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HomeMy WebLinkAbout5802_Madison_MSWLF_Sept20GW_FID1522027_20201230N.ft t1Y [-]PaperReport [:]Electronic Data -Email CD data loaded: Yes /Noy Doc/Event #: ' NC DENR Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: • Prepare one form for each individually monitored unit • Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(1). Send the original signed and sealed fonn, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Anchor QEA of North Carolina, PLLC Contact for questions about data formatting. Include data preparers name, telephone number and E-mail address: Name: Alec Macbeth E-mail: amacbeth(cDanchoraea.com Facility name: Facility Address: Madison County Closed Solid 389 Long Branch Road Waste Facility Marshall, NC 28753 Environmental Status: (Check all that apply) Initial/Background Monitoring ❑X Detection Monitoring Type of data submitted: (Check all that apply) p( Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells I Leachate monitoring data X� Surface water monitoring data Phone: 850-240-5263 NC Landfill Rule: Facility Permit # (.0500 or .1600) 58-02 .0500 ❑ Assessment Monitoring ❑ Methane gas monitoring data Corrective action data (specify) Other(specify) Actual sampling dates (e.g., October 20-24, 2006) ctober 6 and 7, 2019 Corrective Action Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the Informatbin reported and statements made on this data submittal and attachments are true and correct Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment Alec Macbeth, PG Projec tGeologis t Facility Representative Name (Print) Title OL-0_'� a z & , 7' -7-, `c 828-281-3350 (Area Code) Telephone Number December 30, 2020 Affix NC Licensed/ Professional Geologist Seal Signature Date 231 Haywood Street Asheville, North Carolina 28806 Facility Representative Address P-1649 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 December 2020 Madison County Closed Solid Waste Facility, Permit No. 58-02 ti9 ANCHOR QEA Fall 2020 Semiannual Water Quality Monitoring Report Prepared for Madison County, North Carolina December 2020 Madison County Closed Solid Waste Facility, Permit No. 58-02 Fall 2020 Semiannual Water Quality Monitoring Report Prepared for Madison County, North Carolina Post Office Box 579 Marshall, North Carolina 28753 Alec Macbeth, PG Prepared by Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Number: C01500-01.01 \\ashevillel\Asheville\Projects\Madison County\Reports\2020\Fall\58-02 - Closed\Text\5802_Madison Closed_October 2020 Semiannual Water Quality Report_121520.docx TABLE OF CONTENTS 1 Introduction 2 Methods 1 2 2.1 Monitoring Well Sampling Methods...........................................................................................................2 2.1.1 Monitoring Wells MW-01 OLD and BG SPRING OLD...........................................................2 2.1.2 Monitoring Wells MW-02 OLD, MW-03 OLD, and MW-04 OLD......................................2 2.2 Surface Water Sampling Methods................................................................................................................3 2.3 Sample Handling, Documentation, and Analysis....................................................................................3 3 Findings........................................................................................................................................5 3.1 Groundwater.........................................................................................................................................................6 3.1.1 Field Parameters..................................................................................................................................6 3.1.2 RCRA Metals..........................................................................................................................................6 3.1.3 Appendix I VOCs and 1,4-Dioxane...............................................................................................6 3.2 Surface Water.......................................................................................................................................................7 3.2.1 Field Parameters..................................................................................................................................7 3.2.2 RCRA Metals..........................................................................................................................................7 3.2.3 Appendix I VOCs and 1,4-Dioxane...............................................................................................7 3.3 Site Hydrogeology..............................................................................................................................................7 4 Summary......................................................................................................................................9 4.1 Future Activities...................................................................................................................................................9 5 References.................................................................................................................................10 TABLES Table 1 Summary of Laboratory Analyses Performed on Samples Table 2 Summary of Detected Constituents FIGURES Figure 1 Site Location Map Figure 2 Sample Location Map APPENDICES Appendix A Sampling Logs and Equipment Documentation and Instrument Calibration Data Sheets Appendix B Report of Laboratory Analysis and Chain -of -Custody Documentation Fall 2020 Semiannual Water Quality Monitoring Report i December 2020 ABBREVIATIONS µg/L micrograms per liter µS/cm microsiemens per centimeter Closed Landfill closed municipal solid waste landfill DEQ North Carolina Department of Environmental Quality DO dissolved oxygen DWM Division of Waste Management EPA U.S. Environmental Protection Agency IMAC interim maximum allowable concentration MDL method detection limit mg/L milligrams per liter MRL method reporting limit mV millivolt NCAC North Carolina Administrative Code NTU nephelometric turbidity unit ORP oxidation-reduction potential RCRA Resource Conservation and Recovery Act SC specific conductivity SESD EPA Region 4 Science and Ecosystem Support Division SU standard unit SWS Solid Waste Section TOC top of well casing VOC volatile organic compound Fall 2020 Semiannual Water Quality Monitoring Report ii December 2020 Introduction The Madison County Solid Waste Department maintains a closed municipal solid waste landfill (Closed Landfill), located near the intersection of U.S. Highway 25/70 Bypass and Long Branch Road (State Route 1582) in Madison County, North Carolina. The site location is presented in Figure 1. The Closed Landfill is permitted by the North Carolina Department of Environmental Quality (DEQ), Division of Waste Management (DWM), under Permit No. 58-02 (the permit), which requires semiannual monitoring of groundwater and surface water quality. This report, prepared by Anchor QEA of North Carolina, PLLC, is being submitted in accordance with monitoring requirements for the Closed Landfill as stipulated in the permit, with regulations codified in the DEQ Solid Waste Management Rules, Title 15A, Subchapter 13B, Section .1600 of the North Carolina Administrative Code (15A North Carolina Administrative Code [NCAC] 13B .1600). This report describes the second semiannual groundwater and surface water quality monitoring event performed in 2020. The water quality monitoring network for the Closed Landfill consists of four monitoring wells (MW-01 OLD, MW-02 OLD, MW-03 OLD, and MW-04 OLD), a background groundwater quality sampling location (BG SPRING OLD), and two surface water sampling locations (SW-01 OLD [upstream] and SW-02 OLD [downstream]) located along Profitt Branch (Figure 2). Monitoring wells MW-03 OLD and MW-04 OLD are installed in bedrock near the top of a ridge in the western part of the landfill parcel. Monitoring wells MW-01 OLD and MW-02 OLD are at lower elevations within topographic drainages in the southern part of the landfill parcel and are screened in the upper saturated zone. The water sample collected from background sampling location BG SPRING OLD is treated as a groundwater sample for the following reasons: • Groundwater does not discharge to the ground surface at the sampling point. • Construction of the sampling point is similar to that of a temporary monitoring well and is located upslope and upgradient of a springhead. • The sampling point consists of a polyvinyl chloride (PVC) casing extending below ground surface with a screened interval from which groundwater is collected and recharges. Anchor QEA personnel attempted to contact the resident of the property owned by Mrs. J.V. Edwards (99 Log Branch Road, Marshall, North Carolina) but were unsuccessful. Because of the unsuccessful attempt to contact the Mrs. Edwards, coupled with COVID-19 concerns, Anchor QEA did not collect a sample from the residential well (DW-01) owned by Mrs. Edwards during the fall 2020 sampling event. Anchor QEA will coordinate with Madison County to ensure contact with the Edwards family for the Spring 2021 sampling event. Fall 2020 Semiannual Water Quality Monitoring Report 1 December 2020 2 Methods Groundwater samples and a surface water sample were collected at the Closed Landfill by Anchor QEA personnel on October 6 and 7, 2020. 2.1 Monitoring Well Sampling Methods Prior to groundwater sample collection from the monitoring wells, the static water level was measured and recorded to calculate the volume of water within the well. At each sample location, an initial round of field parameters (consisting of pH, specific conductivity [SC], dissolved oxygen [DO], oxidation-reduction potential [ORP], turbidity, and temperature) was measured and recorded. Water level measurements, field parameters, and observations pertaining to water quality are included in the sampling logs in Appendix A. 2.7. 7 Monitoring Well BG SPRING OLD Following initial field parameter collection, sampling point BG SPRING OLD was purged using a new disposable polyethylene bailer due to poor well access, which inhibited the use of pump, controller, and associated tubing. As each consecutive well volume was removed with the bailer, an additional round of groundwater parameters was recorded. The well was purged until a minimum of three well volumes had been removed and field parameters had stabilized, or until the well had been bailed dry. All groundwater samples were collected by a technician wearing a new pair of non -reactive nitrile gloves. Each sample was placed directly into laboratory -supplied sample containers. 2. 7.2 Monitoring Wells MW-01 OLD, MW-02 OLD, MW-03 OLD, and MW-04 OLD Monitoring wells MW-01 OLD and MW-02 OLD were purged and sampled with a peristaltic pump. MW-03 OLD and MW-04 OLD were purged and sampled with a bladder pump. These wells were purged using low -flow techniques in accordance with the procedures described in Low -Flow (Minimal Drawdown) Ground -Water Sampling Procedures (Puls and Barcelona 1996). During purging, pH, SC, DO, ORP, turbidity, and temperature were measured and recorded approximately every 3 minutes. Well purging continued until these parameters had stabilized for three consecutive readings. The following required stabilization criteria have been established by the U.S. Environmental Protection Agency (EPA) Region 4 Science and Ecosystem Support Division Operating Procedure: Groundwater Sampling (EPA SESD 2017): • pH values within ± 0.1 unit • SC values within ± 5% Fall 2020 Semiannual Water Quality Monitoring Report 2 December 2020 • Temperature, DO, and turbidity values within ± 10% Following stabilization of these parameters, a groundwater sample was collected by a technician wearing a new pair of non -reactive nitrile gloves. Each sample was placed directly into laboratory -supplied sample containers. 2.2 Surface Water Sampling Methods Surface water samples SW-01 OLD and SW-02 OLD are collected semiannually at designated locations along Profitt Branch, which flows adjacent to the Closed Landfill's southern boundary in a westerly direction (Figure 2). The surface water sample collected at the SW-01 OLD location is interpreted to represent surface water quality upstream of the Closed Landfill, and the surface water sample collected at the SW-02 OLD location is interpreted to represent surface water quality downstream of the Closed Landfill. For the samples SW-01 OLD and SW-02 OLD, field parameters, including temperature, pH, SC, DO, ORP, and turbidity were measured and recorded at the surface water sampling location prior to sample collection (Appendix A). The one surface water sample was collected and transferred into laboratory -supplied sample containers by a technician wearing a new pair of non -reactive nitrile gloves. 2.3 Sample Handling, Documentation, and Analysis Field parameters and additional observations pertaining to water quality sampling at the Closed Landfill sampling locations are provided in the sampling logs in Appendix A. Following sample collection, groundwater and surface water samples were immediately placed on ice in sample coolers for transport to Waypoint Laboratories, Inc. (Waypoint), a laboratory certified in North Carolina and located in Charlotte, North Carolina. Anchor QEA submitted all collected groundwater and surface water samples to Waypoint for the following analyses: • Appendix I volatile organic compounds (VOCs), using EPA Method 8260B — Appendix I parameters are identified in Appendix I of the Code of Federal Regulations, Title 40, Part 258 (40 Code of Federal Regulations 258). • 1,4-Dioxane, using EPA Method 8260SIM • Eight Resource Conservation and Recovery Act (RCRA) metals, using EPA Methods 6010D and 7470A — In addition to this "totals" metal analysis, if the associated turbidity was measured at a value that exceeded 10 nephelometric turbidity units (NTU), the laboratory was Fall 2020 Semiannual Water Quality Monitoring Report 3 December 2020 requested to filter the associated sample, run the metals analysis, and report the dissolved metal concentrations (in addition to the total metals analysis) • Hardness, using EPA method SM2340C; surface water samples only A summary of laboratory analyses performed on the samples is provided in Table 1. One trip blank, provided by the laboratory and stored in the sample cooler, was analyzed for Appendix I VOCs. Proper chain -of -custody documentation procedures were followed during collection and transport of each sample. The laboratory analytical reports and chain -of -custody documentation are included in Appendix B. Fall 2020 Semiannual Water Quality Monitoring Report 4 December 2020 3 Findings The field parameter data and laboratory analytical results for the groundwater, surface water, and trip blank samples collected at the Closed Landfill are included in Appendices A and B, respectively, and are also submitted separately to the DEQ DWM Solid Waste Section (SWS) in the Electronic Data Deliverable format (DEQ 2020). All laboratory analytical results were reported and appropriately qualified as follows: • Non -Detections: Non -detections are values reported by the laboratory as "below method detection limits (MDLs)" and are flagged with a "U" qualifier in Table 2. The MDL is the minimum concentration of a substance that can be measured and reported by a laboratory with 99% confidence that the constituent concentration is greater than zero. • Estimated or "J" Qualified: A "Y' qualifier is used by the laboratory for parameters that are detected at estimated concentrations greater than the MDL but less than the laboratory's method reporting limit (MRL). The MRL is the minimum concentration of a target analyte that can be accurately determined by the referenced method. • "CCVL" Qualified: A "CCVL" qualifier is used by the laboratory for parameters that are less than control limits but within method parameters. These results are reported but considered estimated. • Groundwater Quality Standards: Detected concentrations of constituents in groundwater samples were compared to applicable North Carolina groundwater quality standards. For most constituents, this standard is the 2L standard, defined in 15A NCAC 02L .0202. Detected concentrations of analytes in groundwater with no established 2L standard were compared to the interim maximum allowable concentrations (IMAC) for Class GA and GSA groundwater (in accordance with 15A NCAC 02L .0202). For the purposes of this report, groundwater standards were taken from the October 15, 2018 list published by the North Carolina SWS (DEQ 2018). • 2B Standard: Detections of analytes in surface water samples were compared to the surface water quality standards described in 15A NCAC 02B (213 standards). Hardness -dependent 2B surface water standards were calculated using the average analyzed hardness value (calculated from the upstream and downstream surface water sampling location results) via the most stringent hardness -dependent metal calculation. Table 2 summarizes the field parameter results and laboratory analytical results for detected constituents. The following discussion outlines constituents detected at concentrations that exceeded their respective groundwater quality standards or 2B standards. Fall 2020 Semiannual Water Quality Monitoring Report 5 December 2020 3.1 Groundwater The following sections summarize the results of field parameter and laboratory analyses of groundwater samples collected on October 6 and 7, 2020. 