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HomeMy WebLinkAbout1403_Caldwell_Foothills_MSWLF_ReleaseResults_FID1516744_20201204REPORT OF LIMITED LEACHATE RELEASE ASSESSMENT FOOTHILLS REGIONAL MSW LANDFILL CALDWELL COUNTY, NORTH CAROLINA Permit No. 1403-MSWLF-1998 Prepared For: Republic Services of North Carolina, LLC AT REPUBLIC bpi$SERVICES BLE Project Number J20-1235-98 �i•Iq l�yy} r H r f r! r, i2t fr o•{ G A R'••� December 3, 202 ���• z 2653 f {kr�'��� ire i• u H �I;� y}'s1 BLE North Carolina Business Licenses C-284 & C-1538 IM 13UNNELL M LAMMONS ENGiNEER1NG 6004 Ponders Court I Greenville, 5C 29615 864-288.1265 A 864,286.4330 w info@hle[orp.com BLECORMOM RUNNELS � LAMMONS ENGINEERING December 3, 2020 Foothills Regional MSW Landfill C/O Republic Services of North Carolina, LLC 1070 Riverside Drive Asheville, North Carolina 28804 Attention: Mr. Derek Bouchard Environmental Manager Subject: Report of Limited Leachate Release Assessment Foothills Regional MSW Landfill Caldwell County, North Carolina Permit No. 1403-MSWLF-1998 BLE Project Number J20-1235-98 Dear Mr. Bouchard: Pursuant to your authorization of Bunnell-Lammons Engineering, Inc. (BLE) Proposal Number J20-1235-98, dated November 10, 2020, BLE has prepared this report of limited leachate release assessment at the Foothills Regional MSW Landfill (FHLF). The purpose of the assessment is to perform sampling and reporting of soil and surface water in general accordance with the North Carolina Division of Waste Management (DWM) — Solid Waste Section (SWS) Leachate Release Sampling and Analysis Guidelines forMSWLandfills updated January 31, 2020. This report contains the information required by the SWS to document the sampling and analysis results in the facility records. Sincerely, BUNNELL LAMMONs ENGINEERING INC. t Timothy J. Daniel, P.G. Staff Hydrogeologist Registered, NC #2653 cc: Ms. Jaclynne Drummond — DWM-SWS ARO 6 W / A � Andrew W. Ale der, P.G., RSM Senior Hydrogeologist Registered, NC #1475 Ilblegvlsvrllsolidwasteprojectslfoothills msw landfill ncV235-98 leachate release samplingl5 reportldraft fhlf 1403-mswlf-1998 leachate assess 1235-98.docx 6004 Ponders Court, Greenville, SC 29615 ( H!54.28B.1265 a B64.288.4430 'P—q5info@hlerorp.Eom 6LECORP.COM 1s 1m 1i Foothills Regional MSW Landfill — Caldwell County, North Carolina December 3, 2020 Report of Limited Leachate Release Assessment BLE Project No. J20-1235-98 TABLE OF CONTENTS 1.0 PROJECT INFORMATION........................................................................................................1 2.0 FIELD ACTIVITIES, SAMPLING, AND ANALYSIS.............................................................1 3.0 RESULTS....................................................................................................................................... 2 3.1 Soil................................................................................................................................................... 2 3.2 Surface Water.................................................................................................................................. 2 4.0 CONCLUSIONS AND RECOMMENDATIONS.......................................................................3 4.1 Soil................................................................................................................................................... 3 4.2 Surface Water.................................................................................................................................. 3 4.3 Summary..........................................................................................................................................3 5.0 QUALIFICATIONS OF REPORT.............................................................................................. 4 6.0 CLOSING.......................................................................................................................................4 Tables Table 1 Soil Analytical Results Table 2 Surface Water Analytical Results Figures Figure 1 Site Location Map Figure 2 Leachate Release Sampling Plan Appendices Appendix A Laboratory Analytical Data — Pace Analytical Services, LLC. iofi 1s 1m 1i Foothills Regional MSW Landfill — Caldwell County, North Carolina December 3, 2020 Report of Limited Leachate Release Assessment BLE Project No. J20-1235-98 1.0 PROJECT INFORMATION The existing Foothills Regional Municipal Solid Waste (MSW) Landfill is located on Cheraw Road approximately two miles northwest of Lenoir, North Carolina (Figure 1). The landfill is owned by the Caldwell County Board of Commissioners and operated by Republic Services of North Carolina, LLC (Republic). The landfill development is being implemented in phases as new solid waste cells are needed. To date, Cell Nos. IA, 1B, 2A, 2B, 3A, 3B, 3C, 4, 5A, and 8A have been constructed. We understand that SWS representative, Mr. Charles Gerstell, observed a small leachate seep during an inspection on November 4, 2020. The seep emanated from Cell No. 4, where it exited the lined area and entered the surface water control ditch line on the western perimeter of the landfill. Leachate was contained within the ditch and had not reached any outlet structures to the facility sediment control basins. Landfill staff excavated the location of the seep and removed a mattress near the bottom of intermediate cover that was the potential cause. The excavation was filled with washed stone to promote drainage from this area into the waste mass and topped with clean fill soil to prevent future seepage. The contact soils were excavated and disposed in the landfill. Clean soils were placed in the excavation area and covered with riprap for erosion control. Mr. Derek Bouchard contacted SWS geologist Ms. Jaclynne Drummond via telephone on November 6, 2020 to report the incident. Mr. Derek Bouchard prepared and issued a Leachate Release Sampling Plan dated November 11, 2020. We understand that the plan was subsequently approved by the SWS. The plan includes the sampling and analysis of two (2) soil samples and two (2) surface water samples in accordance with the aforementioned guidance. Foothills LF retained Pace Analytical Services, LLC (Pace) to provide sampling supplies and analytical services and BLE for sampling and reporting services. 2.0 FIELD ACTIVITIES, SAMPLING, AND ANALYSIS BLE mobilized an environmental professional to the subject site on November 16 & 20, 2020 to perform sampling. Two soil samples and one surface water sample were collected on November 16, 2020 and two surface water samples were collected on November 20, 2020. Soil samples were designated BGS1 (F) for the background sample and DGS2 (1.5') for the potentially impacted sample. Both samples were discrete (grab) samples collected from the depths shown on the sample names. Surface water samples were designated USW-1 for the background (upstream) sample and PIW-1 and PIW-2 for potentially impacted (downstream) samples. All three surface water samples were discrete (grab) samples. Please note that the surface water sampling plan was revised by Republic to include an additional surface water sampling point. Sample locations are shown on Figure 2. The soil and surface water samples were delivered to Pace Analytical Services, LLC. (Pace) of Asheville, North Carolina on the dates collected and subsequently analyzed in Pace's North Carolina certified laboratories. The samples were analyzed in the laboratory for Appendix I volatile organic compound (VOCs) and total metals [40 CFR Part 258 Appendix I], total phosphorus, sulfate, nitrate, and pH. The surface water samples were also measured in the field for pH by BLE. The laboratory analytical data is included in Appendix A. 1 of 4 1s 1M 1i Foothills Regional MSW Landfill — Caldwell County, North Carolina December 3, 2020 Report of Limited Leachate Release Assessment BLE Project No. J20-1235-98 3.0 RESULTS 3.1 Soil The background soil sample BGS1 (F) was collected from a depth of one foot below ground surface and was located north and outside the limits of the future waste boundary. The potentially impacted soil sample DGS2 (1.5') was collected from a depth of 1.5 feet below ground surface and was located at the origin of the leachate outbreak (Figure 2). The results of the soil laboratory analyses are summarized on Table 1 and the laboratory analytical data is included in Appendix A. The laboratory analytical results were compared to the North Carolina Department of Environmental Quality Preliminary Soil Remediation Goals (PSRG) dated July 2020'. The results indicate that concentrations of total antimony, arsenic, chromium, and cobalt exceeded one or more PSRG in both the background and potential impacted samples. The results did not exceed any other PSRG (if established) for the remaining analytes in either of the samples. The soil pH appears to be in the normal range for local soils. 3.2 Surface Water The background (upstream) surface water sample USW-1 was collected from the unnamed tributary to Abingdon Creek west of the leachate release area. Two potentially impacted surface water samples were collected. They included sample PIW-1 collected in Wet Detention Basin No. 1B and PIW-2 collected from the outfall of Basin No. I and prior to discharge into the unnamed tributary (Figure 2). The results of the surface water field and laboratory analyses are summarized on Table 2 and the laboratory analytical data is included in Appendix A. The laboratory analytical results were compared to the North Carolina Surface Water Quality Standards (NC2B)2 limits. The results indicate that concentrations of total copper and lead exceeded the NC2B standards in sample PIW-1 and that concentrations of total copper exceeded the NC2B standard in sample PIW-2. The results did not exceed any other NC2B standard (if established) for the remaining analytes in any of the samples. It was noted during sampling that the surface water in Basin No. 1 B was turbid (sample PIW-1). We understand that this is a typical condition and not related to any infrastructure malfunction. The surface water pH appears to be in the normal range for local surface water and is within the NC2B standard limits for surface water. 'North Carolina Department of Environmental Quality, Preliminary Soil Remediation Goals (PSRG) dated July 2020. 2 North Carolina Department of Environmental Quality, Surface Waters and Wetlands Standards, Section 15A NCAC 02B workbook dated June 10, 2019. 2 of 4 1s 1m 1i Foothills Regional MSW Landfill — Caldwell County, North Carolina December 3, 2020 Report of Limited Leachate Release Assessment BLE Project No. J20-1235-98 4.0 CONCLUSIONS AND RECOMMENDATIONS 4.1 Soil We conclude that the laboratory analytical results for pH, nitrate, total phosphorus, sulfate, and VOCs indicate that the soil has not been impacted by leachate. Additionally, the laboratory analytical results for background total metals are very similar to the results for the potentially impacted soil sample. These metals data indicate that the detected metals are naturally occurring and not an indicator of a leachate release. It is also noted that copper and lead were detected in both soil samples. 4.2 Surface Water The laboratory analytical results for the leachate sample collected during the July 2020 sampling event (which were previously reported to the SWS) have been added to Table 2 to illustrate the constituents of the facility's leachate (the potential source). Additionally, the receiving water for the unnamed tributary at the site has been identified as Abingdon Creek which has been designated a Class C water by the NC Division of Water Resources. Therefore, the water quality in the unnamed tributary is compared to those of Class C waters. We conclude that the laboratory analytical results for pH, nitrate, total phosphorus, sulfate, and VOCs indicate that the surface water has not been impacted by leachate. Additionally, the concentrations of total copper and total lead which exceed NC2B standards are likely naturally occurring as documented in the soil sampling results. The metals detected in surface water sample PIW-1 are likely the result of the turbidity of the surface water in Basin No. 1B. Furthermore, the leachate does not contain copper and cannot be a source of the copper detected in the surface water. 4.3 Summary Soil and surface water sampling and analysis was conducted in general accordance with the SWS approved sampling plan. The data indicates that leachate has not impacted the tested soil or surface water. The metals detected in the site's soil and surface water appear to be naturally occurring. Landfill staff identified the source of the leachate release, mitigated the cause, excavated and disposed contact soils, and backfilled and regraded the affected area for proper drainage. We recommend no further action for the leachate release. 3 of 4 1s 1M 1i Foothills Regional MSW Landfill — Caldwell County, North Carolina December 3, 2020 Report of Limited Leachate Release Assessment BLE Project No. J20-1235-98 5.0 QUALIFICATIONS OF REPORT The activities and evaluative approaches used in this assessment are consistent with those normally employed in hydrogeological and environmental assessments of this type. Our evaluation of site conditions has been based on our understanding of the site and project information and the data provided to BLE. This report has been prepared on behalf of and exclusively for the use of Republic Services of North Carolina, LLC. This report and the findings contained herein shall not, in whole or in part, be used or relied upon by any other parry (excluding the DW1V1) without BLE's prior written consent. 6.0 CLOSING We appreciate the opportunity to be of service to Republic Services of North Carolina, LLC. Please contact us at (864) 288-1265 if you have any questions or comments. 