1203_Burke_JohnsRiver_CDLF_Expansion_Nov20GW_FID1556085_20210310

t ENR USE ONLY I I ❑Paper Report []Electronic Data - Email CD (data loaded: Yes / No) Doc/Event #:
NC DENR I IEnvironmentat Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
of entity submitting data (laboratory, consultant, facility
La Bella Associates (Joyce Engineering)
Contact for questions about data formatting. Include data preparees name, telephone number and E-mail address:
Name: G. Van Ness Burbach, Ph.D., P.G. Phone: [phone]
E-mail: [e-mail]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Johns River 2500 Marsh Trail 12-03 .0500 November 10-11, 2020
C&D Landfill Expansion Morganton, NC January 27-28, 2021
Environmental Status: (Check all that apply)
Initial/Background Monitoring [X Detection Monitoring El
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells
Groundwater monitoring data from private water supply wells El
Leachate monitoring data ❑
Surface water monitoring data
Assessment Monitoring
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Corrective Action
Notification attached?
No. No groundwater or surface water standards were exceeded.
)( Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 213 surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
G. Van Ness Burbach, Ph.D., PG Sr. Technical Consultant [phone]
FacilityRepresentative Name (Print) Title (Area Code) Telephone Number
/jJ/ iJA �J ­� _0 —0i _ , _ _ _ , Affix NC Licensed/ Professional Geologist Seal
Signature ` Date ��,t,.` CARO� jti
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2211 W. Meadowview Rd., Ste. 101 Greensboro, NC 27407 & cli `f
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Facility Representative Address
C-0782
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009
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LaBeRa
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March 10, 2021
Jaclynne Drummond
Compliance Hydrogeologist
NC Department of Environmental Quality
Division of Waste Management - Solid Waste Section
2090 US Highway 70, Swannanoa, NC 28778
Via Email: [e-mail]
RE: Burke County, Johns River Landfill
Permit Number 12-03 C&D Expansion
November 2020 Semiannual Water Quality Monitoring Report
Project No. 2202300
Dear Ms. Drummond:
On behalf of Burke County, we are submitting the November 2020 Semiannual Water Quality
Monitoring Report in electronic format, as well as a copy of the Environmental Monitoring Form and
the laboratory EDDs for the C&D Expansion Landfill at the Johns River Waste Management Facility,
Permit # 12-03. This report completes the second semiannual compliance monitoring event of
2020 as required by the North Carolina Division of Waste Management, Solid Waste Section. If we
can provide any additional information, please call me at [phone].
Respectfully submitted,
LaBella Associates
Van Burbach, Ph.D., P.G.
Sr. Technical Consultant
Enclosure
cc: Brian Tart, Mark Delehant, Burke County
2211 W. Meadowview Road #sos I Greensboro, NC 27407 1 p [phone]
www.LabeLLapc.com

Prepared For:
BOARD OF COMMISSIONERS
COUNTY OF BURKE
P.O. BOX 1486
MORGANTON, NORTH CAROLINA 2868o
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Submitted by:
LaBella Associates (Joyce Engineering)
2211 West Meadow/view Rd.
Suite 1o1
Greensboro, NC 27407
(336) 323-00g2
NC License No. C-0782
LaBeRa
Powered by partnership.
NOVEMBER 2020 SEMIANNUAL WATER QUALITY
MONITORING REPORT
JOHNS RIVER WASTE MANAGEMENT FACILITY
C&D EXPANSION LANDFILL
Permit No. 12-03
MARCH 2O21
PROJECT NO. 2202300

November 2020 Semiannual Water Quality Monitoring Report
Johns River Waste Management Facility - Permit No. 12-03
C&D Expansion Landfill
Burke County, North Carolina
TABLE OF CONTENTS
1.0
INTRODUCTION........................................................................................................1
1.1
Site Information.......................................................................................................1
1.2
Site Geology.............................................................................................................. 2
1.3
Regulatory Status..................................................................................................... 2
2.0
FACILITY MONITORING PROGRAM..........................................................................3
2.1
Groundwater Monitoring Program.......................................................................... 3
2.2
Surface Water Monitoring Program........................................................................ 4
3.0
SECOND SEMIANNUAL SAMPLING EVENT OF 2019..............................................5
3.1
Field Work.................................................................................................................
5
3.1.1 Groundwater Sampling...................................................................................................................
5
3.1.2
Surface Water Sampling.................................................................................................................
6
3.2
Laboratory Analysis and Quality Control................................................................. 6
4.0
HYDROGEOLOGICAL CONDITIONS..........................................................................7
5.0
ANALYTICAL RESULTS.............................................................................................8
5.1
Inorganic Constituents in Groundwater..................................................................
8
5.2
Organic Constituents in Groundwater....................................................................
8
5.3
Analytical Results for Surface Water...................................................................... 9
5.4
Statistical Analyses..................................................................................................9
6.0
CONCLUSIONS.........................................................................................................9
7.0
REFERENCES........................................................................................................10
Burke County - Johns River Landfill, C&D Expansion, Permit No. 12-03 LaBella Associates
November 2020 Semiannual Water Quality Monitoring
Report March 2021
i

November 2020 Semiannual Water Quality Monitoring Report
Johns River Waste Management Facility - Permit No. 12-03
C&D Expansion Landfill
Burke County, North Carolina
TABLE OF CONTENTS (CONTINUED)
Tables:
Figure:
Table 1 Groundwater Elevations (November 2020)
Table 2 Hydraulic Gradients & Linear Velocities (November 2020)
Table 3 Detections of Constituents (November 2020)
Table 4 Exceedances of Standards (November 2020)
Table 5 Field Parameters (November 2020)
Figure 1 Site Location Map
Drawing.
Drawing 1 Groundwater Potentiometric Surface Map (November 2020)
Appendices:
Appendix 1 Laboratory Analytical Reports & Field Data Logs
Appendix 2
Table A2-1
Table A2-2
Table A2-3
Table A2-4
Table A2-5
Historical Data
Historical Groundwater Elevations
Historical Field Parameters
Historically Detected Groundwater Constituents in Compliance Wells
Historically Detected Constituents in Additional Wells/Piezometers
Historically Detected Surface Water Constituents
Burke County - Johns River Landfill, C&D Expansion, Permit No. 12-03
November 2020 Semiannual Water Quality Monitoring
Report
LaBella Associates
August 2020

ACRONYMS
ACM Assessment of Corrective Measures (Report)
AMSL Above Mean Sea Level
AOC Area of Concern
BGS Below Ground Surface
C&D Construction and Demolition Waste
CAP Corrective Action Plan (Report)
CAER Corrective Action Evaluation Report (Report)
CAMP Corrective Action Monitoring Plan (Report)
CAS Chemical Abstracts Service
CFR Code of Federal Regulations
COC Contaminant of Concern (for corrective action)
COC Chain of Custody (for sampling and lab reports)
DL Detection Limit (for laboratory data)
DO Dissolved Oxygen
EPA United States Environmental Protection Agency (or USEPA)
GWPS Groundwater Protection Standards (Established by NCDEQ-SWS - no longer used)
IMAC Interim Maximum Allowable Concentrations
ISTV In -Stream Target Value
MNA Monitored Natural Attenuation
MSW Municipal Solid Waste
NC2B North Carolina Surface Water Standards found in 15A NCAC 2B
NC2L North Carolina Groundwater Standards found in 15A NCAC 2L.0202
NCAC North Carolina Administrative Code
NCDENR North Carolina Dept. of Environment and Natural Resources (now the NCDEQ)
NCDEQ North Carolina Dept. of Environmental Quality (formerly the NCDENR)
NCGS North Carolina Geological Survey
NCSWMR North Carolina Solid Waste Management Regulations (15A NCAC 13B)
ND Not Detected (for laboratory data)
NES Nature and Extent Study (Report)
NRWQC Nationally Recommended Water Quality Criteria (USEPA)
QL Quantitation Limit (for laboratory data)
RL Reporting Limit (for laboratory data)
RQD Rock Quality Designation
SSI Statistically Significant Increase (above background concentrations)
SWS Solid Waste Section (of NCDEQ-Division of Waste Management)
TOC Top of Casing (Well)
USCS Unified Soil Classification System
USEPA United States Environmental Protection Agency (or EPA)
USGS United States Geological Survey
VOC Volatile Organic Compound
WQAR Water Quality Assessment Report
WQMP Water Quality Monitoring Plan
WQMR Water Quality Monitoring Report
Burke County - Johns River Landfill, C&D Expansion, Permit No. 12-03
November 2020 Semiannual Water Quality Monitoring
Report
LaBella Associates
August 2020

1.0 INTRODUCTION
1.1 Site Information
The Johns River Waste Management Facility (JRWMF) is located in the north -central portion
of Burke County, north of Morganton, North Carolina. The 318-acre landfill property is
bounded by Lower Creek to the north and east, and the Catawba River to the south. The
Catawba River forms Lake Rhodhiss along the southeastern property line (Figure 1). Lake
Rhodhiss is a long, narrow lake formed by the Rhodhiss Hydroelectric Dam located
approximately 12 miles downstream of the landfill. The John's River flows into the Catawba
River near the southwest corner of the landfill property. A Municipal Solid Waste (MSW)
transfer facility is located in the eastern half of the property. A site plan showing all the
pertinent features of the facility is provided in Drawing 1.
The site has rolling topography with elevations ranging from 975 feet to 1,150 feet above
mean sea level (AMSL). The central portion is generally gently sloping and contains the
higher elevations; relatively steep slopes and significant drainage features are located
around the perimeter. The 100-year flood boundary extends onto the landfill property. The
adjacent property to the west of the Johns River Waste Management Facility consists of
undeveloped, heavily wooded land. Properties within 2,000 feet of the landfill boundary are
covered by surface water or are heavily wooded.
An unlined municipal solid waste (MSW) landfill began operation in April 1988 on 28 acres
in the southwest corner of the landfill property, but was closed in 1997 to comply with Rule
.1627(c)(1O)(A) of the NCSWMR, a regulation governing MSW Landfills units that were not
designed with a base liner and leachate collection system. Burke County operated a
permitted Construction and Demolition (C&D) disposal area on top of the closed MSW
landfill between 1998 and 2015 that closed in 2016. The results of the November 2020
semiannual sampling event for the C&D-over-MSW landfill will be presented in a separate
report.
A Permit to Construct for Phase 1A of the C&D landfill expansion was issued in March 2014,
and the County completed construction in July 2014. On August 14, 2014, a Permit to
Operate for Phase 1A was issued to the County by the North Carolina Department of
Environment and Natural Resources, now the Department of Environmental Quality
(NCDEQ). A permit to construct was issued for two additional expansions (Phases 2A and 4)
by the NCDEQ on February 07, 2018.
Construction of Phase 2A was completed during the summer of 2018, and Phase 2A
received a temporary permit to operate after construction in a permit modification from the
NCDEQ dated November 7, 2018. The Phase 4 expansion is currently under construction
and is expected to be completed in mid 2021. In accordance with the facility approved
Water Quality Monitoring Plan (WQMP) dated May 2018 (revised November 2018), there
were three groundwater monitoring wells designated as compliance wells for Phase 1A of
the C&D Expansion: MW-21 (background), MW-20, and MW-38. MW-22S was abandoned in
Burke County - Johns River Landfill, C&D Expansion, Permit No. 12-03 LaBella Associates
November 2020 Semiannual Water Quality Monitoring
Report August 2020
1

February 2018 for construction of Phases 2A and 4. In accordance with the November
2018 revision to the May 2018 WQMP, four new monitoring wells were added to the
compliance network for Phases 2A and 4. MW-23S and MW-35 are designated as
compliance wells for Phases 2A and 4, while MW-24S and MW-30 are designated as
compliance wells for Phase 4 only. In a Background Sampling Report dated June 27, 2019,
we noted that MW-24S was mislocated and we recommended it be removed from the
compliance network. In a letter dated July 9, 2019, NCDEQ approved the request.
1.2 Site Geology
The JRWMF is located in the Inner Piedmont Belt of the Piedmont Physiographic Province,
and in close proximity to the Brevard Shear Zone. It is underlain by highly metamorphosed
rocks including gneiss and schist, as well as calc-silicate rocks, felsic rocks, and
metavolcanic rocks. The dominant rock type at the facility is biotite-muscovite schist, as
seen in outcrops, boulders, and rock cores located on site. The structures within limited
outcrops indicate that these rocks are complexly -folded, with attitudes that vary from vertical
to horizontal. The site regolith is typical of the inner piedmont and consists mostly of silty
sand, clayey sand, and sandy silt. The regolith is up to 100 feet thick and varies in thickness
with topography.
An abundance of rounded gravel, cobble, and boulder -sized alluvial deposits are exposed
along the banks of the Catawba River, which borders the site. The greatest accumulation of
these deposits is along the southwestern site boundary. These river deposits are 40 feet or
more above the current river elevation and have been described as ancient river terrace
deposits.
1.3 Regulatory Status
The following report of groundwater monitoring data from the JRWMF C&D expansion has
been prepared in accordance with the NCSWMR 15A NCAC 13B §.0544-.0545 and
§.1630-.1633. The Phase 1A and Phase 2A expansions are currently operating under the
Detection Monitoring Program. The Phase 4 expansion is still under construction and does
not yet have a permit to operate.
Session Law 2018-65, House Bill 573, approved on June 25, 2018, allows for annual
groundwater monitoring frequency at stand-alone C&D landfill facilities in detection
monitoring, as noted in the NCDEQ Solid Waste Section Memorandum dated July 13, 2018.
On behalf of Burke County, LaBella submitted a Request to Reduce Water Quality
Monitoring Frequency to Annual for the Johns River C&D Expansion Landfill to the NCDEQ-
SWS on July 9, 2020. This request was approved by the NCDEQ in a letter dated July 16,
2020.
Burke County - Johns River Landfill, C&D Expansion, Permit No. 12-03 LaBella Associates
November 2020 Semiannual Water Quality Monitoring
Report August 2021
2

2.0 FACILITY MONITORING PROGRAM
2.1 Groundwater Monitoring Program
The compliance groundwater monitoring network originally consisted of one upgradient well
(MW-21), and three downgradient wells (MW-20, MW-22S and MW-38). MW-22S was
abandoned in February 2018 for construction of Phases 2A and 4. In accordance with the
WQMP dated January 2018, four new monitoring wells were added to the compliance
network. MW-35 and MW-23S are designated as compliance wells for Phases 2A and 4,
while MW-30 is designated as compliance well for Phase 4 only. Compliance well 24S is not
longer sampled.
The following is a summary of the compliance monitoring wells:
Well ID
Date Installed
Classification
Monitoring
Total Depth of Well
Lithology of
(Former ID)
Program
(feet)
Screened Interval
MW-20
May 1995
Phase 1A
Detection
67.0
Saprolite
MW-21
May 1995
Background
Detection
46.80
Saprolite
MW-23S
June 1996
Phase 2A
Detection
22.57
Saprolite
MW-30
December
Phase 4
Detection
51.89
Saprolite
2015
MW-35
May 2011
Compliance/
Detection
39.05
Saprolite
Phase 2A
MW-38*
May 2011
Compliance/
Detection
74.50
Bedrock
Phase 1A
* MW-38 is also a performance well for the old C&D-over-MSW landfill.
Groundwater samples are collected semiannually and analyzed for constituents according to
the WQMP. The compliance well samples are analyzed for 40 CFR Part 258, Appendix I,
incorporated by reference into the NCSWMR (NC Appendix 1) organics and inorganics plus
C&D parameters and 1,4-dioxane, as required for routine assessment or detection
monitoring during both semiannual events.
In January 2014, in response to the County's permit application for the C&D expansion area,
the NCDEQ requested that additional wells and/or piezometers in the vicinity of Phases 1
and 2 of the expansion be sampled. The County agreed to sample PZ-31, PZ-30S, PZ-34,
MW-36 (formerly PZ-36), PZ-12, and MW-15S semiannually beginning with the spring 2014
sampling event. The County also agreed to sample the following wells/piezometers in the
event of Groundwater Protection Standard (GPS) exceedances in the referenced
wells/piezometers, as follows:
• PZ-3OD will be added in the event that there are GWPS exceedances at PZ-30S;
• PZ-35 will be added in the event that there are GWPS exceedances at PZ-34; however,
PZ-34 was inadvertently destroyed during the spring of 2014 and PZ-35 was sampled
Burke County - Johns River Landfill, C&D Expansion, Permit No. 12-03 LaBella Associates
November 2020 Semiannual Water Quality Monitoring
Report August 2021
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instead. Eventually, PZ-35 was converted to MW-35 in February 2018 and is now a
compliance well.
• MW-15D will be added in the event that there are GWPS exceedances at MW-15S;
• PZ-16S will be added in the event that there are GWPS exceedances at PZ-35 or
PZ-12; and
• PZ-16D will be added in the event that there are GWPS exceedances at PZ-16S.
The following is a summary of the currently sampled additional wells and piezometers:
Well ID
Date
Classification
Monitoring
Total Depth of well
Lithology of
(Former ID)
Installed
Program
(feet)
Screened Interval
MW-15S
June 1996
Add. Wells &
Detection
58.27
Saprolite
Piezometers
Add. Wells &
PZ-12
June 1996
Detection
14.90
Saprolite
Piezometers
PZ-30S
May 2011
Add. Wells &
Detection
55.30
Transition Zone
Piezometers
Add. Wells &
PZ-31
May 2011
Detection
45.60
Transition Zone
Piezometers
Add, Wells &
MW-36*
May 2011
Piezometers/
Detection
45.58
Bedrock
Performance*
*MW-36 is also a performance well for the Old C&D-over-MSW Landfill.
The additional piezometers/wells are to be sampled for the C&D-over-MSW landfill's organic
contaminants of concern (COCs) (excluding alpha-BHC and beta-BHC).
2.2 Surface Water Monitoring Program
The current surface water monitoring points are SMP-5, SMP-6, and SMP-7. Surface water
monitoring point SMP-5 (located at the southwestern property line) and SMP-6 (located at
the southeastern property line) are both located downstream from existing sediment basins.
Surface water monitoring point SMP-7 is located downstream from the Phase 1A expansion
area. The surface water monitoring program is designed to monitor for possible impacts
from both the C&D over MSW Landfill and the C&D Expansion Landfill; surface water
samples are analyzed for the NC Appendix I list of constituents plus detected NC Appendix II
constituents from the C&D-over-MSW landfill (cyanide, tin, mercury,
dichlorodifluoromethane, alpha-BHC, and beta-BHC) and 1,4-dioxane during both
semiannual events. In addition, surface water samples are analyzed for hardness to
determine appropriate hardness -based NC213 Standards for some metals.
The surface water at JRWMF is classified as Class WS-IV, meaning that it serves as a water
supply in moderately to highly developed watersheds (15A NCAC 02B §.0101(c)). This
classification dictates the NC 213 standard that applies for each constituent.
Burke County - Johns River Landfill, C&D Expansion, Permit No. 12-03 LaBella Associates
November 2020 Semiannual Water Quality Monitoring
Report August 2021
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The following is a summary of the surface water points:
Surface Point
Classification
Monitoring Program
Location
SMP-5
Compliance
Surface Water
Creek on west side of landfill, downstream of
sediment basin.
Creek on east side of landfill, downstream of
SMP-6
Compliance
Surface Water
sediment basin.
Creek southeast of Phase 1A and
SMP-7
Compliance
Surface Water
east of sediment basin SB-2A. Downstream
of PZ-12.
3.0 NOVEMBER 2020 SEMIANNUAL SAMPLING EVENT
3.1 Field Work
3.1.1 Groundwater Sampling
On November 10-11, 2020, personnel from LaBella Associates visited the JRWMF to purge
and collect groundwater samples from monitoring wells MW-15S, MW-20, MW-21, MW-23S,
MW-30, MW-35, MW-36, MW-38, PZ-12, PZ-30S, and PZ-31. On January 27-18,2021,
personeel from LaBella Associates conducted a resampling event due to missing wells and
data from November event. Depth -to -water measurements were obtained to the nearest
0.01 foot using an electronic water level indicator for all monitoring wells in the compliance
network prior to purging. The November 2020 and Janurary 2021 resample groundwater
elevations data are presented in Table 1.
Monitoring wells were purged and sampled using disposable bailers or a 12-volt
submersible pump. Measurements of temperature, pH, specific conductivity, dissolved
oxygen, oxidation reduction potential, and turbidity were recorded in the site log book as well
as on field data logs prior to purging, after each purge volume, and before sampling. Field
sampling logs for the November 2020 and January 2021 event are provided in Appendix 1.
Laboratory -supplied containers were prepared and labeled (either by the laboratory or in the
field, as indicated) with the following information:
• Monitoring well number (completed by field personnel),
• Date and time of sample collection (completed by field personnel),
• Initials of sampling personnel (completed by field personnel),
• Project name and number (completed by the laboratory),
• Chemical preservative (completed by the laboratory); and
• Requested chemical analysis (completed by the laboratory).
Groundwater samples from each monitoring well were dispensed directly from the
disposable bailers or directly from the 12-volt pump discharge tube into the provided
laboratory containers within 24 hours of the final purge volume. Immediately after
collection, the samples were placed in a laboratory -provided cooler and chilled with ice.
Burke County - Johns River Landfill, C&D Expansion, Permit No. 12-03 LaBella Associates
November 2020 Semiannual Water Quality Monitoring
Report August 2021
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3.1.2 Surface Water Sampling
Surface monitoring points SMP-5, SMP-6, and SMP-7 were sampled during the November
2020 sampling event. Surface water samples were collected directly from stream flow by
lowering a clean, unpreserved sample container into the stream flow, and then carefully
dispensing it into the laboratory -prepared sample containers. Care was taken to avoid
sample -induced turbidity. At the time of sampling, surface water was measured for
temperature, pH, specific conductivity, dissolved oxygen, oxidation reduction potential, and
turbidity and recorded in the site log book as well as on field data logs. After sample
collection, the samples were placed in a laboratory -provided cooler and chilled on ice. Field
sampling logs are provided in Appendix 1.
3.2 Laboratory Analysis and Quality Control
The November 2020 groundwater and surface water samples, as well as the January 2021
Groundwater resample, were submitted to Pace Analytical Services, Inc. of Huntersville,
North Carolina under chain -of -custody control for analysis. The November 2020
groundwater samples were analyzed for the NC Appendix I list of constituents, plus
additional required C&D parameters and 1,4-dioxane. Surface water samples were
analyzed for the NC Appendix I list of constituents plus detected NC Appendix II constituents
from the old C&D-over-MSW landfill (cyanide, tin, mercury, dichlorodifluoromethane, alpha-
BHC, and beta-BHC), plus 1,4-dioxane and hardness. The January 2021 resample of
M W-11, M W-12, M W-16S, M W-18, M W-19, M W-20, M W-21, M W-23S, M W-30, M W-35,
MW-36, and MW-38, were analyzed for various constituents based on missing data in the
November 2020 samples and wells/constituents that were not sampled for during the initial
event. As a quality control measure, LaBella Associates requested a Level II data report for
the final laboratory report. As stated in the laboratory reports, the samples were received by
the laboratory in good condition, properly preserved, and within required hold times.
In addition to samples collected for compliance monitoring at the JRWMF and as a quality
control measure, a Field Blank was collected by LaBella personnel as part of the November
2020 sampling event. Also, a Trip Blank prepared by the laboratory accompanied the
volatile sampling containers from and to the laboratory. The Field Blank was analyzed for
the NC Appendix I, plus previously detected NC Appendix 11 list of constituents, plus iron,
manganese, tetrahydrofuran, and 1,4-dioxane, and the Trip Blank was analyzed for NC
Appendix I list of constituents plus additional detected NC Appendix II volatile organic
compounds, tetrahydrofuran, and 1,4-dioxane.
Upon receipt of the laboratory data package, LaBella personnel reviewed the data package
for quality assurance/quality control (QA/QC) purposes and for possible regulatory issues. If
any QA/QC or regulatory issues were found, the laboratory would be contacted to resolve the
issue, and a resampling event might be scheduled, if needed. The laboratory analytical
packages can be found in Appendix 1 of this report. The data packages were reviewed for
the following:
Burke County - Johns River Landfill, C&D Expansion, Permit No. 12-03 LaBella Associates
November 2020 Semiannual Water Quality Monitoring
Report August 2021
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• General typographical errors;
• Correct analyses performed and within method specified hold times;
• Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike
Duplicate, and Laboratory Control Samples;
• Blank -qualified data (B-flags);
• Groundwater detections exceeding the North Carolina 15A NCAC 2L .0202
Groundwater Standards (NC2L) or Interim maximum Allowable Concentrations
(I MAC);
• Surface water detections exceeding North Carolina 15A NCAC 2B Surface Water
Standards (NC2B), NC In -Stream Target Values (ISTV), or EPA National
Recommended Water Quality Criteria (NRWQC); and
• Detections that are above historical levels.
4.0 HYDROGEOLOGICAL CONDITIONS
Based on outcrop and drilling information, the water table appears to occur within regolith
everywhere across the site. This regolith consists of residual soils, and saprolite. Beneath
the regolith lies variably fractured and weathered metamorphic bedrock. Water in the
bedrock is transmitted primarily through fractures; however, even in the saprolite there is
often enough relict structure for former fracture zones to influence groundwater flow. Along
the low-lying areas of the Catawba River and its tributaries, the water table occurs within
surficial alluvial deposits overlying the residual soils and weathered bedrock.
Static groundwater depth was measured in the compliance monitoring wells at the site prior
to sampling. The November 2020 groundwater elevations are provided in Table 1 and the
historical groundwater elevations are provided in Appendix 2, Table A2-1. The elevations
were calculated relative to the surveyed measuring point (top of casing) for each monitoring
well. A groundwater potentiometric surface map, developed from the static water level data
is presented as Drawing 1. The potentiometric surface map depicts groundwater flow
primarily to the south. Groundwater discharges into creeks to the east and west of the
landfill and to the Catawba River to the south.
Horizontal groundwater gradients along representative flow paths were estimated from the
November 2020 groundwater contours shown on Drawing 1 and are summarized in Table 2.
Horizontal gradients across the site ranged from 0.0341 to 0.0475, with an average of
approximately 0.0414. This is consistent with previous estimates.
Linear groundwater flow velocities for wells screened in saprolite were computed using the
modified Darcy equation: V = Ki/ne,, where:
V = average linear velocity (feet/year),
K = hydraulic conductivity (feet/day),
i = horizontal hydraulic gradient, and
ne = effective porosity.
Burke County - Johns River Landfill, C&D Expansion, Permit No. 12-03 LaBella Associates
November 2020 Semiannual Water Quality Monitoring
Report August 2021
7

The average of hydraulic conductivities from slug -tests conducted at the facility (K = 3.28
feet/day) was used in these calculations, along with an effective porosity of ne = 0.40 (40%)
based on laboratory porosities for soil samples from the facility. The estimated linear
groundwater flow velocity under the facility ranged from 100-150 feet/year, with an
average flow velocity of approximately 124 feet/year (Table 2). The modified Darcy equation
makes the simplified assumptions of a homogeneous and isotropic porous aquifer.
Migration of groundwater contaminants are expected to follow the general groundwater flow
paths and there are no known preferred pathways or barriers to groundwater flow that could
significantly affect plume migration or the effectiveness of the groundwater monitoring
network to monitoring plume migration. The current groundwater monitoring network
remains sufficient for monitoring the groundwater at this facility.
5.0 ANALYTICAL RESULTS
The complete laboratory reports and chains -of -custody for the November 2020 sampling
event for the C&D Expansion Area, as well as the January 2021 resample, are included in
Appendix 1. The constituents detected above the Method Detection Limit (MDL) in one or
more of the compliance monitoring wells, additional wells/piezometers, or surface
monitoring points are presented in Table 3. The constituents in exceedance of their
respective standards in one or more of the compliance monitoring wells, additional
wells/piezometers, or surface monitoring points are presented in Table 4. Field parameters
for the November 2020 sampling event as well as the Janurary 2021 resample, are
presented in Table 5, and the historical field parameters are presented in Appendix 2, Table
A2-2. Historical detected groundwater constituents are presented in Tables A2-3 and A24
in Appendix 2. Historical detected surface water constituents are presented in Table A2-5 in
Appendix 2.
5.1 Inorganic Constituents in Groundwater
On June 3, 2020, Labella submitted an Alternate Source Demonstration (ASD) for metals to
NCDEQ and NCDEQ approved the ASD on June 9, 2020. The ASD established background -
based Groundwater Protection Standards (GPS) for cobalt (11.3 pg/L), iron (14,182 pg/L),
manganese (535 pg/L), and vanadium (45.2 pg/L). A statistical background was aslo
calculated for thallium, but it was below the current IMAC so the GPS remains the IMAC.
Four inorganic constituents (cobalt, iron, manganese, vanadium) were detected above the
method reporting limit (MRL) in one or more monitoring wells during the November 2020
sampling event. Four inorganic constituents were detected above their respective NC2L,
IMAC, or background -based standards in one or more monitoring wells during the November
2020 sampling event. Iron was reported above its background -based standard in
monitoring wells MW-21 and MW-38; however, the results of the January 28, 2021,
resampling event refuted the exceedance of Iron in MW-21. Manganese was reported
above its background -based standard in monitoring well MW-38. Cobalt was reported above
Burke County - Johns River Landfill, C&D Expansion, Permit No. 12-03 LaBella Associates
November 2020 Semiannual Water Quality Monitoring
Report August 2021
8

its background -based standard in monitoring well MW-36. Vanadium was reported above its
background -based standard in monitoring well MW-21; however, the results of the January
28, 2021, resampling event refuted the exceedance of Vanadium in MW-21. These results
are generally consistent with historical data found in Table A2-3 and Table A24 (Appendix
2).
5.2 Organic Constituents in Groundwater
Eight organic constituents (1,1-dichloroethene; 1,4-dichlorobenzene; cis-1,2-dichloroethene;
benzene; tetrachloroethene; trichloroethene; vinyl chloride; and total xylenes) were detected
at quantified concentrations above the MRL in monitoring wells MW-36 and/or MW-38
during the November 2020 sampling event. Benzene, 1,4-dichlorobenzene,
tetrachloroethene, and vinyl chloride were in exceedance of their NC2L standards in
monitoring wells MW-36 and/or MW-38. In general, the detections and concentrations are
consistent with historical data presented in Tables A2-3 and A24 (Appendix 2).
MW-36 and MW-38 are located between the old C&D-over-MSW landfill and the C&D
Expansion landfill. It appears that the VOCs detected in monitoring wells MW-36 and
MW-38 are related to landfill gas migration from the old C&D-over-MSW landfill and do not
represent a release from the C&D Expansion Landfill. For more detailed discussion of these
exceedances, see the November 2020 WQMR for the C&D-over-MSW landfill.
5.3 Analytical Results for Surface Water
During the November 2020 sampling event, cobalt copper, iron, lead, and manganese were
detected above their respective NC2B standards, ISTVs, or NRWQCs. In one or more of the
surface water samples. Historical surface water data can be found in Table A2-5 (Appendix
2). These metals are believed to be naturally occurring. See the November 2020 WQMR for
the C&D-over-MSW landfill for further discussion.
5.4 Statistical Analyses
Statistical evaluation of background for iron, manganese, thallium and vanadium were
presented in the June 2020 Alternate Source Demonstration (ASD). No additional statistical
calulations were performed for this report.
6.0 CONCLUSIONS
Benzene, 1,4-dichlorobenzene, tetrachloroethene, vinyl chloride, cobalt, iron, and
manganese were detected above their respective groundwater protection standards (GPS) in
MW-38 and MW-36 during the November 2020 sampling event; however, these
exceedances are believed to be due to landfill gas migration from the C&D-over-MSW
Landfill and are being addressed in the January 2018 addendum to the August 2013
Burke County - Johns River Landfill, C&D Expansion, Permit No. 12-03 LaBella Associates
November 2020 Semiannual Water Quality Monitoring
Report August 2021
9

Corrective Action Plan for that landfill that was approved by the NCDEQ in a letter dated
February 7, 2018. These results are consistent with historical data from the site.
Cobalt, copper, iron, lead, and manganese were detected above Surface Water Standards
for surface water samples from the November 2020 sampling event.
The groundwater flow regime is consistent with previous events and the groundwater
monitoring network remains adequate to monitor the site.
Based on analytical results from the November 2020 sampling event, C&D Expansion Area
of the Johns River Landfill will remain in Detection Monitoring. The next annual sampling
event is tentatively scheduled for May 2021.
7.0 REFERENCES
Joyce Engineering (JOYCE), 1994. Transition Plan, Johns River Waste Management Facility.
April 1994.
JOYCE, 2000. Water Quality Assessment Report, Johns River Waste Management Facility.
January 2000.
JOYCE, 2004. Update on Groundwater Assessment Activities, Johns River Waste
Management Facility. October 2004.
JOYCE, 20O5a. Assessment of Corrective Measures Report, Johns River Waste
Management Facility. February 2005.
JOYCE, 2005b. Quantitative Risk Assessment, Johns River Waste Management Facility.
February 2005.
JOYCE, 2008. Corrective Action Plan, Johns River Waste Management Facility. June 2008.
JOYCE, 2011. Corrective Action Evaluation Report, Johns River Waste Management Facility.
May 2011.
JOYCE, 2013. Addendum to the Corrective Action Plan, Johns River Waste Management
Facility. August 2013.
JOYCE, 2016. Corrective Action Evaluation Report, Johns River Waste Management Facility.
April 2016.
JOYCE, 2017. Water Quality Monitoring Plan, Johns River Waste Management Facility.
Revised January 2017.
JOYCE, 2018. Addendum #2 to the Corrective Action Plan, Johns River Waste Management
Facility. January 2018.
Burke County - Johns River Landfill, C&D Expansion, Permit No. 12-03 LaBella Associates
November 2020 Semiannual Water Quality Monitoring
Report August 2021
10

JOYCE, 2018. Water Quality Monitoring Plan, Johns River Waste Management Facility.
Revised November 2018.
North Carolina Department of Environmental Quality (NCDEQ), 2011. North Carolina Solid
Waste Management Rules. 15 NCAC 13B. Amended April 2011.
North Carolina Department of Environmental Quality (NCDEQ), 2011. North Carolina
Environmental Management Rules. 15A NCAC 02B .0101 (c).
Sumsion, C.T., and Laney, R.L., 1967, Geology and Ground -water Resources of the
Morganton area North Carolina. N.C. Department of Water Resources, Ground Water
Bulletin No. 12, 119 p.
U.S. Environmental Protection Agency (USEPA), 2009. Statistical Analysis of Groundwater
Monitoring Data at RCRA Facilities, Unified Guidance. March 2009.
Burke County - Johns River Landfill, C&D Expansion, Permit No. 12-03 LaBella Associates
November 2020 Semiannual Water Quality Monitoring
Report August 2021
11

TABLES
Table 1
Groundwater Elevations (November 2020)
Table 2
Hydraulic Gradients & Linear Velocities (November 2020)
Table 3
Detections of Constituents (November 2020)
Table 4
Exceedances of Standards (November 2020)
Table 5
Field Parameters (November 2020)

TABLE 1: Groundwater Elevations (November 2020)
Background
Expansion C&D Landfill Compliance
Additional Wells and Piezometers
Well ID
MW-21
MW-20
MW-23S
MW-35
MW-38
MW-36
(Former ID)
M W-30
M W-15S
PZ-12
PZ-30S
PZ-31
(PZ-1)
(PZ-4)
(PZ-16S)
(PZ-35)
(PZ-38)
(PZ-36)
TOC Elevation
1099.86
1115.04
1040.23
1054.35
1063.39
1087.76
1069.04
1025.64
1088.92
1089.81
1099.52
(FT - AMSL)
Well Depth
46.80
67.00
20.00
50.00
39.05
74.50
58.27
14.90
55.30
45.60
45.58
(FT - BTOC)
Water Levels Measured November 11, 2020
Depth to Water
28.58
NS
NS
NS
21.30
40.62
41.51
14.90
37.96
27.40
31.60
(FT - BTOC)
Groundwater
Elevation
1071.28
NS
NS
NS
1042.09
1047.14
1027.53
1010.74
1050.96
1062.41
1067.92
(FT - AMSL)
Water Levels Measured January 27, 2021
Depth to Water
28.45
56.90
8.54
27.11
21.86
41.23
NS
NS
NS
NS
33.80
(FT - BTOC)
Groundwater
Elevation
1071.41
1058.14
1031.69
1027.24
1041.53
1046.53
NS
NS
NS
NS
1065.72
(FT - AMSL)
Notes:
TOC = Top of Casing
FT - AMSL = Feet above mean sea level
FT - BTOC = Feet below TOC
Burke County --Johns River C+D Expansion Landfill Labella Associates
Permit No. 12-03

TABLE 2: Hydraulic Gradients and Linear Velocities (November 2020)
November 11, 2020
GRADIENT
CALCULATION
SEGMENT
FLOW LINE
LENGTH
(feet)
FLOW
DIRECTION
GROUNDWATER
ELEVATION
(feet)
HORIZONTAL
GRADIENT
HYDRAULIC
CONDUCTIVITY
K
(feet/day)
EFFECTIVE
POROSITY
n e
LINEAR
VELOCITY
V
(feet/year)
1065
11
2,050
S
0.0341
3.28E+00
0.40
102
995
1065
12
1,475
S
0.0475
3.28E+00
0.40
142
995
1065
13
1,385
SE
0.0469
3.28E+00
0.40
140
1000
1065
14
1,220
SE
0.0369
3.28E+00
0.40
110
1020
AVERAGE:
0.0414
AVE RAGE:
124
Notes:
Hydraulic conductivity (K=3.28 fVday) is based on the average K from individual slug tests in saprolite wells at the facility.
Effective Porosity (n e = 0.40) is assummed to be slightly less than the average laboratory porosity for site soil samples (saprolite) = 44% (0.44).
Gradient segments are based on the November 2019 groundwater potentiometric surface map (see Drawing 1).
V = Kiln e; assumes a homogeneous, isotropic, porous aquifer.
Burke County Johns River C+D Expansion Landfill LaBella Associates
Permit # 12-03

TABLE 3: Detected Constituents (November 2020)
SAMPLE ID
PARAMETER
RESULT
UNITS
METHOD
MDL
MRL
STANDARD
SOURCE
Date
Groundwater Background
Barium
47.4
pg/L
EPA 6010D
3.5
5
700
NC2L
Chromium
7.0
pg/L
EPA 6010D
3.7
5
10.0
NC2L
Cobalt
8.7
pg/L
EPA 6010D
3.6
5
11.3
BKGD
Copper
19.7
pg/L
EPA 6010D
4.3
5
1,000
NC2L
MW-21
Iron
15,400
pg/L
EPA 6010D
41.5
50
14,182
NC2L
11/11/2020
Manganese
348
pg/L
EPA 6010D
3.4
5
535
BKGD
Vanadium
63.0
pg/L
EPA 6010D
3.9
5
45.2
BKGD
Zinc
17.2
pg/L
EPA 6010D
9.5
10
1,000
NC2L
Chloride
720 J
pg/L
SM 4500-CI-E-2011
500
1,000
250,000
NC2L
Cobalt
NO
pg/L
EPA 6010D
3.6
5
11.3
BKGD
1203-MW21*
Iron
799
pg/L
EPA 6010D
41.5
50
14,182
BKGD
1/28/2021
Manganese
34.1
pg/L
EPA 6010D
3.4
5
535
BKGD
Vanadium
ND
pg/L
EPA 6010D
3.9
5
45.2
BKGD
C&D Expansion Groundwater Compliance
Barium
25.0
pg/L
EPA 6010D
3.5
5
700
NC2L
Iron
444
pg/L
EPA 6010D
41.5
50
14,182
NC2L
MW 20'
Manganese
10.3
pg/L
EPA 6010D
3.4
5
535
BKGD
1/28/2021
Thallium
0.06 J
pg/L
EPA 6020E
0.05
0
0.20
IMAC
Total Dissolved Solids
42,000
pg/L
SM 254OC-2011
25000
25,000
500,000
NC2L
Chloride
534 J
pg/L
SM 4500-CI-E-2011
500
1,000
250,000
NC2L
Sulfate
746 J
pg/L
EPA 300.0 Rev 2.11993
500
1,000
250,000
NC2L
Barium
14.1
pg/L
EPA 6010D
3.5
5
700
NC2L
Iron
1,340
pg/L
EPA 6010D
41.5
50
14,182
BKGD
MW-23S*
Manganese
70.7
pg/L
EPA 6010D
3.4
5
535
BKGD
1/28/2021
Zinc
11.4
pg/L
EPA 6010D
9.5
10
1,000
NC2L
Total Dissolved Solids
30,000
pg/L
SM 254OC-2011
25000
25,000
500,000
NC2L
Chloride
3,060
pg/L
SM 4500-CI-E-2011
500
1,000
250,000
NC2L
Barium
32.4
pg/L
EPA 6010D
3.5
5
700
NC2L
Iron
713
pg/L
EPA 6010D
41.5
50
14,182
BKGD
Manganese
33.8
pg/L
EPA 6010D
3.4
5
535
BKGD
MW-30*
Alkalinity, Total as CaC%
14,300
pg/L
SM 2320B-2011
5000
5,000
NE
NE
1/28/2021
Total Dissolved Solids
157,000
pg/L
SM 2540C-2011
25000
25,000
500,000
NC2L
Chloride
1,230
pg/L
SM 4500-CI-E-2011
500
1,000
250,000
NC2L
MW-35
Carbon dioxide
19,400
pg/L
RSK-175
1270
9,000
NE
NE
11/11/2020
Barium
30.9
pg/L
EPA 6010D
3.5
5
700
NC2L
Iron
240
pg/L
EPA 6010D
41.5
50
14,182
BKGD
Manganese
5.5
pg/L
EPA 6010D
3.4
5
535
BKGD
MW-35*
Alkalinity, Total as CaCO3
8,650
pg/L
SM 2320B-2011
5000
5,000
NE
NE
�28/2021
Total Dissolved Solids
48,000
pg/L
SM 2540C-2011
25000
25,000
500,000
NC2L
Chloride
1,090
pg/L
SM 4500-CI-E-2011
500
1,000
250,000
NC2L
Arsenic
4.8 J
pg/L
EPA 6010D
4.7
10
10.0
NC2L
Barium
95.4
pg/L
EPA 6010D
3.5
5
700
NC2L
Cadmium
0.43 J
pg/L
EPA 6010D
0.4
1
2.0
NCH
Cobalt
7.5
pg/L
EPA 6010D
3.6
5
11.3
BKGD
1,1-Dichloroethane
4.1
pg/L
EPA8260D
0.27
1
6.0
NC2L
1,2-Dichlorobenzene
0.38 J
pg/L
EPA8260D
0.29
1
20.0
NC2L
1,2-Dichloroethane
0.52 J
pg/L
EPA8260D
0.34
1
0.4
NC2L
1,4-Dichlorobenzene
14
pg/L
EPA 8260D
0.26
1
6.0
NC2L
Benzene
4.7
pg/L
EPA8260D
0.15
1
1.0
NC2L
MW-38
Chlorobenzene
0.67 J
pg/L
EPA8260D
0.23
1
50.0
NC2L
11/11/2020
cis-1,2-Dichloroethene
8.1
pg/L
EPA 8260D
0.29
1
70.0
NC2L
Ethylbenzene
1.4
pg/L
EPA 8260D
0.26
1
600
NC2L
Naphthalene
3.7
pg/L
EPA 8260D
0.35
1
6.0
NC2L
o-Xylene
0.78 J
pg/L
EPA 8260D
0.22
1
500
NCH
Toluene
0.64 J
pg/L
EPA8260D
0.24
1
600
NC2L
Vinyl chloride
1.1
pg/L
EPA 8260D
0.24
1
0.03
NC2L
Methane
12,000
pg/L
RSK 175 Modified
3.4
10
NE
NE
Carbon dioxide
154,000
pg/L
RSK-175
2,540
18,000
NE
NE
Sulfate
806 J
pg/L
EPA 300.0 Rev 2.11993
500
1,000
250,000
NC2L
Iron
19600
pg/L
EPA 6010D
41.5
50
14,182
BKGD
Manganese
7,780
pg/L
EPA 6010D
3.4
5
535
BKGD
MW-38*
1,4-Dioxane (p-Dioxane)
2.7
pg/L
EPA 8260D Mod.
1.2
2
3.0
NC2L
1/28/2021
Alkalinity, Total as CaCO3
275,000
pg/L
SM 2320B-2011
5,000
5,000
NE
NE
Total Dissolved Solids
222,000
pg/L
SM 2540C-2011
25,000
25,000
500,000
NC2L
Chloride
9,010
pg/L
SM 4500-CI-E-2011
500
1,000
250,000
NCH
C&D Expansion Groundwater -Additional Wells and Piezometers
1,4-Dichlorobenzene
0.70 J
pg/L
EPA8260D
0.26
1
6.0
NC2L
Tetrachloroethene
0.70 J
pg/L
EPA8260D
0.16
1
1.0
IMAC
11/11/2020
MW-15S
Methane
14,500
pg/L
RSK 175 Modified
3.4
10
NE
NE
Carbon dioxide
121,000
pg/L
RSK-175
2,540
18,000
NE
NE
PZ-12
Carbon dioxide
19,100
pg/L
RSK-175
1 1,270
9,000
NE
NE
11/11/2020
Burke Co. -Johns River C+D Expansion Landfill
Permit No. 12-03 Page 1 of 2 LaBella Associates

TABLE 3: Detected Constituents (November 2020)
SAMPLE ID
PARAMETER
RESULT
UNITS
METHOD
MDL
MRL
STANDARD
SOURCE
Date
PZ30S
Methane
186 J
pg/L
RSK 175 Modified
3.4
10
NE
NE
Carbon dioxide
36,200
pg/L
RSK-175
1,270
9,000
NE
NE
11/11/2020
Barium
100
pg/L
EPA 6010D
3.5
5
700
NC21-
Cobalt
45.7
pg/L
EPA 6010D
3.6
5
11.3
BKGD
Nickel
5.8
pg/L
EPA 6010D
3.5
5
100
NCH
Thallium
0.052 J
pg/L
EPA 6020E
0.05
0
0.20
IMAC
1,1-Dichloroethane
2.5
pg/L
EPA8260D
0.27
1
6.0
NC2L
1,2-Dichlorobenzene
0.50 J
pg/L
EPA8260D
0.29
1
20.0
NC21-
1,2-Dichloroethane
0.63 J
pg/L
EPA8260D
0.34
1
0.4
NC21-
1,4-Dichlorobenzene
15.2
pg/L
EPA 8260D
0.26
1
6.0
NC21-
MW-36
Benzene
4.0
pg/L
EPA8260D
0.15
1
1.0
NC21-
11/11/2020
Chlorobenzene
0.80 J
pg/L
EPA8260D
0.23
1
50.0
NC21-
cis-1,2-Dichloroethene
12.7
pg/L
EPA 8260D
0.29
1
70.0
NC21-
Ethylbenzene
0.69 J
pg/L
EPA8260D
0.26
1
600
NC21-
Tetrachloroethene
2.3
pg/L
EPA8260D
0.16
1
1.0
IMAC
Trichloroethene
1.7
pg/L
EPA8260D
0.22
1
200
NC21-
Xylene (Total)
10.8
pg/L
EPA 8260D
0.63
1
500
NC21-
Methane
14,200
pg/L
RSK 175 Modified
3.4
10
NE
NE
Carbon dioxide
208,000
pg/L
RSK-175
2,540
18,000
NE
NE
PZ-31
Carbon dioxide
10,700
pg/L
RSK-175
1,270
9,000
NE
NE
11/11/2020
Surface Water
Barium
20.3
pg/L
EPA 6010D
3.5
5
1,000
NC2B
Iron
4,550
pg/L
EPA 6010D
41.5
50
1,000
NRWQC
SMP5
Manganese
72.2
pg/L
EPA 6010D
3.4
5
50
NRWQC
11/11/2020
Vanadium
12.0
pg/L
EPA 6010D
3.9
5
NE
NE
Hardness, Total
16,900
pg/L
EPA 6010D
131
662
100,000
NC2B
Barium
38.5
pg/L
EPA 6010D
3.5
5
1,000
NC26
Chromium
4.7 J
pg/L
EPA 6010D
3.7
5
15.33
NC213*
Cobalt
4.1 J
pg/L
EPA 6010D
3.6
5
3
ISTV
Copper
5.7
pg/L
EPA 6010D
4.3
5
1.73
NC2B*
Iron
7,270
pg/L
EPA 6010D
41.5
50
1,000
NRWQC
SMP6
Lead
5.4
pg/L
EPA 6010D
4.5
5
0.29
NC2B*
11/11/2020
Manganese
231
pg/L
EPA 6010D
3.4
5
50
NRWQC
Thallium
0.076 J
pg/L
EPA 6020B
0.05
0.1
2
ISTV
Vanadium
14.6
pg/L
EPA 6010D
3.9
5
NE
NE
Hardness, Total
14,600
pg/L
EPA 6010D
131
662
100,000
NC26
Barium
52.5
pg/L
EPA 6010D
3.5
5
1,000
NC26
Chromium
8.0
pg/L
EPA 6010D
3.7
5
20.48
NC2B*
Cobalt
5.3
pg/L
EPA 6010D
3.6
5
3
ISTV
Copper
10.6
pg/L
EPA 6010D
4.3
5
2.34
NC26*
Iron
9,650
pg/L
EPA 6010D
41.5
50
1,000
NRWQC
Lead
9.9
pg/L
EPA 6010D
4.5
5
0.44
NC2B*
SMP7
Manganese
154
pg/L
EPA 6010D
3.4
5
50
NRWQC
11/11/2020
Nickel
4.2 J
pg/L
EPA 6010D
3.5
5
13.78
NC2B*
Thallium
0.12
pg/L
EPA 6020E
0.05
0.1
2
ISTV
Vanadium
22.5
pg/L
EPA 6010D
3.9
5
NE
NE
Zinc
18.4
pg/L
EPA 6010D
9.5
10
30.98
NC2B*
Hardness, Total
20,800
pg/L
EPA 6010D
131
662
100,000
1 NC2B
Notes:
pg/L= micrograms per liter.
MOIL = Method Detection Limit
MRL = Method Reporting Limit
J = Estimated concentration below the MRL
B = Blank-qualilfied data due to detections in equipment, trip, or method blanks.
Bold = quantified detections above the Standard
*= Resample event January 2021
NC21- = INC Groundwater Standard frme 15A NCAC 2L.0202
IMAC = NC Interim Maximum Allowable Concentration (IMAC)
NC2B = INC Surface Water Standard from15A NCAC 2B
(NC2B- =hardness -dependant standard)
ISTV = NC In -Stream Target Values
NRWQC = EPA's National Recommended Water Quailty Criteria
NE = Not established
Burke Co. -Johns River C+D Expansion Landfill
Permit No. 12-03 Page 2 of 2 LaBelle Associates

TABLE 4: Exceedances of Standards (November 2020)
SAMPLE ID
PARAMETER
RESULT
UNITS
METHOD
MDL
MRL
STANDARD
SOURCE
COLLECT DATE
Iron (refuted)
15,400
ug/L
EPA 6010D
41.5
50
14,182
NC2L
11/11/2020
MW-21
Vanadium (refuted)
63
ug/L
EPA 6010D
3.9
5
45.2
BKGD
MW 36
Cobalt
45.7
ug/L
EPA 6010D
3.6
5
11.3
BKGD
11/11/2020
1,4-Dichlorobenzene
15.2
ug/L
EPA 8260D
0.26
1
6.0
NC2L
Benzene
4.0
ug/L
EPA 8260D
0.15
1
1.0
NC2L
Tetrachloroethene
2.3
ug/L
EPA 8260D
0.16
1
1.0
IMAC
1,4-Dichlorobenzene
14
ug/L
EPA 8260D
0.26
1
6.0
NC2L
MW-38
Benzene
4.7
ug/L
EPA 8260D
0.15
1
1.0
NC2L
11/11/2020
Vinyl chloride
1.1
ug/L
EPA 8260D
0.24
1
0.03
NC2L
M W-38*
Iron
19,600
ug/L
EPA 6010D
41.5
50
14,182
BKGD
1/28/2021
Manganese
7,780
ug/L
EPA 6010D
3.4
5
535
BKGD
1203
Iron
4,550
pg/L
EPA 6010D
41.5
50
1,000
NRWQC
11/11/2020
SMP5
Manganese
72.2
pg/L
EPA 6010D
3.4
5
50
NRWQC
1203 SMP6
Copper
5.7
pg/L
EPA 6010D
4.3
5
1.73
NC2B*
11/11/2020
Iron
7,270
pg/L
EPA 6010D
41.5
50
1,000
NRWQC
Lead
5.4
pg/L
EPA 6010D
4.5
5
0.29
NC2B*
Manganese
231
pg/L
EPA 6010D
3.4
5
50
NRWQC
Cobalt
5.3
pg/L
EPA 6010D
3.6
5
3
ISTV
Copper
10.6
pg/L
EPA 6010D
4.3
5
2.34
NC2B*
1203-SMP7
Iron
9,650
pg/L
EPA 6010D
41.5
50
1,000
NRWQC
11/11/2020
Lead
9.9
pg/L
EPA 6010D
4.5
5
0.44
NC2B*
Manganese
154
pg/L
EPA 6010D
3.4
5
50
NRWQC
Notes:
pg/L= micrograms per liter.
MDL = Method Detection Limit
MRL = Method Reporting Limit
J = Estimated concentration below the MRL
B = Blank-qualilfied data due to detections in equipment, trip, or method blanks.
*= Resample event January 2021
(refuted) = resample results were below the standard.
NC2L = NC Groundwater Standard frme 15A NCAC 2L.0202
IMAC = NC Interim Maximum Allowable Concentration (IMAC)
NC213 = NC Surface Water Standard from15A NCAC 2B
(NC2B* = hardness -dependant standard)
ISTV = NC In -Stream Target Values
NRWQC = EPA's National Recommended Water Quality Criteria
NE = Not established
Burke Co. -Johns River C+D Expansion Landfill
Permit No. 12-03 Page 1 of 1 La Bella Associates

TABLE 5: Field Parameters (November 2020)
WELL ID
PARAMETER
RESULT
UNITS
I COLLECT DATE
Groundwater Background
pH
6.05
S.U.
Temperature
15.9
°C
Turbidity
318.0
NTU
ORP
246.1
my
MW-21
DO
8.67
mg/L
11/11/2020
Ferrous Iron
0.0
mg/L
Conductivity
17.3
PS/cm
Static Water Level
28.58
ft
Well Depth
46.80
ft
pH
5.88
S.U.
Temperature
14.3
°C
Turbidity
9.0
NTU
ORP
96.2
my
MW-21**
DO
7.65
mg/L
1/28/2021
Ferrous Iron
0.0
mg/L
Conductivity
11.7
PS/cm
Static Water Level
28.45
ft
Well Depth
46.80
1 ft
C&D Expansion Landfill Compliance Wells
pH
5.89
S.U.
Temperature
16.4
°C
Turbidity
10.7
NTU
MW-20**
Conductivity
11.4
PS/cm
1/28/2021
ORP
142.10
my
DO
7.83
mg/L
Static Water Level
56.90
ft
Well Depth
67.00
ft
pH
5.29
S.U.
Temperature
5.41
°C
Turbidity
10.8
NTU
MW-23S**
Conductivity
22.8
PS/cm
1/28/2021
ORP
119.0
my
DO
4.2
mg/L
Static Water Level
8.45
ft
Well Depth
20.00
ft
pH
6.09
S.U.
Temperature
15.1
°C
Turbidity
9.96
NTU
MW-30**
Conductivity
30.9
PS/cm
1/28/2021
ORP
129.2
my
DO
7.1
mg/L
Static Water Level
27.11
ft
Well Depth
50
ft
Burke Co. - Johns River C+D Expansion Landfill LaBella Associates
Permit No. 12-03 1 of 4

TABLE 5: Field Parameters (November 2020)
WELL ID
PARAMETER
RESULT
UNITS
COLLECT DATE
pH
5.78
S.U.
Temperature
17.20
°C
Turbidity
76.70
NTU
MW-35
11/11/2020
DO
3.63
mg/L
Conductivity
24.7
PS/cm
Static Water Level
21.30
ft
Well Depth
39.05
ft
pH
5.76
S.U.
Temperature
15.60
°C
Turbidity
8.85
NTU
MW-35**
1/28/2021
DO
4.35
mg/L
Conductivity
18.5
PS/cm
Static Water Level
21.86
ft
Well Depth
39.05
ft
pH
6.27
S.U.
Temperature
17
°C
Turbidity
4.9
NTU
MW-38
11/11/2020
DO
115
mg/L
Conductivity
502
PS/cm
Static Water Level
40.62
ft
Well Depth
74.50
ft
pH
6.42
S.U.
Temperature
14.4
°C
Turbidity
7.4
NTU
MW-38**
1/28/2021
DO
3.83
mg/L
Conductivity
342.5
PS/cm
Static Water Level
41.23
ft
Well Depth
74.50
ft
C&D Expansion Groundwater - Additional Wells and Piezometers
pH
5.1
S.U.
Temperature
17
°C
Turbidity
13.60
NTU
MW-15S
Conductivity
46.4
PS/cm
11/11/2020
ORP
137.9
PS/Cm
DO
4.58
my
Static Water Level
41.51
ft
Well Depth
58.27
ft
Burke Co. - Johns River C+D Expansion Landfill LaBella Associates
Permit No. 12-03 2 of 4

TABLE 5: Field Parameters (November 2020)
WELL ID
PARAMETER
RESULT
UNITS
COLLECT DATE
pH
5.43
S.U.
Temperature
17.3
°C
Turbidity
189.0
NTU
PZ-12
Conductivity
26.7
PS/cm
11/11/2020
ORP
63.5
PS/cm
DO
5.75
mV
Static Water Level
7.42
ft
Well Depth
14.90
ft
pH
5.52
S.U.
Temperature
20.6
°C
Turbidity
2.26
NTU
PZ-30S
Conductivity
24.1
NTU
11/11/2020
ORP
67.2
PS/cm
DO
3.83
mV
Static Water Level
37.96
ft
Well Depth
55.30
ft
pH
6.69
S.U.
Temperature
17.6
°C
Turbidity
22.00
NTU
PZ-31
Conductivity
26.5
PS/cm
11/11/2020
ORP
32.2
PS/cm
DO
6.43
mV
Static Water Level
27.40
ft
Well Depth
45.60
ft
pH
5.55
S.U.
Temperature
17.7
°C
Turbidity
7.01
NTU
MW-36
Conductivity
215.4
PS/cm
11/11/2020
ORP
113
PS/cm
DO
3.3
mV
Static Water Level
31.60
ft
Well Depth
45.58
ft
pH
6.37
S.U.
Temperature
15.4
°C
Turbidity
276.0
NTU
MW-36**
Conductivity
241
PS/cm
1/28/2021
ORP
64.4
PS/cm
DO
2.48
mV
Static Water Level
33.80
ft
Well Depth
45.58
1 ft
Burke Co. - Johns River C+D Expansion Landfill LaBella Associates
Permit No. 12-03 3 of 4

TABLE 5: Field Parameters (November 2020)
WELL ID
PARAMETER
RESULT
UNITS I COLLECT DATE
Surface Water
pH
6.77
S.U.
Temperature
18.7
°C
SMP-5
Turbidity
124.0
NTU
1/11/1900
ORP
91.5
my
DO
5.61
mg/L
Conductivity
61.8
PS/cm
pH
6.25
S.U.
Temperature
18.9
°C
SMP-6
Turbidity
293.0
NTU
11/11/2020
ORP
145.1
my
DO
7.94
mg/L
Conductivity
39.7
PS/cm
pH
6.43
S.U.
Temperature
19.2
°C
SMP-7
11/11/2020
DO
6.29
mg/L
Turbidity
338.0
NTU
Conductivity
48.3
1 pS/cm
Notes: °C = degrees Centigrade
S.U. = Standard Units
pS/cm = microSemens per centimeter
NTU = Nephelometric Turbidity Units
mg/L = milligrams per liter
my = millivolts
ft = feet
** = sample collected during 01/28/2021 resampling event
Burke Co. - Johns River C+D Expansion Landfill LaBella Associates
Permit No. 12-03 4 of 4

FIGURE
Figure 1 Site Location Map

t�# rl
t
Is
..........
--- --- Pcp
120
APPROXIMATE LOCATION
Q
OF PROPERTY LINE
if
ti�
Nq
Lunn
ol
1101
FOOO
SOURCE: U.S.G.S. TOPOGRAPHIC MAP
FOR MORGANTON NORTH, N.C.
N G.
0 1000 2000 000
ISSUED FOR:
LaBeLLa GROUNDWATER MONITORING REPORT
Powered by partnership. DRAWING NAME: DRAWN BY: DATE: � PROJECT NO.:
SITE LOCATION MAP RWH 02/27/19 2192621
2211 WEST VEADOWVIEW ROAD
GREENSBORO, N.C. 27407
PHONE: [phone] PROJECT NAME: DRAWING NUMBER:
JOHNS RIVER LANDFILL Figure 1
labellapc.com @ 2020 LaBelle Associates BURKE COUNTY, NORTH CAROLINA
I
I N:\D.9.\D,..1.9.-C.—nt\BURKE:\GW EVENT MAPS, JOHNS RIVER SITE LOCATION MAP 2020.d.g

DRAWING
Drawing 1 Groundwater Potentiometric Surface Map (November 2020)

�� , �f ��
LaBeLLa
,\
Powered b partnership.
Y P P
2211 W. MEADOWVIEW ROAD
GREENSBORO, NC 27407
\\ \ \ P TECTED REA
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LEGEND
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1050 EXISTING 25 TOPOGRAPHIC CONTOUR
1080 EXISTING 10' TOPOGRAPHIC CONTOUR
/
EXISTING 5' TOPOGRAPHIC CONTOUR
EXISTING 2' TOPOGRAPHIC CONTOUR
N\'
GROUNDWATER SURFACE CONTOUR [FEET
� 020 ABOVE MEAN SEA LEVEL (AMSL)]
\
TRANSFER FACILITY
PROPERTY LINE
GROUNDWATER FLOW PATHWAY USED TO
CALCULATE HYDRAULIC GRADIENT
CURRENT BACKGROUND W LL
EXISTING ROAD
APPROXIMATE LIMITS OF WASTE
WETLAND
�\� \ ''� \ ,� �` ���� �/� -�\ �\
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o tl � � � —�
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'
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o JE-0020 CONTROL POINT LOCATION AND IDENTIFICATION
0
SEGMENT USED FOR GRADIENT CALCULATION
W- I L L\ _1-
14 M -IIII / � � //� �
b 7.0 J ) / // ��
-23D 1 �
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FLOW PATH LENGTH
-23S CC
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i 2,050 LF
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/11 'r / _- ��� \ \ PZ- 1 I '� I ,°� �� �- 1 `
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NOTES
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0 0 APPRO LIMIT O\� \ I \�
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)UN D R
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_
1. TOPOGRAPHIC CONTOUR INTERVAL 2 AND 10 FEET.
2. GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET.
,W S
v \ \ I I J
3. STATIC WATER LEVELS WERE MEASURED ON NOVEMBER 11, 2020.
4. GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION BETWEEN AND
EXTRAPOLATION FROM KNOWN DATA TOPOGRAPHIC CONTOURS AND KNOWN
,
001
FIELD CONDITIONS.
5. MW-16D GROUNDWATER ELEVATION WAS NOT USED IN CALCULATING
� �— �� \� �� ���� �� � �� \V � � �\� ���'°�° \ ✓�� � 1i/������� �
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GROUNDWATER CONTOURS.
N0:
DATE:
DESCRIPTION:
Revisions
,,�
���'77 _�\v\ V�
6-0 \
PROJECT NUMBER:
2192621.00
DRAWN BY:
\ EXISTING
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\ SEDIMENT Q /\\\\
o \\\�— _ - �� i
BASIN o � � �_ ��/� i
\ \ �� _ _ ✓ ��� �� MW-16S
9� � i /
� 1
RH
REVIEWED BY:
VB
ISSUED FOR:
GROUNDWATER REPORT
DATE:
_— __ - 6D � �
SMP-5
✓� — 99
a MOM =1 `
J ✓O �( � '�/
01�2O�Z1
DRAWING NAME:
s
994.25
993.44
GROUNDWATER SURFACE
CONTOUR MAP
ON,
NOVEMBER 11, 2020
_ GRAPHIC SCALE
_ 0 100 200 400 1 \�� I
-�_ —� (FEET) ��
DRAWING NUMBER:

APPENDICES
Appendix 1 Laboratory Analytical Reports & Field Data Logs
Appendix 2 Historical Data

Appendix 1
Field Data Logs & Laboratory Analytical Reports

0 LaBella
DATE: 26
GROUND WATER SAMPLING LOG
Project Name: SAP. CO.:S�)n 's Project No. /Task No.: a a 03 23CO, 061oq
Well ID: rq LJ—,SSY
o I Sampler(s):Z J' h-� sk D. & "
Well Location:q (vZ. - d QS 1'`10- I�Q S
Well Diameter:
Initial Depth to Water (DTW)
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
` 0' 6 `� feet
"7 9--S feet
�3•$� feet [DTB-DTW]
�• 5r gallons
gallons
= 16 •� gallons
6. gallons
Purged with:
Bailer
PUmo
Other:
Sampled with:
Bailer
Pum
Other:
Depth to Water before Sampling:
feet
Gallons
Time
Temp
(°C)
pH
Cond.
(uS/cm)
Dis.02
mg/L
ORP
my
Turb. Initials
(ntu)
O
0 �" (
, 5�-
1 ' og
L-/s 1.
q7S,O
zo3
rDate
1600
�7, a
6,
5Q'),
NS
of sample:
I
l.-6
Before Sampling
3�&,P
tirn
ieaje(
Comments (weather conditions, odor, color, silt, etc.):
�6 s
I�
Signature: 4e. ���` Date:
QA/QC Sign Off: i '-��— Date: l i 1'> 2r0Zz-�

0 LaBella
DATE: I1//o -- 11/2��20
GROUND WATER SAMPLING LOG
Project Name: '��t {{�� &C CIO SO%NS �• Project No. /Task No.: ?Q o23oo, o%
Well ID: r 7, "1r)— Sampler(s): e 0 —t A Lj Bendy —
Well Location: IQ �i i � © d,
.
Well Diameter: 2 inch 4 2�
Initial Depth to Water (DTW): 1 •90 feet
Depth to Bottom (DTB): 7•q9 feet
Water Column Thickness (WCT): 7, �g feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 gallons
For 4" Well: WCT X 0.653 = gallons
For THREE Well Volumes: WV X 3 = 3, 6 gallons
Actual Amount Purged/Bailed: gallons
Purged with: _ Ba er Pump Other:
Sampled with: z A�ai I Pump Other:
Depth to Water before Sampling: 7,-7q feet
Time
Temp
(°C)
pH
Cond.
(US/CM)
Dis.02
mg/L
ORP
my
Turb. Initials
(ntu)
FGs
16�D
)G�w
6•
. 3�
��.$
�.ai
,�s-.1
734
3�Cc
Date of sample:
Before Sampling
1300
C3•�
Comments (weather conditions, odor, color, silt, etc.):
cr�l CIO -i An
Signature: Date:_ RA /20a-b
QA/QC Sign Off: Date: I

0 La Bella
DATE: IWO -II .202O
n GROUND WATER SAMPLING LOG
Project Name: f f- 0!)A65 1� =0 a 2 jJ Project No. /Task No.: , cj::4/6a
Well ID: MQ'3 Sampler(s):e.MqIA-,
Well Location: %ow!t P7 - 3 )
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
2 inches
-21 •S feet
39, vs feet
R-75 feet [DTB-DTW]
gallons
=
gallons
gallons
�
gallons
Purged with: ailer Pump Other:
Sampled with: Baile'� Pump Other:
Depth to Water before Sampling: 029 feet
Gallons
Time
Temp
(°C)
pH
Cond.
(US/CM)
Dis.02
mg/L
ORP
my
Turb. InitiJals
(ntu)
6
1��6
17.
2. J
1�92
17. b
S. y2
a3,
�.9
�6 3.H
Mond
B�
15N4.
16,
�.a
aQ,3
3f 63
17a, `3
>1God
.1 `7
1`7 s,s
oc)
Date of sample:
I�/�i1
ao
[Before Sampling
���
(-7,
5,78
dZ�,�
�, (,_S
12,�-
Comments (weather conditions, odor, color, silt, etc.):
`S —70`S
R
Signature: LADate: 0a0
QA/QC Sign Off: Date: /3 2t»Zv

e LaBella
DATE: 1) /0-1 1 / Q b
/l GROUND WATER SAMPLING LOG
Project Name: & e (y . �b"f�S �. Project No. /Task No.: Q�202& n, W/00
Well ID: T Z -3(D !F, Sampler(s)l�r;��p,
Well Location: . bcc-�'Z� M Ql, 31
Well Diameter:
Initial Depth to Water (DTW)
Depth to Bottom (DTB):
Water Column Thickness (WCT)
2 inches.---. - . - -
3-7.5 6 feet
:55 Sr6 feet
'�•3q feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 = �' gallons
For 4" Well: WCT X 0.653 = gallons
For THREE Well Volumes: WV X 3 4 gallons
Actual Amount Purged/Bailed: g ° L gallons
Purged with: Pump Other:
Sampled with: 'I— er�) Pumg Other
Depth to Water before Sampling: 37, 1 feet
Gallons
Time
Temp
pH
Cond.
Dis.02
ORP
Turb.
Initials
(°C)
(uS/cm)
mg/L
my
(ntu)
0
�LJ
�,
�yso
��, i
s.a9
35,
a•g6
i'3�. 6
-7 3
�. 6
03-
gz9. 9
�, 3H
N n 3
�y 7
��
Iy <e
a-o,7
5, bR
20,q
3, 61
1 Sq. 6
�7y
Date of sample:
l
()2-b
Before Sampling
0•
�';��
3, g�
�7.
•,�
Comments (weather conditions, odor, color, silt, etc.):
7otS Dor�v d o o d u
Signature: Date: PAW
QA/QC Sign Off: Date: f3 c z -)

0 LaBella
DATE: Il l l t—V D0
GROUND WATER SAMPLING LOG
Project Name: J�Uat C_p , f�U\tnS Project No. /Task No.: gI L 6Za0" oc°weD
Well ID: P2L ��' Sampler(s):, 4i .F_54,is, E"e,
Well Location:
W5fl Diameter:
MA
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT)
Calculation for One Well Volume (WV):
-56
2 inches
feet
95,66 feet
13, Q feet [DTB-DTW]
For 2" Well: WCT X 0.163 = % gallons
For 4" Well: WCT X 0.653 = q gallons
For THREE Well Volumes: WV X 3 gallons
Actual Amount Purged/Bailed: ��gallons
Purged with: CEO Pump Other:
Sampled with: Pump Other:
Depth to Water before Sampling: 2-7, � 1;?, feet
Gallons
Time
Temp
(°C)
pH
Cond.
(uS/cm)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
2,qi
►yza
�7.q
17.E
6.32
�.a�
aa.e
fro. a
y.yo
s.cg
z6.0
�o.S
13�
C.3y
6,q
6.q.
(Gq. I
332
Date of sample:
/�, /
10
Before Sampling
to a�s-
P. %
r., ��
�6.5
6.N 3
3q.0-
a Q. 6
Comments (weather conditions, odor, color, silt, etc.):
Signature: JA Date:'/1/ 2,)(�
QA/QC Sign Off: — Date: 0/13Zozp

0 LaBella
DATE: ////O -11 /�- Q
n GROUND WATER SAMPLING LOG
Project Name: 2 �S K , J / 2a Oa'3c)o.dd/o
J LAC
f�.. J0� Project No. Task No.: �
Well ID: m �� p Sampler(s):Z: Wr+q�k,
Well Location: WrA mW 3 z7
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
2 inches
314 b feet
�feet
eet [DTB-DTW]
•� gallons
gallons
= 61q, gallons
19 1 09 gallons
Purged with: aile� Pump Other:
Sampled with: Bailers Pump Other:
Depth to Water before Sampling: 3),06 feet
Gallons
Time
Temp
(°C)
pH
Cond.
(US/CM)
Dis.02
mgL
ORP
my
Turb.
(ntu)
Initials
17.3
s-��
I.9q
7gii
1357
14 _ R
q2
2s 0
a ty
s-�'.'gL. 7
I-1.s6
1qa!
c,gy
1ya 3
1-7 . 6
�.t�
30g,q
"677
33,,y
�1Iq
Date of sample:
Before Sampling
104 0
�'],�
5.��'
�15.
�• 30
113 L,617.
d
Comments (weather conditions, odor, color, silt, etc.):
0'S—%0`S
WS Uan) f Q A `7—
Signature: C. Date: erA11.2-0ea-6
QA/QC Sign Off: - Date: 13 2a O

0 LaBella
It/,I a -(i�
DATE:J;�A
f"s
(� GROUND WATER SAMPLING LOG
Project Name:Y)L>U� ��� 11, z�J Project No. /Task No.: 3w.,uoA72
Well ID: Sampler(s):L, 06614 kS b j AJe
Well Location:
t'Im ;S
Well Diameter: 2 inches 4k trd\_�M
Initial Depth to Water (DTW):feet
Depth to Bottom (DTB): 6' ASO feet
Water Column Thickness (WCT): 6.'29L feet (DTB-DTWI
k
Calculation for One Well Volume (WV):
For 2" Well
For 4" Well
WCT X 0.163 = -7 gallons
WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled witt
Depth to Water before Sampling: 2 Y, ! C1 feet
gallons
gallons
gallons
Gallons
Time
Temp
pH
Cond.
Dis.02
mgL
my
ORr P
Turb.
(ntu)
Init
ials(US/Cm)
d
(4,35
11,
7-7'3
Ti /5
r� •��
OC��
iSrS
`�,�U
'`fir=�
't,�"�
���.�
� �i
Date of sample:
I i
12COL-C
Before Sampling
0135
t
S_
1-7, j .
a, ,7
Qy
Comments (weather cconditions, odor, color, silt, etc.):
I -'-2o' S i,,�ts-1', (71 o,) J a 'i r r I C\
Signature: . &k, Date:
QA/QC Sign Off: Date: /� /3

DATE: f AVZD��
0, LaBettaby�,SURFACE WATER MONITORING LOG
Project Name: Project/Task No.: -Qa09SC0.0o1O
Surface Point ID:yM 1 — Sampler(s):f- ��C4. k.9S�S , p, �d(!S'
Location: Y1 �lkzaM Y(c N - Ia W'34 n-�
Field Parameters:
Time of Sampling: 1316
pH: C, a.`7
Temperature:
Conductivity:
Turbidity:
Dissolved Oxygen
Oxidation -Reduction Potential
Comments/Sample Description
aO's - 7ig_5 0iirlL, /-,I,
`J
3-q•-7 (US/CM)
qq 3 (ntu)
,.% H
(mg/L)
(mv)
er conditions, odor, color, silt, etc.):
Signature: Date:
QA/QC Sign Off: . Date:

DATE: 11/ 1l/ 202L
LaBetta
Powt!red by no.rtri r-hi, SURFACE WATER MONITORING LOG
Project Name: I� e° Co. 5_o6s Project/Task No.: C)2_300_,C90/op ?
Surface Point ID: f)— Sampler(s):f"i � p, mac_
Location: —> eD
Field Parameters:
Time of Sampling:
pH:
Temperature:
Conductivity:
Turbidity:
Dissolved Oxygen
Oxidation -Reduction Potential
,o ments/Sample Description 1
6 0's-- "M's r�.,- I I. _ A
136 6
G' q 3
`33g
6.�
VQ
(US/CM)
(ntu)
(mg/L)
(mv)
er conditions, odor, color, silt, etc.):
�7 f A
Signature: Date: f/1-2o 0-6
QA/QC Sign Off: Date: t/13?.v-v

DATE:
LaBetLa
Powe ec€ by n,xtn r5NP SURFACE WATER MONITORING LOG
Project Name:LgLe- C-J:p.�On6•s Project/Task No.: PQC`)300, 00/0Q
Surface Point ID: Sm P— Sampler(s):,rGJhgV,K. g c5—
Location:(' CeeK LL�n ta.� .y G�
I �
Field Parameters:
Time of Sampling:
pH:
Temperature:
Conductivity:
Turbidity:
Dissolved Oxygen
Oxidation -Reduction Potential
nq1`7
6"Q-7"7
(US/cm)
q (ntu)
�'. f I (mg/L)
gl,15 (mv)
Comments/Sample Description
/(weather conditions, odor, color, silt, etc.):
676,5 --�h S no r4l � r ("l n, ,Y)% i ra fka I'l
Summary/Sketch of Sampling Location
�w-10
d
Flo
Signature: C c Date: /// ��/,2,ya0
QA/QC Sign Off: '(JY Date: I I I j3 lu 4' _

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
January 26, 2021
Mr. Van Burbach
Joyce Engineering -Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on November 12, 2020. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Gulf Coast
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
This report was issued on 1/26/21 to report the full NC App I VOC list for 92506094-001, -006, and -007, and to report the
full list of NC App I Metals for 92506094-001 and -007, per client request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Van Burbach, Joyce Engineering -NC
Gretta Eller, LaBella Associates, D.P.C.
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
�pQ ACrfFO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
9e0 without the written consent of Pace Analytical Services, LLC.
Page 1 of 37

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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
CERTIFICATIONS
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
Pace Analytical Gulf Coast
7979 Innovation Park Drive, Baton Rouge, LA 70820
Arkansas Certification #: 88-0655
DoD ELAP Certification #: L18-597
Florida Certification #: E87854
Illinois Certification #: 004585
Kansas Certification #: E-10354
Louisiana/LELAP Certification #: 01955
North Carolina Certification #: 618
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Dakota Certification #: R-195
Oklahoma Certification #: 2019-101
South Carolina Certification #: 73006001
Texas Certification #: T104704178-19-11
USDA Soil Permit # P330-19-00209
Virginia Certification #: 460215
Washington Certification #: C929
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 2 of 37

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92506094001
1203-MW-36
Water
11/11/20 10:40
11/12/20 09:51
92506094002
1203-MW-15S
Water
11/11/20 11:10
11/12/20 09:51
92506094003
1203-PZ-12
Water
11/11/20 13:00
11/12/20 09:51
92506094004
1203-PZ-31
Water
11/11/20 10:25
11/12/20 09:51
92506094005
1203-PZ30S
Water
11/11/20 10:35
11/12/20 09:51
92506094006
1203-MW-35
Water
11/11/20 12:35
11/12/20 09:51
92506094007
1203-MW-38
Water
11/11/20 10:02
11/12/20 09:51
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 37

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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
92506094001 1203-MW-36
EPA 8081 B
SEM
4
PASI-C
RSK 175 Modified
MAD
1
PASI-C
RSK-175
JAR
1
GCLA
EPA 601OD
SH1
14
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
CL
50
PASI-C
92506094002 1203-MW-15S
RSK 175 Modified
MAD
1
PASI-C
RSK-175
JAR
1
GCLA
EPA 8260D
CL
11
PASI-C
92506094003 1203-PZ-12
RSK 175 Modified
MAD
1
PASI-C
RSK-175
JAR
1
GCLA
EPA 8260D
CL
11
PASI-C
92506094004 1203-PZ-31
RSK 175 Modified
MAD
1
PASI-C
RSK-175
JAR
1
GCLA
EPA 8260D
CL
11
PASI-C
92506094005 1203-PZ30S
RSK 175 Modified
MAD
1
PASI-C
RSK-175
JAR
1
GCLA
EPA 8260D
CL
11
PASI-C
92506094006 1203-MW-35
RSK 175 Modified
MAD
1
PASI-C
RSK-175
JAR
1
GCLA
EPA 8260D
CL
50
PASI-C
92506094007 1203-MW-38
EPA 8081 B
SEM
4
PASI-C
RSK 175 Modified
MAD
1
PASI-C
RSK-175
JAR
1
GCLA
EPA 601 OD
RDT
14
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
CL
59
PASI-C
GCLA = Pace Analytical Gulf Coast
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 4 of 37

