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HomeMy WebLinkAbout19067_Gateway Plaza_VIR_20190828Mid Atlantic Engineering & Environmental Solutions August 28, 2019 Mr. Henry Ward c/o Elixir Retail Partners, LLC Loden Properties 1207 Front Street, Suite 100 Raleigh, North Carolina 27609 Subject: SUB -SLAB AND INDOOR AIR ASSESSMENT REPORT GATEWAY PLAZA 2427 CRABTREE BOULEVARD RALEIGH, NORTH CAROLINA MID -ATLANTIC JOB NO. OOOR2667.01 Dear Mr. Ward: 409 Rogers View Court Raleigh, NC 27610 office 919.250.9918 facsimile 919.250.9950 MAAONLINE.COM We are pleased to present this Sub -Slab and Indoor Air Assessment Report for the above - referenced site. We appreciate the opportunity to provide Loden Properties and Elixir Retail Partners, LLC with environmental services. Please contact me at 919-250-9918 if any questions arise or if we may be of further service. Sincerely, MID -ATLANTIC ASSOCIATES, INC. 4. Q 4e� Katie Lippard Senior Project Manager Darin McClure, P.E. Principal Engineer — EXPERIENCED CUSTOMER FOCUSED INNOVATIVE SUB -SLAB AND INDOOR AIR ASSESSMENT REPORT GATEWAY PLAZA 2427 CRABTREE BOULEVARD RALEIGH, NORTH CAROLINA Prepared For: Mr. Henry Ward c/o Elixir Retail Partners, LLC Loden Properties 1207 Front Street, Suite 100 Raleigh, North Carolina 27609 Prepared By: Mid -Atlantic Associates, Inc. 409 Rogers View Court Raleigh, North Carolina 27610 Mid -Atlantic Job No. OOOR2667.01 August 28, 2019 Mid Atlantic �� Engineering & EnvwonMental SoiuLlOnS 46 Mid Atlantic Engineering & Environmental Solutions 409 Rogers View Court Raleigh, NC 27610 office 919.250.9918 facsimile 919.250.9950 - MAAONLINE.COM SUB -SLAB AND INDOOR AIR ASSESSMENT REPORT GATEWAY PLAZA 2427 CRABTREE BOULEVARD RALEIGH, NORTH CAROLINA BROWNFIELDS PROJECT NUMBER 19067-15-092 Mid -Atlantic Associates Job No. OOOR2667.01 Prepared For: Mr. Henry Ward c/o Elixir Retail Partners, LLC Loden Properties 1207 Front Street, Suite 100 Raleigh, North Carolina 27609 August 28, 2019 Prepared By: MID -ATLANTIC ASSOCIATES, INC. Ruth Tull. Staff Scientist Katie Lippard SeniorEraiect Ma Darin McClure, P.E. Principal Engineer CAS( j EXPERIENCED CUSTOMER FOCUSED INNOVATIVE TABLE OF CONTENTS 1.0 GENERAL INFORMATION.................................................................................................1 1.1 Introduction.......................................................................................................................1 1.2 Laboratory.........................................................................................................................1 2.0 SUMMARY OF FIELD ACTIVITIES....................................................................................1 2.1 Soil Gas Sample Collection...............................................................................................2 2.1.1 Vapor Pin Installation Procedures...............................................................................2 2.1.2 Helium Leak Check Procedures.................................................................................2 2.1.3 Sample Collection Procedures....................................................................................2 2.2 Indoor Air Sample Collection.............................................................................................3 3.0 SUMMARY OF LABORATORY ANALYTICAL RESULTS.................................................3 3.1 Soil Gas Sampling Results................................................................................................3 3.2 Indoor Air Sampling Results..............................................................................................3 3.3 Risk Calculations...............................................................................................................4 4.0 QUALITY ASSURANCE......................................................................................................7 5.0 CONCLUSIONS...................................................................................................................7 DRAWINGS Drawing 1 Topographic Site Map Drawing 2 Sub -Slab Sample Location Map Drawing 3 Indoor Air Sample Location Map TABLES Table 3.1 Summary of Sub -Slab Soil Gas Sample Analysis Table 3.2 Summary of Indoor and Ambient Air Sample Analysis APPENDICES Appendix A Photographic log of sample locations Appendix B Laboratory Analytical Report and Chain -of -Custody Record for Sub -Slab Soil Gas Samples Appendix C Laboratory Analytical Report and Chain -of -Custody Record for Indoor Air Samples Appendix D Sub -Slab Soil Gas Vapor Intrusion Non -Residential Risk Calculations Appendix E Sub -Slab Soil Gas Vapor Intrusion Residential Risk Calculations Appendix F Indoor Air Non -Residential Risk Calculations Appendix G Indoor Air Residential Risk Calculations Appendix H Adjusted Indoor Air Non -Residential Risk Calculations Appendix I Adjusted Indoor Air Residential Risk Calculations IN Mid Atlantic 1.0 GENERAL INFORMATION 1.1 Introduction The subject site consists of approximately 6.77-acres and is located at 2427 Crabtree Boulevard in Raleigh, North Carolina (Drawing 1). The subject site is currently undergoing parking lot upgrades and the renovating and re -tenanting of some spaces. As part of this process, Elixir Retail Partners, LLC has identified a potential drop off day care as a tenant in Space 1 — Little Makers Academy, depicted on Drawings 2 and 3. During a recent site meeting with the Brownfields Program, it was determined that this use may be approved if data shows that vapor intrusion is not a concern in and around the proposed space. This Sub -Slab and Indoor Air Assessment Report is designed to fill gaps in assessment data at the subject site identified by the Brownfields Program. This report details the additional sub -slab and indoor air sampling activities conducted at the site in June and July 2019. The opinions included herein are based on our experience and the information obtained during the study. This report is based on limited observations made on the dates noted using the procedures described herein. If additional information becomes available, we request the opportunity to review the information, reassess the potential environmental concerns and modify our conclusions and recommendations, if appropriate. 1.2 Laboratory Con -Test Analytical Laboratories 39 Spruce Street East Longmeadow, Massachusetts 01028 (413) 525-2332 N.C. Certification No. 652 Contact: Ms. Kerry McGee 2.0 SUMMARY OF FIELD ACTIVITIES The scope of work conducted as part of this vapor assessment was conducted in accordance with the June 20, 2019 Sub -slab and Indoor Air Assessment Work Plan prepared by Mid -Atlantic and approved by the North Carolina Department of Environmental Quality (NCDEQ) Brownfields Program. On June 28, 2019, Mid -Atlantic mobilized to the site to collect six primary sub -slab soil gas samples and one duplicate sample. Mid -Atlantic returned to the subject site on July 24, 2019 to collect four primary indoor air samples and one duplicate sample. Field observations during both sampling events note the spaces as nearly finished with walls erected, doors and windows installed and closed, and HVAC units functional and in operation. The floors were noted to be concrete slab and finishing products had not been applied to the walls or floors at the time of sampling. A photograph log depicting the Mid Atlantic Sub -Slab and Indoor Air Assessment Report Gateway Plaza Raleigh, North Carolina Brownfield Project Number 19067-15-092 August 28, 2019 Page 2 conditions of the spaces during sampling can be found in Appendix A. The sample locations are shown on Drawings 2 and 3. 2.1 Soil Gas Sample Collection A total of six interior sub -slab soil gas sampling points (SS-1 through SS-6) were installed at the site to evaluate potential vapor encroachment conditions inside the spaces. The approximate sample locations are shown on Drawing 2 and discussed below. 2.1.1 Vapor Pin Installation Procedures Six sub -slab borings (SS-1 through SS-6) were advanced inside the onsite building in the anticipated locations of Little Makers Academy (Space 1), Azure Violins (Space 2), and 2409-117 (Space 3) on June 28, 2019, to support the installation of vapor pins and collection of sub -slab soil gas samples at these locations. The samples were collected from the locations specified in the June 20, 2019 Sub -slab and Indoor Air Assessment Work Plan. To create a sub -slab sampling port, a rotary -impact drill equipped with a decontaminated spline drill bit was utilized to drill a 5/8-inch diameter hole through the concrete slab. The concrete slab was approximately four inches thick and did not appear to have a gravel base beneath the slab. Upon completion, a vapor sampling probe was established using a new "Vapor Pin TM" which utilizes a brass barb fitting with a silicone sleeve to create a seal with the concrete when inserted using an installation/extraction tool. The vapor pin was then fitted with'/4-inch outer diameter rigid -wall tubing to complete the vapor sampling probe assembly. Subsequent helium leak check and soil gas sampling activities are discussed below in Sections 2.1.2 and 2.1.3, respectively. 2.1.2 Helium Leak Check Procedures Upon completion of sample point construction activities, the points were purged and a leak checked was performed at each probe location using a plastic shroud, helium gas and a portable helium gas detector. A plastic shroud was placed over the soil gas sampling location with the tubing of the probe exiting the shroud through a small hole. A 3-way valve was placed on the probe termination and connected to the sampling apparatus. Helium was released into the shroud via tubing from the cylinder into the shroud, and a grab sample was collected by filling a Tedlar bag using the exhaust port of the purge syringe. Helium monitoring indicated that there were no leaks detected in either sampling apparatus. 2.1.3 Sample Collection Procedures After performing the helium leak check at each of the interior sub -slab soil gas sample locations, six primary samples and one duplicate sample were collected using 1-liter stainless steel canisters at a maximum flow rate of 100 ml/min. Upon collection, the soil Mid Atlantic Sub -Slab and Indoor Air Assessment Report Gateway Plaza Raleigh, North Carolina Brownfield Project Number 19067-15-092 August 28, 2019 Page 3 gas samples were shipped to Con -Test Analytical Laboratories in East Longmeadow, Massachusetts under proper chain of custody for analysis. The canisters were analyzed in the laboratory for Volatile Organic Compounds (VOCs) according to EPA Method TO- 15. 2.2 Indoor Air Sample Collection Five primary air samples were collected at the subject site: two from Space 1, one from Space 2 , and one from Space 3, and one outdoor ambient air sample. One duplicate sample was also collected from Space 1 for QA/QC purposes. The samples were collected from the locations and heights specified in the June 20, 2019 Sub -slab and Indoor Air Assessment Work Plan. The eight -hour Summa air samples were collected using batch certified, 6-liter, stainless steel, Summa canisters at a maximum flow rate of 8-10 ml/min. The six air samples were analyzed for VOCs using EPA Compendium Method TO-15 with the analyte list limited to the constituents detected in the sub -slab soil gas samples and the degradation products of those compounds. The approximate sample locations are shown on Drawing 3. 3.0 SUMMARY OF LABORATORY ANALYTICAL RESULTS 3.1 Soil Gas Sampling Results The laboratory analytical report and chain -of -custody record for soil gas samples collected in June 2019 are provided in Appendix B and summarized in Table 3.1. The results of the soil gas sampling activities were compared to the February 2018 Division of Waste Management (DWM) Residential and Non -Residential Vapor Intrusion Soil Gas Screening Levels (SGSLs) and a cumulative risk evaluation(s) performed. As summarized, several VOCs were detected in each of the primary sub -slab soil gas samples and the duplicate sub -slab soil gas sample at concentrations above laboratory method detection limits. However, the VOC concentrations did not exceed the DWM Residential or Non -Residential SGSLs. Please note the 1,2-dibromoethane (EDB) and 1,1,2-trichloroethane method detection limits exceeded Residential VISLs for the Sub -Slab sample SS-1. Additional discussion regarding risk calculations for the constituents detected in soil gas is provided below in Section 3.3. 3.2 Indoor Air Sampling Results The laboratory analytical report and chain -of -custody record for indoor air samples collected in July 2019 are provided in Appendix C and summarized in Table 3.2. The results of the indoor air sampling activities were compared to the February 2019 EPA Region 4 Residential and Non -Residential Vapor Intrusion (VI) Indoor Air Screening Levels (IASLs). Mid Atlantic Sub -Slab and Indoor Air Assessment Report Gateway Plaza Raleigh, North Carolina Brownfield Project Number 19067-15-092 August 28, 2019 Page 4 As summarized, naphthalene and ethylbenzene were detected in all indoor air samples exceeding Residential and Non -Residential IASLs. Naphthalene was also detected at a concentration exceeding both the Residential and Non -Residential IASLs in the outdoor Ambient Air Sample (AMB-1). Benzene was detected in indoor air samples IA-1, IA-2 and IA-3, exceeding the Residential IASLs, but did not exceed the Non -Residential IASLs. Xylenes m&p were detected in Indoor Air samples IA-1 through IA-4, exceeding the Residential IASLs. The m&p-xylenes detected in IA-3 also exceeded Non -Residential IASLs. The o-xylenes were detected in Indoor Air Samples IA-1 through IA-3 exceeding Residential IASLs. The constituents ethylbenzene, dichlorodifluoromethane (freon 12), heptane, naphthalene, m&p-xylenes and o-xylenes were each detected in greater concentrations in indoor air samples than observed in the sub -slab soil gas samples. Several other VOCs were detected in each of the primary indoor air samples and the duplicate indoor air sample at concentrations above laboratory method detection limits without exceeding Residential IASLs. Additional discussion regarding risk calculations for the constituents detected in indoor air is provided below in Section 3.3. 3.3 Risk Calculations The DWM establishes vapor intrusion SGSLs for individual compounds for both residential and non-residential (industrial/commercial) exposure scenarios. The EPA Region 4 Residential and Non -Residential IASLs are established for individual compounds detected in both residential and non-residential indoor air exposure scenarios. The North Carolina Brownfields Program allows a maximum cumulative cancer risk for all carcinogens of 1.0E- 4 and a maximum cumulative hazard index (HI) of 1 for all non -carcinogens in soil gas and indoor air'. Mid -Atlantic compared the sub -slab and indoor air sampling results to the DWM Residential and Non -Residential SGSLs and the EPA Residential and Non -Residential IASLs then calculated the cancer risk and non -cancer risk hazard quotient for each compound detected above the laboratory reporting limit. Residential and Non -Residential cumulative cancer risk and cumulative non -cancer hazard indexes were then determined for each Sub -Slab soil gas sample (Appendices D and E). The Residential and Non - Residential exposure cancer risk sums and non -cancer hazard indexes for the Sub -Slab soil gas samples are summarized in the following table: Division of Waste Management Vapor Intrusion Guidance Document. May 2019. Page 2. ft Mid Atlantic Sub -Slab and Indoor Air Assessment Report Gateway Plaza Raleigh, North Carolina Brownfield Project Number 19067-15-092 August 28, 2019 Page 5 Sub -Slab Soil Gas Risk Calculations Sample ID Non -Residential Calculated Carcinogenic Risk Sum Non -Residential Cumulative Non- Carcinogenic Hazard Index Residential Calculated Carcinogenic Risk Sum Residential Cumulative Non - Carcinogenic Hazard Index SS-1 2.8 x 10-8 8.2 x 10-3 4.6 x 10-7 1.0 x 10-' SS-2 3.3 X 10-7 8.7 X 10-3 4.4 X 10-6 1.1 X 10-' SS-2 Duplicate 1.3 X 10-7 6.5 X 10-3 1.8 X 10-6 8.2 x 10-2 SS-3 1.6 x 10-7 5.2 x 10-3 2.0 X 10-6 6.6 X 10-2 SS-4 1.2 x 10-7 5.3 x 10-3 1.6 x 10-6 6.7 X 10-2 SS-5 2.0 X 10-7 1.2 X 10-2 2.7 X 10-6 1.5 x 10-' SS-6 1.5 x 10-7 1.2 X 10-2 2.0 X 10-6 1.5 x 10-' As indicated, the cancer risk sums and cumulative non -cancer hazard indexes for soil gas samples SS-1 through SS-6 did not exceed the target risk sum of 1.0E-4, nor the target cumulative non -cancer hazard index of 1, for either the residential or non-residential exposure scenarios. Residential and Non -Residential cancer risk sums and cumulative non -cancer hazard indexes were then calculated for each Indoor and Ambient air sample (Appendices F and G). The Residential and Non -Residential exposure cancer risk sums and non -cancer hazard indexes for the Indoor and Ambient air samples are summarized in the following table: Indoor Air Risk Calculations Sample ID Non -Residential Calculated Carcinogenic Risk Sum Non -Residential Cumulative Non- Carcinogenic Hazard Index Residential Calculated Carcinogenic Risk Sum Residential Cumulative Non - Carcinogenic Hazard Index IA-1 2.7 x 10-5 9.2 x 10-1 1.2 X 10-4 3.9 X 10+0 IA-1 Duplicate 2.8 X 10-5 9.2 x 10-' 1.2 X 10-4 3.9 X 10+0 IA-2 2.6 x 10-5 8.9 x 10-' 1.1 X 10-4 3.7 X 10+0 IA-3 3.1 X 10-5 1.1 x 10+0 1.3 X 10-4 4.6 X 10+0 IA-4 2.3 x 10-5 7.6 X 10-' 1.0 X 10-4 3.2 X 10+0 AMB-1 2.0 X 10-6 5.9 x 10-2 8.7 X 10-6 2.5 X 10-' As indicated, the residential cumulative non -carcinogenic hazard index as well as residential carcinogenic risk sums for all Indoor Air samples (IA-1, IA-1 Duplicate, IA-2, IA-3, and IA-4 exceeded the target risk sum of 1.0E-4 and the target cumulative non -cancer hazard index 0 Mid Atlantic Sub -Slab and Indoor Air Assessment Report Gateway Plaza Raleigh, North Carolina Brownfield Project Number 19067-15-092 August 28, 2019 Page 6 of 1. The Non -Residential cumulative non -carcinogenic hazard index for Indoor Air sample IA-3 also exceeded the target cumulative non -cancer hazard index of 1. As discussed previously in Section 3.2, several constituents were detected with greater concentrations in indoor air samples than observed in the sub -slab soil gas samples. In addition, attenuation factors from sub -slab to indoor air for PCE ranged from 5.9 to 23.7 while the attenuation factors for naphthalene and ethylbenzene were below 1.0 (0.31 — 0.71). This confirms that the majority of the contributions for ethylbenzene, dichlorodifluoromethane (freon 12), heptane, hexane, naphthalene, toluene, m&p-xylenes, and o-xylenes are from indoor air sources and not from vapor intrusion. In order to account for this scenario, an additional set of risk calculations were produced. In these modified risk calculations, the sub -slab concentrations for the constituents detected with greater indoor air than sub -slab concentrations were reduced by the lowest attenuation factor calculated for PCE (5.9) to come up with a more realistic indoor air concentration attributable to vapor intrusion. Residential and Non -Residential cumulative cancer risk sums and cumulative non - cancer hazard indexes were then calculated using these adjusted values for each indoor air sample (Appendices H and 1). The Residential and Non -Residential exposure cancer risk sums and non -cancer hazard indexes for the Indoor and Ambient air samples are summarized in the following table: Adjusted Indoor Air Values Risk Calculations Sample ID Non -Residential Calculated Carcinogenic Risk Sum Non -Residential Cumulative Non- Carcinogenic Hazard Index Residential Calculated Carcinogenic Risk Sum Residential Cumulative Non - Carcinogenic Hazard Index IA-1 2.3 x 10-6 8.7 x 10-2 1.0 x 10-5 3.6 X 10-' IA-1 Duplicate 2.3 x 10-6 9.1 x 10-2 1.0 x 10-5 3.8 X 10-' IA-2 2.5 x 10-6 9.6 x 10-2 1.1 x 10-5 4.0 X 10-' IA-3 2.5 x 10-6 1.1 x 10-' 1.1 x 10-5 4.5 X 10-' IA-4 2.9 x 10-6 1.0 x 10-' 1.3 x 10-5 4.3 X 10-' As indicated, the carcinogenic risk sums and cumulative non -carcinogenic hazard indexes for all Indoor Air samples (IA-1, IA-1 Duplicate, IA-2, IA-3, and IA-4) did not exceed the target risk sum of 1.0E-4 or the target cumulative non -cancer hazard index of 1 for either the Residential or Non -Residential exposure scenarios. 0 Mid Atlantic Sub -Slab and Indoor Air Assessment Report August 28, 2019 Gateway Plaza Page 7 Raleigh, North Carolina Brownfield Project Number 19067-15-092 4.0 QUALITY ASSURANCE One duplicate sub -slab and one duplicate indoor air sample were collected during sampling activities. The duplicate samples were analyzed for EPA Compendium Method TO-15 (Table 1). Mid -Atlantic filled each laboratory provided Summa canister such that the final vacuum in the canister was at least three to four inches of mercury. The chain - of -custody was completed in the field and packed with the samples. The Mid -Atlantic field technician returned to the office with the packed boxes which were picked up by a Con - Test courier. The courier then hand delivered the boxes to a national carrier for delivery to the laboratory located in East Longmeadow, Massachusetts. 5.0 CONCLUSIONS The overall objective of this assessment was to fill gaps in assessment data at the subject site identified by the Brownfield Program to determine if a drop off day care facilty was an appropriate use for the identified Space 1. Mid -Atlantic offers the following conclusions based on the results of this assessment as they pertain to the subject site: • Several constituents were detected in sub -slab soil gas samples at concentrations above laboratory method detection limits, but below their respective DWM Residential and Non -Residential SGSLs; • Ethylbenzene and naphthalene were detected in both the primary and duplicate indoor air samples collected at concentrations exceeding their respective EPA Non - Residential IASLs; • Several constituents were detected in indoor air samples at concentrations greater than observed in sub -slab soil gas samples, including: ethylbenzene, dichlorodifluoromethane (freon 12), heptane, naphthalene, m&p-xylenes and o- xylenes. This points to indoor air contributions of these compounds; • Attenuation factors for PCE ranged from 5.9 to 23.7, while attenuation factors for naphthalene and ethylbenzene ranged from 0.31 to 0.71, confirming the indoor air source contributions for various compounds; • The Non -Residential cancer risk and Non -Residential cumulative non -cancer hazard index for all sub -slab soil gas samples (SS-1, SS-2, SS-2 Duplicate, SS-3, SS-4, SS- 5 and SS-6) did not exceed the target risk sum of 1.0E-4, nor the target cumulative non -cancer hazard index of 1; • The Residential cancer risk and Residential cumulative non -cancer hazard index for all sub -slab soil gas samples (SS-1, SS-2, SS-2 Duplicate, SS-3, SS-4, SS-5 and SS-6) did not exceed the target risk sum of 1.0E-4, nor the target cumulative non - cancer hazard index of 1; IS Mid Atlantic Sub -Slab and Indoor Air Assessment Report Gateway Plaza Raleigh, North Carolina Brownfield Project Number 19067-15-092 August 28, 2019 Page 8 • The Residential cancer risk sums and Residential cumulative non -cancer hazard index for indoor air samples (IA-1, IA-1 Duplicate, IA-2, IA-3, and IA-4) exceeded the target risk sum of 1.0E-4, and the target cumulative non -cancer hazard index of 1 for all sampled locations; • The Non -Residential cancer risk and Non -Residential cumulative non -cancer hazard index values were calculated for indoor air samples IA-1, IA-1 Duplicate, IA-2, IA-3, and IA-4. None of the samples exceeded the carcinogenic target risk sum of 1.0E- 4, however, sample IA-3 did exceed the target cumulative non -cancer hazard index of 1; • When indoor air risk was evaluated using sub slab concentrations adjusted by the most conservative attenuation factor calculated for PCE (5.9) and applied to those constituents detected with greater indoor air than sub -slab concentrations, carcinogenic risk sums and cumulative non -carcinogenic hazard indexes for all indoor air samples (IA-1, IA-1 Duplicate, IA-2, IA-3, and IA-4) did not exceed the target risk sum of 1.0E-4 or the target cumulative non -cancer hazard index of 1 for either the Residential or Non -Residential exposure scenarios As indicated, vapor intrusion risk calculations for the soil gas samples collected at the site during this investigation did not exceed the cancer risk sum of 1.0E-4 or the cumulative non -cancer hazard index of 1 for either the Residential or Non -Residential exposure scenario. After calculating more realistic indoor air values for compounds that exhibited higher concentrations in indoor air than in the sub -slab using the most conservative attenuation factor calculated for PCE, risk calculations again did not exceed the cancer risk sum of 1.0E-4 or the cumulative non -cancer hazard index of 1, for either the Residential or Non -Residential exposure scenario. Based on the data collected during this investigation, vapor intrusion does not appear to be causing an unacceptable risk in the spaces tested. As such, it appears a drop-off day care should be approved use for this part of the facility. IS Mid Atlantic DRAWINGS IS Mid Atlantic a IN 1 �LffpR, L�-J\ 7/ O0J-11, 4 N� Woo crest 4 B RKS LE DR�g � N BARKS ST �G NIS-Av` < VI _ WF AREA SHOWN WITHIN WAKE COUNTY REFERENCES: 1. WAKE, NC DIGITAL RASTER GRAPHICS, USGS. SCANNED FROM 1:24,000-SCALE RALEIGH EAST, NC SCALE: 1:13,144 TOPOGRAPHIC MAPS, PUBLISHED 2016, USGS. 2. INSET MAP DIGITAL DATA FROM 2002 NATIONAL TRANSPORTATION ATLAS, 0 2.25 4.5 9 13.5 18 BUREAU OF TRANSPORTATION STATISTICS, WASHINGTON, D.C. Miles 3. PROPERTY BOUNDARY DATA FROM WAKE COUNTY GIS. TOPOGRAPHIC SITE MAP DRAWN DATE: BY: GCH AUGUST 2019 DRAFT JOB NO: Mid Atlantic 2409 CRABTREE BLVD CHECK: 00OR2667.01 Engineering & Environmental Solutions RALEIGH, NORTH CAROLINA ENG. GIS NO: CHECK: 2G-R3667.01 APPROVAL: DWG NO: 1 `` 41 Af Y a r 4 Calculated Calculated Non- SS-1 Carcinogenic Risk Carcinogenic Hazard Quotient Residential 4.6E-07 1.0E-01 Non -Residential 2.8E-08 I 8.2E-03 t Calculated Non - SS SS Calculated SS-5 Carcinogenic Hazard © SS ,. Carcinogenic Risk f . Quotient Q Residential 2.7E 06 1.5E-01 S SS '!