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1102_Buncombe_BASFEnka_Indus_Brownfields_MonitoringRequest_FID1469227_20201020
ELM Site Solutions, Inc. P. O. Box 97607 Raleigh, North Carolina 27624 (919) 792-3733 October 20, 2020 submitted via Electronic Mail Ms. Jaclynne Drummond Compliance Hydrogeologist North Carolina Department of Environmental Quality Division of Waste Management - Solid Waste Section 2090 US Highway 70 Swannanoa, North Carolina 28778 Subject: Enka Landfill Compliance Monitoring BASF Former Industrial Landfill Facility Permit # 11-02 Enka, Buncombe County, North Carolina Dear Ms. Drummond: On behalf of BASF Corporation, ELM Site Solutions (ELMSS) herein requests a modification to the Enka Landfill Compliance Monitoring Program required under the facility's post -closure permit. This request is based on our previous discussions, a change in site conditions due to re- development and data results collected previously from the site. The following sections provide background information and justification details for the request. Background Information The current compliance monitoring program consists of quarterly landfill gas monitoring and semi- annual groundwater and surface water monitoring, including sample collection from an on -site seep. Landfill detection monitoring for groundwater and surface water includes analysis for Appendix I VOCs, metals and the wet chemistry parameters of total dissolved solids and sulfates. Semi-annual monitoring reports have been provided to the North Carolina Department of Environmental Quality (NCDEQ) with the latest covering the April 2020 sampling event. A brownfield permit was issued for the site resulting in the construction of three baseball/softball fields 1 Ms. Jaclynne Drummond Monitoring Program Reduction Request Former BASF Closed Industrial Landfill (11-02) October 20, 2020 and supporting parking. To facilitate property development, a very significant amount of fill material was imported to the site (source unknown) to establish grades required for the improvements. This work was completed inside the facility's permitted waste boundary. During grading operations, groundwater monitoring wells MW-3 and MW-6 (background well) were destroyed. Accordingly, compliance monitoring reports beginning with the April 2017 sampling event have not included these wells. In addition, landfill gas monitoring well LG-1 was destroyed at an unknown time by road construction activities performed between March 2019 and June 2019 and based on a recent report provided to BASF (Work Plan for Limited Soil Assessment (Rev1), S&ME, August 20, 2020), it appears LG-7 and LG-8 may be impacted during pipeline installation. Monitoring Program Reduction Request The post -closure permit requires semi-annual groundwater monitoring from the site network consisting of MW-3, MW-4R, MW-5 and background well MW-6 and surface water sample locations (SW-1 and DW-2) in Hominy Creek. In a letter dated November 4, 2010, the NCDEQ Solid Waste Section requested the collection of an additional surface water sample from a seep area at the site in conjunction with the semi-annual groundwater sampling events for a minimum of 5 years. Landfill gas monitoring wells were installed in 2010 with initial sampling beginning in December 2010. BASF herein requests the following: • quarterly landfill gas monitoring be modified to semi-annual monitoring; • elimination of the seep sampling requirement; • semi-annual groundwater and surface water monitoring be modified to annual monitoring and VOC monitoring requirements be removed. Details for these requests are provided below. Landfill Gas Monitoring As noted above, landfill gas concentrations are currently monitored quarterly with well LG-1 being destroyed in 2019 from construction related activities and therefore, no longer monitored. Figure A depicts landfill gas monitoring well locations. Table A contains historical (2010 — 2020) monitoring data for the landfill gas wells. No landfill gas monitoring wells have exhibited a concentration greater than 0.02% LEL at the site since 2010. Given these very low-level historical detections and no future detections are planned, the concentrations are stable and do not pose a risk to the public or the environment. Based on this information, BASF requests that the monitoring frequency for landfill gases be reduced to semi-annually. Seep Monitoring As noted above, the NCDEQ Solid Waste Section requested the collection of an additional surface water sample from a seep area at the site for a minimum of 5 years in a letter dated November 4, VA Ms. Jaclynne Drummond Monitoring Program Reduction Request Former BASF Closed Industrial Landfill (11-02) October 20, 2020 2010. Since that time (i.e., over the past 10 years), only acetone and benzene have been observed above laboratory detection limits. Table B includes seep sampling data since April 2011. Acetone, which is not a site constituent of concern, was only detected in the April 2019 and October 2019 sampling events at estimated concentrations (1.2J ug/L and 2.6J