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HomeMy WebLinkAboutAS-428_6505_CA_MRP_20150330 GROUNDWATER MONITORING REPORT FORMER E-Z WAY AUTO SALES 1036 MORGANTON BOULEVARD SW. LENOIR, CALDWELL COUNTY, NORTH CAROLINA NCDENR INCIDENT NUMBER: 6505 NCDENR CONTRACT NUMBER: N14007i-C ECS PROJECT 09.25119 PREPARED FOR: NCDENR, UST SECTION RALEIGH, NORTH CAROLINA March 30, 2015 i SITE INFORMATION Site Name: Former E-Z Way Auto Sales Site Address: 1036 Morganton Boulevard SW. Lenoir, North Carolina 28645 Facility ID Number: Unknown NCDENR Incident Number: 6505 Site Risk Ranking: Intermediate (Assigned) Land Use Category: Commercial Latitude/Longitude: 36.9040269 N /79.538430 W Responsible Party: Unknown Current Property Owner: 3rd Wimbish Family Prop. LLC 858 13th Street Pl. SW. Hickory, North Carolina 28602 Primary Contact: Ms. Sharon Ghiold NCDENR, Division of Waste Management, UST Section 1637 Mail Service Center Raleigh, North Carolina 27699-1637 Primary Consultant: ECS Carolinas, LLP 4811 Koger Boulevard Greensboro, North Carolina 27407 (336) 856-7150 Laboratory: Research and Analytical Laboratories, Inc. Short Street Kernersville, North Carolina 28224-0403 (336) 996-2841 Laboratory Certification No. 35 Release Information: Two 8,000-gallon and two 4,000-gallon underground storage tanks (USTs) were closed and removed from the site in 1990. A release was discovered after the USTs were removed and soil samples were analyzed. Samples obtained from the UST removal contained total petroleum hydrocarbons-gasoline range organics (TPH-GRO) at 63.5 milligrams per kilogram (mg/kg). Free phase Product was measure in monitoring well MW-1 in September 2007 and April 2010. A 96-hour Mobile Multiphase Extraction (MMPE) Event was conducted in May of 2011 on iii TABLE OF CONTENTS 1.0 EXECUTIVE SUMMARY ....................................................................................................... 1 2.0 PROJECT INFORMATION .................................................................................................... 2 3.0 GROUNDWATER ASSESSMENT ......................................................................................... 3 3.1 Static Water Levels for Groundwater Flow Direction .................................................. 3 3.2 Groundwater Chemistry .............................................................................................. 3 3.3 Monitoring Well Sampling ........................................................................................... 3 4.0 RESULTS ............................................................................................................................... 3 4.1 Groundwater Flow Direction ........................................................................................ 3 4.2 Groundwater Chemistry .............................................................................................. 3 4.3 Monitoring Well Sampling Results .............................................................................. 4 5.0 CONCLUSIONS ..................................................................................................................... 4 6.0 RECOMMENDATIONS .......................................................................................................... 