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HomeMy WebLinkAbout1302_Cabarrus_Unit1_MSWLF_Sept20GW_FID1521940_20201229Cabarrus County Sanitary Landfill — Unit 1 Semi -Annual Sampling Report Facility Permit # 1302-MSWLF-1974 (September 2020 Sampling Event) Prepared December 2020 pENR U6E ONLY i]Paper Repot DEleclronic Data - Email CD (data loaded: Yes / No) DoGmwrd#: 17DENR Environmental Monitoring Division of Waste Management - Solid Waste ReDOrtina Form Notice: This form and any infommtion attached to it are "Pubic Records" as defined in NC General Stande 132-1. As such, these documents are available for inspection and examination by any person upon request INC General Slatute 132�6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table wth values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The ratification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable a: Compliance Unit NCDENR-DM, Solid Waste Section, 16" Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitorina Data Submittal Information Name a entity submitting data (laboratory, consultant, facility owner) Consultant - CDM Smith Inc. Contact for questions about data formatting. Include data preparer's more, telephone number and E-mail address: Name: Mathew F. Colors, Phone: (919) 325-3500 E-mafi: colonemf@dodmsmith.cem NC Landfill Rule: Actual sampling dates (e.g., Facility rmma: Facility Address: Facility Parrott# (.0500 or .1600) October2044,2006) Carious County Landfill Unit 1 Potato arm MSWLF-L7J September 22-25, 2020 Concord, Carolina 28025 1974 Environmental Status: (Check all that apply) ❑ InitiauRackgmund Monitoring M Detection Monitoring of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells Leachate monitoring data ❑ Assessment Monitoring ❑ Corrective Action ❑ Methane gas monitoring data ❑ Connective action data (specify) Other(specffy) Notification affeched? No. No groundwater or surface water standards were exceeded. x Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water montoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the beat of my knowledge, the information reported and statements marls on this dam submittal and attachments are We and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am swam that them are significant penalties for making any false statement, representation, or certification including the possibility of a fine and Imprisonment. Tide Signature 5400 Glenwood Avenue, Suite 400. Raleigh, North Carolina 27612 Facility Representative Address Date Affix NC Ucani miff Prof ea onal ogost F-0412 NC PE Firm License Number (lt applicable effective May 1, 2009) Revised 62009 Smith 5400 Glenwood Avenue, Suite 400 Raleigh, North Carolina 27612 tel: 919 325-3500 fax: 919 781-5730 December 29, 2020 Ms. Jaclynne Drummond North Carolina Department of Environmental Quality Division of Waste Management Solid Waste Section 2090 U.S. 70 Highway Swannanoa, North Carolina 28778 Subject: September 2020 Semi -Annual Sampling Report Cabarrus County Unit 1 Landfill Facility Permit No. 1302-MSWLF-1974 Dear Ms. Drummond: CDM Smith Inc., on behalf of Cabarrus County, is submitting an electronic copy of the September 2020 semi-annual sampling report for the recent event completed at the Cabarrus County Unit 1 Landfill. This letter report constitutes the second semi-annual sampling event for 2020. The approved monitoring well network consists of compliance wells MW-5, -7, -8A, -10, -11, and background wells CD-1s and -1d. The monitoring network also includes surface water sample locations SW-1 and -2. Field activities and sampling results for the groundwater and surface water samples are discussed below. Field Activities Groundwater and surface water samples from the Cabarrus County Unit 1 Landfill were collected on September 22-25, 2020. Groundwater samples were collected from the monitoring wells by use of disposable, laboratory decontaminated bailers. Monitoring well and surface water sample locations for the Unit 1 landfill are provided on Figure 1. Groundwater elevations were measured at each well prior to sampling and are presented in Table 1. Well construction details for each monitoring well are also provided in Table 1. These groundwater elevations were used to construct potentiometric contours for this sampling event and are presented on Figure 1. After depth to groundwater was measured, each well was purged prior to sampling to provide fresh formation water within the well water column. Each purge volume was measured for pH, conductivity, turbidity, temperature, dissolved oxygen, and oxidation-reduction potential using a YSI-556 multi -parameter water quality meter and a HANNA HI 98703 turbidity meter. The water quality parameters at the time of sampling are presented in Table 2. Of WATER + ENVIRONMENT +TRANSPORTATION + ENERGY + FACILITIES Smith Ms. Jaclynne Drummond December 29, 2020 Page 2 Sampling Results Pace Analytical Services, LLC, located in West Columbia, South Carolina, analyzed the groundwater samples for North Carolina Appendix I volatile organic compounds (VOCs) and metals. In a letter dated May 28, 2019, the Solid Waste Section (SWS) requested that all groundwater and surface water samples collected from landfills be analyzed for 1,4-dioxane after July 1, 2018. On July 1, 2019, the SWS approved the removal of 1,4-dioxane from the sampling program for CD-1s and -1d due to two consecutive non -detect events (January and May 2019). Samples were collected from MW-5, -7, -8A, -10, -11, and SW-1 and -2 during the September 2020 sampling event and analyzed for 1,4-dioxane due to previous detections of 1,4-dioxane. Sample results are provided below. The analytical results were reported to the laboratory specific method detection limit (MDL) and are quantifiable at or below the method reporting limit (MRL). All monitoring wells for the Unit 1 Landfill had detections of analytes above the MDL but below the MRL. These detections were qualified as estimated or "J" flags. The following list indicates the VOCs and metals detected above the MRL at each sampling location. No "J" flag detections are provided. Underlined analytes exceeded the 15A NCAC 02L .0202 (NC 2L) Groundwater Standard, Interim Maximum Allowable Concentration (IMAC), or 15A NCAC 02B .0211 or North Carolina In -Stream Target Value Surface Water Quality Standards for Class C Waters. A complete summary of all detected and estimated concentrations from the May 2011 through the September 2020 sampling events is presented in Table 3. Laboratory data reports are provided in Appendix A. CD-1s (Background) Metals: Volatile Organic Compounds CD-1d (Background) Metals: Volatile Organic Compounds Barium None Detected Barium, Copper, Vanadium, Zinc None Detected MW-5 Metals: Arsenic, Barium, Beryllium, Chromium, Copper, Lead, Nickel, Vanadium, Zinc Volatile Organic Compounds: Chlorobenzene, 1,4-Dioxane MW-7 Metals: Arsenic, Barium, Cobalt, Nickel, Selenium Volatile Organic Compounds: Benzene, Chlorobenzene, 1,2-Dichlorobenzene, 1,4-Dichlorobenzene 1,4-Dioxane 0 Smith Ms. Jaclynne Drummond December 29, 2020 Page 3 MW-8A Metals: Volatile Organic Compounds MW-10 Metals: Volatile Organic Compounds MW-11 Metals: Volatile Organic Compounds SW-1 Metals: Volatile Organic Compounds SW-2 Metals: Volatile Organic Compounds Barium, Cobalt, Copper, Lead, Nickel, Zinc None Detected Arsenic, Barium, Cobalt, Nickel Benzene, Chlorobenzene, 1,2-Dichlorobenzene, 1,4-Dichlorobenzene, IA-Dioxane Barium, Cobalt, Nickel Chlorobenzene, 1,4-Dichlorobenzene, 1,4-Dioxane Barium, Copper, Lead, Vanadium, Zinc None Detected Arsenic, Barium, Beryllium, Chromium, Copper, Lead, Nickel, Vanadium, Zinc None Detected "J" flags were not included in the previous list, but several locations had "J" flag detections that exceeded the standards. These constituents along with their location are listed below. Cobalt: MW-S, SW-1, and -2 Vanadium: CD-1s, MW-7, and -8A Trip and equipment blanks and a duplicate sample were analyzed for quality control. The trip blank had no detections above the MDLs. The equipment blank had an estimated detection of acetone below its NC 2L Groundwater Standard. The duplicate sample, identified as DUP-1, was collected from MW-10, and had similar analyte concentrations as those detected in MW-10. Metals detected above the standards are likely naturally occurring based on concentrations in the background monitoring wells or are from elevated turbidity at the time of sample collection. VOCs detected above the standards in several of the compliance wells will continue to be monitored. Table 4 presents a summary of all analytes detected during the September 2020 sampling event that exceeded the NC 2L Groundwater Standards or IMACs. The next semi-annual sampling event will be completed in the spring of 2021. 0 cSmith Ms. Jaclynne Drummond December 29, 2020 Page 4 If you have any questions or require further explanation, do not hesitate to call me at (919) 325-3500 or by email at colonemf@cdmsmith.com. Very truly yours, Mathew F. Colone, P.G. CDM Smith Inc. cc: Kevin Grant, Cabarrus County 0 Table 1 Monitoring Well Construction Summary and Groundwater Elevations September 2020 Semi -Annual Sampling Event Unit 1- Cabarrus County Landfill Facility Permit Number 1302-MSWLF-1974 Notes: 1. BTOC - Below Top of Casing 2. bgs - Below Ground Surface 3. PWR - Partially Weathered Rock CDM Smith Page 1 of 1 December 2020 Table 2 Water Quality Measurements September 2020 Semi -Annual Sampling Event Unit 1- Cabarrus County Landfill Facility Permit Number 1302-MSWLF-1974 Water Quality Measurements Facility Permit Code Turbidity.R Oxygen CD-1s 1302-MSWLF-1974 5.82 125 17.1 9 6.00 50.1 (background well) CD -Id 1302-MSWLF-1974 5.98 120 17.1 10 4.18 70.4 (background well) 1302-MSWLF-1974 MW-5 6.20 1,007 15.8 16 4.36 19.8 1302-MSWLF-1974 MW-7 6.29 2,828 18.1 9 0.23 13.0 1302-MSWLF-1974 MW-8A 5.93 416 18.7 4 0.69 28.1 1302-MSWLF-1974 MW-10 6.50 1,980 17.1 6 0.35 -29.4 1302-MSWLF-1974 MW-11 6.10 1,004 16.7 11 0.32 20.4 Surface Water Sample Locations 1302-MSWLF-1974 SW-1 7.34 174 17.21 32 10.43 23.7 1302-MSWLF-1974 SW-2 7.56 130 17.12 27 9.91 29.6 Notes: 1. Water quality measurements were taken on September 21-25, 2020. 2. µS/cm - Microsiemens per centimeter 3. mg/L - Milligrams per liter 4. ORP - Oxidation -Reduction Potential 5. NTUs - Nephelometric Turbidity Units 6. mVs - Millivolts 7. S.U. - Standard Units Smith Page 1 of 1 December 2020 Table 3a Detected Groundwater Constituents - Metals September 2020 Semi -Annual Sampling Event Cabarrus County Unit 1 Landfill Facility Permit Number 1302-MSWLF-1974 CD-ls 9-Nov-11 59.7J 0.25B-01,J 4.46J 12.4 1.901 4.411 0.081 11.21 18.2 CD -Is 28-Nov-12 63.8J 0.111 5.65J 11.6 1.431 4.66J 17.1J 16.9 CD-1s 7-May-13 0.941 2.40BJ 35.6J 0.881 0.671 4.041 0.391 1.781 0.131 6.061 5.081 CD -Is 5-Nov-13 46.8J 0.12J 3.59J 10.2 1.351 3.50J 18.4BJ 15.4E CD-1s 6-May-14 28.81 4.14BJ 1.481 0.111 1.031 0.311 3.40J 2.98BJ CD -Is 4-Nov-14 28.7J 0.13J 1.311 0.06J 1.04J 0.111 2.57B-01,J 1.581 CD-ls 5-May-15 1.631 29.5B-01,J 1.331 0.151 1.171 2.40J 2.75B-01,J CD-ls 27-Oct-15 28.4J 0.801 0.39J 0.751 0.121 1.21J 4.19CN,J 0.151 4.10J 3.36E-01,J 1302-MSWLF-1974 CD-1s 17-May-16 29.31 0.941 0.991 0.121 1.011 4.70J 1.931 CD-ls 1-Nov-16 30.5J 1.23J 1.361 0.281 1.35J 4.30J CD-1s 9-May-17 34.1 1.171 1.261 0.201 0.971 6.69J 1.821 CD-1s 31-Oct-17 0.52J 36.31 1.811 0.541 2.871 0.371 1.41J 6.911 4.OJ CD-ls 11-Jun-18 28.9J 4.3J 4.4J CD-ls 17-Dec-18 26.7J 0.601 3.6J 15.01 7.01 9.5J CD-1s 7-May-19 29.8 1.3J 7.OJ 5.1J CD-ls 6-Nov-19 31.9 1.01 1.81E 0.070J 0.73J 5.OJ 7.3JB CD-1s 18-May-20 0.46J 34.5 2.2J 0.92J 0.23J 1.4J 6.4J 6.9J CD-ls 23-Sep-20 34 1.3J 1.51 4.9J 4.2J CD-ld 8-Nov-11 74.5J 0.511 4.08J 4.27J 26.8 2.84J 5.681 24.61 26.3 CD-1d 28-Nov-12 0.33J 37.7J 0.07J 2.38J 0.94J 12.6 1.141 2.50J 8.901 13 CD-ld 8-May-13 0.881 1.02B1 31.2J 0.07J 0.781 4.501 0.49J 1.921 6.181 13.1 CD-1d 5-Nov-13 35.OJ 0.86J 4.341 1.131 1.901 17.1BJ 10.8E CD-ld 6-May-14 1.14J 37.8J 0.07J 0.05J 3.22B1 1.161 7.34J 0.811 2.741 0.12J 6.161 9.41BJ CD-1d 4-Nov-14 43.1J 0.16J 0.111 2.251 9.091 0.87J 2.88J 10.2B-01,J 10.7 CD-ld 5-May-15 34.5B-01,J 0.841 3.63J 0.39J 1.421 5.181 3.68B-01,J CD-1d 27-Oct-15 0.42J 42.31 0.13J 1.87J 2.151 8.181 0.97J 2.49J 4.37CN,J 0.061 10.91 14.0E-01 1302-MSWLF-1974 CD-ld 17-May-16 81.31 0.46J 4.86J 7.42J 26.0 3.13J 7.111 2.11J 0.07J 29.3 29.7 CD-ld 1-Nov-16 32.6J 1.191 0.77J 2.82J 0.33J 1.24J 7.961 4.29J CD-1d 9-May-17 33.91 1.27J 0.521 1.811 6.92J 1.091 6.951 3.12J CD-ld 31-Oct-17 29.5J 0.68J 0.61J 0.111 0.64J 5.381 1.24J CD-1d 12-Jun-18 32.41 2.5J 1.01 6.9J 3.2J CD-ld 17-Dec-18 31.91 9.3J 2.3J 