ug/l, respectively). Concentrations of acetone within 10% of the detection limit or instrument blank are considered laboratory contaminants. Remaining results for acetone were below the laboratory detection limits that range from 0.7 ug/L to 10 ug/L. Benzene was initially detected at an estimated concentration (0.9J in 2011) and the only subsequent detections were in April 2013, May 2014 and April 2019 at concentrations of 1.2 ug/L, 0.81 J ug/L and 0.05J ug/L, respectively. All remaining results were below the laboratory detection limit. It should also be noted that detected and estimated results for benzene are within 10% of the detection limit. Based on this information, the concentrations are stable and do not pose a risk to the public or the environment. BASF requests that seep sampling be removed from the compliance monitoring program. Surface Water Monitoring The location of the BASF Enka Landfill monitoring wells and surface water/seep sample points are provided on Figure B. As stated previously, the compliance monitoring program includes surface water sample locations SW-1 (upstream) and DW-2 (downstream) in Hominy Creek. Table B contains VOC surface water sampling data for the previous seven years (i.e., since 2014). For SW-1, two VOCs were detected at estimated concentrations. Acetone was observed at estimated concentrations during the October 2017 (3.1 J ug/L), April 2019 (2.3J ug/L) and April 2020 (0.9J ug/L) events and 1,2 dichloroethane was observed at an estimated concentration during the April 2019 (0.05J ug/L) event. For DW-2, acetone and 1,2 dichloroethane detections mimicked those of the upgradient sample location with the exception of acetone detected at 1.3J ug/L during the October 2018 sampling event. Cis-1,2-dichloroethane was detected in DW-2 during one event (October 2019) at an estimated concentration (0.05J). A review of inorganic and wet chemistry data (Table C) since October 2014 indicates the concentrations are relatively stable with some outliers present that may be due to turbidity or site construction activities. Based on this data review, VOCs have not been detected above reporting limits and upgradient sample results closely mimic downgradient results. In addition, the distribution of inorganic and wet chemistry parameters remains relatively consistent. Based on this information, the concentrations are stable and do not pose a risk to the public or the environment. BASF requests that surface water sampling be modified to annual sampling and VOC monitoring be removed for surface water. 3 Ms. Jaclynne Drummond Monitoring Program Reduction Request Former BASF Closed Industrial Landfill (11-02) October 20, 2020 Groundwater Monitoring As noted above, the groundwater compliance monitoring program includes monitoring wells MW- 3, MW-4R, MW-5 and background well MW-6, with MW-3 and MW-6 (background well) destroyed during site grading operations from brownfield development activities. Historical VOC groundwater results from 2014 to present are provided in Table B. There were no Appendix I detections above the 15A NCAC 2L (2L) standards in groundwater since 2014. Samples collected from MW-4R and MW-5 continue to be analyzed for the inorganic and wet chemistry constituents. Historical data from 2014 to present for inorganic constituents are presented in Table C. Consistent unqualified detections of barium, cobalt, sulfate, and total dissolved solids are observed in the data. Results for other constituents vary from non -detect, estimated, and occasionally detected values above the reporting limit. Appendix I VOCs have not been detected above 2L groundwater standards and the distribution of inorganic and wet chemistry parameters remain relatively consistent. Based on this information, the concentrations are stable and do not pose a risk to the public or the environment. BASF requests that groundwater sampling be modified to annual sampling and VOC monitoring be removed for groundwater. Thank you for considering BASF's request. Implementation of the proposed sampling modifications would result in the next groundwater and surface water event occurring in April 2021 and continuing on an annual basis. We would also propose to conduct to conduct the next landfill gas monitoring event in April 2021 with continuation on a semi-annual basis. Please contact us if you have any questions or require any further information. Sincerely, ELM Site Solutions, Inc. Rusty Norris, PE, PLS, RSM Senior Engineer attachments c Vernon Burrows, BASF Corporation 4 TABLES Table A Landfill Gas Monitoring Results (2010 - 2020) BASF Enka Landfill Former BASF Manufacturing Facility Enka, NC LFG WELL ID SAMPLE DATE Sample Time Sample Tube Purge Time Pumped % CH4 By Volume 0 �0 LEL 0 /0 02 0 /o CO2 12/13/2010 1124 >60s >60s 0 0 17.0 4.8 3/11/2011 1335 >60s >60s 0 0 18.2 3.8 6/3/2011 1100 >60s >60s 0 0 17.0 3.4 10/12/2011 1130 >60s >60s 0 0 16.8 3.8 12/14/2011 1300 >60s >60s 0 0 17.0 3.7 3/8/2012 1200 >60s >60s 1 0 0 17.3 3.6 6/14/2012 1115 >60s >60s 0 0 17.0 3.8 9/26/2012 1200 >60s >60s 0 0 17.2 3.6 12/3/2012 1200 >60s >60s 0 0 18.3 3.9 3/27/2013 