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
Burke Co Johns Riv Add MW/PZs-Revised Report
92506094
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92506094001
1203-MW-36
RSK 175 Modified
Methane
14200
ug/L
10.0
11/17/20 13:03
RSK-175
Carbon dioxide
208000
ug/L
18000
11/23/20 17:10
EPA 6010D
Barium
100
ug/L
5.0
11/18/20 22:54
EPA 6010D
Cobalt
45.7
ug/L
5.0
11/18/20 22:54
EPA 6010D
Nickel
5.8
ug/L
5.0
11/18/20 22:54
EPA6020B
Thallium
0.052J
ug/L
0.10
11/17/2017:40
EPA 8260D
Benzene
4.0
ug/L
1.0
11/17/20 03:55
EPA 8260D
Chlorobenzene
0.801
ug/L
1.0
11/17/20 03:55
EPA 8260D
1,2-Dichlorobenzene
0.50J
ug/L
1.0
11/17/20 03:55
EPA 8260D
1,4-Dichlorobenzene
15.2
ug/L
1.0
11/17/20 03:55
EPA 8260D
1,1-Dichloroethane
2.5
ug/L
1.0
11/17/20 03:55
EPA 8260D
1,2-Dichloroethane
0.63J
ug/L
1.0
11/17/20 03:55
EPA 8260D
cis-1,2-Dichloroethene
12.7
ug/L
1.0
11/17/20 03:55
EPA 8260D
Ethylbenzene
0.69J
ug/L
1.0
11/17/20 03:55
EPA 8260D
Tetrachloroethene
2.3
ug/L
1.0
11/17/20 03:55
EPA 8260D
Trichloroethene
1.7
ug/L
1.0
11/17/20 03:55
EPA 8260D
Xylene (Total)
10.8
ug/L
1.0
11/17/20 03:55
92506094002
1203-MW-15S
RSK 175 Modified
Methane
14500
ug/L
10.0
11/17/20 13:19
RSK-175
Carbon dioxide
121000
ug/L
18000
11/23/20 17:15
EPA 8260D
1,4-Dichlorobenzene
0.70J
ug/L
1.0
11/17/2003:36
EPA 8260D
Tetrachloroethene
0.70J
ug/L
1.0
11/17/20 03:36
92506094003
1203-PZ-12
RSK-175
Carbon dioxide
19100
ug/L
9000
11/23/20 17:30
92506094004
1203-PZ-31
RSK-175
Carbon dioxide
10700
ug/L
9000
11/23/20 17:34
92506094005
1203-PZ30S
RSK 175 Modified
Methane
186
ug/L
10.0
11/17/20 14:05 M1
RSK-175
Carbon dioxide
36200
ug/L
9000
11/23/20 17:40
92506094006
1203-MW-35
RSK-175
Carbon dioxide
19400
ug/L
9000
11/23/20 17:47
92506094007
1203-MW-38
RSK 175 Modified
Methane
12000
ug/L
10.0
11/17/20 14:20
RSK-175
Carbon dioxide
154000
ug/L
18000
11/23/20 18:03
EPA 6010D
Arsenic
4.8J
ug/L
10.0
01/25/2104:19
EPA 6010D
Barium
95.4
ug/L
5.0
01/25/2104:19
EPA 6010D
Cadmium
0.43J
ug/L
1.0
01/25/2104:19
EPA 6010D
Cobalt
7.5
ug/L
5.0
01/25/2104:19
EPA 8260D
Benzene
4.7
ug/L
1.0
11/17/20 04:31
EPA 8260D
Chlorobenzene
0.67J
ug/L
1.0
11/17/20 04:31
EPA 8260D
1,2-Dichlorobenzene
0.38J
ug/L
1.0
11/17/20 04:31
EPA 8260D
1,4-Dichlorobenzene
14.0
ug/L
1.0
11/17/20 04:31
EPA 8260D
1,1-Dichloroethane
4.1
ug/L
1.0
11/17/20 04:31
EPA 8260D
1,2-Dichloroethane
0.52J
ug/L
1.0
11/17/20 04:31
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 5 of 37

leAnalyiical
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Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
Burke Co Johns Riv Add MW/PZs-Revised Report
92506094
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92506094007
1203-MW-38
EPA 8260D
cis-1,2-Dichloroethene
8.1
ug/L
1.0
11/17/20 04:31
EPA 8260D
Ethylbenzene
1.4
ug/L
1.0
11/17/20 04:31
EPA 8260D
Naphthalene
3.7
ug/L
1.0
11/17/20 04:31
EPA 8260D
Toluene
0.64J
ug/L
1.0
11/17/20 04:31
EPA 8260D
Vinyl chloride
1.1
ug/L
1.0
11/17/20 04:31
EPA 8260D
o-Xylene
0.78J
ug/L
1.0
11/17/20 04:31
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 6 of 37

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ANALYTICAL RESULTS
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
Sample: 1203-MW-36 Lab ID: 92506094001 Collected: 11/11/20 10:40 Received: 11/12/20 09:51 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8081 OC Pesticides RVE
alpha-BHC
beta-BHC
Surrogates
Tetrachloro-m-xylene (S)
Decachlorobiphenyl (S)
RSK 175 Headspace
Methane
EPA RSK-175
Carbon dioxide
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
6020 MET ICPMS
Thallium
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Date: 01/26/2021 09:01 AM
Analytical Method: EPA 8081 B Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
ND ug/L
0.050
0.019
1
11/18/2018:40
11/19/2013:33
319-84-6
ND ug/L
0.050
0.014
1
11/18/2018:40
11/19/2013:33
319-85-7
137 %
10-184
1
11/18/2018:40
11/19/2013:33
877-09-8
86 %
10-154
1
11/18/2018:40
11/19/2013:33
2051-24-3
Analytical Method: RSK 175 Modified
Pace Analytical Services
- Charlotte
14200 ug/L
10.0
3.4
1
11/17/2013:03
74-82-8
Analytical Method: RSK-175
Pace Analytical Gulf Coast
208000 ug/L
18000
2540
20
11/23/2017:10
124-38-9
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical Services
-Asheville
ND ug/L
5.0
3.0
1
11/17/20 02:36
11/18/20 22:54
7440-36-0
ND ug/L
10.0
4.7
1
11/17/20 02:36
11/18/20 22:54
7440-38-2
100 ug/L
5.0
3.5
1
11/17/20 02:36
11/18/20 22:54
7440-39-3
ND ug/L
1.0
0.70
1
11/17/20 02:36
11/18/20 22:54
7440-41-7
ND ug/L
1.0
0.40
1
11/17/20 02:36
11/18/20 22:54
7440-43-9
ND ug/L
5.0
3.7
1
11/17/20 02:36
11/18/20 22:54
7440-47-3
45.7 ug/L
5.0
3.6
1
11/17/20 02:36
11/18/20 22:54
7440-48-4
ND ug/L
5.0
4.3
1
11/17/20 02:36
11/18/20 22:54
7440-50-8
ND ug/L
5.0
4.5
1
11/17/20 02:36
11/18/20 22:54
7439-92-1
5.8 ug/L
5.0
3.5
1
11/17/20 02:36
11/18/20 22:54
7440-02-0
ND ug/L
10.0
4.7
1
11/17/20 02:36
11/18/20 22:54
7782-49-2
ND ug/L
5.0
2.5
1
11/17/20 02:36
11/18/20 22:54
7440-22-4
ND ug/L
5.0
3.9
1
11/17/20 02:36
11/18/20 22:54
7440-62-2
ND ug/L
10.0
9.5
1
11/17/20 02:36
11/18/20 22:54
7440-66-6
Analytical Method: EPA 6020B Preparation Method:
EPA 3010A
Pace Analytical Services
-Asheville
0.052J ug/L
0.10
0.050
1
11/17/20 02:15
11/17/20 17:40
7440-28-0
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND ug/L
25.0
6.2
1
11/17/20 03:55
67-64-1
ND ug/L
10.0
0.90
1
11/17/20 03:55
107-13-1
4.0 ug/L
1.0
0.15
1
11/17/20 03:55
71-43-2
ND ug/L
1.0
0.34
1
11/17/20 03:55
74-97-5
ND ug/L
1.0
0.26
1
11/17/20 03:55
75-27-4
ND ug/L
1.0
0.62
1
11/17/20 03:55
75-25-2
ND ug/L
2.0
0.62
1
11/17/20 03:55
74-83-9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 37

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
Sample: 1203-MW-36 Lab ID: 92506094001 Collected: 11/11/20 10:40 Received: 11/12/20 09:51 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 01/26/2021 09:01 AM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
5.0
3.3
1
11/17/20 03:55
78-93-3
ND
ug/L
2.0
0.40
1
11/17/20 03:55
75-15-0
ND
ug/L
1.0
0.22
1
11/17/20 03:55
56-23-5
0.801
ug/L
1.0
0.23
1
11/17/20 03:55
108-90-7
ND
ug/L
1.0
0.49
1
11/17/20 03:55
75-00-3
ND
ug/L
5.0
2.3
1
11/17/20 03:55
67-66-3
ND
ug/L
1.0
0.39
1
11/17/20 03:55
74-87-3
ND
ug/L
5.0
0.26
1
11/17/20 03:55
96-12-8
ND
ug/L
1.0
0.41
1
11/17/20 03:55
124-48-1
ND
ug/L
1.0
0.26
1
11/17/20 03:55
106-93-4
ND
ug/L
1.0
0.46
1
11/17/20 03:55
74-95-3
0.501
ug/L
1.0
0.29
1
11/17/20 03:55
95-50-1
15.2
ug/L
1.0
0.26
1
11/17/20 03:55
106-46-7
ND
ug/L
1.0
0.54
1
11/17/20 03:55
110-57-6
2.5
ug/L
1.0
0.27
1
11/17/20 03:55
75-34-3
0.63J
ug/L
1.0
0.34
1
11/17/20 03:55
107-06-2
ND
ug/L
1.0
0.24
1
11/17/20 03:55
75-35-4
12.7
ug/L
1.0
0.29
1
11/17/20 03:55
156-59-2
ND
ug/L
1.0
0.25
1
11/17/20 03:55
156-60-5
ND
ug/L
1.0
0.19
1
11/17/20 03:55
78-87-5
ND
ug/L
1.0
0.30
1
11/17/20 03:55
10061-01-5
ND
ug/L
1.0
0.31
1
11/17/20 03:55
10061-02-6
0.69J
ug/L
1.0
0.26
1
11/17/20 03:55
100-41-4
ND
ug/L
5.0
0.57
1
11/17/20 03:55
591-78-6
ND
ug/L
20.0
12.5
1
11/17/20 03:55
74-88-4
ND
ug/L
5.0
3.7
1
11/17/20 03:55
75-09-2
ND
ug/L
5.0
4.5
1
11/17/20 03:55
108-10-1
ND
ug/L
1.0
0.27
1
11/17/20 03:55
100-42-5
ND
ug/L
1.0
0.34
1
11/17/20 03:55
630-20-6
ND
ug/L
1.0
0.22
1
11/17/20 03:55
79-34-5
2.3
ug/L
1.0
0.16
1
11/17/20 03:55
127-18-4
ND
ug/L
1.0
0.24
1
11/17/20 03:55
108-88-3
ND
ug/L
1.0
0.18
1
11/17/20 03:55
71-55-6
ND
ug/L
1.0
0.24
1
11/17/20 03:55
79-00-5
1.7
ug/L
1.0
0.22
1
11/17/20 03:55
79-01-6
ND
ug/L
1.0
0.31
1
11/17/20 03:55
75-69-4
ND
ug/L
1.0
0.35
1
11/17/20 03:55
96-18-4
ND
ug/L
2.0
1.4
1
11/17/20 03:55
108-05-4
ND
ug/L
1.0
0.24
1
11/17/20 03:55
75-01-4
10.8
ug/L
1.0
0.63
1
11/17/20 03:55
1330-20-7
99
%
70-130
1
11/17/20 03:55
460-00-4
114
%
70-130
1
11/17/20 03:55
17060-07-0
101
%
70-130
1
11/17/20 03:55
2037-26-5
REPORT
OF LABORATORY ANALYSIS
This report shall not be reproduced,
except in full,
without the written
consent of Pace
Analytical Services, LLC.
Page 8 of 37

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
Sample: 1203-MW-15S
Lab ID: 92506094002 Collected:
11/11/20 11:10
Received: 11/12/20 09:51 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
14500 ug/L 10.0
3.4
1
11/17/2013:19
74-82-8
EPA RSK-175
Analytical Method: RSK-175
Pace Analytical Gulf Coast
Carbon dioxide
121000 ug/L 18000
2540
20
11/23/20 17:15
124-38-9
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Benzene
ND ug/L 1.0
0.15
1
11/17/20 03:36
71-43-2
1,4-Dichlorobenzene
0.70J ug/L 1.0
0.26
1
11/17/20 03:36
106-46-7
1,1-Dichloroethane
ND ug/L 1.0
0.27
1
11/17/20 03:36
75-34-3
1,2-Dichloroethane
ND ug/L 1.0
0.34
1
11/17/20 03:36
107-06-2
Methylene Chloride
ND ug/L 5.0
3.7
1
11/17/20 03:36
75-09-2
Tetrachloroethene
0.70J ug/L 1.0
0.16
1
11/17/20 03:36
127-18-4
Trichloroethene
ND ug/L 1.0
0.22
1
11/17/20 03:36
79-01-6
Vinyl chloride
ND ug/L 1.0
0.24
1
11/17/20 03:36
75-01-4
Surrogates
4-Bromofluorobenzene (S)
100 % 70-130
1
11/17/20 03:36
460-00-4
1,2-Dichloroethane-d4 (S)
108 % 70-130
1
11/17/20 03:36
17060-07-0
Toluene-d8 (S)
102 % 70-130
1
11/17/20 03:36
2037-26-5
Date: 01/26/2021 09:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 37

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
Sample: 1203-PZ-12
Lab ID: 92506094003 Collected:
11/11/20 13:00
Received: 11/12/20 09:51 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
ND ug/L 10.0
3.4
1
11/17/2015:21
74-82-8
EPA RSK-175
Analytical Method: RSK-175
Pace Analytical Gulf Coast
Carbon dioxide
19100 ug/L 9000
1270
10
11/23/20 17:30
124-38-9
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Benzene
ND ug/L 1.0
0.15
1
11/17/20 02:23
71-43-2
1,4-Dichlorobenzene
ND ug/L 1.0
0.26
1
11/17/20 02:23
106-46-7
1,1-Dichloroethane
ND ug/L 1.0
0.27
1
11/17/20 02:23
75-34-3
1,2-Dichloroethane
ND ug/L 1.0
0.34
1
11/17/20 02:23
107-06-2
Methylene Chloride
ND ug/L 5.0
3.7
1
11/17/20 02:23
75-09-2
Tetrachloroethene
ND ug/L 1.0
0.16
1
11/17/20 02:23
127-18-4
Trichloroethene
ND ug/L 1.0
0.22
1
11/17/20 02:23
79-01-6
Vinyl chloride
ND ug/L 1.0
0.24
1
11/17/20 02:23
75-01-4
Surrogates
4-Bromofluorobenzene (S)
100 % 70-130
1
11/17/20 02:23
460-00-4
1,2-Dichloroethane-d4 (S)
108 % 70-130
1
11/17/20 02:23
17060-07-0
Toluene-d8 (S)
100 % 70-130
1
11/17/20 02:23
2037-26-5
Date: 01/26/2021 09:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 10 of 37

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
Sample: 1203-PZ-31
Lab ID: 92506094004 Collected:
11/11/20 10:25
Received: 11/12/20 09:51 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
ND ug/L 10.0
3.4
1
11/17/2013:49
74-82-8
EPA RSK-175
Analytical Method: RSK-175
Pace Analytical Gulf Coast
Carbon dioxide
10700 ug/L 9000
1270
10
11/23/20 17:34
124-38-9
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Benzene
ND ug/L 1.0
0.15
1
11/17/20 02:42
71-43-2
1,4-Dichlorobenzene
ND ug/L 1.0
0.26
1
11/17/20 02:42
106-46-7
1,1-Dichloroethane
ND ug/L 1.0
0.27
1
11/17/20 02:42
75-34-3
1,2-Dichloroethane
ND ug/L 1.0
0.34
1
11/17/20 02:42
107-06-2
Methylene Chloride
ND ug/L 5.0
3.7
1
11/17/20 02:42
75-09-2
Tetrachloroethene
ND ug/L 1.0
0.16
1
11/17/20 02:42
127-18-4
Trichloroethene
ND ug/L 1.0
0.22
1
11/17/20 02:42
79-01-6
Vinyl chloride
ND ug/L 1.0
0.24
1
11/17/20 02:42
75-01-4
Surrogates
4-Bromofluorobenzene (S)
97 % 70-130
1
11/17/20 02:42
460-00-4
1,2-Dichloroethane-d4 (S)
110 % 70-130
1
11/17/20 02:42
17060-07-0
Toluene-d8 (S)
102 % 70-130
1
11/17/20 02:42
2037-26-5
Date: 01/26/2021 09:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 37

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
Sample: 1203-PZ30S
Lab ID: 92506094005 Collected:
11/11/20 10:35
Received: 11/12/20 09:51 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
186 ug/L 10.0
3.4
1
11/17/2014:05
74-82-8 M1
EPA RSK-175
Analytical Method: RSK-175
Pace Analytical Gulf Coast
Carbon dioxide
36200 ug/L 9000
1270
10
11/23/20 17:40
124-38-9
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Benzene
ND ug/L 1.0
0.15
1
11/17/20 03:00
71-43-2
1,4-Dichlorobenzene
ND ug/L 1.0
0.26
1
11/17/20 03:00
106-46-7
1,1-Dichloroethane
ND ug/L 1.0
0.27
1
11/17/20 03:00
75-34-3
1,2-Dichloroethane
ND ug/L 1.0
0.34
1
11/17/20 03:00
107-06-2
Methylene Chloride
ND ug/L 5.0
3.7
1
11/17/20 03:00
75-09-2
Tetrachloroethene
ND ug/L 1.0
0.16
1
11/17/20 03:00
127-18-4
Trichloroethene
ND ug/L 1.0
0.22
1
11/17/20 03:00
79-01-6
Vinyl chloride
ND ug/L 1.0
0.24
1
11/17/20 03:00
75-01-4
Surrogates
4-Bromofluorobenzene (S)
99 % 70-130
1
11/17/20 03:00
460-00-4
1,2-Dichloroethane-d4 (S)
106 % 70-130
1
11/17/20 03:00
17060-07-0
Toluene-d8 (S)
101 % 70-130
1
11/17/20 03:00
2037-26-5
Date: 01/26/2021 09:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 37

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
Sample: 1203-MW-35 Lab ID: 92506094006 Collected: 11/11/20 12:35 Received: 11/12/20 09:51 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
EPA RSK-175
Carbon dioxide
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Date: 01/26/2021 09:01 AM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
ND
ug/L
10.0
3.4
1
11/16/2016:27
74-82-8
Analytical Method: RSK-175
Pace Analytical Gulf Coast
19400
ug/L
9000
1270
10
11/23/2017:47
124-38-9
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
6.2
1
11/17/20 04:13
67-64-1
ND
ug/L
10.0
0.90
1
11/17/20 04:13
107-13-1
ND
ug/L
1.0
0.15
1
11/17/20 04:13
71-43-2
ND
ug/L
1.0
0.34
1
11/17/20 04:13
74-97-5
ND
ug/L
1.0
0.26
1
11/17/20 04:13
75-27-4
ND
ug/L
1.0
0.62
1
11/17/20 04:13
75-25-2
ND
ug/L
2.0
0.62
1
11/17/20 04:13
74-83-9
ND
ug/L
5.0
3.3
1
11/17/20 04:13
78-93-3
ND
ug/L
2.0
0.40
1
11/17/20 04:13
75-15-0
ND
ug/L
1.0
0.22
1
11/17/20 04:13
56-23-5
ND
ug/L
1.0
0.23
1
11/17/20 04:13
108-90-7
ND
ug/L
1.0
0.49
1
11/17/20 04:13
75-00-3
ND
ug/L
5.0
2.3
1
11/17/20 04:13
67-66-3
ND
ug/L
1.0
0.39
1
11/17/20 04:13
74-87-3
ND
ug/L
5.0
0.26
1
11/17/20 04:13
96-12-8
ND
ug/L
1.0
0.41
1
11/17/20 04:13
124-48-1
ND
ug/L
1.0
0.26
1
11/17/20 04:13
106-93-4
ND
ug/L
1.0
0.46
1
11/17/20 04:13
74-95-3
ND
ug/L
1.0
0.29
1
11/17/20 04:13
95-50-1
ND
ug/L
1.0
0.26
1
11/17/20 04:13
106-46-7
ND
ug/L
1.0
0.54
1
11/17/20 04:13
110-57-6
ND
ug/L
1.0
0.27
1
11/17/20 04:13
75-34-3
ND
ug/L
1.0
0.34
1
11/17/20 04:13
107-06-2
ND
ug/L
1.0
0.24
1
11/17/20 04:13
75-35-4
ND
ug/L
1.0
0.29
1
11/17/20 04:13
156-59-2
ND
ug/L
1.0
0.25
1
11/17/20 04:13
156-60-5
ND
ug/L
1.0
0.19
1
11/17/20 04:13
78-87-5
ND
ug/L
1.0
0.30
1
11/17/20 04:13
10061-01-5
ND
ug/L
1.0
0.31
1
11/17/20 04:13
10061-02-6
ND
ug/L
1.0
0.26
1
11/17/20 04:13
100-41-4
ND
ug/L
5.0
0.57
1
11/17/20 04:13
591-78-6
ND
ug/L
20.0
12.5
1
11/17/20 04:13
74-88-4
ND
ug/L
5.0
3.7
1
11/17/20 04:13
75-09-2
ND
ug/L
5.0
4.5
1
11/17/20 04:13
108-10-1
ND
ug/L
1.0
0.27
1
11/17/20 04:13
100-42-5
ND
ug/L
1.0
0.34
1
11/17/20 04:13
630-20-6
ND
ug/L
1.0
0.22
1
11/17/20 04:13
79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 37

leAnalyiical
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
Sample: 1203-MW-35
Parameters
Lab ID:
Results
92506094006
Units
Collected:
Report
Limit
11/11/20 12:35
MDL DF
Received: 11/12/20 09:51 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
Tetrachloroethene
ND
ug/L
1.0
0.16
1
11/17/20 04:13
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
11/17/20 04:13
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.18
1
11/17/20 04:13
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.24
1
11/17/20 04:13
79-00-5
Trichloroethene
ND
ug/L
1.0
0.22
1
11/17/20 04:13
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.31
1
11/17/20 04:13
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.35
1
11/17/20 04:13
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.4
1
11/17/20 04:13
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.24
1
11/17/20 04:13
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.63
1
11/17/20 04:13
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
101
%
70-130
1
11/17/20 04:13
460-00-4
1,2-Dichloroethane-d4 (S)
109
%
70-130
1
11/17/20 04:13
17060-07-0
Toluene-d8 (S)
103
%
70-130
1
11/17/20 04:13
2037-26-5
Date: 01/26/2021 09:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 14 of 37

leAnalyiical
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ANALYTICAL RESULTS
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
Sample: 1203-MW-38
Lab ID: 92506094007 Collected:
11/11/20 10:02
Received: 11/12/20 09:51 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
8081 OC Pesticides RVE
Analytical Method: EPA 8081 B Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
alpha-BHC
ND ug/L 0.050
0.019
1
11/20/20 17:42
11/23/20 12:44
319-84-6 H2
beta-BHC
ND ug/L 0.050
0.014
1
11/20/20 17:42
11/23/20 12:44
319-85-7 H2
Surrogates
Tetrachloro-m-xylene (S)
87 % 10-184
1
11/20/20 17:42
11/23/20 12:44
877-09-8
Decachlorobiphenyl (S)
86 % 10-154
1
11/20/20 17:42
11/23/20 12:44
2051-24-3
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
12000 ug/L 10.0
3.4
1
11/17/2014:20
74-82-8
EPA RSK-175
Analytical Method: RSK-175
Pace Analytical Gulf Coast
Carbon dioxide
154000 ug/L 18000
2540
20
11/23/20 18:03
124-38-9
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND ug/L 5.0
3.0
1
01/23/2102:05
01/25/2104:19
7440-36-0
Arsenic
4.8J ug/L 10.0
4.7
1
01/23/2102:05
01/25/2104:19
7440-38-2
Barium
95.4 ug/L 5.0
3.5
1
01/23/2102:05
01/25/2104:19
7440-39-3
Beryllium
ND ug/L 1.0
0.70
1
01/23/2102:05
01/25/2104:19
7440-41-7
Cadmium
0.43J ug/L 1.0
0.40
1
01/23/2102:05
01/25/2104:19
7440-43-9
Chromium
ND ug/L 5.0
3.7
1
01/23/2102:05
01/25/2104:19
7440-47-3
Cobalt
7.5 ug/L 5.0
3.6
1
01/23/2102:05
01/25/2104:19
7440-48-4
Copper
ND ug/L 5.0
4.3
1
01/23/2102:05
01/25/2104:19
7440-50-8
Lead
ND ug/L 5.0
4.5
1
01/23/2102:05
01/25/2104:19
7439-92-1
Nickel
ND ug/L 5.0
3.5
1
01/23/2102:05
01/25/2104:19
7440-02-0
Selenium
ND ug/L 10.0
4.7
1
01/23/2102:05
01/25/2104:19
7782-49-2
Silver
ND ug/L 5.0
2.5
1
01/23/2102:05
01/25/2104:19
7440-22-4
Vanadium
ND ug/L 5.0
3.9
1
01/23/2102:05
01/25/2104:19
7440-62-2
Zinc
ND ug/L 10.0
9.5
1
01/23/2102:05
01/25/2104:19
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020B Preparation Method:
EPA 3010A
Pace Analytical Services -Asheville
Thallium
ND ug/L 0.10
0.050
1
11/17/20 02:15
11/17/20 17:55
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND ug/L 25.0
6.2
1
11/17/20 04:31
67-64-1 M1
Acrylonitrile
ND ug/L 10.0
0.90
1
11/17/20 04:31
107-13-1
Benzene
4.7 ug/L 1.0
0.15
1
11/17/20 04:31
71-43-2
Bromochloromethane
ND ug/L 1.0
0.34
1
11/17/20 04:31
74-97-5
Bromodichloromethane
ND ug/L 1.0
0.26
1
11/17/20 04:31
75-27-4
Bromoform
ND ug/L 1.0
0.62
1
11/17/20 04:31
75-25-2
Bromomethane
ND ug/L 2.0
0.62
1
11/17/20 04:31
74-83-9
Date: 01/26/2021 09:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 15 of 37

leAnalyiical
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9800 Kincey Ave. Suite 100
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[phone]
ANALYTICAL RESULTS
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
Sample: 1203-MW-38 Lab ID: 92506094007 Collected: 11/11/20 10:02 Received: 11/12/20 09:51 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Date: 01/26/2021 09:01 AM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
5.0
3.3
1
11/17/20 04:31
78-93-3
ND
ug/L
2.0
0.40
1
11/17/20 04:31
75-15-0
ND
ug/L
1.0
0.22
1
11/17/20 04:31
56-23-5
0.67J
ug/L
1.0
0.23
1
11/17/20 04:31
108-90-7
ND
ug/L
1.0
0.49
1
11/17/20 04:31
75-00-3
ND
ug/L
5.0
2.3
1
11/17/20 04:31
67-66-3
ND
ug/L
1.0
0.39
1
11/17/20 04:31
74-87-3
ND
ug/L
5.0
0.26
1
11/17/20 04:31
96-12-8
ND
ug/L
1.0
0.41
1
11/17/20 04:31
124-48-1
ND
ug/L
1.0
0.26
1
11/17/20 04:31
106-93-4
ND
ug/L
1.0
0.46
1
11/17/20 04:31
74-95-3
0.38J
ug/L
1.0
0.29
1
11/17/20 04:31
95-50-1
ND
ug/L
1.0
0.22
1
11/17/20 04:31
541-73-1
14.0
ug/L
1.0
0.26
1
11/17/20 04:31
106-46-7
ND
ug/L
1.0
0.54
1
11/17/20 04:31
110-57-6
ND
ug/L
1.0
0.23
1
11/17/20 04:31
75-71-8
4.1
ug/L
1.0
0.27
1
11/17/20 04:31
75-34-3
0.52J
ug/L
1.0
0.34
1
11/17/20 04:31
107-06-2
ND
ug/L
1.0
0.24
1
11/17/20 04:31
75-35-4
8.1
ug/L
1.0
0.29
1
11/17/20 04:31
156-59-2
ND
ug/L
1.0
0.25
1
11/17/20 04:31
156-60-5
ND
ug/L
1.0
0.19
1
11/17/20 04:31
78-87-5
ND
ug/L
1.0
0.16
1
11/17/20 04:31
142-28-9
ND
ug/L
1.0
0.27
1
11/17/20 04:31
594-20-7
ND
ug/L
1.0
0.21
1
11/17/20 04:31
563-58-6
ND
ug/L
1.0
0.30
1
11/17/20 04:31
10061-01-5
ND
ug/L
1.0
0.31
1
11/17/20 04:31
10061-02-6
1.4
ug/L
1.0
0.26
1
11/17/20 04:31
100-41-4
ND
ug/L
1.0
0.44
1
11/17/20 04:31
87-68-3
ND
ug/L
5.0
0.57
1
11/17/20 04:31
591-78-6
ND
ug/L
20.0
12.5
1
11/17/20 04:31
74-88-4
ND
ug/L
5.0
3.7
1
11/17/20 04:31
75-09-2
ND
ug/L
5.0
4.5
1
11/17/20 04:31
108-10-1
3.7
ug/L
1.0
0.35
1
11/17/20 04:31
91-20-3
ND
ug/L
1.0
0.27
1
11/17/20 04:31
100-42-5
ND
ug/L
1.0
0.34
1
11/17/20 04:31
630-20-6
ND
ug/L
1.0
0.22
1
11/17/20 04:31
79-34-5
ND
ug/L
1.0
0.16
1
11/17/20 04:31
127-18-4
0.64J
ug/L
1.0
0.24
1
11/17/20 04:31
108-88-3
ND
ug/L
1.0
0.22
1
11/17/20 04:31
120-82-1
ND
ug/L
1.0
0.18
1
11/17/20 04:31
71-55-6
ND
ug/L
1.0
0.24
1
11/17/20 04:31
79-00-5
ND
ug/L
1.0
0.22
1
11/17/20 04:31
79-01-6
ND
ug/L
1.0
0.31
1
11/17/20 04:31
75-69-4
ND
ug/L
1.0
0.35
1
11/17/20 04:31
96-18-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
12
Page 16 of 37

leAnalyiical
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
Sample: 1203-MW-38
Parameters
Lab ID:
Results
92506094007
Units
Collected:
Report
Limit
11/11/20 10:02
MDL DF
Received: 11/12/20 09:51 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
Vinyl acetate
ND
ug/L
2.0
1.4
1
11/17/20 04:31
108-05-4
Vinyl chloride
1.1
ug/L
1.0
0.24
1
11/17/20 04:31
75-01-4
m&p-Xylene
ND
ug/L
2.0
0.41
1
11/17/20 04:31
179601-23-1
o-Xylene
0.78J
ug/L
1.0
0.22
1
11/17/20 04:31
95-47-6
Surrogates
4-Bromofluorobenzene (S)
97
%
70-130
1
11/17/20 04:31
460-00-4
1,2-Dichloroethane-d4 (S)
111
%
70-130
1
11/17/20 04:31
17060-07-0
Toluene-d8 (S)
100
%
70-130
1
11/17/20 04:31
2037-26-5
Date: 01/26/2021 09:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 17 of 37

Pace Analytical Services, LLC
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Analyilcal ® 9800 Kincey Ave. Suite 100
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QUALITY CONTROL DATA
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
QC Batch: 580638 Analysis Method: RSK 175 Modified
QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92506094006
METHOD BLANK: 3071469
Associated Lab Samples: 92506094006
Parameter
Units
Methane
ug/L
LABORATORY CONTROL SAMPLE:
3071470
Parameter
Units
Methane
ug/L
MATRIX SPIKE SAMPLE:
3071959
Parameter
Units
Methane
ug/L
Matrix: Water
Blank Reporting
Result Limit
ND 10.0
MDL Analyzed Qualifiers
3.4 11 /16/20 15:26
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
396 386 97 70-130
92505848001 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 396 379 96 70-130
SAMPLE DUPLICATE: 3071958
92505845014 Dup
Parameter Units Result Result
Methane ug/L 118 115
Max
RPD RPD Qualifiers
3 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 01 /26/2021 09:01 AM without the written consent of Pace Analytical Services, LLC. Page 18 of 37

Pace Analytical Services, LLC
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Analyilcal ® 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
QC Batch: 580895 Analysis Method: RSK 175 Modified
QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92506094001, 92506094002, 92506094003, 92506094004, 92506094005, 92506094007
METHOD BLANK: 3072559 Matrix: Water
Associated Lab Samples: 92506094001, 92506094002, 92506094003, 92506094004, 92506094005, 92506094007
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Methane ug/L ND 10.0 3.4 11/17/2012:33
LABORATORY CONTROL SAMPLE: 3072560
Parameter Units
Methane ug/L
MATRIX SPIKE SAMPLE: 3078578
Parameter Units
Methane ug/L
Spike LCS LCS
Conc. Result % Rec
396 415 105
92506094005 Spike MS
Result Conc. Result
186 396 351
SAMPLE DUPLICATE: 3078577
92506094004 Dup
Parameter Units Result Result
Methane ug/L ND ND
% Rec
Limits Qualifiers
70-130
MS % Rec
% Rec Limits Qualifiers
42 70-130 M1
Max
RPD RPD Qualifiers
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /26/2021 09:01 AM without the written consent of Pace Analytical Services, LLC. Page 19 of 37

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
QC Batch: 698097 Analysis Method: RSK-175
QC Batch Method: RSK-175 Analysis Description: EPA RSK 175 CO2
Laboratory: Pace Analytical Gulf Coast
Associated Lab Samples: 92506094001, 92506094002, 92506094003, 92506094004, 92506094005, 92506094006, 92506094007
METHOD BLANK: 2115766 Matrix: Water
Associated Lab Samples: 92506094001, 92506094002, 92506094003, 92506094004, 92506094005, 92506094006, 92506094007
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Carbon dioxide ug/L ND 900 127 11/23/20 15:34
LABORATORY CONTROL SAMPLE & LCSD: 2115767 2115768
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers
Carbon dioxide ug/L 8700 8600 8550 99 98 38-147 1 40
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /26/2021 09:01 AM without the written consent of Pace Analytical Services, LLC.
Page 20 of 37

Pace Analytical Services, LLC
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Analyilcal ® 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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QUALITY CONTROL DATA
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
QC Batch: 580735 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92506094001
METHOD BLANK: 3071816
Associated Lab Samples: 92506094001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Antimony
ug/L
ND
5.0
3.0
11/20/2013:16
Arsenic
ug/L
ND
10.0
4.7
11/20/2013:16
Barium
ug/L
ND
5.0
3.5
11/20/2013:16
Beryllium
ug/L
ND
1.0
0.70
11/20/2013:16
Cadmium
ug/L
ND
1.0
0.40
11/21/2017:24
Chromium
ug/L
ND
5.0
3.7
11/20/2013:16
Cobalt
ug/L
ND
5.0
3.6
11/20/2013:16
Copper
ug/L
ND
5.0
4.3
11/20/2013:16
Lead
ug/L
ND
5.0
4.5
11/20/2013:16
Nickel
ug/L
ND
5.0
3.5
11/20/2013:16
Selenium
ug/L
ND
10.0
4.7
11/20/2013:16
Silver
ug/L
ND
5.0
2.5
11/20/2013:16
Vanadium
ug/L
ND
5.0
3.9
11/20/2013:16
Zinc
ug/L
ND
10.0
9.5
11/20/2013:16
LABORATORY CONTROL SAMPLE:
Parameter
3071817
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
500
501
100
80-120
Arsenic
ug/L
500
501
100
80-120
Barium
ug/L
500
487
97
80-120
Beryllium
ug/L
500
489
98
80-120
Cadmium
ug/L
500
477
95
80-120
Chromium
ug/L
500
478
96
80-120
Cobalt
ug/L
500
493
99
80-120
Copper
ug/L
500
500
100
80-120
Lead
ug/L
500
492
98
80-120
Nickel
ug/L
500
493
99
80-120
Selenium
ug/L
500
487
97
80-120
Silver
ug/L
250
240
96
80-120
Vanadium
ug/L
500
479
96
80-120
Zinc
ug/L
500
462
92
80-120
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /26/2021 09:01 AM without the written consent of Pace Analytical Services, LLC.
Page 21 of 37

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
Burke Co Johns Riv Add MW/PZs-Revised Report
92506094
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3071818
3071819
MS
MSD
92506069001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
250
250
268
264
107
105
75-125
2
20
Arsenic
ug/L
ND
250
250
280
274
112
109
75-125
2
20
Barium
ug/L
1390
250
250
1630
1670
99
113
75-125
2
20
Beryllium
ug/L
ND
250
250
253
251
101
101
75-125
1
20
Cadmium
ug/L
ND
250
250
254
252
101
101
75-125
1
20
Chromium
ug/L
ND
250
250
246
244
98
97
75-125
1
20
Cobalt
ug/L
122
250
250
373
373
101
101
75-125
0
20
Copper
ug/L
ND
250
250
272
267
108
106
75-125
2
20
Lead
ug/L
9.3
250
250
255
254
98
98
75-125
0
20
Nickel
ug/L
21.7
250
250
270
268
99
99
75-125
1
20
Selenium
ug/L
ND
250
250
264
258
105
103
75-125
2
20
Silver
ug/L
ND
125
125
127
125
102
100
75-125
2
20
Vanadium
ug/L
ND
250
250
ND
ND
0
0
75-125
20 M1
Zinc
ug/L
ND
250
250
233
231
93
92
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /26/2021 09:01 AM without the written consent of Pace Analytical Services, LLC.
Page 22 of 37

Pace Analytical Services, LLC
lac,
Analyilcal ® 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
QC Batch: 594831 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92506094007
METHOD BLANK: 3138378
Associated Lab Samples: 92506094007
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Antimony
ug/L
ND
5.0
3.0
01/25/2104:06
Arsenic
ug/L
ND
10.0
4.7
01/25/2104:06
Barium
ug/L
ND
5.0
3.5
01/25/2104:06
Beryllium
ug/L
ND
1.0
0.70
01/25/2104:06
Cadmium
ug/L
ND
1.0
0.40
01/25/2104:06
Chromium
ug/L
ND
5.0
3.7
01/25/2104:06
Cobalt
ug/L
ND
5.0
3.6
01/25/2104:06
Copper
ug/L
ND
5.0
4.3
01/25/2115:58
Lead
ug/L
ND
5.0
4.5
01/25/2104:06
Nickel
ug/L
ND
5.0
3.5
01/25/2104:06
Selenium
ug/L
ND
10.0
4.7
01/25/2104:06
Silver
ug/L
ND
5.0
2.5
01/25/2104:06
Vanadium
ug/L
ND
5.0
3.9
01/25/2104:06
Zinc
ug/L
ND
10.0
9.5
01/25/2104:06
LABORATORY CONTROL SAMPLE:
Parameter
3138379
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
500
461
92
80-120
Arsenic
ug/L
500
490
98
80-120
Barium
ug/L
500
478
96
80-120
Beryllium
ug/L
500
473
95
80-120
Cadmium
ug/L
500
483
97
80-120
Chromium
ug/L
500
469
94
80-120
Cobalt
ug/L
500
478
96
80-120
Copper
ug/L
500
473
95
80-120
Lead
ug/L
500
468
94
80-120
Nickel
ug/L
500
492
98
80-120
Selenium
ug/L
500
492
98
80-120
Silver
ug/L
250
219
88
80-120
Vanadium
ug/L
500
502
100
80-120
Zinc
ug/L
500
499
100
80-120
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /26/2021 09:01 AM without the written consent of Pace Analytical Services, LLC.
Page 23 of 37

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
Burke Co Johns Riv Add MW/PZs-Revised Report
92506094
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3138380
3138381
MS
MSD
92506094007
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
500
500
461
461
92
92
75-125
0
20
Arsenic
ug/L
4.8J
500
500
490
503
97
100
75-125
3
20
Barium
ug/L
95.4
500
500
586
576
98
96
75-125
2
20
Beryllium
ug/L
ND
500
500
489
480
98
96
75-125
2
20
Cadmium
ug/L
0.43J
500
500
493
490
98
98
75-125
1
20
Chromium
ug/L
ND
500
500
475
467
95
93
75-125
2
20
Cobalt
ug/L
7.5
500
500
480
479
95
94
75-125
0
20
Copper
ug/L
ND
500
500
470
464
94
93
75-125
1
20
Lead
ug/L
ND
500
500
465
468
93
93
75-125
1
20
Nickel
ug/L
ND
500
500
483
481
96
96
75-125
0
20
Selenium
ug/L
ND
500
500
513
514
103
103
75-125
0
20
Silver
ug/L
ND
250
250
225
222
90
89
75-125
1
20
Vanadium
ug/L
ND
500
500
507
500
101
100
75-125
1
20
Zinc
ug/L
ND
500
500
498
496
99
99
75-125
0
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /26/2021 09:01 AM without the written consent of Pace Analytical Services, LLC.
Page 24 of 37

Pace Analytical Services, LLC
lac,
Analyilcal ® 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
QC Batch: 580736 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92506094001, 92506094007
METHOD BLANK: 3071820 Matrix: Water
Associated Lab Samples: 92506094001, 92506094007
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Thallium ug/L ND 0.10 0.050 11/17/2015:02
LABORATORY CONTROL SAMPLE: 3071821
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Thallium ug/L 10 10.6 106 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3071822 3071823
MS MSD
92506069002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Thallium ug/L ND 10 10 10.7 10.9 107 109 75-125 2 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /26/2021 09:01 AM without the written consent of Pace Analytical Services, LLC.
Page 25 of 37

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
QC Batch: 580628 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92506094001, 92506094002, 92506094003, 92506094004, 92506094005, 92506094006, 92506094007
METHOD BLANK: 3071409 Matrix: Water
Associated Lab Samples: 92506094001, 92506094002, 92506094003, 92506094004, 92506094005, 92506094006, 92506094007
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.34
11/17/20 00:16
1,1,1-Trichloroethane
ug/L
ND
1.0
0.18
11/17/20 00:16
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
11/17/20 00:16
1,1,2-Trichloroethane
ug/L
ND
1.0
0.24
11/17/20 00:16
1,1-Dichloroethane
ug/L
ND
1.0
0.27
11/17/20 00:16
1,1-Dichloroethene
ug/L
ND
1.0
0.24
11/17/20 00:16
1,1-Dichloropropene
ug/L
ND
1.0
0.21
11/17/20 00:16
1,2,3-Trichloropropane
ug/L
ND
1.0
0.35
11/17/20 00:16
1,2,4-Trichlorobenzene
ug/L
ND
1.0
0.22
11/17/20 00:16
1,2-Dibromo-3-chloropropane
ug/L
ND
5.0
0.26
11/17/20 00:16
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.26
11/17/20 00:16
1,2-Dichlorobenzene
ug/L
ND
1.0
0.29
11/17/20 00:16
1,2-Dichloroethane
ug/L
ND
1.0
0.34
11/17/20 00:16
1,2-Dichloropropane
ug/L
ND
1.0
0.19
11/17/20 00:16
1,3-Dichlorobenzene
ug/L
ND
1.0
0.22
11/17/20 00:16
1,3-Dichloropropane
ug/L
ND
1.0
0.16
11/17/20 00:16
1,4-Dichlorobenzene
ug/L
ND
1.0
0.26
11/17/20 00:16
2,2-Dichloropropane
ug/L
ND
1.0
0.27
11/17/20 00:16
2-Butanone (MEK)
ug/L
ND
5.0
3.3
11/17/20 00:16
2-Hexanone
ug/L
ND
5.0
0.57
11/17/20 00:16
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
4.5
11/17/20 00:16
Acetone
ug/L
ND
25.0
6.2
11/17/20 00:16
Acrylonitrile
ug/L
ND
10.0
0.90
11/17/20 00:16
Benzene
ug/L
ND
1.0
0.15
11/17/20 00:16
Bromochloromethane
ug/L
ND
1.0
0.34
11/17/20 00:16
Bromodichloromethane
ug/L
ND
1.0
0.26
11/17/20 00:16
Bromoform
ug/L
ND
1.0
0.62
11/17/20 00:16
Bromomethane
ug/L
ND
2.0
0.62
11/17/20 00:16
Carbon disulfide
ug/L
ND
2.0
0.40
11/17/20 00:16
Carbon tetrachloride
ug/L
ND
1.0
0.22
11/17/20 00:16
Chlorobenzene
ug/L
ND
1.0
0.23
11/17/20 00:16
Chloroethane
ug/L
ND
1.0
0.49
11/17/20 00:16
Chloroform
ug/L
ND
5.0
2.3
11/17/20 00:16
Chloromethane
ug/L
ND
1.0
0.39
11/17/20 00:16
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.29
11/17/20 00:16
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.30
11/17/20 00:16
Dibromochloromethane
ug/L
ND
1.0
0.41
11/17/20 00:16
Dibromomethane
ug/L
ND
1.0
0.46
11/17/20 00:16
Dichlorodifluoromethane
ug/L
ND
1.0
0.23
11/17/20 00:16
Ethylbenzene
ug/L
ND
1.0
0.26
11/17/20 00:16
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /26/2021 09:01 AM without the written consent of Pace Analytical Services, LLC. Page 26 of 37

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
METHOD BLANK: 3071409 Matrix: Water
Associated Lab Samples: 92506094001, 92506094002, 92506094003, 92506094004, 92506094005, 92506094006, 92506094007
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Hexachloro-1,3-butadiene
ug/L
ND
1.0
0.44
11/17/20 00:16
lodomethane
ug/L
ND
20.0
12.5
11/17/20 00:16 IK
m&p-Xylene
ug/L
ND
2.0
0.41
11/17/20 00:16
Methylene Chloride
ug/L
ND
5.0
3.7
11/17/20 00:16
Naphthalene
ug/L
ND
1.0
0.35
11/17/20 00:16
o-Xylene
ug/L
ND
1.0
0.22
11/17/20 00:16
Styrene
ug/L
ND
1.0
0.27
11/17/20 00:16
Tetrachloroethene
ug/L
ND
1.0
0.16
11/17/20 00:16
Toluene
ug/L
ND
1.0
0.24
11/17/20 00:16
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.25
11/17/20 00:16
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.31
11/17/20 00:16
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.54
11/17/20 00:16
Trichloroethene
ug/L
ND
1.0
0.22
11/17/20 00:16
Trichlorofluoromethane
ug/L
ND
1.0
0.31
11/17/20 00:16
Vinyl acetate
ug/L
ND
2.0
1.4
11/17/20 00:16
Vinyl chloride
ug/L
ND
1.0
0.24
11/17/20 00:16
Xylene (Total)
ug/L
ND
1.0
0.63
11/17/20 00:16
1,2-Dichloroethane-d4 (S)
%
107
70-130
11/17/20 00:16
4-Bromofluorobenzene (S)
%
99
70-130
11/17/20 00:16
Toluene-d8 (S)
%
101
70-130
11/17/20 00:16
LABORATORY CONTROL SAMPLE:
Parameter
3071410
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
49.8
100
70-130
1,1,1-Trichloroethane
ug/L
50
52.8
106
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
48.7
97
70-130
1,1,2-Trichloroethane
ug/L
50
50.3
101
70-130
1,1-Dichloroethane
ug/L
50
54.4
109
70-130
1,1-Dichloroethene
ug/L
50
59.6
119
70-132
1,1-Dichloropropene
ug/L
50
52.9
106
70-131
1,2,3-Trichloropropane
ug/L
50
50.5
101
70-130
1,2,4-Trichlorobenzene
ug/L
50
50.8
102
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
49.8
100
70-132
1,2-Dibromoethane (EDB)
ug/L
50
51.1
102
70-130
1,2-Dichlorobenzene
ug/L
50
50.3
101
70-130
1,2-Dichloroethane
ug/L
50
53.0
106
70-130
1,2-Dichloropropane
ug/L
50
51.0
102
70-130
1,3-Dichlorobenzene
ug/L
50
49.8
100
70-130
1,3-Dichloropropane
ug/L
50
50.8
102
70-130
1,4-Dichlorobenzene
ug/L
50
48.7
97
70-130
2,2-Dichloropropane
ug/L
50
55.0
110
70-130
2-Butanone (MEK)
ug/L
100
103
103
70-133
2-Hexanone
ug/L
100
101
101
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /26/2021 09:01 AM without the written consent of Pace Analytical Services, LLC. Page 27 of 37

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
LABORATORY CONTROL SAMPLE:
Parameter
3071410
Units
Spike
Conc.
4-Methyl-2-pentanone (MIBK)
ug/L
100
Acetone
ug/L
100
Acrylonitrile
ug/L
250
Benzene
ug/L
50
Bromochloromethane
ug/L
50
Bromodichloromethane
ug/L
50
Bromoform
ug/L
50
Bromomethane
ug/L
50
Carbon disulfide
ug/L
50
Carbon tetrachloride
ug/L
50
Chlorobenzene
ug/L
50
Chloroethane
ug/L
50
Chloroform
ug/L
50
Chloromethane
ug/L
50
cis-1,2-Dichloroethene
ug/L
50
cis-1,3-Dichloropropene
ug/L
50
Dibromochloromethane
ug/L
50
Dibromomethane
ug/L
50
Dichlorodifluoromethane
ug/L
50
Ethylbenzene
ug/L
50
Hexachloro-1,3-butadiene
ug/L
50
lodomethane
ug/L
100
m&p-Xylene
ug/L
100
Methylene Chloride
ug/L
50
Naphthalene
ug/L
50
o-Xylene
ug/L
50
Styrene
ug/L
50
Tetrachloroethene
ug/L
50
Toluene
ug/L
50
trans-1,2-Dichloroethene
ug/L
50
trans- 1,3-Dichloropropene
ug/L
50
trans-1,4-Dichloro-2-butene
ug/L
50
Trichloroethene
ug/L
50
Trichlorofluoromethane
ug/L
50
Vinyl acetate
ug/L
100
Vinyl chloride
ug/L
50
Xylene (Total)
ug/L
150
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
101
101
70-130
109
109
70-144
274
110
70-130
50.1
100
70-130
53.9
108
70-130
47.5
95
70-130
47.9
96
70-131
42.9
86
30-177
55.6
111
70-133
50.6
101
70-130
49.0
98
70-130
51.7
103
46-131
55.7
111
70-130
42.2
84
49-130
52.0
104
70-130
53.9
108
70-130
50.6
101
70-130
51.4
103
70-130
45.3
91
52-134
48.5
97
70-130
51.4
103
70-131
117
117
47-140IK
99.9
100
70-130
50.7
101
68-130
51.1
102
70-133
48.4
97
70-130
49.6
99
70-130
47.7
95
70-130
50.3
101
70-130
57.9
116
70-130
51.5
103
70-130
52.9
106
25-200
54.3
109
70-130
49.2
98
61-130
122
122
70-140
47.8
96
59-142
148
99
70-130
100
70-130
99
70-130
100
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 01 /26/2021 09:01 AM without the written consent of Pace Analytical Services, LLC. Page 28 of 37

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QUALITY CONTROL DATA
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3071411
MS
92506094007 Spike
Parameter Units Result Conc.
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1, 2,2-Tetrachloroethane
1,1, 2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2-Dibromo-3-
chloropropane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichloropropane
2-Butanone (MEK)
2-Hexanone
4-Methyl-2-pentanone
(MIBK)
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Hexachloro-1,3-butadiene
lodomethane
m&p-Xylene
Methylene Chloride
3071412
MSD
Spike MS MSD MS MSD % Rec
Conc. Result Result % Rec % Rec Limits
ug/L
ND
20
20
22.7
22.5
113
113
70-135
ug/L
ND
20
20
21.3
21.4
107
107
70-148
ug/L
ND
20
20
21.5
20.5
107
102
70-131
ug/L
ND
20
20
21.5
21.2
107
106
70-136
ug/L
4.1
20
20
25.4
25.0
106
104
70-147
ug/L
ND
20
20
23.9
24.0
120
120
70-158
ug/L
ND
20
20
21.4
22.5
107
112
70-149
ug/L
ND
20
20
21.0
20.3
105
101
67-137
ug/L
ND
20
20
21.8
22.3
109
111
70-139
ug/L
ND
20
20
20.6
20.5
103
102
69-136
Max
RPD RPD Qual
1 30
0 30
5 30
1 30
2 30
0 30
5 30
4 30
2 30
1 30
ug/L
ND
20
20
21.1
20.4
105
102
70-137
3
30
ug/L
0.38J
20
20
22.4
22.4
110
110
70-133
0
30
ug/L
0.52J
20
20
20.5
20.2
100
99
67-138
2
30
ug/L
ND
20
20
21.7
22.0
109
110
70-138
1
30
ug/L
ND
20
20
22.7
22.7
114
114
70-133
0
30
ug/L
ND
20
20
21.2
21.6
106
108
70-136
2
30
ug/L
14.0
20
20
38.0
37.4
120
117
70-133
2
30
ug/L
ND
20
20
21.5
24.9
108
125
52-155
15
30
ug/L
ND
40
40
41.0
41.4
102
104
61-147
1
30
ug/L
ND
40
40
42.6
42.0
106
105
67-139
1
30
ug/L
ND
40
40
41.3
41.4
103
103
67-136
0
30
ug/L
ND
40
40
87.4
87.1
219
218
55-159
0
30 M1
ug/L
ND
100
100
102
98.2
102
98
68-140
4
30
ug/L
4.7
20
20
26.3
26.0
108
106
67-150
1
30
ug/L
ND
20
20
20.9
21.1
105
106
70-146
1
30
ug/L
ND
20
20
20.6
20.4
103
102
70-138
1
30
ug/L
ND
20
20
19.1
18.5
96
92
57-138
3
30
ug/L
ND
20
20
15.3
13.8
76
69
10-200
10
30
ug/L
ND
20
20
23.8
23.6
119
118
70-152
1
30
ug/L
ND
20
20
23.4
23.1
117
116
70-147
1
30
ug/L
0.67J
20
20
24.1
23.4
117
114
70-137
3
30
ug/L
ND
20
20
22.6
21.1
113
106
51-166
7
30
ug/L
ND
20
20
18.9
20.0
94
100
70-144
6
30
ug/L
ND
20
20
15.8
14.6
79
73
24-161
8
30
ug/L
8.1
20
20
27.7
28.0
98
100
67-148
1
30
ug/L
ND
20
20
20.7
20.8
104
104
70-142
0
30
ug/L
ND
20
20
21.0
21.0
105
105
68-138
0
30
ug/L
ND
20
20
21.7
20.8
109
104
70-134
4
30
ug/L
ND
20
20
16.6
16.8
83
84
43-155
1
30
ug/L
1.4
20
20
24.5
24.1
116
114
68-143
2
30
ug/L
ND
20
20
23.1
23.2
116
116
62-151
0
30
ug/L
ND
40
40
41.6
42.4
104
106
20-161
2
30
ug/L
ND
40
40
47.1
45.8
118
115
53-157
3
30
ug/L
ND
20
20
19.7
18.8
98
94
64-148
5
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 3071411
3071412
MS
MSD
92506094007
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Naphthalene
ug/L
3.7
20
20
26.7
26.3
115
113
57-150
1
30
o-Xylene
ug/L
0.78J
20
20
24.1
23.7
117
114
68-143
2
30
Styrene
ug/L
ND
20
20
22.1
22.2
111
111
70-136
0
30
Tetrachloroethene
ug/L
ND
20
20
20.0
20.2
100
101
70-139
1
30
Toluene
ug/L
0.64J
20
20
22.7
22.4
110
109
47-157
1
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
21.1
20.9
106
105
70-149
1
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
20.2
20.1
101
100
70-138
1
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
16.0
16.2
80
81
31-145
1
30
Trichloroethene
ug/L
ND
20
20
23.1
23.0
116
115
70-149
0
30
Trichlorofluoromethane
ug/L
ND
20
20
20.5
20.1
103
100
61-154
2
30
Vinyl acetate
ug/L
ND
40
40
40.3
40.1
101
100
48-156
1
30
Vinyl chloride
ug/L
1.1
20
20
20.2
19.7
95
93
55-172
2
30
Xylene (Total)
ug/L
0.78J
60
60
71.2
69.5
117
115
66-145
2
30
1,2-Dichloroethane-d4 (S)
%
93
93
70-130
4-Bromofluorobenzene (S)
%
100
99
70-130
Toluene-d8 (S)
%
98
98
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /26/2021 09:01 AM without the written consent of Pace Analytical Services, LLC.
Page 30 of 37

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
QC Batch: 581374
Analysis Method: EPA 8081 B
QC Batch Method: EPA 3510C
Analysis Description: 8081 OC Pesticides Red Vol
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92506094001
METHOD BLANK: 3075233
Matrix: Water
Associated Lab Samples: 92506094001
Blank Reporting
Parameter
Units
Result Limit
MDL Analyzed Qualifiers
alpha-BHC
ug/L
ND 0.050
0.019 11/19/20 13:56
beta-BHC
ug/L
ND 0.050
0.014 11/19/20 13:56
Decachlorobiphenyl (S)
%
115 10-154
11/19/20 13:56
Tetrachloro-m-xylene (S)
%
94 10-184
11/19/20 13:56
LABORATORY CONTROL SAMPLE: 3075234
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
alpha-BHC
ug/L
0.25 0.29
116 37-139
beta-BHC
ug/L
0.25 0.33
130 39-176
Decachlorobiphenyl (S)
%
119 10-154
Tetrachloro-m-xylene (S)
%
81 10-184
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3075235 3075236
MS MSD
92505868003
Spike Spike MS
MSD MS MSD % Rec
Max
Parameter Units
Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD
RPD Qual
alpha-BHC ug/L
ND
0.5 0.5 0.50
0.47 101 93 25-151 8
30
beta-BHC ug/L
ND
0.5 0.5 0.62
0.58 125 116 30-188 7
30
Decachlorobiphenyl (S) %
71 102 10-154
Tetrachloro-m-xylene (S) %
154 68 10-184
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /26/2021 09:01 AM without the written consent of Pace Analytical Services, LLC.
Page 31 of 37

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
QC Batch: 582019
Analysis Method: EPA 8081 B
QC Batch Method: EPA 3510C
Analysis Description: 8081 OC Pesticides Red Vol
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92506094007
METHOD BLANK: 3078447
Matrix: Water
Associated Lab Samples: 92506094007
Blank Reporting
Parameter
Units
Result Limit
MDL Analyzed Qualifiers
alpha-BHC
ug/L
ND 0.050
0.019 11/23/20 14:50
beta-BHC
ug/L
ND 0.050
0.014 11/23/20 14:50
Decachlorobiphenyl (S)
%
105 10-154
11/23/20 14:50
Tetrachloro-m-xylene (S)
%
97 10-184
11/23/20 14:50
LABORATORY CONTROL SAMPLE: 3078448
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
alpha-BHC
ug/L
0.25 0.25
100 37-139
beta-BHC
ug/L
0.25 0.32
126 39-176
Decachlorobiphenyl (S)
%
108 10-154
Tetrachloro-m-xylene (S)
%
96 10-184
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3078449 3078450
MS MSD
92507361004
Spike Spike MS
MSD MS MSD % Rec
Max
Parameter Units
Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD
RPD Qual
alpha-BHC ug/L
ND
0.25 0.25 0.21
0.24 84 95 25-151 12
30
beta-BHC ug/L
ND
0.25 0.25 0.29
0.32 116 127 30-188 9
30
Decachlorobiphenyl (S) %
73 82 10-154
Tetrachloro-m-xylene (S) %
77 84 10-184
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /26/2021 09:01 AM without the written consent of Pace Analytical Services, LLC.
Page 32 of 37

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[phone]
QUALIFIERS
Project: Burke Co Johns Riv Add MW/PZs-Revised Report
Pace Project No.: 92506094
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
ANALYTE QUALIFIERS
H2 Extraction or preparation conducted outside EPA method holding time.
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
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[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Burke Co Johns Riv Add
92506094
MW/PZs-Revised Report
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92506094001
1203-MW-36
EPA 3510C
581374
EPA 8081 B
581591
92506094007
1203-MW-38
EPA 3510C
582019
EPA 8081 B
582219
92506094001
1203-MW-36
RSK 175 Modified
580895
92506094002
1203-MW-15S
RSK 175 Modified
580895
92506094003
1203-PZ-12
RSK 175 Modified
580895
92506094004
1203-PZ-31
RSK 175 Modified
580895
92506094005
1203-PZ30S
RSK 175 Modified
580895
92506094006
1203-MW-35
RSK 175 Modified
580638
92506094007
1203-MW-38
RSK 175 Modified
580895
92506094001
1203-MW-36
RSK-175
698097
92506094002
1203-MW-15S
RSK-175
698097
92506094003
1203-PZ-12
RSK-175
698097
92506094004
1203-PZ-31
RSK-175
698097
92506094005
1203-PZ30S
RSK-175
698097
92506094006
1203-MW-35
RSK-175
698097
92506094007
1203-MW-38
RSK-175
698097
92506094001
1203-MW-36
EPA 3010A
580735
EPA 6010D
580747
92506094007
1203-MW-38
EPA 3010A
594831
EPA 6010D
594847
92506094001
1203-MW-36
EPA 3010A
580736
EPA 6020B
580755
92506094007
1203-MW-38
EPA 3010A
580736
EPA 6020B
580755
92506094001
1203-MW-36
EPA 8260D
580628
92506094002
1203-MW-15S
EPA 8260D
580628
92506094003
1203-PZ-12
EPA 8260D
580628
92506094004
1203-PZ-31
EPA 8260D
580628
92506094005
1203-PZ30S
EPA 8260D
580628
92506094006
1203-MW-35
EPA 8260D
580628
92506094007
1203-MW-38
EPA 8260D
580628
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /26/2021 09:01 AM without the written consent of Pace Analytical Services, LLC. Page 34 of 37

Document Name:
Document Revised: October 28, 2020
Sample Condition Upon Receipt(SCUR)
Page 1 of 2
,7ceAnaVica!
Y `
Dacu ment Na.:
Issuing Authority:
O
M
F-CAR-CS-033-Rev.07
Pate Carolinas quality Office
,
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood
❑ Huntersville [Z Raleigh[]
m
d
Mechanicsville[] Atlanta❑ Kernersville❑
ConditionSample Client Name:
Project#
WO## •• 92506094
,. Receipt
Lilt, be. I hF_
//
14 f J0cdaTe-f
I
Courier: ❑Fed Ex ❑UPS ❑LISPS ❑Client
❑ Commercial Pace
❑Other:
+ I
I
92506094
Custody Seal Present? ❑Yes /JNo Seals Intact? ❑Yes 14No �
pate/initials Person Examining Contents:
Packing Material: ❑Bubble wrap ❑Bubble Bags ❑None KJ Other Biological Tissue Frozen? 1 (/13/ Z-O
Thermo met r. fflWet ❑Rive ❑None ❑Yes ❑No ON/A
�j IR Gun ID: 92TO61 Type of Ice:
Correction Factor:
Cooler Temp: '� Add/Subtract (°C) 0.0 Temp should be above freezing to 6`C
❑Samples out of temp criteria. Samples on ice, cooling process
Cooler Temp Corrected ('Cl: L�' �' has begun
USDA Regulated Soil (� N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source {internationally,
❑Yes []NO including Hawaii and Puerto Kitoj f L,._ires urvo
Comments/Discrepancy:
Chain of Custody Present? plyes ONO ❑N/A
1.
Samples Arrived within Hold Time? ClYrs []NO [—]N/A
2.
Short Hold Time Analysis (02 hr.)? ❑Yes UrN. ❑N/A
3.
Rush Turn Around Time Requested? ❑Yes No QN/a
4,
Sufficient Volume? Yes ❑No ❑N/A
5.
Correct Containers Used? Byes ❑No ❑N/A
-Pace Containers Used? es ❑No ❑N/A
Containers Intact? es ❑No ❑N/A
Dissolved analysis: Samples Field Filtered? []Yes VrNo ❑N/A
Sample Labels Match COC? Feres []No []N/A
-Includes Date/Time/ID/Analysis Matrix: t�
6.
7,
8.
9.
Headspace in VOA Vials (>S-6mml? ❑Yes No
141/i'
Trip Blank Present? ❑yes ❑No/A
Trip Blank Custody Seals Present? []yes[:]No/A
11.
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Lot ID of split containers:
Date/Time:
Field Data Required? ❑Yes (]NO
Project Manager SCURF Review: Date: 4 �tD 2b
Project Manager SRF Review: Date: ��

�AceMaVical`
i
Document Name:
Sample Condition Upon Receil
Document No.:
F-CAR-CS-033-Rev.07
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
*"Bottom half of box is to list number of bottles
Document Revised: October 28, 2020
Page 2 of 2
Issuing Authority:
Pace Carolinas Quality Office
Project WO# : 92506094
PM: NMG Due Date: 11/30/20
CLIENT: 92-Joyce Eng
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot H
Note Whenever there is a discrepancy affecting North Carolina compliance samples, a copy oT tnu Corm win oe sent io ine Norin t-arouna ucnrvn t-eroncauun ufTice h.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
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<ceAnaiyrrcal CHAIN -OF -CUSTODY /Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. Alf relevant fields must be completed accurately.
Section A Section B Section C
Required Client Information: Required Project Information: Invoice Information: Page : 1 Of i
Company: La$ella Associates Report To: Van Burbach Attention: Lecia Jones
Address: 2211 West Meadowview Rd copy To: Miguel Vazquez Company Name. LaBella Associates
Greensboro, NC 27407 Address: 1604 Ownby Lane, Richmond, VA 23220 Regulatory Agency
Email To: [e-mail] Purchase Order No, 2202300.00.02 Pace quote Reterence:
Phone: [phone] Far Client Project ID: Burke Co. Johns Riv. Add. MWs & PZs Pace Projacl Manager Nicole Gasforowski State I Location
Requested Due DatefrAT: 10 Day l [1) Container Order NumberPace Prolile #: North Carolina
Requested Analysis Filtered (YIN)
-.x COLLECTED Preservatives
..V.,_ J
SAMPLE ID G.
a
One Character per box. 5'+==
�Sample Ids must be unique
W
F-
1 1203-M W -36
2 1203-MW-15S
3 1203-PZ-12
4 1203PZ-31
5 1203-PZ30S
6 1203-M W -36
7 1203-MW-36
8
9
10
11
12
ADDITIONAL COMMENTS
'8260 COCs = Benzene: 1,4-0ichlorobenzene: Methylene chloride,
Tetrachloroeltlene:Trichloroelhene, 1,1-Drchloroethane:1,2-
Dichloroethans: & Vinyl chloride.
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SAMPLE CONDITIONS
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SAMPLER NAME AND SIGNATURE
PRINT Name of SAMPLER: f /- _ _ t� Q1 z
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SIGNATURE of SAMPLER: DATE Si ned: j% Jf 7�
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leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
November 23, 2020
Mr. Van Burbach
Joyce Engineering -Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Burke Co. Johns R Background
Pace Project No.: 92505711
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on November 12, 2020. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace National - Mt. Juliet
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Van Burbach, Joyce Engineering -NC
Gretta Eller, LaBella Associates, D.P.C.
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 61

lacieAnalyfica('
www,pacelabs.com
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
Pace Analytical Services National
12065 Lebanon Road, Mt. Juliet, TN 37122
Alabama Certification #: 40660
Alaska Certification 17-026
Arizona Certification #: AZ0612
Arkansas Certification #: 88-0469
California Certification #: 2932
Canada Certification #: 1461.01
Colorado Certification #: TN00003
Connecticut Certification #: PH-0197
DOD Certification: #1461.01
EPA# TN00003
Florida Certification #: E87487
Georgia DW Certification #: 923
Georgia Certification: NELAP
Idaho Certification #: TN00003
Illinois Certification #: 200008
Indiana Certification #: C-TN-01
Iowa Certification #: 364
Kansas Certification #: E-10277
Kentucky UST Certification #: 16
Kentucky Certification #: 90010
Louisiana Certification #: A130792
Louisiana DW Certification #: LA180010
Maine Certification #: TN0002
Maryland Certification #: 324
Massachusetts Certification #: M-TNO03
Michigan Certification #: 9958
Minnesota Certification #: 047-999-395
Mississippi Certification #: TN00003
Missouri Certification #: 340
Montana Certification M CERT0086
Nebraska Certification #: NE-OS-15-05
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification M 37712
CERTIFICATIONS
Nevada Certification #: TN-03-2002-34
New Hampshire Certification #: 2975
New Jersey Certification #: TNO02
New Mexico DW Certification
New York Certification #: 11742
North Carolina Aquatic Toxicity Certification #: 41
North Carolina Drinking Water Certification #: 21704
North Carolina Environmental Certificate #: 375
North Dakota Certification #: R-140
Ohio VAP Certification #: CL0069
Oklahoma Certification #: 9915
Oregon Certification #: TN200002
Pennsylvania Certification #: 68-02979
Rhode Island Certification #: LA000356
South Carolina Certification #: 84004
South Dakota Certification
Tennessee DW/Chem/Micro Certification #: 2006
Texas Certification #: T 104704245-17-14
Texas Mold Certification #: LAB0152
USDA Soil Permit #: P330-15-00234
Utah Certification #: TN00003
Vermont Dept. of Health: ID# VT-2006
Virginia Certification #: VT2006
Virginia Certification #: 460132
Washington Certification #: C847
West Virginia Certification #: 233
Wisconsin Certification #: 998093910
Wyoming UST Certification #: via A21-A 2926.01
A21-A-ISO 17025 Certification #: 1461.01
A21-A-ISO 17025 Certification #: 1461.02
AIHA-LAP/LLC EMLAP Certification #:100789
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 61

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92505711001
1203-MW21
Water
11/11/20 07:35
11/12/20 09:51
92505711002
1203-FIELD BLANK
Water
11/11/20 14:08
11/12/20 09:51
92505711003
TRIP BLANK
Water
11/10/20 09:24
11/12/20 09:51
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 61

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
92505711001
1203-MW21
EPA 8151
MTJ
5
PAN
EPA 8081 B
SEM
21
PASI-C
EPA 8082A
SEM
8
PASI-C
EPA 601 OD
BG2
17
PASI-A
EPA 6020E
BG2
1
PASI-A
EPA 7470A
SOO
1
PASI-A
EPA 8270E
PKS
112
PASI-C
EPA 8260D
CL
67
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
SM 2320B-2011
ECH
1
PASI-A
SM 2540C-2011
RED
1
PASI-A
SM 4500-S2D-2011
NAL
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
SM 4500-CN-E-2011
CJL
1
PASI-A
92505711002
1203-FIELD BLANK
EPA 8151
MTJ
5
PAN
EPA 8081 B
SEM
21
PASI-C
EPA 8082A
SEM
8
PASI-C
EPA 601 OD
BG2
17
PASI-A
EPA 6020E
BG2
1
PASI-A
EPA 7470A
SOO
1
PASI-A
EPA 8270E
PKS
112
PASI-C
EPA 8260D
CL
67
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
SM 2320B-2011
ECH
1
PASI-A
SM 2540C-2011
RED
1
PASI-A
SM 4500-S2D-2011
NAL
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
SM 4500-CN-E-2011
CJL
1
PASI-A
92505711003
TRIP BLANK
EPA 8260D
CL
67
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
PAN = Pace National - Mt. Juliet
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 61