4 of 4 TABLES Table 1 Soil Analytical Results Foothills Regional MSW Landfill Caldwell County, North Carolina Permit No. 1403-MSWLF-1999 BLE Project Number: J20-1235-98 TESTS Ref. Class UNITS Residential Health -Based PSRG Protection of Groundwater PSRG BGSl 1 (�) DGS2 1,5 ( I) pH su NE NE 5.8 6.0 Nitrogen, Nitrate mg/kg 25,000 NE <2.4 <1.3 Phosphourus, Total mg/kg NE NE 45.0 131 Sulfate mg/kg NE NE <12.9 34.1 J Metals (Total) Total Antimony (Sb) metallic mg/kg 6.3 0.90 1.4 1.5 ----------------------- Total Arsenic (As) ----------------------- ------------ ------ inorganic ------------------- -------- mg/kg -------- ------------ 0.68 ------------ -------------- 5.8 -------------- -------- 2.0 -------- --------- 3.2 --------- Total -Barium (Ba)- -------------------- ------------------- mg/kg -------- ----3_100 --- ----- 580 ----- - 154 -- - ---161 --- Total and compounds mg/kg 31 63 1.2 15 -Beryllium -(Be) --------------------- Total Cadmium (Cd) ----------------------- ------------------- diet ------------------- -------- mg/kg -------- ----- -- ------------ 14 ------------ -------- 3.0 -------------- -------- <0.037 -------- --------- <0.054 --------- Total Chromium (Cr) ----------------------- VI ------------------- mg/kg -------- 0.31 ------------ 3.8 -------------- 20.5 -------- 29.3 --------- Total Cobalt (Co) ----------------------- ------------------- mg/kg -------- 4.7 ------------ 0.9 -------------- 8.4 -------- 8.4 --------- Total Copper (Cu) mg/kg 630 700 14.0 18.2 ----------------------- Total Lead (Pb) ------------------- and compounds -------- mg/kg ------------ 250 -------------- 270 -------- 7.9 --------- 12.5 - ---------------------- Total Nickel (Ni) ------------------- soluble salts -------- mg/kg -------- --------- 310 ---- -------- 130 -- ------ 15.6 ------ 15.7 ----------------------- Total Selenium (Se) ----------------------- ------------------ ------------------ -------- mg/kg -------- ------------ 78 ---------------------------------------------- -------------- 2.1 -------- 1.5 --------- 2.0 Total Silver (Ag) mg/kg 78 3.4 <0.19 <0.27 ----------------------- Total Thallium (T1) ---------- ------------- ------------------- soluble salts ------------------- -- ------------------------ mg/kg -------- ---------- 0.16 ------------ ----------- 0.28 -------------- -- <0.37 -------- -- <0.54 --------- Total Vanadium (V) and compounds mg/kg 78 350 26.4 47.7 ----------------------- Total Zinc (Zn) ------------------- and compounds -------- mg/kg ------------ 4,700 -------------- 1,200 -------- 69.4 --------- 62.2 VOCs Benzene mg/kg 1.2 0.0032 J <0.0032 Toluene mg/kg ]_____O.O1 990 8.3 1 0.0071 1 <0.0023 Notes: PSRG - North Carolina Department of Environmental Quality Preliminary Soil Remediation Goals (July 2020) Ref. Class = regulatory standard reference class Bold = Constituents detected above the laboratory detection limit. Shaded Value - Concentration detected above one or more regulatory standards NE = Not Established; Agency has not established an applicable standard ND - Not Detected J = estimated value between the detection limit and reporting limit mg/kg - milligrams per kilogram Samples colleted by BLE on November 16, 2020 11' 'MM I BUNNELL LAMMONS ENGINEERING Table 2 Surface Water Analytical Results Foothills Regional MSW Landfill Caldwell County, North Carolina Permit No. 1403-MSWLF-1999 BLE Project Number: J20-1235-98 TESTS UNITS NC2B Leachate USW-1 PlW-1 PIW-2 pH pH (field) so <6.0; >9.0 7.31 7.30 7.65 pH (lab) su <6.0; >9.0 8.02 1 6.7 6.5 6.7 Nitrogen, Nitrate µg/L NE <80 <60 1,800 72.1 Phosphourus, Total µg/L NE 9,400 97 50 49 J Sulfate ug/L NE <25,000 1,400 2,400 1,800 Metals (Total) Total Antimony (Sb) ------------------------------- µg L ------------ 5,300 ------------- 13.4 J ------------ <3.0 ------------ <3.0 ------------ <3.0 ------------ Total Arsenic (As) ------------------------------- µg/L ------------ 10 ------------- 31.1 J ------------ <4.7 ------------ 8.6 J ------------ <4.7 ------------ Total Barium (Ba) ------------------------------- µg/L ------------ 21,000 ------------- 66.9 J ------------ 19.7 ------------ 152 ------------ 59.7 ------------ Total Beryllium (Be) ------------------------------- µg/L ------------ 65 ------------- <0.23 ------------ <0.7 ------------ 2.0 ------------ <0.7 ------------ Total Cadmium (Cd) ------------------------------- µg/L ------------ 0.82 ------------- <0.59 ------------ 0.74 J ------------ <0.4 ------------ <0.4 ------------ TotalChromium (Cr) <3.7 -----Cobalt(- ------------- Total Cobalt (Co) ---µg/L - --- ----183- - ---- -----16 ----- ---104- - ---- --- 7.3 J---- -- - ---- ----<3_6-- ---23_9 .... ---- ----10_5 ----6_3 - ---- --- Total Copper (Cu)---------------- ------- ---- µg/L --- ---- 3.6 - ----- -- <8_5 - ---- -- <4.3 - ---- ---- 30_4 ---- ----5_5 - ---- Total Lead (Pb) 13.9 J <4.5---- To--------- -------------------- tal Nickel (Ni) ------------------------------- ----- ------ µg/L ------------ --------- ---- -----145 -------- ---0_51 --- ---52.2 J --------- ----<4- ---- <3.5 -------- ----24_1---- ----12.6 -------- ---- ----3.7 J --- ----- Total Selenium (Se) ------------------------------- µg/L ------------ 5.0 ------------- <7.8 ------------ <4.7 ------------ <4.7 ------------ <4.7 ------------ Total Silver Ap----------------- - --- µ --- ---- -- - ----- - ---- -- --- - ---- -- --- <25 -------------------------- <2.5----------�-) Total Thallium (T1) ------------------------------- µg/L ------------ 2 ------------- <0.72 ------------ <8.1 ------------ <8.1 ------------ <8.1 ------------ Total Vanadium (V) ------------------------------- µg/L ------------ NE ------------- 23.8 J ------------ <3.9 ------------ 71.2 ------------ 10.4 ------------ Total Zinc (Zn) 36 36.8 J <9.5 30 23.6 VOCs 1,2-Dichloroethane µg/L 650 0.43 J <0.34 <0.1 <0.34 ------------------------------- cis-1,2-Dichloroethene ------------ µg/L ------------- 720 ------------ 0.54 J ------------ <0.29 ------------ <0.29 ------------ <0.29 ------------------------------- 1,4-Dichlorobenzene ------------------------------- ------------ µg/L ------------ ------------- 100 ------------- ------------ 3.6 ------------ ------------ <0.26 ------------ ------------ <0.26 ------------ ------------ <0.26 ------------ 2-Butanone ------------------------------- µg/L ------------ 26,000 ------------- 262 ------------ <3.3 ------------ <3.3 ------------ <3.3 ------------ 2-Hexanone ------------------------------- µg/L ------------ NE ------------- 2.0 J ------------ <0.57 ------------ <0.57 ------------ <0.57 ------------ 4-Methyl-2-pentanone (MIBK) ------------------------------- µg/L ------------ 26,000 ------------- ----7.1 ---J ----- <4.5 ------------ <4.5 ---- ---- --------- <4.5 -------- Acetone ------------------------------- µg/L ------------ 2,000 ------------- 322 ------------ <6.2 ------------ <6.2 ------------ <6.2 ------------ Benzene ------------------------------- µg/L ------------ 51 ------------- 3.0 ------------ <0.15 ------------ <0.15 ------------ <0.15 ------------ Chlorobenzene------------- --------------------------------------------- µg/L ---- --- 140 ---------- 0.28 J ------ <0.23 ------- <0.23 ---- <0.23 ------------ Ethylbenzene ------------------------------- µg/L ------------ 97 ------------- 19.6 ------------ <0.26 ------------ <0.26 ------------ <0.26 ------------ Toluene ------------------------------- µg/L ------------ 11 ------------- 7.4 ------------ <0.24 ------------ <0.24 ------------ <0.24 ------------ Xylenes, Total µg/L 670 27.8 <0.63 <0.63 <0.63 -------------------------------I------- All Other Analytes µg/L -----NE ..-- NE ------------ ND ------------ ND ------------ ND ------------ ND Notes: NC2B - North Carolina Surface Water Standards for Class C freshwater under Title 15A Subchapter 213. per NC DWR Surface Water Quality Standards, Criteria, & In -Stream Target Values (Workbook Dated 6-10-2019) An assumed hardness of 25 mg/L was utilized to calculate a acute standard for metals Bold = Constituents detected above the laboratory detection limit. Shaded Value - Concentration detected above one or more regulatory standards NE = Not Established; Agency has not established an applicable standard ND - Not Detected J = estimated value between the detection limit and reporting limit µg/L - micrograms per liter Sample Leachate colleted by ES&S on July 27, 2020 Sample PIW-2 colleted by BLE on November 16, 2020 Sample USW-1 & PIW-1 colleted by BLE on November 20, 2020 I== I BUNNELL BUNNELL ENGINEERING FIGURES Oli�ette � - 0 o v� GREASY CREEK RD V t600 � Q � t P A Grassy O Peaked�Top v O � a o t Top U Ir� O o � D Sq�G b I BROOKS H I R� ¢ ingdon Q D I LAP o o h O� �T 1ti Cgti 1200 2000 1000 0 2000 4000 REFERENCE: USGS TOPOGRAPHIC MAP, 7.5 MINUTE SERIES, APPROXIMATE SCALE IN FEET LENOIR, N.C. QUADRANGLE, 2019. DRAWN: KLW DATE: 12-1-20 FIGURE AWA FHLF98—SLM II I.I. BAMM ONS FOOTHILLS REGIONAL M W LANDFILL TE LOCATION MAP CHECKED: CAD: 6004 Ponders Court, Greenville, SC 29615 CALDWELL COUNTY, NORTH CAROLINA 1 APPROVED: JOB NO: J20-1235-98 Phone: (864) 288-1265 Fax: (864) 288-4430 " F 6HWrM tl,K�.U. II Mik.1 0 10 `Dl\M.1,I111OMMJ!1J!1` III'YAT6 Q61 6ACr. ACC6CC1U16wIT CAYLS1 IME-2 LI1 M APPENDIX A LABORATORY ANALYTICAL DATA - PACE ANALYTICAL SERVICES, LLC. leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 December 02, 2020 Derek Bouchard Republic Services 1070 Riverside Dr Asheville, NC 28804 RE: Project: Foothills Landfill 11/16 Pace Project No.: 92506305 Dear Derek Bouchard: Enclosed are the analytical results for sample(s) received by the laboratory on November 16, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace National - Mt. Juliet • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte Revised Report: Report revised to report J-values,Rename sample DGSW-2 to PIW-2, To remove 1,4-dioxane from all samples,Remove sample BGSW-1 from report If you have any questions concerning this report, please feel free to contact me. Sincerely, Chris Derouen christopher.derouen@pacelabs.com (828)254-7176 Project Manager Enclosures cc: Trihydro, Republic Services REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 50 lacieAnalyfica(' www,pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Foothills Landfill 11/16 Pace Project No.: 92506305 Pace Analytical Services National 12065 Lebanon Road, Mt. Juliet, TN 37122 Alabama Certification #: 40660 Alaska Certification 17-026 Arizona Certification #: AZ0612 Arkansas Certification #: 88-0469 California Certification #: 2932 Canada Certification #: 1461.01 Colorado Certification #: TN00003 Connecticut Certification #: PH-0197 DOD Certification: #1461.01 EPA# TN00003 Florida Certification #: E87487 Georgia DW Certification #: 923 Georgia Certification: NELAP Idaho Certification #: TN00003 Illinois Certification #: 200008 Indiana Certification #: C-TN-01 Iowa Certification #: 364 Kansas Certification #: E-10277 Kentucky UST Certification #: 16 Kentucky Certification #: 90010 Louisiana Certification #: A130792 Louisiana DW Certification #: LA180010 Maine Certification #: TN0002 Maryland Certification #: 324 Massachusetts Certification #: M-TNO03 Michigan Certification #: 9958 Minnesota Certification #: 047-999-395 Mississippi Certification #: TN00003 Missouri Certification #: 340 Montana Certification M CERT0086 Nebraska Certification #: NE-OS-15-05 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification M 37712 CERTIFICATIONS Nevada Certification #: TN-03-2002-34 New Hampshire Certification #: 2975 New Jersey Certification #: TNO02 New Mexico DW Certification New York Certification #: 11742 North Carolina Aquatic Toxicity Certification #: 41 North Carolina Drinking Water Certification #: 21704 North Carolina Environmental Certificate #: 375 North Dakota Certification #: R-140 Ohio VAP Certification #: CL0069 Oklahoma Certification #: 9915 Oregon Certification #: TN200002 Pennsylvania Certification #: 68-02979 Rhode Island Certification #: LA000356 South Carolina Certification #: 84004 South Dakota Certification Tennessee DW/Chem/Micro Certification #: 2006 Texas Certification #: T 104704245-17-14 Texas Mold Certification #: LAB0152 USDA Soil Permit #: P330-15-00234 Utah Certification #: TN00003 Vermont Dept. of Health: ID# VT-2006 Virginia Certification #: VT2006 Virginia Certification #: 460132 Washington Certification #: C847 West Virginia Certification #: 233 Wisconsin Certification #: 998093910 Wyoming UST Certification #: via A21-A 2926.01 A21-A-ISO 17025 Certification #: 1461.01 A21-A-ISO 17025 Certification #: 1461.02 AIHA-LAP/LLC EMLAP Certification #:100789 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 SAMPLE SUMMARY Project: Foothills Landfill 11/16 Pace Project No.: 92506305 Lab ID Sample ID Matrix Date Collected Date Received 92506305001 BGS1 (1) Solid 11/16/20 10:55 11/16/20 13:34 92506305002 DGS2 (1.5) Solid 11/16/20 09:45 11/16/20 13:34 92506305004 PIW-2 Water 11/16/2010:20 11/16/20 13:34 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 SAMPLE ANALYTE COUNT Project: Foothills Landfill 11/16 Pace Project No.: 92506305 Analytes Lab lD Sample ID Method Analysts Reported Laboratory 92506305001 BGS1 (1) EPA 6010D SH1 15 PASI-A EPA 8260D CL 48 PASI-C ASTM D2974-87 KDF 1 PASI-C SM 2540G KBC 1 PAN EPA 9056A MCG 1 PAN EPA 9045D SMK 1 PASI-A EPA 353.2 Rev 2.0 1993 CJL 3 PASI-A EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A 92506305002 DGS2 (1.5) EPA 6010D SH1 15 PASI-A EPA 8260D CL 48 PASI-C ASTM D2974-87 KDF 1 PASI-C SM 2540G KBC 1 PAN EPA 9056A MCG 1 PAN EPA 9045D SMK 1 PASI-A EPA 353.2 Rev 2.0 1993 CJL 3 PASI-A EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A 92506305004 PIW-2 EPA 6010D SH1 15 PASI-A EPA 8260D SAS 52 PASI-C EPA 9040C SMK 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 4 PASI-A EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A PAN = Pace National - Mt. Juliet PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Foothills Landfill 11/16 Pace Project No.: 92506305 Sample: BGS1 (1) Lab ID: 92506305001 Collected: 11/16/20 10:55 Received: 11/16/20 13:34 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3050B Pace Analytical Services -Asheville Antimony 1.4 mg/kg 0.37 0.29 1 11/17/20 09:49 11/18/20 02:15 7440-36-0 Arsenic 2.0 mg/kg 0.75 0.37 1 11/17/20 09:49 11/18/20 02:15 7440-38-2 Barium 154 mg/kg 0.37 0.19 1 11/17/20 09:49 11/18/20 02:15 7440-39-3 Beryllium 1.2 mg/kg 0.075 0.037 1 11/17/20 09:49 11/18/20 02:15 7440-41-7 Cadmium ND mg/kg 0.075 0.037 1 11/17/20 09:49 11/18/20 02:15 7440-43-9 Chromium 20.5 mg/kg 0.37 0.19 1 11/17/20 09:49 11/18/20 12:34 7440-47-3 Cobalt 8.4 mg/kg 0.37 0.19 1 11/17/20 09:49 11/18/20 02:15 7440-48-4 Copper 14.0 mg/kg 0.37 0.19 1 11/17/20 09:49 11/18/20 02:15 7440-50-8 Lead 7.9 mg/kg 0.37 0.19 1 11/17/20 09:49 11/18/20 02:15 7439-92-1 Nickel 15.6 mg/kg 0.37 0.19 1 11/17/20 09:49 11/18/20 02:15 7440-02-0 Selenium 1.5 mg/kg 0.75 0.37 1 11/17/20 09:49 11/18/20 02:15 7782-49-2 Silver ND mg/kg 0.37 0.19 1 11/17/20 09:49 11/18/20 02:15 7440-22-4 Thallium ND mg/kg 0.75 0.37 1 11/17/20 09:49 11/18/20 02:15 7440-28-0 Vanadium 26.4 mg/kg 0.37 0.19 1 11/17/20 09:49 11/18/20 02:15 7440-62-2 Zinc 69.4 mg/kg 0.75 0.37 1 11/17/20 09:49 11/18/20 02:15 7440-66-6 8260D/5035A/5030B Volatiles Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte Acetone ND ug/kg 133 42.6 1 11/17/20 15:50 11/17/20 20:25 67-64-1 Acrylonitrile ND ug/kg 133 23.1 1 11/17/20 15:50 11/17/20 20:25 107-13-1 Benzene 3.2J ug/kg 6.6 2.6 1 11/17/20 15:50 11/17/20 20:25 71-43-2 Bromochloromethane ND ug/kg 6.6 2.0 1 11/17/20 15:50 11/17/20 20:25 74-97-5 Bromodichloromethane ND ug/kg 6.6 2.6 1 11/17/20 15:50 11/17/20 20:25 75-27-4 IK Bromoform ND ug/kg 6.6 2.3 1 11/17/20 15:50 11/17/20 20:25 75-25-2 Bromomethane ND ug/kg 13.3 10.5 1 11/17/20 15:50 11/17/20 20:25 74-83-9 v2 2-Butanone (MEK) ND ug/kg 133 31.9 1 11/17/20 15:50 11/17/20 20:25 78-93-3 Carbon disulfide ND ug/kg 13.3 8.3 1 11/17/20 15:50 11/17/20 20:25 75-15-0 Carbon tetrachloride ND ug/kg 6.6 2.5 1 11/17/20 15:50 11/17/20 20:25 56-23-5 Chlorobenzene ND ug/kg 6.6 1.3 1 11/17/20 15:50 11/17/20 20:25 108-90-7 Chloroethane ND ug/kg 13.3 5.1 1 11/17/20 15:50 11/17/20 20:25 75-00-3 Chloroform ND ug/kg 6.6 4.0 1 11/17/20 15:50 11/17/20 20:25 67-66-3 Chloromethane ND ug/kg 13.3 5.6 1 11/17/20 15:50 11/17/20 20:25 74-87-3 v2 1,2-Dibromo-3-chloropropane ND ug/kg 6.6 2.6 1 11/17/20 15:50 11/17/20 20:25 96-12-8 Dibromochloromethane ND ug/kg 6.6 3.7 1 11/17/20 15:50 11/17/20 20:25 124-48-1 1,2-Dibromoethane (EDB) ND ug/kg 6.6 2.9 1 11/17/20 15:50 11/17/20 20:25 106-93-4 Dibromomethane ND ug/kg 6.6 1.4 1 11/17/20 15:50 11/17/20 20:25 74-95-3 1,2-Dichlorobenzene ND ug/kg 6.6 2.4 1 11/17/20 15:50 11/17/20 20:25 95-50-1 1,4-Dichlorobenzene ND ug/kg 6.6 1.7 1 11/17/20 15:50 11/17/20 20:25 106-46-7 trans-1,4-Dichloro-2-butene ND ug/kg 13.3 4.9 1 11/17/20 15:50 11/17/20 20:25 110-57-6 1,1-Dichloroethane ND ug/kg 6.6 2.7 1 11/17/20 15:50 11/17/20 20:25 75-34-3 1,2-Dichloroethane ND ug/kg 6.6 4.4 1 11/17/20 15:50 11/17/20 20:25 107-06-2 1,1-Dichloroethene ND ug/kg 6.6 2.7 1 11/17/20 15:50 11/17/20 20:25 75-35-4 cis-1,2-Dichloroethene ND ug/kg 6.6 2.3 1 11/17/20 15:50 11/17/20 20:25 156-59-2 trans-1,2-Dichloroethene ND ug/kg 6.6 2.3 1 11/17/20 15:50 11/17/20 20:25 156-60-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Foothills Landfill 11/16 Pace Project No.: 92506305 Sample: BGS1 (1) Lab ID: 92506305001 Collected: 11/16/20 10:55 Received: 11/16/20 13:34 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters 8260D/5035A/5030B Volatiles Ethylbenzene 2-Hexanone lodomethane 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates Toluene-d8 (S) 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Percent Moisture Percent Moisture Total Solids 2540 G-2011 Total Solids Results Units PQL MDL DF Prepared Analyzed CAS No. Qual Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte ND ug/kg 6.6 3.1 1 11/17/20 15:50 11/17/20 20:25 100-41-4 ND ug/kg 66.4 6.4 1 11/17/20 15:50 11/17/20 20:25 591-78-6 ND ug/kg 66.4 55.8 1 11/17/20 15:50 11/17/20 20:25 74-88-4 ND ug/kg 66.4 6.4 1 11/17/20 15:50 11/17/20 20:25 108-10-1 ND ug/kg 6.6 1.8 1 11/17/20 15:50 11/17/20 20:25 100-42-5 ND ug/kg 6.6 2.5 1 11/17/20 15:50 11/17/20 20:25 630-20-6 ND ug/kg 6.6 1.8 1 11/17/20 15:50 11/17/20 20:25 79-34-5 ND ug/kg 6.6 2.1 1 11/17/20 15:50 