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HomeMy WebLinkAbout8606_Surry_Lined_MSWLF_June20GW_FID1522109_20210106[YEN-R USE ONLY ❑Paper Report []Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR I IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Municipal Engineering Services Co., PA Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Jonathan Pfohl Phone: (919)772-5393 E-mail: jpfohl@mesco.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or. 1600) October 20-24, 2006) Surry County Lined MSWLF Mt. Landfill Road Airy, NC 27030 86-06 1 .1600 June 22-25, 2020 Mt. Environmental Status: (Check all that apply) Initial/Background Monitoring ❑X Detection Monitoring QX Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Groundwater monitoring data from private water supply wells El Leachate monitoring data ❑ Surface water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater -or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive -methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values -meeting_ or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Benjamin Clawson, P.E. Senior Project Manager (919) 772 5393 Facility Representative ame (Print) Title (Area Code) Telephone Number '��.�-- �� l Affix NC Licensed/ Professional Geologist Seal G AR0�/ii °OF E S Slo �i4- - a SEAL �• 033710 = �, ,,•• ciNEti. ICI Signature P.O. BOX 97, Garner, NC 27529 Facility Representative Address C-0281 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 Date Semi -Annual Water Quality Monitoring Report Benjamin Clawson, P.E. Senior Project Manager bclawson(a,mesco. com June 2020 Prepared for Surry County Lined Landfill Mt. Airy, North Carolina Permit No. 86-06 Prepared by Municipal Engineering Services Company, P.A. P.O. BOX 97 Garner, North Carolina MESCO Project Number: G20031.0 %tt E \fI MUNICIPAL ENGINEERING SERVICES COMPANY P.A. 68 SHIPWASH DRIVE, GARNER, NC 27529 •PHONE: 919.772.5393 P.O. BoX 344, BOONE, NC 28607 -PHONE: 828-,262.1767 LICENSE NUMBER; C-02B7 Jonathan Pfohl Environmental Specialist jpfohl(a,mesco.com Introduction On behalf of Surry County, Municipal Engineering Services Company, P.A. (MESCO) is pleased to present this Semi -Annual Water Quality Monitoring Report for an event performed at the Surry County Lined Municipal Solid Waste Landfill (MSWLF) in the Fall of 2019. NCDEQ Solid Waste Rules 15A NCAC 1313.1632 requires that Surry County provide this report to the SWS on a semi-annual basis. This report documents the quality of the ground and surface waters during a monitoring event performed between June 22-25, 2020. During this event a few constituents were detected above allowable regulatory compliance levels in samples collected from MW-6R, MW-9S and MW-11D. Surface water samples did not contain constituents in levels above applicable 213 Standards. The leachate samples continue to contain a few contaminants but were in low concentrations relative to Standards and published values. Background The Surry County Subtitle D lined MSWLF, permit #86-06, is located at 237 Landfill Road, Mount Airy, Surry County, North Carolina. The site location topographic map is depicted in the attached Sheet 1. The lined MSWLF is comprised of contiguous Phases 1-4 which are treated as a single unit in this report. Water quality at this facility has been monitored at least semi-annually since 1998 with all historical data reviewed in support of this report. This event was performed in accordance with the NC SWS rules/regulations as promulgated in 15A NCAC 13B and as a condition of the permit to operate. Assessment monitoring was initiated site -wide in response to detections of volatile organic compounds (VOCs) above allowable Standards in samples collected from MW-2, MW-6R and MW-9S in the spring of 2016. Assessment monitoring of MW-2, MW-6R and MW-9S and landfill gas monitoring of MGP-5 and MGP-12 continued during this event as approved by NCDEQ. An Alternative Source Demonstration Addendum (ASD-Add) which established Site Maximum Allowable Contaminate (SMAC) regulatory compliance levels for three metals (cadmium, cobalt, vanadium) was approved by the NCDEQ on April 20, 2020 (FID.1395468). As specified within 15A NCAC 13B.16320), the SWS Environmental Monitoring Report Form and SWS memorandums this report contains sampling procedures, field and laboratory results, groundwater and surface water characterization. Well construction summary table, field observations table, field parameter data table, sampling and analysis summary table, detections compared to Standards tables, a groundwater flow directions/rates table, potentiometric map, quality assurance/quality control data, and laboratory analytical data results are enclosed herein. Sampling Procedure MESCO personnel performed this sampling event using portable monitoring methodology in general accordance with the site -specific Water Quality Monitoring Plan dated July 12, 2018 (DIN:1234484) which was approved by the NC SWS on August 8, 2018 (DIN:1235187). Water samples were collected from 14 downgradient groundwater monitoring wells (MW-2, MW-3R, MW-4S, MW-4D, MW-5, MW-6R, MW-8, MW-9S, MW-9D, MW-10, MW-115, MW-1ID, MW-12, MW-13, MW-24, MW-25 and MW-26), one background well (MW-1), four downstream surface water locations (SW-4 , SWN-2, SW-C and SW-D), four upstream surface water points (SWN-1, SW-1, SW-2 and SW-3) and a raw leachate sample (LAGOON). Quality control (QC) measures included analysis of equipment blanks (EB) and field blanks (FB). MW-10 was re -sampled and tested for VOCs on March 6, 2020 since the original sample contained elevated benzene concentrations. Sampling locations are shown on the potentiometric map (Sheet 2). A summary detailing the construction of the water monitoring wells is presented on Table 1. The function and integrity of all monitoring locations were visually evaluated as documented on Table 2. The depth to water in each well was electronically gaged prior to purging to quantify the static water level elevation. Submersible pumping methodology or bailing was utilized to purge the wells to a minimum of three times the volume of standing water in the well or until dry. Surface water samples were collected from Stoney Creek discharge feature at previously designated locations. During well purging and surface water sample collection the required field parameters were recorded. The samples were then placed into laboratory -prepared, pre -preserved containers via a new disposable polyethylene bailer. Samples were collected, kept on ice, and transported to a NC -certified laboratory under proper C-O-C protocols within the specified hold times for each analysis. Field Parameter Data Stabilized field parameters were recorded during purging which included pH, specific conductance, temperature, methane gas and turbidity. A summary of the field parameter data is presented in Table 3 and the field sampling data sheet is enclosed in Appendix A. Laboratory Results Pace Analytical Services, Inc. (PACE) performed the laboratory analysis of the water and leachate samples. Pace reported that their procedures conformed to the most current, applicable TNI/NELAC standards and the their Quality Assurance Manual, where applicable, unless otherwise noted in the body of the laboratory report. Groundwater samples MW-2, MW-6R and MW-9S were tested for constituents listed in 40 CFR 258 Appendix II and 1,4-dioxane. The other groundwater and surface water samples were tested for constituents listed in 40 CFR 258 Appendix I and 1,4-dioxane. Untreated leachate was tested for the specific parameters required by the SWS which includes Appendix I constituents, phosphorous, BOD, COD, sulfide and nitrate. A sampling and analysis table summarizing the locations, constituents and methods is presented as Table 4. Laboratory results and C-O-Cs are presented in Appendix B. Water samples were analyzed to the laboratory -established Method Detection Limits (MDL) and any value between the MDL and laboratory -established Reporting Limit (RL) is qualified by the laboratory as an estimated concentration hence qualified with a "J". Estimated concentrations are considered non -quantifiable and discretion should be made prior to making decisions based solely on an approximate value. Table 5 summarizes constituents detected in groundwater, leachate and quality control samples compared to regulatory groundwater compliance standards which include Interim Maximum Allowable Concentrations (IMAC), Site Maximum Allowable Concentrations (SMAC) and North Carolina Groundwater Standards (2L). Although not applicable for regulatory compliance purposes the detections are also compared to the Maximum Contaminant Level (MCL) commonly referenced as the Federal "Drinking Water Standard". Table 6 lists the constituents detected in surface water samples compared to the current version of the Division of Water Quality Surface Water Quality Tables and the MCL. Quality Control Samples Total cadmium was detected in the EB sample. Arsenic was detected in the laboratory quality control blanks associated with samples WSW-2 and the lagoon, therefore they were flagged by the laboratory 2 Groundwater Sample Exceedances Metals Four total recoverable forms of metals were detected above the NC 2L/IMAC/SMAC in samples collected from three wells as summarized below. Metals Detected Above Groundwater Standards Antimonv Cadmium Cobalt Thallium 2L/IMAC/SMAC 1 8 0.3 0.28 MW-9S 9.3 76.7 0.29 MW-11D 6.2 Concentrations in ug/L. Volatile Organic Compounds VOCs, vinyl chloride 2.1 ug/L (2L=0.3 ug/L) and benzene 2.2 ug/L / (2L=1.0 ug/L), were detected in sample MW- 6R above their respective NC 2L Standard. Surface Water Samples Detected Above Standards Contaminants were not detected above established NC 2B Surface Water Standards in any of the surface water samples. Leachate Samples Raw leachate samples contained concentrations of arsenic 14.4 ug/L (2L=10), cobalt 19.4 (SMAC=11) and 1,2- dichloroethane 1.1 (2L=0.4). Contaminant concentrations in leachate remain low relative to Standards applicable to ground and surface waters and values published from similar MSWLF's which is consistent with previous observations. Groundwater and Surface Water Characterization A potentiometric map of the uppermost aquifer constructed from groundwater elevation data recorded during this monitoring event is on Sheet 2. Groundwater flow rates and directions were calculated and are included in the hydrologic properties table (Table 7). Groundwater flow directions remain generally in a southerly direction towards the Ararat River with groundwater velocities calculated by modified Darcy's equation varied considerably due to the anisotropic geologic conditions. Streams located within the facility boundaries were observed to be of moderate volume and flow with low turbidity. MW-6R Area Investigations During this event MESCO investigated the area around MW-6R in an attempt to identify the source of VOC detections. MW-6R is located in a ditch that previously conveyed stormwater originating from the lined landfill. During the construction of Phased 2 in 2009, stormwater originating near the landfill was rerouted so that it no longer flows adjacent to MW-6R. Methane (3.2%/vol.) was detected in shallow migration monitoring probe MGP- 5, located less than 75 feet from MW-6R on May 12, 2020 (Figure 1). Active LFG extraction has been initiated at Lined Phase 1 which includes vacuum applied at the closest leachate collection system cleanout. Vinyl chloride was detected in sample MW-6R during this and the previous 13 events above the 2L Standard and benzene levels were found above the 2L Standard for the third time. There were no elevated levels of contaminants detected in groundwater sample MW-8 or surface water samples (SWN-2, SW-D) collected hydraulically downgradient of MW- 6R. K Findings Groundwater near MW-6R continues to be impacted with levels remaining within their historically identified range. MW-6R is located approximately 100 feet downgradient of the Phase 2 liner and within the compliance boundary. The portion of the aquifer impacted is believed to be small as evidenced by lack of detections in MW-8 located along the downgradient flow path. The active LFG extraction system has been expanded proximal to MW-6R and is expected to operate indefinitely which may mitigate potential groundwater impacts. Interpretation of results of surface water samples collected along Stoney Creek and the Ararat River, including those instituted directly downgradient of MW-6R, continue to indicate the local discharge features remain unimpaired. MW-9S continues to be impacted with metals detected above allowable Standards. Total cadmium was found outside of it's historically identified range. The metals are likely a product from dissolution from the soil in response to changes in the geochemistry from a past release. Constituents listed on Appendix II that are not also found on Appendix I were not detected during this event. The detection of arsenic in the water supply well (WSW-2) may be a false positive or high bias since it was also detected in the associated lab blank. Results of future analysis should determine the validity of the arsenic detection. Closing Water quality and LFG monitoring was performed again in December 2020. Phase four has yet to begin receiving waste as of this report date, therefore water quality data from MW-24 through MW-28 should be considered background. 4 Sheets Topographic Map with Site Location Surry County Landfill, Mt. Airy fl 237 Landfill Road Mount Airy, NC 28621 Lat: 36-26-30.065 Long:-80-34-15.314 Northing:983356.18 Easting:1537885.48 0 Surry Co Property Line O Closed Unlined C&D Landfill O Closed Unlined Sanitary Landfill O Active Lined MSW Landfill SHEET 1 OWNED BY SURRY COUNTY `9s0 NOW OR FORMERLY OWNED BY JOHNNY COX — /000 os MW--28 GWE=1013.09 MWL-A LINED > E 1 1ooU / O '/1 /98 STONEY CREEK 1�2p q5o 101� g9� �110o w SW-4 LFG 9g0 1050 7ION o � o o ' \ Vp,GOON j / \/ -MW--4S GWE=935.39 v - v MW--2 �O MW-4D*--_ - M� - GWE=923.3295 GWE=935.93 ` S o*7 M-MW-3R L /, , , SW-C GWE=925.54 0 �- G WE=934.88 i MGP-5 i o50 MW-6R GWE=939.61 MW-8 ` Vinyl Chloride- u 30'MGP-12 M; GWE=911.32 Benzene- 1.7 ug/L i SWN-2 V-9D* MW--9S— E=917.76 GWE=922.38 1o� P-4 - 9 SOV7H � ERN RgI�ROq p _- 1 SW-D RA `Rj 7.RI DER ` ft_�% OWNED BY SURRY 00000 ` COUNTY = I I SW-2 (1000' FURTHER UPSTREAM) Soso O O� CLOSED C&D OVER CLOSED MSW STOPPED RECEIVING C&D BEFORE JUNE 1, 2008 STOPPED RECEIVING MSW BY JAN. 1, 1999 PROPERTY LINE NOW OR FORMERLY OWNED BY SHAWNA SUMMERS LEGEND ESTIMATED WASTE LIMITS UNLINED LANDFILL WASTE LIMITS OF LINED LANDFILL FACILITY OUTERMOST PROPERTY BOUNDARY TOPOGRAPHIC CONTOURS -EXISTING RELATIVE GROUNDWATER COMPLIANCE BOUNDARY RAILROAD o� OBSERVATION WELL nn� MONITORING WELL LANDFILL GAS MONITORING WELL ROADS STREAM/CREEK As, SURFACE WATER SAMPLING LOCATION 960 EQUIPOTENTIAL UPPERMOST GROUNDWATER CONTOURS (JUNE 22-25, 2020) GWE = 941.66 GROUNDWATER POTENTIOMETRIC ELEVATION *MW- POTENTIOMETRIC ELEVATION NOT USED FOR CONTOURING GRAPHIC SCALE 200 0 100 200 400 800 ( IN FEET ) SHEET 2 L9Q r, Z0. � N l0 L` 0� N �0 W �N W > N 00 Z zZ °W� 2 CL o 00 f n a m = CL N 1�1 z � N `n . 0 U w w 0 N V002 0m Z N U 71 Z J �W Z Z Z Q Q Lrj W Z ° W U CL W wm ° J U � Zm � a/ 2 3 [r] X m W _ . Ln rn co a J 0 � Z J Q 0 >ft � Lu W Q V 0o Q� L O �• J � Z J O ca cr) Z) J Q cl) Q �— C z CL O Q O � N � z a w Lu �. 0oc W z � CL C) Q o � Lu J CL zCL m � � O L O SCALE: SEE SCALE BAR DATE: 4110120 DRWN. BY: J. PFOHL CHKD. BY: J. PFOHL PROJECT NUMBER G 19025.0 DRAWING NO. SHEET NO. SHEET 2 1 OF 1 Figures Figure 1 Landfill Gas Migration Monitoring Data February 4, 2020 NC Division of Waste Management — Solid Waste Section Landfill Gas Monitoring Data Form Notice:This form and any information attached to it are 'Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Facility Name: Surry County Landfill Ph 1-4 Permit Number: 86-06 Date of Sampling: 05/12/20 NC Landfill Rule (.0500 or .1600): 0.1600 Name & Position of Sample Collector: Evan Lambert (Env. Specialist 1) Factory Type & Serial Number of Gas Meter: Envision (1901205B) Calibration Date of Gas Meter: 01/15/19 Date & Time of Field Calibration: 05/11/20 01:00 PM Type of Field Calibration Gas (15/15 or 35/50): 15/15 Expiration Date of Field Calibration Gas Canister: 12/20/22 Pump Rate of Gas Meter: 240 cc/min Ambient Air Temperature: 55 F Barometric Pressure: 29.15" Hg General Weather Conditions: Clear Instructions: Under "Location or LFG Well" identify the monitoring wells or describe the location for other tests (e.g., inside buildings). A drawing showing the location of test must be attached. Report methane readings in both %LEL and % methane by volume. A reading in percent methane by volume can be converted to %LEL as follows: % methane by volume = %LEL/20 Sample Location Tube Time Time Initial Stabilized Stabilized or LFG Purge Reading Pumped in Ch4 Ch4 Ch4 02 CO2 1-112S Well ID (Sec) Taken (Sec.) (% LEL) (% LEL) (%/Vol) (%/Vol) (%/Vol) (ppm) Notes MGP-5 30 05:21 PM 60 64 64 3.2 5.7 13.6 0 MGP-12 1 30 05:27 PM 60 0 0 0.0 14.9 4.9 1 0 These readings are supplemental for groundwater corrective action monitoring not for migration compliance purposes. NOTES/COMMENTS: Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. �_cnsc- � SIGNATURE Environmental Specialist I (MESCO) TITLE Surry County Lined Landfill Page 1 of 1 Tables Table 1 Groundwater Monitoring Well Construction Table June 22-25, 2020 Monitoring Well Date Installed Well Diameter Total Well Depth Top of Screen Depth Screen Length Geology of Screened Interval Top of casing Elevation Ground Elevation Groundwater Elevation Depth to Water Latitude Longitude (inches) (ft bgs) (ft bgs) (ft) (ft amsl) (ft amsl) (ft amsl) (ft btoc) MW-1 8/14/98 2 68.5 53.5 15 Rock 1127.02 1124.23 1062.54 64.48 36.434494 -80.577989 MW-2 8/16/98 2 23.5 8.5 15 Rock 936.68 933.91 923.32 13.36 36.430833 -80.571161 MW-3R 12/2/98 2 20 5 15 Rock 930.00 928.15 925.54 4.46 36.430714 -80.571575 MW-4S 8/11/98 2 20 5 15 Saprolite 943.23 940.31 935.39 7.84 36.430853 -80.572400 MW-4D 8/11/98 2 45 35 10 Rock 942.80 940.31 935.93 6.87 36.430853 -80.572400 MW-5 8/18/98 2 47.5 32.5 15 Rock 977.93 971.57 934.88 43.05 36.430356 -80.572961 MW-6R 3/22/99 2 79 64 15 Fractured Rock 1004.75 1001.81 939.61 65.14 36.429958 -80.573508 MW-8 9/1/09 2 70.75 55.75 15 Fractured Rock 971.03 968.35 911.32 59.71 36.429283 -80.573453 MW-9S 6/16/06 2 42.28 27.28 15 Fractured Rock 952.83 949.75 922.28 30.55 36.429314 -80.574464 MW-9D 6/16/06 2 65.54 55.54 10 Competent Rock 952.47 949.49 919.30 33.17 36.429314 -80.574464 MW-10 6/16/06 2 47.13 27.13 20 Fractured Rock 970.24 967.35 942.79 27.45 36.429519 -80.575486 MW-11S 9/3/09 2 46.05 31.05 15 Competent Rock 969.09 965.95 939.26 29.83 36.430197 -80.577131 MW-11D 9/3/09 2 65.31 55.31 10 Competent Rock 965.38 962.38 933.15 32.23 36.430197 -80.577131 MW-12 9/4/09 2 65 50 15 Competent Rock 996.66 993.71 945.41 51.25 36.429831 -80.576750 MW-13 9/3/09 2 36.31 21.31 15 Fractured Rock 983.13 979.83 947.66 35.47 36.430625 -80.578531 MW-24 1/27/15 2 38.78 28.78 10 Competent Rock 979.72 976.72 941.44 38.28 36.430707 -80.579134 MW-25 1/24/15 2 71 56 15 Competent Rock 989.85 986.85 967.45 22.40 36.431058 -80.579869 MW-26 1/25/15 2 45.26 30.26 15 Competent Rock 999.04 996.04 971.59 27.45 36.431476 -80.580518 MW-27 1/22/15 2 53.07 38.07 15 Competent Rock 1043.01 1040.01 1010.55 32.46 36.432314 -80.580081 MW-28 1/28/15 2 80.48 65.48 15 Competent Rock 1077.41 1074.41 1013.09 64.32 36.433712 -80.575106 MLW-A 8/19/98 2 84 69 15 Competent Rock 1095.51 1092.51 #VALUE! NR 36.432881 -80.573539 P2-11S 6/16/06 2 50.13 40.13 10 Competent Rock 1021.53 1018.40 #VALUE! NR 36.430197 -80.577131 P2-11D 6/16/06 2 65.45 60.45 5 Competent Rock 1021.13 1018.73 #VALUE! NR 36.430197 -80.577131 132-12 6/16/06 2 59.56 44.56 15 Competent Rock 986.61 983.54 #VALUE! NR 36.429831 -80.576750 NOTE: bgs = below ground surface amsl= above mean sea level btoc = below top of casing (PVC well casing) Slurry County Lined Landfill Page 1 of 1 Table 2 Field Observations of Monitoring Locations June 22-25, 2020 Sample Location Viable Monitoring Location Lack of Any Evidence of Tampering Locked on Arrival & Departure Hinge/Hasp Operational Tagged or Labeled Concrete Surface Pad Appears Effective Comments MW-1 Yes Yes Yes Yes Yes Yes Background Well MW-2 Yes Yes Yes Yes Yes Yes MW-3R Yes Yes Yes Yes Yes Yes MW-4S Yes Yes Yes Yes Yes Yes MW-4D Yes Yes Yes Yes Yes Yes MW-5 Yes Yes Yes Yes Yes Yes MW-6R Yes Yes Yes Yes Yes Yes County improved surface seal in September 2013 MW-8 Yes Yes Yes Yes Yes Yes Path to well recently cleared by County MW-9S Yes Yes Yes Yes Yes Yes MW-9D Yes Yes Yes Yes Yes Yes MW-10 Yes Yes Yes Yes Yes Yes Foul odor in purge water MW-11S Yes Yes Yes Yes Yes Yes MW-11 D Yes Yes Yes Yes Yes Yes Slightly turbid purge water MW-12 Yes Yes Yes Yes Yes Yes MW-13 Yes Yes Yes Yes Yes ? Bumped by JR Lynch (Contractor). Well needs repaired MW-24 Yes Yes Yes Yes Yes Yes MW-25 Yes Yes Yes Yes Yes Yes MW-26 Yes Yes Yes Yes Yes Yes MW-27 Yes Yes Yes Yes Yes Yes MW-28 Yes Yes Yes Yes Yes Yes SW-1 Yes High gage height & flow SW-2 Yes High gage height & flow SW-3 Yes High gage height & flow SWN-1 Yes High gage height & flow SWN-2 Yes High gage height & flow SW-C Yes High gage height & flow SW-D Yes High gage height & flow LAGOON Yes Yes Yes Sample from invert which is typical Any unusual field conditions, observations, or events: Phase 2 has an earthen berm built Win liner limits which may reduce any potential for overland flow from Phase 2. Paths leading to wells and around entire facility have been maintained by County. All are 4X4 accessible. Co performed well maintenance by pouring new concrete pads around several wells in the Fall of 2017. Slurry County Lined Landfill Page 1 of 1 Table 3 Hydrogeologic Properties at Monitoring Locations June 22-25, 2020 Parameter Depth to Water Water Elevation TOC Elevation Temp. pH Specific Conductance ORP DO Hardness Methane Gas in Headspace Turbidity of Metal Sample Units ft (btoc) ft (amsl) ft (amsl) C SU umhos/cm mV mg/L mg/L (%/Vol) (NTU) MW-1 64.48 1062.54 1127.02 15.4 5.92 61 NR NR NR NR 6.12 MW-2 13.36 923.32 936.68 14.7 6.19 73 NR NR NR NR 4.19 MW-3R 4.46 925.54 930.00 14.7 6.28 271 NR NR NR NR 2.00 MW-4S 7.84 935.39 943.23 15.4 5.44 88 NR NR NR NR 0.85 MW-4D 6.87 935.93 942.80 15.3 5.32 111 NR NR NR NR 0.79 MW-5 43.05 934.88 977.93 14.1 5.29 99 NR NR NR NR 3.52 MW-6R 65.14 939.61 1004.75 15.2 5.22 165 NR NR NR NR 2.23 MW-8 59.71 911.32 971.03 14.8 5.81 210 NR NR NR NR 0.84 MW-9S 30.55 922.28 952.83 19.6 5.72 158 NR NR NR NR 2.31 MW-9D 33.17 919.30 952.47 14.6 6.50 206 NR NR NR NR 15.3 MW-10 27.45 942.79 970.24 15.3 5.78 138 NR NR NR NR 11.9 MW-11S 29.83 939.26 969.09 14.8 5.89 312 NR NR NR NR 0.49 MW-11D 32.23 933.15 965.38 14.7 6.65 48 NR NR NR NR 82.3 MW-12 51.25 945.41 996.66 14.6 6.32 206 NR NR NR NR 2.94 MW-13 35.47 947.66 983.13 15.7 5.31 76 NR NR NR NR 15.9 MLW-A NR NR 1095.51 NR NR NR NR NR NR NR NR MW-24 38.28 941.44 979.72 15.1 6.61 74 NR NR NR NR 7.06 MW-25 22.40 967.45 989.85 15.6 7.46 159 NR NR NR NR 1.56 MW-26 27.45 971.59 999.04 14.0 5.39 33 NR NR NR NR 4.04 MW-27 32.46 1010.55 1043.01 14.2 5.85 113 NR NR NR NR 21.2 MW-28 64.32 1013.09 1077.41 16.1 6.06 97 NR NR NR NR 7.77 Minimum 4.46 911.32 930.00 14.0 5.22 33 NR NR NR NR 0.49 Average 34.49 951.12 990.85 15.2 5.95 135 NR NR NR NR 9.67 Maximum 65.14 1062.54 1127.02 19.6 7.46 312 NR NR NR NR 82.3 SW-1 - - - 17.1 6.51 58 NR NR 20 - 9.86 SW-2 19.1 6.52 83 NR NR 20 - 9.20 SW-3 18.1 6.81 332 NR NR 20 - 37.9 SW-4 18.3 6.82 63 NR NR 30 - 9.55 SWN-1 17.2 7.73 121 NR NR 20 - 6.52 SWN-2 17.9 7.81 132 NR NR 20 - 8.25 SW-C 17.8 7.01 119 NR NR 20 - 10.0 SW-D 18.3 7.29 136 NR NR 40 - 1 9.07 Minimum 17.1 6.51 58 NR NR 20 NR 6.52 Average 18.0 7.06 131 NR NR 24 NR 12.5 Maximum 19.1 7.81 332 NR NR 40 NR 37.9 NR = No reading attempted btoc = Below top of casing amsl = Above mean sea level Slurry County Lined Landfill Page 1 of 1 Table 4 Sampling and Analysis Summary June 22-25, 2020 �.. �..Field Parameter • • ■ Appendix I & I I = Lists from current 40 CFR 258 Surry County Lined Landfill Page 1 of 1 Table 5 Groundwater, Leachate and Quality Control Sample Detections June 23-25, 2020 Parameter Name MDL RL 2L Standard MCL MW-2 MW-3R MW-4D MW-4S MW-5 MW-6R MW-6 MW-9S MW-9D MW-10 MWA1S MW-11D MWA2 MWA3 WSW-2 LAGOON EB FB IMAC Value* SMAC Value** %II BG S S S S S S S S S S S S S S WSW Leachate QC QC Metals (Targeted 40CFR 258 Appendix I Antimony, total 3 5 1 6 6.2 (N) Arsenic, total 4.7 10 10 10 5.7 J 8.6 J 7.3 J 14.4 BC Barium, total 3.5 5 700 2000 17.3 38.6 7.6 45.6 41.1 63.5 78.6 67.2 99.2 49.4 37 21.4 48.3 14.4 36.4 242 Cadmium, total 0.4 1 8** 5 1.1 0.63 J 1.9 9.3 (N) 1.5 1.3 1.9 0.47 J Copper, total 4.3 5 1000 1300 7.4 Cobalt, total 3.6 5 11** NE 76.7 19.4 Nickel, total 3.5 5 100 NE 3.7 J 7.4 8.5 Thallium, total 0.05 0.1 0.28 2 0.069 J 0.11 0.098 J 0.29 (N) 0.15 Vanadium, total 3.9 5 27** NE 4.2 J Zinc, total 9.5 10 1000 NE 9.7J 11 21.8 VOCs (Targeted 40CFR 258 Appendix I and 1,4-Dioxane) 1,1-Dichloroethane 0.27 1 6 NE 1.9 1,2-Dichloroethane 0.34 1 0.4 5 1.1 1,4-Dichlorobenzene 0.26 1 6 75 3.5 2-Butanone (MEK) 3.3 5 4000 NE 38.5 Benzene 0.15 1 1 5 0.57 J 2.2 (L) 0.4 J 0.44 J 0.62 J 0.38 J Bromomethane 0.62 2 10 NE 0.9 J Chlorobenzene 0.23 1 50 100 0.43 J cis-1,2-Dichloroethene 0.29 1 70 70 1.5 0.6 J 2.3 10.3 2.5 0.61 J 0.95 J 0.63 J 0.9 J Ethylbenzene 1 0.26 1 1 1 600 1 700 1 1 1 1 1 1 1 0.82J Tetrachloroethene 0.16 1 0.7 5 0.551 Toluene 0.24 1 600 1000 2 trans-1,2-Dichloroethene 0.25 1 100 100 0.64 J 3.1 0.7 J 0.6 J Vinyl chloride 0.24 1 0.03 2 2.1 (L) 0.59 J Xylene (Total) 0.63 1 500 10000 1.7 Leachate Parameters BOD, 5 day 2000 2000 NE NE - -- -- -- -- -- -- -- -- -- - -- - - - - 6240 - -- Nitrate 5 40 NE NE - -- -- -- -- -- -- -- - -- - -- - - - - 12.9 J - -- COD 12500 25000 NE NE - -- -- -- -- -- -- -- - -- - -- - - - - 164000 - -- pH 0.01 0.1 NE NE - -- -- -- -- -- -- -- - 6.6 - Phosphorus 5 50 NE NE - -- -- -- -- -- -- -- - -- - -- - - - - 86 - -- Sulfate 500 1000 250000 NE - -- -- -- -- -- - -- - -- - -- - - - - 4230 - -- Turbidity (Field Measured) (NTU) Turbidity NTU 0.01 NE NE 6.12 4.19 2 0.79 0.85 1 3.52 2.23 0.84 2.31 15.3 1 11.9 1 0.49 1 82.3 1 2.94 15.9 Notes: Units ug/L unless shown otherwise, Blank cells means not detected above MDL, -- means parameter not analyzed, NE means not established. Bold Above RL and Established 2L/IMAC Std. (Regulatory compliance Standard) Above Established Federal MCL Drinking Water Std. (NOT a regulatory compliance Standard) BG= Background Well Sample, QC = Quality Control Sample, S = Sentinel Well Sample MDL = Adjusted Method Detection Limit established by the laboratory via a statistical calculation. Since the MDL is below the point of calibration, results reported down to the MDL are not reliable and must be qualified as estimated values and, as such, carry a "J" qualifier designation. RL = Reporting Limit defined by Pace laboratory as "The lowest concentration value that meats project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix." 21JIMAC/SMAC = NC 2L, IMAC and SMAC values recognized by the NC SWS as regulatory groundater Standards. 2L = NC 2L Groundater Standard 15A NCAC 02L .0202 IMAC = Interim Maximum Allowable Concentration SMAC = Site Maximum Allwable Concentration. Approved by NC SWS via ASO April 1, 2020. MCL = Primary Maximum Contaminant Level for drinking water established by the USEPA. J = "J-qualified". Defined by the lab as "estimated concentration above the adjusted method detection limit and below the adjusted reporting limit". BC = The same analyte was detected in an associated blank at a concentration above 1/2 the reporting limit but below the laboratory reporting limit. (N) Preliminary source is believed to be Natural originating from erosion of natural deposits. Source not anthropogenic. (L) Prelilminary source is believed to be anthropogenic with Landfill Gas Wor leachate as suspected transport mechanism. A definitive source of the detections was not determined as part of this report. Surry County Lined Landfill Page 1 of 1 Table 6 Surface Water Sample Detections June 25, 2020 Parameter Name MDL RL NC 213 STD' EPA NRWQCZI NC ISTV3 MCL" SWN-1 SW-4 SW-C SW-D SWN-2 Up IDown DownlDown Down Targeted 40CFR 258 Appendix I and 1,4-Dioxane Arsenic, total 4.7 10 340 NE NE 1 10 1 6.1 J 1 17.3 J BC Barium, total 3.5 5 NE NE 21,000 1 2000 17.7 18 17.8 18.8 17.5 Hardness as CaCo3 (Field Measured) Hardness (mg/L) 20 20 NE I NE NE NE 20 30 40 40 20 Turbidity (Field Measured) Turbidity (NTU) 0.01 50 NE NE 6.52 6.52 10.0 9.07 8.25 Notes: Units ug/L unless indicated otherwise, Blank cells means Not Detected, NE means Standard Not Established J = "J-qualified". Defined by the lab as "Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit". BC = The same analyte was detected in an associated blank at a concentration above 1/2 the reporting limit but below the laboratory reporting limit. Red Bold Above RL and Applicable Established 26 Sid. Above Established Federal MCL Primary Drinking Water Std. MDL = Adjusted Method Detection Limit established by the laboratory via a statistical calculation. Since the MDL is below the point of calibration, results reported down to the MDL are not reliable and must be qualified as estimated values and, as such, carry a "J" qualifier designation. quantitative data with known precision and bias for a specific analyte in a specific matrix." Receivina surface waters are Stonev Creek (12-72-12) and Ararat River (12-7244.5) Both Class C. 03040101 (8-Diait HUC). 1 NC 2B STD = North Carolina 15A NCAC 02B Water Quality Standards for Surface Waters. Presumed NC SWS adopted the numerical Standard for regulatory compliance purposes 2B Standards from All Waters (C & SC) or Class C. `EPA NRWQC = EPA Nationally Recommended Water Quality Criteria for Aquatic Life & Human Health. Nationally Recommended Water Quality Criteria for which NC does not have a Water Quality Standard for one or more uses NC ISTV= North Carolina In -Stream Target Value. Established per language in 15A NCAC 02B .0202 & .0208. Contact DWR staff for further information. NC ISTV for barium and cobalt fresh water All waters (Class C) " MCL= Maximum Contaminant Level. Federal Primary "Drinking Water Standard". Shown for comparison purposes only. Not applicable for regulatory compliance purposes. Surry County Lined Landfill Page 1 of 1 Table 7 Hydrogeologic Prpoperties at Monitoring Locations June 22-25, 2020 Monitoring Location Hydraulic Conductivity (cm/sec) Effective porosity Hydraulic Gradient Flow Rate Flow Direction Depth to Groundwater Groundwater Potentiometric Elevation Screened Interval Lithology (cm/second) N (feet/feet) (feet/year) (feet btoc) (feet amsl) MW-1 2.45E-04 3 0.122 1,028 N51E 64.48 1062.54 Rock MW-2 3.20E-04 3 0.103 1,139 S09E 13.36 923.32 Rock MW-3R 3.20E-04 3 0.056 615 S18E 4.46 925.54 Rock MW-4S 1.50E-04 3 0.111 576 S21 E 7.84 935.39 Sandy Silt & Fractured Rock MW-4D 1.59E-04 3 - - 6.87 935.93 Rock MW-5 3.20E-04 3 0.110 1,213 S49E 43.70 934.88 Rock MW-6R 3.20E-04 3 0.080 883 S30E 65.14 939.61 Fractured Rock MW-8 1.08E-03 3 0.103 3,840 S03E 59.71 911.32 Fractured Rock MW-9S 7.45E-04 3 0.088 2,254 S23E 30.55 922.28 Fractured Rock MW-9D 1.07E-05 3 - - 33.17 919.30 Competent Rock MW-10 1.43E-04 3 0.114 560 S01 E 27.45 942.79 Fractured Rock MW-11S 6.19E-05 3 0.110 235 S15W 29.83 939.26 Competent Rock MW-11 D na 3 - - - 37.35 933.15 Competent Rock MW-12 1.91 E-06 3 na na na 51.25 945.41 Competent Rock MW-13 2.71E-03 3 0.122 11,398 S35W 35.47 947.66 Fractured Rock MW-24 7.81 E-03 3 0.167 44,892 S03W 38.28 941.44 Competent Rock MW-25 2.99E-06 3 0.147 15 S22W 22.40 967.45 Competent Rock MW-26 3.85E-02 3 0.164 217,671 S40W 27.45 971.59 Competent Rock MW-27 6.67E-06 3 0.088 20.357 S65W 32.46 1010.55 Competent Rock MW-28 1.45E-04 3 0.108 538 N20E 64.32 1013.09 Competent Rock Minimum 1.91 E-06 3 0.056 15 - 4.46 911.32 Average 2.79E-03 3 0.112 17,930 34.78 951.12 Maximum 3.85E-02 3 0.167 217,671 - 65.14 1062.54 NOTE: Hydraulic conductivity and effective porosity values derived from slug tests performed by MESCO. Hydrologic gradient from water levels recorded on June 22-25, 2020. Flow rate for MW-13 was considered an outlier; therefore not included in the average or maximum. Flow rate (Q) is defined by modified Darcy's equation: where K _ K A ,ity dl n e dl dl = horizontal distance Slurry County Lined MSWLF Page 1 of 1 Appendix A Laboratory Analysis Reports Chains of Custody lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 July 06, 2020 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on June 26, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Steven R. Gandy, Municipal Engineering Services Co. REPORT OF LABORATORY ANALYSIS r e This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 43 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 43 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 Lab ID Sample ID Matrix Date Collected Date Received 92483790001 SW-D Water 06/25/20 09:05 06/26/20 08:30 92483790002 LAGOON Water 06/25/20 11:30 06/26/20 08:30 92483790003 MW-2 Water 06/25/20 08:51 06/26/20 08:30 92483790004 MW-6R Water 06/25/20 08:58 06/26/20 08:30 92483790005 MW-9S Water 06/25/20 16:06 06/26/20 08:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 43 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92483790001 SW-D EPA 601 OD KQ 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92483790002 LAGOON EPA 601 OD KQ 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C SM 521OB-2011 JP1 1 PASI-A EPA 9040C SMK 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 CJL 1 PASI-A EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A SM 5220D-2011 LMS1 1 PASI-A 92483790003 MW-2 EPA 601OD RDT, SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92483790004 MW-6R EPA 601OD RDT, SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D SAS 51 PASI-C 92483790005 MW-9S EPA 601OD RDT, SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D SAS 51 PASI-C PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 43 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 Sample: SW-D Lab ID: 92483790001 Collected: 06/25/20 09:05 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 06/27/20 00:47 06/30/20 04:17 7440-36-0 Arsenic 7.3J ug/L 10.0 4.7 1 06/27/20 00:47 06/30/20 04:17 7440-38-2 BC Barium 18.8 ug/L 5.0 3.5 1 06/27/20 00:47 06/30/20 04:17 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 06/27/20 00:47 06/30/20 04:17 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 06/27/20 00:47 06/30/20 04:17 7440-43-9 Chromium ND ug/L 5.0 3.7 1 06/27/20 00:47 06/30/20 04:17 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 06/27/20 00:47 06/30/20 04:17 7440-48-4 Copper ND ug/L 5.0 4.3 1 06/27/20 00:47 06/30/20 04:17 7440-50-8 Lead ND ug/L 5.0 4.5 1 06/27/20 00:47 06/30/20 04:17 7439-92-1 Nickel ND ug/L 5.0 3.5 1 06/27/20 00:47 06/30/20 04:17 7440-02-0 Selenium ND ug/L 10.0 4.7 1 06/27/20 00:47 06/30/20 04:17 7782-49-2 Silver ND ug/L 5.0 2.5 1 06/27/20 00:47 06/30/20 04:17 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 06/27/20 00:47 06/30/20 04:17 7440-62-2 Zinc ND ug/L 10.0 9.5 1 06/27/20 00:47 06/30/20 04:17 7440-66-6 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene Date: 07/06/2020 04:17 PM Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville ND ug/L 0.10 0.050 1 06/27/20 00:13 06/29/20 05:14 7440-28-0 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 6.2 1 07/02/20 09:02 67-64-1 ND ug/L 10.0 0.90 1 07/02/20 09:02 107-13-1 ND ug/L 1.0 0.15 1 07/02/20 09:02 71-43-2 ND ug/L 1.0 0.34 1 07/02/20 09:02 74-97-5 ND ug/L 1.0 0.26 1 07/02/20 09:02 75-27-4 ND ug/L 1.0 0.62 1 07/02/20 09:02 75-25-2 ND ug/L 2.0 0.62 1 07/02/20 09:02 74-83-9 IK ND ug/L 5.0 3.3 1 07/02/20 09:02 78-93-3 ND ug/L 2.0 0.40 1 07/02/20 09:02 75-15-0 ND ug/L 1.0 0.22 1 07/02/20 09:02 56-23-5 ND ug/L 1.0 0.23 1 07/02/20 09:02 108-90-7 ND ug/L 1.0 0.49 1 07/02/20 09:02 75-00-3 ND ug/L 5.0 2.3 1 07/02/20 09:02 67-66-3 ND ug/L 1.0 0.39 1 07/02/20 09:02 74-87-3 v2 ND ug/L 5.0 0.26 1 07/02/20 09:02 96-12-8 ND ug/L 1.0 0.41 1 07/02/20 09:02 124-48-1 ND ug/L 1.0 0.26 1 07/02/20 09:02 106-93-4 ND ug/L 1.0 0.46 1 07/02/20 09:02 74-95-3 ND ug/L 1.0 0.29 1 07/02/20 09:02 95-50-1 ND ug/L 1.0 0.26 1 07/02/20 09:02 106-46-7 ND ug/L 1.0 0.54 1 07/02/20 09:02 110-57-6 ND ug/L 1.0 0.27 1 07/02/20 09:02 75-34-3 ND ug/L 1.0 0.34 1 07/02/20 09:02 107-06-2 ND ug/L 1.0 0.24 1 07/02/20 09:02 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 43 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 Sample: SW-D Lab ID: 92483790001 Collected: 06/25/20 09:05 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/06/2020 04:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 07/02/20 09:02 156-59-2 ND ug/L 1.0 0.25 1 07/02/20 09:02 156-60-5 ND ug/L 1.0 0.19 1 07/02/20 09:02 78-87-5 ND ug/L 1.0 0.30 1 07/02/20 09:02 10061-01-5 ND ug/L 1.0 0.31 1 07/02/20 09:02 10061-02-6 ND ug/L 150 56.2 1 07/02/20 09:02 123-91-1 ND ug/L 1.0 0.26 1 07/02/20 09:02 100-41-4 ND ug/L 5.0 0.57 1 07/02/20 09:02 591-78-6 ND ug/L 20.0 12.5 1 07/02/20 09:02 74-88-4 ND ug/L 5.0 3.7 1 07/02/20 09:02 75-09-2 ND ug/L 5.0 4.5 1 07/02/20 09:02 108-10-1 ND ug/L 1.0 0.27 1 07/02/20 09:02 100-42-5 ND ug/L 1.0 0.34 1 07/02/20 