1200 >60s >60s 0 0 18.0 3.4 6/3/2013 1300 >60s >60s 0 0 15.3 3.0 9/17/2013 1130 >60s >60s 0 0 14.5 7.2 12/11/2013 1200 >60s >60s 0 0 15.3 1 5.7 3/13/2014 1200 >60s >60s 0 0 18.2 3.2 6/5/2014 1230 >60s >60s 0 0 15.6 4.2 9/30/2014 1130 >60s >60s 0 0 14.4 5.5 12/19/2014 1100 >60s >60s 0 0 14.8 5.1 LG-1 3/17/2015 1130 >60s >60s 0 0 16.8 4.3 6/19/2015 1215 >60s >60s 0 0 17.1 3.9 9/14/2015 1400 >60s >60s 0 0 18.2 3.1 12/1/2015 1130 >60s >60s 1 0 0 1 15.5 5.5 3/15/2016 1200 >60s >60s 0 0 15.7 2.6 6/29/2016 1200 >60s >60s 0 0 16.9 4.2 9/16/2016 1200 >60s >60s 0 0 16.0 4.8 12/30/2016 1100 >60s >60s 0 0 20.5 3.1 3/24/2017 1030 >60s >60s 0 0 15.5 2.7 6/9/2017 1130 >60s >60s 0 0 15.2 4.5 9/1/2017 1130 >60s >60s 0 0 18.0 4.1 12/22/2017 1130 >60s >60s 1 0 0 1 17.0 4.4 3/30/2018 1100 >60s >60s 0 0 16.6 4.5 6/15/2018 1030 >60s >60s 0 0 17.2 4.7 9/22/2018 1140 >60s >60s 0 0 17.1 4.4 12/26/2018 1300 >60s >60s 0 0 15.2 6.5 3/9/2019 1515 >60s >60s 0.4 0.02 1 15.8 3.8 6/29/2019 Well Demolished since Last Sampling Event at an Unknown Time 12/13/2010 1131 >60s >60s 0 0 18.9 2.2 3/11/2011 1345 >60s >60s 0 0 20.4 0.9 6/3/2011 1130 >60s >60s 0 0 19.5 2.3 10/12/2011 1145 >60s >60s 0 0 18.1 2.4 12/14/2011 1330 >60s >60s 0 0 18.6 2.2 3/8/2012 1145 >60s >60s 0 0 19.3 1.8 6/14/2012 1130 >60s >60s 0 0 18.5 2.4 9/26/2012 1215 >60s >60s 0 0 1 18.8 2.2 12/3/2012 1230 >60s >60s 0 0 19.2 2.0 3/27/2013 1230 >60s >60s 0 0 19.6 2.5 6/3/2013 1315 >60s >60s 0 0 16.8 3.3 9/17/2013 1140 >60s >60s 0 0 17.5 3.7 12/11/2013 1215 >60s >60s 0 0 17.3 3.2 3/13/2014 1230 >60s >60s 0 0 19.3 2.7 6/5/2014 1245 >60s >60s 0 1 0 17.0 3.0 9/30/2014 1145 >60s >60s 0 0 1 16.7 3.9 12/19/2014 1115 >60s >60s 0 0 16.9 3.5 3/17/2015 1140 >60s >60s 0 0 17.1 2.9 6/19/2015 1230 >60s >60s 0 0 18.1 2.8 LG-2 9/14/2015 1415 >60s >60s 0 0 19.6 0.8 12/1/2015 1145 >60s >60s 0 0 17.1 3.4 3/15/2016 1230 >60s >60s 0 0 18.6 1.3 6/29/2016 1230 >60s >60s 0 0 18.5 2.4 9/16/2016 1215 >60s >60s 0 0 1 16.9 3.2 12/30/2016 1115 >60s >60s 0 0 20.9 2.2 3/24/2017 1100 >60s >60s 0 0 18.2 1.5 6/9/2017 1200 >60s >60s 0 0 19.5 2.1 9/1/2017 1215 >60s >60s 0 0 17.8 3.0 12/22/2017 1145 >60s >60s 0 0 19.1 2.6 3/30/2018 1115 >60s >60s 1 0 0 17.0 3.0 6/15/2018 1100 >60s >60s 0 0 16.8 4.0 9/22/2018 1200 >60s >60s 0 0 1 16.6 3.4 12/26/2018 1310 >60s >60s 0 0 15.5 3.4 3/9/2019 1520 >60s >60s 0.4 0.02 17.3 2.3 6/29/2019 940 >60s >60s 0 0 16.9 2.4 9/25/2019 1200 >60s >60s 0 0 17.5 3.1 12/21/2019 1350 >60s >60s 0 0 15.9 2.2 1400 >60s >60s 0.1 0.005 16.3 1 2.3 1 of 6 Table A Landfill Gas Monitoring Results (2010 - 2020) BASF Enka Landfill Former BASF Manufacturing Facility Enka, NC LFG WELL ID SAMPLE DATE Sample Time Sample Tube Purge Time Pumped % CH4 By Volume % LEL % 02 % CO2 12/13/2010 1136 >60s >60s 0 0 18.6 3.2 3/11/2011 1400 >60s >60s 0 0 19.7 2.1 6/3/2011 1200 >60s >60s 0 0 17.4 3.4 10/12/2011 1200 >60s >60s 0 0 17.8 3.0 12/14/2011 1345 >60s >60s 0 0 18.0 2.9 3/8/2012 1230 >60s >60s 0 0 1 18.4 2.8 6/14/2012 1200 >60s >60s 0 0 18.8 2.5 9/26/2012 1230 >60s >60s 0 0 18.6 2.7 12/3/2012 1245 >60s >60s 0 0 18.9 2.9 3/27/2013 1245 >60s >60s 0 0 20.4 2.4 6/3/2013 1230 >60s >60s 0 0 16.8 3.2 9/17/2013 1150 >60s >60s 0 0 17.4 3.8 12/11/2013 1230 >60s >60s 0 0 17.5 3.7 3/13/2014 1300 >60s >60s 0 0 20.1 2.5 6/5/2014 1300 >60s >60s 0 0 17.7 3.1 9/30/2014 1200 >60s >60s 0 0 16.9 3.5 12/19/2014 1145 >60s >60s 0 0 16.5 4.0 3/17/2015 1150 >60s >60s 0 0 18.5 2.6 6/19/2015 1245 >60s >60s 0 0 17.5 3.3 LG-3 9/14/2015 1430 >60s >60s 0 0 18.2 2.5 12/1/2015 1200 >60s >60s 0 0 17.5 3.6 3/15/2016 1245 >60s >60s 0 0 16.7 2.9 6/29/2016 1245 >60s >60s 0 0 17.9 3.1 9/16/2016 1230 >60s >60s 0 0 17.1 3.8 12/30/2016 1145 >60s >60s 0 0 20.5 2.6 3/24/2017 1115 >60s >60s 0 0 17.5 2.2 6/9/2017 1230 >60s >60s 0 0 18.9 2.4 9/1/2017 1230 >60s >60s 0 0 19.0 2.3 12/22/2017 1200 >60s >60s 0 0 19.4 2.5 3/30/2018 1145 >60s >60s 0 0 18.6 2.5 6/15/2018 1115 >60s >60s 0 0 18.9 2.2 9/22/2018 1215 >60s >60s 0 0 18.6 1.7 12/26/2018 1320 >60s >60s 0 0 18.4 3.1 3/9/2019 1530 >60s >60s 0.3 0.015 19.2 1.5 6/29/2019 950 >60s >60s 0 0 17.9 2.2 9/25/2019 1210 >60s >60s 0 0 18.3 2.0 12/21/2019 1400 >60s >60s 0 0 19.6 2.2 3 8 2020 1410 >60s >60s 0.1 0.005 1 18.6 2.1 12/13/2010 1143 >60s >60s 0 0 16.6 5.5 3/11/2011 1415 >60s >60s 0 0 18.8 2.8 6/3/2011 1230 >60s >60s 0 0 17.8 3.2 10/12/2011 1230 >60s >60s 0 0 14.1 5.4 12/14/2011 1400 >60s >60s 0 0 13.9 5.3 3/8/2012 1245 >60s >60s 0 0 16.8 4.2 6/14/2012 1215 >60s >60s 0 0 16.4 4.4 9/26/2012 1245 >60s >60s 0 0 16.5 4.6 12/3/2012 1300 >60s >60s 0 0 15.5 5.9 3/27/2013 1300 >60s >60s 0 0 19.9 3.2 6/3/2013 1430 >60s >60s 0 0 16.0 4.2 9/17/2013 1200 >60s >60s 0 0 12.9 6.4 12/11/2013 1245 >60s >60s 0 0 15.4 5.7 3/13/2014 1330 >60s >60s 0 0 19.7 3.3 6/5/2014 1330 >60s >60s 0 0 14.7 4.2 9/30/2014 1230 >60s >60s 0 0 1 13.9 5.4 12/19/2014 1230 >60s >60s 0 0 14.1 5.2 3/17/2015 1200 >60s >60s 0 0 18.4 3.3 6/19/2015 1300 >60s >60s 0 0 17.8 3.2 LG-4 9/14/2015 1445 >60s >60s 0 0 16.2 4.6 12/1/2015 1230 >60s >60s 0 0 15.5 5.6 3/15/2016 1300 >60s >60s 0 0 17.1 3.0 6/29/2016 1300 >60s >60s 1 0 0 17.7 3.4 9/16/2016 1300 >60s >60s 0 0 15.8 4.9 12/30/2016 