11/17/20 20:25 127-18-4 7.1 ug/kg 6.6 1.9 1 11/17/20 15:50 11/17/20 20:25 108-88-3 ND ug/kg 6.6 3.5 1 11/17/20 15:50 11/17/20 20:25 71-55-6 ND ug/kg 6.6 2.2 1 11/17/20 15:50 11/17/20 20:25 79-00-5 ND ug/kg 6.6 1.7 1 11/17/20 15:50 11/17/20 20:25 79-01-6 ND ug/kg 6.6 3.7 1 11/17/20 15:50 11/17/20 20:25 75-69-4 ND ug/kg 6.6 3.4 1 11/17/20 15:50 11/17/20 20:25 96-18-4 ND ug/kg 66.4 4.8 1 11/17/20 15:50 11/17/20 20:25 108-05-4 ND ug/kg 13.3 3.4 1 11/17/20 15:50 11/17/20 20:25 75-01-4 ND ug/kg 13.3 3.8 1 11/17/20 15:50 11/17/20 20:25 1330-20-7 ND ug/kg 13.3 4.5 1 11/17/20 15:50 11/17/20 20:25 179601-23-1 ND ug/kg 6.6 2.9 1 11/17/20 15:50 11/17/20 20:25 95-47-6 99 % 70-130 1 11/17/20 15:50 11/17/20 20:25 2037-26-5 99 % 69-134 1 11/17/20 15:50 11/17/20 20:25 460-00-4 100 % 70-130 1 11/17/20 15:50 11/17/20 20:25 17060-07-0 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte 18.7 % 0.10 0.10 1 11/17/2014:53 Analytical Method: SM 2540G Preparation Method: SM 2540 G Pace National - Mt. Juliet 82.7 % 1 11/20/20 00:50 11/20/20 01:00 Wet Chemistry 9056A Analytical Method: EPA 9056A Preparation Method: 9056 Pace National - Mt. Juliet Sulfate ND mg/kg 50.0 12.9 1 11/20/20 09:50 11/20/20 12:11 14808-79-8 9045 pH Soil pH at 25 Degrees C 353.2 Nitrogen, NO2/NO3 Nitrogen, NO2 plus NO3 Nitrogen, Nitrate Date: 12/02/2020 10:38 AM Analytical Method: EPA 9045D Pace Analytical Services -Asheville 5.8 Std. Units 0.10 0.10 1 11/17/20 16:36 Analytical Method: EPA 353.2 Rev 2.0 1993 Preparation Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville ND mg/kg 4.9 2.4 1 11/17/20 19:26 11/17/20 22:43 ND mg/kg 4.9 2.4 1 11/17/20 19:26 11/17/20 22:43 14797-55-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. H3 Page 6 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Foothills Landfill 11/16 Pace Project No.: 92506305 Sample: BGS1 (1) Lab ID: 92506305001 Collected: 11/16/20 10:55 Received: 11/16/20 13:34 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 353.2 Nitrogen, NO2/NO3 Analytical Method: EPA 353.2 Rev 2.0 1993 Preparation Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrite ND mg/kg 4.9 1.2 1 11/17/20 19:26 11/17/20 22:43 14797-65-0 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 45.0 mg/kg 1.1 0.55 1 11/17/20 18:38 11/17/20 21:29 7723-14-0 Date: 12/02/2020 10:38 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Foothills Landfill 11/16 Pace Project No.: 92506305 Sample: DGS2 (1.5) Lab ID: 92506305002 Collected: 11/16/20 09:45 Received: 11/16/20 13:34 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3050B Pace Analytical Services -Asheville Antimony 1.5 mg/kg 0.54 0.42 1 11/17/20 09:49 11/18/20 02:18 7440-36-0 Arsenic 3.2 mg/kg 1.1 0.54 1 11/17/20 09:49 11/18/20 02:18 7440-38-2 Barium 161 mg/kg 0.54 0.27 1 11/17/20 09:49 11/18/20 02:18 7440-39-3 Beryllium 1.5 mg/kg 0.11 0.054 1 11/17/20 09:49 11/18/20 02:18 7440-41-7 Cadmium ND mg/kg 0.11 0.054 1 11/17/20 09:49 11/18/20 02:18 7440-43-9 Chromium 29.3 mg/kg 0.54 0.27 1 11/17/20 09:49 11/18/20 12:37 7440-47-3 Cobalt 8.4 mg/kg 0.54 0.27 1 11/17/20 09:49 11/18/20 02:18 7440-48-4 Copper 18.2 mg/kg 0.54 0.27 1 11/17/20 09:49 11/18/20 02:18 7440-50-8 Lead 12.5 mg/kg 0.54 0.27 1 11/17/20 09:49 11/18/20 02:18 7439-92-1 Nickel 15.7 mg/kg 0.54 0.27 1 11/17/20 09:49 11/18/20 02:18 7440-02-0 Selenium 2.0 mg/kg 1.1 0.54 1 11/17/20 09:49 11/18/20 02:18 7782-49-2 Silver ND mg/kg 0.54 0.27 1 11/17/20 09:49 11/18/20 02:18 7440-22-4 Thallium ND mg/kg 1.1 0.54 1 11/17/20 09:49 11/18/20 02:18 7440-28-0 Vanadium 47.7 mg/kg 0.54 0.27 1 11/17/20 09:49 11/18/20 02:18 7440-62-2 Zinc 62.2 mg/kg 1.1 0.54 1 11/17/20 09:49 11/18/20 02:18 7440-66-6 8260D/5035A/5030B Volatiles Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte Acetone ND ug/kg 161 51.8 1 11/17/20 15:50 11/17/20 21:01 67-64-1 Acrylonitrile ND ug/kg 161 28.1 1 11/17/20 15:50 11/17/20 21:01 107-13-1 Benzene ND ug/kg 8.1 3.2 1 11/17/20 15:50 11/17/20 21:01 71-43-2 Bromochloromethane ND ug/kg 8.1 2.4 1 11/17/20 15:50 11/17/20 21:01 74-97-5 Bromodichloromethane ND ug/kg 8.1 3.1 1 11/17/20 15:50 11/17/20 21:01 75-27-4 IK Bromoform ND ug/kg 8.1 2.8 1 11/17/20 15:50 11/17/20 21:01 75-25-2 Bromomethane ND ug/kg 16.1 12.7 1 11/17/20 15:50 11/17/20 21:01 74-83-9 v2 2-Butanone (MEK) ND ug/kg 161 38.7 1 11/17/20 15:50 11/17/20 21:01 78-93-3 Carbon disulfide ND ug/kg 16.1 10.1 1 11/17/20 15:50 11/17/20 21:01 75-15-0 Carbon tetrachloride ND ug/kg 8.1 3.0 1 11/17/20 15:50 11/17/20 21:01 56-23-5 Chlorobenzene ND ug/kg 8.1 1.5 1 11/17/20 15:50 11/17/20 21:01 108-90-7 Chloroethane ND ug/kg 16.1 6.2 1 11/17/20 15:50 11/17/20 21:01 75-00-3 M1 Chloroform ND ug/kg 8.1 4.9 1 11/17/20 15:50 11/17/20 21:01 67-66-3 Chloromethane ND ug/kg 16.1 6.8 1 11/17/20 15:50 11/17/20 21:01 74-87-3 v2 1,2-Dibromo-3-chloropropane ND ug/kg 8.1 3.1 1 11/17/20 15:50 11/17/20 21:01 96-12-8 Dibromochloromethane ND ug/kg 8.1 4.5 1 11/17/20 15:50 11/17/20 21:01 124-48-1 1,2-Dibromoethane (EDB) ND ug/kg 8.1 3.5 1 11/17/20 15:50 11/17/20 21:01 106-93-4 Dibromomethane ND ug/kg 8.1 1.7 1 11/17/20 15:50 11/17/20 21:01 74-95-3 1,2-Dichlorobenzene ND ug/kg 8.1 2.9 1 11/17/20 15:50 11/17/20 21:01 95-50-1 1,4-Dichlorobenzene ND ug/kg 8.1 2.1 1 11/17/20 15:50 11/17/20 21:01 106-46-7 trans-1,4-Dichloro-2-butene ND ug/kg 16.1 6.0 1 11/17/20 15:50 11/17/20 21:01 110-57-6 M1 1,1-Dichloroethane ND ug/kg 8.1 3.3 1 11/17/20 15:50 11/17/20 21:01 75-34-3 1,2-Dichloroethane ND ug/kg 8.1 5.3 1 11/17/20 15:50 11/17/20 21:01 107-06-2 1,1-Dichloroethene ND ug/kg 8.1 3.3 1 11/17/20 15:50 11/17/20 21:01 75-35-4 cis-1,2-Dichloroethene ND ug/kg 8.1 2.8 1 11/17/20 15:50 11/17/20 21:01 156-59-2 trans-1,2-Dichloroethene ND ug/kg 8.1 2.8 1 11/17/20 15:50 11/17/20 21:01 156-60-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Foothills Landfill 11/16 Pace Project No.: 92506305 Sample: DGS2 (1.5) Lab ID: 92506305002 Collected: 11/16/20 09:45 Received: 11/16/20 13:34 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D/5035A/5030B Volatiles Ethylbenzene 2-Hexanone lodomethane 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates Toluene-d8 (S) 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Percent Moisture Percent Moisture Total Solids 2540 G-2011 Total Solids Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte ND ug/kg 8.1 3.8 1 11/17/20 15:50 11/17/20 21:01 100-41-4 ND ug/kg 80.6 7.8 1 11/17/20 15:50 11/17/20 21:01 591-78-6 ND ug/kg 80.6 67.7 1 11/17/20 15:50 11/17/20 21:01 74-88-4 M1 ND ug/kg 80.6 7.8 1 11/17/20 15:50 11/17/20 21:01 108-10-1 ND ug/kg 8.1 2.1 1 11/17/20 15:50 11/17/20 21:01 100-42-5 ND ug/kg 8.1 3.1 1 11/17/20 15:50 11/17/20 21:01 630-20-6 ND ug/kg 8.1 2.1 1 11/17/20 15:50 11/17/20 21:01 79-34-5 ND ug/kg 8.1 2.5 1 11/17/20 15:50 11/17/20 21:01 127-18-4 ND ug/kg 8.1 2.3 1 11/17/20 15:50 11/17/20 21:01 108-88-3 ND ug/kg 8.1 4.2 1 11/17/20 15:50 11/17/20 21:01 71-55-6 ND ug/kg 8.1 2.7 1 11/17/20 15:50 11/17/20 21:01 79-00-5 ND ug/kg 8.1 2.1 1 11/17/20 15:50 11/17/20 21:01 79-01-6 ND ug/kg 8.1 4.4 1 11/17/20 15:50 11/17/20 21:01 75-69-4 ND ug/kg 8.1 4.1 1 11/17/20 15:50 11/17/20 21:01 96-18-4 ND ug/kg 80.6 5.9 1 11/17/20 15:50 11/17/20 21:01 108-05-4 ND ug/kg 16.1 4.1 1 11/17/20 15:50 11/17/20 21:01 75-01-4 ND ug/kg 16.1 4.6 1 11/17/20 15:50 11/17/20 21:01 1330-20-7 ND ug/kg 16.1 5.5 1 11/17/20 15:50 11/17/20 21:01 179601-23-1 ND ug/kg 8.1 3.6 1 11/17/20 15:50 11/17/20 21:01 95-47-6 99 % 70-130 1 11/17/20 15:50 11/17/20 21:01 2037-26-5 101 % 69-134 1 11/17/20 15:50 11/17/20 21:01 460-00-4 95 % 70-130 1 11/17/20 15:50 11/17/20 21:01 17060-07-0 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte 27.1 % 0.10 0.10 1 11/17/2014:53 Analytical Method: SM 2540G Preparation Method: SM 2540 G Pace National - Mt. Juliet 76.3 % 1 11/20/20 00:50 11/20/20 01:00 Wet Chemistry 9056A Analytical Method: EPA 9056A Preparation Method: 9056 Pace National - Mt. Juliet Sulfate 34.1J mg/kg 50.0 12.9 1 11/20/20 09:50 11/20/20 12:28 14808-79-8 J 9045 pH Soil pH at 25 Degrees C 353.2 Nitrogen, NO2/NO3 Nitrogen, NO2 plus NO3 Nitrogen, Nitrate Date: 12/02/2020 10:38 AM Analytical Method: EPA 9045D Pace Analytical Services -Asheville 6.0 Std. Units 0.10 0.10 1 11/17/20 16:32 Analytical Method: EPA 353.2 Rev 2.0 1993 Preparation Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville ND mg/kg 5.3 2.6 1 11/17/20 19:26 11/17/20 22:47 ND mg/kg 5.3 2.6 1 11/17/20 19:26 11/17/20 22:47 14797-55-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. H3 Page 9 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Foothills Landfill 11/16 Pace Project No.: 92506305 Sample: DGS2 (1.5) Lab ID: 92506305002 Collected: 11/16/20 09:45 Received: 11/16/20 13:34 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 353.2 Nitrogen, NO2/NO3 Analytical Method: EPA 353.2 Rev 2.0 1993 Preparation Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrite ND mg/kg 5.3 1.3 1 11/17/20 19:26 11/17/20 22:47 14797-65-0 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 131 mg/kg 2.7 1.3 2 11/17/20 18:38 11/17/20 21:30 7723-14-0 Date: 12/02/2020 10:38 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Foothills Landfill 11/16 Pace Project No.: 92506305 Sample: PIW-2 Lab ID: 92506305004 Collected: 11/16/20 10:20 Received: 11/16/20 13:34 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 11/17/20 02:36 11/17/20 22:36 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 11/17/20 02:36 11/17/20 22:36 7440-38-2 Barium 59.7 ug/L 5.0 3.5 1 11/17/20 02:36 11/17/20 22:36 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 11/17/20 02:36 11/17/20 22:36 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 11/17/20 02:36 11/17/20 22:36 7440-43-9 BC Chromium 6.3 ug/L 5.0 3.7 1 11/17/20 02:36 11/17/20 22:36 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 11/17/20 02:36 11/17/20 22:36 7440-48-4 Copper 5.5 ug/L 5.0 4.3 1 11/17/20 02:36 11/17/20 22:36 7440-50-8 Lead ND ug/L 5.0 4.5 1 11/17/20 02:36 11/17/20 22:36 7439-92-1 Nickel 3.7J ug/L 5.0 3.5 1 11/17/20 02:36 11/17/20 22:36 7440-02-0 Selenium ND ug/L 10.0 4.7 1 11/17/20 02:36 11/17/20 22:36 7782-49-2 Silver ND ug/L 5.0 2.5 1 11/17/20 02:36 11/17/20 22:36 7440-22-4 Thallium ND ug/L 10.0 8.1 1 11/17/20 02:36 11/17/20 22:36 7440-28-0 Vanadium 10.4 ug/L 5.0 3.9 1 11/17/20 02:36 11/17/20 22:36 7440-62-2 Zinc 23.6 ug/L 10.0 9.5 1 11/17/20 02:36 11/17/20 22:36 7440-66-6 8260D MSV Low Level Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 11/18/20 02:54 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 11/18/20 02:54 107-13-1 Benzene ND ug/L 1.0 0.15 1 11/18/20 02:54 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 11/18/20 02:54 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 11/18/20 02:54 75-27-4 Bromoform ND ug/L 1.0 0.62 1 11/18/20 02:54 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 11/18/20 02:54 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 11/18/20 02:54 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 11/18/20 02:54 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 11/18/20 02:54 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 11/18/20 02:54 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 11/18/20 02:54 75-00-3 Chloroform ND ug/L 5.0 2.3 1 11/18/20 02:54 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 11/18/20 02:54 74-87-3 v2 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 11/18/20 02:54 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 11/18/20 02:54 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 11/18/20 02:54 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 11/18/20 02:54 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 11/18/20 02:54 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 11/18/20 02:54 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 11/18/20 02:54 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 11/18/20 02:54 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 11/18/20 02:54 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 11/18/20 02:54 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.29 1 11/18/20 02:54 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.25 1 11/18/20 02:54 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.19 1 11/18/20 02:54 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Foothills Landfill 11/16 Pace Project No.: 92506305 Sample: PIW-2 Lab ID: 92506305004 Collected: 11/16/20 10:20 Received: 11/16/20 13:34 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Analytical Method: EPA 8260D Pace Analytical Services - Charlotte cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 11/18/20 02:54 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 11/18/20 02:54 10061-02-6 Ethylbenzene ND ug/L 1.0 0.26 1 11/18/20 02:54 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 11/18/20 02:54 591-78-6 lodomethane ND ug/L 20.0 12.5 1 11/18/20 02:54 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 11/18/20 02:54 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 11/18/20 02:54 108-10-1 Styrene ND ug/L 1.0 0.27 1 11/18/20 02:54 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 11/18/20 02:54 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 11/18/20 02:54 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 11/18/20 02:54 127-18-4 Toluene ND ug/L 1.0 0.24 1 11/18/20 02:54 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 11/18/20 02:54 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 11/18/20 02:54 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 11/18/20 02:54 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 11/18/20 02:54 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 11/18/20 02:54 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 11/18/20 02:54 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 11/18/20 02:54 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 11/18/20 02:54 1330-20-7 m&p-Xylene ND ug/L 2.0 0.41 1 11/18/20 02:54 179601-23-1 o-Xylene ND ug/L 1.0 0.22 1 11/18/20 02:54 95-47-6 Surrogates 4-Bromofluorobenzene (S) 94 % 70-130 1 11/18/20 02:54 460-00-4 1,2-Dichloroethane-d4 (S) 97 % 70-130 1 11/18/20 02:54 17060-07-0 Toluene-d8 (S) 98 % 70-130 1 11/18/20 02:54 2037-26-5 9040 pH Analytical Method: EPA 9040C Pace Analytical Services -Asheville pH at 25 Degrees C 6.7 Std. Units 0.10 0.10 1 11/17/20 16:27 H3 300.0 IC anions 48hr Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Nitrate as N 0.072J mg/L 0.10 0.060 1 11/17/20 12:20 14797-55-8 Nitrate -Nitrite (as N) ND mg/L 0.20 0.11 1 11/17/20 12:20 7727-37-9 Nitrite as N ND mg/L 0.10 0.050 1 11/17/20 12:20 14797-65-0 Sulfate 1.8 mg/L 1.0 0.50 1 11/17/20 12:20 14808-79-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 0.049J mg/L 0.050 0.025 1 11/17/20 18:38 11/17/20 21:29 7723-14-0 Date: 12/02/2020 10:38 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/16 Pace Project No.: 92506305 QC Batch: 580794 Analysis Method: EPA 6010D QC Batch Method: EPA 3050E Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92506305001, 92506305002 METHOD BLANK: 3071944 Associated Lab Samples: 92506305001, 92506305002 Parameter Units Matrix: Blank Result Solid Reporting Limit MDL Analyzed Antimony mg/kg ND 0.50 0.39 11/18/20 01:10 Arsenic mg/kg ND 1.0 0.50 11/18/20 01:10 Barium mg/kg ND 0.50 0.25 11/18/20 01:10 Beryllium mg/kg ND 0.10 0.050 11/18/20 01:10 Cadmium mg/kg 0.055J 0.10 0.050 11/18/20 01:10 Chromium mg/kg ND 0.50 0.25 11/18/2012:28 Cobalt mg/kg ND 0.50 0.25 11/18/20 01:10 Copper mg/kg ND 0.50 0.25 11/18/20 01:10 Lead mg/kg ND 0.50 0.25 11/18/20 01:10 Nickel mg/kg ND 0.50 0.25 11/18/20 01:10 Selenium mg/kg ND 1.0 0.50 11/18/20 01:10 Silver mg/kg ND 0.50 0.25 11/18/20 01:10 Thallium mg/kg ND 1.0 0.50 11/18/20 01:10 Vanadium mg/kg ND 0.50 0.25 11/18/20 01:10 Zinc mg/kg ND 1.0 0.50 11/18/20 01:10 LABORATORY CONTROL SAMPLE: Parameter 3071945 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony mg/kg 25 23.3 93 80-120 Arsenic mg/kg 25 23.2 93 80-120 Barium mg/kg 25 24.8 99 80-120 Beryllium mg/kg 25 24.4 98 80-120 Cadmium mg/kg 25 23.4 94 80-120 Chromium mg/kg 25 22.5 90 80-120 Cobalt mg/kg 25 24.5 98 80-120 Copper mg/kg 25 24.8 99 80-120 Lead mg/kg 25 23.9 96 80-120 Nickel mg/kg 25 24.4 98 80-120 Selenium mg/kg 25 22.7 91 80-120 Silver