0.41J 3.OJ 6.81 4.1J CD-1d 7-May-19 30.7 1.41 7.4J 2.9J CD-ld 5-Nov-19 0.48J 30.1 1.91 1.11B 0.13J 1.8J 4.7J 8.2JB CD-1d 18-May-20 29.1 0.64J 0.331 5.6J 2.OJ CD-1d 22-Sep-20 0.67J 38 1.91 8.6 0.991 4.21 36 Smith I1 of 7 December 2020 Table 3a Detected Groundwater Constituents - Metals September 2020 Semi -Annual Sampling Event Cabarrus County Unit 1 Landfill Facility Permit Number 1302-MSWLF-1974 North Carolina 2L or IMAC Standard ,,, 1 15 1.00 ,,, MW-5 8-Nov-11 1.981 108 0.19131 0.111 0.541 12 4.391 0.38J 37.71 3.431 10.1 MW-5 9-May-12 0.191 29.2J 0.14J 3.22B1 0.78J 5.9581 0.811 6.22J 0.92J 2.401 9.6481 MW-5 28-Nov-12 0.291 4.571 173 0.081 21.8 2.851 0.131 46.21 3.451 6.66J MW-5 10-May-13 34.1 0.15J 0.07J 1.94J 6.00J 4.611 0.461 16.41 5.151 4.12.1 6.79.1 MW-5 5-Nov-13 1.021 160 0.081 16.6 2.881 0.401 39.81 2.831 7.591 5.90131 MW-5 6-May-14 2.41J 91.91 0.051 0.091 11.8 2.841 0.3481 23.1J 8.85J 5.261 MW-5 4-Nov-14 5.381 173 19.5 2.611 0.411 52.2 3.881 3.771 3.1613-01) MW-5 5-May-15 2.39J 93.2E-01,J 18.8 2.591 0.411 29.1J 3.91J 3.838-01,J MW-5 27-Oct-15 5.491 163 0.101 16.3 1.971 0.331 47.91 2.721 3.01CN,1 2.181 3.22J 1302-MSWLF-1974 MW-5(dup) 27-Oct-15 5.6OJ 174 0.16J 16.5 2.321 0.641 48.4J 3.381 3.53CN,J 3.35.1 5.081 MW-5 17-May-16 1.401 158 0.741 18.7 1.171 0.181 36.31 1.001 2.42J MW-5 1-Nov-16 1.75J 166 1.091 19.3 0.631 0.201 47.1J 3.281 MW-5 9-May-17 0.951 91.01 0.151 0.081 1.591 2.221 0.771 26.51 1.561 3.671 3.83J MW-5 31-Oct-17 1.981 165 1.14J 19.4 1.101 0.331 43.5J 5.181 MW-5 6-Jun-18 2.41 198 O.O69J 26.9 0.28J 46.61 4.3J MW-5 20-Dec-18 102 14.5 2.21 0.321 24.1 5.91 MW-5 8-May-19 0.62J 144 0.13J 0.9O1 19.3 4.81 0.29J 41.3 1.7J 9.5JB MW-5 5-Nov-19 0.7OJ 1.11 164 0.95J 18.1 1.216 0.251 46.3 1.6J 7.618 MW-5 19-May-20 1.3JB 161 0.861 17.5 0.84J 0.24J 43.5 1.11 4.71 MW-5 25-Sep-20 0.92J 2.0 55 0.53 5.0 3.51 6.3 2.5 12 2.81 12 20 MW-7 8-Nov-11 0.16131 0.07131 62.1 1.7OJ 13.01 0.081 6.97J MW-7 9-May-12 0.23J 9.14J 0.1OJ 0.3OJ 0.7461 29.5 3.1561 1.111 85.5 5.36J 6.031 17.78 MW-7 28-Nov-12 0.53J 9.85J 437 45.9 1.27J 30.41 5.011 MW-7 10-May-13 6.73J 300 0.081 49.1 1.961 0.461 11.01 0.79J 0.091 6.361 MW-7 5-Nov-13 448 0.12J 0.41J 45.4 2.57J 1.33J 33.21 2.711 13.51 6.79BJ MW-7 6-May-14 9.34J 460 0.2OJ 0.79J 2.23131 47.6 4.391 4.5561 44.4J 5.94J 16 17.3 MW-7 4-Nov-14 5.74J 391 0.13J 46.0 1.54.1 0.411 31.91 1.691 0.991 1.9813-01,J MW-7 5-May-15 5.77J 398E-01,J 0.31J 49.4 2.351 1.211 31.2J 3.521 3.236-01,J MW-7 27-Oct-15 323 48.2 O.67J 0.091 11.91 1.25CN,J 0.O7J 3.54.1 MW-7 17-May-16 0.26J 3.9OJ 646 0.33J 1.38 6.26J 45.2 5.791 7.011 76.8 3.461 0.131 Fill 23.2 12.4 1302-MSWLF-1974 MW-7(dup) 17-May-16 0.26J 4.08J 604 0.32J 1.37 5.64J 47.6 5.73.1 6.13.1 63.1 3.03J 0.13.1 21.3 13.1 MW-7 1-Nov-16 2.33J 390 0.14J 51.9 0.271 27.4J 2.24J 3.081 MW-7 9-May-17 2.86J 0.36J 48.8 0.3OJ 0.38J 18.4J 2.321 0.O9J MW-7 31-Oct-17 3.17J 383 0.7OJ 42.3 0.431 0.451 25.0J 0.071 2.041 MW-7 6-Jun-18 4.01 551 42.1 0.76.1 45.71 5.81 MW-7 20-Dec-18 3.1J 451 43.5 37.8J 11.5 MW-7 8-May-19 1.61 606 0.611 35.1 0.35.1 0.12.1 77.6 1.1J 4.6J13 MW-7(dup) 8-May-19 1.21 603 0.851 34.0 0.751 0.271 77.1 1.7J 1.81 7.216 MW-7 4-Nov-19 0.321 5.0 320 0.441 40.2 0.24J13 0.0651 9.9 0.066.1 6.8113 MW-7(dup) 4-Nov-19 4.11 304 38.3 0.0671 9.4 0.0601 6.81E MW-7 19-May-20 1.61 646 1.01 35.0 0.781 0.321 82.6 2.9J 0.086J 4.41 MW-7 24-Sep-20 1 1 2.8 1 610 1 1 1 1 27 1 1 1 77 1 64 1 1 2.6J S Mth 2 of 7 December 2020 Table 3a Smith Detected Groundwater Constituents - Metals September 2020 Semi -Annual Sampling Event Cabarrus County Unit 1 Landfill Facility Permit Number 1302-MSWLF-1974 MW-8A 8-Nov-11 0.42131 112 0.07131 0.95J 16.3 24.1 0.46J 52.5 1.591 178 MW-8A 9-May-12 0.3OJ 59.4J 1.12J 13.2 5.781 0.471 34.6J 93.68 MW-8A 28-Nov-12 80.11 0.38J 5.45) 5.171 0.351 10.71 1.821 5.801 28.6 MW-8A 7-May-13 0.3OJ 1.0881 48.7J 0.2OJ 7.54J 6.181 0.291 9.81J 5.161 31.4 MW-8A 5-Nov-13 0.341 64.61 0.2OJ 5.64) 6.721 0.391 10.61 2.211 14.7J 24.113 MW-8A 6-May-14 41.7J 0.07J 7.88J 3.841 0.0881 6.00J 1.87J 4.271 13.1 MW-8A 4-Nov-14 64.61 0.171 5.761 8.181 0.271 11.41 5.661 4.621 17.213-01 MW-8A 5-May-15 31.4B-01,J 5.88J 3.511 5.91J 2.86J 7.41E-01,1 MW-8A 27-Oct-15 54.41 0.181 11.2 10.4 0.121 17.51 2.17J 2.80CN,1 47.8 MW-8A 17-May-16 35.8J 0.12J 8.081 4.031 9.051 27.2 1302-MSWLF-1974 MW-8A 1-Nov-16 61.81 0.14J 18.7 4.401 0.181 27.91 119 MW-8A(dup) 1-Nov-16 64.4J 0.16J 20.1 4.341 0.151 28.5J 125 MW-8A 9-May-17 3.84) 1.16J 66.01 0.661 12.9 58.5 80.7 6.40J 247 MW-8A 31-Oct-17 1.991 2.77J 88.7J 0.87J 0.67J 13.0 29.3 13.5 3O.5J 0.061 3.65J 241 MW-8A 6-Jun-18 2.71 0.94J 65.5J 0.0591 0.591 11.1 29.0 3.01 84.5 4.41 490 MW-8A(dup) 6-Jun-18 2.8J 1.01 69.7J 0.O75J 0.86J 10.9 30.5 3.41 86.6 5.41 530 MW-8A 21-Dec-18 2.61 2.71 104 1.1 8.01 25.9 7.51 45.01 4.4J 246 MW-8A 8-May-19 3.SJ 2.31 77.9 0.67 6.1 11.8 2.2 33.2 3.6J 88.1 MW-8A 5-Nov-19 1.51 173 0.11J 13.3 28.1B 1.9 189 0.0861 4.0J 671 MW-8A 19-May-20 4.1J 0.62J 91.1 0.24J 0.93J 8.3 22.1 2.5 94.7 0.161 2.01 260 MW-8A(dup) 19-May-20 4.0J 0.57J 91.8 0.23J 0.79J 8.7 21.0 2.9 96.5 0.069J 2.5J 277 MW-8A 24-Sep-20 0.76J 1.5J 120 0.31J 16 1 13 1 1.7 90 1 2.6J 15 MW-10 8-Nov-11 0.2581 14.7 219 0.47131 25.1 4.09J 123 6.66J 0.111 5.22J MW-30 9-May-12 0.23J 24.5 194 0.4OJ 0.78J 36.8 3.591 0.13J 168 9.44J 2.251 6.2081 MW-10 28-Nov-12 0.331 16.8 193 0.41J 0.721 25.9 3.26J 0.251 129 8.601 O.24J 2.33.1 MW-30 10-May-13 0.25J 16.7 174 0.511 1.98J 32.6 4.101 0.37J 153 7.771 0.071 5.301 MW-10 5-Nov-13 0.371 10.6 195 0.49J 22.8 3.64.1 0.301 111 6.991 0.15.1 13.91 5.28131 MW-30 6-May-14 15.4 165 0.41J 33.8 3.091 0.2181 146 8.011 6.051 2.421 MW-10 4-Nov-14 16.2 166 0.53J 1.31B-01,J 25.5 3.591 1.271 122 7.151 5.421 5.77B-01,J MW-10 5-May-15 17.1 157B-01 0.48J 29.2 2.641 0.421 140 10.4 2.241 2.76E-01,J MW-10 27-Oct-15 0.25J 12.8 167 0.52J 25.2 2.52.1 0.261 122 6.911 2.56CN,J 0.10.1 2.961 2.47.1 MW-10 17-May-16 16.7 166 0.39J 1.67J 31.6 0.721 0.211 147 1.06J 3.21J 2.881 1302-MSWLF-1974 MW-10 1-Nov-16 14.6 157 0.49J 1.98 32.2 0.71.1 0.271 146 3.71.1 MW-10 9-May-17 7.93J 138 0.29J 1.81J 20.9 1.281 0.351 92.0 1.63J 0.061 2.741 MW-10 31-Oct-17 15.7 162 0.54J 2.82J 27.1 0.561 133 O.10J MW-30 6-Jun-18 15.5 170 0.35J 3.61 26.1 0.67J 120 8.21 MW-10 20-Dec-18 23.5J 3.71 8.01 3.11 MW-10(dup) 20-Dec-18 22.11 3.4J 7.6J 2.51 MW-10 8-May-19 14.1 1 116 0.22J 1.31 20.9 3.61 0.101 123 4.0J13 MW-10 5-Nov-19 12.0 172 0.38J 1.61 22.6 0.471 0.211 95.3 0.068J 4 8.41 MW-10 19-May-20 15.4 131 0.36J 1.31 27.0 0.491 0.151 0.0541 2.1J 2.41 MW-10 24-Sep-20 27 140 0.35J 1.71 27 0.611 4.61 2.81 MW-10(dup) 24-Sep-20 27 140 0.45 1.81 1 27 0.581 4.8J 2.91 3 of 7 December 2020 Table 3a Detected Groundwater Constituents - Metals September 2020 Semi -Annual Sampling Event Cabarrus County Unit 1 Landfill Facility Permit Number 1302-MSWLF-1974 North Carolina 2L or IMAC Standardr rr r., rr r1 20 1 r rrr MW-11 8-Nov-11 0.29131 509 0.06131 0.12J 24.2 27.2 0.201 37.91 7.701 10.6 MW-11 9-May-12 79.5J 18.2 3.791 0.42J 10.6J 1.10J 1.961 50.18 MW-11 28-Nov-12 494 0.151 35.8 6.621 0.301 38.11 9.361 9.48J MW-11 10-May-13 52.9J 2.56J 0.431 1.711 2.56J 1.101 55.7 MW-11 5-Nov-13 1.321 503 0.061 34.5 11.9 0.471 38.71 8.261 0.31J 5.7981 11.713 MW-11 6-May-14 1.75J 144 0.07J 6.721 3.921 0.1713.1 13.0J 5.16J 5.12.1 23.1 MW-11 4-Nov-14 4.001 449 35.1 11.3 0.371 39.81 3.541 4.091 2.38B-01,J MW-11 5-May-15 2186-01 13.0 11.9 0.541 20.6J 9.53J 39.58-01 MW-11 27-Oct-15 2.121 503 37.0 16.4 0.621 44.81 3.771 2.89CN,1 2.411 4.68J MW-11 17-May-16 163 10.9 2.121 11.7J 5.561 19.4 1302-MSWLF-1974 MW-11 1-Nov-16 455 0.111 41.7 15.2 0.561 40.41 5.711 MW-11 9-May-17 151 7.92J 3.191 0.091 10.81 2.79.1 18.9 MW-11 9-May-17 150 0.081 7.851 3.201 0.101 10.71 2.901 19.5 MW-11 31-Oct-17 515 0.181 35.7 8.441 0.29J 37.8J MW-11 (dup) 31-Oct-17 0.87J 498 0.16J 1.181 34.7 7.601 0.321 37.01 3.301 MW-11 6-Jun-18 1.31 438 27.1 6.5.1 32.9J 15.0 M W-11 20-Dec-18 SOS 3.51 1.61 4.31 26.1 MW-11 9-May-19 191 0.084J 12.5 1.6.1 0.191 12.8 8.118 MW-11 5-Nov-19 530 34.4 3.91 0.411 36.0 1.11 8.3J MW-11 19-May-20 189 0.47J 18.0 2.2.1 0.281 11.3 12.5 MW-11 24-Sep-20 250 15 0.261 17 2.9J 2.6.1 Notes: 1. All units are in micrograms per liter (parts per billion). 2. "- Interim Maximum Allowable Concentration (IMAC) 3. dup - Duplicate Sample 4. J - Indicates the analytical result is an established concentration between the method detection limit and the adjusted reporting limit. 5. B, B-01-The analyte concentration detected in the method blank was greaterthan the method detection limit. 6. CN - Detected silver concentrations were determined to be the result of contamination from the preservative acid. Concentration exceeds the 15A NCAC 02L .0202 (North Carolina 2L) or IMAC Standard - Indicates the result is below the detection limit. S Mth 4 of 7 December 2020 Table 3b Detected Groundwater Constituents - Volatile Organic Compounds September 2020 Semi -Annual Sampling Event Cabarrus County Unit 1 Landfill Facility Permit Number 1302-MSWLF-1974 o oo o CD-1s 8-Nov-11 CD-ls 27-Nov-12 0.41 0.21 CD -Ss 7-May-13 CD-ls 5-Nov-13 CD-1s 6-May-14 CD -Is 4-Nov-14 CD-1s 5-May-15 CD-ls 27-Oct-15 1302-MSWLF-1974 CD-1s 17-May-16 CD-1 s 1-Nov-16 CD-1s 9-May-17 CD-ls 31-Oct-17 CD-1s 11-Jun-18 CD-ls 17-Dec-18 1.2 CD-1s 7-May-19 CD-ls 6-Nov-19 CD-1s 18-May-20 CD-ls 23-Sep-20 CD-ld 8-Nov-11 CD-ld 27-Nov-12 CD-ld 7-May-13 CD-ld 5-Nov-13 CD-ld 6-May-14 CD-ld 4-Nov-14 CD-ld 5-May-15 CD-ld 27-Oct-15 1302-MSWLF-1974 CD-ld 17-May-16 CD-ld 1-Nov-16 CD-ld 31-0ct-17 CD-ld 12-Jun-18 CD-ld 17-Dec-18 CD-ld 7-May-19 CD-ld 5-Nov-19 CD-1d 18-May-20 CD-ld 22-Sep-20 MW-5 7-Nov-11 0.81 7.6 6.2 MW-5 8-May-12 0.3J MW-5 27-Nov-12 1.3 18 0.6B1 14 0.31 0.21 MW-5 9-May-13 1.7J 0.3J 4.2 3.4 MW-5 4-Nov-13 1.5 18 0.61 13 0.61 MW-5 5-May-14 1.01 11 0.3J 7.4 MW-5 3-Nov-14 1.6 23 0.71 16 0.21 MW-5 4-May-15 0.9J 16 0.51 10 MW-5 26-OR-15 1.1 21 0.61 14 1302-M5WLF-1974 MW-5)dup) 26-Oct-15 2.0 20 0.6J 13 MW-5 16-May-16 1.2 19 0.51 12 MW-5 31-Oct-16 2.4 26 0.7J 15 2.6J MW-5 8-May-17 0.81 16 9.1 MW-5 30-Oct-17 1.2 23 0.51 14 MW-5 6-Jun-18 1.1 21.6 0.601 12.3 1.5 MW-5 20-Dec-18 0.52J 12.4 5.9 87.7 MW-5 7-May-19 1.2 18.2 9.9 142 MW-5 4-Nov-19 1.5 29.2 0.6J 14.1 142 5.11 MW-5 19-May-20 0.62J 126 3.2J MW-5 25-Sep-20 0.79 0.44J 15 MW-7 7-Nov-11 2.3 24 0.81 13 0.81 0.51 1.11 MW-7 8-May-12 0.91 11 0.81 8.5 0.61 1.01 MW-7 27-Nov-12 2.3 29 0.8B1 14 0.71 0.3J 0.41 MW-7 9-May-13 1.81 2.2 24 0.8J 15 0.7J 0.3J 6.3 MW-7 5-Nov-13 1.4 17 0.81 11 0.61 0.51 MW-7 5-May-14 1.7 16 0.6J 13 0.7J 0.4J MW-7 3-Nov-14 1.6 29 0.91 14 0.51 0.2J MW-7 4-May-15 1.6 33 0.8J 0.31 MW-7 26-0ct-15 1.9 38 0.91 16 0.31 MW-7 16-May-16 1.0 19 0.7J 12 0.6J 1302-MSWLF-1974 MW-7)dup) 16-May-16 0.81 17 0.81 11 0.61 0.61 MW-7 31-0ct-16 1.4 31 0.91 14 0.4J 2.51 MW-7 8-May-17 1.5 32 0.801 14.0 MW-7 30-0ct-17 1.5 29 0.901 13.0 MW-7 6-Jun-18 1.9 32.2 0.961 12.7 0.97J MW-7 20-Dec-18 1.5 16.7 4.8 76.6 MW-7 7-May-19 1.0 20.9 0.741 9.80 1.7 0.541 130 9.7J MW-7)dup) 7-May-19 1.2 21.1 0.831 10.3 1.4 0.54J 131 9.4J MW-7 4-Nov-19 2 45.8 0.961 14.8 66.5 13.9 0.861 MW-7)dup) 4-Nov-19 2.7 0.531 0.851 16.5 61.5 12.1 0.47 MW-7 19-May-20 0.86J 0.621 0.51J 105 MW-7 24-Sep-20 1.2 26 0.68 10 93 Smith 5 of 7 December 2020 Table 3b Detected Groundwater Constituents - Volatile Organic Compounds September 2020 Semi -Annual Sampling Event Cabarrus County Unit 1 Landfill Facility Permit Number 1302-MSWLF-1974 North Carolina 2L or IMAC Standard 000 1 o 4,000 50 o 3 20 MW-8A 7-Nov-11 1 MW-8A 8-May-12 MW-8A 27-Nov-12 MW-8A 6-May-13 MW-8A 4-Nov-13 MW-8A 5-May-14 MW-8A 3-Nov-14 MW-8A 4-May-15 3.81 MW-8A 26-0ct-15 MW-8A 16-May-16 1302-MSWLF-1974 MW-8A 31-Oct-16 MW-8A(dup) 31-Oct-16 MW-8A 8-May-17 MW-8A 30-0ct-17 MW-8A 6-Jun-18 0.73J MW-8A(dup) 6-Jun-18 MW-8A 20-Dec-18 MW-8A 7-May-19 2.4 MW-8A 4-Nov-19 MW-8A 19-May-20 MW-8A(dup) 19-May-20 MW-8A 24-Sep-20 MW-10 7-Nov-11 8.21 1.3 31 0.81 8.4 MW-10 8-May-12 1.3 32 1.01 8.9 011 MW-10 27-Nov-12 1.3 35 1.1B1 9.5 0.31 MW-10 9-May-13 5.01 1.1 6.01 31 0.91 8.2 MW-10 4-Nov-13 73J 1.2 4.2J 39 1.11 10 0.91 MW-10 5-May-14 1.1 7.91 39 1,21 10 0.51 MW-10 3-Nov-14 23J 1.3 42 1.31 11 0.41 MW-10 4-May-15 8.5J 1.1 40 1,21 11 0.41 MW-10 26-OC-15 1.2 41 1.11 9.8 0.31 MW-10 16-May-16 1.0 39 1.01 9.6 1302-MSWLF-1974 MW-10 31-0ct-16 1.2 44.0 1.31 30 0.41 MW-10 8-May-17 1.01 41.0 1.21 9.2 0.3J MW-10 30-0ct-17 1.0 1.01 9.0 MW-10 6-Jun-18 1.2 41.7 1.11 8.7 10.2J MW-10 20-Dec-18 1AJ MW-10 dup 20-Dec-18 MW-10 8-May-19 1.1 43.8 1.1 104 24.6 MW-10 4-Nov-19 1.4 1.4 85.6 31.5 33.6 MW-10 19-May-20 0.931 0.94J 82.8 MW-10 24-Sep-20 1.5 40 0.86 6. 76 7.1 MW-10(dup) 24-Sep-20 1.5 40 0.96 79 MW-11 7-Nov-11 1.3 13 7.6 0.51 0.41 0.51 MW-11 8-May-12 MW-11 27-Nov-12 1.3 18 0.7B1 8.