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
Lab Sample ID
Method
Client Sample ID
Parameters
92505711001
1203-MW21
EPA 6010D
Barium
EPA 6010D
Chromium
EPA 6010D
Cobalt
EPA 6010D
Copper
EPA 6010D
Iron
EPA 6010D
Manganese
EPA 6010D
Vanadium
EPA 6010D
Zinc
SM 4500-CI-E-2011
Chloride
SUMMARY OF DETECTION
Result
Units
Report Limit
Analyzed Qualifiers
47.4
ug/L
5.0
11/15/2018:53
7.0
ug/L
5.0
11/15/2018:53
8.7
ug/L
5.0
11/15/2018:53
19.7
ug/L
5.0
11/15/2018:53
15400
ug/L
50.0
11/15/2018:53 M1
348
ug/L
5.0
11/15/2018:53
63.0
ug/L
5.0
11/15/2018:53
17.2
ug/L
10.0
11/15/2018:53
720J
ug/L
1000
11/20/20 00:23
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
Sample: 1203-MW21
Lab ID:
92505711001
Collected:
11/11/20 07:35
Received: 11/12/20 09:51 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
Chlorinated Herb. (GC) 8151
Analytical
Method: EPA8151
Preparation
Method: 8151A
Pace National
- Mt. Juliet
2,4-D
ND
ug/L
2.00
0.547
1
11/17/20 08:23
11/18/20 22:58
94-75-7
2,4,5-T
ND
ug/L
2.00
0.258
1
11/17/20 08:23
11/18/20 22:58
93-76-5
2,4,5-TP (Silvex)
ND
ug/L
2.00
0.335
1
11/17/20 08:23
11/18/20 22:58
93-72-1
Dinoseb
ND
ug/L
2.00
0.250
1
11/17/20 08:23
11/18/20 22:58
88-85-7
Surrogates
2,4-DCAA (S)
65.2
%
14.0-158
1
11/17/20 08:23
11/18/20 22:58
19719-28-9
8081 OC Pesticides RVE
Analytical
Method: EPA 8081
B Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
Aldrin
ND
ug/L
0.050
0.022
1
11/16/20 17:36
11/18/20 09:21
309-00-2
alpha-BHC
ND
ug/L
0.050
0.019
1
11/16/20 17:36
11/18/20 09:21
319-84-6
beta-BHC
ND
ug/L
0.050
0.014
1
11/16/20 17:36
11/18/20 09:21
319-85-7
delta-BHC
ND
ug/L
0.050
0.020
1
11/16/20 17:36
11/18/20 09:21
319-86-8
gamma-BHC (Lindane)
ND
ug/L
0.050
0.012
1
11/16/20 17:36
11/18/20 09:21
58-89-9
Chlordane (Technical)
ND
ug/L
0.20
0.14
1
11/16/20 17:36
11/18/20 09:21
57-74-9
4,4'-DDD
ND
ug/L
0.050
0.0069
1
11/16/20 17:36
11/18/20 09:21
72-54-8
4,4'-DDE
ND
ug/L
0.050
0.0064
1
11/16/20 17:36
11/18/20 09:21
72-55-9 L1
4,4'-DDT
ND
ug/L
0.050
0.018
1
11/16/20 17:36
11/18/20 09:21
50-29-3 L1
Dieldrin
ND
ug/L
0.050
0.0073
1
11/16/20 17:36
11/18/20 09:21
60-57-1
Endosulfan I
ND
ug/L
0.050
0.0094
1
11/16/20 17:36
11/18/20 09:21
959-98-8 L1
Endosulfan 11
ND
ug/L
0.050
0.0065
1
11/16/20 17:36
11/18/20 09:21
33213-65-9
Endosulfan sulfate
ND
ug/L
0.050
0.0091
1
11/16/20 17:36
11/18/20 09:21
1031-07-8
Endrin
ND
ug/L
0.050
0.0089
1
11/16/20 17:36
11/18/20 09:21
72-20-8
Endrin aldehyde
ND
ug/L
0.050
0.013
1
11/16/20 17:36
11/18/20 09:21
7421-93-4
Heptachlor
ND
ug/L
0.050
0.016
1
11/16/20 17:36
11/18/20 09:21
76-44-8
Heptachlor epoxide
ND
ug/L
0.050
0.0097
1
11/16/20 17:36
11/18/20 09:21
1024-57-3
Methoxychlor
ND
ug/L
0.15
0.033
1
11/16/20 17:36
11/18/20 09:21
72-43-5
Toxaphene
ND
ug/L
0.20
0.19
1
11/16/20 17:36
11/18/20 09:21
8001-35-2
Surrogates
Tetrachloro-m-xylene (S)
51
%
10-184
1
11/16/20 17:36
11/18/20 09:21
877-09-8
Decachlorobiphenyl (S)
93
%
10-154
1
11/16/20 17:36
11/18/20 09:21
2051-24-3
8082 GCS PCB RVE
Analytical
Method: EPA 8082A
Preparation Method:
EPA 3510C
Pace Analytical
Services
- Charlotte
PCB-1016 (Aroclor 1016)
ND
ug/L
0.50
0.22
1
11/16/20 17:36
11/18/20 19:21
12674-11-2
PCB-1221 (Aroclor 1221)
ND
ug/L
0.50
0.32
1
11/16/20 17:36
11/18/20 19:21
11104-28-2
PCB-1232 (Aroclor 1232)
ND
ug/L
0.50
0.21
1
11/16/20 17:36
11/18/20 19:21
11141-16-5
PCB-1242 (Aroclor 1242)
ND
ug/L
0.50
0.44
1
11/16/20 17:36
11/18/20 19:21
53469-21-9
PCB-1248 (Aroclor 1248)
ND
ug/L
0.50
0.34
1
11/16/20 17:36
11/18/20 19:21
12672-29-6
PCB-1254 (Aroclor 1254)
ND
ug/L
0.50
0.24
1
11/16/20 17:36
11/18/20 19:21
11097-69-1
PCB-1260 (Aroclor 1260)
ND
ug/L
0.50
0.30
1
11/16/20 17:36
11/18/20 19:21
11096-82-5
Surrogates
Decachlorobiphenyl (S)
81
%
10-181
1
11/16/20 17:36
11/18/20 19:21
2051-24-3
Date: 11/23/2020 04:17 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
Sample: 1203-MW21
Lab ID:
92505711001
Collected:
11/11/20
07:35
Received: 11/12/20 09:51 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
6010 MET ICP
Analytical
Method: EPA 6010D
Preparation Method: EPA 3010A
Pace Analytical
Services
-Asheville
Antimony
ND
ug/L
5.0
3.0
1
11/13/20 02:07
11/15/20 18:53
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
11/13/20 02:07
11/15/20 18:53
7440-38-2
Barium
47.4
ug/L
5.0
3.5
1
11/13/20 02:07
11/15/20 18:53
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
11/13/20 02:07
11/15/20 18:53
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
11/13/20 02:07
11/15/20 18:53
7440-43-9
Chromium
7.0
ug/L
5.0
3.7
1
11/13/20 02:07
11/15/20 18:53
7440-47-3
Cobalt
8.7
ug/L
5.0
3.6
1
11/13/20 02:07
11/15/20 18:53
7440-48-4
Copper
19.7
ug/L
5.0
4.3
1
11/13/20 02:07
11/15/20 18:53
7440-50-8
Iron
15400
ug/L
50.0
41.5
1
11/13/20 02:07
11/15/20 18:53
7439-89-6 M1
Lead
ND
ug/L
5.0
4.5
1
11/13/20 02:07
11/15/20 18:53
7439-92-1
Manganese
348
ug/L
5.0
3.4
1
11/13/20 02:07
11/15/20 18:53
7439-96-5
Nickel
ND
ug/L
5.0
3.5
1
11/13/20 02:07
11/15/20 18:53
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
11/13/20 02:07
11/15/20 18:53
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
11/13/20 02:07
11/15/20 18:53
7440-22-4
Tin
ND
ug/L
5.0
4.7
1
11/13/20 02:07
11/15/20 18:53
7440-31-5
Vanadium
63.0
ug/L
5.0
3.9
1
11/13/20 02:07
11/15/20 18:53
7440-62-2
Zinc
17.2
ug/L
10.0
9.5
1
11/13/20 02:07
11/15/20 18:53
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020E
Preparation Method: EPA 3010A
Pace Analytical
Services
-Asheville
Thallium
ND
ug/L
0.10
0.050
1
11/13/20 02:03
11/15/20 02:34
7440-28-0
7470 Mercury
Analytical
Method: EPA 7470A Preparation Method:
EPA 7470A
Pace Analytical
Services
-Asheville
Mercury
ND
ug/L
0.20
0.12
1
11/13/2013:31
11/16/2013:57
7439-97-6
8270E APP9 RV
Analytical
Method: EPA 8270E
Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
Acenaphthene
ND
ug/L
10.0
2.0
1
11/18/20 10:25
11/20/20 13:43
83-32-9
Acenaphthylene
ND
ug/L
10.0
2.0
1
11/18/20 10:25
11/20/20 13:43
208-96-8
Acetophenone
ND
ug/L
10.0
1.5
1
11/18/20 10:25
11/20/20 13:43
98-86-2
2-Acetylaminofluorene
ND
ug/L
10.0
1.9
1
11/18/20 10:25
11/20/20 13:43
53-96-3
4-Aminobiphenyl
ND
ug/L
10.0
4.2
1
11/18/20 10:25
11/20/20 13:43
92-67-1
Anthracene
ND
ug/L
10.0
2.3
1
11/18/20 10:25
11/20/20 13:43
120-12-7
Benzo(a)anthracene
ND
ug/L
10.0
2.7
1
11/18/20 10:25
11/20/20 13:43
56-55-3
Benzo(a)pyrene
ND
ug/L
10.0
2.8
1
11/18/20 10:25
11/20/20 13:43
50-32-8
Benzo(b)fluoranthene
ND
ug/L
10.0
2.6
1
11/18/20 10:25
11/20/20 13:43
205-99-2
Benzo(g,h,i)perylene
ND
ug/L
10.0
2.8
1
11/18/20 10:25
11/20/20 13:43
191-24-2
Benzo(k)fluoranthene
ND
ug/L
10.0
2.7
1
11/18/20 10:25
11/20/20 13:43
207-08-9
Benzyl alcohol
ND
ug/L
20.0
2.9
1
11/18/20 10:25
11/20/20 13:43
100-51-6
4-Bromophenylphenyl ether
ND
ug/L
10.0
1.8
1
11/18/20 10:25
11/20/20 13:43
101-55-3
Butylbenzylphthalate
ND
ug/L
10.0
3.1
1
11/18/20 10:25
11/20/20 13:43
85-68-7
4-ChIoro-3-methyl phenol
ND
ug/L
10.0
3.3
1
11/18/20 10:25
11/20/20 13:43
59-50-7
4-Chloroaniline
ND
ug/L
20.0
3.6
1
11/18/20 10:25
11/20/20 13:43
106-47-8
Chlorobenzilate
ND
ug/L
10.0
3.6
1
11/18/20 10:25
11/20/20 13:43
510-15-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
Sample: 1203-MW21
Lab ID:
92505711001
Collected:
11/11/20
07:35
Received: 11/12/20 09:51 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
8270E APP9 RV
Analytical
Method: EPA 8270E
Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
bis(2-Chloroethoxy)methane
ND
ug/L
10.0
1.8
1
11/18/20 10:25
11/20/20 13:43
111-91-1
bis(2-Chloroethyl) ether
ND
ug/L
10.0
1.9
1
11/18/20 10:25
11/20/20 13:43
111-44-4
2-Chloronaphthalene
ND
ug/L
10.0
1.7
1
11/18/20 10:25
11/20/20 13:43
91-58-7
2-Chlorophenol
ND
ug/L
10.0
1.2
1
11/18/20 10:25
11/20/20 13:43
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
10.0
2.0
1
11/18/20 10:25
11/20/20 13:43
7005-72-3
Chrysene
ND
ug/L
10.0
2.8
1
11/18/20 10:25
11/20/20 13:43
218-01-9
Diallate
ND
ug/L
10.0
2.7
1
11/18/20 10:25
11/20/20 13:43
2303-16-4
Dibenz(a,h)anthracene
ND
ug/L
10.0
3.0
1
11/18/20 10:25
11/20/20 13:43
53-70-3
Dibenzofuran
ND
ug/L
10.0
2.1
1
11/18/20 10:25
11/20/20 13:43
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
20.0
8.1
1
11/18/20 10:25
11/20/20 13:43
91-94-1
2,4-Dichlorophenol
ND
ug/L
10.0
1.4
1
11/18/20 10:25
11/20/20 13:43
120-83-2
2,6-Dichlorophenol
ND
ug/L
10.0
2.7
1
11/18/20 10:25
11/20/20 13:43
87-65-0
Diethylphthalate
ND
ug/L
10.0
2.0
1
11/18/20 10:25
11/20/20 13:43
84-66-2
Dimethoate
ND
ug/L
10.0
2.0
1
11/18/20 10:25
11/20/20 13:43
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
5.0
3.3
1
11/18/20 10:25
11/20/20 13:43
60-11-7
IL
7,12-Dimethylbenz(a)anthracene
ND
ug/L
10.0
2.8
1
11/18/20 10:25
11/20/20 13:43
57-97-6
3,3'-Dimethylbenzidine
ND
ug/L
25.0
23.5
1
11/18/20 10:25
11/20/20 13:43
119-93-7
IH,L1
2,4-Dimethylphenol
ND
ug/L
10.0
1.7
1
11/18/20 10:25
11/20/20 13:43
105-67-9
Dimethylphthalate
ND
ug/L
10.0
2.1
1
11/18/20 10:25
11/20/20 13:43
131-11-3
Di-n-butylphthalate
ND
ug/L
10.0
2.2
1
11/18/20 10:25
11/20/20 13:43
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
20.0
3.4
1
11/18/20 10:25
11/20/20 13:43
534-52-1
1,3-Dinitrobenzene
ND
ug/L
10.0
3.7
1
11/18/20 10:25
11/20/20 13:43
99-65-0
2,4-Dinitrophenol
ND
ug/L
50.0
26.0
1
11/18/20 10:25
11/20/20 13:43
51-28-5
2,4-Dinitrotoluene
ND
ug/L
10.0
1.6
1
11/18/20 10:25
11/20/20 13:43
121-14-2
2,6-Dinitrotoluene
ND
ug/L
10.0
1.7
1
11/18/20 10:25
11/20/20 13:43
606-20-2
Di-n-octylphthalate
ND
ug/L
10.0
3.9
1
11/18/20 10:25
11/20/20 13:43
117-84-0
Diphenylamine
ND
ug/L
10.0
3.0
1
11/18/20 10:25
11/20/20 13:43
122-39-4
Disulfoton
ND
ug/L
10.0
6.0
1
11/18/20 10:25
11/20/20 13:43
298-04-4
v2
bis(2- Ethyl hexyl)phthalate
ND
ug/L
6.0
3.7
1
11/18/20 10:25
11/20/20 13:43
117-81-7
Ethyl methanesulfonate
ND
ug/L
20.0
2.8
1
11/18/20 10:25
11/20/20 13:43
62-50-0
Famphur
ND
ug/L
10.0
5.7
1
11/18/20 10:25
11/20/20 13:43
52-85-7
IH
Fluoranthene
ND
ug/L
10.0
2.2
1
11/18/20 10:25
11/20/20 13:43
206-44-0
Fluorene
ND
ug/L
10.0
2.1
1
11/18/20 10:25
11/20/20 13:43
86-73-7
Hexachloro-1,3-butadiene
ND
ug/L
10.0
1.8
1
11/18/20 10:25
11/20/20 13:43
87-68-3
Hexachlorobenzene
ND
ug/L
10.0
2.2
1
11/18/20 10:25
11/20/20 13:43
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
10.0
1.6
1
11/18/20 10:25
11/20/20 13:43
77-47-4
Hexachloroethane
ND
ug/L
10.0
1.4
1
11/18/20 10:25
11/20/20 13:43
67-72-1
Hexachloropropene
ND
ug/L
10.0
5.5
1
11/18/20 10:25
11/20/20 13:43
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
10.0
2.9
1
11/18/20 10:25
11/20/20 13:43
193-39-5
Isodrin
ND
ug/L
10.0
3.0
1
11/18/20 10:25
11/20/20 13:43
465-73-6
Isophorone
ND
ug/L
10.0
1.7
1
11/18/20 10:25
11/20/20 13:43
78-59-1
Isosafrole
ND
ug/L
10.0
3.6
1
11/18/20 10:25
11/20/20 13:43
120-58-1
Kepone
ND
ug/L
10.0
8.2
1
11/18/20 10:25
11/20/20 13:43
143-50-0
IL
Methapyrilene
ND
ug/L
50.0
27.2
1
11/18/20 10:25
11/20/20 13:43
91-80-5
IH,v2
3-Methylcholanthrene
ND
ug/L
10.0
5.3
1
11/18/20 10:25
11/20/20 13:43
56-49-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
Sample: 1203-MW21 Lab ID: 92505711001 Collected: 11/11/20 07:35 Received: 11/12/20 09:51 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Methyl methanesulfonate
ND
ug/L
5.0
3.0
1
11/18/20 10:25
11/20/20 13:43
66-27-3
2-Methylnaphthalene
ND
ug/L
10.0
1.9
1
11/18/20 10:25
11/20/20 13:43
91-57-6
Methyl parathion
ND
ug/L
10.0
2.0
1
11/18/20 10:25
11/20/20 13:43
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
10.0
1.9
1
11/18/20 10:25
11/20/20 13:43
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
10.0
1.2
1
11/18/20 10:25
11/20/20 13:43
15831-10-4
1-Naphthalenamine
ND
ug/L
5.0
4.6
1
11/18/20 10:25
11/20/20 13:43
134-32-7
2-Naphthalenamine
ND
ug/L
10.0
6.1
1
11/18/20 10:25
11/20/20 13:43
91-59-8
1,4-Naphthoquinone
ND
ug/L
5.0
2.4
1
11/18/20 10:25
11/20/20 13:43
130-15-4
2-Nitroaniline
ND
ug/L
20.0
3.0
1
11/18/20 10:25
11/20/20 13:43
88-74-4
3-Nitroaniline
ND
ug/L
20.0
3.8
1
11/18/20 10:25
11/20/20 13:43
99-09-2
4-Nitroaniline
ND
ug/L
20.0
5.1
1
11/18/20 10:25
11/20/20 13:43
100-01-6
Nitrobenzene
ND
ug/L
10.0
1.9
1
11/18/20 10:25
11/20/20 13:43
98-95-3
2-Nitrophenol
ND
ug/L
10.0
1.4
1
11/18/20 10:25
11/20/20 13:43
88-75-5
4-Nitrophenol
ND
ug/L
50.0
6.6
1
11/18/20 10:25
11/20/20 13:43
100-02-7
5-Nitro-o-toluidine
ND
ug/L
10.0
2.4
1
11/18/20 10:25
11/20/20 13:43
99-55-8
N-Nitrosodiethylamine
ND
ug/L
10.0
2.0
1
11/18/20 10:25
11/20/20 13:43
55-18-5
N-Nitrosodimethylamine
ND
ug/L
10.0
1.9
1
11/18/20 10:25
11/20/20 13:43
62-75-9
N-Nitroso-di-n-butylamine
ND
ug/L
10.0
6.2
1
11/18/20 10:25
11/20/20 13:43
924-16-3
N-Nitroso-di-n-propylamine
ND
ug/L
10.0
1.3
1
11/18/20 10:25
11/20/20 13:43
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
10.0
3.0
1
11/18/20 10:25
11/20/20 13:43
86-30-6
N-Nitrosomethylethylamine
ND
ug/L
10.0
3.3
1
11/18/20 10:25
11/20/20 13:43
10595-95-6
N-Nitrosopiperidine
ND
ug/L
10.0
2.6
1
11/18/20 10:25
11/20/20 13:43
100-75-4
N-Nitrosopyrrolidine
ND
ug/L
10.0
2.1
1
11/18/20 10:25
11/20/20 13:43
930-55-2
O,O,O-Triethylphosphorothioate
ND
ug/L
10.0
3.5
1
11/18/20 10:25
11/20/20 13:43
126-68-1
2,2'-Oxybis(1-chloropropane)
ND
ug/L
10.0
1.2
1
11/18/20 10:25
11/20/20 13:43
108-60-1
Parathion (Ethyl parathion)
ND
ug/L
10.0
2.0
1
11/18/20 10:25
11/20/20 13:43
56-38-2
Pentachlorobenzene
ND
ug/L
10.0
4.4
1
11/18/20 10:25
11/20/20 13:43
608-93-5
Pentachloronitrobenzene
ND
ug/L
10.0
2.4
1
11/18/20 10:25
11/20/20 13:43
82-68-8
Pentachlorophenol
ND
ug/L
20.0
3.8
1
11/18/20 10:25
11/20/20 13:43
87-86-5
Phenacetin
ND
ug/L
10.0
1.9
1
11/18/20 10:25
11/20/20 13:43
62-44-2
Phenanthrene
ND
ug/L
10.0
2.0
1
11/18/20 10:25
11/20/20 13:43
85-01-8
Phenol
ND
ug/L
10.0
1.4
1
11/18/20 10:25
11/20/20 13:43
108-95-2
p-Phenylenediamine
ND
ug/L
10.0
10.0
1
11/18/20 10:25
11/20/20 13:43
106-50-3
Phorate
ND
ug/L
10.0
3.8
1
11/18/20 10:25
11/20/20 13:43
298-02-2
Pronamide
ND
ug/L
10.0
2.4
1
11/18/20 10:25
11/20/20 13:43
23950-58-5
Pyrene
ND
ug/L
10.0
2.2
1
11/18/20 10:25
11/20/20 13:43
129-00-0
Safrole
ND
ug/L
10.0
3.2
1
11/18/20 10:25
11/20/20 13:43
94-59-7
1,2,4,5-Tetrachlorobenzene
ND
ug/L
10.0
4.6
1
11/18/20 10:25
11/20/20 13:43
95-94-3
2,3,4,6-Tetrachlorophenol
ND
ug/L
10.0
1.5
1
11/18/20 10:25
11/20/20 13:43
58-90-2
Thionazin
ND
ug/L
10.0
1.8
1
11/18/20 10:25
11/20/20 13:43
297-97-2
O-Toluidine
ND
ug/L
10.0
2.8
1
11/18/20 10:25
11/20/20 13:43
95-53-4
2,4,5-Trichlorophenol
ND
ug/L
10.0
1.4
1
11/18/20 10:25
11/20/20 13:43
95-95-4
2,4,6-Trichlorophenol
ND
ug/L
10.0
1.6
1
11/18/20 10:25
11/20/20 13:43
88-06-2
1,3,5-Trinitrobenzene
ND
ug/L
10.0
5.3
1
11/18/20 10:25
11/20/20 13:43
99-35-4
REPORT OF LABORATORY ANALYSIS
1g,IH,
L2
v2
v1
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
Sample: 1203-MW21 Lab ID: 92505711001 Collected: 11/11/20 07:35 Received: 11/12/20 09:51 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260D MSV Low Level Landfill
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Allyl chloride
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Chloroprene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
Date: 11/23/2020 04:17 PM
52
%
10-144
1
11/18/2010:25
11/20/2013:43
4165-60-0
21
%
10-130
1
11 /18/20 10:25
11 /20/20 13:43
321-60-8
130
%
34-163
1
11 /18/20 10:25
11 /20/20 13:43
1718-51-0
24
%
10-130
1
11/18/2010:25
11/20/2013:43
13127-88-3
37
%
10-130
1
11/18/2010:25
11/20/2013:43
367-12-4
86
%
10-144
1
11/18/2010:25
11/20/2013:43
118-79-6
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
6.2
1
11/17/20 01:11
67-64-1
ND
ug/L
50.0
30.4
1
11/17/20 01:11
75-05-8
ND
ug/L
10.0
2.7
1
11/17/20 01:11
107-02-8
ND
ug/L
10.0
0.90
1
11/17/20 01:11
107-13-1
ND
ug/L
2.0
0.28
1
11/17/20 01:11
107-05-1
ND
ug/L
1.0
0.15
1
11/17/20 01:11
71-43-2
ND
ug/L
1.0
0.34
1
11/17/20 01:11
74-97-5
ND
ug/L
1.0
0.26
1
11/17/20 01:11
75-27-4
ND
ug/L
1.0
0.62
1
11/17/20 01:11
75-25-2
ND
ug/L
2.0
0.62
1
11/17/20 01:11
74-83-9
ND
ug/L
5.0
3.3
1
11/17/20 01:11
78-93-3
ND
ug/L
2.0
0.40
1
11/17/20 01:11
75-15-0
ND
ug/L
1.0
0.22
1
11/17/20 01:11
56-23-5
ND
ug/L
1.0
0.23
1
11/17/20 01:11
108-90-7
ND
ug/L
1.0
0.49
1
11/17/20 01:11
75-00-3
ND
ug/L
5.0
2.3
1
11/17/20 01:11
67-66-3
ND
ug/L
1.0
0.39
1
11/17/20 01:11
74-87-3
ND
ug/L
5.0
1.7
1
11/17/20 01:11
126-99-8
ND
ug/L
5.0
0.26
1
11/17/20 01:11
96-12-8
ND
ug/L
1.0
0.41
1
11/17/20 01:11
124-48-1
ND
ug/L
1.0
0.26
1
11/17/20 01:11
106-93-4
ND
ug/L
1.0
0.46
1
11/17/20 01:11
74-95-3
ND
ug/L
1.0
0.29
1
11/17/20 01:11
95-50-1
ND
ug/L
1.0
0.22
1
11/17/20 01:11
541-73-1
ND
ug/L
1.0
0.26
1
11/17/20 01:11
106-46-7
ND
ug/L
1.0
0.54
1
11/17/20 01:11
110-57-6
ND
ug/L
1.0
0.23
1
11/17/20 01:11
75-71-8
ND
ug/L
1.0
0.27
1
11/17/20 01:11
75-34-3
ND
ug/L
1.0
0.34
1
11/17/20 01:11
107-06-2
ND
ug/L
1.0
0.24
1
11/17/20 01:11
75-35-4
ND
ug/L
1.0
0.29
1
11/17/20 01:11
156-59-2
ND
ug/L
1.0
0.25
1
11/17/20 01:11
156-60-5
ND
ug/L
1.0
0.19
1
11/17/20 01:11
78-87-5
ND
ug/L
1.0
0.16
1
11/17/20 01:11
142-28-9
ND
ug/L
1.0
0.27
1
11/17/20 01:11
594-20-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
IH,v1
Page 10 of 61

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
Sample: 1203-MW21 Lab ID: 92505711001 Collected: 11/11/20 07:35 Received: 11/12/20 09:51 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Ethyl methacrylate
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Methylene Chloride
Methyl methacrylate
4-Methyl-2-pentanone (MIBK)
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Date: 11/23/2020 04:17 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND ug/L
1.0
0.21
1
11/17/20 01:11
563-58-6
ND ug/L
1.0
0.30
1
11/17/20 01:11
10061-01-5
ND ug/L
1.0
0.31
1
11/17/20 01:11
10061-02-6
ND ug/L
1.0
0.26
1
11/17/20 01:11
100-41-4
ND ug/L
1.0
0.51
1
11/17/20 01:11
97-63-2
ND ug/L
1.0
0.44
1
11/17/20 01:11
87-68-3
ND ug/L
5.0
0.57
1
11/17/20 01:11
591-78-6
ND ug/L
20.0
12.5
1
11/17/20 01:11
74-88-4 IK
ND ug/L
100
66.4
1
11/17/20 01:11
78-83-1
ND ug/L
10.0
1.9
1
11/17/20 01:11
126-98-7
ND ug/L
5.0
3.7
1
11/17/20 01:11
75-09-2
ND ug/L
2.0
0.46
1
11/17/20 01:11
80-62-6
ND ug/L
5.0
4.5
1
11/17/20 01:11
108-10-1
ND ug/L
1.0
0.35
1
11/17/20 01:11
91-20-3
ND ug/L
20.0
1.8
1
11/17/20 01:11
107-12-0
ND ug/L
1.0
0.27
1
11/17/20 01:11
100-42-5
ND ug/L
1.0
0.34
1
11/17/20 01:11
630-20-6
ND ug/L
1.0
0.22
1
11/17/20 01:11
79-34-5
ND ug/L
1.0
0.16
1
11/17/20 01:11
127-18-4
ND ug/L
1.0
0.24
1
11/17/20 01:11
108-88-3
ND ug/L
1.0
0.22
1
11/17/20 01:11
120-82-1
ND ug/L
1.0
0.18
1
11/17/20 01:11
71-55-6
ND ug/L
1.0
0.24
1
11/17/20 01:11
79-00-5
ND ug/L
1.0
0.22
1
11/17/20 01:11
79-01-6
ND ug/L
1.0
0.31
1
11/17/20 01:11
75-69-4
ND ug/L
1.0
0.35
1
11/17/20 01:11
96-18-4
ND ug/L
2.0
1.4
1
11/17/20 01:11
108-05-4
ND ug/L
1.0
0.24
1
11/17/20 01:11
75-01-4
ND ug/L
1.0
0.63
1
11/17/20 01:11
1330-20-7
98 %
70-130
1
11/17/20 01:11
460-00-4
105 %
70-130
1
11/17/20 01:11
17060-07-0
101 %
70-130
1
11/17/20 01:11
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
ND ug/L
2.0
1.2
1
11/14/20 05:19
123-91-1
98 %
70-130
1
11/14/20 05:19
17060-07-0
86 %
66-133
1
11/14/20 05:19
2037-26-5
Analytical Method: SM 2320B-2011
Pace Analytical Services
-Asheville
ND ug/L
5000
5000
1
11/20/2014:34
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 61

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
Sample: 1203-MW21 Lab ID: 92505711001 Collected: 11/11/20 07:35 Received: 11/12/20 09:51 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids ND ug/L 25000 25000 1 11/17/20 15:51
4500S2D Sulfide Water Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
Sulfide
300.0 IC Anions 28 Days
Sulfate
4500 Chloride
Chloride
4500CNE Cyanide, Total
Cyanide
Date: 11/23/2020 04:17 PM
ND ug/L 100
50.0
1 11/17/2015:49
18496-25-8 M1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
ND ug/L 1000
500
1 11/13/20 20:48
14808-79-8
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
720J ug/L 1000
500
1 11/20/20 00:23
16887-00-6
Analytical Method: SM 4500-CN-E-2011
Preparation Method: SM 4500-CN-E-2011
Pace Analytical Services -Asheville
ND ug/L 8.0
6.0
1 11 /20/20 21:21 11 /22/20 13:17
57-12-5 M 1, R 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
Sample: 1203-FIELD BLANK
Lab ID:
92505711002
Collected:
11/11/20 14:08
Received: 11/12/20 09:51 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
Chlorinated Herb. (GC) 8151
Analytical
Method: EPA8151
Preparation
Method: 8151A
Pace National
- Mt. Juliet
2,4-D
ND
ug/L
2.00
0.547
1
11/17/20 08:23
11/18/20 23:13
94-75-7
2,4,5-T
ND
ug/L
2.00
0.258
1
11/17/20 08:23
11/18/20 23:13
93-76-5
2,4,5-TP (Silvex)
ND
ug/L
2.00
0.335
1
11/17/20 08:23
11/18/20 23:13
93-72-1
Dinoseb
ND
ug/L
2.00
0.250
1
11/17/20 08:23
11/18/20 23:13
88-85-7
Surrogates
2,4-DCAA (S)
72.4
%
14.0-158
1
11/17/20 08:23
11/18/20 23:13
19719-28-9
8081 OC Pesticides RVE
Analytical
Method: EPA 8081
B Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
Aldrin
ND
ug/L
0.050
0.022
1
11/16/20 17:36
11/18/20 09:32
309-00-2
alpha-BHC
ND
ug/L
0.050
0.019
1
11/16/20 17:36
11/18/20 09:32
319-84-6
beta-BHC
ND
ug/L
0.050
0.014
1
11/16/20 17:36
11/18/20 09:32
319-85-7
delta-BHC
ND
ug/L
0.050
0.020
1
11/16/20 17:36
11/18/20 09:32
319-86-8
gamma-BHC (Lindane)
ND
ug/L
0.050
0.012
1
11/16/20 17:36
11/18/20 09:32
58-89-9
Chlordane (Technical)
ND
ug/L
0.20
0.14
1
11/16/20 17:36
11/18/20 09:32
57-74-9
4,4'-DDD
ND
ug/L
0.050
0.0069
1
11/16/20 17:36
11/18/20 09:32
72-54-8
4,4'-DDE
ND
ug/L
0.050
0.0064
1
11/16/20 17:36
11/18/20 09:32
72-55-9 L1
4,4'-DDT
ND
ug/L
0.050
0.018
1
11/16/20 17:36
11/18/20 09:32
50-29-3 L1
Dieldrin
ND
ug/L
0.050
0.0073
1
11/16/20 17:36
11/18/20 09:32
60-57-1
Endosulfan I
ND
ug/L
0.050
0.0094
1
11/16/20 17:36
11/18/20 09:32
959-98-8 L1
Endosulfan 11
ND
ug/L
0.050
0.0065
1
11/16/20 17:36
11/18/20 09:32
33213-65-9
Endosulfan sulfate
ND
ug/L
0.050
0.0091
1
11/16/20 17:36
11/18/20 09:32
1031-07-8
Endrin
ND
ug/L
0.050
0.0089
1
11/16/20 17:36
11/18/20 09:32
72-20-8
Endrin aldehyde
ND
ug/L
0.050
0.013
1
11/16/20 17:36
11/18/20 09:32
7421-93-4
Heptachlor
ND
ug/L
0.050
0.016
1
11/16/20 17:36
11/18/20 09:32
76-44-8
Heptachlor epoxide
ND
ug/L
0.050
0.0097
1
11/16/20 17:36
11/18/20 09:32
1024-57-3
Methoxychlor
ND
ug/L
0.15
0.033
1
11/16/20 17:36
11/18/20 09:32
72-43-5
Toxaphene
ND
ug/L
0.20
0.19
1
11/16/20 17:36
11/18/20 09:32
8001-35-2
Surrogates
Tetrachloro-m-xylene (S)
110
%
10-184
1
11/16/20 17:36
11/18/20 09:32
877-09-8
Decachlorobiphenyl (S)
107
%
10-154
1
11/16/20 17:36
11/18/20 09:32
2051-24-3
8082 GCS PCB RVE
Analytical
Method: EPA 8082A
Preparation Method:
EPA 3510C
Pace Analytical
Services
- Charlotte
PCB-1016 (Aroclor 1016)
ND
ug/L
0.50
0.22
1
11/16/20 17:36
11/18/20 19:33
12674-11-2
PCB-1221 (Aroclor 1221)
ND
ug/L
0.50
0.32
1
11/16/20 17:36
11/18/20 19:33
11104-28-2
PCB-1232 (Aroclor 1232)
ND
ug/L
0.50
0.21
1
11/16/20 17:36
11/18/20 19:33
11141-16-5
PCB-1242 (Aroclor 1242)
ND
ug/L
0.50
0.44
1
11/16/20 17:36
11/18/20 19:33
53469-21-9
PCB-1248 (Aroclor 1248)
ND
ug/L
0.50
0.34
1
11/16/20 17:36
11/18/20 19:33
12672-29-6
PCB-1254 (Aroclor 1254)
ND
ug/L
0.50
0.24
1
11/16/20 17:36
11/18/20 19:33
11097-69-1
PCB-1260 (Aroclor 1260)
ND
ug/L
0.50
0.30
1
11/16/20 17:36
11/18/20 19:33
11096-82-5
Surrogates
Decachlorobiphenyl (S)
90
%
10-181
1
11/16/20 17:36
11/18/20 19:33
2051-24-3
Date: 11/23/2020 04:17 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 61

leAnalyiical
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
Sample: 1203-FIELD BLANK Lab ID: 92505711002 Collected: 11/11/20 14:08 Received: 11/12/20 09:51 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
11/13/20 02:07
11/15/20 19:06
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
11/13/20 02:07
11/15/20 19:06
7440-38-2
Barium
ND
ug/L
5.0
3.5
1
11/13/20 02:07
11/15/20 19:06
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
11/13/20 02:07
11/15/20 19:06
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
11/13/20 02:07
11/15/20 19:06
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
11/13/20 02:07
11/15/20 19:06
7440-47-3
Cobalt
ND
ug/L
5.0
3.6
1
11/13/20 02:07
11/15/20 19:06
7440-48-4
Copper
ND
ug/L
5.0
4.3
1
11/13/20 02:07
11/15/20 19:06
7440-50-8
Iron
ND
ug/L
50.0
41.5
1
11/13/20 02:07
11/15/20 19:06
7439-89-6
Lead
ND
ug/L
5.0
4.5
1
11/13/20 02:07
11/15/20 19:06
7439-92-1
Manganese
ND
ug/L
5.0
3.4
1
11/13/20 02:07
11/15/20 19:06
7439-96-5
Nickel
ND
ug/L
5.0
3.5
1
11/13/20 02:07
11/15/20 19:06
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
11/13/20 02:07
11/15/20 19:06
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
11/13/20 02:07
11/15/20 19:06
7440-22-4
Tin
ND
ug/L
5.0
4.7
1
11/13/20 02:07
11/15/20 19:06
7440-31-5
Vanadium
ND
ug/L
5.0
3.9
1
11/13/20 02:07
11/15/20 19:06
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
11/13/20 02:07
11/15/20 19:06
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.10
0.050
1
11/13/20 02:03
11/15/20 02:37
7440-28-0
7470 Mercury
Analytical Method: EPA 7470A Preparation Method: EPA
7470A
Pace Analytical Services -Asheville
Mercury
ND
ug/L
0.20
0.12
1
11/13/2013:31
11/16/2013:59
7439-97-6
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA
3510C
Pace Analytical Services - Charlotte
Acenaphthene
ND
ug/L
10.0
2.0
1
11/18/20 10:25
11/20/20 14:08
83-32-9
Acenaphthylene
ND
ug/L
10.0
2.0
1
11/18/20 10:25
11/20/20 14:08
208-96-8
Acetophenone
ND
ug/L
10.0
1.5
1
11/18/20 10:25
11/20/20 14:08
98-86-2
2-Acetylaminofluorene
ND
ug/L
10.0
1.9
1
11/18/20 10:25
11/20/20 14:08
53-96-3
4-Aminobiphenyl
ND
ug/L
10.0
4.2
1
11/18/20 10:25
11/20/20 14:08
92-67-1
Anthracene
ND
ug/L
10.0
2.3
1
11/18/20 10:25
11/20/20 14:08
120-12-7
Benzo(a)anthracene
ND
ug/L
10.0
2.7
1
11/18/20 10:25
11/20/20 14:08
56-55-3
Benzo(a)pyrene
ND
ug/L
10.0
2.8
1
11/18/20 10:25
11/20/20 14:08
50-32-8
Benzo(b)fluoranthene
ND
ug/L
10.0
2.6
1
11/18/20 10:25
11/20/20 14:08
205-99-2
Benzo(g,h,i)perylene
ND
ug/L
10.0
2.8
1
11/18/20 10:25
11/20/20 14:08
191-24-2
Benzo(k)fluoranthene
ND
ug/L
10.0
2.7
1
11/18/20 10:25
11/20/20 14:08
207-08-9
Benzyl alcohol
ND
ug/L
20.0
2.9
1
11/18/20 10:25
11/20/20 14:08
100-51-6
4-Bromophenylphenyl ether
ND
ug/L
10.0
1.8
1
11/18/20 10:25
11/20/20 14:08
101-55-3
Butylbenzylphthalate
ND
ug/L
10.0
3.1
1
11/18/20 10:25
11/20/20 14:08
85-68-7
4-ChIoro-3-methyl phenol
ND
ug/L
10.0
3.3
1
11/18/20 10:25
11/20/20 14:08
59-50-7
4-Chloroaniline
ND
ug/L
20.0
3.6
1
11/18/20 10:25
11/20/20 14:08
106-47-8
Chlorobenzilate
ND
ug/L
10.0
3.6
1
11/18/20 10:25
11/20/20 14:08
510-15-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
Sample: 1203-FIELD BLANK Lab ID: 92505711002 Collected: 11/11/20 14:08 Received: 11/12/20 09:51 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
bis(2-Chloroethoxy)methane
ND
ug/L
10.0
1.8
1
11/18/20 10:25
11/20/20 14:08
111-91-1
bis(2-Chloroethyl) ether
ND
ug/L
10.0
1.9
1
11/18/20 10:25
11/20/20 14:08
111-44-4
2-Chloronaphthalene
ND
ug/L
10.0
1.7
1
11/18/20 10:25
11/20/20 14:08
91-58-7
2-Chlorophenol
ND
ug/L
10.0
1.2
1
11/18/20 10:25
11/20/20 14:08
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
10.0
2.0
1
11/18/20 10:25
11/20/20 14:08
7005-72-3
Chrysene
ND
ug/L
10.0
2.8
1
11/18/20 10:25
11/20/20 14:08
218-01-9
Diallate
ND
ug/L
10.0
2.7
1
11/18/20 10:25
11/20/20 14:08
2303-16-4
Dibenz(a,h)anthracene
ND
ug/L
10.0
3.0
1
11/18/20 10:25
11/20/20 14:08
53-70-3
Dibenzofuran
ND
ug/L
10.0
2.1
1
11/18/20 10:25
11/20/20 14:08
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
20.0
8.1
1
11/18/20 10:25
11/20/20 14:08
91-94-1
2,4-Dichlorophenol
ND
ug/L
10.0
1.4
1
11/18/20 10:25
11/20/20 14:08
120-83-2
2,6-Dichlorophenol
ND
ug/L
10.0
2.7
1
11/18/20 10:25
11/20/20 14:08
87-65-0
Diethylphthalate
ND
ug/L
10.0
2.0
1
11/18/20 10:25
11/20/20 14:08
84-66-2
Dimethoate
ND
ug/L
10.0
2.0
1
11/18/20 10:25
11/20/20 14:08
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
5.0
3.3
1
11/18/20 10:25
11/20/20 14:08
60-11-7
7,12-Dimethylbenz(a)anthracene
ND
ug/L
10.0
2.8
1
11/18/20 10:25
11/20/20 14:08
57-97-6
3,3'-Dimethylbenzidine
ND
ug/L
25.0
23.5
1
11/18/20 10:25
11/20/20 14:08
119-93-7
2,4-Dimethylphenol
ND
ug/L
10.0
1.7
1
11/18/20 10:25
11/20/20 14:08
105-67-9
Dimethylphthalate
ND
ug/L
10.0
2.1
1
11/18/20 10:25
11/20/20 14:08
131-11-3
Di-n-butylphthalate
ND
ug/L
10.0
2.2
1
11/18/20 10:25
11/20/20 14:08
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
20.0
3.4
1
11/18/20 10:25
11/20/20 14:08
534-52-1
1,3-Dinitrobenzene
ND
ug/L
10.0
3.7
1
11/18/20 10:25
11/20/20 14:08
99-65-0
2,4-Dinitrophenol
ND
ug/L
50.0
26.0
1
11/18/20 10:25
11/20/20 14:08
51-28-5
2,4-Dinitrotoluene
ND
ug/L
10.0
1.6
1
11/18/20 10:25
11/20/20 14:08
121-14-2
2,6-Dinitrotoluene
ND
ug/L
10.0
1.7
1
11/18/20 10:25
11/20/20 14:08
606-20-2
Di-n-octylphthalate
ND
ug/L
10.0
3.9
1
11/18/20 10:25
11/20/20 14:08
117-84-0
Diphenylamine
ND
ug/L
10.0
3.0
1
11/18/20 10:25
11/20/20 14:08
122-39-4
Disulfoton
ND
ug/L
10.0
6.0
1
11/18/20 10:25
11/20/20 14:08
298-04-4
bis(2- Ethyl hexyl)phthalate
ND
ug/L
6.0
3.7
1
11/18/20 10:25
11/20/20 14:08
117-81-7
Ethyl methanesulfonate
ND
ug/L
20.0
2.8
1
11/18/20 10:25
11/20/20 14:08
62-50-0
Famphur
ND
ug/L
10.0
5.7
1
11/18/20 10:25
11/20/20 14:08
52-85-7
Fluoranthene
ND
ug/L
10.0
2.2
1
11/18/20 10:25
11/20/20 14:08
206-44-0
Fluorene
ND
ug/L
10.0
2.1
1
11/18/20 10:25
11/20/20 14:08
86-73-7
Hexachloro-1,3-butadiene
ND
ug/L
10.0
1.8
1
11/18/20 10:25
11/20/20 14:08
87-68-3
Hexachlorobenzene
ND
ug/L
10.0
2.2
1
11/18/20 10:25
11/20/20 14:08
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
10.0
1.6
1
11/18/20 10:25
11/20/20 14:08
77-47-4
Hexachloroethane
ND
ug/L
10.0
1.4
1
11/18/20 10:25
11/20/20 14:08
67-72-1
Hexachloropropene
ND
ug/L
10.0
5.5
1
11/18/20 10:25
11/20/20 14:08
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
10.0
2.9
1
11/18/20 10:25
11/20/20 14:08
193-39-5
Isodrin
ND
ug/L
10.0
3.0
1
11/18/20 10:25
11/20/20 14:08
465-73-6
Isophorone
ND
ug/L
10.0
1.7
1
11/18/20 10:25
11/20/20 14:08
78-59-1
Isosafrole
ND
ug/L
10.0
3.6
1
11/18/20 10:25
11/20/20 14:08
120-58-1
Kepone
ND
ug/L
10.0
8.2
1
11/18/20 10:25
11/20/20 14:08
143-50-0
Methapyrilene
ND
ug/L
50.0
27.2
1
11/18/20 10:25
11/20/20 14:08
91-80-5
3-Methylcholanthrene
ND
ug/L
10.0
5.3
1
11/18/20 10:25
11/20/20 14:08
56-49-5
REPORT OF LABORATORY ANALYSIS
IL
IH,L1
v2
IH
IL
IH,v2
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
Sample: 1203-FIELD BLANK Lab ID: 92505711002 Collected: 11/11/20 14:08 Received: 11/12/20 09:51 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Methyl methanesulfonate
ND
ug/L
5.0
3.0
1
11/18/20 10:25
11/20/20 14:08
66-27-3
2-Methylnaphthalene
ND
ug/L
10.0
1.9
1
11/18/20 10:25
11/20/20 14:08
91-57-6
Methyl parathion
ND
ug/L
10.0
2.0
1
11/18/20 10:25
11/20/20 14:08
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
10.0
1.9
1
11/18/20 10:25
11/20/20 14:08
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
10.0
1.2
1
11/18/20 10:25
11/20/20 14:08
15831-10-4
1-Naphthalenamine
ND
ug/L
5.0
4.6
1
11/18/20 10:25
11/20/20 14:08
134-32-7
2-Naphthalenamine
ND
ug/L
10.0
6.1
1
11/18/20 10:25
11/20/20 14:08
91-59-8
1,4-Naphthoquinone
ND
ug/L
5.0
2.4
1
11/18/20 10:25
11/20/20 14:08
130-15-4
2-Nitroaniline
ND
ug/L
20.0
3.0
1
11/18/20 10:25
11/20/20 14:08
88-74-4
3-Nitroaniline
ND
ug/L
20.0
3.8
1
11/18/20 10:25
11/20/20 14:08
99-09-2
4-Nitroaniline
ND
ug/L
20.0
5.1
1
11/18/20 10:25
11/20/20 14:08
100-01-6
Nitrobenzene
ND
ug/L
10.0
1.9
1
11/18/20 10:25
11/20/20 14:08
98-95-3
2-Nitrophenol
ND
ug/L
10.0
1.4
1
11/18/20 10:25
11/20/20 14:08
88-75-5
4-Nitrophenol
ND
ug/L
50.0
6.6
1
11/18/20 10:25
11/20/20 14:08
100-02-7
5-Nitro-o-toluidine
ND
ug/L
10.0
2.4
1
11/18/20 10:25
11/20/20 14:08
99-55-8
N-Nitrosodiethylamine
ND
ug/L
10.0
2.0
1
11/18/20 10:25
11/20/20 14:08
55-18-5
N-Nitrosodimethylamine
ND
ug/L
10.0
1.9
1
11/18/20 10:25
11/20/20 14:08
62-75-9
N-Nitroso-di-n-butylamine
ND
ug/L
10.0
6.2
1
11/18/20 10:25
11/20/20 14:08
924-16-3
N-Nitroso-di-n-propylamine
ND
ug/L
10.0
1.3
1
11/18/20 10:25
11/20/20 14:08
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
10.0
3.0
1
11/18/20 10:25
11/20/20 14:08
86-30-6
N-Nitrosomethylethylamine
ND
ug/L
10.0
3.3
1
11/18/20 10:25
11/20/20 14:08
10595-95-6
N-Nitrosopiperidine
ND
ug/L
10.0
2.6
1
11/18/20 10:25
11/20/20 14:08
100-75-4
N-Nitrosopyrrolidine
ND
ug/L
10.0
2.1
1
11/18/20 10:25
11/20/20 14:08
930-55-2
O,O,O-Triethylphosphorothioate
ND
ug/L
10.0
3.5
1
11/18/20 10:25
11/20/20 14:08
126-68-1
2,2'-Oxybis(1-chloropropane)
ND
ug/L
10.0
1.2
1
11/18/20 10:25
11/20/20 14:08
108-60-1
Parathion (Ethyl parathion)
ND
ug/L
10.0
2.0
1
11/18/20 10:25
11/20/20 14:08
56-38-2
Pentachlorobenzene
ND
ug/L
10.0
4.4
1
11/18/20 10:25
11/20/20 14:08
608-93-5
Pentachloronitrobenzene
ND
ug/L
10.0
2.4
1
11/18/20 10:25
11/20/20 14:08
82-68-8
Pentachlorophenol
ND
ug/L
20.0
3.8
1
11/18/20 10:25
11/20/20 14:08
87-86-5
Phenacetin
ND
ug/L
10.0
1.9
1
11/18/20 10:25
11/20/20 14:08
62-44-2
Phenanthrene
ND
ug/L
10.0
2.0
1
11/18/20 10:25
11/20/20 14:08
85-01-8
Phenol
ND
ug/L
10.0
1.4
1
11/18/20 10:25
11/20/20 14:08
108-95-2
p-Phenylenediamine
ND
ug/L
10.0
10.0
1
11/18/20 10:25
11/20/20 14:08
106-50-3
Phorate
ND
ug/L
10.0
3.8
1
11/18/20 10:25
11/20/20 14:08
298-02-2
Pronamide
ND
ug/L
10.0
2.4
1
11/18/20 10:25
11/20/20 14:08
23950-58-5
Pyrene
ND
ug/L
10.0
2.2
1
11/18/20 10:25
11/20/20 14:08
129-00-0
Safrole
ND
ug/L
10.0
3.2
1
11/18/20 10:25
11/20/20 14:08
94-59-7
1,2,4,5-Tetrachlorobenzene
ND
ug/L
10.0
4.6
1
11/18/20 10:25
11/20/20 14:08
95-94-3
2,3,4,6-Tetrachlorophenol
ND
ug/L
10.0
1.5
1
11/18/20 10:25
11/20/20 14:08
58-90-2
Thionazin
ND
ug/L
10.0
1.8
1
11/18/20 10:25
11/20/20 14:08
297-97-2
O-Toluidine
ND
ug/L
10.0
2.8
1
11/18/20 10:25
11/20/20 14:08
95-53-4
2,4,5-Trichlorophenol
ND
ug/L
10.0
1.4
1
11/18/20 10:25
11/20/20 14:08
95-95-4
2,4,6-Trichlorophenol
ND
ug/L
10.0
1.6
1
11/18/20 10:25
11/20/20 14:08
88-06-2
1,3,5-Trinitrobenzene
ND
ug/L
10.0
5.3
1
11/18/20 10:25
11/20/20 14:08
99-35-4
REPORT OF LABORATORY ANALYSIS
1g,IH,
L2
v2
v1
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
Sample: 1203-FIELD BLANK
Lab ID:
92505711002
Collected:
11/11/20
14:08 Received: 11/12/20 09:51 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF Prepared
Analyzed
CAS No. Qual
8270E APP9 RV
Analytical
Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services
- Charlotte
Surrogates
Nitrobenzene-d5 (S)
37
%
10-144
1 11/18/20 10:25
11/20/20 14:08
4165-60-0
2-Fluorobiphenyl (S)
17
%
10-130
1 11/18/20 10:25
11/20/20 14:08
321-60-8
Terphenyl-d14 (S)
118
%
34-163
1 11/18/20 10:25
11/20/20 14:08
1718-51-0
Phenol-d6 (S)
17
%
10-130
1 11/18/20 10:25
11/20/20 14:08
13127-88-3
2-Fluorophenol (S)
27
%
10-130
1 11/18/20 10:25
11/20/20 14:08
367-12-4
2,4,6-Tribromophenol (S)
55
%
10-144
1 11/18/20 10:25
11/20/20 14:08
118-79-6
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
6.2
1
11/16/20 13:58
67-64-1
Acetonitrile
ND
ug/L
50.0
30.4
1
11/16/20 13:58
75-05-8
Acrolein
ND
ug/L
10.0
2.7
1
11/16/20 13:58
107-02-8
Acrylonitrile
ND
ug/L
10.0
0.90
1
11/16/20 13:58
107-13-1
Allyl chloride
ND
ug/L
2.0
0.28
1
11/16/20 13:58
107-05-1
Benzene
ND
ug/L
1.0
0.15
1
11/16/20 13:58
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.34
1
11/16/20 13:58
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.26
1
11/16/20 13:58
75-27-4
Bromoform
ND
ug/L
1.0
0.62
1
11/16/20 13:58
75-25-2
Bromomethane
ND
ug/L
2.0
0.62
1
11/16/20 13:58
74-83-9 v2
2-Butanone (MEK)
ND
ug/L
5.0
3.3
1
11/16/20 13:58
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.40
1
11/16/20 13:58
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.22
1
11/16/20 13:58
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.23
1
11/16/20 13:58
108-90-7
Chloroethane
ND
ug/L
1.0
0.49
1
11/16/20 13:58
75-00-3
Chloroform
ND
ug/L
5.0
2.3
1
11/16/20 13:58
67-66-3
Chloromethane
ND
ug/L
1.0
0.39
1
11/16/20 13:58
74-87-3
Chloroprene
ND
ug/L
5.0
1.7
1
11/16/20 13:58
126-99-8
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
0.26
1
11/16/20 13:58
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.41
1
11/16/20 13:58
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.26
1
11/16/20 13:58
106-93-4
Dibromomethane
ND
ug/L
1.0
0.46
1
11/16/20 13:58
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.29
1
11/16/20 13:58
95-50-1
1,3-Dichlorobenzene
ND
ug/L
1.0
0.22
1
11/16/20 13:58
541-73-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.26
1
11/16/20 13:58
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.54
1
11/16/20 13:58
110-57-6 IH
Dichlorodifluoromethane
ND
ug/L
1.0
0.23
1
11/16/20 13:58
75-71-8
1,1-Dichloroethane
ND
ug/L
1.0
0.27
1
11/16/20 13:58
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.34
1
11/16/20 13:58
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.24
1
11/16/20 13:58
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.29
1
11/16/20 13:58
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.25
1
11/16/20 13:58
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.19
1
11/16/20 13:58
78-87-5
1,3-Dichloropropane
ND
ug/L
1.0
0.16
1
11/16/20 13:58
142-28-9
2,2-Dichloropropane
ND
ug/L
1.0
0.27
1
11/16/20 13:58
594-20-7
REPORT OF LABORATORY
ANALYSIS
This report
shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM
without the written
consent of Pace Analytical Services, LLC.
Page 17 of 61

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
Sample: 1203-FIELD BLANK Lab ID: 92505711002 Collected: 11/11/20 14:08 Received: 11/12/20 09:51 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Ethyl methacrylate
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Methylene Chloride
Methyl methacrylate
4-Methyl-2-pentanone (MIBK)
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Date: 11/23/2020 04:17 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.21
1
11/16/2013:58
563-58-6
ND
ug/L
1.0
0.30
1
11 /16/20 13:58
10061-01-5
ND
ug/L
1.0
0.31
1
11/16/2013:58
10061-02-6
ND
ug/L
1.0
0.26
1
11/16/2013:58
100-41-4
ND
ug/L
1.0
0.51
1
11/16/2013:58
97-63-2
ND
ug/L
1.0
0.44
1
11/16/2013:58
87-68-3
ND
ug/L
5.0
0.57
1
11/16/2013:58
591-78-6
ND
ug/L
20.0
12.5
1
11/16/2013:58
74-88-4
ND
ug/L
100
66.4
1
11/16/2013:58
78-83-1
ND
ug/L
10.0
1.9
1
11/16/2013:58
126-98-7
ND
ug/L
5.0
3.7
1
11/16/2013:58
75-09-2
ND
ug/L
2.0
0.46
1
11/16/2013:58
80-62-6
ND
ug/L
5.0
4.5
1
11/16/2013:58
108-10-1
ND
ug/L
1.0
0.35
1
11/16/2013:58
91-20-3
ND
ug/L
20.0
1.8
1
11/16/2013:58
107-12-0
ND
ug/L
1.0
0.27
1
11/16/2013:58
100-42-5
ND
ug/L
1.0
0.34
1
11/16/2013:58
630-20-6
ND
ug/L
1.0
0.22
1
11/16/2013:58
79-34-5
ND
ug/L
1.0
0.16
1
11/16/2013:58
127-18-4
ND
ug/L
1.0
0.24
1
11/16/2013:58
108-88-3
ND
ug/L
1.0
0.22
1
11/16/2013:58
120-82-1
ND
ug/L
1.0
0.18
1
11/16/2013:58
71-55-6
ND
ug/L
1.0
0.24
1
11/16/2013:58
79-00-5
ND
ug/L
1.0
0.22
1
11/16/2013:58
79-01-6
ND
ug/L
1.0
0.31
1
11/16/2013:58
75-69-4
ND
ug/L
1.0
0.35
1
11/16/2013:58
96-18-4
ND
ug/L
2.0
1.4
1
11/16/2013:58
108-05-4
ND
ug/L
1.0
0.24
1
11/16/2013:58
75-01-4
ND
ug/L
1.0
0.63
1
11/16/2013:58
1330-20-7
98
%
70-130
1
11/16/2013:58
460-00-4
98
%
70-130
1
11/16/2013:58
17060-07-0
99
%
70-130
1
11/16/2013:58
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
ND
ug/L
2.0
1.2
1
11/14/20 03:44
123-91-1
98
%
70-130
1
11/14/20 03:44
17060-07-0
86
%
66-133
1
11/14/20 03:44
2037-26-5
Analytical Method: SM 2320B-2011
Pace Analytical Services
-Asheville
ND
ug/L
5000
5000
1
11/20/2014:38
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 18 of 61

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
Sample: 1203-FIELD BLANK
Lab ID: 92505711002 Collected:
11/11/20
14:08
Received: 11/12/20 09:51 Matrix: Water
Report
Parameters
Results Units Limit MDL
DF
Prepared Analyzed
CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2011
Pace Analytical Services -Asheville
Total Dissolved Solids
ND ug/L 25000
25000
1
11/17/20 15:51
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
Sulfide
ND ug/L 100
50.0
1
11/17/2015:51
18496-25-8
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
Sulfate
ND ug/L 1000
500
1
11/13/20 21:03
14808-79-8
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
ND ug/L 1000
500
1
11/20/20 00:25
16887-00-6
450OCNE Cyanide, Total
Analytical Method: SM 4500-CN-E-2011
Preparation Method:
SM 4500-CN-E-2011
Pace Analytical Services -Asheville
Cyanide
ND ug/L 8.0
6.0
1
11 /20/20 21:21 11/22/2013:19
57-12-5 M1,R1
Date: 11/23/2020 04:17 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 19 of 61

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
Sample: TRIP BLANK Lab ID: 92505711003 Collected: 11/10/20 09:24 Received: 11/12/20 09:51 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Allyl chloride
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Chloroprene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Ethyl methacrylate
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Date: 11/23/2020 04:17 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
6.2
1
11/17/20 00:34
67-64-1
ND
ug/L
50.0
30.4
1
11/17/20 00:34
75-05-8
ND
ug/L
10.0
2.7
1
11/17/20 00:34
107-02-8 IH,v1
ND
ug/L
10.0
0.90
1
11/17/20 00:34
107-13-1
ND
ug/L
2.0
0.28
1
11/17/20 00:34
107-05-1
ND
ug/L
1.0
0.15
1
11/17/20 00:34
71-43-2
ND
ug/L
1.0
0.34
1
11/17/20 00:34
74-97-5
ND
ug/L
1.0
0.26
1
11/17/20 00:34
75-27-4
ND
ug/L
1.0
0.62
1
11/17/20 00:34
75-25-2
ND
ug/L
2.0
0.62
1
11/17/20 00:34
74-83-9
ND
ug/L
5.0
3.3
1
11/17/20 00:34
78-93-3
ND
ug/L
2.0
0.40
1
11/17/20 00:34
75-15-0
ND
ug/L
1.0
0.22
1
11/17/20 00:34
56-23-5
ND
ug/L
1.0
0.23
1
11/17/20 00:34
108-90-7
ND
ug/L
1.0
0.49
1
11/17/20 00:34
75-00-3
ND
ug/L
5.0
2.3
1
11/17/20 00:34
67-66-3
ND
ug/L
1.0
0.39
1
11/17/20 00:34
74-87-3
ND
ug/L
5.0
1.7
1
11/17/20 00:34
126-99-8
ND
ug/L
5.0
0.26
1
11/17/20 00:34
96-12-8
ND
ug/L
1.0
0.41
1
11/17/20 00:34
124-48-1
ND
ug/L
1.0
0.26
1
11/17/20 00:34
106-93-4
ND
ug/L
1.0
0.46
1
11/17/20 00:34
74-95-3
ND
ug/L
1.0
0.29
1
11/17/20 00:34
95-50-1
ND
ug/L
1.0
0.22
1
11/17/20 00:34
541-73-1
ND
ug/L
1.0
0.26
1
11/17/20 00:34
106-46-7
ND
ug/L
1.0
0.54
1
11/17/20 00:34
110-57-6
ND
ug/L
1.0
0.23
1
11/17/20 00:34
75-71-8
ND
ug/L
1.0
0.27
1
11/17/20 00:34
75-34-3
ND
ug/L
1.0
0.34
1
11/17/20 00:34
107-06-2
ND
ug/L
1.0
0.24
1
11/17/20 00:34
75-35-4
ND
ug/L
1.0
0.29
1
11/17/20 00:34
156-59-2
ND
ug/L
1.0
0.25
1
11/17/20 00:34
156-60-5
ND
ug/L
1.0
0.19
1
11/17/20 00:34
78-87-5
ND
ug/L
1.0
0.16
1
11/17/20 00:34
142-28-9
ND
ug/L
1.0
0.27
1
11/17/20 00:34
594-20-7
ND
ug/L
1.0
0.21
1
11/17/20 00:34
563-58-6
ND
ug/L
1.0
0.30
1
11/17/20 00:34
10061-01-5
ND
ug/L
1.0
0.31
1
11/17/20 00:34
10061-02-6
ND
ug/L
1.0
0.26
1
11/17/20 00:34
100-41-4
ND
ug/L
1.0
0.51
1
11/17/20 00:34
97-63-2
ND
ug/L
1.0
0.44
1
11/17/20 00:34
87-68-3
ND
ug/L
5.0
0.57
1
11/17/20 00:34
591-78-6
ND
ug/L
20.0
12.5
1
11/17/20 00:34
74-88-4 IK
ND
ug/L
100
66.4
1
11/17/20 00:34
78-83-1
ND
ug/L
10.0
1.9
1
11/17/20 00:34
126-98-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 20 of 61

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
Sample: TRIP BLANK Lab ID: 92505711003 Collected: 11/10/20 09:24 Received: 11/12/20 09:51 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Methylene Chloride
Methyl methacrylate
4-Methyl-2-pentanone (MIBK)
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 11/23/2020 04:17 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
5.0
3.7
1
11/17/20 00:34
75-09-2
ND
ug/L
2.0
0.46
1
11/17/20 00:34
80-62-6
ND
ug/L
5.0
4.5
1
11/17/20 00:34
108-10-1
ND
ug/L
1.0
0.35
1
11/17/20 00:34
91-20-3
ND
ug/L
20.0
1.8
1
11/17/20 00:34
107-12-0
ND
ug/L
1.0
0.27
1
11/17/20 00:34
100-42-5
ND
ug/L
1.0
0.34
1
11/17/20 00:34
630-20-6
ND
ug/L
1.0
0.22
1
11/17/20 00:34
79-34-5
ND
ug/L
1.0
0.16
1
11/17/20 00:34
127-18-4
ND
ug/L
1.0
0.24
1
11/17/20 00:34
108-88-3
ND
ug/L
1.0
0.22
1
11/17/20 00:34
120-82-1
ND
ug/L
1.0
0.18
1
11/17/20 00:34
71-55-6
ND
ug/L
1.0
0.24
1
11/17/20 00:34
79-00-5
ND
ug/L
1.0
0.22
1
11/17/20 00:34
79-01-6
ND
ug/L
1.0
0.31
1
11/17/20 00:34
75-69-4
ND
ug/L
1.0
0.35
1
11/17/20 00:34
96-18-4
ND
ug/L
2.0
1.4
1
11/17/20 00:34
108-05-4
ND
ug/L
1.0
0.24
1
11/17/20 00:34
75-01-4
ND
ug/L
1.0
0.63
1
11/17/20 00:34
1330-20-7
102
%
70-130
1
11/17/20 00:34
460-00-4
107
%
70-130
1
11/17/20 00:34
17060-07-0
103
%
70-130
1
11/17/20 00:34
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
ND
ug/L
2.0
1.2
1
11/14/20 03:25
123-91-1
99
%
70-130
1
11/14/20 03:25
17060-07-0
86
%
66-133
1
11/14/20 03:25
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 21 of 61

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
QC Batch: 1577499 Analysis Method: EPA 8151
QC Batch Method: 8151A Analysis Description: Chlorinated Herb. (GC) 8151
Laboratory: Pace National - Mt. Juliet
Associated Lab Samples: 92505711001, 92505711002
METHOD BLANK: R3594900-1
Matrix:
Water
Associated Lab Samples:
92505711001, 92505711002
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
2,4-D
ug/L
ND
2.00
0.547
11/18/20 21:03
Dinoseb
ug/L
ND
2.00
0.250
11/18/20 21:03
2,4,5-T
ug/L
ND
2.00
0.258
11/18/20 21:03
2,4,5-TP (Silvex)
ug/L
ND
2.00
0.335
11/18/20 21:03
2,4-DCAA (S)
%
67.2
14.0-158
11/18/20 21:03
LABORATORY CONTROL SAMPLE & LCSD:
R3594900-2
R3594900-3
Spike
LCS
LCSD
LCS
LCSD
% Rec
Max
Parameter
Units
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qualifiers
2,4-D
ug/L
5.00
4.84
5.14
96.8
103
50.0-120
6.01
20 P9
Dinoseb
ug/L
5.00
2.95
3.04
59.0
60.8
36.0-134
3.01
20 P9
2,4,5-T
ug/L
5.00
5.56
5.81
111
116
54.0-120
4.40
20 P9
2,4,5-TP (Silvex)
ug/L
5.00
5.03
5.25
101
105
50.0-125
4.28
20 P9
2,4-DCAA (S)
%
67.6
71.0
14.0-158
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC.
Page 22 of 61

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
QC Batch: 580216 Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92505711001, 92505711002
METHOD BLANK: 3069164 Matrix: Water
Associated Lab Samples: 92505711001, 92505711002
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Mercury ug/L ND 0.20 0.12 11/16/2013:23
LABORATORY CONTROL SAMPLE: 3069165
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 2.5 2.4 98 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3069166 3069167
MS MSD
92505328003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND 2.5 2.5 2.6 2.6 103 103 75-125 0 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC.
Page 23 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
QC Batch: 580091 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92505711001, 92505711002
METHOD BLANK: 3068763
Associated Lab Samples: 92505711001, 92505711002
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
Antimony
ug/L
ND
5.0
3.0
11/15/2017:55
Arsenic
ug/L
ND
10.0
4.7
11/15/2017:55
Barium
ug/L
ND
5.0
3.5
11/15/2017:55
Beryllium
ug/L
ND
1.0
0.70
11/15/2017:55
Cadmium
ug/L
ND
1.0
0.40
11/15/2017:55
Chromium
ug/L
ND
5.0
3.7
11/15/2017:55
Cobalt
ug/L
ND
5.0
3.6
11/15/2017:55
Copper
ug/L
ND
5.0
4.3
11/15/2017:55
Iron
ug/L
ND
50.0
41.5
11/15/2017:55
Lead
ug/L
ND
5.0
4.5
11/15/2017:55
Manganese
ug/L
ND
5.0
3.4
11/15/2017:55
Nickel
ug/L
ND
5.0
3.5
11/15/2017:55
Selenium
ug/L
ND
10.0
4.7
11/15/2017:55
Silver
ug/L
ND
5.0
2.5
11/15/2017:55
Tin
ug/L
ND
5.0
4.7
11/15/2017:55
Vanadium
ug/L
ND
5.0
3.9
11/15/2017:55
Zinc
ug/L
ND
10.0
9.5
11/15/2017:55
LABORATORY CONTROL SAMPLE:
3068764
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Antimony
ug/L
500
491
98
80-120
Arsenic
ug/L
500
486
97
80-120
Barium
ug/L
500
483
97
80-120
Beryllium
ug/L
500
496
99
80-120
Cadmium
ug/L
500
481
96
80-120
Chromium
ug/L
500
485
97
80-120
Cobalt
ug/L
500
488
98
80-120
Copper
ug/L
500
494
99
80-120
Iron
ug/L
5000
4880
98
80-120
Lead
ug/L
500
486
97
80-120
Manganese
ug/L
500
478
96
80-120
Nickel
ug/L
500
486
97
80-120
Selenium
ug/L
500
479
96
80-120
Silver
ug/L
250
240
96
80-120
Tin
ug/L
500
487
97
80-120
Vanadium
ug/L
500
482
96
80-120
Zinc
ug/L
500
473
95
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC.
Page 24 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
Burke Co. Johns R Background
92505711
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3068765
3068766
MS
MSD
92505711001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
250
250
225
226
90
90
75-125
0
20
Arsenic
ug/L
ND
250
250
240
247
95
97
75-125
3
20
Barium
ug/L
47.4
250
250
283
284
94
95
75-125
1
20
Beryllium
ug/L
ND
250
250
236
239
94
95
75-125
1
20
Cadmium
ug/L
ND
250
250
242
244
97
98
75-125
1
20
Chromium
ug/L
7.0
250
250
250
252
97
98
75-125
1
20
Cobalt
ug/L
8.7
250
250
248
249
96
96
75-125
0
20
Copper
ug/L
19.7
250
250
269
268
100
99
75-125
0
20
Iron
ug/L
15400
2500
2500
19300
19600
154
169
75-125
2
20 M1
Lead
ug/L
ND
250
250
243
247
96
98
75-125
2
20
Manganese
ug/L
348
250
250
560
562
85
86
75-125
0
20
Nickel
ug/L
ND
250
250
244
245
97
97
75-125
0
20
Selenium
ug/L
ND
250
250
237
234
95
93
75-125
2
20
Silver
ug/L
ND
125
125
117
118
93
94
75-125
1
20
Tin
ug/L
ND
250
250
238
241
95
96
75-125
1
20
Vanadium
ug/L
63.0
250
250
302
306
96
97
75-125
1
20
Zinc
ug/L
17.2
250
250
261
263
98
98
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC.
Page 25 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
QC Batch: 580093 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92505711001, 92505711002
METHOD BLANK: 3068771 Matrix: Water
Associated Lab Samples: 92505711001, 92505711002
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Thallium ug/L ND 0.10 0.050 11/15/2019:17
LABORATORY CONTROL SAMPLE: 3068772
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Thallium ug/L 10 10.8 108 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3068773 3068774
MS MSD
92505685001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Thallium ug/L ND 10 10 10.8 10.6 107 106 75-125 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC.
Page 26 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
QC Batch: 580552 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92505711002
METHOD BLANK: 3070998
Associated Lab Samples: 92505711002
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.34
11/16/20 12:46
1,1,1-Trichloroethane
ug/L
ND
1.0
0.18
11/16/20 12:46
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
11/16/20 12:46
1,1,2-Trichloroethane
ug/L
ND
1.0
0.24
11/16/20 12:46
1,1-Dichloroethane
ug/L
ND
1.0
0.27
11/16/20 12:46
1,1-Dichloroethene
ug/L
ND
1.0
0.24
11/16/20 12:46
1,1-Dichloropropene
ug/L
ND
1.0
0.21
11/16/20 12:46
1,2,3-Trichloropropane
ug/L
ND
1.0
0.35
11/16/20 12:46
1,2,4-Trichlorobenzene
ug/L
ND
1.0
0.22
11/16/20 12:46
1,2-Dibromo-3-chloropropane
ug/L
ND
5.0
0.26
11/16/20 12:46
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.26
11/16/20 12:46
1,2-Dichlorobenzene
ug/L
ND
1.0
0.29
11/16/20 12:46
1,2-Dichloroethane
ug/L
ND
1.0
0.34
11/16/20 12:46
1,2-Dichloropropane
ug/L
ND
1.0
0.19
11/16/20 12:46
1,3-Dichlorobenzene
ug/L
ND
1.0
0.22
11/16/20 12:46
1,3-Dichloropropane
ug/L
ND
1.0
0.16
11/16/20 12:46
1,4-Dichlorobenzene
ug/L
ND
1.0
0.26
11/16/20 12:46
2,2-Dichloropropane
ug/L
ND
1.0
0.27
11/16/20 12:46
2-Butanone (MEK)
ug/L
ND
5.0
3.3
11/16/20 12:46
2-Hexanone
ug/L
ND
5.0
0.57
11/16/20 12:46
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
4.5
11/16/20 12:46
Acetone
ug/L
ND
25.0
6.2
11/16/20 12:46
Acetonitrile
ug/L
ND
50.0
30.4
11/16/20 12:46
Acrolein
ug/L
ND
10.0
2.7
11/16/20 12:46
Acrylonitrile
ug/L
ND
10.0
0.90
11/16/20 12:46
Allyl chloride
ug/L
ND
2.0
0.28
11/16/20 12:46
Benzene
ug/L
ND
1.0
0.15
11/16/20 12:46
Bromochloromethane
ug/L
ND
1.0
0.34
11/16/20 12:46
Bromodichloromethane
ug/L
ND
1.0
0.26
11/16/20 12:46
Bromoform
ug/L
ND
1.0
0.62
11/16/20 12:46
Bromomethane
ug/L
ND
2.0
0.62
11/16/20 12:46 v2
Carbon disulfide
ug/L
ND
2.0
0.40
11/16/20 12:46
Carbon tetrachloride
ug/L
ND
1.0
0.22
11/16/20 12:46
Chlorobenzene
ug/L
ND
1.0
0.23
11/16/20 12:46
Chloroethane
ug/L
ND
1.0
0.49
11/16/20 12:46
Chloroform
ug/L
ND
5.0
2.3
11/16/20 12:46
Chloromethane
ug/L
ND
1.0
0.39
11/16/20 12:46
Chloroprene
ug/L
ND
5.0
1.7
11/16/20 12:46
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.29
11/16/20 12:46
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.30
11/16/20 12:46
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC.
Page 27 of 61

Pace Analytical Services, LLC
lac,
Analyilcal ® 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
METHOD BLANK: 3070998
Matrix:
Water
Associated Lab Samples: 92505711002
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
Dibromochloromethane
ug/L
ND
1.0
0.41
11/16/20 12:46
Dibromomethane
ug/L
ND
1.0
0.46
11/16/20 12:46
Dichlorodifluoromethane
ug/L
ND
1.0
0.23
11/16/20 12:46
Ethyl methacrylate
ug/L
ND
1.0
0.51
11/16/20 12:46
Ethylbenzene
ug/L
ND
1.0
0.26
11/16/20 12:46
Hexachloro-1,3-butadiene
ug/L
ND
1.0
0.44
11/16/20 12:46
lodomethane
ug/L
ND
20.0
12.5
11/16/20 12:46
Isobutanol
ug/L
ND
100
66.4
11/16/20 12:46
Methacrylonitrile
ug/L
ND
10.0
1.9
11/16/20 12:46
Methyl methacrylate
ug/L
ND
2.0
0.46
11/16/20 12:46
Methylene Chloride
ug/L
ND
5.0
3.7
11/16/20 12:46
Naphthalene
ug/L
ND
1.0
0.35
11/16/20 12:46
Propionitrile
ug/L
ND
20.0
1.8
11/16/20 12:46
Styrene
ug/L
ND
1.0
0.27
11/16/20 12:46
Tetrachloroethene
ug/L
ND
1.0
0.16
11/16/20 12:46
Toluene
ug/L
ND
1.0
0.24
11/16/20 12:46
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.25
11/16/20 12:46
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.31
11/16/20 12:46
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.54
11/16/20 12:46 IH
Trichloroethene
ug/L
ND
1.0
0.22
11/16/20 12:46
Trichlorofluoromethane
ug/L
ND
1.0
0.31
11/16/20 12:46
Vinyl acetate
ug/L
ND
2.0
1.4
11/16/20 12:46
Vinyl chloride
ug/L
ND
1.0
0.24
11/16/20 12:46
Xylene (Total)
ug/L
ND
1.0
0.63
11/16/20 12:46
1,2-Dichloroethane-d4 (S)
%
97
70-130
11/16/20 12:46
4-Bromofluorobenzene (S)
%
96
70-130
11/16/20 12:46
Toluene-d8 (S)
%
98
70-130
11/16/20 12:46
LABORATORY CONTROL SAMPLE:
3070999
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
53.5
107
70-130
1,1,1-Trichloroethane
ug/L
50
50.0
100
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
49.4
99
70-130
1,1,2-Trichloroethane
ug/L
50
51.4
103
70-130
1,1-Dichloroethane
ug/L
50
49.9
100
70-130
1,1-Dichloroethene
ug/L
50
54.2
108
70-132
1,1-Dichloropropene
ug/L
50
50.5
101
70-131
1,2,3-Trichloropropane
ug/L
50
50.3
101
70-130
1,2,4-Trichlorobenzene
ug/L
50
54.3
109
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
53.7
107
70-132
1,2-Dibromoethane (EDB)
ug/L
50
50.3
101
70-130
1,2-Dichlorobenzene
ug/L
50
54.2
108
70-130
1,2-Dichloroethane
ug/L
50
47.2
94
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
LABORATORY CONTROL SAMPLE:
Parameter
3070999
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,2-Dichloropropane
ug/L
50
51.4
103
70-130
1,3-Dichlorobenzene
ug/L
50
53.9
108
70-130
1,3-Dichloropropane
ug/L
50
51.7
103
70-130
1,4-Dichlorobenzene
ug/L
50
54.4
109
70-130
2,2-Dichloropropane
ug/L
50
53.1
106
70-130
2-Butanone (MEK)
ug/L
100
95.2
95
70-133
2-Hexanone
ug/L
100
104
104
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
100
101
101
70-130
Acetone
ug/L
100
101
101
70-144
Acetonitrile
ug/L
500
469
94
68-134
Acrolein
ug/L
250
318
127
32-200
Acrylonitrile
ug/L
250
241
96
70-130
Allyl chloride
ug/L
50
60.5
121
70-134
Benzene
ug/L
50
49.9
100
70-130
Bromochloromethane
ug/L
50
50.1
100
70-130
Bromodichloromethane
ug/L
50
50.7
101
70-130
Bromoform
ug/L
50
52.8
106
70-131
Bromomethane
ug/L
50
34.9
70
30-177 v2
Carbon disulfide
ug/L
50
56.5
113
70-133
Carbon tetrachloride
ug/L
50
53.7
107
70-130
Chlorobenzene
ug/L
50
54.2
108
70-130
Chloroethane
ug/L
50
45.2
90
46-131
Chloroform
ug/L
50
46.1
92
70-130
Chloromethane
ug/L
50
38.6
77
49-130
Chloroprene
ug/L
50
49.7
99
70-130
cis-1,2-Dichloroethene
ug/L
50
46.6
93
70-130
cis-1,3-Dichloropropene
ug/L
50
53.0
106
70-130
Dibromochloromethane
ug/L
50
53.3
107
70-130
Dibromomethane
ug/L
50
51.7
103
70-130
Dichlorodifluoromethane
ug/L
50
36.3
73
52-134
Ethyl methacrylate
ug/L
50
53.0
106
70-130
Ethylbenzene
ug/L
50
53.3
107
70-130
Hexachloro-1,3-butadiene
ug/L
50
56.6
113
70-131
lodomethane
ug/L
100
92.2
92
47-140
Isobutanol
ug/L
1000
1000
100
62-136
Methacrylonitrile
ug/L
500
487
97
70-130
Methyl methacrylate
ug/L
50
51.7
103
70-130
Methylene Chloride
ug/L
50
47.5
95
68-130
Naphthalene
ug/L
50
57.0
114
70-133
Propionitrile
ug/L
500
480
96
70-130
Styrene
ug/L
50
53.3
107
70-130
Tetrachloroethene
ug/L
50
46.5
93
70-130
Toluene
ug/L
50
51.5
103
70-130
trans-1,2-Dichloroethene
ug/L
50
48.9
98
70-130
trans- 1,3-Dichloropropene
ug/L
50
52.0
104
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
61.3
123
25-2001H
Trichloroethene
ug/L
50
52.9
106
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
LABORATORY CONTROL SAMPLE:
3070999
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Trichlorofluoromethane
ug/L
50
44.9
90
61-130
Vinyl acetate
ug/L
100
105
105
70-140
Vinyl chloride
ug/L
50
35.8
72
59-142
Xylene (Total)
ug/L
150
162
108
70-130
1,2-Dichloroethane-d4 (S)
%
93
70-130
4-Bromofluorobenzene (S)
%
97
70-130
Toluene-d8 (S)
%
98
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3071000
MS
92505685005 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3071001
MS
Result
MSD MS
Result % Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
22.4
22.0
112
110
70-135
2
30
1,1,1-Trichloroethane
ug/L
ND
20
20
20.9
20.5
105
102
70-148
2
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
20.9
20.1
104
100
70-131
4
30
1,1,2-Trichloroethane
ug/L
ND
20
20
20.8
20.7
104
103
70-136
0
30
1,1-Dichloroethane
ug/L
ND
20
20
20.6
19.9
103
99
70-147
4
30
1,1-Dichloroethene
ug/L
ND
20
20
23.0
22.9
115
114
70-158
0
30
1,1-Dichloropropene
ug/L
ND
20
20
20.5
20.2
102
101
70-149
1
30
1,2,3-Trichloropropane
ug/L
ND
20
20
21.2
20.5
106
103
67-137
3
30
1,2,4-Trichlorobenzene
ug/L
ND
20
20
20.7
21.0
103
105
70-139
1
30
1,2-Dibromo-3-
ug/L
ND
20
20
20.2
20.8
101
104
69-136
3
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
20.6
19.3
103
97
70-137
6
30
1,2-Dichlorobenzene
ug/L
ND
20
20
21.8
21.3
109
106
70-133
2
30
1,2-Dichloroethane
ug/L
ND
20
20
18.9
18.8
94
94
67-138
0
30
1,2-Dichloropropane
ug/L
ND
20
20
21.5
21.5
108
107
70-138
0
30
1,3-Dichlorobenzene
ug/L
ND
20
20
21.8
21.7
109
108
70-133
0
30
1,3-Dichloropropane
ug/L
ND
20
20
20.9
20.8
104
104
70-136
0
30
1,4-Dichlorobenzene
ug/L
ND
20
20
21.5
22.0
108
110
70-133
2
30
2,2-Dichloropropane
ug/L
ND
20
20
21.1
20.2
106
101
52-155
5
30
2-Butanone (MEK)
ug/L
ND
40
40
37.8
36.9
94
92
61-147
3
30
2-Hexanone
ug/L
ND
40
40
41.5
40.5
104
101
67-139
3
30
4-Methyl-2-pentanone
ug/L
ND
40
40
39.7
39.3
99
98
67-136
1
30
(MIBK)
Acetone
ug/L
ND
40
40
37.5
36.7
94
92
55-159
2
30
Acetonitrile
ug/L
ND
200
200
191
189
95
95
66-145
1
30
Acrolein
ug/L
ND
100
100
94.9
101
95
101
10-200
6
30 v2
Acrylonitrile
ug/L
ND
100
100
99.1
98.0
99
98
68-140
1
30
Allyl chloride
ug/L
ND
20
20
19.4
19.7
97
99
70-147
2
30
Benzene
ug/L
ND
20
20
20.9
21.2
105
106
67-150
1
30
Bromochloromethane
ug/L
ND
20
20
20.7
19.3
104
97
70-146
7
30
Bromodichloromethane
ug/L
ND
20
20
20.1
20.0
101
100
70-138
1
30
Bromoform
ug/L
ND
20
20
18.4
18.2
92
91
57-138
1
30
Bromomethane
ug/L
ND
20
20
15.7
16.1
79
81
10-200
3
30 v2
Carbon disulfide
ug/L
ND
20
20
22.9
23.1
115
115
70-152
1
30
Results presented on this page are in the units
indicated by the "Units" column except where
an alternate unit is presented to the right of the result.
REPORT
OF LABORATORY ANALYSIS
This report shall
not be reproduced,
except in full,
Date: 11 /23/2020 04:17 PM
without
the written
consent of Pace Analytical
Services, LLC.
Page 30 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3071000
3071001
MS
MSD
92505685005
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Carbon tetrachloride
ug/L
ND
20
20
22.3
22.9
112
115
70-147
3
30
Chlorobenzene
ug/L
ND
20
20
22.2
21.9
111
110
70-137
1
30
Chloroethane
ug/L
ND
20
20
19.7
19.7
98
98
51-166
0
30
Chloroform
ug/L
ND
20
20
19.7
18.8
97
93
70-144
5
30
Chloromethane
ug/L
ND
20
20
14.5
14.8
72
74
24-161
2
30
Chloroprene
ug/L
ND
20
20
20.5
20.4
102
102
70-143
0
30
cis-1,2-Dichloroethene
ug/L
ND
20
20
19.7
19.4
99
97
67-148
2
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
20.7
19.9
104
100
70-142
4
30
Dibromochloromethane
ug/L
ND
20
20
20.7
19.6
104
98
68-138
6
30
Dibromomethane
ug/L
ND
20
20
20.4
21.3
102
106
70-134
4
30
Dichlorodifluoromethane
ug/L
ND
20
20
16.3
15.9
81
79
43-155
2
30 v2
Ethyl methacrylate
ug/L
ND
20
20
20.7
20.7
103
104
70-137
0
30
Ethylbenzene
ug/L
ND
20
20
22.5
22.2
113
111
68-143
1
30
Hexachloro-1,3-butadiene
ug/L
ND
20
20
22.9
21.8
114
109
62-151
5
30
lodomethane
ug/L
ND
40
40
41.0
39.5
102
99
20-161
4
30
Isobutanol
ug/L
ND
400
400
377
383
94
96
44-145
2
30
Methacrylonitrile
ug/L
ND
200
200
192
189
96
94
67-139
2
30
Methyl methacrylate
ug/L
ND
20
20
19.6
20.1
98
100
70-130
2
30
Methylene Chloride
ug/L
ND
20
20
18.7
17.8
93
89
64-148
5
30
Naphthalene
ug/L
ND
20
20
21.2
20.8
106
104
57-150
2
30
Propionitrile
ug/L
ND
200
200
190
184
95
92
70-138
3
30
Styrene
ug/L
ND
20
20
20.6
20.9
103
104
70-136
1
30
Tetrachloroethene
ug/L
ND
20
20
20.4
19.8
102
99
70-139
3
30
Toluene
ug/L
ND
20
20
21.5
21.8
108
109
47-157
1
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
20.4
20.4
102
102
70-149
0
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
19.3
19.2
97
96
70-138
0
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
17.3
16.5
86
83
31-145
5
30
Trichloroethene
ug/L
ND
20
20
22.8
22.2
114
111
70-149
3
30
Trichlorofluoromethane
ug/L
ND
20
20
19.8
19.1
99
95
61-154
3
30
Vinyl acetate
ug/L
ND
40
40
37.3
36.4
93
91
48-156
2
30
Vinyl chloride
ug/L
ND
20
20
18.2
17.5
91
88
55-172
3
30
Xylene (Total)
ug/L
ND
60
60
66.8
66.7
111
111
66-145
0
30
1,2-Dichloroethane-d4 (S)
%
94
90
70-130
4-Bromofluorobenzene (S)
%
100
99
70-130
Toluene-d8 (S)
%
98
98
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC.
Page 31 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
QC Batch: 580628 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92505711001, 92505711003
METHOD BLANK: 3071409
Associated Lab Samples: 92505711001, 92505711003
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.34
11/17/20 00:16
1,1,1-Trichloroethane
ug/L
ND
1.0
0.18
11/17/20 00:16
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
11/17/20 00:16
1,1,2-Trichloroethane
ug/L
ND
1.0
0.24
11/17/20 00:16
1,1-Dichloroethane
ug/L
ND
1.0
0.27
11/17/20 00:16
1,1-Dichloroethene
ug/L
ND
1.0
0.24
11/17/20 00:16
1,1-Dichloropropene
ug/L
ND
1.0
0.21
11/17/20 00:16
1,2,3-Trichloropropane
ug/L
ND
1.0
0.35
11/17/20 00:16
1,2,4-Trichlorobenzene
ug/L
ND
1.0
0.22
11/17/20 00:16
1,2-Dibromo-3-chloropropane
ug/L
ND
5.0
0.26
11/17/20 00:16
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.26
11/17/20 00:16
1,2-Dichlorobenzene
ug/L
ND
1.0
0.29
11/17/20 00:16
1,2-Dichloroethane
ug/L
ND
1.0
0.34
11/17/20 00:16
1,2-Dichloropropane
ug/L
ND
1.0
0.19
11/17/20 00:16
1,3-Dichlorobenzene
ug/L
ND
1.0
0.22
11/17/20 00:16
1,3-Dichloropropane
ug/L
ND
1.0
0.16
11/17/20 00:16
1,4-Dichlorobenzene
ug/L
ND
1.0
0.26
11/17/20 00:16
2,2-Dichloropropane
ug/L
ND
1.0
0.27
11/17/20 00:16
2-Butanone (MEK)
ug/L
ND
5.0
3.3
11/17/20 00:16
2-Hexanone
ug/L
ND
5.0
0.57
11/17/20 00:16
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
4.5
11/17/20 00:16
Acetone
ug/L
ND
25.0
6.2
11/17/20 00:16
Acetonitrile
ug/L
ND
50.0
30.4
11/17/20 00:16
Acrolein
ug/L
ND
10.0
2.7
11/17/20 00:16
Acrylonitrile
ug/L
ND
10.0
0.90
11/17/20 00:16
Allyl chloride
ug/L
ND
2.0
0.28
11/17/20 00:16
Benzene
ug/L
ND
1.0
0.15
11/17/20 00:16
Bromochloromethane
ug/L
ND
1.0
0.34
11/17/20 00:16
Bromodichloromethane
ug/L
ND
1.0
0.26
11/17/20 00:16
Bromoform
ug/L
ND
1.0
0.62
11/17/20 00:16
Bromomethane
ug/L
ND
2.0
0.62
11/17/20 00:16
Carbon disulfide
ug/L
ND
2.0
0.40
11/17/20 00:16
Carbon tetrachloride
ug/L
ND
1.0
0.22
11/17/20 00:16
Chlorobenzene
ug/L
ND
1.0
0.23
11/17/20 00:16
Chloroethane
ug/L
ND
1.0
0.49
11/17/20 00:16
Chloroform
ug/L
ND
5.0
2.3
11/17/20 00:16
Chloromethane
ug/L
ND
1.0
0.39
11/17/20 00:16
Chloroprene
ug/L
ND
5.0
1.7
11/17/20 00:16
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.29
11/17/20 00:16
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.30
11/17/20 00:16
Qualifiers
IH,v1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC.
Page 32 of 61

