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1101_Buncombe_MSWLF_April20GW_FID1427498_20200723
DENR USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Bunnell-Lammons Engineering Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Timothy J Daniel Phone: 864-288-1265 E-mail: tj.daniel@blecorp.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or. 1600) October 20-24, 2006) Id Buncombe County Landfill 2726 Riverside Drive, Woodfin, NC, 28804 1101-MSWLF .1600 April 27-29, 2020 1979 Environmental Status: (Check all that apply) Initial/Background Monitoring Detection Monitoring 0 Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells Leachate monitoring data ❑ Surface water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Timothy J. Daniel Staff Hydrogeologist 864-288-1265 Facility Representative Name (Print) Title (Area Code) Telephone Number l , Affix NC Licensed/ Professional Geologist Seal Signature Date 6004 Ponders Court, Greenville, SC, 29615 Facility Representative Address C-284 & C-1538 H I Ill". A2r f, .•`'" H.. A' { Q 4 r 2653 _ NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 REPORT OF WATER QUALITY SAMPLING AND ANALYSIS 1st SEMI—ANNUAL EVENT 2020 OLD BUNCOMBE COUNTY LANDFILL WOODFIN, NORTH CAROLINA DWM Permit Number 1101-MSWLF-1979 DWR UIC Permit No. WI0100353 Prepared For: Buncombe County, North Carolina BLE Project Number J20-14175-02 r y C +� z{ 2653 l�J ti r f �� }`1�'•y� NON {�i�1 ■\M� +r�rf{!f'"t�i• urtiks■k* Ley■, 11111t1lr July 14, 2020 `��+■'[�� �A�[�]`�'■�,�� NSyY�9 14' 5 LO�•'��. ,�1�1rrlSiitll't BLE North Carolina Business Licenses C-284 & C-1538 IM 13UNNELL M LAMMONS ENGiNEERTNG 6004 Panders Court I Greenville, 5C 29615 864-288.1265 A 864,286.4330 w info@hlecorp.com BLECORMOM � LAMM(INS ENGINEERING July 14, 2020 Buncombe County Solid Waste Department 81 Panther Branch Road Alexander, North Carolina 28701 Attention: Ms. Kristy Smith Subject: Report of Water Quality Sampling and Analysis 1" Semi -Annual Event 2020 Old Buncombe County Landfill Woodfin, North Carolina DWM Permit Number 1101-MSWLF-1979 DWR UIC Permit No. W10100353 BLE Project Number J20-14175-02 Dear Ms. Smith: Pursuant to Buncombe County authorization of Bunnell-Lammons Engineering, Inc. (BLE) Proposal Number J20-14175-02, dated February 27, 2020, BLE has prepared this report of the groundwater and surface water sampling and laboratory analysis for the 1st semi-annual sampling event of 2020 at the Old Buncombe County Landfill. Consistent with the North Carolina Division of Waste Management (DWM) — Solid Waste Section (SWS) and the North Carolina Division of Water Resources (DWR) approved monitoring program, sampling and analysis will be conducted twice in 2020. This report contains the information required by both the DWM and DWR to document the sampling and analysis activities for the 1st semi-annual sampling event of 2020 in the State's permanent project record. Sincerely, BUNNELL LAMMONs ENGINEERING INC. t Timothy J. Daniel, P.G. Staff Hydrogeologist Registered, NC #2653 cc: Ms. Jaclynne Drummond — DWM-ARO Mr. Andrew Moore, P.G. — DWR-ARO Mr. Michael Rogers, P.G. — DWR-CO v 4 / a � Andrew W. Ale ander, P.G., RSM Senior Hydrogeologist Registered, NC #1475 Ilblegvlsvrllsolidwasteprojectslbuncombe county old lf, nc114175-02 spring 2020 semi repor4reportlold bclf 1101-msw6r1979 2020 semi-annual 14175-02.docx 6004 Ponders Court, Greenville, SC 29615 ( H!54.28B.1265 a B64.288.4430 045info@hleMrp com 6LECORP.COM 1s 1m 1i Old Buncombe County Landfill -- Woodfin, North Carolina July 14, 2020 Report of Groundwater Sampling and Analysis — 1'tSemi-Annual Event 2020 BLE Project No. J20-14175-02 TABLE OF CONTENTS 1.0 PROJECT INFORMATION........................................................................................................1 2.0 FIELD ACTIVITIES, SAMPLING, AND ANALYSIS.............................................................1 3.0 GROUNDWATER FLOW........................................................................................................... 2 4.0 RESULTS....................................................................................................................................... 2 4.1 Groundwater.................................................................................................................................... 2 4.2 Surface Water.................................................................................................................................. 3 4.3 Geochemical Parameters for Monitored Natural Attenuation......................................................... 3 5.0 CONCLUSIONS AND RECOMMENDATIONS....................................................................... 4 6.0 QUALIFICATIONS OF REPORT.............................................................................................. 4 7.0 CLOSING.......................................................................................................................................4 Tables Table 1 Well Construction and Monitoring Well Data Table 2 Groundwater VOCs Table 3 Groundwater Field Parameters and Total Metals Table 4 Surface Water VOCs Table 5 Surface Water Field Parameters and Total Metals Table 6 Groundwater Transects for Remedial Monitoring Table 7 Groundwater Geochemical Parameters for MNA Figures Figure 1 Site Location Map Figure 2 Groundwater Elevation Contour Map — April 27, 2020 Appendices Appendix A Field Sampling Logs — Pace Analytical Services, LLC. Appendix B Laboratory Analytical Data — Pace Analytical Services, LLC. 1 of 1 1s 1m 1i Old Buncombe County Landfill -- Woodfin, North Carolina July 14, 2020 Report of Groundwater Sampling and Analysis — 1'tSemi-Annual Event 2020 BLE Project No. J20-14175-02 1.0 PROJECT INFORMATION Buncombe County provides post -closure care for the Pre -Subtitle D MSWLF (unlined) located at 2726 Riverside Drive, Woodfin, North Carolina (Figure 1). The county operated the facility as a municipal solid waste (MSW), industrial solid waste (ISW), and construction and demolition (C&D) landfill. The landfill is separated into four (4) separate waste areas labeled A through D. Waste areas A, B, and C stopped receiving waste before October 9, 1991 and waste area D stopped receiving waste on September 27, 1997. Groundwater and surface water monitoring is performed at the site in accordance with a DWM approved Corrective Action Plan (CAP) dated September 3, 2014 [DIN 21838 (SCS Engineers File No 09204072.06)] and a DWM approved Request for Reduction of MNA Parameters dated November 30, 2016 [DIN 27144 (SCS Engineers File No 09204072.14)]. The facility requires semi-annual groundwater and surface water monitoring and reporting in accordance with the CAP, et seq. As part of the correction action at the facility, Buncombe County applied for, and was granted a permit for subsurface injection of materials for enhanced bioremediation of VOCs in groundwater. The Underground Injection Control (UIC) Permit (No W10100353) was transmitted by the DWR on September 11, 2015. The permit issue date was September 15, 2015 and the permit expires on August 31, 2020 (effective dates). The UIC permit requires groundwater monitoring and reporting. We understand that this semi-annual monitoring report prepared as part of the DWM approved sampling and analysis matrix is sufficient to meet the monitoring requirements of the UIC permit. The active groundwater monitoring network for the Closed Buncombe County Landfill consists of one (1) upgradient (background) well and twenty-four (24) downgradient (compliance, performance, and sentinel) wells. There are a total of fourteen (14) additional wells that are considering inactive for sampling purposes and are used for collecting water levels only. Five (5) wells have been abandoned. Five (5) active surface water monitoring locations have been established for the facility to monitor surface water quality. The existing surface water locations consist of one (1) upstream (background) location and four (4) downstream (compliance) locations. Five (5) inactive surface water monitoring locations have been established but are not sampled. 2.0 FIELD ACTIVITIES, SAMPLING, AND ANALYSIS Groundwater and surface water samples were collected for the I' semi-annual sampling event by personnel from Pace Analytical Services, LLC. (Pace) of Asheville, North Carolina between April 27-29, 2020. Groundwater samples were collected from twenty-two (22) of the twenty-four (24) active groundwater monitoring well locations located on the site. Additionally, the five (5) surface water locations were sampled during the event. The groundwater and surface water samples were delivered to Pace Analytical Services, LLC. (Pace) of Columbia, South Carolina and analyzed in the laboratory per the approved monitoring plan. The field parameters of dissolved oxygen, pH, redox potential, specific conductance, turbidity, and temperature were measured in the field by Pace. A copy of the Pace field sampling logs is included in Appendix A. A copy of the laboratory analytical data is included in Appendix B. 1 of 4 1s 1M 1i Old Buncombe County Landfill -- Woodfin, North Carolina July 14, 2020 Report of Groundwater Sampling and Analysis — 1'tSemi-Annual Event 2020 BLE Project No. J20-14175-02 3.0 GROUNDWATER FLOW The water level data collected during the groundwater sampling event on April 27, 2020 is presented in Table 1. A groundwater elevation contour map is presented as Figure 2 which includes generalized groundwater flow directions. 4.0 RESULTS 4.1 Groundwater The results of the groundwater field and laboratory analyses are summarized on Tables 2 and 3 and the laboratory analytical data is included in Appendix B. VOC detections during the current sampling event included: • Acetone (7 wells); • Benzene (10 wells); • Carbon Disulfide (1 well); • Chlorobenzene (13 wells); • Chloroethane (11 wells); • 1,2-Dichlorobenzene (1,2 DCB) (5 wells) • 1,4-Dichlorobenzene (1,4 DCB) (17 wells); • 1,1-Dichlorethane (1,1 DCA) (14 wells); • 1,2-Dichlorethane (1,2 DCA) (3 wells); • cis-1,2-Dichloroethene (cis-DCE) (13 wells); • trans-1,2-Dichloroethene (trans-DCE) (2 wells); • Ethylbenzene (1 well); • 2-Butanone (3 wells); • 4-Methyl-2-Pentanone (1 well); • Toluene (2 wells); • Trichloroethene (3 wells); • Vinyl chloride (11 wells); • Total Xylenes (4 wells); and • 1,4-Dioxane (14 wells). Total metal detections during the current sampling event included: • total barium (23 wells); • total beryllium (1 well); • total cadmium (3 wells); • total chromium (1 well); • total cobalt (8 wells); • total copper (6 wells); • total lead (4 wells); • total nickel (18 wells); and • total zinc (15 wells). 2 of 4 1s 1m 1i Old Buncombe County Landfill -- Woodfin, North Carolina July 14, 2020 Report of Groundwater Sampling and Analysis — 1'tSemi-Annual Event 2020 BLE Project No. J20-14175-02 Please refer to Tables 2 and 3 for a summary of which groundwater constituents exceed North Carolina Groundwater Quality Standards (NC2L) maximum contaminant levels' (MCLs). Field parameters measured in the groundwater included dissolved oxygen, pH, redox potential, specific conductance, turbidity, and temperature. 4.2 Surface Water The results of the surface water field and laboratory analyses are summarized on Tables 4 and 5 and the laboratory analytical data is included in Appendix B. VOC detections during the current sampling event included: • Acetone (1 location); and • 1,4-Dioxane (3 locations). Total metal detections during the current sampling event included: • total barium all locations; • total cobalt (2 locations); • total lead (2 locations); • total nickel (3 locations); • total selenium (1 location); and • total zinc (3 locations). Field parameters measured in the surface water included dissolved oxygen, pH, redox potential, specific conductance, turbidity, and temperature. Please refer to Table 4 and 5 for a summary of which surface water constituents and field parameters exceeded their established North Carolina Surface Water Quality Standards (NC2B)2 standard limits. 4.3 Geochemical Parameters for Monitored Natural Attenuation Buncombe County selected Monitored Natural Attenuation (MNA), Institutional Controls (restrictive cover; a.k.a. landfill cap), and In Situ Enhanced Bioremediation and Bioaugmentation as the groundwater remedies for the facility. The selected remedies are in progress. A series of transects along groundwater flowpaths were identified in the CAP, et. Seq, which includes groundwater monitoring wells selected for remedial monitoring. A summary table which identifies each transect (1 through 5) and associated monitoring wells is included as Table 6. Sampling for specific geochemical parameters to evaluate remedial performance was performed during the lst semi-annual event of 2020. Those results are summarized on Table 7 and the laboratory analytical data is included in Appendix B. ' North Carolina Department of Environmental Quality, Classifications of Water Quality Standards, Section 15A NCAC 2L.202, April 1, 2013. 2 North Carolina Department of Environmental Quality, Surface Waters and Wetlands Standards, Section 15A NCAC 0213.0100, .0200, and .0300, June 10, 2019. 3 of 4 1s 1m 1i Old Buncombe County Landfill -- Woodfin, North Carolina July 14, 2020 Report of Groundwater Sampling and Analysis — 1'tSemi-Annual Event 2020 BLE Project No. J20-14175-02 The CAP specifies that a Corrective -Action Plan Evaluation Report (CAER) will be submitted to evaluate the site's remedial progress on a 5-year schedule. Buncombe County plans to issue a CAER on or about October 2020. 5.0 CONCLUSIONS AND RECOMMENDATIONS Semi-annual assessment monitoring was performed during the 1' semi-annual event of 2020 in general accordance with the approved CAP and monitoring plan. Detected constituents which exceed their respective groundwater and surface water standards are identified on the summary tables. We recommend that semi-annual sampling continue in accordance the approved CAP and monitoring plan. As previously stated, a CAER will be prepared and submitted in which will evaluate monitoring data and remedial progress. A revised monitoring matrix will be submitted as part of the CAER. 6.0 QUALIFICATIONS OF REPORT The activities and evaluative approaches used in this assessment are consistent with those normally employed in hydrogeological and environmental assessments of this type. Our evaluation of site conditions has been based on our understanding of the site and project information and the data provided to BLE. This report has been prepared on behalf of and exclusively for the use of Buncombe County, North Carolina. This report and the findings contained herein shall not, in whole or in part, be used or relied upon by any other parry (excluding the DWM and DWR) without BLE's prior written consent. 7.0 CLOSING We appreciate the opportunity to be of service to Buncombe County, North Carolina. Please contact us at (864) 288-1265 if you have any questions or comments. 