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1201_BurkeCounty_KirkseyDr_MSWLF_May20GW_FID1450236_20200827
L pENR USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No) Doc/Event #: r NC DENR I IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. • Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). • Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. • Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): LaBella Associates (Joyce Engineering) Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: G. Van Ness Burbach. Ph.D.. P.G. Phone: (336) 323-0092 E-mail: vburbach@ilabellapc.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or. 1600) October 20-24, 2006) Kirksey Drive May 5-7, 2020, July Burke Co. - Kirksey Dr. Landfill Morganton, NC 12-01 .0500 16,2020 Environmental Status: (Check all that apply) Initial/Background Monitoring X❑ Detection Monitoring ❑ Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Methane gas monitoring data Groundwater monitoring data from private water supply wells Corrective action data (specify) Leachate monitoring data ❑ Surface water monitoring data Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. K Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. G. Van Ness Burbach, Ph.D., P.G. Technical Consultant (336) 323-0092 2211 W. Meadowview Rd., Ste. 101 Greensboro, NC 27407 Facility Representative Address C-0782 NC PE Firm License Number (if applicable effective May 1, 2009) Q—A-4 al9nno !a Code) Telephone Number Affix NC Licensed/ Professional Geologist Seal 'o Z J349 C At E G' c,P% 01 � Wt'QC A9 LaBeRa Powered by oartnershio. August 24, 2020 Ms. Jackie Drummond North Carolina Department of Environmental Quality Division of Waste Management, Solid Waste Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Via Email: jaclynne.drummond@ncdenr.gov RE: May 2020 Semiannual Water Quality Monitoring Report Burke County Kirksey Drive Landfill, Permit No. 12-01 Project No. 2202300 Dear Ms. Drummond: Please find the attached May 2020 Semiannual Groundwater Monitoring Report for the Burke County Kirksey Drive Landfill (Permit No. 12-01). Attached are electronic versions of the complete report and all appendices for the May 2020 sampling event. Also attached is the North Carolina Environmental Monitoring Reporting Form and the laboratory EDD's. If you wish to have a hard copy of the report, drawings, or appendices, we will be happy to provide them upon your request. Please feel free to contact me at (336) 323-0092 if you have any questions regarding this report. Respectfully submitted, LaBella Associates rzo�t-lr--� Van Burbach, Ph.D., P.G. Sr. Technical Consultant Enclosure Cc: Miles Champion - Burke County 2211 W. Meadowview Road #sos I Greensboro, NC 27407 1 p (336) 323-0092 www.tabettapc.com Prepared For: BOARD OF COMMISSIONERS COUNTY OF BURKE P.O. BOX 1486 MORGANTON, NORTH CAROLINA 28680 L ii 1i;a r. is R' 1* �j Submitted by: LaBella Associates (Joyce Engineering) 2211 West Meadowview Rd. Suite 101 Greensboro, NC 27407 (336) 323-00g2 NC License No. C-0782 LaBeRa Powered by partnership. MAY 2020 SEMIANNUAL WATER QUALITY MONITORING REPORT KIRKSEY DRIVE LANDFILL Permit No. 12-01 AUGUST 2020 PROJECT NO. 2202300 May 2020 Semiannual Water Quality Monitoring Report Kirksey Drive Landfill Burke County, North Carolina TABLE OF CONTENTS 1.0 INTRODUCTION.................................................................................................................1 1.1 Site Information................................................................................................................ 1 1.2 Site Geology........................................................................................................................ 1 1.3 Regulatory Status............................................................................................................... 2 2.0 FACILITY MONITORING PROGRAM...................................................................................2 2.1 Groundwater Monitoring Program.................................................................................... 2 2.2 Surface Water Monitoring Program.................................................................................. 2 3.0 MAY 2020 SEMIANNUAL SAMPLING EVENT...................................................................3 3.1 Field Work...........................................................................................................................3 3.2 Laboratory Analysis and Quality Control........................................................................... 4 4.0 HYDROGEOLOGY..............................................................................................................4 5.0 DATA ANALYSIS................................................................................................................6 5.1 Analytical Results and Comparison to Standards............................................................ 6 5.1.1 Groundwater............................................................................................................6 5.1.2 Surface Water..........................................................................................................6 7.0 REFERENCES....................................................................................................................7 Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2020 Semiannual Water Quality Monitoring Report August 2020 i May 2020 Semiannual Water Quality Monitoring Report Kirksey Drive Landfill Burke County, North Carolina TABLE OF CONTENTS CONTINUED Tables Table 1 May 2020 Groundwater Elevations Table 2 May 2020 Estimated Hydraulic Gradients and Velocities Table 3 May 2020 Detections of Constituents Table 4 May 2020 Exceedances of Standards Table 5 May 2020 Field Parameters Figure Figure 1 Site Location Map Drawing Drawing 1 Groundwater Potentiometric Surface Map Appendices Appendix 1 Laboratory Analytical Reports and Field Logs Appendix 2 Historical Data Table A2-1 Historical Groundwater Elevations Table A2-2 Historical Groundwater Constituents Table A2-3 Historical Groundwater Field Parameters Table A2-4 Historical Surface Water Constituents Table A2-5 Historical Surface Water Field Parameters Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2020 Semiannual Water Quality Monitoring Report August 2020 ii 1.0 INTRODUCTION 1.1 Site Information The Kirksey Drive Sanitary Landfill, Permit No. 12-01, is located in Burke County, North Carolina, approximately two miles northwest of downtown Morganton, North Carolina. The Landfill is on Kirksey Drive, which is accessed by U.S. Highway 70 (Figure 1). The landfill was operated by Burke County as a municipal solid waste (MSW) landfill between 1968 and 1985 but has been closed since 1985. 1.2 Site Geology The Kirksey Drive Landfill is located in the Inner Piedmont Belt of the Piedmont Physiographic Province in western North Carolina. The Inner Piedmont Belt is separated from the Blue Ridge Belt to the northwest by the Brevard Fault Zone and from the Charlotte and Milton Belts to the east by the Kings Mountain Shear Zone. The Inner Piedmont Belt consists primarily of amphibolite facies metamorphic rock. The rocks are predominantly thinly layered mica schist and biotite gneiss interlayered with lesser amounts of amphibolite, calc-silicate rock, hornblende gneiss, quartzite, and in rare instances, marble (Goldsmith, et. al., 1989). Protoliths of Inner Piedmont Belt rocks were mostly sedimentary (graywacke) with intermediate volcanic flows and tuffs. Numerous large and small bodies of granite and granodiorite and a few quartz diorite bodies are scattered throughout the Inner Piedmont. The history of emplacement of igneous intrusives and of structural deformation in the Inner Piedmont is complex. The rocks have been extensively folded, sheared, and faulted. Granite dikes and larger granite masses have been emplaced along shear zones and discordances. A major east -west trending lineament coincides with the course of the Catawba River in Caldwell, Burke, and Alexander Counties, but no offset has been documented. According to Goldsmith et al. (1978), the site is located in an area underlain by a rock unit comprised of gneisses and schists of various compositions, calc-silicates, and felsic metavolcanics. This unit occupies the nose of a northeast -plunging broad synclinal feature, surrounded by a unit mapped as foliated -to -massive migmatitic granitic gneiss with biotite gneiss and amphibolite, approximately three miles to the northwest and one mile to the south. Map patterns suggest that regional metamorphic foliation near the site would be generally east -west, with gentle dips. Outcrop foliations are likely to have steeper dips, with northeast -trending strikes parallel to the map -scale folds shown on the regional map of Goldsmith, et al. Approximately three miles to the east of the site is a small area around Rhodhiss Lake that has been mapped as metamorphosed granitic rock. A major diabase dike system, oriented northwest -southeast, has been mapped over a distance of more than 40 miles and passes approximately two miles to the northeast of the site. Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2020 Semiannual Water Quality Monitoring Report August 2020 1 1.3 Regulatory Status The landfill is regulated under Rules .0500 and .0600 of the North Carolina Solid Waste Management Regulations (NCSWMR) for MSW landfills closed prior to October 9, 1993. The County monitors groundwater at the landfill in accordance with criteria set forth in Rule .0600 of the NCSWMR. 2.0 FACILITY MONITORING PROGRAM 2.1 Groundwater Monitoring Program Groundwater monitoring at the Kirksey Drive Landfill is completed in accordance with the monitoring requirements of Rule .0600 of the NCSWMR. Eight active groundwater monitoring wells comprise the groundwater monitoring network at the Kirksey Drive Landfill and groundwater samples are collected semiannually. The current compliance network consists of the following monitoring wells: MW-1 (background), MW-2, MW-3D, MW-3S, MW-4, MW-5, MW-6D, and MW-6S. Well classification and monitored geologic unit of the upper most aquifer is summarized in the table below. A site plan indicating the facility and waste boundaries in addition to monitoring well locations can be found in Drawing 1. All monitoring wells are monitored the constituents listed in Appendix I of 40 CFR Part 258 (NC Appendix 1) plus 1,4-dioxane. Well MW-1 was damaged and has not been able to be sampled since June 2017. Monitoring Well Date Installed Classification Monitoring Program Total Depth from TOC (feet) Lithology of Screened Interval MW-1 1992 Background .0600 35.65 Saprolite MW-2 1992 Compliance .0600 45.70 Saprolite MW-3D Feb. 27, 1998 Compliance .0600 78.40 Bedrock MW-3S 1992 Compliance .0600 26.69 Bedrock MW-4 Feb. 24, 1998 Compliance .0600 29.50 Saprolite MW-5 Feb. 24, 1998 Compliance .0600 49.80 Saprolite MW-6D Apr. 7, 2000 Compliance .0600 60.00 Bedrock MW-6S Apr. 6, 2000 Compliance .0600 25.00 Saprolite 2.2 Surface Water Monitoring Program Surface water monitoring at the Kirksey Drive Landfill is completed in accordance with the monitoring requirements of Rule .0600 of the NCSWMR. Three surface water monitoring points (SMP-1, SMP-2, and SMP-3) comprise the surface water monitoring program for the Kirksey Drive Landfill. The locations of the monitoring points are shown on Drawing 1. The NC Division of Water Resources has classified the surface water at the Kirksey Drive landfill as water supply IV. All surface water monitoring points are monitored semiannually for the NC Appendix I list of constituents plus 1,4-dioxane. Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2020 Semiannual Water Quality Monitoring Report August 2020 2 Surface Point Classification Monitoring Location Program SW-1 (SMP-1) Compliance .0600 Upstream of bridge on Quarry Rd. SW-2 (SMP-2) Compliance .0600 Downstream of SW-3 SW-3 (SMP-3) Compliance .0600 24" pipe @ base of landfill along river 3.0 MAY 2020 SEMIANNUAL SAMPLING EVENT 3.1 Field Work On May 5-6, 2020, personnel from LaBella visited the Kirksey Drive Landfill to purge and sample monitoring wells MW-2, MW-3D, MW-3S, MW-4, MW-5, MW-6D, and MW-6S. Well MW-1 is damaged and was not able to be monitored during this sampling event. This well should be evaluated for replacement. Depth -to -water measurements were obtained to the nearest 0.01 foot using an electronic water level indicator for all monitoring wells in the compliance network prior to purging. Groundwater elevations for the May 2020 monitoring event can be found in Table 1. Monitoring wells were purged using either disposable bailers, or a 12-volt submersible pump. Measurements of temperature, pH, specific conductivity, dissolved oxygen, oxidation reduction potential, and turbidity were recorded in the site log book and on field log forms prior to purging, after each purge volume, and at the time of sampling. Field data logs are included in Appendix 1. Prior to sampling, laboratory -supplied containers were prepared with the following information: • Monitoring well number (completed by field personnel); • Date and time of sample collection (completed by field personnel); • Initials of sampling personnel (completed by field personnel); • Project name and number (completed by the laboratory); • Chemical preservative (completed by the laboratory); and • Requested chemical analysis (completed by the laboratory). Groundwater samples from each monitoring well were collected either directly from the disposable bailers or directly from the pump discharge tube in the provided laboratory containers either immediately after purging or within 24 hours of the final purge volume. Immediately after collection, the samples were placed on ice in a cooler. A resampling event to confirm suspect detections of vanadium and thallium in MW-5 was conducted on July 16, 2020. MW-5 was sampled using a portable bladder pump and using low -flow sampling methodology. Surface monitoring points SW-1, SW-2 and SW-3 were sampled during the May 2020 monitoring event. The surface water samples were collected directly from the stream by lowering a clean, unpreserved sample container into the stream flow and dispensing the water into laboratory -prepared sample containers. Care was taken to Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2020 Semiannual Water Quality Monitoring Report August 2020 3 avoid sample -induced turbidity. At the time of sampling, surface water was also measured for temperature, pH, specific conductivity, dissolved oxygen, oxidation reduction potential, and turbidity and recorded in the site log book. Immediately after sample collection, the samples were placed on ice in a laboratory -provided cooler. Field sampling logs are provided in Appendix 1. 3.2 Laboratory Analysis and Quality Control The May 2020 groundwater and surface water samples were submitted to Pace Analytical Services, Inc. of Huntersville, North Carolina under chain -of -custody control for analysis. LaBella requested a Level II data report for the final laboratory report. According to laboratory sample receipts, the samples were received by the laboratory in good condition, properly preserved, at proper temperature, and within analysis hold times. In addition to samples collected for compliance monitoring at the Kirksey Drive Landfill, a Field Blank was collected by LaBella personnel as part of the sampling event. Also, a Trip Blank was prepared by the laboratory to accompany the volatile sampling during shipment. The Field Blank was analyzed for the NC Appendix I list compounds while the Trip Blank was analyzed for NC Appendix I VOCs only, and both were analyzed for 1,4-dioxane. Upon receipt of the laboratory data package, the data was reviewed by LaBella personnel for the following: • General typographical errors; • Correct analyses performed and within method specified hold times; • Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate, and Laboratory Control Samples; • Blank qualified data (B-flags); • Detections above the Method Reporting Limits (MRL); • Detections above the 15A NCAC 2L Groundwater Standards (NC2L), NC Interim Maximum Allowable Concentrations (IMACs), 15A NCAC 2B Surface Water Standards (NC2B), or NC In -stream Target Values (ISTV); and • Detections that are above historical levels. Review of the laboratory analytical reports indicated that the laboratory data package was acceptable. The complete analytical data packages and chains -of -custody are included in Appendix 1. 4.0 HYDROGEOLOGY The surficial aquifer is believed to include the regolith and the underlying fractured metamorphic bedrock. The regolith consists of residual soils, saprolite, and variably fractured and weathered layered metamorphic rock. In this regard, regolith behaves Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2020 Semiannual Water Quality Monitoring Report August 2020 4 similar to unweathered bedrock, except that fractures are more numerous and better connected in the regolith, and will tend to have more isotropic hydraulic properties. Groundwater discharges into Hunting Creek to the east of the site, which flows northward to the Catawba River. A groundwater potentiometric surface map, developed from static water level data obtained in May 2020, is presented as Drawing 1. Horizontal groundwater gradients along representative flow paths were estimated from the May 2020 groundwater contours shown on Drawing 1 and are summarized in Table 2. Horizontal gradients across the site ranged from 0.050 to 0.072, with an average of approximately 0.058. Linear groundwater flow velocities for wells screened in saprolite were computed using the modified Darcy equation: V = Ki/ne Where; V = average linear velocity, K = hydraulic conductivity, i = horizontal hydraulic gradient and ne = effective porosity. The mean of hydraulic conductivities from slug -tests conducted at the Burke County John's River facility (K = 3.28 ft/day) was used in these calculations, along with an estimated effective porosity of ne = 0.20 (20%) for regolith. The estimated linear groundwater flow velocity under the facility ranged from 300 to 433 feet/year, with an average flow velocity of approximately 346 feet/year (Table 2). Because of our conservative estimate of effective porosity, actual groundwater velocities may be significantly less than those calculated. Also, the modified Darcy equation makes the simplifying assumptions of a homogeneous and isotropic aquifer, which may yield inaccurate results when applied to heterogeneous and/or anisotropic conditions such as are believed to exist at this site. Migration of groundwater contaminants are expected to follow the general groundwater flow paths and there are no known barriers to groundwater flow that could significantly affect plume migration or the effectiveness of the groundwater monitoring network to monitoring plume migration. The current groundwater monitoring network remains sufficient for monitoring the groundwater at this facility. Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2020 Semiannual Water Quality Monitoring Report August 2020 5 5.0 DATA ANALYSIS 5.1 Analytical Results and Comparison to Standards 5.1.1 Groundwater Inorganic and organic constituents detected in the groundwater during the May 2020 monitoring event are listed in Table 3. Results with quantified concentrations above their respective NC2L or IMAC are presented in Table 4. Field parameter data from the May 2020 event are summarized in Table 5. Historically detected groundwater constituents can be found in Appendix 2 (Table A2-2), and historical groundwater field parameters can be found in Appendix 2 (Table A2-3). During the May 2020 monitoring event, the constituents detected at quantified concentrations above the MRL in the groundwater samples included: barium (all monitoring wells); cobalt (MW-2, MW-3S); nickel (MW-2, MW-3D, MW-3S); thallium (MW-5); vanadium (MW-5); zinc (MW-5); acetone (MW-2); chlorobenzene (MW-2, MW- 3S, MW-3D); ethylbenzene (MW-2); toluene (MW-2); tetrachloroethene (MW-3D); trichloroethene (MW-3D); xylenes (MW-2, MW-3S); 1,1-dichloroethane (MW-3D); 1,2- dichlorobenzene (MW-2); 1,4-dichlorobenzene (MW-2, MW-3S, MW-3D); 2-butanone (MW-2); 4-methyl-2-pentanone (MW-2); 1,4-dioxane (MW-2, MW-3S, MW-3D); and cis- 1,2-dichloroethene (MW-3D, MW-4). The constituents detected at quantified concentrations in exceedance of their respective NC2L or IMAC during the May 2020 sampling event include: barium (MW-2); cobalt (MW-2, MW-3S); vanadium (MW-5); benzene (MW-2, MW-3S, MW-3D), tetrachloroethene (MW-3D), trichloroethene (MW-3D); 1,4-dichlorobenzene (MW-2, MW-3S); and 1,4-dioxane (MW-2, MW-3S, MW-3D). The results July 2020 resampling event for MW-5 were non -detect for both thallium and vanadium, refuting the initial detections. In general, these results are consistent with historical data for the site (Appendix 2, Table A2-2). 5.1.2 Surface Water Inorganic and organic constituents detected in the surface water during the May 2020 monitoring event are presented in Table 3. Historically detected surface water constituents can be found in Appendix 2 (Table A24), and historical surface water field parameters can be found in Appendix 2 (Table A2-5). Barium was the only constituent detected in any of the surface water samples during the May 2020 sampling event. The NC Division of Water Resources has classified the surface water at the Kirksey Drive landfill as Water Supply IV. There were no organic or inorganic constituents detected at quantified concentrations above their respective NC213 Standards or ISTV for class WS-IV waters during this sampling event. Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2020 Semiannual Water Quality Monitoring Report August 2020 6 6.0 CONCLUSION The Burke County Kirksey Drive Landfill will continue monitoring groundwater in accordance with criteria set forth in Rules .0500 and .0600 of the NCSWMR for MSW landfills closed prior to October 9, 1993. The next scheduled semiannual sampling event is tentatively scheduled for November -December 2020. 7.0 REFERENCES Goldsmith, R., Milton, D.J., and Wilson, F.A., 1978, Preliminary geologic map, geologic map index, and annotated bibliography, Charlotte 1x2 degree sheet, North and South Carolina, U.S.G.S. Open File Report 78-590. Goldsmith, R., Milton, D.J., and Horton J.W., 1989, Geology of the Charlotte 1x2 degree quadrangle, in Gair, J.E., eds., Mineral resources of the Charlotte 1x2 degree quadrangle, North and South Carolina: U.S.G.S. Professional Paper 1462. Harned, Douglas A., 1989, The Hydrogeologic Framework and a Reconnaissance of Ground -Water Quality in the Piedmont Province of North Carolina, U.S. Geological Survey, Water Resources Investigations Report 88-4130 Heath, R.C., 1989, The Piedmont ground -water system, in Ground Water in the Piedmont; Edited by Daniel, C.,White, R., and Stone, P., Proceedings published by Clemson University, pp. 1-13. Joyce Engineering, Inc., October 29, 1999. Water Quality Assessment Plan. Prepared for Burke County Kirksey Drive Landfill. LeGrand, Harry E. Sr., 1989, A Conceptual Model of Ground Water Settings in the Piedmont Region, Conference on Ground Water in the Piedmont, Charlotte, North Carolina North Carolina Dept. Environment, Health, and Natural Resources (NCDEHNR), 1995, N.C. Water Quality Monitoring Guidance Document for Solid Waste Facilities. Sumsion, C.T., and Laney, R.L., 1967, Geology and ground -water resources of the Morganton area North Carolina, N.C. Department of Water Resources, Ground Water Bulletin No. 12, P. 119 RCRA Ground Water Monitoring Technical Enforcement Guidance Document (TEGD), 1986. Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2020 Semiannual Water Quality Monitoring Report August 2020 7 TABLES Table 1 Table 2 Table 3 Table 4 Table 5 May 2020 Groundwater Elevations May 2020 Estimated Hydraulic Gradients and Velocities May 2020 Detections of Constituents May 2020 Exceedances of Standards May 2020 Field Parameters TABLE 1: May 2020 Groundwater Elevations Location TOC Elevation (Ft-AMSL) Depth to Groundwater (Ft-BTOC) Lithology Well Depth (Ft-BTOC) Groundwater Elevation (Ft-AMSL) MW-1 1119.82 --- Saprolite 35.65 --- MW-2 1077.23 26.00 Saprolite 45.70 1051.23 MW-3S 1022.76 5.68 Bedrock 26.69 1017.08 MW-3D 1021.90 0.00 Bedrock 78.40 1021.90 MW-4 1054.99 18.90 Saprolite 29.50 1-036.09 MW-5 1137.43 35.66 Saprolite 49.80 1101.77 MW-6S 1065.00 9.75 Bedrock 25.00 1055.25 MW-6D 1065.00 11.62 Saprolite 60.00 1053.38 Notes: TOC = Top of casing Ft-BTOC = Feet below TOC Ft-AMSL = Feet above mean sea level --- = well damaged, not sampled. Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 TABLE 2: May 2020 Hydraulic Gradients and Velocities Water Levels Measured: May 5, 2020 GRADIENT CALCULATION SEGMENT FLOW LINE LENGTH (feet) FLOW DIRECTION GROUNDWATER ELEVATION (feet) HORIZONTAL GRADIENT ► HYDRAULIC CONDUCTIVITY K (feet/day) EFFECTIVE POROSITY n LINEAR VELOCITY V (feet/year) 1100 11 1,105 NW 0.0724 3.28E+00 0.20 433 1020 1090 12 1,196 NE 0.0502 3.28E+00 0.20 300 1030 1090 13 987 N 0.0507 3.28E+00 0.20 303 1040 AVERAGE: 0.0577 AVERAGE: 346 Notes: The mean of K estimates from individual well slug tests from the Burke Co. John's River facility was used to calculate the hydraulic conductivity. Velocity: V= Kiln ; assumes homogeneous isotropic porous aquifer and an effective porosity of 20% (0.20). Gradient segments based on the December 03, 2018 groundwater potentiometric surface map (Drawing 1) . Burke County, Kirksey Drive Landfill Permit No. 12-01 LaBella Associates TABLE 3: Detections of Constituents SAMPLE ID PARAMETER RESULT UNITS METHOD MDL MRL Standard Source DATE Barium 1160 pg/L EPA 6010D 3.5 5 700 NC2L Cobalt 106 pg/L EPA 6010D 3.6 5 1 IMAC Nickel 14.4 pg/L EPA 6010D 3.5 5 100 NC21- Selenium 9.2 J pg/L EPA 6010D 4.7 10 20 NC21- Acetone 255 pg/L EPA 8260D 6.2 25 6,000 NC21- Benzene 9.6 pg/L EPA 8260D 0.15 1 1 NC2L 1,4-Dichlorobenzene 39.0 pg/L EPA 8260D 0.26 1 6 NC21- 1,4-Dioxane (p-Dioxane) 213 pg/L EPA 8260D Mod. 5.8 10 3 NC21- MW-2 4-Methyl-2-pentanone (MIBK) 187 pg/L EPA 8260D 4.5 5 40 IMAC 5/6/2020 1,1-Dichloroethane 0.61 J pg/L EPA 8260D 0.27 1 6 NC21- 1,2-Dichlorobenzene 2.2 pg/L EPA 8260D 0.29 1 20 NC21- 2-Butanone (MEK) 222 pg/L EPA 8260D 3.3 5 4,000 NC2L Chlorobenzene 26.7 pg/L EPA 8260D 0.23 1 50 NC21- cis-1,2-Dichloroethene 0.41 J pg/L EPA 8260D 0.29 1 70 NC2L Ethylbenzene 17.0 pg/L EPA 8260D 0.26 1 600 NC21- Toluene 2.5 pg/L EPA 8260D 0.24 1 600 NC21- Xylene (Total) 34.0 pg/L EPA 8260D 0.63 1 500 NC21- Barium 194 pg/L EPA 6010D 3.5 5 700 NC21- Nickel 24.1 pg/L EPA 6010D 3.5 5 100 NC21- Benzene 1.4 pg/L EPA 8260D 0.15 1 1 NC21- 1,2-Dichloropropane 0.84 J pg/L EPA 8260D 0.19 1 0.6 NC21- 1,4-Dioxane (p-Dioxane) 111 pg/L EPA 8260D Mod. 2.3 4 3 NC2L Tetrachloroethene 8.1 pg/L EPA 8260D 0.16 1 0.7 NC2L MW-3D Trichloroethene 5.0 pg/L EPA 8260D 0.22 1 3 NC2L 5/6/2020 1,1-Dichloroethane 4.8 pg/L EPA 8260D 0.27 1 6 NC21- 1,4-Dichlorobenzene 4.1 pg/L EPA 8260D 0.26 1 6 NC21- Chlorobenzene 8.2 pg/L EPA 8260D 0.23 1 50 NC21- cis-1,2-Dichloroethene 16.4 pg/L EPA 8260D 0.29 1 70 NC2L Vinyl chloride 0.88 J pg/L EPA 8260D 0.24 1 0.03 NC2L Barium 486 pg/L EPA 6010D 3.5 5 700 NC21- Cadmium 0.51 J pg/L EPA 6010D 0.4 1 2 NC2L Cobalt 16.8 pg/L EPA 6010D 3.6 5 1 IMAC Nickel 5.4 pg/L EPA 6010D 3.5 5 100 NC21- Benzene 3.7 pg/L EPA 8260D 0.15 1 1 NC21- MW-3S 1,4-Dichlorobenzene 10.7 pg/L EPA 8260D 0.26 1 6 NC21- 5/6/2020 1,4-Dioxane (p-Dioxane) 33.3 pg/L EPA 8260D Mod. 1.2 2 3 NC21- 1,2-Dichlorobenzene 0.64 J pg/L EPA 8260D 0.29 1 20 NC21- Chlorobenzene 32.3 pg/L EPA 8260D 0.23 1 50 NC2L Chloroethane 1.6 pg/L EPA 8260D 0.49 1 3,000 NC21- Xylene (Total) 15.1 pg/L EPA 8260D 0.63 1 500 NC21- Barium 71.2 pg/L EPA 6010D 3.5 5 700 NC2L MW 4 1,1-Dichloroethane 0.48 J pg/L EPA 8260D 0.27 1 6 NC2L cis-1,2-Dichloroethene 2.6 pg/L EPA 8260D 0.29 1 70 NC2L 5/6/2020 Tetrachloroethene 0.69 JI pg/L I EPA 8260D 1 0.16 1 1 0.7 1 NC21- Burke Co. - Kirksey Dr. Landfill Permit # 12-01 Page 1 of 2 LaBella Associates TABLE 3: Detections of Constituents SAMPLE ID PARAMETER RESULT UNITS METHOD MOIL MRL Standard Source DATE Barium 55.4 pg/L EPA 6010D 3.5 5 700 NC21- Selenium 7.2 J pg/L EPA 6010D 4.7 10 20 NC21- MW-5 Thallium 0.20 pg/L EPA 6020B 0.06 0.1 0.2 IMAC 5/6/2020 Vanadium 7.2 pg/L EPA 6010D 3.9 5 0.3 IMAC Zinc 12.6 pg/L EPA 6010D 9.5 10 1,000 NC21- Vanadium NO pg/L EPA 6010D 3.9 5 0.3 IMAC MW-5* Thallium NO pg/L EPA 6020B 0.06 0.1 0.2 IMAC 7/16/2020 MW-6D Barium 12.8 pg/L EPA 6010D 3.5 5 700 NC2L 5/6/2020 MW-6S Barium 27.2 pg/L EPA 6010D 3.5 5 700 NC21- 5/6/2020 Barium 31.9 pg/L EPA 6010D 3.5 5 1,000 NC2B SW-1 Hardness, Total(SM 2340B) 25,300 pg/L EPA 6010D 131 662 100,000 NC2B 5/6/2020 Barium 28.7 pg/L EPA 6010D 3.5 5 1,000 NC2B SW-2 Hardness, Total(SM 2340B) 22,600 pg/L EPA 6010D 131 662 100,000 NC2B 5/6/2020 Barium 32.3 pg/L EPA 6010D 3.5 5 1,000 NC2B SW-3 Hardness, Total(SM 2340B) 25,100 pg/L EPA 6010D 131 662 100,000 NC2B 5/6/2020 Notes: pg/L= micrograms per liter. MDL = Method Detection Limit MRL = Method Reporting Limit J = Estimated concentration below the MRL B = Blank-qualilfied data due to detections in equipment, trip, or method blanks. Bold = quantified detections above the Standard * = Resampling event. NC21- = NC Groundwater Standard frme 15A NCAC 2L.0202 IMAC = NC Interim Maximum Allowable Concentration (IMAC) NC26 = NC Surface Water Standard from15A NCAC 2B (Note that NC2B for some metals is hardness -dependant.) ISTV = NC InStream Target Values NE = Not established Burke Co. - Kirksey Dr. Landfill Permit # 12-01 Page 2 of 2 LaBella Associates TABLE 4: Exceedances of Standards SAMPLE ID PARAMETER RESULT UNITS METHOD MDL MRL Standard Source DATE Barium 1,160 pg/L EPA 6010D 3.5 5 700 NC21- Cobalt 106 pg/L EPA 6010D 3.6 5 1 IMAC Benzene 9.6 pg/L EPA 8260D 0.15 1 1 NC21- MW 2 5/6/2020 1,4-Dichlorobenzene 39 pg/L EPA 8260D 0.26 1 6 NC21- 1,4-Dioxane (p-Dioxane) 213 pg/L EPA 8260D Mod. 5.8 10 3 NC21- 4-Methyl-2-pentanone (MIBK) 187 pg/L EPA 8260D 4.5 5 40 IMAC Benzene 1.4 pg/L EPA 8260D 0.15 1 1 NC21- 1,4-Dioxane (p-Dioxane) 111 pg/L EPA 8260D Mod. 2.3 4 3 NC21- MW-3D 5/7/2020 Tetrachloroethene 8.1 pg/L EPA 8260D 0.16 1 0.7 NC21- Trichloroethene 5 pg/L EPA 8260D 0.22 1 3 NC21- Cobalt 16.8 pg/L EPA 6010D 3.6 5 1 IMAC Benzene 3.7 pg/L EPA 8260D 0.15 1 1 NC21- MW-3S 5/6/2020 1,4-Dichlorobenzene 10.7 pg/L EPA 8260D 0.26 1 6 NC21- 1,4-Dioxane (p-Dioxane) 33.3 pg/L EPA 8260D Mod. 1.2 2 3 NC2L MW-5 Vanadium 7.2 pg/L EPA 6010D 3.9 5 0.3 IMAC 5/6/2020 MW-5* Vanadium ND pg/L EPA 6010D 3.9 5 0.3 IMAC 7/16/2020 Notes: pg/L= micrograms per liter. MDL = Method Detection Limit MRL = Method Reporting Limit NC21- = NC Groundwater Standard frme 15A NCAC 2L.0202 IMAC = NC Interim Maximum Allowable Concentration (IMAC) * = Resampling event. Burke Co. - Kirksey Dr. Landfill Permit # 12-01 La Bella Associates TABLE 5: May 2020 Field Parameters GW Upgradient Groundwater Downgradient Surface Water Parameter Units Collect Date MW-1 - MW-2 MW-3S MW-3D MW-4 I MW-5 MW-6S MW-61D SW-1 SW-2 I SW-3 Well Depth Ft. 5/6/2020 71.05 26.69 78.40 29.50 49.80 25.00 60.00 - - -- pH S.U. 5/6/2020 6 6.35 6.59 5.66 5.47 5.80 6.44 7.46 7.43 7.43 Temperature °C 5/6/2020 16 16 16.7 14.6 16 13.3 14.2 14.4 17.2 17.2 Conductivity PS/Cm 5/6/2020 2226 913 842 59 19.2 80.4 101.5 77 76.8 76.8 Dissolved Oxygen mg/L 5/6/2020 5.06 4.71 5.14 6.7 1.85 5.74 4.33 5.21 4.89 4.89 Oxidation Reduction Potential my 5/6/2020 218.2 272.5 323 192.5 300.9 192 201.5 326.9 214 214 Turbidity NTU 5/6/2020 - 8.25 8.12 12.17 97.58 356.5 79.08 3.74 15.66 15.6 15.60 Static Water Level Ft. 5/6/2020 26.00 5.68 0.00 18.90 35.66 9.75 11.62 -- -- -- pH S.U. 7/16/2020 -- -- -- -- 5.55 -- -- Temperature °C 7/16/2020 20.9 Conductivity pS/cm 7/16/2020 16.6 Dissolved Oxygen mg/L 7/16/2020 7.37 Oxidation Reduction Potential my 7/16/2020 - - 282.3 Turbidity NTU 7/16/2020 13.23 Static Water Level Ft. 7/16/2020 - - 35.51 Notes: °C = degrees Centigrade S.U. = Standard Units pS/cm = microSemens per centimeter my = millivolts NTU = Nephelometric Turbidity Units Ft = feet Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 FIGURE Figure 1 Site Location Map a6 ,ram_ -` ' `�- -,, .•r .� " �� �' � .. ti i n `160 900 ate_- f ._" •;t � - APPROXIMATE LOCATION OF PROPERTY LINE SCALE ' 2001) 0� s yO— �_.+• .. s Cam. i ► -l'1380 40 0,:3LaBella ISSUED FOR: GROUNDWATER MONITORING REPORT Powered by partnership. DRAWING NAME: SITE LOCATION MAP DRAWN BY: RWH DATE: 02/27/19 PROJECT NO.: 2192621 2211 WEST MEADOWVIEW ROAD GREENSBORO, N.C.27407 PHONE: (336) 323-0092 PROJECT NAME: DRAWING NUMBER: KIRKSEY DRIVE LANDFILL Figure 1 labellapc.com © 2020 LaBella Associates BURKE COUNTY, NORTH CAROLINA N:\DWgs\Drawings—Current\BURKE\GW EVENT MAPS\, SITE LOCA-104 MAP KIRKSEY DRIVE 2020.dwg DRAWING Drawing 1 Groundwater Potentiometric Surface Map LaBeRa Powered by partnership. 2211 WEST NSBORO, NC 27407 SUITE 101 GRE I I \ \ C \ (336) 323-0092 label lapc.com LIMITS OF WAS'fl'-(WP j — \ ( L L L — — _ — — LIMITS OF WASTE ��� / / 0 \ �M 2 1051.23 \ \ T �\ \ — I I — MW-3S / \MPS - 021.90 17.08� / /^�g� / ' \ \ \ \ \ �� \ \ \ \ / -- —\� ^ \ / —�� / © 202OLaBella Associates Z\\ f\ 1 �` / / � / I KIRKSEY DRIVE \ I LANDFILL 1Q5 BURKE COUNTY, NORTH CAROLINA �0000, / \ \ M 6S 1 0 38 \ ;000_ MW-1 \ 089.9 / �c — \ GRAPHIC SCALE Mo-�7770O �p� \ 7� /�/ / 0 150 300 600 \ \ o o / 1-1 (FEET) NOTES LEGEND 1. TOPOGRAPHIC CONTOUR INTERVAL = 20 FEET. NO DATE DESCRIPTION R,sai es 1080 EXISTING 100' TOPOGRAPHIC CONTOUR EXISTING ROAD 2• GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET. PROBECTNUMBER: 2192621.00 EXISTING 20' TOPOGRAPHIC CONTOUR APPROXIMATE LIMITS OF WASTE 3. STATIC WATER LEVELS WERE MEASURED ON MAY 05, 2020. DRAWN BY RH REVIEWED BY: GROUNDWATER SURFACE CONTOUR [FEET CENTERLINE OF STREAM 4. GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION 1080 — — — — — BETWEEN AND EXTRAPOLATION DATA, KE ISSUED FOR GROUNDWATER REPORT DATE osilzizo FROM KNOWN ABOVE MEAN SEA LEVEL (AMSL)] - MW-5 COMPLIANCE WELL LOCATION AND TOPOGRAPHIC CONTOURS, AND KNOWN FIELD CONDITIONS. DRAWING NAME: IDENTIFICATION WITH STATIC WATER — — PROPERTY LINE ELEV LEVEL ELEVATION (FEET AMSL) GROUNDWATER FLOW PATHWAY USED TO FLOW PATH LENGTH SURFACE MONITORING POINT LOCATION PERMIT N0.12-01 CALCULATE HYDRAULIC GRADIENT O SW-2 AND IDENTIFICATION GROUNDWATER POTENTIOMETRIC SEGMENT USED FOR GRADIENT CALCULATION Q 1,105 LF OMAY SURFACE MAP 05, 2020 1 Q 1,196 LF DRAWING NUMBER'. 13 987 LF 1 APPENDICES Appendix 1 Field Logs and Laboratory Analytical Reports Appendix 2 Historical Data APPENDIX 1 Field Logs and Laboratory Analytical Reports 0 La Betta GROUND WATER SAMPLING LOG Project Name: "�Ir � Dr. Project No. /Task No.: a I017-0-I ,u11/03 Well ID:Mvv — Sampler(s): Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: For 4" Well: WCT X 0.163 WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled witl' Depth to Water before Sampling: DATE: OS v� 2a�w 2 inches (o- 00 feet 4la05 feet /4S. bS- feet [DTB-DTW] gallons gallons Z�k • o gallons • d gallons feet Gallons Time Temp (°C) pH Cond. (US/CM) Dis.02 mg/L ORP my Turb. (ntu) Initials C� p33S 15 • , v �- as � . S� �-�-2 I " �- �� T 34 U-tLty 1(a. I " , 05 ? Qt49, 0 IG PJM 11+(vg (0•05 22 - - ,3v 243.4-Z 0 Fs03 i r'o. n � �� 2zz � o (v Date of sample: Before Sampling Comments (weather conditions, odor, colors, silt, etc.): -'u nsll 0 C .. ,P U ► 6-P U h CX Signature: Date:-8 -5 O- %7-OZca QA/QC Sign Off:- Date: e LaBetta DATE: GROUND WATER SAMPLING LOG Project Name: Project No. /Task No.: o2t �j?ir� I oo�a� Well ID: MNN-3 Sampler(s):l�l<_&)t,-)-1M1�qotz/P'x(vSu Well Location: Well Diameter: 2 inches Initial Depth to Water (DTW): 5, 69 feet Depth to Bottom (DTB): a (o . G q feet Water Column Thickness (WCT): a (. of feet [DTB-DTW] Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 gallons For 4" Well: WCT X 0.653 = — gallons For THREE Well Volumes: WV X 3 gallons Actual Amount Purged/Bailed: % gallons Purged with: ai eer Pump Other: Sampled with: Bit Pump Other: Depth to Water before Sampling: feet Gallons Time Temp (°C) pH Cond. (US/CM) Dis.02 mg/L ORP my Turb. (ntu) Initials 0 i vu (o 2i612AJ J. q & AqD LJ 0.3 `f 3 3 Z 4,33 309 .'3 f 2. {a IM �0'2 l�ti �W•o iP �S 13 I 5 g,r2 �M Date of sample: Before Sampling Comments (weather conditions, odor, color, silt, etc.): Signature: ' Gwte_ Date: QA/QC Sign Off: Date: e LaBeRa DATE: QS/CUr/UZ,0 GROUND WATER SAMPLING LOG k� Project Name: - Qv. Project No. /Task Well ID: Mw3 Sampler(s): N So+° Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: For 4" Well: WCT X 0.163 WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled witP Depth to Water before Sampling: 2 inches 0 feet '�?