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HomeMy WebLinkAbout5001_Jackson_WCU_MSWLF_Feb2021GW_FID1571623_20210322wood. FEBRUARY 2021 SEMI-ANNUAL WATER QUALITY AND LANDFILL GAS MONITORING REPORT Western Carolina University Closed Municipal Solid Waste Landfill Monteith Gap Road Cullowhee, Jackson County, North Carolina 28723 NCDEQ Permit: 50-01 Prepared For: Western Carolina University 3476 Old Cullowhee Road Cullowhee, North Carolina 28723 Prepared by: Wood Environment & Infrastructure Solutions, Inc. 1308-C Patton Avenue Asheville, North Carolina 28806 March 11, 2021 Wood Project 6252-15-0221 wood. Wood Environment & Infrastructure Solutions, Inc. 1308-C Patton Avenue Asheville, NC 28806 USA March 11, 2021 Mr. Roger Turk Western Carolina University 3476 Old Cullowhee Road Cullowhee, North Carolina 28723 Subject: February 2021 Water Quality and Landfill Gas Monitoring Report WCU Closed Municipal Solid Waste Landfill Cullowhee, Jackson County, North Carolina NCDEQ Permit: 50-01 Wood Project 6252-15-0221 Dear Mr. Turk: T: 828-252-8130 www.woodpic.com Wood Environment & Infrastructure Solutions, Inc. (Wood) is pleased to submit this February 2021 Water Quality and Landfill Gas Monitoring Report for Western Carolina University's (WCU's) closed municipal solid waste landfill located in Cullowhee, North Carolina. The scope of work for this monitoring event was described in Wood's Proposal for Environmental Services, dated May 26, 2020. Wood appreciates the opportunity to provide our environmental services to WCU. If you have any questions regarding this report, please contact us at (828) 252-8130. Sincerely, Wood Environment & Infrastructure Solutions, Inc. Rodney M. Clark, L.G. Technical Professional RMC/MEW:rmc I6 t. Waw,' Matthew E. Wallace, P.E. Principal Engineer cc: Ms. Jaclynne Drummond — NCDEQ Solid Waste Section, Asheville Regional Office Mr. Lee Hill — NCDEQ Solid Waste Section, Asheville Regional Office North Carolina Corporate Engineering License No. F-1253; Geology No. C-247 9 February 2021 Water Quality and Landfill Gas Monitoring Report March 11, 2021 WCU Closed MSWLF Wood Project 6252-15-0221 TABLE OF CONTENTS Page 1. Introduction..................................................................................................................................1 1.1. Site -Specific Information............................................................................................................................1 1.2. Background Information............................................................................................................................1 2. Field Activities..............................................................................................................................3 2.1. Landfill Gas Monitoring..............................................................................................................................3 2.2. Water Quality Monitoring..........................................................................................................................3 3. Results and Discussion................................................................................................................5 3.1. Landfill Gas.......................................................................................................................................................5 3.2. Groundwater and Surface Water............................................................................................................ 5 3.2.1. Appendix I VOCs....................................................................................................................................... 5 3.2.2. 1,4- D i oxa n e................................................................................................................................................. 6 3.2.3. Appendix I Metals....................................................................................................................................6 LIST OF TABLES 1 Landfill Gas Well Construction Details 2 Well Construction and Water Level Data — February 2021 3 Groundwater Quality Data — February 2021 4 Groundwater Analytical Results — February 2021 5 Surface Water Analytical Results — February 2021 6 Historical Groundwater Analytical Results 7 Historical Surface Water Analytical Results LIST OF FIGURES 1 Topographic Site Map 2 Site Map with Monitoring Locations APPENDICES A Landfill Gas Monitoring Data Form B Groundwater Sampling Logs C NCDEQ Environmental Monitoring Reporting Form D Laboratory Analytical Report February 2021 Water Quality and Landfill Gas Monitoring Report March 11, 2021 WCU Closed MSWLF Wood Project 6252-15-0221 1. INTRODUCTION This report documents field activities and results from the February 2021 water quality and landfill gas monitoring event at Western Carolina University's (WCU's) closed Municipal Solid Waste Landfill (MSWLF) located in Cullowhee, North Carolina (Site) as shown on Figure 1. 1.1. Site -Specific Information Site Name: WCU Closed MSWLF Facility Permit Number: Facility Latitude/Longitude Site Location Map: Facility Address: Facility Owner: 50-01 N 350 19' 30" / W 830 10' 55" Figure 1 Monteith Gap Road Cullowhee, North Carolina Jackson County Western Carolina University Attn. Mr. Roger Turk 3476 Old Cullowhee Road Cullowhee, North Carolina, 28723 (828) 227-3571 Primary Consultant: Wood Environment & Infrastructure Solutions, Inc. 1308-C Patton Avenue Asheville, North Carolina 28806 (828) 252-8130 1.2. Background Information WCU operated the MSWLF from approximately the 1960s until 1993. Jackson County also disposed of municipal solid waste at the landfill from approximately the early 1970s through the early 1980s. The landfill property is approximately 31.5 acres, approximately four acres of which contain the former landfill. The landfill was closed in accordance with the then applicable North Carolina Department of Environmental Quality (NCDEQ) closure standards (15A NCAC 13B 0.0510), and a closure letter was issued to WCU by NCDEQ on September 5, 1995. NCDEQ personnel conducted a facility audit on March 16, 2011 and determined that semi-annual water quality and landfill gas monitoring at the landfill must be performed in order for the landfill to be in compliance with the post -closure conditions identified in the 1995 closure letter. In response to the audit, a Landfill Gas Investigation Work Plan, which described the preliminary landfill gas investigation, as well as the 'full' landfill gas investigation, was submitted to NCDEQ on October 19, 2011, and approved by NCDEQ in a letter dated November 29, 2011. Wood February 2021 Water Quality and Landfill Gas Monitoring Report March 11, 2021 WCU Closed MSWLF Wood Project 6252-15-0221 Environment & Infrastructure Solutions, Inc. (Wood) conducted the preliminary landfill gas investigation in January 2012 using the existing groundwater monitoring wells. NCDEQ indicated that when funding became available to WCU from the State of North Carolina, the 'full' landfill gas investigation was to be implemented. Wood has conducted semi-annual water quality monitoring since August 2011 and conducted semi-annual landfill gas monitoring utilizing the existing groundwater monitoring wells from August 2012 to November 2015 to comply with the post - closure conditions. The 'full' landfill gas investigation, including the installation of eight permanent landfill gas monitoring wells, was performed in February 2016. Quarterly landfill gas monitoring is now conducted. February 2021 Water Quality and Landfill Gas Monitoring Report March 11, 2021 WCU Closed MSWLF Wood Project 6252-15-0221 2. FIELD ACTIVITIES Wood personnel visited the Site on February 9, 2021 to conduct water quality monitoring and on February 10, 2021 to conduct landfill gas monitoring. 2.1. Landfill Gas Monitoring Wood personnel measured landfill gas at the eight landfill gas monitoring wells (LG-1, LG-2, LG-3S, LG-3D, LG-4, LG-5, LG-6 and LG-7) at the Site (Figure 2). The landfill gas monitoring wells are screened in the unsaturated zone and located between the landfill and the Site's property boundary (Table 1). The landfill gas monitoring wells are fitted with a slip cap and ball valve to allow for measurement of potential landfill gas. A calibrated gas monitoring instrument, a Landtec GEM 5000, was used to measure atmospheric barometric pressure, as well as the following landfill gas parameters: Methane (percent by volume) Oxygen (percent by volume) Carbon dioxide (percent by volume) The initial and stabilized readings for the above parameters were measured and recorded. The Solid Waste Section's Landfill Gas Monitoring Data Form was used to record measurements and other relevant information and is provided in Appendix A. 2.2. Water Quality Monitoring Wood personnel gauged static groundwater levels in the four Site monitoring wells (MW-1, MW-2, MW-3 and MW-4). Water levels were referenced to the top -of -casing at the wells. Depth to water measurements and water table elevations for the monitoring wells are presented in Table 2. The monitoring wells were purged and sampled using low -flow purging techniques with a variable - speed submersible or a peristaltic pump with new polyethylene tubing. The tubing intake was lowered to within five feet of the bottom of the monitoring wells. The pumping rate was minimized to prevent excessive drawdown in the well and simulate the groundwater recharge rate, which was monitored using an electronic water level indicator. Water quality parameters (temperature, pH, specific conductance, dissolved oxygen, oxidation-reduction potential, and turbidity) were measured using a water quality meter equipped with a flow -through cell (Table 3). Groundwater samples were collected from the monitoring wells after the water quality parameters stabilized. The purge water was discharged to the ground surface in proximity to each well in a manner that precluded erosion or surface runoff. Copies of the groundwater sampling logs are provided in Appendix B. The submersible pump was decontaminated by washing the pump and electrical cable in an industrial detergent and distilled water solution. The pump was then rinsed with distilled water. An equipment blank sample, EB-1, was collected from the pump discharge by operating the pump in deionized water and pumping the water into sample containers. February 2021 Water Quality and Landfill Gas Monitoring Report March 11, 2021 WCU Closed MSWLF Wood Project 6252-15-0221 Surface water samples SW-1 and SW-2 were collected at the approximate locations depicted in Figure 2. The water samples were placed in laboratory -supplied containers, labeled with sampling information, packed in an ice -chilled cooler, and shipped with appropriate chain -of -custody records via overnight delivery to Waypoint Analytical (a North Carolina -accredited analytical laboratory). The samples were submitted for analysis of Appendix I volatile organic compounds (VOCs) according to Environmental Protection Agency (EPA) Method 8260, 1,4-dioxane via EPA Method 8260 SIM (selective ion monitoring), and Appendix I metals according to EPA Method 6020 (3030C preparation method). 4 February 2021 Water Quality and Landfill Gas Monitoring Report March 11, 2021 WCU Closed MSWLF Wood Project 6252-15-0221 3. RESULTS AND DISCUSSION The results of the water quality and landfill gas monitoring event are reported in the NCDEQ Environmental Monitoring Report Form that is provided in Appendix C and summarized in the following sections. 3.1. Landfill Gas The Site landfill gas monitoring wells were tested for methane, carbon dioxide and oxygen. Refer to the attached Landfill Gas Monitoring Data Form for the testing results. Concentrations of methane were not detected in the landfill gas monitoring wells. The regulatory limit for methane at a MSWLF property boundary is equal to the lower explosive limit of methane (15A NCAC 1313.1627 (d)). The recorded results from the eight landfill gas wells (non -detect) do not exceed this limit indicating that regulatory limits are not being exceeded at the Site's property boundary. 3.2. Groundwater and Surface Water Monitoring well MW-1 is the u pg rad ient/backg round monitoring well. The groundwater analytical results were compared to the North Carolina Groundwater Classification and Standards (15A NCAC 2L .0202, amended effective April 1, 2013), which includes applicable interim standards updated April 6, 2018, herein referred to as the "2L Groundwater Standards", and the EPA Maximum Contaminant Levels (MCLs) established in the National Primary Drinking Water Regulations, dated May 2009. The surface water analytical results were compared to the North Carolina Surface Water Quality Standards, Criteria and In -Stream Target Values (15A NCAC 213, summary tables, dated June 10, 2019), which include EPA's Nationally Recognized Water Quality Criteria for Aquatic Life and Human Health, herein referred to as the "Surface Water Standards." Analytical results from the February 2021 water quality monitoring event are presented in Tables 4 and 5, and historical analytical results are presented in Tables 6 and 7. The laboratory analytical report is included in Appendix D. 3.2.1. Appendix I VOCs Appendix I VOCs were not detected above the method detection limit (MDL) in the groundwater samples collected from monitoring wells MW-1 and MW-2. Four Appendix I VOCs were estimated or detected at concentrations above the MDLs in the groundwater sample collected from monitoring well MW-3, and one Appendix I VOC was estimated at a concentration above the MDL in the groundwater sample collected from monitoring well MW-4. Five Appendix I VOCs were detected or estimated at concentrations above the MDLs in the field duplicate groundwater sample, FD-1, which was also collected from monitoring well MW-3. The detected or estimated VOC concentrations were below their respective 2L Groundwater Standards and EPA MCLs. Four Appendix I VOCs were estimated or detected at concentrations above the MDLs in the surface water samples SW-1 and SW-2. The VOC concentrations were below their respective Surface Water Standards, if established. February 2021 Water Quality and Landfill Gas Monitoring Report March 11, 2021 WCU Closed MSWLF Wood Project 6252-15-0221 3.2.2. 1,4-Dioxane 1,4-Dioxane was not detected above the MDL or 2L Groundwater Standard in the groundwater samples collected from the monitoring wells, including the field duplicate. An EPA MCL is not currently established for 1,4-dioxane in groundwater. 1,4-Dioxane was detected at concentrations above the MDL in the surface water samples collected at locations SW-1 and SW-2. The concentration of 1,4-dioxane detected in SW-1, 3.93 micrograms per liter (pg/L), and in SW-2, 2.30 pg/L, did not exceed the applicable Surface Water Standard/In- Stream Target Value (Human Health) of 80 pg/L. 3.2.3. Appendix I Metals Seven Appendix I metals were detected above the MDLs in the groundwater samples, including the field duplicate sample FD-1, which was collected from MW-3, and the equipment blank EB-1. Six of the seven Appendix I metals were detected at concentrations and/or estimated concentrations below their respective 2L Groundwater Standards. The seven Appendix I metals were detected at concentrations and/or estimated concentrations below their respective EPA MCLs, if established. Information on each of the metals is presented below. Antimony was estimated at a concentration above the MDL, but below the laboratory reporting limits and its respective 2L Groundwater Standard and EPA MCL in the groundwater sample collected from MW-1. Arsenic was estimated at concentrations above the MDL, but below the laboratory reporting limits, and its respective 2L Groundwater Standard and EPA MCL in the groundwater samples collected from MW-1, MW-2, MW-3 (including duplicate FD-1) and MW-4. Arsenic was also estimated above the MDL, but below the laboratory reporting limit, 2L Groundwater Standard and EPA MCL in the equipment blank. Barium was detected at concentrations above the MDL, but below the 2L Groundwater Standard and EPA MCL in groundwater samples collected from MW-1, MW-2, MW-3 (including duplicate FD- 1) and MW-4. Barium was also detected above the MDL, but below the 2L Groundwater Standard and EPA MCL in the equipment blank. Concentrations of copper and zinc were not detected above the MDL in the groundwater samples. Copper and zinc were detected above the MDL, but below their respective 2L Groundwater Standards and/or EPA MCLs, if applicable, in the equipment blank. Cobalt was detected at concentrations of 8.88 pg/L and 8.77 pg/L in the groundwater samples collected from MW-3 and associated duplicate FD-1, respectively, which exceed the 2L Groundwater Standard of 1 pg/L. An EPA MCL is not currently established for cobalt. Cobalt was not detected above the MDL in the other groundwater samples or the equipment blank. Nickel was estimated at concentrations above the MDL, but below the laboratory reporting limits and the 2L Groundwater Standards, in the groundwater samples collected from MW-1, MW-2 and MW-3 (including duplicate FD-1). Nickel was also detected above the MDL, but below the 2L Groundwater Standard in the equipment blank. An EPA MCL is not currently established for nickel. 