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1107_Buncombe_MSWLF_CDLF_Oct20GW_FID1575383_20210407
DEN R USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR I IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Bunnell-Lammons Engineering, Inc. (consultant) Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Andrew W. Alexander, PG RSM E-mail: andy.alexander@blecorp.com Phone: (864)288-1265 NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) 1107-MSWLF 1 Panther Branch Road -1996 Buncombe County Landfill Alexander, NC, 28701 .1600 October 26-30, 2020 1107-CDLF -1998 0 Environmental Status: (Check all that apply) Initial/Background Monitoring 0 Detection Monitoring Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells El Leachate monitoring data El water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. El Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Andrew W. Alexander, PG RSM Consulting Hydrogeologist (864) 288-1265 Facility Representative Name (Print) Title (Area Code) Telephone Number �� w a• �E,o•,....=.. ®e,•o.owm, 04-02-2021 Signature Date 6004 Ponders Court, Greenville, SC, 29615 Facility Representative Address C-284 & C-1538 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 Affix NC Licensed/ Professional Geologist Seal ZN CAAp 1' JGE NSF•ti% • ? �► t 5 cr aF�Lo4�•P�o, WA fi W. A��;.�� rrr poll $i t��� REPORT OF WATER QUALITY SAMPLING AND ANALYSIS 2nd SEMI-ANNUAL EVENT 2020 BUNCOMBE COUNTY LANDFILL ALEXANDER, NORTH CAROLINA Permit No. 1107-MSWLF-1996 Permit No. 1107-CDLF-1998 Prepared For: Buncombe County BLE Project Number J20-9378-22 ►111111lr April 2, 2021 ``�+■'[�kk GAF?[�]`�'■.,�� .Z.�� NSF",, NZ BLE North Carolina Business Licenses C-284 & C-1538 IM 13UNNELL M LAMMONS ENGINEERING 6004 Panders Court I Greenville, 5C 29615 t, 864.288.1265 A. 864,286.4338 w fnft]@blecorwom BLECORP.COM � CANNONS ENGINEERING April 2, 2021 Buncombe County Solid Waste Department 81 Panther Branch Road Alexander, North Carolina 28701 Attention: Ms. Kristy Smith Subject: Report of Water Quality Sampling and Analysis 2" Semi -Annual Event 2020 Buncombe County Landfill Alexander, North Carolina Permit Nos. 1107-MSWLF-1996 & 1107-CDLF-1998 BLE Project Number J20-9378-22 Dear Ms. Smith: Pursuant to your county's authorization of Bunnell-Lammons Engineering, Inc. (BLE) Proposal Number J20- 9378-22, dated July 30, 2020, BLE has prepared this report of the groundwater and surface water sampling and laboratory analysis for the 2' semi-annual sampling event of 2020 at the Buncombe County Landfill. Consistent with the North Carolina Division of Waste Management (DWM) — Solid Waste Section (SWS) approved monitoring program, sampling and analysis was conducted twice in 2020. This report contains the information required by the DWM to document the sampling and analysis activities for the second event of 2020 in the State's permanent project record. Sincerely, BUNNELL LAMMONS ENGINEERING INC. I it . B1aisOGGr.. Staff Hydrogeologist cc: Ms. Jaclynne Drummond — DWM-ARO 94/ Andrew W. Ale der, P.G., RSM Senior Hydrogeologist Registered, NC #1475 Ilblegvlsvrllsolidwasteprojectslbuncombe county lf, nc19378-22 fall 2020 semi repor6reportlactive bclf 1107-mswlf-1996 2nd 2020 semi-annual 9378-22.docx 6004 Ponders Court, Greenville, SC 29615 ILH64.288.1265 1`4864.288.4430 P—Minfo@hleeorp.rom BLECORP.COM 1s 1m 1i Buncombe County Landfill -- Alexander, North Carolina April 2, 2021 Report of Groundwater Sampling and Analysis — 2,d Semi -Annual Event 2020 BLE Project No. J20-9378-22 TABLE OF CONTENTS 1.0 PROJECT INFORMATION........................................................................................................1 2.0 FIELD ACTIVITIES, SAMPLING, AND ANALYSIS.............................................................1 3.0 GROUNDWATER FLOW........................................................................................................... 2 4.0 RESULTS....................................................................................................................................... 2 4.1 Groundwater.................................................................................................................................... 2 4.2 Surface Water.................................................................................................................................. 3 4.3 Leak Detectors and Leachate Samples............................................................................................. 4 5.0 CONCLUSIONS AND RECOMMENDATIONS....................................................................... 5 6.0 QUALIFICATIONS OF REPORT.............................................................................................. 5 7.0 CLOSING.......................................................................................................................................5 Tables Table 1 Well Construction and Monitoring Well Data Table 2 Groundwater VOCs Table 3 Groundwater Field Parameters, Geochemical Parameters, and Total Metals Table 4 Surface Water VOCs Table 5 Surface Water Field Parameters and Total Metals Table 6 Leak Detector and Leachate VOCs Table 7 Leak Detector and Leachate Field Parameters and Total Metals Figures Figure 1 Site Location Map Figure 2 Groundwater Elevation Contour Map — October 26 — 30, 2020 Appendices Appendix A Field Sampling Logs — Pace Analytical Services, LLC. Appendix B Laboratory Analytical Data — Pace Analytical Services, LLC. iofi 1s 1m 1i Buncombe County Landfill -- Alexander, North Carolina April 2, 2021 Report of Groundwater Sampling and Analysis — 2,d Semi -Annual Event 2020 BLE Project No. J20-9378-22 1.0 PROJECT INFORMATION The subject 654-acre landfill site is located in Buncombe County, North Carolina, approximately nine miles north of the city of Asheville with a physical address of 81 Panther Branch Road in Alexander, North Carolina. Buncombe County owns and operates a Subtitle D MSWLF which includes Cell 1 through Cell 6 and a CDLF consisting of Phase 1 through Phase 6. Currently Cell 6 of the MSWLF and Phase 6 of the CDLF are the active waste units. MSWLF Cell 7 has been permitted for construction and MSWLF Cells 8 through 10 are planned (but not permitted) for future expansion. A Water Quality Monitoring Plan (WQMP) was finalized by BLE and submitted to the North Carolina Solid Waste Section (SWS). The WQMP was approved on January 2, 2018 (DIN 28513). The facility requires semi-annual groundwater, surface water, and leachate monitoring and reporting in accordance with the WQMP. Semi-annual sampling is typically conducted each April and October and those events are designated "Spring" and "Fall," respectively. This report represents the 2" d semi-annual (Fall) sampling event of 2020. The existing groundwater monitoring network for the Buncombe County Landfill consists of two (2) upgradient (background) wells (MW-1 and MW-ID) and twenty-five (25) downgradient (compliance) wells (MW-2, MW-2D, MW-3R, MW-4, MW-4D, MW-5, MW-5D, MW-6, MW-7, MW-8, MW-8D, MW-10, MW-10D, MW-11, MW-11D, MW-12, MW-12D, MW-13, MW-13D, MW-14, MW-14D, MW-15, MW- 15D, MW-17R, and MW-17DR). Wells MW-17 and MW-17D were abandoned September 14, 2020 and replaced by MW-17R and MW-DR respectively. In accordance with Rule .0602 and Rule .0544(c), eight (8) surface water monitoring locations have been established for the facility to monitor surface water quality surrounding the existing waste footprint. The existing surface water locations consist of one (1) upstream (background) point (SW-1) and seven (7) downstream (compliance) points (SW-2 through SW-8). In accordance with Rule .1626(12)(c), eight (8) active leachate sampling locations have been established for the facility. The locations include six (6) existing leak detection sampling locations associated with each MSWLF cell (Cells 1 through 6) designated LD-1 through LD-6, one (1) leachate leak detection sampling location near the leachate pond designated Leachate LD, and the Leachate Pond itself. 2.0 FIELD ACTIVITIES, SAMPLING, AND ANALYSIS Groundwater, surface water, and leachate samples were collected for the 2' semi-annual sampling event by personnel from Pace Analytical Services, LLC. (Pace) of Asheville, North Carolina between October 26-30, 2020. Groundwater samples were collected from all of the active groundwater monitoring well locations located on the site. The eight (8) surface water locations were sampled during the event. Additionally, the seven (7) leak detection and one (1) leachate pond locations were sampled. The groundwater, surface water, and leachate samples were delivered and analyzed in Pace's Columbia, South Carolina laboratory (former Shealy Environmental) for the constituents in the approved WQMP. The field parameters of dissolved oxygen, pH, redox potential, specific conductance, turbidity, and temperature were measured in the field by Pace. A copy of the Pace field sampling logs is included in Appendix A. A copy of the laboratory analytical data is included in Appendix B. 1 of 5 1s 1M 1i Buncombe County Landfill -- Alexander, North Carolina April 2, 2021 Report of Groundwater Sampling and Analysis — 2,d Semi -Annual Event 2020 BLE Project No. J20-9378-22 3.0 GROUNDWATER FLOW The water level data collected during the groundwater sampling event on October 26-30, 2020 is presented in Table 1. A groundwater elevation contour map is presented as Figure 2 which includes generalized groundwater flow directions. 4.0 RESULTS 4.1 Groundwater The results of the groundwater field and laboratory analyses are summarized on Tables 2 and 3 and the laboratory analytical data is included in Appendix B. VOC detections during the current sampling event included: • acetone (4 wells); • 1,1-DCA (1 well); • 1,2-DCA (1 well); • dichloromethane (1 well); • 2-Butanone (1 well); • vinyl chloride (2 wells); • tetrahydrofuran (2 wells); and • 1,4-Dioxane (4 wells). Geochemical and field parameter water quality detections during the current sampling event included: • TDS (10 wells); • chloride (10 wells); • iron Il (10 wells); and • sulfate (10 wells). Total metals detections during the current sampling event included: • total antimony (3 wells); • total barium (27 wells); • total beryllium (2 well); • total cadmium (1 well); • total chromium (13 wells); • total cobalt (10 wells); • total copper (6 wells); • total lead (3 wells); • total manganese (10 wells); • total nickel (23 wells); • total vanadium (5 wells); and • total zinc (14 wells). 2 of 5 1s 1M 1i Buncombe County Landfill -- Alexander, North Carolina April 2, 2021 Report of Groundwater Sampling and Analysis — 2,d Semi -Annual Event 2020 BLE Project No. J20-9378-22 Please refer to Tables 2 and 3 for a summary of which groundwater constituents exceeded North Carolina Groundwater Quality Standards (NC2L) maximum contaminant levels' (MCLs). Field parameters measured in the groundwater included pH, specific conductance, turbidity, and temperature. The field parameter of pH was below its NC2L standard in seventeen (17) wells. However, previous semi- annual reports for the subject site indicate that pH frequently varies between values both below and within the NC2L standards in the majority of the wells on site. No other field parameters were outside their NC2L standard limits for groundwater, if established. 4.2 Surface Water The results of the surface water field and laboratory analyses are summarized on Tables 4 and 5 and the laboratory analytical data is included in Appendix B. VOC detections during the current sampling event included: • acetone (1 locations); • chloromethane (1 location); • tetrahydrofuran (1 location); and • 1,4-Dioxane (5 locations). Total metal detections during the current sampling event included: • total antimony (3 locations); • total arsenic (2 locations); • total barium (8 locations); • total beryllium (1 location); • total cadmium (1 location); • total chromium (5 locations); • total cobalt (6 locations); • total copper (4 locations); • total lead (5 locations); • total nickel (7 locations); • total selenium (2 locations); • total vanadium (4 locations); and • total zinc (6 locations). Please refer to Table 4 and 5 for a summary of which surface water constituents exceeded their established North Carolina Surface Water Quality Standards (NC2B)2 standard limits. Field parameters measured in the surface water included dissolved oxygen, pH, redox potential, specific conductance, turbidity, and temperature. The field parameter of turbidity was above the NC213 limit at one surface water location (SW-7). ' North Carolina Department of Environmental Quality, Classifications of Water Quality Standards, Section 15A NCAC 2L.202, July 24, 2020. 2 North Carolina Department of Environmental Quality, Surface Waters and Wetlands Standards, Section 15A NCAC 02B workbook dated June 10, 2019. 3 of 5 1s 1M 1i Buncombe County Landfill -- Alexander, North Carolina April 2, 2021 Report of Groundwater Sampling and Analysis — 2,d Semi -Annual Event 2020 BLE Project No. J20-9378-22 None of the other sampled field parameters were outside their NC2B standard limits for surface water, if established. 4.3 Leak Detectors and Leachate Samples The results of the leak detector field and laboratory analyses are summarized on Tables 6 and 7 and the laboratory analytical data is included in Appendix B. VOC detections during the current sampling event included: • acetone (4 location); • benzene (3 locations); • chlorobenzene (1 location); • chloroethane (2 locations); • 1,4-dichlorobenzene (2 locations); • 1,1-dichloroethane (3 locations); • cis-DCE (4 locations); • toluene (1 location); • vinyl chloride (2 locations); and • total xylenes (1 location). Geochemical and field parameter water quality detections during the current sampling event included: • BOD (1 location); • COD (1 location); • sulfates (1 location); and • phosphates (1 location). Total metals detections during the current sampling event included: • total antimony (2 locations); • total arsenic (2 locations); • total barium (all locations); • total beryllium (2 locations); • total cadmium (1 location); • total chromium (3 locations); • total cobalt (all locations); • total copper (3 locations); • total lead (1 locations); • total nickel (7 locations); • total selenium (4 locations); • total thallium (1 location); • total vanadium (2 locations); and • total zinc (5 locations). 4 of 5 1s 1m 1i Buncombe County Landfill -- Alexander, North Carolina April 2, 2021 Report of Groundwater Sampling and Analysis — 2,d Semi -Annual Event 2020 BLE Project No. J20-9378-22 Please refer to Tables 6 and 7 for a summary of which leak detector and leachate constituents exceeded North Carolina Groundwater Quality Standards (NC2L) maximum contaminant levels' (MCLs). Field parameters measured in the groundwater included pH, specific conductance, turbidity, and temperature. The field parameter of pH was beneath its NC2L standard at seven (7) locations. It is our understanding that in the past, semi-annual reports by others have not included the pH of samples collected from these locations, therefore we only have two semi-annual reports prepared by BLE including pH and no historical basis to conclude whether these results are typical. No other field parameters were outside their NC2L standard limits for groundwater, if established. 5.0 CONCLUSIONS AND RECOMMENDATIONS Semi-annual assessment monitoring was performed during the 2nd semi-annual event of 2020 in general accordance with the approved WQMP. Detected constituents which exceed their respective groundwater and surface water standards are identified on the summary tables. We recommend that detections of vinyl chloride in MW-15 and MW-15D be verified by sampling to be conducted in April 2021 as part of the regularly scheduled sampling event. We do not recommend a change to the sampling program as the result of these recent detections. We recommend that semi-annual sampling continue in accordance the approved WQMP. 6.0 QUALIFICATIONS OF REPORT The activities and evaluative approaches used in this assessment are consistent with those normally employed in hydrogeological and environmental assessments of this type. Our evaluation of site conditions has been based on our understanding of the site and project information and the data provided to BLE. This report has been prepared on behalf of and exclusively for the use of Buncombe County, North Carolina. This report and the findings contained herein shall not, in whole or in part, be used or relied upon by any other party (excluding the DWM) without BLE's prior written consent. 7.0 CLOSING We appreciate the opportunity to be of service to Buncombe County, North Carolina. Please contact us at (864) 288-1265 if you have any questions or comments. 5 of 5 TABLES Table 1 Well Construction and Monitoring Well Data Buncombe County Landfill Alexander, North Carolina BLE Project Number J20-9378-22 Permit No. 1107-CDLF-1998 Permit No. 1107-MSWLF-1996 Monitoring Point MSW or C&D Northing' Easting' TOC Elevation (ft)' Ground Surface Elevation (ft)' Depth to GW (ft) October 26-30, 2020 Groundwater Elevation (ft) Well Depth (ft)' Screen Depth (below GS)' Waste Unit Monitored Installation Date' Geology Monitored' Well Status/Purpose Well Diameter (in)' MW-1 Facility 737,383.3 923,481.5 2021.22 2019.28 65.12 1956.10 76 61.0 - 76.0 Facility 1990's Saprolite/PWR Background 2.0 MW-11) Facility 737,371.0 923,468.7 2021.57 2019.97 66.81 1954.76 200 85.0 - 95.0 Facility 1990's Bedrock Background 2.0 MW-2 MSW 739,569.6 921,033.3 1920.86 1918.54 8.06 1912.80 20 5.0 - 20.0 Cell 1990's Saprolite/PWR Compliance 2.0 MW-2D MSW 739,565.7 921,027.7 1920.51 1918.63 8.65 1911.86 55 45.0 - 55.0 Cell 1990's Bedrock Compliance 2.0 MW-3R MSW 739,499.1 920,384.3 1973.18 1975.67 53.46 1919.72 55 45.0 - 55.0 Cell 7/28/2014 PWR Compliance 2.0 MW-4 MSW 739,263.0 920,192.1 1944.35 1942.48 13.13 1931.22 25 9.0 - 24.0 Cell 1011011996 Saprolite/PWR Compliance 2.0 MW-41) MSW 739,261.0 920,177.3 1944.64 1942.79 13.56 1931.08 55 45.0 - 55.0 Cell 1011111996 Bedrock Compliance 2.0 MW-5 MSW 739,111.5 920,246.7 1977.12 1975.39 33.81 1943.31 50 35.0 - 50.0 Cell 101911996 Saprolite/PWR Compliance 2.0 MW-5D MSW 739,103.6 920,242.3 1976.92 1975.31 35.60 1941.32 81 71.0 - 81.0 Cell 1011011996 Bedrock Compliance 2.0 MW-6 MSW 738,767.9 920,223.6 1987.34 1985.39 24.16 1963.18 50 35.0 - 50.0 Cell 101811996 Saprolite/PWR Compliance 2.0 MW-7 MSW 738,286.3 920,586.8 2022.83 2020.72 41.83 1981.00 61 42.0 - 61.0 Cell 101411996 Saprolite/PWR Compliance 2.0 MW-8 MSW 738,102.0 920,801.7 1962.06 1959.85 29.20 1932.86 70 55.0 - 70.0 Cell 1990's Saprolite/PWR Compliance 2.0 MW-8D MSW 738,116.7 920,812.0 1962.47 1960.57 27.84 1934.63 95 85.0 - 95.0 Cell 1990's Bedrock Compliance 2.0 MW-10 MSW 739,324.0 921,597.0 2010.54 2007.50 68.40 1942.14 73 58.0 - 73.0 Cell 3/6/2002 Saprolite/PWR Compliance 2.0 MW-10D MSW 739,324.0 921,590.8 2010.56 2007.50 69.08 1941.48 117 102.0 - 117.0 Cell 3/6/2002 Bedrock Compliance 2.0 MW-11 MSW 738,169.2 921,422.1 1966.71 1963.70 31.82 1934.89 50 35.0 - 50.0 Cell 3/6/2002 Bedrock Compliance 2.0 MW-11D MSW 738,154.0 921,406.0 1966.15 1963.20 32.73 1933.42 70 60.0 - 70.0 Cell 3/6/2002 Bedrock Compliance 2.0 MW-12 C&D 738,703.7 919,192.4 1947.39 1944.70 9.96 1937.43 17 7.0 - 17.0 Phases 1 - 5 6/25/2002 Saprolite/PWR/Bedrock Compliance 2.0 MW-12D C&D 739,489.5 921,966.6 1947.10 1944.30 9.14 1937.96 37 27.0 - 37.0 Phases 1 - 5 6/25/2002 Bedrock Compliance 2.0 MW-13 MSW 739,489.5 921,966.6 1953.92 1951.30 3.64 1950.28 16 6.0 - 16.0 Cell 612412005 Bedrock Compliance 2.0 MW-13D MSW 738,761.6 919,055.7 1953.82 1951.40 6.70 1947.12 44 39.0 - 44.0 Cell 6/23/2005 Bedrock Compliance 2.0 MW-14 C&D 738,782.5 919,037.1 1952.77 1949.80 28.37 1924.40 49 39.0 - 49.0 Phases 1 - 5 4/5/2006 Bedrock Compliance 2.0 MW-14D C&D 738,703.7 919,192.4 1953.76 1950.70 28.77 1924.99 88 78.0 - 88.0 Phases 1 - 5 4/6/2006 Bedrock Compliance 2.0 MW-15 C&D 739,143.4 919,829.3 1973.29 1 1970.21 21.23 1952.06 26 16.0 - 26.0 1 Phases 1 - 5 1 6/7/2012 Saprolite/PWR Compliance 2.0 MW-15D C&D 739,143.4 919,829.3 1973.51 1970.25 24.09 1949.42 43 33.0 - 43.0 Phases 1 - 5 6/7/2012 Bedrock Compliance 2.0 MW-17 Abandoned - September 14, 2020 MW-17D Abandoned - September 14, 2020 MW-17R C&D 738,579.7 918,662.0 1891.61 1888.96 14.55 1877.06 23.5 8.5 - 23.5 Phase 6 9/3/2020 Bedrock Compliance 2.0 MW-17DR C&D 738,569.7 918,659.3 1891.70 1889.14 13.13 1878.57 k 39 34.0 - 39.0 Phase 6 9/2/2020 Bedrock Compliance 2.0 - Data from Table 3, Well Construction, New Buncombe County Landfill, Buncombe County, North Carolina, provided by SCS Engineers. 2 - Based on visual observation of Sheet No 1 Groundwater and Methane Monitoring Well Locations by CDM Smith dated August 2014. Some well installation dates appear inconsistent with water level records and may not be accurate. Changes to some dates (italics) made based on water level records and dates from SHR and DHR documents by CDM. The top of casing and ground surface elevations for MW-3R are a probable error (reversed) based on April 2016 water levels in the SCS Engineers report. The top of casing and ground surface elevations for MW-14 and MW-14D do not match those in the SHR and DHR documents by CDM. The well construction and survey data for MW-17R and MW-17DR are from a report by SCS dated October 13, 2020 TOC - Top of Casing. GS - Ground Surface. All depth measurments in feet -- All elevations in feet above an arbitrary site datum. 9378-22 GW Tables (Completion, water levels, detections).xlsx Prepared by: RLB T1 (10-30-20) MW Points Checked by: IAI Table 2 Groundwater VOCs Buncombe County Landfill Alexander, North Carolina BLE Project Number J20-9378-22 Permit No. 1107-CDLF-1998 Permit No. 1107-MSWLF-1996 Sampled by Pace Analytical Services, LLC. October 28-30, 2020 TEST UNITS MRL MDL MCL MW-1 MW-11) MW-2 MW-21) MW-3R MW-4 MW-41) MW-5 MW-51) MW-6 MW-7 MW-8 MW-81) MW-10 MW-10D MW-11 MW-11D MW-12 MW-12D MW-13 MW-13D MW-14 MW-14D MW-15 MW-15D MW-17 MW-17D EQUIP. BLANK Acetone µg/I 20.0 5.0 6,000 <5.0 <5.0 15.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 5.2 J <5.0 <5.0 <5.0 <5.0 5.9 J <5.0 5.6 J <5.0 <5.0 <5.0 <5.0 5.8 J <5.0 <5.0 <5.0 Acrylonitrile µg/I 20.0 0.8 NE <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 Benzene µg/I 1.0 0.4 1.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromochloromethane µg/l 1.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromodichloromethane µg/l 1.0 0.4 0.6 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromoform µg/l 1.0 0.4 4.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Carbon Disulfide µ9/1 1.0 0.4 700 1 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromomethane (Methylbromtde) µg/I 2.0 0.4 10.0 (i) <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Carbon tetrachloride µg/I 1.0 0.4 0.3 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chlorobenzene (mono) µg/I 1.0 0.4 50.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloroethane µg/1 2.0 0.4 3,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloroform µg/I 1.0 0.4 70.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloromethane (Methylchloride) µg/1 1.0 0.5 3.0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 Dibromochloromedume µg/l 1.0 0.4 0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dibromo-3-chloropropane; DBCP µ9/1 1.0 0.4 0.04 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dibromoethane; Ethylene dibromide µg/I 1.0 0.4 0.02 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Dibromomethane µg/I 1.0 0.4 70.0 (i) 1 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichlorobenzene µg/I 1.0 0.4 20.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,4-Dichlorobenzene µg/1 1.0 0.4 6.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,4-Dichloro-2-butene µg/l 2.0 0.5 NE <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <05 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 1,1-Dichloroethane µg/1 1.0 0.4 6.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 0.60 J <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1 <0.4 1,2-Dichloroethane µg/l 1.0 0.4 0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 0.46 J <0.4 <0.4 <0.4 1,1-Dichloroethene (-ethylene) µg/I 1.0 0.4 350.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 cis-1,2-Dichloroethene (-ethylene) µg/I 1.0 0.4 70.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,2-Dichloroethene (-ylene) µ9/1 1.0 0.4 100 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichloropropane µg/I 1.0 0.4 0.6 1 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0,4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 cis-1,3-Dichloropropene (-propylene) µg/l 1.0 0.4 0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,3-Dichloropropene (-propylene) µg/l 1.0 0.4 0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Ethylbenzene µg/l 1.0 0.4 600 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 2-Hexanone µg/l 10.0 2.0 40.0 (i) <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 1 <2.0 Iodomethane µg/I 5.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Dichloromethane (Methylene chloride) µg/l 1.0 0.4 5.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 0.45 J <0.4 <0.4 <0.4 2-Butanone (Methyl ethyl ketone) µg/I 10.0 2.0 4000 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 2.5 J <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 4-Methyl-2-Pentanone µg/I 10.0 2.0 NE <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 1 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Styrene µ9/1 1.0 0.4 70.0 1 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1,1,2-Tetrachloroethane µg/1 1.0 0.4 1.0(i) <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1, 1,2,2-Tetrachloroethane µg/I 1.0 0.4 0.2 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Tetrachloroethene (-ethylene) µg/1 1.0 0.4 0.7 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Toluene µ 1 1.0 0.4 600 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1,1-Trichloroethane µg/1 1.0 0.4 200 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1,2-Trichloroethane µg/I 1.0 0.4 0.6 i <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1 <0.4 <0.4 <0.4 <0.4 <0.4 Trichloroethee (-ethylene) µg/I 1.0 0.4 3.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Trichlorofluoromethane µg/I 1.0 0.4 2,000 1 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2,3-Trichloropropane µg/1 1.0 0.4 0.005 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Vinyl acetate µg/l 5.0 1.2 88.0 (i) <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 Vinyl chloride µg/1 1.0 0.4 0.03 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 0.47 J .2 <0.4 <0.4 <0.4 Total Xylenes µ 1 1.0 0.4 500 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Tetrahydrofuran µg/1 5.0 1.0 NE <1.0 <1.0 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT 5.1 <1.0 NT NT <1.0 <1.0 <1.0 2.9 J <1.0 <1.0 <1.0 1,4-dioxane 1 3.0 1.0 3.0 NT NT NT NT NT <1.0 <1.0 NT NT NT NT NT NT <1.0 <1.0 NT NT 1.3 J NT NT NT NT 6.7 30 <1.0 <1.0 <1.0 Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable to Groundwaters of North Carolina, Section 15A NCAC 2L .0202. Dated April 1, 2013 2. (i) = Interim Maximum Allowable Concentrations (IMACs). Updated April 6, 2018 3. Shaded cells indicate exceedances of IMACs 4. Shaded cells indicated exceedances of MCLs 5. NE = Not Established; North Carolina has not established a MCL 6. MRL = Method Reporting Limit 7. MDL = Minimum Detection Limit 8. NT = Not Tested 9. "J"-flagged data (i.e, values estimated between the MDL and the MRL) are presented on this spreadsheet. 9378-22 GW Tables (Completion, water levels, detections).xlsx Prepared by: RLB T2 (10-30-20) VOC Checked by: 1AI Table 3 Groundwater Field Parameters, Geochemical Parameters, and Total Metals Buncombe County Landfill Alexander, North Carolina BLE Project Number J20-9378-22 Permit No. 1107-CDLF-1998 Permit No. 1107-MSWLF-1996 Sampled by Pace Analytical Services, LLC. October 26-30, 2020 TEST UNITS MRL MDL MCL MW-1 MW-ID MW-2 MW-2D MW-311 MW-4 MW-4D MW-5 MW-5D MW-6 MW-7 MW-8 MW-81) MW-10 MW-IOD MW-11 MW-11D MW-12 MW-12D MW-13 MW-13D MW-14 MW-14D MW-15 MW-15D MW-17R MW-17DR EQUIP. BLANK pH S.U. <6.5; >8.5 6.307.5il 6.50 6.10 6.20 6.70 6.20 6.20 5.90 IL 6.40 6.40 6.30 6.10 6.50 6.60 6.70 6.30 6.80IL 6.40 6.30 6.20 7.30 6.10 5.90 7.10 7.30 NT Specific Conductance µmhos/cm NE 177.1 262.1 500.3 270.9 78.2 237.6 315.8 213.8 215.3 131.6 659.0 391.5 433.9 311.0 350.7 431.7 450.5 1141.0 427.0 399.3 423.2 176.9 328.3 621.0 1025.0 261.9 271.7 NT Temperature °C NE 12.1 12.5 14.1 13.7 20.8 19.2 17.1 18.8 17.7 19.4 18.3 21.9 21.1 13.7 13.3 10.6 9.9 27.1 28.4 19.6 19.3 18.3 18.1 21.4 25.2 13 11.9 NT Turbidity NTU NE 9.6 6.6 9.9 0.8 5.4 0.6 1.7 8 5.1 0.2 9.8 5.4 3 1.1 6.6 9.9 5.3 3.1 0.4 5.5 0.7 9.5 1.2 5.8 1 0.6 2.2 NT Alkalinity mg/l 20.0 20.0 NE 56 81 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT 290 160 NT NT 65 140 280 300 93 120 NT Total Dissolved Solids (TDS) mg/l 25.0 25.0 500 160 200 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT 870 280 NT NT 170 1 220 380 1,100 200 200 NT Iron H (Fez) µg/1 50.0 13.0 300 260 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT 370 72 NT NT 61 66,000 1,600 130 340 NT Sulfate mg/l 1.0 0.2 250 16.0 39 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT 280 43 NT NT 18 26 24 120 1 35 22 1 NT Chloride mg/l 1.0 0.2 250 5.8 2.2 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT 43.0 9.3 NT NT 2.2 3.7 20.0 78.0 3.1 3.5 NT Total Antimony (Sb) µg/l 2.0 0.5 1.0 (i) <0.5 0.60 J <0.5 <0.5 <0.5 <0.5 <0,5 <0.5 <0.5 0.69 J <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 1.1 J <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0,5 <0.5 <0.5 <0.5 Total Arsenic (As) µg/l 2.0 1.3 10.0 <1.3 <1.3 <1.3 <1.3 <13 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <13 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <13 <1.3 <1.3 <1.3 <13 <1.3 <1.3 <1.3 <1.3 <1.3 Total Barium (Ba) µg/l 5.0 1.3 700 130 29 240 100 46 72 44 120 69 48 160 140 170 130 51 110 45 110 38 190 240 47 6.7 210 140 57 59 <1.3 Total Beryllium (Be) µg/l 0.4 0.15 4.0 (i) <0.2 1 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.24 J <0.2 <0.2 <0.2 <0.2 <0,2 <0.2 <0.2 <0.2 0.19 J <0.2 <0.2 <0.2 Total Cadmium (Cd) µg/l 0.5 0.13 2.0 <0.1 I <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 I <0.1 0.17 J <0.1 <0.1 <0,1 <0.1 I <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 Total Chromium (Cr) µg/l 5.0 1.3 10.0 5.3 <1.3 <1.3 1 <1.3 4.9 J 5.6 <1.3 2.1 J <1.3 <1.3 5.7 4.4 J <1.3 2.0 J 2.8 J 25 1.5 J 2.3 J <1.3 <1.3 <1.3 1.4 J <1.3 4.3 J <1.3 <1.3 <1.3 <1.3 Total Cobalt (Co) µg/l 5.0 1.3 1.0 (i) <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 4.0 J 1.9 J <1.3 r 40 <1.3 <1.3 4.3 2.7 <1.3 <1.3 <1.3 Total Copper (Cu) µg/l 5.0 1.3 1000 <1.3 <1.3 <1.3 <1.3 <1.3 1.7 J <1.3 <1.3 <1.3 <1.3 1.4 J <1.3 <1.3 <1.3 1.4 J 5.2 1.3 J 5.2 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 Total Lead (Pb) µg/l 1.0 0.25 15.0 <0.3 0.25 J <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 3.9 0.26 J <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 Total Manganese (Mn) Total Mercury (Hg) µg/l µg/l 5.0 0.20 1.3 0.091 50.0 1.0 9.8 <0.1 7.2 <0.1 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT Im 0 <0.1 <0.1 NT NT NT NT 3.7 J <0.1 18 <0.1 L. 11,000 <0.1 1,400 <0.1 150 <0.1 77 <0.1 NT NT Total Nickel (NI) µg/l 5.0 1.3 100.0 3.1 J 3.0 J 23 <1.3 3.8 J 9.5 <1.3 3.5 J 3.8 J 1.7 J 17 4.4 J 4.0 J 9.1 19 38 12 40 2.6 J 9.4 9.2 2.7 J <1.3 11 29 9.6 <1.3 <1.3 Total Selenium (Se) µg/l 6.0 1.3 20.0 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 Total Silver (Ag) µg/l 1.0 0.3 20.0 <0.3 <0.3 < . 1 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 Total Thallium (Tl) µg/l 0.5 0.2 0.2 (i) <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 Total Vanadium (V) µg/l 5.0 2.5 ) 3.6 J <2.5 <2.5 <2.5 3.7 J <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 Total Zinc (Zn) µ l 10.0 2.5 1000.0 4.5 J 3.6 J 10 <2.5 <2.5 1 <2.5 <2.5 3.6 J 1 3.6 J <2.5 4.2 J 4.8 J <2.5 7.7 J 3.8 J 14 14 5.9 J <2.5 3.8 J <2.5 <2.5 <2.5 4.8 J <2.5 <2.5 <2.5 <2.5 Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable to Groundwaters of North Carolina, Section 15A NCAC 2L .0202. Dated April 1, 2013 2. (i) = Interim Maximum Allowable Concentrations (IMACs). Updated April 6, 2018 . 3. Shaded cells indicate exceedances of IMACs 5. NE = Not Established; North Carolina has not established a MCL 6. MRL = Method Reporting Limit 7. MDL = Minimum Detection Limit 8. NT = Not Tested 9378-22 GW Tables (Completion, water levels, detections).xlsx Prepared by: RLB T3 (10-30-20) Metals Checked by: IAI Table 4 Surface Water VOCs Buncombe County Landfill Alexander, North Carolina BLE Project Number J20-9378-22 Permit No.1107-CDLF-1998 Permit No. 1107-MSWLF-1996 Sampled by Pace Analytical Services, LLC. October 27, 2020 TEST UNITS MRL MDL NC2B SW-1 SW-2 SW-3 SW4 SW-5 SW-6 SW-7 SW-8 Acetone µg/l 20.0 5.0 2,000 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 39 <5.0 Acrylonitrile 99/1 20.0 0.8 420.0 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 Benzene µg/l 1.0 0.4 51.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromochloromethane µg/l 1.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromodichloromethane µg/l 1.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromoform µg/l LO 0.4 120 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Carbon Disulfide µ LO 0.4 100 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromomethane (Methylbromide) µg/l 2.0 0.4 0.04 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Carbon tetrachloride µg/l 1.0 0.4 1.6 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chlorobenzene (mono) µg/l LO 0.4 800 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloroethane µg/l 2.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloroform µg/l 1.0 0.4 2,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloromethane (Methylchloride) µg/l 1.0 0.5 96 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 0.75 J <0.5 Dibromochloromethane µg/l 1.0 0.4 21 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dibromo-3-chloropropane; DBCP µg/l LO 0.4 0.13 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dibromoethane; Ethylene dibromide µg/l 1.0 0.4 0.1 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Dibromomethane µg/l 1.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichlorobenzene 99/1 1.0 0.4 3,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,4-Dichlorobenzene µgp LO 0.4 900 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,4-Dichloro-2butene 99/1 2.0 0.5 NE <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 1,1-Dichloroethane µg/l 1.0 0.4 100 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichloroethane 99/1 1.0 0.4 650 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1-Dichloroethene(-ethylene) 99/1 LO 0.4 20,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 cis-1,2-Dichlomethene (-ethylene) µg/l LO 0.4 720 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,2-Dichloroethene (-ylene) µg/l 1.0 0.4 4,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichloropropane µg/l LO 0.4 31.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 cis-1,3-Dichloropropene (-propylene) µg/l LO 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,3-Dichloropropene (-propylene) µg/l 1.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Ethylbenzene µg/l 1.0 0.4 97 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 2-Hexanone 99/1 10.0 2.0 NE <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Iodomethane 99/1 5.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Dichloromethane (Methylene chloride) µ LO 0.4 1,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 2-Butanone (Methyl ethyl ketone) µg/l 10.0 2.0 26,000 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 4-Methyl-2-Pentanone 49/1 10.0 2.0 26000 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Styrene µg/l LO 0.41 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1,1,2-Tetrachloroethane 99/1 LO 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1, 1,2,2-Tetrachloroethane 99/1 1.0 0.4 4.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Tetrachloroethene (-ethylene) µg/l 1.0 0.4 3.3 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Toluene 99/1 1.0 0.4 11.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1,1-Trichloroethane µg/l LO 0.4 200,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1, 1,2-Trichlomethane 99/1 1.0 0.4 8.9 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Trichloroethene (-ethylene) µg/l 1.0 0.4 30.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Trichloroflumomethane 99/1 1.0 0.4 67,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2,3-Trichloropropane µg/l LO 0.4 0.001 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Vinyl acetate µg/l 5.0 1.2 NE <L2 <L2 <L2 <L2 <L2 <L2 <L2 <1.2 Vinyl chloride 99/1 1.0 0.4 2.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Total Xylenes µg/l 1.0 0.4 670 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Tetrahydrofuran 99/1 5.0 1.0 110,000 NT NT NT NT 1.3 J <1.0 NT <1.0 1,4-dioxane 1 3.0 1.0 80.0 <1.0 <1.0 5.7 <1.0 7.1 8.7 12 1.4 J Notes: 1. NC2B = North Carolina Surface Water Standards for Class C freshwater under Title 15A Subchapter 2B. 4. MRL = Method Reporting Limit per NC DWR Surface Water Quality Standards, Criteria, & In -Stream Target Values (Workbook Dated 6-10-2019) 5. MDL = Minimum Detection Limit 2. NE = Not Established; North Carolina has not established a MCL 6. NT - Not Tested 3. "J"-flagged data (i.e., values estimated between the MDL and the MRL) are presented on this spreadsheet. 7. DNA = Data Not Available 9378-22 SW Tables.xlsx Prepared by: RLB T4 SW VOC (10-27-20) Checked by: IAI Table 5 Surface Water Field Parameters and Total Metals Buncombe County Landfill Alexander, North Carolina BLE Project Number J20-9378-22 Permit No. 1107-CDLF-1998 Permit No. 1107-MSWLF-1996 Sampled by Pace Analytical Services, LLC. October 27, 2020. TEST UNITS MRL MDL NC2B SW-1 SW-2 SW-3 SW4 SW-5 SW-6 SW-7 SW-8 pH s.u. (on -site) <6.0; >9.0 6.52 7.5 7.77 7.82 8.08 7.69 8.15 7.5 Specific Conductance µmhos/cm (on -site) NE 133.7 163.3 619 308.7 1,426 517.9 488 302 Temperature °C (on -site) 29.0 15.6 15.2 23.3 17.5 16.5 15.7 16.2 15.6 Turbidity NTU (on -site) 50.0 16.34 11.95 4.51 46.27 5.32 3.42 125.1 39.97 Hardness mg/1 10 2.0 NE NT NT NT NT NT NT NT NT Total Antimony (Sb) µg/1 2.0 0.5 5,300 <0.5 0.62 J <0.5 1.2 J <0.5 <0.5 3.1 <0.5 Total Arsenic (As) µg/I 2.0 1.3 10 <1.3 <1.3 <1.3 <1.3 <1.3 4.3 17 2.0 Total Barium (Ba) µg/1 5.0 1.3 21,000 100 58 150 120 83 97 320 120 Total Beryllium (Be) µg/I 0.4 0.15 65 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.84 <0.2 Total Cadmium (Cd) µg/1 0.5 0.13 0.82 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.24 J <0.1 Total Chromium (Cr) µg/1 5.0 1.3 183.07 <1.3 <1.3 <1.3 4.3 J 5.1 2.1 J 96 6.6 Total Cobalt (Co) µg/l 5.0 1.3 16 3.7 J <1.3 41 1.8 J 3.1 J <1.3 61 2.6 J Total Copper (Cu) µg/1 5.0 1.3 3.64 <1.3 <1.3 <1.3 3.9 J <1.3 1.5 J 35 AN 4.2 J Total Lead (Pb) µg/I 1.0 0.25 14 0.34 J <0.3 <0.3 0.86 J <0.3 0.33 J 5.1 0.76 J Total Nickel (Ni) µg/l 5.0 1.3 144.92 <1.3 1.4 J 13 5.0 9.2 3.4 J 94 6.3 Total Selenium (Se) µg/1 5.0 1.3 5.0 <1.3 <1.3 <1.3 <1.3 1.4 J <1.3 4.7 J <1.3 Total Silver (Ag) µg/I 1.0 0.25 m 0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 Total Thallium (Tl) µg/l 0.5 0.15 NE <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 Total Vanadium (V) µg/1 5.0 2.5 NE <2.5 <2.5 <2.5 5.8 <2.5 3.3 J 48 8.9 Total Zinc (Zn) 10 2.5 36 2.5 J <2.5 5.6 J 9.1 J <2.5 3.5 J 150 8.7 J Notes: 1. NC213 =North Carolina Surface Water Standards for Class C freshwater under Title 15A Subchapter 213. per NC DWR Surface Water Quality Standards, Criteria, & In -Stream Target Values (Workbook Dated 6-10-2019) An assumed hardness of 25 mg/L was utilized to calculate a acute standard for metals highlighted in green. 2. NE - Not Established; North Carolina has not established a standard 3. "J"-flagged data (i.e., values estimated between the MDL and the MRL) are presented on this spreadsheet. 4. Shaded cells indicated exceedances of MCLs 9378-22 SW Tables.xlsx T5 SW Metals (10-27-20) 5. MRL = Method Reporting Limit 6. MDL = Minimum Detection Limit 7. NT = Not Tested 8. DNA = Data Not Available Prepared by: RLB Checked by: IAI Table 6 Leak Detector and Leachate VOCs Buncombe County Landfill Alexander, North Carolina BLE Project Number J20-9378-22 Permit No. 1107-CDLF-1998 Permit No. 1107-MSWLF-1996 Sampled by Pace Analytical Services, LLC. October 27-30, 2020. TEST UNITS MRL MDL MCL LD-1 LD-2 LD-3 LD-4 LD-5 LD-6 Leachate LD Leachate Pond Acetone µg/1 25.0 5.0 6,000 6.8 J 5.9 J 5.0 J <5.0 <5.0 <5.0 6.3 J 15.0 Acrylonitrile µ9/1 10.0 0.8 NE 10.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 Benzene µo 1.0 0.4 1.0 1.6 10.4 0.80 J 2.1 10.4 10.4 10.4 10.4 Bremochloromethane µg/I 1.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromodichlommethane 99/1 1.0 0.4 0.6 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 Bromofor n µg/I 1.0 0.4 4.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Carbon Disulfide µg/I 2.0 0.4 700 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 Bromomethane (Medrylbromide) µg/1 2.0 0.4 10.0 (1) <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Carbon tetrachloride µgfl 1.0 0.4 0.3 10.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chlorobenzene (mono) 99/1 1.0 0.4 50.0 0.46 J 10.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloroethane µgfl 1.0 0.4 3,000 0.83 J <0.4 0.47 J <0.4 <0.4 <0.4 <0.4 <0.4 Chloroform µg/1 1.0 0.4 70.0 10.4 10.4 10.4 10.4 10.4 <0.4 <0.4 <0.4 Chloromethane (Methylchlorlde) µgfl 1.0 0.5 3.0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 Dibromochloromethane µ 1.0 0.4 NE 10.4 10.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dibromo-3-chloropropane; DBCP µg/I 2.0 0.4 0.04 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dibromoethane; Ethylene dibromide µ 1.0 0.4 0.02 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Dibromomethane µg/I 1.0 0.4 70.0(1) <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichlorobenzene µ 1.0 0.4 20.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,4-Dlchlorobenzene 99/1 1.0 0.4 6.0 0.93 J <0.4 0.67 J <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,4-Dichlom-2butene µ 1.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 IJ-Dichloroethane 99/1 1.0 0.5 6.0 1.2 1.1 <0.5 0.60 J <0.5 <0.5 <0.5 <0.5 1,2-Dichloroethane 99/1 1.0 0.4 0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1-Dichloroethene(-ethylene) 99/1 1.0 0.4 7.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 10.4 cis-1,2-Dichloroethene (-ethylene) 99/1 1.0 0.4 70.0 0.90 J 0.57 J 1.5 <0.4 0.40 J <0.4 <0.4 <0.4 trans-1,2-Dichloroethene (-ylene) 99/1 1.0 0.4 100 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichlompropane 99/1 1.0 0.4 0.6 10.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 cis-1,3-Dichloropropene (-propylene) 99/1 1.0 0.4 0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,3-Dichlompropene (-propylene) 99/1 1.0 0.4 0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Ethylbenzene µ9/1 1.0 0.4 600 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 2-I1exanone µo 5.0 2.0 40.0 (i) 12.0 12.0 12.0 12.0 12.0 12.0 12.0 12.0 lodomethane µg1l 5.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Dichloromethane (Methylene chloride) 99/1 2.0 0.4 5.0 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 2-1hutanone (Methyl ethyl ketone) 99/1 5.0 2.0 4000 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 4-Methyl-2-Pentanone µgfl 5.0 2.0 NE 12.0 12.0 12.0 12.0 12.0 12.0 12.0 12.0 Styrene µo 1.0 0.4 70.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1,1,2-Tetrachlomethane 99/1 1.0 0.4 1.0 (i) 10.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1,2,2-Tetrachloroethane 99/1 1.0 0.4 NE 10.4 10.4 10.4 10.4 <0.4 <0.4 <0.4 <0.4 Tetrachloroethene (-ethylene) 99/1 1.0 0.4 0.7 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Toluene µo 1.0 0.4 600 10.4 10.4 <0.4 0.93 J <0.4 <0.4 <0.4 <0.4 1,1,1-Trichloroe0ume µg/1 1.0 0.4 200 <0.4 <0.4 <0.4 <0.4 <0.4 10.4 <0.4 <0.4 1,1,2-Trichloroethane µ 1.0 0.4 0.6 (i) <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Trlchlomethene (-ethylene) 99/1 1.0 0.4 3.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Trichloroflumomethane µ 1.0 0.4 2,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2,3-Trichloropropane 99/1 1.0 0.4 0.005 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Vinyl acetate µ 2.0 1.2 88.0 i <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 Vinyl chloride 99/1 1.0 0.4 0.03 <0.4 <0.4 3.2 1.2 <0.4 <0.4 <0.4 <0.4 Total Xylenes 99/1 2.0 0.4 500 <0.4 <0.4 <0.4 0.58 J <0.4 <0.4 <0.4 <0.4 1,4-dioxane 2.0 1 1.0 1 3.0 1 NT I NT I NT I NT I <1.0 I NT I NT I NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable to Groundwaters of North Carolina, Section 15A NCAC 2L .0202. Updated July 24, 2020 2. (i) = Interim Maximum Allowable Concentrations (IMACs). Updated April 6, 2018 3. Shaded cells indicate exceedances of IMACs 4. Shaded cells indicated exceedances of MCLs 5. NE = Not Established; North Carolina has not established a MC: 6. MRL = Method Reporting Limit 7. MDL= Minimum Detection Limit 8. NT = Not Tested 9. "J"-flagged data (i.e., values estimated between the MDL and the MRL) are presented on this spreadsheet. 