Pace Analytical Services, LLC
lac,
Analyilcal ® 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
METHOD BLANK: 3071409
Associated Lab Samples: 92505711001, 92505711003
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
Dibromochloromethane
ug/L
ND
1.0
0.41
11/17/20 00:16
Dibromomethane
ug/L
ND
1.0
0.46
11/17/20 00:16
Dichlorodifluoromethane
ug/L
ND
1.0
0.23
11/17/20 00:16
Ethyl methacrylate
ug/L
ND
1.0
0.51
11/17/20 00:16
Ethylbenzene
ug/L
ND
1.0
0.26
11/17/20 00:16
Hexachloro-1,3-butadiene
ug/L
ND
1.0
0.44
11/17/20 00:16
lodomethane
ug/L
ND
20.0
12.5
11/17/20 00:16 IK
Isobutanol
ug/L
ND
100
66.4
11/17/20 00:16
Methacrylonitrile
ug/L
ND
10.0
1.9
11/17/20 00:16
Methyl methacrylate
ug/L
ND
2.0
0.46
11/17/20 00:16
Methylene Chloride
ug/L
ND
5.0
3.7
11/17/20 00:16
Naphthalene
ug/L
ND
1.0
0.35
11/17/20 00:16
Propionitrile
ug/L
ND
20.0
1.8
11/17/20 00:16
Styrene
ug/L
ND
1.0
0.27
11/17/20 00:16
Tetrachloroethene
ug/L
ND
1.0
0.16
11/17/20 00:16
Toluene
ug/L
ND
1.0
0.24
11/17/20 00:16
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.25
11/17/20 00:16
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.31
11/17/20 00:16
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.54
11/17/20 00:16
Trichloroethene
ug/L
ND
1.0
0.22
11/17/20 00:16
Trichlorofluoromethane
ug/L
ND
1.0
0.31
11/17/20 00:16
Vinyl acetate
ug/L
ND
2.0
1.4
11/17/20 00:16
Vinyl chloride
ug/L
ND
1.0
0.24
11/17/20 00:16
Xylene (Total)
ug/L
ND
1.0
0.63
11/17/20 00:16
1,2-Dichloroethane-d4 (S)
%
107
70-130
11/17/20 00:16
4-Bromofluorobenzene (S)
%
99
70-130
11/17/20 00:16
Toluene-d8 (S)
%
101
70-130
11/17/20 00:16
LABORATORY CONTROL SAMPLE:
3071410
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
49.8
100
70-130
1,1,1-Trichloroethane
ug/L
50
52.8
106
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
48.7
97
70-130
1,1,2-Trichloroethane
ug/L
50
50.3
101
70-130
1,1-Dichloroethane
ug/L
50
54.4
109
70-130
1,1-Dichloroethene
ug/L
50
59.6
119
70-132
1,1-Dichloropropene
ug/L
50
52.9
106
70-131
1,2,3-Trichloropropane
ug/L
50
50.5
101
70-130
1,2,4-Trichlorobenzene
ug/L
50
50.8
102
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
49.8
100
70-132
1,2-Dibromoethane (EDB)
ug/L
50
51.1
102
70-130
1,2-Dichlorobenzene
ug/L
50
50.3
101
70-130
1,2-Dichloroethane
ug/L
50
53.0
106
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
LABORATORY CONTROL SAMPLE: 3071410
Parameter
QUALITY CONTROL DATA
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
1,2-Dichloropropane
ug/L
50
51.0
102
70-130
1,3-Dichlorobenzene
ug/L
50
49.8
100
70-130
1,3-Dichloropropane
ug/L
50
50.8
102
70-130
1,4-Dichlorobenzene
ug/L
50
48.7
97
70-130
2,2-Dichloropropane
ug/L
50
55.0
110
70-130
2-Butanone (MEK)
ug/L
100
103
103
70-133
2-Hexanone
ug/L
100
101
101
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
100
101
101
70-130
Acetone
ug/L
100
109
109
70-144
Acetonitrile
ug/L
500
541
108
68-134
Acrolein
ug/L
250
343
137
32-200lH,v1
Acrylonitrile
ug/L
250
274
110
70-130
Allyl chloride
ug/L
50
50.5
101
70-134
Benzene
ug/L
50
50.1
100
70-130
Bromochloromethane
ug/L
50
53.9
108
70-130
Bromodichloromethane
ug/L
50
47.5
95
70-130
Bromoform
ug/L
50
47.9
96
70-131
Bromomethane
ug/L
50
42.9
86
30-177
Carbon disulfide
ug/L
50
55.6
111
70-133
Carbon tetrachloride
ug/L
50
50.6
101
70-130
Chlorobenzene
ug/L
50
49.0
98
70-130
Chloroethane
ug/L
50
51.7
103
46-131
Chloroform
ug/L
50
55.7
111
70-130
Chloromethane
ug/L
50
42.2
84
49-130
Chloroprene
ug/L
50
59.8
120
70-130
cis-1,2-Dichloroethene
ug/L
50
52.0
104
70-130
cis-1,3-Dichloropropene
ug/L
50
53.9
108
70-130
Dibromochloromethane
ug/L
50
50.6
101
70-130
Dibromomethane
ug/L
50
51.4
103
70-130
Dichlorodifluoromethane
ug/L
50
45.3
91
52-134
Ethyl methacrylate
ug/L
50
52.0
104
70-130
Ethylbenzene
ug/L
50
48.5
97
70-130
Hexachloro-1,3-butadiene
ug/L
50
51.4
103
70-131
lodomethane
ug/L
100
117
117
47-140lK
Isobutanol
ug/L
1000
1120
112
62-136
Methacrylonitrile
ug/L
500
518
104
70-130
Methyl methacrylate
ug/L
50
51.6
103
70-130
Methylene Chloride
ug/L
50
50.7
101
68-130
Naphthalene
ug/L
50
51.1
102
70-133
Propionitrile
ug/L
500
586
117
70-130
Styrene
ug/L
50
49.6
99
70-130
Tetrachloroethene
ug/L
50
47.7
95
70-130
Toluene
ug/L
50
50.3
101
70-130
trans-1,2-Dichloroethene
ug/L
50
57.9
116
70-130
trans- 1,3-Dichloropropene
ug/L
50
51.5
103
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
52.9
106
25-200
Trichloroethene
ug/L
50
54.3
109
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 61

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
LABORATORY CONTROL SAMPLE:
3071410
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Trichlorofluoromethane
ug/L
50
49.2
98
61-130
Vinyl acetate
ug/L
100
122
122
70-140
Vinyl chloride
ug/L
50
47.8
96
59-142
Xylene (Total)
ug/L
150
148
99
70-130
1,2-Dichloroethane-d4 (S)
%
100
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
100
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3071411
MS
92506094007 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3071412
MS
Result
MSD MS
Result % Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
22.7
22.5
113
113
70-135
1
30
1,1,1-Trichloroethane
ug/L
ND
20
20
21.3
21.4
107
107
70-148
0
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
21.5
20.5
107
102
70-131
5
30
1,1,2-Trichloroethane
ug/L
ND
20
20
21.5
21.2
107
106
70-136
1
30
1,1-Dichloroethane
ug/L
4.1
20
20
25.4
25.0
106
104
70-147
2
30
1,1-Dichloroethene
ug/L
ND
20
20
23.9
24.0
120
120
70-158
0
30
1,1-Dichloropropene
ug/L
ND
20
20
21.4
22.5
107
112
70-149
5
30
1,2,3-Trichloropropane
ug/L
ND
20
20
21.0
20.3
105
101
67-137
4
30
1,2,4-Trichlorobenzene
ug/L
ND
20
20
21.8
22.3
109
111
70-139
2
30
1,2-Dibromo-3-
ug/L
ND
20
20
20.6
20.5
103
102
69-136
1
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
21.1
20.4
105
102
70-137
3
30
1,2-Dichlorobenzene
ug/L
0.38J
20
20
22.4
22.4
110
110
70-133
0
30
1,2-Dichloroethane
ug/L
0.52J
20
20
20.5
20.2
100
99
67-138
2
30
1,2-Dichloropropane
ug/L
ND
20
20
21.7
22.0
109
110
70-138
1
30
1,3-Dichlorobenzene
ug/L
ND
20
20
22.7
22.7
114
114
70-133
0
30
1,3-Dichloropropane
ug/L
ND
20
20
21.2
21.6
106
108
70-136
2
30
1,4-Dichlorobenzene
ug/L
14.0
20
20
38.0
37.4
120
117
70-133
2
30
2,2-Dichloropropane
ug/L
ND
20
20
21.5
24.9
108
125
52-155
15
30
2-Butanone (MEK)
ug/L
ND
40
40
41.0
41.4
102
104
61-147
1
30
2-Hexanone
ug/L
ND
40
40
42.6
42.0
106
105
67-139
1
30
4-Methyl-2-pentanone
ug/L
ND
40
40
41.3
41.4
103
103
67-136
0
30
(MIBK)
Acetone
ug/L
ND
40
40
87.4
87.1
219
218
55-159
0
30 M1
Acetonitrile
ug/L
ND
200
200
197
193
98
97
66-145
2
30
Acrolein
ug/L
ND
100
100
106
102
106
102
10-200
4
30 v2
Acrylonitrile
ug/L
ND
100
100
102
98.2
102
98
68-140
4
30
Allyl chloride
ug/L
ND
20
20
19.6
20.6
98
103
70-147
5
30
Benzene
ug/L
4.7
20
20
26.3
26.0
108
106
67-150
1
30
Bromochloromethane
ug/L
ND
20
20
20.9
21.1
105
106
70-146
1
30
Bromodichloromethane
ug/L
ND
20
20
20.6
20.4
103
102
70-138
1
30
Bromoform
ug/L
ND
20
20
19.1
18.5
96
92
57-138
3
30
Bromomethane
ug/L
ND
20
20
15.3
13.8
76
69
10-200
10
30 v2
Carbon disulfide
ug/L
ND
20
20
23.8
23.6
119
118
70-152
1
30
Results presented on this page are in the units
indicated by the "Units" column except where
an alternate unit is presented to the right of the result.
REPORT
OF LABORATORY ANALYSIS
This report shall
not be reproduced,
except in full,
Date: 11 /23/2020 04:17 PM
without
the written
consent of Pace Analytical
Services, LLC.
Page 35 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3071411
3071412
MS
MSD
92506094007
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Carbon tetrachloride
ug/L
ND
20
20
23.4
23.1
117
116
70-147
1
30
Chlorobenzene
ug/L
0.67J
20
20
24.1
23.4
117
114
70-137
3
30
Chloroethane
ug/L
ND
20
20
22.6
21.1
113
106
51-166
7
30
Chloroform
ug/L
ND
20
20
18.9
20.0
94
100
70-144
6
30
Chloromethane
ug/L
ND
20
20
15.8
14.6
79
73
24-161
8
30
Chloroprene
ug/L
ND
20
20
21.0
21.0
105
105
70-143
0
30
cis-1,2-Dichloroethene
ug/L
8.1
20
20
27.7
28.0
98
100
67-148
1
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
20.7
20.8
104
104
70-142
0
30
Dibromochloromethane
ug/L
ND
20
20
21.0
21.0
105
105
68-138
0
30
Dibromomethane
ug/L
ND
20
20
21.7
20.8
109
104
70-134
4
30
Dichlorodifluoromethane
ug/L
ND
20
20
16.6
16.8
83
84
43-155
1
30 v2
Ethyl methacrylate
ug/L
ND
20
20
22.7
21.7
114
108
70-137
5
30
Ethylbenzene
ug/L
1.4
20
20
24.5
24.1
116
114
68-143
2
30
Hexachloro-1,3-butadiene
ug/L
ND
20
20
23.1
23.2
116
116
62-151
0
30
lodomethane
ug/L
ND
40
40
41.6
42.4
104
106
20-161
2
30
Isobutanol
ug/L
ND
400
400
407
395
102
99
44-145
3
30
Methacrylonitrile
ug/L
ND
200
200
196
196
98
98
67-139
0
30
Methyl methacrylate
ug/L
ND
20
20
21.0
20.5
105
102
70-130
2
30
Methylene Chloride
ug/L
ND
20
20
19.7
18.8
98
94
64-148
5
30
Naphthalene
ug/L
3.7
20
20
26.7
26.3
115
113
57-150
1
30
Propionitrile
ug/L
ND
200
200
195
191
97
96
70-138
2
30
Styrene
ug/L
ND
20
20
22.1
22.2
111
111
70-136
0
30
Tetrachloroethene
ug/L
ND
20
20
20.0
20.2
100
101
70-139
1
30
Toluene
ug/L
0.64J
20
20
22.7
22.4
110
109
47-157
1
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
21.1
20.9
106
105
70-149
1
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
20.2
20.1
101
100
70-138
1
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
16.0
16.2
80
81
31-145
1
30
Trichloroethene
ug/L
ND
20
20
23.1
23.0
116
115
70-149
0
30
Trichlorofluoromethane
ug/L
ND
20
20
20.5
20.1
103
100
61-154
2
30
Vinyl acetate
ug/L
ND
40
40
40.3
40.1
101
100
48-156
1
30
Vinyl chloride
ug/L
1.1
20
20
20.2
19.7
95
93
55-172
2
30
Xylene (Total)
ug/L
ND
60
60
71.2
69.5
119
116
66-145
2
30
1,2-Dichloroethane-d4 (S)
%
93
93
70-130
4-Bromofluorobenzene (S)
%
100
99
70-130
Toluene-d8 (S)
%
98
98
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC.
Page 36 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
QC Batch: 580296 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92505711001, 92505711002, 92505711003
METHOD BLANK: 3069740
Matrix:
Water
Associated Lab Samples:
92505711001, 92505711002,
92505711003
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
1.2 11/14/20 02:46
1,2-Dichloroethane-d4 (S)
%
100
70-130
11/14/20 02:46
Toluene-d8 (S)
%
87
66-133
11/14/20 02:46
LABORATORY CONTROL SAMPLE: 3069741
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 18.7 94 70-130
1,2-Dichloroethane-d4 (S) % 98 70-130
Toluene-d8 (S) % 87 66-133
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3069742
3069743
MS
MSD
92505897004 Spike
Spike MS MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result
% Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L ND 20
20 20.1 19.2
95
91
64-141
4 30
1,2-Dichloroethane-d4 (S)
%
98
100
70-130
30
Toluene-d8 (S)
%
85
85
66-133
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC.
Page 37 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
QC Batch: 580717 Analysis Method: EPA 8081 B
QC Batch Method: EPA 3510C Analysis Description: 8081 OC Pesticides Red Vol
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92505711001, 92505711002
METHOD BLANK: 3071766
Associated Lab Samples: 92505711001, 92505711002
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
4,4'-DDD
ug/L
ND
0.050
0.0069
11/18/20 12:01
4,4'-DDE
ug/L
ND
0.050
0.0064
11/18/20 12:01
4,4'-DDT
ug/L
ND
0.050
0.018
11/18/20 12:01
Aldrin
ug/L
ND
0.050
0.022
11/18/20 12:01
alpha-BHC
ug/L
ND
0.050
0.019
11/18/20 12:01
beta-BHC
ug/L
ND
0.050
0.014
11/18/20 12:01
Chlordane (Technical)
ug/L
ND
0.20
0.14
11/18/20 12:01
delta-BHC
ug/L
ND
0.050
0.020
11/18/20 12:01
Dieldrin
ug/L
ND
0.050
0.0073
11/18/20 12:01
Endosulfan I
ug/L
ND
0.050
0.0094
11/18/20 12:01
Endosulfan 11
ug/L
ND
0.050
0.0065
11/18/20 12:01
Endosulfan sulfate
ug/L
ND
0.050
0.0091
11/18/20 12:01
Endrin
ug/L
ND
0.050
0.0089
11/18/20 12:01
Endrin aldehyde
ug/L
ND
0.050
0.013
11/18/20 12:01
gamma-BHC (Lindane)
ug/L
ND
0.050
0.012
11/18/20 12:01
Heptachlor
ug/L
ND
0.050
0.016
11/18/20 12:01
Heptachlor epoxide
ug/L
ND
0.050
0.0097
11/18/20 12:01
Methoxychlor
ug/L
ND
0.15
0.033
11/18/20 12:01
Toxaphene
ug/L
ND
0.20
0.19
11/18/20 12:01
Decachlorobiphenyl (S)
%
120
10-154
11/18/20 12:01
Tetrachloro-m-xylene (S)
%
89
10-184
11/18/20 12:01
LABORATORY CONTROL SAMPLE: 3071767
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
4,4'-DDD
ug/L
0.25
0.37
146
45-158
4,4'-DDE
ug/L
0.25
0.35
142
37-141 L1
4,4'-DDT
ug/L
0.25
0.42
167
52-160 L1
Aldrin
ug/L
0.25
0.28
110
10-130
alpha-BHC
ug/L
0.25
0.30
121
37-139
beta-BHC
ug/L
0.25
0.38
153
39-176
delta-BHC
ug/L
0.25
0.35
140
39-144
Dieldrin
ug/L
0.25
0.36
145
40-149
Endosulfan I
ug/L
0.25
0.37
148
44-145 L1
Endosulfan II
ug/L
0.25
0.37
146
47-153
Endosulfan sulfate
ug/L
0.25
0.37
148
48-159
Endrin
ug/L
0.25
0.37
149
41-155
Endrin aldehyde
ug/L
0.25
0.32
129
45-146
gamma-BHC (Lindane)
ug/L
0.25
0.34
135
42-146
Results presented on
this page are in the units
indicated by the "Units"
column except
where an alternate unit
is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC.
Page 38 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
LABORATORY CONTROL SAMPLE:
3071767
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Heptachlor
ug/L
0.25
0.31
123
23-135
Heptachlor epoxide
ug/L
0.25
0.34
138
39-142
Methoxychlor
ug/L
0.75
1.2
159
55-173
Decachlorobiphenyl (S)
%
126
10-154
Tetrachloro-m-xylene (S)
%
101
10-184
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3071770
3071771
MS
MSD
92498632007
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
4,4'-DDD
ug/L
ND
0.25
0.25
0.31
0.34
126
135
36-169
7
30
4,4'-DDE
ug/L
ND
0.25
0.25
0.35
0.39
142
156
31-154
10
30 MO
4,4'-DDT
ug/L
ND
0.25
0.25
0.38
0.38
152
152
23-187
0
30
Aldrin
ug/L
ND
0.25
0.25
0.71
0.44
285
176
10-141
47
30 M1,R1
alpha-BHC
ug/L
ND
0.25
0.25
0.29
0.47
116
187
25-151
47
30 M1,R1
beta-BHC
ug/L
ND
0.25
0.25
0.52
0.76
209
306
30-188
38
30 M1,R1
delta-BHC
ug/L
ND
0.25
0.25
0.52
0.45
206
180
32-157
14
30 M1
Dieldrin
ug/L
ND
0.25
0.25
0.33
0.38
130
151
24-165
15
30
Endosulfan I
ug/L
ND
0.25
0.25
0.41
0.41
165
164
19-168
0
30
Endosulfan II
ug/L
ND
0.25
0.25
0.33
0.34
132
136
27-176
3
30
Endosulfan sulfate
ug/L
ND
0.25
0.25
0.34
0.34
138
138
31-174
0
30
Endrin
ug/L
ND
0.25
0.25
0.30
0.33
121
133
23-171
9
30
Endrin aldehyde
ug/L
ND
0.25
0.25
0.36
0.32
145
127
16-177
13
30
gamma-BHC (Lindane)
ug/L
ND
0.25
0.25
0.33
0.40
131
162
29-157
21
30 M1
Heptachlor
ug/L
ND
0.25
0.25
0.53
0.50
212
200
11-149
6
30 M1
Heptachlor epoxide
ug/L
ND
0.25
0.25
0.99
0.54
394
214
21-157
59
30 M1,R1
Methoxychlor
ug/L
ND
0.75
0.75
1.1
1.1
140
147
33-193
5
30
Decachlorobiphenyl (S)
%
108
105
10-154
Tetrachloro-m-xylene (S)
%
115
192
10-184
SO
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC.
Page 39 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
QC Batch: 580445 Analysis Method: EPA 8082A
QC Batch Method: EPA 3510C Analysis Description: 8082 GCS PCB
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92505711001, 92505711002
METHOD BLANK: 3070458
Matrix:
Water
Associated Lab Samples:
92505711001, 92505711002
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
PCB-1016 (Aroclor 1016)
ug/L
ND
0.50
0.22
11/16/20 19:34
PCB-1221 (Aroclor 1221)
ug/L
ND
0.50
0.32
11/16/20 19:34
PCB-1232 (Aroclor 1232)
ug/L
ND
0.50
0.21
11/16/20 19:34
PCB-1242 (Aroclor 1242)
ug/L
ND
0.50
0.44
11/16/20 19:34
PCB-1248 (Aroclor 1248)
ug/L
ND
0.50
0.34
11/16/20 19:34
PCB-1254 (Aroclor 1254)
ug/L
ND
0.50
0.24
11/16/20 19:34
PCB-1260 (Aroclor 1260)
ug/L
ND
0.50
0.30
11/16/20 19:34
Decachlorobiphenyl (S)
%
136
10-181
11/16/20 19:34
LABORATORY CONTROL SAMPLE: 3070459
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
PCB-1016 (Aroclor 1016) ug/L 5 6.3 126 41-137
PCB-1260 (Aroclor 1260) ug/L 5 6.1 122 42-156
Decachlorobiphenyl (S) % 131 10-181
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3070460
3070461
MS
MSD
92498633012 Spike
Spike MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result
Result
% Rec
% Rec
Limits
RPD RPD Qual
PCB-1016 (Aroclor 1016)
ug/L ND 5
5 5.5
5.5
110
110
22-145
0 30
PCB-1260 (Aroclor 1260)
ug/L ND 5
5 6.4
6.2
128
124
10-167
3 30
Decachlorobiphenyl (S)
%
146
138
10-181
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC.
Page 40 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
QC Batch: 581129 Analysis Method: EPA 8270E
QC Batch Method: EPA 3510C Analysis Description: 8270E Water APP9 RV MSSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92505711001, 92505711002
METHOD BLANK: 3073581
Associated Lab Samples: 92505711001, 92505711002
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
1,2,4,5-Tetrachlorobenzene
ug/L
ND
10.0
4.6
11/20/20 12:53
1,3,5-Trinitrobenzene
ug/L
ND
10.0
5.3
11/20/20 12:53
1,3-Dinitrobenzene
ug/L
ND
10.0
3.7
11/20/20 12:53
1,4-Naphthoquinone
ug/L
ND
5.0
2.4
11/20/20 12:53
1-Naphthalenamine
ug/L
ND
5.0
4.6
11/20/20 12:53
2,2'-Oxybis(1-chloropropane)
ug/L
ND
10.0
1.2
11/20/20 12:53
2,3,4,6-Tetrachlorophenol
ug/L
ND
10.0
1.5
11/20/20 12:53
2,4,5-Trichlorophenol
ug/L
ND
10.0
1.4
11/20/20 12:53
2,4,6-Trichlorophenol
ug/L
ND
10.0
1.6
11/20/20 12:53
2,4-Dichlorophenol
ug/L
ND
10.0
1.4
11/20/20 12:53
2,4-Dimethylphenol
ug/L
ND
10.0
1.7
11/20/20 12:53
2,4-Dinitrophenol
ug/L
ND
50.0
26.0
11/20/20 12:53
2,4-Dinitrotoluene
ug/L
ND
10.0
1.6
11/20/20 12:53
2,6-Dichlorophenol
ug/L
ND
10.0
2.7
11/20/20 12:53
2,6-Dinitrotoluene
ug/L
ND
10.0
1.7
11/20/20 12:53
2-Acetylaminofluorene
ug/L
ND
10.0
1.9
11/20/20 12:53
2-Chloronaphthalene
ug/L
ND
10.0
1.7
11/20/20 12:53
2-Chlorophenol
ug/L
ND
10.0
1.2
11/20/20 12:53
2-Methylnaphthalene
ug/L
ND
10.0
1.9
11/20/20 12:53
2-Methylphenol(o-Cresol)
ug/L
ND
10.0
1.9
11/20/20 12:53
2-Naphthalenamine
ug/L
ND
10.0
6.1
11/20/20 12:53
2-Nitroaniline
ug/L
ND
20.0
3.0
11/20/20 12:53
2-Nitrophenol
ug/L
ND
10.0
1.4
11/20/20 12:53
3&4-Methyl phenol (m&p Cresol)
ug/L
ND
10.0
1.2
11/20/20 12:53
3,3'-Dichlorobenzidine
ug/L
ND
20.0
8.1
11/20/20 12:53
3,3'-Dimethylbenzidine
ug/L
ND
25.0
23.5
11/20/20 12:53
3-Methylcholanthrene
ug/L
ND
10.0
5.3
11/20/20 12:53
3-Nitroaniline
ug/L
ND
20.0
3.8
11/20/20 12:53
4,6-Dinitro-2-methyl phenol
ug/L
ND
20.0
3.4
11/20/20 12:53
4-Aminobiphenyl
ug/L
ND
10.0
4.2
11/20/20 12:53
4-Bromophenylphenyl ether
ug/L
ND
10.0
1.8
11/20/20 12:53
4-ChIoro-3-methyl phenol
ug/L
ND
10.0
3.3
11/20/20 12:53
4-Chloroaniline
ug/L
ND
20.0
3.6
11/20/20 12:53
4-Chlorophenylphenyl ether
ug/L
ND
10.0
2.0
11/20/20 12:53
4-Nitroaniline
ug/L
ND
20.0
5.1
11/20/20 12:53
4-Nitrophenol
ug/L
ND
50.0
6.6
11/20/20 12:53
5-Nitro-o-toluidine
ug/L
ND
10.0
2.4
11/20/20 12:53
7,12-Dimethylbenz(a)anthracene
ug/L
ND
10.0
2.8
11/20/20 12:53
Acenaphthene
ug/L
ND
10.0
2.0
11/20/20 12:53
Acenaphthylene
ug/L
ND
10.0
2.0
11/20/20 12:53
v1
IH
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
METHOD BLANK: 3073581
Associated Lab Samples: 92505711001, 92505711002
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Acetophenone
ug/L
ND
10.0
1.5
11/20/20 12:53
Anthracene
ug/L
ND
10.0
2.3
11/20/20 12:53
Benzo(a)anthracene
ug/L
ND
10.0
2.7
11/20/20 12:53
Benzo(a)pyrene
ug/L
ND
10.0
2.8
11/20/20 12:53
Benzo(b)fluoranthene
ug/L
ND
10.0
2.6
11/20/20 12:53
Benzo(g,h,i)perylene
ug/L
ND
10.0
2.8
11/20/20 12:53
Benzo(k)fluoranthene
ug/L
ND
10.0
2.7
11/20/20 12:53
Benzyl alcohol
ug/L
ND
20.0
2.9
11/20/20 12:53
bis(2-Chloroethoxy)methane
ug/L
ND
10.0
1.8
11/20/20 12:53
bis(2-Chloroethyl) ether
ug/L
ND
10.0
1.9
11/20/20 12:53
bis(2-Ethylhexyl)phthalate
ug/L
ND
6.0
3.7
11/20/20 12:53
Butylbenzylphthalate
ug/L
ND
10.0
3.1
11/20/20 12:53
Chlorobenzilate
ug/L
ND
10.0
3.6
11/20/20 12:53
Chrysene
ug/L
ND
10.0
2.8
11/20/20 12:53
Di-n-butylphthalate
ug/L
ND
10.0
2.2
11/20/20 12:53
Di-n-octylphthalate
ug/L
ND
10.0
3.9
11/20/20 12:53
Diallate
ug/L
ND
10.0
2.7
11/20/20 12:53
Dibenz(a,h)anthracene
ug/L
ND
10.0
3.0
11/20/20 12:53
Dibenzofuran
ug/L
ND
10.0
2.1
11/20/20 12:53
Diethylphthalate
ug/L
ND
10.0
2.0
11/20/20 12:53
Dimethoate
ug/L
ND
10.0
2.0
11/20/20 12:53
Dimethylphthalate
ug/L
ND
10.0
2.1
11/20/20 12:53
Diphenylamine
ug/L
ND
10.0
3.0
11/20/20 12:53
Disulfoton
ug/L
ND
10.0
6.0
11/20/20 12:53
Ethyl methanesulfonate
ug/L
ND
20.0
2.8
11/20/20 12:53
Famphur
ug/L
ND
10.0
5.7
11/20/20 12:53
Fluoranthene
ug/L
ND
10.0
2.2
11/20/20 12:53
Fluorene
ug/L
ND
10.0
2.1
11/20/20 12:53
Hexachloro-1,3-butadiene
ug/L
ND
10.0
1.8
11/20/20 12:53
Hexachlorobenzene
ug/L
ND
10.0
2.2
11/20/20 12:53
Hexachlorocyclopentadiene
ug/L
ND
10.0
1.6
11/20/20 12:53
Hexachloroethane
ug/L
ND
10.0
1.4
11/20/20 12:53
Hexachloropropene
ug/L
ND
10.0
5.5
11/20/20 12:53
Indeno(1,2,3-cd)pyrene
ug/L
ND
10.0
2.9
11/20/20 12:53
Isodrin
ug/L
ND
10.0
3.0
11/20/20 12:53
Isophorone
ug/L
ND
10.0
1.7
11/20/20 12:53
Isosafrole
ug/L
ND
10.0
3.6
11/20/20 12:53
Kepone
ug/L
ND
10.0
8.2
11/20/20 12:53
Methapyrilene
ug/L
ND
50.0
27.2
11/20/20 12:53
Methyl methanesulfonate
ug/L
ND
5.0
3.0
11/20/20 12:53
Methyl parathion
ug/L
ND
10.0
2.0
11/20/20 12:53
N-Nitroso-di-n-butylamine
ug/L
ND
10.0
6.2
11/20/20 12:53
N-Nitroso-di-n-propylamine
ug/L
ND
10.0
1.3
11/20/20 12:53
N-Nitrosodiethylamine
ug/L
ND
10.0
2.0
11/20/20 12:53
N-Nitrosodimethylamine
ug/L
ND
10.0
1.9
11/20/20 12:53
Qualifiers
v2
IH
IL
IH,v2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 42 of 61

Pace Analytical Services, LLC
lac,
Analyilcal ® 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
METHOD BLANK: 3073581
Associated Lab Samples: 92505711001, 92505711002
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
N-Nitrosodiphenylamine
ug/L
ND
10.0
3.0
11/20/20 12:53
N-Nitrosomethylethylamine
ug/L
ND
10.0
3.3
11/20/20 12:53
N-Nitrosopiperidine
ug/L
ND
10.0
2.6
11/20/20 12:53
N-Nitrosopyrrolidine
ug/L
ND
10.0
2.1
11/20/20 12:53
Nitrobenzene
ug/L
ND
10.0
1.9
11/20/20 12:53
O,O,O-Triethylphosphorothioate
ug/L
ND
10.0
3.5
11/20/20 12:53
O-Toluidine
ug/L
ND
10.0
2.8
11/20/20 12:53
P-Dimethylaminoazobenzene
ug/L
ND
5.0
3.3
11/20/20 12:53 IL
p-Phenylenediamine
ug/L
ND
10.0
10.0
11/20/20 12:53 1g,IH
Parathion (Ethyl parathion)
ug/L
ND
10.0
2.0
11/20/20 12:53
Pentachlorobenzene
ug/L
ND
10.0
4.4
11/20/20 12:53
Pentachloronitrobenzene
ug/L
ND
10.0
2.4
11/20/20 12:53
Pentachlorophenol
ug/L
ND
20.0
3.8
11/20/20 12:53
Phenacetin
ug/L
ND
10.0
1.9
11/20/20 12:53
Phenanthrene
ug/L
ND
10.0
2.0
11/20/20 12:53
Phenol
ug/L
ND
10.0
1.4
11/20/20 12:53
Phorate
ug/L
ND
10.0
3.8
11/20/20 12:53
Pronamide
ug/L
ND
10.0
2.4
11/20/20 12:53
Pyrene
ug/L
ND
10.0
2.2
11/20/20 12:53
Safrole
ug/L
ND
10.0
3.2
11/20/20 12:53
Thionazin
ug/L
ND
10.0
1.8
11/20/20 12:53 v2
2,4,6-Tribromophenol (S)
%
90
10-144
11/20/20 12:53
2-Fluorobiphenyl (S)
%
61
10-130
11/20/20 12:53
2-Fluorophenol (S)
%
57
10-130
11/20/20 12:53
Nitrobenzene-d5 (S)
%
84
10-144
11/20/20 12:53
Phenol-d6 (S)
%
40
10-130
11/20/20 12:53
Terphenyl-d14 (S)
%
140
34-163
11/20/20 12:53
LABORATORY CONTROL SAMPLE:
Parameter
3073582
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,2,4,5-Tetrachlorobenzene
ug/L
50
35.5
71
17-130
1,3,5-Trinitrobenzene
ug/L
50
56.5
113
44-200 v1
1,3-Dinitrobenzene
ug/L
50
50.6
101
39-159
1,4-Naphthoquinone
ug/L
50
17.5
35
10-159
1-Naphthalenamine
ug/L
50
47.6
95
10-130
2,2'-Oxybis(1-chloropropane)
ug/L
50
32.4
65
28-130
2,3,4,6-Tetrachlorophenol
ug/L
50
46.7
93
10-200
2,4,5-Trichlorophenol
ug/L
50
44.8
90
35-130
2,4,6-Trichlorophenol
ug/L
50
43.9
88
31-130
2,4-Dichlorophenol
ug/L
50
41.6
83
35-130
2,4-Dimethylphenol
ug/L
50
44.2
88
34-130
2,4-Dinitrophenol
ug/L
250
210
84
10-153
2,4-Dinitrotoluene
ug/L
50
52.7
105
37-136
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 43 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
LABORATORY CONTROL SAMPLE: 3073582
Parameter
QUALITY CONTROL DATA
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
2,6-Dichlorophenol
ug/L
50
48.7
97
31-139
2,6-Dinitrotoluene
ug/L
50
50.4
101
33-136
2-Acetylaminofluorene
ug/L
50
44.4
89
19-181
2-Chloronaphthalene
ug/L
50
42.2
84
26-130
2-Chlorophenol
ug/L
50
37.9
76
37-130
2-Methylnaphthalene
ug/L
50
36.9
74
29-130
2-Methylphenol(o-Cresol)
ug/L
50
34.8
70
35-130
2-Naphthalenamine
ug/L
50
47.8
96
10-136
2-Nitroaniline
ug/L
100
86.0
86
37-130
2-Nitrophenol
ug/L
50
43.2
86
32-130
3&4-Methyl phenol (m&p Cresol)
ug/L
50
37.1
74
34-130
3,3'-Dichlorobenzidine
ug/L
100
112
112
34-136
3,3'-Dimethylbenzidine
ug/L
100
212
212
10-200lH,L1
3-Methylcholanthrene
ug/L
50
55.0
110
39-190
3-Nitroaniline
ug/L
100
96.0
96
37-138
4,6-Dinitro-2-methyl phenol
ug/L
100
99.4
99
21-157
4-Aminobiphenyl
ug/L
50
56.8
114
17-137
4-Bromophenylphenyl ether
ug/L
50
47.4
95
38-130
4-ChIoro-3-methyl phenol
ug/L
100
82.8
83
37-130
4-Chloroaniline
ug/L
100
85.3
85
38-130
4-Chlorophenylphenyl ether
ug/L
50
44.7
89
33-130
4-Nitroaniline
ug/L
100
104
104
42-137
4-Nitrophenol
ug/L
250
152
61
10-130
5-Nitro-o-toluidine
ug/L
50
54.8
110
39-170
7,12-Dimethylbenz(a)anthracene
ug/L
50
47.6
95
33-139
Acenaphthene
ug/L
50
44.1
88
33-130
Acenaphthylene
ug/L
50
43.9
88
35-130
Acetophenone
ug/L
50
40.7
81
36-130
Anthracene
ug/L
50
44.6
89
48-130
Benzo(a)anthracene
ug/L
50
49.2
98
48-137
Benzo(a)pyrene
ug/L
50
52.1
104
49-138
Benzo(b)fluoranthene
ug/L
50
56.5
113
52-138
Benzo(g,h,i)perylene
ug/L
50
51.8
104
48-140
Benzo(k)fluoranthene
ug/L
50
54.8
110
48-139
Benzyl alcohol
ug/L
100
68.7
69
35-130
bis(2-Chloroethoxy)methane
ug/L
50
39.1
78
34-130
bis(2-Chloroethyl) ether
ug/L
50
38.1
76
36-130
bis(2-Ethylhexyl)phthalate
ug/L
50
57.2
114
32-165
Butylbenzylphthalate
ug/L
50
64.2
128
34-161
Chlorobenzilate
ug/L
50
54.7
109
43-176
Chrysene
ug/L
50
49.1
98
47-131
Di-n-butylphthalate
ug/L
50
50.9
102
39-144
Di-n-octylphthalate
ug/L
50
53.3
107
30-170
Diallate
ug/L
50
45.8
92
33-143
Dibenz(a,h)anthracene
ug/L
50
52.7
105
49-138
Dibenzofuran
ug/L
50
46.2
92
33-130
Diethylphthalate
ug/L
50
51.1
102
38-131
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
LABORATORY CONTROL SAMPLE: 3073582
Parameter
QUALITY CONTROL DATA
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
Dimethoate
ug/L
50
43.5
87
46-173
Dimethylphthalate
ug/L
50
47.3
95
37-130
Diphenylamine
ug/L
50
49.1
98
35-135
Disulfoton
ug/L
50
41.6
83
34-139 v2
Ethyl methanesulfonate
ug/L
50
33.6
67
33-133
Famphur
ug/L
100
56.9
57
10-1301H
Fluoranthene
ug/L
50
47.5
95
46-137
Fluorene
ug/L
50
47.6
95
37-130
Hexachloro-1,3-butadiene
ug/L
50
19.0
38
11-130
Hexachlorobenzene
ug/L
50
47.9
96
38-130
Hexachlorocyclopentadiene
ug/L
50
28.7
57
10-130
Hexachloroethane
ug/L
50
14.7
29
14-130
Hexachloropropene
ug/L
50
18.7
37
10-130
Indeno(1,2,3-cd)pyrene
ug/L
50
53.7
107
41-130
Isodrin
ug/L
50
51.9
104
36-139
Isophorone
ug/L
50
41.9
84
33-130
Isosafrole
ug/L
50
39.4
79
22-130
Kepone
ug/L
100
38.8
39
10-130IL
Methapyrilene
ug/L
50
50.8
102
10-1731H,v3
Methyl methanesulfonate
ug/L
50
28.1
56
33-130
Methyl parathion
ug/L
50
56.9
114
39-200
N-Nitroso-di-n-butylamine
ug/L
50
30.1
60
22-130
N-Nitroso-di-n-propylamine
ug/L
50
42.6
85
36-130
N-Nitrosodiethylamine
ug/L
50
35.8
72
23-136
N-Nitrosodimethylamine
ug/L
50
31.1
62
34-130
N-Nitrosodiphenylamine
ug/L
50
49.1
98
37-130
N-Nitrosomethylethylamine
ug/L
50
31.7
63
18-137
N-Nitrosopiperidine
ug/L
50
42.7
85
25-142
N-Nitrosopyrrolidine
ug/L
50
38.6
77
24-146
Nitrobenzene
ug/L
50
41.3
83
36-130
O,O,O-Triethylphosphorothioate
ug/L
50
39.9
80
29-130
O-Toluidine
ug/L
50
37.7
75
27-132
P-Dimethylaminoazobenzene
ug/L
50
23.1
46
17-130IL
p-Phenylenediamine
ug/L
50
ND
0
10-130 1g,IH,L2
Parathion (Ethyl parathion)
ug/L
50
55.1
110
32-200
Pentachlorobenzene
ug/L
50
46.6
93
27-130
Pentachloronitrobenzene
ug/L
50
65.8
132
47-164
Pentachlorophenol
ug/L
100
97.0
97
23-149
Phenacetin
ug/L
50
49.9
100
44-181
Phenanthrene
ug/L
50
48.0
96
44-130
Phenol
ug/L
50
23.4
47
18-130
Phorate
ug/L
50
49.5
99
18-183
Pronamide
ug/L
50
58.0
116
45-163
Pyrene
ug/L
50
51.3
103
47-134
Safrole
ug/L
50
38.0
76
27-130
Thionazin
ug/L
50
47.3
95
36-162 v3
2,4,6-Tribromophenol (S)
%
102
10-144
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
LABORATORY CONTROL SAMPLE:
3073582
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
2-Fluorobiphenyl (S)
%
72
10-130
2-Fluorophenol(S)
%
53
10-130
Nitrobenzene-d5 (S)
%
86
10-144
Phenol-d6 (S)
%
41
10-130
Terphenyl-d14 (S)
%
119
34-163
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3073583
3073584
MS
MSD
92505728005
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result % Rec % Rec
Limits
RPD
RPD Qual
1,2,4,5-Tetrachlorobenzene
ug/L
ND
50
50
45.6
31.4
91
63
10-130
37
30 R1
1,3,5-Trinitrobenzene
ug/L
ND
50
50
65.3
53.0
131
106
50-200
21
30 v1
1,3-Dinitrobenzene
ug/L
ND
50
50
61.2
46.2
122
92
43-161
28
30
1,4-Naphthoquinone
ug/L
ND
50
50
21.5
16.0
43
32
10-184
30
30
1-Naphthalenamine
ug/L
ND
50
50
58.3
43.3
117
87
10-130
30
30
2,2'-Oxybis(1-
ug/L
ND
50
50
36.3
24.0
73
48
12-142
41
30 R1
chloropropane)
2,3,4,6-Tetrachlorophenol
ug/L
ND
50
50
51.8
42.7
104
85
10-198
19
30
2,4,5-Trichlorophenol
ug/L
ND
50
50
51.7
36.9
103
74
10-143
33
30 R1
2,4,6-Trichlorophenol
ug/L
ND
50
50
53.0
34.4
106
69
10-147
42
30 R1
2,4-Dichlorophenol
ug/L
ND
50
50
50.5
34.8
101
70
10-138
37
30 R1
2,4-Dimethylphenol
ug/L
ND
50
50
55.1
38.2
110
76
25-130
36
30 R1
2,4-Dinitrophenol
ug/L
ND
250
250
113
158
45
63
10-165
34
30 R1
2,4-Dinitrotoluene
ug/L
ND
50
50
60.6
52.9
121
106
29-148
13
30
2,6-Dichlorophenol
ug/L
ND
50
50
61.2
41.3
122
83
33-139
39
30 R1
2,6-Dinitrotoluene
ug/L
ND
50
50
60.6
43.6
121
87
26-146
33
30 R1
2-Acetylam inofl uorene
ug/L
ND
50
50
55.1
54.7
110
109
27-172
1
30
2-Chloronaphthalene
ug/L
ND
50
50
49.8
34.5
100
69
11-130
36
30 R1
2-Chlorophenol
ug/L
ND
50
50
45.5
31.5
91
63
10-133
36
30 R1
2-Methyl naphthalene
ug/L
ND
50
50
43.1
34.4
86
69
13-130
22
30
2-Methyl phenol(o-Cresol)
ug/L
ND
50
50
44.2
30.5
88
61
20-130
37
30 R1
2-Naphthalenamine
ug/L
ND
50
50
58.0
43.6
116
87
10-135
28
30
2-Nitroaniline
ug/L
ND
100
100
103
66.6
103
67
24-136
42
30 R1
2-Nitrophenol
ug/L
ND
50
50
50.3
35.3
101
71
10-153
35
30 R1
3&4-Methylphenol(m&p
ug/L
ND
50
50
49.8
33.2
100
66
16-130
40
30 R1
Cresol)
3,3'-Dichlorobenzidine
ug/L
ND
100
100
136
112
136
112
10-153
19
30
3,3'-Dimethylbenzidine
ug/L
ND
100
100
243
221
243
221
10-200
10
30 IH,MO
3-Methylcholanthrene
ug/L
ND
50
50
64.7
54.4
129
109
53-181
17
30
3-Nitroaniline
ug/L
ND
100
100
111
87.7
111
88
22-151
23
30
4,6-Dinitro-2-methylphenol
ug/L
ND
100
100
95.4
89.7
95
90
10-180
6
30
4-Aminobiphenyl
ug/L
ND
50
50
73.4
59.5
147
119
10-139
21
30 M1
4-Bromophenylphenyl ether
ug/L
ND
50
50
52.8
42.4
106
85
25-130
22
30
4-Chloro-3-methylphenol
ug/L
ND
100
100
101
72.2
101
72
25-133
33
30 R1
4-Chloroaniline
ug/L
ND
100
100
101
65.7
101
66
14-132
43
30 R1
4-Chlorophenylphenyl ether
ug/L
ND
50
50
53.0
39.1
106
78
19-130
30
30
Results presented on this page are in the units
indicated by the
"Units" column except where
an alternate unit is presented to the right of the result.
REPORT
OF LABORATORY ANALYSIS
This report shall not be reproduced,
except
in full,
Date: 11 /23/2020 04:17 PM
without
the written consent of Pace Analytical Services, LLC.
Page 46 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3073583
MS
92505728005 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3073584
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
4-Nitroaniline
ug/L
ND
100
100
118
104
118
104
29-150
13
30
4-Nitrophenol
ug/L
ND
250
250
183
200
73
80
10-130
9
30
5-Nitro-o-toluidine
ug/L
ND
50
50
63.8
51.0
128
102
48-163
22
30
7,12-
ug/L
ND
50
50
57.5
49.1
115
98
40-140
16
30
Dimethylbenz(a)anthracene
Acenaphthene
ug/L
ND
50
50
52.3
37.1
105
74
16-130
34
30 R1
Acenaphthylene
ug/L
ND
50
50
52.8
36.6
106
73
15-137
36
30 R1
Acetophenone
ug/L
ND
50
50
46.9
32.9
94
66
28-130
35
30 R1
Anthracene
ug/L
ND
50
50
49.2
44.4
98
89
37-136
10
30
Benzo(a)anth race ne
ug/L
ND
50
50
56.9
47.9
114
96
40-145
17
30
Benzo(a)pyrene
ug/L
ND
50
50
59.6
50.1
119
100
41-146
17
30
Benzo(b)fluoranthene
ug/L
ND
50
50
66.3
54.8
133
110
39-151
19
30
Benzo(g,h,i)perylene
ug/L
ND
50
50
61.7
45.1
123
90
40-147
31
30 R1
Benzo(k)fluoranthene
ug/L
ND
50
50
61.9
51.8
124
104
40-146
18
30
Benzyl alcohol
ug/L
ND
100
100
89.6
60.0
90
60
25-130
40
30 R1
bis(2-
ug/L
ND
50
50
45.2
30.8
90
62
23-130
38
30 R1
Chloroethoxy)methane
bis(2-Chloroethyl) ether
ug/L
ND
50
50
44.0
29.6
88
59
25-130
39
30 R1
bis(2- Ethyl hexyl)phthalate
ug/L
ND
50
50
62.4
53.4
125
107
28-166
16
30
Butylbenzylphthalate
ug/L
ND
50
50
75.3
63.2
151
126
33-165
18
30
Chlorobenzilate
ug/L
ND
50
50
62.3
56.3
125
113
55-170
10
30
Chrysene
ug/L
ND
50
50
55.6
46.1
111
92
38-141
19
30
Di-n-butylphthalate
ug/L
ND
50
50
56.0
50.5
112
101
32-153
10
30
Di-n-octylphthalate
ug/L
ND
50
50
58.2
53.2
116
106
30-175
9
30
Diallate
ug/L
ND
50
50
51.6
41.9
103
84
39-141
21
30
Dibenz(a,h)anthracene
ug/L
ND
50
50
62.5
46.3
125
93
39-148
30
30
Dibenzofuran
ug/L
ND
50
50
54.7
38.8
109
78
20-130
34
30 R1
Diethylphthalate
ug/L
ND
50
50
58.5
48.0
117
96
28-142
20
30
Dimethoate
ug/L
ND
50
50
49.7
44.8
99
90
57-167
10
30
Dimethylphthalate
ug/L
ND
50
50
54.7
40.1
109
80
26-136
31
30 R1
Diphenylamine
ug/L
ND
50
50
55.0
45.5
110
91
38-132
19
30
Disulfoton
ug/L
ND
50
50
47.1
39.3
94
79
40-140
18
30 v3
Ethyl methanesulfonate
ug/L
ND
50
50
41.8
28.3
84
57
38-134
38
30 R1
Famphur
ug/L
ND
100
100
54.4
50.9
54
51
10-130
7
30 IH
Fluoranthene
ug/L
ND
50
50
52.3
47.4
105
95
39-143
10
30
Fluorene
ug/L
ND
50
50
55.5
41.1
111
82
24-132
30
30
Hexachloro-1,3-butadiene
ug/L
ND
50
50
18.3
23.1
37
46
10-130
23
30
Hexachlorobenzene
ug/L
ND
50
50
52.9
45.1
106
90
29-130
16
30
Hexachlorocyclopentadiene
ug/L
ND
50
50
37.5
28.7
75
57
10-130
26
30
Hexachloroethane
ug/L
ND
50
50
9.01
13.6
18
27
10-130
30
Hexachloropropene
ug/L
ND
50
50
26.2
31.1
52
62
10-130
17
30
Indeno(1,2,3-cd)pyrene
ug/L
ND
50
50
62.9
47.1
126
94
39-148
29
30
Isodrin
ug/L
ND
50
50
55.5
50.9
111
102
45-138
8
30
Isophorone
ug/L
ND
50
50
49.5
33.2
99
66
23-130
39
30 R1
Isosafrole
ug/L
ND
50
50
49.4
32.8
99
66
25-130
41
30 R1
Kepone
ug/L
ND
100
100
32.0
31.1
32
31
10-130
3
30 IL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC.
Page 47 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3073583 3073584
Parameter Units
Methapyrilene ug/L
Methyl methanesulfonate
ug/L
Methyl parathion
ug/L
N-Nitroso-di-n-butylamine
ug/L
N-Nitroso-di-n-propylamine
ug/L
N-Nitrosodiethylamine
ug/L
N-Nitrosodimethylamine
ug/L
N-Nitrosodiphenylamine
ug/L
N-Nitrosomethylethylamine
ug/L
N-Nitrosopiperidine
ug/L
N-Nitrosopyrrolidine
ug/L
Nitrobenzene
ug/L
0,0,0-
ug/L
Triethylphosphorothioate
O-Toluidine
ug/L
P-
ug/L
Dimethylaminoazobenzene
p-Phenylenediamine
ug/L
Parathion (Ethyl parathion)
ug/L
Pentachlorobenzene
ug/L
Pentachloronitrobenzene
ug/L
Pentachlorophenol
ug/L
Phenacetin
ug/L
Phenanthrene
ug/L
Phenol
ug/L
Phorate
ug/L
Pronamide
ug/L
Pyrene
ug/L
Safrole
ug/L
Thionazin
ug/L
2,4,6-Tribromophenol (S)
%
2-Fluorobiphenyl (S)
%
2-Fluorophenol (S)
%
Nitrobenzene-d5 (S)
%
Phenol-d6 (S)
%
Terphenyl-d14 (S)
%
MS
MSD
92505728005
Spike
Spike
MS
MSD
Result
Conc.
Conc.
Result
Result
ND
50
50
79.1
94.1
ND
50
50
36.4
25.2
ND
50
50
64.5
64.4
ND
50
50
37.5
25.0
ND
50
50
49.8
32.1
ND
50
50
44.7
29.8
ND
50
50
41.7
27.9
ND
50
50
55.0
45.5
ND
50
50
41.3
26.4
ND
50
50
52.7
35.6
ND
50
50
51.6
32.8
ND
50
50
46.8
32.2
ND
50
50
49.1
34.0
ND
50
50
46.1
30.7
ND
50
50
27.0
24.4
ND
50
50
ND
ND
ND
50
50
61.7
72.4
ND
50
50
57.1
40.6
ND
50
50
76.6
62.6
ND
100
100
108
89.7
ND
50
50
60.0
48.7
ND
50
50
53.2
45.2
ND
50
50
34.1
25.3
ND
50
50
70.7
55.8
ND
50
50
66.0
58.0
ND
50
50
59.0
54.0
ND
50
50
46.5
34.7
ND
50
50
53.7
45.3
MS
% Rec
158
73
129
75
100
89
83
110
83
105
103
94
98
92
54
0
123
114
153
108
120
106
68
141
132
118
93
107
110
67
66
88
59
132
MSD % Rec
% Rec Limits
188 10-181
50 31-130
129 53-197
50 28-130
64 25-130
60 29-132
56 22-130
91 26-134
53 24-133
71 29-141
66 29-140
64 25-130
68 30-130
61 27-130
49 20-130
0 68-152
145 48-200
81 23-130
125 57-159
90 10-175
97 57-179
90 36-133
51 10-130
112 21-192
116 55-162
108 40-143
69 25-130
91 50-157
92 10-144
48 10-130
44 10-130
57 10-144
42 10-130
118 34-163
Max
RPD RPD Qual
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC.
17 30 IH,M1,
v3
36 30 R1
0 30
40 30 R1
43 30 R1
40 30 R1
40 30 R1
19 30
44 30 R1
39 30 R1
45 30 R1
37 30 R1
36 30 R1
40 30 R1
10 30 IL
30 1g,IH,
MO
16 30
34 30 R1
20 30
19 30
21 30
16 30
30 30
23 30
13 30
9 30
29 30
17 30 v3
Page 48 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
QC Batch: 581835 Analysis Method: SM 2320B-2011
QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92505711001, 92505711002
METHOD BLANK: 3077281 Matrix: Water
Associated Lab Samples: 92505711001, 92505711002
Blank Reporting
Parameter Units Result Limit
Alkalinity, Total as CaCO3 ug/L ND 5000
LABORATORY CONTROL SAMPLE: 3077282
Spike LCS
Parameter Units Conc. Result
Alkalinity, Total as CaCO3 ug/L 50000 54700
MDL Analyzed Qualifiers
5000 11 /20/20 12:38
LCS % Rec
% Rec Limits Qualifiers
109 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3077283 3077284
MS MSD
92506244004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 ug/L ND 50000 50000 53400 53200 107 106 80-120 0 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3077285 3077286
MS MSD
92506244005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 ug/L ND 50000 50000 53200 52900 106 106 80-120 1 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC.
Page 49 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
QC Batch: 580967 Analysis Method: SM 2540C-2011
QC Batch Method: SM 2540C-2011 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92505711001, 92505711002
METHOD BLANK: 3072938
Matrix:
Water
Associated Lab Samples: 92505711001, 92505711002
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
Total Dissolved Solids
ug/L
ND
25000
25000 11/17/20 15:49
LABORATORY CONTROL SAMPLE:
3072939
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Total Dissolved Solids
ug/L
251000
254000
101 90-110
SAMPLE DUPLICATE: 3072940
92505508002
Dup
Max
Parameter
Units
Result
Result
RPD RPD Qualifiers
Total Dissolved Solids
ug/L
620 mg/L
652000
5 25
SAMPLE DUPLICATE: 3072941
92505728005 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Dissolved Solids ug/L 172000 157000 9 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
QC Batch: 580668 Analysis Method: SM 4500-S2D-2011
QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92505711001, 92505711002
METHOD BLANK: 3071577 Matrix: Water
Associated Lab Samples: 92505711001, 92505711002
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Sulfide ug/L ND 100 50.0 11/17/2015:48
LABORATORY CONTROL SAMPLE: 3071578
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide ug/L 500 505 101 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3071579 3071580
MS MSD
92505505014 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide ug/L ND 500 500 545 546 105 106 80-120 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3071581 3071582
MS MSD
92505711001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide ug/L ND 500 500 114 108 23 22 80-120 5 10 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC.
Page 51 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
QC Batch: 580171 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92505711001, 92505711002
METHOD BLANK: 3068947 Matrix: Water
Associated Lab Samples: 92505711001, 92505711002
Blank Reporting
Parameter Units Result Limit
Sulfate ug/L ND 1000
LABORATORY CONTROL SAMPLE: 3068948
Spike LCS
Parameter Units Conc. Result
Sulfate ug/L 50000 51400
MDL Analyzed Qualifiers
500 11 /13/20 17:04
LCS % Rec
% Rec Limits Qualifiers
103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3068949 3068950
MS MSD
92505741001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate ug/L 171 mg/L 50000 50000 210000 223000 77 104 90-110 6 10 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3068951 3068952
MS MSD
92505711002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate ug/L ND 50000 50000 54000 54400 108 109 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC.
Page 52 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
QC Batch: 581424 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92505711001
METHOD BLANK: 3075368
Matrix:
Water
Associated Lab Samples: 92505711001
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Chloride
ug/L
ND
1000
500 11/19/20 23:57
LABORATORY CONTROL SAMPLE:
3075369
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Chloride
ug/L
20000
20600 103
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3077166 3077167
MS MSD
92505655002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride ug/L 14.8 mg/L 10000 10000 24600 24700 98 99 90-110 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3077168 3077169
MS MSD
92505655003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride ug/L 15.0 mg/L 10000 10000 25600 25500 106 105 90-110 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC.
Page 53 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
QC Batch: 581425 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92505711002
METHOD BLANK: 3075374
Matrix:
Water
Associated Lab Samples: 92505711002
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Chloride
ug/L
ND
1000
500 11/20/20 00:24
LABORATORY CONTROL SAMPLE:
3075375
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Chloride
ug/L
20000
20500 103
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3075376 3075377
MS MSD
92505711002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride ug/L ND 10000 10000 9450 9440 95 94 90-110 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3075378 3075379
MS MSD
92505728001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride ug/L 9790 10000 10000 19900 20000 101 103 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC.
Page 54 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
QC Batch: 581757 Analysis Method: SM 4500-CN-E-2011
QC Batch Method: SM 4500-CN-E-2011 Analysis Description: 450OCNE Cyanide, Total
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92505711001, 92505711002
METHOD BLANK: 3077079 Matrix: Water
Associated Lab Samples: 92505711001, 92505711002
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Cyanide ug/L ND 8.0 6.0 11/22/2013:06
LABORATORY CONTROL SAMPLE: 3077080
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Cyanide ug/L 100 100 100 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3077095 3077096
MS MSD
92505711001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Cyanide ug/L ND 100 100 72.5 63.9 71 63 80-120 13 10 M1,R1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3077097 3077098
MS MSD
92505711002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Cyanide ug/L ND 100 100 75.2 86.4 72 83 80-120 14 10 M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC.
Page 55 of 61

Pace Analytical Services, LLC
lac,
Analyilcal ® 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
www.pacelabs.com [phone]
QUALIFIERS
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
ANALYTE QUALIFIERS
1g p-Phenylenediamine is reporting with critically low recovery in the laboratory control sample(s). Results are estimated.
IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
IL This analyte exceeded secondary source verification criteria low for the initial calibration. The reported results should be
considered an estimated value.
L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.
L2 Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.
MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
P9 RPD between the primary and confirmatory analysis exceeded 40%.
R1 RPD value was outside control limits.
SO Surrogate recovery outside laboratory control limits.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
REPORT OF LABORATORY ANALYSIS
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leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: Burke Co. Johns R Background
Pace Project No.: 92505711
ANALYTE QUALIFIERS
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 57 of 61

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Burke Co. Johns R Background
92505711
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92505711001
1203-MW21
8151A
1577499
EPA8151
1577499
92505711002
1203-FIELD
BLANK
8151A
1577499
EPA8151
1577499
92505711001
1203-MW21
EPA 3510C
580717
EPA 8081 B
581192
92505711002
1203-FIELD
BLANK
EPA 3510C
580717
EPA 8081 B
581192
92505711001
1203-MW21
EPA 3510C
580445
EPA 8082A
580760
92505711002
1203-FIELD
BLANK
EPA 3510C
580445
EPA 8082A
580760
92505711001
1203-MW21
EPA 3010A
580091
EPA 6010D
580106
92505711002
1203-FIELD
BLANK
EPA 3010A
580091
EPA6010D
580106
92505711001
1203-MW21
EPA 3010A
580093
EPA 6020B
580104
92505711002
1203-FIELD
BLANK
EPA 3010A
580093
EPA 6020B
580104
92505711001
1203-MW21
EPA 7470A
580216
EPA 7470A
580275
92505711002
1203-FIELD
BLANK
EPA 7470A
580216
EPA 7470A
580275
92505711001
1203-MW21
EPA 3510C
581129
EPA 8270E
581697
92505711002
1203-FIELD
BLANK
EPA 3510C
581129
EPA 8270E
581697
92505711001
1203-MW21
EPA 8260D
580628
92505711002
1203-FIELD
BLANK
EPA 8260D
580552
92505711003
TRIP BLANK
EPA 8260D
580628
92505711001
1203-MW21
EPA 8260D Mod.
580296
92505711002
1203-FIELD
BLANK
EPA 8260D Mod.
580296
92505711003
TRIP BLANK
EPA 8260D Mod.
580296
92505711001
1203-MW21
SM 2320B-2011
581835
92505711002
1203-FIELD
BLANK
SM 2320B-2011
581835
92505711001
1203-MW21
SM 2540C-2011
580967
92505711002
1203-FIELD
BLANK
SM 2540C-2011
580967
92505711001
1203-MW21
SM 4500-S2D-2011
580668
92505711002
1203-FIELD
BLANK
SM 4500-S2D-2011
580668
92505711001
1203-MW21
EPA 300.0 Rev 2.1 1993
580171
92505711002
1203-FIELD
BLANK
EPA 300.0 Rev 2.1 1993
580171
92505711001
1203-MW21
SM 4500-CI-E-2011
581424
92505711002
1203-FIELD
BLANK
SM 4500-CI-E-2011
581425
92505711001
1203-MW21
SM 4500-CN-E-2011
581757
SM 4500-CN-E-2011
582089
92505711002
1203-FIELD
BLANK
SM 4500-CN-E-2011
581757
SM 4500-CN-E-2011
582089
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 58 of 61

/ :l"c1C�Analytical Document No.:
F-CAR•CS-033-Rev, 07
Issuing Authority:
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Ec1en❑ Greenwood ❑ Huntersville Raleigh[]Mechanicsville❑ Atlanta[]Kernersvillai�
SampleCondition Client Name; WO# : 92505711
Upon • • • • Project #:
Courier: ❑Fed Ex ❑UPS ❑USPS --]Client
❑ Commercial ❑i isace ❑Other: 92*�06711
Custody Seal Present? ❑Yes ❑No Seals Intact? []Yes ❑60 I
t7ate/Initials Person Examining Contents: L-{
ut10
Packing Material: UBuobie wrap LLJnuuuie ❑dg�- ui'ouIit: t�J .
[]yes -[:]No [3-NIA
Thermometer: [3 et [-]Blue ❑None
❑ IR Gun ID: 92TO61 Type of Ice:
1 � 1 `4 Correction Factor:
Cooler Temp: L` _� + Add/Subtract Faor: 0.0 Temp should be above freezing to VC
• ❑Samples out of temp criteria. Samples an ice, coaling process
Cooler Temp Corrected ('Cl: V1 has begun
USDA Regulated Soil ( �N/A, water sample)
Did samples originate In a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally,
[]Yes []No including Hawaii and Puerto Rico)? []Yes []No
Comments/Discrepancy:
Chain of Custody Present?
Samples Arrived within Hold Time?
Short Hold Time Analysis (<72 hr.)?
Rush Turn Around Time Requested?
Sufficient Volume7
Correct Containers Used?
-Pace Containers Used?
Containers Intact?
Dissolved analysis: Samples Field Filtered?
Sample Labels Match COC?
-Includes Date/Time/ID/Analysis
Headspace in VOA Vials (>5-6mm)?
Trip Blank Present?
Trio Blank Custody Seals Present?
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RE50LLITION
Person contacted:
Project Manager SCURF Review:
Project Manager SRF Review:
[311es
ONO
❑N/A 1
1.
�res
❑NO
❑N/A
2.
[]Yes
096
❑N/A
3.
[]Yes
Oiqa
❑N/A
4.
QYes
❑No
[]N/A
5.
QYes
[]NO
(-]N/A
6.
ores
[:]No
❑N/A
❑iYes
[]NO
E�]N/A
7.
❑yes
[]No
I-HN/A
8.
❑Y�i!s
❑No
[]NIA
9.
3
N/A la.
N/A 11.
Lot ID of split containers:
Date/Time:
Date:
Date:
Field Data Required? Oyes (:]No
Page 59 of 61

Document No.:
F-CAR-CS-033-Rev.07
Issuing Authority:
n...,, r.,,,h. nL llt" rlffiro
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
Samples.
Exceptions; VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
"Bottom half of box is to list number of bottles
Project # WO# : 92505711
Phi: NMG Due Date; 11/30/20
CLIENT: 92-Joyete Eno
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Dote: wnenever mere Is a fflscrepancy arrecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNA Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 60 of 61
Dote: wnenever mere Is a fflscrepancy arrecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNA Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 60 of 61

0
CHAIN -OF -CUSTODY ! Analytical Request Document
ceAnalytical
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
co
Section A
Section B
Section C Page : 1
of 1
Required Client information:
Required Project information:
Invoice Information:
Company. La Bella Associates
Report To, Van Burbach
Attention_ Lecia Jones
Address 2211 West Meadowview Rd
Copy To Miguel Vazquez
company Name: La Bella Associates
Greensboro, NC 27407
AddresS 1604 Ownby Lane, Richmond. VA 23220
Regulatory Agency
Email To: vburbach(a)[e-mail]
Purchase Order No. 2202300.00.02
Pace Quote Reference.
Phone. [phone] Fax:
Client Project ID, Burke Co. Johns R Background
Pace Project Manager. Nicole Gaslorowski
State I Location
Requested Due DatufTAT: 10 Day (Default)
ConlainLr Order Number.
Pace Profile it 2327-7
North Carolina
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leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
November 22, 2020
Mr. Van Burbach
Joyce Engineering -Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on November 12, 2020. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
/7j"4w'
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Van Burbach, Joyce Engineering -NC
Gretta Eller, LaBella Associates, D.P.C.
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 29

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 29

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92505868001
1203-SMP5
Water
11/11/20 08:17
11/12/20 09:51
92505868002
1203-SMP6
Water
11/11/20 13:16
11/12/20 09:51
92505868003
1203-SMP7
Water
11/11/20 13:06
11/12/20 09:51
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 29

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
92505868001 1203-SMP5
EPA 8081 B
SEM
4
PASI-C
EPA 601 OD
BG2
19
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
CL
53
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
SM 4500-CN-E-2011
CJL
1
PASI-A
92505868002 1203-SMP6
EPA 8081 B
SEM
4
PASI-C
EPA 601 OD
BG2
19
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
CL
53
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
SM 4500-CN-E-2011
CJL
1
PASI-A
92505868003 1203-SMP7
EPA 8081 B
SEM
4
PASI-C
EPA 601 OD
BG2
19
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
CL
53
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
SM 4500-CN-E-2011
CJL
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 29

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
Johns R. - SURFACE WATER
92505868
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92505868001
1203-SMP5
EPA 6010D
Barium
20.3
ug/L
5.0
11/15/20 22:05
EPA 6010D
Iron
4550
ug/L
50.0
11/15/20 22:05
EPA 6010D
Magnesium
1820
ug/L
100
11/15/20 22:05
EPA 6010D
Manganese
72.2
ug/L
5.0
11/15/20 22:05
EPA 6010D
Hardness, Total(SM 2340B)
16900
ug/L
662
11/15/20 22:05
EPA 6010D
Vanadium
12.0
ug/L
5.0
11/15/20 22:05
92505868002
1203-SMP6
EPA 6010D
Barium
38.5
ug/L
5.0
11/15/20 22:25
EPA 6010D
Chromium
4.7J
ug/L
5.0
11/15/20 22:25
EPA 6010D
Cobalt
4.1 J
ug/L
5.0
11/15/20 22:25
EPA 6010D
Copper
5.7
ug/L
5.0
11/15/20 22:25
EPA 6010D
Iron
7270
ug/L
50.0
11/15/20 22:25
EPA 6010D
Lead
5.4
ug/L
5.0
11/15/20 22:25
EPA 6010D
Magnesium
1320
ug/L
100
11/15/20 22:25
EPA 6010D
Manganese
231
ug/L
5.0
11/15/20 22:25
EPA 6010D
Hardness, Total(SM 2340B)
14600
ug/L
662
11/15/20 22:25
EPA 6010D
Vanadium
14.6
ug/L
5.0
11/15/20 22:25
EPA 6020B
Thallium
0.076J
ug/L
0.10
11/18/20 23:11
92505868003
1203-SMP7
EPA 6010D
Barium
52.5
ug/L
5.0
11/15/20 22:28
EPA 6010D
Chromium
8.0
ug/L
5.0
11/15/20 22:28
EPA 6010D
Cobalt
5.3
ug/L
5.0
11/15/20 22:28
EPA 6010D
Copper
10.6
ug/L
5.0
11/15/20 22:28
EPA 6010D
Iron
9650
ug/L
50.0
11/15/20 22:28
EPA 6010D
Lead
9.9
ug/L
5.0
11/15/20 22:28
EPA 6010D
Magnesium
2040
ug/L
100
11/15/20 22:28
EPA 6010D
Manganese
154
ug/L
5.0
11/15/20 22:28
EPA 6010D
Nickel
4.2J
ug/L
5.0
11/15/20 22:28
EPA 6010D
Hardness, Total(SM 2340B)
20800
ug/L
662
11/15/20 22:28
EPA 6010D
Vanadium
22.5
ug/L
5.0
11/15/20 22:28
EPA 6010D
Zinc
18.4
ug/L
10.0
11/15/20 22:28
EPA 6020B
Thallium
0.12
ug/L
0.10
11/18/20 23:30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 5 of 29

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
Sample: 1203-SMP5
Lab ID:
92505868001
Collected:
11/11/20 08:17
Received: 11/12/20 09:51 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
8081 OC Pesticides RVE
Analytical
Method: EPA 8081 B Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
alpha-BHC
ND
ug/L
0.050
0.019
1
11/18/2018:40
11/19/2012:36
319-84-6
beta-BHC
ND
ug/L
0.050
0.014
1
11/18/20 18:40
11/19/20 12:36
319-85-7
Surrogates
Tetrachloro-m-xylene (S)
66
%
10-184
1
11/18/20 18:40
11/19/20 12:36
877-09-8
Decachlorobiphenyl (S)
99
%
10-154
1
11/18/20 18:40
11/19/20 12:36
2051-24-3
6010 MET ICP
Analytical
Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical
Services
-Asheville
Antimony
ND
ug/L
5.0
3.0
1
11/14/20 00:58
11/15/20 22:05
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
11/14/20 00:58
11/15/20 22:05
7440-38-2
Barium
20.3
ug/L
5.0
3.5
1
11/14/20 00:58
11/15/20 22:05
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
11/14/20 00:58
11/15/20 22:05
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
11/14/20 00:58
11/15/20 22:05
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
11/14/20 00:58
11/15/20 22:05
7440-47-3
Cobalt
ND
ug/L
5.0
3.6
1
11/14/20 00:58
11/15/20 22:05
7440-48-4
Copper
ND
ug/L
5.0
4.3
1
11/14/20 00:58
11/15/20 22:05
7440-50-8
Iron
4550
ug/L
50.0
41.5
1
11/14/20 00:58
11/15/20 22:05
7439-89-6
Lead
ND
ug/L
5.0
4.5
1
11/14/20 00:58
11/15/20 22:05
7439-92-1
Magnesium
1820
ug/L
100
67.8
1
11/14/20 00:58
11/15/20 22:05
7439-95-4
Manganese
72.2
ug/L
5.0
3.4
1
11/14/20 00:58
11/15/20 22:05
7439-96-5
Nickel
ND
ug/L
5.0
3.5
1
11/14/20 00:58
11/15/20 22:05
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
11/14/20 00:58
11/15/20 22:05
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
11/14/20 00:58
11/15/20 22:05
7440-22-4
Tin
ND
ug/L
5.0
4.7
1
11/14/20 00:58
11/15/20 22:05
7440-31-5
Hardness, Total(SM 2340B)
16900
ug/L
662
131
1
11/14/20 00:58
11/15/20 22:05
Vanadium
12.0
ug/L
5.0
3.9
1
11/14/20 00:58
11/15/20 22:05
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
11/14/20 00:58
11/15/20 22:05
7440-66-6
6020 MET ICPMS
Thallium
8260D MSV Low Level Landfill
Acetone
Acetonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Date: 11/22/2020 04:30 PM
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
ND ug/L 0.10 0.050 1 11/14/20 00:54 11/18/20 23:00 7440-28-0
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
ND
ug/L
50.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
6.2
1
11/17/20 01:29
67-64-1
30.4
1
11/17/20 01:29
75-05-8
0.15
1
11/17/20 01:29
71-43-2
0.34
1
11/17/20 01:29
74-97-5
0.26
1
11/17/20 01:29
75-27-4
0.62
1
11/17/20 01:29
75-25-2
0.62
1
11/17/20 01:29
74-83-9
3.3
1
11/17/20 01:29
78-93-3
0.40
1
11/17/20 01:29
75-15-0
0.22
1
11/17/20 01:29
56-23-5
0.23
1
11/17/20 01:29
108-90-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 29

leAnalyiical
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ANALYTICAL RESULTS
Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
Sample: 1203-SMP5 Lab ID: 92505868001 Collected: 11/11/20 08:17 Received: 11/12/20 09:51 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Isobutanol
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 11/22/2020 04:30 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.49
1
11/17/20 01:29
75-00-3
ND
ug/L
5.0
2.3
1
11/17/20 01:29
67-66-3
ND
ug/L
1.0
0.39
1
11/17/20 01:29
74-87-3
ND
ug/L
5.0
0.26
1
11/17/20 01:29
96-12-8
ND
ug/L
1.0
0.41
1
11/17/20 01:29
124-48-1
ND
ug/L
1.0
0.26
1
11/17/20 01:29
106-93-4
ND
ug/L
1.0
0.46
1
11/17/20 01:29
74-95-3
ND
ug/L
1.0
0.29
1
11/17/20 01:29
95-50-1
ND
ug/L
1.0
0.26
1
11/17/20 01:29
106-46-7
ND
ug/L
1.0
0.54
1
11/17/20 01:29
110-57-6
ND
ug/L
1.0
0.23
1
11/17/20 01:29
75-71-8
ND
ug/L
1.0
0.27
1
11/17/20 01:29
75-34-3
ND
ug/L
1.0
0.34
1
11/17/20 01:29
107-06-2
ND
ug/L
1.0
0.24
1
11/17/20 01:29
75-35-4
ND
ug/L
1.0
0.29
1
11/17/20 01:29
156-59-2
ND
ug/L
1.0
0.25
1
11/17/20 01:29
156-60-5
ND
ug/L
1.0
0.19
1
11/17/20 01:29
78-87-5
ND
ug/L
1.0
0.30
1
11/17/20 01:29
10061-01-5
ND
ug/L
1.0
0.31
1
11/17/20 01:29
10061-02-6
ND
ug/L
1.0
0.26
1
11/17/20 01:29
100-41-4
ND
ug/L
5.0
0.57
1
11/17/20 01:29
591-78-6
ND
ug/L
20.0
12.5
1
11/17/20 01:29
74-88-4 IK
ND
ug/L
100
66.4
1
11/17/20 01:29
78-83-1
ND
ug/L
5.0
3.7
1
11/17/20 01:29
75-09-2
ND
ug/L
5.0
4.5
1
11/17/20 01:29
108-10-1
ND
ug/L
1.0
0.27
1
11/17/20 01:29
100-42-5
ND
ug/L
1.0
0.34
1
11/17/20 01:29
630-20-6
ND
ug/L
1.0
0.22
1
11/17/20 01:29
79-34-5
ND
ug/L
1.0
0.16
1
11/17/20 01:29
127-18-4
ND
ug/L
10.0
1.9
1
11/17/20 01:29
109-99-9
ND
ug/L
1.0
0.24
1
11/17/20 01:29
108-88-3
ND
ug/L
1.0
0.18
1
11/17/20 01:29
71-55-6
ND
ug/L
1.0
0.24
1
11/17/20 01:29
79-00-5
ND
ug/L
1.0
0.22
1
11/17/20 01:29
79-01-6
ND
ug/L
1.0
0.31
1
11/17/20 01:29
75-69-4
ND
ug/L
1.0
0.35
1
11/17/20 01:29
96-18-4
ND
ug/L
2.0
1.4
1
11/17/20 01:29
108-05-4
ND
ug/L
1.0
0.24
1
11/17/20 01:29
75-01-4
ND
ug/L
1.0
0.63
1
11/17/20 01:29
1330-20-7
97
%
70-130
1
11/17/20 01:29
460-00-4
109
%
70-130
1
11/17/20 01:29
17060-07-0
101
%
70-130
1
11/17/20 01:29
2037-26-5
REPORT
OF LABORATORY ANALYSIS
This report shall not be reproduced,
except in full,
without the written
consent of Pace
Analytical Services, LLC.
Page 7 of 29

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
Sample: 1203-SMP5
Lab ID: 92505868001 Collected:
11/11/20 08:17
Received: 11/12/20 09:51 Matrix: Water
Report
Parameters
Results Units Limit
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV SIM
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1,4-Dioxane (p-Dioxane)
ND ug/L 2.0
1.2 1
11/14/20 04:22
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
99 % 70-130
1
11/14/20 04:22
17060-07-0
Toluene-d8 (S)
86 % 66-133
1
11/14/20 04:22
2037-26-5
4500CNE Cyanide, Total
Analytical Method: SM 4500-CN-E-2011 Preparation Method:
SM 4500-CN-E-2011
Pace Analytical Services -Asheville
Cyanide
ND ug/L 8.0
6.0 1
11/20/20 21:21 11/22/20 13:29
57-12-5
Date: 11/22/2020 04:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 29

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
Sample: 1203-SMP6
Lab ID:
92505868002
Collected:
11/11/20 13:16
Received: 11/12/20 09:51 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
8081 OC Pesticides RVE
Analytical
Method: EPA 8081 B Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
alpha-BHC
ND
ug/L
0.050
0.019
1
11/18/2018:40
11/19/2012:47
319-84-6
beta-BHC
ND
ug/L
0.050
0.014
1
11/18/20 18:40
11/19/20 12:47
319-85-7
Surrogates
Tetrachloro-m-xylene (S)
37
%
10-184
1
11/18/20 18:40
11/19/20 12:47
877-09-8
Decachlorobiphenyl (S)
64
%
10-154
1
11/18/20 18:40
11/19/20 12:47
2051-24-3
6010 MET ICP
Analytical
Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical
Services
-Asheville
Antimony
ND
ug/L
5.0
3.0
1
11/14/20 00:58
11/15/20 22:25
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
11/14/20 00:58
11/15/20 22:25
7440-38-2
Barium
38.5
ug/L
5.0
3.5
1
11/14/20 00:58
11/15/20 22:25
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
11/14/20 00:58
11/15/20 22:25
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
11/14/20 00:58
11/15/20 22:25
7440-43-9
Chromium
4.7J
ug/L
5.0
3.7
1
11/14/20 00:58
11/15/20 22:25
7440-47-3
Cobalt
4.1J
ug/L
5.0
3.6
1
11/14/20 00:58
11/15/20 22:25
7440-48-4
Copper
5.7
ug/L
5.0
4.3
1
11/14/20 00:58
11/15/20 22:25
7440-50-8
Iron
7270
ug/L
50.0
41.5
1
11/14/20 00:58
11/15/20 22:25
7439-89-6
Lead
5.4
ug/L
5.0
4.5
1
11/14/20 00:58
11/15/20 22:25
7439-92-1
Magnesium
1320
ug/L
100
67.8
1
11/14/20 00:58
11/15/20 22:25
7439-95-4
Manganese
231
ug/L
5.0
3.4
1
11/14/20 00:58
11/15/20 22:25
7439-96-5
Nickel
ND
ug/L
5.0
3.5
1
11/14/20 00:58
11/15/20 22:25
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
11/14/20 00:58
11/15/20 22:25
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
11/14/20 00:58
11/15/20 22:25
7440-22-4
Tin
ND
ug/L
5.0
4.7
1
11/14/20 00:58
11/15/20 22:25
7440-31-5
Hardness, Total(SM 2340B)
14600
ug/L
662
131
1
11/14/20 00:58
11/15/20 22:25
Vanadium
14.6
ug/L
5.0
3.9
1
11/14/20 00:58
11/15/20 22:25
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
11/14/20 00:58
11/15/20 22:25
7440-66-6
6020 MET ICPMS
Thallium
8260D MSV Low Level Landfill
Acetone
Acetonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Date: 11/22/2020 04:30 PM
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
0.076J ug/L 0.10 0.050 1 11/14/20 00:54 11/18/20 23:11 7440-28-0
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
ND
ug/L
50.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
6.2
1
11/17/20 01:47
67-64-1
30.4
1
11/17/20 01:47
75-05-8
0.15
1
11/17/20 01:47
71-43-2
0.34
1
11/17/20 01:47
74-97-5
0.26
1
11/17/20 01:47
75-27-4
0.62
1
11/17/20 01:47
75-25-2
0.62
1
11/17/20 01:47
74-83-9
3.3
1
11/17/20 01:47
78-93-3
0.40
1
11/17/20 01:47
75-15-0
0.22
1
11/17/20 01:47
56-23-5
0.23
1
11/17/20 01:47
108-90-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 29