09:02 630-20-6 ND ug/L 1.0 0.22 1 07/02/20 09:02 79-34-5 ND ug/L 1.0 0.16 1 07/02/20 09:02 127-18-4 ND ug/L 1.0 0.24 1 07/02/20 09:02 108-88-3 ND ug/L 1.0 0.18 1 07/02/20 09:02 71-55-6 ND ug/L 1.0 0.24 1 07/02/20 09:02 79-00-5 ND ug/L 1.0 0.22 1 07/02/20 09:02 79-01-6 ND ug/L 1.0 0.31 1 07/02/20 09:02 75-69-4 ND ug/L 1.0 0.35 1 07/02/20 09:02 96-18-4 ND ug/L 2.0 1.4 1 07/02/20 09:02 108-05-4 ND ug/L 1.0 0.24 1 07/02/20 09:02 75-01-4 ND ug/L 1.0 0.63 1 07/02/20 09:02 1330-20-7 93 % 70-130 1 07/02/20 09:02 460-00-4 91 % 70-130 1 07/02/20 09:02 17060-07-0 99 % 70-130 1 07/02/20 09:02 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 43 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 Sample: LAGOON Lab ID: 92483790002 Collected: 06/25/20 11:30 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 06/27/20 00:47 06/30/20 04:20 7440-36-0 Arsenic 14.4 ug/L 10.0 4.7 1 06/27/20 00:47 06/30/20 04:20 7440-38-2 BC Barium 242 ug/L 5.0 3.5 1 06/27/20 00:47 06/30/20 04:20 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 06/27/20 00:47 06/30/20 04:20 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 06/27/20 00:47 06/30/20 04:20 7440-43-9 Chromium ND ug/L 5.0 3.7 1 06/27/20 00:47 06/30/20 04:20 7440-47-3 Cobalt 19.4 ug/L 5.0 3.6 1 06/27/20 00:47 06/30/20 04:20 7440-48-4 Copper ND ug/L 5.0 4.3 1 06/27/20 00:47 06/30/20 04:20 7440-50-8 Lead ND ug/L 5.0 4.5 1 06/27/20 00:47 06/30/20 04:20 7439-92-1 Nickel 8.5 ug/L 5.0 3.5 1 06/27/20 00:47 06/30/20 04:20 7440-02-0 Selenium ND ug/L 10.0 4.7 1 06/27/20 00:47 06/30/20 04:20 7782-49-2 Silver ND ug/L 5.0 2.5 1 06/27/20 00:47 06/30/20 04:20 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 06/27/20 00:47 06/30/20 04:20 7440-62-2 Zinc ND ug/L 10.0 9.5 1 06/27/20 00:47 06/30/20 04:20 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 06/27/20 00:13 06/29/20 05:21 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/02/20 07:31 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/02/20 07:31 107-13-1 Benzene 0.38J ug/L 1.0 0.15 1 07/02/20 07:31 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/02/20 07:31 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/02/20 07:31 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/02/20 07:31 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/02/20 07:31 74-83-9 IK 2-Butanone (MEK) 38.5 ug/L 5.0 3.3 1 07/02/20 07:31 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/02/20 07:31 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/02/20 07:31 56-23-5 Chlorobenzene 0.43J ug/L 1.0 0.23 1 07/02/20 07:31 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/02/20 07:31 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/02/20 07:31 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/02/20 07:31 74-87-3 v2 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/02/20 07:31 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/02/20 07:31 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/02/20 07:31 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/02/20 07:31 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/02/20 07:31 95-50-1 1,4-Dichlorobenzene 3.5 ug/L 1.0 0.26 1 07/02/20 07:31 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/02/20 07:31 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/02/20 07:31 75-34-3 1,2-Dichloroethane 1.1 ug/L 1.0 0.34 1 07/02/20 07:31 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/02/20 07:31 75-35-4 Date: 07/06/2020 04:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 43 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 Sample: LAGOON Lab ID: 92483790002 Collected: 06/25/20 11:30 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 5210B BOD, 5 day BOD, 5 day 9040 pH pH at 25 Degrees C 300.0 IC Anions 28 Days Sulfate 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate Date: 07/06/2020 04:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 0.901 ug/L 1.0 0.60J ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 150 0.82J ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 0.591 ug/L 1.0 1.7 ug/L 1.0 0.29 1 07/02/20 07:31 156-59-2 0.25 1 07/02/20 07:31 156-60-5 0.19 1 07/02/20 07:31 78-87-5 0.30 1 07/02/20 07:31 10061-01-5 0.31 1 07/02/20 07:31 10061-02-6 56.2 1 07/02/20 07:31 123-91-1 0.26 1 07/02/20 07:31 100-41-4 0.57 1 07/02/20 07:31 591-78-6 12.5 1 07/02/20 07:31 74-88-4 3.7 1 07/02/20 07:31 75-09-2 4.5 1 07/02/20 07:31 108-10-1 0.27 1 07/02/20 07:31 100-42-5 0.34 1 07/02/20 07:31 630-20-6 0.22 1 07/02/20 07:31 79-34-5 0.16 1 07/02/20 07:31 127-18-4 0.24 1 07/02/20 07:31 108-88-3 0.18 1 07/02/20 07:31 71-55-6 0.24 1 07/02/20 07:31 79-00-5 0.22 1 07/02/20 07:31 79-01-6 0.31 1 07/02/20 07:31 75-69-4 0.35 1 07/02/20 07:31 96-18-4 1.4 1 07/02/20 07:31 108-05-4 0.24 1 07/02/20 07:31 75-01-4 0.63 1 07/02/20 07:31 1330-20-7 92 % 70-130 90 % 70-130 98 % 70-130 Analytical Method: SM 521OB-2011 Pace Analytical Services -Asheville 6240 ug/L 2000 2000 Analytical Method: EPA 9040C Pace Analytical Services -Asheville 6.6 Std. Units 0.10 0.10 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 4230 ug/L 1000 500 Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville 12.9J ug/L 40.0 10.0 1 07/02/20 07:31 460-00-4 1 07/02/20 07:31 17060-07-0 1 07/02/20 07:31 2037-26-5 iIit R-M ] K1ef/LIYaf �11111 [11110 E, 9 1 07/05/20 13:18 1 06/30/20 14:58 14808-79-8 1 06/26/20 22:46 14797-55-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. B2 H3 Page 8 of 43 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 Sample: LAGOON Lab ID: 92483790002 Collected: 06/25/20 11:30 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 0.086 mg/L 0.050 0.025 1 06/29/2018:42 06/30/2018:11 7723-14-0 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services -Asheville Chemical Oxygen Demand 164000 ug/L 25000 12500 1 07/01/20 19:05 07/02/20 16:37 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 43 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 Sample: MW-2 Lab ID: 92483790003 Collected: 06/25/20 08:51 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 06/27/20 00:47 06/30/20 20:27 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 06/27/20 00:47 06/29/20 12:16 7440-38-2 Barium 38.6 ug/L 5.0 3.5 1 06/27/20 00:47 06/29/20 12:16 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 06/27/20 00:47 06/29/20 12:16 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 06/27/20 00:47 06/29/20 12:16 7440-43-9 Chromium ND ug/L 5.0 3.7 1 06/27/20 00:47 06/29/20 12:16 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 06/27/20 00:47 06/29/20 12:16 7440-48-4 Copper ND ug/L 5.0 4.3 1 06/27/20 00:47 06/29/20 12:16 7440-50-8 Lead ND ug/L 5.0 4.5 1 06/27/20 00:47 06/29/20 12:16 7439-92-1 Nickel ND ug/L 5.0 3.5 1 06/27/20 00:47 06/29/20 12:16 7440-02-0 Selenium ND ug/L 10.0 4.7 1 06/27/20 00:47 06/29/20 12:16 7782-49-2 Silver ND ug/L 5.0 2.5 1 06/27/20 00:47 06/29/20 12:16 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 06/27/20 00:47 06/29/20 12:16 7440-62-2 Zinc ND ug/L 10.0 9.5 1 06/27/20 00:47 06/29/20 12:16 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 06/27/20 00:13 06/29/20 05:36 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/02/20 07:49 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/02/20 07:49 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/02/20 07:49 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/02/20 07:49 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/02/20 07:49 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/02/20 07:49 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/02/20 07:49 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/02/20 07:49 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/02/20 07:49 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/02/20 07:49 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/02/20 07:49 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/02/20 07:49 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/02/20 07:49 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/02/20 07:49 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/02/20 07:49 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/02/20 07:49 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/02/20 07:49 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/02/20 07:49 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/02/20 07:49 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/02/20 07:49 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/02/20 07:49 110-57-6 1,1-Dichloroethane 1.9 ug/L 1.0 0.27 1 07/02/20 07:49 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/02/20 07:49 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/02/20 07:49 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. IK v2 Page 10 of 43 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 Sample: MW-2 Lab ID: 92483790003 Collected: 06/25/20 08:51 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/06/2020 04:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 1.5 ug/L 1.0 0.29 1 07/02/20 07:49 156-59-2 ND ug/L 1.0 0.25 1 07/02/20 07:49 156-60-5 ND ug/L 1.0 0.19 1 07/02/20 07:49 78-87-5 ND ug/L 1.0 0.30 1 07/02/20 07:49 10061-01-5 ND ug/L 1.0 0.31 1 07/02/20 07:49 10061-02-6 ND ug/L 150 56.2 1 07/02/20 07:49 123-91-1 ND ug/L 1.0 0.26 1 07/02/20 07:49 100-41-4 ND ug/L 5.0 0.57 1 07/02/20 07:49 591-78-6 ND ug/L 20.0 12.5 1 07/02/20 07:49 74-88-4 ND ug/L 5.0 3.7 1 07/02/20 07:49 75-09-2 ND ug/L 5.0 4.5 1 07/02/20 07:49 108-10-1 ND ug/L 1.0 0.27 1 07/02/20 07:49 100-42-5 ND ug/L 1.0 0.34 1 07/02/20 07:49 630-20-6 ND ug/L 1.0 0.22 1 07/02/20 07:49 79-34-5 ND ug/L 1.0 0.16 1 07/02/20 07:49 127-18-4 ND ug/L 1.0 0.24 1 07/02/20 07:49 108-88-3 ND ug/L 1.0 0.18 1 07/02/20 07:49 71-55-6 ND ug/L 1.0 0.24 1 07/02/20 07:49 79-00-5 ND ug/L 1.0 0.22 1 07/02/20 07:49 79-01-6 ND ug/L 1.0 0.31 1 07/02/20 07:49 75-69-4 ND ug/L 1.0 0.35 1 07/02/20 07:49 96-18-4 ND ug/L 2.0 1.4 1 07/02/20 07:49 108-05-4 ND ug/L 1.0 0.24 1 07/02/20 07:49 75-01-4 ND ug/L 1.0 0.63 1 07/02/20 07:49 1330-20-7 96 % 70-130 1 07/02/20 07:49 460-00-4 90 % 70-130 1 07/02/20 07:49 17060-07-0 99 % 70-130 1 07/02/20 07:49 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 43 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 Sample: MW-6R Lab ID: 92483790004 Collected: 06/25/20 08:58 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 06/27/20 00:47 06/30/20 20:39 7440-36-0 Arsenic 5.7J ug/L 10.0 4.7 1 06/27/20 00:47 06/29/20 12:36 7440-38-2 Barium 78.6 ug/L 5.0 3.5 1 06/27/20 00:47 06/29/20 12:36 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 06/27/20 00:47 06/29/20 12:36 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 06/27/20 00:47 06/29/20 12:36 7440-43-9 Chromium ND ug/L 5.0 3.7 1 06/27/20 00:47 06/29/20 12:36 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 06/27/20 00:47 06/29/20 12:36 7440-48-4 Copper ND ug/L 5.0 4.3 1 06/27/20 00:47 06/29/20 12:36 7440-50-8 Lead ND ug/L 5.0 4.5 1 06/27/20 00:47 06/29/20 12:36 7439-92-1 Nickel 3.7.1 ug/L 5.0 3.5 1 06/27/20 00:47 06/29/20 12:36 7440-02-0 Selenium ND ug/L 10.0 4.7 1 06/27/20 00:47 06/29/20 12:36 7782-49-2 Silver ND ug/L 5.0 2.5 1 06/27/20 00:47 06/29/20 12:36 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 06/27/20 00:47 06/29/20 12:36 7440-62-2 Zinc ND ug/L 10.0 9.5 1 06/27/20 00:47 06/29/20 12:36 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.0981 ug/L 0.10 0.050 1 06/27/20 00:13 06/29/20 05:43 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/02/20 04:35 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/02/20 04:35 107-13-1 Benzene 2.2 ug/L 1.0 0.15 1 07/02/20 04:35 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/02/20 04:35 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/02/20 04:35 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/02/20 04:35 75-25-2 Bromomethane 0.901 ug/L 2.0 0.62 1 07/02/20 04:35 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/02/20 04:35 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/02/20 04:35 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/02/20 04:35 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/02/20 04:35 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/02/20 04:35 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/02/20 04:35 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/02/20 04:35 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/02/20 04:35 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/02/20 04:35 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/02/20 04:35 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/02/20 04:35 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/02/20 04:35 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/02/20 04:35 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/02/20 04:35 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/02/20 04:35 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/02/20 04:35 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/02/20 04:35 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. B,IH,v2 v2 v2 IK Page 12 of 43 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 Sample: MW-6R Lab ID: 92483790004 Collected: 06/25/20 08:58 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/06/2020 04:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 10.3 ug/L 1.0 0.29 1 07/02/20 04:35 156-59-2 3.1 ug/L 1.0 0.25 1 07/02/20 04:35 156-60-5 ND ug/L 1.0 0.19 1 07/02/20 04:35 78-87-5 N D ug/L 1.0 0.30 1 07/02/20 04:35 10061-01-5 ND ug/L 1.0 0.31 1 07/02/20 04:35 10061-02-6 ND ug/L 150 56.2 1 07/02/20 04:35 123-91-1 ND ug/L 1.0 0.26 1 07/02/20 04:35 100-41-4 ND ug/L 5.0 0.57 1 07/02/20 04:35 591-78-6 ND ug/L 20.0 12.5 1 07/02/20 04:35 74-88-4 ND ug/L 5.0 3.7 1 07/02/20 04:35 75-09-2 ND ug/L 5.0 4.5 1 07/02/20 04:35 108-10-1 ND ug/L 1.0 0.27 1 07/02/20 04:35 100-42-5 ND ug/L 1.0 0.34 1 07/02/20 04:35 630-20-6 ND ug/L 1.0 0.22 1 07/02/20 04:35 79-34-5 0.55J ug/L 1.0 0.16 1 07/02/20 04:35 127-18-4 ND ug/L 1.0 0.24 1 07/02/20 04:35 108-88-3 ND ug/L 1.0 0.18 1 07/02/20 04:35 71-55-6 ND ug/L 1.0 0.24 1 07/02/20 04:35 79-00-5 ND ug/L 1.0 0.22 1 07/02/20 04:35 79-01-6 ND ug/L 1.0 0.31 1 07/02/20 04:35 75-69-4 ND ug/L 1.0 0.35 1 07/02/20 04:35 96-18-4 ND ug/L 2.0 1.4 1 07/02/20 04:35 108-05-4 2.1 ug/L 1.0 0.24 1 07/02/20 04:35 75-01-4 ND ug/L 1.0 0.63 1 07/02/20 04:35 1330-20-7 98 % 70-130 1 07/02/20 04:35 460-00-4 106 % 70-130 1 07/02/20 04:35 17060-07-0 99 % 70-130 1 07/02/20 04:35 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v1 v2 Page 13 of 43 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 Sample: MW-9S Lab ID: 92483790005 Collected: 06/25/20 16:06 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 06/27/20 00:47 06/30/20 20:49 7440-36-0 Arsenic 8.6J ug/L 10.0 4.7 1 06/27/20 00:47 06/29/20 12:39 7440-38-2 Barium 99.2 ug/L 5.0 3.5 1 06/27/20 00:47 06/29/20 12:39 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 06/27/20 00:47 06/29/20 12:39 7440-41-7 Cadmium 9.3 ug/L 1.0 0.40 1 06/27/20 00:47 06/29/20 12:39 7440-43-9 Chromium ND ug/L 5.0 3.7 1 06/27/20 00:47 06/29/20 12:39 7440-47-3 Cobalt 76.7 ug/L 5.0 3.6 1 06/27/20 00:47 06/29/20 12:39 7440-48-4 Copper ND ug/L 5.0 4.3 1 06/27/20 00:47 06/29/20 12:39 7440-50-8 Lead ND ug/L 5.0 4.5 1 06/27/20 00:47 06/29/20 12:39 7439-92-1 Nickel 7.4 ug/L 5.0 3.5 1 06/27/20 00:47 06/29/20 12:39 7440-02-0 Selenium ND ug/L 10.0 4.7 1 06/27/20 00:47 06/29/20 12:39 7782-49-2 Silver ND ug/L 5.0 2.5 1 06/27/20 00:47 06/29/20 12:39 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 06/27/20 00:47 06/29/20 12:39 7440-62-2 Zinc ND ug/L 10.0 9.5 1 06/27/20 00:47 06/29/20 12:39 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.29 ug/L 0.10 0.050 1 06/27/20 00:13 06/29/20 06:43 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/02/20 04:18 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/02/20 04:18 107-13-1 Benzene 0.40J ug/L 1.0 0.15 1 07/02/20 04:18 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/02/20 04:18 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/02/20 04:18 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/02/20 04:18 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/02/20 04:18 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/02/20 04:18 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/02/20 04:18 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/02/20 04:18 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/02/20 04:18 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/02/20 04:18 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/02/20 04:18 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/02/20 04:18 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/02/20 04:18 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/02/20 04:18 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/02/20 04:18 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/02/20 04:18 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/02/20 04:18 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/02/20 04:18 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/02/20 04:18 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/02/20 04:18 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/02/20 04:18 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/02/20 04:18 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. IH,v2 v2 v2 IK Page 14 of 43 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 Sample: MW-9S Lab ID: 92483790005 Collected: 06/25/20 16:06 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/06/2020 04:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 2.5 ug/L 1.0 0.29 1 07/02/20 04:18 156-59-2 ND ug/L 1.0 0.25 1 07/02/20 04:18 156-60-5 ND ug/L 1.0 0.19 1 07/02/20 04:18 78-87-5 ND ug/L 1.0 0.30 1 07/02/20 04:18 10061-01-5 ND ug/L 1.0 0.31 1 07/02/20 04:18 10061-02-6 ND ug/L 150 56.2 1 07/02/20 04:18 123-91-1 ND ug/L 1.0 0.26 1 07/02/20 04:18 100-41-4 ND ug/L 5.0 0.57 1 07/02/20 04:18 591-78-6 ND ug/L 20.0 12.5 1 07/02/20 04:18 74-88-4 ND ug/L 5.0 3.7 1 07/02/20 04:18 75-09-2 ND ug/L 5.0 4.5 1 07/02/20 04:18 108-10-1 ND ug/L 1.0 0.27 1 07/02/20 04:18 100-42-5 ND ug/L 1.0 0.34 1 07/02/20 04:18 630-20-6 ND ug/L 1.0 0.22 1 07/02/20 04:18 79-34-5 ND ug/L 1.0 0.16 1 07/02/20 04:18 127-18-4 ND ug/L 1.0 0.24 1 07/02/20 04:18 108-88-3 ND ug/L 1.0 0.18 1 07/02/20 04:18 71-55-6 ND ug/L 1.0 0.24 1 07/02/20 04:18 79-00-5 ND ug/L 1.0 0.22 1 07/02/20 04:18 79-01-6 ND ug/L 1.0 0.31 1 07/02/20 04:18 75-69-4 ND ug/L 1.0 0.35 1 07/02/20 04:18 96-18-4 ND ug/L 2.0 1.4 1 07/02/20 04:18 108-05-4 ND ug/L 1.0 0.24 1 07/02/20 04:18 75-01-4 ND ug/L 1.0 0.63 1 07/02/20 04:18 1330-20-7 98 % 70-130 1 07/02/20 04:18 460-00-4 105 % 70-130 1 07/02/20 04:18 17060-07-0 97 % 70-130 1 07/02/20 04:18 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v1 v2 Page 15 of 43 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 QC Batch: 550033 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92483790001, 92483790002 METHOD BLANK: 2924973 Associated Lab Samples: 92483790001, 92483790002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers Antimony ug/L ND 5.0 3.0 06/30/20 02:42 Arsenic ug/L 6.8J 10.0 4.7 06/30/20 02:42 BC Barium ug/L ND 5.0 3.5 06/30/20 02:42 Beryllium ug/L ND 1.0 0.70 06/30/20 02:42 Cadmium ug/L ND 1.0 0.40 06/30/20 02:42 Chromium ug/L ND 5.0 3.7 06/30/20 02:42 Cobalt ug/L ND 5.0 3.6 06/30/20 02:42 Copper ug/L ND 5.0 4.3 06/30/20 02:42 Lead ug/L ND 5.0 4.5 06/30/20 02:42 Nickel ug/L ND 5.0 3.5 06/30/20 02:42 Selenium ug/L ND 10.0 4.7 06/30/20 02:42 Silver ug/L ND 5.0 2.5 06/30/20 02:42 Vanadium ug/L ND 5.0 3.9 06/30/20 02:42 Zinc ug/L ND 10.0 9.5 06/30/20 02:42 LABORATORY CONTROL SAMPLE: Parameter 2924974 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 500 523 105 80-120 Arsenic ug/L 500 516 103 80-120 Barium ug/L 500 516 103 80-120 Beryllium ug/L 500 510 102 80-120 Cadmium ug/L 500 511 102 80-120 Chromium ug/L 500 495 99 80-120 Cobalt ug/L 500 514 103 80-120 Copper ug/L 500 527 105 80-120 Lead ug/L 500 511 102 80-120 Nickel ug/L 500 518 104 80-120 Selenium ug/L 500 511 102 80-120 Silver ug/L 250 244 98 80-120 Vanadium ug/L 500 498 100 80-120 Zinc ug/L 500 479 96 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 43 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Surry Co. Lined MSWLF 92483790 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2924975 2924976 MS MSD 92483741007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 537 537 107 107 75-125 0 20 Arsenic ug/L ND 500 500 527 546 104 108 75-125 4 20 Barium ug/L 191 500 500 722 725 106 107 75-125 0 20 Beryllium ug/L ND 500 500 526 527 105 105 75-125 0 20 Cadmium ug/L 1.4 500 500 539 538 108 107 75-125 0 20 Chromium ug/L ND 500 500 524 522 105 104 75-125 0 20 Cobalt ug/L 18.2 500 500 540 538 104 104 75-125 0 20 Copper ug/L ND 500 500 539 538 108 107 75-125 0 20 Lead ug/L ND 500 500 522 516 104 103 75-125 1 20 Nickel ug/L ND 500 500 528 526 105 105 75-125 0 20 Selenium ug/L ND 500 500 550 564 109 112 75-125 2 20 Silver ug/L ND 250 250 258 256 103 102 75-125 1 20 Vanadium ug/L ND 500 500 524 521 104 104 75-125 1 20 Zinc ug/L ND 500 500 517 516 102 102 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 43 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 QC Batch: 550034 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92483790003, 92483790004, 92483790005 METHOD BLANK: 2924977 Matrix: Associated Lab Samples: 92483790003, 92483790004, 92483790005 Blank Parameter Units Result Water Reporting Limit Antimony ug/L ND 5.0 Arsenic ug/L ND 10.0 Barium ug/L ND 5.0 Beryllium ug/L ND 1.0 Cadmium ug/L ND 1.0 Chromium ug/L ND 5.0 Cobalt ug/L ND 5.0 Copper ug/L ND 5.0 Lead ug/L ND 5.0 Nickel ug/L ND 5.0 Selenium ug/L ND 10.0 Silver ug/L ND 5.0 Vanadium ug/L ND 5.0 Zinc ug/L ND 10.0 MDL Analyzed 3.0 06/30/20 20:20 4.7 06/30/20 20:20 3.5 06/29/2012:09 0.70 06/29/2012:09 0.40 06/29/2012:09 3.7 06/29/2012:09 3.6 06/29/2012:09 4.3 06/29/2012:09 4.5 06/29/2012:09 3.5 06/29/2012:09 4.7 06/29/2012:09 2.5 06/29/2012:09 3.9 06/29/2012:09 9.5 06/29/2012:09 LABORATORY CONTROL SAMPLE: Parameter 2924978 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 500 100 80-120 Arsenic ug/L 500 504 101 80-120 Barium ug/L 500 509 102 80-120 Beryllium ug/L 500 516 103 80-120 Cadmium ug/L 500 503 101 80-120 Chromium ug/L 500 506 101 80-120 Cobalt ug/L 500 504 101 80-120 Copper ug/L 500 509 102 80-120 Lead ug/L 500 511 102 80-120 Nickel ug/L 500 502 100 80-120 Selenium ug/L 500 493 99 80-120 Silver ug/L 250 249 100 80-120 Vanadium ug/L 500 513 103 80-120 Zinc ug/L 500 492 98 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 43 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Surry Co. Lined MSWLF 92483790 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2924979 2924980 MS MSD 92483790003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 524 517 105 103 75-125 1 20 Arsenic ug/L ND 500 500 513 492 102 98 75-125 4 20 Barium ug/L 38.6 500 500 557 529 104 98 75-125 5 20 Beryllium ug/L ND 500 500 527 499 105 100 75-125 6 20 Cadmium ug/L ND 500 500 530 507 106 101 75-125 5 20 Chromium ug/L ND 500 500 526 500 105 100 75-125 5 20 Cobalt ug/L ND 500 500 513 487 103 97 75-125 5 20 Copper ug/L ND 500 500 519 497 104 99 75-125 4 20 Lead ug/L ND 500 500 514 494 103 99 75-125 4 20 Nickel ug/L ND 500 500 516 491 103 98 75-125 5 20 Selenium ug/L ND 500 500 531 511 106 102 75-125 4 20 Silver ug/L ND 250 250 260 248 104 99 75-125 4 20 Vanadium ug/L ND 500 500 528 494 105 99 75-125 7 20 Zinc ug/L ND 500 500 514 483 103 96 75-125 6 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 43 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 QC Batch: 550035 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92483790001, 92483790002 METHOD BLANK: 2924981 Matrix: Water Associated Lab Samples: 92483790001, 92483790002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.050 06/28/20 23:02 LABORATORY CONTROL SAMPLE: 2924982 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10.4 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2924983 2924984 MS MSD 92483741002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 10.4 10.3 104 103 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 43 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 QC Batch: 550036 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92483790003, 92483790004, 92483790005 METHOD BLANK: 2924985 Matrix: Water Associated Lab Samples: 92483790003, 92483790004, 92483790005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.050 06/28/20 23:09 LABORATORY CONTROL SAMPLE: 2924986 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10.0 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2924987 2924988 MS MSD 92483790004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L 0.098J 10 10 10.5 10.3 104 102 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 43 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 QC Batch: 550875 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92483790001, 92483790002, 92483790003 METHOD BLANK: 2928332 Matrix: Associated Lab Samples: 92483790001, 92483790002, 92483790003 Blank Parameter Units Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 07/02/20 00:15 1,1,1-Trichloroethane ug/L ND 1.0 0.18 07/02/20 00:15 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 07/02/20 00:15 1,1,2-Trichloroethane ug/L ND 1.0 0.24 07/02/20 00:15 1,1-Dichloroethane ug/L ND 1.0 0.27 07/02/20 00:15 1,1-Dichloroethene ug/L ND 1.0 0.24 07/02/20 00:15 1,2,3-Trichloropropane ug/L ND 1.0 0.35 07/02/20 00:15 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 07/02/20 00:15 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 07/02/20 00:15 1,2-Dichlorobenzene ug/L ND 1.0 0.29 07/02/20 00:15 1,2-Dichloroethane ug/L ND 1.0 0.34 07/02/20 00:15 1,2-Dichloropropane ug/L ND 1.0 0.19 07/02/20 00:15 1,4-Dichlorobenzene ug/L ND 1.0 0.26 07/02/20 00:15 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 07/02/20 00:15 2-Butanone (MEK) ug/L ND 5.0 3.3 07/02/20 00:15 2-Hexanone ug/L ND 5.0 0.57 07/02/20 00:15 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 07/02/20 00:15 Acetone ug/L ND 25.0 6.2 07/02/20 00:15 Acrylonitrile ug/L ND 10.0 0.90 07/02/20 00:15 Benzene ug/L ND 1.0 0.15 07/02/20 00:15 Bromochloromethane ug/L ND 1.0 0.34 07/02/20 00:15 Bromodichloromethane ug/L ND 1.0 0.26 07/02/20 00:15 Bromoform ug/L ND 1.0 0.62 07/02/20 00:15 Bromomethane ug/L ND 2.0 0.62 07/02/20 00:15 Carbon disulfide ug/L ND 2.0 0.40 07/02/20 00:15 Carbon tetrachloride ug/L ND 1.0 0.22 07/02/20 00:15 Chlorobenzene ug/L ND 1.0 0.23 07/02/20 00:15 Chloroethane ug/L ND 1.0 0.49 07/02/20 00:15 Chloroform ug/L ND 5.0 2.3 07/02/20 00:15 Chloromethane ug/L ND 1.0 0.39 07/02/20 00:15 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 07/02/20 00:15 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 07/02/20 00:15 Dibromochloromethane ug/L ND 1.0 0.41 07/02/20 00:15 Dibromomethane ug/L ND 1.0 0.46 07/02/20 00:15 Ethylbenzene ug/L ND 1.0 0.26 07/02/20 00:15 lodomethane ug/L ND 20.0 12.5 07/02/20 00:15 Methylene Chloride ug/L ND 5.0 3.7 07/02/20 00:15 Styrene ug/L ND 1.0 0.27 07/02/20 00:15 Tetrachloroethene ug/L ND 1.0 0.16 07/02/20 00:15 Toluene ug/L ND 1.0 0.24 07/02/20 00:15 13 v2 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 43 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 METHOD BLANK: 2928332 Matrix: Associated Lab Samples: 92483790001, 92483790002, 92483790003 Blank Parameter Units Result Water Reporting Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.25 07/02/20 00:15 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 07/02/20 00:15 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 07/02/20 00:15 Trichloroethene ug/L ND 1.0 0.22 07/02/20 00:15 Trichlorofluoromethane ug/L ND 1.0 0.31 07/02/20 00:15 Vinyl acetate ug/L ND 2.0 1.4 07/02/20 00:15 Vinyl chloride ug/L ND 1.0 0.24 07/02/20 00:15 Xylene (Total) ug/L ND 1.0 0.63 07/02/20 00:15 1,2-Dichloroethane-d4 (S) % 90 70-130 07/02/20 00:15 4-Bromofluorobenzene (S) % 95 70-130 07/02/20 00:15 Toluene-d8 (S) % 99 70-130 07/02/20 00:15 LABORATORY CONTROL SAMPLE: Parameter 2928333 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 53.7 107 70-130 1,1,1-Trichloroethane ug/L 50 47.5 95 70-130 1,1,2,2-Tetrachloroethane ug/L 50 53.5 107 70-130 1,1,2-Trichloroethane ug/L 50 50.2 100 70-130 1,1-Dichloroethane ug/L 50 46.3 93 70-130 1,1-Dichloroethene ug/L 50 49.5 99 70-130 1,2,3-Trichloropropane ug/L 50 52.9 106 70-130 1,2-Dibromo-3-chloropropane ug/L 50 51.0 102 70-130 1,2-Dibromoethane (EDB) ug/L 50 52.3 105 70-130 1,2-Dichlorobenzene ug/L 50 52.2 104 70-130 1,2-Dichloroethane ug/L 50 48.2 96 70-130 1,2-Dichloropropane ug/L 50 50.0 100 70-130 1,4-Dichlorobenzene ug/L 50 51.9 104 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1060 106 59-169 2-Butanone (MEK) ug/L 100 88.8 89 64-135 2-Hexanone ug/L 100 103 103 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 96.9 97 70-130 Acetone ug/L 100 86.1 86 61-157 Acrylonitrile ug/L 250 223 89 61-143 Benzene ug/L 50 49.4 99 70-130 Bromochloromethane ug/L 50 47.3 95 70-130 Bromodichloromethane ug/L 50 46.4 93 70-130 Bromoform ug/L 50 54.0 108 70-130 Bromomethane ug/L 50 43.4 87 38-130lK Carbon disulfide ug/L 50 43.2 86 68-130 Carbon tetrachloride ug/L 50 50.4 101 70-130 Chlorobenzene ug/L 50 51.3 103 70-130 Chloroethane ug/L 50 51.5 103 37-142 Chloroform ug/L 50 47.1 94 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 43 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 LABORATORY CONTROL SAMPLE: Parameter 2928333 Units Spike Conc. LCS LCS Result % Rec Chloromethane ug/L 50 33.5 cis-1,2-Dichloroethene ug/L 50 47.0 cis-1,3-Dichloropropene ug/L 50 51.7 Dibromochloromethane ug/L 50 53.5 Dibromomethane ug/L 50 51.2 Ethylbenzene ug/L 50 51.3 lodomethane ug/L 100 77.6 Methylene Chloride ug/L 50 46.5 Styrene ug/L 50 54.7 Tetrachloroethene ug/L 50 50.4 Toluene ug/L 50 48.4 trans-1,2-Dichloroethene ug/L 50 47.7 trans- 1,3-Dichloropropene ug/L 50 50.8 trans-1,4-Dichloro-2-butene ug/L 50 50.2 Trichloroethene ug/L 50 51.9 Trichlorofluoromethane ug/L 50 45.5 Vinyl acetate ug/L 100 94.3 Vinyl chloride ug/L 50 40.7 Xylene (Total) ug/L 150 156 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % % Rec Limits Qualifiers 67 48-130 v3 94 70-130 103 70-130 107 70-130 102 70-130 103 70-130 78 40-130 93 67-132 109 70-130 101 69-130 97 70-130 95 70-130 102 70-130 100 35-189 104 70-130 91 63-130 94 55-143 81 70-131 104 70-130 92 70-130 104 70-130 96 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2928334 MS 92483822003 Spike Parameter Units Result Conc. MSD Spike Conc. 2928335 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 21.2 20.9 106 105 73-134 1 30 1,1,1-Trichloroethane ug/L ND 20 20 24.0 23.9 120 119 82-143 1 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 23.4 23.3 117 116 70-136 1 30 1,1,2-Trichloroethane ug/L ND 20 20 21.9 21.7 109 108 70-135 1 30 1,1-Dichloroethane ug/L ND 20 20 25.8 25.6 129 128 70-139 1 30 1,1-Dichloroethene ug/L ND 20 20 26.5 26.4 132 132 70-154 0 30 1,2,3-Trichloropropane ug/L ND 20 20 22.5 22.9 112 115 71-137 2 30 1,2-Dibromo-3- ug/L ND 20 20 20.6 20.4 103 102 65-134 1 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 22.6 22.6 113 113 70-137 0 30 1,2-Dichlorobenzene ug/L ND 20 20 23.0 23.0 115 115 70-133 0 30 1,2-Dichloroethane ug/L ND 20 20 24.4 24.4 122 122 70-137 0 30 1,2-Dichloropropane ug/L ND 20 20 24.1 24.1 121 121 70-140 0 30 1,4-Dichlorobenzene ug/L ND 20 20 22.5 22.4 112 112 70-133 0 30 1,4-Dioxane (p-Dioxane) ug/L ND 400 400 479 485 120 121 53-168 1 30 2-Butanone (MEK) ug/L ND 40 40 53.2 51.9 133 130 60-139 2 30 2-Hexanone ug/L ND 40 40 48.1 47.5 120 119 65-138 1 30 4-Methyl-2-pentanone ug/L ND 40 40 46.4 45.8 116 114 65-135 1 30 (MIBK) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 43 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2928334 2928335 MS MSD 92483822003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acetone ug/L ND 40 40 56.4 54.7 141 137 60-148 3 30 v1 Acrylonitrile ug/L ND 100 100 123 126 123 126 64-147 2 30 Benzene ug/L ND 20 20 23.3 23.4 117 117 70-151 0 30 Bromochloromethane ug/L ND 20 20 23.7 23.8 118 119 70-141 0 30 Bromodichloromethane ug/L ND 20 20 19.3 19.6 97 98 70-138 2 30 Bromoform ug/L ND 20 20 18.2 18.2 91 91 63-130 0 30 Bromomethane ug/L ND 20 20 28.5 28.8 142 144 15-152 1 30 Carbon disulfide ug/L ND 20 20 25.9 25.8 129 129 69-149 1 30 Carbon tetrachloride ug/L ND 20 20 20.9 21.3 104 106 70-143 2 30 Chlorobenzene ug/L ND 20 20 22.5 22.7 112 113 70-138 1 30 Chloroethane ug/L ND 20 20 38.1 37.4 190 187 52-163 2 30 IK,IL, M1,v1 Chloroform ug/L ND 20 20 23.8 23.6 119 118 70-139 1 30 Chloromethane ug/L ND 20 20 24.4 24.6 122 123 41-139 1 30 cis-1,2-Dichloroethene ug/L ND 20 20 25.0 25.0 125 125 70-141 0 30 cis-1,3-Dichloropropene ug/L ND 20 20 22.6 22.6 113 113 70-137 0 30 Dibromochloromethane ug/L ND 20 20 20.4 20.3 102 101 70-134 1 30 Dibromomethane ug/L ND 20 20 20.5 20.4 103 102 70-138 1 30 Ethylbenzene ug/L ND 20 20 22.8 22.9 114 115 66-153 0 30 lodomethane ug/L ND 40 40 28.6 28.0 71 70 20-138 2 30 v3 Methylene Chloride ug/L ND 20 20 25.3 25.5 126 127 42-159 1 30 Styrene ug/L ND 20 20 22.8 22.5 114 113 70-135 1 30 Tetrachloroethene ug/L ND 20 20 20.7 21.2 103 106 59-143 3 30 Toluene ug/L ND 20 20 22.4 22.5 112 112 59-148 0 30 trans-1,2-Dichloroethene ug/L ND 20 20 26.2 26.4 131 132 70-146 1 30 trans-1,3-Dichloropropene ug/L ND 20 20 21.7 21.8 108 109 70-135 0 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 17.7 17.8 88 89 47-135 1 30 Trichloroethene ug/L ND 20 20 22.1 22.3 110 111 70-147 1 30 Trichlorofluoromethane ug/L ND 20 20 25.0 25.1 125 125 70-148 0 30 Vinyl acetate ug/L ND 40 40 50.8 49.8 127 125 49-151 2 30 Vinyl chloride ug/L ND 20 20 23.4 23.0 117 115 70-156 2 30 Xylene (Total) ug/L ND 60 60 68.8 69.3 115 115 63-158 1 30 1,2-Dichloroethane-d4 (S) % 115 116 70-130 4-Bromofluorobenzene (S) % 101 101 70-130 Toluene-d8 (S) % 102 103 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 43 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 QC Batch: 550889 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92483790004, 92483790005 METHOD BLANK: 2928454 Associated Lab Samples: 92483790004, 92483790005 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 07/02/20 01:01 1,1,1-Trichloroethane ug/L ND 1.0 0.18 07/02/20 01:01 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 07/02/20 01:01 1,1,2-Trichloroethane ug/L ND 1.0 0.24 07/02/20 01:01 1,1-Dichloroethane ug/L ND 1.0 0.27 07/02/20 01:01 1,1-Dichloroethene ug/L ND 1.0 0.24 07/02/20 01:01 1,2,3-Trichloropropane ug/L ND 1.0 0.35 07/02/20 01:01 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 07/02/20 01:01 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 07/02/20 01:01 1,2-Dichlorobenzene ug/L ND 1.0 0.29 07/02/20 01:01 1,2-Dichloroethane ug/L ND 1.0 0.34 07/02/20 01:01 1,2-Dichloropropane ug/L ND 1.0 0.19 07/02/20 01:01 1,4-Dichlorobenzene ug/L ND 1.0 0.26 07/02/20 01:01 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 07/02/20 01:01 2-Butanone (MEK) ug/L ND 5.0 3.3 07/02/20 01:01 2-Hexanone ug/L ND 5.0 0.57 07/02/20 01:01 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 07/02/20 01:01 Acetone ug/L ND 25.0 6.2 07/02/20 01:01 Acrylonitrile ug/L ND 10.0 0.90 07/02/20 01:01 Benzene ug/L ND 1.0 0.15 07/02/20 01:01 Bromochloromethane ug/L ND 1.0 0.34 07/02/20 01:01 Bromodichloromethane ug/L ND 1.0 0.26 07/02/20 01:01 Bromoform ug/L ND 1.0 0.62 07/02/20 01:01 Bromomethane ug/L 0.89J 2.0 0.62 07/02/20 01:01 Carbon disulfide ug/L ND 2.0 0.40 07/02/20 01:01 Carbon tetrachloride ug/L ND 1.0 0.22 07/02/20 01:01 Chlorobenzene ug/L ND 1.0 0.23 07/02/20 01:01 Chloroethane ug/L ND 1.0 0.49 07/02/20 01:01 Chloroform ug/L ND 5.0 2.3 07/02/20 01:01 Chloromethane ug/L ND 1.0 0.39 07/02/20 01:01 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 07/02/20 01:01 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 07/02/20 01:01 Dibromochloromethane ug/L ND 1.0 0.41 07/02/20 01:01 Dibromomethane ug/L ND 1.0 0.46 07/02/20 01:01 Ethylbenzene ug/L ND 1.0 0.26 07/02/20 01:01 lodomethane ug/L ND 20.0 12.5 07/02/20 01:01 Methylene Chloride ug/L ND 5.0 3.7 07/02/20 01:01 Styrene ug/L ND 1.0 0.27 07/02/20 01:01 Tetrachloroethene ug/L ND 1.0 0.16 07/02/20 01:01 Toluene ug/L ND 1.0 0.24 07/02/20 01:01 Qualifiers v1 IH,v2 v2 v2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 43 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 METHOD BLANK: 2928454 Associated Lab Samples: 92483790004, 92483790005 Parameter Units trans-1,2-Dichloroethene ug/L trans- 1,3-Dichloropropene ug/L trans-1,4-Dichloro-2-butene ug/L Trichloroethene ug/L Trichlorofluoromethane ug/L Vinyl acetate ug/L Vinyl chloride ug/L Xylene (Total) ug/L 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % IAd1 Z.7:7\ to] :YYK.].rr:Z•]I&y1LTA l ;ill �4➢�:Ll.' 1 Parameter QUALITY CONTROL DATA Matrix: Water Blank Result Reporting Limit ND 1.0 ND 1.0 ND 1.0 ND 1.0 ND 1.0 ND 2.0 ND 1.0 ND 1.0 106 70-130 102 70-130 100 70-130 Spike LCS Units Conc. Result MDL Analyzed 0.25 07/02/20 01:01 0.31 07/02/20 01:01 0.54 07/02/20 01:01 0.22 07/02/20 01:01 0.31 07/02/20 01:01 1.4 07/02/20 01:01 0.24 07/02/20 01:01 0.63 07/02/20 01:01 07/02/20 01:01 07/02/20 01:01 07/02/20 01:01 IK v2 Qualifiers LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 53.4 107 70-130 1,1,1-Trichloroethane ug/L 50 46.6 93 70-130 1,1,2,2-Tetrachloroethane ug/L 50 53.7 107 70-130 1,1,2-Trichloroethane ug/L 50 47.2 94 70-130 