3. 7.1 Field Parameters The pH reading obtained from monitoring well MW-01 OLD (6.20 standard units [SU]) was less than the range for pH (6.5 to 8.5 SU) specified in the 2L standard (Table 2). The pH readings obtained from monitoring wells MW-02 OLD, MW-03 OLD, MW-04 OLD, and BG-SPRING OLD (6.61 to 6.89 SU) were within the 2L standard. Turbidity in the monitoring wells ranged from 5.21 NTU in monitoring well MW-03 OLD to 23 NTU in BG SPRING OLD. Measured DO values ranged from 0.99 milligrams per liter (mg/L) in MW-01 OLD to 5.37 mg/L in MW-02 OLD. SC values ranged from 180 microsiemens per centimeter (pS/cm) in BG SPRING OLD to 983 pS/cm in MW-03 OLD. ORP values in the monitoring wells ranged from -99.5 millivolts (mV) in MW-03 OLD to 149.6 mV in MW-02 OLD (Table 2). These parameters do not have established groundwater quality standards. The measured concentrations of field parameters are generally consistent with historical concentrations. 3.1.2 RCRA Metals Five metals (arsenic, barium, cadmium, chromium, and lead) were detected in groundwater samples collected from one or more monitoring wells (Table 2). Only one of these metals, barium, was detected at concentrations that exceeded its associated groundwater protection standard of 700 micrograms per liter (pg/L). These exceedances occurred in the samples collected from MW-03 OLD (790 pg/L) and MW-04 OLD (750 pg/L). These findings are consistent with recent historical data: in spring 2020, barium exceedances were reported in MW-03 OLD and MW-04 OLD, as well as an exceedance of chromium in BG SPRING OLD. Samples collected from BG SPRING OLD and MW-04 OLD were analyzed for laboratory -filtered metals due to turbidity readings of greater than 10 NTU. In the samples collected and analyzed for dissolved metals, only barium was detected at concentrations that exceeded the associated MDLs with concentration very similar to total barium in both locations. 3.1.3 Appendix 1 VOCs and 1,4-Dioxane Twelve VOCs (1,1-dichloroethane; 1,2-dichlorobenzene; cis-1,2-dichloroethene; trans-1,2- dichloroethene; 1,4-dichlorobenzene; 1,4-dioxane; acetone; benzene; chlorobenzene; chloroethane; tetra hyd rofuran; and vinyl chloride) were detected in groundwater samples collected from one or more of the monitoring wells (Table 2). Of the detected compounds, two (1,4-dioxane and vinyl chloride) were detected at concentrations that exceeded the associated groundwater quality Fall 2020 Semiannual Water Quality Monitoring Report 6 December 2020 standard. Both of these exceedances occurred in a single monitoring well, MW-01 OLD. 1,4-Dioxane was detected at 7 pg/L, which exceeded its 2L standard of 3 pg/L, and vinyl chloride was detected at 0.91 pg/L, which exceeded its 2L standard of 0.03 pg/L. The VOC detections are generally consistent with recent historical data. During the spring 2020 sampling event, vinyl chloride was also reported in MW-01 OLD at an estimated concentration (0.41 pg/L) that exceeds its 2L standard. 1,4-Dioxane was detected in MW-01 OLD, but at a concentration (2.6 pg/L) less than the associated 2L standard. Benzene, detected in spring 2020 at 2 pg/L in exceedance of its 2L standard (1 pg/L) in MW-03 OLD, was detected at 0.78 pg/L in the well during the current sampling event (Anchor QEA 2020). 3.2 Surface Water The following sections summarize the results of laboratory and field parameter analyses of surface water samples SW-01 OLD and SW-02 OLD. 3.2. 7 Field Parameters The pH readings collected from SW-01 OLD and SW-02 OLD were 7.93 and 8.42 SU, respectively. The readings were within the 2B standard range established at 6 to 9 SU. The turbidity readings collected from SW-01 OLD and SW-02 OLD were 9.26 and 9.80 NTU, respectively. The readings were within the 2B standard established of less than 50 NTU. The DO readings collected from SW-01 OLD and SW-02 OLD were 9.94 and 11.74 mg/L, respectively. The values are within the 2B standard for Class C waters (greater than or equal to 5 mg/L). The SC measurements in SW-01 OLD and SW-02 OLD were recorded at 195.9 and 177.1 pS/cm, respectively. The ORP values for these samples were recorded at 84.9 and 72.9 mV (Table 2). These parameters do not have established surface water quality standards. 3.2.2 RCRA Metals Four metals (arsenic, barium, chromium, and lead) were detected in the surface water samples. There were no detections that exceeded 2B standards in either of the surface water samples. 3.2.3 Appendix 1 VOCs and 1,4-Dioxane No VOCs were detected in either of the surface water samples. 3.3 Site Hydrogeology Groundwater levels were measured in the four monitoring wells, MW-01 OLD, MW-02 OLD, MW-03 OLD, and MW-04 OLD, at the Closed Landfill at depths of 5.95, 7.4, 41.7, and 42.7 feet below the top of the well casing (TOC), respectively (Appendix A). Fall 2020 Semiannual Water Quality Monitoring Report 7 December 2020 The spatial distributions and screened intervals of the monitoring wells at the Closed Landfill prohibit an accurate calculation of groundwater flow direction. However, within the upper saturated zone, the shallow groundwater is interpreted to generally mimic topography, flowing primarily southward toward Profitt Branch. The Closed Landfill is situated on the southwest side of a knoll with an elevation of approximately 2,100 feet above mean sea level and slopes downward toward Profitt Branch. Fall 2020 Semiannual Water Quality Monitoring Report 8 December 2020 4 Summary Anchor QEA completed the second semiannual water quality monitoring event of 2020 at the Closed Landfill on October 6 and 7, 2020. Table 1 summarizes the sampling and analyses that were performed. Table 2, the field sampling logs (Appendix A), and the Waypoint Reports of Laboratory Analysis (Appendix B) provide detailed analytical results and field data related to groundwater and surface water quality at the Closed Landfill. The following bullets summarize the results of the sampling event: • The detected concentration of barium exceeded its 2L standard of 700 pg/L in the samples collected from two of the monitoring wells, MW-03 OLD (790 pg/L) and MW-04 OLD (750 pg/L). • Two VOCs, 1,4-dioxane (7 pg/L) and vinyl chloride (0.91 J pg/L) were detected in the samples collected from MW-03 OLD at concentrations exceeding the associated groundwater quality standards (2L standards). • In the surface water samples, no metals were detected at concentrations that exceeded the associated 2B standards. No VOCs were detected in the surface water samples. • The measured depths to groundwater in the upper saturated zone within the topographic drainages at the landfill ranged from 5.95 to 7.4 feet below TOC. The groundwater depths in the bedrock monitoring wells at top of the ridge ranged from 41.7 to 42.7 feet TOC. The shallow groundwater is interpreted to generally mimic topography, flowing primarily southward toward Profitt Branch. 4.1 Future Activities Anchor QEA will continue to measure field parameters and collect water quality samples from groundwater and surface water monitoring points associated with the Closed Landfill. Water quality samples will be submitted to a North Carolina -certified laboratory for analysis of RCRA metals and Appendix I VOCs, including 1,4-dioxane, on a semiannual basis. The next sampling event is scheduled for March 2021. Fall 2020 Semiannual Water Quality Monitoring Report 9 December 2020 5 References Anchor QEA (Anchor QEA of North Carolina, PLLC). 2020. Spring 2020 Semiannual Water Quality Monitoring Report, June. DEQ (North Carolina Department of Environmental Quality), 2018. "Groundwater Protection Compliance Standards — Constituents List". Last modified October 15, 2018. Available at: https://edocs.deq.nc.gov/WasteM a nag ement/0/edoc/1257181/SWS EnviroMonitoring Const ituents List.pdf?searchid=13f8efbl-eel 1-485a-b03f-718f2287b271 DEQ, 2020. Memorandum Re: New Electronic Data Deliverable (EDD) Format, July 20, 2020. EPA SESD (U.S. Environmental Protection Agency Science and Ecosystem Support Division), 2017. Operating Procedure: Groundwater Sampling. April 26, 2017. Puls, R.W., and M.J. Barcelona, 1996. Low -Flow (Minimal Drawdown) Ground -Water Sampling Procedures. Prepared for the U.S. Environmental Protection Agency, Office of Solid Waste and Emergency Response. EPA/540/5-95/504. April 1996. Fall 2020 Semiannual Water Quality Monitoring Report 10 December 2020 Tables Table 1 Summary of Laboratory Analyses Performed on Samples Groundwater Samples Facility Permit Well ID Collect Date Sample ID Appendix I VOCs 1,4-Dioxane RCRA Metals EPA 8260B EPA 8260B SIM EPA 6020B EPA 7470A 58-02 MW-01 OLD 10/06/2020 MW-01 OLD-20201006 X X X 58-02 MW-02 OLD 10/06/2020 MW-02 OLD-20201006 X X X 58-02 MW-03 OLD 10/06/2020 MW-03 OLD-20201006 X X X 58-02 MW-04 OLD 10/06/2020 MW-04 OLD-20201006 X X X1 58-02 BG SPRING OLD 10/07/2020 BG SPRING OLD-20201007 X X X1 Surface Water Samples Facility Permit Location ID Collect Date Sample ID Appendix I VOCs 1,4-Dioxane RCRA Metals Total Hardness EPA 8260B EPA 8260B SIM EPA 6020B EPA 7470A EPA SM 2340C 58-02 SW-01 OLD 10/07/2020 SW-01 OLD-20201007 X X X X 58-02 SW-02 OLD 10/07/2020 SW-02 OLD-20201007 X X X X Quality Control Samples Facility Permit ID Collect Date Sample ID Appendix I VOCs EPA 8260B 58-02 TRIP BLANK 10/07/2020 TB-202010070000 X Notes: Analyses include Appendix I constituents per the Code of Federal Regulations (40 CFR Part 258). A sample could not be collected from the Edwards's residence domestic water supply sample, DW-01 OLD, during this sampling event. In addition to this "totals" metal analysis, the laboratory was requested to filter the associated sample, run the metals analysis, and report the dissolved metal concentrations EPA: U.S. Environmental Protection Agency RCRA: Resource Conservation and Recovery Act SM: standard method SIM: selective ion monitoring VOC: volatile organic compound Fall 2020 Semiannual Water Quality Monitoring Report Page 1 of 1 Madison County Closed Municipal Solid Waste Landfill, Permit Number 58-02 December 2020 Table 2 Summary of Detected Constituents Location ID Sample ID Sample Date Sample Type Matrix NC2L Method NC21- IMAC NC2B Groundwater Samples Surface Water Samples QC Sample BG SPRING OLD MW-01 OLD MW-02 OLD MW-03 OLD MW-04 OLD SW-01 OLD SW-02 OLD Field QC BG SPRING OLD- 20201007 MW-01 OLD- 20201006 MW-02 OLD- 20201006 MW-03 OLD- 20201006 MW-04 OLD- 20201006 SW-01 OLD- 20201007 SW-02 OLD - 20201007 TB-202010070000 10/7/2020 10/6/2020 10/6/2020 10/6/2020 10/6/2020 10/7/2020 10/7/2020 10/7/2020 N N N N N N N TB WG WG WG WG WG WS WS WQ Field Parameters Water Level Depth (feet TOC) Field Measure 8.94 5.95 7.40 41.70 42.70 -- -- Temperature (°C) Field Measure 16.2 16.1 20.9 16.1 24.3 12.6 12.4 -- Dissolved oxygen (mg/L) Field Measure >_5.0 2.44 0.99 5.37 1.55 1.59 9.94 11.74 -- ORP (mV) Field Measure 41.3 -41.8 149.6 -99.5 34.6 84.9 72.9 -- Turbidity (NTU) Field Measure <50 23.0 8.57 5.39 5.21 13.2 9.26 9.80 pH (SU) Field Measure 6.5-8.5 6.0-9.0 6.67 6.20 6.61 6.89 6.83 7.93 8.42 Specific Conductivity ([is/cm) Field Measure 180 908 233 983 876 195.9 177.1 -- Other Hardness as CaCO3 SM2340C -- -- -- -- -- 56 54 -- Metals, Total (Ng/L) Arsenic SW6020 10 10 0.17 U 0.71 J 0.17 U 0.17 U 0.21 J 0.23 J 0.17 U -- Barium SW6020 700 21000 130 490 57 790 750 83 42 -- Cadmium SW6020 2 * 0.27 0.16 U 0.16 U 0.16 U 0.16 U 0.27 J 0.16 U 0.16 U -- Chromium SW6020 10 *45.42 1.0 J 0.79 U 0.79 U 0.79 U 2.2 1.4 J 0.79 U -- Lead SW6020 15 * 1.30 0.30 J 0.26 U 0.26 U 0.26 U 1.5 0.85 J 0.26 U -- Metals, Dissolved (Ng/L) Barium SW6020 21000 130 -- -- -- 650 -- -- -- Volatile Organics (Ng/L) 1,1-Dichloroethane SW8260 6 100 0.083 U 0.79 0.67 0.32 J 0.083 U 0.083 U 0.083 U 0.083 U 1,2-Dichlorobenzene SW8260 20 0.076 U 0.7 0.076 U 0.83 0.34 J 0.076 U 0.076 U 0.076 U 1,2-Dichloroethene, cis- SW8260 70 720 0.056 U 2.9 0.056 U 1.8 0.33 J 0.056 U 0.056 U 0.056 U 1,2-Dichloroethene, trans- SW8260 100 4000 0.094 U 0.33 J 0.094 U 0.094 U 0.094 U 0.094 U 0.094 U 0.094 U 1,4-Dichlorobenzene SW8260 6 1 56 0.050 U 5.6 0.050 U 4.2 1.6 0.050 U 0.050 U 0.050 U 1,4-Dioxane SW8260 3 0.14 U 7 0.14 U 0.14 U 0.14 U 0.14 U 0.14 U -- Acetone SW8260 6000 2000 0.31 U 0.31 U 2.0 J 0.66 J 2.0 J 0.31 U 0.31 U 1.9 J Benzene SW8260 1 51 0.048 U 0.85 0.048 U 0.78 0.28 J 0.048 U 0.048 U 0.048 U Chlorobenzene SW8260 50 140 0.062 U 4.1 0.062 U 5.7 3.6 0.062 U 0.062 U 0.062 U Chloroethane SW8260 3000 0.22 U 0.22 U 0.22 U 0.81 0.64 0.22 U 0.22 U 0.22 U Ethylbenzene SW8260 600 97 0.061 U 0.061 U 0.061 U 0.21 J 0.061 U 0.061 U 0.061 U 0.061 U m,p-X lene SW8260 500 550 0.12 U 0.12 U 0.39 J 0.12 U 0.36 J 0.12 U 0.12 U 0.12 U o-Xylene SW8260 500 400 0.044 U 0.044 U 0.044 U 0.044 U 0.22 J 0.044 U 0.044 U 0.044 U Tetrahydrofuran SW8260 1.1 U 1.1 U 1.1 U 1.1 U 1.9 J 1.1 U 1.1 U 1.1 U Toluene SW8260 600 0.36 0.044 U 0.044 U 0.044 U 0.044 U 0.23 J 0.044 U 0.044 U 0.044 U Total Xylene SW8260 0.15 U 0.15 U 0.39 J 0.15 U 0.58 J 0.15 U 0.15 U 0.15 U Trichloroethene (TCE) SW8260 3 30 0.078 U 0.27 J 0.078 U 0.43 J 0.078 U 0.078 U 0.078 U 0.078 U Vinyl chloride SW8260 0.03 2.4 0.097 U 0.91 0.097 U 0.097 U 0.097 U 0.097 U 0.097 U 0.097 U Fall 2020 Semiannual Water Quality Monitoring Report Page 1 of 2 Madison County Closed Municipal Solid Waste Landfill, Permit Number 58-02 December 2020 Table 2 Summary of Detected Constituents Notes: Detected concentration is greater than NC2L (2013) or IMAC (2013) screening level Detected concentration is greater than NC213 screening level Bold: Detected result Italicized: Non -detected concentration is above one or more identified screening levels *: NC213 surface water standard calculated using average analyzed hardness value (calculated from the upstream and downstream sampling location results) via the most stringent hardness -dependent metal calculation, per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2B - Surface Water and Wetland Standards (last amended September 2017). µg/L: micrograms per liter NC2B: surface water standard per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2B — Surface Water and Wetland Standards (last amended in September 2017), or the standard obtained from the EPA Nationally Recommended Water Quality Criteria for Aquatic Life and Human Health. NC2L: Subchapter 2L — Groundwater Classifications and Standards, Department of Environmental Quality (Amended April 1, 2013). Groundwater standard from North Carolina Administrative Code, Title 15A. All nondetect results are reported at the method detection limit. Appendix I: indicates volatile organic compounds and metals per 40 Code of Federal Regulations Part 258 Horizontal coordinate datum is NAD 1983 State Plane North Carolina FIPS 3200 (U.S. Survey Feet). °C: degrees Celsius µg/LL micrograms per liter µs/cm: microsiemens per centimeter CCVL: laboratory qualfier used to indicate results that are below control limits but within method parameters. These results are reported but considered estimated. CaCO3: calcium carbonate IMAC: Interim Maximum Allowable Concentration. IMAC concentrations are listed in Appendix #1 of the 2L. J: laboratory qualifier used to indicate a detection at estimated concentrations greater than the minimum detection limit (MDL) but less than the laboratory's method reporting limit (MRL) mg/L: milligrams per liter mV: millivolts N: normal environmental sample NTU: nephelometric turbidity unit ORP: oxidation-reduction potential SU: standard unit TB: Trip Blank TOC: top of casing U: Compound analyzed for, but not detected above detection limit WG: groundwater WS: surface water WQ: water quality Fall 2020 Semiannual Water Quality Monitoring Report Page 2 of 2 Madison County Closed Municipal Solid Waste Landfill, Permit Number 58-02 December 2020 Figures t• ': � �� � woe :.