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
Sample: 1203-SMP6 Lab ID: 92505868002 Collected: 11/11/20 13:16 Received: 11/12/20 09:51 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Isobutanol
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 11/22/2020 04:30 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.49
1
11/17/20 01:47
75-00-3
ND
ug/L
5.0
2.3
1
11/17/20 01:47
67-66-3
ND
ug/L
1.0
0.39
1
11/17/20 01:47
74-87-3
ND
ug/L
5.0
0.26
1
11/17/20 01:47
96-12-8
ND
ug/L
1.0
0.41
1
11/17/20 01:47
124-48-1
ND
ug/L
1.0
0.26
1
11/17/20 01:47
106-93-4
ND
ug/L
1.0
0.46
1
11/17/20 01:47
74-95-3
ND
ug/L
1.0
0.29
1
11/17/20 01:47
95-50-1
ND
ug/L
1.0
0.26
1
11/17/20 01:47
106-46-7
ND
ug/L
1.0
0.54
1
11/17/20 01:47
110-57-6
ND
ug/L
1.0
0.23
1
11/17/20 01:47
75-71-8
ND
ug/L
1.0
0.27
1
11/17/20 01:47
75-34-3
ND
ug/L
1.0
0.34
1
11/17/20 01:47
107-06-2
ND
ug/L
1.0
0.24
1
11/17/20 01:47
75-35-4
ND
ug/L
1.0
0.29
1
11/17/20 01:47
156-59-2
ND
ug/L
1.0
0.25
1
11/17/20 01:47
156-60-5
ND
ug/L
1.0
0.19
1
11/17/20 01:47
78-87-5
ND
ug/L
1.0
0.30
1
11/17/20 01:47
10061-01-5
ND
ug/L
1.0
0.31
1
11/17/20 01:47
10061-02-6
ND
ug/L
1.0
0.26
1
11/17/20 01:47
100-41-4
ND
ug/L
5.0
0.57
1
11/17/20 01:47
591-78-6
ND
ug/L
20.0
12.5
1
11/17/20 01:47
74-88-4 IK
ND
ug/L
100
66.4
1
11/17/20 01:47
78-83-1
ND
ug/L
5.0
3.7
1
11/17/20 01:47
75-09-2
ND
ug/L
5.0
4.5
1
11/17/20 01:47
108-10-1
ND
ug/L
1.0
0.27
1
11/17/20 01:47
100-42-5
ND
ug/L
1.0
0.34
1
11/17/20 01:47
630-20-6
ND
ug/L
1.0
0.22
1
11/17/20 01:47
79-34-5
ND
ug/L
1.0
0.16
1
11/17/20 01:47
127-18-4
ND
ug/L
10.0
1.9
1
11/17/20 01:47
109-99-9
ND
ug/L
1.0
0.24
1
11/17/20 01:47
108-88-3
ND
ug/L
1.0
0.18
1
11/17/20 01:47
71-55-6
ND
ug/L
1.0
0.24
1
11/17/20 01:47
79-00-5
ND
ug/L
1.0
0.22
1
11/17/20 01:47
79-01-6
ND
ug/L
1.0
0.31
1
11/17/20 01:47
75-69-4
ND
ug/L
1.0
0.35
1
11/17/20 01:47
96-18-4
ND
ug/L
2.0
1.4
1
11/17/20 01:47
108-05-4
ND
ug/L
1.0
0.24
1
11/17/20 01:47
75-01-4
ND
ug/L
1.0
0.63
1
11/17/20 01:47
1330-20-7
102
%
70-130
1
11/17/20 01:47
460-00-4
108
%
70-130
1
11/17/20 01:47
17060-07-0
103
%
70-130
1
11/17/20 01:47
2037-26-5
REPORT
OF LABORATORY ANALYSIS
This report shall not be reproduced,
except in full,
without the written
consent of Pace
Analytical Services, LLC.
Page 10 of 29

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
Sample: 1203-SMP6
Lab ID: 92505868002 Collected:
11/11/20 13:16
Received: 11/12/20 09:51 Matrix: Water
Report
Parameters
Results Units Limit
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV SIM
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1,4-Dioxane (p-Dioxane)
ND ug/L 2.0
1.2 1
11/14/20 04:41
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
100 % 70-130
1
11/14/20 04:41
17060-07-0
Toluene-d8 (S)
86 % 66-133
1
11/14/20 04:41
2037-26-5
450OCNE Cyanide, Total
Analytical Method: SM 4500-CN-E-2011 Preparation Method:
SM 4500-CN-E-2011
Pace Analytical Services -Asheville
Cyanide
ND ug/L 8.0
6.0 1
11/20/20 21:21 11/22/20 13:30
57-12-5
Date: 11/22/2020 04:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 29

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
Sample: 1203-SMP7
Lab ID:
92505868003
Collected:
11/11/20 13:06
Received: 11/12/20 09:51 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
8081 OC Pesticides RVE
Analytical
Method: EPA 8081 B Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
alpha-BHC
ND
ug/L
0.050
0.019
1
11/18/2018:40
11/19/2012:59
319-84-6
beta-BHC
ND
ug/L
0.050
0.014
1
11/18/20 18:40
11/19/20 12:59
319-85-7
Surrogates
Tetrachloro-m-xylene (S)
76
%
10-184
1
11/18/20 18:40
11/19/20 12:59
877-09-8
Decachlorobiphenyl (S)
105
%
10-154
1
11/18/20 18:40
11/19/20 12:59
2051-24-3
6010 MET ICP
Analytical
Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical
Services
-Asheville
Antimony
ND
ug/L
5.0
3.0
1
11/14/20 00:58
11/15/20 22:28
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
11/14/20 00:58
11/15/20 22:28
7440-38-2
Barium
52.5
ug/L
5.0
3.5
1
11/14/20 00:58
11/15/20 22:28
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
11/14/20 00:58
11/15/20 22:28
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
11/14/20 00:58
11/15/20 22:28
7440-43-9
Chromium
8.0
ug/L
5.0
3.7
1
11/14/20 00:58
11/15/20 22:28
7440-47-3
Cobalt
5.3
ug/L
5.0
3.6
1
11/14/20 00:58
11/15/20 22:28
7440-48-4
Copper
10.6
ug/L
5.0
4.3
1
11/14/20 00:58
11/15/20 22:28
7440-50-8
Iron
9650
ug/L
50.0
41.5
1
11/14/20 00:58
11/15/20 22:28
7439-89-6
Lead
9.9
ug/L
5.0
4.5
1
11/14/20 00:58
11/15/20 22:28
7439-92-1
Magnesium
2040
ug/L
100
67.8
1
11/14/20 00:58
11/15/20 22:28
7439-95-4
Manganese
154
ug/L
5.0
3.4
1
11/14/20 00:58
11/15/20 22:28
7439-96-5
Nickel
4.2J
ug/L
5.0
3.5
1
11/14/20 00:58
11/15/20 22:28
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
11/14/20 00:58
11/15/20 22:28
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
11/14/20 00:58
11/15/20 22:28
7440-22-4
Tin
ND
ug/L
5.0
4.7
1
11/14/20 00:58
11/15/20 22:28
7440-31-5
Hardness, Total(SM 2340B)
20800
ug/L
662
131
1
11/14/20 00:58
11/15/20 22:28
Vanadium
22.5
ug/L
5.0
3.9
1
11/14/20 00:58
11/15/20 22:28
7440-62-2
Zinc
18.4
ug/L
10.0
9.5
1
11/14/20 00:58
11/15/20 22:28
7440-66-6
6020 MET ICPMS
Thallium
8260D MSV Low Level Landfill
Acetone
Acetonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Date: 11/22/2020 04:30 PM
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
0.12 ug/L 0.10 0.050 1 11/14/20 00:54 11/18/20 23:30 7440-28-0
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
ND
ug/L
50.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
6.2
1
11/17/20 02:05
67-64-1
30.4
1
11/17/20 02:05
75-05-8
0.15
1
11/17/20 02:05
71-43-2
0.34
1
11/17/20 02:05
74-97-5
0.26
1
11/17/20 02:05
75-27-4
0.62
1
11/17/20 02:05
75-25-2
0.62
1
11/17/20 02:05
74-83-9
3.3
1
11/17/20 02:05
78-93-3
0.40
1
11/17/20 02:05
75-15-0
0.22
1
11/17/20 02:05
56-23-5
0.23
1
11/17/20 02:05
108-90-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 29

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[phone]
ANALYTICAL RESULTS
Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
Sample: 1203-SMP7 Lab ID: 92505868003 Collected: 11/11/20 13:06 Received: 11/12/20 09:51 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Isobutanol
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 11/22/2020 04:30 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.49
1
11/17/20 02:05
75-00-3
ND
ug/L
5.0
2.3
1
11/17/20 02:05
67-66-3
ND
ug/L
1.0
0.39
1
11/17/20 02:05
74-87-3
ND
ug/L
5.0
0.26
1
11/17/20 02:05
96-12-8
ND
ug/L
1.0
0.41
1
11/17/20 02:05
124-48-1
ND
ug/L
1.0
0.26
1
11/17/20 02:05
106-93-4
ND
ug/L
1.0
0.46
1
11/17/20 02:05
74-95-3
ND
ug/L
1.0
0.29
1
11/17/20 02:05
95-50-1
ND
ug/L
1.0
0.26
1
11/17/20 02:05
106-46-7
ND
ug/L
1.0
0.54
1
11/17/20 02:05
110-57-6
ND
ug/L
1.0
0.23
1
11/17/20 02:05
75-71-8
ND
ug/L
1.0
0.27
1
11/17/20 02:05
75-34-3
ND
ug/L
1.0
0.34
1
11/17/20 02:05
107-06-2
ND
ug/L
1.0
0.24
1
11/17/20 02:05
75-35-4
ND
ug/L
1.0
0.29
1
11/17/20 02:05
156-59-2
ND
ug/L
1.0
0.25
1
11/17/20 02:05
156-60-5
ND
ug/L
1.0
0.19
1
11/17/20 02:05
78-87-5
ND
ug/L
1.0
0.30
1
11/17/20 02:05
10061-01-5
ND
ug/L
1.0
0.31
1
11/17/20 02:05
10061-02-6
ND
ug/L
1.0
0.26
1
11/17/20 02:05
100-41-4
ND
ug/L
5.0
0.57
1
11/17/20 02:05
591-78-6
ND
ug/L
20.0
12.5
1
11/17/20 02:05
74-88-4 IK
ND
ug/L
100
66.4
1
11/17/20 02:05
78-83-1
ND
ug/L
5.0
3.7
1
11/17/20 02:05
75-09-2
ND
ug/L
5.0
4.5
1
11/17/20 02:05
108-10-1
ND
ug/L
1.0
0.27
1
11/17/20 02:05
100-42-5
ND
ug/L
1.0
0.34
1
11/17/20 02:05
630-20-6
ND
ug/L
1.0
0.22
1
11/17/20 02:05
79-34-5
ND
ug/L
1.0
0.16
1
11/17/20 02:05
127-18-4
ND
ug/L
10.0
1.9
1
11/17/20 02:05
109-99-9
ND
ug/L
1.0
0.24
1
11/17/20 02:05
108-88-3
ND
ug/L
1.0
0.18
1
11/17/20 02:05
71-55-6
ND
ug/L
1.0
0.24
1
11/17/20 02:05
79-00-5
ND
ug/L
1.0
0.22
1
11/17/20 02:05
79-01-6
ND
ug/L
1.0
0.31
1
11/17/20 02:05
75-69-4
ND
ug/L
1.0
0.35
1
11/17/20 02:05
96-18-4
ND
ug/L
2.0
1.4
1
11/17/20 02:05
108-05-4
ND
ug/L
1.0
0.24
1
11/17/20 02:05
75-01-4
ND
ug/L
1.0
0.63
1
11/17/20 02:05
1330-20-7
101
%
70-130
1
11/17/20 02:05
460-00-4
111
%
70-130
1
11/17/20 02:05
17060-07-0
103
%
70-130
1
11/17/20 02:05
2037-26-5
REPORT
OF LABORATORY ANALYSIS
This report shall not be reproduced,
except in full,
without the written
consent of Pace
Analytical Services, LLC.
Page 13 of 29

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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
Sample: 1203-SMP7
Lab ID: 92505868003 Collected:
11/11/20 13:06
Received: 11/12/20 09:51 Matrix: Water
Report
Parameters
Results Units Limit
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV SIM
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1,4-Dioxane (p-Dioxane)
ND ug/L 2.0
1.2 1
11/14/20 05:00
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
97 % 70-130
1
11/14/20 05:00
17060-07-0
Toluene-d8 (S)
85 % 66-133
1
11/14/20 05:00
2037-26-5
450OCNE Cyanide, Total
Analytical Method: SM 4500-CN-E-2011 Preparation Method:
SM 4500-CN-E-2011
Pace Analytical Services -Asheville
Cyanide
ND ug/L 8.0
6.0 1
11/20/20 21:21 11/22/20 13:30
57-12-5
Date: 11/22/2020 04:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 14 of 29

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
QC Batch: 580349 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92505868001, 92505868002, 92505868003
METHOD BLANK: 3070197 Matrix:
Associated Lab Samples: 92505868001, 92505868002, 92505868003
Blank
Parameter Units Result
Water
Reporting
Limit
MDL
Analyzed
Antimony
ug/L
ND
5.0
3.0
11/15/20 21:14
Arsenic
ug/L
ND
10.0
4.7
11/15/20 21:14
Barium
ug/L
ND
5.0
3.5
11/15/20 21:14
Beryllium
ug/L
ND
1.0
0.70
11/15/20 21:14
Cadmium
ug/L
ND
1.0
0.40
11/15/20 21:14
Chromium
ug/L
ND
5.0
3.7
11/15/20 21:14
Cobalt
ug/L
ND
5.0
3.6
11/15/20 21:14
Copper
ug/L
ND
5.0
4.3
11/15/20 21:14
Hardness, Total(SM 2340B)
ug/L
ND
662
131
11/15/20 21:14
Iron
ug/L
ND
50.0
41.5
11/15/20 21:14
Lead
ug/L
ND
5.0
4.5
11/15/20 21:14
Magnesium
ug/L
ND
100
67.8
11/15/20 21:14
Manganese
ug/L
ND
5.0
3.4
11/15/20 21:14
Nickel
ug/L
ND
5.0
3.5
11/15/20 21:14
Selenium
ug/L
ND
10.0
4.7
11/15/20 21:14
Silver
ug/L
ND
5.0
2.5
11/15/20 21:14
Tin
ug/L
ND
5.0
4.7
11/15/20 21:14
Vanadium
ug/L
ND
5.0
3.9
11/15/20 21:14
Zinc
ug/L
ND
10.0
9.5
11/15/20 21:14
LABORATORY CONTROL SAMPLE:
Parameter
3070198
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
500
495
99
80-120
Arsenic
ug/L
500
489
98
80-120
Barium
ug/L
500
478
96
80-120
Beryllium
ug/L
500
486
97
80-120
Cadmium
ug/L
500
485
97
80-120
Chromium
ug/L
500
485
97
80-120
Cobalt
ug/L
500
498
100
80-120
Copper
ug/L
500
499
100
80-120
Hardness, Total(SM 2340B)
ug/L
33100
32500
98
80-120
Iron
ug/L
5000
4850
97
80-120
Lead
ug/L
500
501
100
80-120
Magnesium
ug/L
5000
4920
98
80-120
Manganese
ug/L
500
485
97
80-120
Nickel
ug/L
500
488
98
80-120
Selenium
ug/L
500
486
97
80-120
Silver
ug/L
250
245
98
80-120
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /22/2020 04:30 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 29

leAnalyiical
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
LABORATORY CONTROL SAMPLE:
3070198
Spike
LCS LCS % Rec
Parameter
Units
Conc.
Result % Rec Limits Qualifiers
Tin
ug/L
500
499 100 80-120
Vanadium
ug/L
500
488 98 80-120
Zinc
ug/L
500
488 98 80-120
MATRIX SPIKE & MATRIX SPIKE
Parameter
DUPLICATE: 3070199
MS
92505868001 Spike
Units Result Conc.
MSD
Spike
Conc.
3070200
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
Antimony
ug/L
ND
250
250
252
253
101
101
75-125
1
20
Arsenic
ug/L
ND
250
250
257
260
103
104
75-125
1
20
Barium
ug/L
20.3
250
250
272
276
101
102
75-125
2
20
Beryllium
ug/L
ND
250
250
251
254
100
102
75-125
1
20
Cadmium
ug/L
ND
250
250
257
262
103
105
75-125
2
20
Chromium
ug/L
ND
250
250
256
260
101
103
75-125
2
20
Cobalt
ug/L
ND
250
250
258
263
103
105
75-125
2
20
Copper
ug/L
ND
250
250
260
264
102
104
75-125
1
20
Hardness, Total(SM 2340B)
ug/L
16900
16500
16500
33900
34800
103
108
75-125
2
Iron
ug/L
4550
2500
2500
7490
7600
117
122
75-125
1
20
Lead
ug/L
ND
250
250
264
266
105
106
75-125
1
20
Magnesium
ug/L
1820
2500
2500
4410
4520
103
108
75-125
3
20
Manganese
ug/L
72.2
250
250
324
330
101
103
75-125
2
20
Nickel
ug/L
ND
250
250
256
261
102
104
75-125
2
20
Selenium
ug/L
ND
250
250
264
268
105
107
75-125
2
20
Silver
ug/L
ND
125
125
128
130
102
104
75-125
1
20
Tin
ug/L
ND
250
250
258
263
103
105
75-125
2
20
Vanadium
ug/L
12.0
250
250
262
268
100
102
75-125
2
20
Zinc
ug/L
ND
250
250
263
272
104
108
75-125
3
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /22/2020 04:30 PM without the written consent of Pace Analytical Services, LLC.
Page 16 of 29

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
QC Batch: 580352 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92505868001, 92505868002, 92505868003
METHOD BLANK: 3070209 Matrix: Water
Associated Lab Samples: 92505868001, 92505868002, 92505868003
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Thallium ug/L ND 0.10 0.050 11/18/20 22:52
LABORATORY CONTROL SAMPLE: 3070210
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Thallium ug/L 10 10.3 103 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3070211 3070212
MS MSD
92505868002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Thallium ug/L 0.076J 10 10 10.6 10.5 105 105 75-125 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /22/2020 04:30 PM without the written consent of Pace Analytical Services, LLC.
Page 17 of 29

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
QC Batch: 580628 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92505868001, 92505868002, 92505868003
METHOD BLANK: 3071409 Matrix:
Associated Lab Samples: 92505868001, 92505868002, 92505868003
Blank
Parameter Units Result
Water
Reporting
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.34
11/17/20 00:16
1,1,1-Trichloroethane
ug/L
ND
1.0
0.18
11/17/20 00:16
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
11/17/20 00:16
1,1,2-Trichloroethane
ug/L
ND
1.0
0.24
11/17/20 00:16
1,1-Dichloroethane
ug/L
ND
1.0
0.27
11/17/20 00:16
1,1-Dichloroethene
ug/L
ND
1.0
0.24
11/17/20 00:16
1,2,3-Trichloropropane
ug/L
ND
1.0
0.35
11/17/20 00:16
1,2-Dibromo-3-chloropropane
ug/L
ND
5.0
0.26
11/17/20 00:16
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.26
11/17/20 00:16
1,2-Dichlorobenzene
ug/L
ND
1.0
0.29
11/17/20 00:16
1,2-Dichloroethane
ug/L
ND
1.0
0.34
11/17/20 00:16
1,2-Dichloropropane
ug/L
ND
1.0
0.19
11/17/20 00:16
1,4-Dichlorobenzene
ug/L
ND
1.0
0.26
11/17/20 00:16
2-Butanone (MEK)
ug/L
ND
5.0
3.3
11/17/20 00:16
2-Hexanone
ug/L
ND
5.0
0.57
11/17/20 00:16
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
4.5
11/17/20 00:16
Acetone
ug/L
ND
25.0
6.2
11/17/20 00:16
Acetonitrile
ug/L
ND
50.0
30.4
11/17/20 00:16
Benzene
ug/L
ND
1.0
0.15
11/17/20 00:16
Bromochloromethane
ug/L
ND
1.0
0.34
11/17/20 00:16
Bromodichloromethane
ug/L
ND
1.0
0.26
11/17/20 00:16
Bromoform
ug/L
ND
1.0
0.62
11/17/20 00:16
Bromomethane
ug/L
ND
2.0
0.62
11/17/20 00:16
Carbon disulfide
ug/L
ND
2.0
0.40
11/17/20 00:16
Carbon tetrachloride
ug/L
ND
1.0
0.22
11/17/20 00:16
Chlorobenzene
ug/L
ND
1.0
0.23
11/17/20 00:16
Chloroethane
ug/L
ND
1.0
0.49
11/17/20 00:16
Chloroform
ug/L
ND
5.0
2.3
11/17/20 00:16
Chloromethane
ug/L
ND
1.0
0.39
11/17/20 00:16
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.29
11/17/20 00:16
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.30
11/17/20 00:16
Dibromochloromethane
ug/L
ND
1.0
0.41
11/17/20 00:16
Dibromomethane
ug/L
ND
1.0
0.46
11/17/20 00:16
Dichlorodifluoromethane
ug/L
ND
1.0
0.23
11/17/20 00:16
Ethylbenzene
ug/L
ND
1.0
0.26
11/17/20 00:16
lodomethane
ug/L
ND
20.0
12.5
11/17/20 00:16 IK
Isobutanol
ug/L
ND
100
66.4
11/17/20 00:16
Methylene Chloride
ug/L
ND
5.0
3.7
11/17/20 00:16
Styrene
ug/L
ND
1.0
0.27
11/17/20 00:16
Tetrachloroethene
ug/L
ND
1.0
0.16
11/17/20 00:16
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /22/2020 04:30 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 29

leAnalyiical
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
METHOD BLANK: 3071409 Matrix:
Associated Lab Samples: 92505868001, 92505868002, 92505868003
Blank
Parameter Units Result
Water
Reporting
Limit
MDL
Analyzed
Tetrahydrofuran
ug/L
ND
10.0
1.9
11/17/20 00:16
Toluene
ug/L
ND
1.0
0.24
11/17/20 00:16
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.25
11/17/20 00:16
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.31
11/17/20 00:16
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.54
11/17/20 00:16
Trichloroethene
ug/L
ND
1.0
0.22
11/17/20 00:16
Trichlorofluoromethane
ug/L
ND
1.0
0.31
11/17/20 00:16
Vinyl acetate
ug/L
ND
2.0
1.4
11/17/20 00:16
Vinyl chloride
ug/L
ND
1.0
0.24
11/17/20 00:16
Xylene (Total)
ug/L
ND
1.0
0.63
11/17/20 00:16
1,2-Dichloroethane-d4 (S)
%
107
70-130
11/17/20 00:16
4-Bromofluorobenzene (S)
%
99
70-130
11/17/20 00:16
Toluene-d8 (S)
%
101
70-130
11/17/20 00:16
LABORATORY CONTROL SAMPLE:
Parameter
3071410
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1,2-Tetrachloroethane
ug/L
50
49.8
100
70-130
1,1,1-Trichloroethane
ug/L
50
52.8
106
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
48.7
97
70-130
1,1,2-Trichloroethane
ug/L
50
50.3
101
70-130
1,1-Dichloroethane
ug/L
50
54.4
109
70-130
1,1-Dichloroethene
ug/L
50
59.6
119
70-132
1,2,3-Trichloropropane
ug/L
50
50.5
101
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
49.8
100
70-132
1,2-Dibromoethane (EDB)
ug/L
50
51.1
102
70-130
1,2-Dichlorobenzene
ug/L
50
50.3
101
70-130
1,2-Dichloroethane
ug/L
50
53.0
106
70-130
1,2-Dichloropropane
ug/L
50
51.0
102
70-130
1,4-Dichlorobenzene
ug/L
50
48.7
97
70-130
2-Butanone (MEK)
ug/L
100
103
103
70-133
2-Hexanone
ug/L
100
101
101
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
100
101
101
70-130
Acetone
ug/L
100
109
109
70-144
Acetonitrile
ug/L
500
541
108
68-134
Benzene
ug/L
50
50.1
100
70-130
Bromochloromethane
ug/L
50
53.9
108
70-130
Bromodichloromethane
ug/L
50
47.5
95
70-130
Bromoform
ug/L
50
47.9
96
70-131
Bromomethane
ug/L
50
42.9
86
30-177
Carbon disulfide
ug/L
50
55.6
111
70-133
Carbon tetrachloride
ug/L
50
50.6
101
70-130
Chlorobenzene
ug/L
50
49.0
98
70-130
Chloroethane
ug/L
50
51.7
103
46-131
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
LABORATORY CONTROL SAMPLE:
Parameter
3071410
Units
Spike
Conc.
LCS LCS
Result % Rec
Chloroform
ug/L
50
55.7
Chloromethane
ug/L
50
42.2
cis-1,2-Dichloroethene
ug/L
50
52.0
cis-1,3-Dichloropropene
ug/L
50
53.9
Dibromochloromethane
ug/L
50
50.6
Dibromomethane
ug/L
50
51.4
Dichlorodifluoromethane
ug/L
50
45.3
Ethylbenzene
ug/L
50
48.5
lodomethane
ug/L
100
117
Isobutanol
ug/L
1000
1120
Methylene Chloride
ug/L
50
50.7
Styrene
ug/L
50
49.6
Tetrachloroethene
ug/L
50
47.7
Tetrahydrofuran
ug/L
500
539
Toluene
ug/L
50
50.3
trans-1,2-Dichloroethene
ug/L
50
57.9
trans- 1,3-Dichloropropene
ug/L
50
51.5
trans-1,4-Dichloro-2-butene
ug/L
50
52.9
Trichloroethene
ug/L
50
54.3
Trichlorofluoromethane
ug/L
50
49.2
Vinyl acetate
ug/L
100
122
Vinyl chloride
ug/L
50
47.8
Xylene (Total)
ug/L
150
148
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
% Rec
Limits Qualifiers
111
70-130
84
49-130
104
70-130
108
70-130
101
70-130
103
70-130
91
52-134
97
70-130
117
47-1401K
112
62-136
101
68-130
99
70-130
95
70-130
108
70-130
101
70-130
116
70-130
103
70-130
106
25-200
109
70-130
98
61-130
122
70-140
96
59-142
99
70-130
100
70-130
99
70-130
100
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3071411
MS
92506094007 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3071412
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
22.7
22.5
113
113
70-135
1
30
1,1,1-Trichloroethane
ug/L
ND
20
20
21.3
21.4
107
107
70-148
0
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
21.5
20.5
107
102
70-131
5
30
1,1,2-Trichloroethane
ug/L
ND
20
20
21.5
21.2
107
106
70-136
1
30
1,1-Dichloroethane
ug/L
4.1
20
20
25.4
25.0
106
104
70-147
2
30
1,1-Dichloroethene
ug/L
ND
20
20
23.9
24.0
120
120
70-158
0
30
1,2,3-Trichloropropane
ug/L
ND
20
20
21.0
20.3
105
101
67-137
4
30
1,2-Dibromo-3-
ug/L
ND
20
20
20.6
20.5
103
102
69-136
1
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
21.1
20.4
105
102
70-137
3
30
1,2-Dichlorobenzene
ug/L
0.38J
20
20
22.4
22.4
110
110
70-133
0
30
1,2-Dichloroethane
ug/L
0.52J
20
20
20.5
20.2
100
99
67-138
2
30
1,2-Dichloropropane
ug/L
ND
20
20
21.7
22.0
109
110
70-138
1
30
1,4-Dichlorobenzene
ug/L
14.0
20
20
38.0
37.4
120
117
70-133
2
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /22/2020 04:30 PM without the written consent of Pace Analytical Services, LLC.
Page 20 of 29

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QUALITY CONTROL DATA
Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 3071411
3071412
MS
MSD
92506094007
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
2-Butanone (MEK)
ug/L
ND
40
40
41.0
41.4
102
104
61-147
1
30
2-Hexanone
ug/L
ND
40
40
42.6
42.0
106
105
67-139
1
30
4-Methyl-2-pentanone
ug/L
ND
40
40
41.3
41.4
103
103
67-136
0
30
(MIBK)
Acetone
ug/L
ND
40
40
87.4
87.1
219
218
55-159
0
30 M1
Acetonitrile
ug/L
ND
200
200
197
193
98
97
66-145
2
30
Benzene
ug/L
4.7
20
20
26.3
26.0
108
106
67-150
1
30
Bromochloromethane
ug/L
ND
20
20
20.9
21.1
105
106
70-146
1
30
Bromodichloromethane
ug/L
ND
20
20
20.6
20.4
103
102
70-138
1
30
Bromoform
ug/L
ND
20
20
19.1
18.5
96
92
57-138
3
30
Bromomethane
ug/L
ND
20
20
15.3
13.8
76
69
10-200
10
30 v2
Carbon disulfide
ug/L
ND
20
20
23.8
23.6
119
118
70-152
1
30
Carbon tetrachloride
ug/L
ND
20
20
23.4
23.1
117
116
70-147
1
30
Chlorobenzene
ug/L
0.67J
20
20
24.1
23.4
117
114
70-137
3
30
Chloroethane
ug/L
ND
20
20
22.6
21.1
113
106
51-166
7
30
Chloroform
ug/L
ND
20
20
18.9
20.0
94
100
70-144
6
30
Chloromethane
ug/L
ND
20
20
15.8
14.6
79
73
24-161
8
30
cis-1,2-Dichloroethene
ug/L
8.1
20
20
27.7
28.0
98
100
67-148
1
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
20.7
20.8
104
104
70-142
0
30
Dibromochloromethane
ug/L
ND
20
20
21.0
21.0
105
105
68-138
0
30
Dibromomethane
ug/L
ND
20
20
21.7
20.8
109
104
70-134
4
30
Dichlorodifluoromethane
ug/L
ND
20
20
16.6
16.8
83
84
43-155
1
30 v2
Ethylbenzene
ug/L
1.4
20
20
24.5
24.1
116
114
68-143
2
30
lodomethane
ug/L
ND
40
40
41.6
42.4
104
106
20-161
2
30
Isobutanol
ug/L
ND
400
400
407
395
102
99
44-145
3
30
Methylene Chloride
ug/L
ND
20
20
19.7
18.8
98
94
64-148
5
30
Styrene
ug/L
ND
20
20
22.1
22.2
111
111
70-136
0
30
Tetrachloroethene
ug/L
ND
20
20
20.0
20.2
100
101
70-139
1
30
Tetrahydrofuran
ug/L
166
200
200
351
352
93
93
65-145
0
30
Toluene
ug/L
0.64J
20
20
22.7
22.4
110
109
47-157
1
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
21.1
20.9
106
105
70-149
1
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
20.2
20.1
101
100
70-138
1
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
16.0
16.2
80
81
31-145
1
30
Trichloroethene
ug/L
ND
20
20
23.1
23.0
116
115
70-149
0
30
Trichlorofluoromethane
ug/L
ND
20
20
20.5
20.1
103
100
61-154
2
30
Vinyl acetate
ug/L
ND
40
40
40.3
40.1
101
100
48-156
1
30
Vinyl chloride
ug/L
1.1
20
20
20.2
19.7
95
93
55-172
2
30
Xylene (Total)
ug/L
ND
60
60
71.2
69.5
119
116
66-145
2
30
1,2-Dichloroethane-d4 (S)
%
93
93
70-130
4-Bromofluorobenzene (S)
%
100
99
70-130
Toluene-d8 (S)
%
98
98
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /22/2020 04:30 PM without the written consent of Pace Analytical Services, LLC.
Page 21 of 29

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9800 Kincey Ave. Suite 100
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QUALITY CONTROL DATA
Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
QC Batch: 580296 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92505868001, 92505868002, 92505868003
METHOD BLANK: 3069740
Matrix:
Water
Associated Lab Samples:
92505868001, 92505868002, 92505868003
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
1.2 11/14/20 02:46
1,2-Dichloroethane-d4 (S)
%
100
70-130
11/14/20 02:46
Toluene-d8 (S)
%
87
66-133
11/14/20 02:46
LABORATORY CONTROL SAMPLE: 3069741
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 18.7 94 70-130
1,2-Dichloroethane-d4 (S) % 98 70-130
Toluene-d8 (S) % 87 66-133
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3069742
3069743
MS
MSD
92505897004 Spike
Spike MS MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result
% Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L ND 20
20 20.1 19.2
95
91
64-141
4 30
1,2-Dichloroethane-d4 (S)
%
98
100
70-130
30
Toluene-d8 (S)
%
85
85
66-133
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /22/2020 04:30 PM without the written consent of Pace Analytical Services, LLC.
Page 22 of 29

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QUALITY CONTROL DATA
Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
QC Batch: 581374
Analysis Method: EPA 8081 B
QC Batch Method: EPA 3510C
Analysis Description: 8081 OC Pesticides Red Vol
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92505868001, 92505868002,
92505868003
METHOD BLANK: 3075233
Matrix: Water
Associated Lab Samples: 92505868001, 92505868002,
92505868003
Blank Reporting
Parameter
Units
Result Limit
MDL Analyzed Qualifiers
alpha-BHC
ug/L
ND 0.050
0.019 11/19/20 13:56
beta-BHC
ug/L
ND 0.050
0.014 11/19/20 13:56
Decachlorobiphenyl (S)
%
115 10-154
11/19/20 13:56
Tetrachloro-m-xylene (S)
%
94 10-184
11/19/20 13:56
LABORATORY CONTROL SAMPLE:
3075234
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
alpha-BHC
ug/L
0.25 0.29
116 37-139
beta-BHC
ug/L
0.25 0.33
130 39-176
Decachlorobiphenyl (S)
%
119 10-154
Tetrachloro-m-xylene (S)
%
81 10-184
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3075235 3075236
MS MSD
92505868003
Spike Spike MS
MSD MS MSD % Rec
Max
Parameter Units
Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD
RPD Qual
alpha-BHC ug/L
ND
0.5 0.5 0.50
0.47 101 93 25-151 8
30
beta-BHC ug/L
ND
0.5 0.5 0.62
0.58 125 116 30-188 7
30
Decachlorobiphenyl (S) %
71 102 10-154
Tetrachloro-m-xylene (S) %
154 68 10-184
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /22/2020 04:30 PM without the written consent of Pace Analytical Services, LLC.
Page 23 of 29

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Huntersville, NC 28078
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QUALITY CONTROL DATA
Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
QC Batch: 581757 Analysis Method: SM 4500-CN-E-2011
QC Batch Method: SM 4500-CN-E-2011 Analysis Description: 450OCNE Cyanide, Total
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92505868001, 92505868002, 92505868003
METHOD BLANK: 3077079 Matrix: Water
Associated Lab Samples: 92505868001, 92505868002, 92505868003
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Cyanide ug/L ND 8.0 6.0 11/22/2013:06
LABORATORY CONTROL SAMPLE: 3077080
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Cyanide ug/L 100 100 100 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3077095 3077096
MS MSD
92505711001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Cyanide ug/L ND 100 100 72.5 63.9 71 63 80-120 13 10 M1,R1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3077097 3077098
MS MSD
92505711002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Cyanide ug/L ND 100 100 75.2 86.4 72 83 80-120 14 10 M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /22/2020 04:30 PM without the written consent of Pace Analytical Services, LLC.
Page 24 of 29

Pace Analytical Services, LLC
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QUALIFIERS
Project: Johns R. - SURFACE WATER
Pace Project No.: 92505868
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
ANALYTE QUALIFIERS
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Johns R. - SURFACE WATER
92505868
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92505868001
1203-SMP5
EPA 3510C
581374
EPA 8081 B
581591
92505868002
1203-SMP6
EPA 3510C
581374
EPA 8081 B
581591
92505868003
1203-SMP7
EPA 3510C
581374
EPA 8081 B
581591
92505868001
1203-SMP5
EPA 3010A
580349
EPA 6010D
580362
92505868002
1203-SMP6
EPA 3010A
580349
EPA 6010D
580362
92505868003
1203-SMP7
EPA 3010A
580349
EPA 6010D
580362
92505868001
1203-SMP5
EPA 3010A
580352
EPA 6020B
580359
92505868002
1203-SMP6
EPA 3010A
580352
EPA 6020B
580359
92505868003
1203-SMP7
EPA 3010A
580352
EPA 6020B
580359
92505868001
1203-SMP5
EPA 8260D
580628
92505868002
1203-SMP6
EPA 8260D
580628
92505868003
1203-SMP7
EPA 8260D
580628
92505868001
1203-SMP5
EPA 8260D Mod.
580296
92505868002
1203-SMP6
EPA 8260D Mod.
580296
92505868003
1203-SMP7
EPA 8260D Mod.
580296
92505868001
1203-SMP5
SM 4500-CN-E-2011
581757
SM 4500-CN-E-2011
582089
92505868002
1203-SMP6
SM 4500-CN-E-2011
581757
SM 4500-CN-E-2011
582089
92505868003
1203-SMP7
SM 4500-CN-E-2011
581757
SM 4500-CN-E-2011
582089
Date: 11/22/2020 04:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 26 of 29

Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville V Raleigh❑
Mechanicsville[] Atlanta[] Kerners�ille
Name:
F WQ# ' 92505868
sampleClient
Project
#:
.. Ca' �e I AfJoe, of
II` IIII
II I
``
II
Courier: []Fed Ex ❑UPS ❑USPS ❑Client
i
11
❑ commercial Pace []Other:
8Z605S68
Custody Seal Present? []Yes No Seals Intact? [Dyes eoNp
(((```���
G
Elate/Initials Person Examining Contents;
Packing Material: ❑Bubble Wrap ❑Bubble sags ❑None Other
biological Tissue Frozen?
❑Yes ❑No ON/A
Thermom et r: Wet []Blue
[]None
lR Gun ID: 42Td6 i. Type of Ice:
�
''^^ f r � Correction Factor:
Add/subtract (°Cj �,�
p should be above freezing to 6°C
Temp
ice,
Cooler Temp:
�`(.
❑5amples out of temp criteria, samples on cooling process
Z
Cooler Temp Corrected QCl:
has begun
USDA Regulated Sail (N/A, water sample)
Did originate in a quarantine zone within the United States: CA, NY, or 5C [check mapsj7
nglHawaii and Puerto Rica]? l❑Yes source ['nt❑Noon ally,
samples
nyes ❑No
including
Comments/Discrepancy:
Chain of Custody Present?
Samoles Arrived within Hold Time?
Short Hold Time Analysis [<72 hr.)?
Rush Turn Around Time Requested?
Sufficient Volume?
Correct Containers Used?
-Pace Containers Used?
Containers Intact?
Dissolved analysis: Samples Field Filtered?
Sample Labels Match CDC?
-IncludesOate/Time/1D/Analysis Matrix; tr
Headspace in VOA Vials (>5-6mm)?
Trip Blank Present?
Trip Blank Custody Seals Present?
COMMENTS/SAMPLE DISCREPANCY
Yes UNo UJN
Yes ❑No ❑N/A
]Yes
No
❑N/A
3.
❑Yes
No
N/A
4•
Yes
No
[]N/A
S.
71yes
❑No
❑N/A
❑No
❑res
❑No
❑N/A
f6.es
Yes
No
❑N/AZres
❑No
❑N/A
❑Yes No 1"
❑Yes []NO�/A 11.
Ayes ONO IA
Lot lD of split containers:
Fleld Data Required? ❑Yes []No
CLIENT NOTIFICA
Page 27 of 29

*Check mark top half of box tt pH anot or uCL111-1to �•+
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliforrn, TOC, Oil and Grease, t7ROM15 (water) DOC, UHg
**Bottom half of box is to.list number of bottles
z
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a
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=
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CLIENT: 92-Joyce En9
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pH Adjustment Log for Preserved Samples
Sample ID Type of Preservative pH upon pH
Date preservation adjusted Time preservation Amount addredservative lot 1#
adjusted

CHAIN-OF-CU TODY 1 Analytical Request Document
The Chain -of -Custody i a LEGAL DOCUMENT, All relevant fields must be completed accurately.
Section B Section
C
rmation: Required Project Information: Invoi
a Information: Pg e
ion Lecia Jones
Name: La Bella Associates
Ella Associates
Report To: Van Burbach
Atten
West Meadowview Rd
Copy To: Miguel Vazquez
Company
27407
Address:
1604 Ownby Lane, Richmond, VA 23220
Regulatory Agency
bach(cNabellapc.com
Purchase Order No. 2202300.00.02
Pace
Ouote Reference:
323-0092 Fax
Client Project ID: Johns R. -SURFACE WATER
face
Project Manager: Nicole Gasiurowsk's
State! Location
(TAT 10 Da Default)
Container Order Number;
Pace
Profile #: 2327-14
North Carolina
Requested Anal is Filtered Y!N
a
Z
nArRix LODE
—
COLLECTED
z
Preservatives
A
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Water WT
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SAMPLE ID S.,Vsmm
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START
END
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to Character per box. wipe WP
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DATE
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DATF
TIME
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ADDITIONAL COMMENTS
RELINQUISHED BY f AFFILIATION
DATE
rIME
ACCEPTEQ BY I AFFILIATION
DATE
TIME
SAM
JJ
SAMPLER NAME AND SIGNATURE
c
c
z
PRINT Name of SAMPLER:
1, �. � I
W
c
-
a
w
u
SIGNATURE of SAMPLER:
DATE Signed: d I
a
r-,

0. LaBella
Project Name
Location:
Project No.:
Burke County -Johns River Resample
2202300 00
2211W. Meadowview Rd Suite 101
Greensboro NC 27407 Sampled By' G Eller / K Rctac
Telephone: [phone]
Facsimile: [phone] Date:
WELL I.D.: U "I _ 2-0 Weather:
WELL SAMPLING INFORMATION
�1
Well Diameter:
Depth of Well: .pU
Measuring Point:
Pump Type:��
FIELD PARAMF,TF,R MF.ACiTRF.MRNT
Static Water Level:
Length of Well Screen:
Depth to Top of Pump:
Tubing Type:
1�5wo F 9 0
da-I I o -ns
Turbidity
�issolved �O2
Depth to
Alkalinity Iron (11)
■uiai Ib4• , vailuus ruigcu
Purge Time Purge Time End: Final Static Water Level:
Start: A � � �
OBSERVATIONS

LaBella Project Name: Burke County -Johns River Resample
Location:
2211W. Meadowview Rd Suite 101 Project No.: 2202300.00
Greensboro, NC 27407 Sampled By: G. Eller / K. Estes
Telephone: [phone]
Facsimile: [phone] Date:
WELL I.D.: Weather:
WELL SAMPLING INFORMATION
Well Diameter:
,r
Depth of Well: 44(0-92
Measuring Point:
Pump Type: at
FIELD PARAMETER MEASUREMFNT
Static Water Level: 00-
Length of Well Screen:
Depth to Top of Pump:
Tubing Type:
Gallons
Purged
Conductivity
(ms/cm)
Turmd�
(NTU)
Depth to Alkalinity Iron (11) Comments
Water
But
------------
------------
---------
-
---------
-
Purge Time
Start:
OBSERVATIONS
i orai C:% , iJ tlaiwns rurgea
Purge Time End:
Notes: ry a
112.3
Final Static Water Level:

C. LaBeRa
Burke County -Johns River Resample
2202300.00
2211W. Meadowview Rd Suite 101
Greensboro, NC 27407 Sampled By: G. Eller / K. Estes
Telephone: [phone]
Facsimile: [phone] Date:
WELL I.D.: k4W r ?3S Weather:
WELL SAMPLING INFORMATION
Well Diameter: 6
Depth of Well:
Measuring Point:
Pump Type:CLS�
FiFI.D PARAMF.TF.R MF.Ag1JRF.MFNT
Project Name:
Location:
Project No.:
Static Water Level:
Length of Well Screen:
Depth to Top of Pump:
Tubing Type:
go
Gallons
Purged
Dissolved 02
(mg/L)
Depth to
Water
Alkalinity
Iron (11)
iota] . -:), _ t,auons rurgea
Purge Time
Start: 1-3j[)
OBSERVATIONS
Purge Time End: Final Static Water Level:
8.ors
Notes:
G�1, pV I
tA-
' 1-affi/ 41.011

LaBeRa
Burke County -Johns River Resample
2202300.00
2211W. Meadowview Rd Suite 101
Greensboro, NC 27407 Sampled By: G. Eller / K. Estes
Telephone: [phone] Adz.]
Facsimile: [phone] Date:
WELL I.D.: UOY - t ' Weather: Id is
WELL SAMPLING INFORMATION
Well Diameter: —011
Depth of Well: 5v. OD
Measuring Point:
Pump Type:�y�
FlrF,I,D PARAMF,TRR MF.ACiIRF.MRNT
Project Name:
Location:
Project No.:
Static Water Level:
Length of Well Screen:
Depth to Top of Pump:
Tubing Type:
a
NW-G-a-Hom
Purged
Mw
Conductivity
Turbidity
( U)
=—Depth
to
Alkalinity Iron (11) Comments
Purge Time
Start:
OBSERVATIONS
►Uiai vauons rurgea
1141 (o Purge Time End:
Notes: & 1(4,37'
14 3-4
3,
Final Static Water Level:
7-

C., LaBella
Burke County -Johns River Resample
2202300.00
2211W. Meadowview Rd Suite 101
Greensboro, NC 27407 Sampled By: G. Eller / x FcrP.c
Telephone: [phone]
Facsimile: [phone] Date:
WELL I.D.: M w - 3y Weather:
WELL SAMPLING INFORM TION
Well Diameter: ��
Depth of Well: p
Measuring Point:
Pump Type: p�,r
FIELD PARAMETFR MEARTIRF.MF.NT
Project Name:
Location:
Project No.:
Static Water Level:
Length of Well Screen:
Depth to Top of Pump:
Tubing Type:
oil•ib(o
Pump Rate
Gallons
Turbidity
Dissolved 02 Redox Depth to Alkalinity Iron (11) Comments
------------
------------
-------
I Utal vtai vaiivus rulgcu
Purge Time Purge Time End: / Final Static Water Level:
Start:
OBSERVATIONS
Notes: � � L�ti%may _ � � r �- � •�"

0
LaBelLa
-3-0
DATE: L2-o 2
GROUND WATER SAMPLING LOG
Project Name: Project No. /Task No.:aada�L cx-)
Well ID: Sampler(s):_ k Qlr (�
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well:
For 4" Well:
WCT X 0.163
WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled wits
2 inches
5 feet
? s S'5 feet
1 1• 7t feet [DTB-DTW]
= lgallons
gallons
` gallons
gallons
Depth to Water before Sampling: feet
Gallons
Time
Temp
(°C)
pH
Cond.
(US/CM)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
3-�
io►z
CS-3
b
P21,V
5
Date of sample:
�
Before Sampling
Comments (wea her conditions, odor, color, silt, etc.):
Signature: Date: % L2-q LZI
QA/QC Sign Off: Date: �". y

0. LaBeRa
Project Name:
Location:
Project No.:
Burke County -Johns River Resample
2202300.00
2211W. Meadowview Rd Suite 101
Greensboro, NC 27407 Sampled By: G. Eller / K. Estes
Telephone: [phone]
Facsimile: [phone] Date:
WELL I.D.: M Weather:
WELL SAMPLING INFORMATION
Well Diameter: (�
Depth of Well:
Measuring Point:
Pump Type:
FIELD PARAMF.TF.R MF.ANUIRFMIRNT
Static Water Level:
Length of Well Screen:
Depth to Top of Pump:
Tubing Type:
Gallons
Conductivity
Turbidity
9�1 =1
Redox
Depth to
Alkalinity Iron (11) Comments
NMI M"
IMai L- Z;' vailuus rulgcu
Purge Time Purge Time End: Final Static Water Level:
Start: j,-S—(Q (7
OBSERVATIONS
Notes: �44UJ
G j
P-1 A
al-Z /,,I

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
February 11, 2021
Mr. Van Burbach
Joyce Engineering -NC
2211 W. Meadowview Road
Suite 101
Greensboro, NC 27407
RE: Project: Johns River EXP Resample
Pace Project No.: 92519331
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on January 29, 2021. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
/7j"4w'
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Van Burbach, Joyce Engineering -NC
Gretta Eller, LaBella Associates, D.P.C.
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Johns River EXP Resample
Pace Project No.: 92519331
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Johns River EXP Resample
Pace Project No.: 92519331
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92519331001
MW-20
Water
01/28/21
09:36
01/29/21
08:20
92519331002
MW-30
Water
01/28/21
14:37
01/29/21
08:20
92519331003
MW-23S
Water
01/28/21
13:55
01/29/21
08:20
92519331004
MW-35
Water
01/28/21
12:17
01/29/21
08:20
92519331005
Field Blank
Water
01/28/21
14:48
01/29/21
08:20
92519331006
MW-38
Water
01/28/21
13:05
01/29/21
08:20
92519331007
Trip Blank
Water
01/27/21
08:00
01/29/21
08:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Johns River EXP Resample
92519331
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92519331001
MW-20
EPA 601 OD
RDT
16
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 7470A
SOO
1
PASI-A
EPA 8260D
CL
51
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
SM 2320B-2011
ECH
1
PASI-A
SM 2540C-2011
RED
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
SM 4500-CI-E-2011
MDW
1
PASI-A
92519331002
MW-30
EPA 601 OD
RDT
16
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 7470A
SOO
1
PASI-A
EPA 8260D
CL
51
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
SM 2320B-2011
ECH
1
PASI-A
SM 2540C-2011
RED
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
SM 4500-CI-E-2011
MDW
1
PASI-A
92519331003
MW-23S
EPA 601 OD
RDT
16
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 7470A
SOO
1
PASI-A
EPA 8260D
CL
51
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
SM 2320B-2011
ECH
1
PASI-A
SM 2540C-2011
RED
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
SM 4500-CI-E-2011
MDW
1
PASI-A
92519331004
MW-35
EPA 601OD
SH1
16
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 7470A
SOO
1
PASI-A
EPA 8260D Mod.
LMB
3
PASI-C
SM 2320B-2011
ECH
1
PASI-A
SM 2540C-2011
RED
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
SM 4500-CI-E-2011
MDW
1
PASI-A
92519331005
Field Blank
EPA 601OD
SH1
14
PASI-A
EPA 6020E
JOR
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Johns River EXP Resample
Pace Project No.:
92519331
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
EPA 8260D
CL
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92519331006
MW-38
EPA 601OD
SH1
2
PASI-A
EPA 7470A
SOO
1
PASI-A
EPA 8260D Mod.
LMB
3
PASI-C
SM 2320B-2011
ECH
1
PASI-A
SM 2540C-2011
RED
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
SM 4500-CI-E-2011
MDW
1
PASI-A
92519331007
Trip Blank
EPA 8260D
CL
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 5 of 50

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Johns River EXP Resample
Pace Project No.: 92519331
Lab Sample ID Client Sample ID
Method Parameters
92519331001
EPA 601 OD
EPA 601 OD
EPA 601 OD
EPA 6020B
SM 2540C-2011
SM 4500-CI-E-2011
92519331002
EPA 601 OD
EPA 601 OD
EPA 601 OD
SM 2320B-2011
SM 2540C-2011
SM 4500-CI-E-2011
92519331003
EPA 601 OD
EPA 601 OD
EPA 601 OD
EPA 601 OD
SM 2540C-2011
EPA 300.0 Rev 2.1 1993
SM 4500-CI-E-2011
92519331004
EPA 601 OD
EPA 601 OD
EPA 601 OD
SM 2320B-2011
SM 2540C-2011
SM 4500-CI-E-2011
92519331006
EPA 601 OD
EPA 601 OD
EPA 8260D Mod.
SM 2320B-2011
SM 2540C-2011
EPA 300.0 Rev 2.1 1993
SM 4500-CI-E-2011
MW-20
Barium
Iron
Manganese
Thallium
Total Dissolved Solids
Chloride
MW-30
Barium
Iron
Manganese
Alkalinity, Total as CaCO3
Total Dissolved Solids
Chloride
MW-23S
Barium
Iron
Manganese
Zinc
Total Dissolved Solids
Sulfate
Chloride
MW-35
Barium
Iron
Manganese
Alkalinity, Total as CaCO3
Total Dissolved Solids
Chloride
MW-38
Iron
Manganese
1,4-Dioxane (p-Dioxane)
Alkalinity, Total as CaCO3
Total Dissolved Solids
Sulfate
Chloride
SUMMARY OF DETECTION
Result
Units
Report Limit
Analyzed Qualifiers
25.0
ug/L
5.0
02/01/2102:35
444
ug/L
50.0
02/01/2102:35
10.3
ug/L
5.0
02/01/2102:35
0.060J
ug/L
0.10
02/02/2119:19
42000
ug/L
25000
02/02/2118:46
534J
ug/L
1000
02/01/21 18:00
32.4
ug/L
5.0
02/01/2102:48
713
ug/L
50.0
02/01/2102:48
33.8
ug/L
5.0
02/01/2102:48
14300
ug/L
5000
02/10/2100:04
157000
ug/L
25000
02/02/2118:46
1230
ug/L
1000
02/01/2118:01
14.1
ug/L
5.0
02/01/2103:04
1340
ug/L
50.0
02/01/2103:04
70.7
ug/L
5.0
02/01/2103:04
11.4
ug/L
10.0
02/01/2103:04
30000
ug/L
25000
02/02/2118:47
746J
ug/L
1000
02/02/2123:53
3060
ug/L
1000
02/01/21 18:02
30.9
ug/L
5.0
02/04/2103:28
240
ug/L
50.0
02/04/2103:28
5.5
ug/L
5.0
02/04/2103:28
8650
ug/L
5000
02/10/2115:52
48000
ug/L
25000
02/02/2118:47
1090
ug/L
1000
02/01/2118:05
19600
ug/L
50.0
02/04/2103:35
7780
ug/L
5.0
02/04/2103:35
2.7
ug/L
2.0
01 /29/21 18:15
275000
ug/L
5000
02/10/2117:28
292000
ug/L
25000
02/02/2118:47
806J
ug/L
1000
02/03/21 00:51
9010
ug/L
1000
02/01/2118:06
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 50

leAnalyiical
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns River EXP Resample
Pace Project No.: 92519331
Sample: MW-20 Lab ID: 92519331001 Collected: 01/28/21 09:36 Received: 01/29/21 08:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
01/30/2101:46
02/01/2102:35
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
01/30/2101:46
02/01/2102:35
7440-38-2
Barium
25.0
ug/L
5.0
3.5
1
01/30/2101:46
02/01/2102:35
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
01/30/2101:46
02/01/2102:35
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
01/30/2101:46
02/01/2102:35
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
01/30/2101:46
02/01/2102:35
7440-47-3
Cobalt
ND
ug/L
5.0
3.6
1
01/30/2101:46
02/01/2102:35
7440-48-4
Copper
ND
ug/L
5.0
4.3
1
01/30/2101:46
02/01/2102:35
7440-50-8
Iron
444
ug/L
50.0
41.5
1
01/30/2101:46
02/01/2102:35
7439-89-6
Lead
ND
ug/L
5.0
4.5
1
01/30/2101:46
02/01/2102:35
7439-92-1
Manganese
10.3
ug/L
5.0
3.4
1
01/30/2101:46
02/01/2102:35
7439-96-5
Nickel
ND
ug/L
5.0
3.5
1
01/30/2101:46
02/01/2102:35
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
01/30/2101:46
02/01/2102:35
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
01/30/2101:46
02/01/2102:35
7440-22-4
Vanadium
ND
ug/L
5.0
3.9
1
01/30/2101:46
02/01/2102:35
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
01/30/2101:46
02/01/2102:35
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020B Preparation
Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
0.060J
ug/L
0.10
0.050
1
01/30/2101:38
02/02/2119:19
7440-28-0
7470 Mercury
Mercury
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
Date: 02/11/2021 01:48 PM
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
ND ug/L 0.20 0.12 1 02/03/2118:44 02/04/2115:35 7439-97-6
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
ND
ug/L
10.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
6.2
1
02/03/21 07:22
67-64-1
0.90
1
02/03/21 07:22
107-13-1
0.15
1
02/03/21 07:22
71-43-2
0.34
1
02/03/21 07:22
74-97-5
0.26
1
02/03/21 07:22
75-27-4
0.62
1
02/03/21 07:22
75-25-2
0.62
1
02/03/21 07:22
74-83-9
3.3
1
02/03/21 07:22
78-93-3
0.40
1
02/03/21 07:22
75-15-0
0.22
1
02/03/21 07:22
56-23-5
0.23
1
02/03/21 07:22
108-90-7
0.49
1
02/03/21 07:22
75-00-3
2.3
1
02/03/21 07:22
67-66-3
0.39
1
02/03/21 07:22
74-87-3
0.26
1
02/03/21 07:22
96-12-8
0.41
1
02/03/21 07:22
124-48-1
0.26
1
02/03/21 07:22
106-93-4
0.46
1
02/03/21 07:22
74-95-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
IK,L1,v1
v1
Page 7 of 50

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns River EXP Resample
Pace Project No.: 92519331
Sample: MW-20 Lab ID: 92519331001 Collected: 01/28/21 09:36 Received: 01/29/21 08:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Date: 02/11/2021 01:48 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.29
1
02/03/21 07:22
95-50-1
ND
ug/L
1.0
0.26
1
02/03/21 07:22
106-46-7
ND
ug/L
1.0
0.54
1
02/03/21 07:22
110-57-6
ND
ug/L
1.0
0.27
1
02/03/21 07:22
75-34-3
ND
ug/L
1.0
0.34
1
02/03/21 07:22
107-06-2
ND
ug/L
1.0
0.24
1
02/03/21 07:22
75-35-4
ND
ug/L
1.0
0.29
1
02/03/21 07:22
156-59-2
ND
ug/L
1.0
0.25
1
02/03/21 07:22
156-60-5
ND
ug/L
1.0
0.19
1
02/03/21 07:22
78-87-5
ND
ug/L
1.0
0.30
1
02/03/21 07:22
10061-01-5
ND
ug/L
1.0
0.31
1
02/03/21 07:22
10061-02-6
ND
ug/L
1.0
0.26
1
02/03/21 07:22
100-41-4
ND
ug/L
5.0
0.57
1
02/03/21 07:22
591-78-6
ND
ug/L
20.0
12.5
1
02/03/21 07:22
74-88-4
ND
ug/L
5.0
3.7
1
02/03/21 07:22
75-09-2
ND
ug/L
5.0
4.5
1
02/03/21 07:22
108-10-1
ND
ug/L
1.0
0.27
1
02/03/21 07:22
100-42-5
ND
ug/L
1.0
0.34
1
02/03/21 07:22
630-20-6
ND
ug/L
1.0
0.22
1
02/03/21 07:22
79-34-5
ND
ug/L
1.0
0.16
1
02/03/21 07:22
127-18-4
ND
ug/L
10.0
1.9
1
02/03/21 07:22
109-99-9
ND
ug/L
1.0
0.24
1
02/03/21 07:22
108-88-3
ND
ug/L
1.0
0.18
1
02/03/21 07:22
71-55-6
ND
ug/L
1.0
0.24
1
02/03/21 07:22
79-00-5
ND
ug/L
1.0
0.22
1
02/03/21 07:22
79-01-6
ND
ug/L
1.0
0.31
1
02/03/21 07:22
75-69-4
ND
ug/L
1.0
0.35
1
02/03/21 07:22
96-18-4
ND
ug/L
2.0
1.4
1
02/03/21 07:22
108-05-4
ND
ug/L
1.0
0.24
1
02/03/21 07:22
75-01-4
ND
ug/L
1.0
0.63
1
02/03/21 07:22
1330-20-7
108
%
70-130
1
02/03/21 07:22
460-00-4
92
%
70-130
1
02/03/21 07:22
17060-07-0
108
%
70-130
1
02/03/21 07:22
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
ND
ug/L
2.0
1.2
1
01/29/2116:59
123-91-1
102
%
70-130
1
01/29/2116:59
17060-07-0
105
%
66-133
1
01/29/2116:59
2037-26-5
Analytical Method: SM 2320B-2011
Pace Analytical Services
-Asheville
ND
ug/L
5000
5000
1
02/09/2123:59
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
L1,v1
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leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns River EXP Resample
Pace Project No.: 92519331
Sample: MW-20
Parameters
Lab ID: 92519331001 Collected:
Report
Results Units Limit
01/28/21 09:36
MDL DF
Received: 01/29/21 08:20 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids
42000 ug/L 25000
25000
1
02/02/21 18:46
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Pace Analytical Services -Asheville
Sulfate
ND ug/L 1000
500
1
02/02/2119:36 14808-79-8
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
534J ug/L 1000
500
1
02/01/2118:00 16887-00-6
Date: 02/11/2021 01:48 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 9 of 50

