3902_Granville_Butner_MSWLF_Aug20GW_FID1523593_20201222

-HENR USE ONLY ❑Paper Report EjElectronic Data - Email CD (data loaded: Yes / No) Doc/Event #:
' NC DENR II Environmental Monitoring
Division of Waste Management - Solid Waste Reoortina Form
Notice: This form and any information attached to it are 'Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 136 .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information _
Name of entity submitting data (laboratory, consultant, facility owner):
La Bella Associates (Joyce Engineering)
Contact for questions about data formatting. Include data preparers name, telephone number and E-mail address:
Name: G. Van Ness Burbach, PhD, PG Phone: [phone]
E-mail: [e-mail]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
State Road 1004 August 27, 2020
Butner Landfill Butner, NC 39-02 .1600 September 10, 2020
September 30, 2020
Environmental Status: (Check all that apply)
❑ InitiaUBackground Monitoring Detection Monitoring QX Assessment Monitoring Q Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells
Groundwater monitoring data from private water supply wells FRI
Leachate monitoring data
Surface water monitoring data ❑
Methane gas monitoring data
Corrective action data (specify) MNA Data
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, 1 have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. 1 am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
G. Van Ness Burbach, PhD, PG Senior Technical Consultant [phone]
2211 W. Meadowview Rd., Ste. 101 Greensboro, NC 27407
Facility Representative Address
C-0762
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009
:ode) Telephone Number
Affix NC Licensed/ Professional Geologist Seal
.•� BAR O(jti°�,,,.
'o9z �NSEp q
�349 C.)

LaBeRa
Powered by par Lnef sh11,
December 21, 2020
Ms. Jaclynne Drummond
Dept. of Environmental and Natural Resources
Solid Waste Section
Asheville Regional Office
2090 US Highway 70
Swannanoa, NC 28778
Via Email: [e-mail]
RE: Water Quality Monitoring Report — August 2020 Event
and Corrective Action Evaluation Report
Granville County — Butner Landfill, Permit No. 39-02
Project No. 2203013
Dear Jackie:
On behalf of Granville County, LaBella Associates is submitting this combination Water Quality
Monitoring Report (WQMR) and Corrective Action Evaluation Report (CAER) for the Butner Landfill
(Permit No. 39-02) via ShareFile. If you have any questions, please contact me at [phone] or
[e-mail]. Thank you.
Respectfully submitted,
LaBella Associates
ro�5z-cr-�
Van Burbach, PhD, PG
Senior Technical Consultant
Enclosure
cc: Jason Falls, Granville County
2211 W. Meadowview Road #1o1 i Greensboro. NC 27407 p [phone]
www.labeLLapc.corn

Prepared For:
Granville County
Solid Waste Department
P.O. Box go6
Oxford, North Carolina 27565
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Submitted by:
LaBella Associates (Joyce Engineering)
2211 West Meadow/view Rd.
Suite 101
Greensboro, NC 27407
(336) 323-oog2
NC License No. C-0782
LaBeRa
Powered by partnership.
August 2020 WATER QUALITY MONITORING REPORT
and CORRECTIVE ACTION EVALUATION REPORT
BUTNER LANDFILL
Permit NO.39-02
DECEMBER 2020
PROJECT NO. 2203013

August 2020 Water Quality Monitoring Report
and Corrective Action Evaluation Report
Butner Landfill, Permit No. 39-02
Granville County, North Carolina
TABLE OF CONTENTS
ACRONYMS
1.0 INTRODUCTION...........................................................................................................................
1.1 Site Information.........................................................................................................................
1.2 Regulatory Status.......................................................................................................................
1.3 Site Conceptual Model..............................................................................................................
1.3.1 Site Geology.....................................................................................................................
iv
1
1
1
1
1
1.3.2 Aquifer Characteristics.........................................................................................................2
2.0 FACILITY MONITORING PROGRAM.................................................................................................2
2.1 Groundwater Monitoring Program.................................................................................................2
2.2 Surface Water Monitoring Program...............................................................................................3
3.0 AUGUST 2020 SAMPLING EVENT..................................................................................................4
3.1 Field Work........................................................................................................................................4
3.3 Laboratory Analyses and Quality Control.......................................................................................4
4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSES....................................................................5
4.1 Analytical Results for Groundwater and Comparisons to Standards...........................................5
4.1.1 Inorganic Analyses...............................................................................................................5
4.1.2 Organic Analyses..................................................................................................................6
4.2 Statistical Analyses.........................................................................................................................6
4.2.1 Statistical Methods..............................................................................................................6
4.2.2 Results of Statistical Analyses............................................................................................6
4.3 Analytical Results for Surface Water and Comparisons to Standards........................................6
5.0 HYDROGEOLOGICAL CONDITIONS.................................................................................................7
5.1 Horizontal Gradient and Flow.........................................................................................................7
5.2 Vertical Gradients...........................................................................................................................7
6.0 CONCLUSIONS FOR AUGUST 2020 WATER QUALITY MONITORING REPORT .............................8
August 2020 Water Quality Monitoring Report LaBella Associates
and Corrective Action Evaluation Report December 2020
Granville County - Butner Landfill, Permit No. 39-02

August 2020 Water Quality Monitoring Report
and Corrective Action Evaluation Report
Butner Landfill, Permit No. 39-02
Granville County, North Carolina
TABLE OF CONTENTS (Continued)
7.0 2020 CORRECTIVE ACTION EVALUATION REPORT(CAER)...........................................................8
7.1 Contaminant Distribution...............................................................................................................8
7.2 Contaminant Trends.......................................................................................................................9
7.3 Physical and Chemical Changes in Aquifer Conditions............................................................. 10
7.4 Physical and Chemical Changes in Plume Characteristics....................................................... 11
7.5 Refining the Site Conceptual Model........................................................................................... 12
7.6 Evaluation of the Impact of Corrective Actions.......................................................................... 12
7.6.1 Contaminant Levels.......................................................................................................... 12
7.6.2 Evaluation of MNA Parameters........................................................................................ 13
7.6.3 Evaluation of Phytoremediation....................................................................................... 17
7.6.4 Impacts on Hydraulic Gradients....................................................................................... 18
7.6.5 Contaminant Removal Efficiencies and Mass of Contaminants Removed ................... 18
7.7 Status of Impacts at the Compliance Boundary........................................................................ 19
7.8 Off -Site Migration Concerns........................................................................................................ 20
7.9 CONCLUSIONS FOR CAER............................................................................................................ 20
7.9.1 Proposed ASD for Vanadium............................................................................................ 20
7.9.2 Modifications Needed to Selected Remedy.................................................................... 20
7.9.3 Recommendations for MNA Indicator Parameters......................................................... 20
7.9.4 Contingency Plan............................................................................................................... 21
7.9.5 Land Use Restrictions....................................................................................................... 21
8.0 REFERENCES................................................................................................................................22
August 2020 Water Quality Monitoring Report LaBella Associates
and Corrective Action Evaluation Report December 2020
Granville County- Butner Landfill, Permit No. 39-02

August 2020 Water Quality Monitoring Report
and Corrective Action Evaluation Report
Butner Landfill, Permit No. 39-02
Granville County, North Carolina
TABLE OF CONTENTS (Continued)
Tables
Table 1
August 2020 Groundwater Elevations
Table 2
August 2020 Field Parameters
Table 3
August 2020 Detected Constituents in Groundwater
Table 4
August 2020 Exceedances of Groundwater Standards
Table 5
August 2020 Hydraulic Gradients and Groundwater Flow Velocities
Table 6
August 2020 Monitored Natural Attenuation Parameters
Charts
Chart 1
Benzene Concentrations vs. Time
Chart 2
1,4-Dioxane Concentrations vs. Time
Chart 3
Cobalt Concentrations vs. Time
Chart 4
Vanadium Concentrations vs. Time
Chart 5
pH vs. Time
Chart 6
Conductivity vs. Time
Chart 7
ORP vs. Time
Chart 8
DO vs. Time
Figures
Figure 1
Site Location Map
Figure 2
Geologic Map
Drawings
Drawing 1
Groundwater Potentiometric Surface Map
Drawing 2
Benzene Isoconcentration Map
Drawing 3
Benzene Cross -Sections A and B
Drawing 4
1,4-Dioxane Isoconcentration Map
Drawing 5
1,4-Dioxane Cross -Sections A and B
Drawing 6
Cobalt Isoconcentration Map
Drawing 7
Cobalt Cross -Sections A and B
Drawing 8
Vanadium Isoconcentration Map
Drawing 9
Vanadium Cross -Sections A and B
Drawing 10
2020 Tree Survey
Appendices
Appendix A
Monitoring Well Construction Data
Appendix B
Field Data Logs
Appendix C
Laboratory Analytical Reports and Chains of Custody
Appendix D
Historical Groundwater Elevations
Appendix E
Historical Constituents in Groundwater
Appendix F
Historical Constituents in Surface Water
Appendix G
Historical Monitored Natural Attenuation Parameters
Appendix H
Phytoremediation Tree inspection Log
Appendix I
BIOSCREEN Input and Output
August 2020 Water Quality Monitoring Report LaBella Associates
and Corrective Action Evaluation Report December 2020
Granville County- Butner Landfill, Permit No. 39-02

ACRONYMS
ACM Assessment of Corrective Measures (Report)
C&D Construction and Demolition Waste
CAP Corrective Action Plan (Report)
CAER Corrective Action Evaluation Report (Report)
COC Chain of Custody (for samples sent to a laboratory)
COC Constituent of Concern (for groundwater corrective action)
DENR See NCDENR
DEQ See NCDEQ
DL Detection Limit (for laboratory data) (or MDL)
DO Dissolved Oxygen
EPA United States Environmental Protection Agency
GPS Site -specific Groundwater Protection Standards per NCSWMR §1634.g-h
GWPS Groundwater Protection Standards (established by DENR-SWS - no longer used)
IMAC Interim Maximum Allowable Concentration
JOYCE Joyce Engineering, Inc.
LaBella LaBella Associates, PC
LFG Landfill Gas
MDL Method Detection Limit (for laboratory data) (or DL)
MNA Monitored Natural Attenuation
MRL Method Reporting Limit (for laboratory data) (or RL)
MSW Municipal Solid Waste
NC213 North Carolina Surface Water Standards found in 15A NCAC 2B
NC2L North Carolina Groundwater Standards found in 15A NCAC 2L
NCAC North Carolina Administrative Code
NCDENR North Carolina Department of Environment and Natural Resources (now NCDEQ)
NCDEQ North Carolina Department of Environmental Quality (formerly NCDENR)
NCSWMR North Carolina Solid Waste Management Regulations (15A NCAC 13B.1600)
ND Not Detected (for laboratory data)
NES Nature and Extent Study (Report)
0&M Operations and Maintenance
PQL Practical Quantitation Limit (for laboratory data) (or QL)
QL Quantitation Limit (for laboratory data) (or PQL)
RL Reporting Limit (for laboratory data) (or MRL)
SWS Solid Waste Section (of NCDENR/NCDEQ)
VOC Volatile Organic Compound
WQMP Water Quality Monitoring Plan (Report)
WQMR Water Quality Monitoring Report (Report)
August 2020 Water Quality Monitoring Report
and Corrective Action Evaluation Report
Granville County- Butner Landfill, Permit No. 39-02
LaBella Associates
December 2020
iv

1.0 INTRODUCTION
1.1 Site Information
The Butner Landfill is a closed municipal solid waste (MSW) landfill, located off State Route 1004
near the town of Butner, in Granville County, North Carolina (Figure 1). The Butner facility started
receiving solid waste prior to May 1973. Permit Number 39-02, was issued by the State of North
Carolina on March 3, 1982. The facility stopped receiving solid waste in August 1998. At the
present, a small recycling center and transfer station are operated by the County of Granville at the
entrance of the closed landfill.
1.2 Regulatory Status
Groundwater and surface water monitoring at the Butner Landfill is completed in accordance with
NCSWMR §.1634-.1637. The site is currently in Assessment Monitoring and a Corrective Action
Monitoring Program. Groundwater samples are collected semiannually and analyzed following the
approved Corrective Action Plan. Surface water samples are collected and sampled for constituents
listed in Appendix I of 40 CFR Part 258 (from here on known as the Appendix I constituents) during
each sampling event.
In accordance with North Carolina Solid Waste Management Regulations (NCSWMR), the Butner
Landfill entered an Assessment Monitoring Program in December of 1997 as a result of detections
of volatile organic compounds and pesticides above Title 15A of the North Carolina Administrative
Code Subchapter 2L (NC2L) Groundwater Standards. An Assessment of Corrective Measures (ACM)
was initiated in 2003 and then suspended by North Carolina Department of Environment and
Natural Resources (NCDENR) [now the North Carolina Department of Environmental Quality
(NCDEQ)] since there had been no more NC21- exceedances. The Nature and Extent Study (NES) and
ACM recommenced in 2007 when apparent volatile organic compound (VOC) exceedances of the
NC21- Standards began to appear; however, they were again suspended when it was determined that
the apparent exceedances were not statistically significant increases (SSTs) above background. An
ACM was reinitiated after an exceedance of benzene in monitoring well MW-2R in December 2012,
and was submitted to NCDENR in May 2013. Approval of the ACM was granted in a letter from
NCDENR dated June 27, 2013. A Corrective Action Plan (CAP) for monitored natural attenuation
(MNA) plus phytoremediation was submitted to NCDENR on May 23, 2014, and was approved by
NCDENR on June 18, 2014.
1.3 Site Conceptual Model
1.3.1 Site Geology
The Butner Landfill lies within the Piedmont physiographic province. The topography of the area
consists of rolling hills that support farmland and forest. The majority of the landfill area is underlain
by Carolina Slate Belt felsic volcanic rocks, which have been metamorphosed into greenish grey
foliated tuffs. The Carolina Slate Belt geologic province is characterized by a thick mantle of
saprolite overlying Late Proterozoic and Paleozoic (550 to 650 million year old) metamorphosed
sedimentary and volcanic rocks, intruded by granitic rocks.
A geologic map of the area has been included as Figure 2 (Rhodes, et al, 2012). The geologic map
indicates that the Butner Landfill is located in an area mapped as Zfgms/Zgms - Granodiorite
Tonalite of the Stem and Moriah plutons. In addition, the geologic map (Rhodes, et al, 2012)
indicates a diabase (Jd) intrusion under the southeastern corner of the facility. Granitic and felsic
August 2020 Water Quality Monitoring Report
and Corrective Action Evaluation Report
Granville County- Butner Landfill, Permit No. 39-02
LaBella Associates
December 2020
1

metavolcanic rocks have been observed in float and borings at the facility. Diabase outcrops have
been observed in the creek along the southeastern portion of the site.
The southeastern portion of the site is underlain by Triassic Sanford Formation (conglomerate,
sandstone, and mudstone), which unconformably overlies the Carolina Slate Belt felsic volcanic
rocks. There is no exposure of the Sanford Formation at the site; however, float material consisting
of grey, coarse -grained sandstone with quartz pebbles has been observed. Both the Sanford
Formation and the diabase dikes observed in the vicinity of the site are related to the formation of
the Deep River Triassic Basin.
1.3.2 Aquifer Characteristics
The water table under the area of investigation was encountered in the unconfined aquifer that is
mostly in the transition zone that consists of saprolite and weathered and/or highly fractured
bedrock. The saturated portion of the uppermost aquifer beneath the study area is vertically
continuous to bedrock. Groundwater in the saprolite feeds the fractures in the bedrock and is
discharged into creeks south of the landfill. Groundwater flow at deeper levels within the fractured
bedrock is controlled by fracture orientation and connectivity. This unconfined aquifer is pervasive
across the site and the water table generally mimics the surface topography; however, flow at deeper
levels within the bedrock may be controlled by fractures.
Depth to groundwater is measured in all compliance monitoring wells at the site prior to each
sampling event. Depth to water typically ranges from 2 to 3 feet below top of casing (ft-btoc) in wells
MW-2R and MW 3R; 8-14 ft-btoc in MW-4, MW-5, and MW-6; and 42-48 ft-btoc in MW 1R. Recent
(August 2020) water level data are presented in Table 1. The groundwater potentiometric surface
contours shown in Drawing 1 are based on data from the August 2020 sampling event.
Groundwater flow beneath the facility is predominantly to the south and southeast. Assessment of
Groundwater flow based on the August 2020 data is presented in Section 5.0.
Based on the above -described geologic and hydrogeologic information, the groundwater flow regime
on this site is well -constrained and predictable. Migration of groundwater contaminants are
expected to follow the general groundwater flow paths shown on Drawing 1. The creek which
crosses the southern corner of the facility property, downgradient of the plume, is a groundwater
discharge feature and therefore a hydrologic divide that should prevent migration of the plume
beyond it. Also, there is a diabase dike roughly coinciding with the creek which could also act as a
barrier to groundwater flow off of the property, or it could create a preferred pathway parallel to the
creek. There are no known preferred pathways that could significantly affect plume migration or the
effectiveness of the groundwater monitoring network to monitor plume migration.
2.0 FACILITY MONITORING PROGRAM
2.1 Groundwater Monitoring Program
Seven active groundwater monitoring wells comprise the monitoring network at the Butner Landfill:
MW-1R (facility background well), MW-2R, MW-3R, MW-4, MW-5, MW-6, and NES-1 (which was
installed as part of a Nature and Extent Study on November 14, 2007). The monitoring well
locations are shown on Drawing 1. The following table summarizes the monitoring network and
required analytical parameters. A summary of well construction details is provided in Appendix A.
August 2020 Water Quality Monitoring Report
and Corrective Action Evaluation Report
Granville County- Butner Landfill, Permit No. 39-02
LaBella Associates
December 2020
2

Groundwater Monitoring Network
Total
Lithology
1st SA
Monitoring
Date
Classification
Monitoring
Depth
of
Event
2"d SA Event
Well
Installed
Program
(feet)
Screened
Analyses
Analyses
Interval
Assessment
App. 11,
App. I + Det.
MW-1R
4/21/94
Background
/CAMP
45.1
Saprolite
MNA*
plus 1,4-
Dioxane
Compliance/
Assessment
App. 11,
App. I + Det.
MW-2R
4/12/94
Performance
/CAMP
19.0
Saprolite
MNA
plus 1,4-
Dioxane, MNA
Compliance/
Assessment
App. 11,
App. I + Det.
MW-3R
4/14/94
Performance
/CAMP
37.2
Bedrock
MNA
plus 1,4-
Dioxane, MNA
MW-4
4/18/94
Compliance
Detection
31.5
Bedrock
App. I
App. I plus
1,4-Dioxane
MW-5
4/18/94
Compliance
Detection
23.4
Saprolite
App. I
App. I plus
1,4-Dioxane
MW-6
4/19/94
Compliance
Detection
31.7
Saprolite/
App I
App. I plus
Bedrock
1,4-Dioxane
NES-1
11/14/07
Nature &
Sentinel
33.0
Saprolite/
COCs,
COCs
Extent
Bedrock
MNA*
Notes:
App. I = NCSWMR Appendix I list of constituents plus 1,4-Dioxane.
App. II = NCSWMR Appendix II list of constituents plus 1,4-Dioxane.
App. I + Det. = App. I list plus detected App. II constituents.
COCs = Constituents of Concern.
MNA = Monitored Natural Attenuation parameters.
CAMP = Corrective Action Monitoring Plan.
Current Appendix II detected constituents: Tin.
Current COCs: Benzene, 1,4-dioxane, cobalt, vanadium.
MNA Field Parameters: Temperature, pH, specific conductance, oxidation reduction potential,
turbidity, dissolved oxygen, and ferrous iron. Dissolved carbon dioxide will be tested during both
events every third year (next in 2022).
MNA Laboratory Parameters: Dissolved methane, alkalinity, sulfate, nitrate, chloride, biological oxygen
demand (BOD), chemical oxygen demand (COD), and total organic carbon (TOC). Dissolved hydrogen,
volatile fatty acids, sulfide, ethane and ethene are analyzed during both events every third year (next
in 2022).
MNA parameters are only required annually for MW-1R & NES-1.
2.2 Surface Water Monitoring Program
Two surface water samples have been collected semiannually since September 1994, at the Butner
Landfill. The surface water sample points SW-1 and SW-2 are located respectively upstream and
downstream of the facility, along an unnamed tributary of Picture Creek. The surface water samples
are collected and analyzed for the NC Appendix I list of constituents plus 1,4-dioxane during both
semiannual events when there is sufficient water flow in the creek. The surface water sampling
locations are shown on Drawing 1.
August 2020 Water Quality Monitoring Report
and Corrective Action Evaluation Report
Granville County- Butner Landfill, Permit No. 39-02
LaBella Associates
December 2020
3

3.0 AUGUST 2020 SAMPLING EVENT
3.1 Field Work
On August 27, 2020, LaBella Associates PC (LaBella) personnel visited the Butner Landfill to purge
and sample monitoring wells MW-1R, MW-2R, MW-3R, MW-4, MW-5, MW-6, and NES-1. All
monitoring wells were purged and sampled using new, disposable bailers or a submersible pump.
An electronic water level meter was used to take the depth to water to ±0.05 foot. Calculated
groundwater elevations can be found in Table 1. Measurements of temperature, pH, turbidity,
dissolved oxygen, oxidation-reduction potential (ORP), and conductivity were recorded in a field log.
Ferrous Iron (an MNA parameter) was also measured for monitoring wells MW-2R and MW-3R for
this sampling event and recorded in the field log.
Prior to sampling, laboratory -supplied containers were prepared with the following information:
• Monitoring well number (completed by laboratory/field personnel),
• Date and time of sample collection (completed by laboratory/field personnel),
• Initials of sampling personnel (completed by laboratory/field personnel),
• Project name and number (completed by the laboratory/field personnel),
• Chemical preservative (completed by the laboratory/field personnel); and
• Requested chemical analysis (completed by the laboratory/field personnel).
Groundwater samples from each monitoring well were collected directly from the bailers or tubing
into the provided laboratory containers, within 24 hours of the final purge volume. Immediately after
collection, the samples were placed in a laboratory provided cooler and preserved on ice. Field Logs
are provided in Appendix B and field parameters are summarized in Table 2.
Surface water points SW-1 and SW-2 were dry and therefore were not sampled during the August
2020 event.
On September 30, 2020, LaBella personnel visited the Butner Landfill to purge and resample
monitoring well MW-3R due to a suspect detection of vinyl chloride in the August sample. The
resampling followed the same protocol as the August 2020 sampling event.
3.3 Laboratory Analyses and Quality Control
Pace Analytical Services, Inc. of Huntersville, North Carolina, received the August 2020 groundwater
samples under chain -of -custody control within required hold times and properly preserved. The
groundwater samples from monitoring wells MW-1R, MW-2R, and MW-3R were analyzed for the NC
Appendix I list of constituents plus tin (current Appendix II detected constituent) and 1,4-dioxane.
Groundwater samples from monitoring wells MW-2R and MW-3R were also analyzed for MNA
parameters. Additionally, groundwater from monitoring well NES-1 was analyzed for benzene,
1,4-dioxane, cobalt, and vanadium as constituents of concern. The groundwater samples from
monitoring wells MW-4, MW-5, and MW-6 were analyzed for the NC Appendix I list of constituents
plus 1,4-dioxane.
In addition to samples collected for compliance monitoring at the Butner Landfill, LaBella personnel
collected a Field Blank for the August 2020 Sampling Event as part of the Quality Control/Quality
Assurance program. The Field Blank was analyzed for the NC Appendix I constituents plus
1,4-dioxane and tin (current Appendix II detected constituent). Also, a Trip Blank that was prepared
August 2020 Water Quality Monitoring Report
and Corrective Action Evaluation Report
Granville County- Butner Landfill, Permit No. 39-02
LaBella Associates
December 2020
FAI

by the laboratory accompanied the volatile sampling containers to and from the laboratory. The Trip
Blank was analyzed for the NC Appendix I volatile organic compounds plus 1,4-dioxane. The
complete laboratory analytical reports are included in Appendix C.
Upon receipt of the laboratory data package, LaBella personnel reviewed the following data for:
• General typographical errors;
• Correct analyses performed and within method specified hold times;
• Biased data results based on Matrix Spike, Matrix Spike Duplicate, and Laboratory Control
Samples;
• Blank qualified data (B-flags);
• Detections above Groundwater Protection Standards (GPS) as defined in NCSWMR §
.1634(g), which are generally either the Groundwater Standards found in 15A NCAC 2L.0202
(NC2L), the Interim Maximum Allowable Concentrations (IMAC), or a NCDEQ-approved
statistical background value;
• Detections above NC Surface Water Standards established in 15A NCAC 2B (NC2B), NCDEQ
In -Stream Target Values (ISTV), or EPA Nationally Recommended Water Quality Criteria
(NRWQC); and
• Detections that are above historical levels.
The September 30, 2020 resample from MW-3R was analyzed for vinyl chloride only.
The complete laboratory analytical reports and the chains of custody from the August 2020 sampling
event and the September 2020 resampling event are included in Appendix C. The historical
groundwater elevation data are presented in Appendix D. Historical analytical results for
groundwater and surface water are presented in Appendices E and F, respectively.
4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSES
4.1 Analytical Results for Groundwater and Comparisons to Standards
4.1.1 Inorganic Analyses
The following inorganic constituents were detected at quantified concentrations above the method
reporting limit (MRL) or practical quantitation limit (PQL) in one or more wells during the August 2020
sampling event: barium, cobalt, copper, nickel, vanadium, and tin. Table 3 summarizes all of the
detections from the August 2020 sampling event.
Cobalt was detected in exceedance of the IMAC in MW-2R and MW-5. Vanadium was detected in
exceedance of the IMAC in MW-4 and NES-1. The results for cobalt in MW-2R and MW-5 are
consistent with historical data. Exceedances of groundwater standards from the August 2020
Sampling Event are summarized in Table 4.
No other inorganic constituents were detected above their NC2L/IMAC during the August 2020
sampling event. The laboratory analytical reports and the chains of custody are included in Appendix
C. Complete historical analytical results for inorganic constituents are included in Appendix E.
August 2020 Water Quality Monitoring Report
and Corrective Action Evaluation Report
Granville County- Butner Landfill, Permit No. 39-02
LaBella Associates
December 2020
5

4.1.2 Organic Analyses
Benzene, chlorobenzene, 1,2-dichlorobenzene, 1,4-dichlorobenzene, chloroethane, vinyl chloride,
and 1,4-dioxane were detected in one or more monitoring wells at quantified concentrations above
the method reportable limit (MRL) or practical quantitation limit (PQL) during the August 2020
sampling event. Table 3 summarizes all of the detections from the August 2020 Sampling Event.
These results are consistent with historical data as shown in Appendix E.
Benzene was detected above the NC2L Standard in MW-2R. The benzene in MW-2R is consistent
with historical data and has been addressed in the ACM, approved in June 2013, and the CAP,
approved in June 2014. Concentrations of 1,4-dioxane in exceedance of its NC2L standard were
reported in monitoring wells MW-2R, MW-31R, and MW-4, and 1,4-dioxane has been added as a
constituent of concern (COC).
Vinyl Chloride was initially detected in exceedance of the NC2L Standard in MW-3R; however, it was
not detected in the September 30, 2020, resampling event. Since the initial exceedance was
refuted by resampling, vinyl chloride will not be added to the COC list. Exceedances of groundwater
standards from the August 2020 Sampling Event are summarized in Table 4.
No other organic constituents were detected above their GPS during the August 2020 sampling
event. The laboratory analytical reports and the chains of custody are included in Appendix C.
Historical analytical results for organic constituents are presented in Appendix E.
4.2 Statistical Analyses
4.2.1 Statistical Methods
Monitoring well MW-1R is designated as the up -gradient background well for the facility. Data from
MW-1R between September 1994 and August 2020 have been used to determine interwell
statistical background concentrations for constituents detected at the facility.
The background data are evaluated using the Shapiro-Francia Test of Normality, Parametric
Prediction Limits, Parametric Tolerance Intervals, Aitchison's Adjustment, Non -Parametric Prediction
Limits, and Poisson Prediction Limits, as appropriate. Background data, tests for normality, outliers,
Aitchison's adjustment, tolerance interval, or prediction limits are used, as appropriate based on the
background data. The statistical test by which downgradient data are compared to facility
background data is based upon the nature of the data and the number of data values that are less
than the laboratory limit of detection. All statistical tests are evaluated at the 0.05 level of
significance, 95% confidence level, and are conducted as one -tailed tests. The data are evaluated to
determine the appropriate procedure for calculation of the background value for each parameter.
4.2.2 Results of Statistical Analyses
No statistical analyses were required or performed for this event.
4.3 Analytical Results for Surface Water and Comparisons to Standards
Surface water points SW-1 and SW-2 were not sampled during the August 2020 sampling event due
to insufficient flow.
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5.0 HYDROGEOLOGICAL CONDITIONS
Groundwater in the saprolite feeds the fractures in the bedrock and discharges into creeks northeast
of the landfill. Groundwater flow direction at deeper levels within the fractured bedrock is controlled
by fractures.
Depth to groundwater was measured in the compliance monitoring wells at the site prior to purging.
The groundwater elevations were calculated relative to the surveyed measuring point (top of casing)
for each monitoring well. Table 1 presents the groundwater elevation data obtained on August 27,
2020. A groundwater surface contour map, developed with static water level data obtained on
August 27, 2020, is presented as Drawing 1. The static water elevations depict groundwater flow to
the southeast. Historical groundwater elevations are summarized in Appendix D.
5.1 Horizontal Gradient and Flow
Horizontal groundwater gradients along a representative flow path was estimated from the August
2020 groundwater contours shown on Drawing 1 and are summarized in Table 5. The average
horizontal hydraulic gradient (i) across the site was approximately 0.048.
Linear groundwater flow velocities were computed using the modified Darcy equation:
Where:
V=K►/ne
V = average linear velocity (feet/year),
K = hydraulic conductivity (feet/day),
i = horizontal hydraulic gradient, and
ne = effective porosity.
The average of hydraulic conductivities (K = 2.18x10-05 cm/sec = 6.18x10-02 feet/day) from single
well aquifer test commonly known as slug -tests conducted in 1994 (GAI, 1994) was used in these
calculations. The average effective porosity (ne = 18%) based on 90% of reported total porosity for
soils (GAI, 1994). Although the saprolite and bedrock are hydraulically connected, the effective
porosity generally decreases with depth into the underlying fractured bedrock. Groundwater flow
direction beneath the landfill is predominantly to the south and southeast. The calculated flow
velocity was 6.0 feet/year.
Because of our conservative estimate of effective porosity, actual groundwater velocities may be
significantly less than the calculated values. Also, the modified Darcy equation makes the
simplifying assumptions of a homogeneous and isotropic aquifer, which may not be accurate for this
site.
5.2 Vertical Gradients
Monitoring wells MW-2R and MW-3R are a pair of wells set 20 feet apart with different screened
intervals. MW-2R is screened from 1.5-16.5 feet below ground surface (ft-bgs), and MW-3R is
screened from 23.65-33.65 ft-bgs, giving a vertical distance between screen midpoints of 19.65
feet. The groundwater elevation is typically higher in MW-2R than in MW 3R, indicating a downward
vertical hydraulic gradient. The August 27, 2020 water level measurements indicated a groundwater
elevation of 329.18 feet above mean sea level (ft-amsl) in MW-2R, and 328.55 ft-amsl in MW-3R.
This gives us a calculated downward gradient of 0.032 feet/foot between these two wells, indicating
a weak downward component to groundwater flow. This indicates that during dry periods, the creek
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downgradient of MW-2R and MW-3R may be a losing steam rather than a gaining stream, which is
likely why the creek was dry during the August 2020 sampling event.
6.0 CONCLUSIONS FOR AUGUST 2020 WATER QUALITY MONITORING REPORT
The groundwater flow regime is consistent with previous events and the groundwater monitoring
network remains adequate to monitor the site.
Benzene was detected above the NC21- in MW-2R during the August 2020 sampling event. Review
of MNA parameter data, plume stability, and benzene trends indicate that the selected remedies of
natural attenuation and phytoremediation are adequately controlling the plume.
Analyte 1,4-dioxane was detected above the NC21- standard in MW-2R, MW-3R, and MW-4.
1,4-Dioxane has been added to the COC list.
Cobalt was detected in MW-2R and MW-5 above its corresponding IMAC. This exceedance is
consistent with historical detections. Cobalt has been added to the COC list.
Vanadium was detected above the IMAC in MW-4 and NES-1. The exceedance in MW-4 is consistent
with historical detections and vanadium was added to the COC list. NES-1 was sampled for
vanadium during the August 2020 event for the first time since 2014 and was found in exceedance
of the standard. An Alternate Source Demonstration (ASD) to determine the statistical background
for vanadium is recommended.
The facility will remain in Assessment Monitoring and Corrective Action. The next semiannual
sampling event is tentatively scheduled for February 2021.
7.0 2020 CORRECTIVE ACTION EVALUATION REPORT (CAER)
7.1 Contaminant Distribution
There are currently four constituents of concern (COCs) at the Butner Landfill: benzene, 1,4-dioxane,
cobalt, and vanadium. Table 4 presents the most recent (August 2020) exceedances of
groundwater protection standards at the facility. Note that vinyl chloride was initially detected in
exceedance of the GPS in MW-2R during the August 2020 event; however, this exceedance was
refuted by a resampling event conducted on September 30, 2020. Appendices E and F present the
historical detections of constituents in groundwater and surface water, respectively.
Based on recent groundwater sampling at the facility, there appears to be one primary area of
concern (AOC) for the Butner Landfill, which is located hydraulically downgradient of the waste
disposal area in the vicinity of MW-2R, MW-3R, and MW-4. Drawings 2, 4, 6, and 8 present
isoconcentration maps for benzene, 1,4-dioxane, cobalt, and vanadium, respectively, based on the
August 2020 sampling event data. Drawings 3, 5, 7, and 9 present two roughly orthogonal cross -
sections showing the benzene, 1,4-dioxane, cobalt, and vanadium plumes, respectively, based on
the August 2020 sampling event data.
The plume for benzene is constrained to the vicinity of MW-2R and MW-3R, which is consistent with
previous reports and there has been no significant change since the last CAER (2015). The plume
for 1,4-dioxane is primarily around MW-2R and MW-3R; but extends up to MW-4. There appear to be
two plumes for cobalt, with the highest concertations around MW-5 and significantly lower
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concertation in MW-21R. The plume for vanadium is concentrated around MW-4; however, it extends
to NES-1.
MW-5, MW-2R, and NES-1 are screened in the transition zone between saprolite and fractured
bedrock while MW-4 and MW-3R are screened entirely in the fractured bedrock (see Appendix A).
This could explain the apparent separation between the cobalt plumes around MW-5 and MW-2R, in
that the plume may be continuous in the saprolite but not extend into bedrock. The high
concentration of cobalt in MW-5, which is cross gradient from the landfill, indicates either significant
transverse dispersivity or a natural geologic source near MW-5. For the vanadium plum, the fact
that its concentration is highest in MW-4and non -detect in MW-21R or MW-3R, where the highest VOC
concentrations are, suggests a natural geologic source. Also, the fact that it also appears at a lower
concentration in NES-1, which is across a hydrologic divide from MW-4, further supports a varying
geologic source.
The downgradient extent of the contaminant plumes are well constrained by well NES-1, with the
exception of vanadium. Benzene, 1,4-dioxane, and cobalt were all below the detection limit in NES-1
in the August 2020 results. Vanadium was detected in NES-1 at 6.8 pg/L in NES-1, which is
significantly less than the concentration at MW-4 (21.1 pg/L) but is still above the current IMAC for
vanadium (0.3 pg/L); however, a new NCH standard of 7.0 pg/L has been proposed for vanadium
which is likely to become effective in the near future. Also, we recommend preparation of an
Alternate Source Demonstration (ASD) to establish a statistical background value for vanadium that
may be used to establish a background -based GPS.
The creek, an unnamed tributary of Picture Creek which runs along the south side of the landfill,
between MW-21R, MW-31R, and MW-41R and NES-1, is generally considered a groundwater discharge
feature and thus is expected to provide a hydrologic barrier to plume migration; however, during dry
periods, the creek may be a losing stream and therefore a less effective hydraulic barrier.
Surface water sampling points SW-1 and SW-2 are located on the creek respectively upstream and
downstream of the landfill; however, both points were dry during the August 2020 sampling event,
and so could not be sampled. During the February 2020 sampling event, neither benzene nor cobalt
were detected in either SW-1 or SW-2. 1,4-Dioxane was not detected in SW-1, but was detected as
an estimated concentration of 1.2 pg/L in SW-2 during the February 2020 sampling event, below
both the NC2L and the ISTV. Vanadium was detected at an estimated concentration of 4.5 pg/L in
SW-1 and at 5.0 pg/L in SW-2 during the February 2020 event. The fact that vanadium was
detected at similar concentrations both upstream and downstream of the landfill supports the
contention that it is naturally occurring.
The vertical extent of the contaminant plumes are generally constrained by the results from MW-31R,
which is screened from 15-30 ft-bgs, deeper than MW-2R, which is screed from 5-15 ft-bgs.
Benzene and cobalt, which were in exceedance of the GPS in MW-2R were not detected in
exceedance of the GPS in MW-3R during the August 2020 sampling event. 1,4-Dioxane was in
exceedance in MW-3R, but at less than half the concentration detected in MW-2R in the August
2020 event. This could be due to the fact that 1,4-dioxane is slightly heavier than water, so it is
more likely to sink in the aquifer than benzene. Vanadium was not detected in either MW-2R or
MW-3R during the August 2020 event.
7.2 Contaminant Trends
Trend charts for contaminant concentrations versus time for benzene, 1,4-dioxane, cobalt, and
vanadium are presented in Charts 1, 4, 3, and 4, respectively. Each chart presents the data for all
wells where the respective constituent has been consistently detected over the time period where we
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have historic detections. Chart 4 is presented in two versions (Chart 4a and Chart 4b) with different
scales to allow for clearer presentation of the data.
Chart 1 shows that benzene has consistently been detected in MW-2R between 1.0 and 2.0 pg/L
since August 2006. If one considers only data since August 2018, there is an apparent increasing
trend over the short term; however, prior to August 2018, there was an apparent downward trend,
and the over-all trend since August 2006 is still slightly downward. Benzene in MW-3R and MW-4
have remained consistently below the NC2L standard of 1.0 pg/L.
1,4-Dioxane has only been analyzed since August 2018, so there is limited data for examining long-
term trends. As shown in Chart 2, 1,4-dioxane in MW-2R has fluctuated between 88 and 132 pg/L.
1,4-Dioxane in MW-3R and MW-4 have ranged from 36 to 53 pg/L, while 1,4-dioxane in MW-5 has
ranged from non -detect to 3.1 pg/L. There are no clear trends.
Chart 3 shows that cobalt in MW-5 has fluctuated greatly since February 1995, from non -detect to
251 pg/L, with no clear long-term trend. Cobalt in MW-21R has been both lower and more consistent,
ranging from 4.7 to 38 pg/L, with perhaps a slight downward trend.
Chart 4a shows that between February 1995 and February 1999, vanadium concentrations in
MW-11R (background well) and MW-21R fluctuated widely between non -detect and 560 pg/L. Between
July 1999 and June 2006, there were no detections of vanadium in any of the wells. Between
December 2006 and August 2020, vanadium in MW-4 ranged from 6.3 to 22.1 pg/L, while
vanadium in the other wells ranged from non -detect to 11.6 pg/L, with most results below 5 pg/L
(Chart 4b). There are no clear long-term trends in vanadium concentrations; although in the short
term (since December 2006), there may be a slight upward trend in MW-4.
7.3 Physical and Chemical Changes in Aquifer Conditions
Data obtained from the August 2020 semiannual sampling event, include groundwater elevation and
flow (Tables 1 and 5), groundwater field parameters (Table 2), and MNA parameters (Table 6).
Historical groundwater elevations are presented in Appendix D, historical constituents in
groundwater are presented in Appendix E, historical constituents in surface water are presented in
Appendix F, and historical MINA parameters are presented in Appendix G.
Constituent concentrations have been evaluated with regard to the physical and chemical conditions
in the uppermost aquifer at the site. Temperature, pH, specific conductance, oxidation-reduction
potential (ORP), turbidity, dissolved oxygen (DO), dissolved carbon dioxide, and ferrous iron fluctuate
within normal ranges for groundwater in saprolite and partly weathered bedrock of the Piedmont
physiographic province; however, we have observed some significant differences between the
upgradient and downgradient wells, which we attribute primarily to the presence of the contaminant
plume. In general, there has been little change over time in most of the parameters, indicating
stable conditions in the aquifer; however, there are some exceptions. Charts 5, 6, 7, and 8 show
results, respectively, for pH, conductivity, ORP, and DO versus time for all monitoring wells from May
2013 to present.
Chart 5 presents groundwater pH versus time. There have been a few anomalous readings, but
overall the pH has remained fairly stable between 5.5 and 7.5 for all of the wells. There may be a
slight overall increase in pH comparing the data after 2017 to the data before 2017; however, the
difference is minor (average 2013-2016 = 6.46; average 2017-2020 = 6.64). There is no clear,
consistent difference between pH in upgradient wells, downgradient wells inside the plume, and
downgradient wells outside the plume.
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Chart 6 presents the conductivity of the groundwater versus time. The conductivities in each well
are very consistent over time; however, there is a clear difference between wells inside the plume
and wells outside the plume. The conductivities in wells MW-1R (the background well) and NES-1
(the sentinel well) ranges from 68 to 231 pS/cm. The conductivities in MW-2R, MW-3R, and MW-4,
which are inside the plume, are much higher, ranging from 996 to 1974 pS/cm. The conductivities
for wells MW-5 and MW-6, which are downgradient wells but outside the main plume, are in
between, ranging from 195 to 870 pS/cm. This is consistent with active biodegradation occurring
within the plume.
Chart 7 shows ORP versus time. ORP in MW-2R and MW-3R are consistently lower than the ORP in
MW-1R. The results for MW-2R and MW-3R have been fairly consistent over time; however, ORP in
MW-1R shows an increasing trend over the last three years (February 2018 - August 2020). ORP
data for the other wells is less complete; however, MW-4, MW-5, MW-6, and NES-1 all appear to
show a similar increasing trend overt the last 2-3 years.
Chart 8 presents DO versus time. The DO data are less consistent than other parameters, showing
significant fluctuations over time with no clear long-term trends. DO in MW-1R has been mostly
higher than other wells, but has been low in some recent events, most notably August 2020. There
appear to be downward trends over the last three years (February 2018 - August 2020) in MW-2R
and MW-3R, while there may be corresponding upward trends over the last 2-3 years in MW-4,
MW-5, and MW-6.
7.4 Physical and Chemical Changes in Plume Characteristics
Data obtained from the compliance and sentinel well (NES-1) is used annually to re-evaluate the risk
posed by the contaminant plume. Evaluation of the analytical results from the sentinel well will be
used to determine the need for additional sentinel wells or for implementation of an alternative
remedy.
Although there have been three additional constituents of concern added since the 2015 CAER,
these new COCs do not necessarily represent significant changes in the concentrations of these
constituents in the groundwater at the facility; rather, they reflect changes in NCDEQ policy.
1,4-Dioxane was not a required analytical parameter until it was added by NCDEQ in a Memo dated
May 29, 2018; therefore, it was first detected and added as a COC after the August 2018 sampling
event.
Cobalt has been detected above its IMAC consistently in MW-5 and periodically in MW-2R since at
least 2011; however, it was generally not above its site -specific background of 130 pg/L as
calculated at the time, so it was not considered an exceedance per NCSWMR rule .1634.(g) as it was
typically applied. In July 2017, the NCDEQ issued a new guidance for Alternate Source
Demonstrations (ASDs) with new requirements for statistical background calculations, including the
requirement to use only low -turbidity data. This resulted in a much lower background value and
Cobalt was added as a COC after the August 2017 sampling event.
Vanadium was detected in MW-4 between July 2007 and August 2018 at estimated values below
the NCDEQ-established Solid Waste Section Limit of 25 pg/L. Those estimated values were similar
in magnitude to the more recent quantified values; however, concentrations reported as estimated
values below the reporting limit are not considered exceedances even if the estimated values are
above the NC2L or IMAC. In the May 2018 Memo from NCDEQ, Solid Waste Section Limits were
eliminated, effectively reducing the reporting limits for many constituents, including cobalt and
vanadium. The new, lower reporting limits resulted in new exceedances for vanadium in MW-4 and
vanadium was added as a COC after the February 2019 sampling event.
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As shown in the trend charts (Charts 1-4), the concentrations of all four COCs have remained stable
over the last several years and there have been no significant changes in the associated
contaminant plumes. Also, the plume for benzene (Drawings 2 and 3), which was the only COC in
2015, has not changed significantly since the 2015 CAER.
7.5 Refining the Site Conceptual Model
Any new information that comes to the attention of the facility, either from the data collected on site
or other sources, which impact the site conceptual model will be reported and evaluated. This
includes data on site or regional geology, hydrogeology, or other aspects of the site conceptual
model. The site conceptual model will be refined in response to the new information as needed and
appropriate.
The landfill is bound to the south by an unnamed tributary of the Picture Creek. The landfill is bound
to the west by a man-made drainage ditch that runs along the side of Butner Road. All of the
drainages on the site eventually flow into the unnamed tributary of the Picture Creek.
Historically, two surface water points [SW-1(upgradient) and SW-2 (downgradient)] have been
sampled semiannually in conjunction with the groundwater sampling at the Butner Landfill. Both
SW-1 and SW-2 were dry during the August 2020 sampling event; however, historical surface water
data indicate that groundwater discharge into the creek has not impacted the surface water as there
have been no exceedances of NC2B surface water standards or ISTVs; therefore, the surface water
does not constitute a sensitive receptor pathway risk. If the plume migrated to impact the surface
water, dilution would quickly reduce the concentrations to below detectable levels.
Flora and fauna on or above the ground surface are at minimal risk, because there have been no
confirmed exceedances of surface water standards in the downstream surface water samples.
Organisms suspected to be living in the subsurface at the site are at potential risk; however, soil
microorganisms are known to use the organic acids and by-products of the degradation process of
the groundwater plumes as a food source; therefore, the potential risk to the environment from the
impacted groundwater is considered to be low. LaBella conducted a tree survey in July 2020 and no
evidence of distressed vegetation or obvious impacts to wildlife were observed as a result of
exposure to the contaminant plume.
As noted above, the benzene plume remains unchanged and the concentrations of all COCs are
stable. There is no data indicating a need to modify the site conceptual model at this time.
7.6 Evaluation of the Impact of Corrective Actions
7.6.1 Contaminant Levels
Benzene
Chart 1 shows benzene concentrations versus time for all the facility monitoring wells between June
2006 and August 2020. In June 2006 and earlier, there were no reported detections of benzene;
however, that is likely due to the fact the prior to December 2006, there was a higher reporting limit
and no estimated results below the reporting limit were reported.
Since December 2006, excluding anomalous non -detect values, the concentrations of benzene in
MW-2R have averaged 1.5 pg/L with a standard deviation of ±0.25. The benzene concentrations in
MW-3R have averaged 0.57 pg/L with a standard deviation of ±0.082. The benzene concentrations
in MW-4 have averaged 0.32 pg/L with a standard deviation of ±0.057. The data since December
2006 show no obvious trends in benzene concentrations in any of the wells. This indicates that the
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plume is stable and natural attenuation and phytoremediation are reducing the benzene
concentration at a rate roughly equal to the rate benzene is being released from the landfill.
1,4-Dioxane
Chart 2 shows 1,4-dioxane concentrations versus time for all the facility monitoring wells between
August 2018 and August 2020. Concentrations of 1,4-dioxane in MW-2R have averaged 106 pg/L
with a standard deviation of ±50. The 1,4-dioxane concentrations in MW-3R have averaged 49.8
pg/L with a standard deviation of ±3.3. The 1,4-dioxane concentrations in MW-4 have averaged
39.7 pg/L with a standard deviation of ±6.4. The 1,4-dioxane concentrations in MW-5 have
averaged 2.7 pg/L with a standard deviation of ±0.61. The data show no obvious trends in 1,4-
dioxane concentrations in any of the wells. This indicates that the plume is stable and natural
attenuation and phytoremediation are reducing the 1,4-dioxane concentration at a rate roughly
equal to the rate 1,4-dioxane is being released from the landfill.
Cobalt
Chart 3 shows cobalt concentrations versus time for all the facility monitoring wells between
February 1995 and August 2020. The cobalt concentrations in MW-5 have averaged 74.8 pg/L with
a standard deviation of ±68.2. Concentrations of cobalt in MW-2R have averaged 14.0 pg/L with a
standard deviation of ±1.6. The data show no obvious trends in cobalt concentrations in either well.
This indicates that the plume is stable.
Vanadium
Chart 4 shows vanadium concentrations versus time for all the facility monitoring wells between
September 1994 and August 2020. The vanadium concentrations in MW-4 have averaged 18.3
pg/L with a standard deviation of ±8.6. Concentrations of vanadium in NES-1 have averaged 6.4
pg/L with a standard deviation of ±2.3. Vanadium has been detected in other wells, including the
background well (MW-113); however, there have been no GPS exceedances in other wells in recent
years. The data show no obvious trends in vanadium concentrations in either well. This indicates
that the plume is stable.
7.6.2 Evaluation of MNA Parameters
Baseline sampling data for MNA parameters at this facility was collected between May 2013 and
August 2014 for wells MW-1R, MW-2R, MW-3R, and NES-1. The baseline MNA data were evaluated
in the first CAER dated December 2015. Based on the 2015 CAER, the NCDEQ reduced the required
frequency for some MNA parameters. MNA parameters are analyzed form MW-2R and MW-3R
semiannually; however, they are only required annually for MW-1R and NES-1. The current list of
MNA parameters included the following:
MNA Field Parameters: Temperature, pH, specific conductance, oxidation-reduction
potential, turbidity, dissolved oxygen, and ferrous iron. Dissolved carbon dioxide is tested
during both events every third year (next in 2022).
MNA Laboratory Parameters: Dissolved methane, alkalinity, sulfate, nitrate, chloride,
biological oxygen demand (BOD), chemical oxygen demand (COD), and total organic carbon
(TOC). Dissolved hydrogen, volatile fatty acids, sulfide, ethane, and ethene are analyzed
during both events every third year (next in 2022).
Table 6 summarizes all of the MNA parameter data for the August 2020 sampling event and
Appendix G presents historical MNA data for the facility. Following are discussion of the results from
each MNA parameter as they related to evaluation of MNA as the remedy for this facility.
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Standard MNA Parameters:
Temperature of groundwater is used to help assess the representativeness of water samples, and to
correct temperature sensitive parameters/measuring devices. Microorganisms are active over a
wide temperature range, although some may become more active with increasing temperature.
Temperature measurements for groundwater samples have fluctuated between 11.1°C and 21.1°C,
with some seasonal variation.
pH is an indication of the suitability of environment to support wide range of microbial species.
Activity tends to be reduced outside of pH range of 5 to 9, and anaerobic microorganisms are
typically more sensitive to pH extremes. pH is also used to help assess the representativeness of
the water sample taken during purging of wells. Nearly all pH measurements of groundwater at the
site have been within the 5-9 range, and about 80% have been between 6.0 and 7.5. Chart 5
presents historical pH data versus time for all wells at the facility.
Conductivity or specific conductance of groundwater is a measure of its ability to conduct electricity.
The standard unit of conductivity is micro -Siemens per centimeter (pS/cm). Conductivity
measurements are used in environmental applications as a way of measuring the ionic content in
water. Conductivity in facility wells has been fairly consistent with time for each well. The
conductivity in MW-2R, MW 3R, and MW-4 (wells within the plume) has ranged from 996 to 2013
pS/cm. The conductivity in MW 1R (background well) and NES-1(sentinel well) ranged from 50.0 to
231 pS/cm. The higher conductivity values in the area of the plume may reflect higher dissolved
ions in the groundwater either due to the presence of contaminants or due to biological activity, or
both. Chart 6 presents historical conductivity data versus time for all wells at the facility.
Oxidation -Reduction Potential (ORP), also referred at as redox potential or Eh, measures whether the
environment is reducing or oxidizing. Ranges from 0 to +500 mV indicate oxidizing (aerobic)
environments, and ranges from -500 mV to 0 indicate reducing (anaerobic) environments. The ORP
measurements at the MW-2R have fluctuated between -96.3 and +33.4 mV and ORP in MW-3R has
ranged from -68.8 to 132.2 mV, indicating a weakly aerobic to weakly anaerobic environment within
the plume or a transition from aerobic to anaerobic conditions, which suggests microbial activity and
biodegradation. ORP measurements in the background well, MW-1R, and the sentinel well, NES-1,
have been entirely in the aerobic range, between 28.4 and 336.5 mV. The ORP data shows a
fluctuating anaerobic/aerobic environment around MW-2R and a clear difference between wells
inside and outside of the plume. Biological activity associated with natural attenuation is expected
to reduce the ORP. Chart 7 presents historical ORP data versus time for all wells at the facility.
Dissolved Oxygen (DO) is an indicator of aerobic versus anaerobic environments. The availability of
oxygen is essential for aerobic microbes to metabolize organic contaminants, but DO > 5 mg/L is
detrimental to the ability of anaerobic microbes to metabolize organic contaminants. Groundwater
at all wells showed fluctuations in DO concentrations over time, ranging from 0.26 to 8.36 mg/L. DO
in MW-1R has been mostly higher than other wells, but has been low in some recent events, most
notably August 2020. There appear to be downward trends over the last three years (February 2018
to August 2020) in MW-2R and MW-3R, while there may be corresponding upward trends over the
last 2-3 years in MW-4, MW-5, and MW-6. This may indicate a transition from aerobic to anaerobic
conditions, which suggests microbial activity and biodegradation. The key observation is that there
is sufficient oxygen in the plume area to facilitate aerobic biodegradation of benzene. Chart 8
presents historical DO data versus time for all wells at the facility.
Chloride is an ultimate daughter product of reductive dehalogenation, and is usually an indicator of
anaerobic degradation of chlorinated hydrocarbons; however, chloride production has been
documented to occur also in association with biodegradation of benzene. Chloride concentrations
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within the plume in MW-2R and MW-3R have consistently been a magnitude greater than in
background well MW-1R or the sentinel well, NES-1. Concentrations have ranged from 203-318
mg/L in MW-2R and 144-297 in MW-3R; but concentrations have only been 3.50-4.96 mg/L in
MW-1R and 2.52-7.90 mg/L in NES-1. This is a strong indication that natural attenuation is
occurring.
Nitrate and Sulfate compounds can be used as electron acceptors by reducing bacteria. Changes in
concentrations may provide evidence of biological activity. At high concentrations, they may interfere
with reductive pathways. In general, one would expect concentrations of nitrate and sulfate to
decrease if active biodegradation is occurring. Concentrations of nitrate and sulfate have been low
across the site and they have been either estimated or non -detected in MW 2R and MW 3R. Nitrate
and sulfate were both non -detect in MW-1R, MW-2R, and MW-3R during the August 2020 sampling
event. Interestingly, nitrate and sulfate have generally been higher in the sentinel well, NES-1, than
in the other wells. The low background concentrations make it difficult to tell whether there is a
significant decrease in the area of the plume. The low levels of nitrate and sulfate may be
associated to the presence of other electron acceptors, because conditions at the site are more
aerobic so these compounds are not used as much as oxygen.
Extended MNA Parameters:
Dissolved Hydrogen (DH) concentrations in anaerobic environments can be correlated with types of
anaerobic activities. DH may be the limiting factor for complete dechlorination of chlorinated
hydrocarbons. A concentration of >1 nM in considered necessary for effective reductive
dehalogenation. Concentrations of DH have little impact on aerobic degradation, as is expected for
benzene. In general, the measured DH concentrations have been greater than 1.0 nM in most wells,
ranging from 0.4 to 7.4 nM. DH concentrations have been approximately the same in MW-2R and
MW-3R as in background well MW-1R or sentinel well NES-1. Since there are no chlorinated
hydrocarbon COCs, the relevance of these data is limited.
Sulfide presence may provide evidence of sulfate reduction; however, it may not be detected even if
sulfate -reducing bacteria are active because it can react with various oxygenated chemical species
and metals. Sulfide has not been detected in any wells at this site except for one detection in NES-1
in August 2015 and one estimated detection in MW-2R in February 2020.
Alkalinity level increase may be indicative of carbon dioxide production and mineralization of organic
compounds. Alkalinity has ranged from 744 to 856 mg/L in MW-2R and from 653 to 754 mg/L in
MW 3R, and has been consistently higher than in MW-1R, which ranged from 37.0 to 62.0 or NES-1
witch has ranged from 7.02 to 14.5 mg/L (except for one anomalous reading of 190 mg/L). This is a
strong sign that natural attenuation is occurring.
Total Organic Carbon (TOC) in significant concentrations indicates the availability of general growth
substrates for microorganisms. One would expect TOC to be higher inside the plume than outside of
it. TOC has ranged from 25.4 to 54.3 mg/L in MW-2R (except for one anomalous reading of 229
mg/L) and from 7.46 to 30.0 mg/L in MW 3R, and has been consistently higher than in MW-1R,
which ranged from non -detect to 2.9 mg/L. This indicates that there is sufficient organic matter in
the plume area to sustain biological activity.
BTEX (the sum of benzene, toluene, ethylbenzene, and xylenes) in significant concentrations indicate
the availability of general growth substrates for microorganisms. There have been no detections of
toluene, ethylbenzene, or xylenes in any well in the last 2 years (four sampling events), so the BTEX
is simply the benzene concentration, which is our COC.
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Biological Oxygen Demand (BOD) is based on the activities of bacteria and aerobic microorganisms
which feed on organic matter in presence of oxygen. The result of a BOD test indicates the amount
of water -dissolved oxygen (mg/L) consumed by microbes. In general, the higher the BOD, the higher
the amount of pollution in the test sample. Typical values for pristine rivers will have BOD below 1
mg/L. Moderately polluted rivers may have a BOD value in the range of 2 to 8 mg/L. The BOD
values in the background well, MW-1R, range from non -detect (ND) to 2.55 mg/L; however, they
have been all ND since February 2016. In MW-2R, the BOD values ranged from ND to 83.4 mg/L;
and in MW-3R, the BOD values ranged from ND to 3.56 mg/L. The BOD values in the sentinel well,
NES-1, ranged from ND to 2.0 mg/L. This is an indication of heightened biological activity within the
plume, which implies significant biodegradation is occurring.
Chemical Oxygen Demand (COD) tells how much oxygen is needed to fully oxidize compounds
containing carbon, hydrogen or both. As an indicator of the amount of organic pollutants found in
groundwater, COD indicates the mass of oxygen consumed per liter (mg/L). The COD values in the
background well, MW-1R, ranged from ND to 25.0 mg/L. In MW-2R, the values ranged from 101 to
295 mg/L; and in MW-3R, they ranged from ND to 756 mg/L. The NES-1 COD values ranged from
ND to 50 mg,/L. This is an indication of heightened biological activity within the plume, which implies
significant biodegradation of the COC is occurring.
Dissolved Methane, Ethane, Ethene in groundwater can provide evidence of dechlorination of
chlorinated hydrocarbons; however, methane may also indicate activity of methanogenic bacteria.
Methane produced by methanogenic bacteria decomposing organic waste is common and expected
in an MSW landfill. Dissolved methane has been detected consistently in MW-2R and MW-3R, but is
most likely generated directly from the landfill waste rather than by degradation of groundwater
contaminants. The concentrations of methane in MW-2R and MW-3R have been significantly higher
than in the background well MW-1R or the sentinel well NES-1. The higher methane in MW-2R and
MW-3R may indicate impact by landfill gas. Low concentrations of ethane and ethene have been
detected in groundwater samples sporadically, but have usually been ND.
Volatile Fatt Ay cids (VFAs) include pyruvic acid, lactic acid, acetic acid, propionic acid, and butyric
acid. Analysis of VFAs can provide insight into the types of microbial activity that are occurring. VFAs
can also serve as electron donors. A few VFAs have been detected sporadically, and they have not
been consistent enough to evaluate natural attenuation processes at the facility. During the August
2020 sampling event, total VFAs in MW-2R were 49.7 mg/L, while total VFAs in MW-1R, MW-3R, and
NES-1 were 5.43 mg/L, 5.40 mg/L, and 5.66 mg/L, respectively. This higher concentration in
MW-2R may indicate elevated microbial activity; however, these results were unusual compared to
the historical data.
Carbon Dioxide (CO2) is an ultimate oxidative daughter product of the biodegradation of
hydrocarbons; however, carbon dioxide is also a principal constituent of landfill gas, and when
landfill gas is in contact with the water table CO2 will partition into the groundwater. CO2
concentrations have been consistently higher in MW-2R and MW-3R than in MW-1R or NES-1. CO2 it
the background well, MW-1R, has ranged from 25 to 75 mg/L; and in the NES-1, CO2 has ranged
from 20 to 75 mg/L. CO2 in the wells within the plume, MW-2R and MW-3R, has ranged from 110 to
475 mg/L and from 75 to 250 mg/L, respectively. The higher CO2 in MW-2R and MW-3R may also
be indicative of impact by landfill gas.
Ferrous Iron (Fe2+) (the soluble reduced form of iron) is a nutrient and indicates the activity of iron
reducing bacteria. Fe2+ is used as electron acceptor. Fe2+ has been detected consistently in the
MW-2R in the range of 1.0 to 7.2 mg/L and in MW-3R from 0.2 to 1.3 mg/L, but has not been
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detected in the background well MW-1R and only once in NES-1(0.2 mg/L). These data indicate
that biodegradation is occurring within the plume.
7.6.3 Evaluation of Phytoremediation
Phytoremediation is the use of plants to remove, transfer, or stabilize contaminants in soil or
groundwater. Plants may remove contaminants from groundwater either by direct plant uptake and
metabolization or by microbial degradation in the root zone. Contaminants in groundwater can be
removed when plant -produced enzymes break down contaminants that enter the plant during
transpiration (phytodegredation). Another method by which plants can enhance groundwater quality
is by phytoaccumulation, which is the process of uptake and storage of contaminants in the root
systems. Plants may also uptake contaminants and transpire them through the leaves
(phytovolatization). Finally, plants can provide secretions that enhance microbial activity in the root
zone that aid in the breakdown of contaminants (ITRC, 1999). Phytoremediation via direct uptake of
groundwater contaminants has been demonstrated to be a very efficient removal mechanism for
aromatic hydrocarbons, such as those observed at the site.
Generally the octanol-water partition coefficient (log Kow) of organic contaminants must be between
1.0 and 3.5 (moderately hydrophobic organic chemicals) to be susceptible to uptake by plants.
Hydrophobic chemicals (log Kow>3.5) are bound too strongly to roots and soil to be translocated
within the plants. Water-soluble chemicals (log Kow<1.0) are neither sufficiently sorbed to roots nor
actively transported through plant membranes (Briggs, et. al., 1982). The log Kow of benzene is
2.13, within the range to be susceptible to phytoremediation.
Root contact is a primary limitation on phytoremediation applicability. Remediation via plants
requires that the contaminants be in contact with the root zone of the plants. Either the plants must
be able to extend roots to the contaminants, or the contaminated media must be moved to within
range of the plants. Rhizodegradation, which is the breakdown of an organic contaminant in soil
through microbial activity that is enhanced by the presence of the root zone, is the most effective
mode of phytoremediation for petroleum hydrocarbons (US -EPA, 2000).
The groundwater is extremely shallow (1-3 feet, or less) in the vicinity of MW-2R and in most of the
area of the plume, and GPS exceedances of benzene are constrained to approximately the upper 15
feet of the aquifer. This puts most if not all of the plume within reach of the root systems of large
trees, like poplars and sweet gums, and the shallower parts of the plume will be within reach of even
the shallower root systems of grasses and shrubs. Typically, phytoremediation as a remedial
technology includes selection of a plant species, planting the selected species, and possibly
harvesting the plants at some time in the future; however, at this site, we believe that
phytoremediation is already taking place with existing flora and site conditions.
Annual surveys of tree species, health, and maturity already present within the plume area have
been conducted annually through the CAER period and are typically included in the Second
Semiannual Water Quality Monitoring Reports. The eighth annual phytoremediation tree survey for
the Butner Landfill was conducted on July 30, 2020. Drawing 10 presents the results of the 2020
tree survey and a survey log is included in Appendix H. The 2020 tree survey found the flora in the
area of concern to be relatively unchanged since previous surveys, and the trees and other flora are
healthy and flourishing.
The tree survey covered the south side of the landfill between the edge of waste and the creek
(Drawing 10). Some of the areas downgradient of the landfill were logged in 2010 and these areas
are collectively labeled "Area 1" on Drawing 10. The logged areas were reportedly replanted with
pines after logging. At the time of the 2020 tree survey, the impact of logging was still evident;
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however, new growth had progressed well and there were numerous sweet gum and beech saplings
observed, as well as long -leaf pine that could have been from the reported re -planting.
There are still areas of mature trees downgradient of the landfill. Most importantly, the main area of
the plume between MW-2R and the creek was not logged in 2010 and is still well -wooded with many
mature trees. This area is labeled "Area 2" on Drawing 10. The tree survey found that
approximately 70% of the mature trees in Area 2 were American sweet gums (Liquidambar
styraciflua), with about 10% tulip poplars (Liriodendron tulipifera) and 10% blue beech (Carpinus
caroliniana). The remaining 10% included black maple, white cedar, and loblolly pine. Area 3 on
Drawing 10 is another area that was not logged and which contains mature trees. Area 3 contains
approximately 50% tulip poplars, 20% American sweet gum, and 15% each of black maple and
loblolly pine. There were also abundant herbaceous plants observed in Areas 2 and 3.
There were several areas of apparent wetlands observed in the area between the landfill and the
creek at the time of the tree survey. Some apparent wetlands in the logged areas (Area 1) appeared
to be recently developed as a result of water accumulating in ruts and low areas left after the
logging; however, there were also apparent wetland areas observed in Area 2 between MW-2R and
the creek. The apparent wetlands in Area 2 appear to be natural and more mature than those in
Area 1.
The trees and other plants present on site are expected to effectively metabolize and/or transpire
observed groundwater contamination, and rhizodegradation in the root zone is expected to
remediate the groundwater further. Poplars have been well -studied in phytoremediation applications
(Gordon, et al, 1997; Ferro, et al, 1999), and are one of the most commonly recommended trees for
phytoremediation of VOCs, metals, and radionuclides. Sweet gum trees have less documentation;
however, they have also been used successfully in similar phytoremediation applications (Negri and
Hinchman, 2000). Other trees and herbaceous plants in and downgradient of the plume are also
likely to contribute to phytoremediation. Furthermore, wetlands are among the most biologically
active ecosystems, and are considered to have high potential for phytoremediation of VOCs and
other contaminants (Williams, 2002). The presence of wetlands downgradient of the plume is
expected to enhance phytoremediation at this site.
7.6.4 Impacts on Hydraulic Gradients
Based on historic groundwater elevations at this site, the average hydraulic gradient has been 0.05
toward the south and southeast, with horizontal flow velocities of approximately 6 feet per year. The
most recent estimate of hydraulic gradients and groundwater flow velocities are provided in Table 5
of this report and are discussed in Section 5.0. Since there is no pumping or injection associated
with the corrective action at this facility, there is no impact on hydraulic gradients.
7.6.5 Contaminant Removal Efficiencies and Mass of Contaminants Removed
Natural attenuation for benzene was modeled using EPA Bioscreen Version 1.4 (Newell, 1996 &
1997). Bioscreen offers multiple kinetic model options, including no degradation, first -order decay,
and instantaneous reaction. Bioscreen automatically selects the correct source half-life value
depending on which kinetic model is being used.
The First -order Decay model assumes biodegradation starts immediately downgradient of the
source, and that the rate of dissolution is reflected by the concentration of dissolved organics
actually measured in monitoring wells. In other words, the first -order decay model assumes CO
(concentration before biodegradation) is equal to the observed source concentration. Since the
landfill is considered an ongoing source, the First -Order Decay model is the most appropriate for this
site.
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The Instantaneous Reaction model assumes biodegradation is occurring directly in the source zone,
and that the effective source zone concentration CO is equal to the measured concentration in the
source zone plus any "missing" concentration due to biodegradation. For example, if the source zone
concentration in monitoring wells is 5 mg/L, and the biodegradation capacity is 10 mg/L, the
effective source concentration CO is 15 mg/L. In other words, CO is equal to the measured source
concentration plus the biodegradation capacity provided by the electron acceptor concentration. This
means use of the instantaneous reaction assumption will result in higher dissolution rates and
shorter source lifetimes.
Bioscreen was set up to model hydrogeology, dispersion, adsorption, and biodegradation along a
flow line running northeast -southeast direction from the waste unit through MW-2R, surface water
point SW-2 and NES-1. The source is considered the edge of waste. Distances were selected from
the source to MW 2R (140 feet), SW-2 (400 feet), and NES-1(535 feet). The plume is estimated to
be at most approximately 350 feet long and 800 feet wide. The concentration in the source area
(beneath the landfill) was set equal 5.0 pg/L (assuming the source concentration is higher than the
downgradient well). The Bioscreen modeling simulation time was set to 22 years based on the time
since the facility stopped receiving waste (August 1998). Hydrogeology parameters used as input
values were based on the groundwater flow rate calculations of the August 2020 semiannual
sampling event presented in Table 5 of this report.
Bioscreen modeling was performed for benzene with the first -order decay assumption that the total
biodegradation capacity be reduced to account for electron acceptor utilization by other constituents
present in plume. Since no toluene, ethylbenzene and xylenes are present, there was no need to
reduce the amount of oxygen, nitrate, sulfate, iron, and methane to account for utilization of those
electron -receptors by other BTEX constituents. The modeling was found to fit the field data fairly well
assuming a 1st order decay coefficient of 10-2 per year. The input and output of the Bioscreen
modeling are presented in Appendix 1.
The plume and source mass calculations from Bioscreen are summarized below. In the natural
attenuation of the First -order Decay model the biodegradation starts downgradient of the source and
the rate of dissolution is reflected by the concentration of dissolved organics measured in monitoring
well MW-2R. Based on the modeling, approximately .0016 kg of the plume mass (benzene) has
been removed by biodegradation during the modeling period of 22 years.
Plume Parameter: First Order Decay (22 yrs.)
Benzene plume mass if no biodegradation: 0.01614 Kg
Actual benzene plume mass: 0.0146 Kg
Benzene plume mass removed by biodegradation: 0.0016 / 10%
Please note that many assumptions are made in the Bioscreen modeling. These results are based
on the limited data available and professional judgement where detailed data were unavailable;
therefore, these results should only be considered estimates.
7.7 Status of Impacts at the Compliance Boundary
Sentinel well NES-1, adjacent to the facility's property boundary, has not been impacted with any
Appendix I VOCs, including benzene, or 1,4-dioxane. Cobalt has not been detected in exceedance of
its IMAC in NES-1. Vanadium was detected in exceedance of its IMAC in NES-1 during the August
2020 sampling event; however, the concentration is significantly lower than in MW-4, which is the
only other well with an exceedance for vanadium. There have been no exceedances of surface water
standards for any parameters, including the COCs.
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7.8 Off -Site Migration Concerns
Groundwater flow is primarily toward the south-southeast beneath the landfill (Drawing 1). Benzene,
1,4-dioxane, cobalt, and vanadium have been detected in one or more downgradient wells in
exceedance of applicable groundwater protection standards, with the most significant impacts in
MW-2R (Table 4). Well NES-1 is a sentinel well located near the property boundary south of MW-2R.
There have been no detections of benzene or 1,4-dioxane in NES-1, nor have there been any IMAC
exceedances for cobalt in NES-1. Vanadium was detected in exceedance of its IMAC in NES-1 during
the August 2020 sampling event; however, the concentration was below the proposed NC2L
standard for Vanadium, which is likely to become effective in the near future. The current COC
plumes all appear to be stable, with no indication that they are expanding; therefore, there is no
reason to suspect any significant impact beyond the property boundary in the foreseeable future.
The landfill is bordered to the east and southeast by an unnamed tributary to the Picture Creek,
which is classified "C", for waters protected for secondary recreation, aquatic life, and wildlife. This
creek is between the landfill and the downgradient property boundary. To date, there have been no
exceedances of NC2B standards or ISTVs for surface water samples from this creek.
7.9 CONCLUSIONS FOR CAER
7.9.1 Proposed ASD for Vanadium
The only GPS exceedance in sentinel well NES-1 has been vanadium at 6.8 pg/L in August 2020.
The current IMAC for vanadium is 0.3 pg/L; however, a proposed NC2L standard of 7.0 pg/L has
been proposed and is expected to become effective in the near future. Vanadium is a common,
natural element in soil and groundwater in the North Carolina Piedmont and in the Triassic basins
and it has been detected in every well at the facility, including the upgradient background well,
MW-1R. It has also been detected in both upstream and downstream surface water samples. We
recommend preparation of an Alternate Source Demonstration (ASD) to establish a background
value for vanadium in accordance with NC Solid Waste Section Guidelines for Alternate Source
Demonstration Submittals for Solid Waste Management Facilities (NCDEQ, 2017).
7.9.2 Modifications Needed to Selected Remedv
Since the last CAER (December 2015), there have been three constituents added to the COC list for
the facility, including 1,4-dioxane, cobalt, and vanadium; however, we believe the current remedy is
sufficient for all current COCs. The facts that no VOCs, including benzene and 1,4-dioxane, have
been detected in the sentinel well NES-1, the plumes appear to be stable, and evidence from
evaluation of MNA parameters and BIOSCREEN modeling indicate that natural attenuation is
occurring, support the contention that MNA is an adequate remedy for the organic COCs. Also,
phytoremediation is very effective at remediation both organic contaminates and metals, and the
evaluation of phytoremediation at this facility indicates that it remains a viable and effective remedy
for all COCs. No changes to the current remedies are recommended.
7.9.3 Recommendations for MNA Indicator Parameters
Several of the extended MNA parameters described above show limited usefulness in evaluating
natural attenuation at this site. Several of these parameters are important for evaluating anaerobic
degradation of chlorinated hydrocarbons; however, we have no chlorinated hydrocarbons that are
COCs for this facility, so these parameters are not relevant for this site. Benzene and 1,4-dioxane
are is the only organic COCs, and they are primarily degraded aerobically, so only those MNA
parameters with significance for aerobic degradation are needed for this site. The following MNA
parameters have little or no relevance to aerobic degradation at this site:
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• Dissolved Hydrogen (important of dehalogenation of chlorinated hydrocarbons, but not for
aerobic degradation of benzene);
• Sulfide (has not been detected at this site);
• Volatile Fatty Acids (very few sporadic detections, insufficient detections to assess);
• Dissolved CO2 (product of anaerobic degradation of chlorinated hydrocarbons, not relevant to
aerobic degradation of benzene) ; and
• Ethene/Ethane (product of anaerobic degradation of chlorinated hydrocarbons, not relevant
to aerobic degradation of benzene). [Note - methane will continue to be monitored to track
impact of landfill gas on the groundwater.]
After the first CAER (December 2015), the NCDEQ agreed to reduce the frequency of these
parameters to both semiannual sampling events every third year. On behalf of Granville County,
LaBella recommends and requests a further reduction to two events every five years, corresponding
to the two events immediately preceding each CAER. The next CAER will be due after the second
semiannual sampling event of 2025; therefore, the next time these parameters will be analyzed will
be the two semiannual events in 2025.
7.9.4 Contingency Plan
The CAP included a contingency plan in the event that MNA plus phytoremediation is shown to be
ineffective at controlling migration of the contaminant plume. The contingency plan consists of in -
situ or ex -situ treatment of the groundwater to enhance biodegradation and to prevent or remediate
the off -site migration of impacted groundwater with GPS exceedances. If required, the contingency
remedies may include one or more of the following:
• Construction of a man-made wetland area downgradient of MW-2R;
• Installation of an air-sparging system in the vicinity of MW-2R; and/or
• Additional active remedies, with approval of NCDEQ.
At this time, MNA plus phytoremediation remains an appropriate and effective remedy for the Butner
Landfill facility. No contingency remedies are recommended.
7.9.5 Land Use Restrictions
Groundwater beneath the landfill property appears to have been impacted by leachate that
originates from the unlined landfill and/or by the migration of landfill gas. Benzene, 1,4-dioxane,
cobalt, and vanadium have been detected in exceedance of GPS. There is no evidence that the
contaminant plume extends up to the creek downgradient of the plume, or beyond the property
boundary. There have not been any GPS exceedances of in sentinel NES-1, except for a relatively
low detection of vanadium in NES-1. The current COC plumes are stable.
Based on the semiannual groundwater and surface water monitoring and the annual tree survey,
MNA and Phytoremediation appear to be effectively controlling the contaminant plume. The plume
appears stable and is not migrating toward the property boundary. At this time there is no need to
impose land use restrictions on the landfill or adjoining property.
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8.0 REFERENCES
The references cited herein were used to prepare this document and may or may not be cited in the
text of this report.
Aburto, A., 2009. Mixed Aerobic and Anaerobic Microbial Communities in Benzene -Contaminated
Groundwater. JOURNAL OF APPLIED MICROBIOLOGY, Issue 1, 2009.
Briggs, G.C., Browmilow, R.H., and Evans, A.A., "Relationship between Lipophicity and Root Uptake
and Translocation of Non -ionized Chemicals by Barley", Pesticide Science, Volume 13, 1982.
Ferro, A., Kennedy, J., Kjelgren, R., Rieder, J., and S. Perrin. 1999. "Toxicity Assessment of Volatile
Organic Compounds in Poplar Trees". International Journal of Phytoremediation. 1(1): 9-17.
Fritsche, Wolfgang, and Hofrichter, Martin, 2008. Aerobic Degradation by Microorganisms, in
Biotechnology: Environmental Processes II, Volume 11b, Second Edition, H. J. Rehm & G.
Reed, eds. WILEY-VCH Verlag GmbH. Published Online: 20 MAR 2008.
GAI Consultants - NC, Inc. (GAI), 1994. Ground and Surface Water Monitoring System, Granville
County, Butner Landfill, NC Permit No. 39-02. June, 1994.
Gordon, M., N. Choe, J. Duffy, G. Ekuan, P. Heilman, I. Muiznieks, L. Newman, M. Ruszaj, B.B.
Shurtleff, S. Strand, and J. Wilmoth. 1997. Phytoremediation of Trichloroethylene with
Hybrid Poplars. p. 177-185. In E.L. Kruger etg al. (ed.) Phytoremediation of Soil and Water
Contaminants. ACS symposium series 664. American Chemical Society, Washington, DC.
Interstate Technology and Regulatory Cooperation Work Group (ITRC). Phytoremediation Decision
Tree. Prepared by: ITRC Phytoremediation Work Team. November 1999. Available at
http://www.itrcweb.org.
Jindrova, E., M. Chocova, K. Demnerova, and V. Brenner, 2002. Bacterial Aerobic Degradation of
Benzene, Toluene, Ethylbenzene and Xylene. Folia Microbiologica, Volume 47, Issue 2, pp
83-93, April 2002.
Joyce Engineering (JOYCE), 2013. Assessment of Corrective Action, Butner Landfill, Granville
County, Permit No. 39-02. May 2013.
Joyce Engineering (JOYCE), 2014. Corrective Action Plan, Butner Landfill, Granville County, Permit
No. 39-02. May 2014.
Joyce Engineering (JOYCE), 2015. Corrective Evaluation Report, Butner Landfill, Granville County,
Permit No. 39-02. December 2015.
Miller, R. Phytoremediation, Technology Overview Report. Ground -Water Remediation Technologies
Analysis Center (GWRTAC), available at http://ww.gwrtac.org
Musat, Florin, 2008. Anaerobic Degradation of Benzene by a Marine Sulfate -Reducing Enrichment
Culture, and Cell Hybridization of the Dominant Phylotype. ENVIRONMENTAL MICROBIOLOGY,
Issue 1, 2008.
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Negri, M. C., and R. R. Hinchman. 2000. The Use of Plants for the Treatment of Radionuclides. in I.
Raskin and B. D. Ensley, editors. Phytoremediation of Toxic Metals. John Wiley & Sons, Inc.,
New York.
Newell, Charles J., Ph.D., P.E., R. Kevin McLeod, and James R. Gonzales, 1996. BIOSCREEN Natural
Attenuation Decision Support System User's Manual, Version 1.3. United States
Environmental Protection Agency, Office of Research and Development, Washington DC.
EPA/600/R-96/087. August 1996.
Newell, Charles J., Ph.D., P.E., R. Kevin McLeod, and James R. Gonzales, 1997. BIOSCREEN Natural
Attenuation Decision Support System, Version 1.4 Revisions. United States Environmental
Protection Agency, Office of Research and Development, Washington DC. July 1997.
North Carolina Department of Environment and Natural Resources (NC-DENR), 2011. North
Carolina Solid Waste Management Rules. 15 NCAC 13B. Amended April 2011.
NC-DENR, 2007. North Carolina Solid Waste Section Guidelines for Corrective Action at Solid Waste
Management Facilities. March 2007.
NC-DEQ, 2017. NC Solid Waste Section Guidelines for Alternate Source Demonstration Submittals
for Solid Waste Management Facilities. July 2017.
Rhodes, Daniel L., David E. Blake, Robert H. Morrow, Joshua D. April, Amy L. Gross, and Jacob M.
Kendall, 2012. Geologic Map of the Eastern and Central Portions of the Lake Michie 7.5-
Minute Quadrangle, Durham, Granville, and Person Counties, North Carolina. North Carolina
Geological Survey Open File Report 2012-01.
Schnoor, J. Phytoremediation, Technology Evaluation Report. GWRTAC. Available at
http://ww.gwrtac.org.
US -EPA, 1998. Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in
Groundwater. ORD, EPA/600/R-98/128. September 1998.
US -EPA, 1999. Phytoremediation Resource Guide, EPA 542-B-99-003. June 1999. Available at
http://www.epa.gov/tio.
US -EPA, 2000. Introduction to Phytoremediation, EPA 600-R-99-107. February 2000. Available at
http://www.epa.gov/tio.
US -EPA, 2009. Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified
Guidance. March 2009.
Williams, John B., 2002. Phytoremediation in Wetland Ecosystems: Progress, Problems, and
Potential. Critical Reviews in Plant Sciences, Volume 21, Issue 6, 2002.
August 2020 Water Quality Monitoring Report
and Corrective Action Evaluation Report
Granville County- Butner Landfill, Permit No. 39-02
LaBella Associates
December 2020
23