0 February 2021 Water Quality and Landfill Gas Monitoring Report March 11, 2021 WCU Closed MSWLF Wood Project 6252-15-0221 Concentrations of three Appendix I metals (arsenic, barium and nickel) were detected above the MDL collected from the site's background/upgradient monitoring well MW-1. Concentrations of Appendix I metals in groundwater samples have generally been lower than historical concentrations with less exceedances above applicable Standards since low -flow purging/sampling has been implemented. Low -flow purging/sampling techniques will continue to be used for the next semi-annual water quality monitoring event. Eight Appendix I metals were detected or estimated at concentrations above the MDLs in the surface water samples collected from SW-1 and/or SW-2. Cobalt was detected at a concentration of 6.82 lag/L in SW-1 and 5.41 lag/L in SW-2, which exceeds the North Carolina In -Stream Target Value (Human Health) of 4 lag/L. Copper was estimated at a concentration of 7.46 lag/L in SW-1, which exceeds its calculated North Carolina In -Stream Target Value (Human Health) of 3.6 lag/L (acute value). Copper was not detected above the MDL in SW-2. Concentrations of the other six Appendix I metals were below their respective North Carolina Surface Water Standards. II February 2021 Water Quality and Landfill Gas Monitoring Report March 11, 2021 WCU Closed MSWLF Wood Project 6252-15-0221 TABLES TABLE 1 Landfill Gas Well Construction Details Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Landfill Gas Well Installation Date Drilling Method Well Material Well Depth (bgs) Screened Interval (bgs) Ground Surface Elevation Top of Casing Elevation Latitude Longitude LG-1 LG-2 2/17/2016 2/17/2016 HSA PVC PVC 18.0 5.0 - 17.8 5.0 - 19.7 2,243.52 2,246.35 35.3241 -83.1822 -83.1825 HSA 20.0 2,207.23 2,209.97 35.3249 LG-3S 2/16/2016 HSA PVC 30.0 4.8 - 29.8 2,180.25 2,183.19 35.3261 -83.1831 LG-3D 2/16/2016 HSA PVC 66.2 36.0 - 66.0 2,180.25 2,183.14 35.3261 -83.1831 LG-4 2/18/2016 HSA PVC 7.9 4.9 - 7.7 2,125.80 2,128.58 35.3266 -83.1823 LG-5 2/18/2016 HSA PVC 30.4 5.3 - 30.1 2,166.48 2,169.12 35.3266 -83.1813 LG-6 2/18/2016 HSA PVC 10.7 5.6 - 10.4 2,208.23 2,210.92 35.3253 -83.1810 LG-7 2/17/2016 HSA PVC 35.3 5.2 - 35.0 2,266.43 2,269.08 35.3244 -83.1811 Notes: 1. Depths are in feet relative to ground surface (bgs). 2. Elevations are in feet relative to mean sea level. 3. HSA - hollow -stem auger; PVC - Schedule 40 polyvinyl chloride. Prepared By: RMC 2/17/21 Checked By: GLH 2/22/21 TABLE 2 Well Construction Details and Water Level Data - February 2021 Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Monitoring Well Installation Date* Latitude Longitude Ground Surface Top of Casing Elevation Elevation Well Depth (feet MSL) (feet MSL) (feet BTOQ Depth to Water (feet BTOQ Groundwater Elevation (feet MSL) MW-1 1990 35.3240 -83.1811 2,302.50 2,306.01 93.28 67.52 2,238.49 MW-2 1990 35.3249 -83.1825 2,206.88 2,209.37 50.78 30.15 2,179.22 MW-3* 1990 35.3259 -83.1826 2,182.88 2,185.65 **62.92 51.91 2,133.74 MW-4 1990 35.3264 -83.1818 2,129.14 2,131.66 21.35 6.90 2,124.76 Notes: 1. Water levels were obtained on February 9, 2021. 2. * Actual date of well installation is not known, but monitoring wells were first sampled in March 1990 during closure activities (Law Engineering report dated January 16, 1991); screened interval depths are not known. 3. MSL - mean sea level; BTOC - below top of casing. 4. ** Well depth indicated in 2004 monitoring report (RETAW Corporation) indicates well depth is 71.7 feet. Prepared By: RMC 2/17/21 Checked By: GLH 2/22/21 TABLE 3 Water Quality Data - February 2021 Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Monitoring Well Temperature (°C) pH Conductivity (mS/cm) Oxidation Reduction Potential (mv) Dissolved Oxygen (mg/L) Turbidity (NTU) MW-1 13.84 4.01 0.021 336 7.52 11.9 MW-2 14.35 4.37 0.112 249 2.24 0.0 MW-3 14.93 4.23 0.385 85 4.22 0.0 MW-4 13.36 4.70 0.080 267 3.64 0.0 SW-1 11.76 6.73 0.648 132 7.80 11.8 SW-2 14.69 5.37 0.290 92 6.40 1.20 Notes: 1. Water quality data reported above collected prior to sample collection. 2. Water quality parameters were measured on February 9, 2021. 3. °C - degrees Celcius; mS/cm - milliSiemens per centimeter; my - millivolts; NTU - nephelometric turbidity units; mg/L - milligrams per liter. Prepared By: RMC 2/17/21 Checked By: GLH 2/22/21 TABLE 4 Groundwater Analytical Results - February 2021 Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 2L Groundwater Standard EPA MCL MW-1 MW-2 FD-1 MW-3 (MW-3) MW-4 Appendix I VOCs Benzene 1 5 <0.048 <0.048 0.458 J 0.509 <0.048 Chlorobenzene 50 100 <0.062 <0.062 10.0 9.24 0.477 J 1,2-Dichlorobenzene 20 600 <0.076 <0.076 <0.076 0.203 J <0.076 1,4-Dichlorobenzene 6 75 <0.050 <0.050 2.36 2.20 <0.050 cis-1,2-Dichloroethylene 70 70 <0.056 <0.056 1.66 1.47 <0.056 Appendix I Metals Antimony 1 6 <0.490 <0.492 <0.490 0.631 J <0.492 Arsenic 10 10 0.170 J 0.177 J 0.310 J 0.315 J 0.183 J Barium 700 2,000 35.1 86.0 117 118 30.5 Cobalt 1 NE <0.520 <0.521 8.88 8.77 <0.522 Nickel 100 NE 1 1.12 J 1.18 J 2.75 J 2.71 J <0.513 Notes: 1. Appendix I VOCs (volatile organic compounds) analyzed according to EPA Method 8260B and 1,4-dioxane analyzed via EPA Method 8260B SIM. 2. Appendix I metals analyzed according to EPA Method 6020B using EPA Method 3030C preparation method. 3. Concentrations are in micrograms per liter (Ng/L). 4. 2L Groundwater Standard - from 15A NCAC 2L, effective April 1, 2013, including Interim Maximum Allowable Concentrations. 5. EPA MCL - Environmental Protection Agency Maximum Contaminant Level. 6. NE - associated standard has not been established. 7. Constituents detected above the method detection limit (MDL) are shown; refer to laboratory analytical report for list of constituents. 8. '<' - Constituent not detected above the indicated MDL. 9. J - concentration is estimated. 10. Bold concentrations indicate exceedance of the 2L Groundwater Standard. Prepared by: RMC 2/18/21 Checked by: GLH 2122121 TABLE 5 Surface Water Analytical Results - February 2021 Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 NC Surface Water Standard (Freshwater Aquatic Life) NC Surface Water In -Stream Standard EPA NRWQC Target Values (Human (Human (Freshwater Health) Health) Aquatic Life) In -Stream Target Values (Human Health) SW-1 SW-2 Appendix I VOCs and 1,4-Dioxane Benzene NE 51 NE NE NE <0.048 0.202 J Chlorobenzene NE NE 800 140 NE 1.20 2.48 1,4-Dichlorobenzene NE NE 900 100 NE 0.542 0.621 Tetrahydrafuran NE NE NE NE 3,100 3.43 J <1.10 1,4-Dioxane NE NE NE NE 80 3.93 2.30 Appendix I Metals Arsenic 340 (acute) 10 NE NE NE 0.443 J 0.251 J Barium NE NE NE 21,000 200,000 (t) 309 140 Cadmium 0.82 (acute)* NE NE NE NE 0.207 J <0.160 Cobalt NE NE NE 16 (acute) 4 6.82 5.41 Copper 3.6 (acute)* NE NE NE NE 7.46 J <3.80 Lead 14 (acute)* NE NE NE NE 3.66 <2.60 Nickel 145 (acute)* NE NE NE NE 5.57 0.915 J Zinc 1 36 (acute)* i NE I NE I NE I NE 1 19.1 J 1 <6.90 Notes: 1. Appendix I VOCs (volatile organic compounds) analyzed according to EPA Method 8260B and 1,4-dioxane analyzed via EPA Method 8260B SIM. 2. Appendix I Metals analyzed according to EPA Method 6020B using EPA Method 3030C preparation. 3. Concentrations are in micrograms per liter (pg/L). 4. NC Surface Water Standard - From 15A NCAC 2B (tables dated June 10, 2019). 5. EPA NRWQC - Environmental Protection Agency's Nationally Recognized Water Quality Criteria for Aquatic Life and Human Health. 6. NE - associated standard has not been established. 7. Constituents detected above the method detection limit (MDL) are shown; refer to laboratory analytical report for list of constituents. 8. '<' - Constituent not detected above the indicated method detection limit. 9. J - concentration is estimated 10. Bold concentration indicates exceedance of NC Protective Value. 11. t - Based upon measurement of total recoverable metal. 12. * A hardness of 25 milligrams per liter was assumed to calculate the standard. Prepared By: RMC 2/18/21 Checked By: GLH 2/23/21 TABLE 6 Historical Groundwater Analytical Results Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Appendix I VOCs Appendix I Metals Location Sample Date OY yc N CO d N -0 O L ar L N 41 O Qn! N N 4 O Q d w T O u a 0 w d s O O NiN ar M C O E _ CO CO £ u � 0 2 u u O u RMonitorin9 Z 2 in in £7 I.- _ =R > =O N MW-1 8/3/11 0.35 JB 390 63 B 28 180 7.8 38 0.88 J 0.98 J 160 2/2/12 0.421B 62 1.7 3.5 J 0.79 JB 17 8/28/12 0.651B 0.321 270 0.351 0.591 8.2 JB 16 26 7.0 6.3 0.271 2.9 14 37 B 2/8/13 0.73 J 0.58 JB 530 0.841 0.591 17 B 42 64 19 17 0.341 0.481 0.64J 20 63 9/4/13 350 0.321 1.7 18 22 61 9.8 13 2.4 JB 0.151 26 80 2/19/14 0.20 J 39 0.054 J 0.161 0.261 1.1 J 0.201 0.471 0.074 J 6.01 9/9/14 3.7 0.381 45 0.096 J 0.161 1.4 2.8 J 0.531 0.67 JB 0.28 J 8.6 JA 6.1 JB 2/25/15 7.3 B /*0.27 J 0.641 110 0.141 1.1 2.1 J 0.631 0.91 1 0.831 26 6.8 J 11/6/15 0.082 J 0.781 40 0.141 0.11 1 4.3 B 0.531 2.0 J 0.521 1.0 J 0.042 J 0.171 3.91 3/2/16 0.21 J 2.6 B 37 0.591 6.3 B 0.161 1.9 J 0.391 3.0 0.045 J 0.121 13 B/*4.8 J 9/21/16 0.14 J 36 0.062 J 0.052 J 1.6 0.421 4.7 J 0.241 3.8 0.027 J 0.073 J 7.4 J 2/7/17 0.74 J 37 0.141 0.181 0.971 0.431 4.5 J 0.501 0.961 0.14 J 0.26 J 1.3 J 5.2 J 8/23/17 41 0.57 J 0.47 BL, J 1.81 0.17 J 0.39 J 0.86 J 0.15 J 24 3/15/18 1.0 B /*ND 48 B/*63 0.81 1 0.581 3.4 J 0.371 0.561 0.076 J 0.054 J 20 B /*21 8/21/18 110 0.121 0.076 J 14 5.9 13 2.6 37 0.034 J 3.1 17 3/25/19 2.9 B /*<0.19 54 0.881 0.681 1.7 J 0.621 2.1 0.022 J 16 8/20/19 4.21 32 1.6 J 13 J 2/25/20 2.3 BJ 36 1.1 J 4.7 J 1.5 J 9/10/20 50 14 1.4 J 7.2 J 0.401 7.8 4.2 J 8.01 2/9/21 0.170 J 35.1 1.12 J M W-2 8/3/11 0.48 J 0.221 130 0.201 2.0 1.8 1.2 J 0.591 2.5 0.541 0.076 J 0.76 J 3.8 J 9.51 2/2/12 0.931B 120 0.331 0.721 0.17 JB 2.3 0.064 J 0.26 J 9.31 8/28/12 0.461B 110 0.31 1 0.471 4.8 JB 0.621 1.5 J 0.501 2.5 0.040 J 3.0 2.5 J 11 B 2/8/13 100 0.161 2.2 B 0.31 1 1.4 J 0.151 1.9 J 0.21 1 0.141 0.161 16 9/4/13 100 0.38 J 0.66 J 2.9 J 1.8 J 21 2/19/14 0.22 J 0.361 100 0.151 0.171 0.21 1 0.131 1.5 J 0.181 0.093 J 0.050 J 7.5 J 9/9/14 4.2 92 0.181 0.261 0.621 1.2 J 0.181 1.5 JB 0.046 J 0.35 J 6.6 JA 9.0 JB 2/25/15 5.1 B /*0.22 J 62 1.6 2.7 7.0 1.2 1.7 J 12 33 11/6/15 0.075 J 100 0.11 1 0.131 3.6 B 3.0 2.8 J 0.691 1.7 J 0.039 J 0.151 5.3 J 3/2/16 0.12 J 3.4 B 100 0.601 5.5 B 0.161 1.8 J 0.271 1.6 J 1.3 0.051 J 0.099 J 0.37 J 12 B/*4.3 J 9/21/16 2.4 J 0.12 J 110 0.095 J 1.1 0.281 8.6 0.191 2.6 0.018 J 0.059 J 8.61 2/7/17 0.59 J 89 0.241 0.281 0.571 0.331 1.21 0.431 1.6 J 0.601 0.141 0.37 J 1.1 J 5.31 8/23/17 0.38 J 100 0.081 J 0.071 J 0.53 J 0.80 BL, J 2.31 0.21 J 1.31 0.50 J 0.171 28 3/15/18 0.95 BJ/*0.701 11O B /*110 0.069 J 0.751 0.661 2.5 J 0.131 1.8 J 0.075 J 0.035 J 16 B /*16 8/21/18 100 0.085 J 0.082 J 0.531 0.083 J 4.2 J 0.321 1.5 J 13 3/25/19 3.9 B /*0.22 J 110 0.085 J 0.481 0.491 3.4 J 0.391 1.7 J 0.085 J 16 8/20/19 89 1.7 J 191 2/25/20 2.1 BJ 87 1.3 J 1.5 J 9/10/20 79 1.0J 2/9/21 0.177 J 86 1.18 J 2L GW Standard 6,000 1 50 3000 20 6 70 100 0.030 1 3 1 1 10 700 4 2 10 1 1,000 15 100 20 20 0.2 0.3 1,000 EPA MCL NE 5 100 NE 600 75 70 100 2 NE 6 10 2,000 4 5 100 NE 1,300 15 NE 50 NE 2 NE NE Page 1 of 2 TABLE 6 Historical Groundwater Analytical Results Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Appendix I VOCs Appendix I Metals Location Sample Date Ov Q yc N d N -0 O L CO aJ L N 41 O QN N N 4 O Q - d w T O u a 0 w d s O O NiN aJ M V C O _ CO CO £ u � 0 2 u u O u RMonitorin9 V Z in in £ 7E I.- _ =R > =O N MW-3 8/3/11 78 1.0 15 0.66 4.9 9.5 0.49 J 1.0 150 0.891 1.3 8.5 1.7 J 0.591 5.1 1.5 0.151 1.1 3.0 J 46 2/2/12 6.6 0.79 7.1 3.4 4.8 0.34 J 0.72 JB 5.0 340 0.341 31 36 75 30 8.2 B 79 1.3 0.072 J 1.3 36 3,700 8/28/12 3.3 J 0.97 14 4.5 8.8 0.181B 0.971 130 0.481 4.7 JB 6.3 1.8 J 0.301 4.1 1.6 0.091 J 0.68 J 40 B 2/8/13 3.2 9.1 3.7 5.5 150 0.561 1.6 B 15 2.6 J 0.181 4.0 1.1 0.071 J 26 9/4/13 0.51 11 3.2 5.2 390 0.201 0.701 26 17 16 4.3 J 19 2.3 JB 50 95 2/19/14 0.71 12 3.7 6.4 0.13 J 0.371 150 0.073 J 0.371 7.3 2.1 1 0.331 2.5 0.771 0.068 J 0.054 J 1.8 J 18 9/9/14 0.61 12 4.1 4.5 3.4 130 0.076 J 0.241 9.0 1.61 0.191 3.0 B 0.161 9.5 JA 20 B 2/25/15 79 1.1 12 3.9 5.2 6.1 B /*0.41 J 1.2 340 0.281 2.1 14 13 20 4.8 16 0.831 0.074 J 0.38 J 38 120 11/6/15 250 1.1 17 0.53 4.9 5.6 1.2 390 0.231 1.1 25 B 16 25 6.3 19 1.1 0.058 J 0.33 J 54 120 3/2/16 5.4 0.59 10 2.3 4.0 0.095 J 3.1 B 120 0.048 J 0.431 5.2 B 6.2 1.41 0.341 1.5 J 4.5 0.048 J 0.035 J 12 B/*5.0 J 9/21/16 28 0.79 14 3.5 3.5 0.30 J 150 0.251 0.731 11 3.3 J 0.681 6.6 0.821 0.020 J 0.131 3.4 J 18 2/7/17 260 0.97 10 3.6 2.9 1.6 1.2 250 0.231 3.2 9.0 8.9 17 7.5 14 1.6 0.072 J 0.50 J 17 180 3/15/18 0.85 15 3.8 5.0 0.85BJ/*0.54 J 15o B /*150 0.461 13 4.1 280 13 0.51 1 67 1.2 J 0.074 J 0.38 J 0.90 J 300 B /*280 8/21/18 7.7 0.61 9.9 2.4 2.5 110 0.11 J 0.078 J 0.561 15 2.4 J 0.073 J 4.2 0.571 9.7 3/25/19 6.8 0.63 11 0.261 2.7 2.7 3.1 3.8 B /*<0.19 120 0.341 17 1.5 J 0.161 5.3 0.038 J 12 8/20/19 0.53 11 2.4 2.2 2.5 120 9.2 3.2 15 J 2/25/20 0.40 J 9.2 2.3 1.7 1.6 J 2.1 BJ 120 10 3.5 9/10/20 0.46 J 8.4 2.0 1.6 1.1 J 110 7.8 3.3 2/9/21 0.458 J 10 2.36 1.66 0.310 J 117 8.88 2.751 MW-4 8/3/11 0.67 15 0.53 5.4 4.8 - 0.27 J 0.31 1 210 0.361 4.4 1.9 3.51 1.4 2.3 0.91 1 0.060 J 0.35 J 7.4 11 2/2/12 1.5 0.73 0.52 0.44 JB 89 0.381 1.01 0.46 JB 0.191 14 8/28/12 3.5 1.6 1.1 120 0.371 5.9 JB 0.821 2.81 0.651 1.5 J 0.591 0.41 J 4.1 J 28 B 2/8/13 1.7 0.83 0.65 85 0.131 3.0 B 0.471 1.91 0.331 0.671 0.331 0.041 J 18 9/4/13 10.0 3.9 2.8 190 0.261 8.0 J 3.1 J 7.8 1.6 J 3.0 J 101 46 2/19/14 4.3 1.8 1.4 0.099 J 0.351 120 0.067 J 0.231 0.461 1.1 1 0.351 0.961 0.571 0.054 J 0.053 J 1.9 J 7.8 J 9/9/14 8.3 2.9 1.6 4.0 120 0.089 J 0.241 1.2 1.81 0.601 0.90 JB 0.11 1 12 A 5.9 JB 2/25/15 6.4 2.3 1.6 6.1 B /*0.21 J 90 0.191 0.471 1.1 1 0.301 1.5 J 8.31 11/6/15 4.6 1.5 0.89 100 0.074 J 0.191 9.2 B 0.161 0.951 0.281 2.1 0.971 0.041 J 0.101 3.21 3/2/16 6.6 2.6 1.5 0.084 J 3.7 B 120 0.601 4.3 B 0.099 J 1.31 0.201 0.461 0.851 0.045 J 0.032 J 9.5 B, J/*4.3 J 9/21/16 8.8 2.7 1.8 0.79 0.13 J 150 0.281 0.651 0.241 7.7 0.21 1 1.3 J 0.621 0.023 J 0.050 J 8.2 J 2/7/17 5.0 1.4 0.90 0.471 99 0.151 0.571 0.221 0.801 0.321 0.901 0.791 0.11 1 1.11 4.0 J 8/23/17 9.6 3.0 1.7 140 0.201 0.771 0.31 B,1 1.31 0.099 J 1.21 0.601 0.101 17 3/15/18 1.8 0.83 0.70 BJ /*0.20 J 90 B /*80 0.054 J 0.481 0.082 J 1.1 0.060 J 59 13 B /*13 8/21 /18 2.6 0.98 110 0.131 0.094 J 1.2 0.851 3.0 J 1.0 1.1 J 2.6 21 3/25/19 4.3 1.9 0.70 3.6 3.6 B /*<0.19 110 0.141 0.621 0.471 1.1 1 0.221 0.841 0.020 J 14 8/20/19 0.42 J 11 2.9 1.8 3.7 130 1.71 1.81 16 J 2/25/20 8.4 0.68 2.3 1.1 2.8 2.0 BJ 110 0.891 9/10/20 1.2 37 2/9/21 0.477 J 0.183.1 30.5 2L GW Standard 6,000 1 50 3000 20 6 70 100 0.030 3 1 10 700 4 2 10 1 1,000 15 100 20 20 0.2 0.3 1,000 EPA MCL NE 5 100 NE 600 75 70 100 2 NE 6 10 2,000 4 5 100 NE 1,300 15 NE 50 NE 2 NE NE Notes: Prepared By: RMC 12/19/21 1. VOCs - volatile organic compounds according to EPA Method 8260B and 1,4-dioxane analyzed via EPA Method 8260B SIM. 2. Metals according to EPA Method 6020, using EPA Method 3030C preparation Checked By: GLH 2/22/21 2. Concentrations are in micrograms per liter (Ng/L). 3. 