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns River EXP Resample
Pace Project No.: 92519331
Sample: MW-30 Lab ID: 92519331002 Collected: 01/28/21 14:37 Received: 01/29/21 08:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
01/30/2101:46
02/01/2102:48
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
01/30/2101:46
02/01/2102:48
7440-38-2
Barium
32.4
ug/L
5.0
3.5
1
01/30/2101:46
02/01/2102:48
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
01/30/2101:46
02/01/2102:48
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
01/30/2101:46
02/01/2102:48
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
01/30/2101:46
02/01/2102:48
7440-47-3
Cobalt
ND
ug/L
5.0
3.6
1
01/30/2101:46
02/01/2102:48
7440-48-4
Copper
ND
ug/L
5.0
4.3
1
01/30/2101:46
02/01/2102:48
7440-50-8
Iron
713
ug/L
50.0
41.5
1
01/30/21 01:46
02/01/21 02:48
7439-89-6
Lead
ND
ug/L
5.0
4.5
1
01/30/2101:46
02/01/2102:48
7439-92-1
Manganese
33.8
ug/L
5.0
3.4
1
01/30/2101:46
02/01/2102:48
7439-96-5
Nickel
ND
ug/L
5.0
3.5
1
01/30/2101:46
02/01/2102:48
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
01/30/2101:46
02/01/2102:48
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
01/30/2101:46
02/01/2102:48
7440-22-4
Vanadium
ND
ug/L
5.0
3.9
1
01/30/2101:46
02/01/2102:48
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
01/30/2101:46
02/01/2102:48
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020B Preparation
Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.10
0.050
1
01/30/2101:38
02/02/2119:31
7440-28-0
7470 Mercury
Mercury
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
Date: 02/11/2021 01:48 PM
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
ND ug/L 0.20 0.12 1 02/03/2118:44 02/04/2115:37 7439-97-6
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
ND
ug/L
10.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
6.2
1
02/03/21 07:40
67-64-1
0.90
1
02/03/21 07:40
107-13-1
0.15
1
02/03/21 07:40
71-43-2
0.34
1
02/03/21 07:40
74-97-5
0.26
1
02/03/21 07:40
75-27-4
0.62
1
02/03/21 07:40
75-25-2
0.62
1
02/03/21 07:40
74-83-9
3.3
1
02/03/21 07:40
78-93-3
0.40
1
02/03/21 07:40
75-15-0
0.22
1
02/03/21 07:40
56-23-5
0.23
1
02/03/21 07:40
108-90-7
0.49
1
02/03/21 07:40
75-00-3
2.3
1
02/03/21 07:40
67-66-3
0.39
1
02/03/21 07:40
74-87-3
0.26
1
02/03/21 07:40
96-12-8
0.41
1
02/03/21 07:40
124-48-1
0.26
1
02/03/21 07:40
106-93-4
0.46
1
02/03/21 07:40
74-95-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
IK,L1,v1
v1
Page 10 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns River EXP Resample
Pace Project No.: 92519331
Sample: MW-30 Lab ID: 92519331002 Collected: 01/28/21 14:37 Received: 01/29/21 08:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Date: 02/11/2021 01:48 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.29
1
02/03/21 07:40
95-50-1
ND
ug/L
1.0
0.26
1
02/03/21 07:40
106-46-7
ND
ug/L
1.0
0.54
1
02/03/21 07:40
110-57-6
ND
ug/L
1.0
0.27
1
02/03/21 07:40
75-34-3
ND
ug/L
1.0
0.34
1
02/03/21 07:40
107-06-2
ND
ug/L
1.0
0.24
1
02/03/21 07:40
75-35-4
ND
ug/L
1.0
0.29
1
02/03/21 07:40
156-59-2
ND
ug/L
1.0
0.25
1
02/03/21 07:40
156-60-5
ND
ug/L
1.0
0.19
1
02/03/21 07:40
78-87-5
ND
ug/L
1.0
0.30
1
02/03/21 07:40
10061-01-5
ND
ug/L
1.0
0.31
1
02/03/21 07:40
10061-02-6
ND
ug/L
1.0
0.26
1
02/03/21 07:40
100-41-4
ND
ug/L
5.0
0.57
1
02/03/21 07:40
591-78-6
ND
ug/L
20.0
12.5
1
02/03/21 07:40
74-88-4
ND
ug/L
5.0
3.7
1
02/03/21 07:40
75-09-2
ND
ug/L
5.0
4.5
1
02/03/21 07:40
108-10-1
ND
ug/L
1.0
0.27
1
02/03/21 07:40
100-42-5
ND
ug/L
1.0
0.34
1
02/03/21 07:40
630-20-6
ND
ug/L
1.0
0.22
1
02/03/21 07:40
79-34-5
ND
ug/L
1.0
0.16
1
02/03/21 07:40
127-18-4
ND
ug/L
10.0
1.9
1
02/03/21 07:40
109-99-9
ND
ug/L
1.0
0.24
1
02/03/21 07:40
108-88-3
ND
ug/L
1.0
0.18
1
02/03/21 07:40
71-55-6
ND
ug/L
1.0
0.24
1
02/03/21 07:40
79-00-5
ND
ug/L
1.0
0.22
1
02/03/21 07:40
79-01-6
ND
ug/L
1.0
0.31
1
02/03/21 07:40
75-69-4
ND
ug/L
1.0
0.35
1
02/03/21 07:40
96-18-4
ND
ug/L
2.0
1.4
1
02/03/21 07:40
108-05-4
ND
ug/L
1.0
0.24
1
02/03/21 07:40
75-01-4
ND
ug/L
1.0
0.63
1
02/03/21 07:40
1330-20-7
106
%
70-130
1
02/03/21 07:40
460-00-4
97
%
70-130
1
02/03/21 07:40
17060-07-0
108
%
70-130
1
02/03/21 07:40
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
ND
ug/L
2.0
1.2
1
01/29/2117:18
123-91-1
104
%
70-130
1
01/29/2117:18
17060-07-0
105
%
66-133
1
01/29/2117:18
2037-26-5
Analytical Method: SM 2320B-2011
Pace Analytical Services
-Asheville
14300
ug/L
5000
5000
1
02/10/2100:04
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
L1,v1
Page 11 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns River EXP Resample
Pace Project No.: 92519331
Sample: MW-30
Parameters
Lab ID: 92519331002 Collected:
Report
Results Units Limit
01/28/21 14:37
MDL DF
Received: 01/29/21 08:20 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids
157000 ug/L 25000
25000
1
02/02/21 18:46
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Pace Analytical Services -Asheville
Sulfate
ND ug/L 1000
500
1
02/02/2123:38 14808-79-8
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
1230 ug/L 1000
500
1
02/01/2118:01 16887-00-6
Date: 02/11/2021 01:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns River EXP Resample
Pace Project No.: 92519331
Sample: MW-23S Lab ID: 92519331003 Collected: 01/28/21 13:55 Received: 01/29/21 08:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
01/30/2101:46
02/01/2103:04
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
01/30/2101:46
02/01/2103:04
7440-38-2
Barium
14.1
ug/L
5.0
3.5
1
01/30/2101:46
02/01/2103:04
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
01/30/2101:46
02/01/2103:04
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
01/30/2101:46
02/01/2103:04
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
01/30/2101:46
02/01/2103:04
7440-47-3
Cobalt
ND
ug/L
5.0
3.6
1
01/30/2101:46
02/01/2103:04
7440-48-4
Copper
ND
ug/L
5.0
4.3
1
01/30/2101:46
02/01/2103:04
7440-50-8
Iron
1340
ug/L
50.0
41.5
1
01/30/2101:46
02/01/2103:04
7439-89-6
Lead
ND
ug/L
5.0
4.5
1
01/30/2101:46
02/01/2103:04
7439-92-1
Manganese
70.7
ug/L
5.0
3.4
1
01/30/2101:46
02/01/2103:04
7439-96-5
Nickel
ND
ug/L
5.0
3.5
1
01/30/2101:46
02/01/2103:04
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
01/30/2101:46
02/01/2103:04
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
01/30/2101:46
02/01/2103:04
7440-22-4
Vanadium
ND
ug/L
5.0
3.9
1
01/30/2101:46
02/01/2103:04
7440-62-2
Zinc
11.4
ug/L
10.0
9.5
1
01/30/2101:46
02/01/2103:04
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020B Preparation
Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.10
0.050
1
01/30/2101:38
02/02/2119:35
7440-28-0
7470 Mercury
Mercury
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
Date: 02/11/2021 01:48 PM
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
ND ug/L 0.20 0.12 1 02/03/2118:44 02/04/2115:39 7439-97-6
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
ND
ug/L
10.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
6.2
1
02/03/21 07:58
67-64-1
0.90
1
02/03/21 07:58
107-13-1
0.15
1
02/03/21 07:58
71-43-2
0.34
1
02/03/21 07:58
74-97-5
0.26
1
02/03/21 07:58
75-27-4
0.62
1
02/03/21 07:58
75-25-2
0.62
1
02/03/21 07:58
74-83-9
3.3
1
02/03/21 07:58
78-93-3
0.40
1
02/03/21 07:58
75-15-0
0.22
1
02/03/21 07:58
56-23-5
0.23
1
02/03/21 07:58
108-90-7
0.49
1
02/03/21 07:58
75-00-3
2.3
1
02/03/21 07:58
67-66-3
0.39
1
02/03/21 07:58
74-87-3
0.26
1
02/03/21 07:58
96-12-8
0.41
1
02/03/21 07:58
124-48-1
0.26
1
02/03/21 07:58
106-93-4
0.46
1
02/03/21 07:58
74-95-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
IK,L1,v1
v1
Page 13 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns River EXP Resample
Pace Project No.: 92519331
Sample: MW-23S Lab ID: 92519331003 Collected: 01/28/21 13:55 Received: 01/29/21 08:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Date: 02/11/2021 01:48 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.29
1
02/03/21 07:58
95-50-1
ND
ug/L
1.0
0.26
1
02/03/21 07:58
106-46-7
ND
ug/L
1.0
0.54
1
02/03/21 07:58
110-57-6
ND
ug/L
1.0
0.27
1
02/03/21 07:58
75-34-3
ND
ug/L
1.0
0.34
1
02/03/21 07:58
107-06-2
ND
ug/L
1.0
0.24
1
02/03/21 07:58
75-35-4
ND
ug/L
1.0
0.29
1
02/03/21 07:58
156-59-2
ND
ug/L
1.0
0.25
1
02/03/21 07:58
156-60-5
ND
ug/L
1.0
0.19
1
02/03/21 07:58
78-87-5
ND
ug/L
1.0
0.30
1
02/03/21 07:58
10061-01-5
ND
ug/L
1.0
0.31
1
02/03/21 07:58
10061-02-6
ND
ug/L
1.0
0.26
1
02/03/21 07:58
100-41-4
ND
ug/L
5.0
0.57
1
02/03/21 07:58
591-78-6
ND
ug/L
20.0
12.5
1
02/03/21 07:58
74-88-4
ND
ug/L
5.0
3.7
1
02/03/21 07:58
75-09-2
ND
ug/L
5.0
4.5
1
02/03/21 07:58
108-10-1
ND
ug/L
1.0
0.27
1
02/03/21 07:58
100-42-5
ND
ug/L
1.0
0.34
1
02/03/21 07:58
630-20-6
ND
ug/L
1.0
0.22
1
02/03/21 07:58
79-34-5
ND
ug/L
1.0
0.16
1
02/03/21 07:58
127-18-4
ND
ug/L
10.0
1.9
1
02/03/21 07:58
109-99-9
ND
ug/L
1.0
0.24
1
02/03/21 07:58
108-88-3
ND
ug/L
1.0
0.18
1
02/03/21 07:58
71-55-6
ND
ug/L
1.0
0.24
1
02/03/21 07:58
79-00-5
ND
ug/L
1.0
0.22
1
02/03/21 07:58
79-01-6
ND
ug/L
1.0
0.31
1
02/03/21 07:58
75-69-4
ND
ug/L
1.0
0.35
1
02/03/21 07:58
96-18-4
ND
ug/L
2.0
1.4
1
02/03/21 07:58
108-05-4
ND
ug/L
1.0
0.24
1
02/03/21 07:58
75-01-4
ND
ug/L
1.0
0.63
1
02/03/21 07:58
1330-20-7
105
%
70-130
1
02/03/21 07:58
460-00-4
95
%
70-130
1
02/03/21 07:58
17060-07-0
107
%
70-130
1
02/03/21 07:58
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
ND
ug/L
2.0
1.2
1
01/29/2117:37
123-91-1
105
%
70-130
1
01/29/2117:37
17060-07-0
105
%
66-133
1
01/29/2117:37
2037-26-5
Analytical Method: SM 2320B-2011
Pace Analytical Services
-Asheville
ND
ug/L
5000
5000
1
02/10/2115:33
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
L1,v1
Page 14 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns River EXP Resample
Pace Project No.: 92519331
Sample: MW-23S
Parameters
Lab ID: 92519331003 Collected:
Report
Results Units Limit
01/28/21 13:55
MDL DF
Received: 01/29/21 08:20 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids
30000 ug/L 25000
25000
1
02/02/21 18:47
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Pace Analytical Services -Asheville
Sulfate
746J ug/L 1000
500
1
02/02/2123:53 14808-79-8
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
3060 ug/L 1000
500
1
02/01/2118:02 16887-00-6
Date: 02/11/2021 01:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 15 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns River EXP Resample
Pace Project No.: 92519331
Sample: MW-35 Lab ID: 92519331004 Collected: 01/28/21 12:17 Received: 01/29/21 08:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND ug/L 5.0
3.0
1
02/03/2102:11
02/04/2103:28
7440-36-0
Arsenic
ND ug/L 10.0
4.7
1
02/03/2102:11
02/04/2103:28
7440-38-2
Barium
30.9 ug/L 5.0
3.5
1
02/03/2102:11
02/04/2103:28
7440-39-3
Beryllium
ND ug/L 1.0
0.70
1
02/03/2102:11
02/04/2103:28
7440-41-7
Cadmium
ND ug/L 1.0
0.40
1
02/03/2102:11
02/04/2103:28
7440-43-9
Chromium
ND ug/L 5.0
3.7
1
02/03/2102:11
02/04/2103:28
7440-47-3
Cobalt
ND ug/L 5.0
3.6
1
02/03/2102:11
02/04/2103:28
7440-48-4
Copper
ND ug/L 5.0
4.3
1
02/03/2102:11
02/04/2103:28
7440-50-8
Iron
240 ug/L 50.0
41.5
1
02/03/2102:11
02/04/2103:28
7439-89-6
Lead
ND ug/L 5.0
4.5
1
02/03/2102:11
02/04/2103:28
7439-92-1
Manganese
5.5 ug/L 5.0
3.4
1
02/03/2102:11
02/04/2103:28
7439-96-5
Nickel
ND ug/L 5.0
3.5
1
02/03/2102:11
02/04/2103:28
7440-02-0
Selenium
ND ug/L 10.0
4.7
1
02/03/2102:11
02/04/2103:28
7782-49-2
Silver
ND ug/L 5.0
2.5
1
02/03/2102:11
02/04/2103:28
7440-22-4
Vanadium
ND ug/L 5.0
3.9
1
02/03/2102:11
02/04/2103:28
7440-62-2
Zinc
ND ug/L 10.0
9.5
1
02/03/2102:11
02/04/2103:28
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020B Preparation
Method: EPA
3010A
Pace Analytical Services -Asheville
Thallium
ND ug/L 0.10
0.050
1
01/30/2101:38
02/02/2119:39
7440-28-0
7470 Mercury
Analytical Method: EPA 7470A Preparation Method: EPA
7470A
Pace Analytical Services -Asheville
Mercury
ND ug/L 0.20
0.12
1
02/03/2118:44
02/04/2115:46
7439-97-6
8260D MSV SIM
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1,4-Dioxane (p-Dioxane)
ND ug/L 2.0
1.2
1
01/29/21 17:56
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
103 % 70-130
1
01/29/21 17:56
17060-07-0
Toluene-d8 (S)
106 % 66-133
1
01/29/21 17:56
2037-26-5
2320B Alkalinity
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
Alkalinity, Total as CaCO3
8650 ug/L 5000
5000
1
02/10/21 15:52
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids
48000 ug/L 25000
25000
1
02/02/21 18:47
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Pace Analytical Services -Asheville
Sulfate
ND ug/L 1000
500
1
02/03/2100:36
14808-79-8
Date: 02/11/2021 01:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 16 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns River EXP Resample
Pace Project No.: 92519331
Sample: MW-35 Lab ID: 92519331004 Collected: 01/28/21 12:17 Received: 01/29/21 08:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
4500 Chloride Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride 1090 ug/L 1000 500 1 02/01/2118:05 16887-00-6
Date: 02/11/2021 01:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 17 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns River EXP Resample
Pace Project No.: 92519331
Sample: Field Blank Lab ID: 92519331005 Collected: 01/28/21 14:48 Received: 01/29/21 08:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
02/03/2102:11
02/04/2103:31
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
02/03/2102:11
02/04/2103:31
7440-38-2
Barium
ND
ug/L
5.0
3.5
1
02/03/2102:11
02/04/2103:31
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
02/03/2102:11
02/04/2103:31
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
02/03/2102:11
02/04/2103:31
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
02/03/2102:11
02/04/2103:31
7440-47-3
Cobalt
ND
ug/L
5.0
3.6
1
02/03/2102:11
02/04/2103:31
7440-48-4
Copper
ND
ug/L
5.0
4.3
1
02/03/2102:11
02/04/2103:31
7440-50-8
Lead
ND
ug/L
5.0
4.5
1
02/03/2102:11
02/04/2103:31
7439-92-1
Nickel
ND
ug/L
5.0
3.5
1
02/03/2102:11
02/04/2103:31
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
02/03/2102:11
02/04/2103:31
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
02/03/2102:11
02/04/2103:31
7440-22-4
Vanadium
ND
ug/L
5.0
3.9
1
02/03/2102:11
02/04/2103:31
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
02/03/2102:11
02/04/2103:31
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.10
0.050
1
01/30/2101:38
02/02/2119:43
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
6.2
1
02/03/21 00:02
67-64-1
Acrylonitrile
ND
ug/L
10.0
0.90
1
02/03/21 00:02
107-13-1
Benzene
ND
ug/L
1.0
0.15
1
02/03/21 00:02
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.34
1
02/03/21 00:02
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.26
1
02/03/21 00:02
75-27-4
Bromoform
ND
ug/L
1.0
0.62
1
02/03/21 00:02
75-25-2
Bromomethane
ND
ug/L
2.0
0.62
1
02/03/21 00:02
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
3.3
1
02/03/21 00:02
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.40
1
02/03/21 00:02
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.22
1
02/03/21 00:02
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.23
1
02/03/21 00:02
108-90-7
Chloroethane
ND
ug/L
1.0
0.49
1
02/03/21 00:02
75-00-3
Chloroform
ND
ug/L
5.0
2.3
1
02/03/21 00:02
67-66-3
Chloromethane
ND
ug/L
1.0
0.39
1
02/03/21 00:02
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
0.26
1
02/03/21 00:02
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.41
1
02/03/21 00:02
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.26
1
02/03/21 00:02
106-93-4
Dibromomethane
ND
ug/L
1.0
0.46
1
02/03/21 00:02
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.29
1
02/03/21 00:02
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.26
1
02/03/21 00:02
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.54
1
02/03/21 00:02
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.27
1
02/03/21 00:02
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.34
1
02/03/21 00:02
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.24
1
02/03/21 00:02
75-35-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11 /2021 01:48 PM without the written consent of Pace Analytical Services, LLC.
IK,L1,v1
v1
Page 18 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns River EXP Resample
Pace Project No.: 92519331
Sample: Field Blank Lab ID: 92519331005 Collected: 01/28/21 14:48 Received: 01/29/21 08:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 02/11/2021 01:48 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.29
1
02/03/21 00:02
156-59-2
ND
ug/L
1.0
0.25
1
02/03/21 00:02
156-60-5
ND
ug/L
1.0
0.19
1
02/03/21 00:02
78-87-5
ND
ug/L
1.0
0.30
1
02/03/21 00:02
10061-01-5
ND
ug/L
1.0
0.31
1
02/03/21 00:02
10061-02-6
ND
ug/L
1.0
0.26
1
02/03/21 00:02
100-41-4
ND
ug/L
5.0
0.57
1
02/03/21 00:02
591-78-6
ND
ug/L
20.0
12.5
1
02/03/21 00:02
74-88-4 L1,v1
ND
ug/L
5.0
3.7
1
02/03/21 00:02
75-09-2
ND
ug/L
5.0
4.5
1
02/03/21 00:02
108-10-1
ND
ug/L
1.0
0.27
1
02/03/21 00:02
100-42-5
ND
ug/L
1.0
0.34
1
02/03/21 00:02
630-20-6
ND
ug/L
1.0
0.22
1
02/03/21 00:02
79-34-5
ND
ug/L
1.0
0.16
1
02/03/21 00:02
127-18-4
ND
ug/L
1.0
0.24
1
02/03/21 00:02
108-88-3
ND
ug/L
1.0
0.18
1
02/03/21 00:02
71-55-6
ND
ug/L
1.0
0.24
1
02/03/21 00:02
79-00-5
ND
ug/L
1.0
0.22
1
02/03/21 00:02
79-01-6
ND
ug/L
1.0
0.31
1
02/03/21 00:02
75-69-4
ND
ug/L
1.0
0.35
1
02/03/21 00:02
96-18-4
ND
ug/L
2.0
1.4
1
02/03/21 00:02
108-05-4
ND
ug/L
1.0
0.24
1
02/03/21 00:02
75-01-4
ND
ug/L
1.0
0.63
1
02/03/21 00:02
1330-20-7
106
%
70-130
1
02/03/21 00:02
460-00-4
94
%
70-130
1
02/03/21 00:02
17060-07-0
107
%
70-130
1
02/03/21 00:02
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
ND
ug/L
2.0
1.2
1
01/29/2116:21
123-91-1
106
%
70-130
1
01/29/2116:21
17060-07-0
105
%
66-133
1
01/29/2116:21
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 19 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns River EXP Resample
Pace Project No.: 92519331
Sample: MW-38
Lab ID: 92519331006 Collected:
01/28/21 13:05
Received: 01/29/21 08:20 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Iron
19600 ug/L 50.0
41.5
1
02/03/2102:11
02/04/2103:35
7439-89-6
Manganese
7780 ug/L 5.0
3.4
1
02/03/21 02:11
02/04/21 03:35
7439-96-5
7470 Mercury
Analytical Method: EPA 7470A Preparation Method:
EPA 7470A
Pace Analytical Services -Asheville
Mercury
ND ug/L 0.20
0.12
1
02/03/2118:44
02/04/2115:49
7439-97-6
8260D MSV SIM
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1,4-Dioxane (p-Dioxane)
2.7 ug/L 2.0
1.2
1
01/29/21 18:15
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
101 % 70-130
1
01/29/21 18:15
17060-07-0
Toluene-d8 (S)
98 % 66-133
1
01/29/21 18:15
2037-26-5
2320B Alkalinity
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
Alkalinity, Total as CaCO3
275000 ug/L 5000
5000
1
02/10/21 17:28
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2011
Pace Analytical Services -Asheville
Total Dissolved Solids
292000 ug/L 25000
25000
1
02/02/21 18:47
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Pace Analytical Services -Asheville
Sulfate
806J ug/L 1000
500
1
02/03/2100:51
14808-79-8
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
9010 ug/L 1000
500
1
02/01/2118:06
16887-00-6
Date: 02/11/2021 01:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 20 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns River EXP Resample
Pace Project No.: 92519331
Sample: Trip Blank Lab ID: 92519331007 Collected: 01/27/21 08:00 Received: 01/29/21 08:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Date: 02/11/2021 01:48 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
6.2
1
02/02/2123:44
67-64-1
ND
ug/L
10.0
0.90
1
02/02/2123:44
107-13-1
ND
ug/L
1.0
0.15
1
02/02/2123:44
71-43-2
ND
ug/L
1.0
0.34
1
02/02/2123:44
74-97-5
ND
ug/L
1.0
0.26
1
02/02/2123:44
75-27-4
ND
ug/L
1.0
0.62
1
02/02/2123:44
75-25-2
ND
ug/L
2.0
0.62
1
02/02/2123:44
74-83-9
ND
ug/L
5.0
3.3
1
02/02/2123:44
78-93-3
ND
ug/L
2.0
0.40
1
02/02/2123:44
75-15-0
ND
ug/L
1.0
0.22
1
02/02/2123:44
56-23-5
ND
ug/L
1.0
0.23
1
02/02/2123:44
108-90-7
ND
ug/L
1.0
0.49
1
02/02/2123:44
75-00-3
ND
ug/L
5.0
2.3
1
02/02/2123:44
67-66-3
ND
ug/L
1.0
0.39
1
02/02/2123:44
74-87-3
ND
ug/L
5.0
0.26
1
02/02/2123:44
96-12-8
ND
ug/L
1.0
0.41
1
02/02/2123:44
124-48-1
ND
ug/L
1.0
0.26
1
02/02/2123:44
106-93-4
ND
ug/L
1.0
0.46
1
02/02/2123:44
74-95-3
ND
ug/L
1.0
0.29
1
02/02/2123:44
95-50-1
ND
ug/L
1.0
0.26
1
02/02/2123:44
106-46-7
ND
ug/L
1.0
0.54
1
02/02/2123:44
110-57-6
ND
ug/L
1.0
0.27
1
02/02/2123:44
75-34-3
ND
ug/L
1.0
0.34
1
02/02/2123:44
107-06-2
ND
ug/L
1.0
0.24
1
02/02/2123:44
75-35-4
ND
ug/L
1.0
0.29
1
02/02/2123:44
156-59-2
ND
ug/L
1.0
0.25
1
02/02/2123:44
156-60-5
ND
ug/L
1.0
0.19
1
02/02/2123:44
78-87-5
ND
ug/L
1.0
0.30
1
02/02/21 23:44
10061-01-5
ND
ug/L
1.0
0.31
1
02/02/2123:44
10061-02-6
ND
ug/L
1.0
0.26
1
02/02/2123:44
100-41-4
ND
ug/L
5.0
0.57
1
02/02/2123:44
591-78-6
ND
ug/L
20.0
12.5
1
02/02/2123:44
74-88-4
ND
ug/L
5.0
3.7
1
02/02/2123:44
75-09-2
ND
ug/L
5.0
4.5
1
02/02/2123:44
108-10-1
ND
ug/L
1.0
0.27
1
02/02/2123:44
100-42-5
ND
ug/L
1.0
0.34
1
02/02/2123:44
630-20-6
ND
ug/L
1.0
0.22
1
02/02/2123:44
79-34-5
ND
ug/L
1.0
0.16
1
02/02/2123:44
127-18-4
ND
ug/L
1.0
0.24
1
02/02/2123:44
108-88-3
ND
ug/L
1.0
0.18
1
02/02/2123:44
71-55-6
ND
ug/L
1.0
0.24
1
02/02/2123:44
79-00-5
ND
ug/L
1.0
0.22
1
02/02/2123:44
79-01-6
ND
ug/L
1.0
0.31
1
02/02/2123:44
75-69-4
ND
ug/L
1.0
0.35
1
02/02/2123:44
96-18-4
ND
ug/L
2.0
1.4
1
02/02/2123:44
108-05-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
IK,L1,v1
v1
L1,v1
Page 21 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns River EXP Resample
Pace Project No.: 92519331
Sample: Trip Blank
Parameters
Lab ID: 92519331007 Collected:
Report
Results Units Limit
01/27/21 08:00
MDL DF
Received: 01/29/21 08:20 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Vinyl chloride
ND ug/L 1.0
0.24 1
02/02/21 23:44
75-01-4
Xylene (Total)
ND ug/L 1.0
0.63 1
02/02/21 23:44
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
109 % 70-130
1
02/02/21 23:44
460-00-4
1,2-Dichloroethane-d4 (S)
96 % 70-130
1
02/02/21 23:44
17060-07-0
Toluene-d8 (S)
110 % 70-130
1
02/02/21 23:44
2037-26-5
8260D MSV SIM
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1,4-Dioxane (p-Dioxane)
ND ug/L 2.0
1.2 1
01/29/21 15:43
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
103 % 70-130
1
01/29/21 15:43
17060-07-0
Toluene-d8 (S)
104 % 66-133
1
01/29/21 15:43
2037-26-5
Date: 02/11/2021 01:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 22 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns River EXP Resample
Pace Project No.: 92519331
QC Batch: 597300 Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92519331001, 92519331002, 92519331003, 92519331004, 92519331006
METHOD BLANK: 3149645 Matrix: Water
Associated Lab Samples: 92519331001, 92519331002, 92519331003, 92519331004, 92519331006
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Mercury ug/L ND 0.20 0.12 02/04/2114:50
LABORATORY CONTROL SAMPLE: 3149646
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 2.5 2.7 107 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3149647 3149648
MS MSD
92519357015 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND 2.5 2.5 2.7 2.7 104 107 75-125 3 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11 /2021 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 23 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns River EXP Resample
Pace Project No.: 92519331
QC Batch: 596489 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92519331001, 92519331002, 92519331003
METHOD BLANK: 3145952 Matrix:
Associated Lab Samples: 92519331001, 92519331002, 92519331003
Blank
Parameter Units Result
Water
Reporting
Limit
MDL
Analyzed
Antimony
ug/L
ND
5.0
3.0
02/01/2101:20
Arsenic
ug/L
ND
10.0
4.7
02/01/2101:20
Barium
ug/L
ND
5.0
3.5
02/01/2101:20
Beryllium
ug/L
ND
1.0
0.70
02/01/2101:20
Cadmium
ug/L
ND
1.0
0.40
02/01/2101:20
Chromium
ug/L
ND
5.0
3.7
02/01/2101:20
Cobalt
ug/L
ND
5.0
3.6
02/01/2101:20
Copper
ug/L
ND
5.0
4.3
02/01/2101:20
Iron
ug/L
ND
50.0
41.5
02/01/2101:20
Lead
ug/L
ND
5.0
4.5
02/01/2101:20
Manganese
ug/L
ND
5.0
3.4
02/01/2101:20
Nickel
ug/L
ND
5.0
3.5
02/01/2101:20
Selenium
ug/L
ND
10.0
4.7
02/01/2101:20
Silver
ug/L
ND
5.0
2.5
02/01/2101:20
Vanadium
ug/L
ND
5.0
3.9
02/01/2101:20
Zinc
ug/L
ND
10.0
9.5
02/01/2101:20
LABORATORY CONTROL SAMPLE:
Parameter
3145953
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
500
441
88
80-120
Arsenic
ug/L
500
461
92
80-120
Barium
ug/L
500
466
93
80-120
Beryllium
ug/L
500
472
94
80-120
Cadmium
ug/L
500
460
92
80-120
Chromium
ug/L
500
462
92
80-120
Cobalt
ug/L
500
473
95
80-120
Copper
ug/L
500
470
94
80-120
Iron
ug/L
5000
4850
97
80-120
Lead
ug/L
500
469
94
80-120
Manganese
ug/L
500
461
92
80-120
Nickel
ug/L
500
466
93
80-120
Selenium
ug/L
500
452
90
80-120
Silver
ug/L
250
222
89
80-120
Vanadium
ug/L
500
468
94
80-120
Zinc
ug/L
500
470
94
80-120
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11 /2021 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 24 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
Johns River EXP Resample
92519331
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3145954
3145955
MS
MSD
92519331001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
500
500
460
464
92
93
75-125
1
20
Arsenic
ug/L
ND
500
500
488
485
98
97
75-125
1
20
Barium
ug/L
25.0
500
500
514
508
98
97
75-125
1
20
Beryllium
ug/L
ND
500
500
496
490
99
98
75-125
1
20
Cadmium
ug/L
ND
500
500
495
493
99
99
75-125
0
20
Chromium
ug/L
ND
500
500
516
511
103
102
75-125
1
20
Cobalt
ug/L
ND
500
500
492
492
98
98
75-125
0
20
Copper
ug/L
ND
500
500
501
495
100
99
75-125
1
20
Iron
ug/L
444
5000
5000
5570
5510
102
101
75-125
1
20
Lead
ug/L
ND
500
500
491
490
98
98
75-125
0
20
Manganese
ug/L
10.3
500
500
513
509
101
100
75-125
1
20
Nickel
ug/L
ND
500
500
492
492
98
98
75-125
0
20
Selenium
ug/L
ND
500
500
503
504
101
101
75-125
0
20
Silver
ug/L
ND
250
250
241
238
96
95
75-125
1
20
Vanadium
ug/L
ND
500
500
501
494
100
99
75-125
2
20
Zinc
ug/L
ND
500
500
506
506
101
101
75-125
0
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11 /2021 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 25 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns River EXP Resample
Pace Project No.: 92519331
QC Batch: 597049 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92519331004, 92519331005, 92519331006
METHOD BLANK: 3148546 Matrix:
Associated Lab Samples: 92519331004, 92519331005, 92519331006
Blank
Parameter Units Result
Water
Reporting
Limit
MDL
Analyzed
Antimony
ug/L
ND
5.0
3.0
02/04/2103:02
Arsenic
ug/L
ND
10.0
4.7
02/04/2103:02
Barium
ug/L
ND
5.0
3.5
02/04/2103:02
Beryllium
ug/L
ND
1.0
0.70
02/04/2103:02
Cadmium
ug/L
ND
1.0
0.40
02/04/2103:02
Chromium
ug/L
ND
5.0
3.7
02/04/2103:02
Cobalt
ug/L
ND
5.0
3.6
02/04/2103:02
Copper
ug/L
ND
5.0
4.3
02/04/2103:02
Iron
ug/L
ND
50.0
41.5
02/04/2103:02
Lead
ug/L
ND
5.0
4.5
02/04/2103:02
Manganese
ug/L
ND
5.0
3.4
02/04/2103:02
Nickel
ug/L
ND
5.0
3.5
02/04/2103:02
Selenium
ug/L
ND
10.0
4.7
02/04/2103:02
Silver
ug/L
ND
5.0
2.5
02/04/2103:02
Vanadium
ug/L
ND
5.0
3.9
02/04/2103:02
Zinc
ug/L
ND
10.0
9.5
02/04/2103:02
LABORATORY CONTROL SAMPLE:
Parameter
3148547
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
500
482
96
80-120
Arsenic
ug/L
500
489
98
80-120
Barium
ug/L
500
472
94
80-120
Beryllium
ug/L
500
480
96
80-120
Cadmium
ug/L
500
482
96
80-120
Chromium
ug/L
500
468
94
80-120
Cobalt
ug/L
500
475
95
80-120
Copper
ug/L
500
460
92
80-120
Iron
ug/L
5000
4900
98
80-120
Lead
ug/L
500
473
95
80-120
Manganese
ug/L
500
443
89
80-120
Nickel
ug/L
500
490
98
80-120
Selenium
ug/L
500
445
89
80-120
Silver
ug/L
250
230
92
80-120
Vanadium
ug/L
500
448
90
80-120
Zinc
ug/L
500
497
99
80-120
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11 /2021 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 26 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
Johns River EXP Resample
92519331
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3148548
3148549
MS
MSD
92519589001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
5.4
500
500
554
538
110
106
75-125
3
20
Arsenic
ug/L
83.4
500
500
645
621
112
107
75-125
4
20
Barium
ug/L
328
500
500
820
807
98
96
75-125
2
20
Beryllium
ug/L
ND
500
500
502
492
100
98
75-125
2
20
Cadmium
ug/L
ND
500
500
525
515
105
103
75-125
2
20
Chromium
ug/L
41.5
500
500
521
512
96
94
75-125
2
20
Cobalt
ug/L
ND
500
500
473
466
95
93
75-125
2
20
Copper
ug/L
ND
500
500
509
498
101
99
75-125
2
20
Iron
ug/L
512
5000
5000
5470
5390
99
98
75-125
2
20
Lead
ug/L
ND
500
500
475
470
94
93
75-125
1
20
Manganese
ug/L
1550
500
500
1970
1940
83
77
75-125
1
20
Nickel
ug/L
ND
500
500
489
481
97
96
75-125
2
20
Selenium
ug/L
ND
500
500
90.7
95.4
18
19
75-125
5
20 M1
Silver
ug/L
ND
250
250
260
255
104
102
75-125
2
20
Vanadium
ug/L
15.9
500
500
494
483
96
93
75-125
2
20
Zinc
ug/L
ND
500
500
501
492
99
97
75-125
2
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11 /2021 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 27 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns River EXP Resample
Pace Project No.: 92519331
QC Batch: 596491 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92519331001, 92519331002, 92519331003, 92519331004, 92519331005
METHOD BLANK: 3145960 Matrix: Water
Associated Lab Samples: 92519331001, 92519331002, 92519331003, 92519331004, 92519331005
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Thallium ug/L ND 0.10 0.050 02/02/2118:25
LABORATORY CONTROL SAMPLE: 3145961
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Thallium ug/L 10 10.2 102 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3145962 3145963
MS MSD
92519400005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Thallium ug/L ND 10 10 10.2 10.4 102 103 75-125 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11 /2021 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 28 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns River EXP Resample
Pace Project No.: 92519331
QC Batch: 597066 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92519331001, 92519331002, 92519331003
METHOD BLANK: 3148748 Matrix:
Associated Lab Samples: 92519331001, 92519331002, 92519331003
Blank
Parameter Units Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.34
02/02/21 22:34
1,1,1-Trichloroethane
ug/L
ND
1.0
0.18
02/02/21 22:34
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
02/02/21 22:34
1,1,2-Trichloroethane
ug/L
ND
1.0
0.24
02/02/21 22:34
1,1-Dichloroethane
ug/L
ND
1.0
0.27
02/02/21 22:34
1,1-Dichloroethene
ug/L
ND
1.0
0.24
02/02/21 22:34
1,2,3-Trichloropropane
ug/L
ND
1.0
0.35
02/02/21 22:34
1,2-Dibromo-3-chloropropane
ug/L
ND
5.0
0.26
02/02/21 22:34
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.26
02/02/21 22:34
1,2-Dichlorobenzene
ug/L
ND
1.0
0.29
02/02/21 22:34
1,2-Dichloroethane
ug/L
ND
1.0
0.34
02/02/21 22:34
1,2-Dichloropropane
ug/L
ND
1.0
0.19
02/02/21 22:34
1,4-Dichlorobenzene
ug/L
ND
1.0
0.26
02/02/21 22:34
2-Butanone (MEK)
ug/L
ND
5.0
3.3
02/02/21 22:34
2-Hexanone
ug/L
ND
5.0
0.57
02/02/21 22:34
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
4.5
02/02/21 22:34
Acetone
ug/L
ND
25.0
6.2
02/02/21 22:34
Acrylonitrile
ug/L
ND
10.0
0.90
02/02/21 22:34
Benzene
ug/L
ND
1.0
0.15
02/02/21 22:34
Bromochloromethane
ug/L
ND
1.0
0.34
02/02/21 22:34 IK,v1
Bromodichloromethane
ug/L
ND
1.0
0.26
02/02/21 22:34
Bromoform
ug/L
ND
1.0
0.62
02/02/21 22:34
Bromomethane
ug/L
ND
2.0
0.62
02/02/21 22:34
Carbon disulfide
ug/L
ND
2.0
0.40
02/02/21 22:34 v1
Carbon tetrachloride
ug/L
ND
1.0
0.22
02/02/21 22:34
Chlorobenzene
ug/L
ND
1.0
0.23
02/02/21 22:34
Chloroethane
ug/L
ND
1.0
0.49
02/02/21 22:34
Chloroform
ug/L
ND
5.0
2.3
02/02/21 22:34
Chloromethane
ug/L
ND
1.0
0.39
02/02/21 22:34
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.29
02/02/21 22:34
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.30
02/02/21 22:34
Dibromochloromethane
ug/L
ND
1.0
0.41
02/02/21 22:34
Dibromomethane
ug/L
ND
1.0
0.46
02/02/21 22:34
Ethylbenzene
ug/L
ND
1.0
0.26
02/02/21 22:34
lodomethane
ug/L
ND
20.0
12.5
02/02/21 22:34 v1
Methylene Chloride
ug/L
ND
5.0
3.7
02/02/21 22:34
Styrene
ug/L
ND
1.0
0.27
02/02/21 22:34
Tetrachloroethene
ug/L
ND
1.0
0.16
02/02/21 22:34
Tetrahydrofuran
ug/L
ND
10.0
1.9
02/02/21 22:34
Toluene
ug/L
ND
1.0
0.24
02/02/21 22:34
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11/2021 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns River EXP Resample
Pace Project No.: 92519331
METHOD BLANK: 3148748 Matrix:
Associated Lab Samples: 92519331001, 92519331002, 92519331003
Blank
Parameter Units Result
Water
Reporting
Limit
MDL
Analyzed
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.25
02/02/21 22:34
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.31
02/02/21 22:34
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.54
02/02/21 22:34
Trichloroethene
ug/L
ND
1.0
0.22
02/02/21 22:34
Trichlorofluoromethane
ug/L
ND
1.0
0.31
02/02/21 22:34
Vinyl acetate
ug/L
ND
2.0
1.4
02/02/21 22:34
Vinyl chloride
ug/L
ND
1.0
0.24
02/02/21 22:34
Xylene (Total)
ug/L
ND
1.0
0.63
02/02/21 22:34
1,2-Dichloroethane-d4 (S)
%
94
70-130
02/02/21 22:34
4-Bromofluorobenzene (S)
%
104
70-130
02/02/21 22:34
Toluene-d8 (S)
%
106
70-130
02/02/21 22:34
IA_1 Z�7:7\Cwl:�-�K.�i.rr:Zwl�ylul»�c71Cf:�l�]
Parameter
Qualifiers
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
45.5
91
70-130
1,1,1-Trichloroethane
ug/L
50
53.4
107
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
47.1
94
70-130
1,1,2-Trichloroethane
ug/L
50
52.3
105
70-130
1,1-Dichloroethane
ug/L
50
55.8
112
70-130
1,1-Dichloroethene
ug/L
50
55.4
111
70-132
1,2,3-Trichloropropane
ug/L
50
43.6
87
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
45.2
90
70-132
1,2-Dibromoethane (EDB)
ug/L
50
51.8
104
70-130
1,2-Dichlorobenzene
ug/L
50
47.0
94
70-130
1,2-Dichloroethane
ug/L
50
52.8
106
70-130
1,2-Dichloropropane
ug/L
50
53.4
107
70-130
1,4-Dichlorobenzene
ug/L
50
46.7
93
70-130
2-Butanone (MEK)
ug/L
100
99.3
99
70-133
2-Hexanone
ug/L
100
88.4
88
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
100
86.6
87
70-130
Acetone
ug/L
100
106
106
70-144
Acrylonitrile
ug/L
250
274
110
70-130
Benzene
ug/L
50
49.6
99
70-130
Bromochloromethane
ug/L
50
70.1
140
70-1301K,L1,v1
Bromodichloromethane
ug/L
50
49.7
99
70-130
Bromoform
ug/L
50
46.0
92
70-131
Bromomethane
ug/L
50
49.5
99
30-177
Carbon disulfide
ug/L
50
60.1
120
70-133 v1
Carbon tetrachloride
ug/L
50
48.3
97
70-130
Chlorobenzene
ug/L
50
47.2
94
70-130
Chloroethane
ug/L
50
50.1
100
46-131
Chloroform
ug/L
50
54.2
108
70-130
Chloromethane
ug/L
50
44.3
89
49-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11/2021 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Johns River EXP Resample
Pace Project No.: 92519331
LABORATORY CONTROL SAMPLE: 3148749
Parameter
QUALITY CONTROL DATA
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
cis-1,2-Dichloroethene
ug/L
50
56.7
113
70-130
cis-1,3-Dichloropropene
ug/L
50
55.5
111
70-130
Dibromochloromethane
ug/L
50
50.8
102
70-130
Dibromomethane
ug/L
50
49.1
98
70-130
Ethylbenzene
ug/L
50
46.5
93
70-130
lodomethane
ug/L
100
143
143
47-140 L1,v1
Methylene Chloride
ug/L
50
50.9
102
68-130
Styrene
ug/L
50
47.0
94
70-130
Tetrachloroethene
ug/L
50
43.2
86
70-130
Tetrahydrofuran
ug/L
500
491
98
70-130
Toluene
ug/L
50
48.5
97
70-130
trans-1,2-Dichloroethene
ug/L
50
56.8
114
70-130
trans- 1,3-Dichloropropene
ug/L
50
52.7
105
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
45.4
91
25-200
Trichloroethene
ug/L
50
51.5
103
70-130
Trichlorofluoromethane
ug/L
50
44.1
88
61-130
Vinyl acetate
ug/L
100
117
117
70-140
Vinyl chloride
ug/L
50
46.4
93
59-142
Xylene (Total)
ug/L
150
143
96
70-130
1,2-Dichloroethane-d4 (S)
%
97
70-130
4-Bromofluorobenzene (S)
%
104
70-130
Toluene-d8 (S)
%
99
70-130
MATRIX SPIKE SAMPLE:
Parameter
3148751
Units
92519414002
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
15.9
79
70-135
1,1,1-Trichloroethane
ug/L
ND
20
18.8
94
70-148
1,1,2,2-Tetrachloroethane
ug/L
ND
20
17.2
86
70-131
1,1,2-Trichloroethane
ug/L
ND
20
18.8
94
70-136
1,1-Dichloroethane
ug/L
ND
20
18.4
92
70-147
1,1-Dichloroethene
ug/L
ND
20
13.4
67
70-158 M1
1,2,3-Trichloropropane
ug/L
ND
20
17.4
87
67-137
1,2-Dibromo-3-chloropropane
ug/L
ND
20
16.0
80
69-136
1,2-Dibromoethane (EDB)
ug/L
ND
20
17.9
90
70-137
1,2-Dichlorobenzene
ug/L
ND
20
18.0
90
70-133
1,2-Dichloroethane
ug/L
ND
20
18.0
90
67-138
1,2-Dichloropropane
ug/L
ND
20
19.7
99
70-138
1,4-Dichlorobenzene
ug/L
ND
20
17.8
89
70-133
2-Butanone (MEK)
ug/L
ND
40
33.9
85
61-147
2-Hexanone
ug/L
ND
40
34.0
85
67-139
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
33.5
84
67-136
Acetone
ug/L
ND
40
37.9
95
55-159
Acrylonitrile
ug/L
ND
100
97.9
98
68-140
Benzene
ug/L
ND
20
17.9
89
67-150
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11/2021 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns River EXP Resample
Pace Project No.: 92519331
MATRIX SPIKE SAMPLE:
3148751
92519414002
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Bromochloromethane
ug/L
ND
20
24.7
123
70-1461K,v1
Bromodichloromethane
ug/L
ND
20
18.7
93
70-138
Bromoform
ug/L
ND
20
15.8
79
57-138
Bromomethane
ug/L
ND
20
10.4
52
10-200
Carbon disulfide
ug/L
ND
20
10.8
54
70-152 M1,v1
Carbon tetrachloride
ug/L
ND
20
18.2
91
70-147
Chlorobenzene
ug/L
ND
20
18.1
90
70-137
Chloroethane
ug/L
ND
20
7.2
36
51-166 M1
Chloroform
ug/L
ND
20
19.5
97
70-144
Chloromethane
ug/L
ND
20
2.4
12
24-161 M1
cis-1,2-Dichloroethene
ug/L
ND
20
20.1
101
67-148
cis-1,3-Dichloropropene
ug/L
ND
20
18.6
93
70-142
Dibromochloromethane
ug/L
ND
20
16.7
83
68-138
Dibromomethane
ug/L
ND
20
18.4
92
70-134
Ethylbenzene
ug/L
ND
20
18.2
91
68-143
lodomethane
ug/L
ND
40
16.1J
40
20-161 v1
Methylene Chloride
ug/L
ND
20
16.9
85
64-148
Styrene
ug/L
ND
20
18.3
91
70-136
Tetrachloroethene
ug/L
ND
20
17.5
87
70-139
Tetrahydrofuran
ug/L
ND
200
179
90
65-145
Toluene
ug/L
ND
20
18.0
90
47-157
trans-1,2-Dichloroethene
ug/L
ND
20
16.7
83
70-149
trans- 1,3-Dichloropropene
ug/L
ND
20
17.7
89
70-138
trans-1,4-Dichloro-2-butene
ug/L
ND
20
15.1
76
31-145
Trichloroethene
ug/L
ND
20
18.8
94
70-149
Trichlorofluoromethane
ug/L
ND
20
8.3
42
61-154 M1
Vinyl acetate
ug/L
ND
40
35.5
89
48-156
Vinyl chloride
ug/L
ND
20
2.8
14
55-172 M1
Xylene (Total)
ug/L
ND
60
55.7
93
66-145
1,2-Dichloroethane-d4 (S)
%
101
70-130
4-Bromofluorobenzene (S)
%
105
70-130
Toluene-d8(S)
%
102
70-130
SAMPLE DUPLICATE: 3148750
92519414001
Dup
Max
Parameter
Units
Result
Result RPD
RPD Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,1-Trichloroethane
ug/L
ND
ND
30
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,2-Trichloroethane
ug/L
ND
ND
30
1,1-Dichloroethane
ug/L
ND
ND
30
1,1-Dichloroethene
ug/L
ND
ND
30
1,2,3-Trichloropropane
ug/L
ND
ND
30
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
30
1,2-Dibromoethane (EDB)
ug/L
ND
ND
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11/2021 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns River EXP Resample
Pace Project No.: 92519331
SAMPLE DUPLICATE: 3148750
Parameter
Units
92519414001
Result
Dup
Result RPD
Max
RPD Qualifiers
1,2-Dichlorobenzene
ug/L
ND
ND
30
1,2-Dichloroethane
ug/L
ND
ND
30
1,2-Dichloropropane
ug/L
ND
ND
30
1,4-Dichlorobenzene
ug/L
ND
ND
30
2-Butanone (MEK)
ug/L
ND
ND
30
2-Hexanone
ug/L
ND
ND
30
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
30
Acetone
ug/L
ND
ND
30
Acrylonitrile
ug/L
ND
ND
30
Benzene
ug/L
ND
ND
30
Bromochloromethane
ug/L
ND
ND
301K,v1
Bromodichloromethane
ug/L
ND
ND
30
Bromoform
ug/L
ND
ND
30
Bromomethane
ug/L
ND
ND
30
Carbon disulfide
ug/L
ND
ND
30 v1
Carbon tetrachloride
ug/L
ND
ND
30
Chlorobenzene
ug/L
ND
ND
30
Chloroethane
ug/L
ND
ND
30
Chloroform
ug/L
ND
ND
30
Chloromethane
ug/L
ND
ND
30
cis-1,2-Dichloroethene
ug/L
ND
ND
30
cis-1,3-Dichloropropene
ug/L
ND
ND
30
Dibromochloromethane
ug/L
ND
ND
30
Dibromomethane
ug/L
ND
ND
30
Ethylbenzene
ug/L
ND
ND
30
lodomethane
ug/L
ND
ND
30 v1
Methylene Chloride
ug/L
ND
ND
30
Styrene
ug/L
ND
ND
30
Tetrachloroethene
ug/L
ND
ND
30
Tetrahydrofuran
ug/L
ND
ND
30
Toluene
ug/L
ND
ND
30
trans-1,2-Dichloroethene
ug/L
ND
ND
30
trans- 1,3-Dichloropropene
ug/L
ND
ND
30
trans-1,4-Dichloro-2-butene
ug/L
ND
ND
30
Trichloroethene
ug/L
ND
ND
30
Trichlorofluoromethane
ug/L
ND
ND
30
Vinyl acetate
ug/L
ND
ND
30
Vinyl chloride
ug/L
ND
ND
30
Xylene (Total)
ug/L
ND
ND
30
1,2-Dichloroethane-d4 (S)
%
95
95
4-Bromofluorobenzene (S)
%
105
106
Toluene-d8 (S)
%
108
107
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11 /2021 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 33 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns River EXP Resample
Pace Project No.: 92519331
QC Batch: 597067 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92519331005, 92519331007
METHOD BLANK: 3148755
Associated Lab Samples: 92519331005, 92519331007
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.34
02/02/21 22:51
1,1,1-Trichloroethane
ug/L
ND
1.0
0.18
02/02/21 22:51
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
02/02/21 22:51
1,1,2-Trichloroethane
ug/L
ND
1.0
0.24
02/02/21 22:51
1,1-Dichloroethane
ug/L
ND
1.0
0.27
02/02/21 22:51
1,1-Dichloroethene
ug/L
ND
1.0
0.24
02/02/21 22:51
1,2,3-Trichloropropane
ug/L
ND
1.0
0.35
02/02/21 22:51
1,2-Dibromo-3-chloropropane
ug/L
ND
5.0
0.26
02/02/21 22:51
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.26
02/02/21 22:51
1,2-Dichlorobenzene
ug/L
ND
1.0
0.29
02/02/21 22:51
1,2-Dichloroethane
ug/L
ND
1.0
0.34
02/02/21 22:51
1,2-Dichloropropane
ug/L
ND
1.0
0.19
02/02/21 22:51
1,4-Dichlorobenzene
ug/L
ND
1.0
0.26
02/02/21 22:51
2-Butanone (MEK)
ug/L
ND
5.0
3.3
02/02/21 22:51
2-Hexanone
ug/L
ND
5.0
0.57
02/02/21 22:51
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
4.5
02/02/21 22:51
Acetone
ug/L
ND
25.0
6.2
02/02/21 22:51
Acrylonitrile
ug/L
ND
10.0
0.90
02/02/21 22:51
Benzene
ug/L
ND
1.0
0.15
02/02/21 22:51
Bromochloromethane
ug/L
ND
1.0
0.34
02/02/21 22:51
Bromodichloromethane
ug/L
ND
1.0
0.26
02/02/21 22:51
Bromoform
ug/L
ND
1.0
0.62
02/02/21 22:51
Bromomethane
ug/L
ND
2.0
0.62
02/02/21 22:51
Carbon disulfide
ug/L
ND
2.0
0.40
02/02/21 22:51
Carbon tetrachloride
ug/L
ND
1.0
0.22
02/02/21 22:51
Chlorobenzene
ug/L
ND
1.0
0.23
02/02/21 22:51
Chloroethane
ug/L
ND
1.0
0.49
02/02/21 22:51
Chloroform
ug/L
ND
5.0
2.3
02/02/21 22:51
Chloromethane
ug/L
ND
1.0
0.39
02/02/21 22:51
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.29
02/02/21 22:51
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.30
02/02/21 22:51
Dibromochloromethane
ug/L
ND
1.0
0.41
02/02/21 22:51
Dibromomethane
ug/L
ND
1.0
0.46
02/02/21 22:51
Ethylbenzene
ug/L
ND
1.0
0.26
02/02/21 22:51
lodomethane
ug/L
ND
20.0
12.5
02/02/21 22:51
Methylene Chloride
ug/L
ND
5.0
3.7
02/02/21 22:51
Styrene
ug/L
ND
1.0
0.27
02/02/21 22:51
Tetrachloroethene
ug/L
ND
1.0
0.16
02/02/21 22:51
Toluene
ug/L
ND
1.0
0.24
02/02/21 22:51
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.25
02/02/21 22:51
Qualifiers
IK,v1
v1
v1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11 /2021 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 34 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Johns River EXP Resample
Pace Project No.: 92519331
METHOD BLANK: 3148755
Associated Lab Samples: 92519331005, 92519331007
Parameter
Units
trans- 1,3-Dichloropropene
ug/L
trans-1,4-Dichloro-2-butene
ug/L
Trichloroethene
ug/L
Trichlorofluoromethane
ug/L
Vinyl acetate
ug/L
Vinyl chloride
ug/L
Xylene (Total)
ug/L
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
LABORATORY CONTROL SAMPLE: 3148756
Parameter
QUALITY CONTROL DATA
Matrix: Water
Blank
Result
Reporting
Limit
ND
1.0
ND
1.0
ND
1.0
ND
1.0
ND
2.0
ND
1.0
ND
1.0
93
70-130
104
70-130
107
70-130
MDL Analyzed
0.31
02/02/21 22:51
0.54
02/02/21 22:51
0.22
02/02/21 22:51
0.31
02/02/21 22:51
1.4
02/02/21 22:51
0.24
02/02/21 22:51
0.63
02/02/21 22:51
02/02/21 22:51
02/02/21 22:51
02/02/21 22:51
Qualifiers
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
47.7
95
70-130
1,1,1-Trichloroethane
ug/L
50
53.5
107
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
48.5
97
70-130
1,1,2-Trichloroethane
ug/L
50
53.8
108
70-130
1,1-Dichloroethane
ug/L
50
57.0
114
70-130
1,1-Dichloroethene
ug/L
50
52.1
104
70-132
1,2,3-Trichloropropane
ug/L
50
44.5
89
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
48.7
97
70-132
1,2-Dibromoethane (EDB)
ug/L
50
51.6
103
70-130
1,2-Dichlorobenzene
ug/L
50
49.0
98
70-130
1,2-Dichloroethane
ug/L
50
53.4
107
70-130
1,2-Dichloropropane
ug/L
50
54.1
108
70-130
1,4-Dichlorobenzene
ug/L
50
48.0
96
70-130
2-Butanone (MEK)
ug/L
100
106
106
70-133
2-Hexanone
ug/L
100
88.5
89
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
100
90.8
91
70-130
Acetone
ug/L
100
109
109
70-144
Acrylonitrile
ug/L
250
284
113
70-130
Benzene
ug/L
50
51.1
102
70-130
Bromochloromethane
ug/L
50
69.9
140
70-1301K,L1,v1
Bromodichloromethane
ug/L
50
50.7
101
70-130
Bromoform
ug/L
50
46.0
92
70-131
Bromomethane
ug/L
50
48.1
96
30-177
Carbon disulfide
ug/L
50
60.8
122
70-133 v1
Carbon tetrachloride
ug/L
50
50.4
101
70-130
Chlorobenzene
ug/L
50
48.3
97
70-130
Chloroethane
ug/L
50
52.5
105
46-131
Chloroform
ug/L
50
54.8
110
70-130
Chloromethane
ug/L
50
46.2
92
49-130
cis-1,2-Dichloroethene
ug/L
50
57.7
115
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11/2021 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 50

Pace Analytical Services, LLC
lac,
Analyilcal ® 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: Johns River EXP Resample
Pace Project No.: 92519331
LABORATORY CONTROL SAMPLE:
Parameter
3148756
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
cis-1,3-Dichloropropene
ug/L
50
56.4
113
70-130
Dibromochloromethane
ug/L
50
51.6
103
70-130
Dibromomethane
ug/L
50
52.0
104
70-130
Ethylbenzene
ug/L
50
46.4
93
70-130
lodomethane
ug/L
100
145
145
47-140 L1,v1
Methylene Chloride
ug/L
50
51.1
102
68-130
Styrene
ug/L
50
48.3
97
70-130
Tetrachloroethene
ug/L
50
44.3
89
70-130
Toluene
ug/L
50
49.5
99
70-130
trans-1,2-Dichloroethene
ug/L
50
56.2
112
70-130
trans- 1,3-Dichloropropene
ug/L
50
54.1
108
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
46.7
93
25-200
Trichloroethene
ug/L
50
53.4
107
70-130
Trichlorofluoromethane
ug/L
50
45.3
91
61-130
Vinyl acetate
ug/L
100
118
118
70-140
Vinyl chloride
ug/L
50
46.6
93
59-142
Xylene (Total)
ug/L
150
143
95
70-130
1,2-Dichloroethane-d4 (S)
%
97
70-130
4-Bromofluorobenzene (S)
%
103
70-130
Toluene-d8(S)
%
101
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3148757
MS
92519414005 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3148758
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
17.9
14.3
90
72
70-135
22
30
1,1,1-Trichloroethane
ug/L
ND
20
20
21.0
17.8
105
89
70-148
17
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
19.4
15.9
97
80
70-131
20
30
1,1,2-Trichloroethane
ug/L
ND
20
20
20.9
17.4
104
87
70-136
18
30
1,1-Dichloroethane
ug/L
ND
20
20
21.4
18.2
107
91
70-147
16
30
1,1-Dichloroethene
ug/L
ND
20
20
14.6
12.4
73
62
70-158
16
30 M1
1,2,3-Trichloropropane
ug/L
ND
20
20
17.6
15.4
88
77
67-137
14
30
1,2-Dibromo-3-
ug/L
ND
20
20
18.6
16.0
93
80
69-136
15
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
19.3
15.7
97
79
70-137
21
30
1,2-Dichlorobenzene
ug/L
ND
20
20
20.6
16.8
103
84
70-133
20
30
1,2-Dichloroethane
ug/L
ND
20
20
20.6
17.5
103
87
67-138
16
30
1,2-Dichloropropane
ug/L
ND
20
20
22.5
18.4
112
92
70-138
20
30
1,4-Dichlorobenzene
ug/L
ND
20
20
20.7
17.5
99
83
70-133
17
30
2-Butanone (MEK)
ug/L
ND
40
40
38.1
31.1
95
78
61-147
20
30
2-Hexanone
ug/L
ND
40
40
36.1
29.3
90
73
67-139
21
30
4-Methyl-2-pentanone
ug/L
ND
40
40
37.7
31.1
91
74
67-136
19
30
(MIBK)
Acetone ug/L
ND 40 40 47.5 37.6 119 94 55-159 23
30
Acrylonitrile ug/L
ND 100 100 110 87.3 110 87 68-140 23
30
Benzene ug/L
10.6 20 20 30.5 27.9 100 87 67-150 9
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11/2021 01:48 PM
without the written consent of Pace Analytical Services, LLC.
Page 36 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns River EXP Resample
Pace Project No.: 92519331
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3148757
MS
92519414005 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3148758
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
Bromochloromethane
ug/L
ND
20
20
26.8
22.9
134
114
70-146
16
30 IK,v1
Bromodichloromethane
ug/L
ND
20
20
20.8
17.7
104
88
70-138
16
30
Bromoform
ug/L
ND
20
20
16.8
13.6
84
68
57-138
21
30
Bromomethane
ug/L
ND
20
20
9.3
7.4
46
37
10-200
22
30
Carbon disulfide
ug/L
ND
20
20
12.7
10.5
64
52
70-152
20
30 M1,v1
Carbon tetrachloride
ug/L
ND
20
20
20.9
17.2
104
86
70-147
19
30
Chlorobenzene
ug/L
ND
20
20
24.3
20.9
103
85
70-137
15
30
Chloroethane
ug/L
ND
20
20
8.5
7.4
43
37
51-166
15
30 M1
Chloroform
ug/L
ND
20
20
20.5
18.6
103
93
70-144
10
30
Chloromethane
ug/L
ND
20
20
2.4
2.1
12
11
24-161
13
30 M1
cis-1,2-Dichloroethene
ug/L
ND
20
20
22.5
19.5
113
98
67-148
14
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
21.5
18.3
108
91
70-142
16
30
Dibromochloromethane
ug/L
ND
20
20
18.7
14.7
94
74
68-138
24
30
Dibromomethane
ug/L
ND
20
20
21.5
18.5
108
92
70-134
15
30
Ethylbenzene
ug/L
ND
20
20
20.6
17.1
103
85
68-143
19
30
lodomethane
ug/L
ND
40
40
24.4
21.4
61
53
20-161
13
30 v1
Methylene Chloride
ug/L
ND
20
20
21.2
17.2
96
76
64-148
21
30
Styrene
ug/L
ND
20
20
20.4
17.2
102
86
70-136
17
30
Tetrachloroethene
ug/L
ND
20
20
18.2
15.6
91
78
70-139
15
30
Toluene
ug/L
ND
20
20
21.4
17.7
106
87
47-157
19
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
19.4
16.3
97
82
70-149
18
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
21.0
16.9
105
84
70-138
22
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
17.1
13.9
85
69
31-145
21
30
Trichloroethene
ug/L
ND
20
20
21.7
18.0
108
90
70-149
19
30
Trichlorofluoromethane
ug/L
ND
20
20
9.9
8.0
49
40
61-154
21
30 M1
Vinyl acetate
ug/L
ND
40
40
42.2
31.6
105
79
48-156
29
30
Vinyl chloride
ug/L
ND
20
20
3.3
2.7
17
13
55-172
21
30 M1
Xylene (Total)
ug/L
ND
60
60
64.3
54.6
107
91
66-145
16
30
1,2-Dichloroethane-d4 (S)
%
97
96
70-130
4-Bromofluorobenzene (S)
%
105
104
70-130
Toluene-d8 (S)
%
104
104
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11 /2021 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 37 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns River EXP Resample
Pace Project No.: 92519331
QC Batch: 596433 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92519331001, 92519331002, 92519331003, 92519331004, 92519331005, 92519331006, 92519331007
METHOD BLANK: 3145582
Matrix:
Water
Associated Lab Samples:
92519331001, 92519331002, 92519331003, 92519331004, 92519331005, 92519331006, 92519331007
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
1.2 01/29/21 12:34
1,2-Dichloroethane-d4 (S)
%
100
70-130
01/29/21 12:34
Toluene-d8 (S)
%
103
66-133
01/29/21 12:34
LABORATORY CONTROL SAMPLE: 3145583
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 18.9 94 70-130
1,2-Dichloroethane-d4 (S) % 102 70-130
Toluene-d8(S) % 102 66-133
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3145584
3145585
MS
MSD
92519331001 Spike
Spike MS MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result
% Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L ND 20
20 19.6 19.2
98
96
64-141
2 30
1,2-Dichloroethane-d4 (S)
%
99
101
70-130
30
Toluene-d8 (S)
%
100
100
66-133
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11 /2021 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 38 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns River EXP Resample
Pace Project No.: 92519331
QC Batch: 598516 Analysis Method: SM 2320B-2011
QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92519331001, 92519331002
METHOD BLANK: 3155741 Matrix: Water
Associated Lab Samples: 92519331001, 92519331002
Blank Reporting
Parameter Units Result Limit
Alkalinity, Total as CaCO3 ug/L ND 5000
LABORATORY CONTROL SAMPLE: 3155742
Spike LCS
Parameter Units Conc. Result
Alkalinity, Total as CaCO3 ug/L 50000 53000
MDL Analyzed Qualifiers
5000 02/09/2120:46
LCS % Rec
% Rec Limits Qualifiers
106 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3155743 3155744
MS MSD
92518942013 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 ug/L 12.6 mg/L 50000 50000 65100 65700 105 106 80-120 1 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3155745 3155746
MS MSD
92518942023 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 ug/L 16.3 mg/L 50000 50000 68100 69200 104 106 80-120 2 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11 /2021 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 39 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns River EXP Resample
Pace Project No.: 92519331
QC Batch: 599004 Analysis Method: SM 2320B-2011
QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92519331003, 92519331004, 92519331006
METHOD BLANK: 3157872 Matrix: Water
Associated Lab Samples: 92519331003, 92519331004, 92519331006
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Alkalinity, Total as CaCO3 ug/L ND 5000 5000 02/10/21 13:15
LABORATORY CONTROL SAMPLE: 3157873
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 ug/L 50000 51600 103 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3157876 3157877
MS MSD
92519331003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 ug/L ND 50000 50000 56700 56400 106 105 80-120 1 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3157975 3157976
MS MSD
92520337004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 ug/L ND 50000 50000 50100 50100 100 100 80-120 0 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11 /2021 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 40 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns River EXP Resample
Pace Project No.: 92519331
QC Batch: 597052 Analysis Method: SM 2540C-2011
QC Batch Method: SM 2540C-2011 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92519331001, 92519331002, 92519331003, 92519331004, 92519331006
METHOD BLANK: 3148561 Matrix: Water
Associated Lab Samples: 92519331001, 92519331002, 92519331003, 92519331004, 92519331006
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Dissolved Solids ug/L ND 25000 25000 02/02/21 18:45
LABORATORY CONTROL SAMPLE: 3148562
Spike
LCS LCS % Rec
Parameter
Units
Conc.
Result % Rec Limits Qualifiers
Total Dissolved Solids
ug/L
249000
262000 105 90-110
SAMPLE DUPLICATE: 3148563
92519207001
Dup Max
Parameter
Units
Result
Result RPD RPD Qualifiers
Total Dissolved Solids
ug/L
670 mg/L
670000 0 25
SAMPLE DUPLICATE: 3148564
92519331006 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Dissolved Solids ug/L 292000 299000 2 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11/2021 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns River EXP Resample
Pace Project No.: 92519331
QC Batch: 596773 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92519331001
METHOD BLANK: 3147322
Matrix:
Water
Associated Lab Samples: 92519331001
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Sulfate
ug/L
ND
1000
500 02/02/2111:52
LABORATORY CONTROL SAMPLE:
3147323
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Sulfate
ug/L
50000
49700 99
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3147324 3147325
MS MSD
92519357015 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate ug/L ND 50000 50000 52200 53600 104 107 90-110 3 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3147326 3147327
MS MSD
92519216001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate ug/L 28.0 mg/L 50000 50000 81000 84500 106 113 90-110 4 10 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11 /2021 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 42 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns River EXP Resample
Pace Project No.: 92519331
QC Batch: 597027 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92519331002, 92519331003, 92519331004, 92519331006
METHOD BLANK: 3148326 Matrix: Water
Associated Lab Samples: 92519331002, 92519331003, 92519331004, 92519331006
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Sulfate ug/L ND 1000 500 02/02/2121:43
LABORATORY CONTROL SAMPLE: 3148327
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfate ug/L 50000 47100 94 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3148328 3148329
MS MSD
92519556001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate ug/L 24.1 mg/L 50000 50000 72500 73800 97 99 90-110 2 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3148330 3148331
MS MSD
92518937004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate ug/L 1360 mg/L 50000 50000 1420000 1420000 122 123 90-110 0 10 M6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11 /2021 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 43 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns River EXP Resample
Pace Project No.: 92519331
QC Batch: 596757 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92519331001, 92519331002, 92519331003, 92519331004, 92519331006
METHOD BLANK: 3147209 Matrix: Water
Associated Lab Samples: 92519331001, 92519331002, 92519331003, 92519331004, 92519331006
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Chloride ug/L ND 1000 500 02/01/2117:44
LABORATORY CONTROL SAMPLE: 3147210
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chloride ug/L 20000 20500 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3147211 3147212
MS MSD
92518810001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride ug/L 65.5 mg/L 10000 10000 76200 64300 107 -12 90-110 17 10 M1,R1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3147213 3147214
MS MSD
92519131002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride ug/L 47.6 mg/L 10000 10000 55000 56700 73 91 90-110 3 10 M6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11 /2021 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 44 of 50

Pace Analytical Services, LLC
lac,
Analyilcal ® 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
www.pacelabs.com [phone]
QUALIFIERS
Project: Johns River EXP Resample
Pace Project No.: 92519331
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
ANALYTE QUALIFIERS
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
R1 RPD value was outside control limits.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11/2021 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Johns River EXP Resample
92519331
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92519331001
MW-20
EPA 3010A
596489
EPA 6010D
596508
92519331002
MW-30
EPA 3010A
596489
EPA 6010D
596508
92519331003
MW-23S
EPA 3010A
596489
EPA 6010D
596508
92519331004
MW-35
EPA 3010A
597049
EPA 6010D
597144
92519331005
Field Blank
EPA 3010A
597049
EPA6010D
597144
92519331006
MW-38
EPA 3010A
597049
EPA 6010D
597144
92519331001
MW-20
EPA 3010A
596491
EPA 6020B
596510
92519331002
MW-30
EPA 3010A
596491
EPA 6020B
596510
92519331003
MW-23S
EPA 3010A
596491
EPA 6020B
596510
92519331004
MW-35
EPA 3010A
596491
EPA 6020B
596510
92519331005
Field Blank
EPA 3010A
596491
EPA 6020B
596510
92519331001
MW-20
EPA 7470A
597300
EPA 7470A
597690
92519331002
MW-30
EPA 7470A
597300
EPA 7470A
597690
92519331003
MW-23S
EPA 7470A
597300
EPA 7470A
597690
92519331004
MW-35
EPA 7470A
597300
EPA 7470A
597690
92519331006
MW-38
EPA 7470A
597300
EPA 7470A
597690
92519331001
MW-20
EPA 8260D
597066
92519331002
MW-30
EPA 8260D
597066
92519331003
MW-23S
EPA 8260D
597066
92519331005
Field Blank
EPA 8260D
597067
92519331007
Trip Blank
EPA 8260D
597067
92519331001
MW-20
EPA 8260D Mod.
596433
92519331002
MW-30
EPA 8260D Mod.
596433
92519331003
MW-23S
EPA 8260D Mod.
596433
92519331004
MW-35
EPA 8260D Mod.
596433
92519331005
Field Blank
EPA 8260D Mod.
596433
92519331006
MW-38
EPA 8260D Mod.
596433
92519331007
Trip Blank
EPA 8260D Mod.
596433
92519331001
MW-20
SM 2320B-2011
598516
92519331002
MW-30
SM 2320B-2011
598516
92519331003
MW-23S
SM 2320B-2011
599004
92519331004
MW-35
SM 2320B-2011
599004
92519331006
MW-38
SM 2320B-2011
599004
92519331001
MW-20
SM 2540C-2011
597052
92519331002
MW-30
SM 2540C-2011
597052
92519331003
MW-23S
SM 2540C-2011
597052
92519331004
MW-35
SM 2540C-2011
597052
92519331006
MW-38
SM 2540C-2011
597052
92519331001
MW-20
EPA 300.0 Rev 2.1 1993
596773
92519331002
MW-30
EPA 300.0 Rev 2.1 1993
597027
92519331003
MW-23S
EPA 300.0 Rev 2.1 1993
597027
92519331004
MW-35
EPA 300.0 Rev 2.1 1993
597027
92519331006
MW-38
EPA 300.0 Rev 2.1 1993
597027
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11/2021
01:48 PM
without the written consent of Pace Analytical Services, LLC.
Page 46 of 50

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Johns River EXP Resample
Pace Project No.: 92519331
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
92519331001
MW-20
SM
4500-CI-E-2011
596757
92519331002
MW-30
SM
4500-CI-E-2011
596757
92519331003
MW-23S
SM
4500-CI-E-2011
596757
92519331004
MW-35
SM
4500-CI-E-2011
596757
92519331006
MW-38
SM
4500-CI-E-2011
596757
Date: 02/11/2021 01:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical
Batch
Page 47 of 50

s r`aceHrrdrylu�rr
Document Na.: Issuing Authority:
F-CAR-CS-033-Rev.07 Face Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ hiuntersville (� italeigh❑ Mechanicsville[] Atlanta[] Kernersville❑
Sample Condition Upon Receipt .-i Client Name-,-e cN C Project #: WQ# : 92519331
Il 111 ill Il III II II I III
Ien
❑ Cornmerdal - 91yai`e - []Other: - 92519331
Custody Seal Present? ❑Yes RNo Seals intact? []Yes ®No /I
oateJlnitiaLS Person Examining tonterits;��l
Parking Material: []Bubble Wrap ®$ubble Bags ❑None ❑ other Biological Tissue Frozen?
Thermometer: 121Net []Blue❑None []Yes []No MN/A
92TO64 Type of Ice:
II Correction Factor:
Cooler Temp: F f Add/Subtract (*Q -0.1 Temp should be above freezing to VC
[]Samples out ar ternpaiteria. Samples on ire, cooling process
Cooler Temp Corrected (*Cl: `' U hasbegun
USDA Regulated Sail (❑ N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or 5C (check maps)? Did samples originate from a foreign source (internationally,
❑Yen FNc. including Hawaii and Puerto Pico]? ❑Yes ❑No
Comments/Discrepancy:
Chain of Custody Present?
Ores
[:]Na
❑NIA
1.
Samples Arrived vrittafn RaM Time?
[]K;s
❑No
❑N/A
2.
Short Haid Time Analysis (42 hr.)7
[]Yes
EJ6 a
❑N/A
3.
Rush Turn Around Time Requested?
❑Yes
WNo
❑N/A
4.
Sufficient Volume?
Dries
[:]NO
❑N/A
5..
Correct Containers Used?
-Pace Containers Used?
(NYes
Yes
❑No
[]No
❑N/A
❑N/A
6.
Containers Intact?
yes
[]No
❑N/A
7.
Dissolved analysis: Samples Feld Filtered?
❑Yes
❑Na
kNIA
8.
Sample Labels Match CDC?
-Includes Oatefrimeftp/Analysis Matrix:
®Yes
u j
[]No
❑N/A
9.
Headspace in VOA Vials (:;,5-6mm)?
❑Yes
No
❑N/A
10.
Trip Blank present?
Trip Blank Custody Seals Present?
Pies
Yes
❑No
[]No
❑N/A
[—]N/A
11.
COMMENTS/SAMPLE DISCREPANCY
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted: Date/Time:
Project Manager SCURF Review:
Project Manager SRF Review:
Date:
Date:
Field Data Required? Des []No
Page 48 of 50

! F-CAR-CS-033-itev.07 Pace Carolinas Quality Office *Check mark top half of box if ply and/or dechlorination is Project PW�# 92519331
verified and within the acceptance range for preservation
samples. PM: NMG Due Date: 02/12/21
Exceptlons: VOA, Coliform, TOC, Oil and Grease, ORO/8015 (water} DOC, LLHg CLIENT: 92—Joyce Eng
"Bottom.half of box is to list number of bottles
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Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot d
adjusted I added
Nate: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this farm will he sent to the ,NorthCarclina DEHNR Certification Office (i•e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 49 of 50

,125 eAmlytical
www WE"05.COp
iection A
Required Client Information:
:ompany: LaBella Associates, D.P.C. - NC
kddress: 2211 W, Meadowview Rd
3reensboro. NC 274D7
small: [e-mail]
rhone- [phone] Fax
Requested Due Date
SAMPLE ID
One Character per box.
(A-Z, 0-9 1, -)
Sample Ids must he unique
W
F
1� (
MW-20
MW-30
3
MW-35
MW-23S.
Field Blank
MW-38
a
9
10
11
12
Section B
Required Project
Information:
Report
TO
Gretta Eller
Copy To:
Purchase Order#�
Project Name:
Johns River EXP
Project #,
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CHAIN -OF -CUSTODY 1 Analytical Request Document
COLLECTED
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tT
N
Section C
d
Invoice Information:
Page:
1 Of 1
Attentiow I CCr'fw.c'
c
Company Name:
Address,
Pace Quote:
Regulatory Agency
Landfill (i
Pace Project Manages nicole.gasiomwski pacelabs com.
State I Location
Pace Profile #: 2186-18
NC
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Appendix 2
Historical Data
Table A2-1 Historical Groundwater Elevations
Table A2-2 Historical Field Parameters
Table A2-3 Historically Detected Groundwater Constituents in Compliance Wells
Table A2-4 Historically Detected Constituents in Additional Wells/Piezometers
Table A2-5 Historically Detected Surface Water Constituents

TABLE A2-1: Historical Groundwater Elevations
Background
C&D Expansion (Phase 1A)
Additional Wells & Piezometers
Well No.
MW-21
MW-20
MW-22S
MW-23S (PZ
MW -24S
MW-35
MW-38
MW-36
MW-30
MW-15S
PZ-12
PZ-30S
PZ-31
(Former ID)
(PZ-1)
(PZ-4)
(PZ-22S)
16S)
(PZ-8S)
(PZ-35)
(PZ-38)
(PZ-36)
TOC Elevation
1099.86
1115.04
1061.20
1040.23
1069.04
1054.35
1063.39
1087.76
1099.52
1069.04
1025.64
1088.92
1089.81
Well Depth
41.00
67.00
26.40
20.00
55.00
50.00
37.75
73.13
45.00
56.16
15.09
55.25
43.13
18-Jun-96
NM
NM
1049.88
NI
NI
NI
1022.70
1017.92
NI
NI
4-Dec-96
NM
NM
1046.75
NI
NI
NI
1021.30
1017.91
NI
NI
6-May-14
1066.06
1058.24
1048.70
-
-
-
1044.47
1042.18
1069.17
1025.74
1018.14
1041.92
1064.14
21-Oct-14
1063.48
1056.42
1045.76
1042.13
1045.18
1066.52
1024.64
1017.68
1048.92
1061.04
21-May-15
1062.18
1053.69
1043.65
1041.12
1044.68
1066.03
1025.17
1017.60
1047.22
1060.17
9-Dec-15
1061.71
1051.65
1042.60
1046.24
1066.72
1025.19
1017.69
1045.57
1058.70
4-May-16
1065.36
1056.81
1045.81
1044.91
1071.22
1026.24
1017.94
1047.47
1056.31
13-Dec-16
1061.11
1051.66
1042.52
1039.44
1042.81
1065.99
1022.89
1017.19
1046.32
1057.01
28-Jun-17
1061.51
1050.54
1042.20
1040.69
1044.86
1065.77
1024.79
1017.64
1045.22
1058.31
15-Dec-17
1060.87
1052.14
1042.30
-
-
-
1040.91
1044.92
1066.07
1025.44
1017.71
1046.92
1059.81
15-May-18
1064.08
1052.84
AB
1036.19
1022.64
1026.45
1040.89
1045.90
1068.02
1026.07
1016.89
1048.44
1061.31
4-Dec-18
1064.45
1054.43
AB
1030.97
1022.76
1026.34
1041.69
1045.84
1067.96
1025.89
1018.09
1048.86
1061.35
7-May-19
1071.05
1059.12
AB
1031.66
1025.72
1028.18
1042.69
1047.19
1070.69
1027.19
1018.49
1052.05
1064.14
6-Nov-19
1065.97
1056.26
AB
1030.33
NM
1025.99
1042.69
1044.85
1066.57
1025.01
1017.92
1048.72
1060.41
7-May-20
1069.16
1056.49
AB
1031.23
NM
1027.00
1043.69
1046.26
1068.31
1026.68
1018.24
1049.95
1061.83
11-Nov-20
1071.28
NM
AB
NM
NM
NM
1044.69
1047.14
1067.92
1027.53
1018.22
1050.96
1062.41
27-Jan-21
1071.41
1058.14
AB
1031.78
NM
1027.24
1041.53
1046.53
1065.72
NM
NM
NM
NM
Notes:
All elevations are in feet above mean sea level.
NM = Groundwater level not measured.
- = well not yet installed.
AB = well abandoned
Burke County -- Johns River CDLF La Bella Associates
Expansion, Permit No. 12-03

TABLE A2-2: Historical Field Parameters
Background
C&D Expansion
Additional Wells & Piezometers
Surface Water
Parameter
Collection Date
MW-21
MW-20
MW-22S
MW-23S
MW-24S
MW-35
MW-38
MW-36
MW-30
MW-15S
PZ-12
PZ-30S
PZ-31
SMP-5
SMP-6
SMP-7
PZ-1)
(PZ-4)
(PZ-22S
PZ-16S
PZ-8S
PZ-35
PZ-38
PZ-36
Well Depth [ft];
46.80
67.00
26.40
20.00
55.00
50.00
39.05
74.50
58.27
14.90
55.30
45.60
45.58
N/A
N/A
N/A
30-May-12
26
-
-
-
54.0
39.4
5-Dec-12
-
19.5
-
-
-
-
-
-
-
-
189
58.4
12-Jun-13
29.8
224.2
80.7
29-Oct-13
26.5
-
-
-
110.7
110.7
10-Dec-13 *
-
-
-
-
-
-
-
-
-
-
6-May-14
16.23
30.1
22.9
33.7
344
79.2
14.90
23.10
26.0
166.8
114.3
26.4
-
21-Oct-14
68.1
7.37
22.3
31.1
389
78.1
31.9
30.7
20.8
190.3
-
68.2
29.7
19-May-15
27.2
19.8
18
24
410
73
28
21
18
204
141
54
25
8-Dec-15
15.5
24.1
31
29
493.0
51.5
27
30
29
232
59
39
38
4-May-16
16.0
19.7
25.7
36.9
413.4
53.8
22.8
18.1
21.2
187.5
64.7
45.8
40.3
17-May-16
-
-
-
-
-
-
-
-
20.0
9-Jun-16
-
-
-
-
348
-
-
-
-
-
-
-
-
13-Dec-16
115
66
19.00
22.0
522
51.0
26.0
21.0
33.0
241
118.7
81
25
Conductivity (at 25 °C)
27-Jun-17
28.9
19.7
29.7
25.7
577
45.6
24.6
43.4
15.4
268.3
110.5
89.6
34.3
[MS/cm]
8-Aug-17
-
440
-
-
-
-
-
14-Dec-17
14.2
23.0
25.8
-
-
-
30.6
413.0
60.8
33.6
24.7
48.4
234
120.2
70.0
32.1
15-May-18
13.5
20.2
AB
46.5
23.5
45.6
23.1
39.2
52.9
25.6
23.2
17.9
192
182
72
77
6-Dec-18
31.3
16.5
AB
22.6
21.3
33.1
20.0
312.7
58.9
24.0
21.2
16.7
182.5
74.6
33.2
27.3
7-Feb-19
19.5
AB
-
-
40.1
25.0
-
-
-
-
-
-
-
-
8-May-19
29.9
15.2
AB
16.4
20.0
34.4
23.2
419.7
44.8
24.6
25.1
21.6
228.0
127.2
47.9
30.1
22-May-19*
48.6
AB
-
-
-
-
-
-
-
-
-
-
24-Jul-19*
-
-
-
-
45.8
-
-
-
-
-
-
-
-
-
6-Nov-19
19.6
19.0
AB
20.1
44.3
22.6
680.0
45.1
28.7
26.9
17.7
244.9
88.2
69.2
31.1
7-May-20
15.6
21.4
AB
25.1
35.2
25.1
592.0
47.8
28.0
27.3
29.10
301.3
101.8
46.4
36.2
16-July-20*
-
12.0
-
-
-
-
-
-
-
-
-
-
-
-
10-Nov-20
17.3
-
-
-
25.0
502.0
46.4
26.7
24.1
26.5
215.4
61.8
39.7
48.3
27-Jan-21*
11.7
11.4
22.8
30.9
18.5
342.5
241.0
Burke County -- Johns River CDLF La Bella Associates
Expansion, Permit No. 12-03 Page 1 of 7

TABLE A2-2: Historical Field Parameters
Background
C&D Expansion
Additional Wells & Piezometers
Surface Water
Parameter
Collection Date
MW-21
MW-20
MW-22S
MW-23S
MW-24S
MW-35
MW-38
MW-36
MW-30
MW-15S
PZ-12
PZ-30S
PZ-31
SMP-5
SMP-6
SMP-7
PZ-1)
(PZ-4)
(PZ-22S
PZ-16S
PZ-8S
PZ-35
PZ-38
PZ-36
Well Depth [ft];
46.80
67.00
26.40
20.00
55.00
50.00
39.05
74.50
58.27
14.90
55.30
45.60
45.58
N/A
N/A
N/A
30-May-12
-
6.61
-
-
-
-
-
-
6.61
5.97
5-Dec-12
5.41
-
-
-
-
-
6.45
6.46
12-Jun-13
5.92
6.36
6.33
29-Oct-13
6.89
-
-
-
6.27
6.27
10-Dec-13 *
-
-
-
-
-
-
-
-
-
-
6-May-14
6.01
5.37
5.86
6.63
6.01
4.93
5.47
5.66
6.71
5.36
8.97
7.10
-
21-Oct-14
5.52
80.6
5.39
5.71
5.69
4.99
5.45
5.50
5.82
5.17
6.06
5.27
19-May-15
5.29
6.18
4.80
5.38
5.77
4.75
5.02
5.22
5.16
5.14
6.09
5.93
5.89
8-Dec-15
5.13
6.09
5.48
5.42
6.19
5.11
5.14
5.47
5.69
5.38
5.93
6.18
5.46
4-May-16
4.83
5.26
6.46
6.17
4.64
4.77
4.78
4.76
4.52
5.36
5.46
5.65
5.25
17-May-16
-
-
-
-
-
-
5.35
9-Jun-16
-
-
-
-
6.08
-
-
-
-
-
-
-
-
13-Dec-16
5.17
6.45
5.70
6.17
6.70
5.55
6.14
5.89
6.78
5.97
7.40
6.69
6.32
pH
27-Jun-17
6.45
5.98
6.27
6.39
6.57
5.31
5.87
7.22
6.23
6.22
6.37
6.49
5.85
[S.U.]
8-Aug-17
-
5.98
-
-
14-Dec-17
7.26
5.14
6.51
-
-
-
5.95
5.81
4.60
5.94
5.49
4.84
5.81
5.17
5.18
6.8
15-May-18
6.60
7.41
AB
5.87
6.64
6.22
6.37
5.93
6.47
5.80
6.18
6.18
5.50
7.30
6.68
6.76
6-Dec-18
5.41
6.39
AB
5.78
5.6
6
6.04
5.79
6.08
5.84
6.26
6.65
5.68
6.64
5.68
5.89
7-Feb-19
5.77
AB
5.88
5.74
-
-
-
-
-
8-May-19
5.43
5.76
AB
5.71
5.65
5.28
5.80
5.90
5.43
5.59
6.07
6.31
5.66
6.34
5.98
5.77
22-May-19*
6.19
AB
-
-
-
-
-
-
-
-
24-Jul-19*
-
-
-
-
-
5.11
-
-
-
-
-
-
-
-
-
6-Nov-19
4.8
5.5
AB
4.57
5.51
5.59
6.0
4.9
5.7
5.3
5.43
4.89
6.1
6.02
4.96
7-May-20
6.1
6.8
AB
6.87
5.76
6.01
6.81
5.3
5.9
5.1
6.27
5.88
6.56
6.04
6.11
16-July-20*
-
6.2
AB
-
-
-
-
-
-
-
-
-
-
-
-
10-Nov-20
6.05
-
-
-
5.78
6.27
5.10
5.43
5.52
6.69
5.55
6.77
6.25
6.43
27-Jan-21*
5.88
5.89
5.29
6.09
5.76
6.42
6.37
Burke County -- Johns River CDLF La Bella Associates
Expansion, Permit No. 12-03 Page 2 of 7

TABLE A2-2: Historical Field Parameters
Background
C&D Expansion
Additional Wells & Piezometers
Surface Water
Parameter
Collection Date
MW-21
MW-20
MW-22S
MW-23S
MW-24S
MW-35
MW-38
MW-36
MW-30
MW-15S
PZ-12
PZ-30S
PZ-31
SMP-5
SMP-6
SMP-7
PZ-1)
(PZ-4)
(PZ-22S
PZ-16S
PZ-8S
PZ-35
PZ-38
PZ-36
Well Depth [ft];
46.80
67.00
26.40
20.00
55.00
50.00
39.05
74.50
58.27
14.90
55.30
45.60
45.58
N/A
N/A
N/A
30-May-12
-
18.18
-
-
-
-
-
-
-
-
-
-
-
23.4
20.7
5-Dec-12
15.4
11.8
12.6
12-Jun-13
18.1
24.4
22.3
29-Oct-13
17.7
15.9
15.9
10-Dec-13 *
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
6-May-14
18.6
20.1
15.0
16.4
17.3
16.9
14.2
16.9
17.0
17.0
17.0
21.1
-
21-Oct-14
17.2
15.3
15.2
15.7
15.0
14.9
15.5
15.7
15.4
15.8
-
10.5
12.2
19-May-15
19.8
17.8
17.8
20.0
24.7
16.6
14.7
21.3
20.4
21.0
21.5
17.5
17.4
8-Dec-15
15.2
16.2
15.9
15.9
15.6
15.1
11.7
15.5
15.4
15.5
8.0
6.3
8.5
4-May-16
17.9
17.5
14.8
16.7
17.1
15.5
13.4
17.1
17.5
16.7
20.7
19.5
16.0
17-May-16
-
-
-
-
-
-
-
-
-
-
-
-
14.1
9-Jun-16
-
-
18.1
-
-
-
-
13-Dec-16
14.4
14.1
16.6
15.2
15.1
14.8
13.5
15.40
14.3
15.6
11.5
10.7
8.9
Temperature
27-Jun-17
15.0
16.4
18.1
20.1
17.9
16.0
15.2
16.3
16.7
16.8
21.1
18.3
16.7
[ 1 C]
8-Aug-17
-
-
-
-
-
-
18.8
-
-
-
-
-
-
-
-
14-Dec-17
14.1
15.1
15.4
-
13.8
15.1
14.9
12.2
14.3
15.9
14.1
7.4
6.3
5.23
15-May-18
18.2
19.6
AB
17.4
15.8
18.2
17.8
19.7
17.6
16.2
19.5
18.9
18.5
25.7
16.9
16.3
6-Dec-18
9.3
13.3
AB
12.7
13
12.7
14.5
14.1
15.5
12.4
15.7
15.1
14.4
3
8.2
8.7
7-Feb-19
-
20.9
AB
-
-
20.5
23.9
-
-
-
-
-
-
-
-
-
8-May-19
16.1
18.3
AB
15.4
16.6
16.9
19.1
18.5
17.5
14.7
21.1
20.5
19.5
21.5
17.5
16.4
22-May-19*
17.9
-
AB
-
-
-
-
-
-
-
-
-
-
-
-
-
24-Jul-19*
28.4
-
-
-
-
-
-
-
-
6-Nov-19
15.8
14.1
AB
16.1
12
14.2
15.8
15.6
15.3
17.7
13.7
15.4
12.4
10.9
11.4
7-May-20
13.9
19.3
AB
13.02
16.8
17.2
18.7
17.0
13.6
19.7
13.0
16.8
12.1
11.5
13
16-July-20*
-
25.7
AB
-
-
-
-
-
-
-
-
-
-
-
-
10-Nov-20
15.9
-
-
-
17.2
17.0
17.0
17.3
20.6
17.6
17.7
18.7
18.9
19.2
27-Jan-21*
14.3
16.4
15.4
15.1
15.6
14.4
15.4
Burke County -- Johns River CDLF La Bella Associates
Expansion, Permit No. 12-03 Page 3 of 7

TABLE A2-2: Historical Field Parameters
Background
C&D Expansion
Additional Wells & Piezometers
Surface Water
Parameter
Collection Date
MW-21
MW-20
MW-22S
MW-23S
MW-24S
MW-35
MW-38
MW-36
MW-30
MW-15S
PZ-12
PZ-30S
PZ-31
SMP-5
SMP-6
SMP-7
PZ-1)
(PZ-4)
(PZ-22S
PZ-16S
PZ-8S
PZ-35
PZ-38
PZ-36
Well Depth [ft];
46.80
67.00
26.40
20.00
55.00
50.00
39.05
74.50
58.27
14.90
1 55.30
1 45.60-1
45.58
N/A
N/A
N/A
30-May-12
14
-
-
-
-
18.3
16.7
5-Dec-12
-
631
-
-
-
-
-
-
-
12.35
12.92
12-Jun-13
21.3
65.7
40.4
29-Oct-13
7.39
-
19.5
19.5
10-Dec-13 *
-
-
-
-
-
-
-
-
-
-
-
-
6-May-14
7.98
37.1
25.7
18.5
5.85
4.47
75.0
12.04
22.5
31.2
13.54
21.9
-
21-Oct-14
8.15
30.1
9.15
45.8
4.94
6.50
125
10.78
25.5
3.28
-
15.3
7.96
19-May-15
8.15
27.1
9.66
>1000
7.04
8.52
>1000
5.81
5.09
4.74
7.63
7.31
17.2
8-Dec-15
25.5
55.6
48.3
25.1
7.71
21.4
33.6
7.55
8.25
17.41
6.61
6.07
4.33
4-May-16
17.55
29.2
18.23
20.8
12.85
18.05
23.7
13.60
15.25
12.72
57.2
42.1
75.3
17-May-16
-
-
-
-
-
-
-
-
21.5
9-Jun-16
-
-
-
-
9.32
-
-
-
-
-
-
-
-
13-Dec-16
12.63
17.55
9.10
9.73
13.47
10.50
17.00
9.15
9.20
13.61
30.4
14.43
10.15
Turbidity
27-Jun-17
12.2
15.2
15.05
10.75
11.25
8.95
15
8.90
7.56
11.6
15.21
12.65
25.4
[NTU]
8-Aug-17
-
-
-
-
7.11
-
-
-
-
-
-
-
-
14-Dec-17
15.01
109.8
12.05
-
-
-
10.15
15.22
9.36
208.6
5.44
274.9
2.59
2.46
15.25
32.63
15-May-18
5.89
38.07
AB
5.02
7.97
51.59
5.54
3.68
8.62
10.51
8.32
8.46
8.75
68.63
19.93
36.61
6-Dec-18
4.40
427.00
AB
21.4
46.5
94.9
104.00
12.00
1.95
37.90
2.16
2.22
2.50
47.10
8.3
14
7-Feb-19
71.1
AB
-
-
2.35
6.42
-
-
-
-
-
-
-
-
8-May-19
24.9
51.1
AB
26.3
41.6
29.7
114
15.8
7.08
41.3
8.2
18.6
3.0
-
22-May-19*
48.9
-
AB
-
-
-
-
-
-
-
-
24-Jul-19*
-
-
-
-
-
918.4
-
-
-
-
-
-
-
-
-
6-Nov-19
50.5
168.0
AB
14.73
123.6
25.8
65.0
4.5
136.5
4.6
8.2
26.7
119.4
23.88
144.1
7-May-20
49.2
262.5
AB
36.64
71.5
83.6
68.4
20.6
50.9
16-July-20*
-
286.6
AB
-
-
-
-
-
-
-
-
-
-
-
-
10-Nov-20
318.0
-
-
-
76.7
4.9
13.6
189.0
2.3
22.0
7.0
124.0
293
338
27-Jan-21*
9.0
10.7
10.8
9.96
8.85
7.40
276
Burke County -- Johns River CDLF La Bella Associates
Expansion, Permit No. 12-03 Page 4 of 7

TABLE A2-2: Historical Field Parameters
Background
C&D Expansion
Additional Wells & Piezometers
Surface Water
Parameter
Collection Date
MW-21
MW-20
MW-22S
MW-23S
MW-24S
MW-35
MW-38
MW-36
MW-30
MW-15S
PZ-12
PZ-30S
PZ-31
SMP-5
SMP-6
SMP-7
PZ-1)
(PZ-4)
(PZ-22S
PZ-16S
PZ-8S
PZ-35
PZ-38
PZ-36
Well Depth [ft];
46.80
67.00
26.40
20.00
55.00
50.00
39.05
74.50
58.27
14.90
55.30
45.60
45.58
N/A
N/A
N/A
30-May-12
-
6.24
-
-
-
-
-
-
-
-
-
-
-
N/A
N/A
5-Dec-12
7.29
N/A
N/A
12-Jun-13
8.68
N/A
N/A
29-Oct-13
5.83
N/A
N/A
10-Dec-13 *
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
6-May-14
N/A
7.83
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
21-Oct-14
5.74
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
19-May-15
5.66
0.01
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
8-Dec-15
7.59
7.53
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
4-May-16
7.26
9.55
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
17-May-16
-
N/A
9-Jun-16
-
-
N/A
13-Dec-16
5.41
7.69
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Dissolved Oxygen (DO)
27-Jun-17
7.06
8.98
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
[mg/L]
8-Aug-17
-
-
N/A
14-Dec-17
9.05
N/A
N/A
-
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
15-May-18
6.54
6.01
AB
N/A
N/A
8.2
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
6-Dec-18
10.55
3.55
AB
2.31
1.9
3.07
3.45
2.85
2.25
1.75
1.66
2.33
2.56
6.18
3.87
2.29
7-Feb-19
-
4.38
AB
-
-
3.57
3.15
-
-
-
-
-
-
-
-
-
8-May-19
1.69
1.89
AB
1.84
2.38
2.10
1.69
2.27
1.45
2.42
1.58
2.09
1.50
22-May-19*
7.21
-
AB
-
-
-
-
-
-
-
-
-
-
24-Jul-19*
-
-
-
-
1.95
-
-
-
-
-
-
-
-
-
6-Nov-19
4.8
2.6
AB
2.41
3.16
2.49
1.6
1.6
2.5
1.9
2.2
3.7
4.0
3.68
2.51
7-May-20
1.96
3.71
AB
2.5
3.15
2.87
4.34
2.52
2.5
27.3
2.19
4.52
3.12
2.09
2.8
16-July-20*
-
5.36
AB
-
-
-
-
-
-
-
-
-
-
-
-
10-Nov-20
8.67
-
-
-
3.63
1.15
4.58
5.8
3.8
6.4
3.3
5.6
7.94
6.29
27-Jan-21*
7.7
7.8
4.2
7.1
4.4
3.8
2.5
Burke County -- Johns River CDLF LaBella Associates
Expansion, Permit No. 12-03 Page 5 of 7

TABLE A2-2: Historical Field Parameters
Background
C&D Expansion
Additional Wells & Piezometers
Surface Water
Parameter
Collection Date
MW-21
MW-20
MW-22S
MW-23S
MW-24S
MW-35
MW-38
MW-36
MW-30
MW-15S
PZ-12
PZ-30S
PZ-31
SMP-5
SMP-6
SMP-7
PZ-1)
(PZ-4)
(PZ-22S
PZ-16S
PZ-8S
PZ-35
PZ-38
PZ-36
Well Depth [ft];
46.80
67.00
26.40
20.00
55.00
50.00
39.05
74.50
58.27
14.90
55.30
45.60
45.58
N/A
N/A
N/A
30-May-12
-
7.1
-
-
-
-
-
-
-
-
-
-
-
N/A
N/A
5-Dec-12
227.2
N/A
N/A
12-Jun-13
104.7
N/A
N/A
29-Oct-13
41.3
N/A
N/A
10-Dec-13 *
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
6-May-14
N/A
116.5
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
21-Oct-14
104.6
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
19-May-15
136.8
61.8
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
8-Dec-15
269.9
148.8
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
4-May-16
80.4
81.7
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
17-May-16
-
N/A
9-Jun-16
-
-
N/A
Oxygen Reduction
13-Dec-16
180.4
217.4
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Potential (ORP)
27-Jun-17
184.2
152.2
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
8-Aug-17
-
-
N/A
[mV]
14-Dec-17
121.2
N/A
N/A
-
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
15-May-18
154.0
147.9
AB
N/A
N/A
97.3
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
6-Dec-18
205.5
59.4
AB
100.8
102.4
103
91.5
91.4
51.4
92.4
90.2
57.1
77.7
26.1
158.6
96.7
7-Feb-19
-
219.9
AB
-
-
186.5
195.4
-
-
-
-
-
-
-
-
-
8-May-19
203.8
202.5
AB
174.7
227.7
253.6
158.7
177.4
172.6
237.8
151.1
101.0
109.8
22-May-19*
214.6
-
AB
-
-
-
-
-
-
-
-
-
-
24-Jul-19*
-
-
-
-
283.7
-
-
-
-
-
-
-
-
-
6-Nov-19
198.0
198.2
AB
298.8
214.7
240.7
25.5
123.4
201.8
271.3
252.0
236.2
74.8
119.8
308
7-May-20
316.8
228.2
AB
361.2
171.5
164.5
220.9
261.7
229.9
257.4
151.4
204.9
309
251.3
260.7
16-July-20*
-
246.20
AB
-
-
-
-
-
-
-
-
-
-
-
-
10-Nov-20
246.1
-
-
-
112.6
14.3
137.9
63.5
67.2
32.2
113.0
91.5
145.1
122.9
27-Jan-21*
96.2
142.1
119
129.2
119.5
51.4
Burke County -- Johns River CDLF LaBella Associates
Expansion, Permit No. 12-03 Page 6 of 7

