4406_ROSCANS_2003

BLUE RIDGE
PAPER PRODUCTS INC.
January 3, 2003
Mr. James Patterson
North Carolina Department of Environment
And Natural Resources
852 Merriman Ave.
Asheville, North Carolina 28804
Re: Chemical and physical analysis of Canton Mill process wastes.
Dear Mr. Patterson:
Attached is laboratory analysis related to the latest sampling of Canton Mill process
wastes, including wastewater treatment plant sludge, lime mud, slaker grits, precoat filter
dregs, boiler fly ash, and boiler cinders. The analysis is in accordance with Permit
Number 44-06, Area A East, and 15A NCAC 13B, Section .103(d).
Samples were collected on December 6, 2002. Each sample was analyzed by TCLP for
RCRA metals, volatile organics, and semi volatile organics (excluding herbicides and
pesticides). In addition, the sludge and lime were tested for reactive cyanide and reactive
sulfide. No samples were found to be in excess of RCRA standards for the tested
parameters.
Please call me at 828-646-2028 if you have questions or comments.
Sincerely,
r
m Giauque
Attachments
Copy: Derric Brown
file:patterson010303.doe
175 Main Street • P.O. Box 4000
Canton, North Carolina 28716 • Phone: [phone]
Raising Your Expectations

aceAnalytical®
www.pacelabs.com
December 24, 2002
Mr. Jim Giaque
Blue Ridge Paper Products Inc.
Main St.
PO Box 4000
Canton, NC 28716
RE: Lab Project Number: 9334878
Client Project ID: PROCESS MATERIALS 2002
Dear Mr. Giaque:
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Enclosed are the analytical results for sample(s) received by the laboratory on December 6, 2002. Results reported
herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
If you have any questions concerning this report please feel free to contact me.
Sincerely,
Tom Williams b �(
[e-mail]
Project Manager
Enclosures
Laboratory Certification IN REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water 37712 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
N ACCOR
`EOM/ n Rq n
r�eiac=
Laboratory Certification IDs
TN Drinking Water 02980
SC Environmental 99030

Face Analytical
www.pacelabs.com
Solid results are reported on a dry weight basis
Lab Sample No: 931420996
Client Sample ID: WWTP SLUDGE
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Lab Project Number: 9334878 Fax:[phone]
Client Project ID: PROCESS MATERIALS 2002
Project Sample Number: 9334878-001 Date Collected: 12/06/02 15:15
Matrix: Soil Date Received: 12/06/02 16:55
Parameters Results Units Report Limit Analyzed By CAS No. Qual RegLmt
Metals
RCRA Metals, ICP, TCLP Method: EPA 6010
Date Digested 12/11/02 12/11/02
RCRA Metals, ICP, TCLP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
Date Digested
Wet Chemistry
'Percent Moisture
Percent Moisture
Date: 12/24/02
Prep/Method: EPA 3010 / EPA 6010
NO
mg/l
0.50
0.33
mg/l
0.10
ND
mg/l
0.010
NO
mg/l
0.020
NO
mg/1
0.10
NO
mg/l
0.10
ND
mg/l
0.050
12/17/02
Method: % Moisture
64.6 %
12/18/02 15:44 EWS 7440.38-2
12/18/02 15:44 EWS 7440-39-3
12/18/02 15:44 EWS 7440-43-9
12/18/02 15:44 EWS 7440-47-3
12/18/02 15:44 EWS 7439-92-1
12/18/02 15:44 EWS 7782-49-2
12/18/02 15:44 EWS 7440-22-4
12/17/02
12/09/02 WCB
Laboratory Certification IN REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 37712 without the written consent of Pace Analytical Services, Inc.
N Accoq
"neiact,
Page: 1 of 8
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Lab Sample No: 931421002
Client Sample ID: LIME MUD
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Lab Project Number: 9334878 Fax:[phone]
Client Project ID: PROCESS MATERIALS 2002
Project Sample Number: 9334878.002 Date Collected: 12/06/02 13:20
Matrix: Soil Date Received: 12/06/02 16:55
Parameters Results Units Report Limit Analyzed By CAS No. Qual RegLmt
Metals
RCRA Metals, ICP, TCLP Method: EPA 6010
Date Digested 12/11/02 12/11/02
RCRA Metals, ICP, TCLP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
Date Digested
Wet Chemistry
Percent Moisture
Percent Moisture
Date: 12/24/02
Prep/Method: EPA 3010 / EPA 6010
NO
mg/l
0.50
0.24
mg/l
0.10
ND
mg/l
0.010
ND
mg/l
0.020
NO
mg/l
0.10
ND
mg/l
0.10
ND
mg/l
0.050
12/17/02
Method: % Moisture
37.2 %
12/18/02 15:47 EWS 7440-38-2
12/18/02 15:47 EWS 7440-39-3
12/18/02 15:47 EWS 7440-43-9
12/18/02 15:47 EWS 7440-47-3
12/18/02 15:47 EWS 7439-92-1
12/18/02 15:47 EWS 7782-49-2
12/18/02 15:47 EWS 7440-22-4
12/17/02
12/09/02 WCB
Laboratory Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 37712 without the written consent of Pace Analytical Services, Inc.
0
ace,
Page: 2 of 8
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ace Analytical
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Lab Sample No: 931421010
Client Sample ID: SLAKER GRITS
Parameters
Metals
RCRA Metals, ICP, TCLP
Date Digested
RCRA Metals, ICP, TCLP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
Date Digested
Wet Chemistry
Percent Moisture
Percent Moisture
Date: 12/24/02
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Lab Project Number: 9334878 Fax [phone]
Client Project ID: PROCESS MATERIALS 2002
Project Sample Number: 9334878.003 Date Collected: 12/06/02 13:50
Matrix: Soil Date Received: 12/06/02 16:55
Results Units Report Limit Analyzed By CAS No. Qual RegLmt
Method: EPA 6010
12/11/02 12/11/02
Prep/Method: EPA 3010 / EPA 6010
ND
mg/l
0.50
12/18/02
15:56
EWS
7440-38-2
0.19
mg/l
0.10
12/18/02
15:56
EWS
7440-39.3
ND
mg/l
0.010
12/18/02
15:56
EWS
7440-43-9
NO
mg/l
0.020
12/18/02
15:56
EWS
7440.47-3
ND
mg/1
0.10
12/18/02
15:56
EWS
7439-92-1
ND
mg/l
0.10
12/18/02
15:56
EWS
7782-49-2
ND
mg/l
0,050
12/18/02
15:56
EWS
7440-22-4
12/17/02
12/17/02
Method: % Moisture
18.9 %
12/09/02 WCB
Laboratory Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 37712 without the written consent of Pace Analytical Services, Inc.
N ACCp,
4
Page: 3 of 8
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ace Analytical
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Lab Sample No: 931421028
Client Sample ID: PRECOAT FILTER DREGS
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Lab Project Number: 9334878 Fax:[phone]
Client Project ID: PROCESS MATERIALS 2002
Project Sample Number: 9334878-004 Date Collected: 12/06/02 13:30
Matrix: Soil Date Received: 12/06/02 16:55
Parameters Results Units Report Limit Analyzed By CAS No. Qual RegLmt
Metals
RCRA Metals, ICP, TCLP Method: EPA 6010
Date Digested 12/11/02 12/11/02
RCRA Metals, ICP, TCLP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
Date Digested
Wet Chemistry
Percent Moisture
Percent Moisture
Date: 12/24/02
Prep/Method: EPA 3010 / EPA 6010
ND
mg/l
0.50
0.48
mg/l
0.10
ND
mg/l
0.010
NO
mg/l
0.020
NO
mg/l
0.10
NO
mg/l
0.10
NO
mg/l
0.050
12/17/02
Method: t Moisture
0 t
12/18/02 15:59 EWS 7440-38-2
12/18/02 15:59 EWS 7440.39.3
12/18/02 15:59 EWS 7440-43-9
12/18/02 15:59 EWS 7440.47-3
12/18/02 15:59 EWS 7439-92-1
12/18/02 15:59 EWS 7782.49-2
12/18/02 15:59 EWS 7440-22-4
12/17/02
12/09/02 WCB
Laboratory Certification IN REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 37712 without the written consent of Pace Analytical Services, Inc.
f
u� act.
Page: 4 of 8
Laboratory Certification IDs
TN Drinking Water 02980
SC Environmental 99030

