwnary 704-i8G-0007(p) 704-58G-0373(E) � Project: PTt oo ) Surface Elev: Job No: Top of Casing Elev: Location: 1.2i/ r, i to��—C Drilling Rig/Method: NO/M&(trb Corc Sampling Method: a -C a o o ,. .a) o -o E o s > MATERIAL DESCRIPTION SPT, Blow Counts v WELL DIAGRAM 0 CL U (The stratification lines represent approximate a>i a) a U m boundaries. The transition may be gradual.) Q > a p U) Y m 0 soi 5 /II Q(u✓I L 5r ��7 c i� 10 15 / -S07' %rlJ 20 ,E fih7z� i 1 pu r Ile �c Completion Depth: Remarks: Date Boring Started: `7%7%t,5 Date Boring Completed: 051,% Engineer/Geologist: � DrillingContractor: C SJ^ R—isi--ownByl Date I Checked Approved { p� 2923 South Tryon Street -Suite to (� (�kMdn Charlotte, North Carolina 28203 ft$dfl PPove35�onia� Caeca-- 704-586-0007(p) 704-586-0373(t) Project: Pry 001 dV Job No: l bb5" rkYAC S)NJ Location: l�C�S pfp1 t G to ... U L c a) O a s _ } MATERIAL __DESCI Surface Eiev: Top of Casing Elev: Drilling Rig/Method: 414 Sampling Method: o U (The stratification lines represent approximate N d U 0 boundaries. The transition may be gradual.) E to W O � to 0 8" CcMctz}cs brotor, getr a f3latk SMd c - A14 ja �- fl Sheet of E -Blow Counts - a Y O < Q m (n Vt s i•� .'3 6.0 Completion Depth: Date Boring Started: 2_ r 6 0 1000 ��($' Date Boring Completed: Engineer/Geologist: 05 W Drilling Contractor: C.5-T rks: Revision'DrawnBy' Date I CheckedlApproved AQT Sheet of & M(kMdD Char South Tryon Carolina 282 3 ,,,ssx'' Charlotte, North Carolina 28203LOG OF BORING: f �,. a PROVCsstoNn� couroaAnoN 704-58G-0007(p) 704-58G-0373(o L✓ Project: Surface Elev: Job NO: Top of Casing Elev: Location: Drilling Rig/Method: Sampling Method: I - U v— O O I] v— L P E C - 0 4) MATERIAL DESCRIPTION O p o. .a� 0(The stratification lines represent approximate > a U a) boundaries. The transition may be gradual.) w `rep," 'iY. 6 a.� B, 6.2 0.0 0.0 0-b 1.1 0 O M m I vi ........__ Completion Depth: Remarks: Date Boring Started: ���� Date Boring Completed: Engineer/Geologist: ey 11,5' Drillin Contractor: S RevisionFDrownByDate Checked Approved & WND Char South Tryon aroEnaStreet-Suite 100 Charlotte, North Carolina 28203 A 704-586-0007(p) 704-586-0373(o Project: Pl-P b0 Job No: Location: P-0 t' u�te1 S /Nel C o a)a- O a)O .D w L r- LOG OF Surface Elev: Top of Casing Elev: Drilling Rig/Method: t � �[ A-1 Cote — Sampling Method: - W MATERIAL DESCRIPTION SPT, Blow Counts vCL p a CX 0 (The stratification lines represent approximate W p U boundaries. The transition may be gradual.) j E � w to C� O 0 Q3 U) f psi, t, A7 c 6.0 5 aa�+� � 0l'.h,qC/7�klj .94AA./ C IA 10 Q.v G s-koly C (AY 6.6 15 n GyqZ 5q f li Sheet of Completion Depth: fcvRemarks: Date Boring Started: `f/�/t f0 Date Boring Completed: Engineer/Geologist: Drilling Contractor: C'r,11 JlRe-4visi.nwnBy Dote Chec kedi Approved &AAA t m Hick aChar South Tryon aroUnaStrect-uitc 100 3Chart86-0 North Carolina 28203LOG OF ft$art Pgarc55.Ot�wl.Cogqoqnnoro 704-i8G-0007(p) 704-58G-0373(f) BORING: Sheet of Project: PTA , Uo 1 Surface Elev: .lob No: i/ Top of Casing Elev: Drilling Rig/Method: MA"/ POL(r�' € Location: I.�b � S. %.��� do Sampling Method: rn Qa U "- N m L a- a O E o � E ..__ - N MATERIAL DESCRIPTION - SPT, Blow Counts a WELL DIAGRAM o a m U (The stratification lines represent approximate > 0 a U m boundaries. The transition may be gradual.) } w 01 _ Y g 0.0 5 0.h snaa{7 c fay to �. oru fe 4 v f 15 Completion Depth: J Remarks: Date Boring Started: r/ Date Boring Completed: Engineer/Geologist:s y I Drilling Contractor: CS3' f 1 Revision DrownBy Date Checked Approved � ckman Char South North St-Suite282 100 Charlotte, Noah Carolina 28203 A PR.......- CORPOR - 704-586-0007(p) 704-586-0373(o Project: pg�001 Job No: Location: N s o ` 0. N O 7 Sheet of LOG OF BORING.- .6 Surface Elev: Top of Casing Elev: f Drilling Rig/Method: j eaCfv Sampling Method: J >, U MATERIAL DESCRIPTION 0 (The stratification lines represent approximate v (D Q V a) boundaries. The transition may be gradual.) w p to 0 1 H E SPT, Blow Counts .a a. tJ m ( (¢ b•D 5 f `t I'G *i f - C 14/ b.� 8 • C1 a, b Completion Depth: is Remarks: Date Boring Started: Date Boring Completed:' Engineer/Geologist: Ogvj Drilling Contractor: S RevisionlDrawnByl Date ICheckediApproved �T100 Sheet of & �1c ali Char South Tryon Stolina 22 3Charlotte, North Carolina 373(LOG OF O- ft$arl PwocEsSrONq� CORPORATION 704-586-0007(p) 704.58G-0373(E) BORING: Project: Surface Elev: Job No: Top of Casing Elev: Location: Drilling Rig/Method: Sampling Method: W a = a o o I- a> o E E o >, cn 0 MATERIAL DESCRIPTION SPT, Blow Counts a WELL DIAGRAM o• -_2 _._U (The stratification lines represent approximate _ .. _. 0- V a) boundaries. The transition may be gradual.) j w ° _ m 0 0.0 ---------------------- ytn �s i o y ti _ 0.6 Completion Depth: Remarks: Date Boring Started: Dote Boring Completed: -� Engineer/Geologist: Revision'DrownBy) Dote I CheckedlApproved ftU2923 South Tryon Street -Suite 100 Charlotte, North Carolina 28203 aaressio704-586-0007(p) 704-586-0373(o Project: Job No: Location: to i m a p b\ N a c BORING:LOG OF Surface Elev: Top of Casing Elev: Drilling Rig/Method: Sampling Method: C O m MATERIAL DESCRIPTION o z cn > o r -ar ---0 (The stratification -tines represent opproximati a>y o- V m boundaries. The transition may be gradual.) tr W E � 0 Vi 0 Sheet of E SPT, Blow Counts `a WELL DIAGRAM YO tt11 m S 0. 5 L.fJ n•0 0.0 101 6.0 1 Completion Depth: Remarks: Date Boring Started: Date Boring Completed: Engineer/Geologist: Drilling Contractor: Revision Dra " nByl Date I Checked Approved 100 ffick a Char South Tryon Sa fina 2 2 3 Sheet of Charlotte, Noah Carolina 373(LOG OF BORING: �F7 A PROFESSIONAL CoaaoannaH 704-586-0007(p) 704-586-0373(t) fj Project: Surface Elev: Job No: Top of Casing Elev: Location: Drilling Rig/Method: Sampling Method: rn - Q) _ E o - 0 > c ) 0 > MATERIAL DESCRIPTION SPT, Blow Counts � WELL DIAGRAM (The stratification lines represent approximate _. a>i 0 a U W boundaries. The transition may be gradual.) w o o a m t`n WW4 5A,47 Ctg7 a. 0.0 1101 0,b ' Completion Depth: O( Remarks: Date Boring Started: Date Boring Completed: ', MM Engineer/Geologist: f35N Drilling Contractor: CS�f Revision DrownByl Date I Checked Approved Sheet of & flickmaChar South Tryon arolina lire 100 3Charlotte, Non) Carolina 28?03LOG OF �' fj - 1tft$aft PaovessioNn1 ConnOewnoea 704-586-0007(p) 704-S8G-0373(E) BORING: /j / Project: Surface Elev: Job No: Top of Casing Elev: Location: Drilling Rig/Method: Sampling Method: ur __ m " aa) v a o E n c MATERIAL DESCRIPTION SPT, Blow Count o a v - v (The stratification lines represent approximate a>i 0 E U boundaries. The transition may be gradual.) W O (J7 (1) � 0 Tb P5 a; k 0,0 t a be AV4 . zohf C�47 0.6 5 �. C7 d.fl 6.0 i I1 E s a WELL DIAGRAM CL M U Completion Depth: p p t o t Remarks: Date Boring Started: - Date Boring Completed: It 111 Engineer/Geologist:fV"' / Drilling Contractor: C5� Revision DrawnByl Date I Checked Approved Street ffick Ii Char South Tryon Carolina 2 2 100 Charlotte, North Carolina 28203LOG OF 0 y+� - p f'p A paoressioruAl CORPORAT�aN 704-586-0007(p) 704-S8G-0373{t) BORING: jj �,/ Project: Job No: Location: N N v 0 t .0 o T E U o(The boun W 0 rn Surface Elev. Top of Casing Elev: Drilling Rig/Method: Sampling Method: MATERIAL DESCRIPTION stratification lines represent approximate dories. The transition may be gradual.) E SPT, Blow Counts a O m I (nn .14ye77TF 0.0 0.0 5C.010 ®.® 10 0 Sheet of WELL DIAGRAM Completion Depth: E6f Date Boring Started: / Date Boring Completed: � 0 k Remorks: Engineer/Geologist:54�. Drilling Contractor: Revision DrownByFte Checked Approved Sheet of 2923 South Tryon Street -Suite 100 ■ � y' f Charlotte, North Carolina 28203 LOG AP ......1GNai. cORP--. 704-586-0007(p) 704-586-0373(o BORING: f-§ Project: Surface Elev: Job NO: Top of Casing Elev: Location: Drilling Rig/Method: Sampling Method: y C o O .c 0 >, aa) > MATERIAL DESCRIPTION SPT, Blow Counts a WELL DIAGRAM aa(DU) C v (The stratification lines represent approximate boundaries. The m to E � transition may be gradual.) D a- w Q ch m t¢ p � .. l¢`"'lam fig i Sri 4 O G, U 5 d. p,a Oarrt Ciu �(�r Gr 0 (j 10 15 20 25 34 35 40 5 Q Completion Depth: D Remarks: Date Boring Started: *-� �' Date Boring Completed: l Engineer/Geologist:G✓ —DrillingContractor: 3r Revision DrawnBy Date Checked Approved Sheet of 2923 South Tryon Strec'-suite 100 ffickffln Charlotte, North Carolina 28203 LOG OF BORING: Sq- A P..' C.---. 704-586-0007(p) 704-586-0373(o ... -.1 Project: Surface Elev. Job No: Top of Casing Elev: Location: Drilling Rig/Method: Sampling Method: W (D a, CL 76 -0 E E 4) MATERIAL DESCRIPTION SPT, Blow Counts CX a WELL DIAGRAM 0 CL 0 0 (The stratification lines represent approximate < > (D CL E V) 4) boundaries. The transition may be gradual.) 0 Cn < M J-aA 't',1VjyA Se' C' '0 5 - re —10- 15 -20- -25- -30- -35- -40- -45- -50 Completion Depth: Remarks: Date Boring Started: 0-1 �70 f Date Boring Completed: Engineer/Geologist: �?5'0 I --------- I I L Drilling Contractor: 1 t Revision DrawnBy Date Checked Approved Sheet of 311�1111i 2923 South Tryon Street -Suite 100 ft$aft Charlotte, North Carolina 28203 BORING: -- P........ LOG OF 704-58G-0007(p) t Cagr.....a 704-58G-0373(E) Project: Surface Elev: .lob No: Top of Casing Elev: Location: Drilling Rig/Method: Sampling Method: U � N L a O o >E, W _> MATERIAL DESCRIPTION SPT, Blow Counts a _.. .�,. WELL DIAGRAM _..._ _.. v a U (The stratification lines represent approximate a>i (D a- U a1 boundaries. The transition may be gradual.) > Q w o O 0 m v`ti 0-Q C 6/c,,, f ye1 t Gt (s 'J 1 10 BJ fi i C et k $tj 15 20 25 30 35 40 45 0 Completion Depth: 7t t Remarks: Date Boring Started: _ Date Boring Completed: Engineer/Geologist: (fit Drilling Contractor: CSr Revision DrawnBy Date Checked Approved Sheet of .off&IIjc Char Southo'h arolin Street -Suite �+ ^. . Charlotte, Nnnh Carolirm 28203 LOG OF BORING: A PaowecaaioNa� CoaF'aea'rrae.� iO4-SSG-O007(p) iO4-58G-03?3(E) tijd% Project: Surface Elev: Job No: Top of Casing Elev: Drilling Rig/Method: Location: Sampling Method: m a) 0 E o s E MATERIAL DESCRIPTION SPT, Blow Counts CL a- WELL DIAGRAM va v (The stratification lines represent approximate U boundaries. The transition may be gradual.) 8 w D m < 0 c°0 0,0 15 20 25 30 35 40 45 0 Completion Depth: Remarks: Date Boring Started: Date Boring Completed: Engineer/Geologist: Revision Drawn By Date I Checked Approved Drilling Contractor: Sheet of 2923 South Try— Street-Siute 100 �'% liWl Charlotte, North Carolina 28203LOG OF BORING: i i --I � Hickman df1111 1�11�i11II1711n A PROFc�,3totuA� CORPORATrJN 704-58G-0007(p) 704-586-0373(f) Project: Surface Elev: Job No: Top of Casing Elev: Drilling Rig/Method: Location: Sampling Method: N a) N C a -0 E a 0) MATERIAL DESCRIPTION SPT, Blow Counts 0- WELL DIAGRAM o s p 0) > 0 (The stratification lines represent approximate > 0 a Cam) � boundaries. The transition may be gradual.) w to m V) 0 t 11='01V 5011 10 15 20 25 30 35 0 5 0 Completion Depth: y Remarks: Date Boring Started: Dote Boring Completed: Engineer/Geologist: Revision Drawn By Date Checked Approved Drilling Contractor: Sheet of South Tryon Scree- 282 100 3 } 121c i Chad t Chadare, North Cazolina 373(LOG OF BORING: /% A PgOFE3510NH1- Caggoqnnoq 704-586-0007(p) 704-SSG0373(f) d,�„} Project: Surface Elev: Job NO: Top of Casing Elev: Location: Drilling Rig/Method: Sampling Method: .U- N C O 6 o � f�' o _ (n 0) MATERIAL DESCRIPTION SPT, Blow Counts a u WELL DIAGRAM o > a 0) 0 (The stratification lines represent approximate boundaries. The transition j V may be gradual.) p d W O = 2 Y 0] VV) � AA r i SY )-� 5�.{ 9 (i.0 EJ i i ili a f [-C.'iel,.C' d 10 G% 5CAAt if (' ,: r� l 15 t� 15 20 25 30 35 40 5 0 Completion Depth: i' �FY Date Boring Started: Remarks: Date Boring Completed: — Engineer/Geologist:MOO Drilling Contractor: Revision DrawnBy Date Checked Approved 2923 South Tryon Street -Suite 100 Sheet of ft$aft & ffickman Charlotte, North Carolina 28203■ A Pa ....... 704-586-0007(p) 704-586-0373(o LOG OF BORING: S13-j�, Project: Surface Elev: Job No: Top of Casing Elev: Location: Drilling Rig/Method: Sampling Method: V) 6 E E >1 V) Q) > MATERIAL DESCRIPTION SPT, Blow Counts 0- Cx WELL DIAGRAM > (D -a to 0 a) (The stratification- -lines represent approximate boundaries. The transition a E C-) ry may be gradual.) 0 UJ a ) VZ) 0- M U) I CtA py Sq^C4 V, 5 c 5 t 6,0 �vq C. (ay ---------------------- C). 9 'r`7 fe i 15 —20- -25- -30- -35- -40- -45- -50— Completion Depth: Date Boring Started: Remarks: Date Boring Completed: Engineer/Geologist: t Drilling Contractor: Revision lDrawnB,, nM. Checked Approved Sheet of on Street -Suite 2923 South TryBORING: L an Charlotte, North Carolina 28203LOG OF rnoress..—, a w�o vco-- 704-58G-0007(p) 704-586-0373(0 tR� Project: Surface Elev: Top of Casing Elev: Job No: Drilling Rig/Method: Location: Sampling Method: m Q3 N �- 0) CL C E o .0) - ° 0 >S w MATERIAL DESCRIPTION SPT, Blow Counts a � WELL DIAGRAM `y 0 (The stratification lines represent approximate Q > Q boundaries The transition may be gradual.) W p m U) 0 Iroyrcq 0,0 e7iMt 0-0 5 [ 6,0 0.0 10_� - 15 20 25 30 35 0 45 0 Completion Depth: Remarks: 101 Date Boring Started: _ Date Boring Completed:f Engineer/Geologist: Us,¢n% Revision Drawn By Dote Checked Appr Drillinoved Contractor: Sheet of 2923 South Tryon S re -suit. 100 ch.d.a., North Carolina 28203 ft$afl & Ifickman StLOG OF 4-17 ® 704-586-0007(p) 704-586-03-,3(o Project: Surface Elev: Job No: Top of Casing Elev: Drilling Rig/Method: Location: Sampling Method: rn -C O -6 E E >1 W MATERIAL DESCRIPTION SPT, Blow Counts 0- a- WELL DIAGRAM 2 0 CL U) > 0 0 (The stratification lines represent approximate 0 E Q) ry boundaries. The transition may be gradual.} 0 0 < 0 Is t, 0 .0 5 — . ..... . .... I- qAX L _10— _15- -20- -25- -30— _35- 40- -45- -50— Completion Depth: Remarks: Date Boring Started: Date Boring Completed: Engineer/Geologist: Drilling Contractor: Revision DrawnByDate I Checked Approved 2923 South Tryon Street -Suite 100 Charlotte, North Carolina 28203 A CORPORATION 704-586-0007(p) 704-586-0373(o Project: Job No: Location: W Q) (U 0 � I- rz Sheet of LOG OF BORING: S!?--20 Surface Elev: Top of Casing Elev: Drilling Rig/Method: Sampling Method: C: -e 0 >' iv MATERIAL DESCRIPTION .2 > 0 Q- 0 (The, stratification lines represent opproximatt > 0o 0 boundaries. The transition may be gradual,) Ld V) 0 Z) En lie-To,I — LI --- i a CL SPT, Blow Counts WELL DIAGRAM M C<n M Completion Depth: 0 Date Boring Started: Remarks: Date Boring Completed: 1 105- Engineer/Geologist:QSh.nn.n Co ilk__. 1�Alj Drilling Contractor: QRQLqdic ExpjorGtion—inc. USTI, Date Sheet of 2923 South `Tryon Street -Suite 100 Hickmdn Charlotte, North Carolina 28203 A PROFESSIONAL CORPORATION 704-586-0007(p) 704-586-0373(0 LOG OF BORING:■ -S9 Surface Elev: Project: Top of Casing Elev: Job No: Drilling Rig/Method: Location: Sampling Method: En -C 6 -0 r. E CF E (D MATERIAL DESCRIPTION SPT, Blow Counts C1 WELL DIAGRAM -C 0- Q) (n > 0 U (The stratification lines represent approximate > CD, -CL E V) 0 Q) C r boundaries., The transition may be gradual.) . a. v) :2 < b so;�tZ 1) 6, el, -5 - -10- -15- -20- -25- Completion Depth: Remarks: Date Boring Started: Date Boring Completed: Engineer/Geologist:.-e-o'ttri4-- Revision 1DrawnBy1 Date I Checked JApproved Drilling Contractor: Gil. _qLc_-Explrrrotfor;--1r1(- 2923 South *rryon Street -Suite 100 4"WHickman Sheet of Charlotte, North Carolina 28203 A R ......... c.--.. 704-586-(M7(p) 704-586-0373(o LOG OF BORING: Project: Surface Elev: Top of Casing Elev: Job No: Drilling Rig/Method: Location: Sampling Method: to Q3 E o > MATERIAL DESCRIPTION SPT, Blow Counts 0- WELL DIAGRAM (D V), 0 (The stratification lines represent approximate < Q) a -E 0- 0 boundaries. The -transition may be gradual.) LLJ < co V) 0- T-CiA -5 0,0 0 -0 -10- for 15 - 25- Completion Depth: Date Boring Started: Remarks: Date Boring Completed: Engineer/Geologist: 4,,�ttdll Drilling Contractor: , C Revision lDrciwnByl Date I Checked Approved Sheet of ' �n 2923 South'i93on Street -Suite 100 can Charlotte, North Carolina 28203 A PROFESSIONAL CORPORATION 704-586-0007(p) 704-586-0373(oLOG OF ° L• BORING. Surface Elev: Project: Top of Casing Etev: Job No: Drilling Rig/Method: Location: Sampling Method: ,a, to U ai s v 11 .. E o MATERIAL DESCRIPTION SPT, Blow Counts a WELL DIAGRAM o a i N (The stratification Lines represent approximate q _ �_.. a- U_ boundaries. The transition may be gradual.) to w o ul Y Ca x2di"3 �d';f 9tT*y J f � (1 C) 5 [�J sµt�(,(�¢g t- 10 e a. 15 20 25 Completion Depth: P Remarks: Date Boring Started: �r Dote Boring Completed: Engineer/Geologist: n-Ge +tL i Y, Drilling Contractor: CC _ �eplpacEr lawki ktc. Revision DrawnBy Date Checked Approved Appendix B Laboratory Analytical Data hart hickman SMARTER ENVIRONMENTAL SOLLMONS NC Certification No. 402 SC Certification No. 99012 Case Narrative PRISM Full -Service Analytical & NC Drinkinq Water Cert No. 37735 07/22/2015 Environmental Solutions VA Certification No. 460211 ,om`. LABORATORIES, INC. DOD ELAP: L-A-B Accredited Certificate No. L2307 ISO/IEC 17025: L-A-B Accredited Certificate No. L2307 Hart & Hickman (Charlotte) Project: PTR.001-3A Aaron Oswald 2923 South Tryon St. Ste 100 Lab Submittal Date: 07/10/2015 Charlotte, NC 28203 Prism Work Order: 5070165 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. a,j Angela D. Overcash VP Laboratory Services Data Qualifiers Key Reference: Reviewed By Terri W. Cole For Angela D. Overcash Project Manager A LCS/LCSD result is below the control limits. CCV recovery within the limits. Analyte not detected in the sample down to the MDL. No further action taken. D RPD value outside of the control limits. H1 Analysis within hold time from preserved vial. L2 LCSD recovery outside of the QC limits. LCS recovery within the limits. No further action taken. M Matrix spike outside of the control limits. MC Sample concentration too high for recovery evaluation. MI Matrix spike outside of the control limits. Matrix interference suspected. SR Surrogate recovery outside the QC limits. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 80 /P R I S M Full -Service Analytical Environmental Solutions LABORATORIES INC. Sample Receipt Summary 07/22/2015 Prism Work Order: 5070165 Client Sample ID Lab Sample ID Matrix Date Sampled Date Received SB-1 (2-4) 5070165-01 Solid 07/07/15 07/10/15 SB-2 (0-2) 5070165-02 Solid 07/08/15 07/10/15 Dup-1 5070165-03 Solid 07/07/15 07/10/15 TMW-1 5070165-04 Water 07/09/15 07/10/15 TMW-2 5070165-05 Water 07/07/15 07/10/15 TMW-3 5070165-06 Water 07/07/15 07/10/15 TMW-4 5070165-07 Water 07/08/15 07/10/15 Dup-1 5070165-08 Water 07/07/15 07/10/15 Trip Blank 5070165-09 Water 07/09/15 07/10/15 Samples were received in good condition at 4.7 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 80 A&P R I S M Full Service Analytical & Environmental Solutions 1LABORATORIES, INC. Summary of Detections 07/22/2015 Prism Work Order: 5070165 Prism ID Client ID Parameter Method Result Units 5070165-01 SB-1 (2-4) 1-Methylnaphthalene `8270D 0.54 mg/kg dry 5070165-01 SB-1 (2-4) 2-Methylnaphthalene '8270D 0.83 mg/kg dry 5070165-01 SB-1 (2-4) Benzo(a)anthracene '8270D 0.48 mg/kg dry 5070165-01 SB-1 (2-4) Benzo(a)pyrene `8270D 0.51 mg/kg dry 5070165-01 SB-1 (2-4) Benzo(b)fluoranthene '8270D 0.79 mg/kg dry 5070165-01 SB-1 (2-4) Benzo(g,h,i)perylene "8270D 0.42 mg/kg dry 5070165-01 SB-1 (2-4) Chrysene '8270D 0.59 mg/kg dry 5070165-01 SB-1 (2-4) Fluoranthene `8270D 0.81 mg/kg dry 5070165-01 SB-1 (2-4) Naphthalene '8270D 0.57 mg/kg dry 5070165-01 SB-1 (2-4) Phenanthrene '8270D 0.81 mg/kg dry 5070165-01 SB-1 (2-4) Pyrene `8270D 0.84 mg/kg dry 5070165-01 SB-1 (2-4) Mercury *7471B 0.30 mg/kg dry 5070165-01 SB-1 (2-4) Arsenic "6010C 77 mg/kg dry 5070165-01 SB-1 (2-4) Barium '6010C 150 mg/kg dry 5070165-01 SB-1 (2-4) Cadmium `6010C 0.59 mg/kg dry 5070165-01 SB-1 (2-4) Chromium "6010C 35 mg/kg dry 5070165-01 SB-1 (2-4) Lead '6010C 230 mg/kg dry 5070165-01 SB-1 (2-4) Acetone '8260B 0.070 mg/kg dry 5070165-02 SB-2 (0-2) Fluoranthene '8270D 0.54 mg/kg dry 5070165-02 SB-2 (0-2) Pyrene "8270D 0.50 mg/kg dry 5070165-02 SB-2(0-2) Mercury `7471B 0.12 mg/kg dry 5070165-02 SB-2 (0-2) Arsenic '6010C 4.8 mg/kg dry 5070165-02 SB-2 (0-2) Barium "6010C 61 mg/kg dry 5070165-02 SB-2 (0-2) Chromium '6010C 28 mg/kg dry 5070165-02 SB-2 (0-2) Lead `6010C 47 mg/kg dry 5070165-02 SB-2 (0-2) Acetone *8260B 0.090 mg/kg dry 5070165-03 Dup-1 Benzo(a)anthracene '8270D 0.57 mg/kg dry 5070165-03 Dup-1 Benzo(a)pyrene `8270D 0.72 mg/kg dry 5070165-03 Dup-1 Benzo(b)fluoranthene '8270D 1.1 mg/kg dry 5070165-03 Dup-1 Benzo(g,h,i)perylene "8270D 0.64 mg/kg dry 5070165-03 Dup-1 Chrysene '8270D 0.72 mg/kg dry 5070165-03 Dup-1 Fluoranthene `8270D 1.5 mg/kg dry 5070165-03 Dup-1 Indeno(1,2,3-cd)pyrene '8270D 0.61 mg/kg dry 5070165-03 Dup-1 Phenanthrene '8270D 0.79 mg/kg dry 5070165-03 Dup-1 Pyrene `8270D 1.3 mg/kg dry 5070165-03 Dup-1 Mercury *7471B 0.088 mg/kg dry 5070165-03 Dup-1 Arsenic "6010C 4.4 mg/kg dry 5070165-03 Dup-1 Barium '6010C 85 mg/kg dry 5070165-03 Dup-1 Chromium `6010C 33 mg/kg dry 5070165-03 Dup-1 Lead "6010C 52 mg/kg dry 5070165-03 Dup-1 Acetone *8260B 0.10 mg/kg dry 5070165-04 TMW-1 1,1-Dichloroethane '8260B 11 ug/L 5070165-04 TMW-1 1,1-Dichloroethylene *8260B 4.0 ug/L 5070165-04 TMW-1 Chloroform *8260B 0.80 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 80 /,GA1P-R I S M Full -Service Analytical Environmental Solutions LABORATORIES, ING Summary of Detections 07/22/2015 Prism Work Order: 5070165 Prism ID Client ID Parameter Method Result Units 5070165-04 TMW-1 cis- 1,2-Dichloroethylene "8260B 1.7 ug/L 5070165-04 TMW-1 Isopropyl Ether *8260B 0.80 ug/L 5070165-04 TMW-1 Tetrachloroethylene `8260B 290 H1 ug/L 5070165-04 TMW-1 Trichloroethylene '8260B 3.4 ug/L 5070165-05 TMW-2 Naphthalene "8270D 22 ug/L 5070165-05 TMW-2 Isopropyl Ether *826013 0.56 ug/L 5070165-05 TMW-2 Naphthalene '8260B 28 ug/L 5070165-05 TMW-2 Tetrachloroethylene "8260B 25 ug/L 5070165-05 TMW-2 Trichloroethylene *8260B 0.80 ug/L 5070165-06 TMW-3 Chloroform '8260B 2.2 ug/L 5070165-06 TMW-3 Tetrachloroethylene *8260B 5.4 ug/L 5070165-07 TMW-4 Barium "6010C 0.19 mg/L 5070165-07 TMW-4 1,1-Dichloroethane `8260B 1.7 ug/L 5070165-07 TMW-4 1,1-Dichloroethylene '8260B 0.94 ug/L 5070165-07 TMW-4 Tetrachloroethylene *8260B 15 ug/L 5070165-07 TMW-4 Trichloroethylene "8260B 1.0 ug/L 5070165-08 Dup-1 1,1-Dichloroethane '8260B 11 ug/L 5070165-08 Dup-1 1,1-Dichloroethylene *8260B 4.1 ug/L 5070165-08 Dup-1 Chloroform *8260B 0.75 ug/L 5070165-08 Dup-1 cis- 1,2-Dichloroethylene `8260B 1.6 ug/L 5070165-08 Dup-1 Isopropyl Ether '8260B 0.77 ug/L 5070165-08 Dup-1 Tetrachloroethylene *8260B 260 H1 ug/L 5070165-08 Dup-1 Trichloroethylene *8260B 3.3 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 80 P R S M Laboratory Report ` Full -Service Analytical & / Environmental Solutions 07/22/2015 LABORATORIES INC. Hart & Hickman (Charlotte) Project: PTR.001-3A Client Sample ID: SB-1 (2-4) Attn: Aaron Oswald Prism Sample ID: 5070165-01 2923 South Tryon St. Ste 100 Prism Work Order: 5070165 Charlotte, NC 28203 Sample Matrix: Solid Time Collected: 07/07/15 10:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters % Solids 78.6 % by 0.100 0.100 1 *SM2540 G 7/13/15 11:55 ARC P5G0176 Weight Semivolatile Organic Compounds by GC/MS 1,2,4-Trichlorobenzene BRL mg/kg dry 0.42 0.065 1 *8270D 7/14/15 0:03 JMV P5G0175 1,2-Dichlorobenzene BRL mg/kg dry 0.42 0.064 1 *8270D 7/14/15 0:03 JMV P5G0175 1,3-Dichlorobenzene BRL mg/kg dry 0.42 0.059 1 *8270D 7/14/15 0:03 JMV P5G0175 1,4-Dichlorobenzene BRL mg/kg dry 0.42 0.061 1 *8270D 7/14/15 0:03 JMV P5G0175 1-Methyl naphthalene 0.54 mg/kg dry 0.42 0.081 1 *8270D 7/14/15 0:03 JMV P5G0175 2,4,6-Trichlorophenol BRL mg/kg dry 0.42 0.079 1 *8270D 7/14/15 0:03 JMV P5G0175 2,4-Dichlorophenol BRL mg/kg dry 0.42 0.081 1 *8270D 7/14/15 0:03 JMV P5G0175 2,4-Dimethylphenol BRL mg/kg dry 0.42 0.064 1 *8270D 7/14/15 0:03 JMV P5G0175 2,4-Dinitrophenol BRL mg/kg dry 0.42 0.059 1 *8270D 7/14/15 0:03 JMV P5G0175 2,4-Dinitrotoluene BRL mg/kg dry 0.42 0.051 1 *8270D 7/14/15 0:03 JMV P5G0175 2,6-Dinitrotoluene BRL mg/kg dry 0.42 0.056 1 *8270D 7/14/15 0:03 JMV P5G0175 2-Chloronaphthalene BRL mg/kg dry 0.42 0.061 1 *8270D 7/14/15 0:03 JMV P5G0175 2-Chlorophenol BRL mg/kg dry 0.42 0.059 1 *8270D 7/14/15 0:03 JMV P5G0175 2-Methyl naphthalene 0.83 mg/kg dry 0.42 0.067 1 *8270D 7/14/15 0:03 JMV P5G0175 2-Methylphenol BRL mg/kg dry 0.42 0.054 1 *8270D 7/14/15 0:03 JMV P5G0175 2-Nitrophenol BRL mg/kg dry 0.42 0.076 1 *8270D 7/14/15 0:03 JMV P5G0175 3,3'-Dichlorobenzidine BRL mg/kg dry 0.42 0.083 1 *8270D 7/14/15 0:03 JMV P5G0175 3/4-Methyl phenol BRL mg/kg dry 0.42 0.052 1 *8270D 7/14/15 0:03 JMV P5G0175 4,6-Dinitro-2-methylphenol BRL mg/kg dry 0.42 0.063 1 *8270D 7/14/15 0:03 JMV P5G0175 4-Bromophenyl phenyl ether BRL mg/kg dry 0.42 0.072 1 *8270D 7/14/15 0:03 JMV P5G0175 4-Chloro-3-methylphenol BRL mg/kg dry 0.42 0.059 1 *8270D 7/14/15 0:03 JMV P5G0175 4-Chloroaniline BRL mg/kg dry 0.42 0.050 1 *8270D 7/14/15 0:03 JMV P5G0175 4-Chlorophenyl phenyl ether BRL mg/kg dry 0.42 0.055 1 *8270D 7/14/15 0:03 JMV P5G0175 4-Nitrophenol BRL mg/kg dry 0.42 0.065 1 *8270D 7/14/15 0:03 JMV P5G0175 Acenaphthene BRL mg/kg dry 0.42 0.057 1 *8270D 7/14/15 0:03 JMV P5G0175 Acenaphthylene BRL mg/kg dry 0.42 0.061 1 *8270D 7/14/15 0:03 JMV P5G0175 Anthracene BRL mg/kg dry 0.42 0.068 1 *8270D 7/14/15 0:03 JMV P5G0175 Azobenzene BRL mg/kg dry 0.42 0.055 1 *8270D 7/14/15 0:03 JMV P5G0175 Benzo(a)anthracene 0.48 mg/kg dry 0.42 0.055 1 *8270D 7/14/15 0:03 JMV P5G0175 Benzo(a)pyrene 0.51 mg/kg dry 0.42 0.045 1 *8270D 7/14/15 0:03 JMV P5G0175 Benzo(b)fluoranthene 0.79 mg/kg dry 0.42 0.049 1 *8270D 7/14/15 0:03 JMV P5G0175 Benzo(g,h,i)perylene 0.42 mg/kg dry 0.42 0.046 1 *8270D 7/14/15 0:03 JMV P5G0175 Benzo(k)fluoranthene BRL mg/kg dry 0.42 0.055 1 *8270D 7/14/15 0:03 JMV P5G0175 Benzoic Acid BRL mg/kg dry 0.42 0.035 1 *8270D 7/14/15 0:03 JMV P5G0175 Benzyl alcohol BRL mg/kg dry 0.42 0.055 1 *8270D 7/14/15 0:03 JMV P5G0175 bis(2-Chloroethoxy)methane BRL mg/kg dry 0.42 0.073 1 *8270D 7/14/15 0:03 JMV P5G0175 Bis(2-Chloroethyl)ether BRL mg/kg dry 0.42 0.059 1 *8270D 7/14/15 0:03 JMV P5G0175 Bis(2-chloroisopropyl)ether BRL mg/kg dry 0.42 0.072 1 *8270D 7/14/15 0:03 JMV P5G0175 Bis(2-Ethylhexyl)phthalate BRL mg/kg dry 0.42 0.062 1 *8270D 7/14/15 0:03 JMV P5G0175 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 80 Laboratory Report ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. 07/22/2015 Hart & Hickman (Charlotte) Project: PTR.001-3A Client Sample ID: SB-1 (2-4) Attn: Aaron Oswald Prism Sample ID: 5070165-01 2923 South Tryon St. Ste 100 Prism Work Order: 5070165 Charlotte, NC 28203 Sample Matrix: Solid Time Collected: 07/07/15 10:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Butyl benzyl phthalate BRL mg/kg dry 0.42 0.060 1 *8270D 7/14/15 0:03 JMV P5G0175 Chrysene 0.59 mg/kg dry 0.42 0.053 1 *8270D 7114/15 0:03 JMV P5G0175 Dibenzo(a,h)anthracene BRL mg/kg dry 0.42 0.051 1 *8270D 7/14/15 0:03 JMV P5G0175 Dibenzofuran BRL mg/kg dry 0.42 0.064 1 *8270D 7/14/15 0:03 JMV P5G0175 Diethyl phthalate BRL mg/kg dry 0.42 0.058 1 *8270D 7/14/15 0:03 JMV P5G0175 Dimethyl phthalate BRL mg/kg dry 0.42 0.055 1 *8270D 7/14/15 0:03 JMV P5G0175 Di-n-butyl phthalate BRL mg/kg dry 0.42 0.060 1 *8270D 7/14/15 0:03 JMV P5G0175 Di-n-octyl phthalate BRL mg/kg dry 0.42 0.052 1 *8270D 7/14/15 0:03 JMV P5G0175 Fluoranthene 0.81 mg/kg dry 0.42 0.054 1 *8270D 7/14/15 0:03 JMV P5G0175 Fluorene BRL mg/kg dry 0.42 0.060 1 *8270D 7/14/15 0:03 JMV P5G0175 Hexachlorobenzene BRL mg/kg dry 0.42 0.067 1 *8270D 7/14/15 0:03 JMV P5G0175 Hexachlorobutadiene BRL mg/kg dry 0.42 0.075 1 *8270D 7/14/15 0:03 JMV P5G0175 Hexachlorocyclopentadiene BRL mg/kg dry 0.42 0.075 1 *8270D 7/14/15 0:03 JMV P5G0175 Hexachloroethane BRL mg/kg dry 0.42 0.070 1 *8270D 7/14/15 0:03 JMV P5G0175 Indeno(1,2,3-cd)pyrene BRL mg/kg dry 0.42 0.048 1 *8270D 7/14/15 0:03 JMV P5G0175 Isophorone BRL mg/kg dry 0.42 0.057 1 *8270D 7/14/15 0:03 JMV P5G0175 Naphthalene 0.57 mg/kg dry 0.42 0.067 1 *8270D 7/14/15 0:03 JMV P5G0175 Nitrobenzene BRL mg/kg dry 0.42 0.060 1 *8270D 7/14/15 0:03 JMV P5G0175 N-Nitroso-di-n-propylamine BRL mg/kg dry 0.42 0.066 1 *8270D 7/14/15 0:03 JMV P5G0175 N-Nitrosodiphenylamine BRL mg/kg dry 0.42 0.064 1 *8270D 7/14/15 0:03 JMV P5G0175 Pentachlorophenol BRL mg/kg dry 0.42 0.050 1 *8270D 7/14/15 0:03 JMV P5G0175 Phenanthrene 0.81 mg/kg dry 0.42 0.055 1 *8270D 7/14/15 0:03 JMV P5G0175 Phenol BRL mg/kg dry 0.42 0.062 1 *8270D 7/14/15 0:03 JMV P5G0175 Pyrene 0.84 mg/kg dry 0.42 0.056 1 *8270D 7/14/15 0:03 JMV P5G0175 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 105 % 39-132 2-Fluorobiphenyl 92 % 44-115 2-Fluorophenol 82 % 35-115 Nitrobenzene-d5 83 % 37-122 Phenol-d5 80 % 34-121 Terphenyl-d14 97 % 54-127 Total Metals Mercury 0.30 mg/kg dry 0.025 0.0016 1 *7471B 7113/15 13:08 JAB P5G0173 Arsenic 77 mg/kg dry 0.31 0.044 1 *6010C 7/13/15 18:16 BGM P5G0172 Barium 150 mg/kg dry 0.62 0.12 1 *6010C 7/13/15 18:16 BGM P5G0172 Cadmium 0.59 mg/kg dry 0.31 0.044 1 *6010C 7113/15 18:16 BGM P5G0172 Chromium 35 mg/kg dry 0.31 0.051 1 *6010C 7/13/15 18:16 BGM P5G0172 Lead 230 mg/kg dry 0.31 0.047 1 *6010C 7/13/15 18:16 BGM P5G0172 Selenium BRL mg/kg dry 0.62 0.075 1 *6010C 7/13/15 18:16 BGM P5G0172 Silver BRL mg/kg dry 0.31 0.036 1 *6010C 7/13/15 18:16 BGM P5G0172 Volatile Organic Compounds by Gil 1,1,1,2-Tetrachloroethane BRL mg/kg dry 0.0057 0.00047 1 *8260B 7/16/15 18:28 MSC P5G0262 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 6 of 80 ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-3A Sample Matrix: Solid Laboratory Report 07/22/2015 Client Sample ID: SB-1 (2-4) Prism Sample ID: 5070165-01 Prism Work Order: 5070165 Time Collected: 07/07/15 10:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,1,1-Trichloroethane BRL mg/kg dry 0.0057 0.00027 1 *8260B 7/16/15 18:28 MSC P5G0262 1,1,2,2-Tetrachloroethane BRL mg/kg dry 0.0057 0.00038 1 *8260B 7/16/15 18:28 MSC P5G0262 1,1,2-Trichloroethane BRL mg/kg dry 0.0057 0.00050 1 *8260B 7/16/15 18:28 MSC P5G0262 1,1-Dichloroethane BRL mg/kg dry 0.0057 0.00016 1 *8260B 7/16/15 18:28 MSC P5G0262 1,1-Dichloroethylene BRL mg/kg dry 0.0057 0.00025 1 *8260B 7/16/15 18:28 MSC P5G0262 1,1-Dichloropropylene BRL mg/kg dry 0.0057 0.00031 1 *8260B 7/16/15 18:28 MSC P5G0262 1,2,3-Trichlorobenzene BRL mg/kg dry 0.0057 0.00032 1 *8260B 7/16/15 18:28 MSC P5G0262 1,2,3-Trichloropropane BRL mg/kg dry 0.0057 0.00072 1 *8260B 7/16/15 18:28 MSC P5G0262 1,2,4-Trichlorobenzene BRL mg/kg dry 0.0057 0.00042 1 *8260B 7/16/15 18:28 MSC P5G0262 1,2,4-Trimethyl benzene BRL mg/kg dry 0.0057 0.00043 1 *8260B 7/16/15 18:28 MSC P5G0262 1,2-Dibromoethane BRL mg/kg dry 0.0057 0.00023 1 *8260B 7/16/15 18:28 MSC P5G0262 1,2-Dichlorobenzene BRL mg/kg dry 0.0057 0.00027 1 *8260B 7/16/15 18:28 MSC P5G0262 1,2-Dichloroethane BRL mg/kg dry 0.0057 0.00034 1 *8260B 7/16/15 18:28 MSC P5G0262 1,2-Dichloropropane BRL mg/kg dry 0.0057 0.00035 1 *8260B 7/16/15 18:28 MSC P5G0262 1,3,5-Trimethyl benzene BRL mg/kg dry 0.0057 0.00043 1 *8260B 7/16/15 18:28 MSC P5G0262 1,3-Dichlorobenzene BRL mg/kg dry 0.0057 0.00038 1 *8260B 7/16/15 18:28 MSC P5G0262 1,3-Dichloropropane BRL mg/kg dry 0.0057 0.00028 1 *8260B 7/16/15 18:28 MSC P5G0262 1,4-Dichlorobenzene BRL mg/kg dry 0.0057 0.00022 1 *8260B 7/16/15 18:28 MSC P5G0262 2,2-Dichloropropane BRL mg/kg dry 0.0057 0.00027 1 *8260B 7/16/15 18:28 MSC P5G0262 2-Chlorotoluene BRL mg/kg dry 0.0057 0.00029 1 *8260B 7/16/15 18:28 MSC P5G0262 4-Chlorotoluene BRL mg/kg dry 0.0057 0.00034 1 *8260B 7/16/15 18:28 MSC P5G0262 4-Isopropyltoluene BRL mg/kg dry 0.0057 0.00027 1 *8260B 7/16/15 18:28 MSC P5G0262 Acetone 0.070 mg/kg dry 0.057 0.0014 1 *8260B 7/16/15 18:28 MSC P5G0262 Benzene BRL mg/kg dry 0.0034 0.00033 1 *8260B 7/16/15 18:28 MSC P5G0262 Bromobenzene BRL mg/kg dry 0.0057 0.00047 1 *8260B 7/16/15 18:28 MSC P5G0262 Bromochloromethane BRL mg/kg dry 0.0057 0.00031 1 *8260B 7/16/15 18:28 MSC P5G0262 Bromodichloromethane BRL mg/kg dry 0.0057 0.00032 1 *8260B 7/16/15 18:28 MSC P5G0262 Bromoform BRL mg/kg dry 0.0057 0.00064 1 *8260B 7/16/15 18:28 MSC P5G0262 Bromomethane BRL mg/kg dry 0.011 0.00070 1 *8260B 7/16/15 18:28 MSC P5G0262 Carbon Tetrachloride BRL mg/kg dry 0.0057 0.00028 1 *8260B 7/16/15 18:28 MSC P5G0262 Chlorobenzene BRL mg/kg dry 0.0057 0.00030 1 *8260B 7/16/15 18:28 MSC P5G0262 Chloroethane BRL mg/kg dry 0.011 0.00047 1 *8260B 7/16/15 18:28 MSC P5G0262 Chloroform BRL mg/kg dry 0.0057 0.00041 1 *8260B 7/16/15 18:28 MSC P5G0262 Chloromethane BRL mg/kg dry 0.0057 0.00038 1 *8260B 7/16/15 18:28 MSC P5G0262 cis-1,2-Dichloroethylene BRL mg/kg dry 0.0057 0.00024 1 *8260B 7/16/15 18:28 MSC P5G0262 cis-1,3-Dichloropropylene BRL mg/kg dry 0.0057 0.00019 1 *8260B 7/16/15 18:28 MSC P5G0262 Dibromochloromethane BRL mg/kg dry 0.0057 0.00023 1 *8260B 7/16/15 18:28 MSC P5G0262 Dichlorodifluoromethane BRL mg/kg dry 0.0057 0.00026 1 *8260B 7/16/15 18:28 MSC P5G0262 Ethylbenzene BRL mg/kg dry 0.0057 0.00022 1 *8260B 7/16/15 18:28 MSC P5G0262 Isopropyl Ether BRL mg/kg dry 0.0057 0.00023 1 *8260B 7/16/15 18:28 MSC P5G0262 Isopropylbenzene (Cumene) BRL mg/kg dry 0.0057 0.00034 1 *8260B 7/16/15 18:28 MSC P5G0262 m,p-Xylenes BRL mg/kg dry 0.011 0.00052 1 *8260B 7/16/15 18:28 MSC P5G0262 Methyl Butyl Ketone (2-Hexanone) BRL mg/kg dry 0.057 0.00051 1 *8260B 7/16/15 18:28 MSC P5G0262 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 7 of 80 P R S M Laboratory Report ` Full -Service Analytical & / Environmental Solutions 07/22/2015 LABORATORIES INC. Hart & Hickman (Charlotte) Project: PTR.001-3A Client Sample ID: SB-1 (2-4) Attn: Aaron Oswald Prism Sample ID: 5070165-01 2923 South Tryon St. Ste 100 Prism Work Order: 5070165 Charlotte, NC 28203 Sample Matrix: Solid Time Collected: 07/07/15 10:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID Methyl Ethyl Ketone (2-Butanone) BRL mg/kg dry 0.11 0.00051 1 *8260B 7/16/15 18:28 MSC P5G0262 Methyl Isobutyl Ketone BRL mg/kg dry 0.057 0.00048 1 *8260B 7/16/15 18:28 MSC P5G0262 Methylene Chloride BRL mg/kg dry 0.0057 0.00032 1 *8260B 7/16/15 18:28 MSC P5G0262 Methyl-tert-Butyl Ether BRL mg/kg dry 0.011 0.00018 1 *8260B 7/16/15 18:28 MSC P5G0262 Naphthalene BRL mg/kg dry 0.011 0.00018 1 *8260B 7/16/15 18:28 MSC P5G0262 n-Butylbenzene BRL mg/kg dry 0.0057 0.00029 1 *8260B 7/16/15 18:28 MSC P5G0262 n-Propylbenzene BRL mg/kg dry 0.0057 0.00034 1 *8260B 7/16/15 18:28 MSC P5G0262 o-Xylene BRL mg/kg dry 0.0057 0.00023 1 *8260B 7/16/15 18:28 MSC P5G0262 sec-Butylbenzene BRL mg/kg dry 0.0057 0.00027 1 *8260B 7/16/15 18:28 MSC P5G0262 Styrene BRL mg/kg dry 0.0057 0.00034 1 *8260B 7/16/15 18:28 MSC P5G0262 tert-Butylbenzene BRL mg/kg dry 0.0057 0.00019 1 *8260B 7/16/15 18:28 MSC P5G0262 Tetrachloroethylene BRL mg/kg dry 0.0057 0.00027 1 *8260B 7/16/15 18:28 MSC P5G0262 Toluene BRL mg/kg dry 0.0057 0.00033 1 *8260B 7/16/15 18:28 MSC P5G0262 trans-1,2-Dichloroethylene BRL mg/kg dry 0.0057 0.00034 1 *8260B 7/16/15 18:28 MSC P5G0262 trans-1,3-Dichloropropylene BRL mg/kg dry 0.0057 0.00030 1 *8260B 7/16/15 18:28 MSC P5G0262 Trichloroethylene BRL mg/kg dry 0.0057 0.00037 1 *8260B 7/16/15 18:28 MSC P5G0262 Trichlorofluoromethane BRL mg/kg dry 0.0057 0.00037 1 *8260B 7/16/15 18:28 MSC P5G0262 Vinyl acetate BRL A mg/kg dry 0.028 0.00078 1 *8260B 7/16/15 18:28 MSC P5G0262 Vinyl chloride BRL mg/kg dry 0.0057 0.00027 1 *8260B 7/16/15 18:28 MSC P5G0262 Xylenes, total BRL mg/kg dry 0.017 0.0011 1 *8260B 7/16/15 18:28 MSC P5G0262 Surrogate Recovery Control Limits 4-Bromofluorobenzene 136 % 70-130 SR Dibromofluoromethane 107 % 84-123 Toluene-d8 112 % 76-129 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 8 of 80 P R S M Laboratory Report ` Full -Service Analytical & / Environmental Solutions 07/22/2015 LABORATORIES INC. Hart & Hickman (Charlotte) Project: PTR.001-3A Client Sample ID: SB-2 (0-2) Attn: Aaron Oswald Prism Sample ID: 5070165-02 2923 South Tryon St. Ste 100 Prism Work Order: 5070165 Charlotte, NC 28203 Sample Matrix: Solid Time Collected: 07/08/15 09:35 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters % Solids 72.9 % by 0.100 0.100 1 *SM2540 G 7/13/15 11:55 ARC P5G0176 Weight Semivolatile Organic Compounds by GC/MS 1,2,4-Trichlorobenzene BRL mg/kg dry 0.45 0.071 1 *8270D 7/13/15 22:37 JMV P5G0175 1,2-Dichlorobenzene BRL mg/kg dry 0.45 0.069 1 *8270D 7/13/15 22:37 JMV P5G0175 1,3-Dichlorobenzene BRL mg/kg dry 0.45 0.064 1 *8270D 7/13/15 22:37 JMV P5G0175 1,4-Dichlorobenzene BRL mg/kg dry 0.45 0.066 1 *8270D 7/13/15 22:37 JMV P5G0175 1-Methyl naphthalene BRL mg/kg dry 0.45 0.087 1 *8270D 7/13/15 22:37 JMV P5G0175 2,4,6-Trichlorophenol BRL mg/kg dry 0.45 0.085 1 *8270D 7/13/15 22:37 JMV P5G0175 2,4-Dichlorophenol BRL mg/kg dry 0.45 0.088 1 *8270D 7/13/15 22:37 JMV P5G0175 2,4-Dimethylphenol BRL mg/kg dry 0.45 0.069 1 *8270D 7/13/15 22:37 JMV P5G0175 2,4-Dinitrophenol BRL mg/kg dry 0.45 0.063 1 *8270D 7/13/15 22:37 JMV P5G0175 2,4-Dinitrotoluene BRL mg/kg dry 0.45 0.055 1 *8270D 7/13/15 22:37 JMV P5G0175 2,6-Dinitrotoluene BRL mg/kg dry 0.45 0.060 1 *8270D 7/13/15 22:37 JMV P5G0175 2-Chloronaphthalene BRL mg/kg dry 0.45 0.066 1 *8270D 7/13/15 22:37 JMV P5G0175 2-Chlorophenol BRL mg/kg dry 0.45 0.064 1 *8270D 7/13/15 22:37 JMV P5G0175 2-Methyl naphthalene BRL mg/kg dry 0.45 0.072 1 *8270D 7/13/15 22:37 JMV P5G0175 2-Methylphenol BRL mg/kg dry 0.45 0.058 1 *8270D 7/13/15 22:37 JMV P5G0175 2-Nitrophenol BRL mg/kg dry 0.45 0.082 1 *8270D 7/13/15 22:37 JMV P5G0175 3,3'-Dichlorobenzidine BRL mg/kg dry 0.45 0.089 1 *8270D 7/13/15 22:37 JMV P5G0175 3/4-Methyl phenol BRL mg/kg dry 0.45 0.056 1 *8270D 7/13/15 22:37 JMV P5G0175 4,6-Dinitro-2-methylphenol BRL mg/kg dry 0.45 0.068 1 *8270D 7/13/15 22:37 JMV P5G0175 4-Bromophenyl phenyl ether BRL mg/kg dry 0.45 0.078 1 *8270D 7/13/15 22:37 JMV P5G0175 4-Chloro-3-methylphenol BRL mg/kg dry 0.45 0.064 1 *8270D 7/13/15 22:37 JMV P5G0175 4-Chloroaniline BRL mg/kg dry 0.45 0.054 1 *8270D 7/13/15 22:37 JMV P5G0175 4-Chlorophenyl phenyl ether BRL mg/kg dry 0.45 0.059 1 *8270D 7/13/15 22:37 JMV P5G0175 4-Nitrophenol BRL mg/kg dry 0.45 0.070 1 *8270D 7/13/15 22:37 JMV P5G0175 Acenaphthene BRL mg/kg dry 0.45 0.062 1 *8270D 7/13/15 22:37 JMV P5G0175 Acenaphthylene BRL mg/kg dry 0.45 0.066 1 *8270D 7/13/15 22:37 JMV P5G0175 Anthracene BRL mg/kg dry 0.45 0.073 1 *8270D 7/13/15 22:37 JMV P5G0175 Azobenzene BRL mg/kg dry 0.45 0.060 1 *8270D 7/13/15 22:37 JMV P5G0175 Benzo(a)anthracene BRL mg/kg dry 0.45 0.059 1 *8270D 7/13/15 22:37 JMV P5G0175 Benzo(a)pyrene BRL mg/kg dry 0.45 0.049 1 *8270D 7/13/15 22:37 JMV P5G0175 Benzo(b)fluoranthene BRL mg/kg dry 0.45 0.053 1 *8270D 7/13/15 22:37 JMV P5G0175 Benzo(g,hJ)perylene BRL mg/kg dry 0.45 0.050 1 *8270D 7/13/15 22:37 JMV P5G0175 Benzo(k)fluoranthene BRL mg/kg dry 0.45 0.059 1 *8270D 7/13/15 22:37 JMV P5G0175 Benzoic Acid BRL mg/kg dry 0.45 0.038 1 *8270D 7/13/15 22:37 JMV P5G0175 Benzyl alcohol BRL mg/kg dry 0.45 0.060 1 *8270D 7/13/15 22:37 JMV P5G0175 bis(2-Chloroethoxy)methane BRL mg/kg dry 0.45 0.079 1 *8270D 7/13/15 22:37 JMV P5G0175 Bis(2-Chloroethyl)ether BRL mg/kg dry 0.45 0.064 1 *8270D 7/13/15 22:37 JMV P5G0175 Bis(2-chloroisopropyl)ether BRL mg/kg dry 0.45 0.077 1 *8270D 7/13/15 22:37 JMV P5G0175 Bis(2-Ethylhexyl)phthalate BRL mg/kg dry 0.45 0.067 1 *8270D 7/13/15 22:37 JMV P5G0175 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 9 of 80 Laboratory Report ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. 07/22/2015 Hart & Hickman (Charlotte) Project: PTR.001-3A Client Sample ID: SB-2 (0-2) Attn: Aaron Oswald Prism Sample ID: 5070165-02 2923 South Tryon St. Ste 100 Prism Work Order: 5070165 Charlotte, NC 28203 Sample Matrix: Solid Time Collected: 07/08/15 09:35 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Butyl benzyl phthalate BRL mg/kg dry 0.45 0.064 1 *8270D 7/13/15 22:37 JMV P5G0175 Chrysene BRL mg/kg dry 0.45 0.057 1 *8270D 7/13/15 22:37 JMV P5G0175 Dibenzo(a,h)anthracene BRL mg/kg dry 0.45 0.055 1 *8270D 7/13/15 22:37 JMV P5G0175 Dibenzofuran BRL mg/kg dry 0.45 0.069 1 *8270D 7/13/15 22:37 JMV P5G0175 Diethyl phthalate BRL mg/kg dry 0.45 0.062 1 *8270D 7/13/15 22:37 JMV P5G0175 Dimethyl phthalate BRL mg/kg dry 0.45 0.060 1 *8270D 7/13/15 22:37 JMV P5G0175 Di-n-butyl phthalate BRL mg/kg dry 0.45 0.064 1 *8270D 7/13/15 22:37 JMV P5G0175 Di-n-octyl phthalate BRL mg/kg dry 0.45 0.056 1 *8270D 7/13/15 22:37 JMV P5G0175 Fluoranthene 0.54 mg/kg dry 0.45 0.058 1 *8270D 7/13/15 22:37 JMV P5G0175 Fluorene BRL mg/kg dry 0.45 0.065 1 *8270D 7/13/15 22:37 JMV P5G0175 Hexachlorobenzene BRL mg/kg dry 0.45 0.072 1 *8270D 7/13/15 22:37 JMV P5G0175 Hexachlorobutadiene BRL mg/kg dry 0.45 0.081 1 *8270D 7/13/15 22:37 JMV P5G0175 Hexachlorocyclopentadiene BRL mg/kg dry 0.45 0.081 1 *8270D 7/13/15 22:37 JMV P5G0175 Hexachloroethane BRL mg/kg dry 0.45 0.076 1 *8270D 7/13/15 22:37 JMV P5G0175 Indeno(1,2,3-cd)pyrene BRL mg/kg dry 0.45 0.052 1 *8270D 7/13/15 22:37 JMV P5G0175 Isophorone BRL mg/kg dry 0.45 0.061 1 *8270D 7/13/15 22:37 JMV P5G0175 Naphthalene BRL mg/kg dry 0.45 0.073 1 *8270D 7/13/15 22:37 JMV P5G0175 Nitrobenzene BRL mg/kg dry 0.45 0.064 1 *8270D 7/13/15 22:37 JMV P5G0175 N-Nitroso-di-n-propylamine BRL mg/kg dry 0.45 0.071 1 *8270D 7/13/15 22:37 JMV P5G0175 N-Nitrosodiphenylamine BRL mg/kg dry 0.45 0.069 1 *8270D 7/13/15 22:37 JMV P5G0175 Pentachlorophenol BRL mg/kg dry 0.45 0.053 1 *8270D 7/13/15 22:37 JMV P5G0175 Phenanthrene BRL mg/kg dry 0.45 0.059 1 *8270D 7/13/15 22:37 JMV P5G0175 Phenol BRL mg/kg dry 0.45 0.067 1 *8270D 7/13/15 22:37 JMV P5G0175 Pyrene 0.50 mg/kg dry 0.45 0.060 1 *8270D 7/13/15 22:37 JMV P5G0175 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 108 % 39-132 2-Fluorobiphenyl 99 % 44-115 2-Fluorophenol 86 % 35-115 Nitrobenzene-d5 88 % 37-122 Phenol-d5 86 % 34-121 Terphenyl-d14 103 % 54-127 Total Metals Mercury 0.12 mg/kg dry 0.026 0.0017 1 *7471B 7113/15 13:13 JAB P5G0173 Arsenic 4.8 mg/kg dry 0.34 0.048 1 *6010C 7/13/15 17:41 BGM P5G0172 Barium 61 mg/kg dry 0.67 0.13 1 *6010C 7/13/15 17:41 BGM P5G0172 Cadmium BRL mg/kg dry 0.34 0.048 1 *6010C 7/13/15 17:41 BGM P5G0172 Chromium 28 mg/kg dry 0.34 0.055 1 *6010C 7/13/15 17:41 BGM P5G0172 Lead 47 mg/kg dry 0.34 0.051 1 *6010C 7113/15 17:41 BGM P5G0172 Selenium BRL mg/kg dry 0.67 0.081 1 *6010C 7/13/15 17:41 BGM P5G0172 Silver BRL mg/kg dry 0.34 0.038 1 *6010C 7/13/15 17:41 BGM P5G0172 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL mg/kg dry 0.0057 0.00047 1 *8260B 7/16/15 18:59 MSC P5G0262 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 10 of 80 ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-3A Sample Matrix: Solid Laboratory Report 07/22/2015 Client Sample ID: SB-2 (0-2) Prism Sample ID: 5070165-02 Prism Work Order: 5070165 Time Collected: 07/08/15 09:35 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,1,1-Trichloroethane BRL mg/kg dry 0.0057 0.00028 1 *8260B 7/16/15 18:59 MSC P5G0262 1,1,2,2-Tetrachloroethane BRL mg/kg dry 0.0057 0.00039 1 *8260B 7/16/15 18:59 MSC P5G0262 1,1,2-Trichloroethane BRL mg/kg dry 0.0057 0.00051 1 *8260B 7/16/15 18:59 MSC P5G0262 1,1-Dichloroethane BRL mg/kg dry 0.0057 0.00016 1 *8260B 7/16/15 18:59 MSC P5G0262 1,1-Dichloroethylene BRL mg/kg dry 0.0057 0.00025 1 *8260B 7/16/15 18:59 MSC P5G0262 1,1-Dichloropropylene BRL mg/kg dry 0.0057 0.00031 1 *8260B 7/16/15 18:59 MSC P5G0262 1,2,3-Trichlorobenzene BRL mg/kg dry 0.0057 0.00033 1 *8260B 7/16/15 18:59 MSC P5G0262 1,2,3-Trichloropropane BRL mg/kg dry 0.0057 0.00073 1 *8260B 7/16/15 18:59 MSC P5G0262 1,2,4-Trichlorobenzene BRL mg/kg dry 0.0057 0.00043 1 *8260B 7/16/15 18:59 MSC P5G0262 1,2,4-Trimethyl benzene BRL mg/kg dry 0.0057 0.00044 1 *8260B 7/16/15 18:59 MSC P5G0262 1,2-Dibromoethane BRL mg/kg dry 0.0057 0.00023 1 *8260B 7/16/15 18:59 MSC P5G0262 1,2-Dichlorobenzene BRL mg/kg dry 0.0057 0.00027 1 *8260B 7/16/15 18:59 MSC P5G0262 1,2-Dichloroethane BRL mg/kg dry 0.0057 0.00034 1 *8260B 7/16/15 18:59 MSC P5G0262 1,2-Dichloropropane BRL mg/kg dry 0.0057 0.00036 1 *8260B 7/16/15 18:59 MSC P5G0262 1,3,5-Trimethyl benzene BRL mg/kg dry 0.0057 0.00043 1 *8260B 7/16/15 18:59 MSC P5G0262 1,3-Dichlorobenzene BRL mg/kg dry 0.0057 0.00038 1 *8260B 7/16/15 18:59 MSC P5G0262 1,3-Dichloropropane BRL mg/kg dry 0.0057 0.00029 1 *8260B 7/16/15 18:59 MSC P5G0262 1,4-Dichlorobenzene BRL mg/kg dry 0.0057 0.00023 1 *8260B 7/16/15 18:59 MSC P5G0262 2,2-Dichloropropane BRL mg/kg dry 0.0057 0.00027 1 *8260B 7/16/15 18:59 MSC P5G0262 2-Chlorotoluene BRL mg/kg dry 0.0057 0.00030 1 *8260B 7/16/15 18:59 MSC P5G0262 4-Chlorotoluene BRL mg/kg dry 0.0057 0.00034 1 *8260B 7/16/15 18:59 MSC P5G0262 4-Isopropyltoluene BRL mg/kg dry 0.0057 0.00028 1 *8260B 7/16/15 18:59 MSC P5G0262 Acetone 0.090 mg/kg dry 0.057 0.0014 1 *8260B 7/16/15 18:59 MSC P5G0262 Benzene BRL mg/kg dry 0.0034 0.00033 1 *8260B 7/16/15 18:59 MSC P5G0262 Bromobenzene BRL mg/kg dry 0.0057 0.00048 1 *8260B 7/16/15 18:59 MSC P5G0262 Bromochloromethane BRL mg/kg dry 0.0057 0.00032 1 *8260B 7/16/15 18:59 MSC P5G0262 Bromodichloromethane BRL mg/kg dry 0.0057 0.00032 1 *8260B 7/16/15 18:59 MSC P5G0262 Bromoform BRL mg/kg dry 0.0057 0.00065 1 *8260B 7/16/15 18:59 MSC P5G0262 Bromomethane BRL mg/kg dry 0.011 0.00071 1 *8260B 7/16/15 18:59 MSC P5G0262 Carbon Tetrachloride BRL mg/kg dry 0.0057 0.00029 1 *8260B 7/16/15 18:59 MSC P5G0262 Chlorobenzene BRL mg/kg dry 0.0057 0.00030 1 *8260B 7/16/15 18:59 MSC P5G0262 Chloroethane BRL mg/kg dry 0.011 0.00048 1 *8260B 7/16/15 18:59 MSC P5G0262 Chloroform BRL mg/kg dry 0.0057 0.00041 1 *8260B 7/16/15 18:59 MSC P5G0262 Chloromethane BRL mg/kg dry 0.0057 0.00039 1 *8260B 7/16/15 18:59 MSC P5G0262 cis-1,2-Dichloroethylene BRL mg/kg dry 0.0057 0.00024 1 *8260B 7/16/15 18:59 MSC P5G0262 cis-1,3-Dichloropropylene BRL mg/kg dry 0.0057 0.00019 1 *8260B 7/16/15 18:59 MSC P5G0262 Dibromochloromethane BRL mg/kg dry 0.0057 0.00024 1 *8260B 7/16/15 18:59 MSC P5G0262 Dichlorodifluoromethane BRL mg/kg dry 0.0057 0.00026 1 *8260B 7/16/15 18:59 MSC P5G0262 Ethylbenzene BRL mg/kg dry 0.0057 0.00022 1 *8260B 7/16/15 18:59 MSC P5G0262 Isopropyl Ether BRL mg/kg dry 0.0057 0.00023 1 *8260B 7/16/15 18:59 MSC P5G0262 Isopropylbenzene (Cumene) BRL mg/kg dry 0.0057 0.00034 1 *8260B 7/16/15 18:59 MSC P5G0262 m,p-Xylenes BRL mg/kg dry 0.011 0.00053 1 *8260B 7/16/15 18:59 MSC P5G0262 Methyl Butyl Ketone (2-Hexanone) BRL mg/kg dry 0.057 0.00052 1 *8260B 7/16/15 18:59 MSC P5G0262 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 11 of 80 P R S M Laboratory Report ` Full -Service Analytical & / Environmental Solutions 07/22/2015 LABORATORIES INC. Hart & Hickman (Charlotte) Project: PTR.001-3A Client Sample ID: SB-2 (0-2) Attn: Aaron Oswald Prism Sample ID: 5070165-02 2923 South Tryon St. Ste 100 Prism Work Order: 5070165 Charlotte, NC 28203 Sample Matrix: Solid Time Collected: 07/08/15 09:35 Time Submitted: 07/10/15 08:50 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID Methyl Ethyl Ketone (2-Butanone) BRL mg/kg dry 0.11 0.00052 1 *8260B 7/16/15 18:59 MSC P5G0262 Methyl Isobutyl Ketone BRL mg/kg dry 0.057 0.00049 1 *8260B 7/16/15 18:59 MSC P5G0262 Methylene Chloride BRL mg/kg dry 0.0057 0.00032 1 *8260B 7/16/15 18:59 MSC P5G0262 Methyl-tert-Butyl Ether BRL mg/kg dry 0.011 0.00018 1 *8260B 7/16/15 18:59 MSC P5G0262 Naphthalene BRL mg/kg dry 0.011 0.00018 1 *8260B 7/16/15 18:59 MSC P5G0262 n-Butylbenzene BRL mg/kg dry 0.0057 0.00029 1 *8260B 7/16/15 18:59 MSC P5G0262 n-Propylbenzene BRL mg/kg dry 0.0057 0.00034 1 *8260B 7/16/15 18:59 MSC P5G0262 o-Xylene BRL mg/kg dry 0.0057 0.00024 1 *8260B 7/16/15 18:59 MSC P5G0262 sec-Butylbenzene BRL mg/kg dry 0.0057 0.00028 1 *8260B 7/16/15 18:59 MSC P5G0262 Styrene BRL mg/kg dry 0.0057 0.00035 1 *8260B 7/16/15 18:59 MSC P5G0262 tert-Butylbenzene BRL mg/kg dry 0.0057 0.00019 1 *8260B 7/16/15 18:59 MSC P5G0262 Tetrachloroethylene BRL mg/kg dry 0.0057 0.00027 1 *8260B 7/16/15 18:59 MSC P5G0262 Toluene BRL mg/kg dry 0.0057 0.00033 1 *8260B 7/16/15 18:59 MSC P5G0262 trans-1,2-Dichloroethylene BRL mg/kg dry 0.0057 0.00034 1 *8260B 7/16/15 18:59 MSC P5G0262 trans-1,3-Dichloropropylene BRL mg/kg dry 0.0057 0.00030 1 *8260B 7/16/15 18:59 MSC P5G0262 Trichloroethylene BRL mg/kg dry 0.0057 0.00037 1 *8260B 7/16/15 18:59 MSC P5G0262 Trichlorofluoromethane BRL mg/kg dry 0.0057 0.00037 1 *8260B 7/16/15 18:59 MSC P5G0262 Vinyl acetate BRL A mg/kg dry 0.029 0.00079 1 *8260B 7/16/15 18:59 MSC P5G0262 Vinyl chloride BRL mg/kg dry 0.0057 0.00028 1 *8260B 7/16/15 18:59 MSC P5G0262 Xylenes, total BRL mg/kg dry 0.017 0.0011 1 *8260B 7/16/15 18:59 MSC P5G0262 Surrogate Recovery Control Limits 4-Bromofluorobenzene 125 % 70-130 Dibromofluoromethane 109 % 84-123 Toluene-d8 109 % 76-129 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 12 of 80 P R S M Laboratory Report ` Full -Service Analytical & / Environmental Solutions 07/22/2015 LABORATORIES INC. Hart & Hickman (Charlotte) Project: PTR.001-3A Client Sample ID: Dup-1 Attn: Aaron Oswald Prism Sample ID: 5070165-03 2923 South Tryon St. Ste 100 Prism Work Order: 5070165 Charlotte, NC 28203 Sample Matrix: Solid Time Collected: 07/07/15 00:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters % Solids 83.3 % by 0.100 0.100 1 *SM2540 G 7/13/15 11:55 ARC P5G0176 Weight Semivolatile Organic Compounds by GC/MS 1,2,4-Trichlorobenzene BRL mg/kg dry 0.40 0.062 1 *8270D 7/13/15 22:16 JMV P5G0175 1,2-Dichlorobenzene BRL mg/kg dry 0.40 0.060 1 *8270D 7/13/15 22:16 JMV P5G0175 1,3-Dichlorobenzene BRL mg/kg dry 0.40 0.056 1 *8270D 7/13/15 22:16 JMV P5G0175 1,4-Dichlorobenzene BRL mg/kg dry 0.40 0.058 1 *8270D 7/13/15 22:16 JMV P5G0175 1-Methyl naphthalene BRL mg/kg dry 0.40 0.076 1 *8270D 7/13/15 22:16 JMV P5G0175 2,4,6-Trichlorophenol BRL mg/kg dry 0.40 0.074 1 *8270D 7/13/15 22:16 JMV P5G0175 2,4-Dichlorophenol BRL mg/kg dry 0.40 0.077 1 *8270D 7/13/15 22:16 JMV P5G0175 2,4-Dimethylphenol BRL mg/kg dry 0.40 0.061 1 *8270D 7/13/15 22:16 JMV P5G0175 2,4-Dinitrophenol BRL mg/kg dry 0.40 0.055 1 *8270D 7/13/15 22:16 JMV P5G0175 2,4-Dinitrotoluene BRL mg/kg dry 0.40 0.048 1 *8270D 7/13/15 22:16 JMV P5G0175 2,6-Dinitrotoluene BRL mg/kg dry 0.40 0.053 1 *8270D 7/13/15 22:16 JMV P5G0175 2-Chloronaphthalene BRL mg/kg dry 0.40 0.057 1 *8270D 7/13/15 22:16 JMV P5G0175 2-Chlorophenol BRL mg/kg dry 0.40 0.056 1 *8270D 7/13/15 22:16 JMV P5G0175 2-Methyl naphthalene BRL mg/kg dry 0.40 0.063 1 *8270D 7/13/15 22:16 JMV P5G0175 2-Methylphenol BRL mg/kg dry 0.40 0.051 1 *8270D 7/13/15 22:16 JMV P5G0175 2-Nitrophenol BRL mg/kg dry 0.40 0.072 1 *8270D 7/13/15 22:16 JMV P5G0175 3,3'-Dichlorobenzidine BRL mg/kg dry 0.40 0.078 1 *8270D 7/13/15 22:16 JMV P5G0175 3/4-Methyl phenol BRL mg/kg dry 0.40 0.049 1 *8270D 7/13/15 22:16 JMV P5G0175 4,6-Dinitro-2-methylphenol BRL mg/kg dry 0.40 0.060 1 *8270D 7/13/15 22:16 JMV P5G0175 4-Bromophenyl phenyl ether BRL mg/kg dry 0.40 0.068 1 *8270D 7/13/15 22:16 JMV P5G0175 4-Chloro-3-methylphenol BRL mg/kg dry 0.40 0.056 1 *8270D 7/13/15 22:16 JMV P5G0175 4-Chloroaniline BRL mg/kg dry 0.40 0.048 1 *8270D 7/13/15 22:16 JMV P5G0175 4-Chlorophenyl phenyl ether BRL mg/kg dry 0.40 0.051 1 *8270D 7/13/15 22:16 JMV P5G0175 4-Nitrophenol BRL mg/kg dry 0.40 0.061 1 *8270D 7/13/15 22:16 JMV P5G0175 Acenaphthene BRL mg/kg dry 0.40 0.054 1 *8270D 7/13/15 22:16 JMV P5G0175 Acenaphthylene BRL mg/kg dry 0.40 0.057 1 *8270D 7/13/15 22:16 JMV P5G0175 Anthracene BRL mg/kg dry 0.40 0.064 1 *8270D 7/13/15 22:16 JMV P5G0175 Azobenzene BRL mg/kg dry 0.40 0.052 1 *8270D 7/13/15 22:16 JMV P5G0175 Benzo(a)anthracene 0.57 mg/kg dry 0.40 0.052 1 *8270D 7/13/15 22:16 JMV P5G0175 Benzo(a)pyrene 0.72 mg/kg dry 0.40 0.043 1 *8270D 7113/15 22:16 JMV P5G0175 Benzo(b)fluoranthene 1.1 mg/kg dry 0.40 0.046 1 *8270D 7/13/15 22:16 JMV P5G0175 Benzo(g,hJ)perylene 0.64 mg/kg dry 0.40 0.043 1 *8270D 7/13/15 22:16 JMV P5G0175 Benzo(k)fluoranthene BRL mg/kg dry 0.40 0.052 1 *8270D 7/13/15 22:16 JMV P5G0175 Benzoic Acid BRL mg/kg dry 0.40 0.033 1 *8270D 7/13/15 22:16 JMV P5G0175 Benzyl alcohol BRL mg/kg dry 0.40 0.052 1 *8270D 7/13/15 22:16 JMV P5G0175 bis(2-Chloroethoxy)methane BRL mg/kg dry 0.40 0.069 1 *8270D 7/13/15 22:16 JMV P5G0175 Bis(2-Chloroethyl)ether BRL mg/kg dry 0.40 0.056 1 *8270D 7/13/15 22:16 JMV P5G0175 Bis(2-chloroisopropyl)ether BRL mg/kg dry 0.40 0.068 1 *8270D 7/13/15 22:16 JMV P5G0175 Bis(2-Ethylhexyl)phthalate BRL mg/kg dry 0.40 0.059 1 *8270D 7/13/15 22:16 JMV P5G0175 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 13 of 80 Laboratory Report ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. 07/22/2015 Hart & Hickman (Charlotte) Project: PTR.001-3A Client Sample ID: Dup-1 Attn: Aaron Oswald Prism Sample ID: 5070165-03 2923 South Tryon St. Ste 100 Prism Work Order: 5070165 Charlotte, NC 28203 Sample Matrix: Solid Time Collected: 07/07/15 00:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Butyl benzyl phthalate BRL mg/kg dry 0.40 0.056 1 *8270D 7/13/15 22:16 JMV P5G0175 Chrysene 0.72 mg/kg dry 0.40 0.050 1 *8270D 7/13/15 22:16 JMV P5G0175 Dibenzo(a,h)anthracene BRL mg/kg dry 0.40 0.048 1 *8270D 7/13/15 22:16 JMV P5G0175 Dibenzofuran BRL mg/kg dry 0.40 0.060 1 *8270D 7/13/15 22:16 JMV P5G0175 Diethyl phthalate BRL mg/kg dry 0.40 0.055 1 *8270D 7/13/15 22:16 JMV P5G0175 Dimethyl phthalate BRL mg/kg dry 0.40 0.052 1 *8270D 7/13/15 22:16 JMV P5G0175 Di-n-butyl phthalate BRL mg/kg dry 0.40 0.056 1 *8270D 7/13/15 22:16 JMV P5G0175 Di-n-octyl phthalate BRL mg/kg dry 0.40 0.049 1 *8270D 7/13/15 22:16 JMV P5G0175 Fluoranthene 1.5 mg/kg dry 0.40 0.051 1 *8270D 7/13/15 22:16 JMV P5G0175 Fluorene BRL mg/kg dry 0.40 0.057 1 *8270D 7/13/15 22:16 JMV P5G0175 Hexachlorobenzene BRL mg/kg dry 0.40 0.063 1 *8270D 7/13/15 22:16 JMV P5G0175 Hexachlorobutadiene BRL mg/kg dry 0.40 0.071 1 *8270D 7/13/15 22:16 JMV P5G0175 Hexachlorocyclopentadiene BRL mg/kg dry 0.40 0.071 1 *8270D 7/13/15 22:16 JMV P5G0175 Hexachloroethane BRL mg/kg dry 0.40 0.066 1 *8270D 7/13/15 22:16 JMV P5G0175 Indeno(1,2,3-cd)pyrene 0.61 mg/kg dry 0.40 0.045 1 *8270D 7/13/15 22:16 JMV P5G0175 Isophorone BRL mg/kg dry 0.40 0.054 1 *8270D 7/13/15 22:16 JMV P5G0175 Naphthalene BRL mg/kg dry 0.40 0.064 1 *8270D 7/13/15 22:16 JMV P5G0175 Nitrobenzene BRL mg/kg dry 0.40 0.056 1 *8270D 7/13/15 22:16 JMV P5G0175 N-Nitroso-di-n-propylamine BRL mg/kg dry 0.40 0.062 1 *8270D 7/13/15 22:16 JMV P5G0175 N-Nitrosodiphenylamine BRL mg/kg dry 0.40 0.060 1 *8270D 7/13/15 22:16 JMV P5G0175 Pentachlorophenol BRL mg/kg dry 0.40 0.047 1 *8270D 7/13/15 22:16 JMV P5G0175 Phenanthrene 0.79 mg/kg dry 0.40 0.051 1 *8270D 7/13/15 22:16 JMV P5G0175 Phenol BRL mg/kg dry 0.40 0.058 1 *8270D 7/13/15 22:16 JMV P5G0175 Pyrene 1.3 mg/kg dry 0.40 0.052 1 *8270D 7/13/15 22:16 JMV P5G0175 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 108 % 39-132 2-Fluorobiphenyl 79 % 44-115 2-Fluorophenol 52 % 35-115 Nitrobenzene-d5 55 % 37-122 Phenol-d5 63 % 34-121 Terphenyl-d14 104 % 54-127 Total Metals Mercury 0.088 mg/kg dry 0.026 0.0017 1 *7471B 7113/15 13:27 JAB P5G0173 Arsenic 4.4 mg/kg dry 0.30 0.043 1 *6010C 7/13/15 18:24 BGM P5G0172 Barium 85 mg/kg dry 0.61 0.12 1 *6010C 7/13/15 18:24 BGM P5G0172 Cadmium BRL mg/kg dry 0.30 0.043 1 *6010C 7/13/15 18:24 BGM P5G0172 Chromium 33 mg/kg dry 0.30 0.050 1 *6010C 7/13/15 18:24 BGM P5G0172 Lead 52 mg/kg dry 0.30 0.046 1 *6010C 7113/15 18:24 BGM P5G0172 Selenium BRL mg/kg dry 0.61 0.073 1 *6010C 7/13/15 18:24 BGM P5G0172 Silver BRL mg/kg dry 0.30 0.035 1 *6010C 7/13/15 18:24 BGM P5G0172 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL mg/kg dry 0.0063 0.00052 1 *8260B 7/16/15 19:30 MSC P5G0262 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 14 of 80 ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-3A Sample Matrix: Solid Laboratory Report 07/22/2015 Client Sample ID: Dup-1 Prism Sample ID: 5070165-03 Prism Work Order: 5070165 Time Collected: 07/07/15 00:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,1,1-Trichloroethane BRL mg/kg dry 0.0063 0.00030 1 *8260B 7/16/15 19:30 MSC P5G0262 1,1,2,2-Tetrachloroethane BRL mg/kg dry 0.0063 0.00043 1 *8260B 7/16/15 19:30 MSC P5G0262 1,1,2-Trichloroethane BRL mg/kg dry 0.0063 0.00056 1 *8260B 7/16/15 19:30 MSC P5G0262 1,1-Dichloroethane BRL mg/kg dry 0.0063 0.00017 1 *8260B 7/16/15 19:30 MSC P5G0262 1,1-Dichloroethylene BRL mg/kg dry 0.0063 0.00028 1 *8260B 7/16/15 19:30 MSC P5G0262 1,1-Dichloropropylene BRL mg/kg dry 0.0063 0.00034 1 *8260B 7/16/15 19:30 MSC P5G0262 1,2,3-Trichlorobenzene BRL mg/kg dry 0.0063 0.00036 1 *8260B 7/16/15 19:30 MSC P5G0262 1,2,3-Trichloropropane BRL mg/kg dry 0.0063 0.00080 1 *8260B 7/16/15 19:30 MSC P5G0262 1,2,4-Trichlorobenzene BRL mg/kg dry 0.0063 0.00047 1 *8260B 7/16/15 19:30 MSC P5G0262 1,2,4-Trimethyl benzene BRL mg/kg dry 0.0063 0.00048 1 *8260B 7/16/15 19:30 MSC P5G0262 1,2-Dibromoethane BRL mg/kg dry 0.0063 0.00025 1 *8260B 7/16/15 19:30 MSC P5G0262 1,2-Dichlorobenzene BRL mg/kg dry 0.0063 0.00030 1 *8260B 7/16/15 19:30 MSC P5G0262 1,2-Dichloroethane BRL mg/kg dry 0.0063 0.00037 1 *8260B 7/16/15 19:30 MSC P5G0262 1,2-Dichloropropane BRL mg/kg dry 0.0063 0.00039 1 *8260B 7/16/15 19:30 MSC P5G0262 1,3,5-Trimethyl benzene BRL mg/kg dry 0.0063 0.00048 1 *8260B 7/16/15 19:30 MSC P5G0262 1,3-Dichlorobenzene BRL mg/kg dry 0.0063 0.00042 1 *8260B 7/16/15 19:30 MSC P5G0262 1,3-Dichloropropane BRL mg/kg dry 0.0063 0.00032 1 *8260B 7/16/15 19:30 MSC P5G0262 1,4-Dichlorobenzene BRL mg/kg dry 0.0063 0.00025 1 *8260B 7/16/15 19:30 MSC P5G0262 2,2-Dichloropropane BRL mg/kg dry 0.0063 0.00030 1 *8260B 7/16/15 19:30 MSC P5G0262 2-Chlorotoluene BRL mg/kg dry 0.0063 0.00032 1 *8260B 7/16/15 19:30 MSC P5G0262 4-Chlorotoluene BRL mg/kg dry 0.0063 0.00037 1 *8260B 7/16/15 19:30 MSC P5G0262 4-Isopropyltoluene BRL mg/kg dry 0.0063 0.00030 1 *8260B 7/16/15 19:30 MSC P5G0262 Acetone 0.10 mg/kg dry 0.063 0.0015 1 *8260B 7/16/15 19:30 MSC P5G0262 Benzene BRL mg/kg dry 0.0038 0.00037 1 *8260B 7/16/15 19:30 MSC P5G0262 Bromobenzene BRL mg/kg dry 0.0063 0.00052 1 *8260B 7/16/15 19:30 MSC P5G0262 Bromochloromethane BRL mg/kg dry 0.0063 0.00035 1 *8260B 7/16/15 19:30 MSC P5G0262 Bromodichloromethane BRL mg/kg dry 0.0063 0.00035 1 *8260B 7/16/15 19:30 MSC P5G0262 Bromoform BRL mg/kg dry 0.0063 0.00071 1 *8260B 7/16/15 19:30 MSC P5G0262 Bromomethane BRL mg/kg dry 0.013 0.00078 1 *8260B 7/16/15 19:30 MSC P5G0262 Carbon Tetrachloride BRL mg/kg dry 0.0063 0.00031 1 *8260B 7/16/15 19:30 MSC P5G0262 Chlorobenzene BRL mg/kg dry 0.0063 0.00033 1 *8260B 7/16/15 19:30 MSC P5G0262 Chloroethane BRL mg/kg dry 0.013 0.00052 1 *8260B 7/16/15 19:30 MSC P5G0262 Chloroform BRL mg/kg dry 0.0063 0.00045 1 *8260B 7/16/15 19:30 MSC P5G0262 Chloromethane BRL mg/kg dry 0.0063 0.00042 1 *8260B 7/16/15 19:30 MSC P5G0262 cis-1,2-Dichloroethylene BRL mg/kg dry 0.0063 0.00027 1 *8260B 7/16/15 19:30 MSC P5G0262 cis-1,3-Dichloropropylene BRL mg/kg dry 0.0063 0.00021 1 *8260B 7/16/15 19:30 MSC P5G0262 Dibromochloromethane BRL mg/kg dry 0.0063 0.00026 1 *8260B 7/16/15 19:30 MSC P5G0262 Dichlorodifluoromethane BRL mg/kg dry 0.0063 0.00029 1 *8260B 7/16/15 19:30 MSC P5G0262 Ethylbenzene BRL mg/kg dry 0.0063 0.00024 1 *8260B 7/16/15 19:30 MSC P5G0262 Isopropyl Ether BRL mg/kg dry 0.0063 0.00026 1 *8260B 7/16/15 19:30 MSC P5G0262 Isopropylbenzene (Cumene) BRL mg/kg dry 0.0063 0.00037 1 *8260B 7/16/15 19:30 MSC P5G0262 m,p-Xylenes BRL mg/kg dry 0.013 0.00058 1 *8260B 7/16/15 19:30 MSC P5G0262 Methyl Butyl Ketone (2-Hexanone) BRL mg/kg dry 0.063 0.00057 1 *8260B 7/16/15 19:30 MSC P5G0262 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 15 of 80 P R S M Laboratory Report ` Full -Service Analytical & / Environmental Solutions 07/22/2015 LABORATORIES INC. Hart & Hickman (Charlotte) Project: PTR.001-3A Client Sample ID: Dup-1 Attn: Aaron Oswald Prism Sample ID: 5070165-03 2923 South Tryon St. Ste 100 Prism Work Order: 5070165 Charlotte, NC 28203 Sample Matrix: Solid Time Collected: 07/07/15 00:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Date/Time Analyst Batch ID Methyl Ethyl Ketone (2-Butanone) BRL mg/kg dry 0.13 0.00057 1 *8260B 7/16/15 19:30 MSC P5G0262 Methyl Isobutyl Ketone BRL mg/kg dry 0.063 0.00054 1 *8260B 7/16/15 19:30 MSC P5G0262 Methylene Chloride BRL mg/kg dry 0.0063 0.00035 1 *8260B 7/16/15 19:30 MSC P5G0262 Methyl-tert-Butyl Ether BRL mg/kg dry 0.013 0.00020 1 *8260B 7/16/15 19:30 MSC P5G0262 Naphthalene BRL mg/kg dry 0.013 0.00020 1 *8260B 7/16/15 19:30 MSC P5G0262 n-Butylbenzene BRL mg/kg dry 0.0063 0.00032 1 *8260B 7/16/15 19:30 MSC P5G0262 n-Propylbenzene BRL mg/kg dry 0.0063 0.00037 1 *8260B 7/16/15 19:30 MSC P5G0262 o-Xylene BRL mg/kg dry 0.0063 0.00026 1 *8260B 7/16/15 19:30 MSC P5G0262 sec-Butylbenzene BRL mg/kg dry 0.0063 0.00030 1 *8260B 7/16/15 19:30 MSC P5G0262 Styrene BRL mg/kg dry 0.0063 0.00038 1 *8260B 7/16/15 19:30 MSC P5G0262 tert-Butylbenzene BRL mg/kg dry 0.0063 0.00021 1 *8260B 7/16/15 19:30 MSC P5G0262 Tetrachloroethylene BRL mg/kg dry 0.0063 0.00030 1 *8260B 7/16/15 19:30 MSC P5G0262 Toluene BRL mg/kg dry 0.0063 0.00036 1 *8260B 7/16/15 19:30 MSC P5G0262 trans-1,2-Dichloroethylene BRL mg/kg dry 0.0063 0.00038 1 *8260B 7/16/15 19:30 MSC P5G0262 trans-1,3-Dichloropropylene BRL mg/kg dry 0.0063 0.00033 1 *8260B 7/16/15 19:30 MSC P5G0262 Trichloroethylene BRL mg/kg dry 0.0063 0.00041 1 *8260B 7/16/15 19:30 MSC P5G0262 Trichlorofluoromethane BRL mg/kg dry 0.0063 0.00041 1 *8260B 7/16/15 19:30 MSC P5G0262 Vinyl acetate BRL A mg/kg dry 0.031 0.00086 1 *8260B 7/16/15 19:30 MSC P5G0262 Vinyl chloride BRL mg/kg dry 0.0063 0.00030 1 *8260B 7/16/15 19:30 MSC P5G0262 Xylenes, total BRL mg/kg dry 0.019 0.0012 1 *8260B 7/16/15 19:30 MSC P5G0262 Surrogate Recovery Control Limits 4-Bromofluorobenzene 122 % 70-130 Dibromofluoromethane 110 % 84-123 Toluene-d8 104 % 76-129 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 16 of 80 PR I S M Full -Service Analytical Environmental Solutions LABORATORIES INC. Laboratory Report 07/22/2015 Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-3A Client Sample ID: TMW-1 Prism Sample ID: 5070165-04 Prism Work Order: 5070165 Sample Matrix: Water Time Collected: 07/09/15 11:35 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Semivolatile Organic Compounds by GC/MS 1,2,4-Trichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 17:56 JMV P5G0184 1,2-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 17:56 JMV P5G0184 1,3-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 17:56 JMV P5G0184 1,4-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 17:56 JMV P5G0184 1-Methyl naphthalene BRL ug/L 10 2.4 1 *8270D 7/16/15 17:56 JMV P5G0184 2,4,5-Trichlorophenol BRL ug/L 10 2.3 1 *8270D 7/16/15 17:56 JMV P5G0184 2,4,6-Trichlorophenol BRL ug/L 10 2.6 1 *8270D 7/16/15 17:56 JMV P5G0184 2,4-Dichlorophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 17:56 JMV P5G0184 2,4-Dimethylphenol BRL ug/L 10 2.3 1 *8270D 7/16/15 17:56 JMV P5G0184 2,4-Dinitrophenol BRL ug/L 10 3.7 1 *8270D 7/16/15 17:56 JMV P5G0184 2,4-Dinitrotoluene BRL ug/L 10 1.9 1 *8270D 7/16/15 17:56 JMV P5G0184 2,6-Dinitrotoluene BRL ug/L 10 2.0 1 *8270D 7/16/15 17:56 JMV P5G0184 2-Chloronaphthalene BRL ug/L 10 3.4 1 *8270D 7/16/15 17:56 JMV P5G0184 2-Chlorophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 17:56 JMV P5G0184 2-Methyl naphthalene BRL ug/L 10 2.2 1 *8270D 7/16/15 17:56 JMV P5G0184 2-Methylphenol BRL ug/L 10 2.1 1 *8270D 7/16/15 17:56 JMV P5G0184 2-Nitroaniline BRL ug/L 10 2.2 1 *8270D 7/16/15 17:56 JMV P5G0184 2-Nitrophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 17:56 JMV P5G0184 3,3'-Dichlorobenzidine BRL ug/L 10 2.2 1 *8270D 7/16/15 17:56 JMV P5G0184 3/4-Methyl phenol BRL ug/L 10 1.9 1 *8270D 7/16/15 17:56 JMV P5G0184 3-Nitroaniline BRL ug/L 10 1.2 1 *8270D 7/16/15 17:56 JMV P5G0184 4,6-Dinitro-2-methylphenol BRL ug/L 10 2.4 1 *8270D 7/16/15 17:56 JMV P5G0184 4-Bromophenyl phenyl ether BRL ug/L 10 1.8 1 *8270D 7/16/15 17:56 JMV P5G0184 4-Chloro-3-methylphenol BRL ug/L 10 1.9 1 *8270D 7/16/15 17:56 JMV P5G0184 4-Chloroaniline BRL ug/L 10 1.8 1 *8270D 7/16/15 17:56 JMV P5G0184 4-Chlorophenyl phenyl ether BRL ug/L 10 2.0 1 *8270D 7/16/15 17:56 JMV P5G0184 4-Nitroaniline BRL ug/L 10 2.0 1 *8270D 7/16/15 17:56 JMV P5G0184 4-Nitrophenol BRL ug/L 10 0.66 1 *8270D 7/16/15 17:56 JMV P5G0184 Acenaphthene BRL ug/L 10 2.5 1 *8270D 7/16/15 17:56 JMV P5G0184 Acenaphthylene BRL ug/L 10 2.5 1 *8270D 7/16/15 17:56 JMV P5G0184 Aniline BRL ug/L 10 2.1 1 *8270D 7/16/15 17:56 JMV P5G0184 Anthracene BRL ug/L 10 3.0 1 *8270D 7/16/15 17:56 JMV P5G0184 Azobenzene BRL ug/L 10 1.8 1 *8270D 7/16/15 17:56 JMV P5G0184 Benzo(a)anthracene BRL ug/L 10 2.0 1 *8270D 7/16/15 17:56 JMV P5G0184 Benzo(a)pyrene BRL ug/L 10 2.4 1 *8270D 7/16/15 17:56 JMV P5G0184 Benzo(b)fluoranthene BRL ug/L 10 1.4 1 *8270D 7/16/15 17:56 JMV P5G0184 Benzo(g,h,i)perylene BRL ug/L 10 1.8 1 *8270D 7/16/15 17:56 JMV P5G0184 Benzo(k)fluoranthene BRL ug/L 10 2.4 1 *8270D 7/16/15 17:56 JMV P5G0184 Benzoic Acid BRL ug/L 100 2.7 1 *8270D 7/16/15 17:56 JMV P5G0184 Benzyl alcohol BRL ug/L 10 1.8 1 *8270D 7/16/15 17:56 JMV P5G0184 bis(2-Chloroethoxy)methane BRL ug/L 10 2.2 1 *8270D 7/16/15 17:56 JMV P5G0184 Bis(2-Chloroethyl)ether BRL ug/L 10 2.4 1 *8270D 7/16/15 17:56 JMV P5G0184 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 17 of 80 Laboratory Report ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. 