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HomeMy WebLinkAbout3404_Forsyth_Kernersville_MSWLF_July2020GW_20200903_%0 WithersRavenel rOur People. Your Success. September 2, 2020 Ms. Jaclynne Drummond Compliance Hydrogeologist NC Department of Environment and Natural Resources Division of Waste Management -Solid Waste Section 2090 US Highway 70 Swannanoa, NC 28778 RE: July 2020 Water Quality Monitoring Report Town of Kernersville Landfill, Permit No. 34-04 Forsyth County, North Carolina WR Project No. 06140180.33 Dear Ms. Drummond: On behalf of the Town of Kernersville, WithersRavenel appreciates the opportunity to submit the attached July 2020 Water Quality Monitoring Report for the Town of Kernersville Closed Landfill, Permit No. 34-04. The attached report contains electronic versions of the complete report, appendices for the July 2020 sampling event, and historic data from the semi-annual sampling event performed in January 2020. Also attached are the North Carolina Environmental Monitoring Reporting Forms for the July 2020 monitoring event. Please contact me at lelliott@withersravenel.com with comments, questions or requests. Sincerely WithersRavenel Laura R. Elliott, PG Project Geologist Attachment C: Brad Beeson -Town of Kernersville, Solid Waste Superintendent 424 Gallimore Dairy Road, Suite C I Greensboro, NC 27409 t: 336.605.3009 1 f: 919.467.6008 1 www.withersravenel.com I License No. C-0832 Asheville I Cary I Greensboro I Pittsboro I Raleigh I Wilmington -40 NpOur People. Your Success. JULY 2020 WATER QUALITY MONITORING REPORT Town of Kernersville Closed Landfill 9900 Freeman Road Kernersville, Forsyth County, North Carolina NCDEQ Permit ID #: 34-04 Prepared for: Town of Kernersville Public Works Department PO Box 728 Kernersville, North Carolina 27285 Prepared By. WithersRavenel, Inc. 424 Gallimore Dairy Road, Suite C Greensboro, North Carolina 27409 WR Project #: 06140180.33 September 2, 2020 Laura R. Elliott, PG Project Geologist Mark Brown, LG, PG, RSM Senior Geologist 4- Our People. Your Success. TABLE OF CONTENTS 1.0 INTRODUCTION................................................................................................................... 1 1.1 Site Information.................................................................................................................. 1 1.2 Site Geology and Hydrogeology..................................................................................... 1 1.3 Regulatory Status............................................................................................................... 1 2.0 FACILITY MONITORING PROGRAM............................................................................... 2 2.1 Groundwater Monitoring Program................................................................................. 2 2.2 Surface Water Monitoring Program............................................................................... 2 3.0 GROUNDWATER AND SURFACE WATER SAMPLING EVENT ................................ 3 3.1 Field Services...................................................................................................................... 3 3.2 Quality Control................................................................................................................... 4 4.0 ANALYTICAL RESULTS........................................................................................................ 4 4.1 Groundwater.......................................................................................................................4 4.2 Surface Water..................................................................................................................... 5 5.0 MONITORED NATURAL ATTENUATION (MNA) EVALUATION .............................. 5 5.1 MNA Parameters............................................................................................................... 5 5.2 Biodegradation Screening Matrix................................................................................... 5 6.0 FINDINGS................................................................................................................................6 7.0 REFERENCES..........................................................................................................................7 Page i of i r■ . ■ Our People. Your Success. FIGURES Figure 1 General Location Map Figure 2 Monitoring Well Location Map Figure 3A Potentiometric Map July 2020 Figure 3B Potentiometric Map January 2020 Figure 4 Groundwater 2L/GWP Exceedances TABLES Table 1 Monitoring Well Construction Details Table 2 Groundwater Surface Elevations Table 3 Historical Groundwater Elevations Table 4 Groundwater Analytical Results Table 5 Surface Water Analytical Results Table 6 Summary of MNA Constituents APPENDICES Appendix I Laboratory Analytical Reports and Field Notes Appendix II Historical Summary Tables (reproduced from Joyce Reports) Table 1A Summary of Historical Groundwater Elevations Table 1B Monitoring Well and Boring Completion Summary Table 2 Summary of Estimated Hydraulic Gradient and Linear Velocity Table 3 Summary of Historical Groundwater Constituents Table 4 Summary of Historical Surface Water Constituents Table 5 Summary of MNA Constituents Table 6 MNA Screening Matrix Page i of i r■ . ■ Our People. Your Success. 1.0 INTRODUCTION 1.1 Site Information The Town of Kernersville Landfill is a closed, unlined municipal solid waste landfill located on approximately 58.2 acres in Forsyth and Guilford Counties, NC, approximately 10 miles north of the Town of Kernersville. The waste disposal area comprises approximately 13.8 acres. Figure 1, General Location Map illustrates the general location of the landfill on top of a 7.5-minute United States Geologic Survey (USGS) topographic map for the Belews Creek, North Carolina quadrangle (quad). The facility was issued a Permit to Operate by the North Carolina Department of Waste Management (DWM) on May 15, 1985, and a Letter of Closure on December 10, 1991. The landfill is zoned residential/agricultural and is bounded on the east and west by open fields and woodlands. The landfill is bounded on the north by property owned by Waste Management and farther north by Freeman Road, and on the south by an unnamed tributary of Belews Creek. Figure 2, Water Quality Sampling Locations Map illustrates the property boundaries, waste disposal boundaries, monitoring well locations, and surface water sample locations. 1.2 Site Geology and Hydrogeology The Town of Kernersville Landfill is located in the Piedmont Physiographic Province (Piedmont) of North Carolina and is underlain by intrusive granitic rocks of Pennsylvanian -to -Permian age, which are part of the Charlotte Belt Geologic Unit. The uppermost aquifer is unconfined and includes both saprolite and fractured bedrock, which are well-connected. Groundwater at the site has historically been reported flowing generally to the southwest. Joyce Engineering (JOYCE) conducted hydraulic conductivity testing in November 2013 and, using the modified Darcy equation (V=Ki/n), reported the following: • Hydraulic gradient (i) is 0.04 ft/ft; • An effective porosity value (n) of 30 percent was estimated; • Hydraulic conductivity (K) 1.73 ft/day: and • The calculated groundwater flow rate averaged approximately 0.20 ft/day. 1.3 Regulatory Status The Town of Kernersville (Town) is currently monitoring groundwater at the landfill in accordance with criteria set forth in Title 15A Subchapter 13B .0500 of the North Carolina Department of Environmental Quality (NCDEQ) Division of Waste Management (DWM) Solid Waste Management Rules for municipal solid waste landfills (MSWLF) closed prior to October 9, 1993. Samples are analyzed for all constituents listed in 40 CFR Part 258, Appendix I Constituents for Detection Monitoring ("Appendix I") and compared to the North Carolina Groundwater Quality Standards as listed in 15A NCAC 2L (the "2L Standards"), or, when a 2L Standard is not established, the NCDEQ DWM Solid Waste Section's Groundwater Protection Standards (GWPs) or Interim Maximum Allowable Concentrations (IMACs). Based on the presence of targeted Appendix I constituents detected at concentrations above the referenced standards that could potentially be crossing the facility boundary, the North July 2020 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project # 06140180.33 September 2020 Page 1 of 7 r■ . ■ Our People. Your Success. Carolina Department of Environment and Natural Resources (NCDENR), Solid Waste Section (Section) requested that the Town submit a Groundwater Assessment Plan to evaluate site conditions as they relate to groundwater quality. JOYCE submitted a Groundwater Assessment Report to the Section on May 13, 2013, and concluded that, based on site hydrogeology, it would be very unlikely that the site impacts at concentrations above their respective standards would cross the property boundaries. In a July 16, 2013 response to information presented in the Groundwater Assessment Report, the Section determined that, despite the conclusions presented in JOYCE's Groundwater Assessment Report, the detection of volatile organic compounds (VOCs) at concentrations that exceeded the referenced standards beyond the compliance boundary of the site constituted a violation of Section regulations. JOYCE submitted a Corrective Action Plan (CAP) on behalf of the Town in July 2014, which the Section approved on November 4, 2014. Note that the NCDENR is now North Carolina Department of Environmental Quality (NCDEQ). f►��>•VITAI I I va a [4]PI1IM 0.11,Eel a:Z91e1:7e1u 2.1 Groundwater Monitoring Program The current groundwater quality monitoring network consists of six monitoring wells, including one upgradient (background) well and five downgradient (compliance) wells. Monitoring well locations are illustrated on Figure 2. Monitoring well MW-6 currently serves as the background well for the facility. Former background monitoring well MW-1 was replaced (by monitoring well MW-6) due to slow recharge in the well, low well volumes, or being dry during sampling events. Downgradient monitoring wells MW-2, MW-3S, MW-3D, MW-4, and MW-5 are monitored for the Appendix I list of constituents as part of the compliance network for the facility. Monitoring well MW-1 is currently monitored for water levels only. Well construction parameters are presented in Table 1, Monitoring Well Construction Details. As a condition of the aforementioned CAP, monitoring wells MW-2, MW-3S, MW-3D, MW-4 and MW-6 are also monitored for the following Monitored Natural Attenuation (MNA) constituents: • Nitrate, sulfate, chloride, sulfide, alkalinity; • Total organic carbon (TOC); Groundwater samples collected semi-annually are analyzed for the Appendix I list of constituents and for the above -referenced MNA parameters. Sample analyses are then compared to the 2L Standards or IMACs or GWPs, where appropriate. 2.2 Surface Water Monitoring Program Surface water at the landfill is monitored semi-annually in conjunction with the groundwater sampling events. Samples are collected from three surface water monitoring points (designated SW-1, SW-2, and SW-3). Surface water sample locations are also illustrated on Figure 2. July 2020 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project # 06140180.33 September 2020 Page 2 of 7 r■ . ■ Our People. Your Success. These surface water monitoring points are summarized below, along with their current monitoring program status. Surface Water Designation SW-1 SW-2 SW-3 Classification Upstream/Compliance Compliance Compliance Surface water samples are collected and analyzed for the Appendix I list of constituents during both semi-annual monitoring events. Analytical results are compared to the Classifications and Water Quality Standards Applicable to Surface Waters of NC as listed in 15A NCAC 2B (213 Standards). 3.0 GROUNDWATER AND SURFACE WATER SAMPLING EVENT 3.1 Field Services On July 15, 2020, WithersRavenel (WR) personnel mobilized to the facility to purge and sample monitoring wells MW-1, MW-2, MW-3S, MW-3D, MW-4, MW-5, and MW-6 and sample surface water sample locations SW-1, SW-2, and SW-3. Prior to purging each well, the depth to the static water level was measured with an electronic water level indicator accurate to 0.01- foot. Due to the lack of water encountered within the well, monitoring well MW-1 was measured for static water level only. Table 2, Groundwater Surface Elevations presents groundwater surface elevations calculated from static water levels recorded by WR personnel compared to top -of -well casing elevations reported by JOYCE in their 2015 reports. For comparison purposes, the most recent sampling event (January 2020) data are illustrated on some of the figures. Figure 3A, Potentiometric Map (July 2020) illustrates estimated groundwater flow across the landfill site based on the reported groundwater surface elevations during the July 2020 sampling event. Figure 313, Potentiometric Map (January 2020) illustrates estimated groundwater flow across the landfill site based on the reported groundwater surface elevations during the January 2020 sampling event. As shown on these figures and in recent sampling events, groundwater appears to be flowing in a southwesterly direction towards an unnamed tributary of East Belews Creek. Table 3, Historical Groundwater Elevations presents groundwater surface elevations reported by JOYCE between 2009 and 2015, and by WR between 2016 and 2020. The monitoring wells were purged and sampled using either disposable bailers or submersible pump. Field parameters, including temperature, pH, specific conductivity, dissolved oxygen, oxidation-reduction potential, and turbidity, were recorded in the site -specific log book prior to purging, after each purge volume, and during sampling. Groundwater samples from each monitoring well were collected directly from a submersible pump into laboratory -prepared and -provided containers or decanted from disposable bailers into the containers immediately after purging. Samples were then placed into laboratory - provided coolers, chilled on ice to approximately 4°C, and delivered to a State of North Carolina - certified laboratory (Research & Analytical Laboratories) under standard Chain -of -Custody (COC) protocol. Field data logs are provided in Appendix I. July 2020 Water Quality Monitoring Report WR Project # 06140180.33 Town of Kernersville Closed Landfill, Permit 34-04 September 2020 Page 3 of 7 r■ . ■ Our People. Your Success. Surface water samples were collected either directly into laboratory -provided, non -preserved sample containers, or by decanting the sample from a non -preserved 1-Liter amber glass container into the appropriate containers. In both methods, samples were collected with the container opening facing into the current flow. Care was taken to not overflow the preserved sample containers (which could lead to preservative loss) and avoid sample -induced turbidity. Samples were collected initially from the downstream sample location (SW-2), and in sequence upstream, SW-3 and then SW-1 (Figure 2). After sample collection, the samples were placed in a laboratory -provided cooler, chilled on ice to approximately 4°C, and submitted to Pace Analytical Laboratories under standard COC protocol. 3.2 Quality Control One Duplicate Sample (DUP-1) was collected by WR personnel as part of the July 2020 sampling event. Also, a Trip Blank was prepared by the laboratory to accompany the volatile sampling containers during shipment to and from the laboratory. The Trip Blank was analyzed for VOCs only. 4.0 ANALYTICAL RESULTS 4.1 Groundwater Groundwater samples were analyzed for the Appendix I list and the modified list of MNA constituents and compared to the respective 2L Standards or GWPs where appropriate. As shown on Table 4, Groundwater Analytical Results, the following organic and inorganic constituents were detected in groundwater samples during the July 2020 sampling event with at least one sample concentration above the 2L Standard or GWP. All concentrations are reported in micrograms per liter (µg/L). Concentrations detected above the 2L Standard or GWPs are illustrated in bold font. Constituent Referenced Standard Compliance Wells (2L/GWP) MW-2R MW-3S MW-31D MW-4 MW-5 MW-6 Lead 15 <6.0 <6.0 <6.0 <6.0 78.9 7.57 Thallium 0.2 <10.0 <10.0 <10.0 4.66 J <10.0 <10.0 Vanadium 0.3 <20.0 <20.0 <20.0 <20.0 91.3 <20.0 Benzene 1 3.81 0.366 J 0.708 J 0.402 J <1.0 <1.0 1,1-Dichloroethane 6 12.0 0.528 J 1.76 1.39 <1.0 <1.0 1,2-Dichloroethane 0.4 0.622 J 0.259 J 0.711 J <1.0 <1.0 <1.0 1,2-Dichloropropane 0.6 4.46 <1.0 1.11 <1.0 <1.0 <1.0 Vinyl Chloride 0.03 4.17 1.85 10.2 <1.0 <1.0 <1.0 Figure 4, Groundwater Standard Exceedances Map illustrates exceedances to the referenced standards at the monitoring well locations. In general, the organic and inorganic results are consistent with historical data. Historical groundwater data, laboratory quality assurance/quality control information and the chain -of -custody records are included in the Appendix. July 2020 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project # 06140180.33 September 2020 Page 4 of 7 r■ . ■ Our People. Your Success. 4.2 Surface Water Surface water samples were analyzed for the Appendix I list only. No analytes were detected at concentrations above the 213 Standards in surface water samples collected during the July 2020 sampling event. The results were consistent with historical data. Surface water data can be found in Table 5, Surface Water Analytical Results. The results, as reported by the laboratory, historical surface water data, the laboratory quality/assurance/quality control information, and the chain -of -custody records are included in the Appendix. 5.0 MONITORED NATURAL ATTENUATION (MNA) EVALUATION 5.1 MNA Parameters According to previous reports, in accordance with the facility CAP, MNA baseline sampling was initiated during the November 2014 sampling event and finished during the November 2015 sampling event. During those events, the full list of MNA parameters (shown below) were measured in samples collected from monitoring wells MW-2, MW-3S, MW-3D, MW-4, and MW-6. MNA field (geochemical) parameters included: • Temperature; • pH; • Specific conductivity; • Oxidation-reduction potential (ORP); • Turbidity; and • Dissolved oxygen. Laboratory parameters included: • Nitrate; • Sulfate: • Chloride; • Alkalinity; • Sulfide; and • Total Organic Carbon (TOC). As shown on Table 6, Summary of MNA Constituents, WR sampled for the MNA parameters during the July 2020 monitoring event as amended by a December 6, 2016 letter from NCDEQ. Laboratory reports and field data forms are included in the Appendix. 5.2 Biodegradation Screening Matrix The MNA parameter data were evaluated in general accordance with the weighted system presented in Table 2.3, Biodegradation Screening Matrix (Matrix) of the United States Environmental Protection Agency's (USEPA's) Technical Protocol for Evaluation of Natural Attenuation of Chlorinated Solvents in Groundwater (Manual), to determine whether the conditions are conducive to, or whether there is evidence of, anaerobic degradation of the chlorinated hydrocarbons. According to information presented in the Manual, • A score less than 5 indicates that there is "inadequate evidence" for anaerobic natural attenuation; • A score of 6 to 14 indicates that there is "limited evidence" for anaerobic natural attenuation; July 2020 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project # 06140180.33 September 2020 Page 5 of 7 r■ . ■ Our People. Your Success. • A score of 15 to 19 indicates that there is "adequate evidence" for anaerobic natural attenuation; and A score of 20 or more indicates that there is "strong evidence" that anaerobic natural attenuation is occurring. The MNA evaluation was performed based on the results from the July 2020 sampling event for downgradient wells located within the contaminant plume and compared, where appropriate, to samples collected from the background well (MW-6). Because it is unclear whether some of the target analytes are naturally -occurring or daughter products resulting from natural attenuation, the scores have been calculated with and without the daughter product points. The site -specific Matrix for this sampling event is presented in the Appendix. As shown, the scores ranged from 12 to 24 (characterized as "limited evidence of natural attenuation" to "strong evidence of natural attenuation.") The mid -range (or average score of 18), indicates there is "adequate evidence of natural attenuation." 6.0 FINDINGS Target analytes detected above their respective 2L Standards and/or GWPs in groundwater samples collected during the July 2020 sampling event appear to generally be consistent with previous events. In addition, there were no target analytes detected in the surface water samples at concentrations above their respective 2B Standards. The Town of Kernersville Closed Landfill will continue to monitor groundwater in accordance with the approved CAP. The next semi-annual sampling event is tentatively scheduled for January 2021. July 2020 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project # 06140180.33 September 2020 Page 6 of 7 r■ . ■ Our People. Your Success. 7.0 REFERENCES Brown, Philip M., Chief Geologist, 1985, Geologic Map of North Carolina, The North Carolina Geologic Survey, scale 1:500,000. Joyce Engineering, Inc. Water Quality Monitoring Plan, Piedmont Landfill & Recycling Center, September 2010. -----, Second Semi-annual Water Quality Monitoring Report of 2014, Town of Kernersville Landfill, Permit 34-04, March 2015. -----, Second Semi-annual Water Quality Monitoring Report of 2015, Town of Kernersville Landfill, Permit 34-04, March 2016. -----, Corrective Action Evaluation Report (CAER), Town of Kernersville Landfill, Permit 34-04, October 16, 2016. North Carolina Department of Environment and Natural Resources, 2016 Solid Waste Section Guidelines for Groundwater, Soil and Surface Water Sampling. -----, Corrective Action Evaluation Report Response Letter, Closed Town of Kernersville MSW Landfill, December 6, 2016. -----, MNA Excerpt from Examples of Approved Groundwater Corrective Measures for Solid Waste Management Facilities, 2008. Technical Protocol for Evaluation Natural Attenuation of Chlorinated Solvents in Groundwater, EPA/600/R-98/128, September 1998. United States Geological Survey, 7.5-Minute Quadrangle, Belews Creek, North Carolina. July 2020 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project # 06140180.33 September 2020 Page 7 of 7 FIGURES JI ooD��1� c sa I g50 �� WASTE ISPOSAL BOUNDARY 01 d 6MOKF HO LOW RDRio i Coln IL'L/.��,L GRAPHIC SCALE"' y�y� 500 1000 2 o Ll - �iiic 000 ft. TOWN F KERNER VILLE DRAWN BY: SCALE: FIGURE NO.: W i t h e rs Ra ve n e l CLOSED LANDFILL - PERMIT #34-04 MDF 1"=1000' 1 1 / Engineers Planners Surveyors GOODWILL CHURCH ROAD DATE: PROJECT NO.: APPROVED BY: KERNERSVILLE, GUILFORD/FORSYTH COUNTY, NC 115 MacKenan Drivel Cary, NC 275111 t: 919A69.3340 I license #:C-08321 www.withemrsvenel.com GENERAL LOCATION MAP SMB 08/21/2020 06140180.33 IC\l4\I4-01W\140180.33-Sae 833 Lm 191 Swli— EYE 2020\En.ie1.R—s a DNtnraEMs\WO Erwn J 2019V0190918_B.