4 of 4 Tables Table 1 Well Construction and Monitoring Well Data Old Buncombe County Landfill Woodfin, North Carolina Permit No. 1101-MSWLF-1979 BLE Project Number J20-14175-02 Monitoring Point Northing' Easting' TOC Elevation (ft)1 GS Elevation (ft)1 Depth to GW (ft) April 27, 2020 Groundwater Elevation (ft) Well Depth (ft)' Screen Depth (below GS)1 Geology Monitored' Well Status/Purpose DPL-1 714,361.2 928,456.1 2040.73 2038.23 Dry Dry 65 55 - 65 Bedrock Compliance DPL-2 714,508.1 928,812.6 2112.15 2109.65 A A 97 87 - 97 Bedrock Injection MW-A 714,654.47 931,068.90 DNA DNA 0.00 DNA DNA DNA - DNA Bedrock DNA MW-B 1713,635.93 930,421.08 1960.86 1960.30 3.71 1957.15 15 5 - 15 Bedrock Compliance MW-2 715,052.9 930,063.8 2205.33 2203.40 108.48 2096.85 175 145 - 175 Bedrock Background MW-3 713,790.10 929,814.44 1991.15 1989.90 65.76 1925.39 90 60 - 90 Bedrock Compliance MW-4 714,177.83 928,875.09 2014.27 2013.60 71.97 1942.30 75 55 75 Bedrock Performance MW-4A 713,351.70 931,195.02 2083.10 2082.50 66.51 2016.59 77 67 77 Bedrock Compliance MW-5 714,620.07 928,174.58 2019.73 2019.00 47.70 1972.03 80 70 80 Bedrock Compliance MW-6 1715,103.13 928,152.69 2002.08 2000.30 0.00 2002.08 40 30 40 Bedrock Performance MW-6-192 715,146.34 928,113.86 2009.02 2006.73 24.42 1984.60 192 1 182 - 192 Bedrock Compliance MW-7 715,604.13 930,534.81 DNA DNA 22.46 DNA DNA DNA - DNA Saprolite Compliance MW-8 716,107.98 930,308.94 2079.02 2077.20 24.27 2054.75 38 23 - 38 Saprolite DNA MW-9 716,024.04 928,619.48 DNA DNA A A DNA DNA - DNA Saprolite DNA MW-10 716,086.5 929,060.5 DNA DNA A A DNA DNA - DNA Saprolite DNA MW-12-10 DNA DNA DNA DNA Dry Dry DNA DNA - DNA DNA DNA MW-12-25 713,258.9 931,353.0 2029.98 2026.36 7.60 2022.38 26 16 - 26 DNA Compliance MW-13-10 713,000.2 931,279.7 DNA DNA 2.79 DNA DNA DNA - DNA Saprolite DNA MW-13-35 713,023.1 931,236.9 2017.68 2014.13 5.24 2012.44 35 25 - 35 Bedrock Compliance MW-13-132 712,997.8 931,274.0 2012.89 2009.58 20.83 1992.06 132 122 - 132 Bedrock Performance MW-14 716,348.1 930,124.0 DNA DNA NM DNA DNA DNA - DNA Bedrock DNA MW-15 716,995.2 929,509.6 2028.08 2024.08 4.80 2023.28 72 62 - 72 Bedrock Compliance MW-16 716,170.0 929,107.2 DNA DNA A A DNA DNA - DNA Bedrock DNA MW-17 DNA DNA DNA DNA A A DNA DNA - DNA DNA DNA MW-17-60 713,339.0 930,205.8 1922.97 1920.35 21.40 1901.57 60 50 - 60 Bedrock Compliance MW-17-137 713,329.8 930,199.1 1921.73 1919.24 20.22 1901.51 137 127 - 137 Bedrock Compliance MW-17-310 713,302.4 930,207.9 1913.50 1918.00 0.00 1913.50 310 300 - 310 Bedrock Compliance MW-18-3 714,130.9 927,843.0 DNA DNA Dry Dry DNA DNA - DNA Flood Plain DNA MW-18-78 714,131.1 927,848.7 1894.62 1891.62 6.53 1888.09 78 68 - 78 Bedrock Sentinel MW-19-4 713,953.9 928,939.4 DNA DNA Dry Dry DNA DNA - DNAI Flood Plain DNA MW-19-75 713,948.7 928,950.0 1900.72 1898.02 9.35 1891.37 75 65 - 75 Bedrock Compliance MW-19-110 713,951.7 928,942.4 1901.43 1898.53 10.03 1891.40 110 1 100 - 110 Bedrock Sentinel MW-20-3 713,865.0 929,310.2 DNA DNA Dry Dry DNA DNA - DNA Flood Plain DNA MW-20-32 713,879.0 929,332.7 DNA DNA 6.06 DNA DNA DNA - DNA Bedrock DNA MW-21-4 713,810.5 929,567.5 DNA DNA 6.18 DNA DNA DNA - DNA Flood Plain DNA MW-21-21 713,826.6 929,581.7 1900.49 1897.49 5.58 1894.91 21 11 - 21 Bedrock Performance MW-21-94 713,829.5 929,577.5 1901.06 1897.76 7.52 1893.54 94 84 - 94 Bedrock Sentinel MW-22-78 716,370.39 930,380.26 DNA DNA 24.15 DNA DNA DNA - DNA Bedrock DNA MW-22-143 716,306.96 930,320.49 DNA DNA 43.12 DNA DNA DNA - DNA Bedrock DNA MW-23-119 716,014.05 930,476.24 DNA DNA 41.73 DNA DNA DNA - DNA Bedrock DNA MW-23-186 716,004.53 930,480.42 DNA DNA 51.12 DNA DNA DNA - DNA Bedrock DNA MW-24-45 711,372.03 930,963.22 1932.07 1929.82 Dry Dry 45 35 - 45 Bedrock Compliance MW-24-160 711,435.81 931,042.73 1933.24 1930.93 95.00 1838.24 160 150 - 160 Bedrock Sentinel - Data from Table 1, Well Construction Summa ry, from Old Buncombe County Landfill Corrective Action Plan, by SCS Engineers, Dated September 3, 2014. Z - Water levels were collected for these wells but no accurate survey data is available. TOC - Top of Casing. GS - Ground Surface. DNA - Data Not Available A - Abandoned 14175-02 GW Tables (Completion, water levels, and detections).xlsx Prepared By: TJD Table 1 Completion Table 1st 20 Checked By: IAI Table 2 Groundwater VOCs Old Buncombe County Landfill Woodfin, North Carolina Permit No. 1101-MSWLF-1979 BLE Project Number J20-14175-02 Sampled by Pace Analytical Services, LLC. April 27, 2020. TEST UNITS MRL MD L MCL MW-B MW-2 NM-3 MW-4 MW-4A NM-5 MW-6 MW-6-192 MW-7 MW-12-25 MW-13-35 MW-13-132 MW-15 NM-17-60 MW-17-137 MW-17-310 MW-18-78 MW-19-75 MW-19-110 MW-21-21 NM-21-94 MW-24-45 MW-24-160 DPI-1 Acetone mg/I 20 0.4 6,000 <20.0 <20.0 <20.0 <20.0 54 <20.0 5.5 J 8.5 J 5.1 J <20.0 <20.0 <20.0 9.4 J <20.0 <20.0 5.2 J 5.9 J <20.0 <20.0 <20.0 <20.0 Dry <20.0 Dry Acrylonitrile m9/1 20 0.4 NE <20.0 <20.0 <20.0 <20.0 <20.0 <20.0 <20.0 <20.0 <20.0 <20.0 <20.0 <20.0 <20.0 <20.0 <20.0 <20.0 <20.0 <20.0 <20.0 <20.0 <20.0 Dry <20.0 Dry Benzene mg/I 1.0 0.4 1.0 <1.0 <1.0 1.6 0.81 J 5.9 0.68 J 1.4 <].0 1.5 <1.0 1.8 <1,0 <1.0 <1.0 <1.0 <1.0 0.50 J <1.0 <1.0 Dry <1.0 Dry Bromochloromethane mg/1 1.0 0.4 NE <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry Bromodichloromethane mg/1 1.0 0.4 0.6 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry Bromoform mg/1 1.0 0.5 4.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry Carbon Disulfide mg/1 1.0 0.8 700 <1.0 <1.0 <1.0 0.49 J <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry Bromomethane (Methylbromide) mg/I 2.0 0.4 10.0 (i) <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Dry <2.0 Dry Carbon tetrachloride mg/1 1.0 1 0.4 0.3 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry Chlorobenzene (mono) mg/I 1.0 0.4 50.0 1.1 <1.0 4.2 5 16 9.1 10 1.3 7.4 <1.0 7.2 <1.0 <1.0 <1.0 <1.0 <1.0 3.3 5.1 <1.0 18 1.5 Dry <1.0 Dry Chloroethane m9/1 2.0 0.4 3,000 0.65 J <2.0 3.4 2 <2.0 1.2 J 4.2 0.77 J 2.4 <2.0 <2.0 <2.0 <2.0 <2.0 0.49 J <2.0 0.70 J <2.0 0.58 J <2.0 2.8 Dry <2.0 Dry Chloroform mg/I 1.0 0.4 70.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry Chloromethane (Methylchloride) mg/1 1.0 0.5 3.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry Dibromochloromethane mg/1 1.0 0.4 NE <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry 1,2-Dibromo-3-chloropropme; DBCP mg/I 1.0 0.4 0.04 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry 1,2-Dibromoethane; Ethylene dibromide m9/1 1.0 0.4 0.02 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry Dibromomethane mg/I 1.0 0.4 70.0 (i) I <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry 1,2-Dichlorobenzene mg/1 1.0 1 0.4 20.0 <1.0 <1.0 1 0.89 J 0.53 J 6.7 <1.0 <1.0 <1.0 <1.0 <1.0 5 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 3.1 <1.0 Dry <1.0 Dry 1,4-Dichlorobenzene mg/1 1.0 0.4 6.0 1.9 11.0 va 5.8 4.2 0.55 J 3.4 Q.0 23 1.2 <1.0 1.3 0.73 J <1.0 2.5 5.1 0.44 J 2.7 Dry <1.0 Dry trans-1,4-Dichloro-2-butene mg/I 2.0 0.5 NE <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Dry <2.0 Dry 1,1-Dichloroethane m9/1 1.0 0.4 6.0 1.7 <1.0 2.8 7.9 <1.0 0.68 J 2.5 0.69 J 3.2 <1.0 <1.0 1.2 <1.0 1.2 0.80 J <1.0 0.96 J 0.69 J <1.0 2.9 0.81 J Dry <1.0 Dry 1,2-Dichloroethane mg/I 1.0 0.4 0.4 <1.0 <1.0 0.47 J 0.49 J <1.0 <1.0 <1.0 <1,0 <1.0 <1.0 <1.0 <1.0 <1,0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 0.47 J Dry <1.0 Dry 1,1-Dichloroethene(-ethylene) m9/1 1.0 0.4 7.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry cis-1,2-Dichloroethene (-ethylene) mg/I 1.0 0.4 70.0 23 <1.0 0.99 J 15 1.2 <1.0 0.60 J <1.0 19 <1.0 3.1 8.4 <1.0 1.8 <1.0 <1.0 0.99 J <1.0 0.46 J 6.5 2.5 Dry <1.0 Dry trans-1,2-Dichloroethene (-ylene) mg/1 1.0 0.4 100 <1.0 <1.0 <1.0 <1.0 0.46 J <1.0 <1.0 <1.0 <1.0 <1.0 0.40 J <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 I <1.0 Dry <1.0 Dry 1,2-Dichloropropme m9/1 1.0 0.4 0.6 1 <1.0 <1.0 I <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry cis-1,3-Dichloropropene (-propylene) mg/I 1.0 1 0.4 0.4 <1.0 <1.0 I <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry trans-1,3-Dichloropropene (-propylene) mg/1 1.0 0.4 0.4 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry Ethylbenzene mg/I 1.0 0.4 600 <1.0 <1.0 <1.0 <1.0 11 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry 2-Hexanone mg/1 10 2.0 40.0 0) <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 Q0.0 <10.0 <10.0 <10.0 <10.0 Q0.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 Dry <10.0 Dry Iodomethane mg/I 5.0 0.4 NE <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Dry <5.0 Dry Dichloromethane (Methylene chloride) mg/I 1.0 0.4 5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry 2-Butanone (Methyl ethyl ketone) mg/1 10 2.0 4000 2.2 J <10.0 <10.0 <10.0 1 140 <10.0 <10.0 I <10.0 <10.0 I <10.0 <10.0 <10.0 2.3 J <10.0 <10.0 I <10.0 <10.0 I <10.0 <10.0 <10.0 <10.0 I Dry <10.0 Dry 4-Methyl-2-Pentanone mg/I 10 2.0 NE <10.0 <10.0 <10.0 <10.0 32 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 Dry <10.0 Dry Styrene mg/1 1.0 0.41 70.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry 1, 1, 1,2-Tetrachloroethme m9/1 1.0 0.4 1.0 (i) <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry 1, 1,2,2-Tetrachloroethme mg/I 1.0 0.4 NE <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry Tetrachloroethene (-ethylene) m9/1 1.0 0.4 0.7 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry Toluene mg/I 1.0 0.4 600 <1.0 <1.0 <1.0 <1.0 3.3 <1.0 0.40 J <1,0 <1.0 <1.0 <1.0 <1.0 <1,0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry 1,1,1-Trichloroedmne m9/1 1.0 0.4 200 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry 1,1,2-Trichloroedme m9/1 1.0 0.4 0.6 (i) <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry Trichloroethene (-ethylene) mg/1 1.0 0.4 3.0 <1.0 <1.0 <1.0 0.73 J <1.0 <1.0 <1.0 <1.0 0.81 J I <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 0.43 J <1.0 Dry <1.0 Dry Trichloroflumomethane m9/1 1.0 0.4 2,000 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry 1,2,3-Trichloropropane mg/I 1.0 0.4 0.005 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry Vinyl acetate mg/1 2.0 1.2 98.0 (i) <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Dry <2.0 Dry Vinyl chloride mg/I 5.0 0.4 0.03 7.7 <5.0 0.91 J 2.3 1.2 <5.0 <5.0 <1.0 <1.0 6.5 28 <5.0 <5.0 <5.0 0.64 J <5.0 0.78 J <1.0 0.52 J <5.0 0.58 J <5.0 <5.0 1.6 0.92 J Dry <5.0 Dry Total Xylenes mg/1 1.0 0.4 500 <1.0 <1.0 0.98 J <1.0 19 <1.0 0.42 J <1.0 <1.0 <1.0 <1.0 0.46 J <1.0 11.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry 1,4-Dioxane mgA 3.0 1.0 3.0 34 <3.0 92 25 15 5.2 <3.0 <3.0 <3.0 <3.0 <3.0 32 <3.0 50 96 29 18 48 Dry <3.0 Dry A . II Volatile Organic Compounds VOC's Various Various Various NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable to Groundwaters of North Carolina, Section 15A NCAC 2L. 202. Dated April 1, 2013 2. (i) = Interim Maximum Allowable Concentrations (IMACs) April 6, 2018 - Non Regulatory (Reference Only) 3. Shaded cells indicate exceedances of IMACs 4. Shaded cells indicated exceedances of MCLs 5. NE = Not Established; North Carolina has not established a MCL 6. MRL = Laboratory Method Reporting Limit 7. MDL = Minimum Laboratory Detection Limit 8. NT = Not Tested 9. "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are presented on this spreadsheet. 14175-02 GW Tables (Completion, water levels, and detections).xlsx Table 2 (4-27-20) APP. VOC Prepared By: TJD Checked By: IAI Table 3 Groundwater Field Parameters and Total Metals Old Buncombe County Landfill Woodfin, North Carolina Permit No. 1101-MSWLF-1979 BLE Project Number J20-14175-02 Sampled by Pace Analytical Services, LLC. April 27, 2020. TEST UNITS MRL MDL MCL MW-B MW-2 MW-3 MW-4 MW4A MW-5 MW-6 AM-6-192 MW-7 MW-12-25 MW-13-35 MW-13-132 MW-15 MW-17-60 MW-17-137 MW-17-310 MW-18-78 MW-19-75 MW-19-110 MW-21-21 MW-21-94 MW-2445 MW-24-160 DPL-1 EQUIP. BLANK PH S.U. - >6.5; <8.5 6.6 6.3 6.9 6.2 6.1 6.4 6.2 6.4 5.7 6.4 5.7 7.1 12.4 6.8 7.3 8.4 6.4 6.3 7.6 6.4 6.7 Dry 7.3 Dry NT Specific Conductance mmhos/cm - NE 679.0 133.5 1,349 11000 733.00 1,332 1,381 465.2 208.2 566 355.9 381.0 6,957 608.0 864.0 146.2 971.0 1,217 438.5 1,321 872.0 Dry 198.0 Dry NT Temperature °C NE 16.8 19.4 15.2 13.8 17.4 13.3 17.1 21.8 15.1 18.9 16.5 18.7 18.8 15.9 18 17 17.8 17.6 16.8 17.4 15.8 Dry 17.6 Dry NT Turbidity NTU NE 9.4 5.1 7.7 1 2.16 2.3 2.9 0.8 9.5 1.75 1.1 2.82 2.6 8.92 1.35 8.37 1.8 0.6 0.9 0.2 0.01 Dry 9.3 Dry NT Dissolved Oxygen (DO) mg/L NE 0.3 5 1 1.2 0.31 0.5 0.9 0.9 0.2 2.15 1.35 0.36 3.1 0.58 1.77 1.53 1 0.6 0.7 0.8 0.6 Dry 0.7 Dry NT Redox mV NE -50 64.5 -40 21.4 -78 -20.6 -45 -41.1 -24.9 164.7 225.8 -139.4 -28.3 -82 -99.1 -80.4 -86.3 -39.8 -56.4 -50.8 -32.9 Dry 43 Dry NT Total Antimony (Sb) mg/I 2.0 0.5 1.0 (i) <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Dry <2.0 Dry <2.0 Total Arsenic (As) mg/I 2.0 1.3 10.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Dry <2.0 Dry <2.0 Total Barium (Ba) mg/I 5.0 1.3 700 180 23 240 610 840 140 64 220 69 180 40 170 24 26 3.5 J 73 130 10 120 53 Dry 18 Dry 4.5 J Total Beryllium (Be) m9/1 0.4 0.15 4.0 (i) <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 0.19 J <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Dry <0.4 Dry <0.4 Total Cadmium (Cd) m9/1 0.5 0.13 2.0 <0.5 <0.5 0.17 J 0.5 <0.5 <0.5 <0.5 <0.5 0.20 J <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 Dry <0.5 Dry <0.5 Total Chromium (Cr) mg/1 5.0 1.3 10.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 1 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 1 <5.0 <5.0 Dry <5.0 Dry <5.0 Total Cobalt (Co) 1119/1 5.0 1.3 1.0 (i) <5.0 <5.0 16 WEEP= NEW= 9.5 <5.0 <5.0 1JU240i <5.0 1.3 J <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 3.2 J <5.0 13 <5.0 Dry <5.0 Dry <5.0 Total Copper (Cu) 1119/1 5.0 1.3 1000 <5.0 2.1 J <5.0 <5.0 3.5 J <5.0 1.4 J <5.0 11 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Dry 4.3 J Dry 1.6 J Total Lead (Pb) mg/I 1.0 0.3 15.0 <1.0 0.63 J <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 0.88 J <1.0 <1.0 0.53 J <1.0 <1.0 <1.0 <1.0 <1.0 Dry 1 Dry <1.0 Total Mercury (Hg) mg/1 NT NT 1.0 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT Dry NT Dry NT Total Nickel (Ni) m9/1 5.0 1.3 100.0 1.3 J 2.9 J 28 96 12 16 11 2.6 J 70 18 4.5 J <5.0 5.4 <5.0 <5.0 <5.0 6.4 24 3.7 J 3.5 J 8.5 Dry 1.9 J Dry <5.0 Total Selenium (Se) m9/1 5.0 1.3 20.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Dry <5.0 Dry <5.0 Total Silver (Ag) 1119/1 1.0 0.3 20.