ace Analytical
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Lab Sample No: 931421036
Client Sample ID: FLY ASH
Parameters
Metals
RCRA Metals, ICP, TCLP
Date Digested
RCRA Metals, ICP, TCLP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
Date Digested
Wet Chemistry
-Percent Moisture
Percent Moisture
Date: 12/24/02
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Lab Project Number: 9334878 Fax.[phone]
Client Project ID: PROCESS MATERIALS 2002
Project Sample Number: 9334878.005 Date Collected: 12/06/02 14:00
Matrix: Soil Date Received: 12/06/02 16:55
Results Units Report Limit Analyzed By CAS No. Qual RegLmt
Method: EPA 6010
12/11/02
Prep/Method: EPA 3010 / EPA 6010
12/11/02
0.63
mg/l
0.50
12/18/02
16:02
EWS
7440.38-2
NO
mg/l
0.10
12/18/02
16:02
EWS
7440-39-3
0.011
mg/l
0.010
12/18/02
16:02
EWS
7440-43-9
NO
mg/1
0.020
12/18/02
16:02
EWS
7440-47-3
NO
mg/1
0.10
12/18/02
16:02
EWS
7439-92-1
ND
mg/1
0.10
12/18/02
16:02
EWS
7782-49-2
ND
mg/l
0.050
12/18/02
16:02
EWS
7440-22-4
12/17/02
12/17/02
Method: X Moisture
41.6 %
12/09/02 WCB
Laboratory Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 37712 without the written consent of Pace Analytical Services, Inc.
N ACCOF
M-P-N.
�
ac_
Page: 5 of 8
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ace At o
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Lab Sample No: 931421044
Client Sample ID: CINDERS
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Lab Project Number: 9334878 Fax:[phone]
Client Project ID: PROCESS MATERIALS 2002
Project Sample Number: 9334878.006 Date Collected: 12/06/02 14:20
Matrix: Soil Date Received: 12/06/02 16:55
Parameters Results Units Report Limit Analyzed By CAS No. Qual Re Lmt
Metals
RCRA Metals, ICP, TCLP Method: EPA 6010
Date Digested 12/16/02 12/16/02
RCRA Metals, ICP, TCLP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
Date Digested
Wet Chemistry
Percent Moisture
Percent Moisture
Date: 12/24/02
Prep/Method: EPA 3010 / EPA 6010
NO
mg/l
0.50
0.62
mg/l
0.10
NO
mg/l
0.010
ND
mg/l
0.020
NO
mg/l
0.10
ND
mg/l
0.10
ND
mg/l
0.050
12/17/02
Method: % Moisture
35.6 %
12/18/02 16:06 EWS 7440.38-2
12/18/02 16:06 EWS 7440-39-3
12/18/02 16:06 EWS 7440-43-9
12/18/02 16:06 EWS 7440-47-3
12/18/02 16:06 EWS 7439-92-1
12/18/02 16:06 EWS 7782-49.2
12/18/02 16:06 EWS 7440-22-4
12/17/02
12/09/02 WCB
Laboratory Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 37712 without the written consent of Pace Analytical Services, Inc.
W � b
� ac ,
Page: 6 of 8
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ceAnalyfical
M wo; ve.Pr3c,0,9bsxnm
r
i
Solid results are reported on a dry weight basis
Lab Sample No: 93142099E
Client Sample ID: WWTP SLUDGE
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC28078
Phone. [phone]
Fax: [phone]
Lab Project Number: 9239317
Client Project ID: BRPP 9334878
Project Sample Number: 9239317-001 Date Collected: 12/06/02 15:15
Matrix: Soil Date Received: 12/06/02 16:55
Parameters Results Units Report Limit DF Analyzed By CAS No. Oual RegLmt
Metals
Mercury, CVAAS, TCLP Leachate Method: EPA 7470
Date Digested 12/15/02 12/15/02
Mercury, CVAAS, TCLP Leachate
Method: EPA
7470
Mercury
ND
mg/1
0.00020
1.0
12/17/02
LBG
7439-97-6
GC/MS Semivolatiles
Semivolatile Organics, TCLP
Prep/Method:
EPA 3510
/ EPA 8270
1,4-Dichlorobenzene
ND
mg/1
0.75
1.0
12/18/02
13:12
BET
106-46-7
2,4-Dinitrotoluene
ND
mg/1
0.013
1.0
12/18/02
13:12
BET
121-14-2
Hexachloro-1,3-butadiene
ND
mg/1
0.050
1.0
12/18/02
13:12
BET
87-68-3
Hexachlorobenzene
ND
mg/1
0.013
1.0
12/18/02
13:12
BET
118-74-1
Hexachloroethane
ND
mg/1
0.30
1.0
12/18/02
13:12
BET
67-72-1
2-Methylphenol (o-Cresol)
ND
mg/l
20.
1.0
12/18/02
13:12
BET
95-48-7
3&4-Methylphenol
ND
mg/1
20.
1.0
12/18/02
13:12
BET
Nitrobenzene
ND
mg/l
0.20
1.0
12/18/02
13:12
BET
98-95-3
Pentachlorophenol
ND
mg/l
10.
1.0
12/18/02
13:12
BET
87-86-5
Pyridine
ND
mg/1
0.50
1.0
12/18/02
13:12
BET
110-86-1
2,4,5-Trichlorophenol
ND
mg/1
40.
1.0
12/18/02
13:12
BET
95-95-4
2,4,6-Trichlorophenol
ND
mg/1
0.20
1.0
12/18/02
13:12
BET
88-06-2
Nitrobenzene-d5 (S)
60
%
1.0
12/18/02
13:12
BET
4165-60-0
2-Fluorobiphenyl (S)
61
%
1.0
12/18/02
13:12
BET
321-60-8
Terphenyl-dl4 (S)
83
%
1.0
12/18/02
13:12
BET
1718-51-0
Phenol-d5 (S)
22
%
1.0
12/18/02
13:12
BET
4165-62-2
2-Fluorophenol (S)
34
%
1.0
12/18/02
13:12
BET
367-12-4
2,4,6-Tribromophenol (S)
79
%
1.0
12/18/02
13:12
BET
Date Extracted
12/16/02
12/16/02
GC/MS Volatiles
Volatile Organics, TCLP Leach.
Method: EPA
8260
Benzene
ND
mg/1
0.010
1.0
12/16/02
16:55
RWS
71-43-2
2-Butanone (MEK)
0.022
mg/1
0.010
1.0
12/16/02
16:55
RWS
78-93-3
Carbon tetrachloride
ND
mg/l
0.010
1.0
12/16/02
16:55
RWS
56-23-5
Chlorobenzene
ND
mg/l
0.010
1.0
12/16/02
16:55
RWS
108-90-7
Chloroform
ND
mg/1
0.010
1.0
12/16/02
16:55
RWS
67-66-3
1,2-Dichloroethane
ND
mg/l
0.010
1.0
12/16/02
16:55
RWS
107-06-2
1,1-Dichloroethene
ND
mg/1
0.010
1.0
12/16/02
16:55
RWS
75-35-4
Date: 12/20/02
I ahoratory Certification ID s REPORT OF LABORATORY ANALYSIS Laboratory Certification ID
NC Wastewater 12 KY Drinking Water 90090
NC Drinking Water 37706 This report shall not be reproduced, except in full, VA Drinking Water 213
Sc 99006 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627
Page: 1 of 21

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i
Lab Sample No: 931420996
Client Sample ID: WWTP SLUDGE
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Hunieisville, NC 28078
Phone:[phone]
Fax: [phone]
Lab Project Number: 9239317
Client Project ID: BRPP 9334878
Project Sample Number: 9239317-001 Date Collected: 12/06/02 15:15
Matrix: Soil Date Received: 12/06/02 16:55
Parameters
Results
Units
Report Limit
DF
Analyzed
By
CAS No. Oual RegLmt
Tetrachloroethene
ND
mg/1
0.010
1.0
12/16/02
16:55
RWS
127-18-4
Trichloroethene
ND
mg/l
0.010
1.0
12/16/02
16:55
RWS
79-01-6
Vinyl chloride
ND
mg/1
0.010
1.0
12/16/02
16:55
RWS
75-01-4
Toluene-d8 (S)
101
%
1.0
12/16/02
16:55
RWS
2037-26-5
4-Bromofluorobenzene (S)
104
%
1.0
12/16/02
16:55
RWS
460-00-4
Dibromofluoromethane (S)
105
%
1.0
12/16/02
16:55
RWS
1868-53-7
1,2-Dichloroethane-d4 (S)
98
%
1.0
12/16/02
16:55
RWS
17060-07-0
Date: 12/20/02
Iaborato Cerlification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
I ahoratory Certification IDs
REPORT OF LABORATORY ANALYSIS KY Drinking Water 90090
This report shall not be reproduced, except in full, VA Drinking Water 213
without the written consent of Pace Analytical Services, Inc. FL NELAP E87627
Page: 2 of 21

Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Analj&af* Nuntersville, NC 28078
Phone:[phone]
n:avr. �4�* S,9as:i i1m fax: [phone]
Lab Project Number: 9239317
Client Project ID: BRPP 9334878
--------------------
Lab Sample No 931421002 Project Sample Number: 9239317-002 Date Collected: 12/06/02 13:20
Client Sample ID: LIME MUD Matrix: Soil Date Received: 12/06/02 16:55
Parameters Results Units Report Limit IF Analyzed By CAS No. Oual ReaLmt
Metals
Mercury, CVAAS, TCLP Leachate Method: EPA 7470
Date Digested 12/15/02 12/15/02
Mercury, CVAAS, TCLP Leachate
Method: EPA
7470
Mercury
ND
mg/l
0.00020
1.0
12/17/02
LBG
7439-97-6
GC/MS Semivolatiles
Semivolatile Organics, TCLP
Prep/Method:
EPA 3510 /
EPA 8270
1,4-Dichlorobenzene
ND
mg/l
0.75
1.0
12/18/02
13:50
BET
106-46-7
2,4-Dinitrotoluene
ND
mg/1
0.013
1.0
12/18/02
13:50
BET
121-14-2
Hexachloro-1,3-butadiene
ND
mg/1
0.050
1.0
12/18/02
13:50
BET
87-68-3
Hexachlorobenzene
ND
mg/1
0.013
1.0
12/18/02
13:50
BET
118-74-1
Hexachloroethane
ND
mg/l
0.30
1.0
12/18/02
13:50
BET
67-72-1
2-Methylphenol (o-Cresol)
ND
mg/1
20.
1.0
12/18/02
13:50
BET
95-48-7
3&4-Methylphenol
ND
mg/1
20.
1.0
12/18/02
13:50
BET
Nitrobenzene
ND
mg/l
0.20
1.0
12/18/02
13:50
BET
98-95-3
Pentachlorophenol
ND
mg/1
10.
1.0
12/18/02
13:50
BET
87-86-5
Pyridine
ND
mg/l
0.50
1.0
12/18/02
13:50
BET
110-86-1
2,4,5-Trichlorophenol
ND
mg/l
40.
1.0
12/18/02
13:50
BET
95-95-4
2,4,6-Trichlorophenol
ND
mg/1
0.20
1.0
12/18/02
13:50
BET
88-06-2
Nitrobenzene-d5 (S)
76
%
1.0
12/18/02
13:50
BET
4165-60-0
2-Fluorobiphenyl (S)
75
%
1.0
12/18/02
13:50
BET
321-60-8
Terphenyl-dl4 (S)
91
%
1.0
12/18/02
13:50
BET
1718-51-0
Phenol-d5 (S)
29
%
1.0
12/18/02
13:50
BET
4165-62-2
2-Fluorophenol (S)
47
%
1.0
12/18/02
13:50
BET
367-12-4
2,4,6-Tribromophenol (S)
87
%
1.0
12/18/02
13:50
BET
Date Extracted
12/16/02
12/16/02
GC/MS Volatiles
Volatile Organics, TCLP Leach.
Method: EPA
8260
Benzene
ND
mg/1
0.010
1.0
12/19/02
18:48
RWS
71-43-2
2-Butanone (MER)
ND
mg/1
0.010
1.0
12/19/02
18:48
RWS
78-93-3
Carbon tetrachloride
ND
mg/1
0.010
1.0
12/19/02
18:48
RWS
56-23-5
Chlorobenzene
ND
mg/l
0.010
1.0
12/19/02
18:48
RWS
108-90-7
Chloroform
ND
mg/1
0.010
1.0
12/19/02
18:48
RWS
67-66-3
1,2-Dichloroethane
ND
mg/1
0.010
1.0
12/19/02
18:48
RWS
107-06-2
1,1-Dichloroethene
ND
mg/1
0.010
1.0
12/19/02
18:48
RWS
75-35-4
Tetrachloroethene
ND
mg/1
0.010
1.0
12/19/02
18:48
RWS
127-18-4
Date: 12/20/02
I C Wastewater
Certification ID s REPORT OF LABORATORY ANALYSIS I abnking v Certification IDs
NC Wastewater 12 KY Drinking Water 90090
NC Drinking Water 37706 This report shall not be reproduced, except in full, VA Drinking Water 213
Sc 99006 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627
Page: 3 of 21