mg/kg 12.5 11.6 93 80-120 Thallium mg/kg 25 24.3 97 80-120 Vanadium mg/kg 25 24.1 96 80-120 Zinc mg/kg 25 22.7 91 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Pace Project No.: Foothills Landfill 11/16 92506305 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3071946 3071947 MS MSD 92505819006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg 0.66 24.1 24.1 8.5 8.9 33 34 75-125 4 20 M1 Arsenic mg/kg 1.7 24.1 24.1 23.5 23.1 91 89 75-125 2 20 Barium mg/kg 16.8 24.1 24.1 43.9 43.8 112 112 75-125 0 20 Beryllium mg/kg ND 24.1 24.1 23.2 23.3 96 96 75-125 1 20 Cadmium mg/kg ND 24.1 24.1 22.4 22.1 93 91 75-125 1 20 Chromium mg/kg 8.3 24.1 24.1 32.9 34.8 102 110 75-125 6 20 Cobalt mg/kg 0.55 24.1 24.1 22.3 22.9 90 93 75-125 3 20 Copper mg/kg 2.8 24.1 24.1 29.5 27.2 110 101 75-125 8 20 Lead mg/kg 4.5 24.1 24.1 25.8 26.9 88 93 75-125 4 20 Nickel mg/kg 1.9 24.1 24.1 24.4 24.8 94 95 75-125 2 20 Selenium mg/kg ND 24.1 24.1 21.3 20.8 86 84 75-125 2 20 Silver mg/kg ND 12 12 11.5 11.3 95 94 75-125 2 20 Thallium mg/kg ND 24.1 24.1 20.9 21.3 87 89 75-125 2 20 Vanadium mg/kg 13.1 24.1 24.1 38.8 40.5 107 114 75-125 4 20 Zinc mg/kg 22.7 24.1 24.1 65.5 43.9 178 88 75-125 39 20 M1,R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/16 Pace Project No.: 92506305 QC Batch: 580734 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92506305004 METHOD BLANK: 3071812 Associated Lab Samples: 92506305004 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers Antimony ug/L ND 5.0 3.0 11/17/20 22:10 Arsenic ug/L ND 10.0 4.7 11/17/20 22:10 Barium ug/L ND 5.0 3.5 11/17/20 22:10 Beryllium ug/L ND 1.0 0.70 11/17/20 22:10 Cadmium ug/L 0.65J 1.0 0.40 11/17/20 22:10 BC Chromium ug/L ND 5.0 3.7 11/17/20 22:10 Cobalt ug/L ND 5.0 3.6 11/17/20 22:10 Copper ug/L ND 5.0 4.3 11/17/20 22:10 Lead ug/L ND 5.0 4.5 11/17/20 22:10 Nickel ug/L ND 5.0 3.5 11/17/20 22:10 Selenium ug/L ND 10.0 4.7 11/17/20 22:10 Silver ug/L ND 5.0 2.5 11/17/20 22:10 Thallium ug/L ND 10.0 8.1 11/17/20 22:10 Vanadium ug/L ND 5.0 3.9 11/17/20 22:10 Zinc ug/L ND 10.0 9.5 11/17/20 22:10 LABORATORY CONTROL SAMPLE: Parameter 3071813 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 500 477 95 80-120 Arsenic ug/L 500 474 95 80-120 Barium ug/L 500 477 95 80-120 Beryllium ug/L 500 486 97 80-120 Cadmium ug/L 500 473 95 80-120 Chromium ug/L 500 479 96 80-120 Cobalt ug/L 500 479 96 80-120 Copper ug/L 500 496 99 80-120 Lead ug/L 500 480 96 80-120 Nickel ug/L 500 478 96 80-120 Selenium ug/L 500 471 94 80-120 Silver ug/L 250 240 96 80-120 Thallium ug/L 500 475 95 80-120 Vanadium ug/L 500 478 96 80-120 Zinc ug/L 500 462 92 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/16 Pace Project No.: 92506305 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3071814 3071815 MS MSD 92506305003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L 181 186 2 20 M1 Arsenic ug/L 235 241 3 20 Barium ug/L 443 444 0 20 Beryllium ug/L 248 250 1 20 Cadmium ug/L 240 240 0 20 Chromium ug/L 273 271 1 20 Cobalt ug/L 250 251 0 20 Copper ug/L 295 292 1 20 Lead ug/L 272 272 0 20 Nickel ug/L 253 254 0 20 Selenium ug/L 232 229 1 20 Silver ug/L 120 120 0 20 Thallium ug/L 233 232 0 20 Vanadium ug/L 334 331 1 20 Zinc ug/L 295 286 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/16 Pace Project No.: 92506305 QC Batch: 580983 Analysis Method: EPA 8260D QC Batch Method: EPA 5035A/5030B Analysis Description: 8260D 5035A 5030E Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92506305001, 92506305002 METHOD BLANK: 3073028 Associated Lab Samples: 92506305001, 92506305002 Parameter Units Matrix: Blank Result Solid Reporting Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/kg ND 5.0 1.9 11/17/20 15:10 1,1,1-Trichloroethane ug/kg ND 5.0 2.6 11/17/20 15:10 1,1,2,2-Tetrachloroethane ug/kg ND 5.0 1.3 11/17/20 15:10 1,1,2-Trichloroethane ug/kg ND 5.0 1.7 11/17/20 15:10 1,1-Dichloroethane ug/kg ND 5.0 2.1 11/17/20 15:10 1,1-Dichloroethene ug/kg ND 5.0 2.1 11/17/20 15:10 1,2,3-Trichloropropane ug/kg ND 5.0 2.5 11/17/20 15:10 1,2-Dibromo-3-chloropropane ug/kg ND 5.0 1.9 11/17/20 15:10 1,2-Dibromoethane (EDB) ug/kg ND 5.0 2.2 11/17/20 15:10 1,2-Dichlorobenzene ug/kg ND 5.0 1.8 11/17/20 15:10 1,2-Dichloroethane ug/kg ND 5.0 3.3 11/17/20 15:10 1,4-Dichlorobenzene ug/kg ND 5.0 1.3 11/17/20 15:10 2-Butanone (MEK) ug/kg ND 100 24.0 11/17/20 15:10 2-Hexanone ug/kg ND 50.0 4.8 11/17/20 15:10 4-Methyl-2-pentanone (MIBK) ug/kg ND 50.0 4.8 11/17/20 15:10 Acetone ug/kg ND 100 32.1 11/17/20 15:10 Acrylonitrile ug/kg ND 100 17.4 11/17/20 15:10 Benzene ug/kg ND 5.0 2.0 11/17/20 15:10 Bromochloromethane ug/kg ND 5.0 1.5 11/17/20 15:10 Bromodichloromethane ug/kg ND 5.0 1.9 11/17/20 15:10 IK Bromoform ug/kg ND 5.0 1.8 11/17/20 15:10 Bromomethane ug/kg ND 10.0 7.9 11/17/20 15:10 v2 Carbon disulfide ug/kg ND 10.0 6.3 11/17/20 15:10 Carbon tetrachloride ug/kg ND 5.0 1.9 11/17/20 15:10 Chlorobenzene ug/kg ND 5.0 0.96 11/17/20 15:10 Chloroethane ug/kg ND 10.0 3.9 11/17/20 15:10 Chloroform ug/kg ND 5.0 3.0 11/17/20 15:10 Chloromethane ug/kg ND 10.0 4.2 11/17/20 15:10 v2 cis-1,2-Dichloroethene ug/kg ND 5.0 1.7 11/17/20 15:10 Dibromochloromethane ug/kg ND 5.0 2.8 11/17/20 15:10 Dibromomethane ug/kg ND 5.0 1.1 11/17/20 15:10 Ethylbenzene ug/kg ND 5.0 2.3 11/17/20 15:10 lodomethane ug/kg ND 50.0 42.0 11/17/20 15:10 m&p-Xylene ug/kg ND 10.0 3.4 11/17/20 15:10 o-Xylene ug/kg ND 5.0 2.2 11/17/20 15:10 Styrene ug/kg ND 5.0 1.3 11/17/20 15:10 Tetrachloroethene ug/kg ND 5.0 1.6 11/17/20 15:10 Toluene ug/kg ND 5.0 1.4 11/17/20 15:10 trans-1,2-Dichloroethene ug/kg ND 5.0 1.8 11/17/20 15:10 trans-1,4-Dichloro-2-butene ug/kg ND 10.0 3.7 11/17/20 15:10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 17 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/16 Pace Project No.: 92506305 METHOD BLANK: 3073028 Matrix: Solid Associated Lab Samples: 92506305001, 92506305002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Trichloroethene ug/kg ND 5.0 1.3 11/17/20 15:10 Trichlorofluoromethane ug/kg ND 5.0 2.8 11/17/20 15:10 Vinyl acetate ug/kg ND 50.0 3.6 11/17/20 15:10 Vinyl chloride ug/kg ND 10.0 2.5 11/17/20 15:10 Xylene (Total) ug/kg ND 10.0 2.8 11/17/20 15:10 1,2-Dichloroethane-d4 (S) % 100 70-130 11/17/20 15:10 4-Bromofluorobenzene (S) % 99 69-134 11/17/20 15:10 Toluene-d8 (S) % 100 70-130 11/17/20 15:10 LABORATORY CONTROL SAMPLE: Parameter 3073029 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/kg 1250 1010 81 70-130 1,1,1-Trichloroethane ug/kg 1250 1120 90 70-130 1,1,2,2-Tetrachloroethane ug/kg 1250 1010 81 70-130 1,1,2-Trichloroethane ug/kg 1250 1140 91 70-130 1,1-Dichloroethane ug/kg 1250 1020 81 70-130 1,1-Dichloroethene ug/kg 1250 1060 85 70-130 1,2,3-Trichloropropane ug/kg 1250 1030 82 70-130 1,2-Dibromo-3-chloropropane ug/kg 1250 1070 86 70-130 1,2-Dibromoethane (EDB) ug/kg 1250 1010 81 70-130 1,2-Dichlorobenzene ug/kg 1250 1060 84 70-130 1,2-Dichloroethane ug/kg 1250 1100 88 63-130 1,4-Dichlorobenzene ug/kg 1250 1060 85 70-130 2-Butanone (MEK) ug/kg 2500 2280 91 70-130 2-Hexanone ug/kg 2500 2200 88 70-130 4-Methyl-2-pentanone (MIBK) ug/kg 2500 2160 86 70-130 Acetone ug/kg 2500 2370 95 69-130 Acrylonitrile ug/kg 6250 5590 89 70-130 Benzene ug/kg 1250 980 78 70-130 Bromochloromethane ug/kg 1250 1140 91 70-130 Bromodichloromethane ug/kg 1250 1060 85 69-130lK Bromoform ug/kg 1250 1050 84 70-130 Bromomethane ug/kg 1250 1580 126 52-130 v3 Carbon disulfide ug/kg 1250 1110 89 67-130 Carbon tetrachloride ug/kg 1250 979 78 70-130 Chlorobenzene ug/kg 1250 1050 84 70-130 Chloroethane ug/kg 1250 1080 87 65-130 Chloroform ug/kg 1250 996 80 70-130 Chloromethane ug/kg 1250 939 75 55-130 v3 cis-1,2-Dichloroethene ug/kg 1250 1010 81 70-130 Dibromochloromethane ug/kg 1250 1050 84 70-130 Dibromomethane ug/kg 1250 1080 87 70-130 Ethylbenzene ug/kg 1250 1180 95 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 18 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/16 Pace Project No.: 92506305 LABORATORY CONTROL SAMPLE: 3073029 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers lodomethane ug/kg 2500 2500 100 70-130 m&p-Xylene ug/kg 2500 2030 81 70-130 o-Xylene ug/kg 1250 1020 82 70-130 Styrene ug/kg 1250 1040 83 70-130 Tetrachloroethene ug/kg 1250 1050 84 70-130 Toluene ug/kg 1250 983 79 70-130 trans-1,2-Dichloroethene ug/kg 1250 1030 82 70-130 trans-1,4-Dichloro-2-butene ug/kg 1250 1340 107 70-130 Trichloroethene ug/kg 1250 1030 82 70-130 Trichlorofluoromethane ug/kg 1250 1040 83 70-130 Vinyl acetate ug/kg 2500 2350 94 70-130 Vinyl chloride ug/kg 1250 1030 82 61-130 Xylene (Total) ug/kg 3750 3050 81 70-130 1,2-Dichloroethane-d4 (S) % 96 70-130 4-Bromofluorobenzene (S) % 98 69-134 Toluene-d8 (S) % 100 70-130 MATRIX SPIKE SAMPLE: 3073031 92506305002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/kg ND 806 779 97 70-131 1,1,1-Trichloroethane ug/kg ND 806 836 104 65-133 1,1,2,2-Tetrachloroethane ug/kg ND 806 798 99 66-130 1,1,2-Trichloroethane ug/kg ND 806 894 111 66-133 1,1-Dichloroethane ug/kg ND 806 773 96 65-130 1,1-Dichloroethene ug/kg ND 806 722 90 10-158 1,2,3-Trichloropropane ug/kg ND 806 791 98 67-130 1,2-Dibromo-3-chloropropane ug/kg ND 806 757 94 32-130 1,2-Dibromoethane (EDB) ug/kg ND 806 789 98 70-130 1,2-Dichlorobenzene ug/kg ND 806 841 104 69-130 1,2-Dichloroethane ug/kg ND 806 845 105 59-130 1,4-Dichlorobenzene ug/kg ND 806 837 104 68-130 2-Butanone (MEK) ug/kg ND 1620 1510 94 10-136 2-Hexanone ug/kg ND 1620 1620 100 10-144 4-Methyl-2-pentanone (MIBK) ug/kg ND 1620 1640 102 25-143 Acetone ug/kg ND 1620 1390 86 10-130 Acrylonitrile ug/kg ND 4030 4140 103 70-130 Benzene ug/kg ND 806 788 98 67-130 Bromochloromethane ug/kg ND 806 875 108 69-134 Bromodichloromethane ug/kg ND 806 802 99 64-1301K Bromoform ug/kg ND 806 729 90 62-130 Bromomethane ug/kg ND 806 650 81 20-176 v3 Carbon disulfide ug/kg ND 806 762 94 42-130 Carbon tetrachloride ug/kg ND 806 733 91 65-140 Chlorobenzene ug/kg ND 806 827 103 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 19 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Foothills Landfill 11/16 Pace Project No.: 92506305 MATRIX SPIKE SAMPLE: 3073031 Parameter Units Chloroethane ug/kg Chloroform ug/kg Chloromethane ug/kg cis-1,2-Dichloroethene ug/kg Dibromochloromethane ug/kg Dibromomethane ug/kg Ethylbenzene ug/kg lodomethane ug/kg m&p-Xylene ug/kg o-Xylene ug/kg Styrene ug/kg Tetrachloroethene ug/kg Toluene ug/kg trans-1,2-Dichloroethene ug/kg trans-1,4-Dichloro-2-butene ug/kg Trichloroethene ug/kg Trichlorofluoromethane ug/kg Vinyl acetate ug/kg Vinyl chloride ug/kg Xylene (Total) ug/kg 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % !1T1�•AI;11!4:8Big] Z!IWTAr c�erLdexIel Parameter Units 1,1,1,2-Tetrachloroethane ug/kg 1,1,1-Trichloroethane ug/kg 1,1,2,2-Tetrachloroethane ug/kg 1,1,2-Trichloroethane ug/kg 1,1-Dichloroethane ug/kg 1,1-Dichloroethene ug/kg 1,2,3-Trichloropropane ug/kg 1,2-Dibromo-3-chloropropane ug/kg 1,2-Dibromoethane (EDB) ug/kg 1,2-Dichlorobenzene ug/kg 1,2-Dichloroethane ug/kg 1,4-Dichlorobenzene ug/kg 2-Butanone (MEK) ug/kg 2-Hexanone ug/kg 4-Methyl-2-pentanone (MIBK) ug/kg Acetone ug/kg Acrylonitrile ug/kg Benzene ug/kg QUALITY CONTROL DATA 92506305002 Result Spike Conc. MS Result ND 806 31.9 ND 806 776 ND 806 820 ND 806 788 ND 806 745 ND 806 818 ND 806 959 ND 1620 919 ND 1620 1640 ND 806 816 ND 806 826 ND 806 821 ND 806 794 ND 806 773 ND 806 555 ND 806 804 ND 806 207 ND 1620 1590 ND 806 824 ND 2410 2450 92506305001 Dup Result Result RPD MS % Rec % Rec Limits Qualifiers 4 10-130 M1 96 63-130 102 58-130 v3 98 66-130 92 67-130 101 63-131 119 66-130 57 70-130 M1 101 60-133 101 66-133 102 70-132 102 70-135 98 67-130 96 69-130 69 70-130 M1 100 70-135 26 10-130 99 53-130 102 61-148 101 63-132 117 70-130 102 69-134 100 70-130 Max RPD Qualifiers ND ND 30 ND ND 30 ND ND 30 ND ND 30 ND ND 30 ND ND 30 ND ND 30 ND ND 30 ND ND 30 ND ND 30 ND ND 30 ND ND 30 ND ND 30 ND ND 30 ND ND 30 ND ND 30 ND ND 30 3.2J 3.5J 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 20 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/16 Pace Project No.: 92506305 SAMPLE DUPLICATE: 3073030 Parameter Units 92506305001 Result Dup Result Bromochloromethane ug/kg ND ND Bromodichloromethane ug/kg ND ND Bromoform ug/kg ND ND Bromomethane ug/kg ND ND Carbon disulfide ug/kg ND ND Carbon tetrachloride ug/kg ND ND Chlorobenzene ug/kg ND ND Chloroethane ug/kg ND ND Chloroform ug/kg ND ND Chloromethane ug/kg ND ND cis-1,2-Dichloroethene ug/kg ND ND Dibromochloromethane ug/kg ND ND Dibromomethane ug/kg ND ND Ethylbenzene ug/kg ND ND lodomethane ug/kg ND ND m&p-Xylene ug/kg ND ND o-Xylene ug/kg ND ND Styrene ug/kg ND ND Tetrachloroethene ug/kg ND ND Toluene ug/kg 7.1 6.2J trans-1,2-Dichloroethene ug/kg ND ND trans-1,4-Dichloro-2-butene ug/kg ND ND Trichloroethene ug/kg ND ND Trichlorofluoromethane ug/kg ND ND Vinyl acetate ug/kg ND ND Vinyl chloride ug/kg ND ND Xylene (Total) ug/kg ND ND 1,2-Dichloroethane-d4 (S) % 100 99 4-Bromofluorobenzene (S) % 99 100 Toluene-d8 (S) % 99 99 Max RPD RPD Qualifiers 30 30 I K 30 30 v2 30 30 30 30 30 30 v2 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 21 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/16 Pace Project No.: 92506305 QC Batch: 580874 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92506305004 METHOD BLANK: 3072426 Associated Lab Samples: 92506305004 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 11/18/20 00:13 1,1,1-Trichloroethane ug/L ND 1.0 0.18 11/18/20 00:13 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 11/18/20 00:13 1,1,2-Trichloroethane ug/L ND 1.0 0.24 11/18/20 00:13 1,1-Dichloroethane ug/L ND 1.0 0.27 11/18/20 00:13 1,1-Dichloroethene ug/L ND 1.0 0.24 11/18/20 00:13 1,2,3-Trichloropropane ug/L ND 1.0 0.35 11/18/20 00:13 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 11/18/20 00:13 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 11/18/20 00:13 1,2-Dichlorobenzene ug/L ND 1.0 0.29 11/18/20 00:13 1,2-Dichloroethane ug/L ND 1.0 0.34 11/18/20 00:13 1,2-Dichloropropane ug/L ND 1.0 0.19 11/18/20 00:13 1,4-Dichlorobenzene ug/L ND 1.0 0.26 11/18/20 00:13 2-Butanone (MEK) ug/L ND 5.0 3.3 11/18/20 00:13 2-Hexanone ug/L ND 5.0 0.57 11/18/20 00:13 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 11/18/20 00:13 Acetone ug/L ND 25.0 6.2 11/18/20 00:13 Acrylonitrile ug/L ND 10.0 0.90 11/18/20 00:13 Benzene ug/L ND 1.0 0.15 11/18/20 00:13 Bromochloromethane ug/L ND 1.0 0.34 11/18/20 00:13 Bromodichloromethane ug/L ND 1.0 0.26 11/18/20 00:13 Bromoform ug/L ND 1.0 0.62 11/18/20 00:13 Bromomethane ug/L ND 2.0 0.62 11/18/20 00:13 Carbon disulfide ug/L ND 2.0 0.40 11/18/20 00:13 Carbon tetrachloride ug/L ND 1.0 0.22 11/18/20 00:13 Chlorobenzene ug/L ND 1.0 0.23 11/18/20 00:13 Chloroethane ug/L ND 1.0 0.49 11/18/20 00:13 Chloroform ug/L ND 5.0 2.3 11/18/20 00:13 Chloromethane ug/L ND 1.0 0.39 11/18/20 00:13 v2 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 11/18/20 00:13 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 11/18/20 00:13 Dibromochloromethane ug/L ND 1.0 0.41 11/18/20 00:13 Dibromomethane ug/L ND 1.0 0.46 11/18/20 00:13 Ethylbenzene ug/L ND 1.0 0.26 11/18/20 00:13 lodomethane ug/L ND 20.0 12.5 11/18/20 00:13 m&p-Xylene ug/L ND 2.0 0.41 11/18/20 00:13 Methylene Chloride ug/L ND 5.0 3.7 11/18/20 00:13 o-Xylene ug/L ND 1.0 0.22 11/18/20 00:13 Styrene ug/L ND 1.0 0.27 11/18/20 00:13 Tetrachloroethene ug/L ND 1.0 0.16 11/18/20 00:13 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 22 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/16 Pace Project No.: 92506305 METHOD BLANK: 3072426 Associated Lab Samples: 92506305004 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Toluene ug/L ND 1.0 0.24 11/18/20 00:13 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 11/18/20 00:13 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 11/18/20 00:13 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 11/18/20 00:13 Trichloroethene ug/L ND 1.0 0.22 11/18/20 00:13 Trichlorofluoromethane ug/L ND 1.0 0.31 11/18/20 00:13 Vinyl acetate ug/L ND 2.0 1.4 11/18/20 00:13 Vinyl chloride ug/L ND 1.0 0.24 11/18/20 00:13 Xylene (Total) ug/L ND 1.0 0.63 11/18/20 00:13 1,2-Dichloroethane-d4 (S) % 97 70-130 11/18/20 00:13 4-Bromofluorobenzene (S) % 94 70-130 11/18/20 00:13 Toluene-d8 (S) % 98 70-130 11/18/20 00:13 LABORATORY CONTROL SAMPLE: Parameter 3072427 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 52.8 106 70-130 1,1,1-Trichloroethane ug/L 50 47.3 95 70-130 1,1,2,2-Tetrachloroethane ug/L 50 48.4 97 70-130 1,1,2-Trichloroethane ug/L 50 48.7 97 70-130 1,1-Dichloroethane ug/L 50 45.0 90 70-130 1,1-Dichloroethene ug/L 50 48.8 98 70-132 1,2,3-Trichloropropane ug/L 50 48.3 97 70-130 1,2-Dibromo-3-chloropropane ug/L 50 54.8 110 70-132 1,2-Dibromoethane (EDB) ug/L 50 52.3 105 70-130 1,2-Dichlorobenzene ug/L 50 53.2 106 70-130 1,2-Dichloroethane ug/L 50 45.0 90 70-130 1,2-Dichloropropane ug/L 50 46.9 94 70-130 1,4-Dichlorobenzene ug/L 50 54.2 108 70-130 2-Butanone (MEK) ug/L 100 87.2 87 70-133 2-Hexanone ug/L 100 98.4 98 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 93.9 94 70-130 Acetone ug/L 100 92.6 93 70-144 Acrylonitrile ug/L 250 233 93 70-130 Benzene ug/L 50 47.4 95 70-130 Bromochloromethane ug/L 50 47.1 94 70-130 Bromodichloromethane ug/L 50 48.2 96 70-130 Bromoform ug/L 50 50.8 102 70-131 Bromomethane ug/L 50 56.3 113 30-177 Carbon disulfide ug/L 50 47.9 96 70-133 Carbon tetrachloride ug/L 50 50.2 100 70-130 Chlorobenzene ug/L 50 50.8 102 70-130 Chloroethane ug/L 50 37.6 75 46-131 Chloroform ug/L 50 46.3 93 70-130 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 23 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/16 Pace Project No.: 92506305 LABORATORY CONTROL SAMPLE: Parameter 3072427 Units Spike Conc. LCS LCS Result % Rec Chloromethane ug/L 50 37.6 cis-1,2-Dichloroethene ug/L 50 45.1 cis-1,3-Dichloropropene ug/L 50 49.9 Dibromochloromethane ug/L 50 53.7 Dibromomethane ug/L 50 52.1 Ethylbenzene ug/L 50 49.4 lodomethane ug/L 100 106 m&p-Xylene ug/L 100 101 Methylene Chloride ug/L 50 41.8 o-Xylene ug/L 50 50.7 Styrene ug/L 50 51.1 Tetrachloroethene ug/L 50 52.0 Toluene ug/L 50 47.4 trans-1,2-Dichloroethene ug/L 50 45.9 trans- 1,3-Dichloropropene ug/L 50 49.4 trans-1,4-Dichloro-2-butene ug/L 50 51.1 Trichloroethene ug/L 50 50.1 Trichlorofluoromethane ug/L 50 41.9 Vinyl acetate ug/L 100 101 Vinyl chloride ug/L 50 37.9 Xylene (Total) ug/L 150 152 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % % Rec Limits Qualifiers 75 49-130 v3 90 70-130 100 70-130 107 70-130 104 70-130 99 70-130 106 47-140 101 70-130 84 68-130 101 70-130 102 70-130 104 70-130 95 70-130 92 70-130 99 70-130 102 25-200 100 70-130 84 61-130 101 70-140 76 59-142 101 70-130 94 70-130 99 70-130 98 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3072428 MS 92506172024 Spike Parameter Units Result Conc. MSD Spike Conc. 3072429 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 2000 2000 2080 2090 104 105 70-135 1 30 1,1,1-Trichloroethane ug/L ND 2000 2000 2340 2400 117 120 70-148 2 30 1,1,2,2-Tetrachloroethane ug/L ND 2000 2000 1830 1870 91 94 70-131 2 30 1,1,2-Trichloroethane ug/L ND 2000 2000 1890 1890 95 94 70-136 0 30 1,1-Dichloroethane ug/L ND 2000 2000 1890 1880 94 94 70-147 0 30 1,1-Dichloroethene ug/L ND 2000 2000 2340 2340 117 117 70-158 0 30 1,2,3-Trichloropropane ug/L ND 2000 2000 1870 1870 93 93 67-137 0 30 1,2-Dibromo-3- ug/L ND 2000 2000 1990 2040 99 102 69-136 3 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 2000 2000 2010 2040 101 102 70-137 1 30 1,2-Dichlorobenzene ug/L ND 2000 2000 2050 2100 103 105 70-133 2 30 1,2-Dichloroethane ug/L ND 2000 2000 1820 1850 91 92 67-138 2 30 1,2-Dichloropropane ug/L ND 2000 2000 1880 1940 94 97 70-138 3 30 1,4-Dichlorobenzene ug/L ND 2000 2000 2070 2170 104 108 70-133 5 30 2-Butanone (MEK) ug/L ND 4000 4000 3230 3270 81 82 61-147 1 30 2-Hexanone ug/L ND 4000 4000 3620 3610 91 90 67-139 0 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 24 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/16 Pace Project No.: 92506305 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3072428 3072429 MS MSD 92506172024 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 4-Methyl-2-pentanone ug/L ND 4000 4000 3490 3500 87 88 67-136 0 30 (MIBK) Acetone ug/L ND 4000 4000 3430 4000 86 100 55-159 15 30 Acrylonitrile ug/L ND 10000 10000 8940 8700 89 87 68-140 3 30 Benzene ug/L ND 2000 2000 1930 1990 97 99 67-150 3 30 Bromochloromethane ug/L ND 2000 2000 1820 1850 91 93 70-146 2 30 Bromodichloromethane ug/L ND 2000 2000 1880 1920 94 96 70-138 3 30 Bromoform ug/L ND 2000 2000 1850 1830 93 92 57-138 1 30 Bromomethane ug/L ND 2000 2000 2470 2590 123 129 10-200 5 30 Carbon disulfide ug/L ND 2000 2000 1990 2060 100 103 70-152 3 30 Carbon tetrachloride ug/L ND 2000 2000 2100 2160 105 108 70-147 3 30 Chlorobenzene ug/L ND 2000 2000 2010 2070 101 103 70-137 2 30 Chloroethane ug/L ND 2000 2000 1870 1870 93 93 51-166 0 30 Chloroform ug/L ND 2000 2000 1960 1980 98 99 70-144 1 30 Chloromethane ug/L ND 2000 2000 1570 1620 78 81 24-161 3 30 v3 cis-1,2-Dichloroethene ug/L ND 2000 2000 1840 1850 92 93 67-148 0 30 cis-1,3-Dichloropropene ug/L ND 2000 2000 1830 1890 92 94 70-142 3 30 Dibromochloromethane ug/L ND 2000 2000 2010 2070 100 103 68-138 3 30 Dibromomethane ug/L ND 2000 2000 2000 2100 100 105 70-134 5 30 Ethylbenzene ug/L ND 2000 2000 2020 2050 101 102 68-143 1 30 lodomethane ug/L ND 4000 4000 3880 4150 97 104 20-161 7 30 m&p-Xylene ug/L ND 4000 4000 4070 4170 102 104 53-157 2 30 Methylene Chloride ug/L ND 2000 2000 1810 1830 91 92 64-148 1 30 o-Xylene ug/L ND 2000 2000 2030 2030 102 101 68-143 0 30 Styrene ug/L ND 2000 2000 1980 2000 99 100 70-136 1 30 Tetrachloroethene ug/L 193 2000 2000 2280 2340 104 107 70-139 3 30 Toluene ug/L ND 2000 2000 1940 1970 97 99 47-157 2 30 trans-1,2-Dichloroethene ug/L ND 2000 2000 1840 1950 92 97 70-149 5 30 trans-1,3-Dichloropropene ug/L ND 2000 2000 1790 1850 90 93 70-138 3 30 trans-1,4-Dichloro-2-butene ug/L ND 2000 2000 1580 1490 79 74 31-145 6 30 Trichloroethene ug/L 14100 2000 2000 16300 16600 110 123 70-149 2 30 Trichlorofluoromethane ug/L ND 2000 2000 1990 2030 99 101 61-154 2 30 Vinyl acetate ug/L ND 4000 4000 3810 3870 95 97 48-156 2 30 Vinyl chloride ug/L ND 2000 2000 1660 1730 83 86 55-172 4 30 Xylene (Total) ug/L ND 6000 6000 6100 6200 102 103 66-145 2 30 1,2-Dichloroethane-d4 (S) % 95 98 70-130 4-Bromofluorobenzene (S) % 97 95 70-130 Toluene-d8 (S) % 96 96 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 25 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/16 Pace Project No.: 92506305 QC Batch: 580942 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92506305001, 92506305002 SAMPLE DUPLICATE: 3072776 Parameter Percent Moisture SAMPLE DUPLICATE: 3072777 Parameter Percent Moisture 92506305001 Dup Units Result Result 18.7 18.9 92506241010 Dup Units Result Result % 33.4 35.9 Max RPD RPD Qualifiers 1 25 Max RPD RPD Qualifiers 7 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 26 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/16 Pace Project No.: 92506305 QC Batch: 1579055 Analysis Method: SM 2540G QC Batch Method: SM 2540 G Analysis Description: Total Solids 2540 G-2011 Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92506305001, 92506305002 METHOD BLANK: R3595360-1 Matrix: Solid Associated Lab Samples: 92506305001, 92506305002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Solids % ND 11/20/20 01:00 LABORATORY CONTROL SAMPLE: R3595360-2 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Solids % 50.0 50.0 100 85.0-115 SAMPLE DUPLICATE: R3595360-3 L1287162-01 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Solids % 81.0 81.0 0.0441 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 27 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/16 Pace Project No.: 92506305 QC Batch: 1579697 Analysis Method: EPA 9056A QC Batch Method: 9056 Analysis Description: Wet Chemistry 9056A Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92506305001, 92506305002 METHOD BLANK: R3595665-1 Matrix: Solid Associated Lab Samples: 92506305001, 92506305002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfate mg/kg ND 50.0 12.9 11/20/2011:37 LABORATORY CONTROL SAMPLE: R3595665-2 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/kg 200 192 95.9 80.0-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 28 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/16 Pace Project No.: 92506305 QC Batch: 580848 Analysis Method: EPA 9040C QC Batch Method: EPA 9040C Analysis Description: 9040 pH Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92506305004 SAMPLE DUPLICATE: 3072281 92506169002 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 0.86 0.84 2 9 E,H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 29 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/16 Pace Project No.: 92506305 QC Batch: 580849 Analysis Method: EPA 9045D QC Batch Method: EPA 9045D Analysis Description: 9045 pH Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92506305001, 92506305002 SAMPLE DUPLICATE: 3072288 92506305002 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.0 5.9 1 10 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 30 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/16 Pace Project No.: 92506305 QC Batch: 580768 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92506305004 METHOD BLANK: 3071876 Matrix: Water Associated Lab Samples: 92506305004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrate as N mg/L ND 0.10 0.060 11/17/20 11:37 Nitrate -Nitrite (as N) mg/L ND 0.20 0.11 11/17/20 11:37 Nitrite as N mg/L ND 0.10 0.050 11/17/20 11:37 Sulfate mg/L ND 1.0 0.50 11/17/20 11:37 LABORATORY CONTROL SAMPLE: 3071877 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/L 2.5 2.3 93 90-110 Nitrate -Nitrite (as N) mg/L 5 4.8 95 90-110 Nitrite as N mg/L 2.5 2.4 97 90-110 Sulfate mg/L 50 47.6 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3071878 3071879 MS MSD 92506305004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrate as N mg/L 0.072J 2.5 2.5 2.5 2.6 99 100 90-110 1 10 Nitrate -Nitrite (as N) mg/L ND 5 5 5.1 5.0 101 100 90-110 1 10 Nitrite as N mg/L ND 2.5 2.5 2.5 2.4 101 97 90-110 4 10 Sulfate mg/L 1.8 50 50 51.1 51.5 99 100 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 31 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/16 Pace Project No.: 92506305 QC Batch: 581059 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92506305001, 92506305002 METHOD BLANK: 3073424 Matrix: Solid Associated Lab Samples: 92506305001, 92506305002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Nitrate mg/kg ND 4.0 2.0 11/17/20 22:41 Nitrogen, Nitrite mg/kg ND 4.0 1.0 11/17/20 22:41 Nitrogen, NO2 plus NO3 mg/kg ND 4.0 2.0 11/17/20 22:41 LABORATORY CONTROL SAMPLE: 3073425 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/kg 15 15.3 102 90-110 Nitrogen, Nitrite mg/kg 10 10.0 100 90-110 Nitrogen, NO2 plus NO3 mg/kg 25 25.3 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3073426 3073427 MS MSD 92506305001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/kg ND 18.3 18.3 20.2 20.4 110 111 90-110 1 10 Nitrogen, Nitrite mg/kg ND 12.2 12.2 12.4 12.4 102 101 90-110 0 10 Nitrogen, NO2 plus NO3 mg/kg ND 30.5 30.5 32.6 32.7 104 104 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 32 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/16 Pace Project No.: 92506305 QC Batch: 580929 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92506305001, 92506305002 METHOD BLANK: 3072717 Matrix: Solid Associated Lab Samples: 92506305001, 92506305002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Phosphorus mg/kg ND 0.85 0.42 11/17/20 21:01 LABORATORY CONTROL SAMPLE: 3072718 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phosphorus mg/kg 50 49.0 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3072719 3072720 MS MSD 92504830001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phosphorus mg/kg 42100 2470 2570 45800 46400 147 166 90-110 1 10 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 33 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/16 Pace Project No.: 92506305 QC Batch: 580934 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92506305004 METHOD BLANK: 3072741 Associated Lab Samples: 92506305004 Parameter Units Phosphorus mg/L LABORATORY CONTROL SAMPLE: 3072742 Parameter Units Phosphorus mg/L Matrix: Water Blank Reporting Result Limit ND 0.050 Spike LCS Conc. Result 2.5 2.4 MDL Analyzed Qualifiers 0.025 11/17/20 21:09 LCS % Rec % Rec Limits Qualifiers 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3072743 3072744 MS MSD 92504849001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phosphorus mg/L ND 2.5 2.5 2.5 2.5 99 98 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3072745 3072746 MS MSD 92504865001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phosphorus mg/L 0.069 2.5 2.5 2.5 2.5 98 99 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 34 of 50 Pace Analytical Services, LLC leac,yficalAnal2225 Riverside Dr. Asheville, NC 28804 www.pacelabs.com (828)254-7176 QUALIFIERS Project: Foothills Landfill 11/16 Pace Project No.: 92506305 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS BC The same analyte was detected in an associated blank at a concentration above 1/2 the reporting limit but below the laboratory reporting limit. E Analyte concentration exceeded the calibration range. The reported result is estimated. H3 Sample was received or analysis requested beyond the recognized method holding time. IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. J Analyte detected below the reporting limit, therefore result is an estimate. This qualifier is also used for all TICs. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. R1 RPD value was outside control limits. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:38 AM without the written consent of Pace Analytical Services, LLC. Page 35 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Foothills Landfill 11/16 92506305 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92506305001 BGS1 (1) EPA 3050B 580794 EPA 6010D 580833 92506305002 DGS2 (1.5) EPA 3050B 580794 EPA 6010D 580833 92506305004 PIW-2 EPA 3010A 580734 EPA 6010D 580748 92506305001 BGS1 (1) EPA 5035A/5030B 580983 EPA 8260D 581019 92506305002 DGS2 (1.5) EPA 5035A/5030B 580983 EPA 8260D 581019 92506305004 PIW-2 EPA 8260D 580874 92506305001 BGS1 (1) ASTM D2974-87 580942 92506305002 DGS2 (1.5) ASTM D2974-87 580942 92506305001 BGS1 (1) SM 2540 G 1579055 SM 2540G 1579055 92506305002 DGS2 (1.5) SM 2540 G 1579055 SM 2540G 1579055 92506305001 BGS1 (1) 9056 1579697 EPA9056A 1579697 92506305002 DGS2 (1.5) 9056 1579697 EPA 9056A 1579697 92506305004 PIW-2 EPA 9040C 580848 92506305001 BGS1 (1) EPA9045D 580849 92506305002 DGS2 (1.5) EPA 9045D 580849 92506305004 PIW-2 EPA 300.0 Rev 2.1 1993 580768 92506305001 BGS1 (1) EPA 353.2 Rev 2.0 1993 581059 EPA 353.2 Rev 2.0 1993 581071 92506305002 DGS2 (1.5) EPA 353.2 Rev 2.0 1993 581059 EPA 353.2 Rev 2.0 1993 581071 92506305001 BGS1 (1) EPA 365.1 Rev 2.0 1993 580929 EPA 365.1 Rev 2.0 1993 581074 92506305002 DGS2 (1.5) EPA 365.1 Rev 2.0 1993 580929 EPA 365.1 Rev 2.0 1993 581074 92506305004 PIW-2 EPA 365.1 Rev 2.0 1993 580934 EPA 365.1 Rev 2.0 1993 581075 Date: 12/02/2020 10:38 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 36 of 50 Document Name: Document Revised: October 28, 2020 H Sample Condition Upon Receipt(SCUR) Page 1 of 2 ace Analytical Document No.: Issuing Authority: F-CAR-CS-033-Rev.07 Pace Carolinas Quality Office Laboratory receiving samples: Asheville,❑ Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑ Atlanta[ Kernersville❑ .Upon Client Name: project 1#: WN : 92506305 Courier; []Fed Ex 005 ❑USPS lent 111111111111111111111111111111❑ Commercial ❑Pace ❑Other: 92506305 Custody Seal Present? Oyes 'QNo Seals Intact? [:]Yes '0I o Date/Initials Person Examining Contents: _I�� Packing Material: ❑Bubble Wrap ,Bubble Bags None ❑ Other Biological Tissue Frozen? Thermometer/:. ❑Yes [—]No ❑N/A P-IR Gun ID: ❑V1et ❑81ue ❑None Type of Ice: Correction Factor: Cooler Temp: 5• y Add/Subtract (°C) 6 Temp Should be above freezing to 6°C ❑samples out of temp criteria. Samples on ice, cooling process Cooler Temp Corrected (°C}; �. V hasbegun USDA Regulated Soil (❑ N/A, water sample) Did samples orieinate in a ouarantine zone within the United States: CA. NY, or SC (check maps)? Did samples originate from a foreign source (internationally, ❑Yes Eho includingHawaii and Puerto Rico)? LJYes No Comments/Discrepancy: Chain of Custody Present? Yes []No ❑N/A 1. Samples Arrived within Hold Time? 6Yes ❑N/A 2• Short Hold Time Analysis (02 hr.)