1,1-Dichloroethane ug/L 50 48.2 96 70-130 1,1-Dichloroethene ug/L 50 47.6 95 70-130 1,2,3-Trichloropropane ug/L 50 54.5 109 70-130 1,2-Dibromo-3-chloropropane ug/L 50 58.8 118 70-130 1,2-Dibromoethane (EDB) ug/L 50 53.3 107 70-130 1,2-Dichlorobenzene ug/L 50 52.7 105 70-130 1,2-Dichloroethane ug/L 50 44.0 88 70-130 1,2-Dichloropropane ug/L 50 49.1 98 70-130 1,4-Dichlorobenzene ug/L 50 52.0 104 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1180 118 59-169 2-Butanone (MEK) ug/L 100 99.1 99 64-135 2-Hexanone ug/L 100 121 121 66-135 v1 4-Methyl-2-pentanone (MIBK) ug/L 100 99.4 99 70-130 Acetone ug/L 100 103 103 61-157 Acrylonitrile ug/L 250 241 96 61-143 Benzene ug/L 50 49.4 99 70-130 Bromochloromethane ug/L 50 49.9 100 70-130 Bromodichloromethane ug/L 50 44.2 88 70-130 Bromoform ug/L 50 54.2 108 70-130 Bromomethane ug/L 50 38.4 77 38-130lH,v3 Carbon disulfide ug/L 50 44.3 89 68-130 Carbon tetrachloride ug/L 50 51.0 102 70-130 Chlorobenzene ug/L 50 52.5 105 70-130 Chloroethane ug/L 50 39.0 78 37-142 v3 Chloroform ug/L 50 46.7 93 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 43 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 LABORATORY CONTROL SAMPLE: Parameter 2928455 Units Spike Conc. LCS LCS Result % Rec Chloromethane ug/L 50 33.0 cis-1,2-Dichloroethene ug/L 50 47.1 cis-1,3-Dichloropropene ug/L 50 52.5 Dibromochloromethane ug/L 50 56.4 Dibromomethane ug/L 50 52.2 Ethylbenzene ug/L 50 53.0 lodomethane ug/L 100 92.7 Methylene Chloride ug/L 50 46.7 Styrene ug/L 50 53.7 Tetrachloroethene ug/L 50 56.4 Toluene ug/L 50 49.1 trans-1,2-Dichloroethene ug/L 50 48.8 trans- 1,3-Dichloropropene ug/L 50 50.9 trans-1,4-Dichloro-2-butene ug/L 50 43.5 Trichloroethene ug/L 50 51.0 Trichlorofluoromethane ug/L 50 33.9 Vinyl acetate ug/L 100 98.9 Vinyl chloride ug/L 50 40.9 Xylene (Total) ug/L 150 161 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % % Rec Limits Qualifiers 66 48-130 v3 94 70-130 105 70-130 113 70-130 104 70-130 106 70-130 93 40-130 93 67-132 107 70-130 113 69-130 98 70-130 98 70-130 102 70-130 87 35-1891K 102 70-130 68 63-130 v3 99 55-143 82 70-131 107 70-130 102 70-130 102 70-130 100 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2928456 MS 92483759023 Spike Parameter Units Result Conc. MSD Spike Conc. 2928457 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 23.2 21.7 116 109 73-134 7 30 1,1,1-Trichloroethane ug/L ND 20 20 21.1 19.9 106 100 82-143 6 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 22.8 21.1 114 106 70-136 8 30 1,1,2-Trichloroethane ug/L ND 20 20 20.6 19.0 103 95 70-135 8 30 1,1-Dichloroethane ug/L ND 20 20 21.3 20.0 106 100 70-139 6 30 1,1-Dichloroethene ug/L ND 20 20 23.0 20.5 115 103 70-154 11 30 1,2,3-Trichloropropane ug/L ND 20 20 22.4 21.9 112 109 71-137 2 30 1,2-Dibromo-3- ug/L ND 20 20 22.9 24.3 115 122 65-134 6 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 22.4 20.1 112 100 70-137 11 30 1,2-Dichlorobenzene ug/L ND 20 20 23.6 21.7 118 109 70-133 8 30 1,2-Dichloroethane ug/L ND 20 20 18.5 17.7 93 88 70-137 5 30 1,2-Dichloropropane ug/L ND 20 20 20.8 20.0 104 100 70-140 4 30 1,4-Dichlorobenzene ug/L ND 20 20 21.2 22.5 106 112 70-133 6 30 1,4-Dioxane (p-Dioxane) ug/L ND 400 400 431 378 108 94 53-168 13 30 2-Butanone (MEK) ug/L ND 40 40 41.3 37.9 103 95 60-139 9 30 2-Hexanone ug/L ND 40 40 44.6 44.8 111 112 65-138 0 30 4-Methyl-2-pentanone ug/L ND 40 40 40.1 36.2 100 90 65-135 10 30 (MIBK) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 43 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2928456 2928457 MS MSD 92483759023 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acetone ug/L ND 40 40 42.4 39.6 106 99 60-148 7 30 Acrylonitrile ug/L ND 100 100 100 94.0 100 94 64-147 6 30 Benzene ug/L ND 20 20 21.7 20.7 109 103 70-151 5 30 Bromochloromethane ug/L ND 20 20 21.9 20.3 109 101 70-141 8 30 Bromodichloromethane ug/L ND 20 20 17.5 17.0 87 85 70-138 3 30 Bromoform ug/L ND 20 20 20.9 19.2 105 96 63-130 8 30 Bromomethane ug/L ND 20 20 26.8 24.6 131 119 15-152 9 30 IH,v3 Carbon disulfide ug/L ND 20 20 20.3 19.1 102 96 69-149 6 30 Carbon tetrachloride ug/L ND 20 20 21.2 19.7 106 99 70-143 7 30 Chlorobenzene ug/L ND 20 20 21.8 21.0 109 105 70-138 4 30 Chloroethane ug/L ND 20 20 19.9 18.1 99 91 52-163 9 30 Chloroform ug/L ND 20 20 21.1 18.9 105 95 70-139 11 30 Chloromethane ug/L ND 20 20 14.4 13.5 72 68 41-139 6 30 v3 cis-1,2-Dichloroethene ug/L ND 20 20 20.5 19.8 103 99 70-141 4 30 cis-1,3-Dichloropropene ug/L ND 20 20 21.7 19.4 109 97 70-137 11 30 Dibromochloromethane ug/L ND 20 20 21.1 20.2 105 101 70-134 4 30 Dibromomethane ug/L ND 20 20 21.8 20.6 109 103 70-138 6 30 Ethylbenzene ug/L ND 20 20 22.3 21.4 111 107 66-153 4 30 lodomethane ug/L ND 40 40 36.7 35.0 92 88 20-138 5 30 v3 Methylene Chloride ug/L ND 20 20 19.8 18.7 99 93 42-159 6 30 Styrene ug/L ND 20 20 22.4 22.7 112 113 70-135 1 30 Tetrachloroethene ug/L ND 20 20 24.0 21.8 120 109 59-143 9 30 Toluene ug/L ND 20 20 20.4 18.2 102 91 59-148 11 30 trans-1,2-Dichloroethene ug/L ND 20 20 21.9 18.7 109 94 70-146 16 30 trans-1,3-Dichloropropene ug/L ND 20 20 20.1 18.1 100 90 70-135 10 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 11.7 13.1 58 65 47-135 11 30 IK,v3 Trichloroethene ug/L ND 20 20 21.5 19.6 107 98 70-147 9 30 Trichlorofluoromethane ug/L ND 20 20 18.6 16.8 93 84 70-148 10 30 Vinyl acetate ug/L ND 40 40 40.1 37.4 100 93 49-151 7 30 Vinyl chloride ug/L ND 20 20 17.6 16.9 88 85 70-156 4 30 Xylene (Total) ug/L ND 60 60 69.6 64.8 116 108 63-158 7 30 1,2-Dichloroethane-d4 (S) % 103 104 70-130 4-Bromofluorobenzene (S) % 98 99 70-130 Toluene-d8 (S) % 99 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 43 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 QC Batch: 550027 Analysis Method: SM 521 OB-2011 QC Batch Method: SM 521OB-2011 Analysis Description: 5210E BOD, 5 day Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92483790002 METHOD BLANK: 2924945 Matrix: Water Associated Lab Samples: 92483790002 Blank Reporting Parameter Units Result Limit BOD, 5 day ug/L ND 2000 LABORATORY CONTROL SAMPLE: 2924946 Spike LCS Parameter Units Conc. Result BOD, 5 day ug/L 198000 198000 SAMPLE DUPLICATE: 2924948 92483576001 Dup Parameter Units Result Result BOD, 5 day ug/L 3.0 mg/L 2820 MDL Analyzed Qualifiers 2000 07/02/20 00:21 LCS % Rec % Rec Limits Qualifiers 100 84.6-115 Max RPD RPD Qualifiers 5 25 B2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 43 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 QC Batch: 551234 Analysis Method: EPA 9040C QC Batch Method: EPA 9040C Analysis Description: 9040 pH Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92483790002 SAMPLE DUPLICATE: 2930240 92483386001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 7.6 7.5 0 9 H3 SAMPLE DUPLICATE: 2930241 92484086002 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 4.7 4.7 0 9 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 43 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 QC Batch: 550394 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92483790002 METHOD BLANK: 2926258 Matrix: Water Associated Lab Samples: 92483790002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfate ug/L ND 1000 500 06/30/2013:16 LABORATORY CONTROL SAMPLE: 2926259 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate ug/L 50000 47700 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2926260 2926261 MS MSD 92483464001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L 21.5 mg/L 50000 50000 70400 71000 98 99 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 43 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 QC Batch: 550019 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92483790002 METHOD BLANK: 2924924 Associated Lab Samples: 92483790002 Parameter Units Nitrogen, Nitrate ug/L LABORATORY CONTROL SAMPLE: 2924925 Parameter Units Nitrogen, Nitrate ug/L Matrix: Water Blank Reporting Result Limit ND 40.0 Spike LCS Conc. Result 1500 1320 MDL Analyzed Qualifiers 10.0 06/26/20 21:47 LCS % Rec % Rec Limits Qualifiers 88 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2924926 2924927 MS MSD 92483695001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate ug/L 0.45 mg/L 1500 1500 1860 1860 94 94 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 43 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 QC Batch: 550271 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92483790002 METHOD BLANK: 2925940 Associated Lab Samples: 92483790002 Parameter Units Phosphorus mg/L LABORATORY CONTROL SAMPLE: 2925941 Parameter Units Phosphorus mg/L Matrix: Water Blank Reporting Result Limit ND 0.050 Spike LCS Conc. Result 2.5 2.5 MDL Analyzed Qualifiers 0.025 06/30/2018:00 LCS % Rec % Rec Limits Qualifiers 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2925942 2925943 MS MSD 92483326003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phosphorus mg/L 0.90 2.5 2.5 3.4 3.4 100 101 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2925944 2925945 MS MSD 92483438001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phosphorus mg/L 2.0 2.5 2.5 4.5 4.5 99 100 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 43 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 QC Batch: 550881 Analysis Method: SM 5220D-2011 QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92483790002 METHOD BLANK: 2928379 Matrix: Water Associated Lab Samples: 92483790002 Blank Reporting Parameter Units Result Limit Chemical Oxygen Demand ug/L ND 25000 LABORATORY CONTROL SAMPLE: 2928380 Spike LCS Parameter Units Conc. Result Chemical Oxygen Demand ug/L 750000 797000 MDL Analyzed Qualifiers 12500 07/02/2016:31 LCS % Rec % Rec Limits Qualifiers 106 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2928381 2928382 MS MSD 92483911002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 6820 mg/L 10000 10000 6670000 6710000 -1470 -1100 90-110 1 3 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2928383 2928384 MS MSD 92483911003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 16400 20000 20000 1700000 1690000 2930 2570 90-110 0 3 M1 mg/L 0 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 43 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Surry Co. Lined MSWLF Pace Project No.: 92483790 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. B2 Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. BC The same analyte was detected in an associated blank at a concentration above 1/2 the reporting limit but below the laboratory reporting limit. H3 Sample was received or analysis requested beyond the recognized method holding time. IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be considered an estimated value. IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. IL This analyte exceeded secondary source verification criteria low for the initial calibration. The reported results should be considered an estimated value. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2020 04:17 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 43 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Surry Co. Lined MSWLF 92483790 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92483790001 SW-D EPA 3010A 550033 EPA 6010D 550040 92483790002 LAGOON EPA 3010A 550033 EPA 6010D 550040 92483790003 MW-2 EPA 3010A 550034 EPA 6010D 550042 92483790004 MW-6R EPA 3010A 550034 EPA 6010D 550042 92483790005 MW-9S EPA 3010A 550034 EPA 6010D 550042 92483790001 SW-D EPA 3010A 550035 EPA 6020B 550045 92483790002 LAGOON EPA 3010A 550035 EPA 6020B 550045 92483790003 MW-2 EPA 3010A 550036 EPA 6020B 550044 92483790004 MW-6R EPA 3010A 550036 EPA 6020B 550044 92483790005 MW-9S EPA 3010A 550036 EPA 6020B 550044 92483790001 SW-D EPA 8260D 550875 92483790002 LAGOON EPA 8260D 550875 92483790003 MW-2 EPA 8260D 550875 92483790004 MW-6R EPA 8260D 550889 92483790005 MW-9S EPA 8260D 550889 92483790002 LAGOON SM 521 OB-2011 550027 SM 521 OB-2011 550049 92483790002 LAGOON EPA 9040C 551234 92483790002 LAGOON EPA 300.0 Rev 2.1 1993 550394 92483790002 LAGOON EPA 353.2 Rev 2.0 1993 550019 92483790002 LAGOON EPA 365.1 Rev 2.0 1993 550271 EPA 365.1 Rev 2.0 1993 550326 92483790002 LAGOON SM 5220D-2011 550881 SM 5220D-2011 551141 Date: 07/06/2020 04:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 37 of 43 Document Name: Document Revised: February 7, 2013 Sample Condition Upon Recelpt(SCUR) Page 1 of 2 Analytical Document No.: Issuing Authority: c_raa_rc.nva-Rav_n6 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersvi(le Q Raleigh[] Mechanicsville[] .. Client Name: PReceiptroject # W 0# : 92483790 Il � III IN 1111111111111 Courier: ❑Fed Esc �DUS�Q U5PS ❑Client ❑ Commercial On-e ❑Other. 92483700 Custody Seal Present? []Yes [21 c Seals Intact? ❑Yes ❑fic—) &—Zd_ J� 6ateJinitlals Person E>uimin ingCantents: UC [.,{J Packing Material: (—]Bubble Wrap Qgu�bble Bags ❑None ❑ Other Biological Tissue Frozen? ❑Yes ®too ❑N/A Thermometer: Type of Ice: ❑Blue ❑None afirt'in ID: 92T061 Cooler Temp {•C): L ' Correction Factor: Add/Subtract ('C) +0. c- • Temp should be above freezing to VC Cooler Temp Corrected (°C): �' ❑Samples out of temp criteria. samples on Ice, cooling process has begun USDA Regulated Soil (E]"N/A, water sample) Did samples origi a in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a Foreign source (internationally, No includingHawall and Puerto Rico)? ❑Yes ❑No Pyes Comments/Discrepancy: Chain of Custody Present? 0V�5 ❑No []N/A 1. Samples Arrived within Hold Time? es QNO ❑N/A 2. Short Hold Time Analysis (42 hr.)? s ❑No El N/A 3. Rush Turn Around Time Requested? ❑Yes Ott ❑N/A 4. Sufficient Volume? [:]No- ❑N/A S. Correct Containers Used? �es ❑No ❑N/A 6. Pace Containers Used? o es ONO ❑NIA Containers Intact? ONO ❑N/A 7, Dissolved analysis: Samples Fleid Filtered? ❑yes uNo ❑N/A B. es No ONIA 9• -IncludesDdte/Time/ID/Analysis Matrix: Heads ace in VOA Vials (>5-6mm)? []yes lNa� []N/A 10. Trip Blank Present? ❑Yes _Qr�tKo ❑IY/A lZ' Trip Blank Custody Seals Present? []yes []No /A COMMENTSISAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted: Datefl­ime: Project Manager SCURF Review: Project Manager SRF Review: Lot ID of split containers: Date: Date: Hefei Data Required? Dyes [:]No Page 38 of 43 Document Name: Ctocurnent Revised Fetruary 7, 20118 'Corldlllan upon Recal t(SCUR) Page 1 of 2 fl 0II Bent No.: Issuing Authority: F•CAR-05-033 Rev.06 Pace Carallnas 4uallty Office *Check maric top half of box if pH anal/or dechlorination is Project # 1 of : 9248379V verified and within the acceptance range for preservation W Samples. PM: AMB Due Date: 07/13/20 exct3ptiorss: VCA, Conform, TQC, Oil and Grease, flRQ/0O15 (water) DCC, LLHg CLIENT: 92—Mun i c i pal -`Bottom half of box is to Ast number of bottle _ � v N QJ 4 � C Z 4 _ y d Z i Q N U n (] z Q 7 3 a b c � A a b H1 m F 2 n a = a o E E ¢ J r. N J in 2 �•+ J ti J J w1 a m � a 2 1 _ a 4 V a c u = m a E Q a E U 0 a O r`� S m E a m U1 v a 2 C 0 a z E G J o 4 m 0 z `.. U O] J E Q N`v b C J E t�7 ? a O J E C�7 = 0 M p 8 0 V u s S O _ j u a S - Z N v"li J L a ,e N v n E o a h z _ n a o m E 4 E 2 y u c a o c 12 _ c v C E o a pH Adjustment Log for Preserved Samples Sample ID Type o6 Preservative PF upon recelpt Date preservation adjusted Tlme preservallan Amaunt of Preservative Lot R adjusted - -- - added — fsote: Whenever there Is a discrepancy affecting iYorth Carolina compliance samples, a copy of this form will be lint cache North Carollna I)EHiJR Certification Office [i.E. Out of hold, Incorrect preservative, out of temp, Incorrect containers. Page 39 of 43 r.+ C m CD a E V 3 A O E N ti d c cu i v w r �LU C � a0 d C) OW � ro N ,h T U�0 1 N L 0 0 Z ro Q � d U� r (NIA) - Pulul seldwaS {N1A1 Jalooa z 2 F Z � PalesS FPo1snD (NIA) ail Lij u d G g N uo pan.MaH cDu!dW3.1 alellnS m w u \v IL 3 o rn 0 Z 4d % LLJ 2' SnHOHdSOHd T 3 LVdilN d (10D �? o0H x U. q w T � C 4 (WIS-uON)euexai0-q'G w t u Fllplgml z •� rn w K O o ddv-sleleW >c S I ddv-SDOA K x >e y LL N a N/A 3sa1 sasdleuv CT i jey10 c m I4ue4iaW m F c cma. Q a tu £OZSZeN ¢ m HOeN N IDH 7 m o c v° - D 2: E E c # d £ONH 6DSZH o z m m I� 'O .0/ `2 w paniasaldun o a v O a a f T AO `n '^ U Q a a IL C W N0I1031100 W dW313ldMS lu 2 J F p V1 Q N 4 V Z Z q tL w w Iy m w LU ❑ z 0 Z r a m w a z w `2 V) W LL yQ} l U C 2 -L�• U] E (dWOD=D eV21O=O) 3dd13ldWtlS C7 (IIeI of sepoo peen seal 9Q03 XiH1vW � O W a O m 9 0 _ °3nwo3�ao� >, fn ix ix [) a v sa E o N y�y U � 07 ;3 o c o c 0 LU a a O O `w w Q c [J n 0 CO of CL � p E O -z;N o E N r L 4 v CC h 4 a U d O Q = N L n N C c O LO O O) @ O E c d N O) ul Z O U Z ❑ ❑ 2 9 F y u a ro E m n w o U¢ C7 w t� a r Page 40 of 43 Document Name: Document Revised: February 7, 2018 Conciltion Upon Retelpt(SCUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville Raleigh[] Mechanicsville❑ ° Client Name: WO# : 92483790 UponlRecei° Project # IIII IN 1111111111111 Courier: ❑Fed Ex ❑UP5❑U5P5 []Client ❑ Commercial [2Pgice []Other,. 924637SO Custody Seal Present? ❑Yes C24o- Seais Intact? Des ❑ffo— Date/initlal5 Person Ewa minlno Contents _ C. Packing Material: ❑dubble Wrap �bt7ie gags ❑None ❑ Other SlologicaI Tissue Fromn? []Yes 014o ❑N/A Thermometer: 92TO61 Type of Ice: �sver lue ❑None L;flrGun iD: ❑B "? Cooler Temp ('Cl: L � �.j.L.iCorrection Factor: Add/subtract (°C) +Q,1 _ Temp should be above freezing to WC Cooler Temp Corrected j'Cj: L' I ❑Samples out of temp criteria. Samples on Ice, cooling process has begun USDA Regulated Soil (O N/A, water sample) Did samples origami ate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples ariginate from a foreign saorce {internaNanaliy, ❑Yes UNa inclu&gHawaii and Puerto aicol?❑Yes []No Comments/Discrepancy: Chain of Custody Present? M es ❑No ❑N/A 1, Samples Arrived within Hold Time? fes No ❑NIA 2. Short Hold Time Analysis (<72 hr.)? des ❑No ❑N/A 3, Rush Turn Around Time Requested? ❑Yes ❑� ❑N/A 4. Sufficient Volume? ❑No ❑NIA 5. Correct Containers Used? {res f j es ❑No ❑N/A 6. Pace Containers Used? jaes ❑No ❑NIA Containers Intact? es ❑Na ❑NIA 7. Dissolved analysis: Samples Field filtered? ❑Yes ErNa ❑NIAsarrinjig. 8. Labels Match COC? files Na N A 9- -Includes Date/Tirne/ID/Analysis Matrix: ifV I Headspace in VOA Vials 1>5-6mmj? ❑Yes ,/ 2<. ❑N/A 10. Trip Blank Present? []yes J24�o ❑N/A 11. Trip Blank Custody 5eals Present? ❑yes RN( �A COMMEN75/SAMPLE DISCREPANCY CLIENT NOTIFICATIONIRESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Date/T-Ime: Field Data Required? Dyes ❑NO Lot ID of split Containers: Date: iC ' G1�7���7Jr Date: � J r� �J(i+ Page 41 of 43 Document Name: Oacurnent Revised: February 7, ZfliB Sample Candltlan UPDst Recel t(5CUR) Page 1 of 2 aceArtaf;ical Document No.: issuing Authority: F•CAR-CS-033-Rev.96 pace Carolinas Quallty Office *Check mark top half of box if PH and/or dechlorination Is Project # { of : 924V379V verified and within the acceptance range for preservation PM: AMB Due Date: 07/13/20 samples. PM Ewceptlorts: VOA, Coliform, TOC, Oil and Grease, ORO/9015 (water) DOC, Mg CLIENT: 92—Mun Lc ipa 1 **Bottom half of box is to list number of bottle 1 2 3 4 5 6 8 9 10 12 a a � z z N Q U = E S 6 M 2 N a v C v Q W N V x o� ri+ S E av l7 a N V Q x a G 0 a z 2 E a E N s J 0 Q z — U x O J¢a ❑ Q Z rn N in N z O 7 E U' 7 Z CL C O E� V' 7 4 O a x O E ❑ _ z L g G. m�E y x 7 x m ? ;r n ] fl Q z a = m Q � 4 a — o N n m V z E ❑o m n > 2 a Z O C -_ ❑ — xl — d oE E o❑ ❑ NN�L PH Adjustment lad fir Preserved Samples Sample ID Type of preservative pM upon receipt Date peeser�atlon adjusted Time preservVan Amount of Preservative !at d adjusted — ——added- Note: Compilance Samples, a Copv of this form Will be>m9 tothe NC)rth Carolina DENNR Certification Office {i.e. Whenever there Is a d15Crepan�y arfetting North Carolina Out of hold, Incorrect preservative, out of temp, Incorrect containers. Page 42 of 43 fNlA1 � }ae{ul sa;dweS 0 F (Null ialoo� 0 O poleeS Apolsn0 �. / w (NIA)8=1 uo PwLlooad $ v C aleJlnS - 3 u! dVJ31 U to am a m a u N 4d x C..) snaDHdSOHd lu F J z w v Goo x a+ E H Goa u a ss N L7� c a O lt� d ❑ E G MIS-uoN} auexo O-y'} � a c d �11PI4tn1 - 2 1 in 1 ddV-sIe}aV4 x x C co � _U I ddb-s00A Q ❑ NIA 3Sa1 SOSAIULIV LL LL a q CY c �0410 TZ ioueUlaW a a - w " j4 g � Q EOZSZeN v U Q Q' 0 ro Z HOeN p c) c .V a, N IOH m M t ❑ 2 # Q a EONH J c O ro v Z v VOSZH �q m o o a m a` a` pauasaiduN Uo rn > G cc ¢ a a a SN3NIH1NU0 d0 ZO N011�31100 IV dk43131dVIVS Q w �1.. O �! zLU J J Q w U 2 LL F u E w cc (} F ¢ ° a Z r w z o u a z w i. - _ J z 0 4 m w € t d {dwo�=� eda�=�1 ddAlaldwvs N o Z Z o v (UOJ UI eePOU pijen ees) 3p07 Xlilltlw z a p m 6 w � - m a o � u a o 7 .v o Vi C rr U a U U m V � �o`3ia`'no3ab� N ❑ ❑ x 2 .aj m c� O W a�d ._ O Co O J r ai j Q W� °T (L ;ems 0 -z ma EN~ 2 =aa a u"m o n a Q—O, a c CL N m N x o ❑ — - tL Q U 0 N F m N ` u ` a n E o C #W 311 r r Page 43 of 43 }n a:c) a C7 w a o lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 July 10, 2020 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on June 26, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace National - Mt. Juliet • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Steven R. Gandy, Municipal Engineering Services Co. REPORT OF LABORATORY ANALYSIS r e This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 81 laneAnalytical www,pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Pace Analytical Services National 12065 Lebanon Road, Mt. Juliet, TN 37122 Alabama Certification #: 40660 Alaska Certification 17-026 Arizona Certification #: AZ0612 Arkansas Certification #: 88-0469 California Certification #: 2932 Canada Certification #: 1461.01 Colorado Certification #: TN00003 Connecticut Certification #: PH-0197 DOD Certification: #1461.01 EPA# TN00003 Florida Certification #: E87487 Georgia DW Certification #: 923 Georgia Certification: NELAP Idaho Certification #: TN00003 Illinois Certification #: 200008 Indiana Certification #: C-TN-01 Iowa Certification #: 364 Kansas Certification #: E-10277 Kentucky UST Certification #: 16 Kentucky Certification #: 90010 Louisiana Certification #: A130792 Louisiana DW Certification #: LA180010 Maine Certification #: TN0002 Maryland Certification #: 324 Massachusetts Certification #: M-TNO03 Michigan Certification #: 9958 Minnesota Certification #: 047-999-395 Mississippi Certification #: TN00003 Missouri Certification #: 340 Montana Certification M CERT0086 Nebraska Certification #: NE-OS-15-05 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS Nevada Certification #: TN-03-2002-34 New Hampshire Certification #: 2975 New Jersey Certification #: TNO02 New Mexico DW Certification New York Certification #: 11742 North Carolina Aquatic Toxicity Certification #: 41 North Carolina Drinking Water Certification #: 21704 North Carolina Environmental Certificate #: 375 North Dakota Certification #: R-140 Ohio VAP Certification #: CL0069 Oklahoma Certification #: 9915 Oregon Certification #: TN200002 Pennsylvania Certification #: 68-02979 Rhode Island Certification #: LA000356 South Carolina Certification #: 84004 South Dakota Certification Tennessee DW/Chem/Micro Certification #: 2006 Texas Certification #: T 104704245-17-14 Texas Mold Certification #: LAB0152 USDA Soil Permit #: P330-15-00234 Utah Certification #: TN00003 Vermont Dept. of Health: ID# VT-2006 Virginia Certification #: VT2006 Virginia Certification #: 460132 Washington Certification #: C847 West Virginia Certification #: 233 Wisconsin Certification #: 9980939910 Wyoming UST Certification #: via A21-A 2926.01 A21-A-ISO 17025 Certification #: 1461.01 A21-A-ISO 17025 Certification #: 1461.02 AIHA-LAP/LLC EMLAP Certification #:100789 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Lab ID Sample ID Matrix Date Collected Date Received 92483788001 MW-10 Water 06/24/20 14:18 06/26/20 08:30 92483788002 MW-1 Water 06/25/20 09:38 06/26/20 08:30 92483788003 MW-3R Water 06/25/20 08:49 06/26/20 08:30 92483788004 MW-4S Water 06/25/20 08:44 06/26/20 08:30 92483788005 MW-41) Water 06/25/20 08:46 06/26/20 08:30 92483788006 MW-5 Water 06/25/20 08:55 06/26/20 08:30 92483788007 MW-8 Water 06/24/2014:36 06/26/20 08:30 92483788008 MW-913 Water 06/23/20 16:02 06/26/20 08:30 92483788009 MW-11S Water 06/24/20 14:15 06/26/20 08:30 92483788010 MW-11D Water 06/24/20 14:16 06/26/20 08:30 92483788011 MW-12 Water 06/23/20 15:16 06/26/20 08:30 92483788012 MW-13 Water 06/23/20 15:10 06/26/20 08:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Surry Co Lined MSWLF 92483788 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92483788001 MW-10 EPA 8151 MTJ 11 PAN EPA 8081 B SEM 21 PASI-C EPA 8082A SEM 8 PASI-C EPA 601 OD KQ 15 PASI-A EPA 6020E JOR 1 PASI-A EPA 7470A SOO 1 PASI-A EPA 8270E PKS 111 PASI-C EPA 8260D LMB 66 PASI-C SM 4500-S2D-2011 LMS1 1 PASI-A SM 4500-CN-E-2011 CJL 1 PASI-A 92483788002 MW-1 EPA 601OD SH1 14 PASI-A EPA 6020E BG2 1 PASI-A EPA 8260D CL 66 PASI-C 92483788003 MW-3R EPA 601OD SH1 14 PASI-A EPA 6020E BG2 1 PASI-A EPA 8260D CL 66 PASI-C 92483788004 MW-4S EPA 601OD SH1 14 PASI-A EPA 6020E BG2 1 PASI-A EPA 8260D CL 66 PASI-C 92483788005 MW-41) EPA 601OD SH1 14 PASI-A EPA 6020E BG2 1 PASI-A EPA 8260D CL 66 PASI-C 92483788006 MW-5 EPA 601OD SH1 14 PASI-A EPA 6020E BG2 1 PASI-A EPA 8260D SAS 66 PASI-C 92483788007 MW-8 EPA 601OD SH1 14 PASI-A EPA 6020E BG2 1 PASI-A EPA 8260D LMB 66 PASI-C 92483788008 MW-91) EPA 601OD SH1 14 PASI-A EPA 6020E BG2 1 PASI-A EPA 8260D CL 66 PASI-C 92483788009 MW-11S EPA 601OD SH1 14 PASI-A EPA 6020E BG2 1 PASI-A EPA 8260D LMB 66 PASI-C 92483788010 MW-11D EPA 601OD SH1 14 PASI-A EPA 6020E BG2 1 PASI-A EPA 8260D LMB 66 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92483788011 MW-12 EPA 6010D SH1 14 PASI-A EPA 6020E BG2 1 PASI-A EPA 8260D CL 66 PASI-C 92483788012 MW-13 EPA 6010D SH1 14 PASI-A EPA 6020E BG2 1 PASI-A EPA 8260D CL 66 PASI-C PAN = Pace National - Mt. Juliet PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-10 Lab ID: 92483788001 Collected: 06/24/20 14:18 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Chlorinated Herb. (GC) 8151 2,4-D Dalapon 2,4-DB Dicamba Dichloroprop Dinoseb MCPA MCPP 2,4,5-T 2,4,5-TP (Silvex) Surrogates 2,4-DCAA (S) 8081 OC Pesticides RVE Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) Chlordane (Technical) 4,4'-DDD 4,4'-DDE 4,4'-DDT Dieldrin Endosulfan I Endosulfan 11 Endosulfan sulfate Endrin Endrin aldehyde Heptachlor Heptachlor epoxide Methoxychlor Toxaphene Surrogates Tetrachloro-m-xylene (S) Decachlorobiphenyl (S) 8082 GCS PCB RVE PCB-1016 (Aroclor 1016) PCB-1221 (Aroclor 1221) PCB-1232 (Aroclor 1232) PCB-1242 (Aroclor 1242) PCB-1248 (Aroclor 1248) Date: 07/10/2020 04:55 PM Analytical Method: EPA8151 Preparation Method: 8151A Pace National - Mt. Juliet ND ug/L 2.00 0.547 1 06/29/20 18:12 07/03/20 03:16 94-75-7 ND ug/L 2.00 0.344 1 06/29/20 18:12 07/03/20 03:16 127-20-8 ND ug/L 2.00 0.302 1 06/29/20 18:12 07/03/20 03:16 94-82-6 ND ug/L 2.00 0.245 1 06/29/20 18:12 07/03/20 03:16 1918-00-9 ND ug/L 2.00 1.04 1 06/29/20 18:12 07/03/20 03:16 15165-67-0 ND ug/L 2.00 0.250 1 06/29/20 18:12 07/03/20 03:16 88-85-7 ND ug/L 100 13.1 1 06/29/20 18:12 07/03/20 03:16 94-74-6 ND ug/L 100 66.0 1 06/29/20 18:12 07/03/20 03:16 7085-19-0 ND ug/L 2.00 0.258 1 06/29/20 18:12 07/03/20 03:16 93-76-5 ND ug/L 2.00 0.335 1 06/29/20 18:12 07/03/20 03:16 93-72-1 53.4 % 14.0-158 1 06/29/20 18:12 07/03/20 03:16 19719-28-9 Analytical Method: EPA 8081 B Preparation Method: EPA 351 OC Pace Analytical Services - Charlotte ND ug/L 0.050 0.022 1 07/01/20 11:13 07/06/20 14:15 309-00-2 ND ug/L 0.050 0.019 1 07/01/20 11:13 07/06/20 14:15 319-84-6 ND ug/L 0.050 0.014 1 07/01/20 11:13 07/06/20 14:15 319-85-7 ND ug/L 0.050 0.020 1 07/01/20 11:13 07/06/20 14:15 319-86-8 ND ug/L 0.050 0.012 1 07/01/20 11:13 07/06/20 14:15 58-89-9 ND ug/L 0.20 0.14 1 07/01/20 11:13 07/06/20 14:15 57-74-9 ND ug/L 0.050 0.0069 1 07/01/20 11:13 07/06/20 14:15 72-54-8 ND ug/L 0.050 0.0064 1 07/01/20 11:13 07/06/20 14:15 72-55-9 ND ug/L 0.050 0.018 1 07/01/20 11:13 07/06/20 14:15 50-29-3 ND ug/L 0.050 0.0073 1 07/01/20 11:13 07/06/20 14:15 60-57-1 ND ug/L 0.050 0.0094 1 07/01/20 11:13 07/06/20 14:15 959-98-8 ND ug/L 0.050 0.0065 1 07/01/20 11:13 07/06/20 14:15 33213-65-9 ND ug/L 0.050 0.0091 1 07/01/20 11:13 07/06/20 14:15 1031-07-8 ND ug/L 0.050 0.0089 1 07/01/20 11:13 07/06/20 14:15 72-20-8 ND ug/L 0.050 0.013 1 07/01/20 11:13 07/06/20 14:15 7421-93-4 ND ug/L 0.050 0.016 1 07/01/20 11:13 07/06/20 14:15 76-44-8 ND ug/L 0.050 0.0097 1 07/01/20 11:13 07/06/20 14:15 1024-57-3 ND ug/L 0.15 0.033 1 07/01/20 11:13 07/06/20 14:15 72-43-5 ND ug/L 0.20 0.19 1 07/01/20 11:13 07/06/20 14:15 8001-35-2 105 % 10-130 1 07/01/20 11:13 07/06/20 14:15 877-09-8 93 % 10-130 1 07/01/20 11:13 07/06/20 14:15 2051-24-3 Analytical Method: EPA 8082A Preparation Method: EPA 351 OC Pace Analytical Services - Charlotte ND ug/L 0.50 0.22 1 07/01/20 11:13 07/02/20 22:50 12674-11-2 ND ug/L 0.50 0.32 1 07/01/20 11:13 07/02/20 22:50 11104-28-2 ND ug/L 0.50 0.21 1 07/01/20 11:13 07/02/20 22:50 11141-16-5 N D ug/L 0.50 0.44 1 07/01/20 11:13 07/02/20 22:50 53469-21-9 ND ug/L 0.50 0.34 1 07/01/20 11:13 07/02/20 22:50 12672-29-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. R1 LO Page 6 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-10 Lab ID: 92483788001 Collected: 06/24/20 14:18 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8082 GCS PCB RVE Analytical Method: EPA 8082A Preparation Method: EPA 3510C Pace Analytical Services - Charlotte PCB-1254 (Aroclor 1254) ND ug/L 0.50 0.24 1 07/01/20 11:13 07/02/20 22:50 11097-69-1 PCB-1260 (Aroclor 1260) ND ug/L 0.50 0.30 1 07/01/20 11:13 07/02/20 22:50 11096-82-5 Surrogates Decachlorobiphenyl (S) 59 % 10-130 1 07/01/20 11:13 07/02/20 22:50 2051-24-3 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 06/27/20 00:47 06/30/20 04:10 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 06/27/20 00:47 06/30/20 04:10 7440-38-2 BC Barium 37.0 ug/L 5.0 3.5 1 06/27/20 00:47 06/30/20 04:10 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 06/27/20 00:47 06/30/20 04:10 7440-41-7 Cadmium 1.3 ug/L 1.0 0.40 1 06/27/20 00:47 06/30/20 04:10 7440-43-9 Chromium ND ug/L 5.0 3.7 1 06/27/20 00:47 06/30/20 04:10 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 06/27/20 00:47 06/30/20 04:10 7440-48-4 Copper ND ug/L 5.0 4.3 1 06/27/20 00:47 06/30/20 04:10 7440-50-8 Lead ND ug/L 5.0 4.5 1 06/27/20 00:47 06/30/20 04:10 7439-92-1 Nickel ND ug/L 5.0 3.5 1 06/27/20 00:47 06/30/20 04:10 7440-02-0 Selenium ND ug/L 10.0 4.7 1 06/27/20 00:47 06/30/20 04:10 7782-49-2 Silver ND ug/L 5.0 2.5 1 06/27/20 00:47 06/30/20 04:10 7440-22-4 Tin ND ug/L 5.0 4.7 1 06/27/20 00:47 06/30/20 04:10 7440-31-5 Vanadium ND ug/L 5.0 3.9 1 06/27/20 00:47 06/30/20 04:10 7440-62-2 Zinc 11.0 ug/L 10.0 9.5 1 06/27/20 00:47 06/30/20 04:10 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 06/27/20 00:13 06/29/20 04:53 7440-28-0 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury ND ug/L 0.20 0.12 1 06/28/20 23:35 06/29/20 16:11 7439-97-6 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte Acenaphthene ND ug/L 10.0 1.4 1 07/01/20 11:28 07/10/20 04:39 83-32-9 Acenaphthylene ND ug/L 10.0 1.5 1 07/01/20 11:28 07/10/20 04:39 208-96-8 Acetophenone ND ug/L 10.0 1.3 1 07/01/20 11:28 07/10/20 04:39 98-86-2 2-Acetylaminofluorene ND ug/L 10.0 1.9 1 07/01/20 11:28 07/10/20 04:39 53-96-3 4-Aminobiphenyl ND ug/L 10.0 4.2 1 07/01/20 11:28 07/10/20 04:39 92-67-1 Anthracene ND ug/L 10.0 1.6 1 07/01/20 11:28 07/10/20 04:39 120-12-7 Benzo(a)anthracene ND ug/L 10.0 1.5 1 07/01/20 11:28 07/10/20 04:39 56-55-3 Benzo(a)pyrene ND ug/L 10.0 1.8 1 07/01/20 11:28 07/10/20 04:39 50-32-8 Benzo(b)fluoranthene ND ug/L 10.0 1.7 1 07/01/20 11:28 07/10/20 04:39 205-99-2 Benzo(g,h,i)perylene ND ug/L 10.0 1.6 1 07/01/20 11:28 07/10/20 04:39 191-24-2 Benzo(k)fluoranthene ND ug/L 10.0 1.5 1 07/01/20 11:28 07/10/20 04:39 207-08-9 Benzyl alcohol ND ug/L 20.0 2.6 1 07/01/20 11:28 07/10/20 04:39 100-51-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-10 Lab ID: 92483788001 Collected: 06/24/20 14:18 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 4-Bromophenylphenyl ether ND ug/L 10.0 1.2 1 07/01/20 11:28 07/10/20 04:39 101-55-3 Butylbenzylphthalate ND ug/L 10.0 1.9 1 07/01/20 11:28 07/10/20 04:39 85-68-7 4-ChIoro-3-methyl phenol ND ug/L 10.0 2.8 1 07/01/20 11:28 07/10/20 04:39 59-50-7 4-Chloroaniline ND ug/L 20.0 2.8 1 07/01/20 11:28 07/10/20 04:39 106-47-8 Chlorobenzilate ND ug/L 10.0 3.6 1 07/01/20 11:28 07/10/20 04:39 510-15-6 L1 bis(2-Chloroethoxy)methane ND ug/L 10.0 1.3 1 07/01/20 11:28 07/10/20 04:39 111-91-1 bis(2-Chloroethyl) ether ND ug/L 10.0 1.7 1 07/01/20 11:28 07/10/20 04:39 111-44-4 2-Chloronaphthalene ND ug/L 10.0 1.4 1 07/01/20 11:28 07/10/20 04:39 91-58-7 2-Chlorophenol ND ug/L 10.0 1.4 1 07/01/20 11:28 07/10/20 04:39 95-57-8 4-Chlorophenylphenyl ether ND ug/L 10.0 1.5 1 07/01/20 11:28 07/10/20 04:39 7005-72-3 Chrysene ND ug/L 10.0 1.4 1 07/01/20 11:28 07/10/20 04:39 218-01-9 Diallate ND ug/L 10.0 2.7 1 07/01/20 11:28 07/10/20 04:39 2303-16-4 Dibenz(a,h)anthracene ND ug/L 10.0 1.6 1 07/01/20 11:28 07/10/20 04:39 53-70-3 Dibenzofuran ND ug/L 10.0 1.3 1 07/01/20 11:28 07/10/20 04:39 132-64-9 3,3'-Dichlorobenzidine ND ug/L 20.0 2.7 1 07/01/20 11:28 07/10/20 04:39 91-94-1 2,4-Dichlorophenol ND ug/L 10.0 1.5 1 07/01/20 11:28 07/10/20 04:39 120-83-2 2,6-Dichlorophenol ND ug/L 10.0 2.7 1 07/01/20 11:28 07/10/20 04:39 87-65-0 Diethylphthalate ND ug/L 10.0 1.6 1 07/01/20 11:28 07/10/20 04:39 84-66-2 Dimethoate ND ug/L 10.0 2.0 1 07/01/20 11:28 07/10/20 04:39 60-51-5 P-Dimethylaminoazobenzene ND ug/L 5.0 3.3 1 07/01/20 11:28 07/10/20 04:39 60-11-7 7,12-Dimethylbenz(a)anthracene ND ug/L 10.0 2.8 1 07/01/20 11:28 07/10/20 04:39 57-97-6 3,3'-Dimethylbenzidine ND ug/L 25.0 23.5 1 07/01/20 11:28 07/10/20 04:39 119-93-7 IH 2,4-Dimethylphenol ND ug/L 10.0 1.5 1 07/01/20 11:28 07/10/20 04:39 105-67-9 Dimethylphthalate ND ug/L 10.0 1.4 1 07/01/20 11:28 07/10/20 04:39 131-11-3 Di-n-butylphthalate ND ug/L 10.0 1.6 1 07/01/20 11:28 07/10/20 04:39 84-74-2 4,6-Dinitro-2-methyl phenol ND ug/L 20.0 4.5 1 07/01/20 11:28 07/10/20 04:39 534-52-1 1,3-Dinitrobenzene ND ug/L 10.0 3.7 1 07/01/20 11:28 07/10/20 04:39 99-65-0 2,4-Dinitrophenol ND ug/L 50.0 7.3 1 07/01/20 11:28 07/10/20 04:39 51-28-5 2,4-Dinitrotoluene ND ug/L 10.0 1.7 1 07/01/20 11:28 07/10/20 04:39 121-14-2 2,6-Dinitrotoluene ND ug/L 10.0 1.7 1 07/01/20 11:28 07/10/20 04:39 606-20-2 Di-n-octylphthalate ND ug/L 10.0 2.2 1 07/01/20 11:28 07/10/20 04:39 117-84-0 Diphenylamine ND ug/L 10.0 1.4 1 07/01/20 11:28 07/10/20 04:39 122-39-4 Disulfoton ND ug/L 10.0 6.0 1 07/01/20 11:28 07/10/20 04:39 298-04-4 bis(2- Ethyl hexyl)phthalate ND ug/L 6.0 2.0 1 07/01/20 11:28 07/10/20 04:39 117-81-7 Ethyl methanesulfonate ND ug/L 20.0 2.8 1 07/01/20 11:28 07/10/20 04:39 62-50-0 Famphur ND ug/L 10.0 5.7 1 07/01/20 11:28 07/10/20 04:39 52-85-7 Fluoranthene ND ug/L 10.0 1.6 1 07/01/20 11:28 07/10/20 04:39 206-44-0 Fluorene ND ug/L 10.0 1.4 1 07/01/20 11:28 07/10/20 04:39 86-73-7 Hexachlorobenzene ND ug/L 10.0 1.3 1 07/01/20 11:28 07/10/20 04:39 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 2.4 1 07/01/20 11:28 07/10/20 04:39 77-47-4 Hexachloroethane ND ug/L 10.0 1.3 1 07/01/20 11:28 07/10/20 04:39 67-72-1 Hexachloropropene ND ug/L 10.0 5.5 1 07/01/20 11:28 07/10/20 04:39 1888-71-7 Indeno(1,2,3-cd)pyrene ND ug/L 10.0 1.7 1 07/01/20 11:28 07/10/20 04:39 193-39-5 Isodrin ND ug/L 10.0 3.0 1 07/01/20 11:28 07/10/20 04:39 465-73-6 Isophorone ND ug/L 10.0 1.3 1 07/01/20 11:28 07/10/20 04:39 78-59-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-10 Lab ID: 92483788001 Collected: 06/24/20 14:18 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte Isosafrole ND ug/L 10.0 3.6 1 07/01/20 11:28 07/10/20 04:39 120-58-1 Kepone ND ug/L 10.0 8.2 1 07/01/20 11:28 07/10/20 04:39 143-50-0 Methapyrilene ND ug/L 50.0 27.2 1 07/01/20 11:28 07/10/20 04:39 91-80-5 3-Methylcholanthrene ND ug/L 10.0 5.3 1 07/01/20 11:28 07/10/20 04:39 56-49-5 Methyl methanesulfonate ND ug/L 5.0 3.0 1 07/01/20 11:28 07/10/20 04:39 66-27-3 2-Methylnaphthalene ND ug/L 10.0 1.4 1 07/01/20 11:28 07/10/20 04:39 91-57-6 Methyl parathion ND ug/L 10.0 2.0 1 07/01/20 11:28 07/10/20 04:39 298-00-0 2-Methylphenol(o-Cresol) ND ug/L 10.0 1.2 1 07/01/20 11:28 07/10/20 04:39 95-48-7 3&4-Methyl phenol (m&p Cresol) ND ug/L 10.0 1.2 1 07/01/20 11:28 07/10/20 04:39 15831-10-4 1-Naphthalenamine ND ug/L 5.0 4.6 1 07/01/20 11:28 07/10/20 04:39 134-32-7 2-Naphthalenamine ND ug/L 10.0 6.1 1 07/01/20 11:28 07/10/20 04:39 91-59-8 1,4-Naphthoquinone ND ug/L 5.0 2.4 1 07/01/20 11:28 07/10/20 04:39 130-15-4 2-Nitroaniline ND ug/L 20.0 3.0 1 07/01/20 11:28 07/10/20 04:39 88-74-4 3-Nitroaniline ND ug/L 20.0 2.8 1 07/01/20 11:28 07/10/20 04:39 99-09-2 4-Nitroaniline ND ug/L 20.0 3.1 1 07/01/20 11:28 07/10/20 04:39 100-01-6 Nitrobenzene ND ug/L 10.0 1.5 1 07/01/20 11:28 07/10/20 04:39 98-95-3 2-Nitrophenol ND ug/L 10.0 1.7 1 07/01/20 11:28 07/10/20 04:39 88-75-5 4-Nitrophenol ND ug/L 50.0 9.4 1 07/01/20 11:28 07/10/20 04:39 100-02-7 5-Nitro-o-toluidine ND ug/L 10.0 2.4 1 07/01/20 11:28 07/10/20 04:39 99-55-8 N-Nitrosodiethylamine ND ug/L 10.0 2.0 1 07/01/20 11:28 07/10/20 04:39 55-18-5 N-Nitrosodimethylamine ND ug/L 10.0 1.8 1 07/01/20 11:28 07/10/20 04:39 62-75-9 N-Nitroso-di-n-butylamine ND ug/L 10.0 6.2 1 07/01/20 11:28 07/10/20 04:39 924-16-3 N-Nitroso-di-n-propylamine ND ug/L 10.0 1.3 1 07/01/20 11:28 07/10/20 04:39 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1.4 1 07/01/20 11:28 07/10/20 04:39 86-30-6 N-Nitrosomethylethylamine ND