TABLES
Table 1
August 2020 Groundwater Elevations
Table 2
August 2020 Field Parameters
Table 3
August 2020 Detected Constituents in Groundwater
Table 4
August 2020 Exceedances of Groundwater Standards
Table 5
August 2020 Hydraulic Gradients and Groundwater Flow Velocities
Table 6
August 2020 Monitored Natural Attenuation Parameters

TABLE 1: August 2020 Groundwater Elevations
Location
Date
TOC Elevation
(Ft AMSL)
Depth to
Groundwater
(Ft BTOC)
Lithology
Well Depth
(Ft BTOC)
Groundwater
Elevation
(Ft AMSL)
MW-1R
8/27/2020
460.51
41.67
Bedrock
56
418.84
MW-213
8/27/2020
331.60
2.42
Alluvial/
18.85
329.18
Residual
MW-3R
8/27/2020
330.96
2.41
Saprolite
35.83
328.55
MW-4
8/27/2020
340.80
7.38
Bedrock
31.43
333.42
MW-5
8/27/2020
343.88
13.40
Saprolite
23.52
330.48
MW-6
8/27/2020
362.53
11.19
Bedrock
32.63
351.34
NES-1
8/27/2020
328.40
17.50
Bedrock
32.8
310.9
Notes:
Butner Landfill, Granville County
Permit # 39-02
TOC = Top of casing
Ft = feet
BTOC = Below TOC AMSL = Above mean sea level
BGS = Below ground surface
LaBella Associates

TABLE 2: August 2020 Field Parameters
WELL ID
PARAMETER
RESULT
UNITS
SAMPLE DATE
pH
5.08
S.U.
Temperature
17.2
°C
Conductivity
82.4
PS/cm
Turbidity
10.58
NTU
3902-MWIR
8/27/2020
Dissolved Oxygen
0.63
mg/L
Oxidation Reduction Potential
242.7
mV
Static Water Level
41.67
ft
Well Depth
56.00
ft
pH
6.13
S.U.
Temperature
18.9
°C
Conductivity
1,601
PS/cm
Turbidity
12.30
NTU
Dissolved Carbon Dioxide
---
mg/L
3902-MW2R
8/27/2020
Dissolved Oxygen
0.22
mg/L
Ferrous Iron
4.5
mg/L
Oxidation Reduction Potential
-10.8
mV
Static Water Level
2.42
ft
Well Depth
18.85
ft
pH
6.42
S.U.
Temperature
19.9
°C
Conductivity
1,217
PS/cm
Turbidity
2.48
NTU
Dissolved Carbon Dioxide
---
mg/L
3902-MW3R
8/27/2020
Dissolved Oxygen
0.48
mg/L
Ferrous Iron
1.0
mg/L
Oxidation Reduction Potential
12.4
mV
Static Water Level
2.41
ft
Well Depth
35.83
ft
pH
6.57
S.U.
Temperature
19.3
°C
Conductivity
1,409
PS/cm
Turbidity
2.97
NTU
Dissolved Carbon Dioxide
---
mg/L
3902-MW3R*
9/30/2020
Dissolved Oxygen
2.00
mg/L
Ferrous Iron
---
mg/L
Oxidation Reduction Potential
232.3
mV
Static Water Level
1.80
ft
Well Depth
35.80
ft
Butner Landfill, Granville Co.
Permit No. 39-02 1 of 3 LaBella Associates

TABLE 2: August 2020 Field Parameters
WELL ID
PARAMETER
RESULT
UNITS
SAMPLE DATE
pH
6.45
S.U.
Temperature
22.2
°C
Conductivity
1,335
PS/cm
Dissolved Oxygen
5.04
mg/L
3902-M W4
8/27/2020
Oxidation Reduction Potential
190.3
my
Turbidity
5.09
NTU
Static Water Level
7.38
ft
Well Depth
31.43
ft
pH
6.71
S.U.
Temperature
20.3
°C
Conductivity
773.0
PS/cm
Turbidity
24.58
NTU
3902-MW5
8/27/2020
Dissolved Oxygen
6.22
mg/L
Oxidation Reduction Potential
196.5
my
Static Water Level
13.40
ft
Well Depth
23.52
ft
pH
6.73
S.U.
Temperature
21.1
°C
Conductivity
577.0
PS/cm
Dissolved Oxygen
4.14
mg/L
3902-MW6
8/27/2020
Oxidation Reduction Potential
188.0
my
Turbidity
101.5
NTU
Static Water Level
11.19
ft
Well Depth
32.63
ft
pH
5.48
S.U.
Temperature
20.1
°C
Conductivity
140.5
PS/cm
Turbidity
73.10
NTU
3902-NES1
8/27/2020
Dissolved Oxygen
3.16
mg/L
Oxidation Reduction Potential
240.6
my
Static Water Level
17.50
ft
Well Depth
36.10
ft
Butner Landfill, Granville Co.
Permit No. 39-02 2 of 3 LaBella Associates

TABLE 2: August 2020 Field Parameters
WELL ID
PARAMETER
RESULT
UNITS
SAMPLE DATE
pH
---
S.U.
Temperature
---
°C
Conductivity
---
PS/cm
3902-SW1
8/27/2020
Turbidity
---
NTU
Dissolved Oxygen
---
mg/L
Oxidation Reduction Potential
---
mV
pH
---
S.U.
Temperature
---
°C
Conductivity
---
PS/cm
3902-SW2
8/27/2020
Turbidity
---
NTU
Dissolved Oxygen
---
mg/L
Oxidation Reduction Potential
--
mV
Units: °C = degrees Centigrade
S.U. = Standard Units
mV = milivolts
pS/cm = micro-Seimens per centimeter
NTU = Nephelometric Turbidity Units
mg/L = miligrams per liter
Notes: * = Sample collected during 9/30/2020 resample
Butner Landfill, Granville Co.
Permit No. 39-02 3 of 3
LaBella Associates

TABLE 3: Detected Constituents in Groundwater
WELL ID
PARAMETER
I RESULT
UNITS
I MDL
I MRL
I GPS
I Source
I DATE
Groundwater Samples
MW-1R
Barium
4.5 J
pg/L
1 3.5
5
700
NC21-
8/27/2020
MW-2R
Barium
127
pg/L
3.5
5
700
NC21-
8/27/2020
Cobalt
9.7
pg/L
3.6
5
1
IMAC
Nickel
99.1
pg/L
3.5
5
100
NC21-
Tin
27.6
pg/L
4.7
5
1 2000
IMAC
1,2-Dichlorobenzene
1.2
pg/L
1 0.29
1
20
NC21-
1,4-Dichlorobenzene
2.1
pg/L
0.26
1
6
NC21-
Benzene
1.9
pg/L
0.15
1
1
NC21-
Chlorobenzene
16.1
pg/L
0.23
1
50
NC21-
Chloroethane
0.87 J
pg/L
0.49
1
1 3000
NC21-
1,4-Dioxane (p-Dioxane)
113
pg/L
2.3
4
3
NC21-
MW-3R
Barium
83.2
pg/L
3.5
5
700
NC21-
8/27/2020
Copper
5.3
pg/L
4.3
5
1000
NC21-
Nickel
19.5
pg/L
3.5
5
100
NC21-
Tin
5.1
pg/L
4.7
5
1 2000
IMAC
1,2-Dichlorobenzene
1.3
pg/L
0.29
1
20
NC21-
1,4-Dichlorobenzene
1.4
pg/L
0.26
1
6
NC21-
Benzene
0.49 J
pg/L
0.15
1
1
NC21-
Chlorobenzene
17.5
pg/L
0.23
1
50
NC21-
Chloroethane
1.5
pg/L
0.49
1
1 3000
NC21-
Vinyl chloride
1.1
pg/L
0.24
1
0.03
NC21-
1,4-Dioxane (p-Dioxane)
50.0
pg/L
1.2
2
3
NC21-
MW-3R
Vinyl chloride (Resample)
ND
pg/L
0.24
1
0.03
NC21-
9/30/2020
MW-4
Copper
13.5
pg/L
4.3
5
1000
NC21-
8/27/2020
Nickel
12.2
pg/L
3.5
5
1 100
NC21-
Vanadium
21.1
pg/L
3.9
5
0.3
IMAC
Chlorobenzene
4.1
pg/L
0.23
1
50
NC21-
Chloroethane
1.1
pg/L
0.49
1
3000
NC21-
1,4-Dioxane (p-Dioxane)
39.3
pg/L
1.2
2
3
NC21-
MW-5
Barium
128
pg/L
3.5
5
700
NC21-
8/27/2020
Cobalt
88.7
pg/L
3.6
5
1
IMAC
Copper
5.6
pg/L
4.3
5
1000
NC21-
Nickel
18.1
pg/L
3.5
5
100
NC21-
Chlorobenzene
0.32 J
pg/L
0.23
1
50
NC21-
1,4-Dioxane (p-Dioxane)
3.0
pg/L
1.2
2
3
NC21-
3902-NES-1
Vanadium
6.8
pg/L
3.9
5
0.3
IMAC
8/27/202 1
NOTES: All Results in micorgrams per liter (pg/L).
GPS = Water Protection Standard
MDL = Method Detection Level .
MRL = Method Reporting Limit.
J = Estimated concentration below the MRL.
NC21- = NC Groundwater Standard from 15A NCAC 2L.0202.
IMAC = NC Interim Maximum Allowable Concentration (for constituents with no NC2L).
Bold = GPS Exceedance.
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02 1 of 1

TABLE 4: Exceedances of Groundwater Standards
WELL ID
PARAMETER
RESULT
UNITS
MDL
MRL
GPS
Source
DATE
Groundwater
Samples
MW-2R
Cobalt
9.7
pg/L
3.6
5
1
IMAC
8/27/2020
Benzene
1.9
pg/L
0.15
1
1
NC21-
1,4-Dioxane (p-Dioxane)
113
pg/L
2.3
4
3
NC21-
MW-3R
Vinyl chloride
1.1
pg/L
0.24
1
0.03
NC21-
8/27/2020
1,4-Dioxane (p-Dioxane)
50.0
pg/L
1.2
2
3
NC21-
MW-3R
Vinyl chloride (Resample)
ND
pg/L
0.24
1
0.03
NC21-
9/30/2020
MW-4
Vanadium
21.1
pg/L
3.9
5
0.3
IMAC
8/27/2020
1,4-Dioxane (p-Dioxane)
39.3
pg/L
1.2
2
3
NC21-
MW-5
Cobalt
88.7
pg/L
3.6
5
1
IMAC
8/27/2020
NES-1
Vanadium
6.8
pg/L
3.9
5
0.3
IMAC
8/27/2020
NOTES: All Results in micorgrams per liter (pg/L).
GPS = Water Protection Standard
MDL = Method Detection Level .
MRL = Method Reporting Limit.
NC21- = NC Groundwater Standard from 15A NCAC 2L.0202.
IMAC = NC Interim Maximum Allowable Concentration (for constituents with no NC2L).
Butner Landfill, Granville Co. LaBella Associates
Permit No. 39-02

TABLE 5: Hydraulic Gradients and Groundwater Flow Velocities
Based on Water Level Data obtained on: August 27, 2020
GROUND-
HORIZ.
HYDRAULIC
EFFECTIVE
LINEAR
GRADIENT
FLOW LINE
FLOW
WATER
GRADIENT
CONDUCTIVITY
POROSITY
VELOCITY
CALCULATION
LENGTH
DIRECTION
ELEVATION
1
K
n e
V
SEGMENT
(feet)
(feet)
(ft/day)
(ft/year)
415 415
11
1980
SE
0.048
6.18E-02
0.18
6.0
Notes:
Hydraulic conductivity (K) value is the average of results from slug -tests conducted in 1994 (GAI, 1994).
Effective Porosity (n e) based on average of 90% of reported Total Porosity (GAI, 1995) for site soils.
Linear flow velocity: V = Kiln a (modified Darcy equation).
See Drawing 1 for Flow Segment.
Granville County, Butner Landfill LaBella Associates
Permit No. 39-02

TABLE 6: August 2020 Monitored Natural Attenuation Parameters
Background
Downgradient
Sentinel
Parameter
Date
Units
DL
RL
MW-1R
MW-2R
MW-3R
NES-1
Field Parameters
Temperature 8/27/2020 °C
17.2
18.9
19.9
20.1
pH 8/27/2020 SU
5.08
6.13
6.42
5.48
Conductivity 8/27/2020 PS/cm
82.4
1,601
1,217
140.5
Redox Potential (ORP) 8/27/2020 mV
242.7
10.8
12.4
240.6
Dissolved Oxygen 8/27/2020 mg/L
0.63
0.22
0.48
3.16
Iron, Ferrous (+2) 8/27/2020 mg/L
ND
4.5
1.0
ND
Laboratory
Parameters
Alkalinity, Total as CaCO3
8/27/2020
mg/L
5,000
5,000
47.6
909
735
ND
BOD, 5 day
8/27/2020
pg/L
2,000
2,000
ND
6,300
ND
ND
Chemical Oxygen Demand (COD)
8/27/2020
pg/L
12,500
25,000
ND
106,000
36,100
ND
Chloride (EPA 300.0)
8/27/2020
pg/L
2,400
4,000
3,840
208,000
148,000
5,330
Ethane
8/27/2020
pg/L
1.200
10
ND
ND
ND
ND
Ethene
8/27/2020
pg/L
1.2
10
ND
ND
ND
ND
Methane
8/27/2020
pg/L
3.4
10
ND
6,000
497
ND
Nitrogen, Nitrate
8/27/2020
pg/L
50
100
ND
ND
ND
6,340
Sulfate
8/27/2020
pg/L
500
1,000
ND
ND
ND
5,210
Sulfide
8/27/2020
pg/L
50
100
ND
ND
ND
ND
Total Organic Carbon
8/27/2020
pg/L
500
1,000
689 J
29,800
8,190
916 J
Dissolved Hydrogen
8/27/2020*
nM
2.8
1.0 J
1.2 J
2.4
Total Volatile Fatty Acids
08/27/20
pg/L
1
1 5,430
1 49,700
1 5,396
1 5,660
NOTES:
DL = laboratory detection limit.
RL = laboratory reporting limit.
ND = not detected above detection limit.
J = estimated concentration between the DL and the RL.
mg/L = milligrams per liter
pg/L = micrograms per liter
* Dissolved Hydrogen for MW-113 & NES-1 were from samples collected on 9/10/2020.
mV = millivolt
SU = standard unit
nM = nano -Molar
°C = degress Celcius
pS/cm = micro-Siemen per centimeter
ntu = nephelometric turbidity units
Butner Landfill, Granville Co.
Permit No. 39-02
LaBella Associates
May 2020

CHARTS
Chart 1 Benzene Concentrations vs. Time
Chart 2 1,4-Dioxane Concentrations vs. Time
Chart 3 Cobalt Concentrations vs. Time
Chart 4 Vanadium Concentrations vs. Time
Chart 5 pH vs. Time
Chart 6 Conductivity vs. Time
Chart 7 ORP vs. Time
Chart 8 DO vs. Time

2.0
1.8
1.6
0.8
0.6
0.4
0.2
0.0
C0 I- r 0D 00 O O O O 11 .-I N N M M V �T Ln M O (D r ti 00 00 O 0) O O
UA � tiA Q tiD Q tiA Q UA � UA Q b.0 Q UA � UA � tiA Q tiD Q UA � UA � Wl Q tiA
O N O N O N O N O N O N 7 N O N O N 7 N O N O N O N 7 O O
Q LL Q l.L Q l.L Q l.L Q LL Q l.L Q l.L Q LL Q l.L Q l.L Q l.L Q l.L Q LL Q LL Q
Granville Co., Butner Landfill
Permit # 39-02 La Bella Associates

140
120
100
0
0
80
U
0
U
0
0
0
0 60
0
Chart 2: 1,4-Dioxane Concentration vs. Time in MW-2R, MW-3R, MW-4, & MW-5
40� ..................................
NC2L = 3 µg/L
NE
0
Q0 �M
0)
Q
BMW-2R
BMW-3R
--e— M W-4
M W-5
0 0
U- N Q N
Granville Co., Butner Landfill
Permit # 39-02 LaBella Associates

Chart 3: Cobalt Concentration vs. Time in MW-2R & MW-5
275
250
225
200
100
75
50
25
0
In V1 w w I, n w w m T O O M M V V In Ln l0 w r� n w w m T O O m M V V In V1 lO w n n w w m m O O
T Ol T T Ol T Ol T Ol T O O O O O O O O O O O O O O O O O O O O c-I c-I c-I c-I c-I c-I c-I c-I c-I c-I c-I c-I c-I c-I c-I c-I c-I c-I c-I c-I N N
-a on -D 09 -a 00 -a 00 -a 09 -a w -D b0 -D b0 -D 09 -D 09 -a 09 -a b0 -D b0 -D b0 -D 09 -a 09 -a 09 -D 00 -D 00 -a 00 -D w -D 09 -a 09 -a 09 -a 09 -a w
a)3 a)3 N 3 N 3 N 3 N 3 N 3 N 3 N D a)3 N D N 3 N 3 N 3 N D U1 3 N 3 a)3 a)3 N 3 a)3 a)3 N 3 a)3 U) 3 N J
LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q
Granville Co., Butner Landfill
Permit # 39-02 La Bella Associates

600
550
500
450
m
350
U
C
O
U
F= 300
m
m
�:' 250
200
150
100
50
0
Chart 4a: Vanadium Concentration vs. Time in All Wells
u1 V1 lD lD I- n w w M M O O cI -1 N N M M V V V1 u1 lD lD I- n w w M M O O ci c-I N N M M-tt V V1 V1 lD lD I, n W w M M O O
T T T T T T T T M T O O O O O O O O O O O O O O O O O O O O 1- 1- 1 i 1- ri 1 i r- 1 i r- 1 i r- r- r- r- ri 1- 1i 1- 1i 1i N N
bA -0 b0 4 b0 4 b0 4 b0 -0 bD -0 by -0 bA -0 bA -0 M 4 M 4 b0 4 M 4 M -0 M -0 M -0 bA -0 M 4 M 4 M 4 bA 4 M -0 bD -0 M -0 M -0 M
41 7 41 7 N 7 N 7 4/ 7 N 7 a1 7 a1 7 a1 7 a1 7 N 7 N 7 N 7 N 3 41 7 41 7 a1 7 41 7 N 7 N 7 N 7 N 7 a1 7 a1 7 a1 7 v 7
LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q
Granville Co., Butner Landfill
Permit # 39-02 LaBella Associates

50
40
10
0
Chart 4b: Vanadium Concentration vs. Time in All Wells
ul ul lD lD I- n w x M M O O ci -1 N N M M V V V1 u1 lD tD I- n W w M M O O ci c-I N N M M -tt Rt V1 V1 lD lD I, n W W M M O O
T T T T T T T T T T O O O O O O O O O O O O O O O O O O O O ti 1- 111- .ti 1- 1i 1- 1- 1- 1- 11- 1i 1- 1111N N
OA -0 OA 4 OA 4 OA 4 Oq 4 UO -0 UO -0 UO -0 OA -0 OA -0 OA 4 OA 4 UO -0 UO -0 Oq -0 w -0 OA 4 OA 4 OA 4 Oq 4 Oq -0 Oq -0 Oq -0 OA -0 OA 4 OA
N O N O U1 O U1 O U1 7 U1 7 N 7 N 7 N O N O U1 O U1 O U1 7 N 7 N 7 N O N O U1 O U1 O U1 7 U1 7 N 7 N 7 N O N O U1 O
LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q U- Q U- Q LL Q LL Q LL Q LL Q LL Q LL Q U- Q U- Q LL Q LL Q LL Q
Granville Co., Butner Landfill
Permit # 39-02 LaBella Associates

9.0
8.5
8.0
7.5
4 7.0
c�
6.5
c
6.0
Ln
M
5.0
4.5
4.0
Chart 5: pH vs. Time in All Wells
m m M 't I;t Ln Ln Ln U) I'D �D -Z (.0 r, r, r" r" 00 00 00 00 M rn M rn o 0 0
T dp > >T w > ? bA > >, by > T dp > T bA > Q T w > -0 >- w
ra O O a) co 7 O aj co O O a) ro O O a (o =5 O 0) M :3 O a) tv =3 O a) M
Q z LL Q z - Q z - ¢ z - 2 Q z - 2 Q z - 2 ¢ z LL Q
BMW-1R BMW-2R BMW-3R BMW-4 BMW-5 MW-6 ONES-1
Granville County- Butner Landfill
Permit # 39-02 LaBella Associates

2000
1500
U
1000
500
n
Chart 6: Conductivity vs. Time in All Wells
M M M V1 u1 Ln Ln l0 l0 l0 l0 I� n n n 00 00 00 00 M M a) 0) O O O
>- 0A > -0 >- dq > -0 d0 > -0 > -0 bJJ > -0 0A > -0 >- dq > -0 to
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FIGURES
Figure 1 Site Location Map
Figure 2 Geologic Map

L•\GranMle\Ewq\Butner\, Site location Mape.dwa

TR CSYE.OnE DIRECTORAN LAND RESOURCES
EENNETR B. TAYLOIL STATE GEOLOGIST This geolOgi< was funded is part by the USES National CooVerb- Geologl< MapPieg Program
NORTR CAROLINA GEOLOGICALS—Y
OPEN FILE REPORT 301E-01
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DRAWINGS
Drawing 1 Groundwater Potentiometric Surface Map
Drawing 2 Benzene Isoconcentration Map
Drawing 3 Benzene Cross -Sections A and B
Drawing 4 1,4-Dioxane Isoconcentration Map
Drawing 5 1,4-Dioxane Cross -Sections A and B
Drawing 6 Cobalt Isoconcentration Map
Drawing 7 Cobalt Cross -Sections A and B
Drawing 8 Vanadium Isoconcentration Map
Drawing 9 Vanadium Cross -Sections A and B
Drawing 10 2020 Tree Survey

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GREENSBORO, NC 27407
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T T
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© 2020 LaBella Associates
GRANVILLE COUNTY
OXFORD, NORTH CAROLINA
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2203013.01
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11 /25/20
DRAWING NAME:
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DRAWING NUMBER
3

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T T
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© 2020 LaBella Associates
GRANVILLE COUNTY
OXFORD, NORTH CAROLINA
BUTNER LANDFILL
OXFORD, NORTH CAROLINA
NO: DATE: DESCRIPTION:
Revisions
PROJECT NUMBER:
2203013.01
DRAWN BY:
RH
REVIEWED BY:
VB
ISSUED FOR:
REVIEW
11 /25/20
DRAWING NAME:
1,4-DIOXANE
CROSS SECTIONS A AND B
AUGUST 2020
DRAWING NUMBER
5

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LaBeLLa
Powered by partnership.
2211 W. MEADOWVIEW ROAD
GREENSBORO, NC 27407
PHONE: [phone]
labellapc.com
T T
T T
© 2020 LaBella Associates
GRANVILLE COUNTY
OXFORD, NORTH CAROLINA
BUTNER LANDFILL
OXFORD, NORTH CAROLINA
NO: DATE: DESCRIPTION:
Revisions
PROJECT NUMBER:
2203013.01
DRAWN BY:
RH
REVIEWED BY:
VB
ISSUED FOR:
REVIEW
11 /25/20
DRAWING NAME
COBALT
CROSS SECTIONS A AND B
AUGUST 2020
DRAWING NUMBER:
7
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AUGUST 2020
fy,
LLI
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2. TOPOGRAPHIC CONTOURS SHOWN IN THIS MAP ARE BASED ON
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BY BATEMAN CIVIL SURVEY
DRAWING NUMBER:
o
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0 50 100 200
L
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W ao VERTICAL
EXAGGERATION = 2 0+00
20
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0 40 80 160
(FEET)
GRAPHIC SCALE
11+00 12+00
ALIGNMENT A - A' PROFILE
1+00 2+00 3+00 4+00 5+00 6+00 7+00 8+00
13+00 14+00 15+00 16+00 17+00 18+00 19+00
9+00 10+00
ALIGNMENT B - B' PROFILE
20+00 21+00 22+00 23+00
11+00 12+00 13+00 14+00 15+00 16+00 17+00 18+00
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19+00 19+50
LaBeLLa
Powered by partnership.
2211 W. MEADOWVIEW ROAD
GREENSBORO, NC 27407
PHONE: [phone]
labellapc.com
T T
T T
© 2020 LaBella Associates
GRANVILLE COUNTY
OXFORD, NORTH CAROLINA
BUTNER LANDFILL
OXFORD, NORTH CAROLINA
NO: DATE: DESCRIPTION:
Revisions
PROJECT NUMBER:
2203013.01
DRAWN BY:
RH
REVIEWED BY:
VB
ISSUED FOR:
REVIEW
11 /25/20
DRAWING NAME:
VANADIUM
CROSS SECTIONS A AND B
AUGUST 2020
DRAWING NUMBER

TREE COVERAGE SURVEY
LOGGED RECENTLY, WITH STANDING SWEET GUM AND BEECH SAPLINGS
WITH EMERGING LONG LEAF PINE.
AREA 1 APPROX. ACRES2. \ \ \ \ \ \ \
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BLUE : 1%\
4. � ,. _
POPLAR 5. .\ I \ \
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AREA APPROX.-
1. TULIP POPLAR (50%)
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APPENDICES
Appendix A
Appendix B
Appendix C
Appendix D
Appendix E
Appendix F
Appendix G
Appendix H
Appendix I
Monitoring Well Construction Data
Field Data Logs
Laboratory Analytical Reports and Chains of Custody
Historical Groundwater Elevations
Historical Constituents in Groundwater
Historical Constituents in Surface Water
Historical Monitored Natural Attenuation Parameters
Phytoremediation Tree inspection Log
BIOSCREEN Input and Output

Appendix
Monitoring Well Construction Data

Appendix A: Well Construction Details
Surface
TOC
Top of
Top of
Bottom of
Water
Depth to
Geologic
Construction
Driller's
Permit #
Well ID
Latitude
Longitude
Total Depth
Comments
Elevation
Elevation
Casing
Screen
Screen
Level*
Bedrock
Unit**
Date
Reg. #
Ft-AMSL
Ft-AMSL
Ft-AGS
Ft-BTOC
Ft-BTOC
Ft-BTOC
Ft-BTOC
Ft-BTOC
Fractured
background well
39-02
MW-1 R
N360 09' 55.49"
W780 45' 37.80"
461.01
461.01
0.00
41.00
56.00
56.00
41.00
30.00
4/21/1994
446
Bedrock
replacement
compliance well
39-02
MW-2 R
N360 09' 38.57"
W780 45' 34.97"
326.60
328.94
2.34
3.85
18.85
18.85
2.60
13.00
Transition Zone
4/12/1994
446
replacement
Fractured
compliance well
39-02
MW-3 R
N360 09' 38.58"
W780 45' 34.85"
328.77
330.95
2.18
25.83
35.83
35.83
3.00
13.00
4/14/1994
446
Bedrock
replacement
Fractured
39-02
MW-4
N360 09' 38.93"
W780 45' 30.15"
338.97
340.92
1.95
16.43
31.43
31.43
9.80
13.00
4/18/1994
446
compliance well
Bedrock
39-02
MW-5
N360 09' 39.35"
W780 45' 23.77"
341.88
344.00
2.12
8.52
23.52
23.52
12.80
17.00
Transition Zone
4/18/1994
446
compliance well
39-02
MW-6
N360 09' 47.00"
W780 45' 25.47"
360.80
362.80
2.00
17.63
32.63
32.63
11.70
21.20
Transition Zone
4/19/1994
446
compliance well
nature extent
39-02
NES-1
N360 09' 35.65"
W780 45' 31.59"
326.22
328.72
2.50
15.00
30.00
30.00
22.00
26.00
Transition Zone
11/14/2007
2675
study y well
Notes:
TOC = Top of Casing.
Ft-AMSL = Feet above mean sea level.
Ft-AGS = Feet above ground surface.
Ft-BTOC = Feet below TOC.
*Water Level from TOC, approx. 24 hours after drilling.
-Geology of screened interval. Bedrock = fractured metavolcanic bedrock of Carolina slate belt. Transition Zone = screen begins in saaprolite and ends in bedrock.
Typical Monitoring Well Construction, materials are 2 inch SCH40 PVC casing and screen with 0.010 inch slot, sand pack, bentonite seal, grout pad, & steel outer casing.
Monitoring Well Summary data is from well construction records, GAI Consultants June 1994, & Joyce Engineering November 2007 and field observations.
Locations and elevations from March 2013 survey.
Butner Landfill, Granville County
Permit # 39-02
LaBella Associates

Appendix B
Field Data Logs

LaBella Project Name:
Location:
Project No.:
2211W. Meadowview Rd Suite 101
Greensboro, NC 27407 Sampled By:
Telephone: [phone] nn
Facsimile: [phone] Date: �IoCr7I� U
WELL I.D.: yyw :� Weather:
Well Diameter:
Depth of Well:
Measuring Point: (�
Pump Type: 204-�AF
F:IF"RA?V[F7sR�l�`{i+"A:�'7lTR.i! Yi NT
r r\tr,%3 C
O (_I
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S -
Static Water Level: t I l0
Length of Well Screen:
Depth to Top of Pump:
Tubing Type: �on
Mw
Gallons
--
Conductivity
Turbidity
Dissolved 0, Redox
Alkalinity
I w
Comments
�
ME
-----------
-----------
-----------
-----------
-----------
-----------
-----------
o a a Ions Purged
Purge Time Purge Time End: Final Static Water Level:
Start:
Notes: 16 i S-&-, O$ S r -
�k CA•� ���R- �� !tea ��S �� a:c� 1�x,� � �o �
�d

0.., LaBella
Project Name
C)fan.r;ltie
Location: G'Ams- ,N C
Project No.: Q 19 a O) G t_I
2211W. Meadowview Rd Suite 101
Greensboro, NC 27407 Sampled By:
C- . i,Jri �k • yam, �0-'(- GG�
Telephone: ( [phone]
Facsimile: 336 323-0093 Date:
�� U
WELL I.D.: Weather:
P"d61. CAOA4 Ie4 86 S
Well Diameter: �
Static Water Level: . LI a
Depth of Well: J '� ,
Length of Well Screen:
Measuring Point:
Depth to Top of Pump:
Pump Type: Wac�_-V
Tubing Type: ( �
FMM1R'13FR�VFi+TA►ll 21l ii3lfllT'I'
Gallom=�,
Purged
Conductivity
(ms/cm)
Dissolved 02
Alblinity
—Comments
men��r��m���a�a�ra����
Purge Time Purge Time End: a Final Static Water Level:
Start: Li 1 Sa ,
{ - _
NOW
Notes: o`\ Q ` V-_)
C-0a bow.e-s c rc c gyp; c e d
ba� III�o Jc y