9378-22 Leachate Table -lax Prepared by: RLB T6 LD VOC (10-30-20) Checked by: IAI Table 7 Leak Detector and Leachate Field Parameters and Total Metals Buncombe County Landfill Alexander, North Carolina BLE Project Number J20-9378-22 Permit No. 1107-CDLF-1998 Permit No. 1107-MSWLF-1996 Sampled by Pace Analytical Services, LLC. October 27-30, 2020 TEST UNITS MRL MDL MCL LD-1 LD-2 LD-3 LD-4 LD-5 LD-6 Leachate LD Leachate Pond pH s.u. units (on -site) 16.5; 18.5 6.3 6.0 6.01 6.38 6.17 6.21 4.8 8.1 Specific Conductance µmhos/cm (on -site) NE 1473 455.6 691 3,765 772 557.4 295.3 6,559 Temperature °C (on -site) NE 15.1 15.6 18.3 17.9 18.7 18.5 14.6 14.5 Turbidity NTU (on -site) NE 12.4 23.3 21.72 8.62 66.29 20.68 9.4 53 Biologic Oxygen Demand (BOD) m9/1 2.0 NE NT NT NT NT NT NT NT 75 Chemical Oxygen Demand (COD) m l 80.0 80.0 NE NT NT NT NT NT NT NT 870 Nitrates mg/l 0.04 10 NT NT NT NT NT NT NT 10.04 Sulfates m l 1.0 250 NT NT NT NT NT NT NT NT Phosphates mg/l 0.05 0.02 NE NT NT NT NT NT NT NT 1.6 Total Antimony (Sb) 99/1 2.0 0.5 1.0 (i) 12.0 <2.0 <2.0 1.2 J <2.0 <2.0 <2.0 9.4 J Total Arsenic (As) 99/1 2.0 1.3 10.0 <2.0 <2.0 <2.0 2.8 <2.0 <2.0 <2.0 30 Total Barium (Ba) 99/1 5.0 1.3 700 1 530 190 220 380 160 410 37.0 510 Total Beryllium (Be) 99/1 0.4 0.15 4.0 (i) <0.4 <0.4 <0.4 0.18 J <0.4 <0.4 0.16 J <0.4 Total Cadmium (Cd) 99/1 0.5 0.13 2.0 <0.5 <0.5 <0.5 0.21 J <0.5 <0.5 <0.5 <0.5 Total Chromium (Cr) µ9/1 5.0 1.3 10.0 <5.0 2.4 J <5.0 180 <5.0 <5.0 1 <5.0 69 Total Cobalt (Co) µo 5.0 1.3 1.0 (i) 280 94 2.3 J 48 87 93 22 20 J Total Copper (Cu) µ9/1 5.0 1.3 1000 <5.0 1.9 J <5.0 57 <5.0 15.0 9.4 <5.0 Total Lead (Ph) 99/1 5.0 0.25 15.0 15.0 <5.0 <5.0 0.55 J <5.0 <5.0 15.0 <5.0 Total Mercury (Hg) µ9/1 NT NT 1.0 NT NT NT NT NT NT NT NT Total Nickel (No µgll 5.0 1.3 100.0 42.0 24.0 <5.0 97.0 25.0 3.9 J 190 91.0 Total Selenium (Se) 99/1 10.0 1.3 20.0 1.5 J <10.0 <10.0 1.9 J <10.0 <10.0 1.3 J 8.7 J Total Silver (Ag) 99/1 1.0 0.25 20.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Total Thallium (n) 99/1 0.5 0.15 0.2 (i) 0.21 J <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 Total Vanadium(V) µgil 5.0 2.5 0.3 (1) <5.0 <5.0 <5.0 5.6 <5.0 <5.0 <5.0 34.0 Total Zinc Zn 10.0 1 2.5 1 1000.0 1 3.4 J 1 6.5 J I <10.0 1 22 1 2.7 J I <10.0 91 <10.0 Notes: 1. MCL - Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable to Groundwaters of North Carolina, Section 15A NCAC 2L .0202. Updated July 24, 2020 2. (i) - Interim Maximum Allowable Concentrations (IMACs). Updated April 6, 2018 3. Shaded cells indicate exceedances of IMACs 4. Shaded cells indicated exceedances of MCLs 5. NE = Not Established; North Carolina has not established a MCL 6. MRL = Method Reporting Limit 7. MDL = Minimum Detection Limit S. NT -Not Tested 9. "J"-flagged data (i.e., values estimated between the MDL and the MRL) are presented on this spreadsheet. 9378-22 Leachate Tables.xlsx Prepared by: RLB T7 LD Metals (10-30-20) Checked by: IAI FIGURES 70 /( 0 T vy. 1750 Z \<aa ti z-- 141 D O J 01 D a 1 gg '9A ti ,s�J " 0 R � 251 y RTi , RD zoG o ° Alexander 2000 1000 0 2000 4000 APPROXIMATE SCALE IN FEET DRAWN: DATE: KLW 10-19-20 IM I BUNNELL � LAMMONS CHECKED: AWA CAD: BCLF22-SLM ENGINEERING 6004 Ponders Court, Greenville, SC 29615 APPROVED: AWA JOB NO: J20-9378-22 Phone: (864) 288-1265 Fax: (864] 288-4430 REFERENCE: USGS TOPOGRAPHIC MAP, 7.5 MINUTE SERIES, LEICESTER AND WEAVERVILLE, N.C. QUADRANGLES, PHOTOREMSED 2017 AND PHOTOREMSED 2017. SITE LOCATION MAP I BUNCOMBE COUNTY LANDFILL ALEXANDER, NORTH CAROLINA FIGURE ♦1 N N � CONVE IE CE CENTER LANDFILL OFFICE BUILDING � F lot OO N Q, - -BL_ 1001, *0' L ral ZO-" it _ .L 16_ _ _ r WELL �SW 2 / _HOUSE = Mw-2 SW-6,- SCALE HOUSE MW-2D* MW-3R �1919,72 1911,86 i PANTHER BRANCH (� FLOW) � ���/ 1 � ,� 1942�14�MW-10D� MW-10 �#-64� � �� _ I /-1931,22_ 1941.48 ',—�icxxx>a � LU ��� / / 1 1 � MW-4 4. I ---- /'�- JkSW-8 1931.08\! 1941,32 ♦i \ -__' 1 - - I M W- 5 D -- ----- -- \___ 1 I 1952,06 1 � � \ / INACTIVE MW-15 \ MW-5,1943,31 \ _ \ / G11� SW-31 CELL 3 — ' INACTIVE �,k MW-15D� _ 1 �_ \ - 1 CELL 4 19 4 9, 4 2 -- I ..INACTIVE ................ I CELL 1 -1,• �\ � I 1 I - \ / 1924.40 SW 5 \ �1 I \\ 1 I CD CD ao 0o I CD c ao I I cnCO Go I r cn oII MW -17IR CD M-12R�(1877.06) MW-17DR IIj ' CD 04 MW-17 MW-17D ® !r (AB) (AB) 1 V ' M\, � \t11924.99 mw-l\ \ I 4D� el MW�-12 1937.43 -- / MW-12D) 1937.96 I BUNCOMBE COUNTY EMERGENCY SERVICES RADIO TOWER EXISTING PHASE 1-5 I C&D AREA \ ` PHASE PERMITTED6 \' \_'\'i0000// C&D AREA 00 4. �'2 g0� 10-101* 10000, 90AWA MW-13 1950.28 -6A M W - 6 I -- ------------------------ i - - - - - - - 1963,18 \ INACTIVE .01 o 1v i CELL 2 I INACTIVE CELL 5 �. �.. +\9�p 1 MW-7 LD_L,-— 11 LLD 0 �i 1981.00 / - M-2 /-LACHATE ,/ i_D '0M W - 8 tom, 1932.86 S ' MW-11 BMW / MW-8D 1934.89� 193: 1934.63 EMPLOYEE E LEACHATE TRAILER E POND -� o SW-4 1 \/ ,9,0 ?,20 7950 \ 1 3°\ 1 > ti °4) 1 0 2050 79,0 1 2oso '89 0 1 2030 2p,a 1 ,99° 1 1810 — J/ 80 lmlit, �TOW �a�o ro too FRENCH BROAD RIVER ♦� MW-13D)K 1947.12 19S0 MW-16��MW-16D NOT NOT PRESENT PRESENT V -------�-- ----------------------�` PERMITTED FUTURE CELL 7 � i ACTIVE �� CELL 6 1956,10 1960 MW-1 MW-1D* 1954.76 �1950 LEGEND —1980 TOPOGRAPHIC CONTOUR — — — — — WASTE UNIT BOUNDARY FACILITY BOUNDARY MW-10 EXISTING GROUNDWATER MONITORING WELL �MW— 16 PERMITTED FUTURE GROUNDWATER MONITORING WELL EXISTING SURFACE WATER SW-2 MONITORING LOCATION * LD-1 LEAK DETECTOR * LD-7 PERMITTED FUTURE LEAK DETECTOR 0 M-3 EXISTING LANDFILL GAS MONITORING WELL \ O +M-5 PERMITTED FUTURE LANDFILL GAS MONITORING WE REFERENCES: 1) SHEET NO. 1 GROUNDWATER AND METHANE MONITORING WELL EXISTING STRUCTURE MONITORED FOR LOCATIONS, CDM SMITH, PROJECT NO. 6447-105257. FILE: SITEMAP ■ LANDFILL GAS 2014.DWG. M-8 2) SURFACE WATER LOCATIONS FROM SHEET NO. 1 GROUNDWATER 1950 POTENTIOMETRIC ELEVATION CONTOUR (FEET AND METHANE MONITORING WELL LOCATION MAP, CDM SMITH, MSL) CONTOUR INTERVAL = 10 FEET NOVEMBER 2012 PROJECT NO. 6447-93318. FILE: SITEMAP. DWG. 3) PHASE 6 C&D BOUNDARY PROVIDED BY MCGILL. _ GROUNDWATER FLOW DIRECTION 4) SHEET NO. OP-1 EXISTING CONDITIONS, CDM SMITH, PROJECT NO. 6447-97693. FILE: OP-1.DWG. * DEEP WELL NOT USED FOR CONTOURING PURPOSES 5) FIGURE NO. 3-1 WATER QUALITY MONITORING PLAN CELL 6 AREA, CDM, PROJECT NO. 6447, DATED NOVEMBER 2004. (AB) ABANDONED 6) SURVEY DATA FOR MW-17R, MW-17DR AND M-12R IN SCS REPORT DATED OCTOBER 13, 2020 �4�ti+t19 554wi} F tCA'r: fsr�1 �fP. [ ' ,k ....... 200 100 0 200 400 �NOTES: • {� AL LOCATION ACCURACY APPROXIMATE SCALE IN FEET 2653 �I j f OF THE FEATURES S�' SHOWN IS LIMITED BY �r�� , THE REFERENCES THEMSELVES. REVISIONS No. DESCRIPTION BY DRAWN: RLB CHECKED: TJD APPROVED: AWA DATE: 12-10-20 CAD FILE: BCLF 9378-22 WTM JOB NO: J20-9378-22 is 1IM I BUNNELL BUNNELL ENGINEERING 6004 Ponders Court, Greenville, SC 29615 Phone; (864) 288-1265 Fax; (864) 288-4430 GROUNDWATER ELEVATION CONTOUR MAP—OCTOBER 26-30, 2020 BUNCOMBE COUNTY LANDFILL ALEXANDER, NORTH CAROLINA FIGURE N0. APPENDIX A FIELD SAMPLING LOGS PACE ANALYTICAL SERVICES, LLC. Document Name: Field data Sheet Date Issued: March 8, 2D19 C8r%I7AF G� 4 C'a e: 1 of Document ltilumbpr. F-CAR-FLU-DDI-rev.D3 Issuing Authority: Pace Huntersville Quality. � . Office . L5 Field Data Sheet K Pi I`�'t61?_o Name and Affiliation { ampler(s): RIA R f&Ie Name and Affiliation (Inspector): . N iA Well Information Well ID: AV l3 Well Diameter: _ -1 ' A Total Well Depth: 15 .38 —ft Static Water Level: it Height of Water Column: I I? '� ft Well Locked: Construction: IG� N Project #: BkAto_onb� C o. Nei✓ L F Field Data Sheet Review: Date: By�"4 VC teeI/Stainless Steel) Multi Factor': O • t 63 r(Radius/12)2 x 3.14 x 7.481 Casing Volume: 1 ' gallons Cal. 3 VoIumes: gallons Pump Intake: i ft Purge Information Date Purged: to / 1� ./ 70 Start: Finish. Purge Rate: �l Purging Method: _Total Volume Purged: 1 O S r,1_ (gallons(mis/ ) SaMpling_lnformation Date Collected:. t o . /? / 2-0 Time Collected: 12 4J (a<D Sampling Equiptnent Used: Q t f-f S4a ti + L Am? Instrument ID: Bottle ''Type Preservation Analysis Required �I L A Field Measurements/Observations sample Telilp (aq, . I cl • Time- O . Turbidity (ntu): 5 . Time:: I y 0- Dias Oxy (mg/L):_ Q.,.W Time: Fe 2+ mg/L: Time: Specific Cond. (uS): 3 qg - 3 Time: Res. Cl (mg/ L)/(µg/L): "~ Time:. Sample pH (s.u.): 6 Time: Odor: N o Time: (� 4 0 ReDox (mV): _ _ — 10. Time: . Appearance: - Time: ReDox (EH value):YSI ProPIus +200mV - .y 3 a • 7 Other: Time: GeneraVWeather Observations: unn cloudy/rainy) Temp-0 ff) Wind 4 T(mph) Sampler Signature: R aA &S Date: i� z L / 20 Stabilization Test Time Purged Temp. (°C) Digs Oxy. (mg/L) Spec. (S) PH (s,u,) ReDox (rnV) Turbidity (ntu) o ume remov {gaily mis/ Water level {ft} Other 17. 2.5 00 1 b 4040. °] �. +� .1Z o 3.74 D ujo 11. �. noo —tZa 6. 35 ?L 4 I%35 Iq 0. ar 6,4-1t, -7, 1 19SO 3. Z Document blame: Field data Sheet Date Issued: March 8, 2019Pa CB Ar&q1J41C. A : 1 Of Document PtTumbpr: P CAI2-FLD-001_rev.03 Issuing Authority. Pace Huntersville Quality, r r Office - Field Data Sheet Name and Affiliation (Sampler(s): 1Z J" B P&. c.e . Name and Affiliation (Inspector): . N (A Well Information Well ID: M W- 13 D Well Locked: Well Diameter: Z ; n Total Well Depth: 4 k; 3 ft Static Water Level: 7 it Height of Water Column: 3 q .O ft Purge Infaiinati'on Construction: Project #: 94d%c . C 0 . ge-w LF ad Data Sheet Review: Date: I I �34a fi3 C� By- O �%O / Fiushmount ) eel/Stainless Steel) Multi Factor`: ['(Radius/12)2 x 3.14 x 7.481 Casing Volume: b ' ci al gallons. Cal. 3 Volumes: r I fll 41 gallons Pump Intake: — qq it Date Purged: t4 / 6 / Z. - Start: ) 3 o S Finish: N' Purge Rate: I00ANI S /!" /I PurgingMethod: Pe S+a1 G tamP TotalVolume'Purged: 3 500 (gallo /mis ) Sampling Information Date Collected: 1`�. /_�,Gj Z 0 Time Collected: I� (amp� Sampling Equipment Used: 4e l s I 14. L PjA m Instrument ID: Y 5I 05 b a / TP k, 69s 3 Bottle Type Preservation Analysis Required �►� af,Pl Field MeasurementgfObservations Sample Temp (°C): . 3 Time: 13 y -5� Turbidity (ntu): 0-7 Time: � Diss Oxy (mg/L): • 3 Time: Fe 2+ mg/L-. Time: Specific Cond. (uS): '1 Z Time: Res. Q (mg/L)/(Ag/L); Time:. Sample pH (s.u.): Time: Odor: . N 9 ne Time: f 3 y S ReDox (mV): eoX 4 - ok Time: Appearance: L12Q Time: � ffz ReDox (FH value):YS ProPlu�s +200mV LD y . ,9 Other: Time: General/Weather Observations: /ray) Sampler Signature: R Y a'AS Date: l o t Z 6 I Z J Stabilization Test Wind Y—J (mph) Time Temp. Digs Oxy. Spec' PH {s.u.) ReDox Turbidity Volume removed Water Other Purged (oq (mg/L) { S) (mV) (ntu) (gallons mis L level (ft) 131� 3 �.5 b • 7 3�. b 13 . o f�+, 3 . 3 Z.� b . _7 31, t. 13. 7 900 131 A 'A-3 3A),4 b•LA T 100 112 a 1'7 1 .2 K r;, '� S . 1500 7.�y 3z5 1A. 7 Ll13.g b . I2. I `7 2.0-30. Ar 1 Client: RL 6 Location: A; 1,aw;Yee C. �e de Project: 8%kAt,tO. L F Weli it): tAw - 13 0 Document Name: Field Data Sheet Document Number: F-CAR-FLD-001.rev.03 Document issued; March 8, 2019 Pagelof I Issueing Authority; Pace Huntersvifle Quality Office DsV'13, 0.6530 2-6100 ime Temp. Purged (00 Spec. Cond. (US) Turbidity ReDox(mV) (ntu) (gallon circle e Water level (ft) Document Name: Field data Sheet Date issued: March 8, 2014 C@Ansljftaia Page: 1 of Document Number: F-CAR-FLD-001-rev.03 issuing Authority: Pace Huntersvitte Quality. Office LS Field Data Sheet A 5hm��'t,e, A Name and Affiliation (Sampler(s): It *$ Qat¢ Name and Affiliation (Inspector): N AA Well Information Well ID: . fA W - 4 Well Diameter: Z ' (\ - Total Well Depth: 2 S . S A ft Static Water Level: 11-.13 aft Height of Water Column: I1,67 ft Well Locked: Construction: ,Project #: F?uAr-- .L o: &-w L F 1d Data Sheet Review: Date: i 1 } -5 � 3{? $y 0_A )NO / Flushmount ) eel/Stainless Steel) Multi Factor*: �• 1 3 r(Radius/12)2 x 3.14 x 7.48]. Casing Volume: Z .O 7 gallons Cal.3 Volumes: " 6 • z 7 gallons Pump Intake: ~ Z' 3 it Purge Information Date Purged: 10 / 6 / -2 -0 Start: 1415 Finish: 14 3 D purge Rate: 10OtA If , r) Purging Method: Total Volume' Purged: !SOD (gallon / mis L) Sampling Information Date Collected:.. i�_L&/ Time Collected: 1435 (am4D Sampling Equipment Used:_P¢� _4-la !�; G 'PA M 12 Instrument ID: Y I Z o S 6 g Z rP w 6 019Z Bottle Type Preservation Analysis Required �- -- I tOK0.ni� Field Measurements/Observations Sample Teatp (°C): 1. 2 Time: 435 Turbidity (ntu): AD. 6 Timer 1 q 3.5 Diss Oxy (mg/L): l 3 Time: Fe 2t mg/L: �� Time: Specific Cond. (uS): 2 37. 4 Time: Res. Cl (mg/ LY(Ag/ L): �--rTime:. Sautple pH (s.u.): 6 -L _ Time: Odor: 1i10nf Time: 1935 ReDox (mV): Z 3. Time: Appearance: _ C /E a- r _Time: ReDox (EH value):YSI Proillus +2ODmV 1 -3 -3 Other: Time. -� General/Weather Observations:. _ suns. cloudy/rainy) Temp. 7 q (IF) Wind0 - 5 (mph) Sampler Signature: R y a $ Date: 1 D 2 C, / z Q Stabilization Test Time Purged Temp. (C) Diss Ox. y (mg/L) Spy' { S) , PH (s.u.) ReDox (mV) Turbidity (ntu) o ume removed (gallons mis Water level (ft) Other '0 6. z 21. 7 z. i s� D ,t P 2o,D 1 234.0 6, Z. 211 2.2 59,0 t4Z5 Iq..b i- 'Z?S,z �,Z' -Lz.7 o.57 1oDo Lw3n tg.l 1. z 7. 6.Z z3.7 1 .q 1500 Document Name: Field data Sheet Date Issued: March 8, 2019 aC$Alwlyt4Cal y 1 of 1 Document Number: F-CAR-FLD-001-rev.03 -Page: Issuing Authority: Pace Huntersvitic Quality Office . Field Data Sheet A5"%,itie .,tie Name and Affiliation (Sampler(s): RM Q rate Name and Affiliation (Inspector): N /A - Well Information Well ID: Well Diameter: 2 + Total Well Depth: 5 7 • q 2 ft Static Water Level: 3 5 't Height of Water Column: 44.3 6 it Project #: R Lt.% L.. Gd ¢ , L P 1d Data Sheet Review: Date: 11 131 any By: Well Locked: E > NO / Flushmount ) Consttuction: 6VC teeI/Stainless Steel) Multi Factor*: 0,1 6 ) 1*(Radius/12)2 x 3.14 x 7.481 Casing Volume: 7-2 3 gallons. Cal. 3 Volumes: -Zl - L I gallons Pump Intake: ... S S f t Purge Inforinati'on Date Purged: l J / 2 6 / ?� Start: _ 4 S Finish:1_S 15 Purge Rate: t 4 0 M 15��, /1 Purging Method: fe-eii4a.l4.•G Pttwt P Tot al Volume Purged: 2 000 (gallon IS/ Sampling Information Date Collected: i� /pbl 2 0 Time Collected: Sampling Equipment Used. Pe ri 4&- t '` PLkrAp Instrument ID: Y 51 0 5 6 R/ i t w 6 06 3 Bottle 'Type Field Measurements/Observations Preservation Analysis Required NL. A,2QI �. tf- D:OX9, Sample Temp (°C): 17 Time: 15Z 0 Turbidity(ntu): 1 Timer Diss Oxy (mg/L): O' 3 Time: Fe 2t mg/L: - Timer Specific Cond. (uS): 3 1 g Time: Res. Cl (mg/L)/(µg/L): r' Time:. Sample pH (s.u.): % _ Time: Odor: K0 A Time:T 15 2.0 ReDox (mV): . Z . Time: I Appearance: Time: 1 ReDox (EH value):YSI ProPlus +200mV Z Z 3.2 Other: Time: General/Weather Observations: cloudy/rainy) Temp._j_Q_ (°F) Wind 0" Sampler Signature: R Y (k A Date: Stabilization Test Time Temp. Diss Oxy. Spy C , pH (s.u.) ReDox Turbidity Volume remov Water Other Purged CC) (mg/L) � (mV) (ntu) (gallons mIs level (ft)(US 1513b 17.6 . 1.5 3o&z b.7- 33,t ,.-. 500 f�a� D %Afl 1.5 2 6. 33,2 3. 5 h 0 C 150 1 7. 7 0-5 jIS �,.� 2g,� 1 , 7- ��� I510 17.4 o. U.7 25.5 1•0 i5oo1515 i7.4 0. .7 23.+{ 2.,_7 1 ZOO Document Name: Field data Sheet ceAnafyfroaj' f Document Number: F-CAR-FLD-001-rev.03 Field Data Sheet nf: B LC Location: A S ke %f 1 le✓1 N l.. Name and Affiliation (Sampler(s): RM Y P*.G f. Name and Affiliation (Inspector): N C4 Well Information Well ID: ^ w -3 FZ Well Diameter: 2 Total Well Depth: q . 1 ft Static Water Level:_5 3 til 6 it Height of Water Column: 5ft Date Issued: March 8, 2019 Page: 1 oft Luthority: Pace HuntersvilIe Quality Office - #: B . G o. New Lr Data Sheet Review: Date: 1 l I )13LO, -Q By: Weil Locked: [YES'jNo / Flushmount ) Consttuction: (5)feel/Stainless Steel) Multi Factor*: 6 3 r(Radius/ 12)2 x 3.14 x 7.48] Casing Volume: O, Q Z ' gallons. Cal. 3 Volumes: ' Z .7 b gallons Pump Intake: ' 5 7 . ft Purge lnforination Date Pur ed; LO Z 6 2O _ Purge Rate: I Qo"A I SI m g / / Start: � bCf Finish: b 2 Purging Method: Vs-r;o.e le i;e,,fG euM P Total Volume'Purged: Z D4O (gallons(mis/ ) Samuline Information Date Collected; l�J /� 4 Time Collected: I b 30 {a pm) Sampling Equipment Used: V -LriQ_b re k o,4e f SOY -Instrument ID: )' g I Q 5 h q/ f� uv �o $ 3 Bottle Type Preservation Analysis Required Au, Field Measurements/Observations sample Temp (oq: 8 Time: b 3 0 Turbidity (ntu): Time: 16 3`J Dias Oxy (mg/ L): S' . 8 Time: Fe 2+ mg/ L: Time: 1 Specific Cond. (us). 7 91 Time:. Res. Cl (mg/ L)/(µg/ L): �Time:- Sample pH (s.u.): i7 Time: Odor: N 9 ne Time: 1 h 3Q ReDox (mV): Z 7• Z Time: Appearance: re? 0. r Time: 16 10 ReDox (EH value):YSI ProPlus +200nV . Z 17.1 Other: Time: General/Weather Observations: . . - sum cloudy/rainy) Temp_7 L(OF) Wind Q 5 (mph) Sampler Signature: _Q.)f_an_ g y C15 Date: 1 O / 7. t /Z 0 stabilization Test Time Temp. Dtss Oxy. Spec. . pH (s.u.) ReDox Turbidity Volume removed Water Other Purged (°C) (mg/L) f 5) (mV) (ntu) (gallons Is/ level (ft) %► 0 113 5.3 7-3.1 6. 1 16 . 11. 6 Soo 5 p zl 5.3 -73.I 1 lei. 1%-0 SQa �$.,+;c 1-11-6 S.9 74.1 7.6 100o tbz!) 'Ll .1 5. 6 Z .0 7.0 IS00 ZS 21 S-b -2. 164 115.0 5 -7 Zoo0 eAnafyffcal f// �� Document No me; Field data Sheet Document Number: F-CAR-FLD-001-rev.03 Date Issued: March 8, 2019 Page: 1 of I Issuing Authority: Pace Huntersville Quality. Office . Field Data Sheet Ask, ;ito_kr Name and Affiliation (Sampler(s): Q ^B Net, Name and Affiliation (Inspector): 14/4 Well Information Well ID: . Mw-90 Well Diameter: 7- r n Total Well Depth: of 7.4 3 ft Static Water Level: 17.8 ft Height of Water Column: 69.5471 ft #: gutAc_ Co. mew LF Data Sheet Review: Date; {t `3 )oc By: Well Locked: CYEONO / Flushmount ) Construction: PV teeI/Stainless Steel) Multi Factor[•(Radius/12)2 x 3.14 is 7.481 Casing Volume: [ • 3 L ' gallons Cal. 3 Volumes; 4 '� 3 gallons Pomp Intake: ft Purge Information Date Purged: 10 / 'Z 7./ . Zq Start : 6 O 5 I a4 rA151A, A ^Finish: i Z.0 Purge hate: Purging Method:_ Pelf; -jn-I.'t A ul A? Total Volume Purged: i 5 OD (gallons mis L) SmRling Information { Date Collected:. 14 a Time Collected: Sampling Equipment Used: ? 0--,; 4 -te I f (_ P K M r Instrument ID:_ Y 4-105 A 9 /TP 6-6 og 3 Bottle Type Preservation Analysis Required Pit- A Pt . Field Measur rnents Observations Sample'Teu1p CC). Z 1 • l Time: l 6 2 S Turbidity (ntu): Time: Dias Oxy (mg/L): 0, 6 Time: Fe 2+ mg/L: Time: Specific Cond. (6): _ L4 31 ?C Time:Res. Cl (mg/L)/(ug/L): '=Time:. Sample pH (s.u.): 6 . 3 Time• Odor: K ^e Time: ReDox (mV): Z $ b Time: Appearance: L 16 Time: ReDox (EH value):YSI ProPlus +200mV Z'2. 5. 6 Other: �� Time: General/Weather Observations: . unny cloudy/rainy) Temp. IZ (°F) Wind (mph) Sampler Signature: 1Z Y a,% 1012 Z O Stabilization Test Time Purged Temp. (°C) Diss Oxy. (mg/L) Spec. (us) . pH (s.u.) ReDox (m) Turbidity (ntu) o urine removed (gallons MIS Water level (ft) Other L l 6t o 3. 7 �} �. 1. i 4 o Zo . 6 .7 >�3�.� 6 u Z I. `� Soo spa+,•� 1 13-3 63 14 6 3. logo 46240 Z1,0 0, 431 6. 7.Z 3, 1500 ---,Ie�r>Flfjnkleal i t Document Name: Field data Sheet Document Number. F-CAR-FLD-001-rev.03 Field Data Sheet Name and Affiliation (Sampler(s): R M 13 P a.. / P Name and Affiliation(Inspector): J4 /A Well Information Well ID: 1A`^� - g Well Diameter: 2 Total Well Depth: 7 Z • H ft Static Water Level: 4LZ,Z1.20 ft � Height of Water Co.-.mnq •Z s ft Purge Infocination Well Lacked: Construction: Date Issued: March 8, 2019 Page: 1 of j Issuing Authority: Pace Huntersvil4 Office - ,ject #: aaAe - to, Neu., i F Data Sheet Review: Date: t1131�� a NO / Flushmount ) VC teeI/Stainless Steel) Multi Factor*: Do Q7 3 (*(Radius/12)2 x 3.14 x 7.481 Casing Volume: '7' O S gallons. Cal. 3 Volumes: "ZIX _ gallons Pump Intake: Et Date Purged: 1 O /ZZ/ 10 Start: ) b 3 5 Finish: S o Purge Rate: Purging Method:__ Q�, r S_�}o. } ? Q d`T Total Volume Purged: 7 S `J (gallons(�L) Sawfing Information Date Collected:_/2V -1 a Time Collected: 4 S 5 ( pm Sampling E ui meet Used: Pt e, 5 ft 1 t: c m Z p 5 P g g P _ �u ? Instrument ID; 1 b /TPw 60 3 Bottle Type Preservation Field Measurements/Observations, Analysis Required 0 c a PQ I - Sample Temp (°C): Z 1. Time. y b 5 Turbidity (ntu): 5• W Time: ) 6 S 5 Diss Oxy (mg/L): y Time: Fe 2+ mg/L: Specific Cond. (uS): 3-A S Time: Res. Cl (mg/L)/(µ /L): .�q'ime:. Sample pH (s.u.): b +4 ` Time: Odor: ri 0A� Time: 16� 5 ReDox (mV): Z 5 Time: Appearance: G I r Time: ReDox (EH value):YSI ProPlus +200mV i Other: Time: General/Weather Observations: (sunny loudy/rainy) Temp. 72 (°F) Wind 2-5 (mph) Sampler Signature: A aa(-) Date: 7�Z� Stabilization Test Time Temp. Dies Qxy. Spy' • pH (s.u.) ReDox Turbidity o ume remove Water Other Purged (QC) (mg/L) Cori, (mV) (ntu) (gallons, Tj level (ft) [uo Z2.5 30t6.1 0 21. 40 zz. } Sala. ( b. 5 2�. [ tit I4 S '101, 5 (y , Z5 7 b. q Soo Za. is .3A1. LA 40 1 5, 750 7-q.4 __ � aceAriaf��Frea7y t Document Name: Field data Sheet Date Issued: March 8, 2014 Pa e: 1 of 2. Document Number. F-CAR-FLD-001-cev.03 Issuing Authority: Pace Huntersville Quality Office Field Data Sheet Clienf:-RL_C Location: A re YJ Project #: _RqAf• CO. Nett/ L F Name and Affiliation (Sampler(s): R Mid Page Field Data Sheet Review: Name- and Affiliation (Inspector). N 14 Well Information Date:I{j3�2r1� By: Well ID: M W Well Locked: YE5 NO / Flushmotult ) Well Diameter- Z Construction: -PSteeI/Stainless Steel) TotaI Well Depth: S ft Multi Factor`: �•l L 3 [*(Radius/12)2 x 3.14 is 7.48] Static Water Level: y 1:-$ 3 ' ft Casing Volume: `� • gallons. n Height of Water Column: i 7 ft CaI.3 Volumes: gallons Pump Intake: S C . A Purge Information Date Purged: L O / 2 . / 20 Start: 12 3 0 Finish: 13 3 5 Purge Rate: 1000011 Purging Method: va.r.;a a ie a Total Volume Purged: 6 � o 0 (gauon 0.$)L) Sampling Information Date Collected: - i 9. /?! / -. D Time Collected: 3 4 4 (am pm) Sampling Equipment Used: _v_ar:,&b le Poop, , P k fA P Instrument ID: f Sr 0 b . 1're oe 3 Bottle Type Preservation Analysis Required Field Measurement Observations Sample Temp (cq: I . 3 Time: 13 A 4 Dins Oxy (mg/L): 2 Time: S� Turbidity (ntu): q . % Time: E 4�; Fe 2+ mg/L: Time:. Specitic Cond. (uS): Time: Res. C1 (mg/L)/(µg/L): = Time:. Sample pH (s.u.): Time: Odor: f -On Time: 13 ReDox (mV): " 20. Time: Appearance: Time: ReDox (EH value):YSI ProPlus +201)mV 17 1.15 Other: Time: General/Weather Observations: . (sunny/cloud /rain) p. b rJ (°F) Wind S-h (mph) Sampler Signature: RNl a,& g p, Date: O Z 0 Stabilization Test Time Temp. Diss Oxy, Spec. PH {s.u.) ReDox Turbidity a ume remo Water Other Purged (°C) (mg/L) ( ) (mV) Otu) (gaUo /mis level (ft) +235 1 17.$ 0.7 7o4 %.5 40J 5o� 42.1% 5 WP 7 0•,7 7D�[ A -6 40, ( , . 0 41,103 i1t}S .j -3 z. 6, `4' —19,3 Za, 5 1 S oo 42,51 1�5 h.I 9.3. 44 4 —1�. l 5 Z500 7-.16 3b5 i�•Z 4, �- V7 6.1 6.4 --�Qq P, 50e) 43.31 Document Name: Document Issued: March S, 2019 Field Data Sheet Pagel of 2 Document Number: F-CAR-FLD-001.rev.03 Issueing Authority: Pace Huntersvllle Quality Office Client; B L C Location: Mk&V:klei N C. . Project: G New �F - -$.u.�:. a. Well ID: in W- 7 Reviewed Date and By: Stabilization Test I 'V'IiC'il- Lfiia:Z7'La'�iCY 15f1���'1lC:ii��..ri•1i Y' ��:E.�'� 1 . 1.2 13 f 4 0,6,50 I :6, 1AUG a 2,6; !4 Time temp. Diss Oxy. Spec. Cond. pH (s.u.) ReDox (mV) I turbidity Volume ovedWater (gallon /mis ) level Other Purged (°C) (mg/L) (us) (ntu) circle one {ft) 4315 IQ o,L 665 V4 -24.1 11,Z 4SOQ 43.71 1320 IS3 o.2 b z 6.11 --zs..3 10. 5000 43,8S 1325 11%,1 0.z bb0 LA 1o, 5500 44.01 1330 1$•3 o.Z 65 q .. 5 .0 J p, j Dop 4 1I I5 i 2� .3 O.z V 51 (q . t.( k z 1. 3 A . q k 4 '+.Z. 5 --- 1.• ac,9An813R;ICaI' f Document Name: Field data Sheet -... Date Issued: March 8, 2019 Page: 1 of k Document Number: F-CAR-FLD-001-rev.03 Issuing Authority: Pace Huntersvilli Office Field Data Sheet Clienf: 8 4 E Location: Slav l!e, N C Project # _BC. GO." r4ev LF Name and Affiliation (Sampler(s): RAS f °,<2 - Field Data Sheet Review: Name and Affiliation (inspector): Well Information N r A Date: i 1 i I �13 c1 By: Well ID; 1nw ' S D Well Locked: YES 0 / Flushmount ) Well Diameter: 2 -` Consttuction: (PVC eel/Stainless Steel) Total Well Depth; S [ - 4 L {t Multi FaCtor*: 0-1 3 [*(Radius/ 12)2 x 3.14 x 7.481 Static Water Level: 3 S. O ft Casing Vc4ume: 14 gallons n Height of Water Column: '� 6 ft Cal. 3 Volumes: ' Z2 3 gallons Pump Intake: 7 al ft Purge Information Date Purged: ID Z4 / ZU _fit•- PurgeRate: Start:.. .L4 IS Finish:l 35 Purging Method: Ve,riatote R-wiC ?JL^4 _ `TotAl Volume Purged: Z000 (gallon Sam ling Information Date Collected: , tO/� 2 Time Collected: 1414 O (a pm) Sampling Equipment Used. IJ0e , # a fkP instrument ID: Y 4L 04bb O DTPw 6o4 3 Bottle Type Preservation Analysis Required Field Measurements/Observations M Sample Temp (°C): r 7. 7 Time.- I Lk 4 Turbidity (ntu): �! . Time.'. 1 4 Diss Oxy (rng/L): O ` S Time: Fe 2+ mg/L: Time:. Specific Cond. (uq: Z t �.3 Time: Res. Cl (mg/L)/(µg/L):�- Sample pH (s.u.): 6. 7- Time: Odor: 1 roll ReDox (mV): 3 4 , 3 Time: Appearance: G W aLr— Time: ReDox (EH value):YSI ProPlus +200mV Z 3 4, Other: Time: •� General/Weather Observations: . (sunny/cloud rainy) emp. b3 (°F) Wind S-t'� (mph) Sampler Signature: R7 y mA 8 ck� Date: ( o f 2s % z 4 Stabilization Test Time Temp. Diss Oxy. Spec. pH (s.u.) ReDox Turbidity o ume removed Water Other Purged (°C) (mg/L) (S, (mV) (ntu) (gallons mis level (ft) 1M'Lo I7.7 -'ZI G, 2. 26. 7, 500 35.73 Dlk �? e3.'� Zti7, b &.2 264 7.9 500 '35.71 1 25 17.6 0.6. 16.3 . 6.7 30,3 G . 9 100 '3 35.) 7 1430 17.6 0.6 21'; 32.6 5.0 I Sow 35,80 11435 111. 0 L5 1 745.y 6.2 3'l.Z I S,a 2ooq 35.8 Z Document Name: Field data Sheet Uate Issued: March 8, 2014 aceAnafytJcaf Page: 1 of Document Number: F-CAR-FLD-001-tev.03 Issuing Authority: Pace HuntersvilL Field Data She t Name and Affiliation (Sampler(s) _IZn R Pace Name and Affiliation (Inspector):_ A Well information Well ID: M w- Well Diameter: -x ' 1 Total Well Depth: 2 . S 3 ft Static Water Level: 3 ft Height of Water Column: lQ• 72 it Pur a Inforinati'on Well Locked: (( YES Construction: #:_ ttnC_. Co, t4ew LP Id Data Sheet Review: Date: By, O / Flushmount ) eel/Stainless Steel) Multi Factor*: � � i 6 � r(Radius/12)2 x 3.14 x 7.481 Casing Volume: 3.0 S gallons. Cal. 3 Volumes: 9 S gallons Pump Intake. "' S O ft Date Purged: 10 / 2/, 4 Start: I S C) 0 Finish: ) b Z s Purge Rate: I a on►! 5 /^; n Purging Method:yar=0.bla pUA' T061VoIume'Purged! 7500 _(gallo s/mIs L) Sampling information Date Collected:_ 0 / / 10 Time Collected: 1630 (a /p Sampling Equipment Used: Uo.-- 0Jo fe„ P^-i a pLt m Instrument ID: 57-o5 % W 6,a9 3 Bottle Type PreservatiG n Analysis Required Field Measurements Observations Sample Temp (°C): 1 Time: 16 30 . Turbidity (ntu): S, Time:. 3 O Dias Oxy (mg/L): O . Time Fe 2+ mg/L: Time: Specific Cond. (uS): l Time: Res. Cl (mg/Ly(µg/L): Nine•. - Sample pH (s.u.): 2 5.7 Time: Odor: - Timm: -3 ReDox (mV): 5 Time: Appearance: G1ec � Time. ReDox (EH value):YSI I'roPlus +200mV 255.7 Other: r Time: ` General/Weather Observations: . (sunn /cloudy/ iny) Temp. 6 (°F) Wind 5-• to (mph) Sampler Signature: y &A R yo.5 Date: 0 If D Stabilization Teat Time Purged Temp. (oC) Digs Oxy. (mg/L) Spec. (us) • PH (s.u.) ReDox (Inv) Turbidity (ntu) volume removed (gallons/ Is Water level Other L (ft) DSO 0,6.5 D.S '114.1 6, 2 33.3 26,1 500 D,k? ►L.5 Q. % 2tiy,1 6. Z 33. 2L.1 S4 v {S15 2 35,E 39.7 ISO 0 3P34 I525 .l 4z.3 33.$ 250 34•S3 ' i! 6-2 50.0 � 3. 7 -3 00 3 ya a Document Name: Document Issued: March 8,2019 Field Data Slieet Page! of Document Number; F-CAR-FLD-001.rev.03 Is5aeft Author": Pace HLntersvffie Quality Office Client: 8 L Location:. A5 Project: Welllb:— tAtA/-5 Reviewed Date and By: Stabilization Test 2 10, 165 0 0.5-6-70- 4 1.A6W, 2.6100 Time Temp. Diss Oxy. Spec. Cond, PH (S.U.) ReDox (mV) Turbidity 'Volume RFMV (gallo4mISA Water level other Purged (1,C) (rng1L) (US) (ntu) "-- ' circle o e -Z 7-13,7 &.Z q 0. Z f-7. 45,o0 16oS 9-, :Z 0,7 '2113.3 2 571 - 3 12. s5oO .111615 J%.7 0 ,Z- al I q 1 51, Z It Lf 00') - 316.49 16-26 1 %-,' o:3 ?J 3.6 (�?,z SS, & 9 Z 7500 3-77.01..... — e Anafjftal' Document Name: Field data Sheet Document Number. F-CAR-FLD-001-rev.03 Field Data Sheet Date Issued: March 8, 2019 Pa : 'of 1 Issuing Authority: Pace Huntersvilte Quality. Office . RI C Name and Affiliation (Sampler(s): K M 8 pkc 2 . Name and Affiliation (Inspector): x to Well Information Well ID: !'n'r!' & Well Locked: Well Diameter: 2 Construction: Total Well Depth: S�J..SS ft Static Water Level: 2 K • i 6 it Height of Water Column 31 -it Project #: Ba.nc . tO; Nee w L F Data Sheet Review: Date: I...k�MC) 'ES )NO / Flushmount ) Steel) Multi Factor: PA 3 r(Radius/12)2 x 3.14 is 7.48]. Casing Volume: 4.3 0 - gallons, Cal. 3 Volumes: ') Z ' 110 gallons Pump Intake: ''.' Lk % ft Purge Information Date Purged: 10 / °I ./ Z4 Start: Q 1110 Finish:0�35_ Purge Rate: Purging Method: PL' r S ra I ��'C >?k r� p Total Volume'Purged: Z. 5 C�0 (gallons mis Samvline Information Date Collected:. I 0 /A/ "2 4 Time Collected: (am m) Sampling Equipment Used: 'Pe '" 412,11 &'c fu mi? Instrument ID:_ ST- D S 6 s1 / l+?w' bVS3 Bottle Type Preservati4in Analysis Required �L _At 1Pp ,( Field Measurements/Observations Sample Temp (°C): a ' Time: _ _O a 14o Turbidity (ntu): Time: G c"``t 0 Dias OxY (mg/L): Time: Fe 2+ mg/L: Specific Cond. (6): 931 • b____ Time: Res. Cl .(mg/Ly ug/L): 'r Time:. SamplepH(s.u.): Time: 1 Odor:_- t4on .Time: 0`l-10 ReDox (mV): _ 4 7 .5 Time: Appearance: _t ie.%-r Time: oCA (-10 ReDox (EH value):YSI ProPlus +200mV Z y 7.5 Other: Time. General/Weather Observations: . (sunny/cloud QTy emp.JL('F) Wind O•- S (mph) Sampler Signature:__Q Y aON f3Y &5 Date: 10 Stabilization Test Time Temp. Digs Oxy. Spec' PH (s.u.) ReDox Turbidity o ume removed Water Other (°C) (mg/L) (u5)Cond (mV) (ntu) (gallons mis level (ft) �Poulrged 1�.7 Z• fi 5.6 S.S- Z.3,� Put 11I . Jo ou'o IA.S °I 13'1,3 .-A 29.E 2.z IQoo 00as lq• �.. ri I31. 5.a 33.1 0,1 1500 ?13() 5.5 115.6 1 , Z000 0955 1R-4 1 .17 131.4 s,A +1b,Z 1.5 7.5.00 1 �., ace�rralylreal" Document Name: Field data Sheet Document Number: F-CAR-FLD-001-rev.03 Date Issued: March Issuing Authority: Pace Hu Office . Clieti Field Data Sheet A 5 a« v; urt, i #: nc. 0 MewLF Name and Affiliation (Sampler(s): R+k 13 i'ac t? Field Data Sheet Review: Name and Affiliation (Inspector): A` Date: Welllnformatidn e Well ID: IM1 W 7 (YES/ Flushmount ) Well Locked:F(Peel/Stainless Well Diameter: Z ` Construction: Steel) Total Well Depth: .ft Multi Factor*:aius/12)2 x 3.14 is 7.48]. Static Water Level: Z_i a 3 ft Casing Volume: �' 2111ons Height of Water Column: 9 gh ft 3 g 3 Cal. 3 Volumes: 621ons Pump Intake:_ 2- 7 ft By: Purge Information Date Purged: 10 ZQ Start : 1015 Finish; 1055 Purge Rate: )0Q,19S/4 k rl Purging Method: f 6 r.'4 fal ; c u an Total Volume'Purged: 4000 (galionsoL) SamnIing Information Date Collected:. t o . W -L Time Collected: 1 l OF] am m) Sampling Equipment Used:_ f e r: StP 1; L Pu,A p Instrument ID: /TOvApI33 Bottle Type Preservation Analysis Required tr4- p "4)eo.RP L 4- ter-5 . Field Measurements/Observations Sample Temp (°C): . I l . LA Time: (� Turbidity (ntu): a _ Time: 1 Digs Oxy (mg/L): 0-1 Time: Fe 2+ mg/L: Time:. Specific Cand. (uS): b 2 Time: Res. CI (mg/L)/(µg/L): Time:. Sample pH (s.u.): Time: Odor: Time: --LjQ ReDox (mV):— y `� . 6 Time: Appearance: _ 616o-e' _Time: ReDox (EH vaIue):YSI ProPlus +200mV -S --1 Other: r Time: r General/Weather Observations: 1 0.. c 94a re, 8 JJl w- 1375 (sunny cloud rainy) Temp. G� (°F) Wind Q-� (mph) Sampler Signature: a & B Y AI Date: ]�� Stabilization Test Time Temp. Digs Oxy. Spec' • PH (s.u,) ReDox Turbidity Volume remove a Water Other Purged (°C) (mg/L) � ) (m� (ntu) (gallo level (ft) 3920 10.41 0.4 53,0 4,1 3b B 32. 5,00 Du, 20.4 0. 577.3 0 3610. 3-2. f) ' Soo 644, 1025 U.2 0.3 5 'ko 1 6,k 7 3b.-7 looO lo35 ,[ 2.3 '�O. 15&o , CyIn 1D S 2,a.q 0,I I;qg ,1 Document Name: Document Issued: March 8, 2019 Field Data Sheet page! of ?— Document Number: F-CAR-FLD-001.rev.03 Issueing Atithority: Pace Huntersville Quality Office Client: B L E Location: 66V► ties N C Project: �►��, Lo. New L F well 10: 5 Reviewed Date and By: 1 4 Stabilization Test s.. 3 y7 � 16, y0�6�5�r0� 1. A68.0 Time Temp. DISS Oxy. Spec. p� (5.u.) ReDox (mV) Turbidity Volume Re ed (gallon Is/ water level Other Purged (°C) (mg/L) (u5}' (ntu) circle one (Ft) ►v;43 Z1.2 0,2 643 6.1 —47 . Z 3ss)0 toss Zl.y. I Q•z IV1�1 �. I ��1� 6 b.2 000 a00Ana1y1Ve8J r Document Name: Field data Sheet Date Issued: March 8, 2019 Page: 1 of j Document Numbor: F•CAR-FLD-001-rev.03 issuing Authority: Pace Huntersvik, Office . Quality, Name and Affiliation (Sampler(s):_Rohg Name and Affiliation (Inspector): . 14 (A Well Information Well ID: MW -1s� Well Diameter: + n Total Well Depth: S.. _ft Static Water Level: 1 0 -ft Height of Water Column: • 3 5 it Well Locked: Consttuction: Project #: banx . l a ;1V¢w Field Data Sheet Review - Date: Date: I I h -,roa-o By: / Flushmount ) Stainless Steel) Multi Factor*: 0.•i6 3 [*(Radius/12)2 x 3.14 x 7.48] Casing Volume: 1 AS gallons. Cal. 3 Volumes: =19, 4 y gallons Pump Intake: 4 3 ft Purge Information Date Purged:fc-� / Z pl ./ 11) Start: 3 b Finish: O age Rate: joo PN1 S /,41 n Purging Method: P to m f Total Volume Purged: 20 00 (gallons(mis/ ) Sampling Information Date Collecfed:- i° /2-V 7.0 Time Collected: 15 S (am/ ) Sampling Equipment Used: r t f wvii?Instrument ID: Y riL o S b yf rf w & 0 9 3 Bottle Type Preservation Analysis Required Field Measureinents Observations Sample Temp CC): Z S• l Time: I 5 Turbidity (ntu): j• 0 Time: 1155 Diss Oxy (mg/L): 0 ' 2 _ Time: Fe 2+ mg/L: Timer Specific Cond. (uS): t 4 5 Time: Sample pH (s.u.): 5 Time: ReDox (mV): __ 2 �q : Time: — ReDox (EH value):YSI ProPlus +200mV 2-2- Genera Meather Observations:. Res. Cl (mg/L)/(µg/L): Time:. Odor: S.t it ur Time: l t s S Appearance: Time: Other: Time: Temp.(°F) Wind D' 5 (mph) Sampler Signature: R L — Date Stabilization Test Time Temp. Diss Oxy. Spy' Cond. PH (s.u.) ReDox Turbidity Volume removed Water Other Purged CC) (mg/L) . (mV) (ntu) (gallons level (ft) .o lb 7 5 - 35.> 2.9' soa va 2 .q l 'Ib7 01 35.7. 2.S tioo ri4ai,'( ilyo 25.E �.I 011 5 8 too 0 Ij 45 7.5.0 0,7 1021 S ot z .z 2. 2 14;00 ►k so 75.2 eAnalX#eal' r/// �__ Document Name: Field data Sheet Document Number: F-CAR-FLD-091-rev.03 Field Data Sheet vale issued: March 8, 2019 Issuing Authority: Pace Fiuntersville Quality, Office . 15 Name and Affiliation (Sampler(s):_a'' g Pat G Name -and Affiliation (Inspector): N /!r- Well Information Well ID: . (kW , CZ Well Diameter: 2 Total WeIl Depth: Z Q `i-it Static Water Level: Q it Height of Water Column: la'4q ft Purge Information Well Locked: Construction: #: & OOC . Co. Ivewt F Data Sheet Review: Date: k 1 j )�),Mo, NO / Flushmotmt ) Steel) - Multi Factor': o-1 e 3 [ (Radius/12)2x 3.14 x 7.481 Casing Volume: 1, 7 q gallons. Cal. 3 Volumes: ' 5 ' 1'7 gallons Pump Intake: ^' 03 ft Date Purged: 10 / Z °M ./ . 2J Start: (Z S O Finish: 13 5. Purge Rate: 1 too ,'06- ;I Purging Method: Pe r, y to l ��'C 4 a A P Total Volume Purged: 2S (ga]Io / mis L) Sampling Information Date Collected:. 10 . /19/ 2 O Time Collected: 1320 (am% m) Sampling Equipment Used: f eri f Y dJ 1, C Psi r''P Instrument ID: Yf z O 5 6 4 /I Q w6 og 3 Bottle 'Type Preservati4n Analysis Required NC APP.1 L + D Po-raf1e4t--5 . Field Measurementg/Observations Sample Temp (°C): . Z ~% •) Time: 3 Z O Turbidity (ntu): Time:" 3 Z7 Diss Oxy (mg/L): 0 Time: Fe 2+ mg/L: Time:, Specific Cond. (-aS): 1.1 Time: Res. Cl (mg/L)/(µg/L): :Time:. Sample pH (s. u.): 17. 3 Time: Odor: ,n 1 +r u/ Time: 3 `J ReDox (mV): _ _ 4 6 , �L-- Time: Appearance: G Ig p- r Time: ReDox (EH value):YSI ProPlus +200rriV L t4 Other: a Time: General/Weather Observations__ sunny/ loudy/rainy) Temp. 72 ff) Wind Q— S (mph) Sampler Signature: RY 0L R 8 Date: 1 D/, Zi Z 0 Stabilization Test Time Purged Temp. (C) Diss Oxy. (mg/L) Spec. on • PH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/ is Water level (ft) Other (USD 'k ILA Z 0,7 10 ('6 6.3 `J,q Li.I Soo 13®4 11.2 9. Lk 1a7 6 V 3 4&. S ( .q 1000 13o S 7.3.q. 0•. 3 to S GS b, 3 45.3 1,4 o0 'ZL4.h 1 0. 1 7112-5 3�. 4-7 .,o ► . 4 Z000 t315 z- 6 z o . � 6.3 410 , 7 1, 3 Z oQ a4 ti°lZ�f �,A - aceAnaliftaly r Document Name: Field data Sheet Document Number: F-CAR-FLD-001-rev,03 Date Issued: March 8, 2014 Page: i of f Issuing Authority: Pace Huntersvilli Office Client: B L E Location: Pi 5I a y; i e Ptoject #: RanL . (O Me w L F Name and Affiliation (Sampler(s): Rrn Pg c e_ Field Data Sheet Review: Name- and Affiliation (Inspector): IN WeU information Well ID: M w I z D Well Diameter: 2 4 1\ Total Well Depth: i • 1 ft Static Water Level: Height of Water Column: Purge Information Date: I i J '� I ,)-,Q D-0 By: WeU Locked: ((YES�,&O / FIushmount ) Consttuction: ((fV(;j-Steel/Stainless Steel) Multi Factor*: 0, 16 � [ (Radius/ 12)2 x 3.14 x 7.48) 4 Casing Volume: � gallons 14.70 Cal, 3 Volumes: gallons Pump Intake: ' 3 7 It Date Purged: 10 / / .20 Start:_ 13 X4 Finish: 16i09 Purge Rate: 1 °` A1s 1.1 Purging Method: Total Volume' Purged: Z, O 00 (gallons Saftlins Information Date Coilected:.�- 11/ 2 `o Time Collected: 1410 (am pm) Sampling Equipment Used:.. QL g ko 1 �'[ P tk,-P _Instrument ID:_ Y 5 T 05 L 14/ T P W (' Bottle Type Preservatimn Analysis Required _. N L A,pP.- 1 1 ; o o. T L d-b P&A.1'1194eA Field Measurements/Observations Sample Teriip (°C); 2 5, t-) Time: 4 10 Turbidity (ntu): 0• Time: I14 i� Diss Oxy (mg/L): o . 3 _Time: Fe 2+ mg/L: -- Time:. Specific Cond. (uS): 4,z 7'o Time: Res. Cl (mg/L)/(gg/L): =:7:— Time:. Sample pH (s.u.): 6 $ Time: Odor: 5xtAk I, Time: ILA 10 ReDox (m.V): Z S . 0 Time: Appearance: G (B —Time:_� ReDox (EH value):YSI ProPlus +200mV Z Z 5, D Other: Time: General/Weather Observations: . (sunny/c>udy/rainy) Temp. ff ) u� Sampler Signature: xy a n °�7---Date: Stabilization Test Time Temp. D1ss Oxy. Spec. on • pH (s.u.) ReDox Turbidity volume remov Water Other Purged (°C) (mg/L) (mV) (ntu) (gallons mis level {ft} i 5O 2�b 7 1�31.�J b,� S. 3, if 500 9.3Z o �� z� . ► . z �3 , . �, 5 . �-t o tca a 1)55 3 �.5 .i .,� �z,S 4,0 10oQ q,4 14,00 °27.91 rJ , y27.o 2.% 1 , 0 So tJ �.61 ZS. 3 eAnalytical r..�~�y Document Name: Field data Sheet Document Number: F-CAR-FLD-001-rev.03 Date Issued: March 8, 2014 Page: 1 of Luthority: Pace Huntersvilh Office . Field Data Sheet A4he�vi Ile, actr Name and Affiliation (Sampler(s):_ RA 8 f ac e . Name -and Affiliation (Inspector): Well Information Well ID: A} k - 14 Q . Well Diameter: Z f Total Well Depth: 1. O ft Static Water Level: Z 66j 7 ft Height of Water Column: 61.7-3 ft Well Locked: Construction: ?V,xc . Go'. New t F Field Data Sheet Review: Date: 11131 �-Oa-0 By: Multi Factor*: I?'t2!-0' 3 / Flushmount ) /Stainless Steel) •adius/12)2 x 3.14 is 7.48]- Casing Volume: 1 ` . Z Z gallons Cal. 3 Volumes: ' , b 7 gallons Pump Intake: Purge Iitforinati'on Date Purged: 1".) -to Start: 1 M 3. 5 - Finish: 1' r7 Purge Date: l oars I S�'�; �1 Purging Method: Vo.c; a6 le (Za+e fkk -P ,_•_Toted Volume Purged: 20 O0 _ (gallo /mIs L) Sampling Information Date Collected:_f /2N 10 Time Collected: J50P (a Vol Sampling Equipment Used. vo-r; ab+2 .&V- m Instrument ID: 7-/ !_ ta.6�$� Bottle Type Preservation Analysis Required Nl. ApPl Field Measurements/Observations Sample Teriip (°C): Time:_ l S A9 Turbidity (ntu): -2, Time: Diss Oxy (mg/L): 2' Time: Fe 2+ mg/L• ~� Time: Specific Cond. (uS): 3 2 %. Time: _ Res. Cl (mg/L)/(µg/L): Time:. Sample pH (s.u.): _ -7, Time: Odor: I a' a r Time: 15 09 ReDox (mV): _ I ,� Time: Appearance: L I Via'-/ Time: ReDox (EH value):YSI ProPlus +2oomV 21 Z . 6 Other: Time: General/Weather Observations: /rainy) Temp._73 (OF) Wind 0' S (mph) Sampler Signature: kya.& e 6Lrf Date: 10 z Stabilization Test Time Temp. Digs Oxy. Spec on • PH (s.u.) ReDox Turbidity o ume removed Water Other Purged (°C) (mg/L) (US) (mV) (ntu) (gallons 6�5 level (ft) 14 .0 15b.� 3 7. 3. zo,4 3, 7 Soo 2 , �Lp i b=3 3 .'3 3 V `7. _0.1_1. 3. -7 5 0. '2g, R k445 lb..6 16 1.-7 3iA-% -7.3 15A 3. > 1000 74 aS `°TOTab" 7.3 Iti z Z9 2.0 455 1 Z _46 743 7.3 12, 8 1 1 . 200q Z .RR �eAnafylkaf f Document Name: Field data Sheet Document Number: F-CAR-FLD-001-Eev.03 Field Data Sheet Date Issued: March 8, 2019 Page: 1 of I Issuing Authority: Pace Huntersville Quality. Office . Name and Affiliation {Sampler(s);_�� V 0.G 9. Name and Affiliation (Inspector): N Well Information Well ID: ^k'�' 1'-4 Well Locked: Well Diameter: Z ^ Construction: Total Well Depth: 0-3 j ft Static Water Level: x% - 3 7 ft Height of Water Column 11.4 b ft Project #: RtLAL. C4j. 1^I ew I-F 1d Data Sheet Review: Date: II15)? W By: YES / NO / Flushmount ) Steel) Multi Factor*: -026 3 [r(Radius/12)2 x 3.14 is 7.48] Casing Volume: R a gallons. Cal. 3 Volumes: ' , A 6 gallons Pump Intake: i-..� ft Purge Itiformati'on Date Purged: 10 / Zq / . � � Start : f. 2-5 Finish: 15 4 S Purge Rate: 1 �ornrS ��•� Purging Method: V.%e;%Lfote, gft-,6e- P iL.Ap Toted Volurm'Purged: 2000 (gallo Sampling Information Date Collected: So /-?�5/ Time Collected: Is 5O Sampling Equipment Used:: va — i a-6 le, (?.n,E.l_ P10"p Instrument ID: Y `� O V/Tq -V 6 03 � Bottle Type 1'reservatipn Analysis Required N L A PP, T Field Measurements/Observations Sample Temp (°C): 3 Time: iS S O Turbidity (ntu): _ Time:'. 1550 Digs Oxy (mg/L): S Time: Fe 2+ mg/L• Time: Specific Cond. (uS): 17b. jTime: Res. Cl (mg/Lu(µg/L): =ime:. Sample pH (s. u. ): to . 2 Time: Odor: N ° ^ P Time: I S S ReDox (mV): 4� 3 Time: Appearance: ime: ) ReDox (EH value):YSI ProPlus +200mV '244,3 Other: _r Time. General/Weather Observations: /rainy) Temp. 6 8_(OF) Wind 06 (mph) Sampler Signature: R y a. A Date:. 10 / 2 q / Stabilization Test Time Temp. Digs Oxy. Spec' Cond. PH {s.u.} ReDox Turbidity volume remov Water der Purged (°C) (mg/L) (mV) (ntu) (gallor mI L level (ft) S.2 1 .1 Z 33 1 12,5 Soo 7g),% Du,P 1�. 15.2 M.1 6.1 T3 q l 500 1535 j7. j S 17n.7 6,-4 3q,A 14.7 0a.0 L9.ZS 15H5 L3 !7b 11 61 44-t 2000 I. ar;efl�fea7y 1 Document Name: Field data Sheet Document Number: F-CAR-FLD-001-rev.03 Date Issued: March Page: 1 of Issuing Authority: Pace Hun Office LE k8 v,"jtei tf t'_ Name and Affiliation (Sampler(s):_R M U PO LL Name and Affiliation (Inspector): P' Well Information Well ID: M 4V .17 D R Well Locked: Well Diameter: Z- "N Construction: Data Sheet Review: Date: V NO / Flusiunount ) Steel) Total Well Depth: Lk (. __ft Multi Factor*: Oil b r(Radius/12)2 x 3.14 x 7.481. Static Water Level: •.� 3 ft Casing Volume: y' 6 gallons.. 14.p7 Height.of Water Column: l%. ? 7 it Cal. 3 Volumes: gallons Pump Intake:-- '""'3 q W_Jft By, Purge Information Date Purged: 10 / . 30 . / -2 O start: Oq 50 Finish. q Purge Rate: I oar^ %5 Purging Method: 4d4A14 ,'L PtL M 1. Total Volume'Purged: (gallo /mIs/ ) Sainvling Information Date Collected: i o . / 34/ Z Time Collected: 4 Sampling Equipment Used: 9� r; ST^ I1+ L f tk N' P—Instrument ID: DS Y>' w 6flB Bottle 'Type Preservati6n Analysis Required D;fl, e Po- rd ihe44'r9 Field Measurements Observations Sample Temp (°C): _ I l . `� Time: 1,015 Turbidity (ntu): Z Time: I D 1 5 Diss Oxy (mg/L): 5 Time: Fe 2+ mg/L: =: Time:. r� Specific Cond. (uS): Zit % Time: Res. Cl (mg/L)/(µg/L): �Time: Sample pH (s.u.): 7 3 Time: Odor: N0^ e Time: ReDox (mV): S 5- Time: Appearance: G 1t; o- r Time:�„ — ReDox (EH value):YSI ProPlus +200ittV 4 3 . Other: Time: General/Weather Observations: y) Temp. S (°F) Wind I4—1 (mph) Sampler Signature: Y 8. A p 1"17 —Date:--- Stab ilization Test Time Temp. Diss Oxy. and pH (s.u.) ReDox Turbidity o ume remov Water Other Purged (°C) (mg/L) ()' (m� (ntu) (gallons mis level (ft) L 271. 7, 4 D Z71, I —3�. �. 3.1-1 Soo �rai't I000 0' . Z _y 3 2A 1000 1005 11.6 0, W 1271-t 1 7•7- -52.7 1 2.6 )Soo l to I %. 0 0.5 2-1. I 7.2 .. b. 2 1 7,3 1 lo0Q Document Name: Field data Sheet Document Number: F-CAR-FLD-001-rev.03 Field Data Sheet Zt: R 1_E Location: A54ev,'i Ie, NG Name and Affiliation (Sampler(s):_ R M 6 Pa ra . Name and Affiliation (Inspector): .N I A Well Information We11ID: . MvW-17(Z Well Diameter: 2 i'� Total Well Depth: 5 ft Static Water Level: `�._ 5 ft Height of Water Column: 11 3 o it Well. Locked: Date Issued: March 8, 2019 Page: 1 of 2_ _ zg Authority; Pace Huntersvi1b Office . #:_B�c_._L_o, Al2w J:F Data Sheet Review: Date; i I J'3, I NO / Flushmount ) Construction: VC Steel/Stainless Steel) Multi Factor: O, l b 3 ["(Radius/12)2 x 3.14 x 7.48] Casing Volume: ( a LI gallons. Cal. 3 Volumes: " % • % 2 gallons Pump Intake: ' I L ( It Purge Information Date Purged: 10 / 4 ./ 20 Start :_IP 4 03 Finish: 1� Purge Rate: IooMf SI^' Purging Method: fi e r; S { a i �}; t ,�, r 4 Total Volume' Purged: LA 500 (gallon Sampling Information Date Collected: 10. /0/ Time Collected: 39 �(am/} Sampling Equipment Used: _¢ +5 fa t+G F t-iP Instrument ID:_ '/ 51- OS b oi. / TPw 5 A 3 Bottle ''Type Pre8ervati6n Analysis Required N L . A e_1. VoLaF-C^ " i, tk D;oK Nd _C.� Q Par��nQfer�j Field Measurements/Observations Sample Temp (cc): .4 3 •4 Time: i 3 9 Turbidity (ntu): b Timer. } 3? Diss Oxy (n►g/L): .3 Time: Fe 2+ mg/L: "'�� Time:.1 Specific Cond. (uS): 2 b Time:. Res. Cl Sample pH (s.u.): % ( Time: Odor:__._,_N `� N Time: 113 0 ReDox (mV): �i Time: Appearance: Timer_ ReDox (EH value):YSI ProPlus +200rnV 6 b Other: Time: General/Weather Observations: . Temp. 5 1 ff) Wind S 10 (mph) Sampler Signature: RY an 6YAJ Stabilization Test Time Temp. Digs Oxy. Spec' • pH {s.u.) ReDox Turbidity Volume remove Water Other Purged (°C) (mg/L) (on) (mV) (ntu) (gallo mis level (ft) 1045 .5 3. 2 ' 44.� 5 ' 1 V) 1.3 Sam. Stea;( DAP 11.5 3.2 244.% b. 13, 1.1 Soo io So 11.4 3.o U5..01 6. 0� 1% , 3 1 . 0 1000 ko55 13.1 2.- Z ,z 7 L � 4 t5oo , � 40 � s�,a t� . -7. & I 'J A zno,3 Document Name: Documerit Issued: March 8,2019 Field Data Sheet page L Of i 1-1!�alc 19 Analylica le f Document Number F-CAR-FLD-001,rev.03 Issueing Authority: Face Hulitersvige Quality Office Client: Location: AS ties i t Project: well 10: fAVV— 17 F f Reviewed Date and BY: hl�hAZPQ/0���� StAbilization'Ttst r 1. -A 8 Time Purged Spec. CDnd. (us) • o ReDx (MV) Turbidity (gallons MIS circle one Water level ® o°%IZt3 8Ca-rAnali JCal' r LE Document Name: Field data Sheet Document Numbir: F-CAR-FLD-001-rev.03 Field Data Sheet Name and Affiliation (Sampler(s):A A8 _ Pa CP Name and Affiliation (Inspector): 111 /4 Well Information Well ID: M W- 10 Q Well Locked: Well Diameter: L Z i Construction: Date issued: March 8, 2019 Page: 1 of t ag Au thodir. Pace Huntersvilli Office #: 91A AI CO, ft(ea.. LF Data Sheet Review: Date: 11 3 J)c)c)W NO / Flushmount ) steel) Total Well Depth: IZO, 2 5 ft Multi Factor": rJ. l{, r(Radius/ 12)2 x 3.14 x 7.481 �j,a4[_3a/z_o Static Water Level: + -`' 6q t Casing Volume: Q gallons Height of Water Column: 5 (• i lit Cal. 3 Volumes: Z S' 0 2 gallons Pump Intake: �' �' g ft Pige 1hfohnati'on Date Purged: i D / 34 ./ 2 start: Z Z Finish: 1145 Purge Rate: 1'30M S '" , Purging Method: Ro,1e a9u.Tf Jot at Volume Purged: 2 000 (gallon mi)L) Sampling Information Date Collected: 10 /)0/ Time Collected: 1 2 SO { / Sampling Equipment Used: VO, r 1 o.b f C R a40- L u "`P Instrument ID 510F6C, T P'w 608 3 Bottle Type Preservation Analysis Required N c. AQQ; _ T 1-4, D,axarC' Field Measurements/Observations Sample Temp (°C): . � � • 3 Time: (2 5 � Turbidity (ntu): � � _ Time:: Diss Oxy (mg/L): 0 `4 Time: Fe 2+ mg/L: !: Time:'�- Specific Cond. (uS): S�• 7 Time: Res. Cl (mg/LY(µg/L): = Time:. `f Sample pH (s.u.): (! . _ Time: Odor: .5,ki Fur Time: l SO ReDox (mV): _ _ -- 7 5-0 - Time: . Appearance: r Time: j ReDox (EH value):YSI ProPlus +200mV L 25. 