•4-0 feet 19- 40 feet [DTB-DTW] gallons gallons _ gallons 3�;,q gallons feet Gallons Time Temp (°C) pH Cond. (US/CM) Dis.02 mg/L ORP my Turb. (ntu) Initials I�03 t S.s 1a,3r og 3312.E ;� P -S i &RC1 , r � b, sZ 933 4,39 .2 YK I 4,32 R/i 3� ►�s� �. s� KV2- Date of sample: Before Sampling Comments (weather conditions, odor, color, silt, etc.): Gtl i SCt M P �—c % m rvl..e Signature: i��-�W Date:_ QA/QC Sign Off: - Date: -10 -a" La BetLa DATE: oSIU6 GROUND WATER SAMPLING LOG ki rl`�'J Project Name: i f Project No. /Task N'3.:O1 2(021.001U3 Well ID: Sampler(s): Ott FkJo' CULL Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled witl 2 inches Aly feet -SO feet /d. feet [DTB-DTW] gallons gallons SIB gallons i gallons Depth to Water before Sampling: feet Gallons Time Temp (°C) pH Cond. (US/CM) Dis.02 mg/L ORP my Turb. (ntu) Initials 08W Iq. (P 133•&�- 15 al .7- 67•43 I- 13 oos H.g 5. 6.0 qv 9 ,1:- i M 3: 493 I 'Sy 1Q/� Date of sample: Before Sampling p0 M. S, W "-I_ 2,35 13os--s- i 13.88' PJV%A Comments (weather conditions, odor, coolr, silt, etc.): S;-ta.Anu , (�D S • nU ldd dry Signature: WV1" Date: 0510� 1 7,V2 Q QA/QC Sign Off: Date: — l a 0 LaBella DATE: CS v5--0(,17 '� 0� _'J F GROUND WATER SAMPLING LOG p►�. Project Name: �' Project No. /Task No.: alb 7_{,zi •oulo3 Well ID: M w'S Sampler(s): Saty-i f J6,4T • bd Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled witt 2 inches 3 s feet feet 14.14 feet [DTB-DTW] a .3 gallons _ r� gallons to GI gallons gallons Depth to Water before Sampling: feet Gallons Time Temp (°C) pH Cond. (US/CM) Dis.02 mg/L ORP my Turb. (ntu) Initials Tlq- 24.1 is, 04 3` N. 3 -` 19 39 RM Z 3 is-p!1 1 5.fi�v ig. I E 3.z-t 3Q9.2_ 2 2,2 R `+•(4;1 1 S-Uq 16.1 1 S•90 (9.1 f. 219,q 1Z.3 U V slq 5-, 4�' I 2. . �S 30-1 q Date of sample: ry 10 j 40 Before Sampling I`j, u -5• SS3 42 .9, aj Comments (weather conditions, odor, color, silt, etc,): s� , (Oct 'S oy) 05-10517'0'7'0 04 fjq*r�lu�%2n7-v D nd S'trnr�,c� t� �n as/o%lz�o v Signature: A"'X f Date: 05 0('040-7,0 QA/QC Sign Off: - Date: 0 LaBeRa DATE: 0"S ob -Zd7 GROUND WATER SAMPLING LOG Ki r KT Project Name: Project No. /Task No.: 2101262i 00/0-35 ID: MyV- CPS Sampler(s): N apfq--iaad►�ct� Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled wit[ 2 inches feet 9 5-D feet S.d-5- feet [DTB-DTW] -gallons gallons gallons .s0 gallons Depth to Water before Sampling: feet Gallons Time Temp (°C) pH Cond. (US/CM) Dis.02 mg/L ORP my Turb. (ntu) Initials 0 MOO ias- (p,94 s 5-.8q 106.-? n-2q RM 4 I10� 3 9..3-V it, 4. I 7g, 13 R/M 4 R oqi?- q 5 • (4 1(0`2• 14 5 /. ST Rto . Sp 3,3 s W $v . 4- 101 z. o �. og P-tn Date of sample: Before Sampling 10 14.1 (a 1.5 Z •? S 30q. a�,S Rlr�n Comments (weather conditions, odour, color, silt, etc.): &a ny)V , _� o S /' f uwzJ and Sn m Dz, gme c( Signature: 0 Date: n,9lo6 h1 QA/QC Sign Off: Date: LaBe[La 05DATE: D � ?.0 GROUND WATER SAMPLING LOG Project Name: br- Project No. /Task No.: a ►012,& Well ID: M Vy- 0 Sampler(s): ",,Wfv. R.v6GLa-2,1,k I!1tLk _4J44 Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: For 4" Well: WCT X 0.163 WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled witt 2 inches h . 67- feet (0 O. L) feet 4139 feet [DTB-DTW] 2" gallons gallons a3�� gallons gallons Depth to Water before Sampling: feet Gallons Time Temp (°C) pH Cond. (US/CM) Dis.02 mg/L ORP my Turb. (ntu) Initials D i 0 6.2 4 Me 35-.'1 /9 • b v1 (19.49 /23.1 s. 5-0 13z if . s RN ri s$ dui 2� 13. �• 31 1 a s y .17 I �. 3 3 J9 R1 A3 14,2- 44 10.5 14-33 3,3 L/ PMNA Date of sample: Before Sampling Comments (weather conditions, odor, color, silt, etc.):Apd aMDULd 'Jrvlkviloj'� &AAA\J , 0--<' '. )VITAed, Signature: ' Date: (9 y[J (o/Z02�U QA/QC Sign Off: Date: ` ao a0 DATE: US10S 1" 0, LaBeLta SURFACE WATER MONITORING LOG Project Name: M rKS Ar. Project/Task No.: AIcl 20A .o 0/0-7, Surface Point ID: SW- Sampler(s): Location: Field Parameters: Time of Sampling: pH: Temperature: Conductivity: Turbidity: Dissolved Oxygen Oxidation -Reduction Potential Comments/Sample Description S•2` 0 (US/CM) /(ntu) (mg/L) 3244t (mv) er conditions, odor, color, silt, etc.): I mi hv-"fj eik4 Summa /Sketch of Sampling Location Signature: Date: us% o5�2v7� QA/QC Sign Off: � • Date: �U DATE: bVOs17,V7-0 LaBetLa >,�•4,t:�z;;�.tr=;� SURFACE WATER MONITORING LOG Project Name: girl< pr. Project/Task No.: 21q,2 a f •yolo3 Surface Point ID: SW ✓7i Sampler(s): N W' • (Zoli ia.- /P - M-esuLVJ Location: Field Parameters: Time of Sampling: / � 5_5 pH: 41 Temperature: 12 (°C) Conductivity: (US/CM) Turbidity: ���• �L) (ntu) Dissolved Oxygen (mg/L) Oxidation -Reduction Potential 21 (mv) Comments/Sample Description (w ather conditions, odor, color, silt, etc.): Summary/Sketch of Sampling Location rl v S-w.-3 MM,,, 3Q RM�tN.3S I Signature: •Ad�Ak�, (VI& Date: QA/QC Sign Off: Date: P.., LaBetta DATE: /,7 S-%Gi `7—''7"D SURFACE WATER MONITORING LOG Project Name: irAL_ey or. Project/Task No.: a (Q 2&2 i.0c/°_3 1 1 Surface Point ID: SW _ 3 Sampler(s):� So v lgodky iv-',) O Location: Field Parameters: Time of Sampling: pH:- 3 Temperature: C) Conductivity: (US/cm) Turbidity: r • c U (ntu) Dissolved Oxygen /U 1 (mg/L) Oxidation -Reduction Potential a IL4— (mv) Comments/Sample Description (weather conditions, odor, color, silt, etc.): _ca Wl 0 Lew J m rne_rxA 4 §0(AW-3D Summary/Sketch of Sampling Location // f •*S V'J -M Mvu 3 S Signature: yiadlallal li'l" QA/QC Sign Off: - I Date: Date: leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 May 26, 2020 Mr. Van Burbach Joyce Engineering -Greensboro 2211 West Meadowview Rd Boone Bldg, Suite 101 Greensboro, NC 27407 RE: Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Dear Mr. Burbach: Enclosed are the analytical results for sample(s) received by the laboratory between May 07, 2020 and May 08, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, /7j"4w' Nicole Gasiorowski nicole.gasiorowski@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Van Burbach, Joyce Engineering -NC Gretta Eller, LaBella Associates, D.P.C. Rochelle Mesubed, Joyce Engineering Miguel Vazquez, Joyce Engineering REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Lab ID Sample ID Matrix Date Collected Date Received 92476718001 MW-3 Water 05/05/2016:20 05/07/20 10:55 92476718002 MW-4 Water 05/06/2016:06 05/07/20 10:55 92476718003 MW-5 Water 05/06/20 09:45 05/07/20 10:55 92476718004 MW-6D Water 05/06/20 09:29 05/07/20 10:55 92476718005 SW-1 Water 05/06/20 07:05 05/07/20 10:55 92476718006 SW-2 Water 05/05/2016:55 05/07/20 10:55 92476718007 TB (NC App I VOCs) Water 05/05/20 06:30 05/07/20 10:55 92476718008 TB (8260SIM 1,4-D) Water 05/05/20 06:30 05/07/20 10:55 92476718009 MW-2 Water 05/06/20 08:03 05/08/20 08:00 92476718010 MW-3D Water 05/05/20 17:57 05/08/20 08:00 92476718011 MW-6S Water 05/06/20 16:20 05/08/20 08:00 92476718012 SW-3 Water 05/05/20 17:06 05/08/20 08:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Burke Co (Kirksey Drive) 92476718 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92476718001 MW-3 EPA 601OD RDT, SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92476718002 MW-4 EPA 601OD RDT, SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92476718003 MW-5 EPA 601 OD DS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92476718004 MW-6D EPA 601OD DS, SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92476718005 SW-1 EPA 601OD DS, SH1 15 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92476718006 SW-2 EPA 601OD KQ, SH1 15 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92476718007 TB (NC App I VOCs) EPA 8260D CL 50 PASI-C 92476718008 TB (8260SIM 1,4-D) EPA 8260D Mod. LMB 3 PASI-C 92476718009 MW-2 EPA 601 OD KQ, RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92476718010 MW-3D EPA 601 OD KQ, RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92476718011 MW-6S EPA 601OD KQ, SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 8260D Mod. LMB 3 PASI-C 92476718012 SW-3 EPA 601 OD DS 15 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: Burke Co (Kirksey Drive) 92476718 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92476718001 MW-3 EPA 601 OD Barium 486 ug/L 5.0 05/15/20 21:54 EPA 601 OD Cadmium 0.51 J ug/L 1.0 05/15/20 21:54 EPA 601 OD Cobalt 16.8 ug/L 5.0 05/15/20 21:54 EPA 601 OD Nickel 5.4 ug/L 5.0 05/15/20 21:54 EPA 8260D Benzene 3.7 ug/L 1.0 05/18/20 18:35 EPA 8260D Chlorobenzene 32.3 ug/L 1.0 05/18/20 18:35 EPA 8260D Chloroethane 1.6 ug/L 1.0 05/18/20 18:35 IK EPA 8260D 1,2-Dichlorobenzene 0.64J ug/L 1.0 05/18/20 18:35 EPA 8260D 1,4-Dichlorobenzene 10.7 ug/L 1.0 05/18/20 18:35 EPA 8260D Xylene (Total) 15.1 ug/L 1.0 05/18/20 18:35 EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 33.3 ug/L 2.0 05/14/20 05:52 92476718002 MW-4 EPA 601 OD Barium 71.2 ug/L 5.0 05/15/20 21:57 EPA 8260D 1,1-Dichloroethane 0.48J ug/L 1.0 05/19/20 06:13 EPA 8260D cis-1,2-Dichloroethene 2.6 ug/L 1.0 05/19/20 06:13 EPA 8260D Tetrachloroethene 0.69J ug/L 1.0 05/19/20 06:13 92476718003 MW-5 EPA 601 OD Barium 55.4 ug/L 5.0 05/18/20 17:24 EPA 601 OD Selenium 7.2J ug/L 10.0 05/18/20 17:24 EPA 601 OD Vanadium 7.2 ug/L 5.0 05/18/20 17:24 EPA 601 OD Zinc 12.6 ug/L 10.0 05/18/20 17:24 EPA 6020B Thallium 0.20 ug/L 0.10 05/13/20 06:51 92476718004 MW-611) EPA 601 OD Barium 12.8 ug/L 5.0 05/18/20 17:43 92476718005 SW-1 EPA 601 OD Barium 31.9 ug/L 5.0 05/18/20 17:47 EPA 601 OD Hardness, Total(SM 2340B) 25300 ug/L 662 05/18/20 17:47 92476718006 SW-2 EPA 601 OD Barium 28.7 ug/L 5.0 05/22/20 13:06 EPA 601 OD Hardness, Total(SM 2340B) 22600 ug/L 662 05/22/20 13:06 92476718009 MW-2 EPA 601 OD Barium 1160 ug/L 5.0 05/22/20 13:21 EPA 601 OD Cobalt 106 ug/L 5.0 05/22/20 13:21 EPA 601 OD Nickel 14.4 ug/L 5.0 05/22/20 13:21 EPA 601 OD Selenium 9.2J ug/L 10.0 05/22/20 13:21 EPA 8260D Acetone 255 ug/L 25.0 05/19/20 07:27 EPA 8260D Benzene 9.6 ug/L 1.0 05/19/20 07:27 EPA 8260D 2-Butanone (MEK) 222 ug/L 5.0 05/19/20 07:27 EPA 8260D Chlorobenzene 26.7 ug/L 1.0 05/19/20 07:27 EPA 8260D 1,2-Dichlorobenzene 2.2 ug/L 1.0 05/19/20 07:27 EPA 8260D 1,4-Dichlorobenzene 39.0 ug/L 1.0 05/19/20 07:27 EPA 8260D 1,1-Dichloroethane 0.61J ug/L 1.0 05/19/20 07:27 EPA 8260D cis-1,2-Dichloroethene 0.41 J ug/L 1.0 05/19/20 07:27 EPA 8260D Ethylbenzene 17.0 ug/L 1.0 05/19/20 07:27 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Lab Sample ID Method Client Sample ID Parameters 92476718009 MW-2 EPA 8260D 4-Methyl-2-pentanone (MIBK) EPA 8260D Toluene EPA 8260D Xylene (Total) EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 92476718010 MW-3D EPA 601 OD Barium EPA 601 OD Nickel EPA 8260D Benzene EPA 8260D Chlorobenzene EPA 8260D 1,4-Dichlorobenzene EPA 8260D 1,1-Dichloroethane EPA 8260D cis-1,2-Dichloroethene EPA 8260D 1,2-Dichloropropane EPA 8260D Tetrachloroethene EPA 8260D Trichloroethene EPA 8260D Vinyl chloride EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 92476718011 MW-6S EPA 601 OD Barium 92476718012 SW-3 EPA 601 OD Barium EPA 601 OD Hardness, Total(SM 2340B) Result Units Report Limit Analyzed 187 ug/L 5.0 05/19/20 07:27 v1 2.5 ug/L 1.0 05/19/20 07:27 34.0 ug/L 1.0 05/19/20 07:27 213 ug/L 10.0 05/15/20 05:52 194 ug/L 5.0 05/22/2013:24 24.1 ug/L 5.0 05/22/2013:24 1.4 ug/L 1.0 05/18/2019:12 8.2 ug/L 1.0 05/18/2019:12 4.1 ug/L 1.0 05/18/2019:12 4.8 ug/L 1.0 05/18/2019:12 16.4 ug/L 1.0 05/18/2019:12 0.84J ug/L 1.0 05/18/2019:12 8.1 ug/L 1.0 05/18/2019:12 5.0 ug/L 1.0 05/18/2019:12 0.88J ug/L 1.0 05/18/2019:12 IK 111 ug/L 4.0 05/15/2013:50 27.2 ug/L 5.0 05/23/2019:51 32.3 ug/L 5.0 05/22/2015:11 25100 ug/L 662 05/22/2015:11 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Qualifiers Page 7 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Sample: MW-3 Lab ID: 92476718001 Collected: 05/05/20 16:20 Received: 05/07/20 10:55 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 05/13/20 02:40 05/18/20 14:23 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 05/13/20 02:40 05/15/20 21:54 7440-38-2 Barium 486 ug/L 5.0 3.5 1 05/13/20 02:40 05/15/20 21:54 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 05/13/20 02:40 05/15/20 21:54 7440-41-7 Cadmium 0.511 ug/L 1.0 0.40 1 05/13/20 02:40 05/15/20 21:54 7440-43-9 Chromium ND ug/L 5.0 3.7 1 05/13/20 02:40 05/15/20 21:54 7440-47-3 Cobalt 16.8 ug/L 5.0 3.6 1 05/13/20 02:40 05/15/20 21:54 7440-48-4 Copper ND ug/L 5.0 4.3 1 05/13/20 02:40 05/15/20 21:54 7440-50-8 Lead ND ug/L 5.0 4.5 1 05/13/20 02:40 05/15/20 21:54 7439-92-1 Nickel 5.4 ug/L 5.0 3.5 1 05/13/20 02:40 05/15/20 21:54 7440-02-0 Selenium ND ug/L 10.0 4.7 1 05/13/20 02:40 05/15/20 21:54 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/13/20 02:40 05/15/20 21:54 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 05/13/20 02:40 05/15/20 21:54 7440-62-2 Zinc ND ug/L 10.0 9.5 1 05/13/20 02:40 05/15/20 21:54 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.060 1 05/12/20 01:45 05/13/20 06:39 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 05/18/20 18:35 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 05/18/20 18:35 107-13-1 Benzene 3.7 ug/L 1.0 0.15 1 05/18/20 18:35 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 05/18/20 18:35 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 05/18/20 18:35 75-27-4 Bromoform ND ug/L 1.0 0.62 1 05/18/20 18:35 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 05/18/20 18:35 74-83-9 IK,v2 2-Butanone (MEK) ND ug/L 5.0 3.3 1 05/18/20 18:35 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 05/18/20 18:35 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 05/18/20 18:35 56-23-5 Chlorobenzene 32.3 ug/L 1.0 0.23 1 05/18/20 18:35 108-90-7 Chloroethane 1.6 ug/L 1.0 0.49 1 05/18/20 18:35 75-00-3 IK Chloroform ND ug/L 5.0 2.3 1 05/18/20 18:35 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 05/18/20 18:35 74-87-3 IK 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 05/18/20 18:35 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 05/18/20 18:35 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 05/18/20 18:35 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 05/18/20 18:35 74-95-3 1,2-Dichlorobenzene 0.64J ug/L 1.0 0.29 1 05/18/20 18:35 95-50-1 1,4-Dichlorobenzene 10.7 ug/L 1.0 0.26 1 05/18/20 18:35 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 05/18/20 18:35 110-57-6 IH 1,1-Dichloroethane ND ug/L 1.0 0.27 1 05/18/20 18:35 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 05/18/20 18:35 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 05/18/20 18:35 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Sample: MW-3 Lab ID: 92476718001 Collected: 05/05/20 16:20 Received: 05/07/20 10:55 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/26/2020 04:21 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 05/18/2018:35 156-59-2 ND ug/L 1.0 0.25 1 05/18/2018:35 156-60-5 ND ug/L 1.0 0.19 1 05/18/2018:35 78-87-5 ND ug/L 1.0 0.30 1 05/18/2018:35 10061-01-5 ND ug/L 1.0 0.31 1 05/18/2018:35 10061-02-6 ND ug/L 1.0 0.26 1 05/18/2018:35 100-41-4 ND ug/L 5.0 0.57 1 05/18/2018:35 591-78-6 ND ug/L 20.0 12.5 1 05/18/2018:35 74-88-4 ND ug/L 5.0 3.7 1 05/18/2018:35 75-09-2 ND ug/L 5.0 4.5 1 05/18/2018:35 108-10-1 ND ug/L 1.0 0.27 1 05/18/2018:35 100-42-5 ND ug/L 1.0 0.34 1 05/18/2018:35 630-20-6 ND ug/L 1.0 0.22 1 05/18/2018:35 79-34-5 ND ug/L 1.0 0.16 1 05/18/2018:35 127-18-4 ND ug/L 1.0 0.24 1 05/18/2018:35 108-88-3 ND ug/L 1.0 0.18 1 05/18/2018:35 71-55-6 ND ug/L 1.0 0.24 1 05/18/2018:35 79-00-5 ND ug/L 1.0 0.22 1 05/18/2018:35 79-01-6 ND ug/L 1.0 0.31 1 05/18/2018:35 75-69-4 ND ug/L 1.0 0.35 1 05/18/2018:35 96-18-4 ND ug/L 2.0 1.4 1 05/18/2018:35 108-05-4 ND ug/L 1.0 0.24 1 05/18/2018:35 75-01-4 15.1 ug/L 1.0 0.63 1 05/18/2018:35 1330-20-7 97 % 70-130 1 05/18/2018:35 460-00-4 102 % 70-130 1 05/18/2018:35 17060-07-0 102 % 70-130 1 05/18/2018:35 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 33.3 ug/L 2.0 1.2 1 05/14/20 05:52 123-91-1 106 % 50-150 1 05/14/20 05:52 17060-07-0 100 % 50-150 1 05/14/20 05:52 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IK IK Page 9 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Sample: MW-4 Lab ID: 92476718002 Collected: 05/06/20 16:06 Received: 05/07/20 10:55 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 05/13/20 02:40 05/18/20 14:26 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 05/13/20 02:40 05/15/20 21:57 7440-38-2 Barium 71.2 ug/L 5.0 3.5 1 05/13/20 02:40 05/15/20 21:57 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 05/13/20 02:40 05/15/20 21:57 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 05/13/20 02:40 05/15/20 21:57 7440-43-9 Chromium ND ug/L 5.0 3.7 1 05/13/20 02:40 05/15/20 21:57 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 05/13/20 02:40 05/15/20 21:57 7440-48-4 Copper ND ug/L 5.0 4.3 1 05/13/20 02:40 05/15/20 21:57 7440-50-8 Lead ND ug/L 5.0 4.5 1 05/13/20 02:40 05/15/20 21:57 7439-92-1 Nickel ND ug/L 5.0 3.5 1 05/13/20 02:40 05/15/20 21:57 7440-02-0 Selenium ND ug/L 10.0 4.7 1 05/13/20 02:40 05/15/20 21:57 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/13/20 02:40 05/15/20 21:57 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 05/13/20 02:40 05/15/20 21:57 7440-62-2 Zinc ND ug/L 10.0 9.5 1 05/13/20 02:40 05/15/20 21:57 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.060 1 05/12/20 01:45 05/13/20 06:47 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 05/19/20 06:13 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 05/19/20 06:13 107-13-1 Benzene ND ug/L 1.0 0.15 1 05/19/20 06:13 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 05/19/20 06:13 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 05/19/20 06:13 75-27-4 Bromoform ND ug/L 1.0 0.62 1 05/19/20 06:13 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 05/19/20 06:13 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 05/19/20 06:13 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 05/19/20 06:13 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 05/19/20 06:13 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 05/19/20 06:13 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 05/19/20 06:13 75-00-3 Chloroform ND ug/L 5.0 2.3 1 05/19/20 06:13 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 05/19/20 06:13 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 05/19/20 06:13 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 05/19/20 06:13 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 05/19/20 06:13 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 05/19/20 06:13 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 05/19/20 06:13 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 05/19/20 06:13 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 05/19/20 06:13 110-57-6 1,1-Dichloroethane 0.48J ug/L 1.0 0.27 1 05/19/20 06:13 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 05/19/20 06:13 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 05/19/20 06:13 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. IK,v2 IK IH Page 10 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Sample: MW-4 Lab ID: 92476718002 Collected: 05/06/20 16:06 Received: 05/07/20 10:55 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/26/2020 04:21 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 2.6 ug/L 1.0 0.29 1 05/19/20 06:13 156-59-2 ND ug/L 1.0 0.25 1 05/19/20 06:13 156-60-5 ND ug/L 1.0 0.19 1 05/19/20 06:13 78-87-5 ND ug/L 1.0 0.30 1 05/19/20 06:13 10061-01-5 ND ug/L 1.0 0.31 1 05/19/20 06:13 10061-02-6 ND ug/L 1.0 0.26 1 05/19/20 06:13 100-41-4 ND ug/L 5.0 0.57 1 05/19/20 06:13 591-78-6 ND ug/L 20.0 12.5 1 05/19/20 06:13 74-88-4 v2 ND ug/L 5.0 3.7 1 05/19/20 06:13 75-09-2 ND ug/L 5.0 4.5 1 05/19/20 06:13 108-10-1 v1 ND ug/L 1.0 0.27 1 05/19/20 06:13 100-42-5 ND ug/L 1.0 0.34 1 05/19/20 06:13 630-20-6 ND ug/L 1.0 0.22 1 05/19/20 06:13 79-34-5 0.69J ug/L 1.0 0.16 1 05/19/20 06:13 127-18-4 ND ug/L 1.0 0.24 1 05/19/20 06:13 108-88-3 ND ug/L 1.0 0.18 1 05/19/20 06:13 71-55-6 ND ug/L 1.0 0.24 1 05/19/20 06:13 79-00-5 ND ug/L 1.0 0.22 1 05/19/20 06:13 79-01-6 ND ug/L 1.0 0.31 1 05/19/20 06:13 75-69-4 IK ND ug/L 1.0 0.35 1 05/19/20 06:13 96-18-4 ND ug/L 2.0 1.4 1 05/19/20 06:13 108-05-4 v1 ND ug/L 1.0 0.24 1 05/19/20 06:13 75-01-4 IK ND ug/L 1.0 0.63 1 05/19/20 06:13 1330-20-7 95 % 70-130 1 05/19/20 06:13 460-00-4 108 % 70-130 1 05/19/20 06:13 17060-07-0 102 % 70-130 1 05/19/20 06:13 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 1.2 1 05/14/20 05:33 123-91-1 109 % 50-150 1 05/14/20 05:33 17060-07-0 90 % 50-150 1 05/14/20 05:33 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Sample: MW-5 Lab ID: 92476718003 Collected: 05/06/20 09:45 Received: 05/07/20 10:55 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 05/13/20 02:40 05/19/20 13:08 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 05/13/20 02:40 05/18/20 17:24 7440-38-2 Barium 55.4 ug/L 5.0 3.5 1 05/13/20 02:40 05/18/20 17:24 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 05/13/20 02:40 05/18/20 17:24 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 05/13/20 02:40 05/18/20 17:24 7440-43-9 Chromium ND ug/L 5.0 3.7 1 05/13/20 02:40 05/18/20 17:24 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 05/13/20 02:40 05/18/20 17:24 7440-48-4 Copper ND ug/L 5.0 4.3 1 05/13/20 02:40 05/18/20 17:24 7440-50-8 Lead ND ug/L 5.0 4.5 1 05/13/20 02:40 05/18/20 17:24 7439-92-1 Nickel ND ug/L 5.0 3.5 1 05/13/20 02:40 05/18/20 17:24 7440-02-0 Selenium 7.2.1 ug/L 10.0 4.7 1 05/13/20 02:40 05/18/20 17:24 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/13/20 02:40 05/18/20 17:24 7440-22-4 Vanadium 7.2 ug/L 5.0 3.9 1 05/13/20 02:40 05/18/20 17:24 7440-62-2 Zinc 12.6 ug/L 10.0 9.5 1 05/13/20 02:40 05/18/20 17:24 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.20 ug/L 0.10 0.060 1 05/12/20 01:45 05/13/20 06:51 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 05/19/20 06:32 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 05/19/20 06:32 107-13-1 Benzene ND ug/L 1.0 0.15 1 05/19/20 06:32 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 05/19/20 06:32 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 05/19/20 06:32 75-27-4 Bromoform ND ug/L 1.0 0.62 1 05/19/20 06:32 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 05/19/20 06:32 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 05/19/20 06:32 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 05/19/20 06:32 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 05/19/20 06:32 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 05/19/20 06:32 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 05/19/20 06:32 75-00-3 Chloroform ND ug/L 5.0 2.3 1 05/19/20 06:32 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 05/19/20 06:32 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 05/19/20 06:32 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 05/19/20 06:32 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 05/19/20 06:32 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 05/19/20 06:32 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 05/19/20 06:32 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 05/19/20 06:32 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 05/19/20 06:32 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 05/19/20 06:32 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 05/19/20 06:32 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 05/19/20 06:32 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. IK,v2 IK IH Page 12 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Sample: MW-5 Lab ID: 92476718003 Collected: 05/06/20 09:45 Received: 05/07/20 10:55 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/26/2020 04:21 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 05/19/20 06:32 156-59-2 ND ug/L 1.0 0.25 1 05/19/20 06:32 156-60-5 ND ug/L 1.0 0.19 1 05/19/20 06:32 78-87-5 ND ug/L 1.0 0.30 1 05/19/20 06:32 10061-01-5 ND ug/L 1.0 0.31 1 05/19/20 06:32 10061-02-6 ND ug/L 1.0 0.26 1 05/19/20 06:32 100-41-4 ND ug/L 5.0 0.57 1 05/19/20 06:32 591-78-6 ND ug/L 20.0 12.5 1 05/19/20 06:32 74-88-4 v2 ND ug/L 5.0 3.7 1 05/19/20 06:32 75-09-2 ND ug/L 5.0 4.5 1 05/19/20 06:32 108-10-1 v1 ND ug/L 1.0 0.27 1 05/19/20 06:32 100-42-5 ND ug/L 1.0 0.34 1 05/19/20 06:32 630-20-6 ND ug/L 1.0 0.22 1 05/19/20 06:32 79-34-5 ND ug/L 1.0 0.16 1 05/19/20 06:32 127-18-4 ND ug/L 1.0 0.24 1 05/19/20 06:32 108-88-3 ND ug/L 1.0 0.18 1 05/19/20 06:32 71-55-6 ND ug/L 1.0 0.24 1 05/19/20 06:32 79-00-5 ND ug/L 1.0 0.22 1 05/19/20 06:32 79-01-6 ND ug/L 1.0 0.31 1 05/19/20 06:32 75-69-4 IK ND ug/L 1.0 0.35 1 05/19/20 06:32 96-18-4 ND ug/L 2.0 1.4 1 05/19/20 06:32 108-05-4 v1 ND ug/L 1.0 0.24 1 05/19/20 06:32 75-01-4 IK ND ug/L 1.0 0.63 1 05/19/20 06:32 1330-20-7 96 % 70-130 1 05/19/20 06:32 460-00-4 110 % 70-130 1 05/19/20 06:32 17060-07-0 103 % 70-130 1 05/19/20 06:32 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 1.2 1 05/15/20 01:37 123-91-1 103 % 50-150 1 05/15/20 01:37 17060-07-0 88 % 50-150 1 05/15/20 01:37 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Sample: MW-61) Lab ID: 92476718004 Collected: 05/06/20 09:29 Received: 05/07/20 10:55 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 05/13/20 02:40 05/20/20 00:36 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 05/13/20 02:40 05/18/20 17:43 7440-38-2 Barium 12.8 ug/L 5.0 3.5 1 05/13/20 02:40 05/18/20 17:43 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 05/13/20 02:40 05/18/20 17:43 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 05/13/20 02:40 05/18/20 17:43 7440-43-9 Chromium ND ug/L 5.0 3.7 1 05/13/20 02:40 05/18/20 17:43 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 05/13/20 02:40 05/18/20 17:43 7440-48-4 Copper ND ug/L 5.0 4.3 1 05/13/20 02:40 05/18/20 17:43 7440-50-8 Lead ND ug/L 5.0 4.5 1 05/13/20 02:40 05/18/20 17:43 7439-92-1 Nickel ND ug/L 5.0 3.5 1 05/13/20 02:40 05/18/20 17:43 7440-02-0 Selenium ND ug/L 10.0 4.7 1 05/13/20 02:40 05/18/20 17:43 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/13/20 02:40 05/18/20 17:43 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 05/13/20 02:40 05/18/20 17:43 7440-62-2 Zinc ND ug/L 10.0 9.5 1 05/13/20 02:40 05/18/20 17:43 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.060 1 05/12/20 01:45 05/13/20 07:07 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 05/19/20 06:50 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 05/19/20 06:50 107-13-1 Benzene ND ug/L 1.0 0.15 1 05/19/20 06:50 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 05/19/20 06:50 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 05/19/20 06:50 75-27-4 Bromoform ND ug/L 1.0 0.62 1 05/19/20 06:50 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 05/19/20 06:50 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 05/19/20 06:50 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 05/19/20 06:50 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 05/19/20 06:50 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 05/19/20 06:50 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 05/19/20 06:50 75-00-3 Chloroform ND ug/L 5.0 2.3 1 05/19/20 06:50 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 05/19/20 06:50 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 05/19/20 06:50 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 05/19/20 06:50 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 05/19/20 06:50 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 05/19/20 06:50 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 05/19/20 06:50 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 05/19/20 06:50 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 05/19/20 06:50 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 05/19/20 06:50 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 05/19/20 06:50 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 05/19/20 06:50 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. IK,v2 IK IH Page 14 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Sample: MW-6D Lab ID: 92476718004 Collected: 05/06/20 09:29 Received: 05/07/20 10:55 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/26/2020 04:21 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 05/19/20 06:50 156-59-2 ND ug/L 1.0 0.25 1 05/19/20 06:50 156-60-5 ND ug/L 1.0 0.19 1 05/19/20 06:50 78-87-5 ND ug/L 1.0 0.30 1 05/19/20 06:50 10061-01-5 ND ug/L 1.0 0.31 1 05/19/20 06:50 10061-02-6 ND ug/L 1.0 0.26 1 05/19/20 06:50 100-41-4 ND ug/L 5.0 0.57 1 05/19/20 06:50 591-78-6 ND ug/L 20.0 12.5 1 05/19/20 06:50 74-88-4 v2 ND ug/L 5.0 3.7 1 05/19/20 06:50 75-09-2 ND ug/L 5.0 4.5 1 05/19/20 06:50 108-10-1 v1 ND ug/L 1.0 0.27 1 05/19/20 06:50 100-42-5 ND ug/L 1.0 0.34 1 05/19/20 06:50 630-20-6 ND ug/L 1.0 0.22 1 05/19/20 06:50 79-34-5 ND ug/L 1.0 0.16 1 05/19/20 06:50 127-18-4 ND ug/L 1.0 0.24 1 05/19/20 06:50 108-88-3 ND ug/L 1.0 0.18 1 05/19/20 06:50 71-55-6 ND ug/L 1.0 0.24 1 05/19/20 06:50 79-00-5 ND ug/L 1.0 0.22 1 05/19/20 06:50 79-01-6 ND ug/L 1.0 0.31 1 05/19/20 06:50 75-69-4 IK ND ug/L 1.0 0.35 1 05/19/20 06:50 96-18-4 ND ug/L 2.0 1.4 1 05/19/20 06:50 108-05-4 v1 ND ug/L 1.0 0.24 1 05/19/20 06:50 75-01-4 IK ND ug/L 1.0 0.63 1 05/19/20 06:50 1330-20-7 96 % 70-130 1 05/19/20 06:50 460-00-4 110 % 70-130 1 05/19/20 06:50 17060-07-0 103 % 70-130 1 05/19/20 06:50 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 1.2 1 05/15/20 01:57 123-91-1 108 % 50-150 1 05/15/20 01:57 17060-07-0 85 % 50-150 1 05/15/20 01:57 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Sample: SW-1 Lab ID: 92476718005 Collected: 05/06/20 07:05 Received: 05/07/20 10:55 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Hardness, Total(SM 2340B) Vanadium Zinc Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville ND ug/L 5.0 3.0 1 05/13/20 02:40 05/20/20 00:39 7440-36-0 ND ug/L 10.0 4.7 1 05/13/20 02:40 05/18/20 17:47 7440-38-2 31.9 ug/L 5.0 3.5 1 05/13/20 02:40 05/18/20 17:47 7440-39-3 ND ug/L 1.0 0.70 1 05/13/20 02:40 05/18/20 17:47 7440-41-7 ND ug/L 1.0 0.40 1 05/13/20 02:40 05/18/20 17:47 7440-43-9 ND ug/L 5.0 3.7 1 05/13/20 02:40 05/18/20 17:47 7440-47-3 ND ug/L 5.0 3.6 1 05/13/20 02:40 05/18/20 17:47 7440-48-4 ND ug/L 5.0 4.3 1 05/13/20 02:40 05/18/20 17:47 7440-50-8 ND ug/L 5.0 4.5 1 05/13/20 02:40 05/18/20 17:47 7439-92-1 ND ug/L 5.0 3.5 1 05/13/20 02:40 05/18/20 17:47 7440-02-0 ND ug/L 10.0 4.7 1 05/13/20 02:40 05/18/20 17:47 7782-49-2 ND ug/L 5.0 2.5 1 05/13/20 02:40 05/18/20 17:47 7440-22-4 25300 ug/L 662 131 1 05/13/20 02:40 05/18/20 17:47 ND ug/L 5.0 3.9 1 05/13/20 02:40 05/18/20 17:47 7440-62-2 ND ug/L 10.0 9.5 1 05/13/20 02:40 05/18/20 17:47 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.060 1 05/12/20 01:45 05/13/20 07:11 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 05/19/20 07:09 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 05/19/20 07:09 107-13-1 Benzene ND ug/L 1.0 0.15 1 05/19/20 07:09 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 05/19/20 07:09 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 05/19/20 07:09 75-27-4 Bromoform ND ug/L 1.0 0.62 1 05/19/20 07:09 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 05/19/20 07:09 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 05/19/20 07:09 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 05/19/20 07:09 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 05/19/20 07:09 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 05/19/20 07:09 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 05/19/20 07:09 75-00-3 Chloroform ND ug/L 5.0 2.3 1 05/19/20 07:09 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 05/19/20 07:09 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 05/19/20 07:09 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 05/19/20 07:09 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 05/19/20 07:09 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 05/19/20 07:09 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 05/19/20 07:09 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 05/19/20 07:09 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 05/19/20 07:09 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 05/19/20 07:09 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 05/19/20 07:09 107-06-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. IK,v2 IK IK I., Page 16 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Sample: SW-1 Lab ID: 92476718005 Collected: 05/06/20 07:05 Received: 05/07/20 10:55 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/26/2020 04:21 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.24 1 05/19/20 07:09 75-35-4 ND ug/L 1.0 0.29 1 05/19/20 07:09 156-59-2 ND ug/L 1.0 0.25 1 05/19/20 07:09 156-60-5 ND ug/L 1.0 0.19 1 05/19/20 07:09 78-87-5 ND ug/L 1.0 0.30 1 05/19/20 07:09 10061-01-5 ND ug/L 1.0 0.31 1 05/19/20 07:09 10061-02-6 ND ug/L 1.0 0.26 1 05/19/20 07:09 100-41-4 ND ug/L 5.0 0.57 1 05/19/20 07:09 591-78-6 ND ug/L 20.0 12.5 1 05/19/20 07:09 74-88-4 v2 ND ug/L 5.0 3.7 1 05/19/20 07:09 75-09-2 ND ug/L 5.0 4.5 1 05/19/20 07:09 108-10-1 v1 ND ug/L 1.0 0.27 1 05/19/20 07:09 100-42-5 ND ug/L 1.0 0.34 1 05/19/20 07:09 630-20-6 ND ug/L 1.0 0.22 1 05/19/20 07:09 79-34-5 ND ug/L 1.0 0.16 1 05/19/20 07:09 127-18-4 ND ug/L 1.0 0.24 1 05/19/20 07:09 108-88-3 ND ug/L 1.0 0.18 1 05/19/20 07:09 71-55-6 ND ug/L 1.0 0.24 1 05/19/20 07:09 79-00-5 ND ug/L 1.0 0.22 1 05/19/20 07:09 79-01-6 ND ug/L 1.0 0.31 1 05/19/20 07:09 75-69-4 IK ND ug/L 1.0 0.35 1 05/19/20 07:09 96-18-4 ND ug/L 2.0 1.4 1 05/19/20 07:09 108-05-4 v1 ND ug/L 1.0 0.24 1 05/19/20 07:09 75-01-4 IK ND ug/L 1.0 0.63 1 05/19/20 07:09 1330-20-7 96 % 70-130 1 05/19/20 07:09 460-00-4 112 % 70-130 1 05/19/20 07:09 17060-07-0 102 % 70-130 1 05/19/20 07:09 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 1.2 1 05/15/20 02:17 123-91-1 96 % 50-150 1 05/15/20 02:17 17060-07-0 94 % 50-150 1 05/15/20 02:17 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Sample: SW-2 Lab ID: 92476718006 Collected: 05/05/20 16:55 Received: 05/07/20 10:55 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Hardness, Total(SM 2340B) Vanadium Zinc Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville ND ug/L 5.0 3.0 1 05/21/20 02:40 05/22/20 13:06 7440-36-0 ND ug/L 10.0 4.7 1 05/21/20 02:40 05/22/20 13:06 7440-38-2 28.7 ug/L 5.0 3.5 1 05/21/20 02:40 05/22/20 13:06 7440-39-3 ND ug/L 1.0 0.70 1 05/21/20 02:40 05/22/20 13:06 7440-41-7 ND ug/L 1.0 0.40 1 05/21/20 02:40 05/22/20 13:06 7440-43-9 ND ug/L 5.0 3.7 1 05/21/20 02:40 05/22/20 13:06 7440-47-3 ND ug/L 5.0 3.6 1 05/21/20 02:40 05/22/20 13:06 7440-48-4 ND ug/L 5.0 4.3 1 05/21/20 02:40 05/22/20 13:06 7440-50-8 ND ug/L 5.0 4.5 1 05/21/20 02:40 05/22/20 13:06 7439-92-1 ND ug/L 5.0 3.5 1 05/21/20 02:40 05/22/20 13:06 7440-02-0 ND ug/L 10.0 4.7 1 05/21/20 02:40 05/22/20 13:06 7782-49-2 ND ug/L 5.0 2.5 1 05/21/20 02:40 05/22/20 13:06 7440-22-4 22600 ug/L 662 131 1 05/21/20 02:40 05/22/20 13:06 ND ug/L 5.0 3.9 1 05/21/20 02:40 05/22/20 13:06 7440-62-2 ND ug/L 10.0 9.5 1 05/21/20 02:40 05/23/20 19:37 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.060 1 05/13/20 01:37 05/13/20 23:10 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 05/18/20 18:53 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 05/18/20 18:53 107-13-1 Benzene ND ug/L 1.0 0.15 1 05/18/20 18:53 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 05/18/20 18:53 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 05/18/20 18:53 75-27-4 Bromoform ND ug/L 1.0 0.62 1 05/18/20 18:53 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 05/18/20 18:53 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 05/18/20 18:53 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 05/18/20 18:53 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 05/18/20 18:53 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 05/18/20 18:53 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 05/18/20 18:53 75-00-3 Chloroform ND ug/L 5.0 2.3 1 05/18/20 18:53 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 05/18/20 18:53 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 05/18/20 18:53 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 05/18/20 18:53 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 05/18/20 18:53 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 05/18/20 18:53 