fi iYeNl.�i74�£St3JS.-�t)dYJ
Lab Sample No: 931421002
Client Sample ID: LIME MUD
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Lab Project Number: 9239317
Client Project ID: BRPP 9334878
Project Sample Number: 9239317-002 Date Collected: 12/06/02 13:20
Matrix: Soil Date Received: 12/06/02 16:55
Parameters
Results
Units
Report Limit DF
Analyzed
By
CAS No. Oual ReaLmt
Trichloroethene
ND
mg/1
0.010 1.0
12/19/02
18:48
RWS
79-01-6
Vinyl chloride
ND
mg/1
0.010 1.0
12/19/02
18:48
RWS
75-01-4
Toluene -dB (S)
101
%
1.0
12/19/02
18:48
RWS
2037-26-5
4-Bromofluorobenzene (S)
90
%
1.0
12/19/02
18:48
RWS
460-00-4
Dibromofluoromethane (S)
105
%
1.0
12/19/02
18:48
RWS
1868-53-7
1,2-Dichloroethane-d4 (S)
96
%
1.0
12/19/02
18:48
RWS
17060-07-0
Date: 22/20/02
I aborato Certification IDs
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
Laboratory Certification IDs
REPORT OF LABORATORY ANALYSIS KY Drinking Water 90090
This report shall not be reproduced, except in full, VA Drinking Water 213
without the written consent of Pace Analytical Services, Inc. FL NELAP E87627
Page: 4 of 21

Analj4ical a
h vm. f ii3r61.gaS:ziw
Lab Sample No: 931421010
Client Sample ID: SLAKER GRITS
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Nuntersville, NC 28078
Phone: [phone]
Fax: [phone]
Lab Project Number: 9239317
Client Project ID: BRPP 9334878
Project Sample Number: 9239317-003 Date Collected: 12/06/02 13:50
Matrix: Soil Date Received: 12/06/02 16:55
Parameters Results Units Report Limit DF Analyzed By CAS No. Oual RegLmt
Metals
Mercury, CVAAS, TCLP Leachate Method: EPA 7470
Date Digested 12/15/02 12/15/02
Mercury, CVAAS, TCLP Leachate
Method: EPA
7470
Mercury
ND
mg/l
0.00020
1.0
12/17/02
LBG
7439-97-6
GC/MS Semivolatiles
Semivolatile Organics, TCLP
Prep/Method:
EPA 3510
/ EPA 8270
1,4-Dichlorobenzene
ND
mg/1
0.75
1.0
12/18/02
14:27
BET
106-46-7
2,4-Dinitrotoluene
ND
mg/1
0.013
1.0
12/18/02
14:27
BET
121-14-2
Hexachloro-1,3-butadiene
ND
mg/1
0.050
1.0
12/18/02
14:27
BET
87-68-3
Hexachlorobenzene
ND
mg/1
0.013
1.0
12/18/02
14:27
BET
118-74-1
Hexachloroethane
NO
mg/l
0.30
1.0
12/18/02
14:27
BET
67-72-1
2-Methylphenol (o-Cresol)
NO
mg/1
20.
1.0
12/18/02
14:27
BET
95-48-7
3&4-Methylphenol
ND
mg/1
20.
1.0
12/18/02
14:27
BET
Nitrobenzene
ND
mg/l
0.20
1.0
12/18/02
14:27
BET
98-95-3
Pentachlorophenol
ND
mg/l
10.
1.0
12/18/02
14:27
BET
87-86-5
Pyridine
ND
mg/1
0.50
1.0
12/18/02
14:27
BET
110-86-1
2,4,5-Trichlorophenol
ND
mg/l
40.
1.0
12/18/02
14:27
BET
95-95-4
2,4,6-Trichlorophenol
ND
mg/l
0.20
1.0
12/18/02
14:27
BET
88-06-2
Nitrobenzene-d5 (S)
49
%
1.0
12/18/02
14:27
BET
4165-60-0
2-Fluorobiphenyl (S)
49
%
1.0
12/18/02
14:27
BET
321-60-8
Terphenyl-dl4 (S)
77
%
1.0
12/18/02
14:27
BET
1718-51-0
Phenol-d5 (S)
23
%
1.0
12/18/02
14:27
BET
4165-62-2
2-Fluorophenol (S)
36
%
1.0
12/18/02
14:27
BET
367-12-4
2,4,6-Tribromophenol (S)
64
%
1.0
12/18/02
14:27
BET
Date Extracted
12/16/02
12/16/02
GC/MS Volatiles
Volatile Organics, TCLP Leach.
Method: EPA
8260
Benzene
ND
mg/1
0.010
1.0
12/19/02
19:05
RWS
71-43-2
2-Butanone (MER)
ND
mg/1
0.010
1.0
12/19/02
19:05
RWS
78-93-3
Carbon tetrachloride
ND
mg/l
0.010
1.0
12/19/02
19:05
RWS
56-23-5
Chlorobenzene
ND
mg/l
0.010
1.0
12/19/02
19:05
RWS
108-90-7
Chloroform
ND
mg/1
0.010
1.0
12/19/02
19:05
RWS
67-66-3
1,2-Dichloroethane
ND
mg/1
0.010
1.0
12/19/02
19:05
RWS
107-06-2
1,1-Dich1oroethene
ND
mg/l
0.010
1.0
12/19/02
19:05
RWS
75-35-4
Tetrachloroethene
ND
mg/1
0.010
1.0
12/19/02
19:05
RWS
127-18-4
Date: 12/20/02
t aboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
laboratory Certification IDs
REPORT OF LABORATORY ANALYSIS KY Drinking Water 9OD90
This report shall not be reproduced, except in full, VA Drinking Water 213
without the written consent of Pace Analytical Services, Inc. FL NELAP E87627
Page: 5 of 21

h 1vr.,t;�sresFaas:stam
Lab Sample No: 931421010
Client Sample ID: SLAKSR GRITS
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
far: 704.875.9091
Lab Project Number: 9239317
Client Project ID: BRPP 9334878
Project Sample Number: 9239317-003 Date Collected: 12/06/02 13:50
Matrix: Soil Date Received: 12/06/02 16:55
Parameters
Results
Units
Report Limit DF
Analyzed
By
CAS No. Oual ReaLmt
Trichloroethene
ND
mg/1
0.010 1.0
12/19/02
19:05
RWS
79-01-6
Vinyl chloride
ND
mg/l
0.010 1.0
12/19/02
19:05
RWS
75-01-4
Toluene-d8 (S)
103
%
1.0
12/19/02
19:05
RWS
2037-26-5
4-Bromofluorobenzene (S)
96
%
1.0
12/19/02
19:05
RWS
460-00-4
Dibromofluoromethane (S)
0
%
1.0
12/19/02
19:05
RWS
1868-53-7 1
1,2-Dichloroethane-d4 (S)
98
%
1.0
12/19/02
19:05
RWS
17060-07-0
Date: 12/20/02
borato Certification IDs
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
I nhoratory Certification IDs
REPORT OF LABORATORY ANALYSIS KY Drinking Water 90090
This report shall not be reproduced, except in full, VA Drinking Water 213
without the written consent of Pace Anahaical Services, Inc. FL NELAP E87627
Page: 6 of 21

1?1!';a7Ce
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Hunteisville, NC 28078
Phone: [phone]
Fax: [phone]
Lab Project Number: 9239317
Client Project ID: BRPP 9334878
Lab Sample No: 931421028
Project Sample Number: 9239317-004
Date Collected: 12/06/02 13:30
Client Sample ID: PRECOAT FILTER
DREGS
Matrix: Soil
Date Received: 12/06/02 16:55
Parameters
Results Units
Report Limit DF Analyzed
By CAS No. Qual RegLmt
Metals
Mercury, CVAAS, TCLP Leachate
Method: EPA 7470
Date Digested
12/15/02
12/15/02
Mercury, CVAAS, TCLP Leachate
Method: EPA
7470
Mercury
ND
mg/1
0.00020
1.0
12/17/02
LBG
7439-97-6
GC/MS Selnivolatiles
Semivolatile Organics, TCLP
Prep/Method:
EPA 3510 /
EPA 8270
1, 4 -Dichlorobenzene
ND
mg/l
0.75
1.0
12/18/02
16:18
BET
106-46-7
2,4-Dinitrotoluene
ND
mg/1
0.013
1.0
12/18/02
16:18
BET
121-14-2
Hexachloro-1,3-butadiene
ND
mg/1
0.050
1.0
12/18/02
16:18
BET
87-68-3
Hexachlorobenzene
ND
mg/l
0.013
1.0
12/18/02
16:18
BET
118-74-1
Hexachloroethane
ND
mg/1
0.30
1.0
12/18/02
16:18
BET
67-72-1
2-Methylphenol (o-Cresol)
ND
mg/1
20.
1.0
12/18/02
16:18
BET
95-4B-7
3&4-Methylphenol
ND
mg/1
20.
1.0
12/18/02
16:18
BET
Nitrobenzene
ND
mg/1
0.20
1.0
12/18/02
16:18
BET
98-95-3
Pentachlorophenol
ND
mg/1
10.
1.0
12/18/02
16:18
BET
87-86-5
Pyridine
ND
mg/l
0.50
1.0
12/18/02
16:18
BET
110-86-1
2,4,5-Trichlorophenol
ND
mg/1
40.
1.0
12/18/02
16:18
BET
95-95-4
2,4,6-Trichlorophenol
ND
mg/1
0.20
1.0
12/18/02
16:18
BET
88-06-2
Nitrobenzene-d5 (S)
67
%
1.0
12/18/02
16:18
BET
4165-60-0
2-Fluorobiphenyl (S)
70
%
1.0
12/18/02
16:18
BET
321-60-8
Terphenyl-dl4 (S)
83
%
1.0
12/18/02
16:18
BET
1718-51-0
Phenol-d5 (8)
27
%
1.0
12/18/02
16:1B
BET
4165-62-2
2-Fluorophenol (S)
44
%
1.0
12/18/02
16:18
BET
367-12-4
2,4,6-Tribromophenol (S)
78
%
1.0
12/18/02
16:18
BET
Date Extracted
12/16/02
12/16/02
GC/MS Volatiles
Volatile Organics, TCLP Leach.
Method: EPA
8260
Benzene
ND
mg/1
0.010
1.0
12/19/02
19:21
RWS
71-43-2
2-Butanone (MER)
ND
mg/1
0.010
1.0
12/19/02
19:21
RWS
78-93-3
Carbon tetrachloride
ND
mg/1
0.010
1.0
12/19/02
19:21
RWS
56-23-5
Chlorobenzene
ND
mg/1
0.010
1.0
12/19/02
19:21
RWS
108-90-7
Chloroform
ND
mg/1
0.010
1.0
12/19/02
19:21
RWS
67-66-3
1,2-Dichloroethane
ND
mg/l
0.010
1.0
12/19/02
19:21
RWS
107-06-2
1,1-Dichloroethene
ND
mg/1
0.010
1.0
12/19/02
19:21
RWS
75-35-4
Tetrachloroethene
ND
mg/l
0.010
1.0
12/19/02
19:21
RWS
127-18-4
Date: 12/20/02
bWast Certification IDs REPORT OF LABORATORY ANALYSIS )abnratoty Certification IDs
NC Wastewater 12 KY Drinking Water 90090
NC Drinking Water 37706 This report shall not be reproduced, except in full, VA Drinking Water 213
Sc 99006 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627
Page: 7 of 21