0 Other: Time: General/Weather Observations: (sunny cloudy/ iny) Temp...?(°F) Wind fl' S (mph) 5ampler Signature:(Z+� ac (� g a` Date: l 3r� Stabilization Test Time Temp. Diss Oxy. spy' PH (s.u.) ReDox Turbidity Volume remove Water Other Purged (°C) (mg/L) (US) (mV) (ntu) (gallons Is/ Ievel (ft) L 1'230 f3,3 0 — ).3 (3._2 13.3 16 351.E to —t-7.3 13.2 70, OZ- i1,�q �2.a D,S 3St. 74.1 1S00 70.06 l 0,4 351. Z 6.. 71.7 7 4 'Z.00D 70A 1-2 eAn8116COfx t Document Name: Field data Sheet Late Issued: March 8, Page: 1 of l Document Number: F-CAR-FLD-001-iev.03 Issuing Authority: Pace Hurttpi Office Client: 6 L L' _ Location:_A S k e v mr-, Ai Project #: R u nc, _ L o, Me L F Name and Affiliation (Sampler(s):_ $14 8 �C.e _ Field Data Sheet Review; Name and Affiliation (Inspector): Well Information Date; t l 3 �o�e By; C Well ID: .W (� _ Well Locked: . ES O / Fluslimount ) Well Diameter: Z Construction: (PVC/ el/Stainless Steel) Total Well Depth; 7 Z 7 ft Multi Factor*; a 6.3 [*(Radius/12)2 x 3.14 x 7.48]. Static Water Level: _� 9J,. it Casing Volume: ( gallons Height of Water Column: 7 ft Cal. 3 Volumes: '3 ' gallons Pump Intake: .,._ 7 Lk ft Purge Information, Date Purged: 10 30./ . z!J Start: 3� {� Finish: 13 7-5�PurgeRate: Purging Method_Umr i q b le- k o.-1'e P>L r'%? Total Volume Purged: (gallo (j) Sampling Information Date Collected:. 4g /30/ Z Time Collected: 3 30 (am/pm Sampling Equipment Used:_I/,b.,-i kb 1 e_ Rc-te- km P _Instrument ID:_ Y S2 OS 6 a / T P W6o 8 Bottle Type Preservation Analysis Required N� Arpl. Field Measurements/Observations Sample Temp (°C): 1 % Time: ) Turbidity (ntu): Time: 3 3 rJ Digs Oxy (mg/L): rJ . 6 Time: Fe 2+ mg/L: Time: Specific Cond. (uS): 1 1.' Time Res. Cl m L Sample pH (s.u.): ' ( Time: Odor: S 1; °1 h4 S K f ortl r Time: 3 3 0 ReDox (mV): --• 1 b 3 Time: Appearance: _ : - L [ i? ,k . Time: ReDox (EH vaIue):YSI ProPlus +200mv 1 Other: Time: General/Weather Observations: Bunn loud rainy) Temp. 5 � (OF) Wind Q' 5 (mph) Sampler Signature: Ry °` n i " Date: / 30 / Z o Stabilization Test Time Purged Temp. (°C) Diss Oxy. (mg/L) Spec. (5) pH (s.u.) ReDox Turbidity Volume remov d Water der (mv) (ntu) (gallo /ml Ll level (ft) 11,1 IZ.r 0.7 3V,)-3 1.S' 13 2p 1#3 C3. 7 3i,%z J3z5 •6 0. 0.2 �e ArAlyffeal * r BLE Name and Affiliation (Sampler(s): i Na.me and Affiliation (Inspector):, Well Information Well tD: `W. it `� Well Diameter: 2 ++n Total Well Depth: 111 O ft Static Water Level: 32,.'73 it Height of Water Column: 38.97 it Document Name: Field data Sheet Document Number: F-CAR-FLD-001-rev.03 Field Data Sheet - ion: As4v,11 t C N R Qace g; Well Locked: r Date Issued: March 8, 2019 Pale: 1 of! _ :eg Authority, Pace Huntersville Qua Office #: unC,. Co. flew L.F Data Sheet Review: Date: 11- 03 r,�6 / NO / Flushmount ) Construction: (V�/Steel/Stainless Steel) Multi Factor.. 0..1 G. [ (Radius/12)2 x 3.14 x 7.49). Casing Volume: (o .3S gallons Cal. 3 VoIumes: I • 05 gallons Pump Intake: ft BY: J D5 Purge Information' ; Date Purged: 10 / 31 ./ o Start: - i 0 ti S -Finish-_Lq30 Purge Rate: Purging Method: Kn3oOf1 Total Volume Purged: 7 500 (gallons/O/L) Sampling Information Date CoHec ted.. I a 3 r: � 147 3 S /"/ Time Collected: O/pm) Sampling Equipment Used: Mo n 5 a eh Instrument ID: j 3 q 7 a TP'w rS Ss Bottle Type Preservation Analysis Required tAe"IS 3 ~VO-A Wct V a C Field Measurements Observations Sample Temp (°C): 9.1 Time: I a 3 S Turbidity (ntu): 5.3 Timer 1035 Dias Oxy (mg/L): O -.� Time: ) 0 3.5 Fe 2t mg/L: `-- Time: Specific Cond. (uS): 50- 5 Time: 1035 Res. C1(mg/L)/(µg/L): `— Time:. f Sample pH (s.u.): ' ro . Z Time: 103 5 . Odor: 90" Time: 075 ReDox (mV): 6.3 Time. .10 3 S AppearanceCleo'r *tates Time: r a 3 5 ReDox (EH value):YSI ProPlus +200MV - Z 11"a'- 3 Other: — Time: — General/Weather Observations: . (sunny/ l�u y/rainy) Temp, 59 (-F) Wind !I (mph) Sampler Signature: Date:_ 10/$0L2 O Stabilization Test Time Temp. Diss Oxy. Spec' . pH (s.u.) ReDox Turbidity o ume removed Water Other Purged (oq (mg/L) (oS) (mV) (ntu) (gallons/io/ level (ft) L o.0 417- 12.q 5a o 33.YG F�D UP (ai5 10•2 O.G �y,$ 6.? 27.o q,g 000 33-13 I� Z c to •o o . C 5t57.G - 7 25.1 .3 Wat 33,U- lots 10.0 11.6 qSZ-0 C.'7 Mt C•2 mob 34.13 103� Q.8-5 ySi•3 b'.'7 1 . j,$ 2500 _. aeeA nafsfisal ' f Document Name: Field data Sheet Document Number: F-CAR-Fi.D-001-rev.03 I Issuing Uate Issued: March 8, 2014 Page: 1 of Office - Name and Affiliation (Sampler(s):_ KZA K fQ Name and Affiliation gnspector): Well Information Well ID: Mw.1t Well Diameter: J It Total Well Depth: Tk' C1dr ft Static Water Level: 3%•Q- it Height of Water Column: W O ft Well Locked: Construction: Project #: y��G _ i (-%ReW Le rld Data Sheet Review: Date: 0 - 03- V) By: cv� / NO / Flushmount ) Stainless Steel) Multi Factor•: O-1O 3 r(Radius/12)2 x 3.14 x 7.481 Casing Volume: 3•a� gallons. Cal, 3 Volumes: gallons Pump Intake: N`I.wil— . ft Purge Information Date Purged: _/ 2/ _ Start: %01S _ Finish: � Purge Rate: �a Purging Method:Q{vSGiJn „_Total Volume Purged:SGb (gallons rt)s L) Sannvlintr Information Date Collected:. LU . /�_�3apn Time Collected _WL Q 6/pm) Sampling Equipment Used: OnbW 11 Instrument ID _qC�.'�t�' Bottle 'Type Preservatipn Analysis Required Field Measurements Observations Sample Temp (°C): 1u .0 Time: Turbidity (ntu): a. q Time: u .0 Diss Oxy (mg/L): Q') Time: �k` Fe 2+ mg/L: ^""^"— Time:. - i3 IDl3olc Specific Cond. (uS): -13i,? , Time: Mo Res. Cl (mg/L)/(µg&): Time:. Sample pH (s.u.): Time: L Odor:-, i.) �`J Time:�� ReDox (mV): _ - 4U - I µ Time: 110 APpearanceS_ 1% �csPfic+�lcrtxime; L 1 L4 ReDox (EH value):YSI ProPlus +200mV )MU- i Other: Time: ~--� GeneraMeather Observations: . I � sunny/(ou /rainy) Temp. !! (°F) Wind 5 Ica (mph) Sampler Signature:Dater Stabilization Test ti Time Temp. Diss Oxy. spec. PH (s.u.) ReDox Turbidity Volume removed Wafter Other Purged (°C) (mg/L) (US, (mV) (ntu) (gallons/iUY level (ft) L o. 4E t (o 3 34, I. 6-7 Los.I (o. (oa. 15.3 3x 5-1 La 1�3v q 0.a . ►�. �o-ca 13,8 ►��� v5D Q LAti fo3� 4.1 0.1 -a- . I &-co tLL-1 I5'K I�-vz 30:4 Lt W, Document Name: Document Issued: March 8,2019 or Field Data Sheet Page)wf 9� Document Number: F-CAR-FLD-001.rev,03 Issueing Authority: Face Huntersville Quality Office Client; 'Reviewed Date and By: Stabilization Test ___-�- 0.040 -1-625 Spec. (US) Turbidity : circle one water level �eAnalyffc,W' f Document Name: Field data Sheet Document Number: F-CAR-FLD-001-revi.03 Date Issued: March 8, 2019 Page: 1 of Authority; Pace Ht Office . LF, tvi Name and Affiliation (Sampler(s): NIK.1 N 1�-H 1 ('! Name- and Affiliation (Inspector):_.. 'IQ Well Information Well ID: Mw — 2l) Well Diameter: Z �n Total Well Depth: Sg• �S ft Static Water Level: .6`J -ft Height of Water Column: q 4• q 0 ft Well Locked: NC Project #:Akn.0 . Co. LFNtW r ata Sheet Review:: - t� 3 By:S (08 / NO / Flushmount ) Consttuction: (&/Steel/Stainless Steel) Multi Factor'`; 0.103 l*(Radius/ 12)2 x 3.14 x 7.481 Casing Volume: .o S gallons Cal. 3 Volumes: . U • 15 gallons Pump Intake: _! 5 ft Purge Information Date Purged: I* / 3 a / . 2a Start: j Q 10 Finish: 12 Z S Purge Rate: C] O /K•n Purging Method:_. Ptris`F4I� : 40''""�_Total Volume Purged: (5 0 (gallons/(D/L) SahlPling Information Date Collected:^10. /� Zo . Time Collected: 2 3 Sampling Equipment Used:, _Instrument ID:__ Ys�3+�? a 'rPWiSs� BottleType f Preservation {Analysis Required L.50 -ML. l�iC _ � 1J0 •� _ _ I"t�70.�S . 3 — VO HC� V oC _.. Field Measurernents/Observations Sample Temp (°C): Time: j Z ?✓ 0 Turbidity(ntu). 0. 8 Time: 2 3 n DissOxy(rng/L): Z•S Time: 1230 Fe2+mg/L: 777 Time: �. Specific Cond. (uS): Z7 •9 Time: 2 3O Res. C1(mg/L)/(µg/L): Time:. Sample pH (s.u.): C • S' Time: - � 23 o Odor: Time: 1 i 3 O ReDox (mV): s' 6 Time: . 12 3 O Appearance: Ck4C' Time: 2 ReDox (EH value):YSI ProPlus +200mV S Other: Time: General/Weather Observations: . (sunny/c ud /rainy) Ternp.52 (OF) Wind 1 (mph) Sampler Signature: Date: r OI 3 O /e O Stabilization Test Time Purged Temp. (°C) Diss Oxy. (mg/L) Spec' Cond. pH (s.u.) ReDox (mV) Turbidity (ntu) o ume removed (gallons/(q/ Water level (ft) der (uS) L 2 55 13•1 Z C.5. r.8.2 o.b Soo . CCU - DO 13.5 It 27IA ,S G I 0.8 �— — OP 1210 3.8 2.6 270.1 G,5. 70.q o {odo $,q$ IQ25 13.8 2.5 �.71. 0 .S `73.6 j.o 1Saa 9.9 9 Document Name: Field data Sheet Date Issued: March 8, 2019Pa aGBl�xfa e: 'of 0' Document l�iumtrer: F-CAR-DOl-rev.03 Issuing Authority: Pace Huntersville Quality. �� Office Name and Affiliation (Sampler(s):_ Name and Affiliation (Inspector):_ Well [reformation Well ID: AAA Well Diameter: a t 4 Total Well Depth: 4-). � � ft Static Water Level: « iv ft Height of Water Column:_15_,;Oft Well Lacked: Construction: Project #:DLS_()_( Field Data Sheet Review: Date: 11G3 ZO / NO / Flushmount ) Steel/Stainless Steel) Multi Factor*: 0• t03 r(Radius/12)2x 3.14 x 7.48] Casing Volume: A1177.gallons. CaI.3 VoIumes: "`l •' gallons Pump Intake: at . (n -k-l" it By: �S Purge Information Date Purged. P 2�2 / .ram Start: Finish: 141.0. Purge Rate: Purging Method: t, tS IZQ t C Total Volume Purged: V,Q&b (gallons/(i�IL) Samvlinz Information Date Collected: 1 �% / v/_ Time Collected: I L4 15 (am/&m Sampling Equipment Used: �� `+'s tl'1-2'L . Instrument 1D�_ Bottle Type Pmervati4n Analysis Required P,\ L Field Measurements/Observations Sample Temp (°C): LA - ( Time: Turbidity (ntu): Time: 4 415 Digs Oxy (rng/L): Q Time: ilf5 Fe 2+ mg/L: Time: Specific Cond. (r1S): ��«, Time: `eti� Res. CL Sample pH (s.u.): CQ- _2> Time: IL05 Odor: Li is ReDox (mV): 3 Time: Appearance:5MUl&(ham(ate3Time: R{l�_ ReDox (EH value):YSI ProPlus +200mV 33. 37 Other: — Time: � General/Weather Observations: . sunny/(1ou /rainy) Temp. ff) Wind (mph) . / Sampler Signature: �/_ _ Date: Stabilization Test Time Temp.Diss Ox Spec' C pH {s.u.} ReDox Turbidityremoved Volume Water Other Purged (°C) (mg/L) (oUs, (rnV) (ntu) (gallonsins level (ft) (0 3 Q IAW l.lV I [;�j o,) ql,4 -1 Co.q •s-cQ 0"6.0 �Iw .1[ .$ qko A [.o.LP ILtO-t ® 1 13.E 0.4 1 L04•q U.-3 1s vS to&c) �q -?-+( a- WaD 1-12ceA11813111 caf Client: Location: Project:_ Document Name: Field Data Sheet Document Number: F-CAR-FLD-001,rev.03 Well ID- MW - a 5-2 Reviewed Date and By: J1*0' �0 05 Stabilization Test Document Issued: March 8, 2019 Page) -of 0 Issueing Authority; Pace Huntersville Quality Office 1. 1.625 0-1.050 4 0,65,30 1,4680 2.6,100. Time Temp. Diss Oxy, Spec. Cond. pH (s.u.) ReDOX (MV) Turbidity Volume Removed (gallons/o/L)ift} Water level other Purged (OC) (mg/L) (us) (ntu) circle one (D Li LAT-A 1119 LA QU - Q -TL LAV�� (08. k s C�vo 05- 6-1 LAS5, o 0--; LK, o S) - -7 (6 Loo '7,0 -7 o. k Ltu&"� (0,9 43,q 9f. .1 7000 OLt L) ILAA 011 LOU.] U U, I are-J bA (2. LP ao. 1(4.1 0.1 LJ 613. C,7. 33--7 1;. q i . I aAM&Ycal a � Document Name: Field data Sheet Date Issued: March 8, 2019 Page: I of a Document TQumber: F-CAR-FLD-001-tev.03 Issuing Authority: Pace Huntersville {duality. Office Field Data Sheet Client: B L F- _ - Location: A S V.vr ! � sz., N r- Project #:'6-n c o rv'�e (5 Name and Affiliation (Sampler(s):_� �G.ca ly f7 ram, { Field Data Sheet Review: Name and Affiliation (Inspector): ij i Well Information Date: � � � ti � - z � BY: �f Well ID: iM W -� Well Locked: YE / NO / Flushmount ) Well Diameter: a"' Construction: e/Steel/Stainless Steel) Total WeIlDepth; CI . Q __ft Multi Factor*: a- i L- [ (Radius/12)2 x 3.14 x 7.49). Static Water Level: S a ft Casing Volume: ?L �� gallons Height of Water Column: 13tiG1 ft Cal. 3 Volumes: 4, �F gallons Pump Intake:_ '16 •S-4 _ . ft Purge Inforjnatton Date Purged: 1 0 / 0/ 7M-�Q Start: 0 0 Finish: I L` Purge hate: L7 Q m z r A s Purging Method: fY1se4$x ^Total Volume Purged: �1 000 (gallons L) Sampling Information Date Collected:. E �k b Time Collected:) Li �— (am%DR`}� Sampling equipment Used: c -Lo n �� Instrument lD:_yS� Bottle Type Field Measuretnent Observations Preservation Analysis Required Sample Temp (aC): Time:_ '-1 `-1 Turbidity (ntu): Time: Lt Lf [� Dins Oxy (rmg/L): L S-- Time: Fe 2+ mg/L: Time: Specific Cond. (uS): Time: L�Res. Cl (mg/L)/(pg/L): Time:. Sample pH (s.u.): Time: Odor: AJO Time: "t-{ C ReDox (mV): i rJ Time: ) ( L-V Appearance: _-- L(-Ur' Time: I `1 ReDox (EH value):YSI ProPlus +200mV ( Other: Time: General/Weather Observations: . / on rainy) Sampler Signature:. Stabilization Test Wind--LC�L—(mph) Time Purged Temp. (°C) Diss Ozy. (mg/L) Spec. (S) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/xi / L Water level (ft) Other I LA 6'�- I -I, 1-31•4 I 6s" 1 6 - H ITi.3 -T —1.4 l� 1 . L. M$1•3.. a,� ►a.a l o c� Gs 3 -___. I �0 .B Ln I l--l-q c , n 1(.5'. `-� Document Name: Documera Issued: March 8,2019 Field Data Sheet Page (�,-f D- Document Number: F-CAR-FLD-001.rev.03 is5ueing Authority; Pace Huritersville Quality Office VVeU|t): RevIewed Date and By: i Sobilization Test .~--�- 102-11*8 1-625 13.3671) 2.6100 Time Purged Spec. Cond. (us) Turbidity (ntu) qwfw-,L . 011me REM-' (gallons/g/1.) circle one Water level Ark7page: acelytiea!° Document Name: Field data Sheet Date Issued: March 8, 2019 1 o€2 Number: F-CAR-FLD-001-rev.03 Issuing Authority: Pace liuntersville Quality. �., � ,Document . Office . LE Name and Affiliation (Sampler(s):_ $Sk Field Data Sheet SK1011Nt,,(AG Project#: Bunc.m6o. Co. Ntw LF Field Data Sheet Review: Name and Affiliation (Inspector): Well Information Date. l t 0 �, Z �' Well ID: i_o Well Locked: ( E / NO / Fluslunount ) Well Diameter: �tn Consttuction: /Steel/StainiessSteel) Total Well Depth: ? ' S ft Multi Factor: NO r(Radius/12)2x 3.14 x -48) Static Water Level: ft Casing Volume:•►• O gallons. Height of Water CoIumn:304- y ft Cal. 3 Volumes: S. 0 3 gallons Pump Intake: 15 ft Mb Purge Information Q �/ Date Purged 10 / SO / 20 Start:_ 1.410 Finish: 14 5 0 Purge Rate: ` � "7""' Purging Method: C `d Aso o n Total Volume' Purged: Z� o (gallons/ ]� L) Sampling Information Date Collected: '" . /o / '2a Time Collected: (am/0) Sampling Equipment Used: iu ° n�O ° �1 Instrument ID:_ YSI *3 47 ;1 j TPW * IS'Cr-*- Bottle Type 3 — VoA - 901D awl. Z50 ML ptasL; c Field. Measurotnerits/Observations PreservatiOn NtJos �(GL V n�sesecv$ VnQcesccyeo�l_ _ Analysis Required Mal als vacs .,.. ._. T' S 5014 ICI Sample Temp (°C): {'Z • S Time. 1 ASS Turbidity (ntu): 6 • S Time: i y s S Diss Oxy (rng/L): a• 5 Time: y ss Fe 2+ mg/L: Time: 'r Specific Cond. (uS): 2• t Time: Res. C1(mg/L)/(µg/L): Time:. Sample pH (s.u.): • 5 Time: 4 SS . Odor: IV an 6 Time; { q $S ReDox (mV): 5 f• 3 Time: 55 Appearance: _ C f t a r Time: S S ReDox (EH value):YSI ProPlus +200mV 2 51. 3 Other: Time: General/Weather Observations:_. (sunny/ <ub/rainy) Temp. s q(°F) Wind f 1 (mph) Sampler Signature: Date: 1 30 ZO Stabilization Test Time Temp, Diss Oxy. Spec. Cond. pH (s.u.) ReDox Turbidity Volume removed Water Other Purged CC) (log/L) (mV) (ntu) (gallons/rta/ level (ft) HIS 13.3 0•8 Z't3.2 $.1- -70-1 1.5 . qso DVP 3.3 0.4 Z73.3 1420 1y.c o.0 277.2 2.1 CY.-1 $.0 qID 6'8.+�o R.rk:o 1 q Zs fu o,S At7g.q •0 Co- o o Go - Be 1450 113.2 0 •S Zy6.2 7•$ 1 58.E $.2 1 Soo Q,Zo ;4a Document Name: Field Data Sheet Document Number: F-CAR-FLD-001.rev,03 Client: BL Location:- 4eville, MC Project: _ 51AAC. C Well ID: MW - Ib Reviewed Date and By: 11- 0 S- 9,0 Stabilization Test Document Issued: March 8, 2019 peee?j Issueing Authority: Pace Huntersvitle Quality Office DJUltip-11cation Facbox* i 7— 0.04138 0.0913, GAGSO 2 01630 4 0. 2.61100 Time•Turbidity Spec. Cond. Volume Removed (gallons/JOL)• Water level (ft) Purged (us) (ntu) circle one Document Name: Field data Sheet aanL_ c��,naaFy��e�at" f L Name and Affiliation (Sampler(s): Name and Affiliation (inspector):y Well Information 3 Well Locked.' Well Diam'-ater: Construction: Total Well Depl Static Water Level: - Height of Water Cc Purge Information Date Purged Purging Method:_ Samvlinw Information Multi Factor*: — Casing Volume: Cal. 3 Volumes: Pump intake:_ Document Number: F-CAR FLD-001-rev.02 Field Data Sheet Project #: L- Z + S Data Sheet Review: ua[e 185ueu. Page, 1 of Issuing Authority: Paee Huntenville Office Date: By: ( YES / NO) (VC/Steel/Stainless Steel) r(Radius/ 12)2 x 3.14 x 7.481 gallons gallons Start: Finish: Purge Rate: Total (gallons/mis) Date Collected. - I e / / 2 Time Collected: it (am/@m Sampling Equipment Used: D ) a 0 8 s j a c -Instrument iD: s r Bottle Type Preservation Analysis Required Field Measurements Observations Sample Temp {°C): IP, i 6`� Q } , 7 h Time: �-_2 Time: Turbidity (ntu): Diss Oxy (mg/LI : a = 3 1 Time: �"a Fe 2+ mg/1_.: Times'— Specific Cond. (uS): q Tine: 6 WO Res. Cl Sample pH (s.u.); _ i Time: !t Y" a Odor: D ` ` Time: ReDox (mV): Time: l b r-') Appearance: 0-6-1- Time: f b� ReDox (EH value):YS1 ProPlus +200mV 1 • L, Other: rate: GeneraVWeather Observations: (s g r/cloudy/rainy) Windy L (mph) Sampler Signatur . - '�r Date: fi{"a }lY�Y7a{'Y flt4 7'ae4 Time Purged Temp. (°C) Diss Oxy. (mg/L) Spec. Cond. (US) pH (s.u.) ReDox (mV) Turbidity (ntu} Volume removed (gallons/mis) Water level (ft) Other Document Fame: Field data Sheet I Pa¢e: 1 oft Document Dumber! F-CAI{-FLO-OR-rev.02 _ office Field Data Sheet Client: C Location: Av✓c. GTr✓c Projects: Name and Affiliation (Sampler(s). P t ' �a c e Field Data Sheet Review: Naive and Affiliation ('Inspector): � B Well Information Date: (( L - Zo �'�� - - We YES / NO)._ Well Construction: (PVC/Steel/Sta' sSteel) Total Well ep : ft Multi Factor*: adius/I2)2,1 3.14 x 7.481 Statzc Water ,LeVP�_� ft Casing V e: gallons Height of Water Ca�1 tux.-~-w ff C . 3 Volumes: gallons Pump Intake: Ptw e Information Date Purged: Purge Rate: Purging Method: Total Volume (goons/zds) Sampling Information Date Collected: L� -/ P/ Time Collected: Sampling Equipment Used: DISI Instrument ID: `? S • Battle Type Preservation Analysis Required J-& I, v U ,@ Vp- Field Measurements/Observations Sample Temp (°C): '),'7 .. Tirne: l6 ° Turbidity (ntu): - 6 ➢iss Oxy (rng/ L): 2° 4� 3 Time: Fe 2+ mg/L: Brie: Specific Cond. (uS): 3 7 7 Time:. 4 5 Res. Cl Sample pH (s.u.): b Ti,,:b a Odor: 5Time: ReDox (mV): ' 6 `- �� r � Time: b � ' Appearance: �`��`�"Time: ReDox (EH value):YSI ProPlus +200mV 13 S _ t Other: A s Al" 1-.,0 Time: OeneraWeather Observations: v (sCy/cloudy/rainy) Temp. (°F) Wind to (mph) Sampler Signature: �/�--' Date: Time Purged Temp.Diss (° C) Ox . y (mg/L) Spec Con d. on H p (su. ) Yoluine ReDox Turbidity Water removed Other (mV) (ntu) (Sallans/mis} level (ft) Document Name: Field data Sheet I v ?age: 1 of Document Number: F-CAR FLD-001-tev,02 I office /6 0 Field Data Sheet 1I r Client: G Location: Ulf A iIC Li Project#: L- J Name and Affiliation (Sampler(s): & % L r,ce - Field Data Sheet Review: Name and Affiliation (Inspector): r12JA- Date: ! 1 - G 3 `Z-0 By: Well Information China 7L1 L l� S Wehvcked: ( YES / NO) 7taticWater Depth: ft bevel: ft Height of Water Column: ft Parg Information Date Purging Constxu Lion: {PVC/Steel/Stainless Steel) Multi Pact r*: r(Radzus/12)2 x 3.14x 7.481 Casing Vol e: gallons Cal. 3 Volumes. all Pump Intake: ft Start : Finish: Purge Tate: Total Volume Sampling Information Date Collected:_-�Z/ / i- o Time Collected: r 61 0 (am/(F (gallons/mis) Sampling Equipment Used: Qr s,p �c / N Instrument ID: V/ T �l �l t�L ��� Z Z Bottle Type __ �j Grjs � •L Pres,mation .Analysis Required Du�ti 1 L o C 4 Field MeasuirementsQbser_vations Sample Temp (°C): 1q + Time: b O Turbidity (ntu): 6 �r Time: % u Diss O, y (mg/L)-. Al7 Time: h J.O Fe 2+ mg/L: Specificond. (u��: 7 7 Time:. b �� Res. CI Sample pH (s.u.): --12 Time: /'� Odor: V..a , Time: ReDox (mV): , %Z 7, � Time: b 1 � 0 Appearance: earance: ReDox (EH value):YSi ProPlus T200mV Time: 6 10 GeneraWeather Observations: r^� (sib /cloudy/rainy) Temp. 7f ('F) Wizlcl � C(mph) Sampler Signature: '7 , e Date:_ / D Stabili7nfinn Tacf Time. Purged Ternp. (°C) Diss Oxy. (mg/L) Spec. p Cond. (us) pH (s_u.} Irct- me ReDox Turbidity xeznoved Water Other (IT (ntu} level (ft) (ga�Lons/mis) Document [Name: Field data Sheet 1 Pa¢e: I of Document Number: r-CAR-FLD-001-rev.02 Office ]Field Data Sheet Client: L%z Location: %%oe Project#: L !� Name and Affiliation (Sampler(s): / 7,1 Field Data Sheet Review: Name and Affiliation (Inspector): o Date: (. � � � 'Z.- .� By: Well Information W449_ - /. 7 ° Well Lo d: ( YES / NO) W7ofWa Construction (P Steel/Stainless Steel) To: ft Multi.Factox*: E*(Ra /12)2x3,14x'/-A Stael: ft Casing Volume: gallons HeColumn: ft Cal. 3 Volumes: gallons Pump Int ft 'urge Information Date Purged: / / Start: Fires Purge Rate: Purging Method: Total Volume Purged: _.-�-- Sampling Information Date Collected: fy / 2--"/ 2'a Time Collected: Sampling Equipment Used: .0 3 e, $ �. Instrument ID: LI 5 L q tt $6 2 4 I Bottle Type Preservation ,Analysis Required V`" I yf G f ZlUt 0 u(I(_ Field Measurements/Observations Sample Temp (°C): 2� Time: 7 Ste' Turbidity (ntu): TLme: Diss Oxy (mg/L): i` Time: Fe 2+ m L: Specific Corid. (uS): S^ i 7,. LF Time -..Res. Cl (mg/L)/(µg/4 Time: Sample pH (s.u.): Time: Odor: O'L/L_ Time: 3 ReDox (mV): 3 '� Time: 7 1 Appearance: —Tirane:—% 3� ReDox (EH value):XSI ProPlus +200MV f t- Other: R s �� ► Time: General/Weather Observations: uru /c3.oudy/rainy) Temp. _2? (°Fj WindR v _ (mph} Sampler Signature: Time Purged Temp. (°C) Diss Oxy. (mg/L) Spec. Sp (US) Cond pH(s_u.) Volume ReDox Turbidity removed Water Other (mV) (ntu) (B level(ft) ailons/ mis) 173� Document Narne: Field data Sheet Date Issued: March 8, 2019 CeAnnllaly 1 of-( Document Numbbr: F•CAR-FLD-001-rev.03 —Page: Issuing Authority: Pace Huntersville Quality Office . Field Data Sheet L—F- Name and Affiliation (Sampler(s): A n 41 ca,( Name and Affiliation (inspector):- .N 0 Well Information Weu ID: . Up Z . Well Diameter: Total Well Depth. f Static Water Level: ft Height of Water Column: f ft Purge Information c Project #: nc9 p/i bt Ca. A c�+.-c L� Data Sheet Review: Date: It - 0 3' -"-(5 By: )0-5 Multi Factor*:_ � � [(Radius/12)2 x 3.14 x 7.48] Casing Volume: gallons. Cal. 3 Volumes: gallons Pump Intake: ft Date Purged: / / Start: Finish. Purge Rate: ' Purging Method:, , _,_Toted Volume Purged: J (gallons/mis/L) Sampling Information Date Collected:. L 4 . /3o /. , n o Time Collected: i `l Q &pm) Sampling Equipment Used: 6cV-6 Instrument ID: � , 4 I�Ixa°• Bottle Type Preservation Analysis Required Z00cs i-.cnt&5klP Field Measur tnerit Observations Sample Temp (°C): S Time: Ci Turbidity (ntu): a Tim& Ld D Diss Oxy (rng/L):. - Time: 1 I C4 Fe 2+ mg/L: Time:. I'-ti1 Specific Cond. (uS): LA S11 Time: 4 l qD Res. Cl (mg/L)/(µg/L): � Time:. Sample pH (s.u.): 6 4 Time: l 1 y Q Odor: Time: l 1 L-f Q ReDox (mV): _ Li 3 _ Time: Appearance: GId t r wI c T-lme:_ I i -10 ReDox (EH value):YSI ProPlus +200inV a'�3 ,-3 --Other: Time: General/Weather Observations:_ . (sunny/ ou /rainy) Temp.�'-7 (7) Wind I (mph) Sampler Signature Stabilization Test Time Purged Temp. (°C) Digs Oxy. (mg/L) Spec. { S) pH (s.u.) ReDox (mV) Turbidity (ntu). Volume removed (gallons/mis/ Water level (ft) Other .�' dCBi{flc?i]�lEal w f Document Name: Field data Sheet Document Number: F-CAR-FLD-001-rev.03 Date Issued: March �, 2019 Page: 1 of Issuing Authority: Pace Huntersville Quality Office Field Data Shet ' Clienf: �-�' _ Location: A 1"�Z , uC Pioject #:u�Eo rytaaRCQ, A c.�nr e. L-. Name and Affiliation (Sampler(s):TG7 - VCU-Q A nest ,, 6 0,� Field Data Sheet Review: Name and Affiliation ns ector N � it P ): � --- Date: � i ' 8 3 ' 2O By: Well Information Well ID: _`c�C.h au 1_i� t) , Well Diameter: Total Well Depth- 1 ft Static Water Level: ft Height of Water Column — ft Purge Information SSc-iusta�e�ien:-- f PtFC�Stee.1�taittlessSteel)-- Multi Factor":['(Radius/ 12)2 x 3.14 x 7.48] Casing Volume: gallons Cal. 3 Volumes: "` gallons Pump Intake. r ft Date Purged: / / Start: Finish: �- Purge Rate: Purging Method: _ Total Volume Purged: (gallons/mis/L) Sampling Information Date Collected:. 1 C / 3�i/moo Time Collected: l am/pm) Sampling Equipment Used: G rab Instrument ID: YS cAnIA r 0),g� lMg(ro7'owif 30-3m Bottle Type Field Measur tnerits Observations Preservation Analysis Required Sample Temp (°C): . I `� Time: 1 1 Turbidity (ntu):_ Time: 1 C Dias Oxy (rng/L): _ =� Time: 1 i S Fe 2+ mg/L.- L�b ;Time: I I E Specific Cond. (uS): �� Z„ Time: 1 l _ Res. C1 (mg/LY(ug/L): Time:. Sample pH (s.u.): _ - L-t Time: ] St Odor: Time: 111� rr f�� > ReDox (mV): l�'8 _ � � ' Time: ) 1 � Appearance: Time: 1 , ReDox (EH value):YSI ProPlus +200mV `x - Other: Time: General/Weather Observations: �. (uriny and /rainy) Temp.L1 p (OF) Wind (mph) r Sampler Signature: Date: Stabilization Test Time Purged Temp. (°C) Digs Oxy. (mg/L) Spec' S) PH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/mis/ Water level (ft) Other alp Document Name: Field data Sheet Date Issued: March 8, 2o14 �, aCsr7Elfieal` Page: 1of Document Num6Er. F-CAR-FLD-ool-rev.o3 Issuing Authority: Pace Huntersville Quality. Office - Field Data Sheet #: Bu. n Ln my�,,o cc • A 0��--- .L�7 Name and Affiliation (Sampler(s). - 'Pc, Ana( 1=0 Field Data Sheet Review: Name and Affiliation (Inspector): N E A Well Information Date: }� - 4� Well ID Ln -- l Well Diameter: Total Well Depth: ft Static Water Level: it Height of Water Column: i t Purge Information C-arlstra a el} Multi Factor`: r(Radius/ 12)2 x 3.14 x 7.481. Casing Volume: gallons Cal. 3 Volumes: gallons Pump Intake: ft By: tom% Date Purged: — / `r / Start: Finish: Purge Rate: Purging Method: Total Volume'Purged: (gallons/mis/L) Sampling Information Date Collected; 1Time Collected---)')' SQ {aC, ) Sampling Equipment Used:. G rg,h Instrument ID: � o g arc c oTpw 3 Bottle Type Preservati6n Analysis Required Field Measuretneras/Observations Sample Temp (°C): 1 Time. � qO Turbidity(ntu): ) a, L4 Time: Diss Oxy (mg/L): 3- Time: 11ZQ^Fe 2+ mg/L: j - - --Time: 1-,d� Specific Cond. (uS): 1 `t� Time: 1 Res. Cl (mg/L)/(µg/L): � Time:. Sample pH (s.u.): Time: 1 Odor: Leac"n & ReDox (m.V): Time: 1 Appearance: _G o Time:_ 1 fit] ReDox (EH value):YSI ProPlus +200r11V ID- , Q Other: Time: -- GeneraVWeather Observations:. su y ouddyy rainy) Temp. (-F) Wind) (mph) Sampler Signature: Date: Stabilization Test Time Purged Temp. (°C) Diss Oxy. (mg/L) Spec. EUS, PH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/mis/ L Water level (ft) Other is / 1.. ase Arrafj�isal ' s Document Name: Field data Sheet Document Number. F-CAR-FLD-001-rev.03 Field Data Sheet Date Issued: March 8, 2019 Page: I of j Issuing Authority: Pace FIuntersvilt+ Office LF— Name and Affiliation (Sampler(s);�( Name and Affi]i-ation (Inspector):_ .nl i A, Well Information WellID• _Lea c6-k?a--n Weh-E�� #: a Co, 4 L-r— Data Sheet Review: Date: i j u 7 - 2,0 Well Diameter. C a ess teel) Total Well Depth: --it Multi Factor*: _ � r(Radius/12)2 x 3.14 x 7.481 Static Water Level: ft Casing Volume: gallons Height of Water Column: ft Cal. 3 Volumes: gallons Pump Intake: It By: �9 Purge Information Date Purged: / / ---- Start: Finish: `— Purge Rate: Purging Method: `` Total Volume' Purged: (gallons/cols/L) Sainolina Information Date CoAected:. 10. 13W p Time Collected. (am� Sampling Equipment Used: InstrumentID:�/ �-T Bottle Type Preservation Analysis Required Lrr� P Field MeasuretnentsjObsery4tions Sample Temp (°C): I 'S� Timer Turbidity (ntu): Time:�(S Dins Oxy (mg/L): Time: Fe 2+ mg/L: Time:. ill Specific Cond. (vS): �. Time: n-I Res. Cl (mg/L)/(µg/L): Time:. Sample pH (s. u.): —Time: N--a ,t Odox: L ce, Gl" , Time: t ReDox (mV): _ _ 6 a . �- Time: 1 1 _ Appearance: ALt)�j Hatt Time: ReDox (EH value):YSI ProPlus +200n1V Other: Time: GeneraVWeather Observations: 1�.�� �n � .5 = S ° 4 ` f � !' /V, -��° 8 • (b 'r„/ Sampler Signature Stabilization Test suxat lou y/rainy) Temp.�Li (°F) Wind_L!-L(mph) X Time Purged Temp. (°C) Dias Oxy. (mg/L) Spec' E n} • pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/nils/ Water level (ft) Other 1Li �nl�vo UULLM LL evauee: rieau uura onee[ Page: 1 of fiTcai Issu ngAut°rity: Pace Hr i Document Number: F-CAR-FLD-001-rev.02 Office Field Data Sheet Client: '� LL 4 Location:_ /,j '�7c :nfal'- G"Project #: Name and Affiliation (Sampler(s)/' Field Data Sheet Review: Name and Affiliation (Inspector): p B Date: �.l 1 " 2 Y c%j Well information WZUQ; Well Locked: ( YES / NO) Weser: Total Well Dep ft Static Water Level: ft Height of Water Column: ft Date Purged:_-__L..___-/ Purging Samvlinizz Information Construction: (PVC/Steel/Stainless Steel) Multi Factor: *(Radius/12)2 z 3.14x 7,481 Casing Volume: gallons Cal. 3 Volumes: gallons Pump Intake: -fe Start: Finish: Purge Rate: (gallons/mis) Date Collected: / C5 /:?) / d Time Collected: Sampling Equipment Used: l�r� ti Instrument ID: Bottle Type Preservation Analysis Required ty I c_ 1/0 C / tF 8 , x�A- 11 AIv Field Measurements/Observations Sample Temp (, C): ! Time: �� 1— Turbidity (ntu): Time: IIl J_ Diss Oxy (mg/ L): A 9 7 Time: /Il aJ Fe 2+ mg/ L: L L e: ' Specific Cond. (uS): 3. 7 Time: 1 ` Res. C1(mg/L)/(µg Sample pH (s.u.): s Z Time: 11 Odor: Time:... ReDox (mV): 3 , (f Time: 111 J- Appearance:� ReDox (EH value):YSI ProPlus +200mv 10. 7 Other: -- — « General/Weather Observations: C 1--3 v �it�a,`Rv�Fy 6¢,1 _(surmy/ �/rainy) Temp. b l ('F) Windo•j—(mph) Sampler Signature: Date] (7 ' 7 ii'a }t77 i �aii nn 'Taai 0Jdr Time Pura T'em p' (IC) Diss Ox y' (mg/L) Spec. Cond, (u5) p H( su:) ReDox (mV) Turbidity (n ) Volume oved Gallons/ s Water level (ft) Other 3.2-,� r Document Number: F-CAR-FLD-001-rev.02 age: x ui Lssuing Authority. Pace Hi Office L Field Data Sheet Name and Affiliation (Sampler(s): M l' S -P- ( ,—' Name and Affiliation (Inspector): Well Information WdHr, S4✓ S t l- 2, Well Locked: Construction: Total Well Depth: ft Multi Factor`:_ Static Water Level: ft Casing Volume: Height of Water Column: ft Cal. 3 Volumes: Project#: S ,/ Data Sheet Review: Date: � % By: )0 ( YES / NO) 'el/Stainless Steel) r(Radius/12)2 x 3.14 x 7.481 gallons - __ gallons Pump Intake: N f Date Purged: / Start : Finn h: Purge Rate: — Purging Method: Total Volume Purge . (gallons/mis) SaMpling Information Date Collected: l / 2 �/ 1 ti Time Collected: m) Sampling Equipment Used: is Lu)�� _Instrument ID: Bottle Type Preservation Analysis Required Field Measurements Observations Sample Temp CC): 1J , I-- Time: r Turbidity (ntu): I � � Diss Oxy (mg/L): y-� Time: Fe 2+ mg/L: Specific Cond. (- S): 4 Time:.—([ `' Res. Cl (mg/L}/(µg/L): 7, 0 // iFG` Odor: /v o ✓e Time. Sample pH (s.u.): Time: (t rJfs ReDox (mV): 35.0 Time: l tea` Appearance: G �d //9a 5 Time: ReDox (EH value):XSI ProPlus +200mV Z •- u Other: ime: General/Weather Observations: C 0 1/0 (sunny/ a/rainy) Temp�-K(°p) Wind 19• ' . (mph) Sampler Signature: Date: % O a Stabilization Test Volume Time Temp. Diss Oxy. Spec. ReDox Turbidity �ternoved Water Other Purged. (°C) (mg/L} Cond, pH (s.u.} (mV) (ntu) aLons/�) level (ft) (US) (S Co YUCaf „ r wcumem !Name: new 0.ata 5neet Document Number: F-CAR-FLD-001-rev.02 Page: 1 of Issuing Authority: Face Huntersvi& Quality Office W Chen Field. Data Sheet ion: "t/,L c' i-,'L—'roiect#: 61 Name and Affiliation (Sampler(s); a �� Name and Affiliation (Inspector):, Well Information T Axi - Well Locked: W eter: Construction: Total Well .De ft Multi Factor*: Static Water Level: ft Casing Volun Height of Water Column: ft Cal. 3 yerlumf Field Data Sheet Review: Date: �'� Z' ZD Byi ( YES / NO) 'VC/Steel/S znlessSteel) x 3.14 x 7.48] gallons gallons Pump Intake: ft Purge Information Date Purge Start : Finis Rate: Purging Method: at Volume Purged: (gallons/n-ls) Sampling information Date Collected:I� / �/ �� Time Collected: Sampling Equipment Used: Cr r �y Ittstrurnent lD;�� �l �' ✓/� } ,; c� Bottle Type Preservation Analysis Required L �_a r , fi Ali -- Field Measurements/Observations r� Sample Temp (°C): 3. Time:/33, Turbidity (ntu): �� S % Time: Diss Oxy (pig/ L): r. Y' 44 Time: 850 Fe 2+ mg/ Specific Cond. (uS): Tune: /33" Res. Cl (mg µg L): Time: Sample pH (s.u.): 7 % Time: PA5 , Odor: /V J C Time: 3 3 C GcTime: ReDox (mV): �'h•7-- Time:. f i ";Appearance: - ReDox (EH value):YSI ProPlus +200mV A �f xA Other: une: GeneraWeather Observations: tl^0 rz--'— sun�ryy—]cloudy/rainy) Temp 7l' ff) Wiad ��' mph) Sampler Signature:. /"�'f��—� - Date: / O' Si'ahi7i7a+in1n ` AI-4- Time Purged Temp. (°C) Diss Oxy. (mg/L) Spec. (on ' pH (s.u.) ReDox (mV) Turbidity (ntu) Vol�arne Toll ed reimov(oallon/ } s n is Water level (ft). Other Sl!u i U—UAI ci« ivau e: rrxcxu uaca Z)neex Document Number: F-CAR-FLD-001-xev,02 I Issuing ge: 1 of Pace Huntersviile Quality Office Field Data Sheet S C✓ J Client:_ L. e Location:i6✓w ( d, — Project li: Name and Affiliation (Sampler(s): /L11/ 1 PAC{ Field Data Sheet Review: Name and Affiliation (Inspector): �,-, : B ]] 1l Well Information Date: ).�' � L` 2 y (1/ Well ID: Well Lock- t ES / NO) Well Diameter: ConstrZL14x inlessSieel) Total Well Depth: ft Multi F)2 x 3.14x 7,Q8j Static Wate vel: ft CasingllonsHeight of Water o umn: ft Cal. 3 onsPump ft Purge Information nformation Date Purge Start : Finish: Purge Rate: Purging Method: �77T�cotalolume Purged: (gallons/Iris) Date Collected: I U Z -0 Time Collected: Sampling Equipment Use �"� Instrument ID: �y Bottle Type 1 A �h J-7i1 6 Vr /r Preservation fl L L Analysis Required u Field Measurements Observations Sample Temp (aq ' Time: ! V Turbidity (ntu): Time: �� Diss Oxy (mg/L): 3 12, Time: ' v Fe 2+ rng/U e: Specific Cond, (us): Time: Res. Cl (mg/L)/(µg/L): `Time: Sample pH (s.u.): . Time: 1 a� Odor: rya �,c- Time: 1 � � o ReDox (mV): Time: 1 tea` Appearance: Time: I' ReDox (EH value):YSI ProPlus +200mV �Z. Other: rzn e: General/Weather Observations: ✓r✓a cloudy/rainy) Temp.77"a (°F) Wind �' � (mph) Sampler Signature: �� Date: Stabilization Test Time Purged Temp. X) Diss Oxy. (mg/L) Spec. on . (US PH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed {gallons/ Water level (ft) Other �,Z 17, b b. GE?ff" f LJ IJI.LLLl LL LNWI=. rltlU 44[4 DLIPCi Document Numbex: F-CAR-FLD-001-Fev.02 Page: 1 of fssuing Authority: Pace T-Iunte�'sville Quality Office D 0 o C M 013e Name and Affiliation (Sarnpler(s): n7 C' � PGe.e. Name and Affiliation (Inspector): _ _ �- Well Information Iq444-14.., sGv " j` Well Locked: f � S % C I �r/x t• I'rOjecf #: S� Field Data Sheet Review: Date:, ). " � By: ( YES / NO) (PVC/Steel/Stainless Steel) Total Well ➢epth: Jt Multi Factor": r(Radius/12)2 x 3.z4x 7.481 Static Wafer Level ft Casing Volume: gallons Height of Water Column: ft Cal. 3 Volumes: gallons Pump Intake: ft Purge luformation Date Purge Start : Finish: Purge Rate: Purging Method: T©+ai V-Q1 e Pur e : �� (gallons/3s) Samplirt Ig_z>:for.,_rnation j/r _ Date Collected: /� " Time Collected. r Y' i Sampling Equipment Used: Cr r� Instrument ID: �s `� G �� Bottle Type Preservation Analysis Required "6-A Field Measurements Observations ] _ Sample Temp (°C): 1�Time__Turbidity (ntu): Time: Diss Oxy (mg/L): Time: Fe 2+ mg/L: T' Specific Cond. (US): ( Time: Sample pH (s.u.): Time: Odor: - Time: ReDox m: 3 e i, Time:! il C I�-- ( V) Appearance: Time: ReDox (EH value):YSI ProPlus +200mV ` J- ', Other: Time: General/Weather Observations: -klJ A✓ cloudy/rainy) Temp. `�D (°F) Windy' r (mph) (s� Sampler Signatur : t��� Date: `7' gfahiii�%44nn Taa4- Time Tux Purged g Temp. ( °C ) Diss Oxy. m L ( g/) Spec. Cond. (US) pH (s.u;) ReDox (mV) Turbidity (n�) Volume xernoved (gallons/uds) Water level A. Other 1 L 3-7 32,E S� ._ LIUL UIIIC1LL 1VAAAIC. i 11" "ILI "11c k age: A UL Aflvb'M=f ` Issuing Authority: Pace H( Doctiment Number: F-CAR-FLD-001-mv,02 Office Field Data Sheet Client:..... a _Location: & `--r- ' a Project #. Name and Affiliation (Sampler(a): i'� P- 4" Field Data Sheet Review; Name and Affiliation (Inspector): 7 - 7o B : ,�(J Date: 1} i Well Information B� sG�1 Well W Construction: (PVC/Steel/St ' essSteel) Total Well Depth: ft Multi Factor*: ['(R s/12)2 r 3.14 x7.481 Static Water Level: ft Casing Volume: gallons Height of W ft Cal. 3 V mes: gallons Pump Intake: Purge Information Date Purged: / / Phiish: purge Rate:_ Purging Sampling Information Date Coliected:Time Collected: ZE3"— (ani& Sampling Equipment Used. ` s Instrument ID: �f ST `t 6 �I z `t f Bottle Type Preservation ALttalysis Required Field Measurements Observations Sample Temp (°C): tS • - Time:_J!t�J_ Turbidity (ntu):±z Time: Diss Oxy (mg/L): �� / Time: t—F -�—Fe 2+ mg/L: Specific Cond. (u5): J 1 7, c7 Time: � i� � � Res. Cl (mg/L)/(µ9A): Sample pH (s.u.): une.—----""- 6�p Time: S Odor: N o ( Time: � -- ReDox (mV); � � �, `� Time: APPearance: ReDox (EH value):YSI ProPlus +200mV jLt - i Other: General/Weather Observations: t/ w 117 W /cloudy/grainy) Temp 1(°� Wind -'Jr --(mph) Sampler Signature:&/ t' Date: f L? " Stabilization Test Time Temp. Diss Oxy Purged (°C) (mg/L) Volume Spec, ReDox Turbidity Water Cond. pH (s.u.) (mVj ntu rernaved level (ft) (US) { ) (galians/mis) Other ee AFi213c21C f { f V VLLL11LC1LL LYAlALC. i'Ac1u ,�aLQ �i « Page: r uL TssuuLg Authority: Pace HuntersviIIe Quality Document Number: F-CAR-FLD-001-rev.02 Office �� 1 client:L Field Data Sleet Location:�� U..�L A C+iyP �Project #: � ` ' 5 Sheet Review: Name and Affiliation (SamPler(s): EDa Name and Affiliation (Inspector): A { ? d By: #, Well Information G47 r,/ d6- A313 Weff-ft�— 5 W - We d.: (YES / NO) Well Diame Construction: (PVC/Ste tainlessSteel) Total WellDeptlh: £t Multi Factor*: (*(Radius/t2)2,,3.z4x7.481 Static Water Level: ft Casing ume: gallons Height of Wat olunnn: ft C . 3 Volumes: ga]70 Pump Intake: It Purge Information. Date Purged: Start : Finish: Purge Rate: Purging Method: Total Volume ged: _��� (gallons/mis) Sampling Information G— - Date Collected:/ ,o/ Z ,0 Time Collected: r Yo p (ani/Cili)) zl Sampling Equipment Used: l�Ur Instrument ID: Bottle Type Preservation Agalysis Required I/„%3 Field Measurements/Observations / . g U Sample Temp CC): b i Time: r7 Turbidity (ntu): t 1 Iime:W [ 7 Diss Oxy (mg/L): , f Time: }_� _._____— Fe 2+ mg' Time: Specific Cond. (uS): Z? Time: _Res. Cl (mg/L)/(gg/L): Time: IS �' Sample pH (s.u.): �. f Time:. Odor: S 1 e &R T Time: ReDox (mV): 1 s a `lime: - O � Appearance: flw, Time:. � J� ReDox (EH value):YSI ProPlus +200mV 3 Other: Time: Genera]/Weather Observations: � "L`L` _( army/cloudy/rainy) Temp. 7J (°F) Wlnd 0' s (mph) Sampler Signature: ' ��� Date: / 0 ' 2, 7" J. o � JMk " i'a e: 1 of fssui gAuthority: Pace Huntetsville Quality r Document Number: F-CAR-FLI}-001-zev.02 Office ( Field Data Sheet r ] r Client:__ L Location: )3 fh-k t roject 9:� Name and Affiliation (Sampler(s): M l� " ��� e .E Review: Naive and Affiliation (Inspector): 7� 2 , Z.d By: Well Information D: fir✓ S ` Well Lac (YES / NO) iameter: Construction: (PV el/StaintessSteel) T�pth: ft Multi Factor*: r(Ra s/12)2 s 3.14x 7,481 Water Level: ft Casing Volume: gallons Height of Water Column: ft Cal. 3 Volume gallons Pump Intake: Purge Information Date urged: / / Purge bate: PurgingMetl�od: urge _..._�— (gallons/mis) OWL Sant,Ding Information Date Collected: Time Collected: t �i— (am/ Sampling Equipment se rAb Instrument ID:�yd �� 6 Bottle Type Preservation J/L/-- NAI7s - Analysis Required Meld Measurements/®bservations .35, ,;� Sample Temp (°C): 1. Time: 1: I r Turbidity (ntu): � Time: 1 k Diss Oxy (Mg/L): a 1S� Time: % Fe 2+mg/L: Time: Specific Corid. (uS):.3 a . 0 Time: % Res. Cl (mg/L)/{µg/L): Time: Sample pH (s.u.): � Time: 1- IS Odor: Afa A Time: ReDox (mV): L) 1 7 Time: }' A_ppearance: A a > Time: ReDox (EH value):YSI ProPlus +2QQmV , (�•') Other: Tinge: GeneraVWeather Observations: 5VN F/cloudy/rainy) Temp(-F) WindQ' --(Mph) SamplerSignatur.. '"�- Date: Q ' ' x Stabilization Teat Time Purged Temp,Diss (°C) Ox . Y (mg/L) Spec tom) • PH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (call ntls) Water level fE () Other 3 0a. �, ►' ��', 1.a? APPENDIX B LABORATORY ANALYTICAL DATA - PACE ANALYTICAL SERVICES, LLC. 0 aceAnalytical Report of Analysis Bunnell-Lammons Engineering, Inc. 6004 Ponders Court Greenville, SC 29615 Attention: Andy Alexander Project Name: Active Buncombe County Landfill Monitoring Wells Project Number: J20-9378-22 Lot Number:VJ27049 Date Completed:11/09/2020 11 /17/2020 2:28 PM Approved and released by: Project Manager II: Lucas Odom PCCRF� 24rA lkiA / ANSI National Accreditation Board A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 154 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Bunnell-Lammons Engineering, Inc. Lot Number: VJ27049 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. VOCs by GC/MS Surrogate recovery for the following sample was outside the upper control limit: VJ27049-011, VJ27049- 012, VJ27049-015, VJ27049-016. These samples did not contain any target analytes; therefore, re - extraction and/or re -analysis was not performed. Surrogate recoveries in the matrix spike and matrix spike duplicate (MS/MSD) in batch 72175 were outside the lower control limit. The CCV and LCS associated with this batch passed acceptance criteria, therefore the data has been reported. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 2 of 154 PACE ANALYTICAL SERVICES, LLC Sample Summary Bunnell-Lammons Engineering, Inc. Lot Number: VJ27049 Sample Number Sample ID Matrix Date Sampled Date Received 001 MW-13 Aqueous 10/26/20201240 10/27/2020 002 MW-13D Aqueous 10/26/20201345 10/27/2020 003 MW-4 Aqueous 10/26/20201435 10/27/2020 004 MW-4D Aqueous 10/26/20201520 10/27/2020 005 MW-3R Aqueous 10/26/20201630 10/27/2020 006 MW-8D Aqueous 10/27/20201620 10/28/2020 007 MW-8 Aqueous 10/27/20201655 10/28/2020 008 MW-7 Aqueous 10/28/20201340 10/30/2020 009 MW-5D Aqueous 10/28/20201440 10/30/2020 010 MW-5 Aqueous 10/28/20201630 10/30/2020 011 MW-6 Aqueous 10/29/2020 0940 10/30/2020 012 MW-15 Aqueous 10/29/20201100 10/30/2020 013 MW-15D Aqueous 10/29/20201155 10/30/2020 014 MW-12 Aqueous 10/29/20201320 10/30/2020 015 MW-12D Aqueous 10/29/20201410 10/30/2020 016 MW-14D Aqueous 10/29/20201500 10/30/2020 017 MW-14 Aqueous 10/29/20201550 10/30/2020 018 MW-17DR Aqueous 10/30/20201015 11/02/2020 019 MW-17R Aqueous 10/30/20201130 11/02/2020 020 MW-1OD Aqueous 10/30/20201250 11/02/2020 021 MW-10 Aqueous 10/30/20201330 11/02/2020 022 MW-11D Aqueous 10/30/20201035 11/02/2020 023 MW-11 Aqueous 10/30/20201110 11/02/2020 024 MW-2D Aqueous 10/30/20201230 11/02/2020 025 MW-2 Aqueous 10/30/20201415 11/02/2020 026 MW-1 Aqueous 10/30/20201445 11/02/2020 027 MW-1D Aqueous 10/30/20201455 11/02/2020 028 TRIP BLANK Aqueous 10/30/2020 11/02/2020 (28 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 154 PACE ANALYTICAL SERVICES, LLC Detection Summary Bunnell-Lammons Engineering, Inc. Lot Number: VJ27049 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 MW-13 Aqueous Acetone 8260D 5.6 J ug/L 9 001 MW-13 Aqueous Barium 6020B 190 ug/L 10 001 MW-13 Aqueous Cobalt 6020B 21 ug/L 10 001 MW-13 Aqueous Nickel 6020B 9.4 ug/L 10 001 MW-13 Aqueous Zinc 6020B 3.8 J ug/L 10 002 MW-13D Aqueous Barium 6020B 240 ug/L 12 002 MW-13D Aqueous Cobalt 6020B 19 ug/L 12 002 MW-13D Aqueous Nickel 6020B 9.2 ug/L 12 003 MW-4 Aqueous Barium 6020B 72 ug/L 14 003 MW-4 Aqueous Chromium 6020B 5.6 ug/L 14 003 MW-4 Aqueous Copper 6020B 1.7 J ug/L 14 003 MW-4 Aqueous Nickel 6020B 9.5 ug/L 14 004 MW-41D Aqueous Barium 6020B 44 ug/L 17 004 MW-41D Aqueous Vanadium 6020B 2.8 J ug/L 18 005 MW-3R Aqueous Barium 6020B 46 ug/L 20 005 MW-3R Aqueous Chromium 6020B 4.9 J ug/L 20 005 MW-3R Aqueous Nickel 6020B 3.8 J ug/L 20 005 MW-3R Aqueous Vanadium 6020B 3.7 J ug/L 20 006 MW-81D Aqueous Acetone 8260D 5.2 J ug/L 21 006 MW-81D Aqueous Barium 6020B 170 ug/L 22 006 MW-81D Aqueous Nickel 6020B 4.0 J ug/L 22 007 MW-8 Aqueous Barium 6020B 140 ug/L 24 007 MW-8 Aqueous Chromium 6020B 4.4 J ug/L 24 007 MW-8 Aqueous Nickel 6020B 4.4 J ug/L 24 007 MW-8 Aqueous Zinc 6020B 4.8 J ug/L 24 008 MW-7 Aqueous Barium 6020B 160 ug/L 26 008 MW-7 Aqueous Chromium 6020B 5.7 ug/L 26 008 MW-7 Aqueous Cobalt 6020B 2.5 J ug/L 26 008 MW-7 Aqueous Copper 6020B 1.4 J ug/L 26 008 MW-7 Aqueous Nickel 6020B 17 ug/L 26 008 MW-7 Aqueous Zinc 6020B 4.2 J ug/L 26 009 MW-51D Aqueous Barium 6020B 69 ug/L 28 009 MW-51D Aqueous Nickel 6020B 3.8 J ug/L 28 009 MW-51D Aqueous Zinc 6020B 3.6 J ug/L 28 010 MW-5 Aqueous Barium 6020B 120 ug/L 30 010 MW-5 Aqueous Chromium 6020B 2.1 J ug/L 30 010 MW-5 Aqueous Nickel 6020B 3.5 J ug/L 30 010 MW-5 Aqueous Vanadium 6020B 2.7 J ug/L 30 010 MW-5 Aqueous Zinc 6020B 3.6 J ug/L 30 011 MW-6 Aqueous Antimony 6020B 0.69 J ug/L 32 011 MW-6 Aqueous Barium 6020B 48 ug/L 32 011 MW-6 Aqueous Nickel 6020B 1.7 J ug/L 32 012 MW-15 Aqueous Alkalinity @ pH 4.5 su SM 2320B- 280 mg CaCO3/1- 33 012 MW-15 Aqueous Chloride 9056A 20 mg/L 33 012 MW-15 Aqueous Sulfate 9056A 24 mg/L 33 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 154 Detection Summary (Continued) Lot Number: VJ27049 Sample Sample ID Matrix Parameter Method Result Q Units Page 012 MW-15 Aqueous TDS SM 2540C- 380 mg/L 33 012 MW-15 Aqueous 1,4-Dioxane 8260D (SIM) 6.7 ug/L 33 012 MW-15 Aqueous Vinyl chloride 8260D 0.47 J ug/L 34 012 MW-15 Aqueous Barium 6020B 210 ug/L 35 012 MW-15 Aqueous Chromium 6020B 4.3 J ug/L 35 012 MW-15 Aqueous Cobalt 6020B 78 ug/L 35 012 MW-15 Aqueous Iron 6020B 66000 ug/L 35 012 MW-15 Aqueous Manganese 6020B 11000 ug/L 35 012 MW-15 Aqueous Nickel 6020B 11 ug/L 35 012 MW-15 Aqueous Zinc 6020B 4.8 J ug/L 35 013 MW-15D Aqueous Alkalinity @ pH 4.5 su SM 232013- 300 mg CaCO3/1- 36 013 MW-15D Aqueous Chloride 9056A 78 mg/L 36 013 MW-15D Aqueous Sulfate 9056A 120 mg/L 36 013 MW-15D Aqueous TDS SM 2540C- 1100 mg/L 36 013 MW-15D Aqueous 1,4-Dioxane 8260D (SIM) 30 ug/L 36 013 MW-15D Aqueous Acetone 8260D 5.8 J ug/L 36 013 MW-15D Aqueous 1,2-Dichloroethane 8260D 0.46 J ug/L 37 013 MW-15D Aqueous Methylene chloride 8260D 0.45 J ug/L 37 013 MW-15D Aqueous Tetrahydrofuran 8260D 2.9 J ug/L 37 013 MW-15D Aqueous Vinyl chloride 8260D 1.2 ug/L 37 013 MW-15D Aqueous Barium 6020B 140 ug/L 38 013 MW-15D Aqueous Beryllium 6020B 0.19 J ug/L 38 013 MW-15D Aqueous Cobalt 6020B 2.7 J ug/L 38 013 MW-15D Aqueous Iron 6020B 1600 ug/L 38 013 MW-15D Aqueous Manganese 6020B 1400 ug/L 38 013 MW-15D Aqueous Nickel 6020B 29 ug/L 38 014 MW-12 Aqueous Alkalinity @ pH 4.5 su SM 232013- 290 mg CaCO3/1- 39 014 MW-12 Aqueous Chloride 9056A 43 mg/L 39 014 MW-12 Aqueous Sulfate 9056A 280 mg/L 39 014 MW-12 Aqueous TDS SM 2540C- 870 mg/L 39 014 MW-12 Aqueous 1,4-Dioxane 8260D (SIM) 6.8 ug/L 39 014 MW-12 Aqueous Acetone 8260D 5.9 J ug/L 39 014 MW-12 Aqueous Tetrahydrofuran 8260D 5.1 ug/L 40 014 MW-12 Aqueous Barium 6020B 110 ug/L 41 014 MW-12 Aqueous Cadmium 6020B 0.17 J ug/L 41 014 MW-12 Aqueous Chromium 6020B 2.3 J ug/L 41 014 MW-12 Aqueous Cobalt 6020B 40 ug/L 41 014 MW-12 Aqueous Copper 6020B 5.2 ug/L 41 014 MW-12 Aqueous Iron 6020B 370 ug/L 41 014 MW-12 Aqueous Manganese 6020B 3300 ug/L 41 014 MW-12 Aqueous Nickel 6020B 40 ug/L 41 014 MW-12 Aqueous Zinc 6020B 5.9 J ug/L 41 015 MW-12D Aqueous Alkalinity @ pH 4.5 su SM 232013- 160 mg CaCO3/1- 42 015 MW-12D Aqueous Chloride 9056A 9.3 mg/L 42 015 MW-12D Aqueous Sulfate 9056A 43 mg/L 42 015 MW-12D Aqueous TDS SM 2540C- 280 mg/L 42 015 MW-12D Aqueous 1,4-Dioxane 8260D (SIM) 1.3 J ug/L 42 015 MW-12D Aqueous 2-Butanone (MEK) 8260D 2.5 J ug/L 42 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 154 Detection Summary (Continued) Lot Number: VJ27049 Sample Sample ID Matrix Parameter Method Result Q Units Page 015 MW-12D Aqueous Barium 6020B 38 ug/L 44 015 MW-12D Aqueous Iron 6020B 72 ug/L 44 015 MW-12D Aqueous Manganese 6020B 210 ug/L 44 015 MW-12D Aqueous Nickel 6020B 2.6 J ug/L 44 016 MW-14D Aqueous Alkalinity @ pH 4.5 su SM 232013- 140 mg CaCO3/1- 45 016 MW-14D Aqueous Chloride 9056A 3.7 mg/L 45 016 MW-14D Aqueous Sulfate 9056A 26 mg/L 45 016 MW-14D Aqueous TDS SM 2540C- 220 mg/L 45 016 MW-14D Aqueous Barium 6020B 6.7 ug/L 47 016 MW-14D Aqueous Iron 6020B 61 ug/L 47 016 MW-14D Aqueous Manganese 6020B 18 ug/L 47 017 MW-14 Aqueous Alkalinity @ pH 4.5 su SM 232013- 65 mg CaCO3/1- 48 017 MW-14 Aqueous Chloride 9056A 2.2 mg/L 48 017 MW-14 Aqueous Sulfate 9056A 18 mg/L 48 017 MW-14 Aqueous TDS SM 2540C- 170 mg/L 48 017 MW-14 Aqueous Barium 6020B 47 ug/L 50 017 MW-14 Aqueous Chromium 6020B 1.4 J ug/L 50 017 MW-14 Aqueous Iron 6020B 440 ug/L 50 017 MW-14 Aqueous Manganese 6020B 3.7 J ug/L 50 017 MW-14 Aqueous Nickel 6020B 2.7 J ug/L 50 017 MW-14 Aqueous Vanadium 6020B 3.0 J ug/L 50 018 MW-17DR Aqueous Alkalinity @ pH 4.5 su SM 232013- 120 mg CaCO3/1- 51 018 MW-17DR Aqueous Chloride 9056A 3.5 mg/L 51 018 MW-17DR Aqueous Sulfate 9056A 22 mg/L 51 018 MW-17DR Aqueous TDS SM 2540C- 200 mg/L 51 018 MW-17DR Aqueous Barium 6020B 59 ug/L 53 018 MW-17DR Aqueous Iron 6020B 340 ug/L 53 018 MW-17DR Aqueous Manganese 6020B 77 ug/L 53 019 MW-17R Aqueous Alkalinity @ pH 4.5 su SM 232013- 93 mg CaCO3/1- 54 019 MW-17R Aqueous Chloride 9056A 3.1 mg/L 54 019 MW-17R Aqueous Sulfate 9056A 35 mg/L 54 019 MW-17R Aqueous TDS SM 2540C- 200 mg/L 54 019 MW-17R Aqueous Barium 6020B 57 ug/L 56 019 MW-17R Aqueous Iron 6020B 130 ug/L 56 019 MW-17R Aqueous Manganese 6020B 150 ug/L 56 019 MW-17R Aqueous Nickel 6020B 9.6 ug/L 56 020 MW-1OD Aqueous 1,1-Dichloroethane 8260D 0.60 J ug/L 57 020 MW-1OD Aqueous Barium 6020B 51 ug/L 58 020 MW-1OD Aqueous Chromium 6020B 2.8 J ug/L 58 020 MW-1OD Aqueous Cobalt 6020B 4.0 J ug/L 58 020 MW-1OD Aqueous Copper 6020B 1.4 J ug/L 58 020 MW-1OD Aqueous Nickel 6020B 19 ug/L 58 020 MW-1OD Aqueous Zinc 6020B 3.8 J ug/L 59 021 MW-10 Aqueous Barium 6020B 130 ug/L 61 021 MW-10 Aqueous Chromium 6020B 2.0 J ug/L 61 021 MW-10 Aqueous Cobalt 6020B 3.0 J ug/L 61 021 MW-10 Aqueous Nickel 6020B 9.1 ug/L 61 021 MW-10 Aqueous Zinc 6020B 7.7 J ug/L 62 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 154 Detection Summary (Continued) Lot Number: VJ27049 Sample Sample ID Matrix Parameter Method Result Q Units Page 022 MW-11D Aqueous Antimony 6020B 1.1 J ug/L 64 022 MW-11D Aqueous Barium 6020B 45 ug/L 64 022 MW-11D Aqueous Chromium 6020B 1.5 J ug/L 64 022 MW-11D Aqueous Copper 6020B 1.3 J ug/L 64 022 MW-11D Aqueous Lead 6020B 0.26 J ug/L 64 022 MW-11D Aqueous Nickel 6020B 12 ug/L 64 022 MW-11D Aqueous Zinc 6020B 14 ug/L 64 023 MW-11 Aqueous Barium 6020B 110 ug/L 66 023 MW-11 Aqueous Beryllium 6020B 0.24 J ug/L 66 023 MW-11 Aqueous Chromium 6020B 25 ug/L 66 023 MW-11 Aqueous Cobalt 6020B 1.9 J ug/L 66 023 MW-11 Aqueous Copper 6020B 5.2 ug/L 66 023 MW-11 Aqueous Lead 6020B 3.9 ug/L 66 023 MW-11 Aqueous Nickel 6020B 38 ug/L 66 023 MW-11 Aqueous Zinc 6020B 14 ug/L 66 024 MW-21D Aqueous Barium 6020B 100 ug/L 68 025 MW-2 Aqueous Barium 6020B 240 ug/L 70 025 MW-2 Aqueous Cobalt 6020B 22 ug/L 70 025 MW-2 Aqueous Nickel 6020B 23 ug/L 70 025 MW-2 Aqueous Zinc 6020B 10 ug/L 70 026 MW-1 Aqueous Alkalinity @ pH 4.5 su SM 232013- 56 mg CaCO3/L 71 026 MW-1 Aqueous Chloride 9056A 5.8 mg/L 71 026 MW-1 Aqueous Sulfate 9056A 16 mg/L 71 026 MW-1 Aqueous TDS SM 2540C- 160 mg/L 71 026 MW-1 Aqueous Barium 6020B 130 ug/L 73 026 MW-1 Aqueous Chromium 6020B 5.3 ug/L 73 026 MW-1 Aqueous Iron 6020B 350 ug/L 73 026 MW-1 Aqueous Manganese 6020B 9.8 ug/L 73 026 MW-1 Aqueous Nickel 6020B 3.1 J ug/L 73 026 MW-1 Aqueous Vanadium 6020B 3.6 J ug/L 73 026 MW-1 Aqueous Zinc 6020B 4.5 J ug/L 73 027 MW-1 D Aqueous Alkalinity @ pH 4.5 su SM 232013- 81 mg CaCO3/L 74 027 MW-1D Aqueous Chloride 9056A 2.2 mg/L 74 027 MW-1D Aqueous Sulfate 9056A 39 mg/L 74 027 MW-1D Aqueous TDS SM 2540C- 200 mg/L 74 027 MW-1D Aqueous Antimony 6020B 0.60 J ug/L 76 027 MW-1D Aqueous Barium 6020B 29 ug/L 76 027 MW-1D Aqueous Iron 6020B 260 ug/L 76 027 MW-1D Aqueous Lead 6020B 0.25 J ug/L 76 027 MW-1D Aqueous Manganese 6020B 7.2 ug/L 76 027 MW-1D Aqueous Nickel 6020B 3.0 J ug/L 76 027 MW-1D Aqueous Zinc 6020B 3.6 J ug/L 76 (183 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-001 Description: MW-13 Matrix: Aqueous Date Sampled:10/26/2020 1240 Date Received:10/27/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0021 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 5.6 J 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-001 Description: MW-13 Matrix: Aqueous Date Sampled:10/26/2020 1240 Date Received:10/27/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0021 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 88 70-130 1,2-Dichloroethane-d4 87 70-130 Toluene-d8 89 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/03/2020 0044 BPK 10/30/2020 1549 71494 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 190 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 21 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 9.4 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.8 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-002 Description: MW-13D Matrix: Aqueous Date Sampled:10/26/2020 1345 Date Received:10/27/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0046 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-002 Description: MW-13D Matrix: Aqueous Date Sampled:10/26/2020 1345 Date Received:10/27/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0046 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 91 70-130 1,2-Dichloroethane-d4 89 70-130 Toluene-d8 91 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/03/2020 0051 BPK 10/30/2020 1549 71494 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 240 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 19 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 9.2 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-003 Description: MW-4 Matrix: Aqueous Date Sampled:10/26/2020 1435 Date Received:10/27/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 5030B 8260D (SIM) 1 11/02/2020 1403 BWS 71945 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 2 Run 2 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 96 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0111 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-003 Description: MW-4 Matrix: Aqueous Date Sampled:10/26/2020 1435 Date Received:10/27/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0111 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 81 70-130 1,2-Dichloroethane-d4 77 70-130 Toluene-d8 79 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/03/2020 0059 BPK 10/30/2020 1549 71494 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 72 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.6 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.7 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 9.5 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-003 Description: MW-4 Matrix: Aqueous Date Sampled:10/26/2020 1435 Date Received:10/27/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/03/2020 0059 BPK 10/30/2020 1549 71494 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-004 Description: MW-4D Matrix: Aqueous Date Sampled:10/26/2020 1520 Date Received:10/27/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/31/2020 0601 DJG 71851 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 107 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0136 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-004 Description: MW-4D Matrix: Aqueous Date Sampled:10/26/2020 1520 Date Received:10/27/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0136 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 78 70-130 1,2-Dichloroethane-d4 77 70-130 Toluene-d8 79 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/03/2020 0106 BPK 10/30/2020 1549 71494 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 44 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 16 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-004 Description: MW-4D Matrix: Aqueous Date Sampled:10/26/2020 1520 Date Received:10/27/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/03/2020 0106 BPK 10/30/2020 1549 71494 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 2.8 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 17 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-005 Description: MW-3R Matrix: Aqueous Date Sampled:10/26/2020 1630 Date Received:10/27/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0200 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 18 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-005 Description: MW-3R Matrix: Aqueous Date Sampled:10/26/2020 1630 Date Received:10/27/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0200 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 87 70-130 1,2-Dichloroethane-d4 87 70-130 Toluene-d8 87 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/03/2020 0114 BPK 10/30/2020 1549 71494 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 46 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 4.9 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 3.8 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 3.7 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 19 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-006 Description: MW-8D Matrix: Aqueous Date Sampled:10/27/2020 1620 Date Received:10/28/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0225 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 5.2 J 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 20 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-006 Description: MW-8D Matrix: Aqueous Date Sampled:10/27/2020 1620 Date Received:10/28/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0225 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 86 70-130 1,2-Dichloroethane-d4 86 70-130 Toluene-d8 87 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/03/2020 0136 BPK 10/30/2020 1549 71494 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 170 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 4.0 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 21 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-007 Description: MW-8 Matrix: Aqueous Date Sampled:10/27/2020 1655 Date Received:10/28/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0250 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 22 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-007 Description: MW-8 Matrix: Aqueous Date Sampled:10/27/2020 1655 Date Received:10/28/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0250 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 84 70-130 1,2-Dichloroethane-d4 81 70-130 Toluene-d8 83 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/03/2020 0144 BPK 10/30/2020 1549 71494 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 140 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 4.4 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 4.4 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 4.8 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 23 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-008 Description: MW-7 Matrix: Aqueous Date Sampled:10/28/2020 1340 Date Received:10/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0315 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 24 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-008 Description: MW-7 Matrix: Aqueous Date Sampled:10/28/2020 1340 Date Received:10/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0315 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 85 70-130 1,2-Dichloroethane-d4 85 70-130 Toluene-d8 87 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/03/2020 2214 BPK 11/03/2020 0936 71917 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 160 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.7 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 2.5 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.4 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 17 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 4.2 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 25 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-009 Description: MW-5D Matrix: Aqueous Date Sampled:10/28/2020 1440 Date Received:10/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0340 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 26 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-009 Description: MW-5D Matrix: Aqueous Date Sampled:10/28/2020 1440 Date Received:10/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0340 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 82 70-130 1,2-Dichloroethane-d4 80 70-130 Toluene-d8 82 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/03/2020 2222 BPK 11/03/2020 0936 71917 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 69 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 3.8 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.6 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 27 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-010 Description: MW-5 Matrix: Aqueous Date Sampled:10/28/2020 1630 Date Received:10/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0404 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 28 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-010 Description: MW-5 Matrix: Aqueous Date Sampled:10/28/2020 1630 Date Received:10/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0404 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 82 70-130 1,2-Dichloroethane-d4 80 70-130 Toluene-d8 82 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/03/2020 2229 BPK 11/03/2020 0936 71917 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 120 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 2.1 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 3.5 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 2.7 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.6 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 29 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-011 Description: MW-6 Matrix: Aqueous Date Sampled:10/29/2020 0940 Date Received:10/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0429 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 30 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-011 Description: MW-6 Matrix: Aqueous Date Sampled:10/29/2020 0940 Date Received:10/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0429 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene N 155 70-130 1,2-Dichloroethane-d4 N 152 70-130 Toluene-d8 N 156 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/03/2020 2322 BPK 11/03/2020 0936 71917 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 0.69 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 48 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 1.7 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 31 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-012 Description: MW-15 Matrix: Aqueous Date Sampled:10/29/2020 1100 Date Received:10/30/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 10/31/2020 1412 AAB 72118 1 (Chloride) 9056A 1 11/02/2020 2027 AMR 72049 1 (Sulfate) 9056A 1 11/02/2020 2027 AMR 72050 1 (TDS) SM 2540C-2011 1 11/02/2020 2228 MOM 72013 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 280 20 20 mg CaCO3/L 1 Chloride 9056A 20 1.0 0.25 mg/L 1 Sulfate 9056A 24 1.0 0.25 mg/L 1 TDS SM 254OC-2011 380 25 25 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 11/02/2020 1452 BWS 71945 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 6.7 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 97 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0454 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 32 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-012 Description: MW-15 Matrix: Aqueous Date Sampled:10/29/2020 1100 Date Received:10/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0454 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.47 J 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene N 154 70-130 1,2-Dichloroethane-d4 N 153 70-130 Toluene-d8 N 155 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 33 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-012 Description: MW-15 Matrix: Aqueous Date Sampled:10/29/2020 1100 Date Received:10/30/2020 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 11/04/2020 1315 JAB2 11/04/2020 0949 72084 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/03/2020 2329 BPK 11/03/2020 0936 71917 2 3005A 6020B 100 11/04/2020 1542 BPK 11/03/2020 0936 71917 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 210 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 4.3 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 78 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 66000 5000 1300 ug/L 2 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 11000 500 130 ug/L 2 Nickel 7440-02-0 6020B 11 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 4.8 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 34 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-013 Description: MW-15D Matrix: Aqueous Date Sampled:10/29/2020 1155 Date Received:10/30/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 10/31/2020 1418 AAB 72118 1 (Chloride) 9056A 1 11/02/2020 2046 AMR 72049 1 (Sulfate) 9056A 1 11/02/2020 2046 AMR 72050 1 (TDS) SM 2540C-2011 1 11/02/2020 2228 MOM 72013 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 300 20 20 mg CaCO3/L 1 Chloride 9056A 78 1.0 0.25 mg/L 1 Sulfate 9056A 120 1.0 0.25 mg/L 1 TDS SM 254OC-2011 1100 25 25 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 11/02/2020 1517 BWS 71945 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 30 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 96 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 5030B 8260D 1 11/06/20201114 TML 72533 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 5.8 J 20 5.0 ug/L 2 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 2 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 2 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 2 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 2 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 2 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 2 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 2 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 2 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 2 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 2 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 2 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 2 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 35 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-013 Description: MW-15D Matrix: Aqueous Date Sampled:10/29/2020 1155 Date Received:10/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 5030B 8260D 1 11/06/20201114 TML 72533 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 2 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 2 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 2 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 2 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 2 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 2 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 2 1,2-Dichloroethane 107-06-2 8260D 0.46 J 1.0 0.40 ug/L 2 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 2 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 2 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 2 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 2 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 2 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 2 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 2 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 2 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 2 Methylene chloride 75-09-2 8260D 0.45 J 1.0 0.40 ug/L 2 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 2 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 2 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 2 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 2 Tetrahydrofuran 109-99-9 8260D 2.9 J 5.0 1.0 ug/L 2 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 2 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 2 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 2 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 2 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 2 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 2 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 2 Vinyl chloride 75-01-4 8260D 1.2 1.0 0.40 ug/L 2 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 2 Run 2 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 92 70-130 1,2-Dichloroethane-d4 93 70-130 Toluene-d8 100 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 36 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-013 Description: MW-15D Matrix: Aqueous Date Sampled:10/29/2020 1155 Date Received:10/30/2020 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 11/04/2020 1322 JA132 11/04/2020 0949 72084 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/03/2020 2337 BPK 11/03/2020 0936 71917 2 3005A 6020B 100 11/04/2020 1535 BPK 11/03/2020 0936 71917 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 140 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.19 J 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 2.7 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 1600 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 1400 500 130 ug/L 2 Nickel 7440-02-0 6020B 29 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 37 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-014 Description: MW-12 Matrix: Aqueous Date Sampled:10/29/2020 1320 Date Received:10/30/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 10/31/2020 1423 AAB 72118 1 (Chloride) 9056A 5 11/02/2020 2104 AMR 72049 1 (Sulfate) 9056A 5 11/02/2020 2104 AMR 72050 1 (TDS) SM 2540C-2011 1 11/02/2020 2228 MOM 72013 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 290 20 20 mg CaCO3/L 1 Chloride 9056A 43 5.0 1.3 mg/L 1 Sulfate 9056A 280 5.0 1.3 mg/L 1 TDS SM 2540C-2011 870 25 25 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 11/02/2020 1541 BWS 71945 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 6.8 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 96 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 5030B 8260D 1 11/06/20201137 TML 72533 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 5.9 J 20 5.0 ug/L 2 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 2 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 2 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 2 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 2 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 2 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 2 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 2 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 2 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 2 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 2 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 2 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 2 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 38 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-014 Description: MW-12 Matrix: Aqueous Date Sampled:10/29/2020 1320 Date Received:10/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 5030B 8260D 1 11/06/20201137 TML 72533 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 2 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 2 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 2 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 2 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 2 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 2 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 2 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 2 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 2 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 2 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 2 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 2 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 2 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 2 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 2 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 2 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 2 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 2 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 2 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 2 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 2 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 2 Tetrahydrofuran 109-99-9 8260D 5.1 5.0 1.0 ug/L 2 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 2 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 2 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 2 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 2 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 2 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 2 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 2 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 2 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 2 Run 2 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 92 70-130 1,2-Dichloroethane-d4 93 70-130 Toluene-d8 100 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 39 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-014 Description: MW-12 Matrix: Aqueous Date Sampled:10/29/2020 1320 Date Received:10/30/2020 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 11/04/2020 1325 JAB2 11/04/2020 0949 72084 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/03/2020 2344 BPK 11/03/2020 0936 71917 2 3005A 6020B 100 11/04/2020 1550 BPK 11/03/2020 0936 71917 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 110 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.17 J 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 2.3 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 40 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.2 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 370 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 3300 500 130 ug/L 2 Nickel 7440-02-0 6020B 40 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 5.9 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 40 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-015 Description: MW-12D Matrix: Aqueous Date Sampled:10/29/2020 1410 Date Received:10/30/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 10/31/2020 1429 AAB 72118 1 (Chloride) 9056A 1 11/02/2020 2123 AMR 72049 1 (Sulfate) 9056A 1 11/02/2020 2123 AMR 72050 1 (TDS) SM 2540C-2011 1 11/02/2020 2228 MOM 72013 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 160 20 20 mg CaCO3/L 1 Chloride 9056A 9.3 1.0 0.25 mg/L 1 Sulfate 9056A 43 1.0 0.25 mg/L 1 TDS SM 254OC-2011 280 25 25 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 5030B 8260D (SIM) 1 11/04/2020 1129 BWS 72222 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 1.3 J 3.0 1.0 ug/L 2 Run 2 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 97 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0609 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 2.5 J 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 41 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-015 Description: MW-12D Matrix: Aqueous Date Sampled:10/29/2020 1410 Date Received:10/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0609 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 125 70-130 1,2-Dichloroethane-d4 N 134 70-130 Toluene-d8 N 132 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 42 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-015 Description: MW-12D Matrix: Aqueous Date Sampled:10/29/2020 1410 Date Received:10/30/2020 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 11/04/2020 1328 JAB2 11/04/2020 0949 72084 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/03/2020 2352 BPK 11/03/2020 0936 71917 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 38 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 72 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 210 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B 2.6 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 43 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-016 Description: MW-14D Matrix: Aqueous Date Sampled:10/29/2020 1500 )ate Received:10/30/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 10/31/2020 1435 AAB 72118 1 (Chloride) 9056A 1 11/02/2020 2142 AMR 72049 1 (Sulfate) 9056A 1 11/02/2020 2142 AMR 72050 1 (TDS) SM 2540C-2011 1 11/02/2020 2228 MOM 72013 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 140 20 20 mg CaCO3/L 1 Chloride 9056A 3.7 1.0 0.25 mg/L 1 Sulfate 9056A 26 1.0 0.25 mg/L 1 TDS SM 254OC-2011 220 25 25 mg/L 1 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0633 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 44 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-016 Description: MW-14D Matrix: Aqueous Date Sampled:10/29/2020 1500 Date Received:10/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0633 STM 72175 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 128 70-130 1,2-Dichloroethane-d4 N 136 70-130 Toluene-d8 N 136 70-130 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 11 /04/2020 1330 JAB2 11 /04/2020 0949 72084 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 45 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-016 Description: MW-14D Matrix: Aqueous Date Sampled:10/29/2020 1500 Date Received:10/30/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/03/2020 2359 BPK 11/03/2020 0936 71917 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 6.7 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 61 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 18 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 46 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-017 Description: MW-14 Matrix: Aqueous Date Sampled:10/29/2020 1550 )ate Received:10/30/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 10/31/2020 1441 AAB 72118 1 (Chloride) 9056A 1 11/02/2020 2239 AMR 72049 1 (Sulfate) 9056A 1 11/02/2020 2239 AMR 72050 1 (TDS) SM 2540C-2011 1 11/02/2020 2228 MOM 72013 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 65 20 20 mg CaCO3/L 1 Chloride 9056A 2.2 1.0 0.25 mg/L 1 Sulfate 9056A 18 1.0 0.25 mg/L 1 TDS SM 254OC-2011 170 25 25 mg/L 1 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/20201037 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 47 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-017 Description: MW-14 Matrix: Aqueous Date Sampled:10/29/2020 1550 Date Received:10/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/20201037 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 91 70-130 Toluene-d8 101 70-130 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 11 /04/2020 1333 JAB2 11 /04/2020 0949 72084 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 48 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-017 Description: MW-14 Matrix: Aqueous Date Sampled:10/29/2020 1550 Date Received:10/30/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/04/2020 0007 BPK 11/03/2020 0936 71917 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 47 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.4 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 440 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 3.7 J 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B 2.7 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 3.0 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 49 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-018 Description: MW-17DR Matrix: Aqueous Date Sampled:10/30/2020 1015 Date Received: 11 /02/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 11/03/2020 1754 AAB 72172 1 (Chloride) 9056A 1 11/03/2020 1810 AMR 72214 2 (Sulfate) 9056A 1 11/04/2020 1357 AMR 72289 1 (TDS) SM 2540C-2011 1 11/02/2020 2228 MOM 72013 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 120 20 20 mg CaCO3/L 1 Chloride 9056A 3.5 1.0 0.25 mg/L 1 Sulfate 9056A 22 1.0 0.25 mg/L 2 TDS SM 254OC-2011 200 25 25 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 11/03/2020 1106 BWS 72081 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 95 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/20201100 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 50 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-018 Description: MW-17DR Matrix: Aqueous Date Sampled:10/30/2020 1015 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/20201100 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 92 70-130 Toluene-d8 103 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 51 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-018 Description: MW-17DR Matrix: Aqueous Date Sampled:10/30/2020 1015 Date Received: 11 /02/2020 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 11/04/2020 1335 JAB2 11/04/2020 0949 72084 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/04/2020 0307 BPK 11/03/2020 0936 72039 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 59 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 340 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 77 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 52 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-019 Description: MW-17R Matrix: Aqueous Date Sampled:10/30/2020 1130 Date Received: 11 /02/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 11/03/2020 1801 AAB 72172 1 (Chloride) 9056A 1 11/03/2020 1829 AMR 72214 2 (Sulfate) 9056A 1 11/04/2020 1416 AMR 72289 1 (TDS) SM 2540C-2011 1 11/02/2020 2228 MOM 72013 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 93 20 20 mg CaCO3/L 1 Chloride 9056A 3.1 1.0 0.25 mg/L 1 Sulfate 9056A 35 1.0 0.25 mg/L 2 TDS SM 254OC-2011 200 25 25 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 11/03/2020 1130 BWS 72081 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 96 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/20201123 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 53 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-019 Description: MW-17R Matrix: Aqueous Date Sampled:10/30/2020 1130 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/20201123 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 93 70-130 1,2-Dichloroethane-d4 91 70-130 Toluene-d8 100 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 54 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-019 Description: MW-17R Matrix: Aqueous Date Sampled:10/30/2020 1130 Date Received: 11 /02/2020 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 11/04/2020 1338 JAB2 11/04/2020 0949 72084 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/04/2020 0314 BPK 11/03/2020 0936 72039 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 57 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 130 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 150 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B 9.6 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 55 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-020 Description: MW-10D Matrix: Aqueous Date Sampled:10/30/2020 1250 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 11/03/2020 1155 BWS 72081 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 95 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/20201146 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.60 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 56 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-020 Description: MW-10D Matrix: Aqueous Date Sampled:10/30/2020 1250 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/20201146 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 92 70-130 Toluene-d8 102 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/04/2020 0322 BPK 11/03/2020 0936 72039 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 51 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 2.8 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 4.0 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.4 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 19 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 57 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-020 Description: MW-10D Matrix: Aqueous Date Sampled:10/30/2020 1250 Date Received: 11 /02/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/04/2020 0322 BPK 11/03/2020 0936 72039 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 Silver 7440-22-4 Thallium 7440-28-0 Vanadium 7440-62-2 Zinc 7440-66-6 6020B ND 5.0 1.3 ug/L 1 6020B ND 1.0 0.25 ug/L 1 6020B ND 0.50 0.15 ug/L 1 6020B ND 5.0 2.5 ug/L 1 6020B 3.8 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 58 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-021 Description: MW-10 Matrix: Aqueous Date Sampled:10/30/2020 1330 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 11/03/2020 1220 BWS 72081 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 96 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/20201209 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 59 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-021 Description: MW-10 Matrix: Aqueous Date Sampled:10/30/2020 1330 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/20201209 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 92 70-130 Toluene-d8 102 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/04/2020 0344 BPK 11/03/2020 0936 72039 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 130 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 2.0 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 3.0 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 9.1 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 60 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-021 Description: MW-10 Matrix: Aqueous Date Sampled:10/30/2020 1330 Date Received: 11 /02/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/04/2020 0344 BPK 11/03/2020 0936 72039 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 Silver 7440-22-4 Thallium 7440-28-0 Vanadium 7440-62-2 Zinc 7440-66-6 6020B ND 5.0 1.3 ug/L 1 6020B ND 1.0 0.25 ug/L 1 6020B ND 0.50 0.15 ug/L 1 6020B ND 5.0 2.5 ug/L 1 6020B 7.7 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 61 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-022 Description: MW-11D Matrix: Aqueous Date Sampled:10/30/2020 1035 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/20201232 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 62 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-022 Description: MW-11D Matrix: Aqueous Date Sampled:10/30/2020 1035 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/20201232 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 92 70-130 Toluene-d8 101 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/04/2020 0422 BPK 11/03/2020 0936 72039 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 1.1 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 45 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.5 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.3 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.26 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 12 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 14 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 63 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-023 Description: MW-11 Matrix: Aqueous Date Sampled:10/30/2020 1110 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/20201255 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 64 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-023 Description: MW-11 Matrix: Aqueous Date Sampled:10/30/2020 1110 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/20201255 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 91 70-130 Toluene-d8 101 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/04/2020 0429 BPK 11/03/2020 0936 72039 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 110 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.24 J 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 25 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 1.9 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.2 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 3.9 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 38 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 14 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 65 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-024 Description: MW-2D Matrix: Aqueous Date Sampled:10/30/2020 1230 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/20201319 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 66 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-024 Description: MW-2D Matrix: Aqueous Date Sampled:10/30/2020 1230 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/20201319 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 94 70-130 1,2-Dichloroethane-d4 92 70-130 Toluene-d8 100 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/04/2020 0437 BPK 11/03/2020 0936 72039 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 100 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 67 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-025 Description: MW-2 Matrix: Aqueous Date Sampled:10/30/2020 1415 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/20201342 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 68 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-025 Description: MW-2 Matrix: Aqueous Date Sampled:10/30/2020 1415 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/20201342 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 94 70-130 1,2-Dichloroethane-d4 92 70-130 Toluene-d8 101 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/04/2020 0444 BPK 11/03/2020 0936 72039 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 240 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 22 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 23 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 10 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 69 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-026 Description: MW-1 Matrix: Aqueous Date Sampled:10/30/2020 1445 )ate Received: 11 /02/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 11/03/2020 1808 AAB 72172 1 (Chloride) 9056A 1 11/03/2020 1848 AMR 72214 2 (Sulfate) 9056A 1 11/04/2020 1435 AMR 72289 1 (TDS) SM 2540C-2011 1 11/02/2020 2228 MOM 72013 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 56 20 20 mg CaCO3/L 1 Chloride 9056A 5.8 1.0 0.25 mg/L 1 Sulfate 9056A 16 1.0 0.25 mg/L 2 TDS SM 254OC-2011 160 25 25 mg/L 1 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/20201405 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 70 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-026 Description: MW-1 Matrix: Aqueous Date Sampled:10/30/2020 1445 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/20201405 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 93 70-130 1,2-Dichloroethane-d4 91 70-130 Toluene-d8 101 70-130 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 11 /04/2020 1340 JAB2 11 /04/2020 0949 72084 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 71 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-026 Description: MW-1 Matrix: Aqueous Date Sampled:10/30/2020 1445 Date Received: 11 /02/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/04/2020 0452 BPK 11/03/2020 0936 72039 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 130 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.3 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 350 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 9.8 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B 3.1 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 3.6 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 4.5 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 72 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-027 Description: MW-1D Matrix: Aqueous Date Sampled:10/30/2020 1455 )ate Received: 11 /02/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 11/03/2020 1814 AAB 72172 1 (Chloride) 9056A 1 11/03/2020 1945 AMR 72214 2 (Sulfate) 9056A 1 11/04/2020 1531 AMR 72289 1 (TDS) SM 2540C-2011 1 11/02/2020 2228 MOM 72013 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 81 20 20 mg CaCO3/L 1 Chloride 9056A 2.2 1.0 0.25 mg/L 1 Sulfate 9056A 39 1.0 0.25 mg/L 2 TDS SM 254OC-2011 200 25 25 mg/L 1 