0 LaBella
Project Name:
Location:
Project No.:
2211W. Meadowview Rd Suite 101
Greensboro, NC 27407 Sampled By:
Telephone: [phone]
Facsimile: [phone] Date:
WELL I.D.: M W ' �� Weather:
O O:
Well Diameter:
�^ 1
Depth of Well: 3S', 2;
Measuring Point: TOL
Pump Type:
w , R F. —T
Static Water Level:
Length of Well Screen:
Depth to Top of Pump:
Tubing Type:
b oc�.a
Time
Pump Rate
ly vm` !?
Gallons
Purged
pH
Temp
"C
Conductivity
(MS/cm)
Turbidity
(NTU)
Dissolved 02 Redox Alkalinity
(m L) (mV)
+ 10% +/- 10 mV
Iron (11) Comments
D I W
+/- 0.1
+/- 3%
77 `��
I
9s3
I
. ,=7
•(
l ,%Z
ILr L
Coo
O�
Sol
or&
5 1+57
N,;I
S! U
b
�' • 0 �'I
►a�t�
15
iq,
3,q2
O.
aG,
S�o61
12SU
Is
1R.3
aoa
3l03
,Ll6
A3-
6-,-71
cl,
liq 5
3
o, u
lq, b
C' (1
4 A
19,17
q! 1
o, gIq
14
Ica. tis
•via, oC ! J "ui,vua ru,gcu
Purge Time �� 2 Purge Time End:
Start: J
Notes:
�e
Cot �; �- w� �Q► c'�
•W
13s 3
Final Static Water Level: s L( S�
"' Yll//Zv 11 &do q11

DATE: o /a-7/;Q,,V
LaBeRa
GROUND WATER SAMPLING LOG
Project Name: 01664 Mf- - VU�'rjf Project No. /Task No.: Q0CL 3S Z t� /OL/
Well ID: �'lt�-Sampler(s): F.Wa�A- ( e, 1�k>cj oC. k
Well Location:�`C(� C
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
2 inches
—7 feet
3 � �I feet
�2 � , bS feet [DTB-DTW]
gallons
_
gallons
gallons
gallons
Purged with: B�� Pump Other:
Sampled with: ailed Pump, Other:
n
Depth to Water before Sampling: `"I * C-S feet
Gallons
Time
Temp
(°C)
pH
Cond.
(US/cm)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
IDLI g
al,a
(� 35
11�2
3��s
liN , I
►'SAS
Ew
q
�d5
17,
�5
1IRS
1, C(3
jos,a
Date of sample:
Before Sampling
rj
qa a
,
s
S, a
s (7
Comments (weather conditions, odor, color, silt, etc.):
'-7 S2^PUJ I�lo
Signature: LLw�Date: q/ I lo?-DaC)
QA/QC Sign Off• Date: _ � /,2d � __

La Bella
GROUND WATER SAMPLING LOG /
Project Name: {���,�1e ^kA-� Project No. /Task No.: 91 � a Z S�• 0 l lG ,/
Well ID: W�S Sampler(s): �. �, (�1vi�oC k
Well Location:
f\U 14 �13 C
Well Diameter: 2 inches
Initial Depth to Water (DTW): 13 ��� U feet
Depth to Bottom (DTB): �3° feet
lo.�j2
Water Column Thickness (WCT): feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with: Bai er Pump Other:
Sampled with: ai Pump Other:
Depth to Water before Sampling: ) � BLl () feet
gallons
-gallons
gallons
gallons
Gallons
Time
Temp
(°C)
pH
Cond.
(us/cm)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
/s,I
3,
(D S1
n'C-1
$a
�,��
�-7,
Date of sample:
$/P:7
0
Before Sampling
S-5-
�W. S
C ,-
-7-73
,xa
l R �. 5
`') •S�
Comments (weather conditions, odor, color, silt, etc.):
00"C��I C�o�-bul , �� C� SD.S
Signature: 91 dui Date:
QA/QC Sign Off: Date:

0- , LaBelLa
DATE: V,71.2o
GROUND WATER SAMPLING LOG
Project Name: (3�Q�IN �� " kl1 PS Project No. /Task No.: �2 � lQ 3:s2' of /vy
Well ID: � f Sampler(s): k� j'�cx}oC lC
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
2 inches
feet
3a • �� feet
feet [DTB-DTW]
For 2" Well: WCT X 0.163 = Q -gallons
For 4" Well: WCT X 0.653 = gallons
For THREE Well Volumes: WV X 3 = 1 0m y gallons
Actual Amount Purged/Bailed: ?-•qs gallons
Purged with: Bailj Pump Other:
Sampled with: B Pump Other:
Depth to Water before Sampling: feet
Gallons
Time
Temp
(°C)
pH
Cond.
(US/CM)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
0
y71,
a6s.-1
19-. 7
� ,fig
©�'�g
I`�, D
� o�`I
� g�oq
N j5 G
�s►,o
�q.;3
Date of sample:
U
Before Sampling
PT
�.73
57,
b
lb .S
Comments (weather conditions, odor, color, silt, etc.):
auv; , ri.L& k,ak K613
1
-7 b, f eg searnpw @ f 62S
Signature: Lr q,�/aO�rJ
Date:
QA/QC Sign Off:" Date:

DATE: D/ �71 �'0
La Bella
GROUND WATER SAMPLING LOG
Project Name: ls�G�y�� ' �k�-2S Project No. /Task No.: alga e� 6-:2. 4) /5 `I
Well ID: `v�5�� Sampler(s): (Z-%lo.doCt
Well Location:
6
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well:
For 4" Well:
WCT X 0.163
WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled witt
Depth to Water before Sampling:
2 inches
- O feet
d feet
Igo G feet [DTB-DTW]
3.6"�> gallons
gallons
= V' • U { gallons
gallons
1W."12
feet
Gallons
Time
Temp
(°C)
pH
Cond.
(US/CM)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
Q
(139
HI
ql.q
3132
:�X,0
7gSQ't-
IS,q
q.lq
-60
3,63
gq'7,0
>IIOcD
IS77
q V
35.9
3, N
a9&, 3
A100
Date of sample:
?IQ`71
Before Sampling
PL`0
go (
S,yg
19D.-S
Comments (weather 11conditions, odor, color, silt, etc.):
86, /QnkS j(1 CcSill G�
Signature: Date: 911��b
QA/QC Sign Off: Date: 446! ter

0 La BeUa
DATE: 3 2 ZoZU
GROUND WATER SAMPLING LOG
Project Name: Project No. /Task No.:
Well ID: W - Sk Sampler(s): lclzl"{I�e
Well Location: '6Af1eS , k�(^
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 =
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled witt
nches
1.8 feet
c5 feet
3,3, 1 ? feet [DTB-DTW]
5.5- gallons
�+—gallons
gallons
7 gallons
Depth to Water before Sampling: ce9 SD feet
Gallons
Time
Temp
(°C)
pH
Cond.
(US/cm)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
0
o9sS
18_57
(o.-41
12 3
1-(00
13b.
.q
55-
last.
l(a.
L, G G
114H
4 0(G
12.2
(0
6
q
Date of sample:
9 �p
Before Sampling
IDS
Iq
(o
MvD
a., oo
PZ 2--3
c� R-
E
Comments (weather conditions, odor, color, silt,, etc.),
r
\D [S/%�S C�(.l.I'i / L!/1 / ! ki,4,21,144
Signature: Date:_ fla��
QA/QC Sign 0 Date: 1 �/ a0 0�

Appendix C
Laboratory Analytical Reports and Chains of Custody

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
September 14, 2020
Van Burbach
Joyce Engineering -NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Butner Landfill Compliance
Pace Project No.: 92493082
Dear Van Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on August 28, 2020. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
/7j"4w'
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Gretta Eller, LaBella Associates, D.P.C.
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Butner Landfill Compliance
Pace Project No.: 92493082
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Butner Landfill Compliance
Pace Project No.: 92493082
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92493082001
3902-MW1R
Water
08/27/20 08:53
08/28/20 09:37
92493082002
3902-MW2R
Water
08/27/2014:29
08/28/20 09:37
92493082003
3902-MW3R
Water
08/27/2012:58
08/28/20 09:37
92493082004
3902-MW4
Water
08/27/20 12:10
08/28/20 09:37
92493082005
3902-MW5
Water
08/27/20 16:55
08/28/20 09:37
92493082006
3902-MW6
Water
08/27/2016:23
08/28/20 09:37
92493082007
3902-NES-1
Water
08/27/20 17:40
08/28/20 09:37
92493082008
3902-Field Blank
Water
08/27/20 18:00
08/28/20 09:37
92493082009
3902-Trip Blank
Water
08/27/20 00:00
08/28/20 09:37
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Butner Landfill Compliance
92493082
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92493082001
3902-MW1R
EPA 601OD
SH1
15
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
BSH
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92493082002
3902-MW2R
EPA 601OD
SH1
15
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
BSH
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92493082003
3902-MW3R
EPA 601OD
SH1
15
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
BSH
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92493082004
3902-MW4
EPA 601OD
SH1
14
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
BSH
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92493082005
3902-MW5
EPA 601OD
SH1
14
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
BSH
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92493082006
3902-MW6
EPA 601OD
SH1
14
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
BSH
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92493082007
3902-NES-1
EPA 601OD
SH1
2
PASI-A
EPA 8260D
BSH
4
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92493082008
3902-Field Blank
EPA 601OD
SH1
15
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
BSH
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92493082009
3902-Trip Blank
EPA 8260D
BSH
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
Butner Landfill Compliance
92493082
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92493082001
3902-MW1 R
EPA 601 OD
Barium
4.5J
ug/L
5.0
09/03/20 00:45
92493082002
3902-MW2R
EPA 601 OD
Barium
127
ug/L
5.0
09/03/20 00:55
EPA 601 OD
Cobalt
9.7
ug/L
5.0
09/03/20 00:55
EPA 601 OD
Nickel
99.1
ug/L
5.0
09/03/20 00:55
EPA 601 OD
Tin
27.6
ug/L
5.0
09/03/20 00:55
EPA 8260D
Benzene
1.9
ug/L
1.0
08/31/2018:51
EPA 8260D
Chlorobenzene
16.1
ug/L
1.0
08/31/2018:51
EPA 8260D
Chloroethane
0.87J
ug/L
1.0
08/31/2018:51 IK
EPA 8260D
1,2-Dichlorobenzene
1.2
ug/L
1.0
08/31/2018:51
EPA 8260D
1,4-Dichlorobenzene
2.1
ug/L
1.0
08/31/2018:51
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
113
ug/L
4.0
09/01/20 21:18
92493082003
3902-MW3R
EPA 601 OD
Barium
83.2
ug/L
5.0
09/03/20 00:58
EPA 601 OD
Copper
5.3
ug/L
5.0
09/03/20 00:58
EPA 601 OD
Nickel
19.5
ug/L
5.0
09/03/20 00:58
EPA 601 OD
Tin
5.1
ug/L
5.0
09/03/20 00:58
EPA 8260D
Benzene
0.49J
ug/L
1.0
09/01/2013:23
EPA 8260D
Chlorobenzene
17.5
ug/L
1.0
09/01/2013:23
EPA 8260D
Chloroethane
1.5
ug/L
1.0
09/01/2013:23 IK
EPA 8260D
1,2-Dichlorobenzene
1.3
ug/L
1.0
09/01/2013:23
EPA 8260D
1,4-Dichlorobenzene
1.4
ug/L
1.0
09/01/2013:23
EPA 8260D
Vinyl chloride
1.1
ug/L
1.0
09/01/20 13:23
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
50.0
ug/L
2.0
09/01/20 20:40
92493082004
3902-MW4
EPA 601 OD
Copper
13.5
ug/L
5.0
09/03/20 01:01
EPA 601 OD
Nickel
12.2
ug/L
5.0
09/03/20 01:01
EPA 601 OD
Vanadium
21.1
ug/L
5.0
09/03/20 01:01
EPA 8260D
Chlorobenzene
4.1
ug/L
1.0
08/31/2019:29
EPA 8260D
Chloroethane
1.1
ug/L
1.0
08/31/2019:29 IK
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
39.3
ug/L
2.0
09/01/20 20:59
92493082005
3902-MW5
EPA 601 OD
Barium
128
ug/L
5.0
09/03/20 01:05
EPA 601 OD
Cobalt
88.7
ug/L
5.0
09/03/20 01:05
EPA 601 OD
Copper
5.6
ug/L
5.0
09/03/20 01:05
EPA 601 OD
Nickel
18.1
ug/L
5.0
09/03/20 01:05
EPA 8260D
Chlorobenzene
0.32J
ug/L
1.0
08/31/2019:47
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
3.0
ug/L
2.0
09/01/20 19:43
92493082007
3902-NES-1
EPA 601 OD
Vanadium
6.8
ug/L
5.0
09/03/20 01:11
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 5 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92493082
Sample: 3902-MW1R Lab ID: 92493082001 Collected: 08/27/20 08:53 Received: 08/28/20 09:37 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
09/02/20 01:33
09/03/20 00:45
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
09/02/20 01:33
09/03/20 00:45
7440-38-2
Barium
4.5J
ug/L
5.0
3.5
1
09/02/20 01:33
09/03/20 00:45
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
09/02/20 01:33
09/03/20 00:45
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
09/02/20 01:33
09/03/20 00:45
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
09/02/20 01:33
09/03/20 00:45
7440-47-3
Cobalt
ND
ug/L
5.0
3.6
1
09/02/20 01:33
09/03/20 00:45
7440-48-4
Copper
ND
ug/L
5.0
4.3
1
09/02/20 01:33
09/03/20 00:45
7440-50-8
Lead
ND
ug/L
5.0
4.5
1
09/02/20 01:33
09/03/20 00:45
7439-92-1
Nickel
ND
ug/L
5.0
3.5
1
09/02/20 01:33
09/03/20 00:45
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
09/02/20 01:33
09/03/20 00:45
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
09/02/20 01:33
09/03/20 00:45
7440-22-4
Tin
ND
ug/L
5.0
4.7
1
09/02/20 01:33
09/03/20 00:45
7440-31-5
Vanadium
ND
ug/L
5.0
3.9
1
09/02/20 01:33
09/03/20 00:45
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
09/02/20 01:33
09/03/20 00:45
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.10
0.050
1
09/02/20 01:04
09/03/20 21:09
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
6.2
1
09/01/20 13:05
67-64-1
Acrylonitrile
ND
ug/L
10.0
0.90
1
09/01/20 13:05
107-13-1
Benzene
ND
ug/L
1.0
0.15
1
09/01/20 13:05
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.34
1
09/01/20 13:05
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.26
1
09/01/20 13:05
75-27-4
Bromoform
ND
ug/L
1.0
0.62
1
09/01/20 13:05
75-25-2
Bromomethane
ND
ug/L
2.0
0.62
1
09/01/20 13:05
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
3.3
1
09/01/20 13:05
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.40
1
09/01/20 13:05
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.22
1
09/01/20 13:05
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.23
1
09/01/20 13:05
108-90-7
Chloroethane
ND
ug/L
1.0
0.49
1
09/01/20 13:05
75-00-3
Chloroform
ND
ug/L
5.0
2.3
1
09/01/20 13:05
67-66-3
Chloromethane
ND
ug/L
1.0
0.39
1
09/01/20 13:05
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
0.26
1
09/01/20 13:05
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.41
1
09/01/20 13:05
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.26
1
09/01/20 13:05
106-93-4
Dibromomethane
ND
ug/L
1.0
0.46
1
09/01/20 13:05
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.29
1
09/01/20 13:05
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.26
1
09/01/20 13:05
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.54
1
09/01/20 13:05
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.27
1
09/01/20 13:05
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.34
1
09/01/20 13:05
107-06-2
REPORT OF
LABORATORY ANALYSIS
This report shall not be reproduced, except in
full,
Date: 09/14/2020 12:23 PM
without the written consent of Pace Analytical Services,
LLC.
IK
Page 6 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92493082
Sample: 3902-MW1R Lab ID: 92493082001 Collected: 08/27/20 08:53 Received: 08/28/20 09:37 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 09/14/2020 12:23 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.24
1
09/01/2013:05
75-35-4
ND
ug/L
1.0
0.29
1
09/01/2013:05
156-59-2
ND
ug/L
1.0
0.25
1
09/01/2013:05
156-60-5
ND
ug/L
1.0
0.19
1
09/01/2013:05
78-87-5
ND
ug/L
1.0
0.30
1
09/01 /20 13:05
10061-01-5
ND
ug/L
1.0
0.31
1
09/01 /20 13:05
10061-02-6
ND
ug/L
1.0
0.26
1
09/01 /20 13:05
100-41-4
ND
ug/L
5.0
0.57
1
09/01 /20 13:05
591-78-6
ND
ug/L
20.0
12.5
1
09/01/2013:05
74-88-4
ND
ug/L
5.0
3.7
1
09/01/2013:05
75-09-2
ND
ug/L
5.0
4.5
1
09/01/2013:05
108-10-1
ND
ug/L
1.0
0.27
1
09/01/2013:05
100-42-5
ND
ug/L
1.0
0.34
1
09/01/2013:05
630-20-6
ND
ug/L
1.0
0.22
1
09/01/2013:05
79-34-5
ND
ug/L
1.0
0.16
1
09/01/2013:05
127-18-4
ND
ug/L
1.0
0.24
1
09/01/2013:05
108-88-3
ND
ug/L
1.0
0.18
1
09/01 /20 13:05
71-55-6
ND
ug/L
1.0
0.24
1
09/01/2013:05
79-00-5
ND
ug/L
1.0
0.22
1
09/01 /20 13:05
79-01-6
ND
ug/L
1.0
0.31
1
09/01/2013:05
75-69-4
ND
ug/L
1.0
0.35
1
09/01/2013:05
96-18-4
ND
ug/L
2.0
1.4
1
09/01/2013:05
108-05-4
ND
ug/L
1.0
0.24
1
09/01 /20 13:05
75-01-4
ND
ug/L
1.0
0.63
1
09/01/2013:05
1330-20-7
99
%
70-130
1
09/01 /20 13:05
460-00-4
96
%
70-130
1
09/01 /20 13:05
17060-07-0
101
%
70-130
1
09/01 /20 13:05
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
ND
ug/L
2.0
1.2
1
09/01/2019:24
123-91-1
100
%
50-150
1
09/01 /20 19:24
17060-07-0
101
%
50-150
1
09/01 /20 19:24
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92493082
Sample: 3902-MW2R Lab ID: 92493082002 Collected: 08/27/20 14:29 Received: 08/28/20 09:37 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
09/02/20 01:33
09/03/20 00:55
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
09/02/20 01:33
09/03/20 00:55
7440-38-2
Barium
127
ug/L
5.0
3.5
1
09/02/20 01:33
09/03/20 00:55
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
09/02/20 01:33
09/03/20 00:55
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
09/02/20 01:33
09/03/20 00:55
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
09/02/20 01:33
09/03/20 00:55
7440-47-3
Cobalt
9.7
ug/L
5.0
3.6
1
09/02/20 01:33
09/03/20 00:55
7440-48-4
Copper
ND
ug/L
5.0
4.3
1
09/02/20 01:33
09/03/20 00:55
7440-50-8
Lead
ND
ug/L
5.0
4.5
1
09/02/20 01:33
09/03/20 00:55
7439-92-1
Nickel
99.1
ug/L
5.0
3.5
1
09/02/20 01:33
09/03/20 00:55
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
09/02/20 01:33
09/03/20 00:55
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
09/02/20 01:33
09/03/20 00:55
7440-22-4
Tin
27.6
ug/L
5.0
4.7
1
09/02/20 01:33
09/03/20 00:55
7440-31-5
Vanadium
ND
ug/L
5.0
3.9
1
09/02/20 01:33
09/03/20 00:55
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
09/02/20 01:33
09/03/20 00:55
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.10
0.050
1
09/02/20 01:04
09/03/20 21:13
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
6.2
1
08/31/20 18:51
67-64-1
Acrylonitrile
ND
ug/L
10.0
0.90
1
08/31/20 18:51
107-13-1
Benzene
1.9
ug/L
1.0
0.15
1
08/31/20 18:51
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.34
1
08/31/20 18:51
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.26
1
08/31/20 18:51
75-27-4
Bromoform
ND
ug/L
1.0
0.62
1
08/31/20 18:51
75-25-2
Bromomethane
ND
ug/L
2.0
0.62
1
08/31/20 18:51
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
3.3
1
08/31/20 18:51
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.40
1
08/31/20 18:51
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.22
1
08/31/20 18:51
56-23-5
Chlorobenzene
16.1
ug/L
1.0
0.23
1
08/31/20 18:51
108-90-7
Chloroethane
0.87J
ug/L
1.0
0.49
1
08/31/20 18:51
75-00-3
Chloroform
ND
ug/L
5.0
2.3
1
08/31/20 18:51
67-66-3
Chloromethane
ND
ug/L
1.0
0.39
1
08/31/20 18:51
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
0.26
1
08/31/20 18:51
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.41
1
08/31/20 18:51
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.26
1
08/31/20 18:51
106-93-4
Dibromomethane
ND
ug/L
1.0
0.46
1
08/31/20 18:51
74-95-3
1,2-Dichlorobenzene
1.2
ug/L
1.0
0.29
1
08/31/20 18:51
95-50-1
1,4-Dichlorobenzene
2.1
ug/L
1.0
0.26
1
08/31/20 18:51
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.54
1
08/31/20 18:51
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.27
1
08/31/20 18:51
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.34
1
08/31/20 18:51
107-06-2
REPORT OF
LABORATORY ANALYSIS
This report shall not be reproduced, except in
full,
Date: 09/14/2020 12:23 PM
without the written consent of Pace Analytical Services,
LLC.
IK
Page 8 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92493082
Sample: 3902-MW2R Lab ID: 92493082002 Collected: 08/27/20 14:29 Received: 08/28/20 09:37 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 09/14/2020 12:23 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.24
1
08/31/2018:51
75-35-4
ND
ug/L
1.0
0.29
1
08/31/2018:51
156-59-2
ND
ug/L
1.0
0.25
1
08/31/2018:51
156-60-5
ND
ug/L
1.0
0.19
1
08/31/2018:51
78-87-5
ND
ug/L
1.0
0.30
1
08/31 /20 18:51
10061-01-5
ND
ug/L
1.0
0.31
1
08/31 /20 18:51
10061-02-6
ND
ug/L
1.0
0.26
1
08/31 /20 18:51
100-41-4
ND
ug/L
5.0
0.57
1
08/31 /20 18:51
591-78-6
ND
ug/L
20.0
12.5
1
08/31/2018:51
74-88-4
ND
ug/L
5.0
3.7
1
08/31/2018:51
75-09-2
ND
ug/L
5.0
4.5
1
08/31/2018:51
108-10-1
ND
ug/L
1.0
0.27
1
08/31/2018:51
100-42-5
ND
ug/L
1.0
0.34
1
08/31/2018:51
630-20-6
ND
ug/L
1.0
0.22
1
08/31/2018:51
79-34-5
ND
ug/L
1.0
0.16
1
08/31/2018:51
127-18-4
ND
ug/L
1.0
0.24
1
08/31/2018:51
108-88-3
ND
ug/L
1.0
0.18
1
08/31 /20 18:51
71-55-6
ND
ug/L
1.0
0.24
1
08/31/2018:51
79-00-5
ND
ug/L
1.0
0.22
1
08/31 /20 18:51
79-01-6
ND
ug/L
1.0
0.31
1
08/31/2018:51
75-69-4
ND
ug/L
1.0
0.35
1
08/31/2018:51
96-18-4
ND
ug/L
2.0
1.4
1
08/31/2018:51
108-05-4
ND
ug/L
1.0
0.24
1
08/31 /20 18:51
75-01-4
ND
ug/L
1.0
0.63
1
08/31/2018:51
1330-20-7
98
%
70-130
1
08/31 /20 18:51
460-00-4
98
%
70-130
1
08/31 /20 18:51
17060-07-0
101
%
70-130
1
08/31 /20 18:51
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
113
ug/L
4.0
2.3
2
09/01/20 21:18
123-91-1
101
%
50-150
2
09/01 /20 21:18
17060-07-0
96
%
50-150
2
09/01 /20 21:18
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92493082
Sample: 3902-MW3R Lab ID: 92493082003 Collected: 08/27/20 12:58 Received: 08/28/20 09:37 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
09/02/20 01:33
09/03/20 00:58
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
09/02/20 01:33
09/03/20 00:58
7440-38-2
Barium
83.2
ug/L
5.0
3.5
1
09/02/20 01:33
09/03/20 00:58
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
09/02/20 01:33
09/03/20 00:58
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
09/02/20 01:33
09/03/20 00:58
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
09/02/20 01:33
09/03/20 00:58
7440-47-3
Cobalt
ND
ug/L
5.0
3.6
1
09/02/20 01:33
09/03/20 00:58
7440-48-4
Copper
5.3
ug/L
5.0
4.3
1
09/02/20 01:33
09/03/20 00:58
7440-50-8
Lead
ND
ug/L
5.0
4.5
1
09/02/20 01:33
09/03/20 00:58
7439-92-1
Nickel
19.5
ug/L
5.0
3.5
1
09/02/20 01:33
09/03/20 00:58
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
09/02/20 01:33
09/03/20 00:58
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
09/02/20 01:33
09/03/20 00:58
7440-22-4
Tin
5.1
ug/L
5.0
4.7
1
09/02/20 01:33
09/03/20 00:58
7440-31-5
Vanadium
ND
ug/L
5.0
3.9
1
09/02/20 01:33
09/03/20 00:58
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
09/02/20 01:33
09/03/20 00:58
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.10
0.050
1
09/02/20 01:04
09/03/20 21:17
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
6.2
1
09/01/20 13:23
67-64-1
Acrylonitrile
ND
ug/L
10.0
0.90
1
09/01/20 13:23
107-13-1
Benzene
0.49J
ug/L
1.0
0.15
1
09/01/20 13:23
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.34
1
09/01/20 13:23
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.26
1
09/01/20 13:23
75-27-4
Bromoform
ND
ug/L
1.0
0.62
1
09/01/20 13:23
75-25-2
Bromomethane
ND
ug/L
2.0
0.62
1
09/01/20 13:23
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
3.3
1
09/01/20 13:23
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.40
1
09/01/20 13:23
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.22
1
09/01/20 13:23
56-23-5
Chlorobenzene
17.5
ug/L
1.0
0.23
1
09/01/20 13:23
108-90-7
Chloroethane
1.5
ug/L
1.0
0.49
1
09/01/20 13:23
75-00-3
Chloroform
ND
ug/L
5.0
2.3
1
09/01/20 13:23
67-66-3
Chloromethane
ND
ug/L
1.0
0.39
1
09/01/20 13:23
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
0.26
1
09/01/20 13:23
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.41
1
09/01/20 13:23
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.26
1
09/01/20 13:23
106-93-4
Dibromomethane
ND
ug/L
1.0
0.46
1
09/01/20 13:23
74-95-3
1,2-Dichlorobenzene
1.3
ug/L
1.0
0.29
1
09/01/20 13:23
95-50-1
1,4-Dichlorobenzene
1.4
ug/L
1.0
0.26
1
09/01/20 13:23
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.54
1
09/01/20 13:23
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.27
1
09/01/20 13:23
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.34
1
09/01/20 13:23
107-06-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/14/2020 12:23 PM without the written consent of Pace Analytical Services, LLC.
IK
Page 10 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92493082
Sample: 3902-MW3R Lab ID: 92493082003 Collected: 08/27/20 12:58 Received: 08/28/20 09:37 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 09/14/2020 12:23 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.24
1
09/01/2013:23
75-35-4
ND
ug/L
1.0
0.29
1
09/01/2013:23
156-59-2
ND
ug/L
1.0
0.25
1
09/01/2013:23
156-60-5
ND
ug/L
1.0
0.19
1
09/01/2013:23
78-87-5
ND
ug/L
1.0
0.30
1
09/01 /20 13:23
10061-01-5
ND
ug/L
1.0
0.31
1
09/01 /20 13:23
10061-02-6
ND
ug/L
1.0
0.26
1
09/01 /20 13:23
100-41-4
ND
ug/L
5.0
0.57
1
09/01 /20 13:23
591-78-6
ND
ug/L
20.0
12.5
1
09/01/2013:23
74-88-4 v2
ND
ug/L
5.0
3.7
1
09/01/2013:23
75-09-2
ND
ug/L
5.0
4.5
1
09/01/2013:23
108-10-1
ND
ug/L
1.0
0.27
1
09/01/2013:23
100-42-5
ND
ug/L
1.0
0.34
1
09/01/2013:23
630-20-6
ND
ug/L
1.0
0.22
1
09/01/2013:23
79-34-5
ND
ug/L
1.0
0.16
1
09/01/2013:23
127-18-4
ND
ug/L
1.0
0.24
1
09/01/2013:23
108-88-3
ND
ug/L
1.0
0.18
1
09/01 /20 13:23
71-55-6
ND
ug/L
1.0
0.24
1
09/01/2013:23
79-00-5
ND
ug/L
1.0
0.22
1
09/01 /20 13:23
79-01-6
ND
ug/L
1.0
0.31
1
09/01/2013:23
75-69-4
ND
ug/L
1.0
0.35
1
09/01/2013:23
96-18-4
ND
ug/L
2.0
1.4
1
09/01/2013:23
108-05-4
1.1
ug/L
1.0
0.24
1
09/01/2013:23
75-01-4
ND
ug/L
1.0
0.63
1
09/01/2013:23
1330-20-7
99
%
70-130
1
09/01 /20 13:23
460-00-4
97
%
70-130
1
09/01 /20 13:23
17060-07-0
101
%
70-130
1
09/01 /20 13:23
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
50.0
ug/L
2.0
1.2
1
09/01/20 20:40
123-91-1
101
%
50-150
1
09/01 /20 20:40
17060-07-0
98
%
50-150
1
09/01 /20 20:40
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92493082
Sample: 3902-MW4 Lab ID: 92493082004 Collected: 08/27/20 12:10 Received: 08/28/20 09:37 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
09/02/20 01:33
09/03/20 01:01
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
09/02/20 01:33
09/03/20 01:01
7440-38-2
Barium
ND
ug/L
5.0
3.5
1
09/02/20 01:33
09/03/20 01:01
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
09/02/20 01:33
09/03/20 01:01
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
09/02/20 01:33
09/03/20 01:01
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
09/02/20 01:33
09/03/20 01:01
7440-47-3
Cobalt
ND
ug/L
5.0
3.6
1
09/02/20 01:33
09/03/20 01:01
7440-48-4
Copper
13.5
ug/L
5.0
4.3
1
09/02/20 01:33
09/03/20 01:01
7440-50-8
Lead
ND
ug/L
5.0
4.5
1
09/02/20 01:33
09/03/20 01:01
7439-92-1
Nickel
12.2
ug/L
5.0
3.5
1
09/02/20 01:33
09/03/20 01:01
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
09/02/20 01:33
09/03/20 01:01
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
09/02/20 01:33
09/03/20 01:01
7440-22-4
Vanadium
21.1
ug/L
5.0
3.9
1
09/02/20 01:33
09/03/20 01:01
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
09/02/20 01:33
09/03/20 01:01
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.10
0.050
1
09/02/20 01:04
09/03/20 21:20
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
6.2
1
08/31/20 19:29
67-64-1
Acrylonitrile
ND
ug/L
10.0
0.90
1
08/31/20 19:29
107-13-1
Benzene
ND
ug/L
1.0
0.15
1
08/31/20 19:29
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.34
1
08/31/20 19:29
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.26
1
08/31/20 19:29
75-27-4
Bromoform
ND
ug/L
1.0
0.62
1
08/31/20 19:29
75-25-2
Bromomethane
ND
ug/L
2.0
0.62
1
08/31/20 19:29
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
3.3
1
08/31/20 19:29
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.40
1
08/31/20 19:29
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.22
1
08/31/20 19:29
56-23-5
Chlorobenzene
4.1
ug/L
1.0
0.23
1
08/31/20 19:29
108-90-7
Chloroethane
1.1
ug/L
1.0
0.49
1
08/31/20 19:29
75-00-3
Chloroform
ND
ug/L
5.0
2.3
1
08/31/20 19:29
67-66-3
Chloromethane
ND
ug/L
1.0
0.39
1
08/31/20 19:29
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
0.26
1
08/31/20 19:29
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.41
1
08/31/20 19:29
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.26
1
08/31/20 19:29
106-93-4
Dibromomethane
ND
ug/L
1.0
0.46
1
08/31/20 19:29
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.29
1
08/31/20 19:29
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.26
1
08/31/20 19:29
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.54
1
08/31/20 19:29
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.27
1
08/31/20 19:29
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.34
1
08/31/20 19:29
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.24
1
08/31/20 19:29
75-35-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/14/2020 12:23 PM without the written consent of Pace Analytical Services, LLC.
IK
Page 12 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92493082
Sample: 3902-MW4 Lab ID: 92493082004 Collected: 08/27/20 12:10 Received: 08/28/20 09:37 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 09/14/2020 12:23 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.29
1
08/31/2019:29
156-59-2
ND
ug/L
1.0
0.25
1
08/31/2019:29
156-60-5
ND
ug/L
1.0
0.19
1
08/31/2019:29
78-87-5
ND
ug/L
1.0
0.30
1
08/31 /20 19:29
10061-01-5
ND
ug/L
1.0
0.31
1
08/31 /20 19:29
10061-02-6
ND
ug/L
1.0
0.26
1
08/31 /20 19:29
100-41-4
ND
ug/L
5.0
0.57
1
08/31 /20 19:29
591-78-6
ND
ug/L
20.0
12.5
1
08/31/2019:29
74-88-4
ND
ug/L
5.0
3.7
1
08/31/2019:29
75-09-2
ND
ug/L
5.0
4.5
1
08/31/2019:29
108-10-1
ND
ug/L
1.0
0.27
1
08/31/2019:29
100-42-5
ND
ug/L
1.0
0.34
1
08/31/2019:29
630-20-6
ND
ug/L
1.0
0.22
1
08/31/2019:29
79-34-5
ND
ug/L
1.0
0.16
1
08/31/2019:29
127-18-4
ND
ug/L
1.0
0.24
1
08/31/2019:29
108-88-3
ND
ug/L
1.0
0.18
1
08/31 /20 19:29
71-55-6
ND
ug/L
1.0
0.24
1
08/31/2019:29
79-00-5
ND
ug/L
1.0
0.22
1
08/31 /20 19:29
79-01-6
ND
ug/L
1.0
0.31
1
08/31/2019:29
75-69-4
ND
ug/L
1.0
0.35
1
08/31/2019:29
96-18-4
ND
ug/L
2.0
1.4
1
08/31/2019:29
108-05-4
ND
ug/L
1.0
0.24
1
08/31 /20 19:29
75-01-4
ND
ug/L
1.0
0.63
1
08/31/2019:29
1330-20-7
99
%
70-130
1
08/31 /20 19:29
460-00-4
98
%
70-130
1
08/31 /20 19:29
17060-07-0
101
%
70-130
1
08/31 /20 19:29
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
39.3
ug/L
2.0
1.2
1
09/01/20 20:59
123-91-1
102
%
50-150
1
09/01 /20 20:59
17060-07-0
97
%
50-150
1
09/01 /20 20:59
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92493082
Sample: 3902-MW5 Lab ID: 92493082005 Collected: 08/27/20 16:55 Received: 08/28/20 09:37 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
09/02/20 01:33
09/03/20 01:05
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
09/02/20 01:33
09/03/20 01:05
7440-38-2
Barium
128
ug/L
5.0
3.5
1
09/02/20 01:33
09/03/20 01:05
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
09/02/20 01:33
09/03/20 01:05
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
09/02/20 01:33
09/03/20 01:05
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
09/02/20 01:33
09/03/20 01:05
7440-47-3
Cobalt
88.7
ug/L
5.0
3.6
1
09/02/20 01:33
09/03/20 01:05
7440-48-4
Copper
5.6
ug/L
5.0
4.3
1
09/02/20 01:33
09/03/20 01:05
7440-50-8
Lead
ND
ug/L
5.0
4.5
1
09/02/20 01:33
09/03/20 01:05
7439-92-1
Nickel
18.1
ug/L
5.0
3.5
1
09/02/20 01:33
09/03/20 01:05
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
09/02/20 01:33
09/03/20 01:05
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
09/02/20 01:33
09/03/20 01:05
7440-22-4
Vanadium
ND
ug/L
5.0
3.9
1
09/02/20 01:33
09/03/20 01:05
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
09/02/20 01:33
09/03/20 01:05
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.10
0.050
1
09/02/20 01:04
09/03/20 21:24
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
6.2
1
08/31/20 19:47
67-64-1
Acrylonitrile
ND
ug/L
10.0
0.90
1
08/31/20 19:47
107-13-1
Benzene
ND
ug/L
1.0
0.15
1
08/31/20 19:47
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.34
1
08/31/20 19:47
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.26
1
08/31/20 19:47
75-27-4
Bromoform
ND
ug/L
1.0
0.62
1
08/31/20 19:47
75-25-2
Bromomethane
ND
ug/L
2.0
0.62
1
08/31/20 19:47
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
3.3
1
08/31/20 19:47
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.40
1
08/31/20 19:47
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.22
1
08/31/20 19:47
56-23-5
Chlorobenzene
0.32J
ug/L
1.0
0.23
1
08/31/20 19:47
108-90-7
Chloroethane
ND
ug/L
1.0
0.49
1
08/31/20 19:47
75-00-3
Chloroform
ND
ug/L
5.0
2.3
1
08/31/20 19:47
67-66-3
Chloromethane
ND
ug/L
1.0
0.39
1
08/31/20 19:47
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
0.26
1
08/31/20 19:47
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.41
1
08/31/20 19:47
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.26
1
08/31/20 19:47
106-93-4
Dibromomethane
ND
ug/L
1.0
0.46
1
08/31/20 19:47
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.29
1
08/31/20 19:47
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.26
1
08/31/20 19:47
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.54
1
08/31/20 19:47
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.27
1
08/31/20 19:47
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.34
1
08/31/20 19:47
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.24
1
08/31/20 19:47
75-35-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/14/2020 12:23 PM without the written consent of Pace Analytical Services, LLC.
IK
Page 14 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92493082
Sample: 3902-MW5 Lab ID: 92493082005 Collected: 08/27/20 16:55 Received: 08/28/20 09:37 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 09/14/2020 12:23 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.29
1
08/31/2019:47
156-59-2
ND
ug/L
1.0
0.25
1
08/31/2019:47
156-60-5
ND
ug/L
1.0
0.19
1
08/31/2019:47
78-87-5
ND
ug/L
1.0
0.30
1
08/31 /20 19:47
10061-01-5
ND
ug/L
1.0
0.31
1
08/31 /20 19:47
10061-02-6
ND
ug/L
1.0
0.26
1
08/31 /20 19:47
100-41-4
ND
ug/L
5.0
0.57
1
08/31 /20 19:47
591-78-6
ND
ug/L
20.0
12.5
1
08/31/2019:47
74-88-4
ND
ug/L
5.0
3.7
1
08/31/2019:47
75-09-2
ND
ug/L
5.0
4.5
1
08/31/2019:47
108-10-1
ND
ug/L
1.0
0.27
1
08/31/2019:47
100-42-5
ND
ug/L
1.0
0.34
1
08/31/2019:47
630-20-6
ND
ug/L
1.0
0.22
1
08/31/2019:47
79-34-5
ND
ug/L
1.0
0.16
1
08/31/2019:47
127-18-4
ND
ug/L
1.0
0.24
1
08/31/2019:47
108-88-3
ND
ug/L
1.0
0.18
1
08/31 /20 19:47
71-55-6
ND
ug/L
1.0
0.24
1
08/31/2019:47
79-00-5
ND
ug/L
1.0
0.22
1
08/31 /20 19:47
79-01-6
ND
ug/L
1.0
0.31
1
08/31/2019:47
75-69-4
ND
ug/L
1.0
0.35
1
08/31/2019:47
96-18-4
ND
ug/L
2.0
1.4
1
08/31/2019:47
108-05-4
ND
ug/L
1.0
0.24
1
08/31 /20 19:47
75-01-4
ND
ug/L
1.0
0.63
1
08/31/2019:47
1330-20-7
99
%
70-130
1
08/31 /20 19:47
460-00-4
99
%
70-130
1
08/31 /20 19:47
17060-07-0
101
%
70-130
1
08/31 /20 19:47
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
3.0
ug/L
2.0
1.2
1
09/01/2019:43
123-91-1
105
%
50-150
1
09/01 /20 19:43
17060-07-0
99
%
50-150
1
09/01 /20 19:43
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 15 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92493082
Sample: 3902-MW6 Lab ID: 92493082006 Collected: 08/27/20 16:23 Received: 08/28/20 09:37 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
09/02/20 01:33
09/03/20 01:08
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
09/02/20 01:33
09/03/20 01:08
7440-38-2
Barium
ND
ug/L
5.0
3.5
1
09/02/20 01:33
09/03/20 01:08
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
09/02/20 01:33
09/03/20 01:08
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
09/02/20 01:33
09/03/20 01:08
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
09/02/20 01:33
09/03/20 01:08
7440-47-3
Cobalt
ND
ug/L
5.0
3.6
1
09/02/20 01:33
09/03/20 01:08
7440-48-4
Copper
ND
ug/L
5.0
4.3
1
09/02/20 01:33
09/03/20 01:08
7440-50-8
Lead
ND
ug/L
5.0
4.5
1
09/02/20 01:33
09/03/20 01:08
7439-92-1
Nickel
ND
ug/L
5.0
3.5
1
09/02/20 01:33
09/03/20 01:08
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
09/02/20 01:33
09/03/20 01:08
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
09/02/20 01:33
09/03/20 01:08
7440-22-4
Vanadium
ND
ug/L
5.0
3.9
1
09/02/20 01:33
09/03/20 01:08
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
09/02/20 01:33
09/03/20 01:08
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.10
0.050
1
09/02/20 01:04
09/03/20 21:28
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
6.2
1
08/31/20 20:05
67-64-1
Acrylonitrile
ND
ug/L
10.0
0.90
1
08/31/20 20:05
107-13-1
Benzene
ND
ug/L
1.0
0.15
1
08/31/20 20:05
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.34
1
08/31/20 20:05
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.26
1
08/31/20 20:05
75-27-4
Bromoform
ND
ug/L
1.0
0.62
1
08/31/20 20:05
75-25-2
Bromomethane
ND
ug/L
2.0
0.62
1
08/31/20 20:05
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
3.3
1
08/31/20 20:05
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.40
1
08/31/20 20:05
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.22
1
08/31/20 20:05
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.23
1
08/31/20 20:05
108-90-7
Chloroethane
ND
ug/L
1.0
0.49
1
08/31/20 20:05
75-00-3
Chloroform
ND
ug/L
5.0
2.3
1
08/31/20 20:05
67-66-3
Chloromethane
ND
ug/L
1.0
0.39
1
08/31/20 20:05
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
0.26
1
08/31/20 20:05
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.41
1
08/31/20 20:05
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.26
1
08/31/20 20:05
106-93-4
Dibromomethane
ND
ug/L
1.0
0.46
1
08/31/20 20:05
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.29
1
08/31/20 20:05
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.26
1
08/31/20 20:05
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.54
1
08/31/20 20:05
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.27
1
08/31/20 20:05
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.34
1
08/31/20 20:05
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.24
1
08/31/20 20:05
75-35-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/14/2020 12:23 PM without the written consent of Pace Analytical Services, LLC.
IK
Page 16 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92493082
Sample: 3902-MW6 Lab ID: 92493082006 Collected: 08/27/20 16:23 Received: 08/28/20 09:37 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 09/14/2020 12:23 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.29
1
08/31/20 20:05
156-59-2
ND
ug/L
1.0
0.25
1
08/31/20 20:05
156-60-5
ND
ug/L
1.0
0.19
1
08/31/20 20:05
78-87-5
ND
ug/L
1.0
0.30
1
08/31/20 20:05
10061-01-5
ND
ug/L
1.0
0.31
1
08/31/20 20:05
10061-02-6
ND
ug/L
1.0
0.26
1
08/31/20 20:05
100-41-4
ND
ug/L
5.0
0.57
1
08/31/20 20:05
591-78-6
ND
ug/L
20.0
12.5
1
08/31/20 20:05
74-88-4
ND
ug/L
5.0
3.7
1
08/31/20 20:05
75-09-2
ND
ug/L
5.0
4.5
1
08/31/20 20:05
108-10-1
ND
ug/L
1.0
0.27
1
08/31/20 20:05
100-42-5
ND
ug/L
1.0
0.34
1
08/31/20 20:05
630-20-6
ND
ug/L
1.0
0.22
1
08/31/20 20:05
79-34-5
ND
ug/L
1.0
0.16
1
08/31/20 20:05
127-18-4
ND
ug/L
1.0
0.24
1
08/31/20 20:05
108-88-3
ND
ug/L
1.0
0.18
1
08/31/20 20:05
71-55-6
ND
ug/L
1.0
0.24
1
08/31/20 20:05
79-00-5
ND
ug/L
1.0
0.22
1
08/31/20 20:05
79-01-6
ND
ug/L
1.0
0.31
1
08/31/20 20:05
75-69-4
ND
ug/L
1.0
0.35
1
08/31/20 20:05
96-18-4
ND
ug/L
2.0
1.4
1
08/31/20 20:05
108-05-4
ND
ug/L
1.0
0.24
1
08/31/20 20:05
75-01-4
ND
ug/L
1.0
0.63
1
08/31/20 20:05
1330-20-7
100
%
70-130
1
08/31/20 20:05
460-00-4
98
%
70-130
1
08/31/20 20:05
17060-07-0
101
%
70-130
1
08/31/20 20:05
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
ND
ug/L
2.0
1.2
1
09/01/20 20:02
123-91-1
100
%
50-150
1
09/01 /20 20:02
17060-07-0
99
%
50-150
1
09/01 /20 20:02
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 17 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92493082
Sample: 3902-NES-1
Lab ID: 92493082007 Collected:
08/27/20 17:40
Received: 08/28/20 09:37 Matrix: Water
Report
Parameters
Results Units Limit
MDL DF
Prepared
Analyzed
CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Cobalt
ND ug/L 5.0
3.6 1
09/02/20 01:33
09/03/20 01:11
7440-48-4
Vanadium
6.8 ug/L 5.0
3.9 1
09/02/20 01:33
09/03/20 01:11
7440-62-2
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Benzene
ND ug/L 1.0
0.15 1
08/31/20 20:23
71-43-2
Surrogates
4-Bromofluorobenzene (S)
100 % 70-130
1
08/31/20 20:23
460-00-4
1,2-Dichloroethane-d4 (S)
98 % 70-130
1
08/31/20 20:23
17060-07-0
Toluene-d8 (S)
101 % 70-130
1
08/31/20 20:23
2037-26-5
8260D MSV SIM
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1,4-Dioxane (p-Dioxane)
ND ug/L 2.0
1.2 1
09/01/20 20:21
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
101 % 50-150
1
09/01/20 20:21
17060-07-0
Toluene-d8 (S)
99 % 50-150
1
09/01/20 20:21
2037-26-5
Date: 09/14/2020 12:23 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 18 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92493082
Sample: 3902-Field Blank Lab ID: 92493082008 Collected: 08/27/20 18:00 Received: 08/28/20 09:37 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
09/02/20 01:33
09/03/20 01:14
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
09/02/20 01:33
09/03/20 01:14
7440-38-2
Barium
ND
ug/L
5.0
3.5
1
09/02/20 01:33
09/03/20 01:14
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
09/02/20 01:33
09/03/20 01:14
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
09/02/20 01:33
09/03/20 01:14
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
09/02/20 01:33
09/03/20 01:14
7440-47-3
Cobalt
ND
ug/L
5.0
3.6
1
09/02/20 01:33
09/03/20 01:14
7440-48-4
Copper
ND
ug/L
5.0
4.3
1
09/02/20 01:33
09/03/20 01:14
7440-50-8
Lead
ND
ug/L
5.0
4.5
1
09/02/20 01:33
09/03/20 01:14
7439-92-1
Nickel
ND
ug/L
5.0
3.5
1
09/02/20 01:33
09/03/20 01:14
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
09/02/20 01:33
09/03/20 01:14
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
09/02/20 01:33
09/03/20 01:14
7440-22-4
Tin
ND
ug/L
5.0
4.7
1
09/02/20 01:33
09/03/20 01:14
7440-31-5
Vanadium
ND
ug/L
5.0
3.9
1
09/02/20 01:33
09/03/20 01:14
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
09/02/20 01:33
09/03/20 01:14
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.10
0.050
1
09/02/20 01:04
09/03/20 21:32
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
6.2
1
09/01/20 11:52
67-64-1
Acrylonitrile
ND
ug/L
10.0
0.90
1
09/01/20 11:52
107-13-1
Benzene
ND
ug/L
1.0
0.15
1
09/01/20 11:52
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.34
1
09/01/20 11:52
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.26
1
09/01/20 11:52
75-27-4
Bromoform
ND
ug/L
1.0
0.62
1
09/01/20 11:52
75-25-2
Bromomethane
ND
ug/L
2.0
0.62
1
09/01/20 11:52
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
3.3
1
09/01/20 11:52
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.40
1
09/01/20 11:52
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.22
1
09/01/20 11:52
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.23
1
09/01/20 11:52
108-90-7
Chloroethane
ND
ug/L
1.0
0.49
1
09/01/20 11:52
75-00-3
Chloroform
ND
ug/L
5.0
2.3
1
09/01/20 11:52
67-66-3
Chloromethane
ND
ug/L
1.0
0.39
1
09/01/20 11:52
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
0.26
1
09/01/20 11:52
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.41
1
09/01/20 11:52
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.26
1
09/01/20 11:52
106-93-4
Dibromomethane
ND
ug/L
1.0
0.46
1
09/01/20 11:52
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.29
1
09/01/20 11:52
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.26
1
09/01/20 11:52
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.54
1
09/01/20 11:52
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.27
1
09/01/20 11:52
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.34
1
09/01/20 11:52
107-06-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/14/2020 12:23 PM without the written consent of Pace Analytical Services, LLC.
IK
Page 19 of 39

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92493082
Sample: 3902-Field Blank Lab ID: 92493082008 Collected: 08/27/20 18:00 Received: 08/28/20 09:37 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 09/14/2020 12:23 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.24
1
09/01/2011:52
75-35-4
ND
ug/L
1.0
0.29
1
09/01/2011:52
156-59-2
ND
ug/L
1.0
0.25
1
09/01/2011:52
156-60-5
ND
ug/L
1.0
0.19
1
09/01/2011:52
78-87-5
ND
ug/L
1.0
0.30
1
09/01 /20 11:52
10061-01-5
ND
ug/L
1.0
0.31
1
09/01 /20 11:52
10061-02-6
ND
ug/L
1.0
0.26
1
09/01 /20 11:52
100-41-4
ND
ug/L
5.0
0.57
1
09/01 /20 11:52
591-78-6
ND
ug/L
20.0
12.5
1
09/01/2011:52
74-88-4 v2
ND
ug/L
5.0
3.7
1
09/01/2011:52
75-09-2
ND
ug/L
5.0
4.5
1
09/01/2011:52
108-10-1
ND
ug/L
1.0
0.27
1
09/01/2011:52
100-42-5
ND
ug/L
1.0
0.34
1
09/01/2011:52
630-20-6
ND
ug/L
1.0
0.22
1
09/01/2011:52
79-34-5
ND
ug/L
1.0
0.16
1
09/01/2011:52
127-18-4
ND
ug/L
1.0
0.24
1
09/01/2011:52
108-88-3
ND
ug/L
1.0
0.18
1
09/01 /20 11:52
71-55-6
ND
ug/L
1.0
0.24
1
09/01/2011:52
79-00-5
ND
ug/L
1.0
0.22
1
09/01 /20 11:52
79-01-6
ND
ug/L
1.0
0.31
1
09/01/2011:52
75-69-4
ND
ug/L
1.0
0.35
1
09/01/2011:52
96-18-4
ND
ug/L
2.0
1.4
1
09/01/2011:52
108-05-4
ND
ug/L
1.0
0.24
1
09/01 /20 11:52
75-01-4
ND
ug/L
1.0
0.63
1
09/01/2011:52
1330-20-7
98
%
70-130
1
09/01 /20 11:52
460-00-4
98
%
70-130
1
09/01 /20 11:52
17060-07-0
102
%
70-130
1
09/01 /20 11:52
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
ND
ug/L
2.0
1.2
1
09/01/2018:46
123-91-1
102
%
50-150
1
09/01 /20 18:46
17060-07-0
100
%
50-150
1
09/01 /20 18:46
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 20 of 39

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92493082
Sample: 3902-Trip Blank Lab ID: 92493082009 Collected: 08/27/20 00:00 Received: 08/28/20 09:37 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Date: 09/14/2020 12:23 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
6.2
1
08/31/2016:41
67-64-1
ND
ug/L
10.0
0.90
1
08/31/2016:41
107-13-1
ND
ug/L
1.0
0.15
1
08/31 /20 16:41
71-43-2
ND
ug/L
1.0
0.34
1
08/31/2016:41
74-97-5
ND
ug/L
1.0
0.26
1
08/31/2016:41
75-27-4
ND
ug/L
1.0
0.62
1
08/31/2016:41
75-25-2
ND
ug/L
2.0
0.62
1
08/31/2016:41
74-83-9
ND
ug/L
5.0
3.3
1
08/31/2016:41
78-93-3
ND
ug/L
2.0
0.40
1
08/31/2016:41
75-15-0
ND
ug/L
1.0
0.22
1
08/31/2016:41
56-23-5
ND
ug/L
1.0
0.23
1
08/31/2016:41
108-90-7
ND
ug/L
1.0
0.49
1
08/31/2016:41
75-00-3
ND
ug/L
5.0
2.3
1
08/31/2016:41
67-66-3
ND
ug/L
1.0
0.39
1
08/31/2016:41
74-87-3
ND
ug/L
5.0
0.26
1
08/31/2016:41
96-12-8
ND
ug/L
1.0
0.41
1
08/31/2016:41
124-48-1
ND
ug/L
1.0
0.26
1
08/31/2016:41
106-93-4
ND
ug/L
1.0
0.46
1
08/31/2016:41
74-95-3
ND
ug/L
1.0
0.29
1
08/31/2016:41
95-50-1
ND
ug/L
1.0
0.26
1
08/31/2016:41
106-46-7
ND
ug/L
1.0
0.54
1
08/31/2016:41
110-57-6
ND
ug/L
1.0
0.27
1
08/31/2016:41
75-34-3
ND
ug/L
1.0
0.34
1
08/31/2016:41
107-06-2
ND
ug/L
1.0
0.24
1
08/31/2016:41
75-35-4
ND
ug/L
1.0
0.29
1
08/31/2016:41
156-59-2
ND
ug/L
1.0
0.25
1
08/31/2016:41
156-60-5
ND
ug/L
1.0
0.19
1
08/31/2016:41
78-87-5
ND
ug/L
1.0
0.30
1
08/31 /20 16:41
10061-01-5
ND
ug/L
1.0
0.31
1
08/31 /20 16:41
10061-02-6
ND
ug/L
1.0
0.26
1
08/31 /20 16:41
100-41-4
ND
ug/L
5.0
0.57
1
08/31 /20 16:41
591-78-6
ND
ug/L
20.0
12.5
1
08/31/2016:41
74-88-4
ND
ug/L
5.0
3.7
1
08/31/2016:41
75-09-2
ND
ug/L
5.0
4.5
1
08/31/2016:41
108-10-1
ND
ug/L
1.0
0.27
1
08/31/2016:41
100-42-5
ND
ug/L
1.0
0.34
1
08/31/2016:41
630-20-6
ND
ug/L
1.0
0.22
1
08/31/2016:41
79-34-5
ND
ug/L
1.0
0.16
1
08/31/2016:41
127-18-4
ND
ug/L
1.0
0.24
1
08/31/2016:41
108-88-3
ND
ug/L
1.0
0.18
1
08/31 /20 16:41
71-55-6
ND
ug/L
1.0
0.24
1
08/31/2016:41
79-00-5
ND
ug/L
1.0
0.22
1
08/31 /20 16:41
79-01-6
ND
ug/L
1.0
0.31
1
08/31/2016:41
75-69-4
ND
ug/L
1.0
0.35
1
08/31/2016:41
96-18-4
ND
ug/L
2.0
1.4
1
08/31/2016:41
108-05-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
IN
Page 21 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92493082
Sample: 3902-Trip Blank
Parameters
Lab ID: 92493082009 Collected:
Report
Results Units Limit
08/27/20 00:00
MDL DF
Received: 08/28/20 09:37 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Vinyl chloride
ND ug/L 1.0
0.24 1
08/31/20 16:41
75-01-4
Xylene (Total)
ND ug/L 1.0
0.63 1
08/31/20 16:41
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99 % 70-130
1
08/31/20 16:41
460-00-4
1,2-Dichloroethane-d4 (S)
97 % 70-130
1
08/31/20 16:41
17060-07-0
Toluene-d8 (S)
101 % 70-130
1
08/31/20 16:41
2037-26-5
8260D MSV SIM
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1,4-Dioxane (p-Dioxane)
ND ug/L 2.0
1.2 1
09/01/20 19:05
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
101 % 50-150
1
09/01/20 19:05
17060-07-0
Toluene-d8 (S)
99 % 50-150
1
09/01/20 19:05
2037-26-5
Date: 09/14/2020 12:23 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 22 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92493082
QC Batch: 563908 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92493082001, 92493082002, 92493082003, 92493082004, 92493082005, 92493082006, 92493082007,
92493082008
METHOD BLANK: 2989435 Matrix: Water
Associated Lab Samples: 92493082001, 92493082002, 92493082003, 92493082004, 92493082005, 92493082006, 92493082007,
92493082008
Parameter
Units
Antimony
ug/L
Arsenic
ug/L
Barium
ug/L
Beryllium
ug/L
Cadmium
ug/L
Chromium
ug/L
Cobalt
ug/L
Copper
ug/L
Lead
ug/L
Nickel
ug/L
Selenium
ug/L
Silver
ug/L
Tin
ug/L
Vanadium
ug/L
Zinc
ug/L
Blank
Result
Reporting
Limit
MDL
Analyzed Qualifiers
ND
5.0
3.0
09/03/20 00:19
ND
10.0
4.7
09/03/20 00:19
ND
5.0
3.5
09/03/20 00:19
ND
1.0
0.70
09/03/20 00:19
ND
1.0
0.40
09/03/20 00:19
ND
5.0
3.7
09/03/20 00:19
ND
5.0
3.6
09/03/20 00:19
ND
5.0
4.3
09/03/20 00:19
ND
5.0
4.5
09/03/20 00:19
ND
5.0
3.5
09/03/20 00:19
ND
10.0
4.7
09/03/20 00:19
ND
5.0
2.5
09/03/20 00:19
ND
5.0
4.7
09/03/20 00:19
ND
5.0
3.9
09/03/20 00:19
ND
10.0
9.5
09/03/20 00:19
LABORATORY CONTROL SAMPLE:
Parameter
2989436
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
500
470
94
80-120
Arsenic
ug/L
500
467
93
80-120
Barium
ug/L
500
486
97
80-120
Beryllium
ug/L
500
493
99
80-120
Cadmium
ug/L
500
480
96
80-120
Chromium
ug/L
500
488
98
80-120
Cobalt
ug/L
500
491
98
80-120
Copper
ug/L
500
485
97
80-120
Lead
ug/L
500
488
98
80-120
Nickel
ug/L
500
487
97
80-120
Selenium
ug/L
500
467
93
80-120
Silver
ug/L
250
238
95
80-120
Tin
ug/L
500
478
96
80-120
Vanadium
ug/L
500
493
99
80-120
Zinc
ug/L
500
490
98
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/14/2020 12:23 PM without the written consent of Pace Analytical Services, LLC.
Page 23 of 39