--- F-- S 2= - 114111rMY. =U -� F� A SW-2 MW-3D MW-4 MW-3S MW-2R SW-3 � MW-5 MW-6 f`� T GOODWILL CHURCH ROAD ,... LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY 0 GROUNDWATER MONITORING WELL G SURFACE WATER SAMPLE LOCATION NOTES: 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. DRAWN BY: SCALE: FIGURE NO.: WithersRavenel TOWN OF KERNERSVILLE CLOSED LANDFILL -PERMIT 34-04 MDF 1"=300' 2 lip Engineers I Planners I Surveyors GOODWILL CHURCH ROAD WATER QUALITY SAMPLE LOCATIONS MAP APPROVED BY: DATE: PROJECT NO.: KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA 115 MacKenan Drive Cary, NC 27511 t: 919.469.3340 license k: C-0832 www.withersraveneLcom 5M B 08/21/2020 06140180.33 It%l4kl4-0I8D<I40I8D.17-Sm 833 LeMli Swvka M 3070\[miekR—is ma DtlwwaeYa\MO Evenl JW 3019V0190918_13erMe- herwr 1 2020 - dINIW. A9lEY � L ' -d j�ti: I I 0000100110010000FAMFAMFAMFAMFAMFAMFAMFAMFAMFAMFAMOVAOFAMMIMUMMIMMOMIMMOFMOlmollmommIJ . - MW-1 (DRY) >>S 770 ;60 'ss (752.62) M 3D M W-4 (754.22) MW 3S (751.10) W-2111 MW-5 v (759.17) 01 (768.57) rn u, 0 s , �T GOODWILL CHURCH ROAD ,... . r: . .. LEGEND 33 w - FACILITY BOUNDARY fk WASTE DISPOSAL BOUNDARY MW-6 x`" d1k (788.90) y, ' \d "A'ee it a a ;^ { 0- GROUNDWATER MONITORING WELL � CID`' (761.96) GROUNDWATER SURFACE ELEVATION GROUNDWATER SURFACE ELEVATION CONTOUR ESTIMATED GROUNDWATER FLOW f NOTES: 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. DRAWN BY: SCALE: FIGURE NO.: �0- WithersRavenel TOWN OF KERNERSVILLE CLOSED LANDFILL - PERMIT #34-04 POTENTIOMETRIC MAP LRE 1"=300' 3A 1 / Engineers I Planners I Surveyors GOODWILL CHURCH ROAD (JULY 2020) APPROVED BY: DATE: PROJECT NO.: KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA 115 MacKenan Drive I Cary, NC 27511 t 919.469.3340 1 license #: C-0832 SMB 08/21/2020 06140180.33 Ik\1A1h-01!D\1�01'^�— M &M L..M Sider FM L— - Ma.! 76 2020' — FLUOR. L GOODWI11 CHURCH ROAD I?CIAD LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY 0- GROUNDWATER MONITORING WELL (761.96) GROUNDWATER ELEVATION NOTES: GROUNDWATER ELEVATION CONTOUR ESTIMATED GROUNDWATER FLOW DIRECTION 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. -40- WithersRavenel TOWN OF KERNERSVILLE CLOSED LANDFILL - # PERMIT 34-04 POTENTIOMETRIC MAP DRAWN BY: LRE SCALE: 1"=300' FIGURE NO.: 3B 1/ Engineers I Planners I Surveyors GOODWILL CHURCH ROAD (JANUARY 2020) APPROVED BY: DATE: PROJECT NO.: KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA 115 MacKenan Drive I Cary, NC 27511 t 919.469.3340 1 license #: C-08321 SM B 08/21/2020 06140180.33 MW-4 THALLIUM VANADIUM VINYL CHLORIDE MW-3D 1,2-DICHLOROETHANE 1,2-DICHLOROPROPANE R O VINYLCHLORIDE A D VANADIUM JAN.2020 JULY2020 3.0 <20.0 7.7 10.4 0.490 J 0.80 9.7 2.61 SW-2 fir (��MW-3D I I &f ,,MW-3S MW-3S JAN.2020 JULY2020 1,2-DICHLOROETHANE 0.17 J 0.259 J , VANADIUM 1.19 <20.0 VINYL CHLORIDE <1.0 1.85 SW-3 Q , 0.711 J 1.11 10.2 <20.0 MW-2R Q SW-1 MW-2R JAN.2020 JULY 2020 BENZENE T53 3.81 1,1-DICHLOROETHANE 8.35 12.0 1,2-DICHLOROETHANE 0.40J 0.662J 1,2-DICHLOROPROPANE 2.69 4.46 TRICHLOROETHENE 1.55 2.09 TETRACHLOROETHENE 0.23 J 0.507 J VANADIUM 2.31 <20.0 VINYL CHLORIDE 3.65 4.17 r \ ,�..xl MW-6 MW-1 (DRY) 1 4 F r \ S J x LVA MW-5 LEAD VANADIUM 7w. s , �T • GOODWILL CHURCH ROAD ... VANADIUM JAN.2020 JULY2020 3.5 78.9 5.18 91.3 JAN.2020 JULY2020 4.37 <20.0 LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY 0 SHALLOW MONITORING WELL ® DEEP MONITORING WELL Q SURFACE WATER SAMPLE LOCATION NOTES: 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. 3.) ONLY ANALYTICAL RESULTS THAT EXCEEDED THE 2L STANDARD ARE ILLUSTRATED. 4.) FOR WELLS FROM WHICH DUPLICATE SAMPLES WERE COLLECTED, THE HIGHEST DETECTED CONCENTRATION OF EACH CONTAMINANT IS SHOWN. GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. -40- Withers Rave n e l 1/ Engineers I Planners I Surveyors III Ma,Ke�a, Dd�e I Cary, NC 27511I e: eie.aa9saao I r�ense a: e-oasz I TOWN OF KERNERSVILLE CLOSED LANDFILL - PERMIT #34-04 GOODWILL CHURCH ROAD KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA GROUNDWATER 2L STANDARD/GWP EXCEEDANCES MAP DRA LREIN BY. 51"=.3001 FIGURE NO': 4 APPROVED BY: SM B DATE: 08/21/20 PROJECT NO.: 06140180.33 eVw.u.�nu\owaee\wwoexl r. ter. L.,M F04A.a- wwt 21. 2020 - BMW INIPA TABLES TABLE 1 MONITORING WELL CONSTRUCTION DETAILS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 Well ID Date Installed Well Casing Diameter (Inches) Casing Depth (ft-bTOC) Screen Interval (ft-bTOC) Total Depth (ft-bTOC) Top of Casing Elevation (feet above MSL) MW-1 Not Listed 2 24.96 24.96 - 34.96 34.96 806.42 MW-2R Not Listed 2 3.18 3.18 - 13.18 13.18 762.19 MW-3S Not Listed 2 14.00 14.00 - 24.00 24.00 764.57 MW-3D Not Listed 2 36.96 36.96 - 56.96 56.96 764.56 MW-4 Not Listed 2 4.40 4.40 - 14.40 14.40 760.26 MW-5 Not Listed 2 6.36 6.36 - 11.36 11.36 773.32 MW-6 Not Listed 2 10.46 10.46 - 20.46 20.46 804.87 Notes: 1) ft-bTOC = Feet below top of casing 2) MSL = Mean sea level Data, including "Top of Casing Elevation", reproduced from Second Semiannual Water Quality Monitoring 3) Report of 2014; Joyce Engineering; March 10, 2015. 1 of 1 TABLE 2 GROUNDWATER SURFACE ELEVATIONS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 7/15/2020 GROUNDWATER SCREENED TOP OF CASING DEPTH WELL ID INTERVAL ELEVATION SURFACE (ft-bTOC) (feet above MSL) WATERR ELEVATION (ft-bTOC) (feet above MSL) MW-1 24.96 - 34.96 806.42 DRY MW-2R 3.18 - 13.18 762.19 3.02 759.17 MW-3S 14.00 - 24.00 764.57 13.47 751.10 MW-3D 36.96 - 56.96 764.56 11.94 752.62 MW-4 4.40 - 14.40 760.26 6.04 754.22 MW-5 6.36 - 11.36 773.32 4.75 1 768.57 MW-6 10.46 - 20.46 804.87 15.97 1 788.90 Notes: 1) All measurements are in feet. 2) Elevation data is measured in feet above Mean Sea Level (MSL). 3) Depth to water measured in feet below top of casing (ft-bTOC) 4) "Screened Interval" and "Top of Casing Elevation" components are reproduced from Second Semiannual Water Quality Monitoring Report of 2014; Joyce Engineering; March 10, 2015. 1 of 1 TABLE 3 HISTORICAL GROUNDWATER ELEVATIONS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 WELL ID Top of Casing Elevation (feet) Date Depth to Groundwater (feet) Groundwater Elevation (feet) MW-1 806.42 12/30/2009 33.97 772.45 6/1/2010 32.97 773.45 11/16/2010 32.87 773.55 12/29/2010 33.13 773.29 6/29/2011 33.32 773.10 11/1/2011 34.50 771.92 5/1/2012 34.54 771.88 11/7/2012 34.77 771.65 5/9/2013 36.47 769.95 11/7/2013 34.96 771.46 6/5/2014 34.20 772.22 11/20/2014 34.69 771.73 7/29/2016 33.91 772.51 12/21/2016 34.47 771.95 9/13/2017 DRY DRY 7/10/2018 DRY DRY 1/9/2019 DRY DRY 7/24/2019 DRY DRY 7/15/2020 DRY DRY MW-2R 762.19 12/30/2009 3.03 759.16 6/1/2010 3.29 758.90 11/16/2010 3.05 759.14 12/29/2010 3.36 758.83 6/29/2011 3.81 758.38 11/1/2011 3.70 758.49 5/1/2012 3.65 758.54 11/7/2012 3.99 758.20 5/9/2013 2.99 759.20 11/7/2013 4.10 758.09 6/5/2014 3.74 758.45 11/20/2014 4.11 758.08 7/29/2016 4.01 758.18 12/21/2016 3.85 758.34 9/13/2017 4.22 757.97 7/10/2018 4.41 757.78 1/9/2019 2.84 759.35 7/24/2019 3.40 758.79 7/15/2020 3.02 759.17 MW-3S 764.57 12/30/2009 13.03 751.54 6/1/2010 13.81 750.76 11/16/2010 13.59 750.98 12/29/2010 14.75 749.82 6/29/2011 14.03 750.54 11/1/2011 9.84 754.73 5/1/2012 13.71 750.86 11/7/2012 14.27 750.30 5/9/2013 12.05 752.52 11/7/2013 14.45 750.12 6/5/2014 13.90 750.67 11/20/2014 14.33 750.24 7/29/2016 14.04 750.53 12/21/2016 14.00 750.57 9/13/2017 14.29 750.28 7/10/2018 15.00 749.57 1/10/2019 12.50 752.07 7/24/2019 1 13.96 750.61 7/15/2020 1 13.47 751.10 Notes: 1) All measurements are in feet. 2) Elevation data is relative to Mean Sea Level. 3) Depth to water measured in feet below top of casing. 4) NM = Not Measured 1 of 3 TABLE 3 HISTORICAL GROUNDWATER ELEVATIONS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 WELL ID Top of Casing Elevation (feet) Date Depth to Groundwater(feet) Groundwater Elev feet) MW-3D 764.56 12/30/2009 11.77 752.79 6/1/2010 11.93 752.63 11/16/2010 11.97 752.59 12/29 /2010 12.11 752.45 6/29/2011 12.40 752.16 11/1/2011 12.66 751.90 5/1/2012 12.22 752.34 11/7/2012 12.95 751.61 5/9/2013 11.32 753.24 11/7/2013 13.06 751.50 6/5/2014 12.42 752.14 11/20/2014 13.03 751.53 7/29/2016 12.32 752.24 12/21/2016 12.46 752.10 9/13/2017 12.96 751.60 7/10/2018 15.00 749.56 1/10/2019 11.25 753.31 7/24/2019 11.86 752.70 7/15/2020 11.94 752.62 MW-4 760.26 12/30/2009 5.93 754.33 6/1/2010 6.36 753.90 11/16/2010 6.52 753.74 12/29/2010 6.58 753.68 6/29/2011 6.85 753.41 11/1/2011 7.18 753.08 5/1/2012 6.71 753.55 11/7/2012 7.39 752.87 5/9/2013 5.82 754.44 11/7/2013 7.47 752.79 6/5/2014 6.90 753.36 11/20/2014 7.45 752.81 7/29/2016 7.00 753.26 12/21/2016 7.00 753.26 9/13/2017 7.33 752.93 7/10/2018 7.00 753.26 1/9/2019 5.24 755.02 7/24/2019 5.89 754.37 7/15/2020 6.04 754.22 Notes: 1) All measurements are in feet. 2) Elevation data is relative to Mean Sea Level 3) Depth to water measured in feet below top of casing. 4) NM = Not Measured 2of3 TABLE 3 HISTORICAL GROUNDWATER ELEVATIONS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 WELL ID Top of Casing Elevation (feet) Date Depth to Groundwater (feet) Groundwater Elevation (feet) MW-5 773.32 12/30/2009 4.11 769.21 6/1/2010 3.63 769.69 11/16/2010 3.51 769.81 12/29/2010 3.76 769.56 6/29/2011 3.59 769.73 11/1/2011 3.69 769.63 5/1/2012 3.77 769.55 11/7/2012 4.75 768.57 5/9/2013 NM NM 11/7/2013 5.19 768.13 6/5/2014 4.75 768.57 11/20/2014 4.09 769.23 7/29/2016 11.36 761.96 12/21/2016 3.41 769.91 9/14/2017 5.48 767.84 7/10/2018 NM NM 1/10/2019 10.50 762.82 7/24/2019 4.03 769.29 7/15/2020 4.75 768.57 MW-6 804.87 12/30/2009 18.21 786.66 6/1/2010 16.55 788.32 11/16/2010 16.94 787.93 12/29/2010 17.50 787.37 6/29/2011 18.06 786.81 11/1/2011 19.77 785.10 5/1/2012 19.55 785.32 11/7/2012 DRY DRY 5/9/2013 17.31 787.56 11/7/2013 DRY DRY 6/5/2014 19.03 785.84 11/20/2014 20.46 784.41 7/29/2016 20.46 784.41 12/21/2016 20.22 784.65 9/14/2017 20.64 784.23 7/10/2018 DRY DRY 1/9/2019 17.49 787.38 7/24/2019 16.51 788.36 7/15/2020 15.97 788.90 Notes: 1) All measurements are in feet. 2) Elevation data is relative to Mean Sea Level 3) Depth to water measured in feet below top of casing. 4) NM = Not Measured 3of3 TABLE 4 GROUNDWATER ANALYTICAL RESULTS (JULY 2020) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 Analytical Method EPA 6010 Contaminant Of Concern C E i+ Q v N Q E 'i m E 2 > i ca E •2 E 'O U o i U +' U N a Q lJ a I n V Z E c N to v in )_ E f6 H C i U N CAS # 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-43-9 7440-47-3 7440-48-4 7440-50-8 7439-92-1 7440-02-0 7782-49-2 7440-22-4 7440-28-0 7440-62-2 7440-66-6 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result 7Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual MW-1 7/15/2020 NOT SAMPLED (DRY WELL) MW-2R 7/15/2020 <10.0 <10.0 234 <2.00 <2.00 <10.0 1.11 J <10.0 <6.00 <10.0 <10.0 <5.0 <10.0 <20.0 19.4 J MW-3S 7/15/2020 <10.0 <10.0 121 <2.00 <2.00 <10.0 8.10 J <10.0 <6.00 3.82 J <10.0 <5.0 <10.0 <20.0 37.9 J MW-3D 7/15/2020 <10.0 <10.0 45.9 <2.00 <2.00 <10.0 <10.0 <10.0 <6.00 <10.0 <10.0 <5.0 <10.0 <20.0 26.3 J DUP-1 7/15/2020 <10.0 <10.0 45.1 <2.00 <2.00 <10.0 <10.0 <10.0 <6.00 <10.0 <10.0 <5.0 <10.0 <20.0 19.6 J MW-4 7/15/2020 <10.0 <10.0 94.2 <2.00 0.63 J <10.0 1.82 J <10.0 <6.00 4.06 J <10.0 <5.0 4.66 J <20.0 22.6 J MW-5 7/15/2020 <10.0 6.92 J 231 2.26 <2.00 5.81 J 17.4 J 22.9 78.9 4.99 J <10.0 <5.0 <10.0 91.3 114 MW-6 7/15/2020 <10.0 <10.0 84.4 <2.00 <2.00 <10.0 0.999 J <10.0 7.57 <10.0 <10.0 JIM <5.0 IN <10.0 <20.0 1 18.3 J Trip Blank 7/15/2020 NA NA NA NA NA NA NA NA NA NA NA NA NA NA 2L Standard/GWP (µg/L) 13 10 700 ��'43 2 1 10 13 1 1,000 1 15 100 20 1 20 0.2 0.3 3 1,000 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. 7) Cobalt and Thallium were analyzed by EPA Method 6020B. NA Not Analyzed by Method Shown Result Result Exceeds 2L Standard or GWP Qualifiers J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limits. Page 1 of 5 TABLE 4 GROUNDWATER ANALYTICAL RESULTS (JULY 2020) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 Analytical Method EPA 8260 v c �a s y � Contaminant Of Concern v c 4) Y � o t v Gl u � c � N v C v p v E O �; aci +s+ e c G v 0 0 O c c O v O O u j. u N E O E O E O 7 m O O O Q Q m m m m cv U s U s U s U CAS # 67-64-1 107-13-1 71-43-2 75-27-4 75-25-2 74-83-9 78-93-3 56-23-5 108-90-7 75-00-3 67-66-3 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qua[ Result Qual MW-1 7/15/2020 NOT SAMPLED (DRY WELL) MW-2R 7/15/2020 <50 <10 3.81 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <5.00 <5.00 MW-3S 7/15/2020 <50 <10 0.366 J <1.00 <1.00 <5.00 <10.0 <1.00 1.82 <5.00 <5.00 MW-3D 7/15/2020 <50 <10 0.708 J <1.00 <1.00 <5.00 <10.0 <1.00 1.16 <5.00 <5.00 DUP-1 7/15/2020 <50 <10 0.690 J <1.00 <1.00 <5.00 <10.0 <1.00 1.080 <5.00 <5.00 MW-4 7/15/2020 <50 <10 0.402 J <1.00 <1.00 <5.00 <10.0 <1.00 0.198 J <5.00 <5.00 MW-5 7/15/2020 <50 <10 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <5.00 <5.00 MW-6 7/15/2020 <50 <10 <1.00 <1.00 <1.00 1 <5.00 1 1 <10.0 <1.00 <1.00 1 <5.00 <5.00 Trip Blank 7/15/2020 <50 <10 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <5.00 <5.00 2L Standard/GWP (µg/L) 6,000 NE 1 0.6 4 100 4,000 0.3 50 3,000 70 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown Result Result Exceeds 2L Standard or GWP Qualifiers J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limits. Page 2 of 5 TABLE 4 GROUNDWATER ANALYTICAL RESULTS (JULY 2020) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 Analytical Method EPA 8260 v c �a a 0 op v 0. 0 c o y c c ar- s s c v v c c c W o Contaminant Of Concern u m m ca Gl G1 0 co 0 +, c u C O C y O O O O O s Q *' v E � � E o 0 s 0 s 0 s 0 s 0 s r7 N 0 -2 u2 E u u u u u N r i 0 0 0 0 0 0 0 0 N t N N 2 N a1 N a1 �A O f6 U ri ri ri ri ri ri u CAS # 74-87-3 96-12-8 106-93-4 74-95-3 95-50-1 106-46-7 75-34-3 107-06-2 75-35-4 156-59-2 156-60-5 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual MW-1 7/15/2020 NOT SAMPLED (DRY WELL) MW-2R 7/15/2020 <2.5 <5.00 <1.00 <1.00 0.189 J 4.88 12.0 0.622 J <1.00 32.5 1.02 MW-3S 7/15/2020 <2.5 <5.00 <1.00 <1.00 <1.00 1.65 0.528 J 0.259 J <1.00 2.52 <1.00 MW-3D 7/15/2020 <2.5 <5.00 <1.00 <1.00 0.151 J 4.77 1.76 0.711 J <1.00 16.5 <1.00 DUP-1 7/15/2020 <2.5 <5.00 <1.00 <1.00 0.143 J 4.61 1.70 0.712 J <1.00 15.800 <1.00 MW-4 7/15/2020 <2.5 <5.00 <1.00 <1.00 0.117 J 2.46 1.39 <1.00 <1.00 15.9 <1.00 MW-5 7/15/2020 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 MW-6 7/15/2020 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 Trip Blank 7/15/2020 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 2L Standard/GWP (µg/L) 3 0.04 0.02 70 20 6 6 0.4 7 70 100 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown Result Result Exceeds 2L Standard or GWP Qualifiers J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limits. Page 3 of 5 TABLE 4 GROUNDWATER ANALYTICAL RESULTS (JULY 2020) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 Analytical Method EPA 8260 Y m fl W N L t c a w a G G Contaminant Of Concern a o c s a, O c p s p s r- G u +, C V p- m N C N tua tua OL O t M fl. Oi N C y Gl H G�1 H G�1 H O Gl u `� fl N p C N N u p C i 7 N c6 O NN cG� ri r N O W H G G In 11 r CAS # 78-87-5 10061-02-6 108-20-3 100-41-4 98-82-8 75-09-2 108-10-1 1634-04-4 100-42-5 630-20-6 79-34-5 127-18-4 108-88-3 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual MW-1 7/15/2020 NOT SAMPLED (DRY WELL) MW-2 7/15/2020 4.46 <1.00 0.269 J <1.00 0.216 J <5.00 <10.0 0.340 <1.00 <1.00 <1.00 0.507 J <1.00 MW-3S 7/15/2020 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 0.168 J <1.00 <1.00 <1.00 <1.00 <1.00 MW-3D 7/15/2020 1.11 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 0.350 J <1.00 <1.00 <1.00 <1.00 <1.00 DUP-1 7/15/2020 1.09 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 0.384 J <1.00 <1.00 <1.00 <1.00 <1.00 MW-4 7/15/2020 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 0.224 J <1.00 <1.00 <1.00 <1.00 <1.00 MW-5 7/15/2020 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 MW-6 7/15/2020 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 Trip Blank 7/15/2020 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 2L Standard/GWP (µg/L) 0.6 0.4 70 600 70 5 100 20 70 1 0.2 0.7 600 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown Result Result Exceeds 2L Standard or GWP Qualifiers J= Estimated concentrate, Estimated concentration above the adjusted method detection limit and below the adjusted reporting the adjusted reporting limits. Page 4 of 5 TABLE 4 GROUNDWATER ANALYTICAL RESULTS (JULY 2020) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 Analytical Method EPA 8260 C C L fC N L L N O41 O N Contaminant Of Concern 0 c O Q o O N L u L u c 4-u L E L O O H 17 O o 17 17 v m ai N L s M CM y ai r-I i •i N N ri ri H H rT ri i X CAS # 71-55-6 79-00-5 79-01-6 75-69-4 96-18-4 526-73 8 75-01-4 1330-20-7 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual MW-1 7/15/2020 NOT SAMPLED (DRY WELL) MW-2R 7/15/2020 <1.00 <1.00 2.09 <5.00 <2.50 0.141 J 4.17 <3.00 MW-3S 7/15/2020 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 1.85 <3.00 MW-3D 7/15/2020 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 10.2 <3.00 DUP-1 7/15/2020 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 <1.00 <3.00 MW-4 7/15/2020 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 10.4 <3.00 MW-5 7/15/2020 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 <1.00 <3.00 MW-6 7/15/2020 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 <1.00 <3.00 Trip Blank 7/15/2020 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 <1.00 <3.00 2L Standard/GWP (µg/L) 200 0.6 3 2,000 0.005 NE 0.03 500 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. Qualifiers NA Not Analyzed by Method Shown J= Estimated concentration above the adjusted method detection limit and below Result Result Exceeds 2L Standard or GWP the adjusted reporting limits. Page 5 of 5 TABLES SURFACE WATER ANALYTICAL RESULTS (JULY 2020) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 Analytical Method EPA 6010 Contaminant Of Concern c £_ E E E _� c ^ m c0 u_ > Q Q CO v m m U s U 0 U 0 U Z N in H i N CAS # 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-43-9 7440-47-3 7440-48-4 7440-50-8 7439-92-1 7440-02-0 7782-49-2 7440-22-4 7440-28-0 7440-62-2 7440-66-6 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result ual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual SW-1 7/15/2020 <10.0 <10.0 44.2 <2.00 <2.00 <10.0 1.45 J <10.0 5.68 J <10.0 <10.0 <5.00 <10.0 <20.0 19.7 J SW-2 7/15/2020 <10.0 <10.0 38.7 <2.00 <2.00 <10.0 0.974 J <10.0 <6.00 <10.0 <10.0 <5.00 <10.0 <20.0 15.8 J SW-3 <10.0 <10.0 35.4 <2.00 < 2.00 <10.0 <10.0 <10.0 3.16 J <10.0 <10.0 <5.00 <10.0 <20.0 15.0 J 2B Standard /L NE 10 0.82 183 NE 3.6 13.88 5 NE NE 36 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2B Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC 3) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. Qualifiers * Hardness -Dependent 15A NCAC 02B Water Quality Standard, Calculated with default in -stream hardness of 25 mg/L J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limits. NA Not Analyzed by Method Shown Result J Result Exceeds 2B Standard Page 1 of 4 TABLES SURFACE WATER ANALYTICAL RESULTS (JULY 2020) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 Analytical Method EPA 8260 v c a 2 v a o s `o v Y s Contaminant Of Concern U c s u v c �y 41 m L W EaN O £ +S+ E v +' y u v O O +' N is+ i £ O 00 v O O O C O O O O 0 u U N v E E E 7 m � O O O O � Q Q m o m 2 m o m N M U s U t U t U s U cv 1 CAS # 67-64-1 107-13-1 71-43 2 75-27-4 75-25-2 74-83-9 78-93-3 56-23 5 108-90-7 75-00-3 67-66 3 74-87-3 96-12-8 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual SW-1 7/15/2020 <50.0 <10.0 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <5.00 <5.00 <2.50 <5.00 SW-2 7/15/2020 <50.0 <10.0 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <5.00 <5.00 <2.50 SW-3 7/15/2020 <50.0 <10.0 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <5.00 <5.00 <2.50 2B Standard /L NE E NE a NE NE 0.254 E NE NE Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2B Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC 3) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. Qualifiers NA Not Analyzed by Method Shown Result J Result Exceeds 2B Standard J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limits. Page 2 of 4 TABLE 5 SURFACE WATER ANALYTICAL RESULTS (JULY 2020) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 Analytical Method EPA 8260 v c y o m c :: a 0 0 O W C C N N aZ N a 0 s y c 0) 0)o c c c o 0 0 Contaminant Of Concern (p 71 N N 00 ra ra `0 0. 0 a 0 `o ch o L w 0 a 0 y 0 E E 0 0 0 0 0 t 5o :Ec u O 0 E 0 o L o L o L O L o L Y N o L M N c s; � E 2 2ri 22 2e i u_ e i w 0 0 0 0 C 0 0 0 C 0 a-i C T N N N i ei N i N vi i L e-I a"I 0 a"I a"I ++ a"I a"I a"I U ++ a"I U ++ i+ W CAS # 96-12-8 106-93-4 74-95-3 95-50-1 106-46-7 110-57-6 75-34-3 107-06-2 75-35-4 156-59-2 156-60-5 78-87-5 10061-01-5 10061-02-6 100-41-4 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result I Qual Result QualLsouQual Result Qual Result Qual SW-1 7/15/2020 <5.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 SW-2 7/15/2020 <5.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 0.164 J <1.00 <1.00 <1.00 <1.00 SW-3 7/15/2020 <5.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 2B Standard /L NE E NE 488 488 NE NE NE NE E NE NE NE NE E Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2B Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC 3) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. Qualifiers NA Not Analyzed by Method Shown Result J Result Exceeds 2B Standard J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limits. Page 3 of 4 TABLES SURFACE WATER ANALYTICAL RESULTS (JULY 2020) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 Analytical Method EPA 8260 Y m � c c � � v s s c m v c I° `o `o v E Contaminant Of Concern c c v v U a v o `o `o s o 1° c v cv a� v + v s s +' v w o 0 >• aL+ C N N U O O U G) 0 O e N i 7 N t L T d C 1 a-i N N T N N a--i e-i H H -4 -4 H H i X CAS # 591-78-6 74-88-4 75-09-2 108-10-1 100-42-5 630-20-6 79-34-5 127-18-4 108-88-3 71-55-6 79-00-5 79-01-6 75-69-4 75-01-4 1330-20-7 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual SW-1 7/15/2020 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <1.00 <3.00 SW-2 7/15/2020 tesultQua, <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <1.00 <3.00 S-3 7/15/2020 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <1.00 <3.00 2B Standard /L NE NE E E NE NE 0.7 11 E E NE 0.025 NE Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2B Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC 3) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. Qualifiers NA Not Analyzed by Method Shown Result J Result Exceeds 2B Standard J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limits. Page 4 of 4 TABLE 6 SUMMARY OF MNA CONSTITUENTS (JULY 2020) TOWN OF KERNERSVILLE LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 Analytical Method EPA 300.0 EPA 353.2 SM 2320B SM 4500-CI-E SM 4500-S2D SM 5310B u ca Contaminant Of Concern ou �,� O 4. L o zz al°u u I°u� CAS # 14808-79-8 NA NA 16887-00-6 18496-25-8 7440-44-0 Well ID Date Collected Result Qual Result Qual Result Qual Result Qua Result Qua Result Qual MW-2R 7/15/2020 <5,000 59.1 J 132,000 11,400 J <50 813 B, J MW-3S 7/15/2020 <5,000 <100 159,000 34,900 <50 J6 2,020 B MW-31D 7/15/2020 <5,000 <100 164,000 21,900 <50 1,010 B MW-4 7/15/2020 <5,000 <100 177,000 19,100 <50 854 13, J MW-6 7/15/2020 3,670 J <100 11,700 J 1,700 <50 2,450 B 2L Standard/GWP (µ /L) 250,000 10,0002 NE 250,000 NE NE Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 4) NE = Not Established 5) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. Qualifiers J = Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit B = The sample analyte is found in the associated blank. J6 = The sample matrix interfered with the ability to make any accurate determinations; spike value was low APPENDIX I Laboratory Analytical Reports and Field Notes aceAnalXical o ANALYTICAL REPORT National Center for Testing & Innovation July 23, 2020 -1r Withers & Ravenel Eng. - Standard Sample Delivery Group: L1240114 Samples Received: 07/16/2020 Project Number: 06140180.24 Description: Kernersville Landfill Report To: Laura Elliott 115 MacKenan Drive Cary, NC 27511 Entire Report Reviewed By: 4�41 Heather J Wagner Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided, and as the samples are received. 