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/20201429 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 73 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-027 Description: MW-1D Matrix: Aqueous Date Sampled:10/30/2020 1455 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/20201429 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 92 70-130 Toluene-d8 101 70-130 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 11 /04/2020 1343 JAB2 11 /04/2020 0949 72084 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 74 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-027 Description: MW-1D Matrix: Aqueous Date Sampled:10/30/2020 1455 Date Received: 11 /02/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/04/2020 0529 BPK 11/03/2020 0936 72039 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 0.60 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 29 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 260 50 13 ug/L 1 Lead 7439-92-1 6020B 0.25 J 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 7.2 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B 3.0 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.6 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 75 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-028 Description: TRIP BLANK Matrix: Aqueous Date Sampled:10/30/2020 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 11/03/2020 1041 BWS 72081 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 95 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0951 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 76 of 154 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VJ27049-028 Description: TRIP BLANK Matrix: Aqueous Date Sampled:10/30/2020 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/04/2020 0951 TML 72210 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 94 70-130 1,2-Dichloroethane-d4 91 70-130 Toluene-d8 101 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 77 of 154 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 78 of 154 Inorganic non-metals - MB Sample ID: VQ72013-001 Matrix: Aqueous Batch: 72013 Analytical Method: SM 2540C-2011 Parameter Result Q Dil LOQ DL Units Analysis Date TDS ND 1 25 25 mg/L 11/02/2020 2228 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 79 of 154 Inorganic non-metals - LCS Sample ID: VQ72013-002 Matrix: Aqueous Batch: 72013 Analytical Method: SM 2540C-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date TDS 1500 1500 1 101 90-110 11/02/2020 2228 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 80 of 154 Inorganic non-metals - MB Sample ID: VQ72049-001 Matrix: Aqueous Batch: 72049 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Chloride ND 1 1.0 0.25 mg/L 11102120201618 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 81 of 154 Inorganic non-metals - LCS Sample ID: VQ72049-002 Matrix: Aqueous Batch: 72049 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Chloride 20 19 1 96 80-120 11102120201658 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 82 of 154 Inorganic non-metals - MS Sample ID: VJ27049-016MS Matrix: Aqueous Batch: 72049 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Chloride 3.7 10 13 1 95 80-120 11/02/2020 2201 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 83 of 154 Inorganic non-metals - MSD Sample ID: VJ27049-016MD Matrix: Aqueous Batch: 72049 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Chloride 3.7 10 13 1 95 0.24 80-120 20 11/02/2020 2220 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 84 of 154 Inorganic non-metals - MB Sample ID: VQ72050-001 Matrix: Aqueous Batch: 72050 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Sulfate ND 1 1.0 0.25 mg/L 11102120201618 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 85 of 154 Inorganic non-metals - LCS Sample ID: VQ72050-002 Matrix: Aqueous Batch: 72050 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 20 19 1 93 80-120 11102120201658 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 86 of 154 Inorganic non-metals - MS Sample ID: VJ27049-016MS Matrix: Aqueous Batch: 72050 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 26 10 35 1 90 80-120 11/02/2020 2201 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 87 of 154 Inorganic non-metals - MSD Sample ID: VJ27049-016MD Matrix: Aqueous Batch: 72050 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Sulfate 26 10 35 1 90 0.083 80-120 20 11/02/2020 2220 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 88 of 154 Inorganic non-metals - LCS Sample ID: VQ72118-002 Matrix: Aqueous Batch: 72118 Analytical Method: SM 2320B-2011 Spike Amount Result % Rec Parameter (mg CaCO3/L) (mg CaCO3/L) Q Dil % Rec Limit Analysis Date Alkalinity @ pH 4.5 su 100 97 1 97 90-110 10/31/2020 1405 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 89 of 154 Inorganic non-metals - LCS Sample ID: VQ72172-002 Matrix: Aqueous Batch: 72172 Analytical Method: SM 2320B-2011 Spike Amount Result % Rec Parameter (mg CaCO3/L) (mg CaCO3/L) Q Dil % Rec Limit Analysis Date Alkalinity @ pH 4.5 su 100 100 1 101 90-110 11/03/2020 1748 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 90 of 154 Inorganic non-metals - Duplicate Sample ID: VJ27049-027DU Matrix: Aqueous Batch: 72172 Analytical Method: SM 2320B-2011 Sample Amount Result % RPD Parameter (mg CaCO3/L) (mg CaCO3/L) 0 Dil % RPD Limit Analysis Date Alkalinity @ pH 4.5 su 81 82 1 0.64 20 11/03/2020 1819 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 91 of 154 Inorganic non-metals - MB Sample ID: VQ72214-001 Matrix: Aqueous Batch: 72214 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Chloride ND 1 1.0 0.25 mg/L 11/03/20201655 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 92 of 154 Inorganic non-metals - LCS Sample ID: VQ72214-002 Matrix: Aqueous Batch: 72214 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Chloride 20 19 1 97 80-120 11/03/20201733 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 93 of 154 Inorganic non-metals - MS Sample ID: VJ27049-O26MS Matrix: Aqueous Batch: 72214 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Chloride 5.8 10 15 1 92 80-120 11/03/20201907 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 94 of 154 Inorganic non-metals - MSD Sample ID: VJ27049-O26MD Matrix: Aqueous Batch: 72214 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Chloride 5.8 10 15 1 93 0.57 80-120 20 11/03/20201926 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 95 of 154 Inorganic non-metals - MB Sample ID: VQ72289-001 Matrix: Aqueous Batch: 72289 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Sulfate ND 1 1.0 0.25 mg/L 11/04/20201241 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 96 of 154 Inorganic non-metals - LCS Sample ID: VQ72289-002 Matrix: Aqueous Batch: 72289 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 20 19 1 95 80-120 11/04/20201319 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 97 of 154 Inorganic non-metals - MS Sample ID: VJ27049-O26MS Matrix: Aqueous Batch: 72289 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 16 10 25 1 89 80-120 11/04/20201454 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 98 of 154 Inorganic non-metals - MSD Sample ID: VJ27049-O26MD Matrix: Aqueous Batch: 72289 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Sulfate 16 10 25 1 90 0.47 80-120 20 11/04/20201512 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 99 of 154 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: VQ71851-001 Matrix: Aqueous Batch: 71851 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 10/30/2020 2310 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 103 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 100 of 154 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: VQ71851-002 Matrix: Aqueous Batch: 71851 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 46 1 91 70-130 10/30/2020 2157 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 104 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 101 of 154 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: VQ71945-001 Matrix: Aqueous Batch: 71945 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 11102120201010 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 95 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 102 of 154 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: VQ71945-002 Matrix: Aqueous Batch: 71945 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 52 1 105 70-130 11/02/2020 0910 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 109 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 103 of 154 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: VQ72081-001 Matrix: Aqueous Batch:72081 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 11/03/2020 0941 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 96 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 104 of 154 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: VQ72081-002 Matrix: Aqueous Batch:72081 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 47 1 93 70-130 11/03/2020 0841 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 101 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 105 of 154 Volatile Organic Compounds by GC/MS (SIM) - Duplicate Sample ID: VJ27049-018DU Matrix: Aqueous Batch:72081 Prep Method: 5030E Analytical Method: 8260D (SIM) Sample Amount Result % RPD Parameter (ug/L) (ug/L) Q Dil % RPD Limit Analysis Date 1,4-Dioxane ND ND 1 0.00 20 11/03/20201805 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 94 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 106 of 154 Volatile Organic Compounds by GC/MS (SIM) - MS Sample ID: VJ27049-019MS Matrix: Aqueous Batch:72081 Prep Method: 5030E Analytical Method: 8260D (SIM) Sample Spike Amount Amount Result % Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane ND 50 47 1 94 70-130 11/03/20201829 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 104 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 107 of 154 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ72175-001 Matrix: Aqueous Batch: 72175 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 11/03/2020 2245 Acrylonitrile ND 1 20 0.80 ug/L 11/03/2020 2245 Benzene ND 1 1.0 0.40 ug/L 11/03/2020 2245 Bromochloromethane ND 1 1.0 0.40 ug/L 11/03/2020 2245 Bromodichloromethane ND 1 1.0 0.40 ug/L 11/03/2020 2245 Bromoform ND 1 1.0 0.40 ug/L 11/03/2020 2245 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 11/03/2020 2245 2-Butanone (MEK) ND 1 10 2.0 ug/L 11/03/2020 2245 Carbon disulfide ND 1 1.0 0.40 ug/L 11/03/2020 2245 Carbon tetrachloride ND 1 1.0 0.40 ug/L 11/03/2020 2245 Chlorobenzene ND 1 1.0 0.40 ug/L 11/03/2020 2245 Chloroethane ND 1 2.0 0.40 ug/L 11/03/2020 2245 Chloroform ND 1 1.0 0.40 ug/L 11/03/2020 2245 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 11/03/2020 2245 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 11/03/2020 2245 Dibromochloromethane ND 1 1.0 0.40 ug/L 11/03/2020 2245 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 11/03/2020 2245 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 11/03/2020 2245 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 11/03/2020 2245 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 11/03/2020 2245 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 11/03/2020 2245 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 11/03/2020 2245 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 11/03/2020 2245 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 11/03/2020 2245 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 11/03/2020 2245 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 11/03/2020 2245 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 11/03/2020 2245 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 11/03/2020 2245 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 11/03/2020 2245 Ethylbenzene ND 1 1.0 0.40 ug/L 11/03/2020 2245 2-Hexanone ND 1 10 2.0 ug/L 11/03/2020 2245 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 11/03/2020 2245 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 11/03/2020 2245 Methylene chloride ND 1 1.0 0.40 ug/L 11/03/2020 2245 Styrene ND 1 1.0 0.41 ug/L 11/03/2020 2245 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 11/03/2020 2245 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 11/03/2020 2245 Tetrachloroethene ND 1 1.0 0.40 ug/L 11/03/2020 2245 Toluene ND 1 1.0 0.40 ug/L 11/03/2020 2245 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 11/03/2020 2245 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 11/03/2020 2245 Trichloroethene ND 1 1.0 0.40 ug/L 11/03/2020 2245 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 11/03/2020 2245 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 11/03/2020 2245 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 108 of 154 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ72175-001 Matrix: Aqueous Batch: 72175 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 11/03/2020 2245 Vinyl chloride ND 1 1.0 0.40 ug/L 11/03/2020 2245 Xylenes (total) ND 1 1.0 0.40 ug/L 11/03/2020 2245 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 84 70-130 1,2-Dichloroethane-d4 83 70-130 Toluene-d8 83 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 109 of 154 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ72175-002 Matrix: Aqueous Batch: 72175 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 120 1 115 60-140 11/03/2020 2134 Acrylonitrile 100 100 1 100 70-130 11/03/2020 2134 Benzene 50 48 1 97 70-130 11/03/2020 2134 Bromochloromethane 50 51 1 102 70-130 11/03/2020 2134 Bromodichloromethane 50 49 1 98 70-130 11/03/2020 2134 Bromoform 50 52 1 103 70-130 11/03/2020 2134 Bromomethane (Methyl bromide) 50 59 1 119 70-130 11/03/2020 2134 2-Butanone (MEK) 100 95 1 95 70-130 11/03/2020 2134 Carbon disulfide 50 48 1 95 70-130 11/03/2020 2134 Carbon tetrachloride 50 48 1 96 70-130 11/03/2020 2134 Chlorobenzene 50 49 1 97 70-130 11/03/2020 2134 Chloroethane 50 49 1 98 70-130 11/03/2020 2134 Chloroform 50 49 1 98 70-130 11/03/2020 2134 Chloromethane (Methyl chloride) 50 50 1 100 60-140 11/03/2020 2134 1,2-Dibromo-3-chloropropane (DBCP) 50 47 1 94 70-130 11/03/2020 2134 Dibromochloromethane 50 51 1 101 70-130 11/03/2020 2134 1,2-Dibromoethane (EDB) 50 46 1 93 70-130 11/03/2020 2134 Dibromomethane (Methylene bromide) 50 48 1 95 70-130 11/03/2020 2134 trans- 1,4-Dichloro-2-butene 50 44 1 88 70-130 11/03/2020 2134 1,2-Dichlorobenzene 50 48 1 96 70-130 11/03/2020 2134 1,4-Dichlorobenzene 50 46 1 92 70-130 11/03/2020 2134 1,1-Dichloroethane 50 49 1 99 70-130 11/03/2020 2134 1,2-Dichloroethane 50 50 1 100 70-130 11/03/2020 2134 1,1-Dichloroethene 50 50 1 99 70-130 11/03/2020 2134 cis- 1,2-Dichloroethene 50 50 1 100 70-130 11/03/2020 2134 trans- 1,2-Dichloroethene 50 49 1 99 70-130 11/03/2020 2134 1,2-Dichloropropane 50 48 1 95 70-130 11/03/2020 2134 cis- 1,3-Dichloropropene 50 47 1 93 70-130 11/03/2020 2134 trans- 1,3-Dichloropropene 50 46 1 93 70-130 11/03/2020 2134 Ethylbenzene 50 47 1 93 70-130 11/03/2020 2134 2-Hexanone 100 92 1 92 70-130 11/03/2020 2134 Methyl iodide (lodomethane) 50 52 1 104 70-130 11/03/2020 2134 4-Methyl-2-pentanone 100 99 1 99 70-130 11/03/2020 2134 Methylene chloride 50 49 1 99 70-130 11/03/2020 2134 Styrene 50 48 1 95 70-130 11/03/2020 2134 1,1,1,2-Tetrachloroethane 50 50 1 100 70-130 11/03/2020 2134 1,1,2,2-Tetrachloroethane 50 47 1 93 70-130 11/03/2020 2134 Tetrachloroethene 50 46 1 93 70-130 11/03/2020 2134 Toluene 50 48 1 95 70-130 11/03/2020 2134 1,1,1-Trichloroethane 50 48 1 96 70-130 11/03/2020 2134 1,1,2-Trichloroethane 50 49 1 98 70-130 11/03/2020 2134 Trichloroethene 50 47 1 95 70-130 11/03/2020 2134 Trichlorofluoromethane 50 51 1 102 70-130 11/03/2020 2134 1,2,3-Trichloropropane 50 46 1 92 70-130 11/03/2020 2134 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 110 of 154 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ72175-002 Matrix: Aqueous Batch: 72175 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 44 1 88 60-140 11/03/2020 2134 Vinyl chloride 50 55 1 110 70-130 11/03/2020 2134 Xylenes (total) 100 94 1 94 70-130 11/03/2020 2134 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 100 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 111 of 154 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ72175-001 Matrix: Aqueous Batch: 72175 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 11/03/2020 2245 Acrylonitrile ND 1 20 0.80 ug/L 11/03/2020 2245 Benzene ND 1 1.0 0.40 ug/L 11/03/2020 2245 Bromochloromethane ND 1 1.0 0.40 ug/L 11/03/2020 2245 Bromodichloromethane ND 1 1.0 0.40 ug/L 11/03/2020 2245 Bromoform ND 1 1.0 0.40 ug/L 11/03/2020 2245 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 11/03/2020 2245 2-Butanone (MEK) ND 1 10 2.0 ug/L 11/03/2020 2245 Carbon disulfide ND 1 1.0 0.40 ug/L 11/03/2020 2245 Carbon tetrachloride ND 1 1.0 0.40 ug/L 11/03/2020 2245 Chlorobenzene ND 1 1.0 0.40 ug/L 11/03/2020 2245 Chloroethane ND 1 2.0 0.40 ug/L 11/03/2020 2245 Chloroform ND 1 1.0 0.40 ug/L 11/03/2020 2245 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 11/03/2020 2245 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 11/03/2020 2245 Dibromochloromethane ND 1 1.0 0.40 ug/L 11/03/2020 2245 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 11/03/2020 2245 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 11/03/2020 2245 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 11/03/2020 2245 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 11/03/2020 2245 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 11/03/2020 2245 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 11/03/2020 2245 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 11/03/2020 2245 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 11/03/2020 2245 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 11/03/2020 2245 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 11/03/2020 2245 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 11/03/2020 2245 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 11/03/2020 2245 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 11/03/2020 2245 Ethylbenzene ND 1 1.0 0.40 ug/L 11/03/2020 2245 2-Hexanone ND 1 10 2.0 ug/L 11/03/2020 2245 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 11/03/2020 2245 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 11/03/2020 2245 Methylene chloride ND 1 1.0 0.40 ug/L 11/03/2020 2245 Styrene ND 1 1.0 0.41 ug/L 11/03/2020 2245 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 11/03/2020 2245 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 11/03/2020 2245 Tetrachloroethene ND 1 1.0 0.40 ug/L 11/03/2020 2245 Tetrahydrofuran ND 1 5.0 1.0 ug/L 11/03/2020 2245 Toluene ND 1 1.0 0.40 ug/L 11/03/2020 2245 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 11/03/2020 2245 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 11/03/2020 2245 Trichloroethene ND 1 1.0 0.40 ug/L 11/03/2020 2245 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 11/03/2020 2245 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 112 of 154 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ72175-001 Matrix: Aqueous Batch: 72175 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 11/03/2020 2245 Vinyl acetate ND 1 5.0 1.2 ug/L 11/03/2020 2245 Vinyl chloride ND 1 1.0 0.40 ug/L 11/03/2020 2245 Xylenes (total) ND 1 1.0 0.40 ug/L 11/03/2020 2245 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 84 70-130 1,2-Dichloroethane-d4 83 70-130 Toluene-d8 83 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 113 of 154 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ72175-002 Matrix: Aqueous Batch: 72175 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 120 1 115 60-140 11/03/2020 2134 Acrylonitrile 100 100 1 100 70-130 11/03/2020 2134 Benzene 50 48 1 97 70-130 11/03/2020 2134 Bromochloromethane 50 51 1 102 70-130 11/03/2020 2134 Bromodichloromethane 50 49 1 98 70-130 11/03/2020 2134 Bromoform 50 52 1 103 70-130 11/03/2020 2134 Bromomethane (Methyl bromide) 50 59 1 119 70-130 11/03/2020 2134 2-Butanone (MEK) 100 95 1 95 70-130 11/03/2020 2134 Carbon disulfide 50 48 1 95 70-130 11/03/2020 2134 Carbon tetrachloride 50 48 1 96 70-130 11/03/2020 2134 Chlorobenzene 50 49 1 97 70-130 11/03/2020 2134 Chloroethane 50 49 1 98 70-130 11/03/2020 2134 Chloroform 50 49 1 98 70-130 11/03/2020 2134 Chloromethane (Methyl chloride) 50 50 1 100 60-140 11/03/2020 2134 1,2-Dibromo-3-chloropropane (DBCP) 50 47 1 94 70-130 11/03/2020 2134 Dibromochloromethane 50 51 1 101 70-130 11/03/2020 2134 1,2-Dibromoethane (EDB) 50 46 1 93 70-130 11/03/2020 2134 Dibromomethane (Methylene bromide) 50 48 1 95 70-130 11/03/2020 2134 trans- 1,4-Dichloro-2-butene 50 44 1 88 70-130 11/03/2020 2134 1,2-Dichlorobenzene 50 48 1 96 70-130 11/03/2020 2134 1,4-Dichlorobenzene 50 46 1 92 70-130 11/03/2020 2134 1,1-Dichloroethane 50 49 1 99 70-130 11/03/2020 2134 1,2-Dichloroethane 50 50 1 100 70-130 11/03/2020 2134 1,1-Dichloroethene 50 50 1 99 70-130 11/03/2020 2134 cis- 1,2-Dichloroethene 50 50 1 100 70-130 11/03/2020 2134 trans- 1,2-Dichloroethene 50 49 1 99 70-130 11/03/2020 2134 1,2-Dichloropropane 50 48 1 95 70-130 11/03/2020 2134 cis- 1,3-Dichloropropene 50 47 1 93 70-130 11/03/2020 2134 trans- 1,3-Dichloropropene 50 46 1 93 70-130 11/03/2020 2134 Ethylbenzene 50 47 1 93 70-130 11/03/2020 2134 2-Hexanone 100 92 1 92 70-130 11/03/2020 2134 Methyl iodide (lodomethane) 50 52 1 104 70-130 11/03/2020 2134 4-Methyl-2-pentanone 100 99 1 99 70-130 11/03/2020 2134 Methylene chloride 50 49 1 99 70-130 11/03/2020 2134 Styrene 50 48 1 95 70-130 11/03/2020 2134 1,1,1,2-Tetrachloroethane 50 50 1 100 70-130 11/03/2020 2134 1,1,2,2-Tetrachloroethane 50 47 1 93 70-130 11/03/2020 2134 Tetrachloroethene 50 46 1 93 70-130 11/03/2020 2134 Tetrahydrofuran 50 46 1 92 70-130 11/03/2020 2134 Toluene 50 48 1 95 70-130 11/03/2020 2134 1,1,1-Trichloroethane 50 48 1 96 70-130 11/03/2020 2134 1,1,2-Trichloroethane 50 49 1 98 70-130 11/03/2020 2134 Trichloroethene 50 47 1 95 70-130 11/03/2020 2134 Trichlorofluoromethane 50 51 1 102 70-130 11/03/2020 2134 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 114 of 154 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ72175-002 Matrix: Aqueous Batch: 72175 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,2,3-Trichloropropane 50 46 1 92 70-130 11/03/2020 2134 Vinyl acetate 50 44 1 88 60-140 11/03/2020 2134 Vinyl chloride 50 55 1 110 70-130 11/03/2020 2134 Xylenes (total) 100 94 1 94 70-130 11/03/2020 2134 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 100 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 115 of 154 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ72210-001 Matrix: Aqueous Batch: 72210 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 11/04/2020 0912 Acrylonitrile ND 1 20 0.80 ug/L 11/04/2020 0912 Benzene ND 1 1.0 0.40 ug/L 11/04/2020 0912 Bromochloromethane ND 1 1.0 0.40 ug/L 11/04/2020 0912 Bromodichloromethane ND 1 1.0 0.40 ug/L 11/04/2020 0912 Bromoform ND 1 1.0 0.40 ug/L 11/04/2020 0912 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 11/04/2020 0912 2-Butanone (MEK) ND 1 10 2.0 ug/L 11/04/2020 0912 Carbon disulfide ND 1 1.0 0.40 ug/L 11/04/2020 0912 Carbon tetrachloride ND 1 1.0 0.40 ug/L 11/04/2020 0912 Chlorobenzene ND 1 1.0 0.40 ug/L 11/04/2020 0912 Chloroethane ND 1 2.0 0.40 ug/L 11/04/2020 0912 Chloroform ND 1 1.0 0.40 ug/L 11/04/2020 0912 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 11/04/2020 0912 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 11/04/2020 0912 Dibromochloromethane ND 1 1.0 0.40 ug/L 11/04/2020 0912 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 11/04/2020 0912 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 11/04/2020 0912 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 11/04/2020 0912 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 11/04/2020 0912 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 11/04/2020 0912 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 11/04/2020 0912 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 11/04/2020 0912 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 11/04/2020 0912 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 11/04/2020 0912 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 11/04/2020 0912 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 11/04/2020 0912 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 11/04/2020 0912 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 11/04/2020 0912 Ethylbenzene ND 1 1.0 0.40 ug/L 11/04/2020 0912 2-Hexanone ND 1 10 2.0 ug/L 11/04/2020 0912 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 11/04/2020 0912 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 11/04/2020 0912 Methylene chloride ND 1 1.0 0.40 ug/L 11/04/2020 0912 Styrene ND 1 1.0 0.41 ug/L 11/04/2020 0912 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 11/04/2020 0912 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 11/04/2020 0912 Tetrachloroethene ND 1 1.0 0.40 ug/L 11/04/2020 0912 Toluene ND 1 1.0 0.40 ug/L 11/04/2020 0912 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 11/04/2020 0912 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 11/04/2020 0912 Trichloroethene ND 1 1.0 0.40 ug/L 11/04/2020 0912 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 11/04/2020 0912 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 11/04/2020 0912 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 116 of 154 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ72210-001 Matrix: Aqueous Batch: 72210 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 11/04/2020 0912 Vinyl chloride ND 1 1.0 0.40 ug/L 11/04/2020 0912 Xylenes (total) ND 1 1.0 0.40 ug/L 11/04/2020 0912 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 94 70-130 Toluene-d8 103 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 117 of 154 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ72210-002 Matrix: Aqueous Batch: 72210 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 84 1 84 60-140 11/04/2020 0745 Acrylonitrile 100 81 1 81 70-130 11/04/2020 0745 Benzene 50 49 1 99 70-130 11/04/2020 0745 Bromochloromethane 50 48 1 96 70-130 11/04/2020 0745 Bromodichloromethane 50 48 1 97 70-130 11/04/2020 0745 Bromoform 50 53 1 106 70-130 11/04/2020 0745 Bromomethane (Methyl bromide) 50 50 1 99 70-130 11/04/2020 0745 2-Butanone (MEK) 100 91 1 91 70-130 11/04/2020 0745 Carbon disulfide 50 47 1 94 70-130 11/04/2020 0745 Carbon tetrachloride 50 49 1 97 70-130 11/04/2020 0745 Chlorobenzene 50 53 1 106 70-130 11/04/2020 0745 Chloroethane 50 47 1 94 70-130 11/04/2020 0745 Chloroform 50 46 1 92 70-130 11/04/2020 0745 Chloromethane (Methyl chloride) 50 48 1 97 60-140 11/04/2020 0745 1,2-Dibromo-3-chloropropane (DBCP) 50 42 1 83 70-130 11/04/2020 0745 Dibromochloromethane 50 51 1 102 70-130 11/04/2020 0745 1,2-Dibromoethane (EDB) 50 52 1 104 70-130 11/04/2020 0745 Dibromomethane (Methylene bromide) 50 50 1 100 70-130 11/04/2020 0745 trans- 1,4-Dichloro-2-butene 50 53 1 106 70-130 11/04/2020 0745 1,2-Dichlorobenzene 50 51 1 101 70-130 11/04/2020 0745 1,4-Dichlorobenzene 50 52 1 104 70-130 11/04/2020 0745 1,1-Dichloroethane 50 47 1 95 70-130 11/04/2020 0745 1,2-Dichloroethane 50 50 1 101 70-130 11/04/2020 0745 1,1-Dichloroethene 50 47 1 95 70-130 11/04/2020 0745 cis- 1,2-Dichloroethene 50 47 1 94 70-130 11/04/2020 0745 trans- 1,2-Dichloroethene 50 47 1 93 70-130 11/04/2020 0745 1,2-Dichloropropane 50 49 1 97 70-130 11/04/2020 0745 cis- 1,3-Dichloropropene 50 50 1 100 70-130 11/04/2020 0745 trans- 1,3-Dichloropropene 50 52 1 105 70-130 11/04/2020 0745 Ethylbenzene 50 53 1 106 70-130 11/04/2020 0745 2-Hexanone 100 100 1 104 70-130 11/04/2020 0745 Methyl iodide (lodomethane) 50 49 1 97 70-130 11/04/2020 0745 4-Methyl-2-pentanone 100 100 1 101 70-130 11/04/2020 0745 Methylene chloride 50 45 1 90 70-130 11/04/2020 0745 Styrene 50 53 1 105 70-130 11/04/2020 0745 1,1,1,2-Tetrachloroethane 50 53 1 106 70-130 11/04/2020 0745 1,1,2,2-Tetrachloroethane 50 50 1 101 70-130 11/04/2020 0745 Tetrachloroethene 50 57 1 113 70-130 11/04/2020 0745 Toluene 50 52 1 105 70-130 11/04/2020 0745 1,1,1-Trichloroethane 50 48 1 96 70-130 11/04/2020 0745 1,1,2-Trichloroethane 50 51 1 102 70-130 11/04/2020 0745 Trichloroethene 50 52 1 103 70-130 11/04/2020 0745 Trichlorofluoromethane 50 50 1 100 70-130 11/04/2020 0745 1,2,3-Trichloropropane 50 52 1 104 70-130 11/04/2020 0745 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 118 of 154 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ72210-002 Matrix: Aqueous Batch: 72210 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 52 1 104 60-140 11/04/2020 0745 Vinyl chloride 50 51 1 102 70-130 11/04/2020 0745 Xylenes (total) 100 110 1 107 70-130 11/04/2020 0745 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 93 70-130 Toluene-d8 99 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 119 of 154 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ72210-001 Matrix: Aqueous Batch: 72210 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 11/04/2020 0912 Acrylonitrile ND 1 20 0.80 ug/L 11/04/2020 0912 Benzene ND 1 1.0 0.40 ug/L 11/04/2020 0912 Bromochloromethane ND 1 1.0 0.40 ug/L 11/04/2020 0912 Bromodichloromethane ND 1 1.0 0.40 ug/L 11/04/2020 0912 Bromoform ND 1 1.0 0.40 ug/L 11/04/2020 0912 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 11/04/2020 0912 2-Butanone (MEK) ND 1 10 2.0 ug/L 11/04/2020 0912 Carbon disulfide ND 1 1.0 0.40 ug/L 11/04/2020 0912 Carbon tetrachloride ND 1 1.0 0.40 ug/L 11/04/2020 0912 Chlorobenzene ND 1 1.0 0.40 ug/L 11/04/2020 0912 Chloroethane ND 1 2.0 0.40 ug/L 11/04/2020 0912 Chloroform ND 1 1.0 0.40 ug/L 11/04/2020 0912 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 11/04/2020 0912 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 11/04/2020 0912 Dibromochloromethane ND 1 1.0 0.40 ug/L 11/04/2020 0912 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 11/04/2020 0912 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 11/04/2020 0912 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 11/04/2020 0912 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 11/04/2020 0912 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 11/04/2020 0912 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 11/04/2020 0912 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 11/04/2020 0912 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 11/04/2020 0912 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 11/04/2020 0912 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 11/04/2020 0912 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 11/04/2020 0912 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 11/04/2020 0912 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 11/04/2020 0912 Ethylbenzene ND 1 1.0 0.40 ug/L 11/04/2020 0912 2-Hexanone ND 1 10 2.0 ug/L 11/04/2020 0912 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 11/04/2020 0912 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 11/04/2020 0912 Methylene chloride ND 1 1.0 0.40 ug/L 11/04/2020 0912 Styrene ND 1 1.0 0.41 ug/L 11/04/2020 0912 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 11/04/2020 0912 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 11/04/2020 0912 Tetrachloroethene ND 1 1.0 0.40 ug/L 11/04/2020 0912 Tetrahydrofuran ND 1 5.0 1.0 ug/L 11/04/2020 0912 Toluene ND 1 1.0 0.40 ug/L 11/04/2020 0912 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 11/04/2020 0912 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 11/04/2020 0912 Trichloroethene ND 1 1.0 0.40 ug/L 11/04/2020 0912 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 11/04/2020 0912 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 120 of 154 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ72210-001 Matrix: Aqueous Batch: 72210 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 11/04/2020 0912 Vinyl acetate ND 1 5.0 1.2 ug/L 11/04/2020 0912 Vinyl chloride ND 1 1.0 0.40 ug/L 11/04/2020 0912 Xylenes (total) ND 1 1.0 0.40 ug/L 11/04/2020 0912 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 94 70-130 Toluene-d8 103 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 121 of 154 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ72210-002 Matrix: Aqueous Batch: 72210 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 84 1 84 60-140 11/04/2020 0745 Acrylonitrile 100 81 1 81 70-130 11/04/2020 0745 Benzene 50 49 1 99 70-130 11/04/2020 0745 Bromochloromethane 50 48 1 96 70-130 11/04/2020 0745 Bromodichloromethane 50 48 1 97 70-130 11/04/2020 0745 Bromoform 50 53 1 106 70-130 11/04/2020 0745 Bromomethane (Methyl bromide) 50 50 1 99 70-130 11/04/2020 0745 2-Butanone (MEK) 100 91 1 91 70-130 11/04/2020 0745 Carbon disulfide 50 47 1 94 70-130 11/04/2020 0745 Carbon tetrachloride 50 49 1 97 70-130 11/04/2020 0745 Chlorobenzene 50 53 1 106 70-130 11/04/2020 0745 Chloroethane 50 47 1 94 70-130 11/04/2020 0745 Chloroform 50 46 1 92 70-130 11/04/2020 0745 Chloromethane (Methyl chloride) 50 48 1 97 60-140 11/04/2020 0745 1,2-Dibromo-3-chloropropane (DBCP) 50 42 1 83 70-130 11/04/2020 0745 Dibromochloromethane 50 51 1 102 70-130 11/04/2020 0745 1,2-Dibromoethane (EDB) 50 52 1 104 70-130 11/04/2020 0745 Dibromomethane (Methylene bromide) 50 50 1 100 70-130 11/04/2020 0745 trans- 1,4-Dichloro-2-butene 50 53 1 106 70-130 11/04/2020 0745 1,2-Dichlorobenzene 50 51 1 101 70-130 11/04/2020 0745 1,4-Dichlorobenzene 50 52 1 104 70-130 11/04/2020 0745 1,1-Dichloroethane 50 47 1 95 70-130 11/04/2020 0745 1,2-Dichloroethane 50 50 1 101 70-130 11/04/2020 0745 1,1-Dichloroethene 50 47 1 95 70-130 11/04/2020 0745 cis- 1,2-Dichloroethene 50 47 1 94 70-130 11/04/2020 0745 trans- 1,2-Dichloroethene 50 47 1 93 70-130 11/04/2020 0745 1,2-Dichloropropane 50 49 1 97 70-130 11/04/2020 0745 cis- 1,3-Dichloropropene 50 50 1 100 70-130 11/04/2020 0745 trans- 1,3-Dichloropropene 50 52 1 105 70-130 11/04/2020 0745 Ethylbenzene 50 53 1 106 70-130 11/04/2020 0745 2-Hexanone 100 100 1 104 70-130 11/04/2020 0745 Methyl iodide (lodomethane) 50 49 1 97 70-130 11/04/2020 0745 4-Methyl-2-pentanone 100 100 1 101 70-130 11/04/2020 0745 Methylene chloride 50 45 1 90 70-130 11/04/2020 0745 Styrene 50 53 1 105 70-130 11/04/2020 0745 1,1,1,2-Tetrachloroethane 50 53 1 106 70-130 11/04/2020 0745 1,1,2,2-Tetrachloroethane 50 50 1 101 70-130 11/04/2020 0745 Tetrachloroethene 50 57 1 113 70-130 11/04/2020 0745 Tetrahydrofuran 50 45 1 90 70-130 11/04/2020 0745 Toluene 50 52 1 105 70-130 11/04/2020 0745 1,1,1-Trichloroethane 50 48 1 96 70-130 11/04/2020 0745 1,1,2-Trichloroethane 50 51 1 102 70-130 11/04/2020 0745 Trichloroethene 50 52 1 103 70-130 11/04/2020 0745 Trichlorofluoromethane 50 50 1 100 70-130 11/04/2020 0745 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 122 of 154 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ72210-002 Matrix: Aqueous Batch: 72210 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,2,3-Trichloropropane 50 52 1 104 70-130 11/04/2020 0745 Vinyl acetate 50 52 1 104 60-140 11/04/2020 0745 Vinyl chloride 50 51 1 102 70-130 11/04/2020 0745 Xylenes (total) 100 110 1 107 70-130 11/04/2020 0745 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 93 70-130 Toluene-d8 99 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 123 of 154 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: VQ72222-001 Matrix: Aqueous Batch:72222 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 11/04/20201019 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 94 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 124 of 154 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: VQ72222-002 Matrix: Aqueous Batch:72222 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 52 1 104 70-130 11/04/2020 0830 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 108 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 125 of 154 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ72533-001 Matrix: Aqueous Batch: 72533 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 11/06/2020 1022 Acrylonitrile ND 1 20 0.80 ug/L 11/06/2020 1022 Benzene ND 1 1.0 0.40 ug/L 11/06/2020 1022 Bromochloromethane ND 1 1.0 0.40 ug/L 11/06/2020 1022 Bromodichloromethane ND 1 1.0 0.40 ug/L 11/06/2020 1022 Bromoform ND 1 1.0 0.40 ug/L 11/06/2020 1022 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 11/06/2020 1022 2-Butanone (MEK) ND 1 10 2.0 ug/L 11/06/2020 1022 Carbon disulfide ND 1 1.0 0.40 ug/L 11/06/2020 1022 Carbon tetrachloride ND 1 1.0 0.40 ug/L 11/06/2020 1022 Chlorobenzene ND 1 1.0 0.40 ug/L 11/06/2020 1022 Chloroethane ND 1 2.0 0.40 ug/L 11/06/2020 1022 Chloroform ND 1 1.0 0.40 ug/L 11/06/2020 1022 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 11/06/2020 1022 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 11/06/2020 1022 Dibromochloromethane ND 1 1.0 0.40 ug/L 11/06/2020 1022 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 11/06/2020 1022 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 11/06/2020 1022 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 11/06/2020 1022 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 11/06/2020 1022 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 11/06/2020 1022 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 11/06/2020 1022 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 11/06/2020 1022 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 11/06/2020 1022 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 11/06/2020 1022 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 11/06/2020 1022 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 11/06/2020 1022 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 11/06/2020 1022 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 11/06/2020 1022 Ethylbenzene ND 1 1.0 0.40 ug/L 11/06/2020 1022 2-Hexanone ND 1 10 2.0 ug/L 11/06/2020 1022 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 11/06/2020 1022 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 11/06/2020 1022 Methylene chloride ND 1 1.0 0.40 ug/L 11/06/2020 1022 Styrene ND 1 1.0 0.41 ug/L 11/06/2020 1022 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 11/06/2020 1022 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 11/06/2020 1022 Tetrachloroethene ND 1 1.0 0.40 ug/L 11/06/2020 1022 Tetrahydrofuran ND 1 5.0 1.0 ug/L 11/06/2020 1022 Toluene ND 1 1.0 0.40 ug/L 11/06/2020 1022 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 11/06/2020 1022 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 11/06/2020 1022 Trichloroethene ND 1 1.0 0.40 ug/L 11/06/2020 1022 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 11/06/2020 1022 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 126 of 154 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ72533-001 Matrix: Aqueous Batch: 72533 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 11/06/2020 1022 Vinyl acetate ND 1 5.0 1.2 ug/L 11/06/2020 1022 Vinyl chloride ND 1 1.0 0.40 ug/L 11/06/2020 1022 Xylenes (total) ND 1 1.0 0.40 ug/L 11/06/2020 1022 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 93 70-130 1,2-Dichloroethane-d4 96 70-130 Toluene-d8 103 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 127 of 154 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ72533-002 Matrix: Aqueous Batch: 72533 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 94 1 94 60-140 11/06/2020 0900 Acrylonitrile 100 97 1 97 70-130 11/06/2020 0900 Benzene 50 48 1 97 70-130 11/06/2020 0900 Bromochloromethane 50 46 1 92 70-130 11/06/2020 0900 Bromodichloromethane 50 46 1 92 70-130 11/06/2020 0900 Bromoform 50 51 1 103 70-130 11/06/2020 0900 Bromomethane (Methyl bromide) 50 52 1 105 70-130 11/06/2020 0900 2-Butanone (MEK) 100 98 1 98 70-130 11/06/2020 0900 Carbon disulfide 50 45 1 90 70-130 11/06/2020 0900 Carbon tetrachloride 50 46 1 92 70-130 11/06/2020 0900 Chlorobenzene 50 51 1 102 70-130 11/06/2020 0900 Chloroethane 50 47 1 94 70-130 11/06/2020 0900 Chloroform 50 44 1 88 70-130 11/06/2020 0900 Chloromethane (Methyl chloride) 50 51 1 102 60-140 11/06/2020 0900 1,2-Dibromo-3-chloropropane (DBCP) 50 43 1 87 70-130 11/06/2020 0900 Dibromochloromethane 50 50 1 100 70-130 11/06/2020 0900 1,2-Dibromoethane (EDB) 50 51 1 102 70-130 11/06/2020 0900 Dibromomethane (Methylene bromide) 50 49 1 98 70-130 11/06/2020 0900 trans- 1,4-Dichloro-2-butene 50 52 1 105 70-130 11/06/2020 0900 1,2-Dichlorobenzene 50 52 1 103 70-130 11/06/2020 0900 1,4-Dichlorobenzene 50 52 1 104 70-130 11/06/2020 0900 1,1-Dichloroethane 50 47 1 93 70-130 11/06/2020 0900 1,2-Dichloroethane 50 49 1 99 70-130 11/06/2020 0900 1,1-Dichloroethene 50 45 1 90 70-130 11/06/2020 0900 cis- 1,2-Dichloroethene 50 45 1 91 70-130 11/06/2020 0900 trans- 1,2-Dichloroethene 50 45 1 91 70-130 11/06/2020 0900 1,2-Dichloropropane 50 49 1 97 70-130 11/06/2020 0900 cis- 1,3-Dichloropropene 50 48 1 96 70-130 11/06/2020 0900 trans- 1,3-Dichloropropene 50 50 1 100 70-130 11/06/2020 0900 Ethylbenzene 50 51 1 103 70-130 11/06/2020 0900 2-Hexanone 100 110 1 110 70-130 11/06/2020 0900 Methyl iodide (lodomethane) 50 46 1 92 70-130 11/06/2020 0900 4-Methyl-2-pentanone 100 100 1 105 70-130 11/06/2020 0900 Methylene chloride 50 44 1 88 70-130 11/06/2020 0900 Styrene 50 50 1 101 70-130 11/06/2020 0900 1,1,1,2-Tetrachloroethane 50 51 1 102 70-130 11/06/2020 0900 1,1,2,2-Tetrachloroethane 50 50 1 100 70-130 11/06/2020 0900 Tetrachloroethene 50 55 1 109 70-130 11/06/2020 0900 Tetrahydrofuran 50 49 1 98 70-130 11/06/2020 0900 Toluene 50 51 1 101 70-130 11/06/2020 0900 1,1,1-Trichloroethane 50 45 1 91 70-130 11/06/2020 0900 1,1,2-Trichloroethane 50 51 1 102 70-130 11/06/2020 0900 Trichloroethene 50 50 1 99 70-130 11/06/2020 0900 Trichlorofluoromethane 50 47 1 94 70-130 11/06/2020 0900 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 128 of 154 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ72533-002 Matrix: Aqueous Batch: 72533 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,2,3-Trichloropropane 50 50 1 101 70-130 11/06/2020 0900 Vinyl acetate 50 50 1 100 60-140 11/06/2020 0900 Vinyl chloride 50 52 1 105 70-130 11/06/2020 0900 Xylenes (total) 100 100 1 103 70-130 11/06/2020 0900 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 101 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 129 of 154 ICP-MS Metals - MB Sample ID: VQ71494-001 Matrix: Aqueous Batch: 71494 Prep Method: 3005A Analytical Method: 6020B Prep Date: 10/30/2020 1549 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 11/03/2020 0029 Arsenic ND 1 2.0 1.3 ug/L 11/03/2020 0029 Barium ND 1 5.0 1.3 ug/L 11/03/2020 0029 Beryllium ND 1 0.40 0.15 ug/L 11/03/2020 0029 Cadmium ND 1 0.50 0.13 ug/L 11/03/2020 0029 Chromium ND 1 5.0 1.3 ug/L 11/03/2020 0029 Cobalt ND 1 5.0 1.3 ug/L 11/03/2020 0029 Copper ND 1 5.0 1.3 ug/L 11/03/2020 0029 Lead ND 1 1.0 0.25 ug/L 11/03/2020 0029 Nickel ND 1 5.0 1.3 ug/L 11/03/2020 0029 Selenium ND 1 5.0 1.3 ug/L 11/03/2020 0029 Silver ND 1 1.0 0.25 ug/L 11/03/2020 0029 Thallium ND 1 0.50 0.15 ug/L 11/03/2020 0029 Vanadium ND 1 5.0 2.5 ug/L 11/03/2020 0029 Zinc ND 1 10 2.5 ug/L 11/03/2020 0029 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 130 of 154 ICP-MS Metals - LCS Sample ID: VQ71494-002 Matrix: Aqueous Batch: 71494 Prep Method: 3005A Analytical Method: 6020B Prep Date: 10/30/2020 1549 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 99 1 99 80-120 11/03/2020 0036 Arsenic 100 100 1 101 80-120 11/03/2020 0036 Barium 100 95 1 95 80-120 11/03/2020 0036 Beryllium 100 100 1 103 80-120 11/03/2020 0036 Cadmium 100 100 1 100 80-120 11/03/2020 0036 Chromium 100 110 1 108 80-120 11/03/2020 0036 Cobalt 100 110 1 110 80-120 11/03/2020 0036 Copper 100 100 1 104 80-120 11/03/2020 0036 Lead 100 110 1 112 80-120 11/03/2020 0036 Nickel 100 110 1 108 80-120 11/03/2020 0036 Selenium 100 92 1 92 80-120 11/03/2020 0036 Silver 100 110 1 105 80-120 11/03/2020 0036 Thallium 100 110 1 112 80-120 11/03/2020 0036 Vanadium 100 110 1 107 80-120 11/03/2020 0036 Zinc 100 94 1 94 80-120 11/03/2020 0036 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 131 of 154 ICP-MS Metals - MS Sample ID: VJ27049-007MS Matrix: Aqueous Batch: 71494 Prep Method: 3005A Analytical Method: 6020B Prep Date: 10/30/2020 1549 Sample Spike Amount Amount Result % Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony ND 100 100 1 101 70-130 11/03/2020 0151 Arsenic ND 100 98 1 98 70-130 11/03/2020 0151 Barium 140 100 240 1 106 70-130 11/03/2020 0151 Beryllium ND 100 100 1 100 70-130 11/03/2020 0151 Cadmium ND 100 100 1 100 70-130 11/03/2020 0151 Chromium 4.4 100 100 1 99 70-130 11/03/2020 0151 Cobalt ND 100 97 1 97 70-130 11/03/2020 0151 Copper ND 100 96 1 96 70-130 11/03/2020 0151 Lead ND 100 100 1 105 70-130 11/03/2020 0151 Nickel 4.4 100 97 1 92 70-130 11/03/2020 0151 Selenium ND 100 94 1 94 70-130 11/03/2020 0151 Silver ND 100 98 1 98 70-130 11/03/2020 0151 Thallium ND 100 110 1 107 70-130 11/03/2020 0151 Vanadium ND 100 98 1 98 70-130 11/03/2020 0151 Zinc 4.8 100 100 1 97 70-130 11/03/2020 0151 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 132 of 154 ICP-MS Metals - MSD Sample ID: VJ27049-007MD Matrix: Aqueous Batch: 71494 Prep Method: 3005A Analytical Method: 6020B Prep Date: 10/30/2020 1549 Sample Spike Amount Amount Result % Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Antimony ND 100 100 1 103 2.1 70-130 20 11/03/2020 0159 Arsenic ND 100 100 1 102 3.5 70-130 20 11/03/2020 0159 Barium 140 100 250 1 114 3.1 70-130 20 11/03/2020 0159 Beryllium ND 100 100 1 103 3.0 70-130 20 11/03/2020 0159 Cadmium ND 100 100 1 102 1.9 70-130 20 11/03/2020 0159 Chromium 4.4 100 110 1 103 3.5 70-130 20 11/03/2020 0159 Cobalt ND 100 100 1 100 3.5 70-130 20 11/03/2020 0159 Copper ND 100 99 1 99 2.8 70-130 20 11/03/2020 0159 Lead ND 100 110 1 107 2.7 70-130 20 11/03/2020 0159 Nickel 4.4 100 100 1 96 3.4 70-130 20 11/03/2020 0159 Selenium ND 100 97 1 97 3.5 70-130 20 11/03/2020 0159 Silver ND 100 100 1 101 2.4 70-130 20 11/03/2020 0159 Thallium ND 100 110 1 109 1.8 70-130 20 11/03/2020 0159 Vanadium ND 100 110 1 105 7.6 70-130 20 11/03/2020 0159 Zinc 4.8 100 100 1 100 3.0 70-130 20 11/03/2020 0159 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 133 of 154 ICP-MS Metals - MB Sample ID: VQ71917-001 Matrix: Aqueous Batch: 71917 Prep Method: 3005A Analytical Method: 6020B Prep Date: 