n:%vr.p6c0ab,;.v am
Lab Sample No: 931421028
Client Sample ID: PRECOAT FILTER DREGS
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Lab Project Number: 9239317
Client Project ID: BRPP 9334878
Project Sample Number: 9239317-004 Date Collected: 12/06/02 13:30
Matrix: Soil Date Received: 12/06/02 16:55
Parameters
Results
Units
Rei)ort Limit DF
Analyzed
By
CAS No. Oual RegLmt
Trichloroethene
ND
mg/l
0.010 1.0
12/19/02
19:21
RWS
79-01-6
Vinyl chloride
ND
mg/l
0.010 1.0
12/19/02
19:21
RWS
75-01-4
Toluene-d8 (S)
100
%
1.0
12/19/02
19:21
RWS
2037-26-5
4-Bromofluorobenzene (S)
88
%
1.0
12/19/02
19:21
RWS
460-00-4
Dibromofluoromethane (S)
85
%
1.0
12/19/02
19:21
RWS
1868-53-7
1,2-Dichloroethane-d4 (S)
103
%
1.0
12/19/02
19:21
RWS
17060-07-0
Date: 12/20/02
I aborato ertitication IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Laboratory Certification IDs
REPORT OF LABORATORY ANALYSIS KY Drinking Water 90090
This report shall not be reproduced, except in full, VA Drinking Water 213
without the written consent of Pace Analytical Services, Inc. FL NELAP E87627
Page: a of 21

1 , aceAna1j&a1 "'
vsrvr.r>srssgbs:snm
t
f
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Lab Project Number: 9239317
Client Project ID: BRPP 9334878
Lab Sample No: 931421036 Project Sample Number: 9239317-005 Date Collected: 12/06/02 14:00
Client Sample ID: FLY ASH Matrix: Soil Date Received: 12/06/02 16:55
Parameters Results Units Report Limit DF Analyzed By CAS No. Oual ReaLmt
Metals
Mercury, CVAAS, TCLP Leachate Method: EPA 7470
Date Digested 12/15/02 12/15/02
Mercury, CVAAS, TCLP Leachate
Method: EPA
7470
Mercury
ND
mg/1
0.00020
1.0
12/17/02
LBG
7439-97-6
GC/MS Semivolatiles
Semivolatile Organics, TCLP
Prep/Method:
EPA 3510
/ EPA 8270
1,4-Dichlorobenzene
ND
mg/1
0.75
1.0
12/18/02
16:55
BET
106-46-7
2,4-Dinitrotoluene
ND
mg/1
0.013
1.0
12/18/02
16:55
BET
121-14-2
Hexachloro-1,3-butadiene
ND
mg/1
0.050
1.0
12/18/02
16:55
BET
87-68-3
Hexachlorobenzene
ND
mg/1
0.013
1.0
12/18/02
16:55
BET
118-74-1
Hexachloroethane
ND
mg/1
0.30
1.0
12/18/02
16:55
BET
67-72-1
2-Methylphenol (o-Cresol)
ND
mg/l
20.
1.0
12/18/02
16:55
BET
95-48-7
3&4-Methylphenol
ND
mg/1
20.
1.0
12/18/02
16:55
BET
Nitrobenzene
ND
mg/l
0.20
1.0
12/18/02
16:55
BET
98-95-3
Pentachlorophenol
ND
mg/l
10.
1.0
12/18/02
16:55
BET
87-86-5
Pyridine
ND
mg/l
0.50
1.0
12/18/02
16:55
BET
110-86-1
2,4,5-Trichlorophenol
ND
mg/1
40.
1.0
12/18/02
16:55
BET
95-95-4
2,4,6-Trichlorophenol
ND
mg/1
0.20
1.0
12/18/02
16:55
BET
88-06-2
Nitrobenzene-d5 (S)
62
%
1.0
12/18/02
16:55
BET
4165-60-0
2-Fluorobiphenyl (S)
63
%
1.0
12/18/02
16:55
BET
321-60-8
Terphenyl-dl4 (S)
83
%
1.0
12/18/02
16:55
BET
1718-51-0
Phenol-d5 (S)
22
`:
1.0
12/18/02
16:55
BET
4165-62-2
2-Fluorophenol (S)
38
%
1.0
12/18/02
16:55
BET
367-12-4
2,4,6-Tribromophenol (S)
72
%
1.0
12/18/02
16:55
BET
Date Extracted
12/16/02
12/16/02
GC/MS Volatiles
Volatile Organics, TCLP Leach.
Method: EPA
8260
Benzene
ND
mg/1
0.010
1.0
12/19/02
19:38
RWS
71-43-2
2-Butanone (MEK)
NO
mg/l
0.010
1.0
12/19/02
19:38
RWS
78-93-3
Carbon tetrachloride
ND
mg/1
0.010
1.0
12/19/02
19:38
RWS
56-23-5
Chlorobenzene
NO
mg/1
0.010
1.0
12/19/02
19:38
RWS
108-90-7
Chloroform
ND
mg/l
0.010
1.0
12/19/02
19:38
RWS
67-66-3
1,2-Dichloroethane
ND
mg/l
0.010
1.0
12/19/02
19:38
RWS
107-06-2
1,1-Dichloroethene
ND
mg/l
0.010
1.0
12/19/02
19:38
RWS
75-35-4
Tetrachloroethene
ND
mg/1
0.010
1.0
12/19/02
19:38
RWS
127-18-4
Date: 12/20/02
Laboratory Certification ID REPORT OF LABORATORY ANALYSIS Inboratory Certification lDs
NC Wastewater 12 KY Drinking Water 90090
NC Drinking Water 37706 This report shall not be reproduced, except in full, VA Drinking Water 213
Sc 99006 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627
Page: 9 of 21

Anal al-
n , rvr.;;scesf�a5:ctam
Lab Sample No: 931421036
Client Sample ID: FLY ASH
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Hunteisville, NC 28078
Phone: [phone]
Fax: [phone]
Lab Project Number: 9239317
Client Project ID: BRPP 9334878
Project Sample Number: 9239317-005 Date Collected: 12/06/02 14:00
Matrix: Soil Date Received: 12/06/02 16:55
Parameters
Results
Units
Report Limit DF
Analyzed
By
CAS No. oual ReaLmt
Trichloroethene
ND
mg/1
0.010 1.0
12/19/02
19:38
RWS
79-01-6
Vinyl chloride
ND
mg/l
0.010 1.0
12/19/02
19:38
RWS
75-01-4
Toluene-d8 (S)
103
%
1.0
12/19/02
19:38
RWS
2037-26-5
4-Bromofluorobenzene (S)
89
%
1.0
12/19/02
19:38
RWS
460-00-4
Dibromofluoromethane (S)
105
%
1.0
12/19/02
19:38
RWS
1868-53-7
1,2-Dichloroethane-d4 (S)
100
%
1.0
12/19/02
19:38
RWS
17060-07-0
Date: 12/20/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
REPORT OF LABORATORY ANALYSIS KY nkingrWatefificati9
D0090
This report shall not be reproduced, except in full, VA Drinking Water 213
without the written consent of Pace Analytical Services, Inc. FL NELAP E87627
Page: 10 of 21

Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
/I �� J t���� ��* Huntersville, NC 28078
J Phone:[phone]
�s:rvr.t;�soes's'as:: ttm Fax [phone]
Lab Project Number: 9239317
Client Project ID: BRPP 9334878
Lab Sample No: 931421044 Project Sample Number: 9239317-006 Date Collected: 12/06/02 14:20
Client Sample ID: CINDERS Matrix: Soil Date Received: 12/06/02 16:55
Parameters Results Units Report Limit DF Analyzed By CAS No. Oual ReoLmt
Metals
Mercury, CVAAS, TCLP Leachate Method: EPA 7470
Date Digested 12/15/02 12/15/02
Mercury, CVAAS, TCLP Leachate
Method: EPA
7470
Mercury
ND
mg/1
0.00020
1.0
12/17/02
LBG
7439-97-6
GC/MS Semivolatiles
Semivolatile Organics, TCLP
Prep/Method:
EPA 3510
/ EPA 8270
1,4-Dichlorobenzene
ND
mg/i
0.75
1.0
12/18/02
17:33
RPJ
106-46-7
2,4-Dinitrotoluene
ND
mg/1
0.013
1.0
12/18/02
17:33
RPJ
121-14-2
Hexachloro-1,3-butadiene
ND
mg/1
0.050
1.0
12/18/02
17:33
RPJ
87-68-3
Hexachlorobenzene
ND
mg/1
0.013
1.0
12/18/02
17:33
RPJ
118-74-1
Hexachloroethane
ND
mg/l
0.30
1.0
12/18/02
17:33
RPJ
67-72-1
2-Methylphenol (o-Cresol)
ND
mg/1
20.
1.0
12/18/02
17:33
RPJ
95-48-7
3&4-Methylphenol
ND
mg/l
20.
1.0
12/18/02
17:33
RPJ
Nitrobenzene
ND
mg/1
0.20
1.0
12/18/02
17:33
RPJ
98-95-3
Pentachlorophenol
ND
mg/l
10.
1.0
12/18/02
17:33
RPJ
87-86-5
Pyridine
ND
mg/1
0.50
1.0
12/18/02
17:33
RPJ
110-86-1
2,4,5-Trichlorophenol
ND
mg/l
40.
1.0
12/18/02
17:33
RPJ
95-95-4
2,4,6-Trichlorophenol
ND
mg/l
0.20
1.0
12/18/02
17:33
RPJ
88-06-2
Nitrobenzene-d5 (S)
60
%
1.0
12/18/02
17:33
RPJ
4165-60-0
2-Fluorobiphenyl (S)
61
%
1.0
12/18/02
17:33
RPJ
321-60-8
Terphenyl-dl4 (S)
83
%
1.0
12/18/02
17:33
RPJ
1718-51-0
Phenol-d5 (S)
23
%
1.0
12/18/02
17:33
RPJ
4165-62-2
2-Fluorophenol (S)
37
%
1.0
12/18/02
17:33
RPJ
367-12-4
2,4,6-Tribromophenol (S)
74
%
1.0
12/18/02
17:33
RPJ
Date Extracted
12/16/02
12/16/02
GC/MS Volatiles
Volatile Organics, TCLP Leach.
Method: EPA
8260
Benzene
ND
mg/1
0.010
1.0
12/19/02
19:54
RWS
71-43-2
2-Butanone (MER)
ND
mg/l
0.010
1.0
12/19/02
19:54
RWS
78-93-3
Carbon tetrachloride
ND
mg/l
0.010
1.0
12/19/02
19:54
RWS
56-23-5
Chlorobenzene
ND
mg/l
0.010
1.0
12/19/02
19:54
RWS
108-90-7
Chloroform
ND
mg/l
0.010
1.0
12/19/02
19:54
RWS
67-66-3
1,2-Dichloroethane
ND
mg/1
0.010
1.0
12/19/02
19:54
RWS
107-06-2
1,1-Dichloroethene
ND
mg/l
0.010
1.0
12/19/02
19:54
RWS
75-35-4
Tetrachloroethene
ND
mg/1
0.010
1.0
12/19/02
19:54
RWS
127-18-4
Date: 12/20/02
IaboratgryCertificationIDs REPORT OF LABORATORY ANALYSIS IahoratoryC rtifi
NC Wastewater 12 KY Drinking Water 90090
NC Drinking Water 37706 This report shall not be reproduced, except in full, VA Drinking Water 213
Sc 99006 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627
Page: 11 of 21

h o.vi.pnjCehgbsxtim
Lab Sample No: 931421044
Client Sample ID: CINDERS
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone. [phone]
Fax: [phone]
Lab Project Number: 9239317
Client Project ID: BRPP 933487E
Project Sample Number: 9239317-006 Date Collected: 12/06/02 14:20
Matrix: Soil Date Received: 12/06/02 16:55
Parameters
Results
Units
Report Limit DF
Analyzed
By
CAS No. Oual RegLmt
Trichloroethene
ND
mg/l
0.010 1.0
12/19/02
19:54
RWS
79-01-6
Vinyl chloride
ND
mg/1
0.010 1.0
12/19/02
19:54
RWS
75-01-4
Toluene-d8 (S)
101
%
1.0
12/19/02
19:54
RWS
2037-26-5
4-Bromofluorobenzene (S)
85
%
1.0
12/19/02
19:54
RWS
460-00-4
Dibromofluoromethane (S)
115
%
1.0
12/19/02
19:54
RWS
1868-53-7
1,2-Dichloroethane-d4 (S)
108
%
1.0
12/19/02
19:54
RWS
17060-07-0
Date: 12/20/02
t aboratocy Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
laboratory Certification IDs
REPORT OF LABORATORY ANALYSIS KY Drinking Water 90090
This report shall not be reproduced, except in full, VA Drinking Water 213
without the written consent of Pace Analytical Services, Inc. FL NELAP E87627
Page: 12 of 21

Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
/� (
na44ica - Huntersville, NC 28078
Phone:[phone]
ss;avr.r> '0igb";.V am Fax: 704,875.9091
Lab Project Number: 9239317
Client Project ID: BRPP 9334878
PARAMETER FOOTNOTES
Dilution factor shown represents the factor applied to the reported result and reporting limit due to changes
in sample preparation, dilution of the extract, or moisture content
ND Not detected at or above adjusted reporting limit
NC Not Calculable
J Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MDL Adjusted Method Detection Limit
(S) Surrogate
Ill Low surrogate recovery was confirmed as a matrix effect by a second analysis.
Date: 12/20/02
I C Waste Certification ID s REPORT OF LABORATORY ANALYSIS LaboratoryCertification IDs
NC Wastewater 12 KY Drinking Water 90090
NC Drinking Water 37706 This report shall not be reproduced, except in full, VA Drinking Water 213
Sc 99006 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627
Page: 13 of 21

laowk
1 f GiileAnal ica
f
i
QC Batch: 67596
QC Batch Method: EPA 3510
Associated Lab Samples: 931420996
931421044
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone.: [phone]
Fax [phone]
QUALITY CONTROL DATA
Lab Project Number: 9239317
Client Project ID: BRPP 9334878
Analysis Method: EPA 8270
Analysis Description: Semivolatile Organics, TCLP
931421002 931421010 931421028 931421036
METHOD BLANK: 922698915
Associated Lab Samples: 931420996 931421002 931421010 931421028 931421036 931421044
Blank
Reporting
Parameter
Units
Result
Limit Footnotes
1,4-Dichlorobenzene
mg/l
ND
0.75
2,4-Dinitrotoluene
mg/l
ND
0.013
Hexachloro-1,3-butadiene
mg/l
ND
0.050
Hexachlorobenzene
mg/1
ND
0.013
Hexachloroethane
mg/1
ND
0.30
2-Methylphenol (o-Cresol)
mg/l
ND
20.
3&4-Methylphenol
mg/1
ND
20.
Nitrobenzene
mg/l
ND
0.20
Pentachlorophenol
mg/1
ND
10.
Pyridine
mg/l
ND
0.50
2,4,5-Trichlorophenol
mg/l
ND
40.
2,4,6-Trichlorophenol
mg/l
ND
0.20
Nitrobenzene-d5 (S)
%
62
2-Fluorobiphenyl (S)
%
60
Terphenyl-dl4 (S)
%
76
Phenol-d5 (S)
%
27
2-Fluorophenol (S)
%
44
2,4,6-Tribromophenol (S)
%
67
LABORATORY CONTROL SAMPLE: 922698923
Spike
LCS
LCS
Parameter
Units
Conc.
Result
Rec Footnotes
1,4-Dichlorobenzene
mg/l
0.2500
0.1471
59
2,4-Dinitrotoluene
mg/1
0.2500
0.2095
84
Hexachloro-1,3-butadiene
mg/l
0.2500
0.1310
52
Hexachlorobenzene
mg/l
0.2500
0.1792
72
Hexachloroethane
mg/l
0.2500
0.1458
58
2-Methylphenol (o-Cresol)
mg/1
0.2500
0.1351
54
Date: 12/20/02
Page: 14 of 21
Laboratory Certification ID s REPORT OF LABORATORY ANALYSIS l abnking • rtifi anon IDs
NC Wastewater 12 KY Drinking Water 90090
NC Drinking Water 37706 This report shall not be reproduced, except in full, VA Drinking Water 213
Sc 99006 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627

QUALITY CONTROL DATA
LABORATORY CONTROL SAMPLE: 922698923
Spike
LCS
Parameter
Units
Conc.
Result
3&4-Methylphenol
mg/1
0.2500
0.1387
Nitrobenzene
mg/1
0.2500
0.1599
Pentachlorophenol
mg/l
0.2500
0.1719
Pyridine
mg/1
0.2500
0.0487
2,4,5-Trichlorophenol
mg/1
0.2500
0.1683
2,4,6-Trichlorophenol
mg/1
0.2500
0.1687
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-dl4 (S)
Phenol-d5 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 922698931 922698949
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone:[phone]
Fax. [phone]
Lab Project Number: 9239317
Client Project ID: BRPP 9334878
LCS
Rec Footnotes
56
64
69
20
67
68
69
71
79
30
47
80
931421010
Spike
MS
MSD
MS
MSD
Parameter
Units
Result
Conc.
Result
Result %
Rec $
Rec
RPD Footnotes
1,4-Dichlorobenzene
mg/1
0
0.2500
0.1519
0.1565
61
63
3
2,4-Dinitrotoluene
mg/l
0
0.2500
0.1938
0.2116
78
85
9
Hexachloro-1,3-butadiene
mg/1
0
0.2500
0.1300
0.1266
52
51
3
Hexachlorobenzene
mg/1
0
0.2500
0.1587
0.1630
64
65
3
Hexachloroethane
mg/1
0
0.2500
0.1450
0.1493
58
60
3
2-Methylphenol (o-Cresol)
mg/1
0
0.2500
0.1365
0.1370
55
55
0
3&4-Methylphenol
mg/1
0
0.5000
0.1397
0.1390
28
28
0
Nitrobenzene
mg/1
0
0.2500
0.1583
0.1633
63
65
3
Pentachlorophenol
mg/l
0
0.2500
0.1555
0.1671
62
67
7
Pyridine
mg/1
0
0.2500
0.0402
0.0468
16
19
15
2,4,5-Trichlorophenol
mg/1
0
0.2500
0.1575
0.1703
63
68
8
2,4,6-Trichlorophenol
mg/1
0
0.2500
0.1549
0.1688
62
68
9
Nitrobenzene-d5 (S)
69
68
2-Fluorobiphenyl (S)
69
70
Terphenyl-dl4 (S)
74
75
Phenol-d5 (S)
32
31
2-Fluorophenol (S)
49
47
2,4,6-Tribromophenol (S)
71
74
Date: 12/20/02
Page: 15 of 21
Laboratory Certification ID REPORT OF LABORATORY ANALYSIS Laboratory Certification 90
NC Wastewater 12 KY Drinking Water 90090
NC Drinking Water 37706 This report shall not be reproduced, except in full, VA Drinking Water 213
Sc 99006 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627