ug/L 10.0 3.3 1 07/01/20 11:28 07/10/20 04:39 10595-95-6 N-Nitrosopiperidine ND ug/L 10.0 2.6 1 07/01/20 11:28 07/10/20 04:39 100-75-4 N-Nitrosopyrrolidine ND ug/L 10.0 2.1 1 07/01/20 11:28 07/10/20 04:39 930-55-2 O,O,O-Triethylphosphorothioate ND ug/L 10.0 3.5 1 07/01/20 11:28 07/10/20 04:39 126-68-1 2,2'-Oxybis(1-chloropropane) ND ug/L 10.0 1.3 1 07/01/20 11:28 07/10/20 04:39 108-60-1 Parathion (Ethyl parathion) ND ug/L 10.0 2.0 1 07/01/20 11:28 07/10/20 04:39 56-38-2 Pentachlorobenzene ND ug/L 10.0 4.4 1 07/01/20 11:28 07/10/20 04:39 608-93-5 Pentachloronitrobenzene ND ug/L 10.0 2.4 1 07/01/20 11:28 07/10/20 04:39 82-68-8 Pentachlorophenol ND ug/L 20.0 2.8 1 07/01/20 11:28 07/10/20 04:39 87-86-5 Phenacetin ND ug/L 10.0 1.9 1 07/01/20 11:28 07/10/20 04:39 62-44-2 Phenanthrene ND ug/L 10.0 1.4 1 07/01/20 11:28 07/10/20 04:39 85-01-8 Phenol ND ug/L 10.0 1.5 1 07/01/20 11:28 07/10/20 04:39 108-95-2 p-Phenylenediamine ND ug/L 10.0 4.2 1 07/01/20 11:28 07/10/20 04:39 106-50-3 Phorate ND ug/L 10.0 3.8 1 07/01/20 11:28 07/10/20 04:39 298-02-2 Pronamide ND ug/L 10.0 2.4 1 07/01/20 11:28 07/10/20 04:39 23950-58-5 Pyrene ND ug/L 10.0 1.5 1 07/01/20 11:28 07/10/20 04:39 129-00-0 Safrole ND ug/L 10.0 3.2 1 07/01/20 11:28 07/10/20 04:39 94-59-7 1,2,4,5-Tetrachlorobenzene ND ug/L 10.0 4.6 1 07/01/20 11:28 07/10/20 04:39 95-94-3 2,3,4,6-Tetrachlorophenol ND ug/L 10.0 1.6 1 07/01/20 11:28 07/10/20 04:39 58-90-2 Thionazin ND ug/L 10.0 1.8 1 07/01/20 11:28 07/10/20 04:39 297-97-2 O-Toluidine ND ug/L 10.0 2.8 1 07/01/20 11:28 07/10/20 04:39 95-53-4 REPORT OF LABORATORY ANALYSIS IH IL L2 This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-10 Lab ID: 92483788001 Collected: 06/24/20 14:18 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 2,4,5-Trichlorophenol ND ug/L 10.0 1.5 1 07/01/20 11:28 07/10/20 04:39 95-95-4 2,4,6-Trichlorophenol ND ug/L 10.0 1.4 1 07/01/20 11:28 07/10/20 04:39 88-06-2 1,3,5-Trinitrobenzene ND ug/L 10.0 5.3 1 07/01/20 11:28 07/10/20 04:39 99-35-4 Surrogates Nitrobenzene-d5 (S) 68 % 13-130 1 07/01/20 11:28 07/10/20 04:39 4165-60-0 2-Fluorobiphenyl (S) 61 % 13-130 1 07/01/20 11:28 07/10/20 04:39 321-60-8 Terphenyl-d14 (S) 117 % 25-130 1 07/01/20 11:28 07/10/20 04:39 1718-51-0 Phenol-d6 (S) 38 % 10-130 1 07/01/20 11:28 07/10/20 04:39 13127-88-3 2-Fluorophenol (S) 45 % 10-130 1 07/01/20 11:28 07/10/20 04:39 367-12-4 2,4,6-Tribromophenol (S) 91 % 10-137 1 07/01/20 11:28 07/10/20 04:39 118-79-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/01/20 09:37 67-64-1 Acetonitrile ND ug/L 50.0 30.4 1 07/01/20 09:37 75-05-8 Acrolein ND ug/L 10.0 2.7 1 07/01/20 09:37 107-02-8 Acrylonitrile ND ug/L 10.0 0.90 1 07/01/20 09:37 107-13-1 Allyl chloride ND ug/L 2.0 0.28 1 07/01/20 09:37 107-05-1 Benzene 0.44J ug/L 1.0 0.15 1 07/01/20 09:37 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/01/20 09:37 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/01/20 09:37 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/01/20 09:37 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/01/20 09:37 74-83-9 IH,IK 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/01/20 09:37 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/01/20 09:37 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/01/20 09:37 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/01/20 09:37 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/01/20 09:37 75-00-3 IK Chloroform ND ug/L 5.0 2.3 1 07/01/20 09:37 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/01/20 09:37 74-87-3 v2 Chloroprene ND ug/L 5.0 1.7 1 07/01/20 09:37 126-99-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/01/20 09:37 124-48-1 Dibromomethane ND ug/L 1.0 0.46 1 07/01/20 09:37 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/01/20 09:37 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/01/20 09:37 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/01/20 09:37 110-57-6 Dichlorodifluoromethane ND ug/L 1.0 0.23 1 07/01/20 09:37 75-71-8 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/01/20 09:37 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/01/20 09:37 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/01/20 09:37 75-35-4 cis-1,2-Dichloroethene 0.95J ug/L 1.0 0.29 1 07/01/20 09:37 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.25 1 07/01/20 09:37 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.19 1 07/01/20 09:37 78-87-5 1,3-Dichloropropane ND ug/L 1.0 0.16 1 07/01/20 09:37 142-28-9 2,2-Dichloropropane ND ug/L 1.0 0.27 1 07/01/20 09:37 594-20-7 Date: 07/10/2020 04:55 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-10 Lab ID: 92483788001 Collected: 06/24/20 14:18 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,1-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene Ethyl methacrylate Hexachloro-1,3-butadiene 2-Hexanone lodomethane Isobutanol Methacrylonitrile Methylene Chloride Methyl methacrylate 4-Methyl-2-pentanone (MIBK) Naphthalene Propionitrile Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 4500S213 Sulfide Water Sulfide 4500CNE Cyanide, Total Cyanide Date: 07/10/2020 04:55 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.21 1 07/01/20 09:37 563-58-6 ND ug/L 1.0 0.30 1 07/01/20 09:37 10061-01-5 ND ug/L 1.0 0.31 1 07/01/20 09:37 10061-02-6 ND ug/L 150 56.2 1 07/01/20 09:37 123-91-1 ND ug/L 1.0 0.26 1 07/01/20 09:37 100-41-4 ND ug/L 1.0 0.51 1 07/01/20 09:37 97-63-2 ND ug/L 1.0 0.44 1 07/01/20 09:37 87-68-3 ND ug/L 5.0 0.57 1 07/01/20 09:37 591-78-6 ND ug/L 20.0 12.5 1 07/01/20 09:37 74-88-4 ND ug/L 100 66.4 1 07/01/20 09:37 78-83-1 v2 ND ug/L 10.0 1.9 1 07/01/20 09:37 126-98-7 ND ug/L 5.0 3.7 1 07/01/20 09:37 75-09-2 ND ug/L 2.0 0.46 1 07/01/20 09:37 80-62-6 ND ug/L 5.0 4.5 1 07/01/20 09:37 108-10-1 ND ug/L 1.0 0.35 1 07/01/20 09:37 91-20-3 ND ug/L 20.0 1.8 1 07/01/20 09:37 107-12-0 ND ug/L 1.0 0.27 1 07/01/20 09:37 100-42-5 ND ug/L 1.0 0.34 1 07/01/20 09:37 630-20-6 ND ug/L 1.0 0.22 1 07/01/20 09:37 79-34-5 ND ug/L 1.0 0.16 1 07/01/20 09:37 127-18-4 ND ug/L 1.0 0.24 1 07/01/20 09:37 108-88-3 ND ug/L 1.0 0.34 1 07/01/20 09:37 87-61-6 ND ug/L 1.0 0.22 1 07/01/20 09:37 120-82-1 ND ug/L 1.0 0.18 1 07/01/20 09:37 71-55-6 ND ug/L 1.0 0.24 1 07/01/20 09:37 79-00-5 ND ug/L 1.0 0.22 1 07/01/20 09:37 79-01-6 ND ug/L 1.0 0.31 1 07/01/20 09:37 75-69-4 ND ug/L 1.0 0.35 1 07/01/20 09:37 96-18-4 ND ug/L 2.0 1.4 1 07/01/20 09:37 108-05-4 ND ug/L 1.0 0.24 1 07/01/20 09:37 75-01-4 ND ug/L 1.0 0.63 1 07/01/20 09:37 1330-20-7 97 % 70-130 1 07/01/20 09:37 460-00-4 100 % 70-130 1 07/01/20 09:37 17060-07-0 99 % 70-130 1 07/01/20 09:37 2037-26-5 Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville ND ug/L 100 50.0 1 06/30/2018:24 18496-25-8 Analytical Method: SM 4500-CN-E-2011 Preparation Method: SM 4500-CN-E-2011 Pace Analytical Services -Asheville ND ug/L 8.0 6.0 1 06/29/20 22:28 06/30/20 01:25 57-12-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MWA Lab ID: 92483788002 Collected: 06/25/20 09:38 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 06/30/20 00:35 07/01/20 04:06 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 04:06 7440-38-2 Barium 17.3 ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 04:06 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 06/30/20 00:35 07/01/20 04:06 7440-41-7 Cadmium 1.1 ug/L 1.0 0.40 1 06/30/20 00:35 07/01/20 04:06 7440-43-9 Chromium ND ug/L 5.0 3.7 1 06/30/20 00:35 07/01/20 04:06 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 06/30/20 00:35 07/01/20 04:06 7440-48-4 Copper ND ug/L 5.0 4.3 1 06/30/20 00:35 07/01/20 04:06 7440-50-8 Lead ND ug/L 5.0 4.5 1 06/30/20 00:35 07/01/20 04:06 7439-92-1 Nickel ND ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 04:06 7440-02-0 Selenium ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 04:06 7782-49-2 Silver ND ug/L 5.0 2.5 1 06/30/20 00:35 07/01/20 04:06 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 06/30/20 00:35 07/01/20 04:06 7440-62-2 Zinc 9.7.1 ug/L 10.0 9.5 1 06/30/20 00:35 07/01/20 04:06 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.069J ug/L 0.10 0.050 1 06/30/20 00:13 06/30/20 16:21 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/02/20 06:00 67-64-1 Acetonitrile ND ug/L 50.0 30.4 1 07/02/20 06:00 75-05-8 Acrolein ND ug/L 10.0 2.7 1 07/02/20 06:00 107-02-8 Acrylonitrile ND ug/L 10.0 0.90 1 07/02/20 06:00 107-13-1 Allyl chloride ND ug/L 2.0 0.28 1 07/02/20 06:00 107-05-1 Benzene ND ug/L 1.0 0.15 1 07/02/20 06:00 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/02/20 06:00 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/02/20 06:00 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/02/20 06:00 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/02/20 06:00 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/02/20 06:00 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/02/20 06:00 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/02/20 06:00 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/02/20 06:00 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/02/20 06:00 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/02/20 06:00 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/02/20 06:00 74-87-3 Chloroprene ND ug/L 5.0 1.7 1 07/02/20 06:00 126-99-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/02/20 06:00 124-48-1 Dibromomethane ND ug/L 1.0 0.46 1 07/02/20 06:00 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/02/20 06:00 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/02/20 06:00 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/02/20 06:00 110-57-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. IH,L1, v1 v2 Page 12 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-1 Lab ID: 92483788002 Collected: 06/25/20 09:38 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Dichlorodifluoromethane ND ug/L 1.0 0.23 1 07/02/20 06:00 75-71-8 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/02/20 06:00 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/02/20 06:00 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/02/20 06:00 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.29 1 07/02/20 06:00 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.25 1 07/02/20 06:00 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.19 1 07/02/20 06:00 78-87-5 1,3-Dichloropropane ND ug/L 1.0 0.16 1 07/02/20 06:00 142-28-9 2,2-Dichloropropane ND ug/L 1.0 0.27 1 07/02/20 06:00 594-20-7 1,1-Dichloropropene ND ug/L 1.0 0.21 1 07/02/20 06:00 563-58-6 cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 07/02/20 06:00 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 07/02/20 06:00 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 07/02/20 06:00 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 07/02/20 06:00 100-41-4 Ethyl methacrylate ND ug/L 1.0 0.51 1 07/02/20 06:00 97-63-2 Hexachloro-1,3-butadiene ND ug/L 1.0 0.44 1 07/02/20 06:00 87-68-3 2-Hexanone ND ug/L 5.0 0.57 1 07/02/20 06:00 591-78-6 lodomethane ND ug/L 20.0 12.5 1 07/02/20 06:00 74-88-4 Isobutanol ND ug/L 100 66.4 1 07/02/20 06:00 78-83-1 Methacrylonitrile ND ug/L 10.0 1.9 1 07/02/20 06:00 126-98-7 Methylene Chloride ND ug/L 5.0 3.7 1 07/02/20 06:00 75-09-2 Methyl methacrylate ND ug/L 2.0 0.46 1 07/02/20 06:00 80-62-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 07/02/20 06:00 108-10-1 Naphthalene ND ug/L 1.0 0.35 1 07/02/20 06:00 91-20-3 Propionitrile ND ug/L 20.0 1.8 1 07/02/20 06:00 107-12-0 Styrene ND ug/L 1.0 0.27 1 07/02/20 06:00 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 07/02/20 06:00 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 07/02/20 06:00 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 07/02/20 06:00 127-18-4 Toluene ND ug/L 1.0 0.24 1 07/02/20 06:00 108-88-3 1,2,3-Trichlorobenzene ND ug/L 1.0 0.34 1 07/02/20 06:00 87-61-6 1,2,4-Trichlorobenzene ND ug/L 1.0 0.22 1 07/02/20 06:00 120-82-1 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 07/02/20 06:00 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 07/02/20 06:00 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 07/02/20 06:00 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 07/02/20 06:00 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 07/02/20 06:00 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 07/02/20 06:00 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 07/02/20 06:00 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 07/02/20 06:00 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 95 % 70-130 1 07/02/20 06:00 460-00-4 1,2-Dichloroethane-d4 (S) 91 % 70-130 1 07/02/20 06:00 17060-07-0 Toluene-d8 (S) 99 % 70-130 1 07/02/20 06:00 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-3R Lab ID: 92483788003 Collected: 06/25/20 08:49 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 06/30/20 00:35 07/01/20 04:09 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 04:09 7440-38-2 Barium 7.6 ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 04:09 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 06/30/20 00:35 07/01/20 04:09 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 06/30/20 00:35 07/01/20 04:09 7440-43-9 Chromium ND ug/L 5.0 3.7 1 06/30/20 00:35 07/01/20 04:09 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 06/30/20 00:35 07/01/20 04:09 7440-48-4 Copper ND ug/L 5.0 4.3 1 06/30/20 00:35 07/01/20 04:09 7440-50-8 Lead ND ug/L 5.0 4.5 1 06/30/20 00:35 07/01/20 04:09 7439-92-1 Nickel ND ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 04:09 7440-02-0 Selenium ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 04:09 7782-49-2 Silver ND ug/L 5.0 2.5 1 06/30/20 00:35 07/01/20 04:09 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 06/30/20 00:35 07/01/20 04:09 7440-62-2 Zinc ND ug/L 10.0 9.5 1 06/30/20 00:35 07/01/20 04:09 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 06/30/20 00:13 06/30/20 16:24 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/02/20 08:26 67-64-1 Acetonitrile ND ug/L 50.0 30.4 1 07/02/20 08:26 75-05-8 Acrolein ND ug/L 10.0 2.7 1 07/02/20 08:26 107-02-8 Acrylonitrile ND ug/L 10.0 0.90 1 07/02/20 08:26 107-13-1 Allyl chloride ND ug/L 2.0 0.28 1 07/02/20 08:26 107-05-1 Benzene ND ug/L 1.0 0.15 1 07/02/20 08:26 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/02/20 08:26 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/02/20 08:26 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/02/20 08:26 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/02/20 08:26 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/02/20 08:26 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/02/20 08:26 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/02/20 08:26 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/02/20 08:26 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/02/20 08:26 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/02/20 08:26 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/02/20 08:26 74-87-3 Chloroprene ND ug/L 5.0 1.7 1 07/02/20 08:26 126-99-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/02/20 08:26 124-48-1 Dibromomethane ND ug/L 1.0 0.46 1 07/02/20 08:26 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/02/20 08:26 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/02/20 08:26 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/02/20 08:26 110-57-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. IH,L1, v1 v2 Page 14 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-3R Lab ID: 92483788003 Collected: 06/25/20 08:49 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Dichlorodifluoromethane ND ug/L 1.0 0.23 1 07/02/20 08:26 75-71-8 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/02/20 08:26 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/02/20 08:26 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/02/20 08:26 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.29 1 07/02/20 08:26 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.25 1 07/02/20 08:26 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.19 1 07/02/20 08:26 78-87-5 1,3-Dichloropropane ND ug/L 1.0 0.16 1 07/02/20 08:26 142-28-9 2,2-Dichloropropane ND ug/L 1.0 0.27 1 07/02/20 08:26 594-20-7 1,1-Dichloropropene ND ug/L 1.0 0.21 1 07/02/20 08:26 563-58-6 cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 07/02/20 08:26 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 07/02/20 08:26 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 07/02/20 08:26 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 07/02/20 08:26 100-41-4 Ethyl methacrylate ND ug/L 1.0 0.51 1 07/02/20 08:26 97-63-2 Hexachloro-1,3-butadiene ND ug/L 1.0 0.44 1 07/02/20 08:26 87-68-3 2-Hexanone ND ug/L 5.0 0.57 1 07/02/20 08:26 591-78-6 lodomethane ND ug/L 20.0 12.5 1 07/02/20 08:26 74-88-4 Isobutanol ND ug/L 100 66.4 1 07/02/20 08:26 78-83-1 Methacrylonitrile ND ug/L 10.0 1.9 1 07/02/20 08:26 126-98-7 Methylene Chloride ND ug/L 5.0 3.7 1 07/02/20 08:26 75-09-2 Methyl methacrylate ND ug/L 2.0 0.46 1 07/02/20 08:26 80-62-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 07/02/20 08:26 108-10-1 Naphthalene ND ug/L 1.0 0.35 1 07/02/20 08:26 91-20-3 Propionitrile ND ug/L 20.0 1.8 1 07/02/20 08:26 107-12-0 Styrene ND ug/L 1.0 0.27 1 07/02/20 08:26 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 07/02/20 08:26 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 07/02/20 08:26 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 07/02/20 08:26 127-18-4 Toluene ND ug/L 1.0 0.24 1 07/02/20 08:26 108-88-3 1,2,3-Trichlorobenzene ND ug/L 1.0 0.34 1 07/02/20 08:26 87-61-6 1,2,4-Trichlorobenzene ND ug/L 1.0 0.22 1 07/02/20 08:26 120-82-1 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 07/02/20 08:26 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 07/02/20 08:26 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 07/02/20 08:26 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 07/02/20 08:26 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 07/02/20 08:26 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 07/02/20 08:26 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 07/02/20 08:26 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 07/02/20 08:26 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 95 % 70-130 1 07/02/20 08:26 460-00-4 1,2-Dichloroethane-d4 (S) 90 % 70-130 1 07/02/20 08:26 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 07/02/20 08:26 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-4S Lab ID: 92483788004 Collected: 06/25/20 08:44 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 06/30/20 00:35 07/01/20 04:13 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 04:13 7440-38-2 Barium 41.1 ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 04:13 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 06/30/20 00:35 07/01/20 04:13 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 06/30/20 00:35 07/01/20 04:13 7440-43-9 Chromium ND ug/L 5.0 3.7 1 06/30/20 00:35 07/01/20 04:13 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 06/30/20 00:35 07/01/20 04:13 7440-48-4 Copper ND ug/L 5.0 4.3 1 06/30/20 00:35 07/01/20 04:13 7440-50-8 Lead ND ug/L 5.0 4.5 1 06/30/20 00:35 07/01/20 04:13 7439-92-1 Nickel ND ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 04:13 7440-02-0 Selenium ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 04:13 7782-49-2 Silver ND ug/L 5.0 2.5 1 06/30/20 00:35 07/01/20 04:13 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 06/30/20 00:35 07/01/20 04:13 7440-62-2 Zinc ND ug/L 10.0 9.5 1 06/30/20 00:35 07/01/20 04:13 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 06/30/20 00:13 06/30/20 16:40 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/02/20 06:18 67-64-1 Acetonitrile ND ug/L 50.0 30.4 1 07/02/20 06:18 75-05-8 Acrolein ND ug/L 10.0 2.7 1 07/02/20 06:18 107-02-8 Acrylonitrile ND ug/L 10.0 0.90 1 07/02/20 06:18 107-13-1 Allyl chloride ND ug/L 2.0 0.28 1 07/02/20 06:18 107-05-1 Benzene ND ug/L 1.0 0.15 1 07/02/20 06:18 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/02/20 06:18 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/02/20 06:18 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/02/20 06:18 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/02/20 06:18 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/02/20 06:18 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/02/20 06:18 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/02/20 06:18 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/02/20 06:18 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/02/20 06:18 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/02/20 06:18 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/02/20 06:18 74-87-3 Chloroprene ND ug/L 5.0 1.7 1 07/02/20 06:18 126-99-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/02/20 06:18 124-48-1 Dibromomethane ND ug/L 1.0 0.46 1 07/02/20 06:18 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/02/20 06:18 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/02/20 06:18 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/02/20 06:18 110-57-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. IH,L1, v1 v2 Page 16 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-4S Lab ID: 92483788004 Collected: 06/25/20 08:44 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Dichlorodifluoromethane ND ug/L 1.0 0.23 1 07/02/20 06:18 75-71-8 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/02/20 06:18 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/02/20 06:18 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/02/20 06:18 75-35-4 cis-1,2-Dichloroethene 0.60J ug/L 1.0 0.29 1 07/02/20 06:18 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.25 1 07/02/20 06:18 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.19 1 07/02/20 06:18 78-87-5 1,3-Dichloropropane ND ug/L 1.0 0.16 1 07/02/20 06:18 142-28-9 2,2-Dichloropropane ND ug/L 1.0 0.27 1 07/02/20 06:18 594-20-7 1,1-Dichloropropene ND ug/L 1.0 0.21 1 07/02/20 06:18 563-58-6 cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 07/02/20 06:18 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 07/02/20 06:18 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 07/02/20 06:18 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 07/02/20 06:18 100-41-4 Ethyl methacrylate ND ug/L 1.0 0.51 1 07/02/20 06:18 97-63-2 Hexachloro-1,3-butadiene ND ug/L 1.0 0.44 1 07/02/20 06:18 87-68-3 2-Hexanone ND ug/L 5.0 0.57 1 07/02/20 06:18 591-78-6 lodomethane ND ug/L 20.0 12.5 1 07/02/20 06:18 74-88-4 Isobutanol ND ug/L 100 66.4 1 07/02/20 06:18 78-83-1 Methacrylonitrile ND ug/L 10.0 1.9 1 07/02/20 06:18 126-98-7 Methylene Chloride ND ug/L 5.0 3.7 1 07/02/20 06:18 75-09-2 Methyl methacrylate ND ug/L 2.0 0.46 1 07/02/20 06:18 80-62-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 07/02/20 06:18 108-10-1 Naphthalene ND ug/L 1.0 0.35 1 07/02/20 06:18 91-20-3 Propionitrile ND ug/L 20.0 1.8 1 07/02/20 06:18 107-12-0 Styrene ND ug/L 1.0 0.27 1 07/02/20 06:18 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 07/02/20 06:18 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 07/02/20 06:18 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 07/02/20 06:18 127-18-4 Toluene ND ug/L 1.0 0.24 1 07/02/20 06:18 108-88-3 1,2,3-Trichlorobenzene ND ug/L 1.0 0.34 1 07/02/20 06:18 87-61-6 1,2,4-Trichlorobenzene ND ug/L 1.0 0.22 1 07/02/20 06:18 120-82-1 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 07/02/20 06:18 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 07/02/20 06:18 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 07/02/20 06:18 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 07/02/20 06:18 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 07/02/20 06:18 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 07/02/20 06:18 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 07/02/20 06:18 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 07/02/20 06:18 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 95 % 70-130 1 07/02/20 06:18 460-00-4 1,2-Dichloroethane-d4 (S) 90 % 70-130 1 07/02/20 06:18 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 07/02/20 06:18 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-41) Lab ID: 92483788005 Collected: 06/25/20 08:46 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 06/30/20 00:35 07/01/20 04:22 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 04:22 7440-38-2 Barium 45.6 ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 04:22 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 06/30/20 00:35 07/01/20 04:22 7440-41-7 Cadmium 0.63J ug/L 1.0 0.40 1 06/30/20 00:35 07/01/20 04:22 7440-43-9 Chromium ND ug/L 5.0 3.7 1 06/30/20 00:35 07/01/20 04:22 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 06/30/20 00:35 07/01/20 04:22 7440-48-4 Copper ND ug/L 5.0 4.3 1 06/30/20 00:35 07/01/20 04:22 7440-50-8 Lead ND ug/L 5.0 4.5 1 06/30/20 00:35 07/01/20 04:22 7439-92-1 Nickel ND ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 04:22 7440-02-0 Selenium ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 04:22 7782-49-2 Silver ND ug/L 5.0 2.5 1 06/30/20 00:35 07/01/20 04:22 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 06/30/20 00:35 07/01/20 04:22 7440-62-2 Zinc ND ug/L 10.0 9.5 1 06/30/20 00:35 07/01/20 04:22 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 06/30/20 00:13 06/30/20 16:43 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/02/20 06:54 67-64-1 Acetonitrile ND ug/L 50.0 30.4 1 07/02/20 06:54 75-05-8 Acrolein ND ug/L 10.0 2.7 1 07/02/20 06:54 107-02-8 Acrylonitrile ND ug/L 10.0 0.90 1 07/02/20 06:54 107-13-1 Allyl chloride ND ug/L 2.0 0.28 1 07/02/20 06:54 107-05-1 Benzene ND ug/L 1.0 0.15 1 07/02/20 06:54 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/02/20 06:54 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/02/20 06:54 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/02/20 06:54 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/02/20 06:54 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/02/20 06:54 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/02/20 06:54 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/02/20 06:54 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/02/20 06:54 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/02/20 06:54 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/02/20 06:54 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/02/20 06:54 74-87-3 Chloroprene ND ug/L 5.0 1.7 1 07/02/20 06:54 126-99-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/02/20 06:54 124-48-1 Dibromomethane ND ug/L 1.0 0.46 1 07/02/20 06:54 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/02/20 06:54 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/02/20 06:54 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/02/20 06:54 110-57-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. IH,L1, v1 v2 Page 18 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-41) Lab ID: 92483788005 Collected: 06/25/20 08:46 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Dichlorodifluoromethane ND ug/L 1.0 0.23 1 07/02/20 06:54 75-71-8 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/02/20 06:54 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/02/20 06:54 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/02/20 06:54 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.29 1 07/02/20 06:54 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.25 1 07/02/20 06:54 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.19 1 07/02/20 06:54 78-87-5 1,3-Dichloropropane ND ug/L 1.0 0.16 1 07/02/20 06:54 142-28-9 2,2-Dichloropropane ND ug/L 1.0 0.27 1 07/02/20 06:54 594-20-7 1,1-Dichloropropene ND ug/L 1.0 0.21 1 07/02/20 06:54 563-58-6 cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 07/02/20 06:54 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 07/02/20 06:54 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 07/02/20 06:54 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 07/02/20 06:54 100-41-4 Ethyl methacrylate ND ug/L 1.0 0.51 1 07/02/20 06:54 97-63-2 Hexachloro-1,3-butadiene ND ug/L 1.0 0.44 1 07/02/20 06:54 87-68-3 2-Hexanone ND ug/L 5.0 0.57 1 07/02/20 06:54 591-78-6 lodomethane ND ug/L 20.0 12.5 1 07/02/20 06:54 74-88-4 Isobutanol ND ug/L 100 66.4 1 07/02/20 06:54 78-83-1 Methacrylonitrile ND ug/L 10.0 1.9 1 07/02/20 06:54 126-98-7 Methylene Chloride ND ug/L 5.0 3.7 1 07/02/20 06:54 75-09-2 Methyl methacrylate ND ug/L 2.0 0.46 1 07/02/20 06:54 80-62-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 07/02/20 06:54 108-10-1 Naphthalene ND ug/L 1.0 0.35 1 07/02/20 06:54 91-20-3 Propionitrile ND ug/L 20.0 1.8 1 07/02/20 06:54 107-12-0 Styrene ND ug/L 1.0 0.27 1 07/02/20 06:54 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 07/02/20 06:54 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 07/02/20 06:54 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 07/02/20 06:54 127-18-4 Toluene ND ug/L 1.0 0.24 1 07/02/20 06:54 108-88-3 1,2,3-Trichlorobenzene ND ug/L 1.0 0.34 1 07/02/20 06:54 87-61-6 1,2,4-Trichlorobenzene ND ug/L 1.0 0.22 1 07/02/20 06:54 120-82-1 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 07/02/20 06:54 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 07/02/20 06:54 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 07/02/20 06:54 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 07/02/20 06:54 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 07/02/20 06:54 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 07/02/20 06:54 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 07/02/20 06:54 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 07/02/20 06:54 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 93 % 70-130 1 07/02/20 06:54 460-00-4 1,2-Dichloroethane-d4 (S) 89 % 70-130 1 07/02/20 06:54 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 07/02/20 06:54 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-5 Lab ID: 92483788006 Collected: 06/25/20 08:55 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 06/30/20 00:35 07/01/20 04:25 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 04:25 7440-38-2 Barium 63.5 ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 04:25 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 06/30/20 00:35 07/01/20 04:25 7440-41-7 Cadmium 1.9 ug/L 1.0 0.40 1 06/30/20 00:35 07/01/20 04:25 7440-43-9 Chromium ND ug/L 5.0 3.7 1 06/30/20 00:35 07/01/20 04:25 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 06/30/20 00:35 07/01/20 04:25 7440-48-4 Copper ND ug/L 5.0 4.3 1 06/30/20 00:35 07/01/20 04:25 7440-50-8 Lead ND ug/L 5.0 4.5 1 06/30/20 00:35 07/01/20 04:25 7439-92-1 Nickel ND ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 04:25 7440-02-0 Selenium ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 04:25 7782-49-2 Silver ND ug/L 5.0 2.5 1 06/30/20 00:35 07/01/20 04:25 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 06/30/20 00:35 07/01/20 04:25 7440-62-2 Zinc ND ug/L 10.0 9.5 1 06/30/20 00:35 07/01/20 04:25 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.11 ug/L 0.10 0.050 1 06/30/20 00:13 06/30/20 16:47 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/02/20 03:24 67-64-1 Acetonitrile ND ug/L 50.0 30.4 1 07/02/20 03:24 75-05-8 Acrolein ND ug/L 10.0 2.7 1 07/02/20 03:24 107-02-8 Acrylonitrile ND ug/L 10.0 0.90 1 07/02/20 03:24 107-13-1 Allyl chloride ND ug/L 2.0 0.28 1 07/02/20 03:24 107-05-1 Benzene 0.57J ug/L 1.0 0.15 1 07/02/20 03:24 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/02/20 03:24 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/02/20 03:24 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/02/20 03:24 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/02/20 03:24 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/02/20 03:24 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/02/20 03:24 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/02/20 03:24 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/02/20 03:24 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/02/20 03:24 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/02/20 03:24 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/02/20 03:24 74-87-3 Chloroprene ND ug/L 5.0 1.7 1 07/02/20 03:24 126-99-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/02/20 03:24 124-48-1 Dibromomethane ND ug/L 1.0 0.46 1 07/02/20 03:24 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/02/20 03:24 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/02/20 03:24 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/02/20 03:24 110-57-6 Dichlorodifluoromethane ND ug/L 1.0 0.23 1 07/02/20 03:24 75-71-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. v1 I.,Rva v2 v2 IK Page 20 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-5 Lab ID: 92483788006 Collected: 06/25/20 08:55 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene Ethyl methacrylate Hexachloro-1,3-butadiene 2-Hexanone lodomethane Isobutanol Methacrylonitrile Methylene Chloride Methyl methacrylate 4-Methyl-2-pentanone (MIBK) Naphthalene Propionitrile Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/10/2020 04:55 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.27 1 07/02/20 03:24 75-34-3 ND ug/L 1.0 0.34 1 07/02/20 03:24 107-06-2 ND ug/L 1.0 0.24 1 07/02/20 03:24 75-35-4 2.3 ug/L 1.0 0.29 1 07/02/20 03:24 156-59-2 0.64J ug/L 1.0 0.25 1 07/02/20 03:24 156-60-5 ND ug/L 1.0 0.19 1 07/02/20 03:24 78-87-5 ND ug/L 1.0 0.16 1 07/02/20 03:24 142-28-9 ND ug/L 1.0 0.27 1 07/02/20 03:24 594-20-7 ND ug/L 1.0 0.21 1 07/02/20 03:24 563-58-6 ND ug/L 1.0 0.30 1 07/02/20 03:24 10061-01-5 ND ug/L 1.0 0.31 1 07/02/20 03:24 10061-02-6 ND ug/L 150 56.2 1 07/02/20 03:24 123-91-1 ND ug/L 1.0 0.26 1 07/02/20 03:24 100-41-4 ND ug/L 1.0 0.51 1 07/02/20 03:24 97-63-2 ND ug/L 1.0 0.44 1 07/02/20 03:24 87-68-3 ND ug/L 5.0 0.57 1 07/02/20 03:24 591-78-6 v1 ND ug/L 20.0 12.5 1 07/02/20 03:24 74-88-4 ND ug/L 100 66.4 1 07/02/20 03:24 78-83-1 ND ug/L 10.0 1.9 1 07/02/20 03:24 126-98-7 ND ug/L 5.0 3.7 1 07/02/20 03:24 75-09-2 ND ug/L 2.0 0.46 1 07/02/20 03:24 80-62-6 ND ug/L 5.0 4.5 1 07/02/20 03:24 108-10-1 ND ug/L 1.0 0.35 1 07/02/20 03:24 91-20-3 ND ug/L 20.0 1.8 1 07/02/20 03:24 107-12-0 ND ug/L 1.0 0.27 1 07/02/20 03:24 100-42-5 ND ug/L 1.0 0.34 1 07/02/20 03:24 630-20-6 ND ug/L 1.0 0.22 1 07/02/20 03:24 79-34-5 ND ug/L 1.0 0.16 1 07/02/20 03:24 127-18-4 ND ug/L 1.0 0.24 1 07/02/20 03:24 108-88-3 ND ug/L 1.0 0.34 1 07/02/20 03:24 87-61-6 ND ug/L 1.0 0.22 1 07/02/20 03:24 120-82-1 ND ug/L 1.0 0.18 1 07/02/20 03:24 71-55-6 ND ug/L 1.0 0.24 1 07/02/20 03:24 79-00-5 ND ug/L 1.0 0.22 1 07/02/20 03:24 79-01-6 ND ug/L 1.0 0.31 1 07/02/20 03:24 75-69-4 v2 ND ug/L 1.0 0.35 1 07/02/20 03:24 96-18-4 ND ug/L 2.0 1.4 1 07/02/20 03:24 108-05-4 ND ug/L 1.0 0.24 1 07/02/20 03:24 75-01-4 ND ug/L 1.0 0.63 1 07/02/20 03:24 1330-20-7 95 % 70-130 1 07/02/20 03:24 460-00-4 109 % 70-130 1 07/02/20 03:24 17060-07-0 98 % 70-130 1 07/02/20 03:24 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-8 Lab ID: 92483788007 Collected: 06/24/20 14:36 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 06/30/20 00:35 07/01/20 04:29 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 04:29 7440-38-2 Barium 67.2 ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 04:29 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 06/30/20 00:35 07/01/20 04:29 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 06/30/20 00:35 07/01/20 04:29 7440-43-9 Chromium ND ug/L 5.0 3.7 1 06/30/20 00:35 07/01/20 04:29 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 06/30/20 00:35 07/01/20 04:29 7440-48-4 Copper ND ug/L 5.0 4.3 1 06/30/20 00:35 07/01/20 04:29 7440-50-8 Lead ND ug/L 5.0 4.5 1 06/30/20 00:35 07/01/20 04:29 7439-92-1 Nickel ND ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 04:29 7440-02-0 Selenium ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 04:29 7782-49-2 Silver ND ug/L 5.0 2.5 1 06/30/20 00:35 07/01/20 04:29 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 06/30/20 00:35 07/01/20 04:29 7440-62-2 Zinc ND ug/L 10.0 9.5 1 06/30/20 00:35 07/01/20 04:29 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 06/30/20 00:13 06/30/20 16:51 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/01/20 09:55 67-64-1 Acetonitrile ND ug/L 50.0 30.4 1 07/01/20 09:55 75-05-8 Acrolein ND ug/L 10.0 2.7 1 07/01/20 09:55 107-02-8 Acrylonitrile ND ug/L 10.0 0.90 1 07/01/20 09:55 107-13-1 Allyl chloride ND ug/L 2.0 0.28 1 07/01/20 09:55 107-05-1 Benzene ND ug/L 1.0 0.15 1 07/01/20 09:55 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/01/20 09:55 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/01/20 09:55 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/01/20 09:55 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/01/20 09:55 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/01/20 09:55 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/01/20 09:55 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/01/20 09:55 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/01/20 09:55 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/01/20 09:55 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/01/20 09:55 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/01/20 09:55 74-87-3 Chloroprene ND ug/L 5.0 1.7 1 07/01/20 09:55 126-99-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/01/20 09:55 124-48-1 Dibromomethane ND ug/L 1.0 0.46 1 07/01/20 09:55 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/01/20 