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 05/18/20 18:53 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 05/18/20 18:53 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 05/18/20 18:53 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 05/18/20 18:53 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 05/18/20 18:53 107-06-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. IK,v2 IK IK I., Page 18 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Sample: SW-2 Lab ID: 92476718006 Collected: 05/05/20 16:55 Received: 05/07/20 10:55 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/26/2020 04:21 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.24 1 05/18/2018:53 75-35-4 ND ug/L 1.0 0.29 1 05/18/2018:53 156-59-2 ND ug/L 1.0 0.25 1 05/18/2018:53 156-60-5 ND ug/L 1.0 0.19 1 05/18/2018:53 78-87-5 ND ug/L 1.0 0.30 1 05/18/2018:53 10061-01-5 ND ug/L 1.0 0.31 1 05/18/2018:53 10061-02-6 ND ug/L 1.0 0.26 1 05/18/2018:53 100-41-4 ND ug/L 5.0 0.57 1 05/18/2018:53 591-78-6 ND ug/L 20.0 12.5 1 05/18/2018:53 74-88-4 ND ug/L 5.0 3.7 1 05/18/2018:53 75-09-2 ND ug/L 5.0 4.5 1 05/18/2018:53 108-10-1 ND ug/L 1.0 0.27 1 05/18/2018:53 100-42-5 ND ug/L 1.0 0.34 1 05/18/2018:53 630-20-6 ND ug/L 1.0 0.22 1 05/18/2018:53 79-34-5 ND ug/L 1.0 0.16 1 05/18/2018:53 127-18-4 ND ug/L 1.0 0.24 1 05/18/2018:53 108-88-3 ND ug/L 1.0 0.18 1 05/18/2018:53 71-55-6 ND ug/L 1.0 0.24 1 05/18/2018:53 79-00-5 ND ug/L 1.0 0.22 1 05/18/2018:53 79-01-6 ND ug/L 1.0 0.31 1 05/18/2018:53 75-69-4 ND ug/L 1.0 0.35 1 05/18/2018:53 96-18-4 ND ug/L 2.0 1.4 1 05/18/2018:53 108-05-4 ND ug/L 1.0 0.24 1 05/18/2018:53 75-01-4 ND ug/L 1.0 0.63 1 05/18/2018:53 1330-20-7 96 % 70-130 1 05/18/2018:53 460-00-4 102 % 70-130 1 05/18/2018:53 17060-07-0 101 % 70-130 1 05/18/2018:53 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 1.2 1 05/14/20 23:19 123-91-1 111 % 50-150 1 05/14/20 23:19 17060-07-0 101 % 50-150 1 05/14/20 23:19 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 119 IK Page 19 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Sample: TB (NC App I VOCs) Lab ID: 92476718007 Collected: 05/05/20 06:30 Received: 05/07/20 10:55 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Date: 05/26/2020 04:21 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 6.2 1 05/18/2017:03 67-64-1 ND ug/L 10.0 0.90 1 05/18/2017:03 107-13-1 ND ug/L 1.0 0.15 1 05/18/2017:03 71-43-2 ND ug/L 1.0 0.34 1 05/18/2017:03 74-97-5 ND ug/L 1.0 0.26 1 05/18/2017:03 75-27-4 ND ug/L 1.0 0.62 1 05/18/2017:03 75-25-2 ND ug/L 2.0 0.62 1 05/18/2017:03 74-83-9 ND ug/L 5.0 3.3 1 05/18/2017:03 78-93-3 ND ug/L 2.0 0.40 1 05/18/2017:03 75-15-0 ND ug/L 1.0 0.22 1 05/18/2017:03 56-23-5 ND ug/L 1.0 0.23 1 05/18/2017:03 108-90-7 ND ug/L 1.0 0.49 1 05/18/2017:03 75-00-3 ND ug/L 5.0 2.3 1 05/18/2017:03 67-66-3 ND ug/L 1.0 0.39 1 05/18/2017:03 74-87-3 ND ug/L 5.0 0.26 1 05/18/2017:03 96-12-8 ND ug/L 1.0 0.41 1 05/18/2017:03 124-48-1 ND ug/L 1.0 0.26 1 05/18/2017:03 106-93-4 ND ug/L 1.0 0.46 1 05/18/2017:03 74-95-3 ND ug/L 1.0 0.29 1 05/18/2017:03 95-50-1 ND ug/L 1.0 0.26 1 05/18/2017:03 106-46-7 ND ug/L 1.0 0.54 1 05/18/2017:03 110-57-6 ND ug/L 1.0 0.27 1 05/18/2017:03 75-34-3 ND ug/L 1.0 0.34 1 05/18/2017:03 107-06-2 ND ug/L 1.0 0.24 1 05/18/2017:03 75-35-4 ND ug/L 1.0 0.29 1 05/18/2017:03 156-59-2 ND ug/L 1.0 0.25 1 05/18/2017:03 156-60-5 ND ug/L 1.0 0.19 1 05/18/2017:03 78-87-5 ND ug/L 1.0 0.30 1 05/18/2017:03 10061-01-5 ND ug/L 1.0 0.31 1 05/18/2017:03 10061-02-6 ND ug/L 1.0 0.26 1 05/18/2017:03 100-41-4 ND ug/L 5.0 0.57 1 05/18/2017:03 591-78-6 ND ug/L 20.0 12.5 1 05/18/2017:03 74-88-4 ND ug/L 5.0 3.7 1 05/18/2017:03 75-09-2 ND ug/L 5.0 4.5 1 05/18/2017:03 108-10-1 ND ug/L 1.0 0.27 1 05/18/2017:03 100-42-5 ND ug/L 1.0 0.34 1 05/18/2017:03 630-20-6 ND ug/L 1.0 0.22 1 05/18/2017:03 79-34-5 ND ug/L 1.0 0.16 1 05/18/2017:03 127-18-4 ND ug/L 1.0 0.24 1 05/18/2017:03 108-88-3 ND ug/L 1.0 0.18 1 05/18/2017:03 71-55-6 ND ug/L 1.0 0.24 1 05/18/2017:03 79-00-5 ND ug/L 1.0 0.22 1 05/18/2017:03 79-01-6 ND ug/L 1.0 0.31 1 05/18/2017:03 75-69-4 ND ug/L 1.0 0.35 1 05/18/2017:03 96-18-4 ND ug/L 2.0 1.4 1 05/18/2017:03 108-05-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IK,v2 IN IK IH IK Page 20 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Sample: TB (NC App I VOCs) Parameters Lab ID: Results 92476718007 Units Collected: Report Limit 05/05/20 06:30 MDL DF Received: 05/07/20 10:55 Matrix: Water Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Vinyl chloride ND ug/L 1.0 0.24 1 05/18/20 17:03 75-01-4 IK Xylene (Total) ND ug/L 1.0 0.63 1 05/18/20 17:03 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 95 % 70-130 1 05/18/20 17:03 460-00-4 1,2-Dichloroethane-d4 (S) 102 % 70-130 1 05/18/20 17:03 17060-07-0 Toluene-d8 (S) 102 % 70-130 1 05/18/20 17:03 2037-26-5 Date: 05/26/2020 04:21 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Sample: TB (8260SIM 1,4-D) Parameters Lab ID: 92476718008 Collected: Report Results Units Limit 05/05/20 06:30 MDL DF Received: 05/07/20 10:55 Matrix: Water Prepared Analyzed CAS No. Qual 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.2 1 05/14/20 22:00 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 95 % 50-150 1 05/14/20 22:00 17060-07-0 Toluene-d8 (S) 96 % 50-150 1 05/14/20 22:00 2037-26-5 Date: 05/26/2020 04:21 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Sample: MW-2 Lab ID: 92476718009 Collected: 05/06/20 08:03 Received: 05/08/20 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 05/21/20 02:40 05/22/20 13:21 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 05/21/20 02:40 05/22/20 13:21 7440-38-2 Barium 1160 ug/L 5.0 3.5 1 05/21/20 02:40 05/22/20 13:21 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 05/21/20 02:40 05/22/20 13:21 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 05/21/20 02:40 05/22/20 13:21 7440-43-9 Chromium ND ug/L 5.0 3.7 1 05/21/20 02:40 05/22/20 13:21 7440-47-3 Cobalt 106 ug/L 5.0 3.6 1 05/21/20 02:40 05/22/20 13:21 7440-48-4 Copper ND ug/L 5.0 4.3 1 05/21/20 02:40 05/22/20 13:21 7440-50-8 Lead ND ug/L 5.0 4.5 1 05/21/20 02:40 05/22/20 13:21 7439-92-1 Nickel 14.4 ug/L 5.0 3.5 1 05/21/20 02:40 05/22/20 13:21 7440-02-0 Selenium 9.2.1 ug/L 10.0 4.7 1 05/21/20 02:40 05/22/20 13:21 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/21/20 02:40 05/22/20 13:21 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 05/21/20 02:40 05/22/20 13:21 7440-62-2 Zinc ND ug/L 10.0 9.5 1 05/21/20 02:40 05/26/20 15:06 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.20 0.12 2 05/13/20 01:37 05/13/20 23:27 7440-28-0 D3 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone 255 ug/L 25.0 6.2 1 05/19/20 07:27 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 05/19/20 07:27 107-13-1 Benzene 9.6 ug/L 1.0 0.15 1 05/19/20 07:27 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 05/19/20 07:27 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 05/19/20 07:27 75-27-4 Bromoform ND ug/L 1.0 0.62 1 05/19/20 07:27 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 05/19/20 07:27 74-83-9 IK,v2 2-Butanone (MEK) 222 ug/L 5.0 3.3 1 05/19/20 07:27 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 05/19/20 07:27 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 05/19/20 07:27 56-23-5 Chlorobenzene 26.7 ug/L 1.0 0.23 1 05/19/20 07:27 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 05/19/20 07:27 75-00-3 IK Chloroform ND ug/L 5.0 2.3 1 05/19/20 07:27 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 05/19/20 07:27 74-87-3 IK 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 05/19/20 07:27 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 05/19/20 07:27 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 05/19/20 07:27 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 05/19/20 07:27 74-95-3 1,2-Dichlorobenzene 2.2 ug/L 1.0 0.29 1 05/19/20 07:27 95-50-1 1,4-Dichlorobenzene 39.0 ug/L 1.0 0.26 1 05/19/20 07:27 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 05/19/20 07:27 110-57-6 IH 1,1-Dichloroethane 0.61J ug/L 1.0 0.27 1 05/19/20 07:27 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 05/19/20 07:27 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 05/19/20 07:27 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Sample: MW-2 Lab ID: 92476718009 Collected: 05/06/20 08:03 Received: 05/08/20 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/26/2020 04:21 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 0.41J ug/L 1.0 0.29 1 05/19/20 07:27 156-59-2 ND ug/L 1.0 0.25 1 05/19/20 07:27 156-60-5 ND ug/L 1.0 0.19 1 05/19/20 07:27 78-87-5 ND ug/L 1.0 0.30 1 05/19/20 07:27 10061-01-5 ND ug/L 1.0 0.31 1 05/19/20 07:27 10061-02-6 17.0 ug/L 1.0 0.26 1 05/19/20 07:27 100-41-4 ND ug/L 5.0 0.57 1 05/19/20 07:27 591-78-6 ND ug/L 20.0 12.5 1 05/19/20 07:27 74-88-4 v2 ND ug/L 5.0 3.7 1 05/19/20 07:27 75-09-2 187 ug/L 5.0 4.5 1 05/19/20 07:27 108-10-1 v1 ND ug/L 1.0 0.27 1 05/19/20 07:27 100-42-5 ND ug/L 1.0 0.34 1 05/19/20 07:27 630-20-6 ND ug/L 1.0 0.22 1 05/19/20 07:27 79-34-5 ND ug/L 1.0 0.16 1 05/19/20 07:27 127-18-4 2.5 ug/L 1.0 0.24 1 05/19/20 07:27 108-88-3 ND ug/L 1.0 0.18 1 05/19/20 07:27 71-55-6 ND ug/L 1.0 0.24 1 05/19/20 07:27 79-00-5 ND ug/L 1.0 0.22 1 05/19/20 07:27 79-01-6 ND ug/L 1.0 0.31 1 05/19/20 07:27 75-69-4 IK ND ug/L 1.0 0.35 1 05/19/20 07:27 96-18-4 ND ug/L 2.0 1.4 1 05/19/20 07:27 108-05-4 v1 ND ug/L 1.0 0.24 1 05/19/20 07:27 75-01-4 IK 34.0 ug/L 1.0 0.63 1 05/19/20 07:27 1330-20-7 97 % 70-130 1 05/19/20 07:27 460-00-4 109 % 70-130 1 05/19/20 07:27 17060-07-0 103 % 70-130 1 05/19/20 07:27 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 213 ug/L 10.0 5.8 5 05/15/20 05:52 123-91-1 99 % 50-150 5 05/15/20 05:52 17060-07-0 98 % 50-150 5 05/15/20 05:52 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Sample: MW-31) Lab ID: 92476718010 Collected: 05/05/20 17:57 Received: 05/08/20 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 05/21/20 02:40 05/22/20 13:24 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 05/21/20 02:40 05/22/20 13:24 7440-38-2 Barium 194 ug/L 5.0 3.5 1 05/21/20 02:40 05/22/20 13:24 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 05/21/20 02:40 05/22/20 13:24 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 05/21/20 02:40 05/22/20 13:24 7440-43-9 Chromium ND ug/L 5.0 3.7 1 05/21/20 02:40 05/22/20 13:24 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 05/21/20 02:40 05/22/20 13:24 7440-48-4 Copper ND ug/L 5.0 4.3 1 05/21/20 02:40 05/22/20 13:24 7440-50-8 Lead ND ug/L 5.0 4.5 1 05/21/20 02:40 05/22/20 13:24 7439-92-1 Nickel 24.1 ug/L 5.0 3.5 1 05/21/20 02:40 05/22/20 13:24 7440-02-0 Selenium ND ug/L 10.0 4.7 1 05/21/20 02:40 05/22/20 13:24 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/21/20 02:40 05/22/20 13:24 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 05/21/20 02:40 05/22/20 13:24 7440-62-2 Zinc ND ug/L 10.0 9.5 1 05/21/20 02:40 05/26/20 15:09 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.060 1 05/13/20 01:37 05/13/20 23:36 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 05/18/20 19:12 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 05/18/20 19:12 107-13-1 Benzene 1.4 ug/L 1.0 0.15 1 05/18/20 19:12 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 05/18/20 19:12 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 05/18/20 19:12 75-27-4 Bromoform ND ug/L 1.0 0.62 1 05/18/20 19:12 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 05/18/20 19:12 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 05/18/20 19:12 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 05/18/20 19:12 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 05/18/20 19:12 56-23-5 Chlorobenzene 8.2 ug/L 1.0 0.23 1 05/18/20 19:12 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 05/18/20 19:12 75-00-3 Chloroform ND ug/L 5.0 2.3 1 05/18/20 19:12 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 05/18/20 19:12 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 05/18/20 19:12 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 05/18/20 19:12 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 05/18/20 19:12 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 05/18/20 19:12 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 05/18/20 19:12 95-50-1 1,4-Dichlorobenzene 4.1 ug/L 1.0 0.26 1 05/18/20 19:12 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 05/18/20 19:12 110-57-6 1,1-Dichloroethane 4.8 ug/L 1.0 0.27 1 05/18/20 19:12 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 05/18/20 19:12 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 05/18/20 19:12 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. IK,v2 IK IH Page 25 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Sample: MW-3D Lab ID: 92476718010 Collected: 05/05/20 17:57 Received: 05/08/20 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/26/2020 04:21 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 16.4 ug/L 1.0 0.29 1 05/18/2019:12 156-59-2 ND ug/L 1.0 0.25 1 05/18/2019:12 156-60-5 0.84J ug/L 1.0 0.19 1 05/18/2019:12 78-87-5 ND ug/L 1.0 0.30 1 05/18/2019:12 10061-01-5 ND ug/L 1.0 0.31 1 05/18/2019:12 10061-02-6 ND ug/L 1.0 0.26 1 05/18/2019:12 100-41-4 ND ug/L 5.0 0.57 1 05/18/2019:12 591-78-6 ND ug/L 20.0 12.5 1 05/18/2019:12 74-88-4 ND ug/L 5.0 3.7 1 05/18/2019:12 75-09-2 ND ug/L 5.0 4.5 1 05/18/2019:12 108-10-1 ND ug/L 1.0 0.27 1 05/18/2019:12 100-42-5 ND ug/L 1.0 0.34 1 05/18/2019:12 630-20-6 ND ug/L 1.0 0.22 1 05/18/2019:12 79-34-5 8.1 ug/L 1.0 0.16 1 05/18/2019:12 127-18-4 ND ug/L 1.0 0.24 1 05/18/2019:12 108-88-3 ND ug/L 1.0 0.18 1 05/18/2019:12 71-55-6 ND ug/L 1.0 0.24 1 05/18/2019:12 79-00-5 5.0 ug/L 1.0 0.22 1 05/18/2019:12 79-01-6 ND ug/L 1.0 0.31 1 05/18/2019:12 75-69-4 ND ug/L 1.0 0.35 1 05/18/2019:12 96-18-4 ND ug/L 2.0 1.4 1 05/18/2019:12 108-05-4 0.88J ug/L 1.0 0.24 1 05/18/2019:12 75-01-4 ND ug/L 1.0 0.63 1 05/18/2019:12 1330-20-7 98 % 70-130 1 05/18/2019:12 460-00-4 103 % 70-130 1 05/18/2019:12 17060-07-0 102 % 70-130 1 05/18/2019:12 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 111 ug/L 4.0 2.3 2 05/15/2013:50 123-91-1 101 % 50-150 2 05/15/2013:50 17060-07-0 96 % 50-150 2 05/15/2013:50 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IK v1 IK Page 26 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Sample: MW-6S Lab ID: 92476718011 Collected: 05/06/20 16:20 Received: 05/08/20 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 05/21/20 02:40 05/22/20 13:28 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 05/21/20 02:40 05/22/20 13:28 7440-38-2 Barium 27.2 ug/L 5.0 3.5 1 05/21/20 02:40 05/23/20 19:51 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 05/21/20 02:40 05/22/20 13:28 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 05/21/20 02:40 05/22/20 13:28 7440-43-9 Chromium ND ug/L 5.0 3.7 1 05/21/20 02:40 05/22/20 13:28 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 05/21/20 02:40 05/22/20 13:28 7440-48-4 Copper ND ug/L 5.0 4.3 1 05/21/20 02:40 05/22/20 13:28 7440-50-8 Lead ND ug/L 5.0 4.5 1 05/21/20 02:40 05/22/20 13:28 7439-92-1 Nickel ND ug/L 5.0 3.5 1 05/21/20 02:40 05/22/20 13:28 7440-02-0 Selenium ND ug/L 10.0 4.7 1 05/21/20 02:40 05/22/20 13:28 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/21/20 02:40 05/22/20 13:28 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 05/21/20 02:40 05/22/20 13:28 7440-62-2 Zinc ND ug/L 10.0 9.5 1 05/21/20 02:40 05/23/20 19:51 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.060 1 05/13/20 01:37 05/13/20 23:44 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 05/19/20 20:03 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 05/19/20 20:03 107-13-1 Benzene ND ug/L 1.0 0.15 1 05/19/20 20:03 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 05/19/20 20:03 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 05/19/20 20:03 75-27-4 Bromoform ND ug/L 1.0 0.62 1 05/19/20 20:03 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 05/19/20 20:03 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 05/19/20 20:03 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 05/19/20 20:03 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 05/19/20 20:03 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 05/19/20 20:03 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 05/19/20 20:03 75-00-3 Chloroform ND ug/L 5.0 2.3 1 05/19/20 20:03 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 05/19/20 20:03 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 05/19/20 20:03 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 05/19/20 20:03 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 05/19/20 20:03 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 05/19/20 20:03 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 05/19/20 20:03 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 05/19/20 20:03 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 05/19/20 20:03 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 05/19/20 20:03 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 05/19/20 20:03 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 05/19/20 20:03 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. IH,v2 IH,L1 Page 27 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Sample: MW-6S Lab ID: 92476718011 Collected: 05/06/20 16:20 Received: 05/08/20 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/26/2020 04:21 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 05/19/20 20:03 156-59-2 ND ug/L 1.0 0.25 1 05/19/20 20:03 156-60-5 ND ug/L 1.0 0.19 1 05/19/20 20:03 78-87-5 ND ug/L 1.0 0.30 1 05/19/20 20:03 10061-01-5 ND ug/L 1.0 0.31 1 05/19/20 20:03 10061-02-6 ND ug/L 1.0 0.26 1 05/19/20 20:03 100-41-4 ND ug/L 5.0 0.57 1 05/19/20 20:03 591-78-6 ND ug/L 20.0 12.5 1 05/19/20 20:03 74-88-4 ND ug/L 5.0 3.7 1 05/19/20 20:03 75-09-2 ND ug/L 5.0 4.5 1 05/19/20 20:03 108-10-1 ND ug/L 1.0 0.27 1 05/19/20 20:03 100-42-5 ND ug/L 1.0 0.34 1 05/19/20 20:03 630-20-6 ND ug/L 1.0 0.22 1 05/19/20 20:03 79-34-5 ND ug/L 1.0 0.16 1 05/19/20 20:03 127-18-4 ND ug/L 1.0 0.24 1 05/19/20 20:03 108-88-3 ND ug/L 1.0 0.18 1 05/19/20 20:03 71-55-6 ND ug/L 1.0 0.24 1 05/19/20 20:03 79-00-5 ND ug/L 1.0 0.22 1 05/19/20 20:03 79-01-6 ND ug/L 1.0 0.31 1 05/19/20 20:03 75-69-4 ND ug/L 1.0 0.35 1 05/19/20 20:03 96-18-4 ND ug/L 2.0 1.4 1 05/19/20 20:03 108-05-4 ND ug/L 1.0 0.24 1 05/19/20 20:03 75-01-4 ND ug/L 1.0 0.63 1 05/19/20 20:03 1330-20-7 105 % 70-130 1 05/19/20 20:03 460-00-4 110 % 70-130 1 05/19/20 20:03 17060-07-0 100 % 70-130 1 05/19/20 20:03 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 1.2 1 05/15/20 02:36 123-91-1 111 % 50-150 1 05/15/20 02:36 17060-07-0 103 % 50-150 1 05/15/20 02:36 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v1 Page 28 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Sample: SW-3 Lab ID: 92476718012 Collected: 05/05/20 17:06 Received: 05/08/20 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Hardness, Total(SM 2340B) Vanadium Zinc Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville ND ug/L 5.0 3.0 1 05/21/20 02:40 05/22/20 15:11 7440-36-0 ND ug/L 10.0 4.7 1 05/21/20 02:40 05/22/20 15:11 7440-38-2 32.3 ug/L 5.0 3.5 1 05/21/20 02:40 05/22/20 15:11 7440-39-3 ND ug/L 1.0 0.70 1 05/21/20 02:40 05/22/20 15:11 7440-41-7 ND ug/L 1.0 0.40 1 05/21/20 02:40 05/22/20 15:11 7440-43-9 ND ug/L 5.0 3.7 1 05/21/20 02:40 05/22/20 15:11 7440-47-3 ND ug/L 5.0 3.6 1 05/21/20 02:40 05/22/20 15:11 7440-48-4 ND ug/L 5.0 4.3 1 05/21/20 02:40 05/22/20 15:11 7440-50-8 ND ug/L 5.0 4.5 1 05/21/20 02:40 05/22/20 15:11 7439-92-1 ND ug/L 5.0 3.5 1 05/21/20 02:40 05/22/20 15:11 7440-02-0 ND ug/L 10.0 4.7 1 05/21/20 02:40 05/22/20 15:11 7782-49-2 ND ug/L 5.0 2.5 1 05/21/20 02:40 05/22/20 15:11 7440-22-4 25100 ug/L 662 131 1 05/21/20 02:40 05/22/20 15:11 ND ug/L 5.0 3.9 1 05/21/20 02:40 05/22/20 15:11 7440-62-2 ND ug/L 10.0 9.5 1 05/21/20 02:40 05/22/20 15:11 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.060 1 05/13/20 01:37 05/13/20 23:48 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 05/18/20 19:30 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 05/18/20 19:30 107-13-1 Benzene ND ug/L 1.0 0.15 1 05/18/20 19:30 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 05/18/20 19:30 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 05/18/20 19:30 75-27-4 Bromoform ND ug/L 1.0 0.62 1 05/18/20 19:30 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 05/18/20 19:30 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 05/18/20 19:30 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 05/18/20 19:30 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 05/18/20 19:30 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 05/18/20 19:30 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 05/18/20 19:30 75-00-3 Chloroform ND ug/L 5.0 2.3 1 05/18/20 19:30 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 05/18/20 19:30 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 05/18/20 19:30 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 05/18/20 19:30 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 05/18/20 19:30 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 05/18/20 19:30 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 05/18/20 19:30 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 05/18/20 19:30 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 05/18/20 19:30 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 05/18/20 19:30 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 05/18/20 19:30 107-06-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. IK,v2 IK IK I., Page 29 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Sample: SW-3 Lab ID: 92476718012 Collected: 05/05/20 17:06 Received: 05/08/20 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/26/2020 04:21 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.24 1 05/18/2019:30 75-35-4 ND ug/L 1.0 0.29 1 05/18/2019:30 156-59-2 ND ug/L 1.0 0.25 1 05/18/2019:30 156-60-5 ND ug/L 1.0 0.19 1 05/18/2019:30 78-87-5 ND ug/L 1.0 0.30 1 05/18/2019:30 10061-01-5 ND ug/L 1.0 0.31 1 05/18/2019:30 10061-02-6 ND ug/L 1.0 0.26 1 05/18/2019:30 100-41-4 ND ug/L 5.0 0.57 1 05/18/2019:30 591-78-6 ND ug/L 20.0 12.5 1 05/18/2019:30 74-88-4 ND ug/L 5.0 3.7 1 05/18/2019:30 75-09-2 ND ug/L 5.0 4.5 1 05/18/2019:30 108-10-1 ND ug/L 1.0 0.27 1 05/18/2019:30 100-42-5 ND ug/L 1.0 0.34 1 05/18/2019:30 630-20-6 ND ug/L 1.0 0.22 1 05/18/2019:30 79-34-5 ND ug/L 1.0 0.16 1 05/18/2019:30 127-18-4 ND ug/L 1.0 0.24 1 05/18/2019:30 108-88-3 ND ug/L 1.0 0.18 1 05/18/2019:30 71-55-6 ND ug/L 1.0 0.24 1 05/18/2019:30 79-00-5 ND ug/L 1.0 0.22 1 05/18/2019:30 79-01-6 ND ug/L 1.0 0.31 1 05/18/2019:30 75-69-4 ND ug/L 1.0 0.35 1 05/18/2019:30 96-18-4 ND ug/L 2.0 1.4 1 05/18/2019:30 108-05-4 ND ug/L 1.0 0.24 1 05/18/2019:30 75-01-4 ND ug/L 1.0 0.63 1 05/18/2019:30 1330-20-7 98 % 70-130 1 05/18/2019:30 460-00-4 104 % 70-130 1 05/18/2019:30 17060-07-0 103 % 70-130 1 05/18/2019:30 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 1.2 1 05/14/20 23:39 123-91-1 94 % 50-150 1 05/14/20 23:39 17060-07-0 95 % 50-150 1 05/14/20 23:39 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 119 IK Page 30 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 QC Batch: 541200 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92476718001, 92476718002 METHOD BLANK: 2884206 Associated Lab Samples: 92476718001, 92476718002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 5.0 3.0 05/15/20 01:44 Arsenic ug/L ND 10.0 4.7 05/15/20 20:13 Barium ug/L ND 5.0 3.5 05/15/20 20:13 Beryllium ug/L ND 1.0 0.70 05/15/20 20:13 Cadmium ug/L ND 1.0 0.40 05/15/20 20:13 Chromium ug/L ND 5.0 3.7 05/15/20 20:13 Cobalt ug/L ND 5.0 3.6 05/15/20 20:13 Copper ug/L ND 5.0 4.3 05/15/20 20:13 Lead ug/L ND 5.0 4.5 05/15/20 20:13 Nickel ug/L ND 5.0 3.5 05/15/20 20:13 Selenium ug/L ND 10.0 4.7 05/15/20 20:13 Silver ug/L ND 5.0 2.5 05/15/20 20:13 Vanadium ug/L ND 5.0 3.9 05/15/20 20:13 Zinc ug/L ND 10.0 9.5 05/15/20 20:13 LABORATORY CONTROL SAMPLE: Parameter 2884207 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 461 92 80-120 Arsenic ug/L 500 495 99 80-120 Barium ug/L 500 509 102 80-120 Beryllium ug/L 500 502 100 80-120 Cadmium ug/L 500 509 102 80-120 Chromium ug/L 500 510 102 80-120 Cobalt ug/L 500 507 101 80-120 Copper ug/L 500 528 106 80-120 Lead ug/L 500 509 102 80-120 Nickel ug/L 500 503 101 80-120 Selenium ug/L 500 494 99 80-120 Silver ug/L 250 234 94 80-120 Vanadium ug/L 500 514 103 80-120 Zinc ug/L 500 494 99 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Burke Co (Kirksey Drive) 92476718 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2884208 2884209 MS MSD 92477131001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 225 229 45 46 75-125 2 20 M1 Arsenic ug/L ND 500 500 398 386 80 77 75-125 3 20 Barium ug/L 3060 500 500 3540 3350 97 59 75-125 5 20 M1 Beryllium ug/L 3.4 500 500 463 449 92 89 75-125 3 20 Cadmium ug/L 2.5 500 500 459 445 91 88 75-125 3 20 Chromium ug/L 319 500 500 784 748 93 86 75-125 5 20 Cobalt ug/L 251 500 500 689 644 88 79 75-125 7 20 Copper ug/L 443 500 500 979 930 107 97 75-125 5 20 Lead ug/L 68.8 500 500 531 514 93 89 75-125 3 20 Nickel ug/L 565 500 500 976 901 82 67 75-125 8 20 M1 Selenium ug/L 19.5 500 500 389 378 74 72 75-125 3 20 M1 Silver ug/L ND 250 250 214 216 86 87 75-125 1 20 Vanadium ug/L 456 500 500 943 896 97 88 75-125 5 20 Zinc ug/L 649 500 500 1090 1030 88 75 75-125 6 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 QC Batch: 541201 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92476718003, 92476718004, 92476718005 METHOD BLANK: 2884210 Matrix: Water Associated Lab Samples: 92476718003, 92476718004, 92476718005 Blank Reporting Parameter Units Result Limit Antimony ug/L ND Arsenic ug/L ND Barium ug/L ND Beryllium ug/L ND Cadmium ug/L ND Chromium ug/L ND Cobalt ug/L ND Copper ug/L ND Hardness, Total(SM 2340B) ug/L ND Lead ug/L ND Nickel ug/L ND Selenium ug/L ND Silver ug/L ND Vanadium ug/L ND Zinc ug/L ND LABORATORY CONTROL SAMPLE: 2884211 Parameter Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Hardness, Total(SM 2340B) Lead Nickel Selenium Silver Vanadium Zinc 5.0 10.0 5.0 1.0 1.0 5.0 5.0 5.0 662 5.0 5.0 10.0 5.0 5.0 10.0 MDL Analyzed 3.0 05/20/20 00:20 4.7 05/18/2017:17 3.5 05/18/2017:17 0.70 05/18/2017:17 0.40 05/18/2017:17 3.7 05/18/2017:17 3.6 05/18/2017:17 4.3 05/18/2017:17 131 05/18/20 17:17 4.5 05/18/2017:17 3.5 05/18/2017:17 4.7 05/18/2017:17 2.5 05/18/2017:17 3.9 05/18/2017:17 9.5 05/18/2017:17 Units Spike Conc. LCS Result LCS % Rec % Rec Limits ug/L 500 453 91 80-120 ug/L 500 475 95 80-120 ug/L 500 502 100 80-120 ug/L 500 497 99 80-120 ug/L 500 494 99 80-120 ug/L 500 509 102 80-120 ug/L 500 496 99 80-120 ug/L 500 514 103 80-120 ug/L 33100 32200 97 80-120 ug/L 500 487 97 80-120 ug/L 500 489 98 80-120 ug/L 500 486 97 80-120 ug/L 250 250 100 80-120 ug/L 500 498 100 80-120 ug/L 500 473 95 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2884212 2884213 MS MSD 92476718003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 488 469 98 94 75-125 4 20 Arsenic ug/L ND 500 500 520 500 104 100 75-125 4 20 Barium ug/L 55.4 500 500 584 569 106 103 75-125 3 20 Beryllium ug/L ND 500 500 533 519 107 104 75-125 3 20 Cadmium ug/L ND 500 500 523 509 105 102 75-125 3 20 Chromium ug/L ND 500 500 542 527 108 105 75-125 3 20 Cobalt ug/L ND 500 500 529 513 105 102 75-125 3 20 Copper ug/L ND 500 500 547 532 109 106 75-125 3 20 Hardness, Total(SM 2340B) ug/L 5760 33100 33100 40400 39200 105 101 75-125 3 Lead ug/L ND 500 500 519 503 103 100 75-125 3 20 Nickel ug/L ND 500 500 522 507 104 101 75-125 3 20 Selenium ug/L 7.2J 500 500 533 523 105 103 75-125 2 20 Silver ug/L ND 250 250 261 254 104 102 75-125 3 20 Vanadium ug/L 7.2 500 500 535 519 105 102 75-125 3 20 Zinc ug/L 12.6 500 500 520 509 102 99 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 QC Batch: 542769 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92476718006, 92476718009, 92476718010, 92476718011, 92476718012 METHOD BLANK: 2891512 Matrix: Water Associated Lab Samples: 92476718006, 92476718009, 92476718010, 92476718011, 92476718012 Blank Reporting Parameter Units Result Limit MDL Analyzed Antimony ug/L ND 5.0 3.0 05/22/2012:59 Arsenic ug/L ND 10.0 4.7 05/23/2019:16 Barium ug/L ND 5.0 3.5 05/22/2012:59 Beryllium ug/L ND 1.0 0.70 05/22/2012:59 Cadmium ug/L ND 1.0 0.40 05/22/2012:59 Chromium ug/L ND 5.0 3.7 05/22/2012:59 Cobalt ug/L ND 5.0 3.6 05/22/2012:59 Copper ug/L ND 5.0 4.3 05/22/2012:59 Hardness, Total(SM 2340B) ug/L ND 662 131 05/22/20 12:59 Lead ug/L ND 5.0 4.5 05/22/2012:59 Nickel ug/L ND 5.0 3.5 05/22/2012:59 Selenium ug/L ND 10.0 4.7 05/22/2012:59 Silver ug/L ND 5.0 2.5 05/23/2019:16 Vanadium ug/L ND 5.0 3.9 05/22/2012:59 Zinc ug/L ND 10.0 9.5 05/23/2019:16 LABORATORY CONTROL SAMPLE: Parameter 2891513 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 474 95 80-120 Arsenic ug/L 500 458 92 80-120 Barium ug/L 500 456 91 80-120 Beryllium ug/L 500 455 91 80-120 Cadmium ug/L 500 458 92 80-120 Chromium ug/L 500 437 87 80-120 Cobalt ug/L 500 461 92 80-120 Copper ug/L 500 464 93 80-120 Hardness, Total(SM 2340B) ug/L 33100 28800 87 80-120 Lead ug/L 500 460 92 80-120 Nickel ug/L 500 455 91 80-120 Selenium ug/L 500 467 93 80-120 Silver ug/L 250 219 88 80-120 Vanadium ug/L 500 442 88 80-120 Zinc ug/L 500 444 89 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2891514 2891515 MS MSD 92476718006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 499 503 100 101 75-125 1 20 Arsenic ug/L ND 500 500 487 495 97 99 75-125 2 20 Barium ug/L 28.7 500 500 521 518 98 98 75-125 0 20 Beryllium ug/L ND 500 500 490 488 98 98 75-125 0 20 Cadmium ug/L ND 500 500 496 500 99 100 75-125 1 20 Chromium ug/L ND 500 500 465 453 93 91 75-125 3 20 Cobalt ug/L ND 500 500 489 493 98 98 75-125 1 20 Copper ug/L ND 500 500 496 483 99 97 75-125 3 20 Hardness, Total(SM 2340B) ug/L 22600 33100 33100 53500 52500 94 91 75-125 2 Lead ug/L ND 500 500 489 490 98 98 75-125 0 20 Nickel ug/L ND 500 500 482 486 96 97 75-125 1 20 Selenium ug/L ND 500 500 520 523 104 105 75-125 1 20 Silver ug/L ND 250 250 234 227 93 91 75-125 3 20 Vanadium ug/L ND 500 500 474 465 94 92 75-125 2 20 Zinc ug/L ND 500 500 486 488 96 97 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 QC Batch: 540953 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92476718001, 92476718002, 92476718003, 92476718004, 92476718005 METHOD BLANK: 2883084 Matrix: Water Associated Lab Samples: 92476718001, 92476718002, 92476718003, 92476718004, 92476718005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 05/13/20 00:36 LABORATORY CONTROL SAMPLE: 2883085 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10.0 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2883086 2883087 MS MSD 92476875005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 10.1 10.0 101 100 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 QC Batch: 541202 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92476718006, 92476718009, 92476718010, 92476718011, 92476718012 METHOD BLANK: 2884214 Matrix: Water Associated Lab Samples: 92476718006, 92476718009, 92476718010, 92476718011, 92476718012 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.050 05/14/2014:08 LABORATORY CONTROL SAMPLE: 2884215 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 9.7 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2884216 2884217 MS MSD 92476703001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L 0.12 10 10 9.9 9.9 98 98 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 QC Batch: 542112 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92476718001, 92476718006, 92476718007, 92476718010, 92476718012 METHOD BLANK: 2888661 Matrix: Water Associated Lab Samples: 92476718001, 92476718006, 92476718007, 92476718010, 92476718012 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 05/18/20 11:33 1,1,1-Trichloroethane ug/L ND 1.0 0.18 05/18/20 11:33 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 05/18/20 11:33 1,1,2-Trichloroethane ug/L ND 1.0 0.24 05/18/20 11:33 1,1-Dichloroethane ug/L ND 1.0 0.27 05/18/20 11:33 1,1-Dichloroethene ug/L ND 1.0 0.24 05/18/20 11:33 1,2,3-Trichloropropane ug/L ND 1.0 0.35 05/18/20 11:33 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 05/18/20 11:33 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 05/18/20 11:33 1,2-Dichlorobenzene ug/L ND 1.0 0.29 05/18/20 11:33 1,2-Dichloroethane ug/L ND 1.0 0.34 05/18/20 11:33 1,2-Dichloropropane ug/L ND 1.0 0.19 05/18/20 11:33 1,4-Dichlorobenzene ug/L ND 1.0 0.26 05/18/20 11:33 2-Butanone (MEK) ug/L ND 5.0 3.3 05/18/20 11:33 2-Hexanone ug/L ND 5.0 0.57 05/18/20 11:33 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 05/18/20 11:33 Acetone ug/L ND 25.0 6.2 05/18/20 11:33 Acrylonitrile ug/L ND 10.0 0.90 05/18/20 11:33 Benzene ug/L ND 1.0 0.15 05/18/20 11:33 Bromochloromethane ug/L ND 1.0 0.34 05/18/20 11:33 Bromodichloromethane ug/L ND 1.0 0.26 05/18/20 11:33 Bromoform ug/L ND 1.0 0.62 05/18/20 11:33 Bromomethane ug/L ND 2.0 0.62 05/18/20 11:33 Carbon disulfide ug/L ND 2.0 0.40 05/18/20 11:33 Carbon tetrachloride ug/L ND 1.0 0.22 05/18/20 11:33 Chlorobenzene ug/L ND 1.0 0.23 05/18/20 11:33 Chloroethane ug/L ND 1.0 0.49 05/18/20 11:33 Chloroform ug/L ND 5.0 2.3 05/18/20 11:33 Chloromethane ug/L ND 1.0 0.39 05/18/20 11:33 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 05/18/20 11:33 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 05/18/20 11:33 Dibromochloromethane ug/L ND 1.0 0.41 05/18/20 11:33 Dibromomethane ug/L ND 1.0 0.46 05/18/20 11:33 Ethylbenzene ug/L ND 1.0 0.26 05/18/20 11:33 lodomethane ug/L ND 20.0 12.5 05/18/20 11:33 Methylene Chloride ug/L ND 5.0 3.7 05/18/20 11:33 Styrene ug/L ND 1.0 0.27 05/18/20 11:33 Tetrachloroethene ug/L ND 1.0 0.16 05/18/20 11:33 Toluene ug/L ND 1.0 0.24 05/18/20 11:33 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 05/18/20 11:33 Qualifiers I K,v2 IK IK Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 39 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 METHOD BLANK: 2888661 Matrix: Water Associated Lab Samples: 92476718001, 92476718006, 92476718007, 92476718010, 92476718012 Blank Reporting Parameter Units Result Limit MDL Analyzed trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 05/18/20 11:33 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 05/18/20 11:33 Trichloroethene ug/L ND 1.0 0.22 05/18/20 11:33 Trichlorofluoromethane ug/L ND 1.0 0.31 05/18/20 11:33 Vinyl acetate ug/L ND 2.0 1.4 05/18/20 11:33 Vinyl chloride ug/L ND 1.0 0.24 05/18/20 11:33 Xylene (Total) ug/L ND 1.0 0.63 05/18/20 11:33 1,2-Dichloroethane-d4 (S) % 98 70-130 05/18/20 11:33 4-Bromofluorobenzene (S) % 97 70-130 05/18/20 11:33 Toluene-d8 (S) % 101 70-130 05/18/20 11:33 LABORATORY CONTROL SAMPLE: 2888662 Parameter Qualifiers IH IK IK Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 52.2 104 70-130 1,1,1-Trichloroethane ug/L 50 48.3 97 70-130 1,1,2,2-Tetrachloroethane ug/L 50 49.9 100 70-130 1,1,2-Trichloroethane ug/L 50 50.4 101 70-130 1,1-Dichloroethane ug/L 50 46.5 93 70-130 1,1-Dichloroethene ug/L 50 48.3 97 70-130 1,2,3-Trichloropropane ug/L 50 51.0 102 70-130 1,2-Dibromo-3-chloropropane ug/L 50 56.3 113 70-130 1,2-Dibromoethane (EDB) ug/L 50 52.0 104 70-130 1,2-Dichlorobenzene ug/L 50 51.9 104 70-130 1,2-Dichloroethane ug/L 50 46.2 92 70-130 1,2-Dichloropropane ug/L 50 49.2 98 70-130 1,4-Dichlorobenzene ug/L 50 51.6 103 70-130 2-Butanone (MEK) ug/L 100 102 102 64-135 2-Hexanone ug/L 100 104 104 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 107 107 70-130 Acetone ug/L 100 96.9 97 61-157 Acrylonitrile ug/L 250 236 95 61-143 Benzene ug/L 50 49.0 98 70-130 Bromochloromethane ug/L 50 47.2 94 70-130 Bromodichloromethane ug/L 50 53.1 106 70-130 Bromoform ug/L 50 53.3 107 70-130 Bromomethane ug/L 50 37.6 75 38-130lK,v3 Carbon disulfide ug/L 50 47.3 95 68-130 Carbon tetrachloride ug/L 50 51.8 104 70-130 Chlorobenzene ug/L 50 50.1 100 70-130 Chloroethane ug/L 50 33.4 67 37-142 IK Chloroform ug/L 50 46.5 93 70-130 Chloromethane ug/L 50 41.4 83 48-130lK cis-1,2-Dichloroethene ug/L 50 46.8 94 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 69 Pace Analytical Services, LLC lac, Analyilcal ® 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 LABORATORY CONTROL SAMPLE: Parameter 2888662 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 51.6 103 70-130 Dibromochloromethane ug/L 50 53.6 107 70-130 Dibromomethane ug/L 50 49.8 100 70-130 Ethylbenzene ug/L 50 47.1 94 70-130 lodomethane ug/L 100 75.3 75 40-130 Methylene Chloride ug/L 50 44.2 88 67-132 Styrene ug/L 50 51.9 104 70-130 Tetrachloroethene ug/L 50 51.1 102 69-130 Toluene