= 0.41 0.3J 0.4J MW-11 9-May-13 1.01 MW-11 4-Nov-13 1.1 16 0.51 7.6 0.4J MW-11 5-May-14 0.4J 4.5 1.7 MW-11 3-Nov-14 1.4 19 0.71 9.4 0.51 MW-11 4-May-15 0.4J 6.0 1.8 MW-11 26-0ct-15 0.91 16 0.61 9.0 0.41 MW-11 16-May-16 0.3J 4.6 1.6 1302-MSWLF-1974 MW-11 31-0ct-16 1.2 18 0.71 8.8 2.51 MW-11 8-May-17 3.8 MW-11(dup) 8-May-17 2.91 MW-11 30-Oct-17 1.2 18 0.7J 8.6 MW-11(dup) 30-Oct-17 1.1 16 0.71 8.0 MW-11 6-Jun-18 13.5J 0.901 14.0 5.5 MW-11 20-Dec-18 2.1 MW-11 8-May-19 6.8 2.1 26.2 3.4J MW-11 4-Nov-19 1 18: 0.751 0.671 7.4 46.2 10.8 MW-11 19-May-20 �0571 12.1 MW-11 24-Sep-20 5.2 1.7 1 1 1 20 Notes: 1. All units are in micrograms per liter (parts per billion). 2.- Interim Maximum Allowable Concentration (IMAC) 3. dup - Duplicate Sample 4. J - Indicates the analytical result is an established concentration between the method detection limit and the adjusted reporting limit. 5. B - The analyte concentration detected in the method blank was greater than the method detection limit. Concentration exceeds the 15A NCAC 02L .0202 (North Carolina 2L) or MAC Standard - Indicates the result is below the detection limit. Smith DM 6 of 7 December 2020 Table 3c Detected Surface Water Constituents - Metals and Volatile Organic Compounds September 2020 Semi -Annual Sampling Event Cabarrus County Unit 1 Landfill Facility Permit Number 1302-MSWLF-1974 North Carol!", 11 or In-Itr­ Life Standard SW-1 9-Nov-Il 94.01 0.771 2.601 0.231 5.32J 1.741 ZSW-1 9-May-12 DRY DRY 1W-1 28-Nov-12 DRY DRY O W1 4931 8146 22.83J 0.121 2.01 0.31 SW-1 5-May-14 1. 01 0.371 4.63B1 6.341 3.5881 9.71J 1411 SW-1 3-Nov-14 DR V DRY SW-1 5-May-15 DRY DRY SW-1 29-OC-15 .091 2371 9I15JI SW-1 119-M.J .21 5.33^0.0865.21302-MSWLF-1974 ay16 3574 I I I I I 1I SW-1 1-Nov-16 DRY DRY SW-1 10-May-17 I I 66.61 I 3.691 I 2.� 1.041 0.071 I 5.92J SW-1 31-Ocb17 DRY DRY SW-1 7-J11-18 DRY DRY W-1 18-Dec-18 0.701 5761 1,051 1.81 2,61 1,11 0.341 4,4) 3.24.91 421 SW1 0 9-May-19 669 761 3.11 1,31 0.1651 1.31 3.91B 8. 7 SW-1 6-No19 59.1 0.381 0B00642.91 081 5. S.9 SW-1 19-May-20 65.4 0.712.91 0.214.51 3.1 9.9 SW-1 4.5J 1 7.2 8.6 1 SW 9-Nov-11 DRY DRY SW-2 9-May-12 I I 65.31 I I I 1.06J I 0.8W 1.6W 0.851 3.33J I 1.33J SW-2 28-Nov-12 DRY DRY SW-2 30-May-13 I 0.971 78.91 I I I 0.631 I 2.531 I 2.20J I 0.841 6.36.1 I 3.021 I 6.051 SW-2 5-Nov-13 DRY DRY SW-2 6-May-14 1.451 137 1 0.051 1 3,291 3.651 1.52131 6.991 3.681 ].111 24.5 SW-2 3-Nov-14 1.881 67.01 1 1 12.7 0.571 0.051 1.421 1.08J 5.15B-01,J 6.0J 1.8 SW-2 5-May-15 73.21-01,1 3.16) 1.211 6.341 3.- 361SW-2 29-Oct-15 1.681 81.11 0.101 0.691 3.fi41 0.951 4.601 6.501 3.28CN,1 1.931 481 ��5 1302-MSWLF-1974 SW-2 19-May-16 2.351 89.01 0.941 12.2 7.231 11.9 8.731 8.331 3.401 32.7 SW-2 1-Nov-16 DRY DRY SW-2 30-May-1] I I 94.71 I I 2.221 0.891 I 0.31J I 4.811 SW-2 31-Oct-1] DRY DRY SW-2 7-Jun-18 0.991 42.91 1.41 0.371 2.51 SW-2 18-Dec-18 0.631 71.81 0.111 1.91 1.81 1.91 3.11 4.31 3.61 2.1 1.8 SW-2 30-May-19 83.8 2.31 1.71 5.1 2.81B ].3 SW-2 6-Nov-19 0.621 83.9 0.661 0.35J 3.31B 0.221B 2.71 1.31 ].11B 3.8 SW-2 19-May-20 0.691 100 0.231 3.51 3.21 4.11 2 5.4 1.71 8.61 30.2 6.7 SW-2 25-Sep-20 2.7 91 0.77 25 4.81 18 8.8 2.71 33 34 Notes.• 1. All units are in micrograms per liter (parts per billion). 2. Standards obtained from section 15A NCAC 02B .0211(North Carolina 2B) or In -Stream Target Value Surface Water Standards for Class C Waters (June 2019). 3. 131- A Standard for total chromium has not been established. The value provided is for chromium (III). 4. NS - No Standard 5.' - North Carolina In -Stream Target Value 6. J - Indicates the analytical result is an estimated concentration between the method detection limit and the limit of quantitation. 7. B - The analyte concentration detected in the method blank was greater than the method detection limit. 8. CN - Detected silver concentrations were determined to be the result of contamination from the preservative acid. Concentration exceeds the North Carolina 2B or In -Stream Target Value Freshwater Aquatic Life Standard for Class C Waters - June 2019 - Indicates the result is below the detection limit. S Mth 7 of 7 December 2020 Table 4 Constituents Detected Above Standards September 2020 Semi -Annual Sampling Event Unit 1- Cabarrus County Landfill Facility Permit Number 1302-MSWLF-1974 Standard Facility Permit Number Monitoring Well Parameters Exceeding North Carolina 2L or IMAC Code Assessment Monitoring - September 2020 CD-1s 1302-MSWLF-1974 Vanadium* (background well) CD-1d 1302-MSWLF-1974 Vanadium* (background well) 1302-MSWLF-1974 MW-5 Cobalt*, Vanadium*, 1,4-Dioxane 1302-MSWLF-1974 MW-7 Cobalt*, Selenium, Vanadium*, Benzene, 1,4-Dichlorobenzene, 1,4-Dioxane 1302-MSWLF-1974 MW-8A Cobalt*, Vanadium* 1302-MSWLF-1974 MW-10 Arsenic, Cobalt*, Nickel, Benzene, 1,4-Dichlorobenzene, 1,4-Dioxane 1302-MSWLF-1974 MW-11 Cobalt*, 1,4-Dioxane Notes: 1. * - Constituent exceeded the Interim Maximum Allowable Concentration (IMAC) 2. Bold - "J" Flag - Indicates the analytical result is an estimated concentration between the method detection limit and the method reporting limit. Smith Page 1 of 1 December 2020 N W+E TVs MGW-15 MGW-1 -i# CD-1s o\ 733.75 CD-1tl MGW-14 SW-3 733.48 1 9° °'O ` CD-4 Rep 4 - CD-2\ C&D` ` 730.52 M 722.43 Landfill > ,1ti0 CD-7-\ 706.76 CD-9 706.15� Unit 2 - ----I o MGW-17 I _ -----_ Unit' —`—�710 700.83 MGW-2 689.38 MW-10 MW-8A ' / 693.14 710.17" MGW-16 695.49 MW /MW-G 707.06 I 685.86 680.980.96 MW-11 690 MW-X � /U _ � ' 678.32 � t 3 � MW-6 MGW-13 p MGW-12 7 700.62 I nl - 1 679.18 6a ,. Borrow Area MGW-3� 'MW-E Rep 0 y >. I 686.55 i SW-1 690 MW-DM67627deep, MW-F / MW� 696.64 :.;,I 1 672.87 .1 / - - ' 685.43 ` / , -670 MGW-8 MW-K 1 -i 682.20-;t1r:.., / MW-1 MGW-4� AMW-1d1-*i 665.85 - - - 660 580 67Z33.\ 'SW-2 - AMW-1s MW-H Mw5 l MGW-7 676.70� �- MW-H deep AMW-2s /MW-3 yy° 676.22 fi74.43 65749/ 670 AMW-2tl °� / MW69 677.59 649.69 6y 658.18 6y° MW-3 deep MGW-6 MW-L deep 659.66 659.90 MGW-5 Scale in Feet 0 Soo 1000 Map Data Source: 2015 Aerial Photograph, Cabarrus County, North Carolina OneMap. MGW-11 MGW-10 MGW-9 Is AXH:11Iww, Groundwater Monitoring Well Surface Water Sample Location ♦ Landfill Gas Well Location Potentiometric Contour 680 — (dashed where inferred( Contour Interval = 10 Feet Appendix A aceAnalytical Report of Analysis CDM Smith 5400 Glenwood Avenue Suite 400 Raleigh, NC 27612 Attention: Mathew Colone Project Name: Cabarrus County LF Background Wells Lot Number:V124026 Date Completed:10/18/2020 10/18/2020 12:34 PM Approved and released by: Project Manager 11: Cathy S. Dover =w�4 aecRFo���A16 TNI / AM Amflvue Acm^rmm Fvu rj (' 4eOfFAi� ACC R E OI TEO TESTINGL aORlTOAY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 50 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative CDM Smith Lot Number: V124026 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. BOD The seed correction factor was above the method range of 0.6 to 1.0 for V124026-001 (CD-1 s). SCF=1.44. If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 2 of 50 PACE ANALYTICAL SERVICES, LLC Sample Summary CDM Smith Lot Number: V124026 Project Name: Cabarrus County LF Background Wells Project Number: Sample Number Sample ID Matrix Date Sampled Date Received 001 CD-1s Aqueous 09/23/2020 0830 09/24/2020 002 CD-1d Aqueous 09/22/20201700 09/24/2020 (2 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 50 PACE ANALYTICAL SERVICES, LLC Detection Summary CDM Smith Lot Number: V124026 Project Name: Cabarrus County LF Background Wells Project Number: Sample Sample ID Matrix Parameter Method Result Q Units Page 001 CD-1s Aqueous Alkalinity @ pH 4.5 su SM 232013- 51 mg 5 001 CD-1s Aqueous Chloride 9056A 5.5 mg/L 5 001 CD-1s Aqueous CO2 (calculation) SM 4500-CO2 96 mg/L 5 001 CD-1s Aqueous Nitrate - N 9056A 0.21 mg/L 5 001 CD-1s Aqueous Sulfate 9056A 2.5 mg/L 5 001 CD-1s Aqueous TDS SM 2540C- 140 mg/L 5 001 CD-1s Aqueous Methane RSK - 175 5.9 J ug/L 8 001 CD-1s Aqueous Barium 6020B 34 ug/L 10 001 CD-1s Aqueous Chromium 6020B 1.3 J ug/L 10 001 CD-1s Aqueous Copper 6020B 1.5 J ug/L 10 001 CD-1s Aqueous Iron 6020B 630 ug/L 10 001 CD-1s Aqueous Manganese 6020B 21 ug/L 10 001 CD-1s Aqueous Vanadium 6020B 4.9 J ug/L 10 001 CD-1s Aqueous Zinc 6020B 4.2 J ug/L 10 002 CD-1d Aqueous Alkalinity @ pH 4.5 su SM 232013- 53 mg 11 002 CD-1d Aqueous Chloride 9056A 3.1 mg/L 11 002 CD-1d Aqueous Sulfate 9056A 2.0 mg/L 11 002 CD-1d Aqueous TDS SM 2540C- 130 mg/L 11 002 CD-1d Aqueous Antimony 6020B 0.67 J ug/L 15 002 CD-1d Aqueous Barium 6020B 38 ug/L 15 002 CD-1d Aqueous Chromium 6020B 1.9 J ug/L 15 002 CD-1d Aqueous Copper 6020B 8.6 ug/L 15 002 CD-1d Aqueous Iron 6020B 2300 ug/L 15 002 CD-1d Aqueous Lead 6020B 0.99 J ug/L 15 002 CD-1d Aqueous Manganese 6020B 47 ug/L 15 002 CD-1d Aqueous Nickel 6020B 4.2 J ug/L 15 002 CD-1d Aqueous Vanadium 6020B 8.8 ug/L 15 002 CD-1d Aqueous Zinc 6020B 36 ug/L 15 (28 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 50 Inorganic non-metals Client:CDM Smith Laboratory ID:VI24026-001 Description: CD-1s Matrix: Aqueous Date Sampled:09/23/2020 0830 Project Name: Cabarrus County LF Date Received: 09/24/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 09/28/2020 1221 AAB 68132 1 (BOD, 5 day) SM 521OB-2011 1 09/29/2020 1456 MOM 09/24/2020 1859 13595 1 (Chloride) 9056A 1 09/24/2020 2234 AMR 67957 1 (CO2 (calcula) SM 4500-CO2 D 1 09/28/2020 1221 AAB 1 (COD) SM 5220D-2011 1 10/03/2020 2053 SRB 68746 1 (Nitrate - N) 9056A 1 09/24/2020 2234 AMR 67959 1 (Sulfate) 9056A 1 09/24/2020 2234 AMR 67954 1 (TDS) SM 2540C-2011 1 09/27/2020 1820 MOM 68070 1 (TOC) SM 531OC-2011 1 10/01/2020 1842 DMA 68547 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 51 20 20 mg CaCO3/L 1 BOD, 5 day SM 521 OB-2011 2.0 U7 2.0 0.18 mg/L 1 Chloride 9056A 5.5 1.0 0.20 mg/L 1 CO2 (calculation) 124-38-9 SM 4500-CC2 D 96 27 27 mg/L 1 COD SM 5220D-2011 20 U 20 20 mg/L 1 Nitrate - N 9056A 0.21 0.020 0.0050 mg/L 1 Sulfate 9056A 2.5 1.0 0.20 mg/L 1 TDS SM 2540C-2011 140 25 25 mg/L 1 TOC SM 531OC-2011 1.0 U 1.0 1.0 mg/L 1 Footnote(s): 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 50 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI24026-001 Description: CD-1s Matrix: Aqueous Date Sampled:09/23/2020 0830 Project Name: Cabarrus County LF Date Received:09/24/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/28/20201839 TML 68113 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Footnote(s): 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 50 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI24026-001 Description: CD-1s Matrix: Aqueous Date Sampled:09/23/2020 0830 Project Name: Cabarrus County LF Date Received:09/24/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/28/20201839 TML 68113 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 105 70-130 1,2-Dichloroethane-d4 112 70-130 Toluene-d8 98 70-130 Footnote(s): 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 50 Dissolved Gases Client:CDM Smith Laboratory ID:VI24026-001 Description: CD-1s Matrix: Aqueous Date Sampled:09/23/2020 0830 Project Name: Cabarrus County LF Date Received:09/24/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 10/01/2020 1348 TML 68503 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1 Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1 Methane 74-82-8 RSK - 175 5.9 J 10 2.5 ug/L 1 Footnote(s): 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 50 CVAA Client:CDM Smith Laboratory ID:VI24026-001 Description: CD-1s Matrix: Aqueous Date Sampled:09/23/2020 0830 Project Name: Cabarrus County LF Date Received:09/24/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 09/25/2020 1509 JA132 09/25/2020 1000 67859 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 Footnote(s): 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 50 ICP-MS Metals Client:CDM Smith Laboratory ID:VI24026-001 Description: CD-1s Matrix: Aqueous Date Sampled:09/23/2020 0830 Project Name: Cabarrus County LF Date Received:09/24/2020 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 10/06/2020 0218 BPK Prep Date Batch 10/03/2020 1555 68279 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.0 U 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 34 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.3 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 5.0 U 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.5 J 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 630 50 13 ug/L 1 Lead 7439-92-1 6020B 1.0 U 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 21 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B 5.0 U 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 4.9 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 4.2 J 10 2.5 ug/L 1 Footnote(s): 