07/22/2015 Hart & Hickman (Charlotte) Project: PTR.001-3A Client Sample ID: TMW-1 Attn: Aaron Oswald Prism Sample ID: 5070165-04 2923 South Tryon St. Ste 100 Prism Work Order: 5070165 Charlotte, NC 28203 Sample Matrix: Water Time Collected: 07/09/15 11:35 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Bis(2-chloroisopropyl)ether BRL ug/L 10 2.2 1 *8270D 7/16/15 17:56 JMV P5G0184 Bis(2-Ethylhexyl)phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 17:56 JMV P5G0184 Butyl benzyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 17:56 JMV P5G0184 Chrysene BRL ug/L 10 2.2 1 *8270D 7/16/15 17:56 JMV P5G0184 Dibenzo(a,h)anthracene BRL ug/L 10 2.0 1 *8270D 7/16/15 17:56 JMV P5G0184 Dibenzofuran BRL ug/L 10 2.3 1 *8270D 7/16/15 17:56 JMV P5G0184 Diethyl phthalate BRL ug/L 10 1.9 1 *8270D 7/16/15 17:56 JMV P5G0184 Dimethyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 17:56 JMV P5G0184 Di-n-butyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 17:56 JMV P5G0184 Di-n-octyl phthalate BRL ug/L 10 1.7 1 *8270D 7/16/15 17:56 JMV P5G0184 Fluoranthene BRL ug/L 10 2.2 1 *8270D 7/16/15 17:56 JMV P5G0184 Fluorene BRL ug/L 10 2.5 1 *8270D 7/16/15 17:56 JMV P5G0184 Hexachlorobenzene BRL ug/L 10 1.9 1 *8270D 7/16/15 17:56 JMV P5G0184 Hexachlorobutadiene BRL ug/L 10 2.6 1 *8270D 7/16/15 17:56 JMV P5G0184 Hexachlorocyclopentadiene BRL ug/L 10 2.2 1 *8270D 7/16/15 17:56 JMV P5G0184 Hexachloroethane BRL ug/L 10 2.5 1 *8270D 7/16/15 17:56 JMV P5G0184 Indeno(1,2,3-cd)pyrene BRL ug/L 10 2.1 1 *8270D 7/16/15 17:56 JMV P5G0184 Isophorone BRL ug/L 10 2.5 1 *8270D 7/16/15 17:56 JMV P5G0184 Naphthalene BRL ug/L 10 2.4 1 *8270D 7/16/15 17:56 JMV P5G0184 Nitrobenzene BRL ug/L 10 2.4 1 *8270D 7/16/15 17:56 JMV P5G0184 N-Nitroso-di-n-propylamine BRL ug/L 10 2.5 1 *8270D 7/16/15 17:56 JMV P5G0184 N-Nitrosodiphenylamine BRL ug/L 10 1.8 1 *8270D 7/16/15 17:56 JMV P5G0184 Pentachlorophenol BRL ug/L 10 2.5 1 *8270D 7/16/15 17:56 JMV P5G0184 Phenanthrene BRL ug/L 10 1.8 1 *8270D 7/16/15 17:56 JMV P5G0184 Phenol BRL ug/L 10 1.2 1 *8270D 7/16/15 17:56 JMV P5G0184 Pyrene BRL ug/L 10 2.2 1 *8270D 7/16/15 17:56 JMV P5G0184 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 107 % 49-109 2-Fluorobiphenyl 84 % 55-96 2-Fluorophenol 48 % 27-74 Nitrobenzene-d5 74 % 53-99 Phenol-d5 32 % 11-52 Terphenyl-d14 104 % 42-133 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL ug/L 0.50 0.11 1 *8260B 7/14/15 18:53 MSC P5G0244 1,1,1-Trichloroethane BRL ug/L 0.50 0.061 1 *8260B 7/14/15 18:53 MSC P5G0244 1,1,2,2-Tetrachloroethane BRL ug/L 0.50 0.036 1 *8260B 7/14/15 18:53 MSC P5G0244 1,1,2-Trichloroethane BRL ug/L 0.50 0.066 1 *8260B 7/14/15 18:53 MSC P5G0244 1,1-Dichloroethane 11 ug/L 0.50 0.083 1 *8260B 7/14/15 18:53 MSC P5G0244 1,1-Dichloroethylene 4.0 ug/L 0.50 0.083 1 *8260B 7/14/15 18:53 MSC P5G0244 1,1-Dichloropropylene BRL ug/L 0.50 0.051 1 *8260B 7/14/15 18:53 MSC P5G0244 1,2,3-Trichlorobenzene BRL ug/L 2.0 0.40 1 *8260B 7/14/15 18:53 MSC P5G0244 1,2,3-Trichloropropane BRL ug/L 1.0 0.14 1 *8260B 7/14/15 18:53 MSC P5G0244 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 18 of 80 ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-3A Sample Matrix: Water Laboratory Report 07/22/2015 Client Sample ID: TMW-1 Prism Sample ID: 5070165-04 Prism Work Order: 5070165 Time Collected: 07/09/15 11:35 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,2,4-Trichlorobenzene BRL ug/L 1.0 0.13 1 *8260B 7/14/15 18:53 MSC P5G0244 1,2,4-Trimethyl benzene BRL ug/L 0.50 0.054 1 *8260B 7/14/15 18:53 MSC P5G0244 1,2-Dibromo-3-chloropropane BRL ug/L 2.0 0.17 1 *8260B 7/14/15 18:53 MSC P5G0244 1,2-Dibromoethane BRL ug/L 0.50 0.051 1 *8260B 7/14/15 18:53 MSC P5G0244 1,2-Dichlorobenzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 18:53 MSC P5G0244 1,2-Dichloroethane BRL ug/L 0.50 0.066 1 *8260B 7/14/15 18:53 MSC P5G0244 1,2-Dichloropropane BRL ug/L 0.50 0.11 1 *8260B 7/14/15 18:53 MSC P5G0244 1,3,5-Trimethyl benzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 18:53 MSC P5G0244 1,3-Dichlorobenzene BRL ug/L 0.50 0.054 1 *8260B 7/14/15 18:53 MSC P5G0244 1,3-Dichloropropane BRL ug/L 0.50 0.043 1 *8260B 7/14/15 18:53 MSC P5G0244 1,4-Dichlorobenzene BRL ug/L 0.50 0.050 1 *8260B 7/14/15 18:53 MSC P5G0244 2,2-Dichloropropane BRL ug/L 2.0 0.11 1 *8260B 7/14/15 18:53 MSC P5G0244 2-Chloroethyl Vinyl Ether BRL ug/L 5.0 0.37 1 *8260B 7/14/15 18:53 MSC P5G0244 2-Chlorotoluene BRL ug/L 0.50 0.066 1 *8260B 7/14/15 18:53 MSC P5G0244 4-Chlorotoluene BRL ug/L 0.50 0.050 1 *8260B 7/14/15 18:53 MSC P5G0244 4-Isopropyltoluene BRL ug/L 0.50 0.089 1 *8260B 7/14/15 18:53 MSC P5G0244 Acetone BRL ug/L 5.0 0.31 1 *8260B 7/14/15 18:53 MSC P5G0244 Acrolein BRL ug/L 20 0.20 1 *8260B 7/14/15 18:53 MSC P5G0244 Acrylonitrile BRL ug/L 20 0.20 1 *8260B 7/14/15 18:53 MSC P5G0244 Benzene BRL ug/L 0.50 0.048 1 *8260B 7/14/15 18:53 MSC P5G0244 Bromobenzene BRL ug/L 0.50 0.057 1 *8260B 7/14/15 18:53 MSC P5G0244 Bromochloromethane BRL ug/L 0.50 0.14 1 *8260B 7/14/15 18:53 MSC P5G0244 Bromodichloromethane BRL ug/L 0.50 0.062 1 *8260B 7/14/15 18:53 MSC P5G0244 Bromoform BRL ug/L 1.0 0.040 1 *8260B 7/14/15 18:53 MSC P5G0244 Bromomethane BRL ug/L 1.0 0.18 1 *8260B 7/14/15 18:53 MSC P5G0244 Carbon disulfide BRL ug/L 5.0 0.075 1 *8260B 7/14/15 18:53 MSC P5G0244 Carbon Tetrachloride BRL ug/L 0.50 0.11 1 *8260B 7/14/15 18:53 MSC P5G0244 Chlorobenzene BRL ug/L 0.50 0.062 1 *8260B 7/14/15 18:53 MSC P5G0244 Chloroethane BRL ug/L 0.50 0.22 1 *8260B 7/14/15 18:53 MSC P5G0244 Chloroform 0.80 ug/L 0.50 0.076 1 *8260B 7/14/15 18:53 MSC P5G0244 Chloromethane BRL ug/L 0.50 0.079 1 *8260B 7/14/15 18:53 MSC P5G0244 cis-1,2-Dichloroethylene 1.7 ug/L 0.50 0.056 1 *8260B 7/14/15 18:53 MSC P5G0244 cis-1,3-Dichloropropylene BRL ug/L 0.50 0.079 1 *8260B 7/14/15 18:53 MSC P5G0244 Dibromochloromethane BRL ug/L 0.50 0.081 1 *8260B 7/14/15 18:53 MSC P5G0244 Dibromomethane BRL ug/L 0.50 0.065 1 *8260B 7/14/15 18:53 MSC P5G0244 Dichlorodifluoromethane BRL ug/L 1.0 0.11 1 *8260B 7/14/15 18:53 MSC P5G0244 Ethylbenzene BRL ug/L 0.50 0.061 1 *8260B 7/14/15 18:53 MSC P5G0244 Hexachlorobutadiene BRL ug/L 2.0 0.16 1 *8260B 7/14/15 18:53 MSC P5G0244 Isopropyl Ether 0.80 ug/L 0.50 0.050 1 *8260B 7/14/15 18:53 MSC P5G0244 Isopropylbenzene (Cumene) BRL ug/L 0.50 0.054 1 *8260B 7/14/15 18:53 MSC P5G0244 m,p-Xylenes BRL ug/L 1.0 0.12 1 *8260B 7/14/15 18:53 MSC P5G0244 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 5.0 0.065 1 *8260B 7/14/15 18:53 MSC P5G0244 Methyl Ethyl Ketone (2-Butanone) BRL ug/L 5.0 0.24 1 *8260B 7/14/15 18:53 MSC P5G0244 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 19 of 80 Laboratory Report ` Full -Service P R S M Analytical & / Environmental Solutions LABORATORIES INC. 07/22/2015 Hart & Hickman (Charlotte) Project: PTR.001-3A Client Sample ID: TMW-1 Attn: Aaron Oswald Prism Sample ID: 5070165-04 2923 South Tryon St. Ste 100 Prism Work Order: 5070165 Charlotte, NC 28203 Sample Matrix: Water Time Collected: 07/09/15 11:35 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Methyl Isobutyl Ketone BRL ug/L 5.0 0.078 1 *8260B 7/14/15 18:53 MSC P5G0244 Methylene Chloride BRL ug/L 1.0 0.083 1 *8260B 7/14/15 18:53 MSC P5G0244 Methyl-tert-Butyl Ether BRL ug/L 0.50 0.042 1 *8260B 7/14/15 18:53 MSC P5G0244 Naphthalene BRL ug/L 1.0 0.19 1 *8260B 7/14/15 18:53 MSC P5G0244 n-Butylbenzene BRL ug/L 1.0 0.076 1 *8260B 7/14/15 18:53 MSC P5G0244 n-Propylbenzene BRL ug/L 0.50 0.087 1 *8260B 7/14/15 18:53 MSC P5G0244 o-Xylene BRL ug/L 0.50 0.044 1 *8260B 7/14/15 18:53 MSC P5G0244 sec-Butylbenzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 18:53 MSC P5G0244 Styrene BRL ug/L 0.50 0.047 1 *8260B 7/14/15 18:53 MSC P5G0244 tert-Butylbenzene BRL ug/L 0.50 0.088 1 *8260B 7/14/15 18:53 MSC P5G0244 Tetrachloroethylene 290 H1 ug/L 5.0 0.98 10 *8260B 7/21/15 15:30 MSC P5G0244 Toluene BRL ug/L 0.50 0.044 1 *8260B 7/14/15 18:53 MSC P5G0244 trans-1,2-Dichloroethylene BRL ug/L 0.50 0.094 1 *8260B 7/14/15 18:53 MSC P5G0244 trans-1,3-Dichloropropylene BRL ug/L 0.50 0.070 1 *8260B 7/14/15 18:53 MSC P5G0244 Trichloroethylene 3.4 ug/L 0.50 0.078 1 *8260B 7/14/15 18:53 MSC P5G0244 Trichlorofluoromethane BRL ug/L 0.50 0.062 1 *8260B 7/14/15 18:53 MSC P5G0244 Vinyl acetate BRL ug/L 2.0 0.060 1 *8260B 7/14/15 18:53 MSC P5G0244 Vinyl chloride BRL ug/L 0.50 0.097 1 *8260B 7/14/15 18:53 MSC P5G0244 Surrogate Recovery Control Limits 4-Bromofluorobenzene 91 % 80-124 Dibromofluoromethane 99 % 75-129 Toluene-d8 96 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 20 of 80 PR I S M Full -Service Analytical Environmental Solutions LABORATORIES INC. Laboratory Report 07/22/2015 Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-3A Client Sample ID: TMW-2 Prism Sample ID: 5070165-05 Prism Work Order: 5070165 Sample Matrix: Water Time Collected: 07/07/15 11:25 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Semivolatile Organic Compounds by GC/MS 1,2,4-Trichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 13:21 JMV P5G0184 1,2-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 13:21 JMV P5G0184 1,3-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 13:21 JMV P5G0184 1,4-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 13:21 JMV P5G0184 1-Methyl naphthalene BRL ug/L 10 2.4 1 *8270D 7/16/15 13:21 JMV P5G0184 2,4,5-Trichlorophenol BRL ug/L 10 2.3 1 *8270D 7/16/15 13:21 JMV P5G0184 2,4,6-Trichlorophenol BRL ug/L 10 2.6 1 *8270D 7/16/15 13:21 JMV P5G0184 2,4-Dichlorophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 13:21 JMV P5G0184 2,4-Dimethylphenol BRL ug/L 10 2.3 1 *8270D 7/16/15 13:21 JMV P5G0184 2,4-Dinitrophenol BRL ug/L 10 3.7 1 *8270D 7/16/15 13:21 JMV P5G0184 2,4-Dinitrotoluene BRL ug/L 10 1.9 1 *8270D 7/16/15 13:21 JMV P5G0184 2,6-Dinitrotoluene BRL ug/L 10 2.0 1 *8270D 7/16/15 13:21 JMV P5G0184 2-Chloronaphthalene BRL ug/L 10 3.4 1 *8270D 7/16/15 13:21 JMV P5G0184 2-Chlorophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 13:21 JMV P5G0184 2-Methyl naphthalene BRL ug/L 10 2.2 1 *8270D 7/16/15 13:21 JMV P5G0184 2-Methylphenol BRL ug/L 10 2.1 1 *8270D 7/16/15 13:21 JMV P5G0184 2-Nitroaniline BRL ug/L 10 2.2 1 *8270D 7/16/15 13:21 JMV P5G0184 2-Nitrophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 13:21 JMV P5G0184 3,3'-Dichlorobenzidine BRL ug/L 10 2.2 1 *8270D 7/16/15 13:21 JMV P5G0184 3/4-Methyl phenol BRL ug/L 10 1.9 1 *8270D 7/16/15 13:21 JMV P5G0184 3-Nitroaniline BRL ug/L 10 1.2 1 *8270D 7/16/15 13:21 JMV P5G0184 4,6-Dinitro-2-methylphenol BRL ug/L 10 2.4 1 *8270D 7/16/15 13:21 JMV P5G0184 4-Bromophenyl phenyl ether BRL ug/L 10 1.8 1 *8270D 7/16/15 13:21 JMV P5G0184 4-Chloro-3-methylphenol BRL ug/L 10 1.9 1 *8270D 7/16/15 13:21 JMV P5G0184 4-Chloroaniline BRL ug/L 10 1.8 1 *8270D 7/16/15 13:21 JMV P5G0184 4-Chlorophenyl phenyl ether BRL ug/L 10 2.0 1 *8270D 7/16/15 13:21 JMV P5G0184 4-Nitroaniline BRL ug/L 10 2.0 1 *8270D 7/16/15 13:21 JMV P5G0184 4-Nitrophenol BRL ug/L 10 0.66 1 *8270D 7/16/15 13:21 JMV P5G0184 Acenaphthene BRL ug/L 10 2.5 1 *8270D 7/16/15 13:21 JMV P5G0184 Acenaphthylene BRL ug/L 10 2.5 1 *8270D 7/16/15 13:21 JMV P5G0184 Aniline BRL ug/L 10 2.1 1 *8270D 7/16/15 13:21 JMV P5G0184 Anthracene BRL ug/L 10 3.0 1 *8270D 7/16/15 13:21 JMV P5G0184 Azobenzene BRL ug/L 10 1.8 1 *8270D 7/16/15 13:21 JMV P5G0184 Benzo(a)anthracene BRL ug/L 10 2.0 1 *8270D 7/16/15 13:21 JMV P5G0184 Benzo(a)pyrene BRL ug/L 10 2.4 1 *8270D 7/16/15 13:21 JMV P5G0184 Benzo(b)fluoranthene BRL ug/L 10 1.4 1 *8270D 7/16/15 13:21 JMV P5G0184 Benzo(g,h,i)perylene BRL ug/L 10 1.8 1 *8270D 7/16/15 13:21 JMV P5G0184 Benzo(k)fluoranthene BRL ug/L 10 2.4 1 *8270D 7/16/15 13:21 JMV P5G0184 Benzoic Acid BRL ug/L 100 2.7 1 *8270D 7/16/15 13:21 JMV P5G0184 Benzyl alcohol BRL ug/L 10 1.8 1 *8270D 7/16/15 13:21 JMV P5G0184 bis(2-Chloroethoxy)methane BRL ug/L 10 2.2 1 *8270D 7/16/15 13:21 JMV P5G0184 Bis(2-Chloroethyl)ether BRL ug/L 10 2.4 1 *8270D 7/16/15 13:21 JMV P5G0184 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 21 of 80 Laboratory Report ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. 07/22/2015 Hart & Hickman (Charlotte) Project: PTR.001-3A Client Sample ID: TMW-2 Attn: Aaron Oswald Prism Sample ID: 5070165-05 2923 South Tryon St. Ste 100 Prism Work Order: 5070165 Charlotte, NC 28203 Sample Matrix: Water Time Collected: 07/07/15 11:25 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Bis(2-chloroisopropyl)ether BRL ug/L 10 2.2 1 *8270D 7/16/15 13:21 JMV P5G0184 Bis(2-Ethylhexyl)phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 13:21 JMV P5G0184 Butyl benzyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 13:21 JMV P5G0184 Chrysene BRL ug/L 10 2.2 1 *8270D 7/16/15 13:21 JMV P5G0184 Dibenzo(a,h)anthracene BRL ug/L 10 2.0 1 *8270D 7/16/15 13:21 JMV P5G0184 Dibenzofuran BRL ug/L 10 2.3 1 *8270D 7/16/15 13:21 JMV P5G0184 Diethyl phthalate BRL ug/L 10 1.9 1 *8270D 7/16/15 13:21 JMV P5G0184 Dimethyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 13:21 JMV P5G0184 Di-n-butyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 13:21 JMV P5G0184 Di-n-octyl phthalate BRL ug/L 10 1.7 1 *8270D 7/16/15 13:21 JMV P5G0184 Fluoranthene BRL ug/L 10 2.2 1 *8270D 7/16/15 13:21 JMV P5G0184 Fluorene BRL ug/L 10 2.5 1 *8270D 7/16/15 13:21 JMV P5G0184 Hexachlorobenzene BRL ug/L 10 1.9 1 *8270D 7/16/15 13:21 JMV P5G0184 Hexachlorobutadiene BRL ug/L 10 2.6 1 *8270D 7/16/15 13:21 JMV P5G0184 Hexachlorocyclopentadiene BRL ug/L 10 2.2 1 *8270D 7/16/15 13:21 JMV P5G0184 Hexachloroethane BRL ug/L 10 2.5 1 *8270D 7/16/15 13:21 JMV P5G0184 Indeno(1,2,3-cd)pyrene BRL ug/L 10 2.1 1 *8270D 7/16/15 13:21 JMV P5G0184 Isophorone BRL ug/L 10 2.5 1 *8270D 7/16/15 13:21 JMV P5G0184 Naphthalene 22 ug/L 10 2.4 1 *8270D 7/16/15 13:21 JMV P5G0184 Nitrobenzene BRL ug/L 10 2.4 1 *8270D 7/16/15 13:21 JMV P5G0184 N-Nitroso-di-n-propylamine BRL ug/L 10 2.5 1 *8270D 7/16/15 13:21 JMV P5G0184 N-Nitrosodiphenylamine BRL ug/L 10 1.8 1 *8270D 7/16/15 13:21 JMV P5G0184 Pentachlorophenol BRL ug/L 10 2.5 1 *8270D 7/16/15 13:21 JMV P5G0184 Phenanthrene BRL ug/L 10 1.8 1 *8270D 7/16/15 13:21 JMV P5G0184 Phenol BRL ug/L 10 1.2 1 *8270D 7/16/15 13:21 JMV P5G0184 Pyrene BRL ug/L 10 2.2 1 *8270D 7/16/15 13:21 JMV P5G0184 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 100 % 49-109 2-Fluorobiphenyl 91 % 55-96 2-Fluorophenol 50 % 27-74 Nitrobenzene-d5 78 % 53-99 Phenol-d5 34 % 11-52 Terphenyl-d14 100 % 42-133 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL ug/L 0.50 0.11 1 *8260B 7/14/15 19:27 MSC P5G0244 1,1,1-Trichloroethane BRL ug/L 0.50 0.061 1 *8260B 7/14/15 19:27 MSC P5G0244 1,1,2,2-Tetrachloroethane BRL ug/L 0.50 0.036 1 *8260B 7/14/15 19:27 MSC P5G0244 1,1,2-Trichloroethane BRL ug/L 0.50 0.066 1 *8260B 7/14/15 19:27 MSC P5G0244 1,1-Dichloroethane BRL ug/L 0.50 0.083 1 *8260B 7/14/15 19:27 MSC P5G0244 1,1-Dichloroethylene BRL ug/L 0.50 0.083 1 *8260B 7/14/15 19:27 MSC P5G0244 1,1-Dichloropropylene BRL ug/L 0.50 0.051 1 *8260B 7/14/15 19:27 MSC P5G0244 1,2,3-Trichlorobenzene BRL ug/L 2.0 0.40 1 *8260B 7/14/15 19:27 MSC P5G0244 1,2,3-Trichloropropane BRL ug/L 1.0 0.14 1 *8260B 7/14/15 19:27 MSC P5G0244 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 22 of 80 ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-3A Sample Matrix: Water Laboratory Report 07/22/2015 Client Sample ID: TMW-2 Prism Sample ID: 5070165-05 Prism Work Order: 5070165 Time Collected: 07/07/15 11:25 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,2,4-Trichlorobenzene BRL ug/L 1.0 0.13 1 *8260B 7/14/15 19:27 MSC P5G0244 1,2,4-Trimethyl benzene BRL ug/L 0.50 0.054 1 *8260B 7/14/15 19:27 MSC P5G0244 1,2-Dibromo-3-chloropropane BRL ug/L 2.0 0.17 1 *8260B 7/14/15 19:27 MSC P5G0244 1,2-Dibromoethane BRL ug/L 0.50 0.051 1 *8260B 7/14/15 19:27 MSC P5G0244 1,2-Dichlorobenzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 19:27 MSC P5G0244 1,2-Dichloroethane BRL ug/L 0.50 0.066 1 *8260B 7/14/15 19:27 MSC P5G0244 1,2-Dichloropropane BRL ug/L 0.50 0.11 1 *8260B 7/14/15 19:27 MSC P5G0244 1,3,5-Trimethyl benzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 19:27 MSC P5G0244 1,3-Dichlorobenzene BRL ug/L 0.50 0.054 1 *8260B 7/14/15 19:27 MSC P5G0244 1,3-Dichloropropane BRL ug/L 0.50 0.043 1 *8260B 7/14/15 19:27 MSC P5G0244 1,4-Dichlorobenzene BRL ug/L 0.50 0.050 1 *8260B 7/14/15 19:27 MSC P5G0244 2,2-Dichloropropane BRL ug/L 2.0 0.11 1 *8260B 7/14/15 19:27 MSC P5G0244 2-Chloroethyl Vinyl Ether BRL ug/L 5.0 0.37 1 *8260B 7/14/15 19:27 MSC P5G0244 2-Chlorotoluene BRL ug/L 0.50 0.066 1 *8260B 7/14/15 19:27 MSC P5G0244 4-Chlorotoluene BRL ug/L 0.50 0.050 1 *8260B 7/14/15 19:27 MSC P5G0244 4-Isopropyltoluene BRL ug/L 0.50 0.089 1 *8260B 7/14/15 19:27 MSC P5G0244 Acetone BRL ug/L 5.0 0.31 1 *8260B 7/14/15 19:27 MSC P5G0244 Acrolein BRL ug/L 20 0.20 1 *8260B 7/14/15 19:27 MSC P5G0244 Acrylonitrile BRL ug/L 20 0.20 1 *8260B 7/14/15 19:27 MSC P5G0244 Benzene BRL ug/L 0.50 0.048 1 *8260B 7/14/15 19:27 MSC P5G0244 Bromobenzene BRL ug/L 0.50 0.057 1 *8260B 7/14/15 19:27 MSC P5G0244 Bromochloromethane BRL ug/L 0.50 0.14 1 *8260B 7/14/15 19:27 MSC P5G0244 Bromodichloromethane BRL ug/L 0.50 0.062 1 *8260B 7/14/15 19:27 MSC P5G0244 Bromoform BRL ug/L 1.0 0.040 1 *8260B 7/14/15 19:27 MSC P5G0244 Bromomethane BRL ug/L 1.0 0.18 1 *8260B 7/14/15 19:27 MSC P5G0244 Carbon disulfide BRL ug/L 5.0 0.075 1 *8260B 7/14/15 19:27 MSC P5G0244 Carbon Tetrachloride BRL ug/L 0.50 0.11 1 *8260B 7/14/15 19:27 MSC P5G0244 Chlorobenzene BRL ug/L 0.50 0.062 1 *8260B 7/14/15 19:27 MSC P5G0244 Chloroethane BRL ug/L 0.50 0.22 1 *8260B 7/14/15 19:27 MSC P5G0244 Chloroform BRL ug/L 0.50 0.076 1 *8260B 7/14/15 19:27 MSC P5G0244 Chloromethane BRL ug/L 0.50 0.079 1 *8260B 7/14/15 19:27 MSC P5G0244 cis-1,2-Dichloroethylene BRL ug/L 0.50 0.056 1 *8260B 7/14/15 19:27 MSC P5G0244 cis-1,3-Dichloropropylene BRL ug/L 0.50 0.079 1 *8260B 7/14/15 19:27 MSC P5G0244 Dibromochloromethane BRL ug/L 0.50 0.081 1 *8260B 7/14/15 19:27 MSC P5G0244 Dibromomethane BRL ug/L 0.50 0.065 1 *8260B 7/14/15 19:27 MSC P5G0244 Dichlorodifluoromethane BRL ug/L 1.0 0.11 1 *8260B 7/14/15 19:27 MSC P5G0244 Ethylbenzene BRL ug/L 0.50 0.061 1 *8260B 7/14/15 19:27 MSC P5G0244 Hexachlorobutadiene BRL ug/L 2.0 0.16 1 *8260B 7/14/15 19:27 MSC P5G0244 Isopropyl Ether 0.56 ug/L 0.50 0.050 1 *8260B 7/14/15 19:27 MSC P5G0244 Isopropylbenzene (Cumene) BRL ug/L 0.50 0.054 1 *8260B 7/14/15 19:27 MSC P5G0244 m,p-Xylenes BRL ug/L 1.0 0.12 1 *8260B 7/14/15 19:27 MSC P5G0244 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 5.0 0.065 1 *8260B 7/14/15 19:27 MSC P5G0244 Methyl Ethyl Ketone (2-Butanone) BRL ug/L 5.0 0.24 1 *8260B 7/14/15 19:27 MSC P5G0244 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 23 of 80 Laboratory Report ` Full -Service P R S M Analytical & / Environmental Solutions LABORATORIES INC. 07/22/2015 Hart & Hickman (Charlotte) Project: PTR.001-3A Client Sample ID: TMW-2 Attn: Aaron Oswald Prism Sample ID: 5070165-05 2923 South Tryon St. Ste 100 Prism Work Order: 5070165 Charlotte, NC 28203 Sample Matrix: Water Time Collected: 07/07/15 11:25 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Methyl Isobutyl Ketone BRL ug/L 5.0 0.078 1 *8260B 7/14/15 19:27 MSC P5G0244 Methylene Chloride BRL ug/L 1.0 0.083 1 *8260B 7/14/15 19:27 MSC P5G0244 Methyl-tert-Butyl Ether BRL ug/L 0.50 0.042 1 *8260B 7/14/15 19:27 MSC P5G0244 Naphthalene 28 ug/L 1.0 0.19 1 *8260B 7/14/15 19:27 MSC P5G0244 n-Butylbenzene BRL ug/L 1.0 0.076 1 *8260B 7/14/15 19:27 MSC P5G0244 n-Propylbenzene BRL ug/L 0.50 0.087 1 *8260B 7/14/15 19:27 MSC P5G0244 o-Xylene BRL ug/L 0.50 0.044 1 *8260B 7/14/15 19:27 MSC P5G0244 sec-Butylbenzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 19:27 MSC P5G0244 Styrene BRL ug/L 0.50 0.047 1 *8260B 7/14/15 19:27 MSC P5G0244 tert-Butylbenzene BRL ug/L 0.50 0.088 1 *8260B 7/14/15 19:27 MSC P5G0244 Tetrachloroethylene 25 ug/L 0.50 0.098 1 *8260B 7/14/15 19:27 MSC P5G0244 Toluene BRL ug/L 0.50 0.044 1 *8260B 7/14/15 19:27 MSC P5G0244 trans-1,2-Dichloroethylene BRL ug/L 0.50 0.094 1 *8260B 7/14/15 19:27 MSC P5G0244 trans- 1,3-Dichloropropylene BRL ug/L 0.50 0.070 1 *8260B 7/14/15 19:27 MSC P5G0244 Trichloroethylene 0.80 ug/L 0.50 0.078 1 *8260B 7/14/15 19:27 MSC P5G0244 Trichlorofluoromethane BRL ug/L 0.50 0.062 1 *8260B 7/14/15 19:27 MSC P5G0244 Vinyl acetate BRL ug/L 2.0 0.060 1 *8260B 7/14/15 19:27 MSC P5G0244 Vinyl chloride BRL ug/L 0.50 0.097 1 *8260B 7/14/15 19:27 MSC P5G0244 Surrogate Recovery Control Limits 4-Bromofluorobenzene 92 % 80-124 Dibromofluoromethane 102 % 75-129 Toluene-d8 94 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 24 of 80 PR I S M Full -Service Analytical Environmental Solutions LABORATORIES INC. Laboratory Report 07/22/2015 Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-3A Client Sample ID: TMW-3 Prism Sample ID: 5070165-06 Prism Work Order: 5070165 Sample Matrix: Water Time Collected: 07/07/15 13:25 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Semivolatile Organic Compounds by GC/MS 1,2,4-Trichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 13:43 JMV P5G0184 1,2-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 13:43 JMV P5G0184 1,3-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 13:43 JMV P5G0184 1,4-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 13:43 JMV P5G0184 1-Methyl naphthalene BRL ug/L 10 2.4 1 *8270D 7/16/15 13:43 JMV P5G0184 2,4,5-Trichlorophenol BRL ug/L 10 2.3 1 *8270D 7/16/15 13:43 JMV P5G0184 2,4,6-Trichlorophenol BRL ug/L 10 2.6 1 *8270D 7/16/15 13:43 JMV P5G0184 2,4-Dichlorophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 13:43 JMV P5G0184 2,4-Dimethylphenol BRL ug/L 10 2.3 1 *8270D 7/16/15 13:43 JMV P5G0184 2,4-Dinitrophenol BRL ug/L 10 3.7 1 *8270D 7/16/15 13:43 JMV P5G0184 2,4-Dinitrotoluene BRL ug/L 10 1.9 1 *8270D 7/16/15 13:43 JMV P5G0184 2,6-Dinitrotoluene BRL ug/L 10 2.0 1 *8270D 7/16/15 13:43 JMV P5G0184 2-Chloronaphthalene BRL ug/L 10 3.4 1 *8270D 7/16/15 13:43 JMV P5G0184 2-Chlorophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 13:43 JMV P5G0184 2-Methyl naphthalene BRL ug/L 10 2.2 1 *8270D 7/16/15 13:43 JMV P5G0184 2-Methylphenol BRL ug/L 10 2.1 1 *8270D 7/16/15 13:43 JMV P5G0184 2-Nitroaniline BRL ug/L 10 2.2 1 *8270D 7/16/15 13:43 JMV P5G0184 2-Nitrophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 13:43 JMV P5G0184 3,3'-Dichlorobenzidine BRL ug/L 10 2.2 1 *8270D 7/16/15 13:43 JMV P5G0184 3/4-Methyl phenol BRL ug/L 10 1.9 1 *8270D 7/16/15 13:43 JMV P5G0184 3-Nitroaniline BRL ug/L 10 1.2 1 *8270D 7/16/15 13:43 JMV P5G0184 4,6-Dinitro-2-methylphenol BRL ug/L 10 2.4 1 *8270D 7/16/15 13:43 JMV P5G0184 4-Bromophenyl phenyl ether BRL ug/L 10 1.8 1 *8270D 7/16/15 13:43 JMV P5G0184 4-Chloro-3-methylphenol BRL ug/L 10 1.9 1 *8270D 7/16/15 13:43 JMV P5G0184 4-Chloroaniline BRL ug/L 10 1.8 1 *8270D 7/16/15 13:43 JMV P5G0184 4-Chlorophenyl phenyl ether BRL ug/L 10 2.0 1 *8270D 7/16/15 13:43 JMV P5G0184 4-Nitroaniline BRL ug/L 10 2.0 1 *8270D 7/16/15 13:43 JMV P5G0184 4-Nitrophenol BRL ug/L 10 0.66 1 *8270D 7/16/15 13:43 JMV P5G0184 Acenaphthene BRL ug/L 10 2.5 1 *8270D 7/16/15 13:43 JMV P5G0184 Acenaphthylene BRL ug/L 10 2.5 1 *8270D 7/16/15 13:43 JMV P5G0184 Aniline BRL ug/L 10 2.1 1 *8270D 7/16/15 13:43 JMV P5G0184 Anthracene BRL ug/L 10 3.0 1 *8270D 7/16/15 13:43 JMV P5G0184 Azobenzene BRL ug/L 10 1.8 1 *8270D 7/16/15 13:43 JMV P5G0184 Benzo(a)anthracene BRL ug/L 10 2.0 1 *8270D 7/16/15 13:43 JMV P5G0184 Benzo(a)pyrene BRL ug/L 10 2.4 1 *8270D 7/16/15 13:43 JMV P5G0184 Benzo(b)fluoranthene BRL ug/L 10 1.4 1 *8270D 7/16/15 13:43 JMV P5G0184 Benzo(g,h,i)perylene BRL ug/L 10 1.8 1 *8270D 7/16/15 13:43 JMV P5G0184 Benzo(k)fluoranthene BRL ug/L 10 2.4 1 *8270D 7/16/15 13:43 JMV P5G0184 Benzoic Acid BRL ug/L 100 2.7 1 *8270D 7/16/15 13:43 JMV P5G0184 Benzyl alcohol BRL ug/L 10 1.8 1 *8270D 7/16/15 13:43 JMV P5G0184 bis(2-Chloroethoxy)methane BRL ug/L 10 2.2 1 *8270D 7/16/15 13:43 JMV P5G0184 Bis(2-Chloroethyl)ether BRL ug/L 10 2.4 1 *8270D 7/16/15 13:43 JMV P5G0184 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 25 of 80 Laboratory Report ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. 07/22/2015 Hart & Hickman (Charlotte) Project: PTR.001-3A Client Sample ID: TMW-3 Attn: Aaron Oswald Prism Sample ID: 5070165-06 2923 South Tryon St. Ste 100 Prism Work Order: 5070165 Charlotte, NC 28203 Sample Matrix: Water Time Collected: 07/07/15 13:25 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Bis(2-chloroisopropyl)ether BRL ug/L 10 2.2 1 *8270D 7/16/15 13:43 JMV P5G0184 Bis(2-Ethylhexyl)phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 13:43 JMV P5G0184 Butyl benzyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 13:43 JMV P5G0184 Chrysene BRL ug/L 10 2.2 1 *8270D 7/16/15 13:43 JMV P5G0184 Dibenzo(a,h)anthracene BRL ug/L 10 2.0 1 *8270D 7/16/15 13:43 JMV P5G0184 Dibenzofuran BRL ug/L 10 2.3 1 *8270D 7/16/15 13:43 JMV P5G0184 Diethyl phthalate BRL ug/L 10 1.9 1 *8270D 7/16/15 13:43 JMV P5G0184 Dimethyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 13:43 JMV P5G0184 Di-n-butyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 13:43 JMV P5G0184 Di-n-octyl phthalate BRL ug/L 10 1.7 1 *8270D 7/16/15 13:43 JMV P5G0184 Fluoranthene BRL ug/L 10 2.2 1 *8270D 7/16/15 13:43 JMV P5G0184 Fluorene BRL ug/L 10 2.5 1 *8270D 7/16/15 13:43 JMV P5G0184 Hexachlorobenzene BRL ug/L 10 1.9 1 *8270D 7/16/15 13:43 JMV P5G0184 Hexachlorobutadiene BRL ug/L 10 2.6 1 *8270D 7/16/15 13:43 JMV P5G0184 Hexachlorocyclopentadiene BRL ug/L 10 2.2 1 *8270D 7/16/15 13:43 JMV P5G0184 Hexachloroethane BRL ug/L 10 2.5 1 *8270D 7/16/15 13:43 JMV P5G0184 Indeno(1,2,3-cd)pyrene BRL ug/L 10 2.1 1 *8270D 7/16/15 13:43 JMV P5G0184 Isophorone BRL ug/L 10 2.5 1 *8270D 7/16/15 13:43 JMV P5G0184 Naphthalene BRL ug/L 10 2.4 1 *8270D 7/16/15 13:43 JMV P5G0184 Nitrobenzene BRL ug/L 10 2.4 1 *8270D 7/16/15 13:43 JMV P5G0184 N-Nitroso-di-n-propylamine BRL ug/L 10 2.5 1 *8270D 7/16/15 13:43 JMV P5G0184 N-Nitrosodiphenylamine BRL ug/L 10 1.8 1 *8270D 7/16/15 13:43 JMV P5G0184 Pentachlorophenol BRL ug/L 10 2.5 1 *8270D 7/16/15 13:43 JMV P5G0184 Phenanthrene BRL ug/L 10 1.8 1 *8270D 7/16/15 13:43 JMV P5G0184 Phenol BRL ug/L 10 1.2 1 *8270D 7/16/15 13:43 JMV P5G0184 Pyrene BRL ug/L 10 2.2 1 *8270D 7/16/15 13:43 JMV P5G0184 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 94 % 49-109 2-Fluorobiphenyl 87 % 55-96 2-Fluorophenol 50 % 27-74 Nitrobenzene-d5 79 % 53-99 Phenol-d5 33 % 11-52 Terphenyl-d14 92 % 42-133 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL ug/L 0.50 0.11 1 *8260B 7/14/15 20:01 MSC P5G0244 1,1,1-Trichloroethane BRL ug/L 0.50 0.061 1 *8260B 7/14/15 20:01 MSC P5G0244 1,1,2,2-Tetrachloroethane BRL ug/L 0.50 0.036 1 *8260B 7/14/15 20:01 MSC P5G0244 1,1,2-Trichloroethane BRL ug/L 0.50 0.066 1 *8260B 7/14/15 20:01 MSC P5G0244 1,1-Dichloroethane BRL ug/L 0.50 0.083 1 *8260B 7/14/15 20:01 MSC P5G0244 1,1-Dichloroethylene BRL ug/L 0.50 0.083 1 *8260B 7/14/15 20:01 MSC P5G0244 1,1-Dichloropropylene BRL ug/L 0.50 0.051 1 *8260B 7/14/15 20:01 MSC P5G0244 1,2,3-Trichlorobenzene BRL ug/L 2.0 0.40 1 *8260B 7/14/15 20:01 MSC P5G0244 1,2,3-Trichloropropane BRL ug/L 1.0 0.14 1 *8260B 7/14/15 20:01 MSC P5G0244 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 26 of 80 ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-3A Sample Matrix: Water Laboratory Report 07/22/2015 Client Sample ID: TMW-3 Prism Sample ID: 5070165-06 Prism Work Order: 5070165 Time Collected: 07/07/15 13:25 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,2,4-Trichlorobenzene BRL ug/L 1.0 0.13 1 *8260B 7/14/15 20:01 MSC P5G0244 1,2,4-Trimethyl benzene BRL ug/L 0.50 0.054 1 *8260B 7/14/15 20:01 MSC P5G0244 1,2-Dibromo-3-chloropropane BRL ug/L 2.0 0.17 1 *8260B 7/14/15 20:01 MSC P5G0244 1,2-Dibromoethane BRL ug/L 0.50 0.051 1 *8260B 7/14/15 20:01 MSC P5G0244 1,2-Dichlorobenzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 20:01 MSC P5G0244 1,2-Dichloroethane BRL ug/L 0.50 0.066 1 *8260B 7/14/15 20:01 MSC P5G0244 1,2-Dichloropropane BRL ug/L 0.50 0.11 1 *8260B 7/14/15 20:01 MSC P5G0244 1,3,5-Trimethyl benzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 20:01 MSC P5G0244 1,3-Dichlorobenzene BRL ug/L 0.50 0.054 1 *8260B 7/14/15 20:01 MSC P5G0244 1,3-Dichloropropane BRL ug/L 0.50 0.043 1 *8260B 7/14/15 20:01 MSC P5G0244 1,4-Dichlorobenzene BRL ug/L 0.50 0.050 1 *8260B 7/14/15 20:01 MSC P5G0244 2,2-Dichloropropane BRL ug/L 2.0 0.11 1 *8260B 7/14/15 20:01 MSC P5G0244 2-Chloroethyl Vinyl Ether BRL ug/L 5.0 0.37 1 *8260B 7/14/15 20:01 MSC P5G0244 2-Chlorotoluene BRL ug/L 0.50 0.066 1 *8260B 7/14/15 20:01 MSC P5G0244 4-Chlorotoluene BRL ug/L 0.50 0.050 1 *8260B 7/14/15 20:01 MSC P5G0244 4-Isopropyltoluene BRL ug/L 0.50 0.089 1 *8260B 7/14/15 20:01 MSC P5G0244 Acetone BRL ug/L 5.0 0.31 1 *8260B 7/14/15 20:01 MSC P5G0244 Acrolein BRL ug/L 20 0.20 1 *8260B 7/14/15 20:01 MSC P5G0244 Acrylonitrile BRL ug/L 20 0.20 1 *8260B 7/14/15 20:01 MSC P5G0244 Benzene BRL ug/L 0.50 0.048 1 *8260B 7/14/15 20:01 MSC P5G0244 Bromobenzene BRL ug/L 0.50 0.057 1 *8260B 7/14/15 20:01 MSC P5G0244 Bromochloromethane BRL ug/L 0.50 0.14 1 *8260B 7/14/15 20:01 MSC P5G0244 Bromodichloromethane BRL ug/L 0.50 0.062 1 *8260B 7/14/15 20:01 MSC P5G0244 Bromoform BRL ug/L 1.0 0.040 1 *8260B 7/14/15 20:01 MSC P5G0244 Bromomethane BRL ug/L 1.0 0.18 1 *8260B 7/14/15 20:01 MSC P5G0244 Carbon disulfide BRL ug/L 5.0 0.075 1 *8260B 7/14/15 20:01 MSC P5G0244 Carbon Tetrachloride BRL ug/L 0.50 0.11 1 *8260B 7/14/15 20:01 MSC P5G0244 Chlorobenzene BRL ug/L 0.50 0.062 1 *8260B 7/14/15 20:01 MSC P5G0244 Chloroethane BRL ug/L 0.50 0.22 1 *8260B 7/14/15 20:01 MSC P5G0244 Chloroform 2.2 ug/L 0.50 0.076 1 *8260B 7/14/15 20:01 MSC P5G0244 Chloromethane BRL ug/L 0.50 0.079 1 *8260B 7/14/15 20:01 MSC P5G0244 cis-1,2-Dichloroethylene BRL ug/L 0.50 0.056 1 *8260B 7/14/15 20:01 MSC P5G0244 cis-1,3-Dichloropropylene BRL ug/L 0.50 0.079 1 *8260B 7/14/15 20:01 MSC P5G0244 Dibromochloromethane BRL ug/L 0.50 0.081 1 *8260B 7/14/15 20:01 MSC P5G0244 Dibromomethane BRL ug/L 0.50 0.065 1 *8260B 7/14/15 20:01 MSC P5G0244 Dichlorodifluoromethane BRL ug/L 1.0 0.11 1 *8260B 7/14/15 20:01 MSC P5G0244 Ethylbenzene BRL ug/L 0.50 0.061 1 *8260B 7/14/15 20:01 MSC P5G0244 Hexachlorobutadiene BRL ug/L 2.0 0.16 1 *8260B 7/14/15 20:01 MSC P5G0244 Isopropyl Ether BRL ug/L 0.50 0.050 1 *8260B 7/14/15 20:01 MSC P5G0244 Isopropylbenzene (Cumene) BRL ug/L 0.50 0.054 1 *8260B 7/14/15 20:01 MSC P5G0244 m,p-Xylenes BRL ug/L 1.0 0.12 1 *8260B 7/14/15 20:01 MSC P5G0244 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 5.0 0.065 1 *8260B 7/14/15 20:01 MSC P5G0244 Methyl Ethyl Ketone (2-Butanone) BRL ug/L 5.0 0.24 1 *8260B 7/14/15 20:01 MSC P5G0244 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 27 of 80 Laboratory Report ` Full -Service P R S M Analytical & / Environmental Solutions LABORATORIES INC. 07/22/2015 Hart & Hickman (Charlotte) Project: PTR.001-3A Client Sample ID: TMW-3 Attn: Aaron Oswald Prism Sample ID: 5070165-06 2923 South Tryon St. Ste 100 Prism Work Order: 5070165 Charlotte, NC 28203 Sample Matrix: Water Time Collected: 07/07/15 13:25 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Methyl Isobutyl Ketone BRL ug/L 5.0 0.078 1 *8260B 7/14/15 20:01 MSC P5G0244 Methylene Chloride BRL ug/L 1.0 0.083 1 *8260B 7/14/15 20:01 MSC P5G0244 Methyl-tert-Butyl Ether BRL ug/L 0.50 0.042 1 *8260B 7/14/15 20:01 MSC P5G0244 Naphthalene BRL ug/L 1.0 0.19 1 *8260B 7/14/15 20:01 MSC P5G0244 n-Butylbenzene BRL ug/L 1.0 0.076 1 *8260B 7/14/15 20:01 MSC P5G0244 n-Propylbenzene BRL ug/L 0.50 0.087 1 *8260B 7/14/15 20:01 MSC P5G0244 o-Xylene BRL ug/L 0.50 0.044 1 *8260B 7/14/15 20:01 MSC P5G0244 sec-Butylbenzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 20:01 MSC P5G0244 Styrene BRL ug/L 0.50 0.047 1 *8260B 7/14/15 20:01 MSC P5G0244 tert-Butylbenzene BRL ug/L 0.50 0.088 1 *8260B 7/14/15 20:01 MSC P5G0244 Tetrachloroethylene 5.4 ug/L 0.50 0.098 1 *8260B 7/14/15 20:01 MSC P5G0244 Toluene BRL ug/L 0.50 0.044 1 *8260B 7/14/15 20:01 MSC P5G0244 trans-1,2-Dichloroethylene BRL ug/L 0.50 0.094 1 *8260B 7/14/15 20:01 MSC P5G0244 trans-1,3-Dichloropropylene BRL ug/L 0.50 0.070 1 *8260B 7/14/15 20:01 MSC P5G0244 Trichloroethylene BRL ug/L 0.50 0.078 1 *8260B 7/14/15 20:01 MSC P5G0244 Trichlorofluoromethane BRL ug/L 0.50 0.062 1 *8260B 7/14/15 20:01 MSC P5G0244 Vinyl acetate BRL ug/L 2.0 0.060 1 *8260B 7/14/15 20:01 MSC P5G0244 Vinyl chloride BRL ug/L 0.50 0.097 1 *8260B 7/14/15 20:01 MSC P5G0244 Surrogate Recovery Control Limits 4-Bromofluorobenzene 91 % 80-124 Dibromofluoromethane 102 % 75-129 Toluene-d8 94 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 28 of 80 PR I S M Full -Service Analytical Environmental Solutions LABORATORIES INC. Laboratory Report 07/22/2015 Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-3A Client Sample ID: TMW-4 Prism Sample ID: 5070165-07 Prism Work Order: 5070165 Sample Matrix: Water Time Collected: 07/08/15 08:55 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Semivolatile Organic Compounds by GC/MS 1,2,4-Trichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 14:04 JMV P5G0184 1,2-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 14:04 JMV P5G0184 1,3-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 14:04 JMV P5G0184 1,4-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 14:04 JMV P5G0184 1-Methyl naphthalene BRL ug/L 10 2.4 1 *8270D 7/16/15 14:04 JMV P5G0184 2,4,5-Trichlorophenol BRL ug/L 10 2.3 1 *8270D 7/16/15 14:04 JMV P5G0184 2,4,6-Trichlorophenol BRL ug/L 10 2.6 1 *8270D 7/16/15 14:04 JMV P5G0184 2,4-Dichlorophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 14:04 JMV P5G0184 2,4-Dimethylphenol BRL ug/L 10 2.3 1 *8270D 7/16/15 14:04 JMV P5G0184 2,4-Dinitrophenol BRL ug/L 10 3.7 1 *8270D 7/16/15 14:04 JMV P5G0184 2,4-Dinitrotoluene BRL ug/L 10 1.9 1 *8270D 7/16/15 14:04 JMV P5G0184 2,6-Dinitrotoluene BRL ug/L 10 2.0 1 *8270D 7/16/15 14:04 JMV P5G0184 2-Chloronaphthalene BRL ug/L 10 3.4 1 *8270D 7/16/15 14:04 JMV P5G0184 2-Chlorophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 14:04 JMV P5G0184 2-Methyl naphthalene BRL ug/L 10 2.2 1 *8270D 7/16/15 14:04 JMV P5G0184 2-Methylphenol BRL ug/L 10 2.1 1 *8270D 7/16/15 14:04 JMV P5G0184 2-Nitroaniline BRL ug/L 10 2.2 1 *8270D 7/16/15 14:04 JMV P5G0184 2-Nitrophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 14:04 JMV P5G0184 3,3'-Dichlorobenzidine BRL ug/L 10 2.2 1 *8270D 7/16/15 14:04 JMV P5G0184 3/4-Methyl phenol BRL ug/L 10 1.9 1 *8270D 7/16/15 14:04 JMV P5G0184 3-Nitroaniline BRL ug/L 10 1.2 1 *8270D 7/16/15 14:04 JMV P5G0184 4,6-Dinitro-2-methylphenol BRL ug/L 10 2.4 1 *8270D 7/16/15 14:04 JMV P5G0184 4-Bromophenyl phenyl ether BRL ug/L 10 1.8 1 *8270D 7/16/15 14:04 JMV P5G0184 4-Chloro-3-methylphenol BRL ug/L 10 1.9 1 *8270D 7/16/15 14:04 JMV P5G0184 4-Chloroaniline BRL ug/L 10 1.8 1 *8270D 7/16/15 14:04 JMV P5G0184 4-Chlorophenyl phenyl ether BRL ug/L 10 2.0 1 *8270D 7/16/15 14:04 JMV P5G0184 4-Nitroaniline BRL ug/L 10 2.0 1 *8270D 7/16/15 14:04 JMV P5G0184 4-Nitrophenol BRL ug/L 10 0.66 1 *8270D 7/16/15 14:04 JMV P5G0184 Acenaphthene BRL ug/L 10 2.5 1 *8270D 7/16/15 14:04 JMV P5G0184 Acenaphthylene BRL ug/L 10 2.5 1 *8270D 7/16/15 14:04 JMV P5G0184 Aniline BRL ug/L 10 2.1 1 *8270D 7/16/15 14:04 JMV P5G0184 Anthracene BRL ug/L 10 3.0 1 *8270D 7/16/15 14:04 JMV P5G0184 Azobenzene BRL ug/L 10 1.8 1 *8270D 7/16/15 14:04 JMV P5G0184 Benzo(a)anthracene BRL ug/L 10 2.0 1 *8270D 7/16/15 14:04 JMV P5G0184 Benzo(a)pyrene BRL ug/L 10 2.4 1 *8270D 7/16/15 14:04 JMV P5G0184 Benzo(b)fluoranthene BRL ug/L 10 1.4 1 *8270D 7/16/15 14:04 JMV P5G0184 Benzo(g,h,i)perylene BRL ug/L 10 1.8 1 *8270D 7/16/15 14:04 JMV P5G0184 Benzo(k)fluoranthene BRL ug/L 10 2.4 1 *8270D 7/16/15 14:04 JMV P5G0184 Benzoic Acid BRL ug/L 100 2.7 1 *8270D 7/16/15 14:04 JMV P5G0184 Benzyl alcohol BRL ug/L 10 1.8 1 *8270D 7/16/15 14:04 JMV P5G0184 bis(2-Chloroethoxy)methane BRL ug/L 10 2.2 1 *8270D 7/16/15 14:04 JMV P5G0184 Bis(2-Chloroethyl)ether BRL ug/L 10 2.4 1 *8270D 7/16/15 14:04 JMV P5G0184 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 29 of 80 Laboratory Report ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. 07/22/2015 Hart & Hickman (Charlotte) Project: PTR.001-3A Client Sample ID: TMW-4 Attn: Aaron Oswald Prism Sample ID: 5070165-07 2923 South Tryon St. Ste 100 Prism Work Order: 5070165 Charlotte, NC 28203 Sample Matrix: Water Time Collected: 07/08/15 08:55 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Bis(2-chloroisopropyl)ether BRL ug/L 10 2.2 1 *8270D 7/16/15 14:04 JMV P5G0184 Bis(2-Ethylhexyl)phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 14:04 JMV P5G0184 Butyl benzyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 14:04 JMV P5G0184 Chrysene BRL ug/L 10 2.2 1 *8270D 7/16/15 14:04 JMV P5G0184 Dibenzo(a,h)anthracene BRL ug/L 10 2.0 1 *8270D 7/16/15 14:04 JMV P5G0184 Dibenzofuran BRL ug/L 10 2.3 1 *8270D 7/16/15 14:04 JMV P5G0184 Diethyl phthalate BRL ug/L 10 1.9 1 *8270D 7/16/15 14:04 JMV P5G0184 Dimethyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 14:04 JMV P5G0184 Di-n-butyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 14:04 JMV P5G0184 Di-n-octyl phthalate BRL ug/L 10 1.7 1 *8270D 7/16/15 14:04 JMV P5G0184 Fluoranthene BRL ug/L 10 2.2 1 *8270D 7/16/15 14:04 JMV P5G0184 Fluorene BRL ug/L 10 2.5 1 *8270D 7/16/15 14:04 JMV P5G0184 Hexachlorobenzene BRL ug/L 10 1.9 1 *8270D 7/16/15 14:04 JMV P5G0184 Hexachlorobutadiene BRL ug/L 10 2.6 1 *8270D 7/16/15 14:04 JMV P5G0184 Hexachlorocyclopentadiene BRL ug/L 10 2.2 1 *8270D 7/16/15 14:04 JMV P5G0184 Hexachloroethane BRL ug/L 10 2.5 1 *8270D 7/16/15 14:04 JMV P5G0184 Indeno(1,2,3-cd)pyrene BRL ug/L 10 2.1 1 *8270D 7/16/15 14:04 JMV P5G0184 Isophorone BRL ug/L 10 2.5 1 *8270D 7/16/15 14:04 JMV P5G0184 Naphthalene BRL ug/L 10 2.4 1 *8270D 7/16/15 14:04 JMV P5G0184 Nitrobenzene BRL ug/L 10 2.4 1 *8270D 7/16/15 14:04 JMV P5G0184 N-Nitroso-di-n-propylamine BRL ug/L 10 2.5 1 *8270D 7/16/15 14:04 JMV P5G0184 N-Nitrosodiphenylamine BRL ug/L 10 1.8 1 *8270D 7/16/15 14:04 JMV P5G0184 Pentachlorophenol BRL ug/L 10 2.5 1 *8270D 7/16/15 14:04 JMV P5G0184 Phenanthrene BRL ug/L 10 1.8 1 *8270D 7/16/15 14:04 JMV P5G0184 Phenol BRL ug/L 10 1.2 1 *8270D 7/16/15 14:04 JMV P5G0184 Pyrene BRL ug/L 10 2.2 1 *8270D 7/16/15 14:04 JMV P5G0184 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 93 % 49-109 2-Fluorobiphenyl 90 % 55-96 2-Fluorophenol 48 % 27-74 Nitrobenzene-d5 84 % 53-99 Phenol-d5 32 % 11-52 Terphenyl-d14 90 % 42-133 Total Metals Mercury BRL mg/L 0.00020 0.000011 1 *7470A 7/14/15 13:47 JAB P5G0189 Arsenic BRL mg/L 0.010 0.00070 1 *6010C 7/14/15 17:02 BGM P5G0170 Barium 0.19 mg/L 0.010 0.00070 1 *6010C 7114/15 17:02 BGM P5G0170 Cadmium BRL mg/L 0.0010 0.00010 1 *6010C 7/14/15 17:02 BGM P5G0170 Chromium BRL mg/L 0.0050 0.00060 1 *6010C 7/14/15 17:02 BGM P5G0170 Lead BRL mg/L 0.0050 0.0013 1 *6010C 7/14/15 17:02 BGM P5G0170 Selenium BRL mg/L 0.020 0.0032 1 *6010C 7/14/15 17:02 BGM P5G0170 Silver BRL mg/L 0.0050 0.00020 1 *6010C 7/14/15 17:02 BGM P5G0170 Volatile Organic Compounds by GC/MS This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 30 of 80 ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-3A Sample Matrix: Water Laboratory Report 07/22/2015 Client Sample ID: TMW-4 Prism Sample ID: 5070165-07 Prism Work Order: 5070165 Time Collected: 07/08/15 08:55 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,1,1,2-Tetrachloroethane BRL ug/L 0.50 0.11 1 *8260B 7/14/15 20:36 MSC P5G0244 1,1,1-Trichloroethane BRL ug/L 0.50 0.061 1 *8260B 7/14/15 20:36 MSC P5G0244 1,1,2,2-Tetrachloroethane BRL ug/L 0.50 0.036 1 *8260B 7/14/15 20:36 MSC P5G0244 1,1,2-Trichloroethane BRL ug/L 0.50 0.066 1 *8260B 7/14/15 20:36 MSC P5G0244 1,1-Dichloroethane 1.7 ug/L 0.50 0.083 1 *8260B 7/14/15 20:36 MSC P5G0244 1,1-Dichloroethylene 0.94 ug/L 0.50 0.083 1 *8260B 7/14/15 20:36 MSC P5G0244 1,1-Dichloropropylene BRL ug/L 0.50 0.051 1 *8260B 7/14/15 20:36 MSC P5G0244 1,2,3-Trichlorobenzene BRL ug/L 2.0 0.40 1 *8260B 7/14/15 20:36 MSC P5G0244 1,2,3-Trichloropropane BRL ug/L 1.0 0.14 1 *8260B 7/14/15 20:36 MSC P5G0244 1,2,4-Trichlorobenzene BRL ug/L 1.0 0.13 1 *8260B 7/14/15 20:36 MSC P5G0244 1,2,4-Trimethyl benzene BRL ug/L 0.50 0.054 1 *8260B 7/14/15 20:36 MSC P5G0244 1,2-Dibromo-3-chloropropane BRL ug/L 2.0 0.17 1 *8260B 7/14/15 20:36 MSC P5G0244 1,2-Dibromoethane BRL ug/L 0.50 0.051 1 *8260B 7/14/15 20:36 MSC P5G0244 1,2-Dichlorobenzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 20:36 MSC P5G0244 1,2-Dichloroethane BRL ug/L 0.50 0.066 1 *8260B 7/14/15 20:36 MSC P5G0244 1,2-Dichloropropane BRL ug/L 0.50 0.11 1 *8260B 7/14/15 20:36 MSC P5G0244 1,3,5-Trimethyl benzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 20:36 MSC P5G0244 1,3-Dichlorobenzene BRL ug/L 0.50 0.054 1 *8260B 7/14/15 20:36 MSC P5G0244 1,3-Dichloropropane BRL ug/L 0.50 0.043 1 *8260B 7/14/15 20:36 MSC P5G0244 II A-Dichlorobenzene BRL ug/L 0.50 0.050 1 *8260B 7/14/15 20:36 MSC P5G0244 2,2-Dichloropropane BRL ug/L 2.0 0.11 1 *8260B 7/14/15 20:36 MSC P5G0244 2-Chloroethyl Vinyl Ether BRL ug/L 5.0 0.37 1 *8260B 7/14/15 20:36 MSC P5G0244 2-Chlorotoluene BRL ug/L 0.50 0.066 1 *8260B 7/14/15 20:36 MSC P5G0244 4-Chlorotoluene BRL ug/L 0.50 0.050 1 *8260B 7/14/15 20:36 MSC P5G0244 4-Isopropyltoluene BRL ug/L 0.50 0.089 1 *8260B 7/14/15 20:36 MSC P5G0244 Acetone BRL ug/L 5.0 0.31 1 *8260B 7/14/15 20:36 MSC P5G0244 Acrolein BRL ug/L 20 0.20 1 *8260B 7/14/15 20:36 MSC P5G0244 Acrylonitrile BRL ug/L 20 0.20 1 *8260B 7/14/15 20:36 MSC P5G0244 Benzene BRL ug/L 0.50 0.048 1 *8260B 7/14/15 20:36 MSC P5G0244 Bromobenzene BRL ug/L 0.50 0.057 1 *8260B 7/14/15 20:36 MSC P5G0244 Bromochloromethane BRL ug/L 0.50 0.14 1 *8260B 7/14/15 20:36 MSC P5G0244 Bromodichloromethane BRL ug/L 0.50 0.062 1 *8260B 7/14/15 20:36 MSC P5G0244 Bromoform BRL ug/L 1.0 0.040 1 *8260B 7/14/15 20:36 MSC P5G0244 Bromomethane BRL ug/L 1.0 0.18 1 *8260B 7/14/15 20:36 MSC P5G0244 Carbon disulfide BRL ug/L 5.0 0.075 1 *8260B 7/14/15 20:36 MSC P5G0244 Carbon Tetrachloride BRL ug/L 0.50 0.11 1 *8260B 7/14/15 20:36 MSC P5G0244 Chlorobenzene BRL ug/L 0.50 0.062 1 *8260B 7/14/15 20:36 MSC P5G0244 Chloroethane BRL ug/L 0.50 0.22 1 *8260B 7/14/15 20:36 MSC P5G0244 Chloroform BRL ug/L 0.50 0.076 1 *8260B 7/14/15 20:36 MSC P5G0244 Chloromethane BRL ug/L 0.50 0.079 1 *8260B 7/14/15 20:36 MSC P5G0244 cis-1,2-Dichloroethylene BRL ug/L 0.50 0.056 1 *8260B 7/14/15 20:36 MSC P5G0244 cis-1,3-Dichloropropylene BRL ug/L 0.50 0.079 1 *8260B 7/14/15 20:36 MSC P5G0244 Dibromochloromethane BRL ug/L 0.50 0.081 1 *8260B 7/14/15 20:36 MSC P5G0244 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 31 of 80 P R S M Laboratory Report ` Full -Service Analytical & / Environmental Solutions 07/22/2015 LABORATORIES INC. Hart & Hickman (Charlotte) Project: PTR.001-3A Client Sample ID: TMW-4 Attn: Aaron Oswald Prism Sample ID: 5070165-07 2923 South Tryon St. Ste 100 Prism Work Order: 5070165 Charlotte, NC 28203 Sample Matrix: Water Time Collected: 07/08/15 08:55 Time Submitted: 07/10/15 08:50 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Date/Time Analyst Batch ID Dibromomethane BRL ug/L 0.50 0.065 1 *8260B 7/14/15 20:36 MSC P5G0244 Dichlorodifluoromethane BRL ug/L 1.0 0.11 1 *8260B 7/14/15 20:36 MSC P5G0244 Ethylbenzene BRL ug/L 0.50 0.061 1 *8260B 7/14/15 20:36 MSC P5G0244 Hexachlorobutadiene BRL ug/L 2.0 0.16 1 *8260B 7/14/15 20:36 MSC P5G0244 Isopropyl Ether BRL ug/L 0.50 0.050 1 *8260B 7/14/15 20:36 MSC P5G0244 Isopropylbenzene (Cumene) BRL ug/L 0.50 0.054 1 *8260B 7/14/15 20:36 MSC P5G0244 m,p-Xylenes BRL ug/L 1.0 0.12 1 *8260B 7/14/15 20:36 MSC P5G0244 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 5.0 0.065 1 *8260B 7/14/15 20:36 MSC P5G0244 Methyl Ethyl Ketone (2-Butanone) BRL ug/L 5.0 0.24 1 *8260B 7/14/15 20:36 MSC P5G0244 Methyl Isobutyl Ketone BRL ug/L 5.0 0.078 1 *8260B 7/14/15 20:36 MSC P5G0244 Methylene Chloride BRL ug/L 1.0 0.083 1 *8260B 7/14/15 20:36 MSC P5G0244 Methyl-tert-Butyl Ether BRL ug/L 0.50 0.042 1 *8260B 7/14/15 20:36 MSC P5G0244 Naphthalene BRL ug/L 1.0 0.19 1 *8260B 7/14/15 20:36 MSC P5G0244 n-Butylbenzene BRL ug/L 1.0 0.076 1 *8260B 7/14/15 20:36 MSC P5G0244 n-Propylbenzene BRL ug/L 0.50 0.087 1 *8260B 7/14/15 20:36 MSC P5G0244 o-Xylene BRL ug/L 0.50 0.044 1 *8260B 7/14/15 20:36 MSC P5G0244 sec-Butylbenzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 20:36 MSC P5G0244 Styrene BRL ug/L 0.50 0.047 1 *8260B 7/14/15 20:36 MSC P5G0244 tert-Butylbenzene BRL ug/L 0.50 0.088 1 *8260B 7/14/15 20:36 MSC P5G0244 Tetrachloroethylene 15 ug/L 0.50 0.098 1 *8260B 7/14/15 20:36 MSC P5G0244 Toluene BRL ug/L 0.50 0.044 1 *8260B 7/14/15 20:36 MSC P5G0244 trans-1,2-Dichloroethylene BRL ug/L 0.50 0.094 1 *8260B 7/14/15 20:36 MSC P5G0244 trans- 1,3-Dichloropropylene BRL ug/L 0.50 0.070 1 *8260B 7/14/15 20:36 MSC P5G0244 Trichloroethylene 1.0 ug/L 0.50 0.078 1 *8260B 7/14/15 20:36 MSC P5G0244 Trichlorofluoromethane BRL ug/L 0.50 0.062 1 *8260B 7/14/15 20:36 MSC P5G0244 Vinyl acetate BRL ug/L 2.0 0.060 1 *8260B 7/14/15 20:36 MSC P5G0244 Vinyl chloride BRL ug/L 0.50 0.097 1 *8260B 7/14/15 20:36 MSC P5G0244 Surrogate Recovery Control Limits 4-Bromofluorobenzene 92 % 80-124 Dibromofluoromethane 102 % 75-129 Toluene-d8 95 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 32 of 80 PR I S M Full -Service Analytical Environmental Solutions LABORATORIES INC. Laboratory Report 07/22/2015 Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-3A Client Sample ID: Dup-1 Prism Sample ID: 5070165-08 Prism Work Order: 5070165 Sample Matrix: Water Time Collected: 07/07/15 00:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Semivolatile Organic Compounds by GC/MS 1,2,4-Trichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 14:25 JMV P5G0184 1,2-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 14:25 JMV P5G0184 1,3-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 14:25 JMV P5G0184 1,4-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 14:25 JMV P5G0184 1-Methyl naphthalene BRL ug/L 10 2.4 1 *8270D 7/16/15 14:25 JMV P5G0184 2,4,5-Trichlorophenol BRL ug/L 10 2.3 1 *8270D 7/16/15 14:25 JMV P5G0184 2,4,6-Trichlorophenol BRL ug/L 10 2.6 1 *8270D 7/16/15 14:25 JMV P5G0184 2,4-Dichlorophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 14:25 JMV P5G0184 2,4-Dimethylphenol BRL ug/L 10 2.3 1 *8270D 7/16/15 14:25 JMV P5G0184 2,4-Dinitrophenol BRL ug/L 10 3.7 1 *8270D 7/16/15 14:25 JMV P5G0184 2,4-Dinitrotoluene BRL ug/L 10 1.9 1 *8270D 7/16/15 14:25 JMV P5G0184 2,6-Dinitrotoluene BRL ug/L 10 2.0 1 *8270D 7/16/15 14:25 JMV P5G0184 2-Chloronaphthalene BRL ug/L 10 3.4 1 *8270D 7/16/15 14:25 JMV P5G0184 2-Chlorophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 14:25 JMV P5G0184 2-Methyl naphthalene BRL ug/L 10 2.2 1 *8270D 7/16/15 14:25 JMV P5G0184 2-Methylphenol BRL ug/L 10 2.1 1 *8270D 7/16/15 14:25 JMV P5G0184 2-Nitroaniline BRL ug/L 10 2.2 1 *8270D 7/16/15 14:25 JMV P5G0184 2-Nitrophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 14:25 JMV P5G0184 3,3'-Dichlorobenzidine BRL ug/L 10 2.2 1 *8270D 7/16/15 14:25 JMV P5G0184 3/4-Methyl phenol BRL ug/L 10 1.9 1 *8270D 7/16/15 14:25 JMV P5G0184 3-Nitroaniline BRL ug/L 10 1.2 1 *8270D 7/16/15 14:25 JMV P5G0184 4,6-Dinitro-2-methylphenol BRL ug/L 10 2.4 1 *8270D 7/16/15 14:25 JMV P5G0184 4-Bromophenyl phenyl ether BRL ug/L 10 1.8 1 *8270D 7/16/15 14:25 JMV P5G0184 4-Chloro-3-methylphenol BRL ug/L 10 1.9 1 *8270D 7/16/15 14:25 JMV P5G0184 4-Chloroaniline BRL ug/L 10 1.8 1 *8270D 7/16/15 14:25 JMV P5G0184 4-Chlorophenyl phenyl ether BRL ug/L 10 2.0 1 *8270D 7/16/15 14:25 JMV P5G0184 4-Nitroaniline BRL ug/L 10 2.0 1 *8270D 7/16/15 14:25 JMV P5G0184 4-Nitrophenol BRL ug/L 10 0.66 1 *8270D 7/16/15 14:25 JMV P5G0184 Acenaphthene BRL ug/L 10 2.5 1 *8270D 7/16/15 14:25 JMV P5G0184 Acenaphthylene BRL ug/L 10 2.5 1 *8270D 7/16/15 14:25 JMV P5G0184 Aniline BRL ug/L 10 2.1 1 *8270D 7/16/15 14:25 JMV P5G0184 Anthracene BRL ug/L 10 3.0 1 *8270D 7/16/15 14:25 JMV P5G0184 Azobenzene BRL ug/L 10 1.8 1 *8270D 7/16/15 14:25 JMV P5G0184 Benzo(a)anthracene BRL ug/L 10 2.0 1 *8270D 7/16/15 14:25 JMV P5G0184 Benzo(a)pyrene BRL ug/L 10 2.4 1 *8270D 7/16/15 14:25 JMV P5G0184 Benzo(b)fluoranthene BRL ug/L 10 1.4 1 *8270D 7/16/15 14:25 JMV P5G0184 Benzo(g,h,i)perylene BRL ug/L 10 1.8 1 *8270D 7/16/15 14:25 JMV P5G0184 Benzo(k)fluoranthene BRL ug/L 10 2.4 1 *8270D 7/16/15 14:25 JMV P5G0184 Benzoic Acid BRL ug/L 100 2.7 1 *8270D 7/16/15 14:25 JMV P5G0184 Benzyl alcohol BRL ug/L 10 1.8 1 *8270D 7/16/15 14:25 JMV P5G0184 bis(2-Chloroethoxy)methane BRL ug/L 10 2.2 1 *8270D 7/16/15 14:25 JMV P5G0184 Bis(2-Chloroethyl)ether BRL ug/L 10 2.4 1 *8270D 7/16/15 14:25 JMV P5G0184 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 33 of 80 Laboratory Report ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. 07/22/2015 Hart & Hickman (Charlotte) Project: PTR.001-3A Client Sample ID: Dup-1 Attn: Aaron Oswald Prism Sample ID: 5070165-08 2923 South Tryon St. Ste 100 Prism Work Order: 5070165 Charlotte, NC 28203 Sample Matrix: Water Time Collected: 07/07/15 00:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Bis(2-chloroisopropyl)ether BRL ug/L 10 2.2 1 *8270D 7/16/15 14:25 JMV P5G0184 Bis(2-Ethylhexyl)phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 14:25 JMV P5G0184 Butyl benzyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 14:25 JMV P5G0184 Chrysene BRL ug/L 10 2.2 1 *8270D 7/16/15 14:25 JMV P5G0184 Dibenzo(a,h)anthracene BRL ug/L 10 2.0 1 *8270D 7/16/15 14:25 JMV P5G0184 Dibenzofuran BRL ug/L 10 2.3 1 *8270D 7/16/15 14:25 JMV P5G0184 Diethyl phthalate BRL ug/L 10 1.9 1 *8270D 7/16/15 14:25 JMV P5G0184 Dimethyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 14:25 JMV P5G0184 Di-n-butyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 14:25 JMV P5G0184 Di-n-octyl phthalate BRL ug/L 10 1.7 1 *8270D 7/16/15 14:25 JMV P5G0184 Fluoranthene BRL ug/L 10 2.2 1 *8270D 7/16/15 14:25 JMV P5G0184 Fluorene BRL ug/L 10 2.5 1 *8270D 7/16/15 14:25 JMV P5G0184 Hexachlorobenzene BRL ug/L 10 1.9 1 *8270D 7/16/15 14:25 JMV P5G0184 Hexachlorobutadiene BRL ug/L 10 2.6 1 *8270D 7/16/15 14:25 JMV P5G0184 Hexachlorocyclopentadiene BRL ug/L 10 2.2 1 *8270D 7/16/15 14:25 JMV P5G0184 Hexachloroethane BRL ug/L 10 2.5 1 *8270D 7/16/15 14:25 JMV P5G0184 Indeno(1,2,3-cd)pyrene BRL ug/L 10 2.1 1 *8270D 7/16/15 14:25 JMV P5G0184 Isophorone BRL ug/L 10 2.5 1 *8270D 7/16/15 14:25 JMV P5G0184 Naphthalene BRL ug/L 10 2.4 1 *8270D 7/16/15 14:25 JMV P5G0184 Nitrobenzene BRL ug/L 10 2.4 1 *8270D 7/16/15 14:25 JMV P5G0184 N-Nitroso-di-n-propylamine BRL ug/L 10 2.5 1 *8270D 7/16/15 14:25 JMV P5G0184 N-Nitrosodiphenylamine BRL ug/L 10 1.8 1 *8270D 7/16/15 14:25 JMV P5G0184 Pentachlorophenol BRL ug/L 10 2.5 1 *8270D 7/16/15 14:25 JMV P5G0184 Phenanthrene BRL ug/L 10 1.8 1 *8270D 7/16/15 14:25 JMV P5G0184 Phenol BRL ug/L 10 1.2 1 *8270D 7/16/15 14:25 JMV P5G0184 Pyrene BRL ug/L 10 2.2 1 *8270D 7/16/15 14:25 JMV P5G0184 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 123 % 49-109 SR 2-Fluorobiphenyl 120 % 55-96 SR 2-Fluorophenol 69 % 27-74 Nitrobenzene-d5 110 % 53-99 SR Phenol-d5 47 % 11-52 Terphenyl-d14 114 % 42-133 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL ug/L 0.50 0.11 1 *8260B 7/14/15 21:10 MSC P5G0244 1,1,1-Trichloroethane BRL ug/L 0.50 0.061 1 *8260B 7/14/15 21:10 MSC P5G0244 1,1,2,2-Tetrachloroethane BRL ug/L 0.50 0.036 1 *8260B 7/14/15 21:10 MSC P5G0244 1,1,2-Trichloroethane BRL ug/L 0.50 0.066 1 *8260B 7/14/15 21:10 MSC P5G0244 1,1-Dichloroethane 11 ug/L 0.50 0.083 1 *8260B 7/14/15 21:10 MSC P5G0244 1,1-Dichloroethylene 4.1 ug/L 0.50 0.083 1 *8260B 7/14/15 21:10 MSC P5G0244 1,1-Dichloropropylene BRL ug/L 0.50 0.051 1 *8260B 7/14/15 21:10 MSC P5G0244 1,2,3-Trichlorobenzene BRL ug/L 2.0 0.40 1 *8260B 7/14/15 21:10 MSC P5G0244 1,2,3-Trichloropropane BRL ug/L 1.0 0.14 1 *8260B 7/14/15 21:10 MSC P5G0244 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 34 of 80 ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-3A Sample Matrix: Water Laboratory Report 07/22/2015 Client Sample ID: Dup-1 Prism Sample ID: 5070165-08 Prism Work Order: 5070165 Time Collected: 07/07/15 00:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,2,4-Trichlorobenzene BRL ug/L 1.0 0.13 1 *8260B 7/14/15 21:10 MSC P5G0244 1,2,4-Trimethyl benzene BRL ug/L 0.50 0.054 1 *8260B 7/14/15 21:10 MSC P5G0244 1,2-Dibromo-3-chloropropane BRL ug/L 2.0 0.17 1 *8260B 7/14/15 21:10 MSC P5G0244 1,2-Dibromoethane BRL ug/L 0.50 0.051 1 *8260B 7/14/15 21:10 MSC P5G0244 1,2-Dichlorobenzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 21:10 MSC P5G0244 1,2-Dichloroethane BRL ug/L 0.50 0.066 1 *8260B 7/14/15 21:10 MSC P5G0244 1,2-Dichloropropane BRL ug/L 0.50 0.11 1 *8260B 7/14/15 21:10 MSC P5G0244 1,3,5-Trimethyl benzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 21:10 MSC P5G0244 1,3-Dichlorobenzene BRL ug/L 0.50 0.054 1 *8260B 7/14/15 21:10 MSC P5G0244 1,3-Dichloropropane BRL ug/L 0.50 0.043 1 *8260B 7/14/15 21:10 MSC P5G0244 1,4-Dichlorobenzene BRL ug/L 0.50 0.050 1 *8260B 7/14/15 21:10 MSC P5G0244 2,2-Dichloropropane BRL ug/L 2.0 0.11 1 *8260B 7/14/15 21:10 MSC P5G0244 2-Chloroethyl Vinyl Ether BRL ug/L 5.0 0.37 1 *8260B 7/14/15 21:10 MSC P5G0244 2-Chlorotoluene BRL ug/L 0.50 0.066 1 *8260B 7/14/15 21:10 MSC P5G0244 4-Chlorotoluene BRL ug/L 0.50 0.050 1 *8260B 7/14/15 21:10 MSC P5G0244 4-Isopropyltoluene BRL ug/L 0.50 0.089 1 *8260B 7/14/15 21:10 MSC P5G0244 Acetone BRL ug/L 5.0 0.31 1 *8260B 7/14/15 21:10 MSC P5G0244 Acrolein BRL ug/L 20 0.20 1 *8260B 7/14/15 21:10 MSC P5G0244 Acrylonitrile BRL ug/L 20 0.20 1 *8260B 7/14/15 21:10 MSC P5G0244 Benzene BRL ug/L 0.50 0.048 1 *8260B 7/14/15 21:10 MSC P5G0244 Bromobenzene BRL ug/L 0.50 0.057 1 *8260B 7/14/15 21:10 MSC P5G0244 Bromochloromethane BRL ug/L 0.50 0.14 1 *8260B 7/14/15 21:10 MSC P5G0244 Bromodichloromethane BRL ug/L 0.50 0.062 1 *8260B 7/14/15 21:10 MSC P5G0244 Bromoform BRL ug/L 1.0 0.040 1 *8260B 7/14/15 21:10 MSC P5G0244 Bromomethane BRL ug/L 1.0 0.18 1 *8260B 7/14/15 21:10 MSC P5G0244 Carbon disulfide BRL ug/L 5.0 0.075 1 *8260B 7/14/15 21:10 MSC P5G0244 Carbon Tetrachloride BRL ug/L 0.50 0.11 1 *8260B 7/14/15 21:10 MSC P5G0244 Chlorobenzene BRL ug/L 0.50 0.062 1 *8260B 7/14/15 21:10 MSC P5G0244 Chloroethane BRL ug/L 0.50 0.22 1 *8260B 7/14/15 21:10 MSC P5G0244 Chloroform 0.75 ug/L 0.50 0.076 1 *8260B 7/14/15 21:10 MSC P5G0244 Chloromethane BRL ug/L 0.50 0.079 1 *8260B 7/14/15 21:10 MSC P5G0244 cis-1,2-Dichloroethylene 1.6 ug/L 0.50 0.056 1 *8260B 7/14/15 21:10 MSC P5G0244 cis-1,3-Dichloropropylene BRL ug/L 0.50 0.079 1 *8260B 7/14/15 21:10 MSC P5G0244 Dibromochloromethane BRL ug/L 0.50 0.081 1 *8260B 7/14/15 21:10 MSC P5G0244 Dibromomethane BRL ug/L 0.50 0.065 1 *8260B 7/14/15 21:10 MSC P5G0244 Dichlorodifluoromethane BRL ug/L 1.0 0.11 1 *8260B 7/14/15 21:10 MSC P5G0244 Ethylbenzene BRL ug/L 0.50 0.061 1 *8260B 7/14/15 21:10 MSC P5G0244 Hexachlorobutadiene BRL ug/L 2.0 0.16 1 *8260B 7/14/15 21:10 MSC P5G0244 Isopropyl Ether 0.77 ug/L 0.50 0.050 1 *8260B 7/14/15 21:10 MSC P5G0244 Isopropylbenzene (Cumene) BRL ug/L 0.50 0.054 1 *8260B 7/14/15 21:10 MSC P5G0244 m,p-Xylenes BRL ug/L 1.0 0.12 1 *8260B 7/14/15 21:10 MSC P5G0244 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 5.0 0.065 1 *8260B 7/14/15 21:10 MSC P5G0244 Methyl Ethyl Ketone (2-Butanone) BRL ug/L 5.0 0.24 1 *8260B 7/14/15 21:10 MSC P5G0244 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 35 of 80 Laboratory Report ` Full -Service P R S M Analytical & / Environmental Solutions LABORATORIES INC. 07/22/2015 Hart & Hickman (Charlotte) Project: PTR.001-3A Client Sample ID: Dup-1 Attn: Aaron Oswald Prism Sample ID: 5070165-08 2923 South Tryon St. Ste 100 Prism Work Order: 5070165 Charlotte, NC 28203 Sample Matrix: Water Time Collected: 07/07/15 00:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Methyl Isobutyl Ketone BRL ug/L 5.0 0.078 1 *8260B 7/14/15 21:10 MSC P5G0244 Methylene Chloride BRL ug/L 1.0 0.083 1 *8260B 7/14/15 21:10 MSC P5G0244 Methyl-tert-Butyl Ether BRL ug/L 0.50 0.042 1 *8260B 7/14/15 21:10 MSC P5G0244 Naphthalene BRL ug/L 1.0 0.19 1 *8260B 7/14/15 21:10 MSC P5G0244 n-Butylbenzene BRL ug/L 1.0 0.076 1 *8260B 7/14/15 21:10 MSC P5G0244 n-Propylbenzene BRL ug/L 0.50 0.087 1 *8260B 7/14/15 21:10 MSC P5G0244 o-Xylene BRL ug/L 0.50 0.044 1 *8260B 7/14/15 21:10 MSC P5G0244 sec-Butylbenzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 21:10 MSC P5G0244 Styrene BRL ug/L 0.50 0.047 1 *8260B 7/14/15 21:10 MSC P5G0244 tert-Butylbenzene BRL ug/L 0.50 0.088 1 *8260B 7/14/15 21:10 MSC P5G0244 Tetrachloroethylene 260 H1 ug/L 5.0 0.98 10 *8260B 7/21/15 16:04 MSC P5G0244 Toluene BRL ug/L 0.50 0.044 1 *8260B 7/14/15 21:10 MSC P5G0244 trans-1,2-Dichloroethylene BRL ug/L 0.50 0.094 1 *8260B 7/14/15 21:10 MSC P5G0244 trans-1,3-Dichloropropylene BRL ug/L 0.50 0.070 1 *8260B 7/14/15 21:10 MSC P5G0244 Trichloroethylene 3.3 ug/L 0.50 0.078 1 *8260B 7/14/15 21:10 MSC P5G0244 Trichlorofluoromethane BRL ug/L 0.50 0.062 1 *8260B 7/14/15 21:10 MSC P5G0244 Vinyl acetate BRL ug/L 2.0 0.060 1 *8260B 7/14/15 21:10 MSC P5G0244 Vinyl chloride BRL ug/L 0.50 0.097 1 *8260B 7/14/15 21:10 MSC P5G0244 Surrogate Recovery Control Limits 4-Bromofluorobenzene 91 % 80-124 Dibromofluoromethane 97 % 75-129 Toluene-d8 94 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 36 of 80 PR I S M Full -Service Analytical Environmental Solutions LABORATORIES INC. Laboratory Report 07/22/2015 Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-3A Client Sample ID: Trip Blank Prism Sample ID: 5070165-09 Prism Work Order: 5070165 Sample Matrix: Water Time Collected: 07/09/15 00:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL ug/L 0.50 0.11 1 *8260B 7/14/15 17:10 MSC P5G0244 1,1,1-Trichloroethane BRL ug/L 0.50 0.061 1 *8260B 7/14/15 17:10 MSC P5G0244 1,1,2,2-Tetrachloroethane BRL ug/L 0.50 0.036 1 *8260B 7/14/15 17:10 MSC P5G0244 1,1,2-Trichloroethane BRL ug/L 0.50 0.066 1 *8260B 7/14/15 17:10 MSC P5G0244 1,1-Dichloroethane BRL ug/L 0.50 0.083 1 *8260B 7/14/15 17:10 MSC P5G0244 1,1-Dichloroethylene BRL ug/L 0.50 0.083 1 *8260B 7/14/15 17:10 MSC P5G0244 1,1-Dichloropropylene BRL ug/L 0.50 0.051 1 *8260B 7/14/15 17:10 MSC P5G0244 1,2,3-Trichlorobenzene BRL ug/L 2.0 0.40 1 *8260B 7/14/15 17:10 MSC P5G0244 1,2,3-Trichloropropane BRL ug/L 1.0 0.14 1 *8260B 7/14/15 17:10 MSC P5G0244 1,2,4-Trichlorobenzene BRL ug/L 1.0 0.13 1 *8260B 7/14/15 17:10 MSC P5G0244 1,2,4-Trimethyl benzene BRL ug/L 0.50 0.054 1 *8260B 7/14/15 17:10 MSC P5G0244 1,2-Dibromo-3-chloropropane BRL ug/L 2.0 0.17 1 *8260B 7/14/15 17:10 MSC P5G0244 1,2-Dibromoethane BRL ug/L 0.50 0.051 1 *8260B 7/14/15 17:10 MSC P5G0244 1,2-Dichlorobenzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 17:10 MSC P5G0244 1,2-Dichloroethane BRL ug/L 0.50 0.066 1 *8260B 7/14/15 17:10 MSC P5G0244 1,2-Dichloropropane BRL ug/L 0.50 0.11 1 *8260B 7/14/15 17:10 MSC P5G0244 1,3,5-Trimethyl benzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 17:10 MSC P5G0244 1,3-Dichlorobenzene BRL ug/L 0.50 0.054 1 *8260B 7/14/15 17:10 MSC P5G0244 1,3-Dichloropropane BRL ug/L 0.50 0.043 1 *8260B 7/14/15 17:10 MSC P5G0244 1,4-Dichlorobenzene BRL ug/L 0.50 0.050 1 *8260B 7/14/15 17:10 MSC P5G0244 2,2-Dichloropropane BRL ug/L 2.0 0.11 1 *8260B 7/14/15 17:10 MSC P5G0244 2-Chloroethyl Vinyl Ether BRL ug/L 5.0 0.37 1 *8260B 7/14/15 17:10 MSC P5G0244 2-Chlorotoluene BRL ug/L 0.50 0.066 1 *8260B 7/14/15 17:10 MSC P5G0244 4-Chlorotoluene BRL ug/L 0.50 0.050 1 *8260B 7/14/15 17:10 MSC P5G0244 4-Isopropyltoluene BRL ug/L 0.50 0.089 1 *8260B 7/14/15 17:10 MSC P5G0244 Acetone BRL ug/L 5.0 0.31 1 *8260B 7/14/15 17:10 MSC P5G0244 Acrolein BRL ug/L 20 0.20 1 *8260B 7/14/15 17:10 MSC P5G0244 Acrylonitrile BRL ug/L 20 0.20 1 *8260B 7/14/15 17:10 MSC P5G0244 Benzene BRL ug/L 0.50 0.048 1 *8260B 7/14/15 17:10 MSC P5G0244 Bromobenzene BRL ug/L 0.50 0.057 1 *8260B 7/14/15 17:10 MSC P5G0244 Bromochloromethane BRL ug/L 0.50 0.14 1 *8260B 7/14/15 17:10 MSC P5G0244 Bromodichloromethane BRL ug/L 0.50 0.062 1 *8260B 7/14/15 17:10 MSC P5G0244 Bromoform BRL ug/L 1.0 0.040 1 *8260B 7/14/15 17:10 MSC P5G0244 Bromomethane BRL ug/L 1.0 0.18 1 *8260B 7/14/15 17:10 MSC P5G0244 Carbon disulfide BRL ug/L 5.0 0.075 1 *8260B 7/14/15 17:10 MSC P5G0244 Carbon Tetrachloride BRL ug/L 0.50 0.11 1 *8260B 7/14/15 17:10 MSC P5G0244 Chlorobenzene BRL ug/L 0.50 0.062 1 *8260B 7/14/15 17:10 MSC P5G0244 Chloroethane BRL ug/L 0.50 0.22 1 *8260B 7/14/15 17:10 MSC P5G0244 Chloroform BRL ug/L 0.50 0.076 1 *8260B 7/14/15 17:10 MSC P5G0244 Chloromethane BRL ug/L 0.50 0.079 1 *8260B 7/14/15 17:10 MSC P5G0244 cis-1,2-Dichloroethylene BRL ug/L 0.50 0.056 1 *8260B 7/14/15 17:10 MSC P5G0244 cis-1,3-Dichloropropylene BRL ug/L 0.50 0.079 1 *8260B 7/14/15 17:10 MSC P5G0244 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 37 of 80 P R S M Laboratory Report ` Full -Service Analytical & / Environmental Solutions 07/22/2015 LABORATORIES INC. Hart & Hickman (Charlotte) Project: PTR.001-3A Client Sample ID: Trip Blank Attn: Aaron Oswald Prism Sample ID: 5070165-09 2923 South Tryon St. Ste 100 Prism Work Order: 5070165 Charlotte, NC 28203 Sample Matrix: Water Time Collected: 07/09/15 00:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Date/Time Analyst Batch ID Dibromochloromethane BRL ug/L 0.50 0.081 1 *8260B 7/14/15 17:10 MSC P5G0244 Dibromomethane BRL ug/L 0.50 0.065 1 *8260B 7/14/15 17:10 MSC P5G0244 Dichlorodifluoromethane BRL ug/L 1.0 0.11 1 *8260B 7/14/15 17:10 MSC P5G0244 Ethylbenzene BRL ug/L 0.50 0.061 1 *8260B 7/14/15 17:10 MSC P5G0244 Hexachlorobutadiene BRL ug/L 2.0 0.16 1 *8260B 7/14/15 17:10 MSC P5G0244 Isopropyl Ether BRL ug/L 0.50 0.050 1 *8260B 7/14/15 17:10 MSC P5G0244 Isopropylbenzene (Cumene) BRL ug/L 0.50 0.054 1 *8260B 7/14/15 17:10 MSC P5G0244 m,p-Xylenes BRL ug/L 1.0 0.12 1 *8260B 7/14/15 17:10 MSC P5G0244 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 5.0 0.065 1 *8260B 7/14/15 17:10 MSC P5G0244 Methyl Ethyl Ketone (2-Butanone) BRL ug/L 5.0 0.24 1 *8260B 7/14/15 17:10 MSC P5G0244 Methyl Isobutyl Ketone BRL ug/L 5.0 0.078 1 *8260B 7/14/15 17:10 MSC P5G0244 Methylene Chloride BRL ug/L 1.0 0.083 1 *8260B 7/14/15 17:10 MSC P5G0244 Methyl-tert-Butyl Ether BRL ug/L 0.50 0.042 1 *8260B 7/14/15 17:10 MSC P5G0244 Naphthalene BRL ug/L 1.0 0.19 1 *8260B 7/14/15 17:10 MSC P5G0244 n-Butylbenzene BRL ug/L 1.0 0.076 1 *8260B 7/14/15 17:10 MSC P5G0244 n-Propylbenzene BRL ug/L 0.50 0.087 1 *8260B 7/14/15 17:10 MSC P5G0244 o-Xylene BRL ug/L 0.50 0.044 1 *8260B 7/14/15 17:10 MSC P5G0244 sec-Butylbenzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 17:10 MSC P5G0244 Styrene BRL ug/L 0.50 0.047 1 *8260B 7/14/15 17:10 MSC P5G0244 tert-Butylbenzene BRL ug/L 0.50 0.088 1 *8260B 7/14/15 17:10 MSC P5G0244 Tetrachloroethylene BRL ug/L 0.50 0.098 1 *8260B 7/14/15 17:10 MSC P5G0244 Toluene BRL ug/L 0.50 0.044 1 *8260B 7/14/15 17:10 MSC P5G0244 trans-1,2-Dichloroethylene BRL ug/L 0.50 0.094 1 *8260B 7/14/15 17:10 MSC P5G0244 trans-1,3-Dichloropropylene BRL ug/L 0.50 0.070 1 *8260B 7/14/15 17:10 MSC P5G0244 Trichloroethylene BRL ug/L 0.50 0.078 1 *8260B 7/14/15 17:10 MSC P5G0244 Trichlorofluoromethane BRL ug/L 0.50 0.062 1 *8260B 7/14/15 17:10 MSC P5G0244 Vinyl acetate BRL ug/L 2.0 0.060 1 *8260B 7/14/15 17:10 MSC P5G0244 Vinyl chloride BRL ug/L 0.50 0.097 1 *8260B 7/14/15 17:10 MSC P5G0244 Surrogate Recovery Control Limits 4-Bromofluorobenzene 93 % 80-124 Dibromofluoromethane 103 % 75-129 Toluene-d8 95 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 38 of 80 /r E P R I IS M Service Analytical Environmental Solutions LABORATORIES, INC. Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5G0244 - 5030B Blank (P5G0244-BLK1) Prepared & Analyzed: 07/14/15 1,1,1,2-Tetrachloroethane BRL 0.50 ug/L 1,1,1-Trichloroethane BRL 0.50 ug/L 1,1,2,2-Tetrachloroethane BRL 0.50 ug/L 1,1,2-Trichloroethane BRL 0.50 ug/L 1,1-Dichloroethane BRL 0.50 ug/L 1,1-Dichloroethylene BRL 0.50 ug/L 1,1-Dichloropropylene BRL 0.50 ug/L 1,2,3-Trichlorobenzene BRL 2.0 ug/L 1,2,3-Trichloropropane BRL 1.0 ug/L 1,2,4-Trichlorobenzene BRL 1.0 ug/L 1,2,4-Trimethyl benzene BRL 0.50 ug/L 1,2-Dibromo-3-chloropropane BRL 2.0 ug/L 1,2-Dibromoethane BRL 0.50 ug/L 1,2-Dichlorobenzene BRL 0.50 ug/L 1,2-Dichloroethane BRL 0.50 ug/L 1,2-Dichloropropane BRL 0.50 ug/L 1,3,5-Trimethyl benzene BRL 0.50 ug/L 1,3-Dichlorobenzene BRL 0.50 ug/L 1,3-Dichloropropane BRL 0.50 ug/L 1,4-Dichlorobenzene BRL 0.50 ug/L 2,2-Dichloropropane BRL 2.0 ug/L 2-Chloroethyl Vinyl Ether BRL 5.0 ug/L 2-Chlorotoluene BRL 0.50 ug/L 4-Chlorotoluene BRL 0.50 ug/L 4-Isopropyltoluene BRL 0.50 ug/L Acetone BRL 5.0 ug/L Acrolein BRL 20 ug/L Acrylonitrile BRL 20 ug/L Benzene BRL 0.50 ug/L Bromobenzene BRL 0.50 ug/L Bromochloromethane BRL 0.50 ug/L Bromodichloromethane BRL 0.50 ug/L Bromoform BRL 1.0 ug/L Bromomethane BRL 1.0 ug/L Carbon disulfide BRL 5.0 ug/L Carbon Tetrachloride BRL 0.50 ug/L Chlorobenzene BRL 0.50 ug/L Chloroethane BRL 0.50 ug/L Chloroform BRL 0.50 ug/L Chloromethane BRL 0.50 ug/L cis-1,2-Dichloroethylene BRL 0.50 ug/L cis-1,3-Dichloropropylene BRL 0.50 ug/L Dibromochloromethane BRL 0.50 ug/L Dibromomethane BRL 0.50 ug/L Dichlorodifluoromethane BRL 1.0 ug/L Ethylbenzene BRL 0.50 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 39 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 7/22/15 Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO244 - 5030B Blank (P5G0244-BLK1) Prepared & Analyzed: 07/14/15 Hexachlorobutadiene BRL 2.0 ug/L Isopropyl Ether BRL 0.50 ug/L Isopropylbenzene (Cumene) BRL 0.50 ug/L m,p-Xylenes BRL 1.0 ug/L Methyl Butyl Ketone (2-Hexanone) BRL 5.0 ug/L Methyl Ethyl Ketone (2-Butanone) BRL 5.0 ug/L Methyl Isobutyl Ketone BRL 5.0 ug/L Methylene Chloride BRL 1.0 ug/L Methyl-tert-Butyl Ether BRL 0.50 ug/L Naphthalene BRL 1.0 ug/L n-Butylbenzene BRL 1.0 ug/L n-Propylbenzene BRL 0.50 ug/L o-Xylene BRL 0.50 ug/L sec-Butylbenzene BRL 0.50 ug/L Styrene BRL 0.50 ug/L tert-Butylbenzene BRL 0.50 ug/L Tetrachloroethylene BRL 0.50 ug/L Toluene BRL 0.50 ug/L trans-1,2-Dichloroethylene BRL 0.50 ug/L trans-1,3-Dichloropropylene BRL 0.50 ug/L Trichloroethylene BRL 0.50 ug/L Trichlorofluoromethane BRL 0.50 ug/L Vinyl acetate BRL 2.0 ug/L Vinyl chloride BRL 0.50 ug/L Surrogate:4-Bromofluorobenzene 23.2 ug/L 25.00 93 80-124 Surrogate: Dibromofluoromethane 26.0 ug/L 25.00 104 75-129 Surrogate: Toluene-d8 23.8 ug/L 25.00 95 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 40 of 80 P R I IS M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Prism Work Order: 5070165 Attn: Aaron Oswald Time Submitted: 7/10/2015 8:50:OOAM 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO244 - 5030B LCS (P51130244-113SI) Prepared & Analyzed: 07/14/15 1,1,1,2-Tetrachloroethane 19.9 0.50 ug/L 20.00 100 79-134 1,1,1-Trichloroethane 19.1 0.50 ug/L 20.00 96 75-136 1,1,2,2-Tetrachloroethane 17.6 0.50 ug/L 20.00 88 62-127 1,1,2-Trichloroethane 19.8 0.50 ug/L 20.00 99 70-140 1,1-Dichloroethane 19.0 0.50 ug/L 20.00 95 78-130 1,1-Dichloroethylene 21.3 0.50 ug/L 20.00 106 70-154 1, 1 -Dichloropropylene 23.4 0.50 ug/L 20.00 117 71-136 1,2,3-Trichlorobenzene 21.4 2.0 ug/L 20.00 107 58-144 1,2,3-Trichloropropane 17.8 1.0 ug/L 20.00 89 71-127 1,2,4-Trichlorobenzene 21.2 1.0 ug/L 20.00 106 66-139 1,2,4-Trimethylbenzene 19.4 0.50 ug/L 20.00 97 75-133 1,2-Dibromo-3-chloropropane 15.1 2.0 ug/L 20.00 76 63-134 1,2-Dibromoethane 20.2 0.50 ug/L 20.00 101 77-135 1,2-Dichlorobenzene 21.2 0.50 ug/L 20.00 106 78-128 1,2-Dichloroethane 18.9 0.50 ug/L 20.00 95 68-131 1,2-Dichloropropane 20.1 0.50 ug/L 20.00 101 77-130 1,3,5-Trimethylbenzene 19.4 0.50 ug/L 20.00 97 75-131 1,3-Dichlorobenzene 21.3 0.50 ug/L 20.00 107 77-125 1,3-Dichloropropane 19.2 0.50 ug/L 20.00 96 76-132 1,4-Dichlorobenzene 20.8 0.50 ug/L 20.00 104 75-126 2,2-Dichloropropane 18.9 2.0 ug/L 20.00 94 29-149 2-Chloroethyl Vinyl Ether 9.38 5.0 ug/L 20.00 47 34-144 2-Chlorotoluene 20.0 0.50 ug/L 20.00 100 74-126 4-Chlorotoluene 20.0 0.50 ug/L 20.00 100 78-129 4-Isopropyltoluene 21.2 0.50 ug/L 20.00 106 69-132 Acetone 36.5 5.0 ug/L 40.00 91 40-166 Acrolein 36.8 20 ug/L 40.00 92 70-130 Acrylonitrile 40.0 20 ug/L 40.00 100 81-127 Benzene 22.1 0.50 ug/L 20.00 111 77-128 Bromobenzene 18.6 0.50 ug/L 20.00 93 78-129 Bromochloromethane 19.4 0.50 ug/L 20.00 97 78-135 Bromodichloromethane 17.8 0.50 ug/L 20.00 89 76-138 Bromoform 18.2 1.0 ug/L 20.00 91 71-135 Bromomethane 17.1 1.0 ug/L 20.00 86 41-168 Carbon disulfide 23.6 5.0 ug/L 20.00 118 59-135 Carbon Tetrachloride 22.0 0.50 ug/L 20.00 110 72-142 Chlorobenzene 20.8 0.50 ug/L 20.00 104 78-119 Chloroethane 21.8 0.50 ug/L 20.00 109 57-142 Chloroform 18.0 0.50 ug/L 20.00 90 77-130 Chloromethane 18.5 0.50 ug/L 20.00 92 47-145 cis-1,2-Dichloroethylene 19.6 0.50 ug/L 20.00 98 76-141 cis-1,3-Dichloropropylene 18.8 0.50 ug/L 20.00 94 65-140 Dibromochloromethane 17.2 0.50 ug/L 20.00 86 75-134 Dibromomethane 20.8 0.50 ug/L 20.00 104 76-138 Dichlorodifluoromethane 19.8 1.0 ug/L 20.00 99 28-163 Ethylbenzene 21.1 0.50 ug/L 20.00 105 80-127 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 41 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO244 - 5030B LCS (P5G0244-BS1) Prepared & Analyzed: 07/14/15 Hexachlorobutadiene 22.8 2.0 ug/L 20.00 114 61-134 Isopropyl Ether 17.5 0.50 ug/L 20.00 87 60-154 Isopropylbenzene (Cumene) 22.5 0.50 ug/L 20.00 113 70-130 m,p-Xylenes 42.5 1.0 ug/L 40.00 106 77-133 Methyl Butyl Ketone (2-Hexanone) 13.3 5.0 ug/L 20.00 67 64-137 Methyl Ethyl Ketone (2-Butanone) 16.4 5.0 ug/L 20.00 82 71-134 Methyl Isobutyl Ketone 14.1 5.0 ug/L 20.00 70 69-134 Methylene Chloride 19.7 1.0 ug/L 20.00 98 73-131 Methyl-tert-Butyl Ether 18.2 0.50 ug/L 20.00 91 68-135 Naphthalene 18.0 1.0 ug/L 20.00 90 64-136 n-Butylbenzene 19.7 1.0 ug/L 20.00 98 68-134 n-Propylbenzene 21.5 0.50 ug/L 20.00 107 72-132 o-Xylene 20.5 0.50 ug/L 20.00 102 78-128 sec-Butylbenzene 22.6 0.50 ug/L 20.00 113 71-131 Styrene 20.9 0.50 ug/L 20.00 104 78-129 tert-Butylbenzene 21.0 0.50 ug/L 20.00 105 70-132 Tetrachloroethylene 22.5 0.50 ug/L 20.00 112 80-129 Toluene 21.8 0.50 ug/L 20.00 109 76-131 trans-1,2-Dichloroethylene 20.1 0.50 ug/L 20.00 101 76-135 trans-1,3-Dichloropropylene 18.6 0.50 ug/L 20.00 93 67-140 Trichloroethylene 22.8 0.50 ug/L 20.00 114 77-133 Trichlorofluoromethane 25.1 0.50 ug/L 20.00 126 62-148 Vinyl acetate 19.6 2.0 ug/L 20.00 98 34-167 Vinyl chloride 20.8 0.50 ug/L 20.00 104 57-141 Surrogate:4-Bromofluorobenzene 22.2 ug/L 25.00 89 80-124 Surrogate: Dibromofluoromethane 25.2 ug/L 25.00 101 75-129 Surrogate: Toluene-d8 24.0 ug/L 25.00 96 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 42 of 80 P R I IS M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO244 - 5030B Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS Dup (P5G0244-BSD1) Prepared & Analyzed: 07/14/15 1,1,1,2-Tetrachloroethane 19.1 0.50 ug/L 20.00 95 79-134 4 20 1,1,1-Trichloroethane 17.8 0.50 ug/L 20.00 89 75-136 7 20 1,1,2,2-Tetrachloroethane 16.8 0.50 ug/L 20.00 84 62-127 5 20 1,1,2-Trichloroethane 18.4 0.50 ug/L 20.00 92 70-140 7 20 1,1-Dichloroethane 18.0 0.50 ug/L 20.00 90 78-130 6 20 1,1-Dichloroethylene 19.9 0.50 ug/L 20.00 99 70-154 7 20 1, 1 -Dichloropropylene 21.1 0.50 ug/L 20.00 105 71-136 10 20 1,2,3-Trichlorobenzene 21.1 2.0 ug/L 20.00 105 58-144 1 20 1,2,3-Trichloropropane 17.6 1.0 ug/L 20.00 88 71-127 1 20 1,2,4-Trichlorobenzene 20.8 1.0 ug/L 20.00 104 66-139 2 20 1,2,4-Trimethylbenzene 18.5 0.50 ug/L 20.00 93 75-133 5 20 1,2-Dibromo-3-chloropropane 17.2 2.0 ug/L 20.00 86 63-134 13 20 1,2-Dibromoethane 19.9 0.50 ug/L 20.00 100 77-135 2 20 1,2-Dichlorobenzene 20.7 0.50 ug/L 20.00 103 78-128 3 20 1,2-Dichloroethane 18.2 0.50 ug/L 20.00 91 68-131 4 20 1,2-Dichloropropane 19.5 0.50 ug/L 20.00 98 77-130 3 20 1,3,5-Trimethylbenzene 18.5 0.50 ug/L 20.00 92 75-131 5 20 1,3-Dichlorobenzene 20.8 0.50 ug/L 20.00 104 77-125 3 20 1,3-Dichloropropane 19.5 0.50 ug/L 20.00 98 76-132 2 20 1,4-Dichlorobenzene 20.1 0.50 ug/L 20.00 100 75-126 3 20 2,2-Dichloropropane 17.7 2.0 ug/L 20.00 88 29-149 7 20 2-Chloroethyl Vinyl Ether 8.81 5.0 ug/L 20.00 44 34-144 6 20 2-Chlorotoluene 19.2 0.50 ug/L 20.00 96 74-126 4 20 4-Chlorotoluene 19.2 0.50 ug/L 20.00 96 78-129 4 20 4-Isopropyltoluene 19.9 0.50 ug/L 20.00 100 69-132 6 20 Acetone 38.3 5.0 ug/L 40.00 96 40-166 5 20 Acrolein 37.3 20 ug/L 40.00 93 70-130 1 20 Acrylonitrile 38.7 20 ug/L 40.00 97 81-127 3 20 Benzene 20.8 0.50 ug/L 20.00 104 77-128 6 20 Bromobenzene 17.7 0.50 ug/L 20.00 88 78-129 5 20 Bromochloromethane 18.7 0.50 ug/L 20.00 93 78-135 4 20 Bromodichloromethane 17.4 0.50 ug/L 20.00 87 76-138 2 20 Bromoform 17.7 1.0 ug/L 20.00 89 71-135 3 20 Bromomethane 16.5 1.0 ug/L 20.00 83 41-168 4 20 Carbon disulfide 22.7 5.0 ug/L 20.00 113 59-135 4 20 Carbon Tetrachloride 20.5 0.50 ug/L 20.00 103 72-142 7 20 Chlorobenzene 20.5 0.50 ug/L 20.00 103 78-119 1 20 Chloroethane 20.1 0.50 ug/L 20.00 100 57-142 8 20 Chloroform 17.3 0.50 ug/L 20.00 86 77-130 4 20 Chloromethane 16.7 0.50 ug/L 20.00 84 47-145 10 20 cis-1,2-Dichloroethylene 18.5 0.50 ug/L 20.00 92 76-141 6 20 cis-1,3-Dichloropropylene 18.1 0.50 ug/L 20.00 90 65-140 4 20 Dibromochloromethane 17.3 0.50 ug/L 20.00 86 75-134 0.3 20 Dibromomethane 20.1 0.50 ug/L 20.00 101 76-138 3 20 Dichlorodifluoromethane 17.9 1.0 ug/L 20.00 90 28-163 10 20 Ethylbenzene 20.3 0.50 ug/L 20.00 101 80-127 4 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 43 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 7/22/15 Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO244 - 5030B LCS Dup (P5G0244-BSD1) Prepared & Analyzed: 07/14/15 Hexachlorobutadiene 21.9 2.0 ug/L 20.00 109 61-134 4 20 Isopropyl Ether 16.9 0.50 ug/L 20.00 85 60-154 3 20 Isopropylbenzene (Cumene) 21.2 0.50 ug/L 20.00 106 70-130 6 20 m,p-Xylenes 41.0 1.0 ug/L 40.00 103 77-133 4 20 Methyl Butyl Ketone (2-Hexanone) 14.0 5.0 ug/L 20.00 70 64-137 5 20 Methyl Ethyl Ketone (2-Butanone) 15.3 5.0 ug/L 20.00 76 71-134 7 20 Methyl Isobutyl Ketone 14.1 5.0 ug/L 20.00 71 69-134 0.4 20 Methylene Chloride 19.2 1.0 ug/L 20.00 96 73-131 3 20 Methyl-tert-Butyl Ether 17.8 0.50 ug/L 20.00 89 68-135 2 20 Naphthalene 17.2 1.0 ug/L 20.00 86 64-136 5 20 n-Butylbenzene 18.4 1.0 ug/L 20.00 92 68-134 7 20 n-Propylbenzene 20.5 0.50 ug/L 20.00 102 72-132 5 20 o-Xylene 20.1 0.50 ug/L 20.00 100 78-128 2 20 sec-Butylbenzene 21.1 0.50 ug/L 20.00 106 71-131 7 20 Styrene 19.9 0.50 ug/L 20.00 100 78-129 5 20 tert-Butylbenzene 19.8 0.50 ug/L 20.00 99 70-132 6 20 Tetrachloroethylene 20.9 0.50 ug/L 20.00 104 80-129 7 20 Toluene 20.6 0.50 ug/L 20.00 103 76-131 5 20 trans-1,2-Dichloroethylene 18.7 0.50 ug/L 20.00 93 76-135 7 20 trans-1,3-Dichloropropylene 17.7 0.50 ug/L 20.00 88 67-140 5 20 Trichloroethylene 21.2 0.50 ug/L 20.00 106 77-133 7 20 Trichlorofluoromethane 23.3 0.50 ug/L 20.00 116 62-148 7 20 Vinyl acetate 19.2 2.0 ug/L 20.00 96 34-167 2 20 Vinyl chloride 18.9 0.50 ug/L 20.00 95 57-141 9 20 Surrogate:4-Bromofluorobenzene 22.3 ug/L 25.00 89 80-124 Surrogate: Dibromofluoromethane 25.0 ug/L 25.00 100 75-129 Surrogate: Toluene-d8 23.9 ug/L 25.00 96 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 44 of 80 P R I IS M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Analyte Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Batch P5GO244 - 5030B Matrix Spike (P5G0244-MS1) Source: 5070165-04 Prepared: 07/14/15 Analyzed: 07/15/15 1,1,1,2-Tetrachloroethane 24.0 0.50 ug/L 20.00 BRL 120 78-134 1,1,1-Trichloroethane 26.6 0.50 ug/L 20.00 BRL 133 67-145 1,1,2,2-Tetrachloroethane 19.6 0.50 ug/L 20.00 BRL 98 68-123 1,1,2-Trichloroethane 26.8 0.50 ug/L 20.00 BRL 134 75-134 1,1-Dichloroethane 27.8 0.50 ug/L 20.00 11.5 82 75-134 1,1-Dichloroethylene 30.8 0.50 ug/L 20.00 4.05 134 65-162 1, 1 -Dichloropropylene 32.2 0.50 ug/L 20.00 BRL 161 68-140 MI 1,2,3-Trichlorobenzene 24.0 2.0 ug/L 20.00 BRL 120 56-146 1,2,3-Trichloropropane 21.6 1.0 ug/L 20.00 BRL 108 73-122 1,2,4-Trichlorobenzene 23.2 1.0 ug/L 20.00 BRL 116 67-135 1,2,4-Trimethylbenzene 21.6 0.50 ug/L 20.00 BRL 108 75-131 1,2-Dibromo-3-chloropropane 18.2 2.0 ug/L 20.00 BRL 91 64-133 1,2-Dibromoethane 25.7 0.50 ug/L 20.00 BRL 129 80-129 1,2-Dichlorobenzene 24.5 0.50 ug/L 20.00 BRL 123 80-125 1,2-Dichloroethane 26.7 0.50 ug/L 20.00 BRL 134 69-129 MI 1,2-Dichloropropane 27.3 0.50 ug/L 20.00 BRL 137 75-131 MI 1,3,5-Trimethylbenzene 22.1 0.50 ug/L 20.00 BRL 110 75-131 1,3-Dichlorobenzene 24.1 0.50 ug/L 20.00 BRL 120 79-122 1,3-Dichloropropane 26.0 0.50 ug/L 20.00 BRL 130 80-125 MI 1,4-Dichlorobenzene 23.4 0.50 ug/L 20.00 BRL 117 76-124 2,2-Dichloropropane 11.9 2.0 ug/L 20.00 BRL 59 21-140 2-Chloroethyl Vinyl Ether BRL 5.0 ug/L 20.00 BRL 15-181 MI 2-Chlorotoluene 22.7 0.50 ug/L 20.00 BRL 113 75-125 4-Chlorotoluene 22.6 0.50 ug/L 20.00 BRL 113 76-130 4-Isopropyltoluene 23.2 0.50 ug/L 20.00 BRL 116 72-129 Acetone 58.4 5.0 ug/L 40.00 BRL 146 40-162 Acrolein 49.6 20 ug/L 40.00 BRL 124 70-130 Acrylonitrile 57.5 20 ug/L 40.00 BRL 144 78-129 MI Benzene 30.6 0.50 ug/L 20.00 BRL 153 73-131 MI Bromobenzene 20.7 0.50 ug/L 20.00 BRL 104 80-125 Bromochloromethane 26.2 0.50 ug/L 20.00 BRL 131 78-135 Bromodichloromethane 24.2 0.50 ug/L 20.00 BRL 121 74-138 Bromoform 23.1 1.0 ug/L 20.00 BRL 115 72-130 Bromomethane 24.5 1.0 ug/L 20.00 BRL 122 41-173 Carbon disulfide 33.9 5.0 ug/L 20.00 BRL 169 59-138 MI Carbon Tetrachloride 29.6 0.50 ug/L 20.00 BRL 148 66-149 Chlorobenzene 26.8 0.50 ug/L 20.00 BRL 134 76-119 MI Chloroethane 29.8 0.50 ug/L 20.00 BRL 149 52-153 Chloroform 25.0 0.50 ug/L 20.00 0.800 121 74-136 Chloromethane 23.8 0.50 ug/L 20.00 BRL 119 39-155 cis-1,2-Dichloroethylene 27.5 0.50 ug/L 20.00 1.72 129 74-144 cis-1,3-Dichloropropylene 21.6 0.50 ug/L 20.00 BRL 108 64-132 Dibromochloromethane 21.5 0.50 ug/L 20.00 BRL 107 77-131 Dibromomethane 28.7 0.50 ug/L 20.00 BRL 144 76-136 MI Dichlorodifluoromethane 26.0 1.0 ug/L 20.00 BRL 130 22-170 Ethylbenzene 27.5 0.50 ug/L 20.00 BRL 137 78-130 MI This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 45 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Prism Work Order: 5070165 Attn: Aaron Oswald Time Submitted: 7/10/2015 8:50:OOAM 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO244 - 5030B Matrix Spike (P5G0244-MS1) Source: 5070165-04 Prepared: 07/14/15 Analyzed: 07/15/15 Hexachlorobutadiene 25.1 2.0 ug/L 20.00 BRL 126 63-132 Isopropyl Ether 23.5 0.50 ug/L 20.00 0.800 114 62-154 Isopropylbenzene (Cumene) 25.9 0.50 ug/L 20.00 BRL 130 72-127 M m,p-Xylenes 55.1 1.0 ug/L 40.00 BRL 138 66-144 Methyl Butyl Ketone (2-Hexanone) 17.5 5.0 ug/L 20.00 BRL 87 65-130 Methyl Ethyl Ketone (2-Butanone) 20.9 5.0 ug/L 20.00 BRL 104 65-137 Methyl Isobutyl Ketone 19.8 5.0 ug/L 20.00 BRL 99 64-137 Methylene Chloride 27.4 1.0 ug/L 20.00 BRL 137 71-134 M Methyl-tert-Butyl Ether 24.8 0.50 ug/L 20.00 BRL 124 71-133 Naphthalene 21.1 1.0 ug/L 20.00 0.730 102 63-134 n-Butylbenzene 21.5 1.0 ug/L 20.00 BRL 107 69-132 n-Propylbenzene 24.4 0.50 ug/L 20.00 BRL 122 75-130 o-Xylene 26.4 0.50 ug/L 20.00 BRL 132 75-131 M sec-Butylbenzene 25.4 0.50 ug/L 20.00 BRL 127 72-130 Styrene 26.5 0.50 ug/L 20.00 BRL 132 77-128 M tert-Butylbenzene 24.0 0.50 ug/L 20.00 BRL 120 72-130 Tetrachloroethylene 60.8 0.50 ug/L 20.00 290 NR 76-130 MI Toluene 30.5 0.50 ug/L 20.00 BRL 152 72-135 M trans-1,2-Dichloroethylene 27.9 0.50 ug/L 20.00 BRL 140 73-141 trans-1,3-Dichloropropylene 21.2 0.50 ug/L 20.00 BRL 106 64-137 Trichloroethylene 31.9 0.50 ug/L 20.00 3.35 143 72-133 M Trichlorofluoromethane 36.8 0.50 ug/L 20.00 BRL 184 61-152 M Vinyl acetate 25.8 2.0 ug/L 20.00 BRL 129 80-154 Vinyl chloride 29.0 0.50 ug/L 20.00 BRL 145 54-146 Surrogate:4-Bromofluorobenzene 21.8 ug/L 25.00 87 80-124 Surrogate: Dibromofluoromethane 26.0 ug/L 25.00 104 75-129 Surrogate: Toluene-d8 22.5 ug/L 25.00 90 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 46 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO262 - 5035 Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Blank (P5G0262-BLK1) Prepared & Analyzed: 07/16/15 1,1,1,2-Tetrachloroethane BRL 0.0050 mg/kg wet 1,1,1-Trichloroethane BRL 0.0050 mg/kg wet 1,1,2,2-Tetrachloroethane BRL 0.0050 mg/kg wet 1,1,2-Trichloroethane BRL 0.0050 mg/kg wet 1,1-Dichloroethane BRL 0.0050 mg/kg wet 1,1-Dichloroethylene BRL 0.0050 mg/kg wet 1,1-Dichloropropylene BRL 0.0050 mg/kg wet 1,2,3-Trichlorobenzene BRL 0.0050 mg/kg wet 1,2,3-Trichloropropane BRL 0.0050 mg/kg wet 1,2,4-Trichlorobenzene BRL 0.0050 mg/kg wet 1,2,4-Trimethyl benzene BRL 0.0050 mg/kg wet 1,2-Dibromoethane BRL 0.0050 mg/kg wet 1,2-Dichlorobenzene BRL 0.0050 mg/kg wet 1,2-Dichloroethane BRL 0.0050 mg/kg wet 1,2-Dichloropropane BRL 0.0050 mg/kg wet 1,3,5-Trimethyl benzene BRL 0.0050 mg/kg wet 1,3-Dichlorobenzene BRL 0.0050 mg/kg wet 1,3-Dichloropropane BRL 0.0050 mg/kg wet 1,4-Dichlorobenzene BRL 0.0050 mg/kg wet 2,2-Dichloropropane BRL 0.0050 mg/kg wet 2-Chlorotoluene BRL 0.0050 mg/kg wet 4-Chlorotoluene BRL 0.0050 mg/kg wet 4-Isopropyltoluene BRL 0.0050 mg/kg wet Acetone BRL 0.050 mg/kg wet Benzene BRL 0.0030 mg/kg wet Bromobenzene BRL 0.0050 mg/kg wet Bromochloromethane BRL 0.0050 mg/kg wet Bromodichloromethane BRL 0.0050 mg/kg wet Bromoform BRL 0.0050 mg/kg wet Bromomethane BRL 0.010 mg/kg wet Carbon Tetrachloride BRL 0.0050 mg/kg wet Chlorobenzene BRL 0.0050 mg/kg wet Chloroethane BRL 0.010 mg/kg wet Chloroform BRL 0.0050 mg/kg wet Chloromethane BRL 0.0050 mg/kg wet cis-1,2-Dichloroethylene BRL 0.0050 mg/kg wet cis-1,3-Dichloropropylene BRL 0.0050 mg/kg wet Dibromochloromethane BRL 0.0050 mg/kg wet Dichlorodifluoromethane BRL 0.0050 mg/kg wet Ethylbenzene BRL 0.0050 mg/kg wet Isopropyl Ether BRL 0.0050 mg/kg wet Isopropylbenzene (Cumene) BRL 0.0050 mg/kg wet m,p-Xylenes BRL 0.010 mg/kg wet Methyl Butyl Ketone (2-Hexanone) BRL 0.050 mg/kg wet Methyl Ethyl Ketone (2-Butanone) BRL 0.10 mg/kg wet Methyl Isobutyl Ketone BRL 0.050 mg/kg wet This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 47 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO262 - 5035 Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Blank (P5G0262-BLK1) Prepared & Analyzed: 07/16/15 Methylene Chloride BRL 0.0050 mg/kg wet Methyl-tert-Butyl Ether BRL 0.010 mg/kg wet Naphthalene BRL 0.010 mg/kg wet n-Butylbenzene BRL 0.0050 mg/kg wet n-Propylbenzene BRL 0.0050 mg/kg wet o-Xylene BRL 0.0050 mg/kg wet sec-Butylbenzene BRL 0.0050 mg/kg wet Styrene BRL 0.0050 mg/kg wet tert-Butylbenzene BRL 0.0050 mg/kg wet Tetrachloroethylene BRL 0.0050 mg/kg wet Toluene BRL 0.0050 mg/kg wet trans-1,2-Dichloroethylene BRL 0.0050 mg/kg wet trans- 1,3-Dichloropropylene BRL 0.0050 mg/kg wet Trichloroethylene BRL 0.0050 mg/kg wet Trichlorofluoromethane BRL 0.0050 mg/kg wet Vinyl acetate BRL 0.025 mg/kg wet Vinyl chloride BRL 0.0050 mg/kg wet Xylenes, total BRL 0.015 mg/kg wet Surrogate: 4-Bromofluorobenzene 0.0612 mg/kg wet 0.05000 122 70-130 Surrogate: Dibromofluoromethane 0.0518 mg/kg wet 0.05000 104 84-123 Surrogate: Toluene-d8 0.0501 mg/kg wet 0.05000 100 76-129 LCS (P5G0262-BS1) Prepared & Analyzed: 07/16/15 1,1,1,2-Tetrachloroethane 0.0498 0.0050 mg/kg wet 0.05000 100 72-115 1,1,1-Trichloroethane 0.0505 0.0050 mg/kg wet 0.05000 101 67-131 1,1,2,2-Tetrachloroethane 0.0520 0.0050 mg/kg wet 0.05000 104 56-126 1,1,2-Trichloroethane 0.0480 0.0050 mg/kg wet 0.05000 96 70-133 1,1-Dichloroethane 0.0433 0.0050 mg/kg wet 0.05000 87 74-127 1,1-Dichloroethylene 0.0468 0.0050 mg/kg wet 0.05000 94 67-149 1,1-Dichloropropylene 0.0493 0.0050 mg/kg wet 0.05000 99 71-130 1,2,3-Trichlorobenzene 0.0567 0.0050 mg/kg wet 0.05000 113 68-130 1,2,3-Trichloropropane 0.0521 0.0050 mg/kg wet 0.05000 104 60-137 1,2,4-Trichlorobenzene 0.0571 0.0050 mg/kg wet 0.05000 114 66-125 1,2,4-Trimethyl benzene 0.0534 0.0050 mg/kg wet 0.05000 107 69-129 1,2-Dibromoethane 0.0528 0.0050 mg/kg wet 0.05000 106 70-132 1,2-Dichlorobenzene 0.0530 0.0050 mg/kg wet 0.05000 106 72-123 1,2-Dichloroethane 0.0487 0.0050 mg/kg wet 0.05000 97 68-128 1,2-Dichloropropane 0.0410 0.0050 mg/kg wet 0.05000 82 73-130 1,3,5-Trimethyl benzene 0.0552 0.0050 mg/kg wet 0.05000 110 69-128 1,3-Dichlorobenzene 0.0519 0.0050 mg/kg wet 0.05000 104 71-120 1,3-Dichloropropane 0.0457 0.0050 mg/kg wet 0.05000 91 75-124 1,4-Dichlorobenzene 0.0512 0.0050 mg/kg wet 0.05000 102 71-123 2,2-Dichloropropane 0.0490 0.0050 mg/kg wet 0.05000 98 50-142 2-Chlorotoluene 0.0544 0.0050 mg/kg wet 0.05000 109 67-124 4-Chlorotoluene 0.0517 0.0050 mg/kg wet 0.05000 103 71-126 4-Isopropyltoluene 0.0520 0.0050 mg/kg wet 0.05000 104 68-129 Acetone 0.0928 0.050 mg/kg wet 0.1000 93 29-198 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 48 of 80 P R I IS M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Analyte Batch P51130262 - 5035 Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS (P5G0262-BSI) Prepared & Analyzed: 07/16/15 Benzene 0.0483 0.0030 mg/kg wet 0.05000 97 74-127 Bromobenzene 0.0526 0.0050 mg/kg wet 0.05000 105 73-125 Bromochloromethane 0.0520 0.0050 mg/kg wet 0.05000 104 72-134 Bromodichloromethane 0.0448 0.0050 mg/kg wet 0.05000 90 75-122 Bromoform 0.0508 0.0050 mg/kg wet 0.05000 102 66-135 Bromomethane 0.0552 0.010 mg/kg wet 0.05000 110 20-180 Carbon Tetrachloride 0.0570 0.0050 mg/kg wet 0.05000 114 64-143 Chlorobenzene 0.0475 0.0050 mg/kg wet 0.05000 95 74-118 Chloroethane 0.0424 0.010 mg/kg wet 0.05000 85 33-149 Chloroform 0.0447 0.0050 mg/kg wet 0.05000 89 73-127 Chloromethane 0.0383 0.0050 mg/kg wet 0.05000 77 45-143 cis-1,2-Dichloroethylene 0.0449 0.0050 mg/kg wet 0.05000 90 76-134 cis-1,3-Dichloropropylene 0.0458 0.0050 mg/kg wet 0.05000 92 71-125 Dibromochloromethane 0.0487 0.0050 mg/kg wet 0.05000 97 73-122 Dichlorodifluoromethane 0.0345 0.0050 mg/kg wet 0.05000 69 26-146 Ethylbenzene 0.0476 0.0050 mg/kg wet 0.05000 95 74-128 Isopropyl Ether 0.0383 0.0050 mg/kg wet 0.05000 77 59-159 Isopropylbenzene (Cumene) 0.0562 0.0050 mg/kg wet 0.05000 112 68-126 m,p-Xylenes 0.100 0.010 mg/kg wet 0.1000 100 75-124 Methyl Butyl Ketone (2-Hexanone) 0.0464 0.050 mg/kg wet 0.05000 93 61-157 Methyl Ethyl Ketone (2-Butanone) 0.0522 0.10 mg/kg wet 0.05000 104 63-149 Methyl Isobutyl Ketone 0.0427 0.050 mg/kg wet 0.05000 85 57-162 Methylene Chloride 0.0412 0.0050 mg/kg wet 0.05000 82 74-129 Methyl-tert-Butyl Ether 0.0460 0.010 mg/kg wet 0.05000 92 70-130 Naphthalene 0.0552 0.010 mg/kg wet 0.05000 110 57-157 n-Butylbenzene 0.0534 0.0050 mg/kg wet 0.05000 107 65-135 n-Propylbenzene 0.0544 0.0050 mg/kg wet 0.05000 109 67-130 o-Xylene 0.0518 0.0050 mg/kg wet 0.05000 104 74-126 sec-Butylbenzene 0.0528 0.0050 mg/kg wet 0.05000 106 66-131 Styrene 0.0514 0.0050 mg/kg wet 0.05000 103 77-121 tert-Butyl benzene 0.0546 0.0050 mg/kg wet 0.05000 109 67-132 Tetrachloroethylene 0.0510 0.0050 mg/kg wet 0.05000 102 68-130 Toluene 0.0494 0.0050 mg/kg wet 0.05000 99 71-129 trans- 1,2-Dichloroethylene 0.0464 0.0050 mg/kg wet 0.05000 93 73-132 trans- 1,3-Dichloropropylene 0.0491 0.0050 mg/kg wet 0.05000 98 68-123 Trichloroethylene 0.0486 0.0050 mg/kg wet 0.05000 97 75-133 Trichlorofluoromethane 0.0547 0.0050 mg/kg wet 0.05000 109 44-146 Vinyl acetate 0.0419 0.025 mg/kg wet 0.05000 84 85-161 Vinyl chloride 0.0434 0.0050 mg/kg wet 0.05000 87 48-147 Xylenes, total 0.152 0.015 mg/kg wet 0.1500 101 74-126 Surrogate: 4-Bromofluorobenzene 0.0561 mg/kg wet 0.05000 112 70-130 Surrogate: Dibromofluoromethane 0.0517 mg/kg wet 0.05000 103 84-123 Surrogate: Toluene-d8 0.0508 mg/kg wet 0.05000 102 76-129 A This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 49 of 80 P R I IS M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Analyte Batch P51130262 - 5035 Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS Dup (P5G0262-BSD1) Prepared & Analyzed: 07/16/15 1,1,1,2-Tetrachloroethane 0.0527 0.0050 mg/kg wet 0.05000 105 72-115 6 20 1,1,1-Trichloroethane 0.0512 0.0050 mg/kg wet 0.05000 102 67-131 1 20 1,1,2,2-Tetrachloroethane 0.0498 0.0050 mg/kg wet 0.05000 100 56-126 4 20 1,1,2-Trichloroethane 0.0464 0.0050 mg/kg wet 0.05000 93 70-133 3 20 1,1-Dichloroethane 0.0443 0.0050 mg/kg wet 0.05000 89 74-127 2 20 1,1-Dichloroethylene 0.0472 0.0050 mg/kg wet 0.05000 94 67-149 0.8 20 1, 1 -Dichloropropylene 0.0490 0.0050 mg/kg wet 0.05000 98 71-130 0.6 20 1,2,3-Trichlorobenzene 0.0563 0.0050 mg/kg wet 0.05000 113 68-130 0.8 20 1,2,3-Trichloropropane 0.0490 0.0050 mg/kg wet 0.05000 98 60-137 6 20 1,2,4-Trichlorobenzene 0.0554 0.0050 mg/kg wet 0.05000 111 66-125 3 20 1,2,4-Trimethylbenzene 0.0516 0.0050 mg/kg wet 0.05000 103 69-129 3 20 1,2-Dibromoethane 0.0523 0.0050 mg/kg wet 0.05000 105 70-132 0.9 20 1,2-Dichlorobenzene 0.0519 0.0050 mg/kg wet 0.05000 104 72-123 2 20 1,2-Dichloroethane 0.0489 0.0050 mg/kg wet 0.05000 98 68-128 0.5 20 1,2-Dichloropropane 0.0427 0.0050 mg/kg wet 0.05000 85 73-130 4 20 1,3,5-Trimethylbenzene 0.0544 0.0050 mg/kg wet 0.05000 109 69-128 1 20 1,3-Dichlorobenzene 0.0519 0.0050 mg/kg wet 0.05000 104 71-120 0.1 20 1,3-Dichloropropane 0.0466 0.0050 mg/kg wet 0.05000 93 75-124 2 20 1,4-Dichlorobenzene 0.0504 0.0050 mg/kg wet 0.05000 101 71-123 2 20 2,2-Dichloropropane 0.0486 0.0050 mg/kg wet 0.05000 97 50-142 0.7 20 2-Chlorotoluene 0.0532 0.0050 mg/kg wet 0.05000 106 67-124 2 20 4-Chlorotoluene 0.0518 0.0050 mg/kg wet 0.05000 104 71-126 0.3 20 4-Isopropyltoluene 0.0538 0.0050 mg/kg wet 0.05000 108 68-129 3 20 Acetone 0.0868 0.050 mg/kg wet 0.1000 87 29-198 7 20 Benzene 0.0501 0.0030 mg/kg wet 0.05000 100 74-127 4 20 Bromobenzene 0.0508 0.0050 mg/kg wet 0.05000 102 73-125 3 20 Bromochloromethane 0.0534 0.0050 mg/kg wet 0.05000 107 72-134 3 20 Bromodichloromethane 0.0446 0.0050 mg/kg wet 0.05000 89 75-122 0.5 20 Bromoform 0.0491 0.0050 mg/kg wet 0.05000 98 66-135 3 20 Bromomethane 0.0544 0.010 mg/kg wet 0.05000 109 20-180 1 20 Carbon Tetrachloride 0.0567 0.0050 mg/kg wet 0.05000 113 64-143 0.4 20 Chlorobenzene 0.0495 0.0050 mg/kg wet 0.05000 99 74-118 4 20 Chloroethane 0.0465 0.010 mg/kg wet 0.05000 93 33-149 9 20 Chloroform 0.0470 0.0050 mg/kg wet 0.05000 94 73-127 5 20 Chloromethane 0.0378 0.0050 mg/kg wet 0.05000 76 45-143 1 20 cis-1,2-Dichloroethylene 0.0459 0.0050 mg/kg wet 0.05000 92 76-134 2 20 cis-1,3-Dichloropropylene 0.0468 0.0050 mg/kg wet 0.05000 94 71-125 2 20 Dibromochloromethane 0.0492 0.0050 mg/kg wet 0.05000 98 73-122 1 20 Dichlorodifluoromethane 0.0344 0.0050 mg/kg wet 0.05000 69 26-146 0.2 20 Ethylbenzene 0.0502 0.0050 mg/kg wet 0.05000 100 74-128 5 20 Isopropyl Ether 0.0392 0.0050 mg/kg wet 0.05000 78 59-159 2 20 Isopropylbenzene (Cumene) 0.0548 0.0050 mg/kg wet 0.05000 110 68-126 3 20 m,p-Xylenes 0.0993 0.010 mg/kg wet 0.1000 99 75-124 0.7 20 Methyl Butyl Ketone (2-Hexanone) 0.0415 0.050 mg/kg wet 0.05000 83 61-157 11 20 Methyl Ethyl Ketone (2-Butanone) 0.0445 0.10 mg/kg wet 0.05000 89 63-149 16 20 Methyl Isobutyl Ketone 0.0402 0.050 mg/kg wet 0.05000 80 57-162 6 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 50 of 80 P R I IS M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO262 - 5035 Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS Dup (P5G0262-BSD1) Prepared & Analyzed: 07/16/15 Methylene Chloride 0.0428 0.0050 mg/kg wet 0.05000 86 74-129 4 20 Methyl-tert-Butyl Ether 0.0468 0.010 mg/kg wet 0.05000 94 70-130 2 20 Naphthalene 0.0500 0.010 mg/kg wet 0.05000 100 57-157 10 20 n-Butylbenzene 0.0531 0.0050 mg/kg wet 0.05000 106 65-135 0.6 20 n-Propylbenzene 0.0536 0.0050 mg/kg wet 0.05000 107 67-130 1 20 o-Xylene 0.0520 0.0050 mg/kg wet 0.05000 104 74-126 0.4 20 sec-Butylbenzene 0.0518 0.0050 mg/kg wet 0.05000 104 66-131 2 20 Styrene 0.0527 0.0050 mg/kg wet 0.05000 105 77-121 3 20 tert-Butyl benzene 0.0527 0.0050 mg/kg wet 0.05000 105 67-132 4 20 Tetrachloroethylene 0.0518 0.0050 mg/kg wet 0.05000 104 68-130 2 20 Toluene 0.0510 0.0050 mg/kg wet 0.05000 102 71-129 3 20 trans- 1,2-Dichloroethylene 0.0466 0.0050 mg/kg wet 0.05000 93 73-132 0.5 20 trans- 1,3-Dichloropropylene 0.0494 0.0050 mg/kg wet 0.05000 99 68-123 0.7 20 Trichloroethylene 0.0511 0.0050 mg/kg wet 0.05000 102 75-133 5 20 Trichlorofluoromethane 0.0545 0.0050 mg/kg wet 0.05000 109 44-146 0.2 20 Vinyl acetate 0.0395 0.025 mg/kg wet 0.05000 79 85-161 6 20 A Vinyl chloride 0.0448 0.0050 mg/kg wet 0.05000 90 48-147 3 20 Xylenes, total 0.151 0.015 mg/kg wet 0.1500 101 74-126 0.3 20 Surrogate: 4-Bromofluorobenzene 0.0534 mg/kg wet 0.05000 107 70-130 Surrogate: Dibromofluoromethane 0.0504 mg/kg wet 0.05000 101 84-123 Surrogate: Toluene-d8 0.0521 mg/kg wet 0.05000 104 76-129 Matrix Spike (P5GO262-MS1) Source: 5070165-02 Prepared & Analyzed: 07/16/15 1,1,1,2-Tetrachloroethane 0.0376 0.0065 mg/kg dry 0.06457 BRL 58 60-120 MI 1,1,1-Trichloroethane 0.0399 0.0065 mg/kg dry 0.06457 BRL 62 52-139 1,1,2,2-Tetrachloroethane 0.0353 0.0065 mg/kg dry 0.06457 BRL 55 39-135 1,1,2-Trichloroethane 0.0721 0.0065 mg/kg dry 0.06457 BRL 112 44-140 1,1-Dichloroethane 0.0367 0.0065 mg/kg dry 0.06457 BRL 57 59-137 MI 1,1-Dichloroethylene 0.0392 0.0065 mg/kg dry 0.06457 BRL 61 54-162 1, 1 -Dichloropropylene 0.0371 0.0065 mg/kg dry 0.06457 BRL 57 55-137 1,2,3-Trichlorobenzene 0.0188 0.0065 mg/kg dry 0.06457 BRL 29 34-120 MI 1,2,3-Trichloropropane 0.0305 0.0065 mg/kg dry 0.06457 BRL 47 45-139 1,2,4-Trichlorobenzene 0.0195 0.0065 mg/kg dry 0.06457 BRL 30 35-116 MI 1,2,4-Trimethylbenzene 0.0332 0.0065 mg/kg dry 0.06457 BRL 51 38-142 1,2-Dibromoethane 0.0342 0.0065 mg/kg dry 0.06457 BRL 53 49-132 1,2-Dichlorobenzene 0.0266 0.0065 mg/kg dry 0.06457 BRL 41 42-130 MI 1,2-Dichloroethane 0.0356 0.0065 mg/kg dry 0.06457 BRL 55 51-131 1,2-Dichloropropane 0.0354 0.0065 mg/kg dry 0.06457 BRL 55 55-138 1,3,5-Trimethylbenzene 0.0330 0.0065 mg/kg dry 0.06457 BRL 51 44-140 1,3-Dichlorobenzene 0.0257 0.0065 mg/kg dry 0.06457 BRL 40 41-129 MI 1,3-Dichloropropane 0.0447 0.0065 mg/kg dry 0.06457 BRL 69 53-129 1,4-Dichlorobenzene 0.0252 0.0065 mg/kg dry 0.06457 BRL 39 44-134 MI 2,2-Dichloropropane 0.0389 0.0065 mg/kg dry 0.06457 BRL 60 30-147 2-Chlorotoluene 0.0308 0.0065 mg/kg dry 0.06457 BRL 48 46-132 4-Chlorotoluene 0.0300 0.0065 mg/kg dry 0.06457 BRL 46 44-135 4-Isopropyltoluene 0.0292 0.0065 mg/kg dry 0.06457 BRL 45 32-144 Acetone 0.0675 0.065 mg/kg dry 0.1291 0.0904 NR 34-143 MI This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 51 of 80 P R I IS M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Analyte Batch P51130262 - 5035 Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Matrix Spike (P5G0262-MS1) Source: 5070165-02 Prepared & Analyzed: 07/16/15 Benzene 0.0400 0.0039 mg/kg dry 0.06457 BRL 62 60-135 Bromobenzene 0.0307 0.0065 mg/kg dry 0.06457 BRL 48 45-135 Bromochloromethane 0.0401 0.0065 mg/kg dry 0.06457 BRL 62 55-136 Bromodichloromethane 0.0323 0.0065 mg/kg dry 0.06457 BRL 50 55-127 Bromoform 0.0303 0.0065 mg/kg dry 0.06457 BRL 47 40-136 Bromomethane 0.0377 0.013 mg/kg dry 0.06457 BRL 58 30-137 Carbon Tetrachloride 0.0403 0.0065 mg/kg dry 0.06457 BRL 62 48-153 Chlorobenzene 0.0329 0.0065 mg/kg dry 0.06457 BRL 51 57-125 Chloroethane 0.0362 0.013 mg/kg dry 0.06457 BRL 56 16-177 Chloroform 0.0367 0.0065 mg/kg dry 0.06457 BRL 57 56-137 Chloromethane 0.0300 0.0065 mg/kg dry 0.06457 BRL 46 40-145 cis-1,2-Dichloroethylene 0.0357 0.0065 mg/kg dry 0.06457 BRL 55 58-140 cis-1,3-Dichloropropylene 0.0315 0.0065 mg/kg dry 0.06457 BRL 49 42-135 Dibromochloromethane 0.0313 0.0065 mg/kg dry 0.06457 BRL 48 49-127 Dichlorodifluoromethane 0.0258 0.0065 mg/kg dry 0.06457 BRL 40 25-151 Ethylbenzene 0.0355 0.0065 mg/kg dry 0.06457 BRL 55 44-144 Isopropyl Ether 0.0316 0.0065 mg/kg dry 0.06457 BRL 49 51-155 Isopropylbenzene (Cumene) 0.0366 0.0065 mg/kg dry 0.06457 BRL 57 41-140 m,p-Xylenes 0.0642 0.013 mg/kg dry 0.1291 BRL 50 36-148 Methyl Butyl Ketone (2-Hexanone) 0.0257 0.065 mg/kg dry 0.06457 BRL 40 30-147 Methyl Ethyl Ketone (2-Butanone) 0.0331 0.13 mg/kg dry 0.06457 0.00467 44 24-160 Methyl Isobutyl Ketone 0.0483 0.065 mg/kg dry 0.06457 BRL 75 25-163 Methylene Chloride 0.0462 0.0065 mg/kg dry 0.06457 BRL 72 53-144 Methyl-tert-Butyl Ether 0.0367 0.013 mg/kg dry 0.06457 BRL 57 49-135 Naphthalene 0.0231 0.013 mg/kg dry 0.06457 BRL 36 32-127 n-Butylbenzene 0.0257 0.0065 mg/kg dry 0.06457 BRL 40 23-148 n-Propylbenzene 0.0316 0.0065 mg/kg dry 0.06457 BRL 49 35-144 o-Xylene 0.0343 0.0065 mg/kg dry 0.06457 BRL 53 43-143 sec-Butylbenzene 0.0299 0.0065 mg/kg dry 0.06457 BRL 46 34-144 Styrene 0.0317 0.0065 mg/kg dry 0.06457 BRL 49 42-132 tert-Butyl benzene 0.0336 0.0065 mg/kg dry 0.06457 BRL 52 36-150 Tetrachloroethylene 0.0342 0.0065 mg/kg dry 0.06457 BRL 53 47-142 Toluene 0.0381 0.0065 mg/kg dry 0.06457 BRL 59 57-135 trans- 1,2-Dichloroethylene 0.0341 0.0065 mg/kg dry 0.06457 BRL 53 58-141 trans- 1,3-Dichloropropylene 0.0303 0.0065 mg/kg dry 0.06457 BRL 47 41-124 Trichloroethylene 0.0367 0.0065 mg/kg dry 0.06457 BRL 57 38-164 Trichlorofluoromethane 0.0366 0.0065 mg/kg dry 0.06457 BRL 57 30-157 Vinyl acetate BRL 0.032 mg/kg dry 0.06457 BRL 61-154 Vinyl chloride 0.0347 0.0065 mg/kg dry 0.06457 BRL 54 40-156 Xylenes, total 0.0986 0.019 mg/kg dry 0.1937 BRL 51 36-148 Surrogate: 4-Bromofluorobenzene 0.0726 mg/kg dry 0.06457 112 70-130 Surrogate: Dibromofluoromethane 0.0646 mg/kg dry 0.06457 100 84-123 Surrogate: Toluene-d8 0.0616 mg/kg dry 0.06457 95 76-129 MI MI MI MI MI bt MI This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 52 of 80 P R I IS M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Analyte Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Batch P51130262 - 5035 Matrix Spike Dup (P5G0262-MSD1) Source: 5070165-02 Prepared & Analyzed: 07/16/15 1,1,1,2-Tetrachloroethane 0.0363 0.0067 mg/kg dry 0.06671 BRL 54 60-120 4 15 MI 1,1,1-Trichloroethane 0.0394 0.0067 mg/kg dry 0.06671 BRL 59 52-139 1 21 1,1,2,2-Tetrachloroethane 0.0359 0.0067 mg/kg dry 0.06671 BRL 54 39-135 2 22 1,1,2-Trichloroethane 0.0368 0.0067 mg/kg dry 0.06671 BRL 55 44-140 65 21 D 1,1-Dichloroethane 0.0363 0.0067 mg/kg dry 0.06671 BRL 54 59-137 1 21 MI 1,1-Dichloroethylene 0.0390 0.0067 mg/kg dry 0.06671 BRL 59 54-162 0.5 22 1, 1 -Dichloropropylene 0.0374 0.0067 mg/kg dry 0.06671 BRL 56 55-137 1 19 1,2,3-Trichlorobenzene 0.0172 0.0067 mg/kg dry 0.06671 BRL 26 34-120 9 41 MI 1,2,3-Trichloropropane 0.0317 0.0067 mg/kg dry 0.06671 BRL 48 45-139 4 25 1,2,4-Trichlorobenzene 0.0178 0.0067 mg/kg dry 0.06671 BRL 27 35-116 9 62 MI 1,2,4-Trimethylbenzene 0.0299 0.0067 mg/kg dry 0.06671 BRL 45 38-142 10 24 1,2-Dibromoethane 0.0346 0.0067 mg/kg dry 0.06671 BRL 52 49-132 1 15 1,2-Dichlorobenzene 0.0233 0.0067 mg/kg dry 0.06671 BRL 35 42-130 13 21 MI 1,2-Dichloroethane 0.0355 0.0067 mg/kg dry 0.06671 BRL 53 51-131 0.2 13 1,2-Dichloropropane 0.0359 0.0067 mg/kg dry 0.06671 BRL 54 55-138 1 16 MI 1,3,5-Trimethylbenzene 0.0308 0.0067 mg/kg dry 0.06671 BRL 46 44-140 7 29 1,3-Dichlorobenzene 0.0244 0.0067 mg/kg dry 0.06671 BRL 37 41-129 5 24 MI 1,3-Dichloropropane 0.0352 0.0067 mg/kg dry 0.06671 BRL 53 53-129 24 15 D 1,4-Dichlorobenzene 0.0232 0.0067 mg/kg dry 0.06671 BRL 35 44-134 8 21 MI 2,2-Dichloropropane 0.0382 0.0067 mg/kg dry 0.06671 BRL 57 30-147 2 20 2-Chlorotoluene 0.0299 0.0067 mg/kg dry 0.06671 BRL 45 46-132 3 29 MI 4-Chlorotoluene 0.0271 0.0067 mg/kg dry 0.06671 BRL 41 44-135 10 23 MI 4-Isopropyltoluene 0.0272 0.0067 mg/kg dry 0.06671 BRL 41 32-144 7 22 Acetone 0.0854 0.067 mg/kg dry 0.1334 0.0904 NR 34-143 23 49 MI Benzene 0.0393 0.0040 mg/kg dry 0.06671 BRL 59 60-135 2 20 MI Bromobenzene 0.0288 0.0067 mg/kg dry 0.06671 BRL 43 45-135 6 25 MI Bromochloromethane 0.0406 0.0067 mg/kg dry 0.06671 BRL 61 55-136 1 18 Bromodichloromethane 0.0333 0.0067 mg/kg dry 0.06671 BRL 50 55-127 3 17 MI Bromoform 0.0314 0.0067 mg/kg dry 0.06671 BRL 47 40-136 4 35 Bromomethane 0.0383 0.013 mg/kg dry 0.06671 BRL 57 30-137 1 30 Carbon Tetrachloride 0.0418 0.0067 mg/kg dry 0.06671 BRL 63 48-153 4 23 Chlorobenzene 0.0302 0.0067 mg/kg dry 0.06671 BRL 45 57-125 9 14 MI Chloroethane 0.0363 0.013 mg/kg dry 0.06671 BRL 54 16-177 0.2 47 Chloroform 0.0363 0.0067 mg/kg dry 0.06671 BRL 54 56-137 1 18 MI Chloromethane 0.0320 0.0067 mg/kg dry 0.06671 BRL 48 40-145 6 26 cis-1,2-Dichloroethylene 0.0338 0.0067 mg/kg dry 0.06671 BRL 51 58-140 6 28 MI cis-1,3-Dichloropropylene 0.0307 0.0067 mg/kg dry 0.06671 BRL 46 42-135 3 32 Dibromochloromethane 0.0325 0.0067 mg/kg dry 0.06671 BRL 49 49-127 4 24 Dichlorodifluoromethane 0.0268 0.0067 mg/kg dry 0.06671 BRL 40 25-151 4 37 Ethylbenzene 0.0332 0.0067 mg/kg dry 0.06671 BRL 50 44-144 7 19 Isopropyl Ether 0.0314 0.0067 mg/kg dry 0.06671 BRL 47 51-155 0.5 13 MI Isopropylbenzene (Cumene) 0.0366 0.0067 mg/kg dry 0.06671 BRL 55 41-140 0.03 27 m,p-Xylenes 0.0634 0.013 mg/kg dry 0.1334 BRL 47 36-148 1 20 Methyl Butyl Ketone (2-Hexanone) 0.0286 0.067 mg/kg dry 0.06671 BRL 43 30-147 10 42 Methyl Ethyl Ketone (2-Butanone) 0.0339 0.13 mg/kg dry 0.06671 0.00467 44 24-160 2 42 Methyl Isobutyl Ketone 0.0342 0.067 mg/kg dry 0.06671 BRL 51 25-163 34 44 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 53 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO262 - 5035 Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Matrix Spike Dup (P5G0262-MSD1) Source: 5070165-02 Prepared & Analyzed: 07/16/15 Methylene Chloride 0.0468 0.0067 mg/kg dry 0.06671 BRL 70 53-144 1 14 Methyl-tert-Butyl Ether 0.0373 0.013 mg/kg dry 0.06671 BRL 56 49-135 2 22 Naphthalene 0.0198 0.013 mg/kg dry 0.06671 BRL 30 32-127 15 44 MI n-Butylbenzene 0.0247 0.0067 mg/kg dry 0.06671 BRL 37 23-148 4 39 n-Propylbenzene 0.0303 0.0067 mg/kg dry 0.06671 BRL 45 35-144 4 27 o-Xylene 0.0332 0.0067 mg/kg dry 0.06671 BRL 50 43-143 3 17 sec-Butylbenzene 0.0285 0.0067 mg/kg dry 0.06671 BRL 43 34-144 5 28 Styrene 0.0288 0.0067 mg/kg dry 0.06671 BRL 43 42-132 10 28 tert-Butylbenzene 0.0316 0.0067 mg/kg dry 0.06671 BRL 47 36-150 6 29 Tetrachloroethylene 0.0328 0.0067 mg/kg dry 0.06671 BRL 49 47-142 4 26 Toluene 0.0354 0.0067 mg/kg dry 0.06671 BRL 53 57-135 8 22 MI trans-1,2-Dichloroethylene 0.0343 0.0067 mg/kg dry 0.06671 BRL 51 58-141 0.7 18 MI trans- 1,3-Dichloropropylene 0.0297 0.0067 mg/kg dry 0.06671 BRL 45 41-124 2 20 Trichloroethylene 0.0363 0.0067 mg/kg dry 0.06671 BRL 54 38-164 1 18 Trichlorofluoromethane 0.0401 0.0067 mg/kg dry 0.06671 BRL 60 30-157 9 27 Vinyl acetate BRL 0.033 mg/kg dry 0.06671 BRL 61-154 35 MI Vinyl chloride 0.0335 0.0067 mg/kg dry 0.06671 BRL 50 40-156 4 35 Xylenes, total 0.0965 0.020 mg/kg dry 0.2001 BRL 48 36-148 2 20 Surrogate: 4-Bromofluorobenzene 0.0748 mg/kg dry 0.06671 112 70-130 Surrogate: Dibromofluoromethane 0.0671 mg/kg dry 0.06671 101 84-123 Surrogate: Toluene-d8 0.0671 mg/kg dry 0.06671 101 76-129 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 54 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Prism Work Order: 5070165 Attn: Aaron Oswald Time Submitted: 7/10/2015 8:50:OOAM 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO175 - 3546 Blank (P5G0175-BLK1) Prepared & Analyzed: 07/13/15 1,2,4-Trichlorobenzene BRL 0.33 mg/kg wet 1,2-Dichlorobenzene BRL 0.33 mg/kg wet 1,3-Dichlorobenzene BRL 0.33 mg/kg wet 1,4-Dichlorobenzene BRL 0.33 mg/kg wet 1-Methyl naphthalene BRL 0.33 mg/kg wet 2,4,6-Trichlorophenol BRL 0.33 mg/kg wet 2,4-Dichlorophenol BRL 0.33 mg/kg wet 2,4-Dimethylphenol BRL 0.33 mg/kg wet 2,4-Dinitrophenol BRL 0.33 mg/kg wet 2,4-Dinitrotoluene BRL 0.33 mg/kg wet 2,6-Dinitrotoluene BRL 0.33 mg/kg wet 2-Chloronaphthalene BRL 0.33 mg/kg wet 2-Chlorophenol BRL 0.33 mg/kg wet 2-Methyl naphthalene BRL 0.33 mg/kg wet 2-Methylphenol BRL 0.33 mg/kg wet 2-Nitrophenol BRL 0.33 mg/kg wet 3,3'-Dichlorobenzidine BRL 0.33 mg/kg wet 3/4-Methyl phenol BRL 0.33 mg/kg wet 4,6-Dinitro-2-methylphenol BRL 0.33 mg/kg wet 4-Bromophenyl phenyl ether BRL 0.33 mg/kg wet 4-Chloro-3-methylphenol BRL 0.33 mg/kg wet 4-Chloroaniline BRL 0.33 mg/kg wet 4-Chlorophenyl phenyl ether BRL 0.33 mg/kg wet 4-Nitrophenol BRL 0.33 mg/kg wet Acenaphthene BRL 0.33 mg/kg wet Acenaphthylene BRL 0.33 mg/kg wet Anthracene BRL 0.33 mg/kg wet Azobenzene BRL 0.33 mg/kg wet Benzo(a)anthracene BRL 0.33 mg/kg wet Benzo(a)pyrene BRL 0.33 mg/kg wet Benzo(b)fluoranthene BRL 0.33 mg/kg wet Benzo(g,h,i)perylene BRL 0.33 mg/kg wet Benzo(k)fluoranthene BRL 0.33 mg/kg wet Benzoic Acid BRL 0.33 mg/kg wet Benzyl alcohol BRL 0.33 mg/kg wet bis(2-Chloroethoxy)methane BRL 0.33 mg/kg wet Bis(2-Chloroethyl)ether BRL 0.33 mg/kg wet Bis(2-chloroisopropyl)ether BRL 0.33 mg/kg wet Bis(2-Ethylhexyl)phthalate BRL 0.33 mg/kg wet Butyl benzyl phthalate BRL 0.33 mg/kg wet Chrysene BRL 0.33 mg/kg wet Dibenzo(a,h)anthracene BRL 0.33 mg/kg wet Dibenzofuran BRL 0.33 mg/kg wet Diethyl phthalate BRL 0.33 mg/kg wet Dimethyl phthalate BRL 0.33 mg/kg wet Di-n-butyl phthalate BRL 0.33 mg/kg wet This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 55 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO175 - 3546 Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Blank (P5G0175-BLK1) Prepared & Analyzed: 07/13/15 Di-n-octyl phthalate BRL 0.33 mg/kg wet Fluoranthene BRL 0.33 mg/kg wet Fluorene BRL 0.33 mg/kg wet Hexachlorobenzene BRL 0.33 mg/kg wet Hexachlorobutadiene BRL 0.33 mg/kg wet Hexachlorocyclopentadiene BRL 0.33 mg/kg wet Hexachloroethane BRL 0.33 mg/kg wet Indeno(1,2,3-cd)pyrene BRL 0.33 mg/kg wet Isophorone BRL 0.33 mg/kg wet Naphthalene BRL 0.33 mg/kg wet Nitrobenzene BRL 0.33 mg/kg wet N-Nitroso-di-n-propylamine BRL 0.33 mg/kg wet N-Nitrosodiphenylamine BRL 0.33 mg/kg wet Pentachlorophenol BRL 0.33 mg/kg wet Phenanthrene BRL 0.33 mg/kg wet Phenol BRL 0.33 mg/kg wet Pyrene BRL 0.33 mg/kg wet Surrogate: 2,4,6-Tribromophenol 3.79 mg/kg wet 3.333 114 39-132 Surrogate: 2-Fluorobiphenyl 1.80 mg/kg wet 1.667 108 44-115 Surrogate: 2-Fluorophenol 3.46 mg/kg wet 3.333 104 35-115 Surrogate: Nitrobenzene-d5 1.68 mg/kg wet 1.667 101 37-122 Surrogate: Phenol-d5 3.47 mg/kg wet 3.333 104 34-121 Surrogate: Terphenyl-d14 1.98 mg/kg wet 1.667 119 54-127 LCS (MG0175-BS1) Prepared & Analyzed: 07/13/15 1,2,4-Trichlorobenzene 1.32 0.33 mg/kg wet 1.667 79 34-118 1,2-Dichlorobenzene 1.22 0.33 mg/kg wet 1.667 73 33-117 1,3-Dichlorobenzene 1.17 0.33 mg/kg wet 1.667 70 30-115 1,4-Dichlorobenzene 1.19 0.33 mg/kg wet 1.667 71 31-115 1-Methyl naphthalene 1.34 0.33 mg/kg wet 1.667 80 40-119 2,4,6-Trichlorophenol 1.46 0.33 mg/kg wet 1.667 88 39-126 2,4-Dichlorophenol 1.42 0.33 mg/kg wet 1.667 85 40-122 2,4-Dimethylphenol 1.41 0.33 mg/kg wet 1.667 84 30-127 2,4-Dinitrophenol 1.05 0.33 mg/kg wet 1.667 63 27-129 2,4-Dinitrotoluene 1.58 0.33 mg/kg wet 1.667 95 48-126 2,6-Dinitrotoluene 1.56 0.33 mg/kg wet 1.667 94 46-124 2-Chloronaphthalene 1.69 0.33 mg/kg wet 1.667 101 41-114 2-Chlorophenol 1.35 0.33 mg/kg wet 1.667 81 34-121 2-Methyl naphthalene 1.35 0.33 mg/kg wet 1.667 81 38-122 2-Methylphenol 1.34 0.33 mg/kg wet 1.667 80 32-122 2-Nitrophenol 1.33 0.33 mg/kg wet 1.667 80 36-123 3,3'-Dichlorobenzidine 1.30 0.33 mg/kg wet 1.667 78 22-121 3/4-Methyl phenol 1.38 0.33 mg/kg wet 1.667 83 34-119 4,6-Dinitro-2-methylphenol 1.30 0.33 mg/kg wet 1.667 78 29-132 4-Bromophenyl phenyl ether 1.46 0.33 mg/kg wet 1.667 87 46-124 4-Chloro-3-methylphenol 1.41 0.33 mg/kg wet 1.667 84 45-122 4-Chloroaniline 1.34 0.33 mg/kg wet 1.667 80 17-106 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 56 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO175 - 3546 Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS (P5G0175-BS1) Prepared & Analyzed: 07/13/15 4-Chlorophenyl phenyl ether 1.42 0.33 mg/kg wet 1.667 85 45-121 4-Nitrophenol 1.40 0.33 mg/kg wet 1.667 84 30-132 Acenaphthene 1.42 0.33 mg/kg wet 1.667 85 40-123 Acenaphthylene 1.47 0.33 mg/kg wet 1.667 88 32-132 Anthracene 1.60 0.33 mg/kg wet 1.667 96 47-123 Azobenzene 1.54 0.33 mg/kg wet 1.667 92 39-125 Benzo(a)anthracene 1.50 0.33 mg/kg wet 1.667 90 49-126 Benzo(a)pyrene 1.58 0.33 mg/kg wet 1.667 95 45-129 Benzo(b)fluoranthene 1.58 0.33 mg/kg wet 1.667 95 45-132 Benzo(g,h,i)perylene 1.48 0.33 mg/kg wet 1.667 88 43-134 Benzo(k)fluoranthene 1.51 0.33 mg/kg wet 1.667 91 47-132 Benzoic Acid 0.843 0.33 mg/kg wet 1.667 51 10-83 Benzyl alcohol 1.25 0.33 mg/kg wet 1.667 75 29-122 bis(2-Chloroethoxy)methane 1.22 0.33 mg/kg wet 1.667 73 36-121 Bis(2-Chloroethyl)ether 1.01 0.33 mg/kg wet 1.667 60 31-120 Bis(2-chloroisopropyl)ether 1.20 0.33 mg/kg wet 1.667 72 33-131 Bis(2-Ethylhexyl)phthalate 1.62 0.33 mg/kg wet 1.667 97 51-133 Butyl benzyl phthalate 1.55 0.33 mg/kg wet 1.667 93 48-132 Chrysene 1.52 0.33 mg/kg wet 1.667 91 50-124 Dibenzo(a,h)anthracene 1.44 0.33 mg/kg wet 1.667 86 45-134 Dibenzofuran 1.52 0.33 mg/kg wet 1.667 91 44-120 Diethyl phthalate 1.60 0.33 mg/kg wet 1.667 96 50-124 Dimethyl phthalate 1.56 0.33 mg/kg wet 1.667 94 48-124 Di-n-butyl phthalate 1.72 0.33 mg/kg wet 1.667 103 51-128 Di-n-octyl phthalate 1.65 0.33 mg/kg wet 1.667 99 45-140 Fluoranthene 1.58 0.33 mg/kg wet 1.667 95 50-127 Fluorene 1.50 0.33 mg/kg wet 1.667 90 43-125 Hexachlorobenzene 1.54 0.33 mg/kg wet 1.667 93 45-122 Hexachlorobutadiene 1.29 0.33 mg/kg wet 1.667 78 32-123 Hexachlorocyclopentadiene 1.20 0.33 mg/kg wet 1.667 72 32-117 Hexachloroethane 1.18 0.33 mg/kg wet 1.667 71 28-117 Indeno(1,2,3-cd)pyrene 1.40 0.33 mg/kg wet 1.667 84 45-133 Isophorone 1.38 0.33 mg/kg wet 1.667 83 30-122 Naphthalene 1.29 0.33 mg/kg wet 1.667 77 35-123 Nitrobenzene 1.31 0.33 mg/kg wet 1.667 79 34-122 N-Nitroso-di-n-propylamine 1.30 0.33 mg/kg wet 1.667 78 36-120 N-Nitrosodiphenylamine 1.52 0.33 mg/kg wet 1.667 91 38-127 Pentachlorophenol 1.30 0.33 mg/kg wet 1.667 78 25-133 Phenanthrene 1.61 0.33 mg/kg wet 1.667 96 50-121 Phenol 1.33 0.33 mg/kg wet 1.667 80 34-121 Pyrene 1.55 0.33 mg/kg wet 1.667 93 47-127 Surrogate: 2,4,6-Tribromophenol 2.95 mg/kg wet 3.333 89 39-132 Surrogate: 2-Fluorobiphenyl 1.42 mg/kg wet 1,667 85 44-115 Surrogate: 2-Fluorophenol 2.75 mg/kg wet 3.333 83 35-115 Surrogate: Nitrobenzene-d5 1.27 mg/kg wet 1.667 76 37-122 Surrogate: Phenol-d5 2.66 mg/kg wet 3,333 80 34-121 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 57 of 80 P R I IS M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO175 - 3546 Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS (P51130175-113SI) Prepared & Analyzed: 07/13/15 Surrogate: Terphenyl-,114 1.47 mg/kg wet 1.667 88 54-127 LCS Dup (P5G0175-BSD1) Prepared & Analyzed: 07/13/15 1,2,4-Trichlorobenzene 1.39 0.33 mg/kg wet 1.667 83 34-118 5 20 1,2-Dichlorobenzene 1.27 0.33 mg/kg wet 1.667 76 33-117 4 20 1,3-Dichlorobenzene 1.22 0.33 mg/kg wet 1.667 73 30-115 5 20 1,4-Dichlorobenzene 1.23 0.33 mg/kg wet 1.667 74 31-115 4 20 1-Methyl naphthalene 1.47 0.33 mg/kg wet 1.667 88 40-119 9 20 2,4,6-Trichlorophenol 1.71 0.33 mg/kg wet 1.667 102 39-126 15 20 2,4-Dichlorophenol 1.54 0.33 mg/kg wet 1.667 93 40-122 8 20 2,4-Dimethylphenol 1.56 0.33 mg/kg wet 1.667 94 30-127 10 20 2,4-Dinitrophenol 1.53 0.33 mg/kg wet 1.667 92 27-129 37 20 D 2,4-Dinitrotoluene 1.98 0.33 mg/kg wet 1.667 119 48-126 22 20 D 2,6-Dinitrotoluene 1.87 0.33 mg/kg wet 1.667 112 46-124 18 20 2-Chloronaphthalene 1.86 0.33 mg/kg wet 1.667 111 41-114 9 20 2-Chlorophenol 1.39 0.33 mg/kg wet 1.667 83 34-121 3 20 2-Methyl naphthalene 1.46 0.33 mg/kg wet 1.667 87 38-122 7 20 2-Methylphenol 1.46 0.33 mg/kg wet 1.667 87 32-122 9 20 2-Nitrophenol 1.45 0.33 mg/kg wet 1.667 87 36-123 9 20 3,3'-Dichlorobenzidine 1.63 0.33 mg/kg wet 1.667 98 22-121 22 20 D 3/4-Methyl phenol 1.52 0.33 mg/kg wet 1.667 91 34-119 9 20 4,6-Dinitro-2-methylphenol 1.67 0.33 mg/kg wet 1.667 100 29-132 24 20 D 4-Bromophenyl phenyl ether 1.69 0.33 mg/kg wet 1.667 102 46-124 15 20 4-Chloro-3-methylphenol 1.65 0.33 mg/kg wet 1.667 99 45-122 16 20 4-Chloroaniline 1.48 0.33 mg/kg wet 1.667 89 17-106 10 20 4-Chlorophenyl phenyl ether 1.63 0.33 mg/kg wet 1.667 98 45-121 14 20 4-Nitrophenol 1.75 0.33 mg/kg wet 1.667 105 30-132 22 20 D Acenaphthene 1.61 0.33 mg/kg wet 1.667 97 40-123 13 20 Acenaphthylene 1.66 0.33 mg/kg wet 1.667 99 32-132 12 20 Anthracene 1.88 0.33 mg/kg wet 1.667 113 47-123 16 20 Azobenzene 1.80 0.33 mg/kg wet 1.667 108 39-125 15 20 Benzo(a)anthracene 1.83 0.33 mg/kg wet 1.667 110 49-126 20 20 Benzo(a)pyrene 1.92 0.33 mg/kg wet 1.667 115 45-129 19 20 Benzo(b)fluoranthene 1.89 0.33 mg/kg wet 1.667 114 45-132 18 20 Benzo(g,h,i)perylene 1.83 0.33 mg/kg wet 1.667 110 43-134 21 20 D Benzo(k)fluoranthene 1.90 0.33 mg/kg wet 1.667 114 47-132 23 20 D Benzoic Acid 1.08 0.33 mg/kg wet 1.667 65 10-83 25 20 D Benzyl alcohol 1.37 0.33 mg/kg wet 1.667 82 29-122 9 20 bis(2-Chloroethoxy)methane 1.33 0.33 mg/kg wet 1.667 80 36-121 8 20 Bis(2-Chloroethyl)ether 1.15 0.33 mg/kg wet 1.667 69 31-120 13 20 Bis(2-chloroisopropyl)ether 1.26 0.33 mg/kg wet 1.667 75 33-131 5 20 Bis(2-Ethylhexyl)phthalate 1.95 0.33 mg/kg wet 1.667 117 51-133 19 20 Butyl benzyl phthalate 1.90 0.33 mg/kg wet 1.667 114 48-132 20 20 Chrysene 1.84 0.33 mg/kg wet 1.667 111 50-124 19 20 Dibenzo(a,h)anthracene 1.80 0.33 mg/kg wet 1.667 108 45-134 22 20 D Dibenzofuran 1.74 0.33 mg/kg wet 1.667 105 44-120 13 20 Diethyl phthalate 1.91 0.33 mg/kg wet 1.667 114 50-124 17 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 58 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO175 - 3546 Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS Dup (P5G0175-BSD1) Prepared & Analyzed: 07/13/15 Dimethyl phthalate 1.86 0.33 mg/kg wet 1.667 ill 48-124 17 20 Di-n-butyl phthalate 2.04 0.33 mg/kg wet 1.667 122 51-128 17 20 Di-n-octyl phthalate 2.03 0.33 mg/kg wet 1.667 122 45-140 21 20 D Fluoranthene 1.89 0.33 mg/kg wet 1.667 114 50-127 18 20 Fluorene 1.76 0.33 mg/kg wet 1.667 105 43-125 16 20 Hexachlorobenzene 1.84 0.33 mg/kg wet 1.667 ill 45-122 18 20 Hexachlorobutadiene 1.39 0.33 mg/kg wet 1.667 84 32-123 8 20 Hexachlorocyclopentadiene 1.27 0.33 mg/kg wet 1.667 76 32-117 6 20 Hexachloroethane 1.22 0.33 mg/kg wet 1.667 73 28-117 3 20 Indeno(1,2,3-cd)pyrene 1.70 0.33 mg/kg wet 1.667 102 45-133 19 20 Isophorone 1.53 0.33 mg/kg wet 1.667 92 30-122 10 20 Naphthalene 1.36 0.33 mg/kg wet 1.667 81 35-123 5 20 Nitrobenzene 1.39 0.33 mg/kg wet 1.667 83 34-122 6 20 N-Nitroso-di-n-propylamine 1.42 0.33 mg/kg wet 1.667 85 36-120 8 20 N-Nitrosodiphenylamine 1.79 0.33 mg/kg wet 1.667 107 38-127 16 20 Pentachlorophenol 1.59 0.33 mg/kg wet 1.667 95 25-133 20 20 Phenanthrene 1.92 0.33 mg/kg wet 1.667 115 50-121 18 20 Phenol 1.40 0.33 mg/kg wet 1.667 84 34-121 5 20 Pyrene 1.88 0.33 mg/kg wet 1.667 113 47-127 20 20 Surrogate: 2,4,6-Tribromophenol 3.59 mg/kg wet 3.333 108 39-132 Surrogate: 2-Fluorobiphenyl 1.56 mg/kg wet 1.667 93 44-115 Surrogate: 2-Fluorophenol 2.84 mg/kg wet 3.333 85 35-115 Surrogate: Nitrobenzene-d5 1.34 mg/kg wet 1.667 80 37-122 Surrogate: Phenol-d5 2.81 mg/kg wet 3.333 84 34-121 Surrogate: Terphenyl-d14 1.77 mg/kg wet 1.667 106 54-127 Matrix Spike (P5G0175-MS1) Source: 5070165-02 Prepared: 07/13/15 Analyzed: 07/16/15 1,2,4-Trichlorobenzene 2.41 0.45 mg/kg dry 2.286 BRL 106 34-118 1,2-Dichlorobenzene 2.03 0.45 mg/kg dry 2.286 BRL 89 33-117 1,3-Dichlorobenzene 1.93 0.45 mg/kg dry 2.286 BRL 85 30-115 1,4-Dichlorobenzene 1.96 0.45 mg/kg dry 2.286 BRL 86 31-115 1-Methyl naphthalene 2.60 0.45 mg/kg dry 2.286 BRL 114 40-119 2,4,6-Trichlorophenol 2.83 0.45 mg/kg dry 2.286 BRL 124 39-126 2,4-Dichlorophenol 2.63 0.45 mg/kg dry 2.286 BRL 115 40-122 2,4-Dimethylphenol 2.35 0.45 mg/kg dry 2.286 BRL 103 30-127 2,4-Dinitrophenol 1.96 0.45 mg/kg dry 2.286 BRL 86 27-129 2,4-Dinitrotoluene 2.86 0.45 mg/kg dry 2.286 BRL 125 48-126 2,6-Dinitrotoluene 2.87 0.45 mg/kg dry 2.286 BRL 126 46-124 M 2-Chloronaphthalene 3.24 0.45 mg/kg dry 2.286 BRL 142 41-114 M 2-Chlorophenol 2.30 0.45 mg/kg dry 2.286 BRL 101 34-121 2-Methyl naphthalene 2.63 0.45 mg/kg dry 2.286 BRL 115 38-122 2-Methylphenol 2.43 0.45 mg/kg dry 2.286 BRL 106 32-122 2-Nitrophenol 2.36 0.45 mg/kg dry 2.286 BRL 103 36-123 3,3'-Dichlorobenzidine 1.54 0.45 mg/kg dry 2.286 BRL 67 22-121 3/4-Methyl phenol 2.43 0.45 mg/kg dry 2.286 BRL 106 34-119 4,6-Dinitro-2-methylphenol 2.29 0.45 mg/kg dry 2.286 BRL 100 29-132 4-Bromophenyl phenyl ether 2.73 0.45 mg/kg dry 2.286 BRL 120 46-124 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 59 of 80 P R I IS M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Batch P5GO175 - 3546 Matrix Spike (P5G0175-MS1) Source: 5070165-02 Prepared: 07/13/15 Analyzed: 07/16/15 4-Chloro-3-methyl phenol 2.81 0.45 mg/kg dry 2.286 BRL 123 45-122 M 4-Chloroaniline 3.00 0.45 mg/kg dry 2.286 BRL 131 17-106 M 4-Chlorophenyl phenyl ether 2.66 0.45 mg/kg dry 2.286 BRL 116 45-121 4-Nitrophenol 2.84 0.45 mg/kg dry 2.286 BRL 124 30-132 Acenaphthene 2.71 0.45 mg/kg dry 2.286 BRL 119 40-123 Acenaphthylene 2.73 0.45 mg/kg dry 2.286 BRL 120 32-132 Anthracene 3.05 0.45 mg/kg dry 2.286 BRL 134 47-123 M Azobenzene 2.89 0.45 mg/kg dry 2.286 BRL 126 39-125 M Benzo(a)anthracene 3.34 0.45 mg/kg dry 2.286 0.235 136 49-126 M Benzo(a)pyrene 3.59 0.45 mg/kg dry 2.286 0.292 144 45-129 M Benzo(b)fluoranthene 3.66 0.45 mg/kg dry 2.286 0.440 141 45-132 M Benzo(g,h,i)perylene 3.40 0.45 mg/kg dry 2.286 0.250 138 43-134 M Benzo(k)fluoranthene 3.28 0.45 mg/kg dry 2.286 0.117 138 47-132 M Benzoic Acid 1.42 0.45 mg/kg dry 2.286 BRL 62 10-83 Benzyl alcohol 2.27 0.45 mg/kg dry 2.286 BRL 99 29-122 bis(2-Chloroethoxy)methane 2.29 0.45 mg/kg dry 2.286 BRL 100 36-121 Bis(2-Chloroethyl)ether 1.99 0.45 mg/kg dry 2.286 BRL 87 31-120 Bis(2-chloroisopropyl)ether 2.12 0.45 mg/kg dry 2.286 BRL 93 33-131 Bis(2-Ethylhexyl)phthalate 3.21 0.45 mg/kg dry 2.286 0.116 135 51-133 M Butyl benzyl phthalate 3.07 0.45 mg/kg dry 2.286 BRL 134 48-132 M Chrysene 3.43 0.45 mg/kg dry 2.286 0.284 137 50-124 M Dibenzo(a,h)anthracene 3.04 0.45 mg/kg dry 2.286 BRL 133 45-134 Dibenzofuran 2.87 0.45 mg/kg dry 2.286 BRL 126 44-120 M Diethyl phthalate 2.93 0.45 mg/kg dry 2.286 BRL 128 50-124 M Dimethyl phthalate 2.86 0.45 mg/kg dry 2.286 BRL 125 48-124 M Di-n-butyl phthalate 3.06 0.45 mg/kg dry 2.286 BRL 134 51-128 M Di-n-octyl phthalate 3.20 0.45 mg/kg dry 2.286 BRL 140 45-140 Fluoranthene 3.89 0.45 mg/kg dry 2.286 0.540 146 50-127 M Fluorene 2.90 0.45 mg/kg dry 2.286 BRL 127 43-125 M Hexachlorobenzene 2.91 0.45 mg/kg dry 2.286 BRL 127 45-122 M Hexachlorobutadiene 2.32 0.45 mg/kg dry 2.286 BRL 102 32-123 Hexachlorocyclopentadiene 1.39 0.45 mg/kg dry 2.286 BRL 61 32-117 Hexachloroethane 2.00 0.45 mg/kg dry 2.286 BRL 87 28-117 Indeno(1,2,3-cd)pyrene 3.31 0.45 mg/kg dry 2.286 0.221 135 45-133 M Isophorone 2.57 0.45 mg/kg dry 2.286 BRL 112 30-122 Naphthalene 2.55 0.45 mg/kg dry 2.286 BRL 112 35-123 Nitrobenzene 2.33 0.45 mg/kg dry 2.286 BRL 102 34-122 N-Nitroso-di-n-propylamine 2.29 0.45 mg/kg dry 2.286 BRL 100 36-120 N-Nitrosodiphenylamine 2.85 0.45 mg/kg dry 2.286 BRL 125 38-127 Pentachlorophenol 2.67 0.45 mg/kg dry 2.286 BRL 117 25-133 Phenanthrene 3.69 0.45 mg/kg dry 2.286 0.307 148 50-121 M Phenol 2.37 0.45 mg/kg dry 2.286 BRL 104 34-121 Pyrene 3.98 0.45 mg/kg dry 2.286 0.502 152 47-127 M Surrogate: 2,4,6-Tribromophenol 5.61 mg/kg dry 4.572 123 39-132 Surrogate: 2-Fluorobiphenyl 2.63 mg/kg dry 2.286 115 44-115 Surrogate: 2-Fluorophenol 4.52 mg/kg dry 4.572 99 35-115 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 60 of 80 P R I IS M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Batch P51130175 - 3546 Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Matrix Spike (P5G0175-MS1) Source: 5070165-02 Prepared: 07/13/15 Analyzed: 07/16/15 Surrogate: Nitrobenzene-d5 2.17 mg/kg dry 2.286 95 37-122 Surrogate: Phenol-d5 4.71 mg/kg dry 4.572 103 34-121 Surrogate: Terphenyl-d14 2.83 mg/kg dry 2.286 124 54-127 Matrix Spike Dup (P5GO175-MSD1) Source: 5070165-02 Prepared: 07/13/15 Analyzed: 07/16/15 1,2,4-Trichlorobenzene 2.40 0.45 mg/kg dry 2.286 BRL 105 34-118 0.3 20 1,2-Dichlorobenzene 2.15 0.45 mg/kg dry 2.286 BRL 94 33-117 6 20 1,3-Dichlorobenzene 2.05 0.45 mg/kg dry 2.286 BRL 90 30-115 6 20 1,4-Dichlorobenzene 2.07 0.45 mg/kg dry 2.286 BRL 91 31-115 6 20 1-Methyl naphthalene 2.55 0.45 mg/kg dry 2.286 BRL ill 40-119 2 20 2,4,6-Trichlorophenol 2.81 0.45 mg/kg dry 2.286 BRL 123 39-126 0.6 20 2,4-Dichlorophenol 2.57 0.45 mg/kg dry 2.286 BRL 113 40-122 2 20 2,4-Dimethylphenol 2.25 0.45 mg/kg dry 2.286 BRL 99 30-127 4 20 2,4-Dinitrophenol 2.28 0.45 mg/kg dry 2.286 BRL 100 27-129 15 20 2,4-Dinitrotoluene 2.92 0.45 mg/kg dry 2.286 BRL 128 48-126 2 20 M 2,6-Dinitrotoluene 2.84 0.45 mg/kg dry 2.286 BRL 124 46-124 0.9 20 2-Chloronaphthalene 3.14 0.45 mg/kg dry 2.286 BRL 137 41-114 3 20 M 2-Chlorophenol 2.36 0.45 mg/kg dry 2.286 BRL 103 34-121 3 20 2-Methyl naphthalene 2.58 0.45 mg/kg dry 2.286 BRL 113 38-122 2 20 2-Methylphenol 2.35 0.45 mg/kg dry 2.286 BRL 103 32-122 3 20 2-Nitrophenol 2.42 0.45 mg/kg dry 2.286 BRL 106 36-123 2 20 3,3'-Dichlorobenzidine 1.88 0.45 mg/kg dry 2.286 BRL 82 22-121 20 20 3/4-Methyl phenol 2.41 0.45 mg/kg dry 2.286 BRL 106 34-119 0.7 20 4,6-Dinitro-2-methylphenol 2.43 0.45 mg/kg dry 2.286 BRL 106 29-132 6 20 4-Bromophenyl phenyl ether 2.70 0.45 mg/kg dry 2.286 BRL 118 46-124 1 20 4-Chloro-3-methylphenol 2.72 0.45 mg/kg dry 2.286 BRL 119 45-122 3 20 4-Chloroaniline 2.88 0.45 mg/kg dry 2.286 BRL 126 17-106 4 20 M 4-Chlorophenyl phenyl ether 2.63 0.45 mg/kg dry 2.286 BRL 115 45-121 1 20 4-Nitrophenol 3.00 0.45 mg/kg dry 2.286 BRL 131 30-132 5 20 Acenaphthene 2.65 0.45 mg/kg dry 2.286 BRL 116 40-123 2 20 Acenaphthylene 2.68 0.45 mg/kg dry 2.286 BRL 117 32-132 2 20 Anthracene 3.01 0.45 mg/kg dry 2.286 BRL 132 47-123 1 20 M Azobenzene 2.81 0.45 mg/kg dry 2.286 BRL 123 39-125 3 20 Benzo(a)anthracene 3.19 0.45 mg/kg dry 2.286 0.235 129 49-126 5 20 M Benzo(a)pyrene 3.46 0.45 mg/kg dry 2.286 0.292 138 45-129 4 20 M Benzo(b)fluoranthene 3.55 0.45 mg/kg dry 2.286 0.440 136 45-132 3 20 M Benzo(g,h,i)perylene 3.32 0.45 mg/kg dry 2.286 0.250 134 43-134 2 20 Benzo(k)fluoranthene 3.11 0.45 mg/kg dry 2.286 0.117 131 47-132 5 20 Benzoic Acid 1.67 0.45 mg/kg dry 2.286 BRL 73 10-83 17 20 Benzyl alcohol 2.32 0.45 mg/kg dry 2.286 BRL 102 29-122 2 20 bis(2-Chloroethoxy)methane 2.23 0.45 mg/kg dry 2.286 BRL 98 36-121 3 20 Bis(2-Chloroethyl)ether 2.15 0.45 mg/kg dry 2.286 BRL 94 31-120 8 20 Bis(2-chloroisopropyl)ether 2.18 0.45 mg/kg dry 2.286 BRL 95 33-131 3 20 Bis(2-Ethylhexyl)phthalate 3.35 0.45 mg/kg dry 2.286 0.116 141 51-133 4 20 M Butyl benzyl phthalate 2.97 0.45 mg/kg dry 2.286 BRL 130 48-132 3 20 Chrysene 3.29 0.45 mg/kg dry 2.286 0.284 131 50-124 4 20 M Dibenzo(a,h)anthracene 2.98 0.45 mg/kg dry 2.286 BRL 130 45-134 2 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 61 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Reporting Analyte Result Limit Units Batch P5GO175 - 3546 Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Matrix Spike Dup (P5G0175-MSD1) Source: 5070165-02 Prepared: 07/13/15 Analyzed: 07/16/15 Dibenzofuran 2.79 0.45 mg/kg dry 2.286 BRL 122 44-120 3 20 M Diethyl phthalate 2.89 0.45 mg/kg dry 2.286 BRL 127 50-124 1 20 M Dimethyl phthalate 2.83 0.45 mg/kg dry 2.286 BRL 124 48-124 1 20 Di-n-butyl phthalate 3.10 0.45 mg/kg dry 2.286 BRL 135 51-128 1 20 M Di-n-octyl phthalate 3.18 0.45 mg/kg dry 2.286 BRL 139 45-140 0.5 20 Fluoranthene 3.67 0.45 mg/kg dry 2.286 0.540 137 50-127 6 20 M Fluorene 2.80 0.45 mg/kg dry 2.286 BRL 123 43-125 3 20 Hexachlorobenzene 2.94 0.45 mg/kg dry 2.286 BRL 128 45-122 0.8 20 M Hexachlorobutadiene 2.38 0.45 mg/kg dry 2.286 BRL 104 32-123 2 20 Hexachlorocyclopentadiene 1.66 0.45 mg/kg dry 2.286 BRL 73 32-117 17 20 Hexachloroethane 2.14 0.45 mg/kg dry 2.286 BRL 94 28-117 7 20 Indeno(1,2,3-cd)pyrene 3.25 0.45 mg/kg dry 2.286 0.221 133 45-133 2 20 Isophorone 2.51 0.45 mg/kg dry 2.286 BRL 110 30-122 2 20 Naphthalene 2.53 0.45 mg/kg dry 2.286 BRL ill 35-123 0.9 20 Nitrobenzene 2.31 0.45 mg/kg dry 2.286 BRL 101 34-122 0.8 20 N-Nitroso-di-n-propylamine 2.33 0.45 mg/kg dry 2.286 BRL 102 36-120 2 20 N-Nitrosodiphenylamine 2.80 0.45 mg/kg dry 2.286 BRL 122 38-127 2 20 Pentachlorophenol 2.87 0.45 mg/kg dry 2.286 BRL 126 25-133 7 20 Phenanthrene 3.45 0.45 mg/kg dry 2.286 0.307 137 50-121 7 20 M Phenol 2.34 0.45 mg/kg dry 2.286 BRL 103 34-121 1 20 Pyrene 3.72 0.45 mg/kg dry 2.286 0.502 141 47-127 7 20 M Surrogate: 2,4,6-Tribromophenol 5.63 mg/kg dry 4.572 123 39-132 Surrogate: 2-Fluorobiphenyl 2.60 mg/kg dry 2.286 114 44-115 Surrogate: 2-Fluorophenol 4.51 mg/kg dry 4.572 99 35-115 Surrogate: Nitrobenzene-d5 2.20 mg/kg dry 2.286 96 37-122 Surrogate: Phenol-d5 4.64 mg/kg dry 4.572 102 34-121 Surrogate: Terphenyl-d14 2.77 mg/kg dry 2.286 121 54-127 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 62 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO184 - 3510C MS Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Blank (P5G0184-BLK1) Prepared & Analyzed: 07/14/15 1,2,4-Trichlorobenzene BRL 10 ug/L 1,2-Dichlorobenzene BRL 10 ug/L 1,3-Dichlorobenzene BRL 10 ug/L 1,4-Dichlorobenzene BRL 10 ug/L 1-Methyl naphthalene BRL 10 ug/L 2,4,5-Trichlorophenol BRL 10 ug/L 2,4,6-Trichlorophenol BRL 10 ug/L 2,4-Dichlorophenol BRL 10 ug/L 2,4-Dimethylphenol BRL 10 ug/L 2,4-Dinitrophenol BRL 10 ug/L 2,4-Dinitrotoluene BRL 10 ug/L 2,6-Dinitrotoluene BRL 10 ug/L 2-Chloronaphthalene