41 r f ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 1 of 48 TABLE OF CONTENTS ONE LAB. NATIONWIDE. Cp: Cover Page 1 Fn Tc: Table of Contents 2 Ss: Sample Summary 3 Cn: Case Narrative 5 Sr: Sample Results 6 FS TRIP BLANK L1240114-01 6 [Cn] MW-2 L1240114-02 8 MW-3S L1240114-03 11 FSr MW-31D L1240114-04 14 MW-4 L1240114-05 17 RC MW-5 L1240114-06 20 �GI MW-6 L1240114-07 22 SW-1 L1240114-08 25 rAl SW-2 L1240114-09 27 SW-3 L1240114-10 29 FSC DUP-1 L1240114-11 31 Qc: Quality Control Summary 34 Wet Chemistry by Method 2320 B-2011 34 Wet Chemistry by Method 4500S2 D-2011 35 Wet Chemistry by Method 9056A 36 Wet Chemistry by Method 9060A 37 Metals (ICP) by Method 6010D 38 Volatile Organic Compounds (GC/MS) by Method 8260D 40 GI: Glossary of Terms 45 Al: Accreditations & Locations 46 Sc: Sample Chain of Custody 47 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 2 of 48 SAMPLE SUMMARY ONE LAB. NATIONWIDE. Collected by Collected date/time Received date/time TRIP BLANK L1240114-01 GW Laura Elliott 07/15/2000:00 07/16/20 08:45 FP1 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time FTC Volatile Organic Compounds (GC/MS) by Method 8260D WG1511373 1 07/18/2015:08 07/18/2015:08 ADM Mt. Juliet, TN Collected by Collected date/time Received date/time M MW-2 L1240114-02 GW Laura Elliott 07/15/2011:30 07/16/20 08:45 Method Batch Dilution Preparation Analysis Analyst Location [Cn] date/time date/time Chemistry by Method 2320 B-2011 WG1511471 1 07/22/2017:47 07/22/2017:47 DGR Mt. Juliet, TN FSrWet Wet Chemistry by Method 4500S2 D-2011 WG1511994 1 07/20/2015:49 07/20/2015:49 MJA Mt. Juliet, TN Wet Chemistry by Method 9056A WG1510095 1 07/17/20 01:07 07/17/20 01:07 ELN Mt. Juliet, TN s QC Wet Chemistry by Method 9060A WG1510700 1 07/17/2015:57 07/17/2015:57 VRP Mt. Juliet, TN Metals (ICP) by Method 6010D WG1510364 1 07/19/20 23:32 07/20/2014:07 EL Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1511373 1 07/18/2016:34 07/18/2016:34 ADM Mt. Juliet, TN G� Volatile Organic Compounds (GC/MS) by Method 8260D WG1512594 1 07/21/20 23:27 07/21/20 23:27 ADM Mt. Juliet, TN $AI Collected by Collected date/time Received date/time MW-3S L1240114-03 GW Laura Elliott 07/15/2010:30 07/16/20 08:45 FSC Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Wet Chemistry by Method 2320 B-2011 WG1511471 1 07/22/2017:54 07/22/2017:54 DGR Mt. Juliet, TN Wet Chemistry by Method 4500S2 D-2011 WG1511994 1 07/20/2015:50 07/20/2015:50 MJA Mt. Juliet, TN Wet Chemistry by Method 9056A WG1510095 1 07/17/20 01:25 07/17/20 01:25 ELN Mt. Juliet, TN Wet Chemistry by Method 9060A WG1510700 1 07/17/2016:22 07/17/2016:22 VRP Mt. Juliet, TN Metals (ICP) by Method 6010D WG1510364 1 07/19/20 23:32 07/20/2014:10 EL Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1511373 1 07/18/2016:55 07/18/2016:55 ADM Mt. Juliet, TN Collected by Collected date/time Received date/time MW-31D L1240114-04 GW Laura Elliott 07/15/2011:40 07/16/20 08:45 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Wet Chemistry by Method 2320 B-2011 WG1511471 1 07/22/2018:01 07/22/2018:01 DGR Mt. Juliet, TN Wet Chemistry by Method 4500S2 D-2011 WG1511994 1 07/20/2015:50 07/20/2015:50 MJA Mt. Juliet, TN Wet Chemistry by Method 9056A WG1510095 1 07/17/20 01:42 07/17/20 01:42 ELN Mt. Juliet, TN Wet Chemistry by Method 9060A WG1510700 1 07/17/2017:31 07/17/2017:31 VRP Mt. Juliet, TN Metals (ICP) by Method 6010D WG1510364 1 07/19/20 23:32 07/20/2014:12 EL Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1511373 1 07/18/2017:17 07/18/2017:17 ADM Mt. Juliet, TN Collected by Collected date/time Received date/time MW-4 L1240114-05 GW Laura Elliott 07/15/2012:00 07/16/20 08:45 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Wet Chemistry by Method 2320 B-2011 WG1511471 1 07/22/2018:08 07/22/2018:08 DGR Mt. Juliet, TN Wet Chemistry by Method 4500S2 D-2011 WG1511994 1 07/20/2015:51 07/20/2015:51 MJA Mt. Juliet, TN Wet Chemistry by Method 9056A WG1510095 1 07/17/20 02:17 07/17/20 02:17 ELN Mt. Juliet, TN Wet Chemistry by Method 9060A WG1510700 1 07/17/2018:18 07/17/2018:18 VRP Mt. Juliet, TN Metals (ICP) by Method 6010D WG1510364 1 07/19/20 23:32 07/20/2014:20 EL Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1511373 1 07/18/2017:38 07/18/2017:38 ADM Mt. Juliet, TN ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 3 of 48 SAMPLE SUMMARY ONE LAB. NATIONWIDE. Collected by Collected date/time Received date/time MW-5 L1240114-06 GW Laura Elliott 07/15/2010:30 07/16/20 08:45 FP1 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time FTC Metals (ICP) by Method 6010D WG1510364 1 07/19/20 23:32 07/20/2014:23 EL Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1511373 1 07/18/2018:00 07/18/2018:00 ADM Mt. Juliet, TN Collected by Collected date/time Received date/time MW-6 L1240114-07 GW Laura Elliott 07/15/20 09:45 07/16/20 08:45 4 n Method Batch Dilution Preparation Analysis Analyst Location date/time FSrdate/time Wet Chemistry by Method 2320 B-2011 WG1511471 1 07/22/2018:15 07/22/2018:15 DGR Mt. Juliet, TN Wet Chemistry by Method 4500S2 D-2011 WG1511994 1 07/20/2015:51 07/20/2015:51 MJA Mt. Juliet, TN FC] Wet Chemistry by Method 9056A WG1510095 1 07/17/20 02:34 07/17/20 02:34 ELN Mt. Juliet, TN Wet Chemistry by Method 9060A WG1510700 1 07/17/2018:32 07/17/2018:32 VRP Mt. Juliet, TN Metals (ICP) by Method 6010D WG1510364 1 07/19/20 23:32 07/20/2014:26 EL Mt. Juliet, TN G� Volatile Organic Compounds (GC/MS) by Method 8260D WG1511373 1 07/18/2018:21 07/18/2018:21 ADM Mt. Juliet, TN $A� Collected by Collected date/time Received date/time SW-1 L1240114-08 GW Laura Elliott 07/15/2012:30 07/16/20 08:45 FSC Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Metals (ICP) by Method 6010D WG1510364 1 07/19/20 23:32 07/20/2014:28 EL Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1511373 1 07/18/2018:43 07/18/2018:43 ADM Mt. Juliet, TN Collected by Collected date/time Received date/time SW-2 L1240114-09 GW Laura Elliott 07/15/2012:10 07/16/20 08:45 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Metals (ICP) by Method 6010D WG1510364 1 07/19/20 23:32 07/20/2014:31 EL Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1511373 1 07/18/2019:04 07/18/2019:04 ADM Mt. Juliet, TN Collected by Collected date/time Received date/time SW-3 L1240114-10 GW Laura Elliott 07/15/2012:25 07/16/20 08:45 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Metals (ICP) by Method 6010D WG1510364 1 07/19/20 23:32 07/20/2014:34 EL Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1511373 1 07/18/2019:25 07/18/2019:25 ADM Mt. Juliet, TN Collected by Collected date/time Received date/time DUP-1 L1240114-11 GW Laura Elliott 07/15/2011:45 07/16/20 08:45 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Wet Chemistry by Method 2320 B-2011 Wet Chemistry by Method 4500S2 D-2011 Wet Chemistry by Method 9056A Wet Chemistry by Method 9060A Metals (ICP) by Method 6010D Volatile Organic Compounds (GC/MS) by Method 8260D WG1511471 1 07/22/2018:21 07/22/2018:21 DGR Mt. Juliet, TN WG1511994 1 07/20/2015:51 07/20/2015:51 MJA Mt. Juliet, TN WG1510095 1 07/17/20 03:44 07/17/20 03:44 ELN Mt. Juliet, TN WG1510700 1 07/17/2018:45 07/17/2018:45 VRP Mt. Juliet, TN WG1510364 1 07/19/20 23:32 07/20/2014:37 EL Mt. Juliet, TN WG1511373 1 07/18/2019:46 07/18/2019:46 ADM Mt. Juliet, TN ACCOUNT: Withers & Ravenel Eng. - Standard PROJECT: SDG: DATE/TIME: PAGE: 06140180.24 L1240114 07/23/20 15:35 4 of 48 CASE NARRATIVE ONE LAB. NATIONWIDE. FP1 All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples FTChave been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my FSS knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. FSr FC-1 4�j �GI Heather J Wagner FAI Project Manager FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 5 of 48 TRIP BLANK SAMPLE RESULTS - 01 ONE LAB. NATIONWIDE. Collected date/time: 07/15/20 00:00 L1240114 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Acetone U 11.3 50.0 1 07/18/202015:08 WG1511373 Acrolein U J4 2.54 50.0 1 07/18/202015:08 WG1511373 Acrylonitrile U 0.671 10.0 1 07/18/202015:08 WG1511373 Benzene U 0.0941 1.00 1 07/18/202015:08 WG1511373 Bromobenzene U 0.118 1.00 1 07/18/202015:08 WG1511373 Bromodichloromethane U 0.136 1.00 1 07/18/202015:08 WG1511373 Bromoform U 0.129 1.00 1 07/18/202015:08 WG1511373 Bromomethane U 0.605 5.00 1 07/18/202015:08 WG1511373 n-Butylbenzene U 0.157 1.00 1 07/18/202015:08 WG1511373 sec -Butyl benzene U 0.125 1.00 1 07/18/202015:08 WG1511373 ter[-Butylbenzene U 0.127 1.00 1 07/18/202015:08 WG1511373 Carbon tetrachloride U 0.128 1.00 1 07/18/202015:08 WG1511373 Chlorobenzene U 0.116 1.00 1 07/18/202015:08 WG1511373 Chlorodibromomethane U 0.140 1.00 1 07/18/202015:08 WG1511373 Chloroethane U 0.192 5.00 1 07/18/202015:08 WG1511373 Chloroform U 0.111 5.00 1 07/18/202015:08 WG1511373 Chloromethane U 0.960 2.50 1 07/18/202015:08 WG1511373 2-Chlorotoluene U 0.106 1.00 1 07/18/202015:08 WG1511373 4-Chlorotoluene U 0.114 1.00 1 07/18/202015:08 WG1511373 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/18/202015:08 WG1511373 1,2-Dibromoethane U 0.126 1.00 1 07/18/202015:08 WG1511373 Dibromomethane U 0.122 1.00 1 07/18/202015:08 WG1511373 1,2-Dichlorobenzene U 0.107 1.00 1 07/18/202015:08 WG1511373 1,3-Dichlorobenzene U 0.110 1.00 1 07/18/202015:08 WG1511373 1,4-Dichlorobenzene U 0.120 1.00 1 07/18/202015:08 WG1511373 DichIorodifluoromethane U 0.374 5.00 1 07/18/202015:08 WG1511373 1,1-Dichloroethane U 0.100 1.00 1 07/18/202015:08 WG1511373 1,2-Dichloroethane U 0.0819 1.00 1 07/18/202015:08 WG1511373 1,1-Dichloroethene U 0.188 1.00 1 07/18/202015:08 WG1511373 cis-1,2-Dichloroethene U 0.126 1.00 1 07/18/202015:08 WG1511373 trans-1,2-Dichloroethene U 0.149 1.00 1 07/18/202015:08 WG1511373 1,2-Dichloropropane U 0.149 1.00 1 07/18/202015:08 WG1511373 1,1-Dichloropropene U 0.142 1.00 1 07/18/202015:08 WG1511373 1,3-Dichloropropane U 0.110 1.00 1 07/18/202015:08 WG1511373 cis-1,3-Dichloropropene U 0.111 1.00 1 07/18/202015:08 WG1511373 trans-1,3-Dichloropropene U 0.118 1.00 1 07/18/202015:08 WG1511373 2,2-Dichloropropane U 0.161 1.00 1 07/18/202015:08 WG1511373 Di -isopropyl ether U 0.105 1.00 1 07/18/202015:08 WG1511373 Ethylbenzene U 0.137 1.00 1 07/18/202015:08 WG1511373 Hexachloro-1,3-butadiene U 0.337 1.00 1 07/18/202015:08 WG1511373 Isopropylbenzene U 0.105 1.00 1 07/18/202015:08 WG1511373 p-Isopropyltoluene U 0.120 1.00 1 07/18/202015:08 WG1511373 2-Butanone (MEK) U 1.19 10.0 1 07/18/202015:08 WG1511373 Methylene Chloride U 0.430 5.00 1 07/18/202015:08 WG1511373 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 1 07/18/202015:08 WG1511373 Methyl tert-butyl ether U 0.101 1.00 1 07/18/202015:08 WG1511373 Naphthalene U 1.00 5.00 1 07/18/202015:08 WG1511373 n-Propylbenzene U 0.0993 1.00 1 07/18/202015:08 WG1511373 Styrene U 0.118 1.00 1 07/18/202015:08 WG1511373 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 07/18/202015:08 WG1511373 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 07/18/202015:08 WG1511373 1,1,2-Trichlorotrifluoroethane U 0.180 1.00 1 07/18/202015:08 WG1511373 Tetrachloroethene U 0.300 1.00 1 07/18/202015:08 WG1511373 Toluene U 0.278 1.00 1 07/18/202015:08 WG1511373 1,23-Trichlorobenzene U 0.230 1.00 1 07/18/202015:08 WG1511373 1,2,4-Trichlorobenzene U 0.481 1.00 1 07/18/202015:08 WG1511373 FP1 FTc FSS 4 Cn FC] F q, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 6 of 48 ONE LAB. NATIONWIDE. TRIP BLANK SAMPLE RESULTS - 01 Collected date/time: 07/15/20 00:00 L1240114 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Analyte ug/I ug/I ug/I date / time 1,1,1-Trichloroethane U 0.149 1.00 1 07/18/202015:08 1,1,2-Trichloroethane U 0.158 1.00 1 07/18/202015:08 Trichloroethene U 0.190 1.00 1 07/18/202015:08 Trichlorofluoromethane U 0.160 5.00 1 07/18/202015:08 1,2,3-Trichloropropane U 0.237 2.50 1 07/18/202015:08 1,2,4-Trimethylbenzene J 0.322 1.00 1 07/18/202015:08 1,2,3-Trimethyl benzene U 0.104 1.00 1 07/18/202015:08 1,3,5-Trimethyl benzene J 0.104 1.00 1 07/18/202015:08 Vinyl chloride U 0.234 1.00 1 07/18/202015:08 Xylenes, Total J 0.174 3.00 1 07/18/202015:08 (S) Toluene-d8 98.6 80.0-120 071181202015:08 (S) 4-Bromof/uorobenzene 96.7 77.0-126 071181202015:08 (S)1,2-Dich/oroethane-d4 90.6 70.0-130 071181202015:08 ACCOUNT: PROJECT: SDG: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 Batch WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 Fp FTc FS Fn Fc F, FAI FSC DATE/TIME: PAGE: 07/23/20 15:35 7 of 48 MW-2 SAMPLE RESULTS - 02 Collected date/time: 07/15/20 11:30 L1240114 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL Analyte ug/I ug/I Alkalinity 132000 8450 Sample Narrative: L1240114-02 WG1511471: Endpoint pH 4.5 headspace Wet Chemistry by Method 4500S2 D-2011 RDL Dilution Analysis Batch ug/I date / time 20000 1 07/22/202017:47 WG1511471 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Sulfide U Wet Chemistry by Method 9056A 25.0 50.0 1 07/20/202015:49 WG1511994 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Chloride 11400 379 1000 1 07/17/2020 01:07 WG1510095 Nitrate 59.1 J 48.0 100 1 07/17/2020 01:07 WG1510095 Sulfate U 594 5000 1 07/17/2020 01:07 WG1510095 Wet Chemistry by Method 9060A ONE LAB. NATIONWIDE. FP1 FTc FSS [Cn] N Rc F FAI FSC Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time TOC (Total Organic Carbon) 813 B J 102 1000 1 07/17/202015:57 WG1510700 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Antimony U 4.30 10.0 1 07/20/202014:07 WG1510364 Arsenic U 4.40 10.0 1 07/20/202014:07 WG1510364 Barium 234 0.895 5.00 1 07/20/202014:07 WG1510364 Beryllium U 0.460 2.00 1 07/20/202014:07 WG1510364 Cadmium U 0.563 2.00 1 07/20/202014:07 WG1510364 Chromium U 5.00 10.0 1 07/20/202014:07 WG1510364 Cobalt 1.11 J 0.807 10.0 1 07/20/202014:07 WG1510364 Copper U 4.69 10.0 1 07/20/202014:07 WG1510364 Lead U 2.95 6.00 1 07/20/202014:07 WG1510364 Nickel U 2.98 10.0 1 07/20/202014:07 WG1510364 Selenium U 7.35 10.0 1 07/20/202014:07 WG1510364 Silver U 1.91 5.00 1 07/20/202014:07 WG1510364 Thallium U 4.31 10.0 1 07/20/202014:07 WG1510364 Vanadium U 6.34 20.0 1 07/20/202014:07 WG1510364 Zinc 19.4 J 9.16 50.0 1 07/20/202014:07 WG1510364 Volatile Organic Compounds (GC/MS) by Method 8260D Result Analyte ug/I Acetone U Acrolein U Acrylonitrile U Benzene 3.81 Bromobenzene U Bromodichloromethane U Bromoform U Bromomethane U n-Butylbenzene U ACCOUNT: Withers & Ravenel Eng. - Standard Qualifier MDL RDL ug/I ug/I 11.3 50.0 J4 2.54 50.0 0.671 10.0 0.0941 1.00 0.118 1.00 0.136 1.00 0.129 1.00 0.605 5.00 0.157 1.00 PROJECT: 06140180.24 Dilution Analysis Batch date / time 1 07/18/202016:34 WG1511373 1 07/18/202016:34 WG1511373 1 07/18/202016:34 WG1511373 1 07/18/202016:34 WG1511373 1 07/18/202016:34 WG1511373 1 07/18/202016:34 WG1511373 1 07/18/202016:34 WG1511373 1 07/18/202016:34 WG1511373 1 07/18/202016:34 WG1511373 SDG: DATE/TIME: PAGE: L1240114 07/23/20 15:35 8 of 48 ONE LAB. NATIONWIDE. MW-2 SAMPLE RESULTS - 02 Collected date/time: 07/15/20 11:30 L1240114 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time sec -Butyl benzene U 0.125 1.00 1 07/18/202016:34 WG1511373 tert-Butylbenzene U 0.127 1.00 1 07/18/202016:34 WG1511373 Carbon tetrachloride U 0.128 1.00 1 07/18/202016:34 WG1511373 Chlorobenzene U 0.116 1.00 1 07/18/202016:34 WG1511373 Chlorodibromomethane U 0.140 1.00 1 07/18/202016:34 WG1511373 Chloroethane U 0.192 5.00 1 07/18/202016:34 WG1511373 Chloroform U 0.111 5.00 1 07/18/202016:34 WG1511373 Chloromethane U 0.960 2.50 1 07/18/202016:34 WG1511373 2-Chlorotoluene U 0.106 1.00 1 07/18/202016:34 WG1511373 4-Chlorotoluene U 0.114 1.00 1 07/18/202016:34 WG1511373 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/18/202016:34 WG1511373 1,2-Dibromoethane U 0.126 1.00 1 07/18/202016:34 WG1511373 Dibromomethane U 0.122 1.00 1 07/18/202016:34 WG1511373 1,2-Dichlorobenzene 0.189 J 0.107 1.00 1 07/18/202016:34 WG1511373 1,3-Dichlorobenzene U 0.110 1.00 1 07/18/202016:34 WG1511373 1,4-Dichlorobenzene 4.88 0.120 1.00 1 07/18/202016:34 WG1511373 Dichlorodifluoromethane U 0.374 5.00 1 07/18/202016:34 WG1511373 1,1-Dichloroethane 12.0 0.100 1.00 1 07/18/202016:34 WG1511373 1,2-Dichloroethane 0.622 1_ 0.0819 1.00 1 07/18/202016:34 WG1511373 1,1-Dichloroethene U 0.188 1.00 1 07/18/202016:34 WG1511373 cis-1,2-Dichloroethene 32.5 0.126 1.00 1 07/18/202016:34 WG1511373 trans-1,2-Dichloroethene 1.02 0.149 1.00 1 07/18/202016:34 WG1511373 1,2-Dichloropropane 4.46 0.149 1.00 1 07/18/202016:34 WG1511373 1,1-Dichloropropene U 0.142 1.00 1 07/18/202016:34 WG1511373 1,3-Dichloropropane U 0.110 1.00 1 07/18/202016:34 WG1511373 cis-1,3-Dichloropropene U 0.111 1.00 1 07/18/202016:34 WG1511373 trans-1,3-Dichloropropene U 0.118 1.00 1 07/18/202016:34 WG1511373 2,2-Dichloropropane U 0.161 1.00 1 07/18/202016:34 WG1511373 Di -isopropyl ether 0.269 J_ 0.105 1.00 1 07/18/202016:34 WG1511373 Ethylbenzene U 0.137 1.00 1 07/18/202016:34 WG1511373 Hexachloro-1,3-butadiene U 0.337 1.00 1 07/18/202016:34 WG1511373 Isopropylbenzene 0.216 J 0.105 1.00 1 07/18/202016:34 WG1511373 p-Isopropyltoluene U 0.120 1.00 1 07/18/202016:34 WG1511373 2-Butanone (MEK) U 1.19 10.0 1 07/18/202016:34 WG1511373 Methylene Chloride U 0.430 5.00 1 07/18/202016:34 WG1511373 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 1 07/18/202016:34 WG1511373 Methyl tert-butyl ether 0.340 J_ 0.101 1.00 1 07/18/202016:34 WG1511373 Naphthalene U 1.00 5.00 1 07/18/202016:34 WG1511373 n-Propylbenzene U 0.0993 1.00 1 07/18/2020 16:34 WG1511373 Styrene U 0.118 1.00 1 07/18/202016:34 WG1511373 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 07/18/202016:34 WG1511373 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 07/18/202016:34 WG1511373 1,1,2-Trichlorotrifluoroethane U 0.180 1.00 1 07/18/202016:34 WG1511373 Tetrachloroethene 0.507 J 0.300 1.00 1 07/18/202016:34 WG1511373 Toluene U 0.278 1.00 1 07/18/202016:34 WG1511373 1,2,3-Trichlorobenzene U 0.230 1.00 1 07/18/202016:34 WG1511373 1,2,4-Trichlorobenzene U 0.481 1.00 1 07/18/202016:34 WG1511373 1,1,1-Trichloroethane U 0.149 1.00 1 07/18/202016:34 WG1511373 1,1,2-Trichloroethane U 0.158 1.00 1 07/18/202016:34 WG1511373 Trichloroethene 2.09 0.190 1.00 1 07/18/202016:34 WG1511373 Trichlorofluoromethane U 0.160 5.00 1 07/18/202016:34 WG1511373 1,2,3-Trichloropropane U 0.237 2.50 1 07/18/202016:34 WG1511373 1,2,4-Trimethylbenzene U 0.322 1.00 1 07/18/202016:34 WG1511373 1,2,3-Trimethyl benzene 0.141 J 0.104 1.00 1 07/21/2020 23:27 WG1512594 1,3,5-Trimethyl benzene U 0.104 1.00 1 07/18/202016:34 WG1511373 Vinyl chloride 4.17 0.234 1.00 1 07/18/202016:34 WG1511373 FP1 FTc FSS 4 Cn Fc F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 9 of 48 MW-2 SAMPLE RESULTS - 02 Collected date/time: 07/15/20 11:30 L1240114 Volatile Organic Compounds (GC/MS) by Method 8260D ONE LAB. NATIONWIDE. Analyte Result Qualifier MDL ug/I ug/I RDL ug/I Dilution Analysis date / time Batch Xylenes, Total U 0.174 3.00 1 07/18/202016:34 WG1511373 (S) Toluene-d8 99.7 80.0-120 07118120201634 WG1511373 (S)Toluene-d8 104 80.0-120 071211202023.27 WG1512594 (S) 4-Bromofluorobenzene 98.8 77.0-126 071181202016:34 WG1511373 (S)4-Bromofluorobenzene 104 77.0-126 071211202023.27 WG1512594 (S)1,2-Dich/oroethone-d4 90.1 70.0-130 07118120201634 WG1511373 (S)1,2-Dich/oroethone-d4 98.3 70.0-130 071211202023.27 WG1512594 Cp FTc FSS 4 Cn Fc F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 PAGE: 10 of 48 MW-3S SAMPLE RESULTS - 03 Collected date/time: 07/15/20 10:30 L1240114 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL Analyte ug/I ug/I Alkalinity 159000 8450 Sample Narrative: L1240114-03 WG1511471: Endpoint pH 4.5 headspace Wet Chemistry by Method 4500S2 D-2011 RDL Dilution Analysis Batch ug/I date / time 20000 1 07/22/202017:54 WG1511471 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Sulfide U J6 Wet Chemistry by Method 9056A 25.0 50.0 1 07/20/202015:50 WG1511994 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Chloride 34900 379 1000 1 07/17/2020 01:25 WG1510095 Nitrate U 48.0 100 1 07/17/2020 01:25 WG1510095 Sulfate U 594 5000 1 07/17/2020 01:25 WG1510095 Wet Chemistry by Method 9060A ONE LAB. NATIONWIDE. FP1 FTc FSS [Cn] Rc F FAI FSC Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time TOC (Total Organic Carbon) 2020 B 102 1000 1 07/17/202016:22 WG1510700 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Antimony U 4.30 10.0 1 07/20/202014:10 WG1510364 Arsenic U 4.40 10.0 1 07/20/202014:10 WG1510364 Barium 121 0.895 5.00 1 07/20/202014:10 WG1510364 Beryllium U 0.460 2.00 1 07/20/202014:10 WG1510364 Cadmium U 0.563 2.00 1 07/20/202014:10 WG1510364 Chromium U 5.00 10.0 1 07/20/202014:10 WG1510364 Cobalt 8.10 J 0.807 10.0 1 07/20/202014:10 WG1510364 Copper U 4.69 10.0 1 07/20/202014:10 WG1510364 Lead U 2.95 6.00 1 07/20/202014:10 WG1510364 Nickel 3.82 J 2.98 10.0 1 07/20/202014:10 WG1510364 Selenium U 7.35 10.0 1 07/20/202014:10 WG1510364 Silver U 1.91 5.00 1 07/20/202014:10 WG1510364 Thallium U 4.31 10.0 1 07/20/202014:10 WG1510364 Vanadium U 6.34 20.0 1 07/20/202014:10 WG1510364 Zinc 37.9 J 9.16 50.0 1 07/20/202014:10 WG1510364 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Analyte ug/I ug/I ug/I Acetone U 11.3 50.0 Acrolein U J4 2.54 50.0 Acrylonitrile U 0.671 10.0 Benzene 0.366 J 0.0941 1.00 Bromobenzene U 0.118 1.00 Bromodichloromethane U 0.136 1.00 Bromoform U 0.129 1.00 Bromomethane U 0.605 5.00 n-Butylbenzene U 0.157 1.00 ACCOUNT: PROJECT: Withers & Ravenel Eng. - Standard 06140180.24 Dilution Analysis Batch date / time 1 07/18/202016:55 WG1511373 1 07/18/202016:55 WG1511373 1 07/18/202016:55 WG1511373 1 07/18/202016:55 WG1511373 1 07/18/202016:55 WG1511373 1 07/18/202016:55 WG1511373 1 07/18/202016:55 WG1511373 1 07/18/202016:55 WG1511373 1 07/18/202016:55 WG1511373 SDG: DATE/TIME: PAGE: L1240114 07/23/20 15:35 11 of 48 ONE LAB. NATIONWIDE. MW-3S SAMPLE RESULTS - 03 Collected date/time: 07/15/20 10:30 L1240114 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time sec -Butyl benzene U 0.125 1.00 1 07/18/202016:55 WG1511373 tert-Butylbenzene U 0.127 1.00 1 07/18/202016:55 WG1511373 Carbon tetrachloride U 0.128 1.00 1 07/18/202016:55 WG1511373 Chlorobenzene 1.82 0.116 1.00 1 07/18/202016:55 WG1511373 Chlorodibromomethane U 0.140 1.00 1 07/18/202016:55 WG1511373 Chloroethane U 0.192 5.00 1 07/18/202016:55 WG1511373 Chloroform U 0.111 5.00 1 07/18/202016:55 WG1511373 Chloromethane U 0.960 2.50 1 07/18/202016:55 WG1511373 2-Chlorotoluene U 0.106 1.00 1 07/18/202016:55 WG1511373 4-Chlorotoluene U 0.114 1.00 1 07/18/202016:55 WG1511373 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/18/202016:55 WG1511373 1,2-Dibromoethane U 0.126 1.00 1 07/18/202016:55 WG1511373 Dibromomethane U 0.122 1.00 1 07/18/202016:55 WG1511373 1,2-Dichlorobenzene U 0.107 1.00 1 07/18/202016:55 WG1511373 1,3-Dichlorobenzene U 0.110 1.00 1 07/18/202016:55 WG1511373 1,4-Dichlorobenzene 1.65 0.120 1.00 1 07/18/202016:55 WG1511373 Dichlorodifluoromethane U 0.374 5.00 1 07/18/202016:55 WG1511373 1,1-Dichloroethane 0.528 J 0.100 1.00 1 07/18/202016:55 WG1511373 1,2-Dichloroethane 0.259 1_ 0.0819 1.00 1 07/18/202016:55 WG1511373 1,1-Dichloroethene U 0.188 1.00 1 07/18/202016:55 WG1511373 cis-1,2-Dichloroethene 2.52 0.126 1.00 1 07/18/202016:55 WG1511373 trans-1,2-Dichloroethene U 0.149 1.00 1 07/18/202016:55 WG1511373 1,2-Dichloropropane U 0.149 1.00 1 07/18/202016:55 WG1511373 1,1-Dichloropropene U 0.142 1.00 1 07/18/202016:55 WG1511373 1,3-Dichloropropane U 0.110 1.00 1 07/18/202016:55 WG1511373 cis-1,3-Dichloropropene U 0.111 1.00 1 07/18/202016:55 WG1511373 trans-1,3-Dichloropropene U 0.118 1.00 1 07/18/202016:55 WG1511373 2,2-Dichloropropane U 0.161 1.00 1 07/18/202016:55 WG1511373 Di -isopropyl ether U 0.105 1.00 1 07/18/202016:55 WG1511373 Ethylbenzene U 0.137 1.00 1 07/18/202016:55 WG1511373 Hexachloro-1,3-butadiene U 0.337 1.00 1 07/18/202016:55 WG1511373 Isopropylbenzene U 0.105 1.00 1 07/18/202016:55 WG1511373 p-Isopropyltoluene U 0.120 1.00 1 07/18/202016:55 WG1511373 2-Butanone (MEK) U 1.19 10.0 1 07/18/202016:55 WG1511373 Methylene Chloride U 0.430 5.00 1 07/18/202016:55 WG1511373 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 1 07/18/202016:55 WG1511373 Methyl tert-butyl ether 0.168 J_ 0.101 1.00 1 07/18/202016:55 WG1511373 Naphthalene U 1.00 5.00 1 07/18/202016:55 WG1511373 n-Propylbenzene U 0.0993 1.00 1 07/18/2020 16:55 WG1511373 Styrene U 0.118 1.00 1 07/18/202016:55 WG1511373 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 07/18/202016:55 WG1511373 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 07/18/202016:55 WG1511373 1,1,2-Trichlorotrifluoroethane U 0.180 1.00 1 07/18/202016:55 WG1511373 Tetrachloroethene U 0.300 1.00 1 07/18/202016:55 WG1511373 Toluene U 0.278 1.00 1 07/18/202016:55 WG1511373 1,2,3-Trichlorobenzene U 0.230 1.00 1 07/18/202016:55 WG1511373 1,2,4-Trichlorobenzene U 0.481 1.00 1 07/18/202016:55 WG1511373 1,1,1-Trichloroethane U 0.149 1.00 1 07/18/202016:55 WG1511373 1,1,2-Trichloroethane U 0.158 1.00 1 07/18/202016:55 WG1511373 Trichloroethene U 0.190 1.00 1 07/18/202016:55 WG1511373 Trichlorofluoromethane U 0.160 5.00 1 07/18/202016:55 WG1511373 1,2,3-Trichloropropane U 0.237 2.50 1 07/18/202016:55 WG1511373 1,2,4-Trimethylbenzene U 0.322 1.00 1 07/18/202016:55 WG1511373 1,2,3-Trimethyl benzene U 0.104 1.00 1 07/18/202016:55 WG1511373 1,3,5-Trimethyl benzene U 0.104 1.00 1 07/18/202016:55 WG1511373 Vinyl chloride 1.85 0.234 1.00 1 07/18/202016:55 WG1511373 FP1 FTc FSS 4 Cn Fc F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 12 of 48 MW-3S SAMPLE RESULTS - 03 Collected date/time: 07/15/20 10:30 L1240114 Volatile Organic Compounds (GC/MS) by Method 8260D ONE LAB. NATIONWIDE. Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Xylenes, Total U 0.174 3.00 1 07/18/202016:55 WG1511373 (S) Toluene-d8 99.4 80.0-120 071181202016:55 WG1511373 (S) 4-Bromof/uorobenzene 96.2 77.0-126 071181202016:55 WG1511373 (S)1,2-Dich/oroethone-d4 93.4 70.0-130 071181202016:55 WG1511373 Cp FTc FSS 4 Cn Fc F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 PAGE: 13 of 48 MW-3D SAMPLE RESULTS - 04 Collected date/time: 07/15/20 11:40 L1240114 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL Analyte ug/I ug/I Alkalinity 164000 8450 Sample Narrative: L1240114-04 WG1511471: Endpoint pH 4.5 headspace Wet Chemistry by Method 4500S2 D-2011 RDL Dilution Analysis Batch ug/I date / time 20000 1 07/22/202018:01 WG1511471 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Sulfide U Wet Chemistry by Method 9056A 25.0 50.0 1 07/20/202015:50 WG1511994 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Chloride 21900 379 1000 1 07/17/2020 01:42 WG1510095 Nitrate U 48.0 100 1 07/17/2020 01:42 WG1510095 Sulfate U 594 5000 1 07/17/2020 01:42 WG1510095 Wet Chemistry by Method 9060A ONE LAB. NATIONWIDE. FP1 FTc FSS [Cn] N Rc F FAI FSC Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time TOC (Total Organic Carbon) 1010 B 102 1000 1 07/17/202017:31 WG1510700 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Antimony U 4.30 10.0 1 07/20/202014:12 WG1510364 Arsenic U 4.40 10.0 1 07/20/202014:12 WG1510364 Barium 45.9 0.895 5.00 1 07/20/202014:12 WG1510364 Beryllium U 0.460 2.00 1 07/20/202014:12 WG1510364 Cadmium U 0.563 2.00 1 07/20/202014:12 WG1510364 Chromium U 5.00 10.0 1 07/20/202014:12 WG1510364 Cobalt U 0.807 10.0 1 07/20/202014:12 WG1510364 Copper U 4.69 10.0 1 07/20/202014:12 WG1510364 Lead U 2.95 6.00 1 07/20/202014:12 WG1510364 Nickel U 2.98 10.0 1 07/20/202014:12 WG1510364 Selenium U 7.35 10.0 1 07/20/202014:12 WG1510364 Silver U 1.91 5.00 1 07/20/202014:12 WG1510364 Thallium U 4.31 10.0 1 07/20/202014:12 WG1510364 Vanadium U 6.34 20.0 1 07/20/202014:12 WG1510364 Zinc 26.3 J 9.16 50.0 1 07/20/202014:12 WG1510364 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Analyte ug/I ug/I ug/I Acetone U 11.3 50.0 Acrolein U J4 2.54 50.0 Acrylonitrile U 0.671 10.0 Benzene 0.708 J 0.0941 1.00 Bromobenzene U 0.118 1.00 Bromodichloromethane U 0.136 1.00 Bromoform U 0.129 1.00 Bromomethane U 0.605 5.00 n-Butylbenzene U 0.157 1.00 ACCOUNT: PROJECT: Withers & Ravenel Eng. - Standard 06140180.24 Dilution Analysis Batch date / time 1 07/18/202017:17 WG1511373 1 07/18/202017:17 WG1511373 1 07/18/202017:17 WG1511373 1 07/18/202017:17 WG1511373 1 07/18/202017:17 WG1511373 1 07/18/202017:17 WG1511373 1 07/18/202017:17 WG1511373 1 07/18/202017:17 WG1511373 1 07/18/202017:17 WG1511373 SDG: DATE/TIME: PAGE: L1240114 07/23/20 15:35 14 of 48 ONE LAB. NATIONWIDE. MW-3D SAMPLE RESULTS - 04 Collected date/time: 07/15/20 11:40 L1240114 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time sec -Butyl benzene U 0.125 1.00 1 07/18/202017:17 WG1511373 tert-Butylbenzene U 0.127 1.00 1 07/18/202017:17 WG1511373 Carbon tetrachloride U 0.128 1.00 1 07/18/202017:17 WG1511373 Chlorobenzene 1.16 0.116 1.00 1 07/18/202017:17 WG1511373 Chlorodibromomethane U 0.140 1.00 1 07/18/202017:17 WG1511373 Chloroethane U 0.192 5.00 1 07/18/202017:17 WG1511373 Chloroform U 0.111 5.00 1 07/18/202017:17 WG1511373 Chloromethane U 0.960 2.50 1 07/18/202017:17 WG1511373 2-Chlorotoluene U 0.106 1.00 1 07/18/202017:17 WG1511373 4-Chlorotoluene U 0.114 1.00 1 07/18/202017:17 WG1511373 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/18/202017:17 WG1511373 1,2-Dibromoethane U 0.126 1.00 1 07/18/202017:17 WG1511373 Dibromomethane U 0.122 1.00 1 07/18/202017:17 WG1511373 1,2-Dichlorobenzene 0.151 J 0.107 1.00 1 07/18/202017:17 WG1511373 1,3-Dichlorobenzene U 0.110 1.00 1 07/18/202017:17 WG1511373 1,4-Dichlorobenzene 4.77 0.120 1.00 1 07/18/202017:17 WG1511373 Dichlorodifluoromethane U 0.374 5.00 1 07/18/202017:17 WG1511373 1,1-Dichloroethane 1.76 0.100 1.00 1 07/18/202017:17 WG1511373 1,2-Dichloroethane 0.711 1_ 0.0819 1.00 1 07/18/202017:17 WG1511373 1,1-Dichloroethene U 0.188 1.00 1 07/18/202017:17 WG1511373 cis-1,2-Dichloroethene 16.5 0.126 1.00 1 07/18/202017:17 WG1511373 trans-1,2-Dichloroethene U 0.149 1.00 1 07/18/202017:17 WG1511373 1,2-Dichloropropane 1.11 0.149 1.00 1 07/18/202017:17 WG1511373 1,1-Dichloropropene U 0.142 1.00 1 07/18/202017:17 WG1511373 1,3-Dichloropropane U 0.110 1.00 1 07/18/202017:17 WG1511373 cis-1,3-Dichloropropene U 0.111 1.00 1 07/18/202017:17 WG1511373 trans-1,3-Dichloropropene U 0.118 1.00 1 07/18/202017:17 WG1511373 2,2-Dichloropropane U 0.161 1.00 1 07/18/202017:17 WG1511373 Di -isopropyl ether U 0.105 1.00 1 07/18/202017:17 WG1511373 Ethylbenzene U 0.137 1.00 1 07/18/202017:17 WG1511373 Hexachloro-1,3-butadiene U 0.337 1.00 1 07/18/202017:17 WG1511373 Isopropylbenzene U 0.105 1.00 1 07/18/202017:17 WG1511373 p-Isopropyltoluene U 0.120 1.00 1 07/18/202017:17 WG1511373 2-Butanone (MEK) U 1.19 10.0 1 07/18/202017:17 WG1511373 Methylene Chloride U 0.430 5.00 1 07/18/202017:17 WG1511373 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 1 07/18/202017:17 WG1511373 Methyl tert-butyl ether 0.350 J_ 0.101 1.00 1 07/18/202017:17 WG1511373 Naphthalene U 1.00 5.00 1 07/18/202017:17 WG1511373 n-Propylbenzene U 0.0993 1.00 1 07/18/202017:17 WG1511373 Styrene U 0.118 1.00 1 07/18/202017:17 WG1511373 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 07/18/202017:17 WG1511373 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 07/18/202017:17 WG1511373 1,1,2-Trichlorotrifluoroethane U 0.180 1.00 1 07/18/202017:17 WG1511373 Tetrachloroethene U 0.300 1.00 1 07/18/202017:17 WG1511373 Toluene U 0.278 1.00 1 07/18/202017:17 WG1511373 1,2,3-Trichlorobenzene U 0.230 1.00 1 07/18/202017:17 WG1511373 1,2,4-Trichlorobenzene U 0.481 1.00 1 07/18/202017:17 WG1511373 1,1,1-Trichloroethane U 0.149 1.00 1 07/18/202017:17 WG1511373 1,1,2-Trichloroethane U 0.158 1.00 1 07/18/202017:17 WG1511373 Trichloroethene U 0.190 1.00 1 07/18/202017:17 WG1511373 Trichlorofluoromethane U 0.160 5.00 1 07/18/202017:17 WG1511373 1,2,3-Trichloropropane U 0.237 2.50 1 07/18/202017:17 WG1511373 1,2,4-Trimethylbenzene U 0.322 1.00 1 07/18/202017:17 WG1511373 1,2,3-Trimethyl benzene U 0.104 1.00 1 07/18/202017:17 WG1511373 1,3,5-Trimethyl benzene U 0.104 1.00 1 07/18/202017:17 WG1511373 Vinyl chloride 10.2 0.234 1.00 1 07/18/202017:17 WG1511373 FP1 FTc FSS 4 Cn Fc F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 15 of 48 MW-3D SAMPLE RESULTS - 04 Collected date/time: 07/15/20 11:40 L1240114 Volatile Organic Compounds (GC/MS) by Method 8260D ONE LAB. NATIONWIDE. Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Xylenes, Total U 0.174 3.00 1 07/18/202017:17 WG1511373 (S Toluene-d8 96.8 80.0-120 071181202017-17 WG1511373 (S 4-Bromof/uorobenzene 101 77.0-126 071181202017.-17 WG1511373 (S 1,2-Dich/oroethone-d4 94.1 70.0-130 071181202017-17 WG1511373 Cp FTc FSS 4 Cn Fc F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 PAGE: 16 of 48 MW-4 SAMPLE RESULTS - 05 Collected date/time: 07/15/20 12:00 L1240114 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL Analyte ug/I ug/I Alkalinity 177000 8450 Sample Narrative: L1240114-05 WG1511471: Endpoint pH 4.5 headspace Wet Chemistry by Method 4500S2 D-2011 RDL Dilution Analysis Batch ug/I date / time 20000 1 07/22/202018:08 WG1511471 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Sulfide U Wet Chemistry by Method 9056A 25.0 50.0 1 07/20/202015:51 WG1511994 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Chloride 19100 379 1000 1 07/17/2020 02:17 WG1510095 Nitrate U 48.0 100 1 07/17/2020 02:17 WG1510095 Sulfate U 594 5000 1 07/17/2020 02:17 WG1510095 Wet Chemistry by Method 9060A ONE LAB. NATIONWIDE. FP1 FTc FSS [Cn] N Rc F FAI FSC Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time TOC (Total Organic Carbon) 854 B J 102 1000 1 07/17/202018:18 WG1510700 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Antimony U 4.30 10.0 1 07/20/202014:20 WG1510364 Arsenic U 4.40 10.0 1 07/20/202014:20 WG1510364 Barium 94.2 0.895 5.00 1 07/20/202014:20 WG1510364 Beryllium U 0.460 2.00 1 07/20/202014:20 WG1510364 Cadmium 0.630 J 0.563 2.00 1 07/20/202014:20 WG1510364 Chromium U 5.00 10.0 1 07/20/202014:20 WG1510364 Cobalt 1.82 J 0.807 10.0 1 07/20/202014:20 WG1510364 Copper U 4.69 10.0 1 07/20/202014:20 WG1510364 Lead U 2.95 6.00 1 07/20/202014:20 WG1510364 Nickel 4.06 J 2.98 10.0 1 07/20/202014:20 WG1510364 Selenium U 7.35 10.0 1 07/20/202014:20 WG1510364 Silver U 1.91 5.00 1 07/20/202014:20 WG1510364 Thallium 4.66 J 4.31 10.0 1 07/20/202014:20 WG1510364 Vanadium U 6.34 20.0 1 07/20/202014:20 WG1510364 Zinc 22.6 J 9.16 50.0 1 07/20/202014:20 WG1510364 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Analyte ug/I ug/I ug/I Acetone U 11.3 50.0 Acrolein U J4 2.54 50.0 Acrylonitrile U 0.671 10.0 Benzene 0.402 J 0.0941 1.00 Bromobenzene U 0.118 1.00 Bromodichloromethane U 0.136 1.00 Bromoform U 0.129 1.00 Bromomethane U 0.605 5.00 n-Butylbenzene U 0.157 1.00 ACCOUNT: PROJECT: Withers & Ravenel Eng. - Standard 06140180.24 Dilution Analysis Batch date / time 1 07/18/202017:38 WG1511373 1 07/18/202017:38 WG1511373 1 07/18/202017:38 WG1511373 1 07/18/202017:38 WG1511373 1 07/18/202017:38 WG1511373 1 07/18/202017:38 WG1511373 1 07/18/202017:38 WG1511373 1 07/18/202017:38 WG1511373 1 07/18/202017:38 WG1511373 SDG: DATE/TIME: PAGE: L1240114 07/23/20 15:35 17 of 48 ONE LAB. NATIONWIDE. MW-4 SAMPLE RESULTS - 05 Collected date/time: 07/15/20 12:00 L1240114 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time sec -Butyl benzene U 0.125 1.00 1 07/18/202017:38 WG1511373 tert-Butylbenzene U 0.127 1.00 1 07/18/202017:38 WG1511373 Carbon tetrachloride U 0.128 1.00 1 07/18/202017:38 WG1511373 Chlorobenzene 0.198 J 0.116 1.00 1 07/18/202017:38 WG1511373 Chlorodibromomethane U 0.140 1.00 1 07/18/202017:38 WG1511373 Chloroethane U 0.192 5.00 1 07/18/202017:38 WG1511373 Chloroform U 0.111 5.00 1 07/18/202017:38 WG1511373 Chloromethane U 0.960 2.50 1 07/18/202017:38 WG1511373 2-Chlorotoluene U 0.106 1.00 1 07/18/202017:38 WG1511373 4-Chlorotoluene U 0.114 1.00 1 07/18/202017:38 WG1511373 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/18/202017:38 WG1511373 1,2-Dibromoethane U 0.126 1.00 1 07/18/202017:38 WG1511373 Dibromomethane U 0.122 1.00 1 07/18/202017:38 WG1511373 1,2-Dichlorobenzene 0.117 J 0.107 1.00 1 07/18/202017:38 WG1511373 1,3-Dichlorobenzene U 0.110 1.00 1 07/18/202017:38 WG1511373 1,4-Dichlorobenzene 2.46 0.120 1.00 1 07/18/202017:38 WG1511373 Dichlorodifluoromethane U 0.374 5.00 1 07/18/202017:38 WG1511373 1,1-Dichloroethane 1.39 0.100 1.00 1 07/18/202017:38 WG1511373 1,2-Dichloroethane U 0.0819 1.00 1 07/18/202017:38 WG1511373 1,1-Dichloroethene U 0.188 1.00 1 07/18/202017:38 WG1511373 cis-1,2-Dichloroethene 15.9 0.126 1.00 1 07/18/202017:38 WG1511373 trans-1,2-Dichloroethene U 0.149 1.00 1 07/18/202017:38 WG1511373 1,2-Dichloropropane U 0.149 1.00 1 07/18/202017:38 WG1511373 1,1-Dichloropropene U 0.142 1.00 1 07/18/202017:38 WG1511373 1,3-Dichloropropane U 0.110 1.00 1 07/18/202017:38 WG1511373 cis-1,3-Dichloropropene U 0.111 1.00 1 07/18/202017:38 WG1511373 trans-1,3-Dichloropropene U 0.118 1.00 1 07/18/202017:38 WG1511373 2,2-Dichloropropane U 0.161 1.00 1 07/18/202017:38 WG1511373 Di -isopropyl ether U 0.105 1.00 1 07/18/202017:38 WG1511373 Ethylbenzene U 0.137 1.00 1 07/18/202017:38 WG1511373 Hexachloro-1,3-butadiene U 0.337 1.00 1 07/18/202017:38 WG1511373 Isopropylbenzene U 0.105 1.00 1 07/18/202017:38 WG1511373 p-Isopropyltoluene U 0.120 1.00 1 07/18/202017:38 WG1511373 2-Butanone (MEK) U 1.19 10.0 1 07/18/202017:38 WG1511373 Methylene Chloride U 0.430 5.00 1 07/18/202017:38 WG1511373 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 1 07/18/202017:38 WG1511373 Methyl tert-butyl ether 0.224 J_ 0.101 1.00 1 07/18/202017:38 WG1511373 Naphthalene U 1.00 5.00 1 07/18/202017:38 WG1511373 n-Propylbenzene U 0.0993 1.00 1 07/18/2020 17:38 WG1511373 Styrene U 0.118 1.00 1 07/18/202017:38 WG1511373 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 07/18/202017:38 WG1511373 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 07/18/202017:38 WG1511373 1,1,2-Trichlorotrifluoroethane U 0.180 1.00 1 07/18/202017:38 WG1511373 Tetrachloroethene U 0.300 1.00 1 07/18/202017:38 WG1511373 Toluene U 0.278 1.00 1 07/18/202017:38 WG1511373 1,2,3-Trichlorobenzene U 0.230 1.00 1 07/18/202017:38 WG1511373 1,2,4-Trichlorobenzene U 0.481 1.00 1 07/18/202017:38 WG1511373 1,1,1-Trichloroethane U 0.149 1.00 1 07/18/202017:38 WG1511373 1,1,2-Trichloroethane U 0.158 1.00 1 07/18/202017:38 WG1511373 Trichloroethene U 0.190 1.00 1 07/18/202017:38 WG1511373 Trichlorofluoromethane U 0.160 5.00 1 07/18/202017:38 WG1511373 1,2,3-Trichloropropane U 0.237 2.50 1 07/18/202017:38 WG1511373 1,2,4-Trimethylbenzene U 0.322 1.00 1 07/18/202017:38 WG1511373 1,2,3-Trimethyl benzene U 0.104 1.00 1 07/18/202017:38 WG1511373 1,3,5-Trimethyl benzene U 0.104 1.00 1 07/18/202017:38 WG1511373 Vinyl chloride 10.4 0.234 1.00 1 07/18/202017:38 WG1511373 FP1 FTc FSS 4 Cn Fc F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 18 of 48 MW-4 SAMPLE RESULTS - 05 Collected date/time: 07/15/20 12:00 L1240114 Volatile Organic Compounds (GC/MS) by Method 8260D ONE LAB. NATIONWIDE. Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Xylenes, Total U 0.174 3.00 1 07/18/202017:38 WG1511373 (S) Toluene-d8 98.6 80.0-120 071181202017.38 WG1511373 (S) 4-Bromof/uorobenzene 95.6 77.0-126 071181202017.38 WG1511373 (S)1,2-Dich/oroethone-d4 94.4 70.0-130 071181202017.38 WG1511373 Cp FTc FSS 4 Cn Fc F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 PAGE: 19 of 48 M W - 5 SAMPLE RESULTS - 06 ONE LAB. NATIONWIDE. Collected date/time: 07/15/20 10:30 L1240114 Metals (ICP) by Method 6010D FP1 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date /time Antimony U 4.30 10.0 1 07/20/202014:23 WG1510364 FTc Arsenic 6.92 J 4.40 10.0 1 07/20/202014:23 WG1510364 Barium 231 0.895 5.00 1 07/20/202014:23 WG1510364 F Beryllium 2.26 0.460 2.00 1 07/20/202014:23 WG1510364 Cadmium U 0.563 2.00 1 07/20/202014:23 WG1510364 Chromium 5.81 J 5.00 10.0 1 07/20/202014:23 WG1510364 4 Cfl Cobalt 17.4 0.807 10.0 1 07/20/202014:23 WG1510364 Copper 22.9 4.69 10.0 1 07/20/202014:23 WG1510364 Lead 78.9 2.95 6.00 1 07/20/202014:23 WG1510364 Nickel 4.99 J 2.98 10.0 1 07/20/202014:23 WG1510364 Selenium U 7.35 10.0 1 07/20/202014:23 WG1510364 6 QC Silver U 1.91 5.00 1 07/20/202014:23 WG1510364 Thallium U 4.31 10.0 1 07/20/202014:23 WG1510364 �GI Vanadium 91.3 6.34 20.0 1 07/20/202014:23 WG1510364 Zinc 114 9.16 50.0 1 07/20/202014:23 WG1510364 rAl Volatile Organic Compounds (GC/MS) by Method 8260D Qualifier MDL RDL Dilution Analysis Batch FSCResult Analyte ug/I ug/I ug/I date / time Acetone U 11.3 50.0 1 07/18/202018:00 WG1511373 Acrolein U J4 2.54 50.0 1 07/18/202018:00 WG1511373 Acrylonitrile U 0.671 10.0 1 07/18/202018:00 WG1511373 Benzene U 0.0941 1.00 1 07/18/202018:00 WG1511373 Bromobenzene U 0.118 1.00 1 07/18/202018:00 WG1511373 Bromodichloromethane U 0.136 1.00 1 07/18/202018:00 WG1511373 Bromoform U 0.129 1.00 1 07/18/202018:00 WG1511373 Bromomethane U 0.605 5.00 1 07/18/202018:00 WG1511373 n-Butylbenzene U 0.157 1.00 1 07/18/202018:00 WG1511373 sec -Butyl benzene U 0.125 1.00 1 07/18/202018:00 WG1511373 ter[-Butylbenzene U 0.127 1.00 1 07/18/202018:00 WG1511373 Carbon tetrachloride U 0.128 1.00 1 07/18/202018:00 WG1511373 Chlorobenzene U 0.116 1.00 1 07/18/202018:00 WG1511373 Chlorodibromomethane U 0.140 1.00 1 07/18/202018:00 WG1511373 Chloroethane U 0.192 5.00 1 07/18/202018:00 WG1511373 Chloroform U 0.111 5.00 1 07/18/202018:00 WG1511373 Chloromethane U 0.960 2.50 1 07/18/202018:00 WG1511373 2-Chlorotoluene U 0.106 1.00 1 07/18/202018:00 WG1511373 4-Chlorotoluene U 0.114 1.00 1 07/18/202018:00 WG1511373 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/18/202018:00 WG1511373 1,2-Dibromoethane U 0.126 1.00 1 07/18/202018:00 WG1511373 Dibromomethane U 0.122 1.00 1 07/18/202018:00 WG1511373 1,2-Dichlorobenzene U 0.107 1.00 1 07/18/202018:00 WG1511373 1,3-Dichlorobenzene U 0.110 1.00 1 07/18/202018:00 WG1511373 1,4-Dichlorobenzene U 0.120 1.00 1 07/18/202018:00 WG1511373 DichIorodifluoromethane U 0.374 5.00 1 07/18/202018:00 WG1511373 1,1-Dichloroethane U 0.100 1.00 1 07/18/202018:00 WG1511373 1,2-Dichloroethane U 0.0819 1.00 1 07/18/202018:00 WG1511373 1,1-Dichloroethene U 0.188 1.00 1 07/18/202018:00 WG1511373 cis-1,2-Dichloroethene U 0.126 1.00 1 07/18/202018:00 WG1511373 trans-1,2-Dichloroethene U 0.149 1.00 1 07/18/202018:00 WG1511373 1,2-Dichloropropane U 0.149 1.00 1 07/18/202018:00 WG1511373 1,1-Dichloropropene U 0.142 1.00 1 07/18/202018:00 WG1511373 1,3-Dichloropropane U 0.110 1.00 1 07/18/202018:00 WG1511373 cis-1,3-Dichloropropene U 0.111 1.00 1 07/18/202018:00 WG1511373 trans-1,3-Dichloropropene U 0.118 1.00 1 07/18/202018:00 WG1511373 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 20 of 48 ONE LAB. NATIONWIDE. MW-5 SAMPLE RESULTS - 06 Collected date/time: 07/15/20 10:30 L1240114 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result ug/I 2,2-Dichloropropane U Di -isopropyl ether U Ethylbenzene U Hexachloro-1,3-butadiene U Isopropylbenzene U p-Isopropyltoluene U 2-Butanone (MEK) U Methylene Chloride U 4-Methyl-2-pentanone (MIBK) U Methyl tert-butyl ether U Naphthalene U n-Propylbenzene U Styrene U 1,1,1,2-Tetrachloroethane U 1,1,2,2-Tetrachloroethane U 1,1,2-Trichlorotrifluoroethane U Tetrachloroethene U Toluene U 1,2,3-Trichlorobenzene U 1,2,4-Trichlorobenzene U 1,1,1-Trichloroethane U 1,1,2-Trichloroethane U Trichloroethene U Trichlorofluoromethane U 1,2,3-Trichloropropane U 1,2,4-Trimethylbenzene U 1,2,3-Trimethyl benzene U 1,3,5-Trimethyl benzene U Vinyl chloride U Xylenes, Total U (S) Toluene-d8 100 (S) 4-Bromof/uorobenzene 98.8 (S) 1,2-Dich/oroethane-d4 94.6 Qualifier MDL RDL Dilution Analysis Batch ug/I ug/I date / time 0.161 1.00 1 07/18/202018:00 WG1511373 0.105 1.00 1 07/18/202018:00 WG1511373 0.137 1.00 1 07/18/202018:00 WG1511373 0.337 1.00 1 07/18/202018:00 WG1511373 0.105 1.00 1 07/18/202018:00 WG1511373 0.120 1.00 1 07/18/202018:00 WG1511373 1.19 10.0 1 07/18/202018:00 WG1511373 0.430 5.00 1 07/18/202018:00 WG1511373 0.478 10.0 1 07/18/2020 18:00 WG1511373 0.101 1.00 1 07/18/202018:00 WG1511373 1.00 5.00 1 07/18/202018:00 WG1511373 0.0993 1.00 1 07/18/202018:00 WG1511373 0.118 1.00 1 07/18/202018:00 WG1511373 0.147 1.00 1 07/18/202018:00 WG1511373 0.133 1.00 1 07/18/202018:00 WG1511373 0.180 1.00 1 07/18/202018:00 WG1511373 0.300 1.00 1 07/18/202018:00 WG1511373 0.278 1.00 1 07/18/202018:00 WG1511373 0.230 1.00 1 07/18/202018:00 WG1511373 0.481 1.00 1 07/18/202018:00 WG1511373 0.149 1.00 1 07/18/202018:00 WG1511373 0.158 1.00 1 07/18/202018:00 WG1511373 0.190 1.00 1 07/18/202018:00 WG1511373 0.160 5.00 1 07/18/202018:00 WG1511373 0.237 2.50 1 07/18/202018:00 WG1511373 0.322 1.00 1 07/18/202018:00 WG1511373 0.104 1.00 1 07/18/202018:00 WG1511373 0.104 1.00 1 07/18/202018:00 WG1511373 0.234 1.00 1 07/18/202018:00 WG1511373 0.174 3.00 1 07/18/202018:00 WG1511373 80.0-120 071181202018:00 WG1511373 77.0-126 071181202018:00 WG1511373 70.0-130 071181202018:00 WG1511373 Fp FTc FS Fn N FC] F ql FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 21 of 48 MW-6 SAMPLE RESULTS - 07 Collected date/time: 07/15/20 09:45 L1240114 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL Analyte ug/I ug/I Alkalinity 11700 J 8450 Sample Narrative: L1240114-07 WG1511471: Endpoint pH 4.5 headspace Wet Chemistry by Method 4500S2 D-2011 RDL Dilution Analysis Batch ug/I date / time 20000 1 07/22/202018:15 WG1511471 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Sulfide U Wet Chemistry by Method 9056A 25.0 50.0 1 07/20/202015:51 WG1511994 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Chloride 1700 379 1000 1 07/17/2020 02:34 WG1510095 Nitrate U 48.0 100 1 07/17/2020 02:34 WG1510095 Sulfate 3670 J 594 5000 1 07/17/2020 02:34 WG1510095 Wet Chemistry by Method 9060A ONE LAB. NATIONWIDE. FP1 FTc FSS [Cn] N Rc F FAI FSC Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time TOC (Total Organic Carbon) 2450 B 102 1000 1 07/17/202018:32 WG1510700 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Antimony U 4.30 10.0 1 07/20/202014:26 WG1510364 Arsenic U 4.40 10.0 1 07/20/202014:26 WG1510364 Barium 84.4 0.895 5.00 1 07/20/202014:26 WG1510364 Beryllium U 0.460 2.00 1 07/20/202014:26 WG1510364 Cadmium U 0.563 2.00 1 07/20/202014:26 WG1510364 Chromium U 5.00 10.0 1 07/20/202014:26 WG1510364 Cobalt 0.999 J 0.807 10.0 1 07/20/202014:26 WG1510364 Copper U 4.69 10.0 1 07/20/202014:26 WG1510364 Lead 7.57 2.95 6.00 1 07/20/202014:26 WG1510364 Nickel U 2.98 10.0 1 07/20/202014:26 WG1510364 Selenium U 7.35 10.0 1 07/20/202014:26 WG1510364 Silver U 1.91 5.00 1 07/20/202014:26 WG1510364 Thallium U 4.31 10.0 1 07/20/202014:26 WG1510364 Vanadium U 6.34 20.0 1 07/20/202014:26 WG1510364 Zinc 18.3 J 9.16 50.0 1 07/20/202014:26 WG1510364 Volatile Organic Compounds (GC/MS) by Method 8260D Result Analyte ug/I Acetone U Acrolein U Acrylonitrile U Benzene U Bromobenzene U Bromodichloromethane U Bromoform U Bromomethane U n-Butylbenzene U ACCOUNT: Withers & Ravenel Eng. - Standard Qualifier MDL RDL ug/I ug/I 11.3 50.0 J4 2.54 50.0 0.671 10.0 0.0941 1.00 0.118 1.00 0.136 1.00 0.129 1.00 0.605 5.00 0.157 1.00 PROJECT: 06140180.24 Dilution Analysis Batch date / time 1 07/18/202018:21 WG1511373 1 07/18/202018:21 WG1511373 1 07/18/202018:21 WG1511373 1 07/18/202018:21 WG1511373 1 07/18/202018:21 WG1511373 1 07/18/202018:21 WG1511373 1 07/18/202018:21 WG1511373 1 07/18/202018:21 WG1511373 1 07/18/202018:21 WG1511373 SDG: DATE/TIME: PAGE: L1240114 07/23/20 15:35 22 of 48 ONE LAB. NATIONWIDE. MW-6 SAMPLE RESULTS - 07 Collected date/time: 07/15/20 09:45 L1240114 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time sec -Butyl benzene U 0.125 1.00 1 