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
Butner Landfill Compliance
92493082
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2989437
2989438
MS
MSD
92493089001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
500
500
516
506
103
101
75-125
2
20
Arsenic
ug/L
10.9
500
500
529
500
104
98
75-125
6
20
Barium
ug/L
231
500
500
751
732
104
100
75-125
3
20
Beryllium
ug/L
ND
500
500
531
515
106
103
75-125
3
20
Cadmium
ug/L
ND
500
500
525
514
105
103
75-125
2
20
Chromium
ug/L
ND
500
500
520
506
104
101
75-125
3
20
Cobalt
ug/L
8.1
500
500
530
515
104
101
75-125
3
20
Copper
ug/L
ND
500
500
527
513
105
102
75-125
3
20
Lead
ug/L
ND
500
500
516
503
103
101
75-125
2
20
Nickel
ug/L
ND
500
500
518
505
103
101
75-125
2
20
Selenium
ug/L
ND
500
500
526
515
105
103
75-125
2
20
Silver
ug/L
ND
250
250
261
254
104
102
75-125
3
20
Tin
ug/L
ND
500
500
518
503
104
101
75-125
3
20
Vanadium
ug/L
ND
500
500
531
516
106
103
75-125
3
20
Zinc
ug/L
ND
500
500
532
514
106
102
75-125
3
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/14/2020 12:23 PM without the written consent of Pace Analytical Services, LLC.
Page 24 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92493082
QC Batch: 563910 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92493082001, 92493082002, 92493082003, 92493082004, 92493082005, 92493082006, 92493082008
METHOD BLANK: 2989443 Matrix: Water
Associated Lab Samples: 92493082001, 92493082002, 92493082003, 92493082004, 92493082005, 92493082006, 92493082008
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Thallium ug/L ND 0.10 0.050 09/07/20 21:42
LABORATORY CONTROL SAMPLE: 2989444
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Thallium ug/L 10 10.1 101 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2989445 2989446
MS MSD
92493089001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Thallium ug/L ND 10 10 10.0 10.2 100 102 75-125 2 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/14/2020 12:23 PM without the written consent of Pace Analytical Services, LLC.
Page 25 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92493082
QC Batch: 563412 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92493082002, 92493082004, 92493082005, 92493082006, 92493082007, 92493082009
METHOD BLANK: 2987326 Matrix: Water
Associated Lab Samples: 92493082002, 92493082004, 92493082005, 92493082006, 92493082007, 92493082009
Blank Reporting
Parameter Units Result Limit MDL Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.34
08/31/20 13:55
1,1,1-Trichloroethane
ug/L
ND
1.0
0.18
08/31/20 13:55
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
08/31/20 13:55
1,1,2-Trichloroethane
ug/L
ND
1.0
0.24
08/31/20 13:55
1,1-Dichloroethane
ug/L
ND
1.0
0.27
08/31/20 13:55
1,1-Dichloroethene
ug/L
ND
1.0
0.24
08/31/20 13:55
1,2,3-Trichloropropane
ug/L
ND
1.0
0.35
08/31/20 13:55
1,2-Dibromo-3-chloropropane
ug/L
ND
5.0
0.26
08/31/20 13:55
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.26
08/31/20 13:55
1,2-Dichlorobenzene
ug/L
ND
1.0
0.29
08/31/20 13:55
1,2-Dichloroethane
ug/L
ND
1.0
0.34
08/31/20 13:55
1,2-Dichloropropane
ug/L
ND
1.0
0.19
08/31/20 13:55
1,4-Dichlorobenzene
ug/L
ND
1.0
0.26
08/31/20 13:55
2-Butanone (MEK)
ug/L
ND
5.0
3.3
08/31/20 13:55
2-Hexanone
ug/L
ND
5.0
0.57
08/31/20 13:55
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
4.5
08/31/20 13:55
Acetone
ug/L
ND
25.0
6.2
08/31/20 13:55
Acrylonitrile
ug/L
ND
10.0
0.90
08/31/20 13:55
Benzene
ug/L
ND
1.0
0.15
08/31/20 13:55
Bromochloromethane
ug/L
ND
1.0
0.34
08/31/20 13:55
Bromodichloromethane
ug/L
ND
1.0
0.26
08/31/20 13:55
Bromoform
ug/L
ND
1.0
0.62
08/31/20 13:55
Bromomethane
ug/L
ND
2.0
0.62
08/31/20 13:55
Carbon disulfide
ug/L
ND
2.0
0.40
08/31/20 13:55
Carbon tetrachloride
ug/L
ND
1.0
0.22
08/31/20 13:55
Chlorobenzene
ug/L
ND
1.0
0.23
08/31/20 13:55
Chloroethane
ug/L
ND
1.0
0.49
08/31/20 13:55
Chloroform
ug/L
ND
5.0
2.3
08/31/20 13:55
Chloromethane
ug/L
ND
1.0
0.39
08/31/20 13:55
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.29
08/31/20 13:55
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.30
08/31/20 13:55
Dibromochloromethane
ug/L
ND
1.0
0.41
08/31/20 13:55
Dibromomethane
ug/L
ND
1.0
0.46
08/31/20 13:55
Ethylbenzene
ug/L
ND
1.0
0.26
08/31/20 13:55
lodomethane
ug/L
ND
20.0
12.5
08/31/20 13:55
Methylene Chloride
ug/L
ND
5.0
3.7
08/31/20 13:55
Styrene
ug/L
ND
1.0
0.27
08/31/20 13:55
Tetrachloroethene
ug/L
ND
1.0
0.16
08/31/20 13:55
Toluene
ug/L
ND
1.0
0.24
08/31/20 13:55
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.25
08/31/20 13:55
IK
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/14/2020 12:23 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92493082
METHOD BLANK: 2987326 Matrix: Water
Associated Lab Samples: 92493082002, 92493082004, 92493082005, 92493082006, 92493082007, 92493082009
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.31
08/31/20 13:55
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.54
08/31/20 13:55
Trichloroethene
ug/L
ND
1.0
0.22
08/31/20 13:55
Trichlorofluoromethane
ug/L
ND
1.0
0.31
08/31/20 13:55
Vinyl acetate
ug/L
ND
2.0
1.4
08/31/20 13:55
Vinyl chloride
ug/L
ND
1.0
0.24
08/31/20 13:55
Xylene (Total)
ug/L
ND
1.0
0.63
08/31/20 13:55
1,2-Dichloroethane-d4 (S)
%
97
70-130
08/31/20 13:55
4-Bromofluorobenzene (S)
%
98
70-130
08/31/20 13:55
Toluene-d8 (S)
%
101
70-130
08/31/20 13:55
LABORATORY CONTROL SAMPLE:
Parameter
2987327
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
52.0
104
70-130
1,1,1-Trichloroethane
ug/L
50
50.3
101
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
50.1
100
70-130
1,1,2-Trichloroethane
ug/L
50
49.8
100
70-130
1,1-Dichloroethane
ug/L
50
50.9
102
70-130
1,1-Dichloroethene
ug/L
50
52.5
105
70-130
1,2,3-Trichloropropane
ug/L
50
50.8
102
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
52.1
104
70-130
1,2-Dibromoethane (EDB)
ug/L
50
51.6
103
70-130
1,2-Dichlorobenzene
ug/L
50
52.5
105
70-130
1,2-Dichloroethane
ug/L
50
48.4
97
70-130
1,2-Dichloropropane
ug/L
50
51.2
102
70-130
1,4-Dichlorobenzene
ug/L
50
52.3
105
70-130
2-Butanone (MEK)
ug/L
100
112
112
64-135
2-Hexanone
ug/L
100
99.5
99
66-135
4-Methyl-2-pentanone (MIBK)
ug/L
100
99.7
100
70-130
Acetone
ug/L
100
97.7
98
61-157
Acrylonitrile
ug/L
250
246
98
61-143
Benzene
ug/L
50
49.9
100
70-130
Bromochloromethane
ug/L
50
51.0
102
70-130
Bromodichloromethane
ug/L
50
45.3
91
70-130
Bromoform
ug/L
50
50.4
101
70-130
Bromomethane
ug/L
50
54.1
108
38-130
Carbon disulfide
ug/L
50
52.7
105
68-130
Carbon tetrachloride
ug/L
50
50.6
101
70-130
Chlorobenzene
ug/L
50
51.6
103
70-130
Chloroethane
ug/L
50
28.0
56
37-142 IK
Chloroform
ug/L
50
49.9
100
70-130
Chloromethane
ug/L
50
43.4
87
48-130
cis-1,2-Dichloroethene
ug/L
50
50.7
101
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/14/2020 12:23 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92493082
LABORATORY CONTROL SAMPLE:
Parameter
2987327
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
cis-1,3-Dichloropropene
ug/L
50
53.5
107
70-130
Dibromochloromethane
ug/L
50
51.8
104
70-130
Dibromomethane
ug/L
50
50.7
101
70-130
Ethylbenzene
ug/L
50
50.4
101
70-130
lodomethane
ug/L
100
102
102
40-130
Methylene Chloride
ug/L
50
48.9
98
67-132
Styrene
ug/L
50
53.0
106
70-130
Tetrachloroethene
ug/L
50
51.4
103
69-130
Toluene
ug/L
50
49.4
99
70-130
trans-1,2-Dichloroethene
ug/L
50
52.5
105
70-130
trans- 1,3-Dichloropropene
ug/L
50
51.4
103
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
49.5
99
35-189
Trichloroethene
ug/L
50
53.1
106
70-130
Trichlorofluoromethane
ug/L
50
46.2
92
63-130
Vinyl acetate
ug/L
100
107
107
55-143
Vinyl chloride
ug/L
50
44.2
88
70-131
Xylene (Total)
ug/L
150
152
101
70-130
1,2-Dichloroethane-d4 (S)
%
92
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8 (S)
%
99
70-130
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2987328
MS
92493082007 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
2987329
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
20.9
22.2
104
111
73-134
6
30
1,1,1-Trichloroethane
ug/L
ND
20
20
21.0
22.5
105
112
82-143
7
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
20.1
21.1
101
106
70-136
5
30
1,1,2-Trichloroethane
ug/L
ND
20
20
20.0
21.5
100
107
70-135
7
30
1,1-Dichloroethane
ug/L
ND
20
20
21.3
22.8
106
114
70-139
7
30
1,1-Dichloroethene
ug/L
ND
20
20
22.4
23.6
112
118
70-154
5
30
1,2,3-Trichloropropane
ug/L
ND
20
20
20.2
21.3
101
106
71-137
5
30
1,2-Dibromo-3-
ug/L
ND
20
20
20.0
20.6
100
103
65-134
3
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
20.9
21.7
104
108
70-137
4
30
1,2-Dichlorobenzene
ug/L
ND
20
20
20.8
22.4
104
112
70-133
7
30
1,2-Dichloroethane
ug/L
ND
20
20
20.5
21.5
102
107
70-137
5
30
1,2-Dichloropropane
ug/L
ND
20
20
21.0
22.4
105
112
70-140
6
30
1,4-Dichlorobenzene
ug/L
ND
20
20
20.6
22.2
103
111
70-133
7
30
2-Butanone (MEK)
ug/L
ND
40
40
45.5
47.1
114
118
60-139
4
30
2-Hexanone
ug/L
ND
40
40
34.2
35.3
85
88
65-138
3
30
4-Methyl-2-pentanone
ug/L
ND
40
40
40.1
41.8
100
105
65-135
4
30
(MIBK)
Acetone ug/L ND 40 40 41.9 39.3 105 98 60-148 6 30
Acrylonitrile ug/L ND 100 100 101 105 101 105 64-147 4 30
Benzene ug/L ND 20 20 20.9 22.3 104 111 70-151 6 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/14/2020 12:23 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92493082
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2987328
MS
92493082007 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
2987329
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
Bromochloromethane
ug/L
ND
20
20
21.0
22.2
105
111
70-141
6
30
Bromodichloromethane
ug/L
ND
20
20
18.4
19.8
92
99
70-138
7
30
Bromoform
ug/L
ND
20
20
19.4
20.5
97
103
63-130
6
30
Bromomethane
ug/L
ND
20
20
20.6
22.9
103
115
15-152
11
30
Carbon disulfide
ug/L
ND
20
20
21.2
22.8
106
114
69-149
7
30
Carbon tetrachloride
ug/L
ND
20
20
21.2
22.9
106
115
70-143
8
30
Chlorobenzene
ug/L
ND
20
20
21.3
22.9
107
115
70-138
7
30
Chloroethane
ug/L
ND
20
20
21.8
22.9
109
115
52-163
5
30 IK
Chloroform
ug/L
ND
20
20
20.9
22.4
105
112
70-139
7
30
Chloromethane
ug/L
ND
20
20
16.7
17.9
83
90
41-139
7
30
cis-1,2-Dichloroethene
ug/L
ND
20
20
21.3
22.4
106
112
70-141
5
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
20.6
22.1
103
111
70-137
7
30
Dibromochloromethane
ug/L
ND
20
20
20.4
21.6
102
108
70-134
6
30
Dibromomethane
ug/L
ND
20
20
21.4
22.5
107
112
70-138
5
30
Ethylbenzene
ug/L
ND
20
20
20.7
22.2
103
111
66-153
7
30
lodomethane
ug/L
ND
40
40
36.6
41.3
91
103
20-138
12
30 v3
Methylene Chloride
ug/L
ND
20
20
20.5
21.6
103
108
42-159
5
30
Styrene
ug/L
ND
20
20
20.9
22.3
105
111
70-135
6
30
Tetrachloroethene
ug/L
ND
20
20
20.5
22.2
102
111
59-143
8
30
Toluene
ug/L
ND
20
20
20.6
22.0
103
110
59-148
7
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
21.5
23.1
108
116
70-146
7
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
19.9
21.1
100
105
70-135
6
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
19.1
20.2
96
101
47-135
6
30
Trichloroethene
ug/L
ND
20
20
21.8
23.4
109
117
70-147
7
30
Trichlorofluoromethane
ug/L
ND
20
20
20.2
21.8
101
109
70-148
8
30
Vinyl acetate
ug/L
ND
40
40
38.9
40.2
97
101
49-151
3
30
Vinyl chloride
ug/L
ND
20
20
18.5
19.9
92
99
70-156
7
30
Xylene (Total)
ug/L
ND
60
60
62.3
66.9
104
112
63-158
7
30
1,2-Dichloroethane-d4 (S)
%
99
99
70-130
4-Bromofluorobenzene (S)
%
99
98
70-130
Toluene-d8 (S)
%
98
98
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/14/2020 12:23 PM without the written consent of Pace Analytical Services, LLC.
Page 29 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92493082
QC Batch: 563694 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92493082001, 92493082003, 92493082008
METHOD BLANK: 2988437 Matrix:
Associated Lab Samples: 92493082001, 92493082003, 92493082008
Blank
Parameter Units Result
Water
Reporting
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.34
09/01/20 11:16
1,1,1-Trichloroethane
ug/L
ND
1.0
0.18
09/01/20 11:16
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
09/01/20 11:16
1,1,2-Trichloroethane
ug/L
ND
1.0
0.24
09/01/20 11:16
1,1-Dichloroethane
ug/L
ND
1.0
0.27
09/01/20 11:16
1,1-Dichloroethene
ug/L
ND
1.0
0.24
09/01/20 11:16
1,2,3-Trichloropropane
ug/L
ND
1.0
0.35
09/01/20 11:16
1,2-Dibromo-3-chloropropane
ug/L
ND
5.0
0.26
09/01/20 11:16
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.26
09/01/20 11:16
1,2-Dichlorobenzene
ug/L
ND
1.0
0.29
09/01/20 11:16
1,2-Dichloroethane
ug/L
ND
1.0
0.34
09/01/20 11:16
1,2-Dichloropropane
ug/L
ND
1.0
0.19
09/01/20 11:16
1,4-Dichlorobenzene
ug/L
ND
1.0
0.26
09/01/20 11:16
2-Butanone (MEK)
ug/L
ND
5.0
3.3
09/01/20 11:16
2-Hexanone
ug/L
ND
5.0
0.57
09/01/20 11:16
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
4.5
09/01/20 11:16
Acetone
ug/L
ND
25.0
6.2
09/01/20 11:16
Acrylonitrile
ug/L
ND
10.0
0.90
09/01/20 11:16
Benzene
ug/L
ND
1.0
0.15
09/01/20 11:16
Bromochloromethane
ug/L
ND
1.0
0.34
09/01/20 11:16
Bromodichloromethane
ug/L
ND
1.0
0.26
09/01/20 11:16
Bromoform
ug/L
ND
1.0
0.62
09/01/20 11:16
Bromomethane
ug/L
ND
2.0
0.62
09/01/20 11:16
Carbon disulfide
ug/L
ND
2.0
0.40
09/01/20 11:16
Carbon tetrachloride
ug/L
ND
1.0
0.22
09/01/20 11:16
Chlorobenzene
ug/L
ND
1.0
0.23
09/01/20 11:16
Chloroethane
ug/L
ND
1.0
0.49
09/01/20 11:16
Chloroform
ug/L
ND
5.0
2.3
09/01/20 11:16
Chloromethane
ug/L
ND
1.0
0.39
09/01/20 11:16
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.29
09/01/20 11:16
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.30
09/01/20 11:16
Dibromochloromethane
ug/L
ND
1.0
0.41
09/01/20 11:16
Dibromomethane
ug/L
ND
1.0
0.46
09/01/20 11:16
Ethylbenzene
ug/L
ND
1.0
0.26
09/01/20 11:16
lodomethane
ug/L
ND
20.0
12.5
09/01/20 11:16
Methylene Chloride
ug/L
ND
5.0
3.7
09/01/20 11:16
Styrene
ug/L
ND
1.0
0.27
09/01/20 11:16
Tetrachloroethene
ug/L
ND
1.0
0.16
09/01/20 11:16
Toluene
ug/L
ND
1.0
0.24
09/01/20 11:16
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.25
09/01/20 11:16
IK
v2
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/14/2020 12:23 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92493082
METHOD BLANK: 2988437 Matrix:
Associated Lab Samples: 92493082001, 92493082003, 92493082008
Blank
Parameter Units Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.31
09/01/20 11:16
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.54
09/01/20 11:16
Trichloroethene
ug/L
ND
1.0
0.22
09/01/20 11:16
Trichlorofluoromethane
ug/L
ND
1.0
0.31
09/01/20 11:16
Vinyl acetate
ug/L
ND
2.0
1.4
09/01/20 11:16
Vinyl chloride
ug/L
ND
1.0
0.24
09/01/20 11:16
Xylene (Total)
ug/L
ND
1.0
0.63
09/01/20 11:16
1,2-Dichloroethane-d4 (S)
%
97
70-130
09/01/20 11:16
4-Bromofluorobenzene (S)
%
98
70-130
09/01/20 11:16
Toluene-d8 (S)
%
102
70-130
09/01/20 11:16
LABORATORY CONTROL SAMPLE:
Parameter
2988438
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
50.6
101
70-130
1,1,1-Trichloroethane
ug/L
50
48.1
96
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
49.6
99
70-130
1,1,2-Trichloroethane
ug/L
50
48.2
96
70-130
1,1-Dichloroethane
ug/L
50
48.9
98
70-130
1,1-Dichloroethene
ug/L
50
50.0
100
70-130
1,2,3-Trichloropropane
ug/L
50
50.4
101
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
50.4
101
70-130
1,2-Dibromoethane (EDB)
ug/L
50
50.7
101
70-130
1,2-Dichlorobenzene
ug/L
50
49.4
99
70-130
1,2-Dichloroethane
ug/L
50
47.4
95
70-130
1,2-Dichloropropane
ug/L
50
49.3
99
70-130
1,4-Dichlorobenzene
ug/L
50
49.8
100
70-130
2-Butanone (MEK)
ug/L
100
111
111
64-135
2-Hexanone
ug/L
100
98.0
98
66-135
4-Methyl-2-pentanone (MIBK)
ug/L
100
98.9
99
70-130
Acetone
ug/L
100
97.6
98
61-157
Acrylonitrile
ug/L
250
243
97
61-143
Benzene
ug/L
50
48.1
96
70-130
Bromochloromethane
ug/L
50
48.0
96
70-130
Bromodichloromethane
ug/L
50
43.5
87
70-130
Bromoform
ug/L
50
49.4
99
70-130
Bromomethane
ug/L
50
55.8
112
38-130
Carbon disulfide
ug/L
50
49.3
99
68-130
Carbon tetrachloride
ug/L
50
48.7
97
70-130
Chlorobenzene
ug/L
50
50.0
100
70-130
Chloroethane
ug/L
50
27.8
56
37-142 IK
Chloroform
ug/L
50
47.1
94
70-130
Chloromethane
ug/L
50
40.6
81
48-130
cis-1,2-Dichloroethene
ug/L
50
48.1
96
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/14/2020 12:23 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 39

Pace Analytical Services, LLC
lac,
Analyilcal ® 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92493082
LABORATORY CONTROL SAMPLE:
Parameter
2988438
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
cis-1,3-Dichloropropene
ug/L
50
50.8
102
70-130
Dibromochloromethane
ug/L
50
50.4
101
70-130
Dibromomethane
ug/L
50
49.9
100
70-130
Ethylbenzene
ug/L
50
48.9
98
70-130
lodomethane
ug/L
100
88.8
89
40-130 v3
Methylene Chloride
ug/L
50
46.1
92
67-132
Styrene
ug/L
50
51.3
103
70-130
Tetrachloroethene
ug/L
50
50.4
101
69-130
Toluene
ug/L
50
47.5
95
70-130
trans-1,2-Dichloroethene
ug/L
50
49.7
99
70-130
trans- 1,3-Dichloropropene
ug/L
50
49.4
99
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
49.2
98
35-189
Trichloroethene
ug/L
50
51.1
102
70-130
Trichlorofluoromethane
ug/L
50
45.2
90
63-130
Vinyl acetate
ug/L
100
105
105
55-143
Vinyl chloride
ug/L
50
41.7
83
70-131
Xylene (Total)
ug/L
150
146
98
70-130
1,2-Dichloroethane-d4 (S)
%
91
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8 (S)
%
98
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2988439
MS
92493089001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
2988440
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
24.0
20.9
120
105
73-134
14
30
1,1,1-Trichloroethane
ug/L
ND
20
20
24.2
21.0
121
105
82-143
14
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
22.7
19.7
114
98
70-136
14
30
1,1,2-Trichloroethane
ug/L
ND
20
20
22.5
19.7
113
99
70-135
13
30
1,1-Dichloroethane
ug/L
1.7
20
20
26.2
22.9
123
106
70-139
13
30
1,1-Dichloroethene
ug/L
ND
20
20
25.4
22.1
127
110
70-154
14
30
1,2,3-Trichloropropane
ug/L
ND
20
20
23.3
20.2
117
101
71-137
15
30
1,2-Dibromo-3-
ug/L
ND
20
20
22.9
19.7
115
98
65-134
15
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
23.6
20.4
118
102
70-137
15
30
1,2-Dichlorobenzene
ug/L
ND
20
20
24.2
21.1
121
105
70-133
14
30
1,2-Dichloroethane
ug/L
ND
20
20
22.9
20.0
115
100
70-137
14
30
1,2-Dichloropropane
ug/L
ND
20
20
24.0
20.8
120
104
70-140
14
30
1,4-Dichlorobenzene
ug/L
ND
20
20
23.8
21.2
119
106
70-133
11
30
2-Butanone (MEK)
ug/L
ND
40
40
51.6
44.8
129
112
60-139
14
30
2-Hexanone
ug/L
ND
40
40
42.4
35.0
106
88
65-138
19
30
4-Methyl-2-pentanone
ug/L
ND
40
40
45.1
39.3
113
98
65-135
14
30
(MIBK)
Acetone ug/L
ND 40 40 47.2 38.0 118 95 60-148 22
30
Acrylonitrile ug/L
ND 100 100 111 98.4 111 98 64-147 12
30
Benzene ug/L
ND 20 20 24.1 20.9 120 104 70-151 14
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/14/2020 12:23 PM
without the written consent of Pace Analytical Services, LLC.
Page 32 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92493082
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2988439
MS
92493089001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
2988440
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
Bromochloromethane
ug/L
ND
20
20
23.6
20.4
118
102
70-141
15
30
Bromodichloromethane
ug/L
ND
20
20
21.0
18.2
105
91
70-138
14
30
Bromoform
ug/L
ND
20
20
22.3
18.8
111
94
63-130
17
30
Bromomethane
ug/L
ND
20
20
23.7
19.5
119
98
15-152
20
30
Carbon disulfide
ug/L
ND
20
20
24.6
21.9
123
110
69-149
12
30
Carbon tetrachloride
ug/L
ND
20
20
24.6
21.6
123
108
70-143
13
30
Chlorobenzene
ug/L
ND
20
20
24.6
21.4
123
107
70-138
14
30
Chloroethane
ug/L
1.4
20
20
26.1
23.5
124
111
52-163
10
30 IK
Chloroform
ug/L
ND
20
20
24.0
21.0
120
105
70-139
13
30
Chloromethane
ug/L
ND
20
20
19.6
17.1
98
85
41-139
14
30
cis-1,2-Dichloroethene
ug/L
ND
20
20
24.4
21.4
122
107
70-141
13
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
23.6
20.3
118
102
70-137
15
30
Dibromochloromethane
ug/L
ND
20
20
23.4
20.0
117
100
70-134
16
30
Dibromomethane
ug/L
ND
20
20
23.7
20.7
119
104
70-138
13
30
Ethylbenzene
ug/L
ND
20
20
24.1
21.3
120
107
66-153
12
30
lodomethane
ug/L
ND
40
40
41.3
35.2
103
88
20-138
16
30 v3
Methylene Chloride
ug/L
ND
20
20
23.0
20.2
115
101
42-159
13
30
Styrene
ug/L
ND
20
20
24.5
21.3
123
107
70-135
14
30
Tetrachloroethene
ug/L
ND
20
20
23.9
21.2
119
106
59-143
12
30
Toluene
ug/L
ND
20
20
23.5
20.8
118
104
59-148
12
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
24.8
22.0
124
110
70-146
12
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
22.6
19.6
113
98
70-135
14
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
19.0
16.8
95
84
47-135
13
30
Trichloroethene
ug/L
ND
20
20
25.0
21.9
125
109
70-147
13
30
Trichlorofluoromethane
ug/L
ND
20
20
23.3
20.5
117
103
70-148
13
30
Vinyl acetate
ug/L
ND
40
40
43.4
38.0
108
95
49-151
13
30
Vinyl chloride
ug/L
ND
20
20
21.3
18.9
107
95
70-156
12
30
Xylene (Total)
ug/L
ND
60
60
72.3
63.0
121
105
63-158
14
30
1,2-Dichloroethane-d4 (S)
%
98
98
70-130
4-Bromofluorobenzene (S)
%
99
98
70-130
Toluene-d8 (S)
%
98
98
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/14/2020 12:23 PM without the written consent of Pace Analytical Services, LLC.
Page 33 of 39

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92493082
QC Batch: 563871 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92493082001, 92493082002, 92493082003, 92493082004, 92493082005, 92493082006, 92493082007,
92493082008,92493082009
METHOD BLANK: 2989263
Matrix:
Water
Associated Lab Samples:
92493082001, 92493082002, 92493082003,
92493082004, 92493082005, 92493082006, 92493082007,
92493082008,92493082009
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
1.2 09/01/20 16:15
1,2-Dichloroethane-d4 (S)
%
97
50-150
09/01/20 16:15
Toluene-d8 (S)
%
100
50-150
09/01/20 16:15
LABORATORY CONTROL SAMPLE: 2989264
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane(p-Dioxane) ug/L 20 19.3 96 70-130
1,2-Dichloroethane-d4 (S) % 99 50-150
Toluene-d8(S) % 101 50-150
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2989265
2989266
MS
MSD
92493082001 Spike
Spike MS MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result
% Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L ND 20
20 20.5 19.8
101
97
50-150
4 30
1,2-Dichloroethane-d4 (S)
%
98
98
50-150
30
Toluene-d8 (S)
%
98
98
50-150
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/14/2020 12:23 PM without the written consent of Pace Analytical Services, LLC.
Page 34 of 39

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: Butner Landfill Compliance
Pace Project No.: 92493082
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
ANALYTE QUALIFIERS
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
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Date: 09/14/2020 12:23 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 39

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Butner Landfill Compliance
92493082
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92493082001
3902-MW1 R
EPA 3010A
563908
EPA 6010D
563932
92493082002
3902-MW2R
EPA 3010A
563908
EPA 6010D
563932
92493082003
3902-MW3R
EPA 3010A
563908
EPA 6010D
563932
92493082004
3902-MW4
EPA 3010A
563908
EPA 6010D
563932
92493082005
3902-MW5
EPA 3010A
563908
EPA 6010D
563932
92493082006
3902-MW6
EPA 3010A
563908
EPA 6010D
563932
92493082007
3902-NES-1
EPA 3010A
563908
EPA 6010D
563932
92493082008
3902-Field Blank
EPA 3010A
563908
EPA 6010D
563932
92493082001
3902-MW1 R
EPA 3010A
563910
EPA 6020B
563924
92493082002
3902-MW2R
EPA 3010A
563910
EPA 6020B
563924
92493082003
3902-MW3R
EPA 3010A
563910
EPA 6020B
563924
92493082004
3902-MW4
EPA 3010A
563910
EPA 6020B
563924
92493082005
3902-MW5
EPA 3010A
563910
EPA 6020B
563924
92493082006
3902-MW6
EPA 3010A
563910
EPA 6020B
563924
92493082008
3902-Field Blank
EPA 3010A
563910
EPA 6020B
563924
92493082001
3902-MW1R
EPA 8260D
563694
92493082002
3902-MW2R
EPA 8260D
563412
92493082003
3902-MW3R
EPA 8260D
563694
92493082004
3902-MW4
EPA 8260D
563412
92493082005
3902-MW5
EPA 8260D
563412
92493082006
3902-MW6
EPA 8260D
563412
92493082007
3902-NES-1
EPA 8260D
563412
92493082008
3902-Field Blank
EPA 8260D
563694
92493082009
3902-Trip Blank
EPA 8260D
563412
92493082001
3902-MW1R
EPA 8260D Mod.
563871
92493082002
3902-MW2R
EPA 8260D Mod.
563871
92493082003
3902-MW3R
EPA 8260D Mod.
563871
92493082004
3902-MW4
EPA 8260D Mod.
563871
92493082005
3902-MW5
EPA 8260D Mod.
563871
92493082006
3902-MW6
EPA 8260D Mod.
563871
92493082007
3902-NES-1
EPA 8260D Mod.
563871
92493082008
3902-Field Blank
EPA 8260D Mod.
563871
92493082009
3902-Trip Blank
EPA 8260D Mod.
563871
Date: 09/14/2020 12:23 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 36 of 39

Document Name:
Document Revised: February 7, 2018
/a'cmnalytical'
Sample Condition Upon Receipt(SCUR)
Page 1 of 2
Document No.:
Issuing Authority:
/
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersviile'V Raleigh[] Mechanicsville[]
SampleClient Name:Upon Receipt Project Wo# : 92493482
Lit -
Courier: []Fed Ex []UPS ❑LISPS ❑Client �il�� �4 �lll llllll I Il{
❑ Commercial ❑Pace ❑Other: } 1
_ 924193082
Date/initials Person Examining Contents:
Packing Material: ❑Bubble Wrap f Bubble Bags ❑None ❑ Other Biological Tissue,Froten?
Thermometer: / 11 ❑Yes ❑No �N/A
❑IR Gun ID: 92T'61 Type of Ice: I /IWet ❑Blue ❑None
Cooler Temp (°C): d Correction Factor: Add/Subtract (°C) 0.0
Temp should be above freezing to VC�' I
Cooler Temp Corrected (`Q: ❑Samples out of temp criterla. Samples on ice, cooling process
has begun
USDA Regulated $oil (JZN/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (Internationally,
I—Ivac liven includingHawall and Puerto Rico)? ❑Yes []No
Comm ents/ Discrepan cy:
Chain of Custody Present?
Yes
[—]No
[]N/A
1.
Samples Arrived within Hold Time?
Oyes
[]No
❑NIA
2.
Short Hold Time Analysis (02 hr.)?
[]Yes
No
❑N/A
3.
Rush Turn Around Time Requested?
❑Yes
ONo
❑N/A
4.
Sufficient Volume?
❑Yes
❑No
❑NIA
5.
Correct Containers Used?
-Pace Containers Used?
,Yes
es
❑No
❑No
❑N/A
❑N/A
6. ,
Containers` Intact?
mYes
❑No
❑NIA
7.
Dissolved analysis: Samples Field Filtered?
[]Yes
No
❑N/A
8.
Sample Labels Match CDC?
❑Yes
❑No
❑NIA
4.
-Includes Date/Time/ID/Analysis Matrix:
Headspace in VOA Vials (>5-6mm)?
Dyes
Z1No
C3 N/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
J2Yes
ves
❑No
❑No
❑N/A
❑N/A
11.
COMMENTS/SAMPLE DISCREPANCY Field Date Required? []Yes []No
Lot ID of spiit containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Project Manager SRF Review:
Date/Time�
Date:
Date:
Page 37 of 39

Document Name:
Dorument Revised: February 7, 2018
a
ace Analytical
Sample Condition Upon Recelpt(5CUR)
Page 1 of 2
Document No.:
Issuing Authority:
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
"Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
"Bottom half of box is to list number of bottle
Project # Wad : 92493Q82
PM: NMG Due Date: 09/14/20
CLIENT: 92-Joyce Eng
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pH Adjustment log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot 9
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will he sent to the North Carolina DEHNR certification Ufflce il.e.
out of hold, Incorrect preservative, out of temp, incorrect containers.
Page 38 of 39

CHAIN -OF -CUSTODY / Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Section A Section B Section C
Required Client Information: Required Project Information: Invoice Information: Page; 1 Of 1
Company: La Bella Associates Report To: Van Burbach Attention: Jason Falls
Address: 2211 West Meadowview Rd Copy To: Miguel Vazquez Company Name: Granville County, Solid Waste
Greensboro, INC 27407
Address: P.O. Box 906, Oxford NC 27565
Regulatory Agency
Email To: vburbarh u ceen ineerin .Com
Purchase Order No.
Phone: [phone] jFax
Client Project ID: Butner Landfill Compliance
State! Location
Requested Due DatelTAT: 10 Da Default
Conlainer Order Number:
3566-3
North Carolina
Requested
Anal
sis
Filtered
Y!N
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COLLECTED
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Preservatives
>-
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SAMPLE ID
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RELINQUISHED BY I AFFILIATION
DATE
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ACCE TED BY I AFFILIATION
DATE
TIME
SAMPLE CONDITIONS
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SAMPLER NAME AND SIGNATURE
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Ir

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
September 14, 2020
Van Burbach
Joyce Engineering -NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Butner Landfill MNA
Pace Project No.: 92493094
Dear Van Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on August 28, 2020. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Gulf Coast
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Gretta Eller, LaBella Associates, D.P.C.
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 30

lacieAnalyfica('
www,pacelabs.com
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Project: Butner Landfill MNA
Pace Project No.: 92493094
Pace Analytical Gulf Coast
7979 Innovation Park Drive, Baton Rouge, LA 70820
Arkansas Certification #: 88-0655
DoD ELAP Certification #: L18-597
Florida Certification #: E87854
Illinois Certification #: 004585
Kansas Certification #: E-10354
Louisiana/LELAP Certification #: 01955
North Carolina Certification #: 618
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
North Dakota Certification #: R-195
Oklahoma Certification #: 2019-101
South Carolina Certification #: 73006001
Texas Certification #: T104704178-19-11
USDA Soil Permit # P330-19-00209
Virginia Certification #: 460215
Washington Certification #: C929
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 30

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Butner Landfill MNA
Pace Project No.: 92493094
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92493094001
3902-MW2R
Water
08/27/20 14:29
08/28/20 09:37
92493094002
3902-MW3R
Water
08/27/20 12:58
08/28/20 09:37
92493094003
3902-MW1R
Water
08/27/20 08:53
08/28/20 09:37
92493094004
3902-NES-1
Water
08/27/20 17:40
08/28/20 09:37
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 30

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Butner Landfill MNA
92493094
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92493094001
3902-MW2R
AM20GAX
AWE
1
GCLA
RSK 175 Modified
MAD
3
PASI-C
SM 2320B-2011
ECH
1
PASI-A
SM 4500-S2D-2011
BAS
1
PASI-A
SM 521OB-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
BRJ
2
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 5220D-2011
BAS
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
AM23G
MOS
10
GCLA
92493094002
3902-MW3R
AM20GAX
AWE
1
GCLA
RSK 175 Modified
MAD
3
PASI-C
SM 2320B-2011
ECH
1
PASI-A
SM 4500-S2D-2011
BAS
1
PASI-A
SM 521OB-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
BRJ
2
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 5220D-2011
BAS
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
AM23G
MOS
10
GCLA
92493094003
3902-MW1R
RSK 175 Modified
MAD
3
PASI-C
SM 2320B-2011
ECH
1
PASI-A
SM 4500-S2D-2011
BAS
1
PASI-A
SM 521OB-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
BRJ
2
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 5220D-2011
BAS
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
AM23G
MOS
10
GCLA
92493094004
3902-NES-1
RSK 175 Modified
MAD
3
PASI-C
SM 2320B-2011
ECH
1
PASI-A
SM 4500-S2D-2011
BAS
1
PASI-A
SM 521OB-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
BRJ
2
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 5220D-2011
BAS
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: Butner Landfill MNA
Pace Project No.: 92493094
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
AM23G MOS 10 GCLA
GCLA = Pace Analytical Gulf Coast
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 5 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Butner Landfill MNA
Pace Project No.: 92493094
Lab Sample ID Client Sample ID
Method Parameters
92493094001
RSK 175 Modified
SM 2320B-2011
SM 521OB-2011
EPA 300.0 Rev 2.1 1993
SM 5220D-2011
SM 531OB-2011
AM23G
92493094002
RSK 175 Modified
SM 2320B-2011
EPA 300.0 Rev 2.1 1993
SM 5220D-2011
SM 531OB-2011
AM23G
AM23G
92493094003
SM 2320B-2011
EPA 300.0 Rev 2.1 1993
SM 531OB-2011
AM23G
AM23G
92493094004
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
EPA 353.2 Rev 2.0 1993
SM 531OB-2011
AM23G
AM23G
3902-MW2R
Methane
Alkalinity, Total as CaCO3
BOD, 5 day
Chloride
Chemical Oxygen Demand
Total Organic Carbon
Formic acid
3902-MW3R
Methane
Alkalinity, Total as CaCO3
Chloride
Chemical Oxygen Demand
Total Organic Carbon
Acetic Acid
Formic acid
3902-MW1 R
Alkalinity, Total as CaCO3
Chloride
Total Organic Carbon
Acetic Acid
Formic acid
3902-NES-1
Chloride
Sulfate
Nitrogen, Nitrate
Total Organic Carbon
Acetic Acid
Formic acid
SUMMARY OF DETECTION
Result
Units
Report Limit
Analyzed Qualifiers
6000
ug/L
10.0
09/03/2015:38
909000
ug/L
5000
09/08/2017:41
9450
ug/L
2000
09/03/20 02:25
208000
ug/L
4000
08/30/20 08:33
112000
ug/L
25000
09/10/2015:54
29800
ug/L
1000
09/10/20 21:01
45
mg/L
0.55
09/12/20 05:24
497
ug/L
10.0
09/03/2015:23
735000
ug/L
5000
09/08/2017:53
148000
ug/L
3000
08/30/20 08:48
35900
ug/L
25000
09/10/2015:54
8190
ug/L
1000
09/10/20 21:20
0.53
mg/L
0.12
09/12/20 06:17
4.8
mg/L
0.055
09/12/20 06:17
47600
ug/L
5000
09/09/20 09:13
3840
ug/L
1000
08/30/20 04:37
689J
ug/L
1000
09/10/20 21:40
0.53
mg/L
0.12
09/12/20 07:11
4.9
mg/L
0.055
09/12/20 07:11
5330
ug/L
1000
08/30/20 05:22
5210
ug/L
1000
08/30/20 05:22
6340
ug/L
200
08/29/20 01:02
916J
ug/L
1000
09/10/20 21:57
0.56
mg/L
0.12
09/12/20 08:04
5.1
mg/L
0.055
09/12/20 08:04
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 6 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill MNA
Pace Project No.: 92493094
Sample: 3902-MW2R
Lab ID: 92493094001 Collected:
08/27/20 14:29 Received: 08/28/20 09:37 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF Prepared
Analyzed
CAS No. Qual
Indicator Gases Bubblestrip H2
Analytical Method: AM20GAX
Pace Analytical Gulf Coast
Tritium (Hydrogen-3)
11.0.1 nM 0.49
0.49
1
09/03/20 12:21
1333-74-0
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Ethane
ND ug/L 10.0
1.2
1
09/03/2015:38
74-84-0
Ethene
ND ug/L 10.0
1.2
1
09/03/2015:38
74-85-1
Methane
6000 ug/L 10.0
3.4
1
09/03/2015:38
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
Alkalinity, Total as CaCO3
909000 ug/L 5000
5000
1
09/08/20 17:41
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
Sulfide
ND ug/L 100
50.0
1
09/03/20 22:21
18496-25-8
5210B BOD, 5 day
Analytical Method: SM 521OB-2011
Pace Analytical Services -Asheville
BOD, 5 day
9450 ug/L 2000
2000
1 08/29/20 05:09
09/03/20 02:25
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Pace Analytical Services -Asheville
Chloride
208000 ug/L 4000
2400
4
08/30/20 08:33
16887-00-6
Sulfate
ND ug/L 1000
500
1
08/30/20 04:08
14808-79-8
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
ND ug/L 40.0
10.0
1
08/29/20 00:52
14797-55-8
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
112000 ug/L 25000
12500
1 09/09/20 21:16
09/10/20 15:54
5310B TOC
Analytical Method: SM 531OB-2011
Pace Analytical Services -Asheville
Total Organic Carbon
29800 ug/L 1000
500
1
09/10/20 21:01
7440-44-0
Low Level Volatile Fatty Acids
Analytical Method: AM23G
Pace Analytical Gulf Coast
Lactic Acid
ND mg/L 0.53
0.53
10
09/12/20 05:24
50-21-5
Acetic Acid
4.7J mg/L 1.2
1.2
10
09/12/20 05:24
64-19-7
Propionic Acid
ND mg/L 0.53
0.53
10
09/12/20 05:24
79-09-4
Formic acid
45 mg/L 0.55
0.55
10
09/12/20 05:24
64-18-6
Butyric Acid
ND mg/L 0.58
0.58
10
09/12/20 05:24
107-92-6
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced,
except in full,
Date: 09/14/2020 11:37 AM
without the written consent of Pace
Analytical Services, LLC.
Page 7 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill MNA
Pace Project No.: 92493094
Sample: 3902-MW2R
Parameters
Lab ID: 92493094001 Collected:
Report
Results Units Limit
08/27/20 14:29
MDL DF
Received: 08/28/20 09:37 Matrix: Water
Prepared Analyzed CAS No. Qual
Low Level Volatile Fatty Acids
Analytical Method: AM23G
Pace Analytical Gulf Coast
Pyruvic Acid
ND mg/L
0.60
0.60
10
09/12/20 05:24
127-17-3
i-Pentanoic Acid
ND mg/L
0.61
0.61
10
09/12/20 05:24
503-74-2
Pentanoic Acid
ND mg/L
0.56
0.56
10
09/12/20 05:24
109-52-4
i-Hexanoic Acid
ND mg/L
0.56
0.56
10
09/12/20 05:24
646-07-1
Hexanoic Acid
ND mg/L
0.58
0.58
10
09/12/20 05:24
142-62-1
Date: 09/14/2020 11:37 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill MNA
Pace Project No.: 92493094
Sample: 3902-MW3R
Lab ID: 92493094002 Collected:
08/27/20 12:58 Received: 08/28/20 09:37 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF Prepared
Analyzed
CAS No. Qual
Indicator Gases Bubblestrip H2
Analytical Method: AM20GAX
Pace Analytical Gulf Coast
Tritium (Hydrogen-3)
11.2.1 nM 0.49
0.49
1
09/03/20 12:33
1333-74-0
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Ethane
ND ug/L 10.0
1.2
1
09/03/2015:23
74-84-0
Ethene
ND ug/L 10.0
1.2
1
09/03/2015:23
74-85-1
Methane
497 ug/L 10.0
3.4
1
09/03/2015:23
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
Alkalinity, Total as CaCO3
735000 ug/L 5000
5000
1
09/08/20 17:53
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
Sulfide
ND ug/L 100
50.0
1
09/03/20 22:24
18496-25-8
5210B BOD, 5 day
Analytical Method: SM 521OB-2011
Pace Analytical Services -Asheville
BOD, 5 day
ND ug/L 2000
2000
1 08/29/20 05:09
09/03/20 02:16
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Pace Analytical Services -Asheville
Chloride
148000 ug/L 3000
1800
3
08/30/20 08:48
16887-00-6
Sulfate
ND ug/L 1000
500
1
08/30/20 04:23
14808-79-8
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
ND ug/L 40.0
10.0
1
08/29/20 00:45
14797-55-8
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
35900 ug/L 25000
12500
1 09/09/20 21:16
09/10/20 15:54
5310B TOC
Analytical Method: SM 531OB-2011
Pace Analytical Services -Asheville
Total Organic Carbon
8190 ug/L 1000
500
1
09/10/20 21:20
7440-44-0
Low Level Volatile Fatty Acids
Analytical Method: AM23G
Pace Analytical Gulf Coast
Lactic Acid
ND mg/L 0.053
0.053
1
09/12/20 06:17
50-21-5
Acetic Acid
0.53 mg/L 0.12
0.12
1
09/12/20 06:17
64-19-7
Propionic Acid
ND mg/L 0.053
0.053
1
09/12/20 06:17
79-09-4
Formic acid
4.8 mg/L 0.055
0.055
1
09/12/20 06:17
64-18-6
Butyric Acid
0.066J mg/L 0.058
0.058
1
09/12/20 06:17
107-92-6
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced,
except in full,
Date: 09/14/2020 11:37 AM
without the written consent of Pace
Analytical Services, LLC.
Page 9 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill MNA
Pace Project No.: 92493094
Sample: 3902-MW3R
Parameters
Lab ID: 92493094002 Collected:
Report
Results Units Limit
08/27/20 12:58
MDL DF
Received: 08/28/20 09:37 Matrix: Water
Prepared Analyzed CAS No. Qual
Low Level Volatile Fatty Acids
Analytical Method: AM23G
Pace Analytical Gulf Coast
Pyruvic Acid
ND mg/L
0.060
0.060
1
09/12/20 06:17
127-17-3
i-Pentanoic Acid
ND mg/L
0.061
0.061
1
09/12/20 06:17
503-74-2
Pentanoic Acid
ND mg/L
0.056
0.056
1
09/12/20 06:17
109-52-4
i-Hexanoic Acid
ND mg/L
0.056
0.056
1
09/12/20 06:17
646-07-1
Hexanoic Acid
ND mg/L
0.058
0.058
1
09/12/20 06:17
142-62-1
Date: 09/14/2020 11:37 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 10 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill MNA
Pace Project No.: 92493094
Sample: 3902-MW1R Lab ID: 92493094003 Collected: 08/27/20 08:53 Received: 08/28/20 09:37 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Ethane
Ethene
Methane
2320B Alkalinity
Alkalinity, Total as CaCO3
4500S2D Sulfide Water
Sulfide
5210B BOD, 5 day
BOD, 5 day
300.0 IC Anions 28 Days
Chloride
Sulfate
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
5220D COD
Chemical Oxygen Demand
5310B TOC
Total Organic Carbon
Low Level Volatile Fatty Acids
Lactic Acid
Acetic Acid
Propionic Acid
Formic acid
Butyric Acid
Pyruvic Acid
i-Pentanoic Acid
Pentanoic Acid
i-Hexanoic Acid
Date: 09/14/2020 11:37 AM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
ND ug/L 10.0
1.2
1
09/03/2017:41
74-84-0
ND ug/L 10.0
1.2
1
09/03/2017:41
74-85-1
ND ug/L 10.0
3.4
1
09/03/2017:41
74-82-8
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
47600 ug/L 5000
5000
1
09/09/20 09:13
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND ug/L 100
50.0
1
09/03/20 22:24
18496-25-8
Analytical Method: SM 521OB-2011
Pace Analytical Services -Asheville
ND ug/L 2000
2000
1
08/29/20 05:09 09/03/20 02:14
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
3840 ug/L 1000
600
1
08/30/20 04:37
16887-00-6
ND ug/L 1000
500
1
08/30/20 04:37
14808-79-8
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
ND ug/L 40.0
10.0
1
08/29/20 00:33
14797-55-8
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
ND ug/L 25000
12500
1
09/09/20 21:16 09/10/20 15:54
Analytical Method: SM 531OB-2011
Pace Analytical Services -Asheville
689J ug/L 1000
500
1
09/10/20 21:40
7440-44-0
Analytical Method: AM23G
Pace Analytical Gulf Coast
ND mg/L 0.053
0.053
1
09/12/20 07:11
50-21-5
0.53 mg/L 0.12
0.12
1
09/12/20 07:11
64-19-7
ND mg/L 0.053
0.053
1
09/12/20 07:11
79-09-4
4.9 mg/L 0.055
0.055
1
09/12/20 07:11
64-18-6
ND mg/L 0.058
0.058
1
09/12/20 07:11
107-92-6
ND mg/L 0.060
0.060
1
09/12/20 07:11
127-17-3
ND mg/L 0.061
0.061
1
09/12/20 07:11
503-74-2
ND mg/L 0.056
0.056
1
09/12/20 07:11
109-52-4
ND mg/L 0.056
0.056
1
09/12/20 07:11
646-07-1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill MNA
Pace Project No.: 92493094
Sample: 3902-MW1R Lab ID: 92493094003 Collected: 08/27/20 08:53 Received: 08/28/20 09:37 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
Low Level Volatile Fatty Acids Analytical Method: AM23G
Pace Analytical Gulf Coast
Hexanoic Acid ND mg/L 0.058 0.058 1 09/12/2007:11 142-62-1
Date: 09/14/2020 11:37 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill MNA
Pace Project No.: 92493094
Sample: 3902-NES-1 Lab ID: 92493094004 Collected: 08/27/20 17:40 Received: 08/28/20 09:37 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Ethane
Ethene
Methane
2320B Alkalinity
Alkalinity, Total as CaCO3
4500S2D Sulfide Water
Sulfide
5210B BOD, 5 day
BOD, 5 day
300.0 IC Anions 28 Days
Chloride
Sulfate
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
5220D COD
Chemical Oxygen Demand
5310B TOC
Total Organic Carbon
Low Level Volatile Fatty Acids
Lactic Acid
Acetic Acid
Propionic Acid
Formic acid
Butyric Acid
Pyruvic Acid
i-Pentanoic Acid
Pentanoic Acid
i-Hexanoic Acid
Date: 09/14/2020 11:37 AM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
ND ug/L 10.0
1.2
1
09/03/2018:12
74-84-0
ND ug/L 10.0
1.2
1
09/03/2018:12
74-85-1
ND ug/L 10.0
3.4
1
09/03/2018:12
74-82-8
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
ND ug/L 5000
5000
1
09/09/2019:00
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND ug/L 100
50.0
1
09/03/20 22:25
18496-25-8
Analytical Method: SM 521OB-2011
Pace Analytical Services -Asheville
ND ug/L 2000
2000
1
08/29/20 05:09 09/03/20 02:28
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
5330 ug/L 1000
600
1
08/30/20 05:22
16887-00-6
5210 ug/L 1000
500
1
08/30/20 05:22
14808-79-8
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
6340 ug/L 200
50.0
5
08/29/20 01:02
14797-55-8
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
ND ug/L 25000
12500
1
09/09/20 21:16 09/10/20 15:55
Analytical Method: SM 531OB-2011
Pace Analytical Services -Asheville
916J ug/L 1000
500
1
09/10/20 21:57
7440-44-0
Analytical Method: AM23G
Pace Analytical Gulf Coast
ND mg/L 0.053
0.053
1
09/12/20 08:04
50-21-5
0.56 mg/L 0.12
0.12
1
09/12/20 08:04
64-19-7
ND mg/L 0.053
0.053
1
09/12/20 08:04
79-09-4
5.1 mg/L 0.055
0.055
1
09/12/20 08:04
64-18-6
ND mg/L 0.058
0.058
1
09/12/20 08:04
107-92-6
ND mg/L 0.060
0.060
1
09/12/20 08:04
127-17-3
ND mg/L 0.061
0.061
1
09/12/20 08:04
503-74-2
ND mg/L 0.056
0.056
1
09/12/20 08:04
109-52-4
ND mg/L 0.056
0.056
1
09/12/20 08:04
646-07-1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill MNA
Pace Project No.: 92493094
Sample: 3902-NES-1 Lab ID: 92493094004 Collected: 08/27/20 17:40 Received: 08/28/20 09:37 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
Low Level Volatile Fatty Acids Analytical Method: AM23G
Pace Analytical Gulf Coast
Hexanoic Acid ND mg/L 0.058 0.058 1 09/12/20 08:04 142-62-1
Date: 09/14/2020 11:37 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 14 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92493094
QC Batch: 691458 Analysis Method: AM20GAX
QC Batch Method: AM20GAX Analysis Description: Indicator Gases Bubble Strip H2
Laboratory: Pace Analytical Gulf Coast
Associated Lab Samples: 92493094001, 92493094002
METHOD BLANK: 2079855 Matrix: Air
Associated Lab Samples: 92493094001, 92493094002
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Tritium (Hydrogen-3) nM ND 0.49 0.49 09/03/20 09:01
LABORATORY CONTROL SAMPLE & LCSD: 2079856 2079857
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers
Tritium (Hydrogen-3) nM 12 9.9 10 83 85 70-130 2 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/14/2020 11:37 AM without the written consent of Pace Analytical Services, LLC.
Page 15 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92493094
QC Batch: 564315 Analysis Method: RSK 175 Modified
QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92493094001, 92493094002, 92493094003, 92493094004
METHOD BLANK: 2991474
Matrix:
Water
Associated Lab Samples:
92493094001, 92493094002, 92493094003, 92493094004
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
Ethane
ug/L
ND
10.0
1.2 09/03/2013:36
Ethene
ug/L
ND
10.0
1.2 09/03/2013:36
Methane
ug/L
ND
10.0
3.4 09/03/2013:36
LABORATORY CONTROL SAMPLE:
2991475
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Ethane
ug/L
658
700
106
70-130
Ethene
ug/L
1120
1280
114
70-130
Methane
ug/L
396
421
106
70-130
MATRIX SPIKE SAMPLE:
2991477
92493080004
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Ethane
ug/L
ND
658
650
99
70-130
Ethene
ug/L
ND
1120
1210
108
70-130
Methane
ug/L
ND
396
287
72
70-130
SAMPLE DUPLICATE: 2991476
92493080003 Dup
Parameter Units Result Result
Ethane ug/L ND ND
Ethene ug/L ND ND
Methane ug/L ND ND
SAMPLE DUPLICATE: 2991478
92493094003 Dup
Parameter Units Result Result
Ethane ug/L ND ND
Ethene ug/L ND ND
Methane ug/L ND ND
Max
RPD RPD Qualifiers
20
20
20
Max
RPD RPD Qualifiers
20
20
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 09/14/2020 11:37 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92493094
QC Batch: 564905 Analysis Method: SM 2320B-2011
QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92493094001, 92493094002, 92493094003
METHOD BLANK: 2994267 Matrix: Water
Associated Lab Samples: 92493094001, 92493094002, 92493094003
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Alkalinity, Total as CaCO3 ug/L ND 5000 5000 09/08/20 14:04
LABORATORY CONTROL SAMPLE: 2994268
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 ug/L 50000 46500 93 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2994269 2994270
MS MSD
92493167004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 ug/L 49.8 mg/L 50000 50000 102000 103000 103 106 80-120 1 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2994271 2994272
MS MSD
92493068005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 ug/L 70.9 mg/L 50000 50000 125000 127000 108 111 80-120 1 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/14/2020 11:37 AM without the written consent of Pace Analytical Services, LLC.
Page 17 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92493094
QC Batch: 565218 Analysis Method: SM 2320B-2011
QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92493094004
METHOD BLANK: 2995440 Matrix: Water
Associated Lab Samples: 92493094004
Blank Reporting
Parameter Units Result Limit
Alkalinity, Total as CaCO3 ug/L ND 5000
LABORATORY CONTROL SAMPLE: 2995441
Spike LCS
Parameter Units Conc. Result
Alkalinity, Total as CaCO3 ug/L 50000 46700
MDL Analyzed Qualifiers
5000 09/09/2013:24
LCS % Rec
% Rec Limits Qualifiers
93 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2995442 2995443
MS MSD
92493653001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 ug/L 21.7 mg/L 50000 50000 73500 73800 104 104 80-120 0 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2995444 2995445
MS MSD
92494262001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 ug/L 137 mg/L 50000 50000 185000 190000 97 105 80-120 2 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/14/2020 11:37 AM without the written consent of Pace Analytical Services, LLC.
Page 18 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92493094
QC Batch: 564083 Analysis Method: SM 4500-S2D-2011
QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92493094001, 92493094002, 92493094003, 92493094004
METHOD BLANK: 2990190 Matrix: Water
Associated Lab Samples: 92493094001, 92493094002, 92493094003, 92493094004
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Sulfide ug/L ND 100 50.0 09/03/20 22:12
LABORATORY CONTROL SAMPLE: 2990191
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide ug/L 500 525 105 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2990192 2990193
MS MSD
92493089004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide ug/L ND 500 500 514 426 98 81 80-120 19 10 R1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2990194 2990195
MS MSD
92493089005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide ug/L ND 500 500 538 542 101 102 80-120 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 09/14/2020 11:37 AM without the written consent of Pace Analytical Services, LLC.
Page 19 of 30