? ves [❑,NNoo [TJo ❑NIA 3. Nv Rush Turn Around Time Requested? Wyes ❑No ❑N/A 4. Sufficient Volume? ❑Yes LXo ❑N/A 5. Correct Containers Used? -Pace Containers Used? EYes _ es ❑No ❑No ❑NIA ❑N/A 6. Containers Intact? DY9 [-]No [—]N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes ❑No /A 8. Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix: Headspace in VOA ViAS (>5-6mm)? k]Yes Wit/ ❑Yes [—]No No []N/A ❑N/A 9. 10. Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes ❑Yes ❑No ❑No 'N/A /A 11. r COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Date/Time: field Data Required? [_]Yes []No Lot ID ofsaiit containers: Date: Date: Page 37 of 50 IA'2ceAnalXical' Document Name: Sample Condition Upon Recel Document No,: F-CAR-CS-033-Rev.07 *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples, Exceptions: VOA, Coliform, TOC, oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottles Document Revised: October 28, 2020 t(SCUR) Page 2 of 2 Issuing Authority: Pace Carolinas Quality Office Project # uc)# . 92,5®630 W CD1 Due Date: 11/18/20 CLIENT: 93—ODS QSHVL E E « a ❑. u d J E N a a m Z a 7 a E M d m ¢ Z C i J E N a m v C 4 ri a as y 2 O N a E n N r a m V vfO Z 2 p --1 E o N Z M a m o Q Z a E n N 1 N It a co ^ 4 0C Z a E h N U a a m @ ID a E LL v a d m = ei 7 l7 d N V U m i-t :G N l7 d a Z dl Z J E o N M U d N V O N S Q v v1 N W d w V 2 N 2 E J E o N N M l7 a U`Z-- a Z S Z d J o i ¢ m d M 0 d Q Z _L U d O > E S 0 W a Q Z M 0 in d O `> E O a N O I.D > \ Z a c d O > J E q Q, C7 > d ? c} m Q O > E O LL M l7 en y M O af y a N v le Q O > a N 2 d i a N m .M.. Y Q > Z N N ii v v J E n r i.1 Ln a 0 Z -•- ++ a v ^ J E o N >^ N 0. rn a O lJ1 N Z a E o 4 M 6. m N a E ¢ E a p l7 d `� O c n J E o = V' 7 Z > 7 41 v C U Q E 0 m d 1 7 t 2 3 i I t i G 4 I � 5 6 7 8 9 10 11 12 —LL pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot # Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNH LPMfication unite tI.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 38 of 50 CHAIN -OF -CUSTODY 1 Analytical Request Document ceAmil The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. NMM oACELIBS,CO. Section A Section B Section C Required Client Information: Required Project Information: Invoice information: Page: 1 Of 1 Company: FOOTHILLS ENV. LANDFILL Report To: GIBBONS, GEORGE Attention: Address: 2800 CHERAW ROAD Copy To, AV-' j!. t • Q � / x4,� a . , r.7 It i. !7 r 6, Company Name': LENOIR, NC 28645 Address: Reoulal Agency Email, Purchase Order #: Pace Quote: Phone' 8267270965 JFax Project Name: Foothills Landfill Pace Project Manager, Christopher_ derouen pacelabs.com, State r Location Requested Due Date: I j]cZ i .t1 Project /" I 9: , h':C � � r• Pace Profile#: 8303 Requested An lysis Filtered !N 2 MATRIX CODE 0 COLLECTED 2 Preservatives Dlinxi+g Warcl ow U g water WT v_ a Waste waltz WW Po°ua R SAMPLE ID s°ins°,° 6L s ;" d raj O_ START END U N m F y ` 1 a H = oil oL 2 r One Character per box. wipe WP w w a z v N m s` (A-Z, 0-9 1, -1 oen., oNr o '� m r• N Q .- m el,-+ Sample Ids must be unique Tiss°e Ts K O v c d m m LU a a 4 a 4 m c O rev Z N t O o h `m m o m 2 m H Q h l DATE TIME DATE TIME ac x z x z z m m rn m 012 (JS 3` 1 r li r fGss 35 3 2 � ✓ 6v; S1 4 -s 5 3 2 a [ � a j Aso iUN a s s 7 s 9 10 11 12 ADDITIONAL COMMENTS RELINQUISHED BY I AFFILIATION DATE TIME ACCEPTED 6Y l AFFILIATION .DATE. TIME SAMPLE CONDmONS SAMPLER NAME AND SIGNATURE c 9 0 PRINT Name of SAMPLER• CL ' _ O v N a SIGNATURE of SAMPLER' D TE 5j9ned: w m Z m uo u m 2 1 I C+ F- wy- 1-1 aceAnalytical o ANALYTICAL REPORT National Center for Testing & Innovation November 20, 2020 • #r Pace Analytical - Asheville, NC Sample Delivery Group: L1287182 Samples Received: 11/18/2020 Project Number: 92506305 Description: Foothills Landfill 11/16 Site: 001 Report To: Christopher Derouen 2225 Riverside Drive Asheville, NC 28804 Entire Report Reviewed By Christl M Wagner Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided, and as the samples are received. 4 V - 16 Page 40 of 50 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Asheville, NC 92506305 L1287182 11/20/20 23:55 1 of 11 TABLE OF CONTENTS ONE LAB. NATIONWIDE. Cp: Cover Page 1 Fn Tc: Table of Contents 2 Ss: Sample Summary 3 Cn: Case Narrative 4 Sr: Sample Results 5 FS BGS1 (1) L1287182-01 5 [Cn] DGS2 (1.5) L1287182-02 6 Qc: Quality Control Summary 7 Fr Total Solids by Method 2540 G-2011 7 Wet Chemistry by Method 9056A 8 RC Gl: Glossary of Terms 9 F Al: Accreditations & Locations 10 Sc: Sample Chain of Custody 11 rAl FSC Page 41 of 50 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Asheville, NC 92506305 L1287182 11/20/20 23:55 2 of 11 SAMPLE SUMMARY ONE LAB. NATIONWIDE. Collected by Collected date/time Received date/time BGS1 (1) L1287182-01 Solid 11/16/2010:55 11/18/2009:00 FP1 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time FTC Total Solids by Method 2540 G-2011 WG1579055 1 11/20/20 00:50 11/20/20 01:00 KBC Mt. Juliet, TN Wet Chemistry by Method 9056A WG1579697 1 11/20/20 09:50 11/20/2012:11 MCG Mt. Juliet, TN Collected by Collected date/time Received date/time DGS2 (1.5) L1287182-02 Solid 11/16/2009:45 11/18/2009:00 4 n Method Batch Dilution Preparation Analysis Analyst Location date/time FSrdate/time Total Solids by Method 2540 G-2011 WG1579055 1 11/20/20 00:50 11/20/20 01:00 KBC Mt. Juliet, TN Wet Chemistry by Method 9056A WG1579697 1 11/20/20 09:50 11/20/2012:28 MCG Mt. Juliet, TN RC F, FAI FSC Page 42 of 50 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Asheville, NC 92506305 L1287182 11/20/20 23:55 3 of 11 CASE NARRATIVE ONE LAB. NATIONWIDE. All sample aliquots were received at the correct temperature, in the proper containers, with the FP1 appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples FTChave been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my FSS knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. FSr 6 . QC �GI Christi M Wagner FAI Project Manager FSC Page 43 of 50 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Asheville, NC 92506305 L1287182 11/20/20 23:55 4 of 11 BGS1 (1) Collected date/time: 11/16/20 10:55 Total Solids by Method 2540 G-2011 SAMPLE RESULTS - 01 L1287182 Result Qualifier Dilution Analysis Batch Analyte % date / time Total Solids 82.7 1 11/20/2020 01:00 WG1579055 Wet Chemistry by Method 9056A Result Analyte mg/kg Sulfate J Qualifier MDL RDL Dilution Analysis Batch — mg/kg mg/kg date / time 12.9 50.0 1 11/20/202012:11 WG1579697 ONE LAB. NATIONWIDE. Fp] FTC FSS 4 Cn FC 7G1 FAI FSC Page 44 of 50 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Asheville, NC 92506305 L1287182 11/20/20 23:55 5 of 11 DGS2 (1.5) Collected date/time: 11/16/20 09:45 Total Solids by Method 2540 G-2011 SAMPLE RESULTS - 02 L1287182 Result Qualifier Dilution Analysis Batch Analyte % date / time Total Solids 76.3 1 11/20/2020 01:00 WG1579055 Wet Chemistry by Method 9056A Result Analyte mg/kg Sulfate 34.1 Qualifier MDL RDL mg/kg mg/kg J 12.9 50.0 Dilution Analysis Batch date / time 1 11/20/202012:28 WG1579697 ONE LAB. NATIONWIDE. Cp FTC FSS 4 Cn FC 7G1 FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Asheville, NC 92506305 L1287182 11/20/20 23:55 Page 45 of 50 PAGE: 6 of 11 WG1579055 Total Solids by Method 2540 G-2011 Method Blank (MB) (MB) R3595360-1 11/20/20 01:00 MB Result MB Qualifier MB MDL Analyte % % Total Solids 0.000 L1287162-01 Original Sample (OS) • Duplicate (DUP) MB RDL (OS) L1287162-01 11/20/20 01:00 • (DUP) R3595360-3 11/20/20 01:00 Original Result DUP Result Dilution DUP RPD Analyte % % % Total Solids 81.0 81.0 1 0.0441 Laboratory Control Sample (LCS) QUALITY CONTROL SUMMARY 1-1287182-01,02 DUP Qualifier DUP RPD Limits 10 (LCS) R3595360-2 11/20/20 01:00 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte % %_ % % Total Solids 50.0 50.0 100 85.0-115 ONE LAB. NATIONWIDE. - I Cp FTc FSS 4 — Cn FSr — 7G1 FAI FSC Page 46 of 50 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Asheville, NC 92506305 L1287182 11/20/20 23:55 7 of 11 WG1579697 Wet Chemistry by Method 9056A Method Blank (MB) (MB) R3595665-1 11/20/2011:37 MB Result Analyte mg/kg Sulfate U MB Qualifier MB MDL MB RDL mg/kg mg/kg 12.9 50.0 Laboratory Control Sample (LCS) (LCS) R3595665-2 11/20/2011:54 Spike Amount LCS Result Analyte mg/kg mg/kg Sulfate 200 192 LCS Rec. 95.9 QUALITY CONTROL SUMMARY 1-1287182-01,02 Rec. Limits LCS Qualifier 80.0-120 ONE LAB. NATIONWIDE. — I Cp FTC FSS 4 — Cn FSr �GI FAI FSC Page 47 of 50 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Asheville, NC 92506305 L1287182 11/20/20 23:55 8 of 11 GLOSSARY OF TERMS Guide to Reading and Understanding Your Laboratory Report ONE LAB. NATIONWIDE. The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name, Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received. Abbreviations and Definitions CP IP FTC FSS MDL Method Detection Limit. RDL Reported Detection Limit. [Cn] Rec. Recovery. RPD Relative Percent Difference. FSr SDG Sample Delivery Group. U Not detected at the Reporting Limit (or MDL where applicable). Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes C F reported. If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the Dilution standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal FAI Limits for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges. Original Sample The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control SC sample. The Original Sample may not be included within the reported SDG. This column provides a letter and/or number designation that corresponds to additional information concerning the result Qualifier reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" Result (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Uncertainty (Radiochemistry) Confidence level of 2 sigma. A brief discussion about the included sample results, including a discussion of any non -conformances to protocol Case Narrative (Cn) observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. Quality Control This section of the report includes the results of the laboratory quality control analyses required by procedure or Summary (Qc) analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. This is the document created in the field when your samples were initially collected. This is used to verify the time and Sample Chain of date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This Custody (Sc) chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. This section of your report will provide the results of all testing performed on your samples. These results are provided Sample Results (Sr) by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. Sample Summary (Ss) This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Qualifier Description J The identification of the analyte is acceptable; the reported value is an estimate. Page 48 of 50 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Asheville, NC 92506305 L1287182 11/20/20 23:55 9 of 11 ACCREDITATIONS & LOCATIONS ONE LAB. NATIONWIDE. Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing FP1 turn -around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. Not all certifications held by the laboratory are applicable to the results reported in the attached report. Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National. Z Tc State Accreditations f—� Alabama 40660 Nebraska _ NE-OS-15-05 SS Alaska 17-026 Nevada TN-03-2002-34 Arizona AZO612 New Hampshire 2975 Arkansas 88-0469 New Jersey_NELAP TNO02 C n California 2932 New Mexico n/a Colorado TN00003 New York 11742 s Connecticut PH-0197 North Carolina Env375 Sr Florida E87487 North Carolina' DW21704 Georgia NELAP North Carolina' 41 Georgia' 923 North Dakota R-140 RC Idaho TN00003 Ohio—VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 G Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhode Island LA000356 Kentucky76 90010 South Carolina 84004 Kentucky 2 16 South Dakota n/a Louisiana A130792 Tennessee' 4 2006 Louisiana' LA180010 Texas T104704245-18-15 [SC Maine TN0002 Texas' LABO152 Maryland 324 Utah Massachusetts M-TNO03 Vermont Michigan 9958 Virginia Minnesota 047-999-395 Washington Mississippi TN00003 West Virginia Missouri 340 Wisconsin Montana CERT0086 Wyoming Third Party Federal Accreditations A21LA — ISO 17025 1461.01 AIHA-LAP,LLC EMLAP A21LA — ISO 17025 5 1461.02 DOD Canada 1461.01 USDA EPA—Crypto TN00003 ' Drinking Water 'Underground Storage Tanks 3 Aquatic Toxicity 4 Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable Our Locations TN00003 VT2006 460132 C847 233 9980939910 A2LA 100789 1461.01 P330-15-00234 Pace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contact our main office. Pace National performs all testing at our central laboratory. WA MT NO OR MN T ID T WI NY SD WY MI NV T NE IA OH T PA T f IL Ills WY vA UT T CA�� T KS MO KY W 11110 � NM O� AR N Sc T MS A`7L GA T TX * LA T AK T T q FL wo HI ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Asheville, NC 92506305 L1287182 11/20/20 23:55 ME Page 49 of 50 PAGE: 10 of 11 Internal Transfer Chain of Custody ❑ Samples Pre -Logged into eCOC. nn�r1C 1]Ar_ M1...6...4Alamo- C: nfhillc I—riFlll 1111A State Of Origin: NC Cert. Needed: ❑ Yes nwnar Rprpivpd Date_ p0g3 f www.pecolabs.com ❑ No , 11/16/2020 Results Reauested Bv: 11/18/2020 Report To V -------- - - `- - Subcontract To Requested Anaiysls Chris Derouen Pace Analytical Nationale Pace Analytical Asheville 12065 Lebanon Rd 2225 Riverside Dr. Mt. Juliet, TN 371227p Asheville, NC 28804 Phone (615)758-5858 Phone (828)254-7176 Preserved Containers v n Sample Collect m m item Sample ID Type DateFTme Lab ID Matrix LAB USE ONLY 1 BGS1 (1) PS 11/16/2020 10,55 92506305001 Sold 1 x 2 JDGS2 (11.5) PS 11/16/2020 09:45 92506305002 Solid 1 x s Z 3 4 5 Comments Transfers Released By DateMme Received By DatelFme 1 � �tfL'��✓ lC r -s b 2 3 Cooler Temperature on Receipt 'C CustodySe N Receiv4d on Ice : Y ar N samples Inta Xf or N ***In order to maintain client confidentiality, location/name of sampling site, sampler's name and signature may not be provided on this COC document. This chain of custody is considered complete as is si this information is available in the owner laboratory. l n L1,2 Tuesday November 17. 