QC Batch: 67614
QC Batch Method: EPA 8260
Associated Lab Samples:
931420996
METHOD BLANK: 922699285
Associated Lab Samples: 931420996
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Nuntersville, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Lab Project Number: 9239317
Client Project ID: BRPP 9334878
Analysis Method: EPA 8260
Analysis Description: Volatile Organics, TCLP Leach.
Blank
Reporting
Parameter
Units
Result
Limit Footnotes
Benzene
mg/1
ND
0.010
2-Butanone (MEK)
mg/1
ND
0.010
Carbon tetrachloride
mg/1
ND
0.010
Chlorobenzene
mg/l
ND
0.010
Chloroform
mg/l
ND
0.010
1,2-Dichloroethane
mg/l
ND
0.010
1,1-Dichloroethene
mg/1
ND
0.010
Tetrachloroethene
mg/1
ND
0.010
Trichloroethene
mg/1
ND
0.010
Vinyl chloride
mg/1
ND
0.010
Toluene -dB (S)
%
99
4-Bromofluorobenzene (S)
%
94
Dibromofluoromethane (S)
%
99
1,2-Dichloroethane-d4 (S)
%
88
LABORATORY CONTROL SAMPLE: 922699293
Parameter
Benzene
2-Butanone (MER)
Carbon tetrachloride
Chlorobenzene
Chloroform
1,2-Dichloroethane
1,1-Dichloroethene
Tetrachloroethene
Trichloroethene
Vinyl chloride
Toluene-d8 (8)
Date: 12/20/02
Laboratory rtifi Cation IDs
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
Spike
LCS
LCS
Units
Conc.
Result
Rec
mg/1
0.0500
0.0443
89
mg/l
0.1000
0.0721
72
mg/1
0.0500
0.0412
82
mg/l
0.0500
0.0451
90
mg/1
0.0500
0.0452
90
mg/1
0.0500
0.0457
91
mg/l
0.0500
0.0486
97
mg/l
0.0500
0.0406
81
mg/1
0.0500
0.0439
88
mg/1
0.0500
0.0447
89
101
Footnotes
laboratory • rtifi ition IDs
REPORT OF LABORATORY ANALYSIS KY Drinking Water 90090
This report shall not be reproduced, except in full, VA Drinking Water 213
without the written consent of Pace Analytical Services, Inc. FL NELAP E87627
Page: 16 of 21

l ✓' aalceA a44ical
�..,,...>�� vs:�.vr.,r>�s>r�s'sax:srlm
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Nuntersville, NC 28078
Phone: [phone]
Fax [phone]
Lab Project Number: 9239317
Client Project ID: BRPP 9334878
LABORATORY CONTROL SAMPLE: 922699293
Spike LCS LCS
Parameter Units Conc. Result Rec Footnotes
4-Bromofluorobenzene (8) 102
Dibromofluoromethane (8) 103
1,2-Dichloroethane-d4 (S) 105
MATRIX SPIKE & MATRIX SPIRE DUPLICATE: 922699301 922699319
922679394
Spike
MS
MSD
MS
MSD
Parameter
Units
Result
Conc.
Result
Result %
Rec
Rec
RPD
Footnotes
Benzene
mg/1
0
0.0500
0.0325
0.0457
65
91
34
1
2-Butanone (MEK)
mg/l
0.00209
0.1000
0.0588
0.0944
57
92
47
1
Carbon tetrachloride
mg/i
0
0.0500
0.0354
0.0516
71
103
37
1
Chlorobenzene
mg/1
0
0.0500
0.0355
0.0494
71
99
33
1
Chloroform
mg/1
0
0.0500
0.0317
0.0477
63
95
40
2,3
1,2-Dichloroethane
mg/1
0
0.0500
0.0302
0.0453
60
90
40
1
1,1-Dichloroethene
mg/1
0
0.0500
0.0362
0.0545
72
109
40
1
Tetrachloroethene
mg/1
0
0.0500
0.0321
0.0449
64
90
33
1
Trichloroethene
mg/1
0
0.0500
0.0344
0.0495
69
99
36
1
Vinyl chloride
mg/1
0
0.0500
0.0318
0.0450
64
90
34
1
Toluene -dB (S)
97
96
4-Bromofluorobenzene (S)
105
104
Dibromofluoromethane (S)
98
103
1,2-Dichloroethane-d4 (S)
90
99
Date: 12/20/02 Page: 17 of 21
laboratory Certification ID s REPORT OF LABORATORY ANALYSIS Laboratory GertlfFGatlon IDs
NC Wastewater 12 KY Drinking Water 90090
NC Drinking Water 37706 This report shall not be reproduced, except in full, VA Drinking Water 213
SC 99006 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627

Anal lt; al."
Pace Analytical Services, Inc.
9800 Kincey A venue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Lab Project Number: 9239317
Client Project ID: BRPP 9334878
QC Batch: 67829 Analysis Method: EPA 8260
QC Batch Method: EPA 8260 Analysis Description: Volatile Organics, TCLP Leach.
Associated Lab Samples: 931421002 931421010 931421028 931421036 931421044
METHOD BLANK: 922709399
Associated Lab Samples: 931421002 931421010 931421028 931421036 931421044
Parameter
Units
Benzene
mg/l
2-Butanone (MEK)
mg/l
Carbon tetrachloride
mg/1
Chlorobenzene
mg/1
Chloroform
mg/l
1,2-Dichloroethane
mg/1
1,1-Dichloroethene
mg/1
Tetrachloroethene
mg/1
Trichloroethene
mg/l
Vinyl chloride
mg/1
Toluene-d8 (S)
%
4-Bromofluorobenzene (S)
%
Dibromofluoromethane (S)
%
1,2-Dichloroethane-d4 (S)
%
LABORATORY CONTROL SAMPLE: 922709407
Parameter
Units
Benzene
mg/l
2-Butanone (MEK)
mg/1
Carbon tetrachloride
mg/l
Chlorobenzene
mg/1
Chloroform
mg/1
1,2-Dichloroethane
mg/1
1,1-Dichloroethene
mg/1
Tetrachloroethene
mg/1
Trichloroethene
mg/1
Vinyl chloride
mg/1
Toluene -dB (S)
Date: 12/20/02
Laborato Certification IDs
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
Blank
Reporting
Result
Limit Footnotes
ND
0.010
ND
0.010
ND
0.010
ND
0.010
ND
0.010
ND
0.010
ND
0.010
ND
0.010
ND
0.010
ND
0.010
100
88
99
96
Spike LCS LCS
Conc. Result Rec Footnotes
0.0500 0.0465 93
0.1000 0.0921 92
0.0500 0.0415 83
0.0500 0.0465 93
0.0500 0.0459 92
0.0500 0.0451 90
0.0500 0.0492 98
0.0500 0.0542 108
0.0500 0.0491 98
0.0500 0.0411 82
100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
t ahoratory Certification IDs
KY Drinking Water 90090
VA Drinking Water 213
FL NELAP E87627
Page: 18 of 21

Ana44ica
h 1r4>1pw0abs.c m
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Far: 704.875.9091
Lab Project Number: 9239317
Client Project ID: BRPP 9334878
LABORATORY CONTROL SAMPLE: 922709407
Spike LCS LCS
Parameter Units Conc. Result Rec Footnotes
4-Bromofluorobenzene (S) 102
Dibromofluoromethane (S) 99
1,2-Dichloroethane-d4 (S) 98
Date: 12/20/02
NC Wastewater
Certification IDs REPORT OF LABORATORY ANALYSIS L2borang Water
90
NC Wastewater 12 KY Drinking Water 90090
NC Drinking Water 37706 This report shall not be reproduced, except in full, VA Drinking Water 213
Sc 99006 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627
Page: 19 of 21

Analytical"'
Y, j,8oeMb,;.stam
Pace Analytical Services, Inc.
9800 Kincey A venue, Suite 100
Huntersville, NC 28078
Phone., 704.875.9092
Fax: [phone]
QUALITY CONTROL DATA
Lab Project Number: 9239317
Client Project ID: BRPP 9334878
QC Batch: 67595 Analysis Method: EPA 7470
QC Batch Method: EPA 7470 Analysis Description: Mercury, CVAAS, TCLP Leachate
Associated Lab Samples: 931420996 931421002 931421010 931421028 931421036
931421044
------------------------------- ---
METHOD BLANK: 922698840
Associated Lab Samples: 931420996 931421002 931421010 931421028 931421036 931421044
Blank Reporting
Parameter Units Result Limit Footnotes
Mercury mg/1 ND 0.0002
------------------------------------------------------------------
LABORATORY CONTROL SAMPLE: 922698857
Spike LCS LCS
Parameter Units Conc. Result Rec Footnotes
Mercury mg/1 0.0050 0.0048 96
--------------------------------------------------------
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 922698865 922698873
931421002 Spike MS MSD MS MSD
Parameter Units Result Conc. Result Result % Rec $ Rec RPD Footnotes
Mercury mg/l 0 0.0050 0.0049 0.0053 99 106 8
SAMPLE DUPLICATE: 922698881
931421010 DUP
Parameter Units Result Result RPD Footnotes
Mercury mg/1 ND ND NC
Date: 12/20/02
I aboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
Laboratory Certification IDs
REPORT OF LABORATORY ANALYSIS KY Drinking Water 90090
This report shall not be reproduced, except in full, VA Drinking Water 213
without the written consent of Pace Analytical Services, Inc. FL NELAP E87627
Page: 20 of 21

Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Analy����?��) �* Huntersville, NC 28078
tical { Phone:[phone]
Y�vr.�;14 est9+as:snm fax. [phone]
Lab Project Number: 9239317
Client Project ID: BRPP 9334878
QUALITY CONTROL DATA PARAMETER FOOTNOTES
Consistent with EPA guidelines, unrounded concentrations are displayed and have been used to calculate % Rec and RPD values.
LCS(D) Laboratory Control Sample (Duplicate)
MS(D) Matrix Spike (Duplicate)
DUP Sample Duplicate
ND Not detected at or above adjusted reporting limit
NC Not Calculable
J Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MDL Adjusted Method Detection Limit
RPD Relative Percent Difference
(S) Surrogate
Ill RPD value was outside of control limits, however % Recoveries were acceptable. Samples for QC batch
accepted based on `k recoveries and completeness of QC data.
[2) The surrogate and/or spike recovery was outside acceptance limits.
[31 The calculated RPD was outside QC acceptance limits.
Date: 12/20/02
Inhoratoa Certification IDs REPORT OF LABORATORY ANALYSIS I.�oratory Gertification IDs
NC Wastewater 12 KY Drinking Water 90090
NC Drinking Water 37706 This report shall not be reproduced, except in full, VA Drinking Water 213
SC 99006 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627
Page: 21 of 21

aceAnalXicalY"
www-. pace]abs.c-0m
1
Solid results are reported on a dry weight basis
Pace Analytical Services, Inc.
900 Gemini Avenue
Houston, TX 77058
Phone: [phone]
Far 281.488.4661
Lab Project Number: 8531389
Client Project ID: RXN/9334878/BRPP
Lab Sample No: 931420996 Project Sample Number: 8531389-001 Date Collected: 12/06/02 15:15
Client Sample ID: WWTP SLUDGE Matrix: Soil Date Received: 12/06/02 15:55
Parameters Results Units Report Limit DF Analyzed By CAS No. Oual ReqLmt
Wet Chemistry
Percent Moisture Method:
Percent Moisture 64.5 1.0 12/16/02 CSAN
Cyanide,
Reactive
Method:
SW-846 7.3.3.2
Cyanide,
Reactive
ND
mg/kg 0.458 0.9 12/16/02 15:00 TWES 250
Sulfide,
Reactive
Method:
SW-846 7.3.4.2
Sulfide,
Reactive
ND
mg/kg 45.8 0.9 12/17/02 16:20 TWES 500
Date: 12/18/02 Page: 1 of 8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.

