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3405_Forsyth_RJReynolds_RuralHall_Indus_Sept20GW_FID1516600_20201202
Signature v e-1, Date ERM NC, Inc. - 300 Summit Avenue, Suite 330, Charlotte, NC 28203 Facility Representative Address DENR USE ONLY�J [:]PaperReport ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: ' NC DENR Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, INC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): ERM NC, Inc. (consultant) Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Alan Martin E-mail: alan.martin(a)erm.com Phone:704-541-8345 NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) R.J. Reynolds Industrial Landfill Edwards Road (S.R. 1903) 34-05 0.0503 September 23-24, 2020 Rural Hall, Forsyth County Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑ Detection Monitoring ❑ Assessment Monitoring ❑X Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Groundwater monitoring data from private water supply wells ❑ Leachate monitoring data ❑ Surface water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, INC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Alan Martin, PG Project Manager 704-541-8345 Facility RepreseVt kiye Name (Print) 1 Title (Area Code) Telephone Number December 2, 2020 ix NC Licensed/ Professional Geologist Seal *as*.-� NC Professional Geologic Corporation # C-470 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 ak o_ ERM ERM, NC, Inc. Telephone: +1 704 541 8345 300 West Summit Avenue Fax: +1 704 624 7928 Suite 330 www.erm.com Charlotte, NC 28203 December 2, 2020 North Carolina Department of Environmental Quality Division of Waste Management 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Attention: Ms. Jaclynne Drummond jaclynne.drummond@ncdenr.gov Via Email Subject: Groundwater and Surface Water Monitoring Semi -Annual Summary Report — September 2020 Permit #34-05 - Edwards Road Landfill Edwards Road Rural Hall, Forsyth County, North Carolina Dear Ms. Drummond: On behalf of R.J. Reynolds Tobacco Company, ERM NC, Inc. (ERM) is submitting the summary report for the September 2020 groundwater and surface water monitoring event associated with the subject property. Please contact Mr. Scott Snow of R.J. Reynolds Tobacco Company at 336-741- 2236 or me if you have any questions or comments. Sincerely, Alan M rtin, P.G. Project Manager Attachments: Environmental Monitoring Reporting Form Groundwater and Surface Water Monitoring Semi -Annual Summary Report cc: Mr. Scott Snow - R.J. Reynolds Tobacco Company Mr. Max Hopkins - R.J. Reynolds Tobacco Company Mr. Tom Wilson - ERM Mr. Dave Wasiela - ERM r Al Groundwater & Surface Water Monitoring Semi- IAeynolds Annual Summary Report — September 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina December 2020 Project No.: 0551517 The business of sustainability ERM Signature Page December 2, 2020 Groundwater & Surface Water Semi -Annual Summary Report 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina Alan Martin P.G. Project Manager JGENSE� • :�9 184 \:qN D. M %-r� A �J x4ov_" Thomas M. Wilson, P.G. Principal in Charge ERM NC, Inc. 300 West Summit Avenue, Suite 330 Charlotte, North Carolina 28203 Phone: +1-704-541-8345 © Copyright 2020 by ERM Worldwide Group Ltd and / or its affiliates ("ERM"). All rights reserved. No part of this work may be reproduced or transmitted in any form, or by any means, without the prior written permission of ERM Monitoring — September www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. December 2020 2020-09 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING CONTENTS SEMI-ANNUAL SUMMARY REPORT — SEPTEMBER 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina CONTENTS 1. INTRODUCTION................................................................................................................................1 2. HISTORICAL GROUNDWATER AND SURFACE WATER QUALITY.............................................1 3. SUMMARY OF MONITORING PROGRAM.......................................................................................1 4. DESCRIPTION OF WATER QUALITY CONDITIONS......................................................................3 4.1 Site Hydrogeology................................................................................................................................3 4.2 Groundwater.........................................................................................................................................4 4.3 Surface Water.......................................................................................................................................5 5. PRELIMINARY ANALYSIS................................................................................................................6 6. REFERENCES...................................................................................................................................8 List of Figures Figure1 Site Location Plan.......................................................................................................................... 9 Figure2 Site Plan.........................................................................................................................................9 Figure 3 Groundwater Flow Directions........................................................................................................9 Figure 4 Groundwater Sampling Results — September 2019......................................................................9 Figure 5 Surface Water Sampling Results — September 2019....................................................................9 Figure 6 Sulfate Isocontour Map - Groundwater..........................................................................................9 Figure 7 Hydrogeologic Conceptual Model..................................................................................................9 Figure 8 Sulfate Trends - Groundwater....................................................................................................... 9 Figure 9 Sulfate Trends — Surface Water.................................................................................................... 9 List of Tables Table 1 Monitor Well Construction Details...................................................................................................9 Table 2 Groundwater Elevations..................................................................................................................9 Table 3 Groundwater and Surface Water Sampling Event Summary Data ................................................. 9 Table 4 Groundwater Field Parameters.......................................................................................................9 APPENDIX A HISTORICAL GROUNDWATER AND SURFACE WATER QUALITY ANALYTICAL DATA APPENDIX B LABORATORY DATA SHEETS APPENDIX C GROUNDWATER SAMPLING LOGS www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. December 2020 Page i 2020-09 Edwards Rd LF Rural Hall GW Repon.docx GROUNDWATER & SURFACE WATER MONITORING SEMI-ANNUAL SUMMARY REPORT — SEPTEMBER 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina 1. INTRODUCTION INTRODUCTION In accordance with the February 4, 2014 Corrective Action Plan (ERM NC, Inc.) and the Industrial Solid Waste Landfill Facility Permit No. 34-05-indus-1986 as amended through August 12, 2011, this report presents the results of the September 2020 groundwater and surface water sampling event conducted at the closed Edwards Road Landfill previously operated by R.J. Reynolds Tobacco Company. The closed landfill is located northeast of the jurisdictional boundaries of Rural Hall, Forsyth County, North Carolina and the location of the Site along with topographic map coverage of the vicinity are shown on Figure 1. Historical monitoring data indicate the occurrence of certain inorganic compounds in excess of the North Carolina Groundwater Standards (15A NCAC 2L) and Surface Water Standards (15A NCAC 213) in portions of the landfill site. A Corrective Action Plan (ERM) to restore groundwater quality beyond the compliance boundary, to stop unacceptable impacts to the adjacent surface waters, and to reduce the overall groundwater contamination at the facility was approved by the North Carolina Department of Environmental Quality (NCDEQ, formerly known as Department of Environment and Natural Resources) on February 19, 2014. The selected remedy includes source area contaminant control via the previous installation of the synthetic liner (cap) over the limits of waste plus drainage improvements (completed in 2012) to minimize rainfall infiltration, leachate generation and discharge of constituents to groundwater, to allow intrinsic remediation of the existing affected -groundwater. Groundwater and surface water monitoring has been conducted semi-annually at the site since the completion of the synthetic cap installation and the drainage improvements in 2012. 2. HISTORICAL GROUNDWATER AND SURFACE WATER QUALITY Groundwater and surface water quality monitoring has been conducted in the vicinity of the Edwards Road Landfill since 1989 in accordance with the conditions of Permit Number 34-05 and subsequent to the closure of the landfill, in accordance with the approved Post Closure Monitoring Plan. An updated water quality monitoring plan presented in the February 2014 CAP (ERM) was approved by NCDEQ on February 19, 2014 and is summarized in Section 3. Figure 2 depicts the locations of the groundwater monitor wells and surface water sampling locations and Table 1 presents a summary of available well construction details. Historical laboratory analytical results for available groundwater and surface water samples are summarized in Appendix A. 3. SUMMARY OF MONITORING PROGRAM Routine groundwater and surface water monitoring activities were conducted on September 23-24, 2020 and are summarized in the following table: www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. December 2020 Page 1 2020-09 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING SEMI-ANNUAL SUMMARY REPORT — SEPTEMBER 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina Sampling and Analyses Plan SUMMARY OF MONITORING PROGRAM Analytical Parameters Sample Metals a Sulfate Total Dissolved Field Location I.D. (EPA 602013/ (EPA 300.0) Solids Parameters b 7074) (SM 2540C) Groundwater: W-1 ✓ ✓ ✓ ✓ W-2 ✓ ✓ ✓ ✓ W-3 ✓ ✓ ✓ ✓ W-313 ✓ ✓ ✓ ✓ W-6 ✓ ✓ ✓ ✓ W-7 ✓ ✓ ✓ ✓ W-8 ✓ ✓ ✓ ✓ W-9 ✓ ✓ ✓ ✓ PW-1 ✓ ✓ Dry, no sample collected ✓ ✓ PZ-1 ° PZ-2 -- e I ✓ ✓ Insufficient volume PZ-3 c Dry, no sample collected PZ-4 c Dry, no sample collected ✓ ✓ PZ-5 Missing, will be replaced for April 2021 sampling event -- PZ-6 d PZ-7 d PZ-8 d - PZ-9 d -- -- PZ-10 d -- -- Subtotal 12 12 12 12 Surface Water: SS-01 ✓ ✓ ✓ ✓ SS-01+150 d -- -- -- -- SS-01+550 d -- -- -- -- SS-01+850 d -- -- -- -- SS-02 ✓ ✓ ✓ ✓ SS-10 -- -- -- SS ' 5 -- -- -- -- SS-20 ✓ ✓ ✓ ✓ SS-25 ✓ ✓ ✓ ✓ SS-30 ✓ ✓ ✓ ✓ SS-40 ✓ ✓ ✓ ✓ SS-50 ✓ ✓ ✓ ✓ SS-60 ✓ ✓ ✓ ✓ SS-70 ✓ ✓ ✓ ✓ SS-80 ✓ ✓ ✓ ✓ SS-90 ✓ ✓ ✓ ✓ Subtotal 11 11 11 11 TOTAL 23 23 23 23 'Aluminum, barium, cadmium, chromium (total), iron, lead, manganese and selenium. b Field parameters include temperature, pH, specific conductivity, turbidity, dissolved oxygen, and oxidation-reduction potential. PZ-1, PZ-3 and PZ-4 were dry during the September 2020 sampling event. d Temporary point not included in routine sampling. 2 Analysis for all metals analyses in PZ samples discontinued per NCDWM authorization 71912020. The groundwater and surface water monitoring activities were performed in general accordance with the techniques presented in the February 2014 CAP. Depth -to -water measurements and groundwater elevations for available monitor wells from the September 2020 sampling event are presented in Table 2. Groundwater flow directions are presented on Figure 3. Groundwater and surface water analytical data www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. December 2020 Page 2 2020-09 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING DESCRIPTION OF WATER QUALITY CONDITIONS SEMI-ANNUAL SUMMARY REPORT — SEPTEMBER 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina from the September 2020 sampling are presented in Table 3. Field collection parameters are provided in Table 4. Historical analytical data for both groundwater and surface water are presented in Appendix A. Laboratory data sheets for the September 2020 sampling event are presented in Appendix B. Copies of the sample logs are provided in Appendix C. Groundwater and surface water sample analytical results from the September 2020 sampling event are presented on Figures 4 and 5, respectively. Figure 6 depicts the isoconcentration contours of sulfates in groundwater at the site and Figure 7 presents a hydrogeologic conceptual site model and cross-section. Sulfate concentrations in groundwater and surface water over time are presented graphically on Figures 8 and 9, respectively. 4. DESCRIPTION OF WATER QUALITY CONDITIONS The following sections highlight key findings from the analytical results. 4.1 Site Hydrogeology The Site geology consists of fractured bedrock (gneiss and schist) overlain by partially weathered rock and a mantle of residual soils near the surface. The depth to bedrock beneath the Site generally ranges from 10 to 50 feet bgs. The first occurrence of groundwater beneath the upper portion of the site is within the fractured bedrock. In the lower portions of the site near the streams, groundwater is encountered within the partially weathered rock above the top of hard bedrock (transition zone). Shallow groundwater beneath the Site migrates either along the top of bedrock or along the permeable zones within the shallow fractured bedrock zone and discharges into nearby creeks, namely Leak Creek and its tributaries. The regional groundwater flow regime within the lower portion of the deep bedrock aquifer is north-eastward toward the nearest regional drainage feature, Town Fork Creek. The depth to groundwater in the top -of -rock aquifer zone ranges from approximately 0 feet at the creeks to 13 feet in shallow monitor wells. The depth to water in the bedrock aquifer ranges from artesian conditions to approximately 110 feet below ground surface in the measured wells. Using recent depth to water measurements, Site groundwater elevations and hydraulic gradients for the Site were calculated as summarized below. Horizontal Hydraulic Gradient - Saprolite/PWR September 22, 2020 Well Reference Depth to Head Head Distance Hydraulic Designation Elevation Water Elevation Change Change Gradient ft MSL ft ft ft ft ft/ft W-1 822.68 15.02 807.66 27.66 180 0.1537 Leak Creek a 780.0 0.00 780.0 W-3 804.43 3.81 801.62 16.12 80 0.2015 Leak Creek a 785.5 0.00 785.5 Average Hydraulic Gradient 0.1776 2 Leak Creek bed elevation represents groundwater discharge line Based on the September 2020 hydraulic gradients, the groundwater flow rate (seepage velocity) in the saprolite/PWR aquifer zone was calculated as summarized below. www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. December 2020 Page 3 2020-09 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING SEMI-ANNUAL SUMMARY REPORT — SEPTEMBER 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina urounawater beepage velocity uaicullatlon = Kline DESCRIPTION OF WATER QUALITY CONDITIONS where: K = hydraulic conductivity 0.080 ft/day (estimated) i = horizontal hydraulic gradient 0.1776 ft/ft (measured) ne = effective porosity 0.25 estimated Groundwater Seepage Velocity (Saprolite/PWR) = _ (0.08) ( 0.1776) / (0.25) = 5.68 x 10-2 ft/day or 21 ft/year The widely spaced locations of the bedrock monitor wells at the Site do not allow for calculation of the hydraulic gradient and groundwater flow rate of the bedrock aquifer. 4.2 Groundwater During the September 2020 groundwater sampling event, nine monitor wells were sampled utilizing a low flow, low volume sample collection technique. During the event, one piezometer was sampled using a bailer due to insufficient volume for low flow sampling procedures. Piezometers PZ-1, PZ-3 and PZ-4 were dry during the sampling event. PZ-5 was missing and will be replaced prior to the April 2021 sampling event. Presently, samples from groundwater monitoring wells at the Site contain concentrations of sulfates, total dissolved solids, and four metals above the applicable North Carolina groundwater standards (NC 2L standard). Sulfate, the primary constituent related to the landfill, was detected in two groundwater samples in excess of the NC 2L standard. Iron was detected in six of the nine groundwater monitoring well samples in excess of the NC 2L standard. Manganese was detected in five of the nine groundwater monitoring well samples in excess of the NC 2L standard. Selenium and total chromium were detected in one groundwater monitoring well sample each in excess of the NC 2L standard. Dissolved solids were detected in two of the groundwater monitoring well samples in excess of the NC 2L standard. The elevated concentrations of iron and manganese in samples from the Site monitor wells may be attributable to their natural occurrence in groundwater as indicated by historical sample results from onsite background monitor wells (W-6 and former W-4). No sulfates or dissolved solids were detected in groundwater from the piezometer PZ-2 sample in concentrations above the applicable NC 2L standards. Metals analyses of piezometer groundwater samples were discontinued with NCDWM authorization due to excessive turbidity issues and the resulting elevated metals concentrations. As noted in Section 1, installation of the synthetic cap and construction of drainage improvements over the limits of waste were completed in September 2012. The September 2020 samples were collected approximately 8 years after the cap installation. Sulfate concentrations from the September 2020 samples from shallow monitor wells W-1 and W-2, located near the limits of waste, indicate a continuing overall trend of decreasing or stable sulfate levels since the installation of the synthetic landfill cap in 2012. The September 2020 sulfate concentrations from shallow monitor well W-3, also near the limits of waste, indicate a continuing trend of fluctuating to decreasing sulfate levels since completion of the landfill cap installation. During the same period, sulfate concentrations at bedrock monitor well W-313, located adjacent to W-3, continue to show an overall stable or decreasing trend. At W-1, a trend of fluctuating concentrations of iron is shown, while manganese concentrations remained stable and total dissolved solids decreased compared to historical sample results prior to installation of the synthetic cap. At W-3, iron concentrations remained below the NC 2L standard and total dissolved solids concentrations have decreased from 2018 to 2020. Manganese concentrations at W-3 trended upward following the www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. December 2020 Page 4 2020-09 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING DESCRIPTION OF WATER QUALITY CONDITIONS SEMI-ANNUAL SUMMARY REPORT — SEPTEMBER 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina installation of the synthetic cap in 2012, but have decreased since 2018 and remain within the range of the historical analytical results. The September 2020 sulfate concentrations from deep bedrock monitor well PW-01, the former supply well located near the topographic high elevation of the landfill (see Figure 7), confirm a continuing trend of decreasing sulfate levels since completion of the landfill cap installation. Compared to the historical sulfate concentrations at PW-01, which represented the highest sulfate levels within the bedrock aquifer zone at the Site, the September 2020 sulfate concentration (330,000 pg/L) is the lowest sulfate concentration ever at PW-01 and represents a 71 percent concentration decrease from the maximum historical sulfate concentration (1,150,000 pg/L) observed at PW-01 in September 2012. The sustained trend of decreasing sulfate concentrations at PW-01 shows that the corrective action has been effective for remediating groundwater quality in the deeper bedrock aquifer zone as well as the shallow saprolite zone. Overall, the September 2020 groundwater quality results and the historical concentration trends indicate that groundwater quality improvements are evident in most monitor wells located at the perimeter of the landfill. 4.3 Surface Water During the September 2020 sampling event, 11 surface water samples were collected. The September 2020 surface water monitoring results indicate there are no surface water quality impacts directly attributable to the landfill. Concentrations of sulfates and total dissolved solids in all of the samples collected during the September 2020 sampling event were below the applicable North Carolina surface water standards (NC 213 standards). Manganese was below the applicable North Carolina surface water standards in all but one of the surface water samples. Iron was reported in six surface water samples above the North Carolina surface water standard however five of the samples were collected from upgradient of the landfill (SS-01, SS-20, SS-25, SS-30, and SS-50). Lead was reported in two surface water samples (SS-20 and SS-25) and manganese was reported in one surface water (SS-50) sample above the applicable NC 213 standards. Elevated turbidity levels (>10 NTUs) were observed in all the surface water samples with iron, lead and manganese exceedances. Sulfate concentrations from the surface water samples with historical results display a generally declining to stable trend when compared to the September 2012 surface water results. Overall, September 2020 surface water quality results confirm that the corrective actions at the site have been effective for the remediation of the surface water quality at the site. Compared to upstream surface water quality, there have been four confirmed on -site exceedances of surface water quality standards in the streams since 2014. There have been no exceedances of surface water quality standards downstream of the landfill (SS-40, SS-80 or SS-90) since installation of the synthetic landfill cap in 2012. www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. December 2020 Page 5 2020-09 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING PRELIMINARY ANALYSIS SEMI-ANNUAL SUMMARY REPORT — SEPTEMBER 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina 5. PRELIMINARY ANALYSIS The September 2020 monitoring results demonstrate: ■ Sulfate, total dissolved solids, iron, manganese, selenium and total chromium in groundwater monitoring well samples exceed the NC 2L standards. Concentrations of all detected analytes in groundwater were within the normal range of historical fluctuations. ■ Overall, the groundwater quality data indicate that the concentration trends and area of affected groundwater have been stabilized or reduced at the Site. Using sulfate as a primary indicator of landfill -related impacts, the sulfate concentration trends in groundwater, since completion of the landfill cap installation in September 2012, are generally decreasing including at PW-1. ■ No sulfates or dissolved solids were detected in groundwater from the piezometer PZ-2 sample in concentrations above the applicable NC 2L standards. Other piezometers had insufficient water present for sample collection or missing. Metals analyses of piezometer groundwater samples were discontinued with NCDWM authorization due to excessive turbidity issues and the resulting elevated metals concentrations. ■ No elevated concentrations of sulfates, metals or total dissolved solids have been detected in the off - site groundwater sample. The September 2020 groundwater sample collected from off -site monitoring well W-9, located to the southeast and side gradient of the landfill, contained a sulfate concentration of 11,000 pg/L which is well below the NC 2L standard (250,000 pg/L) and is consistent with background levels observed in the upgradient monitoring well W-6 (11,000 pg/L). ■ Concentrations of sulfates, total dissolved solids and selenium in all 11 surface water samples did not exceed the applicable NC 213 standards. Iron was detected in six surface water samples above the NC 213 standard including five upgradient, background surface water samples. Concentrations of other detected analytes in surface water were within the normal range of historical fluctuations. Elevated turbidity levels (>10 NTUs) were observed in all the surface water samples with exceedances. ■ Sulfate, manganese, and total dissolved solids concentrations in surface water samples from the Site have generally trended downward or remained stable compared to historical results. There have been no exceedances of surface water quality standards downstream of the landfill since the installation of the synthetic landfill cap in 2012. Installation of the synthetic cap and construction of drainage improvements over the limits of waste were completed in September 2012. The September 2020 samples were collected approximately 8 years after the cap installation and confirm that sustained groundwater quality improvements are evident in the monitoring wells located at the landfill perimeter. The September 2020 surface water quality results indicate that there are no exceedances of the NC 213 standards at any of the 11 surface water monitoring locations. The water quality improvements at the site indicate that the cap installation and the drainage improvements at the landfill are effective remedial measures. The schedule for routine monitoring activities is summarized below. www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. December 2020 Page 6 2020-09 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING SEMI-ANNUAL SUMMARY REPORT — SEPTEMBER 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina PRELIMINARY ANALYSIS Target Activity Completion Date Conduct Semi -Annual Water Quality Monitoring Event Submit Water Quality Monitoring Summary Report to NCDEQ Conduct Semi -Annual Water Quality Monitoring Event Submit Water Quality Monitoring Summary Report to NCDEQ March 2021 June 2021 September 2021 December 2021 www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. December 2020 Page 7 2020-09 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING SEMI-ANNUAL SUMMARY REPORT — SEPTEMBER 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina 6. REFERENCES Date Title REFERENCES Source 1986-05-29 Solid Waste Permit No. 34-05 issued to R.J. Reynolds Tobacco Company NCDENR 1999-10-19 R. J. Reynolds Tobacco Company Ash Landfill Transition Plan Geo-Environmental 2000-01-25 Work Plan for Upgrading Groundwater Monitoring, Phase 11 Ash Fill Area 2000-03-13 Upgrade of Groundwater Monitoring Program, Phase 11 Ash Fill Area 2001-01-02 Modifications to Transition Plan, Permit #34-05 2003-12-23 Post Closure Cover Maintenance Plan, Permit #34-05 2009-04-17 Compliance Order with Administrative Penalty, Facility #34-05 2009-07-17 Preliminary Site Assessment Work Plan, Facility #34-05 2009-10-29 Summary Report — Preliminary Site Assessment, Facility #34-05 2010-11-15 Letter correspondence to NCDENR DWM regarding Off -Site Well Locations, Facility #34-05 2011-03-10 Summary Report — Phase II Site Assessment Consultants, Inc. Geo-Environmental Consultants, Inc. Shield Environmental Associates, Inc. Shield Environmental Associates, Inc. Shield