ug/L 50 47.5 95 70-130 trans-1,2-Dichloroethene ug/L 50 47.6 95 70-130 trans- 1,3-Dichloropropene ug/L 50 52.4 105 70-130 trans-1,4-Dichloro-2-butene ug/L 50 65.0 130 35-1891H Trichloroethene ug/L 50 48.4 97 70-130 Trichlorofluoromethane ug/L 50 45.3 91 63-1301K Vinyl acetate ug/L 100 111 111 55-143 Vinyl chloride ug/L 50 49.5 99 70-131 IK Xylene (Total) ug/L 150 143 95 70-130 1,2-Dichloroethane-d4 (S) % 89 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8(S) % 101 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2888663 MS 92476718010 Spike Parameter Units Result Conc. MSD Spike Conc. 2888664 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 21.3 20.5 106 103 73-134 3 30 1,1,1-Trichloroethane ug/L ND 20 20 20.1 20.7 101 103 82-143 3 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 21.2 22.1 106 111 70-136 4 30 1,1,2-Trichloroethane ug/L ND 20 20 19.7 19.7 98 98 70-135 0 30 1,1-Dichloroethane ug/L 4.8 20 20 26.5 27.0 108 111 70-139 2 30 1,1-Dichloroethene ug/L ND 20 20 23.1 23.3 116 117 70-154 1 30 1,2,3-Trichloropropane ug/L ND 20 20 21.1 21.6 106 108 71-137 2 30 1,2-Dibromo-3- ug/L ND 20 20 18.5 19.5 93 98 65-134 5 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 21.5 22.2 107 111 70-137 4 30 1,2-Dichlorobenzene ug/L ND 20 20 23.7 24.5 119 123 70-133 3 30 1,2-Dichloroethane ug/L ND 20 20 20.8 22.3 104 111 70-137 7 30 1,2-Dichloropropane ug/L 0.84J 20 20 23.6 24.0 114 116 70-140 2 30 1,4-Dichlorobenzene ug/L 4.1 20 20 27.7 28.7 118 123 70-133 4 30 2-Butanone (MEK) ug/L ND 40 40 39.6 41.1 99 103 60-139 4 30 2-Hexanone ug/L ND 40 40 44.4 45.8 111 114 65-138 3 30 4-Methyl-2-pentanone ug/L ND 40 40 41.4 40.8 104 102 65-135 1 30 (MIBK) Acetone ug/L ND 40 40 49.2 54.1 123 135 60-148 10 30 Acrylonitrile ug/L ND 100 100 104 104 104 104 64-147 0 30 Benzene ug/L 1.4 20 20 23.4 23.1 110 108 70-151 1 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2888663 MS 92476718010 Spike Parameter Units Result Conc. MSD Spike Conc. 2888664 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Bromochloromethane ug/L ND 20 20 19.6 20.4 98 102 70-141 4 30 Bromodichloromethane ug/L ND 20 20 19.6 20.1 98 100 70-138 2 30 Bromoform ug/L ND 20 20 18.1 18.4 90 92 63-130 2 30 Bromomethane ug/L ND 20 20 24.4 24.7 122 123 15-152 1 30 IH,v2 Carbon disulfide ug/L ND 20 20 21.7 21.2 109 106 69-149 2 30 Carbon tetrachloride ug/L ND 20 20 21.5 21.3 108 107 70-143 1 30 Chlorobenzene ug/L 8.2 20 20 32.2 31.5 120 116 70-138 2 30 Chloroethane ug/L ND 20 20 20.5 21.8 102 109 52-163 6 30 Chloroform ug/L ND 20 20 21.5 20.8 108 104 70-139 3 30 Chloromethane ug/L ND 20 20 18.8 18.1 94 91 41-139 4 30 cis-1,2-Dichloroethene ug/L 16.4 20 20 37.6 38.5 106 110 70-141 2 30 cis-1,3-Dichloropropene ug/L ND 20 20 19.9 20.4 100 102 70-137 2 30 Dibromochloromethane ug/L ND 20 20 20.4 21.2 102 106 70-134 4 30 Dibromomethane ug/L ND 20 20 20.7 20.4 103 102 70-138 1 30 Ethylbenzene ug/L ND 20 20 22.3 22.9 111 114 66-153 3 30 lodomethane ug/L ND 40 40 23.3 24.5 58 61 20-138 5 30 Methylene Chloride ug/L ND 20 20 24.9 24.9 125 125 42-159 0 30 Styrene ug/L ND 20 20 18.6 16.9 93 85 70-135 10 30 Tetrachloroethene ug/L 8.1 20 20 31.7 31.4 118 117 59-143 1 30 Toluene ug/L ND 20 20 20.6 20.0 103 100 59-148 3 30 trans-1,2-Dichloroethene ug/L ND 20 20 22.4 22.8 112 114 70-146 2 30 trans-1,3-Dichloropropene ug/L ND 20 20 19.1 19.7 96 98 70-135 3 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 21.7 21.8 108 109 47-135 1 30 IH Trichloroethene ug/L 5.0 20 20 27.1 27.0 111 110 70-147 0 30 Trichlorofluoromethane ug/L ND 20 20 18.9 18.3 95 92 70-148 3 30 Vinyl acetate ug/L ND 40 40 42.9 42.1 107 105 49-151 2 30 v1 Vinyl chloride ug/L 0.88J 20 20 22.3 22.1 107 106 70-156 1 30 Xylene (Total) ug/L ND 60 60 70.3 69.5 117 116 63-158 1 30 1,2-Dichloroethane-d4 (S) % 107 105 70-130 4-Bromofluorobenzene (S) % 104 99 70-130 Toluene-d8 (S) % 97 99 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 42 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 QC Batch: 542117 QC Batch Method: EPA 8260D Associated Lab Samples: 92476718002, 92476718003 METHOD BLANK: 2888703 Associated Lab Samples: 92476718002, 92476718003 Parameter Units 1,1,1,2-Tetrachloroethane ug/L 1,1,1-Trichloroethane ug/L 1,1,2,2-Tetrachloroethane ug/L 1,1,2-Trichloroethane ug/L 1,1-Dichloroethane ug/L 1,1-Dichloroethene ug/L 1,2,3-Trichloropropane ug/L 1,2-Dibromo-3-chloropropane ug/L 1,2-Dibromoethane (EDB) ug/L 1,2-Dichlorobenzene ug/L 1,2-Dichloroethane ug/L 1,2-Dichloropropane ug/L 1,4-Dichlorobenzene ug/L 2-Butanone (MEK) ug/L 2-Hexanone ug/L 4-Methyl-2-pentanone (MIBK) ug/L Acetone ug/L Acrylonitrile ug/L Benzene ug/L Bromochloromethane ug/L Bromodichloromethane ug/L Bromoform ug/L Bromomethane ug/L Carbon disulfide ug/L Carbon tetrachloride ug/L Chlorobenzene ug/L Chloroethane ug/L Chloroform ug/L Chloromethane ug/L cis-1,2-Dichloroethene ug/L cis-1,3-Dichloropropene ug/L Dibromochloromethane ug/L Dibromomethane ug/L Ethylbenzene ug/L lodomethane ug/L Methylene Chloride ug/L Styrene ug/L Tetrachloroethene ug/L Toluene ug/L trans-1,2-Dichloroethene ug/L QUALITY CONTROL DATA Analysis Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Matrix: Water Blank Result Reporting Limit MDL Analyzed Qualifiers ND 1.0 0.34 05/19/20 00:24 ND 1.0 0.18 05/19/20 00:24 ND 1.0 0.22 05/19/20 00:24 ND 1.0 0.24 05/19/20 00:24 ND 1.0 0.27 05/19/20 00:24 ND 1.0 0.24 05/19/20 00:24 ND 1.0 0.35 05/19/20 00:24 ND 5.0 0.26 05/19/20 00:24 ND 1.0 0.26 05/19/20 00:24 ND 1.0 0.29 05/19/20 00:24 ND 1.0 0.34 05/19/20 00:24 ND 1.0 0.19 05/19/20 00:24 ND 1.0 0.26 05/19/20 00:24 ND 5.0 3.3 05/19/20 00:24 ND 5.0 0.57 05/19/20 00:24 ND 5.0 4.5 05/19/20 00:24 v1 ND 25.0 6.2 05/19/20 00:24 ND 10.0 0.90 05/19/20 00:24 ND 1.0 0.15 05/19/20 00:24 ND 1.0 0.34 05/19/20 00:24 ND 1.0 0.26 05/19/20 00:24 ND 1.0 0.62 05/19/20 00:24 ND 2.0 0.62 05/19/20 00:24 IK,v2 ND 2.0 0.40 05/19/20 00:24 ND 1.0 0.22 05/19/20 00:24 ND 1.0 0.23 05/19/20 00:24 ND 1.0 0.49 05/19/20 00:24 I K ND 5.0 2.3 05/19/20 00:24 ND 1.0 0.39 05/19/20 00:24 I K ND 1.0 0.29 05/19/20 00:24 ND 1.0 0.30 05/19/20 00:24 ND 1.0 0.41 05/19/20 00:24 ND 1.0 0.46 05/19/20 00:24 ND 1.0 0.26 05/19/20 00:24 ND 20.0 12.5 05/19/20 00:24 v2 ND 5.0 3.7 05/19/20 00:24 ND 1.0 0.27 05/19/20 00:24 ND 1.0 0.16 05/19/20 00:24 ND 1.0 0.24 05/19/20 00:24 ND 1.0 0.25 05/19/20 00:24 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 43 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 METHOD BLANK: 2888703 Associated Lab Samples: 92476718002, 92476718003 Parameter Units trans- 1,3-Dichloropropene ug/L trans-1,4-Dichloro-2-butene ug/L Trichloroethene ug/L Trichlorofluoromethane ug/L Vinyl acetate ug/L Vinyl chloride ug/L Xylene (Total) ug/L 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % LABORATORY CONTROL SAMPLE: 2888704 Parameter QUALITY CONTROL DATA Matrix: Water Blank Result Reporting Limit ND 1.0 ND 1.0 ND 1.0 ND 1.0 ND 2.0 ND 1.0 ND 1.0 102 70-130 97 70-130 102 70-130 MDL Analyzed 0.31 05/19/20 00:24 0.54 05/19/20 00:24 0.22 05/19/20 00:24 0.31 05/19/20 00:24 1.4 05/19/20 00:24 0.24 05/19/20 00:24 0.63 05/19/20 00:24 05/19/20 00:24 05/19/20 00:24 05/19/20 00:24 IH IK v1 IK Qualifiers Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 55.7 111 70-130 1,1,1-Trichloroethane ug/L 50 52.5 105 70-130 1,1,2,2-Tetrachloroethane ug/L 50 53.5 107 70-130 1,1,2-Trichloroethane ug/L 50 54.0 108 70-130 1,1-Dichloroethane ug/L 50 51.7 103 70-130 1,1-Dichloroethene ug/L 50 53.0 106 70-130 1,2,3-Trichloropropane ug/L 50 55.2 110 70-130 1,2-Dibromo-3-chloropropane ug/L 50 58.4 117 70-130 1,2-Dibromoethane (EDB) ug/L 50 54.7 109 70-130 1,2-Dichlorobenzene ug/L 50 53.3 107 70-130 1,2-Dichloroethane ug/L 50 51.9 104 70-130 1,2-Dichloropropane ug/L 50 54.4 109 70-130 1,4-Dichlorobenzene ug/L 50 52.0 104 70-130 2-Butanone (MEK) ug/L 100 119 119 64-135 2-Hexanone ug/L 100 117 117 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 121 121 70-130 v1 Acetone ug/L 100 119 119 61-157 Acrylonitrile ug/L 250 259 104 61-143 Benzene ug/L 50 53.0 106 70-130 Bromochloromethane ug/L 50 48.8 98 70-130 Bromodichloromethane ug/L 50 56.4 113 70-130 Bromoform ug/L 50 56.0 112 70-130 Bromomethane ug/L 50 37.1 74 38-130lK,v3 Carbon disulfide ug/L 50 52.3 105 68-130 Carbon tetrachloride ug/L 50 55.3 111 70-130 Chlorobenzene ug/L 50 53.2 106 70-130 Chloroethane ug/L 50 37.6 75 37-142 IK Chloroform ug/L 50 51.3 103 70-130 Chloromethane ug/L 50 47.6 95 48-130lK cis-1,2-Dichloroethene ug/L 50 52.0 104 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 69 Pace Analytical Services, LLC lac, Analyilcal ® 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 LABORATORY CONTROL SAMPLE: Parameter 2888704 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 55.3 111 70-130 Dibromochloromethane ug/L 50 56.6 113 70-130 Dibromomethane ug/L 50 51.6 103 70-130 Ethylbenzene ug/L 50 50.6 101 70-130 lodomethane ug/L 100 78.8 79 40-130 v3 Methylene Chloride ug/L 50 48.7 97 67-132 Styrene ug/L 50 54.8 110 70-130 Tetrachloroethene ug/L 50 52.4 105 69-130 Toluene ug/L 50 51.1 102 70-130 trans-1,2-Dichloroethene ug/L 50 51.6 103 70-130 trans- 1,3-Dichloropropene ug/L 50 56.0 112 70-130 trans-1,4-Dichloro-2-butene ug/L 50 88.6 177 35-1891H Trichloroethene ug/L 50 51.5 103 70-130 Trichlorofluoromethane ug/L 50 51.6 103 63-1301K Vinyl acetate ug/L 100 120 120 55-143 v1 Vinyl chloride ug/L 50 56.1 112 70-131 IK Xylene (Total) ug/L 150 154 103 70-130 1,2-Dichloroethane-d4 (S) % 96 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 103 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2888705 MS 92476718003 Spike Parameter Units Result Conc. MSD Spike Conc. 2888706 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 22.3 21.7 111 108 73-134 3 30 1,1,1-Trichloroethane ug/L ND 20 20 20.3 21.8 101 109 82-143 7 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 21.3 21.7 106 109 70-136 2 30 1,1,2-Trichloroethane ug/L ND 20 20 19.7 20.0 98 100 70-135 1 30 1,1-Dichloroethane ug/L ND 20 20 21.8 22.8 109 114 70-139 5 30 1,1-Dichloroethene ug/L ND 20 20 22.7 24.1 114 121 70-154 6 30 1,2,3-Trichloropropane ug/L ND 20 20 21.4 22.0 107 110 71-137 3 30 1,2-Dibromo-3- ug/L ND 20 20 18.7 18.4 94 92 65-134 2 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 21.5 22.1 107 111 70-137 3 30 1,2-Dichlorobenzene ug/L ND 20 20 24.1 25.8 121 129 70-133 7 30 1,2-Dichloroethane ug/L ND 20 20 21.5 22.3 108 111 70-137 3 30 1,2-Dichloropropane ug/L ND 20 20 22.3 22.6 112 113 70-140 1 30 1,4-Dichlorobenzene ug/L ND 20 20 24.2 23.9 121 120 70-133 1 30 2-Butanone (MEK) ug/L ND 40 40 37.8 40.3 94 101 60-139 6 30 2-Hexanone ug/L ND 40 40 43.5 43.4 109 108 65-138 0 30 4-Methyl-2-pentanone ug/L ND 40 40 39.2 40.7 98 102 65-135 4 30 (MIBK) Acetone ug/L ND 40 40 38.9 42.2 97 106 60-148 8 30 Acrylonitrile ug/L ND 100 100 102 108 102 108 64-147 5 30 Benzene ug/L ND 20 20 21.7 23.1 109 115 70-151 6 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2888705 MS 92476718003 Spike Parameter Units Result Conc. MSD Spike Conc. 2888706 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Bromochloromethane ug/L ND 20 20 19.0 21.2 95 106 70-141 11 30 Bromodichloromethane ug/L ND 20 20 19.4 20.2 97 101 70-138 4 30 Bromoform ug/L ND 20 20 17.3 18.4 86 92 63-130 7 30 Bromomethane ug/L ND 20 20 24.9 26.3 124 131 15-152 5 30 IH,v3 Carbon disulfide ug/L ND 20 20 21.1 21.9 106 110 69-149 4 30 Carbon tetrachloride ug/L ND 20 20 20.7 21.2 104 106 70-143 2 30 Chlorobenzene ug/L ND 20 20 23.3 23.3 117 116 70-138 0 30 Chloroethane ug/L ND 20 20 20.3 22.0 102 110 52-163 8 30 Chloroform ug/L ND 20 20 21.2 22.3 106 112 70-139 5 30 Chloromethane ug/L ND 20 20 17.7 19.0 88 95 41-139 7 30 cis-1,2-Dichloroethene ug/L ND 20 20 21.4 22.5 107 112 70-141 5 30 cis-1,3-Dichloropropene ug/L ND 20 20 20.2 20.6 101 103 70-137 2 30 Dibromochloromethane ug/L ND 20 20 20.2 21.7 101 108 70-134 7 30 Dibromomethane ug/L ND 20 20 21.1 20.6 105 103 70-138 2 30 Ethylbenzene ug/L ND 20 20 22.4 22.9 112 115 66-153 2 30 lodomethane ug/L ND 40 40 22.7 24.3 57 61 20-138 7 30 v3 Methylene Chloride ug/L ND 20 20 24.5 24.5 122 123 42-159 0 30 Styrene ug/L ND 20 20 23.2 22.9 116 114 70-135 1 30 Tetrachloroethene ug/L ND 20 20 21.7 21.6 109 108 59-143 1 30 Toluene ug/L ND 20 20 20.3 21.3 101 106 59-148 5 30 trans-1,2-Dichloroethene ug/L ND 20 20 22.0 24.0 110 120 70-146 9 30 trans-1,3-Dichloropropene ug/L ND 20 20 19.4 19.7 97 98 70-135 1 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 20.5 19.2 103 96 47-135 7 30 IH Trichloroethene ug/L ND 20 20 21.7 21.5 109 107 70-147 1 30 Trichlorofluoromethane ug/L ND 20 20 18.0 18.5 90 93 70-148 3 30 Vinyl acetate ug/L ND 40 40 44.0 46.1 110 115 49-151 5 30 v1 Vinyl chloride ug/L ND 20 20 21.0 22.0 105 110 70-156 5 30 Xylene (Total) ug/L ND 60 60 69.6 70.6 116 118 63-158 2 30 1,2-Dichloroethane-d4 (S) % 106 106 70-130 4-Bromofluorobenzene (S) % 96 99 70-130 Toluene-d8 (S) % 98 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 46 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 QC Batch: 542119 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92476718004, 92476718005, 92476718009 METHOD BLANK: 2888719 Matrix: Associated Lab Samples: 92476718004, 92476718005, 92476718009 Blank Parameter Units Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 05/19/20 00:06 1,1,1-Trichloroethane ug/L ND 1.0 0.18 05/19/20 00:06 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 05/19/20 00:06 1,1,2-Trichloroethane ug/L ND 1.0 0.24 05/19/20 00:06 1,1-Dichloroethane ug/L ND 1.0 0.27 05/19/20 00:06 1,1-Dichloroethene ug/L ND 1.0 0.24 05/19/20 00:06 1,2,3-Trichloropropane ug/L ND 1.0 0.35 05/19/20 00:06 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 05/19/20 00:06 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 05/19/20 00:06 1,2-Dichlorobenzene ug/L ND 1.0 0.29 05/19/20 00:06 1,2-Dichloroethane ug/L ND 1.0 0.34 05/19/20 00:06 1,2-Dichloropropane ug/L ND 1.0 0.19 05/19/20 00:06 1,4-Dichlorobenzene ug/L ND 1.0 0.26 05/19/20 00:06 2-Butanone (MEK) ug/L ND 5.0 3.3 05/19/20 00:06 2-Hexanone ug/L ND 5.0 0.57 05/19/20 00:06 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 05/19/20 00:06 Acetone ug/L ND 25.0 6.2 05/19/20 00:06 Acrylonitrile ug/L ND 10.0 0.90 05/19/20 00:06 Benzene ug/L ND 1.0 0.15 05/19/20 00:06 Bromochloromethane ug/L ND 1.0 0.34 05/19/20 00:06 Bromodichloromethane ug/L ND 1.0 0.26 05/19/20 00:06 Bromoform ug/L ND 1.0 0.62 05/19/20 00:06 Bromomethane ug/L ND 2.0 0.62 05/19/20 00:06 Carbon disulfide ug/L ND 2.0 0.40 05/19/20 00:06 Carbon tetrachloride ug/L ND 1.0 0.22 05/19/20 00:06 Chlorobenzene ug/L ND 1.0 0.23 05/19/20 00:06 Chloroethane ug/L ND 1.0 0.49 05/19/20 00:06 Chloroform ug/L ND 5.0 2.3 05/19/20 00:06 Chloromethane ug/L ND 1.0 0.39 05/19/20 00:06 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 05/19/20 00:06 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 05/19/20 00:06 Dibromochloromethane ug/L ND 1.0 0.41 05/19/20 00:06 Dibromomethane ug/L ND 1.0 0.46 05/19/20 00:06 Ethylbenzene ug/L ND 1.0 0.26 05/19/20 00:06 lodomethane ug/L ND 20.0 12.5 05/19/20 00:06 Methylene Chloride ug/L ND 5.0 3.7 05/19/20 00:06 Styrene ug/L ND 1.0 0.27 05/19/20 00:06 Tetrachloroethene ug/L ND 1.0 0.16 05/19/20 00:06 Toluene ug/L ND 1.0 0.24 05/19/20 00:06 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 05/19/20 00:06 Qualifiers v1 I K,v2 IK IK v2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 47 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 METHOD BLANK: 2888719 Matrix: Associated Lab Samples: 92476718004, 92476718005, 92476718009 Blank Parameter Units Result Water Reporting Limit MDL Analyzed trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 05/19/20 00:06 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 05/19/20 00:06 Trichloroethene ug/L ND 1.0 0.22 05/19/20 00:06 Trichlorofluoromethane ug/L ND 1.0 0.31 05/19/20 00:06 Vinyl acetate ug/L ND 2.0 1.4 05/19/20 00:06 Vinyl chloride ug/L ND 1.0 0.24 05/19/20 00:06 Xylene (Total) ug/L ND 1.0 0.63 05/19/20 00:06 1,2-Dichloroethane-d4 (S) % 99 70-130 05/19/20 00:06 4-Bromofluorobenzene (S) % 98 70-130 05/19/20 00:06 Toluene-d8 (S) % 101 70-130 05/19/20 00:06 LABORATORY CONTROL SAMPLE: 2888720 Parameter Qualifiers IH IK v1 IK Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 55.6 111 70-130 1,1,1-Trichloroethane ug/L 50 53.1 106 70-130 1,1,2,2-Tetrachloroethane ug/L 50 53.0 106 70-130 1,1,2-Trichloroethane ug/L 50 53.6 107 70-130 1,1-Dichloroethane ug/L 50 51.4 103 70-130 1,1-Dichloroethene ug/L 50 53.5 107 70-130 1,2,3-Trichloropropane ug/L 50 55.8 112 70-130 1,2-Dibromo-3-chloropropane ug/L 50 59.6 119 70-130 1,2-Dibromoethane (EDB) ug/L 50 55.9 112 70-130 1,2-Dichlorobenzene ug/L 50 54.0 108 70-130 1,2-Dichloroethane ug/L 50 52.0 104 70-130 1,2-Dichloropropane ug/L 50 53.5 107 70-130 1,4-Dichlorobenzene ug/L 50 53.7 107 70-130 2-Butanone (MEK) ug/L 100 117 117 64-135 2-Hexanone ug/L 100 116 116 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 118 118 70-130 v1 Acetone ug/L 100 118 118 61-157 Acrylonitrile ug/L 250 259 104 61-143 Benzene ug/L 50 52.3 105 70-130 Bromochloromethane ug/L 50 51.0 102 70-130 Bromodichloromethane ug/L 50 55.7 111 70-130 Bromoform ug/L 50 56.4 113 70-130 Bromomethane ug/L 50 43.8 88 38-130lK,v3 Carbon disulfide ug/L 50 51.5 103 68-130 Carbon tetrachloride ug/L 50 55.3 111 70-130 Chlorobenzene ug/L 50 53.0 106 70-130 Chloroethane ug/L 50 38.9 78 37-142 IK Chloroform ug/L 50 51.5 103 70-130 Chloromethane ug/L 50 47.3 95 48-130lK cis-1,2-Dichloroethene ug/L 50 51.9 104 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 48 of 69 Pace Analytical Services, LLC lac, Analyilcal ® 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 LABORATORY CONTROL SAMPLE: Parameter 2888720 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 54.7 109 70-130 Dibromochloromethane ug/L 50 57.5 115 70-130 Dibromomethane ug/L 50 50.8 102 70-130 Ethylbenzene ug/L 50 51.2 102 70-130 lodomethane ug/L 100 81.6 82 40-130 v3 Methylene Chloride ug/L 50 48.9 98 67-132 Styrene ug/L 50 55.3 111 70-130 Tetrachloroethene ug/L 50 53.5 107 69-130 Toluene ug/L 50 50.0 100 70-130 trans-1,2-Dichloroethene ug/L 50 52.5 105 70-130 trans- 1,3-Dichloropropene ug/L 50 56.7 113 70-130 trans-1,4-Dichloro-2-butene ug/L 50 86.8 174 35-1891H Trichloroethene ug/L 50 51.0 102 70-130 Trichlorofluoromethane ug/L 50 52.1 104 63-1301K Vinyl acetate ug/L 100 120 120 55-143 v1 Vinyl chloride ug/L 50 56.1 112 70-131 IK Xylene (Total) ug/L 150 157 105 70-130 1,2-Dichloroethane-d4 (S) % 107 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 102 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2888721 MS 92476718004 Spike Parameter Units Result Conc. MSD Spike Conc. 2888722 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 22.1 20.3 110 102 73-134 8 30 1,1,1-Trichloroethane ug/L ND 20 20 20.6 20.4 103 102 82-143 1 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 21.4 21.3 107 107 70-136 0 30 1,1,2-Trichloroethane ug/L ND 20 20 19.1 19.9 96 99 70-135 4 30 1,1-Dichloroethane ug/L ND 20 20 21.2 21.6 106 108 70-139 2 30 1,1-Dichloroethene ug/L ND 20 20 23.4 23.6 117 118 70-154 1 30 1,2,3-Trichloropropane ug/L ND 20 20 22.1 21.3 110 107 71-137 4 30 1,2-Dibromo-3- ug/L ND 20 20 19.5 19.7 97 98 65-134 1 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 22.3 22.1 112 110 70-137 1 30 1,2-Dichlorobenzene ug/L ND 20 20 24.5 25.6 123 128 70-133 4 30 1,2-Dichloroethane ug/L ND 20 20 21.1 21.2 106 106 70-137 0 30 1,2-Dichloropropane ug/L ND 20 20 21.5 22.1 108 111 70-140 3 30 1,4-Dichlorobenzene ug/L ND 20 20 24.5 24.2 123 121 70-133 1 30 2-Butanone (MEK) ug/L ND 40 40 40.3 38.4 101 96 60-139 5 30 2-Hexanone ug/L ND 40 40 45.2 43.1 113 108 65-138 5 30 4-Methyl-2-pentanone ug/L ND 40 40 41.1 40.2 103 100 65-135 2 30 (MIBK) Acetone ug/L ND 40 40 40.7 41.0 102 103 60-148 1 30 Acrylonitrile ug/L ND 100 100 105 101 105 101 64-147 4 30 Benzene ug/L ND 20 20 22.0 22.2 110 111 70-151 1 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 49 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2888721 MS 92476718004 Spike Parameter Units Result Conc. MSD Spike Conc. 2888722 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Bromochloromethane ug/L ND 20 20 19.4 20.0 97 100 70-141 3 30 Bromodichloromethane ug/L ND 20 20 19.7 19.2 99 96 70-138 2 30 Bromoform ug/L ND 20 20 19.2 17.9 96 90 63-130 7 30 Bromomethane ug/L ND 20 20 22.7 24.6 114 123 15-152 8 30 IH,v3 Carbon disulfide ug/L ND 20 20 21.1 21.3 106 106 69-149 1 30 Carbon tetrachloride ug/L ND 20 20 21.2 21.5 106 108 70-143 2 30 Chlorobenzene ug/L ND 20 20 23.0 23.1 115 116 70-138 1 30 Chloroethane ug/L ND 20 20 22.9 21.3 114 106 52-163 7 30 Chloroform ug/L ND 20 20 21.3 21.0 106 105 70-139 1 30 Chloromethane ug/L ND 20 20 17.8 18.0 89 90 41-139 1 30 cis-1,2-Dichloroethene ug/L ND 20 20 21.6 21.4 108 107 70-141 1 30 cis-1,3-Dichloropropene ug/L ND 20 20 20.2 19.4 101 97 70-137 4 30 Dibromochloromethane ug/L ND 20 20 21.3 19.8 106 99 70-134 7 30 Dibromomethane ug/L ND 20 20 21.4 19.8 107 99 70-138 8 30 Ethylbenzene ug/L ND 20 20 23.6 22.7 118 114 66-153 4 30 lodomethane ug/L ND 40 40 23.2 22.3 58 56 20-138 4 30 v3 Methylene Chloride ug/L ND 20 20 23.3 23.4 117 117 42-159 0 30 Styrene ug/L ND 20 20 24.1 23.7 121 119 70-135 2 30 Tetrachloroethene ug/L ND 20 20 23.6 22.4 118 112 59-143 5 30 Toluene ug/L ND 20 20 20.5 20.2 102 101 59-148 1 30 trans-1,2-Dichloroethene ug/L ND 20 20 22.8 22.0 114 110 70-146 3 30 trans-1,3-Dichloropropene ug/L ND 20 20 19.2 19.7 96 99 70-135 2 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 21.5 21.3 108 107 47-135 1 30 IH Trichloroethene ug/L ND 20 20 21.9 21.7 109 108 70-147 1 30 Trichlorofluoromethane ug/L ND 20 20 18.4 18.7 92 94 70-148 2 30 Vinyl acetate ug/L ND 40 40 45.4 44.6 113 112 49-151 2 30 v1 Vinyl chloride ug/L ND 20 20 21.0 21.3 105 107 70-156 2 30 Xylene (Total) ug/L ND 60 60 72.5 68.1 121 114 63-158 6 30 1,2-Dichloroethane-d4 (S) % 101 103 70-130 4-Bromofluorobenzene (S) % 99 99 70-130 Toluene-d8 (S) % 97 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 50 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 QC Batch: 542350 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92476718011 METHOD BLANK: 2889712 Associated Lab Samples: 92476718011 Parameter Units 1,1,1,2-Tetrachloroethane ug/L 1,1,1-Trichloroethane ug/L 1,1,2,2-Tetrachloroethane ug/L 1,1,2-Trichloroethane ug/L 1,1-Dichloroethane ug/L 1,1-Dichloroethene ug/L 1,2,3-Trichloropropane ug/L 1,2-Dibromo-3-chloropropane ug/L 1,2-Dibromoethane (EDB) ug/L 1,2-Dichlorobenzene ug/L 1,2-Dichloroethane ug/L 1,2-Dichloropropane ug/L 1,4-Dichlorobenzene ug/L 2-Butanone (MEK) ug/L 2-Hexanone ug/L 4-Methyl-2-pentanone (MIBK) ug/L Acetone ug/L Acrylonitrile ug/L Benzene ug/L Bromochloromethane ug/L Bromodichloromethane ug/L Bromoform ug/L Bromomethane ug/L Carbon disulfide ug/L Carbon tetrachloride ug/L Chlorobenzene ug/L Chloroethane ug/L Chloroform ug/L Chloromethane ug/L cis-1,2-Dichloroethene ug/L cis-1,3-Dichloropropene ug/L Dibromochloromethane ug/L Dibromomethane ug/L Ethylbenzene ug/L lodomethane ug/L Methylene Chloride ug/L Styrene ug/L Tetrachloroethene ug/L Toluene ug/L trans-1,2-Dichloroethene ug/L Matrix: Water Blank Result Reporting Limit MDL Analyzed Qualifiers ND 1.0 0.34 05/19/2013:29 ND 1.0 0.18 05/19/2013:29 ND 1.0 0.22 05/19/2013:29 ND 1.0 0.24 05/19/2013:29 ND 1.0 0.27 05/19/2013:29 ND 1.0 0.24 05/19/2013:29 ND 1.0 0.35 05/19/2013:29 ND 5.0 0.26 05/19/2013:29 ND 1.0 0.26 05/19/2013:29 ND 1.0 0.29 05/19/2013:29 ND 1.0 0.34 05/19/2013:29 ND 1.0 0.19 05/19/2013:29 ND 1.0 0.26 05/19/2013:29 ND 5.0 3.3 05/19/2013:29 ND 5.0 0.57 05/19/2013:29 ND 5.0 4.5 05/19/2013:29 ND 25.0 6.2 05/19/2013:29 ND 10.0 0.90 05/19/2013:29 ND 1.0 0.15 05/19/2013:29 ND 1.0 0.34 05/19/2013:29 ND 1.0 0.26 05/19/2013:29 ND 1.0 0.62 05/19/2013:29 ND 2.0 0.62 05/19/2013:29 IH,v2 ND 2.0 0.40 05/19/2013:29 ND 1.0 0.22 05/19/2013:29 ND 1.0 0.23 05/19/2013:29 ND 1.0 0.49 05/19/2013:29 ND 5.0 2.3 05/19/2013:29 ND 1.0 0.39 05/19/2013:29 ND 1.0 0.29 05/19/2013:29 ND 1.0 0.30 05/19/2013:29 ND 1.0 0.41 05/19/2013:29 ND 1.0 0.46 05/19/2013:29 ND 1.0 0.26 05/19/2013:29 ND 20.0 12.5 05/19/2013:29 v2 ND 5.0 3.7 05/19/2013:29 ND 1.0 0.27 05/19/2013:29 ND 1.0 0.16 05/19/2013:29 ND 1.0 0.24 05/19/2013:29 ND 1.0 0.25 05/19/2013:29 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 51 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 METHOD BLANK: 2889712 Associated Lab Samples: 92476718011 Parameter Units trans- 1,3-Dichloropropene ug/L trans-1,4-Dichloro-2-butene ug/L Trichloroethene ug/L Trichlorofluoromethane ug/L Vinyl acetate ug/L Vinyl chloride ug/L Xylene (Total) ug/L 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % LABORATORY CONTROL SAMPLE: 2889713 Parameter QUALITY CONTROL DATA Matrix: Water Blank Result Reporting Limit ND 1.0 ND 1.0 ND 1.0 ND 1.0 ND 2.0 ND 1.0 ND 1.0 103 70-130 102 70-130 100 70-130 MDL Analyzed 0.31 05/19/20 13:29 0.54 05/19/20 13:29 0.22 05/19/20 13:29 0.31 05/19/20 13:29 1.4 05/19/20 13:29 0.24 05/19/20 13:29 0.63 05/19/20 13:29 05/19/20 13:29 05/19/20 13:29 05/19/20 13:29 IH v1 Qualifiers Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 54.2 108 70-130 1,1,1-Trichloroethane ug/L 50 48.0 96 70-130 1,1,2,2-Tetrachloroethane ug/L 50 55.0 110 70-130 1,1,2-Trichloroethane ug/L 50 49.9 100 70-130 1,1-Dichloroethane ug/L 50 51.6 103 70-130 1,1-Dichloroethene ug/L 50 53.9 108 70-130 1,2,3-Trichloropropane ug/L 50 53.9 108 70-130 1,2-Dibromo-3-chloropropane ug/L 50 49.4 99 70-130 1,2-Dibromoethane (EDB) ug/L 50 54.2 108 70-130 1,2-Dichlorobenzene ug/L 50 59.9 120 70-130 1,2-Dichloroethane ug/L 50 52.6 105 70-130 1,2-Dichloropropane ug/L 50 55.1 110 70-130 1,4-Dichlorobenzene ug/L 50 57.2 114 70-130 2-Butanone (MEK) ug/L 100 110 110 64-135 2-Hexanone ug/L 100 122 122 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 113 113 70-130 Acetone ug/L 100 128 128 61-157 Acrylonitrile ug/L 250 255 102 61-143 Benzene ug/L 50 52.8 106 70-130 Bromochloromethane ug/L 50 47.3 95 70-130 Bromodichloromethane ug/L 50 48.1 96 70-130 Bromoform ug/L 50 48.1 96 70-130 Bromomethane ug/L 50 59.4 119 38-130lH,v3 Carbon disulfide ug/L 50 50.6 101 68-130 Carbon tetrachloride ug/L 50 50.7 101 70-130 Chlorobenzene ug/L 50 56.2 112 70-130 Chloroethane ug/L 50 41.2 82 37-142 Chloroform ug/L 50 50.1 100 70-130 Chloromethane ug/L 50 45.8 92 48-130 cis-1,2-Dichloroethene ug/L 50 50.5 101 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 52 of 69 Pace Analytical Services, LLC lac, Analyilcal ® 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 LABORATORY CONTROL SAMPLE: Parameter 2889713 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 51.1 102 70-130 Dibromochloromethane ug/L 50 52.8 106 70-130 Dibromomethane ug/L 50 50.0 100 70-130 Ethylbenzene ug/L 50 55.4 111 70-130 lodomethane ug/L 100 61.3 61 40-130 v3 Methylene Chloride ug/L 50 55.3 111 67-132 Styrene ug/L 50 57.3 115 70-130 Tetrachloroethene ug/L 50 54.8 110 69-130 Toluene ug/L 50 50.2 100 70-130 trans-1,2-Dichloroethene ug/L 50 52.3 105 70-130 trans- 1,3-Dichloropropene ug/L 50 49.9 100 70-130 trans-1,4-Dichloro-2-butene ug/L 50 99.6 199 35-1891H,L1 Trichloroethene ug/L 50 49.7 99 70-130 Trichlorofluoromethane ug/L 50 42.1 84 63-130 Vinyl acetate ug/L 100 121 121 55-143 v1 Vinyl chloride ug/L 50 51.4 103 70-131 Xylene (Total) ug/L 150 167 111 70-130 1,2-Dichloroethane-d4 (S) % 98 70-130 4-Bromofluorobenzene (S) % 96 70-130 Toluene-d8 (S) % 100 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2889714 MS 92476426001 Spike Parameter Units Result Conc. MSD Spike Conc. 2889715 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 400 400 461 475 115 119 73-134 3 30 1,1,1-Trichloroethane ug/L ND 400 400 467 481 117 120 82-143 3 30 1,1,2,2-Tetrachloroethane ug/L ND 400 400 467 503 117 126 70-136 7 30 1,1,2-Trichloroethane ug/L ND 400 400 432 485 108 121 70-135 12 30 1,1-Dichloroethane ug/L ND 400 400 484 517 121 129 70-139 7 30 1,1-Dichloroethene ug/L ND 400 400 541 556 135 139 70-154 3 30 1,2,3-Trichloropropane ug/L ND 400 400 463 488 116 122 71-137 5 30 1,2-Dibromo-3- ug/L ND 400 400 381 465 95 116 65-134 20 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 400 400 502 517 125 129 70-137 3 30 1,2-Dichlorobenzene ug/L ND 400 400 533 577 133 144 70-133 8 30 M1 1,2-Dichloroethane ug/L ND 400 400 475 506 119 126 70-137 6 30 1,2-Dichloropropane ug/L ND 400 400 507 525 127 131 70-140 3 30 1,4-Dichlorobenzene ug/L 20.8 400 400 534 582 128 140 70-133 9 30 M1 2-Butanone (MEK) ug/L ND 800 800 909 963 114 120 60-139 6 30 2-Hexanone ug/L ND 800 800 967 1040 121 130 65-138 7 30 4-Methyl-2-pentanone ug/L ND 800 800 890 988 111 123 65-135 10 30 (MIBK) Acetone ug/L ND 800 800 967 1120 121 140 60-148 15 30 Acrylonitrile ug/L ND 2000 2000 2190 2370 109 118 64-147 8 30 Benzene ug/L 2640 400 400 2960 3000 78 89 70-151 1 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 53 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2889714 MS 92476426001 Spike Parameter Units Result Conc. MSD Spike Conc. 2889715 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Bromochloromethane ug/L ND 400 400 454 476 114 119 70-141 5 30 Bromodichloromethane ug/L ND 400 400 422 450 106 112 70-138 6 30 Bromoform ug/L ND 400 400 385 423 96 106 63-130 9 30 Bromomethane ug/L ND 400 400 409 518 102 129 15-152 23 30 IH,v3 Carbon disulfide ug/L ND 400 400 485 514 121 129 69-149 6 30 Carbon tetrachloride ug/L ND 400 400 468 499 117 125 70-143 6 30 Chlorobenzene ug/L ND 400 400 527 547 132 137 70-138 4 30 Chloroethane ug/L ND 400 400 502 488 125 122 52-163 3 30 Chloroform ug/L ND 400 400 465 498 116 124 70-139 7 30 Chloromethane ug/L ND 400 400 439 456 110 114 41-139 4 30 cis-1,2-Dichloroethene ug/L ND 400 400 488 516 122 129 70-141 5 30 cis-1,3-Dichloropropene ug/L ND 400 400 432 486 108 121 70-137 12 30 Dibromochloromethane ug/L ND 400 400 446 493 112 123 70-134 10 30 Dibromomethane ug/L ND 400 400 470 501 117 125 70-138 6 30 Ethylbenzene ug/L 143 400 400 636 673 123 132 66-153 6 30 lodomethane ug/L ND 800 800 438 564 55 70 20-138 25 30 v3 Methylene Chloride ug/L ND 400 400 514 559 128 140 42-159 8 30 Styrene ug/L ND 400 400 528 551 132 138 70-135 4 30 M1 Tetrachloroethene ug/L ND 400 400 478 515 120 129 59-143 7 30 Toluene ug/L 19.6J 400 400 472 521 113 125 59-148 10 30 trans-1,2-Dichloroethene ug/L ND 400 400 513 534 128 134 70-146 4 30 trans-1,3-Dichloropropene ug/L ND 400 400 420 464 105 116 70-135 10 30 trans-1,4-Dichloro-2-butene ug/L ND 400 400 435 450 109 112 47-135 3 30 IH Trichloroethene ug/L ND 400 400 483 516 121 129 70-147 7 30 Trichlorofluoromethane ug/L ND 400 400 423 434 106 108 70-148 3 30 Vinyl acetate ug/L ND 800 800 1080 1160 134 145 49-151 8 30 v1 Vinyl chloride ug/L ND 400 400 492 518 123 129 70-156 5 30 Xylene (Total) ug/L 109 1200 1200 1670 1730 130 135 63-158 4 30 1,2-Dichloroethane-d4 (S) % 105 103 70-130 4-Bromofluorobenzene (S) % 100 100 70-130 Toluene-d8 (S) % 96 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 54 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 QC Batch: 541431 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92476718001, 92476718002 METHOD BLANK: 2885371 Matrix: Water Associated Lab Samples: 92476718001, 92476718002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.2 05/13/20 22:16 1,2-Dichloroethane-d4 (S) % 93 50-150 05/13/20 22:16 Toluene-d8 (S) % 95 50-150 05/13/20 22:16 LABORATORY CONTROL SAMPLE: 2885372 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane(p-Dioxane) ug/L 20 18.5 92 70-130 1,2-Dichloroethane-d4 (S) % 97 50-150 Toluene-d8(S) % 84 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2885373 2885374 MS MSD 92476703006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane(p-Dioxane) ug/L 12.6 20 20 30.0 32.3 87 98 50-150 7 30 1,2-Dichloroethane-d4 (S) % 100 99 50-150 30 Toluene-d8 (S) % 86 113 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 55 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 QC Batch: 541676 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92476718003, 92476718004, 92476718005, 92476718006, 92476718008, 92476718011, 92476718012 METHOD BLANK: 2886576 Matrix: Water Associated Lab Samples: 92476718003, 92476718004, 92476718005, 92476718006, 92476718008, 92476718011, 92476718012 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.2 05/14/20 20:02 1,2-Dichloroethane-d4 (S) % 103 50-150 05/14/20 20:02 Toluene-d8 (S) % 100 50-150 05/14/20 20:02 LABORATORY CONTROL SAMPLE: 2886577 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 18.6 93 70-130 1,2-Dichloroethane-d4 (S) % 103 50-150 Toluene-d8 (S) % 102 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2886859 2886860 MS MSD 92477011005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 18.4 19.5 89 95 50-150 6 30 1,2-Dichloroethane-d4 (S) % 98 113 50-150 30 Toluene-d8 (S) % 95 106 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 56 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 QC Batch: 541677 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92476718009 METHOD BLANK: 2886578 Matrix: Water Associated Lab Samples: 92476718009 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.2 05/14/20 20:22 1,2-Dichloroethane-d4 (S) % 99 50-150 05/14/20 20:22 Toluene-d8 (S) % 89 50-150 05/14/20 20:22 LABORATORY CONTROL SAMPLE: 2886579 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 19.2 96 70-130 1,2-Dichloroethane-d4 (S) % 105 50-150 Toluene-d8 (S) % 100 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2886857 2886858 MS MSD 92477011007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 18.9 19.7 93 97 50-150 4 30 1,2-Dichloroethane-d4 (S) % 96 107 50-150 30 Toluene-d8 (S) % 96 83 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 57 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 QC Batch: 541824 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92476718010 METHOD BLANK: 2887087 Matrix: Water Associated Lab Samples: 92476718010 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.2 05/15/20 11:31 1,2-Dichloroethane-d4 (S) % 98 50-150 05/15/20 11:31 Toluene-d8 (S) % 111 50-150 05/15/20 11:31 LABORATORY CONTROL SAMPLE: 2887088 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 19.3 97 70-130 1,2-Dichloroethane-d4 (S) % 98 50-150 Toluene-d8 (S) % 96 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2887460 2887461 MS MSD 92476968001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 19.1 19.1 92 92 50-150 0 30 1,2-Dichloroethane-d4 (S) % 103 97 50-150 30 Toluene-d8 (S) % 91 104 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 58 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be considered an estimated value. IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2020 04:21 PM without the written consent of Pace Analytical Services, LLC. Page 59 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Burke Co (Kirksey Drive) 92476718 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92476718001 MW-3 EPA 3010A 541200 EPA 6010D 541215 92476718002 MW-4 EPA 3010A 541200 EPA 6010D 541215 92476718003 MW-5 EPA 3010A 541201 EPA 6010D 541216 92476718004 MW-61) EPA 3010A 541201 EPA 6010D 541216 92476718005 SW-1 EPA 3010A 541201 EPA 6010D 541216 92476718006 SW-2 EPA 3010A 542769 EPA 6010D 542777 92476718009 MW-2 EPA 3010A 542769 EPA 6010D 542777 92476718010 MW-31) EPA 3010A 542769 EPA 6010D 542777 92476718011 MW-6S EPA 3010A 542769 EPA 6010D 542777 92476718012 SW-3 EPA 3010A 542769 EPA 6010D 542777 92476718001 MW-3 EPA 3010A 540953 EPA 6020B 540959 92476718002 MW-4 EPA 3010A 540953 EPA 6020B 540959 92476718003 MW-5 EPA 3010A 540953 EPA 6020B 540959 92476718004 MW-61) EPA 3010A 540953 EPA 6020B 540959 92476718005 SW-1 EPA 3010A 540953 EPA 6020B 540959 92476718006 SW-2 EPA 3010A 541202 EPA 6020B 541210 92476718009 MW-2 EPA 3010A 541202 EPA 6020B 541210 92476718010 MW-31) EPA 3010A 541202 EPA 6020B 541210 92476718011 MW-6S EPA 3010A 541202 EPA 6020B 541210 92476718012 SW-3 EPA 3010A 541202 EPA 6020B 541210 92476718001 MW-3 EPA 8260D 542112 92476718002 MW-4 EPA 8260D 542117 92476718003 MW-5 EPA 8260D 542117 92476718004 MW-6D EPA 8260D 542119 92476718005 SW-1 EPA 8260D 542119 92476718006 SW-2 EPA 8260D 542112 92476718007 TB (NC App I VOCs) EPA 8260D 542112 92476718009 MW-2 EPA 8260D 542119 92476718010 MW-3D EPA 8260D 542112 92476718011 MW-6S EPA 8260D 542350 92476718012 SW-3 EPA 8260D 542112 92476718001 MW-3 EPA 8260D Mod. 541431 92476718002 MW-4 EPA 8260D Mod. 541431 92476718003 MW-5 EPA 8260D Mod. 541676 92476718004 MW-61) EPA 8260D Mod. 541676 92476718005 SW-1 EPA 8260D Mod. 541676 92476718006 SW-2 EPA 8260D Mod. 541676 92476718008 TB (8260SIM 1,4-D) EPA 8260D Mod. 541676 92476718009 MW-2 EPA 8260D Mod. 541677 92476718010 MW-31) EPA 8260D Mod. 541824 Date: 05/26/2020 04:21 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 60 of 69 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Burke Co (Kirksey Drive) Pace Project No.: 92476718 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92476718011 MW-6S EPA 8260D Mod. 541676 92476718012 SW-3 EPA 8260D Mod. 541676 Date: 05/26/2020 04:21 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Batch Page 61 of 69 Document Name: Document Revised: February 7, 2018 Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: 1'weAnalytical F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville 0 Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑ Sample Condition Client Name: WO# : 92476718 Upon Receipt Project #: �•_��'��''�, Courier: [ ed Ex �<�.S�i•�y_?