2L GW Standard - 2L Groundwater Standard from 15A NCAC 2L, effective April 1, 2013 (including interim maximum allowable concentrations). EPA MCL - Envirommnetal Protection Agency's Maximum Contaminant Level, 4. NE - associated standard has not been established, 5. Constituents detected above the method detection limit (MDL) are shown; refer to laboratory analytical report for list of constituents 6. Blank cells indicate constituent not detected in sample above the MDL. 7. J - concentration is estimated; A - sample diluted due to internal standard recovery outside limits; B - constituent detected in method blank sample 8. Bold concentrations indicate exceedance of 2L GW Standard or EPA MCL. 9. * Total antimony, total barium and/or total zinc re -analyzed and reported (second concentration indicated) due to detection of constituent in the associated blank at a concentration greater than half the laboratory reporting limit 10. '-' constituent not analyzed. Page 2 of 2 TABLE 7 Historical Surface Water Analytical Results Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Appendix I VOCs Appendix I Metals a c v � s N y N O O M L N O v y C O O X A C E is O d Oy u T u Q _ 7 7 •£ L Monitoring Sample a c O m + d i 'a .0 a m W d m c W a s q c I: M d R s o 0 'IV Location Date Q m U - u H > Q Q CO m U U U U � Z vi in H > SW-1 2/2/12 0.75 6.2 1.8 0.68 0.59 JB 250 6.5 1.2 J 0.20 JB 1.2 J 1.0 0.231 33 3/2/16 1.1 0.19 J 3.8 B 260 0.41 J 4.3 B 2.2 5.0 J 3.3 3.3 0.78 J 0.039 J 0.11 J 1.2 J 19 B/*21 8/21/18 6.4 0.44 J 240 0.16 J 0.13 J 0.49 J 4.8 7.2 3.4 5.8 0.076 J 2.4 14 2/25/19 2.2 0.66 4.1 B /*<0.20 J 190 0.16 J 2.5 4.1 J 1.5 3.2 0.084 J 29 2/25/20 1.9 ccvu 2.8 0.77 2.1 2.0 BJ 260 3.9 SA J 2.0 4.3 20 2/9/21 1 1.2 1 0.542 3.43 J 3.93 0.443 J 309 0.207 J 6.8 7.46 J 3.66 5.57 19.1 J SW-2 8/3/11 2.0 0.96 1.1 - 0.23 J 250 1.0 12 1.2 J 0.0801 1.7 J 1.0 0.064 J 0.301 0.67 J 12 2/2/12 1.4 0.57 0.46 JB 0.22 J 170 5.5 0.25 JB 0.95 J 0.69 J 0.19 J 13 8/28/12 2.2 0.78 0.48 J 220 5.4 JB 9.4 0.56 J 1.7 J 1.0 0.37 J 1.11 14 B 2/8/13 1.6 0.55 0.97 JB 170 1.7 B 4.4 0.77 J 1.2 J 0.79 J 0.025 J 20 9/4/13 2.5 0.84 180 8.5 0.51 J 26 2/19/14 1.8 0.62 0.43 J 160 0.12 J 5.6 0.16 J 1.1 J 0.78 J 0.056 J 13 9/9/14 2.7 1.1 4.4 200 0.070 J 10 0.95 J 0.12 J 1.2 JB 0.089 J 9.6 JA 9.1 JB 2/25/15 2.1 0.90 6.3 B /*0.22 J 170 8.0 0.92 J 0.30 J 1.1 J 0.70 J 0.082 J 4.2 J 5.7 J 11/6/15 3.3 1.2 0.31 J 200 0.041 J 3.0 B 8.8 0.59 J 0.25 J 1.5 J 0.97 J 0.038 J 6.9 J 3/2/16 1.4 0.092 J 3.0 B 140 0.36 J 4.0 B 3.1 0.72 J 0.14 J 0.49 J 0.63 J 0.028 J 0.026 J 15 B/*8.9 J 9/21/16 3.3 1.0 0.33 J 220 0.054 J 0.043 J 10 0.077 J 0.95 J 0.91 J 0.019 J 0.060 J 1.7 J 2/7/17 1.4 0.59 0.45 J 180 7.8 0.12 J 1.0 J 1.5 0.047 J 3.2 J 8/23/17 2.0 0.74 390 0.90 J 16 B 0.69 J 0.17 J 2.2 0.48 J 0.069 J 17 3/15/18 1.1 0.90 BJ /*0.29 J 180 B /*170 4.1 4.0 J 0.24 J 1.1 J 18 B /*14 8/21/18 8.1 2.0 0.57 460 0.16 J 0.10 J 0.97 17.0 2.7 J 1.4 3.0 1.1 19 2/25/19 0.80 4.1 B /*<0.19 110 2.0 1.0 J 0.14 J 1.2 J 0.022 J 19 8/20/19 3.4 J 3.1 0.84 5.0 190 10 1.6 J 17 J 2/25/20 1.5 0.51 1.8 J 2.0 BJ 130 3.3 1.2 J 14 J 9/10/20 0.37 J 3.6 0.94 3.0 0.18 J 170 8.6 1.3 J 2/9/21 0.202 J 2.48 0.621 2.3 0.251 J 140 5.4 0.915 J NCSW Standard - 340 65 0.82 3.6 14 140 0.30 36 NE NE NE NE NE NE NE NE NE NE NE 5 (t) NE NE Freshwater Aquatic Life (acute) (acute) (acute)** (acute)** (actute)** (acute)** (acute)** (acute)** NCSW Standard - NE 51 NE NE NE 2.4 NE NE 10 (t) NE NE NE NE NE NE NE NE NE NE NE NE NE Human Health EPA NRWQ - Human NE NE 800 900 NE NE NE 640 NE NE NE NE NE NE NE NE 4,600 4,200 NE 0.47 NE NE Health NCISTV - Freshwater 16 2,000 NE 140 100 NE NE NE NE NE 21,000 NE NE NE NE NE NE NE NE NE NE NE Aquatic Life (acute) NCISTV - Human Health 1,100,000 NE NE NE 720 NE 80 5,300 NE 200,000 (t) NE NE NE 4 NE NE NE NE NE NE NE NE Notes: 1. Appendix I VOCs (volatile organic compounds) analyzed according to EPA Method 8260B and 1,4-diozane analyzed via EPA Method 8260E SIM. Metals anlyzed according to EPA Method 6020, using EPA Method 3030C preparation. 2. Concentrations are in micrograms per liter (Ng/L). 3. NCSW Standard - North Carolina Surface Water Standards from 15A NCAC 2B (table dated June 10, 2019); a = acute Prepared By: RMC 2/19/21 4. EPA NRWQC - Environmental Protection Agency's Nationally Recognized Water Quality Criteria for Aquatic Life and Human Health. Checked By: GLH 2/23/21 5. NCISTV - North Carolina In -Stream Target Values from table dated June 10, 2019. 6. NE - associated standard has not been established. 7. Constituents detected above the method detection limit (MDL) are shown; refer to laboratory analytical report for list of constituents. 8. Blank cells indicate constituent not detected in sample above the MDL. 9. J - concentration is estimated; A - sample diluted due to internal standard recovery outside limits; B - constituent detected in method blank sample; CCVL- continuing calibration verification result is below control limits, but within method parameters, and a standard at or below the reporting limit was analyzed and found acceptable. 10. Bold concentrations indicate exceedance of a Surface Water Standard. 11. * Total antimony, total barium and/or total zinc re -analyzed and reported (second concentration indicated) due to detection of constituent in the associated blank at a concentration greater than half the laboratory reporting limit. 12.-indicates not analyzed. 13. ** A hardness of 25 milligrams per liter was assumed to calculate the standard. 14. t - based upon measurement of total recoverable metal. February 2021 Water Quality and Landfill Gas Monitoring Report March 11, 2021 WCU Closed MSWLF Wood Project 6252-15-0221 FIGURES �hth' BM LHT 1( * J rf �l N �- _ _ �~. I - i l^- . ��_- i_,...i� • h J`����--ti f /� ,gyp yBPI LHT Tr'-- • BM"LHT631. f .��� �� r � —may, Fpea � � �•S, �, •_..� +r Ir0i1Qf' / a %r l�'• .f /�.. ��; � �ti � _ f �i �� 'i• �_ I j. "ro r � _ 1. ��,_ •l - -. ' a' �� '�:� �� � ���� % _�_l` - •..,I{- '•.. l�Fi�l...'as + �f j�.l�`.,'- I _ •-`�,pp --=---f�¢a --�J r��a'���� f ������ f I dam% i /\��_ � \ �� - _O •�.a- 6 �•zsoa..fir E ~ 9_.�.`�\ \ �— ;� `� = �f�N si�y, IR" s • � :n� 'i �' =_, _ �\~� ,� . fir- _ ■°: -s r ♦ SYLVA SOUTH, N.C. QUADRANGLE 35083-C2-TF-024 N.C. DMA 4354 1 SW -SERIES V842 PRINTED 1946 PHOTOREVISED 1990 QUADRANGLE LOCATION NOTE: SITE BOUNDARY IS APPROXIMATE. CONTOUR INTERVAL 40 FEET GRAPHIC SCALE FEET wood 2,000 1,000 0 2,000 4,000 TOPOGRAPHIC SITE MAP DRAWN: RMC DATE: FEB. 2020 DFT CHECK: MEW SCALE: 1" = 2,000' WCU CLOSED MSWLF ENG CHECK: -- JOB: 6252-15-0221 MONTEITH GAP ROAD CULLOWHEE, NORTH CAROLINA APPROVAL: MEW FIG: 1 4~ v EO tea' 1 February 2021 Water Quality and Landfill Gas Monitoring Report March 11, 2021 WCU Closed MSWLF Wood Project 6252-15-0221 LANDFILL GAS MONITORING DATA FORM NC Division of Waste Management - Solid Waste Section Landfill Gas Monitoring Data Form Notice: This farm and any information attached to it are 'Public Records"as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Facility Name:_ W_$WL� Permit Number: Sampling Date:Z 10 +/Zo7 ? NC Landfill Rule (.0500 or.1600): _ Sample Collector Name & Position: kdok'?-, ". C/Q.rk- SO. o-1 0506 Gas Meter Type & Serial Number- 15000 -,- 50513!Y Gas Meter Calibration Date: 2! Z! Field Calibration Date & Time: -O/-t C) ZG 0-7 Field Calibration Gas Type (15115 or 35/50): Field Calibration Gas Canister Expiration Date: 0 1 Z Z Gas Meter Pump Rate: v� n Ambient Air Temperature: 6-2- eOC Barometric Pressure in or mm Hg): 2;.Q5 Weather Conditions: Instructions: Under "Location or LFG Well", list monitoring well # or describe monitoring location (e,g., inside field office). Attach a test location map or drawing. Report methane readings as both % LEL and % CH4 by volume. Convert % CH4 (by volume) to % LEL as follows: % methane (by volume) x 20 = % LEL. *Hydrogen Sulfide (H2S) gas monitoring nut), be required, for Consouction c& Demolition Landfills (CDLFs). See individual permit conditions and/or Facility LFG monitoring plan. Location or Sample Time LFG Well ID rube Purge Time of Day Pumped (see) Initial % LEL Stabilized % LEL % CH4 (volume) �/q 02 % C( (volume) (volur 0 0 2'. p 4-30. LG-1 60 1 3:yC 6'0 O 0 D.a3•- LG 60 p 0 0.0 17.9 p a L�-35 GU 1 q-10 60 p G C.o 1,3 GG-3a 6 0 �'4.45 60 0 c� a. G 11,5 Go 114 :2S 60 o p O. o 5. 2 '--1 . 6o 2q: 35 60 L7 0.0 ZS• ' J c — 6o iy: ys -6o o a a. o . �-G- 6 0 13:5,s 6'a 6 p o. a ?S.6 Z•6 NOTE: If needed, attach additional dataforms to include additional LFG monitoring data locations for the facility. 12 le) % H2S* (volume) NOTES � 4 0 G a a G a a ACTION LEVELS: Methane: >1.25% by volume (inside structures) AND >5% by volume (at facility boundary) Hydrogen Sulfide: >I % by volume (inside structures) AND >4gf by volume (at facility boundary) Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. I am aware that there are significant penalties for making any false statement, representation, or certifca ' luding the possibility of a fine and imprisonment. SIGNATURE — r ��` �r o-�c 5,s 0,c TITLE Revised—February4, 2020 CALIBRATION LOG LANDTEC - GEM 5000+ ES # 1715 uaunrateo materials re uirect METHANE Lot: 304-401897333-1 OXYGEN Lot: 304-401746560-1 HIGH Exp: 8/31/2024 LOW Exp: 8/31/2024 METHANE Lot: 304-401897310-1 CARBON Lot: 304-401897308-1 LOW Exp: 8/31/2024 MONOXIDE Exp: 8/31/2024 OXYGEN Lot: 304-401898357-1 HYDROGEN Lot: 304-401877702-1 HIGH Exp: 11/4/2024 SULFIDE Exp: 8/4/2022 Carbon Filter Saturation (CH4) - Condition: PASS Gas Calibration Check Performed at Room Temperature SENSOR Initial Reading CAL Reading Tolerance Comments CH4 °/n) 0.0 0.0 +/- 0.5 % CO (ppm) 0.0 0.0 +/- 5 vvm SENSOR I Initial Reading I CAL Reading I Tolerance I Comments SENSOR I Initial Reading I CAL Reading I Tolerance I Comments SENSOR Initial Reading CAL Reading Tolerance Comments 02 (%) 21.2 20.9 SENSOR Initial Reading CAL Reading Tolerance Comments 02 (%) 3.9 4.0 +/- 0.5% SENSOR Initial Reading CAL Reading Tolerance Comments CO ( m) 1011 1000 +/- 50 m SENSOR initial Readin CAL Reading Tolerance Comments 1-12S (ppm) 205 200 +/- 10 ppm Signature: RQA Date: 02/08/2021. February 2021 Water Quality and Landfill Gas Monitoring Report March 11, 2021 WCU Closed MSWLF Wood Project 6252-15-0221 /_1»4011911:41:3 GROUNDWATER SAMPLING LOGS FIELD DATA RECORD - LOW FLOW GROUNDWATER SAMPLING PROJECT Western Carolina University JOB NUMBER 6252-15-0221.05 DATE WELL I SAMPLE NUMBER` ACTIVITY TIME START �,� END d . 1/ TIME (Sample time) � QC /" SAMPLES COLLECTED / ASSOCIATED TRIP BLANK WATER LEVEL / PUMP DATA INITIAL FINAL DTW If TOC DTW SCREEN INTERVAL ft TOC DEPTH VOLUME PURGED allons ft TOC SUBMERSIBLE PUMP PERISTALTIC PUMP PURGE DATA TIME DTW ri PURGE RATE Llmin) TEMP (C° H ORP tm(MS/cm) SPECIFIC CONDUCTIVITY TURBIDITY NTU) DO (m IL COMMENTS -22- 0.o46 6,81 7.0q loH4- 61_E5 (Z I� aG� '� 0,0.22- �$ �! (0 `� ire qrl -It l to,, 5:3 7®. `( 326 t ��. �. (� t) 112 1.2 [3, -,dci (.2 (1.oq 1 -3 C, c�.v2 � (, � �.s -7(. o,� p�`w ANALYSES: Appendix I VOCs via 8260, 1,4-Dioxane via 8260 SIM and Appendix I Metals via 6020 NOTES: SIGNATURE: FIELD DATA RECORD - LOW FLOW GROUNDWATER SAMPLING PROJECT Western CarOl€na University JOB NUMBER 1 6252-15-0221.06 DATE WELL 1 SAMPLE NUMBER s ACTIVITY TIME SMART l , S� END ,+ - TIME S (Sample time) QC SAMPLES COLLECTED •T< ASSOCIATED TRIP BLANK P WATER LEVEL l PUMP DATA SUBMERSIBLE PUMP PERISTALTIC PUMP INITIAL I FINAL •1 VOLUME DTW ®. 15 ft TOC DTW - •L ft TOC PURGED 90011si SCREENEINTERVAL 50' DEPTH- fl TPUMP OC PURGE DATA PURGE SPECIFIC DTW RATE TEMP ORP CONDUCTIVITY TURBIDITY DO 3I.18 o.3 -5 14.25 c+, G 5 Z E o o. r L I 2 �.� �- J4,6-j 3a.S2, 0.""5 l4.7,1 c-,5 D, 218 0'2-1 tcp900 3i.`so (9,)5 lY`43 (, 4,4(o 2?"C+� 0,1 1 � C �6 �.z� �•3� �,�`� .c+ L q0 S,,zi )3 ?-(4 0, ),5 - 211 0.1 c4 0,0 2.1 b 3 c9 C+-47� 29- 5 0, E J '-) C9. lq:,Iv '�35- o.37 .35 FO, l L-1 YSES: Appendix I VOCs via 8260, 1,4-Dloxane via 8260 SIM and Appendix I Metals via 6020 I NOTES: FIELD DATA RECORD - LOW FLOW GROUNDWATER SAMPLING PROJECT Western Carolina University JOB NUMBER 6252-15-0221.05 DATE h f 2} WELL I SAMPLE NUMBER �V " ACTIVITY TIME START 1 5-,' O '5 Elf❑ TIME (sample times OC SAMPLES COLLECTED 0 ASSOCIATED TRIP BLANK 0 1 WATER LEVEL I PUMP DATA INITIAL I FINAL DTW g 1 ft (TOG DTW SCREENED INTERVAL p �! o ft TQG PUMP DEPTH VOLUME PURGED H TDC SUBMERSIBLE PUMP PERISTALTIC PUMP (PURGE DATA TIMELlmin EDTW PURGE RATE TEMP C° H ORP mV SPECIFIC CONDUCTIVITY mSlcrn TURBIDITY NTU DO m !L COMMENTS to 0. l4', off $S �o D- �(4: Gic� c�v2a C4.2,�L od 8 0.o i0 0- d 1,2 L,s*, �o �l.�S o kc1: of k - 8 5 0_ 8 5 1. 1 4, 48 4,2 $5' .1 R 5 0- 0 �.22 ANALYSES; Appendix I VOCs via 8260, 1,4-Dioxane via 8260 SIM and Appendix 1 Metals via 6020 ol NOTES: SIGNATURE;..,"4 ., �" FIELD DATA RECORD - LOW FLOW GROUNDWATER SAMPLING PROJECT Western Carolina University I JOB NUMBER 6252-15-0221.06 WELL ! SAMPLE NUMBER ACTIVITY TIME START !/ L2 END �2' QC SAMPLES COLLECTED ASSOCIATED TRIP BLANK 6 DATE TIME (sample time) WATER LEVEL 1 PUMP DATA �/ DTW INITIAL p ft OC DTW �' ` ft TOC PURGED gallons SCREENED j>Ty 21, PUMP INTERVAL DEPTH ftTOC SUBMERSIBLE PUMP= PERISTALTIC PUMP PURGE DATA TIME DTW (R) PURGE RATE Llmin TEMP C° H ORP (mV) SPECIFIC CONDUCTIVITY (mSICm TURBIDITY NTU DO m !L COMMENTS 12.rZ4 Z56 ©•oIp o, o 4,13 Z; z TI& ®j�; 12.EO Z4 o.n 7 E3�• �+.3 p�;Lo 7.2 0-1� v ,Z 4 4 @? o.O�7`1 o, o 0.05 15,E C�, 0.0 ? cl 0-0 �. .1 0.0 f6� 0.3 & 4.1a ZG '� o. ®9® d. 1 _ G14 ANALYSES: Appendix I VOCs via 8260, 1,4-Dioxane via 8260 S I M and Appendix I Metals via 6020 NOTES: w SIGNATURE: , FIELD DATA RECORD - LOW FLOW GROUNDWATER SAMPLING PROJECT Western Carolina university JOB NUMBER 6252-15-0221.015 DATE WELL I SAMPLE NUMBER ��� ACTIVITYTIME START END TIME (sample 41me) QC SAMPLES COLLECTED VI- ASSOCIATED TRIP BLANK DATA INITIAL FINAL VOLUME ft TOG DTW D ft TOC PURGED allons SCREENED PUMP INTERVAL DEPTH ft TOG SUBMERSIBLE PUMP= PERISTALTIC PUMP PURGE DATA E TIME DTW (ft) PURGE RATE Umin TEMP C° H ORP m SPECIFIC CONDUCTIVITY TURBIDITY NTU DO m /L COMMENTS � . I1f11 It, ° " �.� �� �yY•ry(mSfcm I � ® �� c� [�/\ -�V ANALYSES: Appendix I VOCs via 8260, 1,A-Divxane via 8260 SIM and Appendix I Metals via 0020 NOTES: SIGNATUR FIELD DATA RECORD - LOW FLOW GROUNDWATER SAMPLING PROJECT Western Carolina University JOB NUMBER 6252-15-0221.06 DATE z/9le) WELL I SAMPLE NUMBER W r ACTIVITY TIME START 2 ®� END � Z - � � TIME 7 �- s )O (sample time) QC SAMPLES COLLECTED -F.N'J :/:A:= ASSOCIATED TRIP BLANK WATER LEVEL LRD� INITIAL FINAL VOLUME DTW ft TOC DTW ft TOC ' PURGED .., aN allons SCREENED PUMP INTERVAL DEPTH ft TOC� SUBMERSIBLE PUMP= PERISTALTIC PUMP PURGE DATA TIME DTW (tt) PURGE RATE Llmin) TEMP pH ORP (m SPECIFIC CONDUCTIVITY mSlcm TURBIDITY NTU DO m IL COMMENTS ANALYSES: Appendix I VQCs via 8260, 1,4Dioxane via 8260 SIM and Appendix I Metals via 6020 NOTES: SIGNATURE;. -- Check 100% CALIBRATION LOG HORIBA U52 Replace Date: 01/01/2021 ,DO Membrane ConditionReplace D,4/21/2016 pH Internal SolutionCondition \' `"e1, -/ ,- Date: : '�� '� l �C�i: �L .., � \, .,,. � \ Calibration Sta1; 1 � � " \ do Lot # �a �t � ti s � RtR��` e. Exp.Date '. 1 �,° : � •'°' "s w �`:��'a���Z..:1 �:B i'°°:a � �.cv? Calibration '. 1 u pH 4.00 8010228 1 i II pH 7.00 8009698 10/14/2022 6.44 19.31 7.00 Lot # Exp. Date Initial Reading Temp. °C --- --- 0.000 18.75 7002266 2/25/2022 681 19.14 7906275 6/30/2021 4.99 19.07 7002267 2/25/2022 54.4 18.85 inHG mmHG Initial Reading Temp. °C 742.7 93. l % 22.00 Calibration Reading 97.7% Calibration Standard Lot # Exp. Date Initial Reading Temp. °C Calibration Readnnj 0.0 NTU 14202 10/17/2021 0.0 18.43 0.0 100 NTU LC262901 3/4/2021 94.4 18.82 100 800 NTU LC262901 3/4/2021 782 19.13 800 Calibration Standard Lot # Exp. Date Initial Reading Temp. GC Calibration Reading 200 mVolts 8010609 8/9/2021 190 18.97 200 are: fz DATE: 02/4/2021 FIELD INSTRUMENT CALIBRATION RECORD Project Name: Western Carolina University - Closed MSWLF Date: ZI Project Number: 6252-15-0221,06 Name: R.Mc Water Quality Meter Calibration „ Standard Value Meter Value Acceptance „Criteria Manufacturer: 02/ ^� �r)ft SU (low) pH: J SU +1- 10% of standard Model No.: ��C S pH:_,4 5 D SU (med) pH: -A 0 0 SU +/- 10% of standard Unit ID: ��5" % _ � % _5 1 pH: SU (high) pH: SU +1- 10% of standard Conductivity: 4 `4a mslcm Conductivity: . m5/cm +l- 10% of standard Thermometer Temperature: C. Temperature: .