11/03/2020 0936 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 11/03/2020 2159 Arsenic ND 1 2.0 1.3 ug/L 11/03/2020 2159 Barium ND 1 5.0 1.3 ug/L 11/03/2020 2159 Beryllium ND 1 0.40 0.15 ug/L 11/03/2020 2159 Cadmium ND 1 0.50 0.13 ug/L 11/03/2020 2159 Chromium ND 1 5.0 1.3 ug/L 11/03/2020 2159 Cobalt ND 1 5.0 1.3 ug/L 11/03/2020 2159 Copper ND 1 5.0 1.3 ug/L 11/03/2020 2159 Iron ND 1 50 13 ug/L 11/03/2020 2159 Lead ND 1 1.0 0.25 ug/L 11/03/2020 2159 Manganese ND 1 5.0 1.3 ug/L 11/03/2020 2159 Nickel ND 1 5.0 1.3 ug/L 11/03/2020 2159 Selenium ND 1 5.0 1.3 ug/L 11/03/2020 2159 Silver ND 1 1.0 0.25 ug/L 11/03/2020 2159 Thallium ND 1 0.50 0.15 ug/L 11/03/2020 2159 Vanadium ND 1 5.0 2.5 ug/L 11/03/2020 2159 Zinc ND 1 10 2.5 ug/L 11/03/2020 2159 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 134 of 154 ICP-MS Metals - LCS Sample ID: VQ71917-002 Matrix: Aqueous Batch: 71917 Prep Method: 3005A Analytical Method: 6020B Prep Date: 11/03/2020 0936 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 110 1 105 80-120 11/03/2020 2207 Arsenic 100 110 1 106 80-120 11/03/2020 2207 Barium 100 100 1 100 80-120 11/03/2020 2207 Beryllium 100 97 1 97 80-120 11/03/2020 2207 Cadmium 100 100 1 103 80-120 11/03/2020 2207 Chromium 100 110 1 114 80-120 11/03/2020 2207 Cobalt 100 110 1 113 80-120 11/03/2020 2207 Copper 100 100 1 101 80-120 11/03/2020 2207 Iron 1000 1000 1 101 80-120 11/03/2020 2207 Lead 100 110 1 112 80-120 11/03/2020 2207 Manganese 100 110 1 112 80-120 11/03/2020 2207 Nickel 100 110 1 111 80-120 11/03/2020 2207 Selenium 100 98 1 98 80-120 11/03/2020 2207 Silver 100 110 1 106 80-120 11/03/2020 2207 Thallium 100 110 1 115 80-120 11/03/2020 2207 Vanadium 100 110 1 ill 80-120 11/03/2020 2207 Zinc 100 91 1 91 80-120 11/03/2020 2207 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 135 of 154 ICP-MS Metals - MS Sample ID: VJ27049-01OMS Matrix: Aqueous Batch: 71917 Prep Method: 3005A Analytical Method: 6020B Prep Date: 11/03/2020 0936 Sample Spike Amount Amount Result % Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony ND 100 110 1 106 70-130 11/03/2020 2237 Arsenic ND 100 110 1 105 70-130 11/03/2020 2237 Barium 120 100 230 1 107 70-130 11/03/2020 2237 Beryllium ND 100 100 1 102 70-130 11/03/2020 2237 Cadmium ND 100 110 1 108 70-130 11/03/2020 2237 Chromium 2.1 100 110 1 106 70-130 11/03/2020 2237 Cobalt ND 100 110 1 106 70-130 11/03/2020 2237 Copper ND 100 110 1 106 70-130 11/03/2020 2237 Lead ND 100 110 1 105 70-130 11/03/2020 2237 Nickel 3.5 100 110 1 102 70-130 11/03/2020 2237 Selenium ND 100 100 1 102 70-130 11/03/2020 2237 Silver ND 100 110 1 105 70-130 11/03/2020 2237 Thallium ND 100 110 1 109 70-130 11/03/2020 2237 Vanadium 2.7 100 110 1 104 70-130 11/03/2020 2237 Zinc 3.6 100 100 1 101 70-130 11/03/2020 2237 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 136 of 154 ICP-MS Metals - MSD Sample ID: VJ27049-01OMD Matrix: Aqueous Batch: 71917 Prep Method: 3005A Analytical Method: 6020B Prep Date: 11/03/2020 0936 Sample Spike Amount Amount Result % Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Antimony ND 100 100 1 103 2.9 70-130 20 11/03/2020 2244 Arsenic ND 100 100 1 104 1.2 70-130 20 11/03/2020 2244 Barium 120 100 220 1 105 1.3 70-130 20 11/03/2020 2244 Beryllium ND 100 100 1 100 2.3 70-130 20 11/03/2020 2244 Cadmium ND 100 100 1 105 2.9 70-130 20 11/03/2020 2244 Chromium 2.1 100 110 1 105 1.6 70-130 20 11/03/2020 2244 Cobalt ND 100 100 1 103 2.2 70-130 20 11/03/2020 2244 Copper ND 100 110 1 105 1.1 70-130 20 11/03/2020 2244 Lead ND 100 110 1 105 0.12 70-130 20 11/03/2020 2244 Nickel 3.5 100 100 1 101 1.7 70-130 20 11/03/2020 2244 Selenium ND 100 99 1 99 3.0 70-130 20 11/03/2020 2244 Silver ND 100 100 1 103 1.6 70-130 20 11/03/2020 2244 Thallium ND 100 110 1 109 0.26 70-130 20 11/03/2020 2244 Vanadium 2.7 100 110 1 104 0.56 70-130 20 11/03/2020 2244 Zinc 3.6 100 100 1 99 1.7 70-130 20 11/03/2020 2244 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 137 of 154 ICP-MS Metals - MB Sample ID: VQ72039-001 Matrix: Aqueous Batch: 72039 Prep Method: 3005A Analytical Method: 6020B Prep Date: 11/03/2020 0936 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 11/04/2020 0252 Arsenic ND 1 2.0 1.3 ug/L 11/04/2020 0252 Barium ND 1 5.0 1.3 ug/L 11/04/2020 0252 Beryllium ND 1 0.40 0.15 ug/L 11/04/2020 0252 Cadmium ND 1 0.50 0.13 ug/L 11/04/2020 0252 Chromium ND 1 5.0 1.3 ug/L 11/04/2020 0252 Cobalt ND 1 5.0 1.3 ug/L 11/04/2020 0252 Copper ND 1 5.0 1.3 ug/L 11/04/2020 0252 Iron ND 1 50 13 ug/L 11/04/2020 0252 Lead ND 1 1.0 0.25 ug/L 11/04/2020 0252 Manganese ND 1 5.0 1.3 ug/L 11/04/2020 0252 Nickel ND 1 5.0 1.3 ug/L 11/04/2020 0252 Selenium ND 1 5.0 1.3 ug/L 11/04/2020 0252 Silver ND 1 1.0 0.25 ug/L 11/04/2020 0252 Thallium ND 1 0.50 0.15 ug/L 11/04/2020 0252 Vanadium ND 1 5.0 2.5 ug/L 11/04/2020 0252 Zinc ND 1 10 2.5 ug/L 11/04/2020 0252 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 138 of 154 ICP-MS Metals - LCS Sample ID: VQ72039-002 Matrix: Aqueous Batch: 72039 Prep Method: 3005A Analytical Method: 6020B Prep Date: 11/03/2020 0936 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 100 1 103 80-120 11/04/2020 0259 Arsenic 100 110 1 106 80-120 11/04/2020 0259 Barium 100 97 1 97 80-120 11/04/2020 0259 Beryllium 100 100 1 100 80-120 11/04/2020 0259 Cadmium 100 100 1 102 80-120 11/04/2020 0259 Chromium 100 110 1 113 80-120 11/04/2020 0259 Cobalt 100 110 1 113 80-120 11/04/2020 0259 Copper 100 100 1 104 80-120 11/04/2020 0259 Iron 1000 1000 1 101 80-120 11/04/2020 0259 Lead 100 110 1 109 80-120 11/04/2020 0259 Manganese 100 110 1 112 80-120 11/04/2020 0259 Nickel 100 110 1 112 80-120 11/04/2020 0259 Selenium 100 96 1 96 80-120 11/04/2020 0259 Silver 100 110 1 106 80-120 11/04/2020 0259 Thallium 100 110 1 110 80-120 11/04/2020 0259 Vanadium 100 110 1 110 80-120 11/04/2020 0259 Zinc 100 93 1 93 80-120 11/04/2020 0259 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 139 of 154 ICP-MS Metals - MS Sample ID: VJ27049-021 MS Matrix: Aqueous Batch: 72039 Prep Method: 3005A Analytical Method: 6020B Prep Date: 11/03/2020 0936 Sample Spike Amount Amount Result % Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony ND 100 100 1 104 70-130 11/04/2020 0352 Arsenic ND 100 100 1 105 70-130 11/04/2020 0352 Barium 130 100 240 1 108 70-130 11/04/2020 0352 Beryllium ND 100 100 1 100 70-130 11/04/2020 0352 Cadmium ND 100 110 1 106 70-130 11/04/2020 0352 Chromium 2.0 100 110 1 104 70-130 11/04/2020 0352 Cobalt 3.0 100 110 1 103 70-130 11/04/2020 0352 Copper ND 100 100 1 102 70-130 11/04/2020 0352 Lead ND 100 100 1 103 70-130 11/04/2020 0352 Nickel 9.1 100 110 1 100 70-130 11/04/2020 0352 Selenium ND 100 99 1 99 70-130 11/04/2020 0352 Silver ND 100 100 1 103 70-130 11/04/2020 0352 Thallium ND 100 110 1 107 70-130 11/04/2020 0352 Vanadium ND 100 110 1 105 70-130 11/04/2020 0352 Zinc 7.7 100 110 1 98 70-130 11/04/2020 0352 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 140 of 154 ICP-MS Metals - MSD Sample ID: VJ27049-021MD Matrix: Aqueous Batch: 72039 Prep Method: 3005A Analytical Method: 6020B Prep Date: 11/03/2020 0936 Sample Spike Amount Amount Result % Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Antimony ND 100 110 1 106 1.2 70-130 20 11/04/2020 0359 Arsenic ND 100 100 1 104 0.67 70-130 20 11/04/2020 0359 Barium 130 100 230 1 104 2.0 70-130 20 11/04/2020 0359 Beryllium ND 100 99 1 99 0.36 70-130 20 11/04/2020 0359 Cadmium ND 100 100 1 104 2.0 70-130 20 11/04/2020 0359 Chromium 2.0 100 110 1 104 0.0032 70-130 20 11/04/2020 0359 Cobalt 3.0 100 110 1 102 0.93 70-130 20 11/04/2020 0359 Copper ND 100 100 1 101 0.62 70-130 20 11/04/2020 0359 Lead ND 100 100 1 103 0.37 70-130 20 11/04/2020 0359 Nickel 9.1 100 110 1 98 1.6 70-130 20 11/04/2020 0359 Selenium ND 100 99 1 99 0.47 70-130 20 11/04/2020 0359 Silver ND 100 100 1 102 0.96 70-130 20 11/04/2020 0359 Thallium ND 100 110 1 107 0.38 70-130 20 11/04/2020 0359 Vanadium ND 100 100 1 104 0.79 70-130 20 11/04/2020 0359 Zinc 7.7 100 100 1 97 0.30 70-130 20 11/04/2020 0359 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 141 of 154 CVAA -MB Sample ID: VQ72084-001 Matrix: Aqueous Batch: 72084 Prep Method: Analytical Method: 7470A Prep Date: 11/04/2020 0949 Parameter Result Q Dil LOQ DL Units Analysis Date Mercury ND 1 0.00020 0.000091 mg/L 11/04/20201302 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 142 of 154 CVAA - LCS Sample ID: VQ72084-002 Matrix: Aqueous Batch: 72084 Prep Method: Analytical Method: 7470A Prep Date: 11/04/2020 0949 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Mercury 0.0020 0.0020 1 101 80-120 11/04/20201305 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 143 of 154 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 144 of 154 PACE ANALYTICAL SERVICES, LLC � Plr M of CU WE4 1 9 1 r � � w .`� t cc F53 � � d y4' � Ilu i 1= U) R. i I c r ti [V I I i 1.54?Fi I f L_T__. I " ir-1 _ :i 5 j r414 S th 1 I' LLI J r e c 4 i C s� I 'I } aC7 �• q6 5 Li, F i x 5 o � I 5 $ 4a 4 fir` ri jA '3 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 145 of 154 PACE ANALYTICAL SERVICES, LLC Samples Receipt Chenkiist (SRCQT41l1f71}GiBC-15) R,�vised:9/29/2U) lssuillgAirthority'Pace ENy-'NCOL Yag�j I u,'1 L1 a lnple Receipt Cbecklist (SRQ f'licnr BLE t. ein]rT .nxneGted bvldat-., 1 1110%2021) Let }; VJ2,04" sans of receipt: J dace :.C.1ier,t UPS 0 FetLFx Orhefr; Yes s N-o1. Wcre mtody seals prewni on O-E caolcO: El 4'as. LJ Rio R1A 2_ If cumadv seals wero EaTat, we-e tb inner Arai unbrokcn7 pHStrip 1D' zuQx'5 -- Chlmitue Strip 1D, �l`a Tested by: Original. teillPaT tur6 upon rccelpt I Derived (Corrected) torriperat arc: upon receiVt 9d u id &- ap-Gir 1D= NA 3.1 i3_L oc NA r4A aC TEA +NA aC NA jNA aC 1 Me:hnd, �1:]Tamperawm Blank [ uirn4 le_; Bo TR DLui JID: s fit Gun Correction Factor; 0 aC MoLbu: vfr_oOLLIt: 0 %VetIc>o ❑ icePackq ❑ Dry Lce ❑ NQry k Y vs [] lea ONA 3. Tf L&M pert _urn of any cooler cxcoo.ltd (i.s7°C, was Project Manager Nutii.ied? Put was Notified by, p1loiic l cmAil 1 face-tD-face (circle onc), 4. Is tEte comnlerrT�I cnurirr'k pAinkltig slip attached to dtia kwm? 5_ Wets proper czLudy prOaOdureS (r&1 Lip iKhW'LaoaivCd) Wimed? 'e 1No 1 Idrl JI Yes Nc, J Yeti %441. — — 5. Were wnpl : Ms m the COC7 J 'Ycs ❑ to 7 vlcrc sarnpl:: TUi listed nil all sample cont: ners7 S. Was Uolleeuon date & tune listed on the SJU `f V Yrs LjNa. J yus Tofu collecd on date & time lisoad+rn all sum plu wntainti,6? d Yc3 NO — 1L`. Did all =Lgincr label inf01vtation (ILA,datz, time) Mwee with theCsOC� V cw Tito - 11. Wcm tests to be pwFomod fisnad on the WC:? IJ g � 12 _ Did all sALllp€es arnve in Hhe p riy,6r cont'ainam for e9ch test andior in gC{.•�I uurLLlkiou (unbroken, lids on, etc-)? 12. W+a.a adcxLjvc bample volume availab[ - 0 Yesl LJNu Ycs 1Np 14. Were al i wrnpl,_�s received wi€li hi ,£ the holding [irtir, stir 4R h:-jws, WhklleVer conics first: Yes iNa IS_ Were any sarnales containcra rnissingV otr4 6mle ane] sa7u les Not lisfcd on CDC? Lj Yes ❑ ND❑ N 16. For VOA mid KSK-175 samples, ivere b.ubbles prescrt }"p:a ir0" {'.�"ar 61Mn in diaTndesr its tiny oftht VOA vials? Yes LJ ND I INA 17 _ Were all nkOlmeralvn utrient. s:mL lea -eceived at z. pi l Df < 27 Yes No _MN I & Were all cy,uaide samples raeeivtd al, a pH r 12 and sul=Lde samples rcceivt:r7. at a pH > {!'' ❑ Yet ❑ No EZINA re LP. Weal. app tcA c �faJT){Rb'cyanide R io . , 0.5mg1L) samples time of residLral ch:nritle7 I.. h CS ❑ l`{0 �: ]}i WereC lent re•,11wks7ivquoSLs (i.c.:4L14JjW,6llllUtjc;gs, M' WMD designati*ns, etc... ..orrb l}r lrarLccrihed f` m t1w COC into fhe cr�LLzluri stx liw, u r L1 hiS? I El Yrs d Rfn 1. RFas Ent qwtt nun'Der Listed on the coakinzr ]ubc l^ If yvs, Qu0n is Sample Preservation (14i si; be oamplitird fnr any sarnplf (s•)i11cnrucCt1y prosmod or wia) hea&pace-) sampla(E) Y --.were rumivt lncurri-dl poeserved and wero adju4Led accordingly ill sar iple r000lti nC with ' rnL rif`circle one: H29C'l, HNO3, H I., TNaOH using 5R it OA Time of pr-mmNadon NA 1f niore than one prescrtutivo, i.9 ntt[dtld, plrase nota ill the C-OMT31rn1.9'atln v, Samp[erhj NA �Y ware received '.vldl huhhles ;;-6 mm in diameter. rinp€w(s) rdt unsrr; recei vc!d wi-Jt TIC > 0.5 nlglL (If 419 iS rta) and were &sudaccordmgl, y in tarnpleraceiuin; % t1; sadinm diiasuMlie CNA2} ZE);) wilb ShEoly 1D: NA .._._. 5R barcode lalhels applied by, KBS Date. LQ+ 02e C,omnlows: Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 146 of 154 PACE ANALYTICAL SERVICES, LLC SanVles Raraipt Checklist (SRQ (ME6018C-151 Revised;9/29/2020 } trr 4rralyr.'r.>f lss u ii g Autho rlty: Face EMV - VVCOL Pag2 1 or 7 Sample ReceipI C heck] is( ( .RC) Client M, Crwkc-Inspzowdby1datc: AHD f 1012.1 C I_a¢P: VJ27M Means of receipt: f 1'aa� C liert 4 P5 Fa3Ex CAler: --- Yes ,l -No 1. Wwr su8tody s€>'al.k prc.wnt iir. the -Duleo�Ej Yrsl 0 Nol I NA2.Ifcustodusealswere prusect, andUPS)rl€en7 pI-I Strip ID, 21�2295 ChlDrine Strip ID. 2't2232 '1'mtad by: ttina Original temperature upon receipt? deriver} (CL%rrmt5d) temparmure<upon recaip` �,9olid Snap-Cttp ID: VA I i 113 DC NA 1NA T MA iNA o NA ;NA zC Method [?Tfeniperatw-e Hunk i,7 &3'alps lit Ciull ID: w IR Oun Crprrml.inn Fad 31rx: cc lulettiod of coolant; -wet Ice Joe Packs El Dry Ice ElNorie — - Yes ° © NA 3- If temperature ofaTky cooler excaerled6.(rC., was I'rar)ett Maria rNolifi("d'7 PM wzs Notil=l,d by, phone r elnxiI ? taus -in -face (vie 0t! (ine)- Yes LJNo U ;~lA d_ Is ti,e oalnmemial courie~'s harking slip atmch-.d to this fur.? J Yes No 5, Wom proper custody procedures (relInquWiedlreceived) follokt-ed? Yes N 6. WOO wnlpft,Ds I steel an tli,3 DOC? EYes ONo 17, Wtwc simple lD: I=stcd on al' sample con tainers% Yes LJ No 8_ Was oaliection dace & :ur.e listed on iae COM V-, N, 9- Wi& upllection dAw. r�ri. tirre Iis#pd on all sample coaitainea:s? # Ycs ❑floe 10- Dig all utmilainor label inforrttstion (11), date, time) agree Mth the COC? Ycs 17FNo 11. *&W tests to be performed listed bl1 the COC,' Q Y-s /❑;r'cs I --I No No l- . Dir: all 3w r:plcs : i x in t3K: fire uorrltti n €ry for each test arid.'or in good condition (unhrnkun, IU9 (m, fir,)? 13- Was ulcqu-MO sample rafurrc almilublk? Ld Yee I LJNo 14. Weft al] hamples rnntaived within Jte IiDidin-� time ur 49 Ilraurs, WhiOMW T wrnes First? Yes v'No ] 5- Weir, aay 5wrip1m uonluinum toissirduxcess (circle enar) simples Not i Fted or COC? ❑Yes pNn L]NA 16 Yor VOA and RSK-175 sanrple5, were bubblCi proont>"pea-size"('ra'tlr6muti M diynieter) in any oftho VOA vials2 Yes Ll Nu LJMA 17. Worn a! 1 D>l UMQn sd.-/nn tricot Samples received at 2- p_Fl of <' 2? -- — j ❑ Yc N o J hc�l 1 S. Wert all cyanide sr,mples m--Ei ved at a -A-1 _y l2 and 5-elf& tamplos received of a pM > 91 �❑ Yes ❑1tio ©NA ere all applicably N af. I l�Gevtult p .a�a f S.IJG08,3 LI.9tnglLJ samples free of ' residual chlorine? ❑ Y°s C N` ❑J NA Were dknt rC mukS�rrcqumt3 (i.e. regDested dllutinux, MSi'wq } dEn6LT I errs, etc ---1 - currrrlly lruaastribcJ Crum lhs COC inw the zomment section in LIMS? y"A 12I. WaSJJw quotonumberll=da:rthe Cnntainerlabel? 1CNM-,Quote-A Sample Pmeivatimi i Must be cria.1iletct] Cur tan} aartplc(s) incorrectly preserved or wil:t 7kimi ypxcr) SaM131U(S) N^ were received iriccwm tly pTmuved and ivere aclj usted ku:umi i;:gly a7 sample FEEL Vi148 witlr VA mi., of virclo ogre; N2SO4, Hi' M, FC1, N- AOH LISIng Sl2 tf NA Ti me or pmwrmt:an NA If mom Char- one preservative Is needed, pl"sc noto in dhe comments below- 6amp]e(s) NA wore received%vidi Iubbk;. -6 mm in diarctcr. Sa MpJcs(s).W, were itmi,red wifli �itC fF.S mgfl.. (�f 19 is vo) and were adjusmd accordingly er sample iweiving with sodiurn tfioarrlCuLt (Na�;�Q�) witjl Shealy 1I}- 14-1 SP bmcode Jabels applied -:3y: KDS Wre. 1 '?jZ021 — ColnlnelIM! Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 147 of 154 �0 <CD m D m v CD C 0 �CD o m N � r r N 0 o O � C Q m y 1 3 n N V C N 0 O CD CD o� V � �y m -4� V 0 oCD .d oy oo CO O O V to O 0 E3 v SHEALY ENVIRONMENTAL E" E; , INC. S Y Chain of Custody Record III Ile Pain: -79 i . - "loDO Fax No-b�, M -91?ry 1 T�Iraphc�,e Nu. 8o3.79i�7�� Fax '4a_Ai1.9•T91�Aiii AAwd shealylab_c rn 3knr ifwwt3t•ome& --- r�Aq�JOVIPPi0.lt-rmar! .ay FifidNtY hl3nln .13F*c`-fir, E] $ ti ro �O i'e' R Y 431, A `f ."al NO. Rd. Na Ab � Ccrrhd mr: dsarnx �Y .9 caatusie Pyp e fLbcraA— Cream MMO Ow" CATMW"4M Wr fi%w-9.D JN\ %W - % D3.w jynu 1 � I - Df27 a W -17 .0 5 �� PIUMber 106166 A".So {A NLM nF r=deO I wJ I C1 arw�e "_ #� I I�Il�lll� I�I u1�1� J27049 k.In I TTT- rurrrArouridThnaRegu4edjFilcrh�gopFaau�lle�sbsc'larer 'lisaa�f +,ve134now A="&+akazaryfdem'.%wor CRfq.NUUM.-sjNMTJO�'M tm Sderd Qgaup+(SA�Glf G:IGf1?4vCc" GCdWOWdyLN 7hw-ftard ;!Rumhle IlSkinitelan{ QPUI9an GElrl3n— +, F c�ftuba.+rid by bra T,vaa 7_ py r 2 i3cjn*�fi + +•f)3fs n RF,r. R. e,x",eJby Darr �xr !` f I riWMWdshedby J'a Erna S. R"'0V. Dj DR.% 77A-! 4-'-WN]gwme'd by 1�-qfq I . , ., — n J. 4. LAW. -A ty Tin Naire: A8 sanWfes are retaineff to., four yaks 6urn recta. MTM9UTAW 4YF1?7 A YE+LCorf f3efwrr ro kfMr;rxry w7n SNTOPWSX PffiK,FakM.wrf copy - - 101NI_ OrtiQY } orrrcef[S�c;4a},� Nu krFkr�c ��c�t9§m�n_�7 J 'C Da;vrrreft f,�,rlt,er: T,A�i� C�1bCf�ix ��ra; Gt:�Or�u �4 D 0 m z r1 n D r m 0 m Cn r 0 PACE ANALYTICAL SERVICES, LLC Samples Receipt Checklist {SRC} (fu1E001AG15) Revised:9}29170P0 �ceAnaj}lof,a1' lissu;ngAuthority, Pa-:* ENV -WOOL Page l of i Sample Receipt Checklist(SRC) _) {-Tilt: �JN CLUhN 111S eeft ` Idate: , 1 6 I 1h lArr y t W of receipt, Race heat UPS FedEx Yes No t , WOM CHSl{1c1 Filti 3M4tAA u1t ll:e oa0lel? Yes i"N6 NA 2. IfCUSR] seals v.�ies]Iresert; vre the iniaciaud uoluukerl li 4rrip il?: CIAGrillt: SLrip ID. Tested t}y: ri;ival temperatureupon receipt �17}F.}r-ived (Co:rcc:txil Lr�luptrdLJ3e LL[MI receipt %Solid 5raR-Cup Tl3_ hlcthod; ©T LlperuLurr BL#u]lc AtnSt 44t les Ilt: GUn IL1- _ .-...-. 112 Gun CorrcUi00 FPacor- 0 "C Method of I:ODIar,+: Wei Tre l— l Ice Ract€ ❑ Dry Ice ❑ Nonc Yes 1:1FM ❑T4lts t ]d3, iftem i'aE'tit+eofary cooler exceedrd6,0'C:,wlrsProject MaitagerNorified? m m Notified Ly: phones email ! faca4o, a (circl a nrlo}. Yes Ll No -NA 4- Is diecommemial poln-ier'F, packingsl'p attached lu his ftmm`s No 15, Wum prroper uuquidy procedure& (relinquished0rece:-ved) followed? TYes Y ; I —I My 16. Wert samp'c IDs listed on the COC? ED Yes I El No ?- WPM SHn111_4 IDS kitaxl tut all Sauyple oontalners? e'er No I.E. Was calicotim date & times llswdon m,coc? Y(5 Nu No 9, Was collection data & tune lisredtm all sample containers? Yes 10. Did all catriuiarr label iufUnUEL6U01 (ID, Fate, lima) agree witLi the COC7 1.. Were tests to bo ptrfbrmod Listed on the 00H-7 - Ycs ONO X Y N° 12. D1 JJ al sauuules arrive in the proper cawaiue~s for each ti sn ar*0- .4eti in d co"rditinn (unbroken, lies lie>, eta)? Yes N o 13. Was adoqualc sumpla volumt< available" Yc-y ig11 14. Wero all samples=wcivcdwittin'Athe t6oldit1gti�e or48 hpLrs,wbiehever comic-r, firstl Yes N 5. t'f'd Rny ,mrnplus ciml.alrltzs Irdisirq� =L:c-s2 (Cij a Oile) S$L1t:Sles Not 'Isted on C04 •�' 16, For VGA and RS4-175 5ample*, were bubbles pr sent r}` x 3ae" ('A"or 6mm in d izMcLer) in any of the VOA via_s^ i ❑ �� �. t1 �T2A 'e¢ No NA ] 7_ V4'crc ail DRC'mcrlx+ rutricrt sLl�iplcsi rcc4ivc41 al. p H of k 2? Ye: PJu NA l8- Y4'ete 011 cl hide sam Les mceived at 9 H _- 12 arLd sulftict Namplr.4 rucpivcr ut a pH �- W ONo ' NA 19- Weis app kabl e 3 k c,,an1 z plenoli25.1i6oB.3 (--Mnl,g!L) saTtples free of residual ch3c)ritte? ❑Yes NA 20, Wel+e client retnarksh+eyrtests (Le, requested dilutions, NISS SD doeignatiotts, etc. , ,) coileedv tra,lsujwd from the COC Imo die cornmcnt,�oction in LMIS? I V esl LjNi)l 12 f - Vi Em the gLow dumber l igtcd on the coil a ner label? 1f yes, Quote iY Sample Preservation (MUSL be wnpli is for any sampl;.(s) iticQuedy rewlvad or wit:1 se c p�ce,j SaLnp1 (s) WCre received iricoucrdy 7-�5CT ar.4. tare adjastat[ acccmd!11Biy in setnpie ± ceiviu0 with inL cfaircle ane=HSC14, E1 JCi, MCI, Na OH iising SR 4 ; Tirlte of preservad on . �yt[ .. _._. If nne than one preservative is needed, ple--.-,e note in Jie comments below. Sarltple(s}-.-___—.- vvcm rcccivcd with bubbles >6 mm in diameter. garnplwart, Lt all Ld widl TRC { 0.5 m@VL (If-919 is na) and wc:c adj1lsted acxordingly in Sampl�rpceivingwiIh WdflLrr Ih675111faw(Na q,0,)wkb Shealy 1D- SR barcode labels gV1:edby: ~ _S l_ Date: Comments; Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 149 of 154 LChain of Costoily Record 0 CU-" SHEALY ENVIRONMENTAL SERVICES, INC. I W Vartzge Poiryt Orve, VVM Columba. SC 29172 Tc4c-phone No. 803-7:91.9700 Fax Mo- 803-791-41161 P,rw to Iarlea T9. E;A40ry rk,. / GlamT Number 106167 saffbuer-e 2*0rissure ArmfJOL (AlWiP ffsf M Mme 5paLL- i3 P=MS Vr _J Q L F VJ27049 Fbo- W Llr,ui�dmra LJE: -- A317" 0 1 EX-,;C rQ�f-Oft n&L- TMT1 ;E ,A 1, kr=O $ZIP MT 1* GV&W Q" CM dW,' iD/?s/2ro Iq jo T L Rw A myd r.-Mv Requvd jP19rM dpMbW rRljFrj!O Ift' dVEMUF WE) -';S.TPfe MSPOL)ff Pmi-�m HakArd lCr-Ab*ak%'r cj siwwm 11 umm (Spttffy� M Pefurm jo Mur F- DLv3sd by L66 CNOAI�.afd unvnrpswgiWiitwra Mohan []Lhba'm 1700 7. Ramqaiaud by P. ko� yl D91a M W.We ',700 Y. I& fVi (t MU -V�� t ftml%wLfw by I JAII� (2 . w r Dd&t T" 7 rA CE i by Gwq? Troe a.4eM-9a Ddr6 7kps Caro Tlmv 1 41 la".GLV mftv !Jy NotwAri sarros--am f0tv Algok6 ftomrecafpt vp ipff (y fw =PXt Re Imp. LofAsss c4hff afmngeffre-nM ei aiada- fiWa"a on (0-'1r) mj�-f jDIMMJ.ffM-- n"TE & YELLM-Herurn k* ra-Lcr5r yy kLAYM S&TaWsk FV,%;K F-%Uwjj&lf C6pj' COCLYnefdft"V.F-A0-lM 0 m z 0 m 0 m 0 �0 <CD m D ;v v CD C v nn m v� o m N � r r N 0 o o c Q� m y 1 3 0 N •C (NO � V C N 0 W CD O � V � O y CD V 0 O CD O y b W C X .0 w (D w O E3 PACE ANALYTICAL. SERVICES, LLC CMMWical i06 1f3nh„ga Pair+! a - West Columbia, SC 29172 TelaDh0ne N0. PC3-7U1.9-00 Fax No. KM-7914111 www.pacm ice. CS.0 ckw — ,a [t�Cauacr B L _ /j[iii�'E'fS ,�TiffR'a� 5.r�ffc f4�Yy4 f � 81}1P�9 fDl Ueecmrraq MlW.Uco umk. G*To'S�� G p x ' b'w.M N-- ki ndr mff4.6 NWG90MONid M 2-It 1y'd d4fafd i4i5Yr/!4 i N1 w #I 1 ml U -.o ri !' ' IN I ... AW - I llA 1 D L 1 D 1 7um *cwra7 -rrme Ltd jl5iorlsba,� rua. la;�rdrJ?d,LYerlrPdr�ad am7dard i I fiw.S f4'wwsrwdbj d ,4rlfin�J.'�ShSdJ]y i SdfJl�r9 DJJ5fn7b3� Alfa ❑m'a Mnp [eta rrr,•: Audi_ ,dq sa Woes are ratai -r for k Y 11&5ks koirn re re;pt unto" sm- Mar-l6. ONTROOTM.m'frri±&YELLOW-F. f.9 go AbOyankaywrvr ar1"�C1PL^NGFrf�C'k��+ropy JJy eJr.Mhy"m hy."a ImgmOm AT& Number 1 . 9° E5 TesGf fLV No. I E,'rad , DEOL. Ard:'- l.rs¢o,1s 1tEschIVdmarepasaisnd6W VJ27049 LJO JiO�fl]f RQaFL4LM1I i f}. f 4yy_ f X pm,c! * haled Ada *ff?rA lao n Nw m mid I herr=ie 7 Skin IrMrh E. f 1w-1 r' bin —A 2. �.en4f�bd by 'r �G' AJMq�Ve�r�nfa (Sye�NJ OOEe ]Yr!S Tyr* J3w& r, r u N 5 Y [W.L'E.-tarM MATXWr. , SY='01 D m D D n r V/ 0 m cn r r 0 PACE ANALYTICAL SERVICES, LLC Samp1 r ticecipt Crrecldist (SRq {na000> SC-15) Revised-9J19/2020 �eaArra trc-rJ IssuingArrthorit�; Face ENV-l"VCDL Page Iof 1 Sample Receipt Checklist (SRC} Client' BIT, CoDlar l;nhpvctLW lsyldate: KB9 �, ii11 W,120 Lot 9: eaRS 4'(LCC i[T Lj Pace {:Ilcnt Jj UK I JlFadft {Jth,7: s:s No custcwla Sear pTMnt ❑n Lim cooler;" YeR No A ). If C-11 d ' seals 1vor-V pre;SenE, ws3re they inius l alyd unbroken? _ CuPI SC�ip ID,. ' — Chlorine Strip ID: w — I s is L}., K69 DrLgLnal tempt-raturc upo vn 4^ receipt ;DDiv;ed5 r (Cwvcicrr) bn -peraturc stpan rrcelpt %Solid Snap -Cup ID; or mi:Lflad: E]j'en1PcMt11rr nlank L3kgainsi, Bottles IR Gjn 11); _ IR Gun Curwtion Partor; 0 �C Method ix, cookm1- 0 Wet Ica ❑ Ice Packs 17- i)ry loo ❑ Nona _ 3. if ty mer p twe of any oler exceeded 6.0°C, wws Project Mana2etNortlied7 Yes ❑ l v ❑ ]A pM wEs N ti[ted by. phone r emai: 1 facL to-Cw r (circle° one)_ TT yes1sr LytJNA4. is tl re cutruiiers iat cnl ncr's parking slip AttAChrtd m th is i b n? — F7-1 Vey Ll Nu 5. 1k+empropcTcuslutiypracedures(relinnuiShffVrccciuud)followod? d Yea Np 6. Wm �amp;e ID!; listed (m the COO) — V Yet © No 7_ em sample 111; Ii'doz ilui a'I sample mamkWS? yes Na t1, ',Vas collection date &limy listed on The COC? Y-es N 9, Was collegian dote & dmvre listed on s.1 sammplc mntainers? — 771 Sees I F-1m No 10, Did all container lwticl lolbmniatiem (ID: Ewe, time) agree with the COC? v h!o ] 1. 1�,"cre tests to be acrfNrm ed 1 ismed Dn the COC? ❑ Y ❑ tln 12_ Did all samp]cx taxi: i,r the pl:q)v co-trainem for each tact and?or in good condition (sr1hre1kLn1, lids uu, eta]':' d YesLl No 13-'Nos adequate sampic wolu;rle available" — — Yes ,r+ N0 14. %V--rn all samples mcah-ed %W lth=n V- thti holdi,-q time or 48 hal:rs, %vhichevv -comes firs'7 ye4 Na' 15. Were, any sxmpirs curlLaiaer€ missing+txcess (circle onc) gambles Not listed aui COC? Yes ❑No ❑, NA 16. FarV0A trod RSK =75 samplax were bulubles prescrtt pea size"('I+"or Gmm in Ilinrrseter) in nay t+Cihe VQA viaJ:? Ee:i No NA 17_ Were all DRCilmctalsfrluLneot samples mwivnd a* a I -I af< 27 [tin NA 18. Were all cyanide samples rrc-crived at a 31i � 12 XW s' MI& samples rcccivs6 at a pH > 9'� NA I�]_ Worm allapp Ica a Nk{ L }!'e; snide pfrcrrolJ 1 5.11C,OS? 7 0_srrg samples tree of Yes ❑1`Nt} ❑ __ ,.L...I wk lnr.., an ❑ Yes ❑ Nn MNA 20. lVt! . oflent remarkshcgtlests (j,& req leswii diludom, MSS' SD designa-ions, ctc_..j -currucily Lnkmeribed from eK CDC into the commcnt seddw1 Ltl LIMS? Y Vj No 21_ Was tho qtwtarr-urkber listed on :he ootrcaitler IabeP? IfJ"4. QuuLc4 Sample Prewryntkm (Mast be compl;�l4d Cm any sample(s) ini;O=Ay preserved or with haadxpmo. ) tiample�R) 14.E were:receivad inconcatly presc Cd and Were adjiistcd nrcuTdiftVly i� sample receiving with ''IA _IrrL of circle cme: H7304, ] rN01, I CL 14aOH using SR i A TALC Ofrresenation MA lrmore then on-. pre "rvsr.ivt ik needed, plaaw nnic in ths, {, rikineals lldJOW. ale(xl NA w:.7;; r eiVe�a With ktbbleg ») rr: M in diaWVfft0'_ ;s �.o r— were mrei red w ith 7'Rt,_: = 025 m�{L (I t 1k ] 9 is no } and we re accardingly in sfimpie receiving with sodium t}riosulfiAt (Nati53w with Shealy ID: I" barcodu l:beJq tlppliW by' K Date:..' ornman tc Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 152 of 154 �0 <CD �> vv CD vv °' rn �CD v� <0 CD CD � r r N 0 o o c Q� m co 1 3 n m V C N 0 W CD � V � O y -4� CD -40 oy b >v CD CD X E3 PACE ANALYTICAL SERVICES, LLC J08 Vaillage Po I]t r-hiv6L - West C;r)lurnhia: SC; 29172 Tialeahane No. 803-791-7700 Fax No. 803-791-0111 ', vkv.pllrupa4sxo'n BU 4'fdrers � Slimpla'k '�ratau� CiFI vN 'ihdta 1qp C Y—�&& ky-& ji-Lt:f.rJuvar _ � . L-a=A t±.v l._ Van i3yq" € Q Nu � a rm�rr I 89.TAW3 0 ! a4 qr-*0 n j=UWT .b' 11h:1}'in'+nmv'vQl 4rIF 431C,% m `_ p 5 - - - {`4A!`ELtlr vnS'rcS+cfl 7N'� U � � � IWFFJ�?1 3! + ti Dl ?O12 fl it?; 'Jv-3-n 1330 1 N1ylr - t NWB7hi%vhao lAkAf [ 1 'LO 1035 Ir 1 ] i- -2 M IRA! M k h IDA)14 _ 7 1'h�rr•-� � -.. - -- -- '� ��� � l � � it ruya.4 odnd ramp frpquWd jRiorkDaApv"rodol►eMOregm" Alr.) sar;a'e oaaar r SEt"rd ! Rd" !09 ri PrffNo!u CJAP.1 :' bLi nn M� i, 14aMQLV&Ua by J�a Rn kne 4 rjLR UOiej fey Nat" samples ara iTtaxwd yr four ekc "M ramox ofh,;3s Wher mrrrr.^_yelrwmir ?"eMdO. 0lSTAfM7 01W. WHgH & YHLLQV,=PJ Lvn fc fsLcrarwy wkr Same E(6j.- CO,} 7��a AW J£-MV Number 112969 Ar.%*Wa M rrecb Igr If rmarp wme Is nss bt, >L #. �V`Facxuaruar�a 4• �' ! 3 � _ + i ti N y [r T k' I x XIX Q4 JJII ILYI�I r If VJ 2 7049 LIG n4fI1Rn3 � �a'OQ.LIf f. Q. ><-Ix ."OMjb.%5 raa7a0 WnLS;MpMR 110ll rirbrverlrs 66" !ad 9 I rkr•Haxard .i inmahle u OW. rlftl80t J Pm4lan - Unl.. r. gW-;L%W4 61. 8 R�ce.R�dBy 4. LswulorlI" Oy r LAS USE Dlv+ y ReceWd an fae :YcAFJ + M3 PM RNA Fh cL� T,%nip PAR Tkne Dam f r e J3{f7+C� Tiry� { Taw . . f ! n T.P metes `:.: Y ❑ N C4..VIAI Unlw7lber,iffrC0AW60r m D D r n r m 0 cn r rl PACE ANALYTICAL SERVICES, LLC Sorn pies RL wipt ChecJkltst t511C] (MEO0I$C�15) arty 4rkrP,1;. ! I ssuing Author]ty: Pace ENV - WCOL Sample Receipt Checklist (SRC) Clem, 3LJ Cooler ilia ected lr idate; KSC I LUMAM Lot P., V134047 page 2 of i ams of rcoci = J Pam Client Lj UPS Lj €txK=71 Clt[ten - Yes ,f No I]. Wefe custody sr a pmtea,t un thD cool o:'? Yes No I EINA 12. If curtadv teals wore pE435ant, were tliev irw and unboku? -ip ID, -, 1'csted bv: ��s - pH St-ip ID- ' > ;dos Chlorine Sz � Original tempernturp upo-i rm. aip=f Der!ved (CoiTe--Led)tcmpuFuL rrc ,pon mccipt 'Y.Sclid Strap -Cup ID: NP. 4A r.4.8 oc 14A r NA oC NA +e14A �C NA eNA ot- kffethod:©Tcmpr—a-wr.Blank L3lGainst73nrtlrs 'R01r11JD: f IRGuiiCunrutiunFtu:lw:0 ')c Method ofcxrlar.1, P]Wet Ice Ice Pnok> © l)ry luc ❑ done — I ❑Yeao]NA 3, Jf to nFature o= any cnelcr cxc�cdat[ 6.0°C, was Project hie iacr, N��=ifr? PM wm Nei fled by' phone 1 trnai I !cne)- 4. ;� m],c rommucia[ courier's packing slip a l.pi&ed to this fonya? S. Were proper custody proceduies {I e:i:iq�iyhedfrxDivadl &Aawa& -J yes UNko. ,JNA No py - 6. Wcru sir le ills lismd on the C DC'? 7- Were wimple IDs lisped on Al sample eont9:nGrs'.' 8- W2-� tol,CCtion data & time listed oil the COC? 9- Wan WEtAun date & time fisted n-m all sarnril�. conrainers? 10. Did all cantdner label hifarmatian (TU, datr, timD) ag= with the CDC? ❑J Yes Nra No ❑J YesLl Tyra ❑ No J y'-A ,77 11m Nk, 1 I. 1k'Drc tr ots to be performed listed on t.io COC" - 12. Did all s mp'rs arrive in the pfoper earrtain e's for each test u&or to goon conditior {unbroken, lids on, et X _ —sample © Yes ❑ No Yes N* 13, Was acuq.tate vo[Lum avLa[liabjr? Yes LeJN,, id. Wum afl cam lea rviceiwe�d "Il ' ' t ing rime or 48 he--im, %vhiuht!vpr comes first? — ' }Fete �!?' 90rnplr5 containersiss" xa c circle 4s )samples I Tot €fisted on CQC [� k'cs d No UN.A 16. For VOA and RSK- f 7S satnple1, ware bub'Dks preset �`pG¢ sip" (%4 UT 6RlAl in di am, kr) mn any of the VOA via:s' 17- Were al€ DRO/mmttrtjjt-�ient santip-es recei4_•ed at a pH of<27 18- WM alt Cyanide samples received at a phi > I'd and suttide- earn Ies received W a pH > 9? ✓ Yes U No ETA YcsE Lj No O NA �[�� es ❑ No E]NA 1 - Wear a]L Wnp]it;ah'Ic :UN NHS l'cyLmkie.+phenol� 3(� 4.5rnp.fQ samples free u= �Siclgftl C:mltrrin�7 ❑ Yes ❑ No O A 20' m:ra client rcn1arl;slregm_e.;k (i.r„ rer.mrested dilutio_is, MVMSD � Oignatione, cic... eorrccely tMEISO'ihed fmm the C' C tuna fie camnment seclion in I-JM9? VC No 21. Was the q unto rrtirbcr [_stcd on dir. curta;iLVF lal-ml? if s vote � Sample Prx�erYa&A (Must be cn iplated For any wmplo5 s) in,correc_ly pretervcml or with heaclspace.) S2rrple(s) M* ._._. Wen recaivac inrarnaotly preserved: maJ were udjustca accordingly in sa7rrplr rec .ivirmg with NA TtiL gFeircle one: MSC4, J4NC13, HC[, NaOH using SR fi Tirne nrpTmervatian NA if mom tfian ons pftwrvadya, is noeded, plsasa note In tile:.ommonis b�loaw. Surttple{s) NA were reCP,ivrd with bubble5>6nnn in diamrl.vr, 5amrmp]es(s} "A %veje mk7vived with TkC -a 0.3 mg+i, ([f 419 is rm) and were adjus(Waccundingly in rampie rcceivingwitli sodium 1[uosulftate (Na,.;,O-] u�tr SPme l}' ID; NA ;SR balvcZc labcl9 Hpplied by Kild _ [)ate' 11WO24 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 154 of 154 0 aceAnalytical Report of Analysis Bunnell-Lammons Engineering, Inc. 6004 Ponders Court Greenville, SC 29615 Attention: Andy Alexander Project Name: Active Buncombe County Landfill Surface Water Project Number: J20-9378-22 Lot Number:VJ29001 Date Completed:11/09/2020 11 /12/2020 3:02 PM Approved and released by: Project Manager II: Lucas Odom PCCRF� 24rA lkiA / ANSI National Accreditation Board A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 58 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Bunnell-Lammons Engineering, Inc. Lot Number: VJ29001 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. 1,4-Dioxane Internal standard response for the following sample exceeded the lower control limit: VJ29001-007. The sample was re -analyzed with concurring results. As such, the sample results may be biased high. The original set of data has been reported. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 2 of 58 PACE ANALYTICAL SERVICES, LLC Sample Summary Bunnell-Lammons Engineering, Inc. Lot Number: VJ29001 Sample Number Sample ID Matrix Date Sampled Date Received 001 SW-1 Aqueous 10/27/20201115 10/29/2020 002 SW-2 Aqueous 10/27/20201145 10/29/2020 003 SW-3 Aqueous 10/27/20201330 10/29/2020 004 SW-4 Aqueous 10/27/20201520 10/29/2020 005 SW-5 Aqueous 10/27/20201415 10/29/2020 006 SW-6 Aqueous 10/27/20201435 10/29/2020 007 SW-7 Aqueous 10/27/20201307 10/29/2020 008 SW-8 Aqueous 10/27/20201215 10/29/2020 (8 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 58 PACE ANALYTICAL SERVICES, LLC Detection Summary Bunnell-Lammons Engineering, Inc. Lot Number: VJ29001 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 SW-1 Aqueous Barium 6020B 100 ug/L 7 001 SW-1 Aqueous Cobalt 6020B 3.7 J ug/L 7 001 SW-1 Aqueous Lead 6020B 0.34 J ug/L 8 001 SW-1 Aqueous Zinc 6020B 2.5 J ug/L 8 002 SW-2 Aqueous Antimony 6020B 0.62 J ug/L 10 002 SW-2 Aqueous Barium 6020B 58 ug/L 10 002 SW-2 Aqueous Nickel 6020B 1.4 J ug/L 11 003 SW-3 Aqueous 1,4-Dioxane 8260D (SIM) 5.7 ug/L 12 003 SW-3 Aqueous Barium 6020B 150 ug/L 13 003 SW-3 Aqueous Cobalt 6020B 41 ug/L 13 003 SW-3 Aqueous Nickel 6020B 13 ug/L 14 003 SW-3 Aqueous Zinc 6020B 5.6 J ug/L 14 004 SW-4 Aqueous Antimony 6020B 1.2 J ug/L 16 004 SW-4 Aqueous Barium 6020B 120 ug/L 16 004 SW-4 Aqueous Chromium 6020B 4.3 J ug/L 16 004 SW-4 Aqueous Cobalt 6020B 1.8 J ug/L 16 004 SW-4 Aqueous Copper 6020B 3.9 J ug/L 16 004 SW-4 Aqueous Lead 6020B 0.86 J ug/L 17 004 SW-4 Aqueous Nickel 6020B 5.0 ug/L 17 004 SW-4 Aqueous Vanadium 6020B 5.8 ug/L 17 004 SW-4 Aqueous Zinc 6020B 9.1 J ug/L 17 005 SW-5 Aqueous 1,4-Dioxane 8260D (SIM) 7.1 ug/L 18 005 SW-5 Aqueous Tetrahydrofuran 8260D 1.3 J ug/L 19 005 SW-5 Aqueous Barium 6020B 83 ug/L 19 005 SW-5 Aqueous Chromium 6020B 5.1 ug/L 19 005 SW-5 Aqueous Cobalt 6020B 3.1 J ug/L 19 005 SW-5 Aqueous Nickel 6020B 9.2 ug/L 20 005 SW-5 Aqueous Selenium 6020B 1.4 J ug/L 20 006 SW-6 Aqueous 1,4-Dioxane 8260D (SIM) 8.7 ug/L 21 006 SW-6 Aqueous Barium 6020B 97 ug/L 22 006 SW-6 Aqueous Chromium 6020B 2.1 J ug/L 22 006 SW-6 Aqueous Copper 6020B 1.5 J ug/L 23 006 SW-6 Aqueous Lead 6020B 0.33 J ug/L 23 006 SW-6 Aqueous Nickel 6020B 3.4 J ug/L 23 006 SW-6 Aqueous Vanadium 6020B 3.3 J ug/L 23 006 SW-6 Aqueous Zinc 6020B 3.5 J ug/L 23 007 SW-7 Aqueous 1,4-Dioxane 8260D (SIM) 12 ug/L 24 007 SW-7 Aqueous Acetone 8260D 39 ug/L 24 007 SW-7 Aqueous Chloromethane (Methyl 8260D 0.75 J ug/L 24 007 SW-7 Aqueous Antimony 6020B 3.1 ug/L 25 007 SW-7 Aqueous Arsenic 6020B 17 ug/L 25 007 SW-7 Aqueous Barium 6020B 320 ug/L 25 007 SW-7 Aqueous Beryllium 6020B 0.84 ug/L 25 007 SW-7 Aqueous Cadmium 6020B 0.24 J ug/L 25 007 SW-7 Aqueous Chromium 6020B 96 ug/L 25 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 58 Detection Summary (Continued) Lot Number: VJ29001 Sample Sample ID Matrix Parameter Method Result Q Units Page 007 SW-7 Aqueous Cobalt 6020B 61 ug/L 25 007 SW-7 Aqueous Copper 6020B 35 ug/L 26 007 SW-7 Aqueous Lead 6020B 5.1 ug/L 26 007 SW-7 Aqueous Nickel 6020B 94 ug/L 26 007 SW-7 Aqueous Selenium 6020B 4.7 J ug/L 26 007 SW-7 Aqueous Vanadium 6020B 48 ug/L 26 007 SW-7 Aqueous Zinc 6020B 150 ug/L 26 008 SW-8 Aqueous 1,4-Dioxane 8260D (SIM) 1.4 J ug/L 27 008 SW-8 Aqueous Arsenic 6020B 2.0 ug/L 28 008 SW-8 Aqueous Barium 6020B 120 ug/L 28 008 SW-8 Aqueous Chromium 6020B 6.6 ug/L 28 008 SW-8 Aqueous Cobalt 6020B 2.6 J ug/L 28 008 SW-8 Aqueous Copper 6020B 4.2 J ug/L 29 008 SW-8 Aqueous Lead 6020B 0.76 J ug/L 29 008 SW-8 Aqueous Nickel 6020B 6.3 ug/L 29 008 SW-8 Aqueous Vanadium 6020B 8.9 ug/L 29 008 SW-8 Aqueous Zinc 6020B 8.7 J ug/L 29 (62 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 58 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: VJ 29001 -001 Description: SW-1 Matrix: Aqueous Date Sampled:10/27/2020 1115 Date Received:10/29/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 11/04/2020 1154 BWS 72222 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 97 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/05/2020 2201 DJG 72473 2 5030B 8260D 1 11/06/2020 2233 DJG 72627 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 58 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: VJ 29001 -001 Description: SW-1 Matrix: Aqueous Date Sampled:10/27/2020 1115 Date Received:10/29/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/05/2020 2201 DJG 72473 2 5030B 8260D 1 11/06/2020 2233 DJG 72627 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 2 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Run 2 Acceptance Surrogate Q % Recovery Limits Q % Recovery Limits Bromofluorobenzene 94 70-130 99 70-130 1,2-Dichloroethane-d4 94 70-130 94 70-130 Toluene-d8 101 70-130 99 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/04/2020 2254 BPK 11/04/2020 1121 71608 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 100 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 3.7 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 58 Client: Bun nell-Lammons Engineering, Inc. Laboratory ID: VJ29001-001 Description: SW-1 Matrix: Aqueous Date Sampled:10/27/2020 1115 Date Received:10/29/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/04/2020 2254 BPK 11/04/2020 1121 71608 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Lead 7439-92-1 6020B 0.34 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 2.5 J 10 2.5 ug/L 1 LOCI = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 58 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29001-002 Description: SW-2 Matrix: Aqueous Date Sampled:10/27/2020 1145 Date Received:10/29/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 11/04/2020 1219 BWS 72222 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 98 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/05/2020 2224 DJG 72473 2 5030B 8260D 1 11/06/2020 2255 DJG 72627 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 58 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29001-002 Description: SW-2 Matrix: Aqueous Date Sampled:10/27/2020 1145 Date Received:10/29/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/05/2020 2224 DJG 72473 2 5030B 8260D 1 11/06/2020 2255 DJG 72627 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 2 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Run 2 Acceptance Surrogate Q % Recovery Limits Q % Recovery Limits Bromofluorobenzene 92 70-130 103 70-130 1,2-Dichloroethane-d4 93 70-130 94 70-130 Toluene-d8 100 70-130 94 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/04/2020 2332 BPK 11/04/2020 1121 71608 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 0.62 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 58 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 58 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29001-002 Description: SW-2 Matrix: Aqueous Date Sampled:10/27/2020 1145 Date Received:10/29/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/04/2020 2332 BPK 11/04/2020 1121 71608 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 1.4 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 58 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29001-003 Description: SW-3 Matrix: Aqueous Date Sampled:10/27/2020 1330 Date Received:10/29/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 11/04/2020 1243 BWS 72222 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 5.7 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 97 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/05/2020 2247 DJG 72473 2 5030B 8260D 1 11/06/2020 2318 DJG 72627 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 58 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29001-003 Description: SW-3 Matrix: Aqueous Date Sampled:10/27/2020 1330 Date Received:10/29/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/05/2020 2247 DJG 72473 2 5030B 8260D 1 11/06/2020 2318 DJG 72627 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 2 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Run 2 Acceptance Surrogate Q % Recovery Limits Q % Recovery Limits Bromofluorobenzene 93 70-130 95 70-130 1,2-Dichloroethane-d4 95 70-130 93 70-130 Toluene-d8 102 70-130 95 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/04/2020 2339 BPK 11/04/2020 1121 71608 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 150 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 41 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 58 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29001-003 Description: SW-3 Matrix: Aqueous Date Sampled:10/27/2020 1330 Date Received:10/29/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/04/2020 2339 BPK 11/04/2020 1121 71608 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Lead 7439-92-1 Nickel 7440-02-0 Selenium 7782-49-2 Silver 7440-22-4 Thallium 7440-28-0 Vanadium 7440-62-2 Zinc 7440-66-6 6020B ND 1.0 0.25 ug/L 1 6020B 13 5.0 1.3 ug/L 1 6020B ND 5.0 1.3 ug/L 1 6020B ND 1.0 0.25 ug/L 1 6020B ND 0.50 0.15 ug/L 1 6020B ND 5.0 2.5 ug/L 1 6020B 5.6 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 58 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29001-004 Description: SW-4 Matrix: Aqueous Date Sampled:10/27/2020 1520 Date Received:10/29/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 5030B 8260D (SIM) 1 11/06/2020 0428 DJG 72476 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 2 Run 2 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 98 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/05/2020 2311 DJG 72473 2 5030B 8260D 1 11/06/2020 2340 DJG 72627 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of 58 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29001-004 Description: SW-4 Matrix: Aqueous Date Sampled:10/27/2020 1520 Date Received:10/29/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/05/2020 2311 DJG 72473 2 5030B 8260D 1 11/06/2020 2340 DJG 72627 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 2 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Run 2 Acceptance Surrogate Q % Recovery Limits Q % Recovery Limits Bromofluorobenzene 94 70-130 97 70-130 1,2-Dichloroethane-d4 96 70-130 92 70-130 Toluene-d8 103 70-130 96 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/05/2020 0001 BPK 11/04/2020 1121 71608 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 1.2 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 120 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 4.3 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 1.8 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 3.9 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 16 of 58 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29001-004 Description: SW-4 Matrix: Aqueous Date Sampled:10/27/2020 1520 Date Received:10/29/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/05/2020 0001 BPK 11/04/2020 1121 71608 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Lead 7439-92-1 6020B 0.86 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 5.0 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.8 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 9.1 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 17 of 58 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29001-005 Description: SW-5 Matrix: Aqueous Date Sampled:10/27/2020 1415 Date Received:10/29/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 5030B 8260D (SIM) 1 11/06/2020 0453 DJG 72476 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 7.1 3.0 1.0 ug/L 2 Run 2 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 95 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/05/2020 2334 DJG 72473 2 5030B 8260D 1 11/07/2020 0002 DJG 72627 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 18 of 58 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29001-005 Description: SW-5 Matrix: Aqueous Date Sampled:10/27/2020 1415 Date Received:10/29/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/05/2020 2334 DJG 72473 2 5030B 8260D 1 11/07/2020 0002 DJG 72627 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 1.3 J 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 2 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Run 2 Acceptance Surrogate Q % Recovery Limits Q % Recovery Limits Bromofluorobenzene 94 70-130 100 70-130 1,2-Dichloroethane-d4 94 70-130 92 70-130 Toluene-d8 101 70-130 96 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/05/2020 0009 BPK 11/04/2020 1121 71608 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 83 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.1 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 3.1 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 19 of 58 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29001-005 Description: SW-5 Matrix: Aqueous Date Sampled:10/27/2020 1415 Date Received:10/29/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/05/2020 0009 BPK 11/04/2020 1121 71608 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 9.2 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 1.4 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 20 of 58 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29001-006 Description: SW-6 Matrix: Aqueous Date Sampled:10/27/2020 1435 Date Received:10/29/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 11/04/2020 1357 BWS 72222 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 8.7 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 97 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/05/2020 2357 DJG 72473 2 5030B 8260D 1 11/07/2020 0025 DJG 72627 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 21 of 58 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29001-006 Description: SW-6 Matrix: Aqueous Date Sampled:10/27/2020 1435 Date Received:10/29/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/05/2020 2357 DJG 72473 2 5030B 8260D 1 11/07/2020 0025 DJG 72627 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 2 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Run 2 Acceptance Surrogate Q % Recovery Limits Q % Recovery Limits Bromofluorobenzene 93 70-130 104 70-130 1,2-Dichloroethane-d4 93 70-130 93 70-130 Toluene-d8 100 70-130 98 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/05/2020 0016 BPK 11/04/2020 1121 71608 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 97 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 2.1 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 22 of 58 Client: Bun nell-Lammons Engineering, Inc. Laboratory ID:VJ29001-006 Description: SW-6 Matrix: Aqueous Date Sampled:10/27/2020 1435 Date