1200 >60s >60s 0 0 17.0 3.4 3/24/2017 1130 >60s >60s 0 0 16.1 4.0 6/9/2017 1300 >60s >60s 0 0 13.4 5.4 9/1/2017 1300 >60s >60s 0 0 16.7 4.5 12/22/2017 1215 >60s >60s 0 0 15.5 5.2 3/30/2018 1230 >60s >60s 0 0 18.5 1 2.5 6/15/2018 1130 >60s >60s 1 0 0 15.8 4.8 9/22/2018 1230 >60s >60s 0 0 15.3 4.8 12/26/2018 1330 >60s >60s 0 0 16.5 5.3 3/9/2019 1540 >60s >60s 0.3 0.015 18.7 2.3 6/29/2019 1000 >60s >60s 0 0 17.2 2.4 9/25/2019 1215 >60s >60s 0 0 15.7 4.9 12/21/2019 1410 >60s >60s 0 0 16.9 4.1 3 8 2020 1420 >60s >60s 0.1 0.005 17.3 1 3.4 2 of 6 Table A Landfill Gas Monitoring Results (2010 - 2020) BASF Enka Landfill Former BASF Manufacturing Facility Enka, NC LFG WELL ID SAMPLE DATE Sample Time Sample Tube Purge Time Pumped % CH4 By Volume % LEL % 02 % CO2 12/13/2010 1159 >60s >60s 0 0 14.2 6.7 3/11/2011 1430 >60s >60s 0 0 15.6 5.7 6/3/2011 1300 >60s >60s 0 0 16.1 5.5 10/12/2011 1300 >60s >60s 0 0 15.6 5.2 12/14/2011 1430 >60s >60s 0 0 15.9 5.4 3/8/2012 1330 >60s >60s 0 0 1 14.6 6.1 6/14/2012 1245 >60s >60s 0 0 14.8 5.9 9/26/2012 1300 >60s >60s 0 0 14.2 6.0 12/3/2012 1330 >60s >60s 0 0 15.1 7.0 3/27/2013 1330 >60s >60s 0 0 14.7 6.0 6/3/2013 1500 >60s >60s 0 0 15.1 5.7 9/17/2013 1230 >60s >60s 0 0 15.5 4.9 12/11/2013 1330 >60s >60s 1 0 0 17.0 5.5 3/13/2014 1400 >60s >60s 0 0 15.2 5.6 6/5/2014 1400 >60s >60s 0 0 17.6 4.8 9/30/2014 1300 >60s >60s 0 0 17.4 5.0 12/19/2014 1300 >60s >60s 0 0 17.1 5.1 3/17/2015 1230 >60s >60s 0 0 15.1 5.4 6/19/2015 1330 >60s >60s 0 0 14.6 5.8 LG-5 9/14/2015 1500 >60s >60s 0 0 18.8 1.9 12/1/2015 1300 >60s >60s 1 0 0 17.1 5.3 3/15/2016 1330 >60s >60s 0 0 15.5 4.3 6/29/2016 1330 >60s >60s 0 0 14.9 5.2 9/16/2016 1330 >60s >60s 0 0 16.9 5.5 12/30/2016 1230 >60s >60s 0 0 19.7 2.7 3/24/2017 1200 >60s >60s 0 0 15.5 4.3 6/9/2017 1400 >60s >60s 0 0 15.2 4.5 9/1/2017 1330 >60s >60s 0 0 17.2 5.2 12/22/2017 1245 >60s >60s 0 0 15.9 5.1 3/30/2018 1300 >60s >60s 0 0 14.9 5.5 6/15/2018 1200 >60s >60s 0 0 15.3 5.1 9/22/2018 1245 >60s >60s 0 0 18.8 2.5 12/26/2018 1340 >60s >60s 0 0 13.4 6.3 3/9/2019 1550 >60s >60s 0.3 0.015 17.6 2.7 6/29/2019 1010 >60s >60s 0 0 18.6 2.6 9/25/2019 1220 >60s >60s 0 0 18.2 3.1 12/21/2019 1420 >60s >60s 0 0 16.3 4.3 3 8 2020 1430 >60s >60s 0.1 0.005 1 15.4 3.9 12/13/2010 1207 >60s >60s 0 0 18.9 2.1 3/11/2011 1500 >60s >60s 0 0 19.8 1.8 6/3/2011 1320 >60s >60s 0 0 19.4 1.6 10/12/2011 1000 >60s >60s 0 0 16.3 4.4 12/14/2011 1115 >60s >60s 0 0 16.7 4.9 3/8/2012 1400 >60s >60s 0 0 18.1 3.2 6/14/2012 1330 >60s >60s 0 0 17.6 3.4 9/26/2012 1330 >60s >60s 0 0 17.5 3.5 12/3/2012 1400 >60s >60s 0 0 20.2 1.5 3/27/2013 1400 >60s >60s 0 0 17.9 3.5 6/3/2013 1530 >60s >60s 0 0 17.4 3.6 9/17/2013 1300 >60s >60s 0 0 20.5 0.9 12/11/2013 1400 >60s >60s 0 0 19.6 1.2 3/13/2014 1430 >60s >60s 0 0 18.0 3.2 6/5/2014 1430 >60s >60s 0 0 18.1 3.0 9/30/2014 1330 >60s >60s 0 0 1 19.0 1.5 12/19/2014 1330 >60s >60s 0 0 18.9 1.7 3/17/2015 1300 >60s >60s 0 0 17.8 3.3 6/19/2015 1400 >60s >60s 0 0 17.6 3.4 LG-6 9/14/2015 1530 >60s >60s 0 0 17.4 3.4 12/1/2015 1330 >60s >60s 0 0 19.5 1.3 3/15/2016 1400 >60s >60s 0 0 17.9 2.1 6/29/2016 1400 >60s >60s 1 0 0 17.5 3.1 9/16/2016 1400 >60s >60s 0 0 18.9 2.2 12/30/2016 1300 >60s >60s 0 0 19.8 2.7 3/24/2017 1230 >60s >60s 0 0 17.6 2.3 6/9/2017 1430 >60s >60s 0 0 17.4 2.5 9/1/2017 1400 >60s >60s 0 0 19.7 2.3 12/22/2017 1330 >60s >60s 0 0 20.1 1.7 3/30/2018 1330 >60s >60s 0 0 18.0 2.9 6/15/2018 1230 >60s >60s 0 0 20.8 0.7 9/22/2018 1300 >60s >60s 0 0 1 20.0 0.6 12/26/2018 1350 >60s >60s 0 0 20.5 0.5 3/9/2019 1600 >60s >60s 0.4 0.02 20.4 0.3 6/29/2019 1020 >60s >60s 0 0 19.8 0.5 9/25/2019 1230 >60s >60s 0 0 19.5 0.8 1430 >60s >60s 0 0 20.9 0.5 H12/21/2019 3 8 2020 1440 >60s >60s 0.1 0.005 20.4 0.4 3 of 6 Table A Landfill Gas Monitoring Results (2010 - 2020) BASF Enka Landfill Former BASF Manufacturing Facility Enka, NC LFG WELL ID SAMPLE DATE Sample Time Sample Tube Purge Time Pumped % CH4 By Volume % LEL % 02 % CO2 12/13/2010 1215 >60s >60s 0 0 19.4 1.1 3/11/2011 1515 >60s >60s 0 0 17.9 1.1 6/3/2011 1345 >60s >60s 0 0 17.8 1.3 10/12/2011 1015 >60s >60s 0 0 17.9 2.2 12/14/2011 1100 >60s >60s 0 0 18.3 1.5 3/8/2012 1000 >60s >60s 0 0 18.7 2.2 6/14/2012 1030 >60s >60s 0 0 18.1 3.0 9/26/2012 1030 >60s >60s 0 0 18.0 2.9 12/3/2012 1030 >60s >60s 0 0 19.9 1.3 3/27/2013 1030 >60s >60s 0 0 21.9 0.3 6/3/2013 1115 >60s >60s 0 0 19.0 0.4 9/17/2013 1000 >60s >60s 0 0 18.9 2.3 12/11/2013 1100 >60s >60s 0 0 20.2 0.2 3/13/2014 1000 >60s >60s 0 0 19.1 2.4 6/5/2014 1100 >60s >60s 0 0 18.9 1.9 9/30/2014 1000 >60s >60s 0 0 18.1 1.9 12/19/2014 1000 >60s >60s 0 0 18.4 1.6 3/17/2015 1030 >60s >60s 0 0 19.9 1.0 6/19/2015 1100 >60s >60s 0 0 18.8 1.8 LG-7 9/14/2015 1300 >60s >60s 0 0 1 19.0 2.2 12/1/2015 1000 >60s >60s 0 0 19.2 1.5 3/15/2016 1430 >60s >60s 0 0 19.0 1.2 6/29/2016 1415 >60s >60s 0 0 18.6 2.0 9/16/2016 1030 >60s >60s 0 0 18.4 5.3 12/30/2016 1330 >60s >60s 0 0 20.7 1.0 3/24/2017 1300 >60s >60s 0 0 17.4 2.6 6/9/2017 1330 >60s >60s 0 0 17.1 2.9 9/1/2017 1430 >60s >60s 0 0 18.6 2.7 12/22/2017 1400 >60s >60s 0 0 19.7 0.7 3/30/2018 1000 >60s >60s 0 0 19.5 1.1 6/15/2018 1300 >60s >60s 0 0 16.5 3.5 9/22/2018 