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Dry <1.0 Dry <1.0 Total Thallium (TI) 1119/1 0.5 0.2 0.2 (i) <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 Dry <0.5 Dry <0.5 Total Tin mg/I NT NT 2000 (i) NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT Dry NT Dry NT Total Vanadium (V) 1119/1 5.0 2.5 0.3 (i) <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Dry <5.0 Dry <5.0 Total Zinc Zn m 10.0 2.5 1000.0 <10.0 5.0 J 12 18 2.8 J 5.7 J 2.6 J 2.8 J 1 1 11 3.1 J 2.9 J 2.9 J <10.0 <10.0 4.6 J <10.0 3.5 J <10.0 <10.0 <10.0 Dry 7.8 J Dry <10.0 Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable to Groundwaters of North Carolina, Section 15A NCAC 2L. 202. Dated April 1, 2013 2. (i) = Interim Maximum Allowable Concentrations (IMACs) April 6, 2018 - Non Regulatory (Reference Only) 3. Shaded cells indicate exceedances of IMACs 4. Shaded cells indicated exceedances of MCLs 5. NE = Not Established; North Carolina has not established a MCL 6. MRL = Laboratory Method Reporting Limit 7. MDL = Minimum Laboratory Detection Limit 8. NT = Not Tested 9. "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are presented on this spreadsheet. 14175-02 GW Tables (Completion, water levels, and detections).xlsx Table 3 (4-27-20) APP. I Met Prepared By: TJD Checked By: IAI Table 4 Surface Water VOCs Old Buncombe County Landfill Woodfin, North Carolina Permit No. 1101-MSWLF-1979 BLE Project Number J20-14175-02 Sampled by Pace Analytical Services, LLC. April 27, 2020. TEST UNITS MBL MDL NC211 SW-1 SW-2 SAVA 503 SW-4 Acetone µg/1 25 0.4 2,000 <25.0 <25.0 <25.0 <25.0 5.7 J Acrylonitrile µg/1 10.0 0.4 7.0 <10.0 <10.0 <10.0 <10.0 <10.0 Benzene µg/l 1.0 0.4 HA <1A <1A <1A <1A Q.0 Bromochloromethane µg', 1.0 0.4 NE <1A <1A <1A <1A <1.0 Bromodichloromethane µg/1 1.0 0.4 NE <1A <1A <1A <1A <1.0 Bromoform µg/1 1.0 0.5 IN AA AA AA AA 9.0 Carbon Disulfide µg/l 2.0 0.8 100 <2.0 <2.0 <2.0 <2.0 <2.0 Bromomethane (Methylbromide) 99/1 2.0 0.4 0.04 <2.0 <2.0 <2.0 <2.0 <2.0 Carbon tetrachloride µg/I 1.0 0.4 1A 0A 0A 0A 0A 0.0 Chlorobenzene (mono) µg/1 1.0 0.4 800 Q.0 Q.0 Q.0 Q.0 0.0 Chloroethane µg" 1.0 0.4 NE MA MA MA MA 0.0 Chloroform µg/1 5.0 0.4 2,000 <5.0 <5.0 <5.0 <5.0 <5.0 Chloromethane(Methylchloride) 99/1 1.0 0.5 %1 A A A A 0.0 Dibromochloromethane µg/1 1.0 0.4 NE QT QT QT QT 0.0 1,2-Dibromo-3-chlompropane; DBCP 99/1 5.0 0.4 0.13 <5.0 <5.0 <5.0 <5.0 <5.0 1,2-Dibromoethane; Ethylene dibromide 99/1 1.0 0.4 03 of of of of 0.0 Dibromomethane µg/d 1.0 0.4 NE Q.0 Q.0 Q.0 Q.0 0.0 1,2-Dichlorobenzene µg" 1.0 0.4 3,000 <1.0 <1.0 <1.0 <1.0 <1.0 1,4-Dichlorobenzene µg/1 1.0 0.4 900 Q.0 Q.0 Q.0 Q.0 Q.0 trans-1,4-Dichloro-2butene µ 1 1.0 0.5 NE <1.0 <1.0 <1.0 <1.0 <1.0 1,1-Dichloroethene µg/1 1.0 0.4 100 <1A <1A <1A <1A <1.0 1,2-Dichloroethane 99/1 1.0 0.4 650 AA AA AA AA 4.0 1, 1 -Dichloroethene (-ethylene) 99/1 1.0 0.4 21,000 <1.0 <1.0 <1.0 <1.0 0.0 cis-1,2-Dichloroethene (-ethylene) 99/1 1.0 0.4 720 <1.0 <1.0 <1.0 <1.0 0.0 trans-1,2-Dichloroethene (-ylene) 99/1 1.0 0.4 4,000 <1.0 <1.0 <1.0 <1.0 <1.0 1,2-Dichloropropene µg/1 1.0 0.4 31.0 Q.0 Q.0 Q.0 Q.0 9.0 cis-1,3-Dichloropropene(-propylene) µ9/1 1.0 0.4 NE MA MA MA MA 0.0 trans-1,3-Dichloropropene(-propylene) µg/l 1.0 0.4 NE of of of of 0.0 Ethylbenzene µg', 1.0 0.4 IN <lA <lA <lA <lA <1.0 2-Hexanone µg/1 5.0 2.0 NE <5.0 <5.0 <5.0 <5.0 <5.0 Iodomethane µg/1 20.0 0.4 NE <20.0 <20.0 <20.0 <20.0 <20.0 Dichloromethane (Methylene chloride) 99/1 5.0 0.4 1,000 <5.0 <5.0 <5.0 <5.0 <5.0 2-Butanone (Methyl ethyl ketone) 99/1 5.0 2.0 26,000 <5.0 <5.0 <5.0 <5.0 <5.0 4-Methyl-2-Pentanone µg/I 5.0 2.0 NE <5.0 <5.0 <5.0 <5.0 <5.0 Styrene µo 1.0 0.41 NE Q.0 Q.0 Q.0 Q.0 0.0 1,1,1,2-Tetrachloroethane µ9/1 1.0 0.4 NE MA MA MA MA 0.0 1,11,2-Tetrummoethane µg/l 1.0 0.4 4.0 <IM <IM <IM <IM Q.0 Tetrachloroethene(-ethylene) 99/1 1.0 0.4 3.3 AA AA AA AA 0.0 Toluene µg/1 1.0 0.4 11.0 QT QT QT QT 0.0 1,1,1-Trichloroethane 99/1 1.0 0.4 200,000 <1.0 <1.0 <1.0 <1.0 <1.0 1, 1,2-Trichloroethane µg/I 1.0 0.4 8.9 0A 0A 0A 0A 0.0 Trichlomethene (-ethylene) 99/1 1.0 0.4 30.0 Q.0 Q.0 Q.0 Q.0 0.0 Trlchlorofluoromethane µg/1 1.0 0.4 67,000 <1.0 <1.0 <1.0 <1.0 <1.0 1,2,3-Trichloropropare µg/1 1.0 0.4 0.001 <1.0 <1.0 <1.0 <1.0 <1.0 In acetate µ<2.0 <2.0 <2.0 Vinylchloride µg/l 1.0 0.4 2.4 <1.0 <1.0 <1.0 <1.0 <1.0 Total Xylenes µg/1 2.0 0.4 1 670 <2.0 1 <2.0 <2.0 1 <2.0 <2.0 1,4-dioxane 1 2.0 1.0 1 80.0 <2.0 1 <2.0 7.9 1 36 61 Notes: NC2B - North Carolina Surface Water Standards for Class B freshwater under Title 15A Subchapter 2B. per NC DWR Surface Water Quality Standards, Criteria, & In -Stream Target Values (Workbook Dated 6-10-2019) NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit "P"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are presented on this spreadsheet. 14175-02 SW Tables.xlsx Prepared By: T.ID Table 4 SW VOC (4-27-20) Checked By: IAI Table 5 Surface Water Field Parameters and Total Metals Old Buncombe County Landfill Woodfin, North Carolina Permit No. 1101-MSWLF-1979 BLE Project Number J20-14175-02 Sampled by Pace Analytical Services, LLC. April 27, 2020. TEST UNITS MRL MDL NC211 SW-1 NC2B SW-2 NC2B SW-2A NC2B SW-3 NC211 SW4 PH S.U.(on-site) <6.0,>9.0 7.3 <6.0,>9.0 7.6 16.0,>9.0 7.8 <6.0,>9.0 7.3 <6.0,>9.0 8 Specific Conductance µmhos/cm (on -site) NE 51 NE 49 NE 313 NE 554 NE 1333 Temperature oC (on -site) 29.0 14.6 29.0 14.6 29.0 13.5 29.0 15.2 29.0 19.7 Turbidity NTU (on -site) 50.0 8.9 50.0 7.9 50.0 6 50.0 38.4 50.0 123.7 Hardness mg/L 10 2.0 NE 12 NE 12 NE 110 NE 170 NE 390 Dissolved Oxygen mg/L 15.0 9.6 <5.0 9.2 <5.0 8.6 15.0 9.2 <5.0 5.4 Redox mV NE 39.6 NE 22.2 NE 52.1 NE 55.7 NE 79.3 Total Antimony(Sb) µg/l 2.0 0.5 5,300 <2.0 5,300 <2.0 5,300 <2.0 5,300 <2.0 5,300 <2.0 Total Arsenic (As) Total Barium (Ba) µg/I ligA 2.0 5.0 1.3 1.3 10.0 21,000 <2.0 13 10.0 21,000 <2.0 14 10.0 21,000 <2.0 32 10.0 21,000 <2.0 110 10.0 <2.0 21,000 120 Total Beryllium (Be) µg/I 0.4 0.15 65.0 <0.4 65.0 <0.4 65.0 <0.4 65.0 <0.4 65.0 <0.4 Total Cadmium (Cd) Total Chroudum (Cr) µ µg/I 0.5 5.0 0.13 1.3 0.43 100.36 <0.5 <5.0 0.43 100.36 <0.5 <5.0 2.98 616.02 <0.5 <5.0 4.35 879.9 <0.5 <5.0 8.95 <0.5 1736.91 15.0 Total Cobalt (Co) lLgIl 5.0 1.3 16.0 <5.0 16.0 <5.0 16.0 <5.0 16.0 3.1 J 16.0 11 Total Copper (Cu) µg/I 5.0 1.3 1.82 <5.0 1.82 <5.0 14.7 <5.0 22.16 <5.0 48.45 <5.0 Total Lead (Pb) µ 1.0 0.25 6.04 0.37 J 6.04 0.42 J 71.63 11.0 114.5 1I.0 273.64 <I.0 Total Memory (Hg) µg/l NT NT 0.012 NT 0.012 NT 0.012 NT 0.012 NT 0.012 NT Total Nickel (NI) lign 5.0 1.3 77.88 15.0 77.88 <5.0 507.55 1.5 J 733.54 4.8 J 1480.83 21 Total Selenium (Se) is, 5.0 1.3 5.0 <5.0 5.0 <5.0 5.0 <5.0 5.0 <5.0 5.0 1.5 J Total Silver (A 11 0.25 0.08 <1.0 0.08 <1.0 3.79 <1.0 8.01 <I.0 33.42 <I.0 Total Thallium (T]) µg/1 0.5 0.15 NE <0.5 NE <0.5 NE <0.5 NE <0.5 NE <0.5 Total Vanadium(V) PgA 5.0 2.5 NE <5.0 NE <5.0 NE <5.0 NE <5.0 NE <5.0 Total Zinc Zn 10.0 2.5 19.44 7.2 J 19.44 4.1 J 127.04 <10.0 183.7 3.0 J 371.25 <I0.0 Notes: NC2B = North Carolina Surface Water Standards for Class C freshwater under Tide 15A Subchapter 211. MRL = Laboratory Method Reporting Limit per NC DWR Surface Water Quality Standards, Criteria, & In -Stream Target Values (Workbook Dated 6-10-2019) MDL = Laboratory Method Detection Limit Measured values of hardness were utilized to calculate an acute standard at each surface water location for metals highlighted in green. NT =Not Tested NE = Not Established; North Carolina has not established a standard DNA = Data Not Available "3'-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are presented on this spreadsheet. 14175-02 SW Tables.xlsx Prepared By: TJD Table 5 SW Metals (4-27-20) Checked By: IAI Table 6 Groundwater Transects for Remedial Monitoring Old Buncombe County Landfill Woodfin, North Carolina Permit No. 1101-MSWLF-1979 BLE Project Number J20-14175-02 Transect I Transect 2 Transect 3 Transect 4 1 Transect 5 MW-4A MW-B MW-3 DPL-2 MW-6 MW-12-25 MW-17-60 MW-21-21 MW-4 MW-6-192 MW-13-35 MW-17-137 MW-21-194 MW-19-75 MW-5 MW-13-132 MW-19-110 DPL-1 MW-24-45 MW-18-78 MW-24-160 Bold - MNA Performance Well 14175-02 GW Tables (Completion, water levels, and detections).xlsx Prepared By: TJD Table 6 Transect Numbers Checked By: IAUAWA Table 7 Groundwater Geochemical Parameters for MNA Old Buncombe County Landfill Woodfin, North Carolina Permit No. 1101-MSWLF-1979 BLE Project Number J20-14175-02 Sampled by Pace Analytical Services, LLC. April 27, 2020. TEST UNITS MRL MDL MCL MW-B MW-2 NM-3 MW-4 MW-4A MW-5 MW-6 MW-6-192 MW-7 MW-12-25 MW-13-35 MW-13-132 MW-15 MW-17-60 MW-17-137 MW-17-310 NM-18-78 MW-19-75 MW-19-110 MW-21-21 MW-21-94 NM-24-45 MW-24-160 DPL-1 Dissolved Hydrogen (DH) nM 1.0 1.0 NE NT 51 NT 21 NT NT 8.2 NT NT NT NT 3.0 NT NT NT NT 4.6 5.0 5.4 7.7 3.6 NT 27 NT Lactic Acid mg/I 0.2 0.085 NE NT <0.2 NT <0.2 NT NT <0.2 NT NT NT NT <0.2 NT NT NT NT <0.2 <0.2 <0.2 <0.2 <0.2 NT <0.2 NT Acetic Acid m9/1 0.1 o.mv 5.0 (i) NT <0.1 NT <0.1 NT NT <0.1 NT NT NT NT <0.1 NT NT NT NT <0.1 <0.1 <0.1 <0.1 <0.1 NT 0.05 J NT Propionic Acid mg/I 0.1 0.001 NE NT 0.0014 J NT 0.0018 J NT NT 0.003 J NT NT NT NT 0.0013 J NT NT NT NT 0.0036 J 0.004 J 0.0015 J <0.1 0.0023 J NT 0.0048 J NT Formic Acid mg/I 0.5 0.12 NE NT <0.5 NT <0.5 NT NT <0.5 NT NT NT NT <0.5 NT NT NT NT 0.13 J <0.5 <0.5 <0.5 <0.5 NT <0.5 NT Butyric Acid mg/1 0.1 0.009 NE NT <0.1 NT <0.1 NT NT <0.1 NT NT NT NT <0.1 NT NT NT NT <0.1 <0.1 <0.1 <0.1 <0.1 NT <0.1 NT Pyruvic Acid mg/I 0.1 0.014 NE NT <0.1 NT <0.1 NT NT 0.016 J NT NT NT NT <0.1 NT NT NT NT 0.016 J 0.026 J <0.1 <0.1 <0.1 NT <0.1 NT i-Pentanoic Acid m9/1 0.1 0.007 NE NT <0.1 NT <0.1 NT NT <0.1 NT NT NT NT <0.1 NT NT NT NT <0.1 0.0085 J <0.1 <0.1 <0.1 NT <0.1 NT Pentanoic Acid mg/I 0.1 0.005 NE NT <0.1 NT <0.1 NT NT 0.052 J NT NT NT NT <0.1 NT NT NT NT <0.1 0.019 J <0.1 <0.1 0.039 J NT <0.1 NT i-Hexanoic Acid mg/I 0.2 0.01 NE NT <0.2 NT <0.2 NT NT <0.2 NT NT NT NT <0.2 NT NT NT NT <0.2 <0.2 <0.2 <0.2 <0.2 NT <0.2 NT Hexanoic Acid mg/I 0.2 0.02 NE NT <0.2 NT <0.2 NT NT <0.2 NT NT NT NT <0.2 NT NT NT NT <0.2 <0.2 <0.2 <0.2 <0.2 NT <0.2 NT Methane ugll 0.5 0.023 NE NT 3.0 NT 0.20 J NT NT 1600 NT NT NT NT 240 NT NT NT NT 1400 0.28 J 690 1100 3700 NT 490 NT Ethane ug/1 0.1 0.01 NE NT <0.1 NT <0.1 NT NT 0.38 NT NT NT NT 0.072 J NT NT NT NT 0.078 J <0.1 0.16 0.39 0.7 NT 0.11 NT Ethene ug/l 0.1 0.009 NE NT 0.024 J NT 0.059 J NT NT 0.21 NT NT NT NT 0.057 J NT NT NT NT 0.3 0.019 J 1.6 0.068 J 0.28 NT 0.14 NT Carbon Dioxide (CO2) mg/I 5.0 0.27 NE NT 58 NT 4.4 J NT NT 120 NT NT NT NT 8.5 NT NT NT NT 360 59 31 220 580 NT 390 NT Allcalinity mg/I 20 20 NE NT 61 NT 440 NT NT 550 NT NT NT NT 150 NT NT NT NT 300 400 160 680 320 NT 60 NT Sulfide mg/I 1.0 0.99 NE NT <1.0 NT <1.0 NT NT <1.0 NT NT NT NT 1.1 NT NT NT NT <1.0 <1.0 <1.0 <1.0 <1.0 NT <1.0 NT Biological Oxygen Demand (BOD) mg/I 2.0 0.18 NE NT <2.0 NT 2.0 NT NT 8.2 NT NT NT NT <2.0 NT NT NT NT 2.9 2.2 <2.0 3.1 2.2 NT 5.8 NT Sulfate mg/I 1.0 0.2 250 NT 2.9 NT 24 NT NT 1.3 NT NT NT NT 8.2 NT NT NT NT 1.4 14 12 38 2.2 NT 23 NT Nitrate mg/l 0.02 0.005 10 NT 0.014 J NT <0.02 NT NT <0.02 NT NT NT NT <0.02 NT NT NT NT <0.02 <0.02 <0.02 <0.02 <0.02 NT <0.02 NT Chloride mg/I 1.0 0.2 250 NT 2.1 NT 67 NT NT 140 NT NT NT NT 4.8 NT NT NT NT 130 160 38 50 99 NT 7.4 NT Chemical Oxygen Demand (COD) mg/I 20 20 NE NT <20 NT <20 NT NT 37 NT NT NT NT <20 NT NT NT NT 25 38 <20 33 20 NT <20 NT Total Organic Carbon (TOC) mg/I 1.0 1.0 NE NT <1.0 NT 6.2 NT NT 10 NT NT NT NT <1.0 NT NT NT NT 7.6 13 2.0 12 7.3 NT 2.6 NT Iron II field measured u 500 500 NE NT <500 NT 2.0 NT NT 5.0 NT NT NT NT 4.5 NT NT NT NT 4.5 2.5 3.0 3.5 3.0 NT <500 NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable to Groundwaters of North Carolina, Section 15A NCAC 2L. 202. Dated April 1, 2013 2. (i) = Interim Maximum Allowable Concentrations (IMACs) April 6, 2018 - Non Regulatory (Reference Only) 3. Shaded cells indicate exceedances of IMACs 4. Shaded cells indicated exceedances of MCLs 5. NE =Not Established; North Carolina has not established a MCL 6. MRL = Laboratory Method Reporting Limit 7. MDL = Minimum Laboratory Detection Limit 8. NT -Not Tested 9. "J"-flagged data (i.e., values estimated between the laboratory method detection limit [MDL] and the MRL) are presented on this spreadsheet. 14175-02 GW Tables (Completion, water levels, and detections).xlsx Table 7 J VALUES (4-27-20) MNA Prepared By: TJD Checked By: IAI Figures r O � z z H D 25 o Rj z \1 AIKfN St W FOMCHASE'R_D 0 6F Do f ��s 0 CHADWICK WADE'DR � GGG� O ASAA17 u, .r D - - - Ashelawn Gardens MMemory Q emorial Garden � P ! ti 'S- O BAN l �R ODF'IN 1104si G ldvievnob ?CH U l/ PRO D _ ench Broad zve z�D 25 gAIA $ C' IOLivette-Cem� fq 70 ry. ® eo 00 3 pD,ygNRO AL7(� q Ploy �cQ Old Macedonia f Cem 1, 251 N Akp UpLB�N:pR " 3 Bus 23 I 0 1 b OODFIiN r0 N 0 0 m, Q) REFERENCES: Mour USGS TOPOGRAPHIC MAP, 7.5 2000 1000 0 2000 4000 r MINUTE SERIES, WEAVERVILLE AND APPROXIMATE SCALE IN FEET LEICESTER. NC. QUADRANGLE 2019 ;; ' „� , DRAWN: KLW DATE: 6-19-20 BUNNELL FIGURE IM M LAMMONS SITE LOCATION MAP CHECKED: TJD CAD: BCOLF02—SLM M ENGINEERING OLD BUNCOMBE COUNTY LANDFILL 6004 Ponders Court, Greenville, SC 29615 WOODFIN, NORTH CAROLINA 1 APPROVED: AWA JOB NO: J20-14175-02 Phone: (864) 288-1265 Fax: (864) 288-4430 250 125 0 250 500 APPROXIMATE SCALE IN FEET I o0 f 0 I q , LAN, ACTIVE MONITORING WELLS INACTIVE MONITORINC WELLS �BANDONE[ IONITORINC WELLS ACTIVE SURFACE WATER SAMPLING LOCATIONS INACTIVE SURFACE WATER SAMPLING LOCATIONS MW-2 MW-8 MW-9 SW-1 SW-5 MW-3 MW-12-10 MW-10 SW-2 SW-6 MW-4 MW-13-10 MW-16 SW-2A SW-7 MW-4A MW-14 MW-17 SW-3 SW-8 MW-5 MW-18-3 DPL-2 SW-4 SW-9 MW-6 MW-19-4 MW-6-192 MW-20-3 MW-7 MW-20-32 MW-12-25 MW-21-4 MW-13-35 MW-22-78 MW-13-132 MW-22-143 MW-15 MW-23-119 MW-17-60 MW-23-186 MW-17-137 MW-A MW-17-310 MW-18-78 MW-19-75 MW-19-110 M W-21-21 M W-21-94 M W-24-45 M W-24-160 DPL-1 M W-B NOTE: ACTIVE SAMPLING MONITORING WELLS AND SURFACE LOCATIONS ARE TO BE SAMPLED AND TESTED TWICE ANNUALLY. INACTIVE MONITORING WELLS ARE TO BE CHECKED FOR DEPTH TO GROUNDWATER ONLY. *WATER LEVEL IS DEEP AND NOT USED FOR CONTOURING PURPOSES. ** WATER LEVELS COLLECTED BUT NO VERIFIABLE SURVEY DATA COLLECTED FOR GROUNDWATER ELEVATION CONTOURING PURPOSES. NM -NOT MEASURED 1 rr11rN1r'\ MW-2® ACTIVE GROUNDWATER MONITORING WELL MW-8® INACTIVE GROUNDWATER MONITORING WELL MW-8 & ABANDONED GROUNDWATER MONITORING WELL SW-1- ACTIVE SURFACE WATER MONITORING LOCATION SW-54 INACTIVE SURFACE WATER MONITORING LOCATION PROPERTY BOUNDARY SURFACE WATER POTENTIOMETRIC CONTOUR GROUNDWATER FLOW DIRECTION 200 100 0 200 400 APPROXIMATE SCALE IN FEET REVISIONS No. DESCRIPTION BY DRAWN: TJD CHECKED: IAI APPROVED: AWA DATE: 5-26-20 CAD FILE: BCOLF-02WTM NO: J20-14175-02 IM BUNNELL � LAMMONS ENGINEERING 6004 Ponders Court, Greenville, SC 29615 Phone: (864) 288-1265 Fax: (864) 288-4430 GROUNDWATER ELEVATION CONTOUR MAP — APRIL 27, 2020 OLD BUNCOMBE COUNTY LANDFILL WOODFIN, NORTH CAROLINA FIGURE NO. 2 APPENDIX A FIELD SAMPLING LOGS PACE ANALYTICAL SERVICES, LLC. dC8AnaljftNy Document Name: Field data Sheet Date Issued: March 8, 2019 PaLe: 1 of r Document [Number: F-CAR-FLD-001-rev.03 issuing Authority: Pace Huntersvilte Quality Office Field Data Sheet Client: kx�, CQ ,Location: &k9A.r I Le ..0 C Project #: {34_0C-n mbf Cn. Clc( L Ft}Q^ri �Oa p Name and Affiliation (Sampler(s): - pry( -a, Ac i [ Field Data Sheet Review: Name and Affiliation (Inspector): h)l Date: 511 (7.0 By: C' Well Information Well ID: M Well Locked: { / NO / Flushmount ) Well Diameter: o�, Construction: /Steel/Stainless St eel) Total Well Depth: a3.4 _ft Multi Factor*: 0.163 [*(Radius/ 12)2 x 3.14 x 7.48] Static Water Level: �a n ft Height of Water Column: ] Q ft Casing Volume: 3. 