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 50 Inorganic non-metals Client:CDM Smith Laboratory ID:VI24026-002 Description: CD-1d Matrix: Aqueous Date Sampled:09/22/2020 1700 Project Name: Cabarrus County LF Date Received:09/24/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 09/28/2020 1227 AAB 68132 1 (Chloride) 9056A 1 10/01/2020 2333 AMR 68633 1 (Sulfate) 9056A 1 10/01/2020 2333 AMR 68625 1 (TDS) SM 2540C-2011 1 09/27/2020 1820 MOM 68070 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su Chloride Sulfate TDS SM 2320B-2011 53 20 20 mg CaCO3/L 1 9056A 3.1 1.0 0.20 mg/L 1 9056A 2.0 1.0 0.20 mg/L 1 SM 254OC-2011 130 25 25 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 50 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI24026-002 Description: CD-1d Matrix: Aqueous Date Sampled:09/22/2020 1700 Project Name: Cabarrus County LF Date Received:09/24/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/28/20201901 TML 68113 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 50 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI24026-002 Description: CD-1d Matrix: Aqueous Date Sampled:09/22/2020 1700 Project Name: Cabarrus County LF Date Received:09/24/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/28/20201901 TML 68113 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 100 70-130 1,2-Dichloroethane-d4 110 70-130 Toluene-d8 103 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 50 CVAA Client:CDM Smith Laboratory ID:VI24026-002 Description: CD-1d Matrix: Aqueous Date Sampled:09/22/2020 1700 Project Name: Cabarrus County LF Date Received:09/24/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 09/25/2020 1511 JA132 09/25/2020 1000 67859 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 50 ICP-MS Metals Client:CDM Smith Laboratory ID:VI24026-002 Description: CD-1d Matrix: Aqueous Date Sampled:09/22/2020 1700 Project Name: Cabarrus County LF Date Received:09/24/2020 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 10/06/2020 0225 BPK Prep Date Batch 10/03/2020 1555 68279 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 0.67 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.0 U 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 38 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.9 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 5.0 U 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 8.6 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 2300 50 13 ug/L 1 Lead 7439-92-1 6020B 0.99 J 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 47 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B 4.2 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 8.8 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 36 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of 50 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: V124026 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 16 of 50 Inorganic non-metals - MB Sample ID: VQ67954-001 Matrix: Aqueous Batch: 67954 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Sulfate 1.0 U 1 1.0 0.20 mg/L 09/24/2020 2138 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 17 of 50 QC Data for Lot Number: V124026 Inorganic non-metals - LCS Sample ID: VQ67954-002 Matrix: Aqueous Batch: 67954 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 20 20 1 101 80-120 09/24/2020 2215 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 18 of 50 QC Data for Lot Number: V124026 Inorganic non-metals - MB Sample ID: VQ67957-001 Matrix: Aqueous Batch: 67957 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Chloride 1.0 U 1 1.0 0.20 mg/L 09/24/2020 2138 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 19 of 50 QC Data for Lot Number: V124026 Inorganic non-metals - LCS Sample ID: VQ67957-002 Matrix: Aqueous Batch: 67957 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Chloride 20 21 1 103 80-120 09/24/2020 2215 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 20 of 50 QC Data for Lot Number: V124026 Inorganic non-metals - MB Sample ID: VQ67959-001 Matrix: Aqueous Batch: 67959 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Nitrate - N 0.020 U 1 0.020 0.0050 mg/L 09/24/2020 2138 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 21 of 50 QC Data for Lot Number: V124026 Inorganic non-metals - LCS Sample ID: VQ67959-002 Matrix: Aqueous Batch: 67959 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Nitrate - N 0.80 0.82 1 102 80-120 09/24/2020 2215 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 22 of 50 QC Data for Lot Number: V124026 Inorganic non-metals - MB Sample ID: VQ68070-001 Matrix: Aqueous Batch:68070 Analytical Method: SM 2540C-2011 Parameter Result Q Dil LOQ DL Units Analysis Date TDS 25 U 1 25 25 mg/L 09/27/20201820 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 23 of 50 QC Data for Lot Number: V124026 Inorganic non-metals - LCS Sample ID: VQ68070-002 Matrix: Aqueous Batch:68070 Analytical Method: SM 2540C-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date TDS 1500 1500 1 101 90-110 09/27/20201820 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 24 of 50 QC Data for Lot Number: V124026 Inorganic non-metals - LCS Sample ID: VQ68132-002 Matrix: Aqueous Batch: 68132 Analytical Method: SM 2320B-2011 Spike Amount Result % Rec Parameter (mg CaCO3/L) (mg CaCO3/LP Dil % Rec Limit Analysis Date Alkalinity @ pH 4.5 su 100 100 1 103 90-110 09/28/2020 1210 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 25 of 50 QC Data for Lot Number: V124026 Inorganic non-metals - MB Sample ID: VQ68547-001 Matrix: Aqueous Batch: 68547 Analytical Method: SM 531 OC-2011 Parameter Result Q Dil LOQ DL Units Analysis Date TOC 1.0 U 1 1.0 1.0 mg/L 10101120201749 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 26 of 50 QC Data for Lot Number: V124026 Inorganic non-metals - LCS Sample ID: VQ68547-002 Matrix: Aqueous Batch: 68547 Analytical Method: SM 531 OC-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date TOC 20 20 1 100 90-110 10101120201802 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 27 of 50 QC Data for Lot Number: V124026 Inorganic non-metals - MS Sample ID: V124026-001MS Matrix: Aqueous Batch: 68547 Analytical Method: SM 531 OC-2011 Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date TOC 0.0 50 49 1 98 70-130 10101120201855 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 28 of 50 QC Data for Lot Number: V124026 Inorganic non-metals - MSD Sample ID: V124026-001MD Matrix: Aqueous Batch: 68547 Analytical Method: SM 531 OC-2011 Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date TOC 0.0 50 48 1 96 2.3 70-130 20 10101120201908 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 29 of 50 QC Data for Lot Number: V124026 Inorganic non-metals - MB Sample ID: VQ68625-001 Matrix: Aqueous Batch: 68625 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Sulfate 1.0 U 1 1.0 0.20 mg/L 10101120201830 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 30 of 50 QC Data for Lot Number: V124026 Inorganic non-metals - LCS Sample ID: VQ68625-002 Matrix: Aqueous Batch: 68625 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 20 18 1 90 80-120 10101120201908 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 31 of 50 QC Data for Lot Number: V124026 Inorganic non-metals - MB Sample ID: VQ68633-001 Matrix: Aqueous Batch:68633 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Chloride 1.0 U 1 1.0 0.20 mg/L 10101120201830 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 32 of 50 QC Data for Lot Number: V124026 Inorganic non-metals - LCS Sample ID: VQ68633-002 Matrix: Aqueous Batch:68633 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Chloride 20 19 1 96 80-120 10101120201908 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 33 of 50 QC Data for Lot Number: V124026 Inorganic non-metals - MB Sample ID: VQ68746-001 Matrix: Aqueous Batch:68746 Analytical Method: SM 5220D-2011 Parameter Result Q Dil LOQ DL Units Analysis Date COD 20 U 1 20 20 mg/L 10/03/2020 2051 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 34 of 50 QC Data for Lot Number: V124026 Inorganic non-metals - LCS Sample ID: VQ68746-002 Matrix: Aqueous Batch:68746 Analytical Method: SM 5220D-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date COD 40 40 1 101 95-105 10/03/2020 2052 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 35 of 50 QC Data for Lot Number: V124026 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ68113-001 Matrix: Aqueous Batch: 68113 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone 10 U 1 10 4.0 ug/L 09/28/2020 1235 Acrylonitrile 5.0 U 1 5.0 0.80 ug/L 09/28/2020 1235 Benzene 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 Bromochloromethane 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 Bromodichloromethane 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 Bromoform 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 Bromomethane (Methyl bromide) 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 2-Butanone (MEK) 10 U 1 10 2.0 ug/L 09/28/2020 1235 Carbon disulfide 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 Carbon tetrachloride 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 Chlorobenzene 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 Chloroethane 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 Chloroform 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 Chloromethane (Methyl chloride) 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 1,2-Dibromo-3-chloropropane (DBCP) 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 Dibromochloromethane 0.50 u 1 0.50 0.40 ug/L 09/28/2020 1235 1,2-Dibromoethane (EDB) 0.50 u 1 0.50 0.40 ug/L 09/28/2020 1235 Dibromomethane (Methylene bromide) 0.50 u 1 0.50 0.40 ug/L 09/28/2020 1235 trans- 1,4-Dichloro-2-butene 2.0 u 1 2.0 0.40 ug/L 09/28/2020 1235 1,2-Dichlorobenzene 0.50 u 1 0.50 0.40 ug/L 09/28/2020 1235 1,4-Dichlorobenzene 0.50 u 1 0.50 0.40 ug/L 09/28/2020 1235 1,1-Dichloroethane 0.50 u 1 0.50 0.40 ug/L 09/28/2020 1235 1,2-Dichloroethane 0.50 u 1 0.50 0.40 ug/L 09/28/2020 1235 1,1-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 cis- 1,2-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 trans- 1,2-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 1,2-Dichloropropane 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 cis- 1,3-Dichloropropene 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 trans- 1,3-Dichloropropene 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 Ethylbenzene 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 2-Hexanone 10 U 1 10 2.0 ug/L 09/28/2020 1235 Methacrylonitrile 5.0 U 1 5.0 2.0 ug/L 09/28/2020 1235 Methyl iodide (lodomethane) 5.0 U 1 5.0 0.40 ug/L 09/28/2020 1235 4-Methyl-2-pentanone 10 U 1 10 2.0 ug/L 09/28/2020 1235 Methylene chloride 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 Styrene 0.50 U 1 0.50 0.41 ug/L 09/28/2020 1235 1,1,1,2-Tetrachloroethane 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 1,1,2,2-Tetrachloroethane 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 Tetrachloroethene 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 Tetrahydrofuran 5.0 U 1 5.0 1.0 ug/L 09/28/2020 1235 Toluene 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 1,1,1-Trichloroethane 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 1,1,2-Trichloroethane 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 Trichloroethene 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 36 of 50 QC Data for Lot Number: V124026 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ68113-001 Matrix: Aqueous Batch: 68113 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Trichlorofluoromethane 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 1,2,3-Trichloropropane 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 Vinyl acetate 5.0 U 1 5.0 1.2 ug/L 09/28/2020 1235 Vinyl chloride 0.50 U 1 0.50 0.40 ug/L 09/28/2020 1235 Xylenes (total) 1.0 U 1 1.0 0.40 ug/L 09/28/2020 1235 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 109 70-130 Toluene-d8 95 70-130 LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: V124026 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 37 of 50 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ68113-002 Matrix: Aqueous Batch: 68113 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 90 1 90 60-140 09/28/2020 1014 Acrylonitrile 100 97 1 97 70-130 09/28/2020 1014 Benzene 50 50 1 99 70-130 09/28/2020 1014 Bromochloromethane 50 52 1 103 70-130 09/28/2020 1014 Bromodichloromethane 50 49 1 98 70-130 09/28/2020 1014 Bromoform 50 49 1 98 70-130 09/28/2020 1014 Bromomethane (Methyl bromide) 50 47 1 94 70-130 09/28/2020 1014 2-Butanone (MEK) 