leAnalyiical
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92493094
QC Batch: 563234 Analysis Method: SM 521 OB-2011
QC Batch Method: SM 521OB-2011 Analysis Description: 5210E BOD, 5 day
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92493094001, 92493094002, 92493094003, 92493094004
METHOD BLANK: 2986644 Matrix: Water
Associated Lab Samples: 92493094001, 92493094002, 92493094003, 92493094004
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
BOD, 5 day ug/L ND 2000 2000 09/03/20 02:06
LABORATORY CONTROL SAMPLE: 2986645
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
BOD, 5 day ug/L 198000 187000 95 84.6-115
SAMPLE DUPLICATE: 2986647
92493066001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
BOD, 5 day ug/L ND ND 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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leAnalyiical
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Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92493094
QC Batch: 563291
Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993
Analysis Description: 300.0 IC Anions
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92493094001, 92493094002,
92493094003, 92493094004
METHOD BLANK: 2986807
Matrix: Water
Associated Lab Samples: 92493094001, 92493094002,
92493094003, 92493094004
Blank Reporting
Parameter Units
Result Limit
MDL
Analyzed Qualifiers
Chloride ug/L
ND 1000
600 08/29/20 21:55
Sulfate ug/L
ND 1000
500 08/29/20 21:55
LABORATORY CONTROL SAMPLE: 2986808
Spike LCS
LCS
% Rec
Parameter Units
Conc. Result
% Rec
Limits Qualifiers
Chloride ug/L
50000 52900
106
90-110
Sulfate ug/L
50000 52900
106
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2986809 2986810
MS MSD
92492563009
Spike Spike MS
MSD
MS MSD % Rec
Max
Parameter Units Result
Conc. Conc. Result
Result
% Rec % Rec Limits
RPD RPD Qual
Chloride ug/L 6.1 mg/L
50000 50000 58700
59400
105 107 90-110
1 10
Sulfate ug/L 303 mg/L
50000 50000 335000
353000
64 99 90-110
5 10 M6
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2986811 2986812
MS MSD
92493068007
Spike Spike MS
MSD
MS MSD % Rec
Max
Parameter Units Result
Conc. Conc. Result
Result
% Rec % Rec Limits
RPD RPD Qual
Chloride ug/L 11.2 mg/L
50000 50000 64000
64600
106 107 90-110
1 10
Sulfate ug/L ND
50000 50000 52100
52700
104 105 90-110
1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/14/2020 11:37 AM without the written consent of Pace Analytical Services, LLC.
Page 21 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92493094
QC Batch: 563226 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92493094001, 92493094002, 92493094003, 92493094004
METHOD BLANK: 2986620 Matrix: Water
Associated Lab Samples: 92493094001, 92493094002, 92493094003, 92493094004
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Nitrogen, Nitrate ug/L ND 40.0 10.0 08/29/20 00:31
LABORATORY CONTROL SAMPLE: 2986621
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate ug/L 1500 1600 106 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2986622 2986623
MS MSD
92493094003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate ug/L ND 1500 1500 1610 1580 108 106 90-110 2 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2986624 2986625
MS MSD
92493068005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate ug/L ND 1500 1500 1670 1670 111 111 90-110 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 09/14/2020 11:37 AM without the written consent of Pace Analytical Services, LLC.
Page 22 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92493094
QC Batch: 565139 Analysis Method: SM 5220D-2011
QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92493094001, 92493094002, 92493094003, 92493094004
METHOD BLANK: 2995321 Matrix: Water
Associated Lab Samples: 92493094001, 92493094002, 92493094003, 92493094004
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Chemical Oxygen Demand ug/L ND 25000 12500 09/10/20 15:49
LABORATORY CONTROL SAMPLE: 2995322
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chemical Oxygen Demand ug/L 750000 731000 97 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2995323 2995324
MS MSD
92492163005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand ug/L 107 mg/L 100000 100000 195000 220000 87 113 90-110 12 3 M1,R1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2995325 2995326
MS MSD
92492982001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand ug/L 284 mg/L 100000 100000 388000 365000 104 81 90-110 6 3 M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/14/2020 11:37 AM without the written consent of Pace Analytical Services, LLC.
Page 23 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92493094
QC Batch: 565598 Analysis Method: SM 531 OB-2011
QC Batch Method: SM 531 OB-2011 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92493094001, 92493094002, 92493094003, 92493094004
METHOD BLANK: 2997471 Matrix: Water
Associated Lab Samples: 92493094001, 92493094002, 92493094003, 92493094004
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Organic Carbon ug/L ND 1000 500 09/10/20 19:03
LABORATORY CONTROL SAMPLE: 2997472
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Organic Carbon ug/L 25000 26700 107 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2997473 2997474
MS MSD
92493731004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon ug/L 2460 25000 25000 28300 28500 103 104 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 09/14/2020 11:37 AM without the written consent of Pace Analytical Services, LLC.
Page 24 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92493094
QC Batch: 691762 Analysis Method: AM23G
QC Batch Method: AM23G Analysis Description: Low Level Volatile Fatty Acids
Laboratory: Pace Analytical Gulf Coast
Associated Lab Samples: 92493094001, 92493094002, 92493094003, 92493094004
METHOD BLANK: 2081486 Matrix: Water
Associated Lab Samples: 92493094001, 92493094002, 92493094003, 92493094004
Blank Reporting
Parameter Units Result Limit
MDL
Analyzed Qualifiers
Lactic Acid
mg/L
ND
0.053
0.053
09/11/2017:50
Acetic Acid
mg/L
ND
0.12
0.12
09/11/2017:50
Propionic Acid
mg/L
ND
0.053
0.053
09/11/2017:50
Formic acid
mg/L
ND
0.055
0.055
09/11/20 17:50
Butyric Acid
mg/L
ND
0.058
0.058
09/11/2017:50
Pyruvic Acid
mg/L
ND
0.060
0.060
09/11/2017:50
i-Pentanoic Acid
mg/L
ND
0.061
0.061
09/11/2017:50
Pentanoic Acid
mg/L
ND
0.056
0.056
09/11/2017:50
i-Hexanoic Acid
mg/L
ND
0.056
0.056
09/11/2017:50
Hexanoic Acid
mg/L
ND
0.058
0.058
09/11/2017:50
LABORATORY CONTROL SAMPLE & LCSD:
Parameter
2081487
Units
Spike
Conc.
2081488
LCS LCSD
Result Result
LCS LCSD
% Rec % Rec
% Rec
Limits
RPD
Max
RPD Qualifiers
Lactic Acid
mg/L
2
2.1
2.1
104
103
70-130
0
20
Acetic Acid
mg/L
2
2.0
2.0
102
102
70-130
1
20
Propionic Acid
mg/L
2
2.1
2.1
104
105
70-130
0
20
Formic acid
mg/L
2
2.0
2.0
103
103
70-130
0
20
Butyric Acid
mg/L
2
2.1
2.1
104
105
70-130
1
20
Pyruvic Acid
mg/L
2
2.0
2.0
101
103
70-130
2
20
i-Pentanoic Acid
mg/L
2
2.1
2.1
106
105
70-130
1
20
Pentanoic Acid
mg/L
2
2.0
2.0
101
102
70-130
1
20
i-Hexanoic Acid
mg/L
2
2.1
2.1
107
105
70-130
2
20
Hexanoic Acid
mg/L
2
2.1
2.1
104
104
70-130
0
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 09/14/2020 11:37 AM without the written consent of Pace Analytical Services, LLC. Page 25 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: Butner Landfill MNA
Pace Project No.: 92493094
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
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Date: 09/14/2020 11:37 AM without the written consent of Pace Analytical Services, LLC. Page 26 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Butner Landfill MNA
92493094
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92493094001
3902-MW2R
AM20GAX
691458
92493094002
3902-MW3R
AM20GAX
691458
92493094001
3902-MW2R
RSK 175 Modified
564315
92493094002
3902-MW3R
RSK 175 Modified
564315
92493094003
3902-MW1R
RSK 175 Modified
564315
92493094004
3902-NES-1
RSK 175 Modified
564315
92493094001
3902-MW2R
SM 2320B-2011
564905
92493094002
3902-MW3R
SM 2320B-2011
564905
92493094003
3902-MW1R
SM 2320B-2011
564905
92493094004
3902-NES-1
SM 2320E-2011
565218
92493094001
3902-MW2R
SM 4500-S2D-2011
564083
92493094002
3902-MW3R
SM 4500-S2D-2011
564083
92493094003
3902-MW1R
SM 4500-S2D-2011
564083
92493094004
3902-NES-1
SM 4500-S2D-2011
564083
92493094001
3902-MW2R
SM 5210B-2011
563234
SM 5210B-2011
563262
92493094002
3902-MW3R
SM 5210B-2011
563234
SM 5210B-2011
563262
92493094003
3902-MW1R
SM 5210B-2011
563234
SM 5210B-2011
563262
92493094004
3902-NES-1
SM 5210E-2011
563234
SM 5210B-2011
563262
92493094001
3902-MW2R
EPA 300.0 Rev 2.1 1993
563291
92493094002
3902-MW3R
EPA 300.0 Rev 2.1 1993
563291
92493094003
3902-MW1 R
EPA 300.0 Rev 2.1 1993
563291
92493094004
3902-NES-1
EPA 300.0 Rev 2.1 1993
563291
92493094001
3902-MW2R
EPA 353.2 Rev 2.0 1993
563226
92493094002
3902-MW3R
EPA 353.2 Rev 2.0 1993
563226
92493094003
3902-MW1 R
EPA 353.2 Rev 2.0 1993
563226
92493094004
3902-NES-1
EPA 353.2 Rev 2.0 1993
563226
92493094001
3902-MW2R
SM 5220D-2011
565139
SM 5220D-2011
565662
92493094002
3902-MW3R
SM 5220D-2011
565139
SM 5220D-2011
565662
92493094003
3902-MW1R
SM 5220D-2011
565139
SM 5220D-2011
565662
92493094004
3902-NES-1
SM 5220D-2011
565139
SM 5220D-2011
565662
92493094001
3902-MW2R
SM 5310B-2011
565598
92493094002
3902-MW3R
SM 5310B-2011
565598
92493094003
3902-MW1R
SM 5310B-2011
565598
92493094004
3902-NES-1
SM 5310E-2011
565598
92493094001
3902-MW2R
AM23G
691762
92493094002
3902-MW3R
AM23G
691762
92493094003
3902-MW1R
AM23G
691762
92493094004
3902-NES-1
AM23G
691762
Date: 09/14/2020 11:37 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 27 of 30

Document Name:
Document Revised: February 7, 2018
Sample Condition Upon Receipt{SCURj
Page 1 of 2
Document No.:
Issuing Authority:
�OAnalytlCal_
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville P Ralelgh❑ Mechanicsville[]
ConditionSample Client Name: • III�O# : 92493094
Upon �_ ieE�(� Project #
Courier: ❑Fed Ex UPS ❑uses ❑ClienIII
1111111111111111111
Commercial ❑Pace ❑Other:
r— Date/Initials Person Examining Contents: /JJ
Packing Material: []Bubble Wrap OBubbie Bags []None❑ Other Biological Tlssu Frozen? 2_9f�b
Thermometer: 92TO61 Type of Ice: []wet []Blue[-]Nona❑Yes ' ❑NO [PN/A
❑IR Gun ID
Cooler Temp ('Cl: Correction Factor: Add/Subtract (°C) 4,0
Temp should be above freezing to 6°C
Cooler Temp Corrected (°Cj: []Samples out of temp criteria. Samples on ice, cooling process
has begun
USDA Regulated Soil (❑ N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source ;Internationally,
T1lV­ ilm IncludineHawall and Puerto Alcol? FlYes rlNo
Comments/Dlscrepancv�
Chain of Custody Present?
Yes
[:)No
❑N/A
1.
Samples Arrived within Hold Time?
dyes
[]No
❑N/A
2.
Short Hold Time Analysis (<72 hr,l?
6yes
❑No
❑NIA
3.
Rush Turn Around Time Requested?
❑Yes
No
❑N/A
4.
Sufficient Volume?
ioYes
❑No
❑N/A
S.
Correct Containers Used?
-Pace Containers Used?
Yes
Yes
❑No
❑No
[]NIA
❑N/A
6.
Containers Intact?
Y.
❑No
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
qyes
Nn
❑N/A
8.
Sample Labels Match COC?
es
❑No
❑N/A
9.
-Includes Date/rime/ID/Analysis Matrix:
Heads ace in VOA Vials (>5-6mm)?
❑Yes
[6NO
❑N/A
10.
Trip Blank Present?
Trip 91ank Custody Seals Present?
❑Yes
❑yes
VQ
6YNo
[]NIA
❑NIA
11.
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Project Manager SRF Review:
Date/Time:
Lot ID of split containers:
Date:
Da te:
Reld Data Required? []Yes []NO
Page 28 of 30

Document Name: Document Revised February 7, 2018
Sample Condition upon Recel t(SCUR) Page 1 of 2
�IaceAnalyucal Document No.: Issuing Authority:
c_rne.ra_n�z_na„ nr, Pace Carolinas Qualltv Office
*Check mark top half of bore If pH and/or dechlorination is Project; W®# : 92493®94
verified and within the acceptance range for preservation
samples, PM: IVMG Due Dale: 09/14/20
Exceptions: VOA, Coliform, TOC, Oil and Crease, DRQ/8015 (water) DOC, tttis CLIENT: 92-Joyce Eris
**Bottom half of bole Is to list number of bottle
x
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VW-;1
pH Adjustment Log for Preserved Samples
Sample ID I Type of Preservative pH upon receipt Date preservatlon adjusted Time preservation Amount of Preservative
adjusted added
Note: Whenever there is a discrepancy affecting North Carolina compllance samples, a copy of this form will be cent to the North Carolina DEHNR
Out of hold, incorrect prese rvative, out of temp, in Correct conta Iner5.
Lat R
office (i.e.
Page 29 of 30 1

Section A
Required Client Information:
Company: La Bella Assodates
Address: 2211 West Meadov
Greensboro, NC 27407
Email To: vburbach labeila
Phone: [phone]
Requested Due Date/TAT: 10 Dav
W
F-
i
SAMPLE ID
One Character per box.
(A-Z, D-91 , -)
Sample Ids must be unique
3902-MW2R
2
3902-MW3R
3
3902-M W 1 R
4
3902-NES-1
5
6
7
8
9
10
11
12
Field
CHAIN -OF -CUSTODY 1 Analytical Request Document
The Chan -of -Custody is a LEGAL DOCUMENT, All relevant fields must be completed accurately.
Section B Section C
Required Project Information: Invoice Information: Page: 1 Of 1
Report To: Van Burbach Attention, Jason Falls
Rd lCopy, To: Mi uel Vazquez lCompany Name, Granville County, Solid Waste
Address: P.O. Box 906. Oxford NC 27565 1wa rrlar Annnr.,
Purchase Order No.
Client Project ID: Butner Landfill MNA
State I Loci
Container Order Number.
3566-2
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leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
October 06, 2020
Van Burbach
Joyce Engineering -NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Butner LF Dissolved Hydrogen -Revised Report
Pace Project No.: 92495185
Dear Van Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on September 11, 2020. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Gulf Coast
This revision was issued on 10/6/20 to report the requested analyte correctly.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Gretta Eller, LaBella Associates, D.P.C.
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 13

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
CERTIFICATIONS
Project: Butner LF Dissolved Hydrogen -Revised Report
Pace Project No.: 92495185
Pace Analytical Gulf Coast
7979 Innovation Park Drive, Baton Rouge, LA 70820
Arkansas Certification #: 88-0655
DoD ELAP Certification #: L18-597
Florida Certification #: E87854
Illinois Certification #: 004585
Kansas Certification #: E-10354
Louisiana/LELAP Certification #: 01955
North Carolina Certification #: 618
North Dakota Certification #: R-195
Oklahoma Certification #: 2019-101
South Carolina Certification #: 73006001
Texas Certification #: T104704178-19-11
USDA Soil Permit # P330-19-00209
Virginia Certification #: 460215
Washington Certification #: C929
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 13

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Butner LF Dissolved Hydrogen -Revised Report
Pace Project No.: 92495185
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92495185001
92495185002
3902-MW1R
3902-NES-1
Water
Water
09/10/20 11:26
09/10/20 10:08
09/11/20 08:20
09/11/20 08:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 13

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: Butner LF Dissolved Hydrogen -Revised Report
Pace Project No.: 92495185
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92495185001 3902-MW1R AM20GAX AWE 1 GCLA
92495185002 3902-NES-1 AM20GAX AWE 1 GCLA
GCLA = Pace Analytical Gulf Coast
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 13

leAnalyiical
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Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project: Butner LF Dissolved Hydrogen -Revised Report
Pace Project No.: 92495185
Lab Sample ID
Method
Client Sample ID
Parameters Result
92495185001
3902-MW1 R
AM20GAX
Hydrogen
92495185002
3902-NES-1
AM20GAX
Hydrogen
Units Report Limit Analyzed
2.8 nM 1.9 09/22/2015:45
2.4 nM 1.9 09/22/2016:14
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Qualifiers
Page 5 of 13

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner LF Dissolved Hydrogen -Revised Report
Pace Project No.: 92495185
Sample: 3902-MW1R Lab ID: 92495185001 Collected: 09/10/20 11:26 Received: 09/11/20 08:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
Indicator Gases Bubblestrip H2 Analytical Method: AM20GAX
Pace Analytical Gulf Coast
Hydrogen 2.8 nM 1.9 0.49 1 09/22/2015:45 1333-74-0
Date: 10/06/2020 12:19 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 13

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner LF Dissolved Hydrogen -Revised Report
Pace Project No.: 92495185
Sample: 3902-NES-1 Lab ID: 92495185002 Collected: 09/10/20 10:08 Received: 09/11/20 08:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
Indicator Gases Bubblestrip H2 Analytical Method: AM20GAX
Pace Analytical Gulf Coast
Hydrogen 2.4 nM 1.9 0.49 1 09/22/2016:14 1333-74-0
Date: 10/06/2020 12:19 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 13

Pace Analytical Services, LLC
lac,
Analyilcal ® 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: Butner LF Dissolved Hydrogen -Revised Report
Pace Project No.: 92495185
QC Batch: 692101 Analysis Method: AM20GAX
QC Batch Method: AM20GAX Analysis Description: Indicator Gases Bubble Strip H2
Laboratory: Pace Analytical Gulf Coast
Associated Lab Samples: 92495185001, 92495185002
METHOD BLANK: 2083210 Matrix: Air
Associated Lab Samples: 92495185001, 92495185002
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Hydrogen nM ND 1.9 0.49 09/22/2011:25
LABORATORY CONTROL SAMPLE & LCSD: 2083211 2083212
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers
Hydrogen nM 12 9.9 10 84 89 70-130 6 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/06/2020 12:19 PM without the written consent of Pace Analytical Services, LLC.
Page 8 of 13

leAnalyiical
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Huntersville, NC 28078
[phone]
QUALIFIERS
Project: Butner LF Dissolved Hydrogen -Revised Report
Pace Project No.: 92495185
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/06/2020 12:19 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 13

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Butner LF Dissolved Hydrogen -Revised Report
Pace Project No.: 92495185
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
92495185001 3902-MW1 R AM20GAX 692101
92495185002 3902-NES-1 AM20GAX 692101
Date: 10/06/2020 12:19 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical
Batch
Page 10 of 13

Document Name: Document Revised: February 7, 2018
Sample Condition Upon Receipt(SOUR) Page 1 of 2
JC6Analytiea( Document No.: Issuing Authority:
F-CAR-CS-033-Rev.06 Pace Carolinas Ruallty Office
Laboratory rece)ving samples: Asheville ❑ Eden[] Greenwood ❑ Huntersville Raleigh❑ Mechanicsville ❑
Sam* Condition . Client Name: Project I WO# : 92495185
' L_AU�(l'� 4S506+`aFts
Courier: ommerciai OFace x UPS LUSPS
[]Other-[:]clientII � III II III I' �� II I III
71 I92495185
DateltnitlalsPerson ExaminingContents:. r_i v
Biological Tissue F AZen?
Packing Material: Bubble Wrap ubble Bags []None❑ other Biological
ONO '' NIA
Thermometer 92TO61 Type of Ice: ❑wet ❑slue one
tR Gun10:
Cooler Temp VC): V,(Correction Factor: Add/Subtract t°C) 0.0 Temp shouidbe above freezing to VC
lll/� ❑Samples out of temp criteria. Samples on ice, cooling process
Cooler Temp Corrected {°C): has begur
USDA Regulated Soil (B'N/A, water sample)
Did samples originate In a quarantine zone within the United States: CA, NY, or sC (check maps)? Did samples originate from a foreign source {Internationally,
indudineHaw it and Puerto Ricol? ❑yes []NO_
Chain of Custody Present?ON
N°
❑NIA
1.
Samples Arrived Hithin Hold Time?(
—]No
C❑NIA
2•
Short Hold Time Analysis (<72 hr.)?.
b'o
[]N/A
3.
Rush Turn AsaundTlme Requested?OyestJNo
❑NIA
4.
Sufficient Volume?❑No
❑NIA
5.
Correct Containers Used?❑N°
❑NIA
6-
-Pace Containers Used?❑No
❑NIAContainers
Intact?,❑_�,N/�o
❑NIA
?,Oissolved
$•Sample
analysis: Samples Reid filtLJn°
❑N/A
LabEIS Match COC?❑No
❑NIA
9•
-Includes Date/irme/lD/Analysis Matrix:
Headspace',n VOA Vials (>5-fimm)7 ❑Yes No ❑NIA 10.
Trip Blank Present? ❑Yes ❑NIA 11.
Trip Blank Custody Seals Present? Oyes ;�N�.❑NIA
COMM ENTS/SAPAPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted: Date/Time:
Project Manager SCURF Review:
Project Manager SRF Review:
ID of sc9t containers:
Date:
Date:
Field Data Required? ❑Yes [:]No
Page 11 of 13

Document Name: Docurent Revised: February 7, 2018
b Sample Candltion Upon Recelpt(SCUR) Page i of 2
i ceAnalyUol Document No,: Issuing Authority:
F-CAR-0-0334tev.05 Pace Carolinas Quality Office
*Check mark top half of box If pH and/or dechlorination Is
verified and within the acceptance range for preservation
samples,
Exceptions: VOA, Coliform, TOC, Oil and Grease, e110/8015 (water) OOC, LLHg
—Bottom half of bolt is to list number of bottle
Project Wp# : 92495185
PM: NMG Due Date: 09/25/20
CLIENT: 92-Joyce Eng
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Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservatlon Amount of Preservative Lot 9
adjusted I added
Note: Whenever there is a citscrepancy affecting North Carolina compliance samples, a copv of this form will be s:nt to the North Carolina DEHINR Ceriifitation Office (Le
Out of hold, Incorrect preservative, out of temp, incorrect containers.
Page 12 of 13

CHAIN -OF -CUSTODY / Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Section A Section B Section C
Required Client information: Required Project Information: Invoice information: Pa e - 1 Of 1
Company La Bella Associates Reporl To: Van Burbach ALIanIIUn: ,Jason Falls
Address_ 2211 West Meadowview Rd Copy To: Miguel Vazquez Company Name. Granville County, Solid Waste
Greensboro, NC 27407
Address: P.D. Box 906. Oxford NC 27565
Regulatory Agency
rmall Toy vburbachCf'o teen ineerin ,com
Purchase order No
Phones (336 323-0092 Fax:
CEianl Project ID: Butner Landfill Dissolved H
State/ Location
Requested Doe QaterrAT 10 Da Default
Container Order Number.
North Carolina
Re
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Analysis
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RELINQUISHED BY / AFFILIATION
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ACCEPTED BY I AFFILIATION
DATE
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SAMPLE CONDITIONS
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leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
October 06, 2020
Van Burbach
Joyce Engineering -NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Granville -Butner
Pace Project No.: 92498324
Dear Van Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on October 01, 2020. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
/'i"A""
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Gretta Eller, LaBella Associates, D.P.C.
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 13

lacmnalyfica('
www,pacelabs.com
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Project: Granville -Butner
Pace Project No.: 92498324
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 13

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Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Granville -Butner
Pace Project No.: 92498324
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92498324001
92498324002
MW-3R
Trip Blank
Water
Water
09/30/20 13:35
09/30/20 08:00
10/01/20 08:47
10/01/20 08:47
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 13

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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: Granville -Butner
Pace Project No.: 92498324
Analytes
Lab ID Sample ID
Method Analysts Reported Laboratory
92498324001 MW-3R
EPA 8260D SAS 4 PASI-C
92498324002 Trip Blank
EPA 8260D CL 4 PASI-C
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 4 of 13

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[phone]
ANALYTICAL RESULTS
Project: Granville -Butner
Pace Project No.: 92498324
Sample: MW-3R
Parameters
Lab ID: 92498324001 Collected:
Report
Results Units Limit
09/30/20 13:35
MDL DF
Received: 10/01/20 08:47 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Vinyl chloride
ND ug/L 1.0
0.24 1
10/06/20 00:31
75-01-4
Surrogates
4-Bromofluorobenzene (S)
101 % 70-130
1
10/06/20 00:31
460-00-4
1,2-Dichloroethane-d4 (S)
99 % 70-130
1
10/06/20 00:31
17060-07-0
Toluene-d8 (S)
99 % 70-130
1
10/06/20 00:31
2037-26-5
Date: 10/06/2020 04:21 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 13

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Granville -Butner
Pace Project No.: 92498324
Sample: Trip Blank
Parameters
Lab ID: 92498324002 Collected:
Report
Results Units Limit
09/30/20 08:00
MDL DF
Received: 10/01/20 08:47 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Vinyl chloride
ND ug/L 1.0
0.24 1
10/03/20 01:04
75-01-4
Surrogates
4-Bromofluorobenzene (S)
99 % 70-130
1
10/03/20 01:04
460-00-4
1,2-Dichloroethane-d4 (S)
100 % 70-130
1
10/03/20 01:04
17060-07-0
Toluene-d8 (S)
100 % 70-130
1
10/03/20 01:04
2037-26-5
Date: 10/06/2020 04:21 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 13

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Granville -Butner
Pace Project No.: 92498324
QC Batch: 570654
Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D
Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92498324002
METHOD BLANK: 3023013
Matrix: Water
Associated Lab Samples: 92498324002
Blank Reporting
Parameter
Units
Result Limit MDL
Analyzed Qualifiers
Vinyl chloride
ug/L
ND 1.0
0.24 10/02/20 23:52
1,2-Dichloroethane-d4 (S)
%
99 70-130
10/02/20 23:52
4-Bromofluorobenzene (S)
%
99 70-130
10/02/20 23:52
Toluene-d8 (S)
%
100 70-130
10/02/20 23:52
LABORATORY CONTROL SAMPLE: 3023014
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits Qualifiers
Vinyl chloride
ug/L
50 48.2 96
70-131
1,2-Dichloroethane-d4 (S)
%
94
70-130
4-Bromofluorobenzene (S)
%
103
70-130
Toluene-d8 (S)
%
100
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3023015 3023016
MS MSD
92498006009
Spike Spike MS MSD
MS MSD % Rec Max
Parameter Units
Result
Conc. Conc. Result Result
% Rec % Rec Limits RPD RPD Qual
Vinyl chloride ug/L
ND
20 20 20.8 20.8
104 104 70-156 0 30
1,2-Dichloroethane-d4 (S) %
104 105 70-130
4-Bromofluorobenzene (S) %
99 99 70-130
Toluene-d8 (S) %
98 100 70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/06/2020 04:21 PM without the written consent of Pace Analytical Services, LLC.
Page 7 of 13

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Granville -Butner
Pace Project No.: 92498324
QC Batch: 570978
Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D
Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92498324001
METHOD BLANK: 3024497
Matrix: Water
Associated Lab Samples: 92498324001
Blank Reporting
Parameter
Units
Result Limit
MDL
Analyzed Qualifiers
Vinyl chloride
ug/L
ND 1.0
0.24 10/05/20 23:56
1,2-Dichloroethane-d4 (S)
%
95 70-130
10/05/20 23:56
4-Bromofluorobenzene (S)
%
98 70-130
10/05/20 23:56
Toluene-d8 (S)
%
100 70-130
10/05/20 23:56
LABORATORY CONTROL SAMPLE:
3024498
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits Qualifiers
Vinyl chloride
ug/L
50 42.2
84
70-131
1,2-Dichloroethane-d4 (S)
%
93
70-130
4-Bromofluorobenzene (S)
%
98
70-130
Toluene-d8 (S)
%
98
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3024499 3024500
MS MSD
92498205001
Spike Spike MS
MSD
MS MSD % Rec
Max
Parameter Units
Result
Conc. Conc. Result
Result
% Rec % Rec Limits RPD
RPD Qual
Vinyl chloride ug/L
<24.2
2000 2000 2100
2080
105 104 70-156 1
30
1,2-Dichloroethane-d4 (S) %
92 94 70-130
4-Bromofluorobenzene (S) %
101 99 70-130
Toluene-d8 (S) %
97 99 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3024561 3024562
MS MSD
92497302002
Spike Spike MS
MSD
MS MSD % Rec
Max
Parameter Units
Result
Conc. Conc. Result
Result
% Rec % Rec Limits RPD
RPD Qual
Vinyl chloride ug/L
ND
20 20 21.1
19.1
105 95 70-156 10
30
1,2-Dichloroethane-d4 (S) %
95 91 70-130
4-Bromofluorobenzene (S) %
99 100 70-130
Toluene-d8 (S) %
100 98 70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/06/2020 04:21 PM without the written consent of Pace Analytical Services, LLC.
Page 8 of 13

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: Granville -Butner
Pace Project No.: 92498324
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/06/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 13

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Granville -Butner
Pace Project No.: 92498324
Lab ID
Sample ID
QC Batch Method
QC Batch
92498324001
92498324002
MW-3R
Trip Blank
EPA 8260D
EPA 8260D
570978
570654
Date: 10/06/2020 04:21 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical Method
Analytical
Batch
Page 10 of 13

Document Name: Document Revised: February 7, 2018
page1of1
Sample Candltion Upvn Receipt(SCUR)
aceAr?a1601 Document No.: issuing Authority:
jF-CAR-t5-033-Rev.06 °ace Carolinas Quality Office
Laboratory receiving samples: Raleigh[] Mechanicsville❑
Asheville ❑ EdenC Greenwood ❑ Huntersville g
.lE! Condition Client Name* _
Prect x Wp# : 92498324
� a
l�A c, roan tqcS
Courier: ❑F d Ex ❑UPS ❑LISPS ❑Client II
❑ Commercial Pace ❑ Other: `
92498324
7 7 i7yes me'll'a
Efate/Inigats Person Examiningtantents: 5 AP J ZCL'
Pacfting Material: ❑Bubble Wrap �ble Bags []None ❑ Other Blalaglcal Tissue Fro n?
❑Yes ❑No /A
Thermometer: 92TO61 Type of ace: ❑Duet ❑Blue []None
Q(R Gun 10:
Cooler Temp (°C): 2 -7 �Correction factor: Add/Subtract ('C) 0.0 Temp should ae above freezing to VC
Cooler Temp Corrected CC): 2 i-- ❑sampiesout of temp chteTEa. Samples on ice, ceoling process
has begun
USDA Regulated 5oil (EI/N/A, water sample)
Did samples originate .n a quarantine zone within the United States: CA, NY, or SC (check maps)? Did 5a ngleand Puerto R c Dessorarforeign
source llnt❑ at:ona lly,
incluNO
l—Ives 7No
Chain of Custody Present?
&es
❑No
❑N/A
1.
Samples Arrived within Hold Time?
es
❑No
❑N/A
2.
Short Hold Time Analysis (02 hr.)?
[]yes
[ifo
❑NIA
3•
RushTum Around Time Requested?
❑Yes
o
❑NIA
4.
Sufficient Volume?
es
❑No
[]N/A
5.
Correct Containers Used?
es�
❑No
❑NIA
6.
-Pace Containers Used?
r�
]./
[]No
❑NIA
Containers Intact?
lyres
[]No
❑]N//A
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
❑No
11A
8.
Sample Labels Match COC?
es
❑No
❑NIA
9.
-includes Date/Time/ID/Analysis Matrix:
Headspace in VOA Vials (SS-6mml? ❑Yes No N/AV5 10.
Trip Blank Present? PS No N/A 11.
Trio Blank Custody Seals Present? Yes ❑No N/A
COMMIENTSISAMPLE DISCREPANCY
Lot ID of spilt containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted: Date/Time
Project Manager SCURF Review: Date:
Date:
Project Manager SRF Revlew:
Field Data Required? []Yes []No
Page 11 of 13

Document came:
Sample Contdltlon Upon Retell
Ar!alyUcMai Document " o.:
P-CAR-CS-033-Rev,06
Cecument Revised: February 7, 2019
Page 1 of 2
issuing Authority:
?ace Carolinas Quality Office
*Check mark top half of box If pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptiom; VOA, Calif'orm, i CC, Oil and Grease, DRO/SC15 (vvaterl OCC, Wig
**Bottom half of box is to list number of bottle
Project � WQ# : 92498324
PM: NMG Due Date: 10/15/20
CLIENT: 92-Joyce Eng
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PH Adjustment Lag for Preserved Samples
Sample ID Tyipe of Preseative pH upon recelpt Date preservation adiusted Time preservdion Amount of Preservative
ryLet d
adjusted I added
Note: Whenever there s a discrepancy affectin; North Carolina compliance samples, a copy of this form will 4e,ent to the ucrth Carolina DEHNR Certification Office fl.e.
Out of hold, Incorrect preserlative, out of temp, incorrect containers.
Page 12 of 13

, .PSceArralytica!'
www.vutues.torr
Section A
Required Client Information:
Section B
Required Project Information:
CHAIN -OP -CUSTODY 1 Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Section C
Invoice Information:
iT
N
d
Paqe : 1 Of 1
Company. LaBella Associates, D.P.C. - NC
Report To Van Burbach
Attentior:
Address2211 W. Meadomiew Road
Copy To:
Company Name:
Greensboro, NC 27407
Address:
Fteguiatory Agency
Email: vburbach@;abellapr.com
Purchase Order#:
Pace Quote:
Phone. (336)32MO92 Fax
Project Name: Granville -Butner
Pace Project Manager: nicole.gastorowski pacelabs,corn.
State I Location
Requested Due Date:
Project #'
Pace Profile #3566
NC
Requested
Analysis
Filtered
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SAMPLECONDmONS
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SAMPLER NAME AND SIGNATURE
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C a

Appendix D
Historical Groundwater Elevations

APPENDIX D: Historical Groundwater Elevations
Background
Downgradient
Well ID:
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NE
Well TOC Elev.:
460.51
331.60
330.96
340.80
343.88
362.53
328.40
Well Depth:
56.00
18.85
35.83
31.43
23.52
32.63
32.80
21-Aug-99
418.68
329.13
328.06
330.50
330.83
352.10
NI
16-Nov-99
419.75
325.38
324.51
331.53
334.33
352.97
NI
10-May-00
424.53
329.60
328.83
334.15
334.49
355.72
NI
26-Oct-00
419.21
329.26
328.15
331.33
330.94
352.78
NI
18-Apr-01
418.76
329.42
328.63
333.57
334.36
354.22
NI
26-Oct-01
412.53
329.04
327.94
330.57
330.23
350.92
NI
13-Jun-02
413.70
328.38
327.41
330.21
330.29
351.04
NI
19-Nov-02
413.40
329.25
328.35
331.57
337.17
350.94
NI
27-Jun-03
423.61
329.57
328.93
334.24
333.99
355.21
NI
29-Dec-03
420.23
329.70
329.11
334.49
334.78
354.92
NI
30-Jun-04
418.81
329.38
328.48
332.26
331.39
353.10
NI
28-Dec-04
418.02
329.50
328.91
333.45
334.14
355.14
NI
29-Jun-05
418.81
329.10
329.26
331.62
330.90
352.76
NI
29-Dec-05
413.38
329.29
328.71
332.78
334.27
351.52
NI
27-Jun-06
414.75
329.17
328.40
332.18
333.56
353.43
NI
28-Dec-06
415.54
329.40
328.86
333.57
335.24
354.02
NI
12-Jul-07
438.64
328.69
327.97
331.31
330.52
352.30
NI
18-Dec-07
412.59
328.94
328.08
330.32
327.92
347.90
306.54
8-Jul-08
414.52
329.20
326.00
331.46
330.85
351.03
NM
17-Dec-08
412.79
329.39
328.84
333.15
335.03
350.82
NM
9-Jul-09
417.16
329.17
329.48
332.30
331.36
352.17
310.12
16-Dec-09
418.11
329.55
329.09
334.57
336.94
352.87
NM
24-Jun-10
422.42
329.41
328.77
333.65
333.15
353.62
NM
13-Dec-10
415.96
329.49
328.85
332.81
330.34
350.08
NM
20-Jun-11
416.00
328.95
328.18
336.77
331.38
351.83
NM
5-Dec-11
412.94
329.31
328.65
332.32
329.51
349.87
NM
11-Jun-12
414.56
329.10
328.35
332.52
331.33
351.75
312.50
12-Dec-12
412.83
329.19
328.36
331.67
330.35
349.48
NM
1-May-13
415.69
329.65
329.13
334.49
335.15
353.63
317.11
5-Aug-13
417.97
329.02
328.41
333.32
332.83
353.01
NM
24-Feb-14
415.81
329.68
329.17
334.48
331.63
351.78
316.15
11-Aug-14
416.23
329.38
328.48
332.04
329.08
350.08
310.93
10-Mar-15
417.09
329.87
329.45
335.07
336.42
353.13
317.55
17-Aug-15
417.71
328.65
327.81
331.05
327.73
347.63
308.80
17-Feb-16
418.51
330.10
329.71
335.05
337.53
353.44
317.87
9-Aug-16
418.59
329.50
328.61
332.95
330.95
352.03
312.65
13-Feb-17
415.21
329.45
328.96
333.10
333.03
350.83
313.45
22-Aug-17
414.68
328.55
327.61
331.60
329.78
350.38
310.55
5-Feb-18
412.31
329.41
328.21
332.07
328.87
348.18
317.10
14-Aug-18
415.86
328.96
327.96
331.97
329.68
350.12
312.51
4-Feb-19
420.86
329.67
329.28
335.62
335.42
355.30
316.02
6-Aug-19
420.05
329.35
328.37
332.98
329.73
351.46
310.34
12-Feb-20
417.43
329.75
329.30
335.65
336.08
352.38
317.67
27-Aug-20
418.84
329.18
328.55
333.42
330.48
351.34
310.90
Notes: TOC = Top of casing.
Elevations in feet above mean sea level
Granville County -Butner Landfill
Permit No. 39-02
NM = Water level not measured.
NI = Well not yet installed.
La Bella Associates

Appendix E
Historical Constituents in Groundwater

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
INORGANICS
Antimony
8-Sep-94
---
30
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
30
N D
N D
N D
N D
N D
N D
---
---
9-Feb-95
---
30
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
30
ND
ND
ND
ND
ND
ND
---
---
15-Nov-95
---
30
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
30
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
30
ND
ND
ND
ND
ND
ND
---
---
17-Jun-97
---
30
ND
ND
ND
ND
ND
ND
---
---
1-Dec-97
---
30
ND
ND
ND
ND
ND
ND
---
---
20-May-98
---
30
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
30
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
30
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
30
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
30
ND
80.0
38.0
32.0
33.0
31.0
---
---
26-Oct-00
---
30
30.0
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
30
ND
ND
ND
ND
ND
ND
---
---
27-Oct-01
---
30
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
30
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
30
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
30
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
30
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
30
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
30
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
30
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
30
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
30
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
6
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
6
ND
ND
ND
ND
ND
ND
---
ND
IMAC = 1.4 pg/L (10/23/07)
19-Dec-07
---
6
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
---
6
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
2.6
6.0
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
2.6
6.0
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
2.6
6.0
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
2.6
6.0
ND
ND
ND
2.9 J
ND
ND
---
ND
IMAC = 1 pg/L (8/1/10)
13-Dec-10
2.6
6.0
ND
ND
3.0 J
ND
2.8 J
ND
---
ND
20-Jun-11
5.0
6.0
ND
ND
ND
ND
6.0
ND
---
ND
5-Dec-11
5.0
6.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
5.0
6.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
5.0
6.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
5.0
6.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.0
6.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
5.0
6.0
8.8
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
5.0
6.0
ND
10.5
8.0
ND
ND
ND
---
ND
10-Mar-15
3.8
6.0
ND
7.1
6.5
3.9 J
ND
ND
---
ND
18-Aug-15
3.8
6.0
ND
6.2
4.8 J
4.1 J
ND
ND
---
ND
16-Feb-16
3.8
6.0
ND
9.9
6.5
4.3 J
ND
ND
---
ND
9-Aug-16
3.8
6.0
ND
7.7
ND
ND
ND
ND
---
ND
13-Feb-17
3.9
6.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
3.9
6.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
3.9
6.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
3.9
6.0
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
3.9
5.0
ND
ND
ND
ND
ND
ND
---
ND
7-Aug-19
3.0
5.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
3.0
5.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
3.0
5.0
ND
ND
ND
ND
ND
ND
---
ND
Arsenic
8-Sep-94
---
10
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
10
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
10
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
10
ND
ND
ND
ND
ND
ND
---
---
15-Nov-95
---
10
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
10
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
10
ND
ND
ND
ND
ND
ND
---
---
17-Jun-97
---
10
6.0 J
15.0
ND
ND
ND
ND
---
---
1-Dec-97
---
10
ND
5.0 J
ND
ND
ND
ND
---
---
20-May-98
---
10
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
10
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
10
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
10
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
10
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
10
N D
N D
N D
N D
N D
N D
---
---
18-Apr-01
---
10
ND
ND
ND
N D
N D
N D
---
---
27-Oct-01
---
10
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
10
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
10
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
10
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
10
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
10
2.0 J
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
10
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 50 pg/L (10/23/07)
19-Dec-07
---
10
ND
4.1 J
ND
ND
ND
ND
ND
ND
8-Jul-08
---
10
ND
4.9 J
ND
ND
ND
ND
---
ND
17-Dec-08
2.7
10.0
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
2.7
10.0
ND
13.5
10.9
5.6 J
ND
4.0 J
ND
ND
16-Dec-09
2.7
10.0
ND
10.6
6.4 J
5.0 J
ND
3.6 J
---
ND
NC 2L = 10 pg/L (02/05/10)
24-Jun-10
2.7
10.0
ND
11.8
8.1 J
8.2 J
3.3 J
3.1 J
---
ND
Resample >
12-Aug-10
2.7
10.0
---
---
7.2 J
---
---
---
---
ND
Resample >
31-Aug-10
2.7
10.0
---
15.4
---
---
---
---
---
ND
13-Dec-10
2.7
10.0
ND
4.9 J
2.7 J
5.4 J
ND
ND
---
ND
20-Jun-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
5.0
10.0
ND
5.4 J
ND
ND
ND
ND
ND
ND
12-Dec-12
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.0
10.0
ND
ND
5.6 J
ND
ND
ND
---
ND
24-Feb-14
5.0
10.0
ND
6.4 J
ND
ND
ND
ND
ND
ND
12-Aug-14
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
2.5
10.0
4.1 J
5.4 J
ND
ND
3.1 J
3.2 J
---
3.0 J
18-Aug-15
2.5
10.0
ND
5.1 J
ND
ND
ND
ND
---
ND
16-Feb-16
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
2.5
10.0
ND
ND
ND
ND
ND
ND
---
5.1 J
13-Feb-17
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
5.0
10.0
ND
5.4 J
ND
ND
ND
ND
---
ND
4-Feb-19
5.0
10.0
ND
5.7 J
ND
ND
ND
ND
---
ND
7-Aug-19
4.7
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
4.7
10.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
4.7
10.0
ND
ND
ND
ND
ND
ND
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 1 of 20

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Barium
8-Sep-94
---
500
ND
270
ND
ND
830
860
---
---
1-Dec-94
---
500
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
500
ND
ND
ND
ND
510
ND
---
---
2-Mar-95
---
500
ND
ND
ND
ND
ND
ND
---
---
15-Nov-95
---
500
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
500
ND
ND
ND
ND
ND
ND
---
---
22-N ov-96
---
500
ND
82.0
30.0
N D
15.0
N D
---
---
17-Jun-97
---
500
200
320
37.0
17.0
210
31.0
---
---
1-Dec-97
---
500
61.0
180
43.0
46.0
220
33.0
---
---
20-May-98
---
500
30.0
150
45.0
13.0
180
22.0
---
---
19-Nov-98
---
500
48.0
120
42.0
ND
380
12.0
---
---
21-Jul-99
---
500
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
500
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
500
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
500
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
500
ND
ND
ND
ND
ND
ND
---
---
27-Oct-01
---
500
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
500
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
500
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
500
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
500
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
500
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
500
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
500
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
500
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
500
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
500
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
100
5.2 J
120
64.9
1.5 J
64.1
1.8 J
---
0.20 J
12-Jul-07
---
100
2.5 J
129
65.7 J
1.1 J
77.0 J
1.3 J
---
ND
NC 2L = 2,000 pg/L (10/23/07)
19-Dec-07
---
100
2.8 B
99.2
50.0 B
1.4 B
49.6 B
1.7 B
87.8
11.7
8-Jul-08
---
100
5.8 J
102
58.4 J
1.1 B
57.9 J
1.2 B
---
0.29 J
17-Dec-08
0.20
100
2.7 B
92.9 J
53.1 B
1.2 B
55.5 J
1.1 B
---
10.7 J
9-Jul-09
0.20
100
4.6 B
121
63.4 B
0.37 B
81.4 B
0.94 B
72.4 B
17.6 J
16-Dec-09
0.20
100
2.9 B
108
62.8 B
0.61 B
56.8 B
0.87 B
---
17.1 J
NC 2L = 700 pg/L (02/05/10)
24-Jun-10
0.20
100
2.5 B
115 B
61.1 B
1.6 B
93.5 B
1.4 B
---
27.3 J
13-Dec-10
0.20
100
4.3 B
122
67.9 J
1.3 B
90.6 J
1.5 B
---
12.1 J
20-Jun-11
5.0
100
ND
108
70.7 J
ND
84.7 J
ND
---
ND
5-Dec-11
5.0
100
ND
118
73.0 J
ND
90.6 J
ND
---
ND
11-Jun-12
5.0
100
ND
138
65.2 J
ND
76.4 J
ND
61.3 J
ND
12-Dec-12
5.0
100
ND
113
64.7 J
ND
73.6 J
ND
---
ND
1-May-13
5.0
100
ND
118
69.1 J
ND
84.2 J
ND
81.2 J
ND
5-Aug-13
5.0
100
ND
111
65.1 J
ND
95.6 J
ND
---
ND
24-Feb-14
5.0
100
ND
93.8 J
44.8 J
ND
139
ND
ND
ND
12-Aug-14
5.0
100
ND
125
66.4 J
ND
121
ND
---
ND
10-Mar-15
2.5
100
3.0 J
109
61.8 J
ND
116
ND
---
ND
18-Aug-15
2.5
100
4.4 J
119
63.1 J
ND
81.3 J
ND
---
ND
16-Feb-16
2.5
100
5.2 J
123
72.7 J
3.0 J
126
ND
---
ND
9-Aug-16
2.5
100
4.5 J
123
73.3 J
ND
109
ND
---
ND
13-Feb-17
2.5
100
7.8 J
112
68.3 J
ND
151
5.6 J
---
ND
22-Aug-17
2.5
100
ND
102
64.5 J
ND
99.9 J
ND
---
ND
5-Feb-18
2.5
100
8.0 J
117
73.5 J
ND
161
ND
---
ND
13-Aug-18
2.5
100
3.8 J
116
67.6 J
ND
103
ND
---
ND
4-Feb-19
2.5
5.0
ND
104
44.3
ND
110
ND
---
ND
7-Aug-19
1.0
5.0
5.4
113
73.8
1.2 J
95.1
1.9 J
---
ND
12-Feb-20
1.0
5.0
3.6 J
110
56.2
2.5 J
147
1.6 J
---
ND
27-Aug-20
3.5
5.0
4.5 J
127
83.2
ND
128
ND
---
ND
Beryllium
8-Sep-94
---
2
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
2
ND
ND
ND
ND
4.0
ND
---
---
9-Feb-95
---
2
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
2
ND
ND
ND
ND
2.0
ND
---
---
15-Nov-95
---
2
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
2
ND
ND
ND
ND
6.0
ND
---
---
22-Nov-96
---
2
ND
ND
ND
ND
3.0
ND
---
---
17-Jun-97
---
2
2.0
3.0
ND
ND
1.0
ND
---
---
1-Dec-97
---
2
ND
ND
ND
ND
ND
ND
---
---
20-May-98
---
2
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
2
ND
ND
ND
ND
2.0
ND
---
---
21-Jul-99
---
2
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
2
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
2
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
2
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
2
ND
12.0
ND
ND
ND
ND
---
---
27-Oct-01
---
2
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
2
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
2
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
2
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
2
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
2
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
1
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
1
ND
ND
ND
ND
ND
ND
---
ND
IMAC = 4 pg/L (10/23/07)
19-Dec-07
---
1
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
---
1
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
0.10
1.0
ND
ND
ND
ND
0.14 J
ND
---
ND
9-Jul-09
0.10
1.0
ND
0.18 J
0.22 J
0.17 J
ND
ND
0.23 J
ND
16-Dec-09
0.10
1.0
ND
0.15 J
0.17 J
0.15 J
0.25 J
ND
---
ND
24-Jun-10
0.10
1.0
ND
ND
0.27 J
0.16 J
ND
ND
---
ND
13-Dec-10
0.10
1.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
18-Aug-15
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.50
1.0
ND
ND
ND
ND
0.57 J
ND
---
ND
22-Aug-17
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
7-Aug-19
0.20
1.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
0.20
1.0
0.27 J
ND
ND
ND
ND
0.21 J
---
ND
27-Aug-20
0.70
1.0
ND
ND
ND
ND
ND
ND
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 2 of 20