�\ � � o - LEGEND: SOURCES: Basemap: USGS 1:24,000 Scale Topo Maps, "000 Landfill Parcel Marshall Quadrangle, 1990 Parcels: Madison County GIS Feet Publish Date: 2020/11/02, 1:55 PM I User: alesueur Filepath:\\orcas\gis\Jobs\MadisonCounty_NC_1500\Maps\2020\FallWaterQuality\AQ_F01_SiteLocationMap_ClosedLF_FaIIWQ2020.mxd kzANCHOR Figure 1 QEA-- Site Location Map Anchor QEA of North Carolina, PLLC Fall 2020 Semiannual Water Quality Report Madison County Closed Municipal Solid Waste Landfill, Permit No. 58-02 w IF a '< ties g � MW-03 OLD LEGEND: NOTE: Monitoring well and surface water samples are Monitoring Well Location 0 Landfill Parcel Boundary approximate. 0 Elevation Contours Residential Well Location (10-Foot Interval) SOURCES: (Not Sampled in Spring 2020 Basemap: NC OneMap 2018 because Owner Could Not — Roads Contours and Roads: NCDOT 0 400 be Contacted) — Streams Streams: NC OneMap Parcel Boundary: Madison County GIS - Surface Water Sample Location Feet Publish Date: 2020/11/02, 2:03 PM I User: alesueur Filepath:\\orcas\gis\Jobs\MadisonCounty_NC_1500\Maps\2020\FallWaterQuality\AQ_F02_SampleLocationMap_ClosedLF_Fal IWQ2020.mxd ANCHOR Figure 2 QEA�`�.;" Anchor QEA of North Carolina, PLLC Sample Location Map Fall 2020 Semiannual Water Quality Report Madison County Closed Municipal Solid Waste Landfill, Permit No. 58-02 Appendix A Sampling Logs and Equipment Documentation and Instrument Calibration Data Sheets ANCHOR QEA . , A Sampling Log b6W Flow Date: b ✓f Well Name: MW-01 OLD Project Name: Madison County Landfill - Closed Project Number. of Goo -ii)l `► Weather: �jA-1*,bs Sampling Personnel: Sample Time: � - 1 940 Well Information: Well Depth in Feet (WD): 20.8 Well Diameter: 2" Water Level in Feet (WL): Type of Casing: PVC Length of Water Column: feet 40 Screen Interval: -- (WD) - (WL) = (LWC) Flush Mount ick-Up One Casing Volume: gallons 1 1 Comments: (LWC) x (WCV r i®_- V WW - Three Casin umes: gallonsP ' Tagged bottom 5 r'I Actual Volume Purged: a I ar gallons i via^' at _ .� Well Casing Volumes (WCV) 1" = 0.041 Gal/Ft 2" = 0.17 Gal/Ft 3" = 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" = 1.5 Gal/Ft 8".7_�.6-Gn17Ff " = 5.8 Gal/Ft Purge Method: 'sp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Bailer -Teflon Dedicated Pump Whale Pump Grundfos ner: Cher: xi ion Sample Method: ' r-Di rwM5Ws Temp Dissolved Specific Cond. pH (S.U.) Reduction Turbidity . Reading Time ed (°C) Oxygen (mg/L) (NS/cm) report to 0.1 S.U. Potential (m1) (NTU) Comments 1 CG I Ito S 3 • i iT l 4 y a`7 , o 5 I �E e�//- y Q-�i1 Stc?- 8 9 10 Notes: Samples are analyzed immediately upon collection. "C: degrees Celsius pS/cm: micro-Siemen per centimeter mg/L: milligrams per liter mv: millivolt NTU: nephelometric turbidity units S.U: Standard Units Protective Casing: Pad: Lock: f Vegetation: J J Access: / —piing Personnel Signature: M-M Date: Vo k i I N r well information and sampling data has been verified well was tagged after sampling was complete � ti3.5 L ANCHOR Lv QEA Low -Flow Sampling Log Date: Well Name: MW-02 OLD Project Name: Madison County Landfill - Closed Project Number: l_(d 5 00 —O O Location: Marshall, NC Personnel:` Weather: Well Information: Screen Interval: d11.L1`(/Iggluys/� bgs Arrive at Well: 11 Depth to Water:ALE toc Start Time: (� Well Diameter: 2 in Sample Time: Pump Intake:,,3$ ^'f®f(k- toc Finish Sample Time: 112mo Drawdown Set: i0 j toc Leave Well: Pump Used (circle): Bladder Peristaltic Other (description): Comments: Purge Rate: Tagged bottom at: R�� j(� Total Purge Volume: Pump Speed: -`I-LW VKt'rnQ,1n -- �p Time DTW (feet) Temp CC) DO (mg/L) Specific Cond. (PS) pH (S.U.) report to 1. ORP (mv) Turbidity (NTU) Comments I� i l ✓, -F?r /0. te S! ``tl 1 `. jas (�y W xry V J Y 0 N5 to.. r .(, Time between recharge during sample collection: Sampling Personnel Signature: Date: Notes: Stabilization 3 successive readings, 3 minutes apart:� y� 'j`'�JV,p/ within +/- 70% DO and turbidity,, +/- 3% Conductivity; +/- 0.7 PH unit; +/- 10 mV for ORP 1 • •t P \ � ` from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2010) Samples are analyzed immediately upon collection. pS: micro-Siemen mv: millivolt °C: degrees Celsius NTU: nephelometric turbidity units bgs: below ground surface ORP: oxidation reduction potential DO: dissolved oxygen S.U.: standard units mg/L: milligrams per liter toc: top of casing initial if well information and sampling data has been verified 1� well was tagged after sampling was complete ANCHOR QEA u Low -Flow Sampling Log Date: tot V7 v Well Name: MW-03 OLD Project Name: Madison County Landfill - Closed Project Number: Location: Marshall, NC Personnel: ��t[� Weather:Lh S Well Information: Screen Interval: 4449 bgs Arrive at Well:I 4M Depth to Water: qt.:" toc Start Time: I q t g- Well Diameter: 2 in Sample Time: t I?'(p Pump Intake: 45 toc Finish Sample Time: (4'?Q Drawdown Set: '� toc Leave Well: 14 S e Pump Used (circle): Peristaltic Bladder Other (description): Comments: Ns1 Purge Rate: `j,��j M Tagged bottom at: , J � �* j7jr{� Total Purge Volume: Pump Speed: drys Time DTW (feet) Temp VQ DO (mg/L) Specific Cond. OAS) pH (S.U.) report to 0.7. ORP Turbidity (NTU) Corpments �a(mv) t Time between recharge during sample collection: Sampling Personnel Signature: Date: toW n Notes: V Stabilization 3 successive readings, 3 minutes apart: within +/- 10% DO and turbidity,' +/- 3% Conductivity, +/- 0.7 PH unit; +/- 70 mV for ORP from EPA - Low -Flow (Minimal Drowdown) Groundwater Sampling Procedures, April 1996 (Rev 2010) Samples are analyzed immediately upon collection. pS: micro-Siemen mv: millivolt °C: degrees Celsius NTU: nephelometric turbidity units bgs: below ground surface ORP: oxidation reduction potential DO: dissolved oxygen S.U.: standard units mg/L: milligrams per liter toc: top of casing initial if well information and sampling data has been verified well was tagged after sampling was complete ANCHOR QEA' Low -Flow Sampling Log Date: t0i (01.3v Well Name: MW-04 OLD Project Name: Madison County Landfill - Closed Project Number: C6115 60 - 0l' -01 Location: Marshall, NC Personnel:�� �� Weather: 7WL S Well Information: Screen Interval: 70-90 bgs Arrive at Well: Depth to Water: Pao toc Start Time: L3 31� Well Diameter: 2 in Sample Time: I ! LOI Pump Intake: 80 toc Finish Sample Ti e { 95 !� Drawdown Set: LISA.61toc Leave Well:—e Pump Used (circle): Peristaltic Bladder Other (description): Comments: Purge Rate: (,�d k%A Jf%AAh Tagged bottom at:Lq�), 04; :{ PY Total Purge Volume: Pump Speed: (cam [ij$ I Time DTW (feet) Temp VQ DO (mg/L) Specific Cond. (PS) pH (S.U.) ORP report to 0.7. (m1) Turbidity (NTU) Comments 3�U11 0 _aalt >C70 it, A 0411 �S_^ . •�Y� do 0/+�, 5 (�Jiu.�y j� —\ -00 • V (/ems G. �S 'Z6 r r� /(��q V(i.d 1 3 i � 3.50 70 69 3,W2 r - 43 It4 g 1sLf i Time between recharge during sample collection: Sampling Personnel Signature: Date: �v c., — r Notes: Stabilization 3 successive readings, 3 minutes apart: within +/- 70% DO and turbidity,, +/- 3% Conductivity; +/- 0.7 pH unit; +/- 70 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2010) Samples are analyzed immediately upon collection. pS: micro-Siemen mv: millivolt °C: degrees Celsius NTU: nephelometric turbidity units bgs: below ground surface ORP: oxidation reduction potential DO: dissolved oxygen S.U.: standard units mg/L: milligrams per liter toc: top of casing initial if well information and sampling data has been verified well was tagged after sampling was complete w ANCHOR .-� QEA vwell Sampling Log Date: (VJ—f) -?r^ Well Name: BG-SPRING OLD Project Name: Madison County Landfill - Closed Project Number. lot ;00—t)ixi _ Weather: b 05 Sampling Personnel: Sample Time: Well Information: Well Depth in Feet (WD): 14.3 Well Diameter: 2" Water Level in Feet (WL): L1it Type of Casing: PVC Length of Water Column: S. _ feet Screen Interval: - (WD) - (WL) = (LWC) Flush Mount Stick-U One Casing Volume: gallons Comments: �ylciLle— yKia j 1W vI10W (LWC) x (WCV) Three Casing Volumes: gallons Tagged q a bottom �"[ Q_• 0; Actual Volume Purged: �. �. , gallons at: t J� --• •- _ Well Casing Volumes (WCV) 1" = 0.041 GaVFt 2" = 0.17 Gal 3" = 0.3B Gal/Ft 4" = 0-66 Gal/Ft 6" = 1-5 Gal/Ft 8" _ 16 Gai/Ft 12" = 5.8 Gal/Ft JI Purge Method: Baller-Disp- Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other. Sample Method: Bailer-Dis Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other: Oxidation Temp Dissolved Specific Cond. pH (S.U.) Reduction Turbidity IGallons Reading Time Purged (r°C) Ox..y.r7ge%ni (mg/L) (NS/cm) report to 0.1 S.U. Potential (m1) (NTU) Comments 3 . 4 ti 5 6 7 8 9 10 Notes: Samples are analyzed immediately upon collection. 'C: degrees Celsius pS/cm: micro-Siemen per centimeter mg/L: milligrams per liter mV: millivolt F.+ NTU: nephelometric turbidity units S.U.: Standard Units Protective Casing: OE Pad: 4W Lock: Vegetation: Access: �a(npling Personnel Signature: ` � If/ /1 Date: (O I initial if well information and sampling data has been verified 4 well was tagged after sampling was complete ANCHOR surface Water Sampling Log Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name: Madison County Landfill - Closed Project Number. (G 6DsIDIA Sampling Personnel:�.•�} Sample Name: SW-01 OLD Comments: S �y� y+r Date: Weather: I (_ O i Ck-LWsjygaw . Of 1-40'yed' - Sample Method: Grab Syringe Pump Bailer-Disp. Other: Time Temp (°C) Dissolved Oxygen (mg/L) Specific Cond. pH (S.U.) (PS/cm) report to 0.1 S.U. Oxidation Reduction Potential (m1) Turbidity (NTU) Comments )013 Sampling Container Number of Containers Requested Analysis 300 mL Plastic 250 mL Plastic wZAv� �5 125 mL Plastic IF 40 mL Glass 1 L Glass Other Vegetation: �- Lhato Sampling Personnel Signature: Notes: Samples are analyzed immediately up.W °C: degrees Celsius pS/cm: micro-Siemen per cubic centimeter mg/L: milligrams per liter mv: millivolt NTU: nephelometric turbidity units S.U.: standard units Access: t) Date: Q ll Method Reference: Temperature: SM 2550 B-2010 Specific conductivity: EPA Method 120.1, Rev. 1982 DO: SM 4500 O G-2011 PH: SM 4500-H ` B-2011 Page 1 of 1 ANCHOR nE A `urface Water Sampling Log Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name: Madison County Landfill - Closed Project Number. pd n� . U Sampling Personnel: W Sample Name: SW-02 OLD Comments:miA&tc Date: (N�/ Weather: !" los -1 �' Sample Method: Grab Syringe Pump Bailer-Disp. Other. Time Temp (°C) Dissolved Oxygen (mg/L) Specific Cond. (PS/cm) pH (S.U.) report to 0.15.U. Oxidation Reduction Potential (m1) Turbidity (NTU) Comments Sampling Container Number of Containers Requested Analysis .00 mL Plastic 250 mL Plastic,AC�1r/lX 125 mL Plastic 40 mL Glass `L C UU0 s t—& ��ff//V 1 L Glass Other Vegetation: a V y r I - Sampling Personnel Signature: Notes: Samples are analyzed immediately upon collection. °C: degrees Celsius pS/cm: micro-Siemen per cubic centimeter mg/L: milligrams per liter mV: millivolt NTU: nephelometric turbidity units S.U.: standard units Access: S-d?p )0ArK'--- Date: to l �r I N Method Reference: Temperature: SM 2550 B-2010 Specific conductivity: EPA Method 120.1, Rev. 1982 DO: SM 4500 O G-2011 PH: SM 4500-H' B-2011 Page 1 of 1 ANCHOR �.� t'11C A v bi�:�'1 �..irLi .urface Water Sampling Log Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name: Project Number. Sampling Personnel: Sample Name: Comments: Madison County Landfill - Closed 6/D 1— , 4: )r_Yrh�e7-? -1,0 1 r DW-01 OLD kAJOU— -H CJ`Q.t4u Date: Weather: Sample Method: Grab Syringe Pump Bailer-Disp. Other. Time Temp (°C) Dissolved Oxygen (mg/L) Specific Cond. pH (S.U.) (PS/cm) report to 0.1 S.U. Oxidation Reduction Potential (mV) Turb' ' TU) Comments Sampling Container Number of Containers i Requested Analysis ,00 mL Plastic r 250 mL Plastic 125 mL Plastic 40 mL Glass 1 L Glass Other Vegetation: Access: Sampling Personnel Signature: Date: Notes: Method Reference: Samples are analyzed immediately upon collection. °C: degrees Celsius pS/cm: micro-Siemen per cubic centimeter mg/L milligrams per liter mv: millivolt NTU: nephelometric turbidity units S.U: standard units Temperature: SM 2550 B-2010 Specific conductivity: EPA Method 120.1, Rev. 1982 DO: SM 4500 O G-2011 pH: SM 4500-H' B-2011 Page 1 of 1 ANCHOR "Z QEA Equipment Documentation and Instrument Calibration Data Sheet Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 CALIBRATION DOCUMENTATION Project Name: Madison County Operating Landfill Person Conducting Calibration: Project Number: ��I�DU� h(. 1 Date of Calibration: ,J� it) `- Project Location: Marshall, NC _ Date of Field Measurements: 1ZE) EQUIPMENT DOCUMENTATION Rental sample analysis equipment or meters used to take measurements: Equipment T pe Brand Serial Number Date of Use Rental Company Select Turbidimeter: Hach 2100Q (s/n 151006045207) HF Scientific MicroTPW (s/n 200601045) Instrument Reading Instrument Reading (Hach 2100Q) (HF Scientific MicroTPW) 10 NTU 20 NTU 100 NTU 800 NTU 1,000 NTU 10.0 NTU 0.02 NTU Calibration Expiration j ( i( Z1 (i 'ZI-- Date: Cal: `c -• f /I Cal: j Cal: Cal--` Cal: Cal: Time:GiG / r L TimeV� 7 C�Q Time:? C.So Time: Time: _ Time: Calibration *Pre -Analysis Meat: �t Time, � *Pre -Analysis Meas: Timms Verification: Check (10 NTU): u / Check (10 NTU): *Post -Analysis Meas: Time: *Post -Analysis Meas: Time: - Check 00 NTU): Check (10 NTU): YSI Professional Plus Multiparameter Meter (s/n 18B101802) Instrument Readings Calibration Lot No. & Expiration Date Dissolved Oxygen Ini$�'al: i `% 7- Cal: 1 o0i Q 1 mmHg: 766,57 Temperature (°C): a D1 Time: g3�r. it H 7 S.U. In' r� pHmV: P Cal 4,0o pHmV: p Ti e: p Z� report to 0.7 S.U. V Cr p PH 4 S.U. Initial: 4, 1 pHmV: Cal•, /) 0 pHmV: Time: L I i F/z report to 0.1 S.U. i V O pH 10 S.U. In' i iy'�I f'� 1V 1T pHmV: Cal- 0 „^ 00 pHmV: Ti g:� report to 0.1 S.U. 1 , QC* pH 7 S.U. report A Time: 1 " Z Meas•% �/ �/ Mid Day Time: Check: PM Time: Check: to 0.7 S.U. Spec. Cond. 100a Initial: `7y�f Cal: i00U Time: $1`f 3z1 /cm QC*: (000 AM Time: Meas: Mid Day Time: Check: PM Time: Check: h - iiioLf ps/cm % Recovery= ORP 2-0d Q mV Initi�l � 1 Cal: ( Z � (1 Temperature (°C): ff cc==((�1� 'Time; , 5'r(µ0/ G i Signature: Date: 10 L - Notes: Revision 3, 04/30/20, MHF 1. Electronic equipment calibrated according to the manufacturer's operation manual. 2. Specific Conductivity should be calibrated according to values representative of historic range. 3.Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, pH 10, DO, ORP, QC checks. 4. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated. 5. * QC check must be performed prior to sampling and following completion of sampling, at a minimum. 