09:55 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/01/20 09:55 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/01/20 09:55 110-57-6 Dichlorodifluoromethane ND ug/L 1.0 0.23 1 07/01/20 09:55 75-71-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. IK v2 Page 22 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-8 Lab ID: 92483788007 Collected: 06/24/20 14:36 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene Ethyl methacrylate Hexachloro-1,3-butadiene 2-Hexanone lodomethane Isobutanol Methacrylonitrile Methylene Chloride Methyl methacrylate 4-Methyl-2-pentanone (MIBK) Naphthalene Propionitrile Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/10/2020 04:55 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.27 1 07/01/20 09:55 75-34-3 ND ug/L 1.0 0.34 1 07/01/20 09:55 107-06-2 ND ug/L 1.0 0.24 1 07/01/20 09:55 75-35-4 ND ug/L 1.0 0.29 1 07/01/20 09:55 156-59-2 ND ug/L 1.0 0.25 1 07/01/20 09:55 156-60-5 ND ug/L 1.0 0.19 1 07/01/20 09:55 78-87-5 ND ug/L 1.0 0.16 1 07/01/20 09:55 142-28-9 ND ug/L 1.0 0.27 1 07/01/20 09:55 594-20-7 ND ug/L 1.0 0.21 1 07/01/20 09:55 563-58-6 ND ug/L 1.0 0.30 1 07/01/20 09:55 10061-01-5 ND ug/L 1.0 0.31 1 07/01/20 09:55 10061-02-6 ND ug/L 150 56.2 1 07/01/20 09:55 123-91-1 ND ug/L 1.0 0.26 1 07/01/20 09:55 100-41-4 ND ug/L 1.0 0.51 1 07/01/20 09:55 97-63-2 ND ug/L 1.0 0.44 1 07/01/20 09:55 87-68-3 ND ug/L 5.0 0.57 1 07/01/20 09:55 591-78-6 ND ug/L 20.0 12.5 1 07/01/20 09:55 74-88-4 ND ug/L 100 66.4 1 07/01/20 09:55 78-83-1 v2 ND ug/L 10.0 1.9 1 07/01/20 09:55 126-98-7 ND ug/L 5.0 3.7 1 07/01/20 09:55 75-09-2 ND ug/L 2.0 0.46 1 07/01/20 09:55 80-62-6 ND ug/L 5.0 4.5 1 07/01/20 09:55 108-10-1 ND ug/L 1.0 0.35 1 07/01/20 09:55 91-20-3 ND ug/L 20.0 1.8 1 07/01/20 09:55 107-12-0 ND ug/L 1.0 0.27 1 07/01/20 09:55 100-42-5 ND ug/L 1.0 0.34 1 07/01/20 09:55 630-20-6 ND ug/L 1.0 0.22 1 07/01/20 09:55 79-34-5 ND ug/L 1.0 0.16 1 07/01/20 09:55 127-18-4 ND ug/L 1.0 0.24 1 07/01/20 09:55 108-88-3 ND ug/L 1.0 0.34 1 07/01/20 09:55 87-61-6 ND ug/L 1.0 0.22 1 07/01/20 09:55 120-82-1 ND ug/L 1.0 0.18 1 07/01/20 09:55 71-55-6 ND ug/L 1.0 0.24 1 07/01/20 09:55 79-00-5 ND ug/L 1.0 0.22 1 07/01/20 09:55 79-01-6 ND ug/L 1.0 0.31 1 07/01/20 09:55 75-69-4 ND ug/L 1.0 0.35 1 07/01/20 09:55 96-18-4 ND ug/L 2.0 1.4 1 07/01/20 09:55 108-05-4 ND ug/L 1.0 0.24 1 07/01/20 09:55 75-01-4 ND ug/L 1.0 0.63 1 07/01/20 09:55 1330-20-7 97 % 70-130 1 07/01/20 09:55 460-00-4 101 % 70-130 1 07/01/20 09:55 17060-07-0 96 % 70-130 1 07/01/20 09:55 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-91) Lab ID: 92483788008 Collected: 06/23/20 16:02 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 06/30/20 00:35 07/01/20 04:32 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 04:32 7440-38-2 Barium 49.4 ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 04:32 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 06/30/20 00:35 07/01/20 04:32 7440-41-7 Cadmium 1.5 ug/L 1.0 0.40 1 06/30/20 00:35 07/01/20 04:32 7440-43-9 Chromium ND ug/L 5.0 3.7 1 06/30/20 00:35 07/01/20 04:32 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 06/30/20 00:35 07/01/20 04:32 7440-48-4 Copper ND ug/L 5.0 4.3 1 06/30/20 00:35 07/01/20 04:32 7440-50-8 Lead ND ug/L 5.0 4.5 1 06/30/20 00:35 07/01/20 04:32 7439-92-1 Nickel ND ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 04:32 7440-02-0 Selenium ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 04:32 7782-49-2 Silver ND ug/L 5.0 2.5 1 06/30/20 00:35 07/01/20 04:32 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 06/30/20 00:35 07/01/20 04:32 7440-62-2 Zinc ND ug/L 10.0 9.5 1 06/30/20 00:35 07/01/20 04:32 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 06/30/20 00:13 06/30/20 16:55 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/01/20 03:05 67-64-1 Acetonitrile ND ug/L 50.0 30.4 1 07/01/20 03:05 75-05-8 Acrolein ND ug/L 10.0 2.7 1 07/01/20 03:05 107-02-8 Acrylonitrile ND ug/L 10.0 0.90 1 07/01/20 03:05 107-13-1 Allyl chloride ND ug/L 2.0 0.28 1 07/01/20 03:05 107-05-1 Benzene ND ug/L 1.0 0.15 1 07/01/20 03:05 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/01/20 03:05 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/01/20 03:05 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/01/20 03:05 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/01/20 03:05 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/01/20 03:05 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/01/20 03:05 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/01/20 03:05 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/01/20 03:05 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/01/20 03:05 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/01/20 03:05 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/01/20 03:05 74-87-3 Chloroprene ND ug/L 5.0 1.7 1 07/01/20 03:05 126-99-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/01/20 03:05 124-48-1 Dibromomethane ND ug/L 1.0 0.46 1 07/01/20 03:05 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/01/20 03:05 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/01/20 03:05 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/01/20 03:05 110-57-6 Dichlorodifluoromethane ND ug/L 1.0 0.23 1 07/01/20 03:05 75-71-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. IH,v1 Page 24 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-91) Lab ID: 92483788008 Collected: 06/23/20 16:02 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/01/20 03:05 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/01/20 03:05 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/01/20 03:05 75-35-4 cis-1,2-Dichloroethene 0.61J ug/L 1.0 0.29 1 07/01/20 03:05 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.25 1 07/01/20 03:05 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.19 1 07/01/20 03:05 78-87-5 1,3-Dichloropropane ND ug/L 1.0 0.16 1 07/01/20 03:05 142-28-9 2,2-Dichloropropane ND ug/L 1.0 0.27 1 07/01/20 03:05 594-20-7 1,1-Dichloropropene ND ug/L 1.0 0.21 1 07/01/20 03:05 563-58-6 cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 07/01/20 03:05 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 07/01/20 03:05 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 07/01/20 03:05 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 07/01/20 03:05 100-41-4 Ethyl methacrylate ND ug/L 1.0 0.51 1 07/01/20 03:05 97-63-2 Hexachloro-1,3-butadiene ND ug/L 1.0 0.44 1 07/01/20 03:05 87-68-3 2-Hexanone ND ug/L 5.0 0.57 1 07/01/20 03:05 591-78-6 lodomethane ND ug/L 20.0 12.5 1 07/01/20 03:05 74-88-4 Isobutanol ND ug/L 100 66.4 1 07/01/20 03:05 78-83-1 Methacrylonitrile ND ug/L 10.0 1.9 1 07/01/20 03:05 126-98-7 Methylene Chloride ND ug/L 5.0 3.7 1 07/01/20 03:05 75-09-2 Methyl methacrylate ND ug/L 2.0 0.46 1 07/01/20 03:05 80-62-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 07/01/20 03:05 108-10-1 Naphthalene ND ug/L 1.0 0.35 1 07/01/20 03:05 91-20-3 Propionitrile ND ug/L 20.0 1.8 1 07/01/20 03:05 107-12-0 Styrene ND ug/L 1.0 0.27 1 07/01/20 03:05 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 07/01/20 03:05 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 07/01/20 03:05 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 07/01/20 03:05 127-18-4 Toluene ND ug/L 1.0 0.24 1 07/01/20 03:05 108-88-3 1,2,3-Trichlorobenzene ND ug/L 1.0 0.34 1 07/01/20 03:05 87-61-6 1,2,4-Trichlorobenzene ND ug/L 1.0 0.22 1 07/01/20 03:05 120-82-1 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 07/01/20 03:05 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 07/01/20 03:05 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 07/01/20 03:05 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 07/01/20 03:05 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 07/01/20 03:05 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 07/01/20 03:05 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 07/01/20 03:05 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 07/01/20 03:05 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 96 % 70-130 1 07/01/20 03:05 460-00-4 1,2-Dichloroethane-d4 (S) 90 % 70-130 1 07/01/20 03:05 17060-07-0 Toluene-d8 (S) 99 % 70-130 1 07/01/20 03:05 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-11S Lab ID: 92483788009 Collected: 06/24/20 14:15 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 06/30/20 00:35 07/01/20 04:35 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 04:35 7440-38-2 Barium 21.4 ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 04:35 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 06/30/20 00:35 07/01/20 04:35 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 06/30/20 00:35 07/01/20 04:35 7440-43-9 Chromium ND ug/L 5.0 3.7 1 06/30/20 00:35 07/01/20 04:35 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 06/30/20 00:35 07/01/20 04:35 7440-48-4 Copper ND ug/L 5.0 4.3 1 06/30/20 00:35 07/01/20 04:35 7440-50-8 Lead ND ug/L 5.0 4.5 1 06/30/20 00:35 07/01/20 04:35 7439-92-1 Nickel ND ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 04:35 7440-02-0 Selenium ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 04:35 7782-49-2 Silver ND ug/L 5.0 2.5 1 06/30/20 00:35 07/01/20 04:35 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 06/30/20 00:35 07/01/20 04:35 7440-62-2 Zinc ND ug/L 10.0 9.5 1 06/30/20 00:35 07/01/20 04:35 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 06/30/20 00:13 06/30/20 17:06 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/01/20 10:14 67-64-1 Acetonitrile ND ug/L 50.0 30.4 1 07/01/20 10:14 75-05-8 Acrolein ND ug/L 10.0 2.7 1 07/01/20 10:14 107-02-8 Acrylonitrile ND ug/L 10.0 0.90 1 07/01/20 10:14 107-13-1 Allyl chloride ND ug/L 2.0 0.28 1 07/01/20 10:14 107-05-1 Benzene 0.62J ug/L 1.0 0.15 1 07/01/20 10:14 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/01/20 10:14 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/01/20 10:14 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/01/20 10:14 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/01/20 10:14 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/01/20 10:14 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/01/20 10:14 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/01/20 10:14 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/01/20 10:14 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/01/20 10:14 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/01/20 10:14 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/01/20 10:14 74-87-3 Chloroprene ND ug/L 5.0 1.7 1 07/01/20 10:14 126-99-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/01/20 10:14 124-48-1 Dibromomethane ND ug/L 1.0 0.46 1 07/01/20 10:14 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/01/20 10:14 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/01/20 10:14 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/01/20 10:14 110-57-6 Dichlorodifluoromethane ND ug/L 1.0 0.23 1 07/01/20 10:14 75-71-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. IK v2 Page 26 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-11S Lab ID: 92483788009 Collected: 06/24/20 14:15 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene Ethyl methacrylate Hexachloro-1,3-butadiene 2-Hexanone lodomethane Isobutanol Methacrylonitrile Methylene Chloride Methyl methacrylate 4-Methyl-2-pentanone (MIBK) Naphthalene Propionitrile Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/10/2020 04:55 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.27 1 07/01/2010:14 75-34-3 ND ug/L 1.0 0.34 1 07/01/2010:14 107-06-2 ND ug/L 1.0 0.24 1 07/01/2010:14 75-35-4 0.63J ug/L 1.0 0.29 1 07/01 /20 10:14 156-59-2 0.70J ug/L 1.0 0.25 1 07/01 /20 10:14 156-60-5 ND ug/L 1.0 0.19 1 07/01/2010:14 78-87-5 ND ug/L 1.0 0.16 1 07/01/2010:14 142-28-9 ND ug/L 1.0 0.27 1 07/01/2010:14 594-20-7 ND ug/L 1.0 0.21 1 07/01/2010:14 563-58-6 ND ug/L 1.0 0.30 1 07/01 /20 10:14 10061-01-5 ND ug/L 1.0 0.31 1 07/01 /20 10:14 10061-02-6 ND ug/L 150 56.2 1 07/01/2010:14 123-91-1 ND ug/L 1.0 0.26 1 07/01 /20 10:14 100-41-4 ND ug/L 1.0 0.51 1 07/01/2010:14 97-63-2 ND ug/L 1.0 0.44 1 07/01/2010:14 87-68-3 ND ug/L 5.0 0.57 1 07/01 /20 10:14 591-78-6 ND ug/L 20.0 12.5 1 07/01/2010:14 74-88-4 ND ug/L 100 66.4 1 07/01/2010:14 78-83-1 v2 ND ug/L 10.0 1.9 1 07/01/2010:14 126-98-7 ND ug/L 5.0 3.7 1 07/01/2010:14 75-09-2 ND ug/L 2.0 0.46 1 07/01/2010:14 80-62-6 ND ug/L 5.0 4.5 1 07/01/2010:14 108-10-1 ND ug/L 1.0 0.35 1 07/01 /20 10:14 91-20-3 ND ug/L 20.0 1.8 1 07/01/2010:14 107-12-0 ND ug/L 1.0 0.27 1 07/01/2010:14 100-42-5 ND ug/L 1.0 0.34 1 07/01/2010:14 630-20-6 ND ug/L 1.0 0.22 1 07/01/2010:14 79-34-5 ND ug/L 1.0 0.16 1 07/01/2010:14 127-18-4 ND ug/L 1.0 0.24 1 07/01/2010:14 108-88-3 ND ug/L 1.0 0.34 1 07/01 /20 10:14 87-61-6 ND ug/L 1.0 0.22 1 07/01/2010:14 120-82-1 ND ug/L 1.0 0.18 1 07/01 /20 10:14 71-55-6 ND ug/L 1.0 0.24 1 07/01/2010:14 79-00-5 ND ug/L 1.0 0.22 1 07/01 /20 10:14 79-01-6 ND ug/L 1.0 0.31 1 07/01/2010:14 75-69-4 ND ug/L 1.0 0.35 1 07/01/2010:14 96-18-4 ND ug/L 2.0 1.4 1 07/01/2010:14 108-05-4 ND ug/L 1.0 0.24 1 07/01 /20 10:14 75-01-4 ND ug/L 1.0 0.63 1 07/01/2010:14 1330-20-7 97 % 70-130 1 07/01 /20 10:14 460-00-4 99 % 70-130 1 07/01 /20 10:14 17060-07-0 100 % 70-130 1 07/01 /20 10:14 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-11D Lab ID: 92483788010 Collected: 06/24/20 14:16 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony 6.2 ug/L 5.0 3.0 1 06/30/20 00:35 07/01/20 04:38 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 04:38 7440-38-2 Barium 48.3 ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 04:38 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 06/30/20 00:35 07/01/20 04:38 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 06/30/20 00:35 07/01/20 04:38 7440-43-9 Chromium ND ug/L 5.0 3.7 1 06/30/20 00:35 07/01/20 04:38 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 06/30/20 00:35 07/01/20 04:38 7440-48-4 Copper ND ug/L 5.0 4.3 1 06/30/20 00:35 07/01/20 04:38 7440-50-8 Lead ND ug/L 5.0 4.5 1 06/30/20 00:35 07/01/20 04:38 7439-92-1 Nickel ND ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 04:38 7440-02-0 Selenium ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 04:38 7782-49-2 Silver ND ug/L 5.0 2.5 1 06/30/20 00:35 07/01/20 04:38 7440-22-4 Vanadium 4.2.1 ug/L 5.0 3.9 1 06/30/20 00:35 07/01/20 04:38 7440-62-2 Zinc ND ug/L 10.0 9.5 1 06/30/20 00:35 07/01/20 04:38 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 06/30/20 00:13 06/30/20 17:10 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/01/20 10:32 67-64-1 Acetonitrile ND ug/L 50.0 30.4 1 07/01/20 10:32 75-05-8 Acrolein ND ug/L 10.0 2.7 1 07/01/20 10:32 107-02-8 Acrylonitrile ND ug/L 10.0 0.90 1 07/01/20 10:32 107-13-1 Allyl chloride ND ug/L 2.0 0.28 1 07/01/20 10:32 107-05-1 Benzene ND ug/L 1.0 0.15 1 07/01/20 10:32 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/01/20 10:32 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/01/20 10:32 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/01/20 10:32 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/01/20 10:32 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/01/20 10:32 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/01/20 10:32 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/01/20 10:32 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/01/20 10:32 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/01/20 10:32 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/01/20 10:32 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/01/20 10:32 74-87-3 Chloroprene ND ug/L 5.0 1.7 1 07/01/20 10:32 126-99-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/01/20 10:32 124-48-1 Dibromomethane ND ug/L 1.0 0.46 1 07/01/20 10:32 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/01/20 10:32 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/01/20 10:32 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/01/20 10:32 110-57-6 Dichlorodifluoromethane ND ug/L 1.0 0.23 1 07/01/20 10:32 75-71-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. IK v2 Page 28 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-11D Lab ID: 92483788010 Collected: 06/24/20 14:16 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene Ethyl methacrylate Hexachloro-1,3-butadiene 2-Hexanone lodomethane Isobutanol Methacrylonitrile Methylene Chloride Methyl methacrylate 4-Methyl-2-pentanone (MIBK) Naphthalene Propionitrile Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/10/2020 04:55 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.27 1 07/01/2010:32 75-34-3 ND ug/L 1.0 0.34 1 07/01/2010:32 107-06-2 ND ug/L 1.0 0.24 1 07/01/2010:32 75-35-4 ND ug/L 1.0 0.29 1 07/01/2010:32 156-59-2 ND ug/L 1.0 0.25 1 07/01/2010:32 156-60-5 ND ug/L 1.0 0.19 1 07/01/2010:32 78-87-5 ND ug/L 1.0 0.16 1 07/01/2010:32 142-28-9 ND ug/L 1.0 0.27 1 07/01/2010:32 594-20-7 ND ug/L 1.0 0.21 1 07/01/2010:32 563-58-6 ND ug/L 1.0 0.30 1 07/01 /20 10:32 10061-01-5 ND ug/L 1.0 0.31 1 07/01 /20 10:32 10061-02-6 ND ug/L 150 56.2 1 07/01/2010:32 123-91-1 ND ug/L 1.0 0.26 1 07/01 /20 10:32 100-41-4 ND ug/L 1.0 0.51 1 07/01/2010:32 97-63-2 ND ug/L 1.0 0.44 1 07/01/2010:32 87-68-3 ND ug/L 5.0 0.57 1 07/01 /20 10:32 591-78-6 ND ug/L 20.0 12.5 1 07/01/2010:32 74-88-4 ND ug/L 100 66.4 1 07/01/2010:32 78-83-1 v2 ND ug/L 10.0 1.9 1 07/01/2010:32 126-98-7 ND ug/L 5.0 3.7 1 07/01/2010:32 75-09-2 ND ug/L 2.0 0.46 1 07/01/2010:32 80-62-6 ND ug/L 5.0 4.5 1 07/01/2010:32 108-10-1 ND ug/L 1.0 0.35 1 07/01 /20 10:32 91-20-3 ND ug/L 20.0 1.8 1 07/01/2010:32 107-12-0 ND ug/L 1.0 0.27 1 07/01/2010:32 100-42-5 ND ug/L 1.0 0.34 1 07/01/2010:32 630-20-6 ND ug/L 1.0 0.22 1 07/01/2010:32 79-34-5 ND ug/L 1.0 0.16 1 07/01/2010:32 127-18-4 ND ug/L 1.0 0.24 1 07/01/2010:32 108-88-3 ND ug/L 1.0 0.34 1 07/01 /20 10:32 87-61-6 ND ug/L 1.0 0.22 1 07/01/2010:32 120-82-1 ND ug/L 1.0 0.18 1 07/01 /20 10:32 71-55-6 ND ug/L 1.0 0.24 1 07/01/2010:32 79-00-5 ND ug/L 1.0 0.22 1 07/01 /20 10:32 79-01-6 ND ug/L 1.0 0.31 1 07/01/2010:32 75-69-4 ND ug/L 1.0 0.35 1 07/01/2010:32 96-18-4 ND ug/L 2.0 1.4 1 07/01/2010:32 108-05-4 ND ug/L 1.0 0.24 1 07/01 /20 10:32 75-01-4 ND ug/L 1.0 0.63 1 07/01/2010:32 1330-20-7 96 % 70-130 1 07/01 /20 10:32 460-00-4 103 % 70-130 1 07/01 /20 10:32 17060-07-0 97 % 70-130 1 07/01 /20 10:32 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 29 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-12 Lab ID: 92483788011 Collected: 06/23/20 15:16 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 06/30/20 00:35 07/01/20 04:42 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 04:42 7440-38-2 Barium 14.4 ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 04:42 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 06/30/20 00:35 07/01/20 04:42 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 06/30/20 00:35 07/01/20 04:42 7440-43-9 Chromium ND ug/L 5.0 3.7 1 06/30/20 00:35 07/01/20 04:42 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 06/30/20 00:35 07/01/20 04:42 7440-48-4 Copper ND ug/L 5.0 4.3 1 06/30/20 00:35 07/01/20 04:42 7440-50-8 Lead ND ug/L 5.0 4.5 1 06/30/20 00:35 07/01/20 04:42 7439-92-1 Nickel ND ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 04:42 7440-02-0 Selenium ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 04:42 7782-49-2 Silver ND ug/L 5.0 2.5 1 06/30/20 00:35 07/01/20 04:42 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 06/30/20 00:35 07/01/20 04:42 7440-62-2 Zinc ND ug/L 10.0 9.5 1 06/30/20 00:35 07/01/20 04:42 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 06/30/20 00:13 06/30/20 17:14 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/01/20 03:24 67-64-1 Acetonitrile ND ug/L 50.0 30.4 1 07/01/20 03:24 75-05-8 Acrolein ND ug/L 10.0 2.7 1 07/01/20 03:24 107-02-8 Acrylonitrile ND ug/L 10.0 0.90 1 07/01/20 03:24 107-13-1 Allyl chloride ND ug/L 2.0 0.28 1 07/01/20 03:24 107-05-1 Benzene ND ug/L 1.0 0.15 1 07/01/20 03:24 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/01/20 03:24 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/01/20 03:24 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/01/20 03:24 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/01/20 03:24 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/01/20 03:24 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/01/20 03:24 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/01/20 03:24 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/01/20 03:24 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/01/20 03:24 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/01/20 03:24 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/01/20 03:24 74-87-3 Chloroprene ND ug/L 5.0 1.7 1 07/01/20 03:24 126-99-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/01/20 03:24 124-48-1 Dibromomethane ND ug/L 1.0 0.46 1 07/01/20 03:24 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/01/20 03:24 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/01/20 03:24 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/01/20 03:24 110-57-6 Dichlorodifluoromethane ND ug/L 1.0 0.23 1 07/01/20 03:24 75-71-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. IH,v1 Page 30 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-12 Lab ID: 92483788011 Collected: 06/23/20 15:16 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/01/20 03:24 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/01/20 03:24 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/01/20 03:24 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.29 1 07/01/20 03:24 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.25 1 07/01/20 03:24 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.19 1 07/01/20 03:24 78-87-5 1,3-Dichloropropane ND ug/L 1.0 0.16 1 07/01/20 03:24 142-28-9 2,2-Dichloropropane ND ug/L 1.0 0.27 1 07/01/20 03:24 594-20-7 1,1-Dichloropropene ND ug/L 1.0 0.21 1 07/01/20 03:24 563-58-6 cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 07/01/20 03:24 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 07/01/20 03:24 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 07/01/20 03:24 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 07/01/20 03:24 100-41-4 Ethyl methacrylate ND ug/L 1.0 0.51 1 07/01/20 03:24 97-63-2 Hexachloro-1,3-butadiene ND ug/L 1.0 0.44 1 07/01/20 03:24 87-68-3 2-Hexanone ND ug/L 5.0 0.57 1 07/01/20 03:24 591-78-6 lodomethane ND ug/L 20.0 12.5 1 07/01/20 03:24 74-88-4 Isobutanol ND ug/L 100 66.4 1 07/01/20 03:24 78-83-1 Methacrylonitrile ND ug/L 10.0 1.9 1 07/01/20 03:24 126-98-7 Methylene Chloride ND ug/L 5.0 3.7 1 07/01/20 03:24 75-09-2 Methyl methacrylate ND ug/L 2.0 0.46 1 07/01/20 03:24 80-62-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 07/01/20 03:24 108-10-1 Naphthalene ND ug/L 1.0 0.35 1 07/01/20 03:24 91-20-3 Propionitrile ND ug/L 20.0 1.8 1 07/01/20 03:24 107-12-0 Styrene ND ug/L 1.0 0.27 1 07/01/20 03:24 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 07/01/20 03:24 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 07/01/20 03:24 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 07/01/20 03:24 127-18-4 Toluene ND ug/L 1.0 0.24 1 07/01/20 03:24 108-88-3 1,2,3-Trichlorobenzene ND ug/L 1.0 0.34 1 07/01/20 03:24 87-61-6 1,2,4-Trichlorobenzene ND ug/L 1.0 0.22 1 07/01/20 03:24 120-82-1 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 07/01/20 03:24 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 07/01/20 03:24 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 07/01/20 03:24 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 07/01/20 03:24 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 07/01/20 03:24 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 07/01/20 03:24 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 07/01/20 03:24 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 07/01/20 03:24 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 94 % 70-130 1 07/01/20 03:24 460-00-4 1,2-Dichloroethane-d4 (S) 89 % 70-130 1 07/01/20 03:24 17060-07-0 Toluene-d8 (S) 99 % 70-130 1 07/01/20 03:24 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-13 Lab ID: 92483788012 Collected: 06/23/20 15:10 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 06/30/20 00:35 07/01/20 04:45 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 04:45 7440-38-2 Barium 36.4 ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 04:45 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 06/30/20 00:35 07/01/20 04:45 7440-41-7 Cadmium 1.9 ug/L 1.0 0.40 1 06/30/20 00:35 07/01/20 04:45 7440-43-9 Chromium ND ug/L 5.0 3.7 1 06/30/20 00:35 07/01/20 04:45 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 06/30/20 00:35 07/01/20 04:45 7440-48-4 Copper ND ug/L 5.0 4.3 1 06/30/20 00:35 07/01/20 04:45 7440-50-8 Lead ND ug/L 5.0 4.5 1 06/30/20 00:35 07/01/20 04:45 7439-92-1 Nickel ND ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 04:45 7440-02-0 Selenium ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 04:45 7782-49-2 Silver ND ug/L 5.0 2.5 1 06/30/20 00:35 07/01/20 04:45 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 06/30/20 00:35 07/01/20 04:45 7440-62-2 Zinc ND ug/L 10.0 9.5 1 06/30/20 00:35 07/01/20 04:45 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.15 ug/L 0.10 0.050 1 06/30/20 00:13 06/30/20 17:18 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/01/20 03:42 67-64-1 Acetonitrile ND ug/L 50.0 30.4 1 07/01/20 03:42 75-05-8 Acrolein ND ug/L 10.0 2.7 1 07/01/20 03:42 107-02-8 Acrylonitrile ND ug/L 10.0 0.90 1 07/01/20 03:42 107-13-1 Allyl chloride ND ug/L 2.0 0.28 1 07/01/20 03:42 107-05-1 Benzene ND ug/L 1.0 0.15 1 07/01/20 03:42 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/01/20 03:42 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/01/20 03:42 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/01/20 03:42 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/01/20 03:42 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/01/20 03:42 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/01/20 03:42 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/01/20 03:42 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/01/20 03:42 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/01/20 03:42 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/01/20 03:42 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/01/20 03:42 74-87-3 Chloroprene ND ug/L 5.0 1.7 1 07/01/20 03:42 126-99-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/01/20 03:42 124-48-1 Dibromomethane ND ug/L 1.0 0.46 1 07/01/20 03:42 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/01/20 03:42 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/01/20 03:42 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/01/20 03:42 110-57-6 Dichlorodifluoromethane ND ug/L 1.0 0.23 1 07/01/20 03:42 75-71-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. IH,v1 Page 32 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Sample: MW-13 Lab ID: 92483788012 Collected: 06/23/20 15:10 Received: 06/26/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/01/20 03:42 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/01/20 03:42 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/01/20 03:42 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.29 1 07/01/20 03:42 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.25 1 07/01/20 03:42 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.19 1 07/01/20 03:42 78-87-5 1,3-Dichloropropane ND ug/L 1.0 0.16 1 07/01/20 03:42 142-28-9 2,2-Dichloropropane ND ug/L 1.0 0.27 1 07/01/20 03:42 594-20-7 1,1-Dichloropropene ND ug/L 1.0 0.21 1 07/01/20 03:42 563-58-6 cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 07/01/20 03:42 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 07/01/20 03:42 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 07/01/20 03:42 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 07/01/20 03:42 100-41-4 Ethyl methacrylate ND ug/L 1.0 0.51 1 07/01/20 03:42 97-63-2 Hexachloro-1,3-butadiene ND ug/L 1.0 0.44 1 07/01/20 03:42 87-68-3 2-Hexanone ND ug/L 5.0 0.57 1 07/01/20 03:42 591-78-6 lodomethane ND ug/L 20.0 12.5 1 07/01/20 03:42 74-88-4 Isobutanol ND ug/L 100 66.4 1 07/01/20 03:42 78-83-1 Methacrylonitrile ND ug/L 10.0 1.9 1 07/01/20 03:42 126-98-7 Methylene Chloride ND ug/L 5.0 3.7 1 07/01/20 03:42 75-09-2 Methyl methacrylate ND ug/L 2.0 0.46 1 07/01/20 03:42 80-62-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 07/01/20 03:42 108-10-1 Naphthalene ND ug/L 1.0 0.35 1 07/01/20 03:42 91-20-3 Propionitrile ND ug/L 20.0 1.8 1 07/01/20 03:42 107-12-0 Styrene ND ug/L 1.0 0.27 1 07/01/20 03:42 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 07/01/20 03:42 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 07/01/20 03:42 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 07/01/20 03:42 127-18-4 Toluene ND ug/L 1.0 0.24 1 07/01/20 03:42 108-88-3 1,2,3-Trichlorobenzene ND ug/L 1.0 0.34 1 07/01/20 03:42 87-61-6 1,2,4-Trichlorobenzene ND ug/L 1.0 0.22 1 07/01/20 03:42 120-82-1 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 07/01/20 03:42 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 07/01/20 03:42 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 07/01/20 03:42 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 07/01/20 03:42 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 07/01/20 03:42 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 07/01/20 03:42 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 07/01/20 03:42 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 07/01/20 03:42 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 94 % 70-130 1 07/01/20 03:42 460-00-4 1,2-Dichloroethane-d4 (S) 90 % 70-130 1 07/01/20 03:42 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 07/01/20 03:42 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 QC Batch: 1501187 Analysis Method: EPA 8151 QC Batch Method: 8151A Analysis Description: Chlorinated Herb. (GC) 8151 Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92483788001 METHOD BLANK: R3545459-1 Associated Lab Samples: 92483788001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 2,4-D ug/L ND 2.00 0.547 07/01/2015:22 Dalapon ug/L ND 2.00 0.344 07/01/2015:22 2,4-DB ug/L ND 2.00 0.302 07/01/2015:22 Dicamba ug/L ND 2.00 0.245 07/01/2015:22 Dichloroprop ug/L ND 2.00 1.04 07/01/2015:22 Dinoseb ug/L ND 2.00 0.250 07/01/2015:22 MCPA ug/L ND 100 13.1 07/01/2015:22 MCPP ug/L ND 100 66.0 07/01/2015:22 2,4,5-T ug/L ND 2.00 0.258 07/01/2015:22 2,4,5-TP (Silvex) ug/L ND 2.00 0.335 07/01/20 15:22 2,4-DCAA (S) % 76.4 14.0-158 07/01 /20 15:22 Qualifiers LABORATORY CONTROL SAMPLE & LCSD: R3545459-2 R3545459-3 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 2,4-D ug/L 5.00 4.05 3.88 81.0 77.6 50.0-120 4.29 20 Dalapon ug/L 5.00 4.10 3.32 82.0 66.4 32.0-120 21.0 20 P9,R1 2,4-DB ug/L 5.00 4.26 4.11 85.2 82.2 53.0-140 3.58 20 Dicamba ug/L 5.00 4.01 3.89 80.2 77.8 51.0-120 3.04 20 Dichloroprop ug/L 5.00 4.33 4.22 86.6 84.4 55.0-127 2.57 20 Dinoseb ug/L 5.00 4.19 4.05 83.8 81.0 36.0-134 3.40 20 MCPA ug/L 50.0 113 99.5 226 199 10.0-160 12.7 40 E,L0,P9 MCPP ug/L 50.0 26.6 26.2 53.2 52.4 10.0-160 1.52 23 2,4,5-T ug/L 5.00 4.69 4.51 93.8 90.2 54.0-120 3.91 20 2,4,5-TP (Silvex) ug/L 5.00 3.67 4.22 73.4 84.4 50.0-125 13.9 20 2,4-DCAA (S) % 81.6 77.4 14.0-158 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 QC Batch: 550099 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92483788001 METHOD BLANK: 2925125 Matrix: Water Associated Lab Samples: 92483788001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.12 06/29/2015:50 LABORATORY CONTROL SAMPLE: 2925126 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.6 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2925127 2925128 MS MSD 92483741015 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.0 2.0 78 80 75-125 3 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 QC Batch: 550033 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92483788001 METHOD BLANK: 2924973 Associated Lab Samples: 92483788001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers Antimony ug/L ND 5.0 3.0 06/30/20 02:42 Arsenic ug/L 6.8J 10.0 4.7 06/30/20 02:42 BC Barium ug/L ND 5.0 3.5 06/30/20 02:42 Beryllium ug/L ND 1.0 0.70 06/30/20 02:42 Cadmium ug/L ND 1.0 0.40 06/30/20 02:42 Chromium ug/L ND 5.0 3.7 06/30/20 02:42 Cobalt ug/L ND 5.0 3.6 06/30/20 02:42 Copper ug/L ND 5.0 4.3 06/30/20 02:42 Lead ug/L ND 5.0 4.5 06/30/20 02:42 Nickel ug/L ND 5.0 3.5 06/30/20 02:42 Selenium ug/L ND 10.0 4.7 06/30/20 02:42 Silver ug/L ND 5.0 2.5 06/30/20 02:42 Tin ug/L ND 5.0 4.7 06/30/20 02:42 Vanadium ug/L ND 5.0 3.9 06/30/20 02:42 Zinc ug/L ND 10.0 9.5 06/30/20 02:42 LABORATORY CONTROL SAMPLE: Parameter 2924974 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 500 523 105 80-120 Arsenic ug/L 500 516 103 80-120 Barium ug/L 500 516 103 80-120 Beryllium ug/L 500 510 102 80-120 Cadmium ug/L 500 511 102 80-120 Chromium ug/L 500 495 99 80-120 Cobalt ug/L 500 514 103 80-120 Copper ug/L 500 527 105 80-120 Lead ug/L 500 511 102 80-120 Nickel ug/L 500 518 104 80-120 Selenium ug/L 500 511 102 80-120 Silver ug/L 250 244 98 80-120 Tin ug/L 500 507 101 80-120 Vanadium ug/L 500 498 100 80-120 Zinc ug/L 500 479 96 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Surry Co Lined MSWLF 92483788 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2924975 2924976 MS MSD 92483741007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 537 537 107 107 75-125 0 20 Arsenic ug/L ND 500 500 527 546 104 108 75-125 4 20 Barium ug/L 191 500 500 722 725 106 107 75-125 0 20 Beryllium ug/L ND 500 500 526 527 105 105 75-125 0 20 Cadmium ug/L 1.4 500 500 539 538 108 107 75-125 0 20 Chromium ug/L ND 500 500 524 522 105 104 75-125 0 20 Cobalt ug/L 18.2 500 500 540 538 104 104 75-125 0 20 Copper ug/L ND 500 500 539 538 108 107 75-125 0 20 Lead ug/L ND 500 500 522 516 104 103 75-125 1 20 Nickel ug/L ND 500 500 528 526 105 105 75-125 0 20 Selenium ug/L ND 500 500 550 564 109 112 75-125 2 20 Silver ug/L ND 250 250 258 256 103 102 75-125 1 20 Tin ug/L ND 500 500 524 521 104 104 75-125 0 20 Vanadium ug/L ND 500 500 524 521 104 104 75-125 1 20 Zinc ug/L ND 500 500 517 516 102 102 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 QC Batch: 550338 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92483788002, 92483788003, 92483788004, 92483788005, 92483788006, 92483788007, 92483788008, 92483788009,92483788010,92483788011,92483788012 METHOD BLANK: 2926135 Matrix: Water Associated Lab Samples: 92483788002, 92483788003, 92483788004, 92483788005, 92483788006, 92483788007, 92483788008, 92483788009,92483788010,92483788011,92483788012 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 5.0 3.0 07/01/20 03:21 Arsenic ug/L ND 10.0 4.7 07/01/20 03:21 Barium ug/L ND 5.0 3.5 07/01/20 03:21 Beryllium ug/L ND 1.0 0.70 07/01/20 03:21 Cadmium ug/L ND 1.0 0.40 07/01/20 03:21 Chromium ug/L ND 5.0 3.7 07/01/20 03:21 Cobalt ug/L ND 5.0 3.6 07/01/20 03:21 Copper ug/L ND 5.0 4.3 07/01/20 03:21 Lead ug/L ND 5.0 4.5 07/01/20 03:21 Nickel ug/L ND 5.0 3.5 07/01/20 03:21 Selenium ug/L ND 10.0 4.7 07/01/20 03:21 Silver ug/L ND 5.0 2.5 07/01/20 03:21 Vanadium ug/L ND 5.0 3.9 07/01/20 03:21 Zinc ug/L ND 10.0 9.5 07/01/20 03:21 LABORATORY CONTROL SAMPLE: 2926136 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 500 498 100 80-120 Arsenic ug/L 500 504 101 80-120 Barium ug/L 500 502 100 80-120 Beryllium ug/L 500 493 99 80-120 Cadmium ug/L 500 490 98 80-120 Chromium ug/L 500 479 96 80-120 Cobalt ug/L 500 491 98 80-120 Copper ug/L 500 504 101 80-120 Lead ug/L 500 496 99 80-120 Nickel ug/L 500 493 99 80-120 Selenium ug/L 500 488 98 80-120 Silver ug/L 250 239 96 80-120 Vanadium ug/L 500 478 96 80-120 Zinc ug/L 500 468 94 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Surry Co Lined MSWLF 92483788 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2926137 2926138 MS MSD 92483829008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 507 502 101 100 75-125 1 20 Arsenic ug/L ND 500 500 514 511 103 102 75-125 1 20 Barium ug/L 18.9 500 500 520 516 100 99 75-125 1 20 Beryllium ug/L ND 500 500 495 491 99 98 75-125 1 20 Cadmium ug/L 0.43J 500 500 507 501 101 100 75-125 1 20 Chromium ug/L ND 500 500 479 479 96 96 75-125 0 20 Cobalt ug/L ND 500 500 489 485 98 97 75-125 1 20 Copper ug/L ND 500 500 508 503 101 100 75-125 1 20 Lead ug/L ND 500 500 492 488 98 98 75-125 1 20 Nickel ug/L ND 500 500 493 488 98 97 75-125 1 20 Selenium ug/L ND 500 500 523 522 105 104 75-125 0 20 Silver ug/L ND 250 250 243 242 97 97 75-125 1 20 Vanadium ug/L ND 500 500 483 480 97 96 75-125 0 20 Zinc ug/L ND 500 500 478 474 96 95 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 39 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 QC Batch: 550035 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92483788001 METHOD BLANK: 2924981 Matrix: Water Associated Lab Samples: 92483788001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.050 06/28/20 23:02 LABORATORY CONTROL SAMPLE: 2924982 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10.4 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2924983 2924984 MS MSD 92483741002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 10.4 10.3 104 103 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 QC Batch: 550341 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92483788002, 92483788003, 92483788004, 92483788005, 92483788006, 92483788007, 92483788008, 92483788009,92483788010,92483788011,92483788012 METHOD BLANK: 2926147 