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HomeMy WebLinkAbout1403_Caldwell_Foothills_MSWLF_July2020GW_FID1485741_20201109W REPUBLIC SERVICES November 9, 2020 Ms. Jaclynne Drummond Hydrogeologist Solid Waste Section Division of Waste Management North Carolina Department of Environmental Quality 2090 US Highway 70 Swannanoa, North Carolina 28778 RE: Second Semi -Annual Water Quality Monitoring Report of 2020 Foothills Regional Landfill, Permit No. 14-03 Caldwell County, North Carolina Dear Ms. Drummond: Republic Services of North Carolina, LLC is submitting the Second Semi -Annual Water Quality Monitoring Report of 2020 for the Foothills Regional Landfill and Environmental Monitoring Reporting Form in electronic format. The report completes the Second Semi -Annual compliance monitoring event of 2020 for the Foothills Regional Landfill, Permit No. 14-03, as required by the North Carolina Division of Waste Management, Solid Waste Section. If you have any questions, please contact Steve Jett with Jett Environmental Consulting at (314) 496-4654, or me at (314) 302-3634. Sincerely, Republic Services of North Carolina, LLC Mr. Derek Bouchard Environmental Manager Enclosure cc: Stephen Hunter, Foothills Regional Landfill, Republic Services Joe Montello, Republic Services Steve Jett, Jett Environmental Consulting Page 1 of 1 ENR USE ONLY: ❑Pa er Re ort [-]Electronic Data - Email CD data loaded: Yes / No Doc/Event #: NC DENR Environmental Monitoring Division of Waste Management -Solid Waste Reporting Form Notice: This form and any information attached to it are Public Records as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: • Prepare one form for each individually monitored unit. • Please type or print legibly. • Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). • Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. • Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). • Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Jett Environmental Consulting, PLLC Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Steve Jett E-mail: steve.jett@jettenviro.com Phone: (314) 496-4654 NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Foothills Regional Landfill 2800 Cheraw Road g Lenoir, NC 28645 14-03 .1600 July 26-27, 2020 Environmental Status: (Check all that apply) F] Initial/Background Monitoring Detection Monitoring Assessment Monitoring of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells . ❑ Methane gas monitoring data Groundwater monitoring data from private water supply wells ❑ Corrective action data (specify) Leachate monitoring data Surface water monitoring data ❑ Other(specify) Corrective Action Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. F1 Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Lertitication i o ine pest of my Knowlecige, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Steve Jett Owner (314) 496-4654 Facility Represent& N fne Title (Area Code) Telephone Number Signature I I R l 2 L-� Affix NC Licensed/ Professional Geologist Seal Date Jett Environmental Consulting, PLLC, 1002 Morgan Meadow Drive, Wentzville, MO 63385 Facility Representative Address NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 Groundwater Statistical Analysis Report Second Semi -Annual 2020 Sampling Event Foothills Regional Landfill Caldwell County, North Carolina November 2020 Prepared by: JETT ENVIRONMLN IHL C O N S U L T I N G 1002 Morgan Meadow Drive 314-496-4654 Wentzville, MO 63385 www.jettenviro.com TABLE OF CONTENTS 1.0 INTRODUCTION.............................................................................1 2.0 SITE BACKGROUND AND MONITORING NETWORK................1 3.0 SITE HYDROGEOLOGY................................................................2 4.0 DATA EVALUATION......................................................................3 5.0 STATISTICAL PROCEDURES.......................................................3 5.1 Outlier Analysis...........................................................................3 5.2 Inter -Well Prediction Intervals....................................................4 5.3 Intra-Well Confidence Limits......................................................4 5.4 Statistical Results Summary.......................................................5 6.0 CONCLUSIONS..............................................................................5 7.0 RECOMMENDATIONS...................................................................6 Table 1 Groundwater Monitoring Program Table 2 Groundwater Analytical Data Summary Table 3 Surface Water Analytical Data Summary Table 4 Underdrain Analytical Data Summary Table 5 Leachate Analytical Data Summary APPENDICES Appendix A Potentiometric Surface Map Appendix B Statistical Evaluations Appendix C Laboratory Analytical Reports & Field Sampling Forms Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 1 1.0 INTRODUCTION On behalf of Foothills Regional Landfill, Jett Environmental Consulting statistically evaluated the Second Semi -Annual 2020 water quality monitoring data. Groundwater, surface water, underdrain, and leachate sampling were completed by Environmental Sampling & Services, Inc. (ES&S) on July 26-27, 2020, and analytical testing was performed by Pace Analytical Services, LLC. The statistical analysis software package utilized, Sanitasr', follows a documented decision logic that incorporates the following applicable document: USEPA "Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified Guidance" (March 2009). 2.0 SITE BACKGROUND AND MONITORING NETWORK In compliance with North Carolina Department of Environmental Quality (DEQ) Solid Waste Management Regulations, Section .1600 "Requirements for Municipal Solid Waste Landfill Facilities," Jett Environmental Consulting statistically evaluated parameters from the Second Semi -Annual 2020 event using inter -well prediction interval analysis. Prediction intervals are considered a powerful tool for groundwater statistical analysis, when feasible, due to their inherent low false negative and false positive rates utilizing confirmatory resampling, if necessary. The facility's monitoring network is comprised of eleven monitoring wells: MW-1 R2 (background), MW-2R, MW-3R2, MW-4, MW-5, MW-6, MW-7, MW-8, MW-9, MW-10, and MW-11, which monitor the uppermost aquifer beneath the facility. The monitoring wells are sampled on a semi-annual basis, with the groundwater samples submitted to a qualified laboratory for required analyses in accordance with the facility's environmental monitoring program and permit requirements. The monitoring wells are equipped with dedicated bladder pumps and were purged and sampled via the low -flow method. Table 1 lists the groundwater monitoring wells for the site. Each of the wells was sampled during the Second Semi -Annual 2020 event. Groundwater monitoring was initiated in August 1998. Statistical background is defined as samples collected from former upgradient well MW-1, former upgradient well MW-1 R, and current upgradient well MW-1 R2 from 1998 through the current event. The parameters subject to statistical evaluation during detection monitoring are noted in DEQ Section .1633 as constituents listed in Appendix I of 40 CFR Part 258 "Constituents for Detection Monitoring". Well MW-3R2 was added to the monitoring well network on August 17, 2006 as a replacement well for MW-3 and MW-3R. Monitoring wells MW-3 and MW-3R remain for water level data collection purposes only. Monitoring well MW-7 was installed in April 2010 to monitor groundwater beneath Cell 4, which began receiving waste in September 2010. MW-8 was installed in April 2013 to monitor Cell 8A, which was constructed in January 2013. MW-10 was installed in October 2015 to monitor Cell 5A. The former background well MW-1 was abandoned in preparation for construction of Cell 5A and the new background well, MW-1 R, was installed in October 2015. MW-9 was installed June 2016 to monitor Cell 5A. Soil and bedrock removal in the Northern Borrow Area rendered well MW-1 R dry and inaccessible. Therefore, a replacement monitoring well (MW-1 R2) was installed in September 2018. New well MW-11 was also installed in September 2018 as part of the Cell No. 5B construction. The site has a surface water monitoring network consisting of one upstream surface water sampling point (SW-1) and four downstream points (SW-2, SW-3, SW-4, and SW-5). These points are sampled semi- annually for the 40 CFR Part 258 Appendix I list in conjunction with the groundwater monitoring wells. Each surface water monitoring point was sampled during the Second Semi -Annual 2020 event. A sample from the underdrain for Cell 1 (UD-1) was added to the monitoring network prior to the January 2008 sampling event. A sample from the underdrain for Cells 4 and 8A (UD-2) was added to the monitoring network prior to the January 2014 sampling event. The underdrains are to be sampled semi-annually Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 2 (contingent on flow availability) for the 40 CFR Part 258 Appendix I list. Both underdrains were able to be sampled during the Second Semi -Annual 2020 event. A leachate sample is also routinely collected for analysis. The Ieachate sample was analyzed for the 40 CFR Part 258 Appendix I list, biochemical oxygen demand, chemical oxygen demand, nitrate as N, nitrite as N, phosphorus, and sulfate. In accordance with a November 28, 2018 DEQ letter, 1,4-dioxane is no longer required be analyzed for the groundwater and surface water samples; however, will be analyzed annually for the Ieachate sample. The Ieachate was sampled and analyzed for 1,4-dioxane during the First Semi -Annual 2020 event. The facility was in an Assessment Monitoring Program in 2006. An Alternate Source Demonstration (ASD) for volatile organic compounds (VOCs) detected in wells MW-3 and MW-3R was approved by DEQ on December 14, 2006, and the facility reverted to a Detection Monitoring Program. An ASD for cobalt and a request to use background as the groundwater protection standard (GWPS) for cobalt was submitted to the DEQ in November 2016. The ASD is currently under DEQ review. An ASD for benzene and vinyl chloride at MW-2R was submitted to DEQ in June 2017; however, it was not approved in a letter from DEQ dated October 11, 2017 and Assessment Monitoring was initiated. Therefore, during the First Semi -Annual 2018 event, the initial Appendix II Assessment constituent list was sampled at each well. The constituents detected at quantifiable concentrations (barium, benzene, and cobalt) were consistent with past events and also on the Appendix I Detection Monitoring list. On May 18, 2018, the site requested deleting all non -Appendix I monitoring from future sampling events, with the exception of well MW-2R, which will continue with annual Appendix II monitoring. In correspondence dated July 9, 2018, DEQ approved the request to only include MW-2R for future annual Appendix II monitoring. The annual Appendix II monitoring for MW-2R was most recently performed during the First Semi -Annual 2020 event. No Appendix II constituents, not also on the Appendix I list, were detected above their respective PQLs during the First Semi -Annual 2020 event. The next annual Appendix II sampling event for MW-2R will be the First Semi -Annual 2021 (January 2021) event. 3.0 SITE HYDROGEOLOGY The following site hydrogeology summary was taken from the Second Semi -Annual Water Quality Monitoring Report of 2017, dated November 17, 2017 by Joyce Engineering. Geologically, the facility is located in the northwestern portion of the Inner Piedmont Belt of the Piedomont Physiographic Province, approximately 20 miles east of the thrust belt (Brevard Shear Zone) delineating the boundary between the westerly Blue Ridge Belt and the easterly Inner Piedmont Belt. The metamorphic rocks of the Inner Piedmont Belt generally group within the sillimanite facies of the amphibolite metamorphic sequence. Locally, the bedrock underlying the facility has been mapped as migmatitic granitic gneiss of the Ordovician and older Cambrian Periods. These rocks are described as ranging in composition from granitic to quartz dioritic with smaller biotite gneiss and amphibolite facies present locally. The unit as a whole exhibits a variable massive to foliated fabric. The uppermost aquifer beneath the facility is present within weathered bedrock saprolite and fractured bedrock. The saprolite ranges in texture from clayey silt in the upper, most weathered sections to micaceous sandy silt in the lower sections. Immediately above the competent bedrock surface, a variable thickness transitional zone composed of highly weathered and degraded friable bedrock is present. The uppermost aquifer is laterally continuous across the site, with depth to water ranging from less than 31 feet in low-lying areas to greater than 77 feet beneath topographic highs. Groundwater in the uppermost aquifer generally flows from recharge areas associated with broad gently sloping topographic areas towards topographically lower areas that are generally delineated by the presence of stream channels, some of which are perennial receiving streams (groundwater discharge areas) and others of which are intermittent Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 3 discharging streams. In the vicinity of the facility, the general groundwater flow direction is towards the south and west. Appendix A provides a potentiometric surface map utilizing groundwater level data from the Second Semi - Annual 2020 event. Groundwater flow direction for the Second Semi -Annual 2020 event was to the southwest, which is consistent with previous interpretations for this facility. Groundwater flow rate for the Second Semi -Annual 2020 event was estimated at 176 feet/year, consistent with past events. Flow rate calculations are available in Appendix A. 4.0 DATA EVALUATION Appendix C contains a copy of the laboratory analytical report and field sampling forms for the Second Semi -Annual 2020 groundwater, surface water, underdrain, and leachate sampling event. The analytical results for the Second Semi -Annual 2020 event for the groundwater, surface water, underdrain, and leachate samples are summarized on Tables 2, 3, 4, and 5, respectively. One volatile organic compound (VOC) was detected at a quantified concentration at or above a laboratory practical quantitation limit (PQL) in the groundwater samples: benzene at MW-2R, which is typical for the site. As shown on Table 2, two Appendix I inorganic constituents (barium at MW-2R, MW-5, and MW-6; and cobalt at MW-4) were detected at quantified concentrations. Two Appendix I constituents (benzene at MW-2R and cobalt at MW-4) were detected above an NC Interim Maximum Allowable Concentration (IMAC) or 2L Standard during the Second Semi -Annual 2020 sampling event. Cobalt (MW-6 and MW-8), and vanadium (MW-2R, MW-3R2, MW-4, MW-5, MW-7, MW-9, and MW- 10) were detected above their respective IMAC, however at estimated concentrations below their PQL. Per 15A NCAC 02L .0202(b)(1), for the NC 2L Standards and NC IMAC Standards, only detections of a substance at or above the PQL can constitute a violation of the standard. Therefore, estimated values below the PQL are not considered a violation of a NC 2L Rule standard. As shown on Table 3, during the Second Semi -Annual 2020 event, no inorganics were detected in surface water samples at quantified concentrations above a respective NC 2B Surface Water Standard. No VOCs were detected in surface water samples at quantified concentrations above their respective PQLs during the Second Semi -Annual 2020 event. During the Second Semi -Annual 2020 event, no VOCs were detected in the underdrain samples at quantified concentrations above their respective PQLs. The constituents detected in the leachate sample collected during the Second Semi -Annual 2020 event were typical for leachate at this facility. 5.0 STATISTICAL PROCEDURES Statistical analyses (i.e. inter -well prediction limits) were performed to establish background concentrations and determine if the IMAC value -to -value exceedance for cobalt exhibited a statistically significant increase. Statistical analyses (i.e., lower confidence limits) were performed to determine if the 2L Standard value -to - value exceedance for benzene statistically exceeded the 2L Standard. 5.1 Outlier Analysis The background data were evaluated for the presence of statistical outliers. Methodologies for determining a statistical outlier are defined in the EPA document, Statistical Analysis of Ground -Water Monitoring Data at RCRA Facilities — Unified Guidance (March 2009). Any statistical outliers that were determined were removed from the background data set prior to performing prediction interval statistical analysis. According Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 4 to the EPA guidance documents above, data that are not normally or log -normally distributed are not recommended for evaluation of outliers. In cases where the data were not normally or log -normally distributed, outliers were not removed from the data set. Background outliers flagged for removal are identified on the statistical plots provided in Appendix B. 5.2 Inter -Well Prediction Intervals The prediction interval is a statistical method used to compare a single observation to a group of observations. The prediction interval is calculated to include observations from the same population with a specified confidence. In groundwater monitoring, a prediction interval approach may be used to make comparisons between background and compliance data. The interval is developed to contain all future observations, within a certain probability. For the site, inter -well prediction intervals have been developed based on a 99% confidence that future observations will fall within the range. If any future observation exceeds the prediction interval, this is considered statistically significant evidence that the observation is not representative of the background group. During parametric prediction interval analysis, the mean and the standard deviation are calculated for the raw or transformed background data. The number of comparison observations, K, is defined to be included in the interval. If less than 15% of the background observations are nondetects, the nondetects are replaced with one half of the reporting limit prior to performing the analysis. If more than 15% but less than 50% of the background data are below the reporting limit, the data's sample mean and standard deviation are adjusted according to the Kaplan -Meier method. However, when the background data are not transformed - normal or contain greater than 50% observations below the reporting limit, SanitasT" automatically constructs a non -parametric prediction interval. During non -parametric analysis, the highest value from the background data is used to set the upper limit of the prediction interval. Due to the wide range of laboratory reporting limits utilized over time, the historical reporting limits were conservatively replaced with the current event reporting limit prior to performing statistical analyses. Summary tables and graphs for the inter -well prediction interval analysis are available in Appendix B. Included in Appendix B are time series plots for each of the inorganic constituents. For the Second Semi -Annual 2020 event, one inorganic statistically significant increase was exhibited for the groundwater monitoring wells: cobalt at MW-4. The Second Semi -Annual 2020 concentration of total cobalt at MW-4 (15.1 ug/L) was above the background inter -well prediction limit based on pooled data from upgradient wells MW-1, MW-1 R, and MW-1 R2 (10 ug/L, which is equal to the PQL). An ASD for cobalt at MW-4 and a request to use background for the GWPS was submitted to the DEQ by the site on November 4, 2016. The statistical background value for cobalt was determined to be 44.1 ug/L based on an Upper Poisson Prediction Limit, which is higher than the detected concentration at MW-4. The ASD requested that the background value be considered the GWPS for cobalt per 15A NCAC13B.1634.(g).5. The ASD is currently under DEQ review. 5.3 Intra-Well Confidence Limits Per DEQ Regulation .1634(H), Groundwater Protection Standards (GWPSs) are equal to the National Primary Drinking Water Standard -Maximum Contaminant Level (MCL) or North Carolina 15A NCAC 2L Water Quality Standard, whichever is lower. In instances where an MCL or 2L Standard are not established, the GWPSs were derived from the DEQ-Solid Waste Section published GWPSs. In order to determine if the groundwater concentrations exhibit a statistical exceedance of the GWPS, a statistical comparison was made to the GWPSs to determine if further action is warranted. The following text outlines the procedures that were used to statistically compare concentrations to GWPSs. Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 5 Per the U.S. Environmental Protection Agency document (dated March 2009), titled Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified Guidance, a Confidence Interval is constructed from sample data and is designed to contain the mean concentration of a well analyte in groundwater monitoring, with a designated level of confidence. A confidence interval generally is used when samples are being compared to a GWPS, which is typically the MCL or alternate limit (i.e. 2L Standard or NC IMAC). A lower confidence interval analysis was used to statistically compare to GWPSs. The method constructs a normal confidence interval on the mean concentration of a constituent incorporating, at a minimum, the four most recent measurements. The lower confidence interval on the mean was compared to the GWPS to determine whether the mean concentration exceeded its GWPS. If the lower confidence interval on the mean exceeds the GWPS then there is statistically significant evidence that the mean concentration of that constituent exceeds the GWPS. The distribution of the data is evaluated by applying the Shapiro -Wilk or Shapiro -Francis test for normality to the raw data or, when applicable, transformed data. If less than 15 percent of the observations are non - detects, the non -detects will be replaced with one half the reporting limit prior to performing the normality test and constructing the confidence limit. Per .1634(g)(5), if background (statistical limit based on upgradient well data) is higher than the 2L Standard, then background may be utilized as the GWPS. Background for organics is considered the non - detect level (equivalent to the PQL). Organic concentrations detected above PQLs and GWPSs (See Table 2) were statistically compared to their respective GWPSs utilizing intra-well lower confidence limits. As provided in Appendix B, benzene at MW-2R statistically exceeded the GWPS for the Second Semi -Annual 2020 event, consistent with recent events. Time series graphs for VOC detections during recent events are provided in Appendix B. 5.4 Statistical Results Summary For the Second Semi -Annual 2020 event, one inorganic statistically significant increase was exhibited for the groundwater monitoring wells: cobalt at MW-4. The Second Semi -Annual 2020 concentration of total cobalt at MW-4 (15.1 ug/L) was above the background inter -well prediction limit based on pooled data from upgradient wells MW-1, MW-1 R, and MW-1 R2 (10 ug/L, which is equal to the PQL). However, cobalt concentrations at MW-4 have been slowly decreasing since the July 2012 event (25.4 ug/L), with the Second Semi -Annual 2020 concentration at MW-4 being the lowest cobalt reported since 2009. Intra-well lower confidence limits determined benzene at MW-2R (2.1 ug/L) statistically exceeded the GWPS for the Second Semi -Annual 2020 event, consistent with recent events. However, benzene concentrations at MW-2R have not increased since the peak concentration in January 2018 (2.6 ug/L). 6.0 CONCLUSIONS For the Second Semi -Annual 2020 event, one inorganic statistically significant increase was confirmed exhibited for the groundwater monitoring wells: cobalt at MW-4, consistent with recent events. One Appendix I constituent (benzene at MW-2R) was confirmed detected above an NC Interim Maximum Allowable Concentration (IMAC) or 2L Standard during the Second Semi -Annual 2020 sampling event. Intra-well lower confidence limits determined benzene at MW-2R statistically exceeded the GWPS for the Second Semi -Annual 2020 event, consistent with recent events. During the Second Semi -Annual 2020 event, no Appendix I VOCs were detected in surface water and underdrain samples at quantifiable concentrations. No quantified detections of Appendix I metals were confirmed to exceed NC 2B Surface Water Standards for surface water points during the Second Semi - Annual 2020 event. Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 6 The Foothills Regional Landfill will continue monitoring in accordance with the requirements for Detection and Assessment Monitoring as outlined in Title 15A NCAC 13B .1633 and .1634, respectively. The next semi-annual event is scheduled for January 2021. 7.0 RECOMMENDATIONS Wells in the proximity of MW-2R exist directly upgradient (MW-9) and directly downgradient (MW-3R2). No VOCs have been confirmed detected at quantified concentrations at MW-9 or MW-3R2; therefore, the extent of quantified VOC detections (i.e. benzene) has been defined to only MW-2R. As described in the site's June 2017 ASD for benzene/vinyl chloride at MW-2R, the VOCs appear to be related to landfill gas. Wells MW-9, MW-2R, and MW-3R2 would effectively cover the exterior perimeter of the cell (1A) suspected as the source of potential gas migration. The site implemented landfill gas extraction and collection upgrades in the Cell 1A area in late 2017 and installed a horizontal landfill gas collection/mitigation trench in the vicinity of MW-2R in Fall 2018. Benzene concentrations at MW-2R have not increased since the peak concentration in January 2018 (2.6 ug/L). An additional event or two of groundwater monitoring is recommended before any further actions to determine if benzene levels at MW- 2R (2.1 ug/L) decrease to levels below the lab PQL (1.0 ug/L) as a result of the landfill gas system upgrades. It is recommended that well MW-4 continues in Detection Monitoring. The drop of cobalt at MW-4 from 25.4 ug/L in July 2012 to 15.1 ug/L during the Second Semi -Annual 2020 event, indicates a slow decreasing trend near the laboratory PQL (10 ug/L). Since the landfill is lined, it is unlikely the cobalt detections are related to a landfill release. The concentrations are expected to naturally attenuate to levels well below background with minimal migration distance. The lack of receptors of water use in this shallow well, which would not feasibly produce a well with sufficient yield for potable use, is evidence of a lack of risk associated with this level of detection. Cobalt is naturally occurring at the site, evident by the historical cobalt detections in various wells across this site, and is a common element occurring naturally in minerals commonly found in the bedrock, soil, and sediments in the North Carolina Piedmont. According to A Geochemical Atlas of North Carolina (by Jeffery C. Reid, dated 1993 in the North Carolina Geological Survey's Bulletin 93), which displays the distribution of cobalt in stream sediments across the state, Caldwell County has been highlighted. Cobalt was found at concentrations as high as 10 mg/kg throughout Caldwell County; with a significant amount of variability. Metals in the soil and bedrock can easily leach into the groundwater, especially if the groundwater is acidic (pH < 7.0). The pH of groundwater samples from the Foothills Landfill during the Second Semi -Annual 2020 sampling event ranged from 5.23 to 7.90 SU, and the pH of the sample from MW-4, which had the highest cobalt concentration was 5.23 SU. Review of leachate data for the last 10 years indicates cobalt has ranged from 7.3 to 37.8 ug/L, with an average concentration of 22.3 ug/L. The occurrence and levels of cobalt at the site has no indication of being related to a release from the MSWLF unit. The site recommends utilizing the upcoming First Semi -Annual 2021 (January 2021) event to continue to verify the downward trend of cobalt levels at MW-4 and benzene at MW-2R, since levels are so close to the laboratory PQL of 10 ug/L and 1.0 ug/L, respectively. The proposed actions are protective of human health and the environment and the values at this time do not further action, especially for a naturally occurring element (cobalt). TABLES TABLE 1 GROUNDWATER MONITORING PROGRAM SECOND SEMI-ANNUAL 2020 EVENT FOOTHILLS REGIONAL LANDFILL UPGRADIENT WELLS DOWNGRADIENT WELLS MW-1 R2 I MW-2R, MW-3R2, MW-4, MW-5, MW-6, MW-7, MW-8, MW-9, MW-10, MW-11 TABLE 2 GROUNDWATER ANALYTICAL DATA SUMMARY SECOND SEMI-ANNUAL 2020 EVENT FOOTHILLS REGIONAL LANDFILL Constituent Units 2L Std IMAC MDL PQL MW-1R2 MW-2R MW-3112 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 Antimony Total u /L NE 1 0.28 6 <6 <6 <6 <6 <6 <6 0.38 J <6 <6 <6 <6 Arsenic Total u /L 10 NE 0.78 10 <10 0.92 J 1.8 J <10 0.99 J <10 0.95 J 0.9 J 1.1 J <10 <10 Barium Total u /L 700 NE 0.71 100 41.4 J 265 5.2 J 43.4 J 122 126 38.2 J 34 J 8.7 J 25.8 J 59.1 J Beryllium Total u /L NE 4 0.046 1 <1 0.13 J <1 0.076 J 0.066 J 0.3 J 0.15 J 0.17 J <1 <1 <1 Cadmium Total u /L 2 NE 0.12 1 <1 <1 <1 <1 <1 0.14 J <1 <1 <1 <1 <1 Chromium Total u /L 10 NE 0.55 10 <10 <10 1.4 J I <10 1.1 J <10 1.2 J <10 <10 1 J <10 Cobalt Total u /L NE 1 0.38 10 <10 <10 <10 15.1 <10 <10 <10 <10 <10 Copper Total u /L 1,000 NE 1.7 10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Lead Total u /L 15 NE 0.036 10 <10 <10 0.19 J <10 <10 0.09 J 0.038 J 0.096 J <10 0.17 J <10 Nickel Total u /L 100 NE 0.69 50 <50 <50 <50 <50 <50 <50 <50 0.91 J <50 <50 <50 Selenium Total u /L 20 NE 1.6 10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Silver Total u /L 20 NE 0.36 10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Thallium Total u /L NE 0.28 0.14 5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 Vanadium Total u /L NE 0.3 2.2 25 <25 <25 <25 <25 Zinc Total u /L 1,000 NE 2.2 10 <10 2.2 J <10 3 J t68.7 <10 <10 3.2 J 2.9 J 2.4 J 2.3 J Field H Su NE NE NE NE 6.48 5.66 7.90 5.23 5.60 5.76 5.54 5.95 7.09 7.37 Field Redox mV NE NE NE NE 37.7 78.9 -29.1 100.481.6 73.2 84.5 63.1 4.8 -9.2 Field S ecific Conductance umhos/cm NE NE NE NE 71.5 135.7 268.0 34.1 177.5 121.8 76.4 160.3 59.6 54.5 Field Temperature °C NE NE NE NE 17.3 20.1 20.2 19.9 1 20.2 19.3 19.1 20.2 18.4 1 16.0 15.9 Field TurbidityNTU NE NE NE NE 0.92 0.12 1.67 0.15 0.18 3.72 3.08 6.88 0.72 2.45 0.10 Benzene u /L 1 1 NE 0.15 1 <1 2.1 <1 <1 0.52 J <1 <1 <1 <1 <1 I <1 For VOCs, only constituents with one or more detections above a PQL are included on table. NE: Denotes a NC 2L or IMAC Standard is not established. J: Denotes Sample result above the MDL but below the PQL; estimated value; value may not be accurate. Denotes a concentration at or above a PQL is also above a NC 2L Standard: Denotes a concentration at or above a PQL is also above a NC IMAC Standard: Denotes a concentration is above a NC 2L or IMAC Standard, but but below the PQL: TABLE 3 SURFACE WATER ANALYTICAL DATA SUMMARY SECOND SEMI-ANNUAL 2020 EVENT FOOTHILLS REGIONAL LANDFILL Constituent Units NC 2B Std MDL PQL SW-1 SW-2 SW-3 SW-4 SW-5 Antimony Total u /L 640 0.28 6 <6 <6 1.7 J 0.58 J 0.54 J Arsenic Total u /L 10 0.78 10 <10 <10 <10 <10 <10 Barium Total u /L 21,000 0.71 100 19.1 J 31 J 28.2 J 29.1 J 27.5 J Beryllium Total ug/L 6.5 0.046 1 <1 0.073 J 0.068 J 0.072 J 0.14 J Cadmium Total u /L NE 0.12 1 <1 <1 <1 <1 <1 Chromium Total u /L NE 0.55 10 0.61 J 1.2 J 1.5 J 1.6 J 2 J Cobalt Total u /L 4 0.38 10 0.53 J 0.96 J 0.72 J 0.74 J 3.3 J Copper Total u /L NE 1.7 10 <10 <10 <10 <10 1.9 J Lead Total u /L NE 0.036 10 0.24 J 0.51 J 0.62 J 0.68 J 1.6 J Nickel Total u /L NE 0.69 50 <50 <50 0.82 J 0.79 J 1.4 J Selenium Total u /L 5 1.6 10 <10 <10 <10 <10 <10 Silver Total u /L 0.06 0.36 10 <10 <10 <10 <10 <10 Thallium Total u /L 0.47 0.14 5.5 <5.5 <5.5 <5.5 <5.5 <5.5 Vanadium Total ug/L NE 2.2 25 3 J <25 3 J 3.3 J 4.4 J Zinc Total ug/L NE 2.2 10 <10 5.1 J 3.8 J 3.9 J 6 J Field pH SU NE NE NE 6.4 6.36 7.48 7.42 7.01 Field Redox mV NE NE NE 41.6 43.2 -15.8 -12.4 8.9 Field Specific Conductance umhos/cm NE NE NE 55.6 82.7 64.6 66.7 95.5 Field Temperature I °CI NE NE I NE 1 23.9 1 24.3 23.8 25.1 1 26.2 Field Turbidity I NTU I NE I NE I NE 1 9.88 1 12.2 9.72 1 15.7 1 78.7 J: Denotes sample result above the MDL but below the PQL; estimated value; value may not be accurate. NE: Denotes a NC 2B Standard is not established. No VOCs detected above a PQL, therefore not included on this table. Denotes a concentration at or above a PQL is also above the NC 2B Standard: Denotes a concentration is above the NC 2B Standard, but but below the PQL: TABLE 4 UNDERDRAIN ANALYTICAL DATA SUMMARY SECOND SEMI-ANNUAL 2020 EVENT FOOTHILLS REGIONAL LANDFILL Constituent Units MDL PQL UD-1 UD-2 Antimony Total ug/L 0.28 6 <6 <6 Arsenic Total ug/L 0.78 10 <10 <10 Barium Total ug/L 0.71 100 74.6 J 62.9 J Beryllium Total ug/L 0.046 1 0.08 J 0.064 J Cadmium Total ug/L 0.12 1 <1 <1 Chromium Total ug/L 0.55 10 0.64 J 0.62 J Cobalt Total ug/L 0.38 10 7.9 J 6.5 J Copper Total ug/L 1.7 10 <10 <10 Lead Total ug/L 0.036 10 0.5 J 0.28 J Nickel Total ug/L 0.69 50 1.4 J 1.1 J Selenium Total ug/L 1.6 10 <10 <10 Silver Total ug/L 0.36 10 <10 <10 Thallium Total ug/L 0.14 5.5 <5.5 <5.5 Vanadium Total ug/L 2.2 25 <25 <25 Zinc Total ug/L 2.2 10 4.4 J 2.8 J Field pH SU NE NE 5.84 5.72 Field Redox mV NE NE 70.1 74.2 Field Specific Conductance umhos/cm NE NE 218 210 Field Temperature °C NE NE 25.1 23.9 Field Turbidity NTU NE NE 19.7 8.02 J: Denotes sample result above the MDL but below the PQL; estimated value; value may not be accurate. No VOCs detected above a PQL, therefore not included on this table. NE: Not established. TABLE 5 LEACHATE ANALYTICAL DATA SUMMARY SECOND SEMI-ANNUAL 2020 EVENT FOOTHILLS REGIONAL LANDFILL Indicator Parameters Units MDL PQL Leachate Antimony u /L 1.4 30 13.4 J Arsenic ug/L 3.9 50 31.1 J Barium u /L 3.6 500 66.9 J Beryllium ug/L 0.23 5 <5 BOD, 5 day u /L 2000 2000 239000 Cadmium ug/L 0.59 5 <5 Chemical Oxygen Demand u /L 250000 500000 3600000 Chromium ug/L 2.8 50 104 Cobalt u /L 1.9 50 7.3 J Copper ug/L 8.5 50 <50 Lead u /L 0.18 50 0.51 J Nickel ug/L 3.5 250 52.2 J Nitrogen, Ammonia u /L 17500 25000 1710000 Nitrogen, Nitrate ug/L 80 200 <200 Nitrogen, Nitrate & Nitrite u /L 80 200 285 Nitrogen, Nitrite ug/L 90 200 222 Phosphorus u /L 125 250 9400 Selenium ug/L 7.8 50 <50 Silver u /L 1.8 50 <50 Sulfate u /L 25000 50000 <50000 Thallium u /L 0.72 27.5 <27.5 Vanadium ug/L 10.8 125 23.8 J Zinc u /L 11.1 50 36.8 J Field pH SU NE NE 8.02 Field Specific Conductance umhos/cm NE NE 23,700 Field Temperature °C NE NE 29.2 Field Turbidity NTU NE NE 39.8 Volatile Organic Compounds (VOCs) Units MDL PQL Leachate 1,4-Dichlorobenzene u /L 0.26 1 3.6 2-Butanone ug/L 3.3 100 262 Acetone u /L 6.2 100 322 Benzene ug/L 0.15 1 3 Eth (benzene u /L 0.26 1 19.6 Toluene ug/L 0.24 1 7.4 X lenes, Total u /L 0.63 5 27.8 Metals reported at Total. For VOCs, only constituents with detections above a PQL are included on table. J: Denotes Sample result above the MDL but below the PQL; estimated value; value may not be accurate. APPENDICES APPENDIX A POTENTIOMETRIC SURFACE MAP NORTH 0 100 200 400 &SW-1 M6/ M W-8 164.72 \MW-7A 1 1153q�619� IDtll �J MW-6 1136.13 I 1 I MW-5_ 1128.49= a I �M\N • 1129.: :11 Scale in Feet Graphic Scale: 1 inch = 400 feet ,i Q 'TING NO. SA \ ppd� ,rEXISTING p ,c,ELL NO. 111 JJJ 1 W l MW-11 ��t \ t 1319.09 J. EXISTI CELL NO. (UNDE ) r� sTRuc IONS NW-10 128142 J �eo X IN ^ CEL . 