100 93 1 93 70-130 09/28/2020 1014 Carbon disulfide 50 51 1 102 70-130 09/28/2020 1014 Carbon tetrachloride 50 46 1 92 70-130 09/28/2020 1014 Chlorobenzene 50 50 1 100 70-130 09/28/2020 1014 Chloroethane 50 48 1 96 70-130 09/28/2020 1014 Chloroform 50 47 1 94 70-130 09/28/2020 1014 Chloromethane (Methyl chloride) 50 46 1 92 60-140 09/28/2020 1014 1,2-Dibromo-3-chloropropane (DBCP) 50 48 1 96 70-130 09/28/2020 1014 Dibromochloromethane 50 49 1 98 70-130 09/28/2020 1014 1,2-Dibromoethane (EDB) 50 50 1 99 70-130 09/28/2020 1014 Dibromomethane (Methylene bromide) 50 46 1 92 70-130 09/28/2020 1014 trans- 1,4-Dichloro-2-butene 50 49 1 97 70-130 09/28/2020 1014 1,2-Dichlorobenzene 50 49 1 98 70-130 09/28/2020 1014 1,4-Dichlorobenzene 50 51 1 102 70-130 09/28/2020 1014 1,1-Dichloroethane 50 49 1 97 70-130 09/28/2020 1014 1,2-Dichloroethane 50 47 1 93 70-130 09/28/2020 1014 1,1-Dichloroethene 50 50 1 99 70-130 09/28/2020 1014 cis- 1,2-Dichloroethene 50 50 1 100 70-130 09/28/2020 1014 trans- 1,2-Dichloroethene 50 49 1 98 70-130 09/28/2020 1014 1,2-Dichloropropane 50 48 1 96 70-130 09/28/2020 1014 cis- 1,3-Dichloropropene 50 49 1 98 70-130 09/28/2020 1014 trans- 1,3-Dichloropropene 50 50 1 101 70-130 09/28/2020 1014 Ethylbenzene 50 50 1 100 70-130 09/28/2020 1014 2-Hexanone 100 83 1 83 70-130 09/28/2020 1014 Methacrylonitrile 250 240 1 96 70-130 09/28/2020 1014 Methyl iodide (lodomethane) 50 49 1 98 70-130 09/28/2020 1014 4-Methyl-2-pentanone 100 87 1 87 70-130 09/28/2020 1014 Methylene chloride 50 48 1 95 70-130 09/28/2020 1014 Styrene 50 50 1 100 70-130 09/28/2020 1014 1,1,1,2-Tetrachloroethane 50 46 1 93 70-130 09/28/2020 1014 1,1,2,2-Tetrachloroethane 50 48 1 95 70-130 09/28/2020 1014 Tetrachloroethene 50 49 1 99 70-130 09/28/2020 1014 Tetrahydrofuran 50 45 1 90 70-130 09/28/2020 1014 Toluene 50 52 1 104 70-130 09/28/2020 1014 1,1,1-Trichloroethane 50 51 1 102 70-130 09/28/2020 1014 1,1,2-Trichloroethane 50 48 1 96 70-130 09/28/2020 1014 Trichloroethene 50 51 1 102 70-130 09/28/2020 1014 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 38 of 50 QC Data for Lot Number: V124026 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ68113-002 Matrix: Aqueous Batch: 68113 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Trichlorofluoromethane 50 46 1 92 70-130 09/28/2020 1014 1,2,3-Trichloropropane 50 46 1 91 70-130 09/28/2020 1014 Vinyl acetate 50 52 1 105 60-140 09/28/2020 1014 Vinyl chloride 50 46 1 93 70-130 09/28/2020 1014 Xylenes (total) 100 100 1 101 70-130 09/28/2020 1014 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 99 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 99 70-130 LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: V124026 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 39 of 50 Dissolved Gases - MB Sample ID: VQ68503-001 Matrix: Aqueous Batch: 68503 Analytical Method: RSK - 175 Parameter Result Q Dil LOQ DL Units Analysis Date Ethane 10 U 1 10 2.5 ug/L 10/01/20201112 Ethene 10 U 1 10 2.5 ug/L 10/01/20201112 Methane 10 U 1 10 2.5 ug/L 10/01/20201112 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 40 of 50 QC Data for Lot Number: V124026 Dissolved Gases - LCS Sample ID: VQ68503-002 Matrix: Aqueous Batch: 68503 Analytical Method: RSK - 175 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Ethane 550 630 1 114 70-130 10/01/20201022 Ethene 520 570 1 ill 70-130 10/01/2020 1022 Methane 300 330 1 113 70-130 10/01/20201022 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 41 of 50 QC Data for Lot Number: V124026 ICP-MS Metals - MB Sample ID: VQ68279-001 Matrix: Aqueous Batch: 68279 Prep Method: 3005A Analytical Method: 6020B Prep Date: 10/03/2020 1555 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony 2.0 U 1 2.0 0.50 ug/L 10/06/2020 0118 Arsenic 2.0 U 1 2.0 1.3 ug/L 10/06/2020 0118 Barium 5.0 U 1 5.0 1.3 ug/L 10/06/2020 0118 Beryllium 0.40 U 1 0.40 0.15 ug/L 10/06/2020 0118 Cadmium 0.50 U 1 0.50 0.13 ug/L 10/06/2020 0118 Chromium 5.0 U 1 5.0 1.3 ug/L 10/06/2020 0118 Cobalt 5.0 U 1 5.0 1.3 ug/L 10/06/2020 0118 Copper 5.0 U 1 5.0 1.3 ug/L 10/06/2020 0118 Iron 50 U 1 50 13 ug/L 10/06/2020 0118 Lead 1.0 U 1 1.0 0.25 ug/L 10/06/2020 0118 Manganese 5.0 U 1 5.0 1.3 ug/L 10/06/2020 0118 Nickel 5.0 U 1 5.0 1.3 ug/L 10/06/2020 0118 Selenium 5.0 U 1 5.0 1.3 ug/L 10/06/2020 0118 Silver 1.0 U 1 1.0 0.25 ug/L 10/06/2020 0118 Thallium 0.50 U 1 0.50 0.15 ug/L 10/06/2020 0118 Vanadium 5.0 U 1 5.0 2.5 ug/L 10/06/2020 0118 Zinc 10 U 1 10 2.5 ug/L 10/06/2020 0118 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 42 of 50 QC Data for Lot Number: V124026 ICP-MS Metals - LCS Sample ID: VQ68279-002 Matrix: Aqueous Batch: 68279 Prep Method: 3005A Analytical Method: 6020B Prep Date: 10/03/2020 1555 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 93 1 93 80-120 10/06/2020 0125 Arsenic 100 98 1 98 80-120 10/06/2020 0125 Barium 100 95 1 95 80-120 10/06/2020 0125 Beryllium 100 90 1 90 80-120 10/06/2020 0125 Cadmium 100 95 1 95 80-120 10/06/2020 0125 Chromium 100 98 1 98 80-120 10/06/2020 0125 Cobalt 100 110 1 107 80-120 10/06/2020 0125 Copper 100 110 1 109 80-120 10/06/2020 0125 Iron 1000 960 1 96 80-120 10/06/2020 0125 Lead 100 97 1 97 80-120 10/06/2020 0125 Manganese 100 100 1 100 80-120 10/06/2020 0125 Nickel 100 110 1 108 80-120 10/06/2020 0125 Selenium 100 85 1 85 80-120 10/06/2020 0125 Silver 100 100 1 103 80-120 10/06/2020 0125 Thallium 100 96 1 96 80-120 10/06/2020 0125 Vanadium 100 94 1 94 80-120 10/06/2020 0125 Zinc 100 92 1 92 80-120 10/06/2020 0125 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 43 of 50 QC Data for Lot Number: V124026 CVAA -MB Sample ID: VQ67859-001 Matrix: Aqueous Batch: 67859 Prep Method: Analytical Method: 7470A Prep Date: 09/25/2020 1000 Parameter Result Q Dil LOQ DL Units Analysis Date Mercury 0.00020 U 1 0.00020 0.000091 mg/L 09/25/20201504 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 44 of 50 QC Data for Lot Number: V124026 CVAA - LCS Sample ID: VQ67859-002 Matrix: Aqueous Batch: 67859 Prep Method: Analytical Method: 7470A Prep Date: 09/25/2020 1000 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Mercury 0.0020 0.0018 1 92 80-120 09/25/20201506 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 45 of 50 QC Data for Lot Number: V124026 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 46 of 50 PACE ANALYTICAL SERVICES. LLC Cq ctp _I J I' ra !-I ' "p' .l LV '++r' FN � 47c o ki Sidi � T } � o e Viz{ W C - a 1 !! } J L7 fL � CL { O $ r l"' I aow fG6�' z I -3 4 o i QOL}164+ ti I� vn I ,-;-I V 1-1 1 ', r I - 1� u— ii �.7— 4 11 i'J U 4 U [y 3 � Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 47 of 50 PACE ANALYTICAL SERVICES, LLC v } rw� t;eati 1 I c I kJ J S 5j y f CL ulF�a+c�'xJ . Sltt. �"7 r� 'z �2 Q11 Cb Mil -CD VN CA I TM v 4Y iJ~ 5 rt 15 rd F 41 e y . D <1IK L Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 48 of 50 PACE ANALYTICAL SERVICES. LLC t i mi�— V4 � � C'i x ❑ J J L w W air F x W U (n J � r Q Z ii LLI 43J T 5 <J i rilZfw 4 , rL'"' ''C� ),,1 - S3rri� a' . u0rSC7p Uw ia:nu 15 � �cxar U:wr4 ,-*1 ,ryLr aSmCuvy � u � CI iJ } L _ F 4 29 m t'k Q- U I I L p LJV i y Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 49 of 50 PACE ANALYTICAL SERVICES, LLC Sbpmly Prvircmrrn[il Seninm, Iro. Pap 1 M". 1;cgwmcnt n urn": MUP 1 Br_-1 a 1:1fidiv a VOW. it -F3U 16 ,Sample Rixeipf Cbecklist (SRC 6;,k1-V3q1 i �,�'v+�� C1LenL' C.DM';MFFH {'.aialur In _eck hyititi#E: -511 f 09 �r2 27 �[Mr!':2- M `tsofremlpt. Vj SLSI ❑ Climl [� UPS �❑ FQiW ❑ Cdicr: ❑ Yes ® N n 1, }4'cre custody seals Prue t on the cnnGet? Yes Nol 0 NA 12. If ciudndv srxa:s were Lp .nr, wera tl_e y intact and uiibrolceri? PM $trip JD; Nd !LodneStrip JD; NA- 'ICrXl.EJhy:NA Original tempetaturr ulJL]=L rra;cipi 1 Dmivr:J (Convcut Lcmperature upon+eceipt "'❑solid M 1* Cud I ; NA ----- 4.5 ,'4,5 cC 4.2 f4.� 11C 3.5 11_5 cL 5.1 D/,cthod: Z1-cmpc-ahue B.lamk AR3inst Battl" TP IMOthod of coolant; 0 WeL Tee ❑ Im Packs © ; 5.1 °C .�` Gun ID_ _5 IR Gun CeiTecrtion Factor^ 0 °C D lee n NonP Yes l El Nu ONq 3. IC I rmpvratlara G env COK l PNI w.&5 No#itled by; pli —J :eT exceeded EAT' WOS ProjeaG ManagvT N of il3cd? r einail r t to fdCe CirCl un4 , 'e€ ❑N,7 ONA4_ is the cornm=ial"mirie ,ip;Lcxin�.slilyatmhedtothis form? 0 Yes ❑ idyl S. Were rm ner custody prof- vdures (relinquishcd'reccivcd) faltnw�!d? Ycs No 6. WGLM sample Its 1is;ed o� the COC? -- Yerl ❑Nt, 7_ Wels��rlxleTD;ld t:ilsa3rtp:eoontainers" Yet 0 No 8_ Was col levbm datt* ti ie listed on the COC? c listed cai all sample containen? ales ❑ hie 9_ Wa3 COIIeclivn date.$ fl ❑ Yes Tlo 10. Did all cimtniner lebcl' formation (ID, date, time) Pgma with thy, COC? 0 Yes ❑ ML5 11. Were msrs to be perfatlm d listed on the COC? ® 't'os F1-N 12. DW all sair_ples arrive 1e (unhmken, tier, ion, Mtn.)? 11"i. i'�%adequare sample v+tneavralabit,? the proper containers for each D5t arlr:/ci' i1L gOOLL cnndiliOr, ® Ya.r Ci No Yes No 14, ►3fcrc all samples received w4hin 'fir tlw hol€lin tine cr 48 IYow , whi::Itevtr umus first? Yes ® N41 15, Wore any sample's conl3 LLeL1lui�siiLWrx=ss(circle one) sainpler Not IWO 4i1 COC? Yes ❑ Nu 21 NA IG_ For YQA [u1d RSK-I 15 in. iny of Lhe VOA vipls? riples, were hubbies present >1pca-sip" ('14"or 6mff in diamatcr) Yes 17 Nu NA 17_ Wery all 1K: 0imctalSlnt rient samples rO rivW tit ft PH of <2: ❑ lies El No NA 18. Word all c abide sam 1 i Lecrivwj IL a pH > 12 a:i sulfide samplers rep eiaaxl at � PH> g? . Yes Ci hlo ®i�lA 0 KAfG_ T9, Were all app tou c 1�Fli, c � lcnine" fK[*'JcyanideipiienL if{?S (<O.Sm ) S]lti�Y es Ltr ul rnxiduail ❑ Yu ❑ No Were client rL-marksfrotl [COIA: ctly imr Wribrd froin t st& (i.e- requftii: d dilutions, M 'MSL) de; gLral=errs, LAU...) c0c into tht- comment section bi I..1 h1S? Yes Np 71 _ Was thn quDte rumlier :i lxj on the corltaincr label l If yes: Quote # NA S2mplo Preservb4ion (Musk bo completed for any sa ple(S) incortcdy prescr VUd ur wAll hrijC1.TaC^) Simple(s) NA in saMPI0 roodiving with NA iid, otcircic one: 112 Time 4f prWeT at 035 NA 1 f mtLr#' than one p w-Pz rcce:ved incnrrertly preserved and welt adju%Wd nL!cuF l:rg:y 4, iJND3, 14C1, NaOH using SR # NA Servod-m is nodded, please note it the cgrnmcnts below, 5arrlple{s) NA -- w4ro reseiv ed with laul�trl rx r-%0 rr m in c;iameter_ Samples(s) .NA _ _ were received with TR C; > CI.5 mg,'L (If fl t 9 is true) w id wore !adjusted accnrrlinCly in ssln•1plo mcpNing widi sodiu:11 l LinwLdfa#e (i ataS3 s) whit Shealy ID: NA 'SR baroode labels o;aplicd by: JSI I Date, 09,�2C+2020 Conunent�.AMWSANIPLF51.,4BCL.GD.4;Slhf%1ltON a3N1'TATNERS_ Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 50 of 50 aceAnalytical Report of Analysis CDM Smith 5400 Glenwood Avenue Suite 400 Raleigh, NC 27612 Attention: Mathew Colone Project Name: Cabarrus Co.LF Unit 1 Lot Number:V126014 Date Completed:10/19/2020 10/21/2020 10:58 PM Approved and released by: Project Manager 11: Cathy S. Dover =w�4 aecRFo���A4W- TNI / AM Amflvue Acm^rmm Fvu rj (' 4eOfFAi� ACC R E OI TEO TESTINGL aORlTOAY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 52 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative CDM Smith Lot Number: V126014 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. The matrix spike (MS) associated with batch VQ69184 was run outside of the 12-hour tune window by 21 minutes. As such, the MS and sample data have been reported. If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 2 of 52 PACE ANALYTICAL SERVICES, LLC Sample Summary CDM Smith Lot Number: V126014 Project Name: Cabarrus Co.LF Unit 1 Project Number: Sample Number Sample ID Matrix Date Sampled Date Received 001 MW-7 Aqueous 09/24/20201715 09/26/2020 002 MW-8A Aqueous 09/24/20201800 09/26/2020 003 MW-5 Aqueous 09/25/20201030 09/26/2020 004 MW-10 Aqueous 09/24/20201500 09/26/2020 005 MW-11 Aqueous 09/24/20201635 09/26/2020 006 DUP-1 Aqueous 09/24/2020 0801 09/26/2020 007 EQ BLANK Aqueous 09/25/2020 1450 09/26/2020 008 TRIP BLANK Aqueous 09/24/2020 09/26/2020 (8 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 52 PACE ANALYTICAL SERVICES, LLC Detection Summary CDM Smith Lot Number: V126014 Project Name: Cabarrus Co.LF Unit 1 Project Number: Sample Sample ID Matrix Parameter Method Result Q Units Page 001 MW-7 Aqueous Benzene 8260D 1.2 ug/L 6 001 MW-7 Aqueous Chlorobenzene 8260D 26 ug/L 6 001 MW-7 Aqueous 1,2-Dichlorobenzene 8260D 0.68 ug/L 6 001 MW-7 Aqueous 1,4-Dichlorobenzene 8260D 10 ug/L 6 001 MW-7 Aqueous 1,4-Dioxane 8260D (SIM) 93 ug/L 8 001 MW-7 Aqueous Arsenic 6020B 2.8 ug/L 9 001 MW-7 Aqueous Barium 6020B 610 ug/L 9 001 MW-7 Aqueous Cobalt 6020B 27 ug/L 9 001 MW-7 Aqueous Nickel 6020B 77 ug/L 9 001 MW-7 Aqueous Selenium 6020B 64 ug/L 9 001 MW-7 Aqueous