6. % Recovery = (Value Obtained, pS/cm + True Value, pS/cm) x 100 Method Reference: Temp: SM 2550 B-2070 I Conductivity. EPA Method 720.7 1 DO: SM 4500 0 G-2017 I pH: SM 4500-H+B-2011 I Turbidity: SM 2730 B-2017 Page 1 of 1 ANCHOR QEA Equipment Documentation and Instrument Calibration Data Sheet Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 CALIBRATION DOCUMENTATION Project Name: Madison County Closed Landfill Person Conducting Calibration: Project Number: Lb ��jU)—pL of Date of Calibration: Project Location: Marshall, NC Date of Field Measurements: EQUIPMENT DOCUMENTATION Rental sample analysis equipment or meters used to take measurements: Hach 2100Q (s/n 151006045207) HF Scientific MicroTPW (s/n 200601045) Instrument Reading Instrument Reading (Hach 2100Q) (HF Scientific MicroTPW) 10 NTU 20 NTU 100 NTU 800 NTU 1,000 NTU 10.0 NTU 0.02 NTU Calibration Expiration Date: Cal: y Cal: Lit 9 Cal: - Cal: Cal: Cal: Time: flg ` 1 Time: Time:® Time: Time: Time: Calibration *Pre -Analysis Meas, Time: 'Pre -Analysis Meas: Time: Verification: Check (10 NTU): i t Check (10 NTU): *Post -Analysis Meas:g� Time:_ )�,.. *Post -Analysis Meas: Time: Check (10 NTU): U Check (10 NTU): YSI Professional Plus Multiparameter Meter (s/n 1813101802) Instrument Readings Calibration Lot No. St Expiration Date Dissolved Oxygen Initial: � j /) r � , . lVim/ Cal: �,"I, O a� C mmHg: Temperaturerc): 1 Time: ! PH 7 S.U. Initial: pHmV: Cal: pHmV: Time:¢D 0 y� report to 0.1 S.U. .�5(� 4 t PH 4 S.U. Initial- pHmV: Cal: q.0 pHmV: Time: fi report to 0.1 S.U.y - I � . pH 10 S.U. Initial:r. `®c pHmV: Cal: 16. o pHmV: Tim report to 0.1 S.U. V. QC* pH 7 S.U. report AM Time: Mess: Mid Day Time: Check: PM Time: Check: to 0.7 S.U. 0 6 a Spec. Cond. k ()�0 Initial: Cal, Time: �o0 U ?� QC*: AM Time: Meas: Mid Day Time: Check: PM Time: Check: y� a a 1 PS/Cm t % Recovery= ORP�mV Initial: e Cal:��� , Temperature (°C): Time.:ry w Signature: Date: lb Notes: LI/ Revision 3, 04/30/20, MHF 1. Electronic equipment calibrated according to the manufacturer's operation manual. 2. Specific Conductivity should be calibrated according to values representative of historic range. 3. Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, pH 10, DO, ORP, QC checks. 4. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated. 5. * QC check must be performed prior to sampling and following completion of sampling, at a minimum. 6. % Recovery = (Value Obtained, pS/cm + True Value, pS/cm) x 100 Method Reference: Temp: SM 2550 B-2070 I Conductivity EPA Method 120.7 1 DO: SM 4500 O G-2077 I pH: SM 4500-H+B-2011 I Turbidity: SM 2730 B-2077 Page 1 of 1 MW- MV01 Mw-f Mvt- -Bcys' sw®. SW'( CHAIN OF CUSTODY RECORD ONLY Waypoint-WPAGE I OF L QUOTE # TO ENSURE PROPER BILLING: YES NO N/A clo��Samples V1/tAroject INTACT upon arrival?Project ANALYTICAL 449 Spione7 brook4/529 Road • Charlotte, NC 28217Short 704/529-8364 •Fax: 704/525-0409 Name: t ►' l• .UST Project: Yes No y1�"" 1 ( ) ( Hold Anal si�ific Received IN ICE? PROPER PRESERVATIVES indicated?Phone *Please ATTACH an reporting (QC LEVEL 1 II III MT Received WITHIN HOLDING TIMES? Client Company Name: I r �C provisions and/or QC Requirements CUSTODY SEALS INTACT? Report To/Contact Na...-. Z MaLloetin Invoice To: d VOLATILES rec'd W/OUT HEADSPACE? Reporting Address: i St _„s., Address: PROPER CONTAINERS used? TEMP: Therm ID: Observed °C /Corr. °C Phone:-913350 Fax (Yes)(No): 4 Purchase Order No./Billing Reference Cd S00--01t)l 'T UZ TO BE FILLEDIN BY CL�NT/SAMPLING PERSONNEL Email Address: G_ww_a.Cbf� a�14►� CdV✓� Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days Certification: NC SC EDD Type: PDF Excel —Other "Working Days" ❑ 6-9 Days A-efandard 10 days ❑ Rush Work Must Be _ / r� Pre Approved Site Location Name: I�dt� li'j�✓,in�h�Ce�� �h"�— Samples received after 15:00 will be processed next business dayp Turnaround is Other N/A �� Site Location Physical Address: 1 v 1Gt.KLr Shy ,W - time based on business days, excluding weekends and holidays. Water Chlorinated: YES NO (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES RENDERED BY WAYPOINT ANALYTICAL, LLC TO CLIENT) / Samples Iced Upon Collection: YES."'NO NO TIME MATRIX SAMPLE CONTAINER ANA YSIS REQUES D c- �*' CLIENT DATE SAMPLE DESCRIPTION COLLECTED COLLECTED MILITARY (SOIL, WATER, OR *TYPE PRESERVA- TIVES /f� REMARKS ID NO. HOURS SLUDGE) SEE BELOW NO. SIZE a vix'itrxs r ,90 al ow-742 ICD(o [D) G, AV 23(o WA1-fIJO ,07, 0u0-7,cam (00to,1c� Co 14(0 OL17-202v1i30(o (0 (0 109 ' _%07o to ;lv tW 3 i�xx mC1 0 �- - t0 T � b131 207;ID0-J- i®1 % 7 �' Ili Cd� (i'� ,l tic i llL. Zvl�-2o2oro (o I©00 � �� g t 3��9 01 - wQo?-000d 1 7 0xv 4 qw- C/I or Sampler's Signature Sampled By (Print Name) Affiliation _LAB USE ONLY Upon relinquishing, fr Is Chain of Custody is your authorization for Waypoint Analytical to proceed with the analyses as requested above. Any changes must be Site Arrival Time: submitted in writing to the Waypoint Analytical Project Manager. There will be charges for any changes after analyses have been initialized. Relinquished By: (Signature) Received By: (Signature) Date Military/Hours Additional Comments: Site Departure Time: Relinquished By: (Signature) Received By: (Signature) Date Field Tech Fee: Relinquished By: (Signature) Received For Waypoint Analytical By: Date Mileage: Method of Shipment: NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WITH CUSTODY SEALS FOR TRANSPORTATION TO THE LABORATORY. COC Group No. SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST COC UNTIL RECEIVED AT THE LABORATORY. 0 Fed Ex ❑ UPS ❑ Hand -delivered ❑ Waypoint Analytical Field Service ❑ Other_ NPDES: UST: GROUNDWATER: DRINKING WATER: SOLID WASTE: RCRA: BRWNFLD LANDFILL OTHER: ❑NC❑SC ❑NC ❑SC ❑NC ❑SC ❑NC ❑SC ❑NC ❑SC ❑NC ❑SC ❑NC ❑SC ❑NC ❑SC ❑NC ❑SC ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ORIGINAL *CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) Appendix B Report of Laboratory Analysis and Chain -of -Custody Documentation Way poi nt ANALYTICAL Anchor QEA of North Carolina, PLLC Alec Macbeth 231 Haywood Street Asheville, NC 28801 NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Project: Madison Closed Landfill Lab Submittal Date: 10/08/2020 Work Order: 0100081 Case Narrative 11 /23/20 10:05 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Please call if you have any questions relating to this analytical report. Respectfully, WAYPOINT ANALYTICAL a,j Angela D. Overcash Senior Project Manager Data Qualifiers Key Reference: CCVL CCV result is below control limits but within method parameters. A standard at or below the RL was analyzed and found acceptable. Result is reported but considered estimated. J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag). L Parameter reported with possible low bias. LCS recovery below the QC limit. M Matrix spike outside of the control limits. MI Matrix spike outside of the control limits. Matrix interference suspected. PS Post Spike recovery is outside of the control limits. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 35 0Sample Waypoi nt.. ANALYTICAL Receipt Summary 11/23/2020 Work Order: 0100081 Client Sample ID Lab Sample ID Matrix Date/Time Sampled Date/Time Received MW-01 OLD 20201006 0100081-01 Water 10/06/20 12:36 10/08/20 7:45 MW-02 OLD 20201006 0100081-02 Water 10/06/20 11:46 10/08/20 7:45 MW-03 OLD 20201006 0100081-03 Water 10/06/20 14:26 10/08/20 7:45 MW-04 OLD 20201006 0100081-04 Water 10/06/20 13:43 10/08/20 7:45 BG SPRING OLD 20201007 0100081-05 Water 10/07/20 9:31 10/08/20 7:45 SW-01 OLD 20201007 0100081-06 Water 10/07/20 10:13 10/08/20 7:45 SW-02 OLD 20201007 0100081-07 Water 10/07/20 10:00 10/08/20 7:45 TB-202010070000 0100081-08 Water 10/07/20 0:00 10/08/20 7:45 Samples were received in good condition at 2.1 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 35 Way poi nt ANALYTICAL Summary of Detections 11/23/202C Work Order: 0100081 Prism ID Client ID Parameter Method Result Units 0100081-01 MW-01 OLD 20201006 Arsenic 6020B 0.71 J ug/L 0100081-01 MW-01 OLD 20201006 Barium 6020B 490 ug/L 0100081-01 MW-01 OLD 20201006 1,1-Dichloroethane 8260D 0.79 ug/L 0100081-01 MW-01 OLD 20201006 1,2-Dichlorobenzene 8260D 0.70 ug/L 0100081-01 MW-01 OLD 20201006 1,4-Dichlorobenzene 8260D 5.6 ug/L 0100081-01 MW-01 OLD 20201006 Benzene 8260D 0.85 ug/L 0100081-01 MW-01 OLD 20201006 Chlorobenzene 8260D 4.1 ug/L 0100081-01 MW-01 OLD 20201006 cis-1,2-Dichloroethylene 8260D 2.9 ug/L 0100081-01 MW-01 OLD 20201006 trans-1,2-Dichloroethylene 8260D 0.33 J ug/L 0100081-01 MW-01 OLD 20201006 Trichloroethylene 8260D 0.27 J ug/L 0100081-01 MW-01 OLD 20201006 Vinyl chloride 8260D 0.91 ug/L 0100081-01 MW-01 OLD 20201006 1,4-Dioxane 8260D SIM 7.0 ug/L 0100081-02 MW-02 OLD 20201006 Barium 6020B 57 ug/L 0100081-02 MW-02 OLD 20201006 1,1-Dichloroethane 8260D 0.67 ug/L 0100081-02 MW-02 OLD 20201006 Acetone 8260D 2.0 CCVL, ug/L J 0100081-02 MW-02 OLD 20201006 m,p-Xylenes 8260D 0.39 J ug/L 0100081-02 MW-02 OLD 20201006 Xylenes, total 8260D 0.39 J ug/L 0100081-03 MW-03 OLD 20201006 Barium 6020B 790 ug/L 0100081-03 MW-03 OLD 20201006 1,1-Dichloroethane 8260D 0.32 J ug/L 0100081-03 MW-03 OLD 20201006 1,2-Dichlorobenzene 8260D 0.83 ug/L 0100081-03 MW-03 OLD 20201006 1,4-Dichlorobenzene 8260D 4.2 ug/L 0100081-03 MW-03 OLD 20201006 Acetone 8260D 0.66 CCVL, ug/L J 0100081-03 MW-03 OLD 20201006 Benzene 8260D 0.78 ug/L 0100081-03 MW-03 OLD 20201006 Chlorobenzene 8260D 5.7 ug/L 0100081-03 MW-03 OLD 20201006 Chloroethane 8260D 0.81 ug/L 0100081-03 MW-03 OLD 20201006 cis-1,2-Dichloroethylene 8260D 1.8 ug/L 0100081-03 MW-03 OLD 20201006 Ethylbenzene 8260D 0.21 J ug/L 0100081-03 MW-03 OLD 20201006 Trichloroethylene 8260D 0.43 J ug/L 0100081-04 MW-04 OLD 20201006 Barium 6020B 650 ug/L 0100081-04 MW-04 OLD 20201006 Arsenic 6020B 0.21 J ug/L 0100081-04 MW-04 OLD 20201006 Barium 6020B 750 ug/L 0100081-04 MW-04 OLD 20201006 Cadmium 6020B 0.27 J ug/L 0100081-04 MW-04 OLD 20201006 Chromium 6020B 2.2 ug/L 0100081-04 MW-04 OLD 20201006 Lead 6020B 1.5 ug/L 0100081-04 MW-04 OLD 20201006 1,2-Dichlorobenzene 8260D 0.34 J ug/L 0100081-04 MW-04 OLD 20201006 1,4-Dichlorobenzene 8260D 1.6 ug/L 0100081-04 MW-04 OLD 20201006 Acetone 8260D 2.0 CCVL, ug/L J 0100081-04 MW-04 OLD 20201006 Benzene 8260D 0.28 J ug/L 0100081-04 MW-04 OLD 20201006 Chlorobenzene 8260D 3.6 ug/L 0100081-04 MW-04 OLD 20201006 Chloroethane 8260D 0.64 ug/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 35 (D Way po 0nt. ANALYTICAL Summary of Detections 11 /23/202C Work Order: 0100081 Prism ID Client ID Parameter Method Result Units 0100081-04 MW-04 OLD 20201006 cis-1,2-Dichloroethylene 8260D 0.33 J ug/L 0100081-04 MW-04 OLD 20201006 m,p-Xylenes 8260D 0.36 J ug/L 0100081-04 MW-04 OLD 20201006 o-Xylene 8260D 0.22 J ug/L 0100081-04 MW-04 OLD 20201006 Tetrahydrofuran 8260D 1.9 .1 ug/L 0100081-04 MW-04 OLD 20201006 Toluene 8260D 0.23 J ug/L 0100081-04 MW-04 OLD 20201006 Xylenes, total 8260D 0.58 J ug/L 0100081-05 BG SPRING OLD 20201007 Barium 6020B 130 ug/L 0100081-05 BG SPRING OLD 20201007 Barium 6020B 130 ug/L 0100081-05 BG SPRING OLD 20201007 Chromium 6020B 1.0 J ug/L 0100081-05 BG SPRING OLD 20201007 Lead 6020B 0.30 .1 ug/L 0100081-06 SW-01 OLD 20201007 Hardness SM2340 C 56000 ug/L 0100081-06 SW-01 OLD 20201007 Arsenic 6020B 0.23 J ug/L 0100081-06 SW-01 OLD 20201007 Barium 6020B 83 ug/L 0100081-06 SW-01 OLD 20201007 Chromium 6020B 1.4 J ug/L 0100081-06 SW-01 OLD 20201007 Lead 6020B 0.85 J ug/L 0100081-07 SW-02 OLD 20201007 Hardness SM2340 C 54000 ug/L 0100081-07 SW-02 OLD 20201007 Barium 6020B 42 ug/L 0100081-08 TB-202010070000 Acetone 8260D 1.9 CCVL, ug/L J This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 35 Way poi nt.. ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Project: Madison Closed Landfill Sample Matrix: Water Laboratory Report 11 /23/2020 Client Sample ID: MW-01 OLD 20201006 Sample ID: 0100081-01 Work Order: 0100081 Time Collected: 10/06/20 12:36 Time Submitted: 10/08/20 07:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Total Metals Mercury <0.034 ug/L 0.2 0.20 0.034 1 7470A 10/9/20 15:27 EDV POJ0152 Arsenic 0.71 J ug/L 10 1.0 0.17 1 6020B 10/12/20 20:35JAB POJ0164 Barium 490 ug/L 100 2.0 0.81 1 6020B 10/12/20 20:35JAB POJ0164 Cadmium <0.16 ug/L 1 1.0 0.16 1 6020B 10/12/20 20:35JAB POJ0164 Chromium <0.79 ug/L 10 2.0 0.79 1 6020B 10/12/20 20:35JAB POJ0164 Lead <0.26 ug/L 10 1.0 0.26 1 6020B 10/12/20 20:35JAB POJ0164 Selenium <0.74 ug/L 10 5.0 0.74 1 6020B 10/12/20 20:35JAB POJ0164 Silver <0.11 ug/L 10 1.0 0.11 1 6020B 10/12/20 20:35JAB POJ0164 Volatile Organic Compounds by GC/MS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260D 10/17/20 3:00 JLB POK0376 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260D 10/17/20 3:00 JLB POK0376 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260D 10/17/20 3:00 JLB POK0376 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/17/20 3:00 JLB POK0376 1,1-Dichloroethane 0.79 ug/L 5 0.50 0.083 1 8260D 10/17/20 3:00 JLB POK0376 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260D 10/17/20 3:00 JLB POK0376 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260D 10/17/20 3:00 JLB POK0376 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260D 10/17/20 3:00 JLB POK0376 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260D 10/17/20 3:00 JLB POK0376 1,2-Dichlorobenzene 0.70 ug/L 5 0.50 0.076 1 8260D 10/17/20 3:00 JLB POK0376 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/17/20 3:00 JLB POK0376 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260D 10/17/20 3:00 JLB POK0376 1,4-Dichlorobenzene 5.6 ug/L 1 0.50 0.050 1 8260D 10/17/20 3:00 JLB POK0376 Acetone <0.31 ug/L 100 5.0 0.31 1 8260D 10/17/20 3:00 JLB POK0376 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260D 10/17/20 3:00 JLB POK0376 Benzene 0.85 ug/L 1 0.50 0.048 1 8260D 10/17/20 3:00 JLB POK0376 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260D 10/17/20 3:00 JLB POK0376 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/17/20 3:00 JLB POK0376 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260D 10/17/20 3:00 JLB POK0376 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260D 10/17/20 3:00 JLB POK0376 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260D 10/17/20 3:00 JLB POK0376 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260D 10/17/20 3:00 JLB POK0376 Chlorobenzene 4.1 ug/L 3 0.50 0.062 1 8260D 10/17/20 3:00 JLB POK0376 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260D 10/17/20 3:00 JLB POK0376 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260D 10/17/20 3:00 JLB POK0376 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260D 10/17/20 3:00 JLB POK0376 cis-1,2-Dichloroethylene 2.9 ug/L 5 0.50 0.056 1 8260D 10/17/20 3:00 JLB POK0376 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 35 Laboratory Report A i • .0 11 /23/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: MW-01 OLD 20201006 Attn: Alec Macbeth Sample ID: 0100081-01 231 Haywood Street Work Order: 0100081 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/06/20 12:36 Time Submitted: 10/08/20 07:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260D 10/17/20 3:00 JLB POK0376 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260D 10/17/20 3:00 JLB POK0376 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260D 10/17/20 3:00 JLB POK0376 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260D 10/17/20 3:00 JLB POK0376 m,p-Xylenes <0.12 ug/L NE 1.0 0.12 1 8260D 10/17/20 3:00 JLB POK0376 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260D 10/17/20 3:00 JLB POK0376 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260D 10/17/20 3:00 JLB POK0376 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260D 10/17/20 3:00 JLB POK0376 Methyl Isobutyl Ketone <1.0 ug/L 100 5.0 1.0 1 8260D 10/17/20 3:00 JLB POK0376 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260D 10/17/20 3:00 JLB POK0376 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260D 10/17/20 3:00 JLB POK0376 Styrene <0.047 ug/L 1 0.50 0.047 1 8260D 10/17/20 3:00 JLB POK0376 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260D 10/17/20 3:00 JLB POK0376 Tetrahydrofuran <1.1 ug/L NE 10 1.1 1 8260D 10/17/20 3:00 JLB POK0376 Toluene <0.044 ug/L 1 0.50 0.044 1 8260D 10/17/20 3:00 JLB POK0376 trans-1,2-Dichloroethylene 0.33 J ug/L 5 0.50 0.094 1 8260D 10/17/20 3:00 JLB POK0376 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260D 10/17/20 3:00 JLB POK0376 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260D 10/17/20 3:00 JLB POK0376 Trichloroethylene 0.27 J ug/L 1 0.50 0.078 1 8260D 10/17/20 3:00 JLB POK0376 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/17/20 3:00 JLB POK0376 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260D 10/17/20 3:00 JLB POK0376 Vinyl chloride 0.91 ug/L 1 0.50 0.097 1 8260D 10/17/20 3:00 JLB POK0376 Xylenes, total <0.15 ug/L 5 1.5 0.15 1 8260D 10/17/20 3:00 JLB POK0376 Surrogate Recovery Control Limits 4-Bromofluorobenzene 104 % 80-124 Dibromofluoromethane 104 % 75-129 Toluene-d8 105 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane 7.0 ug/L 10 2.0 0.14 1 8260D SIM 10/8/20 12:48 JLB POJ0116 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 6 of 35 . Laboratory Report • � Waynt.