4 FIGURES Figure 1 Site Location Map Figure 2 Aerial Site Map Figure 3 Monitoring Well Location Map Figure 4 Groundwater Elevation Map Figure 5 Isoconcentration Map of Benzene Figure 6 Isoconcentration Map of Naphthalene Figure 7 Isoconcentration Map of Isopropylbenzene Figure 8 Isoconcentration Map of n-Propylbenzene TABLES Table 1 Monitoring Well Information and Groundwater Elevation Data Table 2 Geochemical Measurements Table 3 Summary of Groundwater Analytical Results (Monitoring Wells) APPENDIX Appendix A Site Photographs Appendix B Field Data Sheets Appendix C Laboratory Data Sheets and Chain of Custody Record Appendix D North Carolina General Warranty Deed Groundwater Monitoring Report Task Authorization Request No. 1 – Former E-Z Way Auto Sales Lenoir, Caldwell County, North Carolina NCDENR Incident No.: TF-6505 ECS Project 09.25119 March 30, 2015 1 1.0 EXECUTIVE SUMMARY As part of Task Authorization (TA) #1, NCDENR Contract # N14007i-C, ECS was contracted to sample four groundwater monitoring wells (MW-1, MW-2, MW-3, MW-4) and prepare a State Trust/Federal Trust Fund (STF/FTF) monitoring report in regards to NCDENR Incident No. 6505 – Former E-Z Way Auto Sales. A release was discovered after two 8,000-gallon and two 4,000-gallon underground storage tanks (USTs) were removed by closure June 1990. Analysis of samples collected following the UST removal detected Total Petroleum Hydrocarbons as gasoline (TPH-GRO) above the State Action Level. In January 1991, monitoring well MW-1 was installed and sampled for volatile organic compounds. The analysis detected hydrocarbons above their respective North Carolina 2L Groundwater Quality Standards (NC2LGWQS). In Septembers 2007, three soil borings were drilled and soil samples were collected around the source area. Analysis of the samples detected hydrocarbons above North Carolina Residential Maximum Soil Contaminant Concentrations (MSCCs) in soil boring SB-2. No hydrocarbons were detected above commercial/industrial MSCCs. Monitoring wells MW-2, MW-3, and MW-4 were installed in the locations of the soil borings and sampled. Analysis of the samples collected from MW-2 and MW-3 detected benzene at concentrations exceeding its NC2LGWQS by a factor of ten. Free phase product was measured in monitoring well MW-1. A receptor survey conducted in December 2007 did not locate water-supply wells within a 1,000 foot radius of the source area. Lower Creek is located approximately 300 feet southeast of the release area. A 96-hour mobile multiphase extraction (MMPE) event was conducted in May of 2011 in monitoring wells MW-1 and MW-3. The MMPE removed approximately ninety-five gallons of volatile organic compounds. After the MMPE event, monitoring wells MW-1 through MW-4 were sampled and Biosocks were installed in monitoring well MW-2 and MW-3. No free product has been detected in monitoring well MW-1 since the MMPE event. On July 23, 2013, Crawford Environmental Services (CES) collected samples from monitoring wells MW-1, MW-2, MW-3 and MW-4. The analysis detected various hydrocarbons above NC2LGWQS in MW-1, MW-2, and MW-3. Biosoks were placed in monitoring wells MW-1, MW-2 and MW-3 upon completion of sampling activities. In March 2015, ECS personnel collected samples from four monitoring wells (MW-1, MW-2, MW- 3, and MW-4). Laboratory analysis of groundwater samples collected from the monitoring wells detected various petroleum related hydrocarbons in MW-1, MW-2, and MW-3 a concentration above their