Received:10/29/2020 ICP-MS Metals Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/05/2020 0016 BPK Prep Date Batch 11/04/2020 1121 71608 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Copper 7440-50-8 6020B 1.5 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.33 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 3.4 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 3.3 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.5 J 10 2.5 ug/L 1 LOCI = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 23 of 58 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29001-007 Description: SW-7 Matrix: Aqueous Date Sampled:10/27/2020 1307 Date Received:10/29/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 11/05/2020 0614 DJG 72318 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 12 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 89 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/06/2020 0048 DJG 72473 2 5030B 8260D 1 11/07/2020 0110 DJG 72627 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 39 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.75 J 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 24 of 58 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29001-007 Description: SW-7 Matrix: Aqueous Date Sampled:10/27/2020 1307 Date Received:10/29/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/06/2020 0048 DJG 72473 2 5030B 8260D 1 11/07/2020 0110 DJG 72627 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 2 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Run 2 Acceptance Surrogate Q % Recovery Limits Q % Recovery Limits Bromofluorobenzene 93 70-130 94 70-130 1,2-Dichloroethane-d4 95 70-130 91 70-130 Toluene-d8 102 70-130 96 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/05/2020 0124 BPK 11/04/2020 1121 71608 2 3005A 6020B 5 11/05/2020 0024 BPK 11/04/2020 1121 71608 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 3.1 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 17 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 320 25 6.3 ug/L 2 Beryllium 7440-41-7 6020B 0.84 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.24 J 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 96 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 61 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 25 of 58 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29001-007 Description: SW-7 Matrix: Aqueous Date Sampled:10/27/2020 1307 Date Received:10/29/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/05/2020 0124 BPK 11/04/2020 1121 71608 2 3005A 6020B 5 11/05/2020 0024 BPK 11/04/2020 1121 71608 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Copper 7440-50-8 6020B 35 25 6.3 ug/L 2 Lead 7439-92-1 6020B 5.1 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 94 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 4.7 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 48 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 150 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 26 of 58 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29001-008 Description: SW-8 Matrix: Aqueous Date Sampled:10/27/2020 1215 Date Received:10/29/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 11/05/2020 0550 DJG 72318 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 1.4 J 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 97 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/06/2020 0020 DJG 72473 2 5030B 8260D 1 11/07/2020 0047 DJG 72627 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 27 of 58 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29001-008 Description: SW-8 Matrix: Aqueous Date Sampled:10/27/2020 1215 Date Received:10/29/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/06/2020 0020 DJG 72473 2 5030B 8260D 1 11/07/2020 0047 DJG 72627 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 2 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Run 2 Acceptance Surrogate Q % Recovery Limits Q % Recovery Limits Bromofluorobenzene 93 70-130 102 70-130 1,2-Dichloroethane-d4 95 70-130 95 70-130 Toluene-d8 102 70-130 97 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/05/2020 0031 BPK 11/04/2020 1121 71608 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.0 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 120 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 6.6 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 2.6 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 28 of 58 Client: Bun nell-Lammons Engineering, Inc. Laboratory ID:VJ29001-008 Description: SW-8 Matrix: Aqueous Date Sampled:10/27/2020 1215 Date Received:10/29/2020 ICP-MS Metals Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/05/2020 0031 BPK Prep Date Batch 11/04/2020 1121 71608 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Copper 7440-50-8 6020B 4.2 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.76 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 6.3 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 8.9 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 8.7 J 10 2.5 ug/L 1 LOCI = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 29 of 58 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 30 of 58 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: VQ72222-001 Matrix: Aqueous Batch: 72222 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 11/04/20201019 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 94 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 31 of 58 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: VQ72222-002 Matrix: Aqueous Batch: 72222 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 52 1 104 70-130 11/04/2020 0830 Surrogate Q % Rec Acceptance Limit 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit 108 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 32 of 58 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: VQ72318-001 Matrix: Aqueous Batch: 72318 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 11/04/2020 2141 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 96 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 33 of 58 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: VQ72318-002 Matrix: Aqueous Batch: 72318 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 48 1 96 70-130 11/04/2020 2038 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 102 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 34 of 58 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ72473-001 Matrix: Aqueous Batch: 72473 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 11/05/2020 2107 Acrylonitrile ND 1 20 0.80 ug/L 11/05/2020 2107 Benzene ND 1 1.0 0.40 ug/L 11/05/2020 2107 Bromochloromethane ND 1 1.0 0.40 ug/L 11/05/2020 2107 Bromodichloromethane ND 1 1.0 0.40 ug/L 11/05/2020 2107 Bromoform ND 1 1.0 0.40 ug/L 11/05/2020 2107 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 11/05/2020 2107 2-Butanone (MEK) ND 1 10 2.0 ug/L 11/05/2020 2107 Carbon disulfide ND 1 1.0 0.40 ug/L 11/05/2020 2107 Carbon tetrachloride ND 1 1.0 0.40 ug/L 11/05/2020 2107 Chlorobenzene ND 1 1.0 0.40 ug/L 11/05/2020 2107 Chloroethane ND 1 2.0 0.40 ug/L 11/05/2020 2107 Chloroform ND 1 1.0 0.40 ug/L 11/05/2020 2107 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 11/05/2020 2107 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 11/05/2020 2107 Dibromochloromethane ND 1 1.0 0.40 ug/L 11/05/2020 2107 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 11/05/2020 2107 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 11/05/2020 2107 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 11/05/2020 2107 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 11/05/2020 2107 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 11/05/2020 2107 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 11/05/2020 2107 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 11/05/2020 2107 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 11/05/2020 2107 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 11/05/2020 2107 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 11/05/2020 2107 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 11/05/2020 2107 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 11/05/2020 2107 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 11/05/2020 2107 Ethylbenzene ND 1 1.0 0.40 ug/L 11/05/2020 2107 2-Hexanone ND 1 10 2.0 ug/L 11/05/2020 2107 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 11/05/2020 2107 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 11/05/2020 2107 Methylene chloride ND 1 1.0 0.40 ug/L 11/05/2020 2107 Styrene ND 1 1.0 0.41 ug/L 11/05/2020 2107 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 11/05/2020 2107 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 11/05/2020 2107 Tetrachloroethene ND 1 1.0 0.40 ug/L 11/05/2020 2107 Toluene ND 1 1.0 0.40 ug/L 11/05/2020 2107 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 11/05/2020 2107 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 11/05/2020 2107 Trichloroethene ND 1 1.0 0.40 ug/L 11/05/2020 2107 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 11/05/2020 2107 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 11/05/2020 2107 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 35 of 58 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ72473-001 Matrix: Aqueous Batch: 72473 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl chloride ND 1 1.0 0.40 ug/L 11/05/2020 2107 Xylenes (total) ND 1 1.0 0.40 ug/L 11/05/2020 2107 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 93 70-130 1,2-Dichloroethane-d4 93 70-130 Toluene-d8 100 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 36 of 58 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ72473-002 Matrix: Aqueous Batch: 72473 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 96 1 96 60-140 11/05/2020 2003 Acrylonitrile 100 96 1 96 70-130 11/05/2020 2003 Benzene 50 48 1 95 70-130 11/05/2020 2003 Bromochloromethane 50 47 1 94 70-130 11/05/2020 2003 Bromodichloromethane 50 47 1 94 70-130 11/05/2020 2003 Bromoform 50 54 1 107 70-130 11/05/2020 2003 Bromomethane (Methyl bromide) 50 47 1 94 70-130 11/05/2020 2003 2-Butanone (MEK) 100 98 1 98 70-130 11/05/2020 2003 Carbon disulfide 50 42 1 84 70-130 11/05/2020 2003 Carbon tetrachloride 50 41 1 83 70-130 11/05/2020 2003 Chlorobenzene 50 50 1 101 70-130 11/05/2020 2003 Chloroethane 50 43 1 86 70-130 11/05/2020 2003 Chloroform 50 44 1 88 70-130 11/05/2020 2003 Chloromethane (Methyl chloride) 50 48 1 95 60-140 11/05/2020 2003 1,2-Dibromo-3-chloropropane (DBCP) 50 43 1 87 70-130 11/05/2020 2003 Dibromochloromethane 50 51 1 103 70-130 11/05/2020 2003 1,2-Dibromoethane (EDB) 50 53 1 105 70-130 11/05/2020 2003 Dibromomethane (Methylene bromide) 50 51 1 101 70-130 11/05/2020 2003 trans- 1,4-Dichloro-2-butene 50 51 1 103 70-130 11/05/2020 2003 1,2-Dichlorobenzene 50 52 1 103 70-130 11/05/2020 2003 1,4-Dichlorobenzene 50 51 1 103 70-130 11/05/2020 2003 1,1-Dichloroethane 50 45 1 90 70-130 11/05/2020 2003 1,2-Dichloroethane 50 50 1 101 70-130 11/05/2020 2003 1,1-Dichloroethene 50 40 1 81 70-130 11/05/2020 2003 cis- 1,2-Dichloroethene 50 44 1 89 70-130 11/05/2020 2003 trans- 1,2-Dichloroethene 50 43 1 86 70-130 11/05/2020 2003 1,2-Dichloropropane 50 48 1 96 70-130 11/05/2020 2003 cis- 1,3-Dichloropropene 50 49 1 97 70-130 11/05/2020 2003 trans- 1,3-Dichloropropene 50 51 1 102 70-130 11/05/2020 2003 Ethylbenzene 50 50 1 99 70-130 11/05/2020 2003 2-Hexanone 100 110 1 112 70-130 11/05/2020 2003 Methyl iodide (lodomethane) 50 45 1 91 70-130 11/05/2020 2003 4-Methyl-2-pentanone 100 110 1 106 70-130 11/05/2020 2003 Methylene chloride 50 44 1 88 70-130 11/05/2020 2003 Styrene 50 50 1 100 70-130 11/05/2020 2003 1,1,1,2-Tetrachloroethane 50 52 1 103 70-130 11/05/2020 2003 1,1,2,2-Tetrachloroethane 50 52 1 103 70-130 11/05/2020 2003 Tetrachloroethene 50 50 1 100 70-130 11/05/2020 2003 Toluene 50 49 1 99 70-130 11/05/2020 2003 1,1,1-Trichloroethane 50 41 1 83 70-130 11/05/2020 2003 1,1,2-Trichloroethane 50 52 1 103 70-130 11/05/2020 2003 Trichloroethene 50 48 1 95 70-130 11/05/2020 2003 Trichlorofluoromethane 50 40 1 81 70-130 11/05/2020 2003 1,2,3-Trichloropropane 50 51 1 103 70-130 11/05/2020 2003 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 37 of 58 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ72473-002 Matrix: Aqueous Batch: 72473 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl chloride 50 46 1 93 70-130 11/05/2020 2003 Xylenes (total) 100 99 1 99 70-130 11/05/2020 2003 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 91 70-130 1,2-Dichloroethane-d4 93 70-130 Toluene-d8 92 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 38 of 58 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ72473-001 Matrix: Aqueous Batch: 72473 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 11/05/2020 2107 Acrylonitrile ND 1 20 0.80 ug/L 11/05/2020 2107 Benzene ND 1 1.0 0.40 ug/L 11/05/2020 2107 Bromochloromethane ND 1 1.0 0.40 ug/L 11/05/2020 2107 Bromodichloromethane ND 1 1.0 0.40 ug/L 11/05/2020 2107 Bromoform ND 1 1.0 0.40 ug/L 11/05/2020 2107 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 11/05/2020 2107 2-Butanone (MEK) ND 1 10 2.0 ug/L 11/05/2020 2107 Carbon disulfide ND 1 1.0 0.40 ug/L 11/05/2020 2107 Carbon tetrachloride ND 1 1.0 0.40 ug/L 11/05/2020 2107 Chlorobenzene ND 1 1.0 0.40 ug/L 11/05/2020 2107 Chloroethane ND 1 2.0 0.40 ug/L 11/05/2020 2107 Chloroform ND 1 1.0 0.40 ug/L 11/05/2020 2107 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 11/05/2020 2107 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 11/05/2020 2107 Dibromochloromethane ND 1 1.0 0.40 ug/L 11/05/2020 2107 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 11/05/2020 2107 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 11/05/2020 2107 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 11/05/2020 2107 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 11/05/2020 2107 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 11/05/2020 2107 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 11/05/2020 2107 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 11/05/2020 2107 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 11/05/2020 2107 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 11/05/2020 2107 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 11/05/2020 2107 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 11/05/2020 2107 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 11/05/2020 2107 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 11/05/2020 2107 Ethylbenzene ND 1 1.0 0.40 ug/L 11/05/2020 2107 2-Hexanone ND 1 10 2.0 ug/L 11/05/2020 2107 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 11/05/2020 2107 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 11/05/2020 2107 Methylene chloride ND 1 1.0 0.40 ug/L 11/05/2020 2107 Styrene ND 1 1.0 0.41 ug/L 11/05/2020 2107 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 11/05/2020 2107 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 11/05/2020 2107 Tetrachloroethene ND 1 1.0 0.40 ug/L 11/05/2020 2107 Tetrahydrofuran ND 1 5.0 1.0 ug/L 11/05/2020 2107 Toluene ND 1 1.0 0.40 ug/L 11/05/2020 2107 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 11/05/2020 2107 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 11/05/2020 2107 Trichloroethene ND 1 1.0 0.40 ug/L 11/05/2020 2107 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 11/05/2020 2107 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 39 of 58 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ72473-001 Matrix: Aqueous Batch: 72473 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 11/05/2020 2107 Vinyl chloride ND 1 1.0 0.40 ug/L 11/05/2020 2107 Xylenes (total) ND 1 1.0 0.40 ug/L 11/05/2020 2107 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 93 70-130 1,2-Dichloroethane-d4 93 70-130 Toluene-d8 100 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 40 of 58 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ72473-002 Matrix: Aqueous Batch: 72473 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 96 1 96 60-140 11/05/2020 2003 Acrylonitrile 100 96 1 96 70-130 11/05/2020 2003 Benzene 50 48 1 95 70-130 11/05/2020 2003 Bromochloromethane 50 47 1 94 70-130 11/05/2020 2003 Bromodichloromethane 50 47 1 94 70-130 11/05/2020 2003 Bromoform 50 54 1 107 70-130 11/05/2020 2003 Bromomethane (Methyl bromide) 50 47 1 94 70-130 11/05/2020 2003 2-Butanone (MEK) 100 98 1 98 70-130 11/05/2020 2003 Carbon disulfide 50 42 1 84 70-130 11/05/2020 2003 Carbon tetrachloride 50 41 1 83 70-130 11/05/2020 2003 Chlorobenzene 50 50 1 101 70-130 11/05/2020 2003 Chloroethane 50 43 1 86 70-130 11/05/2020 2003 Chloroform 50 44 1 88 70-130 11/05/2020 2003 Chloromethane (Methyl chloride) 50 48 1 95 60-140 11/05/2020 2003 1,2-Dibromo-3-chloropropane (DBCP) 50 43 1 87 70-130 11/05/2020 2003 Dibromochloromethane 50 51 1 103 70-130 11/05/2020 2003 1,2-Dibromoethane (EDB) 50 53 1 105 70-130 11/05/2020 2003 Dibromomethane (Methylene bromide) 50 51 1 101 70-130 11/05/2020 2003 trans- 1,4-Dichloro-2-butene 50 51 1 103 70-130 11/05/2020 2003 1,2-Dichlorobenzene 50 52 1 103 70-130 11/05/2020 2003 1,4-Dichlorobenzene 50 51 1 103 70-130 11/05/2020 2003 1,1-Dichloroethane 50 45 1 90 70-130 11/05/2020 2003 1,2-Dichloroethane 50 50 1 101 70-130 11/05/2020 2003 1,1-Dichloroethene 50 40 1 81 70-130 11/05/2020 2003 cis- 1,2-Dichloroethene 50 44 1 89 70-130 11/05/2020 2003 trans- 1,2-Dichloroethene 50 43 1 86 70-130 11/05/2020 2003 1,2-Dichloropropane 50 48 1 96 70-130 11/05/2020 2003 cis- 1,3-Dichloropropene 50 49 1 97 70-130 11/05/2020 2003 trans- 1,3-Dichloropropene 50 51 1 102 70-130 11/05/2020 2003 Ethylbenzene 50 50 1 99 70-130 11/05/2020 2003 2-Hexanone 100 110 1 112 70-130 11/05/2020 2003 Methyl iodide (lodomethane) 50 45 1 91 70-130 11/05/2020 2003 4-Methyl-2-pentanone 100 110 1 106 70-130 11/05/2020 2003 Methylene chloride 50 44 1 88 70-130 11/05/2020 2003 Styrene 50 50 1 100 70-130 11/05/2020 2003 1,1,1,2-Tetrachloroethane 50 52 1 103 70-130 11/05/2020 2003 1,1,2,2-Tetrachloroethane 50 52 1 103 70-130 11/05/2020 2003 Tetrachloroethene 50 50 1 100 70-130 11/05/2020 2003 Tetrahydrofuran 50 49 1 98 70-130 11/05/2020 2003 Toluene 50 49 1 99 70-130 11/05/2020 2003 1,1,1-Trichloroethane 50 41 1 83 70-130 11/05/2020 2003 1,1,2-Trichloroethane 50 52 1 103 70-130 11/05/2020 2003 Trichloroethene 50 48 1 95 70-130 11/05/2020 2003 Trichlorofluoromethane 50 40 1 81 70-130 11/05/2020 2003 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 41 of 58 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ72473-002 Matrix: Aqueous Batch: 72473 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,2,3-Trichloropropane 50 51 1 103 70-130 11/05/2020 2003 Vinyl chloride 50 46 1 93 70-130 11/05/2020 2003 Xylenes (total) 100 99 1 99 70-130 11/05/2020 2003 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 91 70-130 1,2-Dichloroethane-d4 93 70-130 Toluene-d8 92 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 42 of 58 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: VQ72476-001 Matrix: Aqueous Batch: 72476 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 11/05/2020 2333 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 102 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 43 of 58 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: VQ72476-002 Matrix: Aqueous Batch: 72476 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 48 1 96 70-130 11/05/2020 2229 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 109 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 44 of 58 Volatile Organic Compounds by GC/MS (SIM) - LCSD Sample ID: VQ72476-003 Matrix: Aqueous Batch: 72476 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result % Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date 1,4-Dioxane 50 48 1 95 0.44 70-130 20 11/06/2020 0835 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 110 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 45 of 58 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ72627-001 Matrix: Aqueous Batch: 72627 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 11/06/2020 2127 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 93 70-130 Toluene-d8 96 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 46 of 58 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ72627-002 Matrix: Aqueous Batch: 72627 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 53 1 106 60-140 11/06/2020 2028 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 95 70-130 Toluene-d8 100 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 47 of 58 Volatile Organic Compounds by GC/MS - LCSD Sample ID: VQ72627-003 Matrix: Aqueous Batch: 72627 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Vinyl acetate 50 52 1 104 2.5 60-140 20 11/07/2020 0132 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 93 70-130 Toluene-d8 98 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 48 of 58 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ72627-001 Matrix: Aqueous Batch: 72627 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 11/06/2020 2127 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 93 70-130 Toluene-d8 96 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 49 of 58 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ72627-002 Matrix: Aqueous Batch: 72627 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 53 1 106 60-140 11/06/2020 2028 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 95 70-130 Toluene-d8 100 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 50 of 58 Volatile Organic Compounds by GC/MS - LCSD Sample ID: VQ72627-003 Matrix: Aqueous Batch: 72627 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Vinyl acetate 50 52 1 104 2.5 60-140 20 11/07/2020 0132 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 93 70-130 Toluene-d8 98 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 51 of 58 ICP-MS Metals - MB Sample ID: VQ71608-001 Matrix: Aqueous Batch: 71608 Prep Method: 3005A Analytical Method: 6020B Prep Date: 11/04/2020 1121 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 11/04/2020 2232 Arsenic ND 1 2.0 1.3 ug/L 11/04/2020 2232 Barium ND 1 5.0 1.3 ug/L 11/04/2020 2232 Beryllium ND 1 0.40 0.15 ug/L 11/04/2020 2232 Cadmium ND 1 0.50 0.13 ug/L 11/04/2020 2232 Chromium ND 1 5.0 1.3 ug/L 11/04/2020 2232 Cobalt ND 1 5.0 1.3 ug/L 11/04/2020 2232 Copper ND 1 5.0 1.3 ug/L 11/04/2020 2232 Lead ND 1 1.0 0.25 ug/L 11/04/2020 2232 Nickel ND 1 5.0 1.3 ug/L 11/04/2020 2232 Selenium ND 1 5.0 1.3 ug/L 11/04/2020 2232 Silver ND 1 1.0 0.25 ug/L 11/04/2020 2232 Thallium ND 1 0.50 0.15 ug/L 11/04/2020 2232 Vanadium ND 1 5.0 2.5 ug/L 11/04/2020 2232 Zinc ND 1 10 2.5 ug/L 11/04/2020 2232 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 52 of 58 ICP-MS Metals - LCS Sample ID: VQ71608-002 Matrix: Aqueous Batch: 71608 Prep Method: 3005A Analytical Method: 6020B Prep Date: 11/04/2020 1121 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 100 1 103 80-120 11/04/2020 2239 Arsenic 100 100 1 101 80-120 11/04/2020 2239 Barium 100 95 1 95 80-120 11/04/2020 2239 Beryllium 100 100 1 104 80-120 11/04/2020 2239 Cadmium 100 98 1 98 80-120 11/04/2020 2239 Chromium 100 110 1 109 80-120 11/04/2020 2239 Cobalt 100 110 1 110 80-120 11/04/2020 2239 Copper 100 110 1 110 80-120 11/04/2020 2239 Lead 100 100 1 105 80-120 11/04/2020 2239 Nickel 100 110 1 108 80-120 11/04/2020 2239 Selenium 100 88 1 88 80-120 11/04/2020 2239 Silver 100 110 1 106 80-120 11/04/2020 2239 Thallium 100 110 1 109 80-120 11/04/2020 2239 Vanadium 100 110 1 107 80-120 11/04/2020 2239 Zinc 100 97 1 97 80-120 11/04/2020 2239 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 53 of 58 ICP-MS Metals - MS Sample ID: VJ29001-001MS Matrix: Aqueous Batch: 71608 Prep Method: 3005A Analytical Method: 6020B Prep Date: 11/04/2020 1121 Sample Spike Amount Amount Result % Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony ND 100 110 1 105 70-130 11/04/2020 2302 Arsenic ND 100 100 1 105 70-130 11/04/2020 2302 Barium 100 100 200 1 103 70-130 11/04/2020 2302 Beryllium ND 100 110 1 111 70-130 11/04/2020 2302 Cadmium ND 100 110 1 105 70-130 11/04/2020 2302 Chromium ND 100 100 1 105 70-130 11/04/2020 2302 Cobalt 3.7 100 110 1 105 70-130 11/04/2020 2302 Copper ND 100 110 1 112 70-130 11/04/2020 2302 Lead 0.34 100 100 1 102 70-130 11/04/2020 2302 Nickel ND 100 100 1 104 70-130 11/04/2020 2302 Selenium ND 100 97 1 97 70-130 11/04/2020 2302 Silver ND 100 110 1 106 70-130 11/04/2020 2302 Thallium ND 100 110 1 105 70-130 11/04/2020 2302 Vanadium ND 100 100 1 105 70-130 11/04/2020 2302 Zinc 2.5 100 130 1 127 70-130 11/04/2020 2302 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 54 of 58 ICP-MS Metals - MSD Sample ID: VJ29001-001MD Matrix: Aqueous Batch: 71608 Prep Method: 3005A Analytical Method: 6020B Prep Date: 11/04/2020 1121 Sample Spike Amount Amount Result % Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Antimony ND 100 100 1 101 3.8 70-130 20 11/04/2020 2309 Arsenic ND 100 100 1 101 4.1 70-130 20 11/04/2020 2309 Barium 100 100 190 1 93 4.9 70-130 20 11/04/2020 2309 Beryllium ND 100 110 1 105 5.6 70-130 20 11/04/2020 2309 Cadmium ND 100 100 1 101 4.5 70-130 20 11/04/2020 2309 Chromium ND 100 100 1 102 3.2 70-130 20 11/04/2020 2309 Cobalt 3.7 100 100 1 100 4.2 70-130 20 11/04/2020 2309 Copper ND 100 110 1 108 3.9 70-130 20 11/04/2020 2309 Lead 0.34 100 98 1 98 4.1 70-130 20 11/04/2020 2309 Nickel ND 100 100 1 100 4.5 70-130 20 11/04/2020 2309 Selenium ND 100 93 1 93 3.4 70-130 20 11/04/2020 2309 Silver ND 100 100 1 102 3.9 70-130 20 11/04/2020 2309 Thallium ND 100 100 1 102 3.5 70-130 20 11/04/2020 2309 Vanadium ND 100 100 1 100 4.9 70-130 20 11/04/2020 2309 Zinc 2.5 100 110 + 1 103 21 70-130 20 11/04/2020 2309 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 55 of 58 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 56 of 58 ,-0 ow CD D D . �" ac 6&aVical PACE AI ALYMAL SERVICES, M6 hIrdri[UgQ I'c:nt Drfviy -Weel Columbia. 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Were sample Ms listed cut all sample corlaincrs? x s Na 8. l Ls colrcct_cu>I data & t me lj' li r rnttoo Cr Yrs ND 9- W--�s Lmiku ion dme & time fisted Ott all sample cartainers'' ] us ❑Ntr 11 Did all Wintainer iabal information (ID, date, time) agree twiih lie f•— ;' J J , V`'erc teas to ne performers listed an the CCC? -- es. Na ❑ hTD I2- .Dld aJ1 s.arnpJes aa'rive Di Ite prop.,r L mtaincrs for each iesC andfar in aped cnrditinn (unbroken iason. amr -- © 5LJ Nu 13- Wus ade bate SalliLie VL51UMIe i14a1.iNO Yes Nu J4, Wun A sate las received within fi the .boJding time or 48 hours, whichever kornas first'? ❑ Ye€ . n 15. W'et0 my samples containers IniS�iT1_WUxcc55 (citcJc are) sanip leg hlol listed on COC9 �11Cr, $ ldU ❑-*1�1 For VOA Eeid RS:�-175 samples, were bubo=es present >"`pca-size' ('/a' ar 6tr11e! itr dinmwter, in ally (IC I11t V 0A vial5.) I` Yes Ll N4 —M�JA =?. Were all1?RQlnteliXla'nur Lens samples received ate pjj of<21J 'es No A L$. W= all cyaajdc sam-jJes received at a p 9> 12 and sulfide sainpltN rnucived rd tt r3H'> 57 El Yes ElNo DK- A 19- Ware all applicable 1N K VcyantdJp,setr.DL'Fi?_5.11609.3 { 0-Sn1 ) -;ampler I'_re of rtniahtstl chlorine? El Y s Q tic qcorrectly 20' Vkfra-r. rr:.eMl rernaVk9reque.Sts (i,e. rNLIrstcd dilul[mts, MYSD d=gnations, et, ---', transcribed from rho CUC into VIC C;DMITlEnt section 'n L[NfS? Yes Wo '• J. Was die ub[e nurnhur 1isied on the-eo11t8iner label? ); Ln •.Iota H Sample PrmeYviblian (Must be cout>pleted for tiny sumplc(s) incanTizily preserwed Or w;lh he dspacv.; d 1p e(s) _-✓mil A ---'.wore revsived incaruthypnrsc.vcdArd were adjuslod acc"A;ngly in samp.1c mcciving %AAA -in pfcirc,le onG; H2SC}4, HNO2I L.10, N90H using SR P t 4� Time ::fprcacrvatiori Jf MOrC Alan oltie preservati re is :trs�lxd, pJcase note in the et3mMents WOW_ v.' _re rtt.ivrd with hubbies ,-6 rnm =n dialnerer- St-: mpJcS(s) —... +* _ WCru rcocivod }vita TIZC > D. € tng1L (2f f 19 is no ) and were vr3juMP4 9cckrdingiy i7 sample rccciving with sodium aiiilsurWi; (NayS,7} %'A1 S, Iealy JDL i`'l _ SJ� barcode labels appliod by; — J.)Qte. IQ7 .LJ Cn?ninenls- Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 58 of 58 0 aceAnalytical Report of Analysis Bunnell-Lammons Engineering, Inc. 6004 Ponders Court Greenville, SC 29615 Attention: Andy Alexander Project Name: Active Buncombe County Landfill Leachate and Leak Detectors Project Number: J20-9378-22 Lot Number:VJ29002 Date Completed:11/09/2020 11 /12/2020 3:17 PM Approved and released by: Project Manager II: Lucas Odom PCCRF� 24rA lkiA / ANSI National Accreditation Board A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 63 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Bunnell-Lammons Engineering, Inc. Lot Number: VJ29002 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. VOCs by GC/MS The following sample was diluted due to the nature of the sample matrix: VJ29002-008. The LOQ has been elevated to reflect the dilution. The LCS associated with batch 72536 recovered Acetone above method criteria. No corretive action is required as all associated samples did not have detections above the LOQ. Metals by ICP-MS The following sample was diluted due to the nature of the sample matrix: VJ29002-008. The LOQ has been elevated to reflect the dilution. Leachate Pond In order to meet all hold times, the analysis for BOD, Nitrate, and TSS was performed by Pace Asheville, This data has been amended to this report. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 2 of 63 PACE ANALYTICAL SERVICES, LLC Sample Summary Bunnell-Lammons Engineering, Inc. Lot Number: VJ29002 Sample Number Sample ID Matrix Date Sampled Date Received 001 LD-3 Aqueous 10/27/20201640 10/28/2020 002 LD-4 Aqueous 10/27/20201655 10/28/2020 003 LD-5 Aqueous 10/27/20201610 10/28/2020 004 LD-6 Aqueous 10/27/20201730 10/28/2020 005 LD-2 Aqueous 10/30/20201140 11/02/2020 006 LEACHATE LD Aqueous 10/30/2020 1155 11/02/2020 007 LD-1 Aqueous 10/30/20201250 11/02/2020 008 LEACHATE POND Aqueous 10/30/2020 1215 11/02/2020 (8 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 63 PACE ANALYTICAL SERVICES, LLC Detection Summary Bunnell-Lammons Engineering, Inc. Lot Number: VJ29002 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 LD-3 Aqueous Acetone 8260D 5.0 J ug/L 6 001 LD-3 Aqueous Benzene 8260D 0.80 J ug/L 6 001 LD-3 Aqueous Chloroethane 8260D 0.47 J ug/L 6 001 LD-3 Aqueous 1,4-Dichlorobenzene 8260D 0.67 J ug/L 6 001 LD-3 Aqueous cis- 1,2-Dichloroethene 8260D 1.5 ug/L 6 001 LD-3 Aqueous Vinyl chloride 8260D 3.2 ug/L 7 001 LD-3 Aqueous Barium 6020B 220 ug/L 7 001 LD-3 Aqueous Cobalt 6020B 2.3 J ug/L 7 002 LD-4 Aqueous Benzene 8260D 2.1 ug/L 8 002 LD-4 Aqueous 1,1-Dichloroethane 8260D 0.60 J ug/L 8 002 LD-4 Aqueous Toluene 8260D 0.93 J ug/L 8 002 LD-4 Aqueous Vinyl chloride 8260D 1.2 ug/L 9 002 LD-4 Aqueous Xylenes (total) 8260D 0.58 J ug/L 9 002 LD-4 Aqueous Antimony 6020B 1.2 J ug/L 9 002 LD-4 Aqueous Arsenic 6020B 2.8 ug/L 9 002 LD-4 Aqueous Barium 6020B 380 ug/L 9 002 LD-4 Aqueous Beryllium 6020B 0.18 J ug/L 9 002 LD-4 Aqueous Cadmium 6020B 0.21 J ug/L 9 002 LD-4 Aqueous Chromium 6020B 180 ug/L 9 002 LD-4 Aqueous Cobalt 6020B 48 ug/L 9 002 LD-4 Aqueous Copper 6020B 57 ug/L 9 002 LD-4 Aqueous Lead 6020B 0.55 J ug/L 9 002 LD-4 Aqueous Nickel 6020B 97 ug/L 9 002 LD-4 Aqueous Selenium 6020B 1.9 J ug/L 9 002 LD-4 Aqueous Vanadium 6020B 5.6 ug/L 9 002 LD-4 Aqueous Zinc 6020B 22 ug/L 9 003 LD-5 Aqueous cis- 1,2-Dichloroethene 8260D 0.40 J ug/L 10 003 LD-5 Aqueous Barium 6020B 160 ug/L 11 003 LD-5 Aqueous Cobalt 6020B 87 ug/L 11 003 LD-5 Aqueous Nickel 6020B 25 ug/L 11 003 LD-5 Aqueous Zinc 6020B 2.7 J ug/L 12 004 LD-6 Aqueous Barium 6020B 410 ug/L 14 004 LD-6 Aqueous Cobalt 6020B 93 ug/L 14 004 LD-6 Aqueous Nickel 6020B 3.9 J ug/L 14 005 LD-2 Aqueous Acetone 8260D 5.9 J ug/L 15 005 LD-2 Aqueous 1,1-Dichloroethane 8260D 1.1 ug/L 15 005 LD-2 Aqueous cis- 1,2-Dichloroethene 8260D 0.57 J ug/L 15 005 LD-2 Aqueous Barium 6020B 190 ug/L 16 005 LD-2 Aqueous Chromium 6020B 2.4 J ug/L 16 005 LD-2 Aqueous Cobalt 6020B 94 ug/L 16 005 LD-2 Aqueous Copper 6020B 1.9 J ug/L 16 005 LD-2 Aqueous Nickel 6020B 24 ug/L 16 005 LD-2 Aqueous Zinc 6020B 6.5 J ug/L 16 006 LEACHATE LID Aqueous Acetone 8260D 6.3 J ug/L 17 006 LEACHATE LID Aqueous Barium 6020B 37 ug/L 18 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 63 Detection Summary (Continued) Lot Number: VJ29002 Sample Sample ID Matrix Parameter Method Result Q Units Page 006 LEACHATE LD Aqueous Beryllium 6020B 0.16 J ug/L 18 006 LEACHATE LD Aqueous Cobalt 6020B 22 ug/L 18 006 LEACHATE LD Aqueous Copper 6020B 9.4 ug/L 18 006 LEACHATE LD Aqueous Nickel 6020B 190 ug/L 18 006 LEACHATE LD Aqueous Selenium 6020B 1.3 J ug/L 18 006 LEACHATE LD Aqueous Zinc 6020B 91 ug/L 18 007 LD-1 Aqueous Acetone 8260D 6.8 J ug/L 19 007 LD-1 Aqueous Benzene 8260D 1.6 ug/L 19 007 LD-1 Aqueous Chlorobenzene 8260D 0.46 J ug/L 19 007 LD-1 Aqueous Chloroethane 8260D 0.83 J ug/L 19 007 LD-1 Aqueous 1,4-Dichlorobenzene 8260D 0.93 J ug/L 19 007 LD-1 Aqueous 1,1-Dichloroethane 8260D 1.2 ug/L 19 007 LD-1 Aqueous cis- 1,2-Dichloroethene 8260D 0.90 J ug/L 19 007 LD-1 Aqueous Barium 6020B 530 ug/L 20 007 LD-1 Aqueous Cobalt 6020B 280 ug/L 20 007 LD-1 Aqueous Nickel 6020B 42 ug/L 20 007 LD-1 Aqueous Selenium 6020B 1.5 J ug/L 20 007 LD-1 Aqueous Thallium 6020B 0.21 J ug/L 20 007 LD-1 Aqueous Zinc 6020B 3.4 J ug/L 20 008 LEACHATE POND Aqueous COD SM 5220D- 870 mg/L 21 008 LEACHATE POND Aqueous Phosphorus 365.1 1.6 mg/L 21 008 LEACHATE POND Aqueous Antimony 6020B 9.4 J ug/L 22 008 LEACHATE POND Aqueous Arsenic 6020B 30 ug/L 22 008 LEACHATE POND Aqueous Barium 6020B 510 ug/L 22 008 LEACHATE POND Aqueous Chromium 6020B 69 ug/L 22 008 LEACHATE POND Aqueous Cobalt 6020B 20 J ug/L 22 008 LEACHATE POND Aqueous Nickel 6020B 91 ug/L 22 008 LEACHATE POND Aqueous Selenium 6020B 8.7 J ug/L 22 008 LEACHATE POND Aqueous Vanadium 6020B 34 ug/L 23 (74 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 63 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29002-001 Description: LD-3 Matrix: Aqueous Date Sampled:10/27/2020 1640 Date Received:10/28/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/06/20201050 TML 72536 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 5.0 J 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D 0.80 J 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D 0.47 J 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D 0.67 J 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis-1,2-Dichloroethene 156-59-2 8260D 1.5 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 63 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29002-001 Description: LD-3 Matrix: Aqueous Date Sampled:10/27/2020 1640 Date Received:10/28/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/06/20201050 TML 72536 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 3.2 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 92 70-130 Toluene-d8 94 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/05/2020 0039 BPK 11/04/2020 1121 71608 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 220 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 2.3 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 63 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29002-002 Description: LD-4 Matrix: Aqueous Date Sampled:10/27/2020 1655 Date Received:10/28/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/06/20201112 TML 72536 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D 2.1 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D 0.60 J 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D 0.93 J 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 63 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29002-002 Description: LD-4 Matrix: Aqueous Date Sampled:10/27/2020 1655 Date Received:10/28/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/06/20201112 TML 72536 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 1.2 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 0.58 J 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 93 70-130 1,2-Dichloroethane-d4 86 70-130 Toluene-d8 95 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/05/2020 0131 BPK 11/04/2020 1121 71608 2 3005A 6020B 5 11/05/2020 0046 BPK 11/04/2020 1121 71608 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 1.2 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.8 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 380 25 6.3 ug/L 2 Beryllium 7440-41-7 6020B 0.18 J 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.21 J 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 180 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 48 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 57 25 6.3 ug/L 2 Lead 7439-92-1 6020B 0.55 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 97 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 1.9 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.6 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 22 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 63 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29002-003 Description: LD-5 Matrix: Aqueous Date Sampled:10/27/2020 1610 Date Received:10/28/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 11/05/2020 0525 DJG 72318 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 95 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/06/20201135 TML 72536 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 0.40 J 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 63 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29002-003 Description: LD-5 Matrix: Aqueous Date Sampled:10/27/2020 1610 Date Received:10/28/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/06/20201135 TML 72536 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 103 70-130 1,2-Dichloroethane-d4 90 70-130 Toluene-d8 97 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/05/2020 0054 BPK 11/04/2020 1121 71608 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 160 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 87 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 25 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 63 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29002-003 Description: LD-5 Matrix: Aqueous Date Sampled:10/27/2020 1610 Date Received:10/28/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/05/2020 0054 BPK 11/04/2020 1121 71608 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 Silver 7440-22-4 Thallium 7440-28-0 Vanadium 7440-62-2 Zinc 7440-66-6 6020B ND 5.0 1.3 ug/L 1 6020B ND 1.0 0.25 ug/L 1 6020B ND 0.50 0.15 ug/L 1 6020B ND 5.0 2.5 ug/L 1 6020B 2.7 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 63 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29002-004 Description: LD-6 Matrix: Aqueous Date Sampled:10/27/2020 1730 Date Received:10/28/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/06/20201157 TML 72536 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 63 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29002-004 Description: LD-6 Matrix: Aqueous Date Sampled:10/27/2020 1730 Date Received:10/28/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/06/20201157 TML 72536 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 88 70-130 Toluene-d8 100 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/05/2020 0101 BPK 11/04/2020 1121 71608 2 3005A 6020B 1 11/06/20201138 BNW 11/04/20201121 71608 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 410 5.0 1.3 ug/L 2 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 93 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 3.9 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 63 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29002-005 Description: LD-2 Matrix: Aqueous Date Sampled:10/30/2020 1140 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/06/2020 0019 STM 72479 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 5.9 J 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D 1.1 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis-1,2-Dichloroethene 156-59-2 8260D 0.57 J 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of 63 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29002-005 Description: LD-2 Matrix: Aqueous Date Sampled:10/30/2020 1140 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/06/2020 0019 STM 72479 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 101 70-130 1,2-Dichloroethane-d4 91 70-130 Toluene-d8 96 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/06/2020 0948 BNW 11/05/2020 1021 72194 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 190 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 2.4 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 94 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.9 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 24 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 6.5 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 16 of 63 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29002-006 Description: LEACHATE LID Matrix: Aqueous Date Sampled:10/30/2020 1155 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/06/2020 0042 STM 72479 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 6.3 J 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 17 of 63 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29002-006 Description: LEACHATE LID Matrix: Aqueous Date Sampled:10/30/2020 1155 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/06/2020 0042 STM 72479 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 93 70-130 Toluene-d8 98 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/06/20201028 BNW 11/05/20201021 72194 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 37 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.16 J 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 22 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 9.4 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 190 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 1.3 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 91 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 18 of 63 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29002-007 Description: LD-1 Matrix: Aqueous Date Sampled:10/30/2020 1250 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/06/2020 0105 STM 72479 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 6.8 J 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D 1.6 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D 0.46 J 1.0 0.40 ug/L Chloroethane 75-00-3 8260D 0.83 J 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D 0.93 J 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D 1.2 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis-1,2-Dichloroethene 156-59-2 8260D 0.90 J 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 19 of 63 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29002-007 Description: LD-1 Matrix: Aqueous Date Sampled:10/30/2020 1250 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 11/06/2020 0105 STM 72479 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 104 70-130 1,2-Dichloroethane-d4 91 70-130 Toluene-d8 98 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/06/20201034 BNW 11/05/20201021 72194 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 530 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 280 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 42 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 1.5 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.21 J 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.4 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 20 of 63 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29002-008 Description: LEACHATE POND Matrix: Aqueous Date Sampled:10/30/2020 1215 Date Received: 11 /02/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (COD) SM 5220D-2011 4 11/05/2020 2238 SRB 72462 2 (Phosphorus) 365.1 1 11/06/2020 1241 DMA 72514 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run COD SM 5220D-2011 870 80 80 mg/L 1 Phosphorus 7723-14-0 365.1 1.6 0.050 0.020 mg/L 2 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 20 11/06/2020 0318 STM 72479 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 400 100 ug/L 1 Acrylonitrile 107-13-1 8260D ND 400 16 ug/L 1 Benzene 71-43-2 8260D ND 20 8.0 ug/L 1 Bromochloromethane 74-97-5 8260D ND 20 8.0 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 20 8.0 ug/L 1 Bromoform 75-25-2 8260D ND 20 8.0 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 40 8.0 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 200 40 ug/L 1 Carbon disulfide 75-15-0 8260D ND 20 8.0 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 20 8.0 ug/L 1 Chlorobenzene 108-90-7 8260D ND 20 8.0 ug/L 1 Chloroethane 75-00-3 8260D ND 40 8.0 ug/L 1 Chloroform 67-66-3 8260D ND 20 8.0 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 20 10 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 20 8.0 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 20 8.0 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 20 8.0 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 20 8.0 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 40 10 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 20 8.0 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 20 8.0 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 20 8.0 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 20 8.0 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 20 8.0 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 20 8.0 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 20 8.0 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 20 8.0 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 20 8.0 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 20 8.0 ug/L 1 Ethylbenzene 100-41-4 8260D ND 20 8.0 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 21 of 63 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29002-008 Description: LEACHATE POND Matrix: Aqueous Date Sampled:10/30/2020 1215 Date Received: 11 /02/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 20 11/06/2020 0318 STM 72479 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 2-Hexanone 591-78-6 8260D ND 200 40 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 100 8.0 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 200 40 ug/L 1 Methylene chloride 75-09-2 8260D ND 20 8.0 ug/L 1 Styrene 100-42-5 8260D ND 20 8.2 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 20 8.0 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 20 8.0 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 20 8.0 ug/L 1 Toluene 108-88-3 8260D ND 20 8.0 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 20 8.0 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 20 8.0 ug/L 1 Trichloroethene 79-01-6 8260D ND 20 8.0 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 20 8.0 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 20 8.0 ug/L 1 Vinyl acetate 108-05-4 8260D ND 100 23 ug/L 1 Vinyl chloride 75-01-4 8260D ND 20 8.0 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 20 8.