1 I `� f I, MW-9 ' 111 � 1189.91 --�_ BMW-3R2 MW-3R ,Zoo --�_ / 1202.04 m 1185.45.' SSW-4 LEGEND 1 SMW-7 Monitoring Well Location y) SUD-1 Underdrain Location 1153.69 Groundwater Elevation (fmsl) —1300— Potentiometric Surface Contour (fmsl) Hydraulic Gradient & Inferred Groundwater Flow Direction SW-1 Surface Water Sampling Location (Approx) Landfill Cell Boundary Water levels collected by Environmental Sampling & Services, Inc. on July 27, 2020. Basemap provided by Joyce Engineering, with topographic survey completed by Cooper Aerial Surveys Co., date of Photography is January 20, 2014. JETT ENVIRONMENTAL C O N S U L T I N G Figure 1 1002 Morgan Meadow Drive July 2020 Event, Potentiometric Surface Map Wentzville, MO 63385 314-496-4654 www.jettenviro.com Foothills Regional Landfill, Caldwell County, North Carolina Groundwater Flow Velocity Calculations Foothills Regional Landfill Second Semi -Annual 2020 Event Velocity V = [(k)(i)]/(n) V = [(0.374 ft/day)(0.1292 ft/ft)] / 0.1 V = 0.483 ft/day V = 176 ft/year Where, Hydraulic conductivity (k) and effective porosity (n) values from the following document: Table 2 of the Second SemiAnnual Water Quality Monitoring Report of 2017, dated November 17, 2017 by Joyce Engineering. Gradient (i) is from the average gradient at site using the potentiometric surface map from Point A to Point B. Gradient (i) = Change in Groundwater Elevation along Flow Path is From Point A (1500 contour) to Point 8 (1150 contour) = 350 ft / 2,710 ft = 0.1292 ft/ft Groundwater Elevation Summary Table Foothills Regional Landfill Well Top of PVC Casing Elevation (fmsl)' 2 Depth to Water (ft) Groundwater Elevation (fmsl) MW-1 R2 1516.22 15.10 1501.12 MW-2R 1253.36 48.41 1204.95 MW-3 1241.95 52.04 1189.91 MW-3R 1242.69 57.24 1185.45 MW-3R2 1240.83 38.79 1202.04 MW-4 1171.18 41.79 1129.39 MW-5 1175.07 46.58 1128.49 MW-6 1176.82 40.69 1136.13 MW-7 1183.13 29.44 1153.69 MW-8 1195.18 30.46 1164.72 MW-9 1290.79 68.44 1222.35 MW-10 1358.53 77.11 1281.42 MW-11 1401.71 82.62 1319.09 Note 1: Top of PVC Casing Elevations from Table 1 of the Water Quality Monitoring Plan dated March 20, 2019 by BLE. Note 2: Depth to water measured by Environmental Sampling & Services, Inc. on July 27, 2020. APPENDIX B STATISTICAL EVALUATIONS Prediction Limit Foothills Client: RSI Data: Foothills Printed 10/1/2020, 2:27 PM Constituent Well Uooer Lim. Lower Lim. Date Observ. Sic. Ba N Ba Mean Std. Dev. %NDs NDAd. Transform Aloha Method Cobalt Total (ug/L) MW-4 10.0 n/a 7/27/2020 15.1 Yes 48 n/a n/a 93.75 n/a n/a 0.0008339 NP Inter (NDs) 1 of 2 Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Exceeds Limit: MW-4 30 24 18 12 A 0 4- 7/19/99 Prediction Limit Interwell Non -parametric 10/1 /03 12/15/07 2/28/12 5/13/16 7/27/20 ♦ MW-4 Limit = 10.0 Non -parametric test used in lieu of parametric prediction limit because censored data exceeded 50%. Limit is highest of 48 background values. 93.75% NDs. Annual per -constituent alpha = 0.001667. Individual comparison alpha = 0.0008339 (1 of 2). After outlier removal distribution was non -normal, so outlier results were invalidated. Constituent: Cobalt Total Analysis Run 10/1/2020 2:26 PM Foothills Client: RSI Data: Foothills Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Parametric Confidence Interval Compliance limit is exceeded. Per -well alpha = 0.01. Normality Test: Shapiro Wilk, alpha based on n. 4 3.2 2.4 1.6 J 0.8 111 Limal­1_____ ->4� Constituent: Benzene Analysis Run 10/1/2020 2:37 PM Foothills Client: RSI Data: Foothills Confidence Interval Constituent: Benzene (ug/L) Analysis Run 10/1/2020 2:37 PM Foothills Client: RSI Data: Foothills MW-2R 1 /28/2019 1.6 7/25/2019 1.8 1/27/2020 2.2 7/27/2020 2.1 Mean 1.925 Std. Dev. 0.2754 Upper Lim. 2.55 Lower Lim. 1.3 TIME SERIES TREND ANALYSIS Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 6 4.8 3.6 J 0) Z3 2.4 1.2 0 1 /6/09 Time Series 4/30/11 8/21 /13 12/13/15 4/5/18 7/27/20 Constituent: Antimony Total Analysis Run 10/1/2020 2:32 PM Foothills Client: RSI Data: Foothills f MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 Ivl vv-y MW-11 MW-1 R2 (bg) Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 20 16 12 0) N"`v�7 Z3 77 M 8 4 Ilk 0 8/10/98 12/31 /02 5/23/07 10/14/11 3/5/16 7/27/20 Constituent: Arsenic Total Analysis Run 10/1/2020 2:32 PM Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 r Ivlvv-y ♦ MW-11 ♦ MW-1 R2 (bg) Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 700 560 420 J 280 140 Time Series 12/31 /02 5/23/07 10/14/11 3/5/16 7/27/20 Constituent: Barium Total Analysis Run 10/1/2020 2:32 PM Foothills Client: RSI Data: Foothills f MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 Ivl vv-y MW-11 MW-1 R2 (bg) Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 3 2.4 1.8 J 1.2 0.6 Time Series 12/31 /02 5/23/07 10/14/11 3/5/16 7/27/20 Constituent: Beryllium Total Analysis Run 10/1/2020 2:32 PM Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 Ivl vv-y MW-11 MW-1 R2 (bg) Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 5 4 3 J 2 0 8/10/98 12/31 /02 5/23/07 10/14/11 3/5/16 7/27/20 Constituent: Cadmium Total Analysis Run 10/1/2020 2:32 PM Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 Ivl vv-y ♦ MW-11 ♦ MW-1 R2 (bg) Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 40 32 24 J 16 8 Time Series 8/10/98 12/31 /02 5/23/07 10/14/11 3/5/16 7/27/20 Constituent: Chromium Total Analysis Run 10/1/2020 2:32 PM Foothills Client: RSI Data: Foothills f MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 Ivl vv-y MW-11 MW-1 R2 (bg) Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 30 24 18 J 12 6 0 4- 8/10/98 Time Series 12/31 /02 5/23/07 10/14/11 3/5/16 7/27/20 Constituent: Cobalt Total Analysis Run 10/1/2020 2:32 PM Foothills Client: RSI Data: Foothills f MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 Ivl vv-y MW-11 MW-1 R2 (bg) Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 500 400 300 J 0) Z3 200 100 0 8/10/98 12/31 /02 5/23/07 10/14/11 3/5/16 7/27/20 Constituent: Copper Total Analysis Run 10/1/2020 2:32 PM Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 ♦ MW-11 ♦ MW-1 R2 (bg) Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 30 24 18 J 12 6 Time Series 1 r. 771 8/10/98 12/31 /02 5/23/07 10/14/11 3/5/16 7/27/20 Constituent: Lead Total Analysis Run 10/1/2020 2:32 PM Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 ♦ MW-11 ♦ MW-1 R2 (bg) SanitasTM v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 50 777 7 7 40 - 30 J 20 10 0 1 •: 12/31 /02 5/23/07 10/14/11 3/5/16 7/27/20 Constituent: Nickel Total Analysis Run 10/1/2020 2:32 PM Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) r MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 MW-6 MW-7 M W-8 lvl vv-y ♦ MW-11 ♦ MW-1 R2 (bg) Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 30 24 18 J 12 6 0 4- 8/10/98 Time Series 12/31 /02 5/23/07 10/14/11 3/5/16 7/27/20 Constituent: Selenium Total Analysis Run 10/1/2020 2:32 PM Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 ♦ MW-11 ♦ MW-1 R2 (bg) Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 50 40 30 J 20 10 0 4- 8/10/98 Time Series 12/31 /02 5/23/07 10/14/11 3/5/16 7/27/20 Constituent: Silver Total Analysis Run 10/1/2020 2:32 PM Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 Ivl vv-y ♦ MW-11 ♦ MW-1 R2 (bg) Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 8/10/98 Time Series 12/31 /02 5/23/07 10/14/11 3/5/16 7/27/20 Constituent: Thallium Total Analysis Run 10/1/2020 2:32 PM Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 Ivl vv-y ♦ MW-11 ♦ MW-1 R2 (bg) Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 60 48 36 J 24 12 Time Series 12/31 /02 5/23/07 10/14/11 3/5/16 7/27/20 Constituent: Vanadium Total Analysis Run 10/1/2020 2:32 PM Foothills Client: RSI Data: Foothills f MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 Ivl vv-y MW-11 MW-1 R2 (bg) Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 200 160 120 J 80 40 8/10/98 Time Series 12/31 /02 5/23/07 10/14/11 3/5/16 7/27/20 Constituent: Zinc Total Analysis Run 10/1/2020 2:32 PM Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 MW-11 MW-1 R2 (bg) Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 5 4 3 J 0) 2 1 0 1 /6/09 4/30/11 8/21 /13 12/13/15 4/5/18 7/27/20 Constituent: 11-Dichloroethane Analysis Run 10/1/2020 2:34 PM Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 Ivl vv-y ♦ MW-11 ♦ MW-1 R2 (bg) Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 5 4--7 3 J 2 1 - LjLj 0 8/10/98 12/31 /02 5/23/07 10/14/11 3/5/16 7/27/20 Constituent: Benzene Analysis Run 10/1/2020 2:34 PM Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 r Ivlvv-y ♦ MW-11 ♦ MW-1 R2 (bg) Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 5--�-��. 4 3 �77 i J Z3 2 — 1 0 — 1 /6/09 4/30/11 8/21 /13 12/13/15 4/5/18 7/27/20 Constituent: cis- 1 2-Dich loroethene Analysis Run 10/1/2020 2:34 PM Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 Ivl vv-y ♦ MW-11 ♦ MW-1 R2 (bg) Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 5 4--7 j 3 J 2 1SnALfi 0 8/10/98 12/31 /02 5/23/07 10/14/11 3/5/16 7/27/20 Constituent: Tetrachloroethene Analysis Run 10/1/2020 2:34 PM Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 Ivl vv-y ♦ MW-11 ♦ MW-1 R2 (bg) Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 0 1 /6/09 ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 MW-7 MW-8 4/30/11 8/21 /13 12/13/15 4/5/18 7/27/20 Constituent: Toluene Analysis Run 10/1/2020 2:34 PM Foothills Client: RSI Data: Foothills ♦ MW-11 ♦ MW-1 R2 (bg) Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 2 1.6 1.2 J 0.8 0.4 0 4- 1 /6/09 Time Series 4/30/11 8/21 /13 12/13/15 4/5/18 7/27/20 Constituent: Trichloroethene Analysis Run 10/1/2020 2:34 PM Foothills Client: RSI Data: Foothills f MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 Ivl vv-y MW-11 MW-1 R2 (bg) Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 2 1.6 1.2 J 0.8 0.4 0 4- 1 /6/09 Time Series 4/30/11 8/21 /13 12/13/15 4/5/18 7/27/20 Constituent: Vinyl chloride Analysis Run 10/1/2020 2:34 PM Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 Ivl vv-y MW-11 MW-1 R2 (bg) Sanitas" v.9.6.27 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 5 ' 4 3 J 2 1 0 1 /6/09 4/30/11 8/21 /13 12/13/15 4/5/18 7/27/20 Constituent: Xylenes [Total] Analysis Run 10/1/2020 2:34 PM Foothills Client: RSI Data: Foothills MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 Ivlvv-y ♦ MW-11 ♦ MW-1 R2 (bg) APPENDIX C LABORATORY ANALYTICAL REPORTS FIELD SAMPLING FORMS leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 September 29, 2020 Environmental Manager Foothills Environmental Landfill 2800 Cheraw Road Lenoir, NC 28645 RE: Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Dear Environmental Manager: Enclosed are the analytical results for sample(s) received by the laboratory on July 28, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Charlotte • Pace Analytical Services - Peachtree Corners, GA This replaces the August 6, 2020 final report. Due system error, this report was reissued to update sample 92487992 -004 reporting limits per historical limits. If you have any questions concerning this report, please feel free to contact me. Sincerely, Maiya Parks maiya.parks@pacelabs.com (770)734-4200 Project Manager Enclosures cc: Data Manager, TriHydro Corporation REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 99 lacmnalyfica(' www,pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Peachtree Corners 110 Technology Pkwy, Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 Georgia DW Microbiology Certification #: 812 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Certification #: 381 South Carolina Certification #: 98011001 Virginia Certification #: 460204 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Lab ID Sample ID Matrix Date Collected Date Received 92487992001 1403-MW-1 R2 Water 07/27/20 08:42 07/28/20 11:50 92487992002 1403-MW-2R Water 07/27/2016:00 07/28/20 11:50 92487992003 1403-MW-3R2 Water 07/27/2014:47 07/28/20 11:50 92487992004 1403-MW-4 Water 07/27/2013:29 07/28/20 11:50 92487992005 1403-Dup@MW-2R Water 07/27/2016:02 07/28/20 11:50 92487992006 1403-MW-5 Water 07/27/2012:42 07/28/20 11:50 92487992007 1403-MW-6 Water 07/27/2011:55 07/28/20 11:50 92487992008 1403-MW-7 Water 07/27/2010:50 07/28/20 11:50 92487992009 1403-MW-8 Water 07/27/2010:01 07/28/20 11:50 92487992010 1403-MW-9 Water 07/27/20 07:49 07/28/20 11:50 92487992011 1403-MW-10 Water 07/27/20 07:01 07/28/20 11:50 92487992012 1403-MW-11 Water 07/27/20 06:12 07/28/20 11:50 92487992013 1403-Field Blank Water 07/26/20 15:15 07/28/20 11:50 92487992014 1403-SW 1 Water 07/27/20 09:10 07/28/20 11:50 92487992015 1403-SW 2 Water 07/27/20 13:56 07/28/20 11:50 92487992016 1403-SW 3 Water 07/26/20 16:12 07/28/20 11:50 92487992017 1403-SW 4 Water 07/26/20 15:50 07/28/20 11:50 92487992018 1403-SW 5 Water 07/26/20 15:28 07/28/20 11:50 92487992019 1403-UD 1 Water 07/27/20 13:40 07/28/20 11:50 92487992020 1403-UD 2 Water 07/27/20 11:05 07/28/20 11:50 92487992021 1403-Trip Blank Water 07/26/20 15:18 07/28/20 11:50 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Foothills LF/Semi-Annual-Revised Report 92487992 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92487992001 1403-MW-1R2 EPA6020B CW1 15 PASI-GA EPA 8260D SAS 50 PASI-C 92487992002 1403-MW-2R EPA6020B CW1 15 PASI-GA EPA 8260D SAS 50 PASI-C 92487992003 1403-MW-3R2 EPA6020B CW1 15 PASI-GA EPA 8260D SAS 50 PASI-C 92487992004 1403-MW-4 EPA6020B CW1 15 PASI-GA EPA 8260D SAS 50 PASI-C 92487992005 1403-Dup@MW-2R EPA6020B CW1 15 PASI-GA EPA 8260D SAS 50 PASI-C 92487992006 1403-MW-5 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92487992007 1403-MW-6 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92487992008 1403-MW-7 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92487992009 1403-MW-8 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92487992010 1403-MW-9 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92487992011 1403-MW-10 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92487992012 1403-MW-11 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92487992013 1403-Field Blank EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92487992014 1403-SW 1 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92487992015 1403-SW2 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92487992016 1403-SW 3 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92487992017 1403-SW4 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92487992018 1403-SW 5 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92487992019 1403-UD 1 EPA6020B CW1 15 PASI-GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 8260D CL 50 PASI-C 92487992020 1403-UD2 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92487992021 1403-Trip Blank EPA 8260D GAW 50 PASI-C PASI-C = Pace Analytical Services - Charlotte PASI-GA = Pace Analytical Services - Peachtree Corners, GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: Foothills LF/Semi-Annual-Revised Report 92487992 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92487992001 1403-MW-1 R2 pH 6.48 Std. Units 07/27/20 08:42 Temperature 17.3 deg C 07/27/20 08:42 Static Water Level 15.27 feet 07/27/20 08:42 Specific Conductance 71.5 umhos/cm 07/27/20 08:42 Oxidation Potential 37.7 mV 07/27/20 08:42 Oxygen, Dissolved 1.32 mg/L 07/27/20 08:42 Turbidity 0.92 NTU 07/27/20 08:42 EPA 6020B Barium 41 AJ ug/L 100 07/31/20 20:24 92487992002 1403-MW-2R pH 5.66 Std. Units 07/27/20 16:00 Temperature 20.1 deg C 07/27/20 16:00 Static Water Level 48.69 feet 07/27/20 16:00 Specific Conductance 135.7 umhos/cm 07/27/20 16:00 Oxidation Potential 78.9 mV 07/27/20 16:00 Oxygen, Dissolved 2.12 mg/L 07/27/20 16:00 Turbidity 0.12 NTU 07/27/20 16:00 EPA 6020B Arsenic 0.92J ug/L 10.0 07/31/20 20:30 EPA 6020B Barium 265 ug/L 100 07/31/20 20:30 EPA 6020B Beryllium 0.13J ug/L 1.0 07/31/20 20:30 EPA 6020B Vanadium 2.6J ug/L 25.0 07/31/20 20:30 EPA 6020B Zinc 2.2J ug/L 10.0 07/31/20 20:30 EPA 8260D Benzene 2.1 ug/L 1.0 07/30/20 02:07 EPA 8260D 1,1-Dichloroethane 1.1J ug/L 5.0 07/30/20 02:07 EPA 8260D cis-1,2-Dichloroethene 3AJ ug/L 5.0 07/30/20 02:07 EPA 8260D Tetrachloroethene 0.64J ug/L 1.0 07/30/20 02:07 EPA 8260D Trichloroethene 0.49J ug/L 1.0 07/30/20 02:07 EPA 8260D Vinyl chloride 0.66J ug/L 1.0 07/30/20 02:07 92487992003 1403-MW-3R2 pH 7.90 Std. Units 07/27/20 14:47 Temperature 20.2 deg C 07/27/20 14:47 Static Water Level 39.18 feet 07/27/20 14:47 Specific Conductance 268 umhos/cm 07/27/20 14:47 Oxidation Potential -29.1 mV 07/27/20 14:47 Oxygen, Dissolved 3.25 mg/L 07/27/20 14:47 Turbidity 1.67 NTU 07/27/20 14:47 EPA 6020B Arsenic 1.8J ug/L 10.0 07/31/20 20:47 EPA 6020B Barium 5.2J ug/L 100 07/31/20 20:47 EPA 6020B Chromium 1 AJ ug/L 10.0 07/31/20 20:47 EPA 6020B Lead 0.191 ug/L 10.0 07/31/20 20:47 EPA 6020B Vanadium 5.1 J ug/L 25.0 07/31/20 20:47 EPA 8260D Trichlorofluoromethane 0.35J ug/L 1.0 07/30/20 02:24 92487992004 1403-MW-4 pH 5.23 Std. Units 07/27/20 13:29 Temperature 19.9 deg C 07/27/20 13:29 Static Water Level 41.93 feet 07/27/20 13:29 Specific Conductance 34.1 umhos/cm 07/27/20 13:29 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92487992004 1403-MW-4 Oxidation Potential 100.4 mV 07/27/20 13:29 Oxygen, Dissolved 1.35 mg/L 07/27/20 13:29 Turbidity 0.15 NTU 07/27/20 13:29 EPA 6020B Barium 43AJ ug/L 100 07/31/20 20:53 EPA 6020B Beryllium 0.076J ug/L 1.0 07/31/20 20:53 EPA 6020B Cobalt 15.1 ug/L 10.0 07/31/20 20:53 EPA 6020B Vanadium 2.3J ug/L 25.0 07/31/20 20:53 EPA 6020B Zinc 3.OJ ug/L 10.0 07/31/20 20:53 92487992005 1403-Dup@MW-2R EPA 6020B Antimony 1.1J ug/L 6.0 07/31/20 21:16 EPA 6020B Arsenic 1.0J ug/L 10.0 07/31/20 21:16 EPA 6020B Barium 121 ug/L 100 07/31/20 21:16 EPA 6020B Beryllium 0.070J ug/L 1.0 07/31/20 21:16 EPA 6020B Chromium 1.2J ug/L 10.0 07/31/20 21:16 EPA 6020B Vanadium 4.6J ug/L 25.0 07/31/20 21:16 EPA 6020B Zinc 2.3J ug/L 10.0 07/31/20 21:16 EPA 8260D Benzene 2.0 ug/L 1.0 07/30/20 03:00 EPA 8260D 1,1-Dichloroethane 1.1J ug/L 5.0 07/30/20 03:00 EPA 8260D cis-1,2-Dichloroethene 3AJ ug/L 5.0 07/30/20 03:00 EPA 8260D Tetrachloroethene 0.65J ug/L 1.0 07/30/20 03:00 EPA 8260D Trichloroethene 0.51 J ug/L 1.0 07/30/20 03:00 EPA 8260D Vinyl chloride 0.75J ug/L 1.0 07/30/20 03:00 92487992006 1403-MW-5 pH 5.85 Std. Units 07/27/20 12:42 Temperature 20.2 deg C 07/27/20 12:42 Static Water Level 46.75 feet 07/27/20 12:42 Specific Conductance 188.1 umhos/cm 07/27/20 12:42 Oxidation Potential 68.7 mV 07/27/20 12:42 Oxygen, Dissolved 2.30 mg/L 07/27/20 12:42 Turbidity 0.18 NTU 07/27/20 12:42 EPA 6020B Arsenic 0.991 ug/L 10.0 07/31/20 21:21 EPA 6020B Barium 122 ug/L 100 07/31/20 21:21 EPA 6020B Beryllium 0.066J ug/L 1.0 07/31/20 21:21 EPA 6020B Chromium 1.1J ug/L 10.0 07/31/20 21:21 EPA 6020B Vanadium 4.8J ug/L 25.0 07/31/20 21:21 EPA 8260D Benzene 0.52J ug/L 1.0 07/29/20 15:59 EPA 8260D 1,2-Dichloroethane 0.39J ug/L 1.0 07/29/2015:59 EPA 8260D cis-1,2-Dichloroethene 1.2J ug/L 5.0 07/29/2015:59 92487992007 1403-MW-6 pH 5.60 Std. Units 07/27/20 11:55 Temperature 19.3 deg C 07/27/20 11:55 Static Water Level 40.81 feet 07/27/20 11:55 Specific Conductance 177.5 umhos/cm 07/27/20 11:55 Oxidation Potential 81.6 mV 07/27/20 11:55 Oxygen, Dissolved 1.85 mg/L 07/27/20 11:55 Turbidity 3.72 NTU 07/27/20 11:55 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: Foothills LF/Semi-Annual-Revised Report 92487992 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92487992007 1403-MW-6 EPA 6020B Barium 126 ug/L 100 07/31/20 21:27 EPA 6020B Beryllium 0.30J ug/L 1.0 07/31/20 21:27 EPA 6020B Cadmium 0.14J ug/L 1.0 07/31/20 21:27 EPA 6020B Cobalt 8AJ ug/L 10.0 07/31/20 21:27 EPA 6020B Lead 0.0901 ug/L 10.0 07/31/20 21:27 92487992008 1403-MW-7 pH 5.76 Std. Units 07/27/20 10:50 Temperature 19.1 deg C 07/27/20 10:50 Static Water Level 29.55 feet 07/27/20 10:50 Specific Conductance 121.8 umhos/cm 07/27/20 10:50 Oxidation Potential 73.2 mV 07/27/20 10:50 Oxygen, Dissolved 5.08 mg/L 07/27/20 10:50 Turbidity 3.08 NTU 07/27/20 10:50 EPA 6020B Antimony 0.38J ug/L 6.0 07/31/20 21:33 EPA 6020B Arsenic 0.95J ug/L 10.0 07/31/20 21:33 EPA 6020B Barium 38.2J ug/L 100 07/31/20 21:33 EPA 6020B Beryllium 0.15J ug/L 1.0 07/31/20 21:33 EPA 6020B Chromium 1.2J ug/L 10.0 07/31/20 21:33 EPA 6020B Lead 0.038J ug/L 10.0 07/31/20 21:33 EPA 6020B Vanadium 3.2J ug/L 25.0 07/31/20 21:33 92487992009 1403-MW-8 pH 5.54 Std. Units 07/27/20 10:01 Temperature 20.2 deg C 07/27/20 10:01 Static Water Level 30.59 feet 07/27/20 10:01 Specific Conductance 76.4 umhos/cm 07/27/20 10:01 Oxidation Potential 84.5 mV 07/27/20 10:01 Oxygen, Dissolved 2.01 mg/L 07/27/20 10:01 Turbidity 6.88 NTU 07/27/20 10:01 EPA 6020B Arsenic 0.901 ug/L 10.0 07/31/20 21:38 EPA 6020B Barium 34.OJ ug/L 100 07/31/20 21:38 EPA 6020B Beryllium 0.17J ug/L 1.0 07/31/20 21:38 EPA 6020B Cobalt 3.8J ug/L 10.0 07/31/20 21:38 EPA 6020B Lead 0.096J ug/L 10.0 07/31/20 21:38 EPA 6020B Nickel 0.91J ug/L 50.0 07/31/20 21:38 EPA 6020B Zinc 3.2J ug/L 10.0 07/31/20 21:38 92487992010 1403-MW-9 pH 5.95 Std. Units 07/27/20 07:49 Temperature 18.4 deg C 07/27/20 07:49 Static Water Level 68.57 feet 07/27/20 07:49 Specific Conductance 160.3 umhos/cm 07/27/20 07:49 Oxidation Potential 63.1 mV 07/27/20 07:49 Oxygen, Dissolved 3.25 mg/L 07/27/20 07:49 Turbidity 0.72 NTU 07/27/20 07:49 EPA 6020B Arsenic 1.1 J ug/L 10.0 07/31/20 21:56 EPA 6020B Barium 8.7J ug/L 100 07/31/20 21:56 EPA 6020B Vanadium 3AJ ug/L 25.0 07/31/20 21:56 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: Foothills LF/Semi-Annual-Revised Report 92487992 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92487992010 1403-MW-9 EPA 6020B Zinc 2.9J ug/L 10.0 07/31/20 21:56 92487992011 1403-MW-10 pH 7.09 Std. Units 07/27/20 07:01 Temperature 16.0 deg C 07/27/20 07:01 Static Water Level 77.31 feet 07/27/20 07:01 Specific Conductance 59.6 umhos/cm 07/27/20 07:01 Oxidation Potential 4.8 mV 07/27/20 07:01 Oxygen, Dissolved 5.90 mg/L 07/27/20 07:01 Turbidity 2.45 NTU 07/27/20 07:01 EPA 6020B Barium 25.8J ug/L 100 07/31/20 22:01 EPA 6020B Chromium 1.0J ug/L 10.0 07/31/20 22:01 EPA 6020B Lead 0.17J ug/L 10.0 07/31/20 22:01 EPA 6020B Vanadium 5.8J ug/L 25.0 07/31/20 22:01 EPA 6020B Zinc 2AJ ug/L 10.0 07/31/20 22:01 92487992012 1403-MW-11 pH 7.37 Std. Units 07/27/20 06:12 Temperature 15.9 deg C 07/27/20 06:12 Static Water Level 82.80 feet 07/27/20 06:12 Specific Conductance 54.5 umhos/cm 07/27/20 06:12 Oxidation Potential -9.2 mV 07/27/20 06:12 Oxygen, Dissolved 1.95 mg/L 07/27/20 06:12 Turbidity 0.10 NTU 07/27/20 06:12 EPA 6020B Barium 59.1 J ug/L 100 07/31/20 22:07 EPA 6020B Zinc 2.3J ug/L 10.0 07/31/20 22:07 92487992014 1403-SW 1 pH 6.40 Std. Units 07/27/20 09:10 Temperature 23.9 deg C 07/27/20 09:10 Specific Conductance 55.6 umhos/cm 07/27/20 09:10 Oxidation Potential 41.6 mV 07/27/20 09:10 Oxygen, Dissolved 4.62 mg/L 07/27/20 09:10 Turbidity 9.88 NTU 07/27/20 09:10 EPA 6020B Barium 19.1 J ug/L 100 07/31/20 22:18 EPA 6020B Chromium 0.61J ug/L 10.0 07/31/20 22:18 EPA 6020B Cobalt 0.53J ug/L 10.0 07/31/20 22:18 EPA 6020B Lead 0.24J ug/L 10.0 07/31/20 22:18 EPA 6020B Vanadium 3.OJ ug/L 25.0 07/31/20 22:18 92487992015 1403-SW 2 pH 6.36 Std. Units 07/27/20 13:56 Temperature 24.3 deg C 07/27/20 13:56 Specific Conductance 82.7 umhos/cm 07/27/20 13:56 Oxidation Potential 43.2 mV 07/27/20 13:56 Oxygen, Dissolved 5.02 mg/L 07/27/20 13:56 Turbidity 12.20 NTU 07/27/20 13:56 EPA 6020B Barium 31.OJ ug/L 100 07/29/20 19:17 EPA 6020B Beryllium 0.073J ug/L 1.0 07/29/20 19:17 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: Foothills LF/Semi-Annual-Revised Report 92487992 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92487992015 1403-SW 2 EPA 6020B Chromium 1.2J ug/L 10.0 07/29/20 19:17 EPA 6020B Cobalt 0.96J ug/L 10.0 07/29/20 19:17 EPA 6020B Lead 0.51 J ug/L 10.0 07/29/20 19:17 EPA 6020B Zinc 5.1 J ug/L 10.0 07/29/20 19:17 92487992016 1403-SW 3 pH 7.48 Std. Units 07/26/20 16:12 Temperature 23.8 deg C 07/26/20 16:12 Specific Conductance 64.6 umhos/cm 07/26/20 16:12 Oxidation Potential -15.8 mV 07/26/20 16:12 Oxygen, Dissolved 5.16 mg/L 07/26/20 16:12 Turbidity 9.72 NTU 07/26/20 16:12 EPA 6020B Antimony 1.7J ug/L 6.0 07/29/20 19:40 EPA 6020B Barium 28.2J ug/L 100 07/29/20 19:40 EPA 6020B Beryllium 0.068J ug/L 1.0 07/29/20 19:40 EPA 6020B Chromium 1.5J ug/L 10.0 07/29/20 19:40 EPA 6020B Cobalt 0.72J ug/L 10.0 07/29/20 19:40 EPA 6020B Lead 0.62J ug/L 10.0 07/29/20 19:40 EPA 6020B Nickel 0.82J ug/L 50.0 07/29/20 19:40 EPA 6020B Vanadium 3.OJ ug/L 25.0 07/29/20 19:40 EPA 6020B Zinc 3.8J ug/L 10.0 07/29/20 19:40 92487992017 1403-SW 4 pH 7.42 Std. Units 07/26/20 15:50 Temperature 25.1 deg C 07/26/20 15:50 Specific Conductance 66.7 umhos/cm 07/26/20 15:50 Oxidation Potential -12.4 mV 07/26/20 15:50 Oxygen, Dissolved 5.06 mg/L 07/26/20 15:50 Turbidity 15.70 NTU 07/26/20 15:50 EPA 6020B Antimony 0.58J ug/L 6.0 07/29/20 19:46 EPA 6020B Barium 29.1 J ug/L 100 07/29/20 19:46 EPA 6020B Beryllium 0.072J ug/L 1.0 07/29/20 19:46 EPA 6020B Chromium 1.6J ug/L 10.0 07/29/20 19:46 EPA 6020B Cobalt 0.74J ug/L 10.0 07/29/20 19:46 EPA 6020B Lead 0.68J ug/L 10.0 07/29/20 19:46 EPA 6020B Nickel 0.79J ug/L 50.0 07/29/20 19:46 EPA 6020B Vanadium 3.3J ug/L 25.0 07/29/20 19:46 EPA 6020B Zinc 3.9J ug/L 10.0 07/29/20 19:46 92487992018 1403-SW 5 pH 7.01 Std. Units 07/26/20 15:28 Temperature 26.2 deg C 07/26/20 15:28 Specific Conductance 95.5 umhos/cm 07/26/20 15:28 Oxidation Potential 8.9 mV 07/26/20 15:28 Oxygen, Dissolved 5.86 mg/L 07/26/20 15:28 Turbidity 78.70 NTU 07/26/20 15:28 EPA 6020B Antimony 0.54J ug/L 6.0 07/29/20 19:52 EPA 6020B Barium 27.5J ug/L 100 07/29/20 19:52 EPA 6020B Beryllium 0.14J ug/L 1.0 07/29/20 19:52 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92487992018 1403-SW 5 EPA 6020B Chromium 2.OJ ug/L 10.0 07/29/20 19:52 EPA 6020B Cobalt 3.3J ug/L 10.0 07/29/20 19:52 EPA 6020B Copper 1.91 ug/L 10.0 07/29/20 19:52 EPA 6020B Lead 1.6J ug/L 10.0 07/29/20 19:52 EPA 6020B Nickel 1 AJ ug/L 50.0 07/29/20 19:52 EPA 6020B Vanadium 4AJ ug/L 25.0 07/29/20 19:52 EPA 6020B Zinc 6.OJ ug/L 10.0 07/29/20 19:52 92487992019 1403-UD 1 pH 5.84 Std. Units 07/27/20 13:40 Temperature 25.1 deg C 07/27/20 13:40 Specific Conductance 218 umhos/cm 07/27/20 13:40 Oxidation Potential 70.1 mV 07/27/20 13:40 Oxygen, Dissolved 4.75 mg/L 07/27/20 13:40 Turbidity 19.70 NTU 07/27/20 13:40 EPA 6020B Barium 74.6J ug/L 100 07/29/20 19:57 EPA 6020B Beryllium 0.080J ug/L 1.0 07/29/20 19:57 EPA 6020B Chromium 0.64J ug/L 10.0 07/29/20 19:57 EPA 6020B Cobalt 7.9J ug/L 10.0 07/29/20 19:57 EPA 6020B Lead 0.501 ug/L 10.0 07/29/20 19:57 EPA 6020B Nickel 1 AJ ug/L 50.0 07/29/20 19:57 EPA 6020B Zinc 4AJ ug/L 10.0 07/29/20 19:57 92487992020 1403-UD 2 pH 5.72 Std. Units 07/27/20 11:05 Temperature 23.9 deg C 07/27/20 11:05 Specific Conductance 210 umhos/cm 07/27/20 11:05 Oxidation Potential 74.2 mV 07/27/20 11:05 Oxygen, Dissolved 4.98 mg/L 07/27/20 11:05 Turbidity 8.02 NTU 07/27/20 11:05 EPA 6020B Barium 62.9J ug/L 100 07/29/20 20:15 EPA 6020B Beryllium 0.064J ug/L 1.0 07/29/20 20:15 EPA 6020B Chromium 0.62J ug/L 10.0 07/29/20 20:15 EPA 6020B Cobalt 6.5J ug/L 10.0 07/29/20 20:15 EPA 6020B Lead 0.28J ug/L 10.0 07/29/20 20:15 EPA 6020B Nickel 1.1 J ug/L 50.0 07/29/20 20:15 EPA 6020B Zinc 2.8J ug/L 10.0 07/29/20 20:15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-MW-1 R2 Lab ID: 92487992001 Collected: 07/27/20 08:42 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte pH 6.48 Std. Units 1 07/27/20 08:42 Temperature 17.3 deg C 1 07/27/20 08:42 Static Water Level 15.27 feet 1 07/27/20 08:42 Specific Conductance 71.5 umhos/c 1 07/27/20 08:42 m Oxidation Potential 37.7 mV 1 07/27/20 08:42 Oxygen, Dissolved 1.32 mg/L 1 07/27/20 08:42 7782-44-7 Turbidity 0.92 NTU 1 07/27/20 08:42 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.28 1 07/28/20 14:30 07/31/20 20:24 7440-36-0 Arsenic ND ug/L 10.0 0.78 1 07/28/20 14:30 07/31/20 20:24 7440-38-2 Barium 41.4J ug/L 100 0.71 1 07/28/20 14:30 07/31/20 20:24 7440-39-3 Beryllium ND ug/L 1.0 0.046 1 07/28/20 14:30 07/31/20 20:24 7440-41-7 Cadmium ND ug/L 1.0 0.12 1 07/28/20 14:30 07/31/20 20:24 7440-43-9 Chromium ND ug/L 10.0 0.55 1 07/28/20 14:30 07/31/20 20:24 7440-47-3 Cobalt ND ug/L 10.0 0.38 1 07/28/20 14:30 07/31/20 20:24 7440-48-4 Copper ND ug/L 10.0 1.7 1 07/28/20 14:30 07/31/20 20:24 7440-50-8 Lead ND ug/L 10.0 0.036 1 07/28/20 14:30 07/31/20 20:24 7439-92-1 Nickel ND ug/L 50.0 0.69 1 07/28/20 14:30 07/31/20 20:24 7440-02-0 Selenium ND ug/L 10.0 1.6 1 07/28/20 14:30 07/31/20 20:24 7782-49-2 Silver ND ug/L 10.0 0.36 1 07/28/20 14:30 07/31/20 20:24 7440-22-4 Thallium ND ug/L 5.5 0.14 1 07/28/20 14:30 07/31/20 20:24 7440-28-0 Vanadium ND ug/L 25.0 2.2 1 07/28/20 14:30 07/31/20 20:24 7440-62-2 Zinc ND ug/L 10.0 2.2 1 07/28/20 14:30 07/31/20 20:24 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 6.2 1 07/30/20 01:49 67-64-1 Acrylonitrile ND ug/L 200 0.90 1 07/30/20 01:49 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/30/20 01:49 71-43-2 Bromochloromethane ND ug/L 3.0 0.34 1 07/30/20 01:49 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/30/20 01:49 75-27-4 Bromoform ND ug/L 3.0 0.62 1 07/30/20 01:49 75-25-2 Bromomethane ND ug/L 10.0 0.62 1 07/30/20 01:49 74-83-9 2-Butanone (MEK) ND ug/L 100 3.3 1 07/30/20 01:49 78-93-3 Carbon disulfide ND ug/L 100 0.40 1 07/30/20 01:49 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/30/20 01:49 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 07/30/20 01:49 108-90-7 Chloroethane ND ug/L 10.0 0.49 1 07/30/20 01:49 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/30/20 01:49 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/30/20 01:49 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.26 1 07/30/20 01:49 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-MW-1 R2 Lab ID: 92487992001 Collected: 07/27/20 08:42 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/29/2020 05:00 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.41 1 07/30/20 01:49 124-48-1 ND ug/L 2.0 0.26 1 07/30/20 01:49 106-93-4 ND ug/L 10.0 0.46 1 07/30/20 01:49 74-95-3 ND ug/L 5.0 0.29 1 07/30/20 01:49 95-50-1 ND ug/L 1.0 0.26 1 07/30/20 01:49 106-46-7 ND ug/L 100 0.54 1 07/30/20 01:49 110-57-6 ND ug/L 5.0 0.27 1 07/30/20 01:49 75-34-3 ND ug/L 1.0 0.34 1 07/30/20 01:49 107-06-2 ND ug/L 5.0 0.24 1 07/30/20 01:49 75-35-4 ND ug/L 5.0 0.29 1 07/30/20 01:49 156-59-2 ND ug/L 5.0 0.25 1 07/30/20 01:49 156-60-5 ND ug/L 1.0 0.19 1 07/30/20 01:49 78-87-5 ND ug/L 1.0 0.30 1 07/30/20 01:49 10061-01-5 ND ug/L 1.0 0.31 1 07/30/20 01:49 10061-02-6 ND ug/L 1.0 0.26 1 07/30/20 01:49 100-41-4 ND ug/L 50.0 0.57 1 07/30/20 01:49 591-78-6 ND ug/L 20.0 12.5 1 07/30/20 01:49 74-88-4 ND ug/L 5.0 3.7 1 07/30/20 01:49 75-09-2 ND ug/L 100 4.5 1 07/30/20 01:49 108-10-1 ND ug/L 1.0 0.27 1 07/30/20 01:49 100-42-5 ND ug/L 5.0 0.34 1 07/30/20 01:49 630-20-6 ND ug/L 3.0 0.22 1 07/30/20 01:49 79-34-5 ND ug/L 1.0 0.16 1 07/30/20 01:49 127-18-4 ND ug/L 1.0 0.24 1 07/30/20 01:49 108-88-3 ND ug/L 1.0 0.18 1 07/30/20 01:49 71-55-6 ND ug/L 1.0 0.24 1 07/30/20 01:49 79-00-5 ND ug/L 1.0 0.22 1 07/30/20 01:49 79-01-6 ND ug/L 1.0 0.31 1 07/30/20 01:49 75-69-4 ND ug/L 1.0 0.35 1 07/30/20 01:49 96-18-4 ND ug/L 50.0 1.4 1 07/30/20 01:49 108-05-4 ND ug/L 1.0 0.24 1 07/30/20 01:49 75-01-4 ND ug/L 5.0 0.63 1 07/30/20 01:49 1330-20-7 102 % 70-130 1 07/30/20 01:49 460-00-4 98 % 70-130 1 07/30/20 01:49 17060-07-0 104 % 70-130 1 07/30/20 01:49 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IL Page 13 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-MW-2R Lab ID: 92487992002 Collected: 07/27/20 16:00 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte pH 5.66 Std. Units 1 07/27/20 16:00 Temperature 20.1 deg C 1 07/27/20 16:00 Static Water Level 48.69 feet 1 07/27/20 16:00 Specific Conductance 135.7 umhos/c 1 07/27/20 16:00 m Oxidation Potential 78.9 mV 1 07/27/20 16:00 Oxygen, Dissolved 2.12 mg/L 1 07/27/20 16:00 7782-44-7 Turbidity 0.12 NTU 1 07/27/20 16:00 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.28 1 07/28/20 14:30 07/31/20 20:30 7440-36-0 Arsenic 0.92J ug/L 10.0 0.78 1 07/28/20 14:30 07/31/20 20:30 7440-38-2 Barium 265 ug/L 100 0.71 1 07/28/20 14:30 07/31/20 20:30 7440-39-3 Beryllium 0.13J ug/L 1.0 0.046 1 07/28/20 14:30 07/31/20 20:30 7440-41-7 Cadmium ND ug/L 1.0 0.12 1 07/28/20 14:30 07/31/20 20:30 7440-43-9 Chromium ND ug/L 10.0 0.55 1 07/28/20 14:30 07/31/20 20:30 7440-47-3 Cobalt ND ug/L 10.0 0.38 1 07/28/20 14:30 07/31/20 20:30 7440-48-4 Copper ND ug/L 10.0 1.7 1 07/28/20 14:30 07/31/20 20:30 7440-50-8 Lead ND ug/L 10.0 0.036 1 07/28/20 14:30 07/31/20 20:30 7439-92-1 Nickel ND ug/L 50.0 0.69 1 07/28/20 14:30 07/31/20 20:30 7440-02-0 Selenium ND ug/L 10.0 1.6 1 07/28/20 14:30 07/31/20 20:30 7782-49-2 Silver ND ug/L 10.0 0.36 1 07/28/20 14:30 07/31/20 20:30 7440-22-4 Thallium ND ug/L 5.5 0.14 1 07/28/20 14:30 07/31/20 20:30 7440-28-0 Vanadium 2.6J ug/L 25.0 2.2 1 07/28/20 14:30 07/31/20 20:30 7440-62-2 Zinc 2.2J ug/L 10.0 2.2 1 07/28/20 14:30 07/31/20 20:30 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 6.2 1 07/30/20 02:07 67-64-1 Acrylonitrile ND ug/L 200 0.90 1 07/30/20 02:07 107-13-1 Benzene 2.1 ug/L 1.0 0.15 1 07/30/20 02:07 71-43-2 Bromochloromethane ND ug/L 3.0 0.34 1 07/30/20 02:07 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/30/20 02:07 75-27-4 Bromoform ND ug/L 3.0 0.62 1 07/30/20 02:07 75-25-2 Bromomethane ND ug/L 10.0 0.62 1 07/30/20 02:07 74-83-9 2-Butanone (MEK) ND ug/L 100 3.3 1 07/30/20 02:07 78-93-3 Carbon disulfide ND ug/L 100 0.40 1 07/30/20 02:07 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/30/20 02:07 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 07/30/20 02:07 108-90-7 Chloroethane ND ug/L 10.0 0.49 1 07/30/20 02:07 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/30/20 02:07 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/30/20 02:07 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.26 1 07/30/20 02:07 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-MW-2R Lab ID: 92487992002 Collected: 07/27/20 16:00 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/29/2020 05:00 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.41 1 07/30/20 02:07 124-48-1 ND ug/L 2.0 0.26 1 07/30/20 02:07 106-93-4 ND ug/L 10.0 0.46 1 07/30/20 02:07 74-95-3 ND ug/L 5.0 0.29 1 07/30/20 02:07 95-50-1 ND ug/L 1.0 0.26 1 07/30/20 02:07 106-46-7 ND ug/L 100 0.54 1 07/30/20 02:07 110-57-6 1.1J ug/L 5.0 0.27 1 07/30/20 02:07 75-34-3 ND ug/L 1.0 0.34 1 07/30/20 02:07 107-06-2 ND ug/L 5.0 0.24 1 07/30/20 02:07 75-35-4 3.4J ug/L 5.0 0.29 1 07/30/20 02:07 156-59-2 ND ug/L 5.0 0.25 1 07/30/20 02:07 156-60-5 ND ug/L 1.0 0.19 1 07/30/20 02:07 78-87-5 ND ug/L 1.0 0.30 1 07/30/20 02:07 10061-01-5 ND ug/L 1.0 0.31 1 07/30/20 02:07 10061-02-6 ND ug/L 1.0 0.26 1 07/30/20 02:07 100-41-4 ND ug/L 50.0 0.57 1 07/30/20 02:07 591-78-6 ND ug/L 20.0 12.5 1 07/30/20 02:07 74-88-4 ND ug/L 5.0 3.7 1 07/30/20 02:07 75-09-2 ND ug/L 100 4.5 1 07/30/20 02:07 108-10-1 ND ug/L 1.0 0.27 1 07/30/20 02:07 100-42-5 ND ug/L 5.0 0.34 1 07/30/20 02:07 630-20-6 ND ug/L 3.0 0.22 1 07/30/20 02:07 79-34-5 0.64J ug/L 1.0 0.16 1 07/30/20 02:07 127-18-4 ND ug/L 1.0 0.24 1 07/30/20 02:07 108-88-3 ND ug/L 1.0 0.18 1 07/30/20 02:07 71-55-6 ND ug/L 1.0 0.24 1 07/30/20 02:07 79-00-5 0.49J ug/L 1.0 0.22 1 07/30/20 02:07 79-01-6 ND ug/L 1.0 0.31 1 07/30/20 02:07 75-69-4 ND ug/L 1.0 0.35 1 07/30/20 02:07 96-18-4 ND ug/L 50.0 1.4 1 07/30/20 02:07 108-05-4 0.66J ug/L 1.0 