1330 >60s >60s 0 0 15.5 3.7 12/26/2018 1400 >60s >60s 0 0 26.0 0.9 3/9/2019 1610 >60s >60s 0.4 0.02 20.1 0.2 6/29/2019 1030 >60s >60s 1 0 0 1 19.4 1.1 9/25/2019 1240 >60s >60s 0 0 17.1 3.4 12/21/2019 1440 >60s >60s 0 0 21.2 0.6 3 8 2020 1450 >60s >60s 0.1 0.005 20.2 0.6 12/13/2010 1222 >60s >60s 0 0 18.0 2.9 3/11/2011 1530 >60s >60s 0 0 13.9 3.6 6/3/2011 1430 >60s >60s 0 0 16.2 3.5 10/12/2011 1030 >60s >60s 0 0 16.2 3.1 12/14/2011 1145 >60s >60s 1 0 0 1 15.9 3.0 3/8/2012 1030 >60s >60s 0 0 19.1 1.9 6/14/2012 1040 >60s >60s 0 0 18.3 2.6 9/26/2012 1100 >60s >60s 0 0 18.2 2.4 12/3/2012 1050 >60s >60s 0 0 19.2 2.4 3/27/2013 1045 >60s >60s 0 0 18.7 2.4 6/3/2013 1145 >60s >60s 0 0 16.4 4.2 9/17/2013 1015 >60s >60s 0 0 18.3 4.1 12/11/2013 1115 >60s >60s 0 0 17.7 3.2 3/13/2014 1030 >60s >60s 0 0 19.1 2.3 6/5/2014 1115 >60s >60s 0 0 18.5 2.9 9/30/2014 1015 >60s >60s 0 0 16.2 4.4 12/19/2014 1010 >60s >60s 0 0 16.5 4.1 3/17/2015 1045 >60s >60s 0 0 17.4 1 2.7 6/19/2015 1115 >60s >60s 0 0 18.3 2.5 LG-8 9/14/2015 1310 >60s >60s 0 0 18.4 2.3 12/1/2015 1015 >60s >60s 0 0 17.6 3.3 3/15/2016 1000 >60s >60s 0 0 17.2 1.9 6/29/2016 1000 >60s >60s 0 0 18.2 2.1 9/16/2016 1100 >60s >60s 0 0 18.4 4.6 12/30/2016 1000 >60s >60s 0 0 19.6 2.2 3/24/2017 930 >60s >60s 0 0 17.3 1.9 6/9/2017 1045 >60s >60s 0 0 14.2 8.0 9/1/2017 1030 >60s >60s 0 0 13.1 5.2 12/22/2017 1030 >60s >60s 0 0 13.0 5.0 3/30/2018 1010 >60s >60s 0 0 17.5 2.6 6/15/2018 945 >60s >60s 0 0 14.9 5.8 9/22/2018 1100 >60s >60s 0 0 7.9 9.1 12/26/2018 1230 >60s >60s 0 0 1 12.0 7.3 3/9/2019 1445 >60s >60s 0.3 0.015 17.6 6.1 6/29/2019 900 >60s >60s 0 0 13.6 5.3 9/25/2019 1130 >60s >60s 0 0 14.3 6.8 12/21/2019 1450 >60s >60s 0 0 10.0 5.3 3 8 2020 1330 >60s >60s 0 0 12.5 4.1 4 of 6 Table A Landfill Gas Monitoring Results (2010 - 2020) BASF Enka Landfill Former BASF Manufacturing Facility Enka, NC LFG WELL ID SAMPLE DATE Sample Time Sample Tube Purge Time Pumped % CH4 By Volume % LEL % 02 % CO2 12/13/2010 1227 >60s >60s 0 0 18.1 3.1 3/11/2011 1545 >60s >60s 0 0 17.9 1.8 6/3/2011 1500 >60s >60s 0 0 17.5 2.1 10/12/2011 1040 >60s >60s 0 0 17.2 3.4 12/14/2011 1215 >60s >60s 0 0 17.5 3.5 3/8/2012 1100 >60s >60s 0 0 20.7 0.4 6/14/2012 1050 >60s >60s 0 0 19.9 1.2 9/26/2012 1115 >60s >60s 0 0 19.7 1.2 12/3/2012 1100 >60s >60s 0 0 19.5 2.9 3/27/2013 1100 >60s >60s 0 0 22.2 0.2 6/3/2013 1200 >60s >60s 0 0 14.0 2.5 9/17/2013 1030 >60s >60s 0 0 15.3 4.4 12/11/2013 1130 >60s >60s 0 0 17.4 3.3 3/13/2014 1100 >60s >60s 0 0 21.6 1.5 6/5/2014 1130 >60s >60s 0 0 15.8 2.7 9/30/2014 1045 >60s >60s 0 0 15.3 4.2 12/19/2014 1020 >60s >60s 0 0 15.5 4.0 3/17/2015 1100 >60s >60s 0 0 16.4 3.1 6/19/2015 1130 >60s >60s 0 0 15.2 4.3 LG-9 9/14/2015 1320 >60s >60s 0 0 1 18.0 3.7 12/1/2015 1035 >60s >60s 0 0 17.2 3.1 3/15/2016 1030 >60s >60s 0 0 19.1 0.8 6/29/2016 1025 >60s >60s 0 0 15.3 4.2 9/16/2016 1115 >60s >60s 0 0 17.6 4.9 12/30/2016 1015 >60s >60s 0 0 20.9 2.3 3/24/2017 945 >60s >60s 0 0 18.1 1.8 6/9/2017 1100 >60s >60s 0 0 13.2 4.5 9/1/2017 1045 >60s >60s 0 0 18.4 4.1 12/22/2017 1100 >60s >60s 0 0 15.3 3.9 3/30/2018 1020 >60s >60s 0 0 15.2 3.7 6/15/2018 950 >60s >60s 0 0 15.6 5.2 9/22/2018 1115 >60s >60s 0 0 16.0 5.0 12/26/2018 1240 >60s >60s 0 0 19.5 1.7 3/9/2019 1455 >60s >60s 0.3 0.015 20.3 0.3 6/29/2019 910 >60s >60s 1 0 0 15.7 3.3 9/25/2019 1140 >60s >60s 0 0 1 17.8 4.4 12/21/2019 1330 >60s >60s 0 0 15.3 4.3 3 8 2020 1340 >60s >60s 0.1 0.005 20.7 0.8 12/13/2010 1235 >60s >60s 0 0 15.5 5.8 3/11/2011 1600 >60s >60s 0 0 16.8 4.7 6/3/2011 1515 >60s >60s 0 0 17.1 3.8 10/12/2011 1100 >60s >60s 0 0 14.9 5.6 12/14/2011 1230 >60s >60s 0 0 14.2 5.7 3/8/2012 1115 >60s >60s 0 0 1 14.9 5.0 6/14/2012 1100 >60s >60s 0 0 14.7 4.9 9/26/2012 1130 >60s >60s 0 0 14.6 4.8 12/3/2012 1130 >60s >60s 0 0 16.0 5.8 3/27/2013 1130 >60s >60s 0 0 16.8 4.4 6/3/2013 1345 >60s >60s 0 0 14.9 4.5 9/17/2013 1100 >60s >60s 0 0 10.9 8.5 12/11/2013 1145 >60s >60s 0 0 13.2 6.9 3/13/2014 1130 >60s >60s 0 0 16.6 5.9 6/5/2014 1200 >60s >60s 0 0 15.0 5.1 9/30/2014 1100 >60s >60s 0 0 12.4 7.6 12/19/2014 1030 >60s >60s 0 0 12.9 7.0 3/17/2015 1110 >60s >60s 0 0 14.6 5.4 6/19/2015 1200 >60s >60s 0 0 16.8 5.7 LG-10 9/14/2015 1330 >60s >60s 0 0 17.8 3.0 12/1/2015 1100 >60s >60s 0 0 14.2 5.9 3/15/2016 1100 >60s >60s 0 0 13.8 4.1 6/29/2016 1105 >60s >60s 0 0 16.9 5.5 9/16/2016 1130 >60s >60s 0 0 15.2 5.3 12/30/2016 1030 >60s >60s 0 0 18.7 4.3 3/24/2017 1000 >60s >60s 0 0 14.4 3.7 6/9/2017 1115 >60s >60s 0 0 15.1 5.6 9/1/2017 1100 >60s >60s 0 0 17.6 3.8 12/22/2017 1115 >60s >60s 0 0 15.8 3.7 3/30/2018 1030 >60s >60s 0 0 15.2 3.7 6/15/2018 1000 >60s >60s 0 0 12.5 6.5 9/22/2018 1130 >60s >60s 0 0 13.0 6.3 12/26/2018 1250 >60s >60s 0 0 13.6 4.7 3/9/2019 1505 >60s >60s 0.4 0.02 16.2 2.3 6/29/2019 920 >60s >60s 0 0 17.1 2.3 9/25/2019 1150 >60s >60s 0 0 18.0 2.5 12/21/2019 1340 >60s >60s 0 0 16.9 3.8 3 8 2020 1350 >60s >60s 0.1 0.005 15.6 33 5 of 6 Table A Landfill Gas Monitoring Results (2010 - 2020) BASF Enka Landfill Former BASF Manufacturing Facility Enka, NC LFG SAMPLE 1 Sample Sample Tube Time % CH4 WELL ID DATE Time Purge Pumped By Volume %LEL % 02 % CO2 Notes: Landfill gas data were collected using a calibrated Landtec GEM 2000+. Landfill gas data collectedduring and after December 2019 were collected using a calibrated Landtec GEM 5000. CH4 = Methane; 02 = Oxygen; CO2 = Carbon Dioxide; LEL = Lower Explosive Limit; 5% CH4 = 100 % LEL 6 of 6 Table B VOCs in Site Monitoring Points BASF Enka Closed Industrial Landfill Enka, North Carolina Monitoring Well Volatile Organic Compounds and Surface Water I.D. Sample Date Acetone 2-Butanone Benzene 1,2 Dichloroethane Carbon Disulfide Chlorobenzene 1,4- Dichlorobenzene cis-1,2 Dichloroethene 1,4-Dioxane Toluene Vinyl Chloride Units u /L u /L ug/L ug/L ug/L ug/L u /L ug/L ug/L ug/L ug/L MW-3 5/1/2014 <PQL <PQL <0.15 <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32 MW-3 11/11/2014 <PQL <PQL <0.15 <PQL <1.5 0.99 J 0.58 J <0.15 <PQL <PQL <0.32 MW-3 F 11/11/2014 <PQL <PQL <0.15 <PQL <1.5 0.53 J <0.19 <0.15 <PQL <PQL <0.32 MW-3 4/16/2015 <1.2 <1.3 <0.15 <0.21 <1.5 1.2 <0.19 <0.15 1 <PQL <0.14 <0.32 MW-3 10/13/2015 <1.2 <1.3 <0.15 <0.21 <1.5 1.4 <0.19 <0.15 1 <PQL <0.14 <0.32 MW-3 4/14/2016 <1.2 <1.3 <0.15 <0.21 <1.5 0.63 J 0.42 J <0.15 <PQL <0.14 <0.32 MW-3 10/13/2016 <10 <PQL <0.15 <0.21 <1.5 1.2 <0.19 <0.15 <PQL <0.14 <0.32 MW-3 4/26/2017 NM NM NM NM NM NM NM NM <PQL NM NM MW-3 10/31/2017 NM NM NM NM NM NM NM NM <PQL NM NM MW-3 4/10/2018 NM NM NM NM NM NM NM NM <PQL NM NM MW-3 10/1/2018 NM NM NM NM NM NM NM NM <PQL NM NM MW-3 4/5/2019 NM NM NM NM NM NM NM NM <PQL NM NM MW-3 10/13/2019 NM NM NM NM NM NM NM NM <PQL NM NM MW-3 4/5/2020 NM NM NM NM NM NM NM NM <PQL NM NM MW-3 (Duplicate) 5/1/2014 <PQL <PQL <PQL <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32 MW-3 (Duplicate) 11/11/2014 <PQL <PQL <PQL <PQL <1.5 1.11 0.64 J <0.15 <PQL <PQL <0.32 MW-3 (Duplicate) 4/16/2015 <1.2 <1.3 <0.15 <0.21 <1.5 1.3 <0.19 <0.15 <PQL <0.14 <0.32 MW-3 (Duplicate) 10/13/2015 <1.2 <1.3 <0.15 <0.21 <1.5 <0.17 1.3 <0.15 <PQL <0.14 <0.32 MW-3 (Duplicate) 4/14/2016 <1.2 <1.3 <0.15 <0.21 <1.5 0.78 J 0.48 J <0.15 <PQL <0.14 <0.32 MW-3 (Duplicate) 10/13/2016 <10 <1.3 <0.15 <0.21 <1.5 1.2 <0.19 <0.15 <PQL <0.14 <0.32 MW-4R 5/1/2014 <PQL <PQL <0.15 <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32 MW-4R 11/11/2014 <PQL <PQL <0.15 <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32 MW-4R F 11/11/2014 <PQL <PQL <0.15 <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32 MW-4R 4/16/2015 <1.2 <1.3 <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 MW-4R 10/13/2015 <1.2 <1.3 <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 MW-4R 4/14/2016 <1.2 <1.3 <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 MW-4R 10/13/2016 <1.2 <1.3 <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 MW-4R 4/26/2017 <10 3.2 J <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 MW-4R 10/31/2017 <2.0 <PQL <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <PQL <0.40 <0.40 MW-4R 4/10/2018 <2.0 <PQL <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <PQL <0.4 <0.4 MW-4R 10/1/2018 <0.9 <PQL <0.05 <0.05 <0.07 <0.06 <0.07 <0.05 <PQL <0.07 <0.1 MW-4R 4/5/2019 2.2 J <PQL <0.05 <0.05 <0.06 <0.06 <0.07 <0.05 <0.2 U <0.07 <0.1 MW-4R 10/13/2019 <0.9 <PQL <0.05 <0.05 <0.06 <0.06 <0.07 <0.05 <PQL <0.07 <0.1 MW-4R 4/5/2020 <0.7 <0.3 <0.2 <0.3 <0.2 <0.2 <0.2 <0.2 <PQL <0.2 <0.2 MW-4R DUP 10/1/2018 <0.9 <PQL <0.05 <0.05 <0.07 <0.06 <0.07 <0.05 <PQL <0.07 <0.1 MW-4R DUP 4/5/2019 2.5 J <PQL <0.05 0.05 J <0.07 <0.06 <0.07 <0.05 <PQL <0.07 <0.1 MW-4R DUP 10/13/2019 <0.9 <PQL <0.05 <0.05 <0.06 <0.06 <0.07 1 <0.05 <PQL <0.07 <0.1 MW-5 5/1/2014 <PQL <PQL <0.15 <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32 MW-5 11/11/2014 <PQL <PQL <0.15 <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32 MW-5 F 11/11/2014 <PQL <PQL <0.15 <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32 MW-5 4/16/2015 <1.2 <1.3 <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 MW-5 10/13/2015 <1.2 <1.3 <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 MW-5 4/14/2016 <1.2 <1.3 <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 MW-5 10/13/2016 <10 <PQL <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 MW-5 4/26/2017 <10 <1.3 <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 MW-5 10/31/2017 <2.0 <PQL <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <PQL <0.40 <0.40 MW-5 4/10/2018 <2.0 <PQL <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <PQL <0.4 <0.4 MW-5 10/1/2018 <0.9 <PQL <0.05 1 <0.05 1.3 <0.06 <0.07 <0.05 <PQL <0.07 <0.1 MW-5 4/5/2019 2.0 J <PQL <0.05 <0.05 <0.06 <0.06 <0.07 <0.05 8.6 <0.07 <0.1 MW-5 10/13/2019 <0.9 <PQL <0.05 <0.05 <0.06 <0.06 <0.07 <0.05 <PQL <0.07 <0.1 MW-5 4/5/2020 <0.7 <0.3 <0.2 <0.3 <0.2 <0.2 <0.2 <0.2 <PQL <0.2 <0.2 MW-6 5/1/2014 <PQL <PQL <0.15 <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32 MW-6 11/11/2014 <PQL <PQL <0.15 <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32 MW-6 F 11/11/2014 <PQL <PQL <0.15 <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32 MW-6 4/16/2015 <1.2 <PQL <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 MW-6 10/13/2015 <1.2 <1.3 <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 