respective NC2LGWQS. No compounds were detected above their Gross Contamination Levels (GCLs) Based on the information collected in this investigation and those performed by others, the concentrations of petroleum related hydrocarbons in the monitoring wells have declined since they were last sampled in 2013. It appears that the Biosocks have assisted in the reduction of Groundwater Monitoring Report Task Authorization Request No. 1 – Former E-Z Way Auto Sales Lenoir, Caldwell County, North Carolina NCDENR Incident No.: TF-6505 ECS Project 09.25119 March 30, 2015 2 VOCs in MW-1, MW-2, and MW-3. No free phase product has been detected in MW-1 since 2010 and no water-supply wells were located within 1,000 feet of the release. The closest surface water receptor is Lower Creek 300 feet south of the site. Based on the information collected by others over the last eight years and the current groundwater quality, ECS recommends that the incident be closed following the submittal of a Notice of Residual Petroleum restricting groundwater use on the site. 2.0 PROJECT INFORMATION The subject site is Former E-Z Way Auto Sales located at 1036 Morganton Boulevard SW. in Lenoir, Caldwell County, North Carolina (Figures 1 and 2). Based on information provided to ECS, two 8,000-gallon and two 4,000-gallon underground storage tanks (USTs) were removed by closure June 1990. Soil contamination was discovered during the removal of the UST system. Groundwater was encountered at 6 to 8 feet below land surface (bls). Photographs of the site are included in Appendix A. In August 1991, monitoring well MW-1 was installed. Analysis of the groundwater sample detected benzene, ethylbenzene, xylene, and isopropyl ether at concentrations exceeding their North Carolina 2L groundwater standards (NC2LGWQS). In Septembers 2007, Hart & Hickman performed a Phase I Limited Site Assessment (LSA). Three soil borings were drilled around the source area. Six petroleum related hydrocarbons were detected in the samples collected from soil borings SB-2 at concentrations above North Carolina Residential Maximum Soil Contaminant Concentrations (MSCCs). No hydrocarbons were detected above commercial/industrial MSCCs. Monitoring wells MW-2, MW-3, and MW-4 were installed in the locations of the soil borings and sampled. Analysis of the samples collected from MW-2 and MW-3 detected benzene at concentrations exceeding its NC2LGWQS by a factor of ten. Three additional hydrocarbons were detected in samples from MW-2 and MW-3 above the NC2LGWQS. Free phase product was measured in monitoring well MW-1. A receptor survey conducted in December 2007 did not locate water-supply wells within a 1,000 foot radius of the source area. Lower Creek is located approximately 300 feet southeast of the release area. In April 28, 2010, Terraine Environmental (Terraine) sampled the monitoring wells. Free product was measured in MW-1. Several hydrocarbons were detected above NC2LGWQS in MW-2 and MW-3. Well Booms were placed in MW-2 and MW-3 to promote biodegrading of petroleum. Terraine conducted a Multi-Mobile Phase (MMPE) event at the site between May 9 and 13, 2011. Approximately 5,010 gallons of fluid was recovered with approximately 95 gallons of volatile organic compounds recovered. Subsequent sampling conducted on May 26, 2011 did not detect free product in MW-1 and reduced contaminant levels in MW-2 