Environmental Associates, Inc. NCDENR ERM ERM ERM ERM 2011-06-14 Proposed Closure Modification - Edwards Road Landfill, Permit No. 34-05 ERM 2011-08-12 Regulatory approval Letter Of Closure Modification, Permit No. 34-05 NCDENR 2012-04-30 Summary Report — Groundwater Modelling for Site Assessment ERM 2012-09-21 Construction Quality Assurance for Closure Modification, Permit No. 34- ERM 05 2012-10-09 Letter correspondence to NCDENR regarding Groundwater Modelling & ERM Water Quality Monitoring, Facility #34-05 2012-11-07 Groundwater Corrective Action Permit Modification Application ERM 2013-10-01 Groundwater Corrective Action Application and Revised Groundwater ERM Modelling Scenarios 2013-10-10 Regulatory approval of Groundwater Corrective Action Application NCDENR 2013-10-11 Regulatory approval of Construction Quality Assurance for Closure NCDENR Modification, Permit No. 34-05 2014-02-04 Corrective Action Plan, Permit No. 34-05 ERM 2014-02-19 Regulatory approval of Corrective Action Plan NCDENR Various Groundwater and Surface Water Monitoring Summary Reports — 2010- ERM present www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. December 2020 Page 8 2020-09 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING SEMI-ANNUAL SUMMARY REPORT — SEPTEMBER 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina Figures Figure 1 Site Location Plan Figure 2 Site Plan Figure 3 Groundwater Flow Directions Figure 4 Groundwater Sampling Results — September 2019 Figure 5 Surface Water Sampling Results — September 2019 Figure 6 Sulfate Isocontour Map - Groundwater Figure 7 Hydrogeologic Conceptual Model Figure 8 Sulfate Trends - Groundwater Figure 9 Sulfate Trends — Surface Water Tables Table 1 Monitor Well Construction Details Table 2 Groundwater Elevations Table 3 Groundwater and Surface Water Sampling Event Summary Data Table 4 Groundwater Field Parameters REFERENCES www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. December 2020 Page 9 2020-09 Edwards Rd LF Rural Hall GW Report.docx 9 ! •, `dam I Cl Lr � '77 if n Feet r77' } t y - 0 y Legend Figure 1 U pCompliance Boundary ±� Limits of Permit Site Location Map Edwards Road Landfill Permit #34-05 R.J. Reynolds Tobacco Co. ERM NC, Inc. ERM www.erm.com 1:24,000 1 inch = 2,000 feet Rural Hall, North Carolina Source: Copyright:© 2013 National Geographic Society, i-cubed Coordinate System: NAD 1983 StatePlane North Carolina FIPS 3200 Feet $rzrx� x ,Jr N SS-80 aoo ,�.. PZ"g '> J @. Johnston SS-90 x SS-70 �" PZ"a O PZ-2 u�a, X a Beck SS-75 ef1�3 ss-40 Ural Hall r+ch SS-65 LA Legend PZ-1 a�.. i -35 O Saprolite/PWR Monitor Well n O Bedrock Monitor Well 1 � a Pne Y o ' Abandoned Monitor Well 'JSS-oz k Piezometer �� �W z E Soil Boring/Piezometer L M� Soil Boring R. J. P , PW-1 /� W_1 Guthrie �'' 4 Surface Water E Reynolds SSSp01+850� rE As -Built Landfill Contours (20r ) �D 44 '' n ,� Compliance Boundary S goo1�'`' ' Limits of Permit W a W-6 ,Tk '" t •� « SS-o1+550 Streams SS-50 Or B-5 *� Parcels PZ-10 PZ-6 Freeman _ ♦ / PZ"7 �3 Payne PZ-8 W-3B Notes PZ-9 Y 1. Contour interval is 20-ft. B 9 B-10 B-8 ss-95' Sprinkle 2. Limits of landfill are approximate based on # person available historic data. R. J. B-7 ♦_ ' SS-01+150 Frierson Reynolds _ � � .. '► 3. Streams estimated based on NC Floodplain z o ASS-01 `phipps Mapping Program, 2008 ci B_12 _ N , N Wagner W 4 W s B"11 SS-25 c ss-20 3F W-9 001 i o MB�y6� � { O m II o F Phipps v� @ k. n Q"' o Ken Stewart W c o W"5 SS-30 Kleitchens B-14 Q > 6 ❑ YKen Stewart n n Don Figure 2 Stewart g ss-10 Hawks Site Area Map ` Edwards Road Landfill @ Freedom' Dave Stewart Permit #34-05 Baptist Don Stewart Sewall R.J. Reynolds Tobacco Co. cnuron . Rural Hall, North Carolina SS-15 2 1:4,320 1 inch = 360 feet Freedom n 0° Baptist 3 0 180 360 540 9 Church ,{�rs,f ERM NC, Inc. i Feet J www.erm.com ERM j Source. NCOneMaD Data Services dmaaerv. Darcelsl. Forsvth Countv GIs Data Download (Streets. buildinasl Sources: Esri. HERE. Garmin. IntermaD. increment P Coro.. GEBCO. USGS. FAO. NPS. NRCAN. GeoBase, IGN, Kadaster NL. Ordnance Survev, Esri JaDan. METI. Esri China (Hong Koncl, (c) ODenStreetMaD contributors. and the GIS User Community Coordinate System: NAD 1983 StatePlane North Carolina RIPS 3200 Feel 1100 Johnston PZ-3 0 W-8 \ (810.55) L___"-PZ-4 Beck �a W-7 �AW4,` ((838.98) PZ-5 `` 0 Al � � ? PZ-1 _ o W-2 W-1 8 3.I24) ( / / (807.66) WGuthrie j' R. J. i ( Reynolds . / W-4 W-6 O } / � � 0 (880.66) I �000i ♦ , boo ♦ W-3 i ! (800.62) (803.82) oil Sprinkle Reynolds ``e ♦ ` Phipps 1 pp0 ~``tea �� v, (811.38) Boyd Ken Stewart o Phipps 7Ke, Stewart I KFreedom Hawks 0 a Freedom Dave Stewart Stewart Mozelle BaptistStewart Church O 1:4,320 1 inch = 360 eet 90o 00 180 360 540 Feet nis ayne Freeman Payne ural,Hall Legend O Saprolite/PWR Monitor Well O Bedrock Monitor Well A Piezometer Streams As -Built Landfill Contours (20') Compliance Boundary Limits of Permit Parcels Regional groundwater flow Local shallow groundwater flow Notes 1. Contour interval is 20-ft. 2. Limits of landfill are approximate based on i Wagner available historic data. Y' 3. Streams estimated based on NC Floodplain O, Mapping Program, 2008 m 4. Regional and Local Shallow Groundwater Flow based on groundwater modeling W(ERM, 2012) U Kleitchens ❑ Q Figure 3 Groundwater Flow Direction o ° Edwards Road Landfill Permit #34-05 R.J. Reynolds Tobacco Co. Rural Hall, North Carolina ERM NC, Inc. �d % r www.erm.com ERM -Source: NCOneMao Data Services (Imaaerv. oarcelsl. Forsvth Countv GIs Data Download (Streets. buildinasl Sources: Esri. HERE. Garmin. Intermao. increment P Coro.. GEBCO. USGS. FAO. NPS. NRCAN. GeoBase. IGN. Kadaster NL. Ordnance Survev, Esri Jaoan. METL Esri China (Nona Konal. (cl ODen StreetMao contributors, and the GIS User Community Iron Lead Lead I < to I W-08-WG-20200924 09/24/2020 Aluminum 940 Barium 180 Cadmium < 0.5 Chromium 13 Iron 1100 Lead < 1. Manganese 18 Selenium Sulfate 37,000 Dis solved Solids, Total 140,000 SS-80 PZ-3 SS-70�PZ-= P�2 / PZ-+5,_ SS-75'`� SS-40�J SS-60 4 ' SS-65 ` PZ_1 iolids Total 730,000 - N � � � SS-35 �► �'� ► r lss-o2 W-07-WG-20200924 09/24/2020 Aluminum 99 Barium 130 Cadmium < 0.5 Chromium 5.9 Iron 1.500 Lead < 1.. Manganese 37 Selenium < 5.0 Sulfate 11,000 Dissolved Solids Total 180,000 r SS-50 `• B-9 -� H1 B-11 B-10 O 2020 120 40 7.8 23o < 5.0 <S' NC 2L Groundwater Standard Aluminum (ug/L) 3,500 Barium (ug/L) 700 Cadmium (ug/L) 2 Chromium (ug/L) 10 Iron (ug/L) 300 Lead (ug/L) 15 Manganese (ug/L) 50 Selenium (ug/L) 20 Sulfate (ug/L) 250,000 Dissolved Solids, Total (ug/L) 500,000 \40 W \� /O1 S maS-01+1;50 y.._:.. O i B-5 a ASS-01+550 .... ,s S-95 ` 133' g �SS-01+150 B-7 SS-01 B12 `� V-� •f SS-20 SS-z5�ra O SS-30 ❑B-14 O ^ / SS-10 SS-15 41 W-09-WG-20200923 09/23/2020 Aluminum < 40.0 Barium 140 Cadmium < 0.5 Chromium < 5.0 Iron < 50.0 Lead < 1.0 Manganese < 5.0 Selenium < 5.0 Sulfate 11,000 9 O �k O, / (.A W-02-WG-20200924 09/24/2020 Aluminum 2,600 Barium 190 Cadmium < 0.5 Chromium < 5.0 Iron 4 300 Lead < 1.0 Manganese 370 Selenium < 5.0 Sulfate 19,000 Dissolved Solids. Total W-01-WG-20200924 Aluminum 73 Barium 24 Cadmium <0.5 - Chromium < 5.0 Iron 950 Lead < 1.0 Manganese 3,700 Selenium 26 Sulfate 1.000.000 Dissolved Solids Total 2 400 00 Barium W-03B-WG-20200924 09/24/2020 Aluminum < 40.0 Barium 54 Cadmium < 0.5 Chromium < 5.0 Iron 350 Lead < 1.0 Manganese 120 Selenium < 5.f Sulfate 19,000 Dissolved Solids, Total 260 000 N Dissolved Solids Total 190,000 �1 u n n 1:7,200 1 inch = 6p0 feet o RV�� NALL- r 0 300 600 900 0 o SRMANTON RD i Feet p e, Source: NCO neMaD Data Services (I macerv. Darcelsl. Forsvth Countv 31S Data Download (Streets. build inasl Sources: Esri. HERE, Garmin. IntermaD. increment P Coro.. GEBCO. USGS. FAO. NPS. NRCAN. GeoBase. IGN. Kadaster NL. Ordnance Survev, Esri JaDan. METL Esri China (Hong Konal. (cl ODenStreetMaD contributors. and the GIS User Communitv Ir. N / .oNO s; 1� Lilc Sethanr, . Legend O Saprolite/PWR Monitor Well O Bedrock Monitor Well O Abandoned Monitor Well z� Piezometer 0 Soil Boring/ Piezometer 1i Soil Boring 4 Surface Water Streams - As -Built Landfill Contours (20') triCompliance Boundary ~ Limits of Permit 0 Parcels Notes 1. Limits of landfill are approximate based on available historic data. 2. Streams estimated based on NC Floodplain Mapping Program, 2008 3. All concentrations in micrograms per liter w,. (ug/L) 4. Metals analyses in piezometer samples discontinued in September 2020 5. PZ-01, PZ-03, & PZ-04 were dry r 6. PZ-05 has been destroyed Figure 4 Groundwater Sampling Results - September 2020 Edwards Road Landfill Permit #34-05 R.J. Reynolds Tobacco Co. Rural Hall, North Carolina ERM NC, Inc. �d www.erm.com ERM SS-50-WS-20200923 09/23/2020 Aluminum 820 Barium 58 Cadmium < 0.5 Chromium < 5.0 Iron 4.400 Lead 1.1 Manganese 180 Selenium < 5.0 Sulfate 1 200 Dissolved Solids, Total 71 000 oanum Cadmium q � Chromium y Iron Lead xr. SS-70-WS-20200923 09/23/2020 Aluminum 170 Barium 57 Cadmium < 0.5 Chromium < 5.0 Iron 350 Lead < 1.0 Manganese Selenium 12 < 5.0 Sulfate 12 000 Dissolved Solids Total 96 000 SS-80-WS-20200923 09/23/2020 Aluminum 470 Barium 65 Cadmium < 0.5 Chromium < 5.0 Iron 840 Lead < 1.0 Manganese 17 Selenium < 5.0 Sulfate 10 000 Dissolved Solids, Total 120 000 niaur auoa ca Selenium < 5.0 Sulfate 9300 - Dissolved Solids Total 1 PZ-3 �a � SS-70 � PZ-4 _ . lO ... � PZ-2 o W-7 PZ-5 •SS-S 0 O `SS-60 �- a,Er SS-65 ', PZ_1 I -� lss-oz /W-2 /y- " W_1 p W-4 W-6 ' ii V B-4 SS-50 O B-5 �� SS-01+550 f 1 ♦ W-3 SS-95 ❑B 9 �- B_10 ` B-8 W-3B _ :•.. B-7 i SS-01+150 B-` \ � � SS-01 \,nr W-4W-6 B-11 SS-20 SS-25�r W_9 r O . + W-5 SS-30 NC 2B Surface Water Standard Aluminum (ug/L) 8,000 Barium (ug/L) 21,000 Cadmium (ug/L) 0.3 Chromium (ug/L) 50.1 Iron (ug/L) 1,000 Lead (ug/L) 1.49 Manganese (ug/L) 100 Selenium (ug/L) 5 Sulfate (ug/L) 250,000 Dissolved Solids, Total (ug/L) 500,000 m u r . n 1:7,200 a 1 inch = fi00 feet n 0 300 600 900 J Feet nicn.,onnan nary �o.�d5o� n.,,a„o.,, ti B-14 SS-10 SS-25-WS-20200923 09/23/2020 SS-15 4458 /� 58 V < 0.5 < 5.0 _ Aluminum Barium Cadmium Chromium Lead 1.8 r Manganese 60 Selenium,Q Sulfate 8 300 0 IY SS-30-WS-20200923 09/23/2020 Aluminum 3,800 Barium 81 Cadmium < 0.` Chromium < 5A Iron 4.300 Lead 1.4 Manganese 56 Selenium < 5. Sulfate 37,000 Dissolved Solids, Total 220,000 Aluminum Dissolved Solids. Total Aluminum ' a - Lead Manganese Selenium Sulfate Dissolved Solids Total a SS-02-WS-202009: Aluminum J, RG' Chromium Iron Lead Manganese Selenium Sulfate Dissolved Soli ;O SS-01-WS-20200923 09/23/2020 Aluminum 1,000 Barium 82 Cadmium < 0.5 Chromium Iron 1,400 Lead Manganese 25 Selenium Sulfate 31,000 Dissolved Solids Total 200,000 V G N e N i a f� Lilc Sethanr, +.A Legend O Saprolite/PWR Monitor Well O Bedrock Monitor Well O Abandoned Monitor Well � Piezometer 0 Soil Boring/Piezometer � Soil Boring 4 Surface Water Streams As -Built Landfill Contours (20') triCompliance Boundary Limits of Permit 0 Parcels Notes 1. Limits of landfill are approximate based on I available historic data. 2. Streams estimated based on NC Floodplain Mapping Program, 2008 3. All concentrations in micrograms per liter (ug/L) .. I Figure 5 Surface Water Sampling Results - April 2020 Edwards Road Landfill Permit #34-05 R.J. Reynolds Tobacco Co. Rural Hall, North Carolina ERM NC, Inc. ko www.erm.com ERM Coordinate System: NAD 1983 StatePlane North Carolina RIPS 3200 Feet arces: Esri, HERE, Garmin, Intermap, increment P Corp., GEBCO, USGS, FAO, NPS, NRCAN, GeoBase, IGN, Kadaster NL, Ordnance Survey, Esri Japan, METI, Esri China (Hong Kong), (c) OpenStreetMap contributors, and the CIS User Community n 3 Sulfate Concentrations - Most Recent n Monitoring Wells Piezometers Date Sulfate u IL PW-01 09/24/2020 330,000 W-01 09/24/2020 W-02 09/24/2020 19,000 W-03 09/24/2020 150.000 W-03B 09/24/2020 19.000 W-06 09/24/2020 9 000 W-07 09/24/2020 11000 W-08 09/24/2020 37 000 W-09 1 09/23/2020 11000 Date Sulfate u IL PZ-01 03/07/2016 110,000 PZ-02 09/23/2020 24,000 PZ-04 04/01/2020 37,000 PZ-05 04/01/2020 35,000 NC Groundwater & Surface Water Standard = 250,000 ug/L Previous sample collected from PZ-03 = 18,000. See tables and appendices for additional results. qlWillill Surface Water Date Sulfate u IL SS-01 09/23/2020 31000 SS-02 09/23/2020 49,000 SS-20 09/23/2020 8,000 SS-25 09/23/2020 1 8,300 SS-30 09/23/2020 37,000 SS-35 09/08/2015 170,000 SS-40 09/23/2020 42,000 SS-50 09/23/2020 1200 SS-60 09/23/2020 9,300 SS-65 09/08/2015 44,000 SS-70 09/23/2020 12,000 SS-75 09/08/2015 41000 SS-80 09/23/2020 10,000 SS-90 0912312020 24 000 SS-95 02124/2020 160 000 t� R. J. s Reynolds: J'" -+-SS-80 (10,000) W-08 (37,000) SS-70� SS-40• 24,00� (12,000) f (42,000) ( ) • 7� Payne • W-02 : r- �♦ (19,000) SS-02 (49,000) fi •�: PW-01 V1,000,000 -01 Guthrie`:: �(_ ) - " W,06 . ' ♦ Sprinkle (9,000) , �: W-03 19,000) . �� • �PSS-01, . ` �(311'000) Phipps trf 'd 5'C Payne Frye ieman G�� Frier�n lok CAA `) 0 �SS-20 �SS-25 O W-09 \ i S' 00 Boyd. (8,000) (8,300) (11,000) Phipps Kle itchens 6 10 o 'P0 SS-30 Ken Stewart •.,. V (37,000) z o00� Don Stewart . Ken Stewart 1�00 o Y � Hawks Dave �Q g 1000 Don Stewart Stewart N Freedom 1 4 Baptist `Mozelle g Church Stewart Freedom o Baptist goo ' Church 0 . o p ;0 U U 'n 1:7,200 1 inch = 800 feet m 9ao R �� FIA�� G �,, W a, o soo soo 900 �, �RMANrON Rp o . J Feet 9� i 9UU z 900 i `; i - s}. Source: NCOneMaD Data Services (Imaaerv. Darcels). Forsvth Countv GIS Data Download (Streets. buildings) Sources: Esri. HERE. Garmin. IntermaD. increment P Coro.. GEBCO. USGS. FAO. NIPS. NRCAN. GeoBase. IGN. Kadaster NL. Ordnance Survev. Esri JaDan`METL Esri China (Hong Kona). (c) ODen StreetMaD contributors. and the CIS User Communitv 1 N ey 0 �� . Legend D Saprolite/PWR Monitor Well O Bedrock Monitor Well Abandoned Monitor Well z�, Piezometer Le Soil Boring/Piezometer 4 Surface Water Water Supply Well Streams As -Built Landfill Contours (20') 9...pCompliance Boundary Limits of Permit 0 Parcels Sulfate Isoconcentration Contours > 250,000 ug/L > 750,000 ug/L Notes 1. Contour interval is 20-ft. 2. Limits of landfill are approximate based on available historic data. 3. Streams estimated based on NC Floodplain Mapping Program, 2008 Figure 6 Sulfate Isocontour Map Groundwater Edwards Road Landfill Permit #34-05 R.J. Reynolds Tobacco Co. Rural Hall, North Carolina ERM NC, Inc. �d www.erm.com ERM r hi AR I C74 CfofcPionc kith Comiino LIPS Q9nn P..f U 1000 0 950 Unnamed 900 Tributary aroli#e Sa #its ° p. o 850 :'+:•:�o::•••-1 r+_.-r , r+i r t + , r+. • :'�-�-'�o:".': -�'::!r.i .. to -� ', r+.-r, • ♦w - - -. - fy. r•y'e ,::�.,.: ...:. =.ter;';-.��;",-;� -� .�;�'; - °#�;:�:;::; -.�;�' .�_,-, .•_, 800 frr�r�• fr+,art• fr+stir r9,300•tirr�• 750 ` c 700 fC A' Synthetic Cap Installation 1000 Completed 3Q2012 0 IL 0 950 " ; • W-3B is Leak ° artesian �..-. �.. .=.;..:.:..-.:.< Creek �' #::: 850 f i �,r ', ��� � 1 jar • y to :: �. r#. .e .;ti'r`<<ti ,-ir l-, f ,-, p 00 SS +. r. -+. r + r . . , -r! ti r r r++-r•�-i:.. _ -, -i i r+.`r . r! .`r > > , r! ti` • , r+. r t , �'i;• `. ,-, •dijj ,-,`.� 150,000'i-y-'� i31,0001i.750 � _. ,- _+-.`• �,-,-.� r� . v r r gr rIN � d �, ,rfirr,• ,•, ir,,•, r+ir,+,r+ir,+, r+i` ,+,r+��,r+ir +i , 700 er ro?�'��.-.�.__+-.� �,-, ,_+,-,_,_•,-,_,_�,-, a __ ' W 650 hI� , .S��'i30o r'r r' 'r.'r'l '! r r`r .r ir; r .r�r; .r r 650 ' i� � ,r,r+, rr.r,r�, r+r���,�so. - -�'`+ti rrir, 1 r,r•ir ir,r+-irr�r,r�irr.r,r`. 600 Bedrock 30� hQ W-03B.++lrrr_1^r r^' 600 35,E?6 19000 %,=,_. =l.r' _ ,.. _ 55 - ,-- - ,---- ----- - ,-- ,-- ,-- ,-- - S"� S .- , ry r- ' r+•r,r,. r r, •r,r ,yr'' :'^rr k'-r'`i 'Rrr�. ° �r. ^ 7e ` ,ram , ; .. �,.i. .,~'�': •r,^ • .r. ^-�r. -.ram - ., _ ., _ r, _ �►r _. ., _ ., _ ,, 550 r ^L-��. ^,-��..��', �rirti+,r+ir�r,r+.-r�+,r+.-r�r,r+ir�r,rl.-r�r,rl�r�r,r+,-rtir, r+irti+, + .-r�r,r+�r�r,r+•-rtir, r+ir�r, �+���: r.-r �r,rr�r�r, ~~,r r+r,r rtir, 50D �'r, •'r, �'r, r,r�•+ 'r,r�,r 'r, �,r•'r, r•'r, �.r•'r, •'r, �'r, r,r�•+ 'r, �,r+'r, �,r•'r, ' r•'r, �,ry, �,r� r,i r,i "I",,rr, �ti'r,^� r•'r, r•'r r,^ r, 500 r , - , f r ti r r ' r r • r 'f_r: i' f r: - , f i • , , f , , r y ' , - �� , - ' , ti - ,'rtir , - _'r� . _ r� ^ _'ram ^ _ r` ti _ r` ti _'!' ti _r!' ti _ ! �.�. _ !� ^ _'r �r�, _ r r` ti _ r` ti _r!' ti _r!' �!`r�.r_ r�r r; r_'r� .l�,i,: !ti`r>>,rl5r�•,r+,rt•,r+•rt+,r+•r>>,r+,r>•+,r+,r�r,r+,`r�.,r!•`r�•,rl5r�•,r+,rt•,r+•rt+,r+•r�.,r+, r�+,r+, r�.,r+. r�.,rlti r�•,r �•, r+. rt•, r+•r7,, r>•+,r+, •,`, :4W: r,',rl, r>>,rrti r, rt•, ^J...-.`�.., -,, �.., r, �-., r, ��, .r ��,-',-• �-',• �-'-r �-'•r � `•.r � `•.r .r ; 1, _r �-', r �-'•r � `•.r � `•.r .r ; 1,-. � �, 450 450 ^'.,, •'r,r -'r,, r,, r,, -'r, ^'r,; ^'r,; ^'r,; •'r,r -'r,; r,; -'r,` •'r, ^'r,; ^'r,; ^'r,;-'r,;''r,; r,;_, ^'r,`�, •'r,;�1r^�^'-i,'r,;_, •'r,;_. rr,1,rri r�•,rr,Jrt•, 400 r •%- %- 400 0 125 250 375 500 625 750 875 1000 1125 1250 1375 1500 1625 1750 1875 2000 2125 2250 2375 2500 2625 2750 2875 3000 N A 55175 PZ-0 e- . W-, 55-]1 O Z-5 SSES4 P, 4 11 5S I 0" '� � ■ PWA W. BB. Z W-3 W-3B B-S 1 V B.7 ss-0, Biwd�� 2``~ Ss-25 �.;✓ 0 325 650 Feet Wa ss-3. A O W8 PZ-2' SSA. PZ1/ ;r 155-35 rSS 2 W9 \ n O , A' \ O Saprolite/PWR Monitor Well O Bedrock Monitor Well A, Piezometer 0 Soil Boring/ Piezometer 51 Soil Boring 4 Surface Water Regional Groundwater Flow L:.'Compliance Boundary Limits of Permit Sulfate Concentrations - Most Recent Monitoring Wells Piezometers Date Sulfate (ug/L) PW-01 09/24/2020 330,000 W-01 09/24/2020 1,000,000 W-02 09/24/2020 19,000 W-03 09/24/2020 150,000 W-03E 1 09/24/2020 19,000 W-06 09/24/2020 9,000 W-07 09/24/2020 11000 W-08 09/24/2020 37,000 W-09 09/23/2020 11000 Date Sulfate (ug/L) PZ-01 03/07/2016 110,000 PZ-02 09/23/2020 24,000 PZ-04 04/01/2020 37,000 PZ-05 04/01/2020 35,000 NC Groundwater & Surface Water Standard = 250,000 ug/L Previous sample collected from PZ-03 = 18,000. See tables and appendices for additional results. Surface Water Date Sulfate (ug/L) SS-01 09/23/2020 31,000 SS-02 09/23/2020 49,000 SS-20 09/23/2020 8,000 SS-25 09/23/2020 8,300 SS-30 09/23/2020 37,000 SS-35 09/08/2015 170,000 SS-40 09/23/2020 42,000 SS-50 09/23/2020 1200 SS-60 09/23/2020 9,300 SS-65 09/08/2015 44,000 SS-70 09/23/2020 12,000 SS-75 09/08/2015 41000 SS-80 09/23/2020 10,000 SS-90 1 09/23/2020 1 24,000 SS-95 1 02/24/2020 1 160,000 _+ Local Groundwater Flow _ Local Perched -� - Water Flow Bedrock Fracture Water Level Well Details Casing Screen Subsurface Details Landfill Confining Unit Saprolite Bedrock Bedrock Aquifer Notes: ? - Estimated /Assumed Vertical Exaggeration = 2:1 1 inch = 250 feet Figure 7 Hydrogeologic Conceptual Model Edwards Road Landfill Permit #34-05 R.J. Reynolds Tobacco Co. Rural Hall, North Carolina Environmental Resources Management w..erm.com ERM ug/L MONITORING WELL W-1 ^ 4,500,000 SAPROLITE AQUIFER Synthetic cap 4,000,000 installed 3Q2012 3,500,000 3,000,000 2,500,000 2,000,000 - 1,500,000 1,000,000 500,000 0 1 900 ^°�o°�,L ^°°A ^°°� ��oe°°o°°°b°°o°°o'Po "A MONITORING WELL W-313 1,200,000 T-- BEDROCK AQUIFER Synthetic cap nstalled 3Q201 1,000,000 800,000 600,000 400,000 - ti 200,000 ' r GW Elevation >804.53 (artesian) \Y� �-•� �r��IL 0 � � ti ti ti ti ti ti ti ti MONITORING WELL W-8 350,000 300,000 250,000 200,000 150,000 100,000 50,000 0 �O ft AMSL ug/L MONITORING WELL W-2 AMSL 818 °g/L 1,600,000 MONITORING WELL W-3 AMSL 815 4,000,000 T- SAPROLITE / PWR AQUIFER Synthetic cap 805 SAPROLITE / PWR AQUIFER Synthetic cap 814 3,500,000 installed 3Q2012 816 1,400,000 installed 3Q2012 804 813 814 803 3,000,000 1,200,000 812 812 802 811 2,500,000 1,000,000 810 801 810 2,000,000 M"=- 800,000 - 808 800 809 1,500,000 - - - 806 600,000 799 808 a ' 1,000,000 - 400,000 - 804 798 807 806 500,000 r _ -i YJ�yn� 802 zoo,000 _ ,.� - 797 805 0 800 0 796 11P e e 1 ^°'�`L ^°9b ^°'g0 ^°'g6 (y°°O (y° ry°°b ry°°6 ry°°0 ry°r�0 `y°^`L ry°fib°�6 (y°,�0 (y°r10 ft AMSL "� BACKGROUND MONITORING ft WELL W-4 & W-6 AMSL 810 800,000 $88 BEDROCK AQUIFER Synthetic cap 809 installed 3Q2012 700,000 886 808 600,000 W-4: 1995-2003 W : 2003-Present 884 807 500,000 806 882 400,000 805 880 300,000 - 804 878 200,000 803 100,000 876 802 ft AMSL 841 Synthetic cap installed 3Q2012 840 839 i 838 837 836 835 834 833 801 0 874 0 832 "WL MONITORING 1 250,000 BEDROCK AQUIFER, Installed 4Q2010 200,000 , 150,000 100,000 50,000 Aft MSL MONITORING WELL W-9 AMSL MONITORING WELL PWA 812 350,000 SAPROLITF AOUIFFR 810 3,500,000 810 300,000 Synthetic cap installed 3Q2012 808 3,000,000 808 250,000 806 2,500,000 806 200,000 804 2,000,000 804 150,000 802 1,500,000 802 100,000 i 800 1,000,000 800 50,000 798 500,000 798 0 796 0 00 90 °`1 41 a0 a0 00 oL ob °6 °0 O ^1. ^b ^0 ^4 O LEGEND NC2L GW STD NC213 SW STD FIGU Sulfates 250,000 ug/L 250,000 ug/L SULFATE TRENDS - GROUNDWATER ❑ Total Dissolved Solids 500,000 ug/L 500,000 ug/L ERM NC, Inc. EDWARDS ROAD LANDFILL - PERMIT # 34-05 Groundwater Table Elevation (above Mean Sea Level) vPw -erm-4cGm ERM RURAL HALL, NORTH CAROLINA ft AMSL 866 864 862 860 858 856 854 852 850 ug/L SURFACE WATER SS-01 1,400,000 Synthetic cap 1,200,00o installed 3Q2012 1,000,000 800,000 600,000 400,000 200,000 AMR K 0 00 O° 0�' Off` OrO 00 O° Off' Off` 06 00 ^O ^'L ,mob ^6 ^0 O ug/L SURFACE WATER SS-30 400,000 Synthetic cap 350,000 installed 3Q2012 300,000 250,000 200,000 1\13 1 V 150,000 V 100,000 50,000 0 ug/L SURFACE WATER SS-70 250,000 200,000 150,000 100,000 50,000 ug/L SURFACE WATER SS-02 1,000,000 900,000 800,000 700,000 600,000 500,000 400,000 300,000 200,000 100,000 0 00 O`L 9b 06 90 00 O`L OP 00 00 ^O $, 111 ^O ^O O �O �O �O �O �O �O �O �O �O �O ug/L SURFACE WATER SS-40 800,000 Synthetic cap 700,000 installed 3Q2012 600,000 500,000 400,000 300,000 - 200,000 100,000 0 O9 O ^^ ^y ^O ^� ^h ^O ^� ^O ^9 ry0 1^ ,yo �o^ ug/L SURFACE WATER SS-80 300,000 Synthetic cap installed 3Q2012 250,000 200,000 150,000 100,000 - V 50,000 0 1 v 0 ,O9 o^O o^^ �o 0 �o do yo do yo yo yo ^yo yo yo yo ,o^do^yo yo yo^O o o^o o o yoti LEGEND NC21- GW STD NC213 SW STD Sulfates 250,000 ug/L 250,000 ug/L 0 Total Dissolved Solids 500,000 ug/L 500,000 ug/L ug/L SURFACE WATER SS-25 180,000 160,000 Synthetic installed cap 3Q2012 140,000 120,000 100,000 80,000 60,000 40,000 20,000 0 ug/L SURFACE WATER SS-60 800,000 Synthetic cap 700,000 installed 3Q2012 600,000 500,000 400,000 300,000 200,000 A A4 100,000 V- 0 ug/L SURFACE WATER SS-90 600,000 Synthetic cap 500,000 installed 3Q2012 400,000 300,000 • 200,000 100,000 0 TABLE 1 MONITOR WELL CONSTRUCTION DETAILS EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 1 of 1 Outer Ground TOC Boring Casing Screened Geologic Well Install Elevation Elevation Depth Depth Interval Zone ID Date Latitude Longitude (ft MSL) (ft MSL) (ft BGL) (ft BGL) (ft BGL) Screened Comments Former supply well, pump removed (8/09): 6 inch dia. gals. casing; Construction details per 405 Clayton Well Drilling log and video inspection by ERM (8/09 & 4/10); Open rock to 405 ft, Total PW-1 5/26/87 36.2499455° -80.2779362° 920.51 920.66 (soft bottom 21.5 21.5-405 Bedrock well yield 25 gpm with no other obvious water -bearing zones below 103 ft (Clayton). Silted in to 819.69 at 326) 326 ft (video). W-1 10/13/87 36.2500121° -80.2757441' 822.68 20.5 NA 10-20 Saprolite 2 inch dia. PVC, Well replaced 11/93, DWM permit -required sample location W-2 12/6/89 36.2504070° -80.2753700' 824.21 827.30 17 NA 7-17 Sap/PWR 2 inch dia. PVC, DWM permit -required sample location, (alternate IDs MW-1A, RH-MW-002) W-3 12/7/89 36.2486237' -80.2761346' 802.00 804.43 17 NA 7-17 Sap/PWR 2 inch dia. PVC, DWM permit -required sample location, (alternate IDs W-3A, W-2A, RH-MW-003) W-3B 5/14/04 36.2485693° -80.2761875' 801.23 804.32 210 Unknown 190-210 Bedrock 2 inch dia. PVC, DWM permit -required sample location, Artesian well W-4 6/8/93 36.24693455' -80.28491769° � NE NE 188 NA 138-188 Bedrock 2 inch dia. PVC, damaged, abandoned 8127103, former background well, replaced with W-6 in 2003. W-5 5/17/93 36.24629033° " -80.27862892° * NE NE 24 NA 13-23.5 Bedrock 2 inch dia PVC, Phase 3 permanent MW W-6 8/22/03 36.2490276' -80.2819968' 977.93 980.71 200 NA 170-200 Bedrock 2 inch dia. PVC, DWM permit -required sample location, (alternate IDs MW-6), current background well, replaced W-4 as background well in 2003 W-7 12/15/10 36.2517944° -80.2798058' 929.51 931.58 341 NA 42-341 Bedrock 6 inch dia. open -rock hole, 6" galavanized casing to 42 ft bgs, TOC value for 6" casing W-8 12/14/10 36.2524760° -80.2744895' 859.39 861.67 129 NA 45-65 PWR 2 inch dia. PVC W-9 12/13/10 36.2469581° -80.2750675' 909.35 911.38 259 NA 229-259 Bedrock 2 inch dia. PVC, Ken Stewart's pasture, B-9 5/20/93 36.24819778' " -80.28420462° " NE NE 23 NA 18-22.5 Saprolite 2 inch dia PVC, Phase 3 temporary piezometer, abandoned Dec. 2019 B-10 5/19/93 36.24815194' ` -80.28243419' * NE NE 14 NA 9-13.5 Saprolite 2 inch dia PVC, Phase 3 temporary piezometer, not located Oct. 2009 or Dec. 2019 B-11 5/20/93 36.24695712' " -80.28385595° ' NE NE 54 NA 48-53 Saprolite 2 inch dia PVC, Phase 3 temporary piezometer, not located Dec. 2019 B-12 5/19/93 36.24765518° -80.28079913° * NE NE 8.5 NA 3.5-8 Saprolite 2 inch dia PVC, Phase 3 temporary piezometer, no protective well box around well B-14 5/20/93 36.2461299° * -80.28188639° " NE I NE 54 NA 48-53 Saprolite 2 inch dia PVC, Phase 3 temporary piezometer, abandoned Dec. 2019 PZ-1 3/15/16 36.25134616' -80.2740505' ' NE NE 1.5 NA 1.0 - 1.5 Alluvium 1 inch dia PVC temporary piezometer. Originally installed 12/2010. Replaced 3/2016 PZ-2 12/15/10 36.25229952' ' -80.27330537' ' NE NE 4.0 NA 3.0 - 4.0 Alluvium 1 inch dia PVC temporary piezometer PZ-3 12/15/10 36.25292715' -80.27477259' ' NE NE 1.5 NA 0.5 - 1.5 Alluvium 1 inch dia PVC temporary piezometer PZ-4 12/16/10 36.25225065' ' -80.27644449' ' NE NE 5.0 NA 4.2 - 5.0 Alluvium 1 inch dia PVC temporary piezometer PZ-5 12/16/10 36.25178958' -80.27767072' ' NE NE 5.0 NA 3.0 - 5.0 Alluvium 1 inch dia PVC temporary piezometer PZ-6 2/18/20 NE NE NE 834.3' 3.5 NA 1.5 - 3.5 Fill/Saprolit 1 inch dia PVC temporary piezometer installed for boil evaluation at ST-1 PZ-7 2/18/20 NE NE NE 833.7 * 4.5 NA 1.5-4.5 Fill/Saprolit 1 inch dia PVC temporary piezometer installed for boil evaluation at ST-1 PZ-8 2/18/20 NE NE NE 830.7' 5.0 NA 2.0 - 5.0 Fill/Saprolit 1 inch dia PVC temporary piezometer installed for boil evaluation at ST-1 PZ-9 2/18/20 NE NE NE 834.6 * 4.5 NA 1.5-4.5 Fill/Saprolit 1 inch dia PVC temporary piezometer installed for boil evaluation at ST-1 PZ-10 2/24/20 NE NE NE 839.9' 4.0 NA 1.0 - 4.0 Fill/Saprolit 1 inch dia PVC temporary piezometer installed for boil evaluation at ST-1 NE - Not Established BGL - Below ground level NM - Not Measured MSL - above mean sea level BTOC - Below top of casing " - Estimated value RJRTI Tables RJRT Ash LF.xlsAl. Well Construction PWR = Partially Weathered Rock Survey data by Lawrence Associates, P.A., January 4, 2010, January 4, 2011 & February 28, 2011 TABLE 2 GROUNDWATER ELEVATIONS EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 1 of 4 Monitor Well ID TOC Elevation Start Screen Depth End Screen Depth Geologic Unit PW-01 W-01 W-02 W-03 W-03B 920.7 822.7 827.3 804.4 804.3 21.5 10 7 7 190 405 20 17 17 210 Bedrock Saprolite Saprolite/PWR Saprolite/PWR Bedrock - Artesian Date Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) 2006-10-19 11.59 811.09 13.32 813.98 7.54 796.89 Artesian -- 2007-04-27 10.88 811.80 13.96 813.34 6.98 797.45 Artesian -- 2007-11-19 13.29 809.39 16.08 811.22 7.78 796.65 Artesian -- 2008-04-30 12.84 809.84 14.68 812.62 7.04 797.39 Artesian -- 2009-04-30 -- -- 13.23 809.45 15.18 812.12 7.12 797.31 Artesian -- 2009-10-12 72.00 848.66 14.53 808.15 17.50 809.80 7.63 796.80 -1.22 805.54 2010-04-19 67.00 853.66 10.75 811.93 14.16 813.14 6.37 798.06 -1.05 805.37 2010-10-11 -- -- 12.04 810.64 15.85 811.45 6.99 797.44 -0.89 805.21 2011-01-05 -- -- 11.97 810.71 13.53 813.77 6.88 797.55 -0.98 805.30 2011-02-28 65.30 855.36 11.66 811.02 14.57 812.73 6.65 797.78 -1.37 805.69 2011-04-20 64.75 855.91 10.92 811.76 14.05 813.25 6.25 798.18 -1.63 805.95 2011-10-17 -- -- 12.55 810.13 15.18 812.12 7.24 797.19 -1.36 805.68 2012-02-06 64.96 855.70 11.97 810.71 13.52 813.78 6.52 797.91 Artesian -- 2012-03-16 -- -- 11.95 810.73 15.45 811.85 6.64 797.79 Artesian -- 2012-09-24 66.03 854.63 11.93 810.75 15.36 811.94 4.87 799.56 Artesian 2013-04-17 65.80 854.86 11.98 810.70 14.03 813.27 4.51 799.92 Artesian 2013-09-10 66.75 853.91 13.01 809.67 15.75 811.55 3.45 800.98 Artesian 2014-04-07 56.15 864.51 11.74 810.94 16.76 810.54 3.29 801.14 Artesian 2014-09-03 67.28 853.38 14.37 808.31 16.65 810.65 3.29 801.14 Artesian 2015-04-02 64.75 855.91 13.29 809.39 13.93 813.37 3.78 800.65 Artesian 2015-09-08 -- -- -- -- 2015-09-10 65.49 855.17 15.18 807.50 17.01 810.29 4.20 800.23 Artesian -- 2016-03-08 62.75 857.91 12.42 810.26 13.32 813.98 2.80 801.63 Artesian -- 2016-09-06 67.21 853.45 14.92 807.76 16.68 810.62 3.31 801.12 Artesian -- 2017-03-27 65.34 855.32 15.50 807.18 15.33 811.97 3.89 800.54 Artesian -- 2017-09-25 65.50 855.16 16.02 806.66 16.89 810.41 3.32 801.11 Artesian -- 2018-03-05 66.00 854.66 16.10 806.58 11.90 815.40 4.45 799.98 Artesian -- 2018-09-12 65.44 855.22 15.88 806.80 16.95 810.35 4.24 800.19 Artesian -- 2019-03-19 61.00 859.66 11.20 811.48 6.23 821.07 1.88 802.55 0.00 804.32 2019-03-20 -- -- -- -- 2019-09-03 65.50 855.16 15.05 807.63 16.23 811.07 3.19 801.24 0.00 804.32 2020-02-13 67.61 853.05 10.31 812.37 5.03 822.27 2.98 801.45 0.21 804.11 2020-02-18 67.00 67.02 853.66 853.64 11.76 11.8 810.92 810.88 6.11 6.12 821.19 821.18 3.24 3.24 801.19 801.19 0.07 0.08 804.25 804.24 2020-02-24 66.70 853.96 12.81 809.87 6.13 821.17 3.38 801.05 0.20 804.12 2020-03-04 66.82 853.84 12.29 810.39 6.29 821.01 3.43 801.00 0.21 804.11 2020-03-31 66.38 854.28 13.28 809.40 13.23 814.07 3.43 801.00 1.05 803.27 2020-09-22 67.42 853.24 15.02 807.66 15.38 811.92 3.81 800.62 0.50 803.82 TABLE 2 GROUNDWATER ELEVATIONS EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 2 of 4 Monitor Well ID TOC Elevation Start Screen Depth End Screen Depth Geologic Unit W-05 W-06 W-07 W-08 W-09 980.7 931.6 861.7 911.4 13 170 42 45 229 23.5 200 341 65 259 Bedrock Bedrock Bedrock PWR Bedrock Date Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) 2006-10-19 99.00 881.71 -- -- -- -- -- -- 2007-04-27 94.48 886.23 -- -- -- -- -- -- 2007-11-19 105.00 875.71 - -- -- -- -- -- 2008-04-30 99.29 881.42 -- -- -- -- -- -- 2009-04-30 -- 98.28 882.43 -- -- -- -- -- -- 2009-10-12 10.08 99.64 881.07 -- -- -- -- -- -- 2010-04-19 8.38 98.29 882.42 -- -- -- -- -- -- 2010-10-11 9.73 98.93 881.78 -- -- -- -- -- -- 2011-01-05 9.67 98.92 881.79 94.73 836.85 52.67 809.00 110.47 800.91 2011-02-28 9.50 99.01 881.70 94.59 836.99 53.45 808.22 112.03 799.35 2011-04-20 7.85 98.42 882.29 94.20 837.38 53.54 808.13 110.03 801.35 2011-10-17 -- 99.41 881.30 -- -- -- -- -- -- 2012-02-06 99.22 881.49 94.71 836.87 54.74 806.93 109.84 801.54 2012-03-16 99.05 881.66 -- -- -- -- -- -- 2012-09-24 99.63 881.08 96.05 835.53 55.47 806.20 110.26 801.12 2013-04-17 99.04 881.67 95.80 835.78 57.40 804.27 108.62 802.76 2013-09-10 98.86 881.85 94.71 836.87 54.20 807.47 110.23 801.15 2014-04-07 98.23 882.48 95.26 836.32 54.01 807.66 110.86 800.52 2014-09-03 98.93 881.78 94.90 836.68 52.78 808.89 110.68 800.70 2015-04-02 99.45 881.26 94.52 837.06 56.22 805.45 110.50 800.88 2015-09-08 -- -- -- -- 58.22 803.45 110.50 800.88 2015-09-10 99.51 881.20 95.23 836.35 -- -- -- -- 2016-03-08 98.62 882.09 93.95 837.63 59.01 802.66 110.06 801.32 2016-09-06 98.90 881.81 94.05 837.53 53.19 808.48 110.11 801.27 2017-03-27 99.10 881.61 94.41 837.17 56.00 805.67 109.90 801.48 2017-09-25 99.68 881.03 95.01 836.57 56.96 804.71 109.30 802.08 2018-03-05 99.94 880.77 94.60 836.98 60.60 801.07 110.30 801.08 2018-09-12 100.05 880.66 94.83 836.75 61.60 800.07 110.33 801.05 2019-03-19 -- -- 2019-03-20 98.59 882.12 92.07 839.51 58.35 803.32 110.06 801.32 2019-09-03 99.46 881.25 92.98 838.60 52.28 809.39 109.54 801.84 2020-02-13 93.41 887.30 91.72 839.86 53.37 808.30 -- -- 2020-02-18 99.14 99.12 881.57 881.59 92.08 92.09 839.5 839.49 53.34 53.33 808.33 808.34 2020-02-24 99.13 1 881.58 1 92.25 1 839.33 1 53.45 1 808.22 1-- -- 2020-03-04 99.14 881.57 92.23 839.35 53.49 808.18 -- -- 2020-03-31 99.00 881.71 91.81 839.77 52.99 808.68 1 110.00 801.38 2020-09-22 100.05 880.66 92.60 838.98 51.12 810.55 100.00 811.38 TABLE 2 GROUNDWATER ELEVATIONS EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 3 of 4 Monitor Well ID TOC Elevation Start Screen Depth End Screen Depth Geologic Unit B-09 B-12 PZ-06 PZ-07 PZ-08 834.3 833.7 830.7 18 3.5 1.5 1.5 2 22.5 8 3.5 4.5 5 Saprolite Saprolite Fill Soil/Saprolite Fill Soil/Saprolite Fill Soil/Saprolite Date Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) 2006-10-19 2007-04-27 2007-11-19 2008-04-30 2009-04-30 -- -- 2009-10-12 20.40 10.26 -- -- -- -- -- -- -- 2010-04-19 18.78 6.18 2010-10-11 21.63 9.40 2011-01-05 22.05 9.05 2011-02-28 22.63 -- 2011-04-20 21.45 5.46 2011-10-17 -- -- 2012-02-06 2012-03-16 2012-09-24 2013-04-17 2013-09-10 2014-04-07 2014-09-03 2015-04-02 2015-09-08 2015-09-10 2016-03-08 2016-09-06 2017-03-27 2017-09-25 2018-03-05 2018-09-12 2019-03-19 2019-03-20 2019-09-03 2020-02-13 Dry Dry Dry 2020-02-18 2020-02-24 Dry Dry Dry 2020-03-04 8.87 825.40 9.69 824.01 Dry 2020-03-31 8.84 825.43 9.39 824.31 Dry 2020-09-22 TABLE 2 GROUNDWATER ELEVATIONS EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Monitor Well ID TOC Elevation Start Screen Depth End Screen Depth Geologic Unit PZ-09 PZ-10 834.6 839.9 1.5 1 4.5 4 Fill Soil/Saprolite Fill Soil/Saprolite Date Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) 2006-10-19 2007-04-27 2007-11-19 2008-04-30 2009-04-30 2009-10-12 2010-04-19 2010-10-11 2011-01-05 2011-02-28 2011-04-20 2011-10-17 2012-02-06 2012-03-16 2012-09-24 2013-04-17 2013-09-10 2014-04-07 2014-09-03 2015-04-02 2015-09-08 2015-09-10 2016-03-08 2016-09-06 2017-03-27 2017-09-25 2018-03-05 2018-09-12 2019-03-19 2019-03-20 2019-09-03 2020-02-13 Dry Dry 2020-02-18 -- -- 2020-02-24 Dry 9.25 830.64 2020-03-04 Dry 8.64 831.25 1 Dry 8.70 831.19 H202020-03-31 20-09-22 -- -- -- -- Notes: NE = Not Established MSL = above mean sea level BTOC = Below Top of Casing PWR = Partially Weathered Rock BGL - Below ground level Artesian condition - Value represents water level above permanent TOC. Measured via temporary standpipe installed on permanent casing. Page 4 of 4 TABLE 3 GROUNDWATER AND SURFACE WATER ANALYTICAL RESULTS EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA 1 of 1 N N 0 � j 7 N N C E d E 7 E 0 0 N O Analyte O a •L m '6 U L U C la - i N in � cn N .6+ H NC 2L Groundwater Standard 3,500 700 2 10 300 15 50 20 250,000 500,000 NC 213 Surface Water Standard 8,000 21,000 0.3 50.1 1,000 1.49 100 5 250,000 500,000 Sample I Location/ID Sample Date Groundwater Monitoring Wells PW-01 9/24/2020 360 56 < 0.5 9.6 1,000 < 1 190 19 330,000 730,000 W-01 9/24/2020 73 24 < 0.5 < 5 950 < 1 3,700 26 1,000,000 2,400,000 W-02 9/24/2020 2,600 190 < 0.5 < 5 4,300 < 1 370 < 5 19,000 130,000 W-03 9/24/2020 < 40 29 < 0.5 < 5 100 < 1 120 10 150,000 460,000 W-03B 9/24/2020 < 40 54 < 0.5 < 5 350 < 1 120 < 5 19,000 260,000 W-06 9/24/2020 120 40 < 0.5 7.8 230 < 1 < 5 < 5 9,000 290,000 W-07 9/24/2020 99 130 < 0.5 5.9 1,500 < 1 37 < 5 11,000 180,000 W-08 9/24/2020 940 180 < 0.5 13 1,100 < 1 18 < 5 37,000 140,000 W-09 9/23/2020 < 40 140 < 0.5 < 5 < 50 < 1 < 5 < 5 11,000 190,000 PZ-01 9/23/2020 Dry, no sample collected I -- I -- -- -- -- -- -- -- PZ-02 9/23/2020 1 Metals analyses in piezometer samples discontinued 9/2020 -- -- -- 24,000 180,000 PZ-03 9/23/2020 Dry, no sample collected -- -- -- -- -- -- -- -- PZ-04 9/23/2020 Dry, no sample collected -- -- -- -- -- -- -- -- PZ-05 9/23/2020 Destroyed, no sample collected -- -- -- -- -- -- -- Surface Water SS-01 9/23/2020 1,000 82 < 0.5 < 5 1,400 < 1 25 < 5 31,000 200,000 SS-02 9/23/2020 1,200 74 < 0.5 < 5 1,400 < 1 39 < 5 49,000 230,000 SS-20 9/23/2020 4,800 59 < 0.5 < 5 6,000 2 88 < 5 8,000 120,000 SS-25 9/23/2020 4,400 58 < 0.5 < 5 4,900 1.8 60 < 5 8,300 110,000 SS-30 9/23/2020 3,800 81 < 0.5 < 5 4,300 1.4 56 < 5 37,000 220,000 SS-40 9/23/2020 550 73 < 0.5 < 5 740 < 1 22 < 5 42,000 230,000 SS-50 9/23/2020 820 58 < 0.5 < 5 4,400 1.1 180 < 5 1,200 71,000 SS-60 9/23/2020 200 53 < 0.5 < 5 490 < 1 25 < 5 9,300 110,000 SS-70 9/23/2020 170 57 < 0.5 < 5 350 < 1 12 < 5 12,000 96,000 SS-80 9/23/2020 470 65 < 0.5 < 5 840 < 1 17 < 5 10,000 120,000 SS-90 1 9/23/2020 1 200 1 64 1 < 0.5 < 5 400 < 1 17 < 5 1 24,000 1 140,000 Notes: All concentrations in micrograms per liter (pg/L) unless otherwise noted. NE - Not established No freshwater aquatic life standard established for barium, manganese, sulfate, and dissolved solids. Water Supply criteria presented. Bold with gray background indicates exceedance of applicable NC Groundwater or Surface Water Standard TABLE 4 GROUNDWATER AND SURFACE WATER FIELD PARAMETER RESULTS EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA E 0 o ` r N H G1 x L) z W E O r (C U) '-' ++ O f0 d fA = M C ' N Z a r Analyte Q- � :2. v il O ao o E NC 2L Groundwater Standard 6.5-8.5 NE NE NE NE NE NC 2B Surface Water Standard 6.0-9.0 NE NE NE NE NE Sample Location/ID I Sample Date Groundwater Monitoring Wells PW-01 9/24/2020 6.0 15.4 954 6.1 214 3.8 W-01 9/24/2020 6.6 16.5 2517 4.6 -61.8 0.62 W-02 9/24/2020 5.6 17.0 127 10.4 -35.1 2.4 W-03 9/24/2020 6.2 16.3 648 0.35 129 0.70 W-03B 9/24/2020 7.6 16.0 392 0.73 185 0.23 W-06 9/24/2020 9.3 15.6 387 6.1 -76.9 0.75 W-07 9/24/2020 7.0 15.1 208 17.6 -81.6 4.2 W-08 9/24/2020 7.7 15.5 166 16.8 47.8 6.70 W-09 9/23/2020 11.2 17.7 473 0.61 -138 0.44 Surface Water SS-01 9/23/2020 7.7 15.5 316 34.2 16.7 7.1 SS-02 9/23/2020 8.0 15.6 372 28.4 9.0 7.3 SS-20 9/23/2020 6.9 15.7 129 85.6 1280 7.3 SS-25 9/23/2020 6.8 15.6 125 91.0 1157 7.5 SS-30 9/23/2020 7.5 15.5 340 61.1 18.2 7.5 SS-40 9/23/2020 8.1 15.2 297 22.4 2.5 7.0 SS-50 9/23/2020 7.3 15.1 68.3 28.0 1470 8.0 SS-60 9/23/2020 8.6 15.5 119 6.1 -8.8 6.9 SS-70 9/23/2020 8.2 15.7 75.4 5.6 12.8 8.3 SS-80 9/23/2020 8.0 15.1 123 9.5 19.1 9.0 SS-90 9/23/2020 8.5 14.8 209 10.7 40.8 9.7 Notes: All concentrations in micrograms per liter (pg/L) unless otherwise noted. NE - Not established No freshwater aquatic life standard established for barium, manganese, sulfate, and dissolved solids. Water Supply criteria presented. Bold with gray background indicates exceedance of applicable NC Groundwater or Surface Water Standard 1 of 1 APPENDIX A HISTORICAL GROUNDWATER AND SURFACE WATER QUALITY ANALYTICAL DATA www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. December 2020 2020-09 Edwards Rd LF Rural Hall GW Report.docx APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 1 of 10 Analyte 3 c .E 7 a c d N i a E = 'C 10 m E ' E "O c6 U _3 E O i L L) `m C. C. O L) C O '6 d -j a> °� @ C R a U L d 2 E .E N N rn d > in t� C N Z cv m cv w z m w 7 U) N y y > O '� ❑ r O o 0 R ) O a@. O fn 2 C N N U N m w @ m C_ E N E_ U) - w c O U w U d C. U) ❑ Z r 3 > E � d O a c C m d' O "6 x O J rn E C �+ x O aD O N N o C 2L Ground Water Standard 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 10,000 250,000 500,000 NE 6.5-8.5 NE NE NE NE NE Sample Date W-01 4/29/1988 8,030 235 8 16 17,400 1,100 31 -- 130,000 156,000 2,240 5.9 W-01 7/13/1989 -- 100 -- -- -- 5 -- -- -- -- -- -- W-01 9/24/1990 5,620 189 8,900 150 59 13,500 185,000 13,000 6.3 19.3 195 - W-01 10/24/1991 161 346 150 97 23.9 126,000 303,000 12,000 6.2 20.3 425 - W-01 3/26/1992 2,850 736 833 1,830 0.32 21.9 38 123,000 482,000 14,000 6.6 9.3 682 - W-01 9/30/1992 -- 120 -- 310 32 292,000 798,000 5,000 5.9 17.8 1153 - W-01 3/31/1993 364 137 1,130 2,230 13.2 33 486,000 1,169,000 33,000 5.5 16.1 1587 - W-01 9/17/1993 28,600 697 3.8 44 59,700 13 3,490 5.1 195 565,000 1,643,000 6,000 5.9 18.0 2310 - W-01 3/30/1994 5,320 545 1 20 1 18,800 8 505 6 1 107 633,000 1,680,000 -- 5.6 15.2 1250 - W-01 9/30/1994 1,810 22 9,960 4,470 13 19 758,000 2,420,000 123,000 6.0 18.1 3010 - W-01 3/31/1995 24,000 1,250 26 53,900 11 1,580 12 115 797,000 2,140,000 -- 5.9 15.8 2820 - W-01 9/29/1995 7,650 367 4 24 18,800 10 4,020 12 -- 464,000 2,780,000 4,040 4.5 16.2 3720 - W-01 3/20/1996 149,000 960 50 200 220 -- 63 11,400 695 2,320,000 2,670,000 8,750 6.5 15.0 3060 - W-01 9/27/1996 7,110 22,600 7 2,300 51 1,320,000 2,970,000 3,810 6.1 19.0 3350 - W-01 3/29/1997 2,990 -- 16 2,340 72 1,360,000 25860,000 6,870 6.0 14.0 1890 - W-01 9/17/1997 2,940 3 12,900 6 3,680 33 136 1,300,000 35110,000 5,290 6.3 17.0 3540 - W-01 3/27/1998 2,400 7,830 2,340 16 1,060,000 3,040,000 3,640 6.5 19.6 627 - W-01 9/30/1998 2,350 5,180 15 2,710 21 1,030,000 3,210,000 17,500 6.2 20.0 1250 - 6.36 20.8 W-01 9/30/1998 1,250 4,980 2,720 30 1,040,000 3,320,000 9,250 -- -- -- - - -- W-01 3/31/1999 1,820 4,690 10 2,450 15 1,830,000 3,230,000 8,820 5.6 17.0 1610 - W-01 (FD) 3/31/1999 1,170 4,200 2,560 18 1,920,000 3,230,000 3,730 -- -- -- W-01 9/29/1999 1,650 4,780 8 2,790 31 2,060 3,440,000 3,730 5.7 19.0 1980 - W-01 3/16/2000 1,820 3,360 6 2,840 31 1,390,000 3,330,000 3,930 -- -- -- W-01 9/15/2000 979 3,200 8 2,930 22 1,540,000 3,480,000 13,300 5.8 18.0 1040 - W-01 3/23/2001 226 1,860 10 3,180 1,260,000 3,320,000 6,130 6.2 17.0 1090 - W-01 10/4/2001 728 2 3,140 9 2,890 37 1,420,000 3,380,000 31,000 8.0 21.0 3300 - - - W-01 3/28/2002 1,010 20 3,600 8 3,270 48 1,220,000 3,310,000 3,430 6.0 15.0 1090 - W-01 (FD) 3/28/2002 5,450 3,580 1,050,000 2,920,000 3,430 6.0 15.0 1090 - W-01 10/3/2002 8,960 2 14,000 8 3,910 51 1,330,000 3,210,000 3,190 6.3 18.0 1280 - W-01 3/25/2003 1,420 2,770 7 3,540 25 1,130,000 3,310,000 3,210 6.4 19.0 910 - W-01 10/2/2003 402 414 1 2,330 5 3,840 1,350,000 3,470,000 3,520 5.9 20.0 3210 - W-01 4/28/2004 1,440 6,890 12 3,920 1,350,000 3,580,000 5,130 -- 15.1 3670 - W-01 10/26/2004 7,450 21 20,100 10 4,800 1,310,000 3,630,000 3,100 - - 3510 - W-01 4/27/2005 697 2 3,990 10 4,080 1,820,000 3,601,000 3,450 - - 3610 - W-01 10/20/2005 9,030 283 18,400 15 3,920 104 790,000 3,520,000 52,000 - - 2370 - W-01 10/19/2006 214 926 6 4,160 56 1,790,000 3,310,000 3,740 - - 2120 - W-01 4/27/2007 787 1,250 3,550 1,300,000 3,390,000 6,350 - - 4510 - W-01 11/19/2007 186 778 4,080 1,950,000 3,430,000 3,950 - - 3460 - W-01 4/30/2008 291 536 3,870 1,920,000 3,410,000 2,990 - - 3590 - W-01 (FD) 4/30/2008 349 698 3,910 1,860,000 3,380,000 2,850 - 3600 - W-01 10/29/2008 25.8 0.32 427 4.9 3,990 1,640,000 3,310,000 4,950 - 3840 - W-01 4/30/2009 30.5 3.44 4.9 599 13.1 4,560 1.44 1,890,000 3,370,000 6,060 - 3860 - W-01 10/12/2009 98 J 2.9 J 22 J 1 2 J 1.1 410 4,000 0.5 J 280 1,500,000 3,100,000 -- 6.1 14.9 4620 14 87 3.32 W-01 4/20/2010 3,500 130 12 6,000 4,200 -- 1,500,000 3,100,000 56,500 6.1 16.5 11800 57.9 119 W-01 10/11/2010 63 J 6.7 27 0.9 J 300 1.3 J 5,000 33 1.3 J 12 780 1,400,000 3,100,000 -- 6.1 20.4 2990 110 147 W-01 4/22/2011 470 6.8 43 15 2,900 4,800 30 530 1,300,000 3,000,000 3,400 6.2 13.1 2780 406 150 0.58 W-01 10/17/2011 1,550 66.2 51.7 2,640 4,400 1,150,000 2,620,000 25,700 6.7 20.1 3740 73 130 0.64 W-01 3/16/2012 24.4 4,480 6.8 270 11,190,000 3,860,0001 21,700 6.2 18.2 3547 0.8 43.5 0.48 W-01 9/24/2012 279 32.2 494 4,580 450 1,500,000 2,890,000 -- 6.5 19.6 3750 9.6 312 APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 2 of 10 Analyte 3 c .E 7 a c d N i a E = 'C 10 m E ' E "O c6 U _3 E O i L L) `m C. C. O L) C O '6 d -j a> °� @ C R a U L d 2 E .E N N rn d > in t� C N Z cv m cv w z m w 7 U) N y y > O '� ❑ r O 0 o R ) O a@. O fn 2 C N N U N m w @ m C_ E N E_ U) - w c O U w U d C. U) ❑ Z r 3 > E � d O a c C m d' O "6 x O J rn E C �+ x O aD O N N o C 2L Ground Water Standard 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 10,000 250,000 500,000 NE 6.5-8.5 NE NE NE NE NE Sample Date W-01 4/18/2013 501 35.2 692 4,590 357 1,380,000 2,610,000 23,500 6.3 17.5 3354 8.03 -441.5 0.32 W-01 9/10/2013 117 34 290 4,920 -- 1,3705000 25900,000 27,600 6.2 22.5 3067 7.29 49.4 0.29 W-01 4/7/2014 156 24.8 360 4,750 1,1605000 25850,000 32,300 6.2 11.9 3406 7.87 374.4 1.46 W-01 9/4/2014 5.9 297 4,600 61.2 1,4505000 25950,000 -- 6.2 20.0 2940 6.1 83.7 0.75 W-01 (FD) 4/1/2015 126 21 300 4,540 53.7 1,2105000 2,710,000 -- -- -- -- -- -- W-01 4/3/2015 212 24.5 500 5.3 4,510 50.4 1,2605000 241,000 6.4 17.9 2676 5.09 76.9 0.66 W-01 (FD) 4/3/2015 126 21 300 4,540 53.7 1,2105000 25710,000 6.4 17.9 2676 5.09 76.9 0.66 W-01 9/10/2015 330 J 38 1 J 0.88 J 850 4,900 1,2005000 25700,000 E 6.4 23.0 3220 0 225 1.13 W-01 3/8/2016 37 0.24 2,000 5,300 28 1,2005000 25600,000 6.4 20.5 3176 8.29 63.1 0.38 W-01 9/8/2016 22 0.38 1,400 4,800 1,1005000 25500,000 6.8 22.3 2905 1.8 -1.5 0.8 W-01 3/29/2017 280 39 1,900 5,100 4.1 J 15200,000 25600,000 E 6.4 18.7 3060 9.7 142.5 0.34 W-01 9/27/2017 190 B 32 860 5,200 1,2005000 25700,000 6.4 22.9 3020 5.6 139 0 W-01 3/6/2018 930 56 1.8 J 7,200 2.4 4,700 5.6 1,2005000 25600,000 6.6 12.7 3182 28 260 0.38 W-01 9/12/2018 26 920 5,200 1,2005000 25700,000 6.2 23.8 2949 2.53 74.5 0.6 W-01 3/19/2019 20 1,300 3,100 11 9405000 25200,000 6.3 14.9 2740 1.39 -109.6 0.67 W-01 9/3/2019 180 24 340 3,800 14 9705000 25200,000 6.1 20.8 2553 5.63 -1.2 0.26 W-01 3/31/2020 180 29 450 4,000 18 9705000 25200,000 6.4 14.4 2635 6.01 45.4 0.3 W-01 9/24/2020 73 24 950 3,700 26 1,0005000 25400,000 6.6 16.5 2517 4.56 -61.8 0.62 W-02 1/16/1990 -- 210 -- -- 0.2 -- -- 6.1 -- -- -- -- - W-02 9/24/1990 850 219 8.3 1,400 9,900 1 41,000 533,000 14,000 6.2 16.7 717 - W-02 10/24/1991 169 82 9,300 7.4 165500 1,150,000 15937,000 15,000 6.0 18.7 2080 - W-02 3/26/1992 2,790 3.4 385400 16 - 1,8605000 25611,000 12,000 5.8 13.8 2880 - W-02 9/30/1992 - -- 215300 1,3205000 25525,000 6,000 1 6.1 17.9 1 2670 - W-02 3/31/1993 417 177 1,280 7.6 53 40 6005000 948,000 2,000 5.6 15.2 167 - W-02 9/17/1993 5,650 508 3.8 79 345700 12 225300 62 1,570,000 35350,000 12,000 6.4 20.8 4030 - W-02 3/30/1994 185700 2,770 3 76 505900 34 2,400 25 200,000 555,000 -- 5.7 16.0 1640 - W-02 9/30/1994 215400 942 37 58 362 13 3,710 88 4155000 969,000 15,900 6.2 18.3 1440 - W-02 3/31/1995 455000 1,710 78 58 5,050 28 3,660 172 155,000 460,000 -- 6.2 13.7 930 - W-02 9/29/1995 109,000 3,950 30 209 142 206,000 68 3,750 5 292 379,000 944,000 7,370 5.6 16.4 1345 - W-02 3/30/1996 665500 1,250 12 105 78 965600 44 3,610 183 12,600 127,000 4,680 5.6 14.0 316 - W-02 9/27/1996 895100 1,510 8.8 150,000 15 3,060 98 -- 373,000 9,220 7.0 21.0 840 - W-02 3/29/1997 645400 1,100 20 102 72 985000 47 2,500 150 1,0105000 25020,000 10,800 6.4 14.0 1300 - W-02 9/17/1997 565500 1 1,620 13 87 88 995900 35 205200 201 1,410,000 35600,000 11,300 6.6 17.0 3780 - - - W-02 3/27/1998 10,900 584 265000 6,160 116,000 15130,000 6,340 6.8 19.9 743 - W-02 9/30/1998 15,400 518 39 34 285800 22 155000 60 762,000 3,380,000 15,700 6.4 21.0 753 - W-02 3/31/1999 2,380 852 45 35 475000 21 6,920 73 26,300 262,000 1,410 6.2 18.0 126 - W-02 9/29/1999 9,700 296 36 265900 9 203 2935000 458,000 15,300 6.2 20.0 182 - W-02 3/16/2000 125700 434 28 25 195400 2,160 28 2815000 642,000 7,360 -- -- -- - W-02 9/15/2000 5,490 508 1,600 7 1,140 93,400 374,000 1,890 6.6 19.0 170 - W-02 3/23/2001 2,600 4,740 6 234 37 26,300 173,000 6,820 6.5 18.0 270 - W-02 3/28/2002 17,900 47 46 455300 16 3,030 88 23,400 219,000 11,900 6.7 14.0 140 - W-02 10/3/2002 -- -- -- -- -- -- -- -- - -- -- - - W-02 3/25/2003 6,070 264 8,420 1 115 25 14,400 118,000 5,290 6.1 18.0 140 - W-02 10/2/2003 4,630 277 105900 8 115100 1,270,000 35380,000 7,780 6.1 20.0 3020 - W-02 4/28/2004 3,600 115000 6 2,630 36 233,000 634,000 8,130 - 14.4 1460 - W-02 10/26/2004 30,200 2,140 9 112 83 655600 21 5,080 144 1,7105000 35800,000 7,220 - - 3690 - W-02 4/27/2005 2,750 6 9,150 8 8,950 26 1,2605000 25868,000 13,800 - - 3170 - W-02 10/20/20051 9,380 377 2 20 203 265200 9 6,800 116 1,510,000 1,700,000 22,000 - - 1110 - APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 3 of 10 Analyte c •� Q y i Q 'C m m -E a m U E L U Q O_ O U C O m a)@ J rN C a i N Z 7 N N fn > to U N Z w z c w 3 cn N N > p G �0, O F- O R O ram. O m 2 a N N m U y d d m Q. E y E C1 U) 3 " C1 c O w N O- U) Z 3 H E � - C O d O Cl d is 'a X O J C1 E G1 x O > o N N o C 2L Ground Water Standard 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 10,000 250,000 500,000 NE 6.5-8.5 NE NE NE NE NE Sample Date W-02 10/19/2006 3,630 8,080 6 1,900 44 -- 749,000 1,210,000 8,990 1050 - W-02 4/27/2007 46,500 451 2 0 55,900 -- -- 46 1,570,000 2,800,000 9,010 - - 1880 - W-02 11/19/20071 5,750 12,000 8 3,030 1,330,000 1,310,000 9,710 - - 1330 - W-02 4/30/2008 4,450 5 334 72 246,000 330,000 7,260 - 609 - W-02 4/30/2009 5,170 268 13.9 11.3 12,500 11.8 441 37.5 10,400 157,000 7,570 - - 94 - W-02 10/15/2009 30,000 13 1,600 4.8 110 67 200,000 36 3,400 42 410 -- -- -- 6.4 15.9 900 30 -145 1.21 W-02 4/20/2010 430 180 490 2,400 830,000 1,900,000 48,800 8.0 13.8 1880 411 15 5.88 W-02 10/11/2010 2,300 2.4 J 240 0.68 J 8.7 11 J 6,600 1.7 J 2,300 11 -- 210 660,000 1,400,000 -- 6.3 17.0 1340 712 46 3.99 W-02 4/22/2011 170 2.3 150 1.8 2,100 4,000 1 14 33 760,000 1,700,000 8,600 -- -- -- -- -- -- W-02 10/17/2011 2,180 113 6.1 2,710 4,020 5.8 365,000 842,000 18,700 -- -- -- -- -- -- W-02 3/16/2012 2,540 122 6.1 3,270 45.4 30,000 153,000 7,700 6.5 16.1 1144 8.4 -8.6 5.75 W-02 9/24/2012 2,020 119 3,910 2,870 430 276,000 2,030,000 -- -- -- -- -- -- - W-02 4/18/2013 192 339 182 425 56,800 149,000 5,000 -- -- -- - -- -- W-02 4/18/2013 -- -- -- -- -- - - -- -- -- -- 6.5 16.7 261 - 97.2 7.37 W-02 9/10/2013 451 315 676 21 44,600 135,000 10,200 -- -- -- -- -- -- W-02 4/7/2014 1,800 291 2,450 18.8 - - 37,000 7,600 5.8 10.8 247 54.9 252 4.81 W-02 9/4/2014 5,930 183 6.3 7,950 163 - - 39,000 182,000 -- 5.5 20.1 168 28.2 126.4 3.08 W-02 4/3/2015 114 255 148 - - 43,900 134,000 - 7.6 16.3 256 8.74 19.8 6.94 W-02 9/10/2015 6,800 220 9.5 J 8,800 93 - 18,000 190,000 B 5.3 22.4 155 30 272 1.38 W-02 3/8/2016 860 280 1,300 29 - - 41,000 130,000 5.7 21.2 193 29.7 136.2 5.59 W-02 9/8/2016 1,900 190 3,200 31 - - 14,000 230,000 - 6.6 17.2 116 -- 101 1.91 W-02 3/29/2017 140 220 200 2.5 J - - 46,000 100,000 B - 7.0 15.2 294 5.76 206.2 6.94 W-02 9/27/2017 -- -- -- - -- - - - -- -- 5.6 21.2 114 22 176 0 W-02 3/6/2018 100 230 150 7.4 1.3 J 47,000 130,000 6.2 10.6 185 7.47 220 3.7 W-02 9/12/2018 380 170 530 6.5 - - 24,000 99,000 5.7 19.7 184 27.6 120.7 2.16 W-02 3/19/2019 230 150 320 11 - - 28,000 94,000 5.3 10.9 126 9.39 142.3 0.69 W-02 9/3/2019 5,100 170 4,800 29 - - 18,000 160,000 5.1 22.3 122 -- 53 -- W-02 3/31/2020 970 150 1,100 20 - - 22,000 82,000 5.5 13.1 101 19.4 83.9 2.57 W-02 (FD) 3/31/2020 990 150 1,300 20 22,000 76,000 - -- -- -- -- -- -- W-02 9/24/2020 2,600 190 4,300 370 - - 19,000 130,000 5.6 17.0 127 10.4 -35.1 2.41 W-03 1/16/1990 -- 300 -- -- -- -- - 7.0 -- -- -- -- -- W-03 9/6/1990 -- 8,990 20 810 -- 330 -- 0.5 5.9 -- -- - 6.7 -- -- W-03 9/21/1990 2,170 134 8.1 2,000 80 8,500 174,000 12,000 6.5 16.2 238 - W-03 10/23/1991 213 149 240 330 116 214,000 12,000 6.7 19.7 207 - W-03 3/25/1992 119 22,500 136,000 10,000 6.1 13.1 307 - W-03 9/29/1992 670 120 580 410 0.3 20,000 189,000 1,000 5.9 17.1 223 - W-03 3/31/1993 1,170 180 2,300 55 14,900 163,000 2,000 5.5 15.7 207 - W-03 9/17/1993 9,460 444 2.8 71 20,700 10 173 106 12,000 207,000 2,000 6.2 18.3 282 - W-03 3/30/1994 4,420 259 24 10,700 150 264 107 17,000 180,000 5.7 15.9 180 - W-03 9/30/1994 25,400 485 26 67 32,000 17 526 86 193,000 26,100 6.3 18.0 202 - W-03 3/31/1995 31,300 466 27 55 36,400 25 430 186 133,000 206,000 6.6 12.7 220 - - - W-03 9/29/1995 55,400 813 7 51 122 70,100 42 1,020 183 139,000 302,000 1,320 5.4 15.4 245 - W-03 3/30/1996 17,100 436 2 20 46 25,900 19 409 100 19,500 217,000 3,410 5.6 13.0 285 - W-03 9/27/1996 11,200 257 16,400 15 235 94 59,800 215,000 1,100 7.8 18.0 243 - W-03 3/29/1997 16,400 347 3 43 23,000 13 384 51 21,100 223,000 7,860 6.6 12.0 153 - W-03 9/17/1997 32,200 478 4 27 67 40,200 24 590 280 88,900 262,000 1,290 6.9 16.0 366 - W-03 3/27/1998 12,200 491 21,300 604 19,100 248,000 1,260 6.1 19.9 542 - W-03 1 9/30/1998 4,150 1 5,690 151 39 5,050 238,000 1,340 6.8 20.0 276 - APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 4 of 10 Analyte c •� Q y i Q 'C m m -E a m U E L U OQ _ O U C O m a)@ J rN C a i N Z 7 N N fn > to U N Z w z c w 3 cn N N > p G �0, O F- O R O ram. O m 2 a N N m U y d d m Q. E y E C1 U) 3 " C1 c O w N O- U) Z 3 H E � - C O d O Cl d is 'a X O J C1 E G1 x O > o N N o C 2L Ground Water Standard 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 10,000 250,000 500,000 NE 6.5-8.5 NE NE NE NE NE Sample Date W-03 3/31/1999 2,380 3,930 126 73 -- 26,300 262,000 1,410 6.2 18.0 126 - W-03 9/29/1999 2,130 4,230 1 90 27,300 272,000 1,710 6.8 19.0 315 - W-03 3/16/20001 11,700 356 35 15,700 7 334 16 36 17,800 193,000 2,630 -- -- -- - - - W-03 9/15/2000 6,590 323 26 9,900 11 309 17 20,900 187,000 1,530 6.7 18.0 390 - W-03 3/23/2001 828 1,020 9 45 23 27,400 175,000 1,560 6.7 17.0 310 - W-03 10/4/2001 3,640 6,020 8 221 13 24,700 186,000 3,200 6.1 17.0 200 - W-03 3/28/2002 1,720 2,820 100 38,500 203,000 1,450 6.7 14.0 470 - W-03 3/28/2002 2,370 2,820 100 17 25,600 177,000 -- -- 238 W-03 10/3/2002 8,770 387 22 16,400 450 35 58,200 231,000 1,020 8.1 19.0 210 - - W-03 3/25/2003 15,300 362 26 23,800 8 622 45 42,600 194,000 6.2 19.0 210 - W-03 10/2/2003 2,460 646 4,080 212 28,300 199,000 6.7 17.0 243 - - - W-03 4/28/2004 1,490 2,820 80 13 1,350,000 171,000 -- 14.6 225 - W-03 10/26/2004 2,370 3,490 129 17 25,600 177,000 -- 238 W-03 4/27/2005 874 1,580 66 16 40 34,400 192,000 740 - - 277 - - - W-03 10/20/2005 3,500 252 107 4,230 72 30 71 44,000 218,000 18,000 - - 317 - W-03 10/19/2006 553 277 1,020 37 48 70,400 237,000 690 - - 330 - - - W-03 4/27/2007 262 708 -- 89,400 251,000 1,510 - - 388 - - - W-03 11/19/2007 124 263 156 65 53,000 293,000 860 - - 403 - W-03 11/19/2007 139 254 158 12 65 64,200 278,000 880 - - 402 - W-03 4/30/2008 261 148 94 91,000 331,000 760 - - 470 - W-03 10/29/2008 274 0.33 10.6 216 3.3 124 0.1 95.5 5.15 96,000 360,000 1,040 - - 571 - - - W-03 4/30/2009 442 368 638 8.5 61.6 154 68.2 199,000 399,000 940 - 603 - W-03 (FD) 4/30/2009 571 268 2.5 332 7.1 30.8 153 32.4 203,000 389,000 1,070 - 617 - - - W-03 10/12/2009 26 J 2.7 J 160 0.9 J 16 J 0.08 J 150 740 140,000 430,000 -- 5.9 15.2 -- 8.6 121 2.82 W-03 4/20/2010 870 280 940 49 100 -- 100,000 380,000 9,000 6.0 12.5 644 23.2 264 3.74 W-03 10/11/2010 110 1.3 J 21 J 1.6 J 77 20 790 89,000 310,000 -- 5.9 18.0 497 6.7 256 1.39 W-03 4/21/2011 2.1 140 210 6.7 100 850 120,000 330,000 1,000 5.8 13.1 399 299 3.68 W-03 10/18/2011 380 195 262 22.1 102 1,100 360,000 413,000 7,700 6.9 17.5 764 6.3 128 1.76 W-03 3/16/2012 97.5 101 10.2 112 5.8 1,700 220,000 1,070,000 7,800 5.5 14.3 755 1.4 125.8 2.36 W-03 9/24/2012 87.4 49.1 51.9 1,000 418,000 719,000 -- 5.8 17.8 1110 1.6 521 W-03 4/18/2013 56.2 75.7 29.6 844 401,000 852,000 10,600 5.7 14.0 1146 1.11 -443.1 0.54 W-03 9/10/2013 45.8 98.4 20 447,000 852,000 9,290 5.9 18.9 959 1.13 221.7 0.44 W-03 4/7/2014 39.8 88.4 20.4 338,000 796,000 10,100 5.9 10.7 1109 0.71 537.7 2.39 W-03 9/3/2014 34 135 23.4 364,000 895,000 -- 5.7 20.6 1049 2.78 501.6 0.74 W-03 4/2/2015 32.8 155 25 449,000 932,000 6.1 15.7 960 2.11 327.6 1.48 W-03 9/9/2015 38 280 11 J 530,000 1,000,000 E 5.9 26.2 1410 0 485 1.02 W-03 3/8/2016 30 