BRL 10 ug/L 2-Chlorophenol BRL 10 ug/L 2-Methyl naphthalene BRL 10 ug/L 2-Methylphenol BRL 10 ug/L 2-Nitroaniline BRL 10 ug/L 2-Nitrophenol BRL 10 ug/L 3,3'-Dichlorobenzidine BRL 10 ug/L 3/4-Methyl phenol BRL 10 ug/L 3-Nitroaniline BRL 10 ug/L 4,6-Dinitro-2-methylphenol BRL 10 ug/L 4-Bromophenyl phenyl ether BRL 10 ug/L 4-Chloro-3-methylphenol BRL 10 ug/L 4-Chloroaniline BRL 10 ug/L 4-Chlorophenyl phenyl ether BRL 10 ug/L 4-Nitroaniline BRL 10 ug/L 4-Nitrophenol BRL 10 ug/L Acenaphthene BRL 10 ug/L Acenaphthylene BRL 10 ug/L Aniline BRL 10 ug/L Anthracene BRL 10 ug/L Azobenzene BRL 10 ug/L Benzo(a)anthracene BRL 10 ug/L Benzo(a)pyrene BRL 10 ug/L Benzo(b)fluoranthene BRL 10 ug/L Benzo(g,h,i)perylene BRL 10 ug/L Benzo(k)fluoranthene BRL 10 ug/L Benzoic Acid BRL 100 ug/L Benzyl alcohol BRL 10 ug/L bis(2-Chloroethoxy)methane BRL 10 ug/L Bis(2-Chloroethyl)ether BRL 10 ug/L Bis(2-chloroisopropyl)ether BRL 10 ug/L Bis(2-Ethylhexyl)phthalate BRL 10 ug/L Butyl benzyl phthalate BRL 10 ug/L Chrysene BRL 10 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 63 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Prism Work Order: 5070165 Attn: Aaron Oswald Time Submitted: 7/10/2015 8:50:OOAM 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO184 - 3510C MS Blank (P5G0184-BLK1) Prepared & Analyzed: 07/14/15 Dibenzo(a,h)anthracene BRL 10 ug/L Dibenzofuran BRL 10 ug/L Diethyl phthalate BRL 10 ug/L Dimethyl phthalate BRL 10 ug/L Di-n-butyl phthalate BRL 10 ug/L Di-n-octyl phthalate BRL 10 ug/L Fluoranthene BRL 10 ug/L Fluorene BRL 10 ug/L Hexachlorobenzene BRL 10 ug/L Hexachlorobutadiene BRL 10 ug/L Hexachlorocyclopentadiene BRL 10 ug/L Hexachloroethane BRL 10 ug/L Indeno(1,2,3-cd)pyrene BRL 10 ug/L Isophorone BRL 10 ug/L Naphthalene BRL 10 ug/L Nitrobenzene BRL 10 ug/L N-Nitroso-di-n-propylamine BRL 10 ug/L N-Nitrosodiphenylamine BRL 10 ug/L Pentachlorophenol BRL 10 ug/L Phenanthrene BRL 10 ug/L Phenol BRL 10 ug/L Pyrene BRL 10 ug/L Surrogate: 2,4,6-Tribromophenol 117 ug/L 100.0 117 49-109 SR Surrogate:2-Fluorobiphenyl 55.4 ug/L 50.00 111 55-96 SR Surrogate:2-Fluorophenol 65.6 ug/L 100.0 66 27-74 Surrogate: Nitrobenzene-d5 53.4 ug/L 50.00 107 53-99 SR Surrogate: Phenol-d5 43.8 ug/L 100.0 44 11-52 Surrogate: Terphenyl-d14 54.2 ug/L 50.00 108 42-133 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 64 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO184 - 3510C MS Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS (P5G0184-BS1) Prepared & Analyzed: 07/14/15 1,2,4-Trichlorobenzene 46.8 10 ug/L 50.00 94 45-103 1,2-Dichlorobenzene 45.3 10 ug/L 50.00 91 43-100 1,3-Dichlorobenzene 44.2 10 ug/L 50.00 88 42-98 1,4-Dichlorobenzene 44.2 10 ug/L 50.00 88 42-100 1-Methyl naphthalene 48.0 10 ug/L 50.00 96 45-135 2,4,5-Trichlorophenol 52.9 10 ug/L 50.00 106 66-120 2,4,6-Trichlorophenol 52.8 10 ug/L 50.00 106 62-121 2,4-Dichlorophenol 49.5 10 ug/L 50.00 99 58-113 2,4-Dimethylphenol 47.6 10 ug/L 50.00 95 42-120 2,4-Dinitrophenol 49.3 10 ug/L 50.00 99 27-129 2,4-Dinitrotoluene 59.4 10 ug/L 50.00 119 62-136 2,6-Dinitrotoluene 57.7 10 ug/L 50.00 115 64-129 2-Chloronaphthalene 60.0 10 ug/L 50.00 120 38-141 2-Chlorophenol 45.8 10 ug/L 50.00 92 49-107 2-Methyl naphthalene 48.2 10 ug/L 50.00 96 55-112 2-Methylphenol 40.8 10 ug/L 50.00 82 40-106 2-Nitroaniline 51.2 10 ug/L 50.00 102 65-122 2-Nitrophenol 49.4 10 ug/L 50.00 99 57-115 3,3'-Dichlorobenzidine 67.9 10 ug/L 50.00 136 58-139 3/4-Methyl phenol 39.0 10 ug/L 50.00 78 34-101 3-Nitroaniline 63.0 10 ug/L 50.00 126 52-155 4,6-Dinitro-2-methylphenol 55.5 10 ug/L 50.00 111 49-138 4-Bromophenyl phenyl ether 51.9 10 ug/L 50.00 104 63-135 4-Chloro-3-methylphenol 52.2 10 ug/L 50.00 104 33-149 4-Chloroaniline 72.8 10 ug/L 50.00 146 44-163 4-Chlorophenyl phenyl ether 51.0 10 ug/L 50.00 102 63-129 4-Nitroaniline 55.5 10 ug/L 50.00 111 63-147 4-Nitrophenol 23.7 10 ug/L 50.00 47 10-77 Acenaphthene 49.6 10 ug/L 50.00 99 64-118 Acenaphthylene 50.8 10 ug/L 50.00 102 65-119 Aniline 70.6 10 ug/L 50.00 141 12-197 Anthracene 52.9 10 ug/L 50.00 106 69-134 Azobenzene 54.4 10 ug/L 50.00 109 56-129 Benzo(a)anthracene 53.3 10 ug/L 50.00 107 71-125 Benzo(a)pyrene 59.4 10 ug/L 50.00 119 67-135 Benzo(b)fluoranthene 56.9 10 ug/L 50.00 114 56-145 Benzo(g,h,i)perylene 56.9 10 ug/L 50.00 114 44-149 Benzo(k)fluoranthene 56.4 10 ug/L 50.00 113 65-138 Benzoic Acid 14.0 100 ug/L 50.00 28 10-125 Benzyl alcohol 41.1 10 ug/L 50.00 82 35-111 bis(2-Chloroethoxy)methane 46.6 10 ug/L 50.00 93 49-126 Bis(2-Chloroethyl)ether 45.6 10 ug/L 50.00 91 47-124 Bis(2-chloroisopropyl)ether 46.6 10 ug/L 50.00 93 42-126 Bis(2-Ethylhexyl)phthalate 59.0 10 ug/L 50.00 118 59-139 Butyl benzyl phthalate 58.5 10 ug/L 50.00 117 67-133 Chrysene 55.1 10 ug/L 50.00 110 64-124 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 65 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO184 - 3510C MS Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS (M0184-BS1) Prepared & Analyzed: 07/14/15 Dibenzo(a,h)anthracene 55.6 10 ug/L 50.00 ill 49-144 Dibenzofuran 53.7 10 ug/L 50.00 107 68-113 Diethyl phthalate 58.9 10 ug/L 50.00 118 70-124 Dimethyl phthalate 57.8 10 ug/L 50.00 116 71-117 Di-n-butyl phthalate 59.7 10 ug/L 50.00 119 69-128 Di-n-octyl phthalate 61.5 10 ug/L 50.00 123 52-150 Fluoranthene 55.4 10 ug/L 50.00 ill 66-135 Fluorene 54.7 10 ug/L 50.00 109 67-124 Hexachlorobenzene 55.5 10 ug/L 50.00 ill 62-124 Hexachlorobutadiene 45.3 10 ug/L 50.00 91 42-105 Hexachlorocyclopentadiene 46.6 10 ug/L 50.00 93 32-117 Hexachloroethane 43.8 10 ug/L 50.00 88 40-99 Indeno(1,2,3-cd)pyrene 56.7 10 ug/L 50.00 113 40-150 Isophorone 53.0 10 ug/L 50.00 106 54-125 Naphthalene 45.3 10 ug/L 50.00 91 54-111 Nitrobenzene 49.9 10 ug/L 50.00 100 51-117 N-Nitroso-di-n-propylamine 49.6 10 ug/L 50.00 99 55-115 N-Nitrosodiphenylamine 54.3 10 ug/L 50.00 109 70-152 Pentachlorophenol 54.6 10 ug/L 50.00 109 23-139 Phenanthrene 55.7 10 ug/L 50.00 ill 68-128 Phenol 23.1 10 ug/L 50.00 46 12-58 Pyrene 54.5 10 ug/L 50.00 109 62-139 Surrogate: 2,4,6-Tribromophenol 124 ug/L 100.0 124 49-109 SR Surrogate:2-Fluorobiphenyl 54.8 ug/L 50.00 110 55-96 SR Surrogate:2-Fluorophenol 67.8 ug/L 100.0 68 27-74 Surrogate: Nitrobenzene-d5 52.3 ug/L 50.00 105 53-99 SR Surrogate: Phenol-d5 44.3 ug/L 100.0 44 11-52 Surrogate: Terphenyl-d14 57.8 ug/L 50.00 116 42-133 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 66 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO184 - 3510C MS Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS Dup (P5G0184-BSD1) Prepared & Analyzed: 07/14/15 1,2,4-Trichlorobenzene 48.8 10 ug/L 50.00 98 45-103 4 20 1,2-Dichlorobenzene 47.9 10 ug/L 50.00 96 43-100 6 20 1,3-Dichlorobenzene 46.9 10 ug/L 50.00 94 42-98 6 20 1,4-Dichlorobenzene 46.8 10 ug/L 50.00 94 42-100 6 20 1-Methyl naphthalene 50.5 10 ug/L 50.00 101 45-135 5 20 2,4,5-Trichlorophenol 56.1 10 ug/L 50.00 112 66-120 6 20 2,4,6-Trichlorophenol 55.0 10 ug/L 50.00 110 62-121 4 20 2,4-Dichlorophenol 52.0 10 ug/L 50.00 104 58-113 5 20 2,4-Dimethylphenol 47.3 10 ug/L 50.00 95 42-120 0.7 20 2,4-Dinitrophenol 53.8 10 ug/L 50.00 108 27-129 9 20 2,4-Dinitrotoluene 61.1 10 ug/L 50.00 122 62-136 3 20 2,6-Dinitrotoluene 61.2 10 ug/L 50.00 122 64-129 6 20 2-Chloronaphthalene 62.7 10 ug/L 50.00 125 38-141 5 20 2-Chlorophenol 48.2 10 ug/L 50.00 96 49-107 5 20 2-Methyl naphthalene 50.5 10 ug/L 50.00 101 55-112 5 20 2-Methylphenol 43.0 10 ug/L 50.00 86 40-106 5 20 2-Nitroaniline 53.4 10 ug/L 50.00 107 65-122 4 20 2-Nitrophenol 52.2 10 ug/L 50.00 104 57-115 6 20 3,3'-Dichlorobenzidine 71.1 10 ug/L 50.00 142 58-139 5 20 L2 3/4-Methyl phenol 40.5 10 ug/L 50.00 81 34-101 4 20 3-Nitroaniline 65.9 10 ug/L 50.00 132 52-155 5 20 4,6-Dinitro-2-methylphenol 61.0 10 ug/L 50.00 122 49-138 9 20 4-Bromophenyl phenyl ether 55.7 10 ug/L 50.00 111 63-135 7 20 4-Chloro-3-methylphenol 55.0 10 ug/L 50.00 110 33-149 5 20 4-Chloroaniline 74.1 10 ug/L 50.00 148 44-163 2 20 4-Chlorophenyl phenyl ether 53.7 10 ug/L 50.00 107 63-129 5 20 4-Nitroaniline 57.0 10 ug/L 50.00 114 63-147 3 20 4-Nitrophenol 24.2 10 ug/L 50.00 48 10-77 2 20 Acenaphthene 52.9 10 ug/L 50.00 106 64-118 6 20 Acenaphthylene 53.8 10 ug/L 50.00 108 65-119 6 20 Aniline 83.9 10 ug/L 50.00 168 12-197 17 20 Anthracene 55.2 10 ug/L 50.00 110 69-134 4 20 Azobenzene 58.0 10 ug/L 50.00 116 56-129 6 20 Benzo(a)anthracene 55.6 10 ug/L 50.00 111 71-125 4 20 Benzo(a)pyrene 61.9 10 ug/L 50.00 124 67-135 4 20 Benzo(b)fluoranthene 59.4 10 ug/L 50.00 119 56-145 4 20 Benzo(g,h,i)perylene 60.6 10 ug/L 50.00 121 44-149 6 20 Benzo(k)fluoranthene 58.6 10 ug/L 50.00 117 65-138 4 20 Benzoic Acid 18.2 100 ug/L 50.00 36 10-125 27 20 D Benzyl alcohol 42.9 10 ug/L 50.00 86 35-111 4 20 bis(2-Chloroethoxy)methane 49.5 10 ug/L 50.00 99 49-126 6 20 Bis(2-Chloroethyl)ether 40.4 10 ug/L 50.00 81 47-124 12 20 Bis(2-chloroisopropyl)ether 48.5 10 ug/L 50.00 97 42-126 4 20 Bis(2-Ethylhexyl)phthalate 61.0 10 ug/L 50.00 122 59-139 3 20 Butyl benzyl phthalate 61.2 10 ug/L 50.00 122 67-133 5 20 Chrysene 57.4 10 ug/L 50.00 115 64-124 4 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 67 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO184 - 3510C MS Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS Dup (P5G0184-BSD1) Prepared & Analyzed: 07/14/15 Dibenzo(a,h)anthracene 59.4 10 ug/L 50.00 119 49-144 7 20 Dibenzofuran 56.5 10 ug/L 50.00 113 68-113 5 20 Diethyl phthalate 60.6 10 ug/L 50.00 121 70-124 3 20 Dimethyl phthalate 60.1 10 ug/L 50.00 120 71-117 4 20 L2 Di-n-butyl phthalate 61.6 10 ug/L 50.00 123 69-128 3 20 Di-n-octyl phthalate 63.8 10 ug/L 50.00 128 52-150 4 20 Fluoranthene 57.8 10 ug/L 50.00 116 66-135 4 20 Fluorene 57.1 10 ug/L 50.00 114 67-124 4 20 Hexachlorobenzene 58.3 10 ug/L 50.00 117 62-124 5 20 Hexachlorobutadiene 48.2 10 ug/L 50.00 96 42-105 6 20 Hexachlorocyclopentadiene 49.3 10 ug/L 50.00 99 32-117 6 20 Hexachloroethane 45.5 10 ug/L 50.00 91 40-99 4 20 Indeno(1,2,3-cd)pyrene 60.3 10 ug/L 50.00 121 40-150 6 20 Isophorone 56.3 10 ug/L 50.00 113 54-125 6 20 Naphthalene 47.7 10 ug/L 50.00 95 54-111 5 20 Nitrobenzene 52.7 10 ug/L 50.00 105 51-117 5 20 N-Nitroso-di-n-propylamine 51.2 10 ug/L 50.00 102 55-115 3 20 N-Nitrosodiphenylamine 57.1 10 ug/L 50.00 114 70-152 5 20 Pentachlorophenol 58.0 10 ug/L 50.00 116 23-139 6 20 Phenanthrene 58.4 10 ug/L 50.00 117 68-128 5 20 Phenol 23.9 10 ug/L 50.00 48 12-58 3 20 Pyrene 56.7 10 ug/L 50.00 113 62-139 4 20 Surrogate: 2,4,6-Tribromophenol 115 ug/L 100.0 115 49-109 SR Surrogate:2-Fluorobiphenyl 52.2 ug/L 50.00 104 55-96 SR Surrogate:2-Fluorophenol 64.1 ug/L 100.0 64 27-74 Surrogate: Nitrobenzene-d5 48.8 ug/L 50.00 98 53-99 Surrogate: Phenol-d5 41.7 ug/L 100.0 42 11-52 Surrogate: Terphenyl-d14 54.8 ug/L 50.00 110 42-133 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 68 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO184 - 3510C MS Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Matrix Spike (P5G0184-MS1) Source: 5070165-04 Prepared: 07/14/15 Analyzed: 07/16/15 1,2,4-Trichlorobenzene 88.0 20 ug/L 100.0 BRL 88 44-100 1,2-Dichlorobenzene 84.1 20 ug/L 100.0 BRL 84 42-99 1,3-Dichlorobenzene 81.5 20 ug/L 100.0 BRL 82 35-101 1,4-Dichlorobenzene 82.3 20 ug/L 100.0 BRL 82 43-97 1-Methyl naphthalene 95.0 20 ug/L 100.0 BRL 95 45-135 2,4,5-Trichlorophenol 108 20 ug/L 100.0 BRL 108 51-122 2,4,6-Trichlorophenol 107 20 ug/L 100.0 BRL 107 46-117 2,4-Dichlorophenol 97.5 20 ug/L 100.0 BRL 98 42-108 2,4-Dimethylphenol 91.8 20 ug/L 100.0 BRL 92 13-122 2,4-Dinitrophenol 94.0 20 ug/L 100.0 BRL 94 10-166 2,4-Dinitrotoluene 113 20 ug/L 100.0 BRL 113 64-135 2,6-Dinitrotoluene 112 20 ug/L 100.0 BRL 112 50-146 2-Chloronaphthalene 134 20 ug/L 100.0 BRL 134 46-114 M 2-Chlorophenol 87.1 20 ug/L 100.0 BRL 87 36-94 2-Methyl naphthalene 93.5 20 ug/L 100.0 BRL 94 36-115 2-Methylphenol 85.9 20 ug/L 100.0 BRL 86 27-92 2-Nitroaniline 99.8 20 ug/L 100.0 BRL 100 51-139 2-Nitrophenol 91.9 20 ug/L 100.0 BRL 92 43-108 3,3'-Dichlorobenzidine 111 20 ug/L 100.0 BRL 111 10-214 3/4-Methyl phenol 86.2 20 ug/L 100.0 BRL 86 22-84 M 3-Nitroaniline 113 20 ug/L 100.0 BRL 113 50-145 4,6-Dinitro-2-methylphenol 100 20 ug/L 100.0 BRL 100 25-152 4-Bromophenyl phenyl ether 105 20 ug/L 100.0 BRL 105 52-128 4-Chloro-3-methylphenol 102 20 ug/L 100.0 BRL 102 44-110 4-Chloroaniline 110 20 ug/L 100.0 BRL 110 10-156 4-Chlorophenyl phenyl ether 102 20 ug/L 100.0 BRL 102 55-125 4-Nitroaniline 100 20 ug/L 100.0 BRL 100 39-159 4-Nitrophenol 71.9 20 ug/L 100.0 BRL 72 10-105 Acenaphthene 104 20 ug/L 100.0 BRL 104 55-117 Acenaphthylene 104 20 ug/L 100.0 BRL 104 52-121 Aniline 100 20 ug/L 100.0 BRL 100 11-124 Anthracene 113 20 ug/L 100.0 BRL 113 60-136 Azobenzene 112 20 ug/L 100.0 BRL 112 50-135 Benzo(a)anthracene 110 20 ug/L 100.0 BRL 110 64-135 Benzo(a)pyrene 110 20 ug/L 100.0 BRL 110 68-136 Benzo(b)fluoranthene 108 20 ug/L 100.0 BRL 108 61-149 Benzo(g,h,i)perylene 105 20 ug/L 100.0 BRL 105 47-151 Benzo(k)fluoranthene 102 20 ug/L 100.0 BRL 102 45-148 Benzoic Acid 55.9 200 ug/L 100.0 BRL 56 10-125 Benzyl alcohol 84.5 20 ug/L 100.0 BRL 84 30-97 bis(2-Chloroethoxy)methane 89.9 20 ug/L 100.0 BRL 90 43-119 Bis(2-Chloroethyl)ether 74.3 20 ug/L 100.0 BRL 74 36-115 Bis(2-chloroisopropyl)ether 86.9 20 ug/L 100.0 BRL 87 36-113 Bis(2-Ethylhexyl)phthalate 114 20 ug/L 100.0 BRL 114 50-168 Butyl benzyl phthalate 118 20 ug/L 100.0 BRL 118 52-166 Chrysene 110 20 ug/L 100.0 BRL 110 62-135 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 69 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO184 - 3510C MS Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Matrix Spike (P5G0184-MS1) Source: 5070165-04 Prepared: 07/14/15 Analyzed: 07/16/15 Dibenzo(a,h)anthracene 104 20 ug/L 100.0 BRL 104 45-155 Dibenzofuran ill 20 ug/L 100.0 BRL ill 58-119 Diethyl phthalate 117 20 ug/L 100.0 BRL 117 55-137 Dimethyl phthalate 114 20 ug/L 100.0 BRL 114 46-135 Di-n-butyl phthalate 117 20 ug/L 100.0 BRL 117 53-141 Di-n-octyl phthalate 113 20 ug/L 100.0 BRL 113 48-166 Fluoranthene 110 20 ug/L 100.0 BRL 110 51-136 Fluorene 110 20 ug/L 100.0 BRL 110 57-121 Hexachlorobenzene 113 20 ug/L 100.0 BRL 113 55-131 Hexachlorobutadiene 85.0 20 ug/L 100.0 BRL 85 39-110 Hexachlorocyclopentadiene 79.7 20 ug/L 100.0 BRL 80 26-122 Hexachloroethane 78.7 20 ug/L 100.0 BRL 79 37-98 Indeno(1,2,3-cd)pyrene 103 20 ug/L 100.0 BRL 103 14-177 Isophorone 104 20 ug/L 100.0 BRL 104 49-113 Naphthalene 89.4 20 ug/L 100.0 BRL 89 38-109 Nitrobenzene 97.1 20 ug/L 100.0 BRL 97 34-117 N-Nitroso-di-n-propylamine 93.7 20 ug/L 100.0 BRL 94 44-115 N-Nitrosodiphenylamine 107 20 ug/L 100.0 BRL 107 57-156 Pentachlorophenol 110 20 ug/L 100.0 BRL 110 17-167 Phenanthrene 112 20 ug/L 100.0 BRL 112 62-131 Phenol 60.6 20 ug/L 100.0 BRL 61 10-68 Pyrene ill 20 ug/L 100.0 BRL ill 46-156 Surrogate: 2,4,6-Tribromophenol 233 ug/L 200.0 117 49-109 SR Surrogate:2-Fluorobiphenyl 109 ug/L 100.0 109 55-96 SR Surrogate:2-Fluorophenol 153 ug/L 200.0 76 27-74 SR Surrogate: Nitrobenzene-d5 93.0 ug/L 100.0 93 53-99 Surrogate: Phenol-d5 123 ug/L 200.0 61 11-52 SR Surrogate: Terphenyl-d14 110 ug/L 100.0 110 42-133 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 70 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO184 - 3510C MS Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Matrix Spike Dup (P5G0184-MSD1) Source: 5070165-04 Prepared: 07/14/15 Analyzed: 07/16/15 1,2,4-Trichlorobenzene 85.5 20 ug/L 100.0 BRL 86 44-100 3 30 1,2-Dichlorobenzene 81.3 20 ug/L 100.0 BRL 81 42-99 3 34 1,3-Dichlorobenzene 80.0 20 ug/L 100.0 BRL 80 35-101 2 36 1,4-Dichlorobenzene 81.3 20 ug/L 100.0 BRL 81 43-97 1 35 1-Methyl naphthalene 90.3 20 ug/L 100.0 BRL 90 45-135 5 50 2,4,5-Trichlorophenol 96.4 20 ug/L 100.0 BRL 96 51-122 11 22 2,4,6-Trichlorophenol 98.4 20 ug/L 100.0 BRL 98 46-117 8 30 2,4-Dichlorophenol 92.9 20 ug/L 100.0 BRL 93 42-108 5 33 2,4-Dimethylphenol 84.8 20 ug/L 100.0 BRL 85 13-122 8 36 2,4-Dinitrophenol 80.8 20 ug/L 100.0 BRL 81 10-166 15 41 2,4-Dinitrotoluene 103 20 ug/L 100.0 BRL 103 64-135 9 24 2,6-Dinitrotoluene 104 20 ug/L 100.0 BRL 104 50-146 7 28 2-Chloronaphthalene 129 20 ug/L 100.0 BRL 129 46-114 4 30 M 2-Chlorophenol 83.0 20 ug/L 100.0 BRL 83 36-94 5 37 2-Methyl naphthalene 89.4 20 ug/L 100.0 BRL 89 36-115 5 33 2-Methylphenol 81.6 20 ug/L 100.0 BRL 82 27-92 5 36 2-Nitroaniline 92.5 20 ug/L 100.0 BRL 93 51-139 8 24 2-Nitrophenol 89.5 20 ug/L 100.0 BRL 90 43-108 3 33 3,3'-Dichlorobenzidine 100 20 ug/L 100.0 BRL 100 10-214 10 34 3/4-Methyl phenol 81.3 20 ug/L 100.0 BRL 81 22-84 6 30 3-Nitroaniline 101 20 ug/L 100.0 BRL 101 50-145 12 24 4,6-Dinitro-2-methylphenol 90.4 20 ug/L 100.0 BRL 90 25-152 10 35 4-Bromophenyl phenyl ether 94.2 20 ug/L 100.0 BRL 94 52-128 11 21 4-Chloro-3-methylphenol 93.8 20 ug/L 100.0 BRL 94 44-110 9 25 4-Chloroaniline 103 20 ug/L 100.0 BRL 103 10-156 7 38 4-Chlorophenyl phenyl ether 93.8 20 ug/L 100.0 BRL 94 55-125 8 29 4-Nitroaniline 92.2 20 ug/L 100.0 BRL 92 39-159 8 29 4-Nitrophenol 68.8 20 ug/L 100.0 BRL 69 10-105 4 40 Acenaphthene 95.8 20 ug/L 100.0 BRL 96 55-117 8 33 Acenaphthylene 96.3 20 ug/L 100.0 BRL 96 52-121 8 30 Aniline 96.7 20 ug/L 100.0 BRL 97 11-124 3 35 Anthracene 99.5 20 ug/L 100.0 BRL 99 60-136 12 27 Azobenzene 101 20 ug/L 100.0 BRL 101 50-135 11 34 Benzo(a)anthracene 97.9 20 ug/L 100.0 BRL 98 64-135 11 18 Benzo(a)pyrene 98.0 20 ug/L 100.0 BRL 98 68-136 12 21 Benzo(b)fluoranthene 99.1 20 ug/L 100.0 BRL 99 61-149 9 34 Benzo(g,h,i)perylene 94.1 20 ug/L 100.0 BRL 94 47-151 11 27 Benzo(k)fluoranthene 90.2 20 ug/L 100.0 BRL 90 45-148 12 39 Benzoic Acid 42.0 200 ug/L 100.0 BRL 42 10-125 29 51 Benzyl alcohol 80.1 20 ug/L 100.0 BRL 80 30-97 5 37 bis(2-Chloroethoxy)methane 86.7 20 ug/L 100.0 BRL 87 43-119 4 30 Bis(2-Chloroethyl)ether 68.6 20 ug/L 100.0 BRL 69 36-115 8 33 Bis(2-chloroisopropyl)ether 82.9 20 ug/L 100.0 BRL 83 36-113 5 34 Bis(2-Ethylhexyl)phthalate 101 20 ug/L 100.0 BRL 101 50-168 12 21 Butyl benzyl phthalate 105 20 ug/L 100.0 BRL 105 52-166 12 23 Chrysene 98.0 20 ug/L 100.0 BRL 98 62-135 12 22 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 71 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO184 - 3510C MS Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Matrix Spike Dup (P5G0184-MSD1) Source: 5070165-04 Prepared: 07/14/15 Analyzed: 07/16/15 Dibenzo(a,h)anthracene 93.8 20 ug/L 100.0 BRL 94 45-155 11 28 Dibenzofuran 99.6 20 ug/L 100.0 BRL 100 58-119 10 23 Diethyl phthalate 105 20 ug/L 100.0 BRL 105 55-137 11 22 Dimethyl phthalate 104 20 ug/L 100.0 BRL 104 46-135 10 25 Di-n-butyl phthalate 104 20 ug/L 100.0 BRL 104 53-141 12 24 Di-n-octyl phthalate 101 20 ug/L 100.0 BRL 101 48-166 11 21 Fluoranthene 98.6 20 ug/L 100.0 BRL 99 51-136 11 26 Fluorene 99.2 20 ug/L 100.0 BRL 99 57-121 10 30 Hexachlorobenzene 101 20 ug/L 100.0 BRL 101 55-131 11 29 Hexachlorobutadiene 82.8 20 ug/L 100.0 BRL 83 39-110 3 35 Hexachlorocyclopentadiene 75.8 20 ug/L 100.0 BRL 76 26-122 5 36 Hexachloroethane 77.3 20 ug/L 100.0 BRL 77 37-98 2 37 Indeno(1,2,3-cd)pyrene 93.2 20 ug/L 100.0 BRL 93 14-177 10 34 Isophorone 97.5 20 ug/L 100.0 BRL 97 49-113 7 27 Naphthalene 87.1 20 ug/L 100.0 BRL 87 38-109 3 35 Nitrobenzene 93.1 20 ug/L 100.0 BRL 93 34-117 4 34 N-Nitroso-di-n-propylamine 86.9 20 ug/L 100.0 BRL 87 44-115 8 33 N-Nitrosodiphenylamine 95.4 20 ug/L 100.0 BRL 95 57-156 11 26 Pentachlorophenol 95.9 20 ug/L 100.0 BRL 96 17-167 14 36 Phenanthrene 102 20 ug/L 100.0 BRL 102 62-131 9 23 Phenol 58.0 20 ug/L 100.0 BRL 58 10-68 4 43 Pyrene 99.9 20 ug/L 100.0 BRL 100 46-156 11 31 Surrogate: 2,4,6-Tribromophenol 198 ug/L 200.0 99 49-109 Surrogate:2-Fluorobiphenyl 97.3 ug/L 100.0 97 55-96 SR Surrogate:2-Fluorophenol 141 ug/L 200.0 70 27-74 Surrogate: Nitrobenzene-d5 86.7 ug/L 100.0 87 53-99 Surrogate: Phenol-d5 113 ug/L 200.0 56 11-52 SR Surrogate: Terphenyl-d14 91.0 ug/L 100.0 91 42-133 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 72 of 80 P R I IS M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Total Metals - Quality Control Analyte Batch P5130170 - 3010A Project: PTR.001-3A Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Blank (P5G0170-BLK1) Prepared: 07/13/15 Analyzed: 07/14/15 Arsenic BRL 0.010 mg/L Barium BRL 0.010 mg/L Cadmium BRL 0.0010 mg/L Chromium BRL 0.0050 mg/L Lead BRL 0.0050 mg/L Selenium BRL 0.020 mg/L Silver BRL 0.0050 mg/L LCS (P5G0170-BS1) Prepared: 07/13/15 Analyzed: 07/14/15 Arsenic 0.256 0.010 mg/L 0.2500 102 80-120 Barium 0.260 0.010 mg/L 0.2500 104 80-120 Cadmium 0.256 0.0010 mg/L 0.2500 103 80-120 Chromium 0.260 0.0050 mg/L 0.2500 104 80-120 Lead 0.257 0.0050 mg/L 0.2500 103 80-120 Selenium 0.257 0.020 mg/L 0.2500 103 80-120 Silver 0.102 0.0050 mg/L 0.1000 102 80-120 Matrix Spike (P5GO170-MS1) Source: 5070165-07 Prepared: 07/13/15 Analyzed: 07/14/15 Arsenic 0.263 0.010 mg/L 0.2500 0.00218 104 75-125 Barium 0.433 0.010 mg/L 0.2500 0.188 98 75-125 Cadmium 0.244 0.0010 mg/L 0.2500 BRL 98 75-125 Chromium 0.249 0.0050 mg/L 0.2500 BRL 100 75-125 Lead 0.246 0.0050 mg/L 0.2500 0.00207 98 75-125 Selenium 0.251 0.020 mg/L 0.2500 BRL 100 75-125 Silver 0.0986 0.0050 mg/L 0.1000 BRL 99 75-125 Matrix Spike Dup (P5GO170-MSD1) Source: 5070165-07 Prepared: 07/13/15 Analyzed: 07/14/15 Arsenic 0.268 0.010 mg/L 0.2500 0.00218 106 75-125 2 20 Barium 0.442 0.010 mg/L 0.2500 0.188 101 75-125 2 20 Cadmium 0.247 0.0010 mg/L 0.2500 BRL 99 75-125 1 20 Chromium 0.254 0.0050 mg/L 0.2500 BRL 102 75-125 2 20 Lead 0.251 0.0050 mg/L 0.2500 0.00207 99 75-125 2 20 Selenium 0.256 0.020 mg/L 0.2500 BRL 102 75-125 2 20 Silver 0.100 0.0050 mg/L 0.1000 BRL 100 75-125 1 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 73 of 80 P R I IS M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Total Metals - Quality Control Analyte Batch P51130172 - 3050B Project: PTR.001-3A Reporting Result Limit Units Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Blank (P5G0172-BLK1) Prepared & Analyzed: 07/13/15 Arsenic BRL 0.25 mg/kg wet Barium BRL 0.50 mg/kg wet Cadmium BRL 0.25 mg/kg wet Chromium BRL 0.25 mg/kg wet Lead BRL 0.25 mg/kg wet Selenium BRL 0.50 mg/kg wet Silver BRL 0.25 mg/kg wet LCS (P5G0172-BS1) Prepared & Analyzed: 07/13/15 Arsenic 24.4 0.25 mg/kg wet 25.00 98 80-120 Barium 25.3 0.50 mg/kg wet 25.00 101 80-120 Cadmium 24.7 0.25 mg/kg wet 25.00 99 80-120 Chromium 25.0 0.25 mg/kg wet 25.00 100 80-120 Lead 24.4 0.25 mg/kg wet 25.00 98 80-120 Selenium 24.3 0.50 mg/kg wet 25.00 97 80-120 Silver 9.82 0.25 mg/kg wet 10.00 98 80-120 Matrix Spike (P5GO172-MS1) Source: 5070165-02 Prepared & Analyzed: 07/13/15 Arsenic 33.8 0.34 mg/kg dry 34.29 4.83 85 75-125 Barium 104 0.69 mg/kg dry 34.29 60.9 127 75-125 Cadmium 28.4 0.34 mg/kg dry 34.29 BRL 83 75-125 Chromium 66.7 0.34 mg/kg dry 34.29 28.5 112 75-125 Lead 83.5 0.34 mg/kg dry 34.29 46.5 108 75-125 Selenium 24.0 0.69 mg/kg dry 34.29 BRL 70 75-125 Silver 11.8 0.34 mg/kg dry 13.72 BRL 86 75-125 Matrix Spike Dup (P5G0172-MSD1) Source: 5070165-02 Prepared & Analyzed: 07/13/15 Arsenic 37.1 0.34 mg/kg dry 33.62 4.83 96 75-125 9 20 Barium 113 0.67 mg/kg dry 33.62 60.9 154 75-125 8 20 Cadmium 29.6 0.34 mg/kg dry 33.62 BRL 88 75-125 4 20 Chromium 92.3 0.34 mg/kg dry 33.62 28.5 190 75-125 32 20 Lead 96.2 0.34 mg/kg dry 33.62 46.5 148 75-125 14 20 Selenium 24.2 0.67 mg/kg dry 33.62 BRL 72 75-125 0.8 20 Silver 12.1 0.34 mg/kg dry 13.45 BRL 90 75-125 3 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 74 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Total Metals - Quality Control Analyte Batch P5GO172 - 3050B Project: PTR.001-3A Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Post Spike (P5G0172-PS1) Source: 5070165-02 Prepared & Analyzed: 07/13/15 Arsenic 1.06 mg/L 1.000 0.141 92 80-120 Barium 2.68 mg/L 1.000 1.78 91 80-120 Cadmium 0.887 mg/L 1.000-0.00323 89 80-120 Chromium 1.72 mg/L 1.000 0.831 89 80-120 Lead 2.21 mg/L 1.000 1.36 85 80-120 Selenium 0.776 mg/L 1.000 -0.142 78 80-120 Silver 0.347 mg/L 0.4000-0.0348 87 80-120 Batch P5GO173 - 7471 B Blank (P5G0173-BLK1) Prepared & Analyzed: 07/13/15 Mercury BRL 0.020 mg/kg wet LCS (P5G0173-BS1) Prepared & Analyzed: 07/13/15 Mercury 0.442 0.020 mg/kg wet 0.4167 106 80-120 Matrix Spike (P5G0173-MS1) Source: 5070165-02 Prepared & Analyzed: 07/13/15 Mercury 0.676 0.028 mg/kg dry 0.5912 0.122 94 80-120 Matrix Spike Dup (P5G0173-MSD1) Source: 5070165-02 Prepared & Analyzed: 07/13/15 Mercury 0.693 0.028 mg/kg dry 0.5912 0.122 97 80-120 2 20 Batch P5GO189 - 7470A Blank (P51130189-13LK1) Prepared & Analyzed: 07/14/15 Mercury BRL 0.00020 mg/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 75 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Total Metals - Quality Control Analyte Batch P5GO189 - 7470A Project: PTR.001-3A Level II QC Report 7/22/15 Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes LCS (P5G0189-BS1) Prepared & Analyzed: 07/14/15 Mercury 0.00976 0.00020 mg/L 0.009375 104 80-120 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 76 of 80 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-3A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 General Chemistry Parameters - Quality Control Prism Work Order: 5070165 Time Submitted: 7/10/2015 8:50:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO176 - Solids, Dry Weight Blank (P5G0176-BLK1) Prepared & Analyzed: 07/13/15 % Solids 100 0.100 % by Weight Duplicate (P5G0176-DUP1) Source: 5070165-02 Prepared & Analyzed: 07/13/15 % Solids 72.2 0.100 % by Weight 72.9 1 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 77 of 80 Sample Extraction Data Prep Method: Solids, Dry Weight Lab Number Batch Initial Final Date/Time 5070165-01 P5G0176 30 g 30 g 07/13/15 11:55 5070165-02 P5G0176 30 g 30 g 07/13/15 11:55 5070165-03 P5G0176 30 g 30 g 07/13/15 11:55 Prep Method: 3510C MS Lab Number Batch Initial Final Date/Time 5070165-04 P5G0184 1000 mL 1 mL 07/14/15 11:30 5070165-05 P5G0184 1000 mL 1 mL 07/14/15 11:30 5070165-06 P5G0184 1000 mL 1 mL 07/14/15 11:30 5070165-07 P5G0184 1000 mL 1 mL 07/14/15 11:30 5070165-08 P5G0184 1000 mL 1 mL 07/14/15 11:30 Prep Method: 3546 Lab Number Batch Initial Final Date/Time 5070165-01 P5G0175 30.03 g 1 mL 07/13/15 10:45 5070165-02 P5G0175 30 g 1 mL 07/13/15 10:45 5070165-03 P5G0175 30 g 1 mL 07/13/15 10:45 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 5070165-07 P5G0170 50 mL 50 mL 07/14/15 8:15 Prep Method: 3050E Lab Number Batch Initial Final DatelTime 5070165-01 P5G0172 2.04 g 50 mL 07/13/15 10:11 5070165-02 P5G0172 2.04 g 50 mL 07/13/15 10:11 5070165-03 P5G0172 1.98 g 50 mL 07/13/15 10:11 Prep Method: 7470A Lab Number Batch Initial Final DatelTime 5070165-07 P5G0189 20 mL 30 mL 07/14/15 8:30 Prep Method: 7471E Lab Number Batch Initial Final Date/Time 5070165-01 P5G0173 0.61 g 50 mL 07/13/15 10:18 5070165-02 P5G0173 0.64 g 50 mL 07/13/15 10:18 5070165-03 P5G0173 0.56 g 50 mL 07/13/15 10:18 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 5070165-04 P5G0244 10 mL 10 mL 07/14/15 13:49 5070165-04 P5G0244 10 mL 10 mL 07/14/15 13:49 5070165-05 P5G0244 10 mL 10 mL 07/14/15 13:49 5070165-06 P5G0244 10 mL 10 mL 07/14/15 13:49 5070165-07 P5G0244 10 mL 10 mL 07/14/15 13:49 5070165-08 P5G0244 10 mL 10 mL 07/14/15 13:49 5070165-08 P5G0244 10 mL 10 mL 07/14/15 13:49 5070165-09 P5G0244 10 mL 10 mL 07/14/15 13:49 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 78 of 80 Sample Extraction Data Prep Method: 5035 Lab Number Batch Initial Final Date/Time 5070165-01 P5G0262 5.61 g 5 mL 07/16/15 9:05 5070165-02 P5G0262 5.98 g 5 mL 07/16/15 9:05 5070165-03 P5G0262 4.77 g 5 mL 07/16/15 9:05 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 79 of 80 PRISMFull -Service Analytical & Environmental Solutions LABORATORIES, INC. 449 Springbrook Road Charlotte, NC 28217 Phone 7041529-6364 Fax: 704/525-0409 Client Company Name: N+ �- Report To/Contact Name: Av v r, 0 Reporting Address: A23 A I, I'I'le k� CHAIN OF CUSTODY RECOR PAGE_A_ OF I QUOTE 9 TO ENSURE PROPER BILLING- - Project 11ame: Short Hold Analysis: (Yes) (No) LIST Project: *Please ATTACH any project specific reporting (QC LEVEL 111111 IV) provisions and/or QC Requirements Invoice To: C,A+t� Address: C WCA Ls(a A-0. hiclm M , com MENFAME CD YES, NO N/A 00 ,CT upon arrivad? 0 VVET ICE? v, 0 -SERVATIVES indical.ed? 'SHIN HOLDING 1 IMES �ALS INTACT? -dd WOUT HEADSPACE, NTA,INERS used? 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Vo vluc V X X >( --I _-F� - 3�- goiL VoA is — X X X_ 5A, V 0) — golL X X 0) V111 i 7/9/lS- 11 -3-5-- _ �/ �rf,- vas A X 0', �,,11 .- c, , i I _V)1R;_V_0A v oT js� A 0 A- OVOA h U 9 - MIA 19;7 voA WIA 5- I/ClICc— Affiliation Sampler's Signature _ — I Sampled By (Print Name) CiA x Upon relinquishing, this Chain of Custody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to 11"Pisim Project Manager. There will be charges for any changes after analyses have been initialized. Relinquished (Signature) �9, (Signature) Received By: (Signature) Date Military/Hours Additional Comments,.: Siilte Arrival 'Iflm e: Relinquished By'(Signature)/ -,7, Receive &gnatu11r6) Date Site Departure Tirnc. , Relinquishect$ P Rece' For Prism bo a res y: Fiefld Tech Fee. Date • '0Y Mileage� Method of Shipment: PLE:IALL SAMPLE COOLERS SHOULD BE TAPED SHUT WITH OUSTODY S=OR TRANSPORTATION TO THE LABORATORY. COC Group No. AND VERIFIED AGAINST CDC UNTIL RECEI THE LABORATORY. ARE NOT ACCEPTED _ Q Fed gr-IJ-UPS LI Hand -delivered El Prism Field Service ;ko-ther 171 DRINKING WATER: S LID WASTE: RC LIS�T- 0 NPDES: GROUNDWATER: CERCLA LANDFILL OTHER: E3 NC E3 E E3 NC E3 SC ®NC ;C� E3 � L3 SC � � L3 SC El NC E3 SC 0 NC E3 SC El NC L3 SC EJ NC ®SC Ll NC LIS C � F1 F1 n D Ell 0 El E3 — EJ *CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) NC Certification No. 402 SC Certification No. 99012 Case Narrative PRISM Full -Service Analytical & NC Drinkinq Water Cert No. 37735 07/22/2015 Environmental Solutions VA Certification No. 460211 ,om`. LABORATORIES, INC. DOD ELAP: L-A-B Accredited Certificate No. L2307 ISO/IEC 17025: L-A-B Accredited Certificate No. L2307 Hart & Hickman (Charlotte) Project: PTR.001-4A Aaron Oswald 2923 South Tryon St. Ste 100 Lab Submittal Date: 07/10/2015 Charlotte, NC 28203 Prism Work Order: 5070164 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. a,j Angela D. Overcash VP Laboratory Services Data Qualifiers Key Reference: Reviewed By Terri W. Cole For Angela D. Overcash Project Manager A LCS/LCSD result is below the control limits. CCV recovery within the limits. Analyte not detected in the sample down to the MDL. No further action taken. CVL CCV result is below the control limits. LCS recovery within the limits. Analyte not detected in the sample. No further action taken. D RPD value outside of the control limits. H1 Analysis within hold time from preserved vial. L2 LCSD recovery outside of the QC limits. LCS recovery within the limits. No further action taken. SE Surrogate recovery outside the QC limits due to emulsion. SR Surrogate recovery outside the QC limits. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 66 /P R I S M Full -Service Analytical Environmental Solutions LABORATORIES INC. Sample Receipt Summary 07/22/2015 Prism Work Order: 5070164 Client Sample ID Lab Sample ID Matrix Date Sampled Date Received SB-3 (0-2) 5070164-01 Solid 07/07/15 07/10/15 SB-4 (0-2) 5070164-02 Solid 07/07/15 07/10/15 SB-5 (0-2) 5070164-03 Solid 07/07/15 07/10/15 SB-16 (8-10) 5070164-04 Solid 07/08/15 07/10/15 TMW-5 5070164-05 Water 07/08/15 07/10/15 TMW-6 5070164-06 Water 07/08/15 07/10/15 TMW-7 5070164-07 Water 07/09/15 07/10/15 Dup-2 5070164-08 Water 07/09/15 07/10/15 Trip Blank 5070164-09 Water 07/09/15 07/10/15 Samples were received in good condition at 4.7 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 66 A&P R I S M Full Service Analytical & Environmental Solutions 1LABORATORIES, INC. Summary of Detections 07/22/2015 Prism Work Order: 5070164 Prism ID Client ID Parameter Method Result Units 5070164-01 SB-3 (0-2) Acetone '8260B 0.096 mg/kg dry 5070164-02 SB-4 (0-2) Acetone *8260B 0.089 mg/kg dry 5070164-04 SB-16 (8-10) 2-Methylnaphthalene '8270D 0.58 mg/kg dry 5070164-04 SB-16 (8-10) Acenaphthylene `8270D 0.77 mg/kg dry 5070164-04 SB-16 (8-10) Anthracene '8270D 0.52 mg/kg dry 5070164-04 SB-16 (8-10) Benzo(a)anthracene "8270D 1.6 mg/kg dry 5070164-04 SB-16 (8-10) Benzo(a)pyrene '8270D 3.0 mg/kg dry 5070164-04 SB-16 (8-10) Benzo(b)fluoranthene `8270D 2.3 mg/kg dry 5070164-04 SB-16 (8-10) Benzo(g,h,i)perylene *8270D 2.6 mg/kg dry 5070164-04 SB-16 (8-10) Benzo(k)fluoranthene '8270D 0.58 mg/kg dry 5070164-04 SB-16 (8-10) Chrysene `8270D 1.7 mg/kg dry 5070164-04 SB-16 (8-10) Dibenzo(a,h)anthracene '8270D 0.39 mg/kg dry 5070164-04 SB-16 (8-10) Fluoranthene "8270D 1.8 mg/kg dry 5070164-04 SB-16 (8-10) Indeno(1,2,3-cd)pyrene '8270D 1.6 mg/kg dry 5070164-04 SB-16 (8-10) Naphthalene `8270D 1.2 mg/kg dry 5070164-04 SB-16 (8-10) Phenanthrene "8270D 1.9 mg/kg dry 5070164-04 SB-16 (8-10) Pyrene '8270D 4.1 mg/kg dry 5070164-04 SB-16 (8-10) Mercury *7471 B 0.20 mg/kg dry 5070164-04 SB-16 (8-10) Arsenic '6010C 3.4 mg/kg dry 5070164-04 SB-16 (8-10) Barium "6010C 160 mg/kg dry 5070164-04 SB-16 (8-10) Chromium '6010C 16 mg/kg dry 5070164-04 SB-16 (8-10) Lead '6010C 110 mg/kg dry 5070164-05 TMW-5 Barium "6010C 0.094 mg/L 5070164-06 TMW-6 Barium '6010C 0.52 mg/L 5070164-07 TMW-7 Barium `6010C 0.25 mg/L 5070164-07 TMW-7 Acetone *8260B 54 ug/L 5070164-07 TMW-7 Methyl Ethyl Ketone (2-Butanone) *8260B 12 ug/L 5070164-08 Dup-2 Barium `6010C 0.24 mg/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 66 P R S M Laboratory Report ` Full -Service Analytical & / Environmental Solutions 07/22/2015 LABORATORIES INC. Hart & Hickman (Charlotte) Project: PTR.001-4A Client Sample ID: SB-3 (0-2) Attn: Aaron Oswald Prism Sample ID: 5070164-01 2923 South Tryon St. Ste 100 Prism Work Order: 5070164 Charlotte, NC 28203 Sample Matrix: Solid Time Collected: 07/07/15 11:30 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters % Solids 88.6 % by 0.100 0.100 1 *SM2540 G 7/13/15 11:55 ARC P5G0176 Weight Semivolatile Organic Compounds by GC/MS 1,2,4-Trichlorobenzene BRL mg/kg dry 0.37 0.058 1 *8270D 7/13/15 20:50 JMV P5G0175 1,2-Dichlorobenzene BRL mg/kg dry 0.37 0.057 1 *8270D 7/13/15 20:50 JMV P5G0175 1,3-Dichlorobenzene BRL mg/kg dry 0.37 0.052 1 *8270D 7/13/15 20:50 JMV P5G0175 1,4-Dichlorobenzene BRL mg/kg dry 0.37 0.055 1 *8270D 7/13/15 20:50 JMV P5G0175 1-Methyl naphthalene BRL mg/kg dry 0.37 0.072 1 *8270D 7/13/15 20:50 JMV P5G0175 2,4,6-Trichlorophenol BRL mg/kg dry 0.37 0.070 1 *8270D 7/13/15 20:50 JMV P5G0175 2,4-Dichlorophenol BRL mg/kg dry 0.37 0.072 1 *8270D 7/13/15 20:50 JMV P5G0175 2,4-Dimethylphenol BRL mg/kg dry 0.37 0.057 1 *8270D 7/13/15 20:50 JMV P5G0175 2,4-Dinitrophenol BRL mg/kg dry 0.37 0.052 1 *8270D 7/13/15 20:50 JMV P5G0175 2,4-Dinitrotoluene BRL mg/kg dry 0.37 0.045 1 *8270D 7/13/15 20:50 JMV P5G0175 2,6-Dinitrotoluene BRL mg/kg dry 0.37 0.050 1 *8270D 7/13/15 20:50 JMV P5G0175 2-Chloronaphthalene BRL mg/kg dry 0.37 0.054 1 *8270D 7/13/15 20:50 JMV P5G0175 2-Chlorophenol BRL mg/kg dry 0.37 0.053 1 *8270D 7/13/15 20:50 JMV P5G0175 2-Methyl naphthalene BRL mg/kg dry 0.37 0.060 1 *8270D 7/13/15 20:50 JMV P5G0175 2-Methylphenol BRL mg/kg dry 0.37 0.048 1 *8270D 7/13/15 20:50 JMV P5G0175 2-Nitrophenol BRL mg/kg dry 0.37 0.068 1 *8270D 7/13/15 20:50 JMV P5G0175 3,3'-Dichlorobenzidine BRL mg/kg dry 0.37 0.074 1 *8270D 7/13/15 20:50 JMV P5G0175 3/4-Methyl phenol BRL mg/kg dry 0.37 0.046 1 *8270D 7/13/15 20:50 JMV P5G0175 4,6-Dinitro-2-methylphenol BRL mg/kg dry 0.37 0.056 1 *8270D 7/13/15 20:50 JMV P5G0175 4-Bromophenyl phenyl ether BRL mg/kg dry 0.37 0.064 1 *8270D 7/13/15 20:50 JMV P5G0175 4-Chloro-3-methylphenol BRL mg/kg dry 0.37 0.052 1 *8270D 7/13/15 20:50 JMV P5G0175 4-Chloroaniline BRL mg/kg dry 0.37 0.045 1 *8270D 7/13/15 20:50 JMV P5G0175 4-Chlorophenyl phenyl ether BRL mg/kg dry 0.37 0.048 1 *8270D 7/13/15 20:50 JMV P5G0175 4-Nitrophenol BRL mg/kg dry 0.37 0.057 1 *8270D 7/13/15 20:50 JMV P5G0175 Acenaphthene BRL mg/kg dry 0.37 0.051 1 *8270D 7/13/15 20:50 JMV P5G0175 Acenaphthylene BRL mg/kg dry 0.37 0.054 1 *8270D 7/13/15 20:50 JMV P5G0175 Anthracene BRL mg/kg dry 0.37 0.060 1 *8270D 7/13/15 20:50 JMV P5G0175 Azobenzene BRL mg/kg dry 0.37 0.049 1 *8270D 7/13/15 20:50 JMV P5G0175 Benzo(a)anthracene BRL mg/kg dry 0.37 0.049 1 *8270D 7/13/15 20:50 JMV P5G0175 Benzo(a)pyrene BRL mg/kg dry 0.37 0.040 1 *8270D 7/13/15 20:50 JMV P5G0175 Benzo(b)fluoranthene BRL mg/kg dry 0.37 0.043 1 *8270D 7/13/15 20:50 JMV P5G0175 Benzo(g,hJ)perylene BRL mg/kg dry 0.37 0.041 1 *8270D 7/13/15 20:50 JMV P5G0175 Benzo(k)fluoranthene BRL mg/kg dry 0.37 0.049 1 *8270D 7/13/15 20:50 JMV P5G0175 Benzoic Acid BRL mg/kg dry 0.37 0.031 1 *8270D 7/13/15 20:50 JMV P5G0175 Benzyl alcohol BRL mg/kg dry 0.37 0.049 1 *8270D 7/13/15 20:50 JMV P5G0175 bis(2-Chloroethoxy)methane BRL mg/kg dry 0.37 0.065 1 *8270D 7/13/15 20:50 JMV P5G0175 Bis(2-Chloroethyl)ether BRL mg/kg dry 0.37 0.053 1 *8270D 7/13/15 20:50 JMV P5G0175 Bis(2-chloroisopropyl)ether BRL mg/kg dry 0.37 0.064 1 *8270D 7/13/15 20:50 JMV P5G0175 Bis(2-Ethylhexyl)phthalate BRL mg/kg dry 0.37 0.055 1 *8270D 7/13/15 20:50 JMV P5G0175 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 66 Laboratory Report ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. 07/22/2015 Hart & Hickman (Charlotte) Project: PTR.001-4A Client Sample ID: SB-3 (0-2) Attn: Aaron Oswald Prism Sample ID: 5070164-01 2923 South Tryon St. Ste 100 Prism Work Order: 5070164 Charlotte, NC 28203 Sample Matrix: Solid Time Collected: 07/07/15 11:30 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Butyl benzyl phthalate BRL mg/kg dry 0.37 0.053 1 *8270D 7/13/15 20:50 JMV P5G0175 Chrysene BRL mg/kg dry 0.37 0.047 1 *8270D 7/13/15 20:50 JMV P5G0175 Dibenzo(a,h)anthracene BRL mg/kg dry 0.37 0.045 1 *8270D 7/13/15 20:50 JMV P5G0175 Dibenzofuran BRL mg/kg dry 0.37 0.057 1 *8270D 7/13/15 20:50 JMV P5G0175 Diethyl phthalate BRL mg/kg dry 0.37 0.051 1 *8270D 7/13/15 20:50 JMV P5G0175 Dimethyl phthalate BRL mg/kg dry 0.37 0.049 1 *8270D 7/13/15 20:50 JMV P5G0175 Di-n-butyl phthalate BRL mg/kg dry 0.37 0.053 1 *8270D 7/13/15 20:50 JMV P5G0175 Di-n-octyl phthalate BRL mg/kg dry 0.37 0.046 1 *8270D 7/13/15 20:50 JMV P5G0175 Fluoranthene BRL mg/kg dry 0.37 0.048 1 *8270D 7/13/15 20:50 JMV P5G0175 Fluorene BRL mg/kg dry 0.37 0.053 1 *8270D 7/13/15 20:50 JMV P5G0175 Hexachlorobenzene BRL mg/kg dry 0.37 0.059 1 *8270D 7/13/15 20:50 JMV P5G0175 Hexachlorobutadiene BRL mg/kg dry 0.37 0.067 1 *8270D 7/13/15 20:50 JMV P5G0175 Hexachlorocyclopentadiene BRL mg/kg dry 0.37 0.066 1 *8270D 7/13/15 20:50 JMV P5G0175 Hexachloroethane BRL mg/kg dry 0.37 0.062 1 *8270D 7/13/15 20:50 JMV P5G0175 Indeno(1,2,3-cd)pyrene BRL mg/kg dry 0.37 0.043 1 *8270D 7/13/15 20:50 JMV P5G0175 Isophorone BRL mg/kg dry 0.37 0.050 1 *8270D 7/13/15 20:50 JMV P5G0175 Naphthalene BRL mg/kg dry 0.37 0.060 1 *8270D 7/13/15 20:50 JMV P5G0175 Nitrobenzene BRL mg/kg dry 0.37 0.053 1 *8270D 7/13/15 20:50 JMV P5G0175 N-Nitroso-di-n-propylamine BRL mg/kg dry 0.37 0.059 1 *8270D 7/13/15 20:50 JMV P5G0175 N-Nitrosodiphenylamine BRL mg/kg dry 0.37 0.057 1 *8270D 7/13/15 20:50 JMV P5G0175 Pentachlorophenol BRL mg/kg dry 0.37 0.044 1 *8270D 7/13/15 20:50 JMV P5G0175 Phenanthrene BRL mg/kg dry 0.37 0.048 1 *8270D 7/13/15 20:50 JMV P5G0175 Phenol BRL mg/kg dry 0.37 0.055 1 *8270D 7/13/15 20:50 JMV P5G0175 Pyrene BRL mg/kg dry 0.37 0.049 1 *8270D 7/13/15 20:50 JMV P5G0175 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 118 % 39-132 2-Fluorobiphenyl 104 % 44-115 2-Fluorophenol 92 % 35-115 Nitrobenzene-d5 92 % 37-122 Phenol-d5 92 % 34-121 Terphenyl-d14 112 % 54-127 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL mg/kg dry 0.0056 0.00046 1 *8260B 7/16/15 16:22 MSC P5G0262 1,1,1-Trichloroethane BRL mg/kg dry 0.0056 0.00027 1 *8260B 7/16/15 16:22 MSC P5G0262 1,1,2,2-Tetrachloroethane BRL mg/kg dry 0.0056 0.00038 1 *8260B 7/16/15 16:22 MSC P5G0262 1,1,2-Trichloroethane BRL mg/kg dry 0.0056 0.00049 1 *8260B 7/16/15 16:22 MSC P5G0262 1,1-Dichloroethane BRL mg/kg dry 0.0056 0.00015 1 *8260B 7/16/15 16:22 MSC P5G0262 1,1-Dichloroethylene BRL mg/kg dry 0.0056 0.00025 1 *8260B 7/16/15 16:22 MSC P5G0262 1,1-Dichloropropylene BRL mg/kg dry 0.0056 0.00030 1 *8260B 7/16/15 16:22 MSC P5G0262 1,2,3-Trichlorobenzene BRL mg/kg dry 0.0056 0.00032 1 *8260B 7/16/15 16:22 MSC P5G0262 1,2,3-Trichloropropane BRL mg/kg dry 0.0056 0.00071 1 *8260B 7/16/15 16:22 MSC P5G0262 1,2,4-Trichlorobenzene BRL mg/kg dry 0.0056 0.00041 1 *8260B 7/16/15 16:22 MSC P5G0262 1,2,4-Trimethyl benzene BRL mg/kg dry 0.0056 0.00042 1 *8260B 7/16/15 16:22 MSC P5G0262 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 66 ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-4A Sample Matrix: Solid Laboratory Report 07/22/2015 Client Sample ID: SB-3 (0-2) Prism Sample ID: 5070164-01 Prism Work Order: 5070164 Time Collected: 07/07/15 11:30 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,2-Dibromoethane BRL mg/kg dry 0.0056 0.00022 1 *8260B 7/16/15 16:22 MSC P5G0262 1,2-Dichlorobenzene BRL mg/kg dry 0.0056 0.00026 1 *8260B 7/16/15 16:22 MSC P5G0262 1,2-Dichloroethane BRL mg/kg dry 0.0056 0.00033 1 *8260B 7/16/15 16:22 MSC P5G0262 1,2-Dichloropropane BRL mg/kg dry 0.0056 0.00034 1 *8260B 7/16/15 16:22 MSC P5G0262 1,3,5-Trimethyl benzene BRL mg/kg dry 0.0056 0.00042 1 *8260B 7/16/15 16:22 MSC P5G0262 1,3-Dichlorobenzene BRL mg/kg dry 0.0056 0.00037 1 *8260B 7/16/15 16:22 MSC P5G0262 1,3-Dichloropropane BRL mg/kg dry 0.0056 0.00028 1 *8260B 7/16/15 16:22 MSC P5G0262 1,4-Dichlorobenzene BRL mg/kg dry 0.0056 0.00022 1 *8260B 7/16/15 16:22 MSC P5G0262 2,2-Dichloropropane BRL mg/kg dry 0.0056 0.00026 1 *8260B 7/16/15 16:22 MSC P5G0262 2-Chlorotoluene BRL mg/kg dry 0.0056 0.00029 1 *8260B 7/16/15 16:22 MSC P5G0262 4-Chlorotoluene BRL mg/kg dry 0.0056 0.00033 1 *8260B 7/16/15 16:22 MSC P5G0262 4-Isopropyltoluene BRL mg/kg dry 0.0056 0.00027 1 *8260B 7/16/15 16:22 MSC P5G0262 Acetone 0.096 mg/kg dry 0.056 0.0014 1 *8260B 7116/15 16:22 MSC P5G0262 Benzene BRL mg/kg dry 0.0033 0.00032 1 *8260B 7/16/15 16:22 MSC P5G0262 Bromobenzene BRL mg/kg dry 0.0056 0.00046 1 *8260B 7/16/15 16:22 MSC P5G0262 Bromochloromethane BRL mg/kg dry 0.0056 0.00031 1 *8260B 7/16/15 16:22 MSC P5G0262 Bromodichloromethane BRL mg/kg dry 0.0056 0.00031 1 *8260B 7/16/15 16:22 MSC P5G0262 Bromoform BRL mg/kg dry 0.0056 0.00063 1 *8260B 7/16/15 16:22 MSC P5G0262 Bromomethane BRL mg/kg dry 0.011 0.00069 1 *8260B 7/16/15 16:22 MSC P5G0262 Carbon Tetrachloride BRL mg/kg dry 0.0056 0.00028 1 *8260B 7/16/15 16:22 MSC P5G0262 Chlorobenzene BRL mg/kg dry 0.0056 0.00029 1 *8260B 7/16/15 16:22 MSC P5G0262 Chloroethane BRL mg/kg dry 0.011 0.00046 1 *8260B 7/16/15 16:22 MSC P5G0262 Chloroform BRL mg/kg dry 0.0056 0.00040 1 *8260B 7/16/15 16:22 MSC P5G0262 Chloromethane BRL mg/kg dry 0.0056 0.00037 1 *8260B 7/16/15 16:22 MSC P5G0262 cis-1,2-Dichloroethylene BRL mg/kg dry 0.0056 0.00024 1 *8260B 7/16/15 16:22 MSC P5G0262 cis-1,3-Dichloropropylene BRL mg/kg dry 0.0056 0.00019 1 *8260B 7/16/15 16:22 MSC P5G0262 Dibromochloromethane BRL mg/kg dry 0.0056 0.00023 1 *8260B 7/16/15 16:22 MSC P5G0262 Dichlorodifluoromethane BRL mg/kg dry 0.0056 0.00025 1 *8260B 7/16/15 16:22 MSC P5G0262 Ethylbenzene BRL mg/kg dry 0.0056 0.00021 1 *8260B 7/16/15 16:22 MSC P5G0262 Isopropyl Ether BRL mg/kg dry 0.0056 0.00023 1 *8260B 7/16/15 16:22 MSC P5G0262 Isopropylbenzene (Cumene) BRL mg/kg dry 0.0056 0.00033 1 *8260B 7/16/15 16:22 MSC P5G0262 m,p-Xylenes BRL mg/kg dry 0.011 0.00051 1 *8260B 7/16/15 16:22 MSC P5G0262 Methyl Butyl Ketone (2-Hexanone) BRL mg/kg dry 0.056 0.00050 1 *8260B 7/16/15 16:22 MSC P5G0262 Methyl Ethyl Ketone (2-Butanone) BRL mg/kg dry 0.11 0.00050 1 *8260B 7/16/15 16:22 MSC P5G0262 Methyl Isobutyl Ketone BRL mg/kg dry 0.056 0.00047 1 *8260B 7/16/15 16:22 MSC P5G0262 Methylene Chloride BRL mg/kg dry 0.0056 0.00031 1 *8260B 7/16/15 16:22 MSC P5G0262 Methyl-tert-Butyl Ether BRL mg/kg dry 0.011 0.00018 1 *8260B 7/16/15 16:22 MSC P5G0262 Naphthalene BRL mg/kg dry 0.011 0.00018 1 *8260B 7/16/15 16:22 MSC P5G0262 n-Butylbenzene BRL mg/kg dry 0.0056 0.00028 1 *8260B 7/16/15 16:22 MSC P5G0262 n-Propylbenzene BRL mg/kg dry 0.0056 0.00033 1 *8260B 7/16/15 16:22 MSC P5G0262 o-Xylene BRL mg/kg dry 0.0056 0.00023 1 *8260B 7/16/15 16:22 MSC P5G0262 sec-Butylbenzene BRL mg/kg dry 0.0056 0.00027 1 *8260B 7/16/15 16:22 MSC P5G0262 Styrene BRL mg/kg dry 0.0056 0.00033 1 *8260B 7/16/15 16:22 MSC P5G0262 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 6 of 66 PR I S M Full -Service Analytical Environmental Solutions LABORATORIES INC. Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-4A Sample Matrix: Solid Laboratory Report 07/22/2015 Client Sample ID: SB-3 (0-2) Prism Sample ID: 5070164-01 Prism Work Order: 5070164 Time Collected: 07/07/15 11:30 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID tert-Butylbenzene BRL mg/kg dry 0.0056 0.00019 1 Tetrachloroethylene BRL mg/kg dry 0.0056 0.00026 1 Toluene BRL mg/kg dry 0.0056 0.00032 1 trans-1,2-Dichloroethylene BRL mg/kg dry 0.0056 0.00033 1 trans-1,3-Dichloropropylene BRL mg/kg dry 0.0056 0.00029 1 Trichloroethylene BRL mg/kg dry 0.0056 0.00036 1 Trichlorofluoromethane BRL mg/kg dry 0.0056 0.00036 1 Vinyl acetate BRL A mg/kg dry 0.028 0.00076 1 Vinyl chloride BRL mg/kg dry 0.0056 0.00027 1 Xylenes, total BRL mg/kg dry 0.017 0.0010 1 Surrogate *8260B 7/16/15 16:22 MSC P5G0262 *8260B 7/16/15 16:22 MSC P5130262 *8260B 7/16/15 16:22 MSC P5130262 *8260B 7/16/15 16:22 MSC P5130262 *8260B 7/16/15 16:22 MSC P5G0262 *8260B 7/16/15 16:22 MSC P5G0262 *8260B 7/16/15 16:22 MSC P5G0262 *8260B 7/16/15 16:22 MSC P5G0262 *8260B 7/16/15 16:22 MSC P5G0262 *8260B 7/16/15 16:22 MSC P5G0262 Recovery Control Limits 4-Bromofluorobenzene 120 % 70-130 Dibromofluoromethane 109 % 84-123 Toluene-d8 102 % 76-129 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 7 of 66 P R S M Laboratory Report ` Full -Service Analytical & / Environmental Solutions 07/22/2015 LABORATORIES INC. Hart & Hickman (Charlotte) Project: PTR.001-4A Client Sample ID: SB-4 (0-2) Attn: Aaron Oswald Prism Sample ID: 5070164-02 2923 South Tryon St. Ste 100 Prism Work Order: 5070164 Charlotte, NC 28203 Sample Matrix: Solid Time Collected: 07/07/15 11:45 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters % Solids 81.3 % by 0.100 0.100 1 *SM2540 G 7/13/15 11:55 ARC P5G0176 Weight Semivolatile Organic Compounds by GC/MS 1,2,4-Trichlorobenzene BRL mg/kg dry 0.41 0.063 1 *8270D 7/13/15 21:54 JMV P5G0175 1,2-Dichlorobenzene BRL mg/kg dry 0.41 0.062 1 *8270D 7/13/15 21:54 JMV P5G0175 1,3-Dichlorobenzene BRL mg/kg dry 0.41 0.057 1 *8270D 7/13/15 21:54 JMV P5G0175 1,4-Dichlorobenzene BRL mg/kg dry 0.41 0.059 1 *8270D 7/13/15 21:54 JMV P5G0175 1-Methyl naphthalene BRL mg/kg dry 0.41 0.078 1 *8270D 7/13/15 21:54 JMV P5G0175 2,4,6-Trichlorophenol BRL mg/kg dry 0.41 0.076 1 *8270D 7/13/15 21:54 JMV P5G0175 2,4-Dichlorophenol BRL mg/kg dry 0.41 0.078 1 *8270D 7/13/15 21:54 JMV P5G0175 2,4-Dimethylphenol BRL mg/kg dry 0.41 0.062 1 *8270D 7/13/15 21:54 JMV P5G0175 2,4-Dinitrophenol BRL mg/kg dry 0.41 0.057 1 *8270D 7/13/15 21:54 JMV P5G0175 2,4-Dinitrotoluene BRL mg/kg dry 0.41 0.049 1 *8270D 7/13/15 21:54 JMV P5G0175 2,6-Dinitrotoluene BRL mg/kg dry 0.41 0.054 1 *8270D 7/13/15 21:54 JMV P5G0175 2-Chloronaphthalene BRL mg/kg dry 0.41 0.059 1 *8270D 7/13/15 21:54 JMV P5G0175 2-Chlorophenol BRL mg/kg dry 0.41 0.057 1 *8270D 7/13/15 21:54 JMV P5G0175 2-Methyl naphthalene BRL mg/kg dry 0.41 0.065 1 *8270D 7/13/15 21:54 JMV P5G0175 2-Methylphenol BRL mg/kg dry 0.41 0.052 1 *8270D 7/13/15 21:54 JMV P5G0175 2-Nitrophenol BRL mg/kg dry 0.41 0.074 1 *8270D 7/13/15 21:54 JMV P5G0175 3,3'-Dichlorobenzidine BRL mg/kg dry 0.41 0.080 1 *8270D 7/13/15 21:54 JMV P5G0175 3/4-Methyl phenol BRL mg/kg dry 0.41 0.050 1 *8270D 7/13/15 21:54 JMV P5G0175 4,6-Dinitro-2-methylphenol BRL mg/kg dry 0.41 0.061 1 *8270D 7/13/15 21:54 JMV P5G0175 4-Bromophenyl phenyl ether BRL mg/kg dry 0.41 0.070 1 *8270D 7/13/15 21:54 JMV P5G0175 4-Chloro-3-methylphenol BRL mg/kg dry 0.41 0.057 1 *8270D 7/13/15 21:54 JMV P5G0175 4-Chloroaniline BRL mg/kg dry 0.41 0.049 1 *8270D 7/13/15 21:54 JMV P5G0175 4-Chlorophenyl phenyl ether BRL mg/kg dry 0.41 0.053 1 *8270D 7/13/15 21:54 JMV P5G0175 4-Nitrophenol BRL mg/kg dry 0.41 0.063 1 *8270D 7/13/15 21:54 JMV P5G0175 Acenaphthene BRL mg/kg dry 0.41 0.055 1 *8270D 7/13/15 21:54 JMV P5G0175 Acenaphthylene BRL mg/kg dry 0.41 0.059 1 *8270D 7/13/15 21:54 JMV P5G0175 Anthracene BRL mg/kg dry 0.41 0.065 1 *8270D 7/13/15 21:54 JMV P5G0175 Azobenzene BRL mg/kg dry 0.41 0.054 1 *8270D 7/13/15 21:54 JMV P5G0175 Benzo(a)anthracene BRL mg/kg dry 0.41 0.053 1 *8270D 7/13/15 21:54 JMV P5G0175 Benzo(a)pyrene BRL mg/kg dry 0.41 0.044 1 *8270D 7/13/15 21:54 JMV P5G0175 Benzo(b)fluoranthene BRL mg/kg dry 0.41 0.047 1 *8270D 7/13/15 21:54 JMV P5G0175 Benzo(g,hJ)perylene BRL mg/kg dry 0.41 0.044 1 *8270D 7/13/15 21:54 JMV P5G0175 Benzo(k)fluoranthene BRL mg/kg dry 0.41 0.053 1 *8270D 7/13/15 21:54 JMV P5G0175 Benzoic Acid BRL mg/kg dry 0.41 0.034 1 *8270D 7/13/15 21:54 JMV P5G0175 Benzyl alcohol BRL mg/kg dry 0.41 0.053 1 *8270D 7/13/15 21:54 JMV P5G0175 bis(2-Chloroethoxy)methane BRL mg/kg dry 0.41 0.070 1 *8270D 7/13/15 21:54 JMV P5G0175 Bis(2-Chloroethyl)ether BRL mg/kg dry 0.41 0.057 1 *8270D 7/13/15 21:54 JMV P5G0175 Bis(2-chloroisopropyl)ether BRL mg/kg dry 0.41 0.069 1 *8270D 7/13/15 21:54 JMV P5G0175 Bis(2-Ethylhexyl)phthalate BRL mg/kg dry 0.41 0.060 1 *8270D 7/13/15 21:54 JMV P5G0175 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 8 of 66 Laboratory Report ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. 07/22/2015 Hart & Hickman (Charlotte) Project: PTR.001-4A Client Sample ID: SB-4 (0-2) Attn: Aaron Oswald Prism Sample ID: 5070164-02 2923 South Tryon St. Ste 100 Prism Work Order: 5070164 Charlotte, NC 28203 Sample Matrix: Solid Time Collected: 07/07/15 11:45 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Butyl benzyl phthalate BRL mg/kg dry 0.41 0.058 1 *8270D 7/13/15 21:54 JMV P5G0175 Chrysene BRL mg/kg dry 0.41 0.051 1 *8270D 7/13/15 21:54 JMV P5G0175 Dibenzo(a,h)anthracene BRL mg/kg dry 0.41 0.049 1 *8270D 7/13/15 21:54 JMV P5G0175 Dibenzofuran BRL mg/kg dry 0.41 0.062 1 *8270D 7/13/15 21:54 JMV P5G0175 Diethyl phthalate BRL mg/kg dry 0.41 0.056 1 *8270D 7/13/15 21:54 JMV P5G0175 Dimethyl phthalate BRL mg/kg dry 0.41 0.054 1 *8270D 7/13/15 21:54 JMV P5G0175 Di-n-butyl phthalate BRL mg/kg dry 0.41 0.058 1 *8270D 7/13/15 21:54 JMV P5G0175 Di-n-octyl phthalate BRL mg/kg dry 0.41 0.050 1 *8270D 7/13/15 21:54 JMV P5G0175 Fluoranthene BRL mg/kg dry 0.41 0.052 1 *8270D 7/13/15 21:54 JMV P5G0175 Fluorene BRL mg/kg dry 0.41 0.058 1 *8270D 7/13/15 21:54 JMV P5G0175 Hexachlorobenzene BRL mg/kg dry 0.41 0.064 1 *8270D 7/13/15 21:54 JMV P5G0175 Hexachlorobutadiene BRL mg/kg dry 0.41 0.073 1 *8270D 7/13/15 21:54 JMV P5G0175 Hexachlorocyclopentadiene BRL mg/kg dry 0.41 0.072 1 *8270D 7/13/15 21:54 JMV P5G0175 Hexachloroethane BRL mg/kg dry 0.41 0.068 1 *8270D 7/13/15 21:54 JMV P5G0175 Indeno(1,2,3-cd)pyrene BRL mg/kg dry 0.41 0.047 1 *8270D 7/13/15 21:54 JMV P5G0175 Isophorone BRL mg/kg dry 0.41 0.055 1 *8270D 7/13/15 21:54 JMV P5G0175 Naphthalene BRL mg/kg dry 0.41 0.065 1 *8270D 7/13/15 21:54 JMV P5G0175 Nitrobenzene BRL mg/kg dry 0.41 0.058 1 *8270D 7/13/15 21:54 JMV P5G0175 N-Nitroso-di-n-propylamine BRL mg/kg dry 0.41 0.064 1 *8270D 7/13/15 21:54 JMV P5G0175 N-Nitrosodiphenylamine BRL mg/kg dry 0.41 0.062 1 *8270D 7/13/15 21:54 JMV P5G0175 Pentachlorophenol BRL mg/kg dry 0.41 0.048 1 *8270D 7/13/15 21:54 JMV P5G0175 Phenanthrene BRL mg/kg dry 0.41 0.053 1 *8270D 7/13/15 21:54 JMV P5G0175 Phenol BRL mg/kg dry 0.41 0.060 1 *8270D 7/13/15 21:54 JMV P5G0175 Pyrene BRL mg/kg dry 0.41 0.054 1 *8270D 7/13/15 21:54 JMV P5G0175 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 116 % 39-132 2-Fluorobiphenyl 104 % 44-115 2-Fluorophenol 91 % 35-115 Nitrobenzene-d5 91 % 37-122 Phenol-d5 92 % 34-121 Terphenyl-d14 111 % 54-127 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL mg/kg dry 0.0056 0.00046 1 *8260B 7/16/15 16:53 MSC P5G0262 1,1,1-Trichloroethane BRL mg/kg dry 0.0056 0.00027 1 *8260B 7/16/15 16:53 MSC P5G0262 1,1,2,2-Tetrachloroethane BRL mg/kg dry 0.0056 0.00038 1 *8260B 7/16/15 16:53 MSC P5G0262 1,1,2-Trichloroethane BRL mg/kg dry 0.0056 0.00049 1 *8260B 7/16/15 16:53 MSC P5G0262 1,1-Dichloroethane BRL mg/kg dry 0.0056 0.00015 1 *8260B 7/16/15 16:53 MSC P5G0262 1,1-Dichloroethylene BRL mg/kg dry 0.0056 0.00025 1 *8260B 7/16/15 16:53 MSC P5G0262 1,1-Dichloropropylene BRL mg/kg dry 0.0056 0.00031 1 *8260B 7/16/15 16:53 MSC P5G0262 1,2,3-Trichlorobenzene BRL mg/kg dry 0.0056 0.00032 1 *8260B 7/16/15 16:53 MSC P5G0262 1,2,3-Trichloropropane BRL mg/kg dry 0.0056 0.00071 1 *8260B 7/16/15 16:53 MSC P5G0262 1,2,4-Trichlorobenzene BRL mg/kg dry 0.0056 0.00041 1 *8260B 7/16/15 16:53 MSC P5G0262 1,2,4-Trimethyl benzene BRL mg/kg dry 0.0056 0.00043 1 *8260B 7/16/15 16:53 MSC P5G0262 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 9 of 66 ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-4A Sample Matrix: Solid Laboratory Report 07/22/2015 Client Sample ID: SB-4 (0-2) Prism Sample ID: 5070164-02 Prism Work Order: 5070164 Time Collected: 07/07/15 11:45 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,2-Dibromoethane BRL mg/kg dry 0.0056 0.00022 1 *8260B 7/16/15 16:53 MSC P5G0262 1,2-Dichlorobenzene BRL mg/kg dry 0.0056 0.00026 1 *8260B 7/16/15 16:53 MSC P5G0262 1,2-Dichloroethane BRL mg/kg dry 0.0056 0.00033 1 *8260B 7/16/15 16:53 MSC P5G0262 1,2-Dichloropropane BRL mg/kg dry 0.0056 0.00035 1 *8260B 7/16/15 16:53 MSC P5G0262 1,3,5-Trimethyl benzene BRL mg/kg dry 0.0056 0.00042 1 *8260B 7/16/15 16:53 MSC P5G0262 1,3-Dichlorobenzene BRL mg/kg dry 0.0056 0.00037 1 *8260B 7/16/15 16:53 MSC P5G0262 1,3-Dichloropropane BRL mg/kg dry 0.0056 0.00028 1 *8260B 7/16/15 16:53 MSC P5G0262 1,4-Dichlorobenzene BRL mg/kg dry 0.0056 0.00022 1 *8260B 7/16/15 16:53 MSC P5G0262 2,2-Dichloropropane BRL mg/kg dry 0.0056 0.00027 1 *8260B 7/16/15 16:53 MSC P5G0262 2-Chlorotoluene BRL mg/kg dry 0.0056 0.00029 1 *8260B 7/16/15 16:53 MSC P5G0262 4-Chlorotoluene BRL mg/kg dry 0.0056 0.00033 1 *8260B 7/16/15 16:53 MSC P5G0262 4-Isopropyltoluene BRL mg/kg dry 0.0056 0.00027 1 *8260B 7/16/15 16:53 MSC P5G0262 Acetone 0.089 mg/kg dry 0.056 0.0014 1 *8260B 7116/15 16:53 MSC P5G0262 Benzene BRL mg/kg dry 0.0033 0.00032 1 *8260B 7/16/15 16:53 MSC P5G0262 Bromobenzene BRL mg/kg dry 0.0056 0.00046 1 *8260B 7/16/15 16:53 MSC P5G0262 Bromochloromethane BRL mg/kg dry 0.0056 0.00031 1 *8260B 7/16/15 16:53 MSC P5G0262 Bromodichloromethane BRL mg/kg dry 0.0056 0.00031 1 *8260B 7/16/15 16:53 MSC P5G0262 Bromoform BRL mg/kg dry 0.0056 0.00063 1 *8260B 7/16/15 16:53 MSC P5G0262 Bromomethane BRL mg/kg dry 0.011 0.00069 1 *8260B 7/16/15 16:53 MSC P5G0262 Carbon Tetrachloride BRL mg/kg dry 0.0056 0.00028 1 *8260B 7/16/15 16:53 MSC P5G0262 Chlorobenzene BRL mg/kg dry 0.0056 0.00030 1 *8260B 7/16/15 16:53 MSC P5G0262 Chloroethane BRL mg/kg dry 0.011 0.00046 1 *8260B 7/16/15 16:53 MSC P5G0262 Chloroform BRL mg/kg dry 0.0056 0.00040 1 *8260B 7/16/15 16:53 MSC P5G0262 Chloromethane BRL mg/kg dry 0.0056 0.00037 1 *8260B 7/16/15 16:53 MSC P5G0262 cis-1,2-Dichloroethylene BRL mg/kg dry 0.0056 0.00024 1 *8260B 7/16/15 16:53 MSC P5G0262 cis-1,3-Dichloropropylene BRL mg/kg dry 0.0056 0.00019 1 *8260B 7/16/15 16:53 MSC P5G0262 Dibromochloromethane BRL mg/kg dry 0.0056 0.00023 1 *8260B 7/16/15 16:53 MSC P5G0262 Dichlorodifluoromethane BRL mg/kg dry 0.0056 0.00025 1 *8260B 7/16/15 16:53 MSC P5G0262 Ethylbenzene BRL mg/kg dry 0.0056 0.00021 1 *8260B 7/16/15 16:53 MSC P5G0262 Isopropyl Ether BRL mg/kg dry 0.0056 0.00023 1 *8260B 7/16/15 16:53 MSC P5G0262 Isopropylbenzene (Cumene) BRL mg/kg dry 0.0056 0.00033 1 *8260B 7/16/15 16:53 MSC P5G0262 m,p-Xylenes BRL mg/kg dry 0.011 0.00051 1 *8260B 7/16/15 16:53 MSC P5G0262 Methyl Butyl Ketone (2-Hexanone) BRL mg/kg dry 0.056 0.00050 1 *8260B 7/16/15 16:53 MSC P5G0262 Methyl Ethyl Ketone (2-Butanone) BRL mg/kg dry 0.11 0.00050 1 *8260B 7/16/15 16:53 MSC P5G0262 Methyl Isobutyl Ketone BRL mg/kg dry 0.056 0.00047 1 *8260B 7/16/15 16:53 MSC P5G0262 Methylene Chloride BRL mg/kg dry 0.0056 0.00031 1 *8260B 7/16/15 16:53 MSC P5G0262 Methyl-tert-Butyl Ether BRL mg/kg dry 0.011 0.00018 1 *8260B 7/16/15 16:53 MSC P5G0262 Naphthalene BRL mg/kg dry 0.011 0.00018 1 *8260B 7/16/15 16:53 MSC P5G0262 n-Butylbenzene BRL mg/kg dry 0.0056 0.00028 1 *8260B 7/16/15 16:53 MSC P5G0262 n-Propylbenzene BRL mg/kg dry 0.0056 0.00033 1 *8260B 7/16/15 16:53 MSC P5G0262 o-Xylene BRL mg/kg dry 0.0056 0.00023 1 *8260B 7/16/15 16:53 MSC P5G0262 sec-Butylbenzene BRL mg/kg dry 0.0056 0.00027 1 *8260B 7/16/15 16:53 MSC P5G0262 Styrene BRL mg/kg dry 0.0056 0.00034 1 *8260B 7/16/15 16:53 MSC P5G0262 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 10 of 66 PR I S M Full -Service Analytical Environmental Solutions LABORATORIES INC. Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-4A Sample Matrix: Solid Laboratory Report 07/22/2015 Client Sample ID: SB-4 (0-2) Prism Sample ID: 5070164-02 Prism Work Order: 5070164 Time Collected: 07/07/15 11:45 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID tert-Butylbenzene BRL mg/kg dry 0.0056 0.00019 1 Tetrachloroethylene BRL mg/kg dry 0.0056 0.00027 1 Toluene BRL mg/kg dry 0.0056 0.00032 1 trans-1,2-Dichloroethylene BRL mg/kg dry 0.0056 0.00033 1 trans-1,3-Dichloropropylene BRL mg/kg dry 0.0056 0.00029 1 Trichloroethylene BRL mg/kg dry 0.0056 0.00036 1 Trichlorofluoromethane BRL mg/kg dry 0.0056 0.00036 1 Vinyl acetate BRL A mg/kg dry 0.028 0.00076 1 Vinyl chloride BRL mg/kg dry 0.0056 0.00027 1 Xylenes, total BRL mg/kg dry 0.017 0.0010 1 Surrogate *8260B 7/16/15 16:53 MSC P5G0262 *8260B 7/16/15 16:53 MSC P5130262 *8260B 7/16/15 16:53 MSC P5130262 *8260B 7/16/15 16:53 MSC P5130262 *8260B 7/16/15 16:53 MSC P5G0262 *8260B 7/16/15 16:53 MSC P5G0262 *8260B 7/16/15 16:53 MSC P5G0262 *8260B 7/16/15 16:53 MSC P5G0262 *8260B 7/16/15 16:53 MSC P5G0262 *8260B 7/16/15 16:53 MSC P5G0262 Recovery Control Limits 4-Bromofluorobenzene 124 % 70-130 Dibromofluoromethane 108 % 84-123 Toluene-d8 102 % 76-129 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 11 of 66 Laboratory Report ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. 07/22/2015 Hart & Hickman (Charlotte) Project: PTR.001-4A Client Sample ID: SB-5 (0-2) Attn: Aaron Oswald Prism Sample ID: 5070164-03 2923 South Tryon St. Ste 100 Prism Work Order: 5070164 Charlotte, NC 28203 Sample Matrix: Solid Time Collected: 07/07/15 12:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters % Solids 82.4 % by 0.100 0.100 1 *SM2540 G 7/13/15 11:55 ARC P5G0176 Weight Semivolatile Organic Compounds by GC/MS 1,2,4-Trichlorobenzene BRL mg/kg dry 0.40 0.063 1 *8270D 7/13/15 21:11 JMV P5G0175 1,2-Dichlorobenzene BRL mg/kg dry 0.40 0.061 1 *8270D 7/13/15 21:11 JMV P5G0175 1,3-Dichlorobenzene BRL mg/kg dry 0.40 0.056 1 *8270D 7/13/15 21:11 JMV P5G0175 1,4-Dichlorobenzene BRL mg/kg dry 0.40 0.059 1 *8270D 7/13/15 21:11 JMV P5G0175 1-Methyl naphthalene BRL mg/kg dry 0.40 0.077 1 *8270D 7/13/15 21:11 JMV P5G0175 2,4,6-Trichlorophenol BRL mg/kg dry 0.40 0.075 1 *8270D 7/13/15 21:11 JMV P5G0175 2,4-Dichlorophenol BRL mg/kg dry 0.40 0.077 1 *8270D 7/13/15 21:11 JMV P5G0175 2,4-Dimethylphenol BRL mg/kg dry 0.40 0.061 1 *8270D 7/13/15 21:11 JMV P5G0175 2,4-Dinitrophenol BRL mg/kg dry 0.40 0.056 1 *8270D 7/13/15 21:11 JMV P5G0175 2,4-Dinitrotoluene BRL mg/kg dry 0.40 0.049 1 *8270D 7/13/15 21:11 JMV P5G0175 2,6-Dinitrotoluene BRL mg/kg dry 0.40 0.053 1 *8270D 7/13/15 21:11 JMV P5G0175 2-Chloronaphthalene BRL mg/kg dry 0.40 0.058 1 *8270D 7/13/15 21:11 JMV P5G0175 2-Chlorophenol BRL mg/kg dry 0.40 0.057 1 *8270D 7/13/15 21:11 JMV P5G0175 2-Methyl naphthalene BRL mg/kg dry 0.40 0.064 1 *8270D 7/13/15 21:11 JMV P5G0175 2-Methylphenol BRL mg/kg dry 0.40 0.051 1 *8270D 7/13/15 21:11 JMV P5G0175 2-Nitrophenol BRL mg/kg dry 0.40 0.073 1 *8270D 7/13/15 21:11 JMV P5G0175 3,3'-Dichlorobenzidine BRL mg/kg dry 0.40 0.079 1 *8270D 7/13/15 21:11 JMV P5G0175 3/4-Methyl phenol BRL mg/kg dry 0.40 0.049 1 *8270D 7/13/15 21:11 JMV P5G0175 4,6-Dinitro-2-methylphenol BRL mg/kg dry 0.40 0.060 1 *8270D 7/13/15 21:11 JMV P5G0175 4-Bromophenyl phenyl ether BRL mg/kg dry 0.40 0.069 1 *8270D 7/13/15 21:11 JMV P5G0175 4-Chloro-3-methylphenol BRL mg/kg dry 0.40 0.056 1 *8270D 7/13/15 21:11 JMV P5G0175 4-Chloroaniline BRL mg/kg dry 0.40 0.048 1 *8270D 7/13/15 21:11 JMV P5G0175 4-Chlorophenyl phenyl ether BRL mg/kg dry 0.40 0.052 1 *8270D 7/13/15 21:11 JMV P5G0175 4-Nitrophenol BRL mg/kg dry 0.40 0.062 1 *8270D 7/13/15 21:11 JMV P5G0175 Acenaphthene BRL mg/kg dry 0.40 0.054 1 *8270D 7/13/15 21:11 JMV P5G0175 Acenaphthylene BRL mg/kg dry 0.40 0.058 1 *8270D 7/13/15 21:11 JMV P5G0175 Anthracene BRL mg/kg dry 0.40 0.065 1 *8270D 7/13/15 21:11 JMV P5G0175 Azobenzene BRL mg/kg dry 0.40 0.053 1 *8270D 7/13/15 21:11 JMV P5G0175 Benzo(a)anthracene BRL mg/kg dry 0.40 0.052 1 *8270D 7/13/15 21:11 JMV P5G0175 Benzo(a)pyrene BRL mg/kg dry 0.40 0.043 1 *8270D 7/13/15 21:11 JMV P5G0175 Benzo(b)fluoranthene BRL mg/kg dry 0.40 0.046 1 *8270D 7/13/15 21:11 JMV P5G0175 Benzo(g,hJ)perylene BRL mg/kg dry 0.40 0.044 1 *8270D 7/13/15 21:11 JMV P5G0175 Benzo(k)fluoranthene BRL mg/kg dry 0.40 0.053 1 *8270D 7/13/15 21:11 JMV P5G0175 Benzoic Acid BRL mg/kg dry 0.40 0.034 1 *8270D 7/13/15 21:11 JMV P5G0175 Benzyl alcohol BRL mg/kg dry 0.40 0.053 1 *8270D 7/13/15 21:11 JMV P5G0175 bis(2-Chloroethoxy)methane BRL mg/kg dry 0.40 0.070 1 *8270D 7/13/15 21:11 JMV P5G0175 Bis(2-Chloroethyl)ether BRL mg/kg dry 0.40 0.057 1 *8270D 7/13/15 21:11 JMV P5G0175 Bis(2-chloroisopropyl)ether BRL mg/kg dry 0.40 0.068 1 *8270D 7/13/15 21:11 JMV P5G0175 Bis(2-Ethylhexyl)phthalate BRL mg/kg dry 0.40 0.059 1 *8270D 7/13/15 21:11 JMV P5G0175 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 12 of 66 Laboratory Report ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. 