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 101 70-130 1,2-Dichloroethane-d4 89 70-130 Toluene-d8 100 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 5 11/06/20201040 BNW 11/05/20201021 72194 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 9.4 J 10 2.5 ug/L Arsenic 7440-38-2 6020B 30 10 6.3 ug/L Barium 7440-39-3 6020B 510 25 6.3 ug/L Beryllium 7440-41-7 6020B ND 2.0 0.75 ug/L Cadmium 7440-43-9 6020B ND 2.5 0.63 ug/L Chromium 7440-47-3 6020B 69 25 6.3 ug/L Cobalt 7440-48-4 6020B 20 J 25 6.3 ug/L Copper 7440-50-8 6020B ND 25 6.3 ug/L Lead 7439-92-1 6020B ND 5.0 1.3 ug/L Nickel 7440-02-0 6020B 91 25 6.3 ug/L Selenium 7782-49-2 6020B 8.7 J 25 6.3 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 22 of 63 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VJ29002-008 Description: LEACHATE POND Matrix: Aqueous Date Sampled:10/30/2020 1215 Date Received: 11 /02/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 5 11/06/20201040 BNW 11/05/20201021 72194 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Silver 7440-22-4 6020B ND 5.0 1.3 ug/L 1 Thallium 7440-28-0 6020B ND 2.5 0.75 ug/L 1 Vanadium 7440-62-2 6020B 34 25 13 ug/L 1 Zinc 7440-66-6 6020B ND 50 13 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 23 of 63 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 24 of 63 Inorganic non-metals - MB Sample ID: VQ72462-001 Matrix: Aqueous Batch: 72462 Analytical Method: SM 5220D-2011 Parameter Result Q Dil LOQ DL Units Analysis Date COD ND 1 20 20 mg/L 11/05/2020 2237 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 25 of 63 Inorganic non-metals - LCS Sample ID: VQ72462-002 Matrix: Aqueous Batch: 72462 Analytical Method: SM 5220D-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date COD 400 400 1 100 95-105 11/05/2020 2237 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 26 of 63 Inorganic non-metals - MB Sample ID: VQ72514-001 Matrix: Aqueous Batch: 72514 Analytical Method: 365.1 Parameter Result Q Dil LOQ DL Units Analysis Date Phosphorus ND 1 0.050 0.020 mg/L 11/06/20201231 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 27 of 63 Inorganic non-metals - LCS Sample ID: VQ72514-002 Matrix: Aqueous Batch: 72514 Analytical Method: 365.1 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Phosphorus 1.0 0.93 1 93 90-110 11/06/20201235 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 28 of 63 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: VQ72318-001 Matrix: Aqueous Batch: 72318 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 11/04/2020 2141 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 96 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 29 of 63 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: VQ72318-002 Matrix: Aqueous Batch: 72318 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 48 1 96 70-130 11/04/2020 2038 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 102 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 30 of 63 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ72479-001 Matrix: Aqueous Batch: 72479 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 11/05/2020 2038 Acrylonitrile ND 1 20 0.80 ug/L 11/05/2020 2038 Benzene ND 1 1.0 0.40 ug/L 11/05/2020 2038 Bromochloromethane ND 1 1.0 0.40 ug/L 11/05/2020 2038 Bromodichloromethane ND 1 1.0 0.40 ug/L 11/05/2020 2038 Bromoform ND 1 1.0 0.40 ug/L 11/05/2020 2038 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 11/05/2020 2038 2-Butanone (MEK) ND 1 10 2.0 ug/L 11/05/2020 2038 Carbon disulfide ND 1 1.0 0.40 ug/L 11/05/2020 2038 Carbon tetrachloride ND 1 1.0 0.40 ug/L 11/05/2020 2038 Chlorobenzene ND 1 1.0 0.40 ug/L 11/05/2020 2038 Chloroethane ND 1 2.0 0.40 ug/L 11/05/2020 2038 Chloroform ND 1 1.0 0.40 ug/L 11/05/2020 2038 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 11/05/2020 2038 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 11/05/2020 2038 Dibromochloromethane ND 1 1.0 0.40 ug/L 11/05/2020 2038 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 11/05/2020 2038 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 11/05/2020 2038 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 11/05/2020 2038 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 11/05/2020 2038 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 11/05/2020 2038 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 11/05/2020 2038 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 11/05/2020 2038 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 11/05/2020 2038 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 11/05/2020 2038 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 11/05/2020 2038 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 11/05/2020 2038 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 11/05/2020 2038 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 11/05/2020 2038 Ethylbenzene ND 1 1.0 0.40 ug/L 11/05/2020 2038 2-Hexanone ND 1 10 2.0 ug/L 11/05/2020 2038 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 11/05/2020 2038 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 11/05/2020 2038 Methylene chloride ND 1 1.0 0.40 ug/L 11/05/2020 2038 Styrene ND 1 1.0 0.41 ug/L 11/05/2020 2038 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 11/05/2020 2038 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 11/05/2020 2038 Tetrachloroethene ND 1 1.0 0.40 ug/L 11/05/2020 2038 Toluene ND 1 1.0 0.40 ug/L 11/05/2020 2038 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 11/05/2020 2038 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 11/05/2020 2038 Trichloroethene ND 1 1.0 0.40 ug/L 11/05/2020 2038 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 11/05/2020 2038 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 11/05/2020 2038 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 31 of 63 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ72479-001 Matrix: Aqueous Batch: 72479 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 11/05/2020 2038 Vinyl chloride ND 1 1.0 0.40 ug/L 11/05/2020 2038 Xylenes (total) ND 1 1.0 0.40 ug/L 11/05/2020 2038 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 99 70-130 1,2-Dichloroethane-d4 93 70-130 Toluene-d8 96 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 32 of 63 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ72479-002 Matrix: Aqueous Batch: 72479 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 140 1 135 60-140 11/05/2020 1938 Acrylonitrile 100 110 1 114 70-130 11/05/2020 1938 Benzene 50 45 1 90 70-130 11/05/2020 1938 Bromochloromethane 50 47 1 94 70-130 11/05/2020 1938 Bromodichloromethane 50 46 1 91 70-130 11/05/2020 1938 Bromoform 50 43 1 86 70-130 11/05/2020 1938 Bromomethane (Methyl bromide) 50 51 1 101 70-130 11/05/2020 1938 2-Butanone (MEK) 100 100 1 102 70-130 11/05/2020 1938 Carbon disulfide 50 45 1 90 70-130 11/05/2020 1938 Carbon tetrachloride 50 49 1 97 70-130 11/05/2020 1938 Chlorobenzene 50 48 1 96 70-130 11/05/2020 1938 Chloroethane 50 48 1 96 70-130 11/05/2020 1938 Chloroform 50 46 1 92 70-130 11/05/2020 1938 Chloromethane (Methyl chloride) 50 59 1 118 60-140 11/05/2020 1938 1,2-Dibromo-3-chloropropane (DBCP) 50 42 1 85 70-130 11/05/2020 1938 Dibromochloromethane 50 46 1 92 70-130 11/05/2020 1938 1,2-Dibromoethane (EDB) 50 48 1 96 70-130 11/05/2020 1938 Dibromomethane (Methylene bromide) 50 48 1 95 70-130 11/05/2020 1938 trans- 1,4-Dichloro-2-butene 50 42 1 84 70-130 11/05/2020 1938 1,2-Dichlorobenzene 50 47 1 93 70-130 11/05/2020 1938 1,4-Dichlorobenzene 50 47 1 95 70-130 11/05/2020 1938 1,1-Dichloroethane 50 46 1 92 70-130 11/05/2020 1938 1,2-Dichloroethane 50 47 1 95 70-130 11/05/2020 1938 1,1-Dichloroethene 50 44 1 88 70-130 11/05/2020 1938 cis- 1,2-Dichloroethene 50 46 1 93 70-130 11/05/2020 1938 trans- 1,2-Dichloroethene 50 46 1 91 70-130 11/05/2020 1938 1,2-Dichloropropane 50 48 1 96 70-130 11/05/2020 1938 cis- 1,3-Dichloropropene 50 47 1 94 70-130 11/05/2020 1938 trans- 1,3-Dichloropropene 50 49 1 98 70-130 11/05/2020 1938 Ethylbenzene 50 48 1 96 70-130 11/05/2020 1938 2-Hexanone 100 100 1 101 70-130 11/05/2020 1938 Methyl iodide (lodomethane) 50 46 1 93 70-130 11/05/2020 1938 4-Methyl-2-pentanone 100 100 1 103 70-130 11/05/2020 1938 Methylene chloride 50 45 1 90 70-130 11/05/2020 1938 Styrene 50 48 1 96 70-130 11/05/2020 1938 1,1,1,2-Tetrachloroethane 50 49 1 98 70-130 11/05/2020 1938 1,1,2,2-Tetrachloroethane 50 52 1 103 70-130 11/05/2020 1938 Tetrachloroethene 50 48 1 96 70-130 11/05/2020 1938 Toluene 50 48 1 96 70-130 11/05/2020 1938 1,1,1-Trichloroethane 50 45 1 90 70-130 11/05/2020 1938 1,1,2-Trichloroethane 50 49 1 98 70-130 11/05/2020 1938 Trichloroethene 50 45 1 89 70-130 11/05/2020 1938 Trichlorofluoromethane 50 51 1 102 70-130 11/05/2020 1938 1,2,3-Trichloropropane 50 47 1 95 70-130 11/05/2020 1938 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 33 of 63 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ72479-002 Matrix: Aqueous Batch: 72479 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 48 1 96 60-140 11/05/2020 1938 Vinyl chloride 50 53 1 106 70-130 11/05/2020 1938 Xylenes (total) 100 98 1 98 70-130 11/05/2020 1938 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 88 70-130 1,2-Dichloroethane-d4 84 70-130 Toluene-d8 91 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 34 of 63 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ72536-001 Matrix: Aqueous Batch: 72536 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 11/06/2020 1014 Acrylonitrile ND 1 20 0.80 ug/L 11/06/2020 1014 Benzene ND 1 1.0 0.40 ug/L 11/06/2020 1014 Bromochloromethane ND 1 1.0 0.40 ug/L 11/06/2020 1014 Bromodichloromethane ND 1 1.0 0.40 ug/L 11/06/2020 1014 Bromoform ND 1 1.0 0.40 ug/L 11/06/2020 1014 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 11/06/2020 1014 2-Butanone (MEK) ND 1 10 2.0 ug/L 11/06/2020 1014 Carbon disulfide ND 1 1.0 0.40 ug/L 11/06/2020 1014 Carbon tetrachloride ND 1 1.0 0.40 ug/L 11/06/2020 1014 Chlorobenzene ND 1 1.0 0.40 ug/L 11/06/2020 1014 Chloroethane ND 1 2.0 0.40 ug/L 11/06/2020 1014 Chloroform ND 1 1.0 0.40 ug/L 11/06/2020 1014 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 11/06/2020 1014 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 11/06/2020 1014 Dibromochloromethane ND 1 1.0 0.40 ug/L 11/06/2020 1014 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 11/06/2020 1014 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 11/06/2020 1014 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 11/06/2020 1014 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 11/06/2020 1014 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 11/06/2020 1014 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 11/06/2020 1014 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 11/06/2020 1014 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 11/06/2020 1014 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 11/06/2020 1014 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 11/06/2020 1014 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 11/06/2020 1014 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 11/06/2020 1014 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 11/06/2020 1014 Ethylbenzene ND 1 1.0 0.40 ug/L 11/06/2020 1014 2-Hexanone ND 1 10 2.0 ug/L 11/06/2020 1014 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 11/06/2020 1014 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 11/06/2020 1014 Methylene chloride ND 1 1.0 0.40 ug/L 11/06/2020 1014 Styrene ND 1 1.0 0.41 ug/L 11/06/2020 1014 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 11/06/2020 1014 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 11/06/2020 1014 Tetrachloroethene ND 1 1.0 0.40 ug/L 11/06/2020 1014 Toluene ND 1 1.0 0.40 ug/L 11/06/2020 1014 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 11/06/2020 1014 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 11/06/2020 1014 Trichloroethene ND 1 1.0 0.40 ug/L 11/06/2020 1014 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 11/06/2020 1014 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 11/06/2020 1014 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 35 of 63 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ72536-001 Matrix: Aqueous Batch: 72536 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 11/06/2020 1014 Vinyl chloride ND 1 1.0 0.40 ug/L 11/06/2020 1014 Xylenes (total) ND 1 1.0 0.40 ug/L 11/06/2020 1014 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 100 70-130 1,2-Dichloroethane-d4 94 70-130 Toluene-d8 94 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 36 of 63 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ72536-002 Matrix: Aqueous Batch: 72536 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 160 N 1 160 60-140 11/06/2020 0907 Acrylonitrile 100 120 1 125 70-130 11/06/2020 0907 Benzene 50 42 1 84 70-130 11/06/2020 0907 Bromochloromethane 50 47 1 93 70-130 11/06/2020 0907 Bromodichloromethane 50 43 1 86 70-130 11/06/2020 0907 Bromoform 50 45 1 89 70-130 11/06/2020 0907 Bromomethane (Methyl bromide) 50 47 1 95 70-130 11/06/2020 0907 2-Butanone (MEK) 100 110 1 110 70-130 11/06/2020 0907 Carbon disulfide 50 44 1 87 70-130 11/06/2020 0907 Carbon tetrachloride 50 49 1 97 70-130 11/06/2020 0907 Chlorobenzene 50 44 1 89 70-130 11/06/2020 0907 Chloroethane 50 46 1 92 70-130 11/06/2020 0907 Chloroform 50 43 1 87 70-130 11/06/2020 0907 Chloromethane (Methyl chloride) 50 57 1 114 60-140 11/06/2020 0907 1,2-Dibromo-3-chloropropane (DBCP) 50 43 1 87 70-130 11/06/2020 0907 Dibromochloromethane 50 45 1 91 70-130 11/06/2020 0907 1,2-Dibromoethane (EDB) 50 47 1 94 70-130 11/06/2020 0907 Dibromomethane (Methylene bromide) 50 45 1 90 70-130 11/06/2020 0907 trans- 1,4-Dichloro-2-butene 50 43 1 86 70-130 11/06/2020 0907 1,2-Dichlorobenzene 50 44 1 87 70-130 11/06/2020 0907 1,4-Dichlorobenzene 50 47 1 93 70-130 11/06/2020 0907 1,1-Dichloroethane 50 44 1 89 70-130 11/06/2020 0907 1,2-Dichloroethane 50 44 1 88 70-130 11/06/2020 0907 1,1-Dichloroethene 50 43 1 86 70-130 11/06/2020 0907 cis- 1,2-Dichloroethene 50 44 1 89 70-130 11/06/2020 0907 trans- 1,2-Dichloroethene 50 44 1 88 70-130 11/06/2020 0907 1,2-Dichloropropane 50 45 1 90 70-130 11/06/2020 0907 cis- 1,3-Dichloropropene 50 45 1 90 70-130 11/06/2020 0907 trans- 1,3-Dichloropropene 50 46 1 92 70-130 11/06/2020 0907 Ethylbenzene 50 44 1 89 70-130 11/06/2020 0907 2-Hexanone 100 100 1 100 70-130 11/06/2020 0907 Methyl iodide (lodomethane) 50 44 1 88 70-130 11/06/2020 0907 4-Methyl-2-pentanone 100 110 1 106 70-130 11/06/2020 0907 Methylene chloride 50 43 1 85 70-130 11/06/2020 0907 Styrene 50 45 1 90 70-130 11/06/2020 0907 1,1,1,2-Tetrachloroethane 50 47 1 95 70-130 11/06/2020 0907 1,1,2,2-Tetrachloroethane 50 51 1 103 70-130 11/06/2020 0907 Tetrachloroethene 50 46 1 92 70-130 11/06/2020 0907 Toluene 50 43 1 85 70-130 11/06/2020 0907 1,1,1-Trichloroethane 50 44 1 88 70-130 11/06/2020 0907 1,1,2-Trichloroethane 50 46 1 92 70-130 11/06/2020 0907 Trichloroethene 50 41 1 81 70-130 11/06/2020 0907 Trichlorofluoromethane 50 50 1 101 70-130 11/06/2020 0907 1,2,3-Trichloropropane 50 48 1 95 70-130 11/06/2020 0907 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 37 of 63 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ72536-002 Matrix: Aqueous Batch: 72536 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 49 1 98 60-140 11/06/2020 0907 Vinyl chloride 50 50 1 100 70-130 11/06/2020 0907 Xylenes (total) 100 91 1 91 70-130 11/06/2020 0907 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 88 70-130 1,2-Dichloroethane-d4 87 70-130 Toluene-d8 88 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 38 of 63 ICP-MS Metals - MB Sample ID: VQ71608-001 Matrix: Aqueous Batch: 71608 Prep Method: 3005A Analytical Method: 6020B Prep Date: 11/04/2020 1121 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 11/04/2020 2232 Arsenic ND 1 2.0 1.3 ug/L 11/04/2020 2232 Barium ND 1 5.0 1.3 ug/L 11/04/2020 2232 Beryllium ND 1 0.40 0.15 ug/L 11/04/2020 2232 Cadmium ND 1 0.50 0.13 ug/L 11/04/2020 2232 Chromium ND 1 5.0 1.3 ug/L 11/04/2020 2232 Cobalt ND 1 5.0 1.3 ug/L 11/04/2020 2232 Copper ND 1 5.0 1.3 ug/L 11/04/2020 2232 Lead ND 1 1.0 0.25 ug/L 11/04/2020 2232 Nickel ND 1 5.0 1.3 ug/L 11/04/2020 2232 Selenium ND 1 5.0 1.3 ug/L 11/04/2020 2232 Silver ND 1 1.0 0.25 ug/L 11/04/2020 2232 Thallium ND 1 0.50 0.15 ug/L 11/04/2020 2232 Vanadium ND 1 5.0 2.5 ug/L 11/04/2020 2232 Zinc ND 1 10 2.5 ug/L 11/04/2020 2232 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 39 of 63 ICP-MS Metals - LCS Sample ID: VQ71608-002 Matrix: Aqueous Batch: 71608 Prep Method: 3005A Analytical Method: 6020B Prep Date: 11/04/2020 1121 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 100 1 103 80-120 11/04/2020 2239 Arsenic 100 100 1 101 80-120 11/04/2020 2239 Barium 100 95 1 95 80-120 11/04/2020 2239 Beryllium 100 100 1 104 80-120 11/04/2020 2239 Cadmium 100 98 1 98 80-120 11/04/2020 2239 Chromium 100 110 1 109 80-120 11/04/2020 2239 Cobalt 100 110 1 110 80-120 11/04/2020 2239 Copper 100 110 1 110 80-120 11/04/2020 2239 Lead 100 100 1 105 80-120 11/04/2020 2239 Nickel 100 110 1 108 80-120 11/04/2020 2239 Selenium 100 88 1 88 80-120 11/04/2020 2239 Silver 100 110 1 106 80-120 11/04/2020 2239 Thallium 100 110 1 109 80-120 11/04/2020 2239 Vanadium 100 110 1 107 80-120 11/04/2020 2239 Zinc 100 97 1 97 80-120 11/04/2020 2239 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 40 of 63 ICP-MS Metals - MB Sample ID: VQ72194-001 Matrix: Aqueous Batch: 72194 Prep Method: 3005A Analytical Method: 6020B Prep Date: 11/05/2020 1021 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 11/06/2020 0936 Arsenic ND 1 2.0 1.3 ug/L 11/06/2020 0936 Barium ND 1 5.0 1.3 ug/L 11/06/2020 0936 Beryllium ND 1 0.40 0.15 ug/L 11/06/2020 0936 Cadmium ND 1 0.50 0.13 ug/L 11/06/2020 0936 Chromium ND 1 5.0 1.3 ug/L 11/06/2020 0936 Cobalt ND 1 5.0 1.3 ug/L 11/06/2020 0936 Copper ND 1 5.0 1.3 ug/L 11/06/2020 0936 Lead ND 1 1.0 0.25 ug/L 11/06/2020 0936 Nickel ND 1 5.0 1.3 ug/L 11/06/2020 0936 Selenium ND 1 5.0 1.3 ug/L 11/06/2020 0936 Silver ND 1 1.0 0.25 ug/L 11/06/2020 0936 Thallium ND 1 0.50 0.15 ug/L 11/06/2020 0936 Vanadium ND 1 5.0 2.5 ug/L 11/06/2020 0936 Zinc ND 1 10 2.5 ug/L 11/06/2020 0936 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 41 of 63 ICP-MS Metals - LCS Sample ID: VQ72194-002 Matrix: Aqueous Batch: 72194 Prep Method: 3005A Analytical Method: 6020B Prep Date: 11/05/2020 1021 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 100 1 104 80-120 11/06/2020 0942 Arsenic 100 100 1 100 80-120 11/06/2020 0942 Barium 100 100 1 102 80-120 11/06/2020 0942 Beryllium 100 100 1 101 80-120 11/06/2020 0942 Cadmium 100 99 1 99 80-120 11/06/2020 0942 Chromium 100 100 1 102 80-120 11/06/2020 0942 Cobalt 100 99 1 99 80-120 11/06/2020 0942 Copper 100 100 1 100 80-120 11/06/2020 0942 Lead 100 99 1 99 80-120 11/06/2020 0942 Nickel 100 100 1 100 80-120 11/06/2020 0942 Selenium 100 94 1 94 80-120 11/06/2020 0942 Silver 100 100 1 101 80-120 11/06/2020 0942 Thallium 100 98 1 98 80-120 11/06/2020 0942 Vanadium 100 97 1 97 80-120 11/06/2020 0942 Zinc 100 95 1 95 80-120 11/06/2020 0942 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 42 of 63 ICP-MS Metals - MS Sample ID: VJ29002-005MS Matrix: Aqueous Batch: 72194 Prep Method: 3005A Analytical Method: 6020B Prep Date: 11/05/2020 1021 Sample Spike Amount Amount Result % Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony ND 100 110 1 106 70-130 11/06/2020 0954 Arsenic ND 100 100 1 103 70-130 11/06/2020 0954 Barium 190 100 290 1 101 70-130 11/06/2020 0954 Beryllium ND 100 96 1 96 70-130 11/06/2020 0954 Cadmium ND 100 100 1 100 70-130 11/06/2020 0954 Chromium 2.4 100 100 1 99 70-130 11/06/2020 0954 Cobalt 94 100 190 1 91 70-130 11/06/2020 0954 Copper 1.9 100 110 1 103 70-130 11/06/2020 0954 Lead ND 100 86 1 86 70-130 11/06/2020 0954 Nickel 24 100 120 1 94 70-130 11/06/2020 0954 Selenium ND 100 100 1 102 70-130 11/06/2020 0954 Silver ND 100 99 1 99 70-130 11/06/2020 0954 Thallium ND 100 86 1 86 70-130 11/06/2020 0954 Vanadium ND 100 97 1 97 70-130 11/06/2020 0954 Zinc 6.5 100 100 1 97 70-130 11/06/2020 0954 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 43 of 63 ICP-MS Metals - MSD Sample ID: VJ29002-005MD Matrix: Aqueous Batch: 72194 Prep Method: 3005A Analytical Method: 6020B Prep Date: 11/05/2020 1021 Sample Spike Amount Amount Result % Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Antimony ND 100 100 1 103 2.9 70-130 20 11/06/2020 0959 Arsenic ND 100 100 1 102 0.88 70-130 20 11/06/2020 0959 Barium 190 100 280 1 93 2.9 70-130 20 11/06/2020 0959 Beryllium ND 100 92 1 92 4.0 70-130 20 11/06/2020 0959 Cadmium ND 100 100 1 101 0.69 70-130 20 11/06/2020 0959 Chromium 2.4 100 100 1 98 0.20 70-130 20 11/06/2020 0959 Cobalt 94 100 180 1 90 0.49 70-130 20 11/06/2020 0959 Copper 1.9 100 99 1 97 6.5 70-130 20 11/06/2020 0959 Lead ND 100 94 1 94 9.0 70-130 20 11/06/2020 0959 Nickel 24 100 120 1 94 0.085 70-130 20 11/06/2020 0959 Selenium ND 100 97 1 97 5.0 70-130 20 11/06/2020 0959 Silver ND 100 98 1 98 1.4 70-130 20 11/06/2020 0959 Thallium ND 100 94 1 94 9.0 70-130 20 11/06/2020 0959 Vanadium ND 100 99 1 99 1.6 70-130 20 11/06/2020 0959 Zinc 6.5 100 100 1 95 1.4 70-130 20 11/06/2020 0959 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 44 of 63 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 45 of 63 CD > CD -0 0 0 CD 0 CD CD 0 E 3 CD 0 CD M -4 < 0 3 C:, CD w co cj) t CD CD R. 4 0 co CD -n PACE ANALYTICAL SERVICES, LLC I OF5 Varitago =Olnl IDMM , Wast COI�Mbla, S� 29172 telephone Nm N0-791 -9700 Fax W. BM-791 - DI 11 VUWW-PaCeAa6a. U-017 Number 1-123.53 A&'rq5v citu Sffm,14.lrat S�TMrfjn? Pmm7d -my.o Ainil"k5 OMM.W.'(rmrk* spato is rlffd%cY) VJ29002 U:,0 Z- pwsi�ieis )or ia-N anAg mWbi mniwd Q.1 gn irN,� Ca%nK'm C�CrAr. 71'1- O:NeI�} 'r,6}'�,}:I i; p'. x 1' `'�. TtoMAjwncfT2ffid MxMo Hazm inarfAmkri UG HaluffiTare P>wljry) D &andind E: alr3hfGp9crM 0 RMw. k MM C' Devaidbytsb ---lron-FLurd FIFLnmu�E A.CrL lrrLETI ".r'ol.c:on _Drjmawei I j%" i 4-db Dag& 17a ILL 2. Ripffn by LL�Jlll�;tz�iyj 1711 -349 * flobil� 4h-d by DAMf Tno * 9vjynq& D few rpt &M nAihe. z kpXerml by 'rhe LLek T"10 TOW a Pscefy.31 j7y ELM 4. Lffl&reW? by 04--dA 'uq 5,3 4AH UM CWLle Na fiM~k T1.1ro M13k ll-F' 1. 1 M WS.—M&LOWLIN.- M-MrE & YELLOV,4?rdwo M 47LWArMy wAh SaMpW(5;;j PlfVK-FW*CALrnr Copi - rkKvmpnt M=L)oF. MEDM%L2 01 W PACE ANALYTICAL SERVICES, LLC Sampres RQCeiPt cherklrst (SRCJ [rviEf1Qi8r-7 } - � I lssuirrg Authority: Pw;e CNV - Y+= L Sample Receipt Checklist (C) C licnr: �� s lcr [nspccted 1 }relate: dos..' Revised:91�9I2E]2E] T z -- oP Pagc 1 Of Means ofrecAmily Ld Facc. LJOjent Ll UPS Fsx�x fter: �g�r4lQ Ycs o l W+ a—:cus_odySe is 2re3entOnttleCoo ktl' Yes [:[No i_ If c Usto6y SGals WC.-C TeSelir.'NeJ+e dley inulctan� uribrok&n? �Fi SirJp 1D: ��'!' $iS Cltlorine 1rp !1); _ ]'mmd'oy: 0 inal remperatum upon eCeipt r' iv {correcte ) Tenrper�JEy'pt�ure upon receipt %9arid Snap -Flip 10: .. 4 rF% � 1r� ¢4 � + rT c Met: br_- [ 'cn1�7�]�tllrL' irli. ¢dEl14t T�11lIIL'S IR CTr_n ]1 ' _ IR (gun C'orrcr:tian Ftctor �t NkI.13M, r,fUiiilart: FR'WPt lce LJIrwjlavh ❑ Dry lcc ❑ 'None �3. Ym EINU Z�%A IftcniWanlre A- Any e'rolrrcr: rAad 6.0'C. was. Pr jrrc:L rMwiager Nctiflec? E3J4il vva.9 Notified hy: phone r emait/face-€o-face (circru anc), Yes Flo n , A- 4, Is the coin"m ial -=, u riar'.5 pan king slip vmchad to ]tie form? Yes s 7 N:a S. W-c grope: custody rocedw-es (rel inquishederm ivcd) followed? 6, [W= :ample ILls listed ors IFe COM es ❑No 7, Wore satnple 1I7s listed err all sum .ccorrminers'2 Yam,LJ too S. Was collection date 4 tuns listed oil tLe COC? No 9, Was coJlect�ui date & time listed on all sainplecQntaln"rs? Y ❑ No 10_ Did all corim-'roF [libel information (ID, date, rime) aur.rwit.,--1W COC. declt io be }*eltorxnad listed on the CO ? 12- Did ail sainpJ s arrive io I= propu eantatner€ for eavh I -an and.IoT in;ood c,on li[itu (unbroken, . ds drk, otc,P 13. Was aa18r1ualr rumple volume available? - K Wm all samples rece'ved'Withirt �ls th%u hording tirrc or 49 hours, whichever conns first'? 'Y I NoWere .Lq ❑ No _ Y es' U No esiLj -No El Yes 7J0 15. Wife airy sarnplr s co-itnincrs misstnVexcess (6-zly and) smyples Not lisA orr COC) Per VOA and RSK-175 samples, wcm bubb]as preserrl %'rice -size' (/.'4r 6mm in diameter.) in any of the VQ_+t Vials? El1.6. Ycs [aN. es No NA J7, W= all JItL7ftnetslslnutr-ent P.am les received at a phi of < 2? Yes Nu A A. Wcrc zJI cyanide samples r,ecel-md at a pH > 12 ar;d sulrirlr sas-lrlr_� rnN_ .iyM aka 11 :# 9` :9, Were applicable7tiH3.TICK/f anidr,'ph=oV62�.IiOS.3 (< 0_5-rLg&) csroples ree of residml chlorine's El� o El Yes ❑-Ko E?fiA 20_ Were c1jz t[ remurk&ircquesis (i.e. requested dilutions, MS. NJSD designations, etc_) core ect:y fraascffaod From the COC: into the cprnrn,. t scttion irL UMS? 'e ltie} 21_ Vas ff rpiore. nu_nber listed on the container label? Lf yes, Qubr,e 4 &smple Hr&SPI'Vation (MLISL be fiompletcd for any sampJe(s) Erermectiy prescr ved or with headspace.) Sarn?le(s) ►JN .. wort, r=h-cd inoarrartip preservt�d arrd adjed risaa�cmdirrsgly I in sample receiving wit? _E±A_ mL ofcircla one, H2504, HNO3, HCL' sI NaOII ur SR 4 irrte nfpresm-&ion __t1.K TfuIQI-49 Ilia Um- preservA tve is needed, �Lemsr. ncte in the cominents beloty, I Samplo(s) rJ -- -- wom received with bubbles>6 mm in dinneter. amples(5) -- _ were mceivec wit TRC > 0.5 :r i L (1 C Ahl -Lv Is 1i0 )and wmm dusted aGoordingiy in samp:w VeCeiVin�_ With sodium thiosrl.fate (Na35c ;) wilh Shealy 117: R barcode laba]s al plietl by: as Dote; ` --- Comments: Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 47 of 63 �0 <CD �> ;v v CD C - 0 0 0 C m v� o co N �r m n 0 O O C CD Q' N CD V1 � n d �m V <, N 0 7 W CD o= V � cCD 4 V O W oN b -n O w v 4 co 0o w O V M O a1 � W � 0 E3 ac nalyt cal x LT-- fi��[148 �-gw�u.Nsrna Fxyecr lW�. Sv,r.'e iUlaczv�laf0�'f pGa rx�,air xmtar mob' `�° c-�rr�d.'nedan Ara 4m; PACE ANALYTICAL SERVICES, LL 7pEi'darrtaqv Poird Drive • West Galurnbli�, SC 29172 :4-'$prDne 1drr01) Fax No. $02-791-3111 ►r kvwplaml1 i�com �� }$i7ipJH'�3 ry.'uu Plumber I'12 r&PANa•rr rya. ,•e,r a,rlysrs �J.ngrfi Ct•:P,Tnaa � isneecR'! Drir-l-nI Nam 4 I Q. W. A li{F rfl �- VI nr R;+Pmuff tl61'$9 iyW ygy� CUY hly- {4�T��J b 17wk, UTI Tmnr Arourro' ?Ino 4a�t4m {FrWYli aPP ►a� �d fur Y�gpecifad AITI �+4re D .eaP r 3taod4rd Li h l�pM115') n y7eMrr io G9�x pf %-E 1. Rr rasdbk Do�B TVW rcl :4 r I r +�r� ro7a - q 7kw �idfq r . 4, P,�f,r,,uished by JtiW! `All sarrrpfe9 are WakAll OF fOL T wbuks from rr3 OOr unress vfffer arTar+gprrinrs are r - OlSFfil6LrP•i -RiYTE d YR J n A-RE.&-q 0 1Pb -ajey w0b F rgxW PWK•Fl,.0 C7h'erPt Geyr3Y ire M, 4j Irrk.Vy,1,�yIIy-,r -- �un7'�Iyj�yyj�,�IyI Ph149f6�C Ffr�&IPA A7aif�t$h'a� ryG .45gYifrs�,fs {3,paa+�•J �1.v7 : Hon•FB�rd '7 Rauur;�Wa ti 3kih 3dl�llk - I'o':on ��Il mnau �,giwao s Uses rrra 4. L�16'n'Aro!}`r�'a•`+cq � � f ''7-ki f7$f I+ — NLY �• T-- �hyrik 1-1 ,IV � J ,qe rigrlrm io6 ;C�'r�ie1 ea Ay C"a Fa[4 Ra:PSb1TOHgP C47iC':R'n5f.'! i 4al'rbP': MEUMNO-Of PACE ANALYTICAL SERVICES, LLC Samples vpretpt Clteddist (SRC) (MEOOLBC 15) 4evlsed:9f 29J?.D70 Issuing Authority: Pac_ ENV - WCOL Page n= t ampic Remipt Checklist (SRC:) client. 13LL Cooler in eoted bylda ; kSC f 1-IM020 Lul �: V]29002 [deans of recei t; E 11acc licni El UPS LFcdFac U 01bar: .LJyCN1 IZIN01 I - Were cus!Lody seals preseiiit an the coo-ler? iiLlyesiNo I , NA 11f cusWdy YC f.'Is wcru prcwut, wcm dLev !rki.a i. n:id Ljubrt3keii? pi 5Trip ID. 1031135-- ------Chlori:ise Strip ID: AA Tcmd by, KRs OfiBitial temperalwe upon receipt ; Derie53 (Oarvecred) temperature upon receipt %Solid Suap-Ctrp ID-. NA :3 f2,9 cc NA jNA aC NA jNA oC NA f NA oC P+lcthod: J11-cnl:crzw�re 31ank Mkgninn lades IR Gun ID: f lR Gun Co=LioCL Fa,:wr,, 0 QC Meahvd of cnnlanf: lF...l Wnt Ic.n ❑ icn ?w*R ❑ Dry Ice ❑ Norm ❑ Yet ❑ �Var [Z]NA3. 1 f it mpernturn o f auy cooler exeeerled 6.0°C, was Project Ma later Notified? Wbl +saU NOtiF1ed by: :3hnn: i crn'ail ! lattrLY3-lace {circle Oft). yua No J }JA 4. Is L33e wnLen:rciELL L:UuriCT`S pauking s3ip atmwhed to this :CAMEL? YL.6 No 5. Were p-oper custody yrocedures (relinquisliedrreceived) fnlloured? J Vc5l No 6. Wero sarnplc ID,. Ii:gi&d tm Lko COC? J Yes F]No 11 Wure sdrnitlt 1Ds IisutLdim J1 NLurip It! LoLlaiut!m? Yc; =No 6- Was colle�don date &. time listed on the DOC? ❑,� Ye., N�, 9. Wa,- callecdon date: &. Litne lisped oiis all ssmple containers? 7 Yc3 .. No 16. Did all c auttaffier la'oel into -nation (ID, date, tim6} agm with the COC? E Ye.; Ll No I _, Were te= to be perfonr_ed listed on the CDC? Yes! ❑J Yes ❑No 12 l7id all gnmpIc% mriva in t4r limper containems for carlh wnT sLndicr :r. -nod annditkia (LrLbJtaUlr :iJM Lau, l3, 14a€ adequate sample volume available? EI Yets No 114. Wcrc all sanu Ica reed yed within', like lrolding time ar 48 hours_ whichevcr cOfncs first? Yes ,' No 11. Wnre any saropJes t,omain errs m'A-PLejsxr�ss (ckle one) 5amplM5 Not ligwj on CDCry Yes ❑ Na ❑ 16. For VOA endRSi 175 :4mple�, WUM ut;bbleN prescn`>L*ft-sire"(r/,�'o: Gmt3t in Cli treter) in any of the VOA Vic Is? Yes Na L_JNA 17. Wcra nil 13ROhneta:s/uurFizn1 samples received at a plI of -� 27 Y No J NA 18. Were all cyai k-Ee sa_nples r,%ei veml at a pIf > 12 2! d sulfide at a pH > 9? ❑Yes ❑TIo ❑J NA 19. 1,re all applicable Nl Ia,riKN', yanid&'piieiw 62S_ I ?60R__r (< b_fm&d.) tramples tree r residuol -chlorin? ❑ Y" ❑N20. Wrro JienL rL• .arlctii requtntcL (i.t_ ruqueM(N] dil--tiwn, MS.'. 9D Llusigtlal-iony, VAL!...1 corrcutly tram-rrJbod from lh:. a intDthe comm rxsere#ion in I. lsf H❑N ii-V Z 1. 1y ns the quote niaiiber liskrd on ne cmitalnm labor! 1i-yes, QLiate it ------ ci9mple >Prcscrva#ion (h4ust be complet-W for ary samplc(s) incorrectly preserved or with headspacc,) S=ple(3).NA we3e ii-ce: ved ikkcptre;.-t1y preserved grid weadjusued acccmdbiSly in simple awoMLig with NA _mL of circle ane: 112SO4,14NO3, HC'I'. NaOI-1 usiarg Sit ,'k �3A Time of preservation - . _—.-. - -... If inore-thenone preservatiue is heeded, note in Like mau)ts Ualow. ample(;) NA *yd'w tcctiwd .aids bubbkes >6 r4tA ir, dip-Metcr_ arrLplw(sj t wcm rumivcd widt TI(C > U,5 ukWL (Lf 41'? is rtu) and wcrc djastcdaccordingly insample receivm with midimnthiosulfate (Na;SYI}.) wAh SFealy lD, NA >Z bpi .ode. Ialxls applied by: KB$ lzte: t i�_rxl[zu CATnp =C,i T,5 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 49 of 63 �0 <CD �> ;v v C CD vv o' fn CD v� o CD N � r r m n 0 o C 3 c m O— �CD n d G m V <, N 0 W N O a co fn t CD CDz -4 C) CD N -n N n X � co O w V O CO ro 0 E3 ip PACE ANALYTICAL SERVICES, PLC U 106 VanU3p PCim Drive • .Nest lunnbla, SG 29172 ier of fif Telephone Nn. 800-7'D1 •9700 Fax Ho, 8U5 Y9� 111 wNv-W_paoelabs-oam GTenr ,YP�o-xrra G'andaof pw'den Name ,gdrt,+�g9 � �'$17�"iar� $u}rsrh,ier --F I#I 4lLYdines � r' pr�,e wf Praia�ra Tnx C3; (ribJl�•H�d fPran ,sr'�larrayb :rnrb. dw�9i�`Lt�F rbfdfW) jr+A"'j' �- Il ium Ilr+wrni TDr� Re�u t�Ncrldapples' l2q�rt+a �ura�ifad RIT)I swfpmrd C] flush ($peelry} i. n,ii;Wc by + 4. Rtrfii4ufe=7rei bJ,f�/� �.{� e. ,4a4MQW-d x}' 8em,4e pwpass' wxnt]m-qr �j R-Pa TLng Ion True Oj3M NOle= �h sq�lt�,fes ire ,re[q++te� 8'�r four weBkS from' race �l.#!#iss other arrarxrorr AMs Ere mad--- _ bJ�fh'S�1TTp4J: WNIJ� � YELZONtFPGm, �o �ataralOryrilih Sid�J: PhW{-. ier�+Y'�9nl;:�Wy Arury9i6 On-h k.J U 171R.r, Chi" 0 fW2a-'W 1 �ioG� hlp jO0 11�L� fda'r. ! LYVJ6V J.p. Pos�ln��xafa�Fde.'�i�ca6wM ... rj�.l7egv�8ia,TrorrJ..(:�as+alr}¢ F M(ngLwj d - HamrFM d Skin l91Mlrt - F lean L Uueaouen L hY6C6i•ne+C' by ..er g TDW 4 it dG$A+¢d VIfr} �&fP �71E f S.po*.rdby — Date� �!— a Laeur.+y'ra�ivalGby r� 7A7a s Utit iJNLY rerrai'dad rn +uv (C6c'e) R ko P" gereJ�r TeR{�. — Dmrnenr mim%a er_ r t:l-VJ rzLGr PACE ANALYTICAL SERVICES, LLC 5aMpla5 Reoelpt rhQsklist 15RC) ilu1E001=,1.5j Re4'See'9{29fK-70 /*;?e I55uIrip Autharity: pace ENV kkrC❑L PEgel of 1 t1 ple Reccipt CheckEst (SRC: Client: BLE f ogler luspra tL!dbyidate K&C f I117�30Q0 Lot ft. Means a'frnc=i�,t: rf P., t Jiort UF'5 ie Fx [ktlrer_ Yes I'10 I _ NYeru cXwtu1 seals present on the cooler? ides No -A 2, lF custadv �t�ls „ere eseni, were -hL irawt arc; u0mker_9 pit Strip LLB; M-^_'�S'3 ., Chlorine Strap Tf} r Tested by: ass Y Original =parature upon receipt' - M-rived (COrreet436) Lr,r�reraMf;, ulron raveipt ai6Solid snap Can L!]: �� 7 4 r 2.9 0C+ 1�IA r h A aC ' A f NA VA j-NA a[ l+ el-ii5d' aEMPLMawle I3l ink ❑� inxt sotthrs IR Gan Ia. _ IR G-an Cap; nr:t�on Fa=c-. � Method of coolant: Q Wet 1r•c 9 Ike Pace ❑ Dry Im ❑ Toone 3, If EN temperatum vC aay coo[e_ e�ceedcd Uff, was Projcot Manager Na#i1 LW? Q °^s ❑ ° RIN'4 Pwas Nuti.ihY1 Fed hone+ email iT71CL'-LaNCa0e (61-0d,QnO. �t-esi No d NAL 4. Is the WAunemk0 cftrier's parking slip attached to Lhis faun? .f y — No 5. Were prier cuswdy prrwr-d 5-es (HEM quislle&'rc=ived) f0llowod? r,r Yes I LJ No G. Wert sample Ids Ijsmd an the COC? y.p,q © N ?. Were ya,r,ple IDS Jistrcl orr all samplo omtainers'? _ Yes mjcr S- Was colleotior date 8c tirue iis#ed on kh CDC? - V yes No 9. as -A'MeLion date & time 1isled on at: sample eantNina,,,? 3re.�F1 Sul 110. Did a ] cantairser Laoal inrrirmatiou (ID, [late, =imc) a<gr_,e wll -J1e C•OC? 1✓IYes Na l l . 1Nera tCSts tO be perfbninud listed on the MC? — 12r Did al: samglm srrrive in 'fie prQper eontairrars fix ehcYf _ast andidf in good ctuidition 0 Yes ❑ No(unbrokM, lidr iri. ctc,)? Y�.s Li No 13. War; ado uax .alrtple. V01urae avaliah1'2? Y� J N0 14. Wm-e a:J saniplcs received wittrin !/ _11e haldiug dme or 43 hrlLEr%, wisicltcyrr cwoues lust" Yes No 15. Were any s:Empl,�s o0ntaintxs (circle aro) sate lea NO'. titled on COC? 15. For VOA auto ItSK 171 samples, ws bubbles pacsel�r >A`pea iixo" (,}+"01' t+r�n in diaiu) ❑Yes �No ❑ in any af$ic VQ.A 11als? Ye3 LJNo NA 17. ''ern all a.pHof C 7? Ycs Ho A N IA, i LTc ult cya_njdc sampleA recciv:d U 9k II > 12 and r;ulfide samples race'ved al n;,FI 9? 19.' 4srr. al� app1Ca aNH51-rK ioyaniktelpllreha ,1i6 63 0,6rrigrti sampkcs Irft of Yes ��� ❑NLA residua3 ehlonnO LEIN.Vr'= cii nt rvi=kthequosis (ix- mt quAnjLeil �1ilurion.s, kl9INISD d kgnati&ns, etc„- �'es Q a Q?Vti MNVdjy tr rV=ii3ad fi'UM the COO into 0- comment sr den in LI DS' r-I i'k�'q ,f NAl 12 1. 9Nas the quote numb-C Ilitod on the eonta:cer label? if w5 Quote 4 mp'Lp 1Preservmti0n (MMt be camPlcted iw any samp:C(S) incarrtCllw 13=ese7red ;ar with lieadspLCe,) mple(s) MA mare rkcuived inconw.l:-y primeryed un4 warn adjusted acmrdh9V HA sample receivinz with _ ml-, of {:hole ano, H2SO41. I-INC6, HG1, NaDH Using SK lr sa— r_Ee of preren�ation NA [f e,�nae t!tian onr ptes�rvative is needed, p:essc no a to #ha eart�menxs bel�,vr. rnple(s) N vtrere rnreived with bubbles �,b rem in diamet_r. rr. &s(s) NA r _ �xerc r ee tvod ►t th TRC � o 5 Jr_@/I. (If 914 is k�) And YID jwled aroardilrgiy in sample ;p ivin with s0diu n thi0sulfate iZs�a2.92D,) with Shealy Ia. — barc� labels applied by, Cannnonts; VVIE. t If2r2D2.0 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 51 of 63 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 November 05, 2020 Lucas Odom Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 RE: Project: VJ27049 Buncombe Co. Pace Project No.: 92503201 Dear Lucas Odom: Enclosed are the analytical results for sample(s) received by the laboratory on October 30, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville If you have any questions concerning this report, please feel free to contact me. Sincerely, Sara Coble sara.coble@pacelabs.com (704)875-9092 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 52 of 63 Page 1 of 12 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: VJ27049 Buncombe Co. Pace Project No.: 92503201 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 53 of 63 Page 2 of 12 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: VJ27049 Buncombe Co. 92503201 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92503201001 Leachate Pond SM 521OB-2011 JP1 1 PASI-A EPA 300.0 Rev 2.1 1993 BRJ 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A PASI-A = Pace Analytical Services -Asheville REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 12 Page 54 of 63 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: VJ27049 Buncombe Co. Pace Project No.: 92503201 Sample: Leachate Pond Lab ID: 92503201001 Collected: 10/30/20 12:15 Received: 10/30/20 16:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 5210B BOD, 5 day Analytical Method: SM 521OB-2011 Pace Analytical Services -Asheville BOD, 5 day 75.0 mg/L 2.0 1 10/31/20 05:29 11/05/20 02:46 B2 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Sulfate 3.9 mg/L 1.0 1 11/03/2013:46 14808-79-8 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate ND mg/L 0.040 1 10/31/20 00:03 14797-55-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2020 03:05 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 12 Page 55 of 63 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: VJ27049 Buncombe Co. Pace Project No.: 92503201 QC Batch: 577139 Analysis Method: SM 521 OB-2011 QC Batch Method: SM 521OB-2011 Analysis Description: 5210E BOD, 5 day Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92503201001 METHOD BLANK: 3054022 Associated Lab Samples: 92503201001 Parameter Units BOD, 5 day mg/L LABORATORY CONTROL SAMPLE: 3054023 Parameter Units BOD, 5 day mg/L SAMPLE DUPLICATE: 3054025 Parameter Units BOD, 5 day mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.0 11 /05/20 01:40 Spike LCS LCS % Rec Cone. Result % Rec Limits Qualifiers 198 215 109 84.6-115 92503084001 Dup Result Result RPD Qualifiers 61.2 59.4 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2020 03:05 PM without the written consent of Pace Analytical Services, LLC. Page 56 of 63 Page 5 of 12 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: VJ27049 Buncombe Co. Pace Project No.: 92503201 QC Batch: 577535 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92503201001 METHOD BLANK: 3055718 Associated Lab Samples: 92503201001 Parameter Units Sulfate mg/L LABORATORY CONTROL SAMPLE: 3055719 Parameter Units Sulfate mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 1.0 11 /03/20 13:15 Spike LCS LCS % Rec Cone. Result % Rec Limits Qualifiers 50 47.4 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3055720 3055721 MS MSD 92502990002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Conc. Result Result % Rec % Rec Limits RPD Qual Sulfate mg/L 62.6 50 50 101 101 77 76 90-110 1 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3055722 3055723 MS MSD 92503186006 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Sulfate mg/L 77100 50 50 118 114 81 74 90-110 3 M1 ug/L Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2020 03:05 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 12 Page 57 of 63 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: VJ27049 Buncombe Co. Pace Project No.: 92503201 QC Batch: 577128 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92503201001 METHOD BLANK: 3053984 Associated Lab Samples: 92503201001 Parameter Units Nitrogen, Nitrate mg/L LABORATORY CONTROL SAMPLE: 3053985 Parameter Units Nitrogen, Nitrate mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.040 10/30/20 23:55 Spike LCS LCS % Rec Cone. Result % Rec Limits Qualifiers 1.5 1.6 104 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3053986 3053987 MS MSD 92503201001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L ND 1.5 1.5 1.4 1.4 92 94 90-110 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2020 03:05 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 12 Page 58 of 63 Pace Analytical Services, LLC lac, Analyilcal ® 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALIFIERS Project: VJ27049 Buncombe Co. Pace Project No.: 92503201 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS B2 Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /05/2020 03:05 PM without the written consent of Pace Analytical Services, LLC. Page 59 of 63 Page 8 of 12 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: VJ27049 Buncombe Co. Pace Project No.: 92503201 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92503201001 Leachate Pond SM 5210B-2011 577139 SM 5210B-2011 577158 92503201001 Leachate Pond EPA 300.0 Rev 2.1 1993 577535 92503201001 Leachate Pond EPA 353.2 Rev 2.0 1993 577128 Date: 11/05/2020 03:05 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 60 of 63 Page 9 of 12 Document Name; Document Revised: October 28, 2020 Sample Condition Upon Recelpt(SCUR) Page 1 of 2 c?CBpI7r��ICB� Document No.: Issuing Authority: F-CAR-CS•033•Rev.07 Pace Carolinas Quality Office Laboratory re Whig sarnples: Greenwood ❑ Nuntersville ❑ Raleigh❑ Mechanicsville[] Atlanta❑` K``ernersviile❑ Asheville Eden❑ ConditionSample Clie Wok U me: UpoC ,/fvbl;rr�ect IICourier: []Fed Ex ❑Ckent❑UPS)Ak�,& ❑LISPS 1111111111111111111 111 ❑ Commercial Pace Other:— 92503201 ��� /// ��,,%% Custody Seal Present,* ❑Yes 1 10 Seals Intact? [:]YesLdNo � Examiningcontents:�^—�/l pate/InitlalsPerson r ��O • z� Bubble Bags one ❑ Other Packing Material: ❑Bubble Wrap [:]Bubbled Biological Tissue Frozen? ❑Yes ❑No 9N/A Thermomet r: r el ❑©lue PIRGu.10: �� [ 1 Type of ice: ❑Noce !( Correction Factor: Cooler Temp: 3' Add/Subtract ('C) �� Ternp should be above freezing to VC ❑sarnples out of temp criteria. Samples on ice, cooling process Cooler Temp Corrected U hasbegun USDA Regulated Soli ( NIA, water sample) Dld sampies orlglnate i a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples ariginare from a foreign source (internationally, Dyes ❑No (-]Yes ❑No — including Hawaii and Puerto Rico)? - - ---_.... ain of Custody Present? Samples Arrived within Hold Time? Short Hold Time Analysis 02 hr. Rush Turn Around Time Requestec Correct Containers Used? -Pace Containers Used? Containers Intact? Dissolved analysis: Samples Field Filtered? Sample Labels Match COC? -Includes Date/Time/ID/Analysis M Headspace in VOA Vials (>5-Gmm)? Trip Blank Present? Trio Blank Custody Seals Present? COMMENTS/SAMPLE DISCREPANCY 1. 2. o Lj N/A r6' ❑No INN/A[]No❑NIA es ❑No NIA 7. ❑Yes No ❑N/A S. �Kes Yu []NO ❑N/A 9• ❑Yes ❑Ycs ❑No []No N/A NIA 10. 11. nYes I1No 21N/A Field Data Required? ❑Yes 0. Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Date/Tlme: Pro)ett Manager SCURF Review; Date: Project Manager SRF Review: Date: Page 61 of 63 Document Name: Sample Condition Upon Recell ..f aCeAnalytlCBfy Document No,: F-CAR-CS-033-Rev.07 *Check mark top half of box if pH and/or clechlorination is verified and within the acceptance range for preservation samples, Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg "Bottom half of box Is to list number of bottles Do umertt Revised: October 28, 2020 t(SCURi Page 2 of 2 Issuing Authority: pace Carolinas Quality Office Project WQ# ; 925032Q1 Pm: SC Due Date: 11/06/20 CLIENT: 92-RaceSheal u Q fE x Z R a io 7 0. m i Z a 1 7 0. m Z Z a ro 7 a m v i to 0 0. m N x a 0 N x m E v a m ry V" m 6 Z a m n x of a 4 Z rc N a m x x 0 1b z m Eg U m m R 7 m v to E LL 4 Z 9°i m a a a rl 0 d N a _ x ¢ 2 N 0 d Z d a c E o ' M U' dFff a 0 z a a 0 N v x nT M l7 U Z z n E Q mE d +�1 L1 a CJE p > q I 91 z O N 4 O 0 F Of L) 7 2 n p 7 01 l7 } a rn m d 0n r d 01 U' A Q m N Q O 7 2 x a Y l7 7 i N n u m - E I+ IA r ro a p ion F- N N _a (TM JI m Ol N x Z U £EJ N0OYs"N 4 Q 7 V a c ] ra da•� l7 'S c o = w oEry� U 4 7 a c 0 40 l:J 8 9 10 11 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot p acIJusted added Note: Whenever there Is a discrepancy affecting North carol#na compliance samples, a copy of this form will be sent to the North Carolina DfHNR Certification Office (Le. out of hold, incorrect preservative, out of tomp, Incorrect containers. Page 62 of 63 FaceAnalytical' CHAIN -OF -CUSTODY 1 P nalytical Request Document The Chain -of -Custody is a LEGAL DOCUME T, All relevant fields must be comPleted accurately. vr.r.pacelaos.com - Page: Of Section A Section B Section C Required Client Information: Required Project Information- Invoice Information' ? 0 I�'1I �13. L \J f �.J b Company: Report To: L_.,k�,n> ()-'lC�.n Anention: Address:. Copy To: Company Name: REGULATORY AGENCY Address: r NPDES GROUNDWATER DRINKING WATER UST RCRA OTHER Email To: Purchase Order No.: Pace Qoote Releroncc Phone: Fax: Project Name: 1n� ;J �.(�.1 �. ,"Y� C-- - Pate PrOje�! Mai rw: Site Location STATE: ~= Requested Due Datr1TAT: Project Number: Paw P.N. a, Requested Analysis Filtered (YIN) Scption D Matrix Codes mQL RaqulredClmnl lnfonna:'bn MATRIX I CODE s Drinking Water DIN Water WT (7 COLLECTED Pre z ervatives r z0 _ Wasle Water WW Product P Soiusolid St. 2 SAMPLE ID oit oL Wipe WP (A-Z,0-91,) Air AR $ample IDs MUST BE UNIQUe Tissue TS O Uz Other OT X m 0 a N SiAF2T TE C N��RAB W O Cn LL LL Z p 0 R moQ n Ul = s r o z z cc O 'r F to y, y �' Z z } `o U cc Pace Project No.1 Lab I.D. DATE TIME DATE TIME 1- ¢a m 1 Ln r,r1 U ^.1 A 'fT IP 2 3 d S 6 7 E 9 10 11 12 ADDITIONAL COMMENTS RELINQUISHED BY i AFFILIATION DATE TIME ACCEPTED BY) AFFILIATION DATE TIME SAMPLE CONDITIONS �.r ��,�, .ti��,LCe i r 15 A-) �i SAMPLER NAME AND SIGNATURE ORIGINAL PRINT Name of SAMPLER: 1.. r r i . v o y fl $ z ,e SIGNATURE of SAMPLER: ., _ DATE Signed (MM1DDfYY}- -Imponan: Note', By srgn,ng lh� forrn you are aecephng Pace's NET 30 day wyment I—S and agleemp to late tnarges of t 5% per month for any 'mvolcos n pald w ihin 30 days. F-A1_L4)-029rev.07, 15-M3y-2DU7