2020 3'08 45 PM Sa^.C�� na_c1.Rr _ti�Ckilst :0C Seal Present Intact: oy N If Applicable Coc Signed/Accurate: /�Y�N VCA Zero Headspace: YN Bottles arrive intact; 7p—rd pres-Correct lCheck: u Correct bottles '-Lsed:- Suffiment volume -lent: I- N RAD Screen '0.5 mR%hrr /y_rj FMT-ALL-C-002rev.00241VIareh2009 Page 1 of 1 Page 50 of 50 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 December 02, 2020 Derek Bouchard Republic Services 1070 Riverside Dr Asheville, NC 28804 RE: Project: Foothills Landfill 11/20 Pace Project No.: 92507557 Dear Derek Bouchard: Enclosed are the analytical results for sample(s) received by the laboratory on November 20, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte Revised Report : Report revised to report J-values, Remove 1,4-dioxane from all samples, correct clerical error on project ID If you have any questions concerning this report, please feel free to contact me. Sincerely, 2 Chris Derouen christopher.derouen@pacelabs.com (828)254-7176 Project Manager Enclosures cc: Trihydro, Republic Services REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Foothills Landfill 11/20 Pace Project No.: 92507557 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 SAMPLE SUMMARY Project: Foothills Landfill 11/20 Pace Project No.: 92507557 Lab ID Sample ID Matrix Date Collected Date Received 92507557001 92507557002 LISW-1 PIW-1 Water Water 11/19/20 09:15 11/19/20 09:40 11/20/20 12:40 11/20/20 12:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 SAMPLE ANALYTE COUNT Project: Foothills Landfill 11/20 Pace Project No.: 92507557 Analytes Lab lD Sample ID Method Analysts Reported Laboratory 92507557001 LISW-1 EPA 6010D BG2 15 PASI-A EPA 8260D CL 52 PASI-C EPA 9040C SMK 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 4 PASI-A EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A 92507557002 PIW-1 EPA 6010D BG2 15 PASI-A EPA 8260D CL 52 PASI-C EPA 9040C SMK 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 4 PASI-A EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Foothills Landfill 11/20 Pace Project No.: 92507557 Sample: USW-1 Lab ID: 92507557001 Collected: 11/19/20 09:15 Received: 11/20/20 12:40 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 11/21/20 03:19 11/21/20 23:47 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 11/21/20 03:19 11/21/20 23:47 7440-38-2 Barium 19.7 ug/L 5.0 3.5 1 11/21/20 03:19 11/21/20 23:47 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 11/21/20 03:19 11/21/20 23:47 7440-41-7 Cadmium 0.74J ug/L 1.0 0.40 1 11/21/20 03:19 11/21/20 23:47 7440-43-9 BC Chromium ND ug/L 5.0 3.7 1 11/21/20 03:19 11/21/20 23:47 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 11/21/20 03:19 11/21/20 23:47 7440-48-4 Copper ND ug/L 5.0 4.3 1 11/21/20 03:19 11/21/20 23:47 7440-50-8 Lead ND ug/L 5.0 4.5 1 11/21/20 03:19 11/21/20 23:47 7439-92-1 Nickel ND ug/L 5.0 3.5 1 11/21/20 03:19 11/21/20 23:47 7440-02-0 Selenium ND ug/L 10.0 4.7 1 11/21/20 03:19 11/21/20 23:47 7782-49-2 Silver ND ug/L 5.0 2.5 1 11/21/20 03:19 11/21/20 23:47 7440-22-4 Thallium ND ug/L 10.0 8.1 1 11/21/20 03:19 11/21/20 23:47 7440-28-0 Vanadium ND ug/L 5.0 3.9 1 11/21/20 03:19 11/21/20 23:47 7440-62-2 Zinc ND ug/L 10.0 9.5 1 11/21/20 03:19 11/21/20 23:47 7440-66-6 8260D MSV Low Level Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 11/21/20 15:37 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 11/21/20 15:37 107-13-1 Benzene ND ug/L 1.0 0.15 1 11/21/20 15:37 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 11/21/20 15:37 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 11/21/20 15:37 75-27-4 Bromoform ND ug/L 1.0 0.62 1 11/21/20 15:37 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 11/21/20 15:37 74-83-9 v2 2-Butanone (MEK) ND ug/L 5.0 3.3 1 11/21/20 15:37 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 11/21/20 15:37 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 11/21/20 15:37 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 11/21/20 15:37 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 11/21/20 15:37 75-00-3 Chloroform ND ug/L 5.0 2.3 1 11/21/20 15:37 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 11/21/20 15:37 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 11/21/20 15:37 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 11/21/20 15:37 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 11/21/20 15:37 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 11/21/20 15:37 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 11/21/20 15:37 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 11/21/20 15:37 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 11/21/20 15:37 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 11/21/20 15:37 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 11/21/20 15:37 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 11/21/20 15:37 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.29 1 11/21/20 15:37 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.25 1 11/21/20 15:37 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.19 1 11/21/20 15:37 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:48 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Foothills Landfill 11/20 Pace Project No.: 92507557 Sample: USW-1 Lab ID: 92507557001 Collected: 11/19/20 09:15 Received: 11/20/20 12:40 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Analytical Method: EPA 8260D Pace Analytical Services - Charlotte cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 11/21/20 15:37 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 11/21/20 15:37 10061-02-6 Ethylbenzene ND ug/L 1.0 0.26 1 11/21/20 15:37 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 11/21/20 15:37 591-78-6 lodomethane ND ug/L 20.0 12.5 1 11/21/20 15:37 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 11/21/20 15:37 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 11/21/20 15:37 108-10-1 Styrene ND ug/L 1.0 0.27 1 11/21/20 15:37 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 11/21/20 15:37 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 11/21/20 15:37 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 11/21/20 15:37 127-18-4 Toluene ND ug/L 1.0 0.24 1 11/21/20 15:37 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 11/21/20 15:37 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 11/21/20 15:37 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 11/21/20 15:37 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 11/21/20 15:37 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 11/21/20 15:37 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 11/21/20 15:37 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 11/21/20 15:37 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 11/21/20 15:37 1330-20-7 m&p-Xylene ND ug/L 2.0 0.41 1 11/21/20 15:37 179601-23-1 o-Xylene ND ug/L 1.0 0.22 1 11/21/20 15:37 95-47-6 Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 11/21/20 15:37 460-00-4 1,2-Dichloroethane-d4 (S) 91 % 70-130 1 11/21/20 15:37 17060-07-0 Toluene-d8 (S) 99 % 70-130 1 11/21/20 15:37 2037-26-5 9040 pH Analytical Method: EPA 9040C Pace Analytical Services -Asheville pH at 25 Degrees C 6.7 Std. Units 0.10 0.10 1 11/22/20 13:05 D6,H3 300.0 IC anions 48hr Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Nitrate as N ND mg/L 0.10 0.060 1 11/20/20 22:16 14797-55-8 Nitrate -Nitrite (as N) ND mg/L 0.20 0.11 1 11/20/20 22:16 7727-37-9 Nitrite as N ND mg/L 0.10 0.050 1 11/20/20 22:16 14797-65-0 Sulfate 1.4 mg/L 1.0 0.50 1 11/20/20 22:16 14808-79-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 0.097 mg/L 0.050 0.025 1 11/23/20 18:27 11/23/20 21:45 7723-14-0 Date: 12/02/2020 10:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Foothills Landfill 11/20 Pace Project No.: 92507557 Sample: PIW-1 Lab ID: 92507557002 Collected: 11/19/20 09:40 Received: 11/20/20 12:40 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 11/21/20 03:19 11/22/20 00:00 7440-36-0 Arsenic 8.6J ug/L 10.0 4.7 1 11/21/20 03:19 11/22/20 00:00 7440-38-2 Barium 152 ug/L 5.0 3.5 1 11/21/20 03:19 11/22/20 00:00 7440-39-3 Beryllium 2.0 ug/L 1.0 0.70 1 11/21/20 03:19 11/22/20 00:00 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 11/21/20 03:19 11/22/20 00:00 7440-43-9 BC Chromium 23.9 ug/L 5.0 3.7 1 11/21/20 03:19 11/22/20 00:00 7440-47-3 Cobalt 10.5 ug/L 5.0 3.6 1 11/21/20 03:19 11/22/20 00:00 7440-48-4 Copper 30.4 ug/L 5.0 4.3 1 11/21/20 03:19 11/22/20 00:00 7440-50-8 Lead 24.1 ug/L 5.0 4.5 1 11/21/20 03:19 11/22/20 00:00 7439-92-1 Nickel 12.6 ug/L 5.0 3.5 1 11/21/20 03:19 11/22/20 00:00 7440-02-0 Selenium ND ug/L 10.0 4.7 1 11/21/20 03:19 11/22/20 00:00 7782-49-2 Silver ND ug/L 5.0 2.5 1 11/21/20 03:19 11/22/20 00:00 7440-22-4 Thallium ND ug/L 10.0 8.1 1 11/21/20 03:19 11/22/20 00:00 7440-28-0 Vanadium 71.2 ug/L 5.0 3.9 1 11/21/20 03:19 11/22/20 00:00 7440-62-2 Zinc 30.0 ug/L 10.0 9.5 1 11/21/20 03:19 11/22/20 00:00 7440-66-6 8260D MSV Low Level Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 11/21/20 21:03 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 11/21/20 21:03 107-13-1 Benzene ND ug/L 1.0 0.15 1 11/21/20 21:03 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 11/21/20 21:03 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 11/21/20 21:03 75-27-4 Bromoform ND ug/L 1.0 0.62 1 11/21/20 21:03 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 11/21/20 21:03 74-83-9 v2 2-Butanone (MEK) ND ug/L 5.0 3.3 1 11/21/20 21:03 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 11/21/20 21:03 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 11/21/20 21:03 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 11/21/20 21:03 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 11/21/20 21:03 75-00-3 Chloroform ND ug/L 5.0 2.3 1 11/21/20 21:03 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 11/21/20 21:03 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 11/21/20 21:03 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 11/21/20 21:03 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 11/21/20 21:03 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 11/21/20 21:03 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 11/21/20 21:03 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 11/21/20 21:03 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 11/21/20 21:03 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 11/21/20 21:03 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 11/21/20 21:03 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 11/21/20 21:03 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.29 1 11/21/20 21:03 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.25 1 11/21/20 21:03 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.19 1 11/21/20 21:03 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:48 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Foothills Landfill 11/20 Pace Project No.: 92507557 Sample: PIW-1 Lab ID: 92507557002 Collected: 11/19/20 09:40 Received: 11/20/20 12:40 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Analytical Method: EPA 8260D Pace Analytical Services - Charlotte cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 11/21/20 21:03 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 11/21/20 21:03 10061-02-6 Ethylbenzene ND ug/L 1.0 0.26 1 11/21/20 21:03 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 11/21/20 21:03 591-78-6 lodomethane ND ug/L 20.0 12.5 1 11/21/20 21:03 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 11/21/20 21:03 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 11/21/20 21:03 108-10-1 Styrene ND ug/L 1.0 0.27 1 11/21/20 21:03 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 11/21/20 21:03 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 11/21/20 21:03 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 11/21/20 21:03 127-18-4 Toluene ND ug/L 1.0 0.24 1 11/21/20 21:03 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 11/21/20 21:03 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 11/21/20 21:03 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 11/21/20 21:03 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 11/21/20 21:03 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 11/21/20 21:03 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 11/21/20 21:03 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 11/21/20 21:03 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 11/21/20 21:03 1330-20-7 m&p-Xylene ND ug/L 2.0 0.41 1 11/21/20 21:03 179601-23-1 o-Xylene ND ug/L 1.0 0.22 1 11/21/20 21:03 95-47-6 Surrogates 4-Bromofluorobenzene (S) 101 % 70-130 1 11/21/20 21:03 460-00-4 1,2-Dichloroethane-d4 (S) 91 % 70-130 1 11/21/20 21:03 17060-07-0 Toluene-d8 (S) 97 % 70-130 1 11/21/20 21:03 2037-26-5 9040 pH Analytical Method: EPA 9040C Pace Analytical Services -Asheville pH at 25 Degrees C 6.5 Std. Units 0.10 0.10 1 11/22/20 13:17 H3 300.0 IC anions 48hr Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Nitrate as N 1.8 mg/L 0.10 0.060 1 11/20/20 22:58 14797-55-8 Nitrate -Nitrite (as N) 1.8 mg/L 0.20 0.11 1 11/20/20 22:58 7727-37-9 Nitrite as N ND mg/L 0.10 0.050 1 11/20/20 22:58 14797-65-0 Sulfate 2.4 mg/L 1.0 0.50 1 11/20/20 22:58 14808-79-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 0.050 mg/L 0.050 0.025 1 11/23/20 18:27 11/23/20 21:47 7723-14-0 Date: 12/02/2020 10:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/20 Pace Project No.: 92507557 QC Batch: 582083 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92507557001, 92507557002 METHOD BLANK: 3078712 Associated Lab Samples: 92507557001, 92507557002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 5.0 3.0 11/21/20 23:41 Arsenic ug/L ND 10.0 4.7 11/21/20 23:41 Barium ug/L ND 5.0 3.5 11/21/20 23:41 Beryllium ug/L ND 1.0 0.70 11/21/20 23:41 Cadmium ug/L 0.58J 1.0 0.40 11/21/20 23:41 Chromium ug/L ND 5.0 3.7 11/21/20 23:41 Cobalt ug/L ND 5.0 3.6 11/21/20 23:41 Copper ug/L ND 5.0 4.3 11/21/20 23:41 Lead ug/L ND 5.0 4.5 11/21/20 23:41 Nickel ug/L ND 5.0 3.5 11/21/20 23:41 Selenium ug/L ND 10.0 4.7 11/21/20 23:41 Silver ug/L ND 5.0 2.5 11/21/20 23:41 Thallium ug/L ND 10.0 8.1 11/21/20 23:41 Vanadium ug/L ND 5.0 3.9 11/21/20 23:41 Zinc ug/L ND 10.0 9.5 11/21/20 23:41 LABORATORY CONTROL SAMPLE: Parameter 3078713 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 483 97 80-120 Arsenic ug/L 500 484 97 80-120 Barium ug/L 500 488 98 80-120 Beryllium ug/L 500 456 91 80-120 Cadmium ug/L 500 481 96 80-120 Chromium ug/L 500 494 99 80-120 Cobalt ug/L 500 479 96 80-120 Copper ug/L 500 508 102 80-120 Lead ug/L 500 478 96 80-120 Nickel ug/L 500 477 95 80-120 Selenium ug/L 500 479 96 80-120 Silver ug/L 250 241 97 80-120 Thallium ug/L 500 472 94 80-120 Vanadium ug/L 500 475 95 80-120 Zinc ug/L 500 462 92 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:48 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Pace Project No.: Foothills Landfill 11/20 92507557 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3078714 3078715 MS MSD 92507557001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 250 250 251 253 100 101 75-125 1 20 Arsenic ug/L ND 250 250 249 255 99 102 75-125 2 20 Barium ug/L 19.7 250 250 275 279 102 104 75-125 2 20 Beryllium ug/L ND 250 250 236 240 94 96 75-125 2 20 Cadmium ug/L 0.74J 250 250 255 258 102 103 75-125 1 20 BC Chromium ug/L ND 250 250 256 261 102 104 75-125 2 20 Cobalt ug/L ND 250 250 249 254 99 101 75-125 2 20 Copper ug/L ND 250 250 261 260 104 104 75-125 0 20 Lead ug/L ND 250 250 249 256 99 102 75-125 3 20 Nickel ug/L ND 250 250 251 255 100 102 75-125 2 20 Selenium ug/L ND 250 250 262 267 105 107 75-125 2 20 Silver ug/L ND 125 125 126 127 100 101 75-125 1 20 Thallium ug/L ND 250 250 252 257 100 102 75-125 2 20 Vanadium ug/L ND 250 250 244 249 97 99 75-125 2 20 Zinc ug/L ND 250 250 250 256 98 101 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:48 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/20 Pace Project No.: 92507557 QC Batch: 582143 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92507557001, 92507557002 METHOD BLANK: 3078829 Associated Lab Samples: 92507557001, 92507557002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 11/21/20 14:25 1,1,1-Trichloroethane ug/L ND 1.0 0.18 11/21/20 14:25 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 11/21/20 14:25 1,1,2-Trichloroethane ug/L ND 1.0 0.24 11/21/20 14:25 1,1-Dichloroethane ug/L ND 1.0 0.27 11/21/20 14:25 1,1-Dichloroethene ug/L ND 1.0 0.24 11/21/20 14:25 1,2,3-Trichloropropane ug/L ND 1.0 0.35 11/21/20 14:25 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 11/21/20 14:25 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 11/21/20 14:25 1,2-Dichlorobenzene ug/L ND 1.0 0.29 11/21/20 14:25 1,2-Dichloroethane ug/L ND 1.0 0.34 11/21/20 14:25 1,2-Dichloropropane ug/L ND 1.0 0.19 11/21/20 14:25 1,4-Dichlorobenzene ug/L ND 1.0 0.26 11/21/20 14:25 2-Butanone (MEK) ug/L ND 5.0 3.3 11/21/20 14:25 2-Hexanone ug/L ND 5.0 0.57 11/21/20 14:25 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 11/21/20 14:25 Acetone ug/L ND 25.0 6.2 11/21/20 14:25 Acrylonitrile ug/L ND 10.0 0.90 11/21/20 14:25 Benzene ug/L ND 1.0 0.15 11/21/20 14:25 Bromochloromethane ug/L ND 1.0 0.34 11/21/20 14:25 Bromodichloromethane ug/L ND 1.0 0.26 11/21/20 14:25 Bromoform ug/L ND 1.0 0.62 11/21/20 14:25 Bromomethane ug/L ND 2.0 0.62 11/21/20 14:25 v2 Carbon disulfide ug/L ND 2.0 0.40 11/21/20 14:25 Carbon tetrachloride ug/L ND 1.0 0.22 11/21/20 14:25 Chlorobenzene ug/L ND 1.0 0.23 11/21/20 14:25 Chloroethane ug/L ND 1.0 0.49 11/21/20 14:25 Chloroform ug/L ND 5.0 2.3 11/21/20 14:25 Chloromethane ug/L ND 1.0 0.39 11/21/20 14:25 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 11/21/20 14:25 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 11/21/20 14:25 Dibromochloromethane ug/L ND 1.0 0.41 11/21/20 14:25 