�}.�\. IlIIIIIIIIIIIIIIIIIIII ❑UPS ❑USPS ❑Client ❑ Commercial ❑Pace ❑Other: 92476718 Custody Seal Present? ❑Yes -nNo Seals Intact? [-]Yes ❑No r' Date/Initials Person Examining Contents: /'!/ Packing Material: ❑Bubble Wrap ❑Bubble Bags ❑None ❑ Other Thermometerj, J Type of Ice: . ❑Wet ❑Blue DIR Gun ID: Cooler Temp ('C : Correction Factor: Add/subtract (°C) I Cooler Temp Corrected (°c): i i USDA Regulated Soil (❑ N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? nv— nhi Biological Tissue Er6en? ❑Yes ❑No []N/A ❑None Temp should be above freezing to 6°C ❑Samples out of temp criteria. Samples on ice, cooling process hasbegun Did samples originate from a foreign source (internationally, including Hatvali and Puerto Rico)? ❑Yes ❑No Comments/Discrepancy: Chain of Custody Present? {JYes ❑No ❑N/A 1. Samples Arrived within Hold Time? ❑Yes [-)No ❑N/A 2. Short Hold Time Analysis (<72 hr.)? ❑Yes ❑P o ❑N/A 3. Rush Turn Around Time Requested? [-]Yes --❑No ❑N/A 4. Sufficient Volume? i Des []No ❑N/A 5. Correct Containers Used? -Pace Containers Used? E]Yes ❑Yes ❑No [-]No ❑N/A ❑N/A 6. Containers Intact? ['7Yes ❑No ❑N/A _. 7. Dissolved analysis: Samples Field Filtered? [-]Yes ❑No ❑k/A S. Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix: j ❑Yes / � � .ZfNo ❑N/A 9. /r�} q ; rr / l /yl `, r �� J�J1�1 �CJ Llti��� � ���T'le Headspace in VOA Vials (>5-6mm)? ❑Yes In`Na ❑N/A 10, Trip Blank Present? Trip Blank Custody Seals Present? -' Yes Yes ❑No ❑No ❑N/A ❑N/A 11. COMMENTS/SAMPLE DISCREPANCY Field Data Required? Des Q<o Lot ID of split containers: CLIENT NOTIFICATJON/RESOLUTION Person contacted: Date/Time: Project Manager SCURF Review: Date: v Project Manager SRF Review: Date: lz"() Page 62 of 69 _-'`.2 1 ,PkeAnall ical Document Name: sample Condition Upon Receipt(SCUR) Document Revised: February 7, 2018 Page 1 of 2 Document No.: F-CAR-CS-033-Rev.06 Issuing Authority: Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is Project # verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottle WO#:92476718 PM: NMG Due Dale: 05/21/20 CLIENT: 92-Joyce Eng d Z v J E N 7 a m Z v m Q J E a 7 a m Z i m a J E o0 n. m ¢ v = M 0.. j a. m = U a J E N LA a m v rn z ;= a J E o Z a m Z v C V m a J E ^ N a m ^' U N `. O U a J E H u a m ° iu ax+ o E u�. 3 � \ d N a G n E E r ; t7 a = U N E Q m = 2 14 l7 a ¢ \ L c Ol E ¢ J E o 7 m C7 a a O N v E Q v r, u� l7 a 2 ` ,.vs E ¢ J E of m C7 a ¢ E Q E o N m a Q m l7 a Z U 2 Q O 7 E a 2 m l7 o ? fJ C O J a r cs l7 > Z 7 C E ° 7 m u > c fY1 2 Q J E °a a M t7 o O .1L y n 0 n Y a 0 n ro 17 a � a+ Y m ec x C4 7 \ z y E N n a v, Z c ro Cl - v n E a Ln ry a Ln n O ry x Z u tj a a E n M a m ? ai v c � y .� E a E CD o l7 a 4> io c O c u cn > z o. c E E a Q o 1 2 3 I Cj 4 5 ; f, 6 ' 7 8 X s i I 1] 12 \\NN c pH Adjustment tog for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot # Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 63 of 69 11)!aceAnalyficaf WWW.PICLLABS.C6N 0 CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. IL Section C Invoice Information: f a e' 1 Of 1 Attention Company Name' Address: R ul A eme Pace Quote: ) Pace Project Manager: niCole.gasiofewski pacelabs.Com, State 7 Location Pace Profile #: 2327-5 NC Seaton A Section B Required Client Information: Required Project Information: Company: LaBeila Associates, D.P.C. - NC Report To, Van Swbach Address. 2211 West Meadowview Rd Copy To Greensboro, NC 27407 Email vburbach labellapc. com Purchase Order #: Phone'. (336)707-3B74 Fax Project Name: Burke Co (Kirksey Drive Requested Due Date' Project#: MATRIX _ CODE _ a COLLE( D--7 w—� ow d wmh wr 3 SAMPLE ID PLOducl 5e,u,o„d p � 5m � pr START One Character per box. w,p., wp (A-Z, 0-81 . -1 Au AR o a Sample Ids must be unique OlhW OT O x F W F n F a N DATE TIME 1 VVI 2 MW-2 WT t 3 MW-3 WT 4 MW-3D WT 5 MW-4 VJT 6 MW-5 W r " 7 Mw-SS WT 8 Mw-GD y� 9 sw-1 wT 0 10 SW-2 Uvr l 11 SW-3 y„R 12 TB NC A I VOCs WT AODmONAL COMMENTS RELINQUISHED BY IAFFILIATION l UVM G k-Mu L4�ak o_ vauvca m z END U a a o m -` a to v 0 d u F > se o w n ii m O 2 w C a in m v o TIME = z Z z m O¢ z z N t- w Sy } ( K x x 11!"� k k x x OWN3 x DATE TIME ACCEPTED BY/ oS G iv $c DATE TIME '71�a V Z ov SAMPLECONDITIONS SAMPLER NAME AND SIGNATURE 0 P T Na c of SAMPL �u t•s u 6 Nai%ti'a. m SIG TUR E PLE m 2 °—' -az E DATE u z Si e �,o EY 0v M . "Awlyrrvar' CHAIN -OF -CUSTODY 1 Analytical Request Documentto www rrctuns COM The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. of Section A Section B � Required Client Information: Required Projoel Section C Information: Invoice Information: 0rm an :Page P Y LaBella Associates, D.P.C.❑- NC Report To: Van Burbach Attention ' 2 Of 2 Address. 2211 West Meadowview Rd Copy To. Company Name Greensboro, NC 27407 Email: vburbach labellnpccom Purchase Order#: Address: Aace Ruo[e: R utato Agency Phone'. (336)707-3874 Fax Requested Due Date, Project Name Burke Co (Kirkse Drive) Pace Project Manager: nicole,gasieraski pacelahs.com, StateILocation _ Project t#: Pace Profile #: 2327-5 NC Requested Amtywls Filtered Y/N z MATRIX CODE — m o COLLECTED Preservatives Zm DnnMmgwm wae�r nW 4r17 $ IJ O t- SAMPLE ID Pl.d,.d P soo-s.ed sL m One Character per box. a„ w." oc wa .. START END i F (� v ¢ N 'a m (A-Z, 0-9 f. -) Sample Ids must 6e unique A., Otha, Arc o of a z v m � Z i, E z 4 O p L C Q Q O m a o c-L z d= Q U m a DATE TIME DATE TIME �+ x z x z z O z z r 13 TB (ffi5651M 1,4-D( WT 14 i5 is 17 18 19 20 21 22 23 24 ADDITIONAL COMMENTS RELINQUISHED BY I,.AFFILIArTION DATE TIME - ACCEPTED BY l AFFLIATION RATE TIME SAMPLE CONDITIONS diftip ikjEy �(? SAMPLER NAME AND SIGNATURE P iNT ame of SAMPLER- ! C, II.f &- 0CEM1:A - .tP ""J ' artA4- U Cm O S NATUR MPL Q DATE Signed: m z} m a? E _ 26*alytltat' Document Name: Sample Condition Upon Recelpt(SCUR) Document Revised: February 7, 2018 Page 1 of 2 Document NO.: F•CAR-CS•033-Rev.05 issuing Authority: Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑ Client Name: r Project k: WO# : 92476718 L, Q 'I) C ( ) PM: NMG Due Date: 05/21/20 Courier: ❑Fed Ex ❑UPS ❑LISPS ❑Client CLIENT: 92—Joyce Eng ❑ Commercial Pace ❑Other: Custody Seal present? Elves ZNo Seals Intact? []Yes ❑No Date/initials Person Examining Contents: ' l 5' - Packing Material: ❑Bubble Wrap ❑ u8' bole Bogs ❑None ❑ Other BlologlcalTissue F Zen? Thermometery Type of Ice: ❑Wet ❑Blue ❑None ❑Yes [-]No ❑N/A ❑IR Gun 10: 92TO61 Cooler Temp (°C): ' Correction Factor: Add/Subtract (°C) *0 ,� •- Temp should be above freezing to 6°C Cooler Temp Corrected (°C): ❑Samples out of temp criteria. Samples on Ice, cooling process / has begun USDA Regulated Sail (❑ N/A, water samplel Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Old samples originate from a foreign source (internationally, Dyes ❑No rnctuoing Hawaii ano vuerio nico+r rJrus LuyU Comments/Dlscre ancy: i Chain of Custody Present? ❑v s .❑No ❑NIA 1. Samples Arrived within Hold Time? 'Yes D�NNo.� ❑N/A 2, Short Hold Time Analysis (<72 hr.)? ❑Yes [:rNa..- ❑NIA 3. Rush Turn Around Time Requested? ❑Yes 0r4o ❑NIA 4. Sufficient Volume? [?Yes ❑No ❑N/A 5- Correct Containers Used? I]res= + ❑No []N/A 5. -Pace Containers Used? ❑Yes _ [:]No ❑NIA Containers Intact? Yes []No ❑N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yet;-' ❑No ❑NIA 8. Yes FINo N A 9. f -Includes Date/Time/ID/Analysis Matrix: Heads ace in VOA Vials (?S-5mm)? ❑Yes QNo - ❑N/A 10. Trip Blank Present? ❑Yes ❑i o ❑N�/AA 1E. Trip Blank Custody Seals Present? El Yes ❑No ❑ /N A COMMENTS/SAMPLE DISCREPANCY � f,C, � � � 1-14) CLIENT NOTIFICATIONIRESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SFtF Review: Date/Time: Field Data Required? []Yes ❑ Lot ID of split contalners: Date: Date: r !1(J r Page 66 of 69 Document Name: Document Revised: February 7, 2018 IAnale�rticalb y' Sa^tPle Candltlon Upon Recel t(SCUR) Page 1 of 2 Document No.: Issuing Authority: lF-CAR-CS-033-Rev.06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptlorl VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg "*Bottom half of box is to list number of bottle Project ii ` io# ' Q247� �� PM: NMG ,+ Due Date: 05/21/20 CLIENT: 92—JovCe Ens 2 a2i 7 U M E N i 0o 2 a�i C U a E N 7 d 0 Z d aai 0. V a J E Q 6 CD Z y L 'v^ v G - p- a rl 7 d go u N V n a O N V a E 0. m rry V M ..d.- ^M O z V c J E N Z a cc z ab 2 N 4 Q Z U R E eq N a m N .-e n c v 2 O Z V a E N U a m d n e � m W o' E �yy ' 1 4 3 2 v e E a rl 7 t7 a ry V y S E a .M 2 G a Z U aJ m a G n E 4 N ID a N M V vbV�� n E Q r.� to l7 a r:� V a O S w E Q J E N %0 a V V Z a Q J E ry Z m Gi a m L9 a 2 _ O > E S 01 tD a ? ^' r.0N1 N tl 7 E I l7 7 Z O a E �r 7 MOe U' � \ Z T O % E 1 M i7 a Q Z Y O a '0 .fir Y a a 7 2 `' a a N To Y C7 3 A ? y J YE1I '�„� f- Ln 0. � m i a h E 0 f• M a. � 1 T IA 2 Z a E a rn a m 3 Ca G D ¢ E 5 O U cc Q u V7 E N 7 �i > a T i C C E Q E K C1 0 a i V V G 3 V 5 6 8 9 10 \NN N 11 \\\N N\\� I I 12 `q Ls NN\ pH Adjustment Lag for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot N Note: Whenever there Is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incarrect preservative, out of temp, incorrect containers. Page 67 of 69 eSo.F A Section B quind Client Information: Requimd Project Information: mpany. LaBelra Associates, D.P.C. - NC Repod To,. Van Burbach iresa: 2211 West RArap kwview Rd Copy To: tmuboa, NC 274W tail: yp h labella com one: r%� ,7m_aw-ri Purchase uIer#, Q R a MATRM CODE V t DFFn.ug vr.ttr ow v ww, wr 3 W..% WM.r VM Pmdu P SAMPLE ID am S.w s& ou Cr. START One Character per boor_ wip. wP w w (Az- a.9l , _) Air AR rL SamrAa lox moat be unkquo �. O x ti a DATE TI ,Tfir. WT s.l MW3 ,SIT 4 MW3D wr 8�o n MWA '�'r MW-5 y� WT MWfis Wf Wr Wf 1yocsL W r CHAIN -OF -CUSTODY / Analytical Request. Document The Chain -of --Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. section C lmalce Information: Pa e : 1 Of 1 tilntion: Company Name: Pace Quote: W) Pace Praierl Manager R1COIe, OwSI{F 1811S.00m, .'vJ�'�i.•:>w _ _ Fare Pile #.' 2327-5 NC = vwuvw 4 0 END d � 4 � � m s — w n m O M y m TIME r*d Z� z s= x Z,:9 VE if►sy -%Jto Ifs.-iYlal3 riLi'1 ff&f-pl i€�c on DATE Si w Z_ ? o z m m Z co wytw r"f'.,n gyp` ction A quired Clierrt trdomtation: mpany. LaBella Associales, D.P.C. - NC dress: 2211 tnrast Meador !v Rd �n*boro. NC 274C7 MaiL vtutrboch IabM.�tlapc. Ccm OM: I paz: SAMPLE ID dne Cha ackcr per f,mX. Sample ld-- must be unique: w H 5�� £WN' TB (82WSIIM 1.4.Dl Section B Required Project information_ Report To: Van Burbech Copy To: Purchase Order #. P-jr t Namc. 13 .ke Co {Kirks project#o 2 � MATRIX CODE C Ori.w.9W>t.. ew'r U WM1ter wT we:m w cer ww v m P=Uv A S.Af-1 E SL ai OL m +? START wiP WIR O[M1M Q'i V � Tiswa Ts yi vu a x IT DATE T ,(A SO CHAIN -OF -CUSTODY f Analytical Request Document The Chain-of-Gustady is a LEGAL DOCUMEt3T. All relevant fields must be completed accurately. Section C Invoice Information- Pa C • 2 Of ,2 Attention' _ Company Name' i Pace Quote'. = o w Preservatives. o !o: END Ws ci o 4 a V m N m S: a h O S x z= TIME x 2 z s O z z L a C LATE Sigrrccj; WO n } 'Gyc ? a we 0) T 0 rn rD CO ar 1O a I LaBeRa 2211W. Meadowview Rd Suite 101 Greensboro, NC 27407 Telephone: (336) 323-0092 Facsimile: (336) 323-0093 WELL I.D.: WELL SAMPLING INFORMATION Well Diameter: .' yl Depth of Well: qj.go Measuring Point: Pump Type: FIELD PARAMETER MEASUREMENT Project Name: Location: Project No.: Sampled By: Date: Weather: u C.) C) alpz i. oolo& Static Water Level: Length of Well Screen: Depth to Top of Pump: Tubing Type: 3S- S l '9'Toc' • !Cit �� • r . �� iZ - • GallonsPurge,® ._ . MN&jk=rFXri ! wx'i Wrl ----------- ----------- ----------- t otal , �� Gallons Purged Purge Time Purge Time End: Final Static Water Level: SS .SS Start: I OBSERVATIONS Notes: 0 P QC, : vv'tt -ff2_0120 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 July 29, 2020 Mr. Van Burbach Joyce Engineering -Greensboro 2211 West Meadowview Rd Boone Bldg, Suite 101 Greensboro, NC 27407 RE: Project: Burke County Kirksey Drive Pace Project No.: 92486784 Dear Mr. Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on July 17, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville If you have any questions concerning this report, please feel free to contact me. Sincerely, /'i"A"" Nicole Gasiorowski nicole.gasiorowski@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Van Burbach, Joyce Engineering -NC Gretta Eller, LaBella Associates, D.P.C. Rochelle Mesubed, Joyce Engineering Miguel Vazquez, Joyce Engineering REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 12 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Burke County Kirksey Drive Pace Project No.: 92486784 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 12 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Burke County Kirksey Drive Pace Project No.: 92486784 Lab ID Sample ID Matrix Date Collected Date Received 92486784001 MW-5 Water 07/16/2011:20 07/17/2010:11 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 12 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Burke County Kirksey Drive Pace Project No.: 92486784 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92486784001 MW-5 EPA 601 OD RDT 1 PASI-A EPA 6020E JOR 1 PASI-A PASI-A = Pace Analytical Services - Asheville REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 12 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke County Kirksey Drive Pace Project No.: 92486784 Sample: MW-5 Parameters Lab ID: 92486784001 Collected: 07/16/20 11:20 Received: 07/17/20 10:11 Matrix: Water Report Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 23:26 7440-62-2 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 07/25/20 01:24 07/29/20 00:28 7440-28-0 Date: 07/29/2020 01:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 12 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke County Kirksey Drive Pace Project No.: 92486784 QC Batch: 555777 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92486784001 METHOD BLANK: 2951816 Matrix: Water Associated Lab Samples: 92486784001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Vanadium ug/L ND 5.0 3.9 07/26/20 21:52 LABORATORY CONTROL SAMPLE: 2951817 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Vanadium ug/L 500 490 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2951818 2951819 MS MSD 92486765014 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Vanadium ug/L ND 500 500 503 506 100 101 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/29/2020 01:11 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 12 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke County Kirksey Drive Pace Project No.: 92486784 QC Batch: 555780 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92486784001 METHOD BLANK: 2951828 Matrix: Water Associated Lab Samples: 92486784001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.050 07/28/20 07:55 LABORATORY CONTROL SAMPLE: 2951829 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10.1 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2951830 2951831 MS MSD 92486765012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L 0.051J 10 10 10.3 10.6 103 106 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/29/2020 01:11 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 12 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Burke County Kirksey Drive Pace Project No.: 92486784 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/29/2020 01:11 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 12 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Burke County Kirksey Drive Pace Project No.: 92486784 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92486784001 MW-5 EPA 3010A 555777 EPA 6010D 555792 92486784001 MW-5 EPA 3010A 555780 EPA 6020B 555790 Date: 07/29/2020 01:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 12 Document Name: Document Revised: February 7, 2018 Sample Condition Upon Receipt(SCUR) Page I of 2 11�?CeAnalytical Document No.: Issuing Authority: / F-CAR-CS-033-Rev.D6 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville ' Raleigh[] Mechanicsville❑ ConditionSample Client Name: WO# : 92486784 Upon Receipt bi J I a1 Project L#: 1III II I 1` aic ilc�. SSGCi L<��� IIII�I IIII IIIIIIII � III Courier: ❑F d Ex [:]UPS❑UsPS ❑Client ❑ Commercial ✓ Race ❑Other: 92486784 Packing Material: Bubble Wrap Rfubble Hags ❑None ❑ Other ete . Thermom92TO61 Type of ice: wet []Blue. IR Gun ID: Cooler Temp (•C): (s ,�i ))Correction Factor: Add/Subtract (°C) 0.0 Cooler Temp Corrected (°C): USDA Regulated Soil (Er"NIA, water sample) Did samnips originate in a nuarantine zone within the United States: CA, NY, or SC (check maps)7 Date/InItialsPers on Exam in[ngCcntents: ✓�7/,20 Biological Tissue Frozen? ❑Yes ❑No ❑N/A ❑None Temp should be above freezing to VC (—]samples out or temp criteria. Samples an ice, cooling process has begun Did samples originate from a foreign source (Internationa Ily, ❑Yes ❑No Includingrlawan and Nuerto KICal' [JTes Ljmo Comments/Discrepancy: Chain of Custody Present? LY. ❑No ❑NIA 1. samples Arrived within Hold lime? Yes ❑No [:]N/A 2. Short Hold Time Analysis (02 hr.l? ❑Yes 2No ❑N/A 1 3. Rush Turn Around Time Requested? ❑Yes [. No ❑N/A 4• Sufficient Volume? Yes ❑No ❑N/A 5. Correct Containers Used? Y [:]NO [-]N/A 6. Pace Containers Used? Yes []No ❑NIA Containers Intact? [�es❑,,NNa ❑N/A 1 7. Dissolved analysis: Samples Field Filtered? e [?No ❑N/A ❑Y 8. Sample Labels Match COC? es ❑No ❑NIA 9. -Includes Date/Time/ID/Analysis Matrix: T Headspace in VOA Vials (>5-6mm)? ❑yes ❑No NAIA 10. Trip Blank Present? ❑Yes ❑No / 11• Trip Blank Custody Seals Present? ❑Yes []NoN/A COMMENTS/SAMPLE DISCREPANCY Lot ID of spilt containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Date/Time7 Date: Date: field Data Required? ❑Yes []No Page 10 of 12 aceAnalytical. Document Name: Sample Condition Upon Recelpt(SCUR) Document Revised: February 7, 2018 page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office *Check mark top half of box If pH and/or dechiorination Is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg "Bottom half of box is to list number of bottle Project # WO# : 92486784 PM: NMG Due Date: 07/31/20 CLIENT: 92-Joyce Eng 2 v a e J E n ,ry-I a m 1S 2 d n c J E a N 7 a Q1 a Z v n c b � E o li l M a ra Z N m a j : a _ aa.. m u, ry 2 v D N ; 1 a E + 1 L% Rr a. m N a m O u a E o 0. m _ N Z N °• E n N a m = '• a r M j a E v, �j a a m H v a N _v W o E ro 7i a ? '0 Z v c � a Q v 7 d _ n u = n d ° = T t7 Q < 2 y a D m E ¢ E w M 0 4 .. xa v Q x p E !ff = in ri l7 Q _ N vA a v O z E q E o ,n M Z d a Z V a z v ¢ a N & Q M W d Q ? v d 0 E o = 01 U O Z m N ro Q O E O C1 0 7 4 z a. c d O> E o} C1 0 S = Z p °n cc O E o a 0� 0 O z of m y = Q O � Y m = n M Y � 7 i Z u ro y vi E u, �j a h ¢ Z a m v yr E o N N a v1 ro m O ry y A a E Ln N r�'1 a m a v w n j v E ¢ E i?i S7 Q : •� o C E o � > z . 'o CU y a E ap i 1 N\N I I I 3 -N NNN\ J\N N\N 5 N\ I N\ N I N\� 7 8 9 10 It 12 1 N pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot p adjusted added Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR CertificaVon Office (l.e Out of hold, Incorrect preservative, out of temp, incorrect containers. Page 11 of 12 CHAIN -OF -CUSTODY / Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. m o_ Section A Section B Section C Required Client Information: Required Project Information- Invoice Information: Page • 1 Of 1 Company: Labella Associates Report To: Van Burbach Atternion: Lecia Jones Address: 2211 West Meadowview Rd, Suite 101 Copy 1o: Molly Peterson Company Name: Labella Assoc. Greensboro, NC 27407 Address: 1604 Ownby Lane, Richmond, VA 23220 Regulatory Agency Email To: VBurbach@LaRellaPC.com Purchase Order No. Ouote Reference, Phone 336 323-0092 Fax: (336) 323-0093 client Project ID: Burke County re ample "e Project Manager: e Nicole Gasiorowski State Location Requested Due DatefrAT: 10 Da Default container Order Number: Profile n: NC Request&d Analysis Filtered YIN m � ' MATRIX COME E O COLLECTED Preservatives r 1,k-ng Water Dw U O womr WT Waste Water WW P. ..t P m b Q rr i? SAMPLE ID SOIA90jid sL a 0 START END '— Oil oL " c7 ti m One Character per box. AI°" AR c- i orhsr or w o w >- w z `° }• u Sample Ids must 6e unique Masao Ts w o O m ~ x J D v M = Z Z m 2 Q DATE TIME DATE TIME M 1 W T G 7j tjI Ix 2 WT 3 3 WT G 4 5 6 7 8 9 10 11 12 ADDITIONAL COMMENTS RELINQUISHED BY J AFFILIATION DATE TIM1w ACCEPTED BY / AFFILIATION DATE TIME SAMPLE CONDITIONS 7 (7(k I� �a ►v SAMPLER NAME AND SIGNATURE PRINT Name of SAMPLER: oL,Ly E SIGNATURE of SAMPLER: DATE Signed: G L0 ¢} ci0 n> 4I r APPENDIX 2 Historical Data Table A2-1 Historical Groundwater Elevations Table A2-2 Historical Groundwater Constituents Table A2-3 Historical Groundwater Field Parameters Table A2-4 Historical Surface Water Constituents Table A2-5 Historical Surface Water Field Parameters TABLE A2-1: Historical Groundwater Elevations Location Background Downgradient MW-1 MW-2 MW-3S MW-31D MW-4 MW-5 MW-6S MW-61D TOC Elevation: 1119.82 1077.23 1021.90 1022.76 1054.99 1137.43 1065.00 1065.00 Well Depth: 35.65 45.70 26.69 78.40 29.50 49.80 25.00 60.00 31-Oct-06 1086.68 1049.61 1014.16 1022.76 1030.93 1096.03 1054.60 1053.22 29-May-07 1087.59 1050.65 1015.08 1022.76 1032.01 1096.91 1054.24 1053.12 27-Nov-07 1085.59 1049.67 1014.06 1022.76 1029.75 1095.15 1054.31 1053.15 27-May-08 1085.56 1049.57 1014.24 1022.76 1030.43 1093.61 1054.21 1053.05 05-Nov-08 1085.12 1049.59 1013.66 1022.46 1029.28 1092.43 1054.23 1053.00 01-Jun-09 1085.94 1050.03 1014.99 1022.76 1032.62 1092.41 1054.85 1053.55 19-Nov-09 1086.91 1050.06 1015.18 1022.76 1032.27 1094.75 1054.84 1053.44 14-Jun-10 1089.98 1050.93 1015.53 1022.76 1033.36 1100.14 1054.33 1053.09 29-Nov-10 1087.62 1050.02 1014.63 1022.76 1030.43 1098.45 1054.53 1053.02 31-May-11 1087.43 1050.02 1014.86 1022.76 1031.78 1096.47 1054.31 1053.06 19-Dec-11 1085.70 1049.85 1014.33 1022.76 1030.57 1094.41 1053.78 1053.00 30-May-12 1086.81 1050.13 1014.99 1022.76 1032.28 1094.12 1054.44 1053.05 03-Dec-12 1085.72 1052.89 1014.46 1022.76 1030.11 1092.06 1054.29 1052.88 11-Jun-13 1088.62 1050.98 1016.30 1022.76 1035.70 1096.08 1058.81 1054.43 29-Oct-13 1090.35 1050.82 1015.75 1022.76 1033.21 1100.48 1054.50 1053.10 05-May-14 1090.34 1031.53 1015.96 1022.76 1034.94 1101.05 1054.76 1053.36 20-Oct-14 1089.05 1050.36 1015.37 1022.76 1032.09 1100.06 1054.57 1044.10 19-May-15 1088.08 1050.25 1015.64 1022.76 1032.77 1097.66 1054.30 1053.05 7-Dec-15 1088.07 1050.26 1014.93 1022.76 1033.54 1096.38 1055.20 1053.55 2-May-16 1090.09 1050.09 1015.40 1022.76 1031.24 1100.12 1054.00 1052.75 12-Dec-16 1087.07 1050.26 1014.80 1022.76 1029.99 1097.68 1054.15 1052.83 26-Jun-17 1086.82 1050.03 1015.10 1022.76 1031.89 1095.63 1053.84 1052.30 14-Dec-17 - 1050.18 1015.15 1022.76 1030.75 1094.65 1054.55 1053.07 16-May-18 - 1050.98 1015.88 1022.76 1033.79 1095.32 1055.10 1053.60 3-Dec-18 1098.92 1050.53 1016.07 1022.76 1034.70 1098.14 1055.09 1053.34 6-May-19 1095.28 1051.26 1016.20 1022.76 1037.20 1104.22 1055.05 1053.44 4-Nov-19 1089.96 1051.23 1016.22 1022.76 1036.09 1101.77 1054.90 1053.09 6-May-20 - 1051.23 1017.08 1022.76 1036.09 1101.77 1055.25 1053.38 Notes: TOC = Top of Casing. All elevations are referenced as feet above mean sea level. All depths measured in feet below TOC. Burke County, Kirksey Drive Landfill MW-6S and MW-6D TOC Elevations are estimated. MW-3D exhibits artesian conditions. MW-1 damaged approx. June 2017 Permit No. 12-01 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks INORGANICS Antimony 28-Apr-94 NR 1 1.0 ND 4.0 NI NI NI NI NI NA 3-May-00 NR 30 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 30 NA ND ND ND ND ND ND ND NA 29-May-01 NR 30 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 30 NA ND ND ND ND ND ND ND ND 21-May-02 NR 30 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 30 NA ND ND ND ND ND ND ND ND 14-May-03 NR 30 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 30 ND ND ND ND ND ND ND ND ND 5-May-04 NR 30 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 30 ND ND ND ND ND ND ND ND ND 25-May-05 NR 30 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 30 ND ND ND ND ND ND ND ND ND 24-May-06 NR 30 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 30 ND ND ND ND ND ND ND ND ND 29-May-07 NR 6 ND ND ND ND ND ND ND ND ND GWPS = 1.4 pg/L (10/23/07) 28-Nov-07 NR 6 ND ND ND ND ND ND ND ND ND 28-May-08 2.7 6.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 2.6 6.0 Dry 14.1 3.8 J ND ND ND ND ND ND 2-Jun-09 2.6 6.0 ND 2.9 J ND ND ND ND ND ND ND 19-Nov-09 2.6 6.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 2.6 6.0 ND ND ND ND ND ND ND ND ND GWPS = 1 pg/L (8/1/10) 29-Nov-10 2.6 6.0 ND ND ND ND ND ND ND ND ND 31-May-11 2.6 6.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 5.0 6.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 6.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 6.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 6.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 6.0 6.5 7.6 ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 6.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 6.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 3.8 6.0 ND 7.1 ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 3.8 6.0 ND 4.9 J ND ND ND ND ND ND ND 2-May-16 EPA 6010 3.8 6.0 ND 6.4 ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 3.8 6.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 3.9 6.0 - ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 3.9 6.0 - ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 3.9 6.0 - ND ND ND ND ND ND ND ND IMAC = 1 pg/L (8/1/10) 4-Dec-18 EPA 6010D 3.9 5.0 - ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 3.9 5.0 - ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 3.0 5.0 - ND ND ND ND ND ND ND --- 6-May-20 EPA 6010D 3.0 5.0 - ND ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 1 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Arsenic 6-Oct-94 NR 5 ND ND 5.0 NI NI NI NI NI NA 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 2.9 J 2.5 J ND 4.1 J 3.0 J ND NC21- = 50 ug/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND ND 28-May-08 2.6 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 2.7 10.0 Dry ND 6.0 B ND ND 3.3 B ND ND 4.8 J 2-Jun-09 2.7 10.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 2.7 10.0 3.0 J ND 5.9 J ND ND ND ND ND ND NC21- = 10 Ng/L (01/01/10) 15-Jun-10 2.7 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 2.7 10.0 ND ND 4.9 J ND ND ND ND ND ND 31-May-11 2.7 10.0 3.3 J 3.0 J 9.9 J ND ND ND ND ND ND 19-Dec-11 5.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND 3.4 J ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND 5.2 J ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 3.4 J ND 6.8 J ND ND ND ND ND ND 26-Jun-17 EPA 6010 5.0 10.0 -- ND 5.1 J ND ND ND ND ND ND 14-Dec-17 EPA 6010 5.0 10.0 - ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 - ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 5.0 10.0 - ND 5.1 J ND ND ND ND ND ND 6-May-19 EPA 6010D 5.0 10.0 - ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 4.7 10.0 - ND ND ND ND ND ND ND --- 6-May-20 EPA 6010D 4.7 10.0 - ND ND ND ND ND ND ND -- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 2 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte DL RL MW-1 MW-2 MW-3 MW-6S MW-61) Blanks Barium 28-Apr-94 NR 100 110 840 590 NI NI NI NI NI NA 3-May-00 NR 500 NA 870 550 ND ND ND ND ND ND 8-Nov-00 NR 500 NA 810 ND ND ND ND ND ND ND 29-May-01 NR 500 NA 890 540 ND ND ND ND ND ND 6-Nov-01 NR 500 NA 790 ND ND ND ND ND ND ND 21-May-02 NR 500 NA 800 510 ND ND ND ND ND ND 13-Nov-02 NR 500 NA 650 ND ND ND ND ND ND ND 14-May-03 NR 500 ND 690 530 ND ND ND ND ND ND 19-Nov-03 NR 500 ND 780 ND ND ND ND ND ND ND 5-May-04 NR 500 ND 810 ND ND ND ND ND ND ND 9-Nov-04 NR 500 ND 890 ND ND ND ND ND ND ND 25-May-05 NR 500 ND 730 ND ND ND ND ND ND ND 2-Nov-05 NR 500 ND 930 ND ND ND ND ND ND ND 24-May-06 NR 500 ND 915 ND ND ND ND ND ND ND 1-Nov-06 NR 500 ND 937 ND ND ND ND ND ND ND 29-May-07 NR 100 107 882 484 127 94.9 J 29.9 J 33.0 J 15.1 J ND NC21- = 2,000 pg/L (10/23/07) 28-Nov-07 NR 100 159 945 434 132 128 34.5 J 25.0 J 16.9 J 0.30 J 28-May-08 0.2 100 Dry 812 394 124 101 31.0 J 37.0 J 13.8 J 0.33 J 5-Nov-08 0.20 100 Dry 773 385 119 88.4 J 22.6 B 74.4 J 13.0 B 10.5 J 2-Jun-09 0.20 100 80.4 J 795 432 118 90.8 J 20.8 B 85.4 J 10.5 B 15.2 J 19-Nov-09 0.20 100 114 758 464 138 103 32.6 B 106 12.5 B 19.8 J NC2L = 700 pg/L (01/01/10) 15-Jun-10 0.20 100 141 751 495 162 163 43.1 B 72.8 B 13.1 B 26.3 J 29-Nov-10 0.20 100 89.0 J 843 416 169 128 36.2 J 71.8 J 11.9 J ND 31-May-11 0.20 100 92.4 J 949 464 190 103 30.8 J 33.5 J 13.9 J ND 19-Dec-11 5.0 100 126 809 435 164 214 39.5 J 39.7 J 13.0 J ND 30-May-12 5.0 100 64.7 J 905 475 175 151 27.9 J 26.3 J 13.1 J ND 3-Dec-12 5.0 100 107 739 431 177 97.8 J 25.3 J 51.9 J 14.7 J ND 11-Jun-13 5.0 100 136 662 539 INS 96.2 J 35.6 B 55.9 B 12.0 B 13.7 J 29-Oct-13 5.0 100 135 906 534 199 88.8 J 34.5 J 23.9 J 12.6 J ND 6-May-14 EPA 6010 5.0 100 81.4 J 772 439 186 110 31.9 J 45.2 J 12.4 J ND 21-Oct-14 EPA 6010 5.0 100 82.2 J 1,050 415 194 86.2 J 29.2 J 22.4 J 11.8 J ND 19-May-15 EPA 6010 2.5 100 94.0 J 421 192 85.6 J 32.9 J 43.6 J 12.2 J ND 7-Dec-15 EPA 6010 2.5 100 109.0 1,210 470 205 157 44.7 J 43.6 J 12.3 J ND 2-May-16 EPA 6010 2.5 100 100.0 J 1,060 497 186 73.2 J 38.5 J 59.8 J 11.4 J ND 12-Dec-16 EPA 6010 2.5 100 78.7 J 1,040 388 167 82 J 28 J 16.3 J 8.1 J ND 26-Jun-17 EPA 6010 2.5 100 -- 1,470 547 218 89.3 J 35.4 J 29.3 J 12.8 J 2.5 J 14-Dec-17 EPA 6010 2.5 100 - 1,240 498 212 87.8 J 27.7 J 62.2 J 12.8 J ND 14-May-18 EPA 6010 2.5 100 - 888 566 206 75.5 J 40.4 J 214 12.0 J ND 4-Dec-18 EPA 6010D 2.5 5 - 1,160 507 205 82 27.1 42.6 12.8 ND 6-May-19 EPA 6010D 2.5 5 - 1,040 454 181 82.6 37.5 43.7 12.2 ND 5-Nov-19 EPA 6010D 2.5 5 - 1,370 448 219 130 46.5 35.6 17.0 - 6-May-20 EPA 6010D 3.5 5 - 1,160 486 194 71.2 55.4 27.2 12.8 - Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 3 of 41 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date MeWA DL RL MW-1 MW-2 S MW-61) Blanks Beryllium 12-May-99 NR 2 ND 2.0 ND ND 2.0 2.1 NI NI ND 19-Oct-99 NR 2 ND ND ND ND ND 4.0 NI NI ND 3-May-00 NR 2 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 2 NA ND ND ND ND 2.0 ND ND ND 29-May-01 NR 2 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 2 NA ND ND ND ND ND ND ND ND 21-May-02 NR 2 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 2 NA 2.4 2.3 2.1 ND ND ND ND ND 14-May-03 NR 2 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 2 ND ND ND ND ND ND ND ND ND 5-May-04 NR 2 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 2 ND ND ND ND ND ND ND ND ND 25-May-05 NR 2 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 2 ND ND ND ND ND ND ND ND ND 24-May-06 NR 2 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 2 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND GWPS = 4 ug/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND ND ND ND ND ND 28-May-08 0.1 1.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.10 1.0 Dry ND ND ND ND 0.11 J 0.17 J ND ND 2-Jun-09 0.10 1.0 ND ND ND ND ND ND 0.18 J ND ND 19-Nov-09 0.10 1.0 ND ND ND ND ND ND 0.11 J ND ND 15-Jun-10 0.10 1.0 ND ND ND ND 0.26 J 0.18 J ND ND ND 29-Nov-10 0.10 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.10 1.0 ND ND 0.21 J ND ND 0.24 J ND ND ND 19-Dec-11 1.0 1.0 ND ND ND ND ND ND ND ND ND 30-May-12 1.0 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 1.0 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 1.0 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 1.0 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 0.5 1.0 - ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 0.5 1.0 - ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 0.5 1.0 - ND ND ND ND ND ND ND ND IMAC = 4 ug/L (10/23/07) 4-Dec-18 EPA 6010D 0.5 1.0 - ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 0.5 1.0 - ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 0.2 1.0 - ND ND ND ND 0.23 J ND ND - 6-May-20 EPA 6010D 0.7 1.0 - ND ND ND ND ND ND ND - Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 4 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Cadmium 28 Apr-94 NR 1 ND ND ND NI NI NI NI NI NA 3-May-00 NR 1 NA 8.0 4.0 J 2.0 J 2.0 J 2.0 J 2.0 J ND ND 8-Nov-00 NR 1 NA 13.0 4.0 ND ND 4.0 1.0 ND ND 29-May-01 NR 1 NA 13.0 5.0 ND ND 2.0 J 1.0 J ND ND 6-Nov-01 NR 1 NA 10.0 3.6 ND ND ND ND ND ND 21-May-02 NR 1 NA 7.9 3.0 ND ND ND ND ND ND 13-Nov-02 NR 1 NA 11.0 4.7 1.5 ND ND ND 1.1 ND 14-May-03 NR 1 11.0 12.0 7.1 ND ND ND ND ND ND 19-Nov-03 NR 1 ND ND ND ND ND 2.3 1.1 ND ND 5-May-04 NR 1 ND 1.6 ND ND ND ND ND ND ND 9-Nov-04 NR 1 2.2 13.0 4.5 ND ND ND ND ND ND 25-May-05 NR 1 ND ND ND ND 16.0 ND ND ND ND 2-Nov-05 NR 1 ND ND ND ND 11.0 ND ND ND ND 24-May-06 NR 1 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 1 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND NC21- = 1.75 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND ND ND ND ND ND 28-May-08 0.5 1.0 Dry 1.7 ND ND 2.6 ND ND ND ND 5-Nov-08 0.50 1.0 Dry 0.50 J ND ND ND ND ND ND ND 1-Jun-09 0.50 1.