0.24 1 07/30/20 02:07 75-01-4 ND ug/L 5.0 0.63 1 07/30/20 02:07 1330-20-7 102 % 70-130 1 07/30/20 02:07 460-00-4 100 % 70-130 1 07/30/20 02:07 17060-07-0 104 % 70-130 1 07/30/20 02:07 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IL Page 15 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-MW-3R2 Lab ID: 92487992003 Collected: 07/27/20 14:47 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte pH 7.90 Std. Units 1 07/27/20 14:47 Temperature 20.2 deg C 1 07/27/20 14:47 Static Water Level 39.18 feet 1 07/27/20 14:47 Specific Conductance 268 umhos/c 1 07/27/20 14:47 m Oxidation Potential -29.1 mV 1 07/27/20 14:47 Oxygen, Dissolved 3.25 mg/L 1 07/27/20 14:47 7782-44-7 Turbidity 1.67 NTU 1 07/27/20 14:47 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.28 1 07/28/20 14:30 07/31/20 20:47 7440-36-0 Arsenic 1.8J ug/L 10.0 0.78 1 07/28/20 14:30 07/31/20 20:47 7440-38-2 Barium 5.2J ug/L 100 0.71 1 07/28/20 14:30 07/31/20 20:47 7440-39-3 Beryllium ND ug/L 1.0 0.046 1 07/28/20 14:30 07/31/20 20:47 7440-41-7 Cadmium ND ug/L 1.0 0.12 1 07/28/20 14:30 07/31/20 20:47 7440-43-9 Chromium 1.4J ug/L 10.0 0.55 1 07/28/20 14:30 07/31/20 20:47 7440-47-3 Cobalt ND ug/L 10.0 0.38 1 07/28/20 14:30 07/31/20 20:47 7440-48-4 Copper ND ug/L 10.0 1.7 1 07/28/20 14:30 07/31/20 20:47 7440-50-8 Lead 0.19J ug/L 10.0 0.036 1 07/28/20 14:30 07/31/20 20:47 7439-92-1 Nickel ND ug/L 50.0 0.69 1 07/28/20 14:30 07/31/20 20:47 7440-02-0 Selenium ND ug/L 10.0 1.6 1 07/28/20 14:30 07/31/20 20:47 7782-49-2 Silver ND ug/L 10.0 0.36 1 07/28/20 14:30 07/31/20 20:47 7440-22-4 Thallium ND ug/L 5.5 0.14 1 07/28/20 14:30 07/31/20 20:47 7440-28-0 Vanadium 5.1J ug/L 25.0 2.2 1 07/28/20 14:30 07/31/20 20:47 7440-62-2 Zinc ND ug/L 10.0 2.2 1 07/28/20 14:30 07/31/20 20:47 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 6.2 1 07/30/20 02:24 67-64-1 Acrylonitrile ND ug/L 200 0.90 1 07/30/20 02:24 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/30/20 02:24 71-43-2 Bromochloromethane ND ug/L 3.0 0.34 1 07/30/20 02:24 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/30/20 02:24 75-27-4 Bromoform ND ug/L 3.0 0.62 1 07/30/20 02:24 75-25-2 Bromomethane ND ug/L 10.0 0.62 1 07/30/20 02:24 74-83-9 2-Butanone (MEK) ND ug/L 100 3.3 1 07/30/20 02:24 78-93-3 Carbon disulfide ND ug/L 100 0.40 1 07/30/20 02:24 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/30/20 02:24 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 07/30/20 02:24 108-90-7 Chloroethane ND ug/L 10.0 0.49 1 07/30/20 02:24 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/30/20 02:24 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/30/20 02:24 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.26 1 07/30/20 02:24 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-MW-3R2 Lab ID: 92487992003 Collected: 07/27/20 14:47 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/29/2020 05:00 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.41 1 07/30/20 02:24 124-48-1 ND ug/L 2.0 0.26 1 07/30/20 02:24 106-93-4 ND ug/L 10.0 0.46 1 07/30/20 02:24 74-95-3 ND ug/L 5.0 0.29 1 07/30/20 02:24 95-50-1 ND ug/L 1.0 0.26 1 07/30/20 02:24 106-46-7 ND ug/L 100 0.54 1 07/30/20 02:24 110-57-6 ND ug/L 5.0 0.27 1 07/30/20 02:24 75-34-3 ND ug/L 1.0 0.34 1 07/30/20 02:24 107-06-2 ND ug/L 5.0 0.24 1 07/30/20 02:24 75-35-4 ND ug/L 5.0 0.29 1 07/30/20 02:24 156-59-2 ND ug/L 5.0 0.25 1 07/30/20 02:24 156-60-5 ND ug/L 1.0 0.19 1 07/30/20 02:24 78-87-5 ND ug/L 1.0 0.30 1 07/30/20 02:24 10061-01-5 ND ug/L 1.0 0.31 1 07/30/20 02:24 10061-02-6 ND ug/L 1.0 0.26 1 07/30/20 02:24 100-41-4 ND ug/L 50.0 0.57 1 07/30/20 02:24 591-78-6 ND ug/L 20.0 12.5 1 07/30/20 02:24 74-88-4 ND ug/L 5.0 3.7 1 07/30/20 02:24 75-09-2 ND ug/L 100 4.5 1 07/30/20 02:24 108-10-1 ND ug/L 1.0 0.27 1 07/30/20 02:24 100-42-5 ND ug/L 5.0 0.34 1 07/30/20 02:24 630-20-6 ND ug/L 3.0 0.22 1 07/30/20 02:24 79-34-5 ND ug/L 1.0 0.16 1 07/30/20 02:24 127-18-4 ND ug/L 1.0 0.24 1 07/30/20 02:24 108-88-3 ND ug/L 1.0 0.18 1 07/30/20 02:24 71-55-6 ND ug/L 1.0 0.24 1 07/30/20 02:24 79-00-5 ND ug/L 1.0 0.22 1 07/30/20 02:24 79-01-6 0.35J ug/L 1.0 0.31 1 07/30/20 02:24 75-69-4 ND ug/L 1.0 0.35 1 07/30/20 02:24 96-18-4 ND ug/L 50.0 1.4 1 07/30/20 02:24 108-05-4 ND ug/L 1.0 0.24 1 07/30/20 02:24 75-01-4 ND ug/L 5.0 0.63 1 07/30/20 02:24 1330-20-7 105 % 70-130 1 07/30/20 02:24 460-00-4 100 % 70-130 1 07/30/20 02:24 17060-07-0 104 % 70-130 1 07/30/20 02:24 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IL Page 17 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-MW-4 Lab ID: 92487992004 Collected: 07/27/20 13:29 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte pH 5.23 Std. Units 1 07/27/20 13:29 Temperature 19.9 deg C 1 07/27/20 13:29 Static Water Level 41.93 feet 1 07/27/20 13:29 Specific Conductance 34.1 umhos/c 1 07/27/20 13:29 m Oxidation Potential 100.4 mV 1 07/27/20 13:29 Oxygen, Dissolved 1.35 mg/L 1 07/27/20 13:29 7782-44-7 Turbidity 0.15 NTU 1 07/27/20 13:29 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.28 1 07/28/20 14:30 07/31/20 20:53 7440-36-0 Arsenic ND ug/L 10.0 0.78 1 07/28/20 14:30 07/31/20 20:53 7440-38-2 Barium 43.4J ug/L 100 0.71 1 07/28/20 14:30 07/31/20 20:53 7440-39-3 Beryllium 0.076J ug/L 1.0 0.046 1 07/28/20 14:30 07/31/20 20:53 7440-41-7 Cadmium ND ug/L 1.0 0.12 1 07/28/20 14:30 07/31/20 20:53 7440-43-9 Chromium ND ug/L 10.0 0.55 1 07/28/20 14:30 07/31/20 20:53 7440-47-3 Cobalt 15.1 ug/L 10.0 0.38 1 07/28/20 14:30 07/31/20 20:53 7440-48-4 Copper ND ug/L 10.0 1.7 1 07/28/20 14:30 07/31/20 20:53 7440-50-8 Lead ND ug/L 10.0 0.036 1 07/28/20 14:30 07/31/20 20:53 7439-92-1 Nickel ND ug/L 50.0 0.69 1 07/28/20 14:30 07/31/20 20:53 7440-02-0 Selenium ND ug/L 10.0 1.6 1 07/28/20 14:30 07/31/20 20:53 7782-49-2 Silver ND ug/L 10.0 0.36 1 07/28/20 14:30 07/31/20 20:53 7440-22-4 Thallium ND ug/L 5.5 0.14 1 07/28/20 14:30 07/31/20 20:53 7440-28-0 Vanadium 2.3J ug/L 25.0 2.2 1 07/28/20 14:30 07/31/20 20:53 7440-62-2 Zinc 3.OJ ug/L 10.0 2.2 1 07/28/20 14:30 07/31/20 20:53 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 6.2 1 07/30/20 02:42 67-64-1 Acrylonitrile ND ug/L 200 0.90 1 07/30/20 02:42 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/30/20 02:42 71-43-2 Bromochloromethane ND ug/L 3.0 0.34 1 07/30/20 02:42 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/30/20 02:42 75-27-4 Bromoform ND ug/L 3.0 0.62 1 07/30/20 02:42 75-25-2 Bromomethane ND ug/L 10.0 0.62 1 07/30/20 02:42 74-83-9 2-Butanone (MEK) ND ug/L 100 3.3 1 07/30/20 02:42 78-93-3 Carbon disulfide ND ug/L 100 0.40 1 07/30/20 02:42 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/30/20 02:42 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 07/30/20 02:42 108-90-7 Chloroethane ND ug/L 10.0 0.49 1 07/30/20 02:42 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/30/20 02:42 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/30/20 02:42 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.26 1 07/30/20 02:42 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-MW-4 Lab ID: 92487992004 Collected: 07/27/20 13:29 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/29/2020 05:00 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.41 1 07/30/20 02:42 124-48-1 ND ug/L 2.0 0.26 1 07/30/20 02:42 106-93-4 ND ug/L 10.0 0.46 1 07/30/20 02:42 74-95-3 ND ug/L 5.0 0.29 1 07/30/20 02:42 95-50-1 ND ug/L 1.0 0.26 1 07/30/20 02:42 106-46-7 ND ug/L 100 0.54 1 07/30/20 02:42 110-57-6 ND ug/L 5.0 0.27 1 07/30/20 02:42 75-34-3 ND ug/L 1.0 0.34 1 07/30/20 02:42 107-06-2 ND ug/L 5.0 0.24 1 07/30/20 02:42 75-35-4 ND ug/L 5.0 0.29 1 07/30/20 02:42 156-59-2 ND ug/L 5.0 0.25 1 07/30/20 02:42 156-60-5 ND ug/L 1.0 0.19 1 07/30/20 02:42 78-87-5 ND ug/L 1.0 0.30 1 07/30/20 02:42 10061-01-5 ND ug/L 1.0 0.31 1 07/30/20 02:42 10061-02-6 ND ug/L 1.0 0.26 1 07/30/20 02:42 100-41-4 ND ug/L 50.0 0.57 1 07/30/20 02:42 591-78-6 ND ug/L 20.0 12.5 1 07/30/20 02:42 74-88-4 ND ug/L 5.0 3.7 1 07/30/20 02:42 75-09-2 ND ug/L 100 4.5 1 07/30/20 02:42 108-10-1 ND ug/L 1.0 0.27 1 07/30/20 02:42 100-42-5 ND ug/L 5.0 0.34 1 07/30/20 02:42 630-20-6 ND ug/L 3.0 0.22 1 07/30/20 02:42 79-34-5 ND ug/L 1.0 0.16 1 07/30/20 02:42 127-18-4 ND ug/L 1.0 0.24 1 07/30/20 02:42 108-88-3 ND ug/L 1.0 0.18 1 07/30/20 02:42 71-55-6 ND ug/L 1.0 0.24 1 07/30/20 02:42 79-00-5 ND ug/L 1.0 0.22 1 07/30/20 02:42 79-01-6 ND ug/L 1.0 0.31 1 07/30/20 02:42 75-69-4 ND ug/L 1.0 0.35 1 07/30/20 02:42 96-18-4 ND ug/L 50.0 1.4 1 07/30/20 02:42 108-05-4 ND ug/L 1.0 0.24 1 07/30/20 02:42 75-01-4 ND ug/L 5.0 0.63 1 07/30/20 02:42 1330-20-7 104 % 70-130 1 07/30/20 02:42 460-00-4 101 % 70-130 1 07/30/20 02:42 17060-07-0 104 % 70-130 1 07/30/20 02:42 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IL Page 19 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-Dup@MW-2R Lab ID: 92487992005 Collected: 07/27/20 16:02 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony 1.1J ug/L 6.0 0.28 1 07/28/20 14:30 07/31/20 21:16 7440-36-0 Arsenic 1.OJ ug/L 10.0 0.78 1 07/28/20 14:30 07/31/20 21:16 7440-38-2 Barium 121 ug/L 100 0.71 1 07/28/20 14:30 07/31/20 21:16 7440-39-3 Beryllium 0.070J ug/L 1.0 0.046 1 07/28/20 14:30 07/31/20 21:16 7440-41-7 Cadmium ND ug/L 1.0 0.12 1 07/28/20 14:30 07/31/20 21:16 7440-43-9 Chromium 1.2J ug/L 10.0 0.55 1 07/28/20 14:30 07/31/20 21:16 7440-47-3 Cobalt ND ug/L 10.0 0.38 1 07/28/20 14:30 07/31/20 21:16 7440-48-4 Copper ND ug/L 10.0 1.7 1 07/28/20 14:30 07/31/20 21:16 7440-50-8 Lead ND ug/L 10.0 0.036 1 07/28/20 14:30 07/31/20 21:16 7439-92-1 Nickel ND ug/L 50.0 0.69 1 07/28/20 14:30 07/31/20 21:16 7440-02-0 Selenium ND ug/L 10.0 1.6 1 07/28/20 14:30 07/31/20 21:16 7782-49-2 Silver ND ug/L 10.0 0.36 1 07/28/20 14:30 07/31/20 21:16 7440-22-4 Thallium ND ug/L 5.5 0.14 1 07/28/20 14:30 07/31/20 21:16 7440-28-0 Vanadium 4.6J ug/L 25.0 2.2 1 07/28/20 14:30 07/31/20 21:16 7440-62-2 Zinc 2.3J ug/L 10.0 2.2 1 07/28/20 14:30 07/31/20 21:16 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 6.2 1 07/30/20 03:00 67-64-1 Acrylonitrile ND ug/L 200 0.90 1 07/30/20 03:00 107-13-1 Benzene 2.0 ug/L 1.0 0.15 1 07/30/20 03:00 71-43-2 Bromochloromethane ND ug/L 3.0 0.34 1 07/30/20 03:00 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/30/20 03:00 75-27-4 Bromoform ND ug/L 3.0 0.62 1 07/30/20 03:00 75-25-2 Bromomethane ND ug/L 10.0 0.62 1 07/30/20 03:00 74-83-9 2-Butanone (MEK) ND ug/L 100 3.3 1 07/30/20 03:00 78-93-3 Carbon disulfide ND ug/L 100 0.40 1 07/30/20 03:00 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/30/20 03:00 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 07/30/20 03:00 108-90-7 Chloroethane ND ug/L 10.0 0.49 1 07/30/20 03:00 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/30/20 03:00 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/30/20 03:00 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.26 1 07/30/20 03:00 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.41 1 07/30/20 03:00 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.26 1 07/30/20 03:00 106-93-4 Dibromomethane ND ug/L 10.0 0.46 1 07/30/20 03:00 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.29 1 07/30/20 03:00 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/30/20 03:00 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 0.54 1 07/30/20 03:00 110-57-6 butene 1,1-Dichloroethane 1.1J ug/L 5.0 0.27 1 07/30/20 03:00 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/30/20 03:00 107-06-2 1,1-Dichloroethene ND ug/L 5.0 0.24 1 07/30/20 03:00 75-35-4 cis-1,2-Dichloroethene 3.4J ug/L 5.0 0.29 1 07/30/20 03:00 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-Dup@MW-2R Lab ID: 92487992005 Collected: 07/27/20 16:02 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/29/2020 05:00 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 5.0 0.25 1 07/30/20 03:00 156-60-5 ND ug/L 1.0 0.19 1 07/30/20 03:00 78-87-5 ND ug/L 1.0 0.30 1 07/30/20 03:00 10061-01-5 ND ug/L 1.0 0.31 1 07/30/20 03:00 10061-02-6 ND ug/L 1.0 0.26 1 07/30/20 03:00 100-41-4 ND ug/L 50.0 0.57 1 07/30/20 03:00 591-78-6 ND ug/L 20.0 12.5 1 07/30/20 03:00 74-88-4 IL ND ug/L 5.0 3.7 1 07/30/20 03:00 75-09-2 ND ug/L 100 4.5 1 07/30/20 03:00 108-10-1 ND ug/L 1.0 0.27 1 07/30/20 03:00 100-42-5 ND ug/L 5.0 0.34 1 07/30/20 03:00 630-20-6 ND ug/L 3.0 0.22 1 07/30/20 03:00 79-34-5 0.65J ug/L 1.0 0.16 1 07/30/20 03:00 127-18-4 ND ug/L 1.0 0.24 1 07/30/20 03:00 108-88-3 ND ug/L 1.0 0.18 1 07/30/20 03:00 71-55-6 ND ug/L 1.0 0.24 1 07/30/20 03:00 79-00-5 0.51 J ug/L 1.0 0.22 1 07/30/20 03:00 79-01-6 ND ug/L 1.0 0.31 1 07/30/20 03:00 75-69-4 ND ug/L 1.0 0.35 1 07/30/20 03:00 96-18-4 ND ug/L 50.0 1.4 1 07/30/20 03:00 108-05-4 0.75J ug/L 1.0 0.24 1 07/30/20 03:00 75-01-4 ND ug/L 5.0 0.63 1 07/30/20 03:00 1330-20-7 104 % 70-130 1 07/30/20 03:00 460-00-4 100 % 70-130 1 07/30/20 03:00 17060-07-0 104 % 70-130 1 07/30/20 03:00 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-MW-5 Lab ID: 92487992006 Collected: 07/27/20 12:42 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte pH 5.85 Std. Units 1 07/27/20 12:42 Temperature 20.2 deg C 1 07/27/20 12:42 Static Water Level 46.75 feet 1 07/27/20 12:42 Specific Conductance 188.1 umhos/c 1 07/27/20 12:42 m Oxidation Potential 68.7 mV 1 07/27/20 12:42 Oxygen, Dissolved 2.30 mg/L 1 07/27/20 12:42 7782-44-7 Turbidity 0.18 NTU 1 07/27/20 12:42 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.28 1 07/28/20 14:30 07/31/20 21:21 7440-36-0 Arsenic 0.99J ug/L 10.0 0.78 1 07/28/20 14:30 07/31/20 21:21 7440-38-2 Barium 122 ug/L 100 0.71 1 07/28/20 14:30 07/31/20 21:21 7440-39-3 Beryllium 0.066J ug/L 1.0 0.046 1 07/28/20 14:30 07/31/20 21:21 7440-41-7 Cadmium ND ug/L 1.0 0.12 1 07/28/20 14:30 07/31/20 21:21 7440-43-9 Chromium 1.1J ug/L 10.0 0.55 1 07/28/20 14:30 07/31/20 21:21 7440-47-3 Cobalt ND ug/L 10.0 0.38 1 07/28/20 14:30 07/31/20 21:21 7440-48-4 Copper ND ug/L 10.0 1.7 1 07/28/20 14:30 07/31/20 21:21 7440-50-8 Lead ND ug/L 10.0 0.036 1 07/28/20 14:30 07/31/20 21:21 7439-92-1 Nickel ND ug/L 50.0 0.69 1 07/28/20 14:30 07/31/20 21:21 7440-02-0 Selenium ND ug/L 10.0 1.6 1 07/28/20 14:30 07/31/20 21:21 7782-49-2 Silver ND ug/L 10.0 0.36 1 07/28/20 14:30 07/31/20 21:21 7440-22-4 Thallium ND ug/L 5.5 0.14 1 07/28/20 14:30 07/31/20 21:21 7440-28-0 Vanadium 4.8J ug/L 25.0 2.2 1 07/28/20 14:30 07/31/20 21:21 7440-62-2 Zinc ND ug/L 10.0 2.2 1 07/28/20 14:30 07/31/20 21:21 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 6.2 1 07/29/20 15:59 67-64-1 Acrylonitrile ND ug/L 200 0.90 1 07/29/20 15:59 107-13-1 Benzene 0.52J ug/L 1.0 0.15 1 07/29/20 15:59 71-43-2 Bromochloromethane ND ug/L 3.0 0.34 1 07/29/20 15:59 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/29/20 15:59 75-27-4 Bromoform ND ug/L 3.0 0.62 1 07/29/20 15:59 75-25-2 Bromomethane ND ug/L 10.0 0.62 1 07/29/20 15:59 74-83-9 v1 2-Butanone (MEK) ND ug/L 100 3.3 1 07/29/20 15:59 78-93-3 Carbon disulfide ND ug/L 100 0.40 1 07/29/20 15:59 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/29/20 15:59 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 07/29/20 15:59 108-90-7 Chloroethane ND ug/L 10.0 0.49 1 07/29/20 15:59 75-00-3 IK,v1 Chloroform ND ug/L 5.0 2.3 1 07/29/20 15:59 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/29/20 15:59 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.26 1 07/29/20 15:59 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-MW-5 Lab ID: 92487992006 Collected: 07/27/20 12:42 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/29/2020 05:00 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.41 1 07/29/20 15:59 124-48-1 ND ug/L 2.0 0.26 1 07/29/20 15:59 106-93-4 ND ug/L 10.0 0.46 1 07/29/20 15:59 74-95-3 ND ug/L 5.0 0.29 1 07/29/20 15:59 95-50-1 ND ug/L 1.0 0.26 1 07/29/20 15:59 106-46-7 ND ug/L 100 0.54 1 07/29/20 15:59 110-57-6 ND ug/L 5.0 0.27 1 07/29/20 15:59 75-34-3 0.39J ug/L 1.0 0.34 1 07/29/20 15:59 107-06-2 ND ug/L 5.0 0.24 1 07/29/20 15:59 75-35-4 1.2J ug/L 5.0 0.29 1 07/29/20 15:59 156-59-2 ND ug/L 5.0 0.25 1 07/29/20 15:59 156-60-5 ND ug/L 1.0 0.19 1 07/29/20 15:59 78-87-5 ND ug/L 1.0 0.30 1 07/29/20 15:59 10061-01-5 ND ug/L 1.0 0.31 1 07/29/20 15:59 10061-02-6 ND ug/L 1.0 0.26 1 07/29/20 15:59 100-41-4 ND ug/L 50.0 0.57 1 07/29/20 15:59 591-78-6 ND ug/L 20.0 12.5 1 07/29/20 15:59 74-88-4 ND ug/L 5.0 3.7 1 07/29/20 15:59 75-09-2 ND ug/L 100 4.5 1 07/29/20 15:59 108-10-1 ND ug/L 1.0 0.27 1 07/29/20 15:59 100-42-5 ND ug/L 5.0 0.34 1 07/29/20 15:59 630-20-6 ND ug/L 3.0 0.22 1 07/29/20 15:59 79-34-5 ND ug/L 1.0 0.16 1 07/29/20 15:59 127-18-4 ND ug/L 1.0 0.24 1 07/29/20 15:59 108-88-3 ND ug/L 1.0 0.18 1 07/29/20 15:59 71-55-6 ND ug/L 1.0 0.24 1 07/29/20 15:59 79-00-5 ND ug/L 1.0 0.22 1 07/29/20 15:59 79-01-6 ND ug/L 1.0 0.31 1 07/29/20 15:59 75-69-4 ND ug/L 1.0 0.35 1 07/29/20 15:59 96-18-4 ND ug/L 50.0 1.4 1 07/29/20 15:59 108-05-4 ND ug/L 1.0 0.24 1 07/29/20 15:59 75-01-4 ND ug/L 5.0 0.63 1 07/29/20 15:59 1330-20-7 96 % 70-130 1 07/29/20 15:59 460-00-4 104 % 70-130 1 07/29/20 15:59 17060-07-0 101 % 70-130 1 07/29/20 15:59 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-MW-6 Lab ID: 92487992007 Collected: 07/27/20 11:55 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte pH 5.60 Std. Units 1 07/27/20 11:55 Temperature 19.3 deg C 1 07/27/20 11:55 Static Water Level 40.81 feet 1 07/27/20 11:55 Specific Conductance 177.5 umhos/c 1 07/27/20 11:55 m Oxidation Potential 81.6 mV 1 07/27/20 11:55 Oxygen, Dissolved 1.85 mg/L 1 07/27/20 11:55 7782-44-7 Turbidity 3.72 NTU 1 07/27/20 11:55 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.28 1 07/28/20 14:30 07/31/20 21:27 7440-36-0 Arsenic ND ug/L 10.0 0.78 1 07/28/20 14:30 07/31/20 21:27 7440-38-2 Barium 126 ug/L 100 0.71 1 07/28/20 14:30 07/31/20 21:27 7440-39-3 Beryllium 0.30J ug/L 1.0 0.046 1 07/28/20 14:30 07/31/20 21:27 7440-41-7 Cadmium 0.14J ug/L 1.0 0.12 1 07/28/20 14:30 07/31/20 21:27 7440-43-9 Chromium ND ug/L 10.0 0.55 1 07/28/20 14:30 07/31/20 21:27 7440-47-3 Cobalt 8.4J ug/L 10.0 0.38 1 07/28/20 14:30 07/31/20 21:27 7440-48-4 Copper ND ug/L 10.0 1.7 1 07/28/20 14:30 07/31/20 21:27 7440-50-8 Lead 0.090J ug/L 10.0 0.036 1 07/28/20 14:30 07/31/20 21:27 7439-92-1 Nickel ND ug/L 50.0 0.69 1 07/28/20 14:30 07/31/20 21:27 7440-02-0 Selenium ND ug/L 10.0 1.6 1 07/28/20 14:30 07/31/20 21:27 7782-49-2 Silver ND ug/L 10.0 0.36 1 07/28/20 14:30 07/31/20 21:27 7440-22-4 Thallium ND ug/L 5.5 0.14 1 07/28/20 14:30 07/31/20 21:27 7440-28-0 Vanadium ND ug/L 25.0 2.2 1 07/28/20 14:30 07/31/20 21:27 7440-62-2 Zinc ND ug/L 10.0 2.2 1 07/28/20 14:30 07/31/20 21:27 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 6.2 1 07/29/20 16:17 67-64-1 Acrylonitrile ND ug/L 200 0.90 1 07/29/20 16:17 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/29/20 16:17 71-43-2 Bromochloromethane ND ug/L 3.0 0.34 1 07/29/20 16:17 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/29/20 16:17 75-27-4 Bromoform ND ug/L 3.0 0.62 1 07/29/20 16:17 75-25-2 Bromomethane ND ug/L 10.0 0.62 1 07/29/20 16:17 74-83-9 v1 2-Butanone (MEK) ND ug/L 100 3.3 1 07/29/20 16:17 78-93-3 Carbon disulfide ND ug/L 100 0.40 1 07/29/20 16:17 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/29/20 16:17 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 07/29/20 16:17 108-90-7 Chloroethane ND ug/L 10.0 0.49 1 07/29/20 16:17 75-00-3 IK,v1 Chloroform ND ug/L 5.0 2.3 1 07/29/20 16:17 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/29/20 16:17 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.26 1 07/29/20 16:17 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-MW-6 Lab ID: 92487992007 Collected: 07/27/20 11:55 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/29/2020 05:00 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.41 1 ND ug/L 2.0 0.26 1 ND ug/L 10.0 0.46 1 ND ug/L 5.0 0.29 1 ND ug/L 1.0 0.26 1 ND ug/L 100 0.54 1 07/29/20 16:17 124-48-1 07/29/20 16:17 106-93-4 07/29/20 16:17 74-95-3 07/29/20 16:17 95-50-1 07/29/20 16:17 106-46-7 07/29/20 16:17 110-57-6 ND ug/L 5.0 0.27 1 07/29/20 16:17 75-34-3 ND ug/L 1.0 0.34 1 07/29/20 16:17 107-06-2 ND ug/L 5.0 0.24 1 07/29/20 16:17 75-35-4 ND ug/L 5.0 0.29 1 07/29/20 16:17 156-59-2 ND ug/L 5.0 0.25 1 07/29/20 16:17 156-60-5 ND ug/L 1.0 0.19 1 07/29/20 16:17 78-87-5 ND ug/L 1.0 0.30 1 07/29/20 16:17 10061-01-5 ND ug/L 1.0 0.31 1 07/29/20 16:17 10061-02-6 ND ug/L 1.0 0.26 1 07/29/20 16:17 100-41-4 ND ug/L 50.0 0.57 1 07/29/20 16:17 591-78-6 ND ug/L 20.0 12.5 1 07/29/20 16:17 74-88-4 ND ug/L 5.0 3.7 1 07/29/20 16:17 75-09-2 ND ug/L 100 4.5 1 07/29/20 16:17 108-10-1 ND ug/L 1.0 0.27 1 07/29/20 16:17 100-42-5 ND ug/L 5.0 0.34 1 07/29/20 16:17 630-20-6 ND ug/L 3.0 0.22 1 07/29/20 16:17 79-34-5 ND ug/L 1.0 0.16 1 07/29/20 16:17 127-18-4 ND ug/L 1.0 0.24 1 07/29/20 16:17 108-88-3 ND ug/L 1.0 0.18 1 07/29/20 16:17 71-55-6 ND ug/L 1.0 0.24 1 07/29/20 16:17 79-00-5 ND ug/L 1.0 0.22 1 07/29/20 16:17 79-01-6 ND ug/L 1.0 0.31 1 07/29/20 16:17 75-69-4 ND ug/L 1.0 0.35 1 07/29/20 16:17 96-18-4 ND ug/L 50.0 1.4 1 07/29/20 16:17 108-05-4 ND ug/L 1.0 0.24 1 07/29/20 16:17 75-01-4 ND ug/L 5.0 0.63 1 07/29/20 16:17 1330-20-7 96 % 70-130 1 07/29/20 16:17 460-00-4 106 % 70-130 1 07/29/20 16:17 17060-07-0 100 % 70-130 1 07/29/20 16:17 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 25 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-MW-7 Lab ID: 92487992008 Collected: 07/27/20 10:50 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte pH 5.76 Std. Units 1 07/27/20 10:50 Temperature 19.1 deg C 1 07/27/20 10:50 Static Water Level 29.55 feet 1 07/27/20 10:50 Specific Conductance 121.8 umhos/c 1 07/27/20 10:50 m Oxidation Potential 73.2 mV 1 07/27/20 10:50 Oxygen, Dissolved 5.08 mg/L 1 07/27/20 10:50 7782-44-7 Turbidity 3.08 NTU 1 07/27/20 10:50 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony 0.38J ug/L 6.0 0.28 1 07/28/20 14:30 07/31/20 21:33 7440-36-0 Arsenic 0.95J ug/L 10.0 0.78 1 07/28/20 14:30 07/31/20 21:33 7440-38-2 Barium 38.2J ug/L 100 0.71 1 07/28/20 14:30 07/31/20 21:33 7440-39-3 Beryllium 0.15J ug/L 1.0 0.046 1 07/28/20 14:30 07/31/20 21:33 7440-41-7 Cadmium ND ug/L 1.0 0.12 1 07/28/20 14:30 07/31/20 21:33 7440-43-9 Chromium 1.2J ug/L 10.0 0.55 1 07/28/20 14:30 07/31/20 21:33 7440-47-3 Cobalt ND ug/L 10.0 0.38 1 07/28/20 14:30 07/31/20 21:33 7440-48-4 Copper ND ug/L 10.0 1.7 1 07/28/20 14:30 07/31/20 21:33 7440-50-8 Lead 0.038J ug/L 10.0 0.036 1 07/28/20 14:30 07/31/20 21:33 7439-92-1 Nickel ND ug/L 50.0 0.69 1 07/28/20 14:30 07/31/20 21:33 7440-02-0 Selenium ND ug/L 10.0 1.6 1 07/28/20 14:30 07/31/20 21:33 7782-49-2 Silver ND ug/L 10.0 0.36 1 07/28/20 14:30 07/31/20 21:33 7440-22-4 Thallium ND ug/L 5.5 0.14 1 07/28/20 14:30 07/31/20 21:33 7440-28-0 Vanadium 3.2J ug/L 25.0 2.2 1 07/28/20 14:30 07/31/20 21:33 7440-62-2 Zinc ND ug/L 10.0 2.2 1 07/28/20 14:30 07/31/20 21:33 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 6.2 1 07/29/20 16:35 67-64-1 Acrylonitrile ND ug/L 200 0.90 1 07/29/20 16:35 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/29/20 16:35 71-43-2 Bromochloromethane ND ug/L 3.0 0.34 1 07/29/20 16:35 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/29/20 16:35 75-27-4 Bromoform ND ug/L 3.0 0.62 1 07/29/20 16:35 75-25-2 Bromomethane ND ug/L 10.0 0.62 1 07/29/20 16:35 74-83-9 v1 2-Butanone (MEK) ND ug/L 100 3.3 1 07/29/20 16:35 78-93-3 Carbon disulfide ND ug/L 100 0.40 1 07/29/20 16:35 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/29/20 16:35 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 07/29/20 16:35 108-90-7 Chloroethane ND ug/L 10.0 0.49 1 07/29/20 16:35 75-00-3 IK,v1 Chloroform ND ug/L 5.0 2.3 1 07/29/20 16:35 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/29/20 16:35 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.26 1 07/29/20 16:35 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-MW-7 Lab ID: 92487992008 Collected: 07/27/20 10:50 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/29/2020 05:00 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.41 1 07/29/2016:35 124-48-1 ND ug/L 2.0 0.26 1 07/29/2016:35 106-93-4 ND ug/L 10.0 0.46 1 07/29/2016:35 74-95-3 ND ug/L 5.0 0.29 1 07/29/2016:35 95-50-1 ND ug/L 1.0 0.26 1 07/29/2016:35 106-46-7 ND ug/L 100 0.54 1 07/29/2016:35 110-57-6 ND ug/L 5.0 0.27 1 07/29/2016:35 75-34-3 ND ug/L 1.0 0.34 1 07/29/2016:35 107-06-2 ND ug/L 5.0 0.24 1 07/29/2016:35 75-35-4 ND ug/L 5.0 0.29 1 07/29/2016:35 156-59-2 ND ug/L 5.0 0.25 1 07/29/2016:35 156-60-5 ND ug/L 1.0 0.19 1 07/29/2016:35 78-87-5 ND ug/L 1.0 0.30 1 07/29/2016:35 10061-01-5 ND ug/L 1.0 0.31 1 07/29/2016:35 10061-02-6 ND ug/L 1.0 0.26 1 07/29/2016:35 100-41-4 ND ug/L 50.0 0.57 1 07/29/20 16:35 591-78-6 ND ug/L 20.0 12.5 1 07/29/2016:35 74-88-4 ND ug/L 5.0 3.7 1 07/29/2016:35 75-09-2 ND ug/L 100 4.5 1 07/29/2016:35 108-10-1 ND ug/L 1.0 0.27 1 07/29/2016:35 100-42-5 ND ug/L 5.0 0.34 1 07/29/2016:35 630-20-6 ND ug/L 3.0 0.22 1 07/29/2016:35 79-34-5 ND ug/L 1.0 0.16 1 07/29/2016:35 127-18-4 ND ug/L 1.0 0.24 1 07/29/2016:35 108-88-3 ND ug/L 1.0 0.18 1 07/29/2016:35 71-55-6 ND ug/L 1.0 0.24 1 07/29/2016:35 79-00-5 ND ug/L 1.0 0.22 1 07/29/2016:35 79-01-6 ND ug/L 1.0 0.31 1 07/29/2016:35 75-69-4 ND ug/L 1.0 0.35 1 07/29/2016:35 96-18-4 ND ug/L 50.0 1.4 1 07/29/2016:35 108-05-4 ND ug/L 1.0 0.24 1 07/29/2016:35 75-01-4 ND ug/L 5.0 0.63 1 07/29/2016:35 1330-20-7 96 % 70-130 1 07/29/2016:35 460-00-4 105 % 70-130 1 07/29/2016:35 17060-07-0 100 % 70-130 1 07/29/2016:35 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-MW-8 Lab ID: 92487992009 Collected: 07/27/20 10:01 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte pH 5.54 Std. Units 1 07/27/20 10:01 Temperature 20.2 deg C 1 07/27/20 10:01 Static Water Level 30.59 feet 1 07/27/20 10:01 Specific Conductance 76.4 umhos/c 1 07/27/20 10:01 m Oxidation Potential 84.5 mV 1 07/27/20 10:01 Oxygen, Dissolved 2.01 mg/L 1 07/27/20 10:01 7782-44-7 Turbidity 6.88 NTU 1 07/27/20 10:01 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.28 1 07/28/20 14:30 07/31/20 21:38 7440-36-0 Arsenic 0.90J ug/L 10.0 0.78 1 07/28/20 14:30 07/31/20 21:38 7440-38-2 Barium 34.OJ ug/L 100 0.71 1 07/28/20 14:30 07/31/20 21:38 7440-39-3 Beryllium 0.17J ug/L 1.0 0.046 1 07/28/20 14:30 07/31/20 21:38 7440-41-7 Cadmium ND ug/L 1.0 0.12 1 07/28/20 14:30 07/31/20 21:38 7440-43-9 Chromium ND ug/L 10.0 0.55 1 07/28/20 14:30 07/31/20 21:38 7440-47-3 Cobalt 3.8J ug/L 10.0 0.38 1 07/28/20 14:30 07/31/20 21:38 7440-48-4 Copper ND ug/L 10.0 1.7 1 07/28/20 14:30 07/31/20 21:38 7440-50-8 Lead 0.096J ug/L 10.0 0.036 1 07/28/20 14:30 07/31/20 21:38 7439-92-1 Nickel 0.91J ug/L 50.0 0.69 1 07/28/20 14:30 07/31/20 21:38 7440-02-0 Selenium ND ug/L 10.0 1.6 1 07/28/20 14:30 07/31/20 21:38 7782-49-2 Silver ND ug/L 10.0 0.36 1 07/28/20 14:30 07/31/20 21:38 7440-22-4 Thallium ND ug/L 5.5 0.14 1 07/28/20 14:30 07/31/20 21:38 7440-28-0 Vanadium ND ug/L 25.0 2.2 1 07/28/20 14:30 07/31/20 21:38 7440-62-2 Zinc 3.2J ug/L 10.0 2.2 1 07/28/20 14:30 07/31/20 21:38 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 6.2 1 07/29/20 16:53 67-64-1 Acrylonitrile ND ug/L 200 0.90 1 07/29/20 16:53 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/29/20 16:53 71-43-2 Bromochloromethane ND ug/L 3.0 0.34 1 07/29/20 16:53 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/29/20 16:53 75-27-4 Bromoform ND ug/L 3.0 0.62 1 07/29/20 16:53 75-25-2 Bromomethane ND ug/L 10.0 0.62 1 07/29/20 16:53 74-83-9 v1 2-Butanone (MEK) ND ug/L 100 3.3 1 07/29/20 16:53 78-93-3 Carbon disulfide ND ug/L 100 0.40 1 07/29/20 16:53 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/29/20 16:53 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 07/29/20 16:53 108-90-7 Chloroethane ND ug/L 10.0 0.49 1 07/29/20 16:53 75-00-3 IK,v1 Chloroform ND ug/L 5.0 2.3 1 07/29/20 16:53 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/29/20 16:53 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.26 1 07/29/20 16:53 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-MW-8 Lab ID: 92487992009 Collected: 07/27/20 10:01 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/29/2020 05:00 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.41 1 ND ug/L 2.0 0.26 1 ND ug/L 10.0 0.46 1 ND ug/L 5.0 0.29 1 ND ug/L 1.0 0.26 1 ND ug/L 100 0.54 1 07/29/20 16:53 124-48-1 07/29/20 16:53 106-93-4 07/29/20 16:53 74-95-3 07/29/20 16:53 95-50-1 07/29/20 16:53 106-46-7 07/29/20 16:53 110-57-6 ND ug/L 5.0 0.27 1 07/29/20 16:53 75-34-3 ND ug/L 1.0 0.34 1 07/29/20 16:53 107-06-2 ND ug/L 5.0 0.24 1 07/29/20 16:53 75-35-4 ND ug/L 5.0 0.29 1 07/29/20 16:53 156-59-2 ND ug/L 5.0 0.25 1 07/29/20 16:53 156-60-5 ND ug/L 1.0 0.19 1 07/29/20 16:53 78-87-5 ND ug/L 1.0 0.30 1 07/29/20 16:53 10061-01-5 ND ug/L 1.0 0.31 1 07/29/20 16:53 10061-02-6 ND ug/L 1.0 0.26 1 07/29/20 16:53 100-41-4 ND ug/L 50.0 0.57 1 07/29/20 16:53 591-78-6 ND ug/L 20.0 12.5 1 07/29/20 16:53 74-88-4 ND ug/L 5.0 3.7 1 07/29/20 16:53 75-09-2 ND ug/L 100 4.5 1 07/29/20 16:53 108-10-1 ND ug/L 1.0 0.27 1 07/29/20 16:53 100-42-5 ND ug/L 5.0 0.34 1 07/29/20 16:53 630-20-6 ND ug/L 3.0 0.22 1 07/29/20 16:53 79-34-5 ND ug/L 1.0 0.16 1 07/29/20 16:53 127-18-4 ND ug/L 1.0 0.24 1 07/29/20 16:53 108-88-3 ND ug/L 1.0 0.18 1 07/29/20 16:53 71-55-6 ND ug/L 1.0 0.24 1 07/29/20 16:53 79-00-5 ND ug/L 1.0 0.22 1 07/29/20 16:53 79-01-6 ND ug/L 1.0 0.31 1 07/29/20 16:53 75-69-4 ND ug/L 1.0 0.35 1 07/29/20 16:53 96-18-4 ND ug/L 50.0 1.4 1 07/29/20 16:53 108-05-4 ND ug/L 1.0 0.24 1 07/29/20 16:53 75-01-4 ND ug/L 5.0 0.63 1 07/29/20 16:53 1330-20-7 97 % 70-130 1 07/29/20 16:53 460-00-4 106 % 70-130 1 07/29/20 16:53 17060-07-0 98 % 70-130 1 07/29/20 16:53 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 29 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-MW-9 Lab ID: 92487992010 Collected: 07/27/20 07:49 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte pH 5.95 Std. Units 1 07/27/20 07:49 Temperature 18.4 deg C 1 07/27/20 07:49 Static Water Level 68.57 feet 1 07/27/20 07:49 Specific Conductance 160.3 umhos/c 1 07/27/20 07:49 m Oxidation Potential 63.1 mV 1 07/27/20 07:49 Oxygen, Dissolved 3.25 mg/L 1 07/27/20 07:49 7782-44-7 Turbidity 0.72 NTU 1 07/27/20 07:49 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.28 1 07/28/20 14:30 07/31/20 21:56 7440-36-0 Arsenic 1.1J ug/L 10.0 0.78 1 07/28/20 14:30 07/31/20 21:56 7440-38-2 Barium 8.7J ug/L 100 0.71 1 07/28/20 14:30 07/31/20 21:56 7440-39-3 Beryllium ND ug/L 1.0 0.046 1 07/28/20 14:30 07/31/20 21:56 7440-41-7 Cadmium ND ug/L 1.0 0.12 1 07/28/20 14:30 07/31/20 21:56 7440-43-9 Chromium ND ug/L 10.0 0.55 1 07/28/20 14:30 07/31/20 21:56 7440-47-3 Cobalt ND ug/L 10.0 0.38 1 07/28/20 14:30 07/31/20 21:56 7440-48-4 Copper ND ug/L 10.0 1.7 1 07/28/20 14:30 07/31/20 21:56 7440-50-8 Lead ND ug/L 10.0 0.036 1 07/28/20 14:30 07/31/20 21:56 7439-92-1 Nickel ND ug/L 50.0 0.69 1 07/28/20 14:30 07/31/20 21:56 7440-02-0 Selenium ND ug/L 10.0 1.6 1 07/28/20 14:30 07/31/20 21:56 7782-49-2 Silver ND ug/L 10.0 0.36 1 07/28/20 14:30 07/31/20 21:56 7440-22-4 Thallium ND ug/L 5.5 0.14 1 07/28/20 14:30 07/31/20 21:56 7440-28-0 Vanadium 3.4J ug/L 25.0 2.2 1 07/28/20 14:30 07/31/20 21:56 7440-62-2 Zinc 2.9J ug/L 10.0 2.2 1 07/28/20 14:30 07/31/20 21:56 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 6.2 1 07/29/20 17:11 67-64-1 Acrylonitrile ND ug/L 200 0.90 1 07/29/20 17:11 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/29/20 17:11 71-43-2 Bromochloromethane ND ug/L 3.0 0.34 1 07/29/20 17:11 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/29/20 17:11 75-27-4 Bromoform ND ug/L 3.0 0.62 1 07/29/20 17:11 75-25-2 Bromomethane ND ug/L 10.0 0.62 1 07/29/20 17:11 74-83-9 v1 2-Butanone (MEK) ND ug/L 100 3.3 1 07/29/20 17:11 78-93-3 Carbon disulfide ND ug/L 100 0.40 1 07/29/20 17:11 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/29/20 17:11 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 07/29/20 17:11 108-90-7 Chloroethane ND ug/L 10.0 0.49 1 07/29/20 17:11 75-00-3 IK,v1 Chloroform ND ug/L 5.0 2.3 1 07/29/20 17:11 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/29/20 17:11 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.26 1 07/29/20 17:11 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-MW-9 Lab ID: 92487992010 Collected: 07/27/20 07:49 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/29/2020 05:00 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.41 1 07/29/20 17:11 124-48-1 ND ug/L 2.0 0.26 1 07/29/20 17:11 106-93-4 ND ug/L 10.0 0.46 1 07/29/20 17:11 74-95-3 ND ug/L 5.0 0.29 1 07/29/20 17:11 95-50-1 ND ug/L 1.0 0.26 1 07/29/20 17:11 106-46-7 ND ug/L 100 0.54 1 07/29/20 17:11 110-57-6 ND ug/L 5.0 0.27 1 07/29/20 17:11 75-34-3 ND ug/L 1.0 0.34 1 07/29/20 17:11 107-06-2 ND ug/L 5.0 0.24 1 07/29/20 17:11 75-35-4 ND ug/L 5.0 0.29 1 07/29/20 17:11 156-59-2 ND ug/L 5.0 0.25 1 07/29/20 17:11 156-60-5 ND ug/L 1.0 0.19 1 07/29/20 17:11 78-87-5 ND ug/L 1.0 0.30 1 07/29/20 17:11 10061-01-5 ND ug/L 1.0 0.31 1 07/29/20 17:11 10061-02-6 ND ug/L 1.0 0.26 1 07/29/20 17:11 100-41-4 ND ug/L 50.0 0.57 1 07/29/20 17:11 591-78-6 ND ug/L 20.0 12.5 1 07/29/20 17:11 74-88-4 ND ug/L 5.0 3.7 1 07/29/20 17:11 75-09-2 ND ug/L 100 4.5 1 07/29/20 17:11 108-10-1 ND ug/L 1.0 0.27 1 07/29/20 17:11 100-42-5 ND ug/L 5.0 0.34 1 07/29/20 17:11 630-20-6 ND ug/L 3.0 0.22 1 07/29/20 17:11 79-34-5 ND ug/L 1.0 0.16 1 07/29/20 17:11 127-18-4 ND ug/L 1.0 0.24 1 07/29/20 17:11 108-88-3 ND ug/L 1.0 0.18 1 07/29/20 17:11 71-55-6 ND ug/L 1.0 0.24 1 07/29/20 17:11 79-00-5 ND ug/L 1.0 0.22 1 07/29/20 17:11 79-01-6 ND ug/L 1.0 0.31 1 07/29/20 17:11 75-69-4 ND ug/L 1.0 0.35 1 07/29/20 17:11 96-18-4 ND ug/L 50.0 1.4 1 07/29/20 17:11 108-05-4 ND ug/L 1.0 0.24 1 07/29/20 17:11 75-01-4 ND ug/L 5.0 0.63 1 07/29/20 17:11 1330-20-7 96 % 70-130 1 07/29/20 17:11 460-00-4 107 % 70-130 1 07/29/20 17:11 17060-07-0 100 % 70-130 1 07/29/20 17:11 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 31 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-MW-10 Lab ID: 92487992011 Collected: 07/27/20 07:01 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte pH 7.09 Std. Units 1 07/27/20 07:01 Temperature 16.0 deg C 1 07/27/20 07:01 Static Water Level 77.31 feet 1 07/27/20 07:01 Specific Conductance 59.6 umhos/c 1 07/27/20 07:01 m Oxidation Potential 4.8 mV 1 07/27/20 07:01 Oxygen, Dissolved 5.90 mg/L 1 07/27/20 07:01 7782-44-7 Turbidity 2.45 NTU 1 07/27/20 07:01 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.28 1 07/28/20 14:30 07/31/20 22:01 7440-36-0 Arsenic ND ug/L 10.0 0.78 1 07/28/20 14:30 07/31/20 22:01 7440-38-2 Barium 25.8J ug/L 100 0.71 1 07/28/20 14:30 07/31/20 22:01 7440-39-3 Beryllium ND ug/L 1.0 0.046 1 07/28/20 14:30 07/31/20 22:01 7440-41-7 Cadmium ND ug/L 1.0 0.12 1 07/28/20 14:30 07/31/20 22:01 7440-43-9 Chromium 1.OJ ug/L 10.0 0.55 1 07/28/20 14:30 07/31/20 22:01 7440-47-3 Cobalt ND ug/L 10.0 0.38 1 07/28/20 14:30 07/31/20 22:01 7440-48-4 Copper ND ug/L 10.0 1.7 1 07/28/20 14:30 07/31/20 22:01 7440-50-8 Lead 0.17J ug/L 10.0 0.036 1 07/28/20 14:30 07/31/20 22:01 7439-92-1 Nickel ND ug/L 50.0 0.69 1 07/28/20 14:30 07/31/20 22:01 7440-02-0 Selenium ND ug/L 10.0 1.6 1 07/28/20 14:30 07/31/20 22:01 7782-49-2 Silver ND ug/L 10.0 0.36 1 07/28/20 14:30 07/31/20 22:01 7440-22-4 Thallium ND ug/L 5.5 0.14 1 07/28/20 14:30 07/31/20 22:01 7440-28-0 Vanadium 5.8J ug/L 25.0 2.2 1 07/28/20 14:30 07/31/20 22:01 7440-62-2 Zinc 2.4J ug/L 10.0 2.2 1 07/28/20 14:30 07/31/20 22:01 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 6.2 1 07/29/20 17:29 67-64-1 Acrylonitrile ND ug/L 200 0.90 1 07/29/20 17:29 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/29/20 17:29 71-43-2 Bromochloromethane ND ug/L 3.0 0.34 1 07/29/20 17:29 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/29/20 17:29 75-27-4 Bromoform ND ug/L 3.0 0.62 1 07/29/20 17:29 75-25-2 Bromomethane ND ug/L 10.0 0.62 1 07/29/20 17:29 74-83-9 v1 2-Butanone (MEK) ND ug/L 100 3.3 1 07/29/20 17:29 