and MW-3. On July 23, 2013, Crawford Environmental Services (CES) collected samples from monitoring wells MW-1, MW-2, MW-3 and MW-4. The analysis detected benzene, 1,2,4- trimethylbenzene, isopropylbenzene, methylene chloride, naphthalene, n-butylbenzene, and n-propylbenzene above their NC2LGWQS in MW-1, benzene above its NC2LGWQS Groundwater Monitoring Report Task Authorization Request No. 1 – Former E-Z Way Auto Sales Lenoir, Caldwell County, North Carolina NCDENR Incident No.: TF-6505 ECS Project 09.25119 March 30, 2015 3 in MW-2, and benzene, isopropylbenzene, methylene chloride, naphthalene, xylenes and n- propylbenzene) above their NC2LGWQS in MW-3. Biosoks were placed in monitoring wells MW-1, MW-2 and MW-3 upon completion of sampling activities. 3.0 GROUNDWATER ASSESSMENT 3.1 Static Water Levels for Groundwater Flow Direction On March 4, 2015, ECS measured the static water level (SWL) in four monitoring wells using a decontaminated electronic water level meter. Information regarding the construction of the monitoring wells and depth to groundwater is summarized on Table 1. 3.2 Groundwater Chemistry Prior to collecting the groundwater samples from the monitoring wells, geochemical parameters (temperature, pH, dissolved oxygen, and conductivity) were measured using an YSI Model 560 meter. The turbidity was observed during the sampling and recorded on the Groundwater Sampling Data Sheets (Appendix B). 3.3 Monitoring Well Sampling On March 4, 2015, ECS personnel collected samples from four monitoring wells (MW-1, MW-2, MW-3, and MW-4). The locations of the wells are shown on Figure 3. Prior to sampling, the wells were purged using a new disposable polyethylene bailer and new length of nylon cord. The wells were developed/purged by evacuating a minimum of 3 well volumes using the bailer and cord. The wells were developed/purged to remove sand, silt and other fine sediments and to promote communication between the surrounding formation and the sand pack surrounding the well’s screened interval. After purging was completed, the sampler wearing a new pair of disposable nitrile gloves for each sampling point poured the groundwater sample from the bailer into laboratory prepared containers. Each container was labeled and placed in a cooler containing ice to maintain the samples at approximately 4 Celsius. The sample containers were then delivered to Research & Analytical Laboratories, Inc. (R&A) in Kernersville, North Carolina to be analyzed for volatile organic compounds (VOCs) using Standard Method 6200B. A Chain of Custody Record was maintained and is included in the Appendix C. 4.0 RESULTS 4.1 Groundwater Flow Direction Based on the depth to water table measurements collected on March 4, 3015, the groundwater gradient is to the southwest across the site (Figure 4). 4.2 Groundwater Chemistry Based on the geochemical data, the average groundwater temperature was 17.79° C and the average conductivity was 0.0.293 mS/cm. The pH ranged between 5.57 to 6.01 and the Groundwater Monitoring Report Task Authorization Request No. 1 – Former E-Z Way Auto Sales Lenoir, Caldwell County, North Carolina NCDENR Incident No.: TF-6505 ECS Project 09.25119 March 30, 2015 4 dissolved oxygen (DO) ranged between 1.53 mg/l to 2.85 mg/l. The geochemical measurements are summarized on Table 2. 