Vanadium 6020B 2.6 J ug/L 9 002 MW-8A Aqueous Antimony 6020B 0.76 J ug/L 13 002 MW-8A Aqueous Arsenic 6020B 1.5 J ug/L 13 002 MW-8A Aqueous Barium 6020B 120 ug/L 13 002 MW-8A Aqueous Cadmium 6020B 0.31 J ug/L 13 002 MW-8A Aqueous Cobalt 6020B 16 ug/L 13 002 MW-8A Aqueous Copper 6020B 13 ug/L 13 002 MW-8A Aqueous Lead 6020B 1.7 ug/L 13 002 MW-8A Aqueous Nickel 6020B 90 ug/L 13 002 MW-8A Aqueous Vanadium 6020B 2.6 J ug/L 13 002 MW-8A Aqueous Zinc 6020B 15 ug/L 13 003 MW-5 Aqueous Chlorobenzene 8260D 0.79 ug/L 14 003 MW-5 Aqueous 1,4-Dichlorobenzene 8260D 0.44 J ug/L 14 003 MW-5 Aqueous 1,4-Dioxane 8260D (SIM) 15 ug/L 16 003 MW-5 Aqueous Antimony 6020B 0.92 J ug/L 17 003 MW-5 Aqueous Arsenic 6020B 2.0 ug/L 17 003 MW-5 Aqueous Barium 6020B 55 ug/L 17 003 MW-5 Aqueous Beryllium 6020B 0.53 ug/L 17 003 MW-5 Aqueous Chromium 6020B 5.0 ug/L 17 003 MW-5 Aqueous Cobalt 6020B 3.5 J ug/L 17 003 MW-5 Aqueous Copper 6020B 6.3 ug/L 17 003 MW-5 Aqueous Lead 6020B 2.5 ug/L 17 003 MW-5 Aqueous Nickel 6020B 12 ug/L 17 003 MW-5 Aqueous Selenium 6020B 2.8 J ug/L 17 003 MW-5 Aqueous Vanadium 6020B 12 ug/L 17 003 MW-5 Aqueous Zinc 6020B 20 ug/L 17 004 MW-10 Aqueous Benzene 8260D 1.5 ug/L 18 004 MW-10 Aqueous Chlorobenzene 8260D 40 ug/L 18 004 MW-10 Aqueous 1,2-Dichlorobenzene 8260D 0.86 ug/L 18 004 MW-10 Aqueous 1,4-Dichlorobenzene 8260D 6.9 ug/L 18 004 MW-10 Aqueous 1,4-Dioxane 8260D (SIM) 76 ug/L 20 004 MW-10 Aqueous Arsenic 6020B 27 ug/L 21 004 MW-10 Aqueous Barium 6020B 140 ug/L 21 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 52 Detection Summary (Continued) Lot Number: V126014 Sample Sample ID Matrix Parameter Method Result Q Units Page 004 MW-10 Aqueous Beryllium 6020B 0.35 J ug/L 21 004 MW-10 Aqueous Chromium 6020B 1.7 J ug/L 21 004 MW-10 Aqueous Cobalt 6020B 27 ug/L 21 004 MW-10 Aqueous Lead 6020B 0.61 J ug/L 21 004 MW-10 Aqueous Nickel 6020B 130 ug/L 21 004 MW-10 Aqueous Selenium 6020B 4.6 J ug/L 21 004 MW-10 Aqueous Zinc 6020B 2.8 J ug/L 21 005 MW-11 Aqueous Chlorobenzene 8260D 5.2 ug/L 22 005 MW-11 Aqueous 1,4-Dichlorobenzene 8260D 1.7 ug/L 22 005 MW-11 Aqueous 1,4-Dioxane 8260D (SIM) 20 ug/L 24 005 MW-11 Aqueous Barium 6020B 250 ug/L 25 005 MW-11 Aqueous Cobalt 6020B 15 ug/L 25 005 MW-11 Aqueous Lead 6020B 0.26 J ug/L 25 005 MW-11 Aqueous Nickel 6020B 17 ug/L 25 005 MW-11 Aqueous Selenium 6020B 2.9 J ug/L 25 005 MW-11 Aqueous Zinc 6020B 2.6 J ug/L 25 006 DUP-1 Aqueous Benzene 8260D 1.5 ug/L 26 006 DUP-1 Aqueous Chlorobenzene 8260D 40 ug/L 26 006 DUP-1 Aqueous 1,2-Dichlorobenzene 8260D 0.96 ug/L 26 006 DUP-1 Aqueous 1,4-Dichlorobenzene 8260D 7.1 ug/L 26 006 DUP-1 Aqueous 1,4-Dioxane 8260D (SIM) 79 ug/L 28 006 DUP-1 Aqueous Arsenic 6020B 27 ug/L 29 006 DUP-1 Aqueous Barium 6020B 140 ug/L 29 006 DUP-1 Aqueous Beryllium 6020B 0.45 ug/L 29 006 DUP-1 Aqueous Chromium 6020B 1.8 J ug/L 29 006 DUP-1 Aqueous Cobalt 6020B 27 ug/L 29 006 DUP-1 Aqueous Lead 6020B 0.58 J ug/L 29 006 DUP-1 Aqueous Nickel 6020B 130 ug/L 29 006 DUP-1 Aqueous Selenium 6020B 4.8 J ug/L 29 006 DUP-1 Aqueous Zinc 6020B 2.9 J ug/L 29 007 EQ BLANK Aqueous Acetone 8260D 4.0 J ug/L 30 (74 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 52 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI26014-001 Description: MW-7 Matrix: Aqueous Date Sampled:09/24/2020 1715 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/30/20201329 TML 68353 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 1.2 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 26 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.68 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 10 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 52 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI26014-001 Description: MW-7 Matrix: Aqueous Date Sampled:09/24/2020 1715 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/30/20201329 TML 68353 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 94 70-130 97 70-130 93 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 52 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:VI26014-001 Description: MW-7 Matrix: Aqueous Date Sampled:09/24/2020 1715 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/07/2020 2213 DJG 69184 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 93 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 96 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 52 ICP-MS Metals Client:CDM Smith Laboratory ID:VI26014-001 Description: MW-7 Matrix: Aqueous Date Sampled:09/24/2020 1715 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method 1 3005A 2 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 10/02/2020 2038 BPK 6020B 10 10/05/2020 1742 BPK Prep Date Batch 10/01/2020 1546 68305 10/01/2020 1546 68305 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.8 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 610 50 13 ug/L 2 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 27 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.0 U 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 77 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 64 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 2.6 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 10 U 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 52 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI26014-002 Description: MW-8A Matrix: Aqueous Date Sampled:09/24/2020 1800 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/30/20201353 TML 68353 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 52 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI26014-002 Description: MW-8A Matrix: Aqueous Date Sampled:09/24/2020 1800 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/30/20201353 TML 68353 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 89 70-130 92 70-130 92 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 52 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:VI26014-002 Description: MW-8A Matrix: Aqueous Date Sampled:09/24/2020 1800 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/07/2020 2237 DJG 69184 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 100 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 52 ICP-MS Metals Client:CDM Smith Laboratory ID:VI26014-002 Description: MW-8A Matrix: Aqueous Date Sampled:09/24/2020 1800 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 10/02/2020 2045 BPK Prep Date Batch 10/01/2020 1546 68305 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 0.76 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 1.5 J 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 120 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.31 J 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 16 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 13 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.7 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 90 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 2.6 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 15 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 52 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI26014-003 Description: MW-5 Matrix: Aqueous Date Sampled:09/25/2020 1030 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/30/20201417 TML 68353 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.79 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.44 J 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 52 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI26014-003 Description: MW-5 Matrix: Aqueous Date Sampled:09/25/2020 1030 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/30/20201417 TML 68353 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 95 70-130 98 70-130 96 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of 52 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:VI26014-003 Description: MW-5 Matrix: Aqueous Date Sampled:09/25/2020 1030 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/07/2020 2301 DJG 69184 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 15 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 98 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 16 of 52 ICP-MS Metals Client:CDM Smith Laboratory ID:VI26014-003 Description: MW-5 Matrix: Aqueous Date Sampled:09/25/2020 1030 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 10/02/2020 2053 BPK Prep Date Batch 10/01/2020 1546 68305 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 0.92 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.0 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 55 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.53 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 3.5 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 6.3 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 2.5 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 12 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 2.8 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 12 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 20 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 17 of 52 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI26014-004 Description: MW-10 Matrix: Aqueous Date Sampled:09/24/2020 1500 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/30/20201440 TML 68353 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 1.5 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 40 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.86 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 6.9 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 18 of 52 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI26014-004 Description: MW-10 Matrix: Aqueous Date Sampled:09/24/2020 1500 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/30/20201440 TML 68353 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 96 70-130 98 70-130 95 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 19 of 52 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:VI26014-004 Description: MW-10 Matrix: Aqueous Date Sampled:09/24/2020 1500 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/07/2020 2326 DJG 69184 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 76 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 93 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 20 of 52 ICP-MS Metals Client:CDM Smith Laboratory ID:VI26014-004 Description: MW-10 Matrix: Aqueous Date Sampled:09/24/2020 1500 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 10/02/2020 2100 BPK Prep Date Batch 10/01/2020 1546 68305 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 27 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 140 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.35 J 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.7 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 27 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.61 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 130 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 4.6 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 2.8 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 21 of 52 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI26014-005 Description: MW-11 Matrix: Aqueous Date Sampled:09/24/2020 1635 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/30/20201504 TML 68353 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 5.2 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 1.7 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 22 of 52 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI26014-005 Description: MW-11 Matrix: Aqueous Date Sampled:09/24/2020 1635 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/30/20201504 TML 68353 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 97 70-130 98 70-130 95 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 23 of 52 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:VI26014-005 Description: MW-11 Matrix: Aqueous Date Sampled:09/24/2020 1635 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/07/2020 2350 DJG 69184 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 20 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 100 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 24 of 52 ICP-MS Metals Client:CDM Smith Laboratory ID:VI26014-005 Description: MW-11 Matrix: Aqueous Date Sampled:09/24/2020 1635 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 10/02/2020 2215 BPK Prep Date Batch 10/01/2020 1546 68305 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.0 U 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 250 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 15 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.26 