� 11 /23/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: MW-02 OLD 20201006 Attn: Alec Macbeth Sample ID: 0100081-02 231 Haywood Street Work Order: 0100081 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/06/20 11:46 Time Submitted: 10/08/20 07:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Total Metals Mercury <0.034 ug/L 0.2 0.20 0.034 1 7470A 10/9/20 15:38 EDV POJ0152 Arsenic <0.17 ug/L 10 1.0 0.17 1 6020B 10/12/20 20:07JAB POJ0164 Barium 57 ug/L 100 2.0 0.81 1 6020B 10/12/20 20:07JAB POJ0164 Cadmium <0.16 ug/L 1 1.0 0.16 1 6020B 10/12/20 20:07JAB POJ0164 Chromium <0.79 ug/L 10 2.0 0.79 1 6020B 10/12/20 20:07JAB POJ0164 Lead <0.26 ug/L 10 1.0 0.26 1 6020B 10/12/20 20:07JAB POJ0164 Selenium <0.74 ug/L 10 5.0 0.74 1 6020B 10/12/20 20:07JAB POJ0164 Silver <0.11 ug/L 10 1.0 0.11 1 6020B 10/12/20 20:07JAB POJ0164 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260D 10/17/20 3:25 JLB POK0376 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260D 10/17/20 3:25 JLB POK0376 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260D 10/17/20 3:25 JLB POK0376 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/17/20 3:25 JLB POK0376 1,1-Dichloroethane 0.67 ug/L 5 0.50 0.083 1 8260D 10/17/20 3:25 JLB POK0376 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260D 10/17/20 3:25 JLB POK0376 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260D 10/17/20 3:25 JLB POK0376 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260D 10/17/20 3:25 JLB POK0376 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260D 10/17/20 3:25 JLB POK0376 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260D 10/17/20 3:25 JLB POK0376 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/17/20 3:25 JLB POK0376 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260D 10/17/20 3:25 JLB POK0376 1,4-Dichlorobenzene <0.050 ug/L 1 0.50 0.050 1 8260D 10/17/20 3:25 JLB POK0376 Acetone 2.0 CC ug/L 100 5.0 0.31 1 8260D 10/17/20 3:25 JLB POK0376 VL, J Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260D 10/17/20 3:25 JLB POK0376 Benzene <0.048 ug/L 1 0.50 0.048 1 8260D 10/17/20 3:25 JLB POK0376 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260D 10/17/20 3:25 JLB POK0376 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/17/20 3:25 JLB POK0376 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260D 10/17/20 3:25 JLB POK0376 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260D 10/17/20 3:25 JLB POK0376 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260D 10/17/20 3:25 JLB POK0376 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260D 10/17/20 3:25 JLB POK0376 Chlorobenzene <0.062 ug/L 3 0.50 0.062 1 8260D 10/17/20 3:25 JLB POK0376 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260D 10/17/20 3:25 JLB POK0376 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260D 10/17/20 3:25 JLB POK0376 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 7 of 35 . Laboratory Report • � Waynt.� 11 /23/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: MW-02 OLD 20201006 Attn: Alec Macbeth Sample ID: 0100081-02 231 Haywood Street Work Order: 0100081 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/06/20 11:46 Time Submitted: 10/08/20 07:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260D 10/17/20 3:25 JLB POK0376 cis- 1,2-Dichloroethylene <0.056 ug/L 5 0.50 0.056 1 8260D 10/17/20 3:25 JLB POK0376 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260D 10/17/20 3:25 JLB POK0376 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260D 10/17/20 3:25 JLB POK0376 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260D 10/17/20 3:25 JLB POK0376 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260D 10/17/20 3:25 JLB POK0376 m,p-Xylenes 0.39 J ug/L NE 1.0 0.12 1 8260D 10/17/20 3:25 JLB POK0376 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260D 10/17/20 3:25 JLB POK0376 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260D 10/17/20 3:25 JLB POK0376 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260D 10/17/20 3:25 JLB POK0376 Methyl Isobutyl Ketone <1.0 ug/L 100 5.0 1.0 1 8260D 10/17/20 3:25 JLB POK0376 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260D 10/17/20 3:25 JLB POK0376 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260D 10/17/20 3:25 JLB POK0376 Styrene <0.047 ug/L 1 0.50 0.047 1 8260D 10/17/20 3:25 JLB POK0376 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260D 10/17/20 3:25 JLB POK0376 Tetrahydrofuran <1.1 ug/L NE 10 1.1 1 8260D 10/17/20 3:25 JLB POK0376 Toluene <0.044 ug/L 1 0.50 0.044 1 8260D 10/17/20 3:25 JLB POK0376 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260D 10/17/20 3:25 JLB POK0376 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260D 10/17/20 3:25 JLB POK0376 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260D 10/17/20 3:25 JLB POK0376 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260D 10/17/20 3:25 JLB POK0376 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/17/20 3:25 JLB POK0376 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260D 10/17/20 3:25 JLB POK0376 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260D 10/17/20 3:25 JLB POK0376 Xylenes, total 0.39 J ug/L 5 1.5 0.15 1 8260D 10/17/20 3:25 JLB POK0376 Surrogate Recovery Control Limits 4-Bromofluorobenzene 101 % 80-124 Dibromofluoromethane 104 % 75-129 Toluene-d8 103 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 10/8/20 13:13 JLB POJ0116 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 8 of 35 . Laboratory Report • � Waynt.� 11 /23/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: MW-03 OLD 20201006 Attn: Alec Macbeth Sample ID: 0100081-03 231 Haywood Street Work Order: 0100081 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/06/20 14:26 Time Submitted: 10/08/20 07:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Total Metals Mercury <0.034 ug/L 0.2 0.20 0.034 1 7470A 10/9/20 15:42 EDV POJ0152 Arsenic <0.17 ug/L 10 1.0 0.17 1 6020B 10/12/20 20:42JAB POJ0164 Barium 790 ug/L 100 2.0 0.81 1 6020B 10/12/20 20:42JAB POJ0164 Cadmium <0.16 ug/L 1 1.0 0.16 1 6020B 10/12/20 20:42JAB POJ0164 Chromium <0.79 ug/L 10 2.0 0.79 1 6020B 10/12/20 20:42JAB POJ0164 Lead <0.26 ug/L 10 1.0 0.26 1 6020B 10/12/20 20:42JAB POJ0164 Selenium <0.74 ug/L 10 5.0 0.74 1 6020B 10/12/20 20:42JAB POJ0164 Silver <0.11 ug/L 10 1.0 0.11 1 6020B 10/12/20 20:42JAB POJ0164 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260D 10/17/20 3:49 JLB POK0376 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260D 10/17/20 3:49 JLB POK0376 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260D 10/17/20 3:49 JLB POK0376 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/17/20 3:49 JLB POK0376 1,1-Dichloroethane 0.32 J ug/L 5 0.50 0.083 1 8260D 10/17/20 3:49 JLB POK0376 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260D 10/17/20 3:49 JLB POK0376 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260D 10/17/20 3:49 JLB POK0376 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260D 10/17/20 3:49 JLB POK0376 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260D 10/17/20 3:49 JLB POK0376 1,2-Dichlorobenzene 0.83 ug/L 5 0.50 0.076 1 8260D 10/17/20 3:49 JLB POK0376 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/17/20 3:49 JLB POK0376 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260D 10/17/20 3:49 JLB POK0376 1,4-Dichlorobenzene 4.2 ug/L 1 0.50 0.050 1 8260D 10/17/20 3:49 JLB POK0376 Acetone 0.66 CC ug/L 100 5.0 0.31 1 8260D 10/17/20 3:49 JLB POK0376 VL, J Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260D 10/17/20 3:49 JLB POK0376 Benzene 0.78 ug/L 1 0.50 0.048 1 8260D 10/17/20 3:49 JLB POK0376 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260D 10/17/20 3:49 JLB POK0376 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/17/20 3:49 JLB POK0376 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260D 10/17/20 3:49 JLB POK0376 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260D 10/17/20 3:49 JLB POK0376 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260D 10/17/20 3:49 JLB POK0376 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260D 10/17/20 3:49 JLB POK0376 Chlorobenzene 5.7 ug/L 3 0.50 0.062 1 8260D 10/17/20 3:49 JLB POK0376 Chloroethane 0.81 ug/L 10 0.50 0.22 1 8260D 10/17/20 3:49 JLB POK0376 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260D 10/17/20 3:49 JLB POK0376 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260D 10/17/20 3:49 JLB POK0376 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 9 of 35 . Laboratory Report • � Waynt.� 11 /23/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: MW-03 OLD 20201006 Attn: Alec Macbeth Sample ID: 0100081-03 231 Haywood Street Work Order: 0100081 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/06/20 14:26 Time Submitted: 10/08/20 07:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID cis-1,2-Dichloroethylene 1.8 ug/L 5 0.50 0.056 1 8260D 10/17/20 3:49 JLB POK0376 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260D 10/17/20 3:49 JLB POK0376 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260D 10/17/20 3:49 JLB POK0376 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260D 10/17/20 3:49 JLB POK0376 Ethylbenzene 0.21 J ug/L 1 0.50 0.061 1 8260D 10/17/20 3:49 JLB POK0376 m,p-Xylenes <0.12 ug/L NE 1.0 0.12 1 8260D 10/17/20 3:49 JLB POK0376 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260D 10/17/20 3:49 JLB POK0376 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260D 10/17/20 3:49 JLB POK0376 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260D 10/17/20 3:49 JLB POK0376 Methyl Isobutyl Ketone <1.0 ug/L 100 5.0 1.0 1 8260D 10/17/20 3:49 JLB POK0376 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260D 10/17/20 3:49 JLB POK0376 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260D 10/17/20 3:49 JLB POK0376 Styrene <0.047 ug/L 1 0.50 0.047 1 8260D 10/17/20 3:49 JLB POK0376 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260D 10/17/20 3:49 JLB POK0376 Tetrahydrofuran <1.1 ug/L NE 10 1.1 1 8260D 10/17/20 3:49 JLB POK0376 Toluene <0.044 ug/L 1 0.50 0.044 1 8260D 10/17/20 3:49 JLB POK0376 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260D 10/17/20 3:49 JLB POK0376 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260D 10/17/20 3:49 JLB POK0376 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260D 10/17/20 3:49 JLB POK0376 Trichloroethylene 0.43 J ug/L 1 0.50 0.078 1 8260D 10/17/20 3:49 JLB POK0376 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/17/20 3:49 JLB POK0376 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260D 10/17/20 3:49 JLB POK0376 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260D 10/17/20 3:49 JLB POK0376 Xylenes, total <0.15 ug/L 5 1.5 0.15 1 8260D 10/17/20 3:49 JLB POK0376 Surrogate Recovery Control Limits 4-Bromofluorobenzene 106 % 80-124 Dibromofluoromethane 98 % 75-129 Toluene-d8 107 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 10/8/20 13:39 JLB POJ0116 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 10 of 35 Laboratory Report A i • .0 11 /23/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: MW-04 OLD 20201006 Attn: Alec Macbeth Sample ID: 0100081-04 231 Haywood Street Work Order: 0100081 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/06/20 13:43 Time Submitted: 10/08/20 07:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Dissolved Metals Mercury <0.034 ug/L 0.20 0.034 1 7470A 10/15/20 16:45EDV POJ0259 Arsenic <0.17 ug/L 1.0 0.17 1 6020B 10/23/20 13:31JAB POJ0218 Barium 650 ug/L 100 10 0.81 1 6020B 10/23/20 13:31 JAB POJ0218 Cadmium <0.16 ug/L 1.0 0.16 1 6020B 10/23/20 13:31JAB POJ0218 Chromium <0.79 ug/L 2.0 0.79 1 6020B 10/23/20 13:31JAB POJ0218 Lead <0.26 ug/L 1.0 0.26 1 6020B 10/23/20 13:31JAB POJ0218 Selenium <0.74 ug/L 10 5.0 0.74 1 6020B 10/23/20 13:31JAB POJ0218 Silver <0.11 ug/L 1.0 0.11 1 6020B 10/23/20 13:31JAB POJ0218 Total Metals Mercury <0.034 ug/L 0.2 0.20 0.034 1 7470A 10/9/20 15:46 EDV POJ0152 Arsenic 0.21 J ug/L 10 1.0 0.17 1 6020B 10/12/20 20:48JAB POJ0164 Barium 750 ug/L 100 2.0 0.81 1 6020B 10/12/20 20:48JAB POJ0164 Cadmium 0.27 J ug/L 1 1.0 0.16 1 6020B 10/12/20 20:48JAB POJ0164 Chromium 2.2 ug/L 10 2.0 0.79 1 6020B 10/12/20 20:48JAB POJ0164 Lead 1.5 ug/L 10 1.0 0.26 1 6020B 10/12/20 20:48JAB POJ0164 Selenium <0.74 ug/L 10 5.0 0.74 1 6020B 10/12/20 20:48JAB POJ0164 Silver <0.11 ug/L 10 1.0 0.11 1 6020B 10/12/20 20:48JAB POJ0164 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260D 10/17/20 4:14 JLB POK0376 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260D 10/17/20 4:14 JLB POK0376 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260D 10/17/20 4:14 JLB POK0376 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/17/20 4:14 JLB POK0376 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260D 10/17/20 4:14 JLB POK0376 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260D 10/17/20 4:14 JLB POK0376 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260D 10/17/20 4:14 JLB POK0376 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260D 10/17/20 4:14 JLB POK0376 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260D 10/17/20 4:14 JLB POK0376 1,2-Dichlorobenzene 0.34 J ug/L 5 0.50 0.076 1 8260D 10/17/20 4:14 JLB POK0376 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/17/20 4:14 JLB POK0376 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260D 10/17/20 4:14 JLB POK0376 1,4-Dichlorobenzene 1.6 ug/L 1 0.50 0.050 1 8260D 10/17/20 4:14 JLB POK0376 Acetone 2.0 CC ug/L 100 5.0 0.31 1 8260D 10/17/20 4:14 JLB POK0376 VL, J Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260D 10/17/20 4:14 JLB POK0376 Benzene 0.28 J ug/L 1 0.50 0.048 1 8260D 10/17/20 4:14 JLB POK0376 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260D 10/17/20 4:14 JLB POK0376 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 11 of 35 . Laboratory Report • � Waynt.