Matrix: Water Associated Lab Samples: 92483788002, 92483788003, 92483788004, 92483788005, 92483788006, 92483788007, 92483788008, 92483788009,92483788010,92483788011,92483788012 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.050 06/30/2015:24 LABORATORY CONTROL SAMPLE: 2926148 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10.2 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2926149 2926150 MS MSD 92483829006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L 0.0901 10 10 10.1 10.3 100 102 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 QC Batch: 550477 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92483788008, 92483788011, 92483788012 METHOD BLANK: 2926633 Matrix: Associated Lab Samples: 92483788008, 92483788011, 92483788012 Blank Parameter Units Result Water Reporting Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 06/30/20 23:10 1,1,1-Trichloroethane ug/L ND 1.0 0.18 06/30/20 23:10 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 06/30/20 23:10 1,1,2-Trichloroethane ug/L ND 1.0 0.24 06/30/20 23:10 1,1-Dichloroethane ug/L ND 1.0 0.27 06/30/20 23:10 1,1-Dichloroethene ug/L ND 1.0 0.24 06/30/20 23:10 1,1-Dichloropropene ug/L ND 1.0 0.21 06/30/20 23:10 1,2,3-Trichlorobenzene ug/L ND 1.0 0.34 06/30/20 23:10 1,2,3-Trichloropropane ug/L ND 1.0 0.35 06/30/20 23:10 1,2,4-Trichlorobenzene ug/L ND 1.0 0.22 06/30/20 23:10 1,2-Dichlorobenzene ug/L ND 1.0 0.29 06/30/20 23:10 1,2-Dichloroethane ug/L ND 1.0 0.34 06/30/20 23:10 1,2-Dichloropropane ug/L ND 1.0 0.19 06/30/20 23:10 1,3-Dichloropropane ug/L ND 1.0 0.16 06/30/20 23:10 1,4-Dichlorobenzene ug/L ND 1.0 0.26 06/30/20 23:10 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 06/30/20 23:10 2,2-Dichloropropane ug/L ND 1.0 0.27 06/30/20 23:10 2-Butanone (MEK) ug/L ND 5.0 3.3 06/30/20 23:10 2-Hexanone ug/L ND 5.0 0.57 06/30/20 23:10 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 06/30/20 23:10 Acetone ug/L ND 25.0 6.2 06/30/20 23:10 Acetonitrile ug/L ND 50.0 30.4 06/30/20 23:10 Acrolein ug/L ND 10.0 2.7 06/30/20 23:10 IH,v1 Acrylonitrile ug/L ND 10.0 0.90 06/30/20 23:10 Allyl chloride ug/L ND 2.0 0.28 06/30/20 23:10 Benzene ug/L ND 1.0 0.15 06/30/20 23:10 Bromochloromethane ug/L ND 1.0 0.34 06/30/20 23:10 Bromodichloromethane ug/L ND 1.0 0.26 06/30/20 23:10 Bromoform ug/L ND 1.0 0.62 06/30/20 23:10 Bromomethane ug/L ND 2.0 0.62 06/30/20 23:10 IK Carbon disulfide ug/L ND 2.0 0.40 06/30/20 23:10 Carbon tetrachloride ug/L ND 1.0 0.22 06/30/20 23:10 Chlorobenzene ug/L ND 1.0 0.23 06/30/20 23:10 Chloroethane ug/L ND 1.0 0.49 06/30/20 23:10 Chloroform ug/L ND 5.0 2.3 06/30/20 23:10 Chloromethane ug/L ND 1.0 0.39 06/30/20 23:10 Chloroprene ug/L ND 5.0 1.7 06/30/20 23:10 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 06/30/20 23:10 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 06/30/20 23:10 Dibromochloromethane ug/L ND 1.0 0.41 06/30/20 23:10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 42 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 METHOD BLANK: 2926633 Matrix: Associated Lab Samples: 92483788008, 92483788011, 92483788012 Blank Parameter Units Result Water Reporting Limit MDL Analyzed Dibromomethane ug/L ND 1.0 0.46 06/30/20 23:10 Dichlorodifluoromethane ug/L ND 1.0 0.23 06/30/20 23:10 Ethyl methacrylate ug/L ND 1.0 0.51 06/30/20 23:10 Ethylbenzene ug/L ND 1.0 0.26 06/30/20 23:10 Hexachloro-1,3-butadiene ug/L ND 1.0 0.44 06/30/20 23:10 lodomethane ug/L ND 20.0 12.5 06/30/20 23:10 Isobutanol ug/L ND 100 66.4 06/30/20 23:10 Methacrylonitrile ug/L ND 10.0 1.9 06/30/20 23:10 Methyl methacrylate ug/L ND 2.0 0.46 06/30/20 23:10 Methylene Chloride ug/L ND 5.0 3.7 06/30/20 23:10 Naphthalene ug/L ND 1.0 0.35 06/30/20 23:10 Propionitrile ug/L ND 20.0 1.8 06/30/20 23:10 Styrene ug/L ND 1.0 0.27 06/30/20 23:10 Tetrachloroethene ug/L ND 1.0 0.16 06/30/20 23:10 Toluene ug/L ND 1.0 0.24 06/30/20 23:10 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 06/30/20 23:10 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 06/30/20 23:10 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 06/30/20 23:10 Trichloroethene ug/L ND 1.0 0.22 06/30/20 23:10 Trichlorofluoromethane ug/L ND 1.0 0.31 06/30/20 23:10 Vinyl acetate ug/L ND 2.0 1.4 06/30/20 23:10 Vinyl chloride ug/L ND 1.0 0.24 06/30/20 23:10 Xylene (Total) ug/L ND 1.0 0.63 06/30/20 23:10 1,2-Dichloroethane-d4 (S) % 90 70-130 06/30/20 23:10 4-Bromofluorobenzene (S) % 97 70-130 06/30/20 23:10 Toluene-d8 (S) % 100 70-130 06/30/20 23:10 LABORATORY CONTROL SAMPLE: Parameter 2926634 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 60.1 120 70-130 1,1,1-Trichloroethane ug/L 50 53.0 106 70-130 1,1,2,2-Tetrachloroethane ug/L 50 59.5 119 70-130 1,1,2-Trichloroethane ug/L 50 57.9 116 70-130 1,1-Dichloroethane ug/L 50 51.7 103 70-130 1,1-Dichloroethene ug/L 50 55.4 111 70-130 1,1-Dichloropropene ug/L 50 53.1 106 70-130 1,2,3-Trichlorobenzene ug/L 50 57.2 114 70-130 1,2,3-Trichloropropane ug/L 50 59.5 119 70-130 1,2,4-Trichlorobenzene ug/L 50 58.3 117 70-130 1,2-Dichlorobenzene ug/L 50 58.4 117 70-130 1,2-Dichloroethane ug/L 50 53.5 107 70-130 1,2-Dichloropropane ug/L 50 55.2 110 70-130 1,3-Dichloropropane ug/L 50 58.0 116 70-131 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 43 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry Co Lined MSWLF Pace Project No.: 92483788 LABORATORY CONTROL SAMPLE: 2926634 Parameter QUALITY CONTROL DATA Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,4-Dichlorobenzene ug/L 50 59.6 119 70-130 1,4-Dioxane (p-Dioxane) ug/L 1000 1230 123 59-169 2,2-Dichloropropane ug/L 50 53.5 107 69-130 2-Butanone (MEK) ug/L 100 105 105 64-135 2-Hexanone ug/L 100 118 118 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 113 113 70-130 Acetone ug/L 100 110 110 61-157 Acetonitrile ug/L 500 525 105 62-130 Acrolein ug/L 250 482 193 10-200lH,v1 Acrylonitrile ug/L 250 257 103 61-143 Allyl chloride ug/L 50 52.5 105 70-130 Benzene ug/L 50 55.2 110 70-130 Bromochloromethane ug/L 50 52.5 105 70-130 Bromodichloromethane ug/L 50 52.1 104 70-130 Bromoform ug/L 50 60.1 120 70-130 Bromomethane ug/L 50 50.5 101 38-130lK Carbon disulfide ug/L 50 48.4 97 68-130 Carbon tetrachloride ug/L 50 56.1 112 70-130 Chlorobenzene ug/L 50 57.9 116 70-130 Chloroethane ug/L 50 48.8 98 37-142 Chloroform ug/L 50 53.0 106 70-130 Chloromethane ug/L 50 36.0 72 48-130 Chloroprene ug/L 50 53.4 107 70-130 cis-1,2-Dichloroethene ug/L 50 52.7 105 70-130 cis-1,3-Dichloropropene ug/L 50 58.1 116 70-130 Dibromochloromethane ug/L 50 59.7 119 70-130 Dibromomethane ug/L 50 57.7 115 70-130 Dichlorodifluoromethane ug/L 50 39.6 79 53-134 Ethyl methacrylate ug/L 50 59.9 120 70-130 Ethylbenzene ug/L 50 56.9 114 70-130 Hexachloro-1,3-butadiene ug/L 50 52.5 105 68-132 lodomethane ug/L 100 79.5 79 40-130 Isobutanol ug/L 1000 887 89 44-144 Methacrylonitrile ug/L 500 536 107 66-130 Methyl methacrylate ug/L 50 55.6 111 69-130 Methylene Chloride ug/L 50 51.6 103 67-132 Naphthalene ug/L 50 58.5 117 70-130 Propionitrile ug/L 500 557 111 70-130 Styrene ug/L 50 61.4 123 70-130 Tetrachloroethene ug/L 50 56.0 112 69-130 Toluene ug/L 50 54.5 109 70-130 trans-1,2-Dichloroethene ug/L 50 53.1 106 70-130 trans- 1,3-Dichloropropene ug/L 50 58.2 116 70-130 trans-1,4-Dichloro-2-butene ug/L 50 76.3 153 35-189 Trichloroethene ug/L 50 59.5 119 70-130 Trichlorofluoromethane ug/L 50 49.4 99 63-130 Vinyl acetate ug/L 100 107 107 55-143 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 LABORATORY CONTROL SAMPLE: 2926634 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Vinyl chloride ug/L 50 42.7 85 70-131 Xylene (Total) ug/L 150 173 115 70-130 1,2-Dichloroethane-d4 (S) % 96 70-130 4-Bromofluorobenzene (S) % 102 70-130 Toluene-d8 (S) % 95 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2926635 2926636 MS MSD 7332837005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1, 1, 1,2-Tetrachloroethane ug/L ND 20 20 18.9 20.4 94 102 73-134 8 30 1,1,1-Trichloroethane ug/L ND 20 20 21.0 22.3 105 111 82-143 6 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 19.8 21.1 99 105 70-136 6 30 1,1,2-Trichloroethane ug/L ND 20 20 18.5 19.8 92 99 70-135 7 30 1,1-Dichloroethane ug/L ND 20 20 21.8 23.3 109 116 70-139 6 30 1,1-Dichloroethene ug/L ND 20 20 22.9 24.0 114 120 70-154 5 30 1,1-Dichloropropene ug/L ND 20 20 21.8 23.3 109 117 70-149 7 30 1,2,3-Trichlorobenzene ug/L ND 20 20 17.7 18.0 88 90 70-135 2 30 1,2,3-Trichooropropane ug/L ND 20 20 19.9 21.4 99 107 71-137 7 30 1,2,4-Trichlorobenzene ug/L ND 20 20 17.9 18.4 90 92 73-140 3 30 1,2-Dichlorobenzene ug/L ND 20 20 19.8 21.2 99 106 70-133 7 30 1,2-Dichloroethane ug/L ND 20 20 21.2 22.5 106 113 70-137 6 30 1,2-Dichloropropane ug/L ND 20 20 20.4 22.0 102 110 70-140 8 30 1,3-Dichloropropane ug/L ND 20 20 20.8 22.0 104 110 70-143 5 30 1,4-Dichlorobenzene ug/L ND 20 20 19.6 20.8 98 104 70-133 6 30 1,4-Dioxane (p-Dioxane) ug/L ND 400 400 417 441 104 110 53-168 6 30 2,2-Dichloropropane ug/L ND 20 20 21.5 22.9 108 114 61-148 6 30 2-Butanone (MEK) ug/L ND 40 40 43.1 47.5 108 119 60-139 10 30 2-Hexanone ug/L ND 40 40 41.2 44.7 103 112 65-138 8 30 4-Methyl-2-pentanone ug/L ND 40 40 39.0 41.7 97 104 65-135 7 30 (MIBK) Acetone ug/L ND 40 40 46.9 50.6 117 126 60-148 7 30 v1 Acetonitrile ug/L ND 200 200 229 244 115 122 65-141 6 30 Acrolein ug/L ND 100 100 172 180 172 180 28-162 4 30 IH,M1, v1 Acrylonitrile ug/L ND 100 100 105 112 105 112 64-147 6 30 Allyl chloride ug/L ND 20 20 21.5 23.3 108 116 70-133 8 30 Benzene ug/L ND 20 20 20.1 21.5 100 107 70-151 7 30 Bromochloromethane ug/L ND 20 20 20.6 21.3 103 107 70-141 3 30 Bromodichloromethane ug/L ND 20 20 17.1 18.1 85 90 70-138 6 30 Bromoform ug/L ND 20 20 15.9 17.2 79 86 63-130 8 30 Bromomethane ug/L ND 20 20 26.4 25.4 132 127 15-152 4 30 Carbon disulfide ug/L ND 20 20 21.3 22.6 106 113 69-149 6 30 Carbon tetrachloride ug/L ND 20 20 18.7 20.5 93 102 70-143 9 30 Chlorobenzene ug/L ND 20 20 20.1 21.4 100 107 70-138 6 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2926635 2926636 MS MSD 7332837005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloroethane ug/L ND 20 20 33.3 34.3 167 172 52-163 3 30 IK,IL, M1,v1 Chloroform ug/L ND 20 20 20.4 23.0 102 115 70-139 12 30 Chloromethane ug/L ND 20 20 18.5 19.4 92 97 41-139 5 30 Chloroprene ug/L ND 20 20 22.2 23.5 111 117 70-135 6 30 cis-1,2-Dichloroethene ug/L ND 20 20 21.0 22.3 105 112 70-141 6 30 cis-1,3-Dichloropropene ug/L ND 20 20 19.3 20.8 97 104 70-137 7 30 Dibromochloromethane ug/L ND 20 20 17.7 19.2 89 96 70-134 8 30 Dibromomethane ug/L ND 20 20 17.8 18.7 89 94 70-138 5 30 Dichlorodifluoromethane ug/L ND 20 20 15.5 17.0 77 85 47-155 10 30 Ethyl methacrylate ug/L ND 20 20 20.0 21.9 100 109 70-132 9 30 Ethylbenzene ug/L ND 20 20 20.3 21.7 102 108 66-153 7 30 Hexachloro-1,3-butadiene ug/L ND 20 20 18.1 19.2 91 96 65-149 6 30 lodomethane ug/L ND 40 40 18.9J 22.6 47 56 20-138 30 v2,v3 Isobutanol ug/L ND 400 400 381 421 95 105 41-152 10 30 Methacrylonitrile ug/L ND 200 200 228 242 114 121 67-134 6 30 v1 Methyl methacrylate ug/L ND 20 20 18.3 19.6 91 98 70-130 7 30 Methylene Chloride ug/L ND 20 20 21.6 22.8 108 114 42-159 6 30 Naphthalene ug/L ND 20 20 18.8 20.3 94 101 61-148 7 30 Propionitrile ug/L ND 200 200 227 239 113 119 70-131 5 30 Styrene ug/L ND 20 20 20.0 21.5 100 107 70-135 7 30 Tetrachloroethene ug/L ND 20 20 18.9 19.8 94 99 59-143 5 30 Toluene ug/L ND 20 20 19.3 20.8 97 104 59-148 7 30 trans-1,2-Dichloroethene ug/L ND 20 20 22.0 23.6 110 118 70-146 7 30 trans-1,3-Dichloropropene ug/L ND 20 20 18.3 19.8 91 99 70-135 8 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 15.8 16.6 79 83 47-135 5 30 Trichloroethene ug/L ND 20 20 19.3 20.6 96 103 70-147 6 30 Trichlorofluoromethane ug/L ND 20 20 21.9 23.4 110 117 70-148 6 30 Vinyl acetate ug/L ND 40 40 42.4 44.7 106 112 49-151 5 30 Vinyl chloride ug/L ND 20 20 18.7 19.9 93 99 70-156 6 30 Xylene (Total) ug/L ND 60 60 60.7 64.7 101 108 63-158 6 30 1,2-Dichloroethane-d4 (S) % 112 111 70-130 4-Bromofluorobenzene (S) % 100 99 70-130 Toluene-d8 (S) % 101 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 46 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 QC Batch: 550582 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92483788001, 92483788007, 92483788009, 92483788010 METHOD BLANK: 2927117 Matrix: Water Associated Lab Samples: 92483788001, 92483788007, 92483788009, 92483788010 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 07/01/20 01:54 1,1,1-Trichloroethane ug/L ND 1.0 0.18 07/01/20 01:54 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 07/01/20 01:54 1,1,2-Trichloroethane ug/L ND 1.0 0.24 07/01/20 01:54 1,1-Dichloroethane ug/L ND 1.0 0.27 07/01/20 01:54 1,1-Dichloroethene ug/L ND 1.0 0.24 07/01/20 01:54 1,1-Dichloropropene ug/L ND 1.0 0.21 07/01/20 01:54 1,2,3-Trichlorobenzene ug/L ND 1.0 0.34 07/01/20 01:54 1,2,3-Trichloropropane ug/L ND 1.0 0.35 07/01/20 01:54 1,2,4-Trichlorobenzene ug/L ND 1.0 0.22 07/01/20 01:54 1,2-Dichlorobenzene ug/L ND 1.0 0.29 07/01/20 01:54 1,2-Dichloroethane ug/L ND 1.0 0.34 07/01/20 01:54 1,2-Dichloropropane ug/L ND 1.0 0.19 07/01/20 01:54 1,3-Dichloropropane ug/L ND 1.0 0.16 07/01/20 01:54 1,4-Dichlorobenzene ug/L ND 1.0 0.26 07/01/20 01:54 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 07/01/20 01:54 2,2-Dichloropropane ug/L ND 1.0 0.27 07/01/20 01:54 2-Butanone (MEK) ug/L ND 5.0 3.3 07/01/20 01:54 2-Hexanone ug/L ND 5.0 0.57 07/01/20 01:54 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 07/01/20 01:54 Acetone ug/L ND 25.0 6.2 07/01/20 01:54 Acetonitrile ug/L ND 50.0 30.4 07/01/20 01:54 Acrolein ug/L ND 10.0 2.7 07/01/20 01:54 Acrylonitrile ug/L ND 10.0 0.90 07/01/20 01:54 Allyl chloride ug/L ND 2.0 0.28 07/01/20 01:54 Benzene ug/L ND 1.0 0.15 07/01/20 01:54 Bromochloromethane ug/L ND 1.0 0.34 07/01/20 01:54 Bromodichloromethane ug/L ND 1.0 0.26 07/01/20 01:54 Bromoform ug/L ND 1.0 0.62 07/01/20 01:54 Bromomethane ug/L ND 2.0 0.62 07/01/20 01:54 Carbon disulfide ug/L ND 2.0 0.40 07/01/20 01:54 Carbon tetrachloride ug/L ND 1.0 0.22 07/01/20 01:54 Chlorobenzene ug/L ND 1.0 0.23 07/01/20 01:54 Chloroethane ug/L ND 1.0 0.49 07/01/20 01:54 Chloroform ug/L ND 5.0 2.3 07/01/20 01:54 Chloromethane ug/L ND 1.0 0.39 07/01/20 01:54 Chloroprene ug/L ND 5.0 1.7 07/01/20 01:54 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 07/01/20 01:54 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 07/01/20 01:54 Dibromochloromethane ug/L ND 1.0 0.41 07/01/20 01:54 Qualifiers IH,IK IK v2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 47 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 METHOD BLANK: 2927117 Matrix: Water Associated Lab Samples: 92483788001, 92483788007, 92483788009, 92483788010 Blank Reporting Parameter Units Result Limit MDL Analyzed Dibromomethane ug/L ND 1.0 0.46 07/01/20 01:54 Dichlorodifluoromethane ug/L ND 1.0 0.23 07/01/20 01:54 Ethyl methacrylate ug/L ND 1.0 0.51 07/01/20 01:54 Ethylbenzene ug/L ND 1.0 0.26 07/01/20 01:54 Hexachloro-1,3-butadiene ug/L ND 1.0 0.44 07/01/20 01:54 lodomethane ug/L ND 20.0 12.5 07/01/20 01:54 Isobutanol ug/L ND 100 66.4 07/01/20 01:54 Methacrylonitrile ug/L ND 10.0 1.9 07/01/20 01:54 Methyl methacrylate ug/L ND 2.0 0.46 07/01/20 01:54 Methylene Chloride ug/L ND 5.0 3.7 07/01/20 01:54 Naphthalene ug/L ND 1.0 0.35 07/01/20 01:54 Propionitrile ug/L ND 20.0 1.8 07/01/20 01:54 Styrene ug/L ND 1.0 0.27 07/01/20 01:54 Tetrachloroethene ug/L ND 1.0 0.16 07/01/20 01:54 Toluene ug/L ND 1.0 0.24 07/01/20 01:54 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 07/01/20 01:54 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 07/01/20 01:54 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 07/01/20 01:54 Trichloroethene ug/L ND 1.0 0.22 07/01/20 01:54 Trichlorofluoromethane ug/L ND 1.0 0.31 07/01/20 01:54 Vinyl acetate ug/L ND 2.0 1.4 07/01/20 01:54 Vinyl chloride ug/L ND 1.0 0.24 07/01/20 01:54 Xylene (Total) ug/L ND 1.0 0.63 07/01/20 01:54 1,2-Dichloroethane-d4 (S) % 100 70-130 07/01/20 01:54 4-Bromofluorobenzene (S) % 97 70-130 07/01/20 01:54 Toluene-d8 (S) % 101 70-130 07/01/20 01:54 LABORATORY CONTROL SAMPLE: Parameter 2927118 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 51.5 103 70-130 1,1,1-Trichloroethane ug/L 50 51.4 103 70-130 1,1,2,2-Tetrachloroethane ug/L 50 51.5 103 70-130 1,1,2-Trichloroethane ug/L 50 51.6 103 70-130 1,1-Dichloroethane ug/L 50 49.8 100 70-130 1,1-Dichloroethene ug/L 50 53.3 107 70-130 1,1-Dichloropropene ug/L 50 51.1 102 70-130 1,2,3-Trichlorobenzene ug/L 50 51.1 102 70-130 1,2,3-Trichloropropane ug/L 50 51.9 104 70-130 1,2,4-Trichlorobenzene ug/L 50 53.7 107 70-130 1,2-Dichlorobenzene ug/L 50 53.6 107 70-130 1,2-Dichloroethane ug/L 50 47.2 94 70-130 1,2-Dichloropropane ug/L 50 51.0 102 70-130 1,3-Dichloropropane ug/L 50 50.1 100 70-131 Qualifiers v2 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 48 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry Co Lined MSWLF Pace Project No.: 92483788 LABORATORY CONTROL SAMPLE: 2927118 Parameter QUALITY CONTROL DATA Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,4-Dichlorobenzene ug/L 50 52.5 105 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1010 101 59-169 2,2-Dichloropropane ug/L 50 51.1 102 69-130 2-Butanone (MEK) ug/L 100 84.3 84 64-135 2-Hexanone ug/L 100 91.4 91 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 93.4 93 70-130 Acetone ug/L 100 99.7 100 61-157 Acetonitrile ug/L 500 439 88 62-130 Acrolein ug/L 250 255 102 10-200 Acrylonitrile ug/L 250 218 87 61-143 Allyl chloride ug/L 50 51.2 102 70-130 Benzene ug/L 50 51.4 103 70-130 Bromochloromethane ug/L 50 53.4 107 70-130 Bromodichloromethane ug/L 50 48.1 96 70-130 Bromoform ug/L 50 52.5 105 70-130 Bromomethane ug/L 50 55.9 112 38-130lH,IK Carbon disulfide ug/L 50 49.0 98 68-130 Carbon tetrachloride ug/L 50 54.5 109 70-130 Chlorobenzene ug/L 50 50.7 101 70-130 Chloroethane ug/L 50 40.6 81 37-142 IK Chloroform ug/L 50 51.5 103 70-130 Chloromethane ug/L 50 32.4 65 48-130 v3 Chloroprene ug/L 50 49.7 99 70-130 cis-1,2-Dichloroethene ug/L 50 48.9 98 70-130 cis-1,3-Dichloropropene ug/L 50 53.9 108 70-130 Dibromochloromethane ug/L 50 51.4 103 70-130 Dibromomethane ug/L 50 55.2 110 70-130 Dichlorodifluoromethane ug/L 50 40.1 80 53-134 Ethyl methacrylate ug/L 50 48.8 98 70-130 Ethylbenzene ug/L 50 51.8 104 70-130 Hexachloro-1,3-butadiene ug/L 50 52.2 104 68-132 lodomethane ug/L 100 83.4 83 40-130 Isobutanol ug/L 1000 747 75 44-144 v3 Methacrylonitrile ug/L 500 432 86 66-130 Methyl methacrylate ug/L 50 47.5 95 69-130 Methylene Chloride ug/L 50 44.6 89 67-132 Naphthalene ug/L 50 50.8 102 70-130 Propionitrile ug/L 500 449 90 70-130 Styrene ug/L 50 53.6 107 70-130 Tetrachloroethene ug/L 50 52.5 105 69-130 Toluene ug/L 50 52.1 104 70-130 trans-1,2-Dichloroethene ug/L 50 51.1 102 70-130 trans- 1,3-Dichloropropene ug/L 50 53.0 106 70-130 trans-1,4-Dichloro-2-butene ug/L 50 65.8 132 35-189 Trichloroethene ug/L 50 53.7 107 70-130 Trichlorofluoromethane ug/L 50 47.5 95 63-130 Vinyl acetate ug/L 100 92.3 92 55-143 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 49 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 LABORATORY CONTROL SAMPLE: 2927118 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Vinyl chloride ug/L 50 41.1 82 70-131 Xylene (Total) ug/L 150 157 105 70-130 1,2-Dichloroethane-d4 (S) % 90 70-130 4-Bromofluorobenzene (S) % 101 70-130 Toluene-d8 (S) % 99 70-130 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2927119 MS 7332839002 Spike Parameter Units Result Conc. MSD Spike Conc. 2927120 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1, 1, 1,2-Tetrachloroethane ug/L ND 20 20 20.6 20.9 103 105 73-134 1 30 1,1,1-Trichloroethane ug/L ND 20 20 21.6 21.8 108 109 82-143 1 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 18.5 18.6 93 93 70-136 0 30 1,1,2-Trichloroethane ug/L ND 20 20 19.3 19.5 97 98 70-135 1 30 1,1-Dichloroethane ug/L ND 20 20 20.8 20.6 101 99 70-139 1 30 1,1-Dichloroethene ug/L ND 20 20 21.8 21.8 109 109 70-154 0 30 1,1-Dichloropropene ug/L ND 20 20 21.5 21.9 107 109 70-149 2 30 1,2,3-Trichlorobenzene ug/L ND 20 20 19.2 19.2 96 96 70-135 0 30 1,2,3-Trichloropropane ug/L ND 20 20 19.0 19.1 95 96 71-137 1 30 1,2,4-Trichlorobenzene ug/L ND 20 20 19.8 20.5 99 102 73-140 3 30 1,2-Dichlorobenzene ug/L ND 20 20 20.6 20.0 103 100 70-133 3 30 1,2-Dichloroethane ug/L ND 20 20 19.7 19.7 98 99 70-137 0 30 1,2-Dichloropropane ug/L ND 20 20 20.3 20.6 102 103 70-140 1 30 1,3-Dichloropropane ug/L ND 20 20 19.7 20.0 99 100 70-143 1 30 1,4-Dichlorobenzene ug/L ND 20 20 23.3 23.4 117 117 70-133 0 30 1,4-Dioxane (p-Dioxane) ug/L ND 400 400 370 368 92 92 53-168 1 30 2,2-Dichloropropane ug/L ND 20 20 23.0 22.2 115 111 61-148 4 30 2-Butanone (MEK) ug/L ND 40 40 33.4 33.7 83 84 60-139 1 30 2-Hexanone ug/L ND 40 40 35.2 34.3 88 86 65-138 2 30 4-Methyl-2-pentanone ug/L ND 40 40 35.5 34.6 89 86 65-135 3 30 (MIBK) Acetone ug/L ND 40 40 38.6 37.8 97 94 60-148 2 30 Acetonitrile ug/L ND 200 200 171 160 85 80 65-141 6 30 Acrolein ug/L ND 100 100 95.9 93.9 96 94 28-162 2 30 Acrylonitrile ug/L ND 100 100 87.1 85.2 87 85 64-147 2 30 Allyl chloride ug/L ND 20 20 21.7 21.6 108 108 70-133 0 30 Benzene ug/L ND 20 20 21.0 21.5 103 105 70-151 2 30 Bromochloromethane ug/L ND 20 20 20.6 20.2 103 101 70-141 2 30 Bromodichloromethane ug/L ND 20 20 18.7 18.6 94 93 70-138 1 30 Bromoform ug/L ND 20 20 19.2 18.8 96 94 63-130 2 30 Bromomethane ug/L ND 20 20 32.2 31.1 161 155 15-152 4 30 IH,IK, M1 Carbon disulfide ug/L ND 20 20 20.7 20.4 103 102 69-149 1 30 Carbon tetrachloride ug/L ND 20 20 22.5 22.4 113 112 70-143 1 30 Chlorobenzene ug/L ND 20 20 24.7 24.3 124 122 70-138 2 30 Chloroethane ug/L 1.3 20 20 22.0 23.6 104 111 52-163 7 30 IK Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 50 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2927119 2927120 MS MSD 7332839002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloroform ug/L ND 20 20 20.1 19.9 101 100 70-139 1 30 Chloromethane ug/L ND 20 20 14.0 13.7 70 68 41-139 2 30 v3 Chloroprene ug/L ND 20 20 21.0 21.1 105 105 70-135 0 30 cis-1,2-Dichloroethene ug/L ND 20 20 20.0 20.2 99 100 70-141 1 30 cis-1,3-Dichloropropene ug/L ND 20 20 21.4 21.0 107 105 70-137 2 30 Dibromochloromethane ug/L ND 20 20 20.2 19.6 101 98 70-134 3 30 Dibromomethane ug/L ND 20 20 20.7 20.3 103 101 70-138 2 30 Dichlorodifluoromethane ug/L ND 20 20 16.3 15.8 81 79 47-155 3 30 Ethyl methacrylate ug/L ND 20 20 19.3 19.1 96 95 70-132 1 30 Ethylbenzene ug/L ND 20 20 20.9 21.3 104 106 66-153 2 30 Hexachloro-1,3-butadiene ug/L ND 20 20 21.5 19.8 108 99 65-149 8 30 lodomethane ug/L ND 40 40 41.6 40.6 104 101 20-138 2 30 Isobutanol ug/L ND 400 400 271 273 68 68 41-152 1 30 Methacrylonitrile ug/L ND 200 200 174 174 87 87 67-134 0 30 Methyl methacrylate ug/L ND 20 20 18.4 17.7 92 88 70-130 4 30 Methylene Chloride ug/L ND 20 20 18.2 18.2 91 91 42-159 0 30 Naphthalene ug/L ND 20 20 19.2 19.0 96 95 61-148 1 30 Propionitrile ug/L ND 200 200 177 173 89 86 70-131 3 30 Styrene ug/L ND 20 20 21.0 20.6 105 103 70-135 2 30 Tetrachloroethene ug/L ND 20 20 21.7 21.7 109 109 59-143 0 30 Toluene ug/L ND 20 20 21.0 20.5 105 102 59-148 2 30 trans-1,2-Dichloroethene ug/L ND 20 20 20.8 20.7 104 103 70-146 0 30 trans-1,3-Dichloropropene ug/L ND 20 20 20.7 20.2 103 101 70-135 2 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 17.6 17.7 88 89 47-135 1 30 Trichloroethene ug/L ND 20 20 22.5 21.9 112 109 70-147 3 30 Trichlorofluoromethane ug/L ND 20 20 20.6 20.7 103 103 70-148 1 30 Vinyl acetate ug/L ND 40 40 36.6 36.1 91 90 49-151 1 30 Vinyl chloride ug/L ND 20 20 18.1 18.0 90 90 70-156 0 30 Xylene (Total) ug/L ND 60 60 63.5 62.6 106 104 63-158 1 30 1,2-Dichloroethane-d4 (S) % 93 93 70-130 4-Bromofluorobenzene (S) % 100 99 70-130 Toluene-d8 (S) % 99 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 51 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 QC Batch: 550875 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92483788002, 92483788003, 92483788004, 92483788005 METHOD BLANK: 2928332 Matrix: Water Associated Lab Samples: 92483788002, 92483788003, 92483788004, 92483788005 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 07/02/20 00:15 1,1,1-Trichloroethane ug/L ND 1.0 0.18 07/02/20 00:15 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 07/02/20 00:15 1,1,2-Trichloroethane ug/L ND 1.0 0.24 07/02/20 00:15 1,1-Dichloroethane ug/L ND 1.0 0.27 07/02/20 00:15 1,1-Dichloroethene ug/L ND 1.0 0.24 07/02/20 00:15 1,1-Dichloropropene ug/L ND 1.0 0.21 07/02/20 00:15 1,2,3-Trichlorobenzene ug/L ND 1.0 0.34 07/02/20 00:15 1,2,3-Trichloropropane ug/L ND 1.0 0.35 07/02/20 00:15 1,2,4-Trichlorobenzene ug/L ND 1.0 0.22 07/02/20 00:15 1,2-Dichlorobenzene ug/L ND 1.0 0.29 07/02/20 00:15 1,2-Dichloroethane ug/L ND 1.0 0.34 07/02/20 00:15 1,2-Dichloropropane ug/L ND 1.0 0.19 07/02/20 00:15 1,3-Dichloropropane ug/L ND 1.0 0.16 07/02/20 00:15 1,4-Dichlorobenzene ug/L ND 1.0 0.26 07/02/20 00:15 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 07/02/20 00:15 2,2-Dichloropropane ug/L ND 1.0 0.27 07/02/20 00:15 2-Butanone (MEK) ug/L ND 5.0 3.3 07/02/20 00:15 2-Hexanone ug/L ND 5.0 0.57 07/02/20 00:15 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 07/02/20 00:15 Acetone ug/L ND 25.0 6.2 07/02/20 00:15 Acetonitrile ug/L ND 50.0 30.4 07/02/20 00:15 Acrolein ug/L ND 10.0 2.7 07/02/20 00:15 Acrylonitrile ug/L ND 10.0 0.90 07/02/20 00:15 Allyl chloride ug/L ND 2.0 0.28 07/02/20 00:15 Benzene ug/L ND 1.0 0.15 07/02/20 00:15 Bromochloromethane ug/L ND 1.0 0.34 07/02/20 00:15 Bromodichloromethane ug/L ND 1.0 0.26 07/02/20 00:15 Bromoform ug/L ND 1.0 0.62 07/02/20 00:15 Bromomethane ug/L ND 2.0 0.62 07/02/20 00:15 Carbon disulfide ug/L ND 2.0 0.40 07/02/20 00:15 Carbon tetrachloride ug/L ND 1.0 0.22 07/02/20 00:15 Chlorobenzene ug/L ND 1.0 0.23 07/02/20 00:15 Chloroethane ug/L ND 1.0 0.49 07/02/20 00:15 Chloroform ug/L ND 5.0 2.3 07/02/20 00:15 Chloromethane ug/L ND 1.0 0.39 07/02/20 00:15 Chloroprene ug/L ND 5.0 1.7 07/02/20 00:15 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 07/02/20 00:15 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 07/02/20 00:15 Dibromochloromethane ug/L ND 1.0 0.41 07/02/20 00:15 Qualifiers IH.v1 IK v2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 52 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 METHOD BLANK: 2928332 Matrix: Water Associated Lab Samples: 92483788002, 92483788003, 92483788004, 92483788005 Blank Reporting Parameter Units Result Limit MDL Analyzed Dibromomethane ug/L ND 1.0 0.46 07/02/20 00:15 Dichlorodifluoromethane ug/L ND 1.0 0.23 07/02/20 00:15 Ethyl methacrylate ug/L ND 1.0 0.51 07/02/20 00:15 Ethylbenzene ug/L ND 1.0 0.26 07/02/20 00:15 Hexachloro-1,3-butadiene ug/L ND 1.0 0.44 07/02/20 00:15 lodomethane ug/L ND 20.0 12.5 07/02/20 00:15 Isobutanol ug/L ND 100 66.4 07/02/20 00:15 Methacrylonitrile ug/L ND 10.0 1.9 07/02/20 00:15 Methyl methacrylate ug/L ND 2.0 0.46 07/02/20 00:15 Methylene Chloride ug/L ND 5.0 3.7 07/02/20 00:15 Naphthalene ug/L ND 1.0 0.35 07/02/20 00:15 Propionitrile ug/L ND 20.0 1.8 07/02/20 00:15 Styrene ug/L ND 1.0 0.27 07/02/20 00:15 Tetrachloroethene ug/L ND 1.0 0.16 07/02/20 00:15 Toluene ug/L ND 1.0 0.24 07/02/20 00:15 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 07/02/20 00:15 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 07/02/20 00:15 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 07/02/20 00:15 Trichloroethene ug/L ND 1.0 0.22 07/02/20 00:15 Trichlorofluoromethane ug/L ND 1.0 0.31 07/02/20 00:15 Vinyl acetate ug/L ND 2.0 1.4 07/02/20 00:15 Vinyl chloride ug/L ND 1.0 0.24 07/02/20 00:15 Xylene (Total) ug/L ND 1.0 0.63 07/02/20 00:15 1,2-Dichloroethane-d4 (S) % 90 70-130 07/02/20 00:15 4-Bromofluorobenzene (S) % 95 70-130 07/02/20 00:15 Toluene-d8 (S) % 99 70-130 07/02/20 00:15 LABORATORY CONTROL SAMPLE: Parameter 2928333 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 53.7 107 70-130 1,1,1-Trichloroethane ug/L 50 47.5 95 70-130 1,1,2,2-Tetrachloroethane ug/L 50 53.5 107 70-130 1,1,2-Trichloroethane ug/L 50 50.2 100 70-130 1,1-Dichloroethane ug/L 50 46.3 93 70-130 1,1-Dichloroethene ug/L 50 49.5 99 70-130 1,1-Dichloropropene ug/L 50 48.1 96 70-130 1,2,3-Trichlorobenzene ug/L 50 49.9 100 70-130 1,2,3-Trichloropropane ug/L 50 52.9 106 70-130 1,2,4-Trichlorobenzene ug/L 50 50.9 102 70-130 1,2-Dichlorobenzene ug/L 50 52.2 104 70-130 1,2-Dichloroethane ug/L 50 48.2 96 70-130 1,2-Dichloropropane ug/L 50 50.0 100 70-130 1,3-Dichloropropane ug/L 50 51.8 104 70-131 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 53 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry Co Lined MSWLF Pace Project No.: 92483788 LABORATORY CONTROL SAMPLE: 2928333 Parameter QUALITY CONTROL DATA Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,4-Dichlorobenzene ug/L 50 51.9 104 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1060 106 59-169 2,2-Dichloropropane ug/L 50 47.4 95 69-130 2-Butanone (MEK) ug/L 100 88.8 89 64-135 2-Hexanone ug/L 100 103 103 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 96.9 97 70-130 Acetone ug/L 100 86.1 86 61-157 Acetonitrile ug/L 500 457 91 62-130 Acrolein ug/L 250 516 207 10-2001H,L1,v1 Acrylonitrile ug/L 250 223 89 61-143 Allyl chloride ug/L 50 47.9 96 70-130 Benzene ug/L 50 49.4 99 70-130 Bromochloromethane ug/L 50 47.3 95 70-130 Bromodichloromethane ug/L 50 46.4 93 70-130 Bromoform ug/L 50 54.0 108 70-130 Bromomethane ug/L 50 43.4 87 38-130lK Carbon disulfide ug/L 50 43.2 86 68-130 Carbon tetrachloride ug/L 50 50.4 101 70-130 Chlorobenzene ug/L 50 51.3 103 70-130 Chloroethane ug/L 50 51.5 103 37-142 Chloroform ug/L 50 47.1 94 70-130 Chloromethane ug/L 50 33.5 67 48-130 v3 Chloroprene ug/L 50 49.2 98 70-130 cis-1,2-Dichloroethene ug/L 50 47.0 94 70-130 cis-1,3-Dichloropropene ug/L 50 51.7 103 70-130 Dibromochloromethane ug/L 50 53.5 107 70-130 Dibromomethane ug/L 50 51.2 102 70-130 Dichlorodifluoromethane ug/L 50 41.6 83 53-134 Ethyl methacrylate ug/L 50 51.9 104 70-130 Ethylbenzene ug/L 50 51.3 103 70-130 Hexachloro-1,3-butadiene ug/L 50 44.6 89 68-132 lodomethane ug/L 100 77.6 78 40-130 Isobutanol ug/L 1000 790 79 44-144 Methacrylonitrile ug/L 500 475 95 66-130 Methyl methacrylate ug/L 50 47.8 96 69-130 Methylene Chloride ug/L 50 46.5 93 67-132 Naphthalene ug/L 50 50.6 101 70-130 Propionitrile ug/L 500 491 98 70-130 Styrene ug/L 50 54.7 109 70-130 Tetrachloroethene ug/L 50 50.4 101 69-130 Toluene ug/L 50 48.4 97 70-130 trans-1,2-Dichloroethene ug/L 50 47.7 95 70-130 trans- 1,3-Dichloropropene ug/L 50 50.8 102 70-130 trans-1,4-Dichloro-2-butene ug/L 50 50.2 100 35-189 Trichloroethene ug/L 50 51.9 104 70-130 Trichlorofluoromethane ug/L 50 45.5 91 63-130 Vinyl acetate ug/L 100 94.3 94 55-143 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 54 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 LABORATORY CONTROL SAMPLE: 2928333 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Vinyl chloride ug/L 50 40.7 81 70-131 Xylene (Total) ug/L 150 156 104 70-130 1,2-Dichloroethane-d4 (S) % 92 70-130 4-Bromofluorobenzene (S) % 104 70-130 Toluene-d8 (S) % 96 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2928334 2928335 MS MSD 92483822003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1, 1, 1,2-Tetrachloroethane ug/L ND 20 20 21.2 20.9 106 105 73-134 1 30 1,1,1-Trichloroethane ug/L ND 20 20 24.0 23.9 120 119 82-143 1 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 23.4 23.3 117 116 70-136 1 30 1,1,2-Trichloroethane ug/L ND 20 20 21.9 21.7 109 108 70-135 1 30 1,1-Dichloroethane ug/L ND 20 20 25.8 25.6 129 128 70-139 1 30 1,1-Dichloroethene ug/L ND 20 20 26.5 26.4 132 132 70-154 0 30 1,1-Dichloropropene ug/L ND 20 20 25.7 25.5 128 128 70-149 0 30 1,2,3-Trichlorobenzene ug/L ND 20 20 21.1 21.5 105 107 70-135 2 30 1,2,3-Trichloropropane ug/L ND 20 20 22.5 22.9 112 115 71-137 2 30 1,2,4-Trichlorobenzene ug/L ND 20 20 21.2 21.5 106 107 73-140 1 30 1,2-Dichlorobenzene ug/L ND 20 20 23.0 23.0 115 115 70-133 0 30 1,2-Dichloroethane ug/L ND 20 20 24.4 24.4 122 122 70-137 0 30 1,2-Dichloropropane ug/L ND 20 20 24.1 24.1 121 121 70-140 0 30 1,3-Dichloropropane ug/L ND 20 20 24.2 24.6 121 123 70-143 2 30 1,4-Dichlorobenzene ug/L ND 20 20 22.5 22.4 112 112 70-133 0 30 1,4-Dioxane (p-Dioxane) ug/L ND 400 400 479 485 120 121 53-168 1 30 2,2-Dichloropropane ug/L ND 20 20 24.8 24.6 124 123 61-148 1 30 2-Butanone (MEK) ug/L ND 40 40 53.2 51.9 133 130 60-139 2 30 2-Hexanone ug/L ND 40 40 48.1 47.5 120 119 65-138 1 30 4-Methyl-2-pentanone ug/L ND 40 40 46.4 45.8 116 114 65-135 1 30 (MIBK) Acetone ug/L ND 40 40 56.4 54.7 141 137 60-148 3 30 v1 Acetonitrile ug/L ND 200 200 272 270 136 135 65-141 1 30 Acrolein ug/L ND 100 100 211 206 211 206 28-162 2 30 IH,MO, v1 Acrylonitrile ug/L ND 100 100 123 126 123 126 64-147 2 30 Allyl chloride ug/L ND 20 20 25.8 26.1 129 130 70-133 1 30 Benzene ug/L ND 20 20 23.3 23.4 117 117 70-151 0 30 Bromochloromethane ug/L ND 20 20 23.7 23.8 118 119 70-141 0 30 Bromodichloromethane ug/L ND 20 20 19.3 19.6 97 98 70-138 2 30 Bromoform ug/L ND 20 20 18.2 18.2 91 91 63-130 0 30 Bromomethane ug/L ND 20 20 28.5 28.8 142 144 15-152 1 30 Carbon disulfide ug/L ND 20 20 25.9 25.8 129 129 69-149 1 30 Carbon tetrachloride ug/L ND 20 20 20.9 21.3 104 106 70-143 2 30 Chlorobenzene ug/L ND 20 20 22.5 22.7 112 113 70-138 1 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 55 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2928334 2928335 MS MSD 92483822003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloroethane ug/L ND 20 20 38.1 37.4 190 187 52-163 2 30 IK,IL, M1,v1 Chloroform ug/L ND 20 20 23.8 23.6 119 118 70-139 1 30 Chloromethane ug/L ND 20 20 24.4 24.6 122 123 41-139 1 30 Chloroprene ug/L ND 20 20 25.9 25.0 130 125 70-135 3 30 cis-1,2-Dichloroethene ug/L ND 20 20 25.0 25.0 125 125 70-141 0 30 cis-1,3-Dichloropropene ug/L ND 20 20 22.6 22.6 113 113 70-137 0 30 Dibromochloromethane ug/L ND 20 20 20.4 20.3 102 101 70-134 1 30 Dibromomethane ug/L ND 20 20 20.5 20.4 103 102 70-138 1 30 Dichlorodifluoromethane ug/L ND 20 20 21.6 21.8 108 109 47-155 1 30 Ethyl methacrylate ug/L ND 20 20 23.8 23.9 119 119 70-132 0 30 Ethylbenzene ug/L ND 20 20 22.8 22.9 114 115 66-153 0 30 Hexachloro-1,3-butadiene ug/L ND 20 20 20.9 21.2 105 106 65-149 1 30 lodomethane ug/L ND 40 40 28.6 28.0 71 70 20-138 2 30 v3 Isobutanol ug/L ND 400 400 454 439 113 110 41-152 3 30 Methacrylonitrile ug/L ND 200 200 270 268 135 134 67-134 1 30 M1 Methyl methacrylate ug/L ND 20 20 21.7 21.6 108 108 70-130 0 30 Methylene Chloride ug/L ND 20 20 25.3 25.5 126 127 42-159 1 30 Naphthalene ug/L ND 20 20 22.7 22.8 113 114 61-148 0 30 Propionitrile ug/L ND 200 200 262 256 131 128 70-131 2 30 Styrene ug/L ND 20 20 22.8 22.5 114 113 70-135 1 30 Tetrachloroethene ug/L ND 20 20 20.7 21.2 103 106 59-143 3 30 Toluene ug/L ND 20 20 22.4 22.5 112 112 59-148 0 30 trans-1,2-Dichloroethene ug/L ND 20 20 26.2 26.4 131 132 70-146 1 30 trans-1,3-Dichloropropene ug/L ND 20 20 21.7 21.8 108 109 70-135 0 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 17.7 17.8 88 89 47-135 1 30 Trichloroethene ug/L ND 20 20 22.1 22.3 110 111 70-147 1 30 Trichlorofluoromethane ug/L ND 20 20 25.0 25.1 125 125 70-148 0 30 Vinyl acetate ug/L ND 40 40 50.8 49.8 127 125 49-151 2 30 Vinyl chloride ug/L ND 20 20 23.4 23.0 117 115 70-156 2 30 Xylene (Total) ug/L ND 60 60 68.8 69.3 115 115 63-158 1 30 1,2-Dichloroethane-d4 (S) % 115 116 70-130 4-Bromofluorobenzene (S) % 101 101 70-130 Toluene-d8 (S) % 102 103 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 56 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 QC Batch: 550889 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92483788006 METHOD BLANK: 2928454 Associated Lab Samples: 92483788006 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 07/02/20 01:01 1,1,1-Trichloroethane ug/L ND 1.0 0.18 07/02/20 01:01 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 07/02/20 01:01 1,1,2-Trichloroethane ug/L ND 1.0 0.24 07/02/20 01:01 1,1-Dichloroethane ug/L ND 1.0 0.27 07/02/20 01:01 1,1-Dichloroethene ug/L ND 1.0 0.24 07/02/20 01:01 1,1-Dichloropropene ug/L ND 1.0 0.21 07/02/20 01:01 1,2,3-Trichlorobenzene ug/L ND 1.0 0.34 07/02/20 01:01 1,2,3-Trichloropropane ug/L ND 1.0 0.35 07/02/20 01:01 1,2,4-Trichlorobenzene ug/L ND 1.0 0.22 07/02/20 01:01 1,2-Dichlorobenzene ug/L ND 1.0 0.29 07/02/20 01:01 1,2-Dichloroethane ug/L ND 1.0 0.34 07/02/20 01:01 1,2-Dichloropropane ug/L ND 1.0 0.19 07/02/20 01:01 1,3-Dichloropropane ug/L ND 1.0 0.16 07/02/20 01:01 1,4-Dichlorobenzene ug/L ND 1.0 0.26 07/02/20 01:01 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 07/02/20 01:01 2,2-Dichloropropane ug/L ND 1.0 0.27 07/02/20 01:01 2-Butanone (MEK) ug/L ND 5.0 3.3 07/02/20 01:01 2-Hexanone ug/L ND 5.0 0.57 07/02/20 01:01 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 07/02/20 01:01 Acetone ug/L ND 25.0 6.2 07/02/20 01:01 Acetonitrile ug/L ND 50.0 30.4 07/02/20 01:01 Acrolein ug/L ND 10.0 2.7 07/02/20 01:01 Acrylonitrile ug/L ND 10.0 0.90 07/02/20 01:01 Allyl chloride ug/L ND 2.0 0.28 07/02/20 01:01 Benzene ug/L ND 1.0 0.15 07/02/20 01:01 Bromochloromethane ug/L ND 1.0 0.34 07/02/20 01:01 Bromodichloromethane ug/L ND 1.0 0.26 07/02/20 01:01 Bromoform ug/L ND 1.0 0.62 07/02/20 01:01 Bromomethane ug/L 0.89J 2.0 0.62 07/02/20 01:01 Carbon disulfide ug/L ND 2.0 0.40 07/02/20 01:01 Carbon tetrachloride ug/L ND 1.0 0.22 07/02/20 01:01 Chlorobenzene ug/L ND 1.0 0.23 07/02/20 01:01 Chloroethane ug/L ND 1.0 0.49 07/02/20 01:01 Chloroform ug/L ND 5.0 2.3 07/02/20 01:01 Chloromethane ug/L ND 1.0 0.39 07/02/20 01:01 Chloroprene