`� C° +/- 2.0 C' Turbidity Meter Calibration Standard Value Meter Value Acce Mance Criteria Manufacturer: 0 . U NTU (low) +� . [;1 NTU +l- 10% of standard Model No.: NTU (med) NTU +1- 10% of standard Unit ID: NTU (high) NTU +1- 10% of standard NTU (high) NTU +l- 10% of standard Photoionization Detector Acceptance Criteria Manufacturer: Background: ppmv Meter: ppmv within 5 ppmv of Zero Model No.: Span Gas: ppmv Meter: ppmv +/_ 10% of standard Unit ID: Calibration Sources Source Value Lot Number Ex iration Date pH (low) G�f�=d Sv�� ��7Lu CA=00 SU pH (med) SU pH (high) SU Conductivity��'� mSlcm Turbidity (low) �. NTU I 1 Turbidity (med): NTU Turbidity (high): NTU Turbidity (high): NTU PID gas: _ppmv QXt %r• 04"f �ej. %:,�r lid C- ��f �.� 801 060(1 � � � -?'' NOTES: If a meter reading is not within acceptance criteria, clean or replace probe and re -calibrate, or use a different meter if available. If project requirements necessitate use of the instrument, clearly document on all data sheets and log book entries that the parameter was not calibrated to the acceptance criteria. February 2021 Water Quality and Landfill Gas Monitoring Report March 11, 2021 WCU Closed MSWLF Wood Project 6252-15-0221 APPENDIX C NCDEQ ENVIRONMENTAL MONITORING REPORTING FORM I pENR USE ONLYt ❑Paper Repori ❑Electronic Data - Email CD (data loaded: Yes 1 No) DoclEvent#: ANC DENR I IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: • Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Wood Environment & Infrastructure Solutions, Inc. Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Rodney Clark E-mail: rodney.clark@woodpic.com Phone: 828-252-8130 NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Western Carolina University Monteith Gap Road (State Road 1336) 50-01 0.0500 February 9 - 10, 2021 MSW Landfill Cullowhee, Jackson County, NC 28723 Environmental Status: (Check all that apply) ❑ InitiallBackground Monitoring 7XX Detection Monitoring XC� Assessment Monitoring ❑ Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑X Methane gas monitoring data Groundwater monitoring data from private water supply wells El Corrective action data (specify) Leachate monitoring data Surface water monitoring data Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Rodney Clark, LG Technical Professional II (828) 252-8130 Facility Repawentative Name (Print) Title (Area Code) Telephone Number Signature 1308 Patton Avenue, Asheville, NC 28806 Facility Representative Address F-1253 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 612009 Date Affix NC Licensed/ Professigpal Geoloqist Seal February 2021 Water Quality and Landfill Gas Monitoring Report March 11, 2021 WCU Closed MSWLF Wood Project 6252-15-0221 /_1»4►1971:4191 LABORATORY ANALYTICAL REPORT Waypointo ANALYTICAL 2/17/2021 Wood Environ. & Infrastructure Inc (Asheville) Greg Hutchins 1308 Patton Avenue (Suite C) Asheville, NC, 28806 Ref: Analytical Testing Lab Report Number: 21-041-0025 Client Project Description: WCU-MSWLF Dear Greg Hutchins: 449 5pringbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Waypoint Analytical, LLC (Charlotte) received sample(s) on 2/10/2021 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2012) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, a'-1 Angela D Overcash Senior Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 52 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date North Carolina State Program 37735 07/31/2021 North Carolina State Program 402 12/31/2021 South Carolina State Program 99012 07/31/2021 South Carolina State Program 99012 12/31/2020 Page 1 of 1 00016/21-041-0025 Page 2 of 52 Waypoint, (D 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointana lyti ca Isom Sample Summary Table Report Number: 21-041-0025 Client Project Description: WCU-MSWLF Lab No Client Sample ID Matrix Date Collected Date Received 92419 TB-1 Aqueous 02/09/2021 02/10/2021 07:35 92420 FD-1 Aqueous 02/09/2021 02/10/2021 07:35 92421 MW-1 Aqueous 02/09/2021 11:10 02/10/2021 07:35 92422 SW-2 Aqueous 02/09/2021 12:10 02/10/2021 07:35 92423 MW-4 Aqueous 02/09/2021 12:30 02/10/2021 07:35 92424 SW-1 Aqueous 02/09/2021 13:15 02/10/2021 07:35 92425 MW-2 Aqueous 02/09/2021 14:30 02/10/2021 07:35 92426 EB-1 Aqueous 02/09/2021 14:45 02/10/2021 07:35 92433 MW-3 Aqueous 02/09/2021 15:40 02/10/2021 07:35 Page 3 of 52 Waypoint'(D 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTIC L www.waypointanalytica I som Summary of Detected Analytes Project: WCU-MSWLF Report Number: 21-041-0025 Client Sample ID Method Lab Sample ID Parameters Result Units Report Limit Analyzed Qualifiers FD-1 V 92420 6020B Antimony 0.631 pg/L 0.491 02/15/202117:42 J 6020E Arsenic 0.315 Ng/L 0.170 02/15/202117:42 J 6020E Barium 118 pg/L 0.811 02/15/202117:42 6020B Cobalt 8.77 Ng/L 0.521 02/15/202117:42 6020B Nickel 2.71 pg/L 0.511 02/15/202117:42 J 8260D Benzene 0.509 Ng/L 0.048 02/12/202117:54 8260D Chlorobenzene 9.24 pg/L 0.062 02/12/202117:54 8260D 1,2-Dichlorobenzene 0.203 Ng/L 0.076 02/12/202117:54 J 8260D 1,4-Dichlorobenzene 2.20 pg/L 0.050 02/12/202117:54 8260D cis- 1,2-Dichloroethene 1.47 Ng/L 0.056 02/12/202117:54 MW-1 V 92421 6020B Arsenic 0.170 pg/L 0.170 02/15/202118:14 J 6020B Barium 35.1 Ng/L 0.810 02/15/202118:14 6020B Nickel 1.12 pg/L 0.510 02/15/202118:14 J SW-2 V 92422 6020E Arsenic 0.251 Ng/L 0.170 02/15/202118:20 J 6020E Barium 140 pg/L 0.810 02/15/202118:20 6020E Cobalt 5.41 Ng/L 0.520 02/15/202118:20 6020B Nickel 0.915 Ng/L 0.510 02/15/202118:20 J 8260D Benzene 0.202 Ng/L 0.048 02/12/202119:02 J 8260D Chlorobenzene 2.48 pg/L 0.062 02/12/202119:02 8260D 1,4-Dichlorobenzene 0.621 Ng/L 0.050 02/12/202119:02 8260D SIM 1,4-Dioxane 2.30 pg/L 0.139 02/16/2021 14:39 MW-4 V 92423 6020B Arsenic 0.183 Ng/L 0.171 02/15/202118:39 J 6020B Barium 30.5 pg/L 0.814 02/15/202118:39 8260D Chlorobenzene 0.477 Ng/L 0.062 02/12/202119:36 J SW-1 V 92424 6020B Arsenic 0.443 pg/L 0.170 02/15/202118:46 J 6020E Barium 309 Ng/L 0.810 02/15/202118:46 6020E Cadmium 0.207 pg/L 0.160 02/15/202118:46 J 6020B Cobalt 6.82 Ng/L 0.520 02/15/202118:46 6020B Copper 7.46 pg/L 3.80 02/15/202118:46 J 6020B Lead 3.66 Ng/L 0.260 02/15/202118:46 Page 4 of 52 Waypoint'(D 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTIC L www.waypointanalytica Isom Summary of Detected Analytes Project: WCU-MSWLF Report Number: 21-041-0025 Client Sample ID Lab Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers SW-1 V 92424 6020B Nickel 5.57 pg/L 0.510 02/15/202118:46 6020B Zinc 19.1 Ng/L 6.91 02/15/202118:46 8260D Chlorobenzene 1.20 pg/L 0.062 02/12/202120:10 8260D 1,4-Dichlorobenzene 0.542 Ng/L 0.050 02/12/202120:10 8260D Tetrahydrofuran 3.43 pg/L 1.10 02/12/202120:10 8260D SIM 1,4-Dioxane 3.93 Ng/L 0.139 02/16/2021 15:29 MW-2 V 92425 6020B Arsenic 0.177 pg/L 0.171 02/15/202118:52 6020B Barium 86.0 Ng/L 0.813 02/15/202118:52 6020B Nickel 1.18 pg/L 0.512 02/15/202118:52 EB-1 V 92426 6020B Arsenic 0.213 Ng/L 0.170 02/15/202118:58 6020B Barium 17.5 pg/L 0.810 02/15/202118:58 6020E Copper 7.95 Ng/L 3.80 02/15/202118:58 6020E Nickel 3.10 pg/L 0.510 02/15/202118:58 6020B Zinc 35.6 Ng/L 6.90 02/15/202118:58 8260D Chloroform 0.583 pg/L 0.076 02/12/202117:20 MW-3 V 92433 6020B Arsenic 0.310 Ng/L 0.170 02/15/202119:05 6020B Barium 117 pg/L 0.810 02/15/202119:05 6020B Cobalt 8.88 Ng/L 0.520 02/15/202119:05 6020B Nickel 2.75 pg/L 0.510 02/15/202119:05 8260D Benzene 0.458 Ng/L 0.048 02/12/202121:18 8260D Chlorobenzene 10.0 pg/L 0.062 02/12/202121:18 8260D 1,4-Dichlorobenzene 2.36 Ng/L 0.050 02/12/202121:18 8260D cis- 1,2-Dichloroethene 1.66 pg/L 0.056 02/12/202121:18 0 0 J J J J 0 0 Page 5 of 52 Waypointo ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Greg Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU-MSWLF Report Date : 02/17/2021 Received : 02/10/2021 Report Number : 21-041-0025 REPOR T OF A NA L YSIS Lab No : 92419 Matrix: Aqueous Sample ID: TB-1 Sampled: 2/9/2021 0:00 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane <0.139 Ng/L 0.139 2.00 1 02/16/21 13:23 TBL 8260D SIM Surrogate:4-Bromofluorobenzene 96.8 Limits:70-130% 1 02/16/2113:23 TBL V636 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value L Limit Exceeded MQL Method Quantitation Limit Page 6 of 52 ■ Waypoint 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU-MSWLF Greg Hutchins Report Date : 02/17/2021 1308 Patton Avenue (Suite C) Information : Received : 02/10/2021 Asheville , NC 28806 Report Number : 21-041-0025 REPOR T OF A NA L YSIS Lab No : 92419 Matrix: Aqueous Sample ID: TB-1 Sampled: 2/9/2021 0:00 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <0.310 N9/L 0.310 5.00 1 02/12/21 16:45 JLB V577 Acrylonitrile <0.200 pg/L 0.200 20.0 1 02/12/21 16:45 JLB V577 Benzene <0.048 N9/L 0.048 0.500 1 02/12/21 16:45 JLB V577 Bromochloromethane <0.140 pg/L 0.140 0.500 1 02/12/21 16:45 JLB V577 Bromodichloromethane <0.062 N9/L 0.062 0.500 1 02/12/21 16:45 JLB V577 Bromoform <0.040 pg/L 0.040 1.00 1 02/12/21 16:45 JLB V577 Bromomethane <0.180 N9/L 0.180 1.00 1 02/12/21 16:45 JLB V577 Carbon Disulfide <0.075 pg/L 0.075 5.00 1 02/12/21 16:45 JLB V577 Carbon Tetrachloride <0.110 N9/L 0.110 0.500 1 02/12/21 16:45 JLB V577 Chlorobenzene <0.062 pg/L 0.062 0.500 1 02/12/21 16:45 JLB V577 Chlorodibromomethane <0.081 N9/L 0.081 0.500 1 02/12/21 16:45 JLB V577 Chloroethane <0.220 pg/L 0.220 0.500 1 02/12/21 16:45 JLB V577 Chloroform <0.076 N9/L 0.076 0.500 1 02/12/21 16:45 JLB V577 Chloromethane <0.079 pg/L 0.079 0.500 1 02/12/21 16:45 JLB V577 Di -Isopropyl Ether(DIPE) <0.960 N9/L 0.960 5.00 1 02/12/21 16:45 JLB V577 1,2-Dibromo-3-Chloropropane <0.170 pg/L 0.170 2.00 1 02/12/21 16:45 JLB V577 1,2-Dibromoethane <0.051 N9/L 0.051 0.500 1 02/12/21 16:45 JLB V577 Dibromomethane <0.065 pg/L 0.065 0.500 1 02/12/21 16:45 JLB V577 trans-1,4-Dichloro-2-butene <0.120 N9/L 0.120 10.0 1 02/12/21 16:45 JLB V577 1,2-Dichlorobenzene <0.076 pg/L 0.076 0.500 1 02/12/21 16:45 JLB V577 1,4-Dichlorobenzene <0.050 N9/L 0.050 0.500 1 02/12/21 16:45 JLB V577 Dichlorodifluoromethane <0.110 pg/L 0.110 5.00 1 02/12/21 16:45 JLB V577 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 7 of 52 ■ Waypoint 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU-MSWLF Greg Hutchins Report Date : 02/17/2021 1308 Patton Avenue (Suite C) Information : Received : 02/10/2021 Asheville , NC 28806 Report Number : 21-041-0025 REPOR T OF A NA L YSIS Lab No : 92419 Matrix: Aqueous Sample ID: TB-1 Sampled: 2/9/2021 0:00 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.083 N9/L 0.083 0.500 1 02/12/21 16:45 JLB V577 1,2-Dichloroethane <0.066 pg/L 0.066 0.500 1 02/12/21 16:45 JLB V577 1,1-Dichloroethene <0.083 N9/L 0.083 0.500 1 02/12/21 16:45 JLB V577 cis- 1,2-Dich loroethene <0.056 pg/L 0.056 0.500 1 02/12/21 16:45 JLB V577 trans-1,2-Dichloroethene <0.094 N9/L 0.094 0.500 1 02/12/21 16:45 JLB V577 1,2-Dichloropropane <0.110 pg/L 0.110 0.500 1 02/12/21 16:45 JLB V577 cis- 1,3-Dich loropropene <0.079 N9/L 0.079 0.500 1 02/12/21 16:45 JLB V577 trans-1,3-Dichloropropene <0.070 pg/L 0.070 0.500 1 02/12/21 16:45 JLB V577 Ethylbenzene <0.061 N9/L 0.061 0.500 1 02/12/21 16:45 JLB V577 2-Hexanone <0.065 pg/L 0.065 5.00 1 02/12/21 16:45 JLB V577 Methyl Ethyl Ketone (MEK) <0.240 N9/L 0.240 5.00 1 02/12/21 16:45 JLB V577 4-Methyl-2-Pentanone <1.00 pg/L 1.00 5.00 1 02/12/21 16:45 JLB V577 Methylene Chloride <0.083 N9/L 0.083 1.00 1 02/12/21 16:45 JLB V577 Styrene <0.047 pg/L 0.047 0.500 1 02/12/21 16:45 JLB V577 1,1,1,2-Tetrachloroethane <0.110 N9/L 0.110 0.500 1 02/12/21 16:45 JLB V577 1,1,2,2-Tetrachloroethane <0.036 pg/L 0.036 0.500 1 02/12/21 16:45 JLB V577 Tetrachloroethene <0.098 N9/L 0.098 0.500 1 02/12/21 16:45 JLB V577 Tetrahydrofuran <1.10 pg/L 1.10 10.0 1 02/12/21 16:45 JLB V577 Toluene <0.044 N9/L 0.044 0.500 1 02/12/21 16:45 JLB V577 1,1,1-Trichloroethane <0.061 pg/L 0.061 0.500 1 02/12/21 16:45 JLB V577 1,1,2-Trichloroethane <0.066 N9/L 0.066 0.500 1 02/12/21 16:45 JLB V577 Trichloroethene <0.078 pg/L 0.078 0.500 1 02/12/21 16:45 JLB V577 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 8 of 52 Waypointo ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Greg Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU-MSWLF Report Date : 02/17/2021 Received : 02/10/2021 Report Number : 21-041-0025 Lab No : 92419 Sample ID: TB-1 REPOR T OF A NA L YSIS Matrix: Aqueous Sampled: 2/9/2021 0:00 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Trichlorofluoromethane <0.062 N9/L 0.062 0.500 1 02/12/21 16:45 JLB V577 1,2,3-Trichloropropane <0.140 u9/L 0.140 1.00 1 02/12/21 16:45 JLB V577 Vinyl Acetate <0.060 N9/L 0.060 2.00 1 02/12/21 16:45 JLB V577 Vinyl Chloride <0.097 u9/L 0.097 0.500 1 02/12/21 16:45 JLB V577 o-Xylene <0.044 N9/L 0.044 0.500 1 02/12/21 16:45 JLB V577 m,p-Xylene <0.120 u9/L 0.120 1.00 1 02/12/21 16:45 JLB V577 Xylene (Total) <0.044 N9/L 0.044 0.500 1 02/12/21 16:45 KCC V577 Surrogate:4-Bromofluorobenzene 95.4 Limits:80-124% 1 02/12/21 16:45 JLB V577 Surrogate: Dibromofluoromethane 102 Limits: 75-129% 1 02/12/21 16:45 JLB V577 Surrogate: 1,2-Dichloroethane - d4 108 Limits: 63-136% 1 02/12/21 16:45 JLB V577 Surrogate: Toluene-d8 96.0 Limits: 77-123% 1 02/12/21 16:45 JLB V577 Qualifiers/ B Analyte detected in blank Definitions J Estimated value DF Dilution Factor MQL Method Quantitation Limit Page 9 of 52 Waypointo ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Greg Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU-MSWLF Report Number : 21-041-0025 REPOR T OF A NA L YSIS Report Date : 02/17/2021 Received : 02/10/2021 Lab No : 92420 Sample ID : FD-1 Matrix: Aqueous Sampled: 2/9/2021 0:00 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Antimony 0.6313 Ng/L 0.491 2.00 1 02/15/21 17:42 JAB 6020B Arsenic 0.3153 ug/L 0.170 1.00 1 02/15/21 17:42 JAB 6020B Barium 118 Ng/L 0.811 10.0 1 02/15/21 17:42 JAB 6020B Beryllium <0.190 ug/L 0.190 1.00 1 02/15/21 17:42 JAB 6020B Cadmium <0.160 Ng/L 0.160 1.00 1 02/15/21 17:42 JAB 6020B Chromium <0.791 ug/L 0.791 2.00 1 02/15/21 17:42 JAB 6020B Cobalt 8.77 Ng/L 0.521 2.00 1 02/15/21 17:42 JAB 6020B Copper <3.81 u9/L 3.81 10.0 1 02/15/21 17:42 JAB 6020B Lead <0.261 Ng/L 0.261 1.00 1 02/15/21 17:42 JAB 6020B Nickel 2.71 J ug/L 0.511 3.01 1 02/15/21 17:42 JAB 6020B Selenium <0.741 Ng/L 0.741 5.01 1 02/15/21 17:42 JAB 6020B Silver <0.110 ug/L 0.110 1.00 1 02/15/21 17:42 JAB 6020B Thallium <0.571 Ng/L 0.571 2.00 1 02/15/21 17:42 JAB 6020B Vanadium <1.30 ug/L 1.30 5.01 1 02/15/21 17:42 JAB 6020B Zinc <6.91 Ng/L 6.91 20.0 1 02/15/21 17:42 JAB 6020B 1,4-Dioxane <0.139 ug/L 0.139 2.00 1 02/16/21 13:48 TBL 8260D SIM Surrogate:4-Bromofluorobenzene 87.6 Limits:70-130% 1 02/16/2113:48 TBL V636 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value L Limit Exceeded MQL Method Quantitation Limit Page 10 of 52 ■ Waypoint 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU-MSWLF Greg Hutchins Report Date : 02/17/2021 1308 Patton Avenue (Suite C) Information : Received : 02/10/2021 Asheville , NC 28806 Report Number : 21-041-0025 REPOR T OF A NA L YSIS Lab No : 92420 Matrix: Aqueous Sample ID : FD-1 Sampled: 2/9/2021 0:00 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <0.310 Ng/L 0.310 5.00 1 02/12/21 17:54 JLB V577 Acrylonitrile <0.200 pg/L 0.200 20.0 1 02/12/21 17:54 JLB V577 Benzene 0.509 Ng/L 0.048 0.500 1 02/12/21 17:54 JLB V577 Bromochloromethane <0.140 pg/L 0.140 0.500 1 02/12/21 17:54 JLB V577 Bromodichloromethane <0.062 Ng/L 0.062 0.500 1 02/12/21 17:54 JLB V577 Bromoform <0.040 pg/L 0.040 1.00 1 02/12/21 17:54 JLB V577 Bromomethane <0.180 Ng/L 0.180 1.00 1 02/12/21 17:54 JLB V577 Carbon Disulfide <0.075 pg/L 0.075 5.00 1 02/12/21 17:54 JLB V577 Carbon Tetrachloride <0.110 Ng/L 0.110 0.500 1 02/12/21 17:54 JLB V577 Chlorobenzene 9.24 pg/L 0.062 0.500 1 02/12/21 17:54 JLB V577 Chlorodibromomethane <0.081 Ng/L 0.081 0.500 1 02/12/21 17:54 JLB V577 Chloroethane <0.220 pg/L 0.220 0.500 1 02/12/21 17:54 JLB V577 Chloroform <0.076 Ng/L 0.076 0.500 1 02/12/21 17:54 JLB V577 Chloromethane <0.079 pg/L 0.079 0.500 1 02/12/21 17:54 JLB V577 Di -Isopropyl Ether(DIPE) <0.960 Ng/L 0.960 5.00 1 02/12/21 17:54 JLB V577 1,2-Dibromo-3-Chloropropane <0.170 pg/L 0.170 2.00 1 02/12/21 17:54 JLB V577 1,2-Dibromoethane <0.051 Ng/L 0.051 0.500 1 02/12/21 17:54 