� 11 /23/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: MW-04 OLD 20201006 Attn: Alec Macbeth Sample ID: 0100081-04 231 Haywood Street Work Order: 0100081 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/06/20 13:43 Time Submitted: 10/08/20 07:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/17/20 4:14 JLB POK0376 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260D 10/17/20 4:14 JLB POK0376 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260D 10/17/20 4:14 JLB POK0376 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260D 10/17/20 4:14 JLB POK0376 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260D 10/17/20 4:14 JLB POK0376 Chlorobenzene 3.6 ug/L 3 0.50 0.062 1 8260D 10/17/20 4:14 JLB POK0376 Chloroethane 0.64 ug/L 10 0.50 0.22 1 8260D 10/17/20 4:14 JLB POK0376 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260D 10/17/20 4:14 JLB POK0376 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260D 10/17/20 4:14 JLB POK0376 cis-1,2-Dichloroethylene 0.33 J ug/L 5 0.50 0.056 1 8260D 10/17/20 4:14 JLB POK0376 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260D 10/17/20 4:14 JLB POK0376 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260D 10/17/20 4:14 JLB POK0376 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260D 10/17/20 4:14 JLB POK0376 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260D 10/17/20 4:14 JLB POK0376 m,p-Xylenes 0.36 J ug/L NE 1.0 0.12 1 8260D 10/17/20 4:14 JLB POK0376 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260D 10/17/20 4:14 JLB POK0376 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260D 10/17/20 4:14 JLB POK0376 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260D 10/17/20 4:14 JLB POK0376 Methyl Isobutyl Ketone <1.0 ug/L 100 5.0 1.0 1 8260D 10/17/20 4:14 JLB POK0376 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260D 10/17/20 4:14 JLB POK0376 o-Xylene 0.22 J ug/L NE 0.50 0.044 1 8260D 10/17/20 4:14 JLB POK0376 Styrene <0.047 ug/L 1 0.50 0.047 1 8260D 10/17/20 4:14 JLB POK0376 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260D 10/17/20 4:14 JLB POK0376 Tetrahydrofuran 1.9 J ug/L NE 10 1.1 1 8260D 10/17/20 4:14 JLB POK0376 Toluene 0.23 J ug/L 1 0.50 0.044 1 8260D 10/17/20 4:14 JLB POK0376 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260D 10/17/20 4:14 JLB POK0376 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260D 10/17/20 4:14 JLB POK0376 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260D 10/17/20 4:14 JLB POK0376 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260D 10/17/20 4:14 JLB POK0376 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/17/20 4:14 JLB POK0376 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260D 10/17/20 4:14 JLB POK0376 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260D 10/17/20 4:14 JLB POK0376 Xylenes, total 0.58 J ug/L 5 1.5 0.15 1 8260D 10/17/20 4:14 JLB POK0376 Surrogate Recovery Control Limits 4-Bromofluorobenzene 103 % 80-124 Dibromofluoromethane 104 % 75-129 Toluene-d8 106 % 77-123 Volatile Organic Compounds by GC/MS SIM This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 12 of 35 Laboratory Report • � 11 /23/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: MW-04 OLD 20201006 Attn: Alec Macbeth Sample ID: 0100081-04 231 Haywood Street Work Order: 0100081 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/06/20 13:43 Time Submitted: 10/08/20 07:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 10/8/20 14:04 JLB POJ0116 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 13 of 35 Laboratory Report A i • .0 11 /23/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: Bc SPRING OLD 20201007 Attn: Alec Macbeth Sample ID: 0100081-05 231 Haywood Street Work Order: 0100081 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/07/20 09:31 Time Submitted: 10/08/20 07:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Dissolved Metals Mercury <0.034 ug/L 0.20 0.034 1 7470A 10/15/20 16:33EDV POJ0259 Arsenic <0.17 ug/L 1.0 0.17 1 6020B 10/23/20 13:38JAB POJ0218 Barium 130 ug/L 100 10 0.81 1 6020B 10/23/20 13:38JAB POJ0218 Cadmium <0.16 ug/L 1.0 0.16 1 6020B 10/23/20 13:38JAB POJ0218 Chromium <0.79 ug/L 2.0 0.79 1 6020B 10/23/20 13:38JAB POJ0218 Lead <0.26 ug/L 1.0 0.26 1 6020B 10/23/20 13:38JAB POJ0218 Selenium <0.74 ug/L 10 5.0 0.74 1 6020B 10/23/20 13:38JAB POJ0218 Silver <0.11 ug/L 1.0 0.11 1 6020B 10/23/20 13:38JAB POJ0218 Total Metals Mercury <0.034 ug/L 0.2 0.20 0.034 1 7470A 10/9/20 15:50 EDV POJ0152 Arsenic <0.17 ug/L 10 1.0 0.17 1 6020B 10/12/20 20:55JAB POJ0164 Barium 130 ug/L 100 2.0 0.81 1 6020B 10/12/20 20:55JAB POJ0164 Cadmium <0.16 ug/L 1 1.0 0.16 1 6020B 10/12/20 20:55JAB POJ0164 Chromium 1.0 J ug/L 10 2.0 0.79 1 6020B 10/12/20 20:55JAB POJ0164 Lead 0.30 J ug/L 10 1.0 0.26 1 6020B 10/12/20 20:55JAB POJ0164 Selenium <0.74 ug/L 10 5.0 0.74 1 6020B 10/12/20 20:55JAB POJ0164 Silver <0.11 ug/L 10 1.0 0.11 1 6020B 10/12/20 20:55JAB POJ0164 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260D 10/17/20 4:39 JLB POK0376 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260D 10/17/20 4:39 JLB POK0376 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260D 10/17/20 4:39 JLB POK0376 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/17/20 4:39 JLB POK0376 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260D 10/17/20 4:39 JLB POK0376 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260D 10/17/20 4:39 JLB POK0376 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260D 10/17/20 4:39 JLB POK0376 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260D 10/17/20 4:39 JLB POK0376 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260D 10/17/20 4:39 JLB POK0376 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260D 10/17/20 4:39 JLB POK0376 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/17/20 4:39 JLB POK0376 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260D 10/17/20 4:39 JLB POK0376 1,4-Dichlorobenzene <0.050 ug/L 1 0.50 0.050 1 8260D 10/17/20 4:39 JLB POK0376 Acetone <0.31 ug/L 100 5.0 0.31 1 8260D 10/17/20 4:39 JLB POK0376 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260D 10/17/20 4:39 JLB POK0376 Benzene <0.048 ug/L 1 0.50 0.048 1 8260D 10/17/20 4:39 JLB POK0376 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260D 10/17/20 4:39 JLB POK0376 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/17/20 4:39 JLB POK0376 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 14 of 35 . • � Waynt.� poi ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Project: Madison Closed Landfill Sample Matrix: Water Laboratory Report 11 /23/2020 Client Sample ID: BG SPRING OLD 20201007 Sample ID: 0100081-05 Work Order: 0100081 Time Collected: 10/07/20 09:31 Time Submitted: 10/08/20 07:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Bromoform <0.040 ug/L 3 1.0 0.040 1 8260D 10/17/20 4:39 JLB POK0376 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260D 10/17/20 4:39 JLB POK0376 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260D 10/17/20 4:39 JLB POK0376 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260D 10/17/20 4:39 JLB POK0376 Chlorobenzene <0.062 ug/L 3 0.50 0.062 1 8260D 10/17/20 4:39 JLB POK0376 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260D 10/17/20 4:39 JLB POK0376 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260D 10/17/20 4:39 JLB POK0376 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260D 10/17/20 4:39 JLB POK0376 cis- 1,2-Dichloroethylene <0.056 ug/L 5 0.50 0.056 1 8260D 10/17/20 4:39 JLB POK0376 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260D 10/17/20 4:39 JLB POK0376 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260D 10/17/20 4:39 JLB POK0376 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260D 10/17/20 4:39 JLB POK0376 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260D 10/17/20 4:39 JLB POK0376 m,p-Xylenes <0.12 ug/L NE 1.0 0.12 1 8260D 10/17/20 4:39 JLB POK0376 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260D 10/17/20 4:39 JLB POK0376 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260D 10/17/20 4:39 JLB POK0376 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260D 10/17/20 4:39 JLB POK0376 Methyl Isobutyl Ketone <1.0 ug/L 100 5.0 1.0 1 8260D 10/17/20 4:39 JLB POK0376 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260D 10/17/20 4:39 JLB POK0376 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260D 10/17/20 4:39 JLB POK0376 Styrene <0.047 ug/L 1 0.50 0.047 1 8260D 10/17/20 4:39 JLB POK0376 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260D 10/17/20 4:39 JLB POK0376 Tetrahydrofuran <1.1 ug/L NE 10 1.1 1 8260D 10/17/20 4:39 JLB POK0376 Toluene <0.044 ug/L 1 0.50 0.044 1 8260D 10/17/20 4:39 JLB POK0376 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260D 10/17/20 4:39 JLB POK0376 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260D 10/17/20 4:39 JLB POK0376 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260D 10/17/20 4:39 JLB POK0376 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260D 10/17/20 4:39 JLB POK0376 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/17/20 4:39 JLB POK0376 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260D 10/17/20 4:39 JLB POK0376 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260D 10/17/20 4:39 JLB POK0376 Xylenes, total <0.15 ug/L 5 1.5 0.15 1 8260D 10/17/20 4:39 JLB POK0376 Surrogate Recovery Control Limits 4-Bromofluorobenzene 102 % 80-124 Dibromofluoromethane 105 % 75-129 Toluene-d8 102 % 77-123 Volatile Organic Compounds by GC/MS SIM This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 15 of 35 Laboratory Report • � 11 /23/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: BG SPRING OLD 20201007 Attn: Alec Macbeth Sample ID: 0100081-05 231 Haywood Street Work Order: 0100081 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/07/20 09:31 Time Submitted: 10/08/20 07:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 10/8/20 14:29 JLB P0J0116 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 16 of 35 Laboratory Report • � 11 /23/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: SW-01 OLD 20201007 Attn: Alec Macbeth Sample ID: 0100081-06 231 Haywood Street Work Order: 0100081 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/07/20 10:13 Time Submitted: 10/08/20 07:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters Hardness 56000 ug/L 5000 570 1 SM2340 C 10/15/20 15:43BMS POJ0269 Total Metals Mercury <0.034 ug/L 0.2 0.20 0.034 1 7470A 10/9/20 16:01 EDV POJ0152 Arsenic 0.23 J ug/L 10 1.0 0.17 1 6020B 10/12/20 21:16JAB POJ0164 Barium 83 ug/L 100 2.0 0.81 1 6020B 10/12/20 21:16JAB POJ0164 Cadmium <0.16 ug/L 1 1.0 0.16 1 6020B 10/12/20 21:16JAB POJ0164 Chromium 1.4 J ug/L 10 2.0 0.79 1 6020B 10/12/20 21:16JAB POJ0164 Lead 0.85 J ug/L 10 1.0 0.26 1 6020B 10/12/20 21:16JAB POJ0164 Selenium <0.74 ug/L 10 5.0 0.74 1 6020B 10/12/20 21:16JAB POJ0164 Silver <0.11 ug/L 10 1.0 0.11 1 6020B 10/12/20 21:16JAB POJ0164 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260D 10/17/20 5:04 JLB POK0376 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260D 10/17/20 5:04 JLB POK0376 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260D 10/17/20 5:04 JLB POK0376 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/17/20 5:04 JLB POK0376 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260D 10/17/20 5:04 JLB POK0376 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260D 10/17/20 5:04 JLB POK0376 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260D 10/17/20 5:04 JLB POK0376 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260D 10/17/20 5:04 JLB POK0376 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260D 10/17/20 5:04 JLB POK0376 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260D 10/17/20 5:04 JLB POK0376 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/17/20 5:04 JLB POK0376 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260D 10/17/20 5:04 JLB POK0376 1,4-Dichlorobenzene <0.050 ug/L 1 0.50 0.050 1 8260D 10/17/20 5:04 JLB POK0376 Acetone <0.31 ug/L 100 5.0 0.31 1 8260D 10/17/20 5:04 JLB POK0376 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260D 10/17/20 5:04 JLB POK0376 Benzene <0.048 ug/L 1 0.50 0.048 1 8260D 10/17/20 5:04 JLB POK0376 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260D 10/17/20 5:04 JLB POK0376 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/17/20 5:04 JLB POK0376 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260D 10/17/20 5:04 JLB POK0376 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260D 10/17/20 5:04 JLB POK0376 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260D 10/17/20 5:04 JLB POK0376 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260D 10/17/20 5:04 JLB POK0376 Chlorobenzene <0.062 ug/L 3 0.50 0.062 1 8260D 10/17/20 5:04 JLB POK0376 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260D 10/17/20 5:04 JLB POK0376 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260D 10/17/20 5:04 JLB POK0376 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 17 of 35 Laboratory Report A i • .0 11 /23/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: SW-01 OLD 20201007 Attn: Alec Macbeth Sample ID: 0100081-06 231 Haywood Street Work Order: 0100081 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/07/20 10:13 Time Submitted: 10/08/20 07:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260D 10/17/20 5:04 JLB POK0376 cis- 1,2-Dichloroethylene <0.056 ug/L 5 0.50 0.056 1 8260D 10/17/20 5:04 JLB POK0376 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260D 10/17/20 5:04 JLB POK0376 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260D 10/17/20 5:04 JLB POK0376 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260D 10/17/20 5:04 JLB POK0376 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260D 10/17/20 5:04 JLB POK0376 m,p-Xylenes <0.12 ug/L NE 1.0 0.12 1 8260D 10/17/20 5:04 JLB POK0376 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260D 10/17/20 5:04 JLB POK0376 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260D 10/17/20 5:04 JLB POK0376 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260D 10/17/20 5:04 JLB POK0376 Methyl Isobutyl Ketone <1.0 ug/L 100 5.0 1.0 1 8260D 10/17/20 5:04 JLB POK0376 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260D 10/17/20 5:04 JLB POK0376 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260D 10/17/20 5:04 JLB POK0376 Styrene <0.047 ug/L 1 0.50 0.047 1 8260D 10/17/20 5:04 JLB POK0376 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260D 10/17/20 5:04 JLB POK0376 Tetrahydrofuran <1.1 ug/L NE 10 1.1 1 8260D 10/17/20 5:04 JLB POK0376 Toluene <0.044 ug/L 1 0.50 0.044 1 8260D 10/17/20 5:04 JLB POK0376 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260D 10/17/20 5:04 JLB POK0376 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260D 10/17/20 5:04 JLB POK0376 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260D 10/17/20 5:04 JLB POK0376 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260D 10/17/20 5:04 JLB POK0376 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/17/20 5:04 JLB POK0376 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260D 10/17/20 5:04 JLB POK0376 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260D 10/17/20 5:04 JLB POK0376 Xylenes, total <0.15 ug/L 5 1.5 0.15 1 8260D 10/17/20 5:04 JLB POK0376 Surrogate Recovery Control Limits 4-Bromofluorobenzene 101 % 80-124 Dibromofluoromethane 104 % 75-129 Toluene-d8 108 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 10/8/20 14:54 JLB POJ0116 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 18 of 35 Laboratory Report • � 11 /23/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: SW-02 OLD 20201007 Attn: Alec Macbeth Sample ID: 0100081-07 231 Haywood Street Work Order: 0100081 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/07/20 10:00 Time Submitted: 10/08/20 07:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters Hardness 54000 ug/L 5000 570 1 SM2340 C 10/15/20 15:43BMS POJ0269 Total Metals Mercury <0.034 ug/L 0.2 0.20 0.034 1 7470A 10/9/20 16:05 EDV POJ0152 Arsenic <0.17 ug/L 10 1.0 0.17 1 6020B 10/12/20 21:22JAB POJ0164 Barium 42 ug/L 100 2.0 0.81 1 6020B 10/12/20 21:22JAB POJ0164 Cadmium <0.16 ug/L 1 1.0 0.16 1 6020B 10/12/20 21:22JAB POJ0164 Chromium <0.79 ug/L 10 2.0 0.79 1 6020B 10/12/20 21:22JAB POJ0164 Lead <0.26 ug/L 10 1.0 0.26 1 6020B 10/12/20 21:22JAB POJ0164 Selenium <0.74 ug/L 10 5.0 0.74 1 6020B 10/12/20 21:22JAB POJ0164 Silver <0.11 ug/L 10 1.0 0.11 1 6020B 10/12/20 21:22JAB POJ0164 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260D 10/17/20 5:28 JLB POK0376 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260D 10/17/20 5:28 JLB POK0376 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260D 10/17/20 5:28 JLB POK0376 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/17/20 5:28 JLB POK0376 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260D 10/17/20 5:28 JLB POK0376 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260D 10/17/20 5:28 JLB POK0376 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260D 10/17/20 5:28 JLB POK0376 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260D 10/17/20 5:28 JLB POK0376 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260D 10/17/20 5:28 JLB POK0376 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260D 