ug/L ND 5.0 1.7 07/02/20 01:01 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 07/02/20 01:01 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 07/02/20 01:01 Dibromochloromethane ug/L ND 1.0 0.41 07/02/20 01:01 Qualifiers v1 v1 IH,v2 v2 v2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 57 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 METHOD BLANK: 2928454 Associated Lab Samples: 92483788006 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Dibromomethane ug/L ND 1.0 0.46 07/02/20 01:01 Dichlorodifluoromethane ug/L ND 1.0 0.23 07/02/20 01:01 Ethyl methacrylate ug/L ND 1.0 0.51 07/02/20 01:01 Ethylbenzene ug/L ND 1.0 0.26 07/02/20 01:01 Hexachloro-1,3-butadiene ug/L 1.1 1.0 0.44 07/02/20 01:01 lodomethane ug/L ND 20.0 12.5 07/02/20 01:01 Isobutanol ug/L ND 100 66.4 07/02/20 01:01 Methacrylonitrile ug/L ND 10.0 1.9 07/02/20 01:01 Methyl methacrylate ug/L ND 2.0 0.46 07/02/20 01:01 Methylene Chloride ug/L ND 5.0 3.7 07/02/20 01:01 Naphthalene ug/L ND 1.0 0.35 07/02/20 01:01 Propionitrile ug/L ND 20.0 1.8 07/02/20 01:01 Styrene ug/L ND 1.0 0.27 07/02/20 01:01 Tetrachloroethene ug/L ND 1.0 0.16 07/02/20 01:01 Toluene ug/L ND 1.0 0.24 07/02/20 01:01 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 07/02/20 01:01 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 07/02/20 01:01 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 07/02/20 01:01 Trichloroethene ug/L ND 1.0 0.22 07/02/20 01:01 Trichlorofluoromethane ug/L ND 1.0 0.31 07/02/20 01:01 Vinyl acetate ug/L ND 2.0 1.4 07/02/20 01:01 Vinyl chloride ug/L ND 1.0 0.24 07/02/20 01:01 Xylene (Total) ug/L ND 1.0 0.63 07/02/20 01:01 1,2-Dichloroethane-d4 (S) % 106 70-130 07/02/20 01:01 4-Bromofluorobenzene (S) % 102 70-130 07/02/20 01:01 Toluene-d8 (S) % 100 70-130 07/02/20 01:01 LABORATORY CONTROL SAMPLE: Parameter 2928455 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 53.4 107 70-130 1,1,1-Trichloroethane ug/L 50 46.6 93 70-130 1,1,2,2-Tetrachloroethane ug/L 50 53.7 107 70-130 1,1,2-Trichloroethane ug/L 50 47.2 94 70-130 1,1-Dichloroethane ug/L 50 48.2 96 70-130 1,1-Dichloroethene ug/L 50 47.6 95 70-130 1,1-Dichloropropene ug/L 50 45.7 91 70-130 1,2,3-Trichlorobenzene ug/L 50 52.3 105 70-130 1,2,3-Trichloropropane ug/L 50 54.5 109 70-130 1,2,4-Trichlorobenzene ug/L 50 50.2 100 70-130 1,2-Dichlorobenzene ug/L 50 52.7 105 70-130 1,2-Dichloroethane ug/L 50 44.0 88 70-130 1,2-Dichloropropane ug/L 50 49.1 98 70-130 1,3-Dichloropropane ug/L 50 56.4 113 70-131 Qualifiers IK v2 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 58 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry Co Lined MSWLF Pace Project No.: 92483788 LABORATORY CONTROL SAMPLE: 2928455 Parameter QUALITY CONTROL DATA Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,4-Dichlorobenzene ug/L 50 52.0 104 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1180 118 59-169 2,2-Dichloropropane ug/L 50 46.7 93 69-130 2-Butanone (MEK) ug/L 100 99.1 99 64-135 2-Hexanone ug/L 100 121 121 66-135 v1 4-Methyl-2-pentanone (MIBK) ug/L 100 99.4 99 70-130 Acetone ug/L 100 103 103 61-157 Acetonitrile ug/L 500 585 117 62-130 Acrolein ug/L 250 308 123 10-200 v3 Acrylonitrile ug/L 250 241 96 61-143 Allyl chloride ug/L 50 51.6 103 70-130 Benzene ug/L 50 49.4 99 70-130 Bromochloromethane ug/L 50 49.9 100 70-130 Bromodichloromethane ug/L 50 44.2 88 70-130 Bromoform ug/L 50 54.2 108 70-130 Bromomethane ug/L 50 38.4 77 38-1301H,v3 Carbon disulfide ug/L 50 44.3 89 68-130 Carbon tetrachloride ug/L 50 51.0 102 70-130 Chlorobenzene ug/L 50 52.5 105 70-130 Chloroethane ug/L 50 39.0 78 37-142 v3 Chloroform ug/L 50 46.7 93 70-130 Chloromethane ug/L 50 33.0 66 48-130 v3 Chloroprene ug/L 50 47.9 96 70-130 cis-1,2-Dichloroethene ug/L 50 47.1 94 70-130 cis-1,3-Dichloropropene ug/L 50 52.5 105 70-130 Dibromochloromethane ug/L 50 56.4 113 70-130 Dibromomethane ug/L 50 52.2 104 70-130 Dichlorodifluoromethane ug/L 50 40.4 81 53-134 Ethyl methacrylate ug/L 50 56.7 113 70-130 Ethylbenzene ug/L 50 53.0 106 70-130 Hexachloro-1,3-butadiene ug/L 50 47.0 94 68-132 lodomethane ug/L 100 92.7 93 40-130 Isobutanol ug/L 1000 1020 102 44-144 Methacrylonitrile ug/L 500 487 97 66-130 Methyl methacrylate ug/L 50 50.3 101 69-130 Methylene Chloride ug/L 50 46.7 93 67-132 Naphthalene ug/L 50 56.4 113 70-130 Propionitrile ug/L 500 506 101 70-130 Styrene ug/L 50 53.7 107 70-130 Tetrachloroethene ug/L 50 56.4 113 69-130 Toluene ug/L 50 49.1 98 70-130 trans-1,2-Dichloroethene ug/L 50 48.8 98 70-130 trans- 1,3-Dichloropropene ug/L 50 50.9 102 70-130 trans-1,4-Dichloro-2-butene ug/L 50 43.5 87 35-189lK Trichloroethene ug/L 50 51.0 102 70-130 Trichlorofluoromethane ug/L 50 33.9 68 63-130 v3 Vinyl acetate ug/L 100 98.9 99 55-143 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 59 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 LABORATORY CONTROL SAMPLE: 2928455 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Vinyl chloride ug/L 50 40.9 82 70-131 Xylene (Total) ug/L 150 161 107 70-130 1,2-Dichloroethane-d4 (S) % 102 70-130 4-Bromofluorobenzene (S) % 102 70-130 Toluene-d8 (S) % 100 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2928456 2928457 MS MSD 92483759023 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1, 1, 1,2-Tetrachloroethane ug/L ND 20 20 23.2 21.7 116 109 73-134 7 30 1,1,1-Trichloroethane ug/L ND 20 20 21.1 19.9 106 100 82-143 6 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 22.8 21.1 114 106 70-136 8 30 1,1,2-Trichloroethane ug/L ND 20 20 20.6 19.0 103 95 70-135 8 30 1,1-Dichloroethane ug/L ND 20 20 21.3 20.0 106 100 70-139 6 30 1,1-Dichloroethene ug/L ND 20 20 23.0 20.5 115 103 70-154 11 30 1,1-Dichloropropene ug/L ND 20 20 21.0 19.7 105 99 70-149 6 30 1,2,3-Trichlorobenzene ug/L ND 20 20 23.8 22.9 119 114 70-135 4 30 1,2,3-Trichloropropane ug/L ND 20 20 22.4 21.9 112 109 71-137 2 30 1,2,4-Trichlorobenzene ug/L ND 20 20 23.5 23.6 118 118 73-140 0 30 1,2-Dichlorobenzene ug/L ND 20 20 23.6 21.7 118 109 70-133 8 30 1,2-Dichloroethane ug/L ND 20 20 18.5 17.7 93 88 70-137 5 30 1,2-Dichloropropane ug/L ND 20 20 20.8 20.0 104 100 70-140 4 30 1,3-Dichloropropane ug/L ND 20 20 23.0 22.7 115 114 70-143 1 30 1,4-Dichlorobenzene ug/L ND 20 20 21.2 22.5 106 112 70-133 6 30 1,4-Dioxane (p-Dioxane) ug/L ND 400 400 431 378 108 94 53-168 13 30 2,2-Dichloropropane ug/L ND 20 20 21.2 19.9 106 100 61-148 6 30 2-Butanone (MEK) ug/L ND 40 40 41.3 37.9 103 95 60-139 9 30 2-Hexanone ug/L ND 40 40 44.6 44.8 111 112 65-138 0 30 4-Methyl-2-pentanone ug/L ND 40 40 40.1 36.2 100 90 65-135 10 30 (MIBK) Acetone ug/L ND 40 40 42.4 39.6 106 99 60-148 7 30 Acetonitrile ug/L ND 200 200 305 190 152 95 65-141 47 30 M1,R1 Acrolein ug/L ND 100 100 121 112 121 112 28-162 8 30 Acrylonitrile ug/L ND 100 100 100 94.0 100 94 64-147 6 30 Allyl chloride ug/L ND 20 20 22.8 19.2 114 96 70-133 17 30 Benzene ug/L ND 20 20 21.7 20.7 109 103 70-151 5 30 Bromochloromethane ug/L ND 20 20 21.9 20.3 109 101 70-141 8 30 Bromodichloromethane ug/L ND 20 20 17.5 17.0 87 85 70-138 3 30 Bromoform ug/L ND 20 20 20.9 19.2 105 96 63-130 8 30 Bromomethane ug/L ND 20 20 26.8 24.6 131 119 15-152 9 30 IH,v3 Carbon disulfide ug/L ND 20 20 20.3 19.1 102 96 69-149 6 30 Carbon tetrachloride ug/L ND 20 20 21.2 19.7 106 99 70-143 7 30 Chlorobenzene ug/L ND 20 20 21.8 21.0 109 105 70-138 4 30 Chloroethane ug/L ND 20 20 19.9 18.1 99 91 52-163 9 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 60 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2928456 2928457 MS MSD 92483759023 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloroform ug/L ND 20 20 21.1 18.9 105 95 70-139 11 30 Chloromethane ug/L ND 20 20 14.4 13.5 72 68 41-139 6 30 v3 Chloroprene ug/L ND 20 20 21.1 20.1 106 101 70-135 5 30 cis-1,2-Dichloroethene ug/L ND 20 20 20.5 19.8 103 99 70-141 4 30 cis-1,3-Dichloropropene ug/L ND 20 20 21.7 19.4 109 97 70-137 11 30 Dibromochloromethane ug/L ND 20 20 21.1 20.2 105 101 70-134 4 30 Dibromomethane ug/L ND 20 20 21.8 20.6 109 103 70-138 6 30 Dichlorodifluoromethane ug/L ND 20 20 17.2 16.0 86 80 47-155 7 30 Ethyl methacrylate ug/L ND 20 20 22.2 21.1 111 106 70-132 5 30 Ethylbenzene ug/L ND 20 20 22.3 21.4 111 107 66-153 4 30 Hexachloro-1,3-butadiene ug/L ND 20 20 24.3 22.4 121 112 65-149 8 30 lodomethane ug/L ND 40 40 36.7 35.0 92 88 20-138 5 30 v3 Isobutanol ug/L ND 400 400 446 409 112 102 41-152 9 30 Methacrylonitrile ug/L ND 200 200 202 190 101 95 67-134 6 30 Methyl methacrylate ug/L ND 20 20 20.8 17.3 104 86 70-130 19 30 Methylene Chloride ug/L ND 20 20 19.8 18.7 99 93 42-159 6 30 Naphthalene ug/L ND 20 20 24.6 24.4 123 122 61-148 1 30 Propionitrile ug/L ND 200 200 205 192 102 96 70-131 7 30 Styrene ug/L ND 20 20 22.4 22.7 112 113 70-135 1 30 Tetrachloroethene ug/L ND 20 20 24.0 21.8 120 109 59-143 9 30 Toluene ug/L ND 20 20 20.4 18.2 102 91 59-148 11 30 trans-1,2-Dichloroethene ug/L ND 20 20 21.9 18.7 109 94 70-146 16 30 trans-1,3-Dichloropropene ug/L ND 20 20 20.1 18.1 100 90 70-135 10 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 11.7 13.1 58 65 47-135 11 30 IK,v3 Trichloroethene ug/L ND 20 20 21.5 19.6 107 98 70-147 9 30 Trichlorofluoromethane ug/L ND 20 20 18.6 16.8 93 84 70-148 10 30 Vinyl acetate ug/L ND 40 40 40.1 37.4 100 93 49-151 7 30 Vinyl chloride ug/L ND 20 20 17.6 16.9 88 85 70-156 4 30 Xylene (Total) ug/L ND 60 60 69.6 64.8 116 108 63-158 7 30 1,2-Dichloroethane-d4 (S) % 103 104 70-130 4-Bromofluorobenzene (S) % 98 99 70-130 Toluene-d8 (S) % 99 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 61 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 QC Batch: 550642 Analysis Method: EPA 8081 B QC Batch Method: EPA 3510C Analysis Description: 8081 OC Pesticides Red Vol Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92483788001 METHOD BLANK: 2927269 Associated Lab Samples: 92483788001 Parameter 4,4'-DDD 4,4'-DDE 4,4'-DDT Aldrin alpha-BHC beta-BHC Chlordane (Technical) delta-BHC Dieldrin Endosulfan I Endosulfan 11 Endosulfan sulfate Endrin Endrin aldehyde gamma-BHC (Lindane) Heptachlor Heptachlor epoxide Methoxychlor Toxaphene Decachlorobiphenyl (S) Tetrachloro-m-xylene (S) Matrix: Water Units Blank Result Reporting Limit MDL Analyzed ug/L ND 0.050 0.0069 07/06/20 15:43 ug/L ND 0.050 0.0064 07/06/20 15:43 ug/L ND 0.050 0.018 07/06/20 15:43 ug/L ND 0.050 0.022 07/06/20 15:43 ug/L ND 0.050 0.019 07/06/20 15:43 ug/L ND 0.050 0.014 07/06/20 15:43 ug/L ND 0.20 0.14 07/06/20 15:43 ug/L ND 0.050 0.020 07/06/20 15:43 ug/L ND 0.050 0.0073 07/06/20 15:43 ug/L ND 0.050 0.0094 07/06/20 15:43 ug/L ND 0.050 0.0065 07/06/20 15:43 ug/L ND 0.050 0.0091 07/06/20 15:43 ug/L ND 0.050 0.0089 07/06/20 15:43 ug/L ND 0.050 0.013 07/06/20 15:43 ug/L ND 0.050 0.012 07/06/20 15:43 ug/L ND 0.050 0.016 07/06/20 15:43 ug/L ND 0.050 0.0097 07/06/20 15:43 ug/L ND 0.15 0.033 07/06/20 15:43 ug/L ND 0.20 0.19 07/06/20 15:43 % 89 10-130 07/06/20 15:43 % 75 10-130 07/06/20 15:43 LABORATORY CONTROL SAMPLE: 2927270 Qualifiers Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 4,4'-DDD ug/L 0.25 0.30 119 49-130 4,4'-DDE ug/L 0.25 0.26 105 56-130 4,4'-DDT ug/L 0.25 0.28 112 45-130 Aldrin ug/L 0.25 0.21 86 25-130 alpha-BHC ug/L 0.25 0.24 96 53-130 beta-BHC ug/L 0.25 0.30 120 46-130 delta-BHC ug/L 0.25 0.26 102 54-130 Dieldrin ug/L 0.25 0.28 110 54-130 Endosulfan I ug/L 0.25 0.26 104 43-130 Endosulfan II ug/L 0.25 0.29 115 64-130 Endosulfan sulfate ug/L 0.25 0.29 115 66-130 Endrin ug/L 0.25 0.27 109 56-130 Endrin aldehyde ug/L 0.25 0.26 106 59-130 gamma-BHC (Lindane) ug/L 0.25 0.25 99 57-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 62 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 LABORATORY CONTROL SAMPLE: 2927270 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Heptachlor ug/L 0.25 0.22 89 37-130 Heptachlor epoxide ug/L 0.25 0.24 96 56-130 Methoxychlor ug/L 0.75 0.79 106 46-130 Decachlorobiphenyl (S) % 92 10-130 Tetrachloro-m-xylene (S) % 89 10-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2927271 2927272 MS MSD 92471456023 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 4,4'-DDD ug/L ND 0.25 0.25 0.23 0.12 92 48 28-130 63 30 R1 4,4'-DDE ug/L ND 0.25 0.25 0.18 0.099 73 40 26-130 59 30 R1 4,4'-DDT ug/L ND 0.25 0.25 0.21 0.11 84 44 11-130 62 30 R1 Aldrin ug/L ND 0.25 0.25 0.20 0.10 78 40 10-130 65 30 R1 alpha-BHC ug/L ND 0.25 0.25 0.20 0.10 79 40 27-130 65 30 R1 beta-BHC ug/L ND 0.25 0.25 0.26 0.13 102 53 15-130 64 30 R1 delta-BHC ug/L ND 0.25 0.25 0.24 0.14 97 54 44-130 56 30 R1 Dieldrin ug/L ND 0.25 0.25 0.21 0.11 84 45 20-130 61 30 R1 Endosulfan I ug/L ND 0.25 0.25 0.25 0.13 99 50 10-139 65 30 R1 Endosulfan II ug/L ND 0.25 0.25 0.23 0.14 94 56 36-130 50 30 R1 Endosulfan sulfate ug/L ND 0.25 0.25 0.30 0.14 118 57 45-130 69 30 R1 Endrin ug/L ND 0.25 0.25 0.23 0.11 90 46 26-130 66 30 R1 Endrin aldehyde ug/L ND 0.25 0.25 0.23 0.12 93 50 19-160 61 30 R1 gamma-BHC (Lindane) ug/L ND 0.25 0.25 0.21 0.10 83 42 33-130 66 30 R1 Heptachlor ug/L ND 0.25 0.25 0.19 0.10 77 42 25-130 59 30 R1 Heptachlor epoxide ug/L ND 0.25 0.25 0.22 0.11 87 44 18-130 66 30 R1 Methoxychlor ug/L ND 0.75 0.75 0.59 0.34 79 45 10-130 55 30 R1 Decachlorobiphenyl (S) % 31 24 10-130 Tetrachloro-m-xylene (S) % 76 40 10-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 63 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 QC Batch: 550643 Analysis Method: EPA 8082A QC Batch Method: EPA 3510C Analysis Description: 8082 GCS PCB Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92483788001 METHOD BLANK: 2927273 Matrix: Water Associated Lab Samples: 92483788001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers PCB-1016 (Aroclor 1016) ug/L ND 0.50 0.22 07/03/20 00:04 PCB-1221 (Aroclor 1221) ug/L ND 0.50 0.32 07/03/20 00:04 PCB-1232 (Aroclor 1232) ug/L ND 0.50 0.21 07/03/20 00:04 PCB-1242 (Aroclor 1242) ug/L ND 0.50 0.44 07/03/20 00:04 PCB-1248 (Aroclor 1248) ug/L ND 0.50 0.34 07/03/20 00:04 PCB-1254 (Aroclor 1254) ug/L ND 0.50 0.24 07/03/20 00:04 PCB-1260 (Aroclor 1260) ug/L ND 0.50 0.30 07/03/20 00:04 Decachlorobiphenyl (S) % 56 10-130 07/03/20 00:04 LABORATORY CONTROL SAMPLE: 2927274 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers PCB-1016 (Aroclor 1016) ug/L 5 5.3 105 41-130 PCB-1260 (Aroclor 1260) ug/L 5 5.0 100 42-130 Decachlorobiphenyl (S) % 76 10-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2927275 2927276 MS MSD 92476314022 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual PCB-1016 (Aroclor 1016) ug/L ND 5 5 4.4 4.9 88 98 15-130 11 30 PCB-1260 (Aroclor 1260) ug/L ND 5 5 3.2 3.5 63 69 10-130 9 30 Decachlorobiphenyl (S) % 38 39 10-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 64 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 QC Batch: 550645 Analysis Method: EPA 8270E QC Batch Method: EPA 3510C Analysis Description: 8270E Water APP9 RV MSSV Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92483788001 METHOD BLANK: 2927281 Associated Lab Samples: 92483788001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,2,4,5-Tetrachlorobenzene ug/L ND 10.0 4.6 07/09/20 21:45 1,3,5-Trinitrobenzene ug/L ND 10.0 5.3 07/09/20 21:45 1,3-Dinitrobenzene ug/L ND 10.0 3.7 07/09/20 21:45 1,4-Naphthoquinone ug/L ND 5.0 2.4 07/09/20 21:45 1-Naphthalenamine ug/L ND 5.0 4.6 07/09/20 21:45 2,2'-Oxybis(1-chloropropane) ug/L ND 10.0 1.3 07/09/20 21:45 2,3,4,6-Tetrachlorophenol ug/L ND 10.0 1.6 07/09/20 21:45 2,4,5-Trichlorophenol ug/L ND 10.0 1.5 07/09/20 21:45 2,4,6-Trichlorophenol ug/L ND 10.0 1.4 07/09/20 21:45 2,4-Dichlorophenol ug/L ND 10.0 1.5 07/09/20 21:45 2,4-Dimethylphenol ug/L ND 10.0 1.5 07/09/20 21:45 2,4-Dinitrophenol ug/L ND 50.0 7.3 07/09/20 21:45 2,4-Dinitrotoluene ug/L ND 10.0 1.7 07/09/20 21:45 2,6-Dichlorophenol ug/L ND 10.0 2.7 07/09/20 21:45 2,6-Dinitrotoluene ug/L ND 10.0 1.7 07/09/20 21:45 2-Acetylaminofluorene ug/L ND 10.0 1.9 07/09/20 21:45 2-Chloronaphthalene ug/L ND 10.0 1.4 07/09/20 21:45 2-Chlorophenol ug/L ND 10.0 1.4 07/09/20 21:45 2-Methylnaphthalene ug/L ND 10.0 1.4 07/09/20 21:45 2-Methylphenol(o-Cresol) ug/L ND 10.0 1.2 07/09/20 21:45 2-Naphthalenamine ug/L ND 10.0 6.1 07/09/20 21:45 2-Nitroaniline ug/L ND 20.0 3.0 07/09/20 21:45 2-Nitrophenol ug/L ND 10.0 1.7 07/09/20 21:45 3&4-Methyl phenol (m&p Cresol) ug/L ND 10.0 1.2 07/09/20 21:45 3,3'-Dichlorobenzidine ug/L ND 20.0 2.7 07/09/20 21:45 3,3'-Dimethylbenzidine ug/L ND 25.0 23.5 07/09/20 21:45 3-Methylcholanthrene ug/L ND 10.0 5.3 07/09/20 21:45 3-Nitroaniline ug/L ND 20.0 2.8 07/09/20 21:45 4,6-Dinitro-2-methyl phenol ug/L ND 20.0 4.5 07/09/20 21:45 4-Aminobiphenyl ug/L ND 10.0 4.2 07/09/20 21:45 4-Bromophenylphenyl ether ug/L ND 10.0 1.2 07/09/20 21:45 4-ChIoro-3-methyl phenol ug/L ND 10.0 2.8 07/09/20 21:45 4-Chloroaniline ug/L ND 20.0 2.8 07/09/20 21:45 4-Chlorophenylphenyl ether ug/L ND 10.0 1.5 07/09/20 21:45 4-Nitroaniline ug/L ND 20.0 3.1 07/09/20 21:45 4-Nitrophenol ug/L ND 50.0 9.4 07/09/20 21:45 5-Nitro-o-toluidine ug/L ND 10.0 2.4 07/09/20 21:45 7,12-Dimethylbenz(a)anthracene ug/L ND 10.0 2.8 07/09/20 21:45 Acenaphthene ug/L ND 10.0 1.4 07/09/20 21:45 Acenaphthylene ug/L ND 10.0 1.5 07/09/20 21:45 IH IL Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 65 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 METHOD BLANK: 2927281 Matrix: Water Associated Lab Samples: 92483788001 Blank Reporting Parameter Units Result Limit MDL Analyzed Acetophenone ug/L ND 10.0 1.3 07/09/20 21:45 Anthracene ug/L ND 10.0 1.6 07/09/20 21:45 Benzo(a)anthracene ug/L ND 10.0 1.5 07/09/20 21:45 Benzo(a)pyrene ug/L ND 10.0 1.8 07/09/20 21:45 Benzo(b)fluoranthene ug/L ND 10.0 1.7 07/09/20 21:45 Benzo(g,h,i)perylene ug/L ND 10.0 1.6 07/09/20 21:45 Benzo(k)fluoranthene ug/L ND 10.0 1.5 07/09/20 21:45 Benzyl alcohol ug/L ND 20.0 2.6 07/09/20 21:45 bis(2-Chloroethoxy)methane ug/L ND 10.0 1.3 07/09/20 21:45 bis(2-Chloroethyl) ether ug/L ND 10.0 1.7 07/09/20 21:45 bis(2-Ethylhexyl)phthalate ug/L ND 6.0 2.0 07/09/20 21:45 Butylbenzylphthalate ug/L ND 10.0 1.9 07/09/20 21:45 Chlorobenzilate ug/L ND 10.0 3.6 07/09/20 21:45 Chrysene ug/L ND 10.0 1.4 07/09/20 21:45 Di-n-butylphthalate ug/L ND 10.0 1.6 07/09/20 21:45 Di-n-octylphthalate ug/L ND 10.0 2.2 07/09/20 21:45 Diallate ug/L ND 10.0 2.7 07/09/20 21:45 Dibenz(a,h)anthracene ug/L ND 10.0 1.6 07/09/20 21:45 Dibenzofuran ug/L ND 10.0 1.3 07/09/20 21:45 Diethylphthalate ug/L ND 10.0 1.6 07/09/20 21:45 Dimethoate ug/L ND 10.0 2.0 07/09/20 21:45 Dimethylphthalate ug/L ND 10.0 1.4 07/09/20 21:45 Diphenylamine ug/L ND 10.0 1.4 07/09/20 21:45 Disulfoton ug/L ND 10.0 6.0 07/09/20 21:45 Ethyl methanesulfonate ug/L ND 20.0 2.8 07/09/20 21:45 Famphur ug/L ND 10.0 5.7 07/09/20 21:45 Fluoranthene ug/L ND 10.0 1.6 07/09/20 21:45 Fluorene ug/L ND 10.0 1.4 07/09/20 21:45 Hexachlorobenzene ug/L ND 10.0 1.3 07/09/20 21:45 Hexachlorocyclopentadiene ug/L ND 10.0 2.4 07/09/20 21:45 Hexachloroethane ug/L ND 10.0 1.3 07/09/20 21:45 Hexachloropropene ug/L ND 10.0 5.5 07/09/20 21:45 Indeno(1,2,3-cd)pyrene ug/L ND 10.0 1.7 07/09/20 21:45 Isodrin ug/L ND 10.0 3.0 07/09/20 21:45 Isophorone ug/L ND 10.0 1.3 07/09/20 21:45 Isosafrole ug/L ND 10.0 3.6 07/09/20 21:45 Kepone ug/L ND 10.0 8.2 07/09/20 21:45 Methapyrilene ug/L ND 50.0 27.2 07/09/20 21:45 IH Methyl methanesulfonate ug/L ND 5.0 3.0 07/09/20 21:45 Methyl parathion ug/L ND 10.0 2.0 07/09/20 21:45 N-Nitroso-di-n-butylamine ug/L ND 10.0 6.2 07/09/20 21:45 N-Nitroso-di-n-propylamine ug/L ND 10.0 1.3 07/09/20 21:45 N-Nitrosodiethylamine ug/L ND 10.0 2.0 07/09/20 21:45 N-Nitrosodimethylamine ug/L ND 10.0 1.8 07/09/20 21:45 N-Nitrosodiphenylamine ug/L ND 10.0 1.4 07/09/20 21:45 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 66 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 METHOD BLANK: 2927281 Associated Lab Samples: 92483788001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed N-Nitrosomethylethylamine ug/L ND 10.0 3.3 07/09/20 21:45 N-Nitrosopiperidine ug/L ND 10.0 2.6 07/09/20 21:45 N-Nitrosopyrrolidine ug/L ND 10.0 2.1 07/09/20 21:45 Nitrobenzene ug/L ND 10.0 1.5 07/09/20 21:45 O,O,O-Triethylphosphorothioate ug/L ND 10.0 3.5 07/09/20 21:45 O-Toluidine ug/L ND 10.0 2.8 07/09/20 21:45 P-Dimethylaminoazobenzene ug/L ND 5.0 3.3 07/09/20 21:45 p-Phenylenediamine ug/L ND 10.0 4.2 07/09/20 21:45 Parathion (Ethyl parathion) ug/L ND 10.0 2.0 07/09/20 21:45 Pentachlorobenzene ug/L ND 10.0 4.4 07/09/20 21:45 Pentachloronitrobenzene ug/L ND 10.0 2.4 07/09/20 21:45 Pentachlorophenol ug/L ND 20.0 2.8 07/09/20 21:45 Phenacetin ug/L ND 10.0 1.9 07/09/20 21:45 Phenanthrene ug/L ND 10.0 1.4 07/09/20 21:45 Phenol ug/L ND 10.0 1.5 07/09/20 21:45 Phorate ug/L ND 10.0 3.8 07/09/20 21:45 Pronamide ug/L ND 10.0 2.4 07/09/20 21:45 Pyrene ug/L ND 10.0 1.5 07/09/20 21:45 Safrole ug/L ND 10.0 3.2 07/09/20 21:45 Thionazin ug/L ND 10.0 1.8 07/09/20 21:45 2,4,6-Tribromophenol (S) % 95 10-137 07/09/20 21:45 2-Fluorobiphenyl (S) % 91 13-130 07/09/20 21:45 2-Fluorophenol (S) % 68 10-130 07/09/20 21:45 Nitrobenzene-d5 (S) % 96 13-130 07/09/20 21:45 Phenol-d6 (S) % 54 10-130 07/09/20 21:45 Terphenyl-d14 (S) % 121 25-130 07/09/20 21:45 LABORATORY CONTROL SAMPLE: Parameter 2927282 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,2,4,5-Tetrachlorobenzene ug/L 50 42.8 86 10-130 1,3,5-Trinitrobenzene ug/L 50 65.0 130 50-130 1,3-Dinitrobenzene ug/L 50 59.3 119 30-130 1,4-Naphthoquinone ug/L 50 31.4 63 30-130 1-Naphthalenamine ug/L 50 44.9 90 30-130 2,2'-Oxybis(1-chloropropane) ug/L 50 47.8 96 20-130 2,3,4,6-Tetrachlorophenol ug/L 50 56.9 114 40-200 2,4,5-Trichlorophenol ug/L 50 55.1 110 40-130 2,4,6-Trichlorophenol ug/L 50 54.0 108 40-130 2,4-Dichlorophenol ug/L 50 50.6 101 31-130 2,4-Dimethylphenol ug/L 50 50.6 101 30-130 2,4-Dinitrophenol ug/L 250 295 118 30-130 2,4-Dinitrotoluene ug/L 50 54.2 108 49-130 2,6-Dichlorophenol ug/L 50 52.5 105 50-130 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 67 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 LABORATORY CONTROL SAMPLE: Parameter 2927282 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 2,6-Dinitrotoluene ug/L 50 55.6 111 50-130 2-Acetylaminofluorene ug/L 50 62.3 125 70-150 2-Chloronaphthalene ug/L 50 49.3 99 30-130 2-Chlorophenol ug/L 50 46.4 93 30-130 2-Methylnaphthalene ug/L 50 47.7 95 30-130 2-Methylphenol(o-Cresol) ug/L 50 45.8 92 30-130 2-Naphthalenamine ug/L 50 47.9 96 30-130 2-Nitroaniline ug/L 100 109 109 40-130 2-Nitrophenol ug/L 50 51.0 102 20-130 3&4-Methyl phenol (m&p Cresol) ug/L 50 42.1 84 20-130 3,3'-Dichlorobenzidine ug/L 100 104 104 10-150 3,3'-Dimethylbenzidine ug/L 100 122 122 10-1501H 3-Methylcholanthrene ug/L 50 55.9 112 40-130IL 3-Nitroaniline ug/L 100 108 108 40-130 4,6-Dinitro-2-methyl phenol ug/L 100 111 111 40-130 4-Aminobiphenyl ug/L 50 37.8 76 20-130 4-Bromophenylphenyl ether ug/L 50 51.4 103 30-130 4-Chloro-3-methylphenol ug/L 100 99.9 100 30-130 4-Chloroaniline ug/L 100 98.1 98 20-130 4-Chlorophenylphenyl ether ug/L 50 49.8 100 20-130 4-Nitroaniline ug/L 100 110 110 40-130 4-Nitrophenol ug/L 250 180 72 10-130 5-Nitro-o-toluidine ug/L 50 62.4 125 50-150 7,12-Dimethylbenz(a)anthracene ug/L 50 51.8 104 50-130 Acenaphthene ug/L 50 51.2 102 30-130 Acenaphthylene ug/L 50 51.9 104 30-130 Acetophenone ug/L 50 46.9 94 20-130 Anthracene ug/L 50 52.1 104 50-130 Benzo(a)anthracene ug/L 50 54.7 109 50-130 Benzo(a)pyrene ug/L 50 56.0 112 50-130 Benzo(b)fluoranthene ug/L 50 59.6 119 50-130 Benzo(g,h,i)perylene ug/L 50 55.5 111 50-130 Benzo(k)fluoranthene ug/L 50 57.2 114 50-130 Benzyl alcohol ug/L 100 92.0 92 20-130 bis(2-Chloroethoxy)methane ug/L 50 50.0 100 30-130 bis(2-Chloroethyl) ether ug/L 50 48.6 97 30-130 bis(2-Ethylhexyl)phthalate ug/L 50 55.8 112 50-130 Butylbenzylphthalate ug/L 50 57.5 115 50-150 Chlorobenzilate ug/L 50 71.4 143 50-130 L1 Chrysene ug/L 50 54.7 109 50-130 Di-n-butylphthalate ug/L 50 52.7 105 50-130 Di-n-octylphthalate ug/L 50 56.0 112 50-130 Diallate ug/L 50 51.8 104 50-130 Dibenz(a,h)anthracene ug/L 50 56.0 112 40-130 Dibenzofuran ug/L 50 50.2 100 40-130 Diethylphthalate ug/L 50 51.3 103 40-130 Dimethoate ug/L 50 57.3 115 50-150 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 68 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 LABORATORY CONTROL SAMPLE: Parameter 2927282 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Dimethylphthalate ug/L 50 50.8 102 40-130 Diphenylamine ug/L 50 50.9 102 30-130 Disulfoton ug/L 50 53.9 108 40-150 Ethyl methanesulfonate ug/L 50 47.7 95 40-130 Famphur ug/L 100 69.0 69 30-150 Fluoranthene ug/L 50 52.6 105 30-130 Fluorene ug/L 50 51.5 103 20-130 Hexachlorobenzene ug/L 50 50.5 101 30-130 Hexachlorocyclopentadiene ug/L 50 44.0 88 10-150 Hexachloroethane ug/L 50 40.1 80 10-130 Hexachloropropene ug/L 50 29.6 59 10-150 Indeno(1,2,3-cd)pyrene ug/L 50 55.3 111 40-130 Isodrin ug/L 50 52.8 106 40-130 Isophorone ug/L 50 50.2 100 30-130 Isosafrole ug/L 50 47.6 95 40-130 Kepone ug/L 100 70.8 71 10-130 Methapyrilene ug/L 50 ND 48 10-1501H Methyl methanesulfonate ug/L 50 43.6 87 20-130 Methyl parathion ug/L 50 64.0 128 50-130 N-Nitroso-di-n-butylamine ug/L 50 44.0 88 30-130 N-Nitroso-di-n-propylamine ug/L 50 48.1 96 30-130 N-Nitrosodiethylamine ug/L 50 49.1 98 40-130 N-Nitrosodimethylamine ug/L 50 42.2 84 10-130 N-Nitrosodiphenylamine ug/L 50 50.9 102 30-130 N-Nitrosomethylethylamine ug/L 50 47.0 94 30-130 N-Nitrosopiperidine ug/L 50 53.2 106 30-130 N-Nitrosopyrrolidine ug/L 50 50.3 101 30-130 Nitrobenzene ug/L 50 50.1 100 20-130 O,O,O-Triethylphosphorothioate ug/L 50 49.2 98 40-130 O-Toluidine ug/L 50 47.2 94 20-130 P-Dimethylaminoazobenzene ug/L 50 26.5 53 10-130 p-Phenylenediamine ug/L 50 ND 0 70-140 L2 Parathion (Ethyl parathion) ug/L 50 65.0 130 50-150 Pentachlorobenzene ug/L 50 47.6 95 30-150 Pentachloronitrobenzene ug/L 50 63.9 128 60-130 Pentachlorophenol ug/L 100 120 120 10-140 Phenacetin ug/L 50 60.5 121 60-130 Phenanthrene ug/L 50 51.9 104 50-130 Phenol ug/L 50 30.0 60 10-130 Phorate ug/L 50 53.0 106 50-130 Pronamide ug/L 50 56.4 113 70-130 Pyrene ug/L 50 54.9 110 50-130 Safrole ug/L 50 47.9 96 30-130 Thionazin ug/L 50 56.1 112 60-130 2,4,6-Tribromophenol (S) % 125 10-137 2-Fluorobiphenyl (S) % 108 13-130 2-Fluorophenol (S) % 79 10-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 69 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 LABORATORY CONTROL SAMPLE: 2927282 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrobenzene-d5 (S) % 110 13-130 Phenol-d6 (S) % 65 10-130 Terphenyl-d14 (S) % 136 25-130 SO MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2927283 2927284 MS MSD 92483783001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,2,4,5-Tetrachlorobenzene ug/L ND 100 100 45.8 55.5 46 55 10-130 19 30 1,3,5-Trinitrobenzene ug/L ND 100 100 95.0 104 95 104 50-130 9 30 1,3-Dinitrobenzene ug/L ND 100 100 82.5 96.3 82 96 30-130 16 30 1,4-Naphthoquinone ug/L ND 100 100 41.4 51.0 41 51 30-130 21 30 1-Naphthalenamine ug/L ND 100 100 38.4 49.1 38 49 30-130 24 30 2,2'-Oxybis(1- ug/L ND 100 100 46.7 55.2 47 55 20-130 17 30 chloropropane) 2,3,4,6-Tetrachlorophenol ug/L ND 100 100 81.5 94.2 82 94 40-200 14 30 2,4,5-Trichlorophenol ug/L ND 100 100 70.6 85.1 71 85 40-130 19 30 2,4,6-Trichlorophenol ug/L ND 100 100 60.8 76.9 61 77 40-130 23 30 2,4-Dichlorophenol ug/L ND 100 100 55.1 66.6 55 67 31-130 19 30 2,4-Dimethylphenol ug/L ND 100 100 57.6 65.6 58 66 30-130 13 30 2,4-Dinitrophenol ug/L ND 500 500 402 472 80 94 30-130 16 30 2,4-Dinitrotoluene ug/L ND 100 100 80.7 89.0 81 89 49-130 10 30 2,6-Dichlorophenol ug/L ND 100 100 57.5 70.0 58 70 50-130 20 30 2,6-Dinitrotoluene ug/L ND 100 100 73.9 85.7 74 86 50-130 15 30 2-Acetylam inofl uorene ug/L ND 100 100 97.1 111 97 111 70-150 14 30 2-Chloronaphthalene ug/L ND 100 100 52.3 62.6 52 63 30-130 18 30 2-Chlorophenol ug/L ND 100 100 51.1 59.6 51 60 30-130 15 30 2-Methyl naphthalene ug/L ND 100 100 51.7 61.2 52 61 30-130 17 30 2-Methyl phenol(o-Cresol) ug/L ND 100 100 53.1 64.4 53 64 30-130 19 30 2-Naphthalenamine ug/L ND 100 100 41.3 52.3 41 52 30-130 23 30 2-Nitroaniline ug/L ND 200 200 131 158 66 79 40-130 19 30 2-Nitrophenol ug/L ND 100 100 54.9 67.1 55 67 20-130 20 30 3&4-Methylphenol(m&p ug/L ND 100 100 49.8 60.5 50 61 20-130 19 30 Cresol) 3,3'-Dichlorobenzidine ug/L ND 200 200 158 168 79 84 10-150 6 30 3,3'-Dimethylbenzidine ug/L ND 200 200 218 215 109 108 10-150 1 30 IH 3-Methylcholanthrene ug/L ND 100 100 89.7 95.7 90 96 40-130 7 30 IL 3-Nitroaniline ug/L ND 200 200 153 176 76 88 40-130 14 30 4,6-Dinitro-2-methylphenol ug/L ND 200 200 161 178 81 89 40-130 10 30 4-Aminobiphenyl ug/L ND 100 100 51.5 56.6 51 57 20-130 10 30 4-Bromophenylphenyl ether ug/L ND 100 100 68.2 80.8 68 81 30-130 17 30 4-Chloro-3-methylphenol ug/L ND 200 200 123 151 61 75 30-130 21 30 4-Chloroaniline ug/L ND 200 200 91.4 119 46 60 20-130 26 30 4-Chlorophenylphenyl ether ug/L ND 100 100 60.4 72.5 60 73 20-130 18 30 4-Nitroaniline ug/L ND 200 200 166 182 83 91 40-130 9 30 4-Nitrophenol ug/L ND 500 500 339 378 68 76 10-130 11 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 70 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2927283 MS 92483783001 Spike Parameter Units Result Conc. MSD Spike Conc. 2927284 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 5-Nitro-o-toluidine ug/L ND 100 100 96.0 105 96 105 50-150 9 30 7,12- ug/L ND 100 100 79.7 84.0 80 84 50-130 5 30 Dimethylbenz(a)anthracene Acenaphthene ug/L ND 100 100 56.6 68.8 57 69 30-130 19 30 Acenaphthylene ug/L ND 100 100 57.4 69.8 57 70 30-130 20 30 Acetophenone ug/L ND 100 100 50.1 59.7 50 60 20-130 17 30 Anthracene ug/L ND 100 100 76.9 84.6 77 85 50-130 10 30 Benzo(a)anth race ne ug/L ND 100 100 86.2 91.1 86 91 50-130 5 30 Benzo(a)pyrene ug/L ND 100 100 84.7 89.8 85 90 50-130 6 30 Benzo(b)fluoranthene ug/L ND 100 100 89.1 94.9 89 95 50-130 6 30 Benzo(g,h,i)perylene ug/L ND 100 100 84.1 89.9 84 90 50-130 7 30 Benzo(k)fluoranthene ug/L ND 100 100 86.0 89.3 86 89 50-130 4 30 Benzyl alcohol ug/L ND 200 200 105 126 52 63 20-130 18 30 bis(2- ug/L ND 100 100 51.9 62.2 52 62 30-130 18 30 Chloroethoxy)methane bis(2-Chloroethyl) ether ug/L ND 100 100 52.1 61.7 52 62 30-130 17 30 bis(2- Ethyl hexyl)phthalate ug/L ND 100 100 90.0 95.0 88 93 50-130 5 30 Butylbenzylphthalate ug/L ND 100 100 89.2 94.2 89 94 50-150 5 30 Chlorobenzilate ug/L ND 100 100 134 133 134 133 50-130 0 30 MO Chrysene ug/L ND 100 100 85.5 89.9 86 90 50-130 5 30 Di-n-butylphthalate ug/L ND 100 100 84.9 89.0 85 89 50-130 5 30 Di-n-octylphthalate ug/L ND 100 100 90.0 103 90 103 50-130 14 30 Diallate ug/L ND 100 100 69.5 81.0 70 81 50-130 15 30 Dibenz(a,h)anthracene ug/L ND 100 100 84.6 90.6 85 91 40-130 7 30 Dibenzofuran ug/L ND 100 100 58.5 71.1 59 71 40-130 19 30 Diethylphthalate ug/L ND 100 100 77.0 84.6 77 85 40-130 9 30 Dimethoate ug/L ND 100 100 91.0 97.0 91 97 50-150 6 30 Dimethylphthalate ug/L ND 100 100 68.5 78.8 68 79 40-130 14 30 Diphenylamine ug/L ND 100 100 71.3 79.7 71 80 30-130 11 30 Disulfoton ug/L ND 100 100 82.4 91.3 82 91 40-150 10 30 Ethyl methanesulfonate ug/L ND 100 100 51.2 62.3 51 62 40-130 20 30 Famphur ug/L ND 200 200 119 128 60 64 30-150 7 30 Fluoranthene ug/L ND 100 100 83.2 87.5 83 88 30-130 5 30 Fluorene ug/L ND 100 100 63.8 76.4 64 76 20-130 18 30 Hexachlorobenzene ug/L ND 100 100 71.3 79.7 71 80 30-130 11 30 Hexachlorocyclopentadiene ug/L ND 100 100 43.0 51.3 43 51 10-150 18 30 Hexachloroethane ug/L ND 100 100 40.9 44.1 41 44 10-130 8 30 Hexachloropropene ug/L ND 100 100 34.3 36.5 34 37 10-150 6 30 Indeno(1,2,3-cd)pyrene ug/L ND 100 100 83.9 89.3 84 89 40-130 6 30 Isodrin ug/L ND 100 100 77.9 85.1 78 85 40-130 9 30 Isophorone ug/L ND 100 100 53.3 64.4 53 64 30-130 19 30 Isosafrole ug/L ND 100 100 51.2 62.9 51 63 40-130 20 30 Kepone ug/L ND 200 200 127 148 63 74 10-130 15 30 Methapyrilene ug/L ND 100 100 58.5J 69.9J 58 70 10-150 30 IH Methyl methanesulfonate ug/L ND 100 100 46.8 58.8 47 59 20-130 23 30 Methyl parathion ug/L ND 100 100 101 107 101 107 50-130 6 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 71 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2927283 2927284 MS MSD 92483783001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual N-Nitroso-di-n-butylamine ug/L ND 100 100 58.5 68.8 58 69 30-130 16 30 N-Nitroso-di-n-propylamine ug/L ND 100 100 51.4 62.1 51 62 30-130 19 30 N-Nitrosodiethylamine ug/L ND 100 100 51.8 63.1 52 63 40-130 20 30 N-Nitrosodimethylamine ug/L ND 100 100 49.3 58.8 49 59 10-130 18 30 N-Nitrosodiphenylamine ug/L ND 100 100 71.3 79.7 71 80 30-130 11 30 N-Nitrosomethylethylamine ug/L ND 100 100 57.2 65.2 57 65 30-130 13 30 N-Nitrosopiperidine ug/L ND 100 100 57.7 69.8 58 70 30-130 19 30 N-Nitrosopyrrolidine ug/L ND 100 100 57.2 70.6 57 71 30-130 21 30 Nitrobenzene ug/L ND 100 100 51.6 61.9 52 62 20-130 18 30 0,0,0- ug/L ND 100 100 51.9 64.0 52 64 40-130 21 30 Triethylphosphorothioate O-Toluidine ug/L ND 100 100 40.9 54.3 41 54 20-130 28 30 P- ug/L ND 100 100 41.8 43.7 42 44 10-130 4 30 Dimethylaminoazobenzene p-Phenylenediamine ug/L ND 100 100 ND ND 0 0 70-140 30 MO Parathion (Ethyl parathion) ug/L ND 100 100 101 108 101 108 50-150 7 30 Pentachlorobenzene ug/L ND 100 100 55.0 67.9 55 68 30-150 21 30 Pentachloronitrobenzene ug/L ND 100 100 96.0 104 96 104 60-130 8 30 Pentachlorophenol ug/L ND 200 200 166 187 83 94 10-140 12 30 Phenacetin ug/L ND 100 100 95.6 102 96 102 60-130 6 30 Phenanthrene ug/L ND 100 100 76.4 83.8 76 84 50-130 9 30 Phenol ug/L ND 100 100 38.8 48.5 39 48 10-130 22 30 Phorate ug/L ND 100 100 73.0 83.5 73 83 50-130 13 30 Pronamide ug/L ND 100 100 89.9 95.5 90 95 70-130 6 30 Pyrene ug/L ND 100 100 86.4 91.4 86 91 50-130 6 30 Safrole ug/L ND 100 100 51.7 61.5 52 61 30-130 17 30 Thionazin ug/L ND 100 100 84.1 91.3 84 91 60-130 8 30 2,4,6-Tribromophenol (S) % 92 103 10-137 2-Fluorobiphenyl (S) % 55 67 13-130 2-Fluorophenol (S) % 45 55 10-130 Nitrobenzene-d5 (S) % 55 67 13-130 Phenol-d6 (S) % 41 52 10-130 Terphenyl-d14 (S) % 106 113 25-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 72 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 QC Batch: 550247 Analysis Method: SM 4500-S2D-2011 QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92483788001 METHOD BLANK: 2925831 Matrix: Water Associated Lab Samples: 92483788001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfide ug/L ND 100 50.0 06/30/2018:17 LABORATORY CONTROL SAMPLE: 2925832 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide ug/L 500 524 105 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2925833 2925834 MS MSD 92483818001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L ND 500 500 419 417 80 80 80-120 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2925876 2925877 MS MSD 92483619006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L ND 500 500 244 246 45 45 80-120 1 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 73 of 81 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MSWLF Pace Project No.: 92483788 QC Batch: 550319 Analysis Method: SM 4500-CN-E-2011 QC Batch Method: SM 4500-CN-E-2011 Analysis Description: 450OCNE Cyanide, Total Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92483788001 METHOD BLANK: 2926095 Matrix: Water Associated Lab Samples: 92483788001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Cyanide ug/L ND 8.0 6.0 06/30/20 01:19 LABORATORY CONTROL SAMPLE: 2926096 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Cyanide ug/L 100 103 103 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2926097 2926098 MS MSD 92483594002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Cyanide ug/L 0.019 100 100 109 107 90 88 80-120 2 10 mg/L Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 74 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS BC The same analyte was detected in an associated blank at a concentration above 1/2 the reporting limit but below the laboratory reporting limit. E Analyte concentration exceeded the calibration range. The reported result is estimated. IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be considered an estimated value. IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. IL This analyte exceeded secondary source verification criteria low for the initial calibration. The reported results should be considered an estimated value. LO Analyte recovery in the laboratory control sample (LCS) was outside QC limits. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. L2 Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated samples may be biased low. MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. P9 RPD between the primary and confirmatory analysis exceeded 40%. R1 RPD value was outside control limits. SO Surrogate recovery outside laboratory control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 75 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Surry Co Lined MSWLF Pace Project No.: 92483788 ANALYTE QUALIFIERS v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 76 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Surry Co Lined MSWLF 92483788 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92483788001 MW-10 8151A 1501187 EPA 8151 1501187 92483788001 MW-10 EPA 3510C 550642 EPA 8081 B 550969 92483788001 MW-10 EPA 3510C 550643 EPA 8082A 550971 92483788001 MW-10 EPA 3010A 550033 EPA 6010D 550040 92483788002 MW-1 EPA 3010A 550338 EPA 6010D 550348 92483788003 MW-3R EPA 3010A 550338 EPA 6010D 550348 92483788004 MW-4S EPA 3010A 550338 EPA 6010D 550348 92483788005 MW-41) EPA 3010A 550338 EPA 6010D 550348 92483788006 MW-5 EPA 3010A 550338 EPA 6010D 550348 92483788007 MW-8 EPA 3010A 550338 EPA 6010D 550348 92483788008 MW-91) EPA 3010A 550338 EPA 6010D 550348 92483788009 MW-11S EPA 3010A 550338 EPA6010D 550348 92483788010 MW-11 D EPA 3010A 550338 EPA 6010D 550348 92483788011 MW-12 EPA 3010A 550338 EPA 6010D 550348 92483788012 MW-13 EPA 3010A 550338 EPA 6010D 550348 92483788001 MW-10 EPA 3010A 550035 EPA 6020B 550045 92483788002 MW-1 EPA 3010A 550341 EPA 6020B 550352 92483788003 MW-3R EPA 3010A 550341 EPA 6020B 550352 92483788004 MW-4S EPA 3010A 550341 EPA 6020B 550352 92483788005 MW-41) EPA 3010A 550341 EPA 6020B 550352 92483788006 MW-5 EPA 3010A 550341 EPA 6020B 550352 92483788007 MW-8 EPA 3010A 550341 EPA 6020B 550352 92483788008 MW-91) EPA 3010A 550341 EPA 6020B 550352 92483788009 MW-11S EPA 3010A 550341 EPA 6020B 550352 92483788010 MW-11 D EPA 3010A 550341 EPA 6020B 550352 92483788011 MW-12 EPA 3010A 550341 EPA 6020B 550352 92483788012 MW-13 EPA 3010A 550341 EPA 6020B 550352 92483788001 MW-10 EPA 7470A 550099 EPA 7470A 550105 92483788001 MW-10 EPA 3510C 550645 EPA 8270E 550849 92483788001 MW-10 EPA 8260D 550582 92483788002 MW-1 EPA 8260D 550875 92483788003 MW-3R EPA 8260D 550875 92483788004 MW-4S EPA 8260D 550875 92483788005 MW-41) EPA 8260D 550875 92483788006 MW-5 EPA 8260D 550889 92483788007 MW-8 EPA 8260D 550582 92483788008 MW-91) EPA 8260D 550477 92483788009 MW-11S EPA 8260D 550582 92483788010 MW-11D EPA 8260D 550582 92483788011 MW-12 EPA 8260D 550477 92483788012 MW-13 EPA 8260D 550477 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/10/2020 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 77 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Surry Co Lined MSWLF Pace Project No.: 92483788 Lab ID Sample ID QC Batch Method QC Batch 92483788001 92483788001 MW-10 MW-10 SM 4500-S2D-2011 SM 4500-CN-E-2011 550247 550319 Date: 07/10/2020 04:55 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Analytical Method Batch SM 4500-CN-E-2011 550344 Page 78 of 81 Document Name: Document Revised: February 7, 2018 a Sample Condition Upon Recelpt(SCUR) Page 1 of 2 'Analy of Document No.: issuingAuthoritY: F-CAR-CS•033-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden[—] Greenwood ❑ Huntersville ❑' Raleigh❑ Mechanicsville❑ Sample Condition Client Name: WO# : 924837 88 i' �I n I c 1v�;,o��t Courier: ❑F Ex []UPS ❑USPS ❑Client ❑ Commercial ace QOther: % 92483788 Custody Seal Present? Des o Seals Intact? []Yes QWO 'J C1 j Contents: I :}a;ellaltlafs Person Eaamining Packing Material: []Bubble Wrap ubbfe Bags ❑None ❑ Other Biological Tissue f zen? [:]yes []No 1/A Thermometer: ❑IR Gun ID: 92TO6i ,...., Type of ice: [ 41 t []Blue ❑None Cooleriemp ('Q: j mid Correction Factor: Add/Subtract ('C) +b, j Temp should be above freezing to 6°C Samples an Ice, cooling process Cooler Temp Corrected CC): ❑5amples out of temp criteria. / has begun USDA Regulated Soil (U;A/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC {check maps)? Did samptes originate from a foreign source (internationally, r _ _ including Haarail and Puerto Rico)? QYes []No Chain of Custody Present? Wes []NO ❑NIA samples Arrived within Hold Time? es EIN ❑MIA Short Hold Time Analysis (02 fr.)? ❑Yes N []NIA Rush Turn Around Time Requested? []yes o ❑NIA Sufficient Volume? ❑No ❑N/A Correct Containers Used? []No ❑NIA Pace Containers Used? [—]NO [_]N/A Containers Intact? SKes ❑No ❑N Dissolved anaivsis: Samples field Filtered? ❑ ❑No IA Heads ace in VOA Vials (>5-6mm)? UYes o Trip Blank Present? ❑Yes []No Trio Blank Costodv Seals Present? []Yes ❑No DISCREPANCY 1311 1. 2. 3. 4. S. 6. 7, a. Lot Z of spat contalners: CLIENT NOTIFICATIONIRE5OLU'RON Person contacted: Project Manager SCURF Review: Project Manager SRF Review: datelTime: Date: )ate: Field Data Required? []Yes []No Page 79 of 81 Document Name; Document Revised: February 7, 2018 L ace Analytical Sample Condition Upon Recelpt(SCUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033•Rev.06 Pace Carolinas Quality Office *Check mark top Ralf of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptlons: VOA, Caliform, TOC, Oil and Grease, DRO/8015 (water) OCC, LLHg "Bottom half of box is to list number of bottle Project fi WO# : 92483788 PM: RMB Due Date: 07/13/20 CLIENT: 92-Municipal L-- y 2 z Z d U ° " O u .. Z C u G z N 2 d Z �➢ M .y Q z '7 o W n, -a u v m v 2 v a ^ V df ro n a 7 Z7 v v ry V U 2 d m Z m S a ❑ a a M v c Q o S In to 2 V a N = o . M v ci N a _ u c az o r�. S E G z `. N z a Q C- o `r' a 2 7 y ' u m a ro a u a Y b a y R a u a to m a a a E 4 _ v a E n E 1 Y a E d .a E d E o N J. U Y 4 0 m— Z d O d 0 d o v a X n y y vi w vi a E d c .0 E In E C3 E o a E E E E N 5 m m of N m = 6 t7 o E p a E o p u _m E E d E of o E p N E v m IT a 7 M Q. u 7 N a r°I a r Q a ry Z MQ a N a V Q a t❑i ^r ID T rr V) ❑ m Lo cAi M 0 N A nY to d M 0 Y S 0 l9 y F T 47 Y 7 M la 4 4 Cn W D Y d ❑ S I, > Ln a N 'N a N M a m O C7 d l7 > 01 l7 m m m oo m m ca cc d d 4 d d d�ja 7 ? w w 1 I / 2 \X\ j 4 4 I S 6 I r y1 1 87- 1 N, g J ti Z 14 I '•. lI / 1 12 ti 7 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted l ' Time preservation aIjusted Amount of Preservative added Lot M Note: Whenever there is a discrepancy affecting North Carolina Campllance samples, a copy of this form will be sent to the North Carolina OEHNR Certification pttice {l.E. Out of hold, incorrect preservative, out of temp, Incorrect containers. 5-T Page 80 of 81 p m v m O > a h rn ITEM# � � m 3 C) 7 z m cn a y A N ro p Z; (A O OE 6 G. I y N J Olp to n Q #N Y > i N "� Ln Ln x N ^ 0 aon tDn �j z ���r OW0 a _ 4 rn m O t. (� n z @ y tit N 0ED n N p o O v - FL n o a n s MATRIX COaE (see valid codes to !efl} C_ t o w0 GT �y �j IG7 C) O O SAMPLE TYPE (G-GRA9 C=COMP) m » m I W m — > a r _ _ • h7 l l �[ m O a GI❑� m 4T fi m cn n Z z n m x Z 3 z m o m mm m 0 0 z o a m to m m q m I I SAMPLE TEMP AT COLLECTION xl A r C s # OF CONTAINERS m v w a o D r^ to o n _• 1 - — — — — — s Unpreserved - L 3 v o v o� a� 0 p -- m o- o `c o h H2504 -- m A m e1 - - — HNO3 N m c .. C.' t � a w w w w w w w w :w 'w w HCI w 2 O NaOH m N rnNa2S203 mMethanol r_. Other y Analyses Test YIN m n x x x x x Ix x x x x x Cx VOCs-8280AppI z A n z A @ y x x x x Metals-App I --I O m x x x x x x x x x x Turbidity m m ri , Z z c Q 0 z N x x x x x x x x x 1,4-Dioxane(Non-51M) n a ICY" / IJ T. O IT N o m m 3 TEMP in C 3 n Received on Ice (YIN) � 00 Q Q' Cus(otly Seaftrd Cooler(YIN) p fV Q d d Q ( [� 1 O Z tr G ,f ID Samples Intact (YIN) m < m a -0 roo CD r1 N N O cr m n O 3 CD CL w C m Page 81 of 81 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 July 02, 2020 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: Surry Blanks Pace Project No.: 92483826 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on June 26, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Steven R. Gandy, Municipal Engineering Services Co. REPORT OF LABORATORY ANALYSIS r e This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 20 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry Blanks Pace Project No.: 92483826 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 20 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Surry Blanks Pace Project No.: 92483826 Lab ID Sample ID Matrix Date Collected Date Received 92483826001 92483826002 EB FIB Water Water 06/25/2015:50 06/25/2015:52 06/26/20 14:41 06/26/20 14:41 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 20 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Surry Blanks Pace Project No.: 92483826 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92483826001 EB EPA 6010D SH1 14 PASI-A EPA 6020E BG2 1 PASI-A EPA 8260D CL 51 PASI-C 92483826002 FIB EPA 6010D SH1 14 PASI-A EPA 6020E BG2 1 PASI-A EPA 8260D CL 51 PASI-C PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 20 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Blanks Pace Project No.: 92483826 Sample: EB Lab ID: 92483826001 Collected: 06/25/20 15:50 Received: 06/26/20 14:41 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 06/30/20 00:35 07/01/20 01:02 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 01:02 7440-38-2 Barium ND ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 01:02 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 06/30/20 00:35 07/01/20 01:02 7440-41-7 Cadmium 0.47J ug/L 1.0 0.40 1 06/30/20 00:35 07/01/20 01:02 7440-43-9 Chromium ND ug/L 5.0 3.7 1 06/30/20 00:35 07/01/20 01:02 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 06/30/20 00:35 07/01/20 01:02 7440-48-4 Copper ND ug/L 5.0 4.3 1 06/30/20 00:35 07/01/20 01:02 7440-50-8 Lead ND ug/L 5.0 4.5 1 06/30/20 00:35 07/01/20 01:02 7439-92-1 Nickel ND ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 01:02 7440-02-0 Selenium ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 01:02 7782-49-2 Silver ND ug/L 5.0 2.5 1 06/30/20 00:35 07/01/20 01:02 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 06/30/20 00:35 07/01/20 01:02 7440-62-2 Zinc ND ug/L 10.0 9.5 1 06/30/20 00:35 07/01/20 01:02 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 06/30/20 00:13 06/30/20 14:38 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/02/20 04:11 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/02/20 04:11 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/02/20 04:11 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/02/20 04:11 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/02/20 04:11 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/02/20 04:11 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/02/20 04:11 74-83-9 IK 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/02/20 04:11 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/02/20 04:11 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/02/20 04:11 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/02/20 04:11 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/02/20 04:11 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/02/20 04:11 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/02/20 04:11 74-87-3 v2 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/02/20 04:11 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/02/20 04:11 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/02/20 04:11 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/02/20 04:11 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/02/20 04:11 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/02/20 04:11 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/02/20 04:11 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/02/20 04:11 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/02/20 04:11 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/02/20 04:11 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/02/2020 04:47 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 20 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Blanks Pace Project No.: 92483826 Sample: EB Lab ID: 92483826001 Collected: 06/25/20 15:50 Received: 06/26/20 14:41 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/02/2020 04:47 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 07/02/20 04:11 156-59-2 ND ug/L 1.0 0.25 1 07/02/20 04:11 156-60-5 ND ug/L 1.0 0.19 1 07/02/20 04:11 78-87-5 ND ug/L 1.0 0.30 1 07/02/20 04:11 10061-01-5 ND ug/L 1.0 0.31 1 07/02/20 04:11 10061-02-6 ND ug/L 150 56.2 1 07/02/20 04:11 123-91-1 ND ug/L 1.0 0.26 1 07/02/20 04:11 100-41-4 ND ug/L 5.0 0.57 1 07/02/20 04:11 591-78-6 ND ug/L 20.0 12.5 1 07/02/20 04:11 74-88-4 ND ug/L 5.0 3.7 1 07/02/20 04:11 75-09-2 ND ug/L 5.0 4.5 1 07/02/20 04:11 108-10-1 ND ug/L 1.0 0.27 1 07/02/20 04:11 100-42-5 ND ug/L 1.0 0.34 1 07/02/20 04:11 630-20-6 ND ug/L 1.0 0.22 1 07/02/20 04:11 79-34-5 ND ug/L 1.0 0.16 1 07/02/20 04:11 127-18-4 ND ug/L 1.0 0.24 1 07/02/20 04:11 108-88-3 ND ug/L 1.0 0.18 1 07/02/20 04:11 71-55-6 ND ug/L 1.0 0.24 1 07/02/20 04:11 79-00-5 ND ug/L 1.0 0.22 1 07/02/20 04:11 79-01-6 ND ug/L 1.0 0.31 1 07/02/20 04:11 75-69-4 ND ug/L 1.0 0.35 1 07/02/20 04:11 96-18-4 ND ug/L 2.0 1.4 1 07/02/20 04:11 108-05-4 ND ug/L 1.0 0.24 1 07/02/20 04:11 75-01-4 ND ug/L 1.0 0.63 1 07/02/20 04:11 1330-20-7 93 % 70-130 1 07/02/20 04:11 460-00-4 90 % 70-130 1 07/02/20 04:11 17060-07-0 99 % 70-130 1 07/02/20 04:11 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 20 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Blanks Pace Project No.: 92483826 Sample: FIB Lab ID: 92483826002 Collected: 06/25/20 15:52 Received: 06/26/20 14:41 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 06/30/20 00:35 07/01/20 01:05 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 01:05 7440-38-2 Barium ND ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 01:05 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 06/30/20 00:35 07/01/20 01:05 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 06/30/20 00:35 07/01/20 01:05 7440-43-9 Chromium ND ug/L 5.0 3.7 1 06/30/20 00:35 07/01/20 01:05 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 06/30/20 00:35 07/01/20 01:05 7440-48-4 Copper ND ug/L 5.0 4.3 1 06/30/20 00:35 07/01/20 01:05 7440-50-8 Lead ND ug/L 5.0 4.5 1 06/30/20 00:35 07/01/20 01:05 7439-92-1 Nickel ND ug/L 5.0 3.5 1 06/30/20 00:35 07/01/20 01:05 7440-02-0 Selenium ND ug/L 10.0 4.7 1 06/30/20 00:35 07/01/20 01:05 7782-49-2 Silver ND ug/L 5.0 2.5 1 06/30/20 00:35 07/01/20 01:05 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 06/30/20 00:35 07/01/20 01:05 7440-62-2 Zinc ND ug/L 10.0 9.5 1 06/30/20 00:35 07/01/20 01:05 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 06/30/20 00:13 06/30/20 14:42 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/02/20 04:29 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/02/20 04:29 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/02/20 04:29 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/02/20 04:29 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/02/20 04:29 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/02/20 04:29 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/02/20 04:29 74-83-9 IK 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/02/20 04:29 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/02/20 04:29 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/02/20 04:29 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/02/20 04:29 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/02/20 04:29 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/02/20 04:29 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/02/20 04:29 74-87-3 v2 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/02/20 04:29 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/02/20 04:29 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/02/20 04:29 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/02/20 04:29 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/02/20 04:29 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/02/20 04:29 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/02/20 04:29 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/02/20 04:29 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/02/20 04:29 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/02/20 04:29 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/02/2020 04:47 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 20 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Blanks Pace Project No.: 92483826 Sample: FIB Lab ID: 92483826002 Collected: 06/25/20 15:52 Received: 06/26/20 14:41 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/02/2020 04:47 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 07/02/20 04:29 156-59-2 ND ug/L 1.0 0.25 1 07/02/20 04:29 156-60-5 ND ug/L 1.0 0.19 1 07/02/20 04:29 78-87-5 ND ug/L 1.0 0.30 1 07/02/20 04:29 10061-01-5 ND ug/L 1.0 0.31 1 07/02/20 04:29 10061-02-6 ND ug/L 150 56.2 1 07/02/20 04:29 123-91-1 ND ug/L 1.0 0.26 1 07/02/20 04:29 100-41-4 ND ug/L 5.0 0.57 1 07/02/20 04:29 591-78-6 ND ug/L 20.0 12.5 1 07/02/20 04:29 74-88-4 ND ug/L 5.0 3.7 1 07/02/20 04:29 75-09-2 ND ug/L 5.0 4.5 1 07/02/20 04:29 108-10-1 ND ug/L 1.0 0.27 1 07/02/20 04:29 100-42-5 ND ug/L 1.0 0.34 1 07/02/20 04:29 630-20-6 ND ug/L 1.0 0.22 1 07/02/20 04:29 79-34-5 ND ug/L 1.0 0.16 1 07/02/20 04:29 127-18-4 ND ug/L 1.0 0.24 1 07/02/20 04:29 108-88-3 ND ug/L 1.0 0.18 1 07/02/20 04:29 71-55-6 ND ug/L 1.0 0.24 1 07/02/20 04:29 79-00-5 ND ug/L 1.0 0.22 1 07/02/20 04:29 79-01-6 ND ug/L 1.0 0.31 1 07/02/20 04:29 75-69-4 ND ug/L 1.0 0.35 1 07/02/20 04:29 96-18-4 ND ug/L 2.0 1.4 1 07/02/20 04:29 108-05-4 ND ug/L 1.0 0.24 1 07/02/20 04:29 75-01-4 ND ug/L 1.0 0.63 1 07/02/20 04:29 1330-20-7 95 % 70-130 1 07/02/20 04:29 460-00-4 89 % 70-130 1 07/02/20 04:29 17060-07-0 100 % 70-130 1 07/02/20 04:29 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 20 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Blanks Pace Project No.: 92483826 QC Batch: 550337 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92483826001, 92483826002 METHOD BLANK: 2926131 Associated Lab Samples: 92483826001, 92483826002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 5.0 3.0 06/30/20 23:57 Arsenic ug/L ND 10.0 4.7 06/30/20 23:57 Barium ug/L ND 5.0 3.5 06/30/20 23:57 Beryllium ug/L ND 1.0 0.70 06/30/20 23:57 Cadmium ug/L ND 1.0 0.40 06/30/20 23:57 Chromium ug/L ND 5.0 3.7 07/01/2018:57 Cobalt ug/L ND 5.0 3.6 06/30/20 23:57 Copper ug/L ND 5.0 4.3 06/30/20 23:57 Lead ug/L ND 5.0 4.5 06/30/20 23:57 Nickel ug/L ND 5.0 3.5 06/30/20 23:57 Selenium ug/L ND 10.0 4.7 06/30/20 23:57 Silver ug/L ND 5.0 2.5 06/30/20 23:57 Vanadium ug/L ND 5.0 3.9 07/01/2018:57 Zinc ug/L ND 10.0 9.5 06/30/20 23:57 LABORATORY CONTROL SAMPLE: Parameter 2926132 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 489 98 80-120 Arsenic ug/L 500 492 98 80-120 Barium ug/L 500 484 97 80-120 Beryllium ug/L 500 470 94 80-120 Cadmium ug/L 500 472 94 80-120 Chromium ug/L 500 495 99 80-120 Cobalt ug/L 500 473 95 80-120 Copper ug/L 500 491 98 80-120 Lead ug/L 500 478 96 80-120 Nickel ug/L 500 472 94 80-120 Selenium ug/L 500 481 96 80-120 Silver ug/L 250 225 90 80-120 Vanadium ug/L 500 499 100 80-120 Zinc ug/L 500 442 88 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/02/2020 04:47 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 20 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Surry Blanks 92483826 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2926133 2926134 MS MSD 92483926003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 512 507 102 101 75-125 1 20 Arsenic ug/L ND 500 500 524 517 105 103 75-125 1 20 Barium ug/L 60.9 500 500 560 550 100 98 75-125 2 20 Beryllium ug/L ND 500 500 493 476 99 95 75-125 4 20 Cadmium ug/L ND 500 500 504 495 101 99 75-125 2 20 Chromium ug/L ND 500 500 515 ND 103 0 75-125 20 M1 Cobalt ug/L ND 500 500 495 483 99 97 75-125 2 20 Copper ug/L ND 500 500 500 496 100 99 75-125 1 20 Lead ug/L ND 500 500 494 488 99 98 75-125 1 20 Nickel ug/L ND 500 500 494 482 98 96 75-125 2 20 Selenium ug/L ND 500 500 533 530 107 106 75-125 1 20 Silver ug/L ND 250 250 237 232 95 93 75-125 2 20 Vanadium ug/L ND 500 500 513 ND 103 0 75-125 20 M1 Zinc ug/L ND 500 500 490 469 97 93 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/02/2020 04:47 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 20 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Blanks Pace Project No.: 92483826 QC Batch: 550340 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92483826001, 92483826002 METHOD BLANK: 2926143 Matrix: Water Associated Lab Samples: 92483826001, 92483826002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.050 06/30/2013:04 LABORATORY CONTROL SAMPLE: 2926144 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10.1 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2926145 2926146 MS MSD 92483822002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 10.1 10.3 100 102 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/02/2020 04:47 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 20 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Blanks Pace Project No.: 92483826 QC Batch: 550875 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92483826001, 92483826002 METHOD BLANK: 2928332 Associated Lab Samples: 92483826001, 92483826002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 07/02/20 00:15 1,1,1-Trichloroethane ug/L ND 1.0 0.18 07/02/20 00:15 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 07/02/20 00:15 1,1,2-Trichloroethane ug/L ND 1.0 0.24 07/02/20 00:15 1,1-Dichloroethane ug/L ND 1.0 0.27 07/02/20 00:15 1,1-Dichloroethene ug/L ND 1.0 0.24 07/02/20 00:15 1,2,3-Trichloropropane ug/L ND 1.0 0.35 07/02/20 00:15 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 07/02/20 00:15 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 07/02/20 00:15 1,2-Dichlorobenzene ug/L ND 1.0 0.29 07/02/20 00:15 1,2-Dichloroethane ug/L ND 1.0 0.34 07/02/20 00:15 1,2-Dichloropropane ug/L ND 1.0 0.19 07/02/20 00:15 1,4-Dichlorobenzene ug/L ND 1.0 0.26 07/02/20 00:15 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 07/02/20 00:15 2-Butanone (MEK) ug/L ND 5.0 3.3 07/02/20 00:15 2-Hexanone ug/L ND 5.0 0.57 07/02/20 00:15 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 07/02/20 00:15 Acetone ug/L ND 25.0 6.2 07/02/20 00:15 Acrylonitrile ug/L ND 10.0 0.90 07/02/20 00:15 Benzene ug/L ND 1.0 0.15 07/02/20 00:15 Bromochloromethane ug/L ND 1.0 0.34 07/02/20 00:15 Bromodichloromethane ug/L ND 1.0 0.26 07/02/20 00:15 Bromoform ug/L ND 1.0 0.62 07/02/20 00:15 Bromomethane ug/L ND 2.0 0.62 07/02/20 00:15 IK Carbon disulfide ug/L ND 2.0 0.40 07/02/20 00:15 Carbon tetrachloride ug/L ND 1.0 0.22 07/02/20 00:15 Chlorobenzene ug/L ND 1.0 0.23 07/02/20 00:15 Chloroethane ug/L ND 1.0 0.49 07/02/20 00:15 Chloroform ug/L ND 5.0 2.3 07/02/20 00:15 Chloromethane ug/L ND 1.0 0.39 07/02/20 00:15 v2 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 07/02/20 00:15 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 07/02/20 00:15 Dibromochloromethane ug/L ND 1.0 0.41 07/02/20 00:15 Dibromomethane ug/L ND 1.0 0.46 07/02/20 00:15 Ethylbenzene ug/L ND 1.0 0.26 07/02/20 00:15 lodomethane ug/L ND 20.0 12.5 07/02/20 00:15 Methylene Chloride ug/L ND 5.0 3.7 07/02/20 00:15 Styrene ug/L ND 1.0 0.27 07/02/20 00:15 Tetrachloroethene ug/L ND 1.0 0.16 07/02/20 00:15 Toluene ug/L ND 1.0 0.24 07/02/20 00:15 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/02/2020 04:47 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 20 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Blanks Pace Project No.: 92483826 METHOD BLANK: 2928332 Associated Lab Samples: 92483826001, 92483826002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.25 07/02/20 00:15 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 07/02/20 00:15 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 07/02/20 00:15 Trichloroethene ug/L ND 1.0 0.22 07/02/20 00:15 Trichlorofluoromethane ug/L ND 1.0 0.31 07/02/20 00:15 Vinyl acetate ug/L ND 2.0 1.4 07/02/20 00:15 Vinyl chloride ug/L ND 1.0 0.24 07/02/20 00:15 Xylene (Total) ug/L ND 1.0 0.63 07/02/20 00:15 1,2-Dichloroethane-d4 (S) % 90 70-130 07/02/20 00:15 4-Bromofluorobenzene (S) % 95 70-130 07/02/20 00:15 Toluene-d8 (S) % 99 70-130 07/02/20 00:15 LABORATORY CONTROL SAMPLE: Parameter 2928333 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 53.7 107 70-130 1,1,1-Trichloroethane ug/L 50 47.5 95 70-130 1,1,2,2-Tetrachloroethane ug/L 50 53.5 107 70-130 1,1,2-Trichloroethane ug/L 50 50.2 100 70-130 1,1-Dichloroethane ug/L 50 46.3 93 70-130 1,1-Dichloroethene ug/L 50 49.5 99 70-130 1,2,3-Trichloropropane ug/L 50 52.9 106 70-130 1,2-Dibromo-3-chloropropane ug/L 50 51.0 102 70-130 1,2-Dibromoethane (EDB) ug/L 50 52.3 105 70-130 1,2-Dichlorobenzene ug/L 50 52.2 104 70-130 1,2-Dichloroethane ug/L 50 48.2 96 70-130 1,2-Dichloropropane ug/L 50 50.0 100 70-130 1,4-Dichlorobenzene ug/L 50 51.9 104 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1060 106 59-169 2-Butanone (MEK) ug/L 100 88.8 89 64-135 2-Hexanone ug/L 100 103 103 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 96.9 97 70-130 Acetone ug/L 100 86.1 86 61-157 Acrylonitrile ug/L 250 223 89 61-143 Benzene ug/L 50 49.4 99 70-130 Bromochloromethane ug/L 50 47.3 95 70-130 Bromodichloromethane ug/L 50 46.4 93 70-130 Bromoform ug/L 50 54.0 108 70-130 Bromomethane ug/L 50 43.4 87 38-130lK Carbon disulfide ug/L 50 43.2 86 68-130 Carbon tetrachloride ug/L 50 50.4 101 70-130 Chlorobenzene ug/L 50 51.3 103 70-130 Chloroethane ug/L 50 51.5 103 37-142 Chloroform ug/L 50 47.1 94 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/02/2020 04:47 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 20 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Blanks Pace Project No.: 92483826 LABORATORY CONTROL SAMPLE: Parameter 2928333 Units Spike Conc. LCS LCS Result % Rec Chloromethane ug/L 50 33.5 cis-1,2-Dichloroethene ug/L 50 47.0 cis-1,3-Dichloropropene ug/L 50 51.7 Dibromochloromethane ug/L 50 53.5 Dibromomethane ug/L 50 51.2 Ethylbenzene ug/L 50 51.3 lodomethane ug/L 100 77.6 Methylene Chloride ug/L 50 46.5 Styrene ug/L 50 54.7 Tetrachloroethene ug/L 50 50.4 Toluene ug/L 50 48.4 trans-1,2-Dichloroethene ug/L 50 47.7 trans- 1,3-Dichloropropene ug/L 50 50.8 trans-1,4-Dichloro-2-butene ug/L 50 50.2 Trichloroethene ug/L 50 51.9 Trichlorofluoromethane ug/L 50 45.5 Vinyl acetate ug/L 100 94.3 Vinyl chloride ug/L 50 40.7 Xylene (Total) ug/L 150 156 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % % Rec Limits Qualifiers 67 48-130 v3 94 70-130 103 70-130 107 70-130 102 70-130 103 70-130 78 40-130 93 67-132 109 70-130 101 69-130 97 70-130 95 70-130 102 70-130 100 35-189 104 70-130 91 63-130 94 55-143 81 70-131 104 70-130 92 70-130 104 70-130 96 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2928334 MS 92483822003 Spike Parameter Units Result Conc. MSD Spike Conc. 2928335 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 21.2 20.9 106 105 73-134 1 30 1,1,1-Trichloroethane ug/L ND 20 20 24.0 23.9 120 119 82-143 1 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 23.4 23.3 117 116 70-136 1 30 1,1,2-Trichloroethane ug/L ND 20 20 21.9 21.7 109 108 70-135 1 30 1,1-Dichloroethane ug/L ND 20 20 25.8 25.6 129 128 70-139 1 30 1,1-Dichloroethene ug/L ND 20 20 26.5 26.4 132 132 70-154 0 30 1,2,3-Trichloropropane ug/L ND 20 20 22.5 22.9 112 115 71-137 2 30 1,2-Dibromo-3- ug/L ND 20 20 20.6 20.4 103 102 65-134 1 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 22.6 22.6 113 113 70-137 0 30 1,2-Dichlorobenzene ug/L ND 20 20 23.0 23.0 115 115 70-133 0 30 1,2-Dichloroethane ug/L ND 20 20 24.4 24.4 122 122 70-137 0 30 1,2-Dichloropropane ug/L ND 20 20 24.1 24.1 121 121 70-140 0 30 1,4-Dichlorobenzene ug/L ND 20 20 22.5 22.4 112 112 70-133 0 30 1,4-Dioxane (p-Dioxane) ug/L ND 400 400 479 485 120 121 53-168 1 30 2-Butanone (MEK) ug/L ND 40 40 53.2 51.9 133 130 60-139 2 30 2-Hexanone ug/L ND 40 40 48.1 47.5 120 119 65-138 1 30 4-Methyl-2-pentanone ug/L ND 40 40 46.4 45.8 116 114 65-135 1 30 (MIBK) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/02/2020 04:47 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 20 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Blanks Pace Project No.: 92483826 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2928334 2928335 MS MSD 92483822003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acetone ug/L ND 40 40 56.4 54.7 141 137 60-148 3 30 v1 Acrylonitrile ug/L ND 100 100 123 126 123 126 64-147 2 30 Benzene ug/L ND 20 20 23.3 23.4 117 117 70-151 0 30 Bromochloromethane ug/L ND 20 20 23.7 23.8 118 119 70-141 0 30 Bromodichloromethane ug/L ND 20 20 19.3 19.6 97 98 70-138 2 30 Bromoform ug/L ND 20 20 18.2 18.2 91 91 63-130 0 30 Bromomethane ug/L ND 20 20 28.5 28.8 142 144 15-152 1 30 Carbon disulfide ug/L ND 20 20 25.9 25.8 129 129 69-149 1 30 Carbon tetrachloride ug/L ND 20 20 20.9 21.3 104 106 70-143 2 30 Chlorobenzene ug/L ND 20 20 22.5 22.7 112 113 70-138 1 30 Chloroethane ug/L ND 20 20 38.1 37.4 190 187 52-163 2 30 IK,IL, M1,v1 Chloroform ug/L ND 20 20 23.8 23.6 119 118 70-139 1 30 Chloromethane ug/L ND 20 20 24.4 24.6 122 123 41-139 1 30 cis-1,2-Dichloroethene ug/L ND 20 20 25.0 25.0 125 125 70-141 0 30 cis-1,3-Dichloropropene ug/L ND 20 20 22.6 22.6 113 113 70-137 0 30 Dibromochloromethane ug/L ND 20 20 20.4 20.3 102 101 70-134 1 30 Dibromomethane ug/L ND 20 20 20.5 20.4 103 102 70-138 1 30 Ethylbenzene ug/L ND 20 20 22.8 22.9 114 115 66-153 0 30 lodomethane ug/L ND 40 40 28.6 28.0 71 70 20-138 2 30 v3 Methylene Chloride ug/L ND 20 20 25.3 25.5 126 127 42-159 1 30 Styrene ug/L ND 20 20 22.8 22.5 114 113 70-135 1 30 Tetrachloroethene ug/L ND 20 20 20.7 21.2 103 106 59-143 3 30 Toluene ug/L ND 20 20 22.4 22.5 112 112 59-148 0 30 trans-1,2-Dichloroethene ug/L ND 20 20 26.2 26.4 131 132 70-146 1 30 trans-1,3-Dichloropropene ug/L ND 20 20 21.7 21.8 108 109 70-135 0 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 17.7 17.8 88 89 47-135 1 30 Trichloroethene ug/L ND 20 20 22.1 22.3 110 111 70-147 1 30 Trichlorofluoromethane ug/L ND 20 20 25.0 25.1 125 125 70-148 0 30 Vinyl acetate ug/L ND 40 40 50.8 49.8 127 125 49-151 2 30 Vinyl chloride ug/L ND 20 20 23.4 23.0 117 115 70-156 2 30 Xylene (Total) ug/L ND 60 60 68.8 69.3 115 115 63-158 1 30 1,2-Dichloroethane-d4 (S) % 115 116 70-130 4-Bromofluorobenzene (S) % 101 101 70-130 Toluene-d8 (S) % 102 103 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/02/2020 04:47 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 20 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALIFIERS Project: Surry Blanks Pace Project No.: 92483826 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. IL This analyte exceeded secondary source verification criteria low for the initial calibration. The reported results should be considered an estimated value. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/02/2020 04:47 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 20 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Surry Blanks Pace Project No.: 92483826 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92483826001 EB EPA 3010A 550337 EPA 6010D 550349 92483826002 FB EPA 3010A 550337 EPA 6010D 550349 92483826001 EB EPA 3010A 550340 EPA 6020B 550353 92483826002 FB EPA 3010A 550340 EPA 6020B 550353 92483826001 EB EPA 8260D 550875 92483826002 FB EPA 8260D 550875 Date: 07/02/2020 04:47 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 20 Document Name: Document Revised: February 7, 2018 Sample Condition Upon Recelpt(SCUR) Page 1 of 2 �C@A0001 Document No.: Issuing Authority: r F-CAR-CS•033-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ �iuntersville Raleigh[:] iVlechanitsdille❑ ConditionSample Client Name: PrQJeet #: WO# :92483826 Upon Receipt n 16, nS-eyvc-_' l! I Courier, ❑F c � []UPS CI USPS other: ❑Client ❑ Commercial a e ❑ 92463826 I 111I 1 Custody Seal Present? Des C i Seats Intact? Des o Zq I (�J T E Enln Contents _ J Pacidng Material: []Bubble Wrap ubble Sags []None ❑ Other Thermometer: 92TQ61 Type of Ice: W-t ❑ewe ❑IR Gun ID: Cooler Temp (°C): I - q %Correction Factor: Add/Subtract CQ +� Cooler Temp Corrected ("C): `� USDA Regulated Soil ( /A, water sample) Did samples originate in a quarantine sane within the United States: CA, NY, or SC )check maps)? Chain of Custady Present? samples Arrived within Hold Time? Short Hold Time Analysis j<72 hr.)? Rush Turn Around Time Requested? Sufficient Volume? Correct Containers Used? -Pace Containers Used? Containers Intact? Dissolved analysis: Samples Field Filtered? Heads ace in VOA Vials (>5-6mm)? Trip Blank Present? Trip Blank Custody Seals Present? COMMENTSISAMPLE DISCREPANCY ]No ❑N/A I 1• N []N/A 2, 3. go❑N/ON/A g4. A []No ❑NIA 5. [:]No ❑N/A 6. []No ❑N/A I1Nn l`INGd1 7. DateHnitlalsPerson Nam g Biological Tissue F zen? []yes []No /A []None Temp should be above freezing to VC ❑5arnples out of temptnteria. Samples an Ice, tooling process has begun Did samptes ariginate from a foreign source {internationally, includingNavra" and Puerto Rico!? Oyes []No Lot It) of spit containers: CLIENT NOTIFICATION/RESOLUTION Person contacted_ Project Manager SCURF Review: Project Manager SRF Review: Dateffime: Date: date:. Field Oata Required? []Yes ❑No Page 18 of 20 Document Name: Document Revised: February 7, 2018 aceAnalytical Sample Condition Upon Retelpt(5CUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, ORO/8015 (water) DOC, LLH8 **Bottom half of box is to list number of bottle Project It W4# a 92483826 PM: AMB Due Date: 07/13/20 CLIENT: 92-Municipal Qr z 'O 2 a c E N 0.O. m z Y] Z a c E o m z U Z a c E 7 G. ro a` a a n v a co _ f'V x O vi a E a _ ry v m o a E Y M a co Z a u ¢ a E V 0. coca x O a E V Q. n n e E 4 t7 u Z u a a E a rY 4 ry a E Q .i i7 4 ? v 2 n c E ¢ r E M V' d N v c O E v rl {:1 d _ N V x O N E 4 E M 0 4 ? U i a E o r�i m M 0 d � Z a O > E dl l;7 A ¢ rn NO a O 7 E M l7 7 C 2 7) ¢ O 7 E In s7 ] ? v p CL 2 a O E a) u 4 ? ran o `^ Ji a ° d p > - 9 Y a ° on U' � > ¢ A u E Ln a yr - m in E N N a, 0 _ gg = 2 Z a E Ln M a m z 76 Z c 'M b E 4 E C Q` 4 c o - c z E > T c c a E E D G 1 -� 1 ` I 3 4 5 6 -\ EN I N\\1a �z pH Adjustment tog for Preserved Samples Sample In Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot 0 Nate: Whenever there is a discrepancy affec[Irg North Carolina compilance samples, a copy of this form will be Sent to the North Carolina DFHNR Certification Office (i.e. Out of hold, Incorrect preservative, out of temp, Incorrect contalners. Page 19 of 20 En rn 0 z z A f z m C d D m m M a � n z Ell n n vLO z r m 2 A A D ' C m n TEMP in C Received on Ice (WN) ustL -orb Sealed Cooler (YIN) Samples Intact (YIN) 9 0 z n n 0 m z a ? M m O C to J = m ° W 'O z y G IC lb � C1� w la � ITEM # m m `a zrno'o SC � r m MATRIX CODE (see valid codes to loll) SAMPLE TYPE (G=GRAB C=COMP) . o D � En m D n J M Or m n m Z o K m SAMPLE TEMP AT COLLECTION 9 OF CONTAINERS Unpreserved H2SO4 HNO3 T HCI NaOH m Na2S203 m Methanol Other VOCs APP I Metals App I Residual Chtorine (YIN) S Q Q w 777 0 o 3 va° 3 a . (0 fp - f� N � -• O a n z � � 0 J a D n V ❑ � N � 3 ? � h m 3 m m 5 N O f N �s m � 3 � � o x � n' m N n m = 0A v— �' Z 0 0 C' 1l rn 1 a 0 N N O' 3 j O n K �C: 9 0 m n A d o M at 3 L7 0 m ,z N z r} � C7 n � N v CO a Q 0 m C n 0 a CD so rM n n n c or v CD c E v z o n R D J n a Page 20 of 20 Appendix B Field Sampling Parameter Data Sheet(s) le 1,11ghl".rhig 14, Samplers: rage.1_of 2 Project: Surry Co Subtitle D Lined MSWLF Sampling Parameters Water Quality Parameters (Stabilized) Depth to Depth to Goes Total Specific CH4 Monitoring Purge Purge Collect Collect Volume Depth Total DO Temp. Hardness :a Gas Water Sample Dry Water Point Date Time Date Time Purged During Measured Depth Comments (mg/L) ORP pH © Cond. (mg/L) Vapors gTOP) (BTOP Type ( ) g as Expected us/Cm ( (Gal) (%/vol) Static Collection Purge expected M W-1 -. 70.3 ''. a 26.74 MW-2 ( 1 7 1Ja MW-3R (�t 1 t/ 26 �n�� 22.1 MW-4S { . MW-4D ' 43.1� 48.5 MW-5 MW-6R 1 81.3 t a�F , 70.75Ile MW-8� %� _ MW-9SIf _� 42.28 _ ? , _ °� -� ,ee _ ,', _ _ 65,54 �d MW-9D 47.13 L MW-10 MW-11 S _. lee) , ; 46.05 a 65,31 -- — MW-11 D � _ 65 - MW-12 1 3634 MW-13- 93.5 MLW-A SW�D Ile, LAGOON i; = SS B=Stainless Steel Baler, D B=Disposable Baler, P=Low flow Pump, PD=Purged Dry VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear NR=No Reading Attempted, NS=No Sample Obtained Field Sampling Data Sheet Project: Surry Co Subtitle D Lined MSWLF Samplers: Page_2_of 2 Sampling Parameters Water Quality Parameters Total CH4. Monitoring Purge Purge Sample Sample Depth to Lab Volume Goes Depth Total Specific DO Temp. TDS Gas Water Parameters Sample Dry Point Date Time Date Time Purged Measured Depth Comments ORP pH © Cond. m /L Vapors During (mg/L) ( g ) pm (BTOP) to be (Gal) Type as Expected (us/cm for (pp ) Static analyzed Purge expected P-4 — — V/LR on13' — — — — — — — — — — — MW-28 _ _ WLR only P2-11 S - - ------ _. __ ..__- WLR only — — — — — — — — — — — — P2-11 D - - __-.. _......__,.a WLRonly — — — — — — — — — — — P2-12 — — — _. WLIZ only — — — — — — — — — — — — MW-26 — — WLR only SS B=Stainless Steel Baler, D B=Disposable baler, r=Low now rump, ru=rurgea Dry VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear NR=No Reading Attempted, NS=No Sample Obtained Project: Surry Co Closed C&D over Closed MSWLF & Active Subtitle D Lined- Mt. Airy (Shared Surface Waters �ampiers: Sampling Parameters Water Quality Parameters (Stabilized) _ Goes Total CH4 MonitoringCollect Collect Visual Lab Visual Sample D ry Depth DO Temp. Specific Hardness n Gas Point Date Time Flow Parameters to be Guag Durin Measured Comments (mg/L) ORP pH © Cond. (mg/L) g Vapors Rats, analyzed for e Ht• Type u as (us/cm Foods (ppm) J_ P ge expected I - - f SWN-1 I � or- SWN-2 I - - or I or *4 or SW-C r%`' I - - orator SS B=Stainless Steel Baler, D B=Disposable Baler, P=Low flow Pump, PD=Purged Dry VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear NR=No Reading Attempted, NS=No Samle Obtained p M i Ipnl knI Work Project: Surry Co. Lined MSWLF, Ph 4 (Pre -Operation Baseline #1) S�implers: Page_1_of 1 Purge Time Collect Date Collect Time Sampling Parameters Water Quality Parameters (Stabilized) Monitoring Point Purge Date Depth to Water (BTOP) Static Depth to Water (BTOP) Collection Volume Purged (Gal) Sample Type Goes Dry During Purge Total Depth Measured as expected Total Depth Expected (ft btoc) Comments DO (mg/L) ORP pH Temp. O S ecific p Cond. (us/cm CH4 Gas Vapors (%/pool) I ell lee 41.78 74.00 48.26 56.07 V ell Ie ell %�. M W 24 ell�� MW 25ell 1 MW-26 MW-27 ,. 83,48- "<E MW-28 SS 6=Stainless Steel Baler, D 6=Disposable Baler, P=Low flow Pump, PD=Purged Dry VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear NR=No Reading Attempted, NS=No Sample Obtained