07/18/202018:21 WG1511373 tert-Butylbenzene U 0.127 1.00 1 07/18/202018:21 WG1511373 Carbon tetrachloride U 0.128 1.00 1 07/18/202018:21 WG1511373 Chlorobenzene U 0.116 1.00 1 07/18/202018:21 WG1511373 Chlorodibromomethane U 0.140 1.00 1 07/18/202018:21 WG1511373 Chloroethane U 0.192 5.00 1 07/18/202018:21 WG1511373 Chloroform U 0.111 5.00 1 07/18/202018:21 WG1511373 Chloromethane U 0.960 2.50 1 07/18/202018:21 WG1511373 2-Chlorotoluene U 0.106 1.00 1 07/18/202018:21 WG1511373 4-Chlorotoluene U 0.114 1.00 1 07/18/202018:21 WG1511373 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/18/202018:21 WG1511373 1,2-Dibromoethane U 0.126 1.00 1 07/18/202018:21 WG1511373 Dibromomethane U 0.122 1.00 1 07/18/202018:21 WG1511373 1,2-Dichlorobenzene U 0.107 1.00 1 07/18/202018:21 WG1511373 1,3-Dichlorobenzene U 0.110 1.00 1 07/18/202018:21 WG1511373 1,4-Dichlorobenzene U 0.120 1.00 1 07/18/202018:21 WG1511373 Dichlorodifluoromethane U 0.374 5.00 1 07/18/202018:21 WG1511373 1,1-Dichloroethane U 0.100 1.00 1 07/18/202018:21 WG1511373 1,2-Dichloroethane U 0.0819 1.00 1 07/18/202018:21 WG1511373 1,1-Dichloroethene U 0.188 1.00 1 07/18/202018:21 WG1511373 cis-1,2-Dichloroethene U 0.126 1.00 1 07/18/202018:21 WG1511373 trans-1,2-Dichloroethene U 0.149 1.00 1 07/18/202018:21 WG1511373 1,2-Dichloropropane U 0.149 1.00 1 07/18/202018:21 WG1511373 1,1-Dichloropropene U 0.142 1.00 1 07/18/202018:21 WG1511373 1,3-Dichloropropane U 0.110 1.00 1 07/18/202018:21 WG1511373 cis-1,3-Dichloropropene U 0.111 1.00 1 07/18/202018:21 WG1511373 trans-1,3-Dichloropropene U 0.118 1.00 1 07/18/202018:21 WG1511373 2,2-Dichloropropane U 0.161 1.00 1 07/18/202018:21 WG1511373 Di -isopropyl ether U 0.105 1.00 1 07/18/202018:21 WG1511373 Ethylbenzene U 0.137 1.00 1 07/18/202018:21 WG1511373 Hexachloro-1,3-butadiene U 0.337 1.00 1 07/18/202018:21 WG1511373 Isopropylbenzene U 0.105 1.00 1 07/18/202018:21 WG1511373 p-Isopropyltoluene U 0.120 1.00 1 07/18/202018:21 WG1511373 2-Butanone (MEK) U 1.19 10.0 1 07/18/202018:21 WG1511373 Methylene Chloride U 0.430 5.00 1 07/18/202018:21 WG1511373 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 1 07/18/202018:21 WG1511373 Methyl tert-butyl ether U 0.101 1.00 1 07/18/202018:21 WG1511373 Naphthalene U 1.00 5.00 1 07/18/202018:21 WG1511373 n-Propylbenzene U 0.0993 1.00 1 07/18/2020 18:21 WG1511373 Styrene U 0.118 1.00 1 07/18/202018:21 WG1511373 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 07/18/202018:21 WG1511373 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 07/18/202018:21 WG1511373 1,1,2-Trichlorotrifluoroethane U 0.180 1.00 1 07/18/202018:21 WG1511373 Tetrachloroethene U 0.300 1.00 1 07/18/202018:21 WG1511373 Toluene U 0.278 1.00 1 07/18/202018:21 WG1511373 1,2,3-Trichlorobenzene U 0.230 1.00 1 07/18/202018:21 WG1511373 1,2,4-Trichlorobenzene U 0.481 1.00 1 07/18/202018:21 WG1511373 1,1,1-Trichloroethane U 0.149 1.00 1 07/18/202018:21 WG1511373 1,1,2-Trichloroethane U 0.158 1.00 1 07/18/202018:21 WG1511373 Trichloroethene U 0.190 1.00 1 07/18/202018:21 WG1511373 Trichlorofluoromethane U 0.160 5.00 1 07/18/202018:21 WG1511373 1,2,3-Trichloropropane U 0.237 2.50 1 07/18/202018:21 WG1511373 1,2,4-Trimethylbenzene U 0.322 1.00 1 07/18/202018:21 WG1511373 1,2,3-Trimethyl benzene U 0.104 1.00 1 07/18/202018:21 WG1511373 1,3,5-Trimethyl benzene U 0.104 1.00 1 07/18/202018:21 WG1511373 Vinyl chloride U 0.234 1.00 1 07/18/202018:21 WG1511373 FP1 FTc FSS 4 Cn Fc F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 23 of 48 MW-6 SAMPLE RESULTS - 07 Collected date/time: 07/15/20 09:45 L1240114 Volatile Organic Compounds (GC/MS) by Method 8260D ONE LAB. NATIONWIDE. Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Xylenes, Total U 0.174 3.00 1 07/18/202018:21 WG1511373 (S) Toluene-d8 99.3 80.0-120 071181202018.21 WG1511373 (S) 4-Bromof/uorobenzene 97.2 77.0-126 071181202018.21 WG1511373 (S)1,2-Dich/oroethone-d4 99.2 70.0-130 071181202018.21 WG1511373 Cp FTc FSS 4 Cn Fc F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 PAGE: 24 of 48 SW-1 SAMPLE RESULTS - 08 ONE LAB. NATIONWIDE. Collected date/time: 07/15/20 12:30 L1240114 Metals (ICP) by Method 6010D FP1 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date /time Antimony U 4.30 10.0 1 07/20/202014:28 WG1510364 FTc Arsenic U 4.40 10.0 1 07/20/202014:28 WG1510364 Barium 44.2 0.895 5.00 1 07/20/202014:28 WG1510364 F Beryllium U 0.460 2.00 1 07/20/202014:28 WG1510364 Cadmium U 0.563 2.00 1 07/20/202014:28 WG1510364 Chromium U 5.00 10.0 1 07/20/202014:28 WG1510364 4 Cfl Cobalt 1.45 J 0.807 10.0 1 07/20/202014:28 WG1510364 Copper U 4.69 10.0 1 07/20/202014:28 WG1510364 Lead 5.68 J 2.95 6.00 1 07/20/202014:28 WG1510364 Nickel U 2.98 10.0 1 07/20/202014:28 WG1510364 Selenium U 7.35 10.0 1 07/20/202014:28 WG1510364 6 QC Silver U 1.91 5.00 1 07/20/202014:28 WG1510364 Thallium U 4.31 10.0 1 07/20/202014:28 WG1510364 �GI Vanadium U 6.34 20.0 1 07/20/202014:28 WG1510364 Zinc 19.7 J 9.16 50.0 1 07/20/202014:28 WG1510364 rAl Volatile Organic Compounds (GC/MS) by Method 8260D Qualifier MDL RDL Dilution Analysis Batch FSCResult Analyte ug/I ug/I ug/I date / time Acetone U 11.3 50.0 1 07/18/202018:43 WG1511373 Acrolein U J4 2.54 50.0 1 07/18/202018:43 WG1511373 Acrylonitrile U 0.671 10.0 1 07/18/202018:43 WG1511373 Benzene U 0.0941 1.00 1 07/18/202018:43 WG1511373 Bromobenzene U 0.118 1.00 1 07/18/202018:43 WG1511373 Bromodichloromethane U 0.136 1.00 1 07/18/202018:43 WG1511373 Bromoform U 0.129 1.00 1 07/18/202018:43 WG1511373 Bromomethane U 0.605 5.00 1 07/18/202018:43 WG1511373 n-Butylbenzene U 0.157 1.00 1 07/18/202018:43 WG1511373 sec -Butyl benzene U 0.125 1.00 1 07/18/202018:43 WG1511373 ter[-Butylbenzene U 0.127 1.00 1 07/18/202018:43 WG1511373 Carbon tetrachloride U 0.128 1.00 1 07/18/202018:43 WG1511373 Chlorobenzene U 0.116 1.00 1 07/18/202018:43 WG1511373 Chlorodibromomethane U 0.140 1.00 1 07/18/202018:43 WG1511373 Chloroethane U 0.192 5.00 1 07/18/202018:43 WG1511373 Chloroform U 0.111 5.00 1 07/18/202018:43 WG1511373 Chloromethane U 0.960 2.50 1 07/18/202018:43 WG1511373 2-Chlorotoluene U 0.106 1.00 1 07/18/202018:43 WG1511373 4-Chlorotoluene U 0.114 1.00 1 07/18/202018:43 WG1511373 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/18/202018:43 WG1511373 1,2-Dibromoethane U 0.126 1.00 1 07/18/202018:43 WG1511373 Dibromomethane U 0.122 1.00 1 07/18/202018:43 WG1511373 1,2-Dichlorobenzene U 0.107 1.00 1 07/18/202018:43 WG1511373 1,3-Dichlorobenzene U 0.110 1.00 1 07/18/202018:43 WG1511373 1,4-Dichlorobenzene U 0.120 1.00 1 07/18/202018:43 WG1511373 DichIorodifluoromethane U 0.374 5.00 1 07/18/202018:43 WG1511373 1,1-Dichloroethane U 0.100 1.00 1 07/18/202018:43 WG1511373 1,2-Dichloroethane U 0.0819 1.00 1 07/18/202018:43 WG1511373 1,1-Dichloroethene U 0.188 1.00 1 07/18/202018:43 WG1511373 cis-1,2-Dichloroethene U 0.126 1.00 1 07/18/202018:43 WG1511373 trans-1,2-Dichloroethene U 0.149 1.00 1 07/18/202018:43 WG1511373 1,2-Dichloropropane U 0.149 1.00 1 07/18/202018:43 WG1511373 1,1-Dichloropropene U 0.142 1.00 1 07/18/202018:43 WG1511373 1,3-Dichloropropane U 0.110 1.00 1 07/18/202018:43 WG1511373 cis-1,3-Dichloropropene U 0.111 1.00 1 07/18/202018:43 WG1511373 trans-1,3-Dichloropropene U 0.118 1.00 1 07/18/202018:43 WG1511373 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 25 of 48 ONE LAB. NATIONWIDE. SW-1 SAMPLE RESULTS - 08 Collected date/time: 07/15/20 12:30 L1240114 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte 2,2-Dichloropropane Di -isopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene p-Isopropyltoluene 2-Butanone (MEK) Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrach I oroeth a n e 1,1,2,2-Tetrachloroetha ne 1,1,2-Trichlorotrifluoroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-T ri c h l o ro eth a n e 1,1,2-Trich I oroetha n e Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Tri methyl benzen e 1,2,3-Trimethyl benzene 1,3,5-Trimethyl benzene Vinyl chloride Xylenes, Total (S) Toluene-d8 (S) 4-Bromof/uorobenzene (S) 1,2-Dich/oroethane-d4 Result Qualifier MDL RDL Dilution Analysis ug/I ug/I ug/I date / time U 0.161 1.00 1 07/18/202018:43 U 0.105 1.00 1 07/18/202018:43 U 0.137 1.00 1 07/18/202018:43 U 0.337 1.00 1 07/18/202018:43 U 0.105 1.00 1 07/18/202018:43 U 0.120 1.00 1 07/18/202018:43 U 1.19 10.0 1 07/18/202018:43 U 0.430 5.00 1 07/18/202018:43 U 0.478 10.0 1 07/18/202018:43 U 0.101 1.00 1 07/18/202018:43 U 1.00 5.00 1 07/18/202018:43 U 0.0993 1.00 1 07/18/202018:43 U 0.118 1.00 1 07/18/202018:43 U 0.147 1.00 1 07/18/202018:43 U 0.133 1.00 1 07/18/202018:43 U 0.180 1.00 1 07/18/202018:43 U 0.300 1.00 1 07/18/202018:43 U 0.278 1.00 1 07/18/202018:43 U 0.230 1.00 1 07/18/202018:43 U 0.481 1.00 1 07/18/202018:43 U 0.149 1.00 1 07/18/202018:43 U 0.158 1.00 1 07/18/202018:43 U 0.190 1.00 1 07/18/202018:43 U 0.160 5.00 1 07/18/202018:43 U 0.237 2.50 1 07/18/202018:43 U 0.322 1.00 1 07/18/202018:43 U 0.104 1.00 1 07/18/202018:43 U 0.104 1.00 1 07/18/202018:43 U 0.234 1.00 1 07/18/202018:43 U 0.174 3.00 1 07/18/202018:43 97.0 80.0-120 071181202018.43 94.6 77.0-126 071181202018.43 95.1 70.0-130 071181202018.43 Batch WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 Fp FTc FS Fn FC] F FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 26 of 48 SW-2 SAMPLE RESULTS - 09 ONE LAB. NATIONWIDE. Collected date/time: 07/15/20 12:10 L1240114 Metals (ICP) by Method 6010D FP1 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date /time Antimony U 4.30 10.0 1 07/20/202014:31 WG1510364 FTc Arsenic U 4.40 10.0 1 07/20/202014:31 WG1510364 Barium 38.7 0.895 5.00 1 07/20/202014:31 WG1510364 F Beryllium U 0.460 2.00 1 07/20/202014:31 WG1510364 Cadmium U 0.563 2.00 1 07/20/202014:31 WG1510364 Chromium U 5.00 10.0 1 07/20/202014:31 WG1510364 4 Cfl Cobalt 0.974 J 0.807 10.0 1 07/20/202014:31 WG1510364 Copper U 4.69 10.0 1 07/20/202014:31 WG1510364 Lead U 2.95 6.00 1 07/20/202014:31 WG1510364 Nickel U 2.98 10.0 1 07/20/202014:31 WG1510364 Selenium U 7.35 10.0 1 07/20/202014:31 WG1510364 6 QC Silver U 1.91 5.00 1 07/20/202014:31 WG1510364 Thallium U 4.31 10.0 1 07/20/202014:31 WG1510364 �GI Vanadium U 6.34 20.0 1 07/20/202014:31 WG1510364 Zinc 15.8 J 9.16 50.0 1 07/20/202014:31 WG1510364 rAl Volatile Organic Compounds (GC/MS) by Method 8260D Qualifier MDL RDL Dilution Analysis Batch FSCResult Analyte ug/I ug/I ug/I date / time Acetone U 11.3 50.0 1 07/18/202019:04 WG1511373 Acrolein U J4 2.54 50.0 1 07/18/202019:04 WG1511373 Acrylonitrile U 0.671 10.0 1 07/18/202019:04 WG1511373 Benzene U 0.0941 1.00 1 07/18/202019:04 WG1511373 Bromobenzene U 0.118 1.00 1 07/18/202019:04 WG1511373 Bromodichloromethane U 0.136 1.00 1 07/18/202019:04 WG1511373 Bromoform U 0.129 1.00 1 07/18/202019:04 WG1511373 Bromomethane U 0.605 5.00 1 07/18/202019:04 WG1511373 n-Butylbenzene U 0.157 1.00 1 07/18/202019:04 WG1511373 sec -Butyl benzene U 0.125 1.00 1 07/18/202019:04 WG1511373 ter[-Butylbenzene U 0.127 1.00 1 07/18/202019:04 WG1511373 Carbon tetrachloride U 0.128 1.00 1 07/18/202019:04 WG1511373 Chlorobenzene U 0.116 1.00 1 07/18/202019:04 WG1511373 Chlorodibromomethane U 0.140 1.00 1 07/18/202019:04 WG1511373 Chloroethane U 0.192 5.00 1 07/18/202019:04 WG1511373 Chloroform U 0.111 5.00 1 07/18/202019:04 WG1511373 Chloromethane U 0.960 2.50 1 07/18/202019:04 WG1511373 2-Chlorotoluene U 0.106 1.00 1 07/18/202019:04 WG1511373 4-Chlorotoluene U 0.114 1.00 1 07/18/202019:04 WG1511373 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/18/202019:04 WG1511373 1,2-Dibromoethane U 0.126 1.00 1 07/18/202019:04 WG1511373 Dibromomethane U 0.122 1.00 1 07/18/202019:04 WG1511373 1,2-Dichlorobenzene U 0.107 1.00 1 07/18/202019:04 WG1511373 1,3-Dichlorobenzene U 0.110 1.00 1 07/18/202019:04 WG1511373 1,4-Dichlorobenzene U 0.120 1.00 1 07/18/202019:04 WG1511373 DichIorodifluoromethane U 0.374 5.00 1 07/18/202019:04 WG1511373 1,1-Dichloroethane U 0.100 1.00 1 07/18/202019:04 WG1511373 1,2-Dichloroethane U 0.0819 1.00 1 07/18/202019:04 WG1511373 1,1-Dichloroethene U 0.188 1.00 1 07/18/202019:04 WG1511373 cis-1,2-Dichloroethene 0.164 J 0.126 1.00 1 07/18/202019:04 WG1511373 trans-1,2-Dichloroethene U 0.149 1.00 1 07/18/202019:04 WG1511373 1,2-Dichloropropane U 0.149 1.00 1 07/18/202019:04 WG1511373 1,1-Dichloropropene U 0.142 1.00 1 07/18/202019:04 WG1511373 1,3-Dichloropropane U 0.110 1.00 1 07/18/202019:04 WG1511373 cis-1,3-Dichloropropene U 0.111 1.00 1 07/18/202019:04 WG1511373 trans-1,3-Dichloropropene U 0.118 1.00 1 07/18/202019:04 WG1511373 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 27 of 48 ONE LAB. NATIONWIDE. SW-2 SAMPLE RESULTS - 09 Collected date/time: 07/15/20 12:10 L1240114 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result ug/I 2,2-Dichloropropane U Di -isopropyl ether U Ethylbenzene U Hexachloro-1,3-butadiene U Isopropylbenzene U p-Isopropyltoluene U 2-Butanone (MEK) U Methylene Chloride U 4-Methyl-2-pentanone (MIBK) U Methyl tert-butyl ether U Naphthalene U n-Propylbenzene U Styrene U 1,1,1,2-Tetrachloroethane U 1,1,2,2-Tetrachloroethane U 1,1,2-Trichlorotrifluoroethane U Tetrachloroethene U Toluene U 1,2,3-Trichlorobenzene U 1,2,4-Trichlorobenzene U 1,1,1-Trichloroethane U 1,1,2-Trichloroethane U Trichloroethene U Trichlorofluoromethane U 1,2,3-Trichloropropane U 1,2,4-Trimethylbenzene U 1,2,3-Trimethyl benzene U 1,3,5-Trimethyl benzene U Vinyl chloride U Xylenes, Total U (S) Toluene-d8 98.8 (S) 4-Bromof/uorobenzene 98.1 (S)1,2-Dich/oroethane-d4 99.1 Qualifier MDL RDL Dilution Analysis Batch ug/I ug/I date / time 0.161 1.00 1 07/18/202019:04 WG1511373 0.105 1.00 1 07/18/202019:04 WG1511373 0.137 1.00 1 07/18/202019:04 WG1511373 0.337 1.00 1 07/18/202019:04 WG1511373 0.105 1.00 1 07/18/202019:04 WG1511373 0.120 1.00 1 07/18/202019:04 WG1511373 1.19 10.0 1 07/18/202019:04 WG1511373 0.430 5.00 1 07/18/202019:04 WG1511373 0.478 10.0 1 07/18/2020 19:04 WG1511373 0.101 1.00 1 07/18/202019:04 WG1511373 1.00 5.00 1 07/18/202019:04 WG1511373 0.0993 1.00 1 07/18/202019:04 WG1511373 0.118 1.00 1 07/18/202019:04 WG1511373 0.147 1.00 1 07/18/202019:04 WG1511373 0.133 1.00 1 07/18/202019:04 WG1511373 0.180 1.00 1 07/18/202019:04 WG1511373 0.300 1.00 1 07/18/202019:04 WG1511373 0.278 1.00 1 07/18/202019:04 WG1511373 0.230 1.00 1 07/18/202019:04 WG1511373 0.481 1.00 1 07/18/202019:04 WG1511373 0.149 1.00 1 07/18/202019:04 WG1511373 0.158 1.00 1 07/18/202019:04 WG1511373 0.190 1.00 1 07/18/202019:04 WG1511373 0.160 5.00 1 07/18/202019:04 WG1511373 0.237 2.50 1 07/18/202019:04 WG1511373 0.322 1.00 1 07/18/202019:04 WG1511373 0.104 1.00 1 07/18/202019:04 WG1511373 0.104 1.00 1 07/18/202019:04 WG1511373 0.234 1.00 1 07/18/202019:04 WG1511373 0.174 3.00 1 07/18/202019:04 WG1511373 80.0-120 071181202019:04 WG1511373 77.0-126 071181202019:04 WG1511373 70.0-130 071181202019:04 WG1511373 Fp FTc FS Fn FC] F ql FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 28 of 48 SW-3 SAMPLE RESULTS - 10 ONE LAB. NATIONWIDE. Collected date/time: 07/15/20 12:25 L1240114 Metals (ICP) by Method 6010D FP1 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date /time Antimony U 4.30 10.0 1 07/20/202014:34 WG1510364 FTc Arsenic U 4.40 10.0 1 07/20/202014:34 WG1510364 Barium 35.4 0.895 5.00 1 07/20/202014:34 WG1510364 F Beryllium U 0.460 2.00 1 07/20/202014:34 WG1510364 Cadmium U 0.563 2.00 1 07/20/202014:34 WG1510364 Chromium U 5.00 10.0 1 07/20/202014:34 WG1510364 4 Cfl Cobalt U 0.807 10.0 1 07/20/202014:34 WG1510364 Copper U 4.69 10.0 1 07/20/202014:34 WG1510364 Lead 3.16 J 2.95 6.00 1 07/20/202014:34 WG1510364 Nickel U 2.98 10.0 1 07/20/2020 14:34 WG1510364 Selenium U 7.35 10.0 1 07/20/202014:34 WG1510364 6 QC Silver U 1.91 5.00 1 07/20/202014:34 WG1510364 Thallium U 4.31 10.0 1 07/20/202014:34 WG1510364 �GI Vanadium U 6.34 20.0 1 07/20/202014:34 WG1510364 Zinc 15.0 J 9.16 50.0 1 07/20/202014:34 WG1510364 rAl Volatile Organic Compounds (GC/MS) by Method 8260D Qualifier MDL RDL Dilution Analysis Batch FSCResult Analyte ug/I ug/I ug/I date / time Acetone U 11.3 50.0 1 07/18/202019:25 WG1511373 Acrolein U J4 2.54 50.0 1 07/18/202019:25 WG1511373 Acrylonitrile U 0.671 10.0 1 07/18/202019:25 WG1511373 Benzene U 0.0941 1.00 1 07/18/202019:25 WG1511373 Bromobenzene U 0.118 1.00 1 07/18/202019:25 WG1511373 Bromodichloromethane U 0.136 1.00 1 07/18/202019:25 WG1511373 Bromoform U 0.129 1.00 1 07/18/202019:25 WG1511373 Bromomethane U 0.605 5.00 1 07/18/202019:25 WG1511373 n-Butylbenzene U 0.157 1.00 1 07/18/202019:25 WG1511373 sec -Butyl benzene U 0.125 1.00 1 07/18/202019:25 WG1511373 ter[-Butylbenzene U 0.127 1.00 1 07/18/202019:25 WG1511373 Carbon tetrachloride U 0.128 1.00 1 07/18/202019:25 WG1511373 Chlorobenzene U 0.116 1.00 1 07/18/202019:25 WG1511373 Chlorodibromomethane U 0.140 1.00 1 07/18/202019:25 WG1511373 Chloroethane U 0.192 5.00 1 07/18/202019:25 WG1511373 Chloroform U 0.111 5.00 1 07/18/202019:25 WG1511373 Chloromethane U 0.960 2.50 1 07/18/202019:25 WG1511373 2-Chlorotoluene U 0.106 1.00 1 07/18/202019:25 WG1511373 4-Chlorotoluene U 0.114 1.00 1 07/18/202019:25 WG1511373 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/18/202019:25 WG1511373 1,2-Dibromoethane U 0.126 1.00 1 07/18/202019:25 WG1511373 Dibromomethane U 0.122 1.00 1 07/18/202019:25 WG1511373 1,2-Dichlorobenzene U 0.107 1.00 1 07/18/202019:25 WG1511373 1,3-Dichlorobenzene U 0.110 1.00 1 07/18/2020 19:25 WG1511373 1,4-Dichlorobenzene U 0.120 1.00 1 07/18/202019:25 WG1511373 DichIorodifluoromethane U 0.374 5.00 1 07/18/202019:25 WG1511373 1,1-Dichloroethane U 0.100 1.00 1 07/18/202019:25 WG1511373 1,2-Dichloroethane U 0.0819 1.00 1 07/18/202019:25 WG1511373 1,1-Dichloroethene U 0.188 1.00 1 07/18/202019:25 WG1511373 cis-1,2-Dichloroethene U 0.126 1.00 1 07/18/202019:25 WG1511373 trans-1,2-Dichloroethene U 0.149 1.00 1 07/18/202019:25 WG1511373 1,2-Dichloropropane U 0.149 1.00 1 07/18/202019:25 WG1511373 1,1-Dichloropropene U 0.142 1.00 1 07/18/202019:25 WG1511373 1,3-Dichloropropane U 0.110 1.00 1 07/18/202019:25 WG1511373 cis-1,3-Dichloropropene U 0.111 1.00 1 07/18/202019:25 WG1511373 trans-1,3-Dichloropropene U 0.118 1.00 1 07/18/202019:25 WG1511373 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 29 of 48 ONE LAB. NATIONWIDE. SW-3 SAMPLE RESULTS - 10 Collected date/time: 07/15/20 12:25 L1240114 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte 2,2-Dichloropropane Di -isopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene p-Isopropyltoluene 2-Butanone (MEK) Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrach I oroeth a n e 1,1,2,2-Tetrachloroetha ne 1,1,2-Trichlorotrifluoroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-T ri c h l o ro eth a n e 1,1,2-Trich I oroetha n e Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Tri methyl benzen e 1,2,3-Trimethyl benzene 1,3,5-Trimethyl benzene Vinyl chloride Xylenes, Total (S) Toluene-d8 (S) 4-Bromof/uorobenzene (S) 1,2-Dich/oroethane-d4 Result Qualifier MDL RDL Dilution Analysis ug/I ug/I ug/I date / time U 0.161 1.00 1 07/18/202019:25 U 0.105 1.00 1 07/18/202019:25 U 0.137 1.00 1 07/18/202019:25 U 0.337 1.00 1 07/18/202019:25 U 0.105 1.00 1 07/18/202019:25 U 0.120 1.00 1 07/18/202019:25 U 1.19 10.0 1 07/18/202019:25 U 0.430 5.00 1 07/18/202019:25 U 0.478 10.0 1 07/18/202019:25 U 0.101 1.00 1 07/18/202019:25 U 1.00 5.00 1 07/18/202019:25 U 0.0993 1.00 1 07/18/202019:25 U 0.118 1.00 1 07/18/202019:25 U 0.147 1.00 1 07/18/202019:25 U 0.133 1.00 1 07/18/202019:25 U 0.180 1.00 1 07/18/202019:25 U 0.300 1.00 1 07/18/202019:25 U 0.278 1.00 1 07/18/202019:25 U 0.230 1.00 1 07/18/202019:25 U 0.481 1.00 1 07/18/202019:25 U 0.149 1.00 1 07/18/202019:25 U 0.158 1.00 1 07/18/202019:25 U 0.190 1.00 1 07/18/202019:25 U 0.160 5.00 1 07/18/202019:25 U 0.237 2.50 1 07/18/202019:25 U 0.322 1.00 1 07/18/202019:25 U 0.104 1.00 1 07/18/202019:25 U 0.104 1.00 1 07/18/202019:25 U 0.234 1.00 1 07/18/202019:25 U 0.174 3.00 1 07/18/202019:25 96.6 80.0-120 071181202019:25 93.4 77.0-126 071181202019:25 101 70.0-130 071181202019:25 Batch WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 WG1511373 Fp FTc FS Fn FC] F FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 30 of 48 DUP-1 SAMPLE RESULTS - 11 Collected date/time: 07/15/20 11:45 L1240114 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL Analyte ug/I ug/I Alkalinity 165000 8450 Sample Narrative: L1240114-11 WG1511471: Endpoint pH 4.5 headspace Wet Chemistry by Method 4500S2 D-2011 RDL Dilution Analysis Batch ug/I date / time 20000 1 07/22/202018:21 WG1511471 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Sulfide U Wet Chemistry by Method 9056A 25.0 50.0 1 07/20/202015:51 WG1511994 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Chloride 22000 379 1000 1 07/17/2020 03:44 WG1510095 Nitrate U 48.0 100 1 07/17/2020 03:44 WG1510095 Sulfate 598 J 594 5000 1 07/17/2020 03:44 WG1510095 Wet Chemistry by Method 9060A Result Qualifier MDL RDL Analyte ug/I ug/I ug/I TOC (Total Organic Carbon) 997 B J 102 1000 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Analyte ug/I ug/I ug/I Antimony U 4.30 10.0 Arsenic U 4.40 10.0 Barium 45.1 0.895 5.00 Beryllium U 0.460 2.00 Cadmium U 0.563 2.00 Chromium U 5.00 10.0 Cobalt U 0.807 10.0 Copper U 4.69 10.0 Lead U 2.95 6.00 Nickel U 2.98 10.0 Selenium U 7.35 10.0 Silver U 1.91 5.00 Thallium U 4.31 10.0 Vanadium U 6.34 20.0 Zinc 19.6 J 9.16 50.0 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Analyte ug/I ug/I ug/I Acetone U 11.3 50.0 Acrolein U J4 2.54 50.0 Acrylonitrile U 0.671 10.0 Benzene 0.690 J 0.0941 1.00 Bromobenzene U 0.118 1.00 Bromodichloromethane U 0.136 1.00 Bromoform U 0.129 1.00 Bromomethane U 0.605 5.00 n-Butylbenzene U 0.157 1.00 ACCOUNT: PROJECT: Withers & Ravenel Eng. - Standard 06140180.24 Dilution Analysis Batch date / time 1 07/17/202018:45 WG1510700 Dilution Analysis Batch date / time 1 07/20/202014:37 WG1510364 1 07/20/202014:37 WG1510364 1 07/20/202014:37 WG1510364 1 07/20/202014:37 WG1510364 1 07/20/202014:37 WG1510364 1 07/20/202014:37 WG1510364 1 07/20/202014:37 WG1510364 1 07/20/202014:37 WG1510364 1 07/20/202014:37 WG1510364 1 07/20/202014:37 WG1510364 1 07/20/202014:37 WG1510364 1 07/20/202014:37 WG1510364 1 07/20/202014:37 WG1510364 1 07/20/202014:37 WG1510364 1 07/20/202014:37 WG1510364 Dilution Analysis Batch date / time 1 07/18/202019:46 WG1511373 1 07/18/202019:46 WG1511373 1 07/18/202019:46 WG1511373 1 07/18/202019:46 WG1511373 1 07/18/202019:46 WG1511373 1 07/18/202019:46 WG1511373 1 07/18/202019:46 WG1511373 1 07/18/202019:46 WG1511373 1 07/18/202019:46 WG1511373 ONE LAB. NATIONWIDE. FP1 FTc FSS [Cn] Rc F FAI FSC SDG: DATE/TIME: PAGE: L1240114 07/23/20 15:35 31 of 48 D U P-1 SAMPLE Collected date/time: 07/15/20 11:45 Volatile Organic Compounds (GC/MS) by Method 8260D RESULTS - 11 L1240114 ONE LAB. NATIONWIDE. Result Qualifier MDL RDL Dilution Analysis Batch FP1 Analyte ug/I ug/I ug/I date / time sec -Butyl benzene U 0.125 1.00 1 07/18/202019:46 WG1511373 FTc tert-Butylbenzene U 0.127 1.00 1 07/18/202019:46 WG1511373 Carbon tetrachloride U 0.128 1.00 1 07/18/202019:46 WG1511373 Chlorobenzene 1.08 0.116 1.00 1 07/18/202019:46 WG1511373 FSS Chlorodibromomethane U 0.140 1.00 1 07/18/202019:46 WG1511373 Chloroethane U 0.192 5.00 1 07/18/202019:46 WG1511373 rCn Chloroform U 0.111 5.00 1 07/18/202019:46 WG1511373 Chloromethane U 0.960 2.50 1 07/18/202019:46 WG1511373 2-Chlorotoluene U 0.106 1.00 1 07/18/202019:46 WG1511373 4-Chlorotoluene U 0.114 1.00 1 07/18/202019:46 WG1511373 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/18/202019:46 WG1511373 Fc 1,2-Dibromoethane U 0.126 1.00 1 07/18/202019:46 WG1511373 Dibromomethane U 0.122 1.00 1 07/18/202019:46 WG1511373 1,2-Dichlorobenzene 0.143 J 0.107 1.00 1 07/18/202019:46 WG1511373 GI 1,3-Dichlorobenzene U 0.110 1.00 1 07/18/202019:46 WG1511373 1,4-Dichlorobenzene 4.61 0.120 1.00 1 07/18/202019:46 WG1511373 FAI Dichlorodifluoromethane U 0.374 5.00 1 07/18/202019:46 WG1511373 1,1-Dichloroethane 1.70 0.100 1.00 1 07/18/202019:46 WG1511373 1,2-Dichloroethane 0.712 J 0.0819 1.00 1 07/18/202019:46 WG1511373 F 1,1-Dichloroethene U 0.188 1.00 1 07/18/202019:46 WG1511373 cis-1,2-Dichloroethene 15.8 0.126 1.00 1 07/18/202019:46 WG1511373 trans-1,2-Dichloroethene U 0.149 1.00 1 07/18/202019:46 WG1511373 1,2-Dichloropropane 1.09 0.149 1.00 1 07/18/202019:46 WG1511373 1,1-Dichloropropene U 0.142 1.00 1 07/18/202019:46 WG1511373 1,3-Dichloropropane U 0.110 1.00 1 07/18/202019:46 WG1511373 cis-1,3-Dichloropropene U 0.111 1.00 1 07/18/202019:46 WG1511373 trans-1,3-Dichloropropene U 0.118 1.00 1 07/18/202019:46 WG1511373 2,2-Dichloropropane U 0.161 1.00 1 07/18/202019:46 WG1511373 Di -isopropyl ether U 0.105 1.00 1 07/18/202019:46 WG1511373 Ethylbenzene U 0.137 1.00 1 07/18/202019:46 WG1511373 Hexachloro-1,3-butadiene U 0.337 1.00 1 07/18/202019:46 WG1511373 Isopropylbenzene U 0.105 1.00 1 07/18/202019:46 WG1511373 p-Isopropyltoluene U 0.120 1.00 1 07/18/202019:46 WG1511373 2-Butanone (MEK) U 1.19 10.0 1 07/18/202019:46 WG1511373 Methylene Chloride U 0.430 5.00 1 07/18/202019:46 WG1511373 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 1 07/18/202019:46 WG1511373 Methyl tert-butyl ether 0.384 J_ 0.101 1.00 1 07/18/202019:46 WG1511373 Naphthalene U 1.00 5.00 1 07/18/202019:46 WG1511373 n-Propylbenzene U 0.0993 1.00 1 07/18/2020 19:46 WG1511373 Styrene U 0.118 1.00 1 07/18/202019:46 WG1511373 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 07/18/202019:46 WG1511373 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 07/18/202019:46 WG1511373 1,1,2-Trichlorotrifluoroethane U 0.180 1.00 1 07/18/202019:46 WG1511373 Tetrachloroethene U 0.300 1.00 1 07/18/202019:46 WG1511373 Toluene U 0.278 1.00 1 07/18/202019:46 WG1511373 1,2,3-Trichlorobenzene U 0.230 1.00 1 07/18/202019:46 WG1511373 1,2,4-Trichlorobenzene U 0.481 1.00 1 07/18/202019:46 WG1511373 1,1,1-Trichloroethane U 0.149 1.00 1 07/18/202019:46 WG1511373 1,1,2-Trichloroethane U 0.158 1.00 1 07/18/202019:46 WG1511373 Trichloroethene U 0.190 1.00 1 07/18/202019:46 WG1511373 Trichlorofluoromethane U 0.160 5.00 1 07/18/202019:46 WG1511373 1,2,3-Trichloropropane U 0.237 2.50 1 07/18/202019:46 WG1511373 1,2,4-Trimethylbenzene U 0.322 1.00 1 07/18/202019:46 WG1511373 1,2,3-Trimethyl benzene U 0.104 1.00 1 07/18/202019:46 WG1511373 1,3,5-Trimethyl benzene U 0.104 1.00 1 07/18/202019:46 WG1511373 Vinyl chloride 10.3 0.234 1.00 1 07/18/202019:46 WG1511373 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 32 of 48 DUP-1 SAMPLE RESULTS - 11 Collected date/time: 07/15/20 11:45 L1240114 Volatile Organic Compounds (GC/MS) by Method 8260D ONE LAB. NATIONWIDE. Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Xylenes, Total U 0.174 3.00 1 07/18/202019:46 WG1511373 (S) Toluene-d8 99.4 80.0-120 071181202019:46 WG1511373 (S) 4-Bromof/uorobenzene 95.6 77.0-126 071181202019:46 WG1511373 (S) 1,2-Dich/oroethone-d4 97.9 70.0-130 0711812020 19:46 WG1511373 Cp FTc FSS 4 Cn Fc F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 PAGE: 33 of 48 WG1511471 QUALITY CONTROL SUMMARY Wet Chemistry by Method 2320 B-2011 L1240114-02,03,04,05,07,11 Method Blank (MB) (MB) R3552237-1 07/22/2015:36 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I Alkalinity U 8450 20000 Sample Narrative: BLANK: Endpoint pH 4.5 L1240041-07 Original Sample (OS) • Duplicate (DUP) (OS) L1240041-07 07/22/2016:03 • (DUP) R3552237-2 07/22/2016:13 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Alkalinity 74500 74500 1 0.00306 20 Sample Narrative: OS: Endpoint pH 4.5 headspace DUP: Endpoint pH 4.5 L1240177-01 Original Sample (OS) • Duplicate (DUP) (OS) L1240177-01 07/22/2018:50 • (DUP) R3552237-4 07/22/2018:57 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Alkalinity 54800 54800 1 0.0627 20 Sample Narrative: OS: Endpoint pH 4.5 headspace DUP: Endpoint pH 4.5 Laboratory Control Sample (LCS) (LCS) R3552237-3 07/22/2017:16 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % Alkalinity 100000 102000 102 85.0-115 Sample Narrative: LCS: Endpoint pH 4.5 ONE LAB. NATIONWIDE. FP1 FTc FSS 4 Cn FSr �GI FAI [Sc ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 34 of 48 WG1511994 Wet Chemistry by Method 450052 D-2011 Method Blank (MB) (MB) R3551277-1 07/20/20 15:48 MB Result MB Qualifier MB MDL Analyte ug/I ug/I Sulfide U 25.0 L1240114-02 Original Sample (OS) • Duplicate (DUP) MB RDL ug/1 50.0 QUALITY CONTROL SUMMARY L1240114-02,03,04,05,07,11 (OS) L1240114-02 07/20/2015:49 • (DUP) R3551277-3 07/20/2015:49 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Sulfide U U 1 0.000 20 L1241248-02 Original Sample (OS) • Duplicate (DUP) (OS) L1241248-02 07/20/2015:53 • (DUP) R3551277-6 07/20/2015:54 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Sulfide U U 1 0.000 20 Laboratory Control Sample (LCS) (LCS) R3551277-2 07/20/2015:49 Spike Amount LCS Result LCS Rec. Analyte ug/I ug/I % Sulfide 500 510 102 Rec. Limits LCS Qualifier 85.0-115 L1240114-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1240114-03 07/20/2015:50 • (MS) R3551277-4 07/20/2015:50 • (MSD) R3551277-5 07/20/2015:50 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD Analyte ug/I ug/I ug/I ug/I % % % % Sulfide 1000 U 517 500 51.7 50.0 1 80.0-120 J6 3.34 ONE LAB. NATIONWIDE. RPD Limits 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 35 of 48 WG1510095 Wet Chemistry by Method 9056A Method Blank (MB) (MB) R3550832-1 07/16/2014:10 MB Result MB Qualifier MB MDL Analyte ug/I ug/I Chloride U 379 Nitrate U 48.0 Sulfate U 594 L1240114-07 Original Sample (OS) • Duplicate (DUP) MB RDL ug/I 1000 100 5000 QUALITY CONTROL SUMMARY L1240114-02,03,04,05,07,11 ONE LAB. NATIONWIDE. (OS) L1240114-07 07/17/20 02:34 • (DUP) R3550832-6 07/17/20 03:27 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Chloride 1700 1730 1 1.67 15 Nitrate U U 1 0.000 15 Sulfate 3670 3820 1 4.21 J 15 Laboratory Control Sample (LCS) (LCS) R3550832-2 07/16/2014:27 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % Chloride 40000 39600 99.1 80.0-120 Nitrate 8000 8120 102 80.0-120 Sulfate 40000 40700 102 80.0-120 L1240055-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1240055-02 07/16/20 21:03 • (MS) R3550832-4 07/16/20 21:21 • (MSD) R3550832-5 07/16/20 21:38 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % Nitrate 5000 6350 6390 103 104 1 80.0-120 0.559 15 Sulfate 50000 68200 116000 117000 96.4 96.7 1 80.0-120 E E 0.127 15 L1240114-11 Original Sample (OS) • Matrix Spike (MS) (OS) L1240114-11 07/17/20 03:44 • (MS) R3550832-7 07/17/20 04:01 Spike Amount Original Result MS Result MS Rec. Analyte ug/I ug/I ug/I % Chloride 50000 22000 71900 99.8 Nitrate 5000 U 5060 101 Sulfate 50000 598 51300 101 Dilution Rec. Limits MS Qualifier o� 1 80.0-120 1 80.0-120 1 80.0-120 FP1 FTc FSS 4 Cn FSr �GI FAI FSC ACCOUNT: Withers & Ravenel Eng. - Standard PROJECT: 06140180.24 SDG: DATE/TIME: PAGE: L1240114 07/23/20 15:35 36 of 48 WG1510700 QUALITY CONTROL SUMMARY Wet Chemistry by Method 9060A L1240114-02,03,04,05,07,11 Method Blank (MB) (MB) R3550710-1 07/17/2010:07 MB Result MB Qualifier MB MDL MB ROL Analyte ug/I ug/I ug/I TOC (Total Organic Carbon) 367 J 102 1000 L1240037-01 Original Sample (OS) • Duplicate (DUP) (OS) L1240037-01 07/17/2013:13 • (DUP) R3550710-3 07/17/2013:25 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % TOC 2990 3040 1 1.69 20 L1240114-02 Original Sample (OS) • Duplicate (DUP) (OS) L1240114-02 07/17/2015:57 • (DUP) R3550710-6 07/17/2016:09 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % TOC 813 826 1 1.66 J 20 Laboratory Control Sample (LCS) (LCS) R3550710-2 07/17/2010:35 Spike Amount LCS Result LCS Rec. Analyte ug/I ug/I % TOC 75000 75500 101 Rec. Limits LCS Qualifier 85.0-115 L1240037-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1240037-03 07/17/2014:47 • (MS) R3550710-4 07/17/2015:02 • (MSD) R3550710-5 07/17/2015:17 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD Analyte ug/I ug/I ug/I ug/I % % % % TOC 50000 957 49900 49300 97.9 96.7 1 80.0-120 1.21 L1240114-04 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1240114-04 07/17/2017:31 • (MS) R3550710-7 07/17/2017:46 • (MSD) R3550710-8 07/17/2018:05 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD Analyte ug/I ug/I ug/I ug/I % % % % TOC 50000 1010 50300 49300 98.5 96.5 1 80.0-120 1.99 ONE LAB. NATIONWIDE. RPD Limits 20 RPD Limits o� 20 — I Cp FTc FSS 4 — Cn FSr — �GI FAI [Sc ACCOUNT: Withers & Ravenel Eng. - Standard PROJECT: SDG: DATE/TIME: PAGE: 06140180.24 L1240114 07/23/20 15:35 37 of 48 WG1510364 Metals (ICP) by Method 6010D Method Blank (MB) (MB) R3551331-1 07/20/2013:49 MB Result Analyte ug/I Antimony U Arsenic U Barium U Beryllium U Cadmium U Chromium U Cobalt U Copper U Lead U Nickel U Selenium U Silver U Thallium U Vanadium U Zinc U MB Qualifier Laboratory Control Sample (LCS) MB MDL ug/I 4.30 4.40 0.895 0.460 0.563 5.00 0.807 4.69 2.95 2.98 7.35 1.91 4.31 6.34 9.16 MB RDL ug/I 10.0 10.0 5.00 2.00 2.00 10.0 10.0 10.0 6.00 10.0 10.0 5.00 10.0 20.0 50.0 QUALITY CONTROL SUMMARY L1240114-02,03,04,05,06,07,08,09,10,11 ONE LAB. NATIONWIDE. (LCS) R3551331-2 07/20/2013:51 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % Antimony 1000 960 96.0 80.0-120 Arsenic 1000 939 93.9 80.0-120 Barium 1000 997 99.7 80.0-120 Beryllium 1000 991 99.1 80.0-120 Cadmium 1000 955 95.5 80.0-120 Chromium 1000 957 95.7 80.0-120 Cobalt 1000 977 97.7 80.0-120 Copper 1000 967 96.7 80.0-120 Lead 1000 955 95.5 80.0-120 Nickel 1000 966 96.6 80.0-120 Selenium 1000 962 96.2 80.0-120 Silver 200 182 90.8 80.0-120 Thallium 1000 955 95.5 80.0-120 Vanadium 1000 977 97.7 80.0-120 Zinc 1000 952 95.2 80.0-120 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 38 of 48 FP1 FTC FSS [Cn] FSr �GI FAI FSC WG1510364 QUALITY CONTROL SUMMARY Metals (ICP) by Method 6010D L1240114-02,03,04,05,06,07,08,09,10,11 L1239953-08 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1239953-08 07/20/2013:54 • (MS) R3551331-4 07/20/2013:59 • (MSD) R3551331-5 07/20/2014:02 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Analyte ug/I ug/I ug/I ug/I % % Antimony 1000 U 970 959 97.0 95.9 Arsenic 1000 U 969 962 96.9 96.2 Barium 1000 68.8 1040 1050 97.5 97.9 Beryllium 1000 U 1000 992 100 99.2 Cadmium 1000 U 964 969 96.4 96.9 Chromium 1000 U 948 950 94.8 95.0 Cobalt 1000 U 1000 1010 100 101 Copper 1000 U 975 992 97.5 99.2 Lead 1000 U 969 966 96.9 96.6 Nickel 1000 3.81 989 996 98.5 99.3 Selenium 1000 U 978 970 97.8 97.0 Silver 200 U 183 183 91.4 91.4 Thallium 1000 U 944 948 94.4 94.8 Vanadium 1000 U 980 972 98.0 97.2 Zinc 1000 U 964 967 96.4 96.7 ONE LAB. NATIONWIDE. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits 1 75.0-125 1.16 20 1 75.0-125 0.655 20 1 75.0-125 0.335 20 1 75.0-125 1.11 20 1 75.0-125 0.556 20 1 75.0-125 0.194 20 1 75.0-125 0.735 20 1 75.0-125 1.80 20 1 75.0-125 0.327 20 1 75.0-125 0.795 20 1 75.0-125 0.798 20 1 75.0-125 0.00995 20 1 75.0-125 0.373 20 1 75.0-125 0.818 20 1 75.0-125 0.401 20 FP1 FTc FSS [Cn] FSr �GI FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 39 of 48 WG1511373 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. Volatile Organic Compounds (GC/MS) by Method 8260D L1240114-01,02,03,04,05,06,07,08,09,10,11 Method Blank (MB) (MB) R3551552-2 07/18/2011:19 MB Result Analyte ug/I Acetone U Acrolein U Acrylonitrile U Benzene U Bromobenzene U Bromodichloromethane U Bromoform U Bromomethane U n-Butylbenzene U sec -Butyl benzene U tert-Butylbenzene U Carbon tetrachloride U Chlorobenzene U Chlorodibromomethane U Chloroethane U Chloroform U Chloromethane U 2-Chlorotoluene U 4-Chlorotoluene U 1,2-Dibromo-3-Chloropropane U 1,2-Dibromoethane U Dibromomethane U 1,2-Dichlorobenzene U 1,3-Dichlorobenzene U 1,4-Dichlorobenzene U Dichlorodifluoromethane U 1,1-Dichloroethane U 1,2-Dichloroethane U 1,1-Dichloroethene U cis-1,2-Dichloroethene U trans-1,2-Dichloroethene U 1,2-Dichloropropane U 1,1-Dichloropropene U 1,3-Dichloropropane U cis-1,3-Dichloropropene U trans-1,3-Dichloropropene U 2,2-Dichloropropane U Di -isopropyl ether U Ethylbenzene U Hexachloro-1,3-butadiene U MB Qualifier MB MDL ug/I MB RDL ug/I 11.3 50.0 2.54 50.0 0.671 10.0 0.0941 1.00 0.118 1.00 0.136 1.00 0.129 1.00 0.605 5.00 0.157 1.00 0.125 1.00 0.127 1.00 0.128 1.00 0.116 1.00 0.140 1.00 0.192 5.00 0.111 5.00 0.960 2.50 0.106 1.00 0.114 1.00 0.276 5.00 0.126 1.00 0.122 1.00 0.107 1.00 0.110 1.00 0.120 1.00 0.374 5.00 0.100 1.00 0.0819 1.00 0.188 1.00 0.126 1.00 0.149 1.00 0.149 1.00 0.142 1.00 0.110 1.00 0.111 1.00 0.118 1.00 0.161 1.00 0.105 1.00 0.137 1.00 0.337 1.00 FP1 FTC FSS [Cn] FSr �GI FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 40 of 48 WG1511373 Volatile Organic Compounds (GC/MS) by Method 8260D Method Blank (MB) QUALITY CONTROL SUMMARY L1240114-01,02,03,04,05,06,07,08,09,10,11 (MB) R3551552-2 07/18/2011:19 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I Isopropylbenzene U 0.105 1.00 p-Isopropyltoluene U 0.120 1.00 2-Butanone (MEK) U 1.19 10.0 Methylene Chloride U 0.430 5.00 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 Methyl tert-butyl ether U 0.101 1.00 Naphthalene U 1.00 5.00 n-Propylbenzene U 0.0993 1.00 Styrene U 0.118 1.00 1,1,1,2-Tetrachloroethane U 0.147 1.00 1,1,2,2-Tetrachloroethane U 0.133 1.00 Tetrachloroethene U 0.300 1.00 Toluene U 0.278 1.00 1,1,2-Trichlorotrifluoroethane U 0.180 1.00 1,2,3-Trichlorobenzene U 0.230 1.00 1,2,4-Trichlorobenzene U 0.481 1.00 1,1,1-Trichloroethane U 0.149 1.00 1,1,2-Trichloroethane U 0.158 1.00 Trichloroethene U 0.190 1.00 Trichlorofluoromethane U 0.160 5.00 1,2,3-Trichloropropane U 0.237 2.50 1,2,3-Trimethyl benzene U 0.104 1.00 1,2,4-Trimethylbenzene U 0.322 1.00 1,3,5-Trimethyl benzene U 0.104 1.00 Vinyl chloride U 0.234 1.00 Xylenes, Total U 0.174 3.00 (S) Toluene-d8 100 80.0-120 (S) 4-Bromof/uorobenzene 98.5 77.0-126 (S)1,2-Dich/oroethone-d4 89.1 70.0-130 Laboratory Control Sample (LCS) (LCS) R3551552-1 07/18/20 10:36 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % Acetone 25.0 35.8 143 19.0-160 Acrolein 25.0 51.4 206 10.0-160 J4 Acrylonitrile 25.0 32.0 128 55.0-149 Benzene 5.00 5.44 109 70.0-123 ONE LAB. NATIONWIDE. FP1 FTC FSS [Cn] FSr �GI FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 41 of 48 WG1511373 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. Volatile Organic Compounds (GC/MS) by Method 8260D L1240114-01,02,03,04,05,06,07,08,09,10,11 Laboratory Control Sample (LCS) (LCS) R3551552-1 07/18/2010:36 Spike Amount Analyte ug/I Bromobenzene Bromodichloromethane Bromoform Bromomethane n-Butylbenzene sec -Butyl benzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-Chloropropane 1,2-Dibromoethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,1-Dichloropropene 1,3-Dichloropropane cis-1,3-Dichloropropene trans-1,3-Dichloropropene 2,2-Dichloropropane Di -isopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene p-Isopropyltoluene 2-Butanone (MEK) Methylene Chloride 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 25.0 5.00 LCS Result ug/I 5.51 5.39 5.28 5.17 5.60 5.83 5.60 4.75 5.40 5.01 4.76 5.20 5.26 5.59 5.72 5.55 5.51 5.37 5.24 5.41 5.40 4.87 5.12 4.94 5.45 5.55 5.41 5.36 5.08 5.57 5.51 5.42 5.06 5.72 5.21 5.27 5.50 5.68 29.3 5.34 LCS Rec 110 108 106 103 112 117 112 95.0 108 100 95.2 104 105 112 114 110 107 105 108 108 97.4 102 98.8 109 108 107 102 110 108 101 114 104 105 110 114 117 107 Rec. Limits LCS Qualifier 73.0-121 75.0-120 68.0-132 10.0-160 73.0-125 75.0-125 76.0-124 68.0-126 80.0-121 77.0-125 47.0-150 73.0-120 41.0-142 76.0-123 75.0-122 58.0-134 80.0-122 80.0-120 79.0-121 79.0-120 79.0-120 51.0-149 70.0-126 70.0-128 71.0-124 73.0-120 73.0-120 77.0-125 74.0-126 80.0-120 80.0-123 78.0-124 58.0-130 58.0-138 79.0-123 54.0-138 76.0-127 76.0-125 44.0-160 67.0-120 FP1 FTC FSS [Cn] FSr �GI FAI FSC ACCOUNT: Withers & Ravenel Eng. - Standard PROJECT: SDG: DATE/TIME: PAGE: 06140180.24 L1240114 07/23/20 15:35 42 of 48 WG1511373 Volatile Organic Compounds (GC/MS) by Method 8260D Laboratory Control Sample (LCS) QUALITY CONTROL SUMMARY L1240114-01,02,03,04,05,06,07,08,09,10,11 ONE LAB. NATIONWIDE. FP1(LCS) R3551552-1 07/18/2010:36 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % 2TC 4-Methyl-2-pentanone (MIBK) 25.0 27.4 110 68.0-142 Methyl tert-butyl ether 5.00 5.38 108 68.0-125 FSS Naphthalene 5.00 5.69 114 54.0-135 n-Propylbenzene 5.00 5.47 109 77.0-124 Styrene 5.00 5.82 116 73.0-130 [Cn] 1,1,1,2-Tetrachloroethane 5.00 5.43 109 75.0-125 1,1,2,2-Tetrachloroethane 5.00 5.81 116 65.0-130 FSr Tetrachloroethene 5.00 5.18 104 72.0-132 Toluene 5.00 5.61 112 79.0-120 1,1,2-Trichlorotrifluoroethane 5.00 4.51 90.2 69.0-132 1,2,3-Trichlorobenzene 5.00 5.55 ill 50.0-138 1,2,4-Trichlorobenzene 5.00 5.99 120 57.0-137 7G1 1,1,1-Trichloroethane 5.00 4.79 95.8 73.0-124 1,1,2-Trichloroethane 5.00 5.36 107 80.0-120 Trichloroethene 5.00 5.12 102 78.0-124 FAI Trichlorofluoromethane 5.00 4.41 88.2 59.0-147 1,2,3-Trichloropropane 5.00 5.35 107 73.0-130 FSC 1,2,3-Trimethylbenzene 5.00 5.52 110 77.0-120 1,2,4-Trimethylbenzene 5.00 5.62 112 76.0-121 1,3,5-Trimethyl benzene 5.00 5.75 115 76.0-122 Vinyl chloride 5.00 5.06 101 67.0-131 Xylenes, Total 15.0 16.4 109 79.0-123 (S) Toluene-d8 97.9 80.0-120 (S) 4-Bromof/uorobenzene 98.0 77.0-126 (S)1,2-Dich/oroethane-d4 89.9 70.0-130 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 43 of 48 WG1512594 Volatile Organic Compounds (GC/MS) by Method 8260D Method Blank (MB) (MB) R3551781-2 07/21/20 20:09 MB Result Analyte ug/I 1,2,3-Trim ethyl benzene U (S) Toluene-d8 101 (S) 4-Bromofluorobenzene 100 (S)1,2-Dich/oroethane-d4 100 QUALITY CONTROL SUMMARY L1240114-02 MB Qualifier MB MDL MB RDL ug/I ug/I 0.104 1.00 80.0-120 77.0-126 70.0-130 Laboratory Control Sample (LCS) (LCS) R3551781-1 07/21/2019:28 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I Ug/I % % 1,2,3-Trimethyl benzene 5.00 4.87 97.4 77.0-120 (S) Toluene-d8 99.7 80.0-120 (S) 4-Bromofluorobenzene 102 77.0-126 (S)1,2-Dich/oroethane-d4 100 70.0-130 ONE LAB. NATIONWIDE. FP1 FTc FSS 4 Cn FSr �GI FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 44 of 48 GLOSSARY OF TERMS ONE LAB. NATIONWIDE. Guide to Reading and Understanding Your Laboratory Report The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name, Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received. Abbreviations and Definitions MDL RDL Rec. RPD SDG (S) U Analyte Dilution Limits Original Sample Method Detection Limit. Reported Detection Limit. Recovery. Relative Percent Difference. Sample Delivery Group. FP1 FTC FSS [Cn] FSr Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be F detected in all environmental media. C Not detected at the Reporting Limit (or MDL where applicable). The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the rA laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal I9 for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or SC duplicated within these ranges. The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG. This column provides a letter and/or number designation that corresponds to additional information concerning the result Qualifier reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" Result (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Uncertainty (Radiochemistry) Confidence level of 2 sigma. A brief discussion about the included sample results, including a discussion of any non -conformances to protocol Case Narrative (Cn) observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. Quality Control This section of the report includes the results of the laboratory quality control analyses required by procedure or Summary (Qc) analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. This is the document created in the field when your samples were initially collected. This is used to verify the time and Sample Chain of date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This Custody (Sc) chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. This section of your report will provide the results of all testing performed on your samples. These results are provided Sample Results (Sr) by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. Sample Summary (Ss) This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Qualifier Description B The same analyte is found in the associated blank. E The analyte concentration exceeds the upper limit of the calibration range of the instrument established by the initial calibration (ICAL). J The identification of the analyte is acceptable; the reported value is an estimate. J4 The associated batch QC was outside the established quality control range for accuracy. J6 The sample matrix interfered with the ability to make any accurate determination; spike value is low. ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 45 of 48 ACCREDITATIONS & LOCATIONS ONE LAB. NATIONWIDE. Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing FP1 turn -around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. Not all certifications held by the laboratory are applicable to the results reported in the attached report. Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National. Z Tc State Accreditations f—� Alabama 40660 Nebraska _ NE-OS-15-05 SS Alaska 17-026 Nevada TN-03-2002-34 Arizona AZO612 New Hampshire 2975 Arkansas 88-0469 New Jersey_NELAP TNO02 C n California 2932 New Mexico n/a Colorado TN00003 New York 11742 s Connecticut PH-0197 North Carolina Env375 Sr Florida E87487 North Carolina' DW21704 Georgia NELAP North Carolina' 41 Georgia' 923 North Dakota R-140 RC Idaho TN00003 Ohio—VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 G Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhode Island LA000356 Kentucky76 90010 South Carolina 84004 Kentucky 2 16 South Dakota n/a Louisiana A130792 Tennessee' 4 2006 Louisiana' LA180010 Texas T104704245-18-15 [SC Maine TN0002 Texas' LABO152 Maryland 324 Utah Massachusetts M-TNO03 Vermont Michigan 9958 Virginia Minnesota 047-999-395 Washington Mississippi TN00003 West Virginia Missouri 340 Wisconsin Montana CERT0086 Wyoming Third Party Federal Accreditations A21LA — ISO 17025 1461.01 AIHA-LAP,LLC EMLAP A21LA — ISO 17025 5 1461.02 DOD Canada 1461.01 USDA EPA—Crypto TN00003 ' Drinking Water 'Underground Storage Tanks 3 Aquatic Toxicity 4 Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable Our Locations TN00003 VT2006 460132 C847 233 9980939910 A2LA 100789 1461.01 P330-15-00234 Pace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contact our main office. Pace National performs all testing at our central laboratory. WA ME MT ND OR MN T ID t WI NY SD WY MI NV t NE IA OH PA T f IL Ills WV vA UT T CA�� T KS MO KY N NM O� AR SC T MS AL`7GA T TX * LA T AK q FL wo HI ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1240114 07/23/20 15:35 46 of 48 Bilhnglnformation: Analvsis/ Container /Preservative Chain of Custody Page of Withers & Ravenel Eng. - Standard Accounts Payable Pres 115 MacKenan Drive chk 2CBAf121yhC2�' 115 MacKenan Drive Cary, NC 27511 NeMo'al CwT✓rY TMXiga, a.a - Cary, NC 27511 ) a Q. 12065 tenanon as QQ MounUu et,TN 3J122 f•4 Report to: Email To: lei liott@withersraveneLcom Laura Elliott z LL ^ ca Q Rho ne,635-Tsa-sass ' Phone. eooa6"F" 2 Fa. '. 615 J59 S959 S � 2 Pro act Descri [ion: 1 p Cit /State \ Y /� Please Circle Kernersville Landfill Collected: rL[,f�%J hL s 1`-J PT MT CT ET O Z p = G r- rJ /, SDG# �,G jU(l y Client Project# Lab Project# Phone:919-469-3340 06140180.24 WITHRAVS-KERNERSVILL M a 2 0 1 F168 Q, �] p � do Z \ ` V Tablt Acctnum: WITHRAVS Collected by (print): c Site/Facility ID # P.O. # i', d 06140180.24 p N a Z a E E = ti In = d 4 Template:T170822 Prelogin: P785189 Coll cte by (sign tune): Rush? (Lab MUST Be Notified) Quote # Day Day I 't,{Jtr —Same _Five CD _ PM: 873-Heather J Wagner Next Day _5 Day(Rad Only) Date Results Needed -gyp medlately / _ Two Day _ 10 Day (Rad Only) V". � ry E O —Qu '� _ PB: shipped via: Fed EX Ground Packed on ice N_ y_ _Three Day of o CD LL O Sample ID Comp/Grab Matrix' Depth Date Time no-s Q n 4 = N O r W 7 Remark: Sample 9(lab only) GW Ili 2 GW NA- 1: X Y X Y X o2 ' GW �- 10 X Y Ix -f GW I '. ) '9 X X — MiAlf GW ! x X 4w !