TABLE A2-2: Historical Field Parameters
Background
C&D Expansion
Additional Wells & Piezometers
Surface Water
Parameter
Collection Date
MW-21
MW-20
MW-22S
MW-23S
MW-24S
MW-35
MW-38
MW-36
MW-30
MW-15S
PZ-12
PZ-30S
PZ-31
SMP-5
SMP-6
SMP-7
PZ-1)
(PZ-4)
(PZ-22S
PZ-16S
PZ-8S
PZ-35
PZ-38
PZ-36
Well Depth [ft];
46.80
67.00
26.40
20.00
55.00
50.00
39.05
74.50
58.27
14.90
55.30
45.60
45.58
N/A
N/A
N/A
30-May-12
-
62.41
-
-
-
-
-
-
-
-
-
-
-
N/A
N/A
5-Dec-12
61.53
N/A
N/A
12-Jun-13
59.24
N/A
N/A
29-Oct-13
54.60
N/A
N/A
10-Dec-13 *
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
6-May-14
33.08
56.80
12.50
18.92
41.80
43.30
7.50
47.00
25.67
30.35
N/A
N/A
21-Oct-14
36.38
58.62
15.44
21.26
42.58
44.40
7.96
40.00
28.77
33.00
N/A
N/A
N/A
19-May-15
37.68
61.35
17.55
22.27
43.08
43.87
8.04
41.70
29.64
33.49
N/A
N/A
N/A
8-Dec-15
38.15
63.39
18.60
21.55
41.52
43.85
7.95
43.35
31.11
32.80
N/A
N/A
N/A
4-May-16
34.50
58.23
15.39
20.74
42.85
42.80
7.70
41.45
33.50
28.30
N/A
N/A
N/A
17-May-16
-
-
-
-
-
-
-
-
-
-
N/A
9-Jun-16
-
-
-
-
43.14
-
-
-
-
-
13-Dec-16
38.75
17.55
18.68
23.95
44.95
46.15
8.45
42.60
45.60
28.30
N/A
N/A
N/A
Static Water Level
27-Jun-17
38.35
64.50
19.00
22.70
42.90
44.25
8.00
43.70
31.50
33.75
N/A
N/A
N/A
[feet]
8-Aug-17
-
-
-
-
43.06
-
-
-
-
-
14-Dec-17
38.99
62.90
18.90
-
-
-
22.48
42.84
43.60
7.93
42.00
30.00
33.45
N/A
N/A
N/A
15-May-18
35.78
62.20
AB
4.04
46.40
27.90
22.50
41.86
42.97
8.75
40.48
28.50
31.50
N/A
N/A
N/A
6-Dec-18
35.41
60.61
AB
9.26
46.28
28.01
22.93
41.92
43.15
7.55
40.06
28.46
31.56
N/A
N/A
N/A
7-Feb-19
30.14
57.42
AB
-
-
26.22
20.99
-
-
-
-
-
-
8-May-19
28.81
55.92
AB
8.57
43.32
26.17
21.30
40.57
41.85
7.15
36.87
25.67
28.83
22-May-19*
28.95
-
AB
-
-
-
-
-
-
-
-
-
-
24-Jul-19*
-
-
-
-
22.07
-
-
-
-
-
-
6-Nov-19
33.9
58.78
AB
9.9
28.36
24.00
42.9
44.0
7.7
40.2
29.4
33.0
7-May-20
30.7
58.55
AB
9
27.35
22.50
41.50
42.36
7.4
38.97
28.0
31.2
16-July-20*
-
58.82
-
-
-
-
-
-
-
-
-
10-Nov-20
28.6
-
-
-
21.3
40.6
41.5
7.4
38.0
27.4
31.6
27-Jan-21*
28.5
56.9
8.45
27.11
21.9
41.2
-
-
-
-
33.8
Notes:
°C = degrees Centigrade
S.U. = Standard Units
pS/cm = microSemens per centimeter
mg/I = milligrams per liter
my = millivolts
NTU = Nephelometric Turbidity Units
- = Not monitored
N/A = Not available (well monitored but parameter not required)
*= Resample
Burke County -- Johns River CDLF La Bella Associates
Expansion, Permit No. 12-03 Page 7 of 7

TABLE A2-3: Historically Detected Groundwater Constituents in Compliance Wells
Sample
EPA
(Background)
Analyte
Collection Date
Method
DL
RL
MW-21
MW-20
MW-22S
MW-38
MW-23S
MW-24S
MW-30
MW-35
Blanks
INORGANICS
Alkalinity, Total aS CaCO3
10-Apr-14
SM 2320B
1,000
5,000
1,560 J
--
5,510
208,000
NI
NI
NI
NI
ND
NC21- = NE (01/01/10)
6-May-14
SM 2320B
1,000
5,000
1,170 J
--
4,060 J
209,000
NI
NI
NI
NI
ND
20-Jun-14
SM 2320B
1,000
5,000
2,020 J
-
4,060 J
262,000
NI
NI
NI
NI
ND
17-Jul-14
SM 2320B
1,000
5,000
1,990 J
-
3,960 J
197,000
NI
NI
NI
NI
ND
23-Oct-14
SM 2320B
1,000
5,000
1,360 J
7,980
4,340 J
232,000
NI
NI
NI
NI
ND
21-May-15
SM 2320B
1,000
5,000
ND
6,540
3,630 J
206,000
NI
NI
NI
NI
-
8-Dec-15
SM 2320B
1,000
5,000
1,030 J
8,280
6,670
234,000
NI
NI
NI
NI
--
4-May-16
SM 2320B
1,000
5,000
1,250 J
5,640
4,190 J
239,000
NI
NI
NI
NI
--
13-Dec-16
SM 2320B
1,000
5,000
1,190 J
6,190
4,100 J
294,000
NI
NI
NI
NI
--
27-Jun-17
SM 2320B
1,000
5,000
ND
6,110
5,060
315,000
NI
NI
NI
NI
--
13-Dec-17
SM 2320B
1,000
5,000
1,610 J
6,410
5,540
221,000
NI
NI
NI
NI
--
16-May-18
SM 2320B
1,000
5,000
2,340 J
7,860
AB
253,000
24,600
5,010
25,000
8,870
-
6-Dec-18
SM 2320B
1,000
5,000
ND
5,290
AB
263,000
2,980 J
3,580 J
16,200
8,340
ND
8-May-19
SM 2320E-2011
1,000
5,000
-
3,950 J
AB
243,000
1,960 J
4,380 J
13,300
9,080
ND
8-Nov-19
SM 2320E-2011
5,000
5,000
ND
ND
AB
357,000
ND
NS
16,500
5,970
ND
8-May-20
SM 2320E-2011
5,000
5,000
ND
6,380
AB
277,000
ND
NS
15,600
8,500
ND
11-Nov-20
SM 2320E-2011
5,000
5,000
ND
-
--
-
-
-
-
-
ND
28-Jan-21
SM 2320E-2011
5,000
5,000
--
ND
--
275,000
ND
--
14,300
8,650
-
Arsenic
8-Dec-15
EPA 6010
2.5
10
ND
ND
12.7
4.9 J
NI
NI
NI
NI
ND
NC21-= 10 p9/1(01/01/10)
4-Feb-16
EPA 6010
2.5
10
-
--
5.8 J
-
NI
NI
NI
NI
ND
4-May-16
EPA 6010
2.5
10
ND
ND
ND
ND
NI
NI
NI
NI
ND
13-Dec-16
EPA 6010
2.5
10
ND
ND
ND
3.2 J
NI
NI
NI
NI
ND
27-Jun-17
EPA 6010
5.0
10
ND
ND
ND
ND
NI
NI
NI
NI
ND
13-Dec-17
EPA 6010
5.0
10
ND
ND
ND
ND
NI
NI
NI
NI
ND
16-May-18
EPA 6010
5.0
10
ND
ND
AB
ND
ND
ND
ND
ND
-
6-Dec-18
EPA 6010D
5.0
10
ND
ND
AB
ND
ND
ND
ND
ND
ND
8-May-19
EPA 6010D
5.0
10
ND
ND
AB
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA 6010D
4.7
10
ND
ND
AB
ND
ND
NS
ND
ND
ND
8-May-20
EPA 6010D
4.7
10
ND
ND
AB
ND
ND
NS
ND
ND
ND
11-Nov-20
EPA 6010D
4.7
10
ND
-
-
4.8 J
-
-
-
-
ND
28-Jan-21
EPA 6010D
4.7
10
-
ND
-
-
ND
-
ND
ND
ND
Barium
10-Apr-14
EPA 6010
5
100
14.4 J
-
86.9 J
127
NI
NI
NI
NI
ND
NC21- = 700 pg/I (01/01/10)
6-May-14
EPA 6010
5
100
11.7 J
--
75.7 J
110
NI
NI
NI
NI
ND
20-Jun-14
EPA 6010
5
100
14.2 J
-
52.2 J
85.2 J
NI
NI
NI
NI
ND
17-Jul-14
EPA 6010
5
100
14.4 J
-
52.4 J
58.1 J
NI
NI
NI
NI
ND
23-Oct-14
EPA 6010
5
100
20.3 J
70.0 J
20.8 J
97.8 J
NI
NI
NI
NI
ND
21-May-15
EPA 6010
5
100
17.9 J
116
28.3 J
91.0 J
NI
NI
NI
NI
ND
8-Dec-15
EPA 6010
2.5
100
17.6 J
67.3 J
1,110
83.5 J
NI
NI
NI
NI
ND
Verification Sample >
4-Feb-16
EPA 6010
2.5
100
-
-
264
-
NI
NI
NI
NI
ND
4-May-16
EPA 6010
2.5
100
26.6 J
118
38.4 J
111
NI
NI
NI
NI
ND
13-Dec-16
EPA 6010
2.5
100
13.4 J
123
56.6 J
92.8 J
NI
NI
NI
NI
ND
27-Jun-17
EPA 6010
2.5
100
18.8 J
72.1 J
74.3 J
77.1 J
NI
NI
NI
NI
ND
13-Dec-17
EPA 6010
2.5
100
17.6 J
87.6 J
32.1 J
98.0 J
NI
NI
NI
NI
ND
16-May-18
EPA 6010
2.5
100
16.1 J
54.1 J
AB
117
10.8 J
42.4 J
44.9 J
22.1 J
--
6-Dec-18
EPA 6010D
2.5
5
16.1
179
AB
106
5.5
32.6
58.4
43.0
9.9
8-May-19
EPA 6010D
2.5
5
22.4
51.9
AB
110
7.0
32.9
36.6
78.1
ND
8-Nov-19
EPA 6010D
1
5
25.6
88.3
AB
130
7.4
NS
32.8
40.5
1.1 J
8-May-20
EPA 6010D
3.5
5
21.7
186
AB
91.8
9.2
NS
39.6
27.8
ND
11-Nov-20
EPA 6010D
3.5
5
47.4
-
-
95.4
-
-
-
-
ND
28-Jan-21
EPA 6010D
3.5
5
-
25
--
-
14.1
-
32.4
30.9
ND
Beryllium
8-Dec-15
EPA 6010
0.5
1
ND
ND
3.4
ND
NI
NI
NI
NI
ND
Verification Sample >
4-Feb-16
EPA 6010
0.5
1
-
-
0.83 J
-
NI
NI
NI
NI
ND
GWPS = 4 pg/I (01/01/10).
4-May-16
EPA 6010
0.5
1
ND
ND
ND
ND
NI
NI
NI
NI
ND
13-Dec-16
EPA 6010
0.5
1
ND
ND
ND
ND
NI
NI
NI
NI
ND
27-Jun-17
EPA 6010
0.5
1
ND
ND
ND
ND
NI
NI
NI
NI
ND
13-Dec-17
EPA 6010
0.5
1
ND
ND
ND
ND
NI
NI
NI
NI
ND
IMAC = 4 pg/I
16-May-18
EPA 6010
0.5
1
ND
ND
AB
ND
ND
ND
ND
ND
-
6-Dec-18
EPA 6010D
0.5
1
ND
ND
AB
ND
ND
ND
ND
ND
ND
8-May-19
EPA 6010D
0.5
1
ND
ND
AB
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA 6010D
0.2
1
ND
0.36 J
AB
0.27 J
ND
NS
ND
0.28 J
0.21 J
8-May-20
EPA 6010D
0.7
1
ND
ND
AB
ND
ND
NS
ND
ND
ND
11-Nov-20
EPA 6010D
0.7
1
ND
-
-
ND
-
-
-
-
ND
28-Jan-21
EPA 6010D
0.7
1
-
ND
-
-
ND
-
ND
ND
ND
Cadmium
11-Nov-20
EPA 6010D
0.4
1
-
-
-
0.43 J
-
-
-
-
-
28-Jan-21
EPA 6010D
0.4
1
-
ND
-
-
ND
-
ND
ND
ND
Chloride
10-Apr-14
SM 4500-CI-E
1000
1000
ND
-
ND
4980
NI
NI
NI
NI
ND
NC21-= 250,000 p9/1(01/01/10)
6-May-14
SM 4500-CI-E
1,000
1,000
ND
--
1,140
4,930
NI
NI
NI
NI
ND
20-Jun-14
SM 4500-CI-E
1,000
1,000
ND
-
1,320
4,410
NI
NI
NI
NI
ND
17-Jul-14
SM 4500-CI-E
500
1,000
570 J
-
1,090
4,310
NI
NI
NI
NI
ND
23-Oct-14
SM 4500-CI-E
500
1,000
ND
1,050
727 J
4,650
NI
NI
NI
NI
ND
21-May-15
SM 4500-CI-E
500
1,000
750 J
1,550
1,380
4,980
NI
NI
NI
NI
--
8-Dec-15
SM 4500-CI-E
500
1,000
859 J
1,840
4,200
4,390
NI
NI
NI
NI
--
4-May-16
SM 4500-CI-E
500
1,000
558 J
4,500
2,440
5,980
NI
NI
NI
NI
--
13-Dec-16
SM 4500-CI-E
500
1,000
1,470
1,460
1,240
4,760
NI
NI
NI
NI
--
27-Jun-17
SM 4500-CI-E
500
1,000
ND
1,380
1,070
4,670
NI
NI
NI
NI
-
13-Dec-17
SM 4500-CI-E
500
1,000
681 J
1,660
1,240
6,170
NI
NI
NI
NI
ND
16-May-18
SM 4500-CI-E
500
1,000
1,100
1,590
AB
6,570
1,340
2,680
1,480
1,320
--
6-Dec-18
SM 4500-CI-E
500
1,000
1,020
2,230
AB
7,280
2,710
2,760
1,310
1,200
ND
8-May-19
SM 4500-CI-E-2011
500
1,000
-
1,330
AB
8,570
1,590
2,340
1,110
803 J
ND
8-Nov-19
SM 4500-CI-E-2011
500
1,000
1,020
1,610
AB
6,690
1,940
NS
1,160
988 J
ND
8-May-20
SM 4500-CI-E-2011
500
1,000
1,270
2,210
AB
10,900
2,970
NS
1,600
8,120
ND
11-Nov-20
SM 4500-CI-E-2011
500
1,000
720 J
-
--
-
-
-
-
-
ND
28-Jan-21
SM 4500-CI-E-2011
500
1,000
-
534 J
--
9,010
3,060
--
1,230
1,090
--
Chromium
10-Apr-14
EPA 6010
5
10
ND
--
ND
ND
NI
NI
NI
NI
ND
NC21-= 10 p9/1(01/01/10)
6-May-14
EPA 6010
5
10
ND
-
ND
ND
NI
NI
NI
NI
ND
20-Jun-14
EPA 6010
5
10
ND
-
ND
ND
NI
NI
NI
NI
ND
17-Jul-14
EPA 6010
5
10
ND
-
ND
ND
NI
NI
NI
NI
ND
23-Oct-14
EPA 6010
5
10
ND
7.0 J
ND
ND
NI
NI
NI
NI
ND
21-May-15
EPA 6010
5
10
ND
7.4 J
ND
ND
NI
NI
NI
NI
ND
8-Dec-15
EPA 6010
2.5
10
ND
4.7 J
16.8
ND
NI
NI
NI
NI
ND
Verification Sample >
4-Feb-16
EPA 6010
2.5
10
-
-
6.6 J
-
NI
NI
NI
NI
ND
4-May-16
EPA 6010
2.5
10
4.2 J
10.4
ND
ND
NI
NI
NI
NI
ND
13-Dec-16
EPA 6010
2.5
10
ND
9.8 J
ND
4.0 J
NI
NI
NI
NI
ND
27-Jun-17
EPA 6010
2.5
10
ND
3.5 J
ND
3.0 J
NI
NI
NI
NI
ND
13-Dec-17
EPA 6010
2.5
10
ND
5.5 J
ND
ND
NI
NI
NI
NI
ND
16-May-18
EPA 6010
2.5
10
ND
ND
AB
ND
ND
ND
3.1 J
ND
-
6-Dec-18
EPA 6010D
2.5
5
ND
13.5
AB
ND
ND
ND
4.1 J
3.8 J
ND
Verification Sample >
7-Feb-19
EPA 6010D
2.5
5
-
4.6 J
AB
-
-
-
-
-
ND
8-May-19
EPA 6010D
2.5
5
ND
4.5 J
AB
ND
ND
ND
ND
7.9
ND
8-Nov-19
EPA 6010D
1
5
2.4 J
6.0
AB
2.3 J
ND
NS
ND
2.5 J
5.1
8-May-20
EPA 6010D
3.7
5
ND
21.7
AB
ND
ND
NS
ND
ND
ND
23-Sep-20
EPA 6010D
3.7
5
--
ND
-
-
-
-
-
-
-
11-Nov-20
EPA 6010D
3.7
5
7
-
-
ND
-
-
-
-
ND
28-Jan-21
EPA 6010D
3.7
5
--
ND
-
-
ND
-
ND
ND
ND
Burke County -- Johns River CDLF LaBella Associates
Expansion, Permit No. 12-03 Page 1 of 6

TABLE A2-3: Historically Detected Groundwater Constituents in Compliance Wells
Sample
EPA
(Background)
nalyte MA
ollection Date
Method
DL
RL
MW-21
MW-20
MW-22S
MW-38
MW-23S
MW-24S
MW-30
MW-35
Blanks
Cobalt
10-Apr-14
EPA 6010
5
10
ND
--
ND
80.8
NI
NI
NI
NI
ND
GWPS = 1 pg/1 (10/1/10)
6-May-14
EPA 6010
5
10
ND
--
ND
58.0
NI
NI
NI
NI
ND
20-Jun-14
EPA 6010
5
10
ND
-
ND
12.5
NI
NI
NI
NI
ND
17-Jul-14
EPA 6010
5
10
ND
-
ND
18.9
NI
NI
NI
NI
ND
23-Oct-14
EPA 6010
5
10
ND
ND
ND
21.5
NI
NI
NI
NI
ND
21-May-15
EPA 6010
5
10
ND
2.9 J
ND
10.5
NI
NI
NI
NI
ND
8-Dec-15
EPA 6010
2.5
10
ND
ND
11.2
4.1 J
NI
NI
NI
NI
ND
Verification Sample >
4-Feb-16
EPA 6010
2.5
10
-
-
3.2 J
-
NI
NI
NI
NI
ND
4-May-16
EPA 6010
2.5
10
4.0 J
3.1 J
ND
10.0
NI
NI
NI
NI
ND
13-Dec-16
EPA 6010
2.5
10
ND
3.6 J
ND
ND
NI
NI
NI
NI
ND
27-Jun-17
EPA 6010
2.5
10
ND
ND
ND
ND
NI
NI
NI
NI
ND
13-Dec-17
EPA 6010
2.5
10
ND
ND
11.6
NI
NI
NI
NI
IMAC = 1 pg/I
16-May-18
EPA 6010
2.5
10
ND
ND
AB
15.7
ND
ND
3.6 J
ND
-
6-Dec-18
EPA 6010D
2.5
5
ND
5.1
AB
17.5
3.1 J
ND
3.7 J
ND
ND
Verification Sample >
7-Feb-19
EPA 6010D
2.5
5
-
ND
AB
-
-
-
-
ND
8-May-19
EPA 6010D
2.5
5
ND
ND
AB
14.3
ND
ND
ND
3.7 J
ND
8-Nov-19
EPA 6010D
1.1
5
2.8 J
2.2 J
AB
4.4 J
2.1 J
NS
ND
ND
ND
BKGD = 11 pg/L (6/09/2020)
8-May-20
EPA 6010D
3.6
5
ND
7.8
AB
8.0
ND
NS
ND
ND
ND
11-Nov-20
EPA 6010D
3.6
5
8.7
-
-
7.5
-
-
-
-
ND
28-Jan-21
EPA 6010D
3.6
5
-
ND
--
--
ND
-
ND
ND
ND
Copper
8-Dec-15
EPA 6010
2.5
10
ND
J
30.0
3.3 J
NI
NI
NI
NI
ND
Verification Sample >
4-Feb-16
EPA 6010
2.5
10
-
--
10.4
-
NI
NI
NI
NI
ND
NC21- = 1,000 pg/I (01/01/10).
4-May-16
EPA 6010
2.5
10
8.7 J
9.8 J
ND
2.8 J
NI
NI
NI
NI
ND
13-Dec-16
EPA 6010
2.5
10
4.1 J
11.9
2.8 J
9.1 J
NI
NI
NI
NI
ND
27-Jun-17
EPA 6010
2.5
10
3.9 J
3.3 J
ND
ND
NI
NI
NI
NI
ND
13-Dec-17
2.5
10
ND
5.9 J
ND
ND
NI
NI
NI
NI
ND
16-May-18
EPA 6010
2.5
10
ND
ND
AB
ND
ND
ND
ND
ND
-
6-Dec-18
EPA 6010D
2.5
5
ND
14.6
AB
ND
ND
ND
ND
4.1 J
5.8
8-May-19
EPA 6010D
2.5
5
3.3 J
2.8 J
AB
ND
ND
ND
ND
11.5
ND
8-Nov-19
EPA 6010D
2.1
5
6.0
6.7
AB
14.2
ND
NS
2.2 J
4.4 J
ND
8-May-20
EPA 6010D
4.3
5
4.5 J
13.7
AB
ND
ND
NS
ND
ND
ND
11-Nov-20
EPA 6010D
4.3
5
19.7
-
-
ND
-
-
-
-
ND
28-Jan-21
EPA 6010D
4.3
5
-
ND
-
--
ND
-
ND
ND
ND
Iron
10-Apr-14
EPA 6010
50
300
ND
-
559
22,800
NI
NI
NI
NI
ND
NC21- = 300 pg/1 (01/01/10)
6-May-14
EPA 6010
50
300
177 J
-
3,930
16,300
NI
NI
NI
NI
ND
20-Jun-14
EPA 6010
50
300
200 J
--
402
14,400
NI
NI
NI
NI
ND
17-Jul-14
EPA 6010
50
300
381
--
2,280
4,390
NI
NI
NI
NI
ND
23-Oct-14
EPA 6010
50
300
2,340
3,990
719
16,700
NI
NI
NI
NI
ND
21-May-15
EPA 6010
50
300
350
6,660
295 J
16,100
NI
NI
NI
NI
ND
8-Dec-15
EPA 6010
25
300
1,380
3,590
29,700
27,800
NI
NI
NI
NI
ND
Verification Sample >
4-Feb-16
EPA 6010
25
300
-
-
9,840
--
NI
NI
NI
NI
ND
4-May-16
EPA 6010
25
300
7,630
8,590
929
30,500
NI
NI
NI
NI
27.3 J
13-Dec-16
EPA 6010
25
300
2,020
9,700
2,440
37,400
NI
NI
NI
NI
ND
27-Jun-17
EPA 6010
25
300
2,340
3,140
1,300
40,800
NI
NI
NI
NI
ND
13-Dec-17
EPA 6010
25
300
1,030
5,160
14,500
NI
NI
NI
NI
16-May-18
EPA 6010
25
300
295 J
1,920
AB
19,900
75.6 J
1,570
3,140
110 J
-
6-Dec-18
EPA 6010D
25
50
141
13,600
AB
17,600
323
1,550
5,440
3,410
167
Verification Sample >
7-Feb-19
EPA 6010D
25
50
--
3,290
AB
--
--
-
-
532
ND
8-May-19
EPA 6010D
25
50
2,550
2,900
AB
18,300
856
1,310
1,770
7,820
ND
8-Nov-19
EPA 6010D
19.5
50
4,320
5,530
AB
41,800
480
NS
883
2,460
155
BKGD = 14,182 pg/L (6/09/2020)
8-May-20
EPA 6010D
41.5
50
2,580
15,800
AB
35,100
401
NS
1,410
237
ND
23-Sep-20
EPA 6010D
41.5
50
-
508
-
-
--
-
-
-
-
11-Nov-20
EPA 6010D
41.5
50
15,400 M
-
-
-
--
-
-
-
ND
28-Jan-21
EPA 6010D
41.5
50
-
444
--
19,600
1340
-
713
240
-
Lead
8-Dec-15
EPA 6010
2.5
10
ND
3.0 J
39.4
3.2 J
NI
NI
NI
NI
ND
NC21- = 15 pg/I (01/01/10)
4-Feb-16
EPA 6010
2.5
10
-
-
10.5
-
NI
NI
NI
NI
ND
4-May-16
EPA 6010
2.5
10
ND
4.4 J
ND
ND
NI
NI
NI
NI
ND
13-Dec-16
EPA 6010
2.5
10
ND
5.1 J
ND
6.2 J
NI
NI
NI
NI
ND
27-Jun-17
EPA 6010
2.5
10
ND
ND
ND
3.4 J
NI
NI
NI
NI
ND
13-Dec-17
EPA 6010
2.5
10
ND
3.6 J
ND
ND
NI
NI
NI
NI
ND
16-May-18
EPA 6010
2.5
10
ND
ND
AB
65.8
ND
ND
2.8 J
ND
-
6-Dec-18
EPA 6010D
2.5
5
ND
6.5
AB
ND
ND
ND
ND
ND
ND
8-May-19
EPA 6010D
2.5
5
ND
ND
AB
ND
ND
ND
ND
4.7 J
ND
8-Nov-19
EPA 6010D
1.6
5
ND
2.5 J
AB
10.7
1.9 J
NS
ND
ND
ND
8-May-20
EPA 6010D
4.5
5
ND
7.4
AB
ND
ND
NS
ND
ND
ND
11-Nov-20
EPA 6010D
4.5
5
ND
--
-
ND
-
-
-
-
ND
28-Jan-21
EPA 6010D
4.5
5
-
ND
-
--
ND
-
ND
ND
ND
Manganese
10-Apr-14
EPA 6010
5
50
20.8 J
-
132
5,450
NI
NI
NI
NI
ND
NC21- = 50 pg/I (01/01/10)
6-May-14
EPA 6010
5
50
22.5 J
-
77.5
4,830
NI
NI
NI
NI
ND
20-Jun-14
EPA 6010
5
50
24.7 J
--
52.2
3,790
NI
NI
NI
NI
ND
17-Jul-14
EPA 6010
5
50
27.9 J
--
39.8 J
3,380
NI
NI
NI
NI
ND
23-Oct-14
EPA 6010
5
50
73.6
77.5
16.6 J
3,930
NI
NI
NI
NI
ND
21-May-15
EPA 6010
5
50
27.4 J
146
11.7 J
3,060
NI
NI
NI
NI
ND
8-Dec-15
EPA 6010
2.5
50
50.0 J
68.5
462
3,220
NI
Ni
NI
NI
ND
Verification Sample >
4-Feb-16
EPA 6010
2.5
50
-
124
-
NI
NI
NI
NI
ND
4-May-16
EPA 6010
2.5
50
142
148
14.3 J
4,170
NI
NI
NI
NI
ND
13-Dec-16
EPA 6010
2.5
50
48.1 J
169
33.0 J
3,380
NI
NI
NI
NI
ND
27-Jun-17
EPA 6010
2.5
50
60.3
65.5
24.9 J
3,700
NI
NI
NI
NI
ND
13-Dec-17
EPA 6010
2.5
50
40.8 J
99.3
11.5 J
3,720
NI
NI
NI
NI
ND
16-May-18
EPA 6010
2.5
50
25.8 J
35.3 J
AB
4,260
17.0 J
29.5 J
762
ND
-
6-Dec-18
EPA 6010D
2.5
5
23.6
235
AB
4,870
73.7
29.5
477
41.2
10
Verification Sample >
7-Feb-19
EPA 6010D
2.5
5
-
61.6
AB
--
--
-
-
-
ND
8-May-19
EPA 6010D
2.5
5
73.7
68.6
AB
4,590
52.4
25.5
280
105
ND
8-Nov-19
EPA 6010D
0.9
5
126
106
AB
4,260
54.2
NS
334
31.0
6.8
BKGD = 535 pg/L (6/09/2020)
8-May-20
EPA 6010D
3.4
5
84.2
328
AB
5,340
58.7
NS
127
3.7 J
ND
11-Nov-20
EPA 6010D
3.4
5
348
-
-
-
--
-
-
-
ND
28-Jan-21
EPA 6010D
3.4
5
--
10
-
7,780
70.7
-
33.8
5.5
-
Nickel
10-Apr-14
EPA 6010
5
50
ND
--
ND
ND
NI
NI
NI
NI
ND
NC21- = 100 pg/1 (10/23/07)
6-May-14
EPA 6008
5
50
ND
--
ND
10.6 J
NI
NI
NI
NI
ND
20-Jun-14
EPA 6009
5
50
ND
-
ND
ND
NI
NI
NI
NI
ND
17-Jul-14
EPA 6010
5
50
ND
-
ND
5 J
NI
NI
NI
NI
ND
23-Oct-14
EPA 6010
5
50
ND
ND
ND
5.1 J
NI
NI
NI
NI
ND
21-May-15
EPA 6010
5
50
ND
4.3
ND
4.3 J
NI
NI
NI
NI
ND
8-Dec-15
EPA 6010
2.5
50
ND
2.5 J
18.7 J
3.0 J
NI
NI
NI
NI
ND
Verification Sample >
4-Feb-16
EPA 6010
2.5
50
-
--
5.7 J
-
NI
NI
NI
NI
ND
4-May-16
EPA 6010
2.5
50
ND
5.9 J
ND
2.7 J
NI
NI
NI
NI
ND
13-Dec-16
EPA 6010
2.5
50
ND
6.8 J
ND
3.4 J
NI
NI
NI
NI
ND
27-Jun-17
EPA 6010
2.5
50
ND
ND
ND
ND
NI
NI
NI
NI
ND
13-Dec-17
EPA 6010
2.5
50
ND
3.4 J
ND
5.4 J
NI
NI
NI
NI
ND
16-May-18
EPA 6010
2.5
50
ND
ND
AB
4.4 J
ND
ND
3.4 J
ND
-
6-Dec-18
EPA 6010D
2.5
5
ND
7.4
AB
4.9 J
ND
ND
3.4 J
ND
ND
8-May-19
EPA 6010D
2.5
5
ND
ND
AB
5.3
ND
ND
ND
3.2 J
ND
8-Nov-19
EPA 6010D
0.9
5
1.1 J
3.0 J
AB
4.8 J
ND
NS
ND
ND
3 J
8-May-20
EPA 6010D
3.5
5
ND
9.4
AB
ND
ND
NS
ND
ND
ND
11-Nov-20
EPA 6010D
3.5
5
ND
--
-
ND
-
-
-
-
ND
28-Jan-21
EPA 6010D
3.5
5
-
ND
-
-
ND
-
ND
ND
ND
Burke County -- Johns River CDLF LaBella Associates
Expansion, Permit No. 12-03 Page 2 of 6

TABLE A2-3: Historically Detected Groundwater Constituents in Compliance Wells
Sample
EPA
(Background)
Collection Date
Method
DL
RL
MW-21
MW-20
MW-22S
MW-38
MW-23S
MW-24S
MW-30
MW-35
Blanks
Thallium
8-Dec-15
EPA 6010
5
5.5
ND
ND
ND
ND J
NI
NI
NI
NI
ND
GWPS = 0.28 pg/I
4-Feb-16
EPA 6010
2.5
50
-
-
9.1
-
Ni
Ni
Ni
Ni
ND
4-May-16
EPA 6010
5
5.5
ND
ND
ND
ND
NI
NI
NI
NI
ND
13-Dec-16
EPA 6010
5
5.5
ND
ND
ND
ND
Ni
NI
NI
NI
ND
27-Jun-17
EPA 6020B
0.02
5.5
ND
0.077 J
0.057 J
ND
NI
NI
NI
NI
ND
13-Dec-17
EPA 6020
0.02
5.5
ND
0.15 J
0.051 J
ND
NI
NI
NI
NI
ND
IMAC - 0.2 pg/I
16-May-18
EPA 6020
0.5
2
ND
ND
AB
ND
ND
ND
ND
ND
-
6-Dec-18
EPA 6020B
0.06
0.1
ND
0.26
AB
ND
ND
0.081 J
0.13
0.062 J
ND
8-May-19
EPA 6020B
0.06
0.1
ND
0.12
AB
ND
ND
0.073 J
ND
0.15
ND
8-Nov-19
EPA 6020E
0.06
0.1
ND
0.15
AB
0.12
ND
NS
ND
ND
ND
8-May-20
EPA 6020B
0.05
0.1
ND
0.38
AB
ND
ND
NS
ND
ND
ND
23-Sep-20
EPA 6020E
0.05
0.1
-
0.052 J
-
-
-
-
-
-
-
11-Nov-20
EPA 6020B
0.05
0.1
ND
-
-
ND
-
-
-
-
ND
28-Jan-21
EPA 6020E
0.05
0.1
-
0.06 J
-
-
ND
-
ND
ND
ND
Sulfate
10-Apr-14
EPA 300.0
2,000
250,000
ND
-
2,110 J
3,430 J
NI
NI
NI
NI
ND
NC21- = 250,000 pg/I (01/01/10)
6-May-14
EPA 300.0
2,000
250,000
ND
-
8,740 J
ND
NI
NI
NI
NI
ND
20-Jun-14
EPA 300.0
2,000
250,000
ND
-
ND
10,100 J
NI
NI
NI
NI
ND
17-Jul-14
EPA 300.0
1,000
250,000
1,340 J
-
1,560 J
8,720 J
NI
NI
NI
NI
ND
23-Oct-14
EPA 300.0
1,000
250,000
ND
1,300 J
1,320 J
3,320 J
NI
NI
NI
NI
ND
21-May-15
EPA 300.0
1,000
250,000
ND
ND
ND
2,650 J
NI
NI
NI
NI
ND
8-Dec-15
EPA 300.0
1,000
250,000
ND
ND
ND
4,640 J
NI
NI
NI
NI
ND
4-May-16
EPA 300.0
1,000
250,000
ND
1,270 J
1,290 J
2,770 J
NI
NI
NI
NI
ND
13-Dec-16
EPA 300.0
1,000
250,000
1,340 J
1,530 J
1,460 J
6,820 J
NI
NI
NI
NI
--
27-Jun-17
EPA 300.0
500
250,000
ND
712 J
761 J
5,400 J
NI
NI
NI
NI
--
13-Dec-17
EPA 300.0
500
250,000
ND
ND
ND
1,190 J
NI
NI
NI
NI
ND
16-May-18
EPA 300.0
500
250,000
ND
ND
AB
983 J
2,890 J
ND
ND
561 J
--
6-Dec-18
EPA 300.0
500
1,000
ND
ND
AB
716 J
1,030
ND
ND
541 J
855 J
8-May-19
EPA 300.0
500
1,000
-
ND
AB
568 J
939 J
ND
ND
535 J
ND
8-Nov-19
EPA 300.0
500
1,000
ND
ND
AB
4,930
1,100
NS
ND
555 J
ND
8-May-20
EPA 300.0 Rev 2.1
500
1,000
ND
ND
AB
2,700
ND
NS
ND
619 J
ND
11-Nov-20
A 300.0 Rev 2.1199
500
1,000
ND
-
-
-
-
-
ND
28-Jan-21
A 300.0 Rev 2.1199
500
1,000
-
ND
-
806 J
746 J
-
ND
ND
-
Total Dissolved Solids (TDS)
10-Apr-14
SM 2540C
25,000
25,000
37,000
--
68,000
302,000
Ni
Ni
Ni
Ni
ND
NC21- = 500,000 pg/I (01/01/10)
6-May-14
SM 2540C
25,000
25,000
ND
--
30,000
257,000
Ni
Ni
Ni
Ni
ND
20-Jun-14
SM 2540C
25,000
25,000
ND
-
ND
301,000
NI
NI
NI
NI
ND
17-Jul-14
SM 2540C
25,000
25,000
ND
-
ND
245,000
Ni
Ni
NI
Ni
ND
23-Oct-14
SM 2540C
25,000
25,000
ND
25,000
ND
265,000
NI
NI
NI
NI
ND
21-May-15
SM 2540C
25,000
25,000
ND
36,000
29,000
268,000
Ni
Ni
Ni
Ni
-
8-Dec-15
SM 2540C
25,000
25,000
ND
31,000
96,000
311,000
NI
NI
NI
NI
--
4-May-16
SM 2540C
25,000
25,000
ND
30,000
30,000
299,000
Ni
Ni
Ni
Ni
--
13-Dec-16
SM 2540C
25,000
25,000
ND
33,000
ND
366,000
NI
NI
NI
NI
--
27-Jun-17
SM 2540C
25,000
25,000
ND
34,000
28,000
374,000
Ni
Ni
Ni
Ni
--
13-Dec-17
SM 2540C
25,000
25,000
ND
45,000
ND
255,000
NI
NI
NI
NI
ND
16-May-18
SM 2540C
25,000
25,000
ND
34,000
AB
282,000
59,000
31,000
56,000
27,000
-
6-Dec-18
SM 2540C
25,000
25,000
ND
82,000
AB
277,000
25,000
26,000
55,000
37,000
ND
8-May-19
SM 2540C-2011
25,000
25,000
-
27,000
AB
284,000
29,000
39,000
48,000
38,000
--
8-Nov-19
SM 254OC-2011
25,000
25,000
ND
37,000
AB
451,000
28,000
NS
67,000
51,000
ND
8-May-20
SM 2540C-2012
25,000
25,000
NO
26,000
AB
357,000
ND
NS
25,000
ND
ND
28-Jan-21
SM 2540C-2011
25,000
25,000
-
42,000
--
292,000
30000
--
157,000
48000
--
Vanadium
10-Apr-14
EPA 6010
5
25
ND
--
ND
ND
NI
NI
NI
NI
ND
GWPS = 0.3 pg/I (10/1/10)
6-May-14
EPA 6010
5
25
ND
--
7.3 J
ND
NI
NI
NI
NI
ND
20-Jun-14
EPA 6010
5
25
ND
--
ND
ND
Ni
Ni
Ni
Ni
ND
17-Jul-14
EPA 6010
5
25
ND
--
ND
ND
NI
NI
NI
NI
ND
23-Oct-14
EPA 6010
5
25
9.6 J
6.5 J
ND
ND
NI
Al
NI
NI
ND
21-May-15
EPA 6010
5
25
ND
11.6
ND
4 J
NI
NI
NI
NI
ND
8-Dec-15
EPA 6010
2.5
25
ND J
6.9 J
44.8
8.5 J
NI
NI
NI
Al
ND
Verification Sample >
4-Feb-16
EPA 6010
2.5
50
-
--
16.0 J
-
NI
NI
NI
NI
ND
4-May-16
EPA 6010
2.5
25
29.7
14.5 J
ND
ND
NI
Al
Al
Al
ND
13-Dec-16
EPA 6010
2.5
25
6.8 J
13.9 J
3.30 J
ND
NI
NI
NI
NI
ND
27-Jun-17
EPA 6010
2.5
25
9.4 J
5.1 J
ND
2.8 J
NI
NI
NI
NI
ND
13-Dec-17
EPA 6010
2.5
25
4.2 J
8.4 J
ND
ND
NI
NI
NI
NI
ND
IMAC = 0.3 pg/I
16-May-18
EPA 6010
2.5
25
ND
3.2 J
AB
ND
ND
ND
4.7 J
ND
6-Dec-18
EPA 6010D
2.5
5
ND
20.7
AB
ND
ND
ND
6.6
6.2
ND
Verification Sample >
7-Feb-19
EPA 6010D
2.5
5
--
5.1
AB
-
-
-
ND
ND
ND
8-May-19
EPA 6010D
2.5
5
10.4
4.2 J
AB
ND
ND
ND
ND
13.6
ND
Verification Sample >
24-Jul-19
EPA 6010D
2.5
5.0
-
--
AB
--
-
-
-
6.4
-
8-Nov-19
EPA 6010D
1.3
5.0
17.5
8.9
AB
14.6
ND
NS
ND
4.3 J
ND
BKGD = 45.2 pg/L (6/09/2020)
8-May-20
EPA 6010D
3.9
5.0
10.3
28.1
AB
ND
ND
NS
ND
ND
ND
11-Nov-20
EPA 6010D
3.9
5.0
63
-
-
ND
-
-
-
-
ND
28-Jan-21
EPA 6010D
3.9
5.0
-
ND
--
-
ND
--
ND
ND
ND
Zinc
10-Apr-14
EPA 6010
10
10
ND
--
19.6
ND
NI
NI
NI
NI
ND
NC21- = 1,000 pg/I (01/01/10)
6-May-14
EPA 6010
10
10
ND
--
15.5
15.8
Ni
Ni
Ni
Ni
ND
20-Jun-14
EPA 6010
10
10
ND
--
ND
ND
Ni
Ni
NI
NI
10.9
17-Jul-14
EPA 6010
10
10
ND
--
ND
12.5 B
NI
NI
NI
NI
10.5
23-Oct-14
EPA 6010
10
10
ND
12.8
ND
ND
NI
NI
NI
NI
ND
21-May-15
EPA 6010
10
10
26.4
19.7
ND
ND
NI
NI
NI
NI
ND
8-Dec-15
EPA 6010
5
10
ND
10.3
127
8.7 J
NI
NI
NI
NI
ND
Verification Sample >
4-Feb-16
EPA 6010
5
10
-
-
36.5
ND
NI
NI
NI
NI
ND
4-May-16
EPA 6010
5
10
10.5
22.4
5.5 J
6.4 J
NI
NI
NI
NI
ND
13-Dec-16
EPA 6010
5
10
ND
23.8
9.3 J
9.5 J
NI
NI
NI
NI
ND
27-Jun-17
EPA 6010
5
10
8.2 J
11.4
11.9
7.0 J
NI
NI
NI
NI
ND
13-Dec-17
EPA 6010
5
10
ND
14.8
ND
ND
NI
NI
NI
NI
ND
16-May-18
EPA 6010
5
10
5.2 J
5.5 J
AB
ND
5.7 J
7.0 J
9.0 J
ND
-
6-Dec-18
EPA 6010D
5
10
ND
32.8
AB
ND
ND
ND
16
7.4 J
51.4
8-May-19
EPA 6010D
5
10
18.1
10.3
AB
ND
ND
5.7 J
5.3 J
15.0
ND
8-Nov-19
EPA 6010D
3.9
10
6.7 J
14.6
AB
22.1
ND
NS
ND
5.1 J
ND
8-May-20
EPA 6010D
9.5
10
ND
44.2
AB
ND
ND
NS
ND
ND
ND
11-Nov-20
EPA 6010D
9.5
10
17.2
-
-
ND
-
-
-
-
ND
28-Jan-21
EPA 6010D
9.5
10
--
ND
-
-
11.4
-
ND
ND
ND
Mercury
8-May-19
EPA 7470A
0.1
0.2
ND
--
AB
ND
--
-
-
ND
0.11 J
NC2L =1 ug/I
8-Nov-19
EPA 7470A
0.1
0.2
ND
0.13 J
AB
ND
0.13 J
NS
ND
ND
0.14 J
8-May-20
EPA 7470A
0.12
0.2
ND
ND
AB
ND
ND
NS
ND
ND
0.58
11-Nov-20
EPA 7470A
0.12
0.2
ND
-
-
-
-
-
-
-
ND
28-Jan-21
EPA 7470A
0.12
0.2
-
ND
-
ND
ND
-
ND
ND
-
ORGANICS
Acetone
10-Apr-14
EPA 8260
10
100
ND
--
ND
10.2 J
NI
NI
NI
NI
ND
NC21- = 6,000 pg/I
6-May-14
EPA 8260
10
100
ND
-
ND
ND
NI
NI
NI
NI
ND
20-Jun-14
EPA 8260
10
100
ND
-
ND
ND
NI
NI
NI
NI
ND
17-Jul-14
EPA 8260
10
100
ND
-
ND
ND
Al
NI
NI
NI
ND
23-Oct-14
EPA 8260
10
100
ND
ND
ND
ND
NI
NI
NI
NI
ND
21-May-15
EPA 8260
10
100
ND
ND
ND
ND
NI
NI
NI
NI
ND
8-Dec-15
EPA 8260
10
100
ND
ND
ND
ND
NI
NI
NI
NI
ND
4-May-16
EPA 8260
10
100
ND
ND
ND
ND
NI
NI
NI
NI
ND
13-Dec-16
EPA 8260
10
100
ND
ND
ND
ND
NI
NI
NI
NI
-
27-Jun-17
EPA 8260
10
100
35.8 B
12.4 B
20.2 B
12.2 B
NI
Ni
NI
NI
35.3 J
13-Dec-17
EPA 8260
10
100
ND
ND
ND
24.5 J
NI
NI
NI
NI
ND
16-May-18
EPA 8260
10
100
ND
ND
AB
ND
ND
ND
ND
ND
-
6-Dec-18
EPA 8260
10
25
ND
ND
AB
ND
ND
ND
ND
ND
ND
8-May-19
EPA8260D
8.2
25
ND
ND
AB
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA8260D
6.2
25
ND
ND
AB
ND
ND
NS
ND
ND
ND
8-May-20
EPA8260D
6.2
25
ND
ND
AB
ND
ND
NS
ND
ND
ND
11-Nov-20
EPA8260D
6.2
25
ND
-
-
ND
-
-
-
-
ND
28-Jan-21
EPA8260D
6.2
25
-
ND
-
-
ND
-
ND
-
ND
Burke County -- Johns River CDLF LaBella Associates
Expansion, Permit No. 12-03 Page 3 of 6

TABLE A2-3: Historically Detected Groundwater Constituents in Compliance Wells
A
Sample
EPA
(Background)
nalyte
ollection Date
Method
DL
RL
MW-21
MW-20
MW-22S
MW-38
MW-23S
MW-24S
MW-30
MW-35
Blanks
Benzene
10-Apr-14
EPA 8260
0.25
1
ND
--
ND
6.6
NI
NI
NI
NI
ND
NC21- = 1 pg/I (10/23/07)
6-May-14
EPA 8260
0.25
1
ND
--
ND
6.5
NI
NI
NI
NI
ND
20-Jun-14
EPA 8260
0.25
1
ND
-
ND
5.5
NI
NI
NI
NI
ND
17-Jul-14
EPA 8260
0.25
1
ND
-
ND
4.6
NI
NI
NI
NI
ND
23-Oct-14
EPA 8260
0.25
1
ND
ND
ND
5.9
NI
NI
NI
NI
ND
21-May-15
EPA 8260
0.25
1
ND
ND
ND
4.9
NI
NI
NI
NI
ND
8-Dec-15
EPA 8260
0.25
1
ND
ND
ND
4.4
NI
NI
NI
NI
ND
4-May-16
EPA 8260
0.25
1
ND
ND
ND
5.4
NI
NI
NI
NI
ND
13-Dec-16
EPA 8260
0.25
1
ND
ND
ND
3.0
NI
NI
NI
NI
ND
27-Jun-17
EPA 8260
0.25
1
ND
ND
ND
5.0
NI
NI
NI
NI
ND
13-Dec-17
EPA 8260
0.25
1
ND
ND
ND
5.0
NI
NI
NI
NI
ND
16-May-18
EPA 8260
0.25
1
ND
ND
AB
4.6
ND
ND
ND
ND
-
6-Dec-18
EPA 8260
0.25
1
ND
ND
AB
5.6
ND
ND
ND
ND
ND
8-May-19
EPA8260D
0.2
1
ND
ND
AB
7.3
ND
ND
ND
ND
ND
8-Nov-19
EPA8260D
0.15
1
ND
ND
AB
2.5
ND
NS
ND
ND
ND
8-May-20
EPA8260D
0.15
1
ND
ND
AB
4.0
ND
NS
ND
ND
ND
11-Nov-20
EPA8260D
0.15
1
ND
-
-
4.7
-
-
-
-
ND
28-Jan-21
EPA8260D
0.15
1
-
ND
-
-
ND
-
ND
-
ND
Chlorobenzene
10-Apr-14
EPA 8260
0.23
3
ND
-
ND
0.71 J
NI
NI
NI
NI
ND
NC21- = 50 pg/I (10/23/07)
6-May-14
EPA 8260
0.23
3
ND
--
ND
0.6 J
NI
NI
NI
NI
ND
20-Jun-14
EPA 8260
0.23
3
ND
--
ND
0.5 J
NI
NI
NI
NI
ND
17-Jul-14
EPA 8260
0.23
3
ND
--
ND
0.61 J
NI
NI
NI
NI
ND
23-Oct-14
EPA 8260
0.23
3
ND
ND
ND
0.61 J
NI
NI
NI
NI
ND
21-May-15
EPA 8260
0.23
3
ND
ND
ND
0.51 J
NI
NI
NI
NI
ND
8-Dec-15
EPA 8260
0.23
3
ND
ND
ND
0.49 J
NI
NI
NI
NI
ND
4-May-16
EPA 8260
0.23
3
ND
ND
ND
0.56 J
NI
NI
NI
NI
ND
13-Dec-16
EPA 8260
0.23
3
ND
ND
ND
0.41 J
NI
NI
NI
NI
ND
27-Jun-17
EPA 8260
0.23
3
ND
ND
ND
ND
NI
NI
NI
NI
ND
13-Dec-17
EPA 8260
0.23
3
ND
ND
ND
0.68 J
NI
NI
NI
NI
ND
16-May-18
EPA 8260
0.23
3
ND
ND
AB
0.70 J
ND
ND
ND
ND
-
6-Dec-18
EPA 8260
0.23
1
ND
ND
AB
0.83 J
ND
ND
ND
ND
ND
8-May-19
EPA8260D
0.53
1
ND
ND
AB
0.99 J
ND
ND
ND
ND
ND
8-Nov-19
EPA8260D
0.23
1
ND
ND
AB
0.40 J
ND
NS
ND
ND
ND
8-May-20
EPA8260D
0.23
1
ND
ND
AB
0.60 J
ND
NS
ND
ND
ND
11-Nov-20
EPA8260D
0.23
1
ND
-
-
0.67 J
-
-
-
-
ND
28-Jan-21
EPA8260D
0.23
1
-
ND
-
-
ND
-
ND
-
ND
1,2-Dichlorobenzene
10-Apr-14
EPA 8260
0.3
5
ND
-
ND
0.3 J
NI
NI
NI
NI
ND
NC21- = 20 pg/I (01/01/10)
6-May-14
EPA 8260
0.3
5
ND
--
ND
0.36 J
NI
NI
NI
NI
ND
20-Jun-14
EPA 8260
0.3
5
ND
-
ND
ND
NI
NI
NI
NI
ND
17-Jul-14
EPA 8260
0.3
5
ND
-
ND
ND
NI
NI
NI
NI
ND
23-Oct-14
EPA 8260
0.3
5
ND
ND
ND
0.31 J
NI
NI
NI
NI
ND
21-May-15
EPA 8260
0.3
5
ND
ND
ND
ND
NI
NI
NI
NI
ND
8-Dec-15
EPA 8260
0.3
5
ND
ND
ND
ND
NI
NI
NI
NI
ND
4-May-16
EPA 8260
0.3
5
ND
ND
ND
0.30 J
NI
NI
NI
NI
ND
13-Dec-16
EPA 8260
0.3
5
ND
ND
ND
ND
NI
NI
NI
NI
ND
27-Jun-17
EPA 8260
0.3
5
ND
ND
ND
ND
NI
NI
NI
NI
ND
13-Dec-17
EPA 8260
0.3
5
ND
ND
ND
0.37 J
NI
NI
NI
NI
ND
16-May-18
EPA 8260
0.3
5
ND
ND
AB
0.34 J
ND
ND
ND
ND
-
6-Dec-18
EPA 8260
0.3
1
ND
ND
AB
ND
ND
ND
ND
ND
ND
8-May-19
EPA8260D
0.49
1
ND
ND
AB
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA8260D
0.29
1
ND
ND
AB
ND
ND
NS
ND
ND
ND
8-May-20
EPA8260D
0.29
1
ND
ND
AB
ND
ND
NS
ND
ND
ND
11-Nov-20
EPA8260D
0.29
1
ND
-
-
0.38 J
-
-
-
-
ND
28-Jan-21
EPA8260D
0.29
1
-
ND
-
--
ND
-
ND
-
ND
1,4-Dichlorobenzene
10-Apr-14
EPA 8260
0.33
1
ND
-
ND
13.9
NI
NI
NI
NI
ND
NC21- = 6 pg/I (01/01/10)
6-May-14
EPA 8260
0.33
1
ND
--
ND
13.5
NI
NI
NI
NI
ND
20-Jun-14
EPA 8260
0.33
1
ND
-
ND
9.9
NI
NI
NI
NI
ND
17-Jul-14
EPA 8260
0.33
1
ND
-
ND
13.0
NI
NI
NI
NI
ND
23-Oct-14
EPA 8260
0.33
1
ND
ND
ND
12.9
NI
NI
NI
NI
ND
21-May-15
EPA 8260
0.33
1
ND
ND
ND
12.3
NI
NI
NI
NI
ND
8-Dec-15
EPA 8260
0.33
1
ND
ND
ND
12.2
NI
NI
NI
NI
ND
4-May-16
EPA 8260
0.33
1
ND
ND
ND
13.3
NI
NI
NI
NI
ND
13-Dec-16
EPA 8260
0.33
1
ND
ND
ND
8.3
NI
NI
NI
NI
ND
27-Jun-17
EPA 8260
0.33
1
ND
ND
ND
11.0
NI
NI
NI
NI
ND
13-Dec-17
EPA 8260
0.33
1
ND
ND
ND
14.4
NI
NI
NI
NI
ND
16-May-18
EPA 8260
0.33
1
ND
ND
AB
15.1
ND
ND
ND
ND
-
6-Dec-18
EPA 8260
0.33
1
ND
ND
AB
16.9
ND
ND
ND
ND
ND
8-May-19
EPA8260D
0.58
1
ND
ND
AB
22.1
ND
ND
ND
ND
ND
8-Nov-19
EPA8260D
0.26
1
ND
ND
AB
7.4
ND
NS
ND
ND
ND
8-May-20
EPA8260D
0.26
1
ND
ND
AB
10.9
ND
NS
ND
ND
ND
11-Nov-20
EPA8260D
0.26
1
ND
-
-
14.0
-
-
-
-
ND
28-Jan-21
EPA8260D
0.26
1
-
ND
-
-
ND
-
ND
-
ND
1,1-Dichloroethane
10-Apr-14
EPA 8260
0.32
5
ND
-
ND
8.6
NI
NI
NI
NI
ND
NC21- = 6 pg/I (01/01/10)
6-May-14
EPA 8260
0.32
5
ND
--
ND
8.1
NI
NI
NI
NI
ND
20-Jun-14
EPA 8260
0.32
5
ND
-
ND
8.0
NI
NI
NI
NI
ND
17-Jul-14
EPA 8260
0.32
5
ND
-
ND
5.7
NI
NI
NI
NI
ND
23-Oct-14
EPA 8260
0.32
5
ND
ND
ND
6.9
NI
NI
NI
NI
ND
21-May-15
EPA 8260
0.32
5
ND
ND
ND
5.5
NI
NI
NI
NI
ND
8-Dec-15
EPA 8260
0.32
5
ND
ND
ND
7.2
NI
NI
NI
NI
ND
4-May-16
EPA 8260
0.32
5
ND
ND
ND
6.5
NI
NI
NI
NI
ND
13-Dec-16
EPA 8260
0.32
5
ND
ND
ND
6.0
NI
NI
NI
NI
ND
27-Jun-17
EPA 8260
0.32
5
ND
ND
ND
6.2
NI
NI
NI
NI
ND
13-Dec-17
EPA 8260
0.32
5
ND
ND
ND
4.4 J
NI
NI
NI
NI
ND
16-May-18
EPA 8260
0.32
5
ND
ND
AB
4.1 J
ND
ND
ND
ND
-
6-Dec-18
EPA 8260
0.32
1
ND
ND
AB
5.2
ND
ND
ND
ND
ND
8-May-19
EPA8260D
0.41
1
ND
ND
AB
6.7
ND
ND
ND
ND
ND
8-Nov-19
EPA8260D
0.27
1
ND
ND
AB
4.3
ND
NS
ND
ND
ND
8-May-20
EPA8260D
0.27
1
ND
ND
AB
3.7
ND
NS
ND
ND
ND
11-Nov-20
EPA8260D
0.27
1
ND
--
--
4.1
-
-
-
-
ND
28-Jan-21
EPA8260D
0.27
1
-
ND
-
-
ND
-
ND
-
ND
1,2-Dichloroethane
10-Apr-14
EPA 8260
0.12
1
ND
-
ND
0.77 J
NI
NI
NI
NI
ND
NC21- = 0.4 pg/I (01/01/10)
6-May-14
EPA 8260
0.12
1
ND
--
ND
ND
NI
NI
NI
NI
ND
20-Jun-14
EPA 8260
0.12
1
ND
--
ND
0.63 J
NI
NI
NI
NI
ND
17-Jul-14
EPA 8260
0.12
1
ND
--
ND
0.79 J
NI
NI
NI
NI
ND
23-Oct-14
EPA 8260
0.12
1
ND
ND
ND
0.63 J
NI
NI
NI
NI
ND
21-May-15
EPA 8260
0.12
1
ND
ND
ND
ND
NI
NI
NI
NI
ND
8-Dec-15
EPA 8260
0.24
1
ND
ND
ND
0.70 J
NI
NI
NI
NI
ND
4-May-16
EPA 8260
0.24
1
ND
ND
ND
0.74 J
NI
NI
NI
NI
ND
13-Dec-16
EPA 8260
0.24
1
ND
ND
ND
0.63 J
NI
NI
NI
NI
ND
27-Jun-17
EPA 8260
0.24
1
ND
ND
ND
0.67 J
NI
NI
NI
NI
ND
13-Dec-17
EPA 8260
0.24
1
ND
ND
ND
0.44 J
NI
NI
NI
NI
ND
16-May-18
EPA 8260
0.24
1
ND
ND
AB
0.64 J
ND
ND
ND
ND
-
6-Dec-18
EPA 8260
0.24
1
ND
ND
AB
ND
ND
ND
ND
ND
ND
8-May-19
EPA8260D
0.67
1
ND
ND
AB
0.82 J
ND
ND
ND
ND
ND
8-Nov-19
EPA8260D
0.34
1
ND
ND
AB
0.63 J
ND
NS
ND
ND
ND
8-May-20
EPA8260D
0.34
1
ND
ND
AB
0.49 J
ND
NS
ND
ND
ND
11-Nov-20
EPA8260D
0.34
1
ND
-
0.52 J
-
-
-
-
ND
28-Jan-21
EPA8260D
0.34
1
-
ND
-
-
ND
-
ND
-
ND
Burke County -- Johns River CDLF LaBella Associates
Expansion, Permit No. 12-03 Page 4 of 6

TABLE A2-3: Historically Detected Groundwater Constituents in Compliance Wells
Sample
EPA
(Background)
nalyte
Collection Date
Method
DL
RL
MW-21
MW-20
MW-22S
MW-38
MW-23S
MW-24S
MW-30
MW-35
Blanks
cis-1,2-Dichlaraethene
10-Apr-14
EPA 8260
0.19
5
ND
--
ND
19.6
NI
NI
NI
NI
ND
NC21- = 70 pg/I (10/23/07)
6-May-14
EPA 8260
0.19
5
ND
--
ND
17.1
NI
NI
NI
NI
ND
20-Jun-14
EPA 8260
0.19
5
ND
-
ND
16
NI
NI
NI
NI
ND
17-Jul-14
EPA 8260
0.19
5
ND
-
ND
14.1
NI
NI
NI
NI
ND
23-Oct-14
EPA 8260
0.19
5
ND
ND
ND
16.3
NI
NI
NI
NI
ND
21-May-15
EPA 8260
0.19
5
ND
ND
ND
12.1
NI
NI
NI
NI
ND
8-Dec-15
EPA 8260
0.19
5
ND
ND
ND
14.7
NI
NI
NI
NI
ND
4-May-16
EPA 8260
0.19
5
ND
ND
ND
13.2
NI
NI
NI
NI
ND
13-Dec-16
EPA 8260
0.19
5
ND
ND
ND
12.7
NI
NI
NI
NI
ND
27-Jun-17
EPA 8260
0.19
5
ND
ND
ND
10.9
NI
NI
NI
NI
ND
13-Dec-17
EPA 8260
0.19
5
ND
ND
ND
7.0
NI
NI
NI
NI
ND
16-May-18
EPA 8260
0.19
5
ND
ND
AB
7.1
ND
ND
ND
ND
-
6-Dec-18
EPA 8260
0.19
1
ND
ND
AB
6.9
ND
ND
ND
ND
ND
8-May-19
EPA 8260D
0.66
1
ND
ND
AB
7.8
ND
ND
ND
ND
ND
8-Nov-19
EPA 8260D
0.29
1
ND
ND
AB
7.1
ND
NS
ND
ND
ND
8-May-20
EPA 8260D
0.29
1
ND
ND
AB
7.9
ND
NS
ND
ND
ND
11-Nov-20
EPA 8260D
0.29
1
ND
-
-
8.1
-
-
-
-
ND
28-Jan-21
EPA 8260D
0.29
1
-
ND
-
-
ND
-
ND
-
ND
1,4-Dioxane (p-Dioxane)
6-Dec-18
1.9
2
ND
ND
AB
2.4
ND
ND
ND
ND
ND
NC21- = 3 pg/I
8-May-19
EPA 8260D Mod.
1.2
2
ND
ND
AB
2.5
ND
ND
ND
ND
ND
8-Nov-19
EPA 8260DMod.
1.2
2
ND
ND
AB
2.2
ND
NS
ND
ND
ND
8-May-20
EPA 8260DMod.
1.2
2
ND
ND
AB
2.7
ND
NS
ND
ND
ND
11-Nov-20
EPA 8260DMod.
1.2
2
ND
-
-
--
-
-
-
-
ND
28-Jan-21
EPA 8260DMod.
1.2
2
-
ND
-
2.7
ND
-
ND
ND
ND
Ethylbenzene
10-Apr-14
EPA 8260
0.3
1
ND
-
ND
1.2
NI
NI
NI
NI
ND
NC21- = 600 pg/I (01/01/10)
6-May-14
EPA 8260
0.3
1
ND
--
ND
1.3
NI
NI
NI
NI
ND
20-Jun-14
EPA 8260
0.3
1
ND
-
ND
0.77 J
NI
NI
NI
NI
ND
17-Jul-14
EPA 8260
0.3
1
ND
-
ND
0.64 J
NI
NI
NI
NI
ND
23-Oct-14
EPA 8260
0.3
1
ND
ND
ND
1.3
NI
NI
NI
NI
ND
21-May-15
EPA 8260
0.3
1
ND
ND
ND
1.1
NI
NI
NI
NI
ND
8-Dec-15
EPA 8260
0.3
1
ND
ND
ND
ND
NI
NI
NI
NI
ND
4-May-16
EPA 8260
0.3
1
ND
ND
ND
0.72 J
NI
NI
NI
NI
ND
13-Dec-16
EPA 8260
0.3
1
ND
ND
ND
ND
NI
NI
NI
NI
ND
27-Jun-17
EPA 8260
0.3
1
ND
ND
ND
ND
NI
NI
NI
NI
ND
13-Dec-17
EPA 8260
0.3
1
ND
ND
ND
ND
NI
NI
NI
NI
ND
16-May-18
EPA 8260
0.3
1
ND
ND
AB
0.70 J
ND
ND
ND
ND
-
6-Dec-18
EPA 8260
0.3
1
ND
ND
AB
0.86 J
ND
ND
ND
ND
ND
8-May-19
EPA 8260D
0.45
1
ND
ND
AB
1.6
ND
ND
ND
ND
ND
8-Nov-19
EPA 8260D
0.26
1
ND
ND
AB
ND
ND
NS
ND
ND
ND
8-May-20
EPA 8260D
0.26
1
ND
ND
AB
0.79 J
ND
NS
ND
ND
ND
11-Nov-20
EPA 8260D
0.26
1
ND
-
-
1.4
-
-
-
-
ND
28-Jan-21
EPA 8260D
0.26
1
-
ND
-
--
ND
-
ND
-
ND
2-Hexanone(MBK)
10-Apr-14
EPA 8260
0.46
50
ND
-
0.55 J
ND
NI
NI
NI
NI
ND
IMAC = 280 pg/I (01/01/10)
6-May-14
EPA 8260
0.46
50
ND
--
ND
ND
NI
NI
NI
NI
ND
20-Jun-14
EPA 8260
0.46
50
ND
-
ND
ND
NI
NI
NI
NI
ND
17-Jul-14
EPA 8260
0.46
50
ND
-
ND
ND
NI
NI
NI
NI
ND
23-Oct-14
EPA 8260
0.46
50
ND
ND
ND
ND
NI
NI
NI
NI
ND
IMAC = 280 pg/I (02/01/15)
21-May-15
EPA 8260
0.46
50
ND
ND
ND
ND
NI
NI
NI
NI
ND
8-Dec-15
EPA 8260
0.46
50
ND
ND
ND
ND
NI
NI
NI
NI
ND
16-May-18
EPA 8260
0.46
50
-
ND
AB
ND
ND
ND
ND
ND
-
6-Dec-18
EPA 8260
0.46
5
ND
ND
AB
ND
ND
ND
ND
ND
ND
4-Methyl-2-penta none (MIBK)
10-Apr-14
EPA 8260
0.33
100
ND
-
ND
3.7 J
NI
NI
NI
NI
ND
IMAC = 560 pg/I (12/7/10)
6-May-14
EPA 8260
0.33
100
ND
--
ND
8.2 J
NI
NI
NI
NI
ND
20-Jun-14
EPA 8260
0.33
100
ND
--
ND
ND
NI
NI
NI
NI
ND
17-Jul-14
EPA 8260
0.33
100
ND
--
ND
ND
NI
NI
NI
NI
ND
23-Oct-14
EPA 8260
0.33
100
ND
ND
ND
1.5 J
NI
NI
NI
NI
ND
21-May-15
EPA 8260
0.33
100
ND
ND
ND
NI
NI
NI
NI
ND
8-Dec-15
EPA 8260
0.33
100
ND
ND
ND
ND
NI
NI
NI
NI
ND
4-May-16
EPA 8260
0.33
100
ND
ND
ND
0.89 J
NI
NI
NI
NI
ND
13-Dec-16
EPA 8260
0.33
100
ND
ND
ND
ND
NI
NI
NI
NI
ND
27-Jun-17
EPA 8260
0.33
100
ND
ND
ND
ND
NI
NI
NI
NI
ND
13-Dec-17
EPA 8260
0.33
100
ND
ND
ND
ND
NI
NI
NI
NI
ND
16-May-18
EPA 8260
0.33
100
ND
ND
AB
ND
ND
ND
ND
ND
-
6-Dec-18
EPA 8260
0.33
5
ND
ND
AB
ND
ND
ND
ND
ND
ND
8-May-19
EPA 8260D
0.86
5
ND
ND
AB
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA 8260D
4.5
5
ND
ND
AB
ND
ND
NS
ND
ND
ND
8-May-20
EPA 8260D
4.5
5
ND
ND
AB
ND
ND
NS
ND
ND
ND
11-Nov-20
EPA 8260D
4.5
5
ND
-
-
ND
-
-
-
-
ND
28-Jan-21
EPA 8260D
4.5
5
-
ND
-
-
ND
-
ND
-
ND
Methane
10-Apr-14
RSK 174
3.3
6.6
-
-
-
--
-
-
-
-
-
6-May-14
RSK 175
3.3
6.6
-
-
-
4,150
-
-
-
ND
-
20-Jun-14
RSK 176
3.3
6.6
-
-
-
--
-
-
-
-
-
17-Jul-14
RSK 177
3.3
6.6
-
-
-
-
-
-
-
-
-
23-Oct-14
RSK 175
3.3
6.6
-
-
-
6,820
-
-
-
ND
-
21-May-15
RSK 175
3.3
6.6
-
-
-
4,900
-
-
-
2.0 J
-
8-Dec-15
RSK 175
3.3
6.6
-
-
-
3,112
-
-
-
2.7 J
2.0 J
4-May-16
RSK 176
2.3 J
13-Dec-16
RSK 175
100
100
-
-
-
15,300 J
-
-
-
ND
-
27-Jun-17
RSK 175
100
100
-
-
-
35,400
-
-
-
ND
ND
13-Dec-17
RSK 175
100
100
-
-
-
10,400
-
-
-
ND
ND
16-May-18
RSK 176
6-Dec-18
RSK 175
10
10
-
-
-
12,300
-
-
-
ND
ND
8-May-19
RSK 175 Modified
3.4
10
-
-
-
14,300
-
-
-
7.6 J
ND
8-Nov-19
RSK 175 Modified
2.91
10
1,730
ND
ND
8-May-20
RSK 175 Modified
2.91
10
8,570
6.9 J
11-Nov-20
RSK 175 Modified
3.4
10
-
-
-
12,000
-
-
-
-
-
Methylene Chloride
8-Dec-15
EPA 8260
0.97
1
ND
ND
ND
ND
NI
NI
NI
NI
2.0
4-May-16
EPA 8260
0.97
1
ND
ND
ND
ND
NI
NI
NI
NI
ND
13-Dec-16
EPA 8260
0.97
1
ND
ND
ND
ND
NI
NI
NI
NI
-
27-Jun-17
EPA 8260
0.97
1
ND
ND
ND
ND
NI
NI
NI
NI
ND
NC21- = 5 (02/01/15)
13-Dec-17
EPA 8260
0.97
1
ND
ND
ND
ND
NI
NI
NI
NI
ND
16-May-18
EPA 8260
0.97
1
ND
ND
AB
ND
ND
ND
ND
ND
-
6-Dec-18
EPA 8260
0.97
1
ND
ND
AB
ND
ND
ND
ND
ND
ND
8-May-19
EPA 8260D
0.5
1
ND
ND
AB
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA 8260D
3.7
5
ND
ND
AB
ND
ND
NS
ND
ND
ND
8-May-20
EPA 8260D
3.7
5
ND
ND
AB
ND
ND
NS
ND
ND
ND
11-Nov-20
EPA 8260D
3.7
5
ND
-
-
ND
-
-
-
-
ND
28-Jan-21
EPA 8260D
3.7
5
-
ND
-
--
ND
-
ND
-
ND
Naphthalene
11-Nov-20
EPA 8260D
0.35
j 1
j
j 3.7
-
--
-
--
-
Burke County -- Johns River CDLF LaBella Associates
Expansion, Permit No. 12-03 Page 5 of 6

TABLE A2-3: Historically Detected Groundwater Constituents in Compliance Wells
Sample
EPA
(Background)
Analyte
Collection Date
Method
DL
RL
MW-21
MW-20
MW-22S
MW-38
MW-23S
MW-24S
MW-30
MW-35
Blanks
Tetrahydrofuran
10-Apr-14
EPA 8260
3.1
10
ND
---
ND
923
NI
NI
NI
NI
ND
NC2L = NE (01/01/10)
6-May-14
EPA 8260
3.1
10
ND
--
ND
848
NI
NI
NI
NI
ND
20-Jun-14
EPA 8260
3.1
10
ND
-
ND
758
NI
NI
NI
NI
ND
17-Jul-14
EPA 8260
3.1
10
ND
-
ND
841
NI
NI
NI
NI
ND
23-Oct-14
EPA 8260
3.1
10
ND
ND
ND
744
NI
NI
NI
NI
ND
21-May-15
EPA 8260
3.1
10
ND
ND
ND
407
NI
NI
NI
NI
ND
8-Dec-15
EPA 8260
3.1
10
ND
ND
ND
39.1
NI
NI
NI
NI
ND
4-May-16
EPA 8260
3.1
10
ND
ND
ND
313
NI
NI
NI
NI
ND
13-Dec-16
EPA 8260
3.1
10
ND
ND
ND
ND
NI
NI
NI
NI
-
27-Jun-17
EPA 8260
3.1
10
ND
ND
ND
3.1 J
NI
NI
NI
NI
ND
13-Dec-17
EPA 8260
3.1
10
ND
ND
ND
325
NI
NI
NI
NI
ND
16-May-18
EPA 8260
3.1
10
ND
ND
AB
314
ND
ND
ND
ND
-
6-Dec-18
EPA 8260
3.1
10
ND
ND
AB
447
ND
ND
ND
ND
ND
8-May-19
EPA826OD
1.3
10
ND
ND
AB
470
ND
ND
ND
ND
ND
8-Nov-19
EPA826OD
1.9
10
ND
ND
AB
ND
ND
INS
ND
ND
ND
8-May-20
EPA826OD
1.9
10
ND
ND
AB
95.3
ND
INS
ND
ND
ND
28-Jan-21
EPA826OD
1.9
10
-
ND
-
-
ND
-
ND
-
-
Toluene
10-Apr-14
EPA 8260
0.26
1
ND
-
ND
0.62 J
NI
NI
NI
NI
ND
NC2L = 600 pg/1 (01/01/10)
6-May-14
EPA 8260
0.26
1
ND
--
ND
0.68 J
NI
NI
NI
NI
ND
20-Jun-14
EPA 8260
0.26
1
ND
-
ND
0.32 J
NI
NI
NI
NI
ND
17-Jul-14
EPA 8260
0.26
1
ND
-
ND
0.28 J
NI
NI
NI
NI
ND
23-Oct-14
EPA 8260
0.26
1
ND
ND
ND
0.66 J
NI
NI
NI
NI
ND
21-May-15
EPA 8260
0.26
1
ND
ND
ND
0.48 J
NI
NI
NI
NI
ND
8-Dec-15
EPA 8260
0.26
1
ND
ND
ND
ND
NI
NI
NI
NI
ND
4-May-16
EPA 8260
0.26
1
ND
ND
ND
0.49 J
NI
NI
NI
NI
ND
13-Dec-16
EPA 8260
0.26
1
ND
ND
ND
ND
NI
NI
NI
NI
-
27-Jun-17
EPA 8260
0.26
1
ND
ND
ND
0.30 J
NI
NI
NI
NI
ND
13-Dec-17
EPA 8260
0.26
1
ND
ND
ND
0.70 J
NI
NI
NI
NI
ND
16-May-18
EPA 8260
0.26
1
ND
ND
AB
0.54 J
ND
ND
ND
ND
-
6-Dec-18
EPA 8260
0.26
1
ND
ND
AB
ND
ND
ND
ND
ND
ND
8-May-19
EPA826OD
0.31
1
ND
ND
AB
1.9
0.50 J
ND
ND
ND
ND
8-Nov-19
EPA826OD
0.24
1
ND
ND
AB
ND
ND
INS
ND
ND
ND
8-May-20
EPA826OD
0.24
1
ND
ND
AB
0.45 J
ND
NS
ND
ND
ND
11-Nov-20
EPA826OD
0.24
1
ND
-
-
0.64 J
-
-
-
-
ND
28-Jan-21
EPA826OD
0.24
1
-
ND
-
-
ND
-
ND
-
ND
Trichlorofluoromethane
27-Jun-17
EPA 8260
0.2
1
ND
ND
0.46 J
ND
NI
NI
NI
NI
ND
NC2L = 2,000 pg/I
13-Dec-17
EPA 8260
0.2
1
ND
ND
0.60 J
ND
NI
NI
NI
NI
ND
16-May-18
EPA 8260
0.2
1
ND
ND
AB
ND
ND
ND
ND
ND
-
6-Dec-18
EPA 8260
0.2
1
ND
ND
AB
ND
ND
ND
ND
ND
ND
8-May-19
EPA826OD
0.51
1
ND
ND
AB
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA826OD
0.31
1
ND
ND
AB
ND
ND
NS
ND
ND
ND
8-May-20
EPA826OD
0.31
1
ND
ND
AB
ND
ND
INS
ND
ND
ND
11-Nov-20
EPA826OD
0.31
1
ND
-
-
ND
-
-
-
-
ND
28-Jan-21
EPA826OD
0.31
1
-
ND
-
-
ND
-
ND
-
ND
Trichloroethene
10-Apr-14
EPA 8260
0.47
1
ND
-
ND
2.7
NI
NI
NI
NI
ND
NC2L = 3 pg/I (01/01/10)
6-May-14
EPA 8260
0.47
1
ND
--
ND
2.1
NI
NI
NI
NI
ND
20-Jun-14
EPA 8260
0.47
1
ND
-
ND
2.2
NI
NI
NI
NI
ND
17-Jul-14
EPA 8260
0.47
1
ND
-
ND
2.5
NI
NI
NI
NI
ND
23-Oct-14
EPA 8260
0.47
1
ND
ND
ND
1.8
NI
NI
NI
NI
ND
21-May-15
EPA 8260
0.47
1
ND
ND
ND
0.92 J
NI
NI
NI
NI
ND
8-Dec-15
EPA 8260
0.47
1
ND
ND
ND
2.1
NI
NI
NI
NI
ND
4-May-16
EPA 8260
0.47
1
ND
ND
ND
1.7
NI
NI
NI
NI
ND
13-Dec-16
EPA 8260
0.47
1
ND
ND
ND
1.8
NI
NI
NI
NI
-
27-Jun-17
EPA 8260
0.47
1
ND
ND
ND
2.1
NI
NI
NI
NI
ND
13-Dec-17
EPA 8260
0.47
1
ND
ND
ND
1.3
NI
NI
NI
NI
ND
16-May-18
EPA 8260
0.47
1
ND
ND
AB
1.2
ND
ND
ND
ND
-
6-Dec-18
EPA 8260
0.47
1
ND
ND
AB
ND
ND
ND
ND
ND
ND
8-May-19
EPA826OD
0.34
1
ND
ND
AB
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA826OD
0.22
1
ND
ND
AB
0.73 J
ND
INS
ND
ND
ND
8-May-20
EPA826OD
0.22
1
ND
ND
AB
0.63 J
ND
NS
ND
ND
ND
11-Nov-20
EPA826OD
0.22
1
ND
-
-
ND
-
-
-
-
ND
28-Jan-21
EPA826OD
0.22
1
-
ND
-
-
ND
-
ND
-
ND
Vinyl chloride
4-May-16
EPA 8260
0.62
1
ND
ND
ND
1.8
NI
NI
NI
NI
ND
Verification Sample >
9-Jun-16
EPA 8260
0.62
1
-
-
-
ND
NI
NI
NI
NI
ND
NC2L = 0.03 pg/1 (02/01/15)
13-Dec-16
EPA 8260
0.62
1
ND
ND
ND
ND
NI
NI
NI
NI
-
27-Jun-17
EPA 8260
0.62
1
ND
ND
ND
1.9
NI
NI
NI
NI
ND
Verification Sample >
8-Aug-17
EPA 8260
0.62
1
-
-
-
ND
NI
NI
NI
NI
ND
13-Dec-17
EPA 8260
0.62
1
ND
ND
ND
3.6
NI
NI
NI
NI
ND
16-May-18
EPA 8260
0.62
1
ND
ND
AB
3.1
ND
ND
ND
ND
-
6-Dec-18
EPA 8260
0.62
1
ND
ND
AB
4.3
ND
ND
ND
ND
ND
8-May-19
EPA826OD
0.6
1
ND
ND
AB
4.8
ND
ND
ND
ND
ND
8-Nov-19
EPA826OD
0.24
1
ND
ND
AB
1.4
ND
NS
ND
ND
ND
8-May-20
EPA826OD
0.24
1
ND
ND
AB
0.85 J
ND
INS
ND
ND
ND
11-Nov-20
EPA826OD
0.24
1
ND
-
-
1.1
-
-
-
-
ND
28-Jan-21
EPA826OD
0.24
1
-
ND
-
-
ND
-
ND
-
ND
Xylene(Total)
10-Apr-14
EPA 8260
0.66
5
ND
-
ND
16.9
NI
NI
NI
NI
ND
NC2L = 500 pg/I (01/01/10)
6-May-14
EPA 8260
0.66
5
ND
--
ND
19.3
NI
NI
NI
NI
ND
20-Jun-14
EPA 8260
0.66
5
ND
-
ND
2.5 J
NI
NI
NI
NI
ND
17-Jul-14
EPA 8260
0.66
5
ND
--
ND
8.8
NI
NI
NI
NI
ND
23-Oct-14
EPA 8260
0.66
5
ND
ND
ND
18.7
NI
NI
NI
NI
ND
21-May-15
EPA 8260
0.66
5
ND
ND
ND
17.1
NI
NI
NI
NI
ND
8-Dec-15
EPA 8260
0.66
5
ND
ND
ND
1.6 J
NI
NI
NI
NI
ND
4-May-16
EPA 8260
0.66
5
ND
ND
ND
11.5
NI
NI
NI
NI
ND
13-Dec-16
EPA 8260
0.66
5
ND
ND
ND
ND
NI
NI
NI
NI
-
27-Jun-17
EPA 8260
0.66
5
ND
ND
ND
ND
NI
NI
NI
NI
ND
13-Dec-17
EPA 8260
0.66
5
ND
ND
ND
13.1
NI
NI
NI
NI
ND
16-May-18
EPA 8260
0.66
5
ND
ND
AB
9.8
ND
ND
ND
ND
-
6-Dec-18
EPA 8260
0.66
1
ND
ND
AB
14.7
ND
ND
ND
ND
ND
8-May-19
EPA826OD
1.5
2
ND
ND
AB
22.8
ND
ND
ND
ND
ND
8-Nov-19
EPA826OD
0.63
1
ND
ND
AB
ND
ND
NS
ND
ND
ND
8-May-20
EPA826OD
0.63
1
ND
ND
AB
ND
ND
INS
ND
ND
ND
11-Nov-20
EPA826OD
0.63
1
ND
-
-
0.78 J
-
-
-
-
ND
28-Jan-21
EPA826OD
0.63
1
-
ND
-
-
ND
-
ND
-
ND
Carbon dioxide
11-Nov-20
j RSK-175
j 2540
18000
j
j 154000
-
-
-
-
-
Notes:
All concentrations in micrograms per liter (pg/1) = parts per billion.
RL = Reporting Limit (SWSL).
DL = Laboratory Detection Limit.
-- = Not sampled for this parameter or Not reported.
ND = Not Detected at or above the DL.
J = Estimated value - concentration is less than the RL but greater than the DL.
B = Blank -Qualified (Similar concentrations detected in field, trip, or method blanks).
NC2L = Groundwater Standard from 15A NCAC 2L.O2O2.
GWPS = Groundwater Protection Standard set by NC-DEQSWS for constituents with no listed NC2L standard (no longer used).
IMAC = NC Interim Maximum Allowable Concentration for constituents with no listed NC2L standard.
Values above the NC2L Standard, IMAC, or GWPS are bold.
Burke County -- Johns River CDLF LaBella Associates
Expansion, Permit No. 12-03 Page 6 of 6