190 170 12 320,000 750,000 5.0 13.1 1018 0.62 550 1.5 W-03 9/8/2016 29 300 320 2.7 360,000 840,000 6.4 20.8 1048 0.46 88.2 1 W-03 3/29/2017 15 J 43 310 290 410,000 880,000 B 6.3 15.1 1218 2.22 180.2 0.79 W-03 9/26/2017 13 BJ 32 190 320 390,000 860,000 6.3 23.3 1080 2.9 371 0 W-03 3/6/2018 35 130 590 8.8 520,000 1,100,000 6.7 11.0 149 0.61 481 0.7 W-03 (FD) 3/6/2018 34 140 550 7.6 530,000 1,100,000 -- -- -- -- -- -- W-03 9/12/2018 26 170 510 400,000 900,000 6.2 20.2 1131 0.64 195.6 3.2 W-03 3/19/2019 28 230 180 7.4 250,000 600,000 6.2 13.5 858 2.04 291 1.77 W-03 9/3/2019 27 110 5.4 - - 200,000 500,000 6.0 20.9 680 0.16 177 1.11 W-03 3/31/2020 26 170 9.8 190,000 510,000 6.2 12.8 712 0.37 3,819.1 0.89 W-03 9/24/2020 29 100 120 10 - - 150,000 460,000 6.2 16.3 648 0.35 129.3 0.7 W-03B 10/26/2004 2,330 3,170 157 24 174,000 545,000 2,710 -- -- 862 -- -- -- APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 5 of 10 Analyte c •� Q y i Q 'C m m -E a m U E L U Q O_ O U C O m a)@ J rN C a i N Z 7 N N fn > to U N Z w Z c w 3 cn N N > p G �0, O H O R O ram. O H m 2 a N N m U y d d m Q. E y H E C1 U) 3 " C1 c O w N O- to Z 3 H E � - C O d O Cl d is :2 X O J C1 E G1 x O > o N N C 2L Ground Water Standard 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 10,000 250,000 500,000 NE 6.5-8.5 NE NE NE NE NE Sample Date W-03B 4/27/2005 203 2 1,830 15 907 41 36 -- 590,000 840,000 10,100 - 1180 - W-03B 10/20/2005 3,630 29 4,290 1 5 68 75 146,000 627,000 30,000 - - 550 - W-03B 10/19/20061 135 950 5 811 42 318,000 750,000 5,240 - - 739 - W-03B 4/27/2007 238 901 1,280 475,000 1,050,000 2,570 - - 1240 - W-03B 11/19/2007 1,170 1,270 582,000 101,000 22,600 - - 1310 - W-03B 4/30/2008 505 1,010 570,000 955,000 1,180 - - 1270 - W-03B 10/29/2008 48 4.9 1,950 946 0.07 10.5 305,000 760,000 830 1080 W-03B 4/30/2009 42.6 490 10.5 999 9.7 1.5 8.7 185,000 827,000 5,560 - - 1150 - W-03B 10/12/2009 39 J 3.6 J 43 J 0.9 J 330 880 250,000 780,000 -- 7.2 14.6 -- 14.4 -42 3.4 W-03B 4/20/2010 49 500 970 280,000 770,000 11,200 6.8 17.5 2320 108 -51 0.23 W-03B 10/11/2010 2.4 J 45 0.95 J 500 980 9.9 6 J 140 J 300,000 830,000 -- 6.7 17.5 1010 41.3 -25 W-03B 4/21/2011 2.5 51 970 1,200 12 85 370,000 890,000 1,100 6.6 15.4 956 -72 0.48 W-03B 10/18/2011 52 606 1,320 460,000 1,090,000 9,700 9.5 15.0 1750 9.4 -86 W-03B (FD) 10/18/2011 50.9 587 1,280 408,000 1,050,000 8,000 9.5 15.0 1750 9.4 -86 W-03B 3/16/2012 48.5 472 1,560 47.6 559,000 533,000 9,800 6.7 14.5 1474 2.9 -35 0.79 W-03B 9/24/2012 45.1 537 1,340 27.1 422,000 1,050,000 -- 7.1 16.0 1650 3.6 -26 W-03B 4/18/2013 40.3 397 743 248,000 623,000 16,800 6.6 14.9 961 0 -71 0.47 W-03B 9/10/2013 43.2 258 448 120,000 421,000 6,580 7.2 19.3 1380 9.2 -43 W-03B 4/7/2014 46.6 772 540 - - 123,000 396,000 49,000 6.9 16.1 987 0 -92 0.38 W-03B 9/3/2014 48.4 321 452 12.5 - - 18,100 403,000 -- 6.9 16.2 988 1.4 -87 2.01 W-03B 4/2/2015 47.8 3,070 520 - - 79,400 415,000 - 7.2 16.0 500 8.5 122.7 0.74 W-03B 9/9/2015 42 170 570 - - 110,000 390,000 B - 6.7 27.2 670 0 -7 0.96 W-03B 3/8/2016 50 680 440 2.3 - - 73,000 390,000 - 7.3 13.0 596 6.02 62 0.23 W-03B 9/8/2016 45 340 380 - - 71,000 380,000 - 7.3 21.4 538 0.44 62 0.7 W-03B (FD) 9/8/2016 46 350 380 1.1 74,000 370,000 -- -- -- -- -- -- W-03B 3/29/2017 8.9 J 44 400 440 - - 110,000 410,000 B - 7.3 13.7 687 0.58 156.6 0.52 W-03B (FD) 3/29/2017 8.2 J - 46 400 470 - - 110,000 360,000 B -- -- -- -- -- -- W-03B 9/26/2017 19 BJ 55 820 310 - - 65,000 370,000 - 7.2 20.2 453 2.7 28 0 W-03B 3/6/2018 45 210 330 - - 100,000 440,000 - 8.0 10.0 652 0.1 -28 0.55 W-03B 9/12/2018 47 240 230 - - 61,000 340,000 - -- 23.0 504 0.18 -36 0.65 W-03B 3/19/2019 47 650 48 - - 39,000 290,000 - 7.2 10.7 460 3.63 71.3 3.17 W-03B 9/3/2019 42 35 - - 24,000 260,000 - 7.2 19.1 385 0.39 -11.5 0.59 W-03B 3/31/2020 59 87 - - 23,000 240,000 - 7.5 12.8 400 0.2 24.9 0.44 W-03B 9/24/2020 54 350 120 - - 19,000 260,000 - 7.6 16.0 392 0.73 185.3 0.23 W-04 4/4/1995 9,720 15,600 7 564 58 7,880 231,000 136,000 6.1 19.0 234 -- -- -- W-04 9/17/1997 4,420 2 10,000 6 406 190 8,860 212,000 3,190 7.5 18.0 366 - W-04 3/27/1998 3,410 6,250 -- 44 7,120 226,000 2,690 6.7 19.2 390 - W-04 9/30/1998 219 1,610 299 6,420 200,000 7,260 5.9 21.0 322 - W-04 3/31/1999 637 2,150 285 5,710 202,000 8,530 6.5 16.0 279 - W-04 9/29/1999 127 1,440 5 271 24 207,000 2,850 6.4 18.0 315 - W-04 3/16/2000 1,470 298 191,000 6,050 -- -- -- - W-04 9/15/2000 165 1,090 252 5,300 241,000 15,500 6.2 17.0 310 - W-04 3/23/2001 2,750 4 9,910 16 447 28 6,530 219,000 5,990 6.4 16.0 240 - W-04 10/4/2001 204 915 7 229 186,000 7,800 6.3 20.0 300 - W-04 3/28/2002 1,460 212 5,160 196,000 1,680 6.2 14.0 190 - W-04 10/3/2002 1,130 237 29 5,080 202,000 4,070 6.1 19.0 280 - W-04 3/25/2003 976 212 61050 185,000 1,610 6.2 16.0 260 - APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 6 of 10 Analyte c •� Q y i Q 'C m m -E a m U E L U OQ _ O U C O m a)@ J rN C a i N Z 7 N N fn > to U N Z w z c w 3 cn N N > p G �0, O F- O R O ram. O m 2 a N N m U y d d m Q. E y E C1 U) 3 " C1 c O w N O- U) Z 3 H E � - C O d O Cl d is 'a X O J C1 E G1 x O > o N N o C 2L Ground Water Standard 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 10,000 250,000 500,000 NE 6.5-8.5 NE NE NE NE NE Sample Date W-06 10/2/2003 1,920 268 24 3,220 154 440 -- 95,000 466,000 34,000 7.3 19.0 661 - W-06 4/28/2004 1,160 30 26 917 1 7 37 149 370,000 692,000 139,000 -- 14.7 937 - W-06 10/26/20041 790 89 32 259 12 87 116,000 630,000 79,200 - - 917 - W-06 4/27/2005 389 5 56 87,500 565,000 13,200 - - 932 - W-06 10/20/2005 40 355.7 60 35,400 553,000 27,000 - - 939 - W-06 10/19/2006 529 77 12 66 46,400 471,000 29,300 - - 655 - W-06 4/27/2007 2,660 29 2,790 106 168 29,500 442,000 8,840 - - 776 - W-06 11/19/2007 627 711 24 38 11,200 431,000 8,980 - - 694 - W-06 4/30/2008 37 392,000 5,610 - - 615 - W-06 10/29/2008 235 35.8 0.41 6.8 268 9.3 67 393,000 4,130 - - 724 - W-06 (FD) 10/29/2008 222 293 1 2.7 460 4.9 84.6 0.16 101 98,800 384,000 860 - 574 - W-06 4/30/2009 139 36.6 7 33.1 2.9 1.5 8.1 33.2 10,500 463,000 10,300 - 807 - - - W-06 10/12/2009 140 2.3 J 28 5.5 4.3 J 44 J 1.7 J 0.2 17,000 J 380,000 -- 10.6 18.9 1020 33.1 -243 0.16 W-06 4/20/2010 1,700 59 400 14 3,200 87 1 69 16,000 450,000 9,100 10.7 18.9 930 209 -227 0.03 W-06 10/11/2010 320 37 420 19 J 2,800 56 -- 120 J 13,000 410,000 -- 10.6 17.7 816 35.7 -250 W-06 4/22/2011 260 1.2 33 190 7 1,000 1.3 28 1.1 17 21 16,000 410,000 3,800 11.1 13.9 562 9.6 -189 1.01 W-06 10/17/2011 421 26.9 60.9 89 311 6.8 60.1 11,000 414,000 6,100 -- -- -- -- -- W-06 10/18/2011 421 26.9 60.9 89 311 6.8 60.1 -- 11,000 414,000 6,100 12.2 18.1 1040 8.6 -313 0.37 W-06 3/16/2012 221 44.7 8.5 83 10.1 11,400 499,000 5,200 11.2 17.3 845 1.9 -234 0.38 W-06 9/26/2012 202 37.3 23.6 162 14.1 12,200 317,000 -- 11.4 16.3 667 8.9 -21 W-06 4/19/2013 517 41.1 18.3 277 6.4 21.2 12,200 334,000 4,920 -- -- -- -- -- -- W-06 4/19/2013 -- - -- 18.3 277 6.4 21.2 12,200 334,000 4,900 10.4 15.8 620 8.6 -450.5 0.4 W-06 9/11/2013 312 46.9 21.7 397 7.7 19.4 12,100 335,000 4,390 10.6 17.9 506 6.87 82.6 0.71 W-06 4/9/2014 154 42.2 6.9 141 -- - 12,400 304,000 4,700 10.9 15.1 634 4.23 -43.1 1.23 W-06 9/5/2014 33.7 - - 11,800 337,000 -- 10.8 15.7 637 3.87 -37.4 1.19 W-06 4/2/2015 35.4 9.4 72.6 - - 11,700 314,000 - 10.3 16.3 555 2.62 -142.1 2.74 W-06 9/8/2015 570 37 110 900 23 - - 11,000 280,000 - 10.2 21.3 496 22.7 -59 1.95 W-06 3/9/2016 35 18 230 - - 12,000 270,000 10.1 16.4 465 7.29 -80.9 0.48 W-06 9/6/2016 62 37 110 - - 9,900 260,000 10.1 16.4 754 2 -106 0.7 W-06 3/28/2017 530 76 36 990 0.5 J 17 - - 10,000 220,000 9.8 15.5 437 9.85 -67.2 0.59 W-06 9/27/2017 220 B 41 14 220 0.58 J 6.5 - - 11,000 270,000 9.9 16.8 360 4.48 82 1.26 W-06 3/6/2018 100 39 32 620 9.4 - -- 11,000 260,000 9.6 11.9 0 11.4 -29 1.5 W-06 9/13/2018 2,100 200 42 2,900 1.6 330 - - 57,000 270,000 9.9 18.2 475 7.38 124 0.67 W-06 3/20/2019 42 5.5 100 - - 10,000 270,000 9.5 15.6 435 3.18 80.7 0.68 W-06 9/4/2019 100 38 100 - - 12,000 270,000 9.0 19.7 398 -- -109.5 0.37 W-06 4/3/2020 180 43 7.2 190 5.6 - - 10,000 250,000 9.4 15.6 397 7.36 -56.6 0.42 W-06 9/24/2020 120 40 7.8 230 - - 9,000 290,000 9.3 15.6 387 6.13 -76.9 0.75 W-07 1/6/2011 -- 110 200 120 - - 9,300 200,000 - 7.1 15.4 298 5.2 83 2 W-07 4/21/2011 92 80 520 160 44 6,600 190,000 7.3 15.2 301 12 0.62 W-07 9/25/2012 318 77.3 628 173 6,200 206,000 - 8.1 15.1 403 18.2 46 W-07 4/18/2013 403 140 6 1,460 146 10,200 173,000 29,000 6.9 15.7 271 17.1 -448.1 1.7 W-07 9/11/2013 257 112 950 124 -- 8,100 3,310 7.4 16.2 271 7.7 4.3 0.87 W-07 4/9/2014 427 131 -- 1,830 97.1 - - 11,200 181,000 3,500 6.8 15.6 265 21.3 119.1 2.87 W-07 9/5/2014 797 81.1 1,580 189 - - 6,400 220,000 -- 7.5 15.9 289 8.08 10.3 1.35 W-07 4/2/2015 402 136 1,970 69.6 - - 10,800 169,000 - 7.5 15.9 284 9.37 6.3 2.19 W-07 9/9/2015 380 J 78 28 1,600 150 - - 5,700 170,000 B - 6.7 18.7 349 5.9 23 4.64 W-07 3/9/2016 800 140 16 3,800 100 - - 11,000 110,000 - 7.0 14.1 284 40.4 114.9 1.87 W-07 9/6/2016 260 130 1,800 53 - - 9,800 89,000 - 7.1 16.8 206 20.5 89 3.1 APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 7 of 10 Analyte c •� Q y i Q 'C m m -E a m U E L U OQ _ O U C O i m a) J rN C @ a i N Z 7 N N fn > to U N Z w Z c w 3 cn N N > p G �0, O H O R O ram. O H m 2 a N N m U y d d m Q. E y H E C1 U) 3 " C1 c O w N O- to Z 3 H E � - C O d O Cl d is :2 X O J C1 E G1 x O > o N N C 2L Ground Water Standard 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 10,000 250,000 500,000 NE 6.5-8.5 NE NE NE NE NE Sample Date W-07 3/28/2017 500 130 28 -- 3,600 0.93 J 110 -- -- -- -- 8,900 160,000 B - 6.9 15.3 280 42.9 12.3 1.9 W-07 9/27/2017 2,200 B 100 11 4,400 0.99 J 800 - - 5,400 160,000 B - 7.5 16.3 281 9.24 50 0.5 W-07 (FD) 9/27/20171 200 B 71 4.1 J 1,100 0.67 J 93 - - 5,400 230,000 - 7.5 16.3 281 9.24 50 0.5 W-07 3/5/2018 240 73 7.9 1,600 0.43 220 - - 5,600 210,000 - 7.3 13.8 341 29.4 16 1.22 W-07 3/6/2018 240 73 7.9 1,600 0.43 J 220 - - 5,600 210,000 - -- -- -- -- -- W-07 9/12/2018 310 81 9.6 2,800 190 - - 6,300 210,000 - 7.3 17.7 327 56.3 32.4 0.74 W-07 9/12/2018 310 81 9.6 2,800 190 - - 6,300 210,000 - -- -- -- -- -- -- W-07 3/20/2019 96 100 1,400 29 - - 11,000 180,000 - 6.5 15.7 267 21.3 134.7 2.28 W-07 (FD) 3/20/2019 140 - 110 1,600 32 - -- 11,000 180,000 - 6.5 15.7 267 21.3 134.7 2.28 W-07 9/4/2019 280 78 1,800 150 - - 6,000 220,000 - 6.8 15.4 322 26.1 -73.3 0.27 W-07 4/2/2020 130 75 6.1 1,200 72 - - 5,400 190,000 - 7.3 13.8 339 31.1 0.5 0.36 W-07 9/24/2020 99 130 5.9 1,500 37 - -- 11,000 180,000 - 7.0 15.1 208 17.6 -81.6 4.21 W-08 1/6/2011 -- -- 330 0.12 2,900 65 - - 73,000 210,000 - 7.5 14.8 300 49.6 182 7.88 W-08 4/20/2011 390 1.2 180 940 20 8.9 240 68,000 240,000 1,100 5.7 15.1 391 133 203 7.06 W-08 9/26/2012 643 166 25.2 7.7 777 63.6 151 250 86,800 242,000 -- 6.1 20.5 382 6.2 158 5.86 W-08 4/18/2013 5,940 465 86.4 85.6 9,760 220 122 292 95,000 247,000 5,160 5.8 19.5 330 9.6 -428 5.3 W-08 9/10/2013 1,180 407 41.7 40 1,900 37.1 67.1 -- 101,000 244,000 5,600 5.7 21.8 310 9.3 95.3 6.02 W-08 4/9/2014 1,670 147 7.5 -- 2,940 86.5 -- - 98,800 263,000 4,900 5.6 18.1 371 11.91 195.4 5.87 W-08 9/3/2014 318 136 463 23 13.4 - - 114,000 300,000 -- 5.4 14.8 329 8.4 154.3 5.91 W-08 4/2/2015 873 206 42.7 1,410 26.9 11.5 62,700 219,000 5.9 21.6 340 39.9 68.4 4.64 W-08 9/9/2015 840 160 84 1,200 180 - - 96,000 240,000 B 5.8 31.2 322 35.6 125 3.55 W-08 3/9/2016 2,700 290 310 4,800 1.9 290 6.4 - - 65,000 230,000 - 6.2 15.6 332 87 84.8 5.24 W-08 9/7/2016 1,900 280 7.9 4,100 60 4 - - 64,000 200,000 6.3 20.1 240 9.6 98 6.5 W-08 3/28/2017 1,700 380 99 3,300 1 58 6.7 - - 66,000 170,000 B 5.7 19.9 275 21.5 177 5.74 W-08 9/26/2017 2,600 B 290 51 2,500 2.5 120 6.4 - - 53,000 210,000 6.0 16.3 211 33.1 128 7.91 W-08 3/5/2018 560 150 20 1,100 0.56 J 67 4 J 56,000 190,000 5.7 19.0 221 41 203 18.32 W-08 9/12/2018 62 36 12 230 - - 11,000 260,000 6.9 18.5 394 91.3 119 5.87 W-08 3/20/2019 450 240 20 730 17 - - 17,000 130,000 5.4 12.7 128 20.6 157.8 6.89 W-08 9/4/2019 270 300 370 11 - - 61,000 180,000 5.1 16.3 206 9.8 61.6 6.47 W-08 4/2/2020 64 150 5.1 97 - -- 69,000 170,000 5.6 18.3 239 4.9 118.1 6.78 W-08 9/24/2020 940 180 13 1,100 18 - - 37,000 140,000 -- -- -- -- -- -- W-08 9/24/2020 -- - -- - -- -- -- - - - - - -- -- 7.7 15.5 166 16.8 47.8 6.7 W-09 1/5/2011 - 27 440 32 - - 16,000 150,000 - 8.4 15.9 274 119 22 W-09 1/5/2011 27 440 32 - - 16,000 150,000 - 8.4 15.9 274 119 22 W-09 4/20/2011 83 39 170 23 42 10,000 130,000 8.8 16.8 286 121 -10 0.45 W-09 9/26/2012 116 102 10 108 10.1 8,800 149,000 -- 11.0 16.3 350 7.9 12 W-09 4/19/2013 281 115 8.5 157 8 9,270 155,000 2,400 9.6 16.5 286 9.7 -455 0.22 W-09 9/10/2013 114 94 68.6 -- 9,100 169,000 2,410 10.5 16.5 272 3.97 -73.4 0.27 W-09 4/9/2014 54.8 - - 11,100 204,000 3,100 9.4 14.4 257 4.7 -421 0.18 W-09 9/4/2014 134 60.2 222 7.3 - - 11,100 212,000 -- 9.7 19.9 303 11.2 32.8 3.54 W-09 4/3/2015 113 - - 9,100 279,000 - 11.7 16.8 982 3.57 -184.4 0.7 W-09 9/8/2015 110 J 100 3.7 J 41 J 1.4 J - - 9,100 280,000 - 11.8 19.2 856 7 -177 1.67 W-09 3/8/2016 90 89 83 - - 10,000 290,000 12.2 16.9 888 3.16 -166.7 0.35 W-09 9/6/2016 74 97 39 - - 8,400 260,000 11.8 16.6 754 2 -106 0.7 W-09 3/28/2017 99 100 11 81 1.3 J - - 9,300 260,000 11.6 17.6 862 2.68 47.9 0.22 W-09 9/26/2017 140 B 100 5.9 96 0.41 J 2 J - - 11,000 230,000 11.6 17.0 655 1.85 -147.2 0.94 W-09 3/6/2018 61 110 3.8 J 51 - 11,000 270,000 11.4 11.6 690 3.7 -36 2.03 APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 8 of 10 Analyte c •� Q y i Q 'C m m -E a m U E L U OQ - O U C O m a)@ J rN C a i N Z 7 N N fn > to U N Z w z c w 3 cn N N > p G �0, O F- O R O ram. O m 2 a N N m U y d d m Q. E y E C1 U) 3 " C1 c O w N O- U) Z 3 H E � - C O d O Cl d is 'a X O J C1 E G1 x O > o N N o C 2L Ground Water Standard 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 10,000 250,000 500,000 NE 6.5-8.5 NE NE NE NE NE Sample Date W-09 9/11/2018 130 -- -- -- -- -- 11,000 190,000 10.8 17.2 487 0.82 90.7 0.33 W-09 3/20/2019 110 - 12,000 270,000 11.3 17.9 798 1.51 -230.1 0.31 W-09 9/4/20191 130 - 13,000 180,000 9.6 17.0 292 0.5 -139.4 0.15 W-09 4/2/2020 42 170 - 12,000 230,000 11.4 18.1 758 0.87 -400 0.19 W-09 9/23/2020 140 - 11,000 190,000 11.2 17.7 473 0.61 -138.2 0.44 PW-01 4/29/1988 152 59 8 57 57 314 576 37,000 500,000 1,280 6.9 -- -- -- -- -- PW-01 7/13/1989 -- 100 -- -- -- -- -- -- -- -- PW-01 9/6/1990 -- 90 -- -- 9.9 -- -- -- -- 6.8 -- -- PW-01 10/23/1991 130 0 620 1,230 3,310 460,000 850,000 8,000 6.4 15.1 1247 -- -- -- PW-01 8/10/2009 -- 35 4,800 1,800 -- 680,000 -- -- 7.0 15.3 2860 32.1 13 PW-01 5/13/2010 46 6,800 2,500 5,100 1,000,000 2,100,000 6.7 16.5 2580 215 -54 13.5 PW-01 5/13/2010 -- -- -- -- -- -- -- - -- -- PW-01 5/14/2010 44 6,300 9.4 2,400 21,000 940,000 2,100,000 - 6.8 16.1 2570 166 -50 13.2 PW-01 5/14/2010 34 2,900 2,000 560 800,000 1,900,000 - 6.8 15.0 2430 217 -20 14.9 PW-01 4/21/2011 280 11 46 4,400 3,000 54 920,000 2,000,000 2,100 6.2 16.6 2250 24 0.6 PW-01 9/26/2012 1,060 52.2 4,280 2,780 13.5 450 1,190,000 2,980,000 -- 6.8 15.9 2890 8.7 2 PW-01 4/18/2013 1,080 55.4 3,830 2,700 10.1 626 1,080,000 1,940,000 14,200 6.2 16.2 2401 3.03 -453.1 0.6 PW-01 9/10/2013 1,010 52.4 5,680 2,990 18.8 -- 1,150,000 2,240,000 20,500 6.2 17.7 2191 5.24 44.1 0.4 PW-01 4/7/2014 628 48.9 4,780 3,130 -- 914,000 1,980,000 16,600 6.2 15.3 2689 3.2 40.7 0.83 PW-01 9/5/2014 1,370 32.3 8.4 6,160 3,080 49.9 1,010,000 2,260,000 -- 6.1 16.7 2552 5.69 -16.2 3.93 PW-01 4/2/2015 195 45 435 595 62.3 1,010,000 187,000 6.0 21.6 241 6.6 332 4.59 PW-01 9/9/2015 410 54 0.8 J 8.3 J 5,000 3,400 990,000 2,100,000 E 6.3 26.1 2220 0 1 0.49 PW-01 3/8/2016 420 51 8.8 5,000 3,500 940,000 2,100,000 6.4 14.3 2524 3.12 39.2 0.4 PW-01 9/6/2016 250 42 0.12 5,300 3,300 2.5 840,000 1,900,000 6.7 17.9 2080 1.6 -2 0.8 PW-01 3/28/2017 61 39 19 4,200 3,300 3.8 J 840,000 1,900,000 E 6.4 15.8 2342 3.39 42.3 0.31 PW-01 9/26/2017 180 B 48 5.3 4,700 1.3 3,600 780,000 1,900,000 6.4 16.8 1880 1 14.3 0.48 PW-01 3/6/2018 870 48 3.8 J 6,500 0.85 J 3,100 3.6 J 760,000 1,800,000 6.1 13.6 2420 39.1 98 1.01 PW-01 9/13/2018 160 37 4,500 3,100 750,000 1,700,000 6.4 15.5 1709 9.76 74.4 0.26 PW-01 (FD) 9/13/2018 150 - 37 4,500 3,300 770,000 1,700,000 6.4 15.5 1709 9.76 74.4 0.26 PW-01 3/19/2019 430 38 5,300 2,700 7.8 670,000 1,500,000 6.4 14.7 1984 5.73 3.2 0.49 PW-01 9/4/2019 330 35 3,000 3,000 20 750,000 1,700,000 5.8 15.6 1963 3.82 -56.1 0.17 PW-01 (FD) 9/4/2019 170 35 3,300 3,100 740,000 1,700,000 -- -- -- -- -- -- PW-01 4/2/2020 250 36 3,300 2,700 21 830,000 1,700,000 6.4 15.2 2088 4.14 -1.6 0.25 PW-01 9/24/2020 360 56 9.6 1,000 190 19 330,000 730,000 6.0 15.4 954 6.09 214.4 3.75 PZ-01 1/4/2011 -- 81 1,600 78 - - 98,000 180,000 - - - - - - PZ-01 4/20/2011 1,600 63 1 1.9 2,700 1.6 110 110 30,000 100,000 4,200 - - - - PZ-01 9/25/2012 99.7 138 119 1,900 319,000 806,000 - PZ-01 4/17/2013 182 64.3 200 55.6 240 95,500 217,000 4,960 - - - - PZ-01 9/10/2013 82.7 72.1 17.8 -- 179,000 485,000 6,530 - - PZ-01 4/6/2014 56.7 148 28.3 - - 98,900 1,430,000 5,000 - - - - PZ-01 9/3/2014 52,800 778 280 69,200 27 3,130 - - 162,000 503,000 - PZ-01 4/1/2015 60.1 87 11.4 - -- 91,900 290,000 - 8.1 16.5 509 2.19 17.4 7.51 PZ-01 9/8/2015 -- -- -- -- -- -- - - - -- - -- -- PZ-01 3/7/2016 72,000 1,100 220 110,000 58 2,800 - - 110,000 260,000 - - - - - - PZ-01 9/7/2016 -- -- -- -- -- -- - - - -- -- - - PZ-01 3/27/2017 - - PZ-01 9/25/2017 - - APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 9 of 10 Analyte c •� Q y i Q 'C M m -E a M U E L U OQ _ O U C O i M a)@ J rN C a i N Z 7 N N fn > to U N Z w Z c w 3 U) N N > p G �0, O H O R O ram. O H m 2 a N N m U y d d m Q. E y H E C1 U) 3 " C1 c O w N O- to Z 3 H E � - C O d O Cl d is 'a X O J C1 E G1 x O > o N N C 2L Ground Water Standard 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 10,000 250,000 500,000 NE 6.5-8.5 NE NE NE NE NE Sample Date PZ-01 3/5/2018 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- PZ-01 9/11/2018 - - - - - - - PZ-02 1/4/2011 -- 120 -- 770 410 -- 180,000 360,000 - - - - - - PZ-02 4/20/2011 4,200 99 6.9 2.7 7,400 3.4 410 0.14 100 82,000 250,000 6,700 - - - - PZ-02 9/25/2012 113 106 38.9 2,000 306,000 767,000 - PZ-02 4/17/2013 222 63.7 247 28.4 180 98,200 197,000 4,630 - - - - PZ-02 9/10/2013 83.9 83.8 13.8 -- 169,000 455,000 6,250 - - - PZ-02 4/6/2014 114 54 180 12 - -- 93,800 255,000 4,000 - - - - - - PZ-02 9/4/2014 4,250 122 5.7 7,330 464 - - 159,000 511,000 - PZ-02 4/1/2015 58.4 159 9.7 - -- 82,200 267,000 - 8.2 15.9 466 3.17 18.7 8.05 PZ-02 9/8/2015 41,000 560 9.5 66 85,000 30 9,600 - - 97,000 340,000 - -- -- -- -- -- - PZ-02 3/7/2016 49,000 810 3.4 69 110,000 34 16,000 - - 38,000 140,000 - - - - - - - PZ-02 9/7/2016 1,900 230 1.3 19,000 8.5 4,500 - - 59,000 240,000 - - - - - - - PZ-02 3/27/2017 11,000 270 7.5 20 33,000 8.1 6,400 - - 63,000 210,000 B PZ-02 9/25/2017 15,000 B 200 6.2 21 24,000 8.4 2,600 - - 55,000 250,000 - 7.5 21.3 373 4.84 -18.8 14.52 PZ-02 3/5/2018 3,100 220 9.3 5.3 26,000 6.8 2,700 - - 66,000 240,000 - -- -- -- -- -- PZ-02 9/11/2018 14,000 280 9.5 31 45,000 16 1,800 - - 57,000 280,000 - -- -- -- -- -- -- PZ-02 3/19/2019 55 36 1.7 390 17 - -- 25,000 120,000 6.0 8.3 192 60.9 157 6.2 PZ-02 9/3/2019 160 62 5.3 770 450 - - 46,000 230,000 - -- -- -- -- -- -- PZ-02 4/1/2020 69,000 710 20 80 130,000 38 7,200 7.4 33,000 160,000 - - - - - - PZ-02 9/23/2020 -- - -- -- -- - -- -- -- -- 24,000 180,000 - - PZ-03 1/5/2011 140 9.4 14,000 1,700 - - 24,000 140,000 - - - - - - - PZ-03 4/21/2011 55 6,700 560 49 25,000 100,000 3,000 - - - - PZ-03 9/25/2012 - -- -- -- -- - - -- -- -- - - PZ-03 4/17/2013 914 55.7 1,090 10.2 30,500 87,000 3,230 - - - - - - PZ-03 9/9/2013 68.6 179 7.2 45,200 158,000 13,300 - - - - PZ-03 4/6/2014 205 51.2 265 - - 25,200 119,000 2,500 - - - - - - PZ-03 9/4/2014 80 233 62.5 - - 37,300 177,000 - - - - - - - PZ-03 4/1/2015 143 57.9 335 5.4 - - 30,400 105,000 - 10.4 10.8 178 4.58 12 9.91 PZ-03 9/8/2015 110 J 82 180 17 - - 56,000 210,000 -- -- -- -- -- -- PZ-03 3/7/2016 16,000 200 1.9 20 56,000 10 400 - - 18,000 49,000 - - - - - - - PZ-03 9/7/2016 -- -- -- -- -- -- -- - - - - - -- -- - - PZ-03 3/27/2017 - - - - - - PZ-03 9/25/2017 - - - - - - - PZ-03 3/5/2018 - - - - - - - - - PZ-03 9/11/2018 - - - - - - - PZ-04 1/5/2011 -- 170 12 10,000 89 - - 46,000 190,000 - - - - - - PZ-04 4/21/2011 170 58 450 15 52 24,000 78,000 2,300 - - - - PZ-04 9/25/2012 168 81.7 285 40.5 58,400 181,000 - - - - - - - PZ-04 4/17/2013 889 53.7 1,050 12.4 30,000 89,000 3,280 - - - - - PZ-04 9/9/2013 155 61.7 307 15.8 -- 31,500 131,000 3,530 - - PZ-04 4/6/2014 295 53.3 399 5.1 - - 24,200 113,000 2,500 - - - - - - PZ-04 9/4/2014 77.5 394 52.4 - - 41,200 183,000 - - - - - - - PZ-04 4/1/2015 133 54.6 249 - - 27,200 105,000 - - 10.0 162 4.21 16.6 8.91 PZ-04 9/8/2015 -- -- -- -- - - - -- -- - - PZ-04 3/7/2016 160,000 2,500 14 200 160,000 51 3,000 - - 45,000 160,000 - - - - - - - APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 10 of 10 E N E � - N m C1 U) C U 3 O J N O y " d C1 E N R d C1 O Cl G1 Z > d c O Z d x O rN p c •� E E Q i 7 c G O m m Q. w N Mo 'a > N Analyte < y i < 'C M m -a M U L U O- O U C O M a)@ J C a N Z N N fn > rn U N w Z w 3 o7 �0, O H ram. O H 2 a E y H O- to 3 H X O U) 0 C 2L Ground Water Standard 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 10,000 250,000 500,000 NE 6.5-8.5 NE NE NE NE NE Sample Date PZ-04 9/7/2016 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- PZ-04 3/27/2017 - - - - - - - PZ-04 9/25/2017 - - - - - - - PZ-04 3/5/2018 - - - - - - - - PZ-04 9/11/2018 2,200 240 1.4 2,800 33 - - 94,000 280,000 - - - - - PZ-04 3/19/2019 130 79 1 200 12 - -- 31,000 120,000 - 7.2 8.3 171 15.7 182.5 5.06 PZ-04 4/1/2020 95,000 1,600 4.8 130 160,000 34 3,400 - - 37,000 130,000 - -- -- -- -- -- -- PZ-05 1/5/2011 -- 92 1,300 1,300 - - 130,000 510,000 PZ-05 4/21/2011 5,300 81 10 14 13,000 2.9 710 2.2 20 60 85,000 230,000 11,000 - - PZ-05 9/25/2012 -- - -- -- -- - -- -- -- -- -- -- -- -- - - PZ-05 4/17/2013 - - - - - - PZ-05 9/9/2013 - - - - - - - - PZ-05 4/6/2014 66 128 - 115,000 270,000 3,500 - - - - - - PZ-05 9/4/2014 143 129 877 567 12.9 306,000 765,000 - PZ-05 4/1/2015 494 83.4 769 82.3 - - 153,000 339,000 - 7.0 10.5 516 1.06 34 7.17 PZ-05 9/8/2015 -- -- -- -- -- -- - - - -- -- - - PZ-05 3/7/2016 41,000 2,500 52 1,300,000 27 32,000 - - 63,000 150,000 - - - - - - - PZ-05 9/7/2016 740 58 0.27 6,800 120 - - 28,000 110,000 - - - - - - - PZ-05 3/27/2017 10,000 510 5.8 30 300,000 5.8 1,100 150,000 -- - -- -- - - PZ-05 9/25/2017 6,000 B 380 0.93 11 250,000 2.7 880 - - 210,000 450,000 - 6.9 18.8 581 1,268 46 2.52 PZ-05 3/5/2018 630 370 1.6 3.2 J 230,000 1.6 2,000 2.5 J 140,000 340,000 7.0 11.0 447 -- 149 11.89 PZ-05 9/11/2018 8,000 410 8 17 170,000 3.7 5,300 - - 140,000 360,000 -- -- -- -- -- -- PZ-05 3/19/2019 2,000 55 3.2 3,400 37 - -- 55,000 160,000 5.8 8.0 211 120 173.5 4.39 PZ-05 9/3/20191 270 75 7.6 1,100 1 470 - - 170,000 400,000 -- -- -- -- -- -- PZ-05 4/1/20201 11,000 180 8.1 17 51,000 1 4.7 770 - - 35,000 150,000 - - - - - - Notes: All concentrations in micrograms per liter (ug/L) unless otherwise noted NE - Not established -- - Not sampled B - Detected in the method blank J - Estimated result < LOQ and > DL Bold with gray background indicates exceedance of NC Groundwater Standard NSA - Location inaccessible; no sample collected NSB - Obstruction in well; no sample collected NSC - Well dry; no sample collected NSD - Insufficient volume; no sample collected NSE - Well damaged; no sample collected NSF - Pump broken; no sample collected NSG - Surface water location dry; no sample collected Analysis for arsenic, copper, mercury, silver, zinc, nitrates & TOC discontinued in 2014 per Corrective Action Plan (ERM, 2/2014). Analysis for all metals analyses in PZ samples discontinued in 2020 per NCDWM authorization 7/9/2020. APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA j •EE u m .�m E E E 'a m j o L O C o G> y N £ u n N Z z n ° O N 6 O NImio H p Q C) C O O CL 3 L •N 2 L) m ` C o j O ii w oAnalyte ui ? R m 0 c 0 7 d' O 6 :C > O £oN c OI O c 0 > � £H NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE Sample Location Date SS-01 4/29/1988 118 8 86 15 220 64,000 220,000 2,810 6.8 SS-01 7/13/1989 -- 100 -- -- -- -- -- -- -- -- -- SS-01 9/6/1990 -- 64 -- -- -- -- -- 7.9 SS-01 9/21/1990 140 4.8 200 520 40,000 352,000 12,000 7.2 11.6 490 -- -- -- SS-01 10/23/1991 109 150 108,000 248,000 12,000 7.9 17.2 381 -- -- -- SS-01 3/25/1992 4,150 3.4 5,000 15.8 64 250 9,400 185,000 14,000 5.8 11.3 126 -- - SS-01 9/29/1992 160 85 190 84,000 241,000 2,000 5.7 13.8 356 -- - SS-01 3/31/1993 400 77 29 1,340 70,400 127,000 2,000 5.9 13.0 207 -- -- SS-01 9/17/1993 240 598 28 450 77,400 251,000 3,000 7.1 20.9 360 -- -- -- SS-01 3/30/1994 220 873 30 250 30,600 108,000 5,000 5.9 14.0 380 -- -- - SS-01 9/30/1994 1,300 1,690 6 84 430 64,800 255,000 30,000 7.1 19.1 332 -- -- -- SS-01 3/31/1995 3,580 2,440 106 246 190 48,900 211,000 7.8 13.9 290 -- - -- SS-01 9/29/1995 200 358 7 38 500 70,000 264,000 3,740 5.2 13.9 458 -- SS-01 3/30/1996 279 547 14 185 31,300 129,000 1,790 6.7 11.0 193 -- -- SS-01 9/27/1996 125 300 5 21 95 290 56,100 225,000 2,360 7.7 19.0 336 -- -- -- SS-01 3/29/1997 307 552 16 13 225 30,000 138,000 3,040 7.6 16.0 94 -- -- -- SS-01 9/17/1997 476 835 40 169 625 47,400 224,000 1,670 7.9 19.0 319 -- -- -- SS-01 3/27/1998 190 685 12 61 680 38,700 163,000 5,230 7.6 18.6 473 -- -- SS-01 9/30/1998 126 540 6 33 300 28,000 177,000 4,090 7.2 18.0 322 -- -- -- SS-01 3/31/1999 239 332 44 120 63,200 191,000 2,490 7.1 16.0 247 -- -- -- SS-01 9/29/1999 1,530 3,330 5 88 90 23,200 143,000 8,810 7.8 16.0 308 -- -- -- SS-01 3/16/2000 117 1,940 922 199 50,900 202,000 3,780 -- -- -- -- -- SS-01 9/15/2000 327 166 38 160 26,100 157,000 5,080 7.3 19.0 410 -- -- SS-01 3/23/2001 158 10 26,100 113,000 2,810 6.9 16.0 150 -- -- SS-01 10/4/2001 116 29 300 99,000 343,000 5,300 7.4 19.0 440 -- -- -- SS-01 3/28/2002 201 10 27 320 41,900 177,000 3,180 7.0 11.0 400 -- -- -- SS-01 10/3/2002 317 767 52 750 73,300 300,000 3,070 -- 19.0 330 -- -- -- SS-01 3/25/2003 673 607 24 115 31,600 119,000 2,080 6.9 18.0 440 -- -- SS-01 10/2/2003 705 72 446 29,400 181,000 2,380 6.3 15.0 249 -- -- SS-01 4/28/2004 179 80 374 70,400 176,000 2,060 -- 11.7 281 -- -- -- SS-01 10/26/2004 145 132 36 209 58,800 217,000 2,620 -- 397 -- -- -- SS-01 4/27/2005 105 11 149 41,400 174,000 2,150 -- 294 -- -- -- SS-01 10/20/2005 347 84 453 15 55 288 47,600 213,000 9,500 -- 232 -- -- SS-01 10/19/2006 937 1,630 130 22 226 59,200 168,000 2,970 - -- 423 -- - - SS-01 4/27/2007 446 1,240 18 188 27,400 128,000 3,600 -- 209 -- -- SS-01 11/19/2007 104 11 117 61,500 243,000 3,540 -- 371 -- -- SS-01 4/30/2008 170 242 21 238 56,300 171,000 2,690 -- -- 260 -- -- -- SS-01 10/29/2008 56.4 0.3 3 20.6 6 0.05 50.9 229 76,300 254,000 2,870 -- -- 392 -- -- -- SS-01 4/30/2009 64.8 77.8 5.4 8.3 9.9 15.9 302 52,300 211,000 4,470 -- -- 325 -- -- -- SS-01 8/26/2009 -- 72 -- 160 14 -- -- -- 45,000 -- -- 8.1 22.0 1490 10 94 9.05 SS-01 10/12/2009 89 J 2.7 J 63 0.8 J 1.1 J 86 7.3 J 370 49,000 240,000 -- 7.8 13.1 2380 8.9 160 12.7 SS-01 4/19/2010 190 64 240 12 400 33,000 190,000 4,900 8.1 12.0 557 63.1 199 10.68 SS-01 10/11/2010 52 J 1.1 J 71 1.6 J 160 16 J 36 640 40,000 240,000 -- 7.8 16.5 455 8 107 12.77 SS-01 4/20/2011 62 66 280 13 300 30,000 140,000 3,400 7.6 18.0 270 4 211 9.71 SS-01 10/18/2011 153 76.7 190 9.6 250 39,200 210,000 5,700 7.5 16.9 289 8.3 236 9.56 SS-01 3/16/2012 170 82.5 238 11 37,400 221,000 4,800 7.8 15.7 359 2.46 -27 11.3 SS-01 9/24/2012 147 94.1 146 10.2 450 47,700 257,000 -- 7.7 15.7 589 21.3 153 8.65 SS-01 4/17/2013 366 73.5 492 12.4 141 29,000 131,000 4,410 8.0 20.9 297 4.9 76.3 6.87 SS-01 9/9/2013 179 87.1 240 18.1 470 41,700 203,000 7,210 8.4 20.6 347 5.4 -173 9.4 SS-01 4/6/2014 62.2 137 60.6 -- 70,000 224,000 4,100 7.9 9.6 381 5.1 142.2 11.65 SS-01 9/3/2014 122 82.6 264 64.7 93,400 339,000 -- 8.0 21.1 396 8.01 47.4 7.32 Page 1 of 9 APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA j •EE u m .