78-93-3 Carbon disulfide ND ug/L 100 0.40 1 07/29/20 17:29 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/29/20 17:29 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 07/29/20 17:29 108-90-7 Chloroethane ND ug/L 10.0 0.49 1 07/29/20 17:29 75-00-3 IK,v1 Chloroform ND ug/L 5.0 2.3 1 07/29/20 17:29 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/29/20 17:29 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.26 1 07/29/20 17:29 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-MW-10 Lab ID: 92487992011 Collected: 07/27/20 07:01 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/29/2020 05:00 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.41 1 ND ug/L 2.0 0.26 1 ND ug/L 10.0 0.46 1 ND ug/L 5.0 0.29 1 ND ug/L 1.0 0.26 1 ND ug/L 100 0.54 1 07/29/20 17:29 124-48-1 07/29/20 17:29 106-93-4 07/29/20 17:29 74-95-3 07/29/20 17:29 95-50-1 07/29/20 17:29 106-46-7 07/29/20 17:29 110-57-6 ND ug/L 5.0 0.27 1 07/29/20 17:29 75-34-3 ND ug/L 1.0 0.34 1 07/29/20 17:29 107-06-2 ND ug/L 5.0 0.24 1 07/29/20 17:29 75-35-4 ND ug/L 5.0 0.29 1 07/29/20 17:29 156-59-2 ND ug/L 5.0 0.25 1 07/29/20 17:29 156-60-5 ND ug/L 1.0 0.19 1 07/29/20 17:29 78-87-5 ND ug/L 1.0 0.30 1 07/29/20 17:29 10061-01-5 ND ug/L 1.0 0.31 1 07/29/20 17:29 10061-02-6 ND ug/L 1.0 0.26 1 07/29/20 17:29 100-41-4 ND ug/L 50.0 0.57 1 07/29/20 17:29 591-78-6 ND ug/L 20.0 12.5 1 07/29/20 17:29 74-88-4 ND ug/L 5.0 3.7 1 07/29/20 17:29 75-09-2 ND ug/L 100 4.5 1 07/29/20 17:29 108-10-1 ND ug/L 1.0 0.27 1 07/29/20 17:29 100-42-5 ND ug/L 5.0 0.34 1 07/29/20 17:29 630-20-6 ND ug/L 3.0 0.22 1 07/29/20 17:29 79-34-5 ND ug/L 1.0 0.16 1 07/29/20 17:29 127-18-4 ND ug/L 1.0 0.24 1 07/29/20 17:29 108-88-3 ND ug/L 1.0 0.18 1 07/29/20 17:29 71-55-6 ND ug/L 1.0 0.24 1 07/29/20 17:29 79-00-5 ND ug/L 1.0 0.22 1 07/29/20 17:29 79-01-6 ND ug/L 1.0 0.31 1 07/29/20 17:29 75-69-4 ND ug/L 1.0 0.35 1 07/29/20 17:29 96-18-4 ND ug/L 50.0 1.4 1 07/29/20 17:29 108-05-4 ND ug/L 1.0 0.24 1 07/29/20 17:29 75-01-4 ND ug/L 5.0 0.63 1 07/29/20 17:29 1330-20-7 98 % 70-130 1 07/29/20 17:29 460-00-4 106 % 70-130 1 07/29/20 17:29 17060-07-0 101 % 70-130 1 07/29/20 17:29 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 33 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-MW-11 Lab ID: 92487992012 Collected: 07/27/20 06:12 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte pH 7.37 Std. Units 1 07/27/20 06:12 Temperature 15.9 deg C 1 07/27/20 06:12 Static Water Level 82.80 feet 1 07/27/20 06:12 Specific Conductance 54.5 umhos/c 1 07/27/20 06:12 m Oxidation Potential -9.2 mV 1 07/27/20 06:12 Oxygen, Dissolved 1.95 mg/L 1 07/27/20 06:12 7782-44-7 Turbidity 0.10 NTU 1 07/27/20 06:12 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.28 1 07/28/20 14:30 07/31/20 22:07 7440-36-0 Arsenic ND ug/L 10.0 0.78 1 07/28/20 14:30 07/31/20 22:07 7440-38-2 Barium 59.1J ug/L 100 0.71 1 07/28/20 14:30 07/31/20 22:07 7440-39-3 Beryllium ND ug/L 1.0 0.046 1 07/28/20 14:30 07/31/20 22:07 7440-41-7 Cadmium ND ug/L 1.0 0.12 1 07/28/20 14:30 07/31/20 22:07 7440-43-9 Chromium ND ug/L 10.0 0.55 1 07/28/20 14:30 07/31/20 22:07 7440-47-3 Cobalt ND ug/L 10.0 0.38 1 07/28/20 14:30 07/31/20 22:07 7440-48-4 Copper ND ug/L 10.0 1.7 1 07/28/20 14:30 07/31/20 22:07 7440-50-8 Lead ND ug/L 10.0 0.036 1 07/28/20 14:30 07/31/20 22:07 7439-92-1 Nickel ND ug/L 50.0 0.69 1 07/28/20 14:30 07/31/20 22:07 7440-02-0 Selenium ND ug/L 10.0 1.6 1 07/28/20 14:30 07/31/20 22:07 7782-49-2 Silver ND ug/L 10.0 0.36 1 07/28/20 14:30 07/31/20 22:07 7440-22-4 Thallium ND ug/L 5.5 0.14 1 07/28/20 14:30 07/31/20 22:07 7440-28-0 Vanadium ND ug/L 25.0 2.2 1 07/28/20 14:30 07/31/20 22:07 7440-62-2 Zinc 2.3J ug/L 10.0 2.2 1 07/28/20 14:30 07/31/20 22:07 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 6.2 1 07/29/20 17:47 67-64-1 Acrylonitrile ND ug/L 200 0.90 1 07/29/20 17:47 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/29/20 17:47 71-43-2 Bromochloromethane ND ug/L 3.0 0.34 1 07/29/20 17:47 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/29/20 17:47 75-27-4 Bromoform ND ug/L 3.0 0.62 1 07/29/20 17:47 75-25-2 Bromomethane ND ug/L 10.0 0.62 1 07/29/20 17:47 74-83-9 v1 2-Butanone (MEK) ND ug/L 100 3.3 1 07/29/20 17:47 78-93-3 Carbon disulfide ND ug/L 100 0.40 1 07/29/20 17:47 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/29/20 17:47 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 07/29/20 17:47 108-90-7 Chloroethane ND ug/L 10.0 0.49 1 07/29/20 17:47 75-00-3 IK,v1 Chloroform ND ug/L 5.0 2.3 1 07/29/20 17:47 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/29/20 17:47 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.26 1 07/29/20 17:47 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-MW-11 Lab ID: 92487992012 Collected: 07/27/20 06:12 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/29/2020 05:00 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.41 1 07/29/20 17:47 124-48-1 ND ug/L 2.0 0.26 1 07/29/20 17:47 106-93-4 ND ug/L 10.0 0.46 1 07/29/20 17:47 74-95-3 ND ug/L 5.0 0.29 1 07/29/20 17:47 95-50-1 ND ug/L 1.0 0.26 1 07/29/20 17:47 106-46-7 ND ug/L 100 0.54 1 07/29/20 17:47 110-57-6 ND ug/L 5.0 0.27 1 07/29/20 17:47 75-34-3 ND ug/L 1.0 0.34 1 07/29/20 17:47 107-06-2 ND ug/L 5.0 0.24 1 07/29/20 17:47 75-35-4 ND ug/L 5.0 0.29 1 07/29/20 17:47 156-59-2 ND ug/L 5.0 0.25 1 07/29/20 17:47 156-60-5 ND ug/L 1.0 0.19 1 07/29/20 17:47 78-87-5 ND ug/L 1.0 0.30 1 07/29/20 17:47 10061-01-5 ND ug/L 1.0 0.31 1 07/29/20 17:47 10061-02-6 ND ug/L 1.0 0.26 1 07/29/20 17:47 100-41-4 ND ug/L 50.0 0.57 1 07/29/20 17:47 591-78-6 ND ug/L 20.0 12.5 1 07/29/20 17:47 74-88-4 ND ug/L 5.0 3.7 1 07/29/20 17:47 75-09-2 ND ug/L 100 4.5 1 07/29/20 17:47 108-10-1 ND ug/L 1.0 0.27 1 07/29/20 17:47 100-42-5 ND ug/L 5.0 0.34 1 07/29/20 17:47 630-20-6 ND ug/L 3.0 0.22 1 07/29/20 17:47 79-34-5 ND ug/L 1.0 0.16 1 07/29/20 17:47 127-18-4 ND ug/L 1.0 0.24 1 07/29/20 17:47 108-88-3 ND ug/L 1.0 0.18 1 07/29/20 17:47 71-55-6 ND ug/L 1.0 0.24 1 07/29/20 17:47 79-00-5 ND ug/L 1.0 0.22 1 07/29/20 17:47 79-01-6 ND ug/L 1.0 0.31 1 07/29/20 17:47 75-69-4 ND ug/L 1.0 0.35 1 07/29/20 17:47 96-18-4 ND ug/L 50.0 1.4 1 07/29/20 17:47 108-05-4 ND ug/L 1.0 0.24 1 07/29/20 17:47 75-01-4 ND ug/L 5.0 0.63 1 07/29/20 17:47 1330-20-7 98 % 70-130 1 07/29/20 17:47 460-00-4 103 % 70-130 1 07/29/20 17:47 17060-07-0 100 % 70-130 1 07/29/20 17:47 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 35 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-Field Blank Lab ID: 92487992013 Collected: 07/26/20 15:15 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.28 1 07/28/20 14:30 07/31/20 22:13 7440-36-0 Arsenic ND ug/L 10.0 0.78 1 07/28/20 14:30 07/31/20 22:13 7440-38-2 Barium ND ug/L 100 0.71 1 07/28/20 14:30 07/31/20 22:13 7440-39-3 Beryllium ND ug/L 1.0 0.046 1 07/28/20 14:30 07/31/20 22:13 7440-41-7 Cadmium ND ug/L 1.0 0.12 1 07/28/20 14:30 07/31/20 22:13 7440-43-9 Chromium ND ug/L 10.0 0.55 1 07/28/20 14:30 07/31/20 22:13 7440-47-3 Cobalt ND ug/L 10.0 0.38 1 07/28/20 14:30 07/31/20 22:13 7440-48-4 Copper ND ug/L 10.0 1.7 1 07/28/20 14:30 07/31/20 22:13 7440-50-8 Lead ND ug/L 10.0 0.036 1 07/28/20 14:30 07/31/20 22:13 7439-92-1 Nickel ND ug/L 50.0 0.69 1 07/28/20 14:30 07/31/20 22:13 7440-02-0 Selenium ND ug/L 10.0 1.6 1 07/28/20 14:30 07/31/20 22:13 7782-49-2 Silver ND ug/L 10.0 0.36 1 07/28/20 14:30 07/31/20 22:13 7440-22-4 Thallium ND ug/L 5.5 0.14 1 07/28/20 14:30 07/31/20 22:13 7440-28-0 Vanadium ND ug/L 25.0 2.2 1 07/28/20 14:30 07/31/20 22:13 7440-62-2 Zinc ND ug/L 10.0 2.2 1 07/28/20 14:30 07/31/20 22:13 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 6.2 1 07/29/20 18:05 67-64-1 Acrylonitrile ND ug/L 200 0.90 1 07/29/20 18:05 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/29/20 18:05 71-43-2 Bromochloromethane ND ug/L 3.0 0.34 1 07/29/20 18:05 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/29/20 18:05 75-27-4 Bromoform ND ug/L 3.0 0.62 1 07/29/20 18:05 75-25-2 Bromomethane ND ug/L 10.0 0.62 1 07/29/20 18:05 74-83-9 2-Butanone (MEK) ND ug/L 100 3.3 1 07/29/20 18:05 78-93-3 Carbon disulfide ND ug/L 100 0.40 1 07/29/20 18:05 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/29/20 18:05 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 07/29/20 18:05 108-90-7 Chloroethane ND ug/L 10.0 0.49 1 07/29/20 18:05 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/29/20 18:05 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/29/20 18:05 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.26 1 07/29/20 18:05 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.41 1 07/29/20 18:05 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.26 1 07/29/20 18:05 106-93-4 Dibromomethane ND ug/L 10.0 0.46 1 07/29/20 18:05 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.29 1 07/29/20 18:05 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/29/20 18:05 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 0.54 1 07/29/20 18:05 110-57-6 butene 1,1-Dichloroethane ND ug/L 5.0 0.27 1 07/29/20 18:05 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/29/20 18:05 107-06-2 1,1-Dichloroethene ND ug/L 5.0 0.24 1 07/29/20 18:05 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 0.29 1 07/29/20 18:05 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. v1 IK,v1 Page 36 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-Field Blank Lab ID: 92487992013 Collected: 07/26/20 15:15 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/29/2020 05:00 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 5.0 0.25 1 07/29/20 18:05 156-60-5 ND ug/L 1.0 0.19 1 07/29/20 18:05 78-87-5 ND ug/L 1.0 0.30 1 07/29/20 18:05 10061-01-5 ND ug/L 1.0 0.31 1 07/29/20 18:05 10061-02-6 ND ug/L 1.0 0.26 1 07/29/20 18:05 100-41-4 ND ug/L 50.0 0.57 1 07/29/20 18:05 591-78-6 ND ug/L 20.0 12.5 1 07/29/20 18:05 74-88-4 ND ug/L 5.0 3.7 1 07/29/20 18:05 75-09-2 ND ug/L 100 4.5 1 07/29/20 18:05 108-10-1 ND ug/L 1.0 0.27 1 07/29/20 18:05 100-42-5 ND ug/L 5.0 0.34 1 07/29/20 18:05 630-20-6 ND ug/L 3.0 0.22 1 07/29/20 18:05 79-34-5 ND ug/L 1.0 0.16 1 07/29/20 18:05 127-18-4 ND ug/L 1.0 0.24 1 07/29/20 18:05 108-88-3 ND ug/L 1.0 0.18 1 07/29/20 18:05 71-55-6 ND ug/L 1.0 0.24 1 07/29/20 18:05 79-00-5 ND ug/L 1.0 0.22 1 07/29/20 18:05 79-01-6 ND ug/L 1.0 0.31 1 07/29/20 18:05 75-69-4 ND ug/L 1.0 0.35 1 07/29/20 18:05 96-18-4 ND ug/L 50.0 1.4 1 07/29/20 18:05 108-05-4 ND ug/L 1.0 0.24 1 07/29/20 18:05 75-01-4 ND ug/L 5.0 0.63 1 07/29/20 18:05 1330-20-7 95 % 70-130 1 07/29/20 18:05 460-00-4 103 % 70-130 1 07/29/20 18:05 17060-07-0 99 % 70-130 1 07/29/20 18:05 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 37 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-SW 1 Lab ID: 92487992014 Collected: 07/27/20 09:10 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte pH 6.40 Std. Units 1 07/27/20 09:10 Temperature 23.9 deg C 1 07/27/20 09:10 Specific Conductance 55.6 umhos/c 1 07/27/20 09:10 m Oxidation Potential 41.6 mV 1 07/27/20 09:10 Oxygen, Dissolved 4.62 mg/L 1 07/27/20 09:10 7782-44-7 Turbidity 9.88 NTU 1 07/27/20 09:10 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.28 1 07/28/20 14:30 07/31/20 22:18 7440-36-0 Arsenic ND ug/L 10.0 0.78 1 07/28/20 14:30 07/31/20 22:18 7440-38-2 Barium 19.1J ug/L 100 0.71 1 07/28/20 14:30 07/31/20 22:18 7440-39-3 Beryllium ND ug/L 1.0 0.046 1 07/28/20 14:30 07/31/20 22:18 7440-41-7 Cadmium ND ug/L 1.0 0.12 1 07/28/20 14:30 07/31/20 22:18 7440-43-9 Chromium 0.61J ug/L 10.0 0.55 1 07/28/20 14:30 07/31/20 22:18 7440-47-3 Cobalt 0.53J ug/L 10.0 0.38 1 07/28/20 14:30 07/31/20 22:18 7440-48-4 Copper ND ug/L 10.0 1.7 1 07/28/20 14:30 07/31/20 22:18 7440-50-8 Lead 0.24J ug/L 10.0 0.036 1 07/28/20 14:30 07/31/20 22:18 7439-92-1 Nickel ND ug/L 50.0 0.69 1 07/28/20 14:30 07/31/20 22:18 7440-02-0 Selenium ND ug/L 10.0 1.6 1 07/28/20 14:30 07/31/20 22:18 7782-49-2 Silver ND ug/L 10.0 0.36 1 07/28/20 14:30 07/31/20 22:18 7440-22-4 Thallium ND ug/L 5.5 0.14 1 07/28/20 14:30 07/31/20 22:18 7440-28-0 Vanadium 3.OJ ug/L 25.0 2.2 1 07/28/20 14:30 07/31/20 22:18 7440-62-2 Zinc ND ug/L 10.0 2.2 1 07/28/20 14:30 07/31/20 22:18 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 6.2 1 07/29/20 18:23 67-64-1 Acrylonitrile ND ug/L 200 0.90 1 07/29/20 18:23 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/29/20 18:23 71-43-2 Bromochloromethane ND ug/L 3.0 0.34 1 07/29/20 18:23 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/29/20 18:23 75-27-4 Bromoform ND ug/L 3.0 0.62 1 07/29/20 18:23 75-25-2 Bromomethane ND ug/L 10.0 0.62 1 07/29/20 18:23 74-83-9 v1 2-Butanone (MEK) ND ug/L 100 3.3 1 07/29/20 18:23 78-93-3 Carbon disulfide ND ug/L 100 0.40 1 07/29/20 18:23 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/29/20 18:23 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 07/29/20 18:23 108-90-7 Chloroethane ND ug/L 10.0 0.49 1 07/29/20 18:23 75-00-3 IK,v1 Chloroform ND ug/L 5.0 2.3 1 07/29/20 18:23 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/29/20 18:23 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.26 1 07/29/20 18:23 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.41 1 07/29/20 18:23 124-48-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-SW 1 Lab ID: 92487992014 Collected: 07/27/20 09:10 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/29/2020 05:00 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 2.0 0.26 1 07/29/2018:23 106-93-4 ND ug/L 10.0 0.46 1 07/29/2018:23 74-95-3 ND ug/L 5.0 0.29 1 07/29/2018:23 95-50-1 ND ug/L 1.0 0.26 1 07/29/2018:23 106-46-7 ND ug/L 100 0.54 1 07/29/2018:23 110-57-6 ND ug/L 5.0 0.27 1 07/29/2018:23 75-34-3 ND ug/L 1.0 0.34 1 07/29/2018:23 107-06-2 ND ug/L 5.0 0.24 1 07/29/2018:23 75-35-4 ND ug/L 5.0 0.29 1 07/29/2018:23 156-59-2 ND ug/L 5.0 0.25 1 07/29/2018:23 156-60-5 ND ug/L 1.0 0.19 1 07/29/2018:23 78-87-5 ND ug/L 1.0 0.30 1 07/29/2018:23 10061-01-5 ND ug/L 1.0 0.31 1 07/29/2018:23 10061-02-6 ND ug/L 1.0 0.26 1 07/29/2018:23 100-41-4 ND ug/L 50.0 0.57 1 07/29/2018:23 591-78-6 ND ug/L 20.0 12.5 1 07/29/2018:23 74-88-4 ND ug/L 5.0 3.7 1 07/29/2018:23 75-09-2 ND ug/L 100 4.5 1 07/29/2018:23 108-10-1 ND ug/L 1.0 0.27 1 07/29/2018:23 100-42-5 ND ug/L 5.0 0.34 1 07/29/2018:23 630-20-6 ND ug/L 3.0 0.22 1 07/29/2018:23 79-34-5 ND ug/L 1.0 0.16 1 07/29/2018:23 127-18-4 ND ug/L 1.0 0.24 1 07/29/2018:23 108-88-3 ND ug/L 1.0 0.18 1 07/29/2018:23 71-55-6 ND ug/L 1.0 0.24 1 07/29/2018:23 79-00-5 ND ug/L 1.0 0.22 1 07/29/2018:23 79-01-6 ND ug/L 1.0 0.31 1 07/29/2018:23 75-69-4 ND ug/L 1.0 0.35 1 07/29/2018:23 96-18-4 ND ug/L 50.0 1.4 1 07/29/2018:23 108-05-4 ND ug/L 1.0 0.24 1 07/29/2018:23 75-01-4 ND ug/L 5.0 0.63 1 07/29/2018:23 1330-20-7 97 % 70-130 1 07/29/2018:23 460-00-4 106 % 70-130 1 07/29/2018:23 17060-07-0 98 % 70-130 1 07/29/2018:23 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 39 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-SW 2 Lab ID: 92487992015 Collected: 07/27/20 13:56 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte pH 6.36 Std. Units 1 07/27/20 13:56 Temperature 24.3 deg C 1 07/27/20 13:56 Specific Conductance 82.7 umhos/c 1 07/27/20 13:56 m Oxidation Potential 43.2 mV 1 07/27/20 13:56 Oxygen, Dissolved 5.02 mg/L 1 07/27/20 13:56 7782-44-7 Turbidity 12.20 NTU 1 07/27/20 13:56 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.28 1 07/29/20 08:00 07/29/20 19:17 7440-36-0 Arsenic ND ug/L 10.0 0.78 1 07/29/20 08:00 07/29/20 19:17 7440-38-2 Barium 31.OJ ug/L 100 0.71 1 07/29/20 08:00 07/29/20 19:17 7440-39-3 Beryllium 0.073J ug/L 1.0 0.046 1 07/29/20 08:00 07/29/20 19:17 7440-41-7 Cadmium ND ug/L 1.0 0.12 1 07/29/20 08:00 07/29/20 19:17 7440-43-9 Chromium 1.2J ug/L 10.0 0.55 1 07/29/20 08:00 07/29/20 19:17 7440-47-3 Cobalt 0.96J ug/L 10.0 0.38 1 07/29/20 08:00 07/29/20 19:17 7440-48-4 Copper ND ug/L 10.0 1.7 1 07/29/20 08:00 07/29/20 19:17 7440-50-8 Lead 0.51J ug/L 10.0 0.036 1 07/29/20 08:00 07/29/20 19:17 7439-92-1 Nickel ND ug/L 50.0 0.69 1 07/29/20 08:00 07/29/20 19:17 7440-02-0 Selenium ND ug/L 10.0 1.6 1 07/29/20 08:00 07/29/20 19:17 7782-49-2 Silver ND ug/L 10.0 0.36 1 07/29/20 08:00 07/29/20 19:17 7440-22-4 Thallium ND ug/L 5.5 0.14 1 07/29/20 08:00 07/29/20 19:17 7440-28-0 Vanadium ND ug/L 25.0 2.2 1 07/29/20 08:00 07/29/20 19:17 7440-62-2 Zinc 5.1J ug/L 10.0 2.2 1 07/29/20 08:00 07/29/20 19:17 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 6.2 1 07/29/20 18:41 67-64-1 Acrylonitrile ND ug/L 200 0.90 1 07/29/20 18:41 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/29/20 18:41 71-43-2 Bromochloromethane ND ug/L 3.0 0.34 1 07/29/20 18:41 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/29/20 18:41 75-27-4 Bromoform ND ug/L 3.0 0.62 1 07/29/20 18:41 75-25-2 Bromomethane ND ug/L 10.0 0.62 1 07/29/20 18:41 74-83-9 v1 2-Butanone (MEK) ND ug/L 100 3.3 1 07/29/20 18:41 78-93-3 Carbon disulfide ND ug/L 100 0.40 1 07/29/20 18:41 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/29/20 18:41 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 07/29/20 18:41 108-90-7 Chloroethane ND ug/L 10.0 0.49 1 07/29/20 18:41 75-00-3 IK,v1 Chloroform ND ug/L 5.0 2.3 1 07/29/20 18:41 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/29/20 18:41 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.26 1 07/29/20 18:41 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.41 1 07/29/20 18:41 124-48-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-SW 2 Lab ID: 92487992015 Collected: 07/27/20 13:56 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/29/2020 05:00 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 2.0 0.26 1 07/29/20 18:41 106-93-4 ND ug/L 10.0 0.46 1 07/29/20 18:41 74-95-3 ND ug/L 5.0 0.29 1 07/29/20 18:41 95-50-1 ND ug/L 1.0 0.26 1 07/29/20 18:41 106-46-7 ND ug/L 100 0.54 1 07/29/20 18:41 110-57-6 ND ug/L 5.0 0.27 1 07/29/20 18:41 75-34-3 ND ug/L 1.0 0.34 1 07/29/20 18:41 107-06-2 ND ug/L 5.0 0.24 1 07/29/20 18:41 75-35-4 ND ug/L 5.0 0.29 1 07/29/20 18:41 156-59-2 ND ug/L 5.0 0.25 1 07/29/20 18:41 156-60-5 ND ug/L 1.0 0.19 1 07/29/20 18:41 78-87-5 ND ug/L 1.0 0.30 1 07/29/20 18:41 10061-01-5 ND ug/L 1.0 0.31 1 07/29/20 18:41 10061-02-6 ND ug/L 1.0 0.26 1 07/29/20 18:41 100-41-4 ND ug/L 50.0 0.57 1 07/29/20 18:41 591-78-6 ND ug/L 20.0 12.5 1 07/29/20 18:41 74-88-4 ND ug/L 5.0 3.7 1 07/29/20 18:41 75-09-2 ND ug/L 100 4.5 1 07/29/20 18:41 108-10-1 ND ug/L 1.0 0.27 1 07/29/20 18:41 100-42-5 ND ug/L 5.0 0.34 1 07/29/20 18:41 630-20-6 ND ug/L 3.0 0.22 1 07/29/20 18:41 79-34-5 ND ug/L 1.0 0.16 1 07/29/20 18:41 127-18-4 ND ug/L 1.0 0.24 1 07/29/20 18:41 108-88-3 ND ug/L 1.0 0.18 1 07/29/20 18:41 71-55-6 ND ug/L 1.0 0.24 1 07/29/20 18:41 79-00-5 ND ug/L 1.0 0.22 1 07/29/20 18:41 79-01-6 ND ug/L 1.0 0.31 1 07/29/20 18:41 75-69-4 ND ug/L 1.0 0.35 1 07/29/20 18:41 96-18-4 ND ug/L 50.0 1.4 1 07/29/20 18:41 108-05-4 ND ug/L 1.0 0.24 1 07/29/20 18:41 75-01-4 ND ug/L 5.0 0.63 1 07/29/20 18:41 1330-20-7 97 % 70-130 1 07/29/20 18:41 460-00-4 106 % 70-130 1 07/29/20 18:41 17060-07-0 101 % 70-130 1 07/29/20 18:41 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 41 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-SW 3 Lab ID: 92487992016 Collected: 07/26/20 16:12 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte pH 7.48 Std. Units 1 07/26/20 16:12 Temperature 23.8 deg C 1 07/26/20 16:12 Specific Conductance 64.6 umhos/c 1 07/26/20 16:12 m Oxidation Potential -15.8 mV 1 07/26/20 16:12 Oxygen, Dissolved 5.16 mg/L 1 07/26/20 16:12 7782-44-7 Turbidity 9.72 NTU 1 07/26/20 16:12 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony 1.7J ug/L 6.0 0.28 1 07/29/20 08:00 07/29/20 19:40 7440-36-0 Arsenic ND ug/L 10.0 0.78 1 07/29/20 08:00 07/29/20 19:40 7440-38-2 Barium 28.2J ug/L 100 0.71 1 07/29/20 08:00 07/29/20 19:40 7440-39-3 Beryllium 0.068J ug/L 1.0 0.046 1 07/29/20 08:00 07/29/20 19:40 7440-41-7 Cadmium ND ug/L 1.0 0.12 1 07/29/20 08:00 07/29/20 19:40 7440-43-9 Chromium 1.5J ug/L 10.0 0.55 1 07/29/20 08:00 07/29/20 19:40 7440-47-3 Cobalt 0.72J ug/L 10.0 0.38 1 07/29/20 08:00 07/29/20 19:40 7440-48-4 Copper ND ug/L 10.0 1.7 1 07/29/20 08:00 07/29/20 19:40 7440-50-8 Lead 0.62J ug/L 10.0 0.036 1 07/29/20 08:00 07/29/20 19:40 7439-92-1 Nickel 0.82J ug/L 50.0 0.69 1 07/29/20 08:00 07/29/20 19:40 7440-02-0 Selenium ND ug/L 10.0 1.6 1 07/29/20 08:00 07/29/20 19:40 7782-49-2 Silver ND ug/L 10.0 0.36 1 07/29/20 08:00 07/29/20 19:40 7440-22-4 Thallium ND ug/L 5.5 0.14 1 07/29/20 08:00 07/29/20 19:40 7440-28-0 Vanadium 3.OJ ug/L 25.0 2.2 1 07/29/20 08:00 07/29/20 19:40 7440-62-2 Zinc 3.8J ug/L 10.0 2.2 1 07/29/20 08:00 07/29/20 19:40 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 6.2 1 07/29/20 18:59 67-64-1 Acrylonitrile ND ug/L 200 0.90 1 07/29/20 18:59 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/29/20 18:59 71-43-2 Bromochloromethane ND ug/L 3.0 0.34 1 07/29/20 18:59 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/29/20 18:59 75-27-4 Bromoform ND ug/L 3.0 0.62 1 07/29/20 18:59 75-25-2 Bromomethane ND ug/L 10.0 0.62 1 07/29/20 18:59 74-83-9 v1 2-Butanone (MEK) ND ug/L 100 3.3 1 07/29/20 18:59 78-93-3 Carbon disulfide ND ug/L 100 0.40 1 07/29/20 18:59 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/29/20 18:59 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 07/29/20 18:59 108-90-7 Chloroethane ND ug/L 10.0 0.49 1 07/29/20 18:59 75-00-3 IK,v1 Chloroform ND ug/L 5.0 2.3 1 07/29/20 18:59 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/29/20 18:59 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.26 1 07/29/20 18:59 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.41 1 07/29/20 18:59 124-48-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 42 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-SW 3 Lab ID: 92487992016 Collected: 07/26/20 16:12 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/29/2020 05:00 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 2.0 0.26 1 07/29/20 18:59 106-93-4 ND ug/L 10.0 0.46 1 07/29/20 18:59 74-95-3 ND ug/L 5.0 0.29 1 07/29/20 18:59 95-50-1 ND ug/L 1.0 0.26 1 07/29/20 18:59 106-46-7 ND ug/L 100 0.54 1 07/29/20 18:59 110-57-6 ND ug/L 5.0 0.27 1 07/29/20 18:59 75-34-3 ND ug/L 1.0 0.34 1 07/29/20 18:59 107-06-2 ND ug/L 5.0 0.24 1 07/29/20 18:59 75-35-4 ND ug/L 5.0 0.29 1 07/29/20 18:59 156-59-2 ND ug/L 5.0 0.25 1 07/29/20 18:59 156-60-5 ND ug/L 1.0 0.19 1 07/29/20 18:59 78-87-5 ND ug/L 1.0 0.30 1 07/29/20 18:59 10061-01-5 ND ug/L 1.0 0.31 1 07/29/20 18:59 10061-02-6 ND ug/L 1.0 0.26 1 07/29/20 18:59 100-41-4 ND ug/L 50.0 0.57 1 07/29/20 18:59 591-78-6 ND ug/L 20.0 12.5 1 07/29/20 18:59 74-88-4 ND ug/L 5.0 3.7 1 07/29/20 18:59 75-09-2 ND ug/L 100 4.5 1 07/29/20 18:59 108-10-1 ND ug/L 1.0 0.27 1 07/29/20 18:59 100-42-5 ND ug/L 5.0 0.34 1 07/29/20 18:59 630-20-6 ND ug/L 3.0 0.22 1 07/29/20 18:59 79-34-5 ND ug/L 1.0 0.16 1 07/29/20 18:59 127-18-4 ND ug/L 1.0 0.24 1 07/29/20 18:59 108-88-3 ND ug/L 1.0 0.18 1 07/29/20 18:59 71-55-6 ND ug/L 1.0 0.24 1 07/29/20 18:59 79-00-5 ND ug/L 1.0 0.22 1 07/29/20 18:59 79-01-6 ND ug/L 1.0 0.31 1 07/29/20 18:59 75-69-4 ND ug/L 1.0 0.35 1 07/29/20 18:59 96-18-4 ND ug/L 50.0 1.4 1 07/29/20 18:59 108-05-4 ND ug/L 1.0 0.24 1 07/29/20 18:59 75-01-4 ND ug/L 5.0 0.63 1 07/29/20 18:59 1330-20-7 97 % 70-130 1 07/29/20 18:59 460-00-4 107 % 70-130 1 07/29/20 18:59 17060-07-0 100 % 70-130 1 07/29/20 18:59 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 43 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-SW 4 Lab ID: 92487992017 Collected: 07/26/20 15:50 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte pH 7.42 Std. Units 1 07/26/20 15:50 Temperature 25.1 deg C 1 07/26/20 15:50 Specific Conductance 66.7 umhos/c 1 07/26/20 15:50 m Oxidation Potential -12.4 mV 1 07/26/20 15:50 Oxygen, Dissolved 5.06 mg/L 1 07/26/20 15:50 7782-44-7 Turbidity 15.70 NTU 1 07/26/20 15:50 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony 0.58J ug/L 6.0 0.28 1 07/29/20 08:00 07/29/20 19:46 7440-36-0 Arsenic ND ug/L 10.0 0.78 1 07/29/20 08:00 07/29/20 19:46 7440-38-2 Barium 29.1J ug/L 100 0.71 1 07/29/20 08:00 07/29/20 19:46 7440-39-3 Beryllium 0.072J ug/L 1.0 0.046 1 07/29/20 08:00 07/29/20 19:46 7440-41-7 Cadmium ND ug/L 1.0 0.12 1 07/29/20 08:00 07/29/20 19:46 7440-43-9 Chromium 1.6J ug/L 10.0 0.55 1 07/29/20 08:00 07/29/20 19:46 7440-47-3 Cobalt 0.74J ug/L 10.0 0.38 1 07/29/20 08:00 07/29/20 19:46 7440-48-4 Copper ND ug/L 10.0 1.7 1 07/29/20 08:00 07/29/20 19:46 7440-50-8 Lead 0.68J ug/L 10.0 0.036 1 07/29/20 08:00 07/29/20 19:46 7439-92-1 Nickel 0.79J ug/L 50.0 0.69 1 07/29/20 08:00 07/29/20 19:46 7440-02-0 Selenium ND ug/L 10.0 1.6 1 07/29/20 08:00 07/29/20 19:46 7782-49-2 Silver ND ug/L 10.0 0.36 1 07/29/20 08:00 07/29/20 19:46 7440-22-4 Thallium ND ug/L 5.5 0.14 1 07/29/20 08:00 07/29/20 19:46 7440-28-0 Vanadium 3.3J ug/L 25.0 2.2 1 07/29/20 08:00 07/29/20 19:46 7440-62-2 Zinc 3.9J ug/L 10.0 2.2 1 07/29/20 08:00 07/29/20 19:46 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 6.2 1 07/29/20 19:17 67-64-1 Acrylonitrile ND ug/L 200 0.90 1 07/29/20 19:17 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/29/20 19:17 71-43-2 Bromochloromethane ND ug/L 3.0 0.34 1 07/29/20 19:17 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/29/20 19:17 75-27-4 Bromoform ND ug/L 3.0 0.62 1 07/29/20 19:17 75-25-2 Bromomethane ND ug/L 10.0 0.62 1 07/29/20 19:17 74-83-9 v1 2-Butanone (MEK) ND ug/L 100 3.3 1 07/29/20 19:17 78-93-3 Carbon disulfide ND ug/L 100 0.40 1 07/29/20 19:17 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/29/20 19:17 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 07/29/20 19:17 108-90-7 Chloroethane ND ug/L 10.0 0.49 1 07/29/20 19:17 75-00-3 IK,v1 Chloroform ND ug/L 5.0 2.3 1 07/29/20 19:17 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/29/20 19:17 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.26 1 07/29/20 19:17 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.41 1 07/29/20 19:17 124-48-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-SW 4 Lab ID: 92487992017 Collected: 07/26/20 15:50 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/29/2020 05:00 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 2.0 0.26 1 07/29/20 19:17 106-93-4 ND ug/L 10.0 0.46 1 07/29/20 19:17 74-95-3 ND ug/L 5.0 0.29 1 07/29/20 19:17 95-50-1 ND ug/L 1.0 0.26 1 07/29/20 19:17 106-46-7 ND ug/L 100 0.54 1 07/29/20 19:17 110-57-6 ND ug/L 5.0 0.27 1 07/29/20 19:17 75-34-3 ND ug/L 1.0 0.34 1 07/29/20 19:17 107-06-2 ND ug/L 5.0 0.24 1 07/29/20 19:17 75-35-4 ND ug/L 5.0 0.29 1 07/29/20 19:17 156-59-2 ND ug/L 5.0 0.25 1 07/29/20 19:17 156-60-5 ND ug/L 1.0 0.19 1 07/29/20 19:17 78-87-5 ND ug/L 1.0 0.30 1 07/29/20 19:17 10061-01-5 ND ug/L 1.0 0.31 1 07/29/20 19:17 10061-02-6 ND ug/L 1.0 0.26 1 07/29/20 19:17 100-41-4 ND ug/L 50.0 0.57 1 07/29/20 19:17 591-78-6 ND ug/L 20.0 12.5 1 07/29/20 19:17 74-88-4 ND ug/L 5.0 3.7 1 07/29/20 19:17 75-09-2 ND ug/L 100 4.5 1 07/29/20 19:17 108-10-1 ND ug/L 1.0 0.27 1 07/29/20 19:17 100-42-5 ND ug/L 5.0 0.34 1 07/29/20 19:17 630-20-6 ND ug/L 3.0 0.22 1 07/29/20 19:17 79-34-5 ND ug/L 1.0 0.16 1 07/29/20 19:17 127-18-4 ND ug/L 1.0 0.24 1 07/29/20 19:17 108-88-3 ND ug/L 1.0 0.18 1 07/29/20 19:17 71-55-6 ND ug/L 1.0 0.24 1 07/29/20 19:17 79-00-5 ND ug/L 1.0 0.22 1 07/29/20 19:17 79-01-6 ND ug/L 1.0 0.31 1 07/29/20 19:17 75-69-4 ND ug/L 1.0 0.35 1 07/29/20 19:17 96-18-4 ND ug/L 50.0 1.4 1 07/29/20 19:17 108-05-4 ND ug/L 1.0 0.24 1 07/29/20 19:17 75-01-4 ND ug/L 5.0 0.63 1 07/29/20 19:17 1330-20-7 96 % 70-130 1 07/29/20 19:17 460-00-4 107 % 70-130 1 07/29/20 19:17 17060-07-0 100 % 70-130 1 07/29/20 19:17 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 45 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-SW 5 Lab ID: 92487992018 Collected: 07/26/20 15:28 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte pH 7.01 Std. Units 1 07/26/20 15:28 Temperature 26.2 deg C 1 07/26/20 15:28 Specific Conductance 95.5 umhos/c 1 07/26/20 15:28 m Oxidation Potential 8.9 mV 1 07/26/20 15:28 Oxygen, Dissolved 5.86 mg/L 1 07/26/20 15:28 7782-44-7 Turbidity 78.70 NTU 1 07/26/20 15:28 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony 0.54J ug/L 6.0 0.28 1 07/29/20 08:00 07/29/20 19:52 7440-36-0 Arsenic ND ug/L 10.0 0.78 1 07/29/20 08:00 07/29/20 19:52 7440-38-2 Barium 27.5J ug/L 100 0.71 1 07/29/20 08:00 07/29/20 19:52 7440-39-3 Beryllium 0.14J ug/L 1.0 0.046 1 07/29/20 08:00 07/29/20 19:52 7440-41-7 Cadmium ND ug/L 1.0 0.12 1 07/29/20 08:00 07/29/20 19:52 7440-43-9 Chromium 2.OJ ug/L 10.0 0.55 1 07/29/20 08:00 07/29/20 19:52 7440-47-3 Cobalt 3.3J ug/L 10.0 0.38 1 07/29/20 08:00 07/29/20 19:52 7440-48-4 Copper 1.9J ug/L 10.0 1.7 1 07/29/20 08:00 07/29/20 19:52 7440-50-8 Lead 1.6J ug/L 10.0 0.036 1 07/29/20 08:00 07/29/20 19:52 7439-92-1 Nickel 1.4J ug/L 50.0 0.69 1 07/29/20 08:00 07/29/20 19:52 7440-02-0 Selenium ND ug/L 10.0 1.6 1 07/29/20 08:00 07/29/20 19:52 7782-49-2 Silver ND ug/L 10.0 0.36 1 07/29/20 08:00 07/29/20 19:52 7440-22-4 Thallium ND ug/L 5.5 0.14 1 07/29/20 08:00 07/29/20 19:52 7440-28-0 Vanadium 4.4J ug/L 25.0 2.2 1 07/29/20 08:00 07/29/20 19:52 7440-62-2 Zinc 6.OJ ug/L 10.0 2.2 1 07/29/20 08:00 07/29/20 19:52 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 6.2 1 07/29/20 19:35 67-64-1 Acrylonitrile ND ug/L 200 0.90 1 07/29/20 19:35 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/29/20 19:35 71-43-2 Bromochloromethane ND ug/L 3.0 0.34 1 07/29/20 19:35 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/29/20 19:35 75-27-4 Bromoform ND ug/L 3.0 0.62 1 07/29/20 19:35 75-25-2 Bromomethane ND ug/L 10.0 0.62 1 07/29/20 19:35 74-83-9 v1 2-Butanone (MEK) ND ug/L 100 3.3 1 07/29/20 19:35 78-93-3 Carbon disulfide ND ug/L 100 0.40 1 07/29/20 19:35 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/29/20 19:35 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 07/29/20 19:35 108-90-7 Chloroethane ND ug/L 10.0 0.49 1 07/29/20 19:35 75-00-3 IK,v1 Chloroform ND ug/L 5.0 2.3 1 07/29/20 19:35 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/29/20 19:35 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.26 1 07/29/20 19:35 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.41 1 07/29/20 19:35 124-48-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 46 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-SW 5 Lab ID: 92487992018 Collected: 07/26/20 15:28 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/29/2020 05:00 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 2.0 0.26 1 07/29/2019:35 106-93-4 ND ug/L 10.0 0.46 1 07/29/2019:35 74-95-3 ND ug/L 5.0 0.29 1 07/29/2019:35 95-50-1 ND ug/L 1.0 0.26 1 07/29/2019:35 106-46-7 ND ug/L 100 0.54 1 07/29/2019:35 110-57-6 ND ug/L 5.0 0.27 1 07/29/2019:35 75-34-3 ND ug/L 1.0 0.34 1 07/29/2019:35 107-06-2 ND ug/L 5.0 0.24 1 07/29/2019:35 75-35-4 ND ug/L 5.0 0.29 1 07/29/2019:35 156-59-2 ND ug/L 5.0 0.25 1 07/29/2019:35 156-60-5 ND ug/L 1.0 0.19 1 07/29/2019:35 78-87-5 ND ug/L 1.0 0.30 1 07/29/2019:35 10061-01-5 ND ug/L 1.0 0.31 1 07/29/2019:35 10061-02-6 ND ug/L 1.0 0.26 1 07/29/2019:35 100-41-4 ND ug/L 50.0 0.57 1 07/29/2019:35 591-78-6 ND ug/L 20.0 12.5 1 07/29/2019:35 74-88-4 ND ug/L 5.0 3.7 1 07/29/2019:35 75-09-2 ND ug/L 100 4.5 1 07/29/2019:35 108-10-1 ND ug/L 1.0 0.27 1 07/29/2019:35 100-42-5 ND ug/L 5.0 0.34 1 07/29/2019:35 630-20-6 ND ug/L 3.0 0.22 1 07/29/2019:35 79-34-5 ND ug/L 1.0 0.16 1 07/29/2019:35 127-18-4 ND ug/L 1.0 0.24 1 07/29/2019:35 108-88-3 ND ug/L 1.0 0.18 1 07/29/2019:35 71-55-6 ND ug/L 1.0 0.24 1 07/29/2019:35 79-00-5 ND ug/L 1.0 0.22 1 07/29/2019:35 79-01-6 ND ug/L 1.0 0.31 1 07/29/2019:35 75-69-4 ND ug/L 1.0 0.35 1 07/29/2019:35 96-18-4 ND ug/L 50.0 1.4 1 07/29/2019:35 108-05-4 ND ug/L 1.0 0.24 1 07/29/2019:35 75-01-4 ND ug/L 5.0 0.63 1 07/29/2019:35 1330-20-7 96 % 70-130 1 07/29/2019:35 460-00-4 106 % 70-130 1 07/29/2019:35 17060-07-0 101 % 70-130 1 07/29/2019:35 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 47 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-UD 1 Lab ID: 92487992019 Collected: 07/27/20 13:40 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte pH 5.84 Std. Units 1 07/27/20 13:40 Temperature 25.1 deg C 1 07/27/20 13:40 Specific Conductance 218 umhos/c 1 07/27/20 13:40 m Oxidation Potential 70.1 mV 1 07/27/20 13:40 Oxygen, Dissolved 4.75 mg/L 1 07/27/20 13:40 7782-44-7 Turbidity 19.70 NTU 1 07/27/20 13:40 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.28 1 07/29/20 08:00 07/29/20 19:57 7440-36-0 Arsenic ND ug/L 10.0 0.78 1 07/29/20 08:00 07/29/20 19:57 7440-38-2 Barium 74.6J ug/L 100 0.71 1 07/29/20 08:00 07/29/20 19:57 7440-39-3 Beryllium 0.080J ug/L 1.0 0.046 1 07/29/20 08:00 07/29/20 19:57 7440-41-7 Cadmium ND ug/L 1.0 0.12 1 07/29/20 08:00 07/29/20 19:57 7440-43-9 Chromium 0.64J ug/L 10.0 0.55 1 07/29/20 08:00 07/29/20 19:57 7440-47-3 Cobalt 7.9J ug/L 10.0 0.38 1 07/29/20 08:00 07/29/20 19:57 7440-48-4 Copper ND ug/L 10.0 1.7 1 07/29/20 08:00 07/29/20 19:57 7440-50-8 Lead 0.50J ug/L 10.0 0.036 1 07/29/20 08:00 07/29/20 19:57 7439-92-1 Nickel 1.4J ug/L 50.0 0.69 1 07/29/20 08:00 07/29/20 19:57 7440-02-0 Selenium ND ug/L 10.0 1.6 1 07/29/20 08:00 07/29/20 19:57 7782-49-2 Silver ND ug/L 10.0 0.36 1 07/29/20 08:00 07/29/20 19:57 7440-22-4 Thallium ND ug/L 5.5 0.14 1 07/29/20 08:00 07/29/20 19:57 7440-28-0 Vanadium ND ug/L 25.0 2.2 1 07/29/20 08:00 07/29/20 19:57 7440-62-2 Zinc 4.4J ug/L 10.0 2.2 1 07/29/20 08:00 07/29/20 19:57 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 6.2 1 07/29/20 19:53 67-64-1 Acrylonitrile ND ug/L 200 0.90 1 07/29/20 19:53 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/29/20 19:53 71-43-2 Bromochloromethane ND ug/L 3.0 0.34 1 07/29/20 19:53 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/29/20 19:53 75-27-4 Bromoform ND ug/L 3.0 0.62 1 07/29/20 19:53 75-25-2 Bromomethane ND ug/L 10.0 0.62 1 07/29/20 19:53 74-83-9 v1 2-Butanone (MEK) ND ug/L 100 3.3 1 07/29/20 19:53 78-93-3 Carbon disulfide ND ug/L 100 0.40 1 07/29/20 19:53 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/29/20 19:53 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 07/29/20 19:53 108-90-7 Chloroethane ND ug/L 10.0 0.49 1 07/29/20 19:53 75-00-3 IK,v1 Chloroform ND ug/L 5.0 2.3 1 07/29/20 19:53 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/29/20 19:53 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.26 1 07/29/20 19:53 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.41 1 07/29/20 19:53 124-48-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 48 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-UD 1 Lab ID: 92487992019 Collected: 07/27/20 13:40 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/29/2020 05:00 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 2.0 0.26 1 07/29/20 19:53 106-93-4 ND ug/L 10.0 0.46 1 07/29/20 19:53 74-95-3 ND ug/L 5.0 0.29 1 07/29/20 19:53 95-50-1 ND ug/L 1.0 0.26 1 07/29/20 19:53 106-46-7 ND ug/L 100 0.54 1 07/29/20 19:53 110-57-6 ND ug/L 5.0 0.27 1 07/29/20 19:53 75-34-3 ND ug/L 1.0 0.34 1 07/29/20 19:53 107-06-2 ND ug/L 5.0 0.24 1 07/29/20 19:53 75-35-4 ND ug/L 5.0 0.29 1 07/29/20 19:53 156-59-2 ND ug/L 5.0 0.25 1 07/29/20 19:53 156-60-5 ND ug/L 1.0 0.19 1 07/29/20 19:53 78-87-5 ND ug/L 1.0 0.30 1 07/29/20 19:53 10061-01-5 ND ug/L 1.0 0.31 1 07/29/20 19:53 10061-02-6 ND ug/L 1.0 0.26 1 07/29/20 19:53 100-41-4 ND ug/L 50.0 0.57 1 07/29/20 19:53 591-78-6 ND ug/L 20.0 12.5 1 07/29/20 19:53 74-88-4 ND ug/L 5.0 3.7 1 07/29/20 19:53 75-09-2 ND ug/L 100 4.5 1 07/29/20 19:53 108-10-1 ND ug/L 1.0 0.27 1 07/29/20 19:53 100-42-5 ND ug/L 5.0 0.34 1 07/29/20 19:53 630-20-6 ND ug/L 3.0 0.22 1 07/29/20 19:53 79-34-5 ND ug/L 1.0 0.16 1 07/29/20 19:53 127-18-4 ND ug/L 1.0 0.24 1 07/29/20 19:53 108-88-3 ND ug/L 1.0 0.18 1 07/29/20 19:53 71-55-6 ND ug/L 1.0 0.24 1 07/29/20 19:53 79-00-5 ND ug/L 1.0 0.22 1 07/29/20 19:53 79-01-6 ND ug/L 1.0 0.31 1 07/29/20 19:53 75-69-4 ND ug/L 1.0 