10/17/20 5:28 JLB POK0376 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/17/20 5:28 JLB POK0376 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260D 10/17/20 5:28 JLB POK0376 1,4-Dichlorobenzene <0.050 ug/L 1 0.50 0.050 1 8260D 10/17/20 5:28 JLB POK0376 Acetone <0.31 ug/L 100 5.0 0.31 1 8260D 10/17/20 5:28 JLB POK0376 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260D 10/17/20 5:28 JLB POK0376 Benzene <0.048 ug/L 1 0.50 0.048 1 8260D 10/17/20 5:28 JLB POK0376 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260D 10/17/20 5:28 JLB POK0376 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/17/20 5:28 JLB POK0376 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260D 10/17/20 5:28 JLB POK0376 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260D 10/17/20 5:28 JLB POK0376 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260D 10/17/20 5:28 JLB POK0376 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260D 10/17/20 5:28 JLB POK0376 Chlorobenzene <0.062 ug/L 3 0.50 0.062 1 8260D 10/17/20 5:28 JLB POK0376 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260D 10/17/20 5:28 JLB POK0376 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260D 10/17/20 5:28 JLB POK0376 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 19 of 35 Laboratory Report A i • .0 11 /23/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: SW-02 OLD 20201007 Attn: Alec Macbeth Sample ID: 0100081-07 231 Haywood Street Work Order: 0100081 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/07/20 10:00 Time Submitted: 10/08/20 07:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260D 10/17/20 5:28 JLB POK0376 cis- 1,2-Dichloroethylene <0.056 ug/L 5 0.50 0.056 1 8260D 10/17/20 5:28 JLB POK0376 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260D 10/17/20 5:28 JLB POK0376 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260D 10/17/20 5:28 JLB POK0376 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260D 10/17/20 5:28 JLB POK0376 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260D 10/17/20 5:28 JLB POK0376 m,p-Xylenes <0.12 ug/L NE 1.0 0.12 1 8260D 10/17/20 5:28 JLB POK0376 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260D 10/17/20 5:28 JLB POK0376 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260D 10/17/20 5:28 JLB POK0376 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260D 10/17/20 5:28 JLB POK0376 Methyl Isobutyl Ketone <1.0 ug/L 100 5.0 1.0 1 8260D 10/17/20 5:28 JLB POK0376 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260D 10/17/20 5:28 JLB POK0376 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260D 10/17/20 5:28 JLB POK0376 Styrene <0.047 ug/L 1 0.50 0.047 1 8260D 10/17/20 5:28 JLB POK0376 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260D 10/17/20 5:28 JLB POK0376 Tetrahydrofuran <1.1 ug/L NE 10 1.1 1 8260D 10/17/20 5:28 JLB POK0376 Toluene <0.044 ug/L 1 0.50 0.044 1 8260D 10/17/20 5:28 JLB POK0376 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260D 10/17/20 5:28 JLB POK0376 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260D 10/17/20 5:28 JLB POK0376 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260D 10/17/20 5:28 JLB POK0376 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260D 10/17/20 5:28 JLB POK0376 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/17/20 5:28 JLB POK0376 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260D 10/17/20 5:28 JLB POK0376 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260D 10/17/20 5:28 JLB POK0376 Xylenes, total <0.15 ug/L 5 1.5 0.15 1 8260D 10/17/20 5:28 JLB POK0376 Surrogate Recovery Control Limits 4-Bromofluorobenzene 103 % 80-124 Dibromofluoromethane 100 % 75-129 Toluene-d8 106 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 10/8/20 15:20 JLB POJ0116 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 20 of 35 Laboratory Report • � 11 /23/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: TB-202010070000 Attn: Alec Macbeth Sample ID: 0100081-08 231 Haywood Street Work Order: 0100081 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/07/20 00:00 Time Submitted: 10/08/20 07:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Volatile Organic Compounds by GC/MS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260D 10/17/20 2:35 JLB POK0376 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260D 10/17/20 2:35 JLB POK0376 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260D 10/17/20 2:35 JLB POK0376 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/17/20 2:35 JLB POK0376 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260D 10/17/20 2:35 JLB POK0376 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260D 10/17/20 2:35 JLB POK0376 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260D 10/17/20 2:35 JLB POK0376 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260D 10/17/20 2:35 JLB POK0376 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260D 10/17/20 2:35 JLB POK0376 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260D 10/17/20 2:35 JLB POK0376 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/17/20 2:35 JLB POK0376 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260D 10/17/20 2:35 JLB POK0376 1,4-Dichlorobenzene <0.050 ug/L 1 0.50 0.050 1 8260D 10/17/20 2:35 JLB POK0376 Acetone 1.9 CC ug/L 100 5.0 0.31 1 8260D 10/17/20 2:35 JLB POK0376 VL, J Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260D 10/17/20 2:35 JLB POK0376 Benzene <0.048 ug/L 1 0.50 0.048 1 8260D 10/17/20 2:35 JLB POK0376 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260D 10/17/20 2:35 JLB POK0376 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/17/20 2:35 JLB POK0376 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260D 10/17/20 2:35 JLB POK0376 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260D 10/17/20 2:35 JLB POK0376 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260D 10/17/20 2:35 JLB POK0376 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260D 10/17/20 2:35 JLB POK0376 Chlorobenzene <0.062 ug/L 3 0.50 0.062 1 8260D 10/17/20 2:35 JLB POK0376 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260D 10/17/20 2:35 JLB POK0376 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260D 10/17/20 2:35 JLB POK0376 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260D 10/17/20 2:35 JLB POK0376 cis- 1,2-Dichloroethylene <0.056 ug/L 5 0.50 0.056 1 8260D 10/17/20 2:35 JLB POK0376 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260D 10/17/20 2:35 JLB POK0376 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260D 10/17/20 2:35 JLB POK0376 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260D 10/17/20 2:35 JLB POK0376 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260D 10/17/20 2:35 JLB POK0376 m,p-Xylenes <0.12 ug/L NE 1.0 0.12 1 8260D 10/17/20 2:35 JLB POK0376 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260D 10/17/20 2:35 JLB POK0376 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260D 10/17/20 2:35 JLB POK0376 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 21 of 35 . Laboratory Report • � Waynt.� 11 /23/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: TB-202010070000 Attn: Alec Macbeth Sample ID: 0100081-08 231 Haywood Street Work Order: 0100081 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/07/20 00:00 Time Submitted: 10/08/20 07:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260D 10/17/20 2:35 JLB POK0376 Methyl Isobutyl Ketone <1.0 ug/L 100 5.0 1.0 1 8260D 10/17/20 2:35 JLB POK0376 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260D 10/17/20 2:35 JLB POK0376 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260D 10/17/20 2:35 JLB POK0376 Styrene <0.047 ug/L 1 0.50 0.047 1 8260D 10/17/20 2:35 JLB POK0376 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260D 10/17/20 2:35 JLB POK0376 Tetrahydrofuran <1.1 ug/L NE 10 1.1 1 8260D 10/17/20 2:35 JLB POK0376 Toluene <0.044 ug/L 1 0.50 0.044 1 8260D 10/17/20 2:35 JLB POK0376 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260D 10/17/20 2:35 JLB POK0376 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260D 10/17/20 2:35 JLB POK0376 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260D 10/17/20 2:35 JLB POK0376 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260D 10/17/20 2:35 JLB POK0376 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/17/20 2:35 JLB POK0376 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260D 10/17/20 2:35 JLB POK0376 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260D 10/17/20 2:35 JLB POK0376 Xylenes, total <0.15 ug/L 5 1.5 0.15 1 8260D 10/17/20 2:35 JLB POK0376 Surrogate Recovery Control Limits 4-Bromofluorobenzene 107 % 80-124 Dibromofluoromethane 101 % 75-129 Toluene-d8 106 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 22 of 35 (2) Way po Int ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 11 /23/20 Work Order: 0100081 Time Submitted: 10/8/2020 7:45:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POK0376 - 5030B Blank (POK0376-BLK1) Prepared: 10/16/20 Analyzed: 10/17/20 1,1,1,2-Tetrachloroethane BRL 0.50 ug/L 1,1,1-Trichloroethane BRL 0.50 ug/L 1,1,2,2-Tetrachloroethane BRL 0.50 ug/L 1,1,2-Trichloroethane BRL 0.50 ug/L 1,1-Dichloroethane BRL 0.50 ug/L 1,1-Dichloroethylene BRL 0.50 ug/L 1,2,3-Trichloropropane BRL 1.0 ug/L 1,2-Dibromo-3-chloropropane BRL 2.0 ug/L 1,2-Dibromoethane BRL 0.50 ug/L 1,2-Dichlorobenzene BRL 0.50 ug/L 1,2-Dichloroethane BRL 0.50 ug/L 1,2-Dichloropropane BRL 0.50 ug/L 1,4-Dichlorobenzene BRL 0.50 ug/L Acetone BRL 5.0 ug/L Acrylonitrile BRL 20 ug/L Benzene BRL 0.50 ug/L Bromochloromethane BRL 0.50 ug/L Bromodichloromethane BRL 0.50 ug/L Bromoform BRL 1.0 ug/L Bromomethane BRL 1.0 ug/L Carbon disulfide BRL 5.0 ug/L Carbon Tetrachloride BRL 0.50 ug/L Chlorobenzene BRL 0.50 ug/L Chloroethane BRL 0.50 ug/L Chloroform BRL 0.50 ug/L Chloromethane BRL 0.50 ug/L cis-1,2-Dichloroethylene BRL 0.50 ug/L cis-1,3-Dichloropropylene BRL 0.50 ug/L Dibromochloromethane BRL 0.50 ug/L Dibromomethane BRL 0.50 ug/L Ethylbenzene BRL 0.50 ug/L m,p-Xylenes BRL 1.0 ug/L Methyl Butyl Ketone (2-Hexanone) BRL 5.0 ug/L Methyl Ethyl Ketone (2-Butanone) BRL 5.0 ug/L Methyl Iodide BRL 5.0 ug/L Methyl Isobutyl Ketone BRL 5.0 ug/L Methylene Chloride BRL 1.0 ug/L o-Xylene BRL 0.50 ug/L Styrene BRL 0.50 ug/L Tetrachloroethylene BRL 0.50 ug/L Tetrahydrofuran BRL 10 ug/L Toluene BRL 0.50 ug/L trans-1,2-Dichloroethylene BRL 0.50 ug/L trans-1,3-Dichloropropylene BRL 0.50 ug/L trans-1,4-Dichloro-2-butene BRL 10 ug/L Trichloroethylene BRL 0.50 ug/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 23 of 35 Waypoint ' ANALYTICAL Level II QC Report 11 /23/20 Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Work Order: 0100081 Attn: Alec Macbeth Time Submitted: 10/8/2020 7:45:OOAM 231 Haywood Street Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POK0376 - 5030B Blank (POK0376-BLK1) Prepared: 10/16/20 Analyzed: 10/17/20 Trichlorofluoromethane BRL 0.50 ug/L Vinyl acetate BRL 2.0 ug/L Vinyl chloride BRL 0.50 ug/L Xylenes, total BRL 1.5 ug/L Surrogate:4-Bromofluorobenzene 53.0 ug/L 50.00 106 80-124 Surrogate: Dibromofluoromethane 51.1 ug/L 50.00 102 75-129 Surrogate: Toluene-d8 52.8 ug/L 50.00 106 77-123 LCS (POK0376-BSI) Prepared: 10/16/20 Analyzed: 10/17/20 1,1,1,2-Tetrachloroethane 21.8 0.50 ug/L 20.00 109 79-134 1,1,1-Trichloroethane 19.6 0.50 ug/L 20.00 98 75-136 1,1,2,2-Tetrachloroethane 22.7 0.50 ug/L 20.00 114 62-127 1,1,2-Trichloroethane 19.0 0.50 ug/L 20.00 95 70-140 1,1-Dichloroethane 19.2 0.50 ug/L 20.00 96 78-130 1,1-Dichloroethylene 18.6 0.50 ug/L 20.00 93 70-154 1,2,3-Trichloropropane 23.9 1.0 ug/L 20.00 119 71-127 1,2-Dibromo-3-chloropropane 23.3 2.0 ug/L 20.00 116 63-134 1,2-Dibromoethane 21.3 0.50 ug/L 20.00 106 77-135 1,2-Dichlorobenzene 22.5 0.50 ug/L 20.00 112 78-128 1,2-Dichloroethane 20.1 0.50 ug/L 20.00 100 68-131 1,2-Dichloropropane 18.7 0.50 ug/L 20.00 94 77-130 1,4-Dichlorobenzene 22.1 0.50 ug/L 20.00 110 75-126 Acetone 28.2 5.0 ug/L 40.00 70 40-166 Acrylonitrile 41.3 20 ug/L 81-127 Benzene 19.0 0.50 ug/L 20.00 95 77-128 Bromochloromethane 20.0 0.50 ug/L 20.00 100 78-135 Bromodichloromethane 19.9 0.50 ug/L 20.00 99 76-138 Bromoform 22.1 1.0 ug/L 20.00 110 71-135 Bromomethane 18.8 1.0 ug/L 20.00 94 41-168 Carbon disulfide 17.9 5.0 ug/L 20.00 89 59-135 Carbon Tetrachloride 19.4 0.50 ug/L 20.00 97 72-142 Chlorobenzene 20.9 0.50 ug/L 20.00 104 78-119 Chloroethane 18.8 0.50 ug/L 20.00 94 57-142 Chloroform 19.6 0.50 ug/L 20.00 98 77-130 Chloromethane 16.2 0.50 ug/L 20.00 81 47-145 cis-1,2-Dichloroethylene 19.0 0.50 ug/L 20.00 95 76-141 cis-1,3-Dichloropropylene 19.0 0.50 ug/L 20.00 95 65-140 Dibromochloromethane 21.1 0.50 ug/L 20.00 106 75-134 Dibromomethane 19.9 0.50 ug/L 20.00 100 76-138 Ethylbenzene 21.1 0.50 ug/L 20.00 105 80-127 m,p-Xylenes 45.5 1.0 ug/L 40.00 114 77-133 Methyl Butyl Ketone (2-Hexanone) 18.9 5.0 ug/L 20.00 95 64-137 Methyl Ethyl Ketone (2-Butanone) 16.3 5.0 ug/L 20.00 81 71-134 Methyl Iodide 14.6 5.0 ug/L 20.00 73 70-130 Methyl Isobutyl Ketone 19.8 5.0 ug/L 20.00 99 69-134 Methylene Chloride 17.2 1.0 ug/L 20.00 86 73-131 o-Xylene 21.8 0.50 ug/L 20.00 109 78-128 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 24 of 35 • 0 Waypoint ANALYTICAL Level II QC Report 11 /23/20 Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Work Order: 0100081 Attn: Alec Macbeth Time Submitted: 10/8/2020 7:45:OOAM 231 Haywood Street Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POK0376 - 5030B LCS (POK0376-BS1) Prepared: 10/16/20 Analyzed: 10/17/20 Styrene 21.3 0.50 ug/L 20.00 106 78-129 Tetrachloroethylene 22.4 0.50 ug/L 20.00 112 80-129 Tetrahydrofuran 18.3 10 ug/L 20.00 92 70-130 Toluene 19.0 0.50 ug/L 20.00 95 76-131 trans-1,2-Dichloroethylene 19.4 0.50 ug/L 20.00 97 76-135 trans-1,3-Dichloropropylene 20.4 0.50 ug/L 20.00 102 67-140 trans-1,4-Dichloro-2-butene 21.5 10 ug/L 20.00 108 70-130 Trichloroethylene 19.7 0.50 ug/L 20.00 99 77-133 Trichlorofluoromethane 21.0 0.50 ug/L 20.00 105 62-148 Vinyl acetate 20.5 2.0 ug/L 34-167 Vinyl chloride 16.6 0.50 ug/L 20.00 83 57-141 Xylenes, total 67.3 1.5 ug/L 60.00 112 77-133 Surrogate:4-Bromofluorobenzene 52.0 ug/L 50.00 104 80-124 Surrogate: Dibromofluoromethane 49.3 ug/L 50.00 99 75-129 Surrogate: Toluene-d8 54.0 ug/L 50.00 108 77-123 Matrix Spike (POK0376-MS1) Source: 0100081-01 Prepared: 10/16/20 Analyzed: 10/17/20 1,1,1,2-Tetrachloroethane 201 5.0 ug/L 200.0 BRL 101 78-134 1,1,1-Trichloroethane 188 5.0 ug/L 200.0 BRL 94 67-145 1,1,2,2-Tetrachloroethane 198 5.0 ug/L 200.0 BRL 99 68-123 1,1,2-Trichloroethane 173 5.0 ug/L 200.0 BRL 87 75-134 1,1-Dichloroethane 178 5.0 ug/L 200.0 BRL 89 75-134 1,1-Dichloroethylene 182 5.0 ug/L 200.0 BRL 91 65-162 1,2,3-Trichloropropane 219 10 ug/L 200.0 BRL 110 73-122 1,2-Dibromo-3-chloropropane 196 20 ug/L 200.0 BRL 98 64-133 1,2-Dibromoethane 186 5.0 ug/L 200.0 BRL 93 80-129 1,2-Dichlorobenzene 193 5.0 ug/L 200.0 BRL 96 80-125 1,2-Dichloroethane 186 5.0 ug/L 200.0 BRL 93 69-129 1,2-Dichloropropane 170 5.0 ug/L 200.0 BRL 85 75-131 1,4-Dichlorobenzene 203 5.0 ug/L 200.0 5.55 99 76-124 Acetone 216 50 ug/L 400.0 BRL 54 40-162 Acrylonitrile 350 200 ug/L BRL 78-129 Benzene 182 5.0 ug/L 200.0 0.850 91 73-131 Bromochloromethane 192 5.0 ug/L 200.0 BRL 96 78-135 Bromodichloromethane 192 5.0 ug/L 200.0 BRL 96 74-138 Bromoform 196 10 ug/L 200.0 BRL 98 72-130 Bromomethane 110 10 ug/L 200.0 BRL 55 41-173 Carbon disulfide 167 50 ug/L 200.0 BRL 83 59-138 Carbon Tetrachloride 190 5.0 ug/L 200.0 BRL 95 66-149 Chlorobenzene 193 5.0 ug/L 200.0 4.08 94 76-119 Chloroethane 166 5.0 ug/L 200.0 BRL 83 52-153 Chloroform 184 5.0 ug/L 200.0 BRL 92 74-136 Chloromethane 139 5.0 ug/L 200.0 BRL 70 39-155 cis-1,2-Dichloroethylene 174 5.0 ug/L 200.0 2.90 86 74-144 cis-1,3-Dichloropropylene 172 5.0 ug/L 200.0 BRL 86 64-132 Dibromochloromethane 196 5.0 ug/L 200.0 BRL 98 77-131 Dibromomethane 172 5.0 ug/L 200.0 BRL 86 76-136 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 25 of 35 • 0 Waypoint ANALYTICAL Level II QC Report 11 /23/20 Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Work Order: 