3 I gallons Cal. 3 Volumes: gallons Pump Intake: c�� QQ �ft Purge Information Date Purged: 09 / j Start: 1 j — Finish: � 3oci Purge Rate: 3 Qom Purging Method: _- Ur)s . }�?.�.r r „nqTot al Volume Purged: 6 (W) (gallons/ is L) 7 Sampling Information Date Collected: Qom. /a�_/ -, -0 )Q Time Collected: y WC (am p_j Sampling Equipment Used:__ \fC..s.5 ViL4_InstrumentID:_ ASS- Psis 741 C`�scrn7Pwa�,c�7� Bottle Type C"nL V1 a1 - LI O , ,L u j cA Field Measurements Observations Preservatibn 9 N0z 140 i-i c Analysis Required 'bDT DIXkst5 L4 P a x ACV _r Unt' Sample Temp (°C): IL :3 Time: f Turbidity (ntu): Time: ; o Diss Oxy (mg/L). 0 ;A Time: 3QC Fe 2+ mg/L: Time: Specific Cond. (uS); (:)'-T '9_ _ Time:. ? Q�_ Res, Cl (mg/L)/(µg/L): f Time:. `! Sample pH (s.u.): - Time: ___L30 �7 Odor: Time: 30 ReDox (mV): - 5 C1. O Time: 130 Appearance: C 1 tcr'— Time: _ 3 o ReDox (EH value):YSI ProPlus +200mVI C) Other: Time: General/Weather Observations:U5i,u\'Dwno jV'e_ k m'L LS ry cloudy/rainy) Temp._ ('F) Wind 5 (mph) Sampler Signature: Date: n LA Stabilization Test Time Purged Temp. (0C) Diss Oxy. (mg/L) Spec' f S) pH (s.u.) ReDox (mV) Turbidity (ntu) o ume removed (gallons/ r / L Water level (ft) Other es` S l 5 '3 i- L ( Ll 0 yI, '5 I;: Document Name: Document issued: March 8, 2019 Field Data Sheet Page -of = .r--aceAr7alylrca� I! Document [number: F-CAR-FLD-001.rev.03 Issueing Authority: Pace Huntersvide Quality Office Client: 6t," n C o M6t co Location: AS6 v 1 UO /U L Project: _Bu o CO M %e Ca - 4 F a i I and WeIIID: Reviewed Date and By: Stabilization Test . ��,r�11.E�i�xns�ar 2LIn1'ra�lirali�n F:arEor° 1 0.0428 1..2 0,0919 1.$ 25 0-.100 2 0.1630 3 '0.3.G70 0.6530 i 3: 2.6-100 Time Purged Temp. (DC) Diss Oxy. (mg/L) Spec. Cjon}. pH(s.u.) ReDox(mV) Turbidity (ntu) Volume Removed (gallons Is L) circle o e Water level (ft) Other -4L LA 0 o _�— o - - _.- ace Artal��ica1 v � Document Name: Field data Sheet ' Date Issued: March 8, 2014 Pa e: 1 of i Document Number: F-CAR-FLD-001-rev.03 Issuing Authority: Pace Huntersville Quality Office Name and Affiliation (Sampler(s): Name and Affiliation (Inspector): Ntq Well Information Well ID: M LJ -'- Well Diameter: 2" - Total Well Depth: 17T. ?6 ft Static Water Level: /O I- 62 ft Height of Water Column: 65. 4 ft Purge Information Well Locked: Construction: #: c Gv oldl-1=-of1 �-Ozo Field Data Sheet Review; Date: S [1 (20 By: GT 8 NO / Flushmount ) Steel) Multi Factor*; G, l6 3 1*(Radius/ 12)2 x 3.14 x 7.48] Casing Volume: to. ba gallons Cal. 3 Volumes: 3 C • gallons Pump Intake: U 9, D C, !'t Date Purge& 0 f-f /-2,C00 Start: W Finish: i 3 O ��__PuAArg��e,, Rate: � l Purging Method: Total Volume Purged: G (gallons/ Is L) Sampling Information Date Collected: 0C1 42-1/ ;0�20 Time Collected:jJ�5 (am/6), Sampling Equipment Used: e., �dv f Instrument ID: Y sr #0139 /TP W#- 4023 Bottle Type Preservation Analysis Required Field Measurements Observations Sample Temp (IC): `� Time; Turbidity (ntu); 5 • I Time, 3 — Diss Oxy (mg/L): 5.• d Time: 3q5 Fe 2+ mg/L: AIP Time: 3q 5 Specific Cond. (uS): 3- S Time: t5g5 Res, C1 (mg/Ly(Fg/L): Time:. Sample pH (s.u.): - Time: 13g3 . Odor: AIV Time: 3yi ReDox (mV): q . 5 Time: l S 6 Appearance; Cle� Time: 13 Zl y ReDox (EH value):YSI ProPlus +200mV Other: Time: General/Weather Observations: /KW -'Z. (sunny c oud airy) Temp.70(OF) Wind A -U (mph) Sampler Signature: Stabilization Test -21-ecru Time Temp. Diss Oxy. Spec. ' pH (s.u.) ReDox Turbidity volume removed Water Other Purged (°C) (mg/L) 5) (mV) (ntu) (gallons ml level (ft) L 1375 l ! 6 Sao( 1 7V , l 6,5 6 $C0 log, 10 13 O (1- 5 5. p 131.0 6.y 63-0 7,9 Ito 00 /p8.K3 5.0 t33.0 6. Lf b 3,C--- 13 r9. 5-1 1 13k.0 1 6.3 63, L 13 a 19.5 5 . D 33 . 6.3 6 Lr - � Zomo 10 , 9 Document Name: Field data Sheet Date Issued: Nrarch 8, 2019 aceAnal34ica1 Page: 1 atV i Document Number. F-CAR-FLD-001•rev.03 Issuing Authority: Pace Huntersvilli Office Field Data Sheet Client: &,7ce n� co Location:. WoodfP! , ^Jr Project #: &P rr \b Go d40 L>•- f}P�.1 ,&Q) Name and Affiliation (Sampler(s): 30S • Field Data Sheet Review: Name and Affiliation (Inspector): NA Well Information Date: S(I 110 By: C"jB Well ID: MW "5 Well Locked; tteel/Stainless NO / Flushmount ) Well Diameter: 02 , Construction: Steel) Total Well Depth; X S ft Static Water Level: 63 • D ft Height of Water Column: 27.06 ft Multi Factork:0. 16 1 [•(Radius/12)2 x 3.14 x 7.48] Casing Volume: 3 - 6a gallons Cal. 3 Volumes: 1G �q gallons Pump Intake: Fi s . ft Purge Information Date Purged: Qq / ,/ ff Start: A$ Finish: 7-0 S Purge Rate, f O mLm -lam 4] 61a0 Purging Method: :C "otal Volume Purged: 2105 (gallons/ s/L) Sampling Information Date Collected: 1-i 12, I .10A0 I' Time Collected: � 21 d (am/ m Sampling Equipment Used ;_�:CO. 9JaQ&f strumentlD:_Y517 _#03391%PW #9003 Bottle Type Preservation Analysis Required lI ✓O C_ Field Measurements/Observations �Z Sample Temp (°C): (5 - Z Time: �a Turbidity (ntu): T Time: t I G Diss Oxy (mg/L): (.0 Time: I Z 16 Fe 2+ mg/L: "r Time: Specific Cond. (uS): 1 ,J Time: 1 Z C Res. Cl (mg/L)/(µg/L): � Time:. Sample pH (s.u.): _q Time: 1 Odor: � , !? Mo Time: (Z ! D ReDox (mV): qo.CD Time: 1 Z1 O Appearance: _C Time; l Z 1 0 ReDox (EH value):YSI ProPlus +200mV 16o . d Other: '-r Time: General/Weather Observations:. 13 " (sunny cloudy my emp-& _(°F) Wind q b (mph) Sampler Signature: Stabilization Test Date: d C! " �5 'ZIC Spec. ,� Uiui„r Time Temp. Diss Oxy. ReDox Turbidity remove Water Cond, pH (s.u,) Other Purged ((,C) (mg/L) (us) (mV) (ntu) (gallons mis level (ft) I 6s -z�-.0 651 II53, 15,2 1 - I 13 6t - 6 t2oa 15.2 1.6 1360 6. 1 3 21c� S.a vZol 15.2, 1 6.9 135Z 6_ 9 1 -�10.2 11.b Z-V A4_l aceAn��l�•tfcal" r Document Name: Field data Sheet Document Number: F-CAR-FLD-001-rev.03 812019 Page: 1 r Issuing Authority: Pace F. Office Field Data Sheet Client:—bu n caro bjL Location: oeK} ; n Name and Affiliation (Sampler(s): 3QS - pa_CQ.- . Name and Affiliation (Inspector): A2 P1 Well Information Well ID; MW - Well Locked: Well Diameter: z rJ Construction: Total Well Depth; ft Static Water Level: it Height of Water Column: I 10 ft #:&nCo- old LF If 1 2�zc Data Sheet Review; Date; 5111 xo NO / Flushmount ) Stainless Steel) Multi Factor* 'Q, [•(Radius/ 12)2 x 3.14 x 7.48] Casing Volume:�7, R gations Cal. 3 Volumes: L _ M gallons Pump Intake: 75.6 0 ft By: CTG Purge Information ]Sate PurgedG'i start: 1010 Finish. 1030 Purge Rate: /LO n'IL /ems ""- Purging Method: Pr urn Total Volume Purged: 2 c1 Q (gallons/(gVL) Sampling Information Date Collected:O'l / K/ + Q Time Collected: 10 & (Opm) i Sampling Equipment Used: e, `C:,Jcl IQ .� Instrument ID: IV S_-r3 9 W 9oZ j Bottle Type Preservati6n Analysis Required AlYpr Field Measuretnents Observations Sample Temp (°C): Time: 103r-, Turbidity (ntu): /. Time 103.5 Diss Oxy (rng/L):__ _i . Time: 1035 Fe 2+ mg/L: % • D Time: /a 35 Specific Cond. (uS): 100o Time: 3L-35 Res. Cl (mg/L)/(µg/L): �Tune:. Sample pH (s.u.): i{} . Time: 1035 Odor;%O Time; 1035 ReDox (mV): I . Time: 10 3 5 Appearance: Cf ezt— Time: f o 35 ReDox (EH value):YSI Proplus +200mV I . Other: Time: General/Weather Observations: &I W-q , Sampler Signature: Time Temp. Diss Oxy. Purged (°C) (mg/L) too 10,,C i3.� 1 • i 0Z5 134 ►.1 1030 13. 1.,1, Spec. Cond. (us) 100 I too / /0o / 1 .� pH (s.u.) laud rainy) Temp.57 ("F) Wind 1 3 (mph) ite: (lzl - z S 60 volume ReDox Turbidity removed Water Other (mV) (ntn) (gallons mis level (ft) I 6 7. %! 0.G 0G 7_ IU f7aG 'T 1 r , I 0 Document Name: Field data Sheet Document Number: F-CAR-FLD-001-rev.02 pate Issued: November 27, 2018 Page: 1 of Issuing Authority: Pace Huntersville Quality Office I —I Field Data Sheet CL a lx A�6F Project #: a� t 19I_ 0 Name and Affiliation s Sam ler : r 01 P� pin { p {) Field Data Sheet Review: Name and Affiliation (Inspector): P. Well Information Well ID: N t✓ • #- it Well Diameter: Total Well Depth. ft Static Water Level: d �' �3 ft Height of Water Column: j a 8 ft Date: 51 l ( Z e y CTC�i Well Locked: / NO) Construction: PV / Steel/ Stainless Steel) Multi Factor*: 6 S [(Radius/ 12)2 x 3.14 x T48l Casing Volume: gallons Cal. 3 Volumes: gallons Pump Intake: I ft Purge Information Date Purged: 4 start: `�, Finish: ' Purge Rate: J� l�4• �! i Purog Method: We 11 tN, rt , Total Volume Purged: �` (gallons/mis) Sampling Information C Date Collected: /f!_/ ' Time Collected: t' aopm) W 1-2 Sampling Equipment Used: zJL i. t whtw 1 I w V > vz a Instrument ID: L J ':� � p� Bottle Type Preservation Analysis Required �As r I` 1 Al) Field Measurements Observations Sample Temp (°C): �� Time: C/ ( A Turbidity (ntu): �'/ G Time: Diss Oxy (mg/L): L9 Time: Fe 2+ mg/L: Time: Specific Cond, (uS): 3 3 Time: t r Iles. Cl (mg/L)/(µg/L): '1"sme: Sample pH (s.u.): 6 Time: �7j'Y Odor: Time: 9 / 1- ReDox (mV): Time: C1 rr Appearance: Ts ne: ReDox TH value):YSI ProPlus f200mVether: Time: General/Weather Observations: S ✓"hdu�g a ry (sunny/cloudy/rainy) Temp.SOTff) Wind mp Sampler Signature: Stabilization Test A`5 -A'a Time Purged Temp. (°C) Diss Ox . (mg/L) Spec. CUS) pH (s.u.) ReDox (mV) TurbidityVolume (ntu) remoallonsVemis Water level (ft) Other 6)00 0,3�— �.3 � �,�5 .��,y- �`, �a o? 1) 6i.2J' Document Name: Field data Sheet Date Issued: March �-\ 8, 2019 - 8C8 r' nali,lical - Page: 1 of c" Document Number: F•CAR-FLD-001-rev.03 Issuing Authority: Pace Huntersville Quality Office '1 C Name and Affiliation (Sampler(s):4� Name and Affiliation (Inspector): Well Information Well ID: C 61,w S Well Diameter:1 Total Well Depth: � V - MJ f Static Water Level: `" T _YS _ft Height of Water Purge Information Date Purged; f / :? Y ./ Purging Sampling Information Date Collected: -- cfl -- / Sampling Equipment Used: ' U cU c Bottle Type ok Field Measurements/Observations Sample Temp (°C): Diss Oxy (mg/L): Specific Cond. (uS):�- Sample pH (sm.): ii ` - ReDox (mV): -' ReDox (EH value):YSI ProPlus +20C General/Weather Observations; Sampler Signature: Stabilization Test Field Data Sheet ion: V. C- Ptoject #: �unumbg (�,. J)d L F 4� � ' �c,.� j Field Data Sheet Review: Date: 51020 By: C I& Well Locked: (Y( / NO / Flushmount) ' Construction: �JC1l/Steel/Stainless Steel) Multi Factor: Q i G (*(Radius/12)2x 3.14 x 7.48) A Casing Volume: 7 4 gallons Cal. 3 Volumes: _ gallons Pump Intake: ft start: Finish: F 0 c: �_ Purge Rate: IZO M I MI q _Total Volume Purged: ',ICO (gallons/L) Time Collected: 10. !! n, (ERY pm) ,D - -- -- Instrument ID: Y ! � Preservation Analysis Required k4 C I Q 1 r" Turbidity (ntu): Fe 2+ mg/L:_ ~ 1 Time: Time: — e: t_fi 4 ^ Res, Cl (mg/L)/(µg/L): ,`._ Time:. e: ! _ Odor: f*f'D Time: te: Appearance: C- alb' Time: 1 Lk Other: Time: Time Purged Temp. ( q Diss Ox (mg/L) peC' Cond.pH (s.u.) ReDox (MV) Turbidityremoved (ntu) Volume (gallons/� Water level (ft) Other Li qo 13 1•t 1.22 6,4 —1l, o•�a �.. I )ocunient Name: Document issued: March 8, 2019 'ield Data Sheet �-�— PageNf - Diccument F-CAR-FLD-001,rev.03 Number: issueing Authority; Pace Hwitersville Quality Office Client: Location Project: -Xk k) L n Well ID: CIP L/Ij - Reviewed Date and By: Stabilization Test C 1kre-11 Ni,-,Itiplication Factor 1.2 0.0918 0,10-0 0.1650 0.3,670 4 1.46 3.2 .6810 6 2 100 Time Temp. Diss Oxy. Spec. Cond. pH (s,u.) ReDox (mV) Turbidity � Volume Removed {gallons/ qsL) Water level other Purged (OCI (mg/L) (us) (ntu) circle one (ft) V�iCI aceArrafjfcal Document Dame: Field data Sheet Date Issued: Marco 8, 2014 Pam I of i= Document Number: F-CAR-FLD-t]01-rev.03 issuing Authority: Pace Huntersville Quality Office ,..f1 C Name and Affiliation (Sampler(s):: 77- - Name and Affiliation (Inspector): tj Well Information Well ID: N` ii ,y� F� Well Diameter: v1 Total Well Depth: L4 t . EaQ f Static Water Level: C .QC1 , -ft Height of Water Purge Information Date Purged: Cat /_ac / Purging Method: 12 c. Sampling Information Date Collected: f ``� / Sampling Equipment Used:. Bottle Type Field Measurements/Observations Sample Temp (°C): -7 Diss Oxy (rng/L): - r T Specific Cond. (6): 1 �>3 T Sample pH (s.u.): L T ReDox (mV): - L� _ I ReDox (EH value):YSI ProPlus +200r General/Weather Observations; Sampler Signature Stabilization Test Field Data Sheet r k /Lr€ project # T Field Data Sheet Review: Date: 51 11 ZG Well Locked: (,YE$ / NO / Flushmount ) Construction: PV5Steel/Stainless Steel) Multi Factor*: [•(Radius/12}2 x 3.14 x 7.481 Casing Volume: 1 ;' gallons Cal. 3 Volumes: ;-0 ; ? 1- gallons Pump Intake: 7'j , 2, C 1 - ft By: CTV Start: Finish: I Purge Rate: m G Total Volume'Purged: (gallons/ s�L) Time Collected: 73D-�\_ (am/ M Instrument ID; Preservatibn AnaIysis Required ime: Turbidity (ntu): r� Time: ) ? -- Line: 3 �r Fe 2+ mg/L: (1, C. Time:. � 3 �n ime: n Res. Cl (mg/L)/(lag/L): �Time:. " ime: - h. Odor: ";; <, �1'<< Time: f 1-2-0 ime: )? Appearance: C. "�� Time: Other: Time: Time Temp.Diss Ox y' Cond. pec' (s,u,) ReDox Turbidityremoved Volume Water Other Purged o (C) (mg/L) pH (mV) (ntu) (ga-lllons/@-il level (ft) (US) it 1 1- 4V ! i �} T I �^ IT—. 1 I, Name: Document Issued: March 8, 2019 ocument Data Sheet Pagof sField aGi�lsil��tfG�P j D F i cwnent Number: AR-FLD-OOl,rev.03 uein Authori : Iss g t3' Pace Huntersville Quality Office Document Name: Field data Sheet pate Issued March 8, 2014 Page 1 ;- aceAna134ical' of Document Number: F-CAR-FLD-001-rev.03 Issuing Authority: Pace Huntersville Quality. Office Name and Affiliation (Sampler(s):' Name and Affiliation (Inspector):_ Well Information Well ID: s -6 1j C' Well Diameter: 41 Total Well Depth: Static Water Level: '-1 ._ ]� ft Height of Water Col Purge Information Date Purged: C' 0—/ ./ Purging Sampling Information Date Collected: C- �-'-: ICJ -;jL Sampling Equipment Used:-- Tf rs5 Bottle Type ' r': t. Field Measurements/Observations Sample Temp (°C): Digs Oxy (mg/L):'•� T Specific Cond. (uS): Sample pH (s.u.):J 7 ReDox (mV): ReDox (EH value):YSI ProPlus +2001 General/Weather Observations: Sampler Signature: Stabilization Test Field Data Sheet Location: AS i cl,�e-� /A)L. Project L' c At1c it ski Field Data Sheet Review: .a [ Date: S (1 f By: CTS Well Locked; YhS / NO / Flushmount) ' Construction V 2/SteelJStainless Steel) Multi Factor*: 4 G, [*(Radius/12)2x 3.14 x 7.481 - 4 Casing Volume: A G gallons �n Cal. 3 Volumes: gallons Pump Intake:_ I Cf H I V 1 ft Start: m Finish: i' # Purge Rate: ± Total Volume Purged: �G (gaIlons/ 1rifl9/L) Time Collected: S 1 (am/(pac} Instrument ID:r S_ �1 �r r ;%^Ff - (? u I r rp .r .. ---r�x Preservation Analysis Required me: ) Turbidity (ntu): Time: - me: ! Fe 2+ mgX Time: me: �' Res. Cl me: Odor: "iTime: rC. ime: ' `. a:! Appearance: ',c t.. Time: 1 tV 157 1 `'t Other: -- Time: y Date: Time Temp.Diss Ox peC' • pH (s.u.) ReDox Turbidity Volume removed Water Other Purged (oC) (mg/L) (mV) (ntu) (gallons/ nr / level (ft) (u$) L Al ILI: i Li �?'