JLB V577 Dibromomethane <0.065 pg/L 0.065 0.500 1 02/12/21 17:54 JLB V577 trans-1,4-Dichloro-2-butene <0.120 Ng/L 0.120 10.0 1 02/12/21 17:54 JLB V577 1,2-Dichlorobenzene 0.2033 pg/L 0.076 0.500 1 02/12/21 17:54 JLB V577 1,4-Dichlorobenzene 2.20 Ng/L 0.050 0.500 1 02/12/21 17:54 JLB V577 Dichlorodifluoromethane <0.110 pg/L 0.110 5.00 1 02/12/21 17:54 JLB V577 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 11 of 52 ■ Waypoint 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU-MSWLF Greg Hutchins Report Date : 02/17/2021 1308 Patton Avenue (Suite C) Information : Received : 02/10/2021 Asheville , NC 28806 Report Number : 21-041-0025 REPOR T OF A NA L YSIS Lab No : 92420 Matrix: Aqueous Sample ID : FD-1 Sampled: 2/9/2021 0:00 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.083 Ng/L 0.083 0.500 1 02/12/21 17:54 JLB V577 1,2-Dichloroethane <0.066 pg/L 0.066 0.500 1 02/12/21 17:54 JLB V577 1,1-Dichloroethene <0.083 Ng/L 0.083 0.500 1 02/12/21 17:54 JLB V577 cis- 1,2-Dich loroethene 1.47 pg/L 0.056 0.500 1 02/12/21 17:54 JLB V577 trans-1,2-Dichloroethene <0.094 Ng/L 0.094 0.500 1 02/12/21 17:54 JLB V577 1,2-Dichloropropane <0.110 pg/L 0.110 0.500 1 02/12/21 17:54 JLB V577 cis- 1,3-Dich loropropene <0.079 Ng/L 0.079 0.500 1 02/12/21 17:54 JLB V577 trans-1,3-Dichloropropene <0.070 pg/L 0.070 0.500 1 02/12/21 17:54 JLB V577 Ethylbenzene <0.061 Ng/L 0.061 0.500 1 02/12/21 17:54 JLB V577 2-Hexanone <0.065 pg/L 0.065 5.00 1 02/12/21 17:54 JLB V577 Methyl Ethyl Ketone (MEK) <0.240 Ng/L 0.240 5.00 1 02/12/21 17:54 JLB V577 4-Methyl-2-Pentanone <1.00 pg/L 1.00 5.00 1 02/12/21 17:54 JLB V577 Methylene Chloride <0.083 Ng/L 0.083 1.00 1 02/12/21 17:54 JLB V577 Styrene <0.047 pg/L 0.047 0.500 1 02/12/21 17:54 JLB V577 1,1,1,2-Tetrachloroethane <0.110 Ng/L 0.110 0.500 1 02/12/21 17:54 JLB V577 1,1,2,2-Tetrachloroethane <0.036 pg/L 0.036 0.500 1 02/12/21 17:54 JLB V577 Tetrachloroethene <0.098 Ng/L 0.098 0.500 1 02/12/21 17:54 JLB V577 Tetrahydrofuran <1.10 pg/L 1.10 10.0 1 02/12/21 17:54 JLB V577 Toluene <0.044 Ng/L 0.044 0.500 1 02/12/21 17:54 JLB V577 1,1,1-Trichloroethane <0.061 pg/L 0.061 0.500 1 02/12/21 17:54 JLB V577 1,1,2-Trichloroethane <0.066 Ng/L 0.066 0.500 1 02/12/21 17:54 JLB V577 Trichloroethene <0.078 pg/L 0.078 0.500 1 02/12/21 17:54 JLB V577 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 12 of 52 Waypointo ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Greg Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU-MSWLF Report Date : 02/17/2021 Received : 02/10/2021 Report Number : 21-041-0025 Lab No : 92420 Sample ID : FD-1 REPOR T OF A NA L YSIS Matrix: Aqueous Sampled: 2/9/2021 0:00 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Trichlorofluoromethane <0.062 Ng/L 0.062 0.500 1 02/12/21 17:54 JLB V577 1,2,3-Trichloropropane <0.140 ug/L 0.140 1.00 1 02/12/21 17:54 JLB V577 Vinyl Acetate <0.060 Ng/L 0.060 2.00 1 02/12/21 17:54 JLB V577 Vinyl Chloride <0.097 ug/L 0.097 0.500 1 02/12/21 17:54 JLB V577 o-Xylene <0.044 Ng/L 0.044 0.500 1 02/12/21 17:54 JLB V577 m,p-Xylene <0.120 ug/L 0.120 1.00 1 02/12/21 17:54 JLB V577 Xylene (Total) <0.044 Ng/L 0.044 0.500 1 02/12/21 17:54 KCC V577 Surrogate:4-Bromofluorobenzene 97.4 Limits:80-124% 1 02/12/21 17:54 JLB V577 Surrogate: Dibromofluoromethane 104 Limits: 75-129% 1 02/12/21 17:54 JLB V577 Surrogate: 1,2-Dichloroethane - d4 101 Limits: 63-136% 1 02/12/21 17:54 JLB V577 Surrogate: Toluene-d8 95.4 Limits: 77-123% 1 02/12/21 17:54 JLB V577 Qualifiers/ B Analyte detected in blank Definitions J Estimated value DF Dilution Factor MQL Method Quantitation Limit Page 13 of 52 Waypointo ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Greg Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU-MSWLF Report Number : 21-041-0025 REPOR T OF A NA L YSIS Report Date : 02/17/2021 Received : 02/10/2021 Lab No : 92421 Sample ID: MW-1 Matrix: Aqueous Sampled: 2/9/2021 11:10 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Antimony <0.490 Ng/L 0.490 2.00 1 02/15/21 18:14 JAB 6020B Arsenic 0.170J ug/L 0.170 1.00 1 02/15/21 18:14 JAB 6020B Barium 35.1 N9/L 0.810 10.0 1 02/15/21 18:14 JAB 6020B Beryllium <0.190 u9/L 0.190 1.00 1 02/15/21 18:14 JAB 6020B Cadmium <0.160 N9/L 0.160 1.00 1 02/15/21 18:14 JAB 6020B Chromium <0.790 u9/L 0.790 2.00 1 02/15/21 18:14 JAB 6020B Cobalt <0.520 N9/L 0.520 2.00 1 02/15/21 18:14 JAB 6020B Copper <3.80 u9/L 3.80 10.0 1 02/15/21 18:14 JAB 6020B Lead <0.260 N9/L 0.260 1.00 1 02/15/21 18:14 JAB 6020B Nickel 1.12J u9/L 0.510 3.00 1 02/15/21 18:14 JAB 6020B Selenium <0.740 N9/L 0.740 5.00 1 02/15/21 18:14 JAB 6020E Silver <0.110 u9/L 0.110 1.00 1 02/15/21 18:14 JAB 6020B Thallium <0.570 N9/L 0.570 2.00 1 02/15/21 18:14 JAB 6020B Vanadium <1.30 u9/L 1.30 5.00 1 02/15/21 18:14 JAB 6020B Zinc <6.90 N9/L 6.90 20.0 1 02/15/21 18:14 JAB 6020B 1,4-Dioxane <0.139 u9/L 0.139 2.00 1 02/16/21 14:14 TBL 8260D SIM Surrogate:4-Bromofluorobenzene 92.8 Limits:70-130% 1 02/16/2114:14 TBL V636 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value L Limit Exceeded MQL Method Quantitation Limit Page 14 of 52 ■ Waypoint 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU-MSWLF Greg Hutchins Report Date : 02/17/2021 1308 Patton Avenue (Suite C) Information : Received : 02/10/2021 Asheville , NC 28806 Report Number : 21-041-0025 REPOR T OF A NA L YSIS Lab No : 92421 Matrix: Aqueous Sample ID: MW-1 Sampled: 2/9/2021 11:10 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <0.310 Ng/L 0.310 5.00 1 02/12/21 18:28 JLB V577 Acrylonitrile <0.200 pg/L 0.200 20.0 1 02/12/21 18:28 JLB V577 Benzene <0.048 Ng/L 0.048 0.500 1 02/12/21 18:28 JLB V577 Bromochloromethane <0.140 pg/L 0.140 0.500 1 02/12/21 18:28 JLB V577 Bromodichloromethane <0.062 Ng/L 0.062 0.500 1 02/12/21 18:28 JLB V577 Bromoform <0.040 pg/L 0.040 1.00 1 02/12/21 18:28 JLB V577 Bromomethane <0.180 Ng/L 0.180 1.00 1 02/12/21 18:28 JLB V577 Carbon Disulfide <0.075 pg/L 0.075 5.00 1 02/12/21 18:28 JLB V577 Carbon Tetrachloride <0.110 Ng/L 0.110 0.500 1 02/12/21 18:28 JLB V577 Chlorobenzene <0.062 pg/L 0.062 0.500 1 02/12/21 18:28 JLB V577 Chlorodibromomethane <0.081 Ng/L 0.081 0.500 1 02/12/21 18:28 JLB V577 Chloroethane <0.220 pg/L 0.220 0.500 1 02/12/21 18:28 JLB V577 Chloroform <0.076 Ng/L 0.076 0.500 1 02/12/21 18:28 JLB V577 Chloromethane <0.079 pg/L 0.079 0.500 1 02/12/21 18:28 JLB V577 Di -Isopropyl Ether(DIPE) <0.960 Ng/L 0.960 5.00 1 02/12/21 18:28 JLB V577 1,2-Dibromo-3-Chloropropane <0.170 pg/L 0.170 2.00 1 02/12/21 18:28 JLB V577 1,2-Dibromoethane <0.051 Ng/L 0.051 0.500 1 02/12/21 18:28 JLB V577 Dibromomethane <0.065 pg/L 0.065 0.500 1 02/12/21 18:28 JLB V577 trans-1,4-Dichloro-2-butene <0.120 Ng/L 0.120 10.0 1 02/12/21 18:28 JLB V577 1,2-Dichlorobenzene <0.076 pg/L 0.076 0.500 1 02/12/21 18:28 JLB V577 1,4-Dichlorobenzene <0.050 Ng/L 0.050 0.500 1 02/12/21 18:28 JLB V577 Dichlorodifluoromethane <0.110 pg/L 0.110 5.00 1 02/12/21 18:28 JLB V577 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 15 of 52 ■ Waypoint 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU-MSWLF Greg Hutchins Report Date : 02/17/2021 1308 Patton Avenue (Suite C) Information : Received : 02/10/2021 Asheville , NC 28806 Report Number : 21-041-0025 REPOR T OF A NA L YSIS Lab No : 92421 Matrix: Aqueous Sample ID: MW-1 Sampled: 2/9/2021 11:10 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.083 Ng/L 0.083 0.500 1 02/12/21 18:28 JLB V577 1,2-Dichloroethane <0.066 pg/L 0.066 0.500 1 02/12/21 18:28 JLB V577 1,1-Dichloroethene <0.083 Ng/L 0.083 0.500 1 02/12/21 18:28 JLB V577 cis- 1,2-Dich loroethene <0.056 pg/L 0.056 0.500 1 02/12/21 18:28 JLB V577 trans-1,2-Dichloroethene <0.094 Ng/L 0.094 0.500 1 02/12/21 18:28 JLB V577 1,2-Dichloropropane <0.110 pg/L 0.110 0.500 1 02/12/21 18:28 JLB V577 cis- 1,3-Dich loropropene <0.079 Ng/L 0.079 0.500 1 02/12/21 18:28 JLB V577 trans-1,3-Dichloropropene <0.070 pg/L 0.070 0.500 1 02/12/21 18:28 JLB V577 Ethylbenzene <0.061 Ng/L 0.061 0.500 1 02/12/21 18:28 JLB V577 2-Hexanone <0.065 pg/L 0.065 5.00 1 02/12/21 18:28 JLB V577 Methyl Ethyl Ketone (MEK) <0.240 Ng/L 0.240 5.00 1 02/12/21 18:28 JLB V577 4-Methyl-2-Pentanone <1.00 pg/L 1.00 5.00 1 02/12/21 18:28 JLB V577 Methylene Chloride <0.083 Ng/L 0.083 1.00 1 02/12/21 18:28 JLB V577 Styrene <0.047 pg/L 0.047 0.500 1 02/12/21 18:28 JLB V577 1,1,1,2-Tetrachloroethane <0.110 Ng/L 0.110 0.500 1 02/12/21 18:28 JLB V577 1,1,2,2-Tetrachloroethane <0.036 pg/L 0.036 0.500 1 02/12/21 18:28 JLB V577 Tetrachloroethene <0.098 Ng/L 0.098 0.500 1 02/12/21 18:28 JLB V577 Tetrahydrofuran <1.10 pg/L 1.10 10.0 1 02/12/21 18:28 JLB V577 Toluene <0.044 Ng/L 0.044 0.500 1 02/12/21 18:28 JLB V577 1,1,1-Trichloroethane <0.061 pg/L 0.061 0.500 1 02/12/21 18:28 JLB V577 1,1,2-Trichloroethane <0.066 Ng/L 0.066 0.500 1 02/12/21 18:28 JLB V577 Trichloroethene <0.078 pg/L 0.078 0.500 1 02/12/21 18:28 JLB V577 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 16 of 52 Waypointo ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Greg Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU-MSWLF Report Date : 02/17/2021 Received : 02/10/2021 Report Number : 21-041-0025 Lab No : 92421 Sample ID: MW-1 REPOR T OF A NA L YSIS Matrix: Aqueous Sampled: 2/9/2021 11:10 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Trichlorofluoromethane <0.062 Ng/L 0.062 0.500 1 02/12/21 18:28 JLB V577 1,2,3-Trichloropropane <0.140 ug/L 0.140 1.00 1 02/12/21 18:28 JLB V577 Vinyl Acetate <0.060 Ng/L 0.060 2.00 1 02/12/21 18:28 JLB V577 Vinyl Chloride <0.097 ug/L 0.097 0.500 1 02/12/21 18:28 JLB V577 o-Xylene <0.044 Ng/L 0.044 0.500 1 02/12/21 18:28 JLB V577 m,p-Xylene <0.120 ug/L 0.120 1.00 1 02/12/21 18:28 JLB V577 Xylene (Total) <0.044 Ng/L 0.044 0.500 1 02/12/21 18:28 KCC V577 Surrogate:4-Bromofluorobenzene 96.2 Limits:80-124% 1 02/12/21 18:28 JLB V577 Surrogate: Dibromofluoromethane 106 Limits: 75-129% 1 02/12/21 18:28 JLB V577 Surrogate: 1,2-Dichloroethane - d4 104 Limits: 63-136% 1 02/12/21 18:28 JLB V577 Surrogate: Toluene-d8 95.4 Limits: 77-123% 1 02/12/21 18:28 JLB V577 Qualifiers/ B Analyte detected in blank Definitions J Estimated value DF Dilution Factor MQL Method Quantitation Limit Page 17 of 52 Waypointo ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Greg Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU-MSWLF Report Number : 21-041-0025 REPOR T OF A NA L YSIS Report Date : 02/17/2021 Received : 02/10/2021 Lab No : 92422 Sample ID: SW-2 Matrix: Aqueous Sampled: 2/9/2021 12:10 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Antimony <0.490 Ng/L 0.490 2.00 1 02/15/21 18:20 JAB 6020B Arsenic 0.251 J u9/L 0.170 1.00 1 02/15/21 18:20 JAB 6020B Barium 140 N9/L 0.810 10.0 1 02/15/21 18:20 JAB 6020B Beryllium <0.190 u9/L 0.190 1.00 1 02/15/21 18:20 JAB 6020B Cadmium <0.160 N9/L 0.160 1.00 1 02/15/21 18:20 JAB 6020B Chromium <0.790 u9/L 0.790 2.00 1 02/15/21 18:20 JAB 6020B Cobalt 5.41 N9/L 0.520 2.00 1 02/15/21 18:20 JAB 6020B Copper <3.80 u9/L 3.80 10.0 1 02/15/21 18:20 JAB 6020B Lead <0.260 N9/L 0.260 1.00 1 02/15/21 18:20 JAB 6020B Nickel 0.9151 ug/L 0.510 3.00 1 02/15/21 18:20 JAB 6020B Selenium <0.740 N9/L 0.740 5.00 1 02/15/21 18:20 JAB 6020B Silver <0.110 u9/L 0.110 1.00 1 02/15/21 18:20 JAB 6020B Thallium <0.570 N9/L 0.570 2.00 1 02/15/21 18:20 JAB 6020B Vanadium <1.30 u9/L 1.30 5.00 1 02/15/21 18:20 JAB 6020B Zinc <6.90 N9/L 6.90 20.0 1 02/15/21 18:20 JAB 6020B 1,4-Dioxane 2.30 u9/L 0.139 2.00 1 02/16/21 14:39 TBL 8260D SIM Surrogate:4-Bromofluorobenzene 96.2 Limits:70-130% 1 02/16/2114:39 TBL V636 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value L Limit Exceeded MQL Method Quantitation Limit Page 18 of 52 ■ Waypoint 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU-MSWLF Greg Hutchins Report Date : 02/17/2021 1308 Patton Avenue (Suite C) Information : Received : 02/10/2021 Asheville , NC 28806 Report Number : 21-041-0025 REPOR T OF A NA L YSIS Lab No : 92422 Matrix: Aqueous Sample ID: SW-2 Sampled: 2/9/2021 12:10 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <0.310 Ng/L 0.310 5.00 1 02/12/21 19:02 JLB V577 Acrylonitrile <0.200 pg/L 0.200 20.0 1 02/12/21 19:02 JLB V577 Benzene 0.2023 Ng/L 0.048 0.500 1 02/12/21 19:02 JLB V577 Bromochloromethane <0.140 pg/L 0.140 0.500 1 02/12/21 19:02 JLB V577 Bromodichloromethane <0.062 Ng/L 0.062 0.500 1 02/12/21 19:02 JLB V577 Bromoform <0.040 pg/L 0.040 1.00 1 02/12/21 19:02 JLB V577 Bromomethane <0.180 Ng/L 0.180 1.00 1 02/12/21 19:02 JLB V577 Carbon Disulfide <0.075 pg/L 0.075 5.00 1 02/12/21 19:02 JLB V577 Carbon Tetrachloride <0.110 Ng/L 0.110 0.500 1 02/12/21 19:02 JLB V577 Chlorobenzene 2.48 pg/L 0.062 0.500 1 02/12/21 19:02 JLB V577 Chlorodibromomethane <0.081 Ng/L 0.081 0.500 1 02/12/21 19:02 JLB V577 Chloroethane <0.220 pg/L 0.220 0.500 1 02/12/21 19:02 JLB V577 Chloroform <0.076 Ng/L 0.076 0.500 1 02/12/21 19:02 JLB V577 Chloromethane <0.079 pg/L 0.079 0.500 1 02/12/21 19:02 JLB V577 Di -Isopropyl Ether(DIPE) <0.960 Ng/L 0.960 5.00 1 02/12/21 19:02 JLB V577 1,2-Dibromo-3-Chloropropane <0.170 pg/L 0.170 2.00 1 02/12/21 19:02 JLB V577 1,2-Dibromoethane <0.051 Ng/L 0.051 0.500 1 02/12/21 19:02 JLB V577 Dibromomethane <0.065 pg/L 0.065 0.500 1 02/12/21 19:02 JLB V577 trans-1,4-Dichloro-2-butene <0.120 Ng/L 0.120 10.0 1 02/12/21 19:02 JLB V577 1,2-Dichlorobenzene <0.076 pg/L 0.076 0.500 1 02/12/21 19:02 JLB V577 1,4-Dichlorobenzene 0.621 Ng/L 0.050 0.500 1 02/12/21 19:02 JLB V577 Dichlorodifluoromethane <0.110 pg/L 0.110 5.00 1 02/12/21 19:02 JLB V577 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 19 of 52 ■ Waypoint 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU-MSWLF Greg Hutchins Report Date : 02/17/2021 1308 Patton Avenue (Suite C) Information : Received : 02/10/2021 Asheville , NC 28806 Report Number : 21-041-0025 REPOR T OF A NA L YSIS Lab No : 92422 Matrix: Aqueous Sample ID: SW-2 Sampled: 2/9/2021 12:10 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.083 Ng/L 0.083 0.500 1 02/12/21 19:02 JLB V577 1,2-Dichloroethane <0.066 pg/L 0.066 0.500 1 02/12/21 19:02 JLB V577 1,1-Dichloroethene <0.083 Ng/L 0.083 0.500 1 02/12/21 19:02 JLB V577 cis- 1,2-Dich loroethene <0.056 pg/L 0.056 0.500 1 02/12/21 19:02 JLB V577 trans-1,2-Dichloroethene <0.094 Ng/L 0.094 0.500 1 02/12/21 19:02 JLB V577 1,2-Dichloropropane <0.110 pg/L 0.110 0.500 1 02/12/21 19:02 JLB V577 cis- 1,3-Dich loropropene <0.079 Ng/L 0.079 0.500 1 02/12/21 19:02 JLB V577 trans-1,3-Dichloropropene <0.070 pg/L 0.070 0.500 1 02/12/21 19:02 JLB V577 Ethylbenzene <0.061 Ng/L 0.061 0.500 1 02/12/21 19:02 JLB V577 2-Hexanone <0.065 pg/L 0.065 5.00 1 02/12/21 19:02 JLB V577 Methyl Ethyl Ketone (MEK) <0.240 Ng/L 0.240 5.00 1 02/12/21 19:02 JLB V577 4-Methyl-2-Pentanone <1.00 pg/L 1.00 5.00 1 02/12/21 19:02 JLB V577 Methylene Chloride <0.083 Ng/L 0.083 1.00 1 02/12/21 19:02 JLB V577 Styrene <0.047 pg/L 0.047 0.500 1 02/12/21 19:02 JLB V577 1,1,1,2-Tetrachloroethane <0.110 Ng/L 0.110 0.500 1 02/12/21 19:02 JLB V577 1,1,2,2-Tetrachloroethane <0.036 pg/L 0.036 0.500 1 02/12/21 19:02 JLB V577 Tetrachloroethene <0.098 Ng/L 0.098 0.500 1 02/12/21 19:02 JLB V577 Tetrahydrofuran <1.10 pg/L 1.10 10.0 1 02/12/21 19:02 JLB V577 Toluene <0.044 Ng/L 0.044 0.500 1 02/12/21 19:02 JLB V577 1,1,1-Trichloroethane <0.061 pg/L 0.061 0.500 1 02/12/21 19:02 JLB V577 1,1,2-Trichloroethane <0.066 Ng/L 0.066 0.500 1 02/12/21 19:02 JLB V577 Trichloroethene <0.078 pg/L 0.078 0.500 1 02/12/21 19:02 JLB V577 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 20 of 52 Waypointo ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Greg Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU-MSWLF Report Date : 02/17/2021 Received : 02/10/2021 Report Number : 21-041-0025 Lab No : 92422 Sample ID: SW-2 REPOR T OF A NA L YSIS Matrix: Aqueous Sampled: 2/9/2021 12:10 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Trichlorofluoromethane <0.062 Ng/L 0.062 0.500 1 02/12/21 19:02 JLB V577 1,2,3-Trichloropropane <0.140 ug/L 0.140 1.00 1 02/12/21 19:02 JLB V577 Vinyl Acetate <0.060 Ng/L 0.060 2.00 1 02/12/21 19:02 JLB V577 Vinyl Chloride <0.097 ug/L 0.097 0.500 1 02/12/21 19:02 JLB V577 o-Xylene <0.044 Ng/L 0.044 0.500 1 02/12/21 19:02 JLB V577 m,p-Xylene <0.120 ug/L 0.120 1.00 1 02/12/21 19:02 JLB V577 Xylene (Total) <0.044 Ng/L 0.044 0.500 1 02/12/21 19:02 KCC V577 Surrogate:4-Bromofluorobenzene 96.0 