0100081 Attn: Alec Macbeth Time Submitted: 10/8/2020 7:45:OOAM 231 Haywood Street Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POK0376 - 5030B Matrix Spike (POK0376-MS1) Source: 0100081-01 Prepared: 10/16/20 Analyzed: 10/17/20 Ethylbenzene 193 5.0 ug/L 200.0 BRL 96 78-130 m,p-Xylenes 414 10 ug/L 400.0 BRL 103 66-144 Methyl Butyl Ketone (2-Hexanone) 171 50 ug/L 200.0 BRL 86 65-130 Methyl Ethyl Ketone (2-Butanone) 147 50 ug/L 200.0 BRL 73 65-137 Methyl Iodide 97.4 50 ug/L 200.0 BRL 49 70-130 M Methyl Isobutyl Ketone 179 50 ug/L 200.0 BRL 89 64-137 Methylene Chloride 164 10 ug/L 200.0 BRL 82 71-134 o-Xylene 198 5.0 ug/L 200.0 BRL 99 75-131 Styrene 196 5.0 ug/L 200.0 BRL 98 77-128 Tetrachloroethylene 190 5.0 ug/L 200.0 BRL 95 76-130 Tetrahydrofuran 173 100 ug/L 200.0 BRL 86 70-130 Toluene 172 5.0 ug/L 200.0 BRL 86 72-135 trans-1,2-Dichloroethylene 178 5.0 ug/L 200.0 BRL 89 73-141 trans-1,3-Dichloropropylene 183 5.0 ug/L 200.0 BRL 92 64-137 trans-1,4-Dichloro-2-butene 157 100 ug/L 200.0 BRL 78 70-130 Trichloroethylene 182 5.0 ug/L 200.0 BRL 91 72-133 Trichlorofluoromethane 190 5.0 ug/L 200.0 BRL 95 61-152 Vinyl acetate 171 20 ug/L BRL 80-154 Vinyl chloride 157 5.0 ug/L 200.0 BRL 78 54-146 Xylenes, total 612 15 ug/L 600.0 BRL 102 66-144 Surrogate:4-Bromofluorobenzene 51.8 ug/L 50.00 104 80-124 Surrogate: Dibromofluoromethane 49.7 ug/L 50.00 99 75-129 Surrogate: Toluene-d8 53.3 ug/L 50.00 107 77-123 Matrix Spike Dup (POK0376-MSD1) Source: 0100081-01 Prepared: 10/16/20 Analyzed: 10/17/20 1,1,1,2-Tetrachloroethane 192 5.0 ug/L 200.0 BRL 96 78-134 5 19 1,1,1-Trichloroethane 184 5.0 ug/L 200.0 BRL 92 67-145 2 18 1,1,2,2-Tetrachloroethane 206 5.0 ug/L 200.0 BRL 103 68-123 4 19 1,1,2-Trichloroethane 169 5.0 ug/L 200.0 BRL 85 75-134 2 18 1,1-Dichloroethane 172 5.0 ug/L 200.0 BRL 86 75-134 4 18 1,1-Dichloroethylene 170 5.0 ug/L 200.0 BRL 85 65-162 7 20 1,2,3-Trichloropropane 216 10 ug/L 200.0 BRL 108 73-122 2 18 1,2-Dibromo-3-chloropropane 203 20 ug/L 200.0 BRL 102 64-133 4 25 1,2-Dibromoethane 191 5.0 ug/L 200.0 BRL 96 80-129 3 19 1,2-Dichlorobenzene 199 5.0 ug/L 200.0 BRL 100 80-125 3 16 1,2-Dichloroethane 182 5.0 ug/L 200.0 BRL 91 69-129 2 17 1,2-Dichloropropane 175 5.0 ug/L 200.0 BRL 88 75-131 3 17 1,4-Dichlorobenzene 200 5.0 ug/L 200.0 5.55 97 76-124 1 17 Acetone 213 50 ug/L 400.0 BRL 53 40-162 1 23 Acrylonitrile 346 200 ug/L BRL 78-129 1 20 Benzene 174 5.0 ug/L 200.0 0.850 87 73-131 4 17 Bromochloromethane 195 5.0 ug/L 200.0 BRL 98 78-135 2 17 Bromodichloromethane 182 5.0 ug/L 200.0 BRL 91 74-138 5 19 Bromoform 193 10 ug/L 200.0 BRL 97 72-130 1 22 Bromomethane 130 10 ug/L 200.0 BRL 65 41-173 17 33 Carbon disulfide 166 50 ug/L 200.0 BRL 83 59-138 0.5 27 Carbon Tetrachloride 185 5.0 ug/L 200.0 BRL 92 66-149 3 23 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 26 of 35 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 11 /23/20 Work Order: 0100081 Time Submitted: 10/8/2020 7:45:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POK0376 - 5030B Matrix Spike Dup (POK0376-MSD1) Source: 0100081-01 Prepared: 10/16/20 Analyzed: 10/17/20 Chlorobenzene 192 5.0 ug/L 200.0 4.08 94 76-119 0.3 20 Chloroethane 167 5.0 ug/L 200.0 BRL 84 52-153 0.7 24 Chloroform 180 5.0 ug/L 200.0 BRL 90 74-136 2 19 Chloromethane 136 5.0 ug/L 200.0 BRL 68 39-155 3 20 cis-1,2-Dichloroethylene 180 5.0 ug/L 200.0 2.90 89 74-144 3 17 cis-1,3-Dichloropropylene 171 5.0 ug/L 200.0 BRL 85 64-132 0.6 18 Dibromochloromethane 197 5.0 ug/L 200.0 BRL 99 77-131 0.8 21 Dibromomethane 177 5.0 ug/L 200.0 BRL 88 76-136 3 18 Ethylbenzene 190 5.0 ug/L 200.0 BRL 95 78-130 2 18 m,p-Xylenes 404 10 ug/L 400.0 BRL 101 66-144 2 19 Methyl Butyl Ketone (2-Hexanone) 163 50 ug/L 200.0 BRL 82 65-130 5 23 Methyl Ethyl Ketone (2-Butanone) 160 50 ug/L 200.0 BRL 80 65-137 9 23 Methyl Iodide 109 50 ug/L 200.0 BRL 55 70-130 11 20 M Methyl Isobutyl Ketone 171 50 ug/L 200.0 BRL 85 64-137 5 24 Methylene Chloride 159 10 ug/L 200.0 BRL 79 71-134 3 17 o-Xylene 197 5.0 ug/L 200.0 BRL 99 75-131 0.5 20 Styrene 190 5.0 ug/L 200.0 BRL 95 77-128 3 17 Tetrachloroethylene 194 5.0 ug/L 200.0 BRL 97 76-130 2 20 Tetrahydrofuran 161 100 ug/L 200.0 BRL 80 70-130 7 20 Toluene 170 5.0 ug/L 200.0 BRL 85 72-135 1 18 trans-1,2-Dichloroethylene 174 5.0 ug/L 200.0 BRL 87 73-141 2 18 trans-1,3-Dichloropropylene 181 5.0 ug/L 200.0 BRL 91 64-137 1 21 trans-1,4-Dichloro-2-butene 166 100 ug/L 200.0 BRL 83 70-130 6 20 Trichloroethylene 172 5.0 ug/L 200.0 BRL 86 72-133 6 17 Trichlorofluoromethane 181 5.0 ug/L 200.0 BRL 91 61-152 5 27 Vinyl acetate 162 20 ug/L BRL 80-154 5 18 Vinyl chloride 146 5.0 ug/L 200.0 BRL 73 54-146 7 25 Xylenes, total 601 15 ug/L 600.0 BRL 100 66-144 2 20 Surrogate:4-Bromofluorobenzene 50.1 ug/L 50.00 100 80-124 Surrogate: Dibromofluoromethane 49.2 ug/L 50.00 98 75-129 Surrogate: Toluene-d8 53.5 ug/L 50.00 107 77-123 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 27 of 35 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Volatile Organic Compounds by GC/MS SIM - Quality Control Level II QC Report 11 /23/20 Work Order: 0100081 Time Submitted: 10/8/2020 7:45:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0116 - 5030B Blank (POJ0116-BLK1) Prepared & Analyzed: 10/08/20 1,4-Dioxane BRL 2.0 ug/L LCS (POJ0116-BS1) Prepared &Analyzed: 10/08/20 1,4-Dioxane 49.1 2.0 ug/L 50.00 98 55-145 Matrix Spike (POJ0116-MS1) Source: 0100081-01 Prepared & Analyzed: 10/08/20 1,4-Dioxane 48.0 2.0 ug/L 50.00 7.03 82 55-145 Matrix Spike Dup (POJ0116-MSD1) Source: 0100081-01 Prepared & Analyzed: 10/08/20 1,4-Dioxane 48.5 2.0 ug/L 50.00 7.03 83 55-145 1 30 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 28 of 35 Level II QC Report 0int 11/23/20 Waypo ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Work Order: 0100081 Attn: Alec Macbeth Time Submitted: 10/8/2020 7:45:OOAM 231 Haywood Street Asheville, NC 28801 Total Metals - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0152 - 7470A Blank (POJ0152-BLK1) Prepared & Analyzed: 10/09/20 Mercury BRL 0.20 ug/L LCS (POJ0152-BS1) Prepared &Analyzed: 10/09/20 Mercury 9.11 0.20 ug/L 9.375 97 80-120 Matrix Spike (POJ0152-MS1) Source: 0100081-01 Prepared & Analyzed: 10/09/20 Mercury 5.48 0.20 ug/L 9.375 BRL 58 80-120 MI Matrix Spike Dup (POJ0152-MSD1) Source: 0100081-01 Prepared & Analyzed: 10/09/20 Mercury 5.06 0.20 ug/L 9.375 BRL 54 80-120 8 20 MI Post Spike (POJ0152-PS1) Source: 0100081-01 Prepared & Analyzed: 10/09/20 Mercury 2.90 ug/L 5.000-0.0134 58 85-115 Ml, PS Batch POJ0164 - 3005A Blank (POJ0164-BLK1) Prepared & Analyzed: 10/12/20 Arsenic BRL 1.0 ug/L Barium BRL 2.0 ug/L Cadmium BRL 1.0 ug/L Chromium BRL 2.0 ug/L Lead BRL 1.0 ug/L Selenium BRL 5.0 ug/L Silver BRL 1.0 ug/L LCS (POJ0164-BS1) Prepared &Analyzed: 10/12/20 Arsenic 92.6 1.0 ug/L 100.0 93 80-120 Barium 90.5 2.0 ug/L 100.0 90 80-120 Cadmium 96.1 1.0 ug/L 100.0 96 80-120 Chromium 95.5 2.0 ug/L 100.0 96 80-120 Lead 97.9 1.0 ug/L 100.0 98 80-120 Selenium 94.9 5.0 ug/L 100.0 95 80-120 Silver 96.2 1.0 ug/L 100.0 96 80-120 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 29 of 35 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Total Metals - Quality Control Analyte Batch POJ0164 - 3005A Project: Madison Closed Landfill Level II QC Report 11 /23/20 Work Order: 0100081 Time Submitted: 10/8/2020 7:45:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Matrix Spike (POJ0164-MS1) Source: 0100081-02 Prepared & Analyzed: 10/12/20 Arsenic 94.1 1.0 ug/L 100.0 BRL 94 75-125 Barium 150 2.0 ug/L 100.0 56.8 94 75-125 Cadmium 100 1.0 ug/L 100.0 BRL 100 75-125 Chromium 96.9 2.0 ug/L 100.0 BRL 97 75-125 Lead 99.6 1.0 ug/L 100.0 BRL 100 75-125 Selenium 94.4 5.0 ug/L 100.0 BRL 94 75-125 Silver 97.8 1.0 ug/L 100.0 BRL 98 75-125 Matrix Spike Dup (POJ0164-MSD1) Source: 0100081-02 Prepared & Analyzed: 10/12/20 Arsenic 94.4 1.0 ug/L 100.0 BRL 94 75-125 0.2 20 Barium 149 2.0 ug/L 100.0 56.8 92 75-125 0.9 20 Cadmium 101 1.0 ug/L 100.0 BRL 101 75-125 0.9 20 Chromium 97.4 2.0 ug/L 100.0 BRL 97 75-125 0.6 20 Lead 99.5 1.0 ug/L 100.0 BRL 99 75-125 0.1 20 Selenium 91.9 5.0 ug/L 100.0 BRL 92 75-125 3 20 Silver 99.0 1.0 ug/L 100.0 BRL 99 75-125 1 20 Post Spike (POJ0164-PS1) Source: 0100081-02 Prepared & Analyzed: 10/12/20 Arsenic 94.7 ug/L 100.0 0.0700 95 80-120 Barium 152 ug/L 100.0 56.8 95 80-120 Cadmium 99.8 ug/L 100.0 0.135 100 80-120 Chromium 97.6 ug/L 100.0 0.366 97 80-120 Lead 99.0 ug/L 100.0 0.149 99 80-120 Selenium 96.3 ug/L 100.0 -0.226 96 80-120 Silver 98.1 ug/L 100.0 0.00400 98 80-120 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 30 of 35 Level II QC Report 0int 11/23/20 Waypo ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Work Order: 0100081 Attn: Alec Macbeth Time Submitted: 10/8/2020 7:45:OOAM 231 Haywood Street Asheville, NC 28801 Dissolved Metals - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0218 - 3005A Blank (POJ0218-BLK1) Prepared: 10/14/20 Analyzed: 10/23/20 Arsenic BRL 1.0 ug/L Barium BRL 10 ug/L Cadmium BRL 1.0 ug/L Chromium BRL 2.0 ug/L Lead BRL 1.0 ug/L Selenium BRL 5.0 ug/L Silver BRL 1.0 ug/L LCS (POJ0218-BS1) Prepared: 10/14/20 Analyzed: 10/23/20 Arsenic 91.5 1.0 ug/L 100.0 92 80-120 Barium 91.9 10 ug/L 100.0 92 80-120 Cadmium 97.3 1.0 ug/L 100.0 97 80-120 Chromium 93.6 2.0 ug/L 100.0 94 80-120 Lead 95.8 1.0 ug/L 100.0 96 80-120 Selenium 96.5 5.0 ug/L 100.0 96 80-120 Silver 45.6 1.0 ug/L 100.0 46 80-120 L Batch POJ0259 - 7470A Blank (POJ0259-BLK1) Prepared & Analyzed: 10/15/20 Mercury BRL 0.20 ug/L LCS (POJ0259-BS1) Prepared &Analyzed: 10/15/20 Mercury 9.44 0.20 ug/L 9.375 101 80-120 Matrix Spike (POJ0259-MS1) Source: 0100081-05 Prepared & Analyzed: 10/15/20 Mercury 9.40 0.20 ug/L 9.375 BRL 100 80-120 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 31 of 35 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Dissolved Metals - Quality Control Analyte Project: Madison Closed Landfill Level II QC Report 11 /23/20 Work Order: 0100081 Time Submitted: 10/8/2020 7:45:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0259 - 7470A Matrix Spike Dup (POJ0259-MSD1) Source: 0100081-05 Prepared & Analyzed: 10/15/20 Mercury 9.46 0.20 ug/L 9.375 BRL 101 80-120 0.6 20 Post Spike (POJ0259-PS1) Source: 0100081-05 Prepared & Analyzed: 10/15/20 Mercury 5.12 ug/L 5.000-0.0501 102 85-115 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 32 of 35 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 General Chemistry Parameters - Quality Control Analyte Project: Madison Closed Landfill Level II QC Report 11 /23/20 Work Order: 0100081 Time Submitted: 10/8/2020 7:45:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0269 - NO PREP Blank (POJ0269-BLK1) Prepared & Analyzed: 10/15/20 Hardness BRL 5000 ug/L LCS (POJ0269-BS1) Prepared &Analyzed: 10/15/20 Hardness 50000 5000 ug/L 50000 100 90-110 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 33 of 35 Sample Extraction Data Prep Method: 3005A Lab Number Batch Initial Final Date/Time 0100081-04 POJ0218 50 mL 50 mL 10/14/20 10:20 0100081-05 POJ0218 50 mL 50 mL 10/14/20 10:20 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 0100081-04 POJ0259 20 mL 30 mL 10/15/20 11:56 0100081-05 POJ0259 20 mL 30 mL 10/15/20 11:56 Prep Method: 3005A Lab Number Batch Initial Final Date/Time 0100081-01 POJ0164 50 mL 50 mL 10/12/20 8:30 0100081-02 POJ0164 50 mL 50 mL 10/12/20 8:30 0100081-03 POJ0164 50 mL 50 mL 10/12/20 8:30 0100081-04 POJ0164 50 mL 50 mL 10/12/20 8:30 0100081-05 POJ0164 50 mL 50 mL 10/12/20 8:30 0100081-06 POJ0164 50 mL 50 mL 10/12/20 8:30 0100081-07 POJ0164 50 mL 50 mL 10/12/20 8:30 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 0100081-01 POJ0152 20 mL 30 mL 10/09/20 12:50 0100081-02 POJ0152 20 mL 30 mL 10/09/20 12:50 0100081-03 POJ0152 20 mL 30 mL 10/09/20 12:50 0100081-04 POJ0152 20 mL 30 mL 10/09/20 12:50 0100081-05 POJ0152 20 mL 30 mL 10/09/20 12:50 0100081-06 POJ0152 20 mL 30 mL 10/09/20 12:50 0100081-07 POJ0152 20 mL 30 mL 10/09/20 12:50 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 0100081-01 POK0376 10 mL 10 mL 10/16/20 15:54 0100081-02 POK0376 10 mL 10 mL 10/16/20 15:54 0100081-03 POK0376 10 mL 10 mL 10/16/20 15:54 0100081-04 POK0376 10 mL 10 mL 10/16/20 15:54 0100081-05 POK0376 10 mL 10 mL 10/16/20 15:54 0100081-06 POK0376 10 mL 10 mL 10/16/20 15:54 0100081-07 POK0376 10 mL 10 mL 10/16/20 15:54 0100081-08 POK0376 10 mL 10 mL 10/16/20 15:54 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 0100081-01 POJ0116 5 mL 5 mL 10/08/20 10:00 0100081-02 POJ0116 5 mL 5 mL 10/08/20 10:00 0100081-03 POJ0116 5 mL 5 mL 10/08/20 10:00 0100081-04 POJ0116 5 mL 5 mL 10/08/20 10:00 0100081-05 POJ0116 5 mL 5 mL 10/08/20 10:00 0100081-06 POJ0116 5 mL 5 mL 10/08/20 10:00 0100081-07 POJ0116 5 mL 5 mL 10/08/20 10:00 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 34 of 35 5 • 0 Waypoint.- ANALYTICAL 449 SpSingbrook Road • Charlotte, NC 26217 Phone 704/529-6364 • Fax:7041525-0409 Client Company Name:A)n orGk&� Report To/Contact Name: Ll (C Reporting Address: 1,F, VLAAA wo pA S CHAIN OF CUSTODY RECORD PAGE I OF —L QU"OTn�, E # TO ENSURE PROPER BILLING: Project Name. M�tOL( �v Short Hold Analysis s (No)ST Project: (Yes) No) *Please ATTACH an roiect Ific reporting (QC LEVEL 1 II 111 fVT provisions and/or QC Requirements Invoice To: l nrnn n Address: YES NO N/A Samples INTACT upon arrival? Received IN ICE? f PROPER PRESERVATIVES indicated? l Received WITHIN HOLDING TIMES? CUSTODY SEALS INTACT? / x VOLATILES rec'd W/OUT HEADSPACE? PROPER CONTAINERS used? TEMP: Therm ID:6T 1s Observed 2 • I °C /Corr.7_ _ I °C Phone: T2$'�"S1535 VI F,ax (Yes)(No)-:f t`'-'/� Purchase Order No./Billing Reference CLj ��y'D� �j 'r UZ TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Email Address: GL I/1/(aC � �� D19� CCMA Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days Certification. NC , / SC EDD Type: PDF ExcelOther y���,l /d � "Working Days" ❑ 6-9 Days CQ�andard 10 days ❑ Rush Work Must Be r� Pre Approved Other N/A ' _1 Site Location Name: (VICC/n.ifSD✓I � . � L� Samples received after 15:00 will be processed next business day. business days, ✓ Site Location Physical Address: M6CK Ci.Q L Turnaround time is based on excluding weekends and holidays. Water Chlorinated: YES_ NO (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES RENDERED BY WAYPOINT ANALYTICAL, LLC TO CLIENT) Samples Iced Upon Collection: YES NO_ CLIENT DATE TIME COLLECTED MATRIX (SOIL, SAMPLE CONTAINER PRESERVA- ANA YSIS REQUEST D c� REMARKS ID NO. SAMPLE DESCRIPTION COLLECTED MILITARY HOURS WATER, OR SLUDGE) *TYPE NO. SIZE TIMES V SEE BELOW ` DJ 0LD-7A26ICD(0 [ID) to -v 03(o Va tr 3- WA 1,10 X o 02 �-7,06 (coke 1 � (o ?�0 � "I �D 0 ) 61-,0-7 lcaz) 10 a - DO-207410a i0 �v 13 3 is dq NC o l0 !T?-0 bg31 S 05 i ou0 20?�lDo7- i0 , f7Q QL, + �dlo 11c% lrL. K X Xryj K LKW -Mo07-006 to 3PIv 00VV vo k - GI cry Sampler's Signature Sampled By (Print Name) t1 I Q, Affiliation I LAB USE ONLY Upon relinquishing, 6 is Chain of Custody is your authorization for Waypoint Analytical to proceed with the analyses as requested above. Any changes must be Site Arrival Time: submitted in writing to the Waypoint Analytical Project Manager. There will be charges for any changes after analyses have been initialized. Relinquished By: (Sig tur Received By: (Signatu e) Date Military/Hours Additional Comments: Site Departure Time: —2 10 Relinquished y; ignature) Re c ' e By: (i ri ure Date d® Field Tech Fee: Relinquished By: (Sig ure) ^ Received For WaypointAnalytical By: Date02o - ©�� Mileage: NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WITH CUSTODY SEALS FOR TRANSPORTAT ON T THE LABO ORY. C ro No. FMethodofS,himent: SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST CDC UNTIL RECEIVED AT THE LABORATOR .UPS ❑ Hand delivered ❑ Waypoint Analytical Field Service ❑Other V lmv"v J. UJ I : lSKUUNLiWAI tK: UKIIV nIryV VYNI CK: AULlu VVAO I C: KGKA: t3KVV IVrLU LiAwuriLL U 1 r7CK: o NC ❑ Sc ❑ NC ❑ sc ❑ NC o SC ❑ NC ❑ sC ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ sc ❑ NC ❑ SC ❑ NC ❑ SC Page 35 of 35 *rnMTAIM9=0 TVoc r•nncc. A - A _ - n _ ni,.... ra= ci— 0 - ;--A r-.-, vnA - %1^1nfila nrnanics Anal%-;� /7..... u.. A c... —%