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Cadmium
8-Sep-94
---
1
ND
ND
ND
ND
ND
4.0
---
---
1-Dec-94
---
1
N D
N D
N D
N D
N D
ND
---
---
9-Feb-95
---
1
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
1
ND
ND
ND
ND
ND
ND
---
---
15-Nov-95
---
1
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
1
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
1
ND
ND
ND
ND
ND
ND
---
---
17-Jun-97
---
1
ND
3.0
1.0
ND
ND
ND
---
---
1-Dec-97
---
1
ND
2.0
ND
ND
ND
ND
---
---
20-May-98
---
1
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
1
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
1
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
1
ND
3.0
3.0
ND
2.0
ND
---
---
10-May-00
---
1
5.0
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
1
N D
2.0
ND
N D
N D
N D
---
---
18-Apr-01
---
1
N D
11.0
ND
ND
ND
ND
---
---
27-Oct-01
---
1
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
1
ND
2.0
ND
ND
ND
ND
---
---
19-Nov-02
---
1
2.0
2.0
ND
ND
2.0
ND
---
---
27-Jun-03
---
1
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
1
ND
1.0
ND
ND
ND
ND
---
ND
30-Jun-04
---
1
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
1
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
1
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
1
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
1
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
1
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
1
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 1.75 pg/L (10/23/07)
19-Dec-07
---
1
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
---
1
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
0.50
1.0
ND
1.4
ND
ND
ND
ND
ND
ND
16-Dec-09
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 2 pg/L (02/05/10)
24-Jun-10
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
18-Aug-15
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
7-Aug-19
0.40
1.0
ND
ND
ND
0.48 J
ND
ND
---
ND
12-Feb-20
0.40
1.0
ND
ND
ND
0.69 J
ND
ND
---
ND
27-Aug-20
0.40
1.0
ND
ND
ND
ND
ND
ND
---
ND
Chromium
8-Sep-94
---
10
8.0
44.0
ND
6.0
48.0
80.0
---
---
1-Dec-94
---
10
14.0
ND
ND
ND
18.0
ND
---
---
9-Feb-95
---
10
14.0
ND
ND
10.0
ND
ND
---
---
2-Mar-95
---
10
ND
ND
ND
ND
ND
ND
---
---
15-Nov-95
---
10
13.0
13.0
ND
ND
ND
ND
---
---
28-May-96
---
10
33.0
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
10
3.0
ND
ND
ND
ND
3.0
---
---
17-Jun-97
---
10
57.0
43.0
ND
3.0
2.0
6.0
---
---
1-Dec-97
---
10
29.0
ND
ND
ND
ND
ND
---
---
20-May-98
---
10
10.0
3.0
ND
ND
12.0
ND
---
---
19-Nov-98
---
10
17.0
3.0
ND
ND
5.0
ND
---
---
21-J u l-99
---
10
ND
ND
N D
N D
N D
N D
---
---
16-Nov-99
---
10
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
10
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
10
N D
N D
N D
N D
N D
N D
---
---
18-Apr-01
---
10
N D
12.0
ND
ND
ND
N D
---
---
27-Oct-01
---
10
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
10
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
10
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
10
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
10
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
10
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 50 pg/L (10/23/07)
19-Dec-07
---
10
ND
2.0 B
ND
ND
ND
ND
1.1 B
1.4 J
8-Jul-08
---
10
ND
0.54 J
0.58 J
ND
ND
ND
---
ND
17-Dec-08
0.40
10.0
0.73 J
1.8 J
0.96 J
N D
0.96 J
0.70 J
---
N D
9-Jul-09
0.40
10.0
1.2 J
2.4 J
1.1 J
1.6 J
0.68 J
0.53 J
4.8 J
ND
16-Dec-09
0.40
10.0
1.3 J
ND
ND
ND
0.95 J
ND
---
ND
NC 2L = 10 pg/L (02/05/10)
24-Jun-10
0.40
10.0
1.1 B
3.5 B
2.8 B
2.4 B
1.2 B
1.4 B
---
0.71 J
13-Dec-10
0.40
10.0
2.5 J
1.3 J
1.8 J
0.69 J
0.57 J
1.2 J
---
ND
20-Jun-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
5.0
10.0
ND
8.6 J
ND
ND
ND
ND
ND
ND
12-Dec-12
5.0
10.0
ND
5.2 J
ND
ND
ND
ND
---
ND
1-May-13
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
18-Aug-15
2.5
10.0
ND
2.7 J
ND
ND
ND
6.7 J
---
ND
16-Feb-16
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
2.5
10.0
2.8 B
2.8 B
ND
ND
ND
ND
---
2.9 J
13-Feb-17
2.5
10.0
ND
2.6 J
ND
ND
ND
ND
---
ND
22-Aug-17
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
2.5
5.0
ND
ND
ND
ND
ND
ND
---
ND
7-Aug-19
1.0
5.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
1.0
5.0
1.5 J
ND
ND
1.1 J
ND
ND
---
ND
27-Aug-20
3.7
5.0
ND
ND
ND
ND
ND
ND
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 3 of 20

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Cobalt
8-Sep-94
---
10
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
10
11.0
ND
13.0
16.0
22.0
ND
---
---
9-Feb-95
---
10
20.0
14.0
ND
48.0
39.0
ND
---
---
2-Mar-95
---
10
16.0
21.0
ND
29.0
121.0
ND
---
---
15-Nov-95
---
10
20.0
21.0
ND
ND
27.0
ND
---
---
28-May-96
---
10
30.0
16.0
ND
ND
122
ND
---
---
22-Nov-96
---
10
6.0
13.0
ND
4.7
93.0
ND
---
---
17-Jun-97
---
10
130
38.0
ND
6.0
45.0
3.0
---
---
1-Dec-97
---
10
32.0
21.0
ND
12.0
36.0
4.0
---
---
20-May-98
---
10
15.0
16.0
2.0
9.0
100
3.0
---
---
19-Nov-98
---
10
21.0
16.0
2.0
7.0
180
3.0
---
---
21-Jul-99
---
10
ND
16.0
ND
ND
100
ND
---
---
16-Nov-99
---
10
ND
15.0
ND
ND
38.0
ND
---
---
10-May-00
---
10
ND
17.0
ND
ND
61.0
ND
---
---
26-Oct-00
---
10
ND
15.0
ND
ND
ND
ND
---
---
18-Apr-01
---
10
ND
27.0
ND
ND
74.0
ND
---
---
27-Oct-01
---
10
ND
12.0
ND
ND
47.0
ND
---
---
13-Jun-02
---
10
ND
14.0
ND
ND
251
ND
---
---
19-Nov-02
---
10
ND
10.0
ND
ND
57.0
ND
---
---
27-Jun-03
---
10
ND
15.0
ND
ND
75.0
ND
---
---
30-Dec-03
---
10
ND
17.0
ND
ND
52.0
ND
---
ND
30-Jun-04
---
10
ND
16.0
ND
ND
31.0
ND
---
ND
29-Dec-04
---
10
ND
11.0
ND
ND
46.0
ND
---
ND
29-Jun-05
---
10
ND
11.0
ND
ND
43.0
ND
---
ND
29-Dec-05
---
10
ND
12.0
ND
ND
30.0
ND
---
ND
28-Jun-06
---
10
ND
ND
ND
ND
72.5
ND
---
ND
29-Dec-06
---
10
ND
11.4
ND
ND
37.5
ND
---
ND
12-Jul-07
---
10
ND
11.8
ND
2.7
58.4
ND
---
ND
IMAC = 70 pg/L (10/23/07)
19-Dec-07
---
10
2.5 B
ND
ND
2.0 B
103
2.6 B
8.0 B
1.8 J
8-Jul-08
---
10
10.3 B
12.1 B
2.0 B
9.0 B
130
4.8 B
---
6.2 J
17-Dec-08
0.60
10.0
2.1 B
11.8 B
2.3 B
3.6 B
43.7
1.6 B
---
2.5 J
9-Jul-09
0.60
10.0
ND
6.2 J
ND
ND
100
ND
2.2 J
ND
16-Dec-09
0.60
10.0
ND
4.7 J
ND
ND
6.6 J
ND
---
ND
24-Jun-10
0.60
10.0
ND
16.3
ND
ND
25.0
ND
---
ND
IMAC = 1 pg/L (2/05/10)
13-Dec-10
0.60
10.0
2.5 B
15.5
ND
ND
[129)
(ND)
---
1.6 (1.0 J) J
20-Jun-11
5.0
10.0
ND
14.2
ND
ND
81.8
ND
---
ND
5-Dec-11
5.0
10.0
ND
12.7
ND
ND
146
ND
---
ND
Resample >
25-Jan-12
5.0
10.0
---
---
---
---
47.5
---
---
ND
11-Jun-12
5.0
10.0
ND
14.2
ND
ND
101
ND
ND
ND
12-Dec-12
5.0
10.0
ND
11.3
ND
ND
113
ND
---
ND
1-May-13
5.0
10.0
ND
24.3
ND
ND
34.0
ND
ND
ND
5-Aug-13
5.0
10.0
ND
24.7
ND
ND
50.9
ND
---
ND
24-Feb-14
5.0
10.0
ND
18.4
ND
ND
9.6 J
ND
ND
ND
12-Aug-14
5.0
10.0
ND
9.4 J
ND
ND
46.3
ND
---
ND
10-Mar-15
2.5
10.0
ND
8.7 J
ND
ND
39.2
ND
---
ND
18-Aug-15
2.5
10.0
ND
9.3 J
ND
ND
116
ND
---
ND
16-Feb-16
2.5
10.0
ND
10.0
ND
ND
13.1
ND
---
ND
9-Aug-16
2.5
10.0
ND
10.0 J
ND
ND
144
ND
---
ND
13-Feb-17
2.5
10.0
ND
8.3 J
ND
ND
78.7
ND
---
ND
22-Aug-17
2.5
10.0
ND
7.4 J
ND
ND
51.1
ND
---
ND
5-Feb-18
2.5
10.0
ND
8.3 J
ND
ND
172
ND
---
ND
13-Aug-18
2.5
10.0
ND
10.7
ND
ND
97.7
ND
---
ND
4-Feb-19
2.5
5.0
ND
9.9
ND
ND
24.0
ND
---
ND
7-Aug-19
1.1
5.0
ND
11.3
ND
ND
127
ND
ND
ND
12-Feb-20
1.1
5.0
ND
7.5
ND
ND
11.4
ND
1.1 J
ND
27-Aug-20
3.6
5.0
ND
9.7
ND
ND
88.7
ND
ND
ND
Copper
8-Sep-94
---
200
ND
ND
ND
ND
ND
660
---
---
1-Dec-94
---
200
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
200
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
200
ND
ND
ND
ND
ND
ND
---
---
15-Nov-95
---
200
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
200
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
200
ND
ND
32.0
13.0
100
ND
---
---
17-Jun-97
---
200
34.0
350
13.0
37.0
28.0
77.0
---
---
1-Dec-97
---
200
19.0
72.0
14.0
88.0
15.0
34.0
---
---
20-May-98
---
200
12.0
48.0
380
41.0
53.0
28.0
---
---
19-Nov-98
---
200
10.0
ND
410
28.0
53.0
14.0
---
---
21-Jul-99
---
200
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
200
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
200
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
200
N D
N D
N D
N D
N D
N D
---
---
18-Apr-01
---
200
ND
ND
ND
ND
ND
ND
---
---
27-Oct-01
---
200
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
200
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
200
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
200
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
200
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
200
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
200
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
200
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
200
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
200
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
10
ND
ND
11.3
5.50 J
10.4
1.90 B
---
0.60 J
12-Jul-07
---
10
ND
ND
13.4
7.90
2.6 J
ND
---
ND
NC 2L = 1,000 pg/L (10/23/07)
19-Dec-07
---
10
2.0 B
ND
8.6 B
3.8 B
7.0 B
0.73 B
5.8 B
9.8
8-J u I-08
---
10
0.64 J
N D
12.1
3.7 J
8.5 J
N D
---
N D
17-Dec-08
0.30
10.0
0.80 J
13.6
10.2
3.9 J
11.9
0.37 J
---
ND
9-Jul-09
0.30
10.0
ND
ND
6.3 J
ND
5.7 J
ND
8.8 J
ND
16-Dec-09
0.30
10.0
ND
ND
9.2 J
1.6 J
5.7 J
ND
---
ND
24-Jun-10
0.30
10.0
ND
ND
10
1.2 J
5.1 J
ND
---
ND
13-Dec-10
0.30
10.0
1.1 B
ND
13.6
5.8 J
5.6 J
0.59 B
---
0.49 J
20-Jun-11
5.0
10.0
ND
ND
15.3
8.1 J
8.7 J
ND
---
ND
5-Dec-11
5.0
10.0
ND
ND
16.9
10.0 J
7.6 J
ND
---
ND
11-Jun-12
5.0
10.0
ND
10.7
12.2
6.3 J
7.4 J
ND
ND
ND
12-Dec-12
5.0
10.0
ND
ND
11.6
8.5 J
10.4
ND
---
ND
1-May-13
5.0
10.0
ND
ND
13.6
5.8 J
9.6 J
ND
ND
ND
5-Aug-13
5.0
10.0
ND
ND
14.3
ND
10.2
ND
---
ND
24-Feb-14
5.0
10.0
ND
ND
12.2
ND
5.1 J
ND
ND
ND
12-Aug-14
5.0
10.0
ND
ND
10.5
ND
ND
ND
---
ND
10-Mar-15
2.5
10.0
ND
ND
8.7 J
ND
15.5
ND
---
ND
18-Aug-15
2.5
10.0
ND
ND
6.7 J
5.6 J
10.1
ND
---
ND
NC 2L = 50 pg/L (06/01/2016)
16-Feb-16
2.5
10.0
ND
ND
7.8 J
ND
5.1 J
ND
---
ND
9-Aug-16
2.5
10.0
ND
ND
5.4 J
ND
7.8 J
ND
---
ND
13-Feb-17
2.5
10.0
ND
ND
6.8 J
4.3 J
14.5
9.4 J
---
ND
22-Aug-17
2.5
10.0
ND
ND
6.5 J
ND
5.7 J
4.4 J
---
ND
5-Feb-18
2.5
10.0
ND
6.5 J
9.0 J
5.5 J
12.4
2.6 J
---
ND
13-Aug-18
2.5
10.0
ND
5.5 J
12.2
3.7 J
48.8
ND
---
ND
4-Feb-19
2.5
5.0
ND
3.0 J
5.4
8.0
4.3 J
ND
---
ND
7-Aug-19
2.1
5.0
ND
3.5 J
6.0
7.2
4.4 J
2.3 J
---
ND
12-Feb-20
2.1
5.0
ND
ND
9.8
12.7
3.3 J
ND
---
ND
27-Aug-20
4.3
5.0
ND
ND
5.3
13.5
5.6
ND
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 4 of 20

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Lead
8-Sep-94
---
10
ND
13.0
ND
ND
30.0
36.0
---
---
1-Dec-94
---
10
11.0
N D
N D
N D
36.0
N D
---
---
9-Feb-95
---
10
ND
ND
ND
10.0
37.0
ND
---
---
2-Mar-95
---
10
ND
ND
ND
ND
44.0
ND
---
---
15-Nov-95
---
10
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
10
ND
ND
ND
ND
42.0
ND
---
---
22-Nov-96
---
10
ND
ND
ND
ND
13.0
ND
---
---
17-Jun-97
---
10
20.0
29.0
ND
ND
13.0
ND
---
---
1-Dec-97
---
10
8.0
14.0
ND
5.0
14.0
ND
---
---
20-May-98
---
10
ND
6.0
ND
6.0
21.0
ND
---
---
19-Nov-98
---
10
5.0
ND
ND
ND
58.0
ND
---
---
21-Jul-99
---
10
ND
12.0
14.0
ND
ND
ND
---
---
16-Nov-99
---
10
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
10
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
10
N D
N D
N D
N D
N D
N D
---
---
18-Apr-01
---
10
ND
ND
ND
N D
N D
N D
---
---
27-Oct-01
---
10
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
10
11.0
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
10
ND
ND
ND
ND
12.0
ND
---
---
27-Jun-03
---
10
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
10
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
10
ND
ND
ND
ND
ND
2.1 J
---
ND
12-Jul-07
---
10
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 15 pg/L (10/23/07)
19-Dec-07
---
10
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
---
10
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
4.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
4.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
4.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
4.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
4.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
18-Aug-15
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
2.5
10.0
ND
5.1 J
ND
ND
ND
ND
---
ND
13-Feb-17
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
2.5
10.0
ND
2.8 J
ND
ND
ND
ND
---
ND
5-Feb-18
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
2.5
10.0
ND
ND
ND
ND
4.6 J
ND
---
ND
4-Feb-19
2.5
5.0
ND
ND
ND
ND
ND
ND
---
ND
7-Aug-19
1.6
5.0
ND
2.0 J
ND
ND
ND
ND
---
ND
12-Feb-20
1.6
5.0
1.9 J
2.1 J
2.1 J
2.8 J
3.1 J
2.3 J
---
ND
27-Aug-20
4.5
5.0
ND
ND
ND
ND
ND
ND
---
ND
Mercury
1-Dec-97
---
0.5
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
0.5
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
0.5
ND
0.59
0.65
0.65
0.76
ND
---
---
10-May-00
---
0.5
---
N D
ND
ND
N D
---
---
---
26-Oct-00
---
0.5
---
N D
N D
N D
N D
---
---
---
18-Apr-01
---
0.5
---
N D
ND
N D
N D
---
---
---
13-J u n-02
---
0.5
---
ND
ND
N D
N D
---
---
---
27-J u n-03
---
0.5
---
ND
ND
N D
N D
---
---
---
30-Dec-03
---
0.5
---
---
---
---
--
30-Jun-04
---
0.5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
---
---
--
---
---
---
---
---
---
29-Jun-05
---
0.5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
---
---
--
---
---
---
---
---
---
28-Jun-06
---
2.0
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
---
---
--
---
---
---
---
---
---
12-Jul-07
---
0.2
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 1.05 pg/L (10/23/07)
19-Dec-07
---
---
---
---
---
---
---
---
ND
---
8-Jul-08
---
0.2
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
---
---
---
--
---
---
---
---
---
---
9-Jul-09
0.070
0.2
ND
ND
ND
ND
ND
ND
---
ND
16-Dec-09
---
---
---
--
---
---
---
---
---
---
NC 2L = 1 pg/L (02/05/10)
24-Jun-10
0.070
0.20
ND
ND
ND
ND
ND
0.098 J
---
ND
13-Dec-10
---
---
---
--
---
---
---
---
---
---
20-Jun-11
0.10
0.20
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
---
---
--
---
---
---
---
---
---
---
11-Jun-12
0.10
0.20
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
---
---
---
--
---
---
---
---
---
---
1-May-13
0.10
0.20
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
--
---
---
---
---
---
---
24-Feb-14
0.10
0.20
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
---
---
---
--
---
---
---
---
---
---
10-Mar-15
0.10
0.20
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.10
0.20
ND
ND
ND
---
---
---
---
ND
13-Feb-17
0.10
0.20
ND
ND
ND
---
---
---
---
ND
22-Aug-17
0.10
0.20
ND
ND
ND
---
---
---
---
ND
5-Feb-18
0.10
0.20
ND
ND
ND
---
---
---
---
ND
4-Feb-19
0.10
0.20
ND
ND
ND
---
---
---
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 5 of 20

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Nickel
8-Sep-94
---
50
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
50
N D
N D
N D
N D
N D
N D
---
---
9-Feb-95
---
50
ND
72
ND
ND
ND
ND
---
---
2-Mar-95
---
50
ND
100
ND
ND
ND
ND
---
---
15-Nov-95
---
50
ND
61.0
ND
ND
ND
ND
---
---
28-May-96
---
50
ND
85.0
ND
ND
ND
ND
---
---
22-Nov-96
---
50
ND
72.0
ND
ND
ND
ND
---
---
17-Jun-97
---
50
75
98.0
ND
ND
ND
ND
---
---
1-Dec-97
---
50
ND
89.0
ND
ND
ND
ND
---
---
20-May-98
---
50
ND
91.0
ND
ND
ND
ND
---
---
19-Nov-98
---
50
ND
83.0
ND
ND
ND
ND
---
---
21-Jul-99
---
50
ND
109
ND
ND
ND
ND
---
---
16-Nov-99
---
50
ND
122
ND
ND
ND
ND
---
---
10-May-00
---
50
ND
104
ND
ND
ND
ND
---
---
26-Oct-00
---
50
ND
93.0
ND
ND
ND
ND
---
---
18-Apr-01
---
50
ND
107
ND
ND
ND
ND
---
---
27-Oct-01
---
50
ND
92.0
ND
ND
ND
ND
---
---
13-Jun-02
---
50
ND
98.0
ND
ND
ND
ND
---
---
19-Nov-02
---
50
ND
74.0
ND
ND
ND
ND
---
---
27-Jun-03
---
50
ND
85.0
ND
ND
ND
ND
---
---
30-Dec-03
---
50
ND
100
ND
ND
ND
ND
---
ND
30-Jun-04
---
50
ND
120(81.0)
ND
ND
ND
ND
---
ND
29-Dec-04
---
50
ND
100
ND
ND
ND
ND
---
ND
29-Jun-05
---
50
ND
150
ND
ND
ND
ND
---
ND
29-Dec-05
---
50
ND
96.0
ND
ND
ND
ND
---
ND
28-Jun-06
---
50
ND
88.7
ND
ND
ND
ND
---
ND
29-Dec-06
---
50
N D
94.7
30.1
14.2
8.9 J
N D
---
N D
12-Jul-07
---
50
ND
99.0
30.6 J
13.9 J
13.7 J
ND
---
ND
NC 2L = 100 pg/L (10/23/07)
19-Dec-07
---
50
ND
83.4
23.7
11.0
18.3
ND
11.4
ND
8-Jul-08
---
50
ND
76.0
28.1 J
11.5 J
27.0 J
ND
---
ND
17-Dec-08
1.7
50.0
ND
75.5
27.8 J
12.2 J
11.0 B
ND
---
2.4 J
9-Jul-09
1.7
50.0
2.2 J
93.5
29.4 J
11.7 J
23.2 J
ND
13.1 J
ND
16-Dec-09
1.7
50.0
ND
81.2
28.2 J
11.8 B
2.6 B
ND
---
3.0 J
24-Jun-10
1.7
50.0
ND
76.3
19.7 J
9.0 J
7.0 J
4.5 J
---
ND
13-Dec-10
1.7
50.0
ND
83.0
23.5 J
6.8 B
20.7 J
ND
---
2.7 J
20-Jun-11
5.0
50.0
ND
78.8
30.1 J
11.2 J
15.3 J
ND
---
ND
5-Dec-11
5.0
50.0
ND
89.1
32.8 J
11.7 J
24.3 J
ND
---
ND
11-Jun-12
5.0
50.0
ND
91.8
28.9 J
10.0 J
17.3 J
ND
ND
ND
12-Dec-12
5.0
50.0
ND
91.8
29.2 J
9.3 J
21.1 J
ND
---
ND
1-May-13
5.0
50.0
ND
89.6
31.9 J
10.4 J
5.7 J
ND
ND
ND
5-Aug-13
5.0
50.0
ND
87.9
28.1 J
9.0 J
8.4 J
ND
---
ND
24-Feb-14
5.0
50.0
ND
83.1
16.7 J
10.4 J
ND
ND
ND
ND
12-Aug-14
5.0
50.0
ND
97.9
29 J
12.9 J
13.2 J
ND
---
ND
10-Mar-15
2.5
50.0
ND
91.9
32.9 J
12.3 J
8.2 J
ND
---
ND
18-Aug-15
2.5
50.0
ND
98.0
28.0 J
11.9 J
26.2 J
5.4 J
---
ND
16-Feb-16
2.5
50.0
ND
92.0
35.4 J
12.7 J
3.7 J
ND
---
ND
9-Aug-16
2.5
50.0
3.3 J
88.9
29.0 J
12.2 J
30.7 J
N D
---
N D
13-Feb-17
2.5
50.0
ND
89.6
30.4 J
13.5 J
16.2 J
ND
---
ND
22-Aug-17
2.5
50.0
ND
84.2
28.2 J
12.3 J
13.5 J
ND
---
ND
5-Feb-18
2.5
50.0
ND
87.6
29.8 J
11.7 J
28.5 J
ND
---
ND
13-Aug-18
2.5
50.0
ND
88.9
29.0 J
12.3 J
21.9 J
ND
---
ND
4-Feb-19
2.5
5.0
ND
85.7
17.4
10.7
5.5
ND
---
ND
7-Aug-19
0.90
5.0
ND
92.6
27.8
11.7
18.7
ND
---
ND
12-Feb-20
0.90
5.0
1.1 J
89.9
20.5
13.2
3.4 J
N D
---
N D
27-Aug-20
3.50
5.0
ND
99.1
19.5
12.2
18.1
ND
---
ND
Selenium
8-Sep-94
---
20
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
20
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
20
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
20
ND
ND
ND
ND
ND
ND
---
---
15-Nov-95
---
20
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
20
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
20
ND
ND
ND
ND
ND
ND
---
---
17-Jun-97
---
20
ND
ND
ND
ND
ND
ND
---
---
1-Dec-97
---
20
ND
ND
ND
ND
ND
ND
---
---
20-May-98
---
20
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
20
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
20
ND
ND
ND
ND
36.0
ND
---
---
16-Nov-99
---
20
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
20
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
20
N D
N D
N D
N D
N D
N D
---
---
18-Apr-01
---
20
ND
ND
ND
ND
ND
ND
---
---
27-Oct-01
---
20
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
20
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
20
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
20
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
20
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
20
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
20
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
20
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
20
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
20
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
10
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 50 pg/L (10/23/07)
19-Dec-07
---
10
ND
11.5
ND
ND
ND
ND
ND
ND
8-Jul-08
---
10
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
3.8
10
4.8 B
5.1 B
4.8 B
ND
ND
ND
---
4.9 J
9-Jul-09
3.8
10
ND
ND
4.2 J
ND
ND
ND
ND
ND
16-Dec-09
3.8
10
ND
ND
ND
5.1 J
ND
ND
---
ND
NC 2L = 20 pg/L (02/05/10)
24-Jun-10
3.8
10
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
3.8
10
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
10.0
10
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
10.0
10
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
10.0
10
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
10.0
10
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
10.0
10
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
10.0
10
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
10.0
10
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
10.0
10
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
18-Aug-15
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
7-Aug-19
4.7
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
4.7
10.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
4.7
10.0
ND
ND
ND
ND
ND
ND
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 6 of 20

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Silver
8-Sep-94
---
10
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
10
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
10
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
10
ND
ND
ND
ND
ND
ND
---
---
15-Nov-95
---
10
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
10
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
10
ND
ND
ND
ND
ND
ND
---
---
17-Jun-97
---
10
ND
ND
ND
ND
ND
ND
---
---
1-Dec-97
---
10
ND
8.0
ND
ND
ND
3.0
---
---
20-May-98
---
10
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
10
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
10
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
10
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
10
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
10
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
10
ND
15.0
ND
ND
ND
N D
---
---
27-Oct-01
---
10
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
10
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
10
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
10
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
10
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
10
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 17.5 pg/L (10/23/07)
19-Dec-07
---
10
ND
0.57 J
0.60 J
0.55 J
ND
0.33 J
ND
ND
8-Jul-08
---
10
ND
2.7 J
2.3 J
1.1 J
0.22 J
0.69 J
---
0.12 J
17-Dec-08
0.10
10.0
0.13 J
1.8 J
1.4 J
0.85 J
0.12 J
0.51 J
---
ND
9-Jul-09
0.10
10.0
ND
0.84 J
0.63 J
0.45 J
ND
0.11 J
ND
ND
16-Dec-09
0.10
10.0
0.12 J
2.0 J
1.6 J
1.0 J
0.12 J
0.52 J
---
ND
NC 2L = 20 pg/L (02/05/10)
24-Jun-10
0.10
10.0
ND
0.38 J
0.33 J
0.35 J
ND
ND
---
ND
13-Dec-10
0.10
10.0
0.15 B
1.3 J
0.99 J
0.45 B
{ND)
(ND)
---
0.21 {0.19 J J
20-Jun-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
18-Aug-15
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
2.5
5.0
ND
ND
ND
ND
ND
ND
---
ND
7-Aug-19
2.5
5.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
2.5
5.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
2.5
5.0
ND
ND
ND
ND
ND
ND
---
ND
Thallium
8-Sep-94
---
10
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
10
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
10
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
10
ND
ND
ND
ND
ND
ND
---
---
15-Nov-95
---
10
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
10
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
10
ND
ND
ND
ND
ND
ND
---
---
17-Jun-97
---
10
ND
3.0
ND
ND
ND
ND
---
---
1-Dec-97
---
10
ND
ND
ND
ND
ND
ND
---
---
20-May-98
---
10
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
10
ND
ND
ND
ND
ND
ND
---
---
21-J u l-99
---
10
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
10
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
10
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
10
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
10
ND
ND
ND
N D
ND
ND
---
---
27-Oct-01
---
10
ND
ND
ND
N D
ND
ND
---
---
13-Jun-02
---
10
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
10
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
10
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
10
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
10
ND
10.0 J
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
22.0
13.0
ND
ND
ND
---
ND
29-Dec-05
---
10
ND
23.0
20.0
ND
ND
ND
---
ND
28-Jun-06
---
10
ND
25.7
12.6
ND
ND
ND
---
ND
29-Dec-06
---
6
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
5.5
ND
ND
ND
ND
ND
ND
---
ND
IMAC = 0.28 pg/L (10/23/07)
19-Dec-07
---
5.5
ND
4.0 J
ND
ND
ND
ND
ND
ND
8-Jul-08
---
5.5
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
3.0
5.5
ND
3.2 J
3.2 J
ND
ND
ND
---
ND
9-Jul-09
3.0
5.5
ND
ND
ND
4.1 J
ND
ND
ND
ND
16-Dec-09
3.0
5.5
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
3.0
5.5
ND
ND
5.2 J
3.1 J
ND
ND
---
ND
IMAC = 0.2 pg/L (10/1/10)
13-Dec-10
3.0
5.5
ND
ND
7.7
ND
ND
ND
---
ND
20-Jun-11
5.4
5.5
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
5.4
5.5
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
5.4
5.5
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
5.4
5.5
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
5.4
5.5
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.4
5.5
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
5.4
5.5
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
5.4
5.5
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
5.0
5.5
ND
ND
ND
ND
ND
ND
---
ND
18-Aug-15
5.0
5.5
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
5.0
5.5
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
5.0
5.5
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.02
5.5
0.023 J
0.040 J
ND
ND
0.035 J
ND
---
ND
22-Aug-17
0.02
5.5
ND
ND
ND
ND
0.033 J
ND
---
ND
5-Feb-18
0.03
0.1
ND
ND
ND
ND
0.047 J
ND
---
ND
13-Aug-18
0.02
5.5
ND
ND
ND
ND
0.037 J
ND
---
ND
4-Feb-19
0.06
0.1
ND
ND
ND
ND
ND
ND
---
ND
7-Aug-19
0.060
0.10
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
0.060
0.10
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
0.050
0.10
ND
ND
ND
ND
ND
ND
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 7 of 20

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Tin
1-Dec-97
---
100
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
100
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
100
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
100
---
ND
ND
ND
ND
---
---
---
18-Apr-01
---
100
---
N D
ND
N D
ND
---
---
---
27-Oct-01
---
100
---
---
---
---
---
---
---
---
13-Jun-02
---
100
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
100
---
---
---
---
---
---
---
---
27-Jun-03
---
100
ND
149
127
ND
ND
ND
---
---
30-Dec-03
---
100
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
100
ND
41.1
14.4
3.2 J
ND
ND
---
ND
12-Jul-07
---
100
ND
35.2 J
13.9 J
5.2 J
ND
ND
---
ND
19-Dec-07
---
100
ND
33.6
7.4
ND
ND
ND
ND
ND
8-Jul-08
---
100
4.4 J
28.6 J
15.1 J
5.4 J
3.0 J
3.6 J
---
ND
17-Dec-08
1.8
100
ND
22.5 J
9.2 J
ND
ND
ND
---
ND
9-Jul-09
1.8
100
ND
21.4 J
8.6 J
ND
ND
ND
---
ND
16-Dec-09
1.8
100
ND
26.3 J
10.7 J
ND
ND
ND
---
ND
IMAC = 2100 pg/L (02/05/10)
24-Jun-10
1.8
100
ND
23.4 J
10.7 J
3.2 J
2.2 J
1.9 J
---
ND
13-Dec-10
1.8
100
ND
30.3 J
12.1 J
5.8 J
ND
ND
---
ND
20-Jun-11
5.0
100
ND
26.8 J
13.8 J
ND
ND
ND
---
ND
5-Dec-11
5.0
100
ND
25.8 J
13.9 J
ND
ND
ND
---
ND
11-Jun-12
5.0
100
ND
22.2 J
9.0 J
ND
ND
ND
ND
ND
12-Dec-12
5.0
100
ND
30.0 J
13.2 J
ND
ND
ND
---
ND
1-May-13
5.0
100
ND
25.8 J
12.2 J
ND
ND
ND
---
ND
5-Aug-13
5.0
100
ND
22.7 J
12.5 J
ND
ND
ND
---
ND
24-Feb-14
5.0
100
ND
26.7 J
11.7 J
9.8 J
ND
ND
ND
ND
12-Aug-14
5.0
100
ND
30.7 J
8.2 J
ND
ND
ND
---
ND
10-Mar-15
2.5
100
ND
28.7 J
11.1 J
ND
ND
ND
---
ND
18-Aug-15
2.5
100
ND
27.7 J
7.5 J
ND
ND
ND
---
ND
16-Feb-16
2.5
100
ND
28.6 J
10.4 J
---
---
---
---
ND
9-Aug-16
2.5
100
ND
20.9 J
5.4 J
---
---
---
---
ND
13-Feb-17
2.5
100
ND
25.5 B
7.8 B
---
---
---
---
3.6 J,
22-Aug-17
2.5
100
ND
17.2 J
5.3 J
---
---
---
---
ND
5-Feb-18
2.5
100
ND
20.3 J
9.5 J
---
---
---
---
ND
13-Aug-18
2.5
100
ND
22.2 J
7.4 J
---
---
ND
---
ND
4-Feb-19
2.5
5.0
ND
24.8
5.5
---
---
---
---
ND
7-Aug-19
1.6
5.0
ND
29.3
9.7
---
---
---
---
ND
12-Feb-20
1.6
5.0
ND
26.0
5.8
---
---
---
---
ND
27-Aug-20
4.7
5.0
ND
27.6
5.1
---
---
---
---
ND
Vanadium
8-Sep-94
---
40
ND
ND
ND
ND
ND
130
---
---
1-Dec-94
---
40
63.0
ND
ND
45.0
ND
ND
---
---
9-Feb-95
---
40
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
40
41.0
ND
ND
45.0
ND
ND
---
---
15-Nov-95
---
40
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
40
83.0
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
40
7.0
17
ND
21.0
ND
ND
---
---
17-Jun-97
---
40
450
560
ND
19.0
ND
ND
---
---
1-Dec-97
---
40
62.0
88.0
ND
41.0
ND
10.0
---
---
20-May-98
---
40
25.0
15.0
ND
10.0
5.0
ND
---
---
19-Nov-98
---
40
33.0
29.0
5.0
16.0
9.0
5.0
---
---
21-Jul-99
---
40
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
40
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
40
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
40
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
40
ND
ND
ND
ND
ND
ND
---
---
27-Oct-01
---
40
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
40
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
40
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
40
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
40
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
40
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
40
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
40
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
40
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
40
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
25
2.7 J
ND
ND
14.5
ND
1.0 J
---
ND
12-Jul-07
---
25
ND
ND
ND
19.4 J
ND
ND
---
ND
IMAC = 3.5 pg/L (10/23/07)
19-Dec-07
---
25
2.2 B
2.2 B
ND
15.7 J
3.0 B
1.2 B
4.0 J
0.62 J
8-Jul-08
---
25
2.6 J
2.4 J
ND
14.6 J
1.4 J
1.2 J
---
0.20 J
17-Dec-08
0.20
25.0
1.9 B
2.3 B
ND
13.9 J
2.5 B
1.2 B
---
0.76 J
9-Jul-09
0.20
25.0
3.9 B
9.7 J
2.5 B
18.4 J
2.9 B
2.2 B
8.5 J
1.30 J
16-Dec-09
0.20
25.0
2.0 B
4.4 J
1.3 B
14.0 J
2.2 B
1.5 B
---
0.53 J
24-Jun-10
0.20
25.0
1.8 J
4.4 J
1.5 J
13.3 J
2.2 J
1.3 J
---
ND
IMAC = 0.3 pg/L (10/1/10)
13-Dec-10
0.20
25.0
3.2 J
3.6 J
0.35 B
16.6 J
1.8 B
1.0 B
---
0.36 J
20-Jun-11
5.0
25.0
ND
ND
ND
14.5 J
ND
ND
---
ND
5-Dec-11
5.0
25.0
ND
ND
ND
13.5 J
ND
ND
---
ND
11-Jun-12
5.0
25.0
ND
18.0 J
ND
12.3 J
ND
ND
ND
ND
12-Dec-12
5.0
25.0
ND
ND
ND
13.6 J
ND
ND
---
ND
1-May-13
5.0
25.0
ND
ND
ND
6.3 J
ND
ND
ND
ND
5-Aug-13
5.0
25.0
ND
ND
ND
10.2 J
ND
ND
---
ND
24-Feb-14
5.0
25.0
ND
ND
ND
12.9 J
ND
ND
ND
ND
12-Aug-14
5.0
25.0
ND
ND
ND
18.6 J
ND
ND
---
ND
10-Mar-15
2.5
25.0
3.1 J
11.6 J
6.2 J
13.4 J
ND
ND
---
ND
18-Aug-15
2.5
25.0
3.4 J
6.8 J
3.6 J
19.6 J
2.8 J
ND
---
ND
16-Feb-16
2.5
25.0
2.7 J
3.3 J
ND
14.4 J
ND
ND
---
ND
9-Aug-16
2.5
25.0
2.5 J
3.5 J
ND
21.2 J
ND
ND
---
ND
13-Feb-17
2.5
25.0
4.4 J
4.1 J
ND
18.4 J
3.0 J
2.9 J
---
ND
22-Aug-17
2.5
25.0
ND
6.6 J
ND
20.6 J
2.6 J
ND
---
ND
5-Feb-18
2.5
25.0
3.6 J
4.4 J
ND
17.6 J
ND
2.5 J
---
ND
13-Aug-18
2.5
25.0
ND
5.3 J
ND
20.4 J
2.9 J
ND
---
ND
4-Feb-19
2.5
5.0
ND
3.5 J
ND
12.0
ND
ND
---
ND
7-Aug-19
1.3
5.0
2.6 J
4.1 J
1.9 J
22.1
1.7 J
2.4 J
---
ND
12-Feb-20
1.3
5.0
ND
ND
ND
17.0
ND
1.4 J
---
ND
27-Aug-20
3.9
5.0
ND
ND
ND
21.1
ND
ND
6.8
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 8 of 20

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Zinc
8-Sep-94
---
50
110
160
ND
ND
320
430
---
---
1-Dec-94
---
50
132
N D
N D
70
164
ND
---
---
9-Feb-95
---
50
144
89
ND
91
79
74
---
---
2-Mar-95
---
50
67
ND
ND
ND
111
ND
---
---
15-Nov-95
---
50
ND
50
ND
ND
ND
ND
---
---
28-May-96
---
50
136
ND
ND
ND
122
ND
---
---
22-Nov-96
---
50
79.0
48.0
28.0
ND
38.0
ND
---
---
17-Jun-97
---
50
370
410
33.0
39.0
36.0
69.0
---
---
1-Dec-97
---
50
140
110
11.0
45.0
34.0
30.0
---
---
20-May-98
---
50
70.0
63.0
23.0
31.0
47.0
34.0
---
---
19-Nov-98
---
50
61.0
33.0
21.0
17.0
53.0
10.0
---
---
21-Jul-99
---
50
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
50
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
50
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
50
N D
N D
N D
N D
N D
N D
---
---
18-Apr-01
---
50
ND
ND
ND
ND
ND
ND
---
---
27-Oct-01
---
50
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
50
ND
ND
ND
ND
382
ND
---
---
19-Nov-02
---
50
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
50
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
50
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
50
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
50
ND
ND
ND
66.0
ND
ND
---
ND
29-Jun-05
---
50
ND
54.0
56.0
ND
ND
ND
---
ND
29-Dec-05
---
50
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
50
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
50
8.0 J
N D
N D
4.1 J
4.3 J
4.1 J
---
N D
12-Jul-07
---
10
9.6 J
ND
ND
ND
ND
ND
---
ND
NC 2L = 1,050 pg/L (10/23/07)
19-Dec-07
---
10
4.3 B
14.3 B
6.3 B
ND
ND
ND
2.4 B
102
8-Jul-08
---
10
5.9 B
ND
ND
ND
4.1 B
ND
---
1.2 J
17-Dec-08
0.40
10.0
2.4 B
6.3 J
N D
N D
4.6 J
0.60 B
---
0.49 J
9-Jul-09
0.40
10.0
3.4 B
ND
ND
ND
ND
ND
6.1 B
1.6 J
16-Dec-09
0.40
10.0
4.6 B
ND
ND
ND
7.4 B
ND
---
7.7 J
NC 2L = 1,000 pg/L (02/05/10)
24-Jun-10
0.40
10.0
0.58 J
ND
ND
ND
ND
1.3 J
---
ND
13-Dec-10
0.40
10.0
4.5 B
ND
ND
ND
ND
ND
---
6.7 J
20-Jun-11
10.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
10.0
10.0
ND
ND
ND
ND
ND
ND
---
12.4
11-Jun-12
10.0
10.0
ND
20.9
ND
ND
ND
ND
ND
ND
12-Dec-12
10.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
10.0
10.0
ND
ND
ND
ND
11.8
ND
10.0
ND
5-Aug-13
10.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
10.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
10.0
10.0
ND
ND
ND
ND
16.9
ND
---
ND
18-Aug-15
5.0
10.0
7.4 J
ND
ND
ND
5.2 J
ND
---
ND
16-Feb-16
5.0
10.0
14.5
16.7
17.8
46.1
5.9 J
ND
---
ND
9-Aug-16
5.0
10.0
12.0
7.7 J
ND
ND
ND
ND
---
ND
13-Feb-17
5.0
10.0
12.3
ND
ND
ND
9.8 J
6.0 J
---
ND
22-Aug-17
5.0
10.0
ND
6.3 J
ND
ND
ND
ND
---
ND
5-Feb-18
5.0
10.0
6.7 J
17.9
ND
ND
ND
ND
---
ND
13-Aug-18
5.0
10.0
ND
ND
ND
ND
8.1 J
ND
---
ND
4-Feb-19
5.0
10.0
6.8 J
ND
5.0 J
ND
ND
ND
---
ND
7-Aug-19
3.9
10.0
8.3 J
ND
ND
ND
ND
ND
---
ND
12-Feb-20
3.9
10.0
4.3 J
ND
ND
ND
4.5 J
ND
---
ND
27-Aug-20
9.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
Cyanide
9-Jul-09
5.0
10
ND
ND
ND
ND
46.9
ND
ND
ND
Resample >
28-Sep-09
5.0
10
---
---
---
---
ND
---
---
ND
NC 2L = 70 pg/L (10/23/07)
16-Dec-09
---
---
---
---
---
---
---
---
---
---
24-Jun-10
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
---
---
---
--
---
---
---
---
---
---
Resample >
20-Jun-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
---
---
--
---
---
---
---
---
---
---
11-Jun-12
5.0
10.0
ND
6.4 J
ND
ND
8.7 J
ND
---
ND
12-Dec-12
---
---
---
--
---
---
---
---
---
---
1-May-13
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
--
---
---
---
---
---
---
---
24-Feb-14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
5.5 J
12-Aug-14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
5.0
10.0
9.5 B
7.5 B
8.5 B
8.8 B
11.8 B
6.6 B
---
5.6 J
16-Feb-16
4.0
10.0
N D
N D
N D
---
---
---
---
ND
13-Feb-17
4.0
10.0
N D
N D
N D
---
---
---
---
N D
22-Aug-17
4.0
10.0
ND
ND
ND
---
---
---
---
ND
5-Feb-18
4.0
10.0
N D
N D
N D
---
---
---
---
N D
4-Feb-19
6.0
8.0
ND
ND
ND
---
---
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 9 of 20

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
ORGANICS
Acetone
27-Oct-01
---
100
244 B
109 B
ND
130 B
128 B
476 B
---
479
13-Jun-02
---
100
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
100
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
100
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
100
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
100
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
100
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
100
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 700 pg/L (10/23/07)
19-Dec-07
---
100
ND
ND
ND
ND
ND
ND
ND
4.5 J
8-Jul-08
---
100
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
20.0
100
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
20.0
100
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
2.2
100
ND
ND
ND
ND
ND
ND
---
2.8 J
NC 2L = 6,000 pg/L (02/05/10)
24-Jun-10
2.2
100
ND
18.5 B
6.5 B
ND
2.2 B
ND
---
7.7 J
13-Dec-10
2.2
100
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
2.2
100
ND
ND
ND
ND
ND
2.4 B
---
3.9 J
5-Dec-11
2.2
100
ND
2.3 B
ND
ND
ND
ND
---
8.8 J
11-Jun-12
2.2
100
ND
3.5 B
ND
ND
ND
ND
ND
4.7 J
12-Dec-12
10.0
100
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
10.0
100
ND
ND
ND
ND
ND
ND
ND
14.6 J
5-Aug-13
10.0
100
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
10.0
100
ND
ND
ND
ND
ND
ND
ND
25.7 J
12-Aug-14
10.0
100
ND
ND
ND
ND
ND
ND
ND
22.0 J
10-Mar-15
10.0
100
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
10.0
100
ND
ND
ND
ND
ND
ND
ND
ND
16-Feb-16
10.0
100
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
10.0
100
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
10.0
100
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
10.0
100
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
10.0
100
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
10.0
100
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
6.2
25
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
6.2
25.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
6.2
25.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
6.2
25.0
ND
ND
ND
ND
ND
ND
---
ND
Benzene
8-Sep-94
---
5
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
5
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
5
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
5
ND
ND
ND
ND
ND
ND
---
---
15-Nov-95
---
5
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
5
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
5
ND
ND
ND
ND
ND
ND
---
---
17-Jun-97
---
5
ND
ND
ND
ND
ND
ND
---
---
1-Dec-97
---
5
ND
ND
ND
ND
ND
ND
---
---
20-May-98
---
5
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
5
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
5
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
5
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
5
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
5
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
5
N D
N D
N D
N D
N D
N D
---
---
27-Oct-01
---
5
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
5
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
5
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
5
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
5
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
3
ND
1.5
ND
ND
ND
ND
---
ND
Resample >
23-Feb-07
---
3
---
1.2
---
---
---
---
---
ND
12-Jul-07
---
1
ND
1.9
ND
ND
ND
ND
---
ND
NC 2L = 1 pg/L (10/23/07)
19-Dec-07
---
1
ND
1.8
0.48 J
0.26 J
ND
ND
ND
ND
8-Jul-08
---
1
ND
1.4
0.51 J
0.32 J
ND
ND
---
ND
17-Dec-08
0.25
1.0
ND
1.7
0.54 J
ND
ND
ND
---
ND
9-Jul-09
0.25
1.0
ND
1.7
0.34 J
ND
ND
ND
ND
ND
16-Dec-09
0.25
1.0
ND
1.7
0.60 J
0.29 J
ND
ND
---
ND
24-Jun-10
0.25
1.0
ND
0.77 J
0.49 J
0.33 J
ND
ND
---
ND
13-Dec-10
0.25
1.0
ND
1.8
0.59 J
0.37 J
ND
ND
---
ND
Resample >
8-Feb-11
0.25
1.0
---
1.4
---
---
---
---
---
ND
20-Jun-11
0.25
1.0
ND
1.7
0.60 J
0.39 J
ND
ND
---
ND
5-Dec-11
0.25
1.0
ND
1.4
0.69 J
0.40 J
ND
ND
---
ND
11-Jun-12
0.25
1.0
ND
ND
0.51 J
ND
ND
ND
ND
ND
12-Dec-12
0.25
1.0
ND
1.6
0.73 J
0.32 J
ND
ND
---
ND
Resample >
10-Jan-13
0.25
1.0
ND
1.4
---
---
---
---
ND
ND
1-May-13
0.25
1.0
ND
1.3
0.56 J
0.27 J
ND
ND
ND
ND
5-Aug-13
0.25
1.0
ND
1.6
0.64 J
0.44 J
ND
ND
---
ND
24-Feb-14
0.25
1.0
ND
1.4
ND
ND
ND
ND
ND
ND
12-Aug-14
0.25
1.0
ND
1.7
0.61 J
0.25 J
ND
ND
ND
ND
10-Mar-15
0.25
1.0
ND
1.3
0.54 J
ND
ND
ND
ND
ND
18-Aug-15
0.25
1.0
ND
1.5
0.66 J
0.32 J
ND
ND
---
ND
16-Feb-16
0.25
1.0
ND
1.3
0.56 J
ND
ND
ND
ND
ND
9-Aug-16
0.25
1.0
ND
1.4
0.53 J
0.29 J
ND
ND
ND
ND
13-Feb-17
0.25
1.0
ND
1.2
0.61 J
ND
ND
ND
ND
ND
22-Aug-17
0.25
1.0
ND
1.3
0.54 J
ND
ND
ND
ND
ND
5-Feb-18
0.25
1.0
ND
1.2
0.67 J
ND
ND
ND
ND
ND
13-Aug-18
0.25
1.0
ND
1.3
0.61 J
0.29 J
ND
ND
ND
ND
4-Feb-19
0.15
1.0
ND
1.6
ND
ND
ND
ND
ND
ND
14-Aug-19 for MW-6 -->
7-Aug-19
0.15
1.0
N D
1.7
0.54 J
0.30 J
N D
N D
N D
N D
12-Feb-20
0.15
1.0
ND
1.5
ND
ND
ND
ND
ND
ND
27-Aug-20
0.15
1.0
ND
1.9
0.49 J
ND
ND
ND
ND
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 10 of 20

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Bromomethane
17-Dec-08
0.29
10.0
ND
ND
0.58 J
ND
ND
ND
---
ND
9-Jul-09
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
IMAC = 10 pg/L (8/1/10)
13-Dec-10
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
11-Jun-12
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
0.62
2.0
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
0.62
2.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
0.62
2.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
0.62
2.0
ND
ND
ND
ND
ND
ND
---
ND
2-Butanone (MEK)
17-Dec-08
0.96
100
ND
ND
ND
ND
1.2 J
ND
---
ND
NC 2L = 4,200 pg/L (10/23/07)
9-Jul-09
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 4,000 pg/L (02/05/10)
24-Jun-10
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
8-May-13
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
3.30
5
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
3.3
5.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
3.3
5.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
3.3
5.0
ND
ND
ND
ND
ND
ND
---
ND
Carbon Disulfide
17-Jun-97
---
100
ND
64.0
ND
ND
ND
ND
---
---
1-Dec-97
---
100
ND
5.0
8.0
ND
ND
ND
---
---
20-May-98
---
100
ND
7.5
6.2
ND
ND
ND
---
---
19-Nov-98
---
100
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
100
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
100
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
100
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
100
N D
N D
N D
N D
N D
N D
---
---
18-Apr-01
---
100
ND
ND
ND
ND
N D
N D
---
---
27-Oct-01
---
100
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
5
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
100
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
100
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
100
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
100
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
100
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 700 pg/L (10/23/07)
19-Dec-07
---
100
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
---
100
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
0.4
2
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
0.40
2.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
0.40
2.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
0.40
2.0
ND
ND
ND
ND
ND
ND
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 11 of 20

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Chlorobenzene
8-Sep-94
---
5
ND
10.0
7.0
ND
ND
ND
---
---
1-Dec-94
---
5
N D
N D
7.0
N D
N D
N D
---
---
9-Feb-95
---
5
ND
13.0
8.0
6.0
ND
ND
---
---
2-Mar-95
---
5
ND
12.0
9.0
ND
ND
ND
---
---
15-Nov-95
---
5
ND
14.0
8.0
9.0
ND
ND
---
---
28-May-96
---
5
ND
15.0
9.0
10.0
ND
ND
---
---
22-Nov-96
---
5
ND
15.0
ND
11.0
ND
ND
---
---
17-Jun-97
---
5
ND
19.0
11.0
14.0
ND
ND
---
---
1-Dec-97
---
5
ND
17.0
9.0
14.0
ND
ND
---
---
20-May-98
---
5
ND
20.0
8.6
12.0
ND
ND
---
---
19-Nov-98
---
5
ND
17.2
9.2
10.0
ND
ND
---
---
21-Jul-99
---
5
ND
14.0
10.0
11.0
ND
ND
---
---
16-Nov-99
---
5
ND
16.0
10.0
8.0
ND
ND
---
---
10-May-00
---
5
ND
17.0
11.0
10.0
ND
ND
---
---
26-Oct-00
---
5
N D
16.0
12.0
9.0
N D
N D
---
---
18-Apr-01
---
5
N D
16.0
13.0
6.0
N D
N D
---
---
27-Oct-01
---
0.5
ND
17.0
12.0
9.0
ND
ND
---
---
13-Jun-02
---
0.5
ND
16.0
11.0
8.0
ND
ND
---
---
19-Nov-02
---
0.5
ND
18.0
15.0
9.0
ND
ND
---
---
27-Jun-03
---
0.5
ND
17.7
13.3
7.4
ND
ND
---
ND
30-Dec-03
---
5
ND
20.0
15.0
6.1
ND
ND
---
ND
30-Jun-04
---
5
ND
18.0
15.0
9.9
ND
ND
---
ND
29-Dec-04
---
5
ND
19.0
16.0
9.4
ND
ND
---
ND
29-Jun-05
---
5
ND
15.0
13.0
8.0
ND
ND
---
ND
29-Dec-05
---
5
ND
18.0
16.0
5.0
ND
ND
---
ND
28-Jun-06
---
5
ND
16.5
10.8
7.8
ND
ND
---
ND
29-Dec-06
---
3
ND
17.0
17.0
4.2
ND
ND
---
ND
12-Jul-07
---
3
ND
17.0
16.0
ND
ND
ND
---
ND
NC 2L = 50 pg/L (10/23/07)
19-Dec-07
---
3
ND
17.3
16.9
4.7
ND
ND
ND
ND
8-Jul-08
---
3
ND
17.2
17.4
6.5
ND
ND
---
ND
17-Dec-08
0.23
3.0
ND
15.9
15.6
2.6 J
ND
ND
---
ND
9-Jul-09
0.23
3.0
ND
16.1
17.2
6.1
ND
ND
ND
ND
16-Dec-09
0.23
3.0
ND
15.5
17.7
4.8
ND
ND
---
ND
24-Jun-10
0.23
3.0
ND
8.3
15.7
6.3
ND
ND
---
ND
13-Dec-10
0.23
3.0
ND
17.7
18.2
6.4
ND
ND
---
0.28 J
20-Jun-11
0.23
3.0
ND
16.3
17.2
6.7
ND
ND
---
ND
5-Dec-11
0.23
3.0
ND
14.2
17.0
5.8
ND
ND
---
ND
11-Jun-12
0.23
3.0
ND
12.0
14.8
4.4
ND
ND
ND
ND
12-Dec-12
0.23
3.0
ND
15.8
17.9
4.5
ND
ND
---
ND
1-May-13
0.23
3.0
ND
14.0
16.6
3.0 J
ND
ND
ND
ND
5-Aug-13
0.23
3.0
ND
14.4
15.9
4.6
ND
ND
---
ND
24-Feb-14
0.23
3.0
ND
16.3
2.5 J
1.4 J
ND
ND
ND
ND
12-Aug-14
0.23
3.0
ND
15.6
18.3
3.6
ND
ND
ND
ND
10-Mar-15
0.23
3.0
ND
16.0
17.0
2.1 J
ND
ND
ND
ND
18-Aug-15
0.23
3.0
ND
12.8
17.6
4.3
ND
ND
---
ND
16-Feb-16
0.23
3.0
ND
13.5
16.4
1.5 J
ND
ND
ND
ND
9-Aug-16
0.23
3.0
ND
13.5
16.9
4.2
ND
ND
---
ND
13-Feb-17
0.23
3.0
ND
13.6
18.0
1.3 J
ND
ND
---
ND
22-Aug-17
0.23
3.0
ND
14.2
19.9
4.2
ND
ND
---
ND
5-Feb-18
0.23
3.0
ND
13.5
17.3
0.54 J
ND
ND
---
ND
13-Aug-18
0.23
3.0
ND
14.5
22.2
3.4
ND
ND
---
ND
4-Feb-19
0.23
1.0
ND
13.6
0.35 J
1.3
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
0.23
1.0
ND
10.2
16.9
ND
ND
ND
---
ND
12-Feb-20
0.23
1.0
ND
ND
ND
2.0
ND
ND
---
ND
27-Aug-20
0.23
1.0
ND
16.1
17.5
4.1
0.32 J
ND
---
ND
Chloroethane
1-Dec-97
---
10
ND
5.0
2.0
2.0
ND
ND
---
---
20-May-98
---
10
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
10
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
10
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
10
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
10
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
10
N D
N D
N D
N D
N D
N D
---
---
18-Apr-01
---
10
N D
N D
N D
N D
N D
N D
---
---
27-Oct-01
---
10
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
10
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
10
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
10
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
10
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
10
ND
2.2
1.9
ND
ND
ND
---
ND
12-Jul-07
---
10
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 2,800 pg/L (10/23/07)
19-Dec-07
---
10
ND
1.9
1.9
1.5
ND
ND
ND
ND
8-Jul-08
---
10
ND
2.2 J
2.5 J
1.8 J
N D
N D
---
N D
17-Dec-08
0.54
10.0
ND
1.6 J
ND
ND
ND
ND
---
ND
9-Jul-09
0.54
10.0
ND
ND
ND
3.8 J
ND
ND
ND
ND
16-Dec-09
0.54
10.0
ND
ND
2.2 J
2.0 J
ND
ND
---
ND
NC 2L = 3,000 pg/L (02/05/10)
24-Jun-10
0.54
10.0
ND
ND
2.1 J
2.0 J
ND
ND
---
ND
13-Dec-10
0.54
10.0
ND
1.8 J
2.0 J
1.7 J
ND
ND
---
ND
20-Jun-11
0.54
10.0
ND
1.2 J
2.2 J
2.0 J
ND
ND
---
ND
5-Dec-11
0.54
10.0
ND
1.3 J
2.0 J
1.7 J
ND
ND
---
ND
11-Jun-12
0.54
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.54
10.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.54
10.0
ND
ND
1.9 J
2.7 J
ND
ND
ND
ND
5-Aug-13
0.54
10.0
ND
ND
2.0 J
2.2 J
ND
ND
---
ND
24-Feb-14
0.54
10.0
ND
1.1 J
0.82 J
ND
ND
ND
ND
ND
12-Aug-14
0.54
10.0
ND
1.1 J
1.50 J
1.1 J
ND
ND
ND
ND
10-Mar-15
0.54
10.0
ND
1.0 J
1.80 J
0.81 J
ND
ND
ND
ND
18-Aug-15
0.54
10.0
ND
1.2 J
2.0 J
3.7 J
ND
ND
---
ND
16-Feb-16
0.54
10.0
ND
1.1 J
1.8 J
0.79 J
ND
ND
ND
ND
9-Aug-16
0.54
10.0
ND
0.68 J
2.4 J
1.5 J
ND
ND
---
ND
13-Feb-17
0.54
10.0
ND
0.76 J
1.6 J
1.1 J
ND
ND
---
ND
22-Aug-17
0.54
10.0
ND
1.3 J
2.0 J
1.6 J
ND
ND
---
ND
5-Feb-18
0.54
10.0
ND
1.7 J
1.7 J
0.68 J
ND
ND
---
ND
13-Aug-18
0.54
10.0
ND
1.2 J
2.4 J
1.40 J
ND
ND
---
ND
4-Feb-19
0.49
1.0
ND
1.3
ND
0.79 J
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
0.49
1.0
N D
0.94 J
1.9
1.3
N D
N D
---
N D
12-Feb-20
0.49
1.0
ND
1.6
1.3
1.5
ND
ND
---
ND
27-Aug-20
0.49
1.0
ND
0.87 J
1.5
1.1
ND
ND
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 12 of 20