Limits:80-124% 1 02/12/21 19:02 JLB V577 Surrogate: Dibromofluoromethane 103 Limits: 75-129% 1 02/12/21 19:02 JLB V577 Surrogate: 1,2-Dichloroethane - d4 101 Limits: 63-136% 1 02/12/21 19:02 JLB V577 Surrogate: Toluene-d8 96.6 Limits: 77-123% 1 02/12/21 19:02 JLB V577 Qualifiers/ B Analyte detected in blank Definitions J Estimated value DF Dilution Factor MQL Method Quantitation Limit Page 21 of 52 Waypointo ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Greg Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU-MSWLF Report Number : 21-041-0025 REPOR T OF A NA L YSIS Report Date : 02/17/2021 Received : 02/10/2021 Lab No : 92423 Sample ID: MW-4 Matrix: Aqueous Sampled: 2/9/2021 12:30 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Antimony <0.492 Ng/L 0.492 2.01 1 02/15/21 18:39 JAB 6020B Arsenic 0.183J u9/L 0.171 1.01 1 02/15/21 18:39 JAB 6020B Barium 30.5 Ng/L 0.814 10.1 1 02/15/21 18:39 JAB 6020B Beryllium <0.191 ug/L 0.191 1.01 1 02/15/21 18:39 JAB 6020B Cadmium <0.161 Ng/L 0.161 1.01 1 02/15/21 18:39 JAB 6020B Chromium <0.793 ug/L 0.793 2.01 1 02/15/21 18:39 JAB 6020B Cobalt <0.522 Ng/L 0.522 2.01 1 02/15/21 18:39 JAB 6020B Copper <3.82 ug/L 3.82 10.1 1 02/15/21 18:39 JAB 6020B Lead <0.261 Ng/L 0.261 1.01 1 02/15/21 18:39 JAB 6020B Nickel <0.513 ug/L 0.513 3.02 1 02/15/21 18:39 JAB 6020B Selenium <0.743 Ng/L 0.743 5.03 1 02/15/21 18:39 JAB 6020E Silver <0.111 u9/L 0.111 1.01 1 02/15/21 18:39 JAB 6020B Thallium <0.573 Ng/L 0.573 2.01 1 02/15/21 18:39 JAB 6020B Vanadium <1.31 ug/L 1.31 5.03 1 02/15/21 18:39 JAB 6020B Zinc <6.93 Ng/L 6.93 20.1 1 02/15/21 18:39 JAB 6020B 1,4-Dioxane <0.139 ug/L 0.139 2.00 1 02/16/21 15:04 TBL 8260D SIM Surrogate:4-Bromofluorobenzene 94.2 Limits:70-130% 1 02/16/2115:04 TBL V636 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value L Limit Exceeded MQL Method Quantitation Limit Page 22 of 52 ■ Waypoint 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU-MSWLF Greg Hutchins Report Date : 02/17/2021 1308 Patton Avenue (Suite C) Information : Received : 02/10/2021 Asheville , NC 28806 Report Number : 21-041-0025 REPOR T OF A NA L YSIS Lab No : 92423 Matrix: Aqueous Sample ID: MW-4 Sampled: 2/9/2021 12:30 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <0.310 Ng/L 0.310 5.00 1 02/12/21 19:36 JLB V577 Acrylonitrile <0.200 pg/L 0.200 20.0 1 02/12/21 19:36 JLB V577 Benzene <0.048 Ng/L 0.048 0.500 1 02/12/21 19:36 JLB V577 Bromochloromethane <0.140 pg/L 0.140 0.500 1 02/12/21 19:36 JLB V577 Bromodichloromethane <0.062 Ng/L 0.062 0.500 1 02/12/21 19:36 JLB V577 Bromoform <0.040 pg/L 0.040 1.00 1 02/12/21 19:36 JLB V577 Bromomethane <0.180 Ng/L 0.180 1.00 1 02/12/21 19:36 JLB V577 Carbon Disulfide <0.075 pg/L 0.075 5.00 1 02/12/21 19:36 JLB V577 Carbon Tetrachloride <0.110 Ng/L 0.110 0.500 1 02/12/21 19:36 JLB V577 Chlorobenzene 0.4773 pg/L 0.062 0.500 1 02/12/21 19:36 JLB V577 Chlorodibromomethane <0.081 Ng/L 0.081 0.500 1 02/12/21 19:36 JLB V577 Chloroethane <0.220 pg/L 0.220 0.500 1 02/12/21 19:36 JLB V577 Chloroform <0.076 Ng/L 0.076 0.500 1 02/12/21 19:36 JLB V577 Chloromethane <0.079 pg/L 0.079 0.500 1 02/12/21 19:36 JLB V577 Di -Isopropyl Ether(DIPE) <0.960 Ng/L 0.960 5.00 1 02/12/21 19:36 JLB V577 1,2-Dibromo-3-Chloropropane <0.170 pg/L 0.170 2.00 1 02/12/21 19:36 JLB V577 1,2-Dibromoethane <0.051 Ng/L 0.051 0.500 1 02/12/21 19:36 JLB V577 Dibromomethane <0.065 pg/L 0.065 0.500 1 02/12/21 19:36 JLB V577 trans-1,4-Dichloro-2-butene <0.120 Ng/L 0.120 10.0 1 02/12/21 19:36 JLB V577 1,2-Dichlorobenzene <0.076 pg/L 0.076 0.500 1 02/12/21 19:36 JLB V577 1,4-Dichlorobenzene <0.050 Ng/L 0.050 0.500 1 02/12/21 19:36 JLB V577 Dichlorodifluoromethane <0.110 pg/L 0.110 5.00 1 02/12/21 19:36 JLB V577 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 23 of 52 ■ Waypoint 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU-MSWLF Greg Hutchins Report Date : 02/17/2021 1308 Patton Avenue (Suite C) Information : Received : 02/10/2021 Asheville , NC 28806 Report Number : 21-041-0025 REPOR T OF A NA L YSIS Lab No : 92423 Matrix: Aqueous Sample ID: MW-4 Sampled: 2/9/2021 12:30 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.083 Ng/L 0.083 0.500 1 02/12/21 19:36 JLB V577 1,2-Dichloroethane <0.066 pg/L 0.066 0.500 1 02/12/21 19:36 JLB V577 1,1-Dichloroethene <0.083 Ng/L 0.083 0.500 1 02/12/21 19:36 JLB V577 cis- 1,2-Dich loroethene <0.056 pg/L 0.056 0.500 1 02/12/21 19:36 JLB V577 trans-1,2-Dichloroethene <0.094 Ng/L 0.094 0.500 1 02/12/21 19:36 JLB V577 1,2-Dichloropropane <0.110 pg/L 0.110 0.500 1 02/12/21 19:36 JLB V577 cis- 1,3-Dich loropropene <0.079 Ng/L 0.079 0.500 1 02/12/21 19:36 JLB V577 trans-1,3-Dichloropropene <0.070 pg/L 0.070 0.500 1 02/12/21 19:36 JLB V577 Ethylbenzene <0.061 Ng/L 0.061 0.500 1 02/12/21 19:36 JLB V577 2-Hexanone <0.065 pg/L 0.065 5.00 1 02/12/21 19:36 JLB V577 Methyl Ethyl Ketone (MEK) <0.240 Ng/L 0.240 5.00 1 02/12/21 19:36 JLB V577 4-Methyl-2-Pentanone <1.00 pg/L 1.00 5.00 1 02/12/21 19:36 JLB V577 Methylene Chloride <0.083 Ng/L 0.083 1.00 1 02/12/21 19:36 JLB V577 Styrene <0.047 pg/L 0.047 0.500 1 02/12/21 19:36 JLB V577 1,1,1,2-Tetrachloroethane <0.110 Ng/L 0.110 0.500 1 02/12/21 19:36 JLB V577 1,1,2,2-Tetrachloroethane <0.036 pg/L 0.036 0.500 1 02/12/21 19:36 JLB V577 Tetrachloroethene <0.098 Ng/L 0.098 0.500 1 02/12/21 19:36 JLB V577 Tetrahydrofuran <1.10 pg/L 1.10 10.0 1 02/12/21 19:36 JLB V577 Toluene <0.044 Ng/L 0.044 0.500 1 02/12/21 19:36 JLB V577 1,1,1-Trichloroethane <0.061 pg/L 0.061 0.500 1 02/12/21 19:36 JLB V577 1,1,2-Trichloroethane <0.066 Ng/L 0.066 0.500 1 02/12/21 19:36 JLB V577 Trichloroethene <0.078 pg/L 0.078 0.500 1 02/12/21 19:36 JLB V577 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 24 of 52 Waypointo ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Greg Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU-MSWLF Report Date : 02/17/2021 Received : 02/10/2021 Report Number : 21-041-0025 Lab No : 92423 Sample ID: MW-4 REPOR T OF A NA L YSIS Matrix: Aqueous Sampled: 2/9/2021 12:30 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Trichlorofluoromethane <0.062 Ng/L 0.062 0.500 1 02/12/21 19:36 JLB V577 1,2,3-Trichloropropane <0.140 ug/L 0.140 1.00 1 02/12/21 19:36 JLB V577 Vinyl Acetate <0.060 Ng/L 0.060 2.00 1 02/12/21 19:36 JLB V577 Vinyl Chloride <0.097 ug/L 0.097 0.500 1 02/12/21 19:36 JLB V577 o-Xylene <0.044 Ng/L 0.044 0.500 1 02/12/21 19:36 JLB V577 m,p-Xylene <0.120 ug/L 0.120 1.00 1 02/12/21 19:36 JLB V577 Xylene (Total) <0.044 Ng/L 0.044 0.500 1 02/12/21 19:36 KCC V577 Surrogate:4-Bromofluorobenzene 96.2 Limits:80-124% 1 02/12/21 19:36 JLB V577 Surrogate: Dibromofluoromethane 104 Limits: 75-129% 1 02/12/21 19:36 JLB V577 Surrogate: 1,2-Dichloroethane - d4 103 Limits: 63-136% 1 02/12/21 19:36 JLB V577 Surrogate: Toluene-d8 95.4 Limits: 77-123% 1 02/12/21 19:36 JLB V577 Qualifiers/ B Analyte detected in blank Definitions J Estimated value DF Dilution Factor MQL Method Quantitation Limit Page 25 of 52 Waypointo ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Greg Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU-MSWLF Report Number : 21-041-0025 REPOR T OF A NA L YSIS Report Date : 02/17/2021 Received : 02/10/2021 Lab No : 92424 Sample ID: SW-1 Matrix: Aqueous Sampled: 2/9/2021 13:15 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Antimony <0.490 Ng/L 0.490 2.00 1 02/15/21 18:46 JAB 6020B Arsenic 0.443J u9/L 0.170 1.00 1 02/15/21 18:46 JAB 6020B Barium 309 Ng/L 0.810 10.0 1 02/15/21 18:46 JAB 6020B Beryllium <0.190 ug/L 0.190 1.00 1 02/15/21 18:46 JAB 6020B Cadmium 0.207J Ng/L 0.160 1.00 1 02/15/21 18:46 JAB 6020B Chromium <0.790 ug/L 0.790 2.00 1 02/15/21 18:46 JAB 6020B Cobalt 6.82 Ng/L 0.520 2.00 1 02/15/21 18:46 JAB 6020B Copper 7.46J ug/L 3.80 10.0 1 02/15/21 18:46 JAB 6020B Lead 3.66 Ng/L 0.260 1.00 1 02/15/21 18:46 JAB 6020B Nickel 5.57 ug/L 0.510 3.00 1 02/15/21 18:46 JAB 6020B Selenium <0.740 Ng/L 0.740 5.00 1 02/15/21 18:46 JAB 6020B Silver <0.110 ug/L 0.110 1.00 1 02/15/21 18:46 JAB 6020B Thallium <0.570 Ng/L 0.570 2.00 1 02/15/21 18:46 JAB 6020B Vanadium <1.30 ug/L 1.30 5.00 1 02/15/21 18:46 JAB 6020B Zinc 19.1 J Ng/L 6.91 20.0 1 02/15/21 18:46 JAB 6020B 1,4-Dioxane 3.93 ug/L 0.139 2.00 1 02/16/21 15:29 TBL 8260D SIM Surrogate:4-Bromofluorobenzene 92.2 Limits:70-130% 1 02/16/2115:29 TBL V636 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value L Limit Exceeded MQL Method Quantitation Limit Page 26 of 52 ■ Waypoint 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU-MSWLF Greg Hutchins Report Date : 02/17/2021 1308 Patton Avenue (Suite C) Information : Received : 02/10/2021 Asheville , NC 28806 Report Number : 21-041-0025 REPOR T OF A NA L YSIS Lab No : 92424 Matrix: Aqueous Sample ID: SW-1 Sampled: 2/9/2021 13:15 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <0.310 Ng/L 0.310 5.00 1 02/12/21 20:10 JLB V577 Acrylonitrile <0.200 pg/L 0.200 20.0 1 02/12/21 20:10 JLB V577 Benzene <0.048 Ng/L 0.048 0.500 1 02/12/21 20:10 JLB V577 Bromochloromethane <0.140 pg/L 0.140 0.500 1 02/12/21 20:10 JLB V577 Bromodichloromethane <0.062 Ng/L 0.062 0.500 1 02/12/21 20:10 JLB V577 Bromoform <0.040 pg/L 0.040 1.00 1 02/12/21 20:10 JLB V577 Bromomethane <0.180 Ng/L 0.180 1.00 1 02/12/21 20:10 JLB V577 Carbon Disulfide <0.075 pg/L 0.075 5.00 1 02/12/21 20:10 JLB V577 Carbon Tetrachloride <0.110 Ng/L 0.110 0.500 1 02/12/21 20:10 JLB V577 Chlorobenzene 1.20 pg/L 0.062 0.500 1 02/12/21 20:10 JLB V577 Chlorodibromomethane <0.081 Ng/L 0.081 0.500 1 02/12/21 20:10 JLB V577 Chloroethane <0.220 pg/L 0.220 0.500 1 02/12/21 20:10 JLB V577 Chloroform <0.076 Ng/L 0.076 0.500 1 02/12/21 20:10 JLB V577 Chloromethane <0.079 pg/L 0.079 0.500 1 02/12/21 20:10 JLB V577 Di -Isopropyl Ether(DIPE) <0.960 Ng/L 0.960 5.00 1 02/12/21 20:10 JLB V577 1,2-Dibromo-3-Chloropropane <0.170 pg/L 0.170 2.00 1 02/12/21 20:10 JLB V577 1,2-Dibromoethane <0.051 Ng/L 0.051 0.500 1 02/12/21 20:10 JLB V577 Dibromomethane <0.065 pg/L 0.065 0.500 1 02/12/21 20:10 JLB V577 trans-1,4-Dichloro-2-butene <0.120 Ng/L 0.120 10.0 1 02/12/21 20:10 JLB V577 1,2-Dichlorobenzene <0.076 pg/L 0.076 0.500 1 02/12/21 20:10 JLB V577 1,4-Dichlorobenzene 0.542 Ng/L 0.050 0.500 1 02/12/21 20:10 JLB V577 Dichlorodifluoromethane <0.110 pg/L 0.110 5.00 1 02/12/21 20:10 JLB V577 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 27 of 52 ■ Waypoint 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU-MSWLF Greg Hutchins Report Date : 02/17/2021 1308 Patton Avenue (Suite C) Information : Received : 02/10/2021 Asheville , NC 28806 Report Number : 21-041-0025 REPORT OF ANAL YSIS Lab No : 92424 Matrix: Aqueous Sample ID: SW-1 Sampled: 2/9/2021 13:15 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.083 Ng/L 0.083 0.500 1 02/12/21 20:10 JLB V577 1,2-Dichloroethane <0.066 pg/L 0.066 0.500 1 02/12/21 20:10 JLB V577 1,1-Dichloroethene <0.083 Ng/L 0.083 0.500 1 02/12/21 20:10 JLB V577 cis- 1,2-Dich loroethene <0.056 pg/L 0.056 0.500 1 02/12/21 20:10 JLB V577 trans-1,2-Dichloroethene <0.094 Ng/L 0.094 0.500 1 02/12/21 20:10 JLB V577 1,2-Dichloropropane <0.110 pg/L 0.110 0.500 1 02/12/21 20:10 JLB V577 cis- 1,3-Dich loropropene <0.079 Ng/L 0.079 0.500 1 02/12/21 20:10 JLB V577 trans-1,3-Dichloropropene <0.070 pg/L 0.070 0.500 1 02/12/21 20:10 JLB V577 Ethylbenzene <0.061 Ng/L 0.061 0.500 1 02/12/21 20:10 JLB V577 2-Hexanone <0.065 pg/L 0.065 5.00 1 02/12/21 20:10 JLB V577 Methyl Ethyl Ketone (MEK) <0.240 Ng/L 0.240 5.00 1 02/12/21 20:10 JLB V577 4-Methyl-2-Pentanone <1.00 pg/L 1.00 5.00 1 02/12/21 20:10 JLB V577 Methylene Chloride <0.083 Ng/L 0.083 1.00 1 02/12/21 20:10 JLB V577 Styrene <0.047 pg/L 0.047 0.500 1 02/12/21 20:10 JLB V577 1,1,1,2-Tetrachloroethane <0.110 Ng/L 0.110 0.500 1 02/12/21 20:10 JLB V577 1,1,2,2-Tetrachloroethane <0.036 pg/L 0.036 0.500 1 02/12/21 20:10 JLB V577 Tetrachloroethene <0.098 Ng/L 0.098 0.500 1 02/12/21 20:10 JLB V577 Tetrahydrofuran 3.433 pg/L 1.10 10.0 1 02/12/21 20:10 JLB V577 Toluene <0.044 Ng/L 0.044 0.500 1 02/12/21 20:10 JLB V577 1,1,1-Trichloroethane <0.061 pg/L 0.061 0.500 1 02/12/21 20:10 JLB V577 1,1,2-Trichloroethane <0.066 Ng/L 0.066 0.500 1 02/12/21 20:10 JLB V577 Trichloroethene <0.078 pg/L 0.078 0.500 1 02/12/21 20:10 JLB V577 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 28 of 52 Waypointo ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Greg Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU-MSWLF Report Number : 21-041-0025 REPOR T OF A NA L YSIS Report Date : 02/17/2021 Received : 02/10/2021 Lab No : 92424 Matrix: Aqueous Sample ID: SW-1 Sampled: 2/9/2021 13:15 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Trichlorofluoromethane <0.062 Ng/L 0.062 0.500 1 02/12/21 20:10 JLB V577 1,2,3-Trichloropropane <0.140 ug/L 0.140 1.00 1 02/12/21 20:10 JLB V577 Vinyl Acetate <0.060 Ng/L 0.060 2.00 1 02/12/21 20:10 JLB V577 Vinyl Chloride <0.097 ug/L 0.097 0.500 1 02/12/21 20:10 JLB V577 o-Xylene <0.044 Ng/L 0.044 0.500 1 02/12/21 20:10 JLB V577 m,p-Xylene <0.120 ug/L 0.120 1.00 1 02/12/21 20:10 JLB V577 Xylene (Total) <0.044 Ng/L 0.044 0.500 1 02/12/21 20:10 KCC V577 Surrogate:4-Bromofluorobenzene 97.0 Limits:80-124% 1 02/12/2120:10 JLB V577 Surrogate: Dibromofluoromethane 103 Limits: 75-129% 1 02/12/21 20:10 JLB V577 Surrogate: 1,2-Dichloroethane - d4 110 Limits: 63-136% 1 02/12/21 20:10 JLB V577 Surrogate: Toluene-d8 96.0 Limits: 77-123% 1 02/12/21 20:10 JLB V577 Qualifiers/ B Analyte detected in blank Definitions J Estimated value DF Dilution Factor MQL Method Quantitation Limit Page 29 of 52 Waypointo ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Greg Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU-MSWLF Report Number : 21-041-0025 REPOR T OF A NA L YSIS Report Date : 02/17/2021 Received : 02/10/2021 Lab No : 92425 Sample ID: MW-2 Matrix: Aqueous Sampled: 2/9/2021 14:30 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Antimony <0.492 Ng/L 0.492 2.01 1 02/15/21 18:52 JAB 6020B Arsenic 0.177J ug/L 0.171 1.00 1 02/15/21 18:52 JAB 6020B Barium 86.0 N9/L 0.813 10.0 1 02/15/21 18:52 JAB 6020B Beryllium <0.191 ug/L 0.191 1.00 1 02/15/21 18:52 JAB 6020B Cadmium <0.161 N9/L 0.161 1.00 1 02/15/21 18:52 JAB 6020B Chromium <0.793 u9/L 0.793 2.01 1 02/15/21 18:52 JAB 6020B Cobalt <0.521 N9/L 0.521 2.01 1 02/15/21 18:52 JAB 6020B Copper <3.81 ug/L 3.81 10.0 1 02/15/21 18:52 JAB 6020B Lead <0.261 N9/L 0.261 1.00 1 02/15/21 18:52 JAB 6020B Nickel 1.18J u9/L 0.512 3.01 1 02/15/21 18:52 JAB 6020B Selenium <0.742 N9/L 0.742 5.02 1 02/15/21 18:52 JAB 6020E Silver <0.110 u9/L 0.110 1.00 1 02/15/21 18:52 JAB 6020B Thallium <0.572 N9/L 0.572 2.01 1 02/15/21 18:52 JAB 6020B Vanadium <1.30 u9/L 1.30 5.02 1 02/15/21 18:52 JAB 6020B Zinc <6.93 N9/L 6.93 20.1 1 02/15/21 18:52 JAB 6020B 1,4-Dioxane <0.139 u9/L 0.139 2.00 1 02/16/21 15:54 TBL 8260D SIM Surrogate:4-Bromofluorobenzene 99.4 Limits:70-130% 1 02/16/2115:54 TBL V636 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value L Limit Exceeded MQL Method Quantitation Limit Page 30 of 52 ■ Waypoint 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU-MSWLF Greg Hutchins Report Date : 02/17/2021 1308 Patton Avenue (Suite C) Information : Received : 02/10/2021 Asheville , NC 28806 Report Number : 21-041-0025 REPOR T OF A NA L YSIS Lab No : 92425 Matrix: Aqueous Sample ID: MW-2 Sampled: 2/9/2021 14:30 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <0.310 Ng/L 0.310 5.00 1 02/12/21 20:44 JLB V577 Acrylonitrile <0.200 pg/L 0.200 20.0 1 02/12/21 20:44 JLB V577 Benzene <0.048 Ng/L 0.048 0.500 1 02/12/21 20:44 JLB V577 Bromochloromethane <0.140 pg/L 0.140 0.500 1 02/12/21 20:44 JLB V577 Bromodichloromethane <0.062 Ng/L 0.062 0.500 1 02/12/21 20:44 JLB V577 Bromoform <0.040 pg/L 0.040 1.00 1 02/12/21 20:44 JLB V577 Bromomethane <0.180 Ng/L 0.180 1.00 1 02/12/21 20:44 JLB V577 Carbon Disulfide <0.075 pg/L 0.075 5.00 1 02/12/21 20:44 JLB V577 Carbon Tetrachloride <0.110 Ng/L 0.110 0.500 1 02/12/21 20:44 JLB V577 Chlorobenzene <0.062 pg/L 0.062 0.500 1 02/12/21 20:44 JLB V577 Chlorodibromomethane <0.081 Ng/L 0.081 0.500 1 02/12/21 20:44 JLB V577 Chloroethane <0.220 pg/L 0.220 0.500 1 02/12/21 20:44 JLB V577 Chloroform <0.076 Ng/L 0.076 0.500 1 02/12/21 20:44 JLB V577 Chloromethane <0.079 pg/L 0.079 0.500 1 02/12/21 20:44 JLB V577 Di -Isopropyl Ether(DIPE) <0.960 Ng/L 0.960 5.00 1 02/12/21 20:44 JLB