4.3 Monitoring Well Sampling Results Laboratory analysis detected benzene, isopropylbenzene, naphthalene, and n-propylbenzene above their NC2LGWQS in MW-1; and benzene and naphthalene above their NC2LGWQS in MW-3. Various other hydrocarbons were detected in the wells but below their NC2LGWQS. Laboratory of analysis of the sample collected from monitoring well MW-2 detected IPE at a concentration above the laboratory quantitative limit but not above its respective NC2LGWQS. Laboratory analysis of the groundwater sample collected from MW-4 did not detect compounds above the laboratory method detection limits. Concentrations of benzene in monitoring well MW-1 and MW-3 was above the North Carolina 2B Surface Water Standard (2B Standard). A summary of the current and historical groundwater analytical results are included in Table 3. Isoconcentration maps of the hydrocarbons detected above NC2LGWQS are shown on Figures 5 through 8. The laboratory data sheets are included in the Appendix C. 5.0 CONCLUSIONS Based on the results of the groundwater assessments, ECS concludes the following: Based on the information collected in this investigation and those performed by others, the concentrations of petroleum related hydrocarbons in the monitoring wells have declined since they were last sampled in 2013. It appears that the Biosocks have assisted in the reduction of VOCs in MW-1, MW-2, and MW-3. Concentrations of benzene were detected above the 2B Human Health standards in MW-1 and MW-3; however, the concentrations of benzene were not above the 2B Standard by a factor of 10. No free product has been detected in MW-1 since 2010; however the water table has been located above the top of the screen since April 2010. However, based on the concentration of total BTEX since May 2011, it is ECS’s opinion that no free product is present in measurable amounts. No water-supply wells were located within 1,000 feet of the release. The closest surface water receptor is Lower Creek 300 feet south of the site. 6.0 RECOMMENDATIONS Based on the information collected by others over the last eight years and the current groundwater quality, ECS recommends that the risk ranking be lowered from intermediate to low risk. ECS also recommends that the incident be closed, following submittal of a Notice of Residual Petroleum restricting the use of groundwater on the site and the site for residential use. The existing monitoring wells should be abandoned by a North Carolina licensed well driller. FIGURES SOURCE: USGS TOPOGRAPHIC MAP LENOIR NC QUADRANGLE DATE 1993 FIGURE 1 SITE LOCATION MAP FORMER E-Z WAY AUTO SALES 1036 MORGANTON BLVD. SW LENOIR, CALDWELL COUNTY, NORTH CAROLINA NCDENR INCIDENT NO. 6505 ECS PROJECT NO. 09-25119 SITE APPROXIMATE SITE BOUNDARY SCALE (IN FEET) 2,000 1,000 0 2,000 SOURCE: CALDWELL COUNTY GIS DEPARTMENT AERIAL PHOTOGRAPH, DATED 2010 FIGURE 2 AERIAL SITE MAP FORMER E-Z WAY AUTO SALES 1036 MORGANTON BLVD. SW LENOIR, CALDWELL COUNTY, NORTH CAROLINA NCDENR INCIDENT NO. 6505 ECS PROJECT NO. 09-25119 SCALE (IN FEET) 35 17.5 0 35 APPROXIMATE SITE BOUNDARY SOURCE: CALDWELL COUNTY GIS DEPARTMENT AERIAL PHOTOGRAPH, DATED 2010 FIGURE 3 MONITORING WELL LOCATION MAP FORMER E-Z WAY AUTO SALES 1036 MORGANTON BLVD. SW LENOIR, CALDWELL COUNTY, NORTH CAROLINA NCDENR INCIDENT NO. 6505 ECS PROJECT NO. 09-25119 MW-3 MW-1 SCALE (IN FEET) 35 17.5 0 35 MW-2 APPROXIMATE SITE BOUNDARY MONITORING WELL MW-4 SOURCE: ALAMANCE COUNTY GIS DEPARTMENT