► SS Non -Residential iq 2.0E-07 1.2E-02 17. 1 R x`` Legend Calculated Calculated Non - Sub Slab Samples SS-2 Carcinogenic Risk Carcinogenic Hazard d Subject Site Quotient Residential 4.4E-06 1.1E-01 O Little Makers Academy �" Non -Residential 3.3xE-07 8.7E-03 O Azure Violins i" © 2409-117 Notes: 1: No exceedances of the DWM Residential/Non-Residential Soil Gas Screening Limits were identified u 1 Calculated Non- Calculated SS-3 Carcinogenic Hazard Carcinogenic Risk Quotient Residential 2.0E-06 6.6E-02 Non -Residential 1.6E-07 5.2E-03 t � Calculated Non- Calculated SS-4 Carcinogenic Hazard Carcinogenic Risk Quotient Residential 1.6E-06 6.7E-02 Non -Residential 1.2E-07 5.3E-03 Calculated Non- Calculated SS-6 Carcinogenic Hazard Carcinogenic Risk Quotient Residential 2.0E-06 1.5E-01 Non -Residential 1.5E-07 1.2E-02 Y i� AM6 �m 80 160 Feet A AWN BY: DATE: AUGUST 2019 AFT CHECK JOB NO.: 00OR2667.01 GINEER CHECK GISNO R1G2G-R266701-1 Engineering & Environmental Solutions RALEIGH, NORTH CAROLINA APPROVEDBY DRAWING NO.: 2 REFERENCE: PARCEL, ROAD, AND WATER GIs DATA FROM WAKE COUNTY GIS. 2013 AERIAL IMAGERY FROM NC ONEMAP. MID -ATLANTIC FIELD NOTES. Calculated alculated Naphthalene Non- AMB-1 Carcinogenic (ug/m3) Carcinogenic Risk Hazard Index Sample Results 0.67 2.0E-06 5.9E-02 dL-�,r Benz Adjusted Non Adjusted Adjusted Residential Residential Residential Residential Benzene Ethylbenzene Naphthalene 0-Xylenes M&PXylenes Calculated Calculated IA-3 (ug/m3) (ug/m3) (ug/m3) (ug/m3) Calculated (ug/m3) Non- Calculated Non - Carcinogenic Carcinogenic Risk Carcinogenic Risk Carcinogenic Hazard Index Hazard index Sample Results 0.39 14 30 36 88 2.5E-06 1.1E-01 1.1E-05 4.5E-01 t � Adjusted Non Adjusted Non Adjusted Adjusted Residential Residential Residential Residential Benzene Ethylbenzene Naphthalene O-Xylenes M&P Xylenes Calculated Calculated IA-2 (ug/m3) (ug/m3) (ug/m3) (ug/m3) (ug/m3) Calculated Non- Calculated Non - Carcinogenic Carcinogenic Risk Carcinogenic Risk Carcinogenic Hazard index Hazard index Sample 0.78 9.5 8.6 25 57 2.5E-06 9.6E-02 1.1E-05 4.0E-01 ^ Results IA-1 Sample Results IT l �12 3 ` w Legend � �'�`. �'",�� \• � , ,, d Subject Site *� . '. Q Outdoor Air Sample Point Indoor Air Sample Points , e ;� •.` r ;, i i O Little Makers Academy © Azure Violins 2409-117 0 80 16Feet� Notes: 1: Unit of ug/m3 = Micrograms per Cubic Meter. ' 2: Only exceedances of calculated EPA Region 4 Residential/Non-Residential Indoor Air Screening Limits (IASLs) are shown. ` 3: Bold values exceed Non -Residential IASLs and risk concentrations 4: Underlined values exceed Residential IASLs and risk concentrations i Adjusted Non- Adjusted Adjusted Non- Adjusted Residential Reidential Residential sResidential ne Ethylbenzene Naphthalene O-Xylenes M&P Xylenes Calculated Calculated (ug/m3) (ug/m3) (ug/m3) (ug/m3) (ug/m3) Calculated Non- Calculated Non - Carcinogenic Carcinogenic Risk Carcinogenic Risk Carcinogenic Hazard Index Hazard Index 0.36 10 9.0 26 61 2.3E-06 8.7E-02 1.0E-05 3.6E-01 A N Aft A N Aft Sample DATE: AUGUST 2019 JOB NO.: 00OR2667.01 GIS NO.: 1G2G-R2667.01-1 DRAWING NO.: 3 1�REFERENCE: PARCEL, ROAD, AND WATER GIS DATA FROM WAKE COUNTY GIS. 2013 AERIAL IMAGERY FROM NC ONEMAP. MID -ATLANTIC FIELD NOTESPARCEL, ROAD, AND WATER GIS DATA FROM WAKE COUNTY GIS. 2013 AERIAL IMAGERY FROM NC ONEMAP. MID -ATLANTIC FIELD NOTES. TABLES IS Mid Atlantic Parameter DWM Residential Vapor Intrusion Screening Levels DWM Non -Residential Vapor Intrusion Screening Levels TABLE 3.1 GATEWAY PLAZA R2667.01 SUBSLAB SOIL GAS SAMPLE ANALYSIS Residential Soil- Gas ug/m3 Non -Residential Soil -Gas ug/m3 SS-1 SS-2 Duplicate SS-2d SS-3 SS-4 SS-5 SS-6 Sampling Date 6/28/2019 10:31 AM 6/28/2019 11:00 AM 6/28/2019 11:06 AM 6/28/2019 11:43 AM 6/28/2019 11:27 AM 6/28/2019 9:35 AM 6/28/2019 10:05 AM EPA TO-15 Acetone 220000 2700000 940 50 42 100 78 80 53 Benzene 120 1600 ND (1.3) 3.4 1.9 3.5 2.8 2.7 2.2 Benzyl Chloride 7 88 ND (1.1) ND (0.23) ND (0.23) ND (0.23) ND (0.23) ND (0.23) ND (0.23) Bromodichloromethane 25 330 ND (2.5) ND (0.49) ND (0.49) ND (0.49) ND (0.49) ND (0.49) ND (0.49) Bromoform 850 11000 ND (4.7) ND (0.93) ND (0.93) ND (0.93) ND (0.93) ND (0.93) ND (0.93) Bromomethane 35 440 ND (2.7) ND (0.53) ND (0.53) ND (0.53) ND (0.53) ND (0.53) ND (0.53) 1,3-Butadiene 14 180 ND (1.4) ND (0.28) ND (0.28) ND (0.28) ND (0.28) ND (0.28) ND (0.28) 2-Butanone (MEK) 35000 440000 150 9.5 J 9.7 J 18 J 12 J 24 111 Carbon Disulfide 4900 61000 ND (2.1) ND (0.43) ND (0.43) ND (0.43) ND (0.43) ND (0.43) 6.9 Carbon Tetrachloride 160 2000 ND (2.1) ND (0.41) ND (0.41) ND (0.41) ND (0.41) ND (0.41) ND (0.41) Chlorobenzene 350 4400 ND (2.3) ND (0.45) ND (0.45) ND (0.45) ND (0.45) ND (0.45) ND (0.45) Chloroethane 70000 880000 ND (1.6) ND (0.32) ND (0.32) ND (0.32) ND (0.32) ND (0.32) ND (0.32) Chloroform 41 530 ND (1.8) ND (0.36) ND (0.36) ND (0.36) ND (0.36) ND (0.36) ND (0.36) Chloromethane 630 7900 ND (1.4) ND (0.28) ND (0.28) ND (0.28) ND (0.28) ND (0.28) ND (0.28) Cyclohexane 42000 530000 ND (2.4) ND (0.49) ND (0.49) ND (0.49) ND (0.49) ND (0.49) ND (0.49) Dibromochloromethane - - ND (2.8) ND (0.57) ND (0.57) ND (0.57) ND (0.57) ND (0.57) ND (0.57) 1,2-Dibromoethane (EDB) 1.6 20 ND (3.0)* ND (0.60) ND (0.60) ND (0.60) ND (0.60) ND (0.60) ND (0.60) 1,2-Dichlorobenzene 1400 18000 ND (2.9) ND (0.58) ND (0.58) ND (0.58) ND (0.58) ND (0.58) ND (0.58) 1,3-Dichlorobenzene - - ND (3.1) 1.5 1.8 2.5 ND (0.62) 3.3 3.7 1,4-Dichlorobenzene 85 1100 ND (3.7) ND (0.73) ND (0.73) ND (0.73) ND (0.73) ND (0.73) ND (0.73) Dichlorodifluoromethane (Freon 12) 700 8800 ND (2.1) 1.3 ND (0.43) 1.7 1.4 1.4 1.4 1,1-Dichloroethane 580 7700 ND (1.2) ND (0.25) ND (0.25) ND (0.25) ND (0.25) ND (0.25) ND (0.25) 1,2-Dichloroethane 36 470 ND (1.5) ND (0.31) ND (0.31) ND (0.31) ND (0.31) ND (0.31) ND (0.31) 1,1-Dichloroethylene 1400 18000 ND (1.6) ND (0.32) ND (0.32) ND (0.32) ND (0.32) ND (0.32) ND (0.32) cis-1,2-Dichloroethylene - - ND (1.6) ND (0.32) ND (0.32) ND (0.32) ND (0.32) ND (0.32) ND (0.32) trans-1,2-Dichloroethylene - - ND (1.6) ND (0.32) ND (0.32) ND (0.32) ND (0.32) ND (0.32) ND (0.32) 1,2-Dichloropropene 28 350 ND (1.6) ND (0.33) ND (0.33) ND (0.33) ND (0.33) ND (0.33) ND (0.33) cis-1,3-Dichloropropene - - ND (1.6) ND (0.32) ND (0.32) ND (0.32) ND (0.32) ND (0.32) ND (0.32) trans-1,3-Dichloropropene ND (1.7) ND (0.33) ND (0.33) ND (0.33) ND (0.33) ND (0.33) ND (0.33) 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) - - ND (3.5) ND (0.70) ND (0.70) ND (0.70) ND (0.70) ND (0.70) ND (0.70) 1,4-Dioxane 190 2500 ND (23) ND (4.6) ND (4.6) ND (4.6) ND (4.6) ND (4.6) ND (4.6) Ethanol - - 1200 84 60 120 95 49 29 Ethyl Acetate 490 6100 ND (2.7) 2.7 ND (0.54) ND (0.54) 2.5 2.9 ND (0.54) Ethylbenzene 370 4900 4.9 6.4 4.3 6.3 6.1 4.4 3.8 4-Ethyltoluene - - ND (3.0) 3.8 2.5 ND (0.60) 2.9 2.9 2.5 Heptane 2800 35000 ND (2.4) 2.5 1.3 ND (0.48) 1.8 2.1 1.3 Hexachlorobutadiene 43 560 ND (4.9) ND (0.98) ND (0.98) ND (0.98) ND (0.98) ND (0.98) ND (0.98) Hexane 4900 61000 ND (6.2) 3.9 J ND (1.2) 3.6 J 2.1 J 1.9 J ND (1.2) 2-Hexanone (MBK) 210 2600 ND (2.4) ND (0.48) ND (0.48) ND (0.48) ND (0.48) ND (0.48) ND (0.48) Isopropanol 1400 18000 120 111 9.6 J 12 J 101 4.6 J 4.1 J Methyl tert-Butyl Ether (MTBE) 3600 47000 ND (1.8) ND (0.36) ND (0.36) ND (0.36) ND (0.36) ND (0.36) ND (0.36) Methylene Chloride 4200 53000 ND (4.2) 0.93 J 1.3 J 1.5 J 1.6 J 0.93 J ND (0.84) 4-Methyl-2-pentanone (MIBK) 21000 260000 ND (2.0) ND (0.39) ND (0.39) ND (0.39) ND (0.39) ND (0.39) ND (0.39) Naphthalene 21 260 ND (4.0) 3.5 3.7 4.3 3.1 5.4 3.6 Propene 21000 260000 ND (1.7) ND (0.34) ND (0.34) ND (0.34) ND (0.34) ND (0.34) ND (0.34) Styrene 7000 88000 4.9 6.2 4.3 5.6 5.4 4.8 4.4 1,1,2,2-Tetrachloroethane 16 210 ND (3.0) ND (0.61) ND (0.61) ND (0.61) ND (0.61) ND (0.61) ND (0.61) Tetrachloroethylene 280 3500 14 9.8 13 7.7 26 18 14 Tetrahydrofuran 14000 180000 ND (2.0) 5.8 4.7 15 19 13 6.5 Toluene 35000 440000 54 63 47 74 63 73 39 1,2,4-Trichlorobenzene 14 180 ND (5.1) ND (1.0) ND (1.0) ND (1.0) ND (1.0) ND (1.0) ND (1.0) 1,1,1-Trichloroethane 35000 440000 ND (2.0) ND (0.41) ND (0.41) ND (0.41) ND (0.41) ND (0.41) ND (0.41) 1,1,2-Trichloroethane 1.4 18 ND (2.2)* ND (0.45) ND (0.45) ND (0.45) ND (0.45) ND (0.45) ND (0.45) Trichloroethylene 14 180 4.6.1 1.3 1.7 ND (0.43) ND (0.43) 4.8 6.3 Trichlorofluoromethane - - 62 39 43 38 39 34 42 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 35000 440000 ND (4.6) ND (0.93) ND (0.93) ND (0.93) ND (0.93) 1.11 ND (0.93) 1,2,4-Trimethyl benzene 420 5300 ND (3.1) ND (0.63) ND (0.63) ND (0.63) ND (0.63) ND (0.63) ND (0.63) 1,3,5-Trimethyl benzene 420 5300 ND (3.1) 2.9 2.1 2.6 2.2 2.5 2.0 Vinyl Acetate 1400 18000 ND (1.7) ND (0.34) ND (0.34) ND (0.34) ND (0.34) ND (0.34) ND (0.34) Vinyl Chloride 56 2800 ND (1.6) ND (0.32) ND (0.32) ND (0.32) ND (0.32) ND (0.32) ND (0.32) Xylene, m&p 700 8800 21 30 20 30 28 20 18 X lene, o- 700 8800 6.7 9.6 6.2 8.7 8.2 6.5 5.5 NOTES: Results are cmpared to the NCDEQ DWM residential/non residential soil gas screening levels (Febuary 2018) 1. ND = Not detected above the lab reporting limits shown in parenthesis. 2. - = No DWM Residential or Non -Residential screening limits established. 3. Underlined values exceed the DWM Residential Indoor Air Screening Limits. 4. Bold values exceed the DWM Non -Residential Indoor Air Screening Limits. 5. * Asterisk indicates the lab reporting limits are greater than the residential Residential Vapor Intrusion Screening Levels 6. ug/m3 = micrograms per cubic meter of air. TABLE 3.2 Residential Vapor Non -Residential GATEWAY PLAZA Parameter Intrusion Vapor Intrusion R2667.01 Screening Levels Screening Levels INDOOR AND AMBIENT AIR SAMPLE ANALYSIS Target Indoor Air Target Indoor Air Concentration Concentration IA-1 Duplicate IA-1D IA-2 IA-3 IA-4 AMB-1 ug/m3 ug/m3 Sampling Date 7/24/2019 16:54 7/24/2019 16:44 7/24/2019 16:53 7/24/2019 16:56 7/24/2019 16:47 7/24/2019 16:44 EPA TO-15 Acetone 6440 27100 79 70 74 100 75 9.4 Benzene 0.36 1.57 0.36 0.34 0.78 0.39 0.32 0.22 2-Butanone (MEK) 1040 4380 120 94 74 140 140 ND (0.16) Carbon Disulfide 146 613 ND (0.075) ND (0.075) ND (0.075) ND (0.075) ND (0.075) ND (0.075) 1,3-Dichlorobenzene - - ND (0.11) ND (0.11) ND (0.11) ND (0.11) ND (0.11) ND (0.11) Dichlorodifluoromethane (Freon 12) 20.9 87.6 2.3 2.9 1.7 2.1 1.4 2.0 cis-1,2-Dichloroethylene - - ND (0.057) ND (0.057) ND (0.057) ND (0.057) ND (0.057) ND (0.057) trans-1,2-Dichloroethylene ND (0.056) ND (0.056) ND (0.056) ND (0.056) ND (0.056) ND (0.056) Ethanol - - 22 18 19 25 19 5.0 Ethyl Acetate 14.6 61.3 ND (0.094) ND (0.094) ND (0.094) ND (0.094) ND (0.094) ND (0.094) Ethylbenzene 1.12 4.91 10 9.7 9.5 14 7.8 ND (0.088) 4-Ethyltoluene - - 3.2 3.0 3.1 3.9 2.8 ND (0.11) Heptane 83.4 350 5.6 5.5 5.5 8.9 3.8 0.20 Hexane 146 613 ND (0.22) ND (0.22) ND (0.22) 5.1 ND (0.22) ND (0.22) Isopropanol 41.7 175 ND (0.11) 4.6 7.7 6.2 ND (0.11) ND (0.11) Methylene Chloride 101 526 ND (0.15) ND (0.15) ND (0.15) ND (0.15) ND (0.15) ND (0.15) Naphthalene 0.0826 0.361 9.0 9.2 8.6 10 7.7 0.67 Styrene 209 876 ND (0.092) ND (0.092) ND (0.092) ND (0.092) ND (0.092) ND (0.092) Tetrachloroethylene 8.34 35 0.89 0.95 0.91 1.3 0.76 ND (0.13) Tetrahydrofuran 417 1750 2.1 2.1 2.0 2.3 1.7 ND (0.069) Toluene 1040 4380 61 62 61 150 31 1.1 Trichlorofluoromethane - - 2.4 2.3 2.2 3.2 2.1 1.0 1,3,5-Trimethylbenzene 12.5 52.6 2.1 2.0 2.0 2.5 2.0 ND (0.11) Xylene, m&p 20.9 87.6 61 59 57 88 45 0.41 X lene, o- 20.9 87.6 26 25 25 36 19 0.18 NOTES: 1. ND = Not detected above the lab reporting limits shown in parenthesis. 2. - = No Calculated Residential or Non -Residential EPA Screening levels established. 3. Underlined values exceed the Calculated Residential EPA Indoor Air Screening Levels. 4. Bold values exceed the Calculated Non -Residential EPA Indoor Air Screening Levels. 5. ug/m3 = micrograms per cubic meter of air. APPENDIX A LABORATORY ANALYTICAL REPORT AND CHAIN -OF -CUSTODY RECORD FOR SUB -SLAB SOIL GAS SAMPLES IS Mid Atlantic icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 July 15, 2019 Dan Nielsen Mid -Atlantic Associates, Inc. - Raleigh, NC 409 Rogers View Court Raleigh, NC 27610 Project Location: Gateway Client Job Number: Project Number: R2667.01 Laboratory Work Order Number: 19G0004 Enclosed are results of analyses for samples received by the laboratory on June 28, 2019. If you have any questions concerning this report, please feel free to contact me. Sincerely, I,&, �. A�� Kerry K. McGee Project Manager QA Officer Katherine Allen Laboratory Manager Daren Damboragian Page 1 of 39 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 Mid -Atlantic Associates, Inc. - Raleigh, NC REPORT DATE: 7/15/2019 409 Rogers View Court Raleigh, NC 27610 PURCHASE ORDER NUMBER: ATTN: Dan Nielsen PROJECT NUMBER: R2667.01 ANALYTICAL SUMMARY WORK ORDER NUMBER: 19G0004 The results of analyses performed on the following samples submitted to the CON -TEST Analytical Laboratory are found in this report. PROJECT LOCATION: Gateway FIELD SAMPLE # LAB ID: MATRIX SAMPLE DESCRIPTION TEST SUB LAB SS-5 SS-6 SS-1 SS-2 SS-2d SS-4 SS-3 Unused Can #2247/ Unused Reg #4107 19G0004-01 Sub Slab EPATO-15 19G0004-02 Sub Slab EPATO-15 19G0004-03 Sub Slab EPATO-15 19G0004-04 Sub Slab EPA TO-15 19G0004-05 Sub Slab EPATO-15 19G0004-06 Sub Slab EPATO-15 19G0004-07 Sub Slab EPATO-15 19G0004-08 Sub Slab Page 2 of 39 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 CASE NARRATIVE SUMMARY All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report. Page 3 of 39 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 EPA TO-15 Qualifications: Laboratory fortified blank /laboratory control sample recovery outside of control limits. Data validation is not affected since all results are "not detected" for all samples in this batch for this compound and bias is on the high side. Analyte & Samples(s) Qualified: Benzyl chloride, Vinyl Acetate B235524-BS1, B235552-BS I Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this compound is likely to be biased on the low side. Analyte & Samples(s) Qualified: Chloromethane, Dichlorodifluoromethane (Freon 12) 19G0004-01[SS-5], 19G0004-02[SS-6], 19G0004-03[SS-1], 19G0004-04[SS-2], 19G0004-05[SS-2d], 19G0004-06[SS-4], 19G0004-07[SS-3], B235524-BLKI, B235524-BS1, B235552-BLKI, B235552-BSI Elevated reporting limit due to high concentration of target compounds. Analyte & Samples(s) Qualified: 19G0004-03 [SS-1 ] Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for this compound. Analyte & Samples(s) Qualified: 1,2,4-Trichlorobenzene, Chloromethane, Dichlorodifluoromethane (Freon 12), Naphthalene, Propene 19G0004-01[SS-5], 19G0004-02[SS-6], 19G0004-03[SS-1], 19G0004-04[SS-2], 19G0004-05[SS-2d], 19G0004-06[SS-4], B235524-BLKI, B235524-BSI, S038082-CCVI, 19G0004-07[SS-3], B235552-BLKI, B235552-BSI, S038102-CCVI Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was "not detected" for this compound. Analyte & Samples(s) Qualified: Vinyl Acetate S038082-CCVI, S038102-CCVI Initial calibration verification (ICV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was 'hot detected" for this compound. Analyte & Samples(s) Qualified: Vinyl Acetate B235524-BS1, B235552-BSI, S038102-CCVI Compound fails the method requirement of 70-l3O% recovery for the LCS. Is classified by the lab as a difficult compound and passes the in house limits of 50-150%. Analyte & Samples(s) Qualified: Propene 19G0004-01[SS-5], 19G0004-02[SS-6], 19G0004-03[SS-1], 19G0004-04[SS-2], 19G0004-05[SS-2d], 19G0004-06[SS-4], 19G0004-07[SS-3], B235524-BLKI, B235524-BSI, B235552-BLKI, B235552-BSI Page 4 of 39 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 The results of analyses reported only relate to samples submitted to the Con -Test Analytical Laboratory for testing. I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. d� Lisa A. Worthington Technical Representative Page 5 of 39 icon-tes w . ANALYTICAL LABORATORY Project Location: Gateway Date Received: 6/28/2019 Field Sample #: SS-5 Sample ID: 19G0004-01 Sample Matrix: Sub Slab Sampled: 6/28/2019 09:35 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 ANALYTICAL RESULTS Sample Description/Location: Work Order: 19G0004 Sub Description/Location: Initial Vacuum(in Hg): -26.5 Canister ID: 2237 Final Vacuum(in Hg): -2 Canister Size: 1 liter Receipt Vacuum(in Hg): -3.9 Flow Controller ID: 4192 Flow Controller Type: Fixed -Orifice Sample Type: 5 min Flow Controller Calibration RPD Pre and Post -Sampling: EPA TO-15 ppbv ug/m3 Date/Time Analyte Results RL MDL Flag/Qual Results ILL MDL Dilution Analyzed Analyst Acetone 34 8.0 2.8 80 19 6.6 4 7/13/19 22:26 BRF Benzene 0.85 0.20 0.082 2.7 0.64 0.26 4 7/13/19 22:26 BRF Benzyl chloride ND 0.20 0.044 ND 1.0 0.23 4 7/13/19 22:26 BRF Bromodichloromethane ND 0.20 0.074 ND 1.3 0.49 4 7/13/19 22:26 BRF Bromoform ND 0.20 0.090 ND 2.1 0.93 4 7/13/19 22:26 BRF Bromomethane ND 0.20 0.14 ND 0.78 0.53 4 7/13/19 22:26 BRF 1,3-Butadiene ND 0.20 0.13 ND 0.44 0.28 4 7/13/19 22:26 BRF 2-Butanone (MEK) 8.1 8.0 0.31 24 24 0.92 4 7/13/19 22:26 BRF Carbon Disulfide ND 2.0 0.14 ND 6.2 0.43 4 7/13/19 22:26 BRF Carbon Tetrachloride ND 0.20 0.065 ND 1.3 0.41 4 7/13/19 22:26 BRF Chlorobenzene ND 0.20 0.098 ND 0.92 0.45 4 7/13/19 22:26 BRF Chloroethane ND 0.20 0.12 ND 0.53 0.32 4 7/13/19 22:26 BRF Chloroform ND 0.20 0.074 ND 0.98 0.36 4 7/13/19 22:26 BRF Chloromethane ND 0.40 0.14 L-03 ND 0.83 0.28 4 7/13/19 22:26 BRF Cyclohexane ND 0.20 0.14 ND 0.69 0.49 4 7/13/19 22:26 BRF Dibromochloromethane ND 0.20 0.066 ND 1.7 0.57 4 7/13/19 22:26 BRF 1,2-Dibromoethane (EDB) ND 0.20 0.078 ND 1.5 0.60 4 7/13/19 22:26 BRF 1,2-Dichlorobenzene ND 0.20 0.096 ND 1.2 0.58 4 7/13/19 22:26 BRF 1,3-Dichlorobenzene 0.56 0.20 0.10 3.3 1.2 0.62 4 7/13/19 22:26 BRF 1,4-Dichlorobenzene ND 0.20 0.12 ND 1.2 0.73 4 7/13/19 22:26 BRF Dichlorodifluoromethane (Freon 12) 0.28 0.20 0.087 V-05, L-03 1.4 0.99 0.43 4 7/13/19 22:26 BRF 1, 1 -Dichloroethane ND 0.20 0.061 ND 0.81 0.25 4 7/13/19 22:26 BRF 1,2-Dichloroethane ND 0.20 0.076 ND 0.81 0.31 4 7/13/19 22:26 BRF 1, 1 -Dichloroethylene ND 0.20 0.081 ND 0.79 0.32 4 7/13/19 22:26 BRF cis-1,2-Dichloroethylene ND 0.20 0.082 ND 0.79 0.32 4 7/13/19 22:26 BRF trans-1,2-Dichloroethylene ND 0.20 0.081 ND 0.79 0.32 4 7/13/19 22:26 BRF 1,2-Dichloropropane ND 0.20 0.071 ND 0.92 0.33 4 7/13/19 22:26 BRF cis- 1,3 -Dichloropropene ND 0.20 0.070 ND 0.91 0.32 4 7/13/19 22:26 BRF trans- 1, 3 -Dichloropropene ND 0.20 0.073 ND 0.91 0.33 4 7/13/19 22:26 BRF 1,2-Dichloro- 1, 1,2,2-tetrafluoroethane (Freon 114) ND 0.20 0.10 ND 1.4 0.70 4 7/13/19 22:26 BRF 1,4-Dioxane ND 2.0 1.3 ND 7.2 4.6 4 7/13/19 22:26 BRF Ethanol 26 8.0 3.6 49 15 6.7 4 7/13/19 22:26 BRF Ethyl Acetate 0.82 0.20 0.15 2.9 0.72 0.54 4 7/13/19 22:26 BRF Ethylbenzene 1.0 0.20 0.12 4.4 0.87 0.50 4 7/13/19 22:26 BRF 4-Ethyltoluene 0.59 0.20 0.12 2.9 0.98 0.60 4 7/13/19 22:26 BRF Heptane 0.50 0.20 0.12 2.1 0.82 0.48 4 7/13/19 22:26 BRF Hexachlorobutadiene ND 0.20 0.092 ND 2.1 0.98 4 7/13/19 22:26 BRF Hexane 0.54 8.0 0.35 J 1.9 28 1.2 4 7/13/19 22:26 BRF 2-Hexanone (MBK) ND 0.20 0.12 ND 0.82 0.48 4 7/13/19 22:26 BRF Isopropanol 1.9 8.0 0.25 J 4.6 20 0.60 4 7/13/19 22:26 BRF Methyl tert-Butyl Ether (MTBE) ND 0.20 0.10 ND 0.72 0.36 4 7/13/19 22:26 BRF Methylene Chloride 0.27 2.0 0.24 J 0.93 6.9 0.84 4 7/13/19 22:26 BRF 4-Methyl-2-pentanone (MIBK) ND 0.20 0.096 ND 0.82 0.39 4 7/13/19 22:26 BRF Naphthalene 1.0 0.20 0.15 V-05 5.4 1.0 0.80 4 7/13/19 22:26 BRF Propene ND 8.0 0.20 V-05, Z-01 ND 14 0.34 4 7/13/19 22:26 BRF Styrene 1.1 0.20 0.12 4.8 0.85 0.53 4 7/13/19 22:26 BRF 1,1,2,2-Tetrachloroethane ND 0.20 0.089 ND 1.4 0.61 4 7/13/19 22:26 BRF Page 6 of 39 icon-tes w . ANALYTICAL LABORATORY Project Location: Gateway Date Received: 6/28/2019 Field Sample #: SS-5 Sample ID: 19G0004-01 Sample Matrix: Sub Slab Sampled: 6/28/2019 09:35 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 ANALYTICAL RESULTS Sample Description/Location: Sub Description/Location: Canister ID: 2237 Canister Size: 1 liter Flow Controller ID: 4192 Sample Type: 5 min Work Order: 19G0004 Initial Vacuum(in Hg): -26.5 Final Vacuum(in Hg): -2 Receipt Vacuum(in Hg): -3.9 Flow Controller Type: Fixed -Orifice Flow Controller Calibration RPD Pre and Post -Sampling: EPA TO-15 ppbv ug/m3 Date/Time Analyte Results RL MDL Flag/Qual Results RL MDL Dilution Analyzed Analyst Tetrachloroethylene 2.6 0.20 0.11 18 1.4 0.75 4 7/13/19 22:26 BRF Tetrahydrofuran 4.4 0.20 0.13 13 0.59 0.39 4 7/13/19 22:26 BRF Toluene 19 0.20 0.10 73 0.75 0.39 4 7/13/19 22:26 BRF 1,2,4-Trichlorobenzene ND 0.20 0.14 V-05 ND 1.5 1.0 4 7/13/19 22:26 BRF 1, 1, 1 -Trichloroethane ND 0.20 0.075 ND 1.1 0.41 4 7/13/19 22:26 BRF 1,1,2-Trichloroethane ND 0.20 0.082 ND 1.1 0.45 4 7/13/19 22:26 BRF Trichloroethylene 0.89 0.20 0.081 4.8 1.1 0.43 4 7/13/19 22:26 BRF Trichlorofluoromethane (Freon 11) 6.0 0.80 0.12 34 4.5 0.65 4 7/13/19 22:26 BRF 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 0.15 0.80 0.12 J 1.1 6.1 0.93 4 7/13/19 22:26 BRF 1,2,4-Trimethylbenzene ND 0.20 0.13 ND 0.98 0.63 4 7/13/19 22:26 BRF 1,3,5-Trimethylbenzene 0.51 0.20 0.13 2.5 0.98 0.62 4 7/13/19 22:26 BRF Vinyl Acetate ND 4.0 0.095 ND 14 0.34 4 7/13/19 22:26 BRF Vinyl Chloride ND 0.20 0.13 ND 0.51 0.32 4 7/13/19 22:26 BRF m&p-Xylene 4.5 0.40 0.23 20 1.7 1.00 4 7/13/19 22:26 BRF o-Xylene 1.5 0.20 0.12 6.5 0.87 0.54 4 7/13/19 22:26 BRF Surrogates 4-Bromofluorobenzene (1) % Recovery 92.1 % REC Limits 70-130 7/13/19 22:26 Page 7 of 39 icon-tes w . ANALYTICAL LABORATORY Project Location: Gateway Date Received: 6/28/2019 Field Sample #: SS-6 Sample ID: 19G0004-02 Sample Matrix: Sub Slab Sampled: 6/28/2019 10:05 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 ANALYTICAL RESULTS Sample Description/Location: Work Order: 19G0004 Sub Description/Location: Initial Vacuum(in Hg): -28 Canister ID: 2241 Final Vacuum(in Hg): -1 Canister Size: 1 liter Receipt Vacuum(in Hg): -2.1 Flow Controller ID: 4201 Flow Controller Type: Fixed -Orifice Sample Type: 5 min Flow Controller Calibration