0.35 1 07/29/20 19:53 96-18-4 ND ug/L 50.0 1.4 1 07/29/20 19:53 108-05-4 ND ug/L 1.0 0.24 1 07/29/20 19:53 75-01-4 ND ug/L 5.0 0.63 1 07/29/20 19:53 1330-20-7 97 % 70-130 1 07/29/20 19:53 460-00-4 109 % 70-130 1 07/29/20 19:53 17060-07-0 103 % 70-130 1 07/29/20 19:53 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 49 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-UD 2 Lab ID: 92487992020 Collected: 07/27/20 11:05 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte pH 5.72 Std. Units 1 07/27/20 11:05 Temperature 23.9 deg C 1 07/27/20 11:05 Specific Conductance 210 umhos/c 1 07/27/20 11:05 m Oxidation Potential 74.2 mV 1 07/27/20 11:05 Oxygen, Dissolved 4.98 mg/L 1 07/27/20 11:05 7782-44-7 Turbidity 8.02 NTU 1 07/27/20 11:05 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.28 1 07/29/20 08:00 07/29/20 20:15 7440-36-0 Arsenic ND ug/L 10.0 0.78 1 07/29/20 08:00 07/29/20 20:15 7440-38-2 Barium 62.9J ug/L 100 0.71 1 07/29/20 08:00 07/29/20 20:15 7440-39-3 Beryllium 0.064J ug/L 1.0 0.046 1 07/29/20 08:00 07/29/20 20:15 7440-41-7 Cadmium ND ug/L 1.0 0.12 1 07/29/20 08:00 07/29/20 20:15 7440-43-9 Chromium 0.62J ug/L 10.0 0.55 1 07/29/20 08:00 07/29/20 20:15 7440-47-3 Cobalt 6.5J ug/L 10.0 0.38 1 07/29/20 08:00 07/29/20 20:15 7440-48-4 Copper ND ug/L 10.0 1.7 1 07/29/20 08:00 07/29/20 20:15 7440-50-8 Lead 0.28J ug/L 10.0 0.036 1 07/29/20 08:00 07/29/20 20:15 7439-92-1 Nickel 1.1J ug/L 50.0 0.69 1 07/29/20 08:00 07/29/20 20:15 7440-02-0 Selenium ND ug/L 10.0 1.6 1 07/29/20 08:00 07/29/20 20:15 7782-49-2 Silver ND ug/L 10.0 0.36 1 07/29/20 08:00 07/29/20 20:15 7440-22-4 Thallium ND ug/L 5.5 0.14 1 07/29/20 08:00 07/29/20 20:15 7440-28-0 Vanadium ND ug/L 25.0 2.2 1 07/29/20 08:00 07/29/20 20:15 7440-62-2 Zinc 2.8J ug/L 10.0 2.2 1 07/29/20 08:00 07/29/20 20:15 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 6.2 1 07/29/20 20:11 67-64-1 Acrylonitrile ND ug/L 200 0.90 1 07/29/20 20:11 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/29/20 20:11 71-43-2 Bromochloromethane ND ug/L 3.0 0.34 1 07/29/20 20:11 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/29/20 20:11 75-27-4 Bromoform ND ug/L 3.0 0.62 1 07/29/20 20:11 75-25-2 Bromomethane ND ug/L 10.0 0.62 1 07/29/20 20:11 74-83-9 v1 2-Butanone (MEK) ND ug/L 100 3.3 1 07/29/20 20:11 78-93-3 Carbon disulfide ND ug/L 100 0.40 1 07/29/20 20:11 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/29/20 20:11 56-23-5 Chlorobenzene ND ug/L 3.0 0.23 1 07/29/20 20:11 108-90-7 Chloroethane ND ug/L 10.0 0.49 1 07/29/20 20:11 75-00-3 IK,v1 Chloroform ND ug/L 5.0 2.3 1 07/29/20 20:11 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/29/20 20:11 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.26 1 07/29/20 20:11 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.41 1 07/29/20 20:11 124-48-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 50 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-UD 2 Lab ID: 92487992020 Collected: 07/27/20 11:05 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/29/2020 05:00 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 2.0 0.26 1 07/29/20 20:11 106-93-4 ND ug/L 10.0 0.46 1 07/29/20 20:11 74-95-3 ND ug/L 5.0 0.29 1 07/29/20 20:11 95-50-1 ND ug/L 1.0 0.26 1 07/29/20 20:11 106-46-7 ND ug/L 100 0.54 1 07/29/20 20:11 110-57-6 ND ug/L 5.0 0.27 1 07/29/20 20:11 75-34-3 ND ug/L 1.0 0.34 1 07/29/20 20:11 107-06-2 ND ug/L 5.0 0.24 1 07/29/20 20:11 75-35-4 ND ug/L 5.0 0.29 1 07/29/20 20:11 156-59-2 ND ug/L 5.0 0.25 1 07/29/20 20:11 156-60-5 ND ug/L 1.0 0.19 1 07/29/20 20:11 78-87-5 ND ug/L 1.0 0.30 1 07/29/20 20:11 10061-01-5 ND ug/L 1.0 0.31 1 07/29/20 20:11 10061-02-6 ND ug/L 1.0 0.26 1 07/29/20 20:11 100-41-4 ND ug/L 50.0 0.57 1 07/29/20 20:11 591-78-6 ND ug/L 20.0 12.5 1 07/29/20 20:11 74-88-4 ND ug/L 5.0 3.7 1 07/29/20 20:11 75-09-2 ND ug/L 100 4.5 1 07/29/20 20:11 108-10-1 ND ug/L 1.0 0.27 1 07/29/20 20:11 100-42-5 ND ug/L 5.0 0.34 1 07/29/20 20:11 630-20-6 ND ug/L 3.0 0.22 1 07/29/20 20:11 79-34-5 ND ug/L 1.0 0.16 1 07/29/20 20:11 127-18-4 ND ug/L 1.0 0.24 1 07/29/20 20:11 108-88-3 ND ug/L 1.0 0.18 1 07/29/20 20:11 71-55-6 ND ug/L 1.0 0.24 1 07/29/20 20:11 79-00-5 ND ug/L 1.0 0.22 1 07/29/20 20:11 79-01-6 ND ug/L 1.0 0.31 1 07/29/20 20:11 75-69-4 ND ug/L 1.0 0.35 1 07/29/20 20:11 96-18-4 ND ug/L 50.0 1.4 1 07/29/20 20:11 108-05-4 ND ug/L 1.0 0.24 1 07/29/20 20:11 75-01-4 ND ug/L 5.0 0.63 1 07/29/20 20:11 1330-20-7 96 % 70-130 1 07/29/20 20:11 460-00-4 108 % 70-130 1 07/29/20 20:11 17060-07-0 101 % 70-130 1 07/29/20 20:11 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 51 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-Trip Blank Lab ID: 92487992021 Collected: 07/26/20 15:18 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrach loroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane Date: 09/29/2020 05:00 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 100 6.2 1 07/29/20 13:24 67-64-1 ND ug/L 200 0.90 1 07/29/20 13:24 107-13-1 ND ug/L 1.0 0.15 1 07/29/20 13:24 71-43-2 ND ug/L 3.0 0.34 1 07/29/20 13:24 74-97-5 ND ug/L 1.0 0.26 1 07/29/20 13:24 75-27-4 ND ug/L 3.0 0.62 1 07/29/20 13:24 75-25-2 ND ug/L 10.0 0.62 1 07/29/20 13:24 74-83-9 ND ug/L 100 3.3 1 07/29/20 13:24 78-93-3 ND ug/L 100 0.40 1 07/29/20 13:24 75-15-0 ND ug/L 1.0 0.22 1 07/29/20 13:24 56-23-5 ND ug/L 3.0 0.23 1 07/29/20 13:24 108-90-7 ND ug/L 10.0 0.49 1 07/29/20 13:24 75-00-3 ND ug/L 5.0 2.3 1 07/29/20 13:24 67-66-3 ND ug/L 1.0 0.39 1 07/29/20 13:24 74-87-3 ND ug/L 13.0 0.26 1 07/29/20 13:24 96-12-8 ND ug/L 3.0 0.41 1 07/29/20 13:24 124-48-1 ND ug/L 2.0 0.26 1 07/29/20 13:24 106-93-4 ND ug/L 10.0 0.46 1 07/29/20 13:24 74-95-3 ND ug/L 5.0 0.29 1 07/29/20 13:24 95-50-1 ND ug/L 1.0 0.26 1 07/29/20 13:24 106-46-7 ND ug/L 100 0.54 1 07/29/20 13:24 110-57-6 ND ug/L 5.0 0.27 1 07/29/20 13:24 75-34-3 ND ug/L 1.0 0.34 1 07/29/20 13:24 107-06-2 ND ug/L 5.0 0.24 1 07/29/20 13:24 75-35-4 ND ug/L 5.0 0.29 1 07/29/20 13:24 156-59-2 ND ug/L 5.0 0.25 1 07/29/20 13:24 156-60-5 ND ug/L 1.0 0.19 1 07/29/20 13:24 78-87-5 ND ug/L 1.0 0.30 1 07/29/20 13:24 10061-01-5 ND ug/L 1.0 0.31 1 07/29/20 13:24 10061-02-6 ND ug/L 1.0 0.26 1 07/29/20 13:24 100-41-4 ND ug/L 50.0 0.57 1 07/29/20 13:24 591-78-6 ND ug/L 20.0 12.5 1 07/29/20 13:24 74-88-4 ND ug/L 5.0 3.7 1 07/29/20 13:24 75-09-2 ND ug/L 100 4.5 1 07/29/20 13:24 108-10-1 ND ug/L 1.0 0.27 1 07/29/20 13:24 100-42-5 ND ug/L 5.0 0.34 1 07/29/20 13:24 630-20-6 ND ug/L 3.0 0.22 1 07/29/20 13:24 79-34-5 ND ug/L 1.0 0.16 1 07/29/20 13:24 127-18-4 ND ug/L 1.0 0.24 1 07/29/20 13:24 108-88-3 ND ug/L 1.0 0.18 1 07/29/20 13:24 71-55-6 ND ug/L 1.0 0.24 1 07/29/20 13:24 79-00-5 ND ug/L 1.0 0.22 1 07/29/20 13:24 79-01-6 ND ug/L 1.0 0.31 1 07/29/20 13:24 75-69-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 52 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Sample: 1403-Trip Blank Lab ID: 92487992021 Collected: 07/26/20 15:18 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/29/2020 05:00 PM ND ug/L 1.0 0.35 1 07/29/2013:24 96-18-4 ND ug/L 50.0 1.4 1 07/29/2013:24 108-05-4 ND ug/L 1.0 0.24 1 07/29/20 13:24 75-01-4 ND ug/L 5.0 0.63 1 07/29/2013:24 1330-20-7 98 % 70-130 1 07/29/2013:24 460-00-4 105 % 70-130 1 07/29/2013:24 17060-07-0 101 % 70-130 1 07/29/2013:24 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 53 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 QC Batch: 556270 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020 MET Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92487992001, 92487992002, 92487992003, 92487992004, 92487992005, 92487992006, 92487992007, 92487992008,92487992009,92487992010,92487992011,92487992012,92487992013,92487992014 METHOD BLANK: 2953747 Matrix: Water Associated Lab Samples: 92487992001, 92487992002, 92487992003, 92487992004, 92487992005, 92487992006, 92487992007, 92487992008,92487992009,92487992010,92487992011,92487992012,92487992013,92487992014 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 6.0 0.28 07/31/2019:38 Arsenic ug/L ND 10.0 0.78 07/31/2019:38 Barium ug/L ND 100 0.71 07/31/2019:38 Beryllium ug/L ND 1.0 0.046 07/31/2019:38 Cadmium ug/L ND 1.0 0.12 07/31/2019:38 Chromium ug/L ND 10.0 0.55 07/31/2019:38 Cobalt ug/L ND 10.0 0.38 07/31/2019:38 Copper ug/L ND 10.0 1.7 07/31/2019:38 Lead ug/L ND 10.0 0.036 07/31/2019:38 Nickel ug/L ND 50.0 0.69 07/31/2019:38 Selenium ug/L ND 10.0 1.6 07/31/2019:38 Silver ug/L ND 10.0 0.36 07/31/2019:38 Thallium ug/L ND 5.5 0.14 07/31/2019:38 Vanadium ug/L ND 25.0 2.2 07/31/2019:38 Zinc ug/L 2.2J 10.0 2.2 07/31/2019:38 LABORATORY CONTROL SAMPLE: Parameter 2953748 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 100 102 102 80-120 Arsenic ug/L 100 96.8 97 80-120 Barium ug/L 100 100 100 80-120 Beryllium ug/L 100 107 107 80-120 Cadmium ug/L 100 99.4 99 80-120 Chromium ug/L 100 106 106 80-120 Cobalt ug/L 100 104 104 80-120 Copper ug/L 100 104 104 80-120 Lead ug/L 100 99.7 100 80-120 Nickel ug/L 100 103 103 80-120 Selenium ug/L 100 93.6 94 80-120 Silver ug/L 100 101 101 80-120 Thallium ug/L 100 98.5 99 80-120 Vanadium ug/L 100 103 103 80-120 Zinc ug/L 100 104 104 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 54 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Foothills LF/Semi-Annual-Revised Report 92487992 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2953891 2953892 MS MSD 92487992004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 107 104 107 104 75-125 2 20 Arsenic ug/L ND 100 100 98.6 98.3 98 98 75-125 0 20 Barium ug/L 43AJ 100 100 148 143 104 100 75-125 3 20 Beryllium ug/L 0.076J 100 100 111 112 111 112 75-125 0 20 Cadmium ug/L ND 100 100 98.9 97.4 99 97 75-125 2 20 Chromium ug/L ND 100 100 107 105 107 105 75-125 2 20 Cobalt ug/L 15.1 100 100 121 117 106 102 75-125 3 20 Copper ug/L ND 100 100 105 101 105 101 75-125 3 20 Lead ug/L ND 100 100 100 99.4 100 99 75-125 1 20 Nickel ug/L ND 100 100 106 104 105 103 75-125 2 20 Selenium ug/L ND 100 100 93.7 92.3 94 92 75-125 2 20 Silver ug/L ND 100 100 103 100 103 100 75-125 2 20 Thallium ug/L ND 100 100 99.2 97.8 99 98 75-125 2 20 Vanadium ug/L 2.3J 100 100 110 106 108 103 75-125 4 20 Zinc ug/L 3.OJ 100 100 107 105 104 102 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 55 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 QC Batch: 556322 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020 MET Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92487992015, 92487992016, 92487992017, 92487992018, 92487992019, 92487992020 METHOD BLANK: 2954004 Matrix: Water Associated Lab Samples: 92487992015, 92487992016, 92487992017, 92487992018, 92487992019, 92487992020 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 6.0 0.28 07/29/2019:06 Arsenic ug/L ND 10.0 0.78 07/29/2019:06 Barium ug/L ND 100 0.71 07/29/2019:06 Beryllium ug/L ND 1.0 0.046 07/29/2019:06 Cadmium ug/L ND 1.0 0.12 07/29/2019:06 Chromium ug/L ND 10.0 0.55 07/29/2019:06 Cobalt ug/L ND 10.0 0.38 07/29/2019:06 Copper ug/L ND 10.0 1.7 07/29/2019:06 Lead ug/L ND 10.0 0.036 07/29/2019:06 Nickel ug/L ND 50.0 0.69 07/29/2019:06 Selenium ug/L ND 10.0 1.6 07/29/2019:06 Silver ug/L ND 10.0 0.36 07/29/2019:06 Thallium ug/L ND 5.5 0.14 07/29/2019:06 Vanadium ug/L ND 25.0 2.2 07/29/2019:06 Zinc ug/L ND 10.0 2.2 07/29/2019:06 LABORATORY CONTROL SAMPLE: Parameter 2954005 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 100 106 106 80-120 Arsenic ug/L 100 95.3 95 80-120 Barium ug/L 100 97.3J 97 80-120 Beryllium ug/L 100 97.6 98 80-120 Cadmium ug/L 100 95.7 96 80-120 Chromium ug/L 100 101 101 80-120 Cobalt ug/L 100 97.1 97 80-120 Copper ug/L 100 97.3 97 80-120 Lead ug/L 100 96.7 97 80-120 Nickel ug/L 100 97.3 97 80-120 Selenium ug/L 100 93.2 93 80-120 Silver ug/L 100 96.7 97 80-120 Thallium ug/L 100 95.2 95 80-120 Vanadium ug/L 100 98.9 99 80-120 Zinc ug/L 100 104 104 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 56 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Foothills LF/Semi-Annual-Revised Report 92487992 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2954006 2954007 MS MSD 92487992015 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 107 107 107 106 75-125 0 20 Arsenic ug/L ND 100 100 97.7 98.6 98 99 75-125 1 20 Barium ug/L 31.OJ 100 100 130 128 99 97 75-125 2 20 Beryllium ug/L 0.073J 100 100 101 100 101 100 75-125 1 20 Cadmium ug/L ND 100 100 97.8 99.2 98 99 75-125 1 20 Chromium ug/L 1.2J 100 100 101 104 100 103 75-125 3 20 Cobalt ug/L 0.96J 100 100 101 99.9 100 99 75-125 1 20 Copper ug/L ND 100 100 101 99.7 100 99 75-125 1 20 Lead ug/L 0.51J 100 100 100 101 100 100 75-125 1 20 Nickel ug/L ND 100 100 99.4 101 99 101 75-125 2 20 Selenium ug/L ND 100 100 94.9 93.8 95 94 75-125 1 20 Silver ug/L ND 100 100 97.8 97.9 98 98 75-125 0 20 Thallium ug/L ND 100 100 98.7 99.7 99 100 75-125 1 20 Vanadium ug/L ND 100 100 101 101 99 100 75-125 1 20 Zinc ug/L 5.1J 100 100 108 108 102 102 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 57 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 QC Batch: 556523 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92487992006,92487992007,92487992008,92487992009,92487992010,92487992011,92487992012, 92487992013, 92487992014, 92487992015, 92487992016, 92487992017, 92487992018, 92487992019, 92487992020 METHOD BLANK: 2954735 Matrix: Water Associated Lab Samples: 92487992006,92487992007,92487992008,92487992009,92487992010,92487992011,92487992012, 92487992013, 92487992014, 92487992015, 92487992016, 92487992017, 92487992018, 92487992019, 92487992020 Parameter Units Blank Result Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.34 07/29/20 15:41 1,1,1-Trichloroethane ug/L ND 1.0 0.18 07/29/20 15:41 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.22 07/29/20 15:41 1,1,2-Trichloroethane ug/L ND 1.0 0.24 07/29/20 15:41 1,1-Dichloroethane ug/L ND 5.0 0.27 07/29/20 15:41 1,1-Dichloroethene ug/L ND 5.0 0.24 07/29/20 15:41 1,2,3-Trichloropropane ug/L ND 1.0 0.35 07/29/20 15:41 1,2-Dibromo-3-chloropropane ug/L ND 13.0 0.26 07/29/20 15:41 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.26 07/29/20 15:41 1,2-Dichlorobenzene ug/L ND 5.0 0.29 07/29/20 15:41 1,2-Dichloroethane ug/L ND 1.0 0.34 07/29/20 15:41 1,2-Dichloropropane ug/L ND 1.0 0.19 07/29/20 15:41 1,4-Dichlorobenzene ug/L ND 1.0 0.26 07/29/20 15:41 2-Butanone (MEK) ug/L ND 100 3.3 07/29/20 15:41 2-Hexanone ug/L ND 50.0 0.57 07/29/20 15:41 4-Methyl-2-pentanone (MIBK) ug/L ND 100 4.5 07/29/20 15:41 Acetone ug/L ND 100 6.2 07/29/20 15:41 Acrylonitrile ug/L ND 200 0.90 07/29/20 15:41 Benzene ug/L ND 1.0 0.15 07/29/20 15:41 Bromochloromethane ug/L ND 3.0 0.34 07/29/20 15:41 Bromodichloromethane ug/L ND 1.0 0.26 07/29/20 15:41 Bromoform ug/L ND 3.0 0.62 07/29/20 15:41 Bromomethane ug/L ND 10.0 0.62 07/29/20 15:41 Carbon disulfide ug/L ND 100 0.40 07/29/20 15:41 Carbon tetrachloride ug/L ND 1.0 0.22 07/29/20 15:41 Chlorobenzene ug/L ND 3.0 0.23 07/29/20 15:41 Chloroethane ug/L ND 10.0 0.49 07/29/20 15:41 Chloroform ug/L ND 5.0 2.3 07/29/20 15:41 Chloromethane ug/L ND 1.0 0.39 07/29/20 15:41 cis-1,2-Dichloroethene ug/L ND 5.0 0.29 07/29/20 15:41 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 07/29/20 15:41 Dibromochloromethane ug/L ND 3.0 0.41 07/29/20 15:41 Dibromomethane ug/L ND 10.0 0.46 07/29/20 15:41 Ethylbenzene ug/L ND 1.0 0.26 07/29/20 15:41 lodomethane ug/L ND 20.0 12.5 07/29/20 15:41 Methylene Chloride ug/L ND 5.0 3.7 07/29/20 15:41 Styrene ug/L ND 1.0 0.27 07/29/20 15:41 Qualifiers v1 IK,v1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 58 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 METHOD BLANK: 2954735 Matrix: Water Associated Lab Samples: 92487992006,92487992007,92487992008,92487992009,92487992010,92487992011,92487992012, 92487992013, 92487992014, 92487992015, 92487992016, 92487992017, 92487992018, 92487992019, 92487992020 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Tetrachloroethene ug/L ND 1.0 0.16 07/29/20 15:41 Toluene ug/L ND 1.0 0.24 07/29/20 15:41 trans-1,2-Dichloroethene ug/L ND 5.0 0.25 07/29/20 15:41 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 07/29/20 15:41 trans-1,4-Dichloro-2-butene ug/L ND 100 0.54 07/29/20 15:41 Trichloroethene ug/L ND 1.0 0.22 07/29/20 15:41 Trichlorofluoromethane ug/L ND 1.0 0.31 07/29/20 15:41 Vinyl acetate ug/L ND 50.0 1.4 07/29/20 15:41 Vinyl chloride ug/L ND 1.0 0.24 07/29/20 15:41 Xylene (Total) ug/L ND 5.0 0.63 07/29/20 15:41 1,2-Dichloroethane-d4 (S) % 105 70-130 07/29/20 15:41 4-Bromofluorobenzene (S) % 97 70-130 07/29/20 15:41 Toluene-d8 (S) % 100 70-130 07/29/20 15:41 LABORATORY CONTROL SAMPLE: Parameter 2954736 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 57.5 115 70-130 1,1,1-Trichloroethane ug/L 50 57.0 114 70-130 1,1,2,2-Tetrachloroethane ug/L 50 53.5 107 70-130 1,1,2-Trichloroethane ug/L 50 55.1 110 70-130 1,1-Dichloroethane ug/L 50 52.5 105 70-130 1,1-Dichloroethene ug/L 50 52.9 106 70-130 1,2,3-Trichloropropane ug/L 50 55.9 112 70-130 1,2-Dibromo-3-chloropropane ug/L 50 63.2 126 70-130 1,2-Dibromoethane (EDB) ug/L 50 56.4 113 70-130 1,2-Dichlorobenzene ug/L 50 56.2 112 70-130 1,2-Dichloroethane ug/L 50 54.9 110 70-130 1,2-Dichloropropane ug/L 50 54.4 109 70-130 1,4-Dichlorobenzene ug/L 50 55.4 111 70-130 2-Butanone (MEK) ug/L 100 105 105 64-135 2-Hexanone ug/L 100 106 106 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 108 108 70-130 Acetone ug/L 100 114 114 61-157 Acrylonitrile ug/L 250 273 109 61-143 Benzene ug/L 50 52.4 105 70-130 Bromochloromethane ug/L 50 53.5 107 70-130 Bromodichloromethane ug/L 50 54.0 108 70-130 Bromoform ug/L 50 59.9 120 70-130 Bromomethane ug/L 50 59.3 119 38-130 v1 Carbon disulfide ug/L 50 48.3J 97 68-130 Carbon tetrachloride ug/L 50 56.4 113 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 59 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 LABORATORY CONTROL SAMPLE: 2954736 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers Chlorobenzene ug/L 50 52.4 105 70-130 Chloroethane ug/L 50 57.7 115 37-142 IK,v1 Chloroform ug/L 50 53.5 107 70-130 Chloromethane ug/L 50 43.5 87 48-130 cis-1,2-Dichloroethene ug/L 50 52.0 104 70-130 cis-1,3-Dichloropropene ug/L 50 59.0 118 70-130 Dibromochloromethane ug/L 50 59.1 118 70-130 Dibromomethane ug/L 50 57.8 116 70-130 Ethylbenzene ug/L 50 52.5 105 70-130 Iodomethane ug/L 100 106 106 40-130 Methylene Chloride ug/L 50 49.1 98 67-132 Styrene ug/L 50 55.3 111 70-130 Tetrachloroethene ug/L 50 51.4 103 69-130 Toluene ug/L 50 53.2 106 70-130 trans-1,2-Dichloroethene ug/L 50 54.3 109 70-130 trans- 1,3-Dichloropropene ug/L 50 59.7 119 70-130 trans-1,4-Dichloro-2-butene ug/L 50 61AJ 123 35-189 Trichloroethene ug/L 50 55.0 110 70-130 Trichlorofluoromethane ug/L 50 47.5 95 63-130 Vinyl acetate ug/L 100 110 110 55-143 Vinyl chloride ug/L 50 43.7 87 70-131 Xylene (Total) ug/L 150 159 106 70-130 1,2-Dichloroethane-d4 (S) % 101 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 97 70-130 MATRIX SPIKE SAMPLE: Parameter 2954738 Units 92487992006 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 21.1 105 73-134 1,1,1-Trichloroethane ug/L ND 20 22.0 110 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 20.9 104 70-136 1,1,2-Trichloroethane ug/L ND 20 21.2 106 70-135 1,1-Dichloroethane ug/L ND 20 22.3 111 70-139 1,1-Dichloroethene ug/L ND 20 22.8 114 70-154 1,2,3-Trichloropropane ug/L ND 20 20.8 104 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 19.8 99 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 22.2 111 70-137 1,2-Dichlorobenzene ug/L ND 20 21.6 108 70-133 1,2-Dichloroethane ug/L 0.39J 20 21.0 103 70-137 1,2-Dichloropropane ug/L ND 20 22.4 112 70-140 1,4-Dichlorobenzene ug/L ND 20 21.6 108 70-133 2-Butanone (MEK) ug/L ND 40 41.8J 105 60-139 IK 2-Hexanone ug/L ND 40 41.6J 104 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 40.7J 102 65-135 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 60 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 MATRIX SPIKE SAMPLE: 2954738 92487992006 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Acetone ug/L ND 40 42.2J 105 60-148 Acrylonitrile ug/L ND 100 1011 101 64-147 Benzene ug/L 0.52J 20 22.6 110 70-151 Bromochloromethane ug/L ND 20 23.8 119 70-141 Bromodichloromethane ug/L ND 20 19.5 98 70-138 Bromoform ug/L ND 20 20.3 102 63-130 Bromomethane ug/L ND 20 17.6 88 15-152 IK,v3 Carbon disulfide ug/L ND 20 21.3J 107 69-149 Carbon tetrachloride ug/L ND 20 22.1 110 70-143 Chlorobenzene ug/L ND 20 21.5 107 70-138 Chloroethane ug/L ND 20 21.6 108 52-163 Chloroform ug/L ND 20 21.4 107 70-139 Chloromethane ug/L ND 20 17.7 89 41-139 cis-1,2-Dichloroethene ug/L 1.2J 20 23.8 113 70-141 cis-1,3-Dichloropropene ug/L ND 20 22.7 114 70-137 Dibromochloromethane ug/L ND 20 20.7 104 70-134 Dibromomethane ug/L ND 20 21.7 109 70-138 Ethylbenzene ug/L ND 20 21.6 108 66-153 Iodomethane ug/L ND 40 34.5 86 20-138 Methylene Chloride ug/L ND 20 22.1 111 42-159 Styrene ug/L ND 20 21.8 109 70-135 Tetrachloroethene ug/L ND 20 21.4 107 59-143 Toluene ug/L ND 20 21.4 107 59-148 trans-1,2-Dichloroethene ug/L ND 20 22.9 114 70-146 trans- 1,3-Dichloropropene ug/L ND 20 21.9 109 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 19.5J 98 47-135 Trichloroethene ug/L ND 20 21.8 109 70-147 Trichlorofluoromethane ug/L ND 20 19.6 98 70-148 Vinyl acetate ug/L ND 40 42.8J 107 49-151 IK Vinyl chloride ug/L ND 20 18.5 92 70-156 Xylene (Total) ug/L ND 60 65.4 109 63-158 1,2-Dichloroethane-d4 (S) % 103 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 100 70-130 SAMPLE DUPLICATE: 2954739 92487992007 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 61 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 SAMPLE DUPLICATE: 2954739 Parameter Units 92487992007 Result Dup Result RPD Max RPD Qualifiers 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 IK 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Acrylonitrile ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 301K,v2 Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 cis-1,2-Dichloroethene ug/L ND ND 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 Iodomethane ug/L ND ND 30 Methylene Chloride ug/L ND ND 30 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 Vinyl acetate ug/L ND ND 30 IK Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L ND ND 30 1,2-Dichloroethane-d4 (S) % 106 99 4-Bromofluorobenzene (S) % 96 101 Toluene-d8 (S) % 100 102 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 62 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 QC Batch: 556529 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92487992001, 92487992002, 92487992003, 92487992004, 92487992005 METHOD BLANK: 2954758 Matrix: Water Associated Lab Samples: 92487992001, 92487992002, 92487992003, 92487992004, 92487992005 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.34 07/30/20 00:03 1,1,1-Trichloroethane ug/L ND 1.0 0.18 07/30/20 00:03 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.22 07/30/20 00:03 1,1,2-Trichloroethane ug/L ND 1.0 0.24 07/30/20 00:03 1,1-Dichloroethane ug/L ND 5.0 0.27 07/30/20 00:03 1,1-Dichloroethene ug/L ND 5.0 0.24 07/30/20 00:03 1,2,3-Trichloropropane ug/L ND 1.0 0.35 07/30/20 00:03 1,2-Dibromo-3-chloropropane ug/L ND 13.0 0.26 07/30/20 00:03 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.26 07/30/20 00:03 1,2-Dichlorobenzene ug/L ND 5.0 0.29 07/30/20 00:03 1,2-Dichloroethane ug/L ND 1.0 0.34 07/30/20 00:03 1,2-Dichloropropane ug/L ND 1.0 0.19 07/30/20 00:03 1,4-Dichlorobenzene ug/L ND 1.0 0.26 07/30/20 00:03 2-Butanone (MEK) ug/L ND 100 3.3 07/30/20 00:03 2-Hexanone ug/L ND 50.0 0.57 07/30/20 00:03 4-Methyl-2-pentanone (MIBK) ug/L ND 100 4.5 07/30/20 00:03 Acetone ug/L ND 100 6.2 07/30/20 00:03 Acrylonitrile ug/L ND 200 0.90 07/30/20 00:03 Benzene ug/L ND 1.0 0.15 07/30/20 00:03 Bromochloromethane ug/L ND 3.0 0.34 07/30/20 00:03 Bromodichloromethane ug/L ND 1.0 0.26 07/30/20 00:03 Bromoform ug/L ND 3.0 0.62 07/30/20 00:03 Bromomethane ug/L ND 10.0 0.62 07/30/20 00:03 Carbon disulfide ug/L ND 100 0.40 07/30/20 00:03 Carbon tetrachloride ug/L ND 1.0 0.22 07/30/20 00:03 Chlorobenzene ug/L ND 3.0 0.23 07/30/20 00:03 Chloroethane ug/L ND 10.0 0.49 07/30/20 00:03 Chloroform ug/L ND 5.0 2.3 07/30/20 00:03 Chloromethane ug/L ND 1.0 0.39 07/30/20 00:03 cis-1,2-Dichloroethene ug/L ND 5.0 0.29 07/30/20 00:03 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 07/30/20 00:03 Dibromochloromethane ug/L ND 3.0 0.41 07/30/20 00:03 Dibromomethane ug/L ND 10.0 0.46 07/30/20 00:03 Ethylbenzene ug/L ND 1.0 0.26 07/30/20 00:03 lodomethane ug/L ND 20.0 12.5 07/30/20 00:03 IL Methylene Chloride ug/L ND 5.0 3.7 07/30/20 00:03 Styrene ug/L ND 1.0 0.27 07/30/20 00:03 Tetrachloroethene ug/L ND 1.0 0.16 07/30/20 00:03 Toluene ug/L ND 1.0 0.24 07/30/20 00:03 trans-1,2-Dichloroethene ug/L ND 5.0 0.25 07/30/20 00:03 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 63 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 METHOD BLANK: 2954758 Matrix: Water Associated Lab Samples: 92487992001, 92487992002, 92487992003, 92487992004, 92487992005 Blank Reporting Parameter Units Result Limit MDL Analyzed trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 07/30/20 00:03 trans-1,4-Dichloro-2-butene ug/L ND 100 0.54 07/30/20 00:03 Trichloroethene ug/L ND 1.0 0.22 07/30/20 00:03 Trichlorofluoromethane ug/L ND 1.0 0.31 07/30/20 00:03 Vinyl acetate ug/L ND 50.0 1.4 07/30/20 00:03 Vinyl chloride ug/L ND 1.0 0.24 07/30/20 00:03 Xylene (Total) ug/L ND 5.0 0.63 07/30/20 00:03 1,2-Dichloroethane-d4 (S) % 99 70-130 07/30/20 00:03 4-Bromofluorobenzene (S) % 103 70-130 07/30/20 00:03 Toluene-d8 (S) % 103 70-130 07/30/20 00:03 LABORATORY CONTROL SAMPLE: Parameter 2954759 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 55.2 110 70-130 1,1,1-Trichloroethane ug/L 50 52.8 106 70-130 1,1,2,2-Tetrachloroethane ug/L 50 55.8 112 70-130 1,1,2-Trichloroethane ug/L 50 54.8 110 70-130 1,1-Dichloroethane ug/L 50 53.3 107 70-130 1,1-Dichloroethene ug/L 50 54.2 108 70-130 1,2,3-Trichloropropane ug/L 50 56.0 112 70-130 1,2-Dibromo-3-chloropropane ug/L 50 59.0 118 70-130 1,2-Dibromoethane (EDB) ug/L 50 56.5 113 70-130 1,2-Dichlorobenzene ug/L 50 52.1 104 70-130 1,2-Dichloroethane ug/L 50 51.6 103 70-130 1,2-Dichloropropane ug/L 50 53.5 107 70-130 1,4-Dichlorobenzene ug/L 50 51.1 102 70-130 2-Butanone (MEK) ug/L 100 118 118 64-135 2-Hexanone ug/L 100 114 114 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 111 111 70-130 Acetone ug/L 100 115 115 61-157 Acrylonitrile ug/L 250 260 104 61-143 Benzene ug/L 50 51.0 102 70-130 Bromochloromethane ug/L 50 54.7 109 70-130 Bromodichloromethane ug/L 50 48.3 97 70-130 Bromoform ug/L 50 55.5 111 70-130 Bromomethane ug/L 50 52.9 106 38-130 Carbon disulfide ug/L 50 50.9J 102 68-130 Carbon tetrachloride ug/L 50 51.3 103 70-130 Chlorobenzene ug/L 50 51.4 103 70-130 Chloroethane ug/L 50 51.7 103 37-142 Chloroform ug/L 50 52.3 105 70-130 Chloromethane ug/L 50 46.1 92 48-130 cis-1,2-Dichloroethene ug/L 50 52.3 105 70-130 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 64 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 LABORATORY CONTROL SAMPLE: Parameter 2954759 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 57.5 115 70-130 Dibromochloromethane ug/L 50 56.8 114 70-130 Dibromomethane ug/L 50 54.0 108 70-130 Ethylbenzene ug/L 50 50.7 101 70-130 lodomethane ug/L 100 102 102 40-130IL Methylene Chloride ug/L 50 51.8 104 67-132 Styrene ug/L 50 53.1 106 70-130 Tetrachloroethene ug/L 50 51.1 102 69-130 Toluene ug/L 50 49.8 100 70-130 trans-1,2-Dichloroethene ug/L 50 53.3 107 70-130 trans- 1,3-Dichloropropene ug/L 50 56.0 112 70-130 trans-1,4-Dichloro-2-butene ug/L 50 55.1J 110 35-189 Trichloroethene ug/L 50 52.1 104 70-130 Trichlorofluoromethane ug/L 50 50.2 100 63-130 Vinyl acetate ug/L 100 117 117 55-143 Vinyl chloride ug/L 50 50.8 102 70-131 Xylene (Total) ug/L 150 153 102 70-130 1,2-Dichloroethane-d4 (S) % 100 70-130 4-Bromofluorobenzene (S) % 101 70-130 Toluene-d8 (S) % 98 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2954760 MS 92487993016 Spike Parameter Units Result Conc. MSD Spike Conc. 2954761 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 20.8 20.0 104 100 73-134 4 30 1,1,1-Trichloroethane ug/L ND 20 20 21.9 21.2 109 106 82-143 3 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 21.1 19.4 106 97 70-136 8 30 1,1,2-Trichloroethane ug/L ND 20 20 21.0 20.5 105 102 70-135 3 30 1,1-Dichloroethane ug/L ND 20 20 21.5 21.2 108 106 70-139 1 30 1,1-Dichloroethene ug/L ND 20 20 22.3 21.9 112 109 70-154 2 30 1,2,3-Trichloropropane ug/L ND 20 20 20.7 19.8 103 99 71-137 4 30 1,2-Dibromo-3- ug/L ND 20 20 20.9 19.4 104 97 65-134 8 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 21.1 20.2 105 101 70-137 4 30 1,2-Dichlorobenzene ug/L ND 20 20 20.6 19.5 103 98 70-133 6 30 1,2-Dichloroethane ug/L ND 20 20 20.8 19.8 104 99 70-137 5 30 1,2-Dichloropropane ug/L ND 20 20 21.6 20.8 108 104 70-140 4 30 1,4-Dichlorobenzene ug/L ND 20 20 20.7 19.2 103 96 70-133 7 30 2-Butanone (MEK) ug/L ND 40 40 44AJ 42.7J 111 107 60-139 4 30 2-Hexanone ug/L ND 40 40 41.7J 38.7J 104 97 65-138 8 30 4-Methyl-2-pentanone ug/L ND 40 40 41.7J 39.OJ 104 98 65-135 7 30 (MIBK) Acetone ug/L ND 40 40 42.5J 41.1J 106 103 60-148 3 30 Acrylonitrile ug/L ND 100 100 1011 98.5J 101 99 64-147 2 30 Benzene ug/L ND 20 20 21.0 20.2 105 101 70-151 4 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 65 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2954760 MS 92487993016 Spike Parameter Units Result Conc. MSD Spike Conc. 2954761 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Bromochloromethane ug/L ND 20 20 22.4 21.3 112 107 70-141 5 30 Bromodichloromethane ug/L ND 20 20 19.1 18.3 96 92 70-138 4 30 Bromoform ug/L ND 20 20 19.9 18.7 100 93 63-130 6 30 Bromomethane ug/L ND 20 20 27.5 26.6 138 133 15-152 4 30 Carbon disulfide ug/L ND 20 20 21.6J 20.9J 108 105 69-149 3 30 Carbon tetrachloride ug/L ND 20 20 21.0 20.9 105 104 70-143 1 30 Chlorobenzene ug/L ND 20 20 20.7 19.3 103 96 70-138 7 30 Chloroethane ug/L ND 20 20 24.0 23.8 120 119 52-163 1 30 Chloroform ug/L ND 20 20 21.1 20.8 106 104 70-139 1 30 Chloromethane ug/L ND 20 20 19.3 18.8 97 94 41-139 2 30 cis-1,2-Dichloroethene ug/L ND 20 20 21.2 20.7 106 103 70-141 2 30 cis-1,3-Dichloropropene ug/L ND 20 20 22.4 21.5 112 108 70-137 4 30 Dibromochloromethane ug/L ND 20 20 20.9 19.5 104 97 70-134 7 30 Dibromomethane ug/L ND 20 20 20.7 19.8 104 99 70-138 4 30 Ethylbenzene ug/L ND 20 20 20.5 19.5 103 98 66-153 5 30 lodomethane ug/L ND 40 40 37.0 35.2 93 88 20-138 5 30 IL Methylene Chloride ug/L ND 20 20 21.6 20.4 108 102 42-159 5 30 Styrene ug/L ND 20 20 21.2 20.0 106 100 70-135 6 30 Tetrachloroethene ug/L ND 20 20 19.7 19.1 99 95 59-143 3 30 Toluene ug/L ND 20 20 20.4 19.4 102 97 59-148 5 30 trans-1,2-Dichloroethene ug/L ND 20 20 21.8 21.5 109 108 70-146 1 30 trans-1,3-Dichloropropene ug/L ND 20 20 21.5 20.4 107 102 70-135 5 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 16.2J 16.7J 81 83 47-135 3 30 Trichloroethene ug/L ND 20 20 21.1 20.6 106 103 70-147 2 30 Trichlorofluoromethane ug/L ND 20 20 20.9 21.2 105 106 70-148 1 30 Vinyl acetate ug/L ND 40 40 43.6J 41.5J 109 104 49-151 5 30 Vinyl chloride ug/L ND 20 20 21.1 20.6 106 103 70-156 2 30 Xylene (Total) ug/L ND 60 60 61.6 58.6 103 98 63-158 5 30 1,2-Dichloroethane-d4 (S) % 99 97 70-130 4-Bromofluorobenzene (S) % 103 104 70-130 Toluene-d8 (S) % 99 98 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2955928 2955929 MS MSD 92487992004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1, 1, 1,2-Tetrachloroethane ug/L ND 20 20 19.8 20.6 99 103 73-134 4 30 1,1,1-Trichloroethane ug/L ND 20 20 21.5 21.5 107 107 82-143 0 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 20.3 20.2 102 101 70-136 1 30 1,1,2-Trichloroethane ug/L ND 20 20 20.3 20.9 102 105 70-135 3 30 1,1-Dichloroethane ug/L ND 20 20 21.9 21.8 109 109 70-139 0 30 1,1-Dichloroethene ug/L ND 20 20 22.6 22.4 113 112 70-154 1 30 1,2,3-Trichloropropane ug/L ND 20 20 20.3 19.9 101 100 71-137 2 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 66 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2955928 2955929 MS MSD 92487992004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,2-Dibromo-3- ug/L ND 20 20 20.2 20.4 101 102 65-134 1 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 20.6 20.1 103 101 70-137 2 30 1,2-Dichlorobenzene ug/L ND 20 20 19.8 20.2 99 101 70-133 2 30 1,2-Dichloroethane ug/L ND 20 20 20.4 20.0 102 100 70-137 2 30 1,2-Dichloropropane ug/L ND 20 20 21.2 21.1 106 105 70-140 1 30 1,4-Dichlorobenzene ug/L ND 20 20 20.2 20.0 101 100 70-133 1 30 2-Butanone (MEK) ug/L ND 40 40 44.3J 43.5J 111 109 60-139 2 30 2-Hexanone ug/L ND 40 40 40.2J 40.3J 101 101 65-138 0 30 4-Methyl-2-pentanone ug/L ND 40 40 39.6J 40.6J 99 102 65-135 2 30 (MIBK) Acetone ug/L ND 40 40 44AJ 43.7J 111 109 60-148 2 30 Acrylonitrile ug/L ND 100 100 1001 1011 100 101 64-147 0 30 Benzene ug/L ND 20 20 20.3 20.5 101 103 70-151 1 30 Bromochloromethane ug/L ND 20 20 22.0 22.2 110 111 70-141 1 30 Bromodichloromethane ug/L ND 20 20 18.3 19.1 92 95 70-138 4 30 Bromoform ug/L ND 20 20 19.0 19.3 95 96 63-130 2 30 Bromomethane ug/L ND 20 20 25.8 26.2 129 131 15-152 2 30 Carbon disulfide ug/L ND 20 20 21.7J 21.3J 108 107 69-149 2 30 Carbon tetrachloride ug/L ND 20 20 20.9 20.9 105 104 70-143 0 30 Chlorobenzene ug/L ND 20 20 20.1 20.0 101 100 70-138 1 30 Chloroethane ug/L ND 20 20 24.0 23.8 120 119 52-163 1 30 Chloroform ug/L ND 20 20 20.9 21.0 105 105 70-139 0 30 Chloromethane ug/L ND 20 20 19.4 19.4 97 97 41-139 0 30 cis-1,2-Dichloroethene ug/L ND 20 20 21.1 21.3 105 107 70-141 1 30 cis-1,3-Dichloropropene ug/L ND 20 20 21.7 22.1 109 110 70-137 1 30 Dibromochloromethane ug/L ND 20 20 20.3 20.5 101 102 70-134 1 30 Dibromomethane ug/L ND 20 20 20.1 20.1 101 101 70-138 0 30 Ethylbenzene ug/L ND 20 20 20.2 20.2 101 101 66-153 0 30 lodomethane ug/L ND 40 40 36.5 36.6 91 92 20-138 0 30 IL Methylene Chloride ug/L ND 20 20 21.1 21.0 105 105 42-159 0 30 Styrene ug/L ND 20 20 20.5 20.6 102 103 70-135 1 30 Tetrachloroethene ug/L ND 20 20 19.5 19.3 97 97 59-143 1 30 Toluene ug/L ND 20 20 19.9 20.0 100 100 59-148 1 30 trans-1,2-Dichloroethene ug/L ND 20 20 22.1 21.8 111 109 70-146 1 30 trans-1,3-Dichloropropene ug/L ND 20 20 20.5 21.0 103 105 70-135 2 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 17.1J 17.6J 86 88 47-135 3 30 Trichloroethene ug/L ND 20 20 20.7 21.2 103 106 70-147 2 30 Trichlorofluoromethane ug/L ND 20 20 21.4 21.1 107 106 70-148 1 30 Vinyl acetate ug/L ND 40 40 42.5J 42.1J 106 105 49-151 1 30 Vinyl chloride ug/L ND 20 20 21.2 21.6 106 108 70-156 2 30 Xylene (Total) ug/L ND 60 60 59.9 60.5 100 101 63-158 1 30 1,2-Dichloroethane-d4 (S) % 102 98 70-130 4-Bromofluorobenzene (S) % 102 103 70-130 Toluene-d8 (S) % 98 99 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 67 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 QC Batch: 557603 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92487992021 METHOD BLANK: 2959471 Associated Lab Samples: 92487992021 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.34 07/29/20 11:53 1,1,1-Trichloroethane ug/L ND 1.0 0.18 07/29/20 11:53 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.22 07/29/20 11:53 1,1,2-Trichloroethane ug/L ND 1.0 0.24 07/29/20 11:53 1,1-Dichloroethane ug/L ND 5.0 0.27 07/29/20 11:53 1,1-Dichloroethene ug/L ND 5.0 0.24 07/29/20 11:53 1,2,3-Trichloropropane ug/L ND 1.0 0.35 07/29/20 11:53 1,2-Dibromo-3-chloropropane ug/L ND 13.0 0.26 07/29/20 11:53 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.26 07/29/20 11:53 1,2-Dichlorobenzene ug/L ND 5.0 0.29 07/29/20 11:53 1,2-Dichloroethane ug/L ND 1.0 0.34 07/29/20 11:53 1,2-Dichloropropane ug/L ND 1.0 0.19 07/29/20 11:53 1,4-Dichlorobenzene ug/L ND 1.0 0.26 07/29/20 11:53 2-Butanone (MEK) ug/L ND 100 3.3 07/29/20 11:53 2-Hexanone