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 17 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 2.9 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 2.6 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 25 of 52 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI26014-006 Description: DUP-1 Matrix: Aqueous Date Sampled:09/24/2020 0801 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/30/20201528 TML 68353 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 1.5 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 40 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.96 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 7.1 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 26 of 52 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI26014-006 Description: DUP-1 Matrix: Aqueous Date Sampled:09/24/2020 0801 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/30/20201528 TML 68353 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 95 70-130 98 70-130 95 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 27 of 52 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:VI26014-006 Description: DUP-1 Matrix: Aqueous Date Sampled:09/24/2020 0801 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/08/2020 0014 DJG 69184 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 79 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 87 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 28 of 52 ICP-MS Metals Client:CDM Smith Laboratory ID:VI26014-006 Description: DUP-1 Matrix: Aqueous Date Sampled:09/24/2020 0801 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 10/02/2020 2222 BPK Prep Date Batch 10/01/2020 1546 68305 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 27 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 140 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.45 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.8 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 27 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.58 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 130 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 4.8 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 2.9 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 29 of 52 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI24027-024 Description: SWA Matrix: Aqueous Date Sampled:09/25/2020 1045 Project Name: Cabarrus County LF Unit 2 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/30/20201154 TML 68353 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 106 of 198 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI24027-024 Description: SWA Matrix: Aqueous Date Sampled:09/25/2020 1045 Project Name: Cabarrus County LF Unit 2 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/30/20201154 TML 68353 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 92 70-130 94 70-130 93 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 107 of 198 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:VI24027-024 Description: SW-1 Matrix: Aqueous Date Sampled:09/25/2020 1045 Project Name: Cabarrus County LF Unit 2 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 09/30/2020 2347 DJG 68452 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 1.2 J 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 105 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 108 of 198 ICP-MS Metals Client:CDM Smith Laboratory ID:VI24027-024 Description: SWA Matrix: Aqueous Date Sampled:09/25/2020 1045 Project Name: Cabarrus County LF Unit 2 Date Received:09/26/2020 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 10/01/2020 2308 BPK Prep Date Batch 10/01/2020 0855 68268 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.0 U 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 49 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.24 J 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 4.5 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 1.9 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 7.2 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 2.4 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 4.5 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 8.6 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 13 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 109 of 198 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI24027-025 Description: SW-2 Matrix: Aqueous Date Sampled:09/25/2020 1000 Project Name: Cabarrus County LF Unit 2 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/30/20201218 TML 68353 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 110 of 198 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI24027-025 Description: SW-2 Matrix: Aqueous Date Sampled:09/25/2020 1000 Project Name: Cabarrus County LF Unit 2 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/30/20201218 TML 68353 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 95 70-130 97 70-130 97 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 111 of 198 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:VI24027-025 Description: SW-2 Matrix: Aqueous Date Sampled:09/25/2020 1000 Project Name: Cabarrus County LF Unit 2 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/01/2020 0012 DJG 68452 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 107 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 112 of 198 ICP-MS Metals Client:CDM Smith Laboratory ID:VI24027-025 Description: SW-2 Matrix: Aqueous Date Sampled:09/25/2020 1000 Project Name: Cabarrus County LF Unit 2 Date Received:09/26/2020 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 10/01/2020 2330 BPK Prep Date Batch 10/01/2020 0855 68268 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.7 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 91 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.77 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 25 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 4.8 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 18 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 8.8 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 8.8 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 2.7 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 33 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 34 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 113 of 198 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI26014-007 Description: EQ BLANK Matrix: Aqueous Date Sampled:09/25/2020 1450 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/30/20201020 TML 68353 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 4.0 J 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 30 of 52 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI26014-007 Description: EQ BLANK Matrix: Aqueous Date Sampled:09/25/2020 1450 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/30/20201020 TML 68353 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 89 70-130 91 70-130 90 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 31 of 52 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:VI26014-007 Description: EQ BLANK Matrix: Aqueous Date Sampled:09/25/2020 1450 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/07/2020 2125 DJG 69184 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 97 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 32 of 52 ICP-MS Metals Client:CDM Smith Laboratory ID:VI26014-007 Description: EQ BLANK Matrix: Aqueous Date Sampled:09/25/2020 1450 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 10/02/2020 2137 BPK Prep Date Batch 10/01/2020 1546 68305 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.0 U 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 5.0 U 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 5.0 U 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.0 U 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 5.0 U 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 10 U 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 33 of 52 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI26014-008 Description: TRIP BLANK Matrix: Aqueous Date Sampled:09/24/2020 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/30/20201043 TML 68353 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 34 of 52 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:VI26014-008 Description: TRIP BLANK Matrix: Aqueous Date Sampled:09/24/2020 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 09/30/20201043 TML 68353 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 98 70-130 99 70-130 97 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 35 of 52 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:VI26014-008 Description: TRIP BLANK Matrix: Aqueous Date Sampled:09/24/2020 Project Name: Cabarrus Co.LF Unit 1 Date Received:09/26/2020 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/07/2020 2149 DJG 69184 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 99 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 36 of 52 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: V126014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 37 of 52 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ68353-001 Matrix: Aqueous Batch: 68353 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone 10 U 1 10 4.0 ug/L 09/30/2020 0920 Acrylonitrile 5.0 U 1 5.0 0.80 ug/L 09/30/2020 0920 Benzene 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 Bromochloromethane 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 Bromodichloromethane 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 Bromoform 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 Bromomethane (Methyl bromide) 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 2-Butanone (MEK) 10 U 1 10 2.0 ug/L 09/30/2020 0920 Carbon disulfide 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 Carbon tetrachloride 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 Chlorobenzene 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 Chloroethane 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 Chloroform 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 Chloromethane (Methyl chloride) 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 1,2-Dibromo-3-chloropropane (DBCP) 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 Dibromochloromethane 0.50 u 1 0.50 0.40 ug/L 09/30/2020 0920 1,2-Dibromoethane (EDB) 0.50 u 1 0.50 0.40 ug/L 09/30/2020 0920 Dibromomethane (Methylene bromide) 0.50 u 1 0.50 0.40 ug/L 09/30/2020 0920 trans- 1,4-Dichloro-2-butene 2.0 u 1 2.0 0.40 ug/L 09/30/2020 0920 1,2-Dichlorobenzene 0.50 u 1 0.50 0.40 ug/L 09/30/2020 0920 1,4-Dichlorobenzene 0.50 u 1 0.50 0.40 ug/L 09/30/2020 0920 1,1-Dichloroethane 0.50 u 1 0.50 0.40 ug/L 09/30/2020 0920 1,2-Dichloroethane 0.50 u 1 0.50 0.40 ug/L 09/30/2020 0920 1,1-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 cis- 1,2-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 trans- 1,2-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 1,2-Dichloropropane 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 cis- 1,3-Dichloropropene 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 trans- 1,3-Dichloropropene 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 Ethylbenzene 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 2-Hexanone 10 U 1 10 2.0 ug/L 09/30/2020 0920 Methacrylonitrile 5.0 U 1 5.0 2.0 ug/L 09/30/2020 0920 Methyl iodide (lodomethane) 5.0 U 1 5.0 0.40 ug/L 09/30/2020 0920 4-Methyl-2-pentanone 10 U 1 10 2.0 ug/L 09/30/2020 0920 Methylene chloride 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 Styrene 0.50 U 1 0.50 0.41 ug/L 09/30/2020 0920 1,1,1,2-Tetrachloroethane 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 1,1,2,2-Tetrachloroethane 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 Tetrachloroethene 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 Toluene 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 1,1,1-Trichloroethane 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 1,1,2-Trichloroethane 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 Trichloroethene 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 Trichlorofluoromethane 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 38 of 52 QC Data for Lot Number: V126014 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ68353-001 Matrix: Aqueous Batch: 68353 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date 1,2,3-Trichloropropane 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 Vinyl acetate 5.0 U 1 5.0 1.2 ug/L 09/30/2020 0920 Vinyl chloride 0.50 U 1 0.50 0.40 ug/L 09/30/2020 0920 Xylenes (total) 