;a'ceAna1j4ica1"
ww%upacelabs.com
t
Pace Analytical Services, Inc.
900 Gemini Avenue
Houston, TX 77058
Phone: [phone]
fax: [phone]
Lab Project Number: 8531389
Client Project ID: RXN/9334878/BRPP
Lab Sample No: 931421002
Project Sample
Number: 8531389-002
Date Collected: 12/06/02 13:20
Client Sample ID: LIME MUD
Matrix: Soil
Date Received: 12/06/02 16:55
Parameters
Results
Units
Report Limit
DF Analyzed
By CAS No. Oual RecLmt
Wet Chemistry
Percent Moisture
Method:
Percent Moisture
37.3
%
1.0 12/16/02
CSAN
Cyanide, Reactive
Method: SW-846
7.3.3.2
Cyanide, Reactive
ND
mg/kg
0.497
1.0 12/16/02 15:00
TWES 250
Sulfide, Reactive
Method: SW-846
7.3.4.2
Sulfide, Reactive
ND
mg/kg
49.7
1.0 12/17/02 16:20
TWES 500
Date: 12/18/02 Page: 2 of 8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.

aceAnalyticalY-y
viw�rpacetabs.cgm
PARAMETER FOOTNOTES
Dilution factor shown represents
in sample preparation, dilution o
Pace Analytical Services, Inc.
900 Gemini Avenue
Houston, TX 11058
Phone: [phone]
Fax: [phone]
Lab Project Number: 8531389
Client Project ID: RXN/9334878/BRPP
the factor applied to the reported result and reporting limit due to changes
f the extract, or moisture content
ND Not detected at or above adjusted reporting limit
NC Not Calculable
J Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MDL Adjusted Method Detection Limit
Date: 12/18/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page: 3 of 8

aceAnaIXical"
www.pace/abs.com
i
i
QC Batch: 77712
QC Batch Method:
Associated Lab Samples:
Pace Analytical Services, Inc.
900 Gemini Avenue
Houston, TX 77058
Phone: [phone]
far: 281.488.4661
QUALITY CONTROL DATA
Lab Project Number: 8531389
Client Project ID: RXN/9334878/BRPP
Analysis Method:
Analysis Description: Percent Moisture
931420996 931421002
METHOD BLANK: 851785998
Associated Lab Samples: 931420996 931421002
Blank Reporting
Parameter Units Result Limit Footnotes
Percent Moisture % 0 1.
SAMPLE DUPLICATE: 851785999
931421002 DUP
Parameter Units Result Result RPD Footnotes
Percent Moisture % 37.30 37.20 0
SAMPLE DUPLICATE: 851786000
Parameter Units
Percent Moisture %
Date: 12/18/02
20128123 DUP
Result Result RPD Footnotes
21.60 20.40 6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page: 4 of 8

aceAnalyticafo
w: nv pacel6bt.com
t
Pace Analytical Services, Inc.
900 Gemini Avenue
Houston, TX 77058
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Lab Project Number: 8531389
Client Project ID: RXN/9334878/BRPP
QC Batch: 77731 Analysis Method: SW-846 7.3.3.2
QC Batch Method: SW-846 7.3.3.2 Analysis Description: Cyanide, Reactive
Associated Lab Samples: 931420996 931421002
METHOD BLANK: 851786108
Associated Lab Samples: 931420996 931421002
Blank Reporting
Parameter Units Result Limit Footnotes
Cyanide, Reactive mg/kg ND 0.500
LABORATORY CONTROL SAMPLE: 851786109
Spike
LCS LCS
Parameter
Units
Conc.
Result % Rec Footnotes
Cyanide, Reactive
mg/kg
17.65
4.850 28
SAMPLE DUPLICATE: 851786110
851785535
DUP
Parameter
Units
Result
Result RPD Footnotes
Cyanide, Reactive
mg/kg
ND
ND NC
Date: 12/18/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page: 5 of 8

aceAna1j cal"
ww�vpacelebs.com
1
i
Pace Analytical Services, Inc.
900 Gemini Avenue
Houston, TX 77058
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Lab Project Number: 8531389
Client Project ID: RXN/9334878/BRPP
QC Batch: 77734 Analysis Method: SW-846 7.3.4.2
QC Batch Method: SW-846 7.3.4.2 Analysis Description: Sulfide, Reactive
Associated Lab Samples: 931420996 931421002
METHOD BLANK: 851786114
Associated Lab Samples: 931420996 931421002
Blank Reporting
Parameter Units Result Limit Footnotes
Sulfide, Reactive mg/kg ND 50.0
LABORATORY CONTROL SAMPLE: 851786115
Spike LCS LCS
Parameter Units Conc. Result % Rec Footnotes
Sulfide, Reactive mg/kg 1000.00 585.0 58
SAMPLE DUPLICATE: 851786116
Parameter Units
Sulfide, Reactive mg/kg
Date: 12/18/02
851785535 DUP
Result Result RPD Footnotes
ND ND NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page: 6 of 8

aceAnalXical "
vvvnv. pacefabs,com
QUALITY CONTROL DATA PARAMETER FOOTNOTES
Pace Analytical Services, Inc.
900 Gemini Avenue
Houston, TX 77058
Phone: [phone]
Fax [phone]
Lab Project Number: 8531389
Client Project ID: RXN/9334878/BRPP
Consistent with EPA guidelines, unrounded concentrations are displayed and have been used to calculate % Rec and RPD values.
LCS(D) Laboratory Control Sample (Duplicate)
MS(D) Matrix Spike (Duplicate)
DUP Sample Duplicate
ND Not detected at or above adjusted reporting limit
NC Not Calculable
J Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MDL Adjusted Method Detection Limit
RPD Relative Percent Difference
Date: 12/18/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page: 7 of 8

aceAnalj cal"
wvv�v.Pacelsbsxom
i
QUALITY CONTROL DATA
CROSS REFERENCE TABLE
Pace Analytical Services, Inc.
900 Gemini Avenue
Houston, IX 77058
Phone: [phone]
Fax: [phone]
Lab Project Number: 8531389
Client Project ID: RXN/9334878/BRPP
Analytical
Lab Sample No Client Sample QC Batch QC Batch Analytical Batch
Identifier Identifier Method Identifier Method Identifier
---------------------------- --------------- -----------------------------------
931420996
WWTP SLUDGE
77712
931421002
LIME MUD
77712
931420996
WWTP SLUDGE
SW-846
7.3.3.2
77731
931421002
LIME MUD
SW-846
7.3.3.2
77731
931420996
WWTP SLUDGE
SW-846
7.3.4.2
77734
931421002
LIME MUD
SW-846
7.3.4.2
77734
Date: 12/18/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page: 8 of 8

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revised 0412510211:37AM
f�
FACILITY COMPLIANCE AUDIT REPORT ,
-'Division of Waste Management
NCDENR
Solid Waste Section
NORTH CAROLINA DEPARTMENT OF
ENVIRONMENT AND NATURAL RESOURCES
UNIT TYPE: (check. all that apply to this audit with'same Permit number
Lined
LCID
YW
Transfer
Compost
SLAS
COUNTY: Haywood
MS WLF
Closed
HHW
White
Incin
T&P
FIRM
PERMIT NO.: 44-06
MS WLF
nods
CDLF
Tire T&P /
Tire
Industrial
x
DEMO
SDTF
FILE TYPE: COMPLIANCE
Collection
Monofill
Landfill
Date of Audit: 04/23/03
Date of Last Audit: 01/25/02
FACILITY NAME AND ADDRESS:
Blue Ridge Paper Products Industrial Landfill
State Road 1550
Canton, NC 28716
FACILITY CONTACT NAME AND PHONE NUMBER:
Jim Giauque
Telephone: [phone]
FACILITY CONTACT ADDRESS (IF DIFFERENT):
Jim Giauque
Blue Ridge Paper Products, Inc
175 Main Street
P.O. Box 4000
Canton, NC 28716
AUDIT PARTICIPANTS:
Jim Patterson, N.C. Solid Waste Section
Jim Giauque, Blue Ridge Paper Products, Inc.
STATUS OF PERMIT:
Active
PURPOSE OF AUDIT:
Inspection of industrial landfill.
NOTICE OF VIOLATIONS) (citation and explanation):
No violations observed.
You are hereby advised that, pursuant to N.C.G.S. 130A-22, an administrative penalty of up to $5,000 per day may be assessed for each
violation of the Solid Waste Statute or Regulations. If the violation(s) noted here continue, you may be subject to enforcement actions
including penalties, injunction from operation of a solid waste management facility or a solid waste collection service and any such
further relief as may be necessary to achieve compliance with the North Carolina Solid Waste Management Act and Rules.
STATUS OF PAST NOTED VIOLATIONS (List all noted last audit)
N/A
OTHER COMMENTS /SUGGESTIONS:
Operation looks good.