TABLE A2-4: Historically Detected Constituents in Additional Wells/Piezometers
Analyte
Sample Collection
EPA
DL
RL
MW-36
MW-15S
PZ-12
PZ-13
PZ-30S
PZ-31
PZ-34
PZ-37
Blanks
Date
Method
Inorganics
Barium
11-Nov-20
EPA 6010D
3.50
5
100
---
---
---
---
---
---
---
---
NC21- = 700 pg/I (01/01/10)
Cobalt
11-Nov-20
EPA 6010D
3.60
5
45.7
---
---
---
---
---
---
---
---
BKGD = 11.3 pg/I
Nickel
11-Nov-20
EPA 6010D
3.50
5
5.8
---
---
---
---
---
---
---
---
NC21L = 100 pg/I (10/23/07)
Thallium
11-Nov-20
EPA 6020B
0.05
0.1
0.052 J
---
---
---
---
---
---
---
---
IMAC = 0.2 pg/I
Organics
Acetone
18-Feb-13
10.00
100
19.8 J
---
---
---
ND
---
---
ND
ND
18-J u I-13
10.00
100
---
---
---
---
---
ND
ND
---
15.80 J
NC 2L = 6,000 pg/I (01/01/10)
6-May-14
EPA 8260
10.00
100
---
---
---
---
---
---
nle
---
ND
22-Oct-14
EPA 8261
10.00
100
---
---
---
---
---
---
nle
---
ND
21-May-15
EPA 8262
10.00
100
---
---
---
---
---
---
nle
---
ND
9-Dec-15
EPA 8262
10.00
100
---
---
---
---
---
---
nle
---
ND
16-May-18
10.00
100
---
---
---
---
---
ND
8-Nov-19
EPA 8260D
6.20
25
---
---
---
---
---
---
---
8-May-20
EPA 8260D
6.20
25
---
---
---
---
---
---
---
---
ND
11-Nov-20
EPA 8260D
6.20
25
ND
---
---
---
ND
---
---
---
---
Benzene
18-Feb-13
0.25
1.0
8.0
---
---
---
ND
---
---
ND
ND
18-J u I-13
0.25
1.0
---
---
---
---
---
7.6
ND
---
ND
NC 2L = 1 pg/I (10/23/07)
6-May-14
0.25
1.0
8.7
4.6
---
ND
ND
ND
nle
ND
ND
22-Oct-14
EPA 8260
0.25
1.0
8.3
3.3
ND
---
ND
ND
nle
---
ND
21-May-15
EPA 8260
0.25
1.0
5.8
2.0
ND
---
ND
ND
nle
ND
9-Dec-15
EPA 8260
0.25
1.0
5.8
1.2
ND
---
ND
ND
---
---
ND
4-May-16
EPA 8260
0.25
1.0
6.7
1.3
ND
---
ND
ND
---
---
ND
14-Dec-16
EPA 8260
0.25
1.0
5.5
0.85 J
ND
---
ND
ND
---
---
ND
28-Jun-17
EPA 8260
0.25
1.0
5.3
0.43 J
ND
---
ND
ND
---
---
ND
15-Dec-17
0.25
1.0
5.3
0.57 J
ND
---
ND
ND
---
---
ND
16-May-18
EPA 8260
0.25
1.0
5.9
---
---
---
---
---
---
---
---
* Resample >
4-Jun-18
EPA 8260
0.25
1.0
-
0.51 J
ND
---
ND
ND
---
---
---
6-Dec-18
EPA 8260B
0.25
1.0
5.0
ND
ND
---
ND
ND
---
---
---
8-May-19
EPA 8260D
0.20
1.0
6.8
0.59 J
ND
---
ND
ND
---
---
ND
8-Nov-19
EPA 8260D
0.15
1.0
4.0
0.43 J
ND
---
ND
ND
---
---
---
8-May-20
EPA 8260D
0.15
1.0
4.0
0.39 J
ND
---
ND
ND
---
---
ND
11-Nov-20
EPA 8260D
0.15
1.0
4.0
ND
ND
---
ND
ND
---
---
---
Burke County -- Johns River CDLF LaBella Associates
Expansion, Permit No. 12-03 Page 1 of 8

TABLE A2-4: Historically Detected Constituents in Additional Wells/Piezometers
Analyte
Sample Collection
EPA
DL
RL
MW-36
MW-15S
PZ-12
PZ-13
PZ-30S
PZ-31
PZ-34
PZ-37
Blanks
Date
Method
Chlorobenzene
18-Feb-13
EPA 8257
0.23
3.0
0.760 J
---
---
---
ND
---
---
ND
ND
18-J u I-13
EPA 8258
0.23
3.0
---
---
---
---
---
0.480 J
ND
---
ND
NC 2L = 50 pg/I (10/23/07)
6-May-14
EPA 8259
0.23
3.0
---
---
---
---
---
---
nle
---
ND
22-Oct-14
EPA 8260
0.23
3.0
---
---
---
---
---
---
nle
---
ND
21-May-15
EPA 8261
0.23
3.0
---
---
---
---
---
---
nle
---
ND
9-Dec-15
EPA 8261
0.23
3.0
---
---
---
---
---
---
nle
---
ND
16-May-18
0.23
3.0
---
---
---
---
---
ND
8-Nov-19
EPA 8260D
0.23
1.0
---
---
---
---
---
---
---
---
---
8-May-20
EPA 8260D
0.23
1.0
---
---
---
---
---
---
---
---
ND
11-Nov-20
EPA 8260D
0.23
1.0
0.80 J
---
---
---
ND
---
---
---
---
Chloroethane
18-Feb-13
EPA 8257
0.54
10.0
1.10 J
---
---
---
ND
---
---
ND
ND
18-J u I-13
EPA 8258
0.54
10.0
---
---
---
---
---
ND
ND
---
ND
NC 2L = 3,000 pg/I (01/01/10)
6-May-14
EPA 8259
0.54
10.0
---
---
---
---
---
---
We
---
ND
22-Oct-14
EPA 8260
0.54
10.0
---
---
---
---
---
---
nle
---
ND
21-May-15
EPA 8261
0.54
10.0
---
---
---
---
---
---
nle
---
ND
9-Dec-15
EPA 8261
0.54
10.0
---
---
---
---
---
---
nle
---
ND
16-May-18
10.00
100
---
---
---
---
---
ND
8-Nov-19
EPA 8260D
0.49
1
---
---
---
---
---
---
---
---
---
8-May-20
EPA 8260D
0.49
1
---
---
---
---
---
---
---
---
ND
11-Nov-20
EPA 8260D
0.49
1
ND
---
---
---
ND
---
---
---
---
1,2-Dichlorobenzene
18-Feb-13
0.30
5.0
0.44 J
---
---
---
ND
---
---
ND
ND
18-J u I-13
0.30
5.0
---
---
---
---
---
0.61 J
ND
---
ND
NC 2L = 20 pg/I (01/01/10)
6-May-14
EPA 8260
0.30
5.0
---
---
---
---
---
---
We
---
ND
22-Oct-14
EPA 8261
0.30
5.0
---
---
---
---
---
---
nle
---
ND
21-May-15
EPA 8262
0.30
5.0
---
---
---
---
---
---
We
---
ND
9-Dec-15
EPA 8261
0.30
5.0
---
---
---
---
---
---
nle
---
ND
16-May-18
0.30
5
---
---
---
---
---
ND
8-Nov-19
EPA 8260D
0.29
1
---
---
---
---
---
---
---
---
---
8-May-20
EPA 8260D
0.29
1
---
---
---
---
---
---
---
---
ND
11-Nov-20
EPA 8260D
0.29
1
0.50 J
---
---
---
ND
---
---
---
---
Burke County -- Johns River CDLF LaBella Associates
Expansion, Permit No. 12-03 Page 2 of 8

TABLE A2-4: Historically Detected Constituents in Additional Wells/Piezometers
Analyte
Sample Collection
Date
EPA
Method
DL
RL
MW-36
MW-15S
PZ-12
PZ-13
PZ-30S
PZ-31
PZ-34
PZ-37
Blanks
1,4-Dichlorobenzene
18-Feb-13
0.33
1.0
18.0
---
---
---
ND
---
---
ND
ND
18-J u I-13
0.33
1.0
---
---
---
---
---
6.5
ND
---
ND
NC 2L = 6 pg/I (01/01/10)
6-May-14
0.33
1.0
10.0
2.3
---
ND
ND
ND
nle
ND
ND
22-Oct-14
EPA 8260
0.33
1.0
15.2
1.6
ND
---
ND
ND
nle
---
ND
21-May-15
EPA 8260
0.33
1.0
18.7
1.4
ND
---
ND
ND
---
ND
9-Dec-15
EPA 8260
0.33
1.0
19.6
1.0
ND
---
ND
ND
---
---
ND
4-May-16
EPA 8260
0.33
1.0
16.5
0.9 J
ND
---
ND
ND
---
---
---
14-Dec-16
EPA 8260
0.33
1.0
15.8
0.7 J
ND
---
ND
ND
---
---
ND
28-Jun-17
EPA 8260
0.33
1.0
20.1
ND
ND
---
ND
ND
---
---
ND
15-Dec-17
0.33
1.0
19.6
0.71 J
ND
---
ND
ND
---
---
ND
16-May-18
EPA 8260
0.33
1.0
19.1
---
---
---
---
---
---
---
---
* Resample >
4-Jun-18
EPA 8260
0.33
1.0
-
0.51 J
ND
---
ND
ND
---
---
---
6-Dec-18
EPA 8260B
0.33
1.0
17.2
ND
ND
---
ND
ND
---
---
---
8-May-19
EPA 8260D
0.58
1.0
19.2
0.74 J
ND
---
ND
ND
---
---
ND
8-Nov-19
EPA 8260D
0.26
1.0
15.4
0.50 J
ND
---
ND
ND
---
---
---
8-May-20
EPA 8260D
0.26
1.0
15.4
0.58 J
ND
---
ND
ND
---
---
ND
11-Nov-20
EPA 8260D
0.26
1.0
15.2
0.70 J
ND
---
ND
ND
---
---
---
1,1-Dichloroethane
18-Feb-13
0.32
5.0
7.9
---
---
---
ND
---
---
ND
ND
18-J u I-13
0.32
5.0
---
---
---
---
---
11.3
ND
---
ND
NC 2L = 6 pg/I (01/01/10)
6-May-14
0.32
5.0
11.6
7.1
---
ND
ND
ND
nle
ND
ND
22-Oct-14
EPA 8260
0.32
5.0
9.0
4.9 J
ND
---
ND
ND
nle
---
ND
21-May-15
EPA 8260
0.32
5.0
4.8 J
2.4 J
ND
---
ND
ND
---
ND
9-Dec-15
EPA 8260
0.32
5.0
5.9
2.2 J
ND
---
ND
ND
---
---
ND
4-May-16
EPA 8260
0.32
5.0
5.9
1.5 J
ND
---
ND
ND
---
---
---
14-Dec-16
EPA 8260
0.32
5.0
4.4 J
0.85 J
ND
---
ND
ND
---
---
ND
28-Jun-17
EPA 8260
0.32
5.0
4.3 J
0.59 J
ND
---
ND
ND
---
---
ND
15-Dec-17
0.32
5.0
3.1 J
0.58 J
ND
---
ND
ND
---
---
ND
16-May-18
EPA 8260
0.32
5.0
3.8 J
---
---
---
---
---
---
---
---
* Resample >
4-Jun-18
EPA 8260
0.32
5.0
---
0.36 J
ND
---
ND
ND
---
---
---
6-Dec-18
EPA 8260B
0.32
1.0
3.6
ND
ND
---
ND
ND
---
---
---
8-May-19
EPA 8260D
0.41
1.0
4.6
ND
ND
---
ND
ND
---
---
ND
8-Nov-19
EPA 8260D
0.27
1.0
3.1
ND
ND
---
ND
ND
---
---
---
8-May-20
EPA 8260D
0.27
1.0
2.7
ND
ND
---
ND
ND
---
---
ND
11-Nov-20
EPA 8260D
0.27
1.0
2.5
ND
ND
---
ND
ND
---
---
---
Burke County -- Johns River CDLF LaBella Associates
Expansion, Permit No. 12-03 Page 3 of 8

TABLE A2-4: Historically Detected Constituents in Additional Wells/Piezometers
Analyte
Sample Collection
EPA
DL
RL
MW-36
MW-15S
PZ-12
PZ-13
PZ-30S
PZ-31
PZ-34
PZ-37
Blanks
Date
Method
1,2-Dichloroethane
18-Feb-13
0.12
1.0
1.0
---
---
---
ND
---
---
ND
ND
18-J u I-13
0.12
1.0
---
---
---
---
---
0.54 J
ND
---
ND
NC 2L = 0.4 pg/I (01/01/10)
6-May-14
0.12
1.0
0.78 J
ND
---
ND
ND
ND
nle
ND
ND
22-Oct-14
EPA 8260
0.12
1.0
0.92 J
ND
ND
---
ND
ND
We
---
ND
21-May-15
EPA 8260
0.12
1.0
ND
ND
ND
---
ND
ND
---
ND
9-Dec-15
EPA 8260
0.24
1.0
0.66 J
ND
ND
---
ND
ND
---
---
ND
4-May-16
EPA 8260
0.24
1.0
0.92 J
ND
ND
---
ND
ND
---
---
---
14-Dec-16
EPA 8260
0.24
1.0
0.77 J
ND
ND
---
ND
ND
---
---
ND
28-Jun-17
EPA 8260
0.24
1.0
0.75 J
ND
ND
---
ND
ND
---
---
ND
15-Dec-17
0.24
1.0
ND
ND
ND
---
ND
ND
---
---
ND
16-May-18
EPA 8260
0.24
1.0
0.73 J
---
---
---
---
---
---
---
---
* Resample >
4-Jun-18
EPA 8260
0.24
1.0
---
ND
ND
---
ND
ND
---
---
---
6-Dec-18
EPA 8260B
0.24
1.0
ND
ND
ND
---
ND
ND
---
---
---
8-May-19
EPA 8260D
0.67
1.0
ND
ND
ND
---
ND
ND
---
---
ND
8-Nov-19
EPA 8260D
0.34
1.0
0.65 J
ND
ND
---
ND
ND
---
---
---
8-May-20
EPA 8260D
0.34
1.0
0.58 J
ND
ND
---
ND
ND
---
---
ND
11-Nov-20
EPA 8260D
0.34
1.0
0.63 J
ND
ND
---
ND
ND
---
---
---
cis-1,2-Dichloroethylene
18-Feb-13
0.19
5.0
21.0
---
---
---
ND
---
---
ND
ND
18-J u I-13
0.19
5.0
---
---
---
---
---
19.3
ND
---
ND
NC 2L = 70 pg/I (10/23/07)
6-May-14
0.19
5.0
---
---
---
---
---
---
nle
---
ND
22-Oct-14
0.19
5.0
---
---
---
---
---
---
n I e
---
ND
21-May-15
0.19
5.0
---
---
---
---
---
---
nle
---
ND
9-Dec-15
EPA 8261
0.19
5.0
---
---
---
---
---
---
nle
---
ND
16-May-18
0.19
5.0
---
---
---
---
---
ND
cis-1,2-Dichloroethene
11-Nov-20
EPA 8260D
0.29
1.0
12.7
---
---
---
ND
---
---
---
---
Ethylbenzene
18-Feb-13
0.30
1.0
23.2
---
---
---
ND
---
---
ND
ND
18-J u I-13
0.30
1.0
---
---
---
---
---
0.94 J
ND
---
ND
NC 2L = 600 pg/I (01/01/10)
6-May-14
0.30
1.0
---
---
---
---
---
---
nle
---
ND
22-Oct-14
0.30
1.0
---
---
---
---
---
---
nle
---
ND
21-May-15
0.30
1.0
---
---
---
---
---
---
nle
---
ND
9-Dec-15
0.30
1.0
---
---
---
---
---
---
nle
---
ND
16-May-18
0.30
1.0
---
---
---
---
---
ND
8-Nov-19
EPA 8260D
0.26
1.0
---
---
---
---
---
---
---
---
---
8-May-20
EPA 8260D
0.26
1.0
---
---
---
---
---
---
---
---
ND
11-Nov-20
EPA 8260D
0.26
1.0
0.69 J
---
---
--
ND
---
---
--
--
Burke County -- Johns River CDLF LaBella Associates
Expansion, Permit No. 12-03 Page 4 of 8

TABLE A2-4: Historically Detected Constituents in Additional Wells/Piezometers
Analyte
Sample Collection
Date
EPA
Method
DL
RL
MW-36
MW-15S
PZ-12
PZ-13
PZ-30S
PZ-31
PZ-34
PZ-37
Blanks
Methylene Chloride
18-Feb-13
0.97
1.0
17.9
---
---
---
ND
---
---
ND
ND
18-J u I-13
0.97
1.0
NS
---
---
---
---
16.4
ND
---
ND
NC 2L = 5 pg/I (01/01/10)
6-May-14
0.97
1.0
24.1
16.7
---
ND
ND
ND
nle
ND
2.20
22-Oct-14
EPA 8260
0.97
1.0
15.7
1.6
ND
---
ND
ND
nle
---
ND
21-May-15
EPA 8260
0.97
1.0
9.5 B
4.4 B
ND
---
ND
ND
---
1.70
9-Dec-15
EPA 8260
0.97
1.0
11.2 B
2.6 B
ND
---
ND
ND
---
---
2.0
4-May-16
EPA 8260
0.97
1.0
3.1
2.0
ND
---
ND
ND
---
---
---
14-Dec-16
EPA 8260
0.97
1.0
ND
ND
ND
---
ND
ND
---
---
ND
28-Jun-17
EPA 8260
0.97
1.0
ND
ND
ND
---
ND
ND
---
---
ND
15-Dec-17
0.97
1.0
ND
ND
ND
---
ND
ND
---
---
ND
16-May-18
EPA 8260
0.97
1.0
ND U
---
---
---
---
---
---
---
---
* Resample >
4-Jun-18
EPA 8260
0.97
1.0
---
ND
ND
---
ND
ND
---
---
---
6-Dec-18
EPA 8260B
0.97
1.0
ND
ND
ND
---
ND
ND
---
---
---
8-May-19
EPA 8260D
0.50
1.0
2.1
0.8 J
ND
---
ND
ND
---
---
ND
8-Nov-19
EPA 8260D
3.70
5.0
ND
ND
ND
---
ND
ND
---
---
---
8-May-20
EPA 8260D
3.70
5.0
ND
ND
ND
---
ND
ND
---
---
ND
11-Nov-20
EPA 8260D
3.70
5.0
ND
ND
ND
---
ND
ND
---
---
---
Tetrachloroethene
18-Feb-13
0.46
1.0
5.5
---
---
---
ND
---
---
ND
ND
18-Jul-13
0.46
1.0
N S
---
---
---
---
7.8
ND
---
ND
NC 2L = 0.7 pg/I (10/23/07)
6-May-14
0.46
1.0
7.9
6.9
---
ND
ND
ND
nle
ND
ND
22-Oct-14
EPA 8260
0.46
1.0
7.3
5.2
ND
---
ND
ND
nle
---
ND
21-May-15
EPA 8260
0.46
1.0
6.0
3.3
ND
---
ND
ND
---
---
ND
9-Dec-15
EPA 8260
0.46
1.0
5.0
2.1
ND
---
ND
ND
---
---
ND
4-May-16
EPA 8260
0.46
1.0
4.5
2.0
ND
---
ND
ND
---
---
---
14-Dec-16
EPA 8260
0.46
1.0
ND
1.4
ND
---
ND
ND
---
---
ND
28-Jun-17
EPA 8260
0.46
1.0
ND
0.80 J
ND
---
ND
ND
---
---
ND
15-Dec-17
0.46
1.0
16-May-18
EPA 8260
0.46
1.0
3.6
---
---
---
---
---
---
---
---
* Resample >
4-Jun-18
EPA 8260
0.46
1.0
---
0.48 J
ND
---
ND
ND
---
---
---
6-Dec-18
EPA 8260B
0.46
1.0
2.9
ND
ND
---
ND
ND
---
---
---
8-May-19
EPA 8260D
0.78
1.0
4.4
ND
ND
---
ND
ND
---
---
ND
8-Nov-19
EPA 8260D
0.16
1.0
2.0
0.64 J
ND
---
ND
ND
---
---
---
8-May-20
EPA 8260D
0.16
1.0
2.4
0.55 J
ND
---
ND
ND
---
---
ND
11-Nov-20
EPA 8260D
0.16
1.0
2.3
0.70 J
ND
---
ND
ND
---
---
---
Burke County -- Johns River CDLF LaBella Associates
Expansion, Permit No. 12-03 Page 5 of 8

TABLE A2-4: Historically Detected Constituents in Additional Wells/Piezometers
Analyte
Sample Collection
EPA
DL
RL
MW-36
MW-15S
PZ-12
PZ-13
PZ-30S
PZ-31
PZ-34
PZ-37
Blanks
Date
Method
Toluene
18-Feb-13
0.26
1.0
44.10
---
---
---
ND
---
---
ND
ND
18-J u I-13
0.26
1.0
---
---
---
---
---
1.50
N D
---
N D
NC 2L = 600 pg/I (01/01/10)
6-May-14
0.26
1.0
---
---
---
---
---
---
nle
---
ND
22-Oct-14
0.26
1.0
---
---
---
---
---
---
n I e
---
N D
21-May-15
0.26
1.0
---
---
---
---
---
---
nle
---
N D
9-Dec-15
0.26
1.0
---
---
---
---
---
---
n I e
---
N D
16-May-18
0.26
1.0
---
---
---
---
---
ND
8-Nov-19
EPA 8260D
0.24
1.0
---
---
---
---
---
---
---
---
---
8-May-20
EPA 8260D
0.24
1.0
---
---
---
---
---
---
---
---
ND
11-Nov-20
EPA 8260D
0.24
1.0
ND
---
---
---
ND
---
---
---
---
Trichloroethene
18-Feb-13
0.47
1.0
3.6
---
---
---
ND
---
---
ND
ND
18-J u I-13
0.47
1.0
---
---
---
---
---
5.8
N D
---
N D
NC 2L = 3 pg/I (01/01/10)
6-May-14
0.47
1.0
6.0
4.3
---
ND
ND
ND
nle
ND
ND
22-Oct-14
EPA 8260
0.47
1.0
5.1
3.4
ND
---
ND
ND
nle
---
ND
21-May-15
EPA 8260
0.47
1.0
3.5
2.1
ND
---
ND
ND
---
ND
9-Dec-15
EPA 8260
0.47
1.0
2.9
1.1
ND
---
ND
ND
---
---
ND
4-May-16
EPA 8260
0.47
1.0
3.1
---
ND
---
ND
ND
---
---
---
14-Dec-16
EPA 8260
0.47
1.0
ND
0.81 J
ND
---
ND
ND
---
---
ND
28-Jun-17
EPA 8260
0.47
1.0
ND
ND
ND
---
ND
ND
---
---
ND
15-Dec-17
0.47
1.0
ND
ND
ND
---
ND
ND
---
---
ND
16-May-18
EPA 8260
0.47
1.0
3.1
---
---
---
---
---
---
---
---
* Resample >
4-Jun-18
EPA 8260
0.47
1.0
---
ND
ND
---
ND
ND
---
---
---
6-Dec-18
EPA 8260B
0.47
1.0
2.2
ND
ND
---
ND
ND
---
---
---
8-May-19
EPA 8260D
0.34
1.0
4.1
ND
ND
---
ND
ND
---
---
ND
8-Nov-19
EPA 8260D
0.22
1.0
1.6
ND
ND
---
ND
ND
---
---
---
8-May-20
EPA 8260D
0.22
1.0
1.9
ND
ND
---
ND
ND
---
---
ND
11-Nov-20
EPA 8260D
0.22
1.0
1.7
ND
ND
---
ND
ND
---
---
---
Trichlorofluoromethane
18-Feb-13
0.20
1.0
0.650 J
---
---
---
ND
---
---
ND
ND
18-J u I-13
0.20
1.0
---
---
---
---
---
0.890 J
N D
---
N D
NC 2L = 2,000 pg/I (01/01/10)
6-May-14
0.20
1.0
---
---
---
---
---
---
nle
---
ND
22-Oct-14
0.20
1.0
---
---
---
---
---
---
nle
---
N D
21-May-15
0.20
1.0
---
---
---
---
---
---
nle
---
N D
9-Dec-15
0.20
1.0
---
---
---
---
---
---
nle
---
N D
16-May-18
0.20
1.0
---
---
---
---
---
N D
8-Nov-19
EPA 8260D
0.31
1.0
---
---
---
---
---
---
---
---
---
8-May-20
EPA 8260D
0.31
1.0
---
---
---
---
---
---
---
---
N D
11-Nov-20
EPA 8260D
0.31
1.0
ND
---
---
---
ND
---
---
---
---
Burke County -- Johns River CDLF LaBella Associates
Expansion, Permit No. 12-03 Page 6 of 8

TABLE A2-4: Historically Detected Constituents in Additional Wells/Piezometers
Analyte
Sample Collection
EPA
DL
RL
MW-36
MW-15S
PZ-12
PZ-13
PZ-30S
PZ-31
PZ-34
PZ-37
Blanks
Date
Method
Vinyl chloride
18-Feb-13
0.62
1.0
1.2
---
---
---
ND
---
---
ND
ND
18-Jul-13
0.62
1.0
---
---
---
---
---
N D
N D
---
N D
NC 2L = 0.03 pg/I (01/01/10)
6-May-14
0.62
1.0
1.1
ND
---
ND
ND
ND
nle
ND
ND
22-Oct-14
EPA 8260
0.62
1.0
0.87 J
ND
ND
---
ND
ND
We
---
ND
21-May-15
EPA 8260
0.62
1.0
ND
ND
ND
---
ND
ND
---
ND
9-Dec-15
EPA 8260
0.62
1.0
0.80 J
ND
ND
---
ND
ND
---
---
ND
4-May-16
EPA 8260
0.62
1.0
0.80 J
ND
ND
---
ND
ND
---
---
---
14-Dec-16
EPA 8260
0.62
1.0
ND
ND
ND
---
ND
ND
---
---
ND
28-Jun-17
EPA 8260
0.62
1.0
0.64 J
ND
ND
---
ND
ND
---
---
ND
15-Dec-17
0.62
1.0
N D
N D
N D
---
N D
N D
---
---
N D
16-May-18
EPA 8260
0.62
1.0
0.66 J
---
---
---
---
---
---
---
---
* Resample >
4-Jun-18
EPA 8260
0.62
1.0
---
N D
N D
---
N D
N D
---
---
---
6-Dec-18
EPA 8260B
0.62
1.0
ND
ND
ND
---
ND
ND
---
---
---
8-May-19
EPA 8260D
0.60
1.0
ND
ND
ND
---
ND
ND
---
---
ND
8-Nov-19
EPA 8260D
0.24
1.0
ND
ND
ND
---
ND
ND
---
---
---
8-May-20
EPA 8260D
0.24
1.0
0.56 J
ND
ND
---
ND
ND
---
---
ND
11-Nov-20
EPA 8260D
0.24
1.0
ND
ND
ND
---
ND
ND
---
---
---
Xylene (Total)
18-Feb-13
0.66
2.0
295
---
---
---
ND
---
---
ND
ND
18-J u I-13
0.66
2.0
---
---
---
---
---
92.5
N D
---
N D
NC 2L = 500 pg/I (01/01/10)
6-May-14
0.66
2.0
---
---
---
---
---
---
nle
---
ND
22-Oct-14
0.66
2.0
---
---
---
---
---
---
nle
---
ND
21-May-15
EPA 8260
0.66
2.0
---
ND
ND
---
ND
ND
---
ND
9-Dec-15
EPA 8260
0.66
2.0
---
ND
ND
---
ND
ND
---
ND
16-May-18
0.66
2
---
---
---
---
---
ND
8-Nov-19
EPA 8260D
0.63
1
---
---
---
---
---
---
---
---
---
8-May-20
EPA 8260D
0.63
1
---
---
---
---
---
---
---
---
ND
11-Nov-20
EPA 8260D
0.63
1
10.80
---
---
---
ND
---
---
---
---
Carbon Dioxide
14-Dec-16
AM20GAX
450.0
5,000
510,000
350,000
35,000
---
22,000
14,000
---
---
---
(Dissolved Carbon Dioxide)
28-Jun-17
450.0
5,000
420,000
250,000
36,000
23,000
14,000
---
11-Nov-20
RSK-175
2540.0
18,000
208,000
121,000
19,100
---
36,200
10,700
---
---
-
--I I
Burke County -- Johns River CDLF LaBella Associates
Expansion, Permit No. 12-03 Page 7 of 8

TABLE A2-4: Historically Detected Constituents in Additional Wells/Piezometers
Analyte
Sample Collection
Date
EPA
Method
DL
RL
MW-36
MW-15S
PZ-12
PZ-13
PZ-30S
PZ-31
PZ-34
PZ-37
Blanks
Methane
18-Feb-13
0.7
2.0
---
---
---
---
---
---
---
---
---
(Dissolved Methane)
18-Jul-13
0.7
2.0
---
---
---
---
---
---
---
---
---
6-May-14
0.7
2.0
348
9,940
---
4.5 J
ND
ND
nle
ND
---
22-Oct-14
RSK 175
3.3
6.6
8,450
13,000
ND
---
ND
ND
nle
---
ND
21-May-15
RSK 175
0.6
10.0
173
4,680
2.0 J
---
1.5 J
1.7 J
---
---
9-Dec-15
RSK 175
0.6
10.0
3,780
8,550
3.0 J
---
2.5 J
4.8 J
---
---
---
4-May-16
RSK 175
0.5
10.0
8,920
7,860
1.6 J
---
1.6 J
1.8 J
---
---
---
14-Dec-16
RSK 175
200
200
32,200
16,700
ND
---
ND
27.0 J
---
---
---
28-Jun-17
RSK 175
10
10
45,400
25,900
ND
---
ND
ND
---
---
---
15-Dec-17
10
10
17,100
25,700
ND
ND
48.4
---
16-May-18
RSK 175
10
10
29,100
18,000
ND U
---
ND U
ND U
---
---
---
6-Dec-18
RSK 175
10
10
27,800
18,100
ND
---
45.7
17.4
---
---
---
8-May-19
RSK 175
3
10
---
19,500
12.1
---
908
15.1
---
---
---
8-Nov-19
RSK 175
3
10
8,820
16,800
ND
---
1,510
ND
---
---
---
8-May-20
RSK 175
3
10
13,800
18,300
ND
---
ND
ND
---
---
---
11-Nov-20
RSK 175
3
10
14,200
14,500
ND
---
186 J
ND
---
---
---
Notes:
All concentrations in micrograms per liter (pg/1) = parts per billion.
DL = Laboratory Detection Limit.
RL = SWSL = Solid Waste Section Reporting Limit.
NC 2L = Groundwater Standard from 15A NCAC 2L.0202.
nle = No longer exists (MW-34 was accidentaly destroyed during construciton activties).
--- = Not reported or not monitored
kyumm% m . a - i - wini sivocia
ND = Not Detected above the DL.
J = Estimated value - Concentration is less than the SWSL but greater than the DL.
B = Blank -Qualified (Similar concentration detected in field, trip, or method blank).
Values above the NC 2L Standard are bold
Italics = Constituent of Concern (COC).
*Resampling event due to laboratory error.
Burke County -- Johns River CDLF LaBella Associates
Expansion, Permit No. 12-03 Page 8 of 8

TABLE A2-5: Historically Detected Surface Water Constituents
Sample
EPA
Analyte Collection Date
Method
DL
RL SMP-5 SMP-6 SMP-7
Blanks
Inorganics
Antimony
6-Nov-08
2.6
6.0
ND 8.4 -
ND
3-Jun-09
2.6
6.0
ND ND -
ND
18-Nov-09
2.6
6.0
ND ND -
ND
NC 2B = NE (05/01/07)
15-Jun-10
2.6
6.0
ND ND -
ND
1-Dec-10
2.6
6.0
ND ND -
ND
1-Jun-11
2.6
6.0
ND ND -
ND
20-Dec-11
5.0
6.0
ND ND -
ND
30-May-12
5.0
6.0
ND ND -
ND
5-Dec-12
5.0
6.0
ND ND -
ND
12-Jun-13
5.0
6.0
ND ND -
ND
28-Oct-13
5.0
6.0
ND ND -
ND
6-May-14
EPA 6010
5.0
6.0
ND ND -
ND
22-Oct-14
EPA 6010
5.0
6.0
- ND ND
ND
21-May-15
EPA 6010
3.8
6.0
ND ND ND
ND
9-Dec-15
EPA 6010
3.8
6.0
ND ND ND
ND
NC 2B = 5.6 pg/I (03/01/16)
4-May-16
EPA 6010
3.8
6.0
ND ND ND
ND
14-Dec-16
EPA 6010
3.8
6.0
ND ND ND
ND
28-Jun-17
EPA 6010
3.9
6.0
ND ND ND
13-Dec-17
3.9
6.0
ND ND ND
ND
16-May-18
EPA 6010
3.9
6.0
ND ND ND
--
6-Dec-18
3.9
5.0
ND ND ND
ND
8-May-19
EPA 6010D
3.9
5.0
ND ND ND
-
8-Nov-19
EPA 6010D
3.0
5.0
ND ND ND
-
8-May-20
EPA 6010D
3.0
5.0
ND ND ND
ND
11-Nov-20
EPA 6010D
3.0
5.0
ND ND ND
-
Arsenic
6-Nov-08
2.7
10.0
2.9 B 4.5 B -
4.1 J
3-Jun-09
2.7
10.0
ND 4.5 J -
ND
18-Nov-09
2.7
10.0
ND ND -
ND
NC 2B = 10 pg/I (05/01/07)
15-Jun-10
2.7
10.0
ND ND -
ND
1-Dec-10
2.7
10.0
ND ND -
ND
1-Jun-11
2.7
10.0
ND ND -
ND
20-Dec-11
5.0
10.0
ND ND -
ND
30-May-12
5.0
10.0
ND ND -
ND
5-Dec-12
5.0
10.0
ND ND -
ND
12-Jun-13
5.0
10.0
ND ND -
ND
28-Oct-13
5.0
10.0
ND ND -
ND
6-May-14
EPA 6010
5.0
10.0
ND ND -
ND
22-Oct-14
EPA 6010
5.0
10.0
- ND ND
ND
21-May-15
EPA 6010
2.5
10.0
ND ND ND
ND
9-Dec-15
EPA 6010
2.5
10.0
ND ND ND
ND
NC 2B = 10 pg/I (03/01/16)
4-May-16
EPA 6010
2.5
10.0
3.0 J ND 3.3 J
ND
14-Dec-16
EPA 6010
2.5
10.0
ND ND ND
ND
28-Jun-17
EPA 6010
5.0
10.0
ND 5.5 J ND
-
13-Dec-17
5.0
10.0
ND ND ND
ND
16-May-18
EPA 6010
5.0
10.0
ND ND ND
--
6-Dec-18
5.0
10.0
ND ND ND
ND
8-May-19
EPA 6010D
5.0
10.0
ND ND ND
--
8-Nov-19
EPA 6010D
4.7
10.0
ND ND ND
-
8-May-20
EPA 6010D
4.7
10.0
ND ND ND
ND
11-Nov-20
EPA 6010D
4.7
10.0
ND ND ND
-
Burke County Johns River C+D Expansion Landfill La Bella Associates
Permit 12-03 Page 1 of 11

TABLE A2-5: Historically Detected Surface Water Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
SMP-5
SMP-6
SMP-7
Blanks
Barium
30-May-07
-
100
81.3
J 23.8
J -
0.2 J
29-Nov-07
-
100
116
27.5
J
0.50 J
29-May-08
0.2
100
71.9
J 19.6
J -
ND
6-Nov-08
0.20
100
82.5
J 40.2
B -
9.6 J
3-Jun-09
0.20
100
104
36.2
B -
15.9 J
18-Nov-09
0.20
100
49.9
B 15.7
B -
20.1 J
NC 2B = 1,000 pg/I (05/01/07)
15-Jun-10
0.20
100
47.6
J 20.7
J -
0.77 J
1-Dec-10
0.20
100
39.8
J 46.8
J -
ND
1-Jun-11
0.20
100
51.6
J 19.9
J -
ND
20-Dec-11
5.0
100
63.7
J 13.9
J -
ND
30-May-12
5.0
100
16.9
J 22.0
J -
ND
5-Dec-12
5.0
100
69.9
J 24.8
J -
ND
12-Jun-13
5.0
100
54.9
B 40.0
B -
13.6 J
28-Oct-13
5.0
100
35.4
J 20.8
J -
ND
6-May-14
EPA 6010
5.0
100
37.0
J 17.8
J -
ND
22-Oct-14
EPA 6010
5.0
100
-
25.5
J 19.8 J
ND
21-May-15
EPA 6010
2.5
100
53.0
J 14.6
J 21.6 J
ND
9-Dec-15
EPA 6010
2.5
100
26.1
J 23.4
J 27.8 J
ND
NC 2B = 1,000 pg/I (03/01/16)
4-May-16
EPA 6010
2.5
100
41.4
J 37.3
J 51.0 J
ND
14-Dec-16
EPA 6010
2.5
100
44.7
J 21.2
J 17.5 J
ND
28-Jun-17
EPA 6010
2.5
100
46.3
J 41.4
J 31.5 J
--
13-Dec-17
2.5
100
38.7
J 26.3
J 20.7 J
ND
16-May-18
EPA 6010
2.5
100
34.5
J 42.5
J 46.3 J
-
6-Dec-18
2.5
5
32.6
31.1
30.3
9.9
8-May-19
EPA 6010D
2.5
5
31.7
30.0
25.0
-
8-Nov-19
EPA 6010D
1.0
5
25.6
27.1
27.0
--
8-May-20
EPA 6010D
3.5
5
22.8
28.3
27.6
ND
11-Nov-20
EPA 6010D
3.5
5
20.3
38.5
52.5
--
Beryllium
14-Nov-02
--
2
2.0
B 2.2
B -
2.1
14-May-03
---
2
ND
ND
--
ND
20-Nov-03
---
2
ND
ND
--
ND
6-May-04
---
2
ND
ND
--
ND
10-Nov-04
---
2
ND
ND
--
ND
5-May-05
---
2
ND
ND
--
ND
3-Nov-05
---
2
ND
ND
--
ND
25-May-06
---
2
ND
ND
ND
2-Nov-06
---
2
ND
ND
--
ND
30-May-07
-
1
ND
ND
--
ND
29-Nov-07
-
1
ND
ND
-
ND
29-May-08
0.10
1.0
ND
ND
--
ND
6-Nov-08
0.10
1.0
0.24
B 0.37
B -
0.29 J
3-Jun-09
0.10
1.0
0.64
J 0.21
J
ND
18-Nov-09
0.10
1.0
ND
ND
ND
NC 2B = 6.5 pg/I (05/01/07)
15-Jun-10
0.10
1.0
ND
ND
-
ND
1-Dec-10
0.10
1.0
ND
ND
ND
1-Jun-11
0.10
1.0
ND
ND
--
ND
20-Dec-11
1.0
1.0
ND
ND
ND
30-May-12
1.0
1.0
ND
ND
ND
5-Dec-12
1.0
1.0
ND
ND
ND
12-Jun-13
1.0
1.0
ND
ND
--
ND
28-Oct-13
1.0
1.0
ND
ND
ND
6-May-14
EPA 6010
1.0
1.0
ND
ND
ND
22-Oct-14
EPA 6010
1.0
1.0
-
ND
ND
ND
21-May-15
EPA 6010
0.5
1.0
ND
ND
ND
ND
9-Dec-15
EPA 6010
0.5
1.0
ND
ND
ND
ND
NC 2B = 6.5 pg/I Chronic (03/01/16)*
4-May-16
EPA 6010
0.5
1.0
ND
ND
ND
ND
14-Dec-16
EPA 6010
0.5
1.0
ND
ND
ND
ND
28-Jun-17
EPA 6010
0.5
1.0
ND
ND
ND
13-Dec-17
0.5
1.0
ND
ND
ND
ND
16-May-18
EPA 6010
0.5
1.0
ND
ND
ND
--
6-Dec-18
0.5
1.0
ND
ND
ND
ND
8-May-19
EPA 6010D
0.5
1.0
ND
ND
ND
--
8-Nov-19
EPA 6010D
0.2
1.0
ND
ND
0.22 J
-
8-May-20
EPA 6010D
0.7
1.0
ND
ND
ND
ND
11-Nov-20
EPA 6010D
0.7
1.0
ND
ND
ND
-
Burke County Johns River C+D Expansion Landfill La Bella Associates
Permit 12-03 Page 2 of 11

TABLE A2-5: Historically Detected Surface Water Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
SMP-5
SMP-6
SMP-7
Blanks
Cadmium
7-Nov-01
---
1
ND
1.0
--
ND
22-May-02
---
1
ND
1.7
B -
1.3
14-Nov-02
---
1
ND
ND
-
ND
14-May-03
---
1
ND
ND
-
ND
20-Nov-03
---
1
ND
ND
-
ND
6-May-04
---
1
ND
ND
-
ND
IC-Nov-04
---
1
ND
ND
-
ND
5-May-05
---
1
ND
ND
-
ND
3-Nov-05
---
1
ND
ND
-
ND
25-May-06
---
1
ND
ND
-
ND
2-Nov-06
---
1
ND
ND
-
ND
30-May-07
---
1
ND
ND
-
ND
29-Nov-07
---
1
ND
ND
-
ND
29-May-08
0.5
1.0
ND
ND
-
ND
6-Nov-08
0.50
1.0
ND
ND
-
ND
3-Jun-09
0.50
1.0
ND
ND
-
ND
18-Nov-09
0.50
1.0
ND
ND
-
ND
NC 2B = 2 pg/I (05/01/07)
15-Jun-10
0.50
1.0
ND
ND
-
ND
1-Dec-10
0.50
1.0
ND
ND
-
ND
1-Jun-11
0.50
1.0
ND
ND
-
ND
20-Dec-11
1.0
1.0
ND
ND
-
ND
30-May-12
1.0
1.0
ND
ND
-
ND
5-Dec-12
1.0
1.0
ND
ND
-
ND
12-Jun-13
1.0
1.0
ND
ND
-
ND
28-Oct-13
1.0
1.0
ND
ND
-
ND
6-May-14
EPA 6010
1.0
1.0
ND
ND
-
ND
22-Oct-14
EPA 6010
1.0
1.0
-
ND
ND
ND
21-May-15
EPA 6010
0.5
1.0
ND
ND
ND
ND
9-Dec-15
EPA 6010
0.5
1.0
ND
ND
ND
ND
NC 2B = 0.15 pg/I Chronic (03/01/16)*
4-May-16
EPA 6010
0.5
1.0
ND
ND
ND
ND
14-Dec-16
EPA 6010
0.5
1.0
ND
ND
ND
ND
28-Jun-17
EPA 6010
0.5
1.0
ND
ND
ND
--
13-Dec-17
0.5
1.0
ND
ND
ND
ND
16-May-18
EPA 6010
0.5
1.0
ND
ND
ND
--
6-Dec-18
0.5
1.0
ND
ND
ND
ND
8-May-19
EPA 6010D
0.5
1.0
ND
ND
ND
--
8-Nov-19
EPA 6010D
0.4
1.0
ND
ND
ND
--
8-May-20
EPA 6010D
0.4
1.0
ND
ND
ND
ND
11-Nov-20
EPA 6010D
0.4
1.0
ND
ND
ND
-
Chromium
6-Nov-08
0.40
10.0
ND
0.47
J -
ND
3-Jun-09
0.40
10.0
7.5
J 3.2
J -
ND
18-Nov-09
0.40
10.0
ND
ND
-
ND
NC 2B = 50 pg/I (05/01/07)
15-Jun-10
0.40
10.0
1.2
B 0.48
B -
0.74 J
1-Dec-10
0.40
10.0
0.68
B 5.1
J -
0.51 J
1-Jun-11
0.40
10.0
0.59
B 0.59
B -
0.73 J
20-Dec-11
5.0
10.0
ND
ND
-
ND
30-May-12
5.0
10.0
ND
ND
-
ND
5-Dec-12
5.0
10.0
ND
ND
-
ND
12-Jun-13
5.0
10.0
ND
ND
-
ND
28-Oct-13
5.0
10.0
ND
ND
-
ND
6-May-14
EPA 6010
5.0
10.0
ND
ND
-
ND
22-Oct-14
EPA 6010
5.0
10.0
-
ND
9.7 J
ND
21-May-15
EPA 6010
2.5
10.0
ND
ND
ND
ND
9-Dec-15
EPA 6010
2.5
10.0
ND
ND
ND
ND
NC 2B = 11 ug/I Chronic (03/01/16)*
4-May-16
EPA 6010
2.5
10.0
4.7
J 4.6
J 8.8 J
ND
14-Oct-16
2.5
10.0
ND
ND
ND
ND
28-Jun-17
2.5
10.0
ND
ND
ND
ND
NC 2B = 23.81 ug/I Chronic (09/22/17)*
13-Dec-17
2.5
10.0
ND
ND
ND
ND
16-May-18
EPA 6010
2.5
10.0
4.8
J ND
ND
--
6-Dec-18
2.5
5.0
ND
ND
ND
ND
8-May-19
EPA 6010D
2.5
5.0
2.7
J ND
ND
--
8-Nov-19
EPA 6010D
1.0
5.0
1.7
J ND
ND
--
8-May-20
EPA 6010D
3.7
5.0
ND
ND
ND
ND
11-Nov-20
EPA 6010D
3.7
5.0
ND
4.7
J 8.0
--
Burke County Johns River C+D Expansion Landfill La Bella Associates
Permit 12-03 Page 3 of 11

TABLE A2-5: Historically Detected Surface Water Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
SMP-5
SMP-6
SMP-7
Blanks
Cobalt
22-May-02
-
10
14.0
17.0
11.0
14-Nov-02
-
10
ND
ND
--
ND
14-May-03
-
10
ND
10.0
--
ND
20-Nov-03
-
10
14.0
ND
--
ND
6-May-04
-
10
ND
ND
--
ND
10-Nov-04
-
10
10.0
ND
--
ND
5-May-05
-
10
10.0
ND
ND
3-Nov-05
-
10
16.0
No
--
No
25-May-06
-
10
12
ND
--
ND
2-Nov-06
-
10
13.6
No
--
No
30-May-07
-
10
12.3
8.8
J
ND
29-Nov-07
-
10
19.0
2.1
J
ND
29-May-08
0.60
10.0
13.7
ND
ND
6-Nov-08
0.60
10.0
12.6
ND
-
0.65 J
3-Jun-09
0.60
10.0
11.9
B 6.6
B -
7.6 J
18-Nov-09
0.60
10.0
3.6
J 4.6
J --
ND
NC 2B = NE (05/01/07)
15-Jun-10
0.60
10.0
6.4
J 22.3
-
ND
1-Dec-10
0.60
10.0
0.76
J 4.1
J -
ND
1-Jun-11
0.60
10.0
2.0
J 1.7
J
ND
20-Dec-11
5.0
10.0
ND
ND
ND
30-May-12
5.0
10.0
ND
ND
-
ND
5-Dec-12
5.0
10.0
29.0
7.7
J
ND
12-Jun-13
5.0
10.0
ND
9.1
J
ND
28-Oct-13
5.0
10.0
11.5
12.4
No
6-May-14
EPA 6010
5.0
10.0
ND
ND
ND
22-Oct-14
EPA 6010
5.0
10.0
-
ND
ND
ND
21-May-15
EPA 6010
2.5
10.0
6.3
J ND
ND
ND
9-Dec-15
EPA 6010
2.5
10.0
ND
ND
ND
ND
NC 2B = 3 pg/I (03/01/16)
4-May-16
EPA 6010
2.5
10.0
4.0
J 5.6
J 3.3 J
ND
14-Dec-16
EPA 6010
2.5
10.0
5.9
J ND
ND
ND
28-Jun-17
EPA 6010
2.5
10.0
6.4
J 3.6
J ND
NC 2B = NE (09/22/17)
13-Dec-17
2.5
10.0
6.9
J 4.7
J ND
ND
16-May-18
EPA 6010
2.5
10.0
3.8
J ND
ND
6-Dec-18
2.5
5.0
ND
3.4
J ND
ND
8-May-19
EPA6O1OD
2.5
5.0
ND
2.9
J ND
--
8-Nov-19
EPA6O1OD
1.1
5.0
ND
2.7
J 5.6
-
8-May-20
EPA6O1OD
3.6
5.0
ND
ND
ND
ND
11-Nov-20
EPA 6O1OD
3.6
5.0
ND
4.1
J 5.3
--
Copper
29-May-08
0.30
10.0
ND
1.3
B -
0.37 J
6-Nov-08
4.0
10.0
0.45
B 3.4
J -
0.65 J
3-Jun-09
0.30
10.0
6.6
J 2.1
J -
ND
18-Nov-09
0.30
10.0
ND
ND
-
ND
NC 2B = 7 pg/I (05/01/07)
15-Jun-10
0.30
10.0
0.56
B ND
-
0.77 J
1-Dec-10
0.30
10.0
3.6
J 5.9
J -
ND
1-Jun-11
0.30
10.0
1.8
J 0.35
J -
ND
20-Dec-11
5.0
10.0
ND
ND
-
ND
30-May-12
5.0
10.0
ND
ND
-
ND
5-Dec-12
5.0
10.0
ND
ND
ND
12-Jun-13
5.0
10.0
5.2
B ND
9.8 J
28-Oct-13
5.0
10.0
ND
ND
ND
6-May-14
EPA 6010
5.0
10.0
ND
ND
ND
22-Oct-14
EPA 6010
5.0
10.0
-
ND
ND
ND
21-May-15
EPA 6010
2.5
10.0
ND
ND
ND
ND
9-Dec-15
EPA 6010
2.5
10.0
ND
ND
ND
ND
NC 2B = 2.74 pg/I Chronic (3/1/16)*
4-May-16
EPA 6010
2.5
10.0
4.6
J 5.5
J 11
ND
Resample >
17-May-16
EPA 6010
2.5
10.0
-
-
ND
ND
14-Dec-16
EPA 6010
2.5
10.0
ND
ND
ND
ND
28-Jun-17
EPA 6010
2.5
10.0
ND
ND
ND
--
13-Dec-17
2.5
10.0
ND
3.9
J ND
ND
16-May-18
EPA 6010
2.5
10.0
5.4
J ND
ND
6-Dec-18
2.5
5.0
ND
ND
ND
5.8
NC 2B = 3.81 ug/I chronic (SMP-5 5/8/19)
8-May-19
EPA 6O1OD
2.5
5.0
5.4
ND
ND
8-Nov-19
EPA6O1OD
2.1
5.0
4.1
J ND
ND
8-May-20
EPA6O1OD
4.3
5.0
ND
ND
ND
ND
11-Nov-20
EPA 6O1OD
4.3
5.0
ND
5.7
10.6
--
Burke County Johns River C+D Expansion Landfill La Bella Associates
Permit 12-03 Page 4 of 11

TABLE A2-5: Historically Detected Surface Water Constituents
Sample
EPA
Collection Date
Method
DL
RL
SMP-5 SMP-6 SMP-7
Blanks
Cyanide
13-Dec-17
4.0
10.0
7.3 B 6.2 B ND
4.2 J
NC 2B = 5 ug/1 (09/22/17)
16-May-18
SM 4500-CN-
4.0
10.0
ND ND ND
6-Dec-18
4.0
8.0
ND ND ND
ND
8-May-19
SM 4500-CN-
6.0
8.0
ND ND ND
ND
8-Nov-19
SM 4500-CN-
6.0
8.0
ND ND ND
--
8-May-20
SM 4500-CN-
6.0
8.0
ND ND ND
ND
11-Nov-20
SM 4500-CN-
6.0
8.0
ND ND ND
-
Iron
13-Dec-17
25.0
300.0
9520 7860 454
ND
NC 2B = NE (09/22/17)
16-May-18
EPA 6010
25.0
300.0
5350 3240 2190
--
6-Dec-18
25.0
50.0
1980 3240 511
167
8-May-19
EPA 6010D
25.0
50.0
3810 3260 315
-
8-Nov-19
EPA 6010D
19.5
50.0
3400 8840 2920
-
8-May-20
EPA 6010D
41.5
50.0
- - -
ND
11-Nov-20
EPA 6010D
41.5
50.0
4550 7270 9650
-
Lead
3-Jun-09
4.0
10.0
7.3 J ND -
ND
18-Nov-09
4.0
10.0
ND ND -
ND
NC 2B = 25 pg/I (05/01/07)
15-Jun-10
4.0
10.0
ND ND -
ND
1-Dec-10
4.0
10.0
ND 4.6 J
ND
1-Jun-11
4.0
10.0
ND ND
ND
20-Dec-11
5.0
10.0
ND ND
ND
30-May-12
5.0
10.0
ND ND
ND
5-Dec-12
5.0
10.0
ND ND
ND
12-Jun-13
5.0
10.0
ND ND
ND
28-Oct-13
5.0
10.0
ND ND
ND
6-May-14
EPA 6010
5.0
10.0
ND ND
ND
22-Oct-14
EPA 6010
5.0
10.0
- ND ND
ND
21-May-15
EPA 6010
2.5
10.0
ND ND ND
ND
9-Dec-15
EPA 6010
2.5
10.0
ND ND ND
ND
NC 2B = 14 pig,/1 Acute, 0.54 pg/I Chronic *
4-May-16
EPA 6010
2.5
10.0
ND 4.9 J 7.2 J
ND
14-Dec-16
EPA 6010
2.5
10.0
ND ND ND
ND
28-Jun-17
EPA 6010
2.5
10.0
ND ND ND
NC 2B = 0.54 ug/I (09/22/17)*
13-Dec-17
2.5
10.0
ND ND ND
ND
16-May-18
EPA 6010
2.5
10.0
3.8 J 2.5 J 2.8 J
--
6-Dec-18
2.5
5.0
ND ND ND
ND
8-May-19
EPA 6010D
2.5
5.0
3.5 J ND ND
8-Nov-19
EPA 6010D
1.6
5.0
3.4 J ND 2.2 J
8-May-20
EPA 6010D
4.5
5.0
ND ND ND
ND
11-Nov-20
EPA 6010D
4.5
5.0
ND 5.4 9.9
-
Manganese
16-May-18
EPA 6010
2.5
50
294 145 89.8
-
NC 2B = NE (09/22/17)
6-Dec-18
2.50
5.0
17.8 206 199
10
8-May-19
EPA 6010D
2.50
5.0
98.2 194 271
--
8-Nov-19
EPA 6010D
0.90
5.0
31.9 687 928
-
8-May-20
EPA 6010D
3.40
5.0
- - -
ND
11-Nov-20
EPA 6010D
3.40
5.0
72.2 231 154
--
Burke County Johns River C+D Expansion Landfill La Bella Associates
Permit 12-03 Page 5 of 11

TABLE A2-5: Historically Detected Surface Water Constituents
Sample
Collection Date
EPA
Method
DL
RL
SMP-5 SMP-6 SMP-7
Blanks
3-Jun-09
1.7
50.0
5.5 B ND
1.7 J
7C213
18-Nov-09
1.7
50.0
ND ND
ND
= 27pV1(05/01/07)
15-Jun-10
1.7
50.0
ND ND -
ND
1-Dec-10
1.7
50.0
2.8 J 2.8 J
ND
1-Jun-11
1.7
50.0
ND ND
2.3 J
20-Dec-11
5.0
50.0
ND ND
ND
30-May-12
5.0
50.0
ND ND
ND
5-Dec-12
5.0
50.0
ND ND
ND
12-Jun-13
5.0
50.0
ND ND
ND
28-Oct-13
5.0
50.0
No No
No
6-May-14
EPA 6010
5.0
50.0
ND ND
ND
22-Oct-14
EPA 6010
5.0
50.0
- No No
No
21-May-15
EPA 6010
2.5
50.0
ND ND ND
ND
9-Dec-15
EPA 6010
2.5
50.0
ND ND ND
ND
NC 2B = 16.1 pg/l Chronic (03/01/16)*
4-May-16
EPA 6010
2.5
50.0
3.8 J 3.9 J 6.7 J
ND
14-Dec-16
EPA 6010
2.5
50.0
ND ND ND
ND
28-Jun-17
EPA 6010
2.5
50.0
ND ND 8.0 J
13-Dec-17
2.5
50.0
ND ND ND
ND
16-May-18
EPA 6010
2.5
50.0
3.9 J ND ND
6-Dec-18
2.5
5.0
ND ND ND
ND
8-May-19
EPA 6010D
2.5
5.0
2.7 J ND ND
--
8-Nov-19
EPA 6010D
0.9
5.0
ND ND ND
--
8-May-20
EPA 6010D
3.5
5.0
ND ND ND
ND
11-Nov-20
EPA 6010D
3.5
5.0
ND ND 4.2 J
-
Selenium
6-Nov-08
3.8
10
ND 10.9 --
ND
3-Jun-09
3.8
10.0
ND ND --
ND
18-Nov-09
3.8
10.0
ND ND
ND
NC 2B = 5 pg/l (05/01/07)
15-Jun-10
3.8
10.0
ND ND -
ND
1-Dec-10
3.8
10.0
ND ND -
ND
1-Jun-11
3.8
10.0
ND ND --
ND
20-Dec-11
10.0
10.0
ND ND
ND
30-May-12
10.0
10.0
ND ND
ND
5-Dec-12
10.0
10.0
ND ND --
ND
12-Jun-13
10.0
10.0
ND ND --
ND
28-Oct-13
10.0
10.0
ND ND --
ND
6-May-14
EPA 6010
10.0
10.0
ND ND --
ND
22-Oct-14
EPA 6010
10.0
10.0
- ND ND
ND
21-May-15
EPA 6010
5.0
10.0
ND ND ND
ND
9-Dec-15
EPA 6010
5.0
10.0
ND ND ND
ND
NC 2B = 5 pg/l (03/01/16)
4-May-16
EPA 6010
5.0
10.0
ND ND ND
ND
14-Dec-16
EPA 6010
5.0
10.0
ND ND ND
ND
28-Jun-17
EPA 6010
5.0
10.0
ND ND ND
13-Dec-17
5.0
10.0
ND ND ND
ND
16-May-18
EPA 6010
5.0
10.0
ND ND ND
--
6-Dec-18
5.0
10.0
ND ND ND
ND
8-May-19
EPA 6010D
5.0
10.0
ND ND ND
--
8-Nov-19
EPA 6010D
4.7
10.0
ND ND ND
--
8-May-20
EPA 6010D
4.7
10.0
ND ND ND
ND
11-Nov-20
EPA 6010D
4.7
10.0
ND ND ND
-
Burke County Johns River C+D Expansion Landfill La Bella Associates
Permit 12-03 Page 6 of 11

TABLE A2-5: Historically Detected Surface Water Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
SMP-5
SMP-6
SMP-7
Blanks
Silver
22-May-02
-
10
16.0
B 15.0
B
15.0
14-Nov-02
-
10
ND
ND
ND
14-May-03
-
10
ND
ND
-
ND
20-Nov-03
-
10
ND
ND
-
ND
6-May-04
-
10
ND
ND
-
ND
10-Nov-04
-
10
ND
ND
-
ND
5-May-05
-
10
ND
ND
-
ND
3-Nov-05
-
10
ND
ND
-
ND
25-May-06
-
10
ND
ND
-
ND
2-Nov-06
-
10
ND
ND
-
ND
30-May-07
-
10
ND
ND
-
ND
29-Nov-07
-
10
ND
ND
-
ND
29-May-08
0.10
10.0
0.29
J 0.13
J -
ND
6-Nov-08
0.10
10.0
0.72
B 0.38
B -
0.23 J
3-Jun-09
0.10
10.0
0.18
B ND
-
0.31 J
18-Nov-09
0.10
10.0
0.27
B 0.23
B -
0.23 J
NC 2B = 0.06 pg/I (05/01/07)
15-Jun-10
0.10
10.0
ND
ND
-
ND
1-Dec-10
0.10
10.0
ND
ND
-
ND
1-Jun-11
0.10
10.0
ND
0.22
J -
ND
20-Dec-11
5.0
10.0
ND
ND
-
ND
30-May-12
5.0
10.0
ND
ND
-
ND
5-Dec-12
5.0
10.0
ND
ND
--
ND
12-Jun-13
5.0
10.0
ND
ND
--
ND
28-Oct-13
5.0
10.0
ND
ND
--
ND
6-May-14
EPA 6010
5.0
10.0
ND
ND
-
ND
22-Oct-14
EPA 6010
5.0
10.0
-
ND
ND
ND
21-May-15
EPA 6010
2.5
10.0
ND
ND
ND
ND
9-Dec-15
EPA 6010
2.5
10.0
ND
ND
ND
ND
NC 2B = 0.06 pg/I Chronic (03/01/16)*
4-May-16
EPA 6010
2.5
10.0
ND
ND
ND
ND
14-Dec-16
EPA 6010
2.5
10.0
ND
ND
ND
ND
28-Jun-17
EPA 6010
2.5
10.0
ND
ND
ND
NC 2B = 0.30 pg/I (09/22/17)*
13-Dec-17
2.5
10.0
ND
ND
ND
ND
16-May-18
EPA 6010
2.5
10.0
ND
ND
ND
6-Dec-18
2.5
5.0
ND
ND
ND
ND
8-May-19
EPA6010D
2.5
5.0
ND
ND
ND
-
8-Nov-19
EPA6010D
2.5
5.0
ND
ND
ND
-
8-May-20
EPA6010D
2.5
5.0
ND
ND
ND
ND
11-Nov-20
EPA 6010D
2.5
5.0
ND
ND
ND
--
Burke County Johns River C+D Expansion Landfill La Bella Associates
Permit 12-03 Page 7 of 11

TABLE A2-5: Historically Detected Surface Water Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
SMP-5
SMP-6
SMP-7
Blanks
Thallium
5-May-05
-
10
22.0
11.0
ND
3-Nov-05
-
10
20.0
ND
ND
25-May-06
-
10
ND
ND
ND
2-Nov-06
-
10
ND
ND
ND
30-May-07
-
5.5
0.053
J ND
ND
29-Nov-07
-
5.5
0.055
J ND
ND
29-May-08
3.0
5.5
ND
ND
ND
6-Nov-08
3.0
5.5
ND
ND
ND
3-Jun-09
3.0
5.5
ND
ND
ND
18-Nov-09
3.0
5.5
ND
ND
4.2 J
NC 2B = NE (05/01/07)
15-Jun-10
3.0
5.5
3.2
J ND
-
ND
1-Dec-10
3.0
5.5
ND
ND
4.0 J
1-Jun-11
3.0
5.5
ND
ND
ND
20-Dec-11
5.4
5.5
ND
ND
ND
30-May-12
5.4
5.5
ND
ND
ND
5-Dec-12
5.4
5.5
ND
ND
ND
12-Jun-13
5.4
5.5
ND
ND
ND
28-Oct-13
5.4
5.5
No
No
No
6-May-14
EPA 6010
5.4
5.5
ND
ND
ND
22-Oct-14
EPA 6010
5.4
5.5
-
ND
ND
ND
21-May-15
EPA 6010
5.0
5.5
ND
ND
ND
ND
9-Dec-15
EPA 6010
5.0
5.5
ND
ND
ND
ND
NC2B=0.24 (03/01/16)
4-May-16
EPA 6010
5.0
5.5
ND
ND
ND
ND
14-Dec-16
EPA 6010
5.0
5.5
ND
ND
ND
ND
28-Jun-17
EPA 6020B
0.020
5.5
ND
ND
0.044 J
--
NC 2B = NE (09/22/17)*
13-Dec-17
0.028
5.5
ND
ND
ND
ND
16-May-18
EPA 6020
2.500
5.5
ND
ND
ND
-
6-Dec-18
0.060
0.1
ND
ND
ND
ND
8-May-19
EPA 6020B
0.060
0.1
ND
ND
ND
--
8-Nov-19
EPA 6020B
0.060
0.1
ND
ND
0.095 J
-
8-May-20
EPA 6020B
0.050
0.1
ND
ND
ND
ND
11-Nov-20
EPA 6020B
0.050
0.1
ND
0.076
J 0.12
-
Vanadium
6-Nov-08
0.20
25.0
0.90
B 8.9
B -
2.1 J
3-Jun-09
0.20
25.0
17.4
J 7.5
J -
1.0 J
18-Nov-09
0.20
25.0
0.26
B 0.30
B -
0.56 J
NC 2B = NE (05/01/07)
15-Jun-10
0.20
25.0
1.5
B 1.0
B -
0.98 J
1-Dec-10
0.20
25.0
1.1
J 13.7
J -
ND
1-Jun-11
0.20
25.0
1.1
J 0.74
J -
ND
20-Dec-11
5.0
25.0
ND
ND
ND
30-May-12
5.0
25.0
ND
ND
ND
5-Dec-12
5.0
25.0
ND
ND
ND
12-Jun-13
5.0
25.0
7.6
J ND
ND
28-Oct-13
5.0
25.0
ND
ND
ND
6-May-14
EPA 6010
5.0
25.0
ND
ND
ND
22-Oct-14
EPA 6010
5.0
25.0
-
ND
ND
ND
21-May-15
EPA 6010
2.5
25.0
7.5
J ND
4.1 J
ND
9-Dec-15
EPA 6010
2.5
25.0
ND
ND
3.9 J
ND
4-May-16
EPA 6010
2.5
25.0
10.9
J 11.4
J 23.9 J
ND
14-Dec-16
EPA 6010
2.5
25.0
ND
ND
ND
ND
28-Jun-17
EPA 6010
2.5
25.0
ND
ND
3.1 J
--
NC 2B = NE (09/22/17)*
13-Dec-17
2.5
25.0
ND
ND
ND
--
16-May-18
EPA 6010
2.5
25.0
14
J 3
J 3.7 J
--
6-Dec-18
2.5
5.0
5.4
ND
ND
ND
8-May-19
EPA 6010D
2.5
5.0
8.9
ND
ND
--
8-Nov-19
EPA 6010D
1.3
5.0
8.5
ND
2.4 J
-
8-May-20
EPA 6010D
3.9
5.0
6.2
ND
ND
ND
11-Nov-20
EPA 6010D
3.9
5.0
12.0
14.6
22.5
-
Burke County Johns River C+D Expansion Landfill La Bella Associates
Permit 12-03 Page 8 of 11

TABLE A2-5: Historically Detected Surface Water Constituents
Sample
EPA
Analyte
Collection Date
Method
DL
RL
SMP-5
SMP-6
SMP-7
Blanks
Zinc
30-May-07
-
10
1.8
B
ND
1.6 J
29-Nov-07
-
10
9.6
B
ND
3.1 J
29-May-08
0.40
10.0
6.0
B
ND
3.0 J
6-Nov-08
0.40
10.0
0.82
B
1.4
B
-
2.7 J
3-Jun-09
0.40
10.0
33.7
B
9.6
B
--
82.0
18-Nov-09
0.40
10.0
2.2
B
2.5
B
--
3.1 J
NC 2B = 50 pg/I (05/01/07)
15-Jun-10
0.40
10.0
ND
ND
-
ND
1-Dec-10
0.40
10.0
8.8
J
6.6
J
--
0.62 J
1-Jun-11
0.40
10.0
15.1
B
21.5
B
-
13.7
20-Dec-11
10.0
10.0
ND
ND
-
ND
30-May-12
10.0
10.0
ND
ND
-
ND
5-Dec-12
10.0
10.0
ND
ND
-
ND
12-Jun-13
10.0
10.0
ND
ND
76.5
28-Oct-13
10.0
10.0
ND
ND
ND
6-May-14
EPA 6010
10.0
10.0
ND
ND
ND
22-Oct-14
EPA 6010
10.0
10.0
-
ND
ND
ND
21-May-15
EPA 6010
5.0
10.0
ND
5.8
J
ND
ND
9-Dec-15
EPA 6010
5.0
10.0
ND
ND
ND
ND
NC 2B = 36.2 pg/I (03/01/16)*
4-May-16
EPA 6010
5.0
10.0
8.7
J
7.7
J
15.2
ND
14-Dec-16
EPA 6010
5.0
10.0
ND
ND
6.9 J
ND
28-Jun-17
EPA 6010
5.0
10.0
5.8
J
17.4
39.4
--
13-Dec-17
5.0
10.0
ND
ND
ND
ND
16-May-18
EPA 6010
5.0
10.0
10.7
ND
ND
--
6-Dec-18
5.0
10.0
5
J
5.3
J
ND
51.4
8-May-19
EPA 6010D
5.0
10.0
5.4
J
ND
ND
--
8-Nov-19
EPA 6010D
3.9
10.0
ND
ND
ND
--
8-May-20
EPA 6010D
9.5
10.0
ND
ND
ND
ND
11-Nov-20
EPA 6010D
9.5
10.0
ND
ND
18.4
--
Hardness, Total (SM 2340B)
28-Jun-17
EPA 6010
662.00
662.0
32,900
20,900
10,800
-
13-Dec-17
662.00
662.0
28,900
12,900
7,410
ND
16-May-18
EPA 6010
662.00
NE
26,100
14,900
18,500
-
6-Dec-18
662.00
662.0
33900
11100
10200
ND
8-May-19
662.00
662.0
36800
13000
9330
ND
Mercury
8-Nov-19
EPA 7470A
0.10
0.2
0.16
J„C
0.15
J„C
0.15 J„
8-May-20
EPA 7470A
0.12
0.2
ND
ND
ND
0.58
Hardness, Total(SM 234013)
8-Nov-19
EPA 6010D
131.00
662.0
20500
15800
9710
8-May-20
EPA 6010D
131.00
662.0
24800
9880
9500
11-Nov-20
EPA 6010D
131.00
662.0
16900
14600
20800
-
Magnesium
8-Nov-19
EPA 6010D
17.10
100.0
2020
1570
1320
-
11-Nov-20
EPA 6010D
67.80
100.0
1820
1320
2040
-
Burke County Johns River C+D Expansion Landfill La Bella Associates
Permit 12-03 Page 9 of 11

TABLE A2-5: Historically Detected Surface Water Constituents
Sample
EPA
Analyte
Collection Date
Method
DL
RL
SMP-5
SMP-6
SMP-7
Blanks
Organics
Acetone
29-Nov-07
--
100
3.6
B ND
5.1 J
29-May-08
20
100
ND
ND
ND
6-Nov-08
20
100
ND
ND
ND
3-Jun-09
2.2
100
5.7
J ND
ND
18-Nov-09
2.2
100
ND
ND
ND
NC 2B = NE (05/01/07)
15-Jun-10
2.2
100
2.2
B 2.3
B -
7.2 J
1-Dec-10
2.2
100
ND
ND
3.7 J
1-Jun-11
2.2
100
5.4
B 2.9
B
3.9 J
20-Dec-11
2.2
100
ND
ND
ND
30-May-12
2.2
100
ND
ND
ND
5-Dec-12
10.0
100
ND
ND
ND
12-Jun-13
10.0
100
ND
ND
--
ND
28-Oct-13
10.0
100
ND
ND
ND
6-May-14
EPA 8260
10.0
100
ND
ND
ND
22-Oct-14
EPA 8260
10.0
100
-
ND
ND
ND
21-May-15
EPA 8260
10.0
100
ND
ND
ND
ND
9-Dec-15
EPA 8260
10.0
100
ND
ND
ND
ND
NC 2B = 1,100 mg/I (03/01/16)
4-May-16
EPA 8260
10.0
100
ND
ND
ND
ND
14-Dec-16
EPA 8260
10.0
100
ND
ND
ND
ND
28-Jun-17
EPA 8260
10.0
100
14.7
J 29.4
J 18 J
35.3 J
NC 2B = NE (09/22/17)
13-Dec-17
10.0
100
ND
ND
ND
ND
16-May-18
EPA 8260
10.0
100
ND
ND
ND
--
6-Dec-18
10.0
25
ND
ND
ND
ND
8-May-19
EPA826OD
8.2
25
ND
ND
ND
ND
8-Nov-19
EPA826OD
6.2
25
ND
ND
ND
--
8-May-20
EPA826OD
6.2
25
ND
ND
ND
ND
11-Nov-20
EPA 826OD
6.2
25
ND
ND
ND
--
Benzene
28-Jun-17
EPA 8260
0.25
1.0
ND
0.59
J ND
--
NC 2B = 1.19 mg/I (03/01/16)
13-Dec-17
0.25
1.0
ND
ND
ND
ND
16-May-18
EPA 8260
0.25
1.0
ND
ND
ND
--
6-Dec-18
0.25
1.0
ND
ND
ND
ND
8-May-19
EPA826OD
0.20
1.0
ND
ND
ND
ND
8-Nov-19
EPA 826OD
0.15
1.0
ND
ND
ND
8-May-20
EPA826OD
0.15
1.0
ND
ND
ND
ND
11-Nov-20
EPA 826OD
0.15
1.0
ND
ND
ND
--
Chloromethane
15-Jun-10
0.11
1.0
ND
0.11
J -
ND
NC 2B = NE (05/01/07)
1-Dec-10
0.11
1.0
ND
ND
-
ND
1-Jun-11
0.11
1.0
ND
ND
-
ND
20-Dec-11
0.11
1.0
ND
ND
--
ND
30-May-12
0.11
1.0
ND
ND
--
ND
5-Dec-12
0.11
1.0
ND
ND
--
ND
12-Jun-13
0.11
1.0
ND
ND
--
ND
28-Oct-13
0.11
1.0
ND
ND
--
ND
6-May-14
EPA 8260
0.11
1.0
ND
ND
-
ND
22-Oct-14
EPA 8260
0.11
1.0
-
ND
ND
ND
21-May-15
EPA 8260
0.11
1.0
ND
ND
ND
ND
9-Dec-15
EPA 8260
0.11
1.0
ND
ND
ND
ND
NC 2B = NE (03/01/16)
4-May-16
EPA 8260
0.11
1.0
ND
ND
ND
ND
14-Dec-16
EPA 8260
0.11
1.0
ND
ND
ND
0.17 J
28-Jun-17
EPA 8260
0.11
1.0
0.46
J 0.65
J 0.5 J
-
NC 2B = NE (09/22/17)
13-Dec-17
0.11
1.0
ND
ND
ND
ND
16-May-18
EPA 8260
0.11
1.0
ND
ND
ND
6-Dec-18
0.11
1.0
ND
ND
ND
ND
8-May-19
EPA826OD
0.38
1.0
ND
ND
ND
ND
8-Nov-19
EPA 826OD
0.39
1.0
ND
ND
ND
8-May-20
EPA826OD
0.39
1.0
ND
ND
ND
ND
11-Nov-20
EPA 826OD
0.39
1.0
ND
ND
ND
--
Burke County Johns River C+D Expansion Landfill LaBella Associates
Permit 12-03 Page 10 of 11

TABLE A2-5: Historically Detected Surface Water Constituents
Sample
EPA
Collection Date
Method
DL
RL
SMP-5 SMP-6 SMP-7
Blanks
Trichloroethene
14-Dec-16
EPA 8260
0.47
1.0
ND 0.52 J ND
ND
NC 2B = 30 ug/I (03101/16)
28-Jun-17
EPA 8260
0.47
1.0
ND 1.1 ND
13-Dec-17
0.47
1.0
ND 0.47 J ND
ND
16-May-18
EPA 8260
0.47
1.0
ND ND ND
--
6-Dec-18
0.47
1.0
ND ND ND
ND
8-May-19
EPA 8260D
0.34
1.0
ND ND ND
ND
8-Nov-19
EPA 8260D
0.22
1.0
ND ND ND
8-May-20
EPA 8260D
0.22
1.0
ND ND ND
ND
11-Nov-20
EPA 8260D
0.22
1.0
ND ND ND
--
1,1-Dichloroethane
1-Jun-11
0.32
5.0
ND 0.41 J --
ND
NC 2B = NE (05/01/07)
20-Dec-11
0.32
5.0
ND ND -
ND
30-May-12
0.32
5.0
ND ND
ND
5-Dec-12
0.32
5.0
ND 1.6 J
ND
12-Jun-13
0.32
5.0
ND ND
ND
28-Oct-13
0.32
5.0
ND 0.96 J
ND
6-May-14
EPA 8260
0.32
5.0
ND ND
ND
22-Oct-14
EPA 8260
0.32
5.0
- 1.5 J ND
ND
21-May-15
EPA 8260
0.32
5.0
ND ND ND
ND
9-Dec-15
EPA 8260
0.32
5.0
ND ND ND
ND
NC 2B = 0.38 pg/I (03/01/16)
4-May-16
EPA 8260
0.32
5.0
ND ND ND
ND
14-Dec-16
EPA 8260
0.32
5.0
ND 2.6 J ND
ND
28-Jun-17
EPA 8260
0.32
5.0
ND 4.2 J ND
NC 2B = NE (09/22/17)
13-Dec-17
0.32
5.0
ND 1.5 J ND
ND
16-May-18
EPA 8260
0.32
5.0
ND ND ND
6-Dec-18
0.32
1.0
ND ND ND
ND
8-May-19
EPA 8260D
0.41
1.0
ND ND ND
ND
8-Nov-19
EPA 8260D
0.27
1.0
ND ND ND
--
8-May-20
EPA 8260D
0.27
1.0
ND ND ND
ND
11-Nov-20
EPA 8260D
0.27
1.0
ND ND ND
--
1,4-Dichlorobenzene
16-May-18
EPA 8260
0.33
1
0.33 J ND ND
--
NC 2B = 488 pg/I
6-Dec-18
0.33
1
ND ND ND
ND
(total chlorinated benzenes)
8-May-19
EPA 8260D
0.58
1
ND ND ND
ND
8-Nov-19
EPA 8260D
0.26
1
ND ND ND
--
8-May-20
EPA 8260D
0.26
1
ND ND ND
ND
11-Nov-20
EPA 8260D
0.26
1
ND ND ND
--
cis-1,2-Dichloroethene
22-Oct-14
EPA 8260
0.19
5.0
- 0.20 J ND
ND
NC 2B = NE (05/15/13)
21-May-15
EPA 8260
0.19
5.0
ND ND ND
ND
9-Dec-15
EPA 8260
0.19
5.0
ND ND ND
ND
NC 2B = 60 pg/I (03/01/16)
4-May-16
EPA 8260
0.19
5.0
ND ND ND
ND
14-Dec-16
EPA 8260
0.19
5.0
ND 0.43 J ND
ND
28-Jun-17
EPA 8260
0.19
5.0
ND 1.10 J ND
NC 2B = NE (09/22/17)
13-Dec-17
0.19
5.0
ND 0.37 J ND
ND
16-May-18
EPA 8260
0.19
5.0
ND ND ND
6-Dec-18
0.2
1.0
ND ND ND
ND
8-May-19
EPA 8260D
0.7
1.0
ND ND ND
ND
8-Nov-19
EPA 8260D
0.3
1.0
ND ND ND
8-May-20
EPA 8260D
0.3
1.0
ND ND ND
ND
11-Nov-20
EPA 8260D
0.3
1.0
ND ND ND
--
Notes:
All concentrations in micrograms per liter (pg/1) = parts per billion. NI = Monitoring well not yet installed.
RL = Method Reporting Limit AB = Monitoring well abandoned.
DL = Laboratory Method Detection Limit. - = Not sampled for this parameter or Not reported
ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006).
J = Estimated value - concentration is less than the RL but greater than the DL.
B = Blank -Qualified (Based on similar concentrations detected in field, trip, or method blanks).
NC 2B = Groundwater Standard from 15A NCAC 2B. NE = No NC 2B established.
Values above the NC 2B Standard are bold.
Surface waters classified as WS-IV (water supply IV, highly developed), B (primary recreation, fresh water), and CA (critical area).
*NC 2B Groundwater Standards and Protective Values include acute and chronic exposure levels for designated metals
based on dissolved metal and in -stream water hardness results. Site specific values may be calculated based on water hardness at time of sampling.
Burke County Johns River C+D Expansion Landfill LaBella Associates
Permit 12-03 Page 11 of 11