1.0 U 1 1.0 0.40 ug/L 09/30/2020 0920 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 100 70-130 Toluene-d8 97 70-130 LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: V126014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 39 of 52 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ68353-002 Matrix: Aqueous Batch: 68353 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 91 1 91 60-140 09/30/2020 0816 Acrylonitrile 100 120 1 117 70-130 09/30/2020 0816 Benzene 50 53 1 106 70-130 09/30/2020 0816 Bromochloromethane 50 51 1 103 70-130 09/30/2020 0816 Bromodichloromethane 50 52 1 105 70-130 09/30/2020 0816 Bromoform 50 48 1 96 70-130 09/30/2020 0816 Bromomethane (Methyl bromide) 50 48 1 97 70-130 09/30/2020 0816 2-Butanone (MEK) 100 120 1 116 70-130 09/30/2020 0816 Carbon disulfide 50 53 1 107 70-130 09/30/2020 0816 Carbon tetrachloride 50 53 1 106 70-130 09/30/2020 0816 Chlorobenzene 50 51 1 102 70-130 09/30/2020 0816 Chloroethane 50 58 1 117 70-130 09/30/2020 0816 Chloroform 50 55 1 110 70-130 09/30/2020 0816 Chloromethane (Methyl chloride) 50 54 1 109 60-140 09/30/2020 0816 1,2-Dibromo-3-chloropropane (DBCP) 50 45 1 91 70-130 09/30/2020 0816 Dibromochloromethane 50 49 1 98 70-130 09/30/2020 0816 1,2-Dibromoethane (EDB) 50 51 1 102 70-130 09/30/2020 0816 Dibromomethane (Methylene bromide) 50 51 1 102 70-130 09/30/2020 0816 trans- 1,4-Dichloro-2-butene 50 51 1 103 70-130 09/30/2020 0816 1,2-Dichlorobenzene 50 49 1 99 70-130 09/30/2020 0816 1,4-Dichlorobenzene 50 49 1 99 70-130 09/30/2020 0816 1,1-Dichloroethane 50 58 1 115 70-130 09/30/2020 0816 1,2-Dichloroethane 50 51 1 102 70-130 09/30/2020 0816 1,1-Dichloroethene 50 55 1 110 70-130 09/30/2020 0816 cis- 1,2-Dichloroethene 50 55 1 109 70-130 09/30/2020 0816 trans- 1,2-Dichloroethene 50 56 1 112 70-130 09/30/2020 0816 1,2-Dichloropropane 50 55 1 109 70-130 09/30/2020 0816 cis- 1,3-Dichloropropene 50 53 1 107 70-130 09/30/2020 0816 trans- 1,3-Dichloropropene 50 50 1 100 70-130 09/30/2020 0816 Ethylbenzene 50 53 1 105 70-130 09/30/2020 0816 2-Hexanone 100 110 1 113 70-130 09/30/2020 0816 Methacrylonitrile 250 290 1 115 70-130 09/30/2020 0816 Methyl iodide (lodomethane) 50 50 1 101 70-130 09/30/2020 0816 4-Methyl-2-pentanone 100 110 1 109 70-130 09/30/2020 0816 Methylene chloride 50 52 1 105 70-130 09/30/2020 0816 Styrene 50 53 1 106 70-130 09/30/2020 0816 1,1,1,2-Tetrachloroethane 50 51 1 103 70-130 09/30/2020 0816 1,1,2,2-Tetrachloroethane 50 52 1 104 70-130 09/30/2020 0816 Tetrachloroethene 50 49 1 98 70-130 09/30/2020 0816 Toluene 50 52 1 103 70-130 09/30/2020 0816 1,1,1-Trichloroethane 50 54 1 107 70-130 09/30/2020 0816 1,1,2-Trichloroethane 50 51 1 102 70-130 09/30/2020 0816 Trichloroethene 50 49 1 99 70-130 09/30/2020 0816 Trichlorofluoromethane 50 52 1 104 70-130 09/30/2020 0816 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 40 of 52 QC Data for Lot Number: V126014 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ68353-002 Matrix: Aqueous Batch: 68353 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,2,3-Trichloropropane 50 50 1 101 70-130 09/30/2020 0816 Vinyl acetate 50 60 1 119 60-140 09/30/2020 0816 Vinyl chloride 50 65 1 129 70-130 09/30/2020 0816 Xylenes (total) 100 100 1 104 70-130 09/30/2020 0816 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 94 70-130 LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: V126014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 41 of 52 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: VQ69184-001 Matrix: Aqueous Batch: 69184 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane 3.0 U 1 3.0 1.0 ug/L 10107120201934 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 96 40-170 U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 42 of 52 QC Data for Lot Number: V126014 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: VQ69184-002 Matrix: Aqueous Batch: 69184 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 48 1 97 70-130 10107120201846 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 97 40-170 U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 43 of 52 QC Data for Lot Number: V126014 Volatile Organic Compounds by GC/MS (SIM) - MS Sample ID: V126014-002MS Matrix: Aqueous Batch: 69184 Prep Method: 5030E Analytical Method: 8260D (SIM) Sample Spike Amount Amount Result % Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 0.0 50 42 1 84 70-130 10/08/2020 0305 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 107 40-170 U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 44 of 52 QC Data for Lot Number: V126014 Volatile Organic Compounds by GC/MS (SIM) - Duplicate Sample ID: V126014-003DU Matrix: Aqueous Batch: 69184 Prep Method: 5030E Analytical Method: 8260D (SIM) Sample Amount Result % RPD Parameter (ug/L) (ug/L) Q Dil % RPD Limit Analysis Date 1,4-Dioxane 15 11 + 1 34 20 10/08/2020 0240 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 104 40-170 U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 45 of 52 QC Data for Lot Number: V126014 ICP-MS Metals - MB Sample ID: VQ68305-001 Matrix: Aqueous Batch: 68305 Prep Method: 3005A Analytical Method: 6020B Prep Date: 10/01/2020 1546 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony 2.0 U 1 2.0 0.50 ug/L 10/02/2020 2000 Arsenic 2.0 U 1 2.0 1.3 ug/L 10/02/2020 2000 Barium 5.0 U 1 5.0 1.3 ug/L 10/02/2020 2000 Beryllium 0.40 U 1 0.40 0.15 ug/L 10/02/2020 2000 Cadmium 0.50 U 1 0.50 0.13 ug/L 10/02/2020 2000 Chromium 5.0 U 1 5.0 1.3 ug/L 10/02/2020 2000 Cobalt 5.0 U 1 5.0 1.3 ug/L 10/02/2020 2000 Copper 5.0 U 1 5.0 1.3 ug/L 10/02/2020 2000 Lead 1.0 U 1 1.0 0.25 ug/L 10/02/2020 2000 Nickel 5.0 U 1 5.0 1.3 ug/L 10/02/2020 2000 Selenium 5.0 U 1 5.0 1.3 ug/L 10/02/2020 2000 Silver 1.0 U 1 1.0 0.25 ug/L 10/02/2020 2000 Thallium 0.50 U 1 0.50 0.15 ug/L 10/02/2020 2000 Vanadium 5.0 U 1 5.0 2.5 ug/L 10/02/2020 2000 Zinc 10 U 1 10 2.5 ug/L 10/02/2020 2000 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 46 of 52 QC Data for Lot Number: V126014 ICP-MS Metals - LCS Sample ID: VQ68305-002 Matrix: Aqueous Batch: 68305 Prep Method: 3005A Analytical Method: 6020B Prep Date: 10/01/2020 1546 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 94 1 94 80-120 10/02/2020 2008 Arsenic 100 98 1 98 80-120 10/02/2020 2008 Barium 100 99 1 99 80-120 10/02/2020 2008 Beryllium 100 94 1 94 80-120 10/02/2020 2008 Cadmium 100 96 1 96 80-120 10/02/2020 2008 Chromium 100 100 1 101 80-120 10/02/2020 2008 Cobalt 100 110 1 106 80-120 10/02/2020 2008 Copper 100 110 1 109 80-120 10/02/2020 2008 Lead 100 100 1 101 80-120 10/02/2020 2008 Nickel 100 110 1 107 80-120 10/02/2020 2008 Selenium 100 91 1 91 80-120 10/02/2020 2008 Silver 100 100 1 103 80-120 10/02/2020 2008 Thallium 100 99 1 99 80-120 10/02/2020 2008 Vanadium 100 96 1 96 80-120 10/02/2020 2008 Zinc 100 88 1 88 80-120 10/02/2020 2008 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 47 of 52 QC Data for Lot Number: V126014 ICP-MS Metals - MS Sample ID: V126014-004MS Matrix: Aqueous Batch: 68305 Prep Method: 3005A Analytical Method: 6020B Prep Date: 10/01/2020 1546 Sample Spike Amount Amount Result % Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 0.0 100 97 1 97 70-130 10/02/2020 2145 Arsenic 27 100 130 1 100 70-130 10/02/2020 2145 Barium 140 100 250 1 106 70-130 10/02/2020 2145 Beryllium 0.35 100 96 1 95 70-130 10/02/2020 2145 Cadmium 0.0 100 92 1 92 70-130 10/02/2020 2145 Chromium 1.7 100 89 1 88 70-130 10/02/2020 2145 Cobalt 27 100 130 1 107 70-130 10/02/2020 2145 Copper 0.0 100 97 1 97 70-130 10/02/2020 2145 Lead 0.61 100 110 1 109 70-130 10/02/2020 2145 Nickel 130 100 240 1 105 70-130 10/02/2020 2145 Selenium 4.6 100 94 1 89 70-130 10/02/2020 2145 Silver 0.0 100 94 1 94 70-130 10/02/2020 2145 Thallium 0.0 100 110 1 108 70-130 10/02/2020 2145 Vanadium 0.0 100 92 1 92 70-130 10/02/2020 2145 Zinc 2.8 100 93 1 90 70-130 10/02/2020 2145 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 48 of 52 QC Data for Lot Number: V126014 ICP-MS Metals - MSD Sample ID: V126014-004MD Matrix: Aqueous Batch: 68305 Prep Method: 3005A Analytical Method: 6020B Prep Date: 10/01/2020 1546 Sample Spike Amount Amount Result % Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Antimony 0.0 100 97 1 97 0.41 70-130 20 10/02/2020 2152 Arsenic 27 100 130 1 98 1.4 70-130 20 10/02/2020 2152 Barium 140 100 250 1 102 1.8 70-130 20 10/02/2020 2152 Beryllium 0.35 100 95 1 95 0.71 70-130 20 10/02/2020 2152 Cadmium 0.0 100 90 1 90 1.7 70-130 20 10/02/2020 2152 Chromium 1.7 100 89 1 87 0.89 70-130 20 10/02/2020 2152 Cobalt 27 100 130 1 104 2.2 70-130 20 10/02/2020 2152 Copper 0.0 100 94 1 94 2.6 70-130 20 10/02/2020 2152 Lead 0.61 100 110 1 108 1.6 70-130 20 10/02/2020 2152 Nickel 130 100 230 1 99 2.6 70-130 20 10/02/2020 2152 Selenium 4.6 100 92 1 88 1.6 70-130 20 10/02/2020 2152 Silver 0.0 100 93 1 93 1.4 70-130 20 10/02/2020 2152 Thallium 0.0 100 110 1 107 0.98 70-130 20 10/02/2020 2152 Vanadium 0.0 100 91 1 91 0.43 70-130 20 10/02/2020 2152 Zinc 2.8 100 93 1 90 0.016 70-130 20 10/02/2020 2152 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 49 of 52 QC Data for Lot Number: V126014 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 50 of 52 PACE ANALYTICAL SERVICES, LLC JLJ� l u E w Q UL �; I ff I w 0 i I i I i I I I � I I �I LL 4' - nry a Itr '4 I ri yy ,fit ll } - 4 ILL z I Q r7 1 r1 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 51 of 52 PACE ANALYTICAL SERVICES, LLC skk- lY [nia:rcxaner�x] Sm ice y :rc Uuaumeul Number. 41 f:;1418{'-'9 p ri'. I of I Sample Receipt C-'hccklist (SRQ yr sop Chen?; llsjatlt nrre eiiO1_ ❑ SFST C11cat UPS EaFecEx ❑ 01.11er' 4M Yee ❑ NO I _ Werr GlMtody W.a]S pL-OSGLit Oil th4, COO]e? 1'esI []NOI DNA2. Ifeusmd ' seals were 1present. wNetc Lhry intact MCI rml)l'okcn', H Strip 1D; X41 _{'hl(irinc SLrip TD: fi/AL- 'bested bY! rigi„a1 temperature upon receipt;' Ded ved (CQ1.1'b L.c+1') Lerrlperawry upun nsccipt Snap -Cup ID: 33 ` 33 ,c 1a? / .)!I "C' "fl "ram=f' Metho&- R' `felTiperulurr Tilank ❑Against BottJcs Ilk L;un ID: I TR Gun Ciin-(xtirli Factor; McIII MI Df L:(Rilasn1: T WU I(T ❑ Ice Packs ❑ Dry lr* [a Nunn tf3r kw-84 IV, I R o — ❑ Yes ❑ ]n I?tNA I. iF t=1wratum of mrf cooler exaseeded fi. OlC, wuo-. F vi uc l Munagu N otiticd'� PA7 wus TNodficx] by. phone: omail ? face•to-tact~ (Circle r3no). T-Yes El No ❑NA 4. 1s the commcroia. courier's packing. slip alLachrd rxith:4 6xui? Ycs El No 5. Wcrc pro cr custody procedures (relinyuishcd,'tecc:v .d) follawod" Yea ❑ No fl. Wcrr. samplw 1Ds listed oil the COG° 5TYml ❑ NO 7_ Werr -, lntiplc llls listed oil all swilple onniitiner5? -R1�Ycs ❑ No R. Was c.IFllr;a lion date cr7. tme listed oil the COC? ❑ Ycs -`No 9- WiL5 .:+ 1cction date r+k time Listed fwl all MM11nit: eclnlain!M'} [a} Yes ❑ No 10. J.)ld all container label information (TD, dale, timc)ag'ee with the COG`' Yls ❑ No 1 1, wststo be p&-armed Jisted Dn the CC1M Yes ❑ Na 12. Did EL11 5anlp]CS an7vO in theproper comainer4 Tore} test andrOt' in �00d C611dil-kin (utibl- of(s:n. ]ids oil- etc_) ? 'kcs ❑ No I_s. Wm - a duquatc samplc ecilume axrailahle? cs [*0 14, %Vvic ali samples receNred �roitll4LYLIIlc liulding ti lie Oro? 1101AIS, wv]IiuhrM,r cum first? Yes N 3 I S_ Wvry tiny snm; lhs container. xe . 1 e11e) sa.lr. lea NOL lisLr£] ern COL'J [� Yes l7 Q 1�:A 16_ For VOA and RST{-17i same cs, a e; lur cnL`~"pcta size`' {i."or 6mm in diam.V. j in a.uy ofthe VDA vial.O }J'e N❑ U N k 17_ Were roll I) Gt rnetal3'llutrieIA �wnplu,, rL!wivcd at a pll of f 2" I❑ Yus ❑ No ' NAI 19. WcrcaJI cvanideiarnp3lrx reccivcd at pH -- 12 allalsulpll;: uanphn rticciyed at a pT4:x ? �] Yrc ❑ No NA ]4_�Grerea appkra e 1TT1!TKNr'cysuli�lw`phcno't5Z3(<il.5m�1T,)eramplcs ceotres[dual ol>Iloriue? ❑'res [I ltr N.4 U. Wcrc client remarks. reques is (:_n, rcrpuested dilutions, ITS,'MSI) &3iglations, etc...) carrur tly transcribed from dieCOC6 inLu Lhc c mimcnt sacrirrn ire TJMg4 .' V '1. War, the quote nultrbe: 1isl.rc ua Ll oumt-ainvr Jahef? If yes, QuratcArL � Sample Preservation f. M u ;[ I,,-- c,,iF;np1vzdforally'sanple(s)i:iL:{IrrQuOl pnc cnrdorwithhaatlspaI :..) SLpnplU: b) wurc received incu--,ezDy prL:sL:rvcdand vw'eit adju.;ia it wccordin�Jy in smuplc rccciving with InT. tsf cir0r. Llnu; WS04, HNO3, I ICl, NiOj3 using SIB { . 11Lne of preSerwdion . If morn than onc-iresenutive IS fieakald, plcas0 nOte ill th-3 GI FMrNUn1.5 below. 5anlrle(s) were received with Nibb'es >6 rtlnl ill di;41mctcr_ SsllttpJcs(s) were l>viceiv,�J wiLh TRC = 0,5 mg L (if 919 is no ) and were idjusicd accordingly in sample receivii;g with 50diuLuth103ulfate (Nrl, f3,) witJl �aealy 1n SR 1z?r{ode lobe Is applied ley'_ Dvtie' 7 p Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 52 of 52