MW-6 4/14/2016 <1.2 <1.3 <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 MW-6 10/13/2016 <10 <PQL <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 MW-6 4/26/2017 NM NM NM NM NM NM NM NM <PQL NM NM MW-6 10/31/2017 NM NM NM NM NM NM NM NM <PQL NM NM MW-6 4/10/2018 NM NM NM NM NM NM NM NM <PQL NM NM MW-6 10/1/2018 NM NM NM NM NM NM NM NM <PQL NM NM MW-6 4/5/2019 NM NM NM NM NM NM NM NM <PQL NM NM MW-6 10/13/2019 NM NM NM NM NM NM NM NM <PQL NM NM MW-6 4/5/2020 NM NM NM NM NM NM NM NM <PQL NM NM Table B VOCs in Site Monitoring Points BASF Enka Closed Industrial Landfill Enka, North Carolina Monitoring Well Volatile Organic Compounds and Surface Water J.D. Sample Date Acetone 2-Butanone Benzene 1,2 Dichloroethane Carbon Disulfide Chlorobenzene 1,4- Dichlorobenzene cis-1,2 Dichloroethene 1,4-Dioxane Toluene Vinyl Chloride SW-1 5/1/2014 <PQL <PQL <0.15 <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32 SW-1 11/11/2014 <PQL <PQL <0.15 <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32 SW-1 4/16/2015 <1.2 <1.3 <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 SW-1 10/13/2015 <1.2 <1.3 <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 SW-1 4/14/2016 <1.2 <1.3 <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 SW-1 10/13/2016 <10 <PQL <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 SW-1 4/26/2017 <10 <1.3 <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 SW-1 10/31/2017 3.1 J <PQL <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <PQL <0.40 <0.40 SW-1 4/10/2018 <2.0 <PQL <0.40 <0.4 <0.4 <0.4 <0.4 <0.4 <PQL <0.4 <0.4 SW-1 10/1/2018 <0.9 <PQL <0.05 <0.05 <0.07 <0.06 <0.07 <0.05 <PQL <0.07 <0.1 SW-1 4/5/2019 2.3 J <PQL <0.05 0.05 J <0.06 <0.06 <0.07 <0.05 <PQL <0.07 <0.1 SW-1 10/13/2019 <0.9 <PQL <0.05 <0.05 <0.06 <0.06 <0.07 <0.05 <PQL <0.07 <0.1 SW-1 4/5/2020 0.9 J <0.3 <0.2 <0.3 <0.2 <0.2 <0.2 <0.2 <PQL <0.2 <0.2 DW-2 5/1/2014 <PQL <PQL <0.15 <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32 DW-2 11/11/2014 <PQL <PQL <0.15 <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32 DW-2 4/16/2015 <1.2 <1.3 <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 DW-2 10/13/2015 <1.2 <1.3 <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 DW-2 4/14/2016 <1.2 <1.3 <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 DW-2 10/13/2016 <10 <PQL <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 DW-2 4/26/2017 <10 <1.3 <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 DW-2 10/31/2017 3.4 J <PQL <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <PQL <0.40 <0.40 DW-2 4/10/2018 <2.0 <PQL <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 j <PQL <0.4 <0.4 DW-2 10/1/2018 1.3 J <PQL <0.05 <0.05 <0.07 <0.06 <0.07 <0.05 <PQL <0.07 <0.1 DW-2 4/5/2019 3.1 J <PQL <0.05 0.05 J <0.06 <0.06 <0.07 <0.05 <PQL <0.07 <0.1 DW-2 10/13/2019 <0.9 <PQL <0.05 <0.05 <0.06 <0.06 <0.07 0.05 J <PQL <0.07 <0.1 DW-2 4/5/2020 0.8 J <0.3 <0.2 <0.3 <0.2 <0.2 <0.2 <0.2 <PQL <0.2 <0.2 Seep-1 4/7/2011 <PQL <PQL 0.9 J <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32 Seep-1 10/10/2011 <PQL <PQL <0.15 <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32 Seep-1 4/9/2012 <PQL <PQL <0.15 <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32 Seep-1 10/11/2012 <PQL <PQL <0.15 <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32 Seep-1 4/22/2013 <PQL <PQL 1.2 <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32 Seep-1 8/1/2013 <PQL <PQL <0.15 <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32 Seep-1 10/23/2013 <PQL <PQL <0.15 <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32 Seep-1 5/1/2014 <PQL <PQL 0.81 J <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32 Seep-1 11/11/2014 <PQL <PQL <0.15 <PQL <1.5 <0.17 <0.19 <0.15 <PQL <PQL <0.32- Seep-1 4/16/2015 <1.2 <1.3 <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 Seep-1 10/13/2015 <1.2 <1.3 <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 Seep-1 4/14/2016 <1.2 <1.3 <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 Seep-1 10/13/2016 <10 <PQL <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 Seep-1 4/26/2017 <10 <1.3 <0.15 <0.21 <1.5 <0.17 <0.19 <0.15 <PQL <0.14 <0.32 Seep-1 10/31/2017 <2.0 <PQL <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <PQL <0.40 <0.40 Seep-1 4/10/2018 <2.0 <PQL <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <PQL <0.4 <0.4 Seep-1 10/1/2018 <0.9 <PQL <0.05 <0.05 <0.07 <0.06 <0.07 <0.05 <PQL <0.07 <0.1 Seep-1 4/5/2019 1.2 J <PQL 0.05 J <0.05 <0.06 <0.06 <0.07 <0.05 <PQL <0.07 <0.1 Seep-1 10/13/2019 2.6 J <PQL <0.05 <0.05 <0.06 <0.06 <0.07 <0.05 <PQL <0.07 <0.1 Seep-1 4/5/2020 <0.7 <0.3 <0.2 <0.2 1 <0.2 <0.2 <0.2 <0.2 <PQL <0.2 <0.2 Notes: For non -detect measurements (<), the detection limit (Practical Quantitation Limit or PQL) is listed. ug/L - micrograms per liter or parts per billion (ppb) mg/L - milligrams per liter or parts per million (ppm) 1.3 Compounds detected above PQL J - Indicates the analytical result is an estimated concentration between the method detection limit and the laboratory method reporting limit. D - The sample was analyzed at