RPD Pre and Post -Sampling: EPA TO-15 ppbv ug/m3 Date/Time Analyte Results RL MDL Flag/Qual Results RL MDL Dilution Analyzed Analyst Acetone 22 8.0 2.8 53 19 6.6 4 7/13/19 23:06 BRF Benzene 0.69 0.20 0.082 2.2 0.64 0.26 4 7/13/19 23:06 BRF Benzyl chloride ND 0.20 0.044 ND 1.0 0.23 4 7/13/19 23:06 BRF Bromodichloromethane ND 0.20 0.074 ND 1.3 0.49 4 7/13/19 23:06 BRF Bromoform ND 0.20 0.090 ND 2.1 0.93 4 7/13/19 23:06 BRF Bromomethane ND 0.20 0.14 ND 0.78 0.53 4 7/13/19 23:06 BRF 1,3-Butadiene ND 0.20 0.13 ND 0.44 0.28 4 7/13/19 23:06 BRF 2-Butanone (MEK) 3.6 8.0 0.31 J 11 24 0.92 4 7/13/19 23:06 BRF Carbon Disulfide 2.2 2.0 0.14 6.9 6.2 0.43 4 7/13/19 23:06 BRF Carbon Tetrachloride ND 0.20 0.065 ND 1.3 0.41 4 7/13/19 23:06 BRF Chlorobenzene ND 0.20 0.098 ND 0.92 0.45 4 7/13/19 23:06 BRF Chloroethane ND 0.20 0.12 ND 0.53 0.32 4 7/13/19 23:06 BRF Chloroform ND 0.20 0.074 ND 0.98 0.36 4 7/13/19 23:06 BRF Chloromethane ND 0.40 0.14 L-03 ND 0.83 0.28 4 7/13/19 23:06 BRF Cyclohexane ND 0.20 0.14 ND 0.69 0.49 4 7/13/19 23:06 BRF Dibromochloromethane ND 0.20 0.066 ND 1.7 0.57 4 7/13/19 23:06 BRF 1,2-Dibromoethane (EDB) ND 0.20 0.078 ND 1.5 0.60 4 7/13/19 23:06 BRF 1,2-Dichlorobenzene ND 0.20 0.096 ND 1.2 0.58 4 7/13/19 23:06 BRF 1,3-Dichlorobenzene 0.61 0.20 0.10 3.7 1.2 0.62 4 7/13/19 23:06 BRF 1,4-Dichlorobenzene ND 0.20 0.12 ND 1.2 0.73 4 7/13/19 23:06 BRF Dichlorodifluoromethane (Freon 12) 0.28 0.20 0.087 L-03, V-05 1.4 0.99 0.43 4 7/13/19 23:06 BRF 1,1-Dichloroethane ND 0.20 0.061 ND 0.81 0.25 4 7/13/19 23:06 BRF 1,2-Dichloroethane ND 0.20 0.076 ND 0.81 0.31 4 7/13/19 23:06 BRF 1,1-Dichloroethylene ND 0.20 0.081 ND 0.79 0.32 4 7/13/19 23:06 BRF cis-1,2-Dichloroethylene ND 0.20 0.082 ND 0.79 0.32 4 7/13/19 23:06 BRF trans-1,2-Dichloroethylene ND 0.20 0.081 ND 0.79 0.32 4 7/13/19 23:06 BRF 1,2-Dichloropropane ND 0.20 0.071 ND 0.92 0.33 4 7/13/19 23:06 BRF cis- 1,3 -Dichloropropene ND 0.20 0.070 ND 0.91 0.32 4 7/13/19 23:06 BRF trans- 1, 3 -Dichloropropene ND 0.20 0.073 ND 0.91 0.33 4 7/13/19 23:06 BRF 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) ND 0.20 0.10 ND 1.4 0.70 4 7/13/19 23:06 BRF 1,4-Dioxane ND 2.0 1.3 ND 7.2 4.6 4 7/13/19 23:06 BRF Ethanol 15 8.0 3.6 29 15 6.7 4 7/13/19 23:06 BRF Ethyl Acetate ND 0.20 0.15 ND 0.72 0.54 4 7/13/19 23:06 BRF Ethylbenzene 0.88 0.20 0.12 3.8 0.87 0.50 4 7/13/19 23:06 BRF 4-Ethyltoluene 0.51 0.20 0.12 2.5 0.98 0.60 4 7/13/19 23:06 BRF Heptane 0.31 0.20 0.12 1.3 0.82 0.48 4 7/13/19 23:06 BRF Hexachlorobutadiene ND 0.20 0.092 ND 2.1 0.98 4 7/13/19 23:06 BRF Hexane ND 8.0 0.35 ND 28 1.2 4 7/13/19 23:06 BRF 2-Hexanone (MBK) ND 0.20 0.12 ND 0.82 0.48 4 7/13/19 23:06 BRF Isopropanol 1.7 8.0 0.25 J 4.1 20 0.60 4 7/13/19 23:06 BRF Methyl tert-Butyl Ether (MTBE) ND 0.20 0.10 ND 0.72 0.36 4 7/13/19 23:06 BRF Methylene Chloride ND 2.0 0.24 ND 6.9 0.84 4 7/13/19 23:06 BRF 4-Methyl-2-pentanone (MIBK) ND 0.20 0.096 ND 0.82 0.39 4 7/13/19 23:06 BRF Naphthalene 0.70 0.20 0.15 V-05 3.6 1.0 0.80 4 7/13/19 23:06 BRF Propene ND 8.0 0.20 V-05, Z-01 ND 14 0.34 4 7/13/19 23:06 BRF Styrene 1.0 0.20 0.12 4.4 0.85 0.53 4 7/13/19 23:06 BRF 1,1,2,2-Tetrachloroethane ND 0.20 0.089 ND 1.4 0.61 4 7/13/19 23:06 BRF Page 8 of 39 icon-tes w . ANALYTICAL LABORATORY Project Location: Gateway Date Received: 6/28/2019 Field Sample #: SS-6 Sample ID: 19G0004-02 Sample Matrix: Sub Slab Sampled: 6/28/2019 10:05 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 ANALYTICAL RESULTS Sample Description/Location: Sub Description/Location: Canister ID: 2241 Canister Size: 1 liter Flow Controller ID: 4201 Sample Type: 5 min Work Order: 19G0004 Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -1 Receipt Vacuum(in Hg): -2.1 Flow Controller Type: Fixed -Orifice Flow Controller Calibration RPD Pre and Post -Sampling: EPA TO-15 ppbv ug/m3 Date/Time Analyte Results RL MDL Flag/Qual Results RL MDL Dilution Analyzed Analyst Tetrachloroethylene 2.0 0.20 0.11 14 1.4 0.75 4 7/13/19 23:06 BRF Tetrahydrofuran 2.2 0.20 0.13 6.5 0.59 0.39 4 7/13/19 23:06 BRF Toluene 10 0.20 0.10 39 0.75 0.39 4 7/13/19 23:06 BRF 1,2,4-Trichlorobenzene ND 0.20 0.14 V-05 ND 1.5 1.0 4 7/13/19 23:06 BRF 1, 1, 1 -Trichloroethane ND 0.20 0.075 ND 1.1 0.41 4 7/13/19 23:06 BRF 1,1,2-Trichloroethane ND 0.20 0.082 ND 1.1 0.45 4 7/13/19 23:06 BRF Trichloroethylene 1.2 0.20 0.081 6.3 1.1 0.43 4 7/13/19 23:06 BRF Trichlorofluoromethane (Freon 11) 7.5 0.80 0.12 42 4.5 0.65 4 7/13/19 23:06 BRF 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) ND 0.80 0.12 ND 6.1 0.93 4 7/13/19 23:06 BRF 1,2,4-Trimethylbenzene ND 0.20 0.13 ND 0.98 0.63 4 7/13/19 23:06 BRF 1,3,5-Trimethylbenzene 0.40 0.20 0.13 2.0 0.98 0.62 4 7/13/19 23:06 BRF Vinyl Acetate ND 4.0 0.095 ND 14 0.34 4 7/13/19 23:06 BRF Vinyl Chloride ND 0.20 0.13 ND 0.51 0.32 4 7/13/19 23:06 BRF m&p-Xylene 4.1 0.40 0.23 18 1.7 1.00 4 7/13/19 23:06 BRF o-Xylene 1.3 0.20 0.12 5.5 0.87 0.54 4 7/13/19 23:06 BRF Surrogates 4-Bromofluorobenzene (1) % Recovery 89.2 % REC Limits 70-130 7/13/19 23:06 Page 9 of 39 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Gateway Sample Description/Location: Work Order: 19G0004 Date Received: 6/28/2019 Sub Description/Location: Initial Vacuum(in Hg): -28.5 Field Sample #: SS-1 Canister ID: 2097 Final Vacuum(in Hg): -5 Sample ID: 19G0004-03 Canister Size: 1 liter Receipt Vacuum(in Hg): -4.5 Sample Matrix: Sub Slab Flow Controller ID: 4069 Flow Controller Type: Fixed -Orifice Sampled: 6/28/2019 10:31 Sample Type: 5 min Flow Controller Calibration RPD Pre and Post -Sampling: Sample Flags: RL-11 Analyte Results ppbv RL EPA TO-15 MDL Flag/Qual Results ug/m3 RI MDL Dilution Date/Time Analyzed Analyst Acetone 400 40 14 940 95 33 20 7/14/19 3:17 BRF Benzene ND 1.0 0.41 ND 3.2 1.3 20 7/14/19 3:17 BRF Benzyl chloride ND 1.0 0.22 ND 5.2 1.1 20 7/14/19 3:17 BRF Bromodichloromethane ND 1.0 0.37 ND 6.7 2.5 20 7/14/19 3:17 BRF Bromoform ND 1.0 0.45 ND 10 4.7 20 7/14/19 3:17 BRF Bromomethane ND 1.0 0.69 ND 3.9 2.7 20 7/14/19 3:17 BRF 1,3-Butadiene ND 1.0 0.63 ND 2.2 1.4 20 7/14/19 3:17 BRF 2-Butanone (MEK) 51 40 1.6 150 120 4.6 20 7/14/19 3:17 BRF Carbon Disulfide ND 10 0.69 ND 31 2.1 20 7/14/19 3:17 BRF Carbon Tetrachloride ND 1.0 0.33 ND 6.3 2.1 20 7/14/19 3:17 BRF Chlorobenzene ND 1.0 0.49 ND 4.6 2.3 20 7/14/19 3:17 BRF Chloroethane ND 1.0 0.61 ND 2.6 1.6 20 7/14/19 3:17 BRF Chloroform ND 1.0 0.37 ND 4.9 1.8 20 7/14/19 3:17 BRF Chloromethane ND 2.0 0.68 L-03 ND 4.1 1.4 20 7/14/19 3:17 BRF Cyclohexane ND 1.0 0.71 ND 3.4 2.4 20 7/14/19 3:17 BRF Dibromochloromethane ND 1.0 0.33 ND 8.5 2.8 20 7/14/19 3:17 BRF 1,2-Dibromoethane (EDB) ND 1.0 0.39 ND 7.7 3.0 20 7/14/19 3:17 BRF 1,2-Dichlorobenzene ND 1.0 0.48 ND 6.0 2.9 20 7/14/19 3:17 BRF 1,3-Dichlorobenzene ND 1.0 0.52 ND 6.0 3.1 20 7/14/19 3:17 BRF 1,4-Dichlorobenzene ND 1.0 0.61 ND 6.0 3.7 20 7/14/19 3:17 BRF Dichlorodifluoromethane (Freon 12) ND 1.0 0.43 L-03, V-05 ND 4.9 2.1 20 7/14/19 3:17 BRF 1,1-Dichloroethane ND 1.0 0.30 ND 4.0 1.2 20 7/14/19 3:17 BRF 1,2-Dichloroethane ND 1.0 0.38 ND 4.0 1.5 20 7/14/19 3:17 BRF 1,1-Dichloroethylene ND 1.0 0.41 ND 4.0 1.6 20 7/14/19 3:17 BRF cis-1,2-Dichloroethylene ND 1.0 0.41 ND 4.0 1.6 20 7/14/19 3:17 BRF trans-1,2-Dichloroethylene ND 1.0 0.41 ND 4.0 1.6 20 7/14/19 3:17 BRF 1,2-Dichloropropane ND 1.0 0.35 ND 4.6 1.6 20 7/14/19 3:17 BRF cis- 1,3 -Dichloropropene ND 1.0 0.35 ND 4.5 1.6 20 7/14/19 3:17 BRF trans- 1, 3 -Dichloropropene ND 1.0 0.36 ND 4.5 1.7 20 7/14/19 3:17 BRF 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) ND 1.0 0.50 ND 7.0 3.5 20 7/14/19 3:17 BRF 1,4-Dioxane ND 10 6.4 ND 36 23 20 7/14/19 3:17 BRF Ethanol 610 80 36 1200 150 67 40 7/14/19 11:40 BRF Ethyl Acetate ND 1.0 0.75 ND 3.6 2.7 20 7/14/19 3:17 BRF Ethylbenzene 1.1 1.0 0.58 4.9 4.3 2.5 20 7/14/19 3:17 BRF 4-Ethyltoluene ND 1.0 0.61 ND 4.9 3.0 20 7/14/19 3:17 BRF Heptane ND 1.0 0.59 ND 4.1 2.4 20 7/14/19 3:17 BRF Hexachlorobutadiene ND 1.0 0.46 ND 11 4.9 20 7/14/19 3:17 BRF Hexane ND 40 1.8 ND 140 6.2 20 7/14/19 3:17 BRF 2-Hexanone (MBK) ND 1.0 0.59 ND 4.1 2.4 20 7/14/19 3:17 BRF Isopropanol 47 40 1.2 120 98 3.0 20 7/14/19 3:17 BRF Methyl tert-Butyl Ether (MTBE) ND 1.0 0.50 ND 3.6 1.8 20 7/14/19 3:17 BRF Methylene Chloride ND 10 1.2 ND 35 4.2 20 7/14/19 3:17 BRF 4-Methyl-2-pentanone (MIBK) ND 1.0 0.48 ND 4.1 2.0 20 7/14/19 3:17 BRF Naphthalene ND 1.0 0.77 V-05 ND 5.2 4.0 20 7/14/19 3:17 BRF Propene ND 40 0.99 V-05, Z-01 ND 69 1.7 20 7/14/19 3:17 BRF Styrene 1.2 1.0 0.62 4.9 4.3 2.6 20 7/14/19 3:17 BRF 1,1,2,2-Tetrachloroethane ND 1.0 0.44 ND 6.9 3.0 20 7/14/19 3:17 BRF Page 10 of 39 icon-tes w . ANALYTICAL LABORATORY Project Location: Gateway Date Received: 6/28/2019 Field Sample #: SS-1 Sample ID: 19G0004-03 Sample Matrix: Sub Slab Sampled: 6/28/2019 10:31 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 ANALYTICAL RESULTS Sample Description/Location: Sub Description/Location: Canister ID: 2097 Canister Size: 1 liter Flow Controller ID: 4069 Sample Type: 5 min Work Order: 19G0004 Initial Vacuum(in Hg): -28.5 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -4.5 Flow Controller Type: Fixed -Orifice Flow Controller Calibration RPD Pre and Post -Sampling: EPA TO-15 Sample Flags: RL-11 ppbv ug/m3 Date/Time Analyte Results RL MDL Flag/Qual Results RL MDL Dilution Analyzed Analyst Tetrachloroethylene 2.0 1.0 0.56 14 6.8 3.8 20 7/14/19 3:17 BRF Tetrahydrofuran ND 1.0 0.66 ND 2.9 2.0 20 7/14/19 3:17 BRF Toluene 14 1.0 0.52 54 3.8 1.9 20 7/14/19 3:17 BRF 1,2,4-Trichlorobenzene ND 1.0 0.69 V-05 ND 7.4 5.1 20 7/14/19 3:17 BRF 1, 1, 1 -Trichloroethane ND 1.0 0.37 ND 5.5 2.0 20 7/14/19 3:17 BRF 1,1,2-Trichloroethane ND 1.0 0.41 ND 5.5 2.2 20 7/14/19 3:17 BRF Trichloroethylene 0.86 1.0 0.40 J 4.6 5.4 2.2 20 7/14/19 3:17 BRF Trichlorofluoromethane (Freon 11) 11 4.0 0.58 62 22 3.3 20 7/14/19 3:17 BRF 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) ND 4.0 0.60 ND 31 4.6 20 7/14/19 3:17 BRF 1,2,4-Trimethylbenzene ND 1.0 0.64 ND 4.9 3.1 20 7/14/19 3:17 BRF 1,3,5-Trimethylbenzene ND 1.0 0.63 ND 4.9 3.1 20 7/14/19 3:17 BRF Vinyl Acetate ND 20 0.48 ND 70 1.7 20 7/14/19 3:17 BRF Vinyl Chloride ND 1.0 0.63 ND 2.6 1.6 20 7/14/19 3:17 BRF m&p-Xylene 4.9 2.0 1.2 21 8.7 5.0 20 7/14/19 3:17 BRF o-Xylene 1.5 1.0 0.62 6.7 4.3 2.7 20 7/14/19 3:17 BRF Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1) 4-Bromofluorobenzene (1) 93.8 70-130 86.1 70-130 7/14/19 11:40 7/14/19 3:17 Page 11 of 39 icon-tes w . ANALYTICAL LABORATORY Project Location: Gateway Date Received: 6/28/2019 Field Sample #: SS-2 Sample ID: 19G0004-04 Sample Matrix: Sub Slab Sampled: 6/28/2019 11:00 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 ANALYTICAL RESULTS Sample Description/Location: Work Order: 19G0004 Sub Description/Location: Initial Vacuum(in Hg): -29.5 Canister ID: 2094 Final Vacuum(in Hg): -4 Canister Size: 1 liter Receipt Vacuum(in Hg): -4.1 Flow Controller ID: 4368 Flow Controller Type: Fixed -Orifice Sample Type: 5 min Flow Controller Calibration RPD Pre and Post -Sampling: EPA TO-15 ppbv ug/m3 Date/Time Analyte Results RL MDL Flag/Qual Results RL MDL Dilution Analyzed Analyst Acetone 21 8.0 2.8 50 19 6.6 4 7/13/19 23:47 BRF Benzene 1.1 0.20 0.082 3.4 0.64 0.26 4 7/13/19 23:47 BRF Benzyl chloride ND 0.20 0.044 ND 1.0 0.23 4 7/13/19 23:47 BRF Bromodichloromethane ND 0.20 0.074 ND 1.3 0.49 4 7/13/19 23:47 BRF Bromoform ND 0.20 0.090 ND 2.1 0.93 4 7/13/19 23:47 BRF Bromomethane ND 0.20 0.14 ND 0.78 0.53 4 7/13/19 23:47 BRF 1,3-Butadiene ND 0.20 0.13 ND 0.44 0.28 4 7/13/19 23:47 BRF 2-Butanone (MEK) 3.2 8.0 0.31 J 9.5 24 0.92 4 7/13/19 23:47 BRF Carbon Disulfide ND 2.0 0.14 ND 6.2 0.43 4 7/13/19 23:47 BRF Carbon Tetrachloride ND 0.20 0.065 ND 1.3 0.41 4 7/13/19 23:47 BRF Chlorobenzene ND 0.20 0.098 ND 0.92 0.45 4 7/13/19 23:47 BRF Chloroethane ND 0.20 0.12 ND 0.53 0.32 4 7/13/19 23:47 BRF Chloroform ND 0.20 0.074 ND 0.98 0.36 4 7/13/19 23:47 BRF Chloromethane ND 0.40 0.14 L-03 ND 0.83 0.28 4 7/13/19 23:47 BRF Cyclohexane ND 0.20 0.14 ND 0.69 0.49 4 7/13/19 23:47 BRF Dibromochloromethane ND 0.20 0.066 ND 1.7 0.57 4 7/13/19 23:47 BRF 1,2-Dibromoethane (EDB) ND 0.20 0.078 ND 1.5 0.60 4 7/13/19 23:47 BRF 1,2-Dichlorobenzene ND 0.20 0.096 ND 1.2 0.58 4 7/13/19 23:47 BRF 1,3-Dichlorobenzene 0.25 0.20 0.10 1.5 1.2 0.62 4 7/13/19 23:47 BRF 1,4-Dichlorobenzene ND 0.20 0.12 ND 1.2 0.73 4 7/13/19 23:47 BRF Dichlorodifluoromethane (Freon 12) 0.26 0.20 0.087 L-03, V-05 1.3 0.99 0.43 4 7/13/19 23:47 BRF 1,1-Dichloroethane ND 0.20 0.061 ND 0.81 0.25 4 7/13/19 23:47 BRF 1,2-Dichloroethane ND 0.20 0.076 ND 0.81 0.31 4 7/13/19 23:47 BRF 1,1-Dichloroethylene ND 0.20 0.081 ND 0.79 0.32 4 7/13/19 23:47 BRF cis-1,2-Dichloroethylene ND 0.20 0.082 ND 0.79 0.32 4 7/13/19 23:47 BRF trans-1,2-Dichloroethylene ND 0.20 0.081 ND 0.79 0.32 4 7/13/19 23:47 BRF 1,2-Dichloropropane ND 0.20 0.071 ND 0.92 0.33 4 7/13/19 23:47 BRF cis- 1,3 -Dichloropropene ND 0.20 0.070 ND 0.91 0.32 4 7/13/19 23:47 BRF trans- 1, 3 -Dichloropropene ND 0.20 0.073 ND 0.91 0.33 4 7/13/19 23:47 BRF 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) ND 0.20 0.10 ND 1.4 0.70 4 7/13/19 23:47 BRF 1,4-Dioxane ND 2.0 1.3 ND 7.2 4.6 4 7/13/19 23:47 BRF Ethanol 44 8.0 3.6 84 15 6.7 4 7/13/19 23:47 BRF Ethyl Acetate 0.75 0.20 0.15 2.7 0.72 0.54 4 7/13/19 23:47 BRF Ethylbenzene 1.5 0.20 0.12 6.4 0.87 0.50 4 7/13/19 23:47 BRF 4-Ethyltoluene 0.78 0.20 0.12 3.8 0.98 0.60 4 7/13/19 23:47 BRF Heptane 0.60 0.20 0.12 2.5 0.82 0.48 4 7/13/19 23:47 BRF Hexachlorobutadiene ND 0.20 0.092 ND 2.1 0.98 4 7/13/19 23:47 BRF Hexane 1.1 8.0 0.35 J 3.9 28 1.2 4 7/13/19 23:47 BRF 2-Hexanone (MBK) ND 0.20 0.12 ND 0.82 0.48 4 7/13/19 23:47 BRF Isopropanol 4.7 8.0 0.25 J 11 20 0.60 4 7/13/19 23:47 BRF Methyl tert-Butyl Ether (MTBE) ND 0.20 0.10 ND 0.72 0.36 4 7/13/19 23:47 BRF Methylene Chloride 0.27 2.0 0.24 J 0.93 6.9 0.84 4 7/13/19 23:47 BRF 4-Methyl-2-pentanone (MIBK) ND 0.20 0.096 ND 0.82 0.39 4 7/13/19 23:47 BRF Naphthalene 0.67 0.20 0.15 V-05 3.5 1.0 0.80 4 7/13/19 23:47 BRF Propene ND 8.0 0.20 V-05, Z-01 ND 14 0.34 4 7/13/19 23:47 BRF Styrene 1.5 0.20 0.12 6.2 0.85 0.53 4 7/13/19 23:47 BRF 1,1,2,2-Tetrachloroethane ND 0.20 0.089 ND 1.4 0.61 4 7/13/19 23:47 BRF Page 12 of 39 icon-tes w . ANALYTICAL LABORATORY Project Location: Gateway Date Received: 6/28/2019 Field Sample #: SS-2 Sample ID: 19G0004-04 Sample Matrix: Sub Slab Sampled: 6/28/2019 11:00 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 ANALYTICAL RESULTS Sample Description/Location: Sub Description/Location: Canister ID: 2094 Canister Size: 1 liter Flow Controller ID: 4368 Sample Type: 5 min Work Order: 19G0004 Initial Vacuum(in Hg): -29.5 Final Vacuum(in Hg): -4 Receipt Vacuum(in Hg): -4.1 Flow Controller Type: Fixed -Orifice Flow Controller Calibration RPD Pre and Post -Sampling: EPA TO-15 ppbv ug/m3 Date/Time Analyte Results RL MDL Flag/Qual Results RL MDL Dilution Analyzed Analyst Tetrachloroethylene 1.4 0.20 0.11 9.8 1.4 0.75 4 7/13/19 23:47 BRF Tetrahydrofuran 2.0 0.20 0.13 5.8 0.59 0.39 4 7/13/19 23:47 BRF Toluene 17 0.20 0.10 63 0.75 0.39 4 7/13/19 23:47 BRF 1,2,4-Trichlorobenzene ND 0.20 0.14 V-05 ND 1.5 1.0 4 7/13/19 23:47 BRF 1, 1, 1 -Trichloroethane ND 0.20 0.075 ND 1.1 0.41 4 7/13/19 23:47 BRF 1,1,2-Trichloroethane ND 0.20 0.082 ND 1.1 0.45 4 7/13/19 23:47 BRF Trichloroethylene 0.24 0.20 0.081 1.3 1.1 0.43 4 7/13/19 23:47 BRF Trichlorofluoromethane (Freon 11) 6.9 0.80 0.12 39 4.5 0.65 4 7/13/19 23:47 BRF 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) ND 0.80 0.12 ND 6.1 0.93 4 7/13/19 23:47 BRF 1,2,4-Trimethylbenzene ND 0.20 0.13 ND 0.98 0.63 4 7/13/19 23:47 BRF 1,3,5-Trimethylbenzene 0.60 0.20 0.13 2.9 0.98 0.62 4 7/13/19 23:47 BRF Vinyl Acetate ND 4.0 0.095 ND 14 0.34 4 7/13/19 23:47 BRF Vinyl Chloride ND 0.20 0.13 ND 0.51 0.32 4 7/13/19 23:47 BRF m&p-Xylene 7.0 0.40 0.23 30 1.7 1.00 4 7/13/19 23:47 BRF o-Xylene 2.2 0.20 0.12 9.6 0.87 0.54 4 7/13/19 23:47 BRF Surrogates 4-Bromofluorobenzene (1) % Recovery 88.0 % REC Limits 70-130 7/13/19 23:47 Page 13 of 39 icon-tes w . ANALYTICAL LABORATORY Project Location: Gateway Date Received: 6/28/2019 Field Sample #: SS-2d Sample ID: 19G0004-05 Sample Matrix: Sub Slab Sampled: 6/28/2019 11:06 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 ANALYTICAL RESULTS Sample Description/Location: Work Order: 19G0004 Sub Description/Location: Initial Vacuum(in Hg): -30 Canister ID: 2127 Final Vacuum(in Hg): -7 Canister Size: 1 liter Receipt Vacuum(in Hg): -6.5 Flow Controller ID: 4637 Flow Controller Type: Fixed -Orifice Sample Type: 5 min Flow Controller Calibration RPD Pre and Post -Sampling: EPA TO-15 ppbv ug/m3 Date/Time Analyte Results RL MDL Flag/Qual Results RL MDL Dilution Analyzed Analyst Acetone 18 8.0 2.8 42 19 6.6 4 7/14/19 0:29 BRF Benzene 0.60 0.20 0.082 1.9 0.64 0.26 4 7/14/19 0:29 BRF Benzyl chloride ND 0.20 0.044 ND 1.0 0.23 4 7/14/19 0:29 BRF Bromodichloromethane ND 0.20 0.074 ND 1.3 0.49 4 7/14/19 0:29 BRF Bromoform ND 0.20 0.090 ND 2.1 0.93 4 7/14/19 0:29 BRF Bromomethane ND 0.20 0.14 ND 0.78 0.53 4 7/14/19 0:29 BRF 1,3-Butadiene ND 0.20 0.13 ND 0.44 0.28 4 7/14/19 0:29 BRF 2-Butanone (MEK) 3.3 8.0 0.31 J 9.7 24 0.92 4 7/14/19 0:29 BRF Carbon Disulfide ND 2.0 0.14 ND 6.2 0.43 4 7/14/19 0:29 BRF Carbon Tetrachloride ND 0.20 0.065 ND 1.3 0.41 4 7/14/19 0:29 BRF Chlorobenzene ND 0.20 0.098 ND 0.92 0.45 4 7/14/19 0:29 BRF Chloroethane ND 0.20 0.12 ND 0.53 0.32 4 7/14/19 0:29 BRF Chloroform ND 0.20 0.074 ND 0.98 0.36 4 7/14/19 0:29 BRF Chloromethane ND 0.40 0.14 L-03 ND 0.83 0.28 4 7/14/19 0:29 BRF Cyclohexane ND 0.20 0.14 ND 0.69 0.49 4 7/14/19 0:29 BRF Dibromochloromethane ND 0.20 0.066 ND 1.7 0.57 4 7/14/19 0:29 BRF 1,2-Dibromoethane (EDB) ND 0.20 0.078 ND 1.5 0.60 4 7/14/19 0:29 BRF 1,2-Dichlorobenzene ND 0.20 0.096 ND 1.2 0.58 4 7/14/19 0:29 BRF 1,3-Dichlorobenzene 0.29 0.20 0.10 1.8 1.2 0.62 4 7/14/19 0:29 BRF 1,4-Dichlorobenzene ND 0.20 0.12 ND 1.2 0.73 4 7/14/19 0:29 BRF Dichlorodifluoromethane (Freon 12) ND 0.20 0.087 L-03, V-05 ND 0.99 0.43 4 7/14/19 0:29 BRF 1,1-Dichloroethane ND 0.20 0.061 ND 0.81 0.25 4 7/14/19 0:29 BRF 1,2-Dichloroethane ND 0.20 0.076 ND 0.81 0.31 4 7/14/19 0:29 BRF 1,1-Dichloroethylene ND 0.20 0.081 ND 0.79 0.32 4 7/14/19 0:29 BRF cis-1,2-Dichloroethylene ND 0.20 0.082 ND 0.79 0.32 4 7/14/19 0:29 BRF trans-1,2-Dichloroethylene ND 0.20 0.081 ND 0.79 0.32 4 7/14/19 0:29 BRF 1,2-Dichloropropane ND 0.20 0.071 ND 0.92 0.33 4 7/14/19 0:29 BRF cis- 1,3 -Dichloropropene ND 0.20 0.070 ND 0.91 0.32 4 7/14/19 0:29 BRF trans- 1, 3 -Dichloropropene ND 0.20 0.073 ND 0.91 0.33 4 7/14/19 0:29 BRF 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) ND 0.20 0.10 ND 1.4 0.70 4 7/14/19 0:29 BRF 1,4-Dioxane ND 2.0 1.3 ND 7.2 4.6 4 7/14/19 0:29 BRF Ethanol 32 8.0 3.6 60 15 6.7 4 7/14/19 0:29 BRF Ethyl Acetate ND 0.20 0.15 ND 0.72 0.54 4 7/14/19 0:29 BRF Ethylbenzene 0.99 0.20 0.12 4.3 0.87 0.50 4 7/14/19 0:29 BRF 4-Ethyltoluene 0.51 0.20 0.12 2.5 0.98 0.60 4 7/14/19 0:29 BRF Heptane 0.32 0.20 0.12 1.3 0.82 0.48 4 7/14/19 0:29 BRF Hexachlorobutadiene ND 0.20 0.092 ND 2.1 0.98 4 7/14/19 0:29 BRF Hexane ND 8.0 0.35 ND 28 1.2 4 7/14/19 0:29 BRF 2-Hexanone (MBK) ND 0.20 0.12 ND 0.82 0.48 4 7/14/19 0:29 BRF Isopropanol 3.9 8.0 0.25 J 9.6 20 0.60 4 7/14/19 0:29 BRF Methyl tert-Butyl Ether (MTBE) ND 0.20 0.10 ND 0.72 0.36 4 7/14/19 0:29 BRF Methylene Chloride 0.36 2.0 0.24 J 1.3 6.9 0.84 4 7/14/19 0:29 BRF 4-Methyl-2-pentanone (MIBK) ND 0.20 0.096 ND 0.82 0.39 4 7/14/19 0:29 BRF Naphthalene 0.70 0.20 0.15 V-05 3.7 1.0 0.80 4 7/14/19 0:29 BRF Propene ND 8.0 0.20 V-05, Z-01 ND 14 0.34 4 7/14/19 0:29 BRF Styrene 1.0 0.20 0.12 4.3 0.85 0.53 4 7/14/19 0:29 BRF 1,1,2,2-Tetrachloroethane ND 0.20 0.089 ND 1.4 0.61 4 7/14/19 0:29 BRF Page 14 of 39 icon-tes w . ANALYTICAL LABORATORY Project Location: Gateway Date Received: 6/28/2019 Field Sample #: SS-2d Sample ID: 19G0004-05 Sample Matrix: Sub Slab Sampled: 6/28/2019 11:06 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 ANALYTICAL RESULTS Sample Description/Location: Sub Description/Location: Canister ID: 2127 Canister Size: 1 liter Flow Controller ID: 4637 Sample Type: 5 min Work Order: 19G0004 Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -7 Receipt Vacuum(in Hg): -6.5 Flow Controller Type: Fixed -Orifice Flow Controller Calibration RPD Pre and Post -Sampling: EPA TO-15 ppbv ug/m3 Date/Time Analyte Results RL MDL Flag/Qual Results RL MDL Dilution Analyzed Analyst Tetrachloroethylene 2.0 0.20 0.11 13 1.4 0.75 4 7/14/19 0:29 BRF Tetrahydrofuran 1.6 0.20 0.13 4.7 0.59 0.39 4 7/14/19 0:29 BRF Toluene 12 0.20 0.10 47 0.75 0.39 4 7/14/19 0:29 BRF 1,2,4-Trichlorobenzene ND 0.20 0.14 V-05 ND 1.5 1.0 4 7/14/19 0:29 BRF 1, 1, 1 -Trichloroethane ND 0.20 0.075 ND 1.1 0.41 4 7/14/19 0:29 BRF 1,1,2-Trichloroethane ND 0.20 0.082 ND 1.1 0.45 4 7/14/19 0:29 BRF Trichloroethylene 0.31 0.20 0.081 1.7 1.1 0.43 4 7/14/19 0:29 BRF Trichlorofluoromethane (Freon 11) 7.6 0.80 0.12 43 4.5 0.65 4 7/14/19 0:29 BRF 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) ND 0.80 0.12 ND 6.1 0.93 4 7/14/19 0:29 BRF 1,2,4-Trimethylbenzene ND 0.20 0.13 ND 0.98 0.63 4 7/14/19 0:29 BRF 1,3,5-Trimethylbenzene 0.42 0.20 0.13 2.1 0.98 0.62 4 7/14/19 0:29 BRF Vinyl Acetate ND 4.0 0.095 ND 14 0.34 4 7/14/19 0:29 BRF Vinyl Chloride ND 0.20 0.13 ND 0.51 0.32 4 7/14/19 0:29 BRF m&p-Xylene 4.6 0.40 0.23 20 1.7 1.00 4 7/14/19 0:29 BRF o-Xylene 1.4 0.20 0.12 6.2 0.87 0.54 4 7/14/19 0:29 BRF Surrogates 4-Bromofluorobenzene (1) % Recovery 87.8 % REC Limits 70-130 7/14/19 0:29 Page 15 of 39 icon-tes w . ANALYTICAL LABORATORY Project Location: Gateway Date Received: 6/28/2019 Field Sample #: SS-4 Sample ID: 19G0004-06 Sample Matrix: Sub Slab Sampled: 6/28/2019 11:27 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 ANALYTICAL RESULTS Sample Description/Location: Work Order: 19G0004 Sub Description/Location: Initial Vacuum(in Hg): -28.5 Canister ID: 2105 Final Vacuum(in Hg): -5 Canister Size: 1 liter Receipt Vacuum(in Hg): -6.1 Flow Controller ID: 4213 Flow Controller Type: Fixed -Orifice Sample Type: 5 min Flow Controller Calibration RPD Pre and Post -Sampling: EPA TO-15 ppbv ug/m3 Date/Time Analyte Results RL MDL Flag/Qual Results RL MDL Dilution Analyzed Analyst Acetone 33 8.0 2.8 78 19 6.6 4 7/14/19 1:10 BRF Benzene 0.88 0.20 0.082 2.8 0.64 0.26 4 7/14/19 1:10 BRF Benzyl chloride ND 0.20 0.044 ND 1.0 0.23 4 7/14/19 1:10 BRF Bromodichloromethane ND 0.20 0.074 ND 1.3 0.49 4 7/14/19 1:10 BRF Bromoform ND 0.20 0.090 ND 2.1 0.93 4 7/14/19 1:10 BRF Bromomethane ND 0.20 0.14 ND 0.78 0.53 4 7/14/19 1:10 BRF 1,3-Butadiene ND 0.20 0.13 ND 0.44 0.28 4 7/14/19 1:10 BRF 2-Butanone (MEK) 4.2 8.0 0.31 J 12 24 0.92 4 7/14/19 1:10 BRF Carbon Disulfide ND 2.0 0.14 ND 6.2 0.43 4 7/14/19 1:10 BRF Carbon Tetrachloride ND 0.20 0.065 ND 1.3 0.41 4 7/14/19 1:10 BRF Chlorobenzene ND 0.20 0.098 ND 0.92 0.45 4 7/14/19 1:10 BRF Chloroethane ND 0.20 0.12 ND 0.53 0.32 4 7/14/19 1:10 BRF Chloroform ND 0.20 0.074 ND 0.98 0.36 4 7/14/19 1:10 BRF Chloromethane ND 0.40 0.14 L-03 ND 0.83 0.28 4 7/14/19 1:10 BRF Cyclohexane ND 0.20 0.14 ND 0.69 0.49 4 7/14/19 1:10 BRF Dibromochloromethane ND 0.20 0.066 ND 1.7 0.57 4 7/14/19 1:10 BRF 1,2-Dibromoethane (EDB) ND 0.20 0.078 ND 1.5 0.60 4 7/14/19 1:10 BRF 1,2-Dichlorobenzene ND 0.20 0.096 ND 1.2 0.58 4 7/14/19 1:10 BRF 1,3-Dichlorobenzene ND 0.20 0.10 ND 1.2 0.62 4 7/14/19 1:10 BRF 1,4-Dichlorobenzene ND 0.20 0.12 ND 1.2 0.73 4 7/14/19 1:10 BRF Dichlorodifluoromethane (Freon 12) 0.28 0.20 0.087 L-03, V-05 1.4 0.99 0.43 4 7/14/19 1:10 BRF 1,1-Dichloroethane ND 0.20 0.061 ND 0.81 0.25 4 7/14/19 1:10 BRF 1,2-Dichloroethane ND 0.20 0.076 ND 0.81 0.31 4 7/14/19 1:10 BRF 1,1-Dichloroethylene ND 0.20 0.081 ND 0.79 0.32 4 7/14/19 1:10 BRF cis-1,2-Dichloroethylene ND 0.20 0.082 ND 0.79 0.32 4 7/14/19 1:10 BRF trans-1,2-Dichloroethylene ND 0.20 0.081 ND 0.79 0.32 4 7/14/19 1:10 BRF 1,2-Dichloropropane ND 0.20 0.071 ND 0.92 0.33 4 7/14/19 1:10 BRF cis- 1,3 -Dichloropropene ND 0.20 0.070 ND 0.91 0.32 4 7/14/19 1:10 BRF trans- 1, 3 -Dichloropropene ND 0.20 0.073 ND 0.91 0.33 4 7/14/19 1:10 BRF 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) ND 0.20 0.10 ND 1.4 0.70 4 7/14/19 1:10 BRF 1,4-Dioxane ND 2.0 1.3 ND 7.2 4.6 4 7/14/19 1:10 BRF Ethanol 50 8.0 3.6 95 15 6.7 4 7/14/19 1:10 BRF Ethyl Acetate 