�m E E E 'a m j o L O C o G> y N £ u n N Z z n ° O N 6 O NImio H p Q C) C O O CL 3 L •N 2 L) m ` C o j O ii w oAnalyte ui ? R m 0 c 0 7 d' O 6 :C > O £oN c OI O c 0 > � £H NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE Sample Location Date SS-01 4/1/2015 146 72.2 -- 291 58.6 -- -- -- -- 69,100 216,000 7.8 17.1 552 3.1 39.6 9.74 SS-01 9/9/2015 7,600 - 190 11 129000 6.2 J 660 93,000 280,000 B -- -- -- -- -- SS-01 3/8/2016 240 -- 63 350 20 29,000 93,000 8.9 9.1 440 -- 98.1 12.3 SS-01 9/7/2016 71 - 67 220 6.3 35,000 200,000 -- -- -- -- -- SS-01 9/7/2016 57 72 210 5.2 32,000 210,000 8.6 21.9 298 3.6 49 8.1 SS-01 3/27/2017 160 - 61 1,400 800 3.6 J 460,000 1,0009000 E 7.6 17.0 1 -- 68 10.6 SS-01 5/8/2017 590 B 57 660 6.8 23,000 150,000 -- -- -- -- -- -- SS-01 9/25/2017 130 B 84 250 8.6 40,000 240,000 8.0 20.2 322 3.33 61 8.23 SS-01 3/5/2018 55 69 140 9.2 38,000 190,000 8.1 11.1 289 3.2 186 10.28 SS-01 9/11/2018 150 - 84 470 22 36,000 1,200,000 8.1 21.8 380 6.07 101 5.84 SS-01 3/18/2019 230 -- 51 590 7.4 20,000 150,000 7.7 11.7 212 9.98 212.9 13.45 SS-01 9/4/2019 250 77 380 11 32,000 200,000 8.1 19.6 293 12.4 -28.6 6.39 SS-01 2/17/2020 3,100 64 3,400 1.2 26 23,000 150,000 7.8 10.4 219 34.9 216 9.58 SS-01 2/24/2020 1,200 - 63 1,600 16 25,000 170,000 8.6 7.7 233 16.2 192 10.95 SS-01 4/1/2020 490 -- 59 690 8.6 26,000 150,000 8.5 11.7 225 34.2 49.5 8.58 SS-01 9/23/2020 1,000 - 82 1,400 25 31,000 200,000 7.7 15.5 316 34.2 16.7 7.06 SS-01+150 2/17/2020 2,700 -- 61 3,400 1.2 24 21,000 150,000 7.8 10.4 208 33.1 232 9.76 SS-01+150 2/24/2020 1,500 -- 67 1,700 49 34,000 180,000 8.2 7.8 198 17.8 209 12.08 SS-01+550 2/17/2020 2,400 -- 60 2,700 1 32 26,000 160,000 7.7 10.2 207 26.4 234 10.26 SS-01+550 2/24/2020 1,300 -- 65 1,400 33 33,000 170,000 8.3 7.9 256 13.2 205 10.26 SS-01+850 2/17/2020 2,500 59 2,700 36 29,000 160,000 7.7 10.0 221 25.2 243 9.42 SS-01+850 2/24/2020 1,100 -- 66 1,300 27 33,000 180,000 8.2 7.9 249 13.9 207 12.28 SS-02 9/21/1990 130 94 4.6 100 -- 1,140 47,000 141,000 15,000 7.5 14.6 607 -- -- -- SS-02 10/23/1991 -- 170 820 711 80 1,020 490,000 8069000 10,000 7.8 18.0 1280 -- -- -- SS-02 3/26/1992 7,650 2.1 8,070 12.9 130 250 13,100 149,000 12,000 6.0 11.5 111 -- -- -- SS-02 9/30/1992 330 -- -- 7.3 550 183,000 474,000 3,000 6.1 15.1 778 -- -- -- SS-02 3/31/1993 208 675 327 350 70,400 185,000 4,000 5.8 14.1 341 -- SS-02 9/17/1993 470 1,270 722 2,300 154,000 523,000 4,000 7.5 22.2 754 -- -- -- SS-02 3/30/1994 220 32 1,120 117 165 320 40,000 143,000 -- 6.0 14.4 692 -- -- SS-02 9/30/1994 120 28 470 356 24 325 135,000 397,000 37,900 7.4 18.6 573 -- -- -- SS-02 3/31/1995 165 526 332 41 750 102,000 342,000 -- 7.9 14.5 496 -- -- -- SS-02 9/29/1995 406 1,020 6 598 1,030 155,000 5059000 2,680 5.6 13.5 1095 -- -- - SS-02 3/30/1996 426 787 250 190 30,600 198,000 2,990 6.5 12.0 282 -- -- -- SS-02 9/27/1996 61 227 10 262 47 750 147,000 409,000 3,190 7.6 20.0 613 -- -- -- SS-02 3/29/1997 209 644 246 10 450 72,800 255,000 2,470 7.8 16.0 224 -- -- -- SS-02 9/17/1997 165 428 6 333 153 2,210 160,000 562,000 2,430 7.8 18.0 826 -- -- -- SS-02 3/27/1998 220 960 363 32 550 94,200 324,000 3,960 7.8 17.5 724 -- -- -- SS-02 9/30/1998 100 1 1 595 351 1,550 89,200 444,000 6,850 7.4 19.0 368 -- -- -- SS-02 3/31/1999 129 947 587 1,550 204,000 420,000 3,260 7.4 17.0 340 -- -- -- SS-02 9/29/1999 1,380 3,030 147 21 160 45,700 173,000 8,100 7.6 17.0 623 -- -- -- SS-02 3/16/2000 960 464 1,180 175,000 500,000 3,750 -- -- -- -- -- -- SS-02 9/15/2000 283 225 416 1,240 170,000 439,000 6,580 7.4 20.0 640 -- -- -- SS-02 3/23/2001 108 260 7 135 34 103 71,900 224,000 3,080 6.6 16.0 170 -- -- -- SS-02 10/4/2001 166 746 8 910 6,320 421,000 192509000 27,000 7.2 19.0 680 -- -- -- SS-02 3/28/2002 121 502 206 320 127,000 405,000 2,970 7.4 11.0 510 -- -- -- SS-02 10/3/2002 220 494 549 1,110 266,000 5179000 4,280 5.8 18.0 130 -- - SS-02 3/25/2003 1,570 1,280 6 264 24 162 90,300 234,000 1,910 6.0 18.0 1260 -- -- -- Page 2 of 9 APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Analyte j E E E 'a m j O L O C o � G> y N £ (n n N Z z n ° O N 6 O N H p Q C) C O O CL 3 L •N 2 L) m m d N C o � j O 0 w � U) H R m 0 c 0 7 d' 22 m :2 > O E c OI O > O N 0 o� £ NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE Sample Location Date SS-02 (FD) 3/25/2003 11750 1,320 265 24 194 94,600 235,000 2,000 6.0 18.0 1260 SS-02 10/2/2003 1,010 546 610 115,000 395,000 2,500 6.5 14.0 556 SS-02 4/28/2004 109 400 417 608 220,000 394,000 2,260 -- 12.7 623 SS-02 10/26/2004 216 839 582 2,000 276,000 554,000 3,060 807 SS-02 4/27/2005 356 272 648 37,600 460,000 2,480 737 SS-02 10/20/2005 72 1,120 330 48 546 240,000 571,000 3,400 419 SS-02 10/19/2006 530 1,060 534 32 299 204,000 422,000 3,490 550 SS-02 4/27/2007 389 811 488 333 439,000 303,000 4,420 511 SS-02 11/19/2007 136 308 23 258 300,000 647,000 3,540 908 SS-02 4/30/2008 278 254 46 285 159,000 371,000 2,740 569 SS-02 10/29/2008 56.3 0.24 128 318 14.2 407 342,000 708,000 3,430 1070 SS-02 4/30/2009 60.8 89.4 222 19.2 499 201,000 518,000 3,390 821 SS-02 8/26/2009 -- -- 71 110 220 -- -- 310,000 -- -- 7.8 21.6 2120 6.4 101 6.38 SS-02 10/12/2009 43 J 5.1 J 60 0.8 J 45 J 48 320 210,000 510,000 -- 7.8 13.3 3360 8.7 123 12.95 SS-02 4/19/2010 64 10 260 260 420 150,000 390,000 6,300 7.6 10.6 632 60.1 181 10.21 SS-02 10/11/2010 1.1 J 69 1.4 J 270 310 8.9 6.4 J 1,200 250,000 660,000 -- 7.6 15.2 999 -- 113 8.29 SS-02 4/20/2011 63 270 150 4 630 120,000 360,000 3,000 7.6 18.6 602 4.2 241 9.7 SS-02 10/18/2011 74.9 181 266 470 202,000 582,000 7,300 7.4 17.6 536 4.6 248 9.7 SS-02 3/16/2012 71.8 171 65.8 1,600 152,000 614,000 6,300 7.6 15.4 781 3.4 14.5 11.52 SS-02 9/25/2012 97.6 236 301 1,600 400,000 858,000 -- 8.5 16.2 1420 9.7 181 9.08 SS-02 4/17/2013 194 71.4 242 110 214 79,100 207,000 5,030 8.1 20.8 382 4.7 79.6 7.97 SS-02 9/10/2013 10C 83 135 102 1,160 167,000 493,000 6,290 8.0 19.8 657 8.2 99.8 7.11 SS-02 4/6/2014 133 56.4 194 21.2 -- 87,000 277,000 5,000 8.9 14.0 445 7.52 138.1 12.13 SS-02 9/3/2014 83.7 68.6 11.1 158,000 526,000 -- 8.1 23.4 733 2.45 61.3 5.09 SS-02 4/1/2015 59 96.1 16.7 92,200 297,000 8.1 15.0 508 1.81 9.6 8.13 SS-02 9/8/2015 260 J 100 1.1 J 450 70 160,000 460,000 -- -- -- -- -- -- SS-02 3/8/2016 150 65 260 36 1.7 61,000 180,000 8.4 8.5 368 -- 227.1 11.32 SS-02 9/7/2016 150 81 0.1 490 44 86,000 300,000 8.5 21.8 452 4.6 89 8.4 SS-02 3/27/2017 65 74 0.5 210 11 68,000 250,000 B 7.2 16.1 403 1.8 169 9.62 SS-02 9/25/2017 86 B 88 0.5 200 43 88,000 310,000 8.0 19.7 458 1.18 183.9 8.41 SS-02 3/5/2018 37 J 69 0.5 160 27 92,000 300,000 8.0 9.9 457 4.6 179 11.75 SS-02 9/11/2018 83 0.5 250 52 89,000 320,000 7.9 22.1 533 4.8 110 5.12 SS-02 3/18/2019 150 47 0.5 530 23 34,000 170,000 6.9 10.7 250 7.68 175.3 12.34 SS-02 9/3/2019 150 80 0.5 240 30 60,000 250,000 7.4 22.6 376 8.62 -15.4 6.3 SS-02 2/17/2020 1,900 60 0.5 2,400 34 30,000 160,000 7.6 10.0 216 24.8 265 9.28 SS-02 2/24/2020 1,100 68 0.5 1,300 40 42,000 190,000 8.0 8.1 294 21.4 208 11.96 SS-02 4/1/2020 450 47 0.5 580 18 38,000 150,000 9.1 12.4 245 13.5 42.7 9.13 SS-02 (FD) 4/1/2020 400 46 0.5 600 18 38,000 160,000 -- -- -- -- -- -- SS-02 9/23/2020 11200 74 0.5 1,400 39 49,000 230,000 8.0 15.6 372 28.4 9 7.32 SS-10 8/11/2009 -- 65 12,000 400 11,000 -- 7.1 20.6 1890 42.9 -40 3.38 SS-15 8/11/2009 52 900 35 7,500 7.8 20.7 1840 52.5 114 9.65 SS-20 8/11/2009 58 800 46 8,200 8.4 23.9 1112 27.3 58 7.63 SS-20 4/21/2011 190 54 550 17 100 4,800 96,000 1,900 7.7 14.6 87 14.2 128 9.4 SS-20 9/24/2012 378 51.4 1,580 51.1 ( 3,600 89,000 -- 7.3 15.6 146 10.3 159 8.55 SS-20 4/17/2013 788 56 1,050 19.8 5,590 55,000 2,760 7.5 19.8 283 7.2 158 8.7 SS-20 9/9/2013 456 60.3 1,170 48.4 274 3,610 78,000 2,280 7.4 21.7 97 9.7 24.2 8.37 SS-20 4/6/2014 126 54.2 269 6 -- 5,200 68,000 1,900 8.1 9.6 212 14.4 134.7 10.32 SS-20 1 9/3/20141 818 73.7 2,450 71.4 3,600 97,000 -- 7.4 20.6 100 20.9 -12.5 5.33 Page 3 of 9 APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Analyte j E •E Q u m Q .� m E ' E 'a m L) j o L U o 0 C o -j G> y N a a £ (n in N Z z cn ° O N 6 O N H p Q C) C O O � CL 3 L •N L) io m m C of � ° j O 0« uoi ' H ? R m 0 c 0 7 d' O C> O £ c OI O N > c N o £ NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE Sample Location Date SS-20 4/1/2015 2,320 105 4,840 99.1 -- -- -- -- 5,000 66,000 7.7 14.9 103 7.26 7.2 7.59 SS-20 9/9/2015 4,700 130 - 5 5.8 J 7,600 170 3,900 90,000 B -- -- -- -- -- -- SS-20 3/8/2016 470 53 0.1 450 8.9 4,300 65,000 7.9 12.1 74 -- 113.9 8.72 SS-20 9/7/2016 310 59 0.1 1,100 36 1,600 89,000 7.6 19.4 80 3.2 59 8.4 SS-20 3/27/2017 2,400 120 0.5 4,700 1.4 280 3,100 62,000 B 7.5 16.3 179 9.7 97.8 8.97 SS-20 9/25/2017 3,200 B 110 0.5 4.6 J 5,500 1.6 140 2,900 69,000 6.9 20.4 84 16.1 -22.3 6.04 SS-20 3/5/2018 120 57 0.5 420 23 4,100 80,000 7.6 10.8 74 7 201 9.63 SS-20 9/11/2018 370 67 0.5 1,600 85 3,300 75,000 7.6 21.3 117 24.3 70 5.11 SS-20 3/18/2019 550 54 0.5 680 8.1 4,300 84,000 7.5 10.5 70 13.2 219.4 8.86 SS-20 9/3/2019 3,700 110 0.5 5,300 2 130 3,100 94,000 6.0 20.7 101 23.9 16.8 6.56 SS-20 2/17/2020 2,200 51 0.5 2,500 1 19 8,700 79,000 7.5 9000.0 86 23 227 8.96 SS-20 2/24/2020 1,400 49 0.5 1,800 16 8,800 86,000 8.6 7.1 97 15.8 190 9.83 SS-20 4/1/2020 1,800 47 0.5 1,600 13 9,300 76,000 6.6 11.8 88 23.4 73.1 9.41 SS-20 9/23/2020 4,800 59 0.5 6,000 2 88 8,000 120,000 6.9 15.7 129 85.6 1,280 7.3 SS-25 8/11/2009 -- 60 1 590 53 -- 28,000 -- 8.4 22.1 1830 32.1 75 7.57 SS-25 4/21/2011 150 50 470 8.2 40 5,000 100,000 1,900 7.6 14.8 89 15.5 128 9.66 SS-25 9/24/2012 508 52.2 1,580 103 22 39,800 156,000 -- 7.2 15.9 257 13.6 145 8.44 SS-25 4/17/2013 820 54.9 1,170 32.6 5,810 62,000 2,940 7.5 19.6 336 6.8 163 8.9 SS-25 9/9/2013 345 54.3 809 23.8 60.9 3,650 82,000 2,590 7.4 20.3 134 5.9 23.7 8.26 SS-25 4/6/2014 310 51.1 555 13.8 -- 5,500 75,000 2,000 7.1 9.6 83 11.9 86.6 10.42 SS-25 9/3/2014 2,000 83.3 3,880 79.3 3,400 100,000 -- 7.4 21.4 92 32.1 -11.9 5.63 SS-25 4/1/2015 292 53.4 649 10.6 5,200 74,000 7.1 15.0 89 9.45 16.3 5.93 SS-25 9/9/2015 660 63 - 5 1,500 58 3,700 85,000 B -- -- -- -- -- -- SS-25 3/8/2016 1,700 92 0.1 2,500 1.8 90 4,700 83,000 8.3 12.8 73 -- 63 11.8 SS-25 9/7/2016 1,400 77 0.1 3,200 81 1,700 86,000 8.0 19.7 64 2.9 43 8.2 SS-25 3/27/2017 390 62 0.5 590 9.4 3,100 73,000 B 7.6 16.7 121 7.4 101 8.02 SS-25 9/25/2017 780 B 56 0.5 1.6 J 1,200 0.29 J 27 2,500 74,000 7.1 20.0 88 11.5 15.3 6.9 SS-25 3/5/2018 210 47 0.5 400 15 4,200 78,000 7.8 11.4 78 13.5 191 8.84 SS-25 9/11/2018 270 53 0.5 1,100 32 2,600 88,000 7.2 21.4 123 18.3 82.8 5.04 SS-25 3/18/2019 610 51 0.5 700 5.5 4,400 69,000 7.8 10.3 70 14.4 226.5 8.44 SS-25 9/3/2019 1,700 70 0.5 2,700 45 3,200 100,000 6.2 21.2 100 60.12 8.9 6.02 SS-25 2/17/2020 2,800 55 0.5 3,600 1.5 25 8,500 81,000 7.5 9.6 79 33.5 251 8.82 SS-25 2/24/2020 1,300 46 0.5 1,500 9.8 8,700 93,000 8.4 7.3 86 24.9 199 10.2 SS-25 4/1/2020 1,700 48 0.5 1,500 9.5 9,200 70,000 6.9 11.7 89 20.8 71 9.8 SS-25 9/23/2020 4,400 58 0.5 4,900 1.8 60 8,300 110,000 6.8 15.6 125 91 1,157 7.46 SS-30 8/11/2009 -- 72 150 25 95,000 -- 8.5 22.8 5250 21.7 57 8.1 SS-30 1/5/2011 -- 77 330 130 63,000 370,000 8.6 3.9 388 6.9 132 10.43 SS-30 4/20/2011 67 220 8.9 330 27,000 160,000 2,800 7.4 17.9 283 3.9 238 9.47 SS-30 9/24/2012 163 88 175 19.8 280 84,700 312,000 -- 7.8 15.4 567 14.9 152 8.77 SS-30 4/17/2013 352 76.4 455 13.2 194 31,000 144,000 18,200 7.8 21.1 268 8.7 62.1 6.24 SS-30 9/9/2013 158 86.2 237 18.6 498 45,600 220,000 4,990 8.1 20.4 318 4.59 17.9 7.13 SS-30 4/6/2014 61.6 159 -- 33,200 170,000 4,000 8.0 9.5 270 5.52 159.3 16.21 SS-30 9/3/2014 145 84.3 277 16.4 43,600 253,000 -- 8.4 21.4 308 11 16.6 6.96 SS-30 4/1/2015 173 67.1 291 11.2 43,200 191,000 7.9 16.5 348 6.3 6.2 7.66 SS-30 9/9/2015 86 110 5.8 J 98,000 280,000 B -- -- -- -- -- -- SS-30 3/8/2016 870 67 1,000 32 31,000 150,000 8.5 9.3 275 -- 164.2 12.04 SS-30 9/7/2016 470 70 0.1 970 44 48,000 270,000 8.5 21.6 357 2.8 48 8.5 SS-30 3/27/2017 160 70 0.5 370 10 41,000 200,000 B 7.8 16.1 343 2.8 114 10.33 SS-30 9/25/2017 200 B 91 0.5 360 11 41,000 220,000 7.9 20.9 335 3.76 66.3 7.84 Page 4 of 9 APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Analyte j E .E Q u m Q .� m E ' E 'a m L) j o L U o 0 C o -j G> y N a a £ (n in N Z z cn ° O N 6 O N H p Q C) C O O � CL 3 L •N L) io m m C of � ° j O 0« uoi ' H ? R m 0 c 0 7 d' O C> O £ c OI O N > c N o £ NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE Sample Location Date SS-30 3/5/2018 66 64 v.o 180 9.8 -- -- -- -- 51,000 240,000 8.0 17.0 357 9.7 197 10.97 SS-30 9/11/2018 130 71 0.5 480 26 52,000 260,000 8.1 21.3 442 10.2 106 6.1 SS-30 3/18/2019 360 54 0.5 880 19 24,000 150,000 7.9 11.5 239 13 216.7 10.14 SS-30 9/4/2019 350 86 0.5 570 14 34,000 220,000 8.0 19.5 301 14.4 -28.6 6.39 SS-30 2/17/2020 3,200 64 0.5 3,600 1.5 62 27,000 200,000 7.6 10.1 240 9.65 259 9.85 SS-30 2/24/2020 1,800 66 0.5 2,500 65 32,000 210,000 8.5 7.6 269 24.2 202 10.23 SS-30 4/1/2020 1,300 59 0.5 1,800 18 31,000 160,000 7.4 11.8 262 24.1 63.3 10.12 SS-30 9/23/2020 3,800 81 0.5 4,300 1.4 56 37,000 220,000 7.5 15.5 340 61.1 18.2 7.46 SS-35 9/8/2015 100 72 J 28 170,000 470,000 -- -- -- -- -- -- SS-40 8/26/2009 -- 91 80 22 300,000 -- 7.8 21.3 2050 7.1 89 7.89 SS-40 4/20/2011 57 59 330 59 0.25 2.1 810 110,000 270,000 2,900 7.3 17.5 494 4.6 223 10.23 SS-40 9/25/2012 112 139 39 2,000 297,000 755,000 -- 8.0 14.8 1260 9.8 174 9.28 SS-40 4/17/2013 221 60.7 294 25.7 179 73,200 195,000 4,980 8.2 19.9 329 4.9 68.9 6.94 SS-40 9/10/2013 89.6 92.5 15.5 20.4 1,440 165,000 450,000 6,230 7.9 19.8 610 5.7 87.8 8.43 SS-40 4/6/2014 53.2 185 11.5 -- -- 81,600 256,000 16,200 9.2 14.0 397 8.31 138.7 11.39 SS-40 9/3/2014 86.5 58.1 9.5 152,000 473,000 -- 8.1 23.7 689 2.45 69.4 4.91 SS-40 4/1/2015 58.5 154 10.8 84,200 264,000 8.0 18.3 469 4.19 13.5 8.25 SS-40 9/8/2015 210 J 110 370 48 160,000 440,000 -- -- -- -- -- SS-40 3/8/2016 220 62 310 12 57,000 180,000 8.4 8.9 333 -- 238.2 13.44 SS-40 9/7/2016 540 94 0.1 1,300 100 78,000 290,000 8.2 21.0 427 3.2 121 7.7 SS-40 3/27/2017 91 67 0.5 240 7.9 65,000 230,000 B 8.0 16.9 357 1.8 154 111.1 SS-40 9/25/2017 100 B 85 0.5 210 17 80,000 280,000 8.1 19.9 425 3.24 121 8.57 SS-40 3/5/2018 45 64 0.5 130 5.8 84,000 290,000 8.2 9.8 417 2.6 190 11.82 SS-40 9/11/2018 79 0.5 210 14 78,000 300,000 7.7 22.0 498 5.03 99.5 4.91 SS-40 3/18/2019 160 47 0.5 480 9.3 32,000 150,000 7.4 10.4 231 7.92 175.8 12.25 SS-40 9/3/2019 75 77 0.5 190 10 51,000 230,000 7.0 21.9 336 4.27 -1.4 5.58 SS-40 2/17/2020 2,600 60 0.5 3,000 1 29 27,000 150,000 7.7 9.0 200 11.13 248 11.18 SS-40 2/24/2020 1,200 66 0.5 1,300 17 37,000 190,000 7.9 7.5 268 10.3 207 13.79 SS-40 4/1/2020 280 48 0.5 400 9 24,000 110,000 8.7 11.9 192 10.9 29.2 9.97 SS-40 9/23/2020 550 73 0.5 740 22 42,000 230,000 8.1 15.2 297 22.4 2.5 7.01 SS-50 8/11/2009 -- 29 2,900 180 5,600 -- 7.8 25.4 1180 32 -21 8.52 SS-50 4/21/2011 120 36 1,100 85 130 3,700 71,000 2,000 6.9 14.7 85 16.3 92 9.88 SS-50 9/25/2012 410 41.9 1,640 110 140 72,000 -- 8.7 17.6 161 9.6 16 8.76 SS-50 4/17/2013 -- -- - -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- SS-50 9/9/2013 SS-50 4/6/2014 -- -- -- -- -- -- -- -- -- -- -- -- -- -- SS-50 9/3/2014 SS-50 4/1/2015 886 49.4 4,620 168 2,900 63,000 7.0 13.5 90 18.8 -6.3 13.7 SS-50 9/9/2015 160,000 2,900 1.6 J 250 850,000 100 16,000 640 J 75,000 B -- -- -- -- -- -- SS-50 3/8/2016 930 46 0.1 1,700 46 -- -- 7.9 12.5 72 -- 111.8 9.84 SS-50 9/7/2016 410 49 0.1 < 5 2,900 180 99,000 8.0 22.8 121 3.6 50 6.9 SS-50 3/27/2017 230 46 0.5 < 5 650 - 13 1,600 130,000 6.5 18.3 9 47.4 195 11.54 SS-50 9/25/2017 960 B 52 0.5 2.1 J 2,200 0.56 J 93 1,300 23,000 6.9 20.3 84 14.7 13.2 7.71 SS-50 3/5/2018 86 40 0.5 < 5 530 '" 22 2,900 68,000 7.4 11.4 74 14.8 213 11.87 SS-50 9/11/2018 -- -- -- I -- -- -- -- - -- -- SS-50 3/18/2019 240 40 0.5 < 5 740 25 3,700 72,000 7.5 9.7 73 11.8 145.8 8.69 SS-50 9/3/2019 1,400 54 0.5 < 5 3,000 93 1,400 78,000 5.2 22.0 104 24.8 6.8 6.85 SS-50 4/1/2020 660 47 0.5 < 5 2,300 96 2,800 74,000 7.6 12.4 74 31.5 22.1 9.81 Page 5 of 9 APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Analyte j E .E Q u m Q .� m E ' E 'a m L) j o L U o 0 C o -j G> y N a a £ (n in N Z z cn ° O N 6 O N H p Q C) C O O � CL 3 L •N L) io m m C of � ° j O 0« uoi ' H ? R m 0 c 0 7 d' O C> O £ c OI O N > c N o £ NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE Sample Location Date SS-50 9/23/2020 820 58 -- 4,400 1.1 180 -- -- -- -- 1,200 71,000 7.3 15.1 68 28 1,470 8.03 SS-60 8/26/2009 -- 140 280 980 -- 350,000 -- 7.1 20.3 4040 65.9 10 6.69 SS-60 4/21/2011 68 61 240 11 4.1 120 130,000 270,000 2,700 7.2 15.9 446 14.3 177 8.89 SS-60 9/25/2012 120 75.9 312 85 58,100 191,000 -- 8.4 12.5 337 11.7 179 8.75 SS-60 4/17/2013 534 63.4 667 43.8 164,000 274,000 4,170 7.8 20.2 380 8.6 70.6 10.79 SS-60 9/10/2013 103 120 116 75.5 2,120 275,000 663,000 6,150 7.5 21.0 423 8.4 87.6 8.17 SS-60 4/6/2014 154 64.9 175 5.7 -- 119,000 234,000 3,300 7.6 13.6 421 5.94 186.4 12.81 SS-60 9/4/2014 127 709 537 16.8 290,000 717,000 -- 7.1 20.8 845 7.26 -3.4 4.53 SS-60 4/1/2015 1,320 93 2,140 69.5 159,000 359,000 7.1 9.7 538 18.8 1.56 6.6 SS-60 9/8/2015 190 J 57 410 33 13,000 110,000 -- -- -- -- -- -- SS-60 3/8/2016 510 68 410 8.6 3 120,000 270,000 7.8 9.3 375 -- 252.1 10.62 SS-60 9/7/2016 780 130 21400 160 250,000 490,000 7.5 20.1 666 4.7 39 6.5 SS-60 3/27/2017 4,500 160 _._ 5.5 7,800 2.7 190 1.5 J 190,000 410,000 B 7.1 14.7 4 297 194 7.03 SS-60 9/25/2017 34 BJ 130 0.5 260 89 270,000 570,000 7.3 18.9 763 1.16 54 3.31 SS-60 3/5/2018 140 93 0.5 280 19 170,000 370,000 7.1 10.1 522 44.7 156 12.41 SS-60 9/11/2018 120 0.5 810 330 240,000 620,000 7.3 21.5 916 4.97 76.3 2.06 SS-60 3/18/2019 560 41 0.5 750 7.9 13,000 78,000 7.2 11.2 91 12.6 213 12.51 SS-60 4/1/2020 650 54 0.5 690 7.3 62,000 160,000 7.4 11.4 232 13.7 78.9 7.91 SS-60 9/23/2020 200 53 0.5 490 25 9,300 110,000 8.6 15.5 119 6.12 -8.8 6.86 SS-65 9/8/2015 780 80 1.3 J 1,300 96 44,000 150,000 -- -- -- -- -- -- SS-70 8/26/2009 -- 120 1,100 250 65,000 -- 6.9 20.6 2520 6.8 91 6.44 SS-70 4/21/2011 160 50 380 5.8 0.12 53 23,000 92,000 2,300 7.0 16.4 138 8.3 189 10.27 SS-70 9/25/2012 120 82.4 303 58.7 61,300 203,000 -- 8.2 12.6 367 10.1 143 8.34 SS-70 4/17/2013 694 51.3 986 13.4 24,100 89,000 3,330 8.0 19.3 129 7.3 60.9 7.67 SS-70 9/10/2013 135 58.8 299 13.6 1,390 28,600 123,000 3,510 7.9 20.9 419 7.6 85.3 8.07 SS-70 4/6/2014 374 47.7 479 5.3 -- 21,000 86,000 2,300 7.5 13.3 125 8.3 165 9.85 SS-70 9/4/2014 79.9 305 71.1 35,000 146,000 -- 7.7 21.0 217 3.68 22.3 7.26 SS-70 4/1/2015 147 55.1 282 8.4 27,300 93,000 7.4 11.1 159 1.56 5.01 8.21 SS-70 9/8/2015 95 J 71 260 27 33,000 160,000 -- -- -- -- -- -- SS-70 3/8/2016 640 47 540 5.7 18,000 90,000 8.2 10.0 113 -- 244.2 11.35 SS-70 9/7/2016 160 52 0.1 470 18 1,600 81,000 7.5 19.9 93 5.3 26 7.6 SS-70 3/27/2017 170 56 0.5 270 4.2 J 21,000 93,000 B 7.5 16.5 722 6.2 170 7.92 SS-70 9/25/2017 350B 62 0.5 1.3J 530 28 11,000 74,000 7.5 19.2 122 7.69 158.8 7.14 SS-70 3/5/2018 78 44 0.5 150 7.2 20,000 91,000 7.3 11.0 120 1.4 197 7.9 SS-70 9/11/2018 86 60 0.5 480 31 8,000 97,000 7.7 21.4 152 4.94 111 5.3 SS-70 3/18/2019 360 45 0.5 500 5.7 14,000 83,000 7.5 11.0 96 10.2 209.7 10.53 SS-70 9/3/2019 91 55 0.5 410 27 16,000 110,000 6.7 22.0 138 4.27 2.3 5.14 SS-70 4/1/2020 630 43 0.5 840 14 12,000 77,000 7.2 11.9 87 14.4 62.9 9.74 SS-70 9/23/2020 170 57 0.5 350 12 12,000 96,000 8.2 15.7 75 5.61 12.8 8.31 SS-75 9/8/2015 78 S 230 26 9.9 J 41,000 170,000 -- -- -- -- -- -- SS-80 8/26/2009 -- 120 250 25 82,000 -- 7.1 20.6 5190 5.8 100 8.34 SS-80 4/21/2011 110 56 310 99 27,000 120,000 2,100 6.8 15.5 161 6.8 92 10.61 SS-80 9/25/2012 192 87 263 15.9 74,600 270,000 -- 8.5 11.7 399 4.8 205 9.08 SS-80 4/17/2013 643 52.5 921 7.5 27,600 88,000 3,170 7.4 20.1 139 7.6 70.8 7.14 SS-80 9/10/2013 110 71.5 211 8.3 265 47,600 152,000 3,430 7.7 21.6 417 6.9 87.9 7.92 SS-80 4/6/20141 180 1 53.7 328 -- 17,500 84,000 2,400 7.4 13.9 106 8.7 136.2 11.78 Page 6 of 9 APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Analyte j E .E Q u m Q .� m E ' E 'a m L) j o L U o 0 C o -j G> y N a a £ (n U) N Z z U) ° O N 6 O N H p Q C) C O O � CL 3 L •N L) io m m C of � ° j O 0« uoi ' H ? R m 0 c 0 7 d' O C> O £ c OI O N > c N o £ NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE Sample Location Date SS-80 9/4/2014 149 81.1 -- 436 16.8 -- -- -- -- 30,100 155,000 8.1 21.2 245 11.3 17.5 6.98 SS-80 4/1/2015 246 58.1 382 7.1 25,500 89,000 7.9 12.8 162 4.37 4.37 9.57 SS-80 9/8/2015 84 180 14 J 41,000 170,000 -- -- -- -- -- -- SS-80 3/8/2016 640 54 U.1 530 6.4 24,000 110,000 8.5 8.8 124 -- 236.8 11.32 SS-80 9/7/2016 140 63 0.1 430 9.7 13,000 110,000 7.7 21.0 98 2.7 53 8.2 SS-80 3/27/2017 100 62 0.5 200 2.5 J 21,000 110,000 B 8.0 16.0 156 1.7 165 8.96 SS-80 9/25/2017 98 B 71 0.5 250 6.8 21,000 110,000 7.7 19.0 158 2.97 146.5 8.89 SS-80 3/5/2018 74 51 0.5 190 10 21,000 96,000 7.6 10.9 127 0.9 185 15.18 SS-80 9/11/2018 490 73 0.5 1,200 34 16,000 110,000 8.2 21.0 191 5.55 109 5.72 SS-80 3/18/2019 400 45 0.5 560 13,000 90,000 7.6 9.9 97 9.89 196.2 9.74 SS-80 9/3/2019 240 67 0.5 500 9.9 13,000 130,000 6.7 21.7 143 6.32 8.1 5.64 SS-80 4/1/2020 510 50 0.5 680 5.8 10,000 76,000 7.2 11.7 87 13.3 83.4 10.86 SS-80 9/23/2020 470 65 0.5 840 17 10,000 120,000 8.0 15.1 123 9.46 19.1 9.02 SS-90 1/4/2011 -- 44 0.1 1,200 10 16 26,000 97,000 8.4 3.0 390 4.2 152 10.55 SS -go 1/4/2011 -- 44 0.1 1,200 '^ 16 26,000 97,000 8.4 3.0 390 4.2 152 10.55 SS-90 4/20/2011 83 57 0.1 330 21 2.1 330 56,000 130,000 2,600 6.7 16.9 292 4.6 293 11.68 SS-90 9/25/2012 121 115 -1 212 30.4 980 202,000 511,000 -- 8.1 11.9 840 12.1 207 8.96 SS-90 4/17/2013 491 56 709 17.4 34.9 38,900 127,000 3,690 7.9 19.7 203 6.9 66 7.59 SS-90 9/10/2013 148 86.6 265 32.4 642 121,000 283,000 4,920 7.9 22.2 429 7.9 91.6 7.26 SS-90 4/6/2014 154 48.5 274 9.4 -- 45,300 151,000 3,300 8.9 15.1 255 5.62 120.9 15.44 SS-90 9/3/2014 90.8 77.5 16 94,500 357,000 -- 7.5 23.5 518 5.56 65.3 6.43 SS-90 4/1/2015 125 58 189 9 51,400 166,000 8.8 11.4 318 5.95 5.95 9.92 SS-90 9/8/2015 290 J 100 - 5 1 J 530 80 110,000 340,000 -- -- -- -- -- -- SS-90 3/8/2016 390 58 0.1 470 11 33,000 110,000 8.4 8.5 210 -- 239.3 13.08 SS-90 9/7/2016 40 73 0.1 230 17 49,000 200,000 8.0 20.8 2886 1.8 48 9 SS-90 3/27/2017 160 62 0.5 340 12 40,000 100,000 B 8.2 16.5 256 1.9 152 11.09 SS-90 9/25/2017 72 B 79 0.5 160 10 48,000 200,000 7.9 19.1 284 1.47 153.2 8.7 SS-90 3/5/2018 51 54 0.5 120 5.8 48,000 170,000 7.8 9.6 262 2.2 192 10.09 SS-90 9/11/2018 54 72 0.5 280 15 46,000 210,000 8.7 21.2 387 4.95 114 6.8 SS-90 3/18/2019 140 45 0.5 340 7.4 20,000 110,000 7.5 9.8 151 8.02 170.9 12.29 SS-90 9/3/2019 71 69 0.5 230 8.2 31,000 160,000 6.6 22.2 229 12.9 12.9 6.44 SS-90 2/17/2020 1,900 49 0.5 1,900 11 17,000 120,000 7.5 8.4 129 12.8 234 11.43 SS-90 2/24/2020 780 52 0.5 850 8.6 22,000 130,000 8.1 7.4 162 5.3 198 16.19 SS-90 4/1/2020 200 47 0.5 300 8.3 22,000 110,000 8.7 11.3 155 10.7 59.2 12.61 SS-90 9/23/2020 200 64 0.5 400 17 24,000 140,000 8.5 14.8 209 10.7 40.8 9.74 SS-95 2/17/2020 360 62 0.5 660 330 94,000 270,000 7.3 9.5 378 8.2 165 8.55 SS-95 2/24/2020 140 66 0.5 650 540 5.1 -- -- 160,000 390,000 8.1 7.5 599 18.5 200 10.12 MW-001 9/30/1994 2,580 16 2 44 23,200 6,490 35 2,950 787,000 2,230,000 258,000 7.4 22.5 3140 -- -- MW-001 3/31/1995 660 5,150 2,360 155 8,880 794,000 2,540,000 459,000 7.8 17.5 3680 MW-001 9/29/1995 156 5,240 8 4,880 1,030 801,000 2,660,000 4,950 5.4 14.8 4220 MW-001 3/30/1996 112 2 20 5,020 5,400 2,080 -- 2,340,000 6,650 7.2 15.0 3050 MW-001 9/27/1996 167 20 -- 9 4,530 66 1,700 1,010,000 2,700,000 4,040 7.3 23.0 1510 MW-001 3/17/1997 164 20 3,660 5,400 55 608 1,160,000 3,000,000 6,430 7.2 22.0 3660 MW-001 3/29/1997 97 20 6,180 5,460 10 1,290 1,050,000 2,460,000 4,310 7.5 22.0 1770 MW-001 3/27/1998 10 20 11,400 5,900 21 290 942,000 2,780,000 4,430 7.2 23.4 1419 MW-001 9/30/1998 274 20 -- 4,940 -- 666,000 2,700,000 15,400 7.6 20.0 1200 MW-001 3/31/1999 20 7,550 6 4,450 600 1,560,000 2,930,000 7,920 7.3 18.0 1021 WMW-001 9/29/1999 877 20 6,770 862 80 3,360 330,000 715,000 13,300 7.1 18.0 2930 Page 7 of 9 APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Analyte j E .E Q u m Q .� m E ' E 'a m L) j o L U o 0 C o -j G> y N a a £ (n in N Z z cn ° O N 6 O N H p Q C) C O O � CL 3 L •N L) io m m C of � ° j O 0« uoi ' H ? R m 0 c 0 7 d' O C> O £ c OI O N > c N o £ NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE Sample Location Date MW-001 3/16/2000 410 72,000 4,540 1,090 948,000 2,610,000 10,600 -- -- -- -- MW-001 9/15/2000 2,020 3,480 6,270 894,000 2,470,000 5,210 6.6 19.0 980 MW-001 3/23/2001 144 4 20 35,900 12 4,070 480 926,000 2,630,000 5,850 6.5 17.0 480 MW-001 (FD) 3/23/2001 20 6,900 7 4,190 350 939,000 2,640,000 7,520 6.5 17.0 480 MW-001 10/4/2001 204 915 7 229 186,000 7,800 6.3 20.0 300 MW-001 3/28/2002 5,100 3,660 280 1,000,000 3,010,000 3,770 6.4 12.0 1080 MW-001 10/3/2002 2 27 1,520 3,340 1,820 1,030,000 2,940,000 4,940 6.7 18.0 370 MW-001 (FD) 10/3/2002 2 24 1,580 3,330 1,780 1,040,000 2,860,000 5,120 5.7 18.0 370 MW-001 3/25/2003 6,690 6 3,560 25 406 846,000 2,530,000 3,720 6.6 17.0 330 MW-001 10/2/2003 11,300 7 3,880 42 174 916,000 2,710,000 3,920 5.6 15.0 3050 MW-001(FD) 10/2/2003 11,400 6 3,880 958,000 2,690,000 3,900 5.6 15.0 3170 MW-001 4/28/2004 11,100 6 6,080 1,460,000 2,550,000 5,360 -- 17.3 2860 MW-001 10/26/2004 20 5,250 4,550 287 1,190,000 2,950,000 3,640 3480 MW-001 4/27/2005 __ 2 < 20 7,630 7 5,730 __ 1,100,000 2,550,000 4,710 2870 MW-001 10/20/2005 1,630 4 28 103,000 6 4,880 57 428 403,000 3,010,000 89,000 529 MW-001 10/19/2006 172 2 347 27,400 3,600 27 139 1,320,000 2,850,000 4,370 2000 MW-001 4/27/2007 5,360 2,380 287 1,380,000 2,750,000 4,010 4830 MW-001 11/19/2007 42 2 < 20 48,200 3,280 25 -50 1,560,000 3,060,000 3,820 3300 MW-001 4/30/2008 < 20 < 20 9,680 2,990 22 155 1,100,000 2,910,000 3,380 4880 MW-001 10/29/2008 68.7 < 10 < 10 4,840 3.5 2,880 188,000 3,060,000 3,510 4200 MW-001 4/30/2009 77.4 1.8 < 10 3.6 4,080 4.4 3,100 264 37,700 2,904,000 3,940 4070 MW-003 9/30/1994 1,770 113 3,370 2,200 96 200 159,000 415,000 20,100 6.9 19.6 519 MW-003 3/31/1995 -- 4,860 5,980 32 100 294,000 625,000 -- 7.6 13.6 896 MW-003 9/29/1995 1,640 20 3,420 7 2,940 104 463 314,000 740,000 3,740 4.9 14.0 1040 MW-003 3/30/1996 11,400 2 20 23,300 9 3,160 126 130 222,000 552,000 3,830 7.2 12.0 750 MW-003 9/27/1996 110 20 1,010 7 2,360 30 160 283,000 737,000 6,730 7.6 20.0 974 MW-003 3/29/1997 238 20 1,930 3,050 13 20 180 809,000 807,000 4,170 7.8 16.0 590 MW-003 9/17/1997 169 20 715 5 3,060 6 212 330 562,000 1,290,000 5,290 7.7 19.0 1650 MW-003 3/27/1998 270 2,500 3,370 13 41 250 -- 929,000 6,980 7.2 20.0 1214 MW-003 9/30/1998 353 1,380 -- 17 780 367,000 1,280,000 10,100 6.9 19.0 920 MW-003 3/31/1999 4,830 5,550 190 482,000 842,000 7,580 7.1 16.0 592 MW-003 9/29/1999 677 1,940 894 100 258,000 413,000 8,140 7.7 19.0 741 MW-003 9/15/2000 224 2,380 2,800 160 550,000 1,260,000 8,580 7.1 21.0 680 MW-003 3/23/2001 3,690 10 2,250 30 230 530,000 1,230,000 5,720 6.6 17.0 640 MW-003 10/4/2001 4,240 6 3,650 80 592,000 1,440,000 30,000 7.0 20.0 600 MW-003 3/28/2002 5,620 2,180 110 682,000 1,590,000 5,360 6.4 13.0 680 MW-003 10/3/2002 2 6,510 5,290 932,000 1,900,000 8,510 6.2 19.0 150 MW-003 3/25/2003 3,280 6,170 8 4,290 78 88 784,000 1,520,000 1,340 6.4 18.0 110 MW-003 10/2/2003 634 5,950 8 6,750 50 174 765,000 1,420,000 3,970 6.1 14.0 1460 MW-003 4/28/2004 152 20 8,370 6,720 10 < 2C 224 1,040,000 1,810,000 3,890 -- 12.1 2030 MW-003 10/26/2004 554 5 20 16,300 4,220 36 289 1,070,000 2,140,000 5,160 2150 MW-003 4/27/2005 2 4,470 6,110 < 2C 246 1,075,000 2,090,000 4,050 2320 MW-003 10/20/2005 5 27 7,900 5,870 44 279 1,300,000 2,090,000 30,000 1060 MW-003 10/19/2006 1,460 6,040 4,550 21 281 1,170,000 1,920,000 4,200 1370 MW-003 4/27/2007 < 20 8,330 4,190 290 1,130,000 2,130,000 3,830 2230 MW-003 11/19/2007 < 20 < 20 8,200 6,000 64 1,680,000 2,550,000 4,590 2710 MW-003 4/30/2008 < 20 < 20 3,360 3,800 37 297 2,090,000 2,110,000 3,560 2290 MW-003 10/29/2008 59.3 < 10 2,880 2.3 4,360 < 1C 171 988,000 2,360,000 3,480 2740 MW-003 4/30/2009 53.2 < 1r, 4,620 7.2 4,960 10 14.6 337 261,000 1 2,460,0001 4,110 2930 Page 8 of 9 APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA R m 0 ° p c O N Q 0 c 6 C) 3 j 7 OI G> Z O C L •N O ♦Y O j 2 E 2 j y N £ N O O L) io m `m 0« wE O N >N E E d E E -a O d � d t7 CL o :a m O- o o - > m L) U c -jAnalyte a a U) U N z U H a ° U H O £ oO £ NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE Sample Location I Date Notes: All concentrations in micrograms per liter (ug/L) unless otherwise noted NE - Not established -- - Not sampled B - Detected in the method blank J - Estimated result < LOQ and > DL Bold with gray background indicates exceedance of NC Surface Water Standard NSA— Location inaccessible; no sample collected NSB - Obstruction in well; no sample collected NSC - Well dry; no sample collected NSD - Insufficient volume; no sample collected NSE - Well damaged; no sample collected NSF - Pump broken; no sample collected NSG - Surface water location dry; no sample collected Analysis for arsenic, copper, mercury, silver, zinc, nitrates & TOC discontinued in 2014 per Corrective Action Plan (ERM, 2/2014). Analysis for all metals analyses in PZ samples discontinued in 2020 per NCDWM authorization 7/9/2020. Page 9 of 9 APPENDIX A3 QA/QC ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Analyte M .C E Q C_i G1 i Q .L R m _� E $ M U 2 E t U L O C. O U C O L R J y O C ma i � E C N Cn L > in t� N Z R 01 Z m .. `� cn y O � � > y N .