V577 1,2-Dibromo-3-Chloropropane <0.170 pg/L 0.170 2.00 1 02/12/21 20:44 JLB V577 1,2-Dibromoethane <0.051 Ng/L 0.051 0.500 1 02/12/21 20:44 JLB V577 Dibromomethane <0.065 pg/L 0.065 0.500 1 02/12/21 20:44 JLB V577 trans-1,4-Dichloro-2-butene <0.120 Ng/L 0.120 10.0 1 02/12/21 20:44 JLB V577 1,2-Dichlorobenzene <0.076 pg/L 0.076 0.500 1 02/12/21 20:44 JLB V577 1,4-Dichlorobenzene <0.050 Ng/L 0.050 0.500 1 02/12/21 20:44 JLB V577 Dichlorodifluoromethane <0.110 pg/L 0.110 5.00 1 02/12/21 20:44 JLB V577 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 31 of 52 ■ Waypoint 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU-MSWLF Greg Hutchins Report Date : 02/17/2021 1308 Patton Avenue (Suite C) Information : Received : 02/10/2021 Asheville , NC 28806 Report Number : 21-041-0025 REPOR T OF A NA L YSIS Lab No : 92425 Matrix: Aqueous Sample ID: MW-2 Sampled: 2/9/2021 14:30 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.083 Ng/L 0.083 0.500 1 02/12/21 20:44 JLB V577 1,2-Dichloroethane <0.066 pg/L 0.066 0.500 1 02/12/21 20:44 JLB V577 1,1-Dichloroethene <0.083 Ng/L 0.083 0.500 1 02/12/21 20:44 JLB V577 cis- 1,2-Dich loroethene <0.056 pg/L 0.056 0.500 1 02/12/21 20:44 JLB V577 trans-1,2-Dichloroethene <0.094 Ng/L 0.094 0.500 1 02/12/21 20:44 JLB V577 1,2-Dichloropropane <0.110 pg/L 0.110 0.500 1 02/12/21 20:44 JLB V577 cis- 1,3-Dich loropropene <0.079 Ng/L 0.079 0.500 1 02/12/21 20:44 JLB V577 trans-1,3-Dichloropropene <0.070 pg/L 0.070 0.500 1 02/12/21 20:44 JLB V577 Ethylbenzene <0.061 Ng/L 0.061 0.500 1 02/12/21 20:44 JLB V577 2-Hexanone <0.065 pg/L 0.065 5.00 1 02/12/21 20:44 JLB V577 Methyl Ethyl Ketone (MEK) <0.240 Ng/L 0.240 5.00 1 02/12/21 20:44 JLB V577 4-Methyl-2-Pentanone <1.00 pg/L 1.00 5.00 1 02/12/21 20:44 JLB V577 Methylene Chloride <0.083 Ng/L 0.083 1.00 1 02/12/21 20:44 JLB V577 Styrene <0.047 pg/L 0.047 0.500 1 02/12/21 20:44 JLB V577 1,1,1,2-Tetrachloroethane <0.110 Ng/L 0.110 0.500 1 02/12/21 20:44 JLB V577 1,1,2,2-Tetrachloroethane <0.036 pg/L 0.036 0.500 1 02/12/21 20:44 JLB V577 Tetrachloroethene <0.098 Ng/L 0.098 0.500 1 02/12/21 20:44 JLB V577 Tetrahydrofuran <1.10 pg/L 1.10 10.0 1 02/12/21 20:44 JLB V577 Toluene <0.044 Ng/L 0.044 0.500 1 02/12/21 20:44 JLB V577 1,1,1-Trichloroethane <0.061 pg/L 0.061 0.500 1 02/12/21 20:44 JLB V577 1,1,2-Trichloroethane <0.066 Ng/L 0.066 0.500 1 02/12/21 20:44 JLB V577 Trichloroethene <0.078 pg/L 0.078 0.500 1 02/12/21 20:44 JLB V577 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 32 of 52 Waypointo ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Greg Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU-MSWLF Report Date : 02/17/2021 Received : 02/10/2021 Report Number : 21-041-0025 Lab No : 92425 Sample ID: MW-2 REPOR T OF A NA L YSIS Matrix: Aqueous Sampled: 2/9/2021 14:30 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Trichlorofluoromethane <0.062 Ng/L 0.062 0.500 1 02/12/21 20:44 JLB V577 1,2,3-Trichloropropane <0.140 ug/L 0.140 1.00 1 02/12/21 20:44 JLB V577 Vinyl Acetate <0.060 Ng/L 0.060 2.00 1 02/12/21 20:44 JLB V577 Vinyl Chloride <0.097 ug/L 0.097 0.500 1 02/12/21 20:44 JLB V577 o-Xylene <0.044 Ng/L 0.044 0.500 1 02/12/21 20:44 JLB V577 m,p-Xylene <0.120 ug/L 0.120 1.00 1 02/12/21 20:44 JLB V577 Xylene (Total) <0.044 Ng/L 0.044 0.500 1 02/12/21 20:44 KCC V577 Surrogate:4-Bromofluorobenzene 96.4 Limits:80-124% 1 02/12/2120:44 JLB V577 Surrogate: Dibromofluoromethane 103 Limits: 75-129% 1 02/12/21 20:44 JLB V577 Surrogate: 1,2-Dichloroethane - d4 106 Limits: 63-136% 1 02/12/21 20:44 JLB V577 Surrogate: Toluene-d8 93.8 Limits: 77-123% 1 02/12/21 20:44 JLB V577 Qualifiers/ B Analyte detected in blank Definitions J Estimated value DF Dilution Factor MQL Method Quantitation Limit Page 33 of 52 Waypointo ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Greg Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU-MSWLF Report Number : 21-041-0025 REPOR T OF A NA L YSIS Report Date : 02/17/2021 Received : 02/10/2021 Lab No : 92426 Sample ID : EB-1 Matrix: Aqueous Sampled: 2/9/2021 14:45 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Antimony <0.490 Ng/L 0.490 2.00 1 02/15/21 18:58 JAB 6020B Arsenic 0.213J ug/L 0.170 1.00 1 02/15/21 18:58 JAB 6020B Barium 17.5 N9/L 0.810 10.0 1 02/15/21 18:58 JAB 6020B Beryllium <0.190 u9/L 0.190 1.00 1 02/15/21 18:58 JAB 6020B Cadmium <0.160 N9/L 0.160 1.00 1 02/15/21 18:58 JAB 6020B Chromium <0.790 u9/L 0.790 2.00 1 02/15/21 18:58 JAB 6020B Cobalt <0.520 N9/L 0.520 2.00 1 02/15/21 18:58 JAB 6020B Copper 7.95J u9/L 3.80 10.0 1 02/15/21 18:58 JAB 6020B Lead <0.260 N9/L 0.260 1.00 1 02/15/21 18:58 JAB 6020B Nickel 3.10 u9/L 0.510 3.00 1 02/15/21 18:58 JAB 6020B Selenium <0.740 N9/L 0.740 5.00 1 02/15/21 18:58 JAB 6020E Silver <0.110 u9/L 0.110 1.00 1 02/15/21 18:58 JAB 6020B Thallium <0.570 N9/L 0.570 2.00 1 02/15/21 18:58 JAB 6020B Vanadium <1.30 u9/L 1.30 5.00 1 02/15/21 18:58 JAB 6020B Zinc 35.6 N9/L 6.90 20.0 1 02/15/21 18:58 JAB 6020B 1,4-Dioxane <0.139 u9/L 0.139 2.00 1 02/16/21 16:20 TBL 8260D SIM Surrogate:4-Bromofluorobenzene 93.6 Limits:70-130% 1 02/16/2116:20 TBL V636 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value L Limit Exceeded MQL Method Quantitation Limit Page 34 of 52 ■ Waypoint 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU-MSWLF Greg Hutchins Report Date : 02/17/2021 1308 Patton Avenue (Suite C) Information : Received : 02/10/2021 Asheville , NC 28806 Report Number : 21-041-0025 REPOR T OF A NA L YSIS Lab No : 92426 Matrix: Aqueous Sample ID : EB-1 Sampled: 2/9/2021 14:45 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <0.310 Ng/L 0.310 5.00 1 02/12/21 17:20 JLB V577 Acrylonitrile <0.200 pg/L 0.200 20.0 1 02/12/21 17:20 JLB V577 Benzene <0.048 Ng/L 0.048 0.500 1 02/12/21 17:20 JLB V577 Bromochloromethane <0.140 pg/L 0.140 0.500 1 02/12/21 17:20 JLB V577 Bromodichloromethane <0.062 Ng/L 0.062 0.500 1 02/12/21 17:20 JLB V577 Bromoform <0.040 pg/L 0.040 1.00 1 02/12/21 17:20 JLB V577 Bromomethane <0.180 Ng/L 0.180 1.00 1 02/12/21 17:20 JLB V577 Carbon Disulfide <0.075 pg/L 0.075 5.00 1 02/12/21 17:20 JLB V577 Carbon Tetrachloride <0.110 Ng/L 0.110 0.500 1 02/12/21 17:20 JLB V577 Chlorobenzene <0.062 pg/L 0.062 0.500 1 02/12/21 17:20 JLB V577 Chlorodibromomethane <0.081 Ng/L 0.081 0.500 1 02/12/21 17:20 JLB V577 Chloroethane <0.220 pg/L 0.220 0.500 1 02/12/21 17:20 JLB V577 Chloroform 0.583 Ng/L 0.076 0.500 1 02/12/21 17:20 JLB V577 Chloromethane <0.079 pg/L 0.079 0.500 1 02/12/21 17:20 JLB V577 Di -Isopropyl Ether(DIPE) <0.960 Ng/L 0.960 5.00 1 02/12/21 17:20 JLB V577 1,2-Dibromo-3-Chloropropane <0.170 pg/L 0.170 2.00 1 02/12/21 17:20 JLB V577 1,2-Dibromoethane <0.051 Ng/L 0.051 0.500 1 02/12/21 17:20 JLB V577 Dibromomethane <0.065 pg/L 0.065 0.500 1 02/12/21 17:20 JLB V577 trans-1,4-Dichloro-2-butene <0.120 Ng/L 0.120 10.0 1 02/12/21 17:20 JLB V577 1,2-Dichlorobenzene <0.076 pg/L 0.076 0.500 1 02/12/21 17:20 JLB V577 1,4-Dichlorobenzene <0.050 Ng/L 0.050 0.500 1 02/12/21 17:20 JLB V577 Dichlorodifluoromethane <0.110 pg/L 0.110 5.00 1 02/12/21 17:20 JLB V577 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 35 of 52 ■ Waypoint 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU-MSWLF Greg Hutchins Report Date : 02/17/2021 1308 Patton Avenue (Suite C) Information : Received : 02/10/2021 Asheville , NC 28806 Report Number : 21-041-0025 REPOR T OF A NA L YSIS Lab No : 92426 Matrix: Aqueous Sample ID : EB-1 Sampled: 2/9/2021 14:45 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.083 Ng/L 0.083 0.500 1 02/12/21 17:20 JLB V577 1,2-Dichloroethane <0.066 pg/L 0.066 0.500 1 02/12/21 17:20 JLB V577 1,1-Dichloroethene <0.083 Ng/L 0.083 0.500 1 02/12/21 17:20 JLB V577 cis- 1,2-Dich loroethene <0.056 pg/L 0.056 0.500 1 02/12/21 17:20 JLB V577 trans-1,2-Dichloroethene <0.094 Ng/L 0.094 0.500 1 02/12/21 17:20 JLB V577 1,2-Dichloropropane <0.110 pg/L 0.110 0.500 1 02/12/21 17:20 JLB V577 cis- 1,3-Dich loropropene <0.079 Ng/L 0.079 0.500 1 02/12/21 17:20 JLB V577 trans-1,3-Dichloropropene <0.070 pg/L 0.070 0.500 1 02/12/21 17:20 JLB V577 Ethylbenzene <0.061 Ng/L 0.061 0.500 1 02/12/21 17:20 JLB V577 2-Hexanone <0.065 pg/L 0.065 5.00 1 02/12/21 17:20 JLB V577 Methyl Ethyl Ketone (MEK) <0.240 Ng/L 0.240 5.00 1 02/12/21 17:20 JLB V577 4-Methyl-2-Pentanone <1.00 pg/L 1.00 5.00 1 02/12/21 17:20 JLB V577 Methylene Chloride <0.083 Ng/L 0.083 1.00 1 02/12/21 17:20 JLB V577 Styrene <0.047 pg/L 0.047 0.500 1 02/12/21 17:20 JLB V577 1,1,1,2-Tetrachloroethane <0.110 Ng/L 0.110 0.500 1 02/12/21 17:20 JLB V577 1,1,2,2-Tetrachloroethane <0.036 pg/L 0.036 0.500 1 02/12/21 17:20 JLB V577 Tetrachloroethene <0.098 Ng/L 0.098 0.500 1 02/12/21 17:20 JLB V577 Tetrahydrofuran <1.10 pg/L 1.10 10.0 1 02/12/21 17:20 JLB V577 Toluene <0.044 Ng/L 0.044 0.500 1 02/12/21 17:20 JLB V577 1,1,1-Trichloroethane <0.061 pg/L 0.061 0.500 1 02/12/21 17:20 JLB V577 1,1,2-Trichloroethane <0.066 Ng/L 0.066 0.500 1 02/12/21 17:20 JLB V577 Trichloroethene <0.078 pg/L 0.078 0.500 1 02/12/21 17:20 JLB V577 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 36 of 52 Waypointo ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Greg Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU-MSWLF Report Date : 02/17/2021 Received : 02/10/2021 Report Number : 21-041-0025 Lab No : 92426 Sample ID : EB-1 REPOR T OF A NA L YSIS Matrix: Aqueous Sampled: 2/9/2021 14:45 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Trichlorofluoromethane <0.062 Ng/L 0.062 0.500 1 02/12/21 17:20 JLB V577 1,2,3-Trichloropropane <0.140 ug/L 0.140 1.00 1 02/12/21 17:20 JLB V577 Vinyl Acetate <0.060 Ng/L 0.060 2.00 1 02/12/21 17:20 JLB V577 Vinyl Chloride <0.097 ug/L 0.097 0.500 1 02/12/21 17:20 JLB V577 o-Xylene <0.044 Ng/L 0.044 0.500 1 02/12/21 17:20 JLB V577 m,p-Xylene <0.120 ug/L 0.120 1.00 1 02/12/21 17:20 JLB V577 Xylene (Total) <0.044 Ng/L 0.044 0.500 1 02/12/21 17:20 KCC V577 Surrogate:4-Bromofluorobenzene 96.2 Limits:80-124% 1 02/12/21 17:20 JLB V577 Surrogate: Dibromofluoromethane 104 Limits: 75-129% 1 02/12/21 17:20 JLB V577 Surrogate: 1,2-Dichloroethane - d4 102 Limits: 63-136% 1 02/12/21 17:20 JLB V577 Surrogate: Toluene-d8 96.2 Limits: 77-123% 1 02/12/21 17:20 JLB V577 Qualifiers/ B Analyte detected in blank Definitions J Estimated value DF Dilution Factor MQL Method Quantitation Limit Page 37 of 52 Waypointo ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Greg Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU-MSWLF Report Number : 21-041-0025 REPOR T OF A NA L YSIS Report Date : 02/17/2021 Received : 02/10/2021 Lab No : 92433 Sample ID: MW-3 Matrix: Aqueous Sampled: 2/9/2021 15:40 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Antimony <0.490 Ng/L 0.490 2.00 1 02/15/21 19:05 JAB 6020B Arsenic 0.310J ug/L 0.170 1.00 1 02/15/21 19:05 JAB 6020B Barium 117 N9/L 0.810 10.0 1 02/15/21 19:05 JAB 6020B Beryllium <0.190 u9/L 0.190 1.00 1 02/15/21 19:05 JAB 6020B Cadmium <0.160 N9/L 0.160 1.00 1 02/15/21 19:05 JAB 6020B Chromium <0.790 u9/L 0.790 2.00 1 02/15/21 19:05 JAB 6020B Cobalt 8.88 N9/L 0.520 2.00 1 02/15/21 19:05 JAB 6020B Copper <3.80 u9/L 3.80 10.0 1 02/15/21 19:05 JAB 6020B Lead <0.260 N9/L 0.260 1.00 1 02/15/21 19:05 JAB 6020B Nickel 2.75J ug/L 0.510 3.00 1 02/15/21 19:05 JAB 6020B Selenium <0.740 N9/L 0.740 5.00 1 02/15/21 19:05 JAB 6020B Silver <0.110 u9/L 0.110 1.00 1 02/15/21 19:05 JAB 6020B Thallium <0.570 N9/L 0.570 2.00 1 02/15/21 19:05 JAB 6020B Vanadium <1.30 u9/L 1.30 5.00 1 02/15/21 19:05 JAB 6020B Zinc <6.91 N9/L 6.91 20.0 1 02/15/21 19:05 JAB 6020B 1,4-Dioxane <0.139 u9/L 0.139 2.00 1 02/16/21 16:45 TBL 8260D SIM Surrogate:4-Bromofluorobenzene 96.2 Limits:70-130% 1 02/16/2116:45 TBL V636 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value L Limit Exceeded MQL Method Quantitation Limit Page 38 of 52 ■ Waypoint 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU-MSWLF Greg Hutchins Report Date : 02/17/2021 1308 Patton Avenue (Suite C) Information : Received : 02/10/2021 Asheville , NC 28806 Report Number : 21-041-0025 REPOR T OF A NA L YSIS Lab No : 92433 Matrix: Aqueous Sample ID: MW-3 Sampled: 2/9/2021 15:40 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <0.310 Ng/L 0.310 5.00 1 02/12/21 21:18 JLB V577 Acrylonitrile <0.200 pg/L 0.200 20.0 1 02/12/21 21:18 JLB V577 Benzene 0.4583 Ng/L 0.048 0.500 1 02/12/21 21:18 JLB V577 Bromochloromethane <0.140 pg/L 0.140 0.500 1 02/12/21 21:18 JLB V577 Bromodichloromethane <0.062 Ng/L 0.062 0.500 1 02/12/21 21:18 JLB V577 Bromoform <0.040 pg/L 0.040 1.00 1 02/12/21 21:18 JLB V577 Bromomethane <0.180 Ng/L 0.180 1.00 1 02/12/21 21:18 JLB V577 Carbon Disulfide <0.075 pg/L 0.075 5.00 1 02/12/21 21:18 JLB V577 Carbon Tetrachloride <0.110 Ng/L 0.110 0.500 1 02/12/21 21:18 JLB V577 Chlorobenzene 10.0 pg/L 0.062 0.500 1 02/12/21 21:18 JLB V577 Chlorodibromomethane <0.081 Ng/L 0.081 0.500 1 02/12/21 21:18 JLB V577 Chloroethane <0.220 pg/L 0.220 0.500 1 02/12/21 21:18 JLB V577 Chloroform <0.076 Ng/L 0.076 0.500 1 02/12/21 21:18 JLB V577 Chloromethane <0.079 pg/L 0.079 0.500 1 02/12/21 21:18 JLB V577 Di -Isopropyl Ether(DIPE) <0.960 Ng/L 0.960 5.00 1 02/12/21 21:18 JLB V577 1,2-Dibromo-3-Chloropropane <0.170 pg/L 0.170 2.00 1 02/12/21 21:18 JLB V577 1,2-Dibromoethane <0.051 Ng/L 0.051 0.500 1 02/12/21 21:18 JLB V577 Dibromomethane <0.065 pg/L 0.065 0.500 1 02/12/21 21:18 JLB V577 trans-1,4-Dichloro-2-butene <0.120 Ng/L 0.120 10.0 1 02/12/21 21:18 JLB V577 1,2-Dichlorobenzene <0.076 pg/L 0.076 0.500 1 02/12/21 21:18 JLB V577 1,4-Dichlorobenzene 2.36 Ng/L 0.050 0.500 1 02/12/21 21:18 JLB V577 Dichlorodifluoromethane <0.110 pg/L 0.110 5.00 1 02/12/21 21:18 JLB V577 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 39 of 52 ■ Waypoint 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU-MSWLF Greg Hutchins Report Date : 02/17/2021 1308 Patton Avenue (Suite C) Information : Received : 02/10/2021 Asheville , NC 28806 Report Number : 21-041-0025 REPOR T OF A NA L YSIS Lab No : 92433 Matrix: Aqueous Sample ID: MW-3 Sampled: 2/9/2021 15:40 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.083 Ng/L 0.083 0.500 1 02/12/21 21:18 JLB V577 1,2-Dichloroethane <0.066 pg/L 0.066 0.500 1 02/12/21 21:18 JLB V577 1,1-Dichloroethene <0.083 Ng/L 0.083 0.500 1 02/12/21 21:18 JLB V577 cis- 1,2-Dich loroethene 1.66 pg/L 0.056 0.500 1 02/12/21 21:18 JLB V577 trans-1,2-Dichloroethene <0.094 Ng/L 0.094 0.500 1 02/12/21 21:18 JLB V577 1,2-Dichloropropane <0.110 pg/L 0.110 0.500 1 02/12/21 21:18 JLB V577 cis- 1,3-Dich loropropene <0.079 Ng/L 0.079 0.500 1 02/12/21 21:18 JLB V577 trans-1,3-Dichloropropene <0.070 pg/L 0.070 0.500 1 02/12/21 21:18 JLB V577 Ethylbenzene <0.061 Ng/L 0.061 0.500 1 02/12/21 21:18 JLB V577 2-Hexanone <0.065 pg/L 0.065 5.00 1 02/12/21 21:18 JLB V577 Methyl Ethyl Ketone (MEK) <0.240 Ng/L 0.240 5.00 1 02/12/21 21:18 JLB V577 4-Methyl-2-Pentanone <1.00 pg/L 1.00 5.00 1 02/12/21 21:18 JLB V577 Methylene Chloride <0.083 Ng/L 0.083 1.00 1 02/12/21 21:18 JLB V577 Styrene <0.047 pg/L 0.047 0.500 1 02/12/21 21:18 JLB V577 1,1,1,2-Tetrachloroethane <0.110 Ng/L 0.110 0.500 1 02/12/21 21:18 JLB V577 1,1,2,2-Tetrachloroethane <0.036 pg/L 0.036 0.500 1 02/12/21 21:18 JLB V577 Tetrachloroethene <0.098 Ng/L 0.098 0.500 1 02/12/21 21:18 JLB V577 Tetrahydrofuran <1.10 pg/L 1.10 10.0 1 02/12/21 21:18 JLB V577 Toluene <0.044 Ng/L 0.044 0.500 1 02/12/21 21:18 JLB V577 1,1,1-Trichloroethane <0.061 pg/L 0.061 0.500 1 02/12/21 21:18 JLB V577 1,1,2-Trichloroethane <0.066 Ng/L 0.066 0.500 1 02/12/21 21:18 JLB V577 Trichloroethene <0.078 pg/L 0.078 0.500 1 02/12/21 21:18 JLB V577 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 40 of 52 Waypointo ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Greg Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU-MSWLF Report Date : 02/17/2021 Received : 02/10/2021 Report Number : 21-041-0025 Lab No : 92433 Sample ID: MW-3 REPOR T OF A NA L YSIS Matrix: Aqueous Sampled: 2/9/2021 15:40 Analytical Method: 8260D Prep Batch(es): V574 02/12/21 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Trichlorofluoromethane <0.062 Ng/L 0.062 0.500 1 02/12/21 21:18 JLB V577 1,2,3-Trichloropropane <0.140 ug/L 0.140 1.00 1 02/12/21 21:18 JLB V577 Vinyl Acetate <0.060 Ng/L 0.060 2.00 1 02/12/21 21:18 JLB V577 Vinyl Chloride <0.097 ug/L 0.097 0.500 1 02/12/21 21:18 JLB V577 o-Xylene <0.044 Ng/L 