0.68 0.20 0.15 2.5 0.72 0.54 4 7/14/19 1:10 BRF Ethylbenzene 1.4 0.20 0.12 6.1 0.87 0.50 4 7/14/19 1:10 BRF 4-Ethyltoluene 0.58 0.20 0.12 2.9 0.98 0.60 4 7/14/19 1:10 BRF Heptane 0.43 0.20 0.12 1.8 0.82 0.48 4 7/14/19 1:10 BRF Hexachlorobutadiene ND 0.20 0.092 ND 2.1 0.98 4 7/14/19 1:10 BRF Hexane 0.60 8.0 0.35 J 2.1 28 1.2 4 7/14/19 1:10 BRF 2-Hexanone (MBK) ND 0.20 0.12 ND 0.82 0.48 4 7/14/19 1:10 BRF Isopropanol 4.1 8.0 0.25 J 10 20 0.60 4 7/14/19 1:10 BRF Methyl tert-Butyl Ether (MTBE) ND 0.20 0.10 ND 0.72 0.36 4 7/14/19 1:10 BRF Methylene Chloride 0.47 2.0 0.24 J 1.6 6.9 0.84 4 7/14/19 1:10 BRF 4-Methyl-2-pentanone (MIBK) ND 0.20 0.096 ND 0.82 0.39 4 7/14/19 1:10 BRF Naphthalene 0.60 0.20 0.15 V-05 3.1 1.0 0.80 4 7/14/19 1:10 BRF Propene ND 8.0 0.20 V-05, Z-01 ND 14 0.34 4 7/14/19 1:10 BRF Styrene 1.3 0.20 0.12 5.4 0.85 0.53 4 7/14/19 1:10 BRF 1,1,2,2-Tetrachloroethane ND 0.20 0.089 ND 1.4 0.61 4 7/14/19 1:10 BRF Page 16 of 39 icon-tes w . ANALYTICAL LABORATORY Project Location: Gateway Date Received: 6/28/2019 Field Sample #: SS-4 Sample ID: 19G0004-06 Sample Matrix: Sub Slab Sampled: 6/28/2019 11:27 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 ANALYTICAL RESULTS Sample Description/Location: Sub Description/Location: Canister ID: 2105 Canister Size: 1 liter Flow Controller ID: 4213 Sample Type: 5 min Work Order: 19G0004 Initial Vacuum(in Hg): -28.5 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -6.1 Flow Controller Type: Fixed -Orifice Flow Controller Calibration RPD Pre and Post -Sampling: EPA TO-15 ppbv ug/m3 Date/Time Analyte Results RL MDL Flag/Qual Results RL MDL Dilution Analyzed Analyst Tetrachloroethylene 3.9 0.20 0.11 26 1.4 0.75 4 7/14/19 1:10 BRF Tetrahydrofuran 6.5 0.20 0.13 19 0.59 0.39 4 7/14/19 1:10 BRF Toluene 17 0.20 0.10 63 0.75 0.39 4 7/14/19 1:10 BRF 1,2,4-Trichlorobenzene ND 0.20 0.14 V-05 ND 1.5 1.0 4 7/14/19 1:10 BRF 1, 1, 1 -Trichloroethane ND 0.20 0.075 ND 1.1 0.41 4 7/14/19 1:10 BRF 1,1,2-Trichloroethane ND 0.20 0.082 ND 1.1 0.45 4 7/14/19 1:10 BRF Trichloroethylene ND 0.20 0.081 ND 1.1 0.43 4 7/14/19 1:10 BRF Trichlorofluoromethane (Freon 11) 7.0 0.80 0.12 39 4.5 0.65 4 7/14/19 1:10 BRF 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) ND 0.80 0.12 ND 6.1 0.93 4 7/14/19 1:10 BRF 1,2,4-Trimethylbenzene ND 0.20 0.13 ND 0.98 0.63 4 7/14/19 1:10 BRF 1,3,5-Trimethylbenzene 0.46 0.20 0.13 2.2 0.98 0.62 4 7/14/19 1:10 BRF Vinyl Acetate ND 4.0 0.095 ND 14 0.34 4 7/14/19 1:10 BRF Vinyl Chloride ND 0.20 0.13 ND 0.51 0.32 4 7/14/19 1:10 BRF m&p-Xylene 6.3 0.40 0.23 28 1.7 1.00 4 7/14/19 1:10 BRF o-Xylene 1.9 0.20 0.12 8.2 0.87 0.54 4 7/14/19 1:10 BRF Surrogates 4-Bromofluorobenzene (1) % Recovery 86.2 % REC Limits 70-130 7/14/19 1:10 Page 17 of 39 icon-tes w . ANALYTICAL LABORATORY Project Location: Gateway Date Received: 6/28/2019 Field Sample #: SS-3 Sample ID: 19G0004-07 Sample Matrix: Sub Slab Sampled: 6/28/2019 11:43 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 ANALYTICAL RESULTS Sample Description/Location: Work Order: 19G0004 Sub Description/Location: Initial Vacuum(in Hg): -29 Canister ID: 2117 Final Vacuum(in Hg): -5 Canister Size: 1 liter Receipt Vacuum(in Hg): -5.2 Flow Controller ID: 4210 Flow Controller Type: Fixed -Orifice Sample Type: 5 min Flow Controller Calibration RPD Pre and Post -Sampling: EPA TO-15 ppbv ug/m3 Date/Time Analyte Results RL MDL Flag/Qual Results RL MDL Dilution Analyzed Analyst Acetone 43 8.0 2.8 100 19 6.6 4 7/15/19 14:54 BRF Benzene 1.1 0.20 0.082 3.5 0.64 0.26 4 7/15/19 14:54 BRF Benzyl chloride ND 0.20 0.044 ND 1.0 0.23 4 7/15/19 14:54 BRF Bromodichloromethane ND 0.20 0.074 ND 1.3 0.49 4 7/15/19 14:54 BRF Bromoform ND 0.20 0.090 ND 2.1 0.93 4 7/15/19 14:54 BRF Bromomethane ND 0.20 0.14 ND 0.78 0.53 4 7/15/19 14:54 BRF 1,3-Butadiene ND 0.20 0.13 ND 0.44 0.28 4 7/15/19 14:54 BRF 2-Butanone (MEK) 6.2 8.0 0.31 J 18 24 0.92 4 7/15/19 14:54 BRF Carbon Disulfide ND 2.0 0.14 ND 6.2 0.43 4 7/15/19 14:54 BRF Carbon Tetrachloride ND 0.20 0.065 ND 1.3 0.41 4 7/15/19 14:54 BRF Chlorobenzene ND 0.20 0.098 ND 0.92 0.45 4 7/15/19 14:54 BRF Chloroethane ND 0.20 0.12 ND 0.53 0.32 4 7/15/19 14:54 BRF Chloroform ND 0.20 0.074 ND 0.98 0.36 4 7/15/19 14:54 BRF Chloromethane ND 0.40 0.14 L-03, V-05 ND 0.83 0.28 4 7/15/19 14:54 BRF Cyclohexane ND 0.20 0.14 ND 0.69 0.49 4 7/15/19 14:54 BRF Dibromochloromethane ND 0.20 0.066 ND 1.7 0.57 4 7/15/19 14:54 BRF 1,2-Dibromoethane (EDB) ND 0.20 0.078 ND 1.5 0.60 4 7/15/19 14:54 BRF 1,2-Dichlorobenzene ND 0.20 0.096 ND 1.2 0.58 4 7/15/19 14:54 BRF 1,3-Dichlorobenzene 0.41 0.20 0.10 2.5 1.2 0.62 4 7/15/19 14:54 BRF 1,4-Dichlorobenzene ND 0.20 0.12 ND 1.2 0.73 4 7/15/19 14:54 BRF Dichlorodifluoromethane (Freon 12) 0.35 0.20 0.087 L-03 1.7 0.99 0.43 4 7/15/19 14:54 BRF 1,1-Dichloroethane ND 0.20 0.061 ND 0.81 0.25 4 7/15/19 14:54 BRF 1,2-Dichloroethane ND 0.20 0.076 ND 0.81 0.31 4 7/15/19 14:54 BRF 1,1-Dichloroethylene ND 0.20 0.081 ND 0.79 0.32 4 7/15/19 14:54 BRF cis-1,2-Dichloroethylene ND 0.20 0.082 ND 0.79 0.32 4 7/15/19 14:54 BRF trans-1,2-Dichloroethylene ND 0.20 0.081 ND 0.79 0.32 4 7/15/19 14:54 BRF 1,2-Dichloropropane ND 0.20 0.071 ND 0.92 0.33 4 7/15/19 14:54 BRF cis- 1,3 -Dichloropropene ND 0.20 0.070 ND 0.91 0.32 4 7/15/19 14:54 BRF trans- 1, 3 -Dichloropropene ND 0.20 0.073 ND 0.91 0.33 4 7/15/19 14:54 BRF 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) ND 0.20 0.10 ND 1.4 0.70 4 7/15/19 14:54 BRF 1,4-Dioxane ND 2.0 1.3 ND 7.2 4.6 4 7/15/19 14:54 BRF Ethanol 62 8.0 3.6 120 15 6.7 4 7/15/19 14:54 BRF Ethyl Acetate ND 0.20 0.15 ND 0.72 0.54 4 7/15/19 14:54 BRF Ethylbenzene 1.4 0.20 0.12 6.3 0.87 0.50 4 7/15/19 14:54 BRF 4-Ethyltoluene ND 0.20 0.12 ND 0.98 0.60 4 7/15/19 14:54 BRF Heptane ND 0.20 0.12 ND 0.82 0.48 4 7/15/19 14:54 BRF Hexachlorobutadiene ND 0.20 0.092 ND 2.1 0.98 4 7/15/19 14:54 BRF Hexane 1.0 8.0 0.35 J 3.6 28 1.2 4 7/15/19 14:54 BRF 2-Hexanone (MBK) ND 0.20 0.12 ND 0.82 0.48 4 7/15/19 14:54 BRF Isopropanol 4.7 8.0 0.25 J 12 20 0.60 4 7/15/19 14:54 BRF Methyl tert-Butyl Ether (MTBE) ND 0.20 0.10 ND 0.72 0.36 4 7/15/19 14:54 BRF Methylene Chloride 0.43 2.0 0.24 J 1.5 6.9 0.84 4 7/15/19 14:54 BRF 4-Methyl-2-pentanone (MIBK) ND 0.20 0.096 ND 0.82 0.39 4 7/15/19 14:54 BRF Naphthalene 0.82 0.20 0.15 4.3 1.0 0.80 4 7/15/19 14:54 BRF Propene ND 8.0 0.20 V-05, Z-01 ND 14 0.34 4 7/15/19 14:54 BRF Styrene 1.3 0.20 0.12 5.6 0.85 0.53 4 7/15/19 14:54 BRF 1,1,2,2-Tetrachloroethane ND 0.20 0.089 ND 1.4 0.61 4 7/15/19 14:54 BRF Page 18 of 39 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Gateway Sample Description/Location: Work Order: 19G0004 Date Received: 6/28/2019 Sub Description/Location: Initial Vacuum(in Hg): -29 Field Sample #: SS-3 Canister ID: 2117 Final Vacuum(in Hg): -5 Sample ID: 19G0004-07 Canister Size: 1 liter Receipt Vacuum(in Hg): -5.2 Sample Matrix: Sub Slab Flow Controller ID: 4210 Flow Controller Type: Fixed -Orifice Sampled: 6/28/2019 11:43 Sample Type: 5 min Flow Controller Calibration RPD Pre and Post -Sampling: Analyte Results ppbv RL EPA TO-15 MDL Flag/Qual Results ug/m3 RL MDL Dilution Date/Time Analyzed Analyst Tetrachloroethylene 1.1 0.20 0.11 7.7 1.4 0.75 4 7/15/19 14:54 BRF Tetrahydrofuran 5.1 0.20 0.13 15 0.59 0.39 4 7/15/19 14:54 BRF Toluene 20 0.20 0.10 74 0.75 0.39 4 7/15/19 14:54 BRF 1,2,4-Trichlorobenzene ND 0.20 0.14 ND 1.5 1.0 4 7/15/19 14:54 BRF 1, 1, 1 -Trichloroethane ND 0.20 0.075 ND 1.1 0.41 4 7/15/19 14:54 BRF 1,1,2-Trichloroethane ND 0.20 0.082 ND 1.1 0.45 4 7/15/19 14:54 BRF Trichloroethylene ND 0.20 0.081 ND 1.1 0.43 4 7/15/19 14:54 BRF Trichlorofluoromethane (Freon 11) 6.8 0.80 0.12 38 4.5 0.65 4 7/15/19 14:54 BRF 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) ND 0.80 0.12 ND 6.1 0.93 4 7/15/19 14:54 BRF 1,2,4-Trimethylbenzene ND 0.20 0.13 ND 0.98 0.63 4 7/15/19 14:54 BRF 1,3,5-Trimethylbenzene 0.54 0.20 0.13 2.6 0.98 0.62 4 7/15/19 14:54 BRF Vinyl Acetate ND 4.0 0.095 ND 14 0.34 4 7/15/19 14:54 BRF Vinyl Chloride ND 0.20 0.13 ND 0.51 0.32 4 7/15/19 14:54 BRF m&p-Xylene 6.9 0.40 0.23 30 1.7 1.00 4 7/15/19 14:54 BRF o-Xylene 2.0 0.20 0.12 8.7 0.87 0.54 4 7/15/19 14:54 BRF Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1) 91.9 70-130 7/15/19 14:54 Page 19 of 39 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 Sample Extraction Data Prep Method: TO-15 Prep -EPA TO-15 Pre-Dil Pre-Dil Default Actual Pressure Pre Initial Final Injection Injection Lab Number [Field ID] Batch Dilution Dilution mL mL mL mL Date 19G0004-01 [SS-5] B235524 1.5 1 N/A 1000 400 150 07/13/19 19G0004-02[SS-6] B235524 1.5 1 N/A 1000 400 150 07/13/19 19G0004-03 [SS-1] B235524 1.5 1 N/A 1000 400 30 07/13/19 19G0004-03RE1 [SS-1] B235524 1.5 1 N/A 1000 400 15 07/13/19 19G0004-04[SS-2] B235524 1.5 1 N/A 1000 400 150 07/13/19 19G0004-05 [SS-2d] B235524 1.5 1 N/A 1000 400 150 07/13/19 19G0004-06[SS-4] B235524 1.5 1 N/A 1000 400 150 07/13/19 Prep Method: TO-15 Prep -EPA TO-15 Pre-Dil Pre-Dil Default Actual Pressure Pre Initial Final Injection Injection Lab Number [Field ID] Batch Dilution Dilution mL mL mL mL Date 19G0004-07[SS-3] B235552 4 1 N/A 1000 400 400 07/15/19 Page 20 of 39 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 QUALITY CONTROL Air Toxics by EPA Compendium Methods - Quality Control ppbv ug/m3 Spike Level Source %REC RPD malyte Results RL Results RL ppbv Result %REC Limits RPD Limit Flag/Qua Batch B235524 - TO-15 Prep Blank (B235524-BLK1) Prepared & Analyzed: 07/13/19 Acetone ND 1.4 Benzene ND 0.035 Benzyl chloride ND 0.035 Bromodichloromethane ND 0.035 Bromoform ND 0.035 Bromomethane ND 0.035 1,3-Butadiene ND 0.035 2-Butanone (MEK) ND 1.4 Carbon Disulfide ND 0.35 Carbon Tetrachloride ND 0.035 Chlorobenzene ND 0.035 Chloroethane ND 0.035 Chloroform ND 0.035 Chloromethane ND 0.070 L-03 Cyclohexane ND 0.035 Dibromochloromethane ND 0.035 1,2-Dibromoethane (EDB) ND 0.035 1,2-Dichlorobenzene ND 0.035 1,3-Dichlorobenzene ND 0.035 1,4-Dichlorobenzene ND 0.035 Dichlorodifluoromethane (Freon 12) ND 0.035 L-03, V-05 1,1-Dichloroethane ND 0.035 1,2-Dichloroethane ND 0.035 1,1-Dichloroethylene ND 0.035 cis-1,2-Dichloroethylene ND 0.035 trans-1,2-Dichloroethylene ND 0.035 1,2-Dichloropropane ND 0.035 cis- 1,3 -Dichloropropene ND 0.035 trans- l,3-Dichloropropene ND 0.035 1,2-Dichloro- 1, 1,2,2-tetrafluoroethane ND 0.035 (Freon 114) 1,4-Dioxane ND 0.35 Ethanol ND 1.4 Ethyl Acetate ND 0.035 Ethylbenzene ND 0.035 4-Ethyltoluene ND 0.035 Heptane ND 0.035 Hexachlorobutadiene ND 0.035 Hexane ND 1.4 2-Hexanone (MBK) ND 0.035 Isopropanol ND 1.4 Methyl tert-Butyl Ether (MTBE) ND 0.035 Methylene Chloride ND 0.35 4-Methyl-2-pentanone (MIBK) ND 0.035 Naphthalene ND 0.035 V-05 Propene ND 1.4 V-05, Z-01 Styrene ND 0.035 Page 21 of 39 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 QUALITY CONTROL Air Toxics by EPA Compendium Methods - Quality Control ppbv ug/m3 Spike Level Source %REC RPD \nalyte Results RL Results RL ppbv Result %REC Limits RPD Limit Flag/Qua] Batch B235524 - TO-15 Prep Blank (B235524-BLKI) Prepared & Analyzed: 07/13/19 1,1,2,2-Tetrachloroethane ND 0.035 Tetrachloroethylene ND 0.035 Tetrahydrofuran ND 0.035 Toluene ND 0.035 1,2,4-Trichlorobenzene ND 0.035 V-Of 1, 1, 1 -Trichloroethane ND 0.035 1,1,2-Trichloroethane ND 0.035 Trichloroethylene ND 0.035 Trichlorofluoromethane (Freon 11) ND 0.14 1, 1,2-Trichloro- 1,2,2-trifluoroethane (Freon ND 0.14 113) 1,2,4-Trimethylbenzene ND 0.035 1,3,5-Trimethylbenzene ND 0.035 Vinyl Acetate ND 0.70 Vinyl Chloride ND 0.035 m&p-Xylene ND 0.070 o-Xylene ND 0.035 Surrogate: 4-Bromofluorobenzene (1) LCS (B235524-BS1) 7.16 8.00 89.5 Prepared & Analyzed: 07/13/19 70-130 Acetone 5.00 5.00 100 70-130 Benzene 5.52 5.00 110 70-130 Benzyl chloride 6.66 5.00 133 * 70-130 L-01 Bromodichloromethane 5.40 5.00 108 70-130 Bromoform 5.17 5.00 103 70-130 Bromomethane 4.24 5.00 84.8 70-130 1,3-Butadiene 4.35 5.00 87.0 70-130 2-Butanone (MEK) 5.07 5.00 101 70-130 Carbon Disulfide 5.66 5.00 113 70-130 Carbon Tetrachloride 4.61 5.00 92.2 70-130 Chlorobenzene 5.53 5.00 111 70-130 Chloroethane 4.32 5.00 86.3 70-130 Chloroform 4.96 5.00 99.2 70-130 Chloromethane 3.28 5.00 65.5 * 70-130 L-03 Cyclohexane 5.27 5.00 105 70-130 Dibromochloromethane 5.02 5.00 100 70-130 1,2-Dibromoethane (EDB) 5.77 5.00 115 70-130 1,2-Dichlorobenzene 5.31 5.00 106 70-130 1,3-Dichlorobenzene 5.51 5.00 110 70-130 1,4-Dichlorobenzene 5.44 5.00 109 70-130 Dichlorodifluoromethane (Freon 12) 2.89 5.00 57.9 * 70-130 L-03, V-05 1,1-Dichloroethane 4.96 5.00 99.1 70-130 1,2-Dichloroethane 5.15 5.00 103 70-130 1, 1 -Dichloroethylene 4.90 5.00 98.0 70-130 cis-1,2-Dichloroethylene 4.81 5.00 96.2 70-130 trans-1,2-Dichloroethylene 5.22 5.00 104 70-130 1,2-Dichloropropane 5.25 5.00 105 70-130 Page 22 of 39 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 QUALITY CONTROL Air Toxics by EPA Compendium Methods - Quality Control ppbv ug/m3 Spike Level Source %REC RPD \nalyte Results RL Results RL ppbv Result %REC Limits RPD Limit Flag/Qua] Batch B235524 - TO-15 Prep LCS (B235524-BSI) Prepared & Analyzed: 07/13/19 cis-1,3-Dichloropropene 5.63 5.00 113 70-130 trans-1,3-Dichloropropene 5.93 5.00 119 70-130 1,2-Dichloro- 1, 1,2,2-tetrafluoroethane 3.66 5.00 73.1 70-130 (Freon 114) 1,4-Dioxane 5.73 5.00 115 70-130 Ethanol 5.72 5.00 114 70-130 Ethyl Acetate 4.21 5.00 84.2 70-130 Ethylbenzene 5.87 5.00 117 70-130 4-Ethyltoluene 5.96 5.00 119 70-130 Heptane 5.55 5.00 ill 70-130 Hexachlorobutadiene 4.15 5.00 82.9 70-130 Hexane 5.47 5.00 109 70-130 2-Hexanone (MBK) 6.24 5.00 125 70-130 Isopropanol 4.37 5.00 87.4 70-130 Methyl tert-Butyl Ether (MTBE) 5.14 5.00 103 70-130 Methylene Chloride 4.63 5.00 92.6 70-130 4-Methyl-2-pentanone (MIBK) 5.35 5.00 107 70-130 Naphthalene 4.90 5.00 98.1 70-130 V-0'- Propene 2.83 5.00 56.5 * 70-130 Z-01, V-Of Styrene 5.86 5.00 117 70-130 1,1,2,2-Tetrachloroethane 6.12 5.00 122 70-130 Tetrachloroethylene 4.85 5.00 97.0 70-130 Tetrahydrofuran 5.48 5.00 110 70-130 Toluene 6.08 5.00 122 70-130 1,2,4-Trichlorobenzene 4.77 5.00 95.5 70-130 V-Of 1, 1, 1 -Trichloroethane 4.76 5.00 95.2 70-130 1,1,2-Trichloroethane 5.94 5.00 119 70-130 Trichloroethylene 5.16 5.00 103 70-130 Trichlorofluoromethane (Freon 11) 4.46 5.00 89.1 70-130 1, 1,2-Trichloro- 1,2,2-trifluoroethane (Freon 4.73 5.00 94.6 70-130 113) 1,2,4-Trimethylbenzene 5.86 5.00 117 70-130 1,3,5-Trimethylbenzene 5.96 5.00 119 70-130 Vinyl Acetate 9.82 5.00 196 * 70-130 V-36,L-01 Vinyl Chloride 3.84 5.00 76.8 70-130 m&p-Xylene 12.8 10.0 128 70-130 o-Xylene 6.17 5.00 123 70-130 Surrogate: 4-Bromofluorobenzene (1) 7.51 8.00 93.8 70-130 Page 23 of 39 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 QUALITY CONTROL Air Toxics by EPA Compendium Methods - Quality Control ppbv ug/m3 Spike Level Source %REC RPD malyte Results RL Results RL ppbv Result %REC Limits RPD Limit Flag/Qua Batch B235552 - TO-15 Prep Blank (B235552-BLKI) Prepared & Analyzed: 07/15/19 Acetone ND 1.4 Benzene ND 0.035 Benzyl chloride ND 0.035 Bromodichloromethane ND 0.035 Bromoform ND 0.035 Bromomethane ND 0.035 1,3-Butadiene ND 0.035 2-Butanone (MEK) ND 1.4 Carbon Disulfide ND 0.35 Carbon Tetrachloride ND 0.035 Chlorobenzene ND 0.035 Chloroethane ND 0.035 Chloroform ND 0.035 Chloromethane ND 0.070 L-03, V-05 Cyclohexane ND 0.035 Dibromochloromethane ND 0.035 1,2-Dibromoethane (EDB) ND 0.035 1,2-Dichlorobenzene ND 0.035 1,3-Dichlorobenzene ND 0.035 1,4-Dichlorobenzene ND 0.035 Dichlorodifluoromethane (Freon 12) ND 0.035 L-03 1,1-Dichloroethane ND 0.035 1,2-Dichloroethane ND 0.035 1,1-Dichloroethylene ND 0.035 cis-1,2-Dichloroethylene ND 0.035 trans-1,2-Dichloroethylene ND 0.035 1,2-Dichloropropane ND 0.035 cis- 1,3 -Dichloropropene ND 0.035 trans- 1, 3 -Dichloropropene ND 0.035 1,2-Dichloro- 1, 1,2,2-tetrafluoroethane ND 0.035 (Freon 114) 1,4-Dioxane ND 0.35 Ethanol ND 1.4 Ethyl Acetate ND 0.035 Ethylbenzene ND 0.035 4-Ethyltoluene ND 0.035 Heptane ND 0.035 Hexachlorobutadiene ND 0.035 Hexane ND 1.4 2-Hexanone (MBK) ND 0.035 Isopropanol ND 1.4 Methyl tert-Butyl Ether (MTBE) ND 0.035 Methylene Chloride ND 0.35 4-Methyl-2-pentanone (MIBK) ND 0.035 Naphthalene ND 0.035 Propene ND 1.4 V-05,Z-01 Styrene ND 0.035 Page 24 of 39 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 QUALITY CONTROL Air Toxics by EPA Compendium Methods - Quality Control ppbv ug/m3 Spike Level Source %REC RPD \nalyte Results RL Results RL ppbv Result %REC Limits RPD Limit Flag/Qua] Batch B235552 - TO-15 Prep Blank (B235552-BLKI) Prepared & Analyzed: 07/15/19 1,1,2,2-Tetrachloroethane ND 0.035 Tetrachloroethylene ND 0.035 Tetrahydrofuran ND 0.035 Toluene ND 0.035 1,2,4-Trichlorobenzene ND 0.035 1, 1, 1 -Trichloroethane ND 0.035 1,1,2-Trichloroethane ND 0.035 Trichloroethylene ND 0.035 Trichlorofluoromethane (Freon 11) ND 0.14 1, 1,2-Trichloro- 1,2,2-trifluoroethane (Freon ND 0.14 113) 1,2,4-Trimethylbenzene ND 0.035 1,3,5-Trimethylbenzene ND 0.035 Vinyl Acetate ND 0.70 Vinyl Chloride ND 0.035 m&p-Xylene ND 0.070 o-Xylene ND 0.035 Surrogate: 4-Bromofluorobenzene (1) LCS (B235552-BS1) 7.32 8.00 91.5 Prepared & Analyzed: 07/15/19 70-130 Acetone 4.79 5.00 95.8 70-130 Benzene 4.46 5.00 89.1 70-130 Benzyl chloride 5.54 5.00 ill 70-130 Bromodichloromethane 4.72 5.00 94.5 70-130 Bromoform 4.62 5.00 92.3 70-130 Bromomethane 4.74 5.00 94.9 70-130 1,3-Butadiene 4.32 5.00 86.3 70-130 2-Butanone (MEK) 4.61 5.00 92.2 70-130 Carbon Disulfide 5.99 5.00 120 70-130 Carbon Tetrachloride 4.30 5.00 85.9 70-130 Chlorobenzene 4.74 5.00 94.7 70-130 Chloroethane 4.44 5.00 88.8 70-130 Chloroform 5.45 5.00 109 70-130 Chloromethane 3.24 5.00 64.7 * 70-130 L-03, V-05 Cyclohexane 4.34 5.00 86.8 70-130 Dibromochloromethane 4.44 5.00 88.8 70-130 1,2-Dibromoethane (EDB) 4.93 5.00 98.7 70-130 1,2-Dichlorobenzene 4.80 5.00 96.1 70-130 1,3-Dichlorobenzene 4.89 5.00 97.7 70-130 1,4-Dichlorobenzene 4.89 5.00 97.8 70-130 Dichlorodifluoromethane (Freon 12) 3.12 5.00 62.4 * 70-130 L-03 1,1-Dichloroethane 4.95 5.00 98.9 70-130 1,2-Dichloroethane 5.54 5.00 ill 70-130 1,1-Dichloroethylene 4.78 5.00 95.5 70-130 cis-1,2-Dichloroethylene 4.64 5.00 92.8 70-130 trans-1,2-Dichloroethylene 5.02 5.00 100 70-130 1,2-Dichloropropane 3.94 5.00 78.8 70-130 Page 25 of 39 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 QUALITY CONTROL Air Toxics by EPA Compendium Methods - Quality Control ppbv ug/m3 Spike Level Source %REC RPD \nalyte Results RL Results RL ppbv Result %REC Limits RPD Limit Flag/Qua] Batch B235552 - TO-15 Prep LCS (B235552-BS1) Prepared & Analyzed: 07/15/19 cis-1,3-Dichloropropene 4.52 5.00 90.4 70-130 trans-1,3-Dichloropropene 4.83 5.00 96.6 70-130 1,2-Dichloro- 1, 1,2,2-tetrafluoroethane 4.07 5.00 81.5 70-130 (Freon 114) 1,4-Dioxane 5.12 5.00 102 70-130 Ethanol 5.52 5.00 110 70-130 Ethyl Acetate 3.82 5.00 76.4 70-130 Ethylbenzene 4.72 5.00 94.4 70-130 4-Ethyltoluene 5.18 5.00 104 70-130 Heptane 4.05 5.00 80.9 70-130 Hexachlorobutadiene 3.88 5.00 77.5 70-130 Hexane 4.92 5.00 98.4 70-130 2-Hexanone (MBK) 4.11 5.00 82.3 70-130 Isopropanol 3.95 5.00 79.0 70-130 Methyl tert-Butyl Ether (MTBE) 5.31 5.00 106 70-130 Methylene Chloride 4.51 5.00 90.3 70-130 4-Methyl-2-pentanone (MIBK) 4.04 5.00 80.7 70-130 Naphthalene 4.46 5.00 89.3 70-130 Propene 2.75 5.00 54.9 * 70-130 Z-01, V-Of Styrene 4.85 5.00 97.0 70-130 1,1,2,2-Tetrachloroethane 4.98 5.00 99.6 70-130 Tetrachloroethylene 4.18 5.00 83.7 70-130 Tetrahydrofuran 4.76 5.00 95.3 70-130 Toluene 4.81 5.00 96.2 70-130 1,2,4-Trichlorobenzene 4.46 5.00 89.3 70-130 1, 1, 1 -Trichloroethane 4.35 5.00 87.1 70-130 1,1,2-Trichloroethane 4.97 5.00 99.3 70-130 Trichloroethylene 4.37 5.00 87.5 70-130 Trichlorofluoromethane (Freon 11) 5.16 5.00 103 70-130 1, 1,2-Trichloro- 1,2,2-trifluoroethane (Freon 5.36 5.00 107 70-130 113) 1,2,4-Trimethylbenzene 5.00 5.00 99.9 70-130 1,3,5-Trimethylbenzene 5.09 5.00 102 70-130 Vinyl Acetate 6.94 5.00 139 * 70-130 V-36,L-01 Vinyl Chloride 3.92 5.00 78.4 70-130 m&p-Xylene 9.70 10.0 97.0 70-130 o-Xylene 5.07 5.00 101 70-130 Surrogate: 4-Bromofluorobenzene (1) 7.55 8.00 94.4 70-130 Page 26 of 39 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 * FAX 413/525-6405 " TEL. 413/525-2332 FLAG/QUALIFIER SUMMARY * QC result is outside of established limits. t Wide recovery limits established for difficult compound. $ Wide RPD limits established for difficult compound. # Data exceeded client recommended or regulatory level RL Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference LCS Laboratory Control Sample LCS Dup Duplicate Laboratory Control Sample MS Matrix Spike Sample MS Dup Duplicate Matrix Spike Sample REC Recovery QC Quality Control ppbv Parts per billion volume EPA United States Environmental Protection Agency % REC Percent Recovery ND Not Detected N/A Not Applicable DL Detection Limit NC Not Calculated LFB/LCS Lab Fortified Blank/Lab Control Sample ORP Oxidation -Reduction Potential wet Not dry weight corrected % wt Percent weight Kg Kilogram g Gram mg Milligram µg Microgram ng Nanogram L Liter mL Milliliter µL Microliter m3 Cubic Meter EPH Extractable Petroleum Hydrocarbons VPH Volatile Petroleum Hydrocarbons APH Air Petroleum Hydrocarbons FID Flame Ionization Detector PID Photo Ionization Detector Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the calculation which have not been rounded. J Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag). L-01 Laboratory fortified blank /laboratory control sample recovery outside of control limits. Data validation is not affected since all results are "not detected" for all samples in this batch for this compound and bias is on the high side. L-03 Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this compound is likely to be biased on the low side. RL-11 Elevated reporting limit due to high concentration of target compounds. V-05 Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for this compound. V-20 Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was "not detected" for this compound. V-36 Initial calibration verification (ICV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was "not detected" for this compound. Z-01 Compound fails the method requirement of 70-130% recovery for the LCS. Is classified by the lab as a difficult compound and passes the in house limits of 50-150%. Page 27 of 39 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 ANALYST TPH Thomas P. Hnitecki RAP Raisa A. Petraitis STATION PDF Management Station KKM Kerry K. McGee BRF Brittany R. Fisk Page 28 of 39 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 INTERNAL STANDARD AREAAND RT SUMMARY EPA TO-15 Internal Standard Response RT Reference Response Reference RT Area % Area o/ Limits RT Diff RT Diff Limit Q Initial Cal Check (S035866-ICV1) Lab File ID: F1913421.13 Analyzed: 05/15/19 07:19 Bromochloromethane (1) 220675 8.627 224825 8.624 98 60 - 140 0.0030 +/-0.50 1,4-Difluorobenzene (1) 904687 10.392 914686 10.389 99 60 - 140 0.0030 +/-0.50 Chlorobenzene-d5(1) 842982 14.756 837686 14.755 101 60-140 0.0010 +/-0.50 INTERNAL STANDARD AREAAND RT SUMMARY EPA TO-15 Internal Standard Response RT Reference Response Reference RT Area % Area o/ Limits RT Diff RT Diff Limit Q Calibration Check (S038082-CCV1) Lab File ID: F1919409.13 Analyzed: 07/13/19 16:57 Bromochloromethane (1) 234978 8.624 224825 8.624 105 60 - 140 0.0000 +/-0.50 1,4-Difluorobenzene (1) 934941 10.389 914686 10.389 102 60 - 140 0.0000 +/-0.50 Chlorobenzene-d5(1) 810325 14.752 837686 14.755 97 60-140 -0.0030 +/-0.50 LCS (B235524-BS1 ) Lab File ID: F1919410.13 Analyzed: 07/13/19 17:37 Bromochloromethane (1) 226132 8.627 234978 8.624 96 60 - 140 0.0030 +/-0.50 1,4-Difluorobenzene(1) 835140 10.392 934941 10.389 89 60-140 0.0030 +/-0.50 Chlorobenzene-d5(1) 705235 14.752 810325 14.752 87 60-140 0.0000 +/-0.50 Blank (B235524-BLK1) Lab File ID: F1919414.13 Analyzed: 07/13/19 20:25 Bromochloromethane (1) 217060 8.627 234978 8.624 92 60 - 140 0.0030 +/-0.50 1,4-Difluorobenzene(1) 845204 10.389 934941 10.389 90 60-140 0.0000 +/-0.50 Chlorobenzene-d5(1) 768267 14.752 810325 14.752 95 60-140 0.0000 +/-0.50 SS-5 (19G0004-01 ) Lab File ID: F1919417.13 Analyzed: 07/13/19 22:26 Bromochloromethane (1) 215224 8.627 234978 8.624 92 60 - 140 0.0030 +/-0.50 1,4-Difluorobenzene(1) 831557 10.389 934941 10.389 89 60-140 0.0000 +/-0.50 Chlorobenzene-d5(1) 730599 14.749 810325 