Dibromomethane ug/L ND 1.0 0.46 11/21/20 14:25 Ethylbenzene ug/L ND 1.0 0.26 11/21/20 14:25 lodomethane ug/L ND 20.0 12.5 11/21/20 14:25 m&p-Xylene ug/L ND 2.0 0.41 11/21/20 14:25 Methylene Chloride ug/L ND 5.0 3.7 11/21/20 14:25 o-Xylene ug/L ND 1.0 0.22 11/21/20 14:25 Styrene ug/L ND 1.0 0.27 11/21/20 14:25 Tetrachloroethene ug/L ND 1.0 0.16 11/21/20 14:25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:48 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/20 Pace Project No.: 92507557 METHOD BLANK: 3078829 Associated Lab Samples: 92507557001, 92507557002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers Toluene ug/L ND 1.0 0.24 11/21/20 14:25 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 11/21/20 14:25 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 11/21/20 14:25 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 11/21/20 14:25 Trichloroethene ug/L ND 1.0 0.22 11/21/20 14:25 Trichlorofluoromethane ug/L ND 1.0 0.31 11/21/20 14:25 Vinyl acetate ug/L ND 2.0 1.4 11/21/20 14:25 Vinyl chloride ug/L ND 1.0 0.24 11/21/20 14:25 Xylene (Total) ug/L ND 1.0 0.63 11/21/20 14:25 1,2-Dichloroethane-d4 (S) % 92 70-130 11/21/20 14:25 4-Bromofluorobenzene (S) % 101 70-130 11/21/20 14:25 Toluene-d8 (S) % 99 70-130 11/21/20 14:25 LABORATORY CONTROL SAMPLE: Parameter 3078830 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 56.4 113 70-130 1,1,1-Trichloroethane ug/L 50 50.4 101 70-130 1,1,2,2-Tetrachloroethane ug/L 50 53.5 107 70-130 1,1,2-Trichloroethane ug/L 50 53.7 107 70-130 1,1-Dichloroethane ug/L 50 50.4 101 70-130 1,1-Dichloroethene ug/L 50 56.1 112 70-132 1,2,3-Trichloropropane ug/L 50 52.4 105 70-130 1,2-Dibromo-3-chloropropane ug/L 50 54.1 108 70-132 1,2-Dibromoethane (EDB) ug/L 50 53.6 107 70-130 1,2-Dichlorobenzene ug/L 50 55.1 110 70-130 1,2-Dichloroethane ug/L 50 47.1 94 70-130 1,2-Dichloropropane ug/L 50 53.0 106 70-130 1,4-Dichlorobenzene ug/L 50 55.5 111 70-130 2-Butanone (MEK) ug/L 100 92.8 93 70-133 2-Hexanone ug/L 100 106 106 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 104 104 70-130 Acetone ug/L 100 99.6 100 70-144 Acrylonitrile ug/L 250 240 96 70-130 Benzene ug/L 50 52.6 105 70-130 Bromochloromethane ug/L 50 51.0 102 70-130 Bromodichloromethane ug/L 50 50.7 101 70-130 Bromoform ug/L 50 53.1 106 70-131 Bromomethane ug/L 50 38.2 76 30-177 v2 Carbon disulfide ug/L 50 57.2 114 70-133 Carbon tetrachloride ug/L 50 54.9 110 70-130 Chlorobenzene ug/L 50 55.9 112 70-130 Chloroethane ug/L 50 46.4 93 46-131 Chloroform ug/L 50 47.0 94 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:48 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/20 Pace Project No.: 92507557 LABORATORY CONTROL SAMPLE: Parameter 3078830 Units Spike LCS Conc. Result Chloromethane ug/L 50 cis-1,2-Dichloroethene ug/L 50 cis-1,3-Dichloropropene ug/L 50 Dibromochloromethane ug/L 50 Dibromomethane ug/L 50 Ethylbenzene ug/L 50 lodomethane ug/L 100 m&p-Xylene ug/L 100 Methylene Chloride ug/L 50 o-Xylene ug/L 50 Styrene ug/L 50 Tetrachloroethene ug/L 50 Toluene ug/L 50 trans-1,2-Dichloroethene ug/L 50 trans- 1,3-Dichloropropene ug/L 50 trans-1,4-Dichloro-2-butene ug/L 50 Trichloroethene ug/L 50 Trichlorofluoromethane ug/L 50 Vinyl acetate ug/L 100 Vinyl chloride ug/L 50 Xylene (Total) ug/L 150 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % LCS % Rec % Rec Limits 40.3 81 49-130 48.6 97 70-130 54.8 110 70-130 56.1 112 70-130 53.3 107 70-130 55.6 111 70-130 95.0 95 47-140 112 112 70-130 46.6 93 68-130 56.7 113 70-130 55.6 111 70-130 49.6 99 70-130 53.1 106 70-130 50.6 101 70-130 52.8 106 70-130 56.9 114 25-200 54.6 109 70-130 46.5 93 61-130 102 102 70-140 39.4 79 59-142 168 112 70-130 93 70-130 102 70-130 99 70-130 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3078831 MS 92507557001 Spike Parameter Units Result Conc. MSD Spike Conc. 3078832 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 21.0 21.9 105 109 70-135 4 30 1,1,1-Trichloroethane ug/L ND 20 20 23.7 24.7 118 123 70-148 4 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 19.1 19.5 95 97 70-131 2 30 1,1,2-Trichloroethane ug/L ND 20 20 20.1 20.9 100 105 70-136 4 30 1,1-Dichloroethane ug/L ND 20 20 20.7 22.1 104 110 70-147 6 30 1,1-Dichloroethene ug/L ND 20 20 24.1 25.6 121 128 70-158 6 30 1,2,3-Trichloropropane ug/L ND 20 20 21.1 20.5 105 103 67-137 3 30 1,2-Dibromo-3- ug/L ND 20 20 20.5 20.4 103 102 69-136 0 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 20.4 20.4 102 102 70-137 0 30 1,2-Dichlorobenzene ug/L ND 20 20 20.7 20.7 103 103 70-133 0 30 1,2-Dichloroethane ug/L ND 20 20 22.8 24.0 114 120 67-138 5 30 1,2-Dichloropropane ug/L ND 20 20 20.3 20.7 102 103 70-138 2 30 1,4-Dichlorobenzene ug/L ND 20 20 20.1 20.8 101 104 70-133 3 30 2-Butanone (MEK) ug/L ND 40 40 38.8 43.6 97 109 61-147 12 30 2-Hexanone ug/L ND 40 40 39.5 39.2 99 98 67-139 1 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:48 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/20 Pace Project No.: 92507557 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3078831 3078832 MS MSD 92507557001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 4-Methyl-2-pentanone ug/L ND 40 40 37.5 38.7 94 97 67-136 3 30 (MIBK) Acetone ug/L ND 40 40 49.1 48.4 123 121 55-159 1 30 Acrylonitrile ug/L ND 100 100 98.2 93.4 98 93 68-140 5 30 Benzene ug/L ND 20 20 20.0 20.7 100 104 67-150 3 30 Bromochloromethane ug/L ND 20 20 19.8 20.4 99 102 70-146 3 30 Bromodichloromethane ug/L ND 20 20 19.9 20.0 99 100 70-138 1 30 Bromoform ug/L ND 20 20 20.3 20.6 102 103 57-138 1 30 Bromomethane ug/L ND 20 20 21.0 23.9 105 120 10-200 13 30 Carbon disulfide ug/L ND 20 20 19.0 20.8 95 104 70-152 9 30 Carbon tetrachloride ug/L ND 20 20 25.9 27.3 129 136 70-147 5 30 Chlorobenzene ug/L ND 20 20 19.5 20.7 98 103 70-137 6 30 Chloroethane ug/L ND 20 20 20.5 22.7 103 113 51-166 10 30 Chloroform ug/L ND 20 20 19.9 22.4 100 112 70-144 12 30 Chloromethane ug/L ND 20 20 18.2 18.8 91 94 24-161 3 30 cis-1,2-Dichloroethene ug/L ND 20 20 20.3 21.1 102 105 67-148 4 30 cis-1,3-Dichloropropene ug/L ND 20 20 20.8 20.9 104 104 70-142 0 30 Dibromochloromethane ug/L ND 20 20 20.7 21.2 104 106 68-138 2 30 Dibromomethane ug/L ND 20 20 20.9 21.4 104 107 70-134 2 30 Ethylbenzene ug/L ND 20 20 20.0 20.9 100 104 68-143 4 30 lodomethane ug/L ND 40 40 34.1 36.8 85 92 20-161 8 30 m&p-Xylene ug/L ND 40 40 40.3 41.9 101 105 53-157 4 30 Methylene Chloride ug/L ND 20 20 18.3 20.9 92 104 64-148 13 30 o-Xylene ug/L ND 20 20 18.9 19.7 95 99 68-143 4 30 Styrene ug/L ND 20 20 19.2 20.2 96 101 70-136 5 30 Tetrachloroethene ug/L ND 20 20 20.8 21.1 104 106 70-139 2 30 Toluene ug/L ND 20 20 19.8 20.3 99 102 47-157 3 30 trans-1,2-Dichloroethene ug/L ND 20 20 22.4 23.8 112 119 70-149 6 30 trans-1,3-Dichloropropene ug/L ND 20 20 21.4 22.6 107 113 70-138 5 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 17.5 21.2 87 106 31-145 19 30 Trichloroethene ug/L ND 20 20 21.8 23.2 109 116 70-149 6 30 Trichlorofluoromethane ug/L ND 20 20 24.8 25.0 124 125 61-154 1 30 Vinyl acetate ug/L ND 40 40 43.1 46.0 108 115 48-156 7 30 Vinyl chloride ug/L ND 20 20 19.6 20.8 98 104 55-172 6 30 Xylene (Total) ug/L ND 60 60 59.2 61.6 99 103 66-145 4 30 1,2-Dichloroethane-d4 (S) % 110 110 70-130 4-Bromofluorobenzene (S) % 101 103 70-130 Toluene-d8 (S) % 97 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:48 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/20 Pace Project No.: 92507557 QC Batch: 582168 Analysis Method: EPA 9040C QC Batch Method: EPA 9040C Analysis Description: 9040 pH Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92507557001, 92507557002 SAMPLE DUPLICATE: 3078948 92505308001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 4.2 4.1 3 9 D6,H3 SAMPLE DUPLICATE: 3078949 92507557001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.7 6.5 3 9 D6,H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:48 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/20 Pace Project No.: 92507557 QC Batch: 582038 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92507557001, 92507557002 METHOD BLANK: 3078568 Matrix: Water Associated Lab Samples: 92507557001, 92507557002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrate as N mg/L ND 0.10 0.060 11/20/20 21:48 Nitrate -Nitrite (as N) mg/L ND 0.20 0.11 11/20/20 21:48 Nitrite as N mg/L ND 0.10 0.050 11/20/20 21:48 Sulfate mg/L ND 1.0 0.50 11/20/20 21:48 LABORATORY CONTROL SAMPLE: 3078569 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/L 2.5 2.6 103 90-110 Nitrate -Nitrite (as N) mg/L 5 5.1 102 90-110 Nitrite as N mg/L 2.5 2.5 101 90-110 Sulfate mg/L 50 51.1 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3078570 3078571 MS MSD 92507557001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrate as N mg/L ND 2.5 2.5 2.5 2.5 98 98 90-110 0 10 Nitrate -Nitrite (as N) mg/L ND 5 5 4.9 4.9 97 98 90-110 1 10 Nitrite as N mg/L ND 2.5 2.5 2.4 2.4 95 97 90-110 2 10 Sulfate mg/L 1.4 50 50 49.8 49.9 97 97 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:48 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Foothills Landfill 11/20 Pace Project No.: 92507557 QC Batch: 582389 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92507557001, 92507557002 METHOD BLANK: 3079905 Matrix: Water Associated Lab Samples: 92507557001, 92507557002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Phosphorus mg/L ND 0.050 0.025 11/23/20 21:39 LABORATORY CONTROL SAMPLE: 3079906 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phosphorus mg/L 2.5 2.5 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3079907 3079908 MS MSD 92506781001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phosphorus mg/L 6.0 2.5 2.5 8.4 8.2 96 88 90-110 2 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:48 AM without the written consent of Pace Analytical Services, LLC. Page 17 of 22 Pace Analytical Services, LLC leac,yficalAnal2225 Riverside Dr. Asheville, NC 28804 www.pacelabs.com (828)254-7176 QUALIFIERS Project: Foothills Landfill 11/20 Pace Project No.: 92507557 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS BC The same analyte was detected in an associated blank at a concentration above 1/2 the reporting limit but below the laboratory reporting limit. D6 The precision between the sample and sample duplicate exceeded laboratory control limits. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/02/2020 10:48 AM without the written consent of Pace Analytical Services, LLC. Page 18 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Foothills Landfill 11/20 92507557 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92507557001 USW-1 EPA 3010A 582083 EPA 6010D 582112 92507557002 PIW-1 EPA 3010A 582083 EPA 6010D 582112 92507557001 USW-1 EPA 8260D 582143 92507557002 PIW-1 EPA 8260D 582143 92507557001 USW-1 EPA 9040C 582168 92507557002 PIW-1 EPA 9040C 582168 92507557001 USW-1 EPA 300.0 Rev 2.1 1993 582038 92507557002 PIW-1 EPA 300.0 Rev 2.1 1993 582038 92507557001 USW-1 EPA 365.1 Rev 2.0 1993 582389 EPA 365.1 Rev 2.0 1993 582495 92507557002 PIW-1 EPA 365.1 Rev 2.0 1993 582389 EPA 365.1 Rev 2.0 1993 582495 Date: 12/02/2020 10:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 22 Document Name: Document Revised: October 28, 2020 Sample Condition Upon Receipt(SOUR) Page 1 of 2 /7ace Analytical' Document No.: Issuing Authority: F-CAR-CS-033-Rev.07 Pace Carolinas Quality Office Laboratory receiving samples: Asheville 7, Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville[] Atlanta[:] Kernersville❑ i Sample Condition Client Name: Upon Receipt Project #; Courier: []Fed Ek ❑UPS ❑USPS ]Client ❑ Commercial ❑Pace ❑Other: Custody Seal Present? ❑Yes 7No Seals Intact? ❑Yes ❑i No WO#:92507557 1111111111111111111111 925071557 Dale/Initials Person Examining Contents:_ Packing Material: ❑Bubble Wrap ❑Bubble Bags ❑None ❑ Other Biological Tissue Frozen? Thermometer; []Yes[]No❑N/A 0 IR Gun ID: pWet ❑Blue ❑None i '. l'1 Type of Ice: Correction Factor: Cooler Temp: ' Add/Subtract (°C) Temp should be above freezing to 6-C ❑Samples out of temp criteria. Samples on ice, coaling process Cooler Temp Corrected (°C): i p hasbzgun USDA Regulated Soil { N/A, water sample) Did samples originate irva quarantine zone within the United States: CA, NY, or SC (check maps)? Did samG'm originate from a foreign source (intern tionally, ❑Yes ❑No including Hawaii ana Nuerro KKO;r U,C� Comments/Discrepancy: Chain of Custody Present? j]Yes [-]No [-]NIA 1. Samples Arrived within Hold Time? ❑Yes [-]No ❑N/A 2. Short Hold Time Analysis (<72 hr.)? [-]Yes ONo ❑N/A 3. Rush Turn Around Time Requested? ;Yes ❑No ❑NIA a. SufficientVolume? r ❑ves [-]No [-]N/A S. Correct Containers Used? Yes ❑No ❑N/A 6. -Pace Containers Used? Dyes ❑No ❑N/A Containers Intact? Yes ❑No []N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes QNo []N/A 8. Sample Labels Match COC? ❑Yes ❑No ❑N/A 9. -Includes Date/Time/ID/Analysis Matrix: Headspace in VOA Vials (>5-6mm)? [--]Yes dNo i IN/A 10. Trip Blank Present? ❑Yes ❑No ❑N/A 11. Trip Blank Custody Seals Present? Dyes [:)No_ ❑NIA COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted: Date/Time: Lot ID of snlit containers: Field Data Required? [-]Yes ❑No Project Manager SCURF Review: Date: // t ✓ Project Manager SRF Review: Date: z a d Page 20 of 22 CeAnalytical" Document Name: Sample Condition Upon Recei Document No.: F-CAR-CS-033-Rev.07 *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VQA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg "Bottom half of box is to list number of bottles Document Revised: October 28, 2020 t(SCUR) Page 2 of 2 Issuing Authority: Pace Carolinas Quality Office Project # W®# . 92aa755 1 PM: CD1 Due Date: 11/24/20 CLIENT: 93—ODS ASHVL tt E d if u Z v v a a E vi .-1 a a m Z v v a a E O N M a m Z v m a E V1 7 N a co ¢ a i v V a rl 7 r a U v a O z a E e-I of V a co V o- p _ o- E fJ Z M a o O Z m q N d E r-I N V a m U N o- p Z a E � V V d m °- '4 a L ° E o 0r 3¢¢ Q Z v n c O E 4 `m •--i M l7 U x a E 6 v .-y :c H 0t7 4 Z -- c = ¢ E N a M a¢ O r`n-� S E q v .� r 0 N ry S C1 ¢ E N M l7 a¢ u 4 Z �- Z E 4 E N Q O M 0 Z u O > E O � M 0 a>> O vi N Z p ] E p v f M U Z Q c fl > E O � M cr t9 4 r, rn 2 O 7 E: O � a U a>> Q Y o y s' a m '} M O Q ? a. 7 « Y n N m -� y Y � u ` a v = ut N r-I F= [n a T Z LL a m _ n E o N H N a m D N T Z Q " a E a ¢ M m '5 q 'y N U, - y a v c o a — 7 m - m -0 n ¢ ¢ E E o p Q O O1 U ¢ 7 R 1 TI i i I 3 A 5 5 7 8 9 10 N \N 11 12 —�d I — \N\ �s phi Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot r3 Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North carouna utnrvrs Cemncauun Vimx 1-- Out of hold, incorrect preservative, out of temp, incorrect containers. Page 21 of 22 N ® PACE ANALYTICAL SERVICES, LLC o aceAnalytical 106 Vantage Point Drive •West Columbia, 5C 29172 Number 108602 N Telephone No. 803-791-9700 Fax No. 803-791-9111 www. pacelabs.co m ca Client . Jz Report to Contact Telephone No. /E-mail rp$4 f} tc k uw << Quote NO- Address 28Dov A�aJ �� Sampler's Signature /�,1 k— �f( Analysis (Attach list if more space is needed) Page I of City 4 State (, Tip Code i s s V � CT '74 IL .� !` Lot # Bar Code {lab use only) Printed Name Project Name _ Project No. P.O. No. m " Matrix No of containers by Preservafive Type scription Sample lt] /Dezi (Containers for each sample may be combined on One fine.) Collation Collection Dale(s) Trme (military) F I d x A k Remarks / Gooier r.D. 711rn Around me Required (Prior lab approvel requtrad forespedlled TAT.) Standard :✓Rush (Specify) �. I Sample Disposal � I Return toClienf 't+TtisposalbyLab Possible Hazard Identification ./Non -Hazard I I Flammable I I Skin Irritant 1_1 Poison I I Unknown OC Requirements (Specify) 1. Relinquished by —a, wv Date �- Time eived - Date Time 2. Relinquished by Date Time eiv y Date Time 3. Relinquished by Date Time 3. Received by Date Time 4. Relinquished by Date Time 4. Laboratory received by Date Time Note: All samples are retained for four weeks from receipt Unless other arrangements care made. LAB USE ONLY _ Received on ice (Circle) Yes No Ice Pack Receipt Temp. I C Temp Blank E Y El �I DISTRIBUTION. W741TE & YELLOW -Return to laboratory with Sample(s); PINK-Field/Client Copy Document Number: MEOWN2-01