ug/L ND 50.0 0.57 07/29/20 11:53 4-Methyl-2-pentanone (MIBK) ug/L ND 100 4.5 07/29/20 11:53 Acetone ug/L ND 100 6.2 07/29/20 11:53 Acrylonitrile ug/L ND 200 0.90 07/29/20 11:53 Benzene ug/L ND 1.0 0.15 07/29/20 11:53 Bromochloromethane ug/L ND 3.0 0.34 07/29/20 11:53 Bromodichloromethane ug/L ND 1.0 0.26 07/29/20 11:53 Bromoform ug/L ND 3.0 0.62 07/29/20 11:53 Bromomethane ug/L ND 10.0 0.62 07/29/20 11:53 Carbon disulfide ug/L ND 100 0.40 07/29/20 11:53 Carbon tetrachloride ug/L ND 1.0 0.22 07/29/20 11:53 Chlorobenzene ug/L ND 3.0 0.23 07/29/20 11:53 Chloroethane ug/L ND 10.0 0.49 07/29/20 11:53 Chloroform ug/L ND 5.0 2.3 07/29/20 11:53 Chloromethane ug/L ND 1.0 0.39 07/29/20 11:53 cis-1,2-Dichloroethene ug/L ND 5.0 0.29 07/29/20 11:53 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 07/29/20 11:53 Dibromochloromethane ug/L ND 3.0 0.41 07/29/20 11:53 Dibromomethane ug/L ND 10.0 0.46 07/29/20 11:53 Ethylbenzene ug/L ND 1.0 0.26 07/29/20 11:53 lodomethane ug/L ND 20.0 12.5 07/29/20 11:53 Methylene Chloride ug/L ND 5.0 3.7 07/29/20 11:53 Styrene ug/L ND 1.0 0.27 07/29/20 11:53 Tetrachloroethene ug/L ND 1.0 0.16 07/29/20 11:53 Toluene ug/L ND 1.0 0.24 07/29/20 11:53 trans-1,2-Dichloroethene ug/L ND 5.0 0.25 07/29/20 11:53 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 68 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 METHOD BLANK: 2959471 Associated Lab Samples: 92487992021 Parameter Units Matrix: Blank Result Water Reporting Limit MDL trans- 1,3-Dichloropropene ug/L ND 1.0 trans-1,4-Dichloro-2-butene ug/L ND 100 Trichloroethene ug/L ND 1.0 Trichlorofluoromethane ug/L ND 1.0 Vinyl acetate ug/L ND 50.0 Vinyl chloride ug/L ND 1.0 Xylene (Total) ug/L ND 5.0 1,2-Dichloroethane-d4 (S) % 96 70-130 4-Bromofluorobenzene (S) % 102 70-130 Toluene-d8 (S) % 86 70-130 Analyzed 0.31 07/29/20 11:53 0.54 07/29/20 11:53 0.22 07/29/20 11:53 0.31 07/29/20 11:53 1.4 07/29/20 11:53 0.24 07/29/20 11:53 0.63 07/29/20 11:53 07/29/20 11:53 07/29/20 11:53 07/29/20 11:53 LABORATORY CONTROL SAMPLE: Parameter 2959472 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 50.1 100 70-130 1,1,1-Trichloroethane ug/L 50 53.8 108 70-130 1,1,2,2-Tetrachloroethane ug/L 50 50.9 102 70-130 1,1,2-Trichloroethane ug/L 50 49.6 99 70-130 1,1-Dichloroethane ug/L 50 53.5 107 70-130 1,1-Dichloroethene ug/L 50 53.9 108 70-130 1,2,3-Trichloropropane ug/L 50 51.2 102 70-130 1,2-Dibromo-3-chloropropane ug/L 50 54.2 108 70-130 1,2-Dibromoethane (EDB) ug/L 50 50.5 101 70-130 1,2-Dichlorobenzene ug/L 50 53.5 107 70-130 1,2-Dichloroethane ug/L 50 44.8 90 70-130 1,2-Dichloropropane ug/L 50 48.8 98 70-130 1,4-Dichlorobenzene ug/L 50 49.5 99 70-130 2-Butanone (MEK) ug/L 100 112 112 64-135 2-Hexanone ug/L 100 92.4 92 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 93.9J 94 70-130 Acetone ug/L 100 106 106 61-157 Acrylonitrile ug/L 250 256 102 61-143 Benzene ug/L 50 46.6 93 70-130 Bromochloromethane ug/L 50 55.8 112 70-130 Bromodichloromethane ug/L 50 45.3 91 70-130 Bromoform ug/L 50 50.5 101 70-130 Bromomethane ug/L 50 53.7 107 38-130 Carbon disulfide ug/L 50 50.2J 100 68-130 Carbon tetrachloride ug/L 50 51.1 102 70-130 Chlorobenzene ug/L 50 48.7 97 70-130 Chloroethane ug/L 50 47.1 94 37-142 Chloroform ug/L 50 54.3 109 70-130 Chloromethane ug/L 50 46.4 93 48-130 cis-1,2-Dichloroethene ug/L 50 53.7 107 70-130 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 69 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 LABORATORY CONTROL SAMPLE: Parameter 2959472 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 52.6 105 70-130 Dibromochloromethane ug/L 50 50.8 102 70-130 Dibromomethane ug/L 50 51.4 103 70-130 Ethylbenzene ug/L 50 47.8 96 70-130 lodomethane ug/L 100 83.2 83 40-130 Methylene Chloride ug/L 50 52.2 104 67-132 Styrene ug/L 50 50.1 100 70-130 Tetrachloroethene ug/L 50 48.1 96 69-130 Toluene ug/L 50 46.6 93 70-130 trans-1,2-Dichloroethene ug/L 50 54.3 109 70-130 trans- 1,3-Dichloropropene ug/L 50 51.3 103 70-130 trans-1,4-Dichloro-2-butene ug/L 50 48.7J 97 35-189 Trichloroethene ug/L 50 49.1 98 70-130 Trichlorofluoromethane ug/L 50 48.4 97 63-130 Vinyl acetate ug/L 100 110 110 55-143 Vinyl chloride ug/L 50 45.9 92 70-131 Xylene (Total) ug/L 150 145 97 70-130 1,2-Dichloroethane-d4 (S) % 93 70-130 4-Bromofluorobenzene (S) % 104 70-130 Toluene-d8 (S) % 99 70-130 MATRIX SPIKE SAMPLE: Parameter 2959473 Units 92487991001 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 22.0 110 73-134 1,1,1-Trichloroethane ug/L ND 20 20.9 104 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 21.6 108 70-136 1,1,2-Trichloroethane ug/L ND 20 20.7 104 70-135 1,1-Dichloroethane ug/L ND 20 20.7 104 70-139 1,1-Dichloroethene ug/L ND 20 21.5 107 70-154 1,2,3-Trichloropropane ug/L ND 20 21.5 108 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 23.2 116 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 21.8 109 70-137 1,2-Dichlorobenzene ug/L ND 20 20.9 104 70-133 1,2-Dichloroethane ug/L ND 20 19.8 99 70-137 1,2-Dichloropropene ug/L ND 20 21.2 106 70-140 1,4-Dichlorobenzene ug/L ND 20 21.0 105 70-133 2-Butanone (MEK) ug/L ND 40 44AJ 111 60-139 2-Hexanone ug/L ND 40 44.2J 111 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 42.OJ 105 65-135 Acetone ug/L ND 40 41.1J 103 60-148 Acrylonitrile ug/L ND 100 99.01 99 64-147 Benzene ug/L ND 20 20.4 102 70-151 Bromochloromethane ug/L ND 20 20.9 104 70-141 Bromodichloromethane ug/L ND 20 19.6 98 70-138 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 70 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 MATRIX SPIKE SAMPLE: Parameter 2959473 Units 92487991001 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers Bromoform ug/L ND 20 22.4 112 63-130 Bromomethane ug/L ND 20 19.9 99 15-152 Carbon disulfide ug/L ND 20 19.91 99 69-149 Carbon tetrachloride ug/L ND 20 21.5 107 70-143 Chlorobenzene ug/L ND 20 21.1 106 70-138 Chloroethane ug/L ND 20 22.0 110 52-163 Chloroform ug/L ND 20 20.3 102 70-139 Chloromethane ug/L ND 20 19.1 95 41-139 v1 cis-1,2-Dichloroethene ug/L ND 20 20.5 103 70-141 cis-1,3-Dichloropropene ug/L ND 20 22.4 112 70-137 Dibromochloromethane ug/L ND 20 22.8 114 70-134 Dibromomethane ug/L ND 20 20.2 101 70-138 Ethylbenzene ug/L ND 20 20.9 104 66-153 lodomethane ug/L ND 40 32.4 81 20-1381K Methylene Chloride ug/L ND 20 20.4 102 42-159 Styrene ug/L ND 20 21.7 108 70-135 Tetrachloroethene ug/L ND 20 20.2 101 59-143 Toluene ug/L ND 20 20.1 101 59-148 trans-1,2-Dichloroethene ug/L ND 20 20.7 103 70-146 trans- 1,3-Dichloropropene ug/L ND 20 21.5 108 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 19.8J 99 47-135 Trichloroethene ug/L ND 20 20.6 103 70-147 Trichlorofluoromethane ug/L ND 20 19.9 99 70-148 Vinyl acetate ug/L ND 40 41.2J 103 49-151 Vinyl chloride ug/L ND 20 19.5 98 70-156 Xylene (Total) ug/L ND 60 62.8 105 63-158 1,2-Dichloroethane-d4 (S) % 101 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 96 70-130 SAMPLE DUPLICATE: 2959474 Parameter Units 92487991002 Result Dup Result RPD Max RPD 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropene ug/L ND ND 30 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 71 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 SAMPLE DUPLICATE: 2959474 Parameter Units 92487991002 Result Dup Result RPD Max RPD 1,4-Dichlorobenzene ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Acrylonitrile ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 30 Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 v1 cis-1,2-Dichloroethene ug/L ND ND 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 lodomethane ug/L ND ND 301K Methylene Chloride ug/L ND ND 30 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 Vinyl acetate ug/L ND ND 30 Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L ND ND 30 1,2-Dichloroethane-d4 (S) % 93 99 4-Bromofluorobenzene (S) % 101 102 Toluene-d8 (S) % 83 100 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 72 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. IL This analyte exceeded secondary source verification criteria low for the initial calibration. The reported results should be considered an estimated value. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 73 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Foothills LF/Semi-Annual-Revised Report 92487992 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92487992001 1403-MW-1R2 556882 92487992002 1403-MW-2R 556882 92487992003 1403-MW-3R2 556882 92487992004 1403-MW-4 556882 92487992006 1403-MW-5 556882 92487992007 1403-MW-6 556882 92487992008 1403-MW-7 556882 92487992009 1403-MW-8 556882 92487992010 1403-MW-9 556882 92487992011 1403-MW-10 556882 92487992012 1403-MW-11 556882 92487992014 1403-SW 1 556882 92487992015 1403-SW 2 556882 92487992016 1403-SW 3 556882 92487992017 1403-SW 4 556882 92487992018 1403-SW 5 556882 92487992019 1403-U D 1 556882 92487992020 1403-U D 2 556882 92487992001 1403-MW-1R2 EPA 3005A 556270 EPA 6020B 556299 92487992002 1403-MW-2R EPA 3005A 556270 EPA 6020B 556299 92487992003 1403-MW-3R2 EPA 3005A 556270 EPA 6020B 556299 92487992004 1403-MW-4 EPA 3005A 556270 EPA 6020B 556299 92487992005 1403-Dup@MW-2R EPA 3005A 556270 EPA 6020B 556299 92487992006 1403-MW-5 EPA 3005A 556270 EPA 6020B 556299 92487992007 1403-MW-6 EPA 3005A 556270 EPA 6020B 556299 92487992008 1403-MW-7 EPA 3005A 556270 EPA 6020B 556299 92487992009 1403-MW-8 EPA 3005A 556270 EPA 6020B 556299 92487992010 1403-MW-9 EPA 3005A 556270 EPA 6020B 556299 92487992011 1403-MW-10 EPA 3005A 556270 EPA 6020B 556299 92487992012 1403-MW-11 EPA 3005A 556270 EPA 6020B 556299 92487992013 1403-Field Blank EPA 3005A 556270 EPA 6020B 556299 92487992014 1403-SW 1 EPA 3005A 556270 EPA 6020B 556299 92487992015 1403-SW 2 EPA 3005A 556322 EPA 6020B 556587 92487992016 1403-SW 3 EPA 3005A 556322 EPA 6020B 556587 92487992017 1403-SW 4 EPA 3005A 556322 EPA 6020B 556587 92487992018 1403-SW 5 EPA 3005A 556322 EPA 6020B 556587 92487992019 1403-U D 1 EPA 3005A 556322 EPA 6020B 556587 92487992020 1403-U D 2 EPA 3005A 556322 EPA 6020B 556587 92487992001 1403-MW-1R2 EPA 8260D 556529 92487992002 1403-MW-2R EPA 8260D 556529 92487992003 1403-MW-3R2 EPA 8260D 556529 92487992004 1403-MW-4 EPA 8260D 556529 92487992005 1403-Dup@MW-2R EPA 8260D 556529 92487992006 1403-MW-5 EPA 8260D 556523 92487992007 1403-MW-6 EPA 8260D 556523 92487992008 1403-MW-7 EPA 8260D 556523 92487992009 1403-MW-8 EPA 8260D 556523 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/29/2020 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 74 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Foothills LF/Semi-Annual-Revised Report Pace Project No.: 92487992 Lab ID Sample ID QC Batch Method QC Batch 92487992010 1403-MW-9 EPA 8260D 556523 92487992011 1403-MW-10 EPA 8260D 556523 92487992012 1403-MW-11 EPA 8260D 556523 92487992013 1403-Field Blank EPA 8260D 556523 92487992014 1403-SW 1 EPA 8260D 556523 92487992015 1403-SW 2 EPA 8260D 556523 92487992016 1403-SW 3 EPA 8260D 556523 92487992017 1403-SW 4 EPA 8260D 556523 92487992018 1403-SW 5 EPA 8260D 556523 92487992019 1403-UD 1 EPA 8260D 556523 92487992020 1403-UD 2 EPA 8260D 556523 92487992021 1403-Trip Blank EPA 8260D 557603 Date: 09/29/2020 05:00 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Method Analytical Batch Page 75 of 99 �i Co��vJ��s��s.lJ� m m n m Q� t h O o 0 m m 2 v i m +V V v N N v N N �V N N N `m rn `m 1 4 a ,... m , v �s , y� V v g c r� o z CL D N *`? �► N N N N N N N N m W o a m p ;, oz 0 v G d O G 0� p G d r� o m rn CAna�� { N J O p �- aA p a o m m 1a S p a z z 4 0 O � i .O l O ,.= m O y RI v N N LD J O N = m m m o cc 0 mIn � 5. x m v ■ `ar Z m C -: �coc> m >< Ix >< >< >< >< >< X X >< >< oo a M c, a' J& 44 P-. w �' 0 0 0 0 00 CD CA) (A)W (A)W CA) (A)W i CA) m p C y o O In W i , C s 1 4 W o . uM, ° o co flo rn cn z w z ` a'� z A �• A �� �nzmz-a�zot� oo$ 00g I �m� D 6- CO = =m X x x x >< x x x >< >< >c APPENDIX I- VOC BY 8260ooCog >< >< >< >< >< >< >< >< >< >< >C APPENDIX I- METALS w � -i G)m -4 j 'V com m m + I OO O N p w q�I m ft Roll T L ... IM .. 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CQ y+ �� t?1•, � � :ODD C r E �+ �.ic��� m a i m�aC-I;K m;a C 0 1 mz G) m Z x g m>E 2 o ;a z x r 13 r > Cl) fA -0rDmf1)0 N ZZ Z pSpC &N O O i � RM v m '- Q li c Z Page Z c CO) O v m O v � 1n Qo y �D a+ 0 02 0 a 4 � ��.. v nn O (�7 n e m o QO g m 5 n o � � N Co M N a r 04 QD' �7 of 99 Sample Condition Upon I -Receipt !Zm"cal Client Name: CPA Project # Courier: ed Ex ❑ UPS ❑ USPS ❑ Client ❑ Commercial ❑ Paces Other wog : 92487992 TrackingVF i PM: MP Due Date: oe/aG/2e Custody Seal on Cooler/Box Present: 0, yes 0 no Seals intact: ; ❑yes CLIENT: cIVepNC Packing Material: ❑ Bubble Wrap Bubble Bags ❑ None ❑ Other Thermometer Used 2 Type of Ice: Rett) Blue None ❑ Samoles on ice, coolina Drocess has begun L' Cooler Temperature Q'% Biological Tissue is Frozen: Yes No Temp should be above freezing to 6°C Comme Date and Initials of person examinin contents, �9 Chain of Custody Present: Yes ❑No ❑NIA 1. Chain of Custody Filled Out: 11Yes ❑No ❑NIA 2. Chain of Custody Relinquished: OYes ONO ❑NIA 3. Sampler Name & Signature on COC: 16Yes ❑N° ❑NIA a. Sam les Arrived within Hold Time: Yes ❑N° ❑NIA 5, Short Hold Time Mal is <72hr : ❑Yes &� ❑NIA 6. Rush Turn Around Time Requested: Yes No ❑NIA 7. Sufficient Volume: Jr.)❑No ❑NIA 8. Correct Containers Used: Y'Ves ONO ❑NIA -Pace Containers Used: Yes ONO ❑NIA 9. Containers Intact: $Yes ONO ❑NIA 10. Filtered volume received for Dissolved tests ❑Yes ONO NrA 11. Sample Labels match COC: /Yes ONO ❑NIA -Includes dateltime11D1Analysis Matrix: i 12. All containers needing preservation have been checked. Yes []No ❑NIA All containers needing preservation are found to be in �Y-s ONO ❑NIA compliance with EPA recommendation. exceptions: VOA, coliform, TOC. 0&G, wl-DRO (watery ❑Yes ❑N0 i 13. Initial when complete Lot # of added preservative :Samples checked for dechlorination: ❑Yes ONO NIA ! 14, I Headspace in VOA Vials >6mm : ❑Yes ONO NIA 15. Trip Blank Present: [,Yes [:]No ❑N/A Trip Blank Custody Seals Present l�Yes ONO ❑NIA Pace Trip Blank Lot All if purchased): 16. Client Notificationt Resolution: Person Contacted: DatelTime: Comments/ Resolution: Field Data Required? Y 1 N Project Manager Review: Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( Le out of hold, incorrect preservative, out of temp, incorrect containers F-ALLCD03rev.3, 11SeptembFp of 99 SITE NAME: FOOTHILLS LF POINT ID: FIELD BLANK LOCATION: SAMPLE MATRIX: EVACUATION INF LENOIR, NORTH CAROLINA ❑EIONIZED WATER INITIAL VOAT EVEL (FT} ELEV., MEAS. PT. (MSL): DATE METHOD OF EVACUATION: { } PVC BAILER { } S.S. BAILER } S.S. BAILER ( ) QED PUMP WELL RISER DIAMETER (IN.): ( } 2 ONE (1) RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA LAB SAMPLE 1 PROJECT #: ( } GRUNDFOS ( } OTHER ( } 3 ( ) 4 ES&8-R.CHIODO NA DEPTH TO BOTTOM (FT) ELEVATION, GIW (MSL): TIME; STARTIFINISH 1 EVACUATION EQUIPMENT DEDICATED: ( ) YES ( ) NO ( )6 ( )OT VITAS WELL PURGED TO DR WATER LEVEL END PURGE FINISH ( ) YES ( ) NO ■ f SAMPLING INFORMATION DATE1TIME t7-2'0 20 1 'S`lS7 METHOD OF SAMPLING: ( } PVC BAILER ( } S.S. BAILER ( } S.S. BAILER ( } QED PUMP SAMPLING FIELD MEASUREMENT DATA DEPTH TO GROUNDWATER (FTC NA SAMPLING EQUIPMENT DEDICATED: ( } GRUNDFOS PUMP ( } YES ( ) OTHER ( ) NO TIME pH Std.Units TEMP. C CONDUCT. umhoslcm TURBIDITY NTU OTHER eh mV DISS.OXY. PPM OTHER NA NA NA NA NA NA NA NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: Iw �.Ap- COMMENTS: APPENDIX I LIST 90 OF SAMPLE COLLECTION NUMBER I Page 79 of 99 SITE NAME: FOOTHILLS LF POINT ID: TRIP BLANK LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: DEIONIZED WATER INITIAI-7'L A� LEVEL (FT) ELEV., MEAS. PT. (MSL): DATE METHOD OF EVACUATION: { } PVC BAILER { } S.S. BAILER ( } S.S. BAILER { } QED PUMP WELL RISER DIAMETER (IN.): ( } 2 ONE (1) RISER VOLUME {GAL} TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA LAB SAMPLE/ PROJECT #: ( } GRUNDFO: ( } OTHER { } 3 ( ) 4 E S & S - R.CHIODO DEPTH TO BOTTOM (FT) ELEVATION, GAIV (MSL): TIME: START/FINISH 1 EVACUATION EQUIPMENT DEDICATED: ME ( ) YES ( ) NO { )6 { }o WAS WELL PURGED TO D ESS { } YES ( } NO WATER LEVEL END PURGE (FT) FINISH Exam SAMPLING INFORMATION DATE 1 TIME - 2-'0— 2O 1 1 -18 METHOD OF SAMPLING: ( } PVC BAILER { ) S.S. BAILER { } S.S. BAILER { ) QED PUMP SAMPLING FIELD MEASUREMENT DAT DEPTH TO GROUNDWATER (FT) NA SAMPLING EQUIPMENT DEDICATED: { } GRUNDFOS PUMP { } YES { } OTHER ( } NO TIME pH Std.Units TEMP. C CONDUCT. umhvskm TURBIDITY NTU OTHER eh m DISS.OXY. PPM OTHER NA NA NA NA NA NA NA NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING SAMPLE CHARACTERISTICS: c LE Arg— COMMENTS: VOA ONLY Sw m NX,, 0 0 1= SAMPLE COLLECTION NUMBER � Page 80 of 99 SITE NAME: FOOTHILLS LF POINT ID: Sw - 5 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER EVACUATION INFORMATION INITIAA�i LEVEL (FEE ELEVATION, MEAS.PT. 5L; INLA" METHOD OF EVACUATION: FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE 1 PROJECT #: NA NA DEPTH TO BOTTOM {FEET} NA NA ELEVATION, G/W {MSQ: NA TIME: STARTIFINISH 1 { ) PVC BAILER { } WELL WIZARD { } S.S. BAILER { } GRUNDFOS PUMP WELL RISER DIAMETER (IN.): { } 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START E]L&I UATION STABILIZATION DATA EVACUATION EQUIPMENT DEDICATED: { } CONTINUOU ( } YES { ) NO PUMPING WELL ( ) OTHER WAS WELL PURGED TO DRY S ( ) YES { )NO WATER LEVEL AFTER PURGE {FT.} 1wkifflF TIME PURGE RATE mlhtz CUMULATIV VOLUME C pH its SPEC. CONDUCT. umhoslcm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE 1 TIME ��'°� ! WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: [ } PVC BAILER { } WELL WIZARD ( } WATERRA PUMP (X ) YES { } S.S. BAILER { } GRUNDFOS PUMP (X) DIP BOTTLE { } NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units SPEC. CONDUCT. umhoslcm TEMP. C TURBIDITY NTU REDOX eh m DISS.OXY. PPM OTHER 115130 7.ol 41E;.S 26.2- r)8'.90 +9-.9 5.9(40 NA GENERAL INFORMATION ¢-r WEATHER CONDITIONS AT TIME OF SAMPLING:`''�'y SAMPLE CHARACTERISTICS: I{ UUJZZ, C> �i$r•.] ^ COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 3 Page 81 of 99 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA E MATRIX: SURFACE WATER INITIAL WATE EL {FEET} NA ELEVATION, MEAS.PT.(MSL): NA DATE METHOD OF EVACUATION: POINT ID: SW-4 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE I PROJECT #: NA DEPTH TO BOTTOM (FEET)_ _ NA ELEVATION, G/W (MSL): NA TIME: STARTIFINISH I EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) CONTIN ( ) YES ( ) NO ( ) S.S. BAILER ( ) GRUNDFOS PUMP PUMPING WELL WELL RISER DIAMETER (IN.): ( } 2 ( } 4 ( } 6 ( ) OTHER ONE (1) RISER VOLUME {GAL} WAS WELL PURGED TO ❑R TOTAL VOLUME EVACUATED (GAL) WATER LEVEL AFTER PURGE (FT.) TURBIDITY OF PURGINGS : START FINISH EVACUATION STABILIZATION DATA ( ) YES ( ) NO TIME PURGE RAT m/htz 1VE VOLUME TEMP. pH Std.Units SPEC. CONDUCT. umhos/cm TURBIDITY NTll OTHER eh mV NA 0 NA NA NA SAMPLING INrF�}ORMATION DATE/TIME t-2�0'1() / i S5() WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( } PVC BAILER } WELL WIZARD [ } WATERRA PUMP (X ) YES ( } S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( } NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std�.Unifs SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh mV ❑ISS.OXY. (PPM OTHER ly�'st T i1I &(•7 2S. j 1S ,70 "I�.11 5,01 NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: W►J 0 SAMPLE CHARACTERISTICS: cL,� COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER I Page 82 of 99 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER EVACUATION INFORMATION INITIAL VCIA5EEVEL (F'EETI NA ELEVATION, MEAS.PT.(MSL): NA DATE METHOD OF EVACUATION: { } PVC BAILER { ) WELL WIZARD { } S.S. BAILER { } GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( } 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA POINT ID: SW-3 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE I PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, GIW (MSL): NA TIME: START/FINISH 1 EVACUATION EQUIPMENT DEDICATED: ( ) CONTINUOUS ( ) YES ( ) NO PUMPING WELL ( } 4 ( } S ( ) OTHER WAS WELL PURGED TO DRYNES WATER LEVEL AFTER PURGE (FT.) FINISH YES ( ) NO TIME PURGE RAT mlhtz TIVE VOLUME TEMP. pH Std.Units SPEC. CONDUCT. umhoslcm TURBIDITY NTU OTHER eh m NA Q NA NA NA SAMPLING INFORMATION DATE 1 TIME '7"'21,a' 20 1 WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: { } PVC BAILER { ) WELL WIZARD { } WATERRA PUMP (X) YES { } S.S. BAILER { } GRUNDFOS PUMP (X) DIP BOTTLE { } NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units SPEC. CONDUCT. umhoslcm TEMP. C TURBIDITY NTU REDOX eh m DISS.OXY. PPM OTHER )v"14 '7.9$ 6q.(47 ;Z3.9 C).'7:. -iS,$ S-,tb NA GENERAL INFORMATION r 9c) a WEATHER CONDITIONS AT TIME OF SAMPLING: suw SAMPLE CHARACTERISTICS: C �.A.' COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER Page 83 of 99 SITE NAME FOOTHILLS LF POINT ID: IIIIw - 11 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSQ: DATE 7—'Z7. �tO 92.62 Not. `7) FIELD REPRESENTATIV E S & S - B.CHIODO LAB SAMPLE I PROJECT #: NA DEPTH TO BOTTOM (FT): ELEVATION, G1W {MSL): TIME: START/FINISH 5': q0 /0 9, q0 ? 3`. cl I 6:l2 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: [ } PVC BAILER ( ) S.S. BAILER { } GRUNDFOS PUMP (X) YES ( } NO ( } S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( } 3 ( ) 4 { } 6 [ } OTHER ONE (1) RISER VOLUME (GAL) 9,)l WAS WELL PURGED TO DRYNESS { } YES (X) NO TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS: WATER LEVEL END PURGE (FT) 9.2. 9-0 START ckz:A • FINISH CkEAR EVACUATION STABILIZATION DATA TIME PURGE RATE ML I MIN DTW CUMUL. VOL GAL TEMP. C pH Sjtd.Urni#s CONDUCT. m o�s/ca u�m^h'/ TURBIDITY NT�U REDOX eh m D.D. MG/L? 5!qo 250 +FT { 0,12 ( [ M !rl q 4 250 W.7-7, 0.25 1 b . 1 7. S'(, 52, z &.71 - A 1 2f /.5 250 Z7yf 0.50 7. Ef 5 S2,9 0,25 -122 2,1 Z. S : 3 250 Z.-Ir 0.75 i lo. � '�. V Z S73. 1 6. 20 -1/.'V 2,09 51,311, 250 �2.77 1.00 110,0 �`. Y0 5 3, c# 6. 1-3 --10. 6 .2,OS `o►� 250 97-71 1.25 1�.o 7,((o 5%11■ e-)( --r10.y 191 r 250 ?2r� 1.50 i s. t .3 8' 5-1, J 0,11 Y /.7 ,r 9k- 8� 250 MO 1.75 1 S, 9 7 37 5Y.1 0. 1 Z. — 9 3 494 `6 250 2w 9C.k 2.00 1 S. f 7. 3 q. i�, i r / , SAMPLING INFORMATION DATE,TIME r7- *2 7' ZO 1 wl F 00 DEPTH TO GROUNDWATER (FT) �? 2. So METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: { } PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES { } S.S. BAILER (X) QED WW PUMP { } OTHER ( } NO GENERAL INFORMATION . Oc WEATHER CONDITIONS AT TIME OF SAMPLING:�� r. SAMPLE CHARACTERISTICS: C LZ4e COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER %v Page 84 of 99 SITE NAME FOOTHILLS LF POINT ID: mW - 10 FIELD REPRESENTATIV LAB SAMPLE 1 PROJECT #: E S & S _ B.CHIODO NA DEPTH TO BOTTOM (FT): i ELEVATION, GIW (MSL): ,;' TIME: STARTIFINISH 6'. 2q l •�_ _/ METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( } PVC BAILER ( ) S.S. BAILER { ) GRUNDFOS PUMP (X) YES ( ) NO [ } S.S. BAILER (X) QED WW PUMP ( ] OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( } 6 ( } OTHER ONE (1) RISER VOLUME {GAL} 1. 1'7 WAS WELL PURGED TO DRYNESS ( j YES (X) NO TOTAL VOL. EVACUATED (GAL) • d O WATER LEVEL END PURGE (FT) r7 r• YI TURBIDITY OF PURGINGS: START Clf„.. FINISH_Y.i EVACUATION STABILIZATION DATA TIME PURGE RATE ML 1 MIN DTW FT CUMUL. VOL GAL TEMP. C pH Std.Units CONDUCT. umhoslcm) TURBIDITY (NTU) REDOX D.O. (MGIL 6 : :Z.q 250 W i l 0 16.2- '-7. 33 Co 1. -3 6. 573 - / r 3 6.O c? a 250 7y 7, z? 0.25 1 (.11 z 'rZ-f 60.9 � s 10 - 3. 9 � �. i3ry I 250 �I�25 0.50 16. �■p�, . it Z. 60. 1i 1 • P ( - 2 . tt .� G 250 77 29 0.75 U1, 7. 7 2ia 6 0, 'Lf � , To - /, (' Sr i :mot 5 250 7 7.?0 1.00 11 to . ;Z 7 1? 40. 2 1,14 +0. -7 �:75 .,-f 250 "7/.;% 1.25 1 l"- 1 17.1 2- :g 1.1 2. 1 C. 4- 7'. 41 6: S 3 250 77.31 1.50 1 b r 1 7, c,,q 5-1.-7 2,5Z 4 q.z) S 9 Z � : 7 250 7731 1.75 16,0 7 / a 5% 7 2. 5'0 q, :�' 5-, ` o 250 7731 2.00 1(e, 0 7,09 S'` Z If:5 r�' 6,90 SAMPLING INFORMATION DATE/ TIME '7-2"7- -20 1 17• ()' LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): f. ELEV., MEAS. PT. (MSL}: 13 5 S. 53 DATE t-7--;�7-�0 DEPTH TO GROUNDWATER (FT) 7'7. -? / METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( } PVC BAILER ( ) S.S. BAILER ( } GRUNDFOS PUMP (X) YES ( } S.S. BAILER (X) QED WW PUMP ( } OTHER ( } NO GENERAL INFORMATION F WEATHER CONDITIONS AT TIME OF SAMPLING: -304PA44S v SAMPLE CHARACTERISTICS: c 0� COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER rl Page 85 of 99 SITE NAME FOOTHILLS LF POINT ID-. mw - 9 LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIV E S & S - B.CHIODO SAMPLE MATRIX: GROUNDWATER LAB SAMPLE I PROJECT ##: NA EVACUATION INFORMATION ( 8-1 L �3. Q INITIAL WATER LEVEL (FT): ❑EPTH TO BOTTOM {FT): �• j ,'1 2 2 , 3 T ELEV., MEAS. PT. (MSL): ELEVATION, G/W (MSL): DATE 7--'A 7- 20 TIME: STARTIFINISH ". i I 1 1 q� METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( } PVC BAILER ( ) S.S. BAILER { } GRUNDFOS PUMP (X) YES ( } NO ( } S.S. BAILER (X) QED WW PUMP { } OTHER WELL RISER DIAMETER (1N.): (X) 2 [ } 3 { ) 4 { } 6 { } OTHER ONE (1) RISER VOLUME {GAL} WAS WELL PURGED TO DRYNESS ( } YES (X) NO TOTAL VOL. EVACUATED (GAL) , 00 WATER LEVEL END PURGE (FT) � � 57 TURBIDITY OF PURGINGS: START CL;-:A.- FINISH C (k, . EVACUATION STABILIZATION DATA, TIME PURGE RATE ML 1 MIN DTW FT CUMUL. VOL GAL TEMP. G pH Sfd.Unifs CONDUCT. umhoslcm TURBIDITY NTU REDOX eh mV D.D. MGIL • P7 250 69gy 0 �, S �� I V), 2 637 4-&/.j? 3, �ro q:21 250 0.$3 0.25 F-17 1a9S 0.35' f62.1 3•.?6 7: z3 250 0,5,5 0.50 11 irr 5 ` (o I Slk 3.35' 1-) *1 zq 250 6,klf 0.75 19 S !;.% I159.q -7,32 7.'33 2C50 1.00 11p0.1 (5,75 4-i 2.S y T'' i 250 �Ri.7 ■ 1.25 . [-"56 ..+A 5- ApO. ( 0,72 4-6 Gi� �r �Si 9:11 1 2550 62 57 1.50 1 %`f S'1:57 IV r2. 0,79 -4-4 2-9 1+4310 3, ZL, 1 • 250 M57 1.75 ) g. tf 5r1157 A00.2- 0, "X 5• 2 (. �:y ► 250 69.57 2.00 119, y 5,95 160.3 6.7Z +f*3, 1 3, 25 z SAMPLING INFORMATION DATE 1 TIME r7-17— '2© 1 DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: { } PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES { } S.S. BAILER (X) QED WW PUMP ( } OTHER { ) NO GENERAL INFORMATION F WEATHER CONDITIONS AT TIME OF SAMPLING: S'►�r SAMPLE CHARACTERISTICS: C k51 - COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER Page 86 of 99 SITE NAME FOOTHILLS LF POINT Ilia: MW - I R2 LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIV E S & S - B.CHIODO SAMPLE MATRIX: GROUNDWATER LAB SAMPLE/ PROJECT #: EVACUATION INFORMATION , INITIAL WATER LEVEL (FT): DEPTH TO BOTTOM (FT) ELEV., MEAS, PT. (MSL): ELEVATION, GIW (MSL): DATE '?2'-7- 20 TIME: START/FINISH 9.) D METHOD OF EVACUATION: ( ) PVC BAILER ( ) S.S. BAILER ( } GRUNDFOS PUMP { ) S.S. BAILER (X) QED WW PUMP ( ) OTHER NA L4 3. 3Y I 0. 12 EVACUATION EQUIPMENT DEDICATED: (X) YES ( ) NO WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 [ ) 4 ( ) $ ( ) OTHER ONE (1) RISER VOLUME (GAL) �"i• WAS WELL PURGED TO DRYNESS ( } YES (X) NO TOTAL VOL. EVACUATED (GAL) '- Dv WATER LEVEL END PURGE (FT) �. TURBIDITY OF PURGINGS: START C �-- FINISH �-F,.. EVACUATION STABILIZATION DATA TIME PURGE RATE ML 1 MIN DTW FT CUMUL. VOL GAL TEMP. C pH Std.Units CONDUCT. umhoslcm TURBIDITY NTU REDOX eta m D.D. MGIL 9"10 250 IS.00 0 1-7,9 G-. O ftv 1 1.22 f31.5 1 Y 14 250 IT Ili 0.25 (7,5 6.5 R),S )_IS- +Pll 81.18 250 IS.2I 0.50 113 &.570 ` ).0 $ 436.(, t.4z 2,2- 250 1523 0.75 174 6.Sco 7.S ).05 4-31 7 139 250 l z 1.00 P4 6, vq P)2.S OM +37, 1 13 tf F.30 250 f�tS 1.25 1-7.4 (•q 7is C,95 +-37Z 1.3a 'A 34 250 ISLE. 1.50 174 6,49 71 f 6,93 +37.5 L30 r3$ 250 Is.t'7 1.75 123 6"-Ig 21.6 0,10 f376 1.31 250 I507 2.00 17.3 6.L#S "i).S` 0.92 +37.7 /3,7 1250 SAMPLING INFORMATION DATE I TIME - I ' 4 2- ❑EPTH TO GROUNDWATER (FT) 19. --1 7 METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( } PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( } OTHER ( ) NO GENERAL INFORMATION pF WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: cUAL COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER ° Page 87 of 99 SITE NAME: FOOTHILLS LF POINT ID, sw - 1 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER INITIAL WATIER-LEj_EL (FEET) NA ELEVATION, MEAS.PT.{MSL}: NA DATE METHOD OF EVACUATION: { ] PVC BAILER { } WELL WIZARD { } S.S. BAILER ( } GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( } 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE I PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, GAN {MSL}: NA TIME: STARTIFINISH ! EVACUATION EQUIPMENT DEDICATED: { } CONTINUOUS ( ) YES ( ) NO PUMPING WELL ( ]4 ( }6 ( )OTHER WAS WELL PURGED TO DRYNES WATER LEVEL AFTER PURGE (FT.) FINISH YES ( ) NO TIME PURGE RATE mlhtr CUMUDMV& VOLUME TEMP, C pH Std.Units SPEC. CONDUCT. urrthoslcm) TURBIDITY (NTU) OTHER [eh tnV NA 0 NA NA NA SAMPLING INFORMATION DATE 1 TIME ! -7© 1 9 ! /o WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( } PVC BAILER [ } WELL WIZARD { } WATERRA PUMP (X) YES ( } S.S. BAILER { } GRUNDFOS PUMP (X) DIP BOTTLE { } NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units SPEC. CONDUCT. umhoslcm TEMP. C TURBIDITY NTU REDOX eh m DISS.OXY. PPM OTHER GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: c kzpt z. COMMENTS: APPENDIX I LIST apt" �lr.,t �+s � r SAMPLE COLLECTION NUMBER /0 Page 88 of 99 SITE NAME FOOTHILLS LF POINT ID: MW .. 8 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT)_ ELEV., MEAS. PT. (MSQ: DATE r7. *,X- 2. b ills. )181 FIELD REPRESENTATIV E S & S - B.CHIODO LAB SAMPLE 1 PROJECT #: NA DEPTH TO BOTTOM (FT): "I 1. 5t'�' ELEVATION, GAM (MSL): H tq • 7 �- TIME: START/FINISH METHOD OF EVACUATION: { } PVC BAILER ( ) S.S. BAILER { } GRUNDFOS PUMP { } S.S. BAILER (X) QED WW PUMP ( ) OTHER 1 /0:0[ EVACUATION EQUIPMENT DEDICATED: (X) YES ( ) NO WELL RISER DIAMETER (IN.): (X) 2 { } 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) . a WAS WELL PURGED TO DRYNESS { } YES (X) NO TOTAL VOL. EVACUATED (GAL) • O E3 WATER LEVEL END PURGE (FT) 3o.59 TURBIDITY OF PURGINGS: START C LEAP- FINISH c tFAL EVACUATION STA131LIZATION DATA PURGE RATE ML 1 MIN DTW FT CUMUL. VOL GAL TEMP. C pH Std.Units CONDUCT. umhos/cm TURBIDITY NTU REDOX eh m D.O. MGIL +TIME 250 70,46 0 5 SY 4 15 :33 250 30,Sy 0.25 -?0' to 5 S 3 '%{a ) 445. 2-11 250 0.50 20. . . s 3 74.0 4/.7 - 2.110 t[i 30 57 0.7rt5 -20,16 5, � � � . $ `�'3� -� ��i�f.}G�J .2-07 . 4.5 r2�50 250 7a 57 1.00 -2vi L S. ci� ��.7+/� t S;, 7 rp�. C• :5b V !i J 2,okt 250 3o.57 1.25 20, 5 �% �. . 7 48S. 3 -2. oy ` 0"53 250 3a.5) 1.50 2o.3 553 "?G-3 4.10 9"!9 Z_az 9 : 5"7 250 3o. S4) 1.75 20. 2. a y 7(. 3 6. 9 (, t �. I 10.0 I 250 50,59 2.00 �2 -6. A ..Stf r%(. q • gg +g%5 •ol �- SAMPLING INFORMATION DATE/TIME '%-2'7-'Z0 1 to-Q DEPTH TO GROUNDWATER (FT) ?0. �l METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: { } PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES { } S.S. BAILER (X) QED WW PUMP { } OTHER ( NO GENERAL INFORMATION v �' WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: C• (F.A-K COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER Page 89 of 99 SITE NAME FOOTHILLS LF POINT ID: I� W - 7 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION . �, INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSL): 3 �'7 � n FIELD REPRESENTATIV LAB SAMPLE 1 PROJECT #: E S & S _ B.CHIODO NA DEPTH TO BOTTOM (FT): 46. 13 ELEVATION, G/W (MSL): 1� 1 15 3, �' q It)` !� In'5a DATE y TIME: STARTIFINISH 1 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: { } PVC BAILER { } S.S. BAILER { } GRUNDFOS PUMP (X ) YES { } NO { } S.S. BAILER { X } QED WW PUMP ( } OTHER WELL RISER DIAMETER (IN.): (X ) 2 { } 3 { } 4 { } 6 } OTHER ONE (1) RISER VOLUME {GAL} 1►111 WAS WELL PURGED TO DRYNESS { } YES (X ) NO TOTAL VOL. EVACUATED {GAL} -2. Qy WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START (Z- FINISH C CW EVACUATION STABILIZATION DATA TIME PURGE RATE ML I MIN DTW FT CUMUL. VOL GAL TEMP. C pH Std.Units CONDUCT. umhoslcm) TURBIDITY (NTU) REDOX D.Q. (MGIL 10.. 3 GCS 250 29 lv 0 a r. 3 (.1) I D 1. 2 6. (o (o + 54t 6' 5; !2 & t0•.zz 250 *ZlS? 0.25 t&9 5790 I12.a ;r.q2 4-617,9 7 I0 : 2k, 250 z,)s3l 0.50 fig..7y 115. �.3� + 72. 6 5. 15 101.30 250 11,5,31 0.75 I S. 70 116. 3,'7 cl 47� 1 5.17 10', 3Y 250 25.SY 1.00 1'3. 3 1 1 - '� �, �' 5- 10 39 S%f 1.25 [`9, � .�:7� 110, Z �.2€ 3 '73.�1j `/��•m`U�2-� r2�50 .Zl 211+ ss 1.50 �. � 121.5 �. 1 5 + l3, ? �5-.10 5, 01 10%46 r250 250 2I.5r 1.15 j� f'lr 2 C�'"�� S-, 15- { I -Z1 .� 3, 1 Z �'�„7. G � vI )0:S0 250 21SS 2.00 r!` , 1 5:7 (a3.a 3.o$ +73.2 .5.ae 3- SAMPLING INFORMATION DATE/TIME '7- -27-'2fl 1 10 • Sd DEPTH TO GROUNDWATER (FT) 57 METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: { } PVC BAILER { } S.S. BAILER { } GRUNDFOS PUMP (X ) YES { } S.S. BAILER (X ) QED WW PUMP { } OTHER ( ) NO GENERAL INFORMATION 4 WEATHER CONDITIONS AT TIME OF SAMPLING: 64 ►4lit SAMPLE CHARACTERISTICS: C �w COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER I ZZ Page 90 of 99 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA 5 LE MATRIX: UNDERDRAIN WATER EVACUATION I MATION INITIAL WATER LEVEL (FE NA ELEVATION, MEAS.PT.(MSL): NA DATE METHOD OF EVACUATION: { } PVC BAILER { } WELL WIZARD { } S.S. BAILER { } GRUNDFOS PUMP WELL RISER DIAMETER (IN.): { } 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA POINT ID: UD - 2 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE I PROJECT #: NA DEPTH TO BOTTOM (FEET NA ELEVATION, GIW (MSL): NA TIME: START/FINISH 1 EVACUATION EQUIPMENT DEDICATED- ( ) CONTINUOUS ( ) YES ( ) NO PUMPING WELL { }4 { }6 ( )OTHER WAS WELL PURGED TO DRYN WATER LEVEL AFTER PURGE (FT.) FINISH ) YES ( ) NO TIME PURGE RATE mlhtz VOLUME TEMP. C pH Std. Units) SPEC. CONDUCT. umhoslcm TURBIDITY NTU OTHER eh mV NA 6 NA NA NA SAMPLING INFORMATION DATE I TIME 1*7 —�� _ 10 1 W 0 5 WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: { } PVC BAILER [ } WELL WIZARD { j WATERRA PUMP (X) YES ( } S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( } NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units SPEC. CONDUCT. umhoslcm TEMP. C TURBIDITY NTU REDOX eh mV ❑ISS.OXY. PPM OTHER 11!0 7' c 1112. � 10 23.9 T. 0 2. +'7Lf. 2- q.q,9' NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: .7nil� SAMPLE CHARACTERISTICS: C VA(Z COMMENTS: APPENDIX I LIST oje SAMPLE COLLECTION NUMBER f 3 Page 91 of 99 SITE NAME FOOTHILLS LF FIELD REPRESENTATIV E S & S - B.CHIODO LAB SAMPLE/ PROJECT #: NA DEPTH TO BOTTOM (FT): 5-0. 5-5' ELEVATION, G!W (MSL}: r' TIME: START/FINISH W.2 3 f : METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: [ } PVC BAILER ( ) S.S. BAILER { ) GRUNDFOS PUMP (X) YES { } NO ( j S.S. BAILER (X) QED WW PUMP { } OTHER WELL RISER DIAMETER (IN.): (X) 2 [ } 3 { ) 4 [) 5 { } OTHER ONE (1) RISER VOLUME (GAL) I. S? WAS WELL PURGED TO DRYNESS ( } YES (X) NO Q. TOTAL VOL. EVACUATED (GAL) .CEO WATER LEVEL END PURGE (FT) Z7 0.91 TURBIDITY OF PURGINGS: START_ p— FINISH EVACUATION STA131LIZATION DATA PURGE RATE MLf MnIN DTW FT CUMUL. VOL GAL TEMP. pH Sid.U/nits CONDUCT. um�hoslc�m} TURBIDITY NTSU REDOX eh m D.O. IVIGlL yTI�yME I . 2 3 50 M 0 r'��r(C)y rf � V r v & Q !; . I L) . ^ / 19 4 /2] (fq0.. yV 5�/�^• 3I �1Gy' �;Z F! /�1 �'9. 1 l .3 ! 250 IVQ7 0.50 [%s 5,147- 192.9 J.10 +�0.z LJ 4 / � .35 250 I �. 1 0.75 193 5rW 1 V �2,7 3 &8 4W/. S- fo U4.19 250 W079 1.00 1�. S��vl 1P2. 3.S7 4go. (0 i : ,l-i 3 250 qa,sol 1.25 I .a . & [ t� 9. � -� '�s + R117 11.10 250 10SD 1.50 113 S . (, o 1-77. 9, 3. 1. S 1 250 qD.$1 1.75 I t 3 57,60 [ -77. (a 3, 4-81. 9 I' S 250 q0.*1 2.00 d 9.3 S: &Q 179 5 3 7 +9/,6 Z S'S 2 ?