� c-' � '- �j :� j '� i L_.1 ��. � l �� { 'f = n � �`R • � J ocument Name: Document Issued: March S, 2019 ield Data Sheet Pagaof _ ac��raal}�ri�a� - Document F Number: R-FLD-001.rev.03 lssueing Authority: Pace HnntersvilleQuality Office Document Name: Field data Sheet Date Issued: March 8, 2019 Page: 1 of J aceAm$41catx Issuing Authority: Pace Huntersville Quality. _ ❑ocument Number: F-CAR-FLD-001-rev.03 Office Field Data Sheet Ciienf: :Yl Location: AS 2,, 6z , A) L Project Cn. 01d L PAC(` 1 a9�4 Name and Affiliation (Sampler(s): Field Data Sheet Review: Name and Affiliation (Inspector): Date: `�; (1 12By: CTT Well Information Well ID: M my Well Locked:NO / Flushmount ) Well Diameter: Construction, 'Y /SteeI/Stainless Steel) Total Well Depth: ft Static Water Level: Y ft Height of Water Column: 11 ft Multi Factor*: Cl l�j'r(Radius/12)20.140-481 Casing Volume: Q . Lt 5 gallons. Cal. 3 Volumes: f . S gallons _r Pump Intake: ft Purge Information Date Purged:�)q �/� Start: l ?Jt"t� Finish: 16 OP. Purge Rate: c� �`L PurgingMethod: �G�f D,�—^Total Volume Purged: (gallons/ is L) Sampling Information Date Collected: () _/�/1t )1\ Time Collected: 1 L Q� (amA Sampling Equipment Used: 15�cd� �nrnl InstrumentID: `,1SL'Vrnj))Uj 1 3111 [Ln Cr-cafieLAJ#r,�Q t'` Bottle Type Preservation Analysis Required ��-i0rn[� V4gj5 Field Measurements/Observations HC NCB AR a 37 (VIP la ADn � Vn C Sample Temp (°C): 1 S ' Time: Turbidity (ntu): Time: Digs Oxy (mg/L). n , Time: I c� SJ_ Fe 2+ mg/L: Time: Specific Cond. (vS): '�,c)Time: 1 (� a\' Res. Cl (mg/L)/(µg/L): Tune:. Sample pH (s.u.): S Time: j 6 Q Odor: ( Q kt((� Cr Timer ReDox (mV): r,) `i M Time: 1�g!S� Appearance; (Jeyy Time: .G a ReDox (EH value):YSI ProPlus +200mV S,1 Other: Time: laQ a4=qJ-"" AOQFn US&J :C' doo_ _(sunny/ Sampler Signature Stabilization Test /rainy) Temp`,$ (OF) Wind 101 (mph) Time Purged Temp. (°C) Diss Oxy, (mg/L) Spec' (US) pH (s.u.) ReDox (mV) Turbidity (ntu) 'Volume removed (gallons/ON L Water level (ft) Other S W ,W �M B r ;1 -U0 1 )3.6 j 1- -I ca d a C 7 c-n l \ i ---- --` Document Issued: March 8, 2019 Document ]Name: Field Data Slieet Page )ofa- -aceA_r��lylrcal - If, Document Number: F-CAR-FLD-001.rev.03 lssueing Authority: Pace Huntersville Quality Office Client: Buo(C)C46R CO, Location: Project: Old L 17 Aof-d WellID: MLA) q Reviewed Date and By: S J I c' CTi3 Stabilization Test MU. -multiplication Factor,, 1..625 a.las.0 2 0.1.3 D 4 a-s4530 1.4680 Time• •Spec Cond. . r. ••Water + level• Purged (US) circle one za . . • � ® ®rem 11r1'��I�J■■lria��lrrlg � �ar�..�■..ate. .��....,�..._ �� Document Name; Field data Sheet Date Issued: November 27, 2018 Page: 1 of 2 Issuing Authority: Pace Huntersvitle Quality Document Number: F-CAR-FLD-001-revA2 Office L/ Name and Affiliation (Sampler(s): 2 c✓ Name and Affiliation (Inspector): Well Information Well ID; M f✓ /� A '� Well Diameter: ) Total Well Depth: Static Water Level: —?. b / ft Height of Water Column: 0 •3A ft yield Data Sheet Q dr✓tycn (c,—.,) Le- Projecf #: ✓�'c {� �` ��� pg Field Data Sheet Review: 5111Z0 CT13 Date: c - , i By: /--? el Well Locked: E / NO) Construction: VC Steel/Stainless Steel) MultiFactor*; 10 j r(Radius/12)2 % 3.14 X 7.4sq Casing Volume: gallons Cal. 3 Volumes: gallons Pump Intake: b'D ft Purge Information Date Purged: `F /d2 / J Start: Ih-.e0 Finish: (L1:ko Purge Rate: Z.S Yates 1M��. Purging Method: L,.1 Total Volume Purged: ,�5 (gallons/&) Sampling Information If Date Collected: _'�• ____/?,V / ao Time Collected: I'^ k� (am/wa) tOr-0 y Sampling Equipment Used: �� 2� s fu Lf� c Instrument ID: V i 3 `t ►�` Bottle Type Preservation Analysis Required Lt5 _ ?Sv Me_�q_ (i Field Measurements/Observations Sample Temp (°C): 1 `1 Time: Turbidity (ntu): (- 7 5 Time: y h0 Diss Oxy (mg/L): Z . 15 Time: Fe 2+ Specific Cond. (us): Time: Res. Ci (mg/L)/(µg/L): Time: Sample pH (s.u.): Time: Odor: nO-c Tune: `Y 1, tio_ ReDox (mV): Time: Appearance: cge— u's cvs Time: ReDox (EH vaiue):XSI ProPlus +200m Other: Time: General/Weather Observations: u rAri (6 {cloudy/rainy) Temp. lZ (°F) Windd ` (mph) Sampler Signature: Date: l Z � (12. Stabilization Test Time Purged Temp. {°C) Diss Oxy. (mg/L) Spec. Cond. (US) pH (s.u,) ReDox (mV) Turbidity (n) Volume removed (gallo) Water level (ft) Other 4;10 1$-x .'�A 5GI.9 to.y •Z,0(0 `x D. 15 18.�3 x.z� SraK.► G.y W2-.% � ts:Q 3C�v �.(uo It,\:IS t'1.$ r► 'Sio'1.5 (�.w i$q.v 4.�-1 250 wa• g jLk1 ;n Z Zn 5(ak.o h i�$. � U. CA 225 j0.65 (0 v L r) L- (' L(-/).0 1--1D � �� Document Name: Field Data Sheet Document Issued: November 27, 2018 Pagekf 2- Document Number: lssueing Authority: F-CAR-FLU-001.rev.02 Pace HuntersvOe Quality Office Client: a L G Location: V� u rle-o m6e- [-, Q 16 L J Project: Well ID: M W - NZ, Z S Reviewed Date and By:-V/dp/d ii Stabilization Test 'A'Ell TDiarneUr M-I-lti-nl ation F atitim:' 1 0. tf?1-?��08 12 13 1.625 t}.1050 0.1630 3 0.3670 t 0.6-5-30 1.4� 6S0 S Z.61f3i7 Time Purged Temp, {°C} Diss Oxy. {mg/L} Spec. Cond. (u5) pH {s,v.} ReDox (nnV) Turbidity (ntuJ Volume Removed gallons/4 tirde one Water level {ft} Other 1y.35 z.Z-0 5(.5 r.,, I -)I -S 1i 5 i 2-25 }f5 CA 'ILA iA(, $.`= '7Z V5 (0 LA livcl�'7 i_-75 Z25 lj.2S ��,4rta�ytic�l, Document Name: Field data Sheet Document Number: F-CAR-FLD-001-rev.02 Date Issued: November 27, 2018 Page: 1 of 2 Issuing Authority: Pace Huntersville C Office � L ` Field Data Sheet c L el - _ (gqiufCvi �3! Ot ") Pr Name and Affiliation {Sampler(s) Name and Affiliation (Inspector): Well Information Well ID; —A lt/ /S J Well Diameter: fr Total Well Depth: 3 )~ ft Static Water Level: S - Z 1 ft Height of Water Column: ZA � -7`1 ft Well Locked: Field Data Sheet Review: srirao C-M Date: °� °� By: NO) Construction: 6P c� teel/Stainless Steel) Multi Factor*: 1 G J l°(Radius/12)2 z 3.14 x 7.181 Casing Volume: gallons Cal. 3 Volumes: `o gallons Pump Intake: 3 D ft Purge Information Date Purged: / OL 2 / Start: 1 S ' 3 S Finish; 1 Co : 35 purge Rate: Purging Method: 2 , j �44 , , t Total Volume Purged: 3__i .0 v (gallons/e- Sampling Information i Date Collected: Gl / 2-9 2-P Time Collected: i 35 (am/1M, y t i 1- Sampling Equipment Used: A- -L Instrument ID:_ Dy f � 3 (4 l� • Bottle Type Preservation Analysis Required \6L5kC, �A �s°3 ►me, ► 1) iris c.il� 1AC, VoC_ k {Jlok"une- w Field Measurements Observations Sample Temp (°C): 1 G , S Time: I IO 3 S 'Turbidity (ntu): I -t o Time: 1 �� Diss Oxy (mg/L): 35 Time: Fe 2+ mg/L: f Time: Specific Cond. (uS): Time: Res- Cl (mg/L)/(µg/L): �Time: �f Sample pH (s.u.): S Time: Odor: doe `Fiore: ReDox (mV): Z2 5 . Time-. Appearance: G4-k LA 5 Time. ReDox (EH value):YSI ProPius +200mV to 2 S _'S Other: Time: General/Weather Observations: ( y/cloudy/rainy) Temp (°F m mp { Sampler Signature: i2W r� a r � Date: ti 1 z1 Stabilization Test Time Purged Temp. (°C) Diss Oxy. (mg/L) Spec. Cored, (US) (uS) u. p {s• ) ReDox (mV) Turbidity (n�) Volume removed (eons/- Water level (Ft) Other 3(.t.L �.v Z�s,3 1.-�o Soo �.lv Li�:oo � 3ipl.Z ';.,•� }(,,� 3-Z13 'iSH. Cq.o 35�.(� Z.i1� ZZs -t.os _ /�;10cer'�147l}/ifCc3 Document Name: Field Data Sheet Document issued: November 27, 2018 Page%of J^ Document Number: lssming Authority: F-CAR-FLD-001.rev.02 Pace Huntersville Quality Office Client: bL G Location: Cc,- Dk6 L.- Project: Well ID: Reviewed Date and By: Il���r'�� pe Stabilization Test \`ell Diax71_tsr :N lioltirli, ation Factor' 1 0.0409 1.2 0.0913 1.625 0.1090 01630 :3 0.36 70 0.6 531D 6 1.-650 3 2.6100 Time Purged Temp. o (C) Diss Oxy. (mg/L} Spec. Cond. (US) PH (s.u.) ReDox (mV) Turbidity (ntu} Volume Removed (gallons/� circle one Water level [ft) Other i(,•b 2 35'z I.5S zS0 `7.Z3 Z'3 S :-1 1. 5� Z Sa `).3`9 I(Q ZD [o,� 1•S`1 3s7-S S.-7 2+ t.S l.-Z 2s0 —7.s� 2,S0 i �S I(9-3G .3(r 375.3 103 zso �(o 15 119.5 3S 3fSK S.'7 ZaS$ Date Issued: November 27, 2018 Document Name: Field data Sheet Page: 1 of 2 4t� €F yltr�2! Authority: Pace Huntersville Quality Document Number: F-CAR-FLD-001-rev.02 lssu ng A tY Office Field Data Sheet Client: F Location:_ CooJay) Project#: Name and Affiliation (Sampler(s). M e l /,7 1 r Field Data Sheet Review: Nance and Affiliation (Inspector): Date: 20 BY: C"iY� Well Information Well ID: Well Locked: E / NO) Well Diameter: ? Construction: ( teel/StainlessSteel) Total Well Depth: ft Multi Factor*: r(Radius/12)2 x 3.14 x 7.48] Static Water Level: Casing Volume: gallons Height of Water Column: 1)�, tj ft Cal. 3 Volumes. gallons i Pump intake: �7 " ft - Pur e Information Date Purged: / �-2 / ' r Start : I LH J Finish: _La~ "' OPurge Rate: 011/'`J- Purging Method: Peat /�+ %% , L —Total Volume Purged: �` (gallo /mis) Sampling Information Date Collected:/ :'/ Time Collected: `� (am/pm) Sampling Equipment Used: Le- 2 � j _Instrument ID: a ��� ° Bottle Type Preservation Analysis Required - M LJR- i & 1 -3 �s Field Measurements/Observations Sample Temp (°C): W, Time: 1 a / Turbidity (ntu): �' Z Time: Diss Oxy (mg/L): D , Time: 1 J Fe 2+ mg/L: `, Time: (f o Specific Cond. (uS): / Time: Cl Sample pH (s.u_): r% Time: 1 J d J Odor: Time: ReDox mV : i J Appearance: -LTime: ReDox (EH value):Y5I PTOPIUS +200mV Other: General/Weather Observations: Gu mot. 42 `/ C� y/rainy) Temp. (°F) Sampler Signature.I Stabilization Test Time Purged Temp.Diss o (C) Ox y' (mg/L) Spec. Cond. (US) pH {s.u.) ReDox {mV) TurbidityIol (ntu) removeVolumWater removed (gallons �l level (ft) Other �.va,2 � I.� 5, 3 0, 7 37 Z, 7 ., , 4� 17 3 o d �, a o 'f �� o, 0 ) ?, I r -" ; ' .� / l �- � 3. r Document Name: Field Data Sheet Document Issued: November 27, 2018 Page�of Document Number: Issueing Authority: F-CAR-FLD-00l.rev.02 Pace Huntersville Quality Office Client G r� Location: 'a UAL (5)4L_ (L 0J, J L,-- Project: Al W S r4l Well ID: A, %, 13 - 13.2 Reviewed Date and By: 511 (ZG C 6 Stabilization Test IV -ell Diametem: 'Multiphcati'071 Facb-ar, 1 0.0405 1.2 D.15 1.62,. 1 i1.16M 3 0.36;r0 4 0.6.530 6 1.4680 2 .,G Time Purged Temp. (°Cj Diss Oxy. (mg/Lj Spec. Cond. (US) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume Removed (gallons mis circle one Water level Other O OXI 3Z�,c7 7 — 1 1`%- / J,�s 5 000 2 3.5,i {soy rZ.'7 r1• -` � 3'7 g 0,3Z 3-2/,� 7,,v -IJ z ,`3 c o, OD 1s`3 f4 �1 aceAfolj flcal4 f Document Name: Field data Sheet Date Issued: March 8, 2019 Pa e: 1 of !:— Document Number: F-CAR-FLD-001-rev.03 Issuing Authority; Pace Hnntersville Quality Office • .w I � i I e / RSi Name and Affiliation (Sampler(s):_ 3 D Field Data Sheet Review: Name and Affiliation (Inspector): NO Well Information Date: S ( 1 / ZD Well ID: rn W - 1 S Well Locked: YES NO / Flushmount ) Well Diameter: ., Construction; V /Steel/Stainless Steel) Total Well Depth; 7 s- T 0 ft Multi Factor*: [*(R,,Iius/ 12)2 x 3.14 x 7.491 Static Water Level: I • 5 - ft Casing Volume: Il. 56 gallons Height of Water Column: 26. 9r ft Cal. 3 Volumes: • 6 9 gallons Pump Intake:`' . D D ft By: C'C1g Purge Information Date Purged-- Pq 26X Start: 1 Z S 5 Finish: 1 L155 Purge Rate: 40m L /-n : *` Purging Method:_g s+oLiK,G Total Volume Purged: ZD . S (gallons/ml� Sampling Information Date Collected: / / 'Oao ' e C llected: I �C3C� {aml Sampling Equipment Used: Pam►` ` I r~C V Instrument ID:41-9023 Bottle Type PreservatiOn. Analysis Required fl1 CVIU le Field Measurements/Observations Sample Temp (°C): . r �- Time. (S OQ Turbidityntu 1 SOG (: �Time: ) Dins Oxy (mg/L):_ 30 Time: / Sow Fe 2+ mg/L: Time: Specific Cond. (uS): 6�� Time: ► 5o C Res. Cl (mg/L)/(µg/L): Time:. Sample pH (s.u.): I Z . ' f Time: 1 SD a . Odor: /U Time: r Som ReDox (mV): - .Z Time: 15001 Appearance: CrPJ Time: f 500 ReDox (EH value):YSI ProPlus +200m.V a21, 7 Other: Time: General/Weather Observations: MW - i5&,meLtd w; k od a, rk.( z 11a)( Sampler Signature Stabilization Test u /cloudy/rainy) Temp.-_z (°F) Wind (mph) �'' - r -� _Date: fazn Time Temp. Diss Oxy. Spec. • pH (s.u.) ReDox Turbidity volume removed Water Other Purged (°C) (mg/L) fond (m-V) (ntu) (gallons mis/ level (ft) r 7W ill /. Ci 26 1 .6 -7L 6- ySc. � fo 13/o 1q, I <,6 SZ q (?.& - 2_ 3 sf.g0 ,cam / . ( f . 926 f j.,6 z. ct 137-o 19,D 6.°+ w9 % 12.6 -6,9,0 2-3 s lr.RS 1330 1. 0 :7$33 l2. b I - (-13_ KZ. 3 1 1h 10 Document Name: Document Issued: March 8, 2019 Y cekialytica - _ I Field Data Sheet Page Tef �j Document Number: F-CAR-FLD-001.rev.03 Issueing Authority: race Huntersville Quality Office Client: 8U n eem.•b Location: wo ; Project: Bun Cab , Co_ wel L F A,oe-; ] Zo zo Well ID: M,\^l Reviewed Date and By: s(1/2-I, C-M Stabilization Test I WeU Dianiatar 'IN.Sultiplicati-mi Facbai:- 1 0.1340 3 1.2 0.003u 1.623 0-1.03:0 I 0 -1,55 0 o.36r0 el 0,6530 i :6. 1.G50 3 2.6100 Time Purged Temp. (DC) Diss Oxy, (mg/L) Spec. Cond. (us) pH (s,u.J Rebox (mVJ Turbidity (ntu) Volume RemovedWater (gallons/ml circle one level (ft) Other M .1 9 12. to 36 • cf LA 17-.W1 61 -3201 U7, ( Oo r6 r R$ U I.2. 6 Z , 6 1 Zl' off I�fZG (5 h (J �IQ� 1`Z•h �Zi; -� �- + Z6 `6G �IQ�.,<,o.� r I �. 3.► 1Z 7S 5 + 14�.KZ iqqo 16.� 3: Z 063 1:2 N - 3 01 Jo !' 12f ( O � `7a 2. 5 261 21. 95 Nip k(.4R. c� 31 6959 i .zq - at-- Date issued: November 27, 2018 Document Name: Field data Sheet Pa e: 1 of! issuing Authority: Pace Huntersville Quality Document Number: F-CAR-FLD-001-rev.02 Office In� Field Data Sheet Client:_ F� �— Location: &,,,e �S 5 0 _a G/C Project #: �"�` �� t.� .i v t J c cvs Name and Affiliation (Sampler(s): tic I _61) 't— Name and Affiliation (Inspector): Well Information Well ID: �✓' 7' Well Locked: Well Diameter: Construction: Field Data Sheet Review: Date: S) 112-0 By: Ci13 / NO) /Steel/Stainless Steel) Total Well Depth: ft Multi Factor*: 1*(Radius/12)2 x 3.14 x 7.48] Static Water Level: % ti' ft Casing Volume: gallons Height of Water Column: 7, 6S' ft Cal. 3 Volumes: gallons Pump Intake: S' ft Purge Information Date Purged: / % / Start: ID A J Finish: �� — Purge Rate: too•^ — Purging Method: Yl— f f Total Volume Purged: 3- 0)o (gallo mis Sampling Information _ �0-9J' Date Collected: k / �`� /k o Time Collected: �� S (am/ y S Sampling Equipment Used: G✓z f I W, ��-��� Instrument ID: 149 k N4 Bottle Type Preservation p (_', -r, lr l-f/✓j3 !/, AL k ]✓cam Analysis Required Field Measurement Observations Sample Temp (°C): I I Time: I Turbidity (ntu): �' 1. Time: Diss Oxy (mg/L): �� Time: r0> >r Fe 2+ mg/L: Time: Specific Cond. (u5). a Time: l�'� Res. Cl (mg/L)/(µg/L): Time: Sample pH (s.u.): Time: f S Odor: 0° "' 'L Time: ReDox (mV): �2 Time: df� Appearance: C44,9, Time: ReDox (EH value):YSI ProPlus+200mV O Time: General/Weather Observations; (sunny/cloudy/rainy) Temp. ff) Wind0- f (mph) Sampler Signature: A__ Date: ` ry Qfn1% ll7ai-inn TE+ct Time Purged Temp. CC) Diss Oxy, (mg/L) Spec. (S; pH (s.u.) ReDox (mV) Turbidity (ntu) Volume (gremoved (gallons/ llon / jo) Water level (ft) Other l060 l�F•'f- o,rT 1r5.7 { 76 -7�,� li,�� (000 a,s7 (--0 L,r1� " 21,V 9, a? A o jl UrGJ (, �f _�l.qi �p,� J1 '00 (�..1� %ro Zj 4/, 1 QiI� 70J9 /�q� )4N Date Issued: November 27, 2018 Document Name: Field data Sheet Page: 1 of t s aceArraF rra�l Issuing Authority: Pace Huntersville (duality Document Number: F-CAR-FLD-001-rev.62 Office Field Data Sheet (c)jFfl) CIient: A L % Location: AV,,r L r7L f- Project #: ✓�' c �� " Name and Affiliation (Sampler (s) :P2 e41 Field Data Sheet Review: Name and Affiliation (Inspector): Date: S 1 t Z u ... By: CTS Well Information Well ID: M �' ' 2 " ! 