FIGURE 4 GROUNDWATER ELEVATION MAP FORMER E-Z WAY AUTO SALES 1036 MORGANTON BLVD. SW LENOIR, CALDWELL COUNTY, NORTH CAROLINA NCDENR INCIDENT NO. 6505 ECS PROJECT NO. 09-25119 SCALE (IN FEET) 80 40 0 80 MONITORING WELL APPROXIMATE PROPERTY LINE GROUNDWATER ELEVATION GROUNDWATER FLOW DIRECTION LEGEND MW-4 90.72 MW-2 91.96MW-1 90.30 MW-3 90.38 90 92 SOURCE: ALAMANCE COUNTY GIS DEPARTMENT FIGURE 5 ISOCONCENTRATION MAP OF BENZENE FORMER E-Z WAY AUTO SALES 1036 MORGANTON BLVD. SW LENOIR, CALDWELL COUNTY, NORTH CAROLINA NCDENR INCIDENT NO. 6505 ECS PROJECT NO. 09-25119 SCALE (IN FEET) 80 40 0 80 MW-4 (BQL)MW-2 (BQL) MW-1 (91.4) MW-3 (66.6) MONITORING WELL APPROXIMATE PROPERTY LINE ISOCONCENTRAION LINE LEGEND 85 BQL SOURCE: ALAMANCE COUNTY GIS DEPARTMENT FIGURE 6 ISOCONCENTRATION MAP OF NAPHTHALENE FORMER E-Z WAY AUTO SALES 1036 MORGANTON BLVD. SW LENOIR, CALDWELL COUNTY, NORTH CAROLINA NCDENR INCIDENT NO. 6505 ECS PROJECT NO. 09-25119 SCALE (IN FEET) 80 40 0 80 MW-4 (BQL) MW-2 (BQL) MW-1 (752)MW-3 (61.3) MONITORING WELL APPROXIMATE PROPERTY LINE ISOCONCENTRAION LINE LEGEND BQL 700 (BQL) SOURCE: ALAMANCE COUNTY GIS DEPARTMENT FIGURE 7 ISOCONCENTRATION MAP OF ISOPROPYLBENZENE FORMER E-Z WAY AUTO SALES 1036 MORGANTON BLVD. SW LENOIR, CALDWELL COUNTY, NORTH CAROLINA NCDENR INCIDENT NO. 6505 ECS PROJECT NO. 09-25119 SCALE (IN FEET) 80 40 0 80 MW-4 (BQL) MW-2 (BQL) MW-1 (145)MW-3 (BQL) MONITORING WELL APPROXIMATE PROPERTY LINE ISOCONCENTRAION LINE LEGEND BQL 100 SOURCE: ALAMANCE COUNTY GIS DEPARTMENT FIGURE 8 ISOCONCENTRATION MAP OF n-PROPYLBENZENE FORMER E-Z WAY AUTO SALES 1036 MORGANTON BLVD. SW LENOIR, CALDWELL COUNTY, NORTH CAROLINA NCDENR INCIDENT NO. 6505 ECS PROJECT NO. 09-25119 SCALE (IN FEET) 80 40 0 80 MW-4 (BQL) MW-2 (BQL) MW-1 (355)MW-3 (BQL) MONITORING WELL APPROXIMATE PROPERTY LINE ISOCONCENTRAION LINE LEGEND BQL 300 TABLES Former EZ Way Auto Sales Lenoir, Caldwell County, NC NCDENR Incident # 6505 ECS Project 09.25119 Table 1: Monitoring Well Groundwater Elevation Data Monitoring Well ID# Total Well Depth (ft.) Top of Casing Elevation Screen Interval (ft.) Date Measured Depth to Water (ft.) Depth to Free Product (ft.) Free Product Thickness (ft.) Groundwater Elevation 09/24/07 11.65 11.45 0.20 88.52 04/28/10 8.01 7.75 0.26 92.21 07/23/13 8.10 ND ND 91.90 03/04/15 9.70 ND ND 90.30 09/24/07 11.64 ND ND 88.82 04/28/10 8.60 ND ND 91.86 07/23/13 8.41 ND ND 92.05 03/04/15 8.50 ND ND 91.96 09/24/07 11.27 ND ND 88.91 04/28/10 7.68 ND ND 92.50 07/23/13 8.29 ND ND 91.89 03/04/15 9.80 ND ND 90.38 09/24/07 11.62 ND ND 88.40 04/28/10 7.84 ND ND 92.18 07/23/13 7.99 ND ND 92.03 03/04/15 9.30 ND ND 90.72 Note: ND= Not Detected 10 - 20100.00 100.46 100.18 19 100.02 9 - 19 6 - 16 8 - 18 MW-1 MW-2 MW-3 MW-4 16 20 18 Former EZ Way Auto Sales Lenoir, Caldwell County, NC NCDENR Incident# 6505 ECS Project 09.25119 TABLE 2: GEOCHEMICAL MEASUREMENTS SAMPLE ID MW-1 MW-2 MW-3 MW-4 Date Sampled pH 6 5.65 6.01 5.57 Temperature (oC) 18.35 17.81 17.75 17.25 Conductivity (mS/cm) 0.353 0.25 0.481 0.09 Dissolved O2 (mg/l) 1.59 1.53 2.85 2.11 Turbidity (Observed) T T ST VT NOTES: mS/cm = milliseimens per centimeter mV = millivolts °C = degress Celsius NT= Not Turbid VT= Very Turbid ST= Slightly Turbid 3/4/2015 Former EZ Way Auto SalesLenoir, Caldwell County, NCNCDENR Incident# 6505ECS Project 09.25119 TABLE 3: SUMMARY OF GROUNDWATER ANALYTICAL RESULTS (MONITORING