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Chloromethane
9-Jul-09
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
NC 2L = 2.6 pg/L (10/23/07)
16-Dec-09
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
0.11
1.0
ND
ND
ND
ND
ND
0.11 J
---
ND
NC 2L = 3 pg/L (02/05/10)
13-Dec-10
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
0.25 J
12-Aug-14
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.11
1.0
0.20 B
ND
0.22 B
0.23 B
0.19 B
0.32 B
---
0.18 J
22-Aug-17
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
0.39
1.0
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19for Mw-6-->
7-Aug-19
0.39
1.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
0.39
1.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
0.39
1.0
ND
ND
ND
ND
ND
ND
---
ND
1,2-Dichlorobenzene
1-Dec-97
---
5
ND
3.0
2.0
1.0
ND
ND
---
---
20-May-98
---
5
ND
ND
ND
ND
ND
ND
---
19-Nov-98
---
5
ND
2.4
2.3
ND
ND
ND
---
---
21-Jul-99
---
5
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
5
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
5
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
5
N D
N D
N D
ND
N D
ND
---
---
18-Apr-01
---
5
N D
N D
N D
N D
N D
ND
---
---
27-Oct-01
---
5
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
5
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
5
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
5
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
5
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
5
ND
1.5
2.3
ND
ND
ND
---
ND
12-Jul-07
---
5
ND
1.4 J
1.7 J
0.31 J
ND
ND
---
ND
NC 2L = 24 pg/L (10/23/07)
19-Dec-07
---
5
ND
1.6
2.0
0.37 J
ND
ND
ND
ND
8-Jul-08
---
5
ND
1.6 J
2.0 J
0.39 J
ND
ND
---
ND
17-Dec-08
0.30
5.0
ND
1.4 J
1.9 J
ND
ND
ND
---
ND
9-Jul-09
0.30
5.0
ND
1.6 J
2.0 J
0.36 J
ND
ND
ND
ND
16-Dec-09
0.30
5.0
ND
1.6 J
2.0 J
0.33 J
ND
ND
---
ND
NC 2L = 20 pg/L (02/05/10)
24-Jun-10
0.30
5.0
ND
0.96 J
1.7 J
0.31 J
ND
ND
---
ND
13-Dec-10
0.30
5.0
ND
1.9 J
1.9 J
0.43 J
ND
ND
---
ND
20-Jun-11
0.30
5.0
ND
1.5 J
1.7 J
0.37 J
ND
ND
---
ND
5-Dec-11
0.30
5.0
ND
1.3 J
1.6 J
ND
ND
ND
---
ND
11-Jun-12
0.30
5.0
ND
1.0 J
1.5 J
ND
ND
ND
ND
ND
12-Dec-12
0.30
5.0
ND
1.3 J
1.7 J
ND
ND
ND
---
ND
1-May-13
0.30
5.0
ND
1.2 J
1.6 J
ND
ND
ND
ND
ND
5-Aug-13
0.30
5.0
ND
1.2 J
1.6 J
0.30 J
ND
ND
---
ND
24-Feb-14
0.30
5.0
ND
1.4 J
0.64 J
ND
ND
ND
ND
ND
12-Aug-14
0.30
5.0
ND
1.2 J
1.5 J
ND
ND
ND
ND
ND
10-Mar-15
0.30
5.0
ND
1.1 J
1.1 J
ND
ND
ND
ND
ND
18-Aug-15
0.30
5.0
ND
0.88 J
1.3 J
ND
ND
ND
---
ND
16-Feb-16
0.30
5.0
ND
1.1 J
1.4 J
ND
ND
ND
ND
ND
9-Aug-16
0.30
5.0
ND
1.2 J
1.4 J
ND
ND
ND
---
ND
13-Feb-17
0.30
5.0
ND
1.2 J
1.4 J
ND
ND
ND
---
ND
22-Aug-17
0.30
5.0
ND
1.2 J
1.5 J
ND
ND
ND
---
ND
5-Feb-18
0.30
5.0
ND
1.0 J
1.4 J
ND
ND
ND
---
ND
13-Aug-18
0.30
5.0
ND
1.2 J
1.6 J
ND
ND
ND
---
ND
4-Feb-19
0.29
1.0
ND
1.0 J
ND
ND
ND
ND
---
ND
14-Aug-19 for MW--6 -->
7-Aug-19
0.29
1.0
N D
0.62 J
1.2
N D
N D
N D
---
N D
12-Feb-20
0.29
1.0
ND
0.82 J
0.71 J
ND
ND
ND
---
ND
27-Aug-20
0.29
1.0
ND
1.20
1.3
ND
ND
ND
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 13 of 20

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
1,4-Dichlorobenzene
8-Sep-94
---
5
ND
ND
5.0
ND
ND
ND
---
---
1-Dec-94
---
5
N D
N D
5.0
N D
N D
N D
---
---
9-Fe b-95
---
5
N D
8.0
6.0
N D
N D
N D
---
---
2-Mar-95
---
5
ND
7.0
6.0
ND
ND
ND
---
---
15-Nov-95
---
5
ND
7.0
6.0
ND
ND
ND
---
---
28-May-96
---
5
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
5
ND
ND
ND
ND
ND
ND
---
---
17-Jun-97
---
5
ND
7.6
6.2
ND
ND
ND
---
---
1-Dec-97
---
5
N D
6.0
5.0
4.0
ND
N D
---
---
20-May-98
---
5
ND
7.6
ND
ND
ND
ND
---
---
19-Nov-98
---
5
ND
3.7
2.8
ND
ND
ND
---
---
21-Jul-99
---
5
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
5
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
5
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
5
N D
5.0
6.0
N D
N D
N D
---
---
18-Apr-01
---
5
N D
N D
5.0
6.0
ND
ND
---
---
27-Oct-01
---
5
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
5
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
5
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
5
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
5
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
3
ND
3.0
3.3
ND
ND
ND
---
ND
Resample >
23-Feb-07
---
3
---
3.2
3.3
---
---
---
---
ND
12-Jul-07
---
1
ND
3.3
2.9
0.31 J
ND
ND
---
ND
NC 2L = 1.4 pg/L (10/23/07)
19-Dec-07
---
1
ND
3.0
2.7
ND
ND
ND
ND
ND
8-Jul-08
---
1
N D
3.0
2.4
N D
N D
N D
---
N D
17-Dec-08
0.33
1.0
ND
2.9
2.5
ND
ND
ND
---
ND
9-Jul-09
0.33
1.0
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
0.33
1.0
ND
2.8
2.2
ND
ND
ND
---
ND
NC 2L = 6 pg/L (02/05/10)
24-Jun-10
0.33
1.0
ND
1.6
ND
ND
ND
ND
---
ND
13-Dec-10
0.33
1.0
ND
3.1
1.9
ND
ND
ND
---
ND
20-Jun-11
0.33
1.0
ND
2.7
1.6
ND
ND
ND
---
ND
5-Dec-11
0.33
1.0
ND
2.2
1.4
ND
ND
ND
---
ND
11-Jun-12
0.33
1.0
ND
1.8
1.4
ND
ND
ND
ND
ND
12-Dec-12
0.33
1.0
ND
2.4
1.3
ND
ND
ND
---
ND
1-May-13
0.33
1.0
ND
2.1
1.2
ND
ND
ND
ND
ND
5-Aug-13
0.33
1.0
ND
2.0
1.3
ND
ND
ND
---
ND
24-Feb-14
0.33
1.0
ND
2.2
1.8
ND
ND
ND
ND
ND
12-Aug-14
0.33
1.0
ND
2.4
1.3
ND
ND
ND
ND
ND
10-Mar-15
0.33
1.0
ND
2.2
1.1
ND
ND
ND
ND
ND
18-Aug-15
0.33
1.0
ND
1.5
1.1
ND
ND
ND
---
ND
16-Feb-16
0.33
1.0
ND
2.0
1.0
ND
ND
ND
ND
ND
9-Aug-16
0.33
1.0
ND
1.9
1.0
ND
ND
ND
---
ND
13-Feb-17
0.33
1.0
ND
1.9
0.90 J
ND
ND
ND
---
ND
22-Aug-17
0.33
1.0
ND
1.9
0.96 J
ND
ND
ND
---
ND
5-Feb-18
0.33
1.0
ND
1.6
1.1
ND
ND
ND
---
ND
13-Aug-18
0.33
1.0
ND
1.9
1.1
ND
ND
ND
---
ND
4-Feb-19
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19for MW--6-->
7-Aug-19
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
0.26
1.0
ND
2.1
1.4
ND
ND
ND
---
ND
Trans-1,4-Dichloro-2-Butene
20-May-98
---
100
ND
ND
5.1
ND
ND
ND
---
---
19-Nov-98
---
100
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
100
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
100
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
100
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
100
N D
N D
N D
N D
N D
N D
---
---
18-Apr-01
---
100
N D
N D
N D
N D
N D
N D
---
---
27-Oct-01
---
100
N D
N D
N D
N D
N D
N D
---
---
19-Nov-02
---
100
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
100
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
100
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
100
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
100
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = NE pg/L
19-Dec-07
---
100
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
---
100
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
0.5
1
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19for MW--6-->
7-Aug-19
0.54
1.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
0.54
1.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
0.54
1.0
ND
ND
ND
ND
ND
ND
---
ND
1,4-Dioxane (p-Dioxane)
13-Aug-18
1.9
10
ND
88.0
53.1
40.7
2.0 J
ND
---
ND
NC 2L = 3 pg/L (2017)
4-Feb-19
1.9
2
ND
132
49.6
49.8
ND
ND
ND
ND
14-Aug-19 for MW--6 -->
7-Aug-19
1.2
2.0
N D
98.1
51.7
32.7
3.1
N D
---
N D
12-Feb-20
1.2
2.0
ND
98.2
44.4
36.0
ND
ND
---
ND
27-Aug-20
1.2
2.0
ND
113
50.0
39.3
3.0
ND
ND
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 14 of 20

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
1,1-Dichloroethane
1-Dec-97
---
5
ND
ND
1.0
ND
ND
ND
---
---
20-May-98
---
5
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
5
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
5
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
5
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
5
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
5
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
5
N D
N D
N D
N D
N D
ND
---
---
27-Oct-01
---
5
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
5
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
5
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
5
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
5
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
5
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
5
ND
ND
0.36 J
0.52 J
ND
ND
---
ND
NC 2L = 70 pg/L (10/23/07)
19-Dec-07
---
5
ND
ND
ND
0.57 J
ND
ND
ND
ND
8-Jul-08
---
5
ND
ND
ND
0.60 J
ND
ND
---
ND
17-Dec-08
0.32
5.0
ND
ND
ND
0.51 J
ND
ND
---
ND
9-Jul-09
0.32
5.0
ND
ND
ND
0.84 J
ND
ND
ND
ND
16-Dec-09
0.32
5.0
ND
ND
ND
0.73 J
ND
ND
---
ND
NC 2L = 6 pg/L (02/05/10)
24-Jun-10
0.32
5.0
ND
ND
ND
0.53 J
ND
ND
---
ND
13-Dec-10
0.32
5.0
ND
ND
ND
0.60 J
ND
ND
---
ND
20-Jun-11
0.32
5.0
ND
ND
ND
0.63 J
ND
ND
---
ND
5-Dec-11
0.32
5.0
ND
ND
ND
0.67 J
ND
ND
---
ND
11-Jun-12
0.32
5.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.32
5.0
ND
ND
ND
0.61 J
ND
ND
---
ND
1-May-13
0.32
5.0
ND
ND
ND
0.62 J
ND
ND
ND
ND
8-May-13
0.32
5.0
ND
ND
ND
0.53 J
ND
ND
---
ND
24-Feb-14
0.32
5.0
ND
ND
ND
0.50 J
ND
ND
ND
ND
12-Aug-14
0.32
5.0
ND
ND
ND
0.47 J
ND
ND
ND
ND
10-Mar-15
0.32
5.0
ND
ND
ND
0.50 J
ND
ND
ND
ND
18-Aug-15
0.32
5.0
ND
ND
ND
0.49 J
ND
ND
---
ND
16-Feb-16
0.32
5.0
ND
ND
ND
0.45 J
ND
ND
ND
ND
9-Aug-16
0.32
5.0
ND
ND
ND
0.34 J
ND
ND
---
ND
13-Feb-17
0.32
5.0
ND
ND
ND
0.33 J
ND
ND
---
ND
22-Aug-17
0.32
5.0
ND
ND
ND
0.37 J
ND
ND
---
ND
5-Feb-18
0.32
5.0
ND
ND
ND
0.38 J
ND
ND
---
ND
13-Aug-18
0.32
5.0
ND
ND
ND
0.37 J
ND
ND
---
ND
4-Feb-19
0.27
1.0
ND
ND
ND
0.36 J
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
0.27
1.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
0.27
1.0
ND
ND
ND
0.33 J
ND
ND
---
ND
27-Aug-20
0.27
1.0
ND
ND
ND
ND
ND
ND
---
ND
1,2-Dichloroethane
17-Dec-08
0.12
1.0
ND
ND
0.15 J
ND
ND
ND
---
ND
NC 2L = 0.38 pg/L (10/23/07)
9-Jul-09
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
0.19 J
16-Dec-09
0.12
1.0
ND
ND
0.14 J
ND
ND
ND
---
ND
NC 2L = 0.4 pg/L (02/05/10)
24-Jun-10
0.12
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
0.12
1.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.12
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.12
1.0
ND
ND
ND
ND
0.18 J
ND
---
ND
11-Jun-12
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.12
1.0
ND
ND
ND
ND
-0.20 J
ND
---
0.20 (ND) J
1-May-13
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.12
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.24
1.0
ND
ND
0.33 J
0.29 J
0.36 J
ND
---
---
16-Feb-16
0.24
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.24
1.0
0.25 J
ND
0.37 J
ND
0.43 J
ND
---
ND
13-Aug-18
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
0.34
1.0
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
0.34
1.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
0.34
1.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
0.34
1.0
ND
ND
ND
ND
ND
ND
---
ND
Ethylbenzene
17-Dec-08
0.30
1.0
ND
0.31 J
ND
ND
ND
ND
---
ND
NC 2L = 550 pg/L (10/23/07)
9-Jul-09
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 600 pg/L (02/05/10)
24-Jun-10
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
Isobutanol
24-Jun-10
35.0
100
ND
59.0 J
ND
ND
ND
ND
---
ND
NC 2L = NE pg/L (02/05/10)
13-Dec-10
---
---
---
---
---
---
---
---
---
---
20-Jun-11
35.0
100
ND
39.5 J
ND
ND
ND
ND
---
ND
5-Dec-11
---
---
---
---
--
---
---
---
---
---
11-Jun-12
35.0
100.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
---
---
---
---
--
---
---
---
---
---
1-May-13
35.0
100
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
--
---
---
---
---
---
24-Feb-14
35.0
100
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
35.0
100
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
35.0
100
ND
ND
ND
---
---
---
---
ND
16-Feb-16
35.0
100
ND
42.5 J
ND
---
---
---
---
ND
13-Feb-17
35.0
100
ND
ND
ND
---
---
---
---
ND
22-Aug-17
35.0
100
ND
ND
ND
---
---
---
---
ND
5-Feb-18
35.0
100
ND
ND
ND
---
---
---
---
ND
4-Feb-19
66.4
100
ND
ND
ND
---
---
---
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 15 of 20

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Methylene Chloride
9-Jul-09
0.97
2.0
ND
ND
ND
ND
ND
ND
ND
9.6
NC 2L = 4.3 pg/L (10/23/07)
16-Dec-09
0.97
2.0
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
0.97
1.0
ND
19.0
ND
ND
ND
ND
---
ND
Resample >
12-Aug-10
0.97
1.0
---
ND
---
---
---
---
---
ND
NC 2L = 5 pg/L (02/05/10)
13-Dec-10
0.97
1.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.97
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.97
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.97
1.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.97
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.97
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.97
1.0
1.3
1.1
1.6
ND
ND
ND
ND
ND
16-Feb-16
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.97
1.0
ND
ND
1.0 B
ND
ND
ND
---
2.2 B
13-Feb-17
0.97
1.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
0.97
1.0
ND
ND
ND
ND
ND
ND
---
1.4 C
5-Feb-18
0.97
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
0.97
1.0
ND
ND
ND
ND
ND
ND
---
6.6
4-Feb-19
3.70
5.0
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
3.7
5.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
3.7
5.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
3.7
5.0
ND
ND
ND
ND
ND
ND
---
ND
Naphthalene
8-Jul-08
---
10
ND
3.8 J
ND
ND
ND
ND
---
ND
NC 2L = 21 pg/L (10/23/07)
17-Dec-08
---
---
---
---
---
---
---
---
---
---
9-Jul-09
0.24
10.0
ND
2.4 J
ND
ND
ND
ND
---
ND
16-Dec-09
---
---
---
---
--
---
---
---
---
---
NC 2L = 6 pg/L (02/05/10)
24-Jun-10
0.24
10.0
ND
7.4 J
ND
ND
ND
ND
---
ND
13-Dec-10
---
---
---
---
--
---
---
---
---
---
20-Jun-11
0.24
10.0
ND
4.6 J
ND
ND
ND
ND
---
0.39 J
5-Dec-11
---
---
---
---
--
---
---
---
---
---
11-Jun-12
0.2
10.0
ND
4.6 J
ND
ND
ND
ND
ND
ND
12-Dec-12
---
---
---
---
--
---
---
---
---
---
1-May-13
0.24
10.0
ND
5.1 J
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
--
---
---
---
---
---
24-Feb-14
0.24
10.0
ND
5.8 J
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
--
---
---
---
---
---
10-Mar-15
0.2
10
ND
5.4 J
ND
---
---
---
---
ND
16-Feb-16
0.2
10
ND
5.7 J
N D
---
---
---
---
ND
13-Feb-17
0.2
10
ND
6.1 J
ND
---
---
---
---
ND
22-Aug-17
0.2
10
ND
7.0 J
0.45 J
---
---
---
---
ND
5-Feb-18
0.2
10
ND
5.7 J
ND
---
---
---
---
ND
4-Feb-19
0.4
1
N D
4.2
N D
---
---
---
---
N D
Toluene
20-May-98
---
5
ND
ND
8.1
ND
ND
ND
---
---
19-Nov-98
---
5
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
5
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
5
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
5
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
5
ND
ND
ND
ND
ND
ND
---
---
18-Apr-01
---
5
N D
N D
N D
N D
N D
ND
---
---
27-Oct-01
---
5
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
5
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
5
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
5
ND
ND
ND
ND
ND
ND
---
30-Dec-03
---
5
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
5
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
1
ND
0.49 B
ND
ND
ND
ND
---
0.34 J
NC 2L = 1,000 pg/L (10/23/07)
19-Dec-07
---
1
ND
0.51 J
ND
ND
ND
ND
ND
ND
8-Jul-08
---
1
ND
0.39 J
ND
ND
1.3
ND
---
ND
17-Dec-08
0.26
1.0
1.4
1.6
ND
ND
11.7
ND
---
ND
9-Jul-09
0.26
1.0
ND
0.46 J
ND
ND
ND
ND
ND
ND
16-Dec-09
0.26
1.0
ND
0.42 J
ND
ND
ND
ND
---
ND
NC 2L = 600 pg/L (02/05/10)
24-Jun-10
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
0.26
1.0
ND
0.54 J
ND
ND
ND
ND
---
ND
20-Jun-11
0.26
1.0
ND
0.34 J
ND
ND
ND
ND
---
ND
5-Dec-11
0.26
1.0
ND
0.28 J
ND
ND
0.30 J
ND
---
ND
11-Jun-12
0.26
1.0
ND
0.28 J
ND
ND
ND
ND
ND
ND
12-Dec-12
0.26
1.0
ND
0.29 J
ND
ND
0.36 J
ND
---
ND
1-May-13
0.26
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.26
1.0
ND
0.29 J
ND
ND
ND
ND
---
ND
24-Feb-14
0.26
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.26
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.26
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.26
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.26
1.0
ND
0.33 J
ND
ND
ND
ND
---
ND
13-Feb-17
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
0.26
1.0
ND
ND
ND
ND
0.44 J
ND
---
ND
4-Feb-19
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 16 of 20

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Vinyl Chloride
8-Sep-94
---
10
ND
ND
12.0
ND
ND
ND
---
---
1-Dec-94
---
10
ND
ND
13.0
ND
ND
ND
---
---
9-Feb-95
---
10
ND
ND
15.0
ND
ND
ND
---
---
2-Mar-95
---
10
ND
ND
14.0
ND
ND
ND
---
---
15-Nov-95
---
10
ND
ND
11.0
ND
ND
ND
---
---
28-May-96
---
10
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
10
ND
ND
ND
ND
ND
ND
---
---
17-Jun-97
---
10
ND
ND
ND
ND
ND
ND
---
---
1-Dec-97
---
10
ND
ND
7.0
4.0
ND
ND
---
---
20-May-98
---
10
ND
ND
ND
ND
ND
ND
---
---
19-Nov-98
---
10
ND
ND
ND
ND
ND
ND
---
---
21-Jul-99
---
10
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
---
10
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
10
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
10
N D
N D
N D
N D
N D
N D
---
---
18-Apr-01
---
10
ND
ND
ND
N D
N D
N D
---
---
27-Oct-01
---
10
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
10
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
10
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
10
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
10
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
5.5
ND
ND
0.98 J
ND
ND
ND
---
ND
Resample >
23-Feb-07
---
5.5
---
---
1.0
---
---
---
---
ND
12-Jul-07
---
1
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 0.015 pg/L (10/23/07)
19-Dec-07
---
1
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
---
1
ND
ND
0.76 J
ND
ND
ND
---
ND
17-Dec-08
0.62
1.0
ND
ND
0.76 J
ND
ND
ND
---
ND
9-Jul-09
0.62
1.0
ND
ND
0.99 J
ND
ND
ND
ND
ND
16-Dec-09
0.62
1.0
ND
ND
0.81 J
ND
ND
ND
---
ND
NC 2L = 0.03 pg/L (02/05/10)
24-Jun-10
0.62
1.0
ND
ND
0.77 J
ND
ND
ND
---
ND
13-Dec-10
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.62
1.0
ND
ND
0.63 J
ND
ND
ND
---
ND
13-Aug-18
0.62
1.0
ND
ND
0.72 J
ND
ND
ND
---
ND
4-Feb-19
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19for Mw-6-->
7-Aug-19
0.24
1.0
ND
ND
1.1
ND
ND
ND
---
ND
Resample >
4-Sep-19
0.24
1.0
ND
---
ND
12-Feb-20
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
0.24
1.0
ND
ND
1.1
ND
ND
ND
---
ND
Resample >
30-Sep-20
0.24
1.0
---
---
ND
---
---
---
---
ND
Xylene (Total)
29-Dec-06
---
5
ND
1.4
ND
ND
ND
ND
---
ND
12-Jul-07
---
4
ND
1.2 J
ND
ND
ND
ND
---
ND
NC 2L = 530 pg/L (10/23/07)
19-Dec-07
---
4
ND
2.0
ND
ND
ND
ND
ND
ND
8-Jul-08
---
4
ND
1.1 J
ND
ND
ND
ND
---
ND
17-Dec-08
0.66
2.0
1.4 J
2.7
ND
ND
ND
ND
---
ND
9-Jul-09
0.66
2.0
ND
1.5 J
ND
ND
ND
ND
ND
ND
16-Dec-09
0.66
2.0
ND
2.2
ND
ND
ND
ND
---
ND
NC 2L = 500 pg/L (02/05/10)
24-Jun-10
0.66
2.0
ND
0.73 J
ND
ND
ND
ND
---
ND
13-Dec-10
0.66
2.0
ND
2.0
ND
ND
ND
ND
---
ND
20-Jun-11
0.66
2.0
ND
1.4 J
ND
ND
ND
ND
---
ND
5-Dec-11
0.66
2.0
ND
1.1 J
ND
ND
ND
ND
---
ND
11-Jun-12
0.66
2.0
ND
0.91 J
ND
ND
ND
ND
ND
ND
12-Dec-12
0.66
5.0
ND
0.97 J
ND
ND
ND
ND
---
ND
1-May-13
0.66
5.0
ND
0.68 J
ND
ND
ND
ND
ND
ND
5-Aug-13
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.66
5.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.66
5.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.66
5.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.66
5.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
0.63
1.0
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19for MW--6-->
7-Aug-19
0.63
1.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
0.63
1.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
0.63
1.0
ND
ND
ND
ND
ND
ND
---
ND
Bis(2-Ethylhexyl)phthalate
24-Feb-14
0.79
15.0
2.6 J
ND
ND
ND
ND
ND
ND
ND
NC 2L = 3 pg/L (2/5/10)
15-Apr-14
0.79
15.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
---
---
---
---
--
---
---
---
---
---
10-Ma r-15
0.5
15.0
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.9
15.0
N D
N D
N D
---
---
---
---
N D
13-Feb-17
0.9
15.0
N D
N D
N D
---
---
---
---
ND
22-Aug-17
2.3
15.0
ND
ND
ND
---
---
---
---
ND
5-Feb-18
2.4
15.6
N D
N D
N D
---
---
---
---
ND
4-Feb-19
1.4
6.0
N D
N D
N D
---
---
---
---
N D
N-Nitroso-di-n-butylamine
24-Feb-14
7.5
10.0
ND
ND
ND
8.6 J
ND
ND
ND
ND
12-Aug-14
---
---
---
--
---
---
---
---
---
---
10-Ma r-15
1.3
10
ND
ND
ND
---
---
---
---
N D
16-Feb-16
2.2
10
N D
N D
N D
---
---
---
---
ND
13-Feb-17
2.2
10
N D
N D
N D
---
---
---
---
N D
22-Aug-17
1.6
10
ND
ND
N D
---
---
---
---
N D
5-Feb-18
1.6
10
N D
N D
N D
---
---
---
---
N D
4-Feb-19
2.2
10
ND
ND
ND
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 17 of 20

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Benzo(g,h,i)perylene
20-Jun-11
0.4
10.0
ND
ND
ND
ND
ND
1.4 J
---
ND
NC 2L = 200 pg/L (2/5/10)
5-Dec-11
---
---
---
---
---
---
---
---
---
---
11-Jun-12
0.38
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
---
---
---
---
--
---
---
---
---
---
1-May-13
0.38
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
--
---
---
---
---
---
24-Feb-14
0.38
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
--
---
---
---
---
---
10-Ma r-15
0.5
10.0
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.4
10.0
N D
N D
N D
---
---
---
---
N D
13-Feb-17
0.4
10.0
N D
N D
N D
---
---
---
---
ND
22-Aug-17
2.1
10.0
ND
ND
ND
---
---
---
---
ND
5-Feb-18
2.2
10.4
N D
N D
N D
---
---
---
---
ND
4-Feb-19
1.8
10.0
N D
N D
N D
---
---
---
---
N D
Dibenz(a,h)anth race ne
20-Jun-11
0.55
10.0
ND
ND
ND
ND
ND
1.5 J
---
ND
NC 2L = 0.005 pg/L (2/5/10)
5-Dec-11
---
---
---
---
---
---
---
---
---
---
11-Jun-12
0.55
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
---
---
---
--
---
---
---
---
---
---
1-May-13
0.55
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
--
---
---
---
---
---
---
24-Feb-14
0.55
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
--
---
---
---
---
---
---
10-Ma r-15
0.5
10.0
ND
ND
N D
---
---
---
---
N D
16-Feb-16
0.6
10.0
N D
N D
N D
---
---
---
---
ND
13-Feb-17
0.6
10.0
N D
N D
N D
---
---
---
---
N D
22-Aug-17
2.0
10.0
ND
ND
ND
---
---
---
---
ND
5-Feb-18
2.1
10.4
ND
ND
ND
---
---
---
---
ND
4-Feb-19
1.9
10.0
N D
N D
N D
---
---
---
---
ND
Fluorene
24-Jun-10
3.8
12.2
ND
4.3 J
ND
ND
ND
ND
---
ND
Resample >
12-Aug-10
3.1
10.0
---
ND
---
---
---
---
---
ND
NC 2L = 300 pg/L (2/5/10)
13-Dec-10
---
---
---
---
---
---
---
---
---
---
20-Jun-11
0.2
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
---
---
--
---
---
---
---
---
---
---
11-Jun-12
0.21
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
---
---
---
--
---
---
---
---
---
---
1-May-13
0.21
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
--
---
---
---
---
---
---
24-Feb-14
0.21
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
--
---
---
---
---
---
---
10-Ma r-15
1.0
10.0
ND
ND
N D
---
---
---
---
N D
16-Feb-16
0.2
10.0
N D
N D
N D
---
---
---
---
ND
13-Feb-17
0.2
10.0
ND
ND
ND
---
---
---
---
N D
22-Aug-17
1.6
10.0
ND
ND
ND
---
---
---
---
ND
5-Feb-18
1.6
10.4
N D
N D
N D
---
---
---
---
N D
4-Feb-19
3.0
10.0
N D
N D
N D
---
---
---
---
ND
Indeno(1,2,3-cd)pyrene
20-Jun-11
0.29
10.0
ND
ND
ND
ND
ND
1.3 J
---
ND
NC 2L = 0.05 pg/L (2/5/10)
5-Dec-11
---
---
---
---
---
---
---
---
---
---
11-Jun-12
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
---
---
---
---
--
---
---
---
---
---
1-May-13
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
--
---
---
---
---
---
24-Feb-14
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
--
---
---
---
---
---
10-Ma r-15
0.5
10.0
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.3
10.0
N D
N D
N D
---
---
---
---
N D
13-Feb-17
0.3
10.0
N D
N D
N D
---
---
---
---
ND
22-Aug-17
2.0
10.0
ND
ND
ND
---
---
---
---
ND
5-Feb-18
2.1
10.4
N D
N D
N D
---
---
---
---
ND
4-Feb-19
1.7
10.0
N D
N D
N D
---
---
---
---
N D
2-Methylnaphthalene
24-Jun-10
5.1
12.2
ND
38.9
ND
ND
ND
ND
---
ND
Resample>
12-Aug-10
4.2
10
---
ND
---
---
---
---
---
ND
NC 2L = 30 pg/L (02/05/10)
13-Dec-10
---
---
---
---
---
---
---
---
---
---
20-Jun-11
0.3
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
---
---
---
---
--
---
---
---
---
---
11-Jun-12
0.28
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
---
---
---
---
--
---
---
---
---
---
1-May-13
0.28
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
--
---
---
---
---
---
24-Feb-14
0.28
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
--
---
---
---
---
---
10-Ma r-15
1.0
10.0
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.3
10.0
N D
N D
N D
---
---
---
---
N D
13-Feb-17
0.3
10.0
N D
N D
N D
---
---
---
---
ND
22-Aug-17
1.4
10.0
ND
ND
ND
---
---
---
---
ND
5-Feb-18
1.5
10.4
N D
N D
N D
---
---
---
---
ND
4-Feb-19
2.8
10.0
N D
N D
N D
---
---
---
---
N D
Phorate
18-Apr-01
---
10
---
3.2
ND
ND
ND
---
---
---
27-Oct-01
---
5
N D
8.1
ND
N D
N D
N D
---
---
27-Oct-01
---
0.5
---
8.1
1.3
ND
ND
---
---
---
13-Jun-02
---
5
ND
ND
ND
ND
ND
ND
---
---
13-J u n-02
---
0.5
---
ND
ND
N D
N D
---
---
---
19-Nov-02
---
5
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
5
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
---
---
--
---
---
---
---
---
---
28-Jun-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
---
---
--
---
---
---
---
---
---
12-Jul-07
---
10
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 1.4 pg/L (10/23/07)
19-Dec-07
---
---
---
---
---
---
---
---
ND
---
8-Jul-08
---
10
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
---
---
---
--
---
---
---
---
---
---
9-Jul-09
6.6
22.2
ND
ND
ND
ND
ND
ND
---
ND
16-Dec-09
---
---
---
--
---
---
---
---
---
---
NC 2L = 1 pg/L (02/05/10)
24-Jun-10
6.5
24.1
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
---
---
---
--
---
---
---
---
---
---
20-Jun-11
5.4
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
---
---
--
---
---
---
---
---
---
---
11-Jun-12
5.4
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
---
---
---
--
---
---
---
---
---
---
1-May-13
5.4
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
--
---
---
---
---
---
---
24-Feb-14
5.4
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
--
---
---
---
---
---
---
10-Ma r-15
0.8
10.0
ND
ND
N D
---
---
---
---
N D
16-Feb-16
1.1
10.0
N D
N D
N D
---
---
---
---
ND
13-Feb-17
1.1
10.0
N D
N D
N D
---
---
---
---
N D
22-Aug-17
1.7
10.0
ND
ND
ND
---
---
---
---
ND
5-Feb-18
1.8
10.4
N D
N D
N D
---
---
---
---
N D
4-Feb-19
1.1
10.0
N D
N D
N D
---
---
---
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 18 of 20

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-IR
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Beta-BHC
11-Jun-12
0.050
0.050
ND
ND
0.16
ND
ND
ND
---
ND
NC 2L = 0.019 pg/L (10/23/07)
19-Jul-12
0.050
0.050
---
---
ND
---
---
---
---
---
12-Dec-12
---
---
---
---
---
---
---
---
---
---
1-May-13
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
---
---
---
---
24-Feb-14
0.050
0.050
IND
0.052
IND
IND
IND
IND
---
IND
Resample >
15-Apr-14
0.050
0.050
---
ND
---
---
---
---
---
ND
12-Aug-14
---
---
---
---
---
---
---
---
---
---
10-Mar-15
0.1
0.1
ND
ND
IND
---
---
---
---
IND
16-Feb-16
0.1
0.1
ND
IND
IND
---
---
---
---
IND
13-Feb-17
0.1
0.1
ND
ND
ND
---
---
---
---
ND
5-Feb-18
0.1
0.1
IND
IND
IND
---
---
---
---
IND
4-Feb-19
0.1
0.1
IND
IND
IND
---
---
---
---
IND
Delta-BHC
11-Jun-12
0.050
0.050
ND
ND
0.090
ND
ND
ND
---
ND
NC 2L = 0.019 pg/L (10/23/07)
19-Jul-12
0.050
0.050
---
---
ND
---
---
---
---
---
12-Dec-12
---
---
---
---
---
---
---
---
---
---
1-May-13
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
---
---
---
---
24-Feb-14
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
---
---
---
---
---
---
10-Mar-15
0.050
0.050
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.050
0.050
ND
ND
ND
---
---
---
---
ND
13-Feb-17
0.050
0.050
ND
ND
ND
---
---
---
---
ND
5-Feb-18
0.052
0.052
ND
ND
ND
---
---
---
---
ND
4-Feb-19
0.050
0.050
ND
ND
ND
---
---
---
---
ND
gamma-BHC (Lindane)
27-Jun-03
---
1.05
ND
0.085
ND
ND
ND
ND
---
ND
30-Dec-03
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 0.2 pg/L (10/23/07)
19-Dec-07
---
0.05
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
---
0.50
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
16-Dec-09
0.01
0.1
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 0.03 pg/L (02/05/10)
24-Jun-10
0.00021
0.010
ND
ND
0.052
ND
ND
ND
---
ND
Resample >
12-Aug-10
0.00020
0.010
---
---
ND
---
---
---
---
ND
13-Dec-10
0.00020
0.050
ND
ND
0.013 J
ND
ND
ND
---
ND
20-Jun-11
0.00020
0.050
ND
ND
0.066
ND
ND
ND
---
ND
Resample >
28-Jul-11
0.00020
0.010
---
---
ND
---
---
---
---
ND
5-Dec-11
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
0.050
0.050
ND
ND
ND
---
---
---
---
ND
10-Mar-15
0.050
0.050
ND
ND
ND
---
---
---
---
ND
18-Aug-15
0.050
0.050
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.050
0.050
ND
ND
ND
---
---
---
---
ND
9-Aug-16
0.050
0.050
ND
ND
ND
---
---
---
---
ND
13-Feb-17
0.050
0.050
ND
ND
ND
---
---
---
---
ND
5-Feb-18
0.052
0.052
ND
ND
ND
---
---
---
---
ND
4-Feb-19
0.050
0.050
ND
ND
ND
---
---
---
---
ND
Heptachlor
27-Jun-03
---
1.05
ND
0.03
0.17
ND
ND
ND
---
ND
30-Dec-03
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 0.0078 pg/L (10/23/07)
19-Dec-07
---
0.05
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
16-Dec-09
0.02
0.1
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 0.008 pg/L (02/05/10)
24-Jun-10
0.0015
0.010
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
0.0500
0.0015
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.050
0.0015
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.050
0.056
ND
0.062
ND
ND
ND
ND
---
ND
Resample >
25-Jan-12
0.050
0.0500
---
ND
---
---
---
---
---
ND
11-Jun-12
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
0.050
0.050
ND
ND
ND
---
---
---
---
ND
10-Mar-15
0.050
0.050
ND
ND
ND
---
---
---
---
ND
18-Aug-15
0.050
0.050
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.050
0.050
ND
ND
ND
---
---
---
---
ND
9-Aug-16
0.050
0.050
ND
ND
ND
---
---
---
---
ND
13-Feb-17
0.050
0.050
ND
ND
ND
---
---
---
---
ND
5-Feb-18
0.052
0.052
ND
ND
ND
---
---
---
---
ND
4-Feb-19
0.050
0.050
ND
ND
ND
---
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 19 of 20

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
2,4-D
27-Jun-03
---
3
---
5.9
ND
ND
ND
---
---
---
30-Dec-03
---
2
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
2
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
2
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
2
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 70 pg/L (10/23/07)
19-Dec-07
---
2
ND
ND
ND
ND
ND
ND
ND
ND
8-Apr-08
---
2
N D
N D
N D
N D
N D
N D
---
N D
17-Dec-08
---
2.0
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
---
2.0
ND
ND
ND
ND
ND
ND
---
ND
16-Dec-09
0.11
5.0
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
0.23
2.1
ND
ND
ND
ND
ND
ND
---
ND
10-Dec-10
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
0.22
2.0
ND
ND
ND
---
---
---
---
ND
10-Mar-15
0.24
2.1
ND
ND
ND
---
---
---
---
ND
18-Aug-15
0.24
2.1
N D
N D
N D
---
---
---
---
N D
16-Feb-16
0.23
1.0
ND
ND
ND
---
---
---
---
ND
9-Aug-16
0.24
1.0
ND
ND
ND
---
---
---
---
ND
13-Feb-17
0.22
0.9
ND
ND
ND
---
---
---
---
ND
22-Aug-17
0.24
1.0
ND
ND
ND
---
---
---
---
ND
5-Feb-18
0.24
1.0
ND
ND
ND
---
---
---
---
ND
4-Feb-19
1.60
5.0
ND
ND
ND
---
---
---
---
ND
4,4'-DDD
11-Jun-12
0.05
0.05
ND
ND
0.13
ND
ND
ND
---
ND
Resample>
19-Jul-12
0.05
0.10
---
---
ND
---
---
---
---
---
NC 2L = 0.1 pg/L (2/5/10)
12-Dec-12
---
---
---
---
---
---
---
---
---
---
1-May-13
0.050
0.10
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
--
---
---
---
---
---
24-Feb-14
0.050
0.10
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
--
---
---
---
---
---
10-Mar-15
0.050
0.10
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.050
0.10
ND
ND
ND
---
---
---
---
ND
13-Feb-17
0.050
0.10
ND
ND
ND
---
---
---
---
ND
5-Feb-18
0.052
0.10
ND
ND
ND
---
---
---
---
ND
4-Feb-19
0.050
0.05
ND
ND
ND
---
---
---
---
ND
4,4'-DDT
11-Jun-12
0.05
0.05
ND
ND
0.10
ND
ND
ND
---
ND
Resample>
19-Jul-12
0.05
0.10
---
---
0.063 J
---
---
---
---
---
NC 2L = 0.1 pg/L (2/5/10)
12-Dec-12
---
---
---
---
---
---
---
---
---
---
1-May-13
0.050
0.10
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
--
---
---
---
---
---
---
24-Feb-14
0.050
0.10
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
--
---
---
---
---
---
---
10-Mar-15
0.050
0.10
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.050
0.10
ND
ND
ND
---
---
---
---
ND
13-Feb-17
0.050
0.10
ND
ND
ND
---
---
---
---
ND
5-Feb-18
0.052
0.10
ND
ND
ND
---
---
---
---
ND
4-Feb-19
0.050
0.05
ND
ND
ND
---
---
---
---
ND
Dinoseb
10-Mar-15
0.061
1.1
ND
ND
0.11 J
---
---
---
---
ND
16-Feb-16
0.058
0.19
ND
ND
ND
---
---
---
---
ND
13-Feb-17
0.057
0.19
ND
ND
ND
---
---
---
---
ND
22-Aug-17
0.062
0.20
ND
ND
ND
---
---
---
---
ND
5-Feb-18
0.061
0.20
ND
ND
ND
---
---
---
---
ND
4-Feb-19
1.200
5.00
ND
ND
ND
---
---
---
---
ND
Endrin aldehyde
11-Jun-12
0.050
0.050
ND
ND
0.14
ND
ND
ND
---
---
NC 2L= 2 (2/5/10)
12-Dec-12
0.050
0.10
ND
ND
ND
ND
ND
ND
---
---
1-May-13
0.050
0.10
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
0.050
0.10
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.050
0.10
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
0.050
0.10
ND
ND
ND
---
---
---
---
ND
10-Mar-15
0.050
0.10
ND
ND
ND
---
---
---
---
ND
18-Aug-15
0.050
0.10
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.050
0.10
ND
ND
ND
---
---
---
---
ND
9-Aug-16
0.050
0.10
ND
ND
ND
---
---
---
---
ND
13-Feb-17
0.050
0.10
ND
ND
ND
---
---
---
---
ND
5-Feb-18
0.052
0.10
ND
ND
ND
---
---
---
---
ND
4-Feb-19
0.050
0.05
ND
ND
ND
---
---
---
---
ND
Diethylphthalate
4-Feb-19
2.00
10.00
ND
7.1 J
ND
---
---
---
---
ND
Endosulfan I
4-Feb-19
0.05
0.05
---
0.078
0.19
---
---
---
---
---
Dichlorodifluoromethane
5-Feb-18
0.21
5.0
ND
0.36 J
ND
---
---
---
---
ND
4-Feb-19
0.23
1.0
N D
N D
N D
---
---
---
---
N D
Notes:
All concentrations are in micrograms per liter (pg/L).
RL = Reporting Limit (SWSL for December 2006 - present).
DL = Laboratory detection limit.
J = Estimated value between the DL and the RL.
B = Blank -qualified data; result is expected to be biased high based on concentrations in the blanks.
ND = Not detected above laboratory reporting limit.
NC 2L = North Carolina Groundwater Standards from 15A NCAC 2L.0202.
IMAC = Interim Maximum Allowable Concetration (for constituents with no NC2L).
Bold values for groundwater are above the NC 2L Standards or IMAC.
--- = Well was not monitored and/or not reported.
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 20 of 20

Appendix F
Historical Constituents in Surface Water

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
INORGANICS
Arsenic
06/24/10
2.7
10.00
4.30 J
2.90 J
ND
NC2B = 10 pg/L (03/28/08)
12/13/10
2.7
10.0
ND
ND
ND
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
ND
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
---
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
3.0 J
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
10.0
ND
ND
ND
08/09/16
EPA 6010
2.5
10.0
3.10 B
ND
5.1 J
02/13/17
EPA 6010
5.0
10.0
ND
ND
ND
08/22/17
EPA 6010
5.0
10.0
ND
ND
ND
02/05/18
EPA 6010
5.0
10.0
ND
ND
ND
08/13/18
EPA 6010D
5.0
10.0
ND
ND
ND
02/04/19
EPA 6010D
5.0
10.0
ND
ND
---
08/07/19
EPA 6010D
4.7
10.0
ND
ND
ND
02/12/20
EPA 6010D
4.7
10.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
Barium
11/22/96
---
500
37.0
37.0
---
06/17/97
---
500
37.0
62.0
---
12/01/97
---
500
53.0
45.0
---
05/20/98
---
500
24.0
69.0
---
11/19/98
---
500
ND
100.0
---
07/21/99
---
500
ND
ND
---
11/16/99
---
500
ND
ND
---
05/10/00
---
500
ND
ND
---
10/26/00
---
500
ND
ND
---
04/18/01
---
500
ND
ND
---
10/27/01
---
500
ND
ND
---
06/13/02
---
500
---
---
---
11/19/02
---
500
ND
ND
---
06/27/03
---
500
ND
ND
---
12/30/03
---
500
ND
ND
ND
06/30/04
---
500
ND
ND
ND
12/29/04
---
500
ND
ND
ND
12/29/04
---
500
ND
ND
ND
06/29/05
---
500
ND
ND
ND
12/29/05
---
500
ND
ND
ND
06/28/06
---
500
ND
ND
ND
12/29/06
---
100
37.5
40.6
0.20 J
07/12/07
---
100
33.3 J
---
ND
12/19/07
---
100
52.6 B
149.0
11.7
07/08/08
---
100
33.8 J
161.0
0.3 J
12/17/08
0.2
100
30.2 B
33.5 B
10.7 J
07/09/09
0.2
100
36.8 B
78.4 B
17.6 J
12/16/09
0.2
100
31.2 B
36.2 B
17.1 J
06/24/10
0.2
100
34.5 B
71.3 B
27.3 J
12/13/10
0.2
100
36.1 B
91.0 J
12.1 J
06/20/11
5.0
100
40.3 J
93.0 J
ND
12/05/11
5.0
100
32.9 J
59.0 J
ND
06/11/12
5.0
100
40.0 J
95.6 J
ND
12/12/12
5.0
100
45.0 J
97.8 J
ND
05/01/13
5.0
100
32.7 J
43.1 J
ND
08/05/13
5.0
100
49.9 J
79.8 J
ND
02/24/14
5.0
100
29.0 J
30.4 J
ND
08/12/14
EPA 6010
5.0
100
---
121
ND
03/10/15
EPA 6010
2.5
100
29.0 J
32.1 J
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
100
33.1 J
33.5 J
ND
08/09/16
EPA 6010
2.5
100
43.3 J
105
ND
02/13/17
EPA 6010
2.5
100
45.3 J
60.4 J
ND
08/22/17
EPA 6010
2.5
100
39.7 J
88.7 J
ND
02/05/18
EPA 6010
2.5
100
32.5 J
29.1 J
ND
08/13/18
EPA 6010D
2.5
100
70.0 J
86.6 J
ND
02/04/19
EPA 6010D
2.5
5
29.1
33.1
---
ISTV = 21,000 pg/L
08/07/19
EPA 6010D
1.0
5.0
70.0
94.4
ND
02/12/20
EPA 6010D
1.0
5.0
27.6
30.3
ND
11
08/27/20
--
--
Dry
Dry
--
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 1 of 8

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Beryllium
07/08/08
---
1.0
0.32 J
ND
ND
12/17/08
0.1
1.0
ND
ND
ND
07/09/09
0.1
1.0
ND
ND
ND
12/16/09
0.1
1.0
0.12 J
ND
ND
NC2B = 6.5 pg/L (02/05/10)
06/24/10
0.1
1.0
ND
ND
ND
12/13/10
0.1
1.0
ND
ND
ND
06/20/11
1.0
1.0
ND
ND
ND
12/05/11
1.0
1.0
ND
ND
ND
06/11/12
1.0
1.0
ND
ND
ND
12/12/12
1.0
1.0
ND
ND
ND
05/01/13
1.0
1.0
ND
ND
ND
08/05/13
1.0
1.0
ND
ND
ND
02/24/14
1.0
1.0
ND
ND
ND
08/12/14
EPA 6010
1.0
1.0
---
ND
ND
03/10/15
EPA 6010
0.50
1.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
0.50
1.0
ND
ND
ND
08/09/16
EPA 6010
0.50
1.0
ND
ND
ND
02/13/17
EPA 6010
0.50
1.0
ND
ND
ND
08/22/17
EPA 6010
0.50
1.0
ND
ND
ND
NC2B = Hardness Dependant
02/05/18
EPA 6010
0.50
1.0
ND
ND
ND
08/13/18
EPA 6010D
0.50
1.0
ND
ND
ND
02/04/19
EPA 6010D
0.50
1.0
ND
ND
---
08/07/19
EPA 6010D
0.20
1.0
ND
ND
ND
02/12/20
EPA 6010D
0.20
1.0
0.21 J
0.25 J
ND
08/27/20
---
---
Dry
Dry
---
Chromium
06/17/97
---
10.0
ND
3.00
---
12/01/97
---
10.0
ND
ND
---
05/20/98
---
10.0
ND
ND
---
11/19/98
---
10.0
ND
ND
---
07/21/99
---
10.0
ND
ND
---
11/16/99
---
10.0
ND
ND
---
05/10/00
---
10.0
ND
ND
---
10/26/00
---
10.0
ND
ND
---
04/18/01
---
10.0
ND
ND
---
10/27/01
---
10.0
ND
ND
---
06/13/02
---
10.0
---
---
---
11/19/02
---
10.0
ND
ND
---
06/27/03
---
10.0
ND
ND
---
12/30/03
---
10.0
ND
ND
ND
06/30/04
---
10.0
ND
ND
ND
12/29/04
---
10.0
ND
ND
ND
06/29/05
---
10.0
ND
ND
ND
12/29/05
---
10.0
ND
ND
ND
06/28/06
---
10.0
ND
ND
ND
12/29/06
---
10.0
ND
ND
ND
07/12/07
---
10.0
ND
---
ND
12/19/07
---
10.0
2.20 B
2.60 B
1.40 J
NC2B = 50 pg/L (03/28/08)
07/08/08
---
10.0
2.50 J
2.20 J
ND
12/17/08
0.4
10.0
1.40 J
2.60 J
ND
07/09/09
0.4
10.0
2.6 J
1.2 J
ND
12/16/09
0.4
10.0
4.1 J
3.4 J
ND
06/24/10
0.4
10.0
3.3 B
7.3 J
0.71 J
12/13/10
0.4
10.0
1.4 J
1.5 J
ND
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
7.2 J
ND
12/12/12
5.0
10.0
ND
8.2 J
ND
05/01/13
5.0
10.0
5.7 J
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
---
ND
ND
03/10/15
EPA 6010
2.5
10.0
4.4 J
3.6 J
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
10.0
4.6 J
6.8 J
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
2.90 J
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
02/05/18
EPA 6010
2.5
10.0
6.9 J
7.9 J
ND
NC2B = Hardness Dependant
08/13/18
EPA 6010D
2.5
10.0
5.9 J
ND
ND
02/04/19
EPA 6010D
2.5
5.0
ND
ND
---
08/07/19
EPA 6010D
1.0
5.0
ND
ND
ND
02/12/20
EPA 6010D
1.0
5.0
5.3
4.7 J
ND
08/27/20
---
---
Dry
Dry
---
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 2 of 8

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Cobalt
05/20/98
---
10
2.0
2.0
---
11/19/98
---
10
ND
3.0
---
07/21/99
---
10
ND
ND
---
11/16/99
---
10
ND
ND
---
05/10/00
---
10
ND
ND
---
10/26/00
---
10
ND
ND
---
04/18/01
---
10
ND
ND
---
10/27/01
---
10.0
ND
22.0
---
06/13/02
---
10.0
---
---
---
11/19/02
---
10.0
ND
ND
---
06/27/03
---
10.0
ND
10.0
---
12/30/03
---
10.0
ND
ND
ND
06/30/04
---
10.0
ND
ND
ND
12/29/04
---
10.0
ND
ND
ND
06/29/05
---
10.0
ND
ND
ND
12/29/05
---
10.0
ND
ND
ND
06/28/06
---
10.0
ND
ND
ND
12/29/06
---
10.0
ND
ND
ND
07/12/07
---
10.0
ND
---
ND
12/19/07
---
10.0
4.2 B
1.20 B
1.8 J
07/08/08
---
10.0
4.80 B
10.5 B
6.20 J
12/17/08
0.6
10.0
1.70 B
1.1 B
2.50 J
07/09/09
0.6
10.0
ND
ND
ND
12/16/09
0.6
10.0
ND
1.0 J
ND
NC2B = NE pg/L (03/24/10)
06/24/10
0.6
10.0
ND
ND
ND
12/13/10
0.6
10.0
14.41 B
(ND}
1.6 (1.0 J} J
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
Resample >
01/25/12
5.0
10.0
---
---
ND
06/11/12
5.0
10.0
ND
5.10 J
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
---
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
10.0
ND
ND
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
ND
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
02/05/18
EPA 6010
2.5
10.0
ND
ND
ND
08/13/18
EPA 6010D
2.5
10.0
6.0 J
ND
ND
02/04/19
EPA 6010D
2.5
5.0
ND
ND
---
ISTV = 4 pg/L
08/07/19
EPA 6010D
1.1
5.0
2.5 J
ND
ND
02/12/20
EPA 6010D
1.1
5.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
Copper
12/29/06
---
10.0
1.3 B
1.10 B
0.60 J
07/12/07
---
10.0
ND
---
ND
12/19/07
---
10.0
5.3 B
ND
9.8
NC2B = 7 pg/L (03/28/08)
07/08/08
---
10.0
1.7 J
4.20 J
ND
12/17/08
0.3
10.0
1.40 J
1.50 J
ND
07/09/09
0.3
10.0
ND
ND
ND
12/16/09
0.3
10.0
1.90 J
2.00 J
ND
06/24/10
0.3
10.0
ND
3.10 J
ND
12/13/10
0.3
10.0
0.31 B
ND
0.49 J
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
5.50 J
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
---
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
10.0
2.90 J
3.40 J
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
ND
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
NC2B = Hardness Dependant
02/05/18
EPA 6010
2.5
10.0
3.8 J
3.8 J
ND
08/13/18
EPA 6010D
2.5
10.0
4.1 J
ND
ND
02/04/19
EPA 6010D
2.5
5.0
ND
ND
---
08/07/19
EPA 6010D
2.1
5.0
3.2 J
3.3 J
ND
02/12/20
EPA 6010D
2.1
5.0
3.9 J
3.4 J
ND
08/27/20
---
---
Dry
Dry
---
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 3 of 8