07/22/2015 Hart & Hickman (Charlotte) Project: PTR.001-4A Client Sample ID: SB-5 (0-2) Attn: Aaron Oswald Prism Sample ID: 5070164-03 2923 South Tryon St. Ste 100 Prism Work Order: 5070164 Charlotte, NC 28203 Sample Matrix: Solid Time Collected: 07/07/15 12:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Butyl benzyl phthalate BRL mg/kg dry 0.40 0.057 1 *8270D 7/13/15 21:11 JMV P5G0175 Chrysene BRL mg/kg dry 0.40 0.050 1 *8270D 7/13/15 21:11 JMV P5G0175 Dibenzo(a,h)anthracene BRL mg/kg dry 0.40 0.049 1 *8270D 7/13/15 21:11 JMV P5G0175 Dibenzofuran BRL mg/kg dry 0.40 0.061 1 *8270D 7/13/15 21:11 JMV P5G0175 Diethyl phthalate BRL mg/kg dry 0.40 0.055 1 *8270D 7/13/15 21:11 JMV P5G0175 Dimethyl phthalate BRL mg/kg dry 0.40 0.053 1 *8270D 7/13/15 21:11 JMV P5G0175 Di-n-butyl phthalate BRL mg/kg dry 0.40 0.057 1 *8270D 7/13/15 21:11 JMV P5G0175 Di-n-octyl phthalate BRL mg/kg dry 0.40 0.049 1 *8270D 7/13/15 21:11 JMV P5G0175 Fluoranthene BRL mg/kg dry 0.40 0.051 1 *8270D 7/13/15 21:11 JMV P5G0175 Fluorene BRL mg/kg dry 0.40 0.058 1 *8270D 7/13/15 21:11 JMV P5G0175 Hexachlorobenzene BRL mg/kg dry 0.40 0.064 1 *8270D 7/13/15 21:11 JMV P5G0175 Hexachlorobutadiene BRL mg/kg dry 0.40 0.072 1 *8270D 7/13/15 21:11 JMV P5G0175 Hexachlorocyclopentadiene BRL mg/kg dry 0.40 0.071 1 *8270D 7/13/15 21:11 JMV P5G0175 Hexachloroethane BRL mg/kg dry 0.40 0.067 1 *8270D 7/13/15 21:11 JMV P5G0175 Indeno(1,2,3-cd)pyrene BRL mg/kg dry 0.40 0.046 1 *8270D 7/13/15 21:11 JMV P5G0175 Isophorone BRL mg/kg dry 0.40 0.054 1 *8270D 7/13/15 21:11 JMV P5G0175 Naphthalene BRL mg/kg dry 0.40 0.064 1 *8270D 7/13/15 21:11 JMV P5G0175 Nitrobenzene BRL mg/kg dry 0.40 0.057 1 *8270D 7/13/15 21:11 JMV P5G0175 N-Nitroso-di-n-propylamine BRL mg/kg dry 0.40 0.063 1 *8270D 7/13/15 21:11 JMV P5G0175 N-Nitrosodiphenylamine BRL mg/kg dry 0.40 0.061 1 *8270D 7/13/15 21:11 JMV P5G0175 Pentachlorophenol BRL mg/kg dry 0.40 0.047 1 *8270D 7/13/15 21:11 JMV P5G0175 Phenanthrene BRL mg/kg dry 0.40 0.052 1 *8270D 7/13/15 21:11 JMV P5G0175 Phenol BRL mg/kg dry 0.40 0.059 1 *8270D 7/13/15 21:11 JMV P5G0175 Pyrene BRL mg/kg dry 0.40 0.053 1 *8270D 7/13/15 21:11 JMV P5G0175 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 120 % 39-132 2-Fluorobiphenyl 103 % 44-115 2-Fluorophenol 93 % 35-115 Nitrobenzene-d5 92 % 37-122 Phenol-d5 92 % 34-121 Terphenyl-d14 113 % 54-127 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL mg/kg dry 0.0063 0.00052 1 *8260B 7/16/15 17:25 MSC P5G0262 1,1,1-Trichloroethane BRL mg/kg dry 0.0063 0.00031 1 *8260B 7/16/15 17:25 MSC P5G0262 1,1,2,2-Tetrachloroethane BRL mg/kg dry 0.0063 0.00043 1 *8260B 7/16/15 17:25 MSC P5G0262 1,1,2-Trichloroethane BRL mg/kg dry 0.0063 0.00056 1 *8260B 7/16/15 17:25 MSC P5G0262 1,1-Dichloroethane BRL mg/kg dry 0.0063 0.00018 1 *8260B 7/16/15 17:25 MSC P5G0262 1,1-Dichloroethylene BRL mg/kg dry 0.0063 0.00028 1 *8260B 7/16/15 17:25 MSC P5G0262 1,1-Dichloropropylene BRL mg/kg dry 0.0063 0.00035 1 *8260B 7/16/15 17:25 MSC P5G0262 1,2,3-Trichlorobenzene BRL mg/kg dry 0.0063 0.00036 1 *8260B 7/16/15 17:25 MSC P5G0262 1,2,3-Trichloropropane BRL mg/kg dry 0.0063 0.00081 1 *8260B 7/16/15 17:25 MSC P5G0262 1,2,4-Trichlorobenzene BRL mg/kg dry 0.0063 0.00047 1 *8260B 7/16/15 17:25 MSC P5G0262 1,2,4-Trimethyl benzene BRL mg/kg dry 0.0063 0.00048 1 *8260B 7/16/15 17:25 MSC P5G0262 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 13 of 66 ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-4A Sample Matrix: Solid Laboratory Report 07/22/2015 Client Sample ID: SB-5 (0-2) Prism Sample ID: 5070164-03 Prism Work Order: 5070164 Time Collected: 07/07/15 12:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,2-Dibromoethane BRL mg/kg dry 0.0063 0.00025 1 *8260B 7/16/15 17:25 MSC P5G0262 1,2-Dichlorobenzene BRL mg/kg dry 0.0063 0.00030 1 *8260B 7/16/15 17:25 MSC P5G0262 1,2-Dichloroethane BRL mg/kg dry 0.0063 0.00038 1 *8260B 7/16/15 17:25 MSC P5G0262 1,2-Dichloropropane BRL mg/kg dry 0.0063 0.00039 1 *8260B 7/16/15 17:25 MSC P5G0262 1,3,5-Trimethyl benzene BRL mg/kg dry 0.0063 0.00048 1 *8260B 7/16/15 17:25 MSC P5G0262 1,3-Dichlorobenzene BRL mg/kg dry 0.0063 0.00042 1 *8260B 7/16/15 17:25 MSC P5G0262 1,3-Dichloropropane BRL mg/kg dry 0.0063 0.00032 1 *8260B 7/16/15 17:25 MSC P5G0262 1,4-Dichlorobenzene BRL mg/kg dry 0.0063 0.00025 1 *8260B 7/16/15 17:25 MSC P5G0262 2,2-Dichloropropane BRL mg/kg dry 0.0063 0.00030 1 *8260B 7/16/15 17:25 MSC P5G0262 2-Chlorotoluene BRL mg/kg dry 0.0063 0.00033 1 *8260B 7/16/15 17:25 MSC P5G0262 4-Chlorotoluene BRL mg/kg dry 0.0063 0.00038 1 *8260B 7/16/15 17:25 MSC P5G0262 4-Isopropyltoluene BRL mg/kg dry 0.0063 0.00031 1 *8260B 7/16/15 17:25 MSC P5G0262 Acetone BRL mg/kg dry 0.063 0.0015 1 *8260B 7/16/15 17:25 MSC P5G0262 Benzene BRL mg/kg dry 0.0038 0.00037 1 *8260B 7/16/15 17:25 MSC P5G0262 Bromobenzene BRL mg/kg dry 0.0063 0.00053 1 *8260B 7/16/15 17:25 MSC P5G0262 Bromochloromethane BRL mg/kg dry 0.0063 0.00035 1 *8260B 7/16/15 17:25 MSC P5G0262 Bromodichloromethane BRL mg/kg dry 0.0063 0.00035 1 *8260B 7/16/15 17:25 MSC P5G0262 Bromoform BRL mg/kg dry 0.0063 0.00072 1 *8260B 7/16/15 17:25 MSC P5G0262 Bromomethane BRL mg/kg dry 0.013 0.00078 1 *8260B 7/16/15 17:25 MSC P5G0262 Carbon Tetrachloride BRL mg/kg dry 0.0063 0.00032 1 *8260B 7/16/15 17:25 MSC P5G0262 Chlorobenzene BRL mg/kg dry 0.0063 0.00034 1 *8260B 7/16/15 17:25 MSC P5G0262 Chloroethane BRL mg/kg dry 0.013 0.00053 1 *8260B 7/16/15 17:25 MSC P5G0262 Chloroform BRL mg/kg dry 0.0063 0.00046 1 *8260B 7/16/15 17:25 MSC P5G0262 Chloromethane BRL mg/kg dry 0.0063 0.00043 1 *8260B 7/16/15 17:25 MSC P5G0262 cis-1,2-Dichloroethylene BRL mg/kg dry 0.0063 0.00027 1 *8260B 7/16/15 17:25 MSC P5G0262 cis-1,3-Dichloropropylene BRL mg/kg dry 0.0063 0.00021 1 *8260B 7/16/15 17:25 MSC P5G0262 Dibromochloromethane BRL mg/kg dry 0.0063 0.00026 1 *8260B 7/16/15 17:25 MSC P5G0262 Dichlorodifluoromethane BRL mg/kg dry 0.0063 0.00029 1 *8260B 7/16/15 17:25 MSC P5G0262 Ethylbenzene BRL mg/kg dry 0.0063 0.00024 1 *8260B 7/16/15 17:25 MSC P5G0262 Isopropyl Ether BRL mg/kg dry 0.0063 0.00026 1 *8260B 7/16/15 17:25 MSC P5G0262 Isopropylbenzene (Cumene) BRL mg/kg dry 0.0063 0.00038 1 *8260B 7/16/15 17:25 MSC P5G0262 m,p-Xylenes BRL mg/kg dry 0.013 0.00058 1 *8260B 7/16/15 17:25 MSC P5G0262 Methyl Butyl Ketone (2-Hexanone) BRL mg/kg dry 0.063 0.00057 1 *8260B 7/16/15 17:25 MSC P5G0262 Methyl Ethyl Ketone (2-Butanone) BRL mg/kg dry 0.13 0.00057 1 *8260B 7/16/15 17:25 MSC P5G0262 Methyl Isobutyl Ketone BRL mg/kg dry 0.063 0.00054 1 *8260B 7/16/15 17:25 MSC P5G0262 Methylene Chloride BRL mg/kg dry 0.0063 0.00036 1 *8260B 7/16/15 17:25 MSC P5G0262 Methyl-tert-Butyl Ether BRL mg/kg dry 0.013 0.00020 1 *8260B 7/16/15 17:25 MSC P5G0262 Naphthalene BRL mg/kg dry 0.013 0.00020 1 *8260B 7/16/15 17:25 MSC P5G0262 n-Butylbenzene BRL mg/kg dry 0.0063 0.00032 1 *8260B 7/16/15 17:25 MSC P5G0262 n-Propylbenzene BRL mg/kg dry 0.0063 0.00038 1 *8260B 7/16/15 17:25 MSC P5G0262 o-Xylene BRL mg/kg dry 0.0063 0.00026 1 *8260B 7/16/15 17:25 MSC P5G0262 sec-Butylbenzene BRL mg/kg dry 0.0063 0.00031 1 *8260B 7/16/15 17:25 MSC P5G0262 Styrene BRL mg/kg dry 0.0063 0.00038 1 *8260B 7/16/15 17:25 MSC P5G0262 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 14 of 66 PR I S M Full -Service Analytical Environmental Solutions LABORATORIES INC. Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-4A Sample Matrix: Solid Laboratory Report 07/22/2015 Client Sample ID: SB-5 (0-2) Prism Sample ID: 5070164-03 Prism Work Order: 5070164 Time Collected: 07/07/15 12:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID tert-Butylbenzene BRL mg/kg dry 0.0063 0.00021 1 Tetrachloroethylene BRL mg/kg dry 0.0063 0.00030 1 Toluene BRL mg/kg dry 0.0063 0.00036 1 trans-1,2-Dichloroethylene BRL mg/kg dry 0.0063 0.00038 1 trans-1,3-Dichloropropylene BRL mg/kg dry 0.0063 0.00033 1 Trichloroethylene BRL mg/kg dry 0.0063 0.00041 1 Trichlorofluoromethane BRL mg/kg dry 0.0063 0.00041 1 Vinyl acetate BRL A mg/kg dry 0.032 0.00087 1 Vinyl chloride BRL mg/kg dry 0.0063 0.00031 1 Xylenes, total BRL mg/kg dry 0.019 0.0012 1 Surrogate *8260B 7/16/15 17:25 MSC P5G0262 *8260B 7/16/15 17:25 MSC P5130262 *8260B 7/16/15 17:25 MSC P5130262 *8260B 7/16/15 17:25 MSC P5130262 *8260B 7/16/15 17:25 MSC P5G0262 *8260B 7/16/15 17:25 MSC P5G0262 *8260B 7/16/15 17:25 MSC P5G0262 *8260B 7/16/15 17:25 MSC P5G0262 *8260B 7/16/15 17:25 MSC P5G0262 *8260B 7/16/15 17:25 MSC P5G0262 Recovery Control Limits 4-Bromofluorobenzene 124 % 70-130 Dibromofluoromethane 107 % 84-123 Toluene-d8 98 % 76-129 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 15 of 66 P R S M Laboratory Report ` Full -Service Analytical & / Environmental Solutions 07/22/2015 LABORATORIES INC. Hart & Hickman (Charlotte) Project: PTR.001-4A Client Sample ID: S13-16 (8-10) Attn: Aaron Oswald Prism Sample ID: 5070164-04 2923 South Tryon St. Ste 100 Prism Work Order: 5070164 Charlotte, NC 28203 Sample Matrix: Solid Time Collected: 07/08/15 14:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters % Solids 85.2 % by 0.100 0.100 1 *SM2540 G 7/13/15 11:55 ARC P5G0176 Weight Semivolatile Organic Compounds by GC/MS 1,2,4-Trichlorobenzene BRL mg/kg dry 0.39 0.060 1 *8270D 7/13/15 22:58 JMV P5G0175 1,2-Dichlorobenzene BRL mg/kg dry 0.39 0.059 1 *8270D 7/13/15 22:58 JMV P5G0175 1,3-Dichlorobenzene BRL mg/kg dry 0.39 0.055 1 *8270D 7/13/15 22:58 JMV P5G0175 1,4-Dichlorobenzene BRL mg/kg dry 0.39 0.057 1 *8270D 7/13/15 22:58 JMV P5G0175 1-Methyl naphthalene BRL mg/kg dry 0.39 0.075 1 *8270D 7/13/15 22:58 JMV P5G0175 2,4,6-Trichlorophenol BRL mg/kg dry 0.39 0.073 1 *8270D 7/13/15 22:58 JMV P5G0175 2,4-Dichlorophenol BRL mg/kg dry 0.39 0.075 1 *8270D 7/13/15 22:58 JMV P5G0175 2,4-Dimethylphenol BRL mg/kg dry 0.39 0.059 1 *8270D 7/13/15 22:58 JMV P5G0175 2,4-Dinitrophenol BRL mg/kg dry 0.39 0.054 1 *8270D 7/13/15 22:58 JMV P5G0175 2,4-Dinitrotoluene BRL mg/kg dry 0.39 0.047 1 *8270D 7/13/15 22:58 JMV P5G0175 2,6-Dinitrotoluene BRL mg/kg dry 0.39 0.052 1 *8270D 7/13/15 22:58 JMV P5G0175 2-Chloronaphthalene BRL mg/kg dry 0.39 0.056 1 *8270D 7/13/15 22:58 JMV P5G0175 2-Chlorophenol BRL mg/kg dry 0.39 0.055 1 *8270D 7/13/15 22:58 JMV P5G0175 2-Methyl naphthalene 0.58 mg/kg dry 0.39 0.062 1 *8270D 7113/15 22:58 JMV P5G0175 2-Methylphenol BRL mg/kg dry 0.39 0.050 1 *8270D 7/13/15 22:58 JMV P5G0175 2-Nitrophenol BRL mg/kg dry 0.39 0.071 1 *8270D 7/13/15 22:58 JMV P5G0175 3,3'-Dichlorobenzidine BRL mg/kg dry 0.39 0.077 1 *8270D 7/13/15 22:58 JMV P5G0175 3/4-Methyl phenol BRL mg/kg dry 0.39 0.048 1 *8270D 7/13/15 22:58 JMV P5G0175 4,6-Dinitro-2-methylphenol BRL mg/kg dry 0.39 0.058 1 *8270D 7/13/15 22:58 JMV P5G0175 4-Bromophenyl phenyl ether BRL mg/kg dry 0.39 0.067 1 *8270D 7/13/15 22:58 JMV P5G0175 4-Chloro-3-methylphenol BRL mg/kg dry 0.39 0.054 1 *8270D 7/13/15 22:58 JMV P5G0175 4-Chloroaniline BRL mg/kg dry 0.39 0.047 1 *8270D 7/13/15 22:58 JMV P5G0175 4-Chlorophenyl phenyl ether BRL mg/kg dry 0.39 0.050 1 *8270D 7/13/15 22:58 JMV P5G0175 4-Nitrophenol BRL mg/kg dry 0.39 0.060 1 *8270D 7/13/15 22:58 JMV P5G0175 Acenaphthene BRL mg/kg dry 0.39 0.053 1 *8270D 7/13/15 22:58 JMV P5G0175 Acenaphthylene 0.77 mg/kg dry 0.39 0.056 1 *8270D 7/13/15 22:58 JMV P5G0175 Anthracene 0.52 mg/kg dry 0.39 0.062 1 *8270D 7/13/15 22:58 JMV P5G0175 Azobenzene BRL mg/kg dry 0.39 0.051 1 *8270D 7/13/15 22:58 JMV P5G0175 Benzo(a)anthrace ne 1.6 mg/kg dry 0.39 0.051 1 *8270D 7/13/15 22:58 JMV P5G0175 Benzo(a)pyrene 3.0 mg/kg dry 0.39 0.042 1 *8270D 7113/15 22:58 JMV P5G0175 Benzo(b)fluoranthene 2.3 mg/kg dry 0.39 0.045 1 *8270D 7/13/15 22:58 JMV P5G0175 Benzo(g,hJ)perylene 2.6 mg/kg dry 0.39 0.042 1 *8270D 7/13/15 22:58 JMV P5G0175 Benzo(k)fluoranthene 0.58 mg/kg dry 0.39 0.051 1 *8270D 7/13/15 22:58 JMV P5G0175 Benzoic Acid BRL mg/kg dry 0.39 0.033 1 *8270D 7/13/15 22:58 JMV P5G0175 Benzyl alcohol BRL mg/kg dry 0.39 0.051 1 *8270D 7/13/15 22:58 JMV P5G0175 bis(2-Chloroethoxy)methane BRL mg/kg dry 0.39 0.067 1 *8270D 7/13/15 22:58 JMV P5G0175 Bis(2-Chloroethyl)ether BRL mg/kg dry 0.39 0.055 1 *8270D 7/13/15 22:58 JMV P5G0175 Bis(2-chloroisopropyl)ether BRL mg/kg dry 0.39 0.066 1 *8270D 7/13/15 22:58 JMV P5G0175 Bis(2-Ethylhexyl)phthalate BRL mg/kg dry 0.39 0.057 1 *8270D 7/13/15 22:58 JMV P5G0175 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 16 of 66 Laboratory Report ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. 07/22/2015 Hart & Hickman (Charlotte) Project: PTR.001-4A Client Sample ID: S13-16 (8-10) Attn: Aaron Oswald Prism Sample ID: 5070164-04 2923 South Tryon St. Ste 100 Prism Work Order: 5070164 Charlotte, NC 28203 Sample Matrix: Solid Time Collected: 07/08/15 14:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Butyl benzyl phthalate BRL mg/kg dry 0.39 0.055 1 *8270D 7/13/15 22:58 JMV P5G0175 Chrysene 1.7 mg/kg dry 0.39 0.049 1 *8270D 7113/15 22:58 JMV P5G0175 Dibenzo(a,h)anthracene 0.39 mg/kg dry 0.39 0.047 1 *8270D 7/13/15 22:58 JMV P5G0175 Dibenzofuran BRL mg/kg dry 0.39 0.059 1 *8270D 7/13/15 22:58 JMV P5G0175 Diethyl phthalate BRL mg/kg dry 0.39 0.053 1 *8270D 7/13/15 22:58 JMV P5G0175 Dimethyl phthalate BRL mg/kg dry 0.39 0.051 1 *8270D 7/13/15 22:58 JMV P5G0175 Di-n-butyl phthalate BRL mg/kg dry 0.39 0.055 1 *8270D 7/13/15 22:58 JMV P5G0175 Di-n-octyl phthalate BRL mg/kg dry 0.39 0.048 1 *8270D 7/13/15 22:58 JMV P5G0175 Fluoranthene 1.8 mg/kg dry 0.39 0.049 1 *8270D 7113/15 22:58 JMV P5G0175 Fluorene BRL mg/kg dry 0.39 0.056 1 *8270D 7/13/15 22:58 JMV P5G0175 Hexachlorobenzene BRL mg/kg dry 0.39 0.061 1 *8270D 7/13/15 22:58 JMV P5G0175 Hexachlorobutadiene BRL mg/kg dry 0.39 0.070 1 *8270D 7/13/15 22:58 JMV P5G0175 Hexachlorocyclopentadiene BRL mg/kg dry 0.39 0.069 1 *8270D 7/13/15 22:58 JMV P5G0175 Hexachloroethane BRL mg/kg dry 0.39 0.065 1 *8270D 7/13/15 22:58 JMV P5G0175 Indeno(1,2,3-cd)pyrene 1.6 mg/kg dry 0.39 0.044 1 *8270D 7/13/15 22:58 JMV P5G0175 Isophorone BRL mg/kg dry 0.39 0.052 1 *8270D 7/13/15 22:58 JMV P5G0175 Naphthalene 1.2 mg/kg dry 0.39 0.062 1 *8270D 7113/15 22:58 JMV P5G0175 Nitrobenzene BRL mg/kg dry 0.39 0.055 1 *8270D 7/13/15 22:58 JMV P5G0175 N-Nitroso-di-n-propylamine BRL mg/kg dry 0.39 0.061 1 *8270D 7/13/15 22:58 JMV P5G0175 N-Nitrosodiphenylamine BRL mg/kg dry 0.39 0.059 1 *8270D 7/13/15 22:58 JMV P5G0175 Pentachlorophenol BRL mg/kg dry 0.39 0.046 1 *8270D 7/13/15 22:58 JMV P5G0175 Phenanthrene 1.9 mg/kg dry 0.39 0.050 1 *8270D 7/13/15 22:58 JMV P5G0175 Phenol BRL mg/kg dry 0.39 0.057 1 *8270D 7/13/15 22:58 JMV P5G0175 Pyrene 4.1 mg/kg dry 0.39 0.051 1 *8270D 7/13/15 22:58 JMV P5G0175 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 89 % 39-132 2-Fluorobiphenyl 79 % 44-115 2-Fluorophenol 68 % 35-115 Nitrobenzene-d5 69 % 37-122 Phenol-d5 68 % 34-121 Terphenyl-d14 84 % 54-127 Total Metals Mercury 0.20 mg/kg dry 0.023 0.0015 1 *7471B 7113/15 13:03 JAB P5G0173 Arsenic 3.4 mg/kg dry 0.30 0.042 1 *6010C 7/13/15 18:07 BGM P5G0172 Barium 160 mg/kg dry 0.59 0.11 1 *6010C 7/13/15 18:07 BGM P5G0172 Cadmium BRL mg/kg dry 0.30 0.042 1 *6010C 7/13/15 18:07 BGM P5G0172 Chromium 16 mg/kg dry 0.30 0.049 1 *6010C 7/13/15 18:07 BGM P5G0172 Lead 110 mg/kg dry 0.30 0.045 1 *6010C 7/13/15 18:07 BGM P5G0172 Selenium BRL mg/kg dry 0.59 0.071 1 *6010C 7/13/15 18:07 BGM P5G0172 Silver BRL mg/kg dry 0.30 0.034 1 *6010C 7/13/15 18:07 BGM P5G0172 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL mg/kg dry 0.0051 0.00042 1 *8260B 7/16/15 17:56 MSC P5G0262 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 17 of 66 ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-4A Sample Matrix: Solid Laboratory Report 07/22/2015 Client Sample ID: S13-16 (8-10) Prism Sample ID: 5070164-04 Prism Work Order: 5070164 Time Collected: 07/08/15 14:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,1,1-Trichloroethane BRL mg/kg dry 0.0051 0.00025 1 *8260B 7/16/15 17:56 MSC P5G0262 1,1,2,2-Tetrachloroethane BRL mg/kg dry 0.0051 0.00034 1 *8260B 7/16/15 17:56 MSC P5G0262 1,1,2-Trichloroethane BRL mg/kg dry 0.0051 0.00045 1 *8260B 7/16/15 17:56 MSC P5G0262 1,1-Dichloroethane BRL mg/kg dry 0.0051 0.00014 1 *8260B 7/16/15 17:56 MSC P5G0262 1,1-Dichloroethylene BRL mg/kg dry 0.0051 0.00022 1 *8260B 7/16/15 17:56 MSC P5G0262 1,1-Dichloropropylene BRL mg/kg dry 0.0051 0.00028 1 *8260B 7/16/15 17:56 MSC P5G0262 1,2,3-Trichlorobenzene BRL mg/kg dry 0.0051 0.00029 1 *8260B 7/16/15 17:56 MSC P5G0262 1,2,3-Trichloropropane BRL mg/kg dry 0.0051 0.00065 1 *8260B 7/16/15 17:56 MSC P5G0262 1,2,4-Trichlorobenzene BRL mg/kg dry 0.0051 0.00038 1 *8260B 7/16/15 17:56 MSC P5G0262 1,2,4-Trimethyl benzene BRL mg/kg dry 0.0051 0.00039 1 *8260B 7/16/15 17:56 MSC P5G0262 1,2-Dibromoethane BRL mg/kg dry 0.0051 0.00020 1 *8260B 7/16/15 17:56 MSC P5G0262 1,2-Dichlorobenzene BRL mg/kg dry 0.0051 0.00024 1 *8260B 7/16/15 17:56 MSC P5G0262 1,2-Dichloroethane BRL mg/kg dry 0.0051 0.00030 1 *8260B 7/16/15 17:56 MSC P5G0262 1,2-Dichloropropane BRL mg/kg dry 0.0051 0.00031 1 *8260B 7/16/15 17:56 MSC P5G0262 1,3,5-Trimethyl benzene BRL mg/kg dry 0.0051 0.00038 1 *8260B 7/16/15 17:56 MSC P5G0262 1,3-Dichlorobenzene BRL mg/kg dry 0.0051 0.00034 1 *8260B 7/16/15 17:56 MSC P5G0262 1,3-Dichloropropane BRL mg/kg dry 0.0051 0.00025 1 *8260B 7/16/15 17:56 MSC P5G0262 1,4-Dichlorobenzene BRL mg/kg dry 0.0051 0.00020 1 *8260B 7/16/15 17:56 MSC P5G0262 2,2-Dichloropropane BRL mg/kg dry 0.0051 0.00024 1 *8260B 7/16/15 17:56 MSC P5G0262 2-Chlorotoluene BRL mg/kg dry 0.0051 0.00026 1 *8260B 7/16/15 17:56 MSC P5G0262 4-Chlorotoluene BRL mg/kg dry 0.0051 0.00030 1 *8260B 7/16/15 17:56 MSC P5G0262 4-Isopropyltoluene BRL mg/kg dry 0.0051 0.00024 1 *8260B 7/16/15 17:56 MSC P5G0262 Acetone BRL mg/kg dry 0.051 0.0012 1 *8260B 7/16/15 17:56 MSC P5G0262 Benzene BRL mg/kg dry 0.0030 0.00030 1 *8260B 7/16/15 17:56 MSC P5G0262 Bromobenzene BRL mg/kg dry 0.0051 0.00042 1 *8260B 7/16/15 17:56 MSC P5G0262 Bromochloromethane BRL mg/kg dry 0.0051 0.00028 1 *8260B 7/16/15 17:56 MSC P5G0262 Bromodichloromethane BRL mg/kg dry 0.0051 0.00028 1 *8260B 7/16/15 17:56 MSC P5G0262 Bromoform BRL mg/kg dry 0.0051 0.00058 1 *8260B 7/16/15 17:56 MSC P5G0262 Bromomethane BRL mg/kg dry 0.010 0.00063 1 *8260B 7/16/15 17:56 MSC P5G0262 Carbon Tetrachloride BRL mg/kg dry 0.0051 0.00025 1 *8260B 7/16/15 17:56 MSC P5G0262 Chlorobenzene BRL mg/kg dry 0.0051 0.00027 1 *8260B 7/16/15 17:56 MSC P5G0262 Chloroethane BRL mg/kg dry 0.010 0.00042 1 *8260B 7/16/15 17:56 MSC P5G0262 Chloroform BRL mg/kg dry 0.0051 0.00037 1 *8260B 7/16/15 17:56 MSC P5G0262 Chloromethane BRL mg/kg dry 0.0051 0.00034 1 *8260B 7/16/15 17:56 MSC P5G0262 cis-1,2-Dichloroethylene BRL mg/kg dry 0.0051 0.00022 1 *8260B 7/16/15 17:56 MSC P5G0262 cis-1,3-Dichloropropylene BRL mg/kg dry 0.0051 0.00017 1 *8260B 7/16/15 17:56 MSC P5G0262 Dibromochloromethane BRL mg/kg dry 0.0051 0.00021 1 *8260B 7/16/15 17:56 MSC P5G0262 Dichlorodifluoromethane BRL mg/kg dry 0.0051 0.00023 1 *8260B 7/16/15 17:56 MSC P5G0262 Ethylbenzene BRL mg/kg dry 0.0051 0.00019 1 *8260B 7/16/15 17:56 MSC P5G0262 Isopropyl Ether BRL mg/kg dry 0.0051 0.00021 1 *8260B 7/16/15 17:56 MSC P5G0262 Isopropylbenzene (Cumene) BRL mg/kg dry 0.0051 0.00030 1 *8260B 7/16/15 17:56 MSC P5G0262 m,p-Xylenes BRL mg/kg dry 0.010 0.00047 1 *8260B 7/16/15 17:56 MSC P5G0262 Methyl Butyl Ketone (2-Hexanone) BRL mg/kg dry 0.051 0.00046 1 *8260B 7/16/15 17:56 MSC P5G0262 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 18 of 66 P R S M Laboratory Report ` Full -Service Analytical & / Environmental Solutions 07/22/2015 LABORATORIES INC. Hart & Hickman (Charlotte) Project: PTR.001-4A Client Sample ID: S13-16 (8-10) Attn: Aaron Oswald Prism Sample ID: 5070164-04 2923 South Tryon St. Ste 100 Prism Work Order: 5070164 Charlotte, NC 28203 Sample Matrix: Solid Time Collected: 07/08/15 14:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Date/Time Analyst Batch ID Methyl Ethyl Ketone (2-Butanone) BRL mg/kg dry 0.10 0.00046 1 *8260B 7/16/15 17:56 MSC P5G0262 Methyl Isobutyl Ketone BRL mg/kg dry 0.051 0.00043 1 *8260B 7/16/15 17:56 MSC P5G0262 Methylene Chloride BRL mg/kg dry 0.0051 0.00029 1 *8260B 7/16/15 17:56 MSC P5G0262 Methyl-tert-Butyl Ether BRL mg/kg dry 0.010 0.00016 1 *8260B 7/16/15 17:56 MSC P5G0262 Naphthalene BRL mg/kg dry 0.010 0.00016 1 *8260B 7/16/15 17:56 MSC P5G0262 n-Butylbenzene BRL mg/kg dry 0.0051 0.00026 1 *8260B 7/16/15 17:56 MSC P5G0262 n-Propylbenzene BRL mg/kg dry 0.0051 0.00030 1 *8260B 7/16/15 17:56 MSC P5G0262 o-Xylene BRL mg/kg dry 0.0051 0.00021 1 *8260B 7/16/15 17:56 MSC P5G0262 sec-Butylbenzene BRL mg/kg dry 0.0051 0.00025 1 *8260B 7/16/15 17:56 MSC P5G0262 Styrene BRL mg/kg dry 0.0051 0.00031 1 *8260B 7/16/15 17:56 MSC P5G0262 tert-Butylbenzene BRL mg/kg dry 0.0051 0.00017 1 *8260B 7/16/15 17:56 MSC P5G0262 Tetrachloroethylene BRL mg/kg dry 0.0051 0.00024 1 *8260B 7/16/15 17:56 MSC P5G0262 Toluene BRL mg/kg dry 0.0051 0.00029 1 *8260B 7/16/15 17:56 MSC P5G0262 trans-1,2-Dichloroethylene BRL mg/kg dry 0.0051 0.00030 1 *8260B 7/16/15 17:56 MSC P5G0262 trans-1,3-Dichloropropylene BRL mg/kg dry 0.0051 0.00027 1 *8260B 7/16/15 17:56 MSC P5G0262 Trichloroethylene BRL mg/kg dry 0.0051 0.00033 1 *8260B 7/16/15 17:56 MSC P5G0262 Trichlorofluoromethane BRL mg/kg dry 0.0051 0.00033 1 *8260B 7/16/15 17:56 MSC P5G0262 Vinyl acetate BRL A mg/kg dry 0.025 0.00070 1 *8260B 7/16/15 17:56 MSC P5G0262 Vinyl chloride BRL mg/kg dry 0.0051 0.00025 1 *8260B 7/16/15 17:56 MSC P5G0262 Xylenes, total BRL mg/kg dry 0.015 0.00095 1 *8260B 7/16/15 17:56 MSC P5G0262 Surrogate Recovery Control Limits 4-Bromofluorobenzene 126 % 70-130 Dibromofluoromethane 103 % 84-123 Toluene-d8 102 % 76-129 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 19 of 66 PR I S M Full -Service Analytical Environmental Solutions LABORATORIES INC. Laboratory Report 07/22/2015 Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-4A Client Sample ID: TMW-5 Prism Sample ID: 5070164-05 Prism Work Order: 5070164 Sample Matrix: Water Time Collected: 07/08/15 10:30 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Semivolatile Organic Compounds by GC/MS 1,2,4-Trichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 12:18 JMV P5G0184 1,2-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 12:18 JMV P5G0184 1,3-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 12:18 JMV P5G0184 1,4-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 12:18 JMV P5G0184 1-Methyl naphthalene BRL ug/L 10 2.4 1 *8270D 7/16/15 12:18 JMV P5G0184 2,4,5-Trichlorophenol BRL ug/L 10 2.3 1 *8270D 7/16/15 12:18 JMV P5G0184 2,4,6-Trichlorophenol BRL ug/L 10 2.6 1 *8270D 7/16/15 12:18 JMV P5G0184 2,4-Dichlorophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 12:18 JMV P5G0184 2,4-Dimethylphenol BRL ug/L 10 2.3 1 *8270D 7/16/15 12:18 JMV P5G0184 2,4-Dinitrophenol BRL ug/L 10 3.7 1 *8270D 7/16/15 12:18 JMV P5G0184 2,4-Dinitrotoluene BRL ug/L 10 1.9 1 *8270D 7/16/15 12:18 JMV P5G0184 2,6-Dinitrotoluene BRL ug/L 10 2.0 1 *8270D 7/16/15 12:18 JMV P5G0184 2-Chloronaphthalene BRL ug/L 10 3.4 1 *8270D 7/16/15 12:18 JMV P5G0184 2-Chlorophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 12:18 JMV P5G0184 2-Methyl naphthalene BRL ug/L 10 2.2 1 *8270D 7/16/15 12:18 JMV P5G0184 2-Methylphenol BRL ug/L 10 2.1 1 *8270D 7/16/15 12:18 JMV P5G0184 2-Nitroaniline BRL ug/L 10 2.2 1 *8270D 7/16/15 12:18 JMV P5G0184 2-Nitrophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 12:18 JMV P5G0184 3,3'-Dichlorobenzidine BRL ug/L 10 2.2 1 *8270D 7/16/15 12:18 JMV P5G0184 3/4-Methyl phenol BRL ug/L 10 1.9 1 *8270D 7/16/15 12:18 JMV P5G0184 3-Nitroaniline BRL ug/L 10 1.2 1 *8270D 7/16/15 12:18 JMV P5G0184 4,6-Dinitro-2-methylphenol BRL ug/L 10 2.4 1 *8270D 7/16/15 12:18 JMV P5G0184 4-Bromophenyl phenyl ether BRL ug/L 10 1.8 1 *8270D 7/16/15 12:18 JMV P5G0184 4-Chloro-3-methylphenol BRL ug/L 10 1.9 1 *8270D 7/16/15 12:18 JMV P5G0184 4-Chloroaniline BRL ug/L 10 1.8 1 *8270D 7/16/15 12:18 JMV P5G0184 4-Chlorophenyl phenyl ether BRL ug/L 10 2.0 1 *8270D 7/16/15 12:18 JMV P5G0184 4-Nitroaniline BRL ug/L 10 2.0 1 *8270D 7/16/15 12:18 JMV P5G0184 4-Nitrophenol BRL ug/L 10 0.66 1 *8270D 7/16/15 12:18 JMV P5G0184 Acenaphthene BRL ug/L 10 2.5 1 *8270D 7/16/15 12:18 JMV P5G0184 Acenaphthylene BRL ug/L 10 2.5 1 *8270D 7/16/15 12:18 JMV P5G0184 Aniline BRL ug/L 10 2.1 1 *8270D 7/16/15 12:18 JMV P5G0184 Anthracene BRL ug/L 10 3.0 1 *8270D 7/16/15 12:18 JMV P5G0184 Azobenzene BRL ug/L 10 1.8 1 *8270D 7/16/15 12:18 JMV P5G0184 Benzo(a)anthracene BRL ug/L 10 2.0 1 *8270D 7/16/15 12:18 JMV P5G0184 Benzo(a)pyrene BRL ug/L 10 2.4 1 *8270D 7/16/15 12:18 JMV P5G0184 Benzo(b)fluoranthene BRL ug/L 10 1.4 1 *8270D 7/16/15 12:18 JMV P5G0184 Benzo(g,h,i)perylene BRL ug/L 10 1.8 1 *8270D 7/16/15 12:18 JMV P5G0184 Benzo(k)fluoranthene BRL ug/L 10 2.4 1 *8270D 7/16/15 12:18 JMV P5G0184 Benzoic Acid BRL ug/L 100 2.7 1 *8270D 7/16/15 12:18 JMV P5G0184 Benzyl alcohol BRL ug/L 10 1.8 1 *8270D 7/16/15 12:18 JMV P5G0184 bis(2-Chloroethoxy)methane BRL ug/L 10 2.2 1 *8270D 7/16/15 12:18 JMV P5G0184 Bis(2-Chloroethyl)ether BRL ug/L 10 2.4 1 *8270D 7/16/15 12:18 JMV P5G0184 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 20 of 66 Laboratory Report ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. 07/22/2015 Hart & Hickman (Charlotte) Project: PTR.001-4A Client Sample ID: TMW-5 Attn: Aaron Oswald Prism Sample ID: 5070164-05 2923 South Tryon St. Ste 100 Prism Work Order: 5070164 Charlotte, NC 28203 Sample Matrix: Water Time Collected: 07/08/15 10:30 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Bis(2-chloroisopropyl)ether BRL ug/L 10 2.2 1 *8270D 7/16/15 12:18 JMV P5G0184 Bis(2-Ethylhexyl)phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 12:18 JMV P5G0184 Butyl benzyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 12:18 JMV P5G0184 Chrysene BRL ug/L 10 2.2 1 *8270D 7/16/15 12:18 JMV P5G0184 Dibenzo(a,h)anthracene BRL ug/L 10 2.0 1 *8270D 7/16/15 12:18 JMV P5G0184 Dibenzofuran BRL ug/L 10 2.3 1 *8270D 7/16/15 12:18 JMV P5G0184 Diethyl phthalate BRL ug/L 10 1.9 1 *8270D 7/16/15 12:18 JMV P5G0184 Dimethyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 12:18 JMV P5G0184 Di-n-butyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 12:18 JMV P5G0184 Di-n-octyl phthalate BRL ug/L 10 1.7 1 *8270D 7/16/15 12:18 JMV P5G0184 Fluoranthene BRL ug/L 10 2.2 1 *8270D 7/16/15 12:18 JMV P5G0184 Fluorene BRL ug/L 10 2.5 1 *8270D 7/16/15 12:18 JMV P5G0184 Hexachlorobenzene BRL ug/L 10 1.9 1 *8270D 7/16/15 12:18 JMV P5G0184 Hexachlorobutadiene BRL ug/L 10 2.6 1 *8270D 7/16/15 12:18 JMV P5G0184 Hexachlorocyclopentadiene BRL ug/L 10 2.2 1 *8270D 7/16/15 12:18 JMV P5G0184 Hexachloroethane BRL ug/L 10 2.5 1 *8270D 7/16/15 12:18 JMV P5G0184 Indeno(1,2,3-cd)pyrene BRL ug/L 10 2.1 1 *8270D 7/16/15 12:18 JMV P5G0184 Isophorone BRL ug/L 10 2.5 1 *8270D 7/16/15 12:18 JMV P5G0184 Naphthalene BRL ug/L 10 2.4 1 *8270D 7/16/15 12:18 JMV P5G0184 Nitrobenzene BRL ug/L 10 2.4 1 *8270D 7/16/15 12:18 JMV P5G0184 N-Nitroso-di-n-propylamine BRL ug/L 10 2.5 1 *8270D 7/16/15 12:18 JMV P5G0184 N-Nitrosodiphenylamine BRL ug/L 10 1.8 1 *8270D 7/16/15 12:18 JMV P5G0184 Pentachlorophenol BRL ug/L 10 2.5 1 *8270D 7/16/15 12:18 JMV P5G0184 Phenanthrene BRL ug/L 10 1.8 1 *8270D 7/16/15 12:18 JMV P5G0184 Phenol BRL ug/L 10 1.2 1 *8270D 7/16/15 12:18 JMV P5G0184 Pyrene BRL ug/L 10 2.2 1 *8270D 7/16/15 12:18 JMV P5G0184 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 96 % 49-109 2-Fluorobiphenyl 88 % 55-96 2-Fluorophenol 50 % 27-74 Nitrobenzene-d5 77 % 53-99 Phenol-d5 33 % 11-52 Terphenyl-d14 96 % 42-133 Total Metals Mercury BRL mg/L 0.00020 0.000011 1 *7470A 7/14/15 13:31 JAB P5G0189 Arsenic BRL mg/L 0.010 0.00070 1 *6010C 7/14/15 17:27 BGM P5G0170 Barium 0.094 mg/L 0.010 0.00070 1 *6010C 7114/15 17:27 BGM P5G0170 Cadmium BRL mg/L 0.0010 0.00010 1 *6010C 7/14/15 17:27 BGM P5G0170 Chromium BRL mg/L 0.0050 0.00060 1 *6010C 7/14/15 17:27 BGM P5G0170 Lead BRL mg/L 0.0050 0.0013 1 *6010C 7/14/15 17:27 BGM P5G0170 Selenium BRL mg/L 0.020 0.0032 1 *6010C 7/14/15 17:27 BGM P5G0170 Silver BRL mg/L 0.0050 0.00020 1 *6010C 7/14/15 17:27 BGM P5G0170 Volatile Organic Compounds by GC/MS This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 21 of 66 ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-4A Sample Matrix: Water Laboratory Report 07/22/2015 Client Sample ID: TMW-5 Prism Sample ID: 5070164-05 Prism Work Order: 5070164 Time Collected: 07/08/15 10:30 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,1,1,2-Tetrachloroethane BRL ug/L 0.50 0.11 1 *8260B 7/14/15 21:44 MSC P5G0244 1,1,1-Trichloroethane BRL ug/L 0.50 0.061 1 *8260B 7/14/15 21:44 MSC P5G0244 1,1,2,2-Tetrachloroethane BRL ug/L 0.50 0.036 1 *8260B 7/14/15 21:44 MSC P5G0244 1,1,2-Trichloroethane BRL ug/L 0.50 0.066 1 *8260B 7/14/15 21:44 MSC P5G0244 1,1-Dichloroethane BRL ug/L 0.50 0.083 1 *8260B 7/14/15 21:44 MSC P5G0244 1,1-Dichloroethylene BRL ug/L 0.50 0.083 1 *8260B 7/14/15 21:44 MSC P5G0244 1,1-Dichloropropylene BRL ug/L 0.50 0.051 1 *8260B 7/14/15 21:44 MSC P5G0244 1,2,3-Trichlorobenzene BRL ug/L 2.0 0.40 1 *8260B 7/14/15 21:44 MSC P5G0244 1,2,3-Trichloropropane BRL ug/L 1.0 0.14 1 *8260B 7/14/15 21:44 MSC P5G0244 1,2,4-Trichlorobenzene BRL ug/L 1.0 0.13 1 *8260B 7/14/15 21:44 MSC P5G0244 1,2,4-Trimethyl benzene BRL ug/L 0.50 0.054 1 *8260B 7/14/15 21:44 MSC P5G0244 1,2-Dibromo-3-chloropropane BRL ug/L 2.0 0.17 1 *8260B 7/14/15 21:44 MSC P5G0244 1,2-Dibromoethane BRL ug/L 0.50 0.051 1 *8260B 7/14/15 21:44 MSC P5G0244 1,2-Dichlorobenzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 21:44 MSC P5G0244 1,2-Dichloroethane BRL ug/L 0.50 0.066 1 *8260B 7/14/15 21:44 MSC P5G0244 1,2-Dichloropropane BRL ug/L 0.50 0.11 1 *8260B 7/14/15 21:44 MSC P5G0244 1,3,5-Trimethyl benzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 21:44 MSC P5G0244 1,3-Dichlorobenzene BRL ug/L 0.50 0.054 1 *8260B 7/14/15 21:44 MSC P5G0244 1,3-Dichloropropane BRL ug/L 0.50 0.043 1 *8260B 7/14/15 21:44 MSC P5G0244 1,4-Dichlorobenzene BRL ug/L 0.50 0.050 1 *8260B 7/14/15 21:44 MSC P5G0244 2,2-Dichloropropane BRL ug/L 2.0 0.11 1 *8260B 7/14/15 21:44 MSC P5G0244 2-Chloroethyl Vinyl Ether BRL ug/L 5.0 0.37 1 *8260B 7/14/15 21:44 MSC P5G0244 2-Chlorotoluene BRL ug/L 0.50 0.066 1 *8260B 7/14/15 21:44 MSC P5G0244 4-Chlorotoluene BRL ug/L 0.50 0.050 1 *8260B 7/14/15 21:44 MSC P5G0244 4-Isopropyltoluene BRL ug/L 0.50 0.089 1 *8260B 7/14/15 21:44 MSC P5G0244 Acetone BRL ug/L 5.0 0.31 1 *8260B 7/14/15 21:44 MSC P5G0244 Acrolein BRL ug/L 20 0.20 1 *8260B 7/14/15 21:44 MSC P5G0244 Acrylonitrile BRL ug/L 20 0.20 1 *8260B 7/14/15 21:44 MSC P5G0244 Benzene BRL ug/L 0.50 0.048 1 *8260B 7/14/15 21:44 MSC P5G0244 Bromobenzene BRL ug/L 0.50 0.057 1 *8260B 7/14/15 21:44 MSC P5G0244 Bromochloromethane BRL ug/L 0.50 0.14 1 *8260B 7/14/15 21:44 MSC P5G0244 Bromodichloromethane BRL ug/L 0.50 0.062 1 *8260B 7/14/15 21:44 MSC P5G0244 Bromoform BRL ug/L 1.0 0.040 1 *8260B 7/14/15 21:44 MSC P5G0244 Bromomethane BRL ug/L 1.0 0.18 1 *8260B 7/14/15 21:44 MSC P5G0244 Carbon disulfide BRL ug/L 5.0 0.075 1 *8260B 7/14/15 21:44 MSC P5G0244 Carbon Tetrachloride BRL ug/L 0.50 0.11 1 *8260B 7/14/15 21:44 MSC P5G0244 Chlorobenzene BRL ug/L 0.50 0.062 1 *8260B 7/14/15 21:44 MSC P5G0244 Chloroethane BRL ug/L 0.50 0.22 1 *8260B 7/14/15 21:44 MSC P5G0244 Chloroform BRL ug/L 0.50 0.076 1 *8260B 7/14/15 21:44 MSC P5G0244 Chloromethane BRL ug/L 0.50 0.079 1 *8260B 7/14/15 21:44 MSC P5G0244 cis-1,2-Dichloroethylene BRL ug/L 0.50 0.056 1 *8260B 7/14/15 21:44 MSC P5G0244 cis-1,3-Dichloropropylene BRL ug/L 0.50 0.079 1 *8260B 7/14/15 21:44 MSC P5G0244 Dibromochloromethane BRL ug/L 0.50 0.081 1 *8260B 7/14/15 21:44 MSC P5G0244 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 22 of 66 P R S M Laboratory Report ` Full -Service Analytical & / Environmental Solutions 07/22/2015 LABORATORIES INC. Hart & Hickman (Charlotte) Project: PTR.001-4A Client Sample ID: TMW-5 Attn: Aaron Oswald Prism Sample ID: 5070164-05 2923 South Tryon St. Ste 100 Prism Work Order: 5070164 Charlotte, NC 28203 Sample Matrix: Water Time Collected: 07/08/15 10:30 Time Submitted: 07/10/15 08:50 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Date/Time Analyst Batch ID Dibromomethane BRL ug/L 0.50 0.065 1 *8260B 7/14/15 21:44 MSC P5G0244 Dichlorodifluoromethane BRL ug/L 1.0 0.11 1 *8260B 7/14/15 21:44 MSC P5G0244 Ethylbenzene BRL ug/L 0.50 0.061 1 *8260B 7/14/15 21:44 MSC P5G0244 Hexachlorobutadiene BRL ug/L 2.0 0.16 1 *8260B 7/14/15 21:44 MSC P5G0244 Isopropyl Ether BRL ug/L 0.50 0.050 1 *8260B 7/14/15 21:44 MSC P5G0244 Isopropylbenzene (Cumene) BRL ug/L 0.50 0.054 1 *8260B 7/14/15 21:44 MSC P5G0244 m,p-Xylenes BRL ug/L 1.0 0.12 1 *8260B 7/14/15 21:44 MSC P5G0244 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 5.0 0.065 1 *8260B 7/14/15 21:44 MSC P5G0244 Methyl Ethyl Ketone (2-Butanone) BRL ug/L 5.0 0.24 1 *8260B 7/14/15 21:44 MSC P5G0244 Methyl Isobutyl Ketone BRL ug/L 5.0 0.078 1 *8260B 7/14/15 21:44 MSC P5G0244 Methylene Chloride BRL ug/L 1.0 0.083 1 *8260B 7/14/15 21:44 MSC P5G0244 Methyl-tert-Butyl Ether BRL ug/L 0.50 0.042 1 *8260B 7/14/15 21:44 MSC P5G0244 Naphthalene BRL ug/L 1.0 0.19 1 *8260B 7/14/15 21:44 MSC P5G0244 n-Butylbenzene BRL ug/L 1.0 0.076 1 *8260B 7/14/15 21:44 MSC P5G0244 n-Propylbenzene BRL ug/L 0.50 0.087 1 *8260B 7/14/15 21:44 MSC P5G0244 o-Xylene BRL ug/L 0.50 0.044 1 *8260B 7/14/15 21:44 MSC P5G0244 sec-Butylbenzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 21:44 MSC P5G0244 Styrene BRL ug/L 0.50 0.047 1 *8260B 7/14/15 21:44 MSC P5G0244 tert-Butylbenzene BRL ug/L 0.50 0.088 1 *8260B 7/14/15 21:44 MSC P5G0244 Tetrachloroethylene BRL ug/L 0.50 0.098 1 *8260B 7/14/15 21:44 MSC P5G0244 Toluene BRL ug/L 0.50 0.044 1 *8260B 7/14/15 21:44 MSC P5G0244 trans-1,2-Dichloroethylene BRL ug/L 0.50 0.094 1 *8260B 7/14/15 21:44 MSC P5G0244 trans-1,3-Dichloropropylene BRL ug/L 0.50 0.070 1 *8260B 7/14/15 21:44 MSC P5G0244 Trichloroethylene BRL ug/L 0.50 0.078 1 *8260B 7/14/15 21:44 MSC P5G0244 Trichlorofluoromethane BRL ug/L 0.50 0.062 1 *8260B 7/14/15 21:44 MSC P5G0244 Vinyl acetate BRL ug/L 2.0 0.060 1 *8260B 7/14/15 21:44 MSC P5G0244 Vinyl chloride BRL ug/L 0.50 0.097 1 *8260B 7/14/15 21:44 MSC P5G0244 Surrogate Recovery Control Limits 4-Bromofluorobenzene 91 % 80-124 Dibromofluoromethane 109 % 75-129 Toluene-d8 90 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 23 of 66 PR I S M Full -Service Analytical Environmental Solutions LABORATORIES INC. Laboratory Report 07/22/2015 Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-4A Client Sample ID: TMW-6 Prism Sample ID: 5070164-06 Prism Work Order: 5070164 Sample Matrix: Water Time Collected: 07/08/15 16:30 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Semivolatile Organic Compounds by GC/MS 1,2,4-Trichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 12:39 JMV P5G0184 1,2-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 12:39 JMV P5G0184 1,3-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 12:39 JMV P5G0184 1,4-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 12:39 JMV P5G0184 1-Methyl naphthalene BRL ug/L 10 2.4 1 *8270D 7/16/15 12:39 JMV P5G0184 2,4,5-Trichlorophenol BRL ug/L 10 2.3 1 *8270D 7/16/15 12:39 JMV P5G0184 2,4,6-Trichlorophenol BRL ug/L 10 2.6 1 *8270D 7/16/15 12:39 JMV P5G0184 2,4-Dichlorophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 12:39 JMV P5G0184 2,4-Dimethylphenol BRL ug/L 10 2.3 1 *8270D 7/16/15 12:39 JMV P5G0184 2,4-Dinitrophenol BRL ug/L 10 3.7 1 *8270D 7/16/15 12:39 JMV P5G0184 2,4-Dinitrotoluene BRL ug/L 10 1.9 1 *8270D 7/16/15 12:39 JMV P5G0184 2,6-Dinitrotoluene BRL ug/L 10 2.0 1 *8270D 7/16/15 12:39 JMV P5G0184 2-Chloronaphthalene BRL ug/L 10 3.4 1 *8270D 7/16/15 12:39 JMV P5G0184 2-Chlorophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 12:39 JMV P5G0184 2-Methyl naphthalene BRL ug/L 10 2.2 1 *8270D 7/16/15 12:39 JMV P5G0184 2-Methylphenol BRL ug/L 10 2.1 1 *8270D 7/16/15 12:39 JMV P5G0184 2-Nitroaniline BRL ug/L 10 2.2 1 *8270D 7/16/15 12:39 JMV P5G0184 2-Nitrophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 12:39 JMV P5G0184 3,3'-Dichlorobenzidine BRL ug/L 10 2.2 1 *8270D 7/16/15 12:39 JMV P5G0184 3/4-Methyl phenol BRL ug/L 10 1.9 1 *8270D 7/16/15 12:39 JMV P5G0184 3-Nitroaniline BRL ug/L 10 1.2 1 *8270D 7/16/15 12:39 JMV P5G0184 4,6-Dinitro-2-methylphenol BRL ug/L 10 2.4 1 *8270D 7/16/15 12:39 JMV P5G0184 4-Bromophenyl phenyl ether BRL ug/L 10 1.8 1 *8270D 7/16/15 12:39 JMV P5G0184 4-Chloro-3-methylphenol BRL ug/L 10 1.9 1 *8270D 7/16/15 12:39 JMV P5G0184 4-Chloroaniline BRL ug/L 10 1.8 1 *8270D 7/16/15 12:39 JMV P5G0184 4-Chlorophenyl phenyl ether BRL ug/L 10 2.0 1 *8270D 7/16/15 12:39 JMV P5G0184 4-Nitroaniline BRL ug/L 10 2.0 1 *8270D 7/16/15 12:39 JMV P5G0184 4-Nitrophenol BRL ug/L 10 0.66 1 *8270D 7/16/15 12:39 JMV P5G0184 Acenaphthene BRL ug/L 10 2.5 1 *8270D 7/16/15 12:39 JMV P5G0184 Acenaphthylene BRL ug/L 10 2.5 1 *8270D 7/16/15 12:39 JMV P5G0184 Aniline BRL ug/L 10 2.1 1 *8270D 7/16/15 12:39 JMV P5G0184 Anthracene BRL ug/L 10 3.0 1 *8270D 7/16/15 12:39 JMV P5G0184 Azobenzene BRL ug/L 10 1.8 1 *8270D 7/16/15 12:39 JMV P5G0184 Benzo(a)anthracene BRL ug/L 10 2.0 1 *8270D 7/16/15 12:39 JMV P5G0184 Benzo(a)pyrene BRL ug/L 10 2.4 1 *8270D 7/16/15 12:39 JMV P5G0184 Benzo(b)fluoranthene BRL ug/L 10 1.4 1 *8270D 7/16/15 12:39 JMV P5G0184 Benzo(g,h,i)perylene BRL ug/L 10 1.8 1 *8270D 7/16/15 12:39 JMV P5G0184 Benzo(k)fluoranthene BRL ug/L 10 2.4 1 *8270D 7/16/15 12:39 JMV P5G0184 Benzoic Acid BRL ug/L 100 2.7 1 *8270D 7/16/15 12:39 JMV P5G0184 Benzyl alcohol BRL ug/L 10 1.8 1 *8270D 7/16/15 12:39 JMV P5G0184 bis(2-Chloroethoxy)methane BRL ug/L 10 2.2 1 *8270D 7/16/15 12:39 JMV P5G0184 Bis(2-Chloroethyl)ether BRL ug/L 10 2.4 1 *8270D 7/16/15 12:39 JMV P5G0184 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 24 of 66 Laboratory Report ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. 07/22/2015 Hart & Hickman (Charlotte) Project: PTR.001-4A Client Sample ID: TMW-6 Attn: Aaron Oswald Prism Sample ID: 5070164-06 2923 South Tryon St. Ste 100 Prism Work Order: 5070164 Charlotte, NC 28203 Sample Matrix: Water Time Collected: 07/08/15 16:30 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Bis(2-chloroisopropyl)ether BRL ug/L 10 2.2 1 *8270D 7/16/15 12:39 JMV P5G0184 Bis(2-Ethylhexyl)phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 12:39 JMV P5G0184 Butyl benzyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 12:39 JMV P5G0184 Chrysene BRL ug/L 10 2.2 1 *8270D 7/16/15 12:39 JMV P5G0184 Dibenzo(a,h)anthracene BRL ug/L 10 2.0 1 *8270D 7/16/15 12:39 JMV P5G0184 Dibenzofuran BRL ug/L 10 2.3 1 *8270D 7/16/15 12:39 JMV P5G0184 Diethyl phthalate BRL ug/L 10 1.9 1 *8270D 7/16/15 12:39 JMV P5G0184 Dimethyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 12:39 JMV P5G0184 Di-n-butyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 12:39 JMV P5G0184 Di-n-octyl phthalate BRL ug/L 10 1.7 1 *8270D 7/16/15 12:39 JMV P5G0184 Fluoranthene BRL ug/L 10 2.2 1 *8270D 7/16/15 12:39 JMV P5G0184 Fluorene BRL ug/L 10 2.5 1 *8270D 7/16/15 12:39 JMV P5G0184 Hexachlorobenzene BRL ug/L 10 1.9 1 *8270D 7/16/15 12:39 JMV P5G0184 Hexachlorobutadiene BRL ug/L 10 2.6 1 *8270D 7/16/15 12:39 JMV P5G0184 Hexachlorocyclopentadiene BRL ug/L 10 2.2 1 *8270D 7/16/15 12:39 JMV P5G0184 Hexachloroethane BRL ug/L 10 2.5 1 *8270D 7/16/15 12:39 JMV P5G0184 Indeno(1,2,3-cd)pyrene BRL ug/L 10 2.1 1 *8270D 7/16/15 12:39 JMV P5G0184 Isophorone BRL ug/L 10 2.5 1 *8270D 7/16/15 12:39 JMV P5G0184 Naphthalene BRL ug/L 10 2.4 1 *8270D 7/16/15 12:39 JMV P5G0184 Nitrobenzene BRL ug/L 10 2.4 1 *8270D 7/16/15 12:39 JMV P5G0184 N-Nitroso-di-n-propylamine BRL ug/L 10 2.5 1 *8270D 7/16/15 12:39 JMV P5G0184 N-Nitrosodiphenylamine BRL ug/L 10 1.8 1 *8270D 7/16/15 12:39 JMV P5G0184 Pentachlorophenol BRL ug/L 10 2.5 1 *8270D 7/16/15 12:39 JMV P5G0184 Phenanthrene BRL ug/L 10 1.8 1 *8270D 7/16/15 12:39 JMV P5G0184 Phenol BRL ug/L 10 1.2 1 *8270D 7/16/15 12:39 JMV P5G0184 Pyrene BRL ug/L 10 2.2 1 *8270D 7/16/15 12:39 JMV P5G0184 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 23 % 49-109 2-Fluorobiphenyl 20 % 55-96 SE 2-Fluorophenol 21 % 27-74 SE Nitrobenzene-d5 17 % 53-99 SE Phenol-d5 16 % 11-52 Terphenyl-d14 24 % 42-133 SE Total Metals Mercury BRL mg/L 0.00020 0.000011 1 *7470A 7/14/15 13:35 JAB P5G0189 Arsenic BRL mg/L 0.010 0.00070 1 *6010C 7/14/15 17:46 BGM P5130170 Barium 0.52 mg/L 0.010 0.00070 1 *6010C 7114/15 17:46 BGM P5G0170 Cadmium BRL mg/L 0.0010 0.00010 1 *6010C 7/14/15 17:46 BGM P5G0170 Chromium BRL mg/L 0.0050 0.00060 1 *6010C 7/14/15 17:46 BGM P5130170 Lead BRL mg/L 0.0050 0.0013 1 *6010C 7/14/15 17:46 BGM P5130170 Selenium BRL mg/L 0.020 0.0032 1 *6010C 7/14/15 17:46 BGM P5130170 Silver BRL mg/L 0.0050 0.00020 1 *6010C 7/14/15 17:46 BGM P5130170 Volatile Organic Compounds by GC/MS This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 25 of 66 ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-4A Sample Matrix: Water Laboratory Report 07/22/2015 Client Sample ID: TMW-6 Prism Sample ID: 5070164-06 Prism Work Order: 5070164 Time Collected: 07/08/15 16:30 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,1,1,2-Tetrachloroethane BRL ug/L 0.50 0.11 1 *8260B 7/14/15 22:18 MSC P5G0244 1,1,1-Trichloroethane BRL ug/L 0.50 0.061 1 *8260B 7/14/15 22:18 MSC P5G0244 1,1,2,2-Tetrachloroethane BRL ug/L 0.50 0.036 1 *8260B 7/14/15 22:18 MSC P5G0244 1,1,2-Trichloroethane BRL ug/L 0.50 0.066 1 *8260B 7/14/15 22:18 MSC P5G0244 1,1-Dichloroethane BRL ug/L 0.50 0.083 1 *8260B 7/14/15 22:18 MSC P5G0244 1,1-Dichloroethylene BRL ug/L 0.50 0.083 1 *8260B 7/14/15 22:18 MSC P5G0244 1,1-Dichloropropylene BRL ug/L 0.50 0.051 1 *8260B 7/14/15 22:18 MSC P5G0244 1,2,3-Trichlorobenzene BRL ug/L 2.0 0.40 1 *8260B 7/14/15 22:18 MSC P5G0244 1,2,3-Trichloropropane BRL ug/L 1.0 0.14 1 *8260B 7/14/15 22:18 MSC P5G0244 1,2,4-Trichlorobenzene BRL ug/L 1.0 0.13 1 *8260B 7/14/15 22:18 MSC P5G0244 1,2,4-Trimethyl benzene BRL ug/L 0.50 0.054 1 *8260B 7/14/15 22:18 MSC P5G0244 1,2-Dibromo-3-chloropropane BRL ug/L 2.0 0.17 1 *8260B 7/14/15 22:18 MSC P5G0244 1,2-Dibromoethane BRL ug/L 0.50 0.051 1 *8260B 7/14/15 22:18 MSC P5G0244 1,2-Dichlorobenzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 22:18 MSC P5G0244 1,2-Dichloroethane BRL ug/L 0.50 0.066 1 *8260B 7/14/15 22:18 MSC P5G0244 1,2-Dichloropropane BRL ug/L 0.50 0.11 1 *8260B 7/14/15 22:18 MSC P5G0244 1,3,5-Trimethyl benzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 22:18 MSC P5G0244 1,3-Dichlorobenzene BRL ug/L 0.50 0.054 1 *8260B 7/14/15 22:18 MSC P5G0244 1,3-Dichloropropane BRL ug/L 0.50 0.043 1 *8260B 7/14/15 22:18 MSC P5G0244 1,4-Dichlorobenzene BRL ug/L 0.50 0.050 1 *8260B 7/14/15 22:18 MSC P5G0244 2,2-Dichloropropane BRL ug/L 2.0 0.11 1 *8260B 7/14/15 22:18 MSC P5G0244 2-Chloroethyl Vinyl Ether BRL ug/L 5.0 0.37 1 *8260B 7/14/15 22:18 MSC P5G0244 2-Chlorotoluene BRL ug/L 0.50 0.066 1 *8260B 7/14/15 22:18 MSC P5G0244 4-Chlorotoluene BRL ug/L 0.50 0.050 1 *8260B 7/14/15 22:18 MSC P5G0244 4-Isopropyltoluene BRL ug/L 0.50 0.089 1 *8260B 7/14/15 22:18 MSC P5G0244 Acetone BRL ug/L 5.0 0.31 1 *8260B 7/14/15 22:18 MSC P5G0244 Acrolein BRL ug/L 20 0.20 1 *8260B 7/14/15 22:18 MSC P5G0244 Acrylonitrile BRL ug/L 20 0.20 1 *8260B 7/14/15 22:18 MSC P5G0244 Benzene BRL ug/L 0.50 0.048 1 *8260B 7/14/15 22:18 MSC P5G0244 Bromobenzene BRL ug/L 0.50 0.057 1 *8260B 7/14/15 22:18 MSC P5G0244 Bromochloromethane BRL ug/L 0.50 0.14 1 *8260B 7/14/15 22:18 MSC P5G0244 Bromodichloromethane BRL ug/L 0.50 0.062 1 *8260B 7/14/15 22:18 MSC P5G0244 Bromoform BRL ug/L 1.0 0.040 1 *8260B 7/14/15 22:18 MSC P5G0244 Bromomethane BRL ug/L 1.0 0.18 1 *8260B 7/14/15 22:18 MSC P5G0244 Carbon disulfide BRL ug/L 5.0 0.075 1 *8260B 7/14/15 22:18 MSC P5G0244 Carbon Tetrachloride BRL ug/L 0.50 0.11 1 *8260B 7/14/15 22:18 MSC P5G0244 Chlorobenzene BRL ug/L 0.50 0.062 1 *8260B 7/14/15 22:18 MSC P5G0244 Chloroethane BRL ug/L 0.50 0.22 1 *8260B 7/14/15 22:18 MSC P5G0244 Chloroform BRL ug/L 0.50 0.076 1 *8260B 7/14/15 22:18 MSC P5G0244 Chloromethane BRL ug/L 0.50 0.079 1 *8260B 7/14/15 22:18 MSC P5G0244 cis-1,2-Dichloroethylene BRL ug/L 0.50 0.056 1 *8260B 7/14/15 22:18 MSC P5G0244 cis-1,3-Dichloropropylene BRL ug/L 0.50 0.079 1 *8260B 7/14/15 22:18 MSC P5G0244 Dibromochloromethane BRL ug/L 0.50 0.081 1 *8260B 7/14/15 22:18 MSC P5G0244 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 26 of 66 P R S M Laboratory Report ` Full -Service Analytical & / Environmental Solutions 07/22/2015 LABORATORIES INC. Hart & Hickman (Charlotte) Project: PTR.001-4A Client Sample ID: TMW-6 Attn: Aaron Oswald Prism Sample ID: 5070164-06 2923 South Tryon St. Ste 100 Prism Work Order: 5070164 Charlotte, NC 28203 Sample Matrix: Water Time Collected: 07/08/15 16:30 Time Submitted: 07/10/15 08:50 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID Dibromomethane BRL ug/L 0.50 0.065 1 *8260B 7/14/15 22:18 MSC P5G0244 Dichlorodifluoromethane BRL ug/L 1.0 0.11 1 *8260B 7/14/15 22:18 MSC P5G0244 Ethylbenzene BRL ug/L 0.50 0.061 1 *8260B 7/14/15 22:18 MSC P5G0244 Hexachlorobutadiene BRL ug/L 2.0 0.16 1 *8260B 7/14/15 22:18 MSC P5G0244 Isopropyl Ether BRL ug/L 0.50 0.050 1 *8260B 7/14/15 22:18 MSC P5G0244 Isopropylbenzene (Cumene) BRL ug/L 0.50 0.054 1 *8260B 7/14/15 22:18 MSC P5G0244 m,p-Xylenes BRL ug/L 1.0 0.12 1 *8260B 7/14/15 22:18 MSC P5G0244 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 5.0 0.065 1 *8260B 7/14/15 22:18 MSC P5G0244 Methyl Ethyl Ketone (2-Butanone) BRL ug/L 5.0 0.24 1 *8260B 7/14/15 22:18 MSC P5G0244 Methyl Isobutyl Ketone BRL ug/L 5.0 0.078 1 *8260B 7/14/15 22:18 MSC P5G0244 Methylene Chloride BRL ug/L 1.0 0.083 1 *8260B 7/14/15 22:18 MSC P5G0244 Methyl-tert-Butyl Ether BRL ug/L 0.50 0.042 1 *8260B 7/14/15 22:18 MSC P5G0244 Naphthalene BRL ug/L 1.0 0.19 1 *8260B 7/14/15 22:18 MSC P5G0244 n-Butylbenzene BRL ug/L 1.0 0.076 1 *8260B 7/14/15 22:18 MSC P5G0244 n-Propylbenzene BRL ug/L 0.50 0.087 1 *8260B 7/14/15 22:18 MSC P5G0244 o-Xylene BRL ug/L 0.50 0.044 1 *8260B 7/14/15 22:18 MSC P5G0244 sec-Butylbenzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 22:18 MSC P5G0244 Styrene BRL ug/L 0.50 0.047 1 *8260B 7/14/15 22:18 MSC P5G0244 tert-Butylbenzene BRL ug/L 0.50 0.088 1 *8260B 7/14/15 22:18 MSC P5G0244 Tetrachloroethylene BRL ug/L 0.50 0.098 1 *8260B 7/14/15 22:18 MSC P5G0244 Toluene BRL ug/L 0.50 0.044 1 *8260B 7/14/15 22:18 MSC P5G0244 trans-1,2-Dichloroethylene BRL ug/L 0.50 0.094 1 *8260B 7/14/15 22:18 MSC P5G0244 trans-1,3-Dichloropropylene BRL ug/L 0.50 0.070 1 *8260B 7/14/15 22:18 MSC P5G0244 Trichloroethylene BRL ug/L 0.50 0.078 1 *8260B 7/14/15 22:18 MSC P5G0244 Trichlorofluoromethane BRL ug/L 0.50 0.062 1 *8260B 7/14/15 22:18 MSC P5G0244 Vinyl acetate BRL ug/L 2.0 0.060 1 *8260B 7/14/15 22:18 MSC P5G0244 Vinyl chloride BRL ug/L 0.50 0.097 1 *8260B 7/14/15 22:18 MSC P5G0244 Surrogate Recovery Control Limits 4-Bromofluorobenzene 93 % 80-124 Dibromofluoromethane 103 % 75-129 Toluene-d8 96 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 27 of 66 PR I S M Full -Service Analytical Environmental Solutions LABORATORIES INC. Laboratory Report 07/22/2015 Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-4A Client Sample ID: TMW-7 Prism Sample ID: 5070164-07 Prism Work Order: 5070164 Sample Matrix: Water Time Collected: 07/09/15 09:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Semivolatile Organic Compounds by GC/MS 1,2,4-Trichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 13:00 JMV P5G0184 1,2-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 13:00 JMV P5G0184 1,3-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 13:00 JMV P5G0184 1,4-Dichlorobenzene BRL ug/L 10 2.5 1 *8270D 7/16/15 13:00 JMV P5G0184 1-Methyl naphthalene BRL ug/L 10 2.4 1 *8270D 7/16/15 13:00 JMV P5G0184 2,4,5-Trichlorophenol BRL ug/L 10 2.3 1 *8270D 7/16/15 13:00 JMV P5G0184 2,4,6-Trichlorophenol BRL ug/L 10 2.6 1 *8270D 7/16/15 13:00 JMV P5G0184 2,4-Dichlorophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 13:00 JMV P5G0184 2,4-Dimethylphenol BRL ug/L 10 2.3 1 *8270D 7/16/15 13:00 JMV P5G0184 2,4-Dinitrophenol BRL ug/L 10 3.7 1 *8270D 7/16/15 13:00 JMV P5G0184 2,4-Dinitrotoluene BRL ug/L 10 1.9 1 *8270D 7/16/15 13:00 JMV P5G0184 2,6-Dinitrotoluene BRL ug/L 10 2.0 1 *8270D 7/16/15 13:00 JMV P5G0184 2-Chloronaphthalene BRL ug/L 10 3.4 1 *8270D 7/16/15 13:00 JMV P5G0184 2-Chlorophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 13:00 JMV P5G0184 2-Methyl naphthalene BRL ug/L 10 2.2 1 *8270D 7/16/15 13:00 JMV P5G0184 2-Methylphenol BRL ug/L 10 2.1 1 *8270D 7/16/15 13:00 JMV P5G0184 2-Nitroaniline BRL ug/L 10 2.2 1 *8270D 7/16/15 13:00 JMV P5G0184 2-Nitrophenol BRL ug/L 10 2.4 1 *8270D 7/16/15 13:00 JMV P5G0184 3,3'-Dichlorobenzidine BRL ug/L 10 2.2 1 *8270D 7/16/15 13:00 JMV P5G0184 3/4-Methyl phenol BRL ug/L 10 1.9 1 *8270D 7/16/15 13:00 JMV P5G0184 3-Nitroaniline BRL ug/L 10 1.2 1 *8270D 7/16/15 13:00 JMV P5G0184 4,6-Dinitro-2-methylphenol BRL ug/L 10 2.4 1 *8270D 7/16/15 13:00 JMV P5G0184 4-Bromophenyl phenyl ether BRL ug/L 10 1.8 1 *8270D 7/16/15 13:00 JMV P5G0184 4-Chloro-3-methylphenol BRL ug/L 10 1.9 1 *8270D 7/16/15 13:00 JMV P5G0184 4-Chloroaniline BRL ug/L 10 1.8 1 *8270D 7/16/15 13:00 JMV P5G0184 4-Chlorophenyl phenyl ether BRL ug/L 10 2.0 1 *8270D 7/16/15 13:00 JMV P5G0184 4-Nitroaniline BRL ug/L 10 2.0 1 *8270D 7/16/15 13:00 JMV P5G0184 4-Nitrophenol BRL ug/L 10 0.66 1 *8270D 7/16/15 13:00 JMV P5G0184 Acenaphthene BRL ug/L 10 2.5 1 *8270D 7/16/15 13:00 JMV P5G0184 Acenaphthylene BRL ug/L 10 2.5 1 *8270D 7/16/15 13:00 JMV P5G0184 Aniline BRL ug/L 10 2.1 1 *8270D 7/16/15 13:00 JMV P5G0184 Anthracene BRL ug/L 10 3.0 1 *8270D 7/16/15 13:00 JMV P5G0184 Azobenzene BRL ug/L 10 1.8 1 *8270D 7/16/15 13:00 JMV P5G0184 Benzo(a)anthracene BRL ug/L 10 2.0 1 *8270D 7/16/15 13:00 JMV P5G0184 Benzo(a)pyrene BRL ug/L 10 2.4 1 *8270D 7/16/15 13:00 JMV P5G0184 Benzo(b)fluoranthene BRL ug/L 10 1.4 1 *8270D 7/16/15 13:00 JMV P5G0184 Benzo(g,h,i)perylene BRL ug/L 10 1.8 1 *8270D 7/16/15 13:00 JMV P5G0184 Benzo(k)fluoranthene BRL ug/L 10 2.4 1 *8270D 7/16/15 13:00 JMV P5G0184 Benzoic Acid BRL ug/L 100 2.7 1 *8270D 7/16/15 13:00 JMV P5G0184 Benzyl alcohol BRL ug/L 10 1.8 1 *8270D 7/16/15 13:00 JMV P5G0184 bis(2-Chloroethoxy)methane BRL ug/L 10 2.2 1 *8270D 7/16/15 13:00 JMV P5G0184 Bis(2-Chloroethyl)ether BRL ug/L 10 2.4 1 *8270D 7/16/15 13:00 JMV P5G0184 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 28 of 66 Laboratory Report ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. 07/22/2015 Hart & Hickman (Charlotte) Project: PTR.001-4A Client Sample ID: TMW-7 Attn: Aaron Oswald Prism Sample ID: 5070164-07 2923 South Tryon St. Ste 100 Prism Work Order: 5070164 Charlotte, NC 28203 Sample Matrix: Water Time Collected: 07/09/15 09:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Bis(2-chloroisopropyl)ether BRL ug/L 10 2.2 1 *8270D 7/16/15 13:00 JMV P5G0184 Bis(2-Ethylhexyl)phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 13:00 JMV P5G0184 Butyl benzyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 13:00 JMV P5G0184 Chrysene BRL ug/L 10 2.2 1 *8270D 7/16/15 13:00 JMV P5G0184 Dibenzo(a,h)anthracene BRL ug/L 10 2.0 1 *8270D 7/16/15 13:00 JMV P5G0184 Dibenzofuran BRL ug/L 10 2.3 1 *8270D 7/16/15 13:00 JMV P5G0184 Diethyl phthalate BRL ug/L 10 1.9 1 *8270D 7/16/15 13:00 JMV P5G0184 Dimethyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 13:00 JMV P5G0184 Di-n-butyl phthalate BRL ug/L 10 2.0 1 *8270D 7/16/15 13:00 JMV P5G0184 Di-n-octyl phthalate BRL ug/L 10 1.7 1 *8270D 7/16/15 13:00 JMV P5G0184 Fluoranthene BRL ug/L 10 2.2 1 *8270D 7/16/15 13:00 JMV P5G0184 Fluorene BRL ug/L 10 2.5 1 *8270D 7/16/15 13:00 JMV P5G0184 Hexachlorobenzene BRL ug/L 10 1.9 1 *8270D 7/16/15 13:00 JMV P5G0184 Hexachlorobutadiene BRL ug/L 10 2.6 1 *8270D 7/16/15 13:00 JMV P5G0184 Hexachlorocyclopentadiene BRL ug/L 10 2.2 1 *8270D 7/16/15 13:00 JMV P5G0184 Hexachloroethane BRL ug/L 10 2.5 1 *8270D 7/16/15 13:00 JMV P5G0184 Indeno(1,2,3-cd)pyrene BRL ug/L 10 2.1 1 *8270D 7/16/15 13:00 JMV P5G0184 Isophorone BRL ug/L 10 2.5 1 *8270D 7/16/15 13:00 JMV P5G0184 Naphthalene BRL ug/L 10 2.4 1 *8270D 7/16/15 13:00 JMV P5G0184 Nitrobenzene BRL ug/L 10 2.4 1 *8270D 7/16/15 13:00 JMV P5G0184 N-Nitroso-di-n-propylamine BRL ug/L 10 2.5 1 *8270D 7/16/15 13:00 JMV P5G0184 N-Nitrosodiphenylamine BRL ug/L 10 1.8 1 *8270D 7/16/15 13:00 JMV P5G0184 Pentachlorophenol BRL ug/L 10 2.5 1 *8270D 7/16/15 13:00 JMV P5G0184 Phenanthrene BRL ug/L 10 1.8 1 *8270D 7/16/15 13:00 JMV P5G0184 Phenol BRL ug/L 10 1.2 1 *8270D 7/16/15 13:00 JMV P5G0184 Pyrene BRL ug/L 10 2.2 1 *8270D 7/16/15 13:00 JMV P5G0184 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 113 % 49-109 SR 2-Fluorobiphenyl 111 % 55-96 SR 2-Fluorophenol 59 % 27-74 Nitrobenzene-d5 100 % 53-99 SR Phenol-d5 40 % 11-52 Terphenyl-d14 105 % 42-133 Total Metals Mercury BRL mg/L 0.00020 0.000011 1 *7470A 7/14/15 13:39 JAB P5G0189 Arsenic BRL mg/L 0.010 0.00070 1 *6010C 7/14/15 17:54 BGM P5130170 Barium 0.25 mg/L 0.010 0.00070 1 *6010C 7114/15 17:54 BGM P5G0170 Cadmium BRL mg/L 0.0010 0.00010 1 *6010C 7/14/15 17:54 BGM P5G0170 Chromium BRL mg/L 0.0050 0.00060 1 *6010C 7/14/15 17:54 BGM P5130170 Lead BRL mg/L 0.0050 0.0013 1 *6010C 7/14/15 17:54 BGM P5130170 Selenium BRL mg/L 0.020 0.0032 1 *6010C 7/14/15 17:54 BGM P5130170 Silver BRL mg/L 0.0050 0.00020 1 *6010C 7/14/15 17:54 BGM P5130170 Volatile Organic Compounds by GC/MS H1 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 29 of 66 ` Full -Service Analytical & / Environmental Solutions P R S M LABORATORIES INC. Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-4A Sample Matrix: Water Laboratory Report 07/22/2015 Client Sample ID: TMW-7 Prism Sample ID: 5070164-07 Prism Work Order: 5070164 Time Collected: 07/09/15 09:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,1,1,2-Tetrachloroethane BRL ug/L 0.50 0.11 1 *8260B 7/21/15 14:56 MSC P5G0393 1,1,1-Trichloroethane BRL ug/L 0.50 0.061 1 *8260B 7/21/15 14:56 MSC P5G0393 1,1,2,2-Tetrachloroethane BRL ug/L 0.50 0.036 1 *8260B 7/21/15 14:56 MSC P5G0393 1,1,2-Trichloroethane BRL ug/L 0.50 0.066 1 *8260B 7/21/15 14:56 MSC P5G0393 1,1-Dichloroethane BRL ug/L 0.50 0.083 1 *8260B 7/21/15 14:56 MSC P5G0393 1,1-Dichloroethylene BRL ug/L 0.50 0.083 1 *8260B 7/21/15 14:56 MSC P5G0393 1,1-Dichloropropylene BRL ug/L 0.50 0.051 1 *8260B 7/21/15 14:56 MSC P5G0393 1,2,3-Trichlorobenzene BRL ug/L 2.0 0.40 1 *8260B 7/21/15 14:56 MSC P5G0393 1,2,3-Trichloropropane BRL ug/L 1.0 0.14 1 *8260B 7/21/15 14:56 MSC P5G0393 1,2,4-Trichlorobenzene BRL ug/L 1.0 0.13 1 *8260B 7/21/15 14:56 MSC P5G0393 1,2,4-Trimethyl benzene BRL ug/L 0.50 0.054 1 *8260B 7/21/15 14:56 MSC P5G0393 1,2-Dibromo-3-chloropropane BRL ug/L 2.0 0.17 1 *8260B 7/21/15 14:56 MSC P5G0393 1,2-Dibromoethane BRL ug/L 0.50 0.051 1 *8260B 7/21/15 14:56 MSC P5G0393 1,2-Dichlorobenzene BRL ug/L 0.50 0.076 1 *8260B 7/21/15 14:56 MSC P5G0393 1,2-Dichloroethane BRL ug/L 0.50 0.066 1 *8260B 7/21/15 14:56 MSC P5G0393 1,2-Dichloropropane BRL ug/L 0.50 0.11 1 *8260B 7/21/15 14:56 MSC P5G0393 1,3,5-Trimethyl benzene BRL ug/L 0.50 0.076 1 *8260B 7/21/15 14:56 MSC P5G0393 1,3-Dichlorobenzene BRL ug/L 0.50 0.054 1 *8260B 7/21/15 14:56 MSC P5G0393 1,3-Dichloropropane BRL ug/L 0.50 0.043 1 *8260B 7/21/15 14:56 MSC P5G0393 1,4-Dichlorobenzene BRL ug/L 0.50 0.050 1 *8260B 7/21/15 14:56 MSC P5G0393 2,2-Dichloropropane BRL ug/L 2.0 0.11 1 *8260B 7/21/15 14:56 MSC P5G0393 2-Chloroethyl Vinyl Ether BRL CVL ug/L 5.0 0.37 1 *8260B 7/21/15 14:56 MSC P5G0393 2-Chlorotoluene BRL ug/L 0.50 0.066 1 *8260B 7/21/15 14:56 MSC P5G0393 4-Chlorotoluene BRL ug/L 0.50 0.050 1 *8260B 7/21/15 14:56 MSC P5G0393 4-Isopropyltoluene BRL ug/L 0.50 0.089 1 *8260B 7/21/15 14:56 MSC P5G0393 Acetone 54 ug/L 5.0 0.31 1 *8260B 7/21/15 14:56 MSC P5G0393 Acrolein BRL ug/L 20 0.20 1 *8260B 7/21/15 14:56 MSC P5G0393 Acrylonitrile BRL ug/L 20 0.20 1 *8260B 7/21/15 14:56 MSC P5G0393 Benzene BRL ug/L 0.50 0.048 1 *8260B 7/21/15 14:56 MSC P5G0393 Bromobenzene BRL ug/L 0.50 0.057 1 *8260B 7/21/15 14:56 MSC P5G0393 Bromochloromethane BRL ug/L 0.50 0.14 1 *8260B 7/21/15 14:56 MSC P5G0393 Bromodichloromethane BRL ug/L 0.50 0.062 1 *8260B 7/21/15 14:56 MSC P5G0393 Bromoform BRL ug/L 1.0 0.040 1 *8260B 7/21/15 14:56 MSC P5G0393 Bromomethane BRL ug/L 1.0 0.18 1 *8260B 7/21/15 14:56 MSC P5G0393 Carbon disulfide BRL ug/L 5.0 0.075 1 *8260B 7/21/15 14:56 MSC P5G0393 Carbon Tetrachloride BRL ug/L 0.50 0.11 1 *8260B 7/21/15 14:56 MSC P5G0393 Chlorobenzene BRL ug/L 0.50 0.062 1 *8260B 7/21/15 14:56 MSC P5G0393 Chloroethane BRL ug/L 0.50 0.22 1 *8260B 7/21/15 14:56 MSC P5G0393 Chloroform BRL ug/L 0.50 0.076 1 *8260B 7/21/15 14:56 MSC P5G0393 Chloromethane BRL ug/L 0.50 0.079 1 *8260B 7/21/15 14:56 MSC P5G0393 cis-1,2-Dichloroethylene BRL ug/L 0.50 0.056 1 *8260B 7/21/15 14:56 MSC P5G0393 cis-1,3-Dichloropropylene BRL ug/L 0.50 0.079 1 *8260B 7/21/15 14:56 MSC P5G0393 Dibromochloromethane BRL ug/L 0.50 0.081 1 *8260B 7/21/15 14:56 MSC P5G0393 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 30 of 66 P R S M Laboratory Report ` Full -Service Analytical & / Environmental Solutions 07/22/2015 LABORATORIES INC. Hart & Hickman (Charlotte) Project: PTR.001-4A Client Sample ID: TMW-7 Attn: Aaron Oswald Prism Sample ID: 5070164-07 2923 South Tryon St. Ste 100 Prism Work Order: 5070164 Charlotte, NC 28203 Sample Matrix: Water Time Collected: 07/09/15 09:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Date/Time Analyst Batch ID Dibromomethane BRL ug/L 0.50 0.065 1 *8260B 7/21/15 14:56 MSC P5G0393 Dichlorodifluoromethane BRL ug/L 1.0 0.11 1 *8260B 7/21/15 14:56 MSC P5G0393 Ethylbenzene BRL ug/L 0.50 0.061 1 *8260B 7/21/15 14:56 MSC P5G0393 Hexachlorobutadiene BRL ug/L 2.0 0.16 1 *8260B 7/21/15 14:56 MSC P5G0393 Isopropyl Ether BRL ug/L 0.50 0.050 1 *8260B 7/21/15 14:56 MSC P5G0393 Isopropylbenzene (Cumene) BRL ug/L 0.50 0.054 1 *8260B 7/21/15 14:56 MSC P5G0393 m,p-Xylenes BRL ug/L 1.0 0.12 1 *8260B 7/21/15 14:56 MSC P5G0393 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 5.0 0.065 1 *8260B 7/21/15 14:56 MSC P5G0393 Methyl Ethyl Ketone (2-Butanone) 12 ug/L 5.0 0.24 1 *8260B 7/21/15 14:56 MSC P5G0393 Methyl Isobutyl Ketone BRL ug/L 5.0 0.078 1 *8260B 7/21/15 14:56 MSC P5G0393 Methylene Chloride BRL ug/L 1.0 0.083 1 *8260B 7/21/15 14:56 MSC P5G0393 Methyl-tert-Butyl Ether BRL ug/L 0.50 0.042 1 *8260B 7/21/15 14:56 MSC P5G0393 Naphthalene BRL ug/L 1.0 0.19 1 *8260B 7/21/15 14:56 MSC P5G0393 n-Butylbenzene BRL ug/L 1.0 0.076 1 *8260B 7/21/15 14:56 MSC P5G0393 n-Propylbenzene BRL ug/L 0.50 0.087 1 *8260B 7/21/15 14:56 MSC P5G0393 o-Xylene BRL ug/L 0.50 0.044 1 *8260B 7/21/15 14:56 MSC P5G0393 sec-Butylbenzene BRL ug/L 0.50 0.076 1 *8260B 7/21/15 14:56 MSC P5G0393 Styrene BRL ug/L 0.50 0.047 1 *8260B 7/21/15 14:56 MSC P5G0393 tert-Butylbenzene BRL ug/L 0.50 0.088 1 *8260B 7/21/15 14:56 MSC P5G0393 Tetrachloroethylene BRL ug/L 0.50 0.098 1 *8260B 7/21/15 14:56 MSC P5G0393 Toluene BRL ug/L 0.50 0.044 1 *8260B 7/21/15 14:56 MSC P5G0393 trans-1,2-Dichloroethylene BRL ug/L 0.50 0.094 1 *8260B 7/21/15 14:56 MSC P5G0393 trans- 1,3-Dichloropropylene BRL ug/L 0.50 0.070 1 *8260B 7/21/15 14:56 MSC P5G0393 Trichloroethylene BRL ug/L 0.50 0.078 1 *8260B 7/21/15 14:56 MSC P5G0393 Trichlorofluoromethane BRL ug/L 0.50 0.062 1 *8260B 7/21/15 14:56 MSC P5G0393 Vinyl acetate BRL ug/L 2.0 0.060 1 *8260B 7/21/15 14:56 MSC P5G0393 Vinyl chloride BRL ug/L 0.50 0.097 1 *8260B 7/21/15 14:56 MSC P5G0393 Surrogate Recovery Control Limits 4-Bromofluorobenzene 89 % 80-124 Dibromofluoromethane 105 % 75-129 Toluene-d8 94 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 31 of 66 Laboratory Report ` Full -Service P R S M Analytical & / Environmental Solutions LABORATORIES INC. 07/22/2015 Hart & Hickman (Charlotte) Project: PTR.001-4A Client Sample ID: Dup-2 Attn: Aaron Oswald Prism Sample ID: 5070164-08 2923 South Tryon St. Ste 100 Prism Work Order: 5070164 Charlotte, NC 28203 Sample Matrix: Water Time Collected: 07/09/15 00:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Total Metals Mercury BRL mg/L 0.00020 0.000011 1 *7470A 7/14/15 13:43 JAB P5G0189 Arsenic BRL mg/L 0.010 0.00070 1 *6010C 7/14/15 18:02 BGM P5G0170 Barium 0.24 mg/L 0.010 0.00070 1 *6010C 7114/15 18:02 BGM P5G0170 Cadmium BRL mg/L 0.0010 0.00010 1 *6010C 7/14/15 18:02 BGM P5G0170 Chromium BRL mg/L 0.0050 0.00060 1 *6010C 7/14/15 18:02 BGM P5G0170 Lead BRL mg/L 0.0050 0.0013 1 *6010C 7/14/15 18:02 BGM P5G0170 Selenium BRL mg/L 0.020 0.0032 1 *6010C 7/14/15 18:02 BGM P5G0170 Silver BRL mg/L 0.0050 0.00020 1 *6010C 7/14/15 18:02 BGM P5G0170 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 32 of 66 PR I S M Full -Service Analytical Environmental Solutions LABORATORIES INC. Laboratory Report 07/22/2015 Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PTR.001-4A Client Sample ID: Trip Blank Prism Sample ID: 5070164-09 Prism Work Order: 5070164 Sample Matrix: Water Time Collected: 07/09/15 00:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL ug/L 0.50 0.11 1 *8260B 7/14/15 16:36 MSC P5G0244 1,1,1-Trichloroethane BRL ug/L 0.50 0.061 1 *8260B 7/14/15 16:36 MSC P5G0244 1,1,2,2-Tetrachloroethane BRL ug/L 0.50 0.036 1 *8260B 7/14/15 16:36 MSC P5G0244 1,1,2-Trichloroethane BRL ug/L 0.50 0.066 1 *8260B 7/14/15 16:36 MSC P5G0244 1,1-Dichloroethane BRL ug/L 0.50 0.083 1 *8260B 7/14/15 16:36 MSC P5G0244 1,1-Dichloroethylene BRL ug/L 0.50 0.083 1 *8260B 7/14/15 16:36 MSC P5G0244 1,1-Dichloropropylene BRL ug/L 0.50 0.051 1 *8260B 7/14/15 16:36 MSC P5G0244 1,2,3-Trichlorobenzene BRL ug/L 2.0 0.40 1 *8260B 7/14/15 16:36 MSC P5G0244 1,2,3-Trichloropropane BRL ug/L 1.0 0.14 1 *8260B 7/14/15 16:36 MSC P5G0244 1,2,4-Trichlorobenzene BRL ug/L 1.0 0.13 1 *8260B 7/14/15 16:36 MSC P5G0244 1,2,4-Trimethyl benzene BRL ug/L 0.50 0.054 1 *8260B 7/14/15 16:36 MSC P5G0244 1,2-Dibromo-3-chloropropane BRL ug/L 2.0 0.17 1 *8260B 7/14/15 16:36 MSC P5G0244 1,2-Dibromoethane BRL ug/L 0.50 0.051 1 *8260B 7/14/15 16:36 MSC P5G0244 1,2-Dichlorobenzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 16:36 MSC P5G0244 1,2-Dichloroethane BRL ug/L 0.50 0.066 1 *8260B 7/14/15 16:36 MSC P5G0244 1,2-Dichloropropane BRL ug/L 0.50 0.11 1 *8260B 7/14/15 16:36 MSC P5G0244 1,3,5-Trimethyl benzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 16:36 MSC P5G0244 1,3-Dichlorobenzene BRL ug/L 0.50 0.054 1 *8260B 7/14/15 16:36 MSC P5G0244 1,3-Dichloropropane BRL ug/L 0.50 0.043 1 *8260B 7/14/15 16:36 MSC P5G0244 1,4-Dichlorobenzene BRL ug/L 0.50 0.050 1 *8260B 7/14/15 16:36 MSC P5G0244 2,2-Dichloropropane BRL ug/L 2.0 0.11 1 *8260B 7/14/15 16:36 MSC P5G0244 2-Chloroethyl Vinyl Ether BRL ug/L 5.0 0.37 1 *8260B 7/14/15 16:36 MSC P5G0244 2-Chlorotoluene BRL ug/L 0.50 0.066 1 *8260B 7/14/15 16:36 MSC P5G0244 4-Chlorotoluene BRL ug/L 0.50 0.050 1 *8260B 7/14/15 16:36 MSC P5G0244 4-Isopropyltoluene BRL ug/L 0.50 0.089 1 *8260B 7/14/15 16:36 MSC P5G0244 Acetone BRL ug/L 5.0 0.31 1 *8260B 7/14/15 16:36 MSC P5G0244 Acrolein BRL ug/L 20 0.20 1 *8260B 7/14/15 16:36 MSC P5G0244 Acrylonitrile BRL ug/L 20 0.20 1 *8260B 7/14/15 16:36 MSC P5G0244 Benzene BRL ug/L 0.50 0.048 1 *8260B 7/14/15 16:36 MSC P5G0244 Bromobenzene BRL ug/L 0.50 0.057 1 *8260B 7/14/15 16:36 MSC P5G0244 Bromochloromethane BRL ug/L 0.50 0.14 1 *8260B 7/14/15 16:36 MSC P5G0244 Bromodichloromethane BRL ug/L 0.50 0.062 1 *8260B 7/14/15 16:36 MSC P5G0244 Bromoform BRL ug/L 1.0 0.040 1 *8260B 7/14/15 16:36 MSC P5G0244 Bromomethane BRL ug/L 1.0 0.18 1 *8260B 7/14/15 16:36 MSC P5G0244 Carbon disulfide BRL ug/L 5.0 0.075 1 *8260B 7/14/15 16:36 MSC P5G0244 Carbon Tetrachloride BRL ug/L 0.50 0.11 1 *8260B 7/14/15 16:36 MSC P5G0244 Chlorobenzene BRL ug/L 0.50 0.062 1 *8260B 7/14/15 16:36 MSC P5G0244 Chloroethane BRL ug/L 0.50 0.22 1 *8260B 7/14/15 16:36 MSC P5G0244 Chloroform BRL ug/L 0.50 0.076 1 *8260B 7/14/15 16:36 MSC P5G0244 Chloromethane BRL ug/L 0.50 0.079 1 *8260B 7/14/15 16:36 MSC P5G0244 cis-1,2-Dichloroethylene BRL ug/L 0.50 0.056 1 *8260B 7/14/15 16:36 MSC P5G0244 cis-1,3-Dichloropropylene BRL ug/L 0.50 0.079 1 *8260B 7/14/15 16:36 MSC P5G0244 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 33 of 66 P R S M Laboratory Report ` Full -Service Analytical & / Environmental Solutions 07/22/2015 LABORATORIES INC. Hart & Hickman (Charlotte) Project: PTR.001-4A Client Sample ID: Trip Blank Attn: Aaron Oswald Prism Sample ID: 5070164-09 2923 South Tryon St. Ste 100 Prism Work Order: 5070164 Charlotte, NC 28203 Sample Matrix: Water Time Collected: 07/09/15 00:00 Time Submitted: 07/10/15 08:50 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Date/Time Analyst Batch ID Dibromochloromethane BRL ug/L 0.50 0.081 1 *8260B 7/14/15 16:36 MSC P5G0244 Dibromomethane BRL ug/L 0.50 0.065 1 *8260B 7/14/15 16:36 MSC P5G0244 Dichlorodifluoromethane BRL ug/L 1.0 0.11 1 *8260B 7/14/15 16:36 MSC P5G0244 Ethylbenzene BRL ug/L 0.50 0.061 1 *8260B 7/14/15 16:36 MSC P5G0244 Hexachlorobutadiene BRL ug/L 2.0 0.16 1 *8260B 7/14/15 16:36 MSC P5G0244 Isopropyl Ether BRL ug/L 0.50 0.050 1 *8260B 7/14/15 16:36 MSC P5G0244 Isopropylbenzene (Cumene) BRL ug/L 0.50 0.054 1 *8260B 7/14/15 16:36 MSC P5G0244 m,p-Xylenes BRL ug/L 1.0 0.12 1 *8260B 7/14/15 16:36 MSC P5G0244 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 5.0 0.065 1 *8260B 7/14/15 16:36 MSC P5G0244 Methyl Ethyl Ketone (2-Butanone) BRL ug/L 5.0 0.24 1 *8260B 7/14/15 16:36 MSC P5G0244 Methyl Isobutyl Ketone BRL ug/L 5.0 0.078 1 *8260B 7/14/15 16:36 MSC P5G0244 Methylene Chloride BRL ug/L 1.0 0.083 1 *8260B 7/14/15 16:36 MSC P5G0244 Methyl-tert-Butyl Ether BRL ug/L 0.50 0.042 1 *8260B 7/14/15 16:36 MSC P5G0244 Naphthalene BRL ug/L 1.0 0.19 1 *8260B 7/14/15 16:36 MSC P5G0244 n-Butylbenzene BRL ug/L 1.0 0.076 1 *8260B 7/14/15 16:36 MSC P5G0244 n-Propylbenzene BRL ug/L 0.50 0.087 1 *8260B 7/14/15 16:36 MSC P5G0244 o-Xylene BRL ug/L 0.50 0.044 1 *8260B 7/14/15 16:36 MSC P5G0244 sec-Butylbenzene BRL ug/L 0.50 0.076 1 *8260B 7/14/15 16:36 MSC P5G0244 Styrene BRL ug/L 0.50 0.047 1 *8260B 7/14/15 16:36 MSC P5G0244 tert-Butylbenzene BRL ug/L 0.50 0.088 1 *8260B 7/14/15 16:36 MSC P5G0244 Tetrachloroethylene BRL ug/L 0.50 0.098 1 *8260B 7/14/15 16:36 MSC P5G0244 Toluene BRL ug/L 0.50 0.044 1 *8260B 7/14/15 16:36 MSC P5G0244 trans-1,2-Dichloroethylene BRL ug/L 0.50 0.094 1 *8260B 7/14/15 16:36 MSC P5G0244 trans-1,3-Dichloropropylene BRL ug/L 0.50 0.070 1 *8260B 7/14/15 16:36 MSC P5G0244 Trichloroethylene BRL ug/L 0.50 0.078 1 *8260B 7/14/15 16:36 MSC P5G0244 Trichlorofluoromethane BRL ug/L 0.50 0.062 1 *8260B 7/14/15 16:36 MSC P5G0244 Vinyl acetate BRL ug/L 2.0 0.060 1 *8260B 7/14/15 16:36 MSC P5G0244 Vinyl chloride BRL ug/L 0.50 0.097 1 *8260B 7/14/15 16:36 MSC P5G0244 Surrogate Recovery Control Limits 4-Bromofluorobenzene 95 % 80-124 Dibromofluoromethane 105 % 75-129 Toluene-d8 94 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 34 of 66 /r E P R I IS M Service Analytical Environmental Solutions LABORATORIES, INC. Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5G0244 - 5030B Blank (P5G0244-BLK1) Prepared & Analyzed: 07/14/15 1,1,1,2-Tetrachloroethane BRL 0.50 ug/L 1,1,1-Trichloroethane BRL 0.50 ug/L 1,1,2,2-Tetrachloroethane BRL 0.50 ug/L 1,1,2-Trichloroethane BRL 0.50 ug/L 1,1-Dichloroethane BRL 0.50 ug/L 1,1-Dichloroethylene BRL 0.50 ug/L 1,1-Dichloropropylene BRL 0.50 ug/L 1,2,3-Trichlorobenzene BRL 2.0 ug/L 1,2,3-Trichloropropane BRL 1.0 ug/L 1,2,4-Trichlorobenzene BRL 1.0 ug/L 1,2,4-Trimethyl benzene BRL 0.50 ug/L 1,2-Dibromo-3-chloropropane BRL 2.0 ug/L 1,2-Dibromoethane BRL 0.50 ug/L 1,2-Dichlorobenzene BRL 0.50 ug/L 1,2-Dichloroethane BRL 0.50 ug/L 1,2-Dichloropropane BRL 0.50 ug/L 1,3,5-Trimethyl benzene BRL 0.50 ug/L 1,3-Dichlorobenzene BRL 0.50 ug/L 1,3-Dichloropropane BRL 0.50 ug/L 1,4-Dichlorobenzene BRL 0.50 ug/L 2,2-Dichloropropane BRL 2.0 ug/L 2-Chloroethyl Vinyl Ether BRL 5.0 ug/L 2-Chlorotoluene BRL 0.50 ug/L 4-Chlorotoluene BRL 0.50 ug/L 4-Isopropyltoluene BRL 0.50 ug/L Acetone BRL 5.0 ug/L Acrolein BRL 20 ug/L Acrylonitrile BRL 20 ug/L Benzene BRL 0.50 ug/L Bromobenzene BRL 0.50 ug/L Bromochloromethane BRL 0.50 ug/L Bromodichloromethane BRL 0.50 ug/L Bromoform BRL 1.0 ug/L Bromomethane BRL 1.0 ug/L Carbon disulfide BRL 5.0 ug/L Carbon Tetrachloride BRL 0.50 ug/L Chlorobenzene BRL 0.50 ug/L Chloroethane BRL 0.50 ug/L Chloroform BRL 0.50 ug/L Chloromethane BRL 0.50 ug/L cis-1,2-Dichloroethylene BRL 0.50 ug/L cis-1,3-Dichloropropylene BRL 0.50 ug/L Dibromochloromethane BRL 0.50 ug/L Dibromomethane BRL 0.50 ug/L Dichlorodifluoromethane BRL 1.0 ug/L Ethylbenzene BRL 0.50 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 35 of 66 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Hart & Hickman (Charlotte) Project: PTR.001-4A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 7/22/15 Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO244 - 5030B Blank (P5G0244-BLK1) Prepared & Analyzed: 07/14/15 Hexachlorobutadiene BRL 2.0 ug/L Isopropyl Ether BRL 0.50 ug/L Isopropylbenzene (Cumene) BRL 0.50 ug/L m,p-Xylenes BRL 1.0 ug/L Methyl Butyl Ketone (2-Hexanone) BRL 5.0 ug/L Methyl Ethyl Ketone (2-Butanone) BRL 5.0 ug/L Methyl Isobutyl Ketone BRL 5.0 ug/L Methylene Chloride BRL 1.0 ug/L Methyl-tert-Butyl Ether BRL 0.50 ug/L Naphthalene BRL 1.0 ug/L n-Butylbenzene BRL 1.0 ug/L n-Propylbenzene BRL 0.50 ug/L o-Xylene BRL 0.50 ug/L sec-Butylbenzene BRL 0.50 ug/L Styrene BRL 0.50 ug/L tert-Butylbenzene BRL 0.50 ug/L Tetrachloroethylene BRL 0.50 ug/L Toluene BRL 0.50 ug/L trans-1,2-Dichloroethylene BRL 0.50 ug/L trans-1,3-Dichloropropylene BRL 0.50 ug/L Trichloroethylene BRL 0.50 ug/L Trichlorofluoromethane BRL 0.50 ug/L Vinyl acetate BRL 2.0 ug/L Vinyl chloride BRL 0.50 ug/L Surrogate:4-Bromofluorobenzene 23.2 ug/L 25.00 93 80-124 Surrogate: Dibromofluoromethane 26.0 ug/L 25.00 104 75-129 Surrogate: Toluene-d8 23.8 ug/L 25.00 95 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 36 of 66 P R I IS M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Prism Work Order: 5070164 Attn: Aaron Oswald Time Submitted: 7/10/2015 8:50:OOAM 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO244 - 5030B LCS (P51130244-113SI) Prepared & Analyzed: 07/14/15 1,1,1,2-Tetrachloroethane 19.9 0.50 ug/L 20.00 100 79-134 1,1,1-Trichloroethane 19.1 0.50 ug/L 20.00 96 75-136 1,1,2,2-Tetrachloroethane 17.6 0.50 ug/L 20.00 88 62-127 1,1,2-Trichloroethane 19.8 0.50 ug/L 20.00 99 70-140 1,1-Dichloroethane 19.0 0.50 ug/L 20.00 95 78-130 1,1-Dichloroethylene 21.3 0.50 ug/L 20.00 106 70-154 1, 1 -Dichloropropylene 23.4 0.50 ug/L 20.00 117 71-136 1,2,3-Trichlorobenzene 21.4 2.0 ug/L 20.00 107 58-144 1,2,3-Trichloropropane 17.8 1.0 ug/L 20.00 89 71-127 1,2,4-Trichlorobenzene 21.2 1.0 ug/L 20.00 106 66-139 1,2,4-Trimethylbenzene 19.4 0.50 ug/L 20.00 97 75-133 1,2-Dibromo-3-chloropropane 15.1 2.0 ug/L 20.00 76 63-134 1,2-Dibromoethane 20.2 0.50 ug/L 20.00 101 77-135 1,2-Dichlorobenzene 21.2 0.50 ug/L 20.00 106 78-128 1,2-Dichloroethane 18.9 0.50 ug/L 20.00 95 68-131 1,2-Dichloropropane 20.1 0.50 ug/L 20.00 101 77-130 1,3,5-Trimethylbenzene 19.4 0.50 ug/L 20.00 97 75-131 1,3-Dichlorobenzene 21.3 0.50 ug/L 20.00 107 77-125 1,3-Dichloropropane 19.2 0.50 ug/L 20.00 96 76-132 1,4-Dichlorobenzene 20.8 0.50 ug/L 20.00 104 75-126 2,2-Dichloropropane 18.9 2.0 ug/L 20.00 94 29-149 2-Chloroethyl Vinyl Ether 9.38 5.0 ug/L 20.00 47 34-144 2-Chlorotoluene 20.0 0.50 ug/L 20.00 100 74-126 4-Chlorotoluene 20.0 0.50 ug/L 20.00 100 78-129 4-Isopropyltoluene 21.2 0.50 ug/L 20.00 106 69-132 Acetone 36.5 5.0 ug/L 40.00 91 40-166 Acrolein 36.8 20 ug/L 40.00 92 70-130 Acrylonitrile 40.0 20 ug/L 40.00 100 81-127 Benzene 22.1 0.50 ug/L 20.00 111 77-128 Bromobenzene 18.6 0.50 ug/L 20.00 93 78-129 Bromochloromethane 19.4 0.50 ug/L 20.00 97 78-135 Bromodichloromethane 17.8 0.50 ug/L 20.00 89 76-138 Bromoform 18.2 1.0 ug/L 20.00 91 71-135 Bromomethane 17.1 1.0 ug/L 20.00 86 41-168 Carbon disulfide 23.6 5.0 ug/L 20.00 118 59-135 Carbon Tetrachloride 22.0 0.50 ug/L 20.00 110 72-142 Chlorobenzene 20.8 0.50 ug/L 20.00 104 78-119 Chloroethane 21.8 0.50 ug/L 20.00 109 57-142 Chloroform 18.0 0.50 ug/L 20.00 90 77-130 Chloromethane 18.5 0.50 ug/L 20.00 92 47-145 cis-1,2-Dichloroethylene 19.6 0.50 ug/L 20.00 98 76-141 cis-1,3-Dichloropropylene 18.8 0.50 ug/L 20.00 94 65-140 Dibromochloromethane 17.2 0.50 ug/L 20.00 86 75-134 Dibromomethane 20.8 0.50 ug/L 20.00 104 76-138 Dichlorodifluoromethane 19.8 1.0 ug/L 20.00 99 28-163 Ethylbenzene 21.1 0.50 ug/L 20.00 105 80-127 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 37 of 66 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO244 - 5030B LCS (P5G0244-BS1) Prepared & Analyzed: 07/14/15 Hexachlorobutadiene 22.8 2.0 ug/L 20.00 114 61-134 Isopropyl Ether 17.5 0.50 ug/L 20.00 87 60-154 Isopropylbenzene (Cumene) 22.5 0.50 ug/L 20.00 113 70-130 m,p-Xylenes 42.5 1.0 ug/L 40.00 106 77-133 Methyl Butyl Ketone (2-Hexanone) 13.3 5.0 ug/L 20.00 67 64-137 Methyl Ethyl Ketone (2-Butanone) 16.4 5.0 ug/L 20.00 82 71-134 Methyl Isobutyl Ketone 14.1 5.0 ug/L 20.00 70 69-134 Methylene Chloride 19.7 1.0 ug/L 20.00 98 73-131 Methyl-tert-Butyl Ether 18.2 0.50 ug/L 20.00 91 68-135 Naphthalene 18.0 1.0 ug/L 20.00 90 64-136 n-Butylbenzene 19.7 1.0 ug/L 20.00 98 68-134 n-Propylbenzene 21.5 0.50 ug/L 20.00 107 72-132 o-Xylene 20.5 0.50 ug/L 20.00 102 78-128 sec-Butylbenzene 22.6 0.50 ug/L 20.00 113 71-131 Styrene 20.9 0.50 ug/L 20.00 104 78-129 tert-Butylbenzene 21.0 0.50 ug/L 20.00 105 70-132 Tetrachloroethylene 22.5 0.50 ug/L 20.00 112 80-129 Toluene 21.8 0.50 ug/L 20.00 109 76-131 trans-1,2-Dichloroethylene 20.1 0.50 ug/L 20.00 101 76-135 trans-1,3-Dichloropropylene 18.6 0.50 ug/L 20.00 93 67-140 Trichloroethylene 22.8 0.50 ug/L 20.00 114 77-133 Trichlorofluoromethane 25.1 0.50 ug/L 20.00 126 62-148 Vinyl acetate 19.6 2.0 ug/L 20.00 98 34-167 Vinyl chloride 20.8 0.50 ug/L 20.00 104 57-141 Surrogate:4-Bromofluorobenzene 22.2 ug/L 25.00 89 80-124 Surrogate: Dibromofluoromethane 25.2 ug/L 25.00 101 75-129 Surrogate: Toluene-d8 24.0 ug/L 25.00 96 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 38 of 66 P R I IS M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO244 - 5030B Reporting Result Limit Units Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS Dup (P5G0244-BSD1) Prepared & Analyzed: 07/14/15 1,1,1,2-Tetrachloroethane 19.1 0.50 ug/L 20.00 95 79-134 4 20 1,1,1-Trichloroethane 17.8 0.50 ug/L 20.00 89 75-136 7 20 1,1,2,2-Tetrachloroethane 16.8 0.50 ug/L 20.00 84 62-127 5 20 1,1,2-Trichloroethane 18.4 0.50 ug/L 20.00 92 70-140 7 20 1,1-Dichloroethane 18.0 0.50 ug/L 20.00 90 78-130 6 20 1,1-Dichloroethylene 19.9 0.50 ug/L 20.00 99 70-154 7 20 1, 1 -Dichloropropylene 21.1 0.50 ug/L 20.00 105 71-136 10 20 1,2,3-Trichlorobenzene 21.1 2.0 ug/L 20.00 105 58-144 1 20 1,2,3-Trichloropropane 17.6 1.0 ug/L 20.00 88 71-127 1 20 1,2,4-Trichlorobenzene 20.8 1.0 ug/L 20.00 104 66-139 2 20 1,2,4-Trimethylbenzene 18.5 0.50 ug/L 20.00 93 75-133 5 20 1,2-Dibromo-3-chloropropane 17.2 2.0 ug/L 20.00 86 63-134 13 20 1,2-Dibromoethane 19.9 0.50 ug/L 20.00 100 77-135 2 20 1,2-Dichlorobenzene 20.7 0.50 ug/L 20.00 103 78-128 3 20 1,2-Dichloroethane 18.2 0.50 ug/L 20.00 91 68-131 4 20 1,2-Dichloropropane 19.5 0.50 ug/L 20.00 98 77-130 3 20 1,3,5-Trimethylbenzene 18.5 0.50 ug/L 20.00 92 75-131 5 20 1,3-Dichlorobenzene 20.8 0.50 ug/L 20.00 104 77-125 3 20 1,3-Dichloropropane 19.5 0.50 ug/L 20.00 98 76-132 2 20 1,4-Dichlorobenzene 20.1 0.50 ug/L 20.00 100 75-126 3 20 2,2-Dichloropropane 17.7 2.0 ug/L 20.00 88 29-149 7 20 2-Chloroethyl Vinyl Ether 8.81 5.0 ug/L 20.00 44 34-144 6 20 2-Chlorotoluene 19.2 0.50 ug/L 20.00 96 74-126 4 20 4-Chlorotoluene 19.2 0.50 ug/L 20.00 96 78-129 4 20 4-Isopropyltoluene 19.9 0.50 ug/L 20.00 100 69-132 6 20 Acetone 38.3 5.0 ug/L 40.00 96 40-166 5 20 Acrolein 37.3 20 ug/L 40.00 93 70-130 1 20 Acrylonitrile 38.7 20 ug/L 40.00 97 81-127 3 20 Benzene 20.8 0.50 ug/L 20.00 104 77-128 6 20 Bromobenzene 17.7 0.50 ug/L 20.00 88 78-129 5 20 Bromochloromethane 18.7 0.50 ug/L 20.00 93 78-135 4 20 Bromodichloromethane 17.4 0.50 ug/L 20.00 87 76-138 2 20 Bromoform 17.7 1.0 ug/L 20.00 89 71-135 3 20 Bromomethane 16.5 1.0 ug/L 20.00 83 41-168 4 20 Carbon disulfide 22.7 5.0 ug/L 20.00 113 59-135 4 20 Carbon Tetrachloride 20.5 0.50 ug/L 20.00 103 72-142 7 20 Chlorobenzene 20.5 0.50 ug/L 20.00 103 78-119 1 20 Chloroethane 20.1 0.50 ug/L 20.00 100 57-142 8 20 Chloroform 17.3 0.50 ug/L 20.00 86 77-130 4 20 Chloromethane 16.7 0.50 ug/L 20.00 84 47-145 10 20 cis-1,2-Dichloroethylene 18.5 0.50 ug/L 20.00 92 76-141 6 20 cis-1,3-Dichloropropylene 18.1 0.50 ug/L 20.00 90 65-140 4 20 Dibromochloromethane 17.3 0.50 ug/L 20.00 86 75-134 0.3 20 Dibromomethane 20.1 0.50 ug/L 20.00 101 76-138 3 20 Dichlorodifluoromethane 17.9 1.0 ug/L 20.00 90 28-163 10 20 Ethylbenzene 20.3 0.50 ug/L 20.00 101 80-127 4 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 39 of 66 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Hart & Hickman (Charlotte) Project: PTR.001-4A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 7/22/15 Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO244 - 5030B LCS Dup (P5G0244-BSD1) Prepared & Analyzed: 07/14/15 Hexachlorobutadiene 21.9 2.0 ug/L 20.00 109 61-134 4 20 Isopropyl Ether 16.9 0.50 ug/L 20.00 85 60-154 3 20 Isopropylbenzene (Cumene) 21.2 0.50 ug/L 20.00 106 70-130 6 20 m,p-Xylenes 41.0 1.0 ug/L 40.00 103 77-133 4 20 Methyl Butyl Ketone (2-Hexanone) 14.0 5.0 ug/L 20.00 70 64-137 5 20 Methyl Ethyl Ketone (2-Butanone) 15.3 5.0 ug/L 20.00 76 71-134 7 20 Methyl Isobutyl Ketone 14.1 5.0 ug/L 20.00 71 69-134 0.4 20 Methylene Chloride 19.2 1.0 ug/L 20.00 96 73-131 3 20 Methyl-tert-Butyl Ether 17.8 0.50 ug/L 20.00 89 68-135 2 20 Naphthalene 17.2 1.0 ug/L 20.00 86 64-136 5 20 n-Butylbenzene 18.4 1.0 ug/L 20.00 92 68-134 7 20 n-Propylbenzene 20.5 0.50 ug/L 20.00 102 72-132 5 20 o-Xylene 20.1 0.50 ug/L 20.00 100 78-128 2 20 sec-Butylbenzene 21.1 0.50 ug/L 20.00 106 71-131 7 20 Styrene 19.9 0.50 ug/L 20.00 100 78-129 5 20 tert-Butylbenzene 19.8 0.50 ug/L 20.00 99 70-132 6 20 Tetrachloroethylene 20.9 0.50 ug/L 20.00 104 80-129 7 20 Toluene 20.6 0.50 ug/L 20.00 103 76-131 5 20 trans-1,2-Dichloroethylene 18.7 0.50 ug/L 20.00 93 76-135 7 20 trans-1,3-Dichloropropylene 17.7 0.50 ug/L 20.00 88 67-140 5 20 Trichloroethylene 21.2 0.50 ug/L 20.00 106 77-133 7 20 Trichlorofluoromethane 23.3 0.50 ug/L 20.00 116 62-148 7 20 Vinyl acetate 19.2 2.0 ug/L 20.00 96 34-167 2 20 Vinyl chloride 18.9 0.50 ug/L 20.00 95 57-141 9 20 Surrogate:4-Bromofluorobenzene 22.3 ug/L 25.00 89 80-124 Surrogate: Dibromofluoromethane 25.0 ug/L 25.00 100 75-129 Surrogate: Toluene-d8 23.9 ug/L 25.00 96 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 40 of 66 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO262 - 5035 Reporting Result Limit Units Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Blank (P5G0262-BLK1) Prepared & Analyzed: 07/16/15 1,1,1,2-Tetrachloroethane BRL 0.0050 mg/kg wet 1,1,1-Trichloroethane BRL 0.0050 mg/kg wet 1,1,2,2-Tetrachloroethane BRL 0.0050 mg/kg wet 1,1,2-Trichloroethane BRL 0.0050 mg/kg wet 1,1-Dichloroethane BRL 0.0050 mg/kg wet 1,1-Dichloroethylene BRL 0.0050 mg/kg wet 1,1-Dichloropropylene BRL 0.0050 mg/kg wet 1,2,3-Trichlorobenzene BRL 0.0050 mg/kg wet 1,2,3-Trichloropropane BRL 0.0050 mg/kg wet 1,2,4-Trichlorobenzene BRL 0.0050 mg/kg wet 1,2,4-Trimethyl benzene BRL 0.0050 mg/kg wet 1,2-Dibromoethane BRL 0.0050 mg/kg wet 1,2-Dichlorobenzene BRL 0.0050 mg/kg wet 1,2-Dichloroethane BRL 0.0050 mg/kg wet 1,2-Dichloropropane BRL 0.0050 mg/kg wet 1,3,5-Trimethyl benzene BRL 0.0050 mg/kg wet 1,3-Dichlorobenzene BRL 0.0050 mg/kg wet 1,3-Dichloropropane BRL 0.0050 mg/kg wet 1,4-Dichlorobenzene BRL 0.0050 mg/kg wet 2,2-Dichloropropane BRL 0.0050 mg/kg wet 2-Chlorotoluene BRL 0.0050 mg/kg wet 4-Chlorotoluene BRL 0.0050 mg/kg wet 4-Isopropyltoluene BRL 0.0050 mg/kg wet Acetone BRL 0.050 mg/kg wet Benzene BRL 0.0030 mg/kg wet Bromobenzene BRL 0.0050 mg/kg wet Bromochloromethane BRL 0.0050 mg/kg wet Bromodichloromethane BRL 0.0050 mg/kg wet Bromoform BRL 0.0050 mg/kg wet Bromomethane BRL 0.010 mg/kg wet Carbon Tetrachloride BRL 0.0050 mg/kg wet Chlorobenzene BRL 0.0050 mg/kg wet Chloroethane BRL 0.010 mg/kg wet Chloroform BRL 0.0050 mg/kg wet Chloromethane BRL 0.0050 mg/kg wet cis-1,2-Dichloroethylene BRL 0.0050 mg/kg wet cis-1,3-Dichloropropylene BRL 0.0050 mg/kg wet Dibromochloromethane BRL 0.0050 mg/kg wet Dichlorodifluoromethane BRL 0.0050 mg/kg wet Ethylbenzene BRL 0.0050 mg/kg wet Isopropyl Ether BRL 0.0050 mg/kg wet Isopropylbenzene (Cumene) BRL 0.0050 mg/kg wet m,p-Xylenes BRL 0.010 mg/kg wet Methyl Butyl Ketone (2-Hexanone) BRL 0.050 mg/kg wet Methyl Ethyl Ketone (2-Butanone) BRL 0.10 mg/kg wet Methyl Isobutyl Ketone BRL 0.050 mg/kg wet This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 41 of 66 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO262 - 5035 Reporting Result Limit Units Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Blank (P5G0262-BLK1) Prepared & Analyzed: 07/16/15 Methylene Chloride BRL 0.0050 mg/kg wet Methyl-tert-Butyl Ether BRL 0.010 mg/kg wet Naphthalene BRL 0.010 mg/kg wet n-Butylbenzene BRL 0.0050 mg/kg wet n-Propylbenzene BRL 0.0050 mg/kg wet o-Xylene BRL 0.0050 mg/kg wet sec-Butylbenzene BRL 0.0050 mg/kg wet Styrene BRL 0.0050 mg/kg wet tert-Butylbenzene BRL 0.0050 mg/kg wet Tetrachloroethylene BRL 0.0050 mg/kg wet Toluene BRL 0.0050 mg/kg wet trans-1,2-Dichloroethylene BRL 0.0050 mg/kg wet trans- 1,3-Dichloropropylene BRL 0.0050 mg/kg wet Trichloroethylene BRL 0.0050 mg/kg wet Trichlorofluoromethane BRL 0.0050 mg/kg wet Vinyl acetate BRL 0.025 mg/kg wet Vinyl chloride BRL 0.0050 mg/kg wet Xylenes, total BRL 0.015 mg/kg wet Surrogate: 4-Bromofluorobenzene 0.0612 mg/kg wet 0.05000 122 70-130 Surrogate: Dibromofluoromethane 0.0518 mg/kg wet 0.05000 104 84-123 Surrogate: Toluene-d8 0.0501 mg/kg wet 0.05000 100 76-129 LCS (P5G0262-BS1) Prepared & Analyzed: 07/16/15 1,1,1,2-Tetrachloroethane 0.0498 0.0050 mg/kg wet 0.05000 100 72-115 1,1,1-Trichloroethane 0.0505 0.0050 mg/kg wet 0.05000 101 67-131 1,1,2,2-Tetrachloroethane 0.0520 0.0050 mg/kg wet 0.05000 104 56-126 1,1,2-Trichloroethane 0.0480 0.0050 mg/kg wet 0.05000 96 70-133 1,1-Dichloroethane 0.0433 0.0050 mg/kg wet 0.05000 87 74-127 1,1-Dichloroethylene 0.0468 0.0050 mg/kg wet 0.05000 94 67-149 1,1-Dichloropropylene 0.0493 0.0050 mg/kg wet 0.05000 99 71-130 1,2,3-Trichlorobenzene 0.0567 0.0050 mg/kg wet 0.05000 113 68-130 1,2,3-Trichloropropane 0.0521 0.0050 mg/kg wet 0.05000 104 60-137 1,2,4-Trichlorobenzene 0.0571 0.0050 mg/kg wet 0.05000 114 66-125 1,2,4-Trimethyl benzene 0.0534 0.0050 mg/kg wet 0.05000 107 69-129 1,2-Dibromoethane 0.0528 0.0050 mg/kg wet 0.05000 106 70-132 1,2-Dichlorobenzene 0.0530 0.0050 mg/kg wet 0.05000 106 72-123 1,2-Dichloroethane 0.0487 0.0050 mg/kg wet 0.05000 97 68-128 1,2-Dichloropropane 0.0410 0.0050 mg/kg wet 0.05000 82 73-130 1,3,5-Trimethyl benzene 0.0552 0.0050 mg/kg wet 0.05000 110 69-128 1,3-Dichlorobenzene 0.0519 0.0050 mg/kg wet 0.05000 104 71-120 1,3-Dichloropropane 0.0457 0.0050 mg/kg wet 0.05000 91 75-124 1,4-Dichlorobenzene 0.0512 0.0050 mg/kg wet 0.05000 102 71-123 2,2-Dichloropropane 0.0490 0.0050 mg/kg wet 0.05000 98 50-142 2-Chlorotoluene 0.0544 0.0050 mg/kg wet 0.05000 109 67-124 4-Chlorotoluene 0.0517 0.0050 mg/kg wet 0.05000 103 71-126 4-Isopropyltoluene 0.0520 0.0050 mg/kg wet 0.05000 104 68-129 Acetone 0.0928 0.050 mg/kg wet 0.1000 93 29-198 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 42 of 66 P R I IS M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Analyte Batch P51130262 - 5035 Reporting Result Limit Units Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS (P5G0262-BSI) Prepared & Analyzed: 07/16/15 Benzene 0.0483 0.0030 mg/kg wet 0.05000 97 74-127 Bromobenzene 0.0526 0.0050 mg/kg wet 0.05000 105 73-125 Bromochloromethane 0.0520 0.0050 mg/kg wet 0.05000 104 72-134 Bromodichloromethane 0.0448 0.0050 mg/kg wet 0.05000 90 75-122 Bromoform 0.0508 0.0050 mg/kg wet 0.05000 102 66-135 Bromomethane 0.0552 0.010 mg/kg wet 0.05000 110 20-180 Carbon Tetrachloride 0.0570 0.0050 mg/kg wet 0.05000 114 64-143 Chlorobenzene 0.0475 0.0050 mg/kg wet 0.05000 95 74-118 Chloroethane 0.0424 0.010 mg/kg wet 0.05000 85 33-149 Chloroform 0.0447 0.0050 mg/kg wet 0.05000 89 73-127 Chloromethane 0.0383 0.0050 mg/kg wet 0.05000 77 45-143 cis-1,2-Dichloroethylene 0.0449 0.0050 mg/kg wet 0.05000 90 76-134 cis-1,3-Dichloropropylene 0.0458 0.0050 mg/kg wet 0.05000 92 71-125 Dibromochloromethane 0.0487 0.0050 mg/kg wet 0.05000 97 73-122 Dichlorodifluoromethane 0.0345 0.0050 mg/kg wet 0.05000 69 26-146 Ethylbenzene 0.0476 0.0050 mg/kg wet 0.05000 95 74-128 Isopropyl Ether 0.0383 0.0050 mg/kg wet 0.05000 77 59-159 Isopropylbenzene (Cumene) 0.0562 0.0050 mg/kg wet 0.05000 112 68-126 m,p-Xylenes 0.100 0.010 mg/kg wet 0.1000 100 75-124 Methyl Butyl Ketone (2-Hexanone) 0.0464 0.050 mg/kg wet 0.05000 93 61-157 Methyl Ethyl Ketone (2-Butanone) 0.0522 0.10 mg/kg wet 0.05000 104 63-149 Methyl Isobutyl Ketone 0.0427 0.050 mg/kg wet 0.05000 85 57-162 Methylene Chloride 0.0412 0.0050 mg/kg wet 0.05000 82 74-129 Methyl-tert-Butyl Ether 0.0460 0.010 mg/kg wet 0.05000 92 70-130 Naphthalene 0.0552 0.010 mg/kg wet 0.05000 110 57-157 n-Butylbenzene 0.0534 0.0050 mg/kg wet 0.05000 107 65-135 n-Propylbenzene 0.0544 0.0050 mg/kg wet 0.05000 109 67-130 o-Xylene 0.0518 0.0050 mg/kg wet 0.05000 104 74-126 sec-Butylbenzene 0.0528 0.0050 mg/kg wet 0.05000 106 66-131 Styrene 0.0514 0.0050 mg/kg wet 0.05000 103 77-121 tert-Butyl benzene 0.0546 0.0050 mg/kg wet 0.05000 109 67-132 Tetrachloroethylene 0.0510 0.0050 mg/kg wet 0.05000 102 68-130 Toluene 0.0494 0.0050 mg/kg wet 0.05000 99 71-129 trans- 1,2-Dichloroethylene 0.0464 0.0050 mg/kg wet 0.05000 93 73-132 trans- 1,3-Dichloropropylene 0.0491 0.0050 mg/kg wet 0.05000 98 68-123 Trichloroethylene 0.0486 0.0050 mg/kg wet 0.05000 97 75-133 Trichlorofluoromethane 0.0547 0.0050 mg/kg wet 0.05000 109 44-146 Vinyl acetate 0.0419 0.025 mg/kg wet 0.05000 84 85-161 Vinyl chloride 0.0434 0.0050 mg/kg wet 0.05000 87 48-147 Xylenes, total 0.152 0.015 mg/kg wet 0.1500 101 74-126 Surrogate: 4-Bromofluorobenzene 0.0561 mg/kg wet 0.05000 112 70-130 Surrogate: Dibromofluoromethane 0.0517 mg/kg wet 0.05000 103 84-123 Surrogate: Toluene-d8 0.0508 mg/kg wet 0.05000 102 76-129 A This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 43 of 66 P R I IS M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Analyte Batch P51130262 - 5035 Reporting Result Limit Units Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS Dup (P5G0262-BSD1) Prepared & Analyzed: 07/16/15 1,1,1,2-Tetrachloroethane 0.0527 0.0050 mg/kg wet 0.05000 105 72-115 6 20 1,1,1-Trichloroethane 0.0512 0.0050 mg/kg wet 0.05000 102 67-131 1 20 1,1,2,2-Tetrachloroethane 0.0498 0.0050 mg/kg wet 0.05000 100 56-126 4 20 1,1,2-Trichloroethane 0.0464 0.0050 mg/kg wet 0.05000 93 70-133 3 20 1,1-Dichloroethane 0.0443 0.0050 mg/kg wet 0.05000 89 74-127 2 20 1,1-Dichloroethylene 0.0472 0.0050 mg/kg wet 0.05000 94 67-149 0.8 20 1, 1 -Dichloropropylene 0.0490 0.0050 mg/kg wet 0.05000 98 71-130 0.6 20 1,2,3-Trichlorobenzene 0.0563 0.0050 mg/kg wet 0.05000 113 68-130 0.8 20 1,2,3-Trichloropropane 0.0490 0.0050 mg/kg wet 0.05000 98 60-137 6 20 1,2,4-Trichlorobenzene 0.0554 0.0050 mg/kg wet 0.05000 111 66-125 3 20 1,2,4-Trimethylbenzene 0.0516 0.0050 mg/kg wet 0.05000 103 69-129 3 20 1,2-Dibromoethane 0.0523 0.0050 mg/kg wet 0.05000 105 70-132 0.9 20 1,2-Dichlorobenzene 0.0519 0.0050 mg/kg wet 0.05000 104 72-123 2 20 1,2-Dichloroethane 0.0489 0.0050 mg/kg wet 0.05000 98 68-128 0.5 20 1,2-Dichloropropane 0.0427 0.0050 mg/kg wet 0.05000 85 73-130 4 20 1,3,5-Trimethylbenzene 0.0544 0.0050 mg/kg wet 0.05000 109 69-128 1 20 1,3-Dichlorobenzene 0.0519 0.0050 mg/kg wet 0.05000 104 71-120 0.1 20 1,3-Dichloropropane 0.0466 0.0050 mg/kg wet 0.05000 93 75-124 2 20 1,4-Dichlorobenzene 0.0504 0.0050 mg/kg wet 0.05000 101 71-123 2 20 2,2-Dichloropropane 0.0486 0.0050 mg/kg wet 0.05000 97 50-142 0.7 20 2-Chlorotoluene 0.0532 0.0050 mg/kg wet 0.05000 106 67-124 2 20 4-Chlorotoluene 0.0518 0.0050 mg/kg wet 0.05000 104 71-126 0.3 20 4-Isopropyltoluene 0.0538 0.0050 mg/kg wet 0.05000 108 68-129 3 20 Acetone 0.0868 0.050 mg/kg wet 0.1000 87 29-198 7 20 Benzene 0.0501 0.0030 mg/kg wet 0.05000 100 74-127 4 20 Bromobenzene 0.0508 0.0050 mg/kg wet 0.05000 102 73-125 3 20 Bromochloromethane 0.0534 0.0050 mg/kg wet 0.05000 107 72-134 3 20 Bromodichloromethane 0.0446 0.0050 mg/kg wet 0.05000 89 75-122 0.5 20 Bromoform 0.0491 0.0050 mg/kg wet 0.05000 98 66-135 3 20 Bromomethane 0.0544 0.010 mg/kg wet 0.05000 109 20-180 1 20 Carbon Tetrachloride 0.0567 0.0050 mg/kg wet 0.05000 113 64-143 0.4 20 Chlorobenzene 0.0495 0.0050 mg/kg wet 0.05000 99 74-118 4 20 Chloroethane 0.0465 0.010 mg/kg wet 0.05000 93 33-149 9 20 Chloroform 0.0470 0.0050 mg/kg wet 0.05000 94 73-127 5 20 Chloromethane 0.0378 0.0050 mg/kg wet 0.05000 76 45-143 1 20 cis-1,2-Dichloroethylene 0.0459 0.0050 mg/kg wet 0.05000 92 76-134 2 20 cis-1,3-Dichloropropylene 0.0468 0.0050 mg/kg wet 0.05000 94 71-125 2 20 Dibromochloromethane 0.0492 0.0050 mg/kg wet 0.05000 98 73-122 1 20 Dichlorodifluoromethane 0.0344 0.0050 mg/kg wet 0.05000 69 26-146 0.2 20 Ethylbenzene 0.0502 0.0050 mg/kg wet 0.05000 100 74-128 5 20 Isopropyl Ether 0.0392 0.0050 mg/kg wet 0.05000 78 59-159 2 20 Isopropylbenzene (Cumene) 0.0548 0.0050 mg/kg wet 0.05000 110 68-126 3 20 m,p-Xylenes 0.0993 0.010 mg/kg wet 0.1000 99 75-124 0.7 20 Methyl Butyl Ketone (2-Hexanone) 0.0415 0.050 mg/kg wet 0.05000 83 61-157 11 20 Methyl Ethyl Ketone (2-Butanone) 0.0445 0.10 mg/kg wet 0.05000 89 63-149 16 20 Methyl Isobutyl Ketone 0.0402 0.050 mg/kg wet 0.05000 80 57-162 6 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 44 of 66 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO262 - 5035 Reporting Result Limit Units Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS Dup (P5G0262-BSD1) Prepared & Analyzed: 07/16/15 Methylene Chloride 0.0428 0.0050 mg/kg wet 0.05000 86 74-129 4 20 Methyl-tert-Butyl Ether 0.0468 0.010 mg/kg wet 0.05000 94 70-130 2 20 Naphthalene 0.0500 0.010 mg/kg wet 0.05000 100 57-157 10 20 n-Butylbenzene 0.0531 0.0050 mg/kg wet 0.05000 106 65-135 0.6 20 n-Propylbenzene 0.0536 0.0050 mg/kg wet 0.05000 107 67-130 1 20 o-Xylene 0.0520 0.0050 mg/kg wet 0.05000 104 74-126 0.4 20 sec-Butylbenzene 0.0518 0.0050 mg/kg wet 0.05000 104 66-131 2 20 Styrene 0.0527 0.0050 mg/kg wet 0.05000 105 77-121 3 20 tert-Butylbenzene 0.0527 0.0050 mg/kg wet 0.05000 105 67-132 4 20 Tetrachloroethylene 0.0518 0.0050 mg/kg wet 0.05000 104 68-130 2 20 Toluene 0.0510 0.0050 mg/kg wet 0.05000 102 71-129 3 20 trans-1,2-Dichloroethylene 0.0466 0.0050 mg/kg wet 0.05000 93 73-132 0.5 20 trans- 1,3-Dichloropropylene 0.0494 0.0050 mg/kg wet 0.05000 99 68-123 0.7 20 Trichloroethylene 0.0511 0.0050 mg/kg wet 0.05000 102 75-133 5 20 Trichlorofluoromethane 0.0545 0.0050 mg/kg wet 0.05000 109 44-146 0.2 20 Vinyl acetate 0.0395 0.025 mg/kg wet 0.05000 79 85-161 6 20 A Vinyl chloride 0.0448 0.0050 mg/kg wet 0.05000 90 48-147 3 20 Xylenes, total 0.151 0.015 mg/kg wet 0.1500 101 74-126 0.3 20 Surrogate: 4-Bromofluorobenzene 0.0534 mg/kg wet 0.05000 107 70-130 Surrogate: Dibromofluoromethane 0.0504 mg/kg wet 0.05000 101 84-123 Surrogate: Toluene-d8 0.0521 mg/kg wet 0.05000 104 76-129 Batch P5GO393 - 5030B Blank (P5G0393-BLK1) Prepared & Analyzed: 07/21/15 1,1,1,2-Tetrachloroethane BRL 0.50 ug/L 1,1,1-Trichloroethane BRL 0.50 ug/L 1,1,2,2-Tetrachloroethane BRL 0.50 ug/L 1,1,2-Trichloroethane BRL 0.50 ug/L 1,1-Dichloroethane BRL 0.50 ug/L 1,1-Dichloroethylene BRL 0.50 ug/L 1,1-Dichloropropylene BRL 0.50 ug/L 1,2,3-Trichlorobenzene BRL 2.0 ug/L 1,2,3-Trichloropropane BRL 1.0 ug/L 1,2,4-Trichlorobenzene BRL 1.0 ug/L 1,2,4-Trimethyl benzene BRL 0.50 ug/L 1,2-Dibromo-3-chloropropane BRL 2.0 ug/L 1,2-Dibromoethane BRL 0.50 ug/L 1,2-Dichlorobenzene BRL 0.50 ug/L 1,2-Dichloroethane BRL 0.50 ug/L 1,2-Dichloropropane BRL 0.50 ug/L 1,3,5-Trimethyl benzene BRL 0.50 ug/L 1,3-Dichlorobenzene BRL 0.50 ug/L 1,3-Dichloropropane BRL 0.50 ug/L 1,4-Dichlorobenzene BRL 0.50 ug/L 2,2-Dichloropropane BRL 2.0 ug/L 2-Chloroethyl Vinyl Ether BRL 5.0 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 45 of 66 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO393 - 5030B Blank (P5G0393-BLK1) Prepared & Analyzed: 07/21/15 2-Chlorotoluene BRL 0.50 ug/L 4-Chlorotoluene BRL 0.50 ug/L 4-Isopropyltoluene BRL 0.50 ug/L Acetone BRL 5.0 ug/L Acrolein BRL 20 ug/L Acrylonitrile BRL 20 ug/L Benzene BRL 0.50 ug/L Bromobenzene BRL 0.50 ug/L Bromochloromethane BRL 0.50 ug/L Bromodichloromethane BRL 0.50 ug/L Bromoform BRL 1.0 ug/L Bromomethane BRL 1.0 ug/L Carbon disulfide BRL 5.0 ug/L Carbon Tetrachloride BRL 0.50 ug/L Chlorobenzene BRL 0.50 ug/L Chloroethane BRL 0.50 ug/L Chloroform BRL 0.50 ug/L Chloromethane BRL 0.50 ug/L cis-1,2-Dichloroethylene BRL 0.50 ug/L cis-1,3-Dichloropropylene BRL 0.50 ug/L Dibromochloromethane BRL 0.50 ug/L Dibromomethane BRL 0.50 ug/L Dichlorodifluoromethane BRL 1.0 ug/L Ethylbenzene BRL 0.50 ug/L Hexachlorobutadiene BRL 2.0 ug/L Isopropyl Ether BRL 0.50 ug/L Isopropylbenzene (Cumene) BRL 0.50 ug/L m,p-Xylenes BRL 1.0 ug/L Methyl Butyl Ketone (2-Hexanone) BRL 5.0 ug/L Methyl Ethyl Ketone (2-Butanone) BRL 5.0 ug/L Methyl Isobutyl Ketone BRL 5.0 ug/L Methylene Chloride BRL 1.0 ug/L Methyl-tert-Butyl Ether BRL 0.50 ug/L Naphthalene BRL 1.0 ug/L n-Butylbenzene BRL 1.0 ug/L n-Propylbenzene BRL 0.50 ug/L o-Xylene BRL 0.50 ug/L sec-Butylbenzene BRL 0.50 ug/L Styrene BRL 0.50 ug/L tert-Butylbenzene BRL 0.50 ug/L Tetrachloroethylene BRL 0.50 ug/L Toluene BRL 0.50 ug/L trans-1,2-Dichloroethylene BRL 0.50 ug/L trans-1,3-Dichloropropylene BRL 0.50 ug/L Trichloroethylene BRL 0.50 ug/L Trichlorofluoromethane BRL 0.50 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 46 of 66 P R I IS M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Prism Work Order: 5070164 Attn: Aaron Oswald Time Submitted: 7/10/2015 8:50:OOAM 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P51130393 - 5030B Blank (125130393-1311-K1) Prepared & Analyzed: 07/21/15 Vinyl acetate BRL 2.0 ug/L Vinyl chloride BRL 0.50 ug/L Surrogate:4-Bromofluorobenzene 22.2 ug/L 25.00 89 80-124 Surrogate: Dibromofluoromethane 25.4 ug/L 25.00 102 75-129 Surrogate: Toluene-d8 23.8 ug/L 25.00 95 77-123 LCS (P5G0393-BS1) Prepared & Analyzed: 07/21/15 1,1,1,2-Tetrachloroethane 20.5 0.50 ug/L 20.00 103 79-134 1,1,1-Trichloroethane 20.3 0.50 ug/L 20.00 101 75-136 1,1,2,2-Tetrachloroethane 20.4 0.50 ug/L 20.00 102 62-127 1,1,2-Trichloroethane 20.5 0.50 ug/L 20.00 103 70-140 1,1-Dichloroethane 19.3 0.50 ug/L 20.00 96 78-130 1,1-Dichloroethylene 22.5 0.50 ug/L 20.00 112 70-154 1, 1 -Dichloropropylene 24.1 0.50 ug/L 20.00 121 71-136 1,2,3-Trichlorobenzene 24.7 2.0 ug/L 20.00 124 58-144 1,2,3-Trichloropropane 21.8 1.0 ug/L 20.00 109 71-127 1,2,4-Trichlorobenzene 23.3 1.0 ug/L 20.00 116 66-139 1,2,4-Trimethylbenzene 20.1 0.50 ug/L 20.00 100 75-133 1,2-Dibromo-3-chloropropane 21.4 2.0 ug/L 20.00 107 63-134 1,2-Dibromoethane 23.0 0.50 ug/L 20.00 115 77-135 1,2-Dichlorobenzene 22.8 0.50 ug/L 20.00 114 78-128 1,2-Dichloroethane 19.8 0.50 ug/L 20.00 99 68-131 1,2-Dichloropropane 20.7 0.50 ug/L 20.00 104 77-130 1,3,5-Trimethylbenzene 20.4 0.50 ug/L 20.00 102 75-131 1,3-Dichlorobenzene 23.0 0.50 ug/L 20.00 115 77-125 1,3-Dichloropropane 22.0 0.50 ug/L 20.00 110 76-132 1,4-Dichlorobenzene 22.8 0.50 ug/L 20.00 114 75-126 2,2-Dichloropropane 18.7 2.0 ug/L 20.00 94 29-149 2-Chloroethyl Vinyl Ether 9.11 5.0 ug/L 20.00 46 34-144 2-Chlorotoluene 21.5 0.50 ug/L 20.00 108 74-126 4-Chlorotoluene 21.4 0.50 ug/L 20.00 107 78-129 4-Isopropyltoluene 22.6 0.50 ug/L 20.00 113 69-132 Acetone 46.7 5.0 ug/L 40.00 117 40-166 Acrolein 39.8 20 ug/L 40.00 100 70-130 Acrylonitrile 41.2 20 ug/L 40.00 103 81-127 Benzene 23.1 0.50 ug/L 20.00 116 77-128 Bromobenzene 19.5 0.50 ug/L 20.00 98 78-129 Bromochloromethane 20.0 0.50 ug/L 20.00 100 78-135 Bromodichloromethane 18.5 0.50 ug/L 20.00 93 76-138 Bromoform 20.8 1.0 ug/L 20.00 104 71-135 Bromomethane 20.2 1.0 ug/L 20.00 101 41-168 Carbon disulfide 24.7 5.0 ug/L 20.00 124 59-135 Carbon Tetrachloride 24.2 0.50 ug/L 20.00 121 72-142 Chlorobenzene 22.2 0.50 ug/L 20.00 ill 78-119 Chloroethane 21.9 0.50 ug/L 20.00 110 57-142 Chloroform 18.5 0.50 ug/L 20.00 92 77-130 Chloromethane 19.7 0.50 ug/L 20.00 99 47-145 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 47 of 66 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Prism Work Order: 5070164 Attn: Aaron Oswald Time Submitted: 7/10/2015 8:50:OOAM 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO393 - 5030B LCS (P5G0393-BS1) Prepared & Analyzed: 07/21/15 cis-1,2-Dichloroethylene 19.5 0.50 ug/L 20.00 98 76-141 cis-1,3-Dichloropropylene 19.6 0.50 ug/L 20.00 98 65-140 Dibromochloromethane 19.5 0.50 ug/L 20.00 97 75-134 Dibromomethane 21.5 0.50 ug/L 20.00 108 76-138 Dichlorodifluoromethane 22.9 1.0 ug/L 20.00 114 28-163 Ethylbenzene 22.6 0.50 ug/L 20.00 113 80-127 Hexachlorobutadiene 25.1 2.0 ug/L 20.00 126 61-134 Isopropyl Ether 17.5 0.50 ug/L 20.00 87 60-154 Isopropylbenzene (Cumene) 24.1 0.50 ug/L 20.00 120 70-130 m,p-Xylenes 45.1 1.0 ug/L 40.00 113 77-133 Methyl Butyl Ketone (2-Hexanone) 16.1 5.0 ug/L 20.00 80 64-137 Methyl Ethyl Ketone (2-Butanone) 19.0 5.0 ug/L 20.00 95 71-134 Methyl Isobutyl Ketone 17.1 5.0 ug/L 20.00 86 69-134 Methylene Chloride 20.2 1.0 ug/L 20.00 101 73-131 Methyl-tert-Butyl Ether 19.6 0.50 ug/L 20.00 98 68-135 Naphthalene 20.9 1.0 ug/L 20.00 104 64-136 n-Butylbenzene 21.1 1.0 ug/L 20.00 106 68-134 n-Propylbenzene 23.2 0.50 ug/L 20.00 116 72-132 o-Xylene 21.3 0.50 ug/L 20.00 106 78-128 sec-Butylbenzene 24.4 0.50 ug/L 20.00 122 71-131 Styrene 22.3 0.50 ug/L 20.00 ill 78-129 tert-Butylbenzene 22.2 0.50 ug/L 20.00 ill 70-132 Tetrachloroethylene 24.5 0.50 ug/L 20.00 123 80-129 Toluene 22.2 0.50 ug/L 20.00 ill 76-131 trans-1,2-Dichloroethylene 20.6 0.50 ug/L 20.00 103 76-135 trans-1,3-Dichloropropylene 19.0 0.50 ug/L 20.00 95 67-140 Trichloroethylene 22.8 0.50 ug/L 20.00 114 77-133 Trichlorofluoromethane 26.8 0.50 ug/L 20.00 134 62-148 Vinyl acetate 20.7 2.0 ug/L 20.00 104 34-167 Vinyl chloride 22.3 0.50 ug/L 20.00 ill 57-141 Surrogate:4-Bromofluorobenzene 21.9 ug/L 25.00 88 80-124 Surrogate: Dibromofluoromethane 24.8 ug/L 25.00 99 75-129 Surrogate: Toluene-d8 24.0 ug/L 25.00 96 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 48 of 66 P R I IS M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO393 - 5030B Reporting Result Limit Units Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS Dup (P5G0393-BSD1) Prepared & Analyzed: 07/21/15 1,1,1,2-Tetrachloroethane 20.3 0.50 ug/L 20.00 101 79-134 1 20 1,1,1-Trichloroethane 19.3 0.50 ug/L 20.00 97 75-136 5 20 1,1,2,2-Tetrachloroethane 18.4 0.50 ug/L 20.00 92 62-127 11 20 1,1,2-Trichloroethane 19.8 0.50 ug/L 20.00 99 70-140 4 20 1,1-Dichloroethane 19.0 0.50 ug/L 20.00 95 78-130 1 20 1,1-Dichloroethylene 22.4 0.50 ug/L 20.00 112 70-154 0.6 20 1, 1 -Dichloropropylene 23.5 0.50 ug/L 20.00 118 71-136 3 20 1,2,3-Trichlorobenzene 23.3 2.0 ug/L 20.00 117 58-144 6 20 1,2,3-Trichloropropane 20.3 1.0 ug/L 20.00 101 71-127 7 20 1,2,4-Trichlorobenzene 22.2 1.0 ug/L 20.00 111 66-139 5 20 1,2,4-Trimethylbenzene 19.4 0.50 ug/L 20.00 97 75-133 3 20 1,2-Dibromo-3-chloropropane 18.2 2.0 ug/L 20.00 91 63-134 16 20 1,2-Dibromoethane 21.4 0.50 ug/L 20.00 107 77-135 7 20 1,2-Dichlorobenzene 21.9 0.50 ug/L 20.00 109 78-128 4 20 1,2-Dichloroethane 19.0 0.50 ug/L 20.00 95 68-131 4 20 1,2-Dichloropropane 19.6 0.50 ug/L 20.00 98 77-130 6 20 1,3,5-Trimethylbenzene 19.8 0.50 ug/L 20.00 99 75-131 3 20 1,3-Dichlorobenzene 22.0 0.50 ug/L 20.00 110 77-125 5 20 1,3-Dichloropropane 21.2 0.50 ug/L 20.00 106 76-132 4 20 1,4-Dichlorobenzene 21.4 0.50 ug/L 20.00 107 75-126 6 20 2,2-Dichloropropane 18.2 2.0 ug/L 20.00 91 29-149 3 20 2-Chloroethyl Vinyl Ether 8.40 5.0 ug/L 20.00 42 34-144 8 20 2-Chlorotoluene 20.9 0.50 ug/L 20.00 104 74-126 3 20 4-Chlorotoluene 20.7 0.50 ug/L 20.00 103 78-129 3 20 4-Isopropyltoluene 21.4 0.50 ug/L 20.00 107 69-132 6 20 Acetone 41.6 5.0 ug/L 40.00 104 40-166 11 20 Acrolein 36.4 20 ug/L 40.00 91 70-130 9 20 Acrylonitrile 39.9 20 ug/L 40.00 100 81-127 3 20 Benzene 22.3 0.50 ug/L 20.00 111 77-128 4 20 Bromobenzene 18.5 0.50 ug/L 20.00 92 78-129 5 20 Bromochloromethane 19.9 0.50 ug/L 20.00 99 78-135 0.8 20 Bromodichloromethane 17.7 0.50 ug/L 20.00 88 76-138 4 20 Bromoform 20.6 1.0 ug/L 20.00 103 71-135 1 20 Bromomethane 19.6 1.0 ug/L 20.00 98 41-168 3 20 Carbon disulfide 24.0 5.0 ug/L 20.00 120 59-135 3 20 Carbon Tetrachloride 22.2 0.50 ug/L 20.00 111 72-142 9 20 Chlorobenzene 21.8 0.50 ug/L 20.00 109 78-119 2 20 Chloroethane 21.2 0.50 ug/L 20.00 106 57-142 4 20 Chloroform 18.0 0.50 ug/L 20.00 90 77-130 3 20 Chloromethane 18.4 0.50 ug/L 20.00 92 47-145 7 20 cis-1,2-Dichloroethylene 19.2 0.50 ug/L 20.00 96 76-141 1 20 cis-1,3-Dichloropropylene 18.6 0.50 ug/L 20.00 93 65-140 5 20 Dibromochloromethane 19.1 0.50 ug/L 20.00 96 75-134 2 20 Dibromomethane 21.3 0.50 ug/L 20.00 107 76-138 0.8 20 Dichlorodifluoromethane 22.6 1.0 ug/L 20.00 113 28-163 1 20 Ethylbenzene 22.4 0.50 ug/L 20.00 112 80-127 1 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 49 of 66 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Hart & Hickman (Charlotte) Project: PTR.001-4A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 7/22/15 Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO393 - 5030B LCS Dup (P5G0393-BSD1) Prepared & Analyzed: 07/21/15 Hexachlorobutadiene 24.0 2.0 ug/L 20.00 120 61-134 5 20 Isopropyl Ether 16.8 0.50 ug/L 20.00 84 60-154 4 20 Isopropylbenzene (Cumene) 23.3 0.50 ug/L 20.00 117 70-130 3 20 m,p-Xylenes 44.3 1.0 ug/L 40.00 ill 77-133 2 20 Methyl Butyl Ketone (2-Hexanone) 15.5 5.0 ug/L 20.00 78 64-137 4 20 Methyl Ethyl Ketone (2-Butanone) 18.3 5.0 ug/L 20.00 92 71-134 4 20 Methyl Isobutyl Ketone 16.0 5.0 ug/L 20.00 80 69-134 7 20 Methylene Chloride 19.6 1.0 ug/L 20.00 98 73-131 3 20 Methyl-tert-Butyl Ether 18.2 0.50 ug/L 20.00 91 68-135 7 20 Naphthalene 19.5 1.0 ug/L 20.00 98 64-136 7 20 n-Butylbenzene 20.0 1.0 ug/L 20.00 100 68-134 5 20 n-Propylbenzene 22.3 0.50 ug/L 20.00 ill 72-132 4 20 o-Xylene 21.0 0.50 ug/L 20.00 105 78-128 1 20 sec-Butylbenzene 23.5 0.50 ug/L 20.00 118 71-131 4 20 Styrene 21.6 0.50 ug/L 20.00 108 78-129 3 20 tert-Butylbenzene 21.4 0.50 ug/L 20.00 107 70-132 4 20 Tetrachloroethylene 24.5 0.50 ug/L 20.00 122 80-129 0.3 20 Toluene 21.8 0.50 ug/L 20.00 109 76-131 2 20 trans-1,2-Dichloroethylene 19.9 0.50 ug/L 20.00 99 76-135 3 20 trans-1,3-Dichloropropylene 18.3 0.50 ug/L 20.00 92 67-140 4 20 Trichloroethylene 22.8 0.50 ug/L 20.00 114 77-133 0.09 20 Trichlorofluoromethane 26.2 0.50 ug/L 20.00 131 62-148 2 20 Vinyl acetate 19.3 2.0 ug/L 20.00 97 34-167 7 20 Vinyl chloride 21.6 0.50 ug/L 20.00 108 57-141 3 20 Surrogate:4-Bromofluorobenzene 21.9 ug/L 25.00 88 80-124 Surrogate: Dibromofluoromethane 25.0 ug/L 25.00 100 75-129 Surrogate: Toluene-d8 24.5 ug/L 25.00 98 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 50 of 66 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Prism Work Order: 5070164 Attn: Aaron Oswald Time Submitted: 7/10/2015 8:50:OOAM 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO175 - 3546 Blank (P5G0175-BLK1) Prepared & Analyzed: 07/13/15 1,2,4-Trichlorobenzene BRL 0.33 mg/kg wet 1,2-Dichlorobenzene BRL 0.33 mg/kg wet 1,3-Dichlorobenzene BRL 0.33 mg/kg wet 1,4-Dichlorobenzene BRL 0.33 mg/kg wet 1-Methyl naphthalene BRL 0.33 mg/kg wet 2,4,6-Trichlorophenol BRL 0.33 mg/kg wet 2,4-Dichlorophenol BRL 0.33 mg/kg wet 2,4-Dimethylphenol BRL 0.33 mg/kg wet 2,4-Dinitrophenol BRL 0.33 mg/kg wet 2,4-Dinitrotoluene BRL 0.33 mg/kg wet 2,6-Dinitrotoluene BRL 0.33 mg/kg wet 2-Chloronaphthalene BRL 0.33 mg/kg wet 2-Chlorophenol BRL 0.33 mg/kg wet 2-Methyl naphthalene BRL 0.33 mg/kg wet 2-Methylphenol BRL 0.33 mg/kg wet 2-Nitrophenol BRL 0.33 mg/kg wet 3,3'-Dichlorobenzidine BRL 0.33 mg/kg wet 3/4-Methyl phenol BRL 0.33 mg/kg wet 4,6-Dinitro-2-methylphenol BRL 0.33 mg/kg wet 4-Bromophenyl phenyl ether BRL 0.33 mg/kg wet 4-Chloro-3-methylphenol BRL 0.33 mg/kg wet 4-Chloroaniline BRL 0.33 mg/kg wet 4-Chlorophenyl phenyl ether BRL 0.33 mg/kg wet 4-Nitrophenol BRL 0.33 mg/kg wet Acenaphthene BRL 0.33 mg/kg wet Acenaphthylene BRL 0.33 mg/kg wet Anthracene BRL 0.33 mg/kg wet Azobenzene BRL 0.33 mg/kg wet Benzo(a)anthracene BRL 0.33 mg/kg wet Benzo(a)pyrene BRL 0.33 mg/kg wet Benzo(b)fluoranthene BRL 0.33 mg/kg wet Benzo(g,h,i)perylene BRL 0.33 mg/kg wet Benzo(k)fluoranthene BRL 0.33 mg/kg wet Benzoic Acid BRL 0.33 mg/kg wet Benzyl alcohol BRL 0.33 mg/kg wet bis(2-Chloroethoxy)methane BRL 0.33 mg/kg wet Bis(2-Chloroethyl)ether BRL 0.33 mg/kg wet Bis(2-chloroisopropyl)ether BRL 0.33 mg/kg wet Bis(2-Ethylhexyl)phthalate BRL 0.33 mg/kg wet Butyl benzyl phthalate BRL 0.33 mg/kg wet Chrysene BRL 0.33 mg/kg wet Dibenzo(a,h)anthracene BRL 0.33 mg/kg wet Dibenzofuran BRL 0.33 mg/kg wet Diethyl phthalate BRL 0.33 mg/kg wet Dimethyl phthalate BRL 0.33 mg/kg wet Di-n-butyl phthalate BRL 0.33 mg/kg wet This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 51 of 66 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO175 - 3546 Reporting Result Limit Units Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Blank (P5G0175-BLK1) Prepared & Analyzed: 07/13/15 Di-n-octyl phthalate BRL 0.33 mg/kg wet Fluoranthene BRL 0.33 mg/kg wet Fluorene BRL 0.33 mg/kg wet Hexachlorobenzene BRL 0.33 mg/kg wet Hexachlorobutadiene BRL 0.33 mg/kg wet Hexachlorocyclopentadiene BRL 0.33 mg/kg wet Hexachloroethane BRL 0.33 mg/kg wet Indeno(1,2,3-cd)pyrene BRL 0.33 mg/kg wet Isophorone BRL 0.33 mg/kg wet Naphthalene BRL 0.33 mg/kg wet Nitrobenzene BRL 0.33 mg/kg wet N-Nitroso-di-n-propylamine BRL 0.33 mg/kg wet N-Nitrosodiphenylamine BRL 0.33 mg/kg wet Pentachlorophenol BRL 0.33 mg/kg wet Phenanthrene BRL 0.33 mg/kg wet Phenol BRL 0.33 mg/kg wet Pyrene BRL 0.33 mg/kg wet Surrogate: 2,4,6-Tribromophenol 3.79 mg/kg wet 3.333 114 39-132 Surrogate: 2-Fluorobiphenyl 1.80 mg/kg wet 1.667 108 44-115 Surrogate: 2-Fluorophenol 3.46 mg/kg wet 3.333 104 35-115 Surrogate: Nitrobenzene-d5 1.68 mg/kg wet 1.667 101 37-122 Surrogate: Phenol-d5 3.47 mg/kg wet 3.333 104 34-121 Surrogate: Terphenyl-d14 1.98 mg/kg wet 1.667 119 54-127 LCS (MG0175-BS1) Prepared & Analyzed: 07/13/15 1,2,4-Trichlorobenzene 1.32 0.33 mg/kg wet 1.667 79 34-118 1,2-Dichlorobenzene 1.22 0.33 mg/kg wet 1.667 73 33-117 1,3-Dichlorobenzene 1.17 0.33 mg/kg wet 1.667 70 30-115 1,4-Dichlorobenzene 1.19 0.33 mg/kg wet 1.667 71 31-115 1-Methyl naphthalene 1.34 0.33 mg/kg wet 1.667 80 40-119 2,4,6-Trichlorophenol 1.46 0.33 mg/kg wet 1.667 88 39-126 2,4-Dichlorophenol 1.42 0.33 mg/kg wet 1.667 85 40-122 2,4-Dimethylphenol 1.41 0.33 mg/kg wet 1.667 84 30-127 2,4-Dinitrophenol 1.05 0.33 mg/kg wet 1.667 63 27-129 2,4-Dinitrotoluene 1.58 0.33 mg/kg wet 1.667 95 48-126 2,6-Dinitrotoluene 1.56 0.33 mg/kg wet 1.667 94 46-124 2-Chloronaphthalene 1.69 0.33 mg/kg wet 1.667 101 41-114 2-Chlorophenol 1.35 0.33 mg/kg wet 1.667 81 34-121 2-Methyl naphthalene 1.35 0.33 mg/kg wet 1.667 81 38-122 2-Methylphenol 1.34 0.33 mg/kg wet 1.667 80 32-122 2-Nitrophenol 1.33 0.33 mg/kg wet 1.667 80 36-123 3,3'-Dichlorobenzidine 1.30 0.33 mg/kg wet 1.667 78 22-121 3/4-Methyl phenol 1.38 0.33 mg/kg wet 1.667 83 34-119 4,6-Dinitro-2-methylphenol 1.30 0.33 mg/kg wet 1.667 78 29-132 4-Bromophenyl phenyl ether 1.46 0.33 mg/kg wet 1.667 87 46-124 4-Chloro-3-methylphenol 1.41 0.33 mg/kg wet 1.667 84 45-122 4-Chloroaniline 1.34 0.33 mg/kg wet 1.667 80 17-106 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 52 of 66 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO175 - 3546 Reporting Result Limit Units Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS (P5G0175-BS1) Prepared & Analyzed: 07/13/15 4-Chlorophenyl phenyl ether 1.42 0.33 mg/kg wet 1.667 85 45-121 4-Nitrophenol 1.40 0.33 mg/kg wet 1.667 84 30-132 Acenaphthene 1.42 0.33 mg/kg wet 1.667 85 40-123 Acenaphthylene 1.47 0.33 mg/kg wet 1.667 88 32-132 Anthracene 1.60 0.33 mg/kg wet 1.667 96 47-123 Azobenzene 1.54 0.33 mg/kg wet 1.667 92 39-125 Benzo(a)anthracene 1.50 0.33 mg/kg wet 1.667 90 49-126 Benzo(a)pyrene 1.58 0.33 mg/kg wet 1.667 95 45-129 Benzo(b)fluoranthene 1.58 0.33 mg/kg wet 1.667 95 45-132 Benzo(g,h,i)perylene 1.48 0.33 mg/kg wet 1.667 88 43-134 Benzo(k)fluoranthene 1.51 0.33 mg/kg wet 1.667 91 47-132 Benzoic Acid 0.843 0.33 mg/kg wet 1.667 51 10-83 Benzyl alcohol 1.25 0.33 mg/kg wet 1.667 75 29-122 bis(2-Chloroethoxy)methane 1.22 0.33 mg/kg wet 1.667 73 36-121 Bis(2-Chloroethyl)ether 1.01 0.33 mg/kg wet 1.667 60 31-120 Bis(2-chloroisopropyl)ether 1.20 0.33 mg/kg wet 1.667 72 33-131 Bis(2-Ethylhexyl)phthalate 1.62 0.33 mg/kg wet 1.667 97 51-133 Butyl benzyl phthalate 1.55 0.33 mg/kg wet 1.667 93 48-132 Chrysene 1.52 0.33 mg/kg wet 1.667 91 50-124 Dibenzo(a,h)anthracene 1.44 0.33 mg/kg wet 1.667 86 45-134 Dibenzofuran 1.52 0.33 mg/kg wet 1.667 91 44-120 Diethyl phthalate 1.60 0.33 mg/kg wet 1.667 96 50-124 Dimethyl phthalate 1.56 0.33 mg/kg wet 1.667 94 48-124 Di-n-butyl phthalate 1.72 0.33 mg/kg wet 1.667 103 51-128 Di-n-octyl phthalate 1.65 0.33 mg/kg wet 1.667 99 45-140 Fluoranthene 1.58 0.33 mg/kg wet 1.667 95 50-127 Fluorene 1.50 0.33 mg/kg wet 1.667 90 43-125 Hexachlorobenzene 1.54 0.33 mg/kg wet 1.667 93 45-122 Hexachlorobutadiene 1.29 0.33 mg/kg wet 1.667 78 32-123 Hexachlorocyclopentadiene 1.20 0.33 mg/kg wet 1.667 72 32-117 Hexachloroethane 1.18 0.33 mg/kg wet 1.667 71 28-117 Indeno(1,2,3-cd)pyrene 1.40 0.33 mg/kg wet 1.667 84 45-133 Isophorone 1.38 0.33 mg/kg wet 1.667 83 30-122 Naphthalene 1.29 0.33 mg/kg wet 1.667 77 35-123 Nitrobenzene 1.31 0.33 mg/kg wet 1.667 79 34-122 N-Nitroso-di-n-propylamine 1.30 0.33 mg/kg wet 1.667 78 36-120 N-Nitrosodiphenylamine 1.52 0.33 mg/kg wet 1.667 91 38-127 Pentachlorophenol 1.30 0.33 mg/kg wet 1.667 78 25-133 Phenanthrene 1.61 0.33 mg/kg wet 1.667 96 50-121 Phenol 1.33 0.33 mg/kg wet 1.667 80 34-121 Pyrene 1.55 0.33 mg/kg wet 1.667 93 47-127 Surrogate: 2,4,6-Tribromophenol 2.95 mg/kg wet 3.333 89 39-132 Surrogate: 2-Fluorobiphenyl 1.42 mg/kg wet 1,667 85 44-115 Surrogate: 2-Fluorophenol 2.75 mg/kg wet 3.333 83 35-115 Surrogate: Nitrobenzene-d5 1.27 mg/kg wet 1.667 76 37-122 Surrogate: Phenol-d5 2.66 mg/kg wet 3,333 80 34-121 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 53 of 66 P R I IS M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO175 - 3546 Reporting Result Limit Units Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS (P51130175-113SI) Prepared & Analyzed: 07/13/15 Surrogate: Terphenyl-,114 1.47 mg/kg wet 1.667 88 54-127 LCS Dup (P5G0175-BSD1) Prepared & Analyzed: 07/13/15 1,2,4-Trichlorobenzene 1.39 0.33 mg/kg wet 1.667 83 34-118 5 20 1,2-Dichlorobenzene 1.27 0.33 mg/kg wet 1.667 76 33-117 4 20 1,3-Dichlorobenzene 1.22 0.33 mg/kg wet 1.667 73 30-115 5 20 1,4-Dichlorobenzene 1.23 0.33 mg/kg wet 1.667 74 31-115 4 20 1-Methyl naphthalene 1.47 0.33 mg/kg wet 1.667 88 40-119 9 20 2,4,6-Trichlorophenol 1.71 0.33 mg/kg wet 1.667 102 39-126 15 20 2,4-Dichlorophenol 1.54 0.33 mg/kg wet 1.667 93 40-122 8 20 2,4-Dimethylphenol 1.56 0.33 mg/kg wet 1.667 94 30-127 10 20 2,4-Dinitrophenol 1.53 0.33 mg/kg wet 1.667 92 27-129 37 20 D 2,4-Dinitrotoluene 1.98 0.33 mg/kg wet 1.667 119 48-126 22 20 D 2,6-Dinitrotoluene 1.87 0.33 mg/kg wet 1.667 112 46-124 18 20 2-Chloronaphthalene 1.86 0.33 mg/kg wet 1.667 111 41-114 9 20 2-Chlorophenol 1.39 0.33 mg/kg wet 1.667 83 34-121 3 20 2-Methyl naphthalene 1.46 0.33 mg/kg wet 1.667 87 38-122 7 20 2-Methylphenol 1.46 0.33 mg/kg wet 1.667 87 32-122 9 20 2-Nitrophenol 1.45 0.33 mg/kg wet 1.667 87 36-123 9 20 3,3'-Dichlorobenzidine 1.63 0.33 mg/kg wet 1.667 98 22-121 22 20 D 3/4-Methyl phenol 1.52 0.33 mg/kg wet 1.667 91 34-119 9 20 4,6-Dinitro-2-methylphenol 1.67 0.33 mg/kg wet 1.667 100 29-132 24 20 D 4-Bromophenyl phenyl ether 1.69 0.33 mg/kg wet 1.667 102 46-124 15 20 4-Chloro-3-methylphenol 1.65 0.33 mg/kg wet 1.667 99 45-122 16 20 4-Chloroaniline 1.48 0.33 mg/kg wet 1.667 89 17-106 10 20 4-Chlorophenyl phenyl ether 1.63 0.33 mg/kg wet 1.667 98 45-121 14 20 4-Nitrophenol 1.75 0.33 mg/kg wet 1.667 105 30-132 22 20 D Acenaphthene 1.61 0.33 mg/kg wet 1.667 97 40-123 13 20 Acenaphthylene 1.66 0.33 mg/kg wet 1.667 99 32-132 12 20 Anthracene 1.88 0.33 mg/kg wet 1.667 113 47-123 16 20 Azobenzene 1.80 0.33 mg/kg wet 1.667 108 39-125 15 20 Benzo(a)anthracene 1.83 0.33 mg/kg wet 1.667 110 49-126 20 20 Benzo(a)pyrene 1.92 0.33 mg/kg wet 1.667 115 45-129 19 20 Benzo(b)fluoranthene 1.89 0.33 mg/kg wet 1.667 114 45-132 18 20 Benzo(g,h,i)perylene 1.83 0.33 mg/kg wet 1.667 110 43-134 21 20 D Benzo(k)fluoranthene 1.90 0.33 mg/kg wet 1.667 114 47-132 23 20 D Benzoic Acid 1.08 0.33 mg/kg wet 1.667 65 10-83 25 20 D Benzyl alcohol 1.37 0.33 mg/kg wet 1.667 82 29-122 9 20 bis(2-Chloroethoxy)methane 1.33 0.33 mg/kg wet 1.667 80 36-121 8 20 Bis(2-Chloroethyl)ether 1.15 0.33 mg/kg wet 1.667 69 31-120 13 20 Bis(2-chloroisopropyl)ether 1.26 0.33 mg/kg wet 1.667 75 33-131 5 20 Bis(2-Ethylhexyl)phthalate 1.95 0.33 mg/kg wet 1.667 117 51-133 19 20 Butyl benzyl phthalate 1.90 0.33 mg/kg wet 1.667 114 48-132 20 20 Chrysene 1.84 0.33 mg/kg wet 1.667 111 50-124 19 20 Dibenzo(a,h)anthracene 1.80 0.33 mg/kg wet 1.667 108 45-134 22 20 D Dibenzofuran 1.74 0.33 mg/kg wet 1.667 105 44-120 13 20 Diethyl phthalate 1.91 0.33 mg/kg wet 1.667 114 50-124 17 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 54 of 66 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Prism Work Order: 5070164 Attn: Aaron Oswald Time Submitted: 7/10/2015 8:50:OOAM 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO175 - 3546 LCS Dup (P5G0175-BSD1) Prepared & Analyzed: 07/13/15 Dimethyl phthalate 1.86 0.33 mg/kg wet 1.667 ill 48-124 17 20 Di-n-butyl phthalate 2.04 0.33 mg/kg wet 1.667 122 51-128 17 20 Di-n-octyl phthalate 2.03 0.33 mg/kg wet 1.667 122 45-140 21 20 D Fluoranthene 1.89 0.33 mg/kg wet 1.667 114 50-127 18 20 Fluorene 1.76 0.33 mg/kg wet 1.667 105 43-125 16 20 Hexachlorobenzene 1.84 0.33 mg/kg wet 1.667 ill 45-122 18 20 Hexachlorobutadiene 1.39 0.33 mg/kg wet 1.667 84 32-123 8 20 Hexachlorocyclopentadiene 1.27 0.33 mg/kg wet 1.667 76 32-117 6 20 Hexachloroethane 1.22 0.33 mg/kg wet 1.667 73 28-117 3 20 Indeno(1,2,3-cd)pyrene 1.70 0.33 mg/kg wet 1.667 102 45-133 19 20 Isophorone 1.53 0.33 mg/kg wet 1.667 92 30-122 10 20 Naphthalene 1.36 0.33 mg/kg wet 1.667 81 35-123 5 20 Nitrobenzene 1.39 0.33 mg/kg wet 1.667 83 34-122 6 20 N-Nitroso-di-n-propylamine 1.42 0.33 mg/kg wet 1.667 85 36-120 8 20 N-Nitrosodiphenylamine 1.79 0.33 mg/kg wet 1.667 107 38-127 16 20 Pentachlorophenol 1.59 0.33 mg/kg wet 1.667 95 25-133 20 20 Phenanthrene 1.92 0.33 mg/kg wet 1.667 115 50-121 18 20 Phenol 1.40 0.33 mg/kg wet 1.667 84 34-121 5 20 Pyrene 1.88 0.33 mg/kg wet 1.667 113 47-127 20 20 Surrogate: 2,4,6-Tribromophenol 3.59 mg/kg wet 3.333 108 39-132 Surrogate: 2-Fluorobiphenyl 1.56 mg/kg wet 1.667 93 44-115 Surrogate: 2-Fluorophenol 2.84 mg/kg wet 3.333 85 35-115 Surrogate: Nitrobenzene-d5 1.34 mg/kg wet 1.667 80 37-122 Surrogate: Phenol-d5 2.81 mg/kg wet 3.333 84 34-121 Surrogate: Terphenyl-d14 1.77 mg/kg wet 1.667 106 54-127 Batch P5GO184 - 3510C MS Blank (1135G0184-13LK1) Prepared & Analyzed: 07/14/15 1,2,4-Trichlorobenzene BRL 10 ug/L 1,2-Dichlorobenzene BRL 10 ug/L 1,3-Dichlorobenzene BRL 10 ug/L 1,4-Dichlorobenzene BRL 10 ug/L 1-Methyl naphthalene BRL 10 ug/L 2,4,5-Trichlorophenol BRL 10 ug/L 2,4,6-Trichlorophenol BRL 10 ug/L 2,4-Dichlorophenol BRL 10 ug/L 2,4-Dimethylphenol BRL 10 ug/L 2,4-Dinitrophenol BRL 10 ug/L 2,4-Dinitrotoluene BRL 10 ug/L 2,6-Dinitrotoluene BRL 10 ug/L 2-Chloronaphthalene BRL 10 ug/L 2-Chlorophenol BRL 10 ug/L 2-Methyl naphthalene BRL 10 ug/L 2-Methylphenol BRL 10 ug/L 2-Nitroaniline BRL 10 ug/L 2-Nitrophenol BRL 10 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 55 of 66 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO184 - 3510C MS Reporting Result Limit Units Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Blank (P5G0184-BLK1) Prepared & Analyzed: 07/14/15 3,3'-Dichlorobenzidine BRL 10 ug/L 3/4-Methyl phenol BRL 10 ug/L 3-Nitroaniline BRL 10 ug/L 4,6-Dinitro-2-methylphenol BRL 10 ug/L 4-Bromophenyl phenyl ether BRL 10 ug/L 4-Chloro-3-methylphenol BRL 10 ug/L 4-Chloroaniline BRL 10 ug/L 4-Chlorophenyl phenyl ether BRL 10 ug/L 4-Nitroaniline BRL 10 ug/L 4-Nitrophenol BRL 10 ug/L Acenaphthene BRL 10 ug/L Acenaphthylene BRL 10 ug/L Aniline BRL 10 ug/L Anthracene BRL 10 ug/L Azobenzene BRL 10 ug/L Benzo(a)anthracene BRL 10 ug/L Benzo(a)pyrene BRL 10 ug/L Benzo(b)fluoranthene BRL 10 ug/L Benzo(g,h,i)perylene BRL 10 ug/L Benzo(k)fluoranthene BRL 10 ug/L Benzoic Acid BRL 100 ug/L Benzyl alcohol BRL 10 ug/L bis(2-Chloroethoxy)methane BRL 10 ug/L Bis(2-Chloroethyl)ether BRL 10 ug/L Bis(2-chloroisopropyl)ether BRL 10 ug/L Bis(2-Ethylhexyl)phthalate BRL 10 ug/L Butyl benzyl phthalate BRL 10 ug/L Chrysene BRL 10 ug/L Dibenzo(a,h)anthracene BRL 10 ug/L Dibenzofuran BRL 10 ug/L Diethyl phthalate BRL 10 ug/L Dimethyl phthalate BRL 10 ug/L Di-n-butyl phthalate BRL 10 ug/L Di-n-octyl phthalate BRL 10 ug/L Fluoranthene BRL 10 ug/L Fluorene BRL 10 ug/L Hexachlorobenzene BRL 10 ug/L Hexachlorobutadiene BRL 10 ug/L Hexachlorocyclopentadiene BRL 10 ug/L Hexachloroethane BRL 10 ug/L Indeno(1,2,3-cd)pyrene BRL 10 ug/L Isophorone BRL 10 ug/L Naphthalene BRL 10 ug/L Nitrobenzene BRL 10 ug/L N-Nitroso-di-n-propylamine BRL 10 ug/L N-Nitrosodiphenylamine BRL 10 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 56 of 66 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO184 - 3510C MS Reporting Result Limit Units Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Blank (P5G0184-BLK1) Prepared & Analyzed: 07/14/15 Pentachlorophenol BRL 10 ug/L Phenanthrene BRL 10 ug/L Phenol BRL 10 ug/L Pyrene BRL 10 ug/L Surrogate: 2,4,6-Tribromophenol 117 ug/L 100.0 117 49-109 SR Surrogate:2-Fluorobiphenyl 55.4 ug/L 50.00 111 55-96 SR Surrogate:2-Fluorophenol 65.6 ug/L 100.0 66 27-74 Surrogate: Nitrobenzene-d5 53.4 ug/L 50.00 107 53-99 SR Surrogate: Phenol-d5 43.8 ug/L 100.0 44 11-52 Surrogate: Terphenyl-d14 54.2 ug/L 50.00 108 42-133 LCS (P5G0184-BSI) Prepared & Analyzed: 07/14/15 1,2,4-Trichlorobenzene 46.8 10 ug/L 50.00 94 45-103 1,2-Dichlorobenzene 45.3 10 ug/L 50.00 91 43-100 1,3-Dichlorobenzene 44.2 10 ug/L 50.00 88 42-98 1,4-Dichlorobenzene 44.2 10 ug/L 50.00 88 42-100 1-Methyl naphthalene 48.0 10 ug/L 50.00 96 45-135 2,4,5-Trichlorophenol 52.9 10 ug/L 50.00 106 66-120 2,4,6-Trichlorophenol 52.8 10 ug/L 50.00 106 62-121 2,4-Dichlorophenol 49.5 10 ug/L 50.00 99 58-113 2,4-Dimethylphenol 47.6 10 ug/L 50.00 95 42-120 2,4-Dinitrophenol 49.3 10 ug/L 50.00 99 27-129 2,4-Dinitrotoluene 59.4 10 ug/L 50.00 119 62-136 2,6-Dinitrotoluene 57.7 10 ug/L 50.00 115 64-129 2-Chloronaphthalene 60.0 10 ug/L 50.00 120 38-141 2-Chorophenol 45.8 10 ug/L 50.00 92 49-107 2-Methyl naphthalene 48.2 10 ug/L 50.00 96 55-112 2-Methylphenol 40.8 10 ug/L 50.00 82 40-106 2-Nitroaniline 51.2 10 ug/L 50.00 102 65-122 2-Nitrophenol 49.4 10 ug/L 50.00 99 57-115 3,3'-Dichlorobenzidine 67.9 10 ug/L 50.00 136 58-139 3/4-Methyl phenol 39.0 10 ug/L 50.00 78 34-101 3-Nitroaniline 63.0 10 ug/L 50.00 126 52-155 4,6-Dinitro-2-methylphenol 55.5 10 ug/L 50.00 ill 49-138 4-Bromophenyl phenyl ether 51.9 10 ug/L 50.00 104 63-135 4-Chloro-3-methylphenol 52.2 10 ug/L 50.00 104 33-149 4-Chloroaniline 72.8 10 ug/L 50.00 146 44-163 4-Chlorophenyl phenyl ether 51.0 10 ug/L 50.00 102 63-129 4-Nitroaniline 55.5 10 ug/L 50.00 ill 63-147 4-Nitrophenol 23.7 10 ug/L 50.00 47 10-77 Acenaphthene 49.6 10 ug/L 50.00 99 64-118 Acenaphthylene 50.8 10 ug/L 50.00 102 65-119 Aniline 70.6 10 ug/L 50.00 141 12-197 Anthracene 52.9 10 ug/L 50.00 106 69-134 Azobenzene 54.4 10 ug/L 50.00 109 56-129 Benzo(a)anthracene 53.3 10 ug/L 50.00 107 71-125 Benzo(a)pyrene 59.4 10 ug/L 50.00 119 67-135 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 57 of 66 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO184 - 3510C MS Reporting Result Limit Units Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS (M0184-BS1) Prepared & Analyzed: 07/14/15 Benzo(b)fluoranthene 56.9 10 ug/L 50.00 114 56-145 Benzo(g,h,i)perylene 56.9 10 ug/L 50.00 114 44-149 Benzo(k)fluoranthene 56.4 10 ug/L 50.00 113 65-138 Benzoic Acid 14.0 100 ug/L 50.00 28 10-125 Benzyl alcohol 41.1 10 ug/L 50.00 82 35-111 bis(2-Chloroethoxy)methane 46.6 10 ug/L 50.00 93 49-126 Bis(2-Chloroethyl)ether 45.6 10 ug/L 50.00 91 47-124 Bis(2-chloroisopropyl)ether 46.6 10 ug/L 50.00 93 42-126 Bis(2-Ethylhexyl)phthalate 59.0 10 ug/L 50.00 118 59-139 Butyl benzyl phthalate 58.5 10 ug/L 50.00 117 67-133 Chrysene 55.1 10 ug/L 50.00 110 64-124 Dibenzo(a,h)anthracene 55.6 10 ug/L 50.00 ill 49-144 Dibenzofuran 53.7 10 ug/L 50.00 107 68-113 Diethyl phthalate 58.9 10 ug/L 50.00 118 70-124 Dimethyl phthalate 57.8 10 ug/L 50.00 116 71-117 Di-n-butyl phthalate 59.7 10 ug/L 50.00 119 69-128 Di-n-octyl phthalate 61.5 10 ug/L 50.00 123 52-150 Fluoranthene 55.4 10 ug/L 50.00 ill 66-135 Fluorene 54.7 10 ug/L 50.00 109 67-124 Hexachlorobenzene 55.5 10 ug/L 50.00 ill 62-124 Hexachlorobutadiene 45.3 10 ug/L 50.00 91 42-105 Hexachlorocyclopentadiene 46.6 10 ug/L 50.00 93 32-117 Hexachloroethane 43.8 10 ug/L 50.00 88 40-99 Indeno(1,2,3-cd)pyrene 56.7 10 ug/L 50.00 113 40-150 Isophorone 53.0 10 ug/L 50.00 106 54-125 Naphthalene 45.3 10 ug/L 50.00 91 54-111 Nitrobenzene 49.9 10 ug/L 50.00 100 51-117 N-Nitroso-di-n-propylamine 49.6 10 ug/L 50.00 99 55-115 N-Nitrosodiphenylamine 54.3 10 ug/L 50.00 109 70-152 Pentachlorophenol 54.6 10 ug/L 50.00 109 23-139 Phenanthrene 55.7 10 ug/L 50.00 ill 68-128 Phenol 23.1 10 ug/L 50.00 46 12-58 Pyrene 54.5 10 ug/L 50.00 109 62-139 Surrogate: 2,4,6-Tribromophenol 124 ug/L 100.0 124 49-109 SR Surrogate:2-Fluorobiphenyl 54.8 ug/L 50.00 110 55-96 SR Surrogate:2-Fluorophenol 67.8 ug/L 100.0 68 27-74 Surrogate: Nitrobenzene-d5 52.3 ug/L 50.00 105 53-99 SR Surrogate: Phenol-d5 44.3 ug/L 100.0 44 11-52 Surrogate: Terphenyl-d14 57.8 ug/L 50.00 116 42-133 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 58 of 66 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO184 - 3510C MS Reporting Result Limit Units Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS Dup (P5G0184-BSD1) Prepared & Analyzed: 07/14/15 1,2,4-Trichlorobenzene 48.8 10 ug/L 50.00 98 45-103 4 20 1,2-Dichlorobenzene 47.9 10 ug/L 50.00 96 43-100 6 20 1,3-Dichlorobenzene 46.9 10 ug/L 50.00 94 42-98 6 20 1,4-Dichlorobenzene 46.8 10 ug/L 50.00 94 42-100 6 20 1-Methyl naphthalene 50.5 10 ug/L 50.00 101 45-135 5 20 2,4,5-Trichlorophenol 56.1 10 ug/L 50.00 112 66-120 6 20 2,4,6-Trichlorophenol 55.0 10 ug/L 50.00 110 62-121 4 20 2,4-Dichlorophenol 52.0 10 ug/L 50.00 104 58-113 5 20 2,4-Dimethylphenol 47.3 10 ug/L 50.00 95 42-120 0.7 20 2,4-Dinitrophenol 53.8 10 ug/L 50.00 108 27-129 9 20 2,4-Dinitrotoluene 61.1 10 ug/L 50.00 122 62-136 3 20 2,6-Dinitrotoluene 61.2 10 ug/L 50.00 122 64-129 6 20 2-Chloronaphthalene 62.7 10 ug/L 50.00 125 38-141 5 20 2-Chlorophenol 48.2 10 ug/L 50.00 96 49-107 5 20 2-Methyl naphthalene 50.5 10 ug/L 50.00 101 55-112 5 20 2-Methylphenol 43.0 10 ug/L 50.00 86 40-106 5 20 2-Nitroaniline 53.4 10 ug/L 50.00 107 65-122 4 20 2-Nitrophenol 52.2 10 ug/L 50.00 104 57-115 6 20 3,3'-Dichlorobenzidine 71.1 10 ug/L 50.00 142 58-139 5 20 L2 3/4-Methyl phenol 40.5 10 ug/L 50.00 81 34-101 4 20 3-Nitroaniline 65.9 10 ug/L 50.00 132 52-155 5 20 4,6-Dinitro-2-methylphenol 61.0 10 ug/L 50.00 122 49-138 9 20 4-Bromophenyl phenyl ether 55.7 10 ug/L 50.00 111 63-135 7 20 4-Chloro-3-methylphenol 55.0 10 ug/L 50.00 110 33-149 5 20 4-Chloroaniline 74.1 10 ug/L 50.00 148 44-163 2 20 4-Chlorophenyl phenyl ether 53.7 10 ug/L 50.00 107 63-129 5 20 4-Nitroaniline 57.0 10 ug/L 50.00 114 63-147 3 20 4-Nitrophenol 24.2 10 ug/L 50.00 48 10-77 2 20 Acenaphthene 52.9 10 ug/L 50.00 106 64-118 6 20 Acenaphthylene 53.8 10 ug/L 50.00 108 65-119 6 20 Aniline 83.9 10 ug/L 50.00 168 12-197 17 20 Anthracene 55.2 10 ug/L 50.00 110 69-134 4 20 Azobenzene 58.0 10 ug/L 50.00 116 56-129 6 20 Benzo(a)anthracene 55.6 10 ug/L 50.00 111 71-125 4 20 Benzo(a)pyrene 61.9 10 ug/L 50.00 124 67-135 4 20 Benzo(b)fluoranthene 59.4 10 ug/L 50.00 119 56-145 4 20 Benzo(g,h,i)perylene 60.6 10 ug/L 50.00 121 44-149 6 20 Benzo(k)fluoranthene 58.6 10 ug/L 50.00 117 65-138 4 20 Benzoic Acid 18.2 100 ug/L 50.00 36 10-125 27 20 D Benzyl alcohol 42.9 10 ug/L 50.00 86 35-111 4 20 bis(2-Chloroethoxy)methane 49.5 10 ug/L 50.00 99 49-126 6 20 Bis(2-Chloroethyl)ether 40.4 10 ug/L 50.00 81 47-124 12 20 Bis(2-chloroisopropyl)ether 48.5 10 ug/L 50.00 97 42-126 4 20 Bis(2-Ethylhexyl)phthalate 61.0 10 ug/L 50.00 122 59-139 3 20 Butyl benzyl phthalate 61.2 10 ug/L 50.00 122 67-133 5 20 Chrysene 57.4 10 ug/L 50.00 115 64-124 4 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 59 of 66 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Batch P5GO184 - 3510C MS Reporting Result Limit Units Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS Dup (P5G0184-BSD1) Prepared & Analyzed: 07/14/15 Dibenzo(a,h)anthracene 59.4 10 ug/L 50.00 119 49-144 7 20 Dibenzofuran 56.5 10 ug/L 50.00 113 68-113 5 20 Diethyl phthalate 60.6 10 ug/L 50.00 121 70-124 3 20 Dimethyl phthalate 60.1 10 ug/L 50.00 120 71-117 4 20 L2 Di-n-butyl phthalate 61.6 10 ug/L 50.00 123 69-128 3 20 Di-n-octyl phthalate 63.8 10 ug/L 50.00 128 52-150 4 20 Fluoranthene 57.8 10 ug/L 50.00 116 66-135 4 20 Fluorene 57.1 10 ug/L 50.00 114 67-124 4 20 Hexachlorobenzene 58.3 10 ug/L 50.00 117 62-124 5 20 Hexachlorobutadiene 48.2 10 ug/L 50.00 96 42-105 6 20 Hexachlorocyclopentadiene 49.3 10 ug/L 50.00 99 32-117 6 20 Hexachloroethane 45.5 10 ug/L 50.00 91 40-99 4 20 Indeno(1,2,3-cd)pyrene 60.3 10 ug/L 50.00 121 40-150 6 20 Isophorone 56.3 10 ug/L 50.00 113 54-125 6 20 Naphthalene 47.7 10 ug/L 50.00 95 54-111 5 20 Nitrobenzene 52.7 10 ug/L 50.00 105 51-117 5 20 N-Nitroso-di-n-propylamine 51.2 10 ug/L 50.00 102 55-115 3 20 N-Nitrosodiphenylamine 57.1 10 ug/L 50.00 114 70-152 5 20 Pentachlorophenol 58.0 10 ug/L 50.00 116 23-139 6 20 Phenanthrene 58.4 10 ug/L 50.00 117 68-128 5 20 Phenol 23.9 10 ug/L 50.00 48 12-58 3 20 Pyrene 56.7 10 ug/L 50.00 113 62-139 4 20 Surrogate: 2,4,6-Tribromophenol 115 ug/L 100.0 115 49-109 SR Surrogate:2-Fluorobiphenyl 52.2 ug/L 50.00 104 55-96 SR Surrogate:2-Fluorophenol 64.1 ug/L 100.0 64 27-74 Surrogate: Nitrobenzene-d5 48.8 ug/L 50.00 98 53-99 Surrogate: Phenol-d5 41.7 ug/L 100.0 42 11-52 Surrogate: Terphenyl-d14 54.8 ug/L 50.00 110 42-133 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 60 of 66 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Total Metals - Quality Control Analyte Batch P5GO170 - 301 OA Project: PTR.001-4A Level II QC Report 7/22/15 Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Blank (P5G0170-BLK1) Prepared: 07/13/15 Analyzed: 07/14/15 Arsenic BRL 0.010 mg/L Barium BRL 0.010 mg/L Cadmium BRL 0.0010 mg/L Chromium BRL 0.0050 mg/L Lead BRL 0.0050 mg/L Selenium BRL 0.020 mg/L Silver BRL 0.0050 mg/L LCS (P5G0170-BS1) Prepared: 07/13/15 Analyzed: 07/14/15 Arsenic 0.256 0.010 mg/L 0.2500 102 80-120 Barium 0.260 0.010 mg/L 0.2500 104 80-120 Cadmium 0.256 0.0010 mg/L 0.2500 103 80-120 Chromium 0.260 0.0050 mg/L 0.2500 104 80-120 Lead 0.257 0.0050 mg/L 0.2500 103 80-120 Selenium 0.257 0.020 mg/L 0.2500 103 80-120 Silver 0.102 0.0050 mg/L 0.1000 102 80-120 Batch P5GO172 - 3050B Blank (P5G0172-BLK1) Prepared & Analyzed: 07/13/15 Arsenic BRL 0.25 mg/kg wet Barium BRL 0.50 mg/kg wet Cadmium BRL 0.25 mg/kg wet Chromium BRL 0.25 mg/kg wet Lead BRL 0.25 mg/kg wet Selenium BRL 0.50 mg/kg wet Silver BRL 0.25 mg/kg wet This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 61 of 66 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Hart & Hickman (Charlotte) Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Total Metals - Quality Control Analyte Batch P5G0172 - 3050B Project: PTR.001-4A Level II QC Report 7/22/15 Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes LCS (P5G0172-BS1) Prepared & Analyzed: 07/13/15 Arsenic 24.4 0.25 mg/kg wet 25.00 98 80-120 Barium 25.3 0.50 mg/kg wet 25.00 101 80-120 Cadmium 24.7 0.25 mg/kg wet 25.00 99 80-120 Chromium 25.0 0.25 mg/kg wet 25.00 100 80-120 Lead 24.4 0.25 mg/kg wet 25.00 98 80-120 Selenium 24.3 0.50 mg/kg wet 25.00 97 80-120 Silver 9.82 0.25 mg/kg wet 10.00 98 80-120 Batch P5G0173 - 7471 B Blank (P5G0173-BLK1) Prepared & Analyzed: 07/13/15 Mercury BRL 0.020 mg/kg wet LCS (P5G0173-13S1) Prepared & Analyzed: 07/13/15 Mercury 0.442 0.020 mg/kg wet 0.4167 106 80-120 Batch P5G0189 - 7470A Blank (1135G0189-131LKII) Prepared & Analyzed: 07/14/15 Mercury BRL 0.00020 mg/L LCS (P5G0189-BS1) Prepared & Analyzed: 07/14/15 Mercury 0.00976 0.00020 mg/L 0.009375 104 80-120 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 62 of 66 P R 1 S M Full -Service Analytical s Environmental Solutions LABORATOR, Level II QC Report 7/22/15 Hart & Hickman (Charlotte) Project: PTR.001-4A Attn: Aaron Oswald 2923 South Tryon St. Ste 100 Charlotte, NC 28203 General Chemistry Parameters - Quality Control Prism Work Order: 5070164 Time Submitted: 7/10/2015 8:50:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5G0176 - Solids, Dry Weight Blank (P5G0176-BLK1) Prepared & Analyzed: 07/13/15 % Solids 100 0.100 % by Weight Duplicate (P5G0176-DUP2) Source: 5070164-01 Prepared & Analyzed: 07/13/15 % Solids 87.9 0.100 % by Weight 88.6 0.7 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 63 of 66 Sample Extraction Data Prep Method: Solids, Dry Weight Lab Number Batch Initial Final Date/Time 5070164-01 P5G0176 30 g 30 g 07/13/15 11:55 5070164-02 P5G0176 30 g 30 g 07/13/15 11:55 5070164-03 P5G0176 30 g 30 g 07/13/15 11:55 5070164-04 P5G0176 30 g 30 g 07/13/15 11:55 Prep Method: 3510C MS Lab Number Batch Initial Final Date/Time 5070164-05 P5G0184 1000 mL 1 mL 07/14/15 11:30 5070164-06 P5G0184 1000 mL 1 mL 07/14/15 11:30 5070164-07 P5G0184 1000 mL 1 mL 07/14/15 11:30 Prep Method: 3546 Lab Number Batch Initial Final Date/Time 5070164-01 P5G0175 30.02 g 1 mL 07/13/15 10:45 5070164-02 P5G0175 30.05 g 1 mL 07/13/15 10:45 5070164-03 P5G0175 30 g 1 mL 07/13/15 10:45 5070164-04 P5G0175 30 g 1 mL 07/13/15 10:45 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 5070164-05 P5G0170 50 mL 50 mL 07/14/15 8:15 5070164-06 P5G0170 50 mL 50 mL 07/14/15 8:15 5070164-07 P5G0170 50 mL 50 mL 07/14/15 8:15 5070164-08 P5G0170 50 mL 50 mL 07/14/15 8:15 Prep Method: 3050E Lab Number Batch Initial Final Date/Time 5070164-04 P5G0172 1.98 g 50 mL 07/13/15 10:11 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 5070164-05 P5G0189 20 mL 30 mL 07/14/15 8:30 5070164-06 P5G0189 20 mL 30 mL 07/14/15 8:30 5070164-07 P5G0189 20 mL 30 mL 07/14/15 8:30 5070164-08 P5G0189 20 mL 30 mL 07/14/15 8:30 Prep Method: 7471E Lab Number Batch Initial Final DatelTime 5070164-04 P5G0173 0.62 g 50 mL 07/13/15 10:18 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 5070164-05 P5G0244 10 mL 10 mL 07/14/15 13:49 5070164-06 P5G0244 10 mL 10 mL 07/14/15 13:49 5070164-07 P5G0393 10 mL 10 mL 07/21/15 10:25 5070164-09 P5G0244 10 mL 10 mL 07/14/15 13:49 Prep Method: 5035 Lab Number Batch Initial Final Date/Time 5070164-01 P5G0262 5.08 g 5 mL 07/16/15 9:05 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 64 of 66 Sample Extraction Data Prep Method: 5035 Lab Number Batch Initial Final Date/Time 5070164-02 P5G0262 5.52 g 5 mL 07/16/15 9:05 5070164-03 P5G0262 4.79 g 5 mL 07/16/15 9:05 5070164-04 P5G0262 5.78 g 5 mL 07/16/15 9:05 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 65 of 66 Full -Service Analytical & P R I S M Environmental Solutions LABORATORIES, INC. 449 Springbrook Road ® Charlotte, NC 28217 Phone 704/529-6361I @ Fax: 704/525-0409 Client Company Name: J- 01 ca 61 Report To/Contact Name: A—,10A Reporting Address: 2123 r. C-L . 