14.752 90 60-140 -0.0030 +/-0.50 SS-6 (19G0004-02 ) Lab File ID: F1919418.13 Analyzed: 07/13/19 23:06 Bromochloromethane (1) 206029 8.627 234978 8.624 88 60 - 140 0.0030 +/-0.50 1,4-Difluorobenzene(1) 843783 10.389 934941 10.389 90 60-140 0.0000 +/-0.50 Chlorobenzene-d5(1) 756738 14.749 810325 14.752 93 60-140 -0.0030 +/-0.50 SS-2 (19G0004-04) Lab File ID: F1919419.1) Analyzed: 07/13/19 23:47 Bromochloromethane (1) 195807 8.624 234978 8.624 83 60 - 140 0.0000 +/-0.50 1,4-Difluorobenzene(1) 839300 10.389 934941 10.389 90 60-140 0.0000 +/-0.50 Chlorobenzene-d5(1) 743884 14.749 810325 14.752 92 60-140 -0.0030 +/-0.50 SS-2d (19G0004-05) Lab File ID: F1919420.1) Analyzed: 07/14/19 00:29 Bromochloromethane (1) 190102 8.624 234978 8.624 81 60 - 140 0.0000 +/-0.50 1,4-Difluorobenzene(1) 835230 10.389 934941 10.389 89 60-140 0.0000 +/-0.50 Chlorobenzene-d5(1) 737340 14.749 810325 14.752 91 60-140 -0.0030 +/-0.50 Page 29 of 39 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 INTERNAL STANDARD AREAAND RT SUMMARY EPA TO-15 Internal Standard Response RT Reference Response Reference RT Area % Area o/ Limits RT Diff RT Diff Limit Q SS-4 (19G0004-06) Lab File ID: F1919421.D Analyzed: 07/14/19 0 1: 10 Bromochloromethane (1) 187397 8.627 234978 8.624 80 60 - 140 0.0030 +/-0.50 1,4-Difluorobenzene (1) 821748 10.389 934941 10.389 88 60 - 140 0.0000 +/-0.50 Chlorobenzene-d5(1) 731423 14.749 810325 14.752 90 60-140 -0.0030 +/-0.50 SS-1 (19G0004-03) Lab File ID: F1919424.D Analyzed: 07/14/19 03:17 Bromochloromethane (1) 167356 8.621 234978 8.624 71 60 - 140 -0.0030 +/-0.50 1,4-Difluorobenzene (1) 801674 10.389 934941 10.389 86 60 - 140 0.0000 +/-0.50 Chlorobenzene-d5(1) 710602 14.749 810325 14.752 88 60-140 -0.0030 +/-0.50 SS-1 (19G0004-03RE1) Lab File ID: F1919435.D Analyzed: 07/14/19 11:40 Bromochloromethane (1) 165890 8.624 234978 8.624 71 60 - 140 0.0000 +/-0.50 1,4-Difluorobenzene(1) 708257 10.389 934941 10.389 76 60-140 0.0000 +/-0.50 Chlorobenzene-d5(1) 617779 14.749 810325 14.752 76 60-140 -0.0030 +/-0.50 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 Internal Standard Response RT Reference Response Reference RT Area % Area % Limits RT Diff RT Diff Limit Q Calibration Check (S038102-CCV1) Lab File ID: F1919604.D Analyzed: 07/15/19 10:41 Bromochloromethane (1) 176423 8.624 224825 8.624 78 60 - 140 0.0000 +/-0.50 1,4-Difluorobenzene(1) 793878 10.392 914686 10.389 87 60-140 0.0030 +/-0.50 Chlorobenzene-d5(1) 700127 14.752 837686 14.755 84 60-140 -0.0030 +/-0.50 LCS (B235552-BS1) Lab File ID: F1919606.D Analyzed: 07/15/19 12:01 Bromochloromethane (1) 165290 8.624 176423 8.624 94 60 - 140 0.0000 +/-0.50 1,4-Difluorobenzene(1) 772282 10.392 793878 10.392 97 60-140 0.0000 +/-0.50 Chlorobenzene-d5(1) 685933 14.752 700127 14.752 98 60-140 0.0000 +/-0.50 Blank (B235552-BLK1) Lab File ID: F1919609.D Analyzed: 07/15/19 14:06 Bromochloromethane (1) 154277 8.627 176423 8.624 87 60 - 140 0.0030 +/-0.50 1,4-Difluorobenzene(1) 726282 10.389 793878 10.392 91 60-140 -0.0030 +/-0.50 Chlorobenzene-d5(1) 649044 14.752 700127 14.752 93 60-140 0.0000 +/-0.50 SS-3 (19G0004-07 ) Lab File ID: F1919610.D Analyzed: 07/15/19 14:54 Bromochloromethane (1) 157556 8.624 176423 8.624 89 60 - 140 0.0000 +/-0.50 1,4-Difluorobenzene(1) 733632 10.392 793878 10.392 92 60-140 0.0000 +/-0.50 Chlorobenzene-d5(1) 665260 14.749 700127 14.752 95 60-140 -0.0030 +/-0.50 Page 30 of 39 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street' East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S038082-CCV 1 COMPOUND TYPE CONC. (ppbv) RESPONSE FACTOR % DIFF / DRIFT STD CCV ICAL CCV MIN (#) CCV LIMIT (#) Acetone A 5.00 4.07 1.134293 0.9222991 -18.7 30 Benzene A 5.00 5.07 0.5688217 0.5767945 1.4 30 Benzyl chloride A 5.00 4.61 0.7404793 0.6822843 -7.9 30 Bromodichloromethane A 5.00 4.98 0.4444491 0.4426581 -0.4 30 Bromoform A 5.00 4.31 0.5091155 0.4386645 -13.8 30 Bromomethane A 5.00 4.20 0.9958814 0.8375184 -15.9 30 1,3-Butadiene A 5.00 4.25 0.6515652 0.5535837 -15.0 30 2-Butanone (MEK) A 5.00 4.58 1.161511 1.06301 -8.5 30 Carbon Disulfide A 5.00 5.35 1.981312 2.121274 7.1 30 Carbon Tetrachloride A 5.00 4.42 0.4566571 0.4034257 -11.7 30 Chlorobenzene A 5.00 4.75 0.7255923 0.6892879 -5.0 30 Chloroethane A 5.00 4.20 0.4347076 0.3656172 -15.9 30 Chloroform A 5.00 4.83 1.662216 1.606401 -3.4 30 Chloromethane A 5.00 4.16 1.093038 0.9086808 -16.9 30 Cyclohexane A 5.00 4.90 0.2571574 0.2521759 -1.9 30 Dibromochloromethane A 5.00 4.37 0.5817998 0.5086927 -12.6 30 1,2-Dibromoethane (EDB) A 5.00 4.94 0.4605409 0.4554874 -1.1 30 1,2-Dichlorobenzene A 5.00 3.87 0.6508703 0.5041098 -22.5 30 1,3-Dichlorobenzene A 5.00 4.17 0.6933458 0.5783773 -16.6 30 1,4-Dichlorobenzene A 5.00 4.04 0.7007496 0.5657878 -19.3 30 Dichlorodifluoromethane (Freon 12) A 5.00 3.44 2.828668 1.944659 -31.3 30 1,1-Dichloroethane A 5.00 4.77 1.297848 1.238836 -4.5 30 1,2-Dichloroethane A 5.00 5.04 0.9119952 0.9189013 0.8 30 1,1-Dichloroethylene A 5.00 4.90 1.101545 1.079148 -2.0 30 cis-1,2-Dichloroethylene A 5.00 4.84 0.9051853 0.8760173 -3.2 30 trans-1,2-Dichloroethylene A 5.00 5.06 0.911153 0.9211143 1.1 30 1,2-Dichloropropane A 5.00 4.76 0.20536 0.1955905 -4.8 30 cis- 1,3 -Dichloropropene A 5.00 5.34 0.3167588 0.3385797 6.9 30 trans- l,3-Dichloropropene A 5.00 5.21 0.2726974 0.2840821 4.2 30 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 1 A 5.00 3.89 2.970822 2.310317 -22.2 30 1,4-Dioxane A 5.00 4.81 0.1168036 0.1123391 -3.8 30 Ethanol A 5.00 6.36 0.1561683 0.1985411 27.1 30 Ethyl Acetate A 5.00 4.07 0.2328644 0.189662 -18.6 30 Ethylbenzene A 5.00 5.15 1.009823 1.039828 3.0 30 4-Ethyltoluene A 5.00 5.06 1.106453 1.118737 1.1 30 Heptane A 5.00 5.25 0.1466615 0.1541162 5.1 30 Hexachlorobutadiene A 5.00 3.62 0.4191439 0.3032857 -27.6 30 Hexane L 5.00 5.41 0.6733638 0.6810646 8.2 30 Page 31 of 39 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street' East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S038082-CCV 1 COMPOUND TYPE CONC. (ppbv) RESPONSE FACTOR % DIFF / DRIFT STD CCV ICAL CCV MIN (#) CCV LIMIT (#) 2-Hexanone(MBK) A 5.00 5.15 0.3284249 0.3384321 3.0 30 Isopropanol A 5.00 4.94 1.145292 1.132606 -1.1 30 Methyl tert-Butyl Ether (MTBE) A 5.00 4.98 1.917484 1.910409 -0.4 30 Methylene Chloride A 5.00 4.70 0.7579443 0.7124275 -6.0 30 4-Methyl-2-pentanone (MI13K) A 5.00 4.63 0.1500871 0.138923 -7.4 30 Naphthalene A 5.00 3.23 1.081685 0.699427 -35.3 30 Propene A 5.00 2.89 1.230285 0.7112836 -42.2 30 Styrene A 5.00 5.47 0.5798817 0.6345207 9.4 30 1,1,2,2-Tetrachloroethane A 5.00 4.91 0.6005027 0.5895886 -1.8 30 Tetrachloroethylene A 5.00 4.27 0.4261708 0.3638698 -14.6 30 Tetrahydroforan A 5.00 4.90 0.5608926 0.5501315 -1.9 30 Toluene A 5.00 5.30 0.7831786 0.8296957 5.9 30 1,2,4-Trichlorobenzene A 5.00 3.03 0.4950118 0.2997138 -39.5 30 1, 1, 1 -Trichloroethane A 5.00 4.80 0.4218366 0.4050412 -4.0 30 1,1,2-Trichloroethane A 5.00 5.18 0.2891513 0.2995697 3.6 30 Trichloroethylene A 5.00 4.67 0.2879883 0.2691541 6.5 30 Trichlorofluoromethane (Freon 11) A 5.00 4.42 2.158739 1.907229 -11.7 30 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 11 A 5.00 4.67 1.801742 1.68444 -6.5 30 1,2,4-Trimethylbenzene A 5.00 4.77 0.9388077 0.8961935 -4.5 30 1,3,5-Trimethylbenzene A 5.00 5.02 0.9351272 0.9380454 0.3 30 Vinyl Acetate A 5.00 9.44 0.9347802 1.764094 88.7 30 Vinyl Chloride A 5.00 3.88 1.06039 0.8239069 -22.3 30 m&p-Xylene A 10.0 11.0 0.789232 0.8709078 10.3 30 o-Xylene A 5.00 5.28 0.7966748 0.8419871 5.7 30 # Column to be used to flag Response Factor and %Diff/Drift values with an asterisk * Values outside of QC limits Page 32 of 39 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street' East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S038102-CCV 1 COMPOUND TYPE CONC. (ppbv) RESPONSE FACTOR % DIFF / DRIFT STD CCV ICAL CCV MIN (#) CCV LIMIT (#) Acetone A 5.00 4.27 1.134293 0.9694065 -14.5 30 Benzene A 5.00 4.86 0.5688217 0.5530905 -2.8 30 Benzyl chloride A 5.00 6.36 0.7404793 0.9418223 27.2 30 Bromodichloromethane A 5.00 5.22 0.4444491 0.4637428 4.3 30 Bromoform A 5.00 5.19 0.5091155 0.5280642 3.7 30 Bromomethane A 5.00 5.00 0.9958814 0.9955165 -0.04 30 1,3-Butadiene A 5.00 4.41 0.6515652 0.5748275 -11.8 30 2-Butanone (MEK) A 5.00 4.65 1.161511 1.079778 -7.0 30 Carbon Disulfide A 5.00 5.98 1.981312 2.368245 19.5 30 Carbon Tetrachloride A 5.00 4.96 0.4566571 0.4528897 -0.8 30 Chlorobenzene A 5.00 5.12 0.7255923 0.743072 2.4 30 Chloroethane A 5.00 4.69 0.4347076 0.4076929 -6.2 30 Chloroform A 5.00 5.67 1.662216 1.885877 13.5 30 Chloromethane A 5.00 3.49 1.093038 0.7637099 -30.1 30 Cyclohexane A 5.00 4.72 0.2571574 0.2425824 -5.7 30 Dibromochloromethane A 5.00 4.90 0.5817998 0.5704954 -1.9 30 1,2-Dibromoethane (EDB) A 5.00 5.27 0.4605409 0.4853451 5.4 30 1,2-Dichlorobenzene A 5.00 5.22 0.6508703 0.6801463 4.5 30 1,3-Dichlorobenzene A 5.00 5.44 0.6933458 0.7541512 8.8 30 1,4-Dichlorobenzene A 5.00 5.29 0.7007496 0.7410198 5.7 30 Dichlorodifluoromethane (Freon 12) A 5.00 4.20 2.828668 2.379091 -15.9 30 1,1-Dichloroethane A 5.00 5.14 1.297848 1.332915 2.7 30 1,2-Dichloroethane A 5.00 5.80 0.9119952 1.057595 16.0 30 1,1-Dichloroethylene A 5.00 5.09 1.101545 1.121205 1.8 30 cis-1,2-Dichloroethylene A 5.00 4.91 0.9051853 0.8887639 -1.8 30 trans-1,2-Dichloroethylene A 5.00 5.14 0.911153 0.9358598 2.7 30 1,2-Dichloropropane A 5.00 4.36 0.20536 0.1790502 -12.8 30 cis- 1,3 -Dichloropropene A 5.00 5.25 0.3167588 0.3324098 4.9 30 trans- l,3-Dichloropropene A 5.00 5.20 0.2726974 0.2837554 4.1 30 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 1 A 5.00 4.57 2.970822 2.715202 -8.6 30 1,4-Dioxane A 5.00 4.90 0.1168036 0.1144357 -2.0 30 Ethanol A 5.00 4.52 0.1561683 0.1412877 -9.5 30 Ethyl Acetate A 5.00 4.16 0.2328644 0.1935076 -16.9 30 Ethylbenzene A 5.00 5.16 1.009823 1.042725 3.3 30 4-Ethyltoluene A 5.00 5.57 1.106453 1.231797 11.3 30 Heptane A 5.00 4.73 0.1466615 0.1387276 -5.4 30 Hexachlorobutadiene 4 5.00 4.50 0.4191439 0.3769145 -10.1 30 Hexane L 5.00 5.36 0.6733638 0.675531 7.2 30 Page 33 of 39 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street' East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S038102-CCV 1 COMPOUND TYPE CONC. (ppbv) RESPONSE FACTOR % DIFF / DRIFT STD CCV ICAL CCV MIN (#) CCV LIMIT (#) 2-Hexanone(MBK) A 5.00 4.67 0.3284249 0.3068106 -6.6 30 Isopropanol A 5.00 4.22 1.145292 0.9663139 -15.6 30 Methyl tert-Butyl Ether (MTBE) A 5.00 5.47 1.917484 2.097078 9.4 30 Methylene Chloride A 5.00 4.86 0.7579443 0.7374186 -2.7 30 4-Methyl-2-pentanone (MI13K) A 5.00 4.43 0.1500871 0.1329393 -11.4 30 Naphthalene A 5.00 5.53 1.081685 1.1955 10.5 30 Propene A 5.00 2.97 1.230285 0.7313151 -40.6 30 Styrene A 5.00 6.05 0.5798817 0.701331 20.9 30 1,1,2,2-Tetrachloroethane A 5.00 5.60 0.6005027 0.6727717 12.0 30 Tetrachloroethylene A 5.00 4.60 0.4261708 0.3921963 -8.0 30 Tetrahydroforan A 5.00 4.88 0.5608926 0.5473844 -2.4 30 Toluene A 5.00 5.12 0.7831786 0.802451 2.5 30 1,2,4-Trichlorobenzene A 5.00 5.07 0.4950118 0.5016553 1.3 30 1, 1, 1 -Trichloroethane A 5.00 5.20 0.4218366 0.438546 4.0 30 1,1,2-Trichloroethane A 5.00 5.34 0.2891513 0.3090068 6.9 30 Trichloroethylene A 5.00 4.76 0.2879883 0.2743051 4.8 30 Trichlorofluoromethane (Freon 11) A 5.00 5.38 2.158739 2.32377 7.6 30 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 11 A 5.00 5.63 1.801742 2.027355 12.5 30 1,2,4-Trimethylbenzene A 5.00 5.54 0.9388077 1.039329 10.7 30 1,3,5-Trimethylbenzene A 5.00 5.68 0.9351272 1.063032 13.7 30 Vinyl Acetate A 5.00 7.91 0.9347802 1.478129 58.1 30 Vinyl Chloride A 5.00 4.10 1.06039 0.8703446 -17.9 30 m&p-Xylene A 10.0 10.8 0.789232 0.853444 8.1 30 o-Xylene A 5.00 5.60 0.7966748 0.8918382 11.9 30 # Column to be used to flag Response Factor and %Diff/Drift values with an asterisk * Values outside of QC limits Page 34 of 39 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ' FAX 413/525-6405 " TEL. 413/525-2332 CERTIFICATIONS Certified Analyses included in this Report Analyte EPA TO-15 in Air Acetone Benzene Benzyl chloride Bromodichloromethane Bromoform Bromomethane 1,3-Butadiene 2-Butanone (MEK) Carbon Disulfide Carbon Tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Cyclohexane Dibromochloromethane 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane (Freon 12) 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethylene cis-1,2-Dichloroethylene trans- l,2-Dichloro ethylene 1,2-Dichloropropane cis- 1,3 -Dichloropropene trans- 1, 3 -Dichloropropene 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 1,4-Dioxane Ethanol Ethyl Acetate Ethylbenzene 4-Ethyltoluene Heptane Hexachlorobutadiene Hexane 2-Hexanone (MBK) Isopropanol Methyl tart -Butyl Ether (MTBE) Methylene Chloride 4-Methyl-2-pentanone (MIBK) Naphthalene Propene Styrene 1,1,2,2-Tetrachloroethane Certifications AIHA,NY,ME,NH AIHA,FL,NJ,NY,ME,NH, VA AIHA,FL,NJ,NY,ME,NH, VA AIHA,NJ,NY,ME,NH,VA AIHA,NJ,NY,ME,NH,VA AIHA,FL,NJ,NY,ME,NH AIHA,NJ,NY,ME,NH,VA AIHA,FL,NJ,NY,ME,NH, VA AIHA,NJ,NY,ME,NH, VA AIHA,FL,NJ,NY,ME,NH, VA AIHA,FL,NJ,NY,ME,NH, VA AIHA,FL,NJ,NY,ME,NH, VA AIHA,FL,NJ,NY,ME,NH, VA AIHA,FL,NJ,NY,ME,NH, VA AIHA,NJ,NY,ME,NH,VA AIHA,NY,ME,NH AIHA,NJ,NY,ME,NH AIHA,FL,NJ,NY,ME,NH, VA AIHA,NJ,NY,ME,NH AIHA,FL,NJ,NY,ME,NH, VA AIHA,NY,ME,NH AIHA,FL,NJ,NY,ME,NH, VA AIHA,FL,NJ,NY,ME,NH, VA AIHA,FL,NJ,NY,ME,NH, VA AIHA,FL,NY,ME,NH,VA AIHA,NJ,NY,ME,NH,VA AIHA,FL,NJ,NY,ME,NH, VA AIHA,FL,NJ,NY,ME,NH, VA AIHA,NY,ME,NH AIHA,NJ,NY,ME,NH,VA AIHA,NJ,NY,ME,NH,VA AIHA AIHA AIHA,FL,NJ,NY,ME,NH, VA AIHA,NJ AIHA,NJ,NY,ME,NH,VA AIHA,NJ,NY,ME,NH,VA AIHA,FL,NJ,NY,ME,NH, VA AIHA AIHA,NY,ME,NH AIHA,FL,NJ,NY,ME,NH, VA AIHA,FL,NJ,NY,ME,NH, VA AIHA,FL,NJ,NY,ME,NH NY,ME,NH AIHA AIHA,FL,NJ,NY,ME,NH, VA AIHA,FL,NJ,NY,ME,NH,VA Page 35 of 39 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ' FAX 413/525-6405 " TEL. 413/525-2332 CERTIFICATIONS Certified Analyses included in this Report Analyte Certifications EPA TO-15 in Air Tetrachloroethylene AIHA,FL,NJ,NY,ME,NH,VA Tetrahydrofuran AIHA Toluene AIHA,FL,NJ,NYM E,NH,VA 1,2,4-Trichlorobenzene AIHA,NJ,NY,ME,NH,VA 1, 1, 1 -Trichloroethane AIHA,FL,NJ,NY,ME,NH,VA 1,1,2-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VA Trichloroethylene AIHA,FL,NJ,NY,ME,NH,VA Trichlorofluoromethane (Freon 11) AIHA,NY,ME,NH 1,1,2-Trichloro-1,2,2-ttifluoroethane (Freon 113) AIHA,NJ,NY,ME,NH,VA 1,2,4-Trimethylbenzene AIHA,NJ,NY,ME,NH 1,3,5-Trimethylbenzene AIHA,NJ,NY,ME,NH Vinyl Acetate AIHA,FLNJ,NY,ME,NH,VA Vinyl Chloride AIHA,FLNJ,NY,ME,NH,VA m&p-Xylene AIHA,FL,NJ,NY,ME,NH,VA o-Xylene AIHA,FL,NJ,NY,ME,NH,VA The CON -TEST Environmental Laboratory operates under the following certifications and accreditations: Code Description Number Expires AIHA AIHA-LAP, LLC - ISO17025:2005 100033 03/l/2020 MA Massachusetts DEP M-MA100 06/30/2020 CT Connecticut Department of Publilc Health PH-0567 09/30/2019 NY New York State Department of Health 10899 NELAP 04/l/2020 NH-S New Hampshire Environmental Lab 2516 NELAP 02/5/2020 RI Rhode Island Department of Health LA000112 12/30/2019 NC North Carolina Div. of Water Quality 652 12/31/2019 NJ New Jersey DEP MA007 NELAP 06/30/2020 FL Florida Department of Health E871027 NELAP 06/30/2020 VT Vermont Department of Health Lead Laboratory LL015036 07/30/2020 ME State of Maine 2011028 06/9/2021 VA Commonwealth of Virginia 460217 12/14/2019 NH-P New Hampshire Environmental Lab 2557 NELAP 09/6/2019 VT-DW Vermont Department of Health Drinking Water VT-255716 06/12/2020 NC-DW North Carolina Department of Health 25703 07/31/2019 PA Commonwealth of Pennsylvania DEP 68-05812 06/30/2020 Page 36 of 39 :E r (D 0 FccCL O ! .-.J r! 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Delivered Rjesday 7i02/Z2_019 at 12:54 pm FROM Raleigh, NC US Multiple -piece Shipment DELIVERED Sighed for by; BBATRAEDUS GET STATUS UPDATES OBTAIN PROOF OF DELIVERY 3 Piece shipment TO Last Lon gig icacin:r,-, MA US TRACIUNG Nl1IYi6ER SHIPPER CITY, SHIP DATE TATIJS DESTINATION/RECIPIENT STATE `AELIUERY DATE CITY, STATE 775597080799 �i�_�tU DURHAMa,NC 6/?H/2019 702120i9 E'ASTL0NG1AEAf')0W,MA ( �. 775597080983 DUF%'1 i .M, EEC 6/28/2W 9 7/02/2019 EAST LONGMSADCVv', MA 7755)97081317 DURI €Ah 1, tiC 6/28/20191 ?/02111�019 EAST L0IJGMEAD0kN, MA Shipment Facts TRACKING NUMBER SERVICE REFERENCE 77559 /080983 r edEx Ground 80 MASTER TRACKING NUMBER WEIGHT DIMENSIONS 775597080799 12 Ibs / S_44 kgs 19x E 4x1 C in. TOTAL PIECES TOTAL SHIPMENT WEIGHT TERMS 3 3O bs 11b.33 kg,, Th1rd !-aiv PACKAGING STANDARD TRANSIT SHIP DATE Package 0 7/02/2019 Fri 6/28/2019 77-1 hrips:llwww.fedex.com/apps/fedextrack/?action=track&tracknumbers=775597080983&locale=en_US&cntry_code=us Page 38 of 39 Received By 11 Date How were the samples In Cooler received? In Box Were samples within Temperature _ By Gun Compliance? 2-6°C By Bla Was Custody Seal Intact? Was COC Relinquished ? `[ Are there any loose caps/valves on any samples? Is COC in ink/ Legible? X D'd CO I 1 Client Analy i C nc ude a Pertinent Information? Project t Are Sample Labels filled out and legible? Are there Rushes? E Samples are received within holding time? Proper Media Used? Are there Trip Blanks? -T ID-- \1 C Time On lee No Ice Ambient Melted Ice # Actual Temp - nk # Actual Temp - Were Samples Tampered with? INAr Does Chain Agree With Samples? � ..�--- sis -7 Sampler Name 7- ID`s j Collection Dates/Times -T— Who was notified? Individually Certified Cans? .f Is there enough Volume? -( -- Summa Cans L 5n� Nut/Ferrule IC Train Tedlar Baqs Tubing TO-17 Tubes T-Connector Radiello S rin e PufsrrO-11 s I I TedIar APPENDIX B LABORATORY ANALYTICAL REPORT AND CHAIN -OF -CUSTODY RECORD FOR AMBIENT/INDOOR AIR SAMPLES IS Mid Atlantic icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 August 5, 2019 Katie Lippard Mid -Atlantic Associates, Inc. - Raleigh, NC 409 Rogers View Court Raleigh, NC 27610 Project Location: Raleigh, NC Client Job Number: Project Number: R2667.01 Laboratory Work Order Number: 19G1535 Enclosed are results of analyses for samples received by the laboratory on July 25, 2019. If you have any questions concerning this report, please feel free to contact me. Sincerely, I,&, �. A�� Kerry K. McGee Project Manager QA Officer Katherine Allen Laboratory Manager Daren Damboragian Page 1 of 23 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 Mid -Atlantic Associates, Inc. - Raleigh, NC REPORT DATE: 8/5/2019 409 Rogers View Court Raleigh, NC 27610 PURCHASE ORDER NUMBER: ATTN: Katie Lippard PROJECT NUMBER: R2667.01 ANALYTICAL SUMMARY WORK ORDER NUMBER: 19G1535 The results of analyses performed on the following samples submitted to the CON -TEST Analytical Laboratory are found in this report. PROJECT LOCATION: Raleigh, NC FIELD SAMPLE # LAB ID: MATRIX SAMPLE DESCRIPTION TEST SUB LAB IA-1 19G1535-01 Indoor air EPA TO-15 IA-2 19G1535-02 Indoor air EPA TO-15 IA-3 19G1535-03 Indoor air EPA TO-15 IA-4 19G1535-04 Indoor air EPA TO-15 AMB-1 19G1535-05 Ambient Air EPATO-15 IA-10 19G1535-06 Indoor air EPA TO-15 Page 2 of 23 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 CASE NARRATIVE SUMMARY All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report. EPA TO-15 Qualifications: Compound fails the method requirement of 70-l3O% recovery for the LCS. Is classified by the lab as a difficult compound and passes the in house limits of 50-150%. Analyte & Samples(s) Qualified: Naphthalene 19G1535-01[IA-1], 19G1535-02[IA-2], 19G1535-03[IA-3], 19G1535-04[IA-4], 19G1535-05[AMB-1], 19G1535-06[IA-10], B236986-BLKI, B236986-BSI The results of analyses reported only relate to samples submitted to the Con -Test Analytical Laboratory for testing. I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. d� Lisa A. Worthington Technical Representative Page 3 of 23 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Raleigh, NC Sample Description/Location: Work Order: 19G1535 Date Received: 7/25/2019 Sub Description/Location: Initial Vacuum(in Hg): -29 Field Sample #: IA-1 Canister ID: 1504 Final Vacuum(in Hg): -7.5 Sample ID: 19G1535-01 Canister Size: 6 liter Receipt Vacuum(in Hg): -7.4 Sample Matrix: Indoor air Flow Controller ID: 3099 Flow Controller Type: Fixed -Orifice Sampled: 7/24/2019 16:54 Sample Type: 8 hr Flow Controller Calibration RPD Pre and Post -Sampling: EPA TO-15 ppbv ug/m3 Date/Time Analyte Results RL MDL Flag/Qual Results ILL MDL Dilution Analyzed Analyst Acetone 33 1.4 0.49 79 3.3 1.2 0.702 7/31/19 18:59 BRF Benzene 0.11 0.035 0.014 0.36 0.11 0.046 0.702 7/31/19 18:59 BRF 2-Butanone (MEK) 42 8.0 0.31 120 24 0.92 4 8/1/19 9:07 BRF Carbon Disulfide ND 0.35 0.024 ND 1.1 0.075 0.702 7/31/19 18:59 BRF 1,3-Dichlorobenzene ND 0.035 0.018 ND 0.21 0.11 0.702 7/31/19 18:59 BRF Dichlorodifluoromethane (Freon 12) 0.47 0.035 0.015 2.3 0.17 0.075 0.702 7/31/19 18:59 BRF cis-1,2-Dichloroethylene ND 0.035 0.014 ND 0.14 0.057 0.702 7/31/19 18:59 BRF trans-1,2-Dichloroethylene ND 0.035 0.014 ND 0.14 0.056 0.702 7/31/19 18:59 BRF Ethanol 11 1.4 0.63 22 2.6 1.2 0.702 7/31/19 18:59 BRF Ethyl Acetate ND 0.035 0.026 ND 0.13 0.094 0.702 7/31/19 18:59 BRF Ethylbenzene 2.3 0.035 0.020 10 0.15 0.088 0.702 7/31/19 18:59 BRF 4-Ethyltoluene 0.65 0.035 0.021 3.2 0.17 0.11 0.702 7/31/19 18:59 BRF Heptane 1.4 0.035 0.021 5.6 0.14 0.085 0.702 7/31/19 18:59 BRF Hexane ND 1.4 0.062 ND 4.9 0.22 0.702 7/31/19 18:59 BRF Isopropanol ND 1.4 0.043 ND 3.4 0.11 0.702 7/31/19 18:59 BRF Methylene Chloride ND 0.35 0.043 ND 1.2 0.15 0.702 7/31/19 18:59 BRF Naphthalene 1.7 0.035 0.027 Z-01 9.0 0.18 0.14 0.702 7/31/19 18:59 BRF Styrene ND 0.035 0.022 ND 0.15 0.092 0.702 7/31/19 18:59 BRF Tetrachloroethylene 0.13 0.035 0.020 0.89 0.24 0.13 0.702 7/31/19 18:59 BRF Tetrahydrofuran 0.72 0.035 0.023 2.1 0.10 0.069 0.702 7/31/19 18:59 BRF Toluene 16 0.035 0.018 61 0.13 0.068 0.702 7/31/19 18:59 BRF Trichloroethylene ND 0.035 0.014 ND 0.19 0.076 0.702 7/31/19 18:59 BRF Trichlorofluoromethane (Freon 11) 0.42 0.14 0.020 2.4 0.79 0.11 0.702 7/31/19 18:59 BRF 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) ND 0.14 0.021 ND 1.1 0.16 0.702 7/31/19 18:59 BRF 1,3,5-Trimethylbenzene 0.44 0.035 0.022 2.1 0.17 0.11 0.702 7/31/19 18:59 BRF Vinyl Chloride ND 0.035 0.022 ND 0.090 0.057 0.702 7/31/19 18:59 BRF m&p-Xylene 14 0.070 0.040 61 0.30 0.18 0.702 7/31/19 18:59 BRF o-Xylene 6.0 0.035 0.022 26 0.15 0.095 0.702 7/31/19 18:59 BRF Surrogates 4-Bromofluorobenzene (1) 4-Bromofluorobenzene (1) % Recovery % REC Limits 104 99.1 70-130 70-130 7/31/19 18:59 8/1/19 9:07 Page 4 of 23 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Raleigh, NC Sample Description/Location: Work Order: 19G1535 Date Received: 7/25/2019 Sub Description/Location: Initial Vacuum(in Hg): -28.5 Field Sample #: IA-2 Canister ID: 1002 Final Vacuum(in Hg): -7 Sample ID: 19G1535-02 Canister Size: 6 liter Receipt Vacuum(in Hg): -6.8 Sample Matrix: Indoor air Flow Controller ID: 3593 Flow Controller Type: Fixed -Orifice Sampled: 7/24/2019 16:53 Sample Type: 8 hr Flow Controller Calibration RPD Pre and Post -Sampling: Analyte Results ppbv RL EPA TO-15 MDL Flag/Qual Results ug/m3 RI MDL Dilution Date/Time Analyzed Analyst Acetone 31 1.4 0.49 74 3.3 1.2 0.702 7/31/19 19:35 BRF Benzene 0.24 0.035 0.014 0.78 0.11 0.046 0.702 7/31/19 19:35 BRF 2-Butanone (MEK) 25 1.4 0.055 74 4.1 0.16 0.702 7/31/19 19:35 BRF Carbon Disulfide ND 0.35 0.024 ND 1.1 0.075 0.702 7/31/19 19:35 BRF 1,3-Dichlorobenzene ND 0.035 0.018 ND 0.21 0.11 0.702 7/31/19 19:35 BRF Dichlorodiflumomethane (Freon 12) 0.34 0.035 0.015 1.7 0.17 0.075 0.702 7/31/19 19:35 BRF cis-1,2-Dichloroethylene ND 0.035 0.014 ND 0.14 0.057 0.702 7/31/19 19:35 BRF trans-1,2-Dichloroethylene ND 0.035 0.014 ND 0.14 0.056 0.702 7/31/19 19:35 BRF Ethanol 10 1.4 0.63 19 2.6 1.2 0.702 7/31/19 19:35 BRF Ethyl Acetate ND 0.035 0.026 ND 0.13 0.094 0.702 7/31/19 19:35 BRF Ethylbenzene 2.2 0.035 0.020 9.5 0.15 0.088 0.702 7/31/19 19:35 BRF 4-Ethyltoluene 0.62 0.035 0.021 3.1 0.17 0.11 0.702 7/31/19 19:35 BRF Heptane 1.3 0.035 0.021 5.5 0.14 0.085 0.702 7/31/19 19:35 BRF Hexane ND 1.4 0.062 ND 4.9 0.22 0.702 7/31/19 19:35 BRF Isopropanol 3.1 1.4 0.043 7.7 3.4 0.11 0.702 7/31/19 19:35 BRF Methylene Chloride ND 0.35 0.043 ND 1.2 0.15 0.702 7/31/19 19:35 BRF Naphthalene 1.6 0.035 0.027 Z-01 8.6 0.18 0.14 0.702 7/31/19 19:35 BRF Styrene ND 0.035 0.022 ND 0.15 0.092 0.702 