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Lead
05/20/98
---
10.0
ND
8.00
---
11/19/98
---
10.0
ND
ND
---
07/21/99
---
10.0
ND
10.0
---
11/16/99
---
10.0
ND
ND
---
05/10/00
---
10.0
ND
ND
---
10/26/00
---
10.0
ND
ND
---
04/18/01
---
10.0
ND
ND
---
10/27/01
---
10.0
ND
ND
---
06/13/02
---
10.0
---
---
---
11/19/02
---
10.0
ND
ND
---
06/27/03
---
10.0
ND
ND
---
12/30/03
---
10.0
ND
ND
ND
06/30/04
---
10.0
ND
ND
ND
12/29/04
---
10.0
ND
ND
ND
06/29/05
---
10.0
ND
ND
ND
12/29/05
---
10.0
ND
ND
ND
06/28/06
---
10.0
ND
ND
ND
12/29/06
---
10.0
ND
ND
ND
07/12/07
---
10.0
ND
---
ND
12/19/07
---
10.0
ND
ND
ND
NC2B = 25 pg/L (03/28/08)
07/08/08
---
10.0
ND
ND
ND
12/17/08
4.0
10.0
ND
ND
ND
07/09/09
4.0
10.0
ND
ND
ND
12/16/09
4.0
10.0
ND
ND
ND
06/24/10
4.0
10.0
ND
ND
ND
12/13/10
4.0
10.0
ND
ND
ND
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
ND
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
---
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
10.0
ND
ND
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
ND
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
NC2B = Hardness Dependant
02/05/18
EPA 6010
2.5
10.0
ND
ND
ND
08/13/18
EPA 6010D
2.5
10.0
ND
ND
ND
02/04/19
EPA 6010D
2.5
5.0
ND
ND
---
08/07/19
EPA 6010D
1.6
5.0
2.2 J
ND
ND
02/12/20
EPA 6010D
1.6
5.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
Nickel
12/29/04
---
50.0
ND
50.0 (ND)
ND
06/29/05
---
50.0
ND
ND
ND
12/29/05
---
50.0
ND
ND
ND
06/28/06
---
50.0
ND
ND
ND
12/29/06
---
50.0
ND
2.9 J
ND
07/12/07
---
50.0
3.8 J
---
ND
12/19/07
---
50.0
6.0
31.5
ND
NC2B = 25 pg/L (03/28/08)
07/08/08
---
50.0
3.2 J
29.8 J
ND
12/17/08
1.7
50.0
2.4 B
4.0 B
2.4 J
07/09/09
1.7
50.0
4.1 J
12.3 J
ND
12/16/09
1.7
50.0
3.8 B
4.4 B
3.0 J
06/24/10
1.7
50.0
ND
2.0 J
ND
12/13/10
1.7
50.0
ND
14.2 J
2.7 J
06/20/11
5.0
50.0
ND
7.8 J
ND
12/05/11
5.0
50.0
ND
5.3 J
ND
06/11/12
5.0
50.0
ND
11.0 J
ND
12/12/12
5.0
50.0
ND
13.8 J
ND
05/01/13
5.0
50.0
ND
ND
ND
08/05/13
5.0
50.0
ND
5.6 J
ND
02/24/14
5.0
50.0
ND
ND
ND
08/12/14
EPA 6010
5.0
50.0
---
20.3 J
ND
03/10/15
EPA 6010
2.5
50.0
3.0 J
3.8 J
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
50.0
2.9 J
4.7 J
ND
08/09/16
EPA 6010
2.5
50.0
3.3 J
15.2 J
ND
02/13/17
EPA 6010
2.5
50.0
ND
7.3 J
ND
08/22/17
EPA 6010
2.5
50.0
ND
16.3 J
ND
NC2B = Hardness Dependant
02/05/18
EPA 6010
2.5
50.0
5.3 J
4.4 J
ND
08/13/18
EPA 6010D
2.5
50.0
7.3 J
12.4 J
ND
02/04/19
EPA 6010D
2.5
5.0
ND
2.7 J
---
08/07/19
EPA 6010D
0.90
5.0
8.8
14.8
ND
02/12/20
EPA 6010D
0.90
5.0
3.1 J
4.6 J
ND
08/27/20
---
---
Dry
Dry
---
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 4 of 8

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Silver
07/12/07
---
10.0
2.20 J
---
ND
12/19/07
---
10.0
ND
0.34 J
ND
NC2B = 0.06 pg/L (03/28/08)
07/08/08
---
10.0
0.35 B
1.00 J
0.12 J
12/17/08
0.1
10.0
ND
ND
ND
07/09/09
0.1
10.0
ND
0.10 J
ND
12/16/09
0.1
10.0
ND
0.16 J
ND
06/24/10
0.1
10.0
ND
0.26 J
ND
12/13/10
0.1
10.0
(ND}
10.281 B
0.21(0.19 J) J
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
ND
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
---
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
10.0
ND
ND
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
ND
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
NC2B = Hardness Dependant
02/05/18
EPA 6010
2.5
10.0
ND
ND
ND
08/13/18
EPA 6010D
2.5
10.0
ND
ND
ND
02/04/19
EPA 6010D
2.5
5.0
ND
ND
---
08/07/19
EPA 6010D
2.5
5.0
ND
ND
ND
02/12/20
EPA 6010D
2.5
5.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
Thallium
12/29/04
---
10.0
ND
10.0 (ND)
ND
06/29/05
---
10.0
ND
ND
ND
12/29/05
---
10.0
ND
ND
ND
06/28/06
---
10.0
ND
ND
ND
12/29/06
---
6.00
ND
ND
ND
07/12/07
---
5.5
ND
---
ND
12/19/07
---
5.5
3.60 J
ND
ND
07/08/08
---
5.5
3.40 J
ND
ND
12/17/08
3.0
5.5
ND
ND
ND
07/09/09
3.0
5.5
ND
ND
ND
12/16/09
3.0
5.5
ND
ND
ND
NC2B = NE (03/24/10)
06/24/10
3.0
5.5
ND
ND
ND
12/13/10
3.0
5.5
3.80 J
ND
ND
06/20/11
5.4
5.5
ND
ND
ND
12/05/11
5.4
5.5
ND
ND
ND
06/11/12
5.4
5.5
ND
ND
ND
12/12/12
5.4
5.5
ND
ND
ND
05/01/13
5.4
5.5
ND
ND
ND
08/05/13
5.4
5.5
ND
ND
ND
02/24/14
5.4
5.5
ND
ND
ND
08/12/14
EPA 6010
5.4
5.5
---
ND
ND
03/10/15
EPA 6010
5.0
5.5
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
5.0
5.5
ND
ND
ND
08/09/16
EPA 6010
5.0
5.5
ND
ND
ND
02/13/17
EPA 6020B
0.020
5.5
ND
ND
ND
08/22/17
EPA 6020B
0.020
5.5
ND
ND
ND
02/05/18
EPA 6020B
0.028
0.10
ND
ND
ND
08/13/18
EPA 6020B
0.020
5.50
ND
ND
ND
02/04/19
EPA 6020B
0.060
0.10
ND
ND
---
08/07/19
EPA 6020B
0.060
0.10
ND
ND
ND
02/12/20
EPA 6020B
0.060
0.10
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 5 of 8

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Vanadium
12/29/06
---
25.0
1.60 J
2.00 J
ND
07/12/07
---
25.0
4.60 J
---
ND
12/19/07
---
25.0
3.30 J
1.40 B
0.62 J
NC2B = NE pg/L (03/28/08)
07/08/08
---
25.0
5.20 J
2.30 J
0.20 J
12/17/08
0.2
25.0
1.80 B
2.70 B
0.76 J
07/09/09
0.2
25.0
5.00 B
3.40 B
1.30 J
12/16/09
0.2
25.0
3.60 J
3.50 J
0.53 J
06/24/10
0.2
25.0
5.80 J
2.60 J
ND
12/13/10
0.2
25.0
1.60 B
0.67 B
0.36 J
06/20/11
5.0
25.0
ND
ND
ND
12/05/11
5.0
25.0
ND
ND
ND
06/11/12
5.0
25.0
ND
11.50 J
ND
12/12/12
5.0
25.0
ND
ND
ND
05/01/13
5.0
25.0
ND
ND
ND
08/05/13
5.0
25.0
ND
ND
ND
02/24/14
5.0
25.0
ND
ND
ND
08/12/14
EPA 6010
5.0
25.0
---
ND
ND
03/10/15
EPA 6010
2.5
25.0
3.9 J
4.7 J
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
25.0
4.1 J
5.8 J
ND
08/09/16
EPA 6010
2.5
25.0
2.9 J
2.8 J
ND
02/13/17
EPA 6010
2.5
25.0
ND
ND
ND
08/22/17
EPA 6010
2.5
25.0
2.8 J
ND
ND
02/05/18
EPA 6010
2.5
25.0
6.6 J
5.9 J
ND
08/13/18
EPA 6010D
2.5
25.0
8.3 J
3.1 J
ND
02/04/19
EPA 6010D
2.5
5.0
2.9 J
2.7 J
---
08/07/19
EPA 6010D
1.3
5.0
1.4 J
2.3 J
ND
02/12/20
EPA 6010D
1.3
5.0
4.5 J
5.0
ND
08/27/20
---
---
Dry
Dry
---
Zinc
11/22/96
---
50.0
11.0
ND
---
06/17/97
---
50.0
ND
ND
---
12/01/97
---
50.0
20.0
ND
---
05/20/98
---
50.0
20.0
28.0
---
11/19/98
---
50.0
ND
ND
---
07/21/99
---
50.0
ND
ND
---
11/16/99
---
50.0
ND
ND
---
05/10/00
---
50.0
ND
ND
---
10/26/00
---
50.0
ND
ND
---
04/18/01
---
50.0
ND
ND
---
10/27/01
---
50.0
ND
ND
---
06/13/02
---
50.0
---
---
---
11/19/02
---
50.0
ND
ND
---
06/27/03
---
50.0
ND
ND
---
12/30/03
---
50.0
ND
ND
ND
06/30/04
---
50.0
ND
ND
ND
12/29/04
---
50.0
ND
ND
ND
06/29/05
---
50.0
ND
ND
ND
12/29/05
---
50.0
ND
ND
ND
06/28/06
---
50.0
ND
ND
ND
12/29/06
---
50.0
ND
ND
ND
07/12/07
---
10.0
ND
---
ND
12/19/07
---
10.0
24.6 B
ND
102
NC2B = 50 pg/L (03/28/08)
07/08/08
---
10.0
ND
ND
1.20 J
12/17/08
0.4
10.0
ND
0.89 B
0.49 J
07/09/09
0.4
10.0
ND
4.90 B
1.60 J
12/16/09
0.4
10.0
2.60 B
2.60 B
7.70 J
06/24/10
0.4
10.0
ND
14.9
ND
12/13/10
0.4
10.0
ND
9.80 B
6.70 J
06/20/11
10.0
10.0
ND
ND
ND
12/05/11
10.0
10.0
ND
ND
12.4
06/11/12
10.0
10.0
ND
ND
ND
12/12/12
10.0
10.0
ND
ND
ND
05/01/13
10.0
10.0
ND
16.80
ND
08/05/13
10.0
10.0
ND
ND
ND
02/24/14
10.0
10.0
ND
ND
ND
08/12/14
EPA 6010
10.0
10.0
---
ND
ND
03/10/15
EPA 6010
5.0
10.0
7.7 B
7.8 B
5.6 J
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
5.0
10.0
7.0 J
ND
ND
08/09/16
EPA 6010
5.0
10.0
ND
ND
ND
02/13/17
EPA 6010
5.0
10.0
ND
5.2 J
ND
08/22/17
EPA 6010
5.0
10.0
ND
ND
ND
NC2B = Hardness Dependant
02/05/18
EPA 6010
5.0
10.0
ND
ND
ND
08/13/18
EPA 6010D
5.0
10.0
6.0 J
ND
ND
02/04/19
EPA 6010D
5.0
10.0
ND
ND
---
08/07/19
EPA 6010D
3.9
10.0
ND
ND
ND
02/12/20
EPA 6010D
3.9
10.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
Hardness, Total(SM 2340B)
02/04/19
EPA 6010D
662
662
57.1
85.3
---
08/07/19
EPA 6010D
131
662
316
460
ND
02/12/20
EPA 6010D
131
662
18300
60200
---
08/27/20
---
---
Dry
Dry
---
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 6 of 8

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
ORGANICS
Acetone
10/27/01
---
100
168.0 B
337.0 B
479.0
06/13/02
---
100
---
---
---
06/13/02
---
100
---
---
---
11/19/02
---
100
ND
ND
---
06/27/03
---
100
ND
ND
---
12/30/03
---
100
ND
ND
ND
06/30/04
---
100
ND
ND
ND
12/29/04
---
100
ND
ND
ND
06/29/05
---
100
ND
ND
ND
12/29/05
---
100
ND
ND
ND
06/28/06
---
100
ND
ND
ND
12/29/06
---
100
ND
ND
ND
07/12/07
---
100
ND
---
ND
12/19/07
---
100
12.70 B
ND
4.50 J
NC2B = 2,000 pg/L (03/28/08)
07/08/08
---
100
ND
ND
ND
12/17/08
20
100
ND
ND
ND
07/09/09
20
100
ND
ND
ND
NC2B = NE (03/24/10)
12/16/09
2.2
100
ND
ND
2.80 J
06/24/10
2.2
100
2.80 B
ND
7.70 J
12/13/10
2.2
100
ND
3.00 J
ND
06/20/11
2.2
100
ND
3.80 B
3.90 J
12/05/11
2.2
100
ND
7.20 B
8.80 J
06/11/12
2.2
100
ND
5.50 B
4.70 J
12/12/12
10.0
100
ND
ND
ND
05/01/13
10.0
100
ND
ND
14.6 J
08/05/13
10.0
100
ND
ND
ND
02/24/14
10.0
100
ND
ND
25.7 J
08/12/14
EPA 8260
10.0
100
---
ND
22.0 J
03/10/15
EPA 8260
10.0
100
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 8260
10.0
100
ND
ND
ND
08/09/16
EPA 8260
10.0
100
ND
ND
ND
02/13/17
EPA 8260
10.0
100
ND
ND
ND
08/22/17
EPA 8260
10.0
100
ND
ND
ND
02/05/18
EPA 8260
10.0
100
ND
ND
ND
08/13/18
EPA 8260B
10.0
100
ND
ND
ND
02/04/19
EPA 8260B
6.2
25
ND
ND
---
ISTV = 2000 pg/L
08/07/19
EPA 8260D
6.2
25.0
ND
ND
ND
02/12/20
EPA 8260D
6.2
25.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
Chlorobenzene
06/27/03
---
5.0
ND
7.20
ND
12/30/03
---
5.0
ND
ND
ND
06/30/04
---
5.0
ND
ND
ND
12/29/04
---
5.0
ND
ND
ND
06/29/05
---
5.0
ND
ND
ND
12/29/05
---
5.0
ND
ND
ND
06/28/06
---
5.0
ND
ND
ND
12/29/06
---
3.0
ND
ND
ND
07/12/07
---
3.0
ND
---
ND
12/19/07
---
3.0
ND
ND
ND
NC2B = 130 pg/L (03/28/08)
07/08/08
---
3.0
ND
ND
ND
12/17/08
0.23
3.0
ND
ND
ND
07/09/09
0.23
3.0
ND
ND
ND
12/16/09
0.23
3.0
ND
ND
ND
06/24/10
0.23
3.0
ND
ND
ND
12/13/10
0.23
3.0
ND
ND
0.28 J
06/20/11
0.23
3.0
ND
ND
ND
12/05/11
0.23
3.0
ND
ND
ND
06/11/12
0.23
3.0
ND
ND
ND
12/12/12
0.23
3.0
ND
ND
ND
05/01/13
0.23
3.0
ND
ND
ND
08/05/13
0.23
3.0
ND
ND
ND
02/24/14
0.23
3.0
ND
ND
ND
08/12/14
EPA 8260
0.23
3.0
---
ND
ND
03/10/15
EPA 8260
0.23
3.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 8260
0.23
3.0
ND
ND
ND
08/09/16
EPA 8260
0.23
3.0
ND
ND
ND
02/13/17
EPA 8260
0.23
3.0
ND
ND
ND
08/22/17
EPA 8260
0.23
3.0
ND
ND
ND
02/05/18
EPA 8260
0.23
3.0
ND
ND
ND
08/13/18
EPA 8260B
0.23
3.0
ND
ND
ND
02/04/19
EPA 8260B
0.23
1.0
ND
ND
---
08/07/19
EPA 8260D
0.23
1.0
ND
ND
ND
02/12/20
EPA 8260D
0.23
1.0
ND
ND
ND
08/27/20
--
--
Dry
Dry
---
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 7 of 8

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Chloromethane
07/09/09
0.11
1.0
ND
0.19 J
ND
12/16/09
0.11
1.0
ND
ND
ND
NC213 = NE (03/24/10)
06/24/10
0.11
1.0
ND
ND
ND
12/13/10
0.11
1.0
ND
ND
ND
06/20/11
0.11
1.0
ND
ND
ND
12/05/11
0.11
1.0
ND
ND
ND
06/11/12
0.11
1.0
ND
ND
ND
12/12/12
0.11
1.0
ND
ND
ND
05/01/13
0.11
1.0
ND
ND
ND
08/05/13
0.11
1.0
ND
ND
ND
02/24/14
0.11
1.0
ND
ND
0.25 J
08/12/14
EPA 8260
0.11
1.0
---
ND
ND
03/10/15
EPA 8260
0.11
1.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 8260
0.11
1.0
ND
ND
ND
08/09/16
EPA 8260
0.11
1.0
ND
ND
ND
02/13/17
EPA 8260
0.11
1.0
0.17 J
0.19 J
0.18 J
08/22/17
EPA 8260
0.11
1.0
ND
ND
ND
02/05/18
EPA 8260
0.11
1.0
ND
ND
ND
08/13/18
EPA 8260B
0.11
1.0
ND
ND
ND
02/04/19
EPA 8260B
0.39
1.0
ND
ND
---
08/07/19
EPA 8260D
0.39
1.0
ND
ND
ND
02/12/20
EPA 8260D
0.39
1.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
1,4-Dioxane (p-Dioxane)
08/13/18
EPA 8260B Mod.
1.9
2.0
ND
14.1
ND
02/04/19
EPA 8260B Mod.
1.9
2.0
ND
ND
---
ISTV = 80 pg/L
08/07/19
EPA 8260D Mod.
1.2
2.0
10.50
22.3
ND
02/12/20
EPA 8260D Mod.
1.2
2.0
ND
1.2 J
ND
08/27/20
---
---
Dry
Dry
---
Methylene Chloride
08/09/16
EPA 8260
0.97
1.0
ND
ND
2.20 J
02/13/17
EPA 8260
0.97
1.0
ND
ND
ND
NC 2L = 5 pg/L (2/5/10)
08/22/17
EPA 8260
0.97
1.0
ND
ND
1.4 C9
02/05/18
EPA 8260
0.97
1.0
ND
ND
ND
08/13/18
EPA 8260B
0.97
1.0
ND
ND
6.60
02/04/19
EPA 8260B
3.7
5.0
ND
ND
---
ISTV = 11,000 pg/L
08/07/19
EPA 8260D
3.7
5.0
ND
ND
ND
02/12/20
EPA 8260D
3.7
5.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
Notes:
All concentrations are in micrograms per liter (pg/L)
RL = Reporting Limit (SWSL for December 2006 - present).
DL = Laboratory detection limit.
J = Estimated value between the DL and the RL.
B = Blank -qualified data; result is expected to be biased high based on concentrations in the blanks
ND = Not detected above laboratory reporting limit,
NS = Not sampled.
NR = Not Reported.
Dry =Surface water point considered to be dry.
NC213 = North Carolina Surface Water Standards from 15A NCAC 213.0101
ISTV = NC In -stream Target Values (for constituents with no NC213)
NE = Not established.
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 8 of 8

Appendix G
Historical Monitored Natural Attenuation Parameters

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL RL
MW-1R
MW-2R MW-3R MW-4 MW-5 MW-6
NES-1
Temperature
12/30/03
°C
15.4
11.1 11.2 12.5 13.6 14.2
-
(FP)
12/19/07
°C
12.3
12.5 13.1 14.4 14.9 14.4
13.3
05/01/13
°C
15.7
13.7 15.1 14.4 14.2 14.2
12.5
08/14/14
°C
17.8
18.0 19.2 19.4 16.8 17.2
16.0
03/10/15
°C
17.3
16.0 15.9 13.8 13.3 13.7
16.1
08/18/15
°C
16.43
17.78 17.79 17.25 16.47 16.64
16.05
02/16/16
°C
14.6
13.8 14.4 14.0 12.0 13.4
13.1
08/09/16
°C
16.4
17.3 19.4 18.2 17.1 16.8
17.9
02/13/17
°C
14.8
14.4 14.9 15.7 14.1 15.3
15.2
08/22/17
°C
17.4
17.9 17.9 17.5 17.4 16.6
17.8
02/05/18
°C
13.06
11.66 13.05 14.46 13.83 14.53
12.25
08/13/18
°C
17.4
21.1 18.2 19.3 20.6 18.4
16.6
02/04/19
°C
13.2
15.5 16.5 14.9 14.5 15.4
13.7
08/06/19
°C
17.0
22.7 17.6 19.9 17.3 18.2
16.0
Resample ->
08/14/19
°C
-
- - - - 24.3
-
02/12/20
°C
17.2
14.3 14.8 16.5 15.1 16.4
14.8
08/27/20
°C
17.2
18.9 19.9 22.2 20.3 21.1
20.1
Resample ->
09/30/20
°C
-
- 19.3 - - -
-
pH
12/30/03
SU
7.31
6.54 6.81 6.90 7.24 7.29
-
(FP)
12/19/07
SU
6.89
6.90 7.07 6.87 7.39 6.67
7.64
05/01/13
SU
7.32
6.37 6.61 6.42 6.92 7.13
6.10
08/14/14
SU
5.84
6.36 6.96 6.79 7.00 6.48
5.59
03/10/15
SU
6.11
6.37 6.56 6.30 6.25 6.55
5.68
08/18/15
SU
5.12
6.68 6.48 6.76 7.03 6.78
4.94
02/16/16
SU
6.15
6.15 6.61 6.69 7.14 6.10
6.52
08/09/16
SU
4.79
5.05 5.30 5.06 4.41 5.75
6.46
02/13/17
SU
6.10
6.55 6.76 6.78 6.24 7.37
6.23
08/22/17
SU
6.58
6.46 6.45 6.98 7.53 7.16
7.16
02/05/18
SU
7.11
6.80 7.01 7.33 7.22 7.54
5.53
08/13/18
SU
6.30
6.45 6.64 6.38 7.15 7.03
5.54
02/04/19
SU
6.17
6.44 7.16 6.87 6.07 7.02
5.13
08/06/19
SU
8.84
6.17 6.49 6.69 7.44 7.49
6.79
Resample ->
08/14/19
SU
-
- - - - 6.47
-
02/12/20
SU
5.63
4.88 6.30 6.73 6.27 7.10
8.72
08/27/20
SU
5.08
6.13 6.42 6.45 6.71 6.73
5.48
Resample ->
09/30/20
SU
-
- 6.57 - - -
-
Conductivity
12/19/07
pS/cm
96
1,964 1,591 1,245 - -
510
(FP)
05/01/13
pS/cm
111
1,587 1,357 1,150 195 594
69.6
08/14/14
pS/cm
231
1,897 1,534 1,413 522 565
172.6
03/10/15
pS/cm
90
996 1,277 1,186 106 504
114
08/18/15
pS/cm
134
1,630 1,680 1,244 617 534
83
02/16/16
pS/cm
72.4
1,611 1,369 1,234 164 474
78.2
08/09/16
pS/cm
100.7
1,924 1,535 1,475 660 600
95.6
02/13/17
pS/cm
68.0
1,535 1,314 1,155 272 508
89.6
08/22/17
pS/cm
77.1
1,752 1,350 1,446 755 560
175
02/05/18
pS/cm
80.0
1,460 1,247 1,230 676 633
50.0
08/13/18
pS/cm
101.2
2,013 1,608 1,569 870 620
131.2
02/04/19
pS/cm
107.9
1,692 1,266 1,364 276.1 546.0
91.6
08/06/19
pS/cm
113.4
1,719 1,307 1,287 775.0 545.3
98.5
Resample ->
08/14/19
pS/cm
-
- - - - 559
-
02/12/20
pS/cm
94.8
1,946 1,475 1,471 276.9 588.3
95.5
08/27/20
pS/cm
82.4
1,601 1,217 1,335 773.0 577.0
140.5
Resample ->
09/30/20
pS/cm
-
- 1,409 - - -
-
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02 Page 1 of 9

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Redox Potential
12/30/03
mV
257.2
76.2
207.6
212.7
187.3
123.6
-
ORP
12/19/07
mV
146
45.0
142
134
-
-
138
(FP)
05/01/13
mV
111.7
-26.7
55.2
120.5
227.1
08/14/14
mV
115.8
-37.2
86.9
-
-
03/10/15
mV
87.0
0.8
56.3
-
96.7
08/18/15
mV
134.7
-96.3
-68.8
-33.9
-49.9
182.8
02/16/16
mV
111.7
-47.3
16.9
173.4
08/09/16
mV
56.0
-43.1
-6.9
-
02/13/17
mV
87.4
0.8
-16.5
-
-
-
08/22/17
mV
102.9
-37.1
87.0
116.7
02/05/18
mV
57.1
29.5
49.4
109.2
08/13/18
mV
117.9
-60.5
-49.3
-
64.4
28.4
02/04/19
mV
197.7
-64.3
132.2
-
9.6
-
281.2
08/06/19
mV
164.7
-69.3
-33.7
171.6
188.6
232.6
231.8
Resample ->
08/14/19
my
-
-
-
-
-
237.6
-
02/12/20
mV
336.5
33.4
22.4
254.5
299.9
282.0
245.6
08/27/20
mV
242.7
-10.8
12.4
190.3
196.5
188.0
240.6
Resample ->
09/30/20
my
-
-
232.3
-
-
-
-
Dissolved Oxygen
12/30/03
mg/L
9.49
4.84
-
-
-
DO
12/19/07
mg/1-
-
1.88
1.44
3.21
0.70
(FP)
05/01/13
mg/1-
4.40
1.37
1.79
4.65
2.90
08/14/14
mg/1-
4.44
3.26
2.48
-
2.80
03/10/15
mg/1-
3.84
1.47
1.80
1.85
08/18/15
mg/1-
4.95
5.75
1.30
3.79
1.77
02/16/16
mg/1-
4.45
3.66
2.51
-
3.72
08/09/16
mg/1-
3.17
2.87
2.29
-
02/13/17
mg/1-
5.37
3.16
2.14
-
08/22/17
mg/1-
5.43
2.24
4.02
5.86
02/05/18
mg/1-
8.08
6.61
9.16
8.36
08/13/18
mg/1-
6.31
3.20
2.35
-
4.80
3.91
02/04/19
mg/1-
1.26
1.82
4.17
4.17
-
1.63
08/06/19
mg/1-
3.77
0.32
0.26
4.55
5.30
2.76
3.04
Resample ->
08/14/19
mg/1-
-
-
-
-
-
1.95
-
02/12/20
mg/1-
5.11
0.65
1.36
4.30
3.48
2.44
6.37
08/27/20
mg/1-
0.63
0.22
0.48
5.04
6.22
4.14
3.16
Resample ->
09/30/20
mg/1-
-
-
2.00
-
-
-
-
Dissolved CO2
12/19/07
mg/1-
25.0
365
175
295
60
(FP)
05/01/13
mg/1-
30.0
245
125
225
45
08/14/14
mg/1-
60.0
390
185
-
75
03/10/15
mg/1-
50.0
110
75
50
08/18/15
mg/1-
30.0
275
125
60
02/16/16
mg/1-
30.0
210
230
20
08/09/16
mg/1-
-
185
210
02/13/17
mg/1-
-
-
-
08/22/17
mg/L
02/05/18
mg/L
08/13/18
mg/1-
-
-
02/04/19
mg/1-
75.0
-
130.0
08/06/19
mg/1-
-
475.0
250.0
02/12/20
mg/1-
260.0
-
08/27/20
mg/1-
-
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02 Page 2 of 9

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5 MW-6
NES-1
Fe, Ferrous (+2)
12/30/03
mg/L
ND
1.5
ND
ND
0.22 ND
-
(FP)
12/19/07
mg/L
ND
7.2
ND
ND
-
0.2
05/01/13
mg/L
ND
1.0
ND
ND
ND
08/14/14
mg/L
ND
2.5
ND
ND
03/10/15
mg/L
ND
5.3
ND
ND
08/18/15
mg/L
ND
4.5
1.0
ND
02/16/16
mg/L
ND
4.0
1.3
ND
08/09/16
mg/L
3.1
1.0
02/13/17
mg/L
ND
3.0
1.5
08/22/17
mg/L
ND
3.5
1.5
ND
02/05/18
mg/L
ND
4.0
0.5
ND
08/13/18
mg/L
ND
5.5
0.2
02/04/19
mg/L
ND
-
ND
08/06/19
mg/L
3.5
0.5
02/12/20
mg/L
1.0
0.5
08/27/20
mg/L
-
4.5
1.0
-
- -
Alkalinity (as CaCO3)
12/30/03
mg/L
9.00
10.0
37.0
800
690
640
68.0 350
-
12/19/07
mg/1-
-
5.00
39.0
763
726
619
- -
190
05/01/13
mg/1-
1.00
5.00
43.4
757
660
645
10.4
08/14/14
mg/1-
1.00
5.00
41.1
784
661
-
14.5
03/10/15
mg/1-
1.00
5.00
38.0
744
653
8.8
08/18/15
mg/1-
1.00
5.00
37.8
772
664
10.3
02/16/16
mg/1-
1.00
5.00
41.2
792
741
8.73
08/09/16
mg/1-
1.00
5.00
-
783
629
-
02/13/17
mg/L
1.00
5.00
37.9
753
654
8.79
08/22/17
mg/L
1.00
5.00
42.4
766
678
10.2
02/05/18
mg/1-
1.00
5.00
44.4
821
752
7.52
08/13/18
mg/1-
1.00
5.00
-
768
722
-
02/04/19
mg/1-
1.00
5.00
62.0
856
638
7.02
08/06/19
mg/1-
5.00
5.00
-
839
754
-
02/02/20
mg/1-
5.00
5.00
-
818
646
08/27/20
mg/1-
5.00
5.00
47.6
909
735
-
Chloride
12/30/03
mg/L
0.200
1.00
3.50
280
170
82.0
13.0 44.0
-
12/19/07
mg/L
-
5.00
ND
13.1
297
89.1
- -
7.90
NC 2L = 250,000 ug/L
05/01/13
mg/L
0.50
1.00
3.54
258
180
123
2.85
(250 mg/L)
08/14/14
mg/L
0.50
1.00
5.53
264
144
-
5.00
03/10/15
mg/L
0.50
1.00
3.80
266
194
4.09
08/18/15
mg/1-
0.50
1.00
4.69
267
178
3.90
02/16/16
mg/1-
0.50
1.00
3.92
274
186
3.24
08/09/16
mg/1-
0.50
1.00
-
269
191
-
02/13/17
mg/1-
0.50
1.00
3.45
309
215
5.09
08/22/17
mg/1-
0.50
1.00
3.73
318
214
5.86
02/05/18
mg/1-
0.50
1.00
3.92
280
205
2.52
08/13/18
mg/1-
0.50
1.00
-
221
165
-
02/04/19
mg/1-
0.50
1.00
3.42
221
147
4.52
08/06/19
mg/1-
2.40
4.00
-
203
154
-
02/12/20
mg/1-
2.40
4.00
-
224
153
-
08/27/20
mg/1-
2.40
4.00
3.84
208
148
5.33
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02 Page 3 of 9

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL RL
MW-1R
MW-2R MW-3R MW-4 MW-5 MW-6
NES-1
Dissolved Hydrogen
05/01/13
nM
0.074 0.60
0.400
0.630 0.610 0.500
0.470
08/14/14
nM
0.13 0.60
1.4
1.6 5.4 -
1.4
03/10/15
nM
0.13 0.60
1.2
1.4 1.4 1.0
1.4
08/18/15
nM
0.13 0.60
1.7
2.2 1.7 -
1.5
02/16/16
nM
0.13 0.60
2.0
1.7 1.9
1.5
08/09/16
nM
0.13 0.60
-
1.5 1.6
-
02/13/17
nM
- -
- -
08/22/17
nM
02/05/18
nM
08/13/18
nM
02/04/19
nM
0.65 1.0
6.7
7.6 7.4
6.8
08/06/19
nM
0.75 1.0
-
2.0 5.4
-
02/12/20
nM
- -
-
5.8 2.7
08/27/20
nM
0.49 0.49
-
1.0 J 1.2 J
-
Resample ->
09/10/20
nM
0.49 1.9
1.8
- -
2.4
Nitrate-N
12/30/03
mg/L
0.020 0.050
0.120
ND ND ND ND 0.13
-
12/19/07
mg/L
- 0.100
ND
ND ND ND -
13.0
05/01/13
mg/L
0.001 10.0
0.163
ND ND ND
3.58
08/14/14
mg/L
0.001 10.0
0.115 J
ND ND
2.02 J
03/10/15
mg/L
0.001 10.0
0.252J
ND ND
2.56J
08/18/15
mg/L
0.001 10.0
0.124 J
ND ND
3.27 J
02/16/16
mg/L
0.001 10.0
0.36 J
ND ND
2.54 J
08/09/16
mg/L
0.001 10.0
-
ND ND
-
02/13/17
mg/L
0.001 10.0
0.248 J
0.189 J ND
2.63 J
08/22/17
mg/1-
0.001 10.0
0.118 J
0.0186 J 0.0451 J
4.06 J
02/05/18
mg/L
0.010 10.0
0.310 J
ND 0.0120 J
1.15 J
08/13/18
mg/L
0.050 0.1
-
ND ND
-
02/04/19
mg/1-
0.050 0.1
0.196
ND 0.113
6.5
08/06/19
mg/L
0.010 0.0
-
ND ND
-
02/12/20
mg/1-
0.010 0.0
-
0.069 0.362
-
08/27/20
mg/L
0.050 0.1
ND
ND ND
6.34
Sulfate
12/30/03
mg/L
0.0600 2.00
ND
ND ND 2.60 9.60 9.00
-
12/19/07
mg/L
- 5.00
ND
ND ND ND - -
36.8
NC 2L = 250,000 Ng/L
05/01/13
mg/L
1.00 250
ND
ND ND 4.69
10.7
(250 mg/L)
08/14/14
mg/L
1.00 250
1.08 J
1.2 J ND -
5.84 J
03/10/15
mg/L
1.00 250
1.52 J
1.13 J 1.52 J
7.04 J
08/18/15
mg/L
1.00 250
1.56 J
1.31 J 2.49 J
524 J
02/16/16
mg/L
1.0 250
1.5 J
1.7 J 1.8 J
10.0 J
08/09/16
mg/1-
1.00 250
-
1.22 J 1.75 J
-
02/13/17
mg/L
1.00 250
1.53 J
1.59 J 1.78 J
11.9 J
08/22/17
mg/L
1.00 250
ND
ND 0.626 J
11.2 J
02/05/18
mg/L
0.500 250
ND
ND 0.627 J
7.48 J
08/13/18
mg/1-
0.500 250
ND
ND 0.630 J
-
02/04/19
mg/1-
0.500 250
1.15
ND 1.10
6.75
08/06/19
mg/1-
0.500 1
-
ND 0.711J
-
02/12/20
mg/L
0.500 1
ND 0.58 J
-
08/27/20
mg/L
0.500 1
ND
ND ND
5.21
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02 Page 4 of 9

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL RL
MW-1R
MW-2R MW-3R MW-4 MW-5 MW-6
NES-1
Sulfide
08/14/14
mg/L
0.05 1.00
ND
ND ND
NO
03/10/15
mg/L
0.05 1.00
ND
ND ND
ND
08/18/15
mg/L
0.05 1.00
ND
ND ND
1.0
02/16/16
mg/L
0.05 1.00
ND
ND ND
ND
08/09/16
mg/L
0.05 1.00
-
ND ND
02/13/17
mg/L
0.05 1.00
ND
ND ND
08/22/17
mg/L
0.05 1.00
ND
ND ND
02/05/18
mg/L
- -
08/13/18
mg/L
- -
02/04/19
mg/L
0.05 1
ND
ND ND
ND
08/06/19
mg/L
0.05 0.1
NO ND
02/12/20
mg/L
0.05 0.1
0.083 J ND
08/27/20
mg/L
0.05 0.1
ND
NO ND -
ND
Total Organic Carbon
12/19/07
mg/L
- 1.0 *
2.9
54.3 23.2 17.2
7.20
05/01/13
mg/1-
0.50 1.00
2.24
29.5 30.0 19.4
5.74
08/14/14
mg/1-
0.50 1.00
ND
229 25.5 -
8.39
03/10/15
mg/1-
0.50 1.00
0.781J
34.8 9.54
1.88
08/18/15
mg/L
0.50 1.00
0.917J
32.9 9.86
27.80
02/16/16
mg/1-
0.50 1.00
1.500
27.6 8.46
40.90
08/09/16
mg/1-
0.50 1.00
-
29.4 9.53
-
02/13/17
mg/1-
0.50 1.00
ND
28.5 9.72
1.36
08/22/17
mg/1-
0.50 1.00
ND
29.1 9.92
1.71
02/05/18
mg/1-
0.50 1.00
ND
25.9 11.4
4.24
08/13/18
mg/L
0.50 1.00
ND
25.8 10.2
NO
02/04/19
mg/1-
0.50 1.00
ND
27.9 8.02
1.6
08/06/19
mg/1-
2.50 5.00
33.3 15.1
-
02/12/20
mg/1-
2.50 5.00
25.4 7.46
-
08/27/20
mg/1-
0.50 1.00
0.689 J
29.8 8.19
0.916 J
Biochemical Oxygen Demand
08/14/14
mg/L
2.00 2.00
ND
83.4 2.49
-
BOD (5-day)
03/10/15
mg/L
2.00 2.00
2.55
10.6 ND
NO
08/18/15
mg/1-
2.00 2.00
2.22
11.8 2.0
2.00
02/16/16
mg/L
2.00 2.00
ND
60.0 6.6
ND
08/09/16
mg/L
2.00 2.00
-
11.6 ND
02/13/17
mg/L
2.00 2.00
NO
9.501 ND
ND
08/22/17
mg/L
2.00 2.00
ND
ND ND
ND
02/05/18
mg/L
2.00 2.00
ND
5.6 ND
ND
08/13/18
mg/L
2.00 2.00
ND
71.8 3.56
ND
02/04/19
mg/L
2.00 2.00
ND
7.5 ND
ND
08/06/19
mg/L
2.00 2.00
8.0 ND
02/12/20
mg/L
2.00 2.00
6.3 ND
08/27/20
mg/L
2.00 2.00
ND
9.45 ND
ND
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02 Page 5 of 9

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5 MW-6
NES-1
Chemical Oxygen Demand
08/14/14
mg/L
12.5
25.0
NO
132.0
NO
50.00
COD
03/10/15
mg/L
12.5
25.0
15.0J
235.0
96.0
ND
08/18/15
mg/1-
12.5
25.0
25.0
110.0
756.0
25.00
02/16/16
mg/L
12.5
25.0
ND
295.0
50.0
ND
08/09/16
mg/1-
12.5
25.0
-
131.0
50.0
-
02/13/17
mg/1-
12.5
25.0
17.0 J
119.0
43.0
22.0 J
08/22/17
mg/1-
12.5
25.0
ND
121.0
74.0
16.0 J
02/05/18
mg/1-
12.5
25.0
ND
113.0
51.0
46.0
08/13/18
mg/L
12.5
25.0
ND
112.0
73.9
ND
02/04/19
mg/L
12.5
25.0
ND
101.0
26.5
ND
08/06/19
mg/1-
12.5
25.0
123.0
45.5
02/12/20
mg/L
12.5
25.0
160.0
36.1
08/27/20
mg/L
12.5
25.0
ND
112.00
35.9
ND
Dissolved Ethane
12/30/03
mg/L
0.0002
0.0010
ND
ND
ND
ND
NO ND
12/19/07
mg/L
-
20.0
ND
ND
ND
ND
ND
05/01/13
mg/L
0.0031
0.0062
ND
ND
ND
ND
ND
08/14/14
mg/L
0.0031
0.0062
ND
ND
0.0036J
ND
03/10/15
mg/L
0.0031
0.0062
ND
ND
ND
ND
08/18/15
mg/L
0.0031
0.0062
0.01
0.01
0.01
0.01
02/16/16
mg/L
0.0031
0.0062
ND
ND
ND
ND
08/09/16
mg/L
0.0031
0.0062
1.6 J
2.6 J
02/13/17
mg/L
-
-
-
-
08/22/17
mg/L
02/05/18
mg/L
08/13/18
mg/L
02/04/19
mg/L
0.001
0.0010
ND
ND
ND
ND
ND ND
ND
08/06/19
mg/L
0.0012
0.0100
ND
2.0 J
.0041 J
ND
02/12/20
mg/L
0.0012
0.0100
ND
0.0026 J
0.0026 J
ND
08/27/20
mg/L
0.001
0.0100
ND
ND
ND
ND
Dissolved Ethene
12/01/03
mg/L
0.0003
0.0010
ND
ND
ND
ND
ND ND
12/19/07
mg/L
-
20.0
ND
ND
ND
ND
ND
05/01/13
mg/L
0.0031
0.0062
ND
ND
0.0017
ND
ND
08/14/14
mg/L
0.0031
0.0062
ND
ND
ND
ND
03/10/15
mg/L
0.0031
0.0062
ND
ND
ND
ND
08/18/15
mg/1-
0.0031
0.0062
0.01
0.01
0.01
0.01
02/16/16
mg/L
0.0031
0.0062
ND
ND
ND
ND
08/09/16
mg/L
0.0031
0.0062
ND
ND
02/13/17
mg/L
-
-
08/22/17
mg/L
02/05/18
mg/L
08/13/18
mg/L
02/04/19
mg/L
0.001
0.001
ND
ND
NO
ND
ND ND
ND
08/06/19
mg/L
0.0012
0.01
ND
ND
.0016 J
ND
02/12/20
mg/L
0.0012
0.01
ND
0.0027 J
NO
ND
08/27/20
mg/L
0.001
0.01
NO
ND
NO
ND
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02 Page 6 of 9

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL RL
MW-1R
MW-2R MW-3R MW-4 MW-5 MW-6
NES-1
Dissolved Methane
12/30/03
mg/L
0.0002 0.0010
ND
0.660 0.130 0.0099 0.0010 ND
12/19/07
mg/L
- 10.0
ND
0.116 0.186 ND -
ND
05/01/13
mg/L
0.0033 0.0066
ND
0.0379 0.100 0.0337
ND
08/14/14
mg/L
0.0033 0.0066
ND
1.29 0.284 -
ND
03/10/15
mg/L
0.0033 0.0066
0.0072
0.996 0.158
ND
08/18/15
mg/L
0.0033 0.0066
0.0027
2.16 0.316
0.0013
02/16/16
mg/L
0.0033 0.0066
0.007 J
0.87 0.098
0.0016 J
08/09/16
mg/L
0.0033 0.0066
-
1.85 0.206
-
02/13/17
mg/L
- -
- -
08/22/17
mg/L
02/05/18
mg/L
08/13/18
mg/L
02/04/19
mg/L
0.001 0.0010
ND
27.2 ND ND ND ND
ND
08/06/19
mg/L
0.0034 0.0100
ND
5.0 0.486
ND
02/12/20
mg/L
0.0034 0.0100
ND
4.5 0.376
ND
08/27/20
mg/L
0.0034 0.0100
ND
6.0 0.497
ND
Pyruvic Acid
12/19/07
mg/L
- -
2.50
ND 1.50 2.00
1.20
05/01/13
mg/L
2 10
ND
ND ND ND
ND
08/14/14
mg/L
0.77 10
ND
ND ND
ND
03/10/15
mg/L
0.77 10
0.41J
0.41J 0.41J
0.41J
08/18/15
mg/L
0.77 10
ND
ND ND
ND
02/16/16
mg/L
0.77 10
ND
ND ND
ND
08/09/16
mg/L
0.77 10
ND ND
02/13/17
mg/L
- -
08/22/17
mg/L
02/05/18
mg/L
08/13/18
mg/L
02/04/19
mg/L
08/06/19
mg/L
ND
ND ND
ND
02/12/20
mg/L
08/27/20
mg/L
0.06 0.06
ND
ND ND -
ND
Lactic Acid
12/19/07
mg/L
ND
5.40 11.9 3.10
ND
05/01/13
mg/L
2.3 25
ND
ND ND ND
ND
08/14/14
mg/L
2.5 25
4.2 J
ND ND
ND
03/10/15
mg/L
2.5 25
ND
ND ND
ND
08/18/15
mg/L
2.5 25
ND
ND ND
ND
02/16/16
mg/L
2.5 25
ND
ND ND
ND
08/09/16
mg/L
2.5 25
ND ND
02/13/17
mg/L
- -
08/22/17
mg/L
02/05/18
mg/L
08/13/18
mg/L
02/04/19
mg/L
08/06/19
mg/L
0.043 0.20
ND
ND 0.087 J
ND
02/12/20
mg/L
- -
-
08/27/20
mg/L
0.053 0.053
ND
ND ND
ND
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02 Page 7 of 9

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL RL
MW-1R
MW-2R MW-3R MW-4 MW-5 MW-6
NES-1
Acetic Acid
12/19/07
mg/L
ND
ND ND ND
ND
05/01/13
mg/L
1.8 5
ND
ND ND ND
ND
08/14/14
mg/L
0.81 5.0
ND
ND ND
ND
03/10/15
mg/L
0.81 5.0
ND
ND ND
ND
08/18/15
mg/L
0.81 5.0
ND
ND 0.97 J
ND
02/16/16
mg/L
0.81 5.0
ND
ND ND
ND
08/09/16
mg/L
0.81 5.0
ND ND
02/13/17
mg/L
- -
08/22/17
mg/L
02/05/18
mg/L
08/13/18
mg/L
02/04/19
mg/L
08/06/19
mg/L
0.028 0.10
ND
0.097 J 0.34
ND
02/12/20
mg/L
- -
-
- -
-
08/27/20
mg/L
0.12 0.12
0.530
4.7 J 0.53 -
0.56
Propionic Acid
12/19/07
mg/L
ND
63.7 38.3 12.8
ND
05/01/13
mg/L
1 5
ND
ND ND ND
ND
08/14/14
mg/L
0.66 5.0
ND
ND ND
ND
03/10/15
mg/L
0.66 5.0
ND
ND ND
ND
08/18/15
mg/L
0.66 5.0
ND
ND ND
ND
02/16/16
mg/L
0.66 5.0
ND
ND ND
ND
08/09/16
mg/L
0.66 5.0
ND ND
08/22/17
mg/L
- -
02/13/17
mg/L
08/22/17
mg/L
02/05/18
mg/L
08/13/18
mg/L
02/04/19
mg/L
08/06/19
mg/1-
0.004 0.10
0.0058 J 0.0045 J
02/12/20
mg/L
- -
-
08/27/20
mg/L
0.053 0.053
ND
ND ND
ND
Butyric Acid
12/19/07
mg/L
ND
ND ND ND
ND
05/01/13
mg/L
0.87 5
ND
ND ND ND
ND
08/14/14
mg/L
0.70 5.0
ND
ND ND
ND
03/10/15
mg/L
0.70 5.0
ND
ND ND
ND
08/18/15
mg/L
0.70 5.0
ND
ND ND
ND
02/16/16
mg/L
0.70 5.0
ND
ND ND
ND
08/09/16
mg/L
0.70 5.0
ND ND
02/13/17
mg/L
- -
08/22/17
mg/L
02/05/18
mg/L
08/13/18
mg/L
02/04/19
mg/L
08/06/19
mg/1-
0.011 0.10
0.22 ND
02/12/20
mg/L
- -
-
08/27/20
mg/L
0.058 0.058
ND
ND 0.066 J
ND
Formic Acid
08/06/19
mg/L
0.086 0.50
1.10 1.60
02/12/20
mg/L
- -
-
-
08/27/20
mg/1-
0.055 0.055
4.9
45.0 4.8
5.1
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02 Page 8 of 9

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL RL
MW-1R
MW-2R MW-3R MW-4 MW-5 MW-6
NES-1
Total Volatile Fatty Acids
12/19/07
mg/L
2.50
69.10 51.70 17.90
1.20
(sum of above 6 acids)
05/01/13
mg/L
ND
ND ND
ND
08/14/14
mg/L
4.2 J
ND ND -
ND
03/10/15
mg/L
ND
ND ND
ND
08/18/15
mg/L
ND
ND 0.97 J
ND
02/16/16
mg/L
ND
ND ND
ND
08/09/16
mg/L
ND ND
02/13/17
mg/L
08/22/17
mg/L
02/05/18
mg/L
08/13/18
mg/L
02/04/19
mg/L
- -
08/06/19
mg/L
1.32 1.94
02/12/20
mg/L
-
-
08/27/20
mg/L
5.43
49.70 5.40
5.66
NOTES:
DL = laboratory detection limit.
mg/L = milligrams per liter
RL = laboratory reporting limit.
my = millivolt
ND = not detected above detection limit.
SU = standard unit
J = estimated concentration between the DL and the RL.
nM = nano -Molar
= not analyzed or not applicable.
°C = degress Celcius
pS/cm = micro-Siemen per centimeter
ntu = nephelometric turbidity units
Butner Landfill, Granville Co.
Permit No. 39-02 Page 9 of 9
La Bella Associates

Appendix H
Phytoremediation Tree inspection Log

LaBeRa
Powered by partnership.
Phytoremediation Tree and Flora Inspection Log
SITE: Butner Landfill, Granville County, NC DATE:
Personnel: 12-0n H
Weather Conditions: KarTc_,l G 1 (3U oy — D (L
�
Description of Area: ece-o�ousL--� L-0 G�e�
Has the ground surface been disturbed by rutting, erosion, tire tracks, settlement etc.?
Are there any indications of vandalism or trespassing:
Is there any ponded water in the area?
KL
Has there been any change in the number of live/dead trees in the area since the last inspection?
�O
Do any trees exhibit signs of disease, damage, or distress (discolored leaves, damaged bark, broken limbs, etc.)?
1Y111UI �, - fV��S�y Fr'� �UerL�{ w2i Qre� (ve--6r Sk�aoe,- 7-CaJQ
Are there any signs of unusual animal/insect damage to the trees?
r;�
Has there been any, change in the type, amount or health of undergrowth or ground cover flora?
lV V
Has there been any ch^^anrrge in the observed wetlands (size, maturity, health) in the area?
Iv()
Pleace describe the nrevalent tree snecies and aive anaroximate oercentaaes in the area:
SPECIES or COMMON NAME
%
AVERAGE MATURITY
AVERAGE HEALTH
bvn--)
s
voonL-
o l , P PO PLC
(�Tore-
o
PU--
s
- M is L
S
COMMENTS:
Fire,)- >�AS n]o.r C�hA+J6e o 16c, �}(P, IN ��-�P�P1�Jon
f G\f) (--.rn,,j,AG i a.AjoP,4 Kos �r�e� (01V1 -,•Vv,e- 0 r'yV-1rTL.�r"-2
Signature of Inspector:

Appendix 1
BIOSCREEN Input and Output

BIOSCREEN Natural Attenuation Decision Support System Bu rn!! LF Data Input Instructions:
BUTNER LANDFILL GRANVILLE COUNTY, NORTH CAROLINA VERSION 1.4 IP1.0 115 1. Enter value directiv.... or
Run Name Tor 2. Calculate by fillinq in prey
1. HYDROGEOLOGY 5. GENERAL 0.02 cells below. (To restore
Seepage Velocity* Vs 6.4 (ft/yr) Modeled Area Length* 500 (ft) t L formulas, hit button below).
or nr Modeled Area Width* 800 1 (ft) W jj� Variable* - Data used directly in model.
Hydraulic Conductivity K 6.2E-02 (cm/sec) Simulation Time* 22 (yr) Value calculated by model.
Hydraulic Gradient i 0.0513 (ft/ft) (Don't enter any data).
Porosity n 0.18 (-) 6. SOURCE DATA
Source Thickness in Sat.Zone* 14 (ft) Vertical Plane Source. Look at Plume Cross -Section
2. DISPERSION Source Zones: and Input Concentrations & Widths
Longitudinal Dispersivity* alpha x 15.0 (ft) Width* ft onc. m /L * for Zones 1, 2, and 3
Transverse Dispersivity* alpha y 1.5 (ft) 125 0.00100
Vertical Dispersivity* alpha z 0.0 (ft) 150 0.00200
or 'r or 150 0.00500 v © ® ® ® ® ® ® m
Estimated Plume Length Lp 350 (ft) 150 0.00200
125 0.00100
3. ADSORPTION Source a i e see Help):_ __7 Factor* R 1.0 20 >1000(yr) View of Plume Looking Down
or or Inst. React. 1 st Order
Soil Bulk Density rho 1.7 (kg/1) Soluble Mass 80 (Kg) Observed Centerline Concentrations at Monitoring Wells
Partition Coefficient Koc 38 (Ukg) In Source NAPL, Soil If No Data Leave Blank or Enter "0"
Fraction Organ icCarbon foc 5.7E-5 (-) 7. FIELD DATA FOR COMPARISON
Concentration (mg/L)l 0.0050 1 1 10.001910.0000 0.00001
4. BIODEGRADATION Dist. from Source (ft) 0 50 1 100 1 140 200 1 250 1 300 1 350 1 400
1 st Order Decay Coeff* lambda 1.0E-2 (per yr)
or T nr 8. CHOOSE TYPE OF OUTPUT TO SEE:
Solute Half -Life t-half 0.15 (year)
or Instantaneous Reaction Model RUN Help Recalculate This
Delta Oxygen* DO 0.22 (mg/L) CENTERLINE RUN ARRAY
Delta Nitrate* NO3 0.05 (mg/L) Paste Example Dataset
Observed Ferrous Iron* Fe2+ 4.5 (mg/L) View Output View Output
Delta Sulfate* SO4 0.5 (mg/L) Restore Formulas for Vs,
Observed Methane* CH4 6.0 (mg/L)

DISSOLVED HYDROCARBON CONCENTRATION ALONG PLUME CENTERLINE (mg/L at Z--0)
Distance from Source (ft) in
100
150
200
250
300
40
450
500
No Degradation 0.005 0.005
0.004
0.002
0.001
0.000
0.000
0.000
0.000
0.000
0.000
1st Order Decay
0.005 0.004
0.003
0.002
0.001
0.000
0.000
0.000
0.000
0.000
0.000
Inst. Reaction
0.000 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Field Data from Site
11 0.00500
1
1 0.00190
-6- 1 st Order Decay JJW Instantaneous Reaction f No Degradation o Field Data from Site
200 300
Distance From Sou
Time:
22 Years

Transverse DISSOLVED HYDROCARBON CONCENTRATIONS IN PLUME (mg/L at Z--0)
Distance (ft) MA Distance from Source (ft)
0 M 50
100
150
200
250
300
350
400
450
500
400
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
200
0.002
0.002
0.001
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0.005
0.004
0.003
0.002
0.001
0.000
0.000
0.000
0.000
0.000
0.000
-200
0.002
0.002
0.001
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-400
0.001
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
MASS
2.0E+0
1.9E+0
1.4E+0
8.2E-1
3.2E-1
7.7E-2
1.1 E-2
9.4E-4
4.5E-5
1.2E-6
1.8E-8
FLUX
FL day)
Time: 22 Years
7 Target Level: 0.005 mg/L * Displayed Model: 1st Order Decay
0.005
0.005
J 0.004
Im 0.004
0.003
_
0.003
R
0.002
P; 0.002
_
C 0.001
U
0.001
0.00(
Plot All Dald
Plot Data > Target ~
(ft)
.sou 400 '•,•,
450
400
Plume and Source Masses
Model to Display: 19
No Degradation
1 st Order Decay
Instantaneous
Plume Mass if No Biodegradation 0.0 661
(Kg)
- Actual Plume Mass 0. 1146
(Kg)
= Plume Mass Removed by Biodeg 0.0016
(Kg)
(10 %)
Change in Electron Acceptor/Byproduct Masses:
ygen Nitrate Iron ll Sulfate Methane
na
na
na
na
I na
(Ka)
Contam. Mass in Source (t=0 Years) 80.5 (Kg)
Contam. Mass in Source Now (t=22Years) 80.5 1 (Kg)
Current Volume of Groundwater in Plume 0.000 (ac-ft)
Flowrate of Water Through Source Zonel 0.260 1 (ac-ft/yr)
Mass HELP
Recalculate