7F,-4 T, - A)(. CHAIN OF CUSTODY RECORIC "AGE I OF —L QUOTE 9 TO ENSURE PROPER BILLING: NEREMEM (0 YES NO N/A (0 Samples INTACT rwon arrival? 0 (.0 Received ON VVET ICE? CD PROPER PRESERVATIVES Indicated? X - ------ ---- Recbived WITHIN HOLDINGTIMES? CUSTODY SEALS INTACT? VOLA-11LES rec'd W/0U'l HEADSPACE? -Al PROPER CONIAINERS rised? TEMP: Them, IC): j,,4—j-" Observed: / Corr:_ Phone: -Fax(Yes)(No): Purchase Order No./Billing Reference pff 001 tlZ/A TO BE FILLED IN BY CLIENTISAMPLING PERSONNEL, Email Address: A 04/0,1,0 d", Requested Due Date LJ I Day U 2 Days Q 3 Days C3 4 Days Days Certification: NELAC— DoD— FL— NC Xrk EDD Type: PExcel Other DF —Z C17+—v 6molsbofo Must Be "Working Days" 0 6-9 Days 0 Standard 10 day. — Pre -Approved SC— OTHER— N/A PrArre Site Location Name: of Samples received after 14:00 will be processed next business day. Turnaround time is based on business days, excluding weekends and holidays. Water Chlorinated: YES NO_ Site Location Physical Address: Cj (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES Sample Iced Upon Collect !on: YES &/-NO— �-eem boro , INC RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) . I TIME MATRIX SAMPLE CONTAINER ANALYSIS REQUESTED PRISM CLIENT DATE COLLECTED SAMPLE DESCRIPTION COLLECTED MILITARY (SOIL, PRESERVA-REMARKS WATER OR *TYPE NO. SIZE TIVES k, LAB ID NO. HOURS SLUDGE) SEE BELOW 'N 19 5 �o 000 C-0,111 4 U11A 'X X aq V1 4 F'4ti) '7 X Tmv-6 �t �0 Tfil) 0 IJ4 Tc VE X V, Ai J 4L MM=Z=MkMnZi I'Vleo e-- Affiliation Sampler's Signature O/�--Sampled By (Print Name) Upon relinquishing, this Chain of Custody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the ?!ism Project Manager. There will be charges for any changes after analyses have been initialized. ,- Relinquished BySignature) %7/ —// Received By: S Xia Date Military/Hours Site Arrival Time: Additional Comments: IS ('0 ft. jo Relinquished By: (Sigbatufe)",­' J1 FZeceive6 By'(Sokat,,# L Date Sqe Departure Time: S -ILch Relinquished By: Rec Pris aboratorles By: Date 3 Reld Fee: Mileage: Method of Shipment: NOTE•ALL SAMPLE COOLERS SHOULD BE TAPED SHUT V_P4,<US SEALS FOR TRANSPORTATION TO THE LABORATORY. SALES ARE NOT ACCEPTED AND VERIFIED AGAINST WkUN 'flL CEIVED AT THE LABORATORY. COC Group No. 0 Fed Ex tqj-JPS— El Hand -delivered U Prism Field Service VOther 70 NPDES:GROUNDWATER: INKING WATER: SOLID WASTE: LANDFILL OTHER: ENCLSCCESC ENC LSC ENC P� UST� � �RC �CERCLA LSC 0Ni I3NCLSCNC 0 SC L3 NC Ll SC 0 NC D SC F1 1­11 0 D 0 0 — 0 El -- - 0 *CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) Appendix C Groundwater Sampling Records hart hickman SMARTER ENVIRONMENTAL SOLLMONS hart 0�Z hickman LOW -FLOW GROUND WATER SAMPLING RECORD Job No: Well ID: Well Location: Z-11 11 J - -3,4 ;4�1 /"' - ,, � _. 6 .., �,, i � S A, Facility Name: Date: Top of Casing Elevation (ft msl): Casing Material: Volume of Water Per Well' Volume: Total Well Depth (feet): Screen Interval (feet): Depth to Water (feet): Well Diameter: r. Sampling Personnel: Bryan Wence Type of Pump: Tubing Material: Pump/Tubing set at: 6 Weather Conditions: 5a, "!9'Z Notes: GROUND WATER SAMPLING PARAMETERS Water Volume Pumping DO Temp. S. Cond. pH ORP Turbidity Time Level li I o 5' Al Pumped Rate (mg/1 S. s/cm) (MV) (NTU) 0 10 1( 15 1.32 S T2__ 77.7q -js 1116 )q, 5-0 5-6.7:r 1101 7, 1 131,16 0.12 61 0 0. 5 ZA &L4L_ Other Sample Parameters: Sampled at: 3 Parameters taken with: I/ Sample Delivered to: N, by: Field Filtration: ( )Yes ( )No If yes, which sample parameters were field filtered Sample Parameter Containers (Types, Number of Containers, Preservatives): at: vl 5VO(I Y11 AA in File:Low Flow Groundwater Sampling Record Template - Copy.xls, Sheet 9 on hart hickman LOW -FLOW GROUND WATER SAMPLING RECORD Job No: Well ID: Well Location: Facility Name: Date: 7f 7# S Top of Casing Elevation (ft msl): Casing Material: Pvc Volume of Water Per Well Volume: Total Well Depth (feet): Screen Interval (feet): Depth to Water (feet): Fr' Well Diameter: C tr Sampling Personnel: Bryan Wence j, t%�( Type of Pump: Pecs Tubing Material: roi4e11-1 /6-6 Pump/Tubing'set at: ft. Weather Conditions: <605 Notes: GROUND WATER SAMPLING PARAMETERS Water Volume Pumping DO Temp. S. Cond. pH" ORP Turbidity Time Level Pumped Rate (mg/i} (OC) S/cm (SU) ' m�V (NTU) [VSS ,✓/zr t sU l C .?_S ZS 23 S ./ 12.c.. 53 q7 t / U Zs�2 sti s�.� lfS_ 2 �a �U3 -IMZ C.� 2 —717-1 1542 2' -77 S j Other Sample Parameters: Sampled at: // 1 S Parameters taken with: PI fur b.` d"me-(et Sample Delivered to: by: at: Field Filtration: ( ) Yes ( ) No If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Number o-T' f Containers, Preservatives): Ms ' Lt VUA3 i 7- FrPs �-I L ,1, v� 6re5, File:Low Flow Groundwater Sampling Record Template - Copy.xls, Sheet 1 hart .- hickman S'AAP%%TCR t=%VTR.0NrAEr4TA.1 SOLUTIMS LOW -FLOW GROUND WATER SAMPLING RECORD Stabilization Criteria DO +/- 0.3 mg/1 Turb. +/- 10% (<10 NTUs) S. Cond. +/- 3% ORP +/- 10 mV pH +/- 0.1 unit Job No: Well ID: Well Location: 7-M w - S Facility Name: Date: 7/ -7% <S Top of Casing Elevation (ft msl): Casing Material: VL Volume of Water Per Well Volume: Total Well Depth (feet): Screen Interval (feet): Depth to Water (feet): 10, It) Well Diameter: Sampling Personnel: Bryan Wence o �• �l(%Sr Type of Pump: ��i pvmp Tubing Material: ( PalydAyle* Pump/Tubing set at: l 3 ft. Weather Conditions: �05 S"my Notes: GROUND WATER SAMPLING PARAMETERS Water Volume Pumping DO Temp. S. Cond. pH ORP Turbidity Time Level Pumped Rate imgza f-C-1 S/cm (SU) (MV) NTU Lfb 411,' ZS.7? S Zq G. 9.1 7C•f� 23 i 1, S� 3 �SU z 2• S -z z2, 6 6s —t45, s .2,0,7 ` r� 1� `LZ&v 6�z- �� r'S2,s '3�v, 3 I I S 3 q 2�1(O 6-5-5IOS, 3 y i YLO 7 x S' 6 -S G (— -- -1 341 65f3 6• S6 S 15 Other Sample Parameters: Sampled at: I /�1 5 Parameters taken with: YS -5 ` SSA p -r ch;6 mv, of Ac.r() T P 1 Sample Delivered to: by: at: Field Filtration: ( ) Yes ( ) No If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Number of Containers, Preservatives): T VU�s Lf ZIOA5 C `L 1p(o, 14U L-n greJ SVUCsl 4,nbef I j,W Quay bj �.170yogre5• v File:Low Flow Groundwater Sampling Record Template - Copy.xls, Sheet 1 hart � A� omckmax m - a�uPAmTmR 15roUmTu�*� LOW -FLOW GROUND WATER SAMPLING RECORD Job No: Well ID: M Well Location: � Facility Name: ' Top cfCasing Elevation U\mu0: Casing Material: Volume ofWater PerVVe Total Well Depth (feet): —Screen Interval (feet): Depth tnWater (feet): Sampling Personnel: Type of Pump: Tubing Material: Pump/Tubing Weather Conditions: Notes: GROUND WATER SAMPLING PARAMETERS Water Volume Pumping DO Temp. G.Cond. | pH Time Level | 15,35 774 _______ _______� Other Sample Parameters: Sampled Parameters taken with: Sample Delivered to: by: Field Filtration: ( )Yes ( )No Ifyes, which sample parameters were field filtered: Sample Containers Volume: Well Diameter: et at: at Turbidity _ Groundwater Sampling Record Template 'cop^xis,Sheet ' mmam�� � ~�~ hickman � �_ a1AAmnrm*mCImWIONS SAMPLING RECORD LOW -FLOW GROUND WATER ! Job No: Well ID: Facility Name: Top of Casing Elevation (ft msl): Casing Material: PVC Volume of Water Per Well Volume: Total Well Depth (feet): Screen Interval (feet): Depth to Water (feet): Well Diameter: Type of Pump: C� r1h Tubing Material: f,vive Pumpfrubing set at: Weather Conditions: 74)s 011"dy Notes: Well Location: GROUND WATER SAMPLING PARAMETERS D(harSample Parameters: � Sample Delivered to: - by: at: Field Filtration: ( )Yes ( )No If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Number of Containers, Preservatives): �Vcy-)S(Ip'es' 1qCL-)-L Turbidity ft. pile:Low Flow Groundwater Sampling Record Template 'o~'�s,Sheet ` hart Wf%%ft, m hickan , 11 St"I'ARTER, LOW -FLOW GROUND WATER I SAMPLING RECORD I Job No: Well ID: Well Location: Facility Name- Date: -7/5, Top of Casing Elevation (ft msl): Casing Material: pvc, Volume of Water Per WE Total Well Depth (feet): Screen Interval (feet): Depth to Water (feet): Sampling Personnel: Bryan Wence 63uo Type of Pump: 81-)7 Weather Conditions: Tubing Material: —Palye4l, , x1xe ePump/Tubing Notes: 1s30 ­01 p,,(Sed d-ol S* Volume: Well Diameter: 11f at: GROUND WATER SAMPLING PARAMETERS Water Volume Pumping DO Temp. S. Cond. pH ORP Turbidity Time Level Pumped Rate m /I (OC) (VS/cm) (SU) (MV) (NTU) if I 5-, S-'s 11 -7 —7 /7 15- la - I Other Sample Parameters: Sampled at: 4 3' f Parameters taken with: vo Tf I T, b, 1; tm&W Sample Delivered to: I by: at: Field Filtration: ( )Yes ( )No If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Number of Containers, Preservatives): TVK5 Llyvro (ILL \A- ,vAgO AmW -,Sok1) )7y ON At .4,110,As /e _t ft. File:1-ow Flow Groundwater Sampling Record Template - Copy.xis, Sheet I hart,TZ hickman LOW -FLOW GROUND WATER SAMPLING RECORD Job No:l Well ID: r bl' Well Location:" Facility Name: Date: 71VI S Top of Casing Elevation (ft msl): Casing Material: (2/G Volume of Water Per Well Volume: Total Well Depth (feet): Screen Interval (feet): Depth to Water (feet): Well Diameter: ,P Sampling Personnel: Bryan Wence ti . olilr�" Type of Pump: r wth Tubing Material (,a14'z r Pump/Tubing set at: ft, Weather Conditions: 05 Notes: GROUND WATER SAMPLING PARAMETERS Water Volume Pumping DO Temp. S. Cond. pH ORP Turbidity Time Level Pumped Rate m /I (°C)(AS/cm) (SU) (MV) NTU i (q so / 1" �Al aG S3 /G 0,7 i, 9 I StG V4 V.W , 3 �r 2,sff rr ,' fla i e$�4-)j),,,,a 4-v (ec 111�a� G 3 t— Other Sample Parameters: Sampled at: Parameters taken with: Y _ ;S1 6 dI ee' Sample Delivered to: by: at: Field Filtration: ( ) Yes ( ) No If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Number of Containers, Preservatives): TVOC Lf V01 (' , C,ps HCL i, z woes- )—r amhV � V 7 ('s mot~ r g> CMP M I'As 1 `2 d t,I j File:Low Flow Groundwater Sampling Record Template - Copy.xis, Sheet 1 Appendix D ACM and Lead -Based Paint Survey Reports hart � hickman SMARTER ENVI RONM ENrAL SOLLMONS July 20, 2015 Ms. Cindy J. Nolan Brownfields Section Chief Resource Conservation and Restoration Division U.S. Environmental Protection Agency 61 Forsyth St. SW Atlanta, GA 30303 Re: Asbestos Inspection Report 1005, 1015, 1201 S. Eugene Street Greensboro, NC PTRC Brownfield Assessment Grant # BF-OOD12113-0 H&H Job No. PTR.001 Dear Cindy: 1.0 Introduction Hart & Hickman, PC (H&H) completed an asbestos survey of the commercial/industrial buildings located at 1005, 1015 and 1201 S. Eugene Street in Greensboro, Guilford County, North Carolina. The City of Greensboro and the Greensboro Housing Authority (GHA) currently own the site. The site is comprised of three parcels totaling 6.76 acres. 1201 S. Eugene Street is comprised of an approximate 12,500 square foot (ft2) office/warehouse/maintenance building, loading docks, canopies, storage buildings, and parking lot. The GHA maintenance facility was reportedly constructed in the mid- to late 1970s and have been vacant since approximately 2006. 1005 and 1015 S. Eugene Street do not currently have any structures on the property. Considering the age of the buildings, a potential for asbestos containing materials (ACMs) exists. Therefore, H&H conducted a survey of the site buildings. The method and results of the asbestos survey are presented in the sections below. 2923 South Tryon Street, Suite 100 3334 Hillsborough Street Charlotte, NC 28203 Raleigh, NC 27607 www.harthickman.com 704.586.0007 main 919.847.4241 main Ms. Cindy J. Nolan July 20, 2015 Page 2 2.0 Asbestos Survey Activities On July 6, 2015, Mr. Gabriel Steil of H&H conducted an asbestos survey of the site buildings. The asbestos survey was conducted in general accordance with the North Carolina Health Hazard Control Unit (HHCU) guidelines for asbestos building inspections. The objectives of the asbestos survey were to: • identify and assess the condition and friability of suspect asbestos -containing materials, on the interior and exterior of the buildings, including the roof system(s); • collect samples from a representative number of random locations in accordance with the Asbestos Hazard Emergency Response Act (AHERA) guidelines; and • prepare a written report detailing findings of the inspection. Mr. Steil is trained and licensed as an NC HHCU asbestos inspector (#12879). AHERA guidelines require that the following minimum number of bulk samples be collected from each homogeneous area: • Three, five, and seven bulk samples are to be collected from interior and exterior surfacing materials with volumes totaling 1,000 square ft, 1,000 to 5,000 square ft, and greater than 5,000 square ft, respectively. • Three bulk samples are to be collected from each material identified as thermal system insulation (TSI). TSI that was identified by the inspector as fiberglass or as a non -suspect material was not sampled. • Two bulk samples are to be collected from TSI that is patched, cemented pipe elbow material commonly found on TSI joints, and miscellaneous and non -friable materials (including floor tile, ceiling tile, and exterior siding). H&H utilized half -faced respirators equipped with a High Efficiency Particulate Air (HEPA) filter for respiratory protection while collecting samples of friable, suspect ACMs. H&H also utilized wet methods to collect bulk samples of suspect ACMs in order to minimize the potential Id hart hickman S:WAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Asbestos Inspection\Draft Asbestos Repomdocx SMARTER ENVIRONMENTAL SOLUTIONS Ms. Cindy J. Nolan July 20, 2015 Page 3 for a fiber release. Wet methods consisted of applying water amended with soap via a spray bottle directly onto the suspect ACMs during sampling activities. H&H decontaminated tools used to collect suspect ACM samples with amended water. H&H collected amended water utilized for decontamination within the sample bag of the collected sample during decontamination activities. Sampled friable suspect ACMs were then sealed with either caulk or tape to minimize the potential for a future fiber release. For each homogeneous area, H&H directed the laboratory to stop analysis on that material in the event of a positive asbestos detection. H&H collected samples of the following suspect ACMs identified during our survey: • floor tile and associated mastic (8 homogenous materials) • shoe molding and associated mastic (2 homogenous materials) • drywall, tape and spackle (1 homogeneous material) • ceiling tile (2 homogenous materials) • roof system (4 homogeneous materials) • flashing associated with roof system (1 homogeneous material) • mastic associated with roof HVAC systems (1 homogeneous material) • asphaltic shingles (1 homogeneous material). 3.0 Positive Asbestos Detections Samples collected from the suspect ACMs within the project area were submitted to Carolina Environmental Inc. (CEI) Labs of Cary, NC. CEI is a National Voluntary Laboratory Accreditation Program (NVLAP) certified laboratory. Based on the AHERA guidelines, 56 samples were analyzed from 20 homogenous materials associated with the building. The results of laboratory analysis indicate that the following suspect ACM sampled during the survey contains asbestos at a concentration of >1%. By EPA's definition, the following material is an ACM: Id hart hickman S:WAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Asbestos Inspection\Draft Asbestos Repomdocx SMARTER ENVIRONMENTAL SOLUTIONS Ms. Cindy J. Nolan July 20, 2015 Page 4 • floor tile (white with gray gashes — 12"xl2", approximately 1,900 square ft.) and associated mastic (black) located in the main hallway, northern hallway and in the men's and women's restrooms contains 2% and 10% Chrysotile asbestos, respectively (Sample 001); • floor file (white with red gashes — 12"xl2", approximately 3 square ft.) and associated mastic (black) located in the main hallway entrance to the electrical room contains 3% and 5% Chrysotile asbestos, respectively (Sample 004); • mastic (black — approximately 20 square ft.) associated with the non -asbestos containing floor tile (dark brown — 9"x9") located in the warehouse toilet area contains 5% Chrysotile asbestos (Sample 013); • roofing (tar and fiber — approximately 2,700 square ft.) located on the eastern section of the canopy roof contains 10% Chrysotile asbestos (Sample 019). Figure 1 illustrates the locations of ACM based upon the work completed for this survey. The asbestos analytical results are included in Appendix A. Photographs of the ACMs are included in Appendix B and a copy of Mr. Steil's NC HHCU Asbestos Inspector license is included in Appendix C. 4.0 Assessment and Recommendations A summary of the identified ACMs, their AHERA and NESHAP Assessment Categories, and recommendations for managing the ACMs are provided below. Category I Non -Friable ACMs H&H characterized the asbestos -containing floor tile and associated mastics and the roofing material under the AHERA Assessment Category "asbestos containing building material (ACBM) with potential for damage." The EPA classifies these materials as non -friable Category I materials under the NESHAP regulations. Removal of non -friable Category I materials is not required prior to demolition as long as routine demolition activities are conducted including no Id hart hickman S:WAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Asbestos Inspection\Draft Asbestos Repomdocx SMARTER ENVIRONMENTAL SOLUTIONS Ms. Cindy J. Nolan July 20, 2015 Page 5 visible emissions, wet methods, and the presence of a "competent person" on -site during demolition activities. In addition, the landfill that receives the demolition debris must be notified and must be permitted to accept non -friable Category I asbestos containing material. Landfills may charge a premium for debris containing asbestos. Therefore, removal of the ACMs prior to demolition should be considered. 5.0 Limitations This report is an inspection report only and must not be taken as a project design plan. Also, there is the potential that other ACMs could be present at the site which are not readily accessible due to the limitations of non-destructive sampling techniques used in baseline surveys (i.e., wall or column interiors, etc.). If other suspect ACMs are identified during renovation or demolition activities, they should be sampled to determine asbestos content and properly managed. We appreciate the opportunity to assist with this project. If you have any questions concerning this report, please do not hesitate to contact us. Sincerely, Hart & Hickman, PC L=7 - W,(-k Gabriel Steil NC Asbestos Inspector #12879 Attachments r;< ZwAC. M OAi'V Leonard Moretz, PG RSM Senior Consultant S:WAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Asbestos Inspection\Draft Asbestos Repomdocx Id hart hickman SMARTER ENVIRONMENTAL SOLUTIONS 0-0 00VA ODOR WOOD SHOP NERAL SHOP c,<.HS TOOL ROOM rvlRr FeraclNc WOMEN'S LOCKER ROOM SHOWER WORKROOM LOCKS MEN (j w 004 M wouEry ; MEN'S LOCKER ROO SUPEAVISOA INSPECTOR ✓ LOOKERS FACILITIES SUPFRVSOR SUPERVISOR NOR. MFETrNG ROOM 0 a L DEPT. w SECRETARY N APPROXIMATE 0 40 80 SCALE IN FEET Location of asbestos containing materials Storage Building I I Storage Building Eastern Canopy Folq Western Canopy — LOADING DOCK OVEHHEAO SHIPPING U 2i WORK ......� �.......i wrAE ORDER FENCING CLERKS TOILET 013 ELECTRICAL ROOM WAREHOUSE FO 0-1 1 Sample Identification Appendix A Analytical Results hart hickman SMARTER ENVIRONMENTAL SOLUTIONS rc L/N BS July 13, 2015 Hart & Hickman, P. C. 2923 S. Tryon Street, Suite 100 Charlotte, NC 28203 CLIENT PROJECT: 1005,1015,1201 S. Eugene St. Greensboro, NC; PTR-001 CEI LAB CODE: B15-4230 Dear Customer: Enclosed are asbestos analysis results for PLM Bulk samples received at our laboratory on July 7, 2015. The samples were analyzed for asbestos using polarizing light microscopy (PLM) per the EPA 600 Method. Sample results containing >1 % asbestos are considered asbestos -containing materials (ACMs) per EPA regulatory requirements. The detection limit for the EPA 600 Method is <1 % asbestos by weight as determined by visual estimation. Thank you for your business and we look forward to continuing good relations. If you have any questions, please feel free to call our office at 919-481-1413. NVtA NVLAP Lab Code 101768.0 Kind Regards, Tianbao Bai, Ph.D., CIH Laboratory Director 107 New Edition Court • Cary, NC 27511 • 919.481.1413 AMENDED CEIL/XBS ASBESTOS ANALYTICAL REPORT By: Polarized Light Microscopy Prepared for Hart & Hickman, P. C. CLIENT PROJECT: 1005,1015,1201 S. Eugene St. Greensboro, NC; PTR -001 CEI LAB CODE: B15-4230 TEST METHOD: EPA 600 / R93 / 116 and EPA 600 / M4-82 / 020 REPORT DATE. 07/09/15 TOTAL SAMPLES ANALYZED: 40 # SAMPLES >1 % ASBESTOS. 6 TEL: 866-481-1412 www.ceilabs.com AMENDED Asbestos Report Summary By: POLARIZING LIGHT MICROSCOPY L/�C3S PROJECT: 1005,1015,1201 S. Eugene St. CEI LAB CODE: B15-4230 Greensboro, NC; PTR-001 METHOD: EPA 600 / R93 / 116 and EPA 600 / M4-82 / 020 ASBESTOS Client ID Layer Lab ID Color Sample Description % 001A B55606A White,Gray Floor Tileremq"Mml B55606B Black Mastic ' , 001 B B55607 Sample Not Analyzed per COC 002A B55608A Off-white,Gray Floor Tile None Detected B55608B Yellow Mastic None Detected 002E B55609A Off-white,Gray Floor Tile None Detected B55609B Yellow Mastic None Detected 003A B55610A Blue,White Floor Tile None Detected B55610B Yellow Mastic None Detected 003B B55611A Blue,White Floor Tile None Detected B55611 B Yellow Mastic None Detected 004A B55612A White,Red Floor Tile B55612B Black Mastic 004B B55613 Sample Not Analyzed per COC 005A B55614A Off-white,Gray Floor Tile None Detected B55614B Yellow Mastic None Detected 005B B55615A Off-white,Gray Floor Tile None Detected B55615B Yellow Mastic None Detected 006A B55616A Brown,Red Floor Tile None Detected B55616B Yellow Mastic None Detected 006B B55617A Brown,Red Floor Tile None Detected B55617B Yellow Mastic None Detected 007A B55618A Gray Floor Tile None Detected B55618B Brown Mastic None Detected 007B B55619A Gray Floor Tile None Detected B55619B Brown Mastic None Detected 008A B55620 Gray Shoe Molding None Detected 008B B55621A Gray Shoe Molding None Detected B55621 B Yellow Mastic None Detected 009A B55622A Black Shoe Molding None Detected B55622B Brown Mastic None Detected Page 1 of 2 AMENDED Asbestos Report Summary By: POLARIZING LIGHT MICROSCOPY L/�C3S PROJECT: 1005,1015,1201 S. Eugene St. CEI LAB CODE: B15-4230 Greensboro, NC; PTR-001 METHOD: EPA 600 / R93 / 116 and EPA 600 / M4-82 / 020 ASBESTOS Client ID Layer Lab ID Color Sample Description % 009B B55623A Black Shoe Molding None Detected B55623B Brown Mastic None Detected 010A B55624 White,Tan Drywall/ Spackle & Tape None Detected 010E B55625 White,Tan Drywall/ Spackle & Tape None Detected 010C B55626 White,Tan Drywall/ Spackle & Tape None Detected 011A B55627 White,Tan Ceiling Tile None Detected 011 B B55628 White,Tan Ceiling Tile None Detected 012A B55629 White,Tan Ceiling Tile None Detected 012B B55630 White,Tan Ceiling Tile None Detected 013A B55631A Brown Floor Tile None Detected B55631 B Black Mastic 013B B55632A Brown Floor Tile None Detected B55632B Sample Not Analyzed per COC 014A B55633 Black Roofing None Detected 014B B55634 Black Roofing None Detected 014C B55635 Black Roofing None Detected 015A B55636 Black Flashing None Detected 015B B55637 Black Flashing None Detected 015C B55638 Black Flashing None Detected 016A B55639 Black Mastic None Detected 016B B55640 Black Mastic None Detected 017A B55641 Black Shingle None Detected 017B B55642 Black Shingle None Detected 018A B55643 Black,Brown Roofing None Detected 018E B55644 Black,Brown Roofing None Detected 019A B55645 Black,Brown Roofing �. 019B B55646 Sample Not Analyzed per COC 020A B55647 Black,Brown Roofing None Detected 020B B55648 Black,Brown Roofing None Detected Page 2 of 2 rc AMENDED ASBESTOS BULK ANALYSIS By: POLARIZING LIGHT MICROSCOPY L/�C35 Client: Hart & Hickman, P. C. CEI Lab Code: B15-4230 2923 S. Tryon Street, Suite 100 Date Received: 07-07-15 Charlotte, NC 28203 Date Analyzed: 07-08-15 Date Reported: 07-09-15 Project: 1005,1015,1201 S. Eugene St. Greensboro, NC; PTR-001 ASBESTOS BULK PLM, EPA 600 METHOD Client ID Lab Lab NON -ASBESTOS COMPONENTS ASBESTOS Lab ID Description Attributes Fibrous Non -Fibrous 001A Floor Tile Heterogeneous 98% Vinyl B55606A White,Gray Non -fibrous Bound B55606B Mastic Heterogeneous 90% Tar Black Non -fibrous Bound 001 B Sample Not Analyzed B55607 per COC 002A Floor Tile Heterogeneous 100% Vinyl None Detected B55608A Off-white,Gray Non -fibrous Bound B55608B Mastic Heterogeneous 100% Mastic None Detected Yellow Non -fibrous Bound 002B Floor Tile Heterogeneous 100% Vinyl None Detected B55609A Off-white,Gray Non -fibrous Bound B55609B Mastic Heterogeneous 100% Mastic None Detected Yellow Non -fibrous Bound 003A Floor Tile Heterogeneous 100% Vinyl None Detected B55610A Blue,White Non -fibrous Bound Page 1 of 9 rc AMENDED ASBESTOS BULK ANALYSIS (:EI By: POLARIZING LIGHT MICROSCOPY L/�C35 Client: Hart & Hickman, P. C. CEI Lab Code: B15-4230 2923 S. Tryon Street, Suite 100 Date Received: 07-07-15 Charlotte, NC 28203 Date Analyzed: 07-08-15 Date Reported: 07-09-15 Project: 1005,1015,1201 S. Eugene St. Greensboro, NC; PTR-001 ASBESTOS BULK PLM, EPA 600 METHOD Client ID Lab Lab NON -ASBESTOS COMPONENTS ASBESTOS Lab ID Description Attributes Fibrous Non -Fibrous B55610B Mastic Heterogeneous 100% Mastic None Detected Yellow Non -fibrous Bound 003B Floor Tile Heterogeneous 100% Vinyl None Detected B55611A Blue,White Non -fibrous Bound B55611 B Mastic Heterogeneous 100% Mastic None Detected Yellow Non -fibrous Bound 004A Floor Tile Heterogeneous 97% Vinyl B55612A White,Red Non -fibrous Bound B55612B Mastic Heterogeneous 95% Tar Black Non -fibrous Bound 004B Sample Not Analyzed B55613 per COC 005A Floor Tile Heterogeneous 100% Vinyl None Detected B55614A Off-white,Gray Non -fibrous Bound B55614B Mastic Heterogeneous 100% Mastic None Detected Yellow Non -fibrous Bound Page 2 of 9 rc AMENDED ASBESTOS BULK ANALYSIS (:EI By: POLARIZING LIGHT MICROSCOPY L/�C35 Client: Hart & Hickman, P. C. CEI Lab Code: B15-4230 2923 S. Tryon Street, Suite 100 Date Received: 07-07-15 Charlotte, NC 28203 Date Analyzed: 07-08-15 Date Reported: 07-09-15 Project: 1005,1015,1201 S. Eugene St. Greensboro, NC; PTR-001 ASBESTOS BULK PLM, EPA 600 METHOD Client ID Lab Lab NON -ASBESTOS COMPONENTS ASBESTOS Lab ID Description Attributes Fibrous Non -Fibrous 005B Floor Tile Heterogeneous 100% Vinyl None Detected B55615A Off-white,Gray Non -fibrous Bound B55615B Mastic Heterogeneous 100% Mastic None Detected Yellow Non -fibrous Bound 006A Floor Tile Heterogeneous 100% Vinyl None Detected B55616A Brown, Red Non -fibrous Bound B55616B Mastic Heterogeneous 100% Mastic None Detected Yellow Non -fibrous Bound 006B Floor Tile Heterogeneous 100% Vinyl None Detected B55617A Brown, Red Non -fibrous Bound B55617B Mastic Heterogeneous 100% Mastic None Detected Yellow Non -fibrous Bound 007A Floor Tile Heterogeneous 100% Vinyl None Detected B55618A Gray Non -fibrous Bound Page 3 of 9 rc AMENDED ASBESTOS BULK ANALYSIS (:EI By: POLARIZING LIGHT MICROSCOPY L/�C35 Client: Hart & Hickman, P. C. CEI Lab Code: B15-4230 2923 S. Tryon Street, Suite 100 Date Received: 07-07-15 Charlotte, NC 28203 Date Analyzed: 07-08-15 Date Reported: 07-09-15 Project: 1005,1015,1201 S. Eugene St. Greensboro, NC; PTR-001 ASBESTOS BULK PLM, EPA 600 METHOD Client ID Lab Lab NON -ASBESTOS COMPONENTS ASBESTOS Lab ID Description Attributes Fibrous Non -Fibrous B55618B Mastic Heterogeneous 100% Mastic None Detected Brown Non -fibrous Bound 007B Floor Tile Heterogeneous 100% Vinyl None Detected B55619A Gray Non -fibrous Bound B55619B Mastic Heterogeneous 100% Mastic None Detected Brown Non -fibrous Bound 008A Shoe Molding Heterogeneous 100% Vinyl None Detected B55620 Gray Non -fibrous Bound Lab Notes: No mastic present 008B Shoe Molding Heterogeneous 100% Vinyl None Detected B55621A Gray Non -fibrous Bound B55621 B Mastic Heterogeneous 100% Mastic None Detected Yellow Non -fibrous Bound 009A Shoe Molding Heterogeneous 100% Vinyl None Detected B55622A Black Non -fibrous Bound Page 4 of 9 rc AMENDED ASBESTOS BULK ANALYSIS (:EI By: POLARIZING LIGHT MICROSCOPY L/�C35 Client: Hart & Hickman, P. C. CEI Lab Code: B15-4230 2923 S. Tryon Street, Suite 100 Date Received: 07-07-15 Charlotte, NC 28203 Date Analyzed: 07-08-15 Date Reported: 07-09-15 Project: 1005,1015,1201 S. Eugene St. Greensboro, NC; PTR-001 ASBESTOS BULK PLM, EPA 600 METHOD Client ID Lab Lab NON -ASBESTOS COMPONENTS ASBESTOS Lab ID Description Attributes Fibrous Non -Fibrous B55622B Mastic Heterogeneous 100% Mastic None Detected Brown Non -fibrous Bound 009B Shoe Molding Heterogeneous 100% Vinyl None Detected B55623A Black Non -fibrous Bound B55623B Mastic Heterogeneous 100% Mastic None Detected Brown Non -fibrous Bound 010A Drywall/ Spackle & Heterogeneous 20% Cellulose 75% Gypsum None Detected B55624 Tape White,Tan 5% Calc Carb Fibrous <1 % Paint Bound 010B Drywall/ Spackle & Heterogeneous 20% Cellulose 75% Gypsum None Detected B55625 Tape White,Tan 5% Calc Carb Fibrous <1 % Paint Bound 010C Drywall/ Spackle & Heterogeneous 20% Cellulose 75% Gypsum None Detected B55626 Tape White,Tan 5% Calc Carb Fibrous <1 % Paint Bound 011A Ceiling Tile Heterogeneous 60% Cellulose 5% Binder None Detected B55627 White,Tan 20% Fiberglass 5% Paint Fibrous 10% Perlite Loosely Bound Page 5 of 9 rc AMENDED ASBESTOS BULK ANALYSIS (:EI By: POLARIZING LIGHT MICROSCOPY L/�C35 Client: Hart & Hickman, P. C. CEI Lab Code: B15-4230 2923 S. Tryon Street, Suite 100 Date Received: 07-07-15 Charlotte, NC 28203 Date Analyzed: 07-08-15 Date Reported: 07-09-15 Project: 1005,1015,1201 S. Eugene St. Greensboro, NC; PTR-001 ASBESTOS BULK PLM, EPA 600 METHOD Client ID Lab Lab NON -ASBESTOS COMPONENTS ASBESTOS Lab ID Description Attributes Fibrous Non -Fibrous 011 B Ceiling Tile Heterogeneous 60% Cellulose 5% Binder None Detected B55628 White,Tan 20% Fiberglass 5% Paint Fibrous 10% Perlite Loosely Bound 012A Ceiling Tile Heterogeneous 60% Cellulose 5% Binder None Detected B55629 White,Tan 20% Fiberglass 5% Paint Fibrous 10% Perlite Loosely Bound 012B Ceiling Tile Heterogeneous 60% Cellulose 5% Binder None Detected B55630 White,Tan 20% Fiberglass 5% Paint Fibrous 10% Perlite Loosely Bound 013A Floor Tile Heterogeneous 100% Vinyl None Detected B55631A Brown Non -fibrous Bound B55631 B Mastic Heterogeneous 95% Tar Black Non -fibrous Bound 013B Floor Tile Heterogeneous 100% Vinyl None Detected B55632A Brown Non -fibrous Bound B55632B Sample Not Analyzed per COC 014A Roofing Heterogeneous 10% Fiberglass 70% Tar None Detected B55633 Black 10% Cellulose 10% Gravel Fibrous Bound Page 6 of 9 rc AMENDED ASBESTOS BULK ANALYSIS (:EI By: POLARIZING LIGHT MICROSCOPY L/�C35 Client: Hart & Hickman, P. C. CEI Lab Code: B15-4230 2923 S. Tryon Street, Suite 100 Date Received: 07-07-15 Charlotte, NC 28203 Date Analyzed: 07-08-15 Date Reported: 07-09-15 Project: 1005,1015,1201 S. Eugene St. Greensboro, NC; PTR-001 ASBESTOS BULK PLM, EPA 600 METHOD Client ID Lab Lab NON -ASBESTOS COMPONENTS ASBESTOS Lab ID Description Attributes Fibrous Non -Fibrous 014B Roofing Heterogeneous 10% Fiberglass 70% Tar None Detected B55634 Black 10% Cellulose 10% Gravel Fibrous Bound 014C Roofing Heterogeneous 10% Fiberglass 70% Tar None Detected B55635 Black 10% Cellulose 10% Gravel Fibrous Bound 015A Flashing Heterogeneous 10% Fiberglass 65% Tar None Detected B55636 Black 10% Synthetic Fiber 10% Gravel Fibrous 5% Paint Bound 015B Flashing Heterogeneous 10% Fiberglass 65% Tar None Detected B55637 Black 10% Synthetic Fiber 10% Gravel Fibrous 5% Paint Bound 015C Flashing Heterogeneous 10% Fiberglass 65% Tar None Detected B55638 Black 10% Synthetic Fiber 10% Gravel Fibrous 5% Paint Bound 016A Mastic Heterogeneous 20% Fiberglass 65% Tar None Detected B55639 Black 15% Paint Fibrous Bound 016B Mastic Heterogeneous 20% Fiberglass 65% Tar None Detected B55640 Black 15% Paint Fibrous Bound Page 7 of 9 rc AMENDED ASBESTOS BULK ANALYSIS (:EI By: POLARIZING LIGHT MICROSCOPY L/�C35 Client: Hart & Hickman, P. C. CEI Lab Code: B15-4230 2923 S. Tryon Street, Suite 100 Date Received: 07-07-15 Charlotte, NC 28203 Date Analyzed: 07-08-15 Date Reported: 07-09-15 Project: 1005,1015,1201 S. Eugene St. Greensboro, NC; PTR-001 ASBESTOS BULK PLM, EPA 600 METHOD Client ID Lab Lab NON -ASBESTOS COMPONENTS ASBESTOS Lab ID Description Attributes Fibrous Non -Fibrous 017A Shingle Heterogeneous 60% Fiberglass 30% Tar None Detected B55641 Black 10% Gravel Fibrous Bound 017B Shingle Heterogeneous 60% Fiberglass 30% Tar None Detected B55642 Black 10% Gravel Fibrous Bound 018A Roofing Heterogeneous 80% Cellulose 20% Vinyl None Detected B55643 Black, Brown Fibrous Bound 018B Roofing Heterogeneous 80% Cellulose 20% Vinyl None Detected B55644 Black, Brown Fibrous Bound 019A Roofing Heterogeneous 60% Cellulose 30% Tar B55645 Black, Brown Fibrous Bound 019B Sample Not Analyzed B55646 per COC 020A Roofing Heterogeneous 70% Cellulose 30% Tar None Detected B55647 Black, Brown Fibrous Bound 020B Roofing Heterogeneous 70% Cellulose 30% Tar None Detected B55648 Black, Brown Fibrous Bound Page 8 of 9 r-C CEIL,4k,BS LEGEND: Non-Anth = Non-Asbestiform Anthophyllite Non-Trem = Non-Asbestiform Tremolite Calc Carb = Calcium Carbonate METHOD: EPA 600 / R93 / 116 and EPA 600 / M4-82 / 020 LIMIT OF DETECTION: <1 % by visual estimation REGULATORY LIMIT: >1 % by weight Due to the limitations of the EPA 600 method, nonfriable organically bound materials (NOBs) such as vinyl floor tiles can be difficult to analyze via polarized light microscopy (PLM). EPA recommends that all NOBs analyzed by PLM, and found not to contain asbestos, be further analyzed by Transmission Electron Microscopy (TEM). Please note that PLM analysis of dust and soil samples for asbestos is not covered under NVLAP accreditation. This report relates only to the samples tested or analyzed and may not be reproduced, except in full, without written approval by CEI Labs, Inc. CEI Labs makes no warranty representation regarding the accuracy of client submitted information in preparing and presenting analytical results. Interpretation of the analytical results is the sole responsibility of the client. This report may not be used by the client to claim product endorsement by NVLAP or any other agency of the U.S. Government. ANALYST: Aa APPROVED BY: Megan Fisher Tianbao Bai, Ph.D., CIH Laboratory Director INV(A NVLAP Lab Code 101768.0 Page 9 of 9 RE: Laboratory Report for 1005,1015,1201 S. Eugene St. Greensboro,NC; PTR-001 (B15-4230) From: Gabriel SteilAdd to Contacts Sent: Mon, Jul 13, 2015 at 10:54 am To: CEI Labs, Inc. IMG 1193.JPG (4.9 MB) Hello, I have a question about the (1315-4230) laboratory report. Regarding Sample 019 —the lab report described it as 60%cellulose and 30%vinyl (which would appear to be similar to sample 018 — black rolled rubber roof and brown felt). Sample 019 should be similar to sample 020 (70%cellulose and 30%tar). Both samples, 019 and 020, were gravel, tar (black) and fiber (gray/brown)). I attached a picture of sample 019A to verify that this the correct sample identified in the report. Please feel free to call, Thanks Gabriel Steil, Staff Environmental Scientist Hart & Hickman, PC 12923 South Tryon Street, Suite 100 1 Charlotte, NC 28203 Main 704-586-0007 1 Direct 704-887-4633 1 Mobile 704-737-0751 www.harthickman.com H&H Asbestos Survey Form r. Page off H&H Inspector: Gabriel Steil (NC Lic. #12879) H&H Job #: p -T2- OO N Project Location: IooS IBIS (Zo 7-(o . Inspection Date -- I -r� t S �vc�ene. 5 I f�l 4a3o hart � hickman srAAnTBn ENVlnotirACn7AL soLUnons 2923 S. Tryon St Charlotte, NC 28203 C� Iphhone # 704-586.0007 Fax # 704586-0373 SignatureofSampler. () rcvs'_oro ItJ c- Laboratory Signature of Receipt - /�-7-U q:/Da„ -, v Bulk Sample # t-a Ub2{: f' nun yv_ Suspect ACBM Material Sampled FT Iq' t4;k •.I/arou oP<t^r; 1L,.1 IA15a is o J - (12,IY".)rl%(Jk.+-,e V e.l%ure- ge;l•.f''fgA})�. (gfll(/J f Izriz" 1.61w �/, ,�_ Location of Suspected ACBM ((r.11olno L('• ,'�•, t.'-I `•= Estimated Quantity SF/LF 120 5T TSI/ Surfacing/ M Isc. Fr)abl (Y/N) NESHA ategoAssessment 1 RA AHE Category" �..,'It.� f-'(n,t> l.,d.;.• f � fnnsi° II I I c,C.,l.l :,<l.es lu.i:r (T(ItxQ° nPB./t,ie Iu o, ;l�vr.r I(s+Pna ;..,,:; -'..� ,. F'� (R':''1 ($rnd+` ..//f¢d Wt:ie 5{-rer•}(St MFSi�t 22o S¢ I I I I r\ Wbvr59"MhS, 1l'(Of i'ILL Ic Sa.1 n..S i r5'. ZD SF nJ 4i ti Cop) �1UP ..,f]�i(1�•,A< (O(p.,i T !A/, Pr\e< .i �'O� e110lJ4\, /��� 30 S(- v \/ ✓ U nor+i.V. o¢ r•oialr� ('"o b,-Y>'� I,- n�<l ,r_ - )M+11 1 300 : OI %L �Ic Lt`)DRelc brw T mkS iL ( (4ev) Art &VSL ar" IJ r Nrf/CC• I An- of =A QC CT/\f1 GnPmnir� r•�- - ---------•-• •� =.-=R unmrl-tU MUMUraeNEOUS AREA; 48 hr TURN -AROUND TIME; andFAXSIGNED 60-C fo(704)•586.0373 ACBM = asbestos containing building materials TSI = thermal system insulation SF/LF = square feetllinear feet AHERA = Asbestos Hazard Emergency Response Act AHERA Assessment Category Codes 1) Damaged or significantly damaged TSI ACBM; 2) Damaged liable surfacing ACBM; . 3) Significantly damaged fdable surfacing ACBM; qq 1 /" �. ✓,J / 4)Damaged or significantly damaged friable miscellaneous ACBM; -�v�e Imsol'L'o 11 1.JGf tea • 5) ACBM with potential for damage; 6) ACBM with the potential for significant damage; or 7)Any remaining-fdable ACBM or friable suspected ACBM. l(�I II NESHAP Categories: Category INon-Friable Materials (resilient flooring, asphalt roof products, packings, and gaskets) l Category 11 Non -Friable Materials (non-fdable materials not Included in Category 1) P j (,'t 'f f;f r/! oi'-'-0•n ((��,' I r -' - ' i Friable Materials l �T= F(�( ' e N�-�ia,�IV+q G� �0,� �-r = �, 1 •� (� ; ,1 z, Sin^• P Jm��e�;��s 1 'r H&H Inspector: Gabriel Steil (NC Lic. #12879) H&HJob #: �!'"�-Op\ Project Location: IUUS, (plSl lZo' S. 6vti,1- Inspection Date H&H Asbestos Survey Form "I hart � hickman Page � of_% w - SMART ENVIAOAf.1enA6 SOWnONS 2923 S. Tryon St. Charlotte, NC 28203 P one#704586-0007 Fax#704586-0373 Signature of Sampler: Laboratory Signature 4 Receipt: Bulk Sample # ni-IAS I /1lrh�'>vA11.IA-bld4t Suspect ACBM Material Sampled �nf,tl?;c `N .� 1' ( C (ILC, � 31uc 1-C Location of Suspected ACBM 5.7..-; „it; 7 ` . 7!.._ S vO5 $hZGI Q-nr�i-' 00o" Estimated Quantity SF/LF) Ca0 Ty- �ODUSI' TSI/ Surfacing/ Misc. M Friable (Y/N) lu NESHAP ategoAssessment ( t AHERA Category j 7— J (n Notes: LAB -PLEASE STOP POSITIVE PER SAMPLED HOMOGENEOUS AREA; 48 hr TURN AROUND TIME, • and FAX SIGNED C-O-C to (704)-586-0373 ACBM = asbestos containing building materials TSI = thermal system insulation SFILF = square feetllinear feet AHERA = Asbestos Hazard Emergency Response Act • AHERA Assessment Category Codes 1) Damaged or significantly damaged TSI ACBM; 2) Damaged friable surfacing ACBM; 3) Significantly damaged friable surfacing ACBM; 4) Damaged or significantly damaged friable miscellaneous ACBM; 5) ACBM with potential for damage; 6) ACBM with the potential for significant damage; or 7) Any remaining,friable ACBM or friable suspected ACBM. NESHAP Categories: Category I Non -Friable Materials (resilient flooring, asphalt roof products, packings, and gaskets) Category II Non -Friable Materials (non -friable materials not included in Category 1) Friable Materials DOOR DOOR GARAGE ?TV-- 0ON /ERH� DOOR FIRE ESCAPE PLAN WOOD SHOP I KEY. 0 YOU ARE HERE 171"i's LOADING DOCK I o : VEg4 SHIPPING 2 DOC 00C ............. ........................ WORK I.....s WIRE TOOL ORDER FENCING GENERAL SHOP ROOM CLERKS WIRE 4 FENCING TOILET WOMEN'S 0 LOCKERROOM ELECTRICAL 1�1 11 1 ROOM WAREHOUSE v rx- -EN SHOWER WOWROOM LOCKS MEN MEN'S LOCKER ROOM SUPERWSOR INS woIa, LLOCKERSFACC ILITIES IT rz SUPERVISOR SUPERVISOR MGR. O MEETING ROOM O DEPT. SECRETARY Appendix B Photographs of ACMs hart hickman SMARTER ENVIRONMENTAL SOLUTIONS 0 0 a Photograph 1: Asbestos -containing floor tile (12" x 12", white with gray gashes) and mastic located in the main hallway, northern hallway and in the mens' and womens' restrooms (Sample 001). Photograph 2: Asbestos -containing floor tile (12" x 12", white with red gashes) and mastic located in the main hallway entrance to the electrical room (Sample 004). 111 2923 S. Tryon Street, Suite 100 1005, 1015, 1201 S. EUGENE STREET hart 1 hickman Charlotte, NC 28203 GREENSBORO, NORTH CAROLINA 704.586.0007(p)704.586.0373(f) Photograph 3: Mastic (black) associated with the non -asbestos -containing floor tile (9" x 9", dark brown) located in the warehouse toilet (Sample 013). Photograph 4: Asbestos -containing roofing (dark gray) located on the eastern section of the canopy roof (Sample 019). 111 2923 S. Tryon Street, Suite 100 1005, 1015, 1201 S. EUGENE STREET hart 1 hickman Charlotte, NC 28203 GREENSBORO, NORTH CAROLINA W 704.586.0007(p)704.586.0373(f) Ms. Cindy J. Nolan July 20, 2015 Page 8 Appendix C NC Certified Asbestos License 10 hart hickman S:\AAA-Master Projects\PTRC\Phase II - S Eugene St Sites - Greensboro\Asbestos Inspection\Draft Asbestos Repomdocx SMARTER ENVIRONMENTAL SOLUTIONS �+SAT,! J�f ` M North Carolina Department of Health and Human Services Division of Public Health Pat McCrory Governor May 13, 2015 Gabriel E Steil 5011 S Tryon St Charlotte, NC 28217 Dear Mr. Steil: Aldona Z. Wos, M.D. Ambassador (Ret.) Secretary DHHS Daniel Staley Acting Division Director Based upon the review of your accreditation application, the Health Hazards Control Unit (HHCU) has determined that you have fulfilled the requirements and are eligible for asbestos accreditation as a(n) INSPECTOR. Your assigned North Carolina accreditation number is 12879, which is reflected on your enclosed North Carolina Accreditation card. Please be sure to take this card with you to any asbestos work site where you are employed. The State requires that all persons conducting asbestos abatement or asbestos management activities be accredited and have their identification card on site. Your North Carolina Inspector accreditation will expire on APRIL 30, 2016. It is NOT the policy of the HHCU to issue renewal notices. If you wish to continue working as a(n) Inspector after this expiration date, you must successfully complete the required training and submit a completed application to this office prior to April 30, 2016. If you should continue to perform asbestos management activities as a(n) Inspector without a valid North Carolina accreditation, you will be in violation of State regulations and may be cited for noncompliance. North Carolina Asbestos Accreditation r 04-30-2016 07-25-1982 M 69" 150 INSPECTOR 12879 04-16 Gabriel E Steil 5011 S Tryon St Charlotte, NC 28217 107963 Enclosure Sincerely, Ed Norman Program Manager Health Hazards Control Unit www.ncdhhs.gov • www.publichealth.nc.gov Tel919-707-5950 • Fax 919-870-4808 Location: 5505 Six Forks Road • Raleigh, NC 27609 Mailing Address: 1912 Mail Service Center • Raleigh, NC 27699-1912 An Equal Opportunity / Affirmative Action Employer D M North Carolina Public Health t1le fEAD OUTS Lead Paint Survey Report 1005 Eugene Street Greensboro, NC PTR-001-3A Prepared for: Aaron Oswald Hart & Hickman, PC 2923 S. Tryon Street, Suite 100 Greensboro, NC 28203 July 8, 2015 Prepared by: Get The Lead Out, LLC 2121 Commonwealth Avenue, Suite 202 Charlotte, North Carolina 28205 704-376-3594 CERTIFICATION AND REVIEW PAGE Lead Paint Survey of 1005 Eugene Street in Greensboro, NC I hereby certify that the Surveys described herein were completed under my supervision. Get the Lead Out cannot warrant that the surveyed property does not contain lead in locations other than those surveyed and identified in this report. This Survey is based solely on the spaces accessed and information provided by the owner. Kathryn O. Hubicki Get The Lead Out, LLC NC Risk Assessor 120243 Date: July 8, 2015 DISCLAIMER AND DISCLOSURE STATEMENTS Disclaimer This report summarizes Get The Lead Out's evaluation of the subject property for the presence of lead -based paint. Our findings are based upon our observations at the property and sampling performed at the time of the Survey activities; conditions at the property may change due to deterioration or maintenance, and Get The Lead Out is not responsible for such changes. Additional lead -based paints may exist in other portions of the property, but were undetected due to inaccessibility or due to an imperceptible change in paints. Any conditions discovered which deviate from the data contained in this report should be presented to us for our evaluation. The observations, results and conclusions contained in this report are time dependent and are subject to changing site conditions and revisions to federal, state and local regulations. Ongoing monitoring by the owner is usually necessary. Except for our evaluation of the subject property for the presence of lead -based paint, no other environmental concerns were addressed during this Survey. Reliance or use of the information or conclusions of this report by a third party (i.e. a party other than the one for whom it was prepared) without explicit authorization shall be at the third party's sole risk. Get The Lead Out makes no warranties or representations, express or implied in this report, to any such third parties. Disclosure A copy of the summary must be provided to new lessees (tenants) and purchasers of this property under Federal law (24 CFR part 35 and 40 CFR part 745) before they become obligated under a lease or sales contract. The complete report must also be provided to new purchasers and it must be made available to new tenants. TABLE OF CONTENTS Page DISCLAIMER I DISCLOSURE I 1.0 EXECUTIVE SUMMARY...................................................................................1-1 2.0 PROPERTY DESCRIPTION.............................................................................2-1 3.0 LEAD SURVEY.................................................................................................3-1 4.0 RESULTS..........................................................................................................4-1 5.0 XRF TESTING PROCEDURE...........................................................................5-1 5.1 TEST EQUIPMENT................................................................... 5-2 5.2 EXPLANATION OF SAMPLE NUMBERING...................................5-2 5.3 QUALITY CONTROL..................................................................5-3 6.0 RECOMMENDATIONS.....................................................................................6-1 7.0 APPENDICES....................................................................................7-1 APPENDIX A — ALL XRF TEST RESULTS APPENDIX B — FLOOR PLAN APPENDIX C — PHOTOGRAPHS APPENDIX D — RISK ASSESSOR AND FIRM CREDENTIALS APPENDIX E — GLOSSARY 1.0 EXECUTIVE SUMMARY Get The Lead Out, LLC was retained by Hart & Hickman, PC to perform a lead -based paint Survey at 1005 Eugene Street in Greensboro, North Carolina. Get The Lead Out employee Don Suleski, a licensed lead risk assessor in the state of North Carolina, tested all painted components according to the specifications described in the HUD Lead -Evaluation Chapter 7 (2"d edition) for lead -based paint testing on July 7, 2015. Additionally, all Federal, State and City Regulations governing the Survey of lead based paint for the site of the Survey were followed. The credentials of the risk assessor and his firm are in Appendix D. Wipe and soil samples were not included in the scope of work. Get The Lead Out test results do not indicate the presence of (=/>1.0 mg/cm2) lead -based paint in the building. The lead -based paint results identified apply to all similar surfaces on the property, not just the surfaces that were sampled. Lead -based paint may exist in other portions of the property, but was undetected due to inaccessibility or due to an imperceptible change in paints. Components which were inaccessible, missing or not tested are listed in Section 2.0. All untested components must be assumed to contain lead -based paint. Under 29CFR 1926.62, OSHA requires worker protection from all levels of lead. This report presents the areas tested and the levels of lead found. A copy of this summary must be provided to new lessees (tenants) and purchasers of this property under Federal law (24 CFR part 35 and 40 CFR part 745) before they become obligated under a lease or sales contract. The complete report must also be provided to new purchasers and it must be made available to new tenants. Landlords (lessors) and sellers are also required to distribute an educational pamphlet and include standard warning language in their leases or sales contracts to ensure that tenants have the information they need to protect themselves from lead -based paint hazards. This report should be kept by the risk assessor and should also be kept by the owner and all future owners for the life of the property. 1-1 2.0 PROPERTY DESCRIPTION The building is located at 1005 Eugene Street in Greensboro, North Carolina. According to the tax records, the building was constructed in 1927 with subsequent additions and has approximately 12,456 square feet of space. It is known as Greensboro Housing and Maintenance Division. The building is constructed of concrete block. Entry doors are metal; there are several aluminum roll -up doors around the building. The building has a few factory finished windows. The front left area of the building is divided into several small rooms. Four of these rooms are restrooms. The front left area of the building is one big room with a catwalk and upper deck running along walls A and D with a smaller deck on side B. There are also a bathroom and small office off of this room. The back part of the building consists of three rooms; one large room and two smaller rooms. Most of the floors are concrete; floors in the office areas have floor tiles. Ceilings in the office areas are acoustic tile or sheetrock. 2-1 3.0 LEAD SURVEY This lead -based paint Survey is an interior and exterior investigation to identify suspect lead -based paint on a surface -by -surface basis. A lead -based paint Survey conforming to HUD guidelines was performed. A drawing of the building has been provided in Appendix B. The drawing identifies room locations and wall labels (A, B, C, D wall etc.) that are used to identify XRF locations. Testing was performed by Don Suleski, a North Carolina licensed lead Risk Assessor, using a Niton XLp Model 300 Series Lead Analyzer, serial #7415. The radioactive source was replaced January 2015. His credentials are provided in Appendix D: Risk Assessor Credentials. The XRF analyzer is designed to measure the lead content of surface coatings on a variety of building surfaces, substrates, and components. The measurement is rapid and nondestructive and, according to the manufacturer, is capable of detecting lead concentrations that occur within numerous layers of various surface coatings. All testing was non-destructive. Please refer to the Appendix A: All XRF Test Results for the detailed analytical testing results for each distinct area inspected. 3-1 4.0 RESULTS Get the Lead Out determined that none of the components tested during this survey contain lead in amounts greater than or equal to 1.0 mg/cmZ in paint in the surfaces tested. Some of the remaining XRF test locations exhibited lead -in -paint levels below the level that North Carolina identifies as lead -based paint, namely 1.0 mg/cm2. Such surfaces could create dust -lead or soil -lead hazards if the paint is turned into dust by abrasion, scraping, or sanding. Should these or any lead containing components or surfaces be disturbed in any manner that generates dust, care should be taken to limit its spread. See Appendix B for all elevated XRF Readings. Please refer to the Appendix A - All XRF Test Results for the detailed analytical testing results for each distinct area inspected. 4-1 5.0 XRF TESTING PROCEDURE The Niton XLp Model 300A is a hand-held, portable lead detector, designed to make fast, accurate non-destructive measurements of lead concentration in lead -based paint. The XLp displays lead levels, indicates precision of measurement and stores up to 3000 readings and spectra. The accuracy and precision of the data is a function not only of the instrument, but also of how well the operator is trained. Get The Lead Out, LLC has developed a standardized test procedure to be followed by technicians as they make measurements. Procedure for XLp 300 1. Turn on the XLp. 2. Log -in to begin self -calibration. 3. When the XLp emits a tone, calibration is complete. 4. Place the Niton XLp on calibration standard block of known 1. 0 mg/cm2 lead content and test for accuracy. Repeat three times. 5. Begin the test by entering into the XLp the structure type, location and substrate of the surface to be tested. 6. Place the XLp on the painted surface, push in the shutter release, and firmly press the XLp flat against the surface. 7. The XLp's time tones will decide when the test has reached the desired level of accuracy. For readings of approximately 1. 0 mg/cm2, a 20 source second reading is advisable. For lead-free areas or high lead areas, a reading of 2-4 source seconds is needed. 8. Lift the XLp from the surface to end the test. 9. To take additional readings, simply repeat steps 7 through 10. 10. At the conclusion of the testing at the site, three additional calibration checks are made. Or, alternatively, calibration checks are made every four hours during continuous testing. The first step is to conduct an inventory of the painted components in interior rooms, of the exterior walls and surfaces, and of the other exterior areas such as play areas and garages. An area is chosen at the sample location for paint testing. A diagram is made of the exterior of the building, the floor plan and the individual rooms. Each area is numbered so that sample identification is consistent and the location of each sample taken can be found on the diagram. Perimeter walls are identified as A, B, C and D. Each room equivalent was orientated so that the wall that the "A Wall" corresponds directly with the main entrance wall. Each room equivalent's side identification follows the scheme for the whole housing unit. A site sketch designating rooms by expected use (kitchen, bathroom, etc) and walls by orientation (A through D) is located in Appendix C. 5-1 Before beginning XRF testing, sample readings are taken as described above. If the reading is not within the accuracy of the range of deviation, the instrument is out of control. For example, if the reading of the 1.0 mg/cm' standard is shown to be 0. 9 ± 0. 2 mg/cm2, it is within the range of standard deviation. If the instrument is out of control, it must be sent back to Niton before any further testing can occur. The shipping, handling and transportation manual must be consulted for instructions. To minimize the potential adverse effects of frequent substrate changes on the Niton instrument, every effort is made to test the substrates within each room in order. All painted wood, for example, could be tested first, then plaster, drywall, concrete, brick and metal. The Niton is retested for accuracy each day or after it has been turned off for breaks or lunch. If continuous testing occurs for more than four hours, the instrument is rechecked. After completing the specific project or at the end of the day, all data is downloaded into a computer using the Niton proprietary software. Then a copy is created for additional safety. This test procedure was developed using the HUD 1997 procedure for XRF testing instruments. 5.1 TEST EQUIPMENT The field measurements were taken with a Niton XLp Model 300A. This is a handheld instrument with sophisticated integrated software that allows the specific identification of sample structure type and location. Containing a Cadmium-109 radioactive isotope as a power source, the XLp has been proven during HUD and Air Force studies to give accurate measurements of the presence and amount of lead -based paint. The PCS (Performance Characteristic Statement) is attached in Appendix IV. Both false positive results and false negative results are minimized when using this equipment. Copies of the Georgia License and Operator Certificates are located at the end of this report in Appendix E. 5.2 EXPLANATION OF SAMPLE NUMBERING Referring to the pages of sample data in Appendix A, one can see that the Niton XLp 300 consecutively numbers the samples. The results are presented in ascending numerical order, just as they were taken. One can see from the Time column the sequential nature of these values. The following chart is an explanation of the columns present in the XRF results. 5-2 eading Explanation No. Test number in this file. Room Type of room, i. e. , kitchen, bath, etc. , with an identifying room number Side The side of the room, building or area is assigned a letter (A, B, C or D) for later identification. Component Wall, door, window, etc. Feature Further delineation of the part of the structure tested. Condition Condition of paint, intact, poor, etc. Substrate Type of substrate, plaster, wood, metal, concrete, etc. PbC Concentration of lead -based paint found, measured in mg/cm2 Date & Time Date of test and the time of the test 5.3 QUALITY CONTROL Assurance of accurate and proper field measurements taken with the Niton XLp is accomplished in four ways. a. The accuracy and precision of the calibration of the instrument is verified routinely. A new calibration is performed every time the instrument is turned on. These "checks" must be within specification in order for the instrument to permit measurements to be taken. In addition, the calibration check is run when the testing is complete, or every four hours. b. The actual spectrum of energies detected during an analysis is recorded, evaluated and saved in memory by the instrument. This spectrum is actually the fingerprint or X-ray print of each sample. The spectrum reveals numerous items of detail about the sample. Details about the information in each column of the printout are explained in Section 5. 2. In addition, the graphs of the actual energy spectra are stored in the data field. This information can be further analyzed if necessary for legal means. c. All samples are numbered, recorded, location and structural information is entered and checked against the floor plan drawings. d. An encrypted, sequential list of each and every measurement is recorded and reported. The combination of all four controls provides empirical, defensible proof that measurements were taken according to plan and indications of whether (or not) the instrument was performing properly. 5-3 6.0 RECOMMENDATIONS The presence of lead in paint means that any contractor performing demolition and/or renovations is required to make provisions for worker protection by complying with North Carolina OSHA regulations, 29 CFR 1926.62 Construction Standard for Lead. Regulated work activities that may generate airborne lead levels (and may require air testing) include torch burning, abrasive blasting, welding, sawing, and grinding. If any of these activities need to occur on lead -based painted surfaces during demolition or renovation, methods such as HEPA vacuums, wet -stripping, water spray or others should be considered to reduce the potential for lead -dust or fume emissions to surrounding areas and workers. At the minimum, GTLO recommends that contract construction workers be told of the presence of lead paint, be given access to Appendices A and B of the OSHA lead standard, and that a negative exposure assessment occur according to OSHA regulations 29 CFR 1926.62. Demolition waste that contains lead is recommended to have representative testing using TCLP to determine appropriate disposal options, depending on whether the debris is considered hazardous waste. This report should be kept by the risk assessor and should also be kept by the owner and all future owners for the life of the property. 