7/31/19 19:35 BRF Tetrachloroethylene 0.13 0.035 0.020 0.91 0.24 0.13 0.702 7/31/19 19:35 BRF Tetrahydrofuran 0.67 0.035 0.023 2.0 0.10 0.069 0.702 7/31/19 19:35 BRF Toluene 16 0.035 0.018 61 0.13 0.068 0.702 7/31/19 19:35 BRF Trichloroethylene ND 0.035 0.014 ND 0.19 0.076 0.702 7/31/19 19:35 BRF Trichlorofluoromethane (Freon 11) 0.40 0.14 0.020 2.2 0.79 0.11 0.702 7/31/19 19:35 BRF 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) ND 0.14 0.021 ND 1.1 0.16 0.702 7/31/19 19:35 BRF 1,3,5-Trimethylbenzene 0.42 0.035 0.022 2.0 0.17 0.11 0.702 7/31/19 19:35 BRF Vinyl Chloride ND 0.035 0.022 ND 0.090 0.057 0.702 7/31/19 19:35 BRF m&p-Xylene 13 0.070 0.040 57 0.30 0.18 0.702 7/31/19 19:35 BRF o-Xylene 5.7 0.035 0.022 25 0.15 0.095 0.702 7/31/19 19:35 BRF Surrogates % Recovery % REC Limits 4-Bromofluorobenzene(1) 105 70-130 7/31/19 19:35 Page 5 of 23 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Raleigh, NC Sample Description/Location: Work Order: 19G1535 Date Received: 7/25/2019 Sub Description/Location: Initial Vacuum(in Hg): -28 Field Sample #: IA-3 Canister ID: 1123 Final Vacuum(in Hg): -8 Sample ID: 19G1535-03 Canister Size: 6 liter Receipt Vacuum(in Hg): -7.5 Sample Matrix: Indoor air Flow Controller ID: 3587 Flow Controller Type: Fixed -Orifice Sampled: 7/24/2019 16:56 Sample Type: 8 hr Flow Controller Calibration RPD Pre and Post -Sampling: Analyte Results ppbv RL EPA TO-15 MDL Flag/Qual Results ug/m3 RL MDL Dilution Date/Time Analyzed Analyst Acetone 44 8.0 2.8 100 19 6.6 4 8/l/19 9:36 BRF Benzene 0.12 0.035 0.014 0.39 0.11 0.046 0.702 7/31/19 20:10 BRF 2-Butanone (MEK) 46 8.0 0.31 140 24 0.92 4 8/1/19 9:36 BRF Carbon Disulfide ND 0.35 0.024 ND 1.1 0.075 0.702 7/31/19 20:10 BRF 1,3-Dichlorobenzene ND 0.035 0.018 ND 0.21 0.11 0.702 7/31/19 20:10 BRF Dichlorodiflumomethane (Freon 12) 0.42 0.035 0.015 2.1 0.17 0.075 0.702 7/31/19 20:10 BRF cis-1,2-Dichloroethylene ND 0.035 0.014 ND 0.14 0.057 0.702 7/31/19 20:10 BRF trans-1,2-Dichloroethylene ND 0.035 0.014 ND 0.14 0.056 0.702 7/31/19 20:10 BRF Ethanol 13 1.4 0.63 25 2.6 1.2 0.702 7/31/19 20:10 BRF Ethyl Acetate ND 0.035 0.026 ND 0.13 0.094 0.702 7/31/19 20:10 BRF Ethylbenzene 3.3 0.035 0.020 14 0.15 0.088 0.702 7/31/19 20:10 BRF 4-Ethyltoluene 0.79 0.035 0.021 3.9 0.17 0.11 0.702 7/31/19 20:10 BRF Heptane 2.2 0.035 0.021 8.9 0.14 0.085 0.702 7/31/19 20:10 BRF Hexane 1.4 1.4 0.062 5.1 4.9 0.22 0.702 7/31/19 20:10 BRF Isopropanol 2.5 1.4 0.043 6.2 3.4 0.11 0.702 7/31/19 20:10 BRF Methylene Chloride ND 0.35 0.043 ND 1.2 0.15 0.702 7/31/19 20:10 BRF Naphthalene 2.0 0.035 0.027 Z-01 10 0.18 0.14 0.702 7/31/19 20:10 BRF Styrene ND 0.035 0.022 ND 0.15 0.092 0.702 7/31/19 20:10 BRF Tetrachloroethylene 0.19 0.035 0.020 1.3 0.24 0.13 0.702 7/31/19 20:10 BRF Tetrahydrofuran 0.77 0.035 0.023 2.3 0.10 0.069 0.702 7/31/19 20:10 BRF Toluene 39 0.20 0.10 150 0.75 0.39 4 8/l/19 9:36 BRF Trichloroethylene ND 0.035 0.014 ND 0.19 0.076 0.702 7/31/19 20:10 BRF Trichlorofluoromethane (Freon 11) 0.58 0.14 0.020 3.2 0.79 0.11 0.702 7/31/19 20:10 BRF 1,1,2-Trichloro-1,2,2-(rifluoroethane (Freon 113) ND 0.14 0.021 ND 1.1 0.16 0.702 7/31/19 20:10 BRF 1,3,5-Trimethylbenzene 0.51 0.035 0.022 2.5 0.17 0.11 0.702 7/31/19 20:10 BRF Vinyl Chloride ND 0.035 0.022 ND 0.090 0.057 0.702 7/31/19 20:10 BRF m&p-Xylene 20 0.070 0.040 88 0.30 0.18 0.702 7/31/19 20:10 BRF o-Xylene 8.2 0.035 0.022 36 0.15 0.095 0.702 7/31/19 20:10 BRF Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1) 101 70-130 8/1/19 9:36 4-Bromofluorobenzene(1) 102 70-130 7/31/19 20:10 Page 6 of 23 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Raleigh, NC Sample Description/Location: Work Order: 19G1535 Date Received: 7/25/2019 Sub Description/Location: Initial Vacuum(in Hg): -30 Field Sample #: IA-4 Canister ID: 1486 Final Vacuum(in Hg): -10 Sample ID: 19G1535-04 Canister Size: 6 liter Receipt Vacuum(in Hg): -9.5 Sample Matrix: Indoor air Flow Controller ID: 3592 Flow Controller Type: Fixed -Orifice Sampled: 7/24/2019 16:47 Sample Type: 8 hr Flow Controller Calibration RPD Pre and Post -Sampling: Analyte Results ppbv RL EPA TO-15 MDL Flag/Qual Results ug/m3 RI MDL Dilution Date/Time Analyzed Analyst Acetone 32 1.4 0.49 75 3.3 1.2 0.702 7/31/19 20:46 BRF Benzene 0.10 0.035 0.014 0.32 0.11 0.046 0.702 7/31/19 20:46 BRF 2-Butanone (MEK) 46 8.0 0.31 140 24 0.92 4 8/1/19 10:05 BRF Carbon Disulfide ND 0.35 0.024 ND 1.1 0.075 0.702 7/31/19 20:46 BRF 1,3-Dichlorobenzene ND 0.035 0.018 ND 0.21 0.11 0.702 7/31/19 20:46 BRF Dichlorodiflumomethane (Freon 12) 0.28 0.035 0.015 1.4 0.17 0.075 0.702 7/31/19 20:46 BRF cis-1,2-Dichloroethylene ND 0.035 0.014 ND 0.14 0.057 0.702 7/31/19 20:46 BRF trans-1,2-Dichloroethylene ND 0.035 0.014 ND 0.14 0.056 0.702 7/31/19 20:46 BRF Ethanol 10 1.4 0.63 19 2.6 1.2 0.702 7/31/19 20:46 BRF Ethyl Acetate ND 0.035 0.026 ND 0.13 0.094 0.702 7/31/19 20:46 BRF Ethylbenzene 1.8 0.035 0.020 7.8 0.15 0.088 0.702 7/31/19 20:46 BRF 4-Ethyltoluene 0.58 0.035 0.021 2.8 0.17 0.11 0.702 7/31/19 20:46 BRF Heptane 0.94 0.035 0.021 3.8 0.14 0.085 0.702 7/31/19 20:46 BRF Hexane ND 1.4 0.062 ND 4.9 0.22 0.702 7/31/19 20:46 BRF Isopropanol ND 1.4 0.043 ND 3.4 0.11 0.702 7/31/19 20:46 BRF Methylene Chloride ND 0.35 0.043 ND 1.2 0.15 0.702 7/31/19 20:46 BRF Naphthalene 1.5 0.035 0.027 Z-01 7.7 0.18 0.14 0.702 7/31/19 20:46 BRF Styrene ND 0.035 0.022 ND 0.15 0.092 0.702 7/31/19 20:46 BRF Tetrachloroethylene 0.11 0.035 0.020 0.76 0.24 0.13 0.702 7/31/19 20:46 BRF Tetrahydrofuran 0.59 0.035 0.023 1.7 0.10 0.069 0.702 7/31/19 20:46 BRF Toluene 8.1 0.035 0.018 31 0.13 0.068 0.702 7/31/19 20:46 BRF Trichloroethylene ND 0.035 0.014 ND 0.19 0.076 0.702 7/31/19 20:46 BRF Trichlorofluoromethane (Freon 11) 0.37 0.14 0.020 2.1 0.79 0.11 0.702 7/31/19 20:46 BRF 1,1,2-Trichloro-1,2,2-(rifluoroethane (Freon 113) ND 0.14 0.021 ND 1.1 0.16 0.702 7/31/19 20:46 BRF 1,3,5-Trimethylbenzene 0.41 0.035 0.022 2.0 0.17 0.11 0.702 7/31/19 20:46 BRF Vinyl Chloride ND 0.035 0.022 ND 0.090 0.057 0.702 7/31/19 20:46 BRF m&p-Xylene 10 0.070 0.040 45 0.30 0.18 0.702 7/31/19 20:46 BRF o-Xylene 4.4 0.035 0.022 19 0.15 0.095 0.702 7/31/19 20:46 BRF Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1) 99.8 70-130 8/1/19 10:05 4-Bromofluorobenzene(1) 101 70-130 7/31/19 20:46 Page 7 of 23 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Raleigh, NC Sample Description/Location: Work Order: 19G1535 Date Received: 7/25/2019 Sub Description/Location: Initial Vacuum(in Hg): -28 Field Sample #: AMB-1 Canister ID: 1015 Final Vacuum(in Hg): -5 Sample ID: 19G1535-05 Canister Size: 6 liter Receipt Vacuum(in Hg): -6.6 Sample Matrix: Ambient Air Flow Controller ID: 3612 Flow Controller Type: Fixed -Orifice Sampled: 7/24/2019 16:44 Sample Type: 8 hr Flow Controller Calibration RPD Pre and Post -Sampling: Analyte Results ppbv RL EPA TO-15 MDL Flag/Qual Results ug/m3 RL MDL Dilution Date/Time Analyzed Analyst Acetone 3.9 1.4 0.49 9.4 3.3 1.2 0.702 7/31/19 21:21 BRF Benzene 0.070 0.035 0.014 0.22 0.11 0.046 0.702 7/31/19 21:21 BRF 2-Butanone (MEK) ND 1.4 0.055 ND 4.1 0.16 0.702 7/31/19 21:21 BRF Carbon Disulfide ND 0.35 0.024 ND 1.1 0.075 0.702 7/31/19 21:21 BRF 1,3-Dichlorobenzene ND 0.035 0.018 ND 0.21 0.11 0.702 7/31/19 21:21 BRF Dichlorodiflumomethane (Freon 12) 0.41 0.035 0.015 2.0 0.17 0.075 0.702 7/31/19 21:21 BRF cis-1,2-Dichloroethylene ND 0.035 0.014 ND 0.14 0.057 0.702 7/31/19 21:21 BRF trans-1,2-Dichloroethylene ND 0.035 0.014 ND 0.14 0.056 0.702 7/31/19 21:21 BRF Ethanol 2.6 1.4 0.63 5.0 2.6 1.2 0.702 7/31/19 21:21 BRF Ethyl Acetate ND 0.035 0.026 ND 0.13 0.094 0.702 7/31/19 21:21 BRF Ethylbenzene ND 0.035 0.020 ND 0.15 0.088 0.702 7/31/19 21:21 BRF 4-Ethyltoluene ND 0.035 0.021 ND 0.17 0.11 0.702 7/31/19 21:21 BRF Heptane 0.050 0.035 0.021 0.20 0.14 0.085 0.702 7/31/19 21:21 BRF Hexane ND 1.4 0.062 ND 4.9 0.22 0.702 7/31/19 21:21 BRF Isopropanol ND 1.4 0.043 ND 3.4 0.11 0.702 7/31/19 21:21 BRF Methylene Chloride ND 0.35 0.043 ND 1.2 0.15 0.702 7/31/19 21:21 BRF Naphthalene 0.13 0.035 0.027 Z-01 0.67 0.18 0.14 0.702 7/31/19 21:21 BRF Styrene ND 0.035 0.022 ND 0.15 0.092 0.702 7/31/19 21:21 BRF Tetrachloroethylene ND 0.035 0.020 ND 0.24 0.13 0.702 7/31/19 21:21 BRF Tetrahydrofuran ND 0.035 0.023 ND 0.10 0.069 0.702 7/31/19 21:21 BRF Toluene 0.29 0.035 0.018 1.1 0.13 0.068 0.702 7/31/19 21:21 BRF Trichloroethylene ND 0.035 0.014 ND 0.19 0.076 0.702 7/31/19 21:21 BRF Trichlorofluoromethane (Freon 11) 0.18 0.14 0.020 1.0 0.79 0.11 0.702 7/31/19 21:21 BRF 1,1,2-Trichloro-1,2,2-(rifluoroethane (Freon 113) ND 0.14 0.021 ND 1.1 0.16 0.702 7/31/19 21:21 BRF 1,3,5-Trimethylbenzene ND 0.035 0.022 ND 0.17 0.11 0.702 7/31/19 21:21 BRF Vinyl Chloride ND 0.035 0.022 ND 0.090 0.057 0.702 7/31/19 21:21 BRF m&p-Xylene 0.094 0.070 0.040 0.41 0.30 0.18 0.702 7/31/19 21:21 BRF o-Xylene 0.042 0.035 0.022 0.18 0.15 0.095 0.702 7/31/19 21:21 BRF Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1) 100 70-130 7/31/19 21:21 Page 8 of 23 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Raleigh, NC Sample Description/Location: Work Order: 19G1535 Date Received: 7/25/2019 Sub Description/Location: Initial Vacuum(in Hg): -29 Field Sample #: IA-10 Canister ID: 1878 Final Vacuum(in Hg): -6 Sample ID: 19G1535-06 Canister Size: 6 liter Receipt Vacuum(in Hg): -6.1 Sample Matrix: Indoor air Flow Controller ID: 3663 Flow Controller Type: Fixed -Orifice Sampled: 7/24/2019 16:54 Sample Type: 8 hr Flow Controller Calibration RPD Pre and Post -Sampling: Analyte Results ppbv RL EPA TO-15 MDL Flag/Qual Results ug/m3 RL MDL Dilution Date/Time Analyzed Analyst Acetone 30 1.4 0.49 70 3.3 1.2 0.702 7/31/19 21:57 BRF Benzene 0.11 0.035 0.014 0.34 0.11 0.046 0.702 7/31/19 21:57 BRF 2-Butanone (MEK) 32 1.4 0.055 94 4.1 0.16 0.702 7/31/19 21:57 BRF Carbon Disulfide ND 0.35 0.024 ND 1.1 0.075 0.702 7/31/19 21:57 BRF 1,3-Dichlorobenzene ND 0.035 0.018 ND 0.21 0.11 0.702 7/31/19 21:57 BRF Dichlorodiflumomethane (Freon 12) 0.59 0.035 0.015 2.9 0.17 0.075 0.702 7/31/19 21:57 BRF cis-1,2-Dichloroethylene ND 0.035 0.014 ND 0.14 0.057 0.702 7/31/19 21:57 BRF trans-1,2-Dichloroethylene ND 0.035 0.014 ND 0.14 0.056 0.702 7/31/19 21:57 BRF Ethanol 9.8 1.4 0.63 18 2.6 1.2 0.702 7/31/19 21:57 BRF Ethyl Acetate ND 0.035 0.026 ND 0.13 0.094 0.702 7/31/19 21:57 BRF Ethylbenzene 2.2 0.035 0.020 9.7 0.15 0.088 0.702 7/31/19 21:57 BRF 4-Ethyltoluene 0.62 0.035 0.021 3.0 0.17 0.11 0.702 7/31/19 21:57 BRF Heptane 1.3 0.035 0.021 5.5 0.14 0.085 0.702 7/31/19 21:57 BRF Hexane ND 1.4 0.062 ND 4.9 0.22 0.702 7/31/19 21:57 BRF Isopropanol 1.9 1.4 0.043 4.6 3.4 0.11 0.702 7/31/19 21:57 BRF Methylene Chloride ND 0.35 0.043 ND 1.2 0.15 0.702 7/31/19 21:57 BRF Naphthalene 1.8 0.035 0.027 Z-01 9.2 0.18 0.14 0.702 7/31/19 21:57 BRF Styrene ND 0.035 0.022 ND 0.15 0.092 0.702 7/31/19 21:57 BRF Tetrachloroethylene 0.14 0.035 0.020 0.95 0.24 0.13 0.702 7/31/19 21:57 BRF Tetrahydrofuran 0.72 0.035 0.023 2.1 0.10 0.069 0.702 7/31/19 21:57 BRF Toluene 17 0.035 0.018 62 0.13 0.068 0.702 7/31/19 21:57 BRF Trichloroethylene ND 0.035 0.014 ND 0.19 0.076 0.702 7/31/19 21:57 BRF Trichlorofluoromethane (Freon 11) 0.40 0.14 0.020 2.3 0.79 0.11 0.702 7/31/19 21:57 BRF 1,1,2-Trichloro-1,2,2-(rifluoroethane (Freon 113) ND 0.14 0.021 ND 1.1 0.16 0.702 7/31/19 21:57 BRF 1,3,5-Trimethylbenzene 0.41 0.035 0.022 2.0 0.17 0.11 0.702 7/31/19 21:57 BRF Vinyl Chloride ND 0.035 0.022 ND 0.090 0.057 0.702 7/31/19 21:57 BRF m&p-Xylene 14 0.070 0.040 59 0.30 0.18 0.702 7/31/19 21:57 BRF o-Xylene 5.7 0.035 0.022 25 0.15 0.095 0.702 7/31/19 21:57 BRF Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1) 101 70-130 7/31/19 21:57 Page 9 of 23 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 Sample Extraction Data Prep Method: TO-15 Prep -EPA TO-15 Pre-Dil Pre-Dil Default Actual Pressure Pre Initial Final Injection Injection Lab Number [Field ID] Batch Dilution Dilution mL mL mL mL Date 19G1535-01 [IA-1] B236986 1.5 1 N/A 1000 400 855 07/31/19 19G1535-OIRE1 [IA-1] B236986 1.5 1 N/A 1000 400 150 07/31/19 19G1535-02 [IA-2] B236986 1.5 1 N/A 1000 400 855 07/31/19 19G1535-03 [IA-3] B236986 1.5 1 N/A 1000 400 855 07/31/19 19GI535-03REI [IA-3] B236986 1.5 1 N/A 1000 400 150 07/31/19 19G1535-04 [IA-4] B236986 1.5 1 N/A 1000 400 855 07/31/19 19G1535-04REI [IA-4] B236986 1.5 1 N/A 1000 400 150 07/31/19 19G1535-05 [AMB-1] B236986 1.5 1 N/A 1000 400 855 07/31/19 19G1535-06 [IA-10] B236986 1.5 1 N/A 1000 400 855 07/31/19 Page 10 of 23 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 QUALITY CONTROL Air Toxics by EPA Compendium Methods - Quality Control ppbv ug/m3 Spike Level Source %REC RPD nalyte Results RL Results RL ppbv Result %REC Limits RPD Limit Flag/Qua Batch B236986 - TO-15 Prep Blank (B236986-BLK1) Prepared & Analyzed: 07/31/19 Acetone ND 1.4 Benzene ND 0.035 2-Butanone (MEK) ND 1.4 Carbon Disulfide ND 0.35 1,3-Dichlorobenzene ND 0.035 Dichlorodifluoromethane (Freon 12) ND 0.035 cis-1,2-Dichloroethylene ND 0.035 trans-1,2-Dichloroethylene ND 0.035 Ethanol ND 1.4 Ethyl Acetate ND 0.035 Ethylbenzene ND 0.035 4-Ethyltoluene ND 0.035 Heptane ND 0.035 Hexane ND 1.4 Isopropanol ND 1.4 Methylene Chloride ND 0.35 Naphthalene ND 0.035 Z-01 Styrene ND 0.035 Tetrachloroethylene ND 0.035 Tetrahydrofuran ND 0.035 Toluene ND 0.035 Trichloroethylene ND 0.035 Trichlorofluoromethane (Freon 11) ND 0.14 1, 1,2-Trichloro- 1,2,2-trifluoroethane (Freon ND 0.14 113) 1,3,5-Trimethylbenzene ND 0.035 Vinyl Chloride ND 0.035 m&p-Xylene ND 0.070 o-Xylene ND 0.035 Surrogate: 4-BromoJluorobenzene (1) 7.89 8.00 98.7 70-130 Page 11 of 23 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 QUALITY CONTROL Air Toxics by EPA Compendium Methods - Quality Control ppbv ug/m3 Spike Level Source %REC RPD .nalyte Results RL Results RL ppbv Result %REC Limits RPD Limit Flag/Qua Batch B236986 - TO-15 Prep LCS (B236986-BS1) Prepared & Analyzed: 07/31/19 Acetone 4.37 5.00 87.4 70-130 Benzene 4.39 5.00 87.7 70-130 2-Butanone(MEK) 4.42 5.00 88.4 70-130 Carbon Disulfide 5.14 5.00 103 70-130 1,3-Dichlorobenzene 5.57 5.00 ill 70-130 Dichlorodifluoromethane (Freon 12) 4.95 5.00 99.0 70-130 cis-1,2-Dichloroethylene 4.85 5.00 97.0 70-130 trans-1,2-Dichloroethylene 4.76 5.00 95.3 70-130 Ethanol 4.06 5.00 81.1 70-130 Ethyl Acetate 4.71 5.00 94.2 70-130 Ethylbenzene 4.70 5.00 94.0 70-130 4-Ethyltoluene 5.04 5.00 101 70-130 Heptane 4.27 5.00 85.3 70-130 Hexane 5.09 5.00 102 70-130 Isopropanol 4.09 5.00 81.8 70-130 Methylene Chloride 4.42 5.00 88.4 70-130 Naphthalene 7.49 5.00 150 * 70-130 Z-01 Styrene 5.30 5.00 106 70-130 Tetrachloroethylene 4.49 5.00 89.8 70-130 Tetrahydrofuran 4.83 5.00 96.5 70-130 Toluene 4.64 5.00 92.7 70-130 Trichloroethylene 4.52 5.00 90.4 70-130 Trichlorofluoromethane (Freon 11) 5.00 5.00 100 70-130 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 4.86 5.00 97.2 70-130 113) 1,3,5-Trimethylbenzene 4.84 5.00 96.8 70-130 Vinyl Chloride 4.69 5.00 93.8 70-130 m&p-Xylene 9.52 10.0 95.2 70-130 o-Xylene 4.71 5.00 94.1 70-130 Surrogate: 4-Bromofluorobenzene (1) 7.87 8.00 98.4 70-130 Page 12 of 23 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 * FAX 413/525-6405 " TEL. 413/525-2332 FLAG/QUALIFIER SUMMARY * QC result is outside of established limits. t Wide recovery limits established for difficult compound. $ Wide RPD limits established for difficult compound. # Data exceeded client recommended or regulatory level RL Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference LCS Laboratory Control Sample LCS Dup Duplicate Laboratory Control Sample MS Matrix Spike Sample MS Dup Duplicate Matrix Spike Sample REC Recovery QC Quality Control ppbv Parts per billion volume EPA United States Environmental Protection Agency % REC Percent Recovery ND Not Detected N/A Not Applicable DL Detection Limit NC Not Calculated LFB/LCS Lab Fortified Blank/Lab Control Sample ORP Oxidation -Reduction Potential wet Not dry weight corrected % wt Percent weight Kg Kilogram g Gram mg Milligram µg Microgram ng Nanogram L Liter mL Milliliter µL Microliter m3 Cubic Meter EPH Extractable Petroleum Hydrocarbons VPH Volatile Petroleum Hydrocarbons APH Air Petroleum Hydrocarbons FID Flame Ionization Detector PID Photo Ionization Detector Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the calculation which have not been rounded. Z-01 Compound fails the method requirement of 70-130% recovery for the LCS. Is classified by the lab as a difficult compound and passes the in house limits of 50-150%. ANALYST RAP Raisa A. Petraitis STATION PDF Management Station KKM Kerry K. McGee CF2 Christine M. Farina BRF Brittany R. Fisk Page 13 of 23 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 INTERNAL STANDARD AREAAND RT SUMMARY EPA TO-15 Internal Standard Response RT Reference Response Reference RT Area % Area o/ Limits RT Diff RT Diff Limit Q Initial Cal Check (S038528-ICV1) Lab File ID: B1920819.D Analyzed: 07/27/19 19:24 Bromochloromethane (1) 144000 5.05 141846 5.054 102 60 - 140 -0.0040 +/-0.50 1,4-Difluorobenzene (1) 338979 6.264 331570 6.268 102 60 - 140 -0.0040 +/-0.50 Chlorobenzene-d5(1) 300441 9.857 293128 9.861 102 60-140 -0.0040 +/-0.50 INTERNAL STANDARD AREAAND RT SUMMARY EPA TO-15 Internal Standard Response RT Reference Response Reference RT Area % Area o/ Limits RT Diff RT Diff Limit Q Calibration Check (S038724-CCVI) Lab File ID: B1921204.D Analyzed: 07/31/19 10:46 Bromochloromethane (1) 123989 5.052 141846 5.054 87 60 - 140 -0.0020 +/-0.50 1,4-Difluorobenzene (1) 303050 6.266 331570 6.268 91 60 - 140 -0.0020 +/-0.50 Chlorobenzene-d5(1) 269377 9.859 293128 9.861 92 60-140 -0.0020 +/-0.50 LCS (B236986-BS1 ) Lab File ID: B1921205.D Analyzed: 07/31/19 11:15 Bromochloromethane (1) 128903 5.065 123989 5.052 104 60 - 140 0.0130 +/-0.50 1,4-Difluorobenzene (1) 317642 6.279 303050 6.266 105 60 - 140 0.0130 +/-0.50 Chlorobenzene-d5(1) 283081 9.86 269377 9.859 105 60-140 0.0010 +/-0.50 Blank (B236986-BLK1) Lab File ID: B1921207.D Analyzed: 07/31/19 12:15 Bromochloromethane (1) 125701 5.052 123989 5.052 101 60 - 140 0.0000 +/-0.50 1,4-Difluorobenzene (1) 304264 6.266 303050 6.266 100 60 - 140 0.0000 +/-0.50 Chlorobenzene-d5(1) 265132 9.859 269377 9.859 98 60-140 0.0000 +/-0.50 IA-1(19G1535-01) Lab File ID: B1921216.D Analyzed: 07/31/19 18:59 Bromochloromethane (1) 126631 5.047 123989 5.052 102 60 - 140 -0.0050 +/-0.50 1,4-Difluorobenzene (1) 302951 6.267 303050 6.266 100 60 - 140 0.0010 +/-0.50 Chlorobenzene-d5 (1) 263278 9.878 269377 9.859 98 60-140 0.0190 +/-0.50 IA-2 (19G1535-02 ) Lab File ID: B1921217.D Analyzed: 07/31/19 19:35 Bromochloromethane (1) 134156 5.052 123989 5.052 108 60 - 140 0.0000 +/-0.50 1,4-Difluorobenzene (1) 335932 6.266 303050 6.266 ill 60 - 140 0.0000 +/-0.50 Chlorobenzene-d5(1) 278021 9.883 269377 9.859 103 60-140 0.0240 +/-0.50 IA-3 (19G1535-03 ) Lab File ID: B1921218.D Analyzed: 07/31/19 20:10 Bromochloromethane (1) 139767 5.053 123989 5.052 113 60 - 140 0.0010 +/-0.50 1,4-Difluorobenzene (1) 349435 6.267 303050 6.266 115 60 - 140 0.0010 +/-0.50 Chlorobenzene-d5(1) 280054 9.896 269377 9.859 104 60-140 0.0370 +/-0.50 IA-4 (19G1535-04) Lab File ID: B1921219.D Analyzed: 07/31/19 20:46 Bromochloromethane (1) 135094 5.052 123989 5.052 109 60 - 140 0.0000 +/-0.50 1,4-Difluorobenzene (1) 347549 6.266 303050 6.266 115 60 - 140 0.0000 +/-0.50 Chlorobenzene-d5(1) 291362 9.871 269377 9.859 108 60-140 0.0120 +/-0.50 Page 14 of 23 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 INTERNAL STANDARD AREAAND RT SUMMARY EPA TO-15 Internal Standard Response RT Reference Response Reference RT Area % Area o/ Limits RT Diff RT Diff Limit Q AMB-1 (19G1535-05) Lab File ID: B1921220.D Analyzed: 07/31/19 21:21 Bromochloromethane (1) 137885 5.053 123989 5.052 111 60 - 140 0.0010 +/-0.50 1,4-Difluorobenzene (1) 357325 6.266 303050 6.266 118 60 - 140 0.0000 +/-0.50 Chlorobenzene-d5(1) 311677 9.86 269377 9.859 116 60-140 0.0010 +/-0.50 IA-10 (19G1535-06) Lab File ID: B1921221.D Analyzed: 07/31/19 21:57 Bromochloromethane (1) 140040 5.048 123989 5.052 113 60 - 140 -0.0040 +/-0.50 1,4-Difluorobenzene (1) 354632 6.268 303050 6.266 117 60 - 140 0.0020 +/-0.50 Chlorobenzene-d5(1) 291992 9.879 269377 9.859 108 60-140 0.0200 +/-0.50 IA-1 (19G1535-01RE1) Lab File ID: B1921234.D Analyzed: 08/01/19 09:07 Bromochloromethane (1) 124940 5.059 123989 5.052 101 60 - 140 0.0070 +/-0.50 1,4-Difluorobenzene (1) 307201 6.272 303050 6.266 101 60 - 140 0.0060 +/-0.50 Chlorobenzene-d5(1) 275531 9.86 269377 9.859 102 60-140 0.0010 +/-0.50 IA-3 (19G1535-03RE1) Lab File ID: B1921235.D Analyzed: 08/01/19 09:36 Bromochloromethane (1) 126617 5.06 123989 5.052 102 60 - 140 0.0080 +/-0.50 1,4-Difluorobenzene (1) 321094 6.273 303050 6.266 106 60 - 140 0.0070 +/-0.50 Chlorobenzene-d5(1) 284151 9.867 269377 9.859 105 60-140 0.0080 +/-0.50 IA-4 (19G1535-04RE1) Lab File ID: B1921236.D Analyzed: 08/01/19 10:05 Bromochloromethane (1) 127004 5.062 123989 5.052 102 60 - 140 0.0100 +/-0.50 1,4-Difluorobenzene (1) 325170 6.276 303050 6.266 107 60 - 140 0.0100 +/-0.50 Chlorobenzene-d5(1) 286409 9.863 269377 9.859 106 60-140 0.0040 +/-0.50 Page 15 of 23 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street' East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S038724-CCV 1 COMPOUND TYPE CONC. (ppbv) RESPONSE FACTOR % DIFF / DRIFT STD CCV ICAL CCV MIN (#) CCV LIMIT (#) Acetone A 5.00 4.49 1.061501 0.9525877 -10.3 30 Benzene A 5.00 4.17 0.8735206 0.728033 -16.7 30 2-Butanone (MEK) A 5.00 4.04 1.510652 1.219528 -19.3 30 Carbon Disulfide A 5.00 4.88 1.951102 1.902414 -2.5 30 1,3-Dichlorobenzene A 5.00 4.61 0.6156422 0.5670922 -7.9 30 Dichlorodifluoromethane (Freon 12) A 5.00 4.68 1.496329 1.399427 -6.5 30 cis-1,2-Dichloroethylene A 5.00 4.58 0.8593978 0.7875666 -8.4 30 trans-1,2-Dichloroethylene A 5.00 4.47 0.9369909 0.8372356 -10.6 30 Ethanol L 5.00 5.60 0.2361095 0.2344466 12.0 30 Ethyl Acetate A 5.00 4.55 0.2359238 0.21469 -9.0 30 Ethylbenzene A 5.00 4.34 1.254903 1.089548 -13.2 30 4-Ethyltoluene A 5.00 4.41 1.170616 1.033324 -11.7 30 Heptane A 5.00 4.14 0.2735238 0.2263864 -17.2 30 Hexane L 5.00 4.82 0.492452 0.3892861 -3.6 30 Isopropanol L 5.00 4.81 1.490308 1.15507 -3.8 30 Methylene Chloride A 5.00 4.22 0.8402594 0.7083209 -15.7 30 Naphthalene A 5.00 5.41 0.6049938 0.6544464 8.2 30 Styrene A 5.00 4.63 0.6473158 0.5994691 -7.4 30 Tetrachloroethylene A 5.00 4.28 0.4931961 0.4218148 -14.5 30 Tetrahydtofuran A 5.00 4.19 0.8848512 0.7413819 -16.2 30 Toluene A 5.00 4.29 0.9917029 0.8517253 -14.1 30 Trichloroethylene A 5.00 4.29 0.357385 0.3063574 -14.3 30 Trichlorofluoromethane (Freon 11) A 5.00 4.58 1.428406 1.309871 -8.3 30 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 11 A 5.00 4.75 1.290004 1.226573 -4.9 30 1,3,5-Trimethylbenzene A 5.00 4.28 0.9344044 0.8001693 -14.4 30 Vinyl Chloride A 5.00 4.45 0.6970639 0.6204292 -11.0 30 m&p-Xylene A 10.0 8.75 0.9303396 0.8144571 -12.5 30 o-Xylene A 5.00 4.28 0.9311699 0.7980963 -14.3 30 # Column to be used to flag Response Factor and %Difi/Drift values with an asterisk * Values outside of QC limits Page 16 of 23 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street ` East Longmeadow, MA 01028 ' FAX 413/525-6405 " TEL. 413/525-2332 CERTIFICATIONS Certified Analyses included in this Report Analyte Certifications EPA TO-15 in Air Acetone AIHA,NY,ME,NH Benzene AIHA,FL,NJ,NYNfE,NH,VA 2-Butanone (MEK) AIHA,FL,NJ,NYNfE,NH,VA Carbon Disulfide AIHA,NJ,NY,ME,NH,VA 1,3-Dichlorobenzene AIHA,NJ,NY,ME,NH Dichlorodifluoromethane (Freon 12) AIHA,NY,ME,NH cis-1,2-Dichloroethylene AIHA,FL,NY,ME,NH,VA trans-1,2-Dichloroethylene AIHA,NJ,NY,ME,NH,VA Ethanol AIHA Ethyl Acetate AIHA Ethylbenzene AIHA,FL,NJ,NY,ME,NH,VA 4-Ethyltoluene AIHA,NJ Heptane AIHA,NJ,NY,ME,NH,VA Hexane AIHA,FL,NJ,NY,ME,NH,VA Isopropanol AIHA,NY,ME,NH Methylene Chloride AIHA,FL,NJ,NY,ME,NH,VA Naphthalene NY,ME,NH Styrene AIHA,FL,NJ,NY,ME,NH,VA Tetrachloroethylene AIHA,FL,NJ,NY,ME,NH,VA Tetrahydrofuran AIHA Toluene AIHA,FL,NJ,NY,ME,NH,VA Trichloroethylene AIHA,FL,NJ,NY,ME,NH,VA Trichlorofluoromethane (Freon 11) AIHA,NY,ME,NH 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) AIHA,NJ,NY,ME,NH,VA 1,3,5-Trimethylbenzene AIHA,NJ,NY,ME,NH Vinyl Chloride AIHA,FL,NJ,NYNfE,NH,VA m&p-Xylene AIHA,FL,NJ,NYNfE,NH,VA o-Xylene AIHA,FL,NJ,NY,ME,NH,VA Page 17 of 23 icon-tes w . ANALYTICAL LABORATORY 39 Spruce Street' East Longmeadow, MA 01028 ` FAX 413/525-6405 " TEL. 413/525-2332 The CON -TEST Environmental Laboratory operates under the following certifications and accreditations: Code Description Number Expires AIHA AIHA-LAP, LLC - ISO17025:2005 100033 03/1/2020 MA Massachusetts DEP M-MA100 06/30/2020 CT Connecticut Department of Publilc Health PH-0567 09/30/2019 NY New York State Department of Health 10899 NELAP 04/1/2020 NH-S New Hampshire Environmental Lab 2516 NELAP 02/5/2020 RI Rhode Island Department of Health LAO00112 12/30/2019 NC North Carolina Div. of Water Quality 652 12/31/2019 NJ New Jersey DEP MA007 NELAP 06/30/2020 FL Florida Department of Health E871027 NELAP 06/30/2020 VT Vermont Department of Health Lead Laboratory LL015036 07/30/2020 ME State of Maine 2011028 06/9/2021 VA Commonwealth of Virginia 460217 12/14/2019 NH-P New Hampshire Environmental Lab 2557 NELAP 09/6/2019 VT-DW Vermont Department of Health Drinking Water VT-255716 06/12/2020 NC-DW North Carolina Department of Health 25703 07/31/2019 PA Commonwealth of Pennsylvania DEP 68-05812 06/30/2020 Page 18 of 23 m� n O m M Lim Q � O � €c co Q M qt n° V k c ❑ ❑❑ f and I m © co w cc E m a— 6 SyG t 5 ". i .x N o Q � ><J>c > �x I`mot a - '" © pn Q 4o 04 oc, yv a_ �zm J � C7 Q OS aC CO x m .