=L — GW iiJA 9!4KX X �� -- GW ' 4 X X (L ----- GW NR 4 X X _ — -- • Matrix:Remarks: s 1 R t Ph kl' t SS - Soil AIR - Air F- Filter pH _ Temp COC Seal Present/Intact: _,, B Y N GW- Groundwater B- Bioassay Flow Other coc signed/Accurate: eY _N Bottles arrive intact: WW- Wastewater Correct bottles used: DW -Drinking Water OT - Other —N su£fio'ent volume sent: Y _N If Applicable 7 Samples re ned via: Tracking#y ]/(y1y/��( � DOV ��/ _UPS YFedEx _Courier V - ICA zero Headspace: ZY _N Rreservat eenon correct/Checked: Y _N RAD Screen <0.5 mR/hr. i-Y N Rure) shed by: (Signs Date, Time: Received by: (Signature) Trip Blank Received: es No _ o -2a Z? H / MeoH RR Re inquished by: (Signature) Date. Time: Received by: (Signature) Temp: oC Bottles Received: If preservation required by Login: Date/Time 3a 3—ohst Relinquished by: (Signature) Date: time: (Slgnatur D e: Time: H Condition: �Receiveby: r -_ NCF / -7 J Billing Information: Analvsis/Co 'ner Preservative Chain of Custody Page of Withers & Ravenel Eng. - Standard Accounts Payable Prey 115 MacKenan Drive chk aceAnatytlealo 115 MacKenan Drive Cary, NC 27511 Cary, NC 27511 12065 Lebanon ad Q �i Report to: e Email To. lelliott@withersravenel.com Laura Elliott 40 Mount Juliet, TN 37122 Y Z d Q Phone: 615-)58-5858 Phone: a00.)6)-5859 r Fax: 615J58 5859 O',r Project Description. City/State Please Circ Kernersville Landfill Collected: ' PT MT Cl ET m O Z ❑ = } Phone:919-469-3340 Client Project# Lab Project # SDG III l'L 06140180.24 WITHRAVS-KERNERSVILL = o = d O Dc 'N m Z Table# Collected by (print): Site/Facility ID # P.O. # Acctnum: WITHRAVS 06140180.24 = O u IJ p rN G LL ,p Template:T170822 Coll e eoft (signature : Rush? (Lab MUST Be Notified) Quote # �/"" (✓iJL.L w same Day _Five Day ^� Z aW ❑ _ Q Prelogin: P7$$1$9 lJ _Ne,<Z Day _SDay (Rod Only) Date Results Needed Y -j L E PM: 873- Heather I Wagner Immediately Packed on Ice N _ Y Two Day 10 Day (Rod Only) IN _ Three Day 117,1,1FZ (� i of o S N OW S O N O V O is !7 PS: —�j.aci Sample kntrs Shipped via: FeclEX Ground ID Comp/Grab Matrix" Depth Date Time Y V ry aema.xs sample Cliab oei;� 00 GW �rl 4 X \. Ilk X 1 ..... ._..__ GW 1-�_. ._ _. GW 1...3 GW ._.X- GW X- GW 3 "Matrix: _—__. _..— -_._ _.............. Remarks: Sample Receipt Checklist SS -Soil AIR -Air F- Filter pH Temp CDC Seal Present/Intact: N GW- Groundwater B-Bioassay _udiiY CDC Signed/Accurate: 1T _N WW - Waste Water Flow Other Bottles arrive intact: 1R _N O W -Drinking Water Correct bottles used: L,Y _N Samples ret ed via: Sufficient volume sent: �Y —N DDrinf UPS FedEx Courier Tracking# If Aomicable — — — VCA zero Headspace: '/Y _N Preservation Correct/Checked: 't N — Reh fished by:(Sign ure) Date: Time: Received bY'(Signature) Trip Blank Receiv ez No Merit RAD Screee <0.5 mR/hr: ZY N LV TBR R nquished by: (Signature) Date Time: Received by: (Signature) Teri ec Bottles Received: If preservation required by Login: Date/Time Relinquished by: (Signature) Date: Tame: atce 4WVor lab by: (Signature) Da : Time: Hold: Condition: NCF / bK Page of lir P cnl Your Succr Job Number 6140180.33 Groundwater Sampling Form State ID Well ID M. Site Name Kernersville Closed Landfill Date 1 Well Depth 1p Depth to Water Well Diameter Casing Material Screen Length J Well Water Volume Sampling Crew A. Barham, L. Elliott, M. Maltba Pump Type Tubing Type Intake set at Weather Conditions Notes (eg odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity 24 Hr. from TOC) Gals. m /L (OCj S/cm standard mV NTU viner rarameiers Sampled at Parameters taken with Samples delivered to by at Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs by 8260 Metals by 6010 HCL Nitric Acid 40 ml VOAs glass 1 Liter glass 14 Days 7 Days NO2, SO4, Cl-, Alk TOC Sulfide Sulfuric Acid None 250 ml plastic 125 ml plastic 1 Liter glass 180 Days 28 Days 7 days 1 Liter glass 7 Days Vv Ull VulUnle Udlculauon 1" well [well depth -depth to water] x 2" well [well depth -depth to water] x 4" well [well depth -depth to water] x 0.0408 gallons/ft. x 3 = 0.124/ft. _ 0.163 gallons/ft. x 3 = 0.489/ft = 0.653 gallons/ft. x 3 = 1.959/ft = N:\14\14-0180\140180.33-Supp #33 Landfill Services FYE 2020\Enviro\Reports and Deliverables\WQ Evernt July 2020\KCLF GW Sampling Form 2020.x1s Page � of 00 Our People. Yol Job Number 6140180.33 Groundwater Sampling Form State ID Well ID .i- Site Name Kernersville Closed Landfill % l� j Date Well Depth Depth to Water]. 62 Well Diamet r Casing Material Screen Length Well Water Volume Sampling Crew A. Barham, L. Elliott, M. Maltba Pump Type Tubing Type Intake set at Weather Conditions`, j� Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity 14 Hr.) from TOG) (Gels.) (m /L (°C) (pS/cm) (standar NTU 1 umer rarameiers Sampled at Parameters taken with Sal)aPie-s,I—LtNv > to by at Analysis Preservative Bottle ware Numb f Bottles Hold Time VOCs by 8260 HCL 40 ml VOAs glass 14 Days Metals by 6010 Nitric Acid 1 Liter glass 7 Days NO2, SO4, Cl-, Alk Sulfuric Acid 250 ml plastic 180 Days TOC None 125 ml plastic 28 Days Sulfide 1 Liter glass \ 7 days 1 Liter glass 7 Days even vulurne �_.alculauon 1 " well [well depth -depth to water] x 2" well [well depth -depth to water] x 4" wel I [well depth -depth to water] x 0.0408 gallons/ft. x 3 = 0.124/ft. _ 0.163 gallons/ft. x 3 = 0.489/ft = 0.653 gallons/ft. x 3 = 1.959/ft = N:\14\14-0180\140180.33-Supp #33 Landfill Services FYE 2020\Enviro\Reports and Deliverables\WQ Evernt July 2020\KCLF GW Sampling Form 2020.x1s Page i of Our People, Your Success Job Number 6140180.33 Groundwater Sampling Form State ID Well ID ILIL j >%?I$ Site Name Kernersville Closed Landfill Date - j:3 , 7_ Well Depth �- Depth to Water Well Diameter Casing Material Q" een Length 1 Well Water Volume Sampling Crew A. Barham L. Elliott . Maltba Pump Type,, Tubing Type_pIntake set at 2Z Weather Conditions •'l!s or NotesT-odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity (24 Hr. l (frnm TC)M If;als 1 Imnll 1 ror_% II I.q/r•ml 1e+nnrl0rrl1 /mM MITI 1% MMEMW umer rarameters Sampled at Samples delivered to Parameters taken with �L I_A , �]t{, A Ak,' .7 by at Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs by 8260 HCL 40 ml VOAs glass 14 Days Metals by 6010 Nitric Acid 1 Liter glass 7 Days NO2, SO4, Cl-, Alk 250 ml plastic 180 Days TOC ,Alen€ A 125 ml plastic 28 Days Sulfide 1 Liter glass 7 days 1—!!;b A-L-Wglass 7 Days vveu volume ualculatlon 1 " well [well depth -depth to water] x 2 well [well depth -depth to water] x 4" well [well depth -depth to water] x 0.0408 gallonslft. x 3 = 0.124/ft. _ 0.163 gallonslft. x 3 = 0.489/ft 0.653 gallonslft. x 3 = 1.959/ft = N:\14\14-0180\140180.33-Supp #33 Landfill Services FYE 2020\Enviro\Reports and Deliverables\WQ Evernt July 2020\KCLF GW Sampling Form 2020.x1s Page of Our People, Your Success Job Number 6140180.33 Groundwater Sampling Form State ID Well ID M�-3 Site Name Kernersville Closed Landfill Date Well Depth sl_q_Qtp Casing Material PVe, Sampling Crew A. Bar. Pump Type Depth to Water 11 A 4 Well Diameter_ 7 U _ reen Length Zee E Well Water Volume r "7 , 3�� 111'0�2M. Maltba Tubing Type 13,} Intake set at �7 i Weather Conditions 7." } Notes eg- odor or color) S azibvll Time Water Level Volume Purged DO Temp EC pH ORP Turbidity (24 Hr 1 Ifrnm TOM (C,alc 1 Irnn![ 1 Ier71 !i iClrml 1—M IN171 n r IM� r`` ` MOMIN �� �1�� Z a,�rl mo �. ERMICE IMMIM's � c '3iif� viner r-arameiers Sampled at Samples delivered to Analysis VOCs by 8260 Metals by 6010 NO2, SO4, Cl-, Alk TOC Sulfide //cad Parameters taken with by Preservative Bottle ware HCL 40 ml VOAs glass Nitric Acid 1 Liter glass Sulfuric Acid 250 ml plastic None 125 ml plastic 1 Liter glass tglass 2� 4t, at Number of Bottles Hold Time 14 Days 7 Days '3 180 Days 28 Days 7 days j 7 Days Well Volume Calculation 1 " well [well depth -depth to water] x 0.0408 gallons/ft. x 3 = 0.124/ft. _ 2" well [well depth -depth to water] x 0.163 gallonsift. x 3 = 0.489/ft = 1-2. D 1 g eQ 4" well [well depth -depth to water] x 0.653 gallons/ft. x 3 = 1.959/ft = N:\14\14-0180\140180.33-Supp #33 Landfill Services FYE 2020\Enviro\Reports and Deliverables\WQ Evernt July 2020\KCLF GW Sampling Form 2020.xls Page � of Our People, Your Success Job Number 6140180.33 Groundwater Sampling Form State ID Well ID Site Name Kernersville Closed Landfill Date Well Depth Depth to Water Well IDDii meter Casing Material Screen Length Well Water Volume Sampling Crew A. Barham, L. Elliott. M. Ma/tba Pump Type Tubing Type Intake set at Weather Conditions a •_ Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity 24 Hr. from TOC Gals. m /L °C S/cm) (standard mV NTl1 caner Narameters Sampled at Parameters taken with Samples delivered to by at f7nalysis Preservative Bottle ware Number of Bottles Hold Time VOCs by 82)AI HCL 40 ml VOAs glass 14 Days Metals by 6 Nitric Acid 1 Liter glass 7 Days NO2, SO4, Cl-, Sulfuric Acid 250 ml plastic 180 Days TOC None 125 ml plastic 28 Days Sulfide 1 Liter glass 7 days 1 Liter glass 7 Days vveu volume uaicu[at[on 1" well [well depth -depth to water] x 0.0408 gallons/ft. x 3 = 0.124/ft. _ 2" well [well depth -depth to water] x 0.163 gallons/ft. x 3 = 0.489/ft = 4" well [well depth -depth to water] x 0.653 gallons/ft. x 3 = 1.959/ft = N:\14\14-0180\140180.33-Supp #33 Landfill Services FYE 2020\Enviro\Reports and Deliverables\WQ Evernt July 2020\KCLF GW Sampling Form 2020.xis 40 Page I of NoOur People, Your Success Job Number 6140180.33 Groundwater Sampling Form State ID Well ID Site Name Kernersville Closed Landfill I Date Well Depth Depth to Water Well Dla�r, Casing Material Screen Length Well Water Volume Sampling Crew A. Barham, L. Elliott, M. Maltba Pump Type 6 T bing Type Intake set at Weather Conditions if t Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity (24 Hr.) (from TOC) (Gals. m /L °C S/cm) (standard mV NTU .1 I- I IS utner rarameters Sampled at Parameters taken with t Samples delivered to by at Preservative Bottle ware Number of Bottles Hold Time s by 8260 Cetals HCL 40 ml VOAs glass 14 Days by 601 Nitric Acid 1 Liter glass 7 Days 4, CI-, Alk Sulfuric Acid 250 ml plastic 180 Days TOC None 125 ml plastic 28 Days Sulfide 1 Liter glass 7 days 1 Liter glass 7 Days vveli volume �,a[culanon 1 n well [well depth -depth to water] x 2" well [well depth -depth to water] x 4" well [well depth -depth to water] x 0.0408 gallonsift, x 3 = 0.124/ft. _ 0.163 gallonsift. x 3 = 0.489/ft = 0.653 gallons/ft. x 3 = 1.959/ft = N:\14\14-0180\140180.33-Supp #33 Landfill Services FYE 2020\Enviro\Reports and Deliverables\WQ Evernt July 2020\KCLF GW Sampling Form 2020.xls 40 Page �, of NO Our People, Your Success Job Number 6140180.33 Groundwater Sampling Form State ID Well ID Site Name Kernersville Closed Landfill Date Well Depth Depth to Water �s• ! Well Diameter Casing Material Screen Length Well Water Volume Sampling Crew A. Barham, L. Elliott, M. Ma/tba Pump Type Tubing Type Intake set at Weather Conditions S-Vft1rjt-j 42 q0 Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity 24 Hr. from TOC Gals. m /L °C S/cm) (standard mV NTU J UU 3 Uther Narameters Sampled at Parameters taken with Samples delivered to by at Preservative Bottle ware Number of Bottles Hold Time HCL 40 ml VOAs glass 14 Days Me Nitric Acid 1 Liter glass 7 Days NO2, SO4, Cl-, Alk Sulfuric Acid 250 ml plastic 180 Days TOC None 125 ml plastic 28 Days Sulfide 1 Liter glass 7 days 1 Liter glass 7 Days vveu volume ualculatnon 1 " well (well depth -depth to water] x 0.0408 gallons/ft. x 3 = 0.124/ft. _ 2"well [well depth -depth to water] x 0.163 gallons/ft. x 3 = 0.489/ft= 4" well [well depth -depth to water] x 0.653 gallonsift. x 3 = 1.959/ft = N:\14\14-0180\140180.33-Supp #33 Landfill Services FYE 2020\Enviro\Reports and Deliverables\WQ Evernt July 2020\KCLF GW Sampling Form 2020.x1s �6ENR USE ONLY [:]Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No) Doc/Event #: NC DENR Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): WithersRavenel, Inc. Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Laura Robertson Elliott, PG Phone: 919.238.0422 (o) / 919.451.9710 E-mail: lellioft@withersravenel.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Town of Kernersville Landfill Freeman Road 34-04 .0500 July 15, 2020 Kernersville, NC 27284 Environmental Status: (Check all that apply) Initial/Background Monitoring OX Detection Monitoring Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Methane gas monitoring data Groundwater monitoring data from private water supply wells Corrective action data (specify) Leachate monitoring data ❑ Surface water monitoring data Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Laura Elliott, PG Project Geologist Fac' ity R&resentative Name intj Title Sig ur 424 Gallimore Dairy Road, Suite C, Greensboro, NC 27409 Facility Representative Address C-082 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 (Area Code) Telephone Number August 31, 2020 Affix NC Licen.§g,rofessional Geologist Seal Date CA 2271 t Goa GW-3i.2P A, 0. tl 1 SO pepe4�es +�A1.i1111 l96t e1.4 i APPENDIX II Historical Summary Tables TABLE1A SUMMARY OF HISTORICAL GROUNDWATER ELEVATIONS Background Downgradient Well ID: MW-1 MW-6 MW-2 MW-3S MW-31) MW-4 MW-5 TOC Elevation: 806.42 804.87 762.19 764.57 764.56 760.26 773.32 Well Depth: 34.69 20.46 13.18 24.00 56.96 14.40 11.36 30-Dec-09 772.45 786.66 759.16 751.54 752.79 754.33 769.21 01-Jun-10 773.45 788.32 758.90 750.76 752.63 753.90 769.69 16-Nov-10 773.55 787.93 759.14 750.98 752.59 753.74 769.81 29-Dec-10 773.29 787.37 758.83 749.82 752.45 753.68 769.56 29-Jun-11 773.10 786.81 758.38 750.54 752.16 753.41 769.73 01-Nov-11 771.92 785.10 758.49 754.73 751.90 753.08 769.63 01-May-12 771.88 785.32 758.54 750.86 752.34 753.55 769.55 07-Nov-12 771.65 DRY 758.20 750.30 751.61 752.87 768.57 09-May-13 769.95 787.56 759.20 752.52 753.24 754.44 - 07-Nov-13 771.46 DRY 758.09 750.12 751.50 752.79 768.13 05-Jun-14 772.22 785.84 758.45 750.67 752.14 753.36 768.57 20-Nov-14 771.73 784.41 758.08 750.24 751.53 752.81 769.23 Notes: TOC = Top of PVC well casing. Elevations in feet above mean sea level. Well depths in feet below TOC. Town of Kernersville Landfill Permit No. 34-04 Joyce Engineering TABLE 1B MONITORING WELL AND BORING COMPLETION SUMMARY WELL NUMBER CASING DIAMETER inches WELL ELEVATIONS TOTAL DEPTH SCREENED INTERVAL* LITHOLOGY OF SCREENED INTERVAL* GROUND SURFACE T.O.C. B.G.S. feet B.T.O.C. feet DEPTH B.G.S. ELEV. M.S.L. feet above M.S.L. from to from to MW-1 2 803.89 806.42 32.16 34.69 24.69 34.96 779.2 768.9 SAPROLITE MW-2 2 760.07 762.19 11.06 13.18 3.18 13.18 756.9 746.9 SAPROLITE MW-3S 2 761.98 764.57 21.41 24.00 14 24 748.0 738.0 SAPROLITE MW-3D 2 762.02 764.56 54.42 56.96 36.96 56.96 725.1 705.1 SAPROLITE MW-4 2 757.00 760.26 11.14 14.40 4.4 14.4 752.6 742.6 SAPROLITE MW-5 2 771.00 773.32 9.04 11.36 6.36 11.36 764.6 759.6 SAPROLITE MW-6 2 801.77 1 804.87 17.36 20.46 10.46 20.46 791.3 781.3 SAPROLITE NOTES: B.G.S. Below Ground Surface M.S.L. Mean Sea Level B.T.O.C. Below Top of Casing T.O.C. Top of Casing * = Due to limited information this data is assumed based on field conditions Town of Kernersville Landfill Page 1 of 1 Joyce Engineering TABLE 2 SUMMARY OF ESTIMATED HYDRAULIC GRADIENT AND LINEAR VELOCITY November 2014 GRADIENT FLOW LINE GROUND- HORIZ. HYDRAULIC EFFECTIVE LINEAR FLOW WATER GRADIENT, CONDUCTIVITY POROSITY VELOCITY, CALCULATION LENGTH DIRECTION ELEV. i K n V SEGMENT (feet) feet ft/ft ft/da ft/da 11 851 SW 0.04 1.73 0.30 0.20 755 Notes: 1. Hydraulic conductivities ("K") was estimated from slug test completed by JOYCE in April 2013 2. Velocity = Ki/n; assume homogeneous isotropic porous aquifer. Town of Kernersville Landfill Permit No. 34-04 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample 11 Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-31) MW-4 MW-5 Blanks Inorganic Compounds Antimony 30-Dec-09 1.2 6.0 --- ND 5.4 B ND ND 4.5 B --- 1.4 J GWPS = 1.4 µg/L (10/23/07) 01-Jun-10 1.2 6.0 --- ND ND ND ND ND --- 3.9 J GWPS = 1 µg/L (8/1/10) 29-Dec-10 2.6 6.0 --- ND ND ND ND ND ND ND 29-Jun-11 5.0 6.0 --- ND ND ND ND ND ND ND 01-Nov-11 5.0 6.0 --- ND ND ND ND ND ND ND 01-May-12 5.0 6.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.48 6.0 --- --- ND ND ND ND --- ND 09-May-13 5.0 6.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 6.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 6.0 --- ND ND ND ND ND ND ND 20-Nov-14 3.8 6.0 --- --- ND ND ND ND ND ND Arsenic 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 6.2 J ND NC 2L = 10 µg/L (1/11/10) 01-Nov-11 5.0 10.0 --- ND ND ND ND ND ND ND 01-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.094 10.0 --- --- 1.43 B 1.42 B 0.87 B 1.04 B --- 1.0 J 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND 2.5 J ND ND 2.7 J ND Barium 30-Dec-09 1.1 100 --- 74.1 J 496 178 18.2 J 89.0 J --- 3.6 J NC 2L = 700 µg/L (1/11/10) 01-Jun-10 1.1 100 --- 58.1 J 326 187 22.2 J 94.9 J --- 2.0 1 29-Dec-10 0.20 100 --- 46.3 B 430 112 38.0 B 92.1 J 72.6 J 11.3 J 29-Jun-11 5.0 100 --- 77.7 J 370 128 41.2 J 98.4 J 113 ND 01-Nov-11 5.0 100 --- 125 413 132 41.7 J ill 72.1 J ND 01-May-12 5.0 100 --- 78.8 J 323 121 40.0 J 99.7 J 66.1 J ND 07-Nov-12 0.39 100 --- --- 369 127 41.0 B 98.7 J --- 12.2 J 09-May-13 5.0 100 --- 78.6 J 307 112 40.0 J 85.6 J --- ND 07-Nov-13 5.0 100 --- --- 302 113 38.0 J 89.6 J --- ND 05-Jun-14 5.0 100 --- 60.3 J 285 117 39.2 J 80.3 J 75.0 J ND 20-Nov-14 2.5 100 --- --- 301 113 39.5 J 83.3 J 108 ND Beryllium 30-Dec-09 0.2 1.0 --- ND 0.5 J ND ND ND --- ND GWPS = 4 µg/L (10/23/07) 01-Jun-10 0.2 1.0 --- 0.6 J 0.7 J ND ND ND --- ND 29-Dec-10 0.10 1.0 --- ND ND ND ND ND 0.48 J ND 29-Jun-11 1.0 1.0 --- ND ND ND ND ND ND ND 01-Nov-11 1.0 1.0 --- ND ND ND ND ND ND ND 01-May-12 1.0 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.049 1.00 --- --- 0.34 J ND ND 0.099 J --- ND 09-May-13 1.0 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 1.0 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 1.0 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.5 1.0 --- --- ND ND ND ND ND ND Cadmium 30-Dec-09 0.2 1.0 --- ND 0.5 1 5.6 ND ND --- ND NC 2L = 2 µg/L (1/11/10) 01-Jun-10 0.2 1.0 --- 2.9 1.0 B 5.3 0.4 B 0.4 B --- 0.4 J 29-Dec-10 0.50 1.0 --- ND ND ND ND ND ND ND 29-Jun-11 1.0 1.0 --- ND ND ND ND ND ND ND 01-Nov-11 1.0 1.0 --- ND ND ND ND ND ND ND 01-May-12 1.0 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.026 1.00 --- --- 0.15 J ND ND 0.043 J --- ND 09-May-13 1.0 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 1.0 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 1.0 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.5 1.0 --- --- ND ND ND ND ND ND Chromium 30-Dec-09 0.7 10.0 --- ND 2.7 J 9.7 J ND 3.1 J --- ND NC 2L = 10 µg/L (1/11/10) 01-Jun-10 0.7 10.0 --- 3.5 J 1.6 J 12.4 1.2 J 3.2 J --- ND 29-Dec-10 0.40 10.0 --- 0.48 J 1.3 J 0.57 J ND 5.5 J 3.8 J ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND ND ND 01-Nov-11 5.0 10.0 --- ND ND ND ND 10.3 ND ND 01-May-12 5.0 10.0 --- ND ND ND ND 5.8 J ND ND 07-Nov-12 0.030 10.0 --- --- 0.71 J 0.12 B 0.094 B 7.31 1 --- 0.099 J 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 1 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample 11 Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-31) MW-4 MW-5 Blanks Cobalt 30-Dec-09 0.7 10.0 --- ND 6.4 J 11.2 ND 1.8 J --- ND GAPS = 70 µg/L (10/23/07) 01-Jun-10 0.7 10.0 --- 1.8 J 2.5 J 8.5 J ND 1.7 J --- ND GAPS = 1 µg/L (10/1/10) 29-Dec-10 0.60 10.0 --- ND 4.9 J 1.7 J ND 1.6 J 10.2 ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 9.9 J ND 01-Nov-11 5.0 10.0 --- ND ND ND ND ND 5.2 J ND 01-May-12 5.0 10.0 --- ND ND ND ND ND 13.9 ND 07-Nov-12 0.053 10.0 --- --- 1.98 J 3.89 J 0.43 B 2.02 J --- 0.24 J 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND 12.0 ND 20-Nov-14 2.5 10.0 --- --- ND 2.5 J ND ND 10.2 ND Copper 30-Dec-09 2.0 10.0 --- ND ND 10.6 ND 1.5 J --- ND NC 2L = 1,000 µg/L (10/23/07) 01-Jun-10 2.0 10.0 --- 12.2 B 3.3 B 33.2 3.9 B 6.8 B --- 4.8 J 29-Dec-10 0.30 10.0 --- ND ND 0.49 J 0.59 J 1.5 J 7.9 J ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 16.6 ND 01-Nov-11 5.0 10.0 --- ND ND ND ND 5.4 J ND ND 01-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.093 10.0 --- --- 3.56 B 0.54 B 0.98 B 1.83 B --- 1.23 J 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND 6.1 J ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND 5.3 J ND Lead 30-Dec-09 2.0 10.0 --- ND ND 10.2 ND ND --- ND NC 2L - 15 µg/L (10/23/07) 01-Jun-10 2.0 10.0 --- 9.1 B 8.2 B 8.7 B 3.0 B 3.9 B --- 3.2 J 29-Dec-10 4.0 10.0 --- ND ND ND ND ND 6.5 J ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 19.9 ND 01-Nov-11 5.0 10.0 --- 5.5 J ND ND ND ND ND ND 01-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.025 10.0 --- --- 1.00 B 0.091 B 0.066 B 1.12 B --- 0.58 J 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND 4.2 J ND Nickel 30-Dec-09 0.6 50.0 --- ND ND 8.1 J 1.8 J 1.6 J --- ND NC 2L = 100 µg/L (10/23/07) 01-Jun-10 0.6 50.0 --- ND ND 6.0 J ND 0.9 J --- ND 29-Dec-10 1.7 50.0 --- ND ND ND ND ND 2.0 B 3.1 J 29-Jun-11 5.0 50.0 --- ND ND ND ND ND ND ND 01-Nov-11 5.0 50.0 --- ND ND ND ND ND ND ND 01-May-12 5.0 50.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.26 50.0 --- --- 0.73 B 1.19 B 0.65 B 5.57 J --- 0.84 J 09-May-13 5.0 50.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 50.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 50.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 50.0 --- --- ND ND ND ND ND ND Selenium 30-Dec-09 6.3 10.0 --- ND ND 8.4 J ND ND --- ND NC 2L = 20 µg/L (1/11/10) 01-Jun-10 6.3 10.0 --- ND ND 6.3 J ND ND --- ND 29-Dec-10 3.8 10.0 --- ND ND ND ND ND ND ND 29-Jun-11 10.0 10.0 --- ND ND ND ND ND ND ND 01-Nov-11 10.0 10.0 --- ND ND ND ND ND ND ND 01-May-12 10.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.11 10.0 --- --- 0.16 J 0.38 J 0.20 J 0.25 J --- ND 09-May-13 10.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 10.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 10.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 5.0 10.0 --- --- ND ND ND ND ND ND Silver 30-Dec-09 1.1 10.0 --- ND 1.7 B 2.2 B ND ND --- 1.9 J NC 2L = 20 µg/L (1/11/10) 01-Jun-10 1.1 10.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.10 10.0 --- ND 1.8 J 0.36 J 0.19 J 0.23 J ND ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND ND ND 01-Nov-11 5.0 10.0 --- ND ND ND ND ND ND ND 01-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.017 10.0 --- --- 0.18 J ND ND 0.078 J --- ND 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 2 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample 11 Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-31) MW-4 MW-5 Blanks Thallium 30-Dec-09 2.7 5.5 --- ND ND ND ND ND --- 3.7 J GWPS = 0.28 µg/L (10/23/07) 01-Jun-10 2.7 5.5 --- ND ND ND ND ND --- ND GWPS = 0.2 µg/L (10/1/10) 29-Dec-10 3.0 5.5 --- ND 3.2 J ND ND 4.8 J ND ND 29-Jun-11 5.4 5.5 --- ND ND ND ND ND ND ND 01-Nov-11 5.4 5.5 --- ND ND ND ND ND ND ND 01-May-12 5.4 5.5 --- ND ND ND ND ND ND ND 07-Nov-12 0.060 5.50 --- --- 0.16 J ND ND 0.76 J --- ND 09-May-13 5.4 5.5 --- ND ND ND ND ND --- ND 07-Nov-13 5.4 5.5 --- --- ND ND ND ND --- ND 05-Jun-14 5.4 5.5 --- ND ND ND ND ND ND ND 20-Nov-14 5.0 5.5 --- --- ND ND ND ND ND ND Vanadium 30-Dec-09 0.4 25.0 --- ND 1.4 J 37.4 1.5 J 4.3 J --- ND GWPS = 3.5 µg/L (10/23/07) 01-Jun-10 0.4 25.0 --- 1.2 J 3.4 J 84.2 1.4 J 4.8 J --- ND GWPS = 0.3 µg/L (10/1/10) 29-Dec-10 0.20 25.0 --- 1.2 B 2.8 J 2.3 J 1.6 J 5.5 J 14.5 J 0.26 J 29-Jun-11 5.0 25.0 --- ND ND ND ND ND 22.0 J ND 01-Nov-11 5.0 25.0 --- 7.2 J ND ND ND 12.0 J 7.2 J ND 01-May-12 5.0 25.0 --- ND ND ND ND 7.2 J 7.6 J ND 07-Nov-12 0.085 25.0 --- --- 2.48 J 2.02 J 2.35 J 4.55 J --- ND 09-May-13 5.0 25.