6-1 7.0 APPENDICES 7-1 APPENDIX A - ALL XRF TEST RESULTS 1005 S. Eugene Street, Greensboro, NC.xlsx All XRF Readings Reading No Rooms Side Component Feature Condition Substrate Color PbC Results 1 7/7/2015 9:05 5.26 2 7/7/2015 9:13 Calibration 1.00 Positive 3 7/7/2015 9:13 Calibration 1.00 Positive 4 7/7/2015 9:14 1 Calibration 1 1.00 Positive 5 7/7/2015 9:15 Calibration 1.00 Positive 6 7/7/2015 9:16 1 Room 1 A Ceiling Ceiling Intact Ceiling Tile White 0.00 Negative 7 7/7/2015 9:16 Room 1 A Wall, Int. Wall Intact Drywall White 0.00 Negative 8 7/7/2015 9:17 Room 1 B Wall, Int. Wall Intact Drywall White 0.00 Negative 9 7/7/2015 9:17 Room 1 C Wall, Int. Wall Intact Drywall White 0.00 Negative 10 7/7/2015 9:17 Room 1 D Wall, Int. Wall Intact Drywall White 0.00 Negative 11 7/7/2015 9:17 Room 1 D Door, Int.1 Door Intact Metal Grey 0.00 Negative 12 7/7/2015 9:17 Room 1 D Door, Int.1 Casing Intact Metal Grey 0.00 Negative 13 7/7/2015 9:18 Room 1 D Door, Int.2 Casing Deteriorated Metal Grey 0.00 Negative 14 1 7/7/2015 9:18 Room 1 D Door, Int.2 Door Deteriorated Metal Grey 0.00 Negative 15 7/7/2015 9:18 Bath 2 D Door, Int. Door Deteriorated Metal Grey 0.00 Negative 16 7/7/2015 9:19 Bath 2 D Door, Int. Casing Deteriorated Metal Grey 0.01 Negative 17 7/7/2015 9:19 Bath 2 D Ceiling Ceiling Deteriorated Drywall White 0.00 Negative 18 7/7/2015 9:19 Hall 3 D Wall, Int. Wall Deteriorated Drywall White 0.00 Negative 19 7/7/2015 9:19 Hall 3 B Wall, Int. Wall Deteriorated Drywall White 0.00 Negative 20 7/7/2015 9:20 Hall 3 B Door, Int. Door Deteriorated Metal Grey 0.00 Negative 21 7/7/2015 9:20 Hall 3 B Door, Int. Casing Deteriorated Metal Grey 0.00 Negative 22 7/7/2015 9:20 Room 4 A Door, Int. Casing Deteriorated Metal Grey 0.00 Negative 23 7/7/2015 9:21 Room 4 A Door, Int. Door Intact Wood Grey 0.00 Negative 24 7/7/2015 9:21 Room 4 A Door, Int. Door Intact Wood Grey 0.00 Negative 25 7/7/2015 9:21 Room 4 C Door, Int.1 Door Deteriorated Metal Grey 0.00 Negative 26 7/7/2015 9:21 Room 4 C Door, Int.1 Casing Deteriorated Metal Grey 0.01 Negative 27 7/7/2015 9:22 Room 4 C Door, Int.2 Casing Deteriorated Metal Grey 0.01 Negative 28 7/7/2015 9:22 1 Room 4 C Door, Int.2 Door Deteriorated Metal Grey 0.00 Negative 29 7/7/2015 9:22 Room 4 C Door, Roll -Up Door Intact Metal Grey 0.00 Negative 30 7/7/2015 9:22 Room 4 C Door, Roll -Up Casing Intact Metal Black 0.00 Negative 31 7/7/2015 9:23 Room 4 C Door, Int.3 Casing Intact Metal Brown 0.00 Negative 32 7/7/2015 9:23 Room 4 C Door, Int.3 Door Deteriorated Metal Brown 0.00 Negative 33 7/7/2015 9:24 Room 4 A Ceiling Ceiling ladder Intact Metal Brown 0.01 Negative 34 7/7/2015 9:24 Room 4 A Wall, Int. Wall Intact Concrete White 0.00 Negative 35 7/7/2015 9:25 Room 4 B Wall, Int. Wall Intact Concrete White 0.00 Negative 36 7/7/2015 9:25 Room 4 C Wall, Int. Wall Intact Block White 0.00 Negative 37 7/7/2015 9:26 Room 4 D Wall, Int. Wall Intact Block White 0.00 Negative 38 7/7/2015 9:27 Room 4 D Ceiling Ceiling Intact Concrete White 0.00 Negative 39 7/7/2015 9:27 Room 4 D Ceiling Ceilingbeam Intact Metal White 0.04 Negative 40 7/7/2015 9:27 Room 5 D Ceiling Ceilingbeam Intact Metal White 0.08 Negative 41 7/7/2015 9:28 Room 5 D Ceiling Ceiling Intact Concrete White 0.00 Negative 42 7/7/2015 9:29 Room 5 D Wall, Int. Wall, Upper Intact Block Grey 0.00 Negative 43 7/7/2015 9:29 Room 5 A Wall, Int. Wall, Upper Intact Block Grey 0.01 Negative 44 7/7/2015 9:29 Room 5 A Wall, Int. Wall, Lower Intact Block Blue 0.03 Negative 45 7/7/2015 9:30 Room 5 A Wall, Int. Wall, Lower Intact Block Yellow 0.00 Negative 46 7/7/2015 9:30 Room 5 B Door, Int. Door Deteriorated Metal Grey 0.00 Negative 47 7/7/2015 9:30 Room 5 B Door, Int. Casing Intact Metal Grey 0.00 Negative 48 7/7/2015 9:30 Room 5 C Door, Roll -Up Casing Intact Metal Grey 0.00 Negative 49 7/7/20159:31 Room 5 C Door, Roll -Up Door Intact Metal White 0.00 Negative 50 7/7/2015 9:32 1 Room 6 C Door, Roll -Up Door Intact Metal White 0.00 Negative 51 7/7/2015 9:32 Room 6 C Door, Roll -Up Casing Intact Metal Grey 0.01 Negative 52 7/7/2015 9:32 Room 6 C Door, Int. Casing Deteriorated Metal Grey 0.00 Negative 53 7/7/2015 9:32 Room 6 C Door, Int. Door Deteriorated Metal Brown 0.00 Negative 54 7/7/2015 9:33 Room 6 C Wall, Int. Wall, Upper Intact Concrete Grey 0.00 Negative 55 7/7/2015 9:33 Room 6 C Wall, Int. Wall, Lower Intact Concrete Brown 0.00 Negative 56 7/7/2015 9:34 Room 6 D Wall, Int. Wall, Lower Intact Concrete Brown 0.00 Negative 57 7/7/2015 9:34 Room 6 A Wall, Int. Wall, Lower Intact Block Brown 0.01 Negative 58 7/7/2015 9:34 Room 6 A Wall, Int. Wall, Lower Intact Block Yellow 0.00 Negative 59 7/7/2015 9:35 Room 6 A Wall, Int. Wall, Upper Intact Block Grey 0.00 Negative 60 1 7/7/2015 9:35 Room 6 A Ceiling Ceiling Intact Concrete Off White 0.00 Negative 61 7/7/2015 9:36 Room 6 A Ceiling Ceiling beam Intact Metal Off White 0.00 Negative 62 7/7/2015 9:36 Room 6 A Floor Floor Deteriorated Concrete Grey 0.00 Negative 1005 S. Eugene Street, Greensboro, NC.xlsx All XRF Readings Reading No Rooms j Side Component Feature Condition Substrate Color PbC Results j 63 7/7/2015 9:37 Bath 7 A Ceiling Ceiling Intact Drywall White 0.00 Negative 64 7/7/2015 9:38 Bath 7 B Door, Int. Door Intact Wood White 0.00 Negative 65 7/7/2015 9:38 Bath 7 B Door, Int. Casing Intact Wood White 0.00 Negative 66 7/7/2015 9:38 Bath 7 A I Door, Int. Casing Intact Metal Brown 1 0.01 Negative 67 7/7/2015 9:38 Bath 7 A Door, Int. Door Intact Metal Brown 0.00 Negative 68 7/7/2015 9:40 Hall 8 A Door, Int.1 Door Intact Metal Grey 0.00 Negative 69 7/7/2015 9:40 Hall 8 A Door, Int.1 Casing Intact Metal Grey 0.01 Negative 70 7/7/2015 9:40 Hall 8 A Door, Int.2 Casing Intact Metal Grey 0.01 Negative 71 7/7/2015 9:40 Hall 8 A Door, Int.2 Door Intact Wood Grey 0.00 Negative 72 7/7/2015 9:41 Hall 8 A Door, Int.3 Door Intact Wood Grey 0.00 Negative 73 7/7/2015 9:41 Hall 8 A Door, Int.3 Casing Intact Wood Grey 0.00 Negative 74 7/7/2015 9:41 Hall 8 A Door, Int.4 Casing Intact Wood Grey 0.00 Negative 75 7/7/2015 9:41 Hall 8 A Door, Int.4 Door Intact Wood Grey 0.00 Negative 76 7/7/2015 9:42 Hall 8 B Door, Int.1 Door Deteriorated Metal Grey 0.00 Negative 77 7/7/2015 9:42 Hall 8 B Door, Int.1 Casing Deteriorated Metal Grey 0.03 Negative 78 7/7/2015 9:42 Hall 8 B Door, Int.2 Casing Deteriorated Metal Grey 0.00 Negative 79 7/7/2015 9:42 Hall 8 B Door, Int.2 Door Deteriorated Metal Grey 0.00 Negative 80 7/7/2015 9:42 Hall 8 B Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 81 7/7/2015 9:42 Hall 8 C Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 82 7/7/2015 9:43 Hall 8 D Wall, Int. Wall Intact Block Yellow 0.00 Negative 83 7/7/2015 9:43 Hall 8 A Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 84 7/7/2015 9:44 Room 9 A Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 85 7/7/2015 9:45 Room 9 B Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 86 7/7/2015 9:46 Room 9 B Door, Int. Door Intact Wood Brown 0.00 Negative 87 7/7/2015 9:46 Room 9 B Door, Int. Casing Intact Metal Brown 0.00 Negative 88 7/7/2015 9:46 Room 10 B Door, Int. Casing Intact Metal Brown 0.00 Negative 89 7/7/2015 9:46 Room 10 B Door, Int. Door Deteriorated Wood Brown 0.00 Negative 90 7/7/2015 9:47 Room 10 B Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 91 7/7/2015 9:47 Room 10 C Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 92 7/7/2015 9:47 Room 10 D Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 93 7/7/2015 9:47 Room 10 A Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 94 7/7/2015 9:48 Room 11 A Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 95 7/7/2015 9:48 Room 11 B Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 96 7/7/2015 9:48 Room 11 C Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 97 7/7/2015 9:49 Room 11 C Door, Int. Door Intact Wood Brown 0.00 Negative 98 7/7/2015 9:49 Room 11 C Door, Int. Casing Intact Wood Brown 0.00 Negative 99 7/7/2015 9:50 Room 13 D Door, Int. Casing Intact Wood Brown 0.00 Negative 100 7/7/2015 9:50 Room 13 D Door, Int. Door Intact Wood Brown 0.00 Negative 101 7/7/2015 9:51 Room 13 D Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 102 7/7/2015 9:51 Room 13 A Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 103 7/7/2015 9:51 Room 13 B Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 104 7/7/2015 9:51 Room 13 C Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 105 7/7/2015 9:51 Room 14 C Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 106 7/7/2015 9:52 Room 14 D Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 107 7/7/2015 9:52 Room 14 D Door, Int. Door Intact Wood Brown 0.00 Negative 108 7/7/2015 9:52 Room 14 D Door, Int. Casing Intact Metal Brown 0.00 Negative 109 7/7/2015 9:53 Hall 15 B Door, Int.1 Casing Intact Metal Brown 0.00 Negative 110 7/7/2015 9:53 Hall 15 B Door, Int.1 Door Deteriorated Metal Brown 0.00 Negative ill 7/7/2015 9:54 Hall 15 B Door, Int.2 Door Intact Wood Brown 0.00 Negative 112 7/7/2015 9:54 Hall 15 B Door, Int.2 Casing Intact Metal Brown 0.00 Negative 113 7/7/2015 9:54 Hall 15 B Door, Int.3 Casing Intact Metal Brown 0.00 Negative 114 7/7/2015 9:54 Hall 15 B Door, Int.3 Door Intact Wood Brown 0.00 Negative 115 7/7/2015 9:54 Hall 15 C Door, Int. Door Intact Wood Brown 0.00 Negative 116 7/7/2015 9:55 Hall 15 C Door, Int. Casing Intact Metal Brown 0.00 Negative 117 7/7/2015 9:55 Hall 15 C Wall, Int. Wall Intact Drywall Wallpaper 0.01 Negative 118 7/7/2015 9:55 Hall 15 D Wall, Int. Wall Intact Drywall Wallpaper 0.00 Negative 119 7/7/2015 9:56 Hall 15 A Wall, Int. Wall Intact Drywall Wallpaper 0.00 Negative 120 7/7/2015 9:56 Hall 15 B Wall, Int. Wall Intact Drywall Wallpaper 0.00 Negative 121 7/7/2015 9:56 Hall 15 B Cabinet Door Intact Wood I Varnish 0.00 Negative 122 7/7/2015 9:56 Hall 15 B Cabinet Casing Intact Wood Varnish 0.00 Negative 123 7/7/2015 9:56 Hall 15 B Win., Int. Casing Intact Wood Brown 0.00 Negative 124 7/7/2015 9:57 Hall 15 B Win., Int. Stool Intact Wood Brown 0.00 Negative 1005 S. Eugene Street, Greensboro, NC.xlsx All XRF Readings Reading No Rooms Side Component Feature Condition Substrate Color PbC Results 125 7/7/2015 9:57 Hall 15 B Door, Int. Casing Deteriorated Metal Brown 0.00 Negative 126 7/7/2015 9:57 Hall 15 B Door, Int. Door Deteriorated Metal Brown 0.00 Negative 127 7/7/2015 9:58 Room 16 B Door, Int. Door Intact Wood Brown 0.00 Negative 128 7/7/2015 9:58 Room 16 B Door, Int. Casing Intact Metal I Brown 0.00 1 Negative 129 7/7/2015 9:59 Room 16 B Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 130 7/7/2015 9:59 1 Room 16 C Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 131 7/7/2015 9:59 Room 16 D Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 132 7/7/2015 9:59 Room 17 D Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 133 7/7/2015 9:59 Room 17 A Wall, Int. Wall Intact Drywall Yellow 0.03 Negative 134 7/7/2015 10:00 Room 17 B Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 135 7/7/2015 10:00 Room 17 B Door, Int. Door Intact Wood Brown 0.00 Negative 136 7/7/2015 10:00 1 Room 17 B Door, Int. Casing Intact Metal Brown 0.01 Negative 137 7/7/2015 10:02 Bath 18 B Door, Int. Casing Intact Metal Brown 0.00 Negative 138 7/7/2015 10:02 Bath 18 B Door, Int. Door Intact Wood Brown 0.00 Negative 139 7/7/2015 10:02 Bath 18 B Wall, Int. Wall Intact Drywall White 0.00 Negative 140 7/7/201510:03 Bath 18 C Wall, Int. Wall Intact Drywall White 0.00 Negative 141 7/7/201510:03 Bath 18 D Wall, Int. Wall Intact Drywall White 0.00 Negative 142 7/7/2015 10:03 Bath 18 A Wall, Int. Wall Intact Drywall White 0.00 Negative 143 7/7/2015 10:04 Bath 19 C Wall, Int. Wall Intact Drywall White 0.00 Negative 144 7/7/2015 10:04 Bath 19 D Wall, Int. Wall Intact Drywall White 0.01 Negative 145 7/7/2015 10:04 Bath 19 A Wall, Int. Wall Intact Drywall White 0.01 Negative 146 7/7/2015 10:04 Bath 19 B Wall, Int. Wall Intact Drywall White 0.00 Negative 147 7/7/2015 10:04 Bath 19 B Door, Int. Door Intact Wood Brown 0.00 Negative 148 7/7/2015 10:05 Bath 19 B Door, Int. Casing Intact Metal Brown 0.02 Negative 149 7/7/2015 10:07 Room elec 20 C Door, Int. Casing Intact Metal Brown 0.00 Negative 150 7/7/2015 10:07 Room elec 20 C Door, Int. Casing Intact Metal Brown 0.00 Negative 151 7/7/2015 10:07 Room elec 20 C Door, Int. Door Intact Wood Brown 0.01 Negative 152 7/7/2015 10:07 Room elec 20 C Door, Int. Door Intact Wood Brown 0.00 Negative 153 1 7/7/2015 10:11 Room upper 21 C Ceiling Ceiling Intact Concrete White 0.60 Negative 154 7/7/2015 10:11 Room upper 21 C Ceiling Ceiling beam Intact Metal White 0.03 Negative 155 7/7/2015 10:11 Room upper2l C Ceiling Ceiling truss Intact Metal White 0.02 Negative 156 7/7/2015 10:12 Room upper 21 B Wall, Int. Wall, Upper Intact Concrete White 0.00 Negative 157 7/7/2015 10:13 Room upper 21 C Wall, Int. Wall, Upper Intact Concrete White 0.00 Negative 158 7/7/2015 10:13 1 Room upper 21 C Wall, Int. Wall, Lower Intact Concrete White 0.00 Negative 159 7/7/2015 10:13 Room upper 21 B Wall, Int. Wall, Lower Intact Block White 0.00 Negative 160 7/7/2015 10:14 Room upper 21 C Wall, Int. Wallbeam Intact Metal White 0.06 Negative 161 7/7/2015 10:14 Room upper 21 D Wall, Int. Wall Intact Wood White 0.00 Negative 162 7/7/2015 10:14 Room upper 21 A Wall, Int. Wall Intact Wood White 0.00 Negative 163 7/7/2015 10:15 Room upper 21 A Wall, Int. Hand Rail Intact Wood Varnish 0.00 Negative 164 7/7/2015 10:15 Room upper 21 A Stairs Hand Rail Intact Wood Varnish 0.00 Negative 165 7/7/2015 10:15 Room upper 21 A Stairs Baluster Intact Wood Varnish 0.00 Negative 166 7/7/2015 10:15 Room upper 21 A Stairs Tread Deteriorated Wood Varnish 0.00 Negative 167 7/7/2015 10:15 Room upper 21 A Stairs Riser Deteriorated Wood Varnish 0.00 Negative 168 7/7/2015 10:16 Room upper 21 A Ceiling Ceiling pipe Intact Metal White 0.01 Negative 169 7/7/2015 10:17 Room 22 A Ceiling Ceiling Intact Drywall White 0.00 Negative 170 7/7/2015 10:17 Room 22 A Wall, Int. Wall Deteriorated Drywall Yellow 0.00 Negative 171 7/7/2015 10:17 Room 22 B Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 172 7/7/2015 10:18 Room 22 C Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 173 7/7/2015 10:18 Room 22 D Wall, Int. Wall Deteriorated Drywall Yellow 0.00 Negative 174 7/7/2015 10:18 Room 22 D Wall, Int. Baseboard Deteriorated Wood White 0.00 Negative 175 7/7/2015 10:18 Room 22 D Win., Int. Stool Intact Wood Varnish 0.00 Negative 176 7/7/2015 10:18 Room 22 D Win., Int. Casing Intact Wood Varnish 0.00 Negative 177 7/7/2015 10:19 Room 22 D Door, Int. Casing Intact Wood Brown 0.00 Negative 178 7/7/2015 10:19 1 Room 22 D Door, Int. Door Intact Wood Brown 0.00 Negative 179 7/7/2015 10:19 Room 22 B Door, Int. Door Deteriorated Wood Brown 0.00 Negative 180 7/7/2015 10:19 Room 22 B Door, Int. Casing Deteriorated Metal Brown 0.00 Negative 181 7/7/2015 10:19 Room 22 C Door, Int. Casing Deteriorated Metal Brown 0.09 Negative 182 7/7/2015 10:20 Room 22 C Door, Int. Door Deteriorated Wood Brown 0.00 Negative 183 7/7/2015 10:20 Room 23 C Door, Int. Door Deteriorated Wood Brown 0.00 Negative 184 7/7/2015 10:20 Room 23 C Door, Int. Casing Deteriorated Metal Brown 0.00 Negative 185 7/7/201510:21 Room 23 B Win., Int. Casing Intact Wood Yellow 0.00 Negative 186 7/7/201510:21 Room 23 B I Win., Int. Sash Intact Wood Yellow 0.00 Negative 1005 S. Eugene Street, Greensboro, NC.xlsx All XRF Readings Reading No Rooms Side Component Feature Condition Substrate Color PbC Results 187 7/7/2015 10:21 Room 23 B Wall, Int. Shelf Intact Wood Yellow 0.00 Negative 188 7/7/2015 10:21 Room 23 B Wall, Int. Baseboard Deteriorated Wood Brown 0.00 Negative 189 7/7/2015 10:22 Room 23 B Wall, Int. Wall Deteriorated Drywall Yellow 0.00 Negative 190 1 7/7/2015 10:22 Room 23 C Wall, Int. Wall Deteriorated I Drywall Yellow 0.00 1 Negative 191 7/7/2015 10:22 Room 23 D Wall, Int. Wall Deteriorated Drywall Yellow 0.00 Negative 192 7/7/2015 10:22 1 Room 23 A Wall, Int. Wall Deteriorated Drywall Yellow 0.00 Negative 193 7/7/2015 10:22 Room 23 A Ceiling Ceiling Intact Drywall White 0.00 Negative 194 7/7/2015 10:23 Room 24 A Ceiling Ceiling Intact Drywall White 0.00 Negative 195 7/7/2015 10:23 Room 24 A Wall, Int. Wall Intact Wood Varnish 0.00 Negative 196 7/7/2015 10:23 Room 24 B Wall, Int. Wall Intact Wood Varnish 0.00 Negative 197 7/7/2015 10:23 Room 24 C Wall, Int. Wall Intact Wood Varnish 0.00 Negative 198 7/7/2015 10:23 Room 24 D Wall, Int. Wall Intact Wood Varnish 0.00 Negative 199 7/7/2015 10:24 Room 24 D Wall, Int. Crn Molding Intact Wood Varnish 0.00 Negative 200 7/7/2015 10:24 Room 24 D Wall, Int. Baseboard Deteriorated Wood Varnish 0.00 Negative 201 7/7/2015 10:24 Room 24 D Door, Int. Door Deteriorated Wood Varnish 0.00 Negative 202 7/7/2015 10:24 Room 24 D Door, Int. Casing Deteriorated Wood Varnish 0.00 Negative 203 7/7/2015 10:24 Room 24 A Door, Int. Casing Deteriorated Metal Grey 0.01 Negative 204 7/7/2015 10:25 Room 24 A Door, Int. Door Deteriorated Wood Grey 0.00 Negative 205 7/7/2015 10:25 Room 25 A Door, Int. Door Intact Wood Grey 0.00 Negative 206 7/7/2015 10:25 Room 25 A Door, Int. Casing Intact Metal Grey 0.00 Negative 207 7/7/2015 10:25 Room 25 B Door, Int. Casing Intact Wood Grey 0.00 Negative 208 7/7/2015 10:26 Room 25 B Door, Int. Door Intact Wood Varnish 0.00 Negative 209 7/7/2015 10:26 Room 25 D Win., Int. Stool Intact Wood Varnish 0.00 Negative 210 7/7/2015 10:26 1 Room 25 D Win., Int. Casing Intact Wood Varnish 0.00 Negative 211 7/7/2015 10:26 Room 25 D Wall, Int. Baseboard Deteriorated Wood Varnish 0.00 Negative 212 7/7/2015 10:27 Room 25 D Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 213 7/7/2015 10:27 Room 25 A Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 214 7/7/2015 10:27 Room 25 B Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 215 7/7/2015 10:27 Room 25 C Wall, Int. Wall Intact Drywall Yellow 0.00 Negative 216 7/7/2015 10:28 Room 26 C Door, Int. Door Intact Wood Grey 0.00 Negative 217 7/7/2015 10:28 Room 26 C Door, Int. Casing Intact Metal Grey 0.00 Negative 218 7/7/201510:29 Room 26 C Door, Int.2 Casing Deteriorated Metal Grey 0.02 Negative 219 7/7/201510:29 Room 26 C Door, Int.2 Door Deteriorated Metal Grey 0.00 Negative 220 7/7/201510:30 Room 26 B Win., Int. Stool Deteriorated Wood Varnish 0.00 Negative 221 7/7/201510:30 Room 26 B Win., Int. Casing Deteriorated Wood Varnish 0.00 Negative 222 7/7/201510:30 Room 26 B Win., Int. Casing Deteriorated Wood Varnish 0.00 Negative 223 7/7/201510:31 Room 26 C Door, Roll -Up Door Deteriorated Metal White 0.00 Negative 224 7/7/2015 10:31 Room 26 C Wall, Int. Wall Intact Block White 0.00 Negative 225 7/7/2015 10:32 Room 26 C Wall, Int. Wall Intact Concrete White 0.00 Negative 226 7/7/2015 10:33 Room 26 D Wall, Int. Wall Intact Concrete White 0.00 Negative 227 7/7/2015 10:33 Room 26 A Wall, Int. Wall Intact Concrete White 0.00 Negative 228 7/7/2015 10:33 Room 26 B Wall, Int. Wall Intact Block White 0.00 Negative 229 7/7/2015 10:34 Room 26 B Ceiling Column 1 Deteriorated Metal White 0.03 Negative 230 7/7/2015 10:35 1 Room 26 B Ceiling Column 2 Deteriorated Metal White 0.14 Negative 231 7/7/2015 10:35 Room 26 B Ceiling Column 3 Deteriorated Metal White 0.05 Negative 232 7/7/2015 10:36 Room 26 B Ceiling Column 4 Deteriorated Metal White 0.03 Negative 233 7/7/201510:36 Room 26 B Ceiling Ceilingpipe Deteriorated Metal White 0.00 Negative 234 7/7/201510:37 Room 26 B Ceiling Ceilingbeam Intact Metal White 0.07 Negative 235 7/7/201510:37 Room 26 B Ceiling Ceilingbeam Intact Metal White 0.03 Negative 236 7/7/201510:38 Room 26 B Ceiling Ceiling truss Intact Metal White 0.05 Negative 237 7/7/201510:38 Room 26 B Ceiling Ceiling Intact Concrete White 0.00 Negative 238 7/7/201510:40 Room 26 B Door, Int.1 Door Deteriorated Wood Grey 0.00 Negative 239 7/7/2015 10:40 Room 26 B Door, Int.1 Casing Deteriorated Wood Grey 0.00 Negative 240 7/7/201510:40 Room 26 B Win., Int. Casing Deteriorated Wood Varnish 0.00 Negative 241 7/7/201510:40 Room 26 B Win., Int. Stool Deteriorated Wood Varnish 0.00 Negative 242 7/7/2015 10:41 Room 26 B Door, Int.2 Door Deteriorated Wood Grey 0.00 Negative 243 7/7/2015 10:41 Room 26 B Door, Int.2 Casing Deteriorated Metal Grey 0.00 Negative 244 7/7/2015 10:41 Bath 27 D Door, Int.2 Casing Deteriorated Metal Grey 0.00 Negative 245 7/7/2015 10:42 Bath 27 D Door, Int.2 Door Deteriorated Wood Grey 0.00 Negative 246 7/7/2015 10:42 Bath 27 D Wall, Int. Wall Intact Block White 0.00 Negative 247 7/7/2015 10:42 Bath 27 A Wall, Int. Wall Intact Block White 0.00 Negative 248 7/7/2015 10:43 Bath 27 B Wall, Int. Wall Intact Block White 0.00 Negative 1005 S. Eugene Street, Greensboro, NC.xlsx All XRF Readings Reading No Time Rooms Side Component Feature Condition Substrate Color PbC Results 249 7/7/2015 10:43 Bath 27 C Wall, Int. Wall Intact Block White 0.00 Negative 250 7/7/201510:43 Bath 27 C Ceiling Ceiling Intact Drywall White 0.00 Negative 251 7/7/2015 10:44 Room 26 A upper deck Floor Deteriorated Wood Grey 0.00 Negative 252 1 7/7/2015 10:45 Room 26 A upper deck Hand Rail Intact Metal I Grey 0.00 1 Negative 253 7/7/2015 10:45 Room 26 A upper deck Column Intact Metal Grey 0.00 Negative 254 7/7/2015 10:45 1 Room 26 A upper deck Tread Deteriorated Wood Grey 0.00 Negative 255 7/7/2015 10:45 Room 26 A upper deck Stringer Deteriorated Wood Grey 0.00 Negative 256 7/7/2015 10:45 Room 26 A upper deck Hand Rail Deteriorated Wood Grey 0.00 Negative 257 7/7/2015 10:46 Room 26 D Door, Int. Door Deteriorated Metal Brown 0.00 Negative 258 7/7/2015 10:46 Room 26 D Door, Int. Door Deteriorated Metal Brown 0.00 Negative 259 7/7/2015 10:46 Room 26 D Door, Int. Casing Deteriorated Metal Brown 0.01 Negative 260 7/7/2015 10:47 Room 26 D Door, Int. Casing Deteriorated Metal Brown 0.00 Negative 261 7/7/2015 10:47 Room 26 D Door, Int. Casing Deteriorated Metal Brown 0.00 Negative 262 7/7/201510:49 Room 26 D deck Floor Deteriorated Wood White 0.00 Negative 263 7/7/201510:49 Room 26 B deck Wall Intact Wood White 0.00 Negative 264 7/7/201510:49 Room 26 B deck Wall Intact Wood White 0.00 Negative 265 7/7/201510:49 Room 26 B deck Column Deteriorated Wood Brown 0.00 Negative 266 7/7/201510:50 Room 26 B deck Column Deteriorated Metal Grey 0.00 Negative 267 7/7/2015 10:52 Exterior A Siding, Ext. Wall Intact Concrete White 0.00 Negative 268 7/7/2015 10:53 Exterior A Siding, Ext. Soffit Intact Stucco White 0.00 Negative 269 7/7/2015 10:54 Exterior B Door, Ext.1 Door Intact Metal Grey 0.01 Negative 270 7/7/2015 10:54 Exterior B Door, Ext.1 Casing Intact Metal Grey 0.00 Negative 271 7/7/2015 10:54 Exterior D Door, Ext.2 Casing Deteriorated Metal Grey 0.04 Negative 272 7/7/2015 10:55 Exterior D Door, Ext.2 Door Deteriorated Metal Grey 0.01 Negative 273 7/7/2015 10:57 Exterior B Siding, Ext. Wall Intact Concrete White 0.00 Negative 274 7/7/2015 10:57 Exterior B Siding, Ext. Soffit Intact Stucco White 0.00 Negative 275 7/7/2015 10:57 Exterior B Door, Ext.2 Door Deteriorated Metal Grey 0.00 Negative 276 7/7/2015 10:58 Exterior B Door, Ext.2 Casing Deteriorated Metal Grey 0.00 Negative 277 7/7/2015 11:00 Exterior B Door, Ext.3 Casing Intact Metal Grey 0.00 Negative 278 7/7/2015 11:00 Exterior B Door, Ext.3 Door Deteriorated Metal Grey 0.03 Negative 279 7/7/2015 11:00 Exterior B Siding, Ext. Fascia Intact Concrete White 0.01 Negative 280 7/7/2015 11:01 Exterior C Siding, Ext. Fascia Intact Concrete White 0.00 Negative 281 7/7/2015 11:06 Exterior C Siding, Ext. Fascia Deteriorated Wood White 0.02 Null 282 7/7/2015 11:06 Exterior C Siding, Ext. Fascia Deteriorated Wood White 0.00 Negative 283 7/7/2015 11:06 Exterior C Siding, Ext. Wall Deteriorated Concrete White 0.00 Negative 284 7/7/2015 11:07 Exterior C Door, Roll-Up1 Door Intact Metal White 0.00 Negative 285 7/7/2015 11:08 Exterior C Door, Roll-Up1 Jamb Deteriorated Metal Grey 0.07 Negative 286 7/7/2015 11:08 Exterior C Door, Ext.1 Jamb Deteriorated Metal Brown 0.01 Negative 287 7/7/2015 11:08 Exterior C Door, Ext.1 Casing Deteriorated Metal Brown 0.01 Negative 288 7/7/2015 11:09 Exterior C Door, Ext.1 Door Deteriorated Metal Brown 0.06 Negative 289 7/7/2015 11:09 Exterior C Siding, Ext. Hand Rail Deteriorated Metal Brown 0.00 Negative 290 7/7/2015 11:10 Exterior C Door, Roll-Up4 Door Intact Metal Grey 0.00 Negative 291 7/7/2015 11:11 Exterior C Door, Ext.2 Door Deteriorated Metal Grey 0.00 Negative 292 7/7/2015 11:11 Exterior C Door, Ext.2 Door Deteriorated Metal Grey 0.00 Negative 293 7/7/2015 11:11 Exterior C Door, Ext.2 Casing Deteriorated Metal Grey 0.00 Negative 294 7/7/2015 11:12 Exterior C Door, Ext.3 Casing Deteriorated Metal Grey 0.00 Negative 295 7/7/2015 11:12 Exterior C Door, Ext.3 Door Deteriorated Metal Grey 0.00 Negative 296 7/7/2015 11:13 Exterior C Door, Ext.3 Door Deteriorated Metal Grey 0.00 Negative 297 7/7/2015 11:13 Exterior C Door, Ext.4 Door Deteriorated Metal Grey 0.00 Negative 298 7/7/2015 11:13 Exterior C Door, Ext.4 Door Deteriorated Metal Grey 0.00 Negative 299 7/7/2015 11:13 Exterior C Door, Ext.4 Casing Deteriorated Metal Grey 0.00 Negative 300 7/7/2015 11:17 Exterior C Door, Roll-Up5 Jamb Deteriorated Metal Grey 0.05 Negative 301 7/7/2015 11:17 Exterior C Door, Roll-Up5 Door Intact Metal White 0.01 Negative 302 7/7/2015 11:18 Exterior B Door, Ext.4 Door Deteriorated Metal Grey 0.01 Negative 303 7/7/2015 11:18 Exterior B Door, Ext.4 Jamb Deteriorated Metal Grey 0.01 Negative 304 7/7/2015 11:18 Exterior B Door, Ext.4 Casing Deteriorated Metal Grey 0.00 Negative 305 7/7/201511:20 Exterior C dock Ceiling Intact Stucco White 0.00 Null 306 7/7/201511:21 Exterior C dock Ceiling Intact Stucco White 0.00 Negative 307 7/7/2015 11:21 Exterior C dock Column 1 Deteriorated Metal Grey 0.07 Negative 308 7/7/2015 11:22 Exterior C dock Column 2 Deteriorated Metal Grey 0.09 Negative 309 7/7/201511:23 Room 28 C Ceiling Ceiling Intact Stucco White 0.01 Negative 310 7/7/2015 11:23 Room 28 B Wall, Int. Wall Intact Block White 0.00 Negative 1005 S. Eugene Street, Greensboro, NC.xlsx All XRF Readings Reading No Time Rooms Side Component Feature Condition Substrate Color PbC Results 311 7/7/2015 11:24 Room 28 C Wall, Int. Wall Intact Block White 0.00 Negative 312 7/7/2015 11:24 Room 28 D Wall, Int. Wall Intact Block White 0.00 Negative 313 7/7/2015 11:24 Room 28 A Wall, Int. Wall Intact Concrete White 0.00 Negative 314 7/7/2015 11:24 Room 28 B Door, Int. Door Deteriorated 1 Metal Grey 0.00 1 Negative 315 7/7/2015 11:25 Room 28 B Door, Int. Casing Deteriorated Metal Grey 0.00 Negative 316 7/7/2015 11:26 Exterior C Siding, Ext. Wall Intact Block White 0.01 Negative 317 7/7/2015 11:28 Exterior D Siding, Ext. Wall Intact Concrete White 0.00 Negative 318 7/7/2015 11:28 Exterior D Siding, Ext. Soffit Intact Stucco White 0.00 Negative 319 1 7/7/2015 11:28 Exterior D Siding, Ext. Fascia Intact Concrete White 0.00 Negative 320 7/7/2015 11:29 Exterior D Door, Ext.1 Door Deteriorated Metal Brown 0.00 Negative 321 7/7/2015 11:30 Exterior D Door, Ext.1 Casing Deteriorated Metal Brown 0.00 Negative 322 7/7/2015 11:31 out bldg 1 C Door, Ext. Door Deteriorated Wood White 0.00 Negative 323 7/7/2015 11:31 out bldg 1 C Door, Ext. Casing Deteriorated Wood White 0.00 Negative 324 7/7/2015 11:31 out bldg 1 C Win., Ext. Casing Deteriorated Wood White 0.00 Negative 325 7/7/2015 11:32 out bldg 1 C Siding, Ext. Wall Deteriorated Wood White 0.00 Negative 326 7/7/2015 11:32 out bldg 1 D Siding, Ext. Wall Deteriorated Wood White 0.00 Negative 327 7/7/2015 11:32 out bldg 1 A Siding, Ext. Wall Deteriorated Wood White 0.00 Negative 328 7/7/2015 11:32 out bldg 1 B Siding, Ext. Wall Deteriorated Wood White 0.00 Negative 329 7/7/201511:34 Carport C Ceiling Ceiling Intact Concrete White 0.00 Negative 330 7/7/2015 11:35 Carport C Ceiling Ceiling beam Intact Metal Grey 0.02 Negative 331 7/7/201511:35 Carport C Ceiling Ceiling truss Deteriorated Metal Grey 0.19 Negative 332 7/7/2015 11:36 Carport A Ceiling Column 1 Deteriorated Metal Grey 0.05 Negative 333 7/7/2015 11:36 Carport A Ceiling Column 3 Deteriorated Metal Grey 0.07 Negative 334 7/7/2015 11:37 Carport A Ceiling Column 5 Deteriorated Metal Grey 0.04 Negative 335 7/7/2015 11:37 Carport A Ceiling Column 7 Deteriorated Metal Grey 0.12 Negative 336 7/7/2015 11:41 Bldg Ext 2 Room 1 A Ceiling Ceiling Intact Concrete White 0.00 Negative 337 7/7/2015 11:42 Bldg Ext 2 Room 1 A Wall, Int. Wall Intact Block White 0.00 Negative 338 7/7/2015 11:42 Bldg Ext 2 Room 1 B Wall, Int. Wall Intact Block White 0.00 Negative 339 7/7/2015 11:42 Bldg Ext 2 Room 1 C Wall, Int. Wall Intact Block White 0.00 Negative 340 7/7/2015 11:43 Bldg Ext 2 Room 1 D Wall, Int. Wall Intact Block White 0.00 Negative 341 7/7/2015 11:43 Bldg Ext 2 Room 1 A Door, Int. Door Deteriorated Metal Grey 0.02 Negative 342 7/7/2015 11:43 Bldg Ext 2 Room 1 A Door, Int. Casing Deteriorated Metal Grey 0.00 Negative 343 7/7/2015 11:43 Bldg Ext 2 Room 1 A Door, Roll -Up Casing Deteriorated Metal Grey 0.00 Negative 344 7/7/2015 11:44 Bldg Ext 2 Room 1 A Door, Roll -Up Door Intact Metal Grey 0.00 Negative 345 7/7/2015 11:44 Bldg Ext 2 Room 2 A Door, Roll -Up Door Intact Metal Grey 0.00 Negative 346 7/7/2015 11:44 Bldg Ext 2 Room 2 A Door, Roll -Up Casing Intact Metal Grey 0.00 Negative 347 7/7/2015 11:45 Bldg Ext 2 Room 2 A Door, Int. Casing Deteriorated Metal Grey 0.00 Negative 348 7/7/2015 11:45 Bldg Ext 2 Room 2 A Door, Int. Door Deteriorated Metal Grey 0.00 Negative 349 7/7/2015 11:45 Bldg Ext 2 Room 2 A Wall, Int. Wall Intact Block White 0.00 Negative 350 7/7/2015 11:46 Bldg Ext 2 Room 2 C Wall, Int. Wall Intact Block White 0.00 Negative 351 7/7/2015 11:46 Bldg Ext 2 Room 2 C Ceiling Ceiling Intact Concrete White 0.00 Negative 352 7/7/2015 11:46 Bldg Ext 2 Room 2 A Siding, Ext. Wall Intact Block White 0.01 Negative 353 7/7/2015 11:46 Bldg Ext 2 Room 2 B Siding, Ext. Wall Intact Block White 0.00 Negative 354 7/7/2015 11:47 Bldg Ext 2 Room 2 C Siding, Ext. Wall Intact Block White 0.00 Negative 355 7/7/2015 11:47 Bldg Ext 2 Room 2 D Siding, Ext. Wall Intact Block White 0.00 Negative 356 7/7/2015 11:48 Bldg Ext 2 Room 2 A Door, Roll -Up Door Intact Metal Grey 0.00 Negative 357 7/7/2015 11:48 Bldg Ext 2 Room 2 A Door, Roll -Up Casing Deteriorated Metal Grey 0.00 Negative 358 7/7/2015 11:48 Bldg Ext 2 Room 2 A Door, Ext. Casing Deteriorated Metal White 0.00 Negative 359 7/7/2015 11:48 Bldg Ext 2 Room 2 A Door, Ext. Door Deteriorated Metal Grey 0.00 Negative 360 7/7/2015 11:49 Bldg Ext 3 Exterior B Door, Ext. Door Deteriorated Metal Brown 0.00 Negative 361 7/7/2015 11:49 Bldg Ext 3 Exterior B Door, Ext. Casing Deteriorated Metal Brown 0.00 Negative 362 7/7/2015 11:50 Bldg Ext 3 Exterior B Siding, Ext. Wall Intact Block White 0.04 Negative 363 7/7/2015 11:50 Bldg Ext 3 Exterior C Siding, Ext. Wall Intact Block White 0.01 Negative 364 7/7/2015 11:50 Bldg Ext 3 Exterior D Siding, Ext. Wall Intact Block White 0.06 Negative 365 7/7/2015 11:51 Bldg Ext 3 Exterior A Siding, Ext. Wall Intact Block White 0.03 Negative 366 7/7/201512:08 Calibration 1.00 Positive 367 7/7/201512:08 Calibration 1.00 Positive 368 7/7/201512:09 Calibration 1.00 Positive APPENDIX B - FLOOR PLAN 10 F l s Z APPENDIX C - PHOTOGRAPHS da"ll -it .29 IF.5 �-�� .� 11 1�7 ABSOLUTELY NO SMOKING r vrr�J APPENDIX D - RISK ASSESSOR AND FIRM CREDENTIALS Pat McCrory Covemor V, North Carolina Department of Health and Human Services Division of Public Health August 26, 2014 Donald P Suleski 2121 Commonwealth Ave Ste 202 Charlotte, NC 28205 Dear Mr. Suleski: Aldona Z. Wos, M.D. Ambaseadcr(Rcr.) Secretary DHHS Penelope Slade-Saayer Divinort Di Y[or The Health Hazards Control Unit (HHCU) has determined that you have fulfilled the application requirements and are eligible for lead certification as a(n) RISK ASSESSOR. Your assigned Risk Assessor certification number is 120249, which is reflected on your enclosed North Carolina Lead Certification card. The State requires that all persons conducting regulated lead -based paint activities be certified and have their identification card on -site. A "Lead -Based Paint Activity Summary" shall be submitted to the HHCU by the certified inspector or risk assessor within 45 days of each inspection, risk assessment, or lead hazard screen conducted. The information shall be submitted on a form provided or approved by the Program, per I OA NCAC 41 C .0807(b), Lead -Based Paint Hazard Management Program Rules. Accredited refresher training must be completed at least every 24 months from the date of the last accredited training course AND within twelve months prior to applying for certification. The HHCU strongly recommends that individuals note the date of certification expiration and ensure all refresher training meets the above requirements. Your North Carolina Risk Assessor certification will expire on AUGUST 31, 2015. It is NOT the policy of the HHCU to issue renewal notices. If you wish to continue working as a(n) Risk Assessor after this expiration date, you must successfully complete the required training and submit a completed application to this office prior to August 31, 2015. If you should perform lead -based paint activities as a(n) Risk Assessor without a valid North Carolina certification, you will be in violation of State regulations and may be cited for noncompliance. If you have any questions, please contact our office at (919) 707-5950. Sincerely, ON Donald P Suleski Ed Norman Coat C e, NC 8205calth Ave Ste Program Manager charlotte, NC 28206 � g Health Hazards Control Unit 1a.ralxo RI51(PSSESSOR 1A3<9 IN$ e�14 LW31-]O15 � RIS L19.15-20Sa114 hhs.gov • www.publichealth.nc.gov 1-707-5950 • Fax 919-870-4808 Six Forks Road • Raleigh, NC 27609 A Mailing Address- 1912 Mail Service Center • Raleigh, NC 27699-1912 A An Equal Opportunity I Affirmative Action Employer y ! 60 1041 ` North Carolina Department of Health and Human Services {( t Division of Public Health P t M17 Aldona Z. W.,M.D. G v mor Ambassador (RcL) Secretary DHHS Penelope Slade -Sawyer Division Director November 17.2014 Peter M Hubicki 3610 Country Club Dr Charlotte, NC 28205 Dear Mr. Hubicki: The Health Hazards Control Unit (HHCU) has determined that you have fulfilled the application requirements and are eligible for lead certification as a(n) RISK ASSESSOR. Your assigned Risk Assessor certification number is 120001, which is reflected on your enclosed North Carolina Lead Certification card. The State requires that all persons conducting regulated lead -based paint activities be certified and have their identification card on -site. A "Lead -Based Paint Activity Summary" shall be submitted to the HHCU by the certified inspector or risk assessor within 45 days of each inspection, risk assessment, or lead hazard screen conducted. The information shall be submitted on a form provided or approved by the Program, per l0A NCAC 41C .0807(b), Lead -Based Paint Hazard Management Program Rules. Accredited refresher training must be completed at least every 24 months from the date of the last accredited training course AND within twelve months prior to applying for certification. The HHCU strongly recommends that individuals note the date of certification expiration and ensure all refresher training meets the above requirements. Your North Carolina Risk Assessor certification will expire on NOVEMBER 30, 2015. It is NOT the policy of the HHCU to issue renewal notices. If you wish to continue working as a(n) Risk Assessor after this expiration date, you must successfully complete the required training and submit a completed application to this office prior to November 30, 2015. If you should perform lead -based paint activities as a(n) Risk Assessor without a valid North Carolina certification, you will be in violation of State regulations and may be cited for noncompliance. If you have any questions, please contact our office at (919) 707-5950. rvoBrP CAROLINA LEAD CERTIFICATION Peter M Hubicki 3610 Country Club Or CharlottI& e, NC 28205 1:.MIN 'DESIGNER 14D]Sa pE 02.16x 4 11-362p15 IRISKASSESSDR 1200ol INS W15_a114 M14 11b.2115 Sincerely, Ed Norman Program Manager Health Hazards Control Unit RIS M16.2014 lv • www.publichealthmc.gov 5950 • Fax 919-8704808 Wks Road . Raleigh, NC 27609 Jt a1 mg ress: Service Center • Raleigh, NC 27699-1912 y An Equal Opportunity / APtrmalive Action Employer jk Mhae NUM RADIOACTIVE MATERIALS BRANCH Page 1 of 3 JAS� RADIATION PROTECTION SECTION N. C. DEPARTMENT OF HEALTH AND HUMAN SERVICES RADIOACTIVE MATERIALS LICENSE Pursuant to North Carolina Regulations for Protection Against Radiation and in reliance on statements and representations heretofore made by the licensee, a license is hereby issued authorizing the licensee to receive, acquire, own, possess, transfer, and import the accelerator(s) listed below; and use such accelerator(s) for the purpose(s) and at the place(s) designated below. This License is subject to all applicable rules and regulations of the North Carolina Department of Health and Human Services now and hereafter in effect and to any conditions specified below. 1 Licensee Get the Lead Out, LLC 3. License No: 060-0989-1 License Type Name: 00310 2a. Mailing 2121 Commonwealth Avenue, Suite 220 Address: Charlotte, NC 28205-5120 4. Expiration Date: December 31, 2019 b. Physical 2121 Commonwealth Avenue, Suite 220 Address: Charlotte, NC 28205-5120 Application Type: Amendment Application c. Radiation 5. a. Amendment No.: 12 Safety Officer: Peter M. Hubicki, b. Issuance Date: May 09, 2014 6. Radioactive Material 7. Chemical and/or Physical 8. Maximum Amount of Radioactivity and/or (element and mass no.) Form Quantity of Radioactive material which Licensee May Possess at Any One Time. A. Cobalt 57 A. Sealed Source A. Total Possession not to exceed 60.00 mCi No Single source to exceed 12.00 mCi B. Cadmium 109 B. Sealed Source B. Total Possession not to exceed 500.00 mCi No Single source to exceed 50.00 mCi C. Americium-241 / Beryllium C. Sealed Source C. Total Possession not to exceed 50.00 mCi No Single source to exceed 10.00 mCi 9. Authorized Use: A. To be used in an RMD Model LPA-1 X-ray Fluorescence Analyzer to test for lead content in paint. Sealed Source & Device Registry No. MA-0573-D-103-B, with a leak test frequency of twelve months. B. To be used in a Niton Model XLp 300 analyzer to test for lead content in paint. Sealed Source & Device Registry No. MA- 1159-D-101-B, with a leak test frequency of six months. C. To be used in a Niton Model XLp 300 analyzer to test for lead content in paint. Sealed Source & Device Registry No. MA- 1159-D-101-B, with a leak test frequency of six months. CONDITIONS 10. A. The authorized place of receipt and storage of radioactive material is the licensee's address stated in condition 2b. above. B. Additional authorized places of receipt and use of radioactive material are listed below if applicable: No Additional Locations C. Radioactive materials may be used at temporary jobsites of the licensee throughout the State of North Carolina in areas not under exclusive Federal jurisdiction (Federal installations such as military bases, V.A. Hospitals, etc.). Authorization for the use of radioactive materials at temporary jobsites under exclusive Federal Jurisdiction shall be obtained either by (1) filing a NRC Form 241 [10 CFR 150.20(b)], or (2) applying for reciprocity, or (3) applying for a specific license from the NRC if the length of the job is to exceed six (6) months. D. This condition does not prohibit the use of radioactive materials in other states; however, before radioactive materials can be used at a temporary jobsite in another state, authorization must be obtained from the State, if it is an Agreement state, or from the Nuclear Regulatory Commission for any non -Agreement State, either by filing for reciprocity or applying for a specific license. 11. The licensee shall comply with the provisions of 15A NCAC 11 .1600 "Standards for Protection Against Radiation," and 15A NCAC 11 .1000 "Notices, Instructions, Reports and Inspections." (The North Carolina Regulations for Protection Against Radiation are contained in 15A NCAC 11.) WITHHOLD FROM PUBLIC DISCLOSURE UNDER N.C,G.S. 104E-9(a)(4) EXCEPT TO INDIVIDUALS WITH NEED TO KNOW NORTH CAROLINA RADIOACTIVE MATERIALS BRANCH Page 2 of 3 !•. RADIATION PROTECTION SECTION License No.: 060-0989-1 N. C. DEPARTMENT OF HEALTH AND HUMAN SERVICES RADIATION PROTECTION RADIOACTIVE MATERIALS LICENSE 12. A. Licensed material shall only be used by: Peter Hubicki OR individuals who (1) have successfully completed a manufacturers training program for gauge users, (2) have been instructed in the licensee's routine operating and emergency procedures, and (3) have been designated in writing as having completed these requirements by the Radiation Safety Officer. B. Records of these designations shall be maintained for three (3) years after the company no longer employs the individual. C. The licensee shall establish a method of identification and documentation of training for the persons authorized in condition A above. This shall be made available for review by the agency at the time of either a field or home office inspection. D. The Radiation Safety Officer for the activities authorized under this license shall be Peter M. Hubicki. 13. A. Each sealed source containing radioactive material, other than Hydrogen 3 with a half-life greater than thirty (30) days and in any form other than gas, shall be tested for leakage and/or contamination at intervals prescribed in the respective Registry of Radioactive Sealed Sources and Devices sheet. In the absence of a Registry of Radioactive Sealed Sources and Devices sheet, tests for leakage and/or contamination shall be conducted at intervals not to exceed six (6) months, except that each source designed for the purpose of emitting alpha particles shall be tested at intervals not to exceed three (3) months. In the absence of a certificate from a transferor indicating that a test has been made within six (6) months prior to the transfer, the sealed source shall not be put into use until tested. B. The test shall be capable of detecting the presence of 0.005 microcurie of radioactive material on the test sample. The test sample shall be taken from the sealed source or from the surfaces of the device in which the sealed source is permanently mounted or stored on which one might expect contamination to accumulate. Records of leak test results shall be kept in units of microcuries and maintained for inspection by the agency. C. If the test reveals the presence of 0.005 microcurie or more of removable contamination, the licensee shall immediately withdraw the sealed source from use and shall cause it to be decontaminated and repaired or to be disposed of in accordance with agency regulations. A report shall be filed within five (5) days of the test with the Radioactive Materials Branch, Radiation Protection Section,1645 Mail Service, Raleigh, NC 27699-1645, describing the equipment involved, the test results, and the corrective action taken. D. Tests for leakage and/or contamination shall be performed by persons specifically authorized by the agency to perform such services. 14. The licensee may transport licensed material or deliver licensed material to a carrier for transport in accordance with the provision of Section 71.5, Title 10, Code of Federal Regulations, Part 71, "Packaging of Radioactive Material For Transport." 15 Sealed sources containing radioactive material shall not be opened or removed from their respective source holders by the licensee. 16. The licensee shall keep records for each device authorized in this license showing which authorized user has the device, the time and date the device was removed from storage, job where device was used and the time and date the device was placed back into storage. Records of use shall be kept for two (2) years for inspection by the agency or until they have been reviewed by the agency and if the records are determined to be satisfactory, then they may be disposed of. 17. The licensee shall conduct a physical inventory of all sealed sources received and possessed under this license at intervals not to exceed six (6) months. Records of the inventories shall be maintained for inspection by the agency and shall include the quantities and kinds of radioactive material, location of sources and the date of the inventory. 18. In addition to the possession limits in condition 8 above, the licensee shall further restrict the possession of licensed material to quantities below the minimum limit specified in 15A NCAC 11 .0353 for establishing decommissioning financial assurance. 19. The licensee shall annually review its Radiation Protection Program for content and implementation [Reference 15A NCAC 11 .1603(c)]. Documentation of the Radiation Protection Program reviews shall be retained for inspection by the agency [Reference: 15A NCAC 11 .1636]. 20. The licensee shall institute the provisions of 15A NCAC 11 .1610 when an occupationally exposed woman voluntarily informs her supervisor, in writing, of the pregnancy and the estimated date of conception. WITHHOLD FROM PUBLIC DISCLOSURE UNDER N.C.G.S. 104E-9(a)(4) EXCEPT TO INDIVIDUALS WITH NEED TO KNOW NORTH CAROLINA RADIOACTIVE MATERIALS BRANCH Page 3 of 3 !•. RADIATION PROTECTION SECTION License No.: 060-0989-1 N. C. DEPARTMENT OF HEALTH AND HUMAN SERVICES RADIATION PROTECTION RADIOACTIVE MATERIALS LICENSE 21. The licensee shall ensure that no individual "member of the public" [Reference: 15A NCAC 11 .0104(81)] receives a radiation dose in excess of the limits specified in 15A NCAC 11 .161 l (a) while conducting licensed activities. 22. This license may be subject to amendment, revision, modification, suspension, or revocation in accordance with the provisions of 15A NCAC 11 .0344. 23. In addition to the possession limits referenced in condition 8. above, the licensee shall further restrict possession of radionuclides listed in the table below to the quantities noted within the table. Sum of fractions for the radionuclides listed below shall not exceed Radionuclide Quantity (curies) Radionuclide Quantity (curies) Am-241 16 Pm-147 10,800 Am-241: Be 16 Pu-238 16 Cf-252 5.4 Pu-239:Be 16 Cm-244 13.5 Ra-226 10.8 Co-60 8.1 Se-75 54 Cs-137 27 Sr-90 (Y-90) 270 Gd-153 270 Tm-170 5,400 Ir-192 21.6 Yb-169 81 24. Except as specifically provided otherwise by this license, the licensee shall possess and use radioactive material described in conditions 6., 7., and 8. of this license in accordance with statements, representations and procedures and attachments listed below. The North Carolina Regulations for Protection Against Radiation shall govern unless the statements, representations, and procedures in the licensee's application and correspondence are more restrictive than the regulations. A. Letter with attachments dated May 12, 2011, signed by Peter M. Hubicki, RSO, email received May 18, 2011, and an administrative amendment to list Total Possession Limits and implement several updates. B. Application with attachments dated October 2, 2009, signed by Peter M. Hubicki, RSO. C. Application for with attachments, dated April 29, 2014, signed by Peter M. Hubicki, Asst. VP, RSO. For: W. Lee Cox, III Chief, Radiation Protection Section WITHHOLD FROM PUBLIC DISCLOSURE UNDER N.C.G.S. 104E-9(a)(4) EXCEPT TO INDIVIDUALS WITHA NEED TO KNOW Niton XLp 300, 912412004, ed. 1 Performance Characteristic Sheet EFFECTIVE DATE: September 24, 2004 MANUFACTURER AND MODEL: EDITION NO.: 1 Make: Niton LLC Tested Model: XLp 300 Source: 109Cd Note: This PCS is also applicable to the equivalent model variations indicated below, for the Lead -in -Paint K+L variable reading time mode, in the XLi and XLp series: XLi 300A, XLi 301A, XLi 302A and XLi 303A. XLp 300A, XLp 301A, XLp 302A and XLp 303A. XLi 700A, XLi 701A, XLi 702A and XLi 703A. XLp 700A, XLp 701A, XLp 702A, and XLp 703A. Note: The XLi and XLp versions refer to the shape of the handle part of the instrument. The differences in the model numbers reflect other modes available, in addition to Lead -in - Paint modes. The manufacturer states that specifications for these instruments are identical for the source, detector, and detector electronics relative to the Lead -in -Paint mode. FIELD OPERATION GUIDANCE OPERATING PARAMETERS: Lead -in -Paint K+L variable reading time mode. XRF CALIBRATION CHECK LIMITS 110.8 to 1.2 mg/cm2 (inclusive) 11 The calibration of the XRF instrument should be checked using the paint film nearest 1.0 mg/cm2 in the NIST Standard Reference Material (SRM) used (e.g., for NIST SRM 2579, use the 1.02 mg/cm2 film). If readings are outside the acceptable calibration check range, follow the manufacturer's instructions to bring the instruments into control before XRF testing proceeds. SUBSTRATE CORRECTION: For XRF results using Lead -in -Paint K+L variable reading time mode, substrate correction is not needed for: Brick, Concrete, Drywall, Metal, Plaster, and Wood INCONCLUSIVE RANGE OR THRESHOLD: K+L MODE READING DESCRIPTION SUBSTRATE THRESHOLD (mg/cm) Results not corrected for substrate bias on any Brick 1.0 substrate Concrete 1.0 Drywall 1.0 Metal 1.0 Plaster 1.0 Wood 1.0 1 of 3 Niton XLp 300, 912412004, ed. 1 BACKGROUND INFORMATION EVALUATION DATA SOURCE AND DATE: This sheet is supplemental information to be used in conjunction with Chapter 7 of the HUD Guidelines for the Evaluation and Control of Lead -Based Paint Hazards in Housing ("HUD Guidelines"). Performance parameters shown on this sheet are calculated from the EPA/HUD evaluation using archived building components. Testing was conducted in August 2004 on 133 testing combinations. The instruments that were used to perform the testing had new sources; one instrument's was installed in November 2003 with 40 mCi initial strength, and the other's was installed June 2004 with 40 mCi initial strength. OPERATING PARAMETERS: Performance parameters shown in this sheet are applicable only when properly operating the instrument using the manufacturer's instructions and procedures described in Chapter 7 of the HUD Guidelines. SUBSTRATE CORRECTION VALUE COMPUTATION Substrate correction is not needed for brick, concrete, drywall, metal, plaster or wood when using Lead -in - Paint K+L variable reading time mode, the normal operating mode for these instruments. If substrate correction is desired, refer to Chapter 7 of the HUD Guidelines for guidance on correcting XRF results for substrate bias. EVALUATING THE QUALITY OF XRF TESTING: Randomly select ten testing combinations for retesting from each house or from two randomly selected units in multifamily housing. Use the K+L variable time mode readings. Conduct XRF retesting at the ten testing combinations selected for retesting. Determine if the XRF testing in the units or house passed or failed the test by applying the steps below. Compute the Retest Tolerance Limit by the following steps: Determine XRF results for the original and retest XRF readings. Do not correct the original or retest results for substrate bias. In single-family housing a result is defined as the average of three readings. In multifamily housing, a result is a single reading. Therefore, there will be ten original and ten retest XRF results for each house or for the two selected units. Calculate the average of the original XRF result and retest XRF result for each testing combination. Square the average for each testing combination. Add the ten squared averages together. Call this quantity C. Multiply the number C by 0.0072. Call this quantity D. Add the number 0.032 to D. Call this quantity E. Take the square root of E. Call this quantity F. Multiply F by 1.645. The result is the Retest Tolerance Limit. Compute the average of all ten original XRF results. Compute the average of all ten re -test XRF results. Find the absolute difference of the two averages. 2of3 Niton XLp 300, 912412004, ed. 1 If the difference is less than the Retest Tolerance Limit, the inspection has passed the retest. If the difference of the overall averages equals or exceeds the Retest Tolerance Limit, this procedure should be repeated with ten new testing combinations. If the difference of the overall averages is equal to or greater than the Retest Tolerance Limit a second time, then the inspection should be considered deficient. Use of this procedure is estimated to produce a spurious result approximately 1 % of the time. That is, results of this procedure will call for further examination when no examination is warranted in approximately 1 out of 100 dwelling units tested. TESTING TIMES: For the Lead -in -Paint K+L variable reading time mode, the instrument continues to read until it is moved away from the testing surface, terminated by the user, or the instrument software indicates the reading is complete. The following table provides testing time information for this testing mode. The times have been adjusted for source decay, normalized to the initial source strengths as noted above. Source strength and type of substrate will affect actual testing times. At the time of testing, the instruments had source strengths of 26.6 and 36.6 mCi. Testing Times Using K+L Reading Mode Seconds All Data Median for laboratory -measured lead levels m /cm2 Substrate 25t" Median 75t" Pb < 0.25 0.25 < Pb<1.0 1.0 < Pb Percentile Percentile Wood 4 11 19 11 15 11 Drywall Metal 4 12 18 9 12 14 Brick 8 16 22 15 18 16 Concrete Plaster CLASSIFICATION RESULTS: XRF results are classified as positive if they are greater than or equal to the threshold, and negative if they are less than the threshold. DOCUMENTATION: A document titled Methodology for XRF Performance Characteristic Sheets provides an explanation of the statistical methodology used to construct the data in the sheets, and provides empirical results from using the recommended inconclusive ranges or thresholds for specific XRF instruments. For a copy of LI IIJ UVL..UI I ICI IL UCIII LI It; IVdLIVI IQI LCCIU II IIVI II IQLIVI I I CI ILCI %,IGQI II IUI IVUJC QL 1-000--t4 t-LC.PILJ. This XRF Performance Characteristic Sheet was developed by the Midwest Research Institute (MRI) and QuanTech, Inc., under a contract between MRI and the XRF manufacturer. HUD has determined that the information provided here is acceptable when used as guidance in conjunction with Chapter 7, Lead -Based Paint Inspection, of HUD's Guidelines for the Evaluation and Control of Lead -Based Paint Hazards in Housing. 3of3 APPENDIX E - GLOSSARY COMMON LEAD -BASED PAINT TERMS Lead -Based Paint: HUD's definition is any paint, varnish, shellac, or other coating that contains lead equal to or greater than 1.0 mg/cm2as measured by XRF or laboratory analysis, or 0.5 percent by dry weight (5,000 mg/g, 5,000 ppm, or 5,000 mg/kg) as measured by laboratory analysis. Lead -Based Paint Hazards: Housing conditions that cause human exposure to unsafe levels of lead from paint. These conditions include deteriorated lead - based paint; friction, impact or chewable painted surfaces; lead -contaminated dust; or lead -contaminated soil. Physical Terms Building Component: Any element of a building that may be painted or have dust on its surface, e. g. walls, stair treads, floors, railings, doors, window sills, etc. Building component replacement: See Replacement. Deteriorated Lead -Based Paint: Any lead -based paint coating on a damaged or deteriorated surface or fixture, or any interior or exterior lead -based paint that is peeling, chipping, blistering, flaking, worn, chalking, alligatoring, cracking, or otherwise becoming separated from the substrate. Lead Hazard Evaluation Clearance Examination: Clearance is performed after hazard reduction, rehabilitation or maintenance activities to determine if a unit is safe for occupancy. It involves a visual assessment, analysis of dust and/or soil samples, and preparation of report. A certified risk assessor, paint risk assessor, or clearance technician (independent from entity/individual conducting paint stabilization or hazard reduction) conducts clearance. Paint Testing: Testing of specific surfaces, by XRF (x-ray fluorescence) or lab analysis, to determine the lead content of these surfaces, performed by a certified lead -based paint risk assessor or certified risk assessor. Risk Assessment: A comprehensive evaluation for lead -based paint hazards that includes paint testing, dust and soil sampling, and a visual evaluation. The risk assessment report identifies lead hazards and appropriate lead hazard reduction methods. A certified risk assessor must conduct the assessment. Visual Assessment: A visual evaluation of interior and exterior painted surfaces to identify specific conditions that contribute to lead -based paint hazards. A certified risk assessor or Housing Quality Standards (HQS) risk assessor trained in visual assessment performs the assessment. Lead Hazard Reduction Abatement: A measure or set of measures designed to permanently (i.e. 20 or more years) eliminate lead -based paint hazards or lead -based paint. Abatement strategies include the removal of lead -based paint, enclosure, encapsulation, replacement of building components coated with lead -based paint, removal of lead -contaminated dust, and removal of lead -contaminated soil or overlaying of soil with a durable covering such as asphalt (grass and sod are considered interim control measures). All of these strategies require preparation; cleanup; waste disposal; post abatement clearance testing; record keeping; and, if applicable, monitoring. See also Complete abatement and Interim controls. Complete abatement: Abatement of all lead -based paint inside and outside a property or building and reduction of any lead -contaminated dust or soil hazards. All of these strategies require preparation; cleanup; waste disposal; post - abatement clearance testing; recordkeeping; and, if applicable, reevaluation and on -going monitoring. See also Abatement. Cleaning: The process of using a HEPA vacuum and wet cleaning agents to remove leaded dust; the process includes the removal of bulk debris from the work area. OSHA prohibits the use of compressed air to clean lead -contaminated dust from a surface. Encapsulation: Any covering or coating that acts as a barrier between lead - based paint and the environment, the durability of which relies on adhesion and the integrity of the existing bonds between multiple layers of paint and between the paint and the substrate. See also Enclosure. Enclosure: The use of rigid, durable construction materials that are mechanically fastened to the substrate to act as a barrier between the lead -based paint and the environment. Lead -based Paint Hazard Control: Activities to control and eliminate lead - based paint hazards, including interim controls, abatement, and complete abatement. Maintenance: Work intended to maintain adequate living conditions in a property, which has the potential to disturb lead -based paint or paint that is suspected of being lead -based. Monitoring: Surveillance to determine (1) that known or suspected lead -based paint is not deteriorating, (2) that lead -based paint hazard controls, such as paint stabilization, enclosure, or encapsulation have not failed, (3) that structural problems do not threaten the integrity of hazard controls or of known or suspected. Paint Film Stabilization: An interim control method that stabilizes painted surfaces and addressed the underlying cause of deterioration. Steps include repairing defective surfaces, wet scraping, priming, and repainting surfaces coated with deteriorated lead -based paint; paint film stabilization includes cleanup and clearance. Paint Removal: An abatement strategy that entails the removal of lead -based paint from surfaces. For lead hazard control work, this can mean using chemicals, heat guns below 1,100 °F, and certain contained abrasive methods. Open flame burning, open abrasive blasting, sandblasting, water blasting, and extensive dry scraping are prohibited paint removal methods. (Methylene chloride paint removers and dry scraping are also not recommended. ) Reevaluation: In lead hazard control work, the combination of a visual assessment and collection of environmental samples performed by a certified risk assessor to determine if a previously implemented lead -based paint hazard control measure is still effective and if the property remains lead -safe. Also known as reSurvey. Replacement: Replacement of existing features can be an appropriate abatement technique if the feature is deteriorated beyond repair or if the feature is of minor significance Treatment: In residential lead -based paint hazard control work, any method designed to control lead -based paint hazards. Treatment includes interim controls, abatement, and removal. Hazardous waste "treatment" is a method, technique, or process (such as neutralization) that is designed to change the physical, chemical, or biological character or composition of hazardous waste to neutralize it; render it non -hazardous or less hazardous; recover it; make it safer to transport, store, or dispose; or allow for easier recovery, storage, or volume reduction. Lead Poisoning Environmental Intervention Blood Lead Level: The level of lead in blood that requires intervention in a child under age six. This is defined as a blood lead level of 20 µg/dL (micrograms per deciliter) of whole blood or above for a single test, or blood lead levels of 15-19 µg/dL in two tests taken at least three months apart. LEAD -BASED PAINT — KEY UNITS OF MEASUREMENT µq (Microgram): A Microgram is 1/1000t" of a milligram (or one millionth of a gram). To put this unit into perspective, a penny weighs 2 grams. To get a microgram, you would need to divide the penny into 2 million pieces. A microgram is one of those two million pieces. ft2 (Square foot): One square foot is equal to an area that has a length of one foot (12 inches) and a width of one foot (12 inches). µg/dL: Micrograms per deciliter used to measure the level of lead in children's blood to establish whether intervention is needed. A deciliter (1/10th of liter) is a little less than half a cup. As noted above, a microgram is the same weight as one penny divided into two million parts. mq/cm2: Milligrams per square centimeter, used for paint by XRF machines. percent: Percent by weight, used usually for lead -based paint (1 percent = 10,000 µg/gram. ppm: Parts per million by weight, equivalent to µg/gram (10,000 ppm = 1 percent). Used to measure lead in paint and soil. LEAD -BASED PAINT STANDARDS Paint — Definition of Lead -Based Paint In North Carolina, paint that contains at least: * 1 milligram per centimeters square (mg/cm2) of lead; * 0.5 percent lead; or * 5,000 parts per million (ppm) lead by dry weight.