WELLS)Sample IdentificationSample Date 01/08/91 09/24/07 04/28/10 05/26/11 07/23/1303/04/15 09/24/07 04/28/10 05/26/11 07/23/13 03/04/15 09/24/07 04/28/10 05/26/11 07/23/13 03/04/15 09/24/07 04/28/10 05/26/11 07/23/13 03/04/15Method 6200BBenzene2,452NS-FP NS-FP140 92.5 91.4 12 230 1.9 12<0.565 3,000 1,500 1,300 66.6ND ND ND ND <0.5 1 5,000 51Toluene NA NS-FP NS-FP 27 72.9 19.2 2.8 26 1.1 1.3 <0.5 32014,000320 23.7 3.03 ND ND ND ND <0.5 600 260,000 NEEthylbenzene1,576NS-FP NS-FP 210 ND 23 8.9 18 ND 0.29J <0.5 442,600 720 5866.41 ND ND ND ND <0.5 600 84,500 NETotal Xylenes2,684NS-FP NS-FP 198 153.6 121 45.6 35 2.9 1.1J <1 19714,600 2,050 1,4526.81 ND ND ND ND <0.5 500 85,500 NEMethyl Tertbutyl Ether NA NS-FP NS-FP 0.28J ND <0.5 ND ND 0.13J ND <0.5 0.57 ND 1.6J 1.6J <0.5 ND ND ND ND <0.5 20 20,000 NEIsopropyl Ether218NS-FP NS-FP 11 ND 15 32 31 14 5.2 4.02120ND 42 46.9 21.4 ND ND ND ND <0.5 70 70,000 NEEDB NA NS-FP NS-FP ND ND <0.5 NA ND ND ND <0.5 NA ND ND ND <0.5 NA NDND ND <0.5 0.02 50 NE1,2-Dichloroethane NA NS-FP NS-FP3ND <0.58ND ND ND <0.5 ND ND32ND <0.5 ND ND ND ND <0.5 0.4 400 NE1,2-Dichloropropane NA NS-FP NS-FP 1.8 ND <0.5 ND ND ND ND <0.5 ND ND ND ND <0.5 ND ND ND ND <0.5 0.6 600 NENaphthalene NA NS-FP NS-FP780 473 752 56 211.8 3.7 <0.515 570 190 353 61.33.5 ND ND ND <0.5 6 6,000 NEn-butylbenzene NA NS-FP NS-FP 9110439.2 12 4.7 0.78 0.71 <0.5 1.6 ND ND 20.1 3.76 1.4 ND ND ND <0.5 706,900 NEsec-butylbenzene NA NS-FP NS-FP 29 41.9 <0.5 4.4 5.9 1.3 1.8 <0.5 1.8 14.9 7.3 14.5 <0.5 1.2 ND 0.32J ND <0.5 70 8,500 NEIsopropylbenzene NA NS-FP NS-FP160 117 1457.8 64 15 7.5 <0.5 131406214722.9 0.65 ND ND ND <0.5 70 25,000 NEtert-butylbenzene NA NS-FP NS-FP ND ND <0.5 ND ND ND 0.26J <0.5 ND ND ND ND <0.5 ND ND ND ND <0.5 25 NL NEp-Isopropyltoluene NA NS-FP NS-FP 9.4 ND <0.5 3.6 ND ND ND <0.5 0.68 ND 7.2 ND <0.5 0.74 ND ND ND <0.5 25 11,700 NEMethylene Chloride NA NS-FP NS-FP ND57.6<0.5 ND ND ND ND <0.5 ND ND ND11.3<0.5 ND ND ND ND <0.5 5 5,000 NEn-propylbenzene NA NS-FP NS-FP380 337 355248711 1.5 <0.5 21360 130 30949.4 1.8 ND ND ND <0.5 70 30,000 NE1,2,4-Trimethylbenzene NA NS-FP NS-FP620 509344 100 1.7 ND 2.6J <0.5 311,900 420365 2.95 ND ND ND ND <0.5 400 28,500 NE1,3,5-Trimethylbenzene NA NS-FP NS-FP 130 123 73.3 32 ND ND ND <0.5 15490100 65.3 <0.5 ND ND ND ND <0.5 400 25,000 NEMethod MADEP VPHC5-C8 Aliphatics ND NS-FP NS-FP NA NA NA510NA NA NA NA1,500NA NA NA NA ND NA NA NA NA 400 NE NEC9-C18 Aliphatics ND NS-FP NS-FP NA NA NA870NA NA NA NA 540 NA NA NA NA 120 NA NA NA NA 700 NE NEC19-C36 Aliphatics ND NS-FP NS-FP NA NA NA ND NA NA NA NA ND NA NA NA NA ND NA NA NA NA 200 NE NEC9-C22 Aromatcis ND NS-FP NS-FP NA NA NA620NA NA NA NA 23 NA NA NA NA ND NA NA NA NA 200 NE NENotes:NC2LGWQS = North Carolina 2L Groundwater Quality Standard GCL = Gross Contaminant Level 2B Standards = 15 A NCAC 2B Human Health StandardsND = Not DetectedNS = Not SampledNE = No Standard EstablishedNA = Not Analyzed for This Compoundµg/l = micrograms per liter = ppb (parts per billion)J-Value = Estimated value between laboratory reporting limit and method detection limit Bold = Concentration Exceeds NC2LGWQSBOLD UNDERLINE=Concentration Exceeds GCL2B Standards (HH)GCLMW-1MW-2MW-3MW-4NC2LGWQS APPENDIX A Photograph No. 1 View of site from Morganton Blvd. SW. Photograph No. 2 View of MW-1 that was filled with dirt but monitoring well was not damaged. APPENDIX B APPENDIX C