+ O z a N y If If co€I II L7 Q i3 Iq Q N €I J E N— a V I Q m Q _m a Al b � Q 'N C O a = Q1 u C 4 C � g E o o s p ❑ ❑ F— �Y t In ❑L7❑ � C � 07 CA v � v a N � 7 � U Page 19 of 23 > / E In § \ Ln § 7@ 22ru \ ƒ y w 2 / E fa E 5 2 k LL E � 2 � u 2 § R & £ 2 0 0 e CD � :E2 c § e m 0 k/_ k§ m 46\kID 3���f3�/ \ § $ % $ § f LY CD«fnAQ-:,Oa Lu&41 \ U. � k 0t & \ (D ° § /C\! ƒƒ m ter § E ° I % - l o b\ m ¢ q X§ 9:E:Ec � �a 0/ 2 2 C c g x S E 6 Page 20 G 23 7/29/2019 Track your package or shipment with Fed Ex Tracking r 775838345886`, Delivered Monday 7/29/2019 at 1:16 pm DELIVERED Signed for by: FFOUST GET STATUS UPDATES OBTAIN PROOF OF DELIVERY FROM TO Prfleig'_i, NC LS East i oElgmeadmv, I,rid US Multiple -piece Shipment 4 Piece shipment TRACKING NUMBER SHIPPER CITY, .. STATE SHIP DATE STATUS DE.LIV1 RY HATE DESTINATION/RECIPIENT CITY, STATE.. 775838345886 DURHAM, NC 7/25/2019 7r 29/2619 EAST LONGMEADOVd, MA 775838345555 DURHAM, NC 7/25/2019 7/29/2019 EAST LONGMEADO1,%' MA 775838345509 DURHAM, NC 7/25i2019 7/29/2019 EAST-LONGMFADGbV, MA 775838345761 DURI1AM, NC 7/25/2019 Shipment Pacts TRACKING NUMBER SERVICE 775838345886 FedEx Ground MASTER TRACKING NUMBER WEIGHT 7 /5838345886 15 Ibs / 6.8 kg,,, 7/29/2019 REFERENCE 80 DIMENSIONS 22x19xl4 in TOTAL PIECES TOTAL SHIPMENT WEIGHT TERMS 4 60 Ibs i 27 22 kgs 1 hird Party EAST LONGMEADOV�l MA PACKAGING STANDARD TRANSIT SHIP DATE https:llwww.fedex.com/apps/fadextracklindex.html?action=track&tracknumbers=775838345886&locale=en_US&cntry_pode=en Page 21 of 23 7/29/2019 Track your package or shipment with FedEx Tracking 775838345555: Delivered Monday 7/29/2019 at 1.16 pry DELIVERED Signed for by: FFOUST GET STATUS UPDATES OBTAIN PROOF OF DELIVERY FROM R;:dLgh, N(. US TO Fast L.ongmeadov�, MA us Multiple -piece Shipment 4 Piece shipment 775838345886 DURHAM, NC (master ) 7/25/2019 //29/2019 EAST LGNGMEAC)OW, MA 775838345555 DURE IAM, NC 7/25/2019 71'29/2019 EAST LONGMEADOW, MBA 775838345569 DURHA.Mt, NC 7r25i2019 7r29/201 � EAsTLONGIVEADtOIk, MA 71 582Kz457b1 DURI ]AM, NC 7/25i2019 7,129/2019 EAST LONGMEADOW, IAA Shipment Facts TRACKING NUMBER SERVICE REFERENCE 775838345555 FedEx Ground 80 MASTER TRACKING NUMBER WEIGHT DIMENSIONS 775838345886 15 ibs / 6.8 kgs 22x ; 4c ire TOTAL PIECES TOTAL SHIPMENT WEIGHT TERMS 4 6C ibs / 27 22 kgs Third Party PACKAGING STANDARD TRANSIT SHIP DATE https:flwww.fedex.com/apps/fedextrackt?action=track&trackingnumber=775838345555&cntrycode=us&locale=en_US Page 22 of 23 Client Received By CP _ Date How were the samples In Cooler received? In Box T Were samples within Temperature By Gun Compliance? 2-6°C N fl By Bla Was Custody Seal Intact? N A Was COC Relinquished ? T Are there any loose caps/valves on any samples? Is COC in ink/ Legible? T(lid COC Include all Client T Pertinent Information? Project T Are Sample Labels filled out and legible? Are there Rushes? I' Samples are received within holding time? Proper Media Used? -r Are there Trip Blanks? F -7L,-! g%y/ �z Time 1-7,30 On Ice No Ice Ambient Melted Ice # Actual Temp - nk # Actual Temp - Were Samples Tampered with? Does Chain Agree With Samples? i Analysis T Sampler Name r ID`s -_ Collection Dates/Times 4 Who was notified? i Individually Certified Cans? Is there enough Volume? T Page 23 of 23 APPENDIX C SUB -SLAB SOIL GAS VAPOR INTRUSION NON-RESIDENTIAL RISK CALCULATIONS IS Mid Atlantic Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. All on-t-tinna - in nbhn3 CAS # Chemical Name: Soil Gas Concentration e (ug/m) Calculated Indoor Air Concentration (ug✓m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1 E-06 Target Indoor Air Conc. for Non - Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 940 9.4 2.7E+04 6.9E-05 100-414 Eth Ibenzene 4.9 0.049 4.9E+00 8.8E+02 1.0E-08 1.1E-05 67-63-0 Iso ro anol 120 1.2 1.8E+02 1.4E-03 78-93-3 Methyl Ethyl Ketone 2-Butanone 150 1.5 4.4E+03 6.8E-05 10042-5 Styrene 4.9 0.049 8.8E+02 L1E-05 127-184 Tetrachloroeth lene 14 0.14 4.7E+01 3.5E+01 3.0E-09 8.0E-04 108-88-3 Toluene 54 0.54 4.4E+03 2.5E-05 79-01-6 Trichloroeth lene 4.6 0.046 3.0E+00 1.8E+00 1.5E-08 5.3E-03 75-69-4 Trichlorofluoromethane 62 0.62 10642-3 X lene P- 21 0.21 8.8E+01 4.8E-04 108-38-3 X lene m- 8.8E+O1 95 47-6 X lene o- 6.7 0.067 8.8E+01 1.5E-04 Cumulative: I 2.8E-08 1 8.2E-03 North Carolina DEQ Risk Calculator Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. All concentrations are in uf:(m3 CAS # Chemical Name: Soil Gas Concentration (ug m) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = I E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 42 0.42 2.7E+04 3.1E-06 7143-2 Benzene 1.9 0.019 1.6E+00 2.6E+01 1.2E-08 1.4E-04 75-71-8 Dichlorodifluoromethane 0 0 8.8E+01 0.0E+00 141-78-6 Ethyl Acetate 0 0 6.1E+01 0.0E+00 10041-4 Eth lbenzene 4.3 0.043 4.9E+00 8.8E+02 8.8E-09 9.8E-06 109-99-9 -Tetrah drofuran 4.7 0.047 1.8E+03 5.4E-06 142-82-5 Heptane, N- 1.3 0.013 3.5E+02 7.4E-06 110-54-3 Hexane N- 0 0 6.1E+02 0.0E+00 67-63-0 Iso ro anol 9.6 0.096 1.8E+02 1.1 E-04 78-93-3 Methyl Ethyl Ketone 2-Butanone 9.7 0.097 4.4E+03 4.4E-06 75-09-2 Methylene Chloride 1.3 0.013 1.2E+03 5.3E+02 1.1E-11 4.9E-06 91-20-3 -Naphthalene 3.7 0.037 3.6E-01 2.6E+00 LOE-07 2.8E-03 100-42-5 Styrene 4.3 0.043 8.8E+02 9.8E-06 127-18-4 Tetrachloroeth lene 13 0.13 4.7E+O1 3.5E+01 2.8E-09 7.4E-04 108-88-3 Toluene 47 0.47 4.4E+03 2.1E-05 79-01-6 Trichloroeth lene 1.7 0.017 3.0E+00 1.8E+00 5.7E-09 1.9E-03 75-69-4 Trichlorofluoromethane 43 0.43 108-67-8 Trimeth lbenzene 1 3 5- 2.1 0.021 5.3E+O1 8.0E-05 10642-3 X lene P- 20 0.2 8.8E+0l 4.6E-04 108-38-3 X lene m- 0 0 8.8E+01 0.0E+00 95-47-6 X lene, o- 6.2 0.062 8.8E+01 1.4E-04 Cumulative: I 1.3E-07 I 6.5E-03 North Carolina DEQ Risk Calculator Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. All concentrations are in ue/m3 CAS # Chemical Name: Soil Gas Concentration � (ug/m,) Calculated indoor Air Concentration (.g/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1 E-06 Target Indoor Air Conc. For Non - Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 50 0.5 2.7E+04 3.7E-06 71-43-2 Benzene 34 0.34 1.6E+00 2.6E+01 2.2E-07 2.6E-03 75-71-8 Dichlorodifluoromethane 1.3 0.013 8.8E+01 3.0E-05 141-78-6 Ethyl Acetate 2.7 0.027 6.1E+01 8.8E-05 100-41-4 Eth lbenzene 6.4 0.064 4.9E+00 8.8E+02 1.3E-08 1.5E-05 109-99-9 -Tetrah drofumn 5.8 0.058 1.8E+03 6.6E-06 142-82-5 Heptane, N- 2.5 0.025 3.5E+02 1.4E-05 110-54-3 Hexane, N- 3.9 0.039 6.IE+02 1.3E-05 67-63-0 Iso ro anol 11 0.11 1.8E+02 1.3E-04 78-93-3 Methyl Ethyl Ketone 2-Butanone) 9.5 0.095 4.4E+03 4.3E-06 75-09-2 Methylene Chloride 0.93 0.0093 1.2E+03 5.3E+02 7.6E-12 3.5E-06 91-20-3 -Naphthalene 3.5 0.035 3.6E-01 2.6E+00 9.7E-08 2.7E-03 100-42-5 Styrene 6.2 0.062 8.8E+02 1.4E-05 127-18-4 Tetrachloroeth lene 9.8 0.098 4.7E+01 3.5E+01 2.1E-09 5.6E-04 108-88-3 Toluene 63 0.63 4.4E+03 2.9E-05 79-01-6 Trichloroeth lene 1.3 0.013 3.0E+00 1.8E+00 4.3E-09 1.5E-03 75-694 Trichlorofluoromethane 39 0.39 108-67-8 Trimeth (benzene 13 5- 2.9 0.029 5.3E+01 1.1E-04 10642-3 X lene P- 30 0.3 8.8E+O1 6.8E-04 108-38-3 X lene m- 0 0 8.8E+01 0.0E+00 95-47-6 X lene o- 9.6 0.96 0 8.8E+O1 2.2E-04 Cumulative: I 3.3E-07 1 8.7E-03 North Carolina DEQ Risk Calculator Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. All concentrations are in uL/ni CAS # Chemical Name: Soil Gas Concentration (ug/m) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Cone. for Carcinogens @ TCR = I E-06 Target Indoor Air Cfor Non - Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 100 1 2.7E+04 7.4E-06 7143-2 Benzene 3.5 0.035 1.6E+00 2.6E+01 2.2E-08 2.7E-04 75-71-8 Dichlorodifluoromethane 1.7 0.017 8.8E+01 3.9E-05 141-78-6 Eth IAcetate 0 0 6.1E+01 0.0E+00 100-414 Eth ]benzene 6.3 0.063 4.9E+00 8.8E+02 1.3E-08 1.4E-05 109-99-9 -Tetrah drofuran 15 0.15 1.8E+03 1.7E-05 142-82-5 Heptane, N- 0 0 3.5E+02 0.0E+00 110-54-3 Hexane N- 3.6 0.036 6.1E+02 1.2E-05 67-63-0 Iso ro anol 12 0.12 1.8E+02 1.4E-04 78-93-3 Methyl Ethyl Ketone 2-Butanone 18 0.18 4.4E+03 8.2E-06 75-09-2 Methylene Chloride 1.5 0.015 1.2E+03 5.3E+02 1.2E-I I 5.7E-06 91-20-3 -Naphthalene 4.3 0.043 3.6E-01 2.6E+00 1.2E-07 3.3E-03 10042-5 Styrene 5.6 0.056 8.8E+02 1.3E-05 127-18-4 Tetrachloroeth lene 7.7 0.077 4.7E+01 3.5E+01 1.6E-09 4.4E-04 108-88-3 Toluene 74 0.74 4.4E+03 3.4E-05 79-01-6 Trichloroeth lene 0 0 3.0E+00 1.8E+00 0.0E+00 0.0E+00 75-694 Trichlorofluoromethane 38 0.38 108-67-8 Trimeth ]benzene 1 3 5- 2.6 0.026 5.3E+01 9.9E-05 10642-3 X lene P- 30 0.3 8.8E+01 6.8E-04 108-38-3 X lene m- 0 0 8.8E+01 0.0E+00 9547-6 X lene o- 8.7 0.087 8.8E+01 2.0E-04 Cumulative: 1.6E-07 I 5.2E-03 North Carolina DEQ Risk Calculator Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. All nnncentratin- are in _/m3 CAS # Chemical Name: Soil Gas Concentration 3 (uglm) Calculated Indoor Air Concentration Co (ug/m') Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non - Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 78 0.78 2.7E+04 5.7E-06 71-43-2 Benzene 2.8 0.028 1.6E+00 2.6E+01 1.8E-08 2.1E-04 75-71-8 Dichlorodifluoromethane 1.4 0.014 8.8E+01 3.2E-05 141-78-6 Ethyl Acetate 2.5 0.025 6.1E+01 8.2E-05 100-41-4 Eth ]benzene 6.1 0.061 4.9E+00 8.8E+02 1.2E-08 1.4E-05 109-99-9 -Tetrah drofuran 19 0.19 1.8E+03 2.2E-05 142-82-5 Heptane, N- 1.8 0.018 3.5E+02 1.0E-05 110-54-3 Hexane N- 2.1 0.021 6.1E+02 6.8E-06 67-63-0 Iso ro anol 10 0.1 1.8E+02 1.1E-04 78-93-3 Methyl Ethyl Ketone 2-Butanone 12 0.12 4.4E+03 5.5E-06 75-09-2 Methylene Chloride 1.6 0.016 1.2E+03 5.3E+02 1.3E-11 6.1E-06 91-20-3 -Naphthalene 3.1 0.031 3.6E-01 2.6E+00 8.6E-08 2.4E-03 100-42-5 Styrene 5.4 0.054 8.8E+02 1.2E-05 127-18-4 Tetrachloroeth lene 26 0.26 4.7E+0I 3.5E+01 5.5E-09 1.5E-03 108-88-3 Toluene 63 0.63 4.4E+03 2.9E-05 79-01-6 Trichloroeth lene 0 0 3.0E+00 1.8E+00 0.0E+00 0.0E+00 75-69-4 Trichlorofluoromethane 39 0.39 108-67-8 Trimeth ]benzene 1 3 5- 2.2 0.022 5.3E+01 8.4E-05 106-42-3 X lene P- 28 0.28 8.8E+01 6.4E-04 108-38-3 X lene, m- 0 0 8.8E+O1 0.0E+00 95-47-6 X lene, o- 8.2 0.082 8.8E+01 1.9E-04 Cumulative: I 1.2E-07 1 5.3E-03 North Carolina DEQ Risk Cal -It., Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. All cnnrentm iri- are in nn/m' CAS €t Chemical Name: Soil Gas Concentration s (ug/m) Calculated Indoor Air Concentration (ug/m') Target Indoor Air Conc. for Carcinogens @ TCR = 1 E-06 Target Indoor Air Conc. for Non - Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 80 0.8 2.7E+04 5.9E-06 7143-2 Benzene 2.7 0.027 1.6E+00 2.6E+01 1.7E-08 2.1E-04 75-71-8 Dichlorodifluoromethane 1.4 0.014 8.8E+01 3.2E-05 141-78-6 Ethyl Acetate 2.9 0.029 6.1E+01 9.5E-05 100-41-4 Eth lbenzene 4.4 0.044 4.9E+00 8.8E+02 9.0E-09 1.0E-05 109-99-9 -Tetrah drofuran 13 0.13 1.8E+03 1.5E-05 142-82-5 Heptane, N- 2.1 0.021 3.5E+02 1.2E-05 110-54-3 Hexane N- 1.9 0.019 6.1E+02 6.2E-06 67-63-0 Iso ro anol 4.6 0.046 1.8E+02 5.3E-05 78-93-3 Methyl Ethyl Ketone 2-Butanone) 24 0.24 4.4E+03 1.1E-05 75-09-2 Methylene Chloride 0.93 0.0093 1.2E+03 5.3E+02 7.6E-12 3.5E-06 91-20-3 -Naphthalene 5.4 0.054 3.6E-01 2.6E+00 1.5E-07 4.1E-03 100-42-5 Styrene 4.8 0.048 8.8E+02 I.1E-05 127-184 Tetrachloroeth lene 18 0.18 4.7E+OI 3.5E+0l 3.8E-09 LOE-03 108-88-3 Toluene 73 0.73 4.4E+03 3.3E-05 76-13-1 Tiichloro-122-trifluoroethane 11,2- 1.1 0.011 4.4E+03 5.0E-07 79-01-6 Trichloroeth lene 4.8 0.048 3.0E+00 1.8E+00 1.6E-08 5.5E-03 75-694 Trichlorofluoromethane 34 0.34 108-67-8 Trimeth lbenzene 1 3 5- 2.5 0.025 5.3E+01 9.5E-05 106-42-3 X lene P- 20 0.2 8.8E+O1 4.6E-04 108-38-3 X lene ni 0 0 8.8E+01 0.0E+00 95-47-6 X lene o- 6.5 0.065 8.8E+01 1.5E-04 Cumulative: I 2.0E-07 1 1.2E-02 North Caroline DEQ Risk Calculator Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. All concentrations are in ue/m3 CAS # Chemical Name: Soil Gas Concentration , (uglm) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Cone. for Carcinogens @ TCR = 1 E-06 Target Indoor Air Cone. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 53 0.53 2.7E+04 3.9E-06 7143-2 Benzene 2.2 0.022 1.6E+00 2.6E+01 1.4E-08 1.7E-04 75-15-0 Carbon Disulfide 6.9 0.069 6.1E+02 2.3E-05 75-71-8 Dichlorodifluoromethane 1.4 0.014 8.8E+01 3.2E-05 141-78-6 Ethyl Acetate 0 0 6.1E+01 0.0E+00 100-414 Eth ]benzene 3.8 0.038 4.9E+00 8.8E+02 7.7E-09 8.7E-06 109-99-9 -Tetrah drofuran 6.5 0.065 1.8E+03 7.4E-06 142-82-5 Heptane, N- 1.3 0.013 3.5E+02 7.4E-06 110-54-3 Hexane N- 0 0 6.1 E+02 0.0E+00 67-63-0 Iso ro anol 4.1 0.041 1.8E+02 4.7E-05 78-93-3 Methyl Ethyl Ketone 2-Butanone 11 0.11 4.4E+03 5.0E-06 75-09-2 Methylene Chloride 0 0 1.2E+03 5.3E+02 0.0E+00 0.0E+00 91-20-3 -Naphthalene 3.6 0.036 3.6E-01 2.6E+00 1.0E-07 2.7E-03 10042-5 Styrene 4.4 0.044 8.8E+02 1.0E-05 127-18-4 Tetrachloroeth lene 14 0.14 4.7E+01 3.5E+01 3.0E-09 8.0E-04 108-88-3 Toluene 39 0.39 4.4E+03 1.8E-05 76-13-1 Trichloro-1 2 2-trifluoroethane 1 1 2- 0 0 4.4E+03 0.0E+00 79-01-6 Trichloroeth lene 6.3 0.063 3.0E+00 1.8E+00 2.1E-08 7.2E-03 75-69-4 Trichlorofluoromethane 42 0.42 108-67-8 Trimeth lbenzene 1 3 5- 2 0.02 5.3E+01 7.6E-05 106-42-3 X lene P- 18 0.18 8.8E+01 4.1E-04 108-38-3 X lene m- 0 0 8.8E+01 0.0E+00 9547-6 X lene o- 5.5 0.055 8.8E+0l I I 1.3E-04 Cumulative: I 1.5E-07 1 1.2E-02 North Caroline DEQ Risk Calculator APPENDIX D SUB -SLAB SOIL GAS VAPOR INTRUSION RESIDENTIAL RISK CALCULATIONS IS Mid Atlantic Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. All concentrations are in ue/m3 CAS # Chemical Name: Soil Gas Concentration (ug m) Calculated Indoor Air Concentration (ugIm3) Target Indoor Air Cone. for Carcinogens @ TCR = I E-06 Target Indoor Air Cone. for Non- Carcinogens (n THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 940 28.2 6.5E+03 8.7E-04 100-41-4 Eth lbenzene 4.9 0.147 1.1E+00 2.1E+02 1.3E-07 1.4E-04 67-63-0 Iso ro anol 120 3.6 4.2E+01 1.7E-02 78-93-3 Methyl Ethyl Ketone 2-Butanone 150 4.5 1.0E+03 8.6E-04 10042-5 Styrene 4.9 0.147 2.1 E+02 1.4E-04 127-18-4 Tetrachloroeth lene 14 0.42 1.1E+01 8.3E+00 3.9E-08 1.0E-02 108-88-3 Toluene 54 1.62 1.0E+03 3.1E-04 79-01-6 Trichlometh lene 4.6 0.138 4.8E-01 4.2E-01 2.9E_07 6.6E-02 75-694 Trichlorofluoromethane 62 1.86 t 0642-3 X lene, P- 21 0.63 2.1E+01 6.0E-03 708-38-3 X lene, m- 2.1E+01 9547-6 X lene, o- 6.7 0.201 2.1E+01 1.9E-03 Cumulative: I 4.6E-07 1 1.0E-01 North Carolina DEQ Risk Calculator Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. All concentrations are in ue/m; CAS # Chemical Name: Soil Gas Concentration 3 (ug/m) Calculated Indoor Air Concentration (ug/m3) Target indoor Air Conc. for Carcinogens (a, TCR = I E-06 Target Indoor Air Conc. for Non - Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 42 1.26 6.5E+03 3.9E-05 71-43-2 Benzene 1.9 0.057 3.6E-01 6.3E+00 1.6E-07 1.8E-03 75-71-8 Dichlorodifluoromethane 0 0 2.1E+01 0.0E+00 141-78-6 Ethyl Acetate 0 0 1.5E+01 0.0E+00 10041-4 Eth lbenzene 4.3 0.129 1.1E+00 2.1E+02 1.1E-07 1.2E-04 109-99-9 -Tetrah drofuran 4.7 0.141 4.2E+02 6.8E-05 142-82-5 He tane N- 1.3 0,039 8.3E+01 9.3E-05 110-54-3 Hexane, N- 0 0 1.5E+02 0.0E+00 67-63-0 Iso ro anol 9.6 0,288 4.2E+01 1.4E-03 78-93-3 Methyl Ethyl Ketone 2-Butanone 9.7 0.291 1.0E+03 5.6E-05 75-09-2 Methylene Chloride 1.3 0.039 I.OE+02 1.3E+02 3.8E-10 6.2E-05 91-20-3 -Naphthalene 3.7 0.111 8.3E-02 6.3E-01 1.3E-06 3.5E-02 10042-5 Styrene 4.3 0.129 2.1E+02 1.2E-04 127-184 Tetrachloroeth lene 13 0.39 1.1E+01 8.3E+00 3.6E-08 9.3E-03 108-88-3 Toluene 47 1.41 1.0E+03 2.7E-04 79-01-6 Trichloroeth lene 1.7 0.051 4.8E_01 4.2E-01 1.1E-07 2.4E-02 75-69-4 Trichlorofluoromethane 43 1.29 108-67-8 Trimeth lbenzene, 1,3,5- 2.1 0.063 1.3E+01 1.0E-03 106-42-3 X lene,P- 20 0.6 2.1E+O1 5.8E-03 108-38-3 X lene,m- 0 0 2.1E+01 0.0E+00 95-47-6 X lene, o- 6.2 0.186 2.1E+01 1.8E-03 Cumulative: I 1.8E-06 I 8.2E-02 North Carolina DEC Risk Calculator Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. All concentrations are in u,,/m3 CAS # Chemical Name: Soil Gas Concentration (ug/m3) Calculated indoorAir Concentration (ug/m) Target Indoor Air Conc. for Carcinogens@ TCR = 1 E-06 Target Indoor Air Conc. for Non - Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 50 1.5 6.5E+03 4.6E-05 71-43-2 Benzene 34 1.02 3.6E-01 6.3E+00 2.8E-06 3.3E-02 75-71-8 Dichlorodifluoromethane 1.3 0.039 2.1E+01 3.7E-04 141-78-6 Ethyl Acetate 2.7 0.081 1.5E+01 1.1E-03 100-41-4 Eth lbenzene 6.4 0.192 1.1E+00 2.1E+02 1.7E-07 7.8E-04 109-99-9 -Tetrah drofuran 5.8 0.174 4.2E+02 8.3E-05 142-82-5 He tane N- 2.5 0.075 8.3E+01 1.8E-04 110-54-3 Hexane N- 3.9 0.117 1.5E+02 1.6E-04 67-63-0 lso ro anol 11 0.33 4.2E+01 1.6E-03 78-93-3 Methyl Ethyl Ketone 2-Butanone 9.5 0.285 1.0E+03 5.5E-05 75-09-2 Methylene Chloride 0.93 0.0279 1.0E+02 1.3E+02 2.8E-10 4.5E-05 91-20-3 -Naphthalene 3.5 0.105 8.3E-02 6.3E-01 1.3E-06 3.4E-02 100-42-5 Styrene 6.2 0.186 2.1E+02 1.8E-04 127-18-4 Tetrachloroeth lene 9.8 0.294 LIE+01 8.3E+00 2.7E-08 7.0E-03 108-88-3 Toluene 63 L89 1.0E+03 3.6E-04 79-01-6 Trichloroeth lene 1.3 0.039 4.8E-01 4.2E-01 8.2E-08 1.9E-02 75-69-4 Trichlorofluoromethane 39 1.17 108-67-8 Trimeth lbenzene, 1,3.5- 2.9 0.087 1.3E+01 1.4E-03 10642-3 X lene, P- 30 0.9 2.1E+01 8.6E-03 108-38-3 X lene, m- 0 0 2.1E+01 0.0E+00 95-47-6 X lene,o- 9.6 0.288 2.IE+01 2.8E-03 Cumulative: I 4.4E-06 I LIE-01 North Carolina DEC, Risk Calculator North Carolina DEQ Risk Calculator Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. All concentrations are in us/m3 CAS # Chemical Name: Soil Gas Concentration s (ug m) Calculated Indoor Air Concentration (uglm3) Target Indoor Air Conc. for Carcinogens TCR = I E-06 Target Indoor Air Conc. for Non - Carcinogens THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 78 2.34 6.5E+03 7.2E-05 71-43-2 Benzene 2.8 0.084 3.6E-01 6.3E+00 2.3E-07 2.7E-03 75-71-8 Dichlorodifluoromethane 1.4 0.042 2.1E+01 4.0E-04 141-78-6 Ethyl Acetate 2.5 0,075 1.5E+01 1.0E-03 100-41-4 Eth ]benzene 6.1 0.183 1.1E+00 2.1E+02 1.6E-07 1.8E-04 109-99-9 -Tetrah drofuran 19 0.57 4.2E+02 2.7E-04 142-82-5 He tane. N- 1.8 0.054 8.3E+OI 1.3E-04 110-54-3 Hexane, N- 2.1 0.063 1.5E+02 8.6E-05 67-63-0 Iso ro anol 10 0.3 4.2E+01 1.4E-03 78-93-3 Methyl Ethyl Ketone 2-Butanone 12 0.36 1.0E+03 6.9E-05 75-09-2 Methylene Chloride 1.6 0.048 I.OE+02 1.3E+02 4.7E-10 7.7E-05 91-20-3 -Naphthalene 3.1 0.093 8.3E-02 6.3E-01 LIE-06 3.0E-02 100-42-5 Styrene 5.4 0.162 2.1E+02 1.6E-04 127-184 Tetrachloroeth lene 26 0.78 1.1E+01 8.3E+00 7.2E-08 1.9E-02 108-88-3 Toluene 63 1.89 1.0E+03 3.6E-04 79-01-6 Trichloroeth lene 0 0 4.8E-01 4.2E-01 0.0E+00 0.0E+00 75-694 Trichlorofluoromethane 39 1.17 108-67-8 Trimeth lbenzene, 1,3,5- 2.2 0.066 1.3E+01 1.1E 03 106-42-3 X lene, P- 28 0.84 2.1E+01 8.1E-03 108-38-3 1 X lene, m- 0 0 2.IE+01 0.0E+00 45-47-6 1 X lene, o- 1 8.2 0.246 2.1E+01 2.4E-03 Cumulative: I 1.6E-06 I 6.7E-02 North Carolina DEQ Risk Calculator North Carolina DEQ Risk Calculator Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. All concentrations are in nr,/m3 CAS # Chemical Name: Soil Gas Concentration s (ug/m) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens (a.) TCR = 1 E-06 Target Indoor Air Conc. for Non - Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 53 1.59 6.5E+03 4.9E-05 71-43-2 Benzene 2.2 0.066 3.6E-01 6.3E+00 1.8E-07 2.1E-03 75-15-0 Carbon Disulfide 6.9 0.207 1.5E+02 2.8E-04 75-71-8 Dichlorodifluoromethane 1.4 0.042 2.1E+01 4.0E-04 141-78-6 Ethyl Acetate 0 0 1.5E+01 0.0E+00 100-414 Eth lbenzene 3.8 0.114 1.1E+00 2.1 E+02 1.0E-07 1.1 E-04 109-99-9 -Tetrah drofuran 6.5 0.195 4.2E+02 9.3E-05 142-82-5 He tane, N- 1.3 0.039 8.3E+01 9.3E-05 110-54-3 Hexane, N- 0 0 1.5E+02 0.0E+00 67-63-0 Isoprophanol 4.1 0.123 4.2E+01 5.9E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone) 11 0.33 1.0E+03 6.3E-05 75-09-2 Methylene Chloride 0 0 1.0E+02 1.3E+02 0.0E+00 0.0E+00 91-20-3 -Naphthalene 3.6 0.108 8.3E-02 6.3E-01 1.3E-06 3.5E-02 10042-5 Styrene 4.4 0.132 2.1E+02 1.3E-04 127-18-4 Tetrachloroeth lene 14 0.42 1.1E+01 8.3E+00 3.9E-08 1.0E-02 108-88-3 Toluene 39 1.17 1.0E+03 2.2E-04 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 0 0 1.0E+03 0.0E+00 79-01-6 Trichloroeth lene 6.3 0,189 4.8E-01 4.2E-01 4.0E-07 9.1E-02 75-694 Trichlorofluoromethane 42 1.26 108-67-8 Trimeth ]benzene 1,3,5- 2 0.06 1.3E+01 9.6E-04 106-42-3 X lene, P- 18 0.54 2.1E+01 5.2E-03 108-38-3 X lene, m- 0 0 2.1E+01 0.0E+00 95-47-6 X lene, o- 5.5 0.165 2.1E+01 1.6E-03 Cumulative: I 2.0E-06 1 1.5E-01 North Carolina DEC Risk Calculator APPENDIX E INDOOR AIR NON-RESIDENTIAL RISK CALCULATIONS IS Mid Atlantic IDEO Risk Calculator - VanOC Intrusion - Non -Residential Worker Indoor Air r Version Date: May 2019 Basis: Mav 2019 EPA RSL Table Site ID: Unit ID: AMB-1 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/1113. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in u¢/m3 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Air Cone. for Carcinogens @ TCR = 1E-06 Target Indoor Air Cone. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 9.4 2.7E+04 6.9E-05 71-43-2 Benzene 0.22 1.6E+00 2.6E+01 1.4E-07 1.7E-03 75-71-8 Dichlorodifluoromethane 2 8.8E+01 4.6E-03 100-41-4 Ethylbenzene 0 4.9E+00 8.8E+02 0.0E+00 0.0E+00 109-99-9 -Tetrahydrofuran 0 1.8E+03 0.0E+00 142-82-5 Heptane, N- 0.2 3.5E+02 1.1E-04 110-54-3 Hexane, N- 0 6.1E+02 0.0E+00 67-63-0 Isopropanol 0 1.8E+02 0.0E+00 78-93-3 Methyl Ethyl Ketone (2-Butanone) 0 4.4E+03 0.0E+00 91-20-3 -Naphthalene 0.67 3.6E-01 2.6E+00 1.9E-06 5.1E-02 127-18-4 Tetrachloroethylene 0 4.7E+01 3.5E+01 0.0E+00 0.0E+00 108-88-3 Toluene 1.1 4.4E+03 5.0E-05 75-69-4 Trichlorofluoromethane 1 108-67-8 Trimethylbenzene, 1,3,5- 0 5.3E+01 0.0E+00 106-42-3 Xylene, P- 0.41 8.8E+01 9.4E-04 108-38-3 Xylene, m- 0 8.8E+01 0.0E+00 95-47-6 Xylene, o- 0.18 8.8E+01 4.1E-04 Cumulative: I 2.0E-06 5.9E-02 North Carolina DEQ Risk Calculator IDEO Risk Calculator - VanOC Intrusion - Non -Residential Worker Indoor Air r Version Date: May 2019 Basis: Mav 2019 EPA RSL Table Site ID: Unit ID: IA-1 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/1113. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in u¢/m3 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Air Cone. for Carcinogens @ TCR = 1E-06 Target Indoor Air Cone. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 79 2.7E+04 5.8E-04 71-43-2 Benzene 0.36 1.6E+00 2.6E+01 2.3E-07 2.7E-03 75-71-8 Dichlorodifluoromethane 2.3 8.8E+01 5.3E-03 100-41-4 Ethylbenzene 10 4.9E+00 8.8E+02 2.0E-06 2.3E-03 109-99-9 -Tetrahydrofuran 2.1 1.8E+03 2.4E-04 142-82-5 Heptane, N- 5.6 3.5E+02 3.2E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone) 120 4.4E+03 5.5E-03 91-20-3 -Naphthalene 9 3.6E-01 2.6E+00 2.5E-05 6.8E-01 127-18-4 Tetrachloroethylene 0.89 4.7E+01 3.5E+01 1.9E-08 5.1E-03 108-88-3 Toluene 61 4.4E+03 2.8E-03 75-69-4 Trichlorofluoromethane 2.4 108-67-8 Trimethylbenzene, 1,3,5- 2.1 5.3E+01 8.0E-03 106-42-3 Xylene, P- 61 8.8E+01 1.4E-01 108-38-3 Xylene, m- 0 8.8E+01 0.0E+00 95-47-6 Xylene, o- 26 8.8E+01 5.9E-02 Cumulative: I 2.7E-05 9.2E-01 North Carolina DEQ Risk Calculator IDEO Risk Calculator - VanOC Intrusion - Non -Residential Worker Indoor Air r Version Date: May 2019 Basis: Mav 2019 EPA RSL Table Site ID: Unit ID: IA-1 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/1113. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in u¢/m3 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Air Cone. for Carcinogens @ TCR = 1E-06 Target Indoor Air Cone. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 70 2.7E+04 5.2E-04 71-43-2 Benzene 0.34 1.6E+00 2.6E+01 2.2E-07 2.6E-03 75-71-8 Dichlorodifluoromethane 2.9 8.8E+01 6.6E-03 100-41-4 Ethylbenzene 9.7 4.9E+00 8.8E+02 2.0E-06 2.2E-03 109-99-9 -Tetrahydrofuran 2.1 1.8E+03 2.4E-04 142-82-5 Heptane, N- 5.5 3.5E+02 3.1E-03 67-63-0 Isopropanol 4.6 1.8E+02 5.3E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone) 94 4.4E+03 4.3E-03 91-20-3 -Naphthalene 9.2 3.6E-01 2.6E+00 2.6E-05 7.0E-01 127-18-4 Tetrachloroethylene 0.95 4.7E+01 3.5E+01 2.0E-08 5.4E-03 108-88-3 Toluene 62 4.4E+03 2.8E-03 75-69-4 Trichlorofluoromethane 2.3 108-67-8 Trimethylbenzene,1,3,5- 2 5.3E+01 7.6E-03 106-42-3 Xylene, P- 59 8.8E+01 1.3E-01 108-38-3 Xylene, m- 0 8.8E+01 0.0E+00 95-47-6 Xylene, o- 25 8.8E+01 5.7E-02 Cumulative: I 2.8E-05 9.3E-01 North Carolina DEQ Risk Calculator IDEO Risk Calculator - VanOC Intrusion - Non -Residential Worker Indoor Air r Version Date: May 2019 Basis: Mav 2019 EPA RSL Table Site ID: Unit ID: IA-2 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/1113. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in u¢/m3 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Air Cone. for Carcinogens @ TCR = 1E-06 Target Indoor Air Cone. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 74 2.7E+04 5.4E-04 71-43-2 Benzene 0.78 1.6E+00 2.6E+01 5.0E-07 5.9E-03 75-71-8 Dichlorodifluoromethane 1.7 8.8E+01 3.9E-03 100-41-4 Ethylbenzene 9.5 4.9E+00 8.8E+02 1.9E-06 2.2E-03 109-99-9 -Tetrahydrofuran 2 1.8E+03 2.3E-04 142-82-5 Heptane, N- 5.5 3.5E+02 3.1E-03 67-63-0 Isopropanol 7.7 1.8E+02 8.8E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone) 74 4.4E+03 3.4E-03 91-20-3 -Naphthalene 8.6 3.6E-01 2.6E+00 2.4E-05 6.5E-01 127-18-4 Tetrachloroethylene 0.91 4.7E+01 3.5E+01 1.9E-08 5.2E-03 108-88-3 Toluene 61 4.4E+03 2.8E-03 75-69-4 Trichlorofluoromethane 2.2 108-67-8 Trimethylbenzene,1,3,5- 2 5.3E+01 7.6E-03 106-42-3 Xylene, P- 57 8.8E+01 1.3E-01 108-38-3 Xylene, m- 0 8.8E+01 0.0E+00 95-47-6 Xylene, o- 25 8.8E+01 5.7E-02 Cumulative: I 2.6E-05 8.9E-01 North Carolina DEQ Risk Calculator IDEO Risk Calculator - VanOC Intrusion - Non -Residential Worker Indoor Air r Version Date: May 2019 Basis: Mav 2019 EPA RSL Table Site ID: Unit ID: IA-3 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/1113. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in u¢/m3 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Air Cone. for Carcinogens @ TCR = 1E-06 Target Indoor Air Cone. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 100 2.7E+04 7.4E-04 71-43-2 Benzene 0.39 1.6E+00 2.6E+01 2.5E-07 3.0E-03 75-71-8 Dichlorodifluoromethane 2.1 8.8E+01 4.8E-03 100-41-4 Ethylbenzene 14 4.9E+00 8.8E+02 2.9E-06 3.2E-03 109-99-9 -Tetrahydrofuran 2.3 1.8E+03 2.6E-04 142-82-5 Heptane, N- 8.9 3.5E+02 5.1E-03 110-54-3 Hexane, N- 5.1 6.1E+02 1.7E-03 67-63-0 Isopropanol 6.2 1.8E+02 7.1E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone) 140 4.4E+03 6.4E-03 91-20-3 -Naphthalene 10 3.6E-01 2.6E+00 2.8E-05 7.6E-01 127-18-4 Tetrachloroethylene 1.3 4.7E+01 3.5E+01 2.8E-08 7.4E-03 108-88-3 Toluene 150 4.4E+03 6.8E-03 75-69-4 Trichlorofluoromethane 3.2 108-67-8 Trimethylbenzene, 1,3,5- 2.5 5.3E+01 9.5E-03 106-42-3 Xylene, P- 88 8.8E+01 2.0E-01 108-38-3 Xylene, m- 0 8.8E+01 0.0E+00 95-47-6 Xylene, o- 36 8.8E+01 8.2E-02 Cumulative: I 3.1E-05 1.1 E+00 North Carolina DEQ Risk Calculator IDEO Risk Calculator - VanOC Intrusion - Non -Residential Worker Indoor Air r Version Date: May 2019 Basis: Mav 2019 EPA RSL Table Site ID: Unit ID: IA-4 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/1113. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in u¢/m3 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Air Cone. for Carcinogens @ TCR = 1E-06 Target Indoor Air Cone. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 75 2.7E+04 5.5E-04 71-43-2 Benzene 0.32 1.6E+00 2.6E+01 2.0E-07 2.4E-03 75-71-8 Dichlorodifluoromethane 1.4 8.8E+01 3.2E-03 100-41-4 Ethylbenzene 7.8 4.9E+00 8.8E+02 1.6E-06 1.8E-03 109-99-9 -Tetrahydrofuran 1.7 1.8E+03 1.9E-04 142-82-5 Heptane, N- 3.8 3.5E+02 2.2E-03 110-54-3 Hexane, N- 0 6.1E+02 0.0E+00 67-63-0 Isopropanol 0 1.8E+02 0.0E+00 78-93-3 Methyl Ethyl Ketone (2-Butanone) 140 4.4E+03 6.4E-03 91-20-3 -Naphthalene 7.7 3.6E-01 2.6E+00 2.1E-05 5.9E-01 127-18-4 Tetrachloroethylene 0.76 4.7E+01 3.5E+01 1.6E-08 4.3E-03 108-88-3 Toluene 31 4.4E+03 1.4E-03 75-69-4 Trichlorofluoromethane 2.1 108-67-8 Trimethylbenzene, 1,3,5- 2 5.3E+01 7.6E-03 106-42-3 Xylene, P- 45 8.8E+01 1.0E-01 108-38-3 Xylene, m- 0 8.8E+01 0.0E+00 95-47-6 Xylene, o- 19 8.8E+01 4.3E-02 Cumulative: I 2.3E-05 7.6E-01 North Carolina DEQ Risk Calculator APPENDIX F INDOOR AIR RESIDENTIAL RISK CALCULATIONS IS Mid Atlantic IDEO Risk Calculator - VaDor Intrusion - Resident Indoor Air ersion Date: May 2019 asis: May 2019 EPA RSL Table to ID: Unit ID: AMB-1 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in ue/m3 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Air Cone. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 9.4 6.5E+03 2.9E-04 71-43-2 Benzene 0.22 3.6E-01 6.3E+00 6.1E-07 7.0E-03 75-71-8 Dichlorodifluoromethane 2 2.1E+01 1.9E-02 100-41-4 Ethylbenzene 0 1.1E+00 2.1E+02 0.0E+00 0.0E+00 109-99-9 -Tetrahydrofuran 0 4.2E+02 0.0E+00 142-82-5 Heptane, N- 0.2 8.3E+01 4.8E-04 110-54-3 Hexane, N- 0 1.5E+02 0.0E+00 67-63-0 Isopropanol 0 4.2E+01 0.0E+00 78-93-3 Methyl Ethyl Ketone (2-Butanone) 0 1.0E+03 0.0E+00 91-20-3 -Naphthalene 0.67 8.3E-02 6.3E-01 8.1E-06 2.1E-01 127-18-4 Tetrachloroethylene 0 1.1E+01 8.3E+00 0.0E+00 0.0E+00 108-88-3 Toluene 1.1 1.0E+03 2.1E-04 75-69-4 Trichlorofluoromethane 1 108-67-8 Trimethylbenzene, 1,3,5- 0 1.3E+01 0.0E+00 106-42-3 Xylene, P- 0.41 2.1E+01 3.9E-03 108-38-3 Xylene, m- 0 2.1E+01 0.0E+00 95-47-6 Xylene, o- 0.18 2.1E+01 1.7E-03 Cumulative: I 8.7E-06 I2.5E-01 North Carolina DEQ Risk Calculator IDEO Risk Calculator - VaDor Intrusion - Resident Indoor Air ersion Date: May 2019 asis: May 2019 EPA RSL Table to ID: Unit ID: IA-1 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in ue/m3 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Air Cone. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 79 6.5E+03 2.4E-03 71-43-2 Benzene 0.36 3.6E-01 6.3E+00 1.0E-06 1.2E-02 75-71-8 Dichlorodifluoromethane 2.3 2.1E+01 2.2E-02 100-41-4 Ethylbenzene 10 1.1E+00 2.1E+02 8.9E-06 9.6E-03 109-99-9 -Tetrahydrofuran 2.1 4.2E+02 1.0E-03 142-82-5 Heptane, N- 5.6 8.3E+01 1.3E-02 78-93-3 Methyl Ethyl Ketone (2-Butanone) 120 1.0E+03 2.3E-02 91-20-3 -Naphthalene 9 8.3E-02 6.3E-01 1.1E-04 2.9E+00 127-18-4 Tetrachloroethylene 0.89 1.1E+01 8.3E+00 8.2E-08 2.1E-02 108-88-3 Toluene 61 1.0E+03 1.2E-02 75-69-4 Trichlorofluoromethane 2.4 108-67-8 Trimethylbenzene, 1,3,5- 2.1 1.3E+01 3.4E-02 106-42-3 Xylene, P- 61 2.1E+01 5.8E-01 108-38-3 1 Xylene, m- 0 2.1E+01 0.0E+00 95-47-6 1 Xylene, o- 26 2.1E+01 2.5E-01 Cumulative: I 1.2E-04 I 3.9E+00 North Carolina DEQ Risk Calculator IDEO Risk Calculator - VaDor Intrusion - Resident Indoor Air ersion Date: May 2019 asis: May 2019 EPA RSL Table to ID: Unit ID: IA-1 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in ue/m3 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Air Cone. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 70 6.5E+03 2.2E-03 71-43-2 Benzene 0.34 3.6E-01 6.3E+00 9.4E-07 1.1E-02 75-71-8 Dichlorodifluoromethane 2.9 2.1E+01 2.8E-02 100-41-4 Ethylbenzene 9.7 1.1E+00 2.1E+02 8.6E-06 9.3E-03 109-99-9 -Tetrahydrofuran 2.1 4.2E+02 1.0E-03 142-82-5 Heptane, N- 5.5 8.3E+01 1.3E-02 67-63-0 Isopropanol 4.6 4.2E+01 2.2E-02 78-93-3 Methyl Ethyl Ketone (2-Butanone) 94 1.0E+03 1.8E-02 91-20-3 -Naphthalene 9.2 8.3E-02 6.3E-01 1.1E-04 2.9E+00 127-18-4 Tetrachloroethylene 0.95 1.1E+01 8.3E+00 8.8E-08 2.3E-02 108-88-3 Toluene 62 1.0E+03 1.2E-02 75-69-4 Trichlorofluoromethane 2.3 108-67-8 Trimethylbenzene, 1,3,5- 2 1.3E+01 3.2E-02 106-42-3 Xylene, P- 59 2.1E+01 5.7E-01 108-38-3 Xylene, m- 0 2.1E+01 0.0E+00 95-47-6 Xylene, o- 25 2.1E+01 2.4E-01 Cumulative: I 1.2E-04 I 3.9E+00 North Carolina DEQ Risk Calculator IDEO Risk Calculator - VaDor Intrusion - Resident Indoor Air ersion Date: May 2019 asis: May 2019 EPA RSL Table to ID: Unit ID: IA-2 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in ue/m3 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Air Cone. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 74 6.5E+03 2.3E-03 71-43-2 Benzene 0.78 3.6E-01 6.3E+00 2.2E-06 2.5E-02 75-71-8 Dichlorodifluoromethane 1.7 2.1E+01 1.6E-02 100-41-4 Ethylbenzene 9.5 1.1E+00 2.1E+02 8.5E-06 9.1E-03 109-99-9 -Tetrahydrofuran 2 4.2E+02 9.6E-04 142-82-5 Heptane, N- 5.5 8.3E+01 1.3E-02 67-63-0 Isopropanol 7.7 4.2E+01 3.7E-02 78-93-3 Methyl Ethyl Ketone (2-Butanone) 74 1.0E+03 1.4E-02 91-20-3 -Naphthalene 8.6 8.3E-02 6.3E-01 1.0E-04 2.7E+00 127-18-4 Tetrachloroethylene 0.91 1.1E+01 8.3E+00 8.4E-08 2.2E-02 108-88-3 Toluene 61 1.0E+03 1.2E-02 75-69-4 Trichlorofluoromethane 2.2 108-67-8 Trimethylbenzene, 1,3,5- 2 1.3E+01 3.2E-02 106-42-3 Xylene, P- 57 2.1E+01 5.5E-01 108-38-3 Xylene, m- 0 2.1E+01 0.0E+00 95-47-6 Xylene, o- 25 2.1E+01 2.4E-01 Cumulative: I 1.1E-04 I 3.7E+00 North Carolina DEQ Risk Calculator IDEO Risk Calculator - VaDor Intrusion - Resident Indoor Air ersion Date: May 2019 asis: May 2019 EPA RSL Table to ID: Unit ID: IA-3 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in ue/m3 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Air Cone. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 100 6.5E+03 3.1E-03 71-43-2 Benzene 0.39 3.6E-01 6.3E+00 1.1E-06 1.2E-02 75-71-8 Dichlorodifluoromethane 2.1 2.1E+01 2.0E-02 100-41-4 Ethylbenzene 14 1.1E+00 2.1E+02 1.2E-05 1.3E-02 109-99-9 -Tetrahydrofuran 2.3 4.2E+02 1.1E-03 142-82-5 Heptane, N- 8.9 8.3E+01 2.1E-02 110-54-3 Hexane, N- 5.1 1.5E+02 7.0E-03 67-63-0 Isopropanol 6.2 4.2E+01 3.0E-02 78-93-3 Methyl Ethyl Ketone (2-Butanone) 140 1.0E+03 2.7E-02 91-20-3 -Naphthalene 10 8.3E-02 6.3E-01 1.2E-04 3.2E+00 127-18-4 Tetrachloroethylene 1.3 1.1E+01 8.3E+00 1.2E-07 3.1E-02 108-88-3 Toluene 150 1.0E+03 2.9E-02 75-69-4 Trichlorofluoromethane 3.2 108-67-8 Trimethylbenzene, 1,3,5- 2.5 1.3E+01 4.0E-02 106-42-3 Xylene, P- 88 2.1E+01 8.4E-01 108-38-3 Xylene, m- 0 2.1E+01 0.0E+00 95-47-6 Xylene, o- 36 2.1E+01 3.5E-01 Cumulative: I 1.3E-04 I4.6E+00 North Carolina DEQ Risk Calculator IDEO Risk Calculator - VaDor Intrusion - Resident Indoor Air ersion Date: May 2019 asis: May 2019 EPA RSL Table to ID: Unit ID: IA-4 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in ue/m3 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Air Cone. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 75 6.5E+03 2.3E-03 71-43-2 Benzene 0.32 3.6E-01 6.3E+00 8.9E-07 1.0E-02 75-71-8 Dichlorodifluoromethane 1.4 2.1E+01 1.3E-02 100-41-4 Ethylbenzene 7.8 1.1E+00 2.1E+02 6.9E-06 7.5E-03 109-99-9 -Tetrahydrofuran 1.7 4.2E+02 8.2E-04 142-82-5 Heptane, N- 3.8 8.3E+01 9.1E-03 110-54-3 Hexane, N- 0 1.5E+02 0.0E+00 67-63-0 Isopropanol 0 4.2E+01 0.0E+00 78-93-3 Methyl Ethyl Ketone (2-Butanone) 140 1.0E+03 2.7E-02 91-20-3 -Naphthalene 7.7 8.3E-02 6.3E-01 9.3E-05 2.5E+00 127-18-4 Tetrachloroethylene 0.76 1.1E+01 8.3E+00 7.0E-08 1.8E-02 108-88-3 Toluene 31 1.0E+03 5.9E-03 75-69-4 Trichlorofluoromethane 2.1 108-67-8 Trimethylbenzene, 1,3,5- 2 1.3E+01 3.2E-02 106-42-3 Xylene, P- 45 2.1E+01 4.3E-01 108-38-3 Xylene, m- 0 2.1E+01 0.0E+00 95-47-6 Xylene, o- 19 2.1E+01 1.8E-01 Cumulative: I 1.0E-04 I3.2E+00 North Carolina DEQ Risk Calculator APPENDIX G ADJUSTED VALUES INDOOR AIR NON-RESIDENTIAL RISK CALCULATIONS IS Mid Atlantic DEQ Risk Calculator - Vapor Intrusion - Non -Residential Worker Indoor Air Llama WITow Version Date: May 2019 Basis: May 2019 EPA RSL Table Site ID: _:2L a Unit ID: Adiusted values IA-1 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in uo/m3 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 79 2.7E+04 5.8E-04 7143-2 Benzene 0.36 1.6E+00 2.6E+01 2.3E-07 2.7E-03 75-71-8 Dichlorodifluoromethane 0.47 8.8E+01 1.1E-03 100-41-4 Eth lbenzene 0.83 4.9E+00 8.8E+02 1.7E-07 1.9E-04 109-99-9 -Tetrah drofuran 2.1 1.8E+03 2.4E-04 142-82-5 Heptane, N- 0.41 3.5E+02 2.3E-04 78-93-3 Methyl Ethyl Ketone 2-Butanone 120 4.4E+03 5.5E-03 91-20-3 -Naphthalene 0.68 3.6E-01 2.6E+00 1.9E-06 5.2E-02 127-184 Tetrachloroeth lene 0.89 4.7E+01 3.5E+01 1.9E-08 5.1E-03 108-88-3 Toluene 9.15 4.4E+03 4.2E-04 75-694 Trichlorofluoromethane 2.4 108-67-8 Trimeth lbenzene, 1,3,5- 2.1 5.3E+01 8.0E-03 10642-3 X lene, P- 3.56 8.8E+01 8.1E-03 108-38-3 1 X lene, m- 0 8.8E+01 0.0E+00 9547-6 1 X lene, o- 1.14 8.8E+01 2.6E-03 Cumulative: I 2.3E-06 8.7E-02 North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non -Residential Worker Indoor Air Llama WITow Version Date: May 2019 Basis: May 2019 EPA RSL Table Site ID: :2L a Unit ID: Adiusted values IA-1 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in uo/m3 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 70 2.7E+04 5.2E-04 7143-2 Benzene 0.34 1.6E+00 2.6E+01 2.2E-07 2.6E-03 75-71-8 Dichlorodifluoromethane 0.47 8.8E+01 1.1E-03 100-41-4 Eth lbenzene 0.83 4.9E+00 8.8E+02 1.7E-07 1.9E-04 109-99-9 -Tetrah drofuran 2.1 1.8E+03 2.4E-04 142-82-5 Heptane, N- 0.41 3.5E+02 2.3E-04 110-54-3 Hexane, N- 1.05 6.1E+02 3.4E-04 67-63-0 Iso ro anol 4.6 1.8E+02 5.3E-03 78-93-3 Methyl Ethyl Ketone 2-Butanone 94 4.4E+03 4.3E-03 91-20-3 -Naphthalene 0.68 3.6E-01 2.6E+00 1.9E-06 5.2E-02 127-184 Tetrachloroeth lene 0.95 4.7E+01 3.5E+01 2.0E-08 5.4E-03 108-88-3 Toluene 9.15 4.4E+03 4.2E-04 75-694 Trichlorofluoromethane 2.3 108-67-8 Trimeth lbenzene, 1,3,5- 2 5.3E+01 7.6E-03 10642-3 X lene, P- 3.56 8.8E+01 8.1E-03 108-38-3 X lene, m- 0 8.8E+01 0.0E+00 9547-6 X lene, o- 1.14 8.8E+01 2.6E-03 Cumulative: I 2.3E-06 9.1E-02 North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non -Residential Worker Indoor Air Llama WITow Version Date: May 2019 Basis: May 2019 EPA RSL Table Site ID: _:2L a Unit ID: Adiusted values IA-2 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All cnncentrntions are in uo/m3 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 74 2.7E+04 5.4E-04 7143-2 Benzene 0.78 1.6E+00 2.6E+01 5.0E-07 5.9E-03 75-71-8 Dichlorodifluoromethane 0.1 8.8E+01 2.3E-04 100-41-4 Eth lbenzene 1.08 4.9E+00 8.8E+02 2.2E-07 2.5E-04 109-99-9 -Tetrah drofuran 2 1.8E+03 2.3E-04 142-82-5 He tane, N- 0.42 3.5E+02 2.4E-04 110-54-3 Hexane, N- 0.66 6.1E+02 2.2E-04 67-63-0 Iso ro anol 7.7 1.8E+02 8.8E-03 78-93-3 Methyl Ethyl Ketone 2-Butanone 74 4.4E+03 3.4E-03 91-20-3 -Naphthalene 0.63 3.6E-01 2.6E+00 1.7E-06 4.8E-02 127-184 Tetrachloroeth lene 0.91 4.7E+01 3.5E+01 1.9E-08 5.2E-03 108-88-3 Toluene 10.68 4.4E+03 4.9E-04 75-694 Trichlorofluoromethane 2.2 108-67-8 Trimeth lbenzene, 1,3,5- 2 5.3E+01 7.6E-03 10642-3 X lene, P- 5.08 8.8E+01 1.2E-02 108-38-3 X lene, m- 0 8.8E+01 0.0E+00 9547-6 X lene, o- 1.63 8.8E+01 3.7E-03 Cumulative: I 2.5E-06 9.6E-02 North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non -Residential Worker Indoor Air Llama WITow Version Date: May 2019 Basis: May 2019 EPA RSL Table Site ID: _:2L a Unit ID: Adiusted values IA-3 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in uo/m3 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 100 2.7E+04 7.4E-04 7143-2 Benzene 0.39 1.6E+00 2.6E+01 2.5E-07 3.0E-03 75-71-8 Dichlorodifluoromethane 0.1 8.8E+01 2.3E-04 100-41-4 Eth lbenzene 1.07 4.9E+00 8.8E+02 2.2E-07 2.4E-04 109-99-9 -Tetrah drofuran 2.3 1.8E+03 2.6E-04 142-82-5 Heptane, N- 0.31 3.5E+02 1.8E-04 110-54-3 Hexane, N- 0.61 6.1E+02 2.0E-04 67-63-0 Iso ro anol 6.2 1.8E+02 7.1E-03 78-93-3 Methyl Ethyl Ketone 2-Butanone 140 4.4E+03 6.4E-03 91-20-3 -Naphthalene 0.73 3.6E-01 2.6E+00 2.0E-06 5.6E-02 127-184 Tetrachloroeth lene 1.3 4.7E+01 3.5E+01 2.8E-08 7.4E-03 108-88-3 Toluene 12.54 4.4E+03 5.7E-04 75-694 Trichlorofluoromethane 3.2 108-67-8 Trimeth lbenzene, 1,3,5- 2.5 5.3E+01 9.5E-03 10642-3 X lene, P- 5.08 8.8E+01 1.2E-02 108-38-3 X lene, m- 0 8.8E+01 0.0E+00 9547-6 X lene, o- 1.47 8.8E+01 3.4E-03 Cumulative: I 2.5E-06 1.1E-01 North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non -Residential Worker Indoor Air Llama WITow Version Date: May 2019 Basis: May 2019 EPA RSL Table JL Site ID: ft�_ Unit ID: Adiustes values IA-4 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in uo/m3 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 75 2.7E+04 5.5E-04 7143-2 Benzene 0.32 1.6E+00 2.6E+01 2.0E-07 2.4E-03 75-71-8 Dichlorodifluoromethane 0.1 8.8E+01 2.3E-04 100-41-4 Eth lbenzene 0.75 4.9E+00 8.8E+02 1.5E-07 1.7E-04 109-99-9 -Tetrah drofuran 1.7 1.8E+03 1.9E-04 142-82-5 Heptane, N- 0.36 3.5E+02 2.1E-04 110-54-3 Hexane, N- 0.32 6.1E+02 1.0E-04 67-63-0 Iso ro anol 0 1.8E+02 0.0E+00 78-93-3 Methyl Ethyl Ketone 2-Butanone 140 4.4E+03 6.4E-03 91-20-3 -Naphthalene 0.92 3.6E-01 2.6E+00 2.6E-06 7.0E-02 127-184 Tetrachloroeth lene 0.76 4.7E+01 3.5E+01 1.6E-08 4.3E-03 108-88-3 Toluene 12.37 4.4E+03 5.6E-04 75-694 Trichlorofluoromethane 2.1 108-67-8 Trimeth lbenzene, 1,3,5- 2 5.3E+01 7.6E-03 10642-3 X lene, P- 3.39 8.8E+01 7.7E-03 108-38-3 X lene, m- 0 8.8E+01 0.0E+00 9547-6 X lene, o- 1.1 8.8E+01 2.5E-03 Cumulative: I 2.9E-06 1.0E-0 l North Carolina DEQ Risk Calculator APPENDIX H ADJUSTED VALUES INDOOR AIR RESIDENTIAL RISK CALCULATIONS IS Mid Atlantic DEQ Risk Calculator - Vapor Intrusion - Resident Indoor Air Version Date: May 2019 Basis: May 2019 EPA RSL Table Site ID: Exposure Unit ID: Adjusted values IA-1 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in u m3 3.6E-01 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Au Conc. for Carcinogens @ TCR = 1 E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 79 - 6.5E+03 2.4E-03 71-43-2 Benzene 0.36 3.6E-01 6.3E+00 1.0E-06 1.2E-02 75-71-8 Dichlorodifluoromethane 0.47 - 2.1E+01 4.5E-03 100-41-4 Eth lbenzene 0.83 1.1E+00 2.1E+02 7.4E-07 8.0E-04 109-99-9 -Tetrah drofuran 2.1 - 4.2E+02 1.0E-03 142-82-5 Heptane, N- 0.41 - 8.3E+01 9.8E-04 110-54-3 Hexane, N- 1.05 - 1.5E+02 1.4E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone) 120 - 1.0E+03 2.3E-02 91-20-3 _Naphthalene 0.68 8.3E-02 6.3E-01 8.2E-06 2.2E-01 127-18-4 Tetrachloroethylene 0.89 1.1E+01 8.3E+00 8.2E-08 2.1E-02 108-88-3 Toluene 9.15 - 1.0E+03 1.8E-03 75-69-4 Trichlorofluoromethane 2.4 - - 108-67-8 Trimethylbenzene, 1,3,5- 2.1 - 1.3E+01 3.4E-02 106-42-3 Xylene, P- 3.56 - 2.1E+01 3.4E-02 108-38-3 Xylene, in- 0 - 2.1E+01 0.0E+00 95-47-6 Xylene, o- 1.14 - 2.1E+01 1.1E-02 North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Indoor Air Version Date: May 2019 Basis: May 2019 EPA RSL Table Site ID: Exposure Unit ID: Adjusted values IA-1 Duplicate ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in u m3 3.8E-01 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Au Conc. for Carcinogens @ TCR = 1 E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 70 - 6.5E+03 2.2E-03 71-43-2 Benzene 0.34 3.6E-01 6.3E+00 9.4E-07 1.1E-02 75-71-8 Dichlorodifluoromethane 0.47 - 2.1E+01 4.5E-03 100-41-4 Eth lbenzene 0.83 1.1E+00 2.1E+02 7.4E-07 8.0E-04 109-99-9 -Tetrah drofuran 2.1 - 4.2E+02 1.0E-03 142-82-5 Heptane, N- 0.41 - 8.3E+01 9.8E-04 110-54-3 Hexane, N- 1.05 - 1.5E+02 1.4E-03 67-63-0 Isopropanol 4.6 - 4.2E+01 2.2E-02 78-93-3 Methyl Ethyl Ketone (2-Butanone) 94 - 1.0E+03 1.8E-02 91-20-3 _Naphthalene 0.68 8.3E-02 6.3E-01 8.2E-06 2.2E-01 127-18-4 Tetrachloroethylene 0.95 1.1E+01 8.3E+00 8.8E-08 2.3E-02 108-88-3 Toluene 9.15 - 1.0E+03 1.8E-03 75-69-4 Trichlorofluoromethane 2.3 - - 108-67-8 Trimethylbenzene, 1,3,5- 2 - 1.3E+01 3.2E-02 106-42-3 Xylene, P- 3.56 - 2.1E+01 3.4E-02 108-38-3 Xylene, in- 0 - 2.1E+01 0.0E+00 95-47-6 Xylene, o- 1.14 - 2.1E+01 1.1E-02 North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Indoor Air Version Date: May 2019 Basis: May 2019 EPA RSL Table Site ID: Exposure Unit ID: Adjusted values IA-2 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in u m3 4.0E-01 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Au Conc. for Carcinogens @ TCR = 1 E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 74 - 6.5E+03 2.3E-03 71-43-2 Benzene 0.78 3.6E-01 6.3E+00 2.2E-06 2.5E-02 75-71-8 Dichlorodifluoromethane 0.1 - 2.1E+01 9.6E-04 100-41-4 Eth lbenzene 1.08 1.1E+00 2.1E+02 9.6E-07 1.0E-03 109-99-9 -Tetrah drofuran 2 - 4.2E+02 9.6E-04 142-82-5 Heptane, N- 0.42 - 8.3E+01 1.0E-03 110-54-3 Hexane, N- 0.66 - 1.5E+02 9.0E-04 67-63-0 Isopropanol 7.7 - 4.2E+01 3.7E-02 78-93-3 Methyl Ethyl Ketone (2-Butanone) 74 - 1.0E+03 1.4E-02 91-20-3 _Naphthalene 0.63 8.3E-02 6.3E-01 7.6E-06 2.0E-01 127-18-4 Tetrachloroethylene 0.91 1.1E+01 8.3E+00 8.4E-08 2.2E-02 108-88-3 Toluene 10.68 - 1.0E+03 2.0E-03 75-69-4 Trichlorofluoromethane 2.2 - - 108-67-8 Trimethylbenzene, 1,3,5- 2 - 1.3E+01 3.2E-02 106-42-3 Xylene, P- 5.08 - 2.1E+01 4.9E-02 108-38-3 Xylene, in- 0 - 2.1E+01 0.0E+00 95-47-6 Xylene, o- 1.63 - 2.1E+01 1.6E-02 North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Indoor Air Version Date: May 2019 Basis: May 2019 EPA RSL Table Site ID: Exposure Unit ID: Adjusted values IA-3 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in u m3 4.5E-01 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Au Conc. for Carcinogens @ TCR = 1 E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 100 - 6.5E+03 3.1E-03 71-43-2 Benzene 0.39 3.6E-01 6.3E+00 1.1E-06 1.2E-02 75-71-8 Dichlorodifluoromethane 0.1 - 2.1E+01 9.6E-04 100-41-4 Eth lbenzene 1.07 1.1E+00 2.1E+02 9.5E-07 1.0E-03 109-99-9 -Tetrah drofuran 2.3 - 4.2E+02 1.1E-03 142-82-5 Heptane, N- 0.31 - 8.3E+01 7.4E-04 110-54-3 Hexane, N- 0.61 - 1.5E+02 8.4E-04 67-63-0 Isopropanol 6.2 - 4.2E+01 3.0E-02 78-93-3 Methyl Ethyl Ketone (2-Butanone) 140 - 1.0E+03 2.7E-02 91-20-3 _Naphthalene 0.73 8.3E-02 6.3E-01 8.8E-06 2.3E-01 127-18-4 Tetrachloroethylene 1.3 1.1E+01 8.3E+00 1.2E-07 3.1E-02 108-88-3 Toluene 12.54 - 1.0E+03 2.4E-03 75-69-4 Trichlorofluoromethane 3.2 - - 108-67-8 Trimethylbenzene, 1,3,5- 2.5 - 1.3E+01 4.0E-02 106-42-3 Xylene, P- 5.08 - 2.1E+01 4.9E-02 108-38-3 Xylene, in- 0 - 2.1E+01 0.0E+00 95-47-6 Xylene, o- 1.47 - 2.1E+01 1.4E-02 North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Indoor Air Version Date: May 2019 Basis: May 2019 EPA RSL Table Site ID: Exposure Unit ID: Ad'ustes values IA-4 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in u m3 4.3E-01 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Au Conc. for Carcinogens @ TCR = 1 E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 75 - 6.5E+03 2.3E-03 71-43-2 Benzene 0.32 3.6E-01 6.3E+00 8.9E-07 1.0E-02 75-71-8 Dichlorodifluoromethane 0.1 - 2.1E+01 9.6E-04 100-41-4 Eth lbenzene 0.75 1.1E+00 2.1E+02 6.7E-07 7.2E-04 109-99-9 -Tetrah drofuran 1.7 - 4.2E+02 8.2E-04 142-82-5 Heptane, N- 0.36 - 8.3E+01 8.6E-04 110-54-3 Hexane, N- 0.32 - 1.5E+02 4.4E-04 67-63-0 Isopropanol 0 - 4.2E+01 0.0E+00 78-93-3 Methyl Ethyl Ketone (2-Butanone) 140 - 1.0E+03 2.7E-02 91-20-3 _Naphthalene 0.92 8.3E-02 6.3E-01 1.1E-05 2.9E-01 127-18-4 Tetrachloroethylene 0.76 1.1E+01 8.3E+00 7.0E-08 1.8E-02 108-88-3 Toluene 12.37 - 1.0E+03 2.4E-03 75-69-4 Trichlorofluoromethane 2.1 - - 108-67-8 Trimethylbenzene, 1,3,5- 2 - 1.3E+01 3.2E-02 106-42-3 Xylene, P- 3.39 - 2.1E+01 3.3E-02 108-38-3 Xylene, in- 0 - 2.1E+01 0.0E+00 95-47-6 Xylene, o- 1.1 - 2.1E+01 1.1E-02 North Carolina DEQ Risk Calculator APPENDIX I PHOTOGRAPHIC LOG OF SAMPLE LOCATIONS IS Mid Atlantic Photo 1 — Sub -slab soil gas sample collected from Azure Violins, Suite 119. Photo 3 — Sample location of SS-2 in Little Makers Academy, Suite 118. Photo 5 — Indoor Air sampling conducted in Little Makers Academy. Photo 7 — Indoor Air sampling conducted in Suite 17 Gateway Plaza — 2427 Crabtree Boulevard Raleigh, North Carolina Photo 2 — Sample location of Sub -slab soil gas sample SS-5 in Suite 117. Photo 4 — Indoor Air sampling conducted in Little Makers Academy. Photo 6 — Indoor Air sampling conducted in Azure Violins, Suite 119. Photo 8 — Outdoor Ambient Air sampling conducted in parking lot of site. Mid -Atlantic Associates, Inc. August 2019