�+ O H � O � R U v C R Oi O �@+ O H NC 2L Groundwater Standardl 3.5 1 0.01 1 0.7 1 0.002 1 0.01 1 1 0.3 0.015 0.05 0.001 0.02 0.02 1 10 1 250 500 NE Date Field Blank 9/30/1998 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 1 3/31/1999 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.19 < 5 < 5 2.18 9/15/2000 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 1 3/23/2001 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 0.006 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 14 < 1 10/4/2001 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 0.006 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.3 < 5 15 < 2 3/28/2002 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 -- < 0.01 < 0.01 < 0.02 < 0.05 < 5 14 < 1 10/3/2002 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 6 < 1 3/25/2003 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.198 < 5 < 5 < 1 10/2/2003 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 1 4/28/2004 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 6 < 1 10/26/2004 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.151 < 5 10 2.18 4/27/2005 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 12 1.79 10/20/2005 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.101 < 5 < 5 < 0.5 10/19/2006 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 0.5 4/27/2007 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 0.5 11/19/2007 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 0.5 4/30/2008 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.336 < 5 < 5 < 0.5 10/29/2008 < 0.1 < 0.01 0.0031 < 0.001 < 0.01 < 0.01 < 0.05 < 0.01 < 0.01 0.00002 < 0.01 0.0022 0.01 < 0.05 < 10 < 5 < 0.5 4/30/2009 < 0.1 < 0.01 0.0077 < 0.001 < 0.01 < 0.01 < 0.05 0.0045 0.008 < 0.0002 < 0.01 < 0.01 < 0.01 < 0.05 < 10 90 < 0.5 Trip Blank 9/30/1998 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 1 3/31/1999 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.22 < 5 15 < 1 9/15/2000 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 1 3/23/2001 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 14 1.03 10/4/2001 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.4 < 5 12 2 3/28/2002 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 -- < 0.01 < 0.01 < 0.02 < 0.05 < 5 14 1.03 10/3/2002 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 0.5 3/25/2003 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.197 < 5 7 < 1 10/2/2003 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 7 < 1 4/28/2004 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 16 < 1 10/26/2004 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 8 1.29 4/27/2005 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 14 1.76 10/20/2005 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 6 < 0.5 10/19/2006 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 0.5 4/27/2007 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 0.5 11/19/2007 <0.1 <0.01 <0.25 <0.002 <0.02 <0.02 <0.1 <0.005 <0.01 <0.0002 <0.01 <0.01 <0.02 <0.05 <5 <5 <0.5 4/30/2008 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 0.5 10/29/2008 < 0.1 < 0.01 0.0046 < 0.001 < 0.01 < 0.01 < 0.05 < 0.01 < 0.01 0.00001 < 0.01 < 0.01 < 0.01 < 0.05 < 10 < 5 < 0.5 4/30/2009 < 0.1 < 0.01 0.0086 0.0003 < 0.01 < 0.01 < 0.05 < 0.01 0.0071 < 0.0002 < 0.01 < 0.01 < 0.01 < 0.05 < 10 85 < 0.5 9/8/2016 < 0.1 < 0.01 0.0086 0.0003 < 0.01 < 0.01 < 0.05 < 0.01 0.0071 < 0.0002 < 0.01 < 0.01 < 0.01 < 0.05 < 10 85 < 0.5 Notes: All concentrations in milligrams per liter (mg/L) unless otherwise noted Analysis for arsenic, copper, mercury, silver, zinc, nitrates & TOC discontinued in 2014 per Corrective Action Plan (ERM, 2/2014). NE - Not established Analysis for all metals analyses in PZ samples discontinued in 2020 per NCDWM authorization 7/9/2020. -- - Not sampled Bold with gray background indicates exceedance of NC Groundwater Standard Page 1 of 1 APPENDIX B LABORATORY DATA SHEETS www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. December 2020 2020-09 Edwards Rd LF Rural Hall GW Report.docx (��a'neAnalyfical Report of Analysis ERM INC, Inc. 300 West Summit Avenue Suite 330 Charlotte, NC 28203 Attention: Alan Martin Project Name: RJRT Ash Landfill Project Number: 055157 Lot Number:V125068 Date Completed:10/06/2020 10/06/2020 3:55 PM Approved and released by: Project Manager I: Hannah K. Lucas .rc o a�Erxauw,w�w The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel: 803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 74 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative ERM INC, Inc. Lot Number: V125068 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ('Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. Metals The matrix spike/matrix spike duplicate (MS/MSD) associated with sample -021 had aluminum and iron recovered outside of the acceptance limits. The laboratory control sample (LCS) was recovered within the required acceptance limits; therefore, this likely demonstrates a matrix effect. Pace Analytical Services, LLC (rormerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 v—pacelabs.com Page 2 of 74 PACE ANALYTICAL SERVICES, LLC Sample Summary ERM INC, Inc. Lot Number: V125068 Sample Number Sample ID Matrix Date Sampled Date Received 001 PW-01-WG-20200924 Aqueous 09/24/2020 1535 09/26/2020 002 W-01-WG-20200924 Aqueous 09/24/20201025 09/25/2020 003 W-02-WG-20200924 Aqueous 09/24/20201120 09/25/2020 004 W-03-WG-20200924 Aqueous 09/24/2020 1155 09/25/2020 005 W-03B-WG-20200924 Aqueous 09/24120201055 09/25/2020 006 W-06-WG-20200924 Aqueous 09/24/20201300 09/25/2020 007 W-07-WG-20200924 Aqueous 09/24/20201350 09/25/2020 008 W-08-WG-20200924 Aqueous 09/24120201455 09/25/2020 009 W-09-WG-20200923 Aqueous 09/23/20201320 09/25/2020 010 PZ-02-WG-20200923 Aqueous 09/23/20201545 09/25/2020 011 SS-01-WS-20200923 Aqueous 09/23120201500 09/25/2020 012 SS-02-WS-20200923 Aqueous 09/23/20201605 09/25/2020 013 SS-20-WS-20200923 Aqueous 09/23/20201435 09/25/2020 014 SS-25-WS-20200923 Aqueous 09/23/2020 1445 09/25/2020 015 SS-30-WS-20200923 Aqueous 09/23120201450 09/25/2020 016 SS-40-WS-20200923 Aqueous 09/23/2020 1545 09/25/2020 017 SS-50-WS-20200923 Aqueous 09/23/2020 09/25/2020 018 SS-60-WS-20200923 Aqueous 09/23120201505 09/25/2020 019 SS-70-WS-20200923 Aqueous 09/23120201520 09/25/2020 020 SS-80-WS-20200923 Aqueous 09/23120201535 09/25/2020 021 SS-90-WS-20200923 Aqueous 09/23120201435 09/25/2020 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelabs.com Page 3 of 74 PACE ANALYTICAL SERVICES, LLC Detection Summary ERM INC, Inc. Lot Number: V125068 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 PW-01-WG-20200924 Aqueous Sulfate 300.0 330 mg/L 7 001 PW-01-WG-20200924 Aqueous TDS SM 2540C- 730 mg/L 7 001 PW-01-WG-20200924 Aqueous Aluminum 6020B 360 ug/L 8 001 PW-01-WG-20200924 Aqueous Barium 6020B 56 ug/L 8 001 PW-01-WG-20200924 Aqueous Chromium 6020B 9.6 ug/L 8 001 PW-01-WG-20200924 Aqueous Iron 6020B 1000 ug/L 8 001 PW-01-WG-20200924 Aqueous Manganese 6020B 190 ug/L 8 001 PW-01-WG-20200924 Aqueous Selenium 6020B 19 ug/L 8 002 W-01-WG-20200924 Aqueous Sulfate 300.0 1000 mg/L 9 002 W-01-WG-20200924 Aqueous TDS SM 2540C- 2400 mg/L 9 002 W-01-WG-20200924 Aqueous Aluminum 6020B 73 ug/L 10 002 W-01-WG-20200924 Aqueous Barium 6020E 24 ug/L 10 002 W-01-WG-20200924 Aqueous Iron 6020B 950 ug/L 10 002 W-01-WG-20200924 Aqueous Manganese 6020B 3700 ug/L 10 002 W-01-WG-20200924 Aqueous Selenium 6020E 26 ug/L 10 003 W-02-WG-20200924 Aqueous Sulfate 300.0 19 mg/L 11 003 W-02-WG-20200924 Aqueous TDS SM 2540C- 130 mg/L 11 003 W-02-WG-20200924 Aqueous Aluminum 6020E 2600 ug/L 12 003 W-02-WG-20200924 Aqueous Barium 6020E 190 ug/L 12 003 W-02-WG-20200924 Aqueous Iron 6020E 4300 ug/L 12 003 W-02-WG-20200924 Aqueous Manganese 6020E 370 ug/L 12 004 W-03-WG-20200924 Aqueous Sulfate 300.0 150 mg/L 13 004 W-03-WG-20200924 Aqueous TDS SM 2540C- 460 mg/L 13 004 W-03-WG-20200924 Aqueous Barium 6020B 29 ug/L 14 004 W-03-WG-20200924 Aqueous Iron 6020E 100 ug/L 14 004 W-03-WG-20200924 Aqueous Manganese 6020E 120 ug/L 14 004 W-03-WG-20200924 Aqueous Selenium 6020B 10 ug/L 14 005 W-03B-WG-20200924 Aqueous Sulfate 300.0 19 mg/L 15 005 W-03B-WG-20200924 Aqueous TDS SM 2540C- 260 mg/L 15 005 W-03B-WG-20200924 Aqueous Barium 6020E 54 ug/L 16 005 W-03B-WG-20200924 Aqueous Iron 6020B 350 ug/L 16 005 W-03B-WG-20200924 Aqueous Manganese 6020E 120 ug/L 16 006 W-06-WG-20200924 Aqueous Sulfate 300.0 9.0 mg/L 17 006 W-06-WG-20200924 Aqueous TDS SM 2540C- 290 mg/L 17 006 W-06-WG-20200924 Aqueous Aluminum 6020B 120 ug/L 18 006 W-06-WG-20200924 Aqueous Barium 6020B 40 ug/L 18 006 W-06-WG-20200924 Aqueous Chromium 6020B 7.8 ug/L 18 006 W-06-WG-20200924 Aqueous Iron 6020B 230 ug/L 18 007 W-07-WG-20200924 Aqueous Sulfate 300.0 11 mg/L 19 007 W-07-WG-20200924 Aqueous TDS SM 2540C- 180 mg/L 19 007 W-07-WG-20200924 Aqueous Aluminum 6020B 99 ug/L 20 007 W-07-WG-20200924 Aqueous Barium 6020B 130 ug/L 20 007 W-07-WG-20200924 Aqueous Chromium 6020B 5.9 ug/L 20 007 W-07-WG-20200924 Aqueous Iron 6020E 1500 ug/L 20 007 W-07-WG-20200924 Aqueous Manganese 6020B 37 ug/L 20 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pamlabs.com Page 4 of 74 Detection Summary (Continued) Lot Number: V125068 Sample Sample ID Matrix Parameter Method Result Q Units Page 008 W-08-WG-20200924 Aqueous Sulfate 300.0 37 mg/L 21 008 W-08-WG-20200924 Aqueous TDS SM 2540C- 140 mg/L 21 008 W-08-WG-20200924 Aqueous Aluminum 6020B 940 ug/L 22 008 W-08-WG-20200924 Aqueous Barium 6020B 180 ug/L 22 008 W-08-WG-20200924 Aqueous Chromium 6020B 13 ug/L 22 008 W-08-WG-20200924 Aqueous Iron 6020B 1100 ug/L 22 008 W-08-WG-20200924 Aqueous Manganese 6020B 18 ug/L 22 009 W-09-WG-20200923 Aqueous Sulfate 300.0 11 mg/L 23 009 W-09-WG-20200923 Aqueous TDS SM 2540C- 190 mg/L 23 009 W-09-WG-20200923 Aqueous Barium 6020B 140 ug/L 24 010 PZ-02-WG-20200923 Aqueous Sulfate 300.0 24 mg/L 25 010 PZ-02-WG-20200923 Aqueous TDS SM 2540C- 180 mg/L 25 011 SS-01-WS-20200923 Aqueous Sulfate 300.0 31 mg/L 26 011 SS-01-WS-20200923 Aqueous TDS SM 2540C- 200 mg/L 26 011 SS-01-WS-20200923 Aqueous Aluminum 6020E 1000 ug/L 27 011 SS-01-WS-20200923 Aqueous Barium 6020E 82 ug/L 27 011 SS-01-WS-20200923 Aqueous Iron 6020B 1400 ug/L 27 011 SS-01-WS-20200923 Aqueous Manganese 6020E 25 ug/L 27 012 SS-02-WS-20200923 Aqueous Sulfate 300.0 49 mg/L 28 012 SS-02-WS-20200923 Aqueous TDS SM 2540C- 230 mg/L 28 012 SS-02-WS-20200923 Aqueous Aluminum 6020E 1200 ug/L 29 012 SS-02-WS-20200923 Aqueous Barium 6020E 74 ug/L 29 012 SS-02-WS-20200923 Aqueous Iron 6020B 1400 ug/L 29 012 SS-02-WS-20200923 Aqueous Manganese 6020E 39 ug/L 29 013 SS-20-WS-20200923 Aqueous Sulfate 300.0 8.0 mg/L 30 013 SS-20-WS-20200923 Aqueous TDS SM 2540C- 120 mg/L 30 013 SS-20-WS-20200923 Aqueous Aluminum 6020E 4800 ug/L 31 013 SS-20-WS-20200923 Aqueous Barium 6020E 59 ug/L 31 013 SS-20-WS-20200923 Aqueous Iron 6020E 6000 ug/L 31 013 SS-20-WS-20200923 Aqueous Lead 6020E 2.0 ug/L 31 013 SS-20-WS-20200923 Aqueous Manganese 6020B 88 ug/L 31 014 SS-25-WS-20200923 Aqueous Sulfate 300.0 8.3 mg/L 32 014 SS-25-WS-20200923 Aqueous TDS SM 2540C- 110 mg/L 32 014 SS-25-WS-20200923 Aqueous Aluminum 6020E 4400 ug/L 33 014 SS-25-WS-20200923 Aqueous Barium 6020E 58 ug/L 33 014 SS-25-WS-20200923 Aqueous Iron 6020E 4900 ug/L 33 014 SS-25-WS-20200923 Aqueous Lead 6020B 1.8 ug/L 33 014 SS-25-WS-20200923 Aqueous Manganese 6020B 60 ug/L 33 015 SS-30-WS-20200923 Aqueous Sulfate 300.0 37 mg/L 34 015 SS-30-WS-20200923 Aqueous TDS SM 2540C- 220 mg/L 34 015 SS-30-WS-20200923 Aqueous Aluminum 6020E 3800 ug/L 35 015 SS-30-WS-20200923 Aqueous Barium 6020B 81 ug/L 35 015 SS-30-WS-20200923 Aqueous Iron 6020B 4300 ug/L 35 015 SS-30-WS-20200923 Aqueous Lead 6020B 1.4 ug/L 35 015 SS-30-WS-20200923 Aqueous Manganese 6020B 56 ug/L 35 016 SS-40-WS-20200923 Aqueous Sulfate 300.0 42 mg/L 36 016 SS-40-WS-20200923 Aqueous TDS SM 2540C- 230 mg/L 36 016 SS-40-WS-20200923 Aqueous Aluminum 6020B 550 ug/L 37 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.com Page 5 of 74 Detection Summary (Continued) Lot Number: V125068 Sample Sample ID Matrix Parameter Method Result Q Units Page 016 SS-40-WS-20200923 Aqueous Barium 6020B 73 ug/L 37 016 SS-40-WS-20200923 Aqueous Iron 6020B 740 ug/L 37 016 SS-40-WS-20200923 Aqueous Manganese 6020B 22 ug/L 37 017 SS-50-WS-20200923 Aqueous Sulfate 300.0 1.2 mg/L 38 017 SS-50-WS-20200923 Aqueous TDS SM 2540C- 71 mg/L 38 017 SS-50-WS-20200923 Aqueous Aluminum 6020B 820 ug/L 39 017 SS-50-WS-20200923 Aqueous Barium 6020B 58 ug/L 39 017 SS-50-WS-20200923 Aqueous Iron 6020B 4400 ug/L 39 017 SS-50-WS-20200923 Aqueous Lead 6020E 1.1 ug/L 39 017 SS-50-WS-20200923 Aqueous Manganese 6020E 180 ug/L 39 018 SS-60-WS-20200923 Aqueous Sulfate 300.0 9.3 mg/L 40 018 SS-60-WS-20200923 Aqueous TDS SM 2540C- 110 mg/L 40 018 SS-60-WS-20200923 Aqueous Aluminum 6020B 200 ug/L 41 018 SS-60-WS-20200923 Aqueous Barium 6020E 53 ug/L 41 018 SS-60-WS-20200923 Aqueous Iron 6020E 490 ug/L 41 018 SS-60-WS-20200923 Aqueous Manganese 6020E 25 ug/L 41 019 SS-70-WS-20200923 Aqueous Sulfate 300.0 12 mg/L 42 019 SS-70-WS-20200923 Aqueous TDS SM 2540C- 96 mg/L 42 019 SS-70-WS-20200923 Aqueous Aluminum 6020B 170 ug/L 43 019 SS-70-WS-20200923 Aqueous Barium 6020B 57 ug/L 43 019 SS-70-WS-20200923 Aqueous Iron 6020E 350 ug/L 43 019 SS-70-WS-20200923 Aqueous Manganese 6020E 12 ug/L 43 020 SS-80-WS-20200923 Aqueous Sulfate 300.0 10 mg/L 44 020 SS-80-WS-20200923 Aqueous TDS SM 2540C- 120 mg/L 44 020 SS-80-WS-20200923 Aqueous Aluminum 6020E 470 ug/L 45 020 SS-80-WS-20200923 Aqueous Barium 6020B 65 ug/L 45 020 SS-80-WS-20200923 Aqueous Iron 6020E 840 ug/L 45 020 SS-80-WS-20200923 Aqueous Manganese 6020E 17 ug/L 45 021 SS-90-WS-20200923 Aqueous Sulfate 300.0 24 mg/L 46 021 SS-90-WS-20200923 Aqueous TDS SM 2540C- 140 mg/L 46 021 SS-90-WS-20200923 Aqueous Aluminum 6020B 200 ug/L 47 021 SS-90-WS-20200923 Aqueous Barium 6020E 64 ug/L 47 021 SS-90-WS-20200923 Aqueous Iron 6020E 400 ug/L 47 021 SS-90-WS-20200923 Aqueous Manganese 6020E 17 ug/L 47 (127 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.com Page 6 of 74 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: V125068-001 Description: PW-01-WG-20200924 Matrix: Aqueous Date Sampled:09/24/2020 1535 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate) 300.0 10 09/29/2020 1908 AMR 68398 1 (TDS) SM 254OC-2011 1 09/27/2020 1820 MOM 68070 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 330 10 ni 1 TDS SM 254OC-2011 730 25 mg/L 1 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not tlatected at or above the LOQ N = Recovery is out of criteria P = The RPD In—... two QC column. e—d. 40% H = Out of holding tlme W = Reported on wet weight beats Pace Analytical Services, LLC (formerly Shealy Environmental Servioes, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs—ra ICP-MS Metals Client:ERM NC, Inc. Laboratory ID.VI25068-001 Description: PW-01-WG-20200924 Matrix: Aqueous Date Sampled:09/24/2020 1535 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 09/30/20202003 BNW 09/30/20200908 68055 2 3005A 6020B 1 10/01/20200938 BNW 09/30/20200908 68055 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020B 360 40 ug/L 1 Barium 7440-39-3 6020B 56 5.0 ug/L 1 Cadmium 7440-43-9 6020E ND 0.50 ug/L 1 Chromium 7440.47.3 6020E 9.6 5.0 ug/L 1 Iron 7439.89.6 6020E 1000 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 2 Manganese 7439-96-5 6020E 190 5.0 ug/L 1 Selenium 7782.49.2 6020E 19 5.0 ug/L 1 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibradon range ND = Not tlatected at or above the LOQ N = Recovery i. out of Intern, P = The RPD laftw n twa QC columns exceed. 40% H = Out of holding tlme W = Reported on wet weight beats Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 74 Page 8 of 74 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: V125068-002 Description: W-01-WG-20200924 Matrix: Aqueous Date Sampled:09/24/2020 1025 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate) 300.0 10 09/29/2020 1929 AMR 68398 2 (TDS) SM 254OC-2011 1 09/30/2020 2353 MOM 68445 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 1000 10 mglL 1 TDS SM 254OC-2011 2400 25 mg/L 2 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calif clan ange ND = Not detected at or above the LOQ N = Recovery is out of cntena P = The RPD In—... two QC column. e—d. 40% H = Out of holding tlme W = Reported on wet weight basl. Pace Analytical Services, LLC ff—ady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com ICP-MS Metals Client: ERM NC, Inc. Laboratory ID: V125068-002 Description: W-01-WG-20200924 Matrix: Aqueous Date Sampled:09/24/2020 1025 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 09/30/20202009 BNW 09/30/20200908 68055 2 3005A 6020E 1 10/01/20200944 BNW 09/30/20200908 68055 3 3005A 6020E 10 10/01/20200950 BNW 09130/20200908 68055 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020B 73 40 ug/L 1 Barium 7440-39-3 6020B 24 5.0 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89-6 6020E 950 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 2 Manganese 7439-96-5 6020E 3700 50 uglL 3 Selenium 7782-49-2 6020E 26 5.0 uglL 1 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibalion range ND = Not detected at or above the LOQ N = Recovery i. out of cnlena P = The RPD be—n twa QC calumny exceed. 40% H = Out of holding tlme W = Reported on wet weight bael. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 74 Page 10 of 74 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: V125068-003 Description: W-02-WG-20200924 Matrix: Aqueous Date Sampled:09/24/2020 1120 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate) 300.0 1 09/29/2020 1951 AMR 68398 1 (TDS) SM 254OC-2011 1 09/27/2020 1820 MOM 68070 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 19 1.0 ni 1 TDS SM 254OC-2011 130 25 mg/L 1 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration ange ND = Not tlatected at or above the LOQ N = Recovery is out of cnteria P = The RPD In—... two QC column. e—d. 40% H = Out of holding tlme W = Reported on wet weight baal. Pace Analytical Services, LLC ff—ady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com ICP-MS Metals Client: ERM NC, Inc. Laboratory ID.VI25068-003 Description: W-02-WG-20200924 Matrix: Aqueous Date Sampled:09/24/2020 1120 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 09/30/20202015 BNW 09/30/20200908 68055 2 3005A 6020B 1 10/01/20200956 BNW 09/30/20200908 68055 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020B 2600 40 ug/L 1 Barium 7440-39-3 6020B 190 5.0 ug/L 1 Cadmium 7440-43-9 6020E ND 0.50 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439.89.6 6020E 4300 50 ug/L 1 Lead 7439-92-1 6020B NO 1.0 ug/L 2 Manganese 7439-96-5 6020E 370 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibalion range ND = Not tlatected at or above the LOQ N = Recovery i. out of cnlena P = The RPD be—n twa QC columns exceed. 40% H = Out of holding tlme W = Reported on wet weight bael. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of74 Page 12 of74 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: V125068-004 Description: W-03-WG-20200924 Matrix: Aqueous Date Sampled:09/24/2020 1155 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate)300.0 5 09/29/20202057 AMR 68398 1 (TDS) SM 254OC-2011 1 09/27/2020 1820 MOM 68070 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 150 5.0 ni 1 TDS SM 254OC-2011 460 25 mg/L 1 LOQ= Limit of Quantitation B= Detected in the method blank E=Quantitation of.mpou.d exceeded the.libation mnge ND = Not detected at or above the LOQ N = Recovery is out of cnteria P = The RPD In—... two QC column. ex—d. 40% H = Out of holding tlme W = Reported on wet weight beet. Pace Analytical Services, LLC (ronnedy Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com ICP-MS Metals Client: ERM NC, Inc. Laboratory ID.VI25068-004 Description: W-03-WG-20200924 Matrix: Aqueous Date Sampled:09/24/2020 1155 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 09/30/20202021 BNW 09/30/20200908 68055 2 3005A 6020B 1 10/01/20201002 BNW 09/30/20200908 68055 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020B ND 40 ug/L 1 Barium 7440-39-3 6020B 29 5.0 ug/L 1 Cadmium 7440-43-9 6020E ND 0.50 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439.89.6 6020E 100 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 2 Manganese 7439-96-5 6020E 120 5.0 ug/L 1 Selenium 7782.49.2 6020E 10 5.0 ug/L 1 LOQ= Limit of Quantitation B= Detected in the method blank E=Quantitation of.mpound exceeded the calibadon range ND= Not detected at or above the LOQ N= Recovery i. out of cntena P=The RPDb nw— two QC columns exceed. 40% H = Out of holding tlme W = Reported on wet weight beet. Pace Analytical Services, LLC (rermerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of74 Page 14 of74 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: V125068-005 Description: W-03B-WG-20200924 Matrix: Aqueous Date Sampled:09/24/2020 1055 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate)300.0 1 09/29/20202119 AMR 68398 1 (TDS) SM 254OC-2011 1 09/27/2020 1820 MOM 68070 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 19 1.0 ni 1 TDS SM 254OC-2011 260 25 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration ange ND = Not tlatected at or above the LOQ N = Recovery is out of cnteria P = The RPD In—... two QC column. e—d. 40% H = Out of holding tlme W = Reported on wet weight baal. Pace Analytical Services, LLC ff—ady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com ICP-MS Metals Client: ERM NC, Inc. Laboratory ID.VI25068-005 Description: W-03B-WG-20200924 Matrix: Aqueous Date Sampled:09/24/2020 1055 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 09/30/20202027 BNW 09/30/20200908 68055 2 3005A 6020B 1 10/01/20201008 BNW 09/30/20200908 68055 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020B ND 40 ug/L 1 Barium 7440-39-3 6020B 54 5.0 ug/L 1 Cadmium 7440-43-9 6020E ND 0.50 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439.89.6 6020E 350 50 ug/L 1 Lead 7439-92-1 6020B NO 1.0 ug/L 2 Manganese 7439-96-5 6020E 120 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibalion range ND= Not tlatected at or above the LOQ N= Recovery i. out of crtena P=The RPD ba—n lwc QC columns exceed. 40% H = Out of holding tlme W = Reported on wet weight beet. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of74 Page 16 of74 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: V125068-006 Description: W-06-WG-20200924 Matrix: Aqueous Date Sampled:09/24/2020 1300 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate)300.0 1 09/29/20202142 AMR 68398 1 (TDS) SM 254OC-2011 1 09/27/2020 1820 MOM 68070 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 9.0 1.0 ni 1 TDS SM 254OC-2011 290 25 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration ange ND = Not tletected at or above the LOQ N = Recovery is out of cnteria P = The RPD In—... two QC column. exceed. 40% H = Out of holding tlme W = Reported on wet weight baels Pace Analytical Services, LLC ff—ady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com ICP-MS Metals Client: ERM NC, Inc. Laboratory ID.VI25068-006 Description: W-06-WG-20200924 Matrix: Aqueous Date Sampled:09/24/2020 1300 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 09/30/20202044 BNW 09/30/20200908 68055 2 3005A 6020B 1 10/01/20201025 BNW 09/30/20200908 68055 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020B 120 40 ug/L 1 Barium 7440-39-3 6020B 40 5.0 ug/L 1 Cadmium 7440-43-9 6020E ND 0.50 ug/L 1 Chromium 7440.47.3 6020E 7.8 5.0 ug/L 1 Iron 7439.89.6 6020E 230 50 ug/L 1 Lead 7439-92-1 6020B NO 1.0 ug/L 2 Manganese 7439-96-5 6020B ND 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibadon range ND = Not tletected at or above the LOQ N = Recovery i. out of cntana P = The RPD behveen two QC columns exceed. 40% H = Out of holding tlme W = Reported on wet weight beets Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 17 of74 Page 18 of74 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: V125068-007 Description: W-07-WG-20200924 Matrix: Aqueous Date Sampled:09/24/2020 1350 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate)300.0 1 09/29/20202248 AMR 68398 1 (TDS) SM 254OC-2011 1 09/28/2020 2218 MOM 68159 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 11 1.0 mg/L 1 TDS SM 254OC-2011 180 25 mg/L 1 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of critana P = The RPD In—... two GC column. e—d. 40% H = Out of holding tlme W = Repotted on wet weight beats Pace Analytical Services, LLC ff—ady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com ICP-MS Metals Client: ERM NC, Inc. Laboratory ID: V125068-007 Description: W-07-WG-20200924 Matrix: Aqueous Date Sampled:09/24/2020 1350 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 09/30/20202050 BNW 09/30/20200908 68055 2 3005A 6020B 1 10/01/20201031 BNW 09/30/20200908 68055 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020B 99 40 ug/L 1 Barium 7440-39-3 6020B 130 5.0 ug/L 1 Cadmium 7440-43-9 6020E ND 0.50 ug/L 1 Chromium 7440.47.3 6020E 5.9 5.0 ug/L 1 Iron 7439.89.6 6020E 1500 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 2 Manganese 7439-96-5 6020E 37 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery i. out of Inter, P = The RPD be—n twa GC columns exceed. 