0.044 0.500 1 02/12/21 21:18 JLB V577 m,p-Xylene <0.120 ug/L 0.120 1.00 1 02/12/21 21:18 JLB V577 Xylene (Total) <0.044 Ng/L 0.044 0.500 1 02/12/21 21:18 KCC V577 Surrogate:4-Bromofluorobenzene 98.0 Limits:80-124% 1 02/12/2121:18 JLB V577 Surrogate: Dibromofluoromethane 105 Limits: 75-129% 1 02/12/21 21:18 JLB V577 Surrogate: 1,2-Dichloroethane - d4 110 Limits: 63-136% 1 02/12/21 21:18 JLB V577 Surrogate: Toluene-d8 94.0 Limits: 77-123% 1 02/12/21 21:18 JLB V577 Qualifiers/ B Analyte detected in blank Definitions J Estimated value DF Dilution Factor MQL Method Quantitation Limit Page 41 of 52 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Wood Environ. & Infrastructure Inc (Asheville) Project Description: WCU-MSWLF Report No: 21-041-0025 QC Prep: V509 QC Analytical Batch(es): V597 QC Prep Batch Method: SM-3030C (PREP) Analysis Method: 6020B Analysis Description: Metals Analyses Lab Reagent Blank LRB-V509 Matrix: AQU Associated Lab Samples: 92420, 92421, 92422, 92423, 92424, 92425, 92426, 92433 Blank MDL MQL Analyzed Parameter Units Result Antimony pg/L <0.490 0.490 2.00 02/15/21 17:29 Arsenic pg/L <0.170 0.170 1.00 02/15/21 17:29 Barium pg/L <0.810 0.810 10.0 02/15/21 17:29 Beryllium pg/L <0.190 0.190 1.00 02/15/21 17:29 Cadmium pg/L <0.160 0.160 1.00 02/15/21 17:29 Chromium pg/L <0.790 0.790 2.00 02/15/21 17:29 Cobalt pg/L <0.520 0.520 2.00 02/15/21 17:29 Copper pg/L <3.80 3.80 10.0 02/15/21 17:29 Lead pg/L <0.260 0.260 1.00 02/15/21 17:29 Nickel pg/L <0.510 0.510 3.00 02/15/21 17:29 Selenium pg/L <0.740 0.740 5.00 02/15/21 17:29 Silver pg/L <0.110 0.110 1.00 02/15/21 17:29 Thallium pg/L <0.570 0.570 2.00 02/15/21 17:29 Vanadium pg/L <1.30 1.30 5.00 02/15/21 17:29 Zinc pg/L <6.90 6.90 20.0 02/15/21 17:29 Laboratory Control Sample LCS-V509 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Antimony pg/L 100 97.3 97.0 80-120 Arsenic pg/L 100 91.6 92.0 80-120 Barium pg/L 100 102 102 80-120 Beryllium pg/L 100 96.9 97.0 80-120 Cadmium pg/L 100 103 103 80-120 Chromium pg/L 100 95.1 95.0 80-120 Cobalt pg/L 100 93.8 94.0 80-120 Copper pg/L 100 93.5 94.0 80-120 Date: 02/17/2021 03:13 PM Page 1 of 9 Page 42 of 52 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Wood Environ. & Infrastructure Inc (Asheville) Project Description: WCU-MSWLF Report No: 21-041-0025 QC Prep: V509 QC Analytical Batch(es): V597 QC Prep Batch Method: SM-3030C (PREP) Analysis Method: 6020B Analysis Description: Metals Analyses Laboratory Control Sample LCS-V509 Parameter Units Spike Conc. LCS Result LCS %Rec % Rec Limits Lead pg/L 100 99.2 99.0 80-120 Nickel pg/L 100 94.6 95.0 80-120 Selenium pg/L 100 98.3 98.0 80-120 Silver pg/L 100 93.7 94.0 80-120 Thallium pg/L 100 85.8 86.0 80-120 Vanadium pg/L 100 96.1 96.0 80-120 Zinc pg/L 100 96.5 97.0 80-120 Matrix Spike & Matrix Spike Duplicate Parameter Units V 92420-MS-V509 MS Spike Result Conc. V 92420-MSD-V509 MSD MS Result Spike Conc. MSD Result MS %Rec MSD %Rec %Rec Limits RPD Max RPD Antimony pg/L 0.631 100 100 115 114 115 114 75-125 0.8 20.0 Arsenic pg/L 0.315 100 100 91.1 90.5 91.0 91.0 75-125 0.6 20.0 Barium pg/L 118 100 100 216 218 98.0 100 75-125 0.9 20.0 Beryllium pg/L < 0.193 100 100 98.8 95.7 99.0 96.0 75-125 3.1 20.0 Cadmium pg/L < 0.163 100 100 104 105 104 105 75-125 0.9 20.0 Chromium pg/L < 0.804 100 100 98.1 99.6 98.0 100 75-125 1.5 20.0 Cobalt pg/L 8.77 100 100 99.5 99.6 91.0 91.0 75-125 0.1 20.0 Copper pg/L < 3.87 100 100 91.6 92.1 92.0 92.0 75-125 0.5 20.0 Lead pg/L < 0.265 100 100 97.8 98.5 98.0 99.0 75-125 0.7 20.0 Nickel pg/L 2.71 100 100 93.7 95.1 94.0 95.0 75-125 1.4 20.0 Selenium pg/L < 0.753 100 100 95.8 98.8 96.0 99.0 75-125 3.0 20.0 Silver pg/L < 0.112 100 100 12.6 23.6 13.0* 24.0* 75-125 60.7* 20.0 Thallium pg/L < 0.580 100 100 97.5 97.9 98.0 98.0 75-125 0.4 20.0 Vanadium pg/L < 1.32 100 100 100 101 100 101 75-125 0.9 20.0 Zinc pg/L < 7.03 100 100 97.6 97.8 98.0 98.0 75-125 0.2 20.0 * QC Fail Date: 02/17/2021 03:13 PM Page 2 of 9 Page 43 of 52 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Wood Environ. & Infrastructure Inc (Asheville) Project Description: WCU-MSWLF Report No: 21-041-0025 QC Prep: V509 QC Prep Batch Method: SM-3030C (PREP) Post Digestion Spike V 92420-PDS-V509 Parameter Units PDS Result Antimony pg/L 53.1 Arsenic pg/L 42.5 Barium pg/L 105 Beryllium pg/L 47.8 Cadmium pg/L 48.8 Chromium pg/L 49.4 Cobalt pg/L 43.9 Copper pg/L 40.9 Lead pg/L 47.2 Nickel pg/L 42.2 Selenium pg/L 42.2 Silver pg/L 45.0 Thallium pg/L 46.7 Vanadium pg/L 50.0 Zinc pg/L 44.2 QC Analytical Batch(es): V597 Analysis Method: 6020B Analysis Description: Metals Analyses 0/0 Recovery 106 85.0 97.0 96.0 98.0 99.0 81.0 82.0 94.0 84.0 84.0 90.0 93.0 100 88.0 Analyzed 02/15/21 18:01 02/15/21 18:01 02/15/21 18:01 02/15/21 18:01 02/15/21 18:01 02/15/21 18:01 02/15/21 18:01 02/15/21 18:01 02/15/21 18:01 02/15/21 18:01 02/15/21 18:01 02/15/21 18:01 02/15/21 18:01 02/15/21 18:01 02/15/21 18:01 Date: 02/17/2021 03:13 PM Page 3 of 9 Page 44 of 52 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Wood Environ. & Infrastructure Inc (Asheville) Project Description: WCU-MSWLF Report No: 21-041-0025 QC Prep: V635 QC Analytical Batch(es): V636 QC Prep Batch Method: 5030B Analysis Method: 8260D SIM Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V635 Matrix: AQU Associated Lab Samples: 92419, 92420, 92421, 92422, 92423, 92424, 92425, 92426, 92433 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1,4-Dioxane pg/L <0.139 0.139 2.00 02/16/2112:58 4-Bromofluorobenzene (S) 02/16/21 12:58 90.2 70-130 Laboratory Control Sample LCS-V635 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits 1,4-Dioxane pg/L 50.0 55.7 111 70-130 4-Bromofluorobenzene (S) 102 70-130 Matrix Spike & Matrix Spike Duplicate V 92420-MS-V635 V 92420-MSD-V635 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD Conc. 1,4-Dioxane pg/L < 0.139 50.0 50.0 53.1 53.0 106 106 70-130 4-Bromofluorobenzene (S) 94.6 95.8 70-130 Date: 02/17/2021 03:13 PM Page 4 of 9 Page 45 of 52 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Wood Environ. & Infrastructure Inc (Asheville) Project Description: WCU-MSWLF Report No: 21-041-0025 QC Prep: V574 QC Prep Batch Method: 5030B QC Analytical Batch(es): V577 Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V574 Matrix: AQU Associated Lab Samples: 92419, 92420, 92421, 92422, 92423, 92424, 92425, 92426, 92433 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Acetone pg/L <0.310 0.310 5.00 02/12/21 16:11 Acrylonitrile pg/L <0.200 0.200 20.0 02/12/21 16:11 Benzene pg/L <0.048 0.048 0.500 02/12/21 16:11 Bromochloromethane pg/L <0.140 0.140 0.500 02/12/21 16:11 Bromodichloromethane pg/L <0.062 0.062 0.500 02/12/21 16:11 Bromoform pg/L <0.040 0.040 1.00 02/12/21 16:11 Bromomethane pg/L <0.180 0.180 1.00 02/12/21 16:11 Carbon Disulfide pg/L <0.075 0.075 5.00 02/12/21 16:11 Carbon Tetrachloride pg/L <0.110 0.110 0.500 02/12/21 16:11 Chlorobenzene pg/L <0.062 0.062 0.500 02/12/21 16:11 Chlorodibromomethane pg/L <0.081 0.081 0.500 02/12/21 16:11 Chloroethane pg/L <0.220 0.220 0.500 02/12/21 16:11 Chloroform pg/L <0.076 0.076 0.500 02/12/21 16:11 Chloromethane pg/L <0.079 0.079 0.500 02/12/21 16:11 Di -Isopropyl Ether (DIPE) pg/L <0.960 0.960 5.00 02/12/21 16:11 1,2-Dibromo-3-Chloropropane pg/L <0.170 0.170 2.00 02/12/21 16:11 1,2-Dibromoethane pg/L <0.051 0.051 0.500 02/12/21 16:11 Dibromomethane pg/L <0.065 0.065 0.500 02/12/21 16:11 trans-1,4-Dichloro-2-butene pg/L <0.120 0.120 10.0 02/12/21 16:11 1,2-Dichlorobenzene pg/L <0.076 0.076 0.500 02/12/21 16:11 1,4-Dichlorobenzene pg/L <0.050 0.050 0.500 02/12/21 16:11 Dichlorodifluoromethane pg/L <0.110 0.110 5.00 02/12/21 16:11 1,1-Dichloroethane pg/L <0.083 0.083 0.500 02/12/21 16:11 1,2-Dichloroethane pg/L <0.066 0.066 0.500 02/12/21 16:11 1,1-Dichloroethene pg/L <0.083 0.083 0.500 02/12/21 16:11 cis-1,2-Dichloroethene pg/L <0.056 0.056 0.500 02/12/21 16:11 trans-1,2-Dichloroethene pg/L <0.094 0.094 0.500 02/12/21 16:11 Date: 02/17/2021 03:13 PM Page 5 of 9 Page 46 of 52 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Wood Environ. & Infrastructure Inc (Asheville) Project Description: WCU-MSWLF Report No: 21-041-0025 QC Prep: V574 QC Prep Batch Method: 5030B QC Analytical Batch(es): V577 Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V574 Matrix: AQU Associated Lab Samples: 92419, 92420, 92421, 92422, 92423, 92424, 92425, 92426, 92433 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1,2-Dichloropropane cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene 2-Hexanone Methyl Ethyl Ketone (MEK) 4-M ethyl-2-Penta none Methylene Chloride Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl Acetate Vinyl Chloride o-Xylene m,p-Xylene 4-Bromofluorobenzene (S) Dibromofluoromethane (S) 1,2-Dichloroethane - d4 (S) pg/L <0.110 0.110 0.500 pg/L <0.079 0.079 0.500 pg/L <0.070 0.070 0.500 pg/L <0.061 0.061 0.500 pg/L <0.065 0.065 5.00 pg/L <0.240 0.240 5.00 pg/L <1.00 1.00 5.00 pg/L <0.083 0.083 1.00 pg/L <0.047 0.047 0.500 pg/L <0.110 0.110 0.500 pg/L <0.036 0.036 0.500 pg/L <0.098 0.098 0.500 pg/L <1.10 1.10 10.0 pg/L <0.044 0.044 0.500 pg/L <0.061 0.061 0.500 pg/L <0.066 0.066 0.500 pg/L <0.078 0.078 0.500 pg/L <0.062 0.062 0.500 pg/L <0.140 0.140 1.00 pg/L <0.060 0.060 2.00 pg/L <0.097 0.097 0.500 pg/L <0.044 0.044 0.500 pg/L <0.120 0.120 1.00 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 02/12/21 16:11 96.6 106 102 80-124 75-129 63-136 Date: 02/17/2021 03:13 PM Page 6 of 9 Page 47 of 52 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Wood Environ. & Infrastructure Inc (Asheville) Project Description: WCU-MSWLF Report No: 21-041-0025 QC Prep: V574 QC Analytical Batch(es): V577 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V574 Matrix: AQU Associated Lab Samples: 92419, 92420, 92421, 92422, 92423, 92424, 92425, 92426, 92433 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Toluene-d8 (S) 02/12/21 16:11 96.6 77-123 Laboratory Control Sample & LCSD LCS-V574 LCSD-V574 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec a/o Rec Limits RPD Max RPD Acetone pg/L 40.0 45.3 44.0 113 110 40-166 2.9 20.0 Acrylonitrile pg/L 40.0 41.3 44.4 103 111 81-127 7.2 20.0 Benzene pg/L 20.0 21.5 21.1 108 106 77-128 1.8 20.0 Bromochloromethane pg/L 20.0 22.1 23.4 111 117 78-135 5.7 20.0 Bromodichloromethane pg/L 20.0 21.5 21.3 108 107 76-138 0.9 20.0 Bromoform pg/L 20.0 19.8 19.9 99.0 99.5 71-135 0.5 20.0 Bromomethane pg/L 20.0 18.1 18.4 90.5 92.0 41-168 1.6 20.0 Carbon Disulfide pg/L 20.0 22.4 21.7 112 109 59-135 3.1 20.0 Carbon Tetrachloride pg/L 20.0 20.8 20.5 104 103 72-142 1.4 20.0 Chlorobenzene pg/L 20.0 20.3 20.2 102 101 78-119 0.4 20.0 Chlorodibromomethane pg/L 20.0 20.1 20.2 101 101 75-134 0.4 20.0 Chloroethane pg/L 20.0 21.3 21.6 107 108 57-142 1.3 20.0 Chloroform pg/L 20.0 21.2 21.4 106 107 77-130 0.9 20.0 Chloromethane pg/L 20.0 22.6 22.4 113 112 47-145 0.8 20.0 Di -Isopropyl Ether (DIPE) pg/L 20.0 21.6 21.6 108 108 60-154 0.0 20.0 1,2-Dibromo-3-Chloropropane pg/L 20.0 19.0 17.2 95.0 86.0 63-134 9.9 20.0 1,2-Dibromoethane pg/L 20.0 21.0 20.7 105 104 77-135 1.4 20.0 Dibromomethane pg/L 20.0 21.7 21.7 109 109 76-138 0.0 20.0 trans-1,4-Dichloro-2-butene pg/L 20.0 18.4 18.8 92.0 94.0 70-130 2.1 20.0 1,2-Dichlorobenzene pg/L 20.0 19.9 19.6 99.5 98.0 78-128 1.5 20.0 1,4-Dichlorobenzene pg/L 20.0 20.1 19.6 101 98.0 75-126 2.5 20.0 Date: 02/17/2021 03:13 PM Page 7 of 9 Page 48 of 52 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Wood Environ. & Infrastructure Inc (Asheville) Project Description: WCU-MSWLF Report No: 21-041-0025 QC Prep: V574 QC Analytical Batch(es): V577 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V574 LCSD-V574 Parameter Units Spike Conc. LCS Result LCSD Result LCS %Rec LCSD % Rec % Rec Limits RPD Max RPD Dichlorodifluoromethane pg/L 20.0 23.5 22.7 118 114 28-163 3.4 20.0 1,1-Dichloroethane pg/L 20.0 21.9 21.9 110 110 70-130 0.0 20.0 1,2-Dichloroethane pg/L 20.0 22.4 21.4 112 107 68-131 4.5 20.0 1,1-Dichloroethene pg/L 20.0 22.1 21.7 111 109 70-154 1.8 20.0 cis-1,2-Dichloroethene pg/L 20.0 21.6 21.6 108 108 76-141 0.0 20.0 trans-1,2-Dichloroethene pg/L 20.0 22.0 21.7 110 109 76-135 1.3 20.0 1,2-Dichloropropane pg/L 20.0 21.8 21.9 109 110 77-130 0.4 20.0 cis-1,3-Dichloropropene pg/L 20.0 20.3 20.4 102 102 65-140 0.4 20.0 trans-1,3-Dichloropropene pg/L 20.0 19.9 20.1 99.5 101 67-140 1.0 20.0 Ethylbenzene pg/L 20.0 20.7 20.4 104 102 80-127 1.4 20.0 2-Hexanone pg/L 20.0 18.6 19.3 93.0 96.5 64-137 3.6 20.0 Methyl Ethyl Ketone (MEK) pg/L 20.0 19.1 19.4 95.5 97.0 71-134 1.5 20.0 4-Methyl-2-Pentanone pg/L 20.0 20.7 21.6 104 108 69-134 4.2 20.0 Methylene Chloride pg/L 20.0 22.6 22.8 113 114 73-131 0.8 20.0 Styrene pg/L 20.0 20.8 20.7 104 104 78-129 0.4 20.0 1,1,1,2-Tetrachloroethane pg/L 20.0 19.9 19.7 99.5 98.5 79-134 1.0 20.0 1,1,2,2-Tetrachloroethane pg/L 20.0 20.5 20.4 103 102 62-127 0.4 20.0 Tetrachloroethene pg/L 20.0 19.8 20.0 99.0 100 80-129 1.0 20.0 Tetrahydrofuran pg/L 20.0 21.0 21.6 105 108 70-130 2.8 20.0 Toluene pg/L 20.0 21.5 21.1 108 106 76-131 1.8 20.0 1,1,1-Trichloroethane pg/L 20.0 21.1 20.8 106 104 75-135 1.4 20.0 1,1,2-Trichloroethane pg/L 20.0 21.9 21.9 110 110 70-140 0.0 20.0 Trichloroethene pg/L 20.0 21.5 21.1 108 106 77-133 1.8 20.0 Trichlorofluoromethane pg/L 20.0 21.3 21.0 107 105 62-148 1.4 20.0 1,2,3-Trichloropropane pg/L 20.0 20.7 19.9 104 99.5 71-127 3.9 20.0 Vinyl Acetate pg/L 20.0 20.6 22.3 103 112 34-167 7.9 20.0 Date: 02/17/2021 03:13 PM Page 8 of 9 Page 49 of 52 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Wood Environ. & Infrastructure Inc (Asheville) Project Description: WCU-MSWLF Report No: 21-041-0025 QC Prep: V574 QC Analytical Batch(es): V577 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V574 LCSD-V574 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD Vinyl Chloride pg/L 20.0 21.7 20.5 109 103 57-141 5.6 20.0 o-Xylene pg/L 20.0 20.3 19.8 102 99.0 78-128 2.4 20.0 m,p-Xylene pg/L 40.0 41.3 40.8 103 102 77-133 1.2 20.0 4-Bromofluorobenzene (S) 96.6 95.4 80-124 Dibromofluoromethane (S) 100 104 75-129 1,2-Dichloroethane - d4 (S) 99.6 99.8 63-136 Toluene-d8 (S) 95.8 97.6 77-123 Date: 02/17/2021 03:13 PM Page 9 of 9 Page 50 of 52 WayPAo0nt.. NALYTICAL 449 Springbrook Rd, Charlotte, NC 28224 Main 704.529.6364 www.wa y p of n to na lyti ca I.c om Shipment Receipt Form Customer Number: 01222 Customer Name: Wood Environ. & Infrastructure Inc (Asheville) Report Number: 21-041-0025 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 Other: 0 UPS 0 Client 0 Courier Thermometer ID: IRT-15 1.5C Shipping container/cooler uncompromised? 0 Yes 0 No Number of coolers/boxes received Custody seals intact on shipping container/cooler? 0 Yes 0 No Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? 0 Yes 0 No COC agrees with sample label(s)? 0 Yes 0 No COC properly completed 0 Yes 0 No Samples in proper containers? 0 Yes 0 No Sample containers intact? ® Yes 0 No Sufficient sample volume for indicated test(s)? 0 Yes 0 No All samples received within holding time? 0 Yes 0 No Cooler temperature in compliance? 0 Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. 0 Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No 0 N/A Water - VOA vials free of headspace 0 Yes 0 No 0 N/A Trip Blanks received with VOAs 0 Yes 0 No 0 N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No ® N/A F High concentration container (48 hr) F_ Low concentration EnCore samplers (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? Comments: F 0 Yes ® No Signature: Talon J Yelton Date & Time: 02/10/2021 09:24:33 Page 51 of 52 C; ❑ L Few 4 L L -0j z m? O n! L O N v n m _ i? L' L n QLL b L L 2 a n m L n L L a L = C N y i37 n m 3 1 , �I m 0. N ❑ C? � � r zn -1 n N id 'Ty Z mrn a in � C 4 �a m _! a me A � 2L A Q YYd W n g .i z n C n � 7' 41 m m W � m 3 � m� 'C �m m m m m 'a m � � N a a� a W C3 ri r a g r y30 m ai O a 0X° m❑• X s m-V w a G m C N 3 d im y ID maam � n m r om3�. o O �Rm�m m r 0A 0 v CD ma Z T Q my m �Naa m L �A; o v [N m Z N C p �_ �p 7'p L- Y a a N m qCML ❑ [A ❑'<. m R = Z. w d L, ro A In C1 (ar m c o❑ Ll m y q 4 Q p a w h t n x y. La m af° m L! a Zm [a`p NZ3� ❑ ..- N L lwic [Cf] N R� > N L c� m T V N. m N 0 z 0 > c 0 ne c0mv2• m Ol N -n•{ pt p ¢ C p a s m iH mz CD x c n p fn N n 4 � %-A � y W D M M r z > In < m r� n C Z X ~ O Page 52 of 52