7 Well Locked: (�Eg / NO) �r WeII Diameter: � Total Well Depth: 7 ft Static Water Level: �` j� d ft Height of Water Column: i ft Construction: Steel) Multi Factor*: , J �[`(Radius/12)2 x3.14 x 7.491 Casing Volume: gallons Cal. 3 Volumes: gallons Pump Intake: ft Purge Information Date Purged: L-�/ hS / Start : f J l� Finish: 11 ` -0 Purge Rate: (L 0 A _ J Purging Method: W-11 tw i -2- a ,Ya a Total Volume Purged: J J (gallons/ s� SamRling Information Date Collected: 1"'E / `7/ a Time Collected: r � `� ii rpm) y 1 µ f F }.�}4 Sampling Equipment Used: �! y InstrumentTT)1. Bottle Type Preservation (Lra,�rc yVd Analysis Required A,- 4 /1 VOL t. r� ,x Field Measurements/Observations Sample Temp (IC): - U Time: �1 `P� Turbidity (ntu): r', 5 Time: '/ Stet) Diss Oxy (mg/L): t' 77 Time: r l'f' Fe 2+ mg/L: Specific Cond. (uS): a L' ' Time: Res. CI (mg/L)&g/L): 71me. Sample pH (s.u.): 71 3 Time Odor: Time. ReDox (mV): ' y `� Time: �! t' Appearance: A2 Time: r/ giro ReDox (EH value):YSI ProPlus +200mV—`� Other: e: ` enera eather Abservationsr d �1�r2 y !,I ra2,5 d1a S (sunny%cloudy/ rainy) Temp. ?�(°F) Windy 3D (mph) Sampler Signature: 03,2 Date: CFyL,ili-»Finn `t'ocF Time Pur Purged g Temp. ( °C ) Diss Oxy. m /L { $ ) Spec. Cond. (US) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume rem°ved (gallons/mis) Water level (ft) Other 1L,13 ),Soo �Itfgerr ��-9elt �p{t��e�£1 5 �npl� pate Issued: November 27, 2018 Document Name: Field data Sheet • i'a e: 1 of 1 Issuing Authority: Pace Huntersville Quality Document Nunmbev F-CAR-FLD-001-rev.02 Office t_ Fietd Data Sheet�«�,��� Name and Affiliation (Sampler(s): M� ` 1 (401 Name and Affiliation (inspector): Well Information Well ID: M ly I Io Well Diameter: } +� Total Well Depth. ft Static Water LeveI:. a , C ft Height of Water Column: � 1 U ft Data Sheet Review: Sri 4"J, i Q Date: 5 F 1 ( 2C) By: .C7V3 Well Locked: QYf / NO) Construction: (61--teel/Stainless Steel) Multi Factor*: (' r(Radius/12)20.14 x 7.48] Casing Volume: � gallons Cal. 3 Volumes. gallons Pump Intake: 3 O ?` ft Purge Information Date Purged: ' / X01 /.b Start: / / it Finish: Purge Rate: top Purging Method: to Lis 4 Total Volume Purged: 'f-ovo (gallons/is Sampling Information Date Collecte& LfLf /?/ Time Collected: r ;"— (am/ m�1 Sampling Equipment Used: G "j ] f + Instrument ID Bottle Type Preservation V16 t, N z L- !oi 6T �• Analysis Required MBA /i vac 1,ff- �'"X9w( Field Measurements/Observations ____ Sample Temp (°C): 17, 0 Time: 1 �" Turbidity (ntu): d j / Time: Diss Oxy (mg/L)- 1'' Time: I> s Fe 2+ mg/L: - Time: - - Specific Cond. (uS): Time: 1 t ' '� Res. Cl (mg/L)&g/L): Time: Sample pH (s.u.)- Time: t ' '� Odor: Time: I ReDox (mV): —TO.`�- Time: 4 '� Appearance: Time: ReDox (EH value):YSI ProPlus *200 Other: =-ime: GeneraVWeather Observations: i 0-1-5, W92:'� Jn y w � dd � (sunny/cloudy/rainy) Temp. J CF) Wind (mph) Sampler Signature: -Date: Stabilization Test Time Purged Temp. (°C) Diss Oxy. (mg/L) Spec. Cond. (us) pH (s,u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/mis) Water level (ft) Other �e 1v).V -).6 a,s L7 kaa2 Mn—, /.40 14-),'t d,�5 --v, 6 + 30Jl �fi 00 lk� IE,2 �,4' Document Name: Field data Sheet Date Issued: March 8, 2014Pa aC9rtlk?flCr71 e: l of � Document Number: F-CAR-FLD-001-rev.03 Issuing Authority: Pace Huntersville Quality �.. Office Field Data Sheet Client: DOOCrJ1'rlhP_ Lc, Location; rzwd� Name and Affiliation (Sampler(s):_W% - Ya-Ce. Name and Affiliation (Inspector): NA - Well Information Well ID: /4W_ 1 rg,' 7L Well Diameter: Total Well Depth: 26. (00 ft Static Water Level: 6, 5 1 ft Height of Water Column:!D , () ft Project #: 1306/07. hP CO Cad I- �� �zoo, Field Data Sheet Review: Date: +-1-- 51 L I Zo By: CTg Well Locked: t{aW/ NO / Flushrnount ) Construction: izsteel/Stainless Steel) Multi Factor*:� r(Radius/12)2 x 3.14 x 7.48) Casing Volume: gallons Cal, 3 Volumes: 5e4 - Z -�- gallons Pump Intake: Y - G� ft Purge Information Date Purged:_. Y /-Q 9' /r o3 Start: _!Cj' Finish. /6a5 Purge Rate: Purging Method:�e-t. Y-4 I 4rt 6.2 Total Volume Purged: Z (gallons/�L) V-- Sampling Information Date Collected:/ / �a Time Collected:1630 (am Sampling Equipment Used: 9J1�► Instrument ID: 3q %TPt�.I0?3 Bottle Type Preservation Analysis Required 1Kill A Field Measurements/Observations Sample Temp (°C): Time: 1630 Turbidity (ntu): Time: /6 3 0 Diss Oxy (mg/L): , d Time: /6 30 Fe 2+ mg/L: s Time: 6 36 Specific Cond. (16): ---Time: 1630 Res. Cl (mg/L)/(µg/L): =Time:. Sample pH (s.u.): Time: 16 50. Odor: ta,+9.1( II OE► Time: 16 30 ReDox (mV): - �(� - �1 Time: M 30Appearance: Ckcl-_ Time:_ 16 SO ReDox (EH value):YSI Pro Plus +200mV 113. Clkher: Time: General/Weather Observations: M W cloudy/rainy) Temp. 76_—(°F) Windy -r (mph) Sampler Signature Stabilization Test Time Temp. Diss Oxy. Spec. pH (s.u.) ReDox Turbidity Volume removed Water Other Purged (°C) (mg/L) (US) (mv) (ntu) (gallorts mis level (ft) o ft3 . 2 q5s 6- 5 0 6.5 5- (61 6, y - �. � I N00 N ! . 7 6 . q --9i2 4. .6.57 .� rb 1 q r ( q?3 1 6- -8 .2 7-0 2foo ti.5i 11 aceAnalytical � Document Name: Field data Sheet Date issued: March 8, 2014 Page: 1 of I Document Number F-CAR-FLD-001-rev Issuing Authority: Pace Huntersville Quality Office Name and Affiliation (Sampler(s):- Name and Affiliation (inspector):_ Well Information Well ID: L- } I/,j - 111 _2S- Well Diameter. _ a,, Total Well Depth'. Static Water Level: ('—t - 3 i ft Height of Water Purge Information Date Purged:_Q9 / 8 / Purging Samv ling Information Field Data Sheet acation: � ShE �r i L� Project #:a, fk3.(.c. A n& { -ra,, { Field Data Sheet Review: 114- Date: S f 1 f 2a By: CTi3 Well Locked: NO / Flushmaunt) ' Construction: (� /Steel/Stainless Steel) Multi Factor*: ["(Radius/12)2 x 3.14 x T48] Casing Volume: f ( gallons Cal. 3 Volumes: _`� }: bQ gallons Pump Intake: �A , 0) �i ft I,60S Finish: t b )r Purge ! ) Total Volume Purged: S�OQ 1 (gallons/mis/L) Date Collected: g 1, //�c�`?!1 Time Collected: Sampling Equipment Used: L.v, Instrument ID: > , p i ?zl l n ; �c c ('�ti •� ` } Bottle Type Preservatidn Analysis Required M /V A I Field Measurements Observations 44 9 Sample Temp (°C): 'lime: (630. Turbidity (ntu): Time: 1 ( Diss Oxy (mg/L): T�me: ' ' Fe 2+ mg/L: 5 Time: Specific Cond. (uS): y �� , ime: Res. Cl (mg/L)/(ug/L): Time:. Sample pH (s.u.): J e: I C ? Q Odor: i�If% Time: ReDox (mV): _- 2 _ Time: (, ?Q Appearance: _ _� le,,(-- Time: ReDox (EH value):YSI Pro Plus +200z W f Sj Other: Time: General/Weather Observations: Sampler Signature: Stabilization Test /rainy) te:�u Time Purged Temp. (°C) Diss Oxy. (mg/L) peC' uSd• PH (s.u,) ReDox (mV) Turbidity (ntu) Volume removed (gallons mr/ Water level (ft) Other _LKIA ts. rl -3S y Document Name: Field data Sheet Date Issued: March 8, 2019 --Pave. 1 of J acerUk?f}�fiCal Issuing Authority: Pace Huntersville Quality _: f Document Number: F-CAR-Fi p-001 rev.03 Office Name and Affiliation (Sampler(s):_ Name and Affiliation (Inspector):_ Well Information Well ID: n'i AI -19 - j i 0 Well Diameter: Total Well Depth: i 13 f Static Water Level: ar ft Height of Water Column: I ILI 2_3 1 Purge Information Date Purged: C"--1 Purging Method: Sampling Information Date Collected: CL_\�/ D 1 Q Sampling Equipment Bottle Type Field Measurements/Observations Sample Temp (°C): 1 Digs Oxy (mg/L): Specific Cond. (uS): 3'9 ,5 Sample pH (s.u.): S L ReDox (mV): S); ReDox (EH value):YSI ProPlus +20C General/Weather Observations - Sampler Signature Stabilization Test Field Data Sheet ion: Project #: +1 1CC L Y A ckCQ A cw a ` cio� ( Field Data Sheet Review: Date: SI112-0 By: Well Locked: Y / NO / Flushmount ) Construction: OVPSteel/Stainless Steel) Multi Factor*: C ' r(Radius/ 12)2 x 3.14 x 7.48] Casing Volume: -T-S gallons Cal. 3 Volumes: SQ J,2 gallons Pump Intake: 4 4 1, go ft Start: ( f Finish: �" 1 Purge Rate: ) () r'�' L/ IVII r1 Total Volume Purged: (gallons(m s L) Time Collected: — {am/ m) '�InstrumentID:, ��j Preservati6n Analysis Required 15 i,' , D cr <.VC C Nn N A ne: ?— G Turbidity (ntu): Time: � 0 ne: t �3 C Fe 2+ mg/L: .O Time: ne:)i __� -2, Res, Cl (mg/I.)/(µg/L): Time:. ne: _I� Vic. Odor: `J D Time: me: Appearance: 0 Time: V �j , Other: Time: cloudy/ Date: Time Purged Temp. (°C) Diss Oxy. (mg/L) peC' (5) • pH (s,u.) ReDox (mV) Turbidity (ntu) oume removed (gallons m1s Water level (ft) Other '�T Document Name: Field data Sheet Date Issued: March 8, 2019 dcenalS�kal ` Page: 1 of _ Document Number: F-CAR-FLp-001-rev Issuing Authority: Pace Huntersville Quality �: Office Field Data Sheet Client: F4Cn M �a L Location: A1,W vv ] ,RUC- Project #: m)g Cc, 0 Id LP AQe-p) )QV Name and Affiliation (Sampler(s):_ 1SI--}'a0 A c)afrsYl Field Data Sheet Review: Name and Affiliation (Inspector): r j Date: 5 f I (2 U By: C 13 Well Information Well ID: M W - - l Well Locked: YE / NO / Flushmount) ' Well Diameter: a h ll Construction; V' C /Steel/Stainless Steel) Total Well Depth: 0-3 l ft Multi Factor*; Q• I bpi' [*(Radius/12)2 x 3.14 x 7.48] Static Water Level: it Casing Volume: J 9 gallons Height of Water Column:_ 1 � ft Cal. 3 Volumes: v gallons Pump Intake: r_ 1. 00 _ ft Puree Information Date Purged: 04 / dL\ / ; 00 Start: � �i� � Finish:_ Purge Rate: S(LM Purging Method: �e o, lVt-c. PuN _ Total Volume Purged: 7 (gallons/�i Sampling Information Date Collected: _/,/-- —o Tune Collected: I Q �i c Wpm) Sampling Equipment Used: Pe-(TSf- (H ( Dim_ Instrurnent ID: _ <,1✓ � c4gGt.c.S 1t--34-3-1_�MY Cr `30-7`l Bottle Type Preservation Analysis Required Z M, ka f � , VCC rnNg Field Measurements/Observations Sample Temp (°C): 4 Time; Turbidity (ntu): Q , a Time: 104L^ Diss Oxy (mg/L):- -- Time: j 0 �1 !� Fe 2+ mg/L: �S Time: If Specific Cond. (uS): Time: C1 Res. Cl (mg/L)/(µg/L): Time:. Sample pH (s.u.): b Time: O k Odor: AA Time: f O `-t f ReDox (mV): 4 • Time: 1 a '-1.0 Appearance;-_C_I-ectr Time: ] ok� ReDox (EH value):YSI ProPlus +200mV I `A cl '�- Other: Time. Temp. � (°F) Wind (mph) Sampler Signature Stabilization Test Time Purged Temp.Diss (°C) Ox (mg/L) Spec. Co5) pH {s.u.) ReDox (mV) Turbidityremoved (ntu) o ume (gallons/� Water level (ft) Other l 1b 3 110 I3 ] W i 6.3 f , a 13 i5 6 Ll -- yg 3 aj,- - --� 10 30, —=-p '1.3 aceAnafj�freal y Document Name: Field data Sheet Date Issued: March 8, 2019Pa e: 1 of Document Number: F•CAR-CAR-ODl-rev.03 Issuing Authority: Pace Hunlersville Quality s Office Field Data Sheet Client: Eun a)mn x_ Cc) Location: A5,kat fL; A_L. Project #: QMCo. Q Id Name and Affiliation (Sampler(s): M - eta .l i Name and Affiliation (Inspector): (Q Well Information WellID:. LJ / Well Diameter: Total WeE Depth: t'1I ft Static Water Level: '.,'I ft Height of Water Columng it ft Well Locked: Construction: Data Sheet Review: Date: 5 ( It 7U By: C AI3 NO / Flushmount ) Steel/Stainless Steel) Multi Factor*: 0, j U r(Radius/12)2 x 3.14 x 7.481 Casing Volume: '� Q"i gallons Cal. 3 Volumes: nn��.a.-3 gallons Pump intake:_- —ft Purge Information Date Purged; OH / _/ 42�0 Start: n vZCFinish: Purge Rate: MTML�m Purging Method:, rS}tr Lb Volume Purged: SQ (gallons/ t�s L) Sampling Information Date Collected:. Q� / Lv 2 n�Cl Time Collected:-Q_`i S-0 (a pm) Sampling Equipment Used: P e O ` >hl "L Instrument ID: Bottle Type Preservation Analysis Required ,a o ox-rnIWs, 1,4 0,0x6qy,VO 0AtiA Field Measurements Observations Sample Temp (°C): Time: Q c15-0 Turbidity (ntu): Time: n c VO Diss Oxy (mg/L): Q Time: QgSTI Fe 2+ mg/L: 3 • d Time: O� �_o Specific Cond. (6): Fla Time: QqM Res. C1 (mg/L)/(ug/L): Time: T" Sample pH (s.u.): t —Time: Q `iSM Odor:__ pb Time: Q`1_Qi C ReDox (mV): - a . r Time: O` Appearance: ' c Time: Q G' C_4 ReDox (EH value):YSI ProPlus +200mV 1 t 1 Other: Tune: T General/Weather Observations: (gunny(clo dy/rainy) Temp.(°F) Wind � - (mph) Sampler Signature Stabilization Test Time Purged Temp. (°C) Diss Oxy. (mg/L) CoSpec. S) PH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/ n� L Water level (ft) Other Q1 S ,�3 I D_ TNI Z.S Q IS =1 1 3 1 -Sq. - 5 . --- r--a 7. _�8.7 � . D ---- Q-1 1s"z Q . L T-3 b ,_. - 31. a o , 03 Ca sa `-� :-.1a Document Name: Field data Sheet Date Issued: March 8, 2019 Page: 1 o4 i 8C8Awl3dical Document Number: F-CAR-FLD-001-rev.03 Issuing Authority: Pace Huntersville Quality Office #: 6,nCor+�be Cd 0W L.Iv Aer:) ZOW Name and Affiliation (Sampler(s):� DS • paw Field Data Sheet Review: Name and Affiliation (Inspector): AIIA- Well Information Date; 50120 Well ID: M hl S _ Well Locked: { ES / NO / Flushmount } Well Diameter: Construction; (Steel/Stainless Steel) Total Well Depth: Z ft Multi Factor*: P-163 [`(Radius/12)2x3.14x 7.48] Static Water Level: k q•zZ £t Casing Volume: 4 .0 3 gallons Height of Water Column: 0. 2y ft Cal. 3 Volumes: 0 . £ c' gallons Pump Intake: — Purge Information Date Purged; Start : Finish: .� Purge Rate: By: C-M Purging Method: Total Volume Purged; (gallons/mis/L) Sampling Information Date Collected: Time Collected: (am/pm) Sampling Equipment Used: Instrument ID: Bottle Type Preservatibn Field Measurements/Observations Sample Temp (°C): Time: Diss Oxy (mg/L); Time: Specific Cond. (uS): Time: Sample pH (s.u.): Time: ReDox (mV): Time: ReDox (EH value):YSI ProPlus +200mV_ General/Weather Observations: MU). 7_ Analysis Required Aas m e46 LS Avy� ✓oc Turbidity (ntu): Fe 2+ mg/L: Res. Cl (mg/L)/(µg/L); Odor: Appearance: Other: y5 . i n ! 'W V& I u ev -t- f� Time: Time: Time: Time: Time: Time: 6',/leded (sunny/ loud airy) Ternp. L 7 (°F) Wind 1 H'tO (mph) Sampler Signature: Date: Z 9 Zcy?:r, Stabilization Test Time Purged Temp.Diss (°C) Ox (mg/L) Spec' Con) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/mis/ L Water level (ft) Other Document Name: Field data Sheet Date Issued: !March 8, 2019 aceAnaljftal s Page: 1 of 2 Document Number: F-CAR-FLD-001-tev.03 Issuing Authority: Pace Huntersville Quality f Office Field Data Sheet Client: Sonc mbL Cd Location: Wodor"A .A/C— Project#: 6JnC-0P112LCD Old tf fief,j -2020 Name and Affiliation (Sampler(s):-At�S , o.Ge Field Data Sheet Review: Name and Affiliation (Inspector): NE} - I Date: S (1120 By: C113 Well Information Well ID: MW - ZN - l60 Well Diameter: 2" Total Well Depth: 16.? ' ft Static Water Level: C161 ` /0 ft Height of Water Column: 6K og ft Well Locked: (61SS/ NO / Flushmount ) Construction: VOSteel/Stainless Steel) Multi Factor':O.I� [*(Radius/12)2 x3.14x 7.481 Casing Volume: l 1- 09 gallons Cal. 3 Volumes: 33. gallons Pump Intake: 166. OU ft Purge Information Date Purged: 01 / A 9 / oAew,, 4W Start: 0930 Finish: f f � Purge Rate: A1,91- Olin, �) Purging Method: 6/,ddu aTotal Volume Purged: (3 Z24?" (gallons mIs L) Samolintr Information Date Collected: Uq /oCZ/ ?.oZt'' T' Collected: /1 ZS (amj pm) Sampling Equipment Used: t�Q� Instrument ID: J SZ #fin 3391-rF WWgGZ3 Bottle Type reservation Analysis Required N Pr Field Measurements Observations Sample Temp (°C): . 