40% H = Out of holding tlme W = Reported on wet weight beats Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 19 of74 Page 20 of74 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: V125068-008 Description: W-08-WG-20200924 Matrix: Aqueous Date Sampled:09/24/2020 1455 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate)300.0 1 09/29/20202310 AMR 68398 1 (TDS) SM 254OC-2011 1 09/28/2020 2218 MOM 68159 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 37 1.0 ni 1 TDS SM 254OC-2011 140 25 ni 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration ange ND = Not detected at or above the LOQ N = Recovery is out of enteric P = The RPD In—... two QC column. e—d. 40% H = Out of holding tlme W = Reported on wet weight beats Pace Analytical Services, LLC ff—ady Shealy Environmental Sewroes, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com ICP-MS Metals Client: ERM NC, Inc. Laboratory ID.VI25068-008 Description: W-08-WG-20200924 Matrix: Aqueous Date Sampled:09/24/2020 1455 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 09/30/20202056 BNW 09/30/20200908 68055 2 3005A 6020B 1 10/01/20201037 BNW 09/30/20200908 68055 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020B 940 40 ug/L 1 Barium 7440-39-3 6020B 180 5.0 ug/L 1 Cadmium 7440-43-9 6020E ND 0.50 ug/L 1 Chromium 7440.47.3 6020E 13 5.0 ug/L 1 Iron 7439.89.6 6020E 1100 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 2 Manganese 7439-96-5 6020E 18 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery i. out of cntana P = The RPD be—n twa QC columns exceed. 40% H = Out of holding tlme W = Repotted on wet weight beets Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 21 of74 Page 22 of74 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: V125068-009 Description: W-09-WG-20200923 Matrix: Aqueous Date Sampled:09/23/2020 1320 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate)300.0 1 09/29/20202328 AMR 68398 1 (TDS) SM 254OC-2011 1 09/28/2020 2218 MOM 68159 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 11 1.0 ni 1 TDS SM 254OC-2011 190 25 mg/L 1 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration ange ND = Not detected at or above the LOQ N = Recovery is out of cnteria P = The RPD In—... two QC column. e—d. 40% H = Out of holding tlme W = Reported on wet weight baels Pace Analytical Services, LLC ff—ady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com ICP-MS Metals Client ERM NC, Inc. Laboratory ID.VI25068-009 Description: W-09-WG-20200923 Matrix: Aqueous Date Sampled:09/23/2020 1320 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 09/30/20202102 BNW 09/30/20200908 68055 2 3005A 6020B 1 10/01/20201043 BNW 09/30/20200908 68055 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020B ND 40 ug/L 1 Barium 744039-3 6020B 140 5.0 ug/L 1 Cadmium 7440-43-9 6020E ND 0.50 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89-6 6020B ND 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 2 Manganese 7439-96-5 6020B ND 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibalion range ND = Not detected at or above the LOQ N = Recovery i. out of cnlena P = The RPD behveen twa QC columns exceed. 40% H = Out of holding tlme W = Reported on wet weight baels Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 23 of74 Page 24 of74 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID:V125068-010 Description: PZ-02-WG-20200923 Matrix: Aqueous Date Sampled:09/23/2020 1545 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate)300.0 1 09/30/20200025 AMR 68398 1 (TDS) SM 254OC-2011 1 09/28/2020 2218 MOM 68159 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 24 1.0 mg/L 1 TDS SM 254OC-2011 180 25 mg/L 1 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibatan range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD In—... two QC column. e—d. 40% H = Out of holding tlme W = Reported on wet weight beet. Pace Analytical Services, LLC (10—dy Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: V125068-011 Description: SS-01-WS-20200923 Matrix: Aqueous Date Sampled:09/23/2020 1500 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate)300.0 1 09/30/20200044 AMR 68398 1 (TDS) SM 254OC-2011 1 09/28/2020 2218 MOM 68159 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 31 1.0 mg/L 1 TDS SM 254OC-2011 200 25 mg/L 1 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of —pound exceeded the calibah,n no. ND= Not detected at or above the LOQ N= Recovery i. out of criteria P=The RPD banes— twa QC columns exceed. 40% H = Out of holding tlme W = Reported on wet weight beet. Pace Analytical Services, LLC (10rmer1y Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 25 of74 Page 26 of74 ICP-MS Metals Client: ERM NC, Inc. Laboratory I D. V 125068-011 Description: SS-01-WS-20200923 Matrix: Aqueous Date Sampled:09/23/2020 1500 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 09/30/20202107 BNW 09/30/20200908 68055 2 3005A 6020E 1 10/01/20201048 BNW 09/30/20200908 68055 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020E 1000 40 ug/L 1 Barium 7440-39-3 6020E 82 5.0 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439.89.6 6020E 1400 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 2 Manganese 7439-96-5 6020E 25 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of —round exceeded the calibration no. ND = Not detected at or above the LOQ N = Recovery is out of cnlena P = The RPD between two QC column. ex—d. 40% H = Out of holding bme W = Reported on wet weight boat. Pace Analytical Services, LLC (/omnady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs—rin Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: V125068-012 Description: SS-02-WS-20200923 Matrix: Aqueous Date Sampled:09/23/2020 1605 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate)300.0 1 09/30/20200103 AMR 68398 1 (TDS) SM 254OC-2011 1 09/28/2020 2218 MOM 68159 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 49 1.0 mg/L 1 TDS SM 254OC-2011 230 25 mg/L 1 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of —pound exceeded the calibation no. ND = Not tletected at or above the LOQ N = Recovery i. out of criteria P = The RPD between twa QC columns exceed. 40% H = Out of holding time W = Reported on wet weight boat. Pace Analytical Services, LLC (10rmerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 27 of 74 Page 28 of 74 ICP-MS Metals Client: ERM NC, Inc. Laboratory ID: V125068-012 Description: SS-02-WS-20200923 Matrix: Aqueous Date Sampled:09/23/2020 1605 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 09/30/20202113 BNW 09/30/20200908 68055 2 3005A 6020E 1 10/01/20201054 BNW 09/30/20200908 68055 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020E 1200 40 ug/L 1 Barium 7440-39-3 6020E 74 5.0 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439.89.6 6020E 1400 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 2 Manganese 7439-96-5 6020E 39 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of cntaria P = The RPD between two QC column. e—d. 40% H = Out of holding tlme W = Reported on wet weight beats Pace Analytical Services, LLC (/omnady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Inorganic non-metals Client: ERM NC, Inc. Laboratory ID:V125068-013 Description: SS-20-WS-20200923 Matrix: Aqueous Date Sampled:09/23/2020 1435 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate)300.0 1 09/30/20200122 AMR 68398 1 (TDS) SM 254OC-2011 1 09/28/2020 2218 MOM 68159 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 8.0 1.0 mg/L 1 TDS SM 254OC-2011 120 25 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of —pound exceeded the calibration range ND = Not tletected at or above the LOQ N = Recovery i. out of cnlena P = The RPD between Iwo QC columns exceed. 40% H = Out of holding tlme W = Reported on wet weight basis Pace Analytical Services, LLC (10rmer1y Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 29 of 74 Page 30 of 74 ICP-MS Metals Client: ERM NC, Inc. Laboratory ID. V 125068-013 Description: SS-20-WS-20200923 Matrix: Aqueous Date Sampled:09/23/2020 1435 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 09/30/20202119 BNW 09/30/20200908 68055 2 3005A 6020E 1 10/01/20201100 BNW 09/30/20200908 68055 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020E 4800 40 ug/L 1 Barium 7440-39-3 6020E 59 5.0 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 6000 50 ug/L 1 Lead 7439-92-1 6020B 2.0 1.0 ug/L 2 Manganese 7439-96-5 6020B 88 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND= Not tlatected at or above the LOQ N= Recovery is out of enter. P=The RPD b—... two QC column. ex —di, 40% H = Out of holding bme W = Reported on wet weight baal. Pace Analytical Services, LLC (/orrnady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs—rin Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: V125068-014 Description: SS-25-WS-20200923 Matrix: Aqueous Date Sampled:09/23/2020 1445 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate)300.0 1 09/30/20200140 AMR 68398 1 (TDS) SM 254OC-2011 1 09/28/2020 2218 MOM 68159 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 8.3 1.0 mg/L 1 TDS SM 254OC-2011 110 25 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of campound exceeded the calibration range ND = Not tlatected at or above the LOQ N = Recovery i. out of cnlena P = The RPD bei... twa QC columns exceed. 40% H = Out of holding time W = Reported on wet weight bast. Pace Analytical Services, LLC (10rmerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 31 of 74 Page 32 of 74 ICP-MS Metals Client: ERM NC, Inc. Laboratory ID. V 125068-014 Description: SS-25-WS-20200923 Matrix: Aqueous Date Sampled:09/23/2020 1445 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 09/30/20202125 BNW 09/30/20200908 68055 2 3005A 6020E 1 10/01/20201106 BNW 09/30/20200908 68055 CAS Analytical Parameter Number Method Result Q LOO Units Run Aluminum 7429-90-5 6020B 4400 40 ug/L 1 Barium 7440-39-3 6020B 58 5.0 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 4900 50 ug/L 1 Lead 7439-92-1 6020B 1.8 1.0 ug/L 2 Manganese 7439-96-5 6020B 60 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of —round exceeded the oalibation no. ND = Not detected at or above the LOQ N = Recovery is out of enter. P = The RPD behveen two QC column. ex—d. 40% H = Out of holding dme W = Reported on wet weight boat. Pace Analytical Services, LLC (/omnady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs—rin Inorganic non-metals Client: ERM NC, Inc. Laboratory ID:V125068-015 Description: SS-30-WS-20200923 Matrix: Aqueous Date Sampled:09/23/2020 1450 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate)300.0 1 09/30/20200237 AMR 68398 1 (TDS) SM 254OC-2011 1 09/28/2020 2218 MOM 68159 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 37 1.0 mg/L 1 TDS SM 254OC-2011 220 25 mg/L 1 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of —pound exceeded the calibation no. ND = Not detected at or above the LOQ N = Recovery i. out of cnlena P = The RPD be—n twa QC columns exceed. 40% H = Out of holding time W = Reported on wet weight boat. Pace Analytical Services, LLC (10rmerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 33 of 74 Page 34 of 74 ICP-MS Metals Client: ERM NC, Inc. Laboratory I D. V 125068-015 Description: SS-30-WS-20200923 Matrix: Aqueous Date Sampled:09/23/2020 1450 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 09/30/20202131 BNW 09/30/20200908 68055 2 3005A 6020E 1 10/01/20201112 BNW 09/30/20200908 68055 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020E 3800 40 ug/L 1 Barium 7440-39-3 6020E 81 5.0 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 4300 50 ug/L 1 Lead 7439-92-1 6020B 1.4 1.0 ug/L 2 Manganese 7439-96-5 6020B 56 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND= Not tlatected at or above the LOQ N= Recovery is out of enter. P=The RPD b—... two QC column. ex —di, 40% H = Out of holding bme W = Reported on wet weight bast. Pace Analytical Services, LLC (/orrnady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs—rin Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: V125068-016 Description: SS-40-WS-20200923 Matrix: Aqueous Date Sampled:09/23/2020 1545 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate) 300.0 1 10/01/2020 1929 AMR 68620 1 (TDS) SM 254OC-2011 1 09/28/2020 2218 MOM 68159 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 42 1.0 mg/L 1 TDS SM 254OC-2011 230 25 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of campound exceeded the calibration range ND = Not tlatected at or above the LOQ N = Recovery i. out of cnlena P = The RPD be—n twa QC columns exceed. 40% H = Out of holding time W = Reported on wet weight bast. Pace Analytical Services, LLC (10rmerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 35 of74 Page 36 of74 ICP-MS Metals Client: ERM NC, Inc. Laboratory ID: V125068-016 Description: SS-40-WS-20200923 Matrix: Aqueous Date Sampled:09/23/2020 1545 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 09/30/20202137 BNW 09/30/20200908 68055 2 3005A 6020E 1 10/01/20201117 BNW 09/30/20200908 68055 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020E 550 40 ug/L 1 Barium 7440-39-3 6020E 73 5.0 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439.89.6 6020E 740 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 2 Manganese 7439-96-5 6020E 22 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration no. ND = Not detected at or above the LOQ N = Recovery is out of cntaria P = The RPD beh — two GC column. e—d. 40% H = Out of holding tlme W = Reported on wet weight beats Pace Analytical Services, LLC (/orrnady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: V125068-017 Description: SS-50-WS-20200923 Matrix: Aqueous Date Sampled:09/23/2020 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate) 300.0 1 10/01/2020 1949 AMR 68620 1 (TDS) SM 254OC-2011 1 09/28/2020 2218 MOM 68159 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 1.2 1.0 mg/L 1 TDS SM 254OC-2011 71 25 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of —pound exceeded the calif adon no. ND= Not tletected at or above the LOQ N= Recovery i. out of crime P=The RPD babe— Iwo GC columns exceed. 40% H = Out of holding tlme W = Reported on wet weight basis Pace Analytical Services, LLC (10rmer1y Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 37 of74 Page 38 of74 ICP-MS Metals Client: ERM NC, Inc. Laboratory ID. V 125068-017 Description: SS-50-WS-20200923 Matrix: Aqueous Date Sampled:09/23/2020 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 09/30/20202200 BNW 09/30/20200908 68055 2 3005A 6020E 1 10/01/20201141 BNW 09/30/20200908 68055 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020E 820 40 ug/L 1 Barium 7440-39-3 6020E 58 5.0 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 4400 50 ug/L 1 Lead 7439-92-1 6020B 1.1 1.0 ug/L 2 Manganese 7439-96-5 6020B 180 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND= Not tlatected at or above the LOQ N= Recovery is out of enter. P=The RPD hnnw n two QC column. ex —di, 40% H = Out of holding dme W = Reported on wet weight boats Pace Analytical Services, LLC (/orrnady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Inorganic non-metals Client: ERM NC, Inc. Laboratory ID:V125068-018 Description: SS-60-WS-20200923 Matrix: Aqueous Date Sampled:09/23/2020 1505 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate)300.0 1 10/01/20202009 AMR 68620 1 (TDS) SM 254OC-2011 1 09/28/2020 2218 MOM 68159 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 9.3 1.0 mg/L 1 TDS SM 254OC-2011 110 25 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of campound exceeded the calibation range ND = Not tlatected at or above the LOQ N = Recovery i. out of cnlena P = The RPD be—n twa QC columns exceed. 40% H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (10rmerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 39 of 74 Page 40 of 74 ICP-MS Metals Client: ERM NC, Inc. Laboratory I D. V 125068-018 Description: SS-60-WS-20200923 Matrix: Aqueous Date Sampled:09/23/2020 1505 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 09/30/20202206 BNW 09/30/20200908 68055 2 3005A 6020E 1 10/01/20201147 BNW 09/30/20200908 68055 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020E 200 40 ug/L 1 Barium 7440-39-3 6020E 53 5.0 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439.89.6 6020E 490 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 2 Manganese 7439-96-5 6020E 25 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not defeated at or above the ii N = Recovery is out of enter. P = The RPD behveen two QC column. exceed. 40% H = Out of holding bme W = Reported on wet weight basis Pace Analytical Services, LLC (/orrnady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs—rin Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: V125066-019 Description: SS-70-WS-20200923 Matrix: Aqueous Date Sampled:09/23/2020 1520 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate)300.0 1 10/01/20202029 AMR 68620 1 (TDS) SM 254OC-2011 1 09/28/2020 2218 MOM 68159 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 12 1.0 mg/L 1 TDS SM 254OC-2011 96 25 di 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of campound exceeded the calibration range ND= Not tletected at or above the ii N= Recovery i. out of cnlena P= The RPD behveen Iwo QC columns exceed.40% H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (10rmerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 41 of74 Page 42 of74 ICP-MS Metals Client: ERM NC, Inc. Laboratory ID. V 125068-019 Description: SS-70-WS-20200923 Matrix: Aqueous Date Sampled:09/23/2020 1520 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 09/30/20202212 BNW 09/30/20200908 68055 2 3005A 6020E 1 10/01/20201153 BNW 09/30/20200908 68055 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020E 170 40 ug/L 1 Barium 7440-39-3 6020E 57 5.0 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439.89.6 6020E 350 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 2 Manganese 7439-96-5 6020E 12 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of —pound exceeded the calibration no. ND = Not detected at or above the LOQ N = Recovery is out of enter. P = The RPD between two QC column. ex—d. 40% H = Out of holding bme W = Reported on wet weight boat. Pace Analytical Services, LLC (/omnady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs—rin Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: V125068-020 Description: SS-80-WS-20200923 Matrix: Aqueous Date Sampled:09/23/2020 1535 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate)300.0 1 10/01/20202049 AMR 68620 1 (TDS) SM 254OC-2011 1 09/28/2020 2218 MOM 68159 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 10 1.0 mg/L 1 TDS SM 254OC-2011 120 25 di 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of —pound exceeded the calibation no. ND = Not tletected at or above the LOQ N = Recovery i. out of criteria P = The RPD between twa QC columns exceed. 40% H = Out of holding time W = Reported on wet weight boat. Pace Analytical Services, LLC (10rmerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 43 of74 Page 44 of74 ICP-MS Metals Client: ERM NC, Inc. Laboratory ID. V 125068-020 Description: SS-80-WS-20200923 Matrix: Aqueous Date Sampled:09/23/2020 1535 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 09/30/20202218 BNW 09/30/20200908 68055 2 3005A 6020E 1 10/01/20201158 BNW 09/30/20200908 68055 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020E 470 40 ug/L 1 Barium 7440-39-3 6020B 65 5.0 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439.89.6 6020E 840 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 2 Manganese 7439-96-5 6020E 17 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not defeated at or above the ii N = Recovery is out of enter. P = The RPD behveen two GC column. exceed. 40% H = Out of holding bme W = Reported on wet weight basis Pace Analytical Services, LLC (/orrnady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs—rin Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: V125068-021 Description: SS-90-WS-20200923 Matrix: Aqueous Date Sampled:09/23/2020 1435 )ate Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate)300.0 1 10/01/20202109 AMR 68620 1 (TDS) SM 254OC-2011 1 09/28/2020 2218 MOM 68159 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 24 1.0 mg/L 1 TDS SM 254OC-2011 140 25 di 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of campound exceeded the calibration range ND= Not tletected at or above the ii N= Recovery i. out of cnlena P=The RPD tatv..n Iwo DC win mnsexceed. 40% H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (10rmerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 45 of74 Page 46 of74 ICP-MS Metals Client: ERM NC, Inc. Laboratory ID. V 125068-021 Description: SS-90-WS-20200923 Matrix: Aqueous Date Sampled:09/23/2020 1435 Date Received: 09/25/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 09/30/20202223 BNW 09/30/20200908 68055 2 3005A 6020E 1 10/01/20201204 BNW 09/30/20200908 68055 CAS Analytical Parameter Number Method Result Q LOO Units Run Aluminum 7429-90-5 6020E 200 40 ug/L 1 Barium 7440-39-3 6020B 64 5.0 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439.89.6 6020E 400 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 2 Manganese 7439-96-5 6020E 17 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 LOO =Limit of Quantitation B = Detected in the method blank E = Quantranion of compound exceeded the calibatan no. ND = Not detected at cr above the LOQ N = Recovery is out of criteria P = The RPD between two OC column. exceed. 40% H = Out of holding bme W = Reported on wet weight bast. Pace Analytical Services, LLC (f—ady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 47 of 74 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 48 of 74 Inorganic non-metals - MB Sample ID: VQ68070-001 Matrix: Aqueous Batch: 68070 Analytical Method: SM 2540C-2011 Parameter Result Q Dil LOQ TDS ND 1 25 Inorganic non-metals - LCS Sample ID: V068070-002 Matrix: Aqueous Batch: 68070 Analytical Method: SM 2540C-2011 Spike Amount Result % Roe Units Analysis Date Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date mg/L 09/27/2020 1820 TDS 1500 1500 1 101 90-110 09/27/2020 1820 LOQ = Limit of Quantilation ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD ie out of criteria * = RPD ie out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelab—m Page 49 of 74 LOQ = Until of Quantilation ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% = RSD ie out of criteria * = RPD ie out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelabs.com Page 50 of 74 Inorganic non-metals - Duplicate Sample ID: V125068-003DU Matrix: Aqueous Batch: 68070 Analytical Method: SM 2540C-2011 Sample Amount Result %RPD Parameter (mg/L) (mg/L) Q Dil % RPD Limit Analysis Date TDS 130 130 1 1.6 20 09/27/20201820 LOQ = Limit of Quanthnion ND =Not detected st or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD is out of cnteri, * = RPD is out of co eri. Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelabs.com Inorganic non-metals - Duplicate Sample ID: V125068-004DU Matrix: Aqueous Batch: 68070 Analytical Method: SM 2540C-2011 Sample Amount Result %RPD Parameter (mg/L) (mg/L) Q Dil %RPD Limit Analysis Date TDS 460 480 1 3.0 20 09/27/20201820 LOQ = Limit of Quanti nion ND =Not detected st or above the LOQ N = Recovery is o of criteria P = The RPD between two GC columns exceeds 40% = RSD is out of crteria * = RPD is aut of.riter. Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelabs—re Page 51 .1774 Page 52 .1774 Inorganic non-metals - MB Sample ID: VQ68159-001 Matrix: Aqueous Batch: 68159 Analytical Method: SM 2540C-2011 Parameter Result Q Dil LOQ TDS ND 1 25 Inorganic non-metals - LCS Sample ID: V068159-002 Matrix: Aqueous Batch: 68159 Analytical Method: SM 2540C-2011 Spike Amount Result % Roe Units Analysis Date Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date mg/L 09/28/2020 2218 TDS 1500 1500 1 101 90-110 09/28/2020 2218 LOQ = Limit of Quantilation ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD ie out of criteria * = RPD ie out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelab—m Page 53 of 74 LOQ = Until of Quantilation ND = Not detected a[ or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% = RSD ie out of criteria * = RPD ie out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelabs.com Page 54 of 74 Inorganic non-metals - MB Sample ID: VQ68398-001 Matrix: Aqueous Batch: 68398 Analytical Method: 300.0 Parameter Result Q Dil LOQ Sulfate ND 1 1.0 Inorganic non-metals - LCS Sample ID: V068398-002 Matrix: Aqueous Batch: 68398 Analytical Method: 300.0 Spike Amount Result %Rec Units Analysis Date Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date mg/L 09/29/2020 1643 Sulfate 20 19 1 97 90-110 09/29/2020 1727 LOQ = Until of Quantilation ND = Not detected a or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD ie out of criteria * = RPD ie out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 caw mcelabs.com Page 55 of74 LOQ = Until of Quantitetion ND = Not detected a[ or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% = RSD ie out of criteria * = RPD ie out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111-pacelabs.com Page 56 of 74 Inorganic non-metals - MS Sample ID: V125068-003MS Matrix: Aqueous Batch: 68398 Analytical Method: 300.0 Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil %Rec Limit Analysis Date Sulfate 19 10 30 1 104 90-110 09/29/2020 2013 LOQ = Limit of Quantilation ND = Not detected al or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD ie out of criteria * = RPD ie out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111-pacelabs.com Inorganic non-metals - MSD Sample ID: V125068-003MD Matrix: Aqueous Batch: 68398 Analytical Method: 300.0 Sample Spike Amount Amount Result %Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Sulfate 19 10 30 1 103 0.34 90-110 20 09/29/2020 2036 LOQ = Limit of Quantilation ND = Not detected al or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% = RSD ie out of criteria * = RPD ie out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111-pacelabs.com Page 57 of 74 Page 58 of 74 Inorganic non-metals - MS Sample ID: V125068-009MS Matrix: Aqueous Batch: 68398 Analytical Method: 300.0 Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 11 10 21 1 100 90-110 09/29/2020 2347 LOQ = Limit of Quantilation ND = Not detected st or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD is out of cn eri, * = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111-pacelabs.com Inorganic non-metals - MSD Sample ID: V125068-009MD Matrix: Aqueous Batch: 68398 Analytical Method: 300.0 Sample Spike Amount Amount Result %Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Sulfate 11 10 21 1 103 1.4 90-110 20 09/30/2020 0006 LOQ = Limit of Quantilation ND = Not detected st or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% = RSD is out of cntena * = RPD is out of triter. Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 -pacelabs.com Page 59 of 74 Page 60 of 74 Inorganic non-metals - MB Sample ID: V068445-001 Matrix: Aqueous Batch: 68445 Analytical Method: SM 2540C-2011 Parameter Result Q Dil LOQ TDS ND 1 25 Inorganic non-metals - LCS Sample ID: V068445-002 Matrix: Aqueous Batch: 68445 Analytical Method: SM 2540C-2011 Spike Amount Result % Roe Units Analysis Date Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date mg/L 09/30/2020 2353 TDS 1500 1500 1 100 90-110 09/30/2020 2353 LOQ = Limit of Quantitation ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD ie out of criteria * = RPD ie out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelab—m Page 61 .1774 LOQ = Until of Quantitation ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% = RSD ie out of criteria * = RPD ie out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelabs.com Page 62 of 74 Inorganic non-metals - Duplicate Sample ID: V125068-002DU Matrix: Aqueous Batch: 68445 Analytical Method: SM 2540C-2011 Sample Amount Result % RPD Parameter (mg/L) (mgiL) Q Dil % RPD Limit Analysis Date TDS 2400 2500 1 2.9 20 09/30/2020 2353 LOQ = Limit of Quantitation ND = Not detected st or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 = RSD is out of cnteri, * = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelab—nn Page 63 of 74 Inorganic non-metals - MB Sample ID: V068620-001 Matrix: Aqueous Batch: 68620 Analytical Method: 300.0 Parameter Result Q Dil LOQ Units Analysis Date Sulfate ND 1 1.0 mg/L 10/01/2020 1830 LOQ = Limit of Quantitation ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% = RSD is out of nten, * = RPD is out of triter. Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelabs.com Page 64 of 74 Inorganic non-metals - LCS Sample ID: V068620-002 Matrix: Aqueous Batch: 68620 Analytical Method: 300.0 Spike Amount Result % Roe Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 20 18 1 90 90-110 10/01/20201910 LOQ = Limit of Q... titation ND = Not detected st or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD is oul of cnteri, * = RPD is out of cotter. Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 caw mcelabs.com Page 65 .1774 ICP-MS Metals - MB Sample ID: V068055-001 Batch: 68055 Analytical Method: 6020B Matrix: Aqueous Prep Method: 3005A Prep Date: 09/30/2020 0908 Parameter Result Q Dil LOQ Units Analysis Date Aluminum ND 1 40 ug/L 09/30/20201952 Barium ND 1 5.0 ug/L 09/30/20201952 Cadmium ND 1 0.50 ug/L 09/30/20201952 Chromium ND 1 5.0 ug/L 09/30/20201952 Iron ND 1 50 ug/L 09/30/20201952 Lead ND 1 1.0 ug/L 10/01/2020 0927 Manganese ND 1 5.0 ug/L 09/30/20201952 Selenium ND 1 5.0 ug/L 09/30/20201952 LOQ = Limit of Quantitation ND = Not detected st or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% = RSD is out of cmena * = RPD is out of triter. Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelabs.com Page 66 .1774 ICP-MS Metals - LCS Sample ID: V068055-002 Batch: 68055 Analytical Method: 6020B Spike Amount Result Parameter (ug/L) (ug/L) Aluminum 100 100 Barium 100 99 Cadmium 100 97 Chromium 100 100 Iron 1000 1000 Lead 100 97 Manganese 100 100 Selenium 100 100 ICP-MS Metals - MS Matrix: Aqueous Prep Method: 3005A Prep Date: 09/30/2020 0908 Sample ID: V125068-021MS Batch: 68055 Analytical Method: 6020B Matrix: Aqueous Prep Method: 3005A Prep Date: 09/30/2020 0908 Sample Spike %Roe Amount Amount Result %Rec Q Dil %Rec Limit Analysis Date Parameter (ug/L) (ug/L) (ug/L) Q Dil %Rec Limit Analysis Date 1 101 80-120 09/30/2020 1957 Aluminum 200 100 930 N 1 735 70-130 09/30/2020 2229 1 99 80-120 09/30/2020 1957 Barium 64 100 170 1 104 70-130 09/30/2020 2229 1 97 80-120 09/30/2020 1957 Cadmium ND 100 99 1 99 70-130 09/30/2020 2229 1 100 80-120 09/30/2020 1957 Chromium ND 100 98 1 98 70-130 09/30/2020 2229 1 104 80-120 09/30/2020 1957 Iron 400 1000 1800 N 1 136 70-130 09/30/2020 2229 1 97 80-120 10/01/2020 0933 Lead ND 100 100 1 101 70-130 10/01/2020 1210 1 101 80-120 09/30/2020 1957 Manganese 17 100 120 1 102 70-130 09/30/2020 2229 1 104 80-120 09/30/2020 1957 Selenium ND 100 100 1 104 70-130 09/30/2020 2229 LOQ = Limit of Quantilation ND = Not detected al or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria * = RPD ie out of criteria Note: Calculations are performed before rounding to avoid round -off errors 1n calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.com Page 67 of 74 LOQ = Limit of Quantilation ND = Not detected al or above the LOQ N = Recovery ie out of criteria P = The RPD between two GC columns exceeds 40% = RSD is out of criteria * = RPD ie out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelabs.com Page 68 of 74 ICP-MS Metals - MSD Sample ID: V125068-021MD Matrix: Aqueous Batch: 68055 Prep Method: 3005A Analytical Method: 6020E Prep Dale: 09/30/2020 0908 Sample Spike Amount Amount Result %Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Aluminum 200 100 1000 N 1 815 8.2 70-130 20 09/30/2020 2235 Barium 64 100 160 1 100 2.5 70-130 20 09/30/2020 2235 Cadmium ND 100 98 1 98 0.36 70-130 20 09/30/2020 2235 Chromium ND 100 100 1 100 1.0 70-130 20 09/30/2020 2235 Iron 400 1000 1800 N 1 142 3.3 70-130 20 09/30/2020 2235 Lead ND 100 100 1 100 0.99 70-130 20 10/01/20201216 Manganese 17 100 120 1 103 0.67 70-130 20 09/30/2020 2235 Selenium ND 100 100 1 102 1.6 70-130 20 09/30/2020 2235 LOQ = Limit & Quantitation ND =Not tletected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD is out & criteria * = RPD ie out &.-H. Note: Calculations are performed before rounding to avoid round -off errors 1n calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.com Page 69 of 74 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 v— pacelabs.com Page 70 of 74 PACE ANALYTICAL SERVICES, LLC 9 -. o ❑ r a N J R s �' � a a a U E s; 5 J� 6krS a L] 'x5 U flzg $ a N ' �s is Qn Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.com Page 71 of 74 0 r� 4 t ra � x m url - µ U, 1 R S Q PACE ANALYTICAL SERVICES, LLC co r~ M 0 Z LO LU E! 2 oc}to1 f y n 2 u s a m t u s y y. N N• rA N M .1 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vnvw.pacelabs.co Page 72 of 74 PACE ANALYTICAL SERVICES, LLC 1�0 M� m ~ XO > E y 7 z k 3 d -- J � Y � SS u.E a Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 73 o1774 PACE ANALYTICAL SERVICES, LLC .Sl—l} F.nrimnnm:nl Fervicn rye. Nee 1 of t Txc,vnm[ NumFc: 1-00: RC-, 4 eflCCGVC :N1C: pie• — Sample Receipt Checklist [SRC) rlu— E2M C..,1—Tom.,..,•"�•A — ; 0 ?/ OD20 h. Vr2606R Means of reoeipn ® sm ❑ Cltern ❑ UPS ❑ FedEx ❑ other. ❑ Yes ®Nu 1. Wore cnsrody seals pr�eslt ou the coolaz'? Yes Nn 1iA 2. Ifeustod • seal¢ wire resent, were they Weiel- and unhn,lnn? pH Strip TT); 20-1820 Cbl-ine Snip Tit: NA Iosted Lw: BTB C7rigin4l teniperuture upmi reLcipi. i Derived (Corrected) temperature upon rcecipt %Sohd S1tap•Cup lD: NA 2.4 r2,4 °C NA iNA eC NA iN.4 •'C N❑ /NA lff Method ®'Temperature Blank ❑Against Bolxles 1R Gnn ID- 5 IR Gun Cnrrecl.inn ruelnr. 0 'C Method of poolant! ® Wei Ice ❑ fee P"k3 ❑ ❑ TQC ❑ Nunc Li yes ❑ No ®NA 3. if temperature of any cooler exceeded F.0°C, was Pnjcd AfunugcrNulificd? pyd was Notified by- phone ! email ! tace-trr-f— [circle one)_ ❑ Ye=- ❑ No V NA 4. Ts the com me,R.ial mooicr'r packing slip atrach�d to this fwm7 ® Yes ❑ No 5. Were pruper cus6udy procedures (m[inqu3shcd4ece ivied) followed? Vj Yes ❑ No 6. W— sample IL)s liAcd —the CDC-7 ® Yes ❑ No 7. We. slmtplc LL)s liskr] un all sample containcrs'7 ® Yea ❑ No S. Wax tulle lion dutc & t nc listed on the C0C7 ® Yea ❑ Nu 9, Was collection date K. time listed on all sample cunlaiin-9 ® Yes ❑ N.1 I 30. Did aII container label iu£ormatien (1D, date, bone -)agree with the COC? Oyes ❑ No 1 L Were icsts to be pcanormcd listed on the CUC7 ® Yes Q tin 12. Did all 1-1,1 ar urrive in the proper ccmkdrmrs £er tech test and+or in goad condition (tulbmken, aids on, cLL.)? 7-V7 El Nu 13, Was adequate sample volume availahl e? VJ Yea ❑ Nu 14. Were all samples receiwil within 54 the holding thnc or 48 hours, whichever cumes Grit? Il—yes ND 15, Were any sam pies containers tnissit c uccss (cirolc one) samples Not Iisted nn COC? ❑ Yes ❑ No ® NA 16 For VUA and RSK-175 samples, were bubbles present �`pca-siu' [%"ur dram in diameter) ;n any ul dlu 4 VA ials• ® Yes 0 No LJ NA 17. Were al] DROimela]Yiku ent samples WCCJV E at a pH of � 27 ❑ Yee ❑ No ®TEA 1 A. Were all cyanide samples rcccived at a pH> 12 and suicide samples receircj al u PH> 97 El Yes ❑ Nu ®IiA 19. Welt all applicable NHIiTKNicyanidc'phwo625 <0.5mgi L) simples lreeorresid'W ehlurme? ❑ Yes ❑ Nn ® NA 4' Were client srnarksirequests (Le. requested dil utiow, NMIMSD designations, ctc... ) ccnc,;c y transcribed from the C(]C into the comment section lt1 LIMS? Yea Nn J21. Was the guete nu ml—listed en The wntainer label? If yes, Quote 9 NA ample Pmuvatiun (Must be completed for any sample(6) incthe preserved or with headspace.l Satnple(s) NA were lecelwd incorrectly prnxrvcd and were adjusted accordingly in sample r ivmg with NA mL of circle one: 112SO4, HNUI, HCI, NaUH using SR if NA Time of preservatiM NA If more than one preserntt ive iy nuxlc,d, please note in the commence l e]nw. Sample(s) NA were )eceived w ide hobbles '�6 = in diameter. Samples(') NA wr7e received with TRC 10.5 mVL (If t119 is no ) and weir adjusted ucwnli ngly in smple receiving with sodium tlliosul fare (Na,Sip,) with Shealy ID: NA SR baronde labels applied by F 1:3 Date: 09125"202t1 CDmmenx Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 74 of 74 APPENDIX C GROUNDWATER SAMPLING LOGS www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. December 2020 2020-09 Edwards Rd LF Rural Hall GW Report.docx I� WATER WATRIX SAMPLING 1 I ' WATER MATRIX SAMPLING FIELD DATA FORM �� HELD DATA FORM rrIF'i Sire Na ma: RJRT Edwards Row LaadfiN Jab d=0551517 Sample Typ a; C1rde one -(Mon flor Ws ll, OPT, Surface Wale r, Pola hie WSW; other) Sample 10: Dale; QZ' Sampiing Pereonnet: c Andrew H- Weather Condltlans: swmy,—>zip,� nNw Time: 1535 Wall e: 1=1u su.fe® Can lc m, Ssrk up comn�eflon Well Ta Present: No e Well l.acksd, We Lock Pre50nt' No Well 10 info. on Ta No Well Boiled: ray Um Weli Cap: No Weil Ca Condition: Replace, Omer, Well Pad Condltton7 Crackwf. Ruweoa, OO+cr We11 Location: cress, sglil4 CmaolR Woods. Other Addition Commen Total Depth of well {T.Dj: +' screon 1Angth: a, 19. 1si xQ• miner Depth to Water ❑.T.W : of - 7 <i Well 01amotor: 1. a. 5 s krheaaher Field Pernmetem measuredwlth: Casing Type: %� i $ul alnar: Purge AM to: khnm Sampling QeVlee; Pmt1 lq Gfundfos- rSM&, P015, Other TubIng Type: Pd h a Measuringpolnl; alhar: Pump Intake [ft below M.P.1: Color: Odor: Yea. Time: min Volume Purged OTW: feel Temp 6C1 pH istd UMS silC luskwl 0A (RWQ ARP mV Turk NTU Comrnenlg: Smbdinw- Crkene, elA. {see.Ae hcl 4 •- 3% 4 6.1-M •- 9ek N- 10% .mV N- !DWI r' 5 91 5 1 5:97 771 7L-6 4g ti rb.�A144 555 9 01 1311,0 13- 2 P m 6•01 .09 16.5 6 ❑3 �IS� 3••} �lw •� . t 3G 1 I 6 -'-I S s 3- 5- R -tl G, QB1e515amalonpeteel Tme- V2VZm 1,; 36' rgg_ra�caueraen: AnalysisRaaueated: Prese-rotfVe: Hold Timewan Pl Lsv. xW�bxxrnax.r rl.rA.lr>rl w.«drprr -... b,neafv.�w x.r�ee ar•y en m. Waew m-.dr...,�,,,�i...wbrw.w,ar..bb wt r,wlw.r=..w.ee.Y Silo flame: RJRT £awards Road Landfill Jeh fk0551$17 Sample Type: Cirde one <URKn T. Surface Water, Potable WSW; o1her) sample ID: LID - 6 [ -- [..:+ 4!� a Z Date: L --t 'Z d Sampiing Porsonnay: Andrew I R. Weather Condlilons; suety- Panty CkWy rnber Time: 6 S _ Woll T Fi eh 0rwfaca Can non, skk Up Com0olon Well TA Present: Yoa- No Well Locked; Yea, H. Lack Present; Yee, No Wall 10 info. on Ta 1 Y.. No Well Boiled: Yns, Na, NM Well Cap: Ves, No Well CaP Condition: Gcad. Redoes, When Well Pad Condition; Goft Craiw A Replace. Other Wail Location: Cx-acs. A4phaR. CMtRlO. waala. Od—; AddhlonaI Commenls; Tote Depth of Well {T.O,{c t Screen Length! s, as, z5 tyw. " Depth to Water D,T.W : Well Diamofer. a indreo-dner. Piofd Parametorsmeasuredwith: Casing Type: Pvg2 swat ether Purge Ratev i CL) mLj.kn Sampling DWCC: —TWA I ldouean, C-4 Ma, 9e1lnr. PPB, 01W. TuhIngrype. Pc1 rhfwm Men sUring Point! TOC other Pump Iplaka fl bninw M,P.t: -[r3 Cplor Odor: Yea No Time; `min Volume Pu ed OTW. Feet Temp pH sld llnlls SpC uslr OO moll-Imoll-I ORP mV Turb NTU Comments- SteaNrnWa+ Crltlria°(Nwom) [sae note h1"! *♦• 3% .1- 0.1 una rF 3% •� 10% •7• 10-V t+- 10%' -- 5 ttS-LL C7,7 -.SfJII .t -- ❑ 1b. 6142,-LoCl T is 14 q 6 6 •G 6.41 2p i L J. L S. z.r s 6L 6,6z {, - 01gCie1 Ssln olina Dale a ITme- 0k lzul LO f L O L BamDles CosecFad: AaalOil a Reauesled PreaswaN. Hold Time fdaaal Lph: t1aW: C •Rrenw.anilrr aMM+.m Arm �a.•�p. ww'i w,�iy sr_r.iruuerry�e.weerrmr,wro.rm Nar.. WATER MATRIX SA44PLING WATER MATRIX SAMPLING k .; FIELD DATA FORM ERM FIELD DATA FORM E J Sipe Name: RJRT tzlwiir15 Road Landfill .lob #0551517 Sampla Type: Crrcinage - (Monitur We% OPT, 9urfaco Water, Potable WSW; Other) Sam fa 10: W - Ile--t-7G •7x r_sa 'c Date! CrLW.I EQ Sampling Personnal- idteal R- Weather Gonditiortz: sunrry, t>a.1ly Caway, c+ewy. C� char Time: ! _ _ Well F4°h Surfers Cvn vomt, up Com - Well Ta Present= tin Well locked: No Lock Present: W Well I11 info. on Tag! es, No Wall Bolted: Yes Nv WeA cap;NA Well Ca Condltian: RevA Olhvr Wall Pad Cand Rion: , Ctacked. Replace. Ola[c Well LaCallgn: r Awhaa, Canmate. Woods, Other_ Add l Banal Cununents: Total Depth of Well (T.D.): Screen Length: 10 fq"l her: Depth to Water D,T.W :lrl 1 ', Well Diameter: +, a, a Ifldw "( Rald Parameter measured with: YeT M&VYA(.tt Casing Typa' 51ea1 0M. Pa rge Ra ta:vl U nAAwn Sampling Device: nsvon. Grundl a. Boller. POB olrwr. _- Tubing Type: Po en one Mea&urLn Point: TOC oiler: Pump Intake (ft bale- M.P,� S Color: Odor. Yet, No Time' min) Wume Puf 0d DTVV: ifaet Temp Cl pH std units SpC uBlcm DO m L ❑RP mV Tat e1TtJ commaplin SkibaO All- Critorla' Aons {pee Wi We.)' N• 7% .1• 7.1 un6 +1- 3% 1dY +1- 10 mV •✓- low 5 !G.`r6,3 1 ILIT I Z lft -G'I•Z 11 i3 w r 131,6 og 4LG Z . I� ! 5 L7.L 1.a a r. v s. g i ! s, c.: s� J. .ti _ dflir ial Sampling Date & Fina: M /Iq/ ] i 4 I L D Samvia& Cdlected Anaivsis Reouasted: Pe=s o yci Nwer. nt n,...,,...�°...ir� n ra.,.r..rw.w.wrr wi u,wt a rwo- iswr-nsrw.ir«�e..n.i d •. Mo e.w�� W -Tur.l y.,uw. x.riu e.M.wi.im W1r u -pier wri+tr. i°wrn n�a•in b4wctiw�eran t m � of R- SIm (Jame: Rd RT Edwards Road Landfg Job 4,0551517 Sample Type: Circle one-(Monhor Well, OPT, Surface Water, Potable WSW; other) Sam lalD: •• 4�•i ' J,� f: - 1v:_ �n •• Dale. Sampling personnel: Andrew Hr_ h:heal Weather CundiHons: S Para C , iCl 4drer Tfine: 7 — Well TypW. FYch Sudae: Comdetek;-rAOtlPCam Well Tag PreaeeC Y@' No Well Locked: �'1' No Lock Preaerlk No WeI11D info. on Ta Na Well Bolted: N0. NIA well Ca �� Y , No Weil Cap Condition: QlG9. RMAd . ppxr, Wall Pad Condition: i CrocKed. Replace. Ocher. Wall Location: Asphalt, Con ',, Woods. Ogren Additional Comments! Total Depth a! Well (T,D.): 1'7 Screen Length: 5, db� is, 2p feet -other, Da 1h to Water ID.T.W : nr Well Diameter: i. a, a k.ches• Lh&-, F laid Parameters measured with: Casing pe: SOeN carer Purge Rafe: 'V mUmin Sampling Davlco: Itic, h►xiaaan, mvad oe. Racer, PDe, Oth- TuLAngTypej Polyoh MeasuringPoint: ❑ 0 other. P Limp Intake (ft below M. P.): Color. Odor: Yes, No Time: min Volume Purged DTW: feel Temp PH std units) W tuVom) 00 (m !L ORP mV Turb NTU Comments: Smbah aaen Crlterw, geAorci flea Into etlo t +F 996 +1- 01 uld 0- 3% rr. $0% 4 1e mV +l- lff%1 J; Ire • y 6-'s N c1,-7 I�� Ic I G -3 C. Ys ryL (i• bc, t K D /: v s 6.3 6-Yv 6. r c. e zl L 7S .[ Cl 7 ! -S G 77 6 7 i2. 1, 044 10 3 L-26 GN 0.17 IG �:7 G tl7 ic,3 G 121.1 0-3 Official Sameline Date & Time: `7'7,r1 / 2 GI r / Fr- HQW TImO fdaysiLab: Sametes Coladad: Anelwis RctagLiPd' Presarvalrve- Fold imgJdayda Lab. - NOW, rm-r�nrwe...raa.i,,...°orm�.Nr. rw.t,w.r....,...°..w•�. tern wo-. r...o.rmnsl4 WATER MATRIX SAMPLING WATER MATRIX SAMPLING FIELD DATA FORM FRM FIELD DATA FORM sae Name: RJRT Edwards Road Landfill .lob t0651517 Sample Typa: Cirde oneOPT, SuAace Water, PotabTe WSW; oth" Sam la ID: r - 15 Date: _ } Sarnipl Ing Personnel: Andrew H. Micheal R- WeatherConditians: sunay, Fe «� Omer Time: Well T e: Fpun Su"m Cwnpeli ' slick U _ ell Tag Prevent, .Yes, No Well Lcekedi Y No Lock Prp ; ea No Well ID We. on Tag. Yes; No Well Solted: v No WA Wall Ca : ran;• rid Well Ca CondHion: Gigd, Replaoa -er Well Pad Condition: ram:' Cracked, astir: Well Lodatian•�"s.a sspt�a, Conaale, NMods, Olner, Add hional Commends: Total Depth of Well [T.D.I- Screen Length: 510, IN- Fee miter Depth to Wafer (D.T.. ut e , - Well Diamer. ter $ w _e, a Incir�aa ar FILM Parameters mmaeured with; Casing Type: .spear deer Purge file: ! - mum ln Samoli no Deulce' 'slelilq ftati+oon. Grundfo% Rolm,, Po6, Other. Tubin Ty Measuring Point: 0157 other - Pump Intake IRhelow M.P,): Color. Odor: Yes, Time' min Volume Pur ed DTW: feel Temp PH std unila SPO uWcm DO m IL ORP mV Turb NTI} Corllmem5' Slnbal"Ilm Cnrerie rwlsi lsee ria19 WOMr •R SY H- o.1 rrll +!- 3% •F 10% 4 10mV N- 10%, M a _i r 7 7 91.s 13A Oi~ 1 LiiGa 7. oc 3 9 ;;, ,5 n 3G IL17 • b 0 Z U �.5 777T c" 2 7' G -G.LS offMal Samolyio-DatQ&-Am `/�,Z!%�='• + j. f'l' Samotes Collected: Anahl3is Reorsasisd: Preservative: Hold Time fdaysl: Imp; Raw ra• o,.d.......,en ee,...� x.,. �.w w. e.rr�e..e.sv,.nK. �.,..n.s,w Mn w�.-r a...�, m...,,+�. Site Name, PAT Edwards Road Landfill .lvn #:i155 �517 Wimp le Type: circle o-1-66hor Wei DPT, Suriave Wale r, Pofahla WSw; vtherl Sam le ID: - U GZr�af2 Dale: C3 zo Sampling Personnel; Andrew H. Mich Weather Cond Nona: PariV-6[au&CRein: other. Time , 20 Well T el R.9� SirtatoC ,,Wi slck u Can Walt 74Present: Yes, No Well Lacked: a un Lock Present; Ne Wall ID into, on Tag: 'eft. No Well Salted: ewrtNo Nan Well Cap: N. Welt Cap Candniow Goad. napiaae, ❑ihye Well Pad Condition: race. rraexeM. Rcpie . piper Welr Location: Grays. Ae2W. porume, V*-La, piner Additional Comments: Total Depth of Well [7,D,]: 20 Screen Length; S. 10, is. 20 rear nher Dc th to Water C]J.W : r'r IGt7. C• Well Dlametor: A. 5. a lhdl -Mw Field Parameters measured with: Casing Type: 54m1 what Purge Rate: mtmrin Sampling DeWco: Pensulao, on. GrunoW% eaitnr- I•DR. ❑weer Tubte Type! Pd t lone Maosurfric Polnl: other - Pump into ko [it below M.F.I: Color: Odor: Yes, Time: min) Vdlums Pu ed ✓7TW: feet Temp 'C pH Nil u+iils W- Uskm DO m fG ORP mV Turin NTtf COmme.ms' 5laheli'rslim Cnrerle' Itanel {eee nitre hdw�' aF 3% ax o.] At Y- d°Aa •r- ]0% •F ia.v H- .a%` B 1 t 3 -Li o. 7 •G ,3 i f5 tom• SASt Q Z _6`I.6 15 r5 9.1.1 c aLe, .Tz. 94'-13 S ts•S a•x� 3 L.6 Z• Lt`t 0 15. a z 5 3 Pad. -1 13 1D Olfrcini samdirio Dais S 71me: (7`11Z L11 L0 1 { 3cx> Samples CpllecledL Anepysis Rerivaesed^ Presaryaiere: Hold Time fdevs]'. Lab. 1rn ...... wit � u.=www mr.wa.wy..e..wrr �w. �...wA-n =.. �.n �..r*, ••••R=.*• -.ewM WA TER MATRIX SAMPLING J ;; I WATER IVIQ7fitX SAMPLING FIELD DATA FORM FiR M FIELD DATA FORM Soto Narnef R.1RT Edwards Road Landfill inh #:055'{ 517 Semple Type: Clyde ❑ [Montt" ell, QPT, Surface Water, Pvtabto WSW: otherl Sam le lQ: Z _ pate: Sampling Personnel: Andrew K - eel R:- WeaiilerCondMuns: Swrp, PanW Cloud Re.n; Oh. Time: Watt TVpa., Flush suu. Com"leoln udr Cam Welt Tag Prasont: No WaH Locked: No Lock Present: ,' N0 Well ID info. on Tag: xEjDNe WaIl Bolted: Na "A Wert Ca , No Well Cap Condition- ;replace, Darr, Weil Pad Canditton7 0& Cracked, Reamee, Odw Well Locatlan: Anna% Conaela woons, olhw Additional Comments: T0181 Depth of W¢A (TA.): 3 t1l screen Lengtl5: laewe.er Depth to Walar O,T-W : III Well Lila meter: x 6. a Indw.lrnow Field Parmme;ern nteasured wJltu Z.15Z Casing Type; pJC, eel corer: Purge Rate; f ] nfUmin sampiing Device- Priam G.ios. 6a4er, Prla. Olhef: To lift T e� ,W h measure Point: alner. Pump!"take ft .P*) Caior: Odor: Yea, No Time: rule voluma Pu ed OTw: feet Temp PH std unlls &PC 01= DO (MOIL) ORP my Tut WLI Commenla' stat><+karvn Crib+a' jgaeuig {ace moo bdaJl° •o- 3% .+. 0.1 wit 16 3% •+- 141% w- 10 my •f ��' I S 2 . dy 7,6Z 209,1 47.29 737. 27- 1 is i^. 7.37 20 .7 y.21 -78-4 20.. 15 C� Lr7 u t Cl 2Ci 15. 1 `1- 07 2 O b t 'V I Z I S. r 0 5 Olwal sam¢lin5if]ateATlmi. I 2,V1 d + l 3 Lit) $afi¢W_s f�vlLerAfdl: Ana[vsis Reeueslo - P ra- . Hold rime wmm L& I4e {p_T.u,ar�wi y.,M •b�y,,.a i �NR q, YuWp �r. rn e.1�.ex r •.•.+w m.no.+m�n aYa..t n m.p � ki ERM Silo Nama: FQ RT Edwards Road Landfim Job #.0551517 Sample Type: Cirdeo -{Monitor W PT, surlace Water, Pala bie WSW; other) - sam le;Q: %V- - G - O Pale: '+_� 1 -7 f, sampiind Peraum al: Andrew H. Woatltier Candiliona: 51wnw Po C ,clue 7 , R nWwr Time: Well T Ffmh Surrxe com Slak Well Tag Present: wa Wall Lacked: No Lock Pirasen : Well IQ info. on Tag-' N. We}I fioltetl: �' W, WA waif Ca No Well Ca ColMitlon: pod FtE* m, Qerec Well Pad Condition: ,' cmdc , Hopkacq ciher, Well Locat}on, f3&esl A3phsll, COnsel", V*o Os- , -Additional Comments; of Well (T,Q.I: P screen LA11fi : 5, 10. 15. fanl..w,er Denthater!➢,Y, ; Ir} . I Well Diameter 1z s, e, B Inchw•oIM. eters measured with: Casing Type- , sw. dhw : +!r � munin NT�bl,qTv Sampling parlca: F.aN9aR- Aerwaoh.�Gnwfos, eaRv, FOR, olnnr Mea Burin Point: T OG Other, k¢ be7 M.P.); Color' Odor: rm, (mil) volume PUFqed OTW' feet Temp pH std units $PC (USlGrFO OO ImniLlmy ORP Turh NTII Comments: S15oell�alrcn CAla�e' ellaisl (son new bobai� •F S% N- 0.1 unit 4. 3% •$_ 10% •F 10 my .F 57kr L j1J Ia. tr •j .L_ I.-r; -J(,. I 2C,6 f5 5.2 U 165 Ifr7 r_ cif 16 IZ 4r7 rzr ls.5 �� 7L i 1. F %.53 7•'7 a.8 r1;; -7 G f. it 5.1 6.20 V70 1G,� Olfictal samplingDe3s3�&Trine: s¢mn[es CQIIe�Jed. Anahram Renuated: Prasarvatwe. H 0 N Tl<nelday=5l Lab ante Pf•rNa www�nx,.ho-rxr•ry�n�31 r1 �+e.r.rxw pvw..,new�r�Y�a v.r+w�ln4¢I mi.vn WATER MATRIX SAMPLING WATER MATRIX SAMPLING FIELD DATA FORM I M FIELD DATA FORM ERM U Sire Name: RJRT Edwards Road Landfill Jnb � U55i5[7 Sample Type: Circle one onitor Well PT, Surfnce Water, Potahle WSW; other) Sample ID: 7- Dais: Sampling Personnel: - icheal R- Weather Cond itlons: Ci¢ud , r`W— Rehr, Oh — Time: Well T e: Flush Swtara eeaa, u aeon Well TagPresent: eai�.. Na Well Lacked: No Lock Present: No Wei] 1D lnfv. on Tag : No Wall Bolted: Yes, Nq Well Cap: e4 ! Na Well Ca Condition: Good,; Repace, Amer Well Pad CGndidon!/'Gaudj Cracked, Raplam cthmr Well Locatio • amm, • 4 Cenaoe, Woods. Ogren: Additional Comments: Total Depth of Wall iT.D.j: 5 Screen Length: 5, 10, f6, 2e •, f6K-.dur: Depth to Water Ixr,%M.• "I 7 L O WBII Dlameter: M 4 e, a Whes-oIW: Field Parameters measured with: Casing Type: sled older. Purge Rate: -! r-i G mLinin Sampling Device: Pe xaab.. Mdtww, GIur,dfvs. Umer• PO& ..her. Tubin 7 o: Measurin Paint: TOC other: Pump Intake IK below M.P.: Color: Odor: Yes, Na Time: min Volume Pu ed DTw: feel Temp PH std urlita SpC u81cm DO IL ORP mV Turb NTU Cnmmenls: SteeallMtlen cdlaria� laee nde 6eJv ry' +1. 3% +F 0.1 udt .F 146 H- 10% +j- ]p mV +F sd°h� i( I. 19 n C7 -/2-1 fc� 06 jlr 3� 7- S -li`IO }1 7, "L N. 7I7 -it) C n - 1. _ T I 1 5l I6 e, 6 s ti - !'ice P. . 1i•� E - S, +7O 17- 19 1Y71 L7 hG 0 b q 13 5 Off1dal Swoling 021Q 6. Times Gam+( ?- 3 / ZID t I - LC.) Samples 4aollesde7 Analysis Reauasled: i w Hold Time !days!: 192 nth- o�,r...r..wrn a w.r,,,¢ ws rn., c.v�.-e...r.+a a r.w...n,.r-+m •,•• oM m,r rrwm� �n..w mom. yxj-m.eY.reneNl. ewNwln. r>•+ru.r.c...r:.. m�� pd-iaJ erraw�nxr¢e Y4r ¢,r gr w,Rv V. �rtw W,...., n,ww.wYaM�w�.dw" "-. ¢rn Aax nF Site Name: RJRT Edwards Road Landfill Job p:U5d1517 Sample Type: Circle one -(Monitor Weil, OPT, Surface Water, Potable WSW; other) Sam la ID: r r Z 0 .sf , rL. +z 7 Date: 01j 2 / 2 V c- Sampling Personnel: Andrew H- Micheal R. Weather Conditlaaw Parer wy, Ckx¢fy Rmn; qoh Time: Wall TYPC FWsh SUft* C Sddr u con,w Wali Ta Presenl: Yw, No Well Lkooked: Yea, No LacPresent Vet No Walr ID info. on Td : Yea W WBII Bolted: Yea, Nn, WA Well Cap; Yet No Weir cap Condition: Good, Raprdce. Omer Well Pad Condition: Good, packed, Reasm fiber- Wall Locadan: prays, AapFatL Canaela. wood., Otl- Additional Cammenra: Total Depth of Wall (T.D.): Screen Length: 5, 10, 16, 20 fanKbw-- Da Ih to Water AT.ft n' Well Diameter: 2, a, S, a lnaws•oanr. Field Parameter's measuredwlth: Casing Type: Pw. Sena! finer: Purge Rate: mU.0 Sampling Device: Penalallic. rewn n, ,rusdfos, nallar, POK Clhw. Tubing a: ne Measuring PoinC TOC other: Pump Intake (I t below M.P.): Color: Odor: Yes, No Time: min Vo"e Purged DTW: fee! Tamp 9c pH std umis W akmj DO m R ORP mV 7urh NTu Comments: Staboixako Cn[ [gee rnta e1FN'lr b •l- 1% ♦b 0.1una .i• 3% +,. ID% 0- 19mV .6 I JfStial Sampiina Date $ Time• r SaD)IOW Celleded; Analysis Reauesled: Prosarvaliva: Hold Time fdaysk Lila ,]i-aY.Lr •win Wrr. r.. �mginr,+mrrw�mn��r. Cy-ieW ew,nw�uru.. Y.. r,..e,mwir�.i r��rwac�lw•wn..�wyw Rrw e.weernrbx¢r�paxru WATER MATRIX SAMPLING FIELD DATA FORM Site Name: Rd RT Edwards Road landfill Job #; 0551517 Sample Type: Ckde one - (Munitor Well, DPT, Surface Wale r, Potable WSW; other) Sample ID: Date: Sampling Personnel: Andrew H, ylictle l R Weather Conditions: qaw :, crowd , Rain; OHrar Time: - Wei e: Flush Svff c cnm ouon, Slzk tla Camernuoe Well Lag Present: Yes, "a Well Loekad: Yea, No Lock Present: Yes, No Wall ID Info, on Tag: Yoe, Nn Wei Halted: Yes, No. NIA Well Ca = Yes, No Well Cap. Condition: Good, Repave, Osier, Well Pad Condition: Good, Cracked, Repace, Other Wail Location: Gra Ayphaft GonoiekL vwooas, Omer Additional Comments: Total Depth of Weil JT.D.): Screen Length: U, 10. 10. 20 reel-odw,r: Depth to Water D.T.W : "I Well Ulameter. 2. A. % a v'her Field Parameters measured with: Casing Type: PVC. Steel other Fu a Rate- mLlmin Sampling Device: Pafttallic, Monsoon, Gnmotoa, SaWr, PPB, Other TuWn T e: WhrmNena Measurin Point: TOG other - Pump Intake (ft below M. P.): Color: Odor. Yes. Na Time: min ? ,r ' Pttr DTW: 7eet Temp pH Sid units SpC vSlan DO IL ORP mV Turb NTU Commens: SlAboaallon cro.ie' T I ewe, 11om1 (see role balowv .I• 3% +J-rF 0.1 will 3% 1d% 10 mV N- 1OW 1,3 3 1� 70 7 LS - 2cJ IH �57 f -q 6(-, 5S- ZS 1N: 5 1 12� O 7•° SS R-Z. 5_3 C 1dJ' S C) 5 '7 uJ cr1 .3- 4 7 5vc L 's-01 15. flu IS 5 777- 316. Z. 7. aC '7• -jIt. 9 -7 3Z O Z r OrWal Sampling Dale S Time: + Samoies Collected: Anslvsis -Nested: Preservative: Hold Time fdaysl: L xe ' m • m w...n..rr,r,eaw. rwe w,...*d wow..e..,wn � �..w. ve�,...+her.n, a....n. nwv......ee,n.,� w•raw•.mnw.rrerbae.ev-norm. ++row,r•e..._.....R.er.�.b...�w�r.�e.aro,mm.ixn (WATER MA TRIX SAMPLING FIELD DATA FORM Site Name: RJ RT Edwards Road Landfill Joo #:GS51517 Sample Type: Circle one -(Monitor Well, OPT, Surface Water, Potable WSW; ❑ttierl Sample ID; , 1 i' ,a (w,• , Date: Sampling Personnetl Andrew H. fdlc►isal R, Wealher Conditions: , P Uxiq, cloudy. kern, oils. Time: Well e: Fkah surla Cum own, Sodi ti Coisplow Weu Tag Present: Yee, no Well Locked: re& No Lock Present: Yam Na Wall ID Info. on Ta : Yea, W Wait eoiw: r • Nq NIA wall cap,.-- Yea. No Waif Cap Condition: Good, Replace, olhw. Well Pad Condition: G—L Cracked, Replace, 01har Wait Location: Grays, AV". CuKk e, Woods, Amer. Addklonal Comments: Total Depth of Well (T.D.} Screen Length: 5, 10, is, 20 feet-0tner Depth to Water (D.T."; "I Well Diameter: x i, a, a k lres•osrer: field Parameters measured with: Casing Type: PVC. Suea1 Purge Rats: mLhhw Sampling Device- pedslaluc, Monsoon, C4un4f4)% Bator, Pole, Omer Tubin e: PGPiethyism Measuring Point: TOC other - Pump Intake;ft below M.P.): Color.. Odor: Yea, No Time min Volume Nrned DTW: feet Temp pH Ow units) SpC uSkm DO ORP mV Turb NTU Comments: stablirat.on Ch[era' f (sae rote nelm„1' *I- 3% .F 0.1 ural +4- d% +!- 10% rb 1n mV H- 10%i 77•; III. 1r •I 5tcsF i. `t j't Its' i:. 10. f -.s n ; T IIT 3 d fib 68 12 S EE Offlcis SaM D[mg g9te TIMO, I sentries Cogaded: 'AnoIvsrs Reouested: Hokt Time ldaysY L& Notes: (nPo.rr eaw,+aMrraoar.rrrrwww e.qa rs..�.na w,,..�e.,� ..u�v ir.ur-a e.,.we�w,.0 e.a.e PI-rdrdAr.'_-nxNmbin.ewntm Pup a�gr¢,rn t. krx.e..rw.uuyr woe a..�.,n b.bwat ni N.ua ERM has over 160 offices across the following countries and territories worldwide Argentina The Netherlands ERM's Charlotte, NC Office Australia New Zealand ERM NC, Inc. 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