dilution. B - The analyte was detected in the associated method blank. NM - Not measured NA - Not Analyzed Table C Inorganics and Wet Chemistry in Site Monitoring Points BASF Enka Closed Industrial Landfill Enka, North Carolina Notes, For non -detect measurements (<), the detection limit (Practical Quantitatlon Limit or PQL) Is llsted. ug/L - micrograms per liter or parts per billion (ppb) mg/L - milligrams per liter or parts per million (Ppm) 1.3 Compounds detected above PQL Me analytical J - Indicates result is an estimated concentration between the method detection limit and the laboratory method reporting limit. D - The sample was analyzed at dilution. B - The analyte was detected in the associated method blank. NM - Not measured NA - Not Analyzed FIGURES I-41D #'SITE \NY_19/23 ��� (04 � car PARCEL E � 2 C6 ,:V \ S I TIE LOCATION - N_T_S_ � C) -) a Z3(fl., U5 ` z ;a -�= a Ho -- --� Cl) Cn Nr q _ S0A, ! / -I ~ �/ NOTES W CL (Y i1L 4• CONCRETE PIPE �"soon~ e 2050--�� PERMITTED LANDFILL VOLUME = 406460 CUBIC YARDS AREA WITHIN ORIGINAL SOLID WASTE PERMIT BOUNDARY = 28.13 ACRES � S(���/%` ' SEDIMENTATION BASIN ri� UG-�4 — i C AREA WITHIN NEW SOLID WASTE PERMIT BOUNDARY = 41.75 ACRES �� / 0 'z PARCEL 2p50 16' CONCRETE PIPE D _`\ I \ —�� \ ORIGINAL TOPOGRAPHIC SURVEY DATA, AND SITE INFORMATION PROVIDED FROM A SURVEY MAP TITLED TOPOGRAPHIC SURVEY - APRIL 2003 BASF CORPORATION INDUSTRIAL LANDFILL-, E:NKA, N.C., DRAWING__ NO. 97053-4_103; PREPARED BY C.O. HAMPTON COMPANY `� \ �L N j om° ee NEW PERMITTED FACILITY BOUNDARY (SEE NOTES) - LAND SURVEYORS, P.O. DRAWER 1319, FLETCHER, N.C. /�/� ��� / / � 2070 //�� � \ // \ LG-3 �� W-4 \ '��� \ ^" J / LG-5 AS -BUILT SURVEY DATA AND SITE INFORMATION PROVIDED FROM A SURVEY MAP TITLED SURVEY OF SOLIID WASTE LANDFILL, PERMIT NO. 11-02, COLBOND ACQUISITION I INC.; DRAWING NO. 05167FINAL-V2000; PREPARED BY BETH B. GILLAM, P.L.S., OF HUTCHISON-IBIGGS & ASSOCIATES, INC., P.O. BOX ---- This drawing is the property of ELM site Solutions, Inc and isnot l:obe reproduced or copied in whole; or in p p It is only to used for the ect / 12•-20• RE HARDW0063\ /�— AN ,�' iA �� ` C LIMIT OF WASTE ) �_778, ASHEVILI_E, N.C. part. project in and site specifically identified herein ly er project. d i �t Is toeused on any be r,:rturned upon 2080 // L-�=e7 ■ —� -��.� -.-�� ��� q ' /. \ SITE TOPOGRAAHIC MAP IS REFLECTIVE OF PRE -SITE RE-DEVELOPIMENT request. -- � .\: \/���� �_ �\ \, \� \ ACTIVITIES AND REQUIRES UPDATING TO REFLECT IMPACTOF ON -GOING SITE 1NORK(2019) 00 \ 7 116-L-u- Mm �cs _ ��i'/ �^_ �3Z �--_-- WOODS �+�-� /----�-— BOUNDARY LINES OF � >OL_ID WASTE PERMIT NO. 1'I-02 NEW PERMITTED FACILITY BOUNDARY REQUIRED PER NCDENR LETTER DATED DATE: 0-C)Q-10 n-=1 f iN Il_N/�ti816DII�ENT ���\ APRIL 1, 2004. SCALE: 1 - 0(�1 /� ^ / ✓�l/r ���-- �� _'�� �` �Q►NQ �\ I I, r A�/\\ -� / o / / / / (t��%,/// o'o'I I ;,/ �� ( �� / \ \\ ` �� \ \ \ / .o yy\ \ \ \ MW-2 ABANDONED ON /4PRIL 23, 2009 IN ACCORDANCE WITH 1EiA V\1CAC 2C.0113. _ MW-6 INSTALLED ON APRIL 23, 2009. PROJECT: 1 OCI7-10-OC18 ---- LG-� / / / �6• M � �/ O /% tit I � /ti // / �//' °y �i N � � �� \\ ' A \ IOwnj STE / IIII \ e \ TBM - TEMPOF;AF;Y BENCH MARKS LANDFILL GAS MONITORING WELL LOCATIONS ARE APPROXIMATE. FINAL r// ,/ / / /// �/ / I / / I ` // ,• /� �\ �-- — —•—�/ // / — \) \\ A A \ Q \ \ LOCATIONS WILL BE INFLUENCED BY ACCESS AND OTHER POTENTIAL IMPEDIMENTS. AN AS -BUILT SURVEY WILL BE COMPLETED ONCE FINAL Z O • \ I I \ c� i' \ �� \ / / (��- \ ( � LG-6 ' I I I I I ) I \\�, ���` r \� \ INSTALLATIONSARE COMPLETE. — �( 10i II // //.�"—�����--Y ) I I i N I �o \ \ LG-1 WAS DEMOLISHED IN 2019 AT AN UNKNOWN TIME AND IS NO LONGER SAMPLED. MW-3 AND MW-6 WERE DESTROYED IN 2017 AT AN UNKNOWN TIME AND ARE NO U o IfLLI \ ) ./ � � r� \_-------_—� \. \ \ •/ / — / //J \, / \ Q 4 �n LONGER SAMPLED. orl \\ \_\\ \\ // // � $ \\'o /�r/ /ram\ \\ q RE W 10 00 \ I I I✓I I IpOIIIIN N-/%% // //� 6 \ \ �1\ \ \ / / / Z < \ �/ ti / N ry N Or / / 00 IL Z FFFfl / Zz 000 �\ \\ \\,\� \�2� -=�, �— ----- _.� / I //'/ ems/ \�� �. �_ / Z� atrt-__\ �/ '/�� MW-•2LJL ABANDONED �— LG-7In 0 __ yam. �Q _ _ �� % Q /'tip ♦ J ---�- ,n �-- _ _-=— =— - SEDIMENI� AB / V) 0. IU ►. Q Q /, � U) } W+ LG�-1 CI _ 1 ��� . .�3.9&s � 916093.699 IL z Cl I Q o UI U LG-8 Z U) �. mi aC U �— LG-9 _LEGEND_ J J L— mO n L_J___ -- --70 -- EXISTING MAJOR CONTOUR O M ^' D, U 0 -- 68 -- EXISTING MINOR CONTOUR w v! i = O z- Y EXISTING MONITORING WELL J Q� w U U,) Z. O EXISTING TREELINE ---- ---x x x --- EXISTING FENCE -- P — EXISTING POWERLINE LGI-1 Q NEiWLANDFILL GAS MONITORING WELLS GRAPHIC' SCALE 100 0 50 100 200 400 ( IId FEET ) -- -- -- — — — — — — — — — — -- -- -- -- 1 uicln = 100 ft- -- -- -- -- Figure - A ---- �"E Soto T vDy $Oy ELM Site Solutions, Inc. P.O. BOX 97607 Raleigh, North Carolina 27624 Phone: (919) 792-3733 Figure B - Monitoring Wells and Surface Water Sample Locations BASF Enka Monitoring Program BASF Closed Industrial Landfill Enka, North Carolina F z Surface Water Sample Location Groundwater Monitoring Well Location 0 350 Scale: 1" _ -350' Date: June 4, 2019 Source: Buncombe County GIS 2015 Aerial