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 25.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 25.0 --- ND ND 11.4 J ND ND ND ND 20-Nov-14 2.5 25.0 --- --- ND 3.2 J ND ND 9.4 J ND Zinc 30-Dec-09 2.7 10.0 --- ND 10.1 B 204 15.9 B 24.8 B --- 5.8 J NC 2L - 1,000 µg/L (1/11/10) 01-Jun-10 2.7 10.0 --- 16.2 13.5 415 8.5 J 22.2 --- ND 29-Dec-10 0.40 10.0 --- 12.2 B 15.8 B 8.9 B ND 4.6 B 38.1 B 12.5 29-Jun-11 10.0 10.0 --- ND 23.6 B 22.3 B ND 15.5 B 91.2 10.5 01-Nov-11 10.0 10.0 --- 16.6 ND 40.0 ND 16.2 31.4 ND 01-May-12 10.0 10.0 --- ND ND 13.5 ND 10.2 12.0 ND 07-Nov-12 1.31 10.0 --- --- 8.61 J 5.20 J 3.98 J 4.65 J --- ND 09-May-13 10.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 10.0 10.0 --- --- 13.8 10.4 ND ND --- ND 05-Jun-14 10.0 10.0 --- ND ND 89.0 ND ND 19.4 ND 20-Nov-14 5.0 10.0 --- --- ND 20.9 ND ND 55.0 ND Organic Compounds Acetone 29-Jun-11 2.2 100 --- ND 2.3 B 2.4 B 3.9 B ND 3.8 B 5.3 J NC 2L = 6,000 µg/L (1/11/10) 01-Nov-11 2.2 100 --- ND ND ND ND ND ND 14.6 J 01-May-12 2.2 100 --- ND ND ND ND ND ND ND 07-Nov-12 0.193 100 --- --- ND ND ND ND --- ND 09-May-13 10.0 100 --- ND ND ND ND ND --- 12.0 J 07-Nov-13 10.0 100 --- --- ND ND ND ND --- ND 05-Jun-14 10.0 100 --- ND ND ND ND ND ND ND 20-Nov-14 10.0 100 --- --- ND ND ND ND ND ND Benzene 30-Dec-09 0.1 1.0 --- ND 8.4 0.3 J 0.4 J 0.3 J --- ND NC 2L = 1 µg/L (10/23/07) 01-Jun-10 0.1 1.0 --- ND 2.9 ND ND ND --- ND 29-Dec-10 0.25 1.0 --- ND 8.1 ND ND ND ND ND 29-Jun-11 0.25 1.0 --- ND 7.2 0.38 J 0.45 J 0.42 J ND ND 01-Nov-11 0.25 1.0 --- ND 8.6 ND ND ND ND ND 01-May-12 0.25 1.0 --- ND 6.7 0.36 J 0.45 1 0.42 J ND ND 07-Nov-12 0.111 1.0 --- --- 8.63 0.430 J 0.504 J 0.478 J --- ND 09-May-13 0.25 1.0 --- ND 5.2 0.27 J 0.32 J 0.30 J --- ND 07-Nov-13 0.25 1.0 --- --- 6.9 0.33 J 0.38 J 0.39 J --- ND 05-Jun-14 0.25 1.0 --- ND 6.0 ND 0.42 J 0.40 J ND ND 20-Nov-14 0.25 1.0 --- --- 6.2 0.30 J ND 0.32 J ND ND Bromoform 09-May-13 0.26 3.0 --- ND ND 0.37 B ND ND --- 0.37 J NC 2L = µg/L 4 (10/23/07) 07-Nov-13 0.26 3.0 --- ND ND ND ND --- ND 05-Jun-14 0.26 3.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.26 3.0 --- --- ND ND ND ND ND ND Chlorobenzene 30-Dec-09 0.1 3.0 --- ND 0.5 J 0.6 J ND ND --- ND NC 2L = 50 µg/L (10/23/07) 01-Jun-10 0.1 3.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.23 3.0 --- ND 0.61 J ND ND ND ND ND 29-Jun-11 0.23 3.0 --- ND 0.46 J 1.0 J 0.37 J ND ND ND 01-Nov-11 0.23 3.0 --- ND 0.59 J 1.1 J 0.37 J ND ND ND 01-May-12 0.23 3.0 --- ND {0.42{ J 0.94 B 0.38 B ND ND 0.30 {ND{ J 07-Nov-12 0.083 3.00 --- --- 0.468 J 1.30 J 0.476 J ND --- ND 09-May-13 0.23 3.0 --- ND 0.27 J 0.72 J 0.27 J ND --- ND 07-Nov-13 0.23 3.0 --- --- 0.42 J 0.97 J 0.38 J ND --- ND 05-Jun-14 0.23 3.0 --- ND 0.30 J 0.78 J 0.33 J ND ND ND 20-Nov-14 0.23 3.0 --- --- 0.37 J 0.95 J 0.36 J ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 3 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample 11 Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-31) MW-4 MW-5 Blanks Chloroethane 30-Dec-09 0.1 10.0 --- ND ND 0.5 J 0.5 J ND --- 0.1 J NC 2L = 3,000 µg/L (1 / 11 / 10) 01-Jun-10 0.1 10.0 --- ND ND 0.4 J ND ND --- ND 29-Dec-10 0.54 10.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.54 10.0 --- ND ND 0.77 J ND 0.57 J ND ND 01-Nov-11 0.54 10.0 --- ND ND 0.79 J ND ND ND ND 01-May-12 0.54 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.235 10.0 --- --- ND ND ND ND --- ND 09-May-13 0.54 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.54 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.54 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.54 10.0 --- --- ND ND ND ND ND ND 1,4-Dichlorobenzene 30-Dec-09 0.1 1.0 --- ND 3.8 2.2 2.3 3.1 --- ND NC 2L = 6 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 1.2 0.9 J ND 1.2 --- ND 29-Dec-10 0.33 1.0 --- ND 3.9 1.1 2.3 1.9 ND ND 29-Jun-11 0.33 1.0 --- ND 3.8 2.8 3.6 3.2 ND ND 01-Nov-11 0.33 1.0 --- ND 4.7 4.1 4.1 3.5 ND ND 01-May-12 0.33 1.0 --- ND 4.0 2.7 4.1 3.2 ND ND 07-Nov-12 0.083 1.00 --- --- 5.12 2.93 4.08 3.64 --- ND 09-May-13 0.33 1.0 --- ND 3.6 2.0 3.1 2.3 --- ND 07-Nov-13 0.33 1.0 --- --- 5.4 2.5 4.2 3.2 --- ND 05-Jun-14 0.33 1.0 --- ND 5.0 1.9 4.0 2.7 ND ND 20-Nov-14 0.33 1.0 --- --- 4.7 1.9 3.8 2.6 ND ND 1, 1 -Dichloroethane 30-Dec-09 0.2 5.0 --- ND 22.8 1.9 J 4.0 J 2.4 J --- ND NC 2L = 6 µg/L (1/11/10) 01-Jun-10 0.2 5.0 --- ND 11.0 1.1 J ND 1.2 J --- ND 29-Dec-10 0.32 5.0 --- ND 28.2 2.4 1 4.1 J 2.6 J ND ND 29-Jun-11 0.32 5.0 --- ND 25.0 2.5 J 3.9 J 2.6 J ND ND 01-Nov-11 0.32 5.0 --- ND 27.2 2.3 1 4.0 J 2.3 J ND ND 01-May-12 0.32 5.0 --- ND 22.6 2.0 J 3.8 J 2.0 J ND ND 07-Nov-12 0.208 5.0 --- --- 28.1 2.06 J 4.08 J ND --- ND 09-May-13 0.32 5.0 --- ND 18.7 1.4 1 3.0 1 1.6 J --- ND 07-Nov-13 0.32 5.0 --- --- 26.6 1.7 J 4.2 J 2.2 J --- ND 05-Jun-14 0.32 5.0 --- ND 21.9 1.4 1 3.9 J 1.9 J ND ND 20-Nov-14 0.32 5.0 --- --- 21.5 1.3 J 3.2 J 1.8 J ND ND 1,2-Dichloroethane 30-Dec-09 0.1 1.0 --- ND 1.2 0.7 J 1.2 ND --- ND NC 2L = 0.4 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.12 1.0 --- ND ND 0.82 J 1.1 ND ND ND 29-Jun-11 0.12 1.0 --- ND 0.76 J 0.86 J 1.3 ND ND ND 01-Nov-11 0.12 1.0 --- ND 0.95 J ND 1.3 ND ND ND 01-May-12 0.12 1.0 --- ND 0.71 J 0.70 J 1.1 ND ND ND 07-Nov-12 0.171 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.12 1.0 --- ND 0.50 J 0.49 J 0.81 J ND --- ND 07-Nov-13 0.12 1.0 --- --- 0.93 J 0.66 1 1.3 ND --- ND 05-Jun-14 0.12 1.0 --- ND 0.76 J 0.52 J 0.99 J ND ND ND 20-Nov-14 0.12 1.0 --- --- 0.68 J 0.47 1 0.81 J ND ND ND 1, 1 -Dichloroethylene 30-Dec-09 0.1 5.0 --- ND 0.4 J ND ND ND --- ND NC 2L = 7 µg/L (10/23/07) 01-Jun-10 0.1 5.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.56 5.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.56 5.0 --- ND ND ND ND ND ND ND 01-Nov-11 0.56 5.0 --- ND ND ND ND ND ND ND 01-May-12 0.56 5.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.208 5.00 --- --- ND ND ND ND --- ND NC 2L = 350 µg/L (04/01/2013) 09-May-13 0.56 5.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.56 5.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.56 5.0 --- ND 4.7 J ND ND ND ND ND 20-Nov-14 0.56 5.0 --- ND ND ND ND ND ND ND cis-1,2-Dichloroethee 30-Dec-09 0.1 5.0 --- ND 68.2 11.0 51.0 21.8 --- ND NC 2L = 70 µg/L (10/23/07) 01-Jun-10 0.1 5.0 --- ND 23.0 7.6 ND 10.2 --- ND 29-Dec-10 0.19 5.0 --- ND 66.7 16.8 56.7 24.1 ND ND 29-Jun-11 0.19 5.0 --- ND 55.1 16.5 62.7 25.1 ND ND 01-Nov-11 0.19 5.0 --- ND 59.4 15.2 59.3 23.2 ND ND 01-May-12 0.19 5.0 --- ND {48.7{ 14.2 59.5 22.1 ND 0.21 {ND{ J 07-Nov-12 0.103 5.00 --- --- 59.7 13.6 71.3 26.4 --- ND 09-May-13 0.19 5.0 --- ND 39.9 10.9 49.7 17.4 --- ND 07-Nov-13 0.19 5.0 --- --- 53.9 10.7 67.1 21.8 --- ND 05-Jun-14 0.19 5.0 --- ND 47.0 11.2 58.1 20.0 ND ND 20-Nov-14 0.19 5.0 --- --- 44.9 9.6 55.4 19.3 ND ND Town of Kernersville Landfill Permit No. 34-04 Page 4 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample 11 Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-31) MW-4 MW-5 Blanks trans-1,2-Dichloroethene 30-Dec-09 0.1 5.0 --- ND 1.4 J ND 0.2 J 0.2 J --- ND NC 2L = 100 µg/L (10/23/07) 01-Jun-10 0.1 5.0 --- ND 0.6 J ND ND ND --- ND 29-Dec-10 0.49 5.0 --- ND 1.7 J ND ND ND ND ND 29-Jun-11 0.49 5.0 --- ND 1.5 J ND ND ND ND ND 01-Nov-11 0.49 5.0 --- ND 1.6 J ND ND ND ND ND 01-May-12 0.49 5.0 --- ND 1.4 J ND ND ND ND ND 07-Nov-12 0.077 5.00 --- --- 1.59 J ND ND ND --- ND 09-May-13 0.49 5.0 --- ND 1.1 J ND ND ND --- ND 07-Nov-13 0.49 5.0 --- --- 1.6 J ND ND ND --- ND 05-Jun-14 0.49 5.0 --- ND 1.4 J ND ND ND ND ND 20-Nov-14 0.49 5.0 --- --- 1.4 J ND ND ND ND ND 1,2-Dichloropropane 30-Dec-09 0.1 1.0 --- ND 5.7 0.6 J 1.1 0.7 J --- ND NC 2L = 0.6 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 1.9 ND ND ND --- ND 29-Dec-10 0.27 1.0 --- ND 5.3 ND ND ND ND ND 29-Jun-11 0.27 1.0 --- ND 4.8 0.90 J 1.3 0.73 J ND ND 01-Nov-11 0.27 1.0 --- ND 4.9 0.76 J 1.3 ND ND ND 01-May-12 0.27 1.0 --- ND 4.4 0.76 J 1.4 0.62 J ND ND 07-Nov-12 0.150 1.0 --- --- 4.93 ND 1.66 ND --- ND 09-May-13 0.27 1.0 --- ND 3.3 0.51 J 0.96 J 0.45 J --- ND 07-Nov-13 0.27 1.0 --- --- 4.4 0.63 J 1.3 0.57 1 --- ND 05-Jun-14 0.27 1.0 --- ND 4.0 0.51 J ND 0.41 J ND ND 20-Nov-14 0.27 1.0 --- --- 4.1 0.56 J 1.2 0.36 J ND ND Ethylbenzene 30-Dec-09 0.1 1.0 --- ND ND ND 0.4 J ND --- ND NC 2L = 600 µg/L (10/23/07) 01-Jun-10 0.1 1.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.30 1.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.30 1.0 --- ND ND ND ND ND ND ND 01-Nov-11 0.30 1.0 --- ND ND ND ND ND ND ND 01-May-12 0.3 0 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.109 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.30 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.30 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.30 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.30 1.0 --- --- ND ND ND ND ND ND Tetrachloroethene 30-Dec-09 0.2 1.0 --- ND 1.2 ND ND ND --- ND NC 2L = 0.7 µg/L (10/23/07) 01-Jun-10 0.2 1.0 --- ND 1.4 ND ND ND --- ND 29-Dec-10 0.46 1.0 --- ND 2.8 ND ND ND ND ND 29-Jun-11 0.46 1.0 --- ND 3.6 ND ND ND ND ND 01-Nov-11 0.46 1.0 --- ND 2.9 ND ND ND ND ND 01-May-12 0.46 1.0 --- ND 3.0 ND ND ND ND ND 07-Nov-12 0.193 1.00 --- --- 2.52 ND ND ND --- ND 09-May-13 0.46 1.0 --- ND 1.9 ND ND ND --- ND 07-Nov-13 0.46 1.0 --- --- 1.8 ND ND ND --- ND 05-Jun-14 0.46 1.0 --- ND 2.3 ND ND ND ND ND 20-Nov-14 0.46 1.0 --- --- 1.1 ND ND ND ND ND Toluene 29-Jun-11 0.26 1.0 --- ND ND ND ND ND 0.76 J ND NC 2L = 600 µg/L (1 / 11 / 10) 01-Nov-11 0.26 1.0 --- ND ND ND ND ND ND ND 01-May-12 0.26 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.122 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.26 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.26 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.26 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.26 1.0 --- --- ND ND ND ND ND ND Trichloroethene 30-Dec-09 0.1 1.0 --- ND 8.0 ND ND 0.2 J --- ND NC 2L = 3 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 6.4 ND ND ND --- ND 29-Dec-10 0.47 1.0 --- ND 10.1 ND ND ND ND ND 29-Jun-11 0.47 1.0 --- ND 14.6 ND ND ND ND ND 01-Nov-11 0.47 1.0 --- ND 10.2 ND ND ND ND ND 01-May-12 0.47 1.0 --- ND 11.6 ND ND ND ND ND 07-Nov-12 0.161 1.00 --- --- 9.97 ND ND ND --- ND 09-May-13 0.47 1.0 --- ND 8.4 ND ND ND --- ND 07-Nov-13 0.47 1.0 --- --- 8.0 ND ND ND --- ND 05-Jun-14 0.47 1.0 --- ND 8.9 ND ND ND ND ND 20-Nov-14 0.47 1.0 --- --- 5.1 ND ND ND ND ND Trichlorofluoromethane 29-Jun-11 0.20 1.0 --- ND 0.95 J ND ND ND ND ND NC 2L = 2000 µg/L (1/11/10) 01-Nov-11 0.20 1.0 --- ND ND ND ND ND ND ND 01-May-12 0.20 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.157 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.20 1.0 --- ND 0.66 J ND ND ND --- ND 07-Nov-13 0.20 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.20 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.20 1.0 --- --- ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 5 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Analyte Sample Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks 11 Vinyl chloride 30-Dec-09 0.1 1.0 --- ND 4.0 2.8 4.1 26.2 --- ND NC 2L = 0.03 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 2.2 3.0 ND 26.7 --- ND 29-Dec-10 0.62 1.0 --- ND 3.5 2.4 4.7 25.6 ND ND 29-Jun-11 0.62 1.0 --- ND 2.8 2.8 4.6 28.7 ND ND 01-Nov-11 0.62 1.0 --- ND 5.1 2.6 6.9 24.0 ND ND 01-May-12 0.62 1.0 --- ND 3.5 2.0 4.8 21.8 ND ND 07-Nov-12 0.127 1.00 --- --- 7.94 2.73 6.99 29.9 --- ND 09-May-13 0.62 1.0 --- ND 2.8 1.9 4.2 18.6 --- ND 07-Nov-13 0.62 1.0 --- --- 6.3 2.1 6.0 21.9 --- ND 05-Jun-14 0.62 1.0 --- ND 7.1 5.6 8.9 21.9 ND ND 20-Nov-14 0.62 1.0 --- --- 5.2 2.1 5.3 16.2 ND ND Xylene (Total) 30-Dec-09 0.3 4.0 --- ND ND ND 3.5 J ND --- ND NC 2L = 500 µg/L (1/11/10) 01-Jun-10 0.3 4.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.66 2.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.66 2.0 --- ND ND ND ND ND ND ND 01-Nov-11 0.66 2.0 --- ND ND ND ND ND ND ND 01-May-12 0.66 2.0 --- ND 0.89 J ND ND ND ND ND 07-Nov-12 0.179 5.00 --- --- ND ND ND ND --- ND 09-May-13 0.66 5.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.66 5.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.66 5.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.66 5.0 --- --- ND ND ND ND ND ND Notes: 1. RL = Reporting limit (NC SWSL). 2. All concentrations are in micrograms per liter (ug/L). 3. NC 2L Standard is the groundwater quality standard established under 15A NCAC 2L. 4. MW = Monitoring well. 5. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. 6. ND = Not detected at the laboratory's detection limit. 7. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. 8. B = Probable field and/or laboratory contamination since the concentration is within five times the concentration reported in the associated quality control blanks. 9. Bold values are greater than the NC 2L Standard or GWPS. 10. DL = Detection limit. 11. GWPS = Groundwater Protection Standard (GWPS is used when the NC 2L Standard has not been established.) 12. --- = Monitoring well was no sampled. Town of Kernersville Landfill Permit No. 34-04 Page 6 of 6 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Inorganic Compounds Antimony 30-Dec-09 1.2 6.0 1.5 B 6.4 B NS 1.4 J NC 2B = NE µg/L (05/01/07) 01-Jun-10 1.2 6.0 6.7 B 2.5 B NS 3.9 J 29-Dec-10 2.6 6.0 ND ND ND ND 29-Jun-11 5.0 6.0 ND ND ND ND 01-Nov-11 5.0 6.0 ND ND ND ND 01-May-12 5.0 6.0 ND ND ND ND 07-Nov-12 0.48 6.0 ND ND ND ND 09-May-13 5.0 6.0 ND ND ND ND 07-Nov-13 5.0 6.0 ND ND ND ND 05-Jun-14 5.0 6.0 ND ND ND ND 20-Nov-14 3.8 6.0 ND ND ND ND Arsenic 07-Nov-12 0.094 10.0 0.17 B 0.26 B 0.24 B 1.0 J NC 2B = 50 µg/L (05/01/07) 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Barium 30-Dec-09 1.1 100 25.1 J 34 J NS 3.4 1 NC 2B = NE µg/L (05/01/07) 01-Jun-10 1.1 100 28.8 J 31.5 J NS 2.0 J 29-Dec-10 0.20 100 22.3 B 27.8 B 27.9 B 11.3 J 29-Jun-11 5.0 100 40.0 J 39.4 J 39.3 J ND 01-Nov-11 5.0 100 30.1 J 35.2 J 34.3 J ND 01-May-12 5.0 100 66.1 J 35.4 J 33.3 J ND 07-Nov-12 0.39 100 27.6 B 31.5 B 29.9 B 12.2 J 09-May-13 5.0 100 33.6 J 33.8 J 32.6 J ND 07-Nov-13 5.0 100 36.6 J 32.0 J 29.8 J ND 05-Jun-14 5.0 100 31.2 J 35.8 J 33.6 J ND 20-Nov-14 2.5 100 26.6 J 31.2 J 29.4 J ND Cadmium 30-Dec-09 0.2 1.0 ND ND NS ND NC 2B = 2 µg/L (05/01/07) 01-Jun-10 0.2 1.0 0.9 B 0.4 B NS 0.4 J 29-Dec-10 0.50 1.0 ND ND ND ND 29-Jun-11 1.0 1.0 ND ND ND ND 01-Nov-11 1.0 1.0 ND ND ND ND 01-May-12 1.0 1.0 ND ND ND ND 07-Nov-12 0.026 1.000 ND ND ND ND 09-May-13 1.0 1.0 ND ND ND ND 07-Nov-13 1.0 1.0 ND ND ND ND 05-Jun-14 1.0 1.0 ND ND ND ND 20-Nov-14 0.5 1.0 ND ND ND ND Chromium 30-Dec-09 0.7 10.0 ND ND NS ND NC 2B = 50 µg/L (05/01/07) 01-Jun-10 0.7 10.0 1.7 J 1.2 J NS ND 29-Dec-10 0.40 10.0 0.69 J 0.53 J 0.41 J ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.030 10.0 0.29 B 0.13 B 0.11 B 0.099 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND 2.7 J ND Town of Kernersville Landfill Permit No. 34-04 Page 1 of 3 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Cobalt 30-Dec-09 0.7 10.0 ND ND NS ND NC 2B = NE µg/L (05/01/07) 01-Jun-10 0.7 10.0 ND ND NS ND 29-Dec-10 0.60 10.0 ND 1.8 J 1.9 J ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.053 10.0 0.34 B 0.76 B 0.76 B 0.24 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Copper 30-Dec-09 2.0 10.0 ND ND NS ND NC 2B = 7 µg/L (05/01/07) 01-Jun-10 2.0 10.0 6.9 B 5.8 B NS 4.8 1 29-Dec-10 0.30 10.0 0.38 J ND ND ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.093 10.0 0.27 B 0.38 B 0.38 B 1.23 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Lead 30-Dec-09 2.0 10.0 ND ND NS ND NC 2B = 25 µg/L (05/01/07) 01-Jun-10 2.0 10.0 2.7 B 2.8 B NS 3.2 J 29-Dec-10 4.0 10.0 ND ND ND ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.025 10.0 0.071 B 0.049 B 0.060 B 0.58 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Nickel 07-Nov-12 0.26 50.0 0.46 B 0.39 B 0.35 B 0.84 J NC 2B = 88 µg/L (05/01/07) 09-May-13 5.0 50.0 ND ND ND ND 07-Nov-13 5.0 50.0 ND ND ND ND 05-Jun-14 5.0 50.0 ND ND ND ND 20-Nov-14 2.5 50.0 ND ND ND ND Vanadium 30-Dec-09 0.4 25.0 2.0 J 0.8 J NS ND NC 2B = NE µg/L (05/01/07) 01-Jun-10 0.4 25.0 2.2 J 2.4 J NS ND 29-Dec-10 0.20 25.0 0.67 B 0.37 B 0.62 B 0.26 J 29-Jun-11 5.0 25.0 ND ND ND ND 01-Nov-11 5.0 25.0 ND ND ND ND 01-May-12 5.0 25.0 ND ND ND ND 07-Nov-12 0.085 25.0 0.63 J 0.44 J 0.52 J ND 09-May-13 5.0 25.0 7.8 J 9.1 J 9.4 J ND 07-Nov-13 5.0 25.0 ND ND ND ND 05-Jun-14 5.0 25.0 ND ND ND ND 20-Nov-14 2.5 25.0 ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 2 of 3 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Zinc 30-Dec-09 2.7 10.0 6.7 B ND NS 4.7 J NC 2B = 50 µg/L (05/01/07) 01-Jun-10 2.7 10.0 6.7 J 8.7 J NS ND 29-Dec-10 0.40 10.0 ND 1.2 B 1.2 B 12.5 29-Jun-11 10.0 10.0 ND ND ND 10.5 01-Nov-11 10.0 10.0 ND ND ND ND 01-May-12 10.0 10.0 ND ND ND ND 07-Nov-12 1.31 10.0 ND ND 1.56 J ND 09-May-13 10.0 10.0 ND ND ND ND 07-Nov-13 10.0 10.0 ND ND ND ND 05-Jun-14 10.0 10.0 ND ND ND ND 20-Nov- 14 5.0 10.0 ND ND ND ND Organic Compounds Acetone 29-Jun-11 2.2 100 2.8 B 3.3 B 4.4 B 5.3 1 NC 2B = NE µg/L (05/01/07) 01-Nov-11 2.2 100 ND ND ND 14.6 1 01-May-12 2.2 100 ND ND ND ND 07-Nov-12 0.193 100 ND ND ND ND 09-May-13 10.0 100 ND ND ND 12.0 J 07-Nov-13 10.0 100 ND ND ND ND 05-Jun-14 10.0 100 ND ND ND ND 20-Nov-14 10.0 100 ND ND ND ND cis-1,2-Dichloroethene 30-Dec-09 0.1 5.0 ND ND NS ND NC 2B = NE µg/L (05/01/07) 01-Jun-10 0.1 5.0 ND ND NS ND 29-Dec-10 0.19 5.0 ND 0.39 J ND ND 29-Jun-11 0.19 5.0 0.26 J 0.30 J 0.33 J ND 01-Nov-11 0.19 5.0 ND ND ND ND 01-May-12 0.19 5.0 0.31 B ND ND 0.21 (ND) J 07-Nov-12 0.103 5.00 ND ND ND ND 09-May-13 0.19 5.0 ND ND ND ND 07-Nov-13 0.19 5.0 ND 0.38 J ND ND 05-Jun-14 0.19 5.0 ND 0.33 J ND ND 20-Nov-14 0.19 5.0 ND 0.49 J ND ND Notes: 1. RL = Reporting limit (NC SWSL). 2. All concentrations are in micrograms per liter (ug/L). 3. NC 2B Standard is the surface water quality standard. Classification is currently Freshwater Aquatic Life. 4. NS = Not sampled. 5. SMP = Surface water monitoring point. 6. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. 7. ND = Not detected at the laboratory's detection limit. 8. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. 9. B = Blank Qualifed 10. Shaded values are greater than the established NC 2B Surface Water Quality Standards. 11. DL = Detection limit. 12. NE = Not established. Town of Kernersville Landfill Permit No. 34-04 Page 3 of 3 Joyce Engineering TABLE 5 SUMMARY OF MNA CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 Alkalinity, Total as CaCO3 Jun-14 1000.0 5000 --- 4600 J 148000 147000 160000 186000 (ug/L) Nov-14 1000.0 5000 --- --- 159000 151000 159000 181000 Sulfate Jun-14 2000 250000 --- 6500 J ND ND ND ND (ug/L) Nov-14 1000 250000 --- --- 1760 J 1730 J 1870 J 1560 J Nitrogen, Nitrate Jun-14 20.0 1000 --- 72 J 56 J ND ND ND (ug/L) Nov-14 10.0 1000 --- --- 45 J ND ND ND Methane Jun-14 3.3 6.6 --- --- 5530 254 242 515 (ug/L) Nov-14 3.3 6.6 --- --- 4980 159 182 186 Chloride Jun-14 1000 1000 --- 2220 11200 25900 16800 15600 (ug/L) Nov-14 500 1000 --- --- 17100 27900 17300 17100 Total Organic Carbon Jun-14 1000 1000 --- 3100 10600 8300 1500 8200 (ug/L) Nov-14 500 1000 --- --- 2150 1750 1370 1100 Hydrogen Jun-14 0.13 0.6 --- --- 1.5 1.2 120 3.5 (nM) Nov-14 0.13 0.6 --- --- 2.0 1.1 4.4 1.4 BOD, 5 day Jun-14 2000 2000 --- ND ND ND ND ND (ug/L) Nov-14 2000 2000 --- --- 4900 ND ND ND Chemical Oxygen Demand Jun-14 12500 25000 --- ND ND ND ND ND (ug/L) Nov-14 12500 25000 --- --- ND ND 431000 ND Notes: MW = Monitoring well. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. ND = Not detected at the laboratory's detection limit. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. B = Probable field and/or laboratory contamination since the concentration is within five times the concentration reported in the associated quality control blanks. DL = Detection limit. QL = Quantitation limit (NC SWSL). --- = Monitoring well was not sampled. Town of Kernersville Landfill Permit No. 34-04 Page 1 of 1 Joyce Engineering TABLE 6: BIODEGRADATION SCREENING MATRIX Parameter Concentration in Plume Interpretation Possible Points Points Awarded with DP points Points Awarded without DP points Oxygen < 0.5 mg/L Tolerated, suppresses the reductive pathway at higher 3 0 0 concentrations > 5 mg/L Not tolerated; however, vinyl chloride may be oxidized -3 0 0 aerobically Nitrate < 1 mg/L At higher concentrations may compete with reductive 2 2 2 pathway Iron II (Ferrous Iron) > 1 mg/L Reductive pathway possible; vinyl chloride may be 3 0 0 oxidized under Fe (III) - reducing conditions Sulfate < 20 mg/L At higher concentrations may compete with reductive 2 2 2 pathway Sulfide > 1 mg/L Reductive pathway possible 3 0 0 Methane < 0.5 mg/L Vinyl chloride oxidizes 0 > 0.5 mg/L Ultimate reductive daughter product, vinyl chloride 3 0 0 accumulates Oxidation Reduction < 50 mV Reductive pathway possible 1 1 1 Potential < -100 mV Reductive pathway likely 2 pH 5 < pH < 9 Optimal range for reductive pathway 0 0 0 5 > pH > 9 Outside optimal range for reductive pathway -2 0 0 TOC > 20 mg/L Carbon and energy source; drives dechlorination; can 2 0 0 be natural or anthropogenic Temperature >200 C At T > 200C biochemical process is accelerated 1 0 0 Carbon Dioxide > 2x background Ultimate oxidative daughter product 1 0 0 Alkalinity > 2x background Results from interaction between CO2 and 1 1 1 aquifer minerals Chloride > 2x background Daughter product of organic chlorine 2 2 2 Hydrogen > 1 nM Reductive pathway possible 3 3 3 < 1 nM Vinyl chloride oxidizes 0 Volatile Fatty Acids > 0.1 mg/L Intermediates resulting from biodegradation of more 2 0 0 complex compounds; carbon and energy source BTEX > 0.1 mg/L Carbon and energy source; drives dechlorination 2 0 0 Tetrachloroethene (PCE) --- Material released 0 0 0 Trichloroethene (TCE) --- Material released 0 0 1 0 --- Daughter product of PCE 2 2 0 Dichloroethenes (DCE) --- Material released 0 0 0 Daughter product of TCE 2 2 0 Dichloroethene, cis-1,2, --- Material released 0 0 0 --- Daughter product of trichlorethene 2 2 0 Vinyl Chloride (VC) --- Material released 0 0 0 --- Daughter product of DCE 2 2 0 1, 1, 1 -Trichloroethane (TCA) --- Material released 0 0 0 1,1-Dichloroethane (DCA) --- Material released 0 0 0 Daughter product of TCA 2 2 0 Chloroethane --- Daughter product of dichloroethane or vinyl chloride 0 0 0 under reducing conditions 2 2 0 Ethene/Ethane > 0.01 mg/L Daughter products of vinyl chloride/ethene 2 0 0 > 0.1 mg/L 3 0 0 Chloroform --- Material released 0 0 0 --- Daughter product of carbon tetrachloride 2 0 0 Dichloromethane (MC) --- Material released 0 0 0 (Methylene Chloride) --- Daughter product of chloroform 2 0 0 Based on data collected in November 2014. Total Points Awarded: 23 11 mg/L = miligrams per liter mV = millivolts nM = Nanometer C = Celcius NOTE: Chloroethane, Methane, TCE, DCE, cis-1,2-DCE, MC, VC, DCA, and CO2 are all present in the plume; however, it is uncertain whether these are primary leachate constituents or daughter products (DPs); therefore, we have two calculation columns. The first column assumes all of these are daughter products, and the NA = Not Analyzed I second column assumes none of them are. The true score is probably between the two. BTEX = Sum of Benzene, Toluene, Ethylbenzene, and Total Xylenes This screening matrix is prepared in general accordance with the United Stated Environmental Protection Agency's (EPA's) Table 2.3 Analytical Parameters and Weighted for Preliminary Screening for Anaerobic Biodegradation Process presented in the EPA's Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Groundwater, September 1988. SCORE: Evid. of Nat. Atten. < 5 inadequate 6-14 limited 15-19 adequate > 20 strong Town of Kernersville Joyce Engineering