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.50 1.0 ND ND ND ND ND 1.3 ND ND ND NC21- = 2 pg/L (01/01/10) 15-Jun-10 0.50 1.0 ND ND ND ND 1.1 ND ND ND ND 29-Nov-10 0.50 1.0 ND ND ND ND ND 0.80 J ND ND ND 31-May-11 0.50 1.0 ND 0.78 J ND ND ND ND ND ND ND 19-Dec-11 1.0 1.0 ND 1.6 ND ND ND 6.6 ND ND ND 30-May-12 1.0 1.0 ND 5.0 ND ND ND ND ND ND ND 3-Dec-12 1.0 1.0 ND 2.3 ND ND ND ND ND ND ND 11-Jun-13 1.0 1.0 ND 2.0 ND NS ND ND ND ND ND 29-Oct-13 1.0 1.0 ND 4.5 ND 2.0 ND ND ND ND ND 6-May-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 0.5 1.0 - ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 0.5 1.0 - ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 0.5 1.0 - 0.91 J ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 0.5 1.0 - 2 0.78 J ND ND ND ND ND ND 6-May-19 EPA 6010D 0.5 1.0 - ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 0.4 1.0 - ND ND ND ND ND ND ND - 6-May-20 EPA 6010D 0.4 1.0 - ND 0.51 J ND ND ND ND ND -- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 5 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-5 MW-6S MW-61) Blanks Chromium 28-Apr-94 NR 20 ND ND ND NI NI NI NI NI NA 3-May-00 NR 10 NA 16.0 ND ND 14.0 14.0 12.0 ND ND 8-Nov-00 NR 10 NA 17.0 ND ND ND 20.0 ND ND ND 29-May-01 NR 10 NA 12.0 J ND ND ND 10.0 J ND ND ND 6-Nov-01 NR 10 NA 12.0 ND ND ND ND ND ND ND 21-May-02 NR 10 NA 10.0 J ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 12.0 ND ND ND ND ND ND ND 14-May-03 NR 10 12.0 ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND ND ND ND ND NC21- = 50 pg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND 2.9 J ND ND ND ND 28-May-08 0.4 10.0 Dry ND ND ND 2.3 B 0.80 B ND ND 0.85 J 5-Nov-08 0.40 10.0 Dry ND ND ND ND 0.46 J 0.59 J ND ND 2-Jun-09 0.40 10.0 ND ND ND ND 2.8 J 0.42 J 0.65 J ND ND 19-Nov-09 0.40 10.0 ND 1.8 B 0.65 B ND 2.7 B ND ND ND 1.1 J NC2L = 10 pg/L (01/01/10) 15-Jun-10 0.40 10.0 ND 0.89 J 2.0 J 1.7 J 12.6 1.9 J 1.3 J ND ND 29-Nov-10 0.40 10.0 ND 3.8 J 3.5 J 1.2 J 5.1 J 0.88 J ND ND ND 31-May-11 0.40 10.0 1.4 B 2.1 B 8.4 J 1.3 B 3.6 B 2.1 B 2.2 B 2.5 B 0.73 J 19-Dec-11 5.0 10.0 ND ND ND ND 15.4 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 8.3 J ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS 5.2 J ND ND 6.2 J ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 8.8 J ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND 2.8 J ND ND 4.2 J ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 3.7 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 -- 3.1 J ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 - ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 - ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 - ND ND ND 3.4 J ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 - 2.5 J ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 1.0 5.0 - ND ND ND 5.9 1.8 J ND ND - 6-May-20 EPA 6010D 3.7 5.0 - ND ND ND ND ND ND ND - Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 6 of 41 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Cobalt 6-Oct-94 NR 10 32.0 172 35.0 NI NI NI NI NI NA 3-May-00 NR 10 NA 110 26.0 ND ND 18.0 21.0 ND ND 8-Nov-00 NR 10 NA 110 ND ND ND 25.0 11.0 ND ND 29-May-01 NR 10 NA 130 21.0 ND ND 12.0 ND ND ND 6-Nov-01 NR 10 NA 110 14.0 ND ND ND ND ND ND 21-May-02 NR 10 NA 110 15.0 ND ND ND ND ND ND 13-Nov-02 NR 10 NA 110 15.0 12.0 ND ND ND ND ND 14-May-03 NR 10 140 100 26.0 ND ND ND ND ND ND 19-Nov-03 NR 10 150 110 27.0 ND ND ND ND ND ND 5-May-04 NR 10 51.0 110 17.0 13.0 ND ND ND ND ND 9-Nov-04 NR 10 54.0 100 ND ND ND ND ND ND ND 25-May-05 NR 10 79.0 95.0 15.0 ND ND ND ND ND ND 2-Nov-05 NR 10 47.0 100 ND ND ND ND ND ND ND 24-May-06 NR 10 62.9 116 10.0 ND ND 10.4 ND ND ND 1-Nov-06 NR 10 63.2 114 ND ND ND ND ND ND ND 29-May-07 NR 10 60.1 105 6.3 J 10.7 ND ND 2.4 J ND ND GWPS = 70 ug/L (10/23/07) 28-Nov-07 NR 10 43.1 110 3.6 J 5.1 J ND ND ND ND ND 28-May-08 0.6 10.0 Dry ND ND 8.8 J ND ND ND ND ND 5-Nov-08 0.60 10.0 Dry 35.7 ND 9.4 B 0.86 B 3.9 B 5.3 B 1.6 B 3.5 J 1-Jun-09 0.60 10.0 158 158 52.8 10.9 B 12.3 B 7.8 B 14.9 B 6.8 B 3.3 J 19-Nov-09 0.60 10.0 126 87.7 18.7 4.5 J ND 0.96 J 5.9 J ND ND 15-Jun-10 0.60 10.0 155 186 53.3 2.9 J 5.2 J 2.2 J 2.9 J 2.3 J ND GWPS = 1 pg/L (10/1/10) 29-Nov-10 0.60 10.0 110 233 67.3 0.69 J ND 1.2 J 3.9 J 3.7 J ND 31-May-11 0.60 10.0 38.6 111 19.2 19.3 1.3 J ND 1.1 J ND ND 19-Dec-11 5.0 10.0 ND 63.8 ND ND ND ND ND ND ND 30-May-12 5.0 10.0 85.6 144 38.4 5.2 J ND ND ND ND ND 3-Dec-12 5.0 10.0 36.0 92.9 10.4 5.2 J ND ND ND ND ND 11-Jun-13 5.0 10.0 178 220 85.7 NS 5.4 J ND 7.1 J 5.8 J ND 29-Oct-13 5.0 10.0 226 267 96.1 ND ND ND ND 6.6 J ND 6-May-14 EPA 6010 5.0 10.0 39.0 65.2 ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 43.8 118 9.1 J ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 47.7 117 10.7 ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 52.0 126 13.9 ND ND ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 56.2 120 15.6 ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 24.6 99.8 7.1 J ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 - 137 12.4 ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 - 114 11.0 ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 - 102 20.2 ND ND ND 4.2 J ND ND IMAC = 1 ug/L (10/1/10) 4-Dec-18 EPA 6010D 2.5 5.0 - 120 17.3 2.6 J ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 - 107 14.4 ND ND ND ND ND ND 5-Nov-19 EPA 6010D 1.1 5.0 - 119 12.3 ND 1.6 J 1.3 J ND ND -- 6-May-20 EPA 6010D 3.6 5.0 - 106 16.8 ND ND ND ND ND -- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 7 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Copper 12-May-99 NR 5 13.0 22.0 ND ND 45.0 5.1 NI NI ND 19-Oct-99 NR 200 ND ND ND ND ND ND NI NI ND 3-May-00 NR 200 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 200 NA ND ND ND ND ND ND ND ND 29-May-01 NR 200 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 200 NA ND ND ND ND ND ND ND ND 21-May-02 NR 200 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 200 NA ND ND ND ND ND ND ND ND 14-May-03 NR 200 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 200 ND ND ND ND ND ND ND ND ND 5-May-04 NR 200 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 200 ND ND ND ND ND ND ND ND ND 25-May-05 NR 200 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 200 ND ND ND ND ND ND ND ND ND 24-May-06 NR 200 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 200 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 1.7 J ND ND 1.6 J ND ND NC21- = 1,000 pg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND 3.30 J ND ND ND ND 28-May-08 0.3 10 Dry 0.49 B ND ND 2.8 J 0.76 B 0.50 B ND 0.38 J 5-Nov-08 0.30 10 Dry 0.89 B ND ND ND ND 0.72 B ND 0.94 J 2-Jun-09 0.30 10 9.7 J ND ND ND 1.5 J ND ND ND ND 19-Nov-09 0.30 10 5.3 J ND 0.35 J ND 2.1 J 0.41 J 1.0 J ND ND 15-Jun-10 0.30 10 13.9 ND ND ND 11.0 5.9 J 1.4 J ND ND 29-Nov-10 0.30 10 2.0 J ND 2.6 J 0.31 J 6.0 J 1.2 J 1.2 J ND ND 31-May-11 0.30 10 4.5 J 5.1 J 13.2 ND 0.98 J ND ND ND ND 19-Dec-11 5.0 10 10.9 ND 5.5 J ND 14.1 ND ND ND ND 30-May-12 5.0 10 ND ND ND ND 10.8 ND ND ND ND 3-Dec-12 5.0 10.0 5.2 J ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 13.1 B 5.1 B ND NS ND ND ND ND 10.8 29-Oct-13 5.0 10.0 10.2 ND ND 8.9 J ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 5.2 J 3.7 J ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 7.9 J 7.7 J 3.6 J ND 7.4 J ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 5.8 J ND ND ND 3.6 J ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 7.9 J ND ND 3.2 J ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 -- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 - 5.9 J 2.8 J 51.3 ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 - ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 - ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 - 8.3 5.8 3.2 J ND 3.1 J ND ND ND 5-Nov-19 EPA 6010D 2.1 5.0 - 3.3 J ND ND 4.6 J ND ND ND -- 6-May-20 EPA 6010D 4.3 5.0 - ND ND ND ND ND ND ND -- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 8 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Lead 28-Apr-94 NR 1 6.0 5.0 2.0 NI NI NI NI NI NA 3-May-00 NR 10 NA ND ND ND ND 12.0 ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND 31.0 10.0 ND ND 29-May-01 NR 10 NA 12.0 J ND ND ND 12.0 J ND ND ND 6-Nov-01 NR 10 NA 11.0 ND ND ND ND ND ND ND 21-May-02 NR 10 NA 10.0 J ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 14.0 ND ND ND ND ND ND ND 14-May-03 NR 10 38.0 10.0 J ND ND ND ND ND ND ND 19-Nov-03 NR 10 16.0 ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND 14.0 ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND 11.7 ND ND ND 22.6 ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 2.5 B 4.2 B 3.5 B 4.6 B 6.0 B 4.5 B 2.9 B ND 6.1 J NC21- = 15 pg/L (10/23/07) 28-Nov-07 NR 10 9.8 J 7.4 J 2.0 J ND ND ND ND ND ND 28-May-08 4 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 4.0 10.0 Dry ND ND ND ND ND ND ND ND 1-Jun-09 4.0 10.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 4.0 10.0 4.6 J ND ND ND ND ND ND ND ND 15-Jun-10 4.0 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 4.0 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 4.0 10.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 5.0 10.0 6.1 J ND ND ND 5.4 J ND ND ND ND 30-May-12 5.0 10.0 ND 5.9 J ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 10.0 6.7 J ND ND 5.4 J ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND 5.1 J ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 2.9 J 6.2 J ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 4.6 J 6.6 J 2.9 J 4.4 J 2.6 J 3.0 J ND ND ND 2-May-16 EPA 6010 2.5 10.0 4.4 J 5 J ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 6.1 J 6.1 J ND 3.9 J ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 -- 6.8 J 2.6 J ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 - 5.4 J ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 - ND ND ND ND 3.5 J 4.1 J ND ND 4-Dec-18 EPA 6010D 2.5 5.0 - ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 - 4.9 J 3.2 J ND ND ND ND ND ND 5-Nov-19 EPA 6010D 1.6 5.0 - 5.2 2.0 J ND ND ND ND ND -- 6-May-20 EPA 6010D 4.5 5.0 - ND ND ND ND ND ND ND -- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 9 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-61) Blanks Nickel 12-May-99 NR 5 11.0 36.0 11.0 NA 23.0 30.0 NI NI ND 19-Oct-99 NR 50 ND ND ND ND ND 59.0 NI NI ND 3-May-00 NR 50 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 50 NA ND ND ND ND ND ND ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND ND ND ND ND 5-May-04 NR 50 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 50 ND ND ND 21.3 J ND ND ND ND ND NC2L = 100 Ng/L (10/23/07) 28-Nov-07 NR 50 ND 2.4 J ND 20.4 J 2.5 J ND ND ND ND 28-May-08 1.7 50.0 Dry 9.1 J 10.5 J 31.9 J 2.1 J ND ND ND ND 5-Nov-08 1.7 50.0 Dry 11.6 J 5.9 B 26.3 J 2.8 B ND ND ND 2.2 J 2-Jun-09 1.7 50.0 14 J 8.9 J 3.8 J 21.8 J 2.3 J ND ND ND ND 19-Nov-09 1.7 50.0 10.3 B 8.6 B 3.1 B 19.8 J 2.3 B ND ND ND 2.2 J 15-Jun-10 1.7 50.0 5.9 J 6.7 J ND 14.5 J 4.8 J ND ND ND ND 29-Nov-10 1.7 50.0 4.7 J 7.6 J ND 17.3 J ND ND ND ND ND 31-May-11 1.7 50.0 3.5 B 15.9 J 11.8 J 23.0 J 2.8 B ND ND ND 2.3 J 19-Dec-11 5.0 50.0 ND 8.8 J ND 18.9 J ND ND ND ND ND 30-May-12 5.0 50.0 ND 9.4 J ND 19.9 J ND ND ND ND ND 3-Dec-12 5.0 50.0 ND 7.5 J ND 20.8 J ND ND ND ND ND 11-Jun-13 5.0 50.0 ND 6.8 J ND INS ND ND ND ND ND 29-Oct-13 5.0 50.0 ND 7.1 J ND 20.6 J ND ND ND ND ND 6-May-14 EPA 6010 5.0 50.0 ND 10.1 J ND 21.1 J ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 50.0 ND 16.9 J ND 24.3 J ND ND ND ND ND 19-May-15 EPA 6010 2.5 50.0 ND 15.8 J 3.1 J 23.8 J ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 50.0 2.6 J 17.0 J 4.3 J 26.4 J 3.8 J ND ND ND ND 2-May-16 EPA 6010 2.5 50.0 ND 14.9 J 3.8 J 23.3 J ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 50.0 2.6 J 14.6 J 3.5 J 21.0 J ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 50.0 -- 20.9 J 4.6 J 25.6 J ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 50.0 - 17.6 J 3.6 J 26.6 J ND ND ND ND ND 14-May-18 EPA 6010 2.5 50.0 - 13.9 J 5.1 J 27.9 J ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 - 17.2 4.3 J 26.3 ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 - 14.5 4.4 J 25.7 3.0 J ND ND ND ND 5-Nov-19 EPA 6010D 0.9 5.0 - 16.8 3.3 J 28.7 2.4 J 1.0 J ND ND - 6-May-20 EPA 6010D 3.5 5.0 - 14.4 5.4 24.1 ND ND ND ND - Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 10 of 41 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-5 MW-6S MW-61) Blanks Selenium 12-May-97 NR 5 ND ND ND NI NI NI NI NI NA 3-May-00 NR 20 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 20 NA ND ND ND ND ND ND ND ND 29-May-01 NR 20 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 20 NA ND ND ND ND ND ND ND ND 21-May-02 NR 20 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 20 NA ND ND ND ND ND ND ND ND 14-May-03 NR 20 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 20 ND ND ND ND ND ND ND ND ND 5-May-04 NR 20 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 20 ND ND ND ND ND ND ND ND ND 25-May-05 NR 20 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 20 ND ND ND ND ND ND ND ND ND 24-May-06 NR 20 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 20 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND 2.5 J 4.6 J ND ND ND NC21- = 50 Ng/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND 2.4 J 28-May-08 3.8 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 3.8 10.0 Dry 29.6 12.3 B ND ND 5.6 B ND 5.1 B 4.2 J 2-Jun-09 3.8 10.0 ND 5.6 J ND ND ND ND ND ND ND 19-Nov-09 3.8 10.0 ND 5.6 J ND ND ND 5.5 J 5.0 J ND ND NC2L = 20 Ng/L (01/01/10) 15-Jun-10 3.8 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 3.8 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 3.8 10.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 10.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 10.0 10.0 11.5 16.8 ND ND ND ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 10.0 10.0 ND ND ND INS ND ND ND ND ND 29-Oct-13 10.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 10.0 10.0 ND ND ND 16.2 ND ND ND ND ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 5.0 10.0 ND 5.2 J 5.7 J ND ND ND ND ND ND 12-Dec-16 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 5.0 10.0 - ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 5.0 10.0 - ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 - ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 5.0 10.0 - ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 5.0 10.0 - ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 4.7 10.0 - ND ND ND ND ND ND ND - 6-May-20 EPA 6010D 4.7 10.0 - 9.2 J ND ND ND 7.2 J ND ND - Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 11 of 41 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Silver 28 Apr-94 NR 1 ND ND ND Ni Ni Ni Ni Ni NA 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10.0 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 2.5 J ND ND 2.2 J ND ND NC21- = 17.5 pg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND ND 28-May-08 0.1 10.0 Dry 1.4 J 0.41 J 0.54 J ND ND ND ND ND 5-Nov-08 0.10 10.0 Dry 2.4 J 0.86 B 0.87 B 0.12 B 0.15 B 0.18 B 0.18 B 0.20 J 2-Jun-09 0.10 10.0 ND 0.90 J ND 0.37 J ND ND ND ND ND 19-Nov-09 0.10 10.0 0.68 J 1.7 J 0.86 J 1.0 J 0.19 J 0.22 J 0.30 J 0.30 J ND NC21- = 20 pg/L (01/01/10) 15-Jun-10 0.10 10.0 ND 0.25 J 0.31 J 0.50 J 0.15 J ND ND 0.14 J ND 29-Nov-10 0.10 10.0 ND 0.58 J 0.11 J 0.59 J ND ND ND ND ND 31-May-11 0.10 10.0 0.91 J 2.9 J 0.81 J 0.71 J ND 0.11 J 0.30 J ND ND 19-Dec-11 5.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 - ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 - ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 - ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 - ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 - ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 2.5 5.0 - ND ND ND ND ND ND ND - 6-May-20 EPA 6010D 2.5 5.0 - ND ND ND ND ND ND ND -- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 12 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Thallium 19-Oct-99 NR 10 ND ND ND ND ND ND NI NI ND 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND NA 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 26.0 ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 10.0 ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 13.0 16.0 12.0 ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5.5 ND ND ND ND ND 0.066 ND ND ND GWPS = 0.28 Ng/L (10/23/07) 28-Nov-07 NR 5.5 0.215 J ND ND ND 0.155 J 0.074 J ND ND ND 28-May-08 3 5.5 Dry ND ND ND 3.8 J ND ND ND ND 5-Nov-08 3.0 5.5 Dry 3.1 J ND ND ND ND ND ND ND 2-Jun-09 3.0 5.5 ND ND ND ND ND ND ND ND ND 19-Nov-09 3.0 5.5 ND ND ND ND ND 3.5 J ND ND ND 15-Jun-10 3.0 5.5 5.5 B 7.8 B 4.2 B ND ND 7.0 B ND ND 3 J GWPS = 0.2 Ng/L (10/1/10) 29-Nov-10 3.0 5.5 4.6 B 4.1 B 4.1 B ND ND (4.8) J ND ND 4.0 (ND) J 31-May-11 3.0 5.5 ND ND ND ND ND ND ND ND ND 19-Dec-11 5.4 5.5 ND ND ND ND ND ND ND ND ND 30-May-12 5.4 5.5 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.4 5.5 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.4 5.5 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.4 5.5 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.4 5.5 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.4 5.5 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 5.0 5.5 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 5.0 5.5 6.9 7.5 ND ND ND ND ND ND ND 2-May-16 EPA 6010 5.0 5.5 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 5.0 5.5 8.3 B ND ND ND ND ND ND ND 5.5 J 26-Jun-17 EPA 6O2OB 0.0 5.5 - ND ND ND ND 0.075 J ND ND ND 14-Dec-17 EPA 6O2OB 0.03 0.1 - ND ND ND ND 0.061 J ND ND ND 14-May-18 EPA 6020 0.50 5.5 - ND ND ND ND ND ND ND ND IMAC = 0.2 Ng/L (10/1/10) 4-Dec-18 EPA 6O2OB 0.06 0.1 - ND ND ND ND ND ND ND ND 6-May-19 EPA 6O2OB 0.06 0.1 - ND ND ND ND 0.087 J ND ND ND 5-Nov-19 EPA 6O2OB 0.06 0.1 - ND ND 0.061 J 0.060 J 0.16 ND ND - 6-May-20 EPA 6O2OB 0.12 0.2 - ND ND ND ND 0.20 ND ND - Resample > 16-Jul-20 EPA 6O2OB 0.12 0.2 - NS NS NS NS ND NS NS - Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 13 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Vanadium 19-Oct-99 NR 40 110 51.0 ND ND 61.0 210 NI NI ND 3-May-00 NR 40 NA 61.0 ND ND ND 49.0 ND ND ND 8-Nov-00 NR 40 NA ND ND ND ND 69.0 ND ND ND 29-May-01 NR 40 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 40 NA ND ND ND ND ND ND ND ND 21-May-02 NR 40 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 40 NA ND ND ND ND ND ND ND ND 14-May-03 NR 40 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 40 ND ND ND ND ND ND ND ND ND 5-May-04 NR 40 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 40 ND ND ND ND ND ND ND ND ND 25-May-05 NR 40 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 40 ND ND ND ND ND ND ND ND ND 24-May-06 NR 40 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 40 ND ND ND ND ND ND ND ND ND 29-May-07 NR 25 ND ND ND ND ND ND 1.5 J ND ND GWPS = 3.5 pg/L (10/23/07) 28-Nov-07 NR 25 ND ND ND ND 10.0 J 1.1 J ND ND ND 28-May-08 0.2 25.0 Dry 0.75 J 0.90 J ND 5.5 J 2.5 J 1.2 J 0.22 J ND 5-Nov-08 0.20 25.0 Dry 1.2 B 0.78 B ND 0.86 B 0.82 B 1.5 B ND 0.85 J 2-Jun-09 0.20 25.0 1.0 B 3.1 B 1.8 B 1.0 B 9.5 J 1.3 B 2.4 B 0.41 B 1.2 J 19-Nov-09 0.20 25.0 0.74 B 2.2 B 2.9 B 0.86 B 6.6 J 1.2 B 2.0 B 0.25 B 0.58 J 15-Jun-10 0.20 25.0 2.0 B 1.4 B 1.3 B 0.34 B 27.4 5.0 B 2.2 B ND 1.2 J GWPS = 0.3 pg/L (10/1/10) 29-Nov-10 0.20 25.0 ND 1.3 J 5.4 J 1.6 J 9.4 J 1.4 J 0.45 J ND ND 31-May-11 0.20 25.0 ND ND 12.0 J 3.3 J 6.1 J 2.2 J 0.85 J 0.31 J ND 19-Dec-11 5.0 25.0 6.6 J ND 6.2 J ND 24.3 J 6.3 J ND ND ND 30-May-12 5.0 25.0 ND ND ND ND 19.3 J ND ND ND ND 3-Dec-12 5.0 25.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 25.0 ND ND ND NS 13.2 J ND ND ND ND 29-Oct-13 5.0 25.0 ND ND ND ND 7.5 J ND ND ND ND 6-May-14 EPA 6010 5.0 25.0 ND ND ND ND 7.6 J ND ND ND ND 21-Oct-14 EPA 6010 5.0 25.0 ND 5.4 J ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 25.0 5.7 J 13.0 J 5.3 J ND 4.3 J ND ND ND ND 7-Dec-15 EPA 6010 2.5 25.0 8.3 J 16.6 J 7.3 J ND 19.4 J 5.6 J ND ND ND 2-May-16 EPA 6010 2.5 25.0 3.9 J 5.0 J 3.7 J ND 7.9 J 3.4 J ND ND ND 12-Dec-16 EPA 6010 2.5 25.0 6.0 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 25.0 -- 4.2 J 3.3 J ND ND 2.9 J ND ND ND 14-Dec-17 EPA 6010 2.5 25.0 - 5.1 J ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 25.0 - 3.6 J ND ND 2.5 J 5.8 J 2.7 J ND ND IMAC = 0.3 pg/L (10/1/10) 4-Dec-18 EPA 6010D 2.5 5.0 - ND 3.0 J ND 6.0 ND ND ND ND Resample -> 8-Feb-19 EPA 6010D 2.5 5.0 - -- - - ND - - - - 6-May-19 EPA 6010D 2.5 5.0 - 4.1 J ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 1.3 5.0 - 5.3 1.8 J ND 10.0 3.8 J ND ND - Resample-> 23-Jan-20 EPA 6010D 1.3 5.0 - 5.1 - - 2.3 J - - - - 6-May-20 EPA 6010D 3.9 5.0 - ND ND ND ND 7.2 ND ND - Resample -> 16-Jul-20 EPA 6010D 3.9 5.0 - NS NS NS NS ND NS NS - Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 14 of 41 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3 MW-5 MW-6S MW-6D Blanks Zinc 28-Apr-94 NR 10 12.0 ND ND NI NI NI NI NI NA 3-May-00 NR 50 NA ND ND 81.0 50.0 J ND ND ND ND 8-Nov-00 NR 50 NA 50.0 ND ND 50.0 100 50.0 ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND 80.0 ND ND ND 5-May-04 NR 50 110 ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 5.1 B ND ND 7.9 B 5.0 B 4.5 B 3.2 B 4.7 B 2.0 J NC21- = 1,050 ug/L (10/23/07) 28-Nov-07 NR 10 26.3 ND 4.5 J 8.4 J 6.7 J 5.8 J ND 4.2 J ND 28-May-08 0.4 10.0 Dry 18.9 2.9 B 93.9 5.7 B 7.0 B 5.5 B 4.9 B 2.1 J 5-Nov-08 0.40 10.0 Dry ND ND 5.2 B ND 2.7 B 2.2 B 1.4 B 8.9 J 2-Jun-09 0.40 10.0 19.1 B 0.48 B ND 6.5 B 8.2 B 4.8 B 3.2 B 0.65 B 83.0 19-Nov-09 0.40 10.0 20.4 7.4 B 12.1 B 15.4 B 6.7 B 11.2 B 5.6 B 5.6 B 3.5 J NC21- = 1,000 ug/L (01/01/10) 15-Jun-10 0.40 10.0 16.9 0.50 J ND 2.3 J 15.0 9.2 J 3.8 J ND ND 29-Nov-10 0.40 10.0 9.6 J 15.3 8.8 J 2.9 J 6.0 J 13.8 1.1 J ND ND 31-May-11 0.40 10.0 6.5 B 11.9 B 47.1 B 12.5 B 12.0 B 10.4 B 9.9 B 4.8 B 13.7 19-Dec-11 10.0 10.0 47.0 ND 13.7 183 24.6 15.6 ND ND ND 30-May-12 10.0 10.0 ND 12.1 ND ND 12.0 ND 13.8 ND ND 3-Dec-12 10.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 10.0 10.0 17.9 B 12.0 B 14.8 B NS ND ND ND ND 76.3 29-Oct-13 10.0 10.0 12.9 ND ND 118 10.1 ND ND ND ND 6-May-14 EPA 6010 10.0 10.0 ND ND ND 17.5 ND ND ND ND ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND ND 19.7 ND ND ND ND ND 19-May-15 EPA 6010 5.0 10.0 ND ND ND 6.1 J ND 5.7 J ND 5.5 J ND 7-Dec-15 EPA 6010 5.0 10.0 6.5 B ND 8.7 B 5.2 B 16.3 B 11.2 B ND ND 7.2 J 2-May-16 EPA 6010 5.0 10.0 6.0 J ND 7.6 J 10.2 7.1 J 6.5 J ND ND ND 12-Dec-16 EPA 6010 5.0 10.0 9.2 J ND 27.8 26.3 ND ND ND ND ND 26-Jun-17 EPA 6010 5.0 10.0 -- ND 5.9 J ND ND ND ND ND ND 14-Dec-17 EPA 6010 5.0 10.0 - ND ND 28.8 ND ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 - 6.2 J ND 5.4 J ND 9.7 J 11.5 ND ND 4-Dec-18 EPA 6010D 5.0 10.0 - ND 12.7 ND 5.3 J ND ND ND ND 6-May-19 EPA 6010D 5.0 10.0 - ND 5.9 J ND ND 7.5 J ND 7.6 J ND 5-Nov-19 EPA 6010D 3.9 10.0 - ND ND ND 15.4 7.5 J ND 7.0 J - 6-May-20 EPA 6010D 9.5 10.0 - ND ND ND ND 12.6 ND ND - Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 15 of 41 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Organics Acetone 28-Apr-94 NR 100 200 2000 ND NI NI NI NI NI NA 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 390 600 ND ND ND ND ND ND ND 19-Nov-03 NR 100 4900 180 ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 230 ND ND ND ND ND ND ND ND 25-May-05 NR 100 580 ND ND ND ND ND ND ND ND 2-Nov-05 NR 100 450 ND ND ND ND ND ND ND ND 24-May-06 NR 100 1380 D ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 340 ND ND ND ND ND ND ND ND 29-May-07 NR 100 1070 28.0 J ND ND ND ND ND ND ND NC21- = 700 pVL (10/23/07) 28-Nov-07 NR 100 690 D ND ND ND 2.8 B 2.5 B ND 2.7 B 4.3 J 28-May-08 20 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 20.0 100 Dry 34.4 J ND ND ND ND ND ND ND 2-Jun-09 2.2 100 13.3 B 45.7 J ND ND 3.9 B ND ND ND 3.2 J 19-Nov-09 2.2 100 3.1 B ND ND 159 50.0 J 5.4 B ND ND 3.8 J NC21- = 6,000 ug/L (01/01/10) 15-Jun-10 2.2 100 193 101 5.7 B 5.4 B ND ND ND ND 9.8 J 29-Nov-10 2.2 100 123 15.7 B ND ND ND ND ND ND 4.3 J 31-May-11 2.2 100 26.3 B ND ND 10.3 B ND ND ND ND 3.9 J 19-Dec-11 2.2 100 24.4 B ND ND ND ND ND ND ND 6.6 J 30-May-12 2.2 100 283 91.3 J ND ND ND ND ND ND ND 3-Dec-12 10.0 100 43.4 J 46.8 J ND ND ND ND ND ND ND 11-Jun-13 10.0 100 763 1190 J ND NS ND ND ND ND ND 29-Oct-13 50.0 500 611 32.9 J ND ND ND ND ND ND ND 6-May-14 EPA 8260 10.0 100 104 109 ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 10.0 100 91.2 J ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 10.0 100 239 J ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 10.0 100 118 21.8 J ND ND ND ND ND ND ND 2-May-16 EPA 8260 10.0 100 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 10.0 100 69.0 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 10.0 100 -- ND ND ND 10.6 J 23.6 J 12.5 J 20.7 J 23.0 J 14-Dec-17 EPA 8260 10.0 100 - ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 10.0 100 - 484 ND ND ND ND ND ND ND 4-Dec-18 EPA 8260E 10.0 25 - ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 8.2 25 - 299 ND ND ND ND ND ND ND 5-Nov-19 EPA8260D 6.2 25 - 105 ND ND ND ND ND ND - 6-May-20 EPA8260D 6.2 25 - 255 ND ND ND ND ND ND - Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 16 of 41 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Benzene 28-Apr-94 NR 5 ND 15.0 8.7 NI NI NI NI NI NA 3-May-00 NR 5 NA 9.2 10.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 9.4 6.3 ND ND ND ND ND ND 29-May-01 NR 5 NA 9.4 7.4 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 7.3 6.4 ND ND ND ND ND ND 21-May-02 NR 5 NA 9.2 8.4 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 7.6 6.8 ND ND ND ND ND ND 14-May-03 NR 5 ND ND 8.6 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 8.9 6.4 ND ND ND ND ND ND 5-May-04 NR 5 ND 7.3 6.4 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 8.4 6.4 ND ND ND ND ND ND 25-May-05 NR 5 ND 9.0 6.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 6.0 ND ND ND ND ND ND ND 24-May-06 NR 5 ND 5.5 ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND 7.5 ND ND ND ND ND ND ND 29-May-07 NR 1 1.1 8.3 5.5 3.0 ND ND ND ND ND NC21- = 1 pg/L (10/23/07) 28-Nov-07 NR 1 ND 7.0 3.9 ND ND ND ND ND ND 28-May-08 0.3 1.0 Dry 6.4 5.1 2.5 0.78 J ND ND ND ND 5-Nov-08 0.25 1.0 Dry 5.8 4.0 2.3 1.1 ND ND ND ND 2-Jun-09 0.25 1.0 1.2 6.4 6.6 2.1 0.58 J ND ND ND ND 19-Nov-09 0.25 1.0 ND ND ND 0.82 J 6.5 5.9 ND ND ND 15-Jun-10 0.25 1.0 1.1 7.9 5.1 1.9 ND ND ND ND ND 29-Nov-10 0.25 1.0 ND 7.1 4.2 2.2 ND ND ND ND ND 31-May-11 0.25 1.0 0.45 J 7.6 4.6 2.0 0.60 J ND ND ND ND 19-Dec-11 0.25 1.0 0.77 J 7.4 4.9 2.2 0.89 J ND ND ND ND 30-May-12 0.25 1.0 0.5 J 6.6 ND 1.6 ND ND ND ND ND 3-Dec-12 0.25 1.0 0.31 J 6.9 4.5 1.6 ND ND ND ND ND 11-Jun-13 0.25 1.0 1.5 8.9 5.7 NS ND ND ND ND ND 29-Oct-13 0.25 1.0 0.81 J 8.7 4.5 1.4 ND ND ND ND ND 6-May-14 EPA 8260 0.25 1.0 0.37 J 9.5 5.4 1.6 ND ND ND ND ND 21-Oct-14 EPA 8260 0.25 1.0 ND 8.4 3.9 1.3 ND ND ND ND ND 19-May-15 EPA 8260 0.25 1.0 ND 7.2 4.1 1.3 ND ND ND ND ND 7-Dec-15 EPA 8260 0.25 1.0 ND 7.7 4.3 1.3 ND ND ND ND ND 2-May-16 EPA 8260 0.25 1.0 0.48 J 9.1 3.9 1.2 ND ND ND ND ND 12-Dec-16 EPA 8260 0.25 1.0 ND 8.0 3.5 1.3 ND ND ND ND ND 26-Jun-17 EPA 8260 0.25 1.0 - 6.7 3.7 1.3 ND ND ND ND ND 14-Dec-17 EPA 8260 0.25 1.0 - 6.3 3.9 1.2 ND ND ND ND ND 14-May-18 EPA 8260 0.25 1.0 - 6.2 3.9 1.1 ND ND ND ND ND 4-Dec-18 EPA 8260B 0.25 1.0 - 7.5 3.8 1.3 ND ND ND ND ND 6-May-19 EPA 8260D 0.20 1.0 - 10.4 4.6 1.7 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.15 1.0 - 8.3 3.4 1.3 ND ND ND ND -- 6-May-20 EPA 8260D 0.15 1.0 - 9.6 3.7 1.4 ND ND ND ND -- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 17 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Carbon disulfide 27-May-98 NR 5 ND ND 8.2 ND ND ND NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND ND ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 ND ND ND ND ND ND ND ND ND NC21- = 700 Ng/L (10/23/07) 28-Nov-07 NR 100 ND ND ND ND ND ND ND ND ND 28-May-08 1.2 101 Dry ND ND ND ND ND ND ND ND 5-Nov-08 1.2 100 Dry ND ND ND ND ND ND ND ND 2-Jun-09 1.2 100 ND ND ND ND ND ND ND ND ND 19-Nov-09 1.2 100 ND ND ND ND ND ND ND ND ND 15-Jun-10 1.2 100 ND ND ND ND ND ND ND ND ND 29-Nov-10 1.2 100 ND ND ND ND ND ND ND ND ND 31-May-11 1.2 100 ND ND ND ND ND ND ND ND ND 19-Dec-11 1.2 100 ND ND ND ND ND ND ND ND ND 30-May-12 1.2 100 ND ND ND ND ND ND ND ND ND 3-Dec-12 1.2 100 ND ND ND ND ND ND ND ND ND 11-Jun-13 1.2 100 ND ND ND NS ND ND ND ND ND 29-Oct-13 1.2 100 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 1.2 100 — ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 1.2 100 — ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 1.2 100 — ND ND ND ND ND ND ND ND 4-Dec-18 EPA 826OB 1.2 2 — ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.8 10 — ND ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.4 2 — ND ND ND ND ND ND ND — 6-May-20 EPA 8260D 0.4 2 — ND ND ND ND ND ND ND -- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 18 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-6S MW-61) Blanks Chlorobenzene 28-Apr-94 NR 5 ND 5.4 12.0 NI NI NI NI NI NA 3-May-00 NR 5 NA 8.8 16.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 8.5 19.0 ND ND ND ND ND ND 29-May-01 NR 5 NA 9.3 18.0 ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND 17.0 ND ND ND ND ND ND 21-May-02 NR 5 NA ND 20.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND 17.0 ND ND ND ND ND ND 14-May-03 NR 5 ND ND 19.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 10.0 21.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 11.0 20.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 12.0 24.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 13.0 24.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 15.0 29.0 ND ND ND ND ND ND 24-May-06 NR 5 ND 11.3 24.3 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 15.0 29.0 ND ND ND ND ND ND 29-May-07 NR 3 0.47 J 16.0 31.0 4.9 0.28 J ND ND ND ND NC21- = 50 pg/L (10/23/07) 28-Nov-07 NR 3 ND 13.0 28.0 4.1 ND ND ND ND ND 28-May-08 0.23 3.0 Dry 13.7 24.3 4.0 0.67 J ND ND ND ND 5-Nov-08 0.23 3.0 Dry 13.5 21.6 4.0 0.89 J ND ND ND ND 2-Jun-09 0.23 3.0 0.30 J 15.0 24.7 3.9 0.49 J ND ND ND ND 19-Nov-09 0.23 3.0 ND ND 1.7 J 0.30 J 14.9 27.0 ND ND ND 15-Jun-10 0.23 3.0 0.31 J 15.5 25.7 4.0 ND ND ND ND ND 29-Nov-10 0.23 3.0 ND 15.4 28.8 5.2 0.76 J ND ND ND ND 31-May-11 0.23 3.0 ND 17.9 26.8 5.7 0.43 J ND ND ND ND 19-Dec-11 0.23 3.0 ND 17.4 28.2 5.7 0.65 J ND ND ND ND 30-May-12 0.23 3.0 0.26 J 17.8 27.6 5.4 ND ND ND ND ND 3-Dec-12 0.23 3.0 ND 18.9 29.0 5.7 ND ND ND ND ND 11-Jun-13 0.23 3.0 0.56 J 18.2 28.4 NS ND ND ND ND ND 29-Oct-13 0.23 3.0 ND 19.0 30.0 5.9 ND ND ND ND ND 6-May-14 EPA 8260 0.23 3.0 ND 19.5 32.1 6.4 ND ND ND ND ND 21-Oct-14 EPA 8260 0.23 3.0 ND 20.5 33.8 6.8 0.32 J ND ND ND ND 19-May-15 EPA 8260 0.23 3.0 ND 21.5 31.5 7.0 ND ND ND ND ND 7-Dec-15 EPA 8260 0.23 3.0 ND 20.6 33.2 7.0 ND ND ND ND ND 2-May-16 EPA 8260 0.23 3.0 0.31 J 24.2 31.1 6.6 ND ND ND ND ND 12-Dec-16 EPA 8260 0.23 3.0 ND 19.9 32.3 7.0 0.27 J ND ND ND ND 26-Jun-17 EPA 8260 0.23 3.0 - 21.4 29.0 7.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.23 3.0 - 22.2 30.5 6.9 ND ND ND ND ND 14-May-18 EPA 8260 0.23 3.0 - 20.4 29.3 6.7 ND ND ND ND ND 4-Dec-18 EPA 8260E 0.23 1.0 - 23.7 34.4 7.1 ND ND ND ND ND 6-May-19 EPA8260D 0.53 1.0 - 26.6 36.4 8.7 ND ND ND ND ND 5-Nov-19 EPA8260D 0.23 1.0 - 22.5 32.7 7.5 ND ND 0.28 J ND --- 6-May-20 EPA8260D 0.23 1.0 - 26.7 32.3 8.2 ND ND ND ND - Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 19 of 41 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Chloroethane 12-May-99 NR 10 ND ND ND ND ND ND NI NI ND 19-Oct-99 NR 10 ND ND ND ND ND ND NI NI ND 3-May-00 NR 10 NA ND ND ND ND ND NA ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND NA ND NA 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND ND ND ND ND NC21- = 2,800 ug/L (10/23/07) 28-Nov-07 NR 10 ND ND 3.4 J ND ND ND ND ND ND 28-May-08 0.54 10.0 Dry ND 2.5 J ND ND ND ND ND ND 5-Nov-08 0.54 10.0 Dry ND 2.3 J ND ND ND ND ND ND 2-Jun-09 0.54 10.0 ND ND 2.7 J ND ND ND ND ND ND 19-Nov-09 0.54 10.0 ND ND ND ND 0.81 J ND ND ND ND NC2L = 3,000 ug/L (01/01/10) 15-Jun-10 0.54 10.0 ND 0.86 J 2.1 J ND ND ND ND ND ND 29-Nov-10 0.54 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.54 10.0 ND ND 4.1 J ND ND ND ND ND ND 19-Dec-11 0.54 10.0 ND 0.58 J ND 0.56 J ND ND ND ND ND 30-May-12 0.54 10.0 ND ND 1.9 J ND ND ND ND ND ND 3-Dec-12 0.54 10.0 ND 0.60 J 2.8 J ND ND ND ND ND ND 11-Jun-13 0.54 10.0 ND ND 1.2 J NS ND ND ND ND ND 29-Oct-13 0.54 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.54 10.0 ND ND 1.7 J ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.54 10.0 ND ND 2.5 J ND ND ND ND ND ND 19-May-15 EPA 8260 0.54 10.0 ND ND 2.1 J ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.54 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.54 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.54 10.0 ND ND 2.6 J ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.54 10.0 - ND 2.0 J ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.54 10.0 - ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.54 10.0 - ND 1.2 J ND ND ND ND ND ND 4-Dec-18 EPA 8260E 0.54 1.0 - ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.52 1.0 - ND 1.8 0.56 J ND ND ND ND ND 5-Nov-19 EPA8260D 0.49 1.0 - ND ND ND ND ND ND ND - 6-May-20 EPA8260D 0.49 1.0 - ND 1.6 ND ND ND ND ND - Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 20 of 41 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Chloroform 19-Nov-09 0.14 5.0 ND ND 0.21 J ND ND ND ND ND ND NC21- = 70 Ng/L (10/23/07) 15-Jun-10 0.14 5.0 ND ND ND ND ND ND 0.33 B ND 0.28 J 29-Nov-10 0.14 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.14 5.0 ND ND ND ND ND ND 0.35 B ND 0.63 J 19-Dec-11 0.14 5.0 ND ND ND ND ND ND 0.44 J ND ND 30-May-12 0.14 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.14 5.0 ND ND ND ND ND ND 0.37 J ND ND 11-Jun-13 0.14 5.0 ND ND ND NS ND ND ND ND 42.4 29-Oct-13 0.14 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.14 5.0 ND ND ND ND ND ND 0.18 J ND ND 21-Oct-14 EPA 8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.14 5.0 ND ND ND ND ND ND 0.20 J ND NA 7-Dec-15 EPA 8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.14 5.0 ND ND ND ND ND ND 0.56 J ND ND 26-Jun-17 EPA 8260 0.14 5.0 - ND ND ND ND ND 0.56 J ND ND 14-Dec-17 EPA 8260 0.14 5.0 - ND ND ND ND ND 0.31 J ND ND 14-May-18 EPA 8260 0.14 5.0 - ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.14 1.0 - ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.58 1.0 - ND ND ND ND ND 0.67 J ND ND 5-Nov-19 EPA 8260D 2.30 5.0 - ND ND ND ND ND ND ND - 6-May-20 EPA 8260D 2.30 5.0 - ND ND ND ND ND ND ND - Chloromethane 2-Jun-09 0.11 1.0 ND ND 0.28 J ND ND ND ND 0.17 J ND NC21- = 2.6 pg/L (10/23/07) 19-Nov-09 0.11 1.0 ND ND ND ND ND ND ND ND ND NC21- = 3 Ng/L (01/01/10) 15-Jun-10 0.11 1.0 ND ND ND ND ND ND ND 0.14 B 0.15 J 29-Nov-10 0.11 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.11 1.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.11 1.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.11 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.11 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.11 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.11 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.11 1.0 0.33 J ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND 0.36 J 26-Jun-17 EPA 8260 0.11 1.0 - 0.26 J 0.16 J ND 0.30 J 1 J 0.33 J 0.45 J ND 14-Dec-17 EPA 8260 0.11 1.0 - ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.11 1.0 - ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.11 1.0 - ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.38 1.0 - ND ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.39 1.0 - ND ND ND ND ND ND ND - 6-May-20 EPA 8260D 0.39 1.0 - ND ND ND ND ND ND ND -- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 21 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Anaiyte Collection Date MethdA DL RL MW-1 MW-2 MW-3S MV ff-MW-6S MW-6D nks 1,2-Dichlorobenzene 28-Apr-94 NR 5 ND ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND 1.1 J ND ND ND ND ND ND ND NC21- = 24 pg/L (10/23/07) 28-Nov-07 NR 5 ND 2.8 J 0.63 J ND 0.74 J ND ND ND ND 28-May-08 0.3 5.0 Dry 2.6 J 0.66 J ND 0.49 J ND ND ND ND 5-Nov-08 0.30 5.0 Dry 2.2 J 0.51 J ND 0.61 J ND ND ND ND 2-Jun-09 0.30 5.0 ND 2.5 J 0.79 J ND 0.34 J ND ND ND ND 19-Nov-09 0.30 5.0 ND ND ND ND 2.7 J 1.2 J ND ND ND NC21- = 20 pg/L (01/01/10) 15-Jun-10 0.30 5.0 ND 2.3 J 1.1 J 0.33 J ND ND ND ND ND 29-Nov-10 0.30 5.0 ND 2.3 J 0.63 J ND ND ND ND ND ND 31-May-11 0.30 5.0 ND 2.2 J 0.51 J ND ND ND ND ND ND 19-Dec-11 0.30 5.0 ND 2.4 J 0.67 J ND ND ND ND ND ND 30-May-12 0.30 5.0 ND 2.3 J 0.72 J ND ND ND ND ND ND 3-Dec-12 0.30 5.0 ND 2.2 J 0.85 J 0.32 J ND ND ND ND ND 11-Jun-13 0.30 5.0 ND 2.2 J 0.91 J NS ND ND ND ND ND 29-Oct-13 0.30 5.0 ND 2.4 J 1.1 J ND ND ND ND ND ND 6-May-14 EPA 8260 0.30 5.0 ND 2.3 J 0.77 J ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.30 5.0 ND 2.5 J 0.64 J ND ND ND ND ND ND 19-May-15 EPA 8260 0.30 5.0 ND ND 0.6 J 0.3 J ND ND ND ND ND 7-Dec-15 EPA 8260 0.30 5.0 ND 2.5 J 0.57 J ND ND ND ND ND ND 2-May-16 EPA 8260 0.30 5.0 ND 2.7 J 0.7 J ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.30 5.0 ND 2.3 J 0.58 J ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.30 5.0 - 2.4 J 0.45 J 0.33 J ND ND ND ND ND 14-Dec-17 EPA 8260 0.30 5.0 - 2.2 J 0.66 J 0.31 J ND ND ND ND ND 14-May-18 EPA 8260 0.30 5.0 - 1.7 J 0.79 J ND ND ND ND ND ND 4-Dec-18 EPA 8260E 0.30 1.0 - 2.2 0.91 J ND ND ND ND ND ND 6-May-19 EPA8260D 0.49 1.0 - 2.4 0.88 J ND ND ND ND ND ND 5-Nov-19 EPA8260D 0.29 1.0 - 2.2 0.6 J ND ND ND ND ND - 6-May-20 EPA8260D 0.29 1.0 - 2.2 0.64 J ND ND ND ND ND - Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 22 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks 1,4-Dichlorobenzene 28-Apr-94 NR 5 ND 34.0 22.0 NI NI NI NI NI ND 3-May-00 NR 5 NA 50.0 12.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 54.0 13.0 ND ND ND ND ND ND 29-May-01 NR 5 NA 58.0 12.0 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 57.0 15.0 ND ND ND ND ND ND 21-May-02 NR 5 NA 59.0 14.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 52.0 13.0 ND ND ND ND ND ND 14-May-03 NR 5 ND 50.0 15.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 50.0 19.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 48.0 18.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 53.0 14.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 59.0 13.