FACILITY COMPLIANCE AUDIT REPORT
Division of Waste Management
Solid Waste Section
Page 2 of 2
Please contact me if you have any questions or concerns regarding this audit report.
(signature) Phone: [phone].
Regional Representative
Distribution: original signed copy to facility -- signed copy to compliance officer e-mail or copy to super
Delivered on : 04/25/02 by I I hand delivery I X I US Mail I I Certified No. LI

revised 04125102 11.37 AM
FACILITY COMPLIANCE AUDIT REPORT
® Division of Waste Management
NCDENR Solid Waste Section,
NORTH CAROLINA DEPARTMENT Op -
ENVIRONMENT
AND NATURAL RESOURCES
UNIT TYPE: (check all that. applyto this audit with same.Permit'number. .
Lined LCID YW Transfer Compost SLAS MSWLF COUNTY. Haywood
Closed HHW White Incin T&P FIRM S WLF goods PERMIT NO.: 44-06
M
CDLF TireT&P/ Tire Industrial x DEMO SDTF FILE TYPE:, COMPLIANCE
Collection Monofill Landfill - -
Date of Audit: 04/23/03 Date of Last Audit: 01/25/02
FACILITY NAME AND ADDRESS:
Blue Ridge Paper Products Industrial Landfill
State Road 1550
Canton, NC 28716
FACILITY CONTACT NAME AND PHONE NUMBER:
Jim Giauque
Telephone: [phone]
FACILITY CONTACT ADDRESS (IF DIFFERENT)•
Jim Giauque
Blue Ridge Paper Products, Inc.
175 Main Street
P.O. Box 4000
Canton, NC 28716
AUDIT PARTICIPANTS:
Jim Patterson, N.C. Solid Waste Section
Jim Giauque, Blue Ridge Paper Products, Inc.
STATUS OF PERMIT:
Active
PURPOSE OF AUDIT:
Inspection of industrial landfill.
NOTICE OF VIOLATIONS) (citation and exulanation)•
No violations observed.
You are hereby advised that, pursuant to N.C.G.S. 130A-22, an administrative penalty of up to $5,000 per day may be assessed for each
violation of the Solid Waste Statute or Regulations. If the violation(s) noted here continue, you may be subject to enforcement actions
including penalties, injunction from operation of a solid waste management facility or a solid waste collection service and any such
further relief as may be necessary to achieve compliance with the North Carolina Solid Waste Management Act and Rules.
STATUS OF PAST NOTED VIOLATIONS (List all noted last audit):
N/A
OTHER COMMENTS /SUGGESTIONS:
Operation looks good.

FACILITY COMPLIANCE AUDIT REPORT
Division of Waste Management
Solid Waste Section
Page 2 of 2
Please contact me if you have any questions or concerns regarding this audit report.
Gam` (signature) Phone: [phone].
Regional Representative
Distribution: original signed copy to facility -- signed copy to compliance officer — e-mail or copy to suner
Delivered on : 04/25/02 by hand delivery X US Mail Certified No.
I

. ..... FACILITY COMPLIANCE AUDIT REPORT
.®.i..
NCDENR
Division of Waste Management
NORTH CAAOLINA OCPARTMCHT OF -
.Solid Waste Section
ENVIRONMENT AND NATURAL RESOURCES ,
:; (check a that' aPP
Y to.:_ au it w> : same;PermitiiumUer:,
.
Lined
LCID
YW
Transfer
Compost
SLAS
COUNTI..:.., aywood
MSWLF
Closed
HHW
Whits
Incin
T&P
FIRM
PERMIT NO 44=06 _
MSWLFgoods
CDLF
TireT&P/
Tire
IndusMal
X
DEMO
SDTF
FILE TYPE:: COMPLIANCE
Collection
Monofill
Landfill
--
Date of Audit: 04/24/03
Date of Last Audit: 10/22/02
FACILITY NAME AND ADDRESS:
Blue Ridge Paper Products Industrial Landfill
State Road 1550
Canton, NC 28716
FACILITY CONTACT NAME AND PHONE NUMBER:
Jim Giauque
Telephone: [phone]
FACILITY CONTACT ADDRESS (IF DIFFERENT):
Jim Giauque
Blue Ridge Paper Products, Inc.
P.O. Box 4000
Canton, NC 28716
AUDIT PARTICIPANTS:
Jim Patterson, N.C. Skid Waste Section
Jim Giauque, Blue Ridge Paper Products, Inc.
STATUS OF PERMIT:
Active - Permit amendment date - February 5, 2002.
PURPOSE OF AUDIT:
Inspection of industrial landfill.
NOTICE OF VIOLATIONS) (citation and explanation):
None
You are hereby advised that, pursuant to N.C.G.S. 130A-22, an administrative penalty of up to $5,000 per day may be assessed for each
violation of the Solid Waste Statute or Regulations. If the violation(s) noted here continue, you may be subject to enforcement actions
including penalties, injunction from operation of a solid waste management facility or a solid waste collection service and any such
further relief as may be necessary to achieve compliance with the North Carolina Solid Waste Management Act and Rules.
STATUS OF PAST NOTED VIOLATIONS (List all noted last audit):
N/A

FACILITY COMPLIANCE AUDIT REPORT
Division of Waste Management
Solid Waste Section
Page 2 of 2
OTHER COMMENTS /SUGGESTIONS:
(1) A portion of sludge has slid inside the cell. Work is being done to rectify this situation (6A East Cell).
(2) Filling has begun in 6A West Cell.
Please contact me if you have any questions or concerns regarding this audit report.
(signature) Phone: [phone].
Regional Representative
Distribution: original signed copy to facility -- signed copy to compliance officer — e-mail or copy to super
Delivered on : 05/08/03 by
cc: Mark Poindexter
Brent Rockett
hand delivery I X I US Mail I I Certified No. F 1

U1IIT TYKE.. (check all thatapplyfta?th7s, audit with
sarne.I'erm>t
Lined
LCID
YW
Transfer
Compost
SLAS
COUNTY: HByWO.Od
MSWLF
Closed
HHW
White
Ltcin
T&P
FIRM
PERMIT NO 44 4
MSWLF
goods
CDLF
TireT&P/
Tire
Industrial
X
DEMO
SDTF
FILETYPE: COMPLIANCE
Collection
Monofill
Landfill
Date of Audit: 07/17/03
Date of Last Audit: 04/24/03
FACILITY NAME AND ADDRESS:
Blue Ridge Paper Products Industrial Landfill
State Road 1550
Canton, NC 28716
FACILITY CONTACT NAME AND PHONE NUMBER:
Jim Giauque
Telephone: [phone]
FACILITY CONTACT ADDRESS (IF DIFFERENT):
Jim Giauque
Blue Ridge Paper Products, Inc.
P.O. Box 4000
Canton, NC 28716
AUDIT PARTICIPANTS:
Jim Patterson, N.C. Solid Waste Section
Jim Giauque, Blue Ridge Paper Products, Inc.
STATUS OF PERMIT:
Active, Permit amendment date - February 5, 2002.
PURPOSE OF AUDIT: --
Inspection of industrial landfill.
NOTICE OF VIOLATIONS) (citation and explanation):
None
You are hereby advised that, pursuant to N.C.G.S. 130A-22, an administrative penalty of up to $5,000 per day may be assessed for each
violation of the Solid Waste Statute or Regulations. If the violation(s) noted here continue, you may be subject to enforcement actions
including penalties, injunction from operation of a solid waste management facility or a solid waste collection service and any such
further relief as may be necessary to achieve compliance with the North Carolina Solid Waste Management Act and Rules.
STATUS OF PAST NOTED VIOLATIONS (List all noted last audit):
N/A
OTHER COMMENTS /SUGGESTIONS:
Most of the erosion of the waste inside the cell has been repaired.

Please contact me if you have any questions or concerns regarding this audit report.
� QUA,..-, (signature) Phone: [phone].
Regional Representative
Distribution: original signed copy to facility -- signed copy to compliance officer — e-mail or copy to super
Delivered on : 07/22/03 by hand delivery X US Mail Certified No. jj
cc: Mark Poindexter
Brent Rockett

1�
Amobodsommm A�
NCDENR
NORTH CAROLINA DEPARTMENT OF
ENVIRONMENT AND NATURAL RESOURCES
UNIT TYPE: (check all that:apply to this audit with same Permit number
Lined LCID YW Transfer Compost SLAS COUNTY: Haywood
MSWLF
Closed HIiW White Incin T&P FIRM MWLF goods PERMIT NO.: 44-06
S
CDLF TireT&P/ Tire Industrial x DEMO SDTF FILE TYPE: COMPLIANCE
Collection Monofill Landfill
Date of Audit: 04/23/03 Date of Last Audit: 01/25/02
FACILITY NAME AND ADDRESS:
Blue Ridge Paper Products Industrial Landfill
State Road 1550
Canton, NC 28716
FACILITY CONTACT NAME AND PHONE NUMBER:
Jim Giauque
Telephone: [phone]
FACILITY CONTACT ADDRESS (IF DIFFERENT):
Jim Giauque .
Blue Ridge Paper Products, Inc
175 Main Street
P.O. Box 4000
Canton, NC 28716
AUDIT PARTICIPANTS:
Jim Patterson, N.C. Solid Waste Section
Jim Giauque, Blue Ridge Paper Products, Inc.
STATUS OF PERMIT:
Active
PURPOSE OF AUDIT:
Inspection of industrial landfill.
NOTICE OF VIOLATIONS) (citation and explanation):
No violations observed.
You are hereby advised that, pursuant to N.C.G.S. 130A-22, an administrative penalty of up to $5,000 per day may be assessed for each
violation of the Solid Waste Statute or Regulations. If the violation(s) noted here continue, you may be subject to enforcement actions
including penalties, injunction from operation of a solid waste management facility or a solid waste collection service and any such
further relief as may be necessary to achieve compliance with the North Carolina Solid Waste Management Act and Rules.
STATUS OF PAST NOTED VIOLATIONS (List all noted last audit):
N/A
OTHER COMMENTS /SUGGESTIONS:
Operation looks good.

FACILITY COMPLIANCE AUDIT REPORT
Division of Waste Management
Solid Waste Section
Page 2 of 2
Please contact me if you have any questions or concerns regarding this audit report.
G�-- Qe27�
(signature) Phone: [phone].
Regional Representative
Distribution: original signed copy to facility -- signed copy to compliance officer — e-mail or copy to super
Delivered on : 04/25/02 by �T hand delivery EFU S Mail Certified No.1I