-- m SAMPLING INFORMATION DATE ITIME 7--727-2-0 f LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): (9• J ELEV., MEAS. PT. {MSL): 7 , DATE`' DEPTH TO GROUNDWATER {FT} 10. * l METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: { } PVC BAILER ( ) S.S. BAILER [ ) GRUNDFOS PUMP (X) YES ( } S.S. BAILER (X) QED WW PUMP ( } OTHER ( ) NO GENERAL INFORMATION of - WEATHER CONDITIONS AT TIME OF SAMPLING: J�•1I+�t r 4 SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 14 Page 92 of 99 SITE NAME FOOTHILLS LF POINT ID: mw - 5 LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIV E S & S - B.CHIODO SAMPLE MATRIX: GROUNDWATER LAB SAMPLE ! PROJECT #: EVACUATION INFORMATION l� INITIAL WATER LEVEL (FT): 16 . s ELEV., MEAS. PT. (MSL): I r7 5>.0 DATE '7 :C7- aD NA DEPTH TO BOTTOM (FT): 7q. .S-O ELEVATION, GA/V (MSL}: q 9 TIME: STARTIFINISH I :Z , 10 I METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( } PVC BAILER ( ) S.S. BAILER ( } GRUNDFOS PUMP (X ) YES ( } NO { } S.S. BAILER (X) QED WW PUMP ( } OTHER WELL RISER DIAMETER (IN.): (X ) 2 ( } 3 ( } 4 ( } Fi { } OTHER ONE (1) RISER VOLUME (GAL) t.')r7 WAS WELL PURGED TO DRYNESS ( } YES (X ) NO TOTAL VOL. EVACUATED (GAL) 2.40 WATER LEVEL END PURGE (FT) 4?(q, 79 TURBIDITY OF PURGINGS: START FINISH' EVACUATION STABILIZATION DATA TIME PURGE RATE ML 1 MIN DTW F CUMUL. VOL GAL TEMP. (C pH Std. Units) CONDUCT. umhoslcm TURBIDITY NTU REDOX eh m D.O. MGIL 11"10 250 G.S 0 P.)%4 250 YkL71 0.25 1q2. "'Z 4-a-1 21.`o 1,2 -19 250 Y4,70 0.50 20.1 S,SS i 0. C7.59 4-(,9,7 23s- t� :2 250 qt Z 0,75 2,0.1 gggs 191, 0. (y( 4a-y' n 2'.?3 12.2to 250 V03 1.00 2 0. 0 5"M 1'913. 7 C.'10 4 (1 7 2.31 t ?1 . 30 250 qL331 1.25 :20. D s-, $kt I ?9-. c' 0.29 4-69. ,3 Z . ? I i 2:3y 250 q6,75'1 1.50 20.1 S19'E9 $'V-. Z 0, 2'Ll 2. 2,30 t :3$ 250 44.7 1.75 S7 $S 1 $g: 2- 0.21 +4Fr. 2,30 4 Z 250 2.00 2(D- S ;i a g, { a. t +G� 7 2. 30 2W= M@ SAMPLING INFORMATION DATE /TIME r7-a7-20 1 t -)' 4 2- DEPTH TO GROUNDWATER (FT) 11(a.75 METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: { } PVC BAILER ( ) S.S. BAILER ( } GRUNDFOS PUMP (X ) YES } S.S. BAILER (X ) QED WW PUMP ( } OTHER ( } NO GENERAL INFORMATION off` WEATHER CONDITIONS AT TIME OF SAMPLING: c.fn��a.� SAMPLE CHARACTERISTICS:, COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER l - Page 93 of 99 SITE NAME FOOTHILLS LF POINT ID: MW - 4 LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIV E S & S - B.CHIODO SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT)' ELEV., MEAS. PT. (MSL): DATE-'�-i—© ) , ri <1 IIrl I.100 LAB SAMPLE 1 PROJECT #: DEPTH TO BOTTOM (FT): NA !;�2,zo ELEVATION, GIW (MSL): 1 1 -2 i• 39 TIME: STARTIFINISH 1-;?"S? METHOD OF EVACUATION: { } PVC BAILER ( ) S.S. BAILER { } GRUNDFOS PUMP ( } S.S. BAILER (X) QED WW PUMP ( ) OTHER I 131.21 EVACUATION EQUIPMENT DEDICATED: (X) YES ( ) NO WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 5 ( ) OTHER ONE (1) RISER VOLUME (GAL) ! . (7 WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) '?- 00 WATER LEVEL END PURGE (FT) 441, '? 3 TURBIDITY OF PURGINGS: START C kZA fZ— FINISH 0, t,.EAe— EVACUATION STABILIZATION DATA TIME PURGE RATE ML 1 MIN DTW FT CUMUL. VOL GAL TEMP. C pH Sfd.Unifs CONDUCT. umhoslcm TURBIDITY NTU REDOX eh (mV) D.O. (MGIL 250 qc1q 0 1. cl s'27 ,� . 33 +js S, /r i L,, 13 :a 1 250 q1, 99 0.25 20. 2- 2 3AZ 0. 30 4-`99, 1 1. 3 13: a5' 250 &AR4 0.50 2-0.1 S, 2 (v 30, 2-Ef 13 ;� fi 250 qj' jo 0.75 20.0 S-' 2 a 33 0. 7,2 H IV' 3 i.'yo 13 J 3 250 ql1 j* 1.00 19,3 '; 257 333 (9. 1-7 7 1,38 13:117 250 / 1.25 lg.(�� 9. 2S- 33.8 6.14 � C 1.'j3�4, t 3. a I 250 �tl�q1 �i'+ 1 .50 1 9. i 4� } i f� "� J I ] 13 : 5 250 403 1.75 1'1,' 1 S�. ?, 3 34/. 0 0. 1 410 0. 3 1, 3 s 13 ; z `l 250 %93 2.00 1 � . `3 5. 23 3 q. 1 0.15' +100, ci 1. 3 S' SAMPLING INFORMATION DATE / TIME 7 �LQ DEPTH TO GROUNDWATER (FT) q1, 9.3 METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( } PVC BAILER ( ) S.S. BAILER { } GRUNDFOS PUMP (X) YES [ } S.S. BAILER (X) QED WW PUMP [ } OTHER ( } NO GENERAL INFORMATION Ps - SAMPLE WEATHER CONDITIONS AT TIME OF SAMPLING: �[� CHARACTERISTICS: �EAC COMMENTS: APPENDIX I LIST S ►`'� utj SAMPLE COLLECTION NUMBER 1(0+ 1*77 Page 94 of 99 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: UNDERDRAIN WATER INITIAL WATER-LEL (FEET) NA ELEVATION, MEAS.PT.(MSL}: .__NA ............. DATE METHOD OF EVACUATION: ( j PVC BAILER } WELL WIZARD ( } S.S. BAILER ( } GRUNDFOS PUMP WELL RISER DIAMETER (IN.): { ] 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA POINT ID: V ❑ - 1 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE 1 PROJECT #: NA DEPTH TO BOTTOM (FEET). NA ELEVATION, GIW (MSL): NA TIME: START/FINISH EVACUATION EQUIPMENT DEDICATED: ( ) CONTINUOUS ( } YES ( } NO PUMPING WELL ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS YES ( ) NO WATER LEVEL AFTER PURGE (FT.) 19IN16`]1r1 TIME PURGE RA mlhtz VOLUME TEMP. pH Std.Units SPEC. CONDUCT. umhoslcm TURBIDITY NTU OTHER eh mV NA 0 NA NA F-F NA SAMPLING INFORMATION DATE I TIME I � � 1 •� WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( } PVC BAILER ( ) WELL WIZARD ( } WATERRA PUMP (X) YES ( } S.S. BAILER ( } GRUNDFOS PUMP (X) DIP BOTTLE ( } NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units SPEC. CONDUCT. umhoslcm TEMP. C TURBIDITY NTU REDOX eh mV DISS.OXY. PPM OTHER I3.,gz .5-.5Lf a 1 s 9.1 19.7p +70. I �. �75 NA GENERAL INFORMATION Isl or WEATHER CONDITIONS AT TIME OF SAMPLING: UAJn3!1,r SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER Page 95 of 99 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER EVACUATION INFORMATION INITIAL EVEL ((FE-ET} NA ELEVATION, MEAS.PT.(MSL): NA DATE METHOD OF EVACUATION: ( } PVC BAILER { ) WELL WIZARD ( } S.S. BAILER ( } GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( } 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA POINT ID: SW-2 FIELD REPRESENTATIVE: E 5 & S - B.CHIODO LAB SAMPLE 1 PROJECT ##: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: STARTIFINISH 1 EVACUATION EQUIPMENT DEDICATED: ( ) CONTINUOUS ( ) YES ( ) NO PUMPING WELL { }4 ( }B ( )OTHER WAS WELL PURGED TO DRYNESS WATER LEVEL AFTER PURGE (FT.) FINISH [am* TIME PURGE RATE mlhtz CUMUtATIVE VOLUME TEMP. C pH Units SPEC. CONDUCT. umhoslcm TURBIDITY NTU OTHER eh m NA D NA NA NA SAMPLING INFORMATION DATE/TIME WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: { } PVC BAILER ( ) WELL WIZARD { } WATERRA PUMP (X) YES { } S.S. SAILER ( } GRUNDFOS PUMP (X) DIP BOTTLE { } NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units SPEC. CONDUCT. umhoslcm TEMP. C TURBIDITY NTU REDOX eh m DISS.OXY, PPM OTHER 1159 6.36 '9�. 7 'P43 ! �. AO 4-4 3. 2. '9, & l NA GENERAL INFORMATION { WEATHER CONDITIONS AT TIME OF SAMPLING: 5r4�}ws I , SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 19 Page 96 of 99 POINT ID: MW - 3R2 SITE NAME FOOTHILLS LF FIELD REPRESENTATIV E S & S - B.CHIODO LAB SAMPLE 1 PROJECT #: NA DEPTH TO BOTTOM (FT): 173. 9 ELEVATION, GIW (MSL): _2 01? �0 TIME; START/FINISH N1.15 1 l q• q7 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: { } PVC BAILER ( ) S.S. BAILER { ) GRUNDFOS PUMP (X) YES ( } NO ( } S.S_ BAILER (X ) QED WW PUMP { } OTHER WELL RISER DIAMETER (IN.): (X) 2 { } 3 ( } 4 { } 6 [ ) OTHER ONE (1) RISER VOLUME (GAL) S, t''l WAS WELL PURGED TO DRYNESS { } YES (X) NO TOTAL VOL. EVACUATED {GAL} ';?'• WATER LEVEL END PURGE (FT) 39,19 TURBIDITY OF PURGINGS, START- FINISH c EVACUATION STABILIZATION DATA TIME PURGE RATE ML I MIN DTW FT CUMUL. VOL GAL TEMP, C pH Std.Units CONDUCT. umhos/cm TURBIDITY NTU REDOX eh m D.O. MGIL �-f. 250 3&.7q ❑ .2o.5' ? &i� �2(o3 ,2. 3a -2d, 3,w,. 250 39. gs 0.25 20.3 7.7 ( .2 �, V1 2 .'o Z, -,2,? 9 3. yo 14',23 250 3klo 0.50 2,03 7go 247Ll 4 fS� -2111 738 114•t 27 250 V03 1 0.75 2-0•3 9,*?- -21P5 r 7& -2 `I. l 3 37 11'1.3 1 250 39.011.0❑ 24.3 7,97 -2lrp(,v �. Gad -2.7.7 330 iv:39 250 39,1? 1.50 2-0-2, 7,95 2-&7 1,70 S;7 3.27 NN 3 2�50 3(1J7 1,775 2o. Z , ?(9 (O5 - 2l o 3,257 114:4-7 25❑ 3`�I.18 2.00 t2{9. 2, i7,90 " c9gy0� I■ ICI ; i&S j1. f• V7 —71, 1 3,2 S' ass asu-..... .. .... SAMPLING INFORMATION DATE/TIME '7--'0- 2Q 1 N: L 7 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION 3 . 7 9 INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSL}: DATE r7---A7- 20 I ZLI o. 83 DEPTH TO GROUNDWATER (FT) 3 �- I METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: { } PVC BAILER ( ) S.S_ BAILER { } GRUNDFOS PUMP (X) YES { } S.S. BAILER (X ) QED WW PUMP ( } OTHER { } NO GENERAL INFORMATION OF WEATHER CONDITIONS AT TIME OF SAMPLING:e.l.•r�►s SAMPLE CHARACTERISTICS: C CE44 COMMENTS: APPENDIX 1 LIST SAMPLE COLLECTION NUMBER Q 0 Page 97 of 99 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: E %CUATION INFORMATION LEACHATE INITIA LEVEL {FEETt NA ELEVATION, MEAS.PT.(MSL NA DATE METHOD OF EVACUATION: ( } PVC BAILER { } WELL WIZARD } S.S. BAILER { } GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( } 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA POINT ID: LEACHATE FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE l PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL}: NA TIME: START/FINISH I EVACUATION EQUIPMENT DEDICATED: ( ) CONTINUOU ( ) YES ( ) NO PUMPING WELL { } 4 ) 5 ( ) OTHER. WAS WELL PURGED TO DRYN WATER LEVEL AFTER PURGE (FT.) FINISH ) YES ( )NO TIME PU mlhtz ULATIVE VOLUME TEMP. pH Std.Units SPEC. CONDUCT. umhoslcm TURBIDITY NTU OTHER eh mV NA a NA NA NA SAMPLING INFORMATION DATE 1 TIME Y7-- a 7— 20 WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER { ) WELL WIZARD ( j WATERRA PUMP (X) YES ( } S.S. BAILER ( } GRUNDFOS PUMP (X) SAMPLE PORT { } NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units SPEC. CONDUCT. umhoslcm TEMP, C TURBIDITY NTU REDOX eh (mV) DISS.OXY. (PPM OTHER )5:07 S. o 2, 23700 29, P, 3`�). kD -- NA NA GENERAL INFORMATION ��r WEATHER CONDITIONS AT TIME OF SAMPLING: Slot'h4v SAMPLE CHARACTERISTICS: CULEA— Avi8E COMMENTS: SAMPLE COLLECTION NUMBER 21 Page 98 of 99 SITE NAME FOOTHILLS LF POINT ID. MW - 2R LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT)_ ELEV., MEAS. PT. (MSL) DATE r7 -I r7- X0 Li $.qI Ia53.36 FIELD REPRESENTATIV LAB SAMPLE 1 PROJECT #: DEPTH TO BOTTOM (FT): ELEVATION, GIVII (MSL): TIME: STARTIFINISH METHOD OF EVACUATION: { } PVC BAILER ( ) S.S. BAILER ( } GRUNDFOS PUMP ( } S.S. BAILER (X) QED WIN PUMP ( ) OTHER E S & S - B.CHIODO NA 6 3, 6,o ! 0q.� 1 !(p.02- EVACUATION EQUIPMENT DEDICATED: (X) YES ( ) NO WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) l?.43 WAS WELL PURGED TO DRYNESS ( } YES (X) NO TOTAL VOL. EVACUATED (GAL) -2 • 5�O WATER LEVEL END PURGE (FT) qe- e" 9 TURBIDITY OF PURGINGS: START LLr a- FINISH C-Lrz A p'- EVACUATION STABILIZATION DATA TIME PURGE RATE ML 1 MIN DTW FT CUMUL. VOL (GAL) TEMP. C pH Std.Units CONDUCT. umhoslcm TURBIDITY NTU REDOX eh (mV) D.Q. (MG1L ls-zD 250 gkgj 0 19,7 5-9) If1 l , 3 0.11`i 46ss �2,,2s; IS:Z4 250 YtSO 0.25 N. !39.S- 0,C{ 2...4-70.1 2,23 1!5"Z9 0.^570 1�/+y.� I�.3(v] +�V.`1 ,23 1 . r2�50 {`g45'33 .f75 1 �y �5171 .J.7f ]1A38-.1 1 , � 0 � 1 } / W �251/0 250 iqi-S.] f t.9* -J0e I.00 �Ilj. "20, 0 5. ■ 0 /3 1 y77 L &/Z� 477.2 7Gr�}�\ 2, 20 1 : WO 250 1&0 1.25 210.0 5(09 13G.(, 0- 2 z + 77. 5- 2.1 Fr 1's .14m 250 qi-,1e7 1.50 2 0. 1 5,-&7 tle, Z 0- fit? +'7k,,3 2,1$r 15:g8 250 qf-*7 1.75 20.1 io 135A 01lzi 7fir ! 1 . $ 210.1 S. ("to i� ��,+ �Q�S' 6,1 S' +79- 7 2 � • r2��5/0�� 250 uf���++:jf�l • E;( I r2�.ry00 2,25 V6• 1 r�r `� l 3s, 8 0.14 V • 1 4 7. . j{ Z ItF* 250 g941 2.50 5,6(o 135.7 6. SAMPLING INFORMATION DATE/TIME -'2?-20 1 1�0:00 �' 0' - DEPTH TO GROUNDWATER (FT) Vk (�p METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: { } PVC BAILER ( ) S.S. BAILER ( } GRUNDFOS PUMP (X) YES ( } S.S. BAILER (X) QED WW PUMP ( } OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING:itn++t f SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX l LIST SAMPLE COLLECTION NUMBER Page 99 of 99 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 August 06, 2020 Environmental Manager Foothills Environmental Landfill 2800 Cheraw Road Lenoir, NC 28645 RE: Project: Foothills LF/Leachate Pace Project No.: 92487995 Dear Environmental Manager: Enclosed are the analytical results for sample(s) received by the laboratory on July 28, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte • Pace Analytical Services - Peachtree Corners, GA If you have any questions concerning this report, please feel free to contact me. Sincerely, "Ai� 5 Maiya Parks maiya.parks@pacelabs.com (770)734-4200 Project Manager Enclosures cc: Data Manager, TriHydro Corporation REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 25 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Foothills LF/Leachate Pace Project No.: 92487995 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 Pace Analytical Services Peachtree Corners 110 Technology Pkwy, Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 Georgia DW Microbiology Certification #: 812 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 North Carolina Certification #: 381 South Carolina Certification #: 98011001 Virginia Certification #: 460204 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 25 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Foothills LF/Leachate Pace Project No.: 92487995 Lab ID Sample ID Matrix Date Collected Date Received 92487995001 1403-Leachate Water 07/27/2015:05 07/28/2011:50 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 25 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Foothills LF/Leachate Pace Project No.: 92487995 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92487995001 1403-Leachate EPA6020B CW1 15 PASI-GA EPA 353.2 JRS 3 PASI-GA SM 5210B-2011 KN 1 PASI-GA EPA 8260D CL 50 PASI-C EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 350.1 Rev 2.0 1993 JKG 1 PASI-A EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A SM 5220D-2011 NAL 1 PASI-A PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte PASI-GA = Pace Analytical Services - Peachtree Corners, GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 25 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Foothills LF/Leachate Pace Project No.: 92487995 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed 92487995001 1403-Leachate pH 8.02 Std. Units 07/27/20 15:05 Temperature 29.2 deg C 07/27/20 15:05 Specific Conductance 23,700 umhos/cm 07/27/20 15:05 Turbidity 39.80 NTU 07/27/20 15:05 EPA 6020B Antimony 13AJ ug/L 30.0 07/29/20 20:20 EPA 6020B Arsenic 31.1 J ug/L 50.0 07/29/20 20:20 EPA 6020B Barium 66.9J ug/L 500 07/29/20 20:20 EPA 6020B Chromium 104 ug/L 50.0 07/29/20 20:20 EPA 6020B Cobalt 7.3J ug/L 50.0 07/29/20 20:20 EPA 6020B Lead 0.511 ug/L 50.0 07/29/20 20:20 EPA 6020B Nickel 52.2J ug/L 250 07/29/20 20:20 EPA 6020B Vanadium 23.8J ug/L 125 07/29/20 20:20 EPA 6020B Zinc 36.8J ug/L 50.0 07/29/20 20:20 EPA 353.2 Nitrogen, NO2 plus NO3 285 ug/L 200 07/28/20 15:57 EPA 353.2 Nitrogen, Nitrite 222 ug/L 200 07/28/20 15:57 SM 5210B-2011 BOD, 5 day 239000 ug/L 2000 08/03/20 09:45 EPA 8260D Acetone 322 ug/L 100 07/29/20 20:29 EPA 8260D Benzene 3.0 ug/L 1.0 07/29/20 20:29 EPA 8260D 2-Butanone (MEK) 262 ug/L 100 07/29/20 20:29 EPA 8260D Chlorobenzene 0.28J ug/L 3.0 07/29/20 20:29 EPA 8260D 1,4-Dichlorobenzene 3.6 ug/L 1.0 07/29/20 20:29 EPA 8260D 1,2-Dichloroethane 0.43J ug/L 1.0 07/29/20 20:29 EPA 8260D cis-1,2-Dichloroethene 0.54J ug/L 5.0 07/29/20 20:29 EPA 8260D Ethylbenzene 19.6 ug/L 1.0 07/29/20 20:29 EPA 8260D 2-Hexanone 2.OJ ug/L 50.0 07/29/20 20:29 EPA 8260D 4-Methyl-2-pentanone (MIBK) 7.1 J ug/L 100 07/29/20 20:29 EPA 8260D Toluene 7.4 ug/L 1.0 07/29/20 20:29 EPA 8260D Xylene (Total) 27.8 ug/L 5.0 07/29/20 20:29 EPA 350.1 Rev 2.0 1993 Nitrogen, Ammonia 1710000 ug/L 25000 08/04/20 12:33 EPA 365.1 Rev 2.0 1993 Phosphorus 9400 ug/L 250 07/30/20 20:00 SM 5220D-2011 Chemical Oxygen Demand 3600000 ug/L 500000 08/04/20 15:20 REPORT OF LABORATORY ANALYSIS D3 D3 D3 D3 D3 D3 D3 D3 M3 M3 Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 25 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Leachate Pace Project No.: 92487995 Sample: 1403-Leachate Lab ID: 92487995001 Collected: 07/27/20 15:05 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte pH 8.02 Std. Units 1 07/27/20 15:05 Temperature 29.2 deg C 1 07/27/20 15:05 Specific Conductance 23,700 umhos/c 1 07/27/20 15:05 m Turbidity 39.80 NTU 1 07/27/20 15:05 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony 13.4J ug/L 30.0 1.4 1 07/29/20 08:00 07/29/20 20:20 7440-36-0 D3 Arsenic 31.1J ug/L 50.0 3.9 1 07/29/20 08:00 07/29/20 20:20 7440-38-2 D3 Barium 66.9J ug/L 500 3.6 1 07/29/20 08:00 07/29/20 20:20 7440-39-3 D3 Beryllium ND ug/L 5.0 0.23 1 07/29/20 08:00 07/29/20 20:20 7440-41-7 D3 Cadmium ND ug/L 5.0 0.59 1 07/29/20 08:00 07/29/20 20:20 7440-43-9 D3 Chromium 104 ug/L 50.0 2.8 1 07/29/20 08:00 07/29/20 20:20 7440-47-3 Cobalt 7.3J ug/L 50.0 1.9 1 07/29/20 08:00 07/29/20 20:20 7440-48-4 D3 Copper ND ug/L 50.0 8.5 1 07/29/20 08:00 07/29/20 20:20 7440-50-8 D3 Lead 0.51J ug/L 50.0 0.18 1 07/29/20 08:00 07/29/20 20:20 7439-92-1 D3 Nickel 52.2J ug/L 250 3.5 1 07/29/20 08:00 07/29/20 20:20 7440-02-0 D3 Selenium ND ug/L 50.0 7.8 1 07/29/20 08:00 07/29/20 20:20 7782-49-2 D3 Silver ND ug/L 50.0 1.8 1 07/29/20 08:00 07/29/20 20:20 7440-22-4 D3 Thallium ND ug/L 27.5 0.72 1 07/29/20 08:00 07/29/20 20:20 7440-28-0 D3 Vanadium 23.8J ug/L 125 10.8 1 07/29/20 08:00 07/29/20 20:20 7440-62-2 D3 Zinc 36.8J ug/L 50.0 11.1 1 07/29/20 08:00 07/29/20 20:20 7440-66-6 D3 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Pace Analytical Services - Peachtree Corners, GA Nitrogen, NO2 plus NO3 285 ug/L 200 80.0 5 07/28/20 15:57 M3 Nitrogen, Nitrate ND ug/L 200 80.0 5 07/28/20 15:57 14797-55-8 Nitrogen, Nitrite 222 ug/L 200 90.0 5 07/28/20 15:57 14797-65-0 M3 5210B BOD, 5 day Analytical Method: SM 521 OB-2011 Preparation Method: SM 521 OB-2011 Pace Analytical Services - Peachtree Corners, GA BOD, 5 day 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Date: 08/06/2020 05:29 PM 239000 ug/L 2000 2000 1 07/29/20 09:31 08/03/20 09:45 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 322 ug/L 100 6.2 1 ND ug/L 200 0.90 1 3.0 ug/L 1.0 0.15 1 ND ug/L 3.0 0.34 1 ND ug/L 1.0 0.26 1 ND ug/L 3.0 0.62 1 ND ug/L 10.0 0.62 1 262 ug/L 100 3.3 1 ND ug/L 100 0.40 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 07/29/20 20:29 67-64-1 07/29/20 20:29 107-13-1 07/29/20 20:29 71-43-2 07/29/20 20:29 74-97-5 07/29/20 20:29 75-27-4 07/29/20 20:29 75-25-2 07/29/20 20:29 74-83-9 07/29/20 20:29 78-93-3 07/29/20 20:29 75-15-0 v1 Page 6 of 25 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Leachate Pace Project No.: 92487995 Sample: 1403-Leachate Lab ID: 92487995001 Collected: 07/27/20 15:05 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/06/2020 05:29 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.22 1 07/29/20 20:29 56-23-5 0.28J ug/L 3.0 0.23 1 07/29/20 20:29 108-90-7 ND ug/L 10.0 0.49 1 07/29/20 20:29 75-00-3 ND ug/L 5.0 2.3 1 07/29/20 20:29 67-66-3 ND ug/L 1.0 0.39 1 07/29/20 20:29 74-87-3 ND ug/L 13.0 0.26 1 07/29/20 20:29 96-12-8 ND ug/L 3.0 0.41 1 07/29/20 20:29 124-48-1 ND ug/L 2.0 0.26 1 07/29/20 20:29 106-93-4 ND ug/L 10.0 0.46 1 07/29/20 20:29 74-95-3 ND ug/L 5.0 0.29 1 07/29/20 20:29 95-50-1 3.6 ug/L 1.0 0.26 1 07/29/20 20:29 106-46-7 ND ug/L 100 0.54 1 07/29/20 20:29 110-57-6 ND ug/L 5.0 0.27 1 07/29/20 20:29 75-34-3 0.43J ug/L 1.0 0.34 1 07/29/20 20:29 107-06-2 ND ug/L 5.0 0.24 1 07/29/20 20:29 75-35-4 0.54J ug/L 5.0 0.29 1 07/29/20 20:29 156-59-2 ND ug/L 5.0 0.25 1 07/29/20 20:29 156-60-5 ND ug/L 1.0 0.19 1 07/29/20 20:29 78-87-5 ND ug/L 1.0 0.30 1 07/29/20 20:29 10061-01-5 ND ug/L 1.0 0.31 1 07/29/20 20:29 10061-02-6 19.6 ug/L 1.0 0.26 1 07/29/20 20:29 100-41-4 2.OJ ug/L 50.0 0.57 1 07/29/20 20:29 591-78-6 ND ug/L 20.0 12.5 1 07/29/20 20:29 74-88-4 ND ug/L 5.0 3.7 1 07/29/20 20:29 75-09-2 7.1J ug/L 100 4.5 1 07/29/20 20:29 108-10-1 ND ug/L 1.0 0.27 1 07/29/20 20:29 100-42-5 ND ug/L 5.0 0.34 1 07/29/20 20:29 630-20-6 ND ug/L 3.0 0.22 1 07/29/20 20:29 79-34-5 ND ug/L 1.0 0.16 1 07/29/20 20:29 127-18-4 7.4 ug/L 1.0 0.24 1 07/29/20 20:29 108-88-3 ND ug/L 1.0 0.18 1 07/29/20 20:29 71-55-6 ND ug/L 1.0 0.24 1 07/29/20 20:29 79-00-5 N D ug/L 1.0 0.22 1 07/29/20 20:29 79-01-6 ND ug/L 1.0 0.31 1 07/29/20 20:29 75-69-4 ND ug/L 1.0 0.35 1 07/29/20 20:29 96-18-4 ND ug/L 50.0 1.4 1 07/29/20 20:29 108-05-4 ND ug/L 1.0 0.24 1 07/29/20 20:29 75-01-4 27.8 ug/L 5.0 0.63 1 07/29/20 20:29 1330-20-7 98 % 70-130 1 07/29/20 20:29 460-00-4 107 % 70-130 1 07/29/20 20:29 17060-07-0 100 % 70-130 1 07/29/20 20:29 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IK,v1 Page 7 of 25 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Leachate Pace Project No.: 92487995 Sample: 1403-Leachate Lab ID: 92487995001 Collected: 07/27/20 15:05 Received: 07/28/20 11:50 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Sulfate ND ug/L 50000 25000 50 07/29/20 22:06 14808-79-8 D3 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia 1710000 ug/L 25000 17500 250 08/04/20 12:33 7664-41-7 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 9400 ug/L 250 125 5 07/29/20 20:36 07/30/20 20:00 7723-14-0 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services -Asheville Chemical Oxygen 3600000 ug/L 500000 250000 1 08/04/2011:55 08/04/2015:20 Demand Date: 08/06/2020 05:29 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 25 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92487995 QC Batch: 556322 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020 MET Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92487995001 METHOD BLANK: 2954004 Associated Lab Samples: 92487995001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 3.0 0.28 07/29/2019:06 Arsenic ug/L ND 5.0 0.78 07/29/2019:06 Barium ug/L ND 5.0 0.71 07/29/2019:06 Beryllium ug/L ND 0.50 0.046 07/29/2019:06 Cadmium ug/L ND 0.50 0.12 07/29/2019:06 Chromium ug/L ND 5.0 0.55 07/29/2019:06 Cobalt ug/L ND 5.0 0.38 07/29/2019:06 Copper ug/L ND 5.0 1.7 07/29/2019:06 Lead ug/L ND 1.0 0.036 07/29/2019:06 Nickel ug/L ND 5.0 0.69 07/29/2019:06 Selenium ug/L ND 5.0 1.6 07/29/2019:06 Silver ug/L ND 5.0 0.36 07/29/2019:06 Thallium ug/L ND 1.0 0.14 07/29/2019:06 Vanadium ug/L ND 10.0 2.2 07/29/2019:06 Zinc ug/L ND 10.0 2.2 07/29/2019:06 LABORATORY CONTROL SAMPLE: Parameter 2954005 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 100 106 106 80-120 Arsenic ug/L 100 95.3 95 80-120 Barium ug/L 100 97.3 97 80-120 Beryllium ug/L 100 97.6 98 80-120 Cadmium ug/L 100 95.7 96 80-120 Chromium ug/L 100 101 101 80-120 Cobalt ug/L 100 97.1 97 80-120 Copper ug/L 100 97.3 97 80-120 Lead ug/L 100 96.7 97 80-120 Nickel ug/L 100 97.3 97 80-120 Selenium ug/L 100 93.2 93 80-120 Silver ug/L 100 96.7 97 80-120 Thallium ug/L 100 95.2 95 80-120 Vanadium ug/L 100 98.9 99 80-120 Zinc ug/L 100 104 104 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/06/2020 05:29 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 25 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Foothills LF/Leachate 92487995 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2954006 2954007 MS MSD 92487992015 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 107 107 107 106 75-125 0 20 Arsenic ug/L ND 100 100 97.7 98.6 98 99 75-125 1 20 Barium ug/L 31.OJ 100 100 130 128 99 97 75-125 2 20 Beryllium ug/L 0.073J 100 100 101 100 101 100 75-125 1 20 Cadmium ug/L ND 100 100 97.8 99.2 98 99 75-125 1 20 Chromium ug/L 1.2J 100 100 101 104 100 103 75-125 3 20 Cobalt ug/L 0.96J 100 100 101 99.9 100 99 75-125 1 20 Copper ug/L ND 100 100 101 99.7 100 99 75-125 1 20 Lead ug/L 0.51J 100 100 100 101 100 100 75-125 1 20 Nickel ug/L ND 100 100 99.4 101 99 101 75-125 2 20 Selenium ug/L ND 100 100 94.9 93.8 95 94 75-125 1 20 Silver ug/L ND 100 100 97.8 97.9 98 98 75-125 0 20 Thallium ug/L ND 100 100 98.7 99.7 99 100 75-125 1 20 Vanadium ug/L ND 100 100 101 101 99 100 75-125 1 20 Zinc ug/L 5.1J 100 100 108 108 102 102 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/06/2020 05:29 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 25 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92487995 QC Batch: 556292 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. G Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92487995001 METHOD BLANK: 2953894 Matrix: Water Associated Lab Samples: 92487995001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Nitrate ug/L ND 40.0 16.0 07/28/20 15:53 Nitrogen, Nitrite ug/L ND 40.0 18.0 07/28/20 15:53 Nitrogen, NO2 plus NO3 ug/L ND 40.0 16.0 07/28/20 15:53 LABORATORY CONTROL SAMPLE: 2953895 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate ug/L 1500 1500 100 90-110 Nitrogen, Nitrite ug/L 1000 1020 102 90-110 Nitrogen, NO2 plus NO3 ug/L 2500 2520 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2953964 2953965 MS MSD 92487995001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate ug/L ND 1500 1500 2220 2380 144 155 90-110 7 10 Nitrogen, Nitrite ug/L 222 1000 1000 1500 1500 127 128 90-110 1 10 M3 Nitrogen, NO2 plus NO3 ug/L 285 2500 2500 3720 3890 137 144 90-110 4 10 M3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/06/2020 05:29 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 25 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92487995 QC Batch: 556276 Analysis Method: SM 521 OB-2011 QC Batch Method: SM 521OB-2011 Analysis Description: 5210E BOD, 5 day Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92487995001 METHOD BLANK: 2953810 Matrix: Water Associated Lab Samples: 92487995001 Blank Reporting Parameter Units Result Limit BOD, 5 day ug/L ND 2000 LABORATORY CONTROL SAMPLE: 2953811 Spike LCS Parameter Units Conc. Result BOD, 5 day ug/L 198000 183000 SAMPLE DUPLICATE: 2954094 92487962002 Dup Parameter Units Result Result BOD, 5 day ug/L 305 mg/L 320000 MDL Analyzed Qualifiers 2000 08/03/20 09:32 LCS % Rec % Rec Limits Qualifiers 92 84.6-115.4 Max RPD RPD Qualifiers 5 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/06/2020 05:29 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 25 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92487995 QC Batch: 556523 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92487995001 METHOD BLANK: 2954735 Associated Lab Samples: 92487995001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 07/29/20 15:41 1,1,1-Trichloroethane ug/L ND 1.0 0.18 07/29/20 15:41 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 07/29/20 15:41 1,1,2-Trichloroethane ug/L ND 1.0 0.24 07/29/20 15:41 1,1-Dichloroethane ug/L ND 1.0 0.27 07/29/20 15:41 1,1-Dichloroethene ug/L ND 1.0 0.24 07/29/20 15:41 1,2,3-Trichloropropane ug/L ND 1.0 0.35 07/29/20 15:41 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 07/29/20 15:41 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 07/29/20 15:41 1,2-Dichlorobenzene ug/L ND 1.0 0.29 07/29/20 15:41 1,2-Dichloroethane ug/L ND 1.0 0.34 07/29/20 15:41 1,2-Dichloropropane ug/L ND 1.0 0.19 07/29/20 15:41 1,4-Dichlorobenzene ug/L ND 1.0 0.26 07/29/20 15:41 2-Butanone (MEK) ug/L ND 5.0 3.3 07/29/20 15:41 2-Hexanone ug/L ND 5.0 0.57 07/29/20 15:41 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 07/29/20 15:41 Acetone ug/L ND 25.0 6.2 07/29/20 15:41 Acrylonitrile ug/L ND 10.0 0.90 07/29/20 15:41 Benzene ug/L ND 1.0 0.15 07/29/20 15:41 Bromochloromethane ug/L ND 1.0 0.34 07/29/20 15:41 Bromodichloromethane ug/L ND 1.0 0.26 07/29/20 15:41 Bromoform ug/L ND 1.0 0.62 07/29/20 15:41 Bromomethane ug/L ND 2.0 0.62 07/29/20 15:41 Carbon disulfide ug/L ND 2.0 0.40 07/29/20 15:41 Carbon tetrachloride ug/L ND 1.0 0.22 07/29/20 15:41 Chlorobenzene ug/L ND 1.0 0.23 07/29/20 15:41 Chloroethane ug/L ND 1.0 0.49 07/29/20 15:41 Chloroform ug/L ND 5.0 2.3 07/29/20 15:41 Chloromethane ug/L ND 1.0 0.39 07/29/20 15:41 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 07/29/20 15:41 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 07/29/20 15:41 Dibromochloromethane ug/L ND 1.0 0.41 07/29/20 15:41 Dibromomethane ug/L ND 1.0 0.46 07/29/20 15:41 Ethylbenzene ug/L ND 1.0 0.26 07/29/20 15:41 lodomethane ug/L ND 20.0 12.5 07/29/20 15:41 Methylene Chloride ug/L ND 5.0 3.7 07/29/20 15:41 Styrene ug/L ND 1.0 0.27 07/29/20 15:41 Tetrachloroethene ug/L ND 1.0 0.16 07/29/20 15:41 Toluene ug/L ND 1.0 0.24 07/29/20 15:41 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 07/29/20 15:41 Qualifiers v1 IK,v1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/06/2020 05:29 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 25 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Foothills LF/Leachate Pace Project No.: 92487995 METHOD BLANK: 2954735 Associated Lab Samples: 92487995001 Parameter Units trans- 1,3-Dichloropropene ug/L trans-1,4-Dichloro-2-butene ug/L Trichloroethene ug/L Trichlorofluoromethane ug/L Vinyl acetate ug/L Vinyl chloride ug/L Xylene (Total) ug/L 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % LABORATORY CONTROL SAMPLE: 2954736 Parameter QUALITY CONTROL DATA Matrix: Water Blank Result Reporting Limit ND 1.0 ND 1.0 ND 1.0 ND 1.0 ND 2.0 ND 1.0 ND 1.0 105 70-130 97 70-130 100 70-130 MDL Analyzed 0.31 07/29/20 15:41 0.54 07/29/20 15:41 0.22 07/29/20 15:41 0.31 07/29/20 15:41 1.4 07/29/20 15:41 0.24 07/29/20 15:41 0.63 07/29/20 15:41 07/29/20 15:41 07/29/20 15:41 07/29/20 15:41 Qualifiers Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 57.5 115 70-130 1,1,1-Trichloroethane ug/L 50 57.0 114 70-130 1,1,2,2-Tetrachloroethane ug/L 50 53.5 107 70-130 1,1,2-Trichloroethane ug/L 50 55.1 110 70-130 1,1-Dichloroethane ug/L 50 52.5 105 70-130 1,1-Dichloroethene ug/L 50 52.9 106 70-130 1,2,3-Trichloropropane ug/L 50 55.9 112 70-130 1,2-Dibromo-3-chloropropane ug/L 50 63.2 126 70-130 1,2-Dibromoethane (EDB) ug/L 50 56.4 113 70-130 1,2-Dichlorobenzene ug/L 50 56.2 112 70-130 1,2-Dichloroethane ug/L 50 54.9 110 70-130 1,2-Dichloropropane ug/L 50 54.4 109 70-130 1,4-Dichlorobenzene ug/L 50 55.4 111 70-130 2-Butanone (MEK) ug/L 100 105 105 64-135 2-Hexanone ug/L 100 106 106 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 108 108 70-130 Acetone ug/L 100 114 114 61-157 Acrylonitrile ug/L 250 273 109 61-143 Benzene ug/L 50 52.4 105 70-130 Bromochloromethane ug/L 50 53.5 107 70-130 Bromodichloromethane ug/L 50 54.0 108 70-130 Bromoform ug/L 50 59.9 120 70-130 Bromomethane ug/L 50 59.3 119 38-130 v1 Carbon disulfide ug/L 50 48.3 97 68-130 Carbon tetrachloride ug/L 50 56.4 113 70-130 Chlorobenzene ug/L 50 52.4 105 70-130 Chloroethane ug/L 50 57.7 115 37-142 IK,v1 Chloroform ug/L 50 53.5 107 70-130 Chloromethane ug/L 50 43.5 87 48-130 cis-1,2-Dichloroethene ug/L 50 52.0 104 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/06/2020 05:29 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 25 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92487995 LABORATORY CONTROL SAMPLE: 2954736 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 59.0 118 70-130 Dibromochloromethane ug/L 50 59.1 118 70-130 Dibromomethane ug/L 50 57.8 116 70-130 Ethylbenzene ug/L 50 52.5 105 70-130 lodomethane ug/L 100 106 106 40-130 Methylene Chloride ug/L 50 49.1 98 67-132 Styrene ug/L 50 55.3 111 70-130 Tetrachloroethene ug/L 50 51.4 103 69-130 Toluene ug/L 50 53.2 106 70-130 trans-1,2-Dichloroethene ug/L 50 54.3 109 70-130 trans- 1,3-Dichloropropene ug/L 50 59.7 119 70-130 trans-1,4-Dichloro-2-butene ug/L 50 61.4 123 35-189 Trichloroethene ug/L 50 55.0 110 70-130 Trichlorofluoromethane ug/L 50 47.5 95 63-130 Vinyl acetate ug/L 100 110 110 55-143 Vinyl chloride ug/L 50 43.7 87 70-131 Xylene (Total) ug/L 150 159 106 70-130 1,2-Dichloroethane-d4 (S) % 101 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 97 70-130 MATRIX SPIKE SAMPLE: 2954738 92487992006 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 21.1 105 73-134 1,1,1-Trichloroethane ug/L ND 20 22.0 110 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 20.9 104 70-136 1,1,2-Trichloroethane ug/L ND 20 21.2 106 70-135 1,1-Dichloroethane ug/L ND 20 22.3 111 70-139 1,1-Dichloroethene ug/L ND 20 22.8 114 70-154 1,2,3-Trichloropropane ug/L ND 20 20.8 104 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 19.8 99 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 22.2 111 70-137 1,2-Dichlorobenzene ug/L ND 20 21.6 108 70-133 1,2-Dichloroethane ug/L 0.39J 20 21.0 103 70-137 1,2-Dichloropropene ug/L ND 20 22.4 112 70-140 1,4-Dichlorobenzene ug/L ND 20 21.6 108 70-133 2-Butanone (MEK) ug/L ND 40 41.8 105 60-139 IK 2-Hexanone ug/L ND 40 41.6 104 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 40.7 102 65-135 Acetone ug/L ND 40 42.2 105 60-148 Acrylonitrile ug/L ND 100 101 101 64-147 Benzene ug/L 0.52J 20 22.6 110 70-151 Bromochloromethane ug/L ND 20 23.8 119 70-141 Bromodichloromethane ug/L ND 20 19.5 98 70-138 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/06/2020 05:29 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 25 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92487995 MATRIX SPIKE SAMPLE: 2954738 92487992006 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Bromoform ug/L ND 20 20.3 102 63-130 Bromomethane ug/L ND 20 17.6 88 15-152 IK,v3 Carbon disulfide ug/L ND 20 21.3 107 69-149 Carbon tetrachloride ug/L ND 20 22.1 110 70-143 Chlorobenzene ug/L ND 20 21.5 107 70-138 Chloroethane ug/L ND 20 21.6 108 52-163 Chloroform ug/L ND 20 21.4 107 70-139 Chloromethane ug/L ND 20 17.7 89 41-139 cis-1,2-Dichloroethene ug/L 1.2J 20 23.8 113 70-141 cis-1,3-Dichloropropene ug/L ND 20 22.7 114 70-137 Dibromochloromethane ug/L ND 20 20.7 104 70-134 Dibromomethane ug/L ND 20 21.7 109 70-138 Ethylbenzene ug/L ND 20 21.6 108 66-153 Iodomethane ug/L ND 40 34.5 86 20-138 Methylene Chloride ug/L ND 20 22.1 111 42-159 Styrene ug/L ND 20 21.8 109 70-135 Tetrachloroethene ug/L ND 20 21.4 107 59-143 Toluene ug/L ND 20 21.4 107 59-148 trans-1,2-Dichloroethene ug/L ND 20 22.9 114 70-146 trans- 1,3-Dichloropropene ug/L ND 20 21.9 109 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 19.5 98 47-135 Trichloroethene ug/L ND 20 21.8 109 70-147 Trichlorofluoromethane ug/L ND 20 19.6 98 70-148 Vinyl acetate ug/L ND 40 42.8 107 49-151 IK Vinyl chloride ug/L ND 20 18.5 92 70-156 Xylene (Total) ug/L ND 60 65.4 109 63-158 1,2-Dichloroethane-d4 (S) % 103 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 100 70-130 SAMPLE DUPLICATE: 2954739 92487992007 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/06/2020 05:29 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 25 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92487995 SAMPLE DUPLICATE: 2954739 Parameter Units 92487992007 Result 1,4-Dichlorobenzene ug/L ND 2-Butanone (MEK) ug/L ND 2-Hexanone ug/L ND 4-Methyl-2-pentanone (MIBK) ug/L ND Acetone ug/L ND Acrylonitrile ug/L ND Benzene ug/L ND Bromochloromethane ug/L ND Bromodichloromethane ug/L ND Bromoform ug/L ND Bromomethane ug/L ND Carbon disulfide ug/L ND Carbon tetrachloride ug/L ND Chlorobenzene ug/L ND Chloroethane ug/L ND Chloroform ug/L ND Chloromethane ug/L ND cis-1,2-Dichloroethene ug/L ND cis-1,3-Dichloropropene ug/L ND Dibromochloromethane ug/L ND Dibromomethane ug/L ND Ethylbenzene ug/L ND lodomethane ug/L ND Methylene Chloride ug/L ND Styrene ug/L ND Tetrachloroethene ug/L ND Toluene ug/L ND trans-1,2-Dichloroethene ug/L ND trans- 1,3-Dichloropropene ug/L ND trans-1,4-Dichloro-2-butene ug/L ND Trichloroethene ug/L ND Trichlorofluoromethane ug/L ND Vinyl acetate ug/L ND Vinyl chloride ug/L ND Xylene (Total) ug/L ND 1,2-Dichloroethane-d4 (S) % 106 4-Bromofluorobenzene (S) % 96 Toluene-d8 (S) % 100 Dup Result RPD Max RPD Qualifiers ND 30 ND 30 IK ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 I K,v2 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 IK ND 30 ND 30 99 101 102 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/06/2020 05:29 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 25 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92487995 QC Batch: 556512 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92487995001 METHOD BLANK: 2954685 Matrix: Water Associated Lab Samples: 92487995001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfate ug/L ND 1000 500 07/29/2018:37 LABORATORY CONTROL SAMPLE: 2954686 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate ug/L 50000 53400 107 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2954687 2954688 MS MSD 92488137001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L 558 mg/L 50000 50000 589000 582000 62 48 90-110 1 10 M6 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2954689 2954690 MS MSD 92488133002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L 7.6 mg/L 50000 50000 59700 60600 104 106 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/06/2020 05:29 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 25 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92487995 QC Batch: 557408 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92487995001 METHOD BLANK: 2958614 Associated Lab Samples: 92487995001 Parameter Units Nitrogen, Ammonia ug/L LABORATORY CONTROL SAMPLE: 2958615 Parameter Units Nitrogen, Ammonia ug/L Matrix: Water Blank Reporting Result Limit ND 100 Spike LCS Conc. Result 5000 4900 MDL Analyzed Qualifiers 70.0 08/04/2010:54 LCS % Rec % Rec Limits Qualifiers 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2958616 2958617 MS MSD 92487592001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Ammonia ug/L 89.4 mg/L 5000 5000 99000 98300 191 177 90-110 1 10 M6 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2958618 2958619 MS MSD 92487594001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Ammonia ug/L 144 mg/L 5000 5000 157000 165000 267 419 90-110 5 10 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/06/2020 05:29 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 25 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92487995 QC Batch: 556675 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92487995001 METHOD BLANK: 2955471 Associated Lab Samples: 92487995001 Parameter Units Phosphorus ug/L LABORATORY CONTROL SAMPLE: 2955472 Parameter Units Phosphorus ug/L Matrix: Water Blank Reporting Result Limit ND 50.0 Spike LCS Conc. Result 2500 2540 MDL Analyzed Qualifiers 25.0 07/30/2018:58 LCS % Rec % Rec Limits Qualifiers 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2955473 2955474 MS MSD 92487594001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phosphorus ug/L 255 mg/L 5000 5000 268000 264000 274 178 90-110 2 10 M6 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2955475 2955476 MS MSD 92487596001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phosphorus ug/L 369 mg/L 5000 5000 368000 376000 -11 145 90-110 2 10 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/06/2020 05:29 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 25 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92487995 QC Batch: 557584 Analysis Method: SM 5220D-2011 QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92487995001 METHOD BLANK: 2959382 Matrix: Water Associated Lab Samples: 92487995001 Blank Reporting Parameter Units Result Limit Chemical Oxygen Demand ug/L ND 25000 LABORATORY CONTROL SAMPLE: 2959383 Spike LCS Parameter Units Conc. Result Chemical Oxygen Demand ug/L 750000 755000 MDL Analyzed Qualifiers 12500 08/04/2015:14 LCS % Rec % Rec Limits Qualifiers 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2959384 2959385 MS MSD 92487571001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 187 mg/L 100000 100000 299000 393000 111 206 90-110 27 3 M1,R1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2959388 2959389 MS MSD 92488178002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L ND 100000 100000 107000 112000 104 109 90-110 4 3 R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/06/2020 05:29 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 25 Pace Analytical Services, LLC lac, Analyilcal ® 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALIFIERS Project: Foothills LF/Leachate Pace Project No.: 92487995 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M3 Matrix spike recovery was outside laboratory control limits due to matrix interferences. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. R1 RPD value was outside control limits. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/06/2020 05:29 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 25 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Foothills LF/Leachate Pace Project No.: 92487995 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92487995001 1403-Leachate 556882 92487995001 1403-Leachate EPA 3005A 556322 EPA 6020B 556587 92487995001 1403-Leachate EPA 353.2 556292 92487995001 1403-Leachate SM 5210B-2011 556276 SM 5210B-2011 557422 92487995001 1403-Leachate EPA 8260D 556523 92487995001 1403-Leachate EPA 300.0 Rev 2.1 1993 556512 92487995001 1403-Leachate EPA 350.1 Rev 2.0 1993 557408 92487995001 1403-Leachate EPA 365.1 Rev 2.0 1993 556675 EPA 365.1 Rev 2.0 1993 556959 92487995001 1403-Leachate SM 5220D-2011 557584 SM 5220D-2011 557816 Date: 08/06/2020 05:29 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 25 , x 41,"-- m m a � `m m m _ - o =r g m I�TI m 0 a � �t C m 7 - O z r O co co •a cl) F f� "' �,a O v o ui 'i o m N og M (Am = s ^� m m m x c m NNon 3a PWM m N -a iA r 0 _ _ r v O 0 .-. � o z o z w C) _D m �---- w7omz-aAzoa 5 z m o =X c APPENDIX I - VOC BY 8260 < m � APPENDIX I - METALS w - BOD, NITRATE, NITRITE w s � - tis< NITRATE+ NITRITE w >< AMMONIA, COD, TKN N PHOSPHORUS N < w a SULFATErn O � _ x V ,. �y N� m m W-3 c z G-- c cam" `'sa_ _ .. ayrs �xsrs 101 I— .� ss�`fa•.tt icSdN:'ee==..,ya,?1 :' to _ m as3cSa; 11= 0p4 m o Dm y0 �D�TL r- 0[ m' -�m�� -4 mX m z O X ;D X r -0r> CAO 1 v -4 CD p wr 1 zn 0) co fn cccmr i e zz aze m Z a o z 0Page 24 o Sample Condition•• Receipt �oeAnlalyt,o 2f Client Name: i �,� -F l�C Project # '; i'V�c _ wo# * 9 Courier: Fed Ex ❑ UPS ❑ USPS ❑ Client ❑ Commercial ❑ Pace Ott 2481`995 Tracking PM: MP Due Date: 08/06/20 Custody Seal on Cooler/Box Present: ❑ yes no Seals intact: T ! CLIENT: GARepHC Packing Material: ❑ Bubble Wrap Bubble Bags ❑ None ❑ Othell Thermometer Used Type of Ice: a Blue ne Samples on ice, cooling process has begun Cooler Temperature (i Biological Tissue is Froze : Yes No Date and Initials of rson examining contents Temp should be above freezing to 6`C Comme Chain of Custod Present: Yes ❑No ©N/A 1. Chain of Custody Filled Out: Yes ❑No IL N/A 2. Chain of Custody Relinquished: Yes ❑No QNIA 3. Sampler Name & Signature on COC: Yes ❑No 6NIA 4. Samples Arrived within Hold Time: J6Yes ❑No ❑NIA 5, Short Hold Time Analysis a72hr : OrYes o ONIA 6, Rush Turn Around Time Requested: ❑Yes (JNo 6WA 7. Sufficient Volume: OYes ❑No [INIA 8. Correct Containers Used: VYes ❑No ONIA $, -Pace Containers Used, Yes ❑Na QN1A Containers Intact: Yes ❑No I❑N1A 10. Filtered volume received for Dissolved tests ❑Yes ❑No R NIA 11. Sample Labels match COC: VYes ❑No E IN/A 12. -Includes date/timellD/Analysis Matrix: a, r All containers needing preservation have been checked. *.s. ❑No / LINIA 13. j} n o+ De aAS V 5+tJ All containers needing preservation are found to be in ❑Yes llo Il7NIA compliance with EPA recommendation. Initial when Lot # of added exceptions VOA, coliform, TOC, O&G WI-DRO (water) ❑Yes ❑No completed preservative Samples checked for dechlorination: ❑Yes ❑No NIA 14. Headspace in VOA Vials >6mm : ❑Yes ❑No N1A 15. Trip Blank Present: ❑Yes �No ❑N1A 16. Trip Blank Custody Seals Present ❑Yes ❑No ANIA Pace Trip Blank Lot # ifpurchased): Client Notification/ Resolution: Field Data Required? Y 1 N Person Contacted: Comments/ Resolution: Project Manager Review: DatelTime: Date: Note Whenever there is a discrepancy affecting North Carolina compliance samples, a DDpry of this form will be sent to the North Carolina DEHNR Certification Office ( i e out of hold, incorrect preservative, out of temp, incorrect containers] F-ALLC003rev.3. I1Septemg&%t& of 25 FOOTHILLS LANDFILL JULY 27, 2020 DEPTH TO RISER .' WATER ,:. SAMPLE'" ':WATER: ELEV`' 64- MW-1 R2 15.10 1516.22 1501.12 MW-2R 48.41 1253.36 1204.95 MW-3 52.04 1241.95 1189.91 MW-3R 57.24 1242.69 1185.45 MW-3R2 38.79 1240.83 1202.04 MW-4 41.79 1171.18 1129.39 MW-5 46.58 1175.07 1128.49 MW-6 40.69 1176.82 1136.13 MW-7 29.44 1183.13 1153.69 MW-8 30.46 1195.18 1164.72 MW-9 68.44 1290.79 1222.35 MW-10 77.11 1358.53 1281.42 MW-11 82.62 1401.71 1 1319.09 * FROM THE TOP OF RISER SITE NAME: FOOTHILLS LF POINT ID. LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: DEIONIZED WATER LAB SAMPLE /PROJECT#: FIELD BLANK E S & S - R.CHIODO NA INITIAL WA'TE EVEL (FT) DEPTH TO BOTTOM (FT) ELEV., MEAS. PT. (MSL): ELEVATION, G/W (MSQ: DATE TIME: START/FINISH / METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PU ( ) YES ( ) NO ( ) S.S. BAILER ( ) QED PUMP ( ) OTHER WELL RISER DIAMETER (IN.): ( ) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OT ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO DR S ( ) YES ( ) NO TOTAL VOL. EVACUATED (GAL) WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START FINISH EVACUATION STABILIZATION DATA DATE/TIME rl'2tO-20 / ,J'IS DEPTH TO GROUNDWATER (FT) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP ( ) YES ( ) S.S. BAILER ( ) QED PUMP ( ) OTHER ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME PH Std.Units TEMP. C CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV DISS.OXY. PPM OTHER NA -NA NA NA NA NA NA NA GENERAL INFORMATION q OF WEATHER CONDITIONS AT TIME OF SAMPLING: SDI ^�'`�`fi /0 SAMPLE CHARACTERISTICS: C�-AQ- 7 COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF POINT ID: TRIP BLANK LOCATION: LENOIR, NORTH CAROLINA E S & S - R.CHIODO SAMPLE MATRIX: DEIONIZED WATER LAB SAMPLE/PROJECT#: NA EVACUATION INFORMATION INITIAL'LEVEL (FT) DEPTH TO BOTTOM (FT) ELEV., MEAS. PT. (MSL): ELEVATION, GNV (MSL): DATE TIME: START/FINISH / METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS P ( ) YES ( ) NO ( ) S.S. BAILER ( ) QED PUMP ( ) OTHER WELL RISER DIAMETER (IN.): ( ) 2 ( ) 3 ( ) 4 ( ) 6 ( ) O ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO D ESS ( ) YES ( ) NO TOTAL VOL. EVACUATED (GAL) WATER LEVEL END PURGE (FT TURBIDITY OF PURGINGS: START FINISH EVACUATION STABILIZATION DATA stligirpTly SAMPLING INFORMATION DATE/TIME rj_2b-20 / 1j;l$ METHOD OF SAMPLING: ( ) PVC BAILER ( ) S.S. BAILER ( ) S.S. BAILER ( ) QED PUMP SAMPLING FIELD MEASUREMENT DATA DEPTH TO GROUNDWATER (FT) NA SAMPLING EQUIPMENT DEDICATED: ( ) GRUNDFOS PUMP ( ) YES ( ) OTHER ( ) NO TIME pH Std.Units TEMP. C CONDUCT. umhos/cm I TURBIDITY NTU OTHER eh m(PM DISS.OXY, OTHER NA NA NA NA NA NA NA NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: ✓UN `� SAMPLE CHARACTERISTICS: CL5-AdL COMMENTS: VOAONLY SAMPLE COLLECTION NUMBER a"` SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER ELEVATION, MEAS.PT.(MSL): NA DATE METHOD OF EVACUATION: POINT ID: FIELD REPRESENTATIVE LAB SAMPLE IPROJECT SW-5 E S & S - B.CHIODO IM_\ DEPTH TO BOTTOM (FEET) NA ELEVATION, GAN (MSQ: NA TIME: START/FINISH I EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) CONTINUOU ( ) YES ( ) NO ( ) S.S. BAILER ( ) GRUNDFOS PUMP PUMPING WELL WELL RISER DIAMETER (IN.): ( ) 2 ( ) 4 ( ) 6 ( ) OTHER_ ONE (1) RISER VOLUME(GAL) WAS WELL PURGED TO DRY S ( )YES( )NO TOTAL VOLUME EVACUATED (GAL) WATER LEVEL AFTER PURGE (FT.) TURBIDITY OF PURGINGS: START FINISH EVACUATION STABILIZATION DATA TIME PURGE RATE m/htz CUMULATIV VOLUME C pH its SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE / TIME '7-2(0.- 2-0 / 1 5 •'' R WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRAPUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME PH Std.Units I SPEC. CONDUCT. umhos/cm I TEMP. C) I TURBIDITY INTL) I REDOX eh m DISS. OXY. P�PyM OTHER Ysno r7.01 9S.S m'26-2- rJ8-,r7 +9,`3 5-&(o NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SUG} or n).:I' /J SAMPLE CHARACTERISTICS: I 2S, _ TArJ COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 3 SITE NAME: FOOTHILLS LF POINT ID: SW-4 LOCATION: LENOIR. NORTH CAROLINA MATRIX: SURFACE WATER INITIAL WATE EL (FEET) NA ELEVATION, MEAS.PT.(MSL): NA DATE METHOD OF EVACUATION: ( ) PVC BAILER ( ) WELL WIZARD ( ) ( ) S.S. BAILER ( ) GRUNDFOS PUMP P WELL RISER DIAMETER (IN.): ( ) 2 ( ) 4 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA FIELD REPRESENTATIVE: E S 8. S - B.CHIODO LAB SAMPLE I PROJECT 4WAS EPURGEDTO T) NA NA / N EQUIPMENT DEDICATED: ( ) NO LI H DR ESS (( )Y ) WATER LEVEL AFTER PURGE (FT.) FINISH TIME PURGERAT m/htz IVE VOLUME TEMP. PH Std.Units SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME /'2("'20 1 ' �'WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRAPUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME PH Std.Units SPEC. CONDUCT. umhosry//cm TEMP. 1 C TURBIDITY NTU REDOX eh mV DISS. OXY. PM OTHER Is:sl '7�qI &G./ 2S.I IS,70 -'IZ.y 'y,0(n NA GENERAL INFORMATION q of WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: CL,FfLQ_ COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 4 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER ELEVATION, MEAS.PT.(MSL): NA DATE METHOD OF EVACUATION: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA POINT ID: SW-3 FIELD REPRESENTATIVE: E S & S - B.CHIODO II_\-11K-Ti Y»r�l DEPTH TO BOTTOM (FEET) NA ELEVATION, GIW (MSL): NA TIME: START/FINISH ! EVACUATION EQUIPMENT DEDICATED: ( ) CONTINUOUS ( ) YES ( ) NO PUMPING WELL ( ) 4 ( ) 6 ( ) OTHER_ WAS WELL PURGED TO DRYNES YES ( ) NO WATER LEVEL AFTER PURGE (FT.) FINISH TIME PURGE RAT m/htr TIVE VOLUME TEMP. pH Std.Units SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh m NA 0 NA NA NA SAMPLING INFORMATION DATE / TIME r7-2to' 2O / �D • I Z WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units SPEC. CONDUCT. umhos/cm I TEMP. C TURBIDITY NTU REDOX eh m DISS.OXY. PPM OTHER ib:ly 799 &N.(- 23.& �.'72 -)s.8 IS-, it, I NA GENERAL INFORMATION q O F WEATHER CONDITIONS AT TIME OF SAMPLING: SurJ�3 L SAMPLE CHARACTERISTICS: C LFAlR. COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER SITE NAME FOOTHILLS LF POINT ID: MW - 11 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER FIELD REPRESENTATIV E S & S - B.CHIODO LAB SAMPLE /PROJECT#: NA EVACUATION INFORMATION 92.(12 log-, y0 INITIAL WATER LEVEL (FT): O 2 • (o 2 DEPTH TO BOTTOM (FT): ELEV., MEAS. PT. (MSL): I �'I O % ! ELEVATION, GAN (MSQ: 1 3) 9• 6 9 DATE / —27— 2D TIME: START/FINISH S: y0 / 6 ( 12 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 9,) l WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) a?, 00 WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START CI.AR FINISH CLEAR EVACUATION STABILIZATION DATA TIME PURGE RATE ML/MIN DTW FT CUMUL. VOL GAL TEMP. C pH Std.Units CONDUCT. umhos/cm TURBIDITY NTU REDOX eh m D.O. MG/L S:yo 250 8UZ 0 Ab.2 ?,99 50.y o,y) -`9o.5 a,22 s, 4 250 92.77 0.25 IL, 1 7,SG 572,2 &.71 - A 1 2,/S S =`� 8 250 2.7y 0.50 11" 1 7, t/> S2, S 0,25 - /2.2. 2,1 Z. 32 250 k23r 0.75 )6.1 '7.Y2 S3. 1 6.2o -(/.y 2o9 Sal. 1 250 fr2,771 1.00 1 I6,0 7,Yo 53,y CG.13 -10.6 2,OS7 6,00 250 87-79 1.25 1 G.0 r% yo 5 % ) &- m - /O, S 1,91 d;ov 250 82,10 1.50 ls.9 7.3' SN,y 0,11 -9.7 /,9b 250 SZ, O 1.75 M9 7.37 5%41 0•12 -9.3 /,94 250 &2.80 2.00 15.9 7,37 5y.5 o./n -9,2 /,9S- m 29;0- SAMPLING INFORMATION DATE/TIME '7-27'20 / �• 12 DEPTH TO GROUNDWATER (FT) 82. &o METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X)QEDWWPUMP ( ) OTHER ( ) NO GENERAL INFORMATION Slw,J�.ft9 of 9 WEATHER CONDITIONS AT TIME OF SAMPLING: r SAMPLE CHARACTERISTICS: C LF-44 COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER SITE NAME FOOTHILLS LF POINT ID: mw - l o LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIV E S & S- B.CHIODO SAMPLE MATRIX: GROUNDWATER LAB SAMPLE I PROJECT#: NA EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ( !. ELEV., MEAS. PT. (MSL): 13 S �• S 3 I-S DATE +-a7-20 DEPTH TO BOTTOM (FT): ELEVATION, G/W (MSQ: I o7, S ) . q 2 TIME: START/FINISH 6:2q l 17,o1 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 1.79 WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) a • 00 WATER LEVEL END PURGE (FT) r77. 31 TURBIDITY OF PURGINGS: START G�f...e1L FINISH CkSWL EVACUATION STABILIZATION DATA TIME PURGE RATE ML/MIN DTW FT CUMUL. VOL GAL TEMP. C pH Std.Units CONDUCT. umhos/cm TURBIDITY NTU REDOX eh m D.O. MG/L :2.4 250 7711 0 16.2 7.33 6o1.3 ©.53 -73 6.09 3 250 77z1 0.25 1(,'2 7,25' 60.9 1,10 _3.9 6,oy 6 %3"7 250 7725 0.50 16.2 "7. 2 Z Ga. 6 1, V, - 2, y 6:41 250 7728- 0.75 I(„Z 7.2a (v0.y 1. To -/,G. 5,99 6;Ws 250 77yo 1.00 1b.2 7.17 60.2 1,14 +0.*7 s 9S 6 :yg 250 77.30 1 1.25 It.- 1 7.12 1 5 9A 2.12 +3. y 5:92 6',S3 250 7231 1.50 Poll 7,ol 5i.7 2,5Z *yq 5:92 6:57 250 7231 1.75 16,0 710 5).7 2. 5'0 4 It. S 5,90 7:ot 250 7731 2.00 709 5OX ?.YS +y.fi 5,90 SAMPLING INFORMATION �-'7 I-7t•� DATE/TIME 7-27_20 / 1 •� ( DEPTH TO GROUNDWATER (FT) / /• •3� METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SoAl"41CTS SAMPLE CHARACTERISTICS: C (F� SAMPLE COLLECTION NUMBER SITE NAME FOOTHILLS LF POINT ID: MW - 9 LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIV E S & S - B.CHIODO SAMPLE MATRIX: GROUNDWATER LAB SAMPLE /PROJECT#: NA EVACUATION INFORMATION INITIAL WATER LEVEL (FT): t0L6O I ELEV., MEAS. PT. (MSL): 12 7 a•'•I DATE 7-'x7-2O DEPTH TO BOTTOM (FT): 73.lfo ELEVATION, GNV (MSL): (2 2 2, 3 5- TIME: START/FINISH 7 17 / I. q9 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X)QEDWWPUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 0.711 WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) s?, 00 WATER LEVEL END PURGE (FT) 68-.' 7 TURBIDITY OF PURGINGS: START CL.;.AA- FINISH CL `-,AZ EVACUATION STABILIZATION DATA. TIME PURGE RATE ML/MIN DTW FT CUMUL. VOL GAL TEMP. C pH Std.Units CONDUCT. umhos/cm TURBIDITY NTU REDOX eh (mV) D.O. (MG/L 71'7 260 69,,vy 0 ) 9- 9 S 99 159, 9 6.37 -hGl.6' 3, Yo 71,21 250 Gf•53 0.25 1$.1. 5:97 159.& 0,35 +62.1 3..?6 7:ZS 250 ss 0.50 M's 5.9to IS91 0.98 +6?3 3.35 7: i9 250 Cast 0.75 tars S % 159.9 D, G 2- +6? y 332 7:33 250 ($37 1.00 1F!,5 5"96 I100,1 0,75 +-G2.S 7,,28 7:37 250 0,y? 1.25 )$.w 5S95- )W.1 0,78 +62,5 3, 28 7:y1 250 69..57 1.50 try S95' )V-Z 0,79 +62.9 3,Z(. `7:yS 250 69,,s7 1.75 ) fr y !;ms A00.L 0,76 +63,o 3, 2(m 7:yg 250 69.S7 2.00 19,4 S.95 160.3 0.7Z +G3,1 3,25 2 26a 2c59 SAMPLING INFORMATION DATE/TIME 7-27_20 / r1'tf9 DEPTH TO GROUNDWATER (FT) 6�S% METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SU Ny, d S SAMPLE CHARACTERISTICS: C 1.EAF-- COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): 15.10 ELEV., MEAAS, PT. (MSQ: 1 J 1 6. 22- DATE / - 2r7- 20 POINT ID: MW - IR2 FIELD REPRESENTATIV E S & S - B.CHIODO LAB SAMPLE/PROJECT#: NA DEPTH TO BOTTOM (FT): "1 3. 3y ELEVATION, GIW (MSL): I 0I. 12 TIME: START/FINISH b .) O / METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X)QEDWWPUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME(GAL) �'I.s2 WAS WELL PURGED TO DRYNESS( )YES(X)NO TOTAL VOL. EVACUATED (GAL) �- 00 WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START C IF.CX- FINISH L' (.F'4-z EVACUATION STABILIZATION DATA TIME PURGE RATE ML/MIN DTW FT CUMUL. VOL GAL TEMP. C pH Std.Units CONDUCT. umhos/cm TURBIDITY NTU REDOX eh m D.O. MG/L 9 ID 250 Is.io 0 1'7.9 6.1-0 8to 1 1.22 +3).5 7.Y8 $%14 250 IS.IR 0.25 (7,5 (,.s F).S )A' +3Y,8 ?-'is 8:18 250 Iszl 0.50 115 (0.50 779 i.0e 436,E P1Z 8:zz 250 15.23 0.75 17.4 (1.SD 7.S ),05 +-V7 1,39 81,zk- 250 IS.zy 1 1.00 17•4 6,y9 72.S o.99 +37,1 1134 8:3o 250 I5.25 1.25 17,4 61119 7. 0,95 4-37Z .30 834 250 IseL 1.50 IZN 6,`18 1 r7k b 6,93 +375 1.30 r6:3$ 250 Is.Z7 1.75 173 6,'98 r7.6 o.90 +371. 1.32, 8;yL 250 Is2? 2.00 17.3 6.98 '77.5 0,92 +37.2 /3Z 250 2!2f� zw 22B SAMPLING INFORMATION DATE/TIME 7-27-20 / .H2 DEPTH TO GROUNDWATER (FT) I9-Z7 METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER ELEVATION, MEAS.PT.(MSL): NA DATE METHOD OF EVACUATION: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED(GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA POINT ID: SW - 1 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE I PROJECT#: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSQ: NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( ) CONTINUOUS ( ) YES ( ) NO PUMPING WELL ( ) 4 ( ) 6 ( ) OTHER_ WAS WELL PURGED TO DRYNES YES ( ) NO WATER LEVEL AFTER PURGE (FT.) TIME PURGE RATE m/htr CUMU VOLUME TEMP. C pH Std.Units SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION / DATE/TIME -2i-20 / / � /o WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units SPEC. CONDUCT. umhos/cm I TEMP. C TURBIDITY NTU REDOX eh m DISS. OXY. PPM OTHER 9:1 6-cm 1 Ss. (o 123.9 1 9.88 +q).(o �1.6z NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: KNhs y SAMPLE CHARACTERISTICS: C kzp(Z. COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER /0 SITE NAME FOOTHILLS LF POINT ID: MW - 8 LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIV E S & S - B.CHIODO SAMPLE MATRIX: GROUNDWATER LAB SAMPLE/PROJECT#: NA EVACUATION INFORMATION 30 yb Li INITIAL WATER LEVEL (FT): DEPTH TO BOTTOM (FT): Lt ELEV., MEAS. PT. (MSQ: I I q IFS ELEVATION, G/W (MSLL): ' 1 A • 7 �- DATE r7-•27- 20 TIME: START/FINISH 1) 2q / /0: o METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X)QEDWWPUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 3nn. `o (o WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) d.00 WATER LEVEL END PURGE (FT) 3o.59 TURBIDITY OF PURGINGS: START C 1,64P- FINISH C tFAL EVACUATION STABILIZATION DATA TIME PURGE RATE ML/MIN DTW FT CUMUL. VOL GAL TEMP. C PH Std.Units CONDUCT. umhos/cm TURBIDITY NTU REDOX eh m D.O. MG/L Ci'.ZQ 250 30,46 0 -)d• 6 S. SS 76,3 2.SS +8N..S 2. /5 `9:33 250 30,sy 0.25 .20.b S.S3 76,1 3.95 +85 2_ 9:37 250 30..St, 0.50 20.1. 5, S 3 76.0 4/.7 S 8SS- 2.10 9:y1 250 30.57 0.75 .20,16 5,51 '7S.& S99- +BL,G 2.07 �:`19 250 7a57 1.00 2V,L S.49 75,7 C•So +g2y 2.0 t1;4q 250 3o.571 1.25 ZJ,5 S.SZ 7�. LIS 8s3 2.ay 9:53 250 3o.sy 1.50 2o,3 553 '7G,3 6,90 "1 2.02- 9:57 250 3o,S9 1.75 120.2 5sy 7L.3 6.9G +9y4 -2.01 )o•.ol 250 Sa.59 2.00 ao.2 S.S'9 '76.y (o.BQ +$N,S 2,0/ A 2w DATE/TIME 7-27-2-0 / 10:0I DEPTH TO GROUNDWATER (FT). 3o. Sq METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED W W PUMP ( ) OTHER ( ) NO GENERAL INFORMATIONr- WEATHER CONDITIONS AT TIME OF SAMPLING: SunJNy d SAMPLE CHARACTERISTICS: C (F-A-K , COMMENTS: APPENDIX I LIST 1 SAMPLE COLLECTION NUMBER SITE NAME FOOTHILLS LF POINT ID: MW - 7 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION („1 INITIAL WATER LEVEL (FT): ELEV., MErAtS. PT. (MSL): 1'R3 , 13 DATE J'��-mod FIELD REPRESENTATIV E S & S - B.CHIODO LAB SAMPLE/PROJECT#: DEPTH TO BOTTOM (FT): LIO. 13 ELEVATION, G/W (MSL): 3, (,9 TIME: START/FINISH I • )E / /0 : 50 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED W W PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 1,91 WAS WELL PURGED TO DRYNESS( )YES(X)NO TOTAL VOL. EVACUATED (GAL) .2 • PO WATER LEVEL END PURGE (FT) ?9. �s TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA G'✓12 FINISH C Lw TIME PURGE RATE ML/MIN DTW FT CUMUL. VOL GAL TEMP. C pH Std.Units CONDUCT. umhos/cm TURBIDITY NTU REDOX eh m D.O. MG/L 10'-I s' 250 29.111 0 1 &.3 (0.1) /D9, 2 " +5H.8 5:2D /0•.zz 250 2352 0.25 1&,9 S, go 112.8s Y2 +65,9 5'•t7 10'.2(� 250 2'),,S3 0.50 14).2 S.7cf 11S.S to,3to 4-72.6 5.15 10'• 30 250 29,53 0.75 1 S. 70 i 16j 3,7 1 +7Y, 2• 5,13 )O:Sv 250 2A 51v 1.00 14, (o S b3 119.) 3,3(, 479,.0 S 10 10:3$ 250 25,51f 1.25 1 11, 11 5.72 1 20, z 3.23 4 75, / 5-.10 1'Z",I L 250 24.57S 1.50 19.2 5.75 1 21.5 3.15 +73,7 $S Oq 10%46 250 25.0 1.75 19,2 S-,75 12),£s 3,17, +73,(, 5:09 )01130 250 21Sf 2.00 1C.1 5-,7b ra).9 3.og +'73,2 5-,06 SAMPLING INFORMATION DATE/TIME '7--27-20 / (o. SO DEPTH TO GROUNDWATER (FT) a9. 57 METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION (? 0 F WEATHER CONDITIONS AT TIME OF SAMPLING: 5m NNH, d S �/� i SAMPLE CHARACTERISTICS: C(F-Q COMMENTS: APPENDIX I LIST ^� SAMPLE COLLECTION NUMBER 'C SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: UNDERDRAIN WATER ELEVATION, MEAS.PT.(MSL): NA: -- DATE METHOD OF EVACUATION: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED(GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA POINT ID: LID - 2 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE PROJECT#: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH ! ( ) CONTINUOUS ( ) YES PUMPING WELL ( ) 4 ( ) 6 ( ) OTHER _ WAS WELL PURGED TO DRYI WATER LEVEL AFTER PURGE ) YES ( ) NO TIME PURGE RATE m/htz CtMtIbkTAlE. VOLUME TEMP. C PH Std.Units SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME `7"2�7"2.0 / WATER LEVEL PRIORTOSAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME PH Std.Units SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh (mV) DISS. OXY. (PPM OTHER lVo7 5-."72, a 10 23.9 $.O:L +7y.2 408' NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: 5CC of 0( jtyi dS SAMPLE CHARACTERISTICS: C CFAR COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 13 SITE NAME FOOTHILLS LF POINT ID: III w - 6 LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIV E S & S - B.CHIODO SAMPLE MATRIX: GROUNDWATER LAB SAMPLE / PROJECT #: NA EVACUATION INFORMATION q INITIAL WATER LEVEL (FT): d • 6 ! DEPTH TO BOTTOM (FT): So. SS ELEV., MEAS. PT. (MSQ: S 2 ELEVATION, G!W (MSQ: 113G.13 DATE %-27- ZO TIME: START/FINISH 11'.2 3 / METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) I. S ? WAS WELL PURGED TO DRYNESS( )YES(X)NO TOTAL VOL. EVACUATED (GAL) Q( o o WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START C. CF/a,2 FINISH C (Fi.I2 EVACUATION STABILIZATION DATA TIME PURGE RATE ML/MIN DTW FT CUMUL. VOL GAL TEMP. C pH Std.Units CONDUCT. umhos/cm TURBIDITY NTU REDOX eh m D.O. MG/L W23 250 qo. 61 o 20,0 S.&V I S'5-.7 y.S2 475,9 /.94 11:27 250 N0,77 0.25 19 .i S, (, Z. 1$3. 5 N $6 +- &a. 1 / 5 1 1I:31 250 111.77 0.50 19,5 S(-2 192.4) 3.90 +9o,2 /,9/ 1135 250 *.71 0,75 193 SG ISt2,7 3.&8 So. S- jo 1I:39 1 250 No.79 1.00 19,2 5,&1 182.y 3.57 +&0.6 4"9 Iwg3 250 g6,S0 1.25 l .Z 5-.&1 1t�9.2 3.75 +80.7 11:4,7 250 N0.9D 1.50 19.3 s.4o 177.& 3.8-) I I: s 1 250 yo.81 1.75 0,3 5,60 177. % 3, 8' y d-$l, s ►r..55 250 y0.81 2.00 19.3 S-.60 Ir775 3.72 ,85- � 2�0 SAMPLING INFORMATION DATE / TIME I -Z7- 20 I W S S DEPTH TO GROUNDWATER IFTI 'Y 0.0 1 METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: �Y�SUNNyrGSS SAMPLE CHARACTERISTICS: C � COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 14 SITE NAME FOOTHILLS LF POINT ID: MW - 5 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): I ELEV., MEAS. PT. (MSL): I i 7 5- 0r7 r! DATE - 27- 20 FIELD REPRESENTATIV E S & S - B.CHIODO LAB SAMPLE /PROJECTM DEPTH TO BOTTOM (FT): 5q, SO ELEVATION, G/W (MSL): i 1 a 9• y 9 TIME: START/FINISH 1 21 10 / 12. y Z METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 1.29 WAS WELL PURGED TO DRYNESS( )YES(X)NO TOTAL VOL. EVACUATED (GAL) 2,00 WATER LEVEL END PURGE (FT) glo.719 TURBIDITY OF PURGINGS: START ( L-/ FINISH aY(�,fLP EVACUATION STABILIZATION DATA TIME PURGE RATE ML/MIN) DTW F CUMUL. VOL GAL TEMP. (C) pH (Std.Units CONDUCT. umhos/cm TURBIDITY NTU REDOX eh m D.O. MG/L 1r.10 250 Y6.s8 0 20-4 5.90 ao 2 L 22 +".V -2.4S (2;14 250 y6L7 0.25 20.2 SAS M. G IO2 Fa.1 2.40 iat12 250 Y4,70 0.50 20.1 S,8S 190.9 o.sy fG&,4 235 t2:i2 250 y6.7Z 0.75 20.1 S.$S 1 Ri,G 0.11(, *419.0 2,33 1212to 250 Y6.73 1.00 20.0 5-M 1 138.7 o.'io 4(-9.7 2,31 tZ'.30 250 yL73 1.25 20.0 5.$V 1$9-,1/ 0.29 +693 2..31 i2:3Y 250 Y6,7S 1.50 20.1 S:$Y )g$,Z 0,24 -&V2 2,30 l2'.38 250 4L.7S 1.75 20.7 5,$5' I go'. 2- 0.21 +G$$ 2.30 12:42 250 y6.7s 2.00 20- 2 S,$5 )$$, 1 0.1 a +6$7 2.30 259 SAMPLING INFORMATION DATE/TIME %.a%-20 / I�>.:N 2 DEPTH TO GROUNDWATER (FT) �Io.7S METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED W W PUMP ( ) OTHER ( ) NO GENERAL INFORMATION r - or WEATHER CONDITIONS AT TIME OF SAMPLING: JuAIM SAMPLE CHARACTERISTICS: CIF.AR COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER i S SITE NAME FOOTHILLS LF POINT ID: MW-4 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION ) npI INITIAL WATER LEVEL (FT): Li / ELEV., MEAS. PT. (MSQ: DATE - Z 7- t.0 FIELD REPRESENTATIV E S & S - B.CHIODO LAB SAMPLE/PROJECT#: NA DEPTH TO BOTTOM (FT): S 2 , 2.0 ELEVATION, G/W (MSL): 1126).39 TIME: START/FINISH I2 $7 1 13:29 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME(GAL) WAS WELL PURGED TO DRYNESS( )YES(X)NO TOTAL VOL. EVACUATED (GAL) " ` 0 WATER LEVEL END PURGE (FT) 441,9 3 TURBIDITY OF PURGINGS: START Ck.FAtZ- FINISH C(..EAe- TIME PURGE RATE ML/MIN DTW FT CUMUL. VOL GAL TEMP. C PH Std.Units CONDUCT. umhos/cm TURBIDITY NTU REDOX eh (mV) D.O. (MG/L 12:5� 250 yl.q 0 al. v S-27 32.7 0, 33 +99,8 /,y(, 13:ot 250 41,99 0.25 20.2 S.2G 32.9 0,3Q t991 /.y3 13: oS 250 Nl.£q 0.50 20.1 S,210 33, 1 0, 2y 4-9%2 /Y/ 13:04 250 yl90 0.75 20.0 S. 21, 33, 2 0. 2 2 +. 99. 3 A V O 13:13 250 ql.jol 1.o0 19,9 S25 333 0.1-7 +95,7 1,38 13;n 250 Waal 1.25 19.9 S. 2S' 33.9 0,1 N +99.6 /.3f_ l3;al 250 Nl,9t 1.50 19A S.2y 3Y.0 6.12 t99.q 43S 13:as 250 -I1g3 1.75 1'9,9 S.23 3No 0.12 +100.3 /,35 13,Z9 250 %93 2.00 Ig,9 5,23 3`i.1 0.15' +100,Cl /,35- a- r 3�0 DATE/TIME ! -27- %O / { �) z �I DEPTH TO GROUNDWATER (FT) yj. 93 METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION y' 8s .X' WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: C (�54C ' COMMENTS: APPENDIX I LIST M51M $O -FA SAMPLE COLLECTION NUMBER 1(o+1`7 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: UNDERDRAIN WATER ELEVATION, MEAS.PT. DATE METHOD OF EVACUATION ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED(GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA POINT ID: VD - 1 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE PROJECT#: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, GAN (MSL): NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( )CONTINUOUS ( ) YES ( ) NO PUMPING WELL ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS YES ( ) NO WATER LEVEL AFTER PURGE (FT.) TIME PURGE RA mlhtr VOLUME TEMP. C pH Std.Units SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME /-2'7—z� / �3'NV WATER LEVEL PRIORTOSAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh mV DISS.OXY. PPM OTHER 13.y2 5.8Lf 1 2)8 PS.1 19.70 1 +70.1 y,75 NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: Just Nit. 6.� SAMPLE CHARACTERISTICS: CVAk COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF POINT ID: SW-2 LOCATION: LENOIR. NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER INITIAL EVEL (FEE;T)� NA ELEVATION, MEAS.PT.(MSL):.. �.� NA DATE METHOD OF EVACUATION: ( ) PVC BAILER ( ) WELL WIZARD ( ) ( ) S.S. BAILER ( ) GRUNDFOS PUMP P WELL RISER DIAMETER (IN.): ( ) 2 ( ) 4 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA ly f�� �1:7q 9Nx.9 �7 Y Veit l�l�xoR!F`n:ZN:IUAZ�] LAB SAMPLE PROJECT DEPTH TO BOTTOM (FEET) NA ELEVATION, GIW (MSL): NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: OUS ( ) YES ( ) NO LIMPING WELL ( ) 6 ( ) OTHER_ WAS WELL PURGED TO DRYNESS WATER LEVEL AFTER PURGE (FT.) FINISH CONTINU ( ) NO TIME PURGE RATE m/htz CU MUtA:FIVF VOLUME TEMP. C pH Units SPEC. CONDUCT. umhos/cm) TURBIDITY INTL) OTHER eh m NA 0 NA NA NA SAMPLING INFORMATION DATE / TIME '7, 7)-%A / 13 ', SiL WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh m DISS.OXY, PPM OTHER l3-.5s 6.36 1 82.' a4-3 1 1A.AO 4-43.2 S.o2 NA GENERAL INFORMATION {, o'r- WEATHER CONDITIONS AT TIME OF SAMPLING: �HNNu�d S SAMPLE CHARACTERISTICS: Ck..4i_ COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 19 SITE NAME FOOTHILLS LF POINT ID: MW - 3R2 LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIV E S & S - B.CHIODO SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION 38 79 INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSL): DL 10, 83 DATE '7.';k7- 20 LAB SAMPLE /PROJECTM NA DEPTH TO BOTTOM (FT): ri 3. 9 } ELEVATION, GM/ (MSL): i 202 •p�1 TIME: START/FINISH r-l.IS / /y: 147 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X)QEDWWPUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) S" ('2 WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) a• 00 WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START C Ll Arc FINISH C LE14Q EVACUATION STABILIZATION DATA TIME PURGE RATE ML/MIN DTW FT CUMUL. VOL GAL TEMP. C pH Std.Units CONDUCT. umhos/cm TURBIDITY NTU REDOX eh m D.O. MG/L I-0:197 250 3&117g 0 20.57 ?.&& �2 (c,3 2.30 -2(1.) 3-cg, N;)q 250 39.ss 0.25 20.3 7.7b .26'! 2.oz --2Z 9 3 vo 111:23 250 3tio o.5o 24.3 7,&o 2(o4 /.85-- -211.1 3.38 IN.27 250 40-0 0.75 20,3 9S?- 2&5 47& -24/.el 3,37 1N:3 1 1 250 39.09 1.00 Zo. 3 '7, 97 1. (, (, - 27.7 3, 3u l'w:3S 25o 39.15 1.25 20.2 7,99 2loG /,7Z -29..t 3,27 i'9:39 250 390-7 1.50 20.2 7.05 2-0 1,70 -?9-.7 3,27 tN:N3 250 39.17 1,75 2o.Z 790 2&9 /,GS -2R0 3.25 Iw:u7 250 39.19 2.00 20.2 '7,90 2&9, j.(07 -79,/ 3,25' SAMPLING INFORMATION DATE /TIME -'z7� 2,0 / 14: t'I -I DEPTH TO GROUNDWATER (FT) 3 9• /9' METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X)QEDWWPUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: S4IN11f 60 SAMPLE CHARACTERISTICS: C (w COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER a O SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: LEACHATE ELEVATION, MEAS.PT.(MSL :_ NA DATE METHOD OF EVACUATION: ( ) PVC BAILER ( i WELL WIZARD ( ) ( ) S.S. BAILER ( ) GRUNDFOS PUMP PU WELL RISER DIAMETER (IN.): ( ) 2 ( ) 4 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA POINT ID: FIELD REPRESENTATIVE: LAB SAMPLE I PROJECT LEACHATE E S & S - B.CHIODO T DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: CONTINUOU ( ) YES ( ) NO MPING WELL ( ) 6 ( ) OTHER_ WAS WELL PURGED TO DRYN ) YES ( ) NO WATER LEVEL AFTER PURGE (F'.) FINISH TIME PU m/htz ULATIVE VOLUME TEMP. pH Std.Units SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME %—Z%— 20 / S • OD WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) SAMPLE PORT ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units SPEC. CONDUCT. umhos/cm TEMP, C TURBIDITY NTU eh REDOX mV DISS . OXY. PPM OTHER 15:07 Ko2, 23700 29,a 3`,ko _yy.9 NA NA GENERAL INFORMATION �} r WEATHER CONDITIONS AT TIME OF SAMppPLIN�/tG: S{�NN r d S SAMPLE CHARACTERISTICS: C ry —Awi8 /1 COMMENTS: ` SAMPLE COLLECTION NUMBER SITE NAME FOOTHILLS LF POINT ID: MW - 2R LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIV E S & S - B.CHIODO SAMPLE MATRIX: GROUNDWATER LAB SAMPLE/PROJECTM NA EVACUATION INFORMATION INITIAL WATER LEVEL (FT): Li y' ELEV., MEAS. PT. (MSL): DATE " /- 2-r7^ 20 DEPTH TO BOTTOM (FT): (03,60 ELEVATION, GM/ (MSL): 1a0�J,�Ys TIME: START/FINISH 15.20 /OZ- METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED W W PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 12.43 WAS WELL PURGED TO DRYNESS( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) .2. �90 WATER LEVEL END PURGE (FT) Ng; 69 TURBIDITY OF PURGINGS: START cLr-4R. FINISH C Lr= A e- EVACUATION STABILIZATION DATA TIME PURGE RATE ML/MIN DTW FT CUMUL. VOL(GAL TEMP. C pH Std.Units CONDUCT. umhos/cm TURBIDITY NTU REDOX eh (mV) D.O. (MG/L fS,Ao 250 4&;4l 0 19,7 5.91 ltt),3 0,11y 4&SS 2,25 15:24 250 YB,SO 0.25 19, 5:87 139.S- 0,Ci9 4-70.1 2,23 15.2S' 250 4$.53 0.50 lell 5.7y 13$ 2 0.3(0 4-V.1 2,23 15:32 250 4kSS 075 lVi 5.7 V 137,5 0.31 +-75, 2,Zt 15:36 250 y8s$ 1.00 �20,0 5,70 (37 L 6,Z5" +772 2,20 IS,40 1 250 'ftl 1.25 2-0.0 S,69 1 13G.G 0-ZZ 1 -725 2,18 )5:44 250 qkW 1.50 20.1 5,&7 t3G.2. 0.20 +7k,3 2./s ISA9 250 gl:07 1.75 20,1 S,66 135.9 0,l i +76;6 ZE. 151.52 250 'f&G9 2.00 20.1 Slot t3J,8r G.1S +79-.7 2,IZ I S'5ts 250 NEb`i 2.25 20. 1 j,(-6 13S 9 0.141 79..$ 2-/2 11c; 00 250 g941 2.50 -20.1 5,&(, 135,7 0- 12 f73-,i 2.1Z SAMPLING INFORMATION DATE/TIME r-2?-2t0 / 11°' 00 f )ID'02 DEPTH TO GROUNDWATER (FT) elk cp ' METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X)QEDWWPUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: C l,F'AP Dwp TA icEr> (423 z I&. SAMPLE COLLECTION NUMBER , -2 4-; ,3