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 57.0 14.0 5.0 ND ND ND ND ND 24-May-06 NR 5 ND 42.9 11.2 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 57.0 10.0 ND ND ND ND ND ND 29-May-07 NR 1 2.3 60.0 16.0 4.7 1.1 ND ND ND ND NC21- = 1.4 Ng/L (10/23/07) 28-Nov-07 NR 1 ND 48.0 10.0 ND 3.3 ND ND ND ND 28-May-08 0.33 1.0 Dry 52.9 9.5 3.8 2.5 ND ND ND ND 5-Nov-08 0.33 1.0 Dry 48.6 8.1 3.7 3.2 ND ND ND ND 2-Jun-09 0.33 1.0 1.9 58.2 12.0 4.2 2.1 ND ND ND ND 19-Nov-09 0.33 1.0 ND ND ND 2.4 49.2 18.5 ND ND ND NC21- = 6 pg/L (01/01/10) 15-Jun-10 0.33 1.0 2.1 46.2 16.4 4.2 0.93 J ND ND ND ND 29-Nov-10 0.33 1.0 1.2 45.8 12.0 4.4 1.8 ND ND ND ND 31-May-11 0.33 1.0 1.2 47.6 8.3 4.2 1.3 ND ND ND ND 19-Dec-11 0.33 1.0 2.1 44.8 10.8 4.3 1.3 ND ND ND ND 30-May-12 0.33 1.0 1.4 47.1 12.0 4.4 0.71 J ND ND ND ND 3-Dec-12 0.33 1.0 0.99 J 47.9 13.1 4.6 0.52 J ND ND ND ND 11-Jun-13 0.33 1.0 1.6 50.0 15.3 NS 0.46 J ND ND ND ND 29-Oct-13 0.33 1.0 1.4 48.3 19.2 5.0 0.48 J ND ND ND ND 6-May-14 EPA 8260 0.33 1.0 0.95 J 47.6 14.2 5.0 0.37 J ND ND ND ND 21-Oct-14 EPA 8260 0.33 1.0 1.2 45.2 12.3 5.0 0.99 J ND ND ND ND 19-May-15 EPA 8260 0.33 1.0 0.56 J 47.5 11.2 4.9 0.54 J ND ND ND ND 7-Dec-15 EPA 8260 0.33 1.0 0.81 J 47.1 11.2 4.3 ND ND ND ND ND 2-May-16 EPA 8260 0.33 1.0 0.97 J 50.5 14.7 4.4 ND ND ND ND ND 12-Dec-16 EPA 8260 0.33 1.0 0.47 J 39.7 10.1 4.9 0.69 J ND ND ND ND 26-Jun-17 EPA 8260 0.33 1.0 -- 42.6 10.5 ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.33 1.0 - 41.6 11.5 4.5 0.69 J ND ND ND ND 14-May-18 EPA 8260 0.33 1.0 - 35.9 13.7 4.4 0.41 J ND ND ND ND 4-Dec-18 EPA 8260B 0.33 1.0 - 39.9 14.8 ND ND ND ND ND ND 6-May-19 EPA 8260D 0.58 1.0 - 47.3 14.6 4.8 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.26 1.0 - 38.6 10.7 4.2 0.48 J ND ND ND -- 6-May-20 EPA 8260D 0.26 1.0 - 39.0 10.7 4.1 ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 23 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3DM ONE S MW-6D Blanks 1,1-Dichloroethane 28-Apr-94 NR 5 14.0 ND 8.4 NI NI NI NI NI ND 3-May-00 NR 5 NA ND 8.4 J 7.6 J 6.1 J ND ND ND ND 8-Nov-00 NR 5 NA ND 7.0 10.0 8.1 ND ND ND ND 29-May-01 NR 5 NA ND 8.7 11.0 9.9 ND ND ND ND 6-Nov-01 NR 5 NA ND 7.3 12.0 7.0 ND ND ND ND 21-May-02 NR 5 NA ND 7.4 12.0 8.9 ND ND ND ND 13-Nov-02 NR 5 NA ND 5.4 11.0 9.0 ND ND ND ND 14-May-03 NR 5 ND ND ND 8.1 5.4 ND ND ND ND 19-Nov-03 NR 5 ND ND ND 7.9 5.3 ND ND ND ND 5-May-04 NR 5 ND ND ND 7.8 7.1 ND ND ND ND 9-Nov-04 NR 5 ND ND ND 7.5 7.0 ND ND ND ND 25-May-05 NR 5 ND ND ND 8.0 6.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND 7.0 5.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 2.8 J 2.6 J 2.7 J 8.8 11.0 ND ND ND ND NC21- = 70 pg/L (10/23/07) 28-Nov-07 NR 5 ND 0.76 J 1.2 J 5.7 11.0 ND ND ND ND 28-May-08 0.32 5.0 Dry 0.87 J 2.0 J 6.6 10.6 ND ND ND ND 5-Nov-08 0.32 5.0 Dry 0.85 J 1.9 J 6.3 11.3 ND ND ND ND 2-Jun-09 0.32 5.0 1.3 J 0.98 J 2.3 J 6.5 8.6 ND ND ND ND 19-Nov-09 0.32 5.0 ND ND ND 0.51 J 1.0 J 1.5 J ND ND ND NC2L = 6 pg/L (01/01/10) 15-Jun-10 0.32 5.0 1.3 J 1.2 J 0.93 J 5.6 3.7 J ND ND ND ND 29-Nov-10 0.32 5.0 ND ND 1.4 J 6.2 8.0 ND ND ND ND 31-May-11 0.32 5.0 0.42 J 1.3 J 2.1 J 6.3 7.8 ND ND ND ND 19-Dec-11 0.32 5.0 0.58 J 1.2 J 1.8 J 5.9 6.7 ND ND ND ND 30-May-12 0.32 5.0 ND 1.0 J 1.2 J 5.4 4.1 J ND ND ND ND 3-Dec-12 0.32 5.0 ND 1.1 J 1.4 J 4.7 J 2.1 J ND ND ND ND 11-Jun-13 0.32 5.0 0.37 J 1.1 J 1.1 J NS 2.2 J ND ND ND ND 29-Oct-13 0.32 5.0 ND 1.1 J 0.67 J 5.1 3 J ND ND ND ND 6-May-14 EPA 8260 0.32 5.0 0.34 J 0.98 J 0.81 J 5.2 2.4 J ND ND ND ND 21-Oct-14 EPA 8260 0.32 5.0 ND 0.90 J 0.83 J 4.2 J 4.6 J ND ND ND ND 19-May-15 EPA 8260 0.32 5.0 ND 0.79 J 0.64 J 4.4 J 2.5 J ND ND ND ND 7-Dec-15 EPA 8260 0.32 5.0 ND 0.59 J 0.75 J 4.9 J 1.9 J ND ND ND ND 2-May-16 EPA 8260 0.32 5.0 ND 0.43 J 0.65 J 4.3 J 0.72 J ND ND ND ND 12-Dec-16 EPA 8260 0.32 5.0 ND 0.71 J 0.87 J 4.9 J 3.1 J ND ND ND ND 26-Jun-17 EPA 8260 0.32 5.0 - 0.71 J 0.83 J 4.5 J 2.1 J ND ND ND ND 14-Dec-17 EPA 8260 0.32 5.0 - 0.59 J 0.68 J 4.6 J 2.2 J ND ND ND ND 14-May-18 EPA 8260 0.32 5.0 - ND 0.5 J 4.3 J 1.3 J ND ND ND ND 4-Dec-18 EPA 8260E 0.32 1.0 - 0.37 J 0.46 J 4.0 1.1 ND ND ND ND 6-May-19 EPA8260D 0.41 1.0 - 0.68 J ND 6.1 ND ND ND ND ND 5-Nov-19 EPA8260D 0.27 1.0 - 0.57 J 0.43 J 4.7 1.5 ND ND ND - 6-May-20 EPA8260D 0.27 1.0 - 0.61 J ND 4.8 0.48 J ND ND ND - Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 24 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks 1,2-Dichloroethane 19-Nov-09 0.12 1.0 ND ND ND ND 0.15 J ND ND ND ND NC21- = 0.4 pVL (01/01/10) 15-Jun-10 0.12 1.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.12 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.12 1.0 ND 0.14 J ND ND ND ND ND ND ND 19-Dec-11 0.12 1.0 ND 0.13 J ND ND ND ND ND ND ND 30-May-12 0.12 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.12 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.12 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.12 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.24 1.0 ND 0.25 J ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.24 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.24 1.0 ND 0.27 J ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.24 1.0 - ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.24 1.0 - ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.24 1.0 - ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.24 1.0 - ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.67 1.0 - ND ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.34 1.0 - ND ND ND ND ND ND ND - 6-May-20 EPA 8260D 0.34 1.0 - ND ND ND ND ND ND ND -- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 25 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyta Collection Date MaIA DL RL MW-1 MW-2 - S MW-61) Blanks 1,1-Dichloroethene 28-Apr-94 NR 5 ND ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND ND ND ND ND ND ND ND ND NC21- = 7 pg/L (10/23/07) 28-Nov-07 NR 5 ND ND ND ND ND ND ND ND ND 28-May-08 0.56 1.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.56 5.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.56 5.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 0.56 5.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.56 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.56 5.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.56 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.56 5.0 ND ND ND ND ND ND ND ND ND NC 2L = 350 pg/L (04/01/2013) II-Jun-13 0.56 5.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.56 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.56 5.0 - ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.56 5.0 - ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.56 5.0 - ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260E 0.56 1.0 - ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.72 1.0 - ND ND ND ND ND ND ND ND 5-Nov-19 EPA8260D 0.24 1.0 - ND ND ND ND ND ND ND - 6-May-20 EPA8260D 0.24 1.0 - ND ND ND ND ND ND ND - 1,4-Dioxane (p-Dioxane) 4-Dec-18 EPA 8260E Mod. 9.5 10 ND 219 56.3 127 ND ND ND 4.0 ND NC 2L = 3 pg/L 6-May-19 EPA 8260D Mod. 5.8 10 -- 218 57.0 128 2.4 ND ND ND ND 5-Nov-19 EPA 8260DMod. 1.2 2 3 236 36.4 269 2.7 ND ND ND - 6-May-20 EPA 8260DMod. 5.8 10 -- 213 33.3 111 ND ND ND ND - Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 26 of 41 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Coll DL RL MW-1 MW-2 MMMM-MW-5 MW-6S MW-61) Blanks cis-1,2-DichIoroethene 28-Apr-94 NR 5 40 ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND 23.0 61.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND 31.0 69.0 ND ND ND ND 29-May-01 NR 5 NA ND ND 34.0 61.0 ND ND ND ND 6-Nov-01 NR 5 NA ND ND 34.0 56.0 ND ND ND ND 21-May-02 NR 5 NA ND ND 29.0 69.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND 25.0 75.0 ND ND ND ND 14-May-03 NR 5 46.0 ND ND 14.0 36.0 ND ND ND ND 19-Nov-03 NR 5 26.0 ND ND 13.0 38.0 ND ND ND ND 5-May-04 NR 5 10.0 ND ND 10.0 46.0 ND ND ND ND 9-Nov-04 NR 5 6.0 ND ND 9.1 47.0 ND ND ND ND 25-May-05 NR 5 6.0 ND ND 7.0 29.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND 11.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND 9.3 ND ND ND ND 1-Nov-06 NR 5 ND ND ND 6.8 2.1 ND ND ND ND 29-May-07 NR 5 8.3 ND ND 7.5 36.0 ND ND ND ND NC2L = 70 pg/L (10/23/07) 28-Nov-07 NR 5 ND ND ND 4.5 J 58.0 ND ND ND ND 28-May-08 0.19 5.0 Dry 0.31 J 0.29 J 5.1 56.3 ND ND ND ND 5-Nov-08 0.19 5.0 Dry ND 0.22 J 4.9 J 65.7 ND ND ND ND 2-Jun-09 0.19 5.0 17.3 0.33 J 0.44 J 5.3 47.6 ND ND ND ND 19-Nov-09 0.19 5.0 ND ND ND 9.1 0.31 B ND ND ND 0.26 J 15-Jun-10 0.19 5.0 9.9 0.45 J ND 6.2 20.9 ND ND ND ND 29-Nov-10 0.19 5.0 4.8 J 0.31 J ND 6.4 37.1 0.46 J ND ND ND 31-May-11 0.19 5.0 3.0 J 0.33 J ND 7.3 38.6 ND ND ND ND 19-Dec-11 0.19 5.0 3.1 J 0.41 J 0.25 J 6.8 30.3 ND ND ND ND 30-May-12 0.19 5.0 4 J ND ND 7.4 17.1 ND ND ND ND 3-Dec-12 0.19 5.0 0.96 J ND ND 7.0 9.2 ND ND ND ND 11-Jun-13 0.19 5.0 9.4 0.69 J 0.20 J NS 8.8 ND ND ND ND 29-Oct-13 0.19 5.0 4.0 J 0.32 J ND 8.1 12.2 ND ND ND ND 6-May-14 EPA 8260 0.19 5.0 2.2 J 0.40 J ND 7.9 9.3 ND ND ND ND 21-Oct-14 EPA 8260 0.19 5.0 1.1 J 0.30 J ND 7.3 21.4 ND ND ND ND 19-May-15 EPA 8260 0.19 5.0 1.1 J 0.34 J ND 7.7 11.3 ND ND ND ND 7-Dec-15 EPA 8260 0.19 5.0 2.1 J ND ND 8.9 8.9 ND ND ND ND 2-May-16 EPA 8260 0.19 5.0 1.7 J 0.38 J ND 7.8 3.6 J ND ND ND ND 12-Dec-16 EPA 8260 0.19 5.0 0.8 J 0.36 J ND 10.4 17.2 ND ND ND ND 26-Jun-17 EPA 8260 0.19 5.0 -- 0.31 J ND 10.0 10.7 ND ND ND ND 14-Dec-17 EPA 8260 0.19 5.0 - 0.38 J 0.22 J 10.8 11.1 ND ND ND ND 14-May-18 EPA 8260 0.19 5.0 - ND 0.22 J 10.7 6.9 ND ND ND ND 4-Dec-18 EPA 8260E 0.19 1.0 - 0.30 J ND 10.8 5.8 ND ND ND ND 6-May-19 EPA8260D 0.66 1.0 - ND ND 18.7 1.2 ND ND ND ND 5-Nov-19 EPA8260D 0.29 1.0 - 0.33 J ND 14.6 J 8 ND ND ND - 6-May-20 EPA8260D 0.29 1.0 - 0.41 J ND 16.4 2.6 ND ND ND - Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 27 of 41 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Me DL RL MW-1 MW-2 MW-3S MW-31) IIIIff MW-5 MW-6S MW-6D Blanks Trans-1,2-Dichloroethene 19-Oct-99 NR 5 ND ND ND ND ND ND NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND NA 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND ND ND ND 0.2 J ND ND ND ND NC21- = 100 Ng/L (10/23/07) 28-Nov-07 NR 5 ND ND ND ND 0.43 J ND ND ND ND 28-May-08 0.49 5.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.49 5.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.49 5.0 ND ND 0.55 J ND ND ND ND ND ND 19-Nov-09 0.49 5.0 ND ND ND ND ND 0.54 J ND ND ND 15-Jun-10 0.49 5.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.49 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.49 5.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.49 5.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.49 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.49 5.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.49 5.0 ND ND 0.57 J NS ND ND ND ND ND 29-Oct-13 0.49 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.49 5.0 - ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.49 5.0 - ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.49 5.0 - ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260E 0.49 1.0 - ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.46 1.0 - ND ND ND ND ND ND ND ND 5-Nov-19 EPA8260D 0.25 1.0 - ND ND ND ND ND ND ND - 6-May-20 EPA8260D 0.25 1.0 - ND ND ND ND ND ND ND - Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 28 of 41 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks 1,2-Dichloropropane 19-Oct-99 NR 5 ND ND ND ND ND ND NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND NA 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND 5.3 ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND 6.0 ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND 4.3 ND ND ND ND ND NC21- = 0.51 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 1.4 ND ND ND ND 28-May-08 0.27 1.0 Dry ND ND 2.5 1.2 ND ND ND ND 5-Nov-08 0.27 1.0 Dry ND ND 2.3 1.3 ND ND ND ND 2-Jun-09 0.27 1.0 ND ND ND 2.4 0.84 J ND ND ND ND 19-Nov-09 0.27 1.0 ND ND ND ND ND ND ND ND ND NC21- = 0.6 pg/L (01/01/10) 15-Jun-10 0.27 1.0 ND ND ND 2.3 0.30 J ND ND ND ND 29-Nov-10 0.27 1.0 ND ND ND 2.5 ND ND ND ND ND 31-May-11 0.27 1.0 ND ND ND 2.3 0.61 J ND ND ND ND 19-Dec-11 0.27 1.0 ND ND ND 2.1 0.66 J ND ND ND ND 30-May-12 0.27 1.0 ND ND ND 1.9 ND ND ND ND ND 3-Dec-12 0.27 1.0 ND ND ND 1.6 ND ND ND ND ND 11-Jun-13 0.27 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.27 1.0 ND ND ND 1.5 ND ND ND ND ND 6-May-14 EPA 8260 0.27 1.0 ND ND ND 1.5 ND ND ND ND ND 21-Oct-14 EPA 8260 0.27 1.0 ND ND ND 1.3 ND ND ND ND ND 19-May-15 EPA 8260 0.27 1.0 ND ND ND 1.2 ND ND ND ND ND 7-Dec-15 EPA 8260 0.27 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.27 1.0 ND ND ND 1.3 ND ND ND ND ND 12-Dec-16 EPA 8260 0.27 1.0 ND ND ND 1.1 0.37 J ND ND ND ND 26-Jun-17 EPA 8260 0.27 1.0 - ND ND 0.92 J ND ND ND ND ND 14-Dec-17 EPA 8260 0.27 1.0 - ND ND 0.92 J ND ND ND ND ND 14-May-18 EPA 8260 0.27 1.0 - ND ND 0.87 J ND ND ND ND ND 4-Dec-18 EPA 8260B 0.27 1.0 - ND ND 0.94 J ND ND ND ND ND 6-May-19 EPA 8260D 0.60 1.0 - ND ND 1.1 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.19 1.0 - ND ND 0.87 J ND ND ND ND -- 6-May-20 EPA 8260D 0.19 1.0 - ND ND 0.84 J ND ND ND ND -- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 29 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-6D Blanks Ethylbenzene 28-Apr-94 NR 50 ND 310 29.0 NI NI NI NI NI ND 3-May-00 NR 5 NA 130 ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA 110 ND ND ND ND ND ND ND 29-May-01 NR 5 NA 120 ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA 89.0 ND ND ND ND ND ND ND 21-May-02 NR 5 NA 100 ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA 86.0 ND ND ND ND ND ND ND 14-May-03 NR 5 ND 160 11.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 66.0 ND ND ND ND ND ND ND 5-May-04 NR 5 ND 58.0 ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND 65.0 ND ND ND ND ND ND ND 25-May-05 NR 5 ND 80.0 ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND 75.0 ND ND ND ND ND ND ND 24-May-06 NR 5 ND 45.8 ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND 64.0 ND ND ND ND ND ND ND 29-May-07 NR 1 ND 59.1 ND ND ND ND ND ND ND NC21- = 550 pg/L (10/23/07) 28-Nov-07 NR 1 ND 39.0 ND ND 0.50 J ND ND ND ND 28-May-08 0.3 1.0 Dry 39.3 ND ND ND ND ND ND ND 5-Nov-08 0.30 1.0 Dry 30.8 ND ND ND ND ND ND ND 2-Jun-09 0.30 1.0 ND 28.7 1.2 ND ND ND ND ND ND 19-Nov-09 0.30 1.0 ND ND ND ND 27.2 0.42 J ND ND ND NC21- = 600 pg/L (01/01/10) 15-Jun-10 0.30 1.0 ND 39.0 0.32 J ND ND ND ND ND ND 29-Nov-10 0.30 1.0 ND 27.3 ND ND ND ND ND ND ND 31-May-11 0.30 1.0 ND 23.8 ND ND ND ND ND ND ND 19-Dec-11 0.30 1.0 ND 18.1 ND ND ND ND ND ND ND 30-May-12 0.30 1.0 ND 16.8 ND ND ND ND ND ND ND 3-Dec-12 0.30 1.0 ND 13.9 ND ND ND ND ND ND ND 11-Jun-13 0.30 1.0 ND 27.7 6.5 NS ND ND ND ND ND 29-Oct-13 0.30 1.0 ND 21.5 ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.30 1.0 ND 18.9 ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.30 1.0 ND 16.5 ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.30 1.0 ND 14.2 ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.30 1.0 ND 16.2 0.41 J ND ND ND ND ND ND 2-May-16 EPA 8260 0.30 1.0 ND 22.2 ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.30 1.0 ND 13.9 ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.30 1.0 - 12.7 ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.30 1.0 - 10.5 ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.30 1.0 - 10.5 3.9 ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.30 1.0 - 10.7 ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.45 1.0 - 24.1 ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.26 1.0 - 12.1 ND ND ND ND ND ND -- 6-May-20 EPA 8260D 0.26 1.0 - 17.0 ND ND ND ND ND ND -- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 30 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3 MW-5 MW-6S MW-61) Blanks 2-Hexanone 19-Oct-99 NR 50 ND 80.0 ND ND ND ND NI NI ND 3-May-00 NR 50 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 50 NA ND ND ND ND ND ND ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND ND ND ND ND 5-May-04 NR 50 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 50 ND ND ND ND ND ND ND ND ND GAPS = 280 ug/L (10/23/07) 28-Nov-07 NR 50 ND ND ND ND ND ND ND ND ND 28-May-08 0.46 50.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.46 50.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.46 50.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.46 50.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 0.46 50.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.46 50.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.46 50.0 ND 1.4 J ND ND ND ND ND ND ND 19-Dec-11 0.46 50.0 0.48 J ND ND ND ND 0.81 J ND ND ND 30-May-12 0.46 50.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.46 50.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.46 50.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.46 50.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.46 50.0 ND 1.6 J ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.46 50.0 - ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.46 50.0 - ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.46 50.0 - 2.8 J ND ND ND ND ND ND ND 4-Dec-18 EPA 8260E 0.46 5.0 - ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.89 5.0 - 8 ND ND ND ND ND ND ND 5-Nov-19 EPA8260D 0.57 5.0 - ND ND ND ND ND ND ND - 6-May-20 EPA8260D 0.57 5.0 - ND ND ND ND ND ND ND - Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 31 of 41 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Collection Date Me DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks lodomethane 11-Jun-13 0.32 10.0 ND ND ND NS ND 7.4 J ND ND ND NC21- = NE ug/L (01/01/10) 29-Oct-13 0.32 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.32 10.0 - ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.32 10.0 - ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.32 10.0 - ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260E 0.32 5.0 - ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 3.10 10.0 - ND ND ND ND ND ND ND ND 5-Nov-19 EPA8260D 12.50 20.0 - ND ND ND ND ND ND ND - 6-May-20 EPA8260D 12.50 20.0 - ND ND ND ND ND ND ND - Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 32 of 41 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Methylene chloride 12-May-99 NR 5 ND ND ND ND 5.5 Ni Ni Ni NA 19-Oct-99 NR 10 ND ND ND ND 12.0 B ND NI NI 21.0 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND 10.0 ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND 12.0 ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND NC21- = 4.6 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 2.7 ND ND ND ND 28-May-08 0.97 2.0 Dry ND ND ND ND ND ND ND 1.5 J 5-Nov-08 0.97 2.0 Dry ND ND ND 6.1 B ND ND ND 2.8 2-Jun-09 0.97 2.0 ND ND ND ND 18.8 ND ND ND ND 19-Nov-09 0.97 2.0 ND ND ND ND ND ND ND ND ND NC21- = 5 Ng/L (01/01/10) 15-Jun-10 0.97 2.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.97 1.0 ND ND ND ND 2.9 B ND ND ND 1.2 31-May-11 0.97 1.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.97 1.0 ND ND ND ND 1.4 B ND ND ND 3.3 30-May-12 0.97 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.97 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.97 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.97 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND 2.6 21-Oct-14 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND 4.8 2-May-16 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.97 1.0 - ND ND ND ND ND ND ND 1.3 J 14-Dec-17 EPA 8260 0.97 1.0 - ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.97 1.0 - ND ND ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.97 1.0 - ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.50 1.0 - ND ND 0.63 J ND ND ND ND ND 5-Nov-19 EPA 8260D 3.70 5.0 - ND ND ND ND ND ND ND - 6-May-20 EPA 8260D 3.70 5.0 - ND ND ND ND ND ND ND -- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 33 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-5 MW-6S MW-61) Blanks 2-Butanone (MEK) 28-Apr-94 NR 2000 ND 2500 ND NI NI NI NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND 1200 ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND 490 ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND 250 ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 26.0 J 81.0 J ND ND ND ND ND ND ND NC21- = 4,200 ug/L (10/23/07) 28-Nov-07 NR 100 18.0 p ND ND ND ND ND ND ND ND 28-May-08 0.96 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.96 100 Dry 17.5 J ND ND ND ND ND ND ND 2-Jun-09 0.96 100 ND 56.1 J ND ND ND ND ND ND ND 19-Nov-09 0.96 100 ND ND ND 24.2 J 17.8 J ND 1.5 J ND ND NC21- = 4,000 ug/L (01/01/10) 15-Jun-10 0.96 100 42.3 J 202 ND ND ND ND ND ND 1.4 J 29-Nov-10 0.96 100 60.6 J 1.9 J ND ND ND ND ND ND ND 31-May-11 0.96 100 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.96 100 1.9 J ND ND ND ND ND ND ND ND 30-May-12 0.96 100 8.1 J ND ND ND ND ND ND ND ND 3-Dec-12 0.96 100 2.2 J 29.5 J ND ND ND ND ND ND ND 11-Jun-13 0.96 100 14.0 J 1650 J 4.0 J NS ND ND ND ND ND 29-Oct-13 0.96 100 158 ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.96 100 13.3 J 128 ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.96 100 9.1 J ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.96 100 6.4 J ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.96 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.96 100 ND 60.7 J ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.96 100 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.96 100 - ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.96 100 - ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.96 100 - 268 ND ND ND ND ND ND ND 4-Dec-18 EPA 8260E 0.96 5 - ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 3.20 5 - 448 ND ND ND ND ND ND ND 5-Nov-19 EPA8260D 3.30 5 - 14.8 ND ND ND ND ND ND - 6-May-20 EPA8260D 3.30 5 - 222 ND ND ND ND ND ND - Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 34 of 41 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S M - M MW-5 MW-6S MW-61) Blanks 4-Methyl-2-pentanone (MIBK) 28-Apr-94 NR 500 ND 910 ND NI NI NI NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND 1200 ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND ND ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND 160 ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 ND ND ND ND ND ND ND ND ND GWPS = 560 ug/L (10/23/07) 28-Nov-07 NR 100 ND ND ND ND ND ND ND ND ND 28-May-08 0.33 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.33 100 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.33 100 ND 113 ND ND ND ND ND ND ND 19-Nov-09 0.33 100 ND ND ND ND 2.3 J ND ND ND ND 15-Jun-10 0.33 100 ND 56.0 J 0.88 J ND ND ND ND ND ND 29-Nov-10 0.33 100 ND ND ND ND ND ND ND ND ND 31-May-11 0.33 100 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.33 100 ND ND ND ND ND ND ND ND ND 30-May-12 0.33 100 ND 13.9 J ND ND ND ND ND ND ND 3-Dec-12 0.33 100 ND 1.9 J ND ND ND ND ND ND ND 11-Jun-13 0.33 100 ND 760 J 4.0 J NS ND ND ND ND ND 29-Oct-13 0.33 100 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.33 100 ND 41.4 J 0.44 J ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.33 100 ND 3.3 J ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.33 100 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.33 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.33 100 ND 61.6 J ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.33 100 ND 3.2 J ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.33 100 - ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.33 100 - ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.33 100 - 169 J ND ND ND ND ND ND ND 4-Dec-18 EPA 8260E 0.33 5 - 2.7 J ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.86 5 - 311 ND ND ND ND ND ND ND 5-Nov-19 EPA8260D 4.50 5 - 11.2 ND ND ND ND ND ND - 6-May-20 EPA8260D 4.50 5 - 187 ND ND ND ND ND ND - Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 35 of 41 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Tetrachloroethene 28-Apr-94 NR 5 20.0 ND ND NI NI NI NI NI ND (PCE) 6-Oct-94 NR 5 16.0 ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND 24.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND 21.0 ND ND ND ND 29-May-01 NR 5 NA ND ND ND 15.0 ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND 13.0 ND ND ND ND 21-May-02 NR 5 NA ND ND ND 17.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND 12.0 ND ND ND ND 14-May-03 NR 5 ND ND ND ND 10.0 ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND 10.0 ND ND ND ND 5-May-04 NR 5 ND ND ND ND 12.0 ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND 14.0 ND ND ND ND 25-May-05 NR 5 ND ND ND ND 12.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND 5.0 28.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND 10.2 ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND 7.0 ND ND ND ND 29-May-07 NR 1 ND ND ND 1.9 11.0 ND ND ND ND NC21- = 0.7 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND 1.2 13.0 ND ND ND ND 28-May-08 0.46 1.0 Dry ND ND 1.6 10.3 ND ND ND ND 5-Nov-08 0.46 1.0 Dry ND ND 1.6 13.1 ND ND ND ND 2-Jun-09 0.46 1.0 1.7 ND ND 1.2 9.1 ND ND ND ND 19-Nov-09 0.46 1.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 0.46 1.0 ND ND ND 0.79 J 4.8 ND ND ND ND 29-Nov-10 0.46 1.0 ND ND ND ND 11.0 ND ND ND ND 31-May-11 0.46 1.0 ND ND ND 0.75 J 6.2 ND ND ND ND 19-Dec-11 0.46 1.0 ND ND ND 0.95 J 8.4 ND ND ND ND 30-May-12 0.46 1.0 ND ND ND 1.3 4.7 ND ND ND ND 3-Dec-12 0.46 1.0 ND ND ND 1.8 3.2 ND ND ND ND 11-Jun-13 0.46 1.0 ND ND ND NS 2.6 ND ND ND ND 29-Oct-13 0.46 1.0 ND ND ND 3.5 3.3 ND ND ND ND 6-May-14 EPA 8260 0.46 1.0 ND ND ND 3.8 3.0 ND ND ND ND 21-Oct-14 EPA 8260 0.46 1.0 ND ND ND 3.9 5.9 ND ND ND ND 19-May-15 EPA 8260 0.46 1.0 ND ND ND 4.6 3.7 ND ND ND ND 7-Dec-15 EPA 8260 0.46 1.0 ND ND ND 3.5 1.9 ND ND ND ND 2-May-16 EPA 8260 0.46 1.0 ND ND ND 4.5 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.46 1.0 ND ND ND 4.7 2.1 ND ND ND ND 26-Jun-17 EPA 8260 0.46 1.0 - ND ND 5.7 1.7 ND ND ND ND 14-Dec-17 EPA 8260 0.46 1.0 - ND ND 5.0 2.0 ND ND ND ND 14-May-18 EPA 8260 0.46 1.0 - ND ND 5.6 1.3 ND ND ND ND 4-Dec-18 EPA 8260B 0.46 1.0 - ND ND 6.6 1.2 ND ND ND ND 6-May-19 EPA 8260D 0.78 1.0 - ND ND 11.1 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.16 1.0 - ND ND 6.5 1.8 ND ND ND -- 6-May-20 EPA 8260D 0.16 1.0 - ND ND 8.1 0.69 J ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 36 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Me DL RL MW-1 MW-2 MW-3 MW-5 MW-6S MW-6D Blanks Toluene 28-Apr-94 NR 5 ND 55.0 10.0 NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND 5.6 ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND 2.8 0.39 B 0.26 B ND ND ND ND 0.52 J NC21- = 1,000 pg/L (10/23/07) 28-Nov-07 NR 1 ND 1.7 ND ND ND ND ND ND ND 28-May-08 0.26 1.0 Dry 2.0 0.35 J ND ND ND ND ND ND 5-Nov-08 0.26 1.0 Dry 1.5 0.44 J ND ND ND ND ND ND 2-Jun-09 0.26 1.0 ND 2.3 0.51 J ND ND ND ND ND ND 19-Nov-09 0.26 1.0 ND ND ND ND 1.6 0.26 J ND ND ND NC21- = 600 pg/L (01/01/10) 15-Jun-10 0.26 1.0 ND 2.4 ND ND ND ND ND ND ND 29-Nov-10 0.26 1.0 ND 1.6 ND ND ND ND ND ND ND 31-May-11 0.26 1.0 ND 1.5 ND ND ND ND ND ND ND 19-Dec-11 0.26 1.0 ND 1.9 ND ND ND ND ND ND ND 30-May-12 0.26 1.0 ND 1.4 0.38 J ND ND ND ND ND ND 3-Dec-12 0.26 1.0 ND 1.0 J 0.27 J ND ND ND ND ND ND 11-Jun-13 0.26 1.0 ND 4.1 2.7 NS ND ND ND ND ND 29-Oct-13 0.26 1.0 ND 1.3 ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.26 1.0 ND 1.6 ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.26 1.0 ND 1.3 ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.26 1.0 ND 1.2 ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.26 1.0 ND 1.6 0.52 J ND ND ND ND ND - 2-May-16 EPA 8260 0.26 1.0 ND 2.4 ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.26 1.0 ND 1.2 ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.26 1.0 - 1.2 0.27 J ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.26 1.0 - 1.1 ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.26 1.0 - 1.7 J 0.48 J ND ND ND ND ND ND 4-Dec-18 EPA 8260E 0.26 1.0 - 0.9 J ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.31 1.0 - 4.8 ND ND ND ND ND ND ND 5-Nov-19 EPA8260D 0.24 1.0 - 1.1 ND ND ND ND ND ND - 6-May-20 EPA8260D 0.24 1.0 - 2.5 ND ND ND ND ND ND - Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 37 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Trichloroethene 28-Apr-94 NR 5 11.0 ND ND NI NI NI NI NI ND (TCE) 6-Oct-94 NR 5 9.3 ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND 12.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND 12.0 ND ND ND ND 29-May-01 NR 5 NA ND ND ND 8.6 ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND 11.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND 10.0 ND ND ND ND 14-May-03 NR 5 ND ND ND ND 7.5 ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND 7.1 ND ND ND ND 5-May-04 NR 5 ND ND ND ND 8.0 ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND 10.0 ND ND ND ND 25-May-05 NR 5 ND ND ND ND 6.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND 6.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 2.4 ND ND 2.6 8.3 ND ND ND ND NC21- = 2.8 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 12.0 ND ND ND ND 28-May-08 0.47 1 Dry ND ND 1.0 10.0 ND ND ND ND 5-Nov-08 0.47 1.0 Dry ND ND 1.1 9.7 ND ND ND ND 2-Jun-09 0.47 1.0 2.4 ND ND 1.4 7.9 ND ND ND ND 19-Nov-09 0.47 1.0 ND ND ND ND ND ND ND ND ND NC21- = 3 pg/L (01/01/10) 15-Jun-10 0.47 1.0 0.56 J ND ND 2.2 2.9 ND ND ND ND 29-Nov-10 0.47 1.0 ND ND ND 2.5 5.7 ND ND ND ND 31-May-11 0.47 1.0 ND ND ND 2.3 3.9 ND ND ND ND 19-Dec-11 0.47 1.0 1.4 ND ND 3.0 5.2 ND ND ND ND 30-May-12 0.47 1.0 0.49 J ND ND 2.8 2.4 ND ND ND ND 3-Dec-12 0.47 1.0 ND ND ND 2.5 1.4 ND ND ND ND 11-Jun-13 0.47 1.0 ND ND ND NS 1.1 ND ND ND ND 29-Oct-13 0.47 1.0 ND ND ND 2.6 1.4 ND ND ND ND 6-May-14 EPA 8260 0.47 1.0 ND ND ND 2.8 ND ND ND ND ND 21-Oct-14 EPA 8260 0.47 1.0 ND ND ND 2.6 2.6 ND ND ND ND 19-May-15 EPA 8260 0.47 1.0 ND ND ND 3.0 1.4 ND ND ND ND 7-Dec-15 EPA 8260 0.47 1.0 ND ND ND 2.5 0.62 J ND ND ND ND 2-May-16 EPA 8260 0.47 1.0 ND ND ND 3.3 ND ND ND ND ND 12-Dec-16 EPA 8260 0.47 1.0 ND ND ND 3.5 1.3 ND ND ND ND 26-Jun-17 EPA 8260 0.47 1.0 - ND ND 3.3 0.76 J ND ND ND ND 14-Dec-17 EPA 8260 0.47 1.0 - ND ND 3.7 0.86 J ND ND ND ND 14-May-18 EPA 8260 0.47 1.0 - ND ND 3.6 0.52 J ND ND ND ND 4-Dec-18 EPA 8260B 0.47 1.0 - ND ND 4.7 0.66 J ND ND ND ND 6-May-19 EPA 8260D 0.34 1.0 - ND ND 5.9 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.22 1.0 - ND ND 4.8 0.72 J ND ND ND - 6-May-20 EPA 8260D 0.22 1.0 - ND ND 5.0 ND ND ND ND -- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 38 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Vinyl Chloride 28-Apr-94 NR 10 ND ND ND Ni Ni Ni Ni Ni ND 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 2.6 ND ND 2.7 0.52 J ND ND ND ND NC21- = 0.015 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND 1.8 1.9 ND ND ND ND 28-May-08 0.62 1.0 Dry ND ND 2.4 1.5 ND ND ND ND 5-Nov-08 0.62 1.0 Dry ND ND 2.1 1.9 ND ND ND ND 2-Jun-09 0.62 1.0 1.9 ND ND 2.4 0.80 J ND ND ND ND 19-Nov-09 0.62 1.0 ND ND ND 1.3 ND ND ND ND ND NC21- = 0.03 pg/L (01/01/10) 15-Jun-10 0.62 1.0 1.4 ND ND 2.3 ND ND ND ND ND 29-Nov-10 0.62 1.0 0.73 J ND ND 2.5 0.73 J ND ND ND ND 31-May-11 0.62 1.0 0.66 J ND ND 2.2 ND ND ND ND ND 19-Dec-11 0.62 1.0 2.8 ND ND 1.9 ND ND ND ND ND 30-May-12 0.62 1.0 1.2 ND ND 1.6 ND ND ND ND ND 3-Dec-12 0.62 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.62 1.0 1.7 ND ND NS ND ND ND ND ND 29-Oct-13 0.62 1.0 0.64 J ND ND 0.99 J ND ND ND ND ND 6-May-14 EPA 8260 0.62 1.0 ND ND ND 1.1 ND ND ND ND ND 21-Oct-14 EPA 8260 0.62 1.0 ND ND ND 0.91 J ND ND ND ND ND 19-May-15 EPA 8260 0.62 1.0 ND ND ND 0.89 J ND ND ND ND ND 7-Dec-15 EPA 8260 0.62 1.0 ND ND ND 1.1 ND ND ND ND ND 2-May-16 EPA 8260 0.62 1.0 ND ND ND 0.62 J ND ND ND ND ND 12-Dec-16 EPA 8260 0.62 1.0 ND ND ND 0.88 J ND ND ND ND ND 26-Jun-17 EPA 8260 0.62 1.0 - ND ND 1.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.62 1.0 - ND ND 1.1 ND ND ND ND ND 14-May-18 EPA 8260 0.62 1.0 - ND ND 1.0 ND ND ND ND ND 4-Dec-18 EPA 8260B 0.62 1.0 - ND ND 1.2 ND ND ND ND ND 6-May-19 EPA 8260D 0.60 1.0 - ND ND 1.4 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.24 1.0 - ND ND ND ND ND ND ND - 6-May-20 EPA 8260D 0.24 1.0 - ND ND 0.88 J ND ND ND ND -- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 39 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Xylene (Total) 28-Apr-94 NR 5 6.2 330 80.0 NI Ni Ni Ni Ni ND 3-May-00 NR 5 NA 120 34.0 ND ND ND ND ND ND 8-Nov-00 NR 5 120 7.2 ND ND ND ND ND ND NA 29-May-01 NR 5 NA 177 20 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 125 7.6 ND ND ND ND ND ND 21-May-02 NR 5 NA 149 18.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 126 21.0 ND ND ND ND ND ND 14-May-03 NR 5 7.0 222 65.9 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 107 29.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 90.0 41.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 106 41.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 152 46.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 209 39.0 ND ND ND ND ND ND 24-May-06 NR 10 ND 82.8 22.5 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 118 14.0 ND ND ND ND ND ND 29-May-07 NR 4 1.1 J 120 37.0 ND ND ND ND ND ND NC21- = 530 pg/L (10/23/07) 28-Nov-07 NR 5 ND 71.0 5.7 ND 2.0 J ND ND ND ND 28-May-08 0.89 5 Dry 76.1 14.4 ND 1.3 J ND ND ND ND 5-Nov-08 0.66 5 Dry 58.5 4.1 ND 2.5 ND ND ND ND 2-Jun-09 0.66 5 ND 56.5 24.6 ND 0.76 J ND ND ND ND 19-Nov-09 0.66 2.0 ND ND ND ND 50.6 29.4 ND ND ND NC21- = 500 pg/L (01/01/10) 15-Jun-10 0.66 2.0 ND 78.1 24.7 ND ND ND ND ND ND 29-Nov-10 0.66 2.0 ND 46.3 12.9 ND 0.72 J ND ND ND ND 31-May-11 0.66 2.0 ND 45.0 15.9 ND ND ND ND ND ND 19-Dec-11 0.66 2.0 ND 39.3 14.0 ND 0.74 J ND ND ND ND 30-May-12 0.66 2.0 ND 30.2 24.5 ND ND ND ND ND ND 3-Dec-12 0.66 2.0 ND 23.7 12.6 ND ND ND ND ND ND 11-Jun-13 0.66 5.0 ND 67.7 59.4 NS ND ND ND ND ND 29-Oct-13 0.66 5.0 ND 33.8 23.1 ND ND ND ND ND ND 6-May-14 EPA 8260 0.66 5.0 ND 42.7 32.6 ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.66 5.0 ND 37.1 15.4 ND ND ND ND ND ND 19-May-15 EPA 8260 0.66 5.0 ND 32.5 25.4 ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.66 5.0 ND 38.6 23.1 ND ND ND ND ND ND 2-May-16 EPA 8260 0.66 5.0 ND 43.2 21.1 ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.66 5.0 ND 31.3 8.10 ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.66 5.0 - 28.0 15.20 ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.66 5.0 - 23.3 16.90 ND ND ND ND ND ND 14-May-18 EPA 8260 0.66 5.0 - 21.8 51.60 ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.66 1.0 - 21.4 28.00 ND ND ND ND ND ND 6-May-19 EPA 8260D 1.50 2.0 - 55.8 17.7 ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.63 1.0 - 22.3 14.3 ND ND ND ND ND - 6-May-20 EPA 8260D 0.63 1.0 - 34.0 15.1 ND ND ND ND ND -- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 40 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Me DL RL MW-1 MW-2 MW-3S MW-3D INEff MW-5 MW-6S MW-6D Blanks 1,1,2-Trichloroethane 11-Jun-13 0.29 1.0 ND 0.79 J ND INS ND ND ND ND ND GWPS = 0.6 Ng/L (10/23/07) 29-Oct-13 0.29 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.29 1.0 - ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.29 1.0 - ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.58 2.0 - ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260E 0.29 1.0 - ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.59 1.0 - ND ND ND ND ND ND ND ND 5-Nov-19 EPA8260D 0.24 1.0 - ND ND ND ND ND ND ND - 6-May-20 EPA8260D 0.24 1.0 - ND ND ND ND ND ND ND - Notes: RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present). DL = Laboratory Detection Limit. ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006). NA = No data available. NI = Not installed. NS = Not sampled. NR = Not reported. NE = Not established. J = Estimated concentration less than the RL but above the DL. B = Blank -Qualified Concentration (suspected to reflect laboratory or field contamination). NC21- = North Carolina Groundwater Standards from 15A NCAC 2L.0202. GWPS = Groundwater Protection Standards established by the SWS for constituents with no listed NC21- standard (no longer used). IMAC = Interim Maximum Allowable Concentration. Bold values are greater than the NC2L, GWPS, or IMAC. Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 41 of 41 Labelle Associates TABLE A2-3: Historical Groundwater Field Parameters Parameter Collection Date Upgradient Downgradient MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Well Depth [ft] - 50.55 45.70 26.69 78.40 29.50 49.80 25.00 60.00 Conductivity (at 25c) 11-Jun-13 233.1 1168.0 847 -- 56.9 14.2 62.8 74.1 [mS/cm] 28-Oct-13 326.9 1721.0 107.8 702 52.3 17.9 46.2 87.1 5-May-14 214.0 1161.0 828 687 70.6 28.8 65.3 102.3 20-Oct-14 376.0 1891.0 841 793 161.1 24.7 70.2 120.1 18-May-15 232.0 2160.0 878 823 99 19 66 106 7-Dec-15 273.0 2102.0 902 833 108 24 84 112 2-May-16 246.7 1873.0 936 746 69.8 18.4 64.9 86 12-Dec-16 176.7 2059.0 767 793 111 24.6 66.6 115.9 26-Jun-17 -- 1937.0 791 791 100.4 24.1 72 107 14-Dec-17 2185.0 920 875 99 25 97 114 14-May-18 1658.0 1117 923 131 22.2 118 59 4-Dec-18 1604.0 776 661 70 48 64.3 92.8 Resample-> 8-Feb-19 -- -- -- 55.9 -- -- -- 6-May-19 1923 916 792 59.6 23.3 50.6 85.6 Resample-> 23-Jul-19 -- -- 1454 -- -- -- -- 4-Nov-19 -- 2225 831 853 92.1 18.3 59.3 90 6-May-20 2226 913 842 59 19.2 80.4 101.5 Resample-> 16-Jul-20 -- -- -- -- 16.6 -- -- pH 11-Jun-13 5.9 6.1 6.36 -- 5.36 5.54 5.3 6.27 [standard units] 28-Oct-13 5.7 6.1 6.42 6.22 5.47 6.64 5.8 6.3 5-May-14 6.4 6.6 7.18 7.2 6.43 6.52 6.84 6.88 20-Oct-14 6.0 6.1 6.38 6.61 6.3 5.59 5.56 6.39 18-May-15 5.8 5.9 6.24 5.99 5.34 4.92 5.65 6.18 7-Dec-15 6.2 6.0 6.3 6.03 5.42 5.66 5.68 6.29 2-May-16 5.5 5.9 5.84 6.09 5.37 5.81 5.61 5.9 12-Dec-16 6.2 6.2 6.5 6.38 5.62 6.28 5.51 5.99 26-Jun-17 -- 5.9 6.19 6.21 5.3 6.92 5.35 5.31 14-Dec-17 6.2 6.44 6.47 5.84 5.47 5.9 6.63 14-May-18 6.2 6.65 6.4 6.11 5.72 6.1 6.76 4-Dec-18 6.0 6.55 6.55 6.54 8.07 7.21 6.15 Resample-> 8-Feb-19 -- -- -- 5.64 -- -- -- 6-May-19 6.01 6.49 6.17 6.66 5.86 6.56 6.08 Resample-> 23-Jul-19 -- -- 6.00 -- -- -- -- 4-Nov-19 5.64 5.94 6.15 5.43 5.49 5.28 5.54 6-May-20 6 6.35 6.59 5.66 5.47 5.8 6.44 Resample-> 16-Jul-20 -- -- -- -- 5.55 -- -- Burke County, Kirksey Drive Landfill La Bella Associates Permit No. 12-01 1 of 2 TABLE A2-3: Historical Groundwater Field Parameters Temperature 11-Jun-13 17.0 17.4 15.2 -- 15.9 16.4 14 15.4 [ ° C] 28-Oct-13 15.9 16.0 16.6 15.8 15.3 15.1 15.7 15.7 5-May-14 16.4 17.9 15.4 16.7 16.7 16.2 14.6 15.6 20-Oct-14 14.5 15.0 16.3 15.2 12.7 15.0 14.5 13.2 18-May-15 22.5 17.1 15.7 16.1 17.3 21.0 16.1 17.1 7-Dec-15 14.7 16.1 15.9 15.7 14.9 14.6 15.7 14.9 2-May-16 17.7 16.8 15.7 17.0 16.8 17.0 14 15.6 12-Dec-16 15.0 15.9 16.6 15.6 15.2 15.5 15.6 14.8 26-Jun-17 -- 17.4 17.1 16.5 16 17.2 14.6 15 14-Dec-17 16.4 15.7 13.4 14.8 14.7 14.3 10.9 14-May-18 19.3 14.4 15.4 18.1 18.5 18.8 19.3 4-Dec-18 15.3 14.6 13.9 14 14 13.3 14.5 Resample-> 8-Feb-19 -- -- -- 15.2 -- -- -- 6-May-19 17.3 15.4 17.0 16.1 17.4 15.1 15.5 Resample-> 23-Jul-19 -- -- 17.3 -- -- -- -- 4-Nov-19 15.1 13 16.4 14.7 15.3 16.4 16.4 6-May-20 16 16 16.7 14.6 16 13.3 14.2 Resample-> 16-Jul-20 -- -- -- -- 20.9 -- -- Dissolved Oxygen 6-May-19 0.92 3.59 1.09 5.18 5.73 5.44 2.13 [mg/L] 23-Jul-19 -- -- 0.91 -- -- -- -- 4-Nov-19 1.63 1.85 4.39 3.99 4.36 3.55 2.89 6-May-20 5.06 4.71 5.14 6.7 1.85 5.74 4.33 Resample-> 16-Jul-20 -- -- -- -- 7.37 -- -- Oxidation Reduction Potential 6-May-19 14.1 -4.6 222.3 165.4 235.3 183.1 126.9 [mv] 23-Jul-19 -- -- 210.5 -- -- -- -- 4-Nov-19 -- 33.3 85.4 180.3 199 146.4 208.3 -81.6 6-May-20 218.2 272.5 323 192.5 300.9 192 201.5 Resample-> 16-Jul-20 -- -- -- -- 282.3 -- -- Turbidity 11-Jun-13 27.4 4.50 3.65 -- 4.14 12.72 7.62 3.84 [NTU] 28-Oct-13 7.86 10.05 8.42 4.31 12.91 6.81 6.08 5.91 5-May-14 13.90 9.25 18.12 7.68 24.30 6.99 6.98 10.55 20-Oct-14 10.50 6.13 11.75 6.03 4.89 7.67 25.10 4.82 18-May-15 15.30 4.09 6.14 4.65 21.10 15.30 14.60 5.57 7-Dec-15 21.90 3.93 7.11 5.15 17.70 13.33 26.10 6.71 2-May-16 12.55 4.44 4.05 7.05 19.85 22.06 24.80 25.75 12-Dec-16 13.12 9.29 7.33 6.75 4.45 8.11 3.39 1.38 26-Jun-17 -- 7.55 7.15 6.15 9.15 12.13 6.58 6.87 14-Dec-17 10.05 4.75 2.26 12.01 20.15 12.75 5.21 14-May-18 2.79 0.24 0.00 20.90 36.92 3.30 0.00 4-Dec-18 8.39 29.40 4.31 31.00 10.30 6.71 4.17 Resample-> 8-Feb-19 -- -- -- 7.96 -- -- -- 6-May-19 5.29 11.5 0.65 5.71 17.8 22.1 5.08 Resample-> 23-Jul-19 -- -- 3.12 -- -- -- -- 4-Nov-19 4.79 9 3.01 35.17 41.15 8.49 30.39 6-May-20 8.25 8.12 12.17 97.58 356.5 79.08 3.74 Resample-> 16-Jul-20 -- -- -- -- 13.23 -- -- Notes: oC= degrees Centigrade mg/L = milligrams per liter S.U.= Standard Units my = millivolts uS = microsemens per cm NTU = Nephelometric Turbidity Units ft = feet Burke County, Kirksey Drive Landfill La Bella Associates Permit No. 12-01 2 of 2 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks INORGANICS Arsenic 25-Oct-95 NR 5 ND ND 10.00 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 5 ND ND ND NA 12-May-97 NR 5 ND ND ND NA 19-Nov-97 NR 5 ND ND ND NA 27-May-98 NR 5 ND ND ND NA 24-Nov-98 NR 5 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND ND ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND 3.10 J Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 2.6 10.0 ND ND Dry ND 5-Nov-08 2.7 10.0 ND ND Dry 4.80 J 2-Jun-09 2.7 10.0 ND ND ND ND 19-Nov-09 2.7 10.0 ND ND ND ND NUB = 10 ug/L (05/01/2007) 14-Jun-10 2.7 10.0 ND ND Dry ND 29-Nov-10 2.7 10.0 ND ND Dry ND 31-May-11 2.7 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 5.0 10.0 ND ND ND ND 14-Dec-17 5.0 10.0 ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 ND ND ND ND 4-Dec-18 EPA 6010D 5.0 10.0 ND ND ND ND 6-May-19 EPA 6010D 5.0 10.0 ND ND 5.2 J ND 5-Nov-19 EPA 6010D 5.0 10.0 ND ND ND --- 6-May-20 EPA 6010D 4.7 10.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 1 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Barium 28-Apr-94 NR 100 ND ND 550.00 NA 6-Oct-94 NR 100 ND ND 356.00 NA 28-Jun-95 NR 100 ND ND 32.00 NA 25-Oct-95 NR 100 ND ND 301.00 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 100 ND ND 540.00 NA 12-May-97 NR 100 ND ND 480.00 NA 19-Nov-97 NR 100 ND ND 400.00 NA 27-May-98 NR 100 ND 2000.00 500.00 NA 24-Nov-98 NR 100 ND ND 430.00 NA 12-May-99 NR 10 32.00 30.00 370.00 ND 19-Oct-99 NR 500 ND ND NA ND 3-May-00 NR 500 ND ND ND ND 8-Nov-00 NR 500 ND ND ND ND 29-May-01 NR 500 ND ND ND ND 6-Nov-01 NR 500 ND ND ND ND 21-May-02 NR 500 ND ND ND ND 13-Nov-02 NR 500 ND ND ND ND 14-May-03 NR 500 ND ND ND ND 19-Nov-03 NR 500 ND ND ND ND 5-May-04 NR 500 ND ND ND ND 9-Nov-04 NR 500 ND ND ND ND 25-May-05 NR 500 ND ND Dry ND 2-Nov-05 NR 500 ND ND Dry ND 24-May-06 NR 500 ND ND Dry ND 1-Nov-06 NR 500 ND ND ND ND 29-May-07 NR 100 33.60 J 35.20 J Dry ND 28-Nov-07 NR 100 31.90 J 32.30 J Dry 0.30 J 28-May-08 0.2 100 40.20 J 40.40 J Dry 0.33 J 5-Nov-08 0.20 100 33.80 B 35.00 B Dry 10.50 J 2-Jun-09 0.20 100 29.60 B 32.60 B 320.00 15.20 J 19-Nov-09 0.20 100 36.30 B 41.20 B 364.00 19.80 J NC2B = 1,000 pg/L (05/01/2007) 14-Jun-10 0.20 100 31.00 B 32.50 B Dry 26.30 J 29-Nov-10 0.20 100 28.20 J 29.00 J Dry ND 31-May-11 0.20 100 30.10 J 29.90 J Dry ND 19-Dec-11 5.0 100 32.40 J 41.40 J 558.00 ND 30-May-12 5.0 100 33.10 J 33.70 J 34.20 J ND 3-Dec-12 5.0 100 31.00 J 28.90 J ND ND 11-Jun-13 5.0 100 43.80 B 45.70 B 261.00 13.70 J 29-Oct-13 5.0 100 31.40 J 33.10 J Dry ND 5-May-14 EPA 6010 5.0 100 31.00 J 33.10 J 301.00 ND 21-Oct-14 EPA 6010 5.0 100 33.60 J 34.30 J 343.00 ND 19-May-15 EPA 6010 2.5 100 33.60 J 34.10 J Dry NA 7-Dec-15 EPA 6010 2.5 100 36.50 J 37.80 J 350.00 ND 2-May-16 EPA 6010 2.5 100 32.50 J 32.90 J 766.00 ND 12-Dec-16 EPA 6010 2.5 100 22.80 J 82.10 J NS ND 26-Jun-17 EPA 6010 2.5 100 38.10 J 38.00 J 301.00 2.50 J 14-Dec-17 2.5 100 36.00 J 36.80 J 282.00 ND 14-May-18 EPA 6010 2.5 100 32.90 J 33.50 J 32.90 J ND 4-Dec-18 EPA 6010D 2.5 5 33.10 32.00 267.00 ND 6-May-19 EPA 6010D 2.5 5 26.40 26.20 239.00 ND 5-Nov-19 EPA 6010D 2.5 5 34.50 35.90 34.80 --- 6-May-20 EPA 6010D 3.5 5 31.90 28.70 32.30 --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 2 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Cadmium 28-Jun-95 NR 1 2.00 2.00 4.00 NA 25-Oct-95 NR 1 1.00 ND 1.00 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 1 ND ND ND NA 12-May-97 NR 1 ND ND ND NA 19-Nov-97 NR 1 ND ND ND NA 27-May-98 NR 1 ND ND ND NA 24-Nov-98 NR 1 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 1 ND ND NA ND 3-May-00 NR 1 ND ND ND ND 8-Nov-00 NR 1 ND ND ND ND 29-May-01 NR 1 ND ND ND ND 6-Nov-01 NR 1 ND ND ND ND 21-May-02 NR 1 ND ND ND ND 13-Nov-02 NR 1 ND ND ND ND 14-May-03 NR 1 ND ND ND ND 19-Nov-03 NR 1 ND ND ND ND 5-May-04 NR 1 ND ND ND ND 9-Nov-04 NR 1 ND ND ND ND 25-May-05 NR 1 ND ND Dry ND 2-Nov-05 NR 1 ND ND Dry ND 24-May-06 NR 1 ND ND Dry ND 1-Nov-06 NR 1 ND ND ND ND 29-May-07 NR 1 ND ND Dry ND 28-Nov-07 NR 1 ND ND Dry ND 28-May-08 0.5 1.0 ND ND Dry ND 5-Nov-08 0.50 1.0 ND ND Dry ND 2-Jun-09 0.50 1.0 ND ND ND ND 19-Nov-09 0.50 1.0 ND ND ND ND NC2B = 2 pg/L (05/01/2007) 14-Jun-10 0.50 1.0 ND ND Dry ND 29-Nov-10 0.50 1.0 ND ND Dry ND 31-May-11 0.50 1.0 ND ND Dry ND 19-Dec-11 1.0 1.0 ND ND ND ND 30-May-12 1.0 1.0 ND ND ND ND 3-Dec-12 1.0 1.0 ND ND ND ND 11-Jun-13 1.0 1.0 ND ND ND ND 29-Oct-13 1.0 1.0 ND ND Dry ND 5-May-14 EPA 6010 1.0 1.0 ND ND ND ND 21-Oct-14 EPA 6010 1.0 1.0 ND ND ND ND 19-May-15 EPA 6010 0.5 1.0 ND ND Dry NA 7-Dec-15 EPA 6010 0.5 1.0 ND ND ND ND 2-May-16 EPA 6010 0.5 1.0 ND ND ND ND 12-Dec-16 EPA 6010 0.5 1.0 ND ND NS ND 26-Jun-17 EPA 6010 0.5 1.0 ND ND ND ND 14-Dec-17 0.5 1.0 ND ND ND ND 14-May-18 EPA 6010 0.5 1.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 0.5 1.0 ND ND ND ND 6-May-19 EPA 6O1OD 0.5 1.0 ND ND ND ND 5-Nov-19 EPA 6O1OD 0.5 1.0 ND ND ND --- 6-May-20 EPA 6O1OD 0.4 1.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 3 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Chromium 12-May-97 NR 1 2.00 1.00 2.00 NA 19-Nov-97 NR 1 ND ND ND NA 27-May-98 NR 1 ND ND ND NA 24-Nov-98 NR 1 ND ND 1.00 NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND 12.00 ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 24.00 22.00 24.00 ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND ND Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.4 10.0 0.87 J 1.00 J Dry 0.85 J 5-Nov-08 0.40 10.0 0.76 J 0.76 J Dry ND 2-Jun-09 0.40 10.0 0.45 J 0.48 J 4.70 J ND 19-Nov-09 0.40 10.0 0.67 B 0.66 B 2.20 B 1.10 J NC2B = 20 ug/L (05/01/2007) 14-Jun-10 0.40 10.0 0.75 J 1.00 J Dry ND 29-Nov-10 0.40 10.0 ND 0.80 J Dry ND 31-May-11 0.40 10.0 1.20 B 0.84 B Dry 0.73 J 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND 7.4 J ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND 6.3 J ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND 3.3 J ND 2-May-16 EPA 6010 2.5 10.0 ND ND 3.8 J ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND 7.7 J ND 14-Dec-17 2.5 10.0 ND ND 4.6 J ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 2.5 5.0 ND ND 2.8 J ND 6-May-19 EPA 6O1OD 2.5 5.0 ND ND 4.4 J ND 5-Nov-19 EPA 6O1OD 2.5 5.0 ND ND ND --- 6-May-20 EPA 6O1OD 3.7 5.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 4 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Cobalt 28-Jun-95 NR 10 ND ND 13.00 NA 25-Oct-95 NR 10 ND ND 12.00 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 10 ND ND 20.00 NA 12-May-97 NR 6 ND ND 11.00 NA 19-Nov-97 NR 5 ND ND 13.00 NA 27-May-98 NR 1 2.00 ND 13.00 NA 24-Nov-98 NR 1 ND ND 11.00 NA 12-May-99 NR 10 ND ND 6.90 ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND 23.00 ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND ND Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.6 10.0 ND ND Dry ND 5-Nov-08 0.60 10.0 4.00 B 3.40 B Dry 3.50 J 2-Jun-09 0.60 10.0 4.80 B 7.00 B 8.60 B 3.30 J 19-Nov-09 0.60 10.0 ND ND 1.10 J ND NC2B = NE (05/01/2007) 14-Jun-10 0.60 10.0 ND ND Dry ND 29-Nov-10 0.60 10.0 ND ND Dry ND 31-May-11 0.60 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND 7.9 J ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND 6 J ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND 9.6 J NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND 7.5 J ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 ND ND 3.6 J ND 6-May-19 EPA 6010D 2.5 5.0 ND ND 4.2 J ND 5-Nov-19 EPA 6010D 2.5 5.0 ND ND ND --- 6-May-20 EPA 6010D 3.6 5.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 5 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Copper 28-May-08 0.3 10 2.10 J 2.20 J Dry 0.38 J 5-Nov-08 0.30 10 1.40 B 0.71 B Dry 0.94 J 2-Jun-09 0.30 10 ND ND 1.80 J ND 19-Nov-09 0.30 10 1.50 J 1.90 J 1.90 J ND NC2B = 7 pg/L (05/01/2007)* 14-Jun-10 0.30 10 0.95 J 1.10 J Dry ND 29-Nov-10 0.30 10 ND 0.39 J Dry ND 31-May-11 0.30 10 ND 1.30 J Dry ND 19-Dec-11 5.0 10 ND ND 8.60 J ND 30-May-12 5.0 10 ND ND ND ND 3-Dec-12 5.0 10 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND 10.80 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND 5.5 J ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND 6.4 J ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND 3.0 J ND 2-May-16 EPA 6010 2.5 10.0 ND ND 12.1 * ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND 6.4 J ND 14-Dec-17 2.5 10.0 ND ND 4.7 J ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 2.5 5.0 ND ND ND ND 6-May-19 EPA 6O1OD 2.5 5.0 ND ND ND ND 5-Nov-19 EPA 6O1OD 2.5 5.0 ND ND ND --- 6-May-20 EPA 6O1OD 4.3 5.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 6 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Lead 28-Apr-94 NR 1 1.00 ND ND NA 6-Oct-94 NR 5 ND ND ND NA 28-Jun-95 NR 5 ND ND ND NA 25-Oct-95 NR 5 ND ND ND NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 5 ND ND ND NA 12-May-97 NR 5 ND ND ND NA 19-Nov-97 NR 5 ND ND ND NA 27-May-98 NR 5 ND ND ND NA 24-Nov-98 NR 5 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND ND ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 16.0 14.0 16.0 ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 2.3 B 2.5 B Dry 6.1 J 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 4 10.0 ND ND Dry ND 5-Nov-08 4.0 10.0 ND ND Dry ND 2-Jun-09 4.0 10.0 ND ND ND ND 19-Nov-09 4.0 10.0 ND ND ND ND NC2B = 25 pg/L (05/01/2007) 14-Jun-10 4.0 10.0 ND ND Dry ND 29-Nov-10 4.0 10.0 ND ND Dry ND 31-May-11 4.0 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND ND ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 4.1 J ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 ND ND ND ND 5-Nov-19 EPA 6010D 2.5 5.0 ND ND ND --- 6-May-20 EPA 6010D 4.5 5.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 7 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Nickel 12-May-99 NR 5 ND ND 5.60 ND 19-Oct-99 NR 50 ND ND NA ND 3-May-00 NR 50 ND ND ND ND 8-Nov-00 NR 50 ND ND ND ND 29-May-01 NR 50 ND ND ND ND 6-Nov-01 NR 50 ND ND ND ND 21-May-02 NR 50 ND ND ND ND 13-Nov-02 NR 50 ND ND ND ND 14-May-03 NR 50 ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND 5-May-04 NR 50 ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND 25-May-05 NR 50 ND ND Dry ND 2-Nov-05 NR 50 ND ND Dry ND 24-May-06 NR 50 ND ND Dry ND 1-Nov-06 NR 50 ND ND ND ND 29-May-07 NR 50 ND ND Dry ND 28-Nov-07 NR 50 ND ND Dry ND 28-May-08 1.7 50.0 ND ND Dry ND 5-Nov-08 1.7 50.0 ND ND Dry 2.20 J 2-Jun-09 1.7 50.0 ND ND 9.40 J ND 19-Nov-09 1.7 50.0 ND ND 4.60 B 2.20 J NC2B = 25 ug/L (05/01/2007) 14-Jun-10 1.7 50.0 ND ND Dry ND 29-Nov-10 1.7 50.0 ND ND Dry ND 31-May-11 1.7 50.0 ND ND Dry 2.30 J 19-Dec-11 5.0 50.0 ND ND 10.2 J ND 30-May-12 5.0 50.0 ND ND ND ND 3-Dec-12 5.0 50.0 ND ND ND ND 11-Jun-13 5.0 50.0 ND ND 5.8 J ND 29-Oct-13 5.0 50.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 50.0 ND ND 9.6 J ND 21-Oct-14 EPA 6010 5.0 50.0 ND ND 10.4 J ND 19-May-15 EPA 6010 2.5 50.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 50.0 ND ND 5.1 J ND 2-May-16 EPA 6010 2.5 50.0 ND ND 10.2 J ND 12-Dec-16 EPA 6010 2.5 50.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 50.0 ND ND 14.4 J ND 14-Dec-17 2.5 50.0 ND ND 8.7 J ND 14-May-18 EPA 6010 2.5 50.0 ND ND ND ND 4-Dec-18 EPA 601OD 2.5 5.0 ND ND 5.9 ND 6-May-19 EPA 6O1OD 2.5 5.0 ND ND 6.3 ND 5-Nov-19 EPA 6O1OD 2.5 5.0 ND ND ND --- 6-May-20 EPA 6O1OD 3.5 5.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 8 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Selenium 29-May-07 NR 10 ND 4.50 J Dry ND 28-Nov-07 NR 10 ND ND Dry 2.40 J 28-May-08 3.8 10.0 ND ND Dry ND 5-Nov-08 3.8 10.0 ND 4.30 B Dry 4.20 J 2-Jun-09 3.8 10.0 ND ND ND ND 19-Nov-09 3.8 10.0 4.50 J ND ND ND NC2B = 5 ug/L (05/01/2007) 14-Jun-10 3.8 10.0 ND ND Dry ND 29-Nov-10 3.8 10.0 ND ND Dry ND 31-May-11 3.8 10.0 ND ND Dry ND 19-Dec-11 10.0 10.0 ND ND ND ND 30-May-12 10.0 10.0 ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND 11-Jun-13 10.0 10.0 ND ND ND ND 29-Oct-13 10.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 10.0 10.0 ND ND ND ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND ND ND 19-May-15 EPA 6010 5.0 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 5.0 10.0 ND ND ND ND 2-May-16 EPA 6010 5.0 10.0 ND ND ND ND 12-Dec-16 EPA 6010 5.0 10.0 ND ND NS ND 26-Jun-17 EPA 6010 5.0 10.0 ND ND ND ND 14-Dec-17 5.0 10.0 ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 5.0 10.0 ND ND ND ND 6-May-19 EPA 601OD 5.0 10.0 ND ND ND ND 5-Nov-19 EPA 6O1OD 5.0 10.0 ND ND ND --- 6-May-20 EPA 601OD 4.7 10.0 ND ND ND --- Silver 5-Nov-08 0.1 10.0 0.17 B 0.11 B Dry 0.20 J 2-Jun-09 0.10 10.0 ND ND ND ND 19-Nov-09 0.10 10.0 0.17 J 0.21 J 0.38 J ND NC2B = 0.06 pg/L (05/01/2007) 14-Jun-10 0.10 10.0 ND ND ND ND 29-Nov-10 0.10 10.0 ND ND Dry ND 31-May-11 0.10 10.0 ND 0.30 J Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND ND ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 2.5 5.0 ND ND ND ND 6-May-19 EPA 6O1OD 2.5 5.0 ND ND ND ND 5-Nov-19 EPA 6010D 2.5 5.0 ND ND ND --- 6-May-20 EPA 6O1OD I 2.5 5.0 ND I ND ND --- Thallium 4-Dec-18 EPA 6O2OB 0.1 0.1 ND ND 0.077 J --- 6-May-19 EPA 6O2OB 0.1 0.1 ND ND 0.11 ND 5-Nov-19 EPA 6O2OB 0.1 0.1 ND ND ND --- 6-May-20 EPA 6O2OB 0.1 0.1 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 9 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Vanadium 19-Nov-03 NR 40.0 62.00 56.00 60.00 ND 5-May-04 NR 40 ND ND ND ND 9-Nov-04 NR 40 ND ND ND ND 25-May-05 NR 40 ND ND Dry ND 2-Nov-05 NR 40 ND ND Dry ND 24-May-06 NR 40 ND ND Dry ND 1-Nov-06 NR 40 ND ND ND ND 29-May-07 NR 25 ND ND Dry ND 28-Nov-07 NR 25 ND ND Dry ND 28-May-08 0.2 25.0 3.20 J 4.10 J Dry ND 5-Nov-08 0.20 25.0 0.63 B 0.78 B Dry 0.85 J 2-Jun-09 0.20 25.0 1.90 B 2.10 B 1.10 B 1.20 J 19-Nov-09 0.20 25.0 2.60 B 3.00 J 0.95 B 0.58 J NC2B = NE (05/01/2007) 14-Jun-10 0.20 25.0 2.30 B 2.20 B Dry 1.20 J 29-Nov-10 0.20 25.0 ND ND Dry ND 31-May-11 0.20 25.0 1.70 J 1.70 J Dry ND 19-Dec-11 5.0 25.0 ND ND ND ND 30-May-12 5.0 25.0 ND ND ND ND 3-Dec-12 5.0 25.0 ND ND ND ND 11-Jun-13 5.0 25.0 8.5 J 8 J ND ND 29-Oct-13 5.0 25.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 25.0 ND ND ND ND 21-Oct-14 EPA 6010 5.0 25.0 ND ND ND ND 19-May-15 EPA 6010 2.5 25.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 25.0 ND ND ND ND 2-May-16 EPA 6010 2.5 25.0 3.3 J 3.1 J ND ND 12-Dec-16 EPA 6010 2.5 25.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 25.0 4 J 4.4 J 4.1 J ND 14-Dec-17 2.5 25.0 ND ND ND ND 14-May-18 EPA 6010 2.5 25.0 ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 ND ND ND ND 5-Nov-19 EPA 6010D 1.3 5.0 1.4 J 1.5 J 1.5 J --- 6-May-20 EPA 6010D 3.9 5.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 10 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Zinc 6-Oct-94 NR 10 ND ND 11.0 NA 28-Jun-95 NR 10 17.0 21.0 60.0 NA 25-Oct-95 NR 10 28.0 ND ND NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 10 18.0 ND 34.0 NA 12-May-97 NR 10 50.0 30.0 30.0 NA 19-Nov-97 NR 10 ND ND ND NA 27-May-98 NR 10 ND 20.0 10.0 NA 24-Nov-98 NR 10 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-oct-99 NR 50 ND ND NA ND 3-May-00 NR 50 ND ND ND ND 8-Nov-00 NR 50 ND ND ND ND 29-May-01 NR 50 ND ND ND ND 6-Nov-01 NR 50 ND ND ND ND 21-May-02 NR 50 ND ND ND ND 13-Nov-02 NR 50 ND ND ND ND 14-May-03 NR 50 ND ND ND ND 19-Nov-03 NR 50 70.0 60.0 70.0 ND 5-May-04 NR 50 ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND 25-May-05 NR 50 ND ND Dry ND 2-Nov-05 NR 50 ND ND Dry ND 24-May-06 NR 50 ND ND Dry ND 1-Nov-06 NR 50 ND ND ND ND 29-May-07 NR 10 3.20 B 3.30 B Dry 2.00 J 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.4 10.0 2.40 B 3.50 B Dry 2.10 J 5-Nov-08 0.40 10.0 2.80 B 1.60 B Dry 8.90 J 2-Jun-09 0.40 10.0 0.70 B 2.70 B 3.90 B 83.0 19-Nov-09 0.40 10.0 6.70 B 8.00 B 14.5 B 3.50 J NC2B = 50 ug/L (05/01/2007) 14-Jun-10 0.40 10.0 ND ND Dry ND 29-Nov-10 0.40 10.0 ND ND Dry ND 31-May-11 0.40 10.0 14.9 B 11.6 B Dry 13.7 19-Dec-11 10.0 10.0 ND ND 181 ND 30-May-12 10.0 10.0 ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND 11-Jun-13 10.0 10.0 11.8 B 13 B 11.7 B 76.3 29-Oct-13 10.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 10.0 10.0 ND ND 10.3 ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND 18.0 ND 19-May-15 EPA 6010 5.0 10.0 ND 10.4 Dry NA 7-Dec-15 EPA 6010 5.0 10.0 ND ND 15.7 B 7.2 J 2-May-16 EPA 6010 5.0 10.0 ND 5.9 J 49.2 ND 12-Dec-16 EPA 6010 5.0 10.0 ND 8.0 J NS ND 26-Jun-17 EPA 6010 5.0 10.0 ND ND 29.9 ND 14-Dec-17 5.0 10.0 ND ND 13.5 ND 14-May-18 EPA 6010 5.0 10.0 ND ND ND ND 4-Dec-18 EPA 6010D 5.0 10.0 ND ND 7.40 J ND 6-May-19 EPA 6010D 5.0 10.0 ND ND ND ND 5-Nov-19 EPA 6010D 5.0 10.0 ND ND ND --- 6-May-20 EPA 6010D 9.5 10.0 ND ND ND --- Beryllium 5-Nov-19 EPA 6010D 0.2 1.0 ND 0.24 J ND --- 6-May-20 EPA 6010D 0.7 1.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 11 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks ORGANICS Acetone 28-Nov-07 NR 100 3.00 B 3.30 B Dry 4.30 J 28-May-08 20 100 ND ND Dry ND 5-Nov-08 20.0 100 ND ND Dry ND 2-Jun-09 2.2 100 ND ND 6.00 B 3.20 J 19-Nov-09 2.2 100 4.00 B ND ND 3.80 J NC2B = NE (05/01/2007) 14-Jun-10 2.2 100 ND ND Dry 9.80 J 29-Nov-10 2.2 100 ND ND Dry 4.30 J 31-May-11 2.2 100 ND ND Dry 3.90 J 19-Dec-11 2.2 100 ND ND ND 6.60 J 30-May-12 2.2 100 ND ND ND ND 3-Dec-12 2.2 100 ND ND ND ND 11-Jun-13 2.2 100 ND ND ND ND 29-Oct-13 50.0 500 ND ND Dry ND 5-May-14 EPA 8260 10.0 100 ND ND 17.6 J ND 21-Oct-14 EPA 8260 10.0 100 ND ND ND ND 19-May-15 EPA 8260 10.0 100 ND ND Dry NA 7-Dec-15 EPA 8260 10.0 100 ND ND ND ND 2-May-16 EPA 8260 10.0 100 ND ND ND ND 12-Dec-16 EPA 8260 10.0 100 ND ND NS ND 26-Jun-17 EPA 8260 10.0 100 10.8 J 26.9 J 13.4 J 23.0 J 14-Dec-17 10.0 100 ND ND ND ND 14-May-18 EPA 8260 10.0 100 ND ND ND ND 4-Dec-18 EPA 8260B 10.0 25 ND ND ND ND 6-May-19 EPA 8260D 8.2 25 ND ND ND ND 5-Nov-19 EPA 8260D 6.2 25 ND ND ND --- 6-May-20 EPA 8260D 6.2 25 ND ND ND ND Benzene 19-Nov-09 0.25 1.0 2.10 0.48 J ND ND Resample> 15-Feb-10 0.25 1.0 ND NS NS ND NC2B = 1.19 ug/L (05/01/2007) 14-Jun-10 0.25 1.0 ND ND Dry ND 29-Nov-10 0.25 1.0 ND ND Dry ND 31-May-11 0.25 1.0 ND ND Dry ND 19-Dec-11 0.25 1.0 ND ND ND ND 30-May-12 0.25 1.0 ND ND ND ND 3-Dec-12 0.25 1.0 ND ND ND ND 11-Jun-13 0.25 1.0 ND ND ND ND 29-Oct-13 0.25 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.25 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.25 1.0 ND ND ND ND 19-May-15 EPA 8260 0.25 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.25 1.0 ND ND ND ND 2-May-16 EPA 8260 0.25 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.25 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.25 1.0 ND ND ND ND 14-Dec-17 0.25 1.0 ND ND ND ND 14-May-18 EPA 8260 0.25 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.25 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.20 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.15 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.15 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 12 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Bromomethane 5-May-14 EPA 8260 0.29 10.0 ND ND 4.6 J ND NC2B = NE (05/01/2007) 21-Oct-14 EPA 8260 0.29 10.0 ND ND 0.41 J ND 19-May-15 EPA 8260 0.29 10.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.29 10.0 ND ND ND ND 2-May-16 EPA 8260 0.29 10.0 ND ND ND ND 12-Dec-16 EPA 8260 0.29 10.0 ND ND NS ND 26-Jun-17 EPA 8260 0.29 10.0 ND ND ND ND 14-Dec-17 0.29 10.0 ND ND ND ND 14-May-18 EPA 8260 0.29 10.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.29 2.0 ND ND ND ND 6-May-19 EPA 8260D 0.95 2.0 ND ND 1.5 J ND 5-Nov-19 EPA 8260D 0.62 2.0 ND ND ND --- 6-May-20 EPA 8260D 0.62 2.0 ND ND ND ND Chlorobenzene 19-Nov-09 0.23 3.0 4.20 0.44 J ND ND NC2B = 488 pg/L (05/01/2007) 14-Jun-10 0.23 3.0 ND ND Dry ND 29-Nov-10 0.23 3.0 ND ND Dry ND 31-May-11 0.23 3.0 ND ND Dry ND 19-Dec-11 0.23 3.0 ND 0.58 J ND ND 30-May-12 0.23 3.0 ND ND ND ND 3-Dec-12 0.23 3.0 ND ND ND ND 11-Jun-13 0.23 3.0 ND ND ND ND 29-Oct-13 0.23 3.0 ND ND Dry ND 5-May-14 EPA 8260 0.23 3.0 ND ND ND ND 21-Oct-14 EPA 8260 0.23 3.0 ND ND ND ND 19-May-15 EPA 8260 0.23 3.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.23 3.0 ND ND ND ND 2-May-16 EPA 8260 0.23 3.0 ND ND ND ND 12-Dec-16 EPA 8260 0.23 3.0 ND ND NS ND 26-Jun-17 EPA 8260 0.23 3.0 ND ND ND ND 14-Dec-17 0.23 3.0 ND ND ND ND 14-May-18 EPA 8260 0.23 3.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.23 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.53 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.23 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.23 1.0 ND ND ND ND Chloromethane 14-Jun-10 0.11 1.0 0.14 B 0.17 B Dry 0.15 J NC2B = NE (05/01/2007) 29-Nov-10 0.11 1.0 ND ND Dry ND 31-May-11 0.11 1.0 ND ND Dry ND 19-Dec-11 0.11 1.0 ND ND ND ND 30-May-12 0.11 1.0 ND ND ND ND 3-Dec-12 0.11 1.0 ND ND ND ND 11-Jun-13 0.11 1.0 ND ND ND ND 29-Oct-13 0.11 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.11 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.11 1.0 ND ND 0.19 J ND 19-May-15 EPA 8260 0.11 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.11 1.0 ND ND ND ND 2-May-16 EPA 8260 0.11 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.11 1.0 ND ND ND 0.36 J 26-Jun-17 EPA 8260 0.11 1.0 ND 0.28 J 0.54 J ND 14-Dec-17 0.11 1.0 ND ND ND ND 14-May-18 EPA 8260 0.11 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.11 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.38 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.39 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.39 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 13 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks 1,2-Dichlorobenzene 19-Nov-09 0.30 5.0 0.31 J 0.34 J ND ND NC2B = 488 pg,/L (05/01/2007) 14-Jun-10 0.30 5.0 ND ND Dry ND 29-Nov-10 0.30 5.0 ND ND Dry ND 31-May-11 0.30 5.0 ND ND Dry ND 19-Dec-11 0.30 5.0 ND ND ND ND 30-May-12 0.30 5.0 ND ND ND ND 3-Dec-12 0.30 5.0 ND ND ND ND 11-Jun-13 0.30 5.0 ND ND ND ND 29-Oct-13 0.30 5.0 ND ND Dry ND 5-May-14 EPA 8260 0.30 5.0 ND ND ND ND 21-Oct-14 EPA 8260 0.30 5.0 ND ND ND ND 19-May-15 EPA 8260 0.30 5.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.30 5.0 ND ND ND ND 2-May-16 EPA 8260 0.30 5.0 ND ND ND ND 12-Dec-16 EPA 8260 0.30 5.0 ND ND NS ND 26-Jun-17 EPA 8260 0.30 5.0 ND ND ND ND 14-Dec-17 0.30 5.0 ND ND ND ND 14-May-18 EPA 8260 0.30 5.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.30 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.49 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.29 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.29 1.0 ND ND ND ND 1,4-Dichlorobenzene 19-Nov-09 0.33 1.0 4.50 1.90 ND ND NC2B = 488 pg/L (05/01/2007) 14-Jun-10 0.33 1.0 ND ND Dry ND 29-Nov-10 0.33 1.0 ND ND Dry ND 31-May-11 0.33 1.0 ND ND Dry ND 19-Dec-11 0.33 1.0 ND ND ND ND 30-May-12 0.33 1.0 ND ND ND ND 3-Dec-12 0.33 1.0 ND ND ND ND 11-Jun-13 0.33 1.0 ND ND ND ND 29-Oct-13 0.33 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.33 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.33 1.0 ND ND ND ND 19-May-15 EPA 8260 0.33 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.33 1.0 ND ND ND ND 2-May-16 EPA 8260 0.33 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.33 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.33 1.0 ND ND ND ND 14-Dec-17 0.33 1.0 ND ND ND ND 14-May-18 EPA 8260 0.33 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.33 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.58 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.26 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.26 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 14 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks 1,1-Dichloroethane 19-Nov-09 0.32 5.0 6.30 7.80 ND ND NC2B = NE (05/01/2007) 14-Jun-10 0.32 5.0 ND ND Dry ND 29-Nov-10 0.32 5.0 ND ND Dry ND 31-May-11 0.32 5.0 ND ND Dry ND 19-Dec-11 0.32 5.0 ND ND ND ND 30-May-12 0.32 5.0 ND ND ND ND 3-Dec-12 0.32 5.0 ND ND ND ND 11-Jun-13 0.32 5.0 ND ND ND ND 29-Oct-13 0.32 5.0 ND ND Dry ND 5-May-14 EPA 8260 0.32 5.0 ND ND ND ND 21-Oct-14 EPA 8260 0.32 5.0 ND ND ND ND 19-May-15 EPA 8260 0.32 5.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.32 5.0 ND ND ND ND 2-May-16 EPA 8260 0.32 5.0 ND ND ND ND 12-Dec-16 EPA 8260 0.32 5.0 ND ND NS ND 26-Jun-17 EPA 8260 0.32 5.0 ND ND ND ND 14-Dec-17 0.32 5.0 ND ND ND ND 14-May-18 EPA 8260 0.32 5.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.32 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.41 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.27 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.27 1.0 ND ND ND ND cis-1,2-Dichloroethene 19-Nov-09 0.19 5.0 5.50 43.80 ND 0.26 J NC2B = NE (05/01/2007) 14-Jun-10 0.19 5.0 ND ND Dry ND 29-Nov-10 0.19 5.0 ND ND Dry ND 31-May-11 0.19 5.0 ND ND Dry ND 19-Dec-11 0.19 5.0 ND ND ND ND 30-May-12 0.19 5.0 ND ND ND ND 3-Dec-12 0.19 5.0 ND ND ND ND 11-Jun-13 0.19 5.0 ND ND ND ND 29-Oct-13 0.19 5.0 ND ND Dry ND 5-May-14 EPA 8260 0.19 5.0 ND ND ND ND 21-Oct-14 EPA 8260 0.19 5.0 ND ND ND ND 19-May-15 EPA 8260 0.19 5.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.19 5.0 ND ND ND ND 2-May-16 EPA 8260 0.19 5.0 ND ND ND ND 12-Dec-16 EPA 8260 0.19 5.0 ND ND NS ND 26-Jun-17 EPA 8260 0.19 5.0 ND ND ND ND 14-Dec-17 0.19 5.0 ND ND ND ND 14-May-18 EPA 8260 0.19 5.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.19 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.66 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.29 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.29 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 15 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks 1,2-Dichloropropane 19-Nov-09 0.27 1.0 2.30 1.00 ND ND Resample> 15-Feb-10 0.27 1.0 ND ND NS ND NC2B = NE (05/01/2007) 14-Jun-10 0.27 1.0 ND ND Dry ND 29-Nov-10 0.27 1.0 ND ND Dry ND 31-May-11 0.27 1.0 ND ND Dry ND 19-Dec-11 0.27 1.0 ND ND ND ND 30-May-12 0.27 1.0 ND ND ND ND 3-Dec-12 0.27 1.0 ND ND ND ND 11-Jun-13 0.27 1.0 ND ND ND ND 29-Oct-13 0.27 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.27 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.27 1.0 ND ND ND ND 19-May-15 EPA 8260 0.27 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.27 1.0 ND ND ND ND 2-May-16 EPA 8260 0.27 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.27 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.27 1.0 ND ND ND ND 14-Dec-17 0.27 1.0 ND ND ND ND 14-May-18 EPA 8260 0.27 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.27 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.60 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.19 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.19 1.0 ND ND ND ND 1,4-Dioxane (p-Dioxane) 4-Dec-18 EPA 8260B 1.90 2.0 ND ND 10.5 ND 6-May-19 EPA 8260D 1.20 2.0 ND ND 7.60 ND 5-Nov-19 EPA 8260D 1.20 2.0 ND ND ND --- 6-May-20 EPA 8260D 1.20 2.0 ND ND ND ND Tetrachloroethene 19-Nov-09 0.46 1.0 0.58 J 8.80 ND ND Resample> 15-Feb-10 0.46 1.0 NS ND NS ND NC2B = 0.7 pg/L (05/01/2007) 14-Jun-10 0.46 1.0 ND ND Dry ND 29-Nov-10 0.46 1.0 ND ND Dry ND 31-May-11 0.46 1.0 ND ND Dry ND 19-Dec-11 0.46 1.0 ND ND ND ND 30-May-12 0.46 1.0 ND ND ND ND 3-Dec-12 0.46 1.0 ND ND ND ND 11-Jun-13 0.46 1.0 ND ND ND ND 29-Oct-13 0.46 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.46 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.46 1.0 ND ND ND ND 19-May-15 EPA 8260 0.46 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.46 1.0 ND ND ND ND 2-May-16 EPA 8260 0.46 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.46 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.46 1.0 ND ND ND ND 14-Dec-17 0.46 1.0 ND ND ND ND 14-May-18 EPA 8260 0.46 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.46 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.78 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.16 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.16 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 16 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Trichloroethene 19-Nov-09 0.47 1.0 2.10 6.90 ND ND Resample> 15-Feb-10 0.47 1.0 NS ND NS ND NC2B = 2.5 pg/L (05/01/2007) 14-Jun-10 0.47 1.0 ND ND Dry ND 29-Nov-10 0.47 1.0 ND ND Dry ND 31-May-11 0.47 1.0 ND ND Dry ND 19-Dec-11 0.47 1.0 ND ND ND ND 30-May-12 0.47 1.0 ND ND ND ND 3-Dec-12 0.47 1.0 ND ND ND ND 11-Jun-13 0.47 1.0 ND ND ND ND 29-Oct-13 0.47 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.47 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.47 1.0 ND ND ND ND 19-May-15 EPA 8260 0.47 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.47 1.0 ND ND ND ND 2-May-16 EPA 8260 0.47 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.47 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.47 1.0 ND ND ND ND 14-Dec-17 0.47 1.0 ND ND ND ND 14-May-18 EPA 8260 0.47 1.0 ND ND ND ND 4-Dec-18 EPA 826OB 0.47 1.0 ND ND ND ND 6-May-19 EPA 826OD 0.34 1.0 ND ND ND ND 5-Nov-19 EPA 826OD 0.22 1.0 ND ND ND --- 6-May-20 EPA 826OD 0.22 1.0 ND ND ND ND Vinyl Chloride 19-Nov-09 0.62 1.0 2.60 ND ND ND Resample> 15-Feb-10 0.62 1.0 ND NS NS ND NC2B = 0.025 pg/L (05/01/2007) 14-Jun-10 0.62 1.0 ND ND Dry ND 29-Nov-10 0.62 1.0 ND ND Dry ND 31-May-11 0.62 1.0 ND ND Dry ND 19-Dec-11 0.62 1.0 ND ND ND ND 30-May-12 0.62 1.0 ND ND ND ND 3-Dec-12 0.62 1.0 ND ND ND ND 11-Jun-13 0.62 1.0 ND ND ND ND 29-Oct-13 0.62 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.62 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.62 1.0 ND ND ND ND 19-May-15 EPA 8260 0.62 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.62 1.0 ND ND ND ND 2-May-16 EPA 8260 0.62 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.62 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.62 1.0 ND ND ND ND 14-Dec-17 0.62 1.0 ND ND ND ND 14-May-18 EPA 8260 0.62 1.0 ND ND ND ND 4-Dec-18 EPA 826OB 0.62 1.0 ND ND ND ND 6-May-19 EPA 826OD 0.60 1.0 ND ND ND ND 5-Nov-19 EPA 826OD 0.24 1.0 ND ND ND --- 6-May-20 EPA 826OD 0.24 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 17 of 18 TABLE A2-4: Historical Surface Water Constituents Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Hardness, Total (SM 2340B) 6-May-20 EPA 6010D 131.00 662.0 25,300 22,600 25,100 Notes: RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; SWSL for December 2006 - 2017, and MRL 2017-present.). DL = Laboratory Detection Limit. ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006). NA = No data available. NI = Not installed. NR = Not reported. NS = Not sampled. NE = Not established. J = Estimated concentration less than the RL but above the DL. B = Blank -Qualified Concentration (suspected to reflect laboratory or field contamination). Dry = Surface water point was considered to be dry and no sample collected. NC213 = 15A NCAC 2B Surface Water Standards. Bold values are greater than the NC213. Surface water has been classified as Water Supply IV - Highly Developed, Freshwater, Critical Area. Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 18 of 18 TABLE A2-5: Historical Surface Water Field Parameters Parameter Collection Date SW-1 SW-2 SW-3 Conductivity (at 25c) 11-Jun-13 54.4 63.2 655 [MS/CM] 29-Oct-13 78.2 67.8 -- 5-May-14 90.0 115.9 1036 20-Oct-14 103.2 130.7 1099 18-May-15 92.0 97 -- 7-Dec-15 90.0 94 647 2-May-16 73.8 71 1391 12-Dec-16 95.8 506 -- 26-Jun-17 92.0 1152 1032 14-Dec-17 122.0 61 869 14-May-18 137.0 220 105 4-Dec-18 102.9 90.6 395.4 6-May-19 96.1 91.8 986 4-Nov-19 78 92.4 80.9 6-May-20 77.0 76.8 76.8 pH 11-Jun-13 7.8 8.25 7.81 [S.U.] 29-Oct-13 7.2 6.85 -- 5-May-14 8.1 8.42 8.17 20-Oct-14 7.0 7.38 7.8 18-May-15 7.0 6.87 -- 7-Dec-15 7.3 7.27 8.03 2-May-16 8.0 6.91 6.78 12-Dec-16 7.0 6.51 -- 26-Jun-17 7.2 5.64 7.36 14-Dec-17 8.3 8.26 8.3 14-May-18 7.6 7.61 7.14 4-Dec-18 7.4 7.36 6.78 6-May-19 6.60 6.98 7.92 4-Nov-19 6.60 6.78 6.63 6-May-20 7.5 7.43 7.43 Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 Page 1 of 2 TABLE A2-5: Historical Surface Water Field Parameters Parameter Collection Date SW-1 SW-2 SW-3 Temperature 11-Jun-13 19.2 18.1 19.7 [ ° C] 29-Oct-13 13.1 12.4 -- 5-May-14 19.2 19 17.9 20-Oct-14 14.3 14.1 13.8 18-May-15 19.1 19.5 -- 7-Dec-15 10.6 10.4 10.7 2-May-16 19.6 19.3 20.2 12-Dec-16 8.7 11 -- 26-Jun-17 20.0 19.9 19.8 14-Dec-17 6.2 6 6.8 14-May-18 12.4 19.9 19.4 4-Dec-18 11.5 11.7 6.3 6-May-19 20.1 19.4 18.5 4-Nov-19 10.0 7 10.6 10.7 6-May-20 14.4 17.2 17.2 Dissolved Oxygen 6-May-19 5.89 6.14 5.93 (mg1L) 4-Nov-19 7.23 6.56 7.27 6-May-20 5.2 4.89 4.89 Oxidation Reduction Potential 6-May-19 135.0 119.8 183.3 (mV) 4-Nov-19 147.6 43.4 99.9 6-May-20 326.9 214 214 Turbidity 11-Jun-13 48.10 34.60 19.71 [NTU] 29-Oct-13 7.34 4.89 -- 5-M ay-14 15.50 16.70 15.80 20-Oct-14 12.02 11.85 20.40 18-May-15 8.63 6.09 -- 7-Dec-15 6.75 5.25 4.86 2-May-16 7.05 8.75 7.85 12-Dec-16 8.05 9.20 -- 26-Jun-17 15.05 8.70 9.01 14-Dec-17 61.00 4.04 4.34 14-May-18 0.40 0.00 0.40 4-Dec-18 12.30 20.60 7.37 6-May-19 11.1 10.2 17.5 4-Nov-19 11.6 10.4 10.0 6-May-20 15.6 15.6 15.6 Notes: °C= degrees Centigrade *= resample S.U.= Standard Units my = millivolts pS/cm = microSemens per centimeter NTU = Nephelometric Turbidity Units mg/L - milligrams per liter Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 Page 2 of 2