11 & Time:_ Turbidity (ntu): 9- 3 Time: l{ z S Diss Oxy (mg/L): d ' '4 Time: rl 71 Fe 2+ mg/L: A V Time: 1 17 � Specific Cond. (uS): 1% 0 Time: 112 S Res. CI' — Sample pH (s.u.): 1-3 Time: Odor: Time: I 1 2 ReDox (mV): _ 113.0 Time: 11 ZS Appearance: C(!mo Time: h 7-5 ReDox (EH value):YSI ProPlus +200m.V 2`13 .0 Other: Time: -- General/Weather Observations: - 16C� , _ (sunny cloud ainy) Temp.-?Z- ff) Wind )9'-?2(mph) Sampler Signature: Date: 0� -a r ' Zola Stabilization Test Time Purged Temp. °C ( ) Diss Oxy. ( m L spec' Cond. pH {s.u.) ReDox V) Turbidity Volume removed 1 Water Other g g/ } (US) ( m ntu ( ) allons (gaIlDrIS/ro/ level (ft) 0,135 11-y T 201.3 -7-3 61,6 (6- 00 oc/ 001 15- 0 z7f,1 1, 8.5 K o 95-SS :c'k Ir- a ti _ zZl. q `1 y i f H 9 10 Tl$. 3 -1,6 5w-1 40, 3 Woo `I6 IG 0130 15.3 1 9 -q 213.3 Tq 165,7 lt6,o I zloo .co Document Name: Field Data Sheet Document Issued: March S, 2019 Page Zof ,, ..ae6Alla/)/I Cr?r� > - f Document Number: F-CAR-FLD-001.rev.03 Issueing Authority, Pace Huntersville Quality Office Client: gun oral he- 6oact- 2g-Zol-0 Location: I,��ojfitYl NC Project: &) COA#e Well ID: \fJ - 2 c"E Reviewed Date and By: 5 l 28 M Stabilization Test we11 Diam.Ur N4jUl-iipUCatiD11 F3Cbar- 1 D.0'=03 1..2 0.0-915 1.625 0A C-3 0 2 0.1630 4 a. ti53 0 i 6. 1.46BG Time Temp. Diss Oxy. Spec. Cond. pH (s.u.) ReDox (mV) Turbidity Vokume Removed (gallon ml /L} Water level ( ft) Purged (°C) {mg/Lj (uS) (ntu) circle one MS (5,3 2. 91$7 7-q 500 7_9S ao 15' q 2.2 215.3 9 L Z7 q ugoa i8'.7-g 1010 I5"( ZEZ. i - 3 yq . 5 5600 9e7. I 5 r5.6 r . r Zr<o.2 .3 C47, 1 36. Z 63p4 73,ga' 10M 15.° 1.0 205,q `1.3 ti6,•6 35.E '7000 / do, VV c025 (6.0 11.0 So$.6 1,3 Nb' q 35, 7-400 IoI.ZS 1035 cl'o 04 g 205. 0 `f -3 143. C1 32. 3 17-00 10K 1 ,Z 0.9 S'. 8/ 1-3 43 -3 ?-b 9W0 I03.zf 10 5 5 17 z 0. Z09, 2 `1. 3 C4 7. 3 16. 5 10700 to 5. g6 t0-51- 203, g1f.0 20.9 11?-00 to .4 +11 5 1 1%9 1.3 W 311 13 1 lz q60 lao I�.b G-� R .O a3.3 - t3Zoo d(09-3q. Other �.- ace�k7fj�ical' t Name and Affiliation (Sampler(s):4 Name and Affiliation (Inspector): — Well Information Well ID; D2 L - Well Diameter: r� Total Well Depth: .C! f Static Water Level: _ s 5 y ft Height of Water Colurnn: h .S � 1 Purge Information Date Purged: CM / -6 / Purging Method: VCk , Sampling Information Date Collected: — /=/ -- Time Collected: (am/pm) Sampling Equipment Used: Instrument ID;�f'"s re u ` M cep —Zt .zr I I Bottle Type Preservation Analysis Required Document Name: Field data Sheet Date Issued: March 8, 2019 Page: 1 of _1 Document Number: F-CAR-FLD-001-rev.03 Issuing Authority; Pace Huntersviile Quality Office Field Data Sheet Location: Sh4 v i I e -4 _ j t��r ' aL Project #: �74 C ��: Cr�vii�? 11 C7L 1� Z - Vct , A,)Z-�I, (, rxj Field Data Sheet Review; ia Date: 5! t 1 ZU By: CTS Well Lacked; { Y g / NO / FIushmount ) Construction: & ! /Steel/Stainless Steel) Multi Factor*; C- 1 6 5 ['(Radius/12)2 x 3.14 x 7 481 a Casing Volume: _ �i .��5 gallons CaI.3 Volumes: �� .;� toy _ gations Pump Intake: ft Start: 10 Q Finish: I C� Purge Rate: L��ir1 Total Volume Purged; (gallons/�)/L) Field Measurements/Observations Sampi&T.emp (�C): Diss Oxy (mg/L,)�'~' Specific Cond. (uS): Sample pH ReDox (mV): ReDox- ER value):YSI ProPlus +200 General/Weather Observations Sampler Signature Stabilization Test Turbidity (ntu): Fe 2+ mg/ L !— ma��Odor; me: Appearance: V Other: rainy) Tem Time; Time: Time: Time: (mph) Time Purged Temp.Diss (°C) Ox y. (mg/L) pec' CuCond. PH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/mis/ L Water level (ft) Other I1 .nct,a t Location Cate TimeOj— Samp[e� C P-- 1 a ?yc_ critc C A, -- LZ•d� � f� a Doc meet Revised_ August 4, 2011 i pocumenfi Name' Page 1 off Report Form for Fieid Monito6ng lssuing.Authorities, ( i i 4ocument No.: ace Asheville Quality Off-ce i F-AUL-F-004-rev.00 Pace Analytical Services, Inc i Report Forma for Field Monitoring C. ' Sai'C1pie FO Water poi (units) TemA �`C ) specific GonSuctivity Turbidit (NTU) ORri omrrients r Level (Ft) (uhmos} �w N1 7 --� � f � ; r,,1 w • � 1, 1. G L � ' � �w-Lt • 'f.frYa� i . 3 w. B C7. O.� � i-I � _I � ,r 0 i� .��'S-i,• Ct.S r tcg �{ 11.E J'�e�ic Cp Y.: e �' i `i-1 u O -,�� ) Cate sam(71e� f samp7 V R�, M/0j�/�iA/-M�� Document Name_ Form for Fieid Monitoring Document No.: F-AVL-F-004-rev.00 Pace Analytical Services, Inc Report Form for Field Monitoring Document Revised_ August 4, 2011 PageA-QfA-- Issu ing.Authorities: P Ce Ashevilie Quality Office � 1D Water Level CFt) P" (units) Terri ("C) Specific Conductivity Turbidity iN•rV� i ORG `o comrn eats 1J t -% ., {uhmosJ i.1,77 C�Q 0.i7, �77_�r �.3 / C�� lei -/I v I o, d �2 7. A, Z it l �.`j -��.�f- O, C4r�i2 3'v �2 ao I JY ��8CEi�17&iyelCcZl Document Name: - Report Formfor Field Monitoring Document Revised: August 4, 2011 Page 1 of x Document No.: - F-AUL-F-004-rev.00 - IssuingAuthorities- Pace Asheville Quality Office Location 6&z- r,✓c Q 0 L-f Pace Analytical Services, Inc Report Form for Field Monitoring S/,,/ J me Sampieg7_ - SamPl'e ID Water Le el (Ft) - H units P ( ) TempC (� ) Specific Condcctiv; uhmos Turbidity (NTU) oRP Comments ]ate' CS� C7,z C�=moo I Vl/3�e2 Lc�S Document Name: - Document Revised August 4 2011 F '.� F„ ' Report Form for Fieid Monitoring - Page 1 of 1 IssuingAuthonties �I - ;' �{�<2CG'i�178%/flCeZl -- Rocument No.: F-AUL-F-0'04-rev.00 Pace Analytical Services, Inc Pace Asheville Quality Office 1 Report Form for Field Monitoring '/µ� Loca Ion - Specific water PR (vnRs) Temp (,C) condoceiv.ey Sample ID - Turbidity (NTV) ORP - comments Case Time Sample( Level (Ft) uhmos or t I MW loq-+ -6-/ .fix , ,, 1 (F•f� N, W•7 z1.NG >� �W, /O 6A,✓Os /r/ � F I ! . �t"<?CG`i�ik9�y eICBI ion Ll `, 4"1& OLD Report 'Formfor LG6oSe�� Document Name, Field Monitoring Document No.: F-AVL"F-004-rev.00 Pace Analytical Services, Inc Report Form for Field Monitoring Document Revised: August 4,2011 Page 1 of 1 IAShevlle Cwaities: Pace Asheville Quality Office Loca Sample to Water level (Ft) TemP('C) specific Co..duaos (uhmos Torpidity ( TV) ORP Comments r Cate Time Samplee � AZI,I x ti> A6q„/Op 7 11 VAI N 37 /7tl i �. 30� j G✓ Te -z Lc a.«$ ✓G / S �QBCG'i�h.2lj(!`IL'cTl f tion c`�' �lix/c OL® Time sampieQ� /[off I Document Name: - Report ForDm for Field Monitoring ocument No.: F-AVL-F-004-rev.00 Pace Analytical Services, Inc Report Form for Field Monitoring Specific Water ry units) Temp (" C.nd. My y Sample ID Level (FT) p ( uhmos) Ncwr�- /�f- �'3,/>, Document Revised: August 4, 2011 Page 1 of L IssuingAuthorities: Pace Asheville Cluality Office Turbidity �Rp -Comments (NTV) j i � ; l �. i S_oca Date LF•>� Site: G l gv../c n c !1 c, e J Date: ? WELL CONDITION SUMMARY Personnel: n-?; ' S Page of Sample Well ID Iira4ec4g Well Casing Label Lock Equipment Comments/Observations* Casing Type 0' OK 0 OK [-W OK ❑- Yes G✓L r ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No NW ✓L 0" OK [3- OK ❑- OK [}- Yes /l.7I� �� ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No �RrRh�- ✓ SlE�d ,. ❑' OK [aJ OK [EI' OK Yes M 41, ❑ Damaged ❑ Damaged i ❑ Inadequate ❑ No IjL-6ejijm veyl ❑ OK E]- OK Ea OK ❑ Yes t, ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No ✓ 11 W, Zrr r., [� OK ❑'OK ❑ OK Yes 1\1 { ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No [3- OK OK [a- OK Yes 'VA W ❑ Damaged ❑ Damaged © Inadequate ❑ No OK ❑ OK ❑ OTC ❑ Yes ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No 0 OK D OK [WOK Ea- Yes ' ICJ CriP 7 Sv a � , L ❑ Damaged ❑ Damaged ❑ inadequate ElNo .�, S � �_ Le% l4 ❑ OK [a' OK OK fl Yes ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No E2 OK a OK El- OK Yes F ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No *Note ponding water, weep holes, or any other information pertaining to well condition. Provide additional details on listed items. Return this form to SCS Engineers WELL CONDITION SUMMARY pp L) �f Site: n7 ' sr fl v JL.�� h k' G r? cL Personnel: /Li Date: r �'� Page of Sample Well ID Protective Well Casing Label Lock Equipment Comments/Observations* Casing Type [- OK ❑WOK EafK ©' Yes /`j k/ _ ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No L L ❑ OK ❑ OK ❑ OK ❑ Yes ❑ Damaged ❑ Damaged ❑ inadequate ❑ No 13 %1� ;- ❑ OK ❑ OK ❑ OK ❑ Yes `J ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No I A41Ai -,'Jj--r ci Q- OK [a- OK [-OK E3- Yes �•� fY_ ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No I L&'14- ❑ OK 0 OK [}-0K Yes tit f;�' 1i ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No a OK [} OK OK ❑- Yes 4✓ �� C'� ❑ DcLmaged ❑ Damaged ❑ Inadequate ❑ No D---OK OK [a OK a Yes C'? U/ r 7 ,35 ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No I Er -OK ['OK ❑-QK Yes ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No D-OK OK OK ❑ Yes ,Zjr✓ I ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No G✓ ,BOOK OK OK [! Yes l'✓- i �~ ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No *Note ponding water, weep holes, or any other information pertaining to well condition. Provide additional details on listed items. Return this form to SCS Engineers Site: 0 L- k Date: If' � -7, 1L d WELL CONDITION SUMMARY Personnel: /fit S Page �of Well ID Protective Well Casing Label Lock sampie Equipment Comments/Observations* Casing Type ❑ OK ❑ OK ❑ OK ❑ Yes `it W ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No ❑ OK ❑ OK ❑ OK ❑ Yes nn Vf (c/• ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No ❑--OK ❑WOK B—OK 8— Yes / ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No S—OK [W OK - []GK [}—Yes (/-`j (✓ j7 �� �� ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No t f� /l W ? Z D--OK [WOK [�--OK ❑—Yes M� I� �� � ' ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No 7 f �7 � hz, 4-r-, ❑—OK [7['OK [I —OK D— Yes (,/ -!7 ej ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No E�—OK OK [�— OK [3Yes ❑ Damaged [J Damaged ❑ Inadequate ❑ No IAQ 41 OK [ OK 0---OK � Yes ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No I., L ❑/OK OK OK []/Yes ❑ Damaged ❑ Damaged ❑ inadequate ❑ No ❑' OK OK OK [}� Yes C'+ i [`I !f ❑ Damaged , ❑ Damaged ❑ Inadequate I I ❑ No CK, J-0r *Note ponding water, weep holes, or any other information pertaining to well condition. Provide additional details on listed items. Return this form to SCS Engineers Site: 6"✓C Date: �-- J ?- )-0 (1> D(- a L G CLofe 1 WELL CONDITION SUMMARY Personnel: /w Page L- - of Well ID Protective Casing Well Casing Label Lock Sample Equipment Comments/Observations* Type [� OK 2--OK ❑�OK ©� Yes ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No jam— OK ❑--QK �K EI—Yes ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No OK ❑- OK [-;—OK Yes fIq,p • 'If _ ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No — Q--'OK ©-OK El ---OK ❑Yes ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No CdI] /.qG�l OK WOK [WOK [J, Yes ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No [� OK ❑- OK [�QK ❑- Yes �(/ I ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No Li OK WOK [],OK [] Yes 1-1 �-/? ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No W L [9- OK [3-- OK 0- OK e Yes w f - I1c7 ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No 4 fN �' ❑- OK ❑—OK [- OK El- Yes ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No ❑ OK ❑ OK ❑ OK ❑ Yes ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No *Note ponding water, weep holes, or any other information pertaining to well condition- Provide additional details on listed items. Return this form to SCS Engineers Site: 1j L C Date: �f 7 a V C� ` 0 L Lco�o-p� WELL CONDITION SUMMARY Personnel: Page 5 of _sue Protective Sample Well: ID Casing Well Casing Label Lock Equipment Comments/Observations* Type OK t—:±J Yes M �" r� El Damaged ❑ Damaged ❑ Inadequate ❑ No L `� [�-OK B-OK � OK 0--Yes �w,r�-IL ❑ Damaged ❑ Damaged ❑ inadequate ❑ No ✓ P Q- OK -❑- OK WOK -Yes ❑ Damaged ❑ Domoged ❑ Inadequate ❑ No �� ����„r J ❑ OK ❑ OK ❑ OK ❑ Yes ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No ❑ OK ❑ OK ❑ OK ❑ Yes ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No ❑ OK ❑ OK ❑ OK ❑ Yes ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No ❑ OK ❑ OK ❑ OK ❑ Yes ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No ❑ QK ❑ OK ❑ OK ❑ Yes ❑ Damaged ❑ Damaged ❑ inadequate ❑ No ❑ OK ❑ OK ❑ OK ❑ Yes ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No ❑ OK ❑ OK ❑ OK ❑ Yes ❑ Damaged ❑ Damaged ❑ Inadequate ❑ No *Note ponding water, weep holes, or any other information pertaining to well condition. Provide additional details on listed items. Return this form to SCS Engineers APPENDIX B LABORATORY ANALYTICAL DATA - PACE ANALYTICAL SERVICES, LLC. aceAnalytical Report of Analysis Bunnell-Lammons Engineering, Inc. 6004 Ponders Court Greenville, SC 29615 Attention: Andy Alexander Project Name: Closed Buncombe County Landfill Monitoring Wells Project Number: J20-14175-02 Lot Number:VD29085 Date Completed:05/11/2020 I 05/19/2020 12:47 PM Approved and released by: Lab Director - Greenville: Lucas Odom �Q PCSREpA 2 lkiA ANSI National Accreditation Board 9e A P ACCREDITED -T�- TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 191 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Bunnell-Lammons Engineering, Inc. Lot Number: VD29085 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Pace policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. BOD The seed correction factor associated withsamples -002, -004, -007, -008, -009, -013, -019, -022, -023, and -025 was above the method range of 0.6 to 1.0. No corrective action is required as the BOD calculation accounts for variances in the SCF. No sample dilutions resulted in a depletion of at least 2.0 mg/L. The reported BOD value was computed using the lowest BOD value that can be calculated with the available data. COD approximate values were used to determine sample dilutions.The data have been 6-flagged accordingly. Nitrate Reanalysis of samples -004 and -022 was performed outside of the analytical holding time . The samples were diluted due to the nature of the sample matrix: The LOQ has been elevated to reflect the dilutions. Subcontracted Analysis The analysis for Dissolved Gases, Hydrogen, CO2, and VFA has been performed by Pace Energy and reported on report 33618. This data has been ammended to the end of this report. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 2 of 191 PACE ANALYTICAL SERVICES, LLC Sample Summary Bunnell-Lammons Engineering, Inc. Lot Number: VD29085 Sample Number Sample ID Matrix Date Sampled Date Received 001 MW-3 Aqueous 04/28/20201210 04/29/2020 002 MW-4 Aqueous 04/28/20201035 04/29/2020 003 MW-5 Aqueous 04/28/20201010 04/29/2020 004 MW-6 Aqueous 04/28/20201320 04/29/2020 005 MW-6-192 Aqueous 04/28/20201500 04/29/2020 006 MW-15 Aqueous 04/28/20201500 04/29/2020 007 MW-18-78 Aqueous 04/28/20201630 04/29/2020 008 MW-19-75 Aqueous 04/28/20201630 04/29/2020 009 MW-19-110 Aqueous 04/28/20201330 04/29/2020 010 DPL-1 Aqueous 04/28/20201015 011 MW-12-25 Aqueous 04/28/20201440 04/29/2020 012 MW-13-35 Aqueous 04/28/20201635 04/29/2020 013 MW-13-132 Aqueous 04/28/20201520 04/29/2020 014 MW-4A Aqueous 04/29/2020 0915 04/30/2020 015 MW-17-60 Aqueous 04/29/20201055 04/30/2020 016 MW-17-137 Aqueous 04/29/20201140 04/30/2020 017 MW-17-310 Aqueous 04/29/20201255 04/30/2020 018 Equip Blk Aqueous 04/29/2020 1400 04/30/2020 019 MW-2 Aqueous 04/29/20201345 04/30/2020 020 MW-7 Aqueous 04/29/20201605 04/30/2020 021 MW-B Aqueous 04/29/20201305 04/30/2020 022 MW-21-21 Aqueous 04/29/20201045 04/30/2020 023 MW-21-94 Aqueous 04/29/2020 0950 04/30/2020 024 MW-24-45 Aqueous 04/29/20201110 025 MW-24-160 Aqueous 04/29/20201125 04/30/2020 026 Trip Blk Aqueous 04/29/2020 04/30/2020 (26 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 191 PACE ANALYTICAL SERVICES, LLC Detection Summary Bunnell-Lammons Engineering, Inc. Lot Number: VD29085 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 MW-3 Aqueous 1,4-Dioxane 8260D (SIM) 92 ug/L 10 001 MW-3 Aqueous Benzene 8260D 1.6 ug/L 10 001 MW-3 Aqueous Chlorobenzene 8260D 4.2 ug/L 10 001 MW-3 Aqueous Chloroethane 8260D 3.4 ug/L 10 001 MW-3 Aqueous 1,2-Dichlorobenzene 8260D 0.89 J ug/L 10 001 MW-3 Aqueous 1,4-Dichlorobenzene 8260D 9.1 ug/L 10 001 MW-3 Aqueous 1,1-Dichloroethane 8260D 2.8 ug/L 10 001 MW-3 Aqueous 1,2-Dichloroethane 8260D 0.47 J ug/L 10 001 MW-3 Aqueous cis- 1,2-Dichloroethene 8260D 0.99 J ug/L 10 001 MW-3 Aqueous Vinyl chloride 8260D 0.91 J ug/L 11 001 MW-3 Aqueous Xylenes (total) 8260D 0.98 J ug/L 11 001 MW-3 Aqueous Barium 6020B 240 ug/L 11 001 MW-3 Aqueous Cadmium 6020B 0.17 J ug/L 11 001 MW-3 Aqueous Cobalt 6020B 16 ug/L 11 001 MW-3 Aqueous Nickel 6020B 28 ug/L 11 001 MW-3 Aqueous Zinc 6020B 12 ug/L 12 002 MW-4 Aqueous Alkalinity SM 232013- 440 mg/L 13 002 MW-4 Aqueous BOD, 5 day SM 5210B- 2.0 7 mg/L 13 002 MW-4 Aqueous Chloride 9056A 67 mg/L 13 002 MW-4 Aqueous Sulfate 9056A 24 mg/L 13 002 MW-4 Aqueous TOC SM 5310C- 6.2 mg/L 13 002 MW-4 Aqueous 1,4-Dioxane 8260D (SIM) 25 ug/L 13 002 MW-4 Aqueous Benzene 8260D 0.81 J ug/L 13 002 MW-4 Aqueous Carbon disulfide 8260D 0.49 J ug/L 14 002 MW-4 Aqueous Chlorobenzene 8260D 5.0 ug/L 14 002 MW-4 Aqueous Chloroethane 8260D 2.0 ug/L 14 002 MW-4 Aqueous 1,2-Dichlorobenzene 8260D 0.53 J ug/L 14 002 MW-4 Aqueous 1,4-Dichlorobenzene 8260D 5.8 ug/L 14 002 MW-4 Aqueous 1,1-Dichloroethane 8260D 7.9 ug/L 14 002 MW-4 Aqueous 1,2-Dichloroethane 8260D 0.49 J ug/L 14 002 MW-4 Aqueous cis- 1,2-Dichloroethene 8260D 15 ug/L 14 002 MW-4 Aqueous Trichloroethene 8260D 0.73 J ug/L 14 002 MW-4 Aqueous Vinyl chloride 8260D 2.3 ug/L 14 002 MW-4 Aqueous Barium 6020B 610 ug/L 15 002 MW-4 Aqueous Cadmium 6020B 0.50 ug/L 15 002 MW-4 Aqueous Cobalt 6020B 74 ug/L 15 002 MW-4 Aqueous Nickel 6020B 96 ug/L 15 002 MW-4 Aqueous Zinc 6020B 18 ug/L 15 003 MW-5 Aqueous 1,4-Dioxane 8260D (SIM) 65 ug/L 16 003 MW-5 Aqueous Benzene 8260D 0.68 J ug/L 16 003 MW-5 Aqueous Chlorobenzene 8260D 9.1 ug/L 16 003 MW-5 Aqueous Chloroethane 8260D 1.2 J ug/L 16 003 MW-5 Aqueous 1,4-Dichlorobenzene 8260D 6.8 ug/L 16 003 MW-5 Aqueous 1,1-Dichloroethane 8260D 0.68 J ug/L 16 003 MW-5 Aqueous Barium 6020B 140 ug/L 17 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 191 Detection Summary (Continued) Lot Number: VD29085 Sample Sample ID Matrix Parameter Method Result Q Units Page 003 MW-5 Aqueous Cobalt 6020B 9.5 ug/L 17 003 MW-5 Aqueous Nickel 6020B 16 ug/L 17 003 MW-5 Aqueous Zinc 6020B 5.7 J ug/L 18 004 MW-6 Aqueous Alkalinity SM 232013- 550 mg/L 19 004 MW-6 Aqueous BOD, 5 day SM 521013- 8.2 7 mg/L 19 004 MW-6 Aqueous Chloride 9056A 140 mg/L 19 004 MW-6 Aqueous COD SM 5220D- 37 mg/L 19 004 MW-6 Aqueous Sulfate 9056A 1.3 mg/L 19 004 MW-6 Aqueous TOC SM 5310C- 10 mg/L 19 004 MW-6 Aqueous 1,4-Dioxane 8260D (SIM) 28 ug/L 19 004 MW-6 Aqueous Acetone 8260D 5.5 J ug/L 19 004 MW-6 Aqueous Benzene 8260D 1.4 ug/L 19 004 MW-6 Aqueous Chlorobenzene 8260D 10 ug/L 20 004 MW-6 Aqueous Chloroethane 8260D 4.2 ug/L 20 004 MW-6 Aqueous 1,4-Dichlorobenzene 8260D 4.2 ug/L 20 004 MW-6 Aqueous 1,1-Dichloroethane 8260D 2.5 ug/L 20 004 MW-6 Aqueous cis- 1,2-Dichloroethene 8260D 0.60 J ug/L 20 004 MW-6 Aqueous Toluene 8260D 0.40 J ug/L 20 004 MW-6 Aqueous Barium 6020E 1500 ug/L 21 004 MW-6 Aqueous Copper 6020E 1.4 J ug/L 21 004 MW-6 Aqueous Nickel 6020E 11 ug/L 21 004 MW-6 Aqueous Zinc 6020E 2.6 J ug/L 21 005 MW-6-192 Aqueous 1,4-Dioxane 8260D (SIM) 5.2 ug/L 22 005 MW-6-192 Aqueous Acetone 8260D 8.5 J ug/L 22 005 MW-6-192 Aqueous Chlorobenzene 8260D 1.3 ug/L 22 005 MW-6-192 Aqueous Chloroethane 8260D 0.77 J ug/L 22 005 MW-6-192 Aqueous 1,4-Dichlorobenzene 8260D 0.55 J ug/L 22 005 MW-6-192 Aqueous 1,1-Dichloroethane 8260D 0.69 J ug/L 22 005 MW-6-192 Aqueous Barium 6020E 64 ug/L 23 005 MW-6-192 Aqueous Nickel 6020E 2.6 J ug/L 23 005 MW-6-192 Aqueous Zinc 6020E 2.8 J ug/L 24 006 MW-15 Aqueous Acetone 8260D 9.4 J ug/L 25 006 MW-15 Aqueous 2-Butanone (MEK) 8260D 2.3 J ug/L 25 006 MW-15 Aqueous Barium 6020B 170 ug/L 26 006 MW-15 Aqueous Chromium 6020B 21 ug/L 26 006 MW-15 Aqueous Lead 6020B 0.88 J ug/L 26 006 MW-15 Aqueous Nickel 6020B 5.4 ug/L 26 006 MW-15 Aqueous Zinc 6020B 2.9 J ug/L 27 007 MW-18-78 Aqueous Alkalinity SM 232013- 300 mg/L 28 007 MW-18-78 Aqueous BOD, 5 day SM 521013- 2.9 76 mg/L 28 007 MW-18-78 Aqueous Chloride 9056A 130 mg/L 28 007 MW-18-78 Aqueous COD SM 5220D- 25 mg/L 28 007 MW-18-78 Aqueous Sulfate 9056A 1.4 mg/L 28 007 MW-18-78 Aqueous TOC SM 5310C- 7.6 mg/L 28 007 MW-18-78 Aqueous 1,4-Dioxane 8260D (SIM) 50 ug/L 28 007 MW-18-78 Aqueous Acetone 8260D 5.9 J ug/L 28 007 MW-18-78 Aqueous Chlorobenzene 8260D 3.3 ug/L 29 007 MW-18-78 Aqueous Chloroethane 8260D 0.70 J ug/L 29 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 191 Detection Summary (Continued) Lot Number: VD29085 Sample Sample ID Matrix Parameter Method Result Q Units Page 007 MW-18-78 Aqueous 1,4-Dichlorobenzene 8260D 2.5 ug/L 29 007 MW-18-78 Aqueous 1,1-Dichloroethane 8260D 0.96 J ug/L 29 007 MW-18-78 Aqueous cis- 1,2-Dichloroethene 8260D 0.99 J ug/L 29 007 MW-18-78 Aqueous Vinyl chloride 8260D 0.58 J ug/L 29 007 MW-18-78 Aqueous Barium 6020B 73 ug/L 30 007 MW-18-78 Aqueous Nickel 6020B 6.4 ug/L 30 008 MW-19-75 Aqueous Alkalinity SM 232013- 400 mg/L 31 008 MW-19-75 Aqueous BOD, 5 day SM 521013- 2.2 7 mg/L 31 008 MW-19-75 Aqueous Chloride 9056A 160 mg/L 31 008 MW-19-75 Aqueous COD SM 5220D- 38 mg/L 31 008 MW-19-75 Aqueous Sulfate 9056A 14 mg/L 31 008 MW-19-75 Aqueous TOC SM 5310C- 13 mg/L 31 008 MW-19-75 Aqueous 1,4-Dioxane 8260D (SIM) 96 ug/L 31 008 MW-19-75 Aqueous Benzene 8260D 0.50 J ug/L 31 008 MW-19-75 Aqueous Chlorobenzene 8260D 5.1 ug/L 32 008 MW-19-75 Aqueous 1,4-Dichlorobenzene 8260D 5.1 ug/L 32 008 MW-19-75 Aqueous 1,1-Dichloroethane 8260D 0.69 J ug/L 32 008 MW-19-75 Aqueous Barium 6020E 130 ug/L 33 008 MW-19-75 Aqueous Cobalt 6020E 3.2 J ug/L 33 008 MW-19-75 Aqueous Nickel 6020E 24 ug/L 33 008 MW-19-75 Aqueous Zinc 6020E 3.5 J ug/L 33 009 MW-19-110 Aqueous Alkalinity SM 232013- 160 mg/L 34 009 MW-19-110 Aqueous Chloride 9056A 38 mg/L 34 009 MW-19-110 Aqueous Sulfate 9056A 12 mg/L 34 009 MW-19-110 Aqueous TOC SM 5310C- 2.0 mg/L 34 009 MW-19-110 Aqueous 1,4-Dioxane 8260D (SIM) 29 ug/L 34 009 MW-19-110 Aqueous Chloroethane 8260D 0.58 J ug/L 35 009 MW-19-110 Aqueous 1,4-Dichlorobenzene 8260D 0.44 J ug/L 35 009 MW-19-110 Aqueous cis- 1,2-Dichloroethene 8260D 0.46 J ug/L 35 009 MW-19-110 Aqueous Barium 6020E 10 ug/L 36 009 MW-19-110 Aqueous Nickel 6020E 3.7 J ug/L 36 011 MW-12-25 Aqueous Barium 6020B 69 ug/L 38 011 MW-12-25 Aqueous Nickel 6020B 18 ug/L 38 011 MW-12-25 Aqueous Zinc 6020B 11 ug/L 39 012 MW-13-35 Aqueous Benzene 8260D 1.8 ug/L 40 012 MW-13-35 Aqueous Chlorobenzene 8260D 7.2 ug/L 40 012 MW-13-35 Aqueous 1,2-Dichlorobenzene 8260D 5.0 ug/L 40 012 MW-13-35 Aqueous 1,4-Dichlorobenzene 8260D 23 ug/L 40 012 MW-13-35 Aqueous cis- 1,2-Dichloroethene 8260D 3.1 ug/L 40 012 MW-13-35 Aqueous trans-1,2-Dichloroethene 8260D 0.40 J ug/L 40 012 MW-13-35 Aqueous Vinyl chloride 8260D 0.64 J ug/L 41 012 MW-13-35 Aqueous Barium 6020B 180 ug/L 41 012 MW-13-35 Aqueous Cobalt 6020B 1.3 J ug/L 41 012 MW-13-35 Aqueous Nickel 6020E 4.5 J ug/L 41 012 MW-13-35 Aqueous Zinc 6020E 3.1 J ug/L 42 013 MW-13-132 Aqueous Alkalinity SM 232013- 150 mg/L 43 013 MW-13-132 Aqueous Chloride 9056A 4.8 mg/L 43 013 MW-13-132 Aqueous Sulfate 9056A 8.2 mg/L 43 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 191 Detection Summary (Continued) Lot Number: VD29085 Sample Sample ID Matrix Parameter Method Result Q Units Page 013 MW-13-132 Aqueous Sulfide SM 4500-S2 F- 1.1 mg/L 43 013 MW-13-132 Aqueous Benzene 8260D 1.8 ug/L 43 013 MW-13-132 Aqueous 1,4-Dichlorobenzene 8260D 1.2 ug/L 44 013 MW-13-132 Aqueous 1,1-Dichloroethane 8260D 1.2 ug/L 44 013 MW-13-132 Aqueous cis- 1,2-Dichloroethene 8260D 8.4 ug/L 44 013 MW-13-132 Aqueous Vinyl chloride 8260D 2.3 ug/L 44 013 MW-13-132 Aqueous Barium 6020B 40 ug/L 45 013 MW-13-132 Aqueous Zinc 6020B 2.9 J ug/L 45 014 MW-4A Aqueous 1,4-Dioxane 8260D (SIM) 15 ug/L 46 014 MW-4A Aqueous Acetone 8260D 54 ug/L 46 014 MW-4A Aqueous Benzene 8260D 5.9 ug/L 46 014 MW-4A Aqueous 2-Butanone (MEK) 8260D 140 ug/L 46 014 MW-4A Aqueous Chlorobenzene 8260D 16 ug/L 46 014 MW-4A Aqueous 1,2-Dichlorobenzene 8260D 6.7 ug/L 46 014 MW-4A Aqueous 1,4-Dichlorobenzene 8260D 56 ug/L 46 014 MW-4A Aqueous cis- 1,2-Dichloroethene 8260D 1.2 ug/L 46 014 MW-4A Aqueous trans-1,2-Dichloroethene 8260D 0.46 J ug/L 46 014 MW-4A Aqueous Ethylbenzene 8260D 11 ug/L 47 014 MW-4A Aqueous 4-Methyl-2-pentanone 8260D 32 ug/L 47 014 MW-4A Aqueous Toluene 8260D 3.3 ug/L 47 014 MW-4A Aqueous Vinyl chloride 8260D 1.2 ug/L 47 014 MW-4A Aqueous Xylenes (total) 8260D 19 ug/L 47 014 MW-4A Aqueous Barium 6020E 840 ug/L 47 014 MW-4A Aqueous Cobalt 6020E 56 ug/L 47 014 MW-4A Aqueous Copper 6020E 3.5 J ug/L 47 014 MW-4A Aqueous Nickel 6020E 12 ug/L 48 014 MW-4A Aqueous Zinc 6020E 2.8 J ug/L 48 015 MW-17-60 Aqueous 1,4-Dioxane 8260D (SIM) 24 ug/L 49 015 MW-17-60 Aqueous 1,4-Dichlorobenzene 8260D 1.3 ug/L 49 015 MW-17-60 Aqueous 1,1-Dichloroethane 8260D 1.2 ug/L 49 015 MW-17-60 Aqueous cis- 1,2-Dichloroethene 8260D 1.8 ug/L 49 015 MW-17-60 Aqueous Vinyl chloride 8260D 0.78 J ug/L 50 015 MW-17-60 Aqueous Barium 6020B 24 ug/L 50 016 MW-17-137 Aqueous 1,4-Dioxane 8260D (SIM) 32 ug/L 52 016 MW-17-137 Aqueous Chloroethane 8260D 0.49 J ug/L 52 016 MW-17-137 Aqueous 1,4-Dichlorobenzene 8260D 0.73 J ug/L 52 016 MW-17-137 Aqueous 1,1-Dichloroethane 8260D 0.80 J ug/L 52 016 MW-17-137 Aqueous Vinyl chloride 8260D 0.52 J ug/L 53 016 MW-17-137 Aqueous Xylenes (total) 8260D 0.46 J ug/L 53 016 MW-17-137 Aqueous Barium 6020B 26 ug/L 53 017 MW-17-310 Aqueous Acetone 8260D 5.2 J ug/L 55 017 MW-17-310 Aqueous Barium 6020B 3.5 J ug/L 56 017 MW-17-310 Aqueous Lead 6020B 0.53 J ug/L 56 017 MW-17-310 Aqueous Zinc 6020E 4.6 J ug/L 57 018 Equip Blk Aqueous Barium 6020E 4.5 J ug/L 59 018 Equip Blk Aqueous Copper 6020B 1.6 J ug/L 59 019 MW-2 Aqueous Alkalinity SM 232013- 61 mg/L 60 019 MW-2 Aqueous Chloride 9056A 2.1 mg/L 60 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 191 Detection Summary (Continued) Lot Number: VD29085 Sample Sample ID Matrix Parameter Method Result Q Units Page 019 MW-2 Aqueous Nitrate - N 9056A 0.014 J mg/L 60 019 MW-2 Aqueous Sulfate 9056A 2.9 mg/L 60 019 MW-2 Aqueous Barium 6020B 23 ug/L 62 019 MW-2 Aqueous Copper 6020B 2.1 J ug/L 62 019 MW-2 Aqueous Lead 6020B 0.63 J ug/L 62 019 MW-2 Aqueous Nickel 6020B 2.9 J ug/L 62 019 MW-2 Aqueous Zinc 6020B 5.0 J ug/L 62 020 MW-7 Aqueous Acetone 8260D 5.1 J ug/L 63 020 MW-7 Aqueous Benzene 8260D 1.5 ug/L 63 020 MW-7 Aqueous Chlorobenzene 8260D 7.4 ug/L 63 020 MW-7 Aqueous Chloroethane 8260D 2.4 ug/L 63 020 MW-7 Aqueous 1,4-Dichlorobenzene 8260D 3.4 ug/L 63 020 MW-7 Aqueous 1,1-Dichloroethane 8260D 3.2 ug/L 63 020 MW-7 Aqueous cis- 1,2-Dichloroethene 8260D 19 ug/L 63 020 MW-7 Aqueous Trichloroethene 8260D 0.81 J ug/L 64 020 MW-7 Aqueous Xylenes (total) 8260D 0.42 J ug/L 64 020 MW-7 Aqueous Barium 6020E 220 ug/L 64 020 MW-7 Aqueous Beryllium 6020E 0.19 J ug/L 64 020 MW-7 Aqueous Cadmium 6020E 0.20 J ug/L 64 020 MW-7 Aqueous Cobalt 6020E 200 ug/L 64 020 MW-7 Aqueous Copper 6020E 11 ug/L 64 020 MW-7 Aqueous Nickel 6020E 70 ug/L 64 020 MW-7 Aqueous Zinc 6020E 17 ug/L 65 021 MW-B Aqueous 1,4-Dioxane 8260D (SIM) 34 ug/L 66 021 MW-B Aqueous 2-Butanone (MEK) 8260D 2.2 J ug/L 66 021 MW-B Aqueous Chlorobenzene 8260D 1.1 ug/L 66 021 MW-B Aqueous Chloroethane 8260D 0.65 J ug/L 66 021 MW-B Aqueous 1,4-Dichlorobenzene 8260D 1.9 ug/L 66 021 MW-B Aqueous 1,1-Dichloroethane 8260D 1.7 ug/L 66 021 MW-B Aqueous cis- 1,2-Dichloroethene 8260D 23 ug/L 66 021 MW-B Aqueous Vinyl chloride 8260D 7.7 ug/L 67 021 MW-B Aqueous Barium 6020B 180 ug/L 67 021 MW-B Aqueous Nickel 6020B 1.3 J ug/L 67 022 MW-21-21 Aqueous Alkalinity SM 232013- 680 mg/L 69 022 MW-21-21 Aqueous BOD, 5 day SM 521013- 3.1 7 mg/L 69 022 MW-21-21 Aqueous Chloride 9056A 50 mg/L 69 022 MW-21-21 Aqueous COD SM 5220D- 33 mg/L 69 022 MW-21-21 Aqueous Sulfate 9056A 38 mg/L 69 022 MW-21-21 Aqueous TOC SM 5310C- 12 mg/L 69 022 MW-21-21 Aqueous 1,4-Dioxane 8260D (SIM) 18 ug/L 69 022 MW-21-21 Aqueous Benzene 8260D 2.1 ug/L 69 022 MW-21-21 Aqueous Chlorobenzene 8260D 18 ug/L 70 022 MW-21-21 Aqueous 1,2-Dichlorobenzene 8260D 3.1 ug/L 70 022 MW-21-21 Aqueous 1,4-Dichlorobenzene 8260D 9.7 ug/L 70 022 MW-21-21 Aqueous 1,1-Dichloroethane 8260D 2.9 ug/L 70 022 MW-21-21 Aqueous cis- 1,2-Dichloroethene 8260D 6.5 ug/L 70 022 MW-21-21 Aqueous Trichloroethene 8260D 0.43 J ug/L 70 022 MW-21-21 Aqueous Vinyl chloride 8260D 1.6 ug/L 70 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 191 Detection Summary (Continued) Lot Number: VD29085 Sample Sample ID Matrix Parameter Method Result Q Units Page 022 MW-21-21 Aqueous Barium 6020B 120 ug/L 71 022 MW-21-21 Aqueous Cobalt 6020B 13 ug/L 71 022 MW-21-21 Aqueous Nickel 6020B 3.5 J ug/L 71 023 MW-21-94 Aqueous Alkalinity SM 232013- 320 mg/L 72 023 MW-21-94 Aqueous BOD, 5 day SM 521013- 2.2 7 mg/L 72 023 MW-21-94 Aqueous Chloride 9056A 99 mg/L 72 023 MW-21-94 Aqueous COD SM 5220D- 20 mg/L 72 023 MW-21-94 Aqueous Sulfate 9056A 2.2 mg/L 72 023 MW-21-94 Aqueous TOC SM 5310C- 7.3 mg/L 72 023 MW-21-94 Aqueous 1,4-Dioxane 8260D (SIM) 48 ug/L 72 023 MW-21-94 Aqueous Chlorobenzene 8260D 1.5 ug/L 73 023 MW-21-94 Aqueous Chloroethane 8260D 2.8 ug/L 73 023 MW-21-94 Aqueous 1,4-Dichlorobenzene 8260D 2.7 ug/L 73 023 MW-21-94 Aqueous 1,1-Dichloroethane 8260D 0.81 J ug/L 73 023 MW-21-94 Aqueous 1,2-Dichloroethane 8260D 0.47 J ug/L 73 023 MW-21-94 Aqueous cis- 1,2-Dichloroethene 8260D 2.5 ug/L 73 023 MW-21-94 Aqueous Vinyl chloride 8260D 0.92 J ug/L 73 023 MW-21-94 Aqueous Barium 6020E 53 ug/L 74 023 MW-21-94 Aqueous Nickel 6020E 8.5 ug/L 74 025 MW-24-160 Aqueous Alkalinity SM 232013- 60 mg/L 75 025 MW-24-160 Aqueous BOD, 5 day SM 521013- 5.8 7 mg/L 75 025 MW-24-160 Aqueous Chloride 9056A 7.4 mg/L 75 025 MW-24-160 Aqueous Sulfate 9056A 23 mg/L 75 025 MW-24-160 Aqueous TOC SM 5310C- 2.6 mg/L 75 025 MW-24-160 Aqueous Barium 6020E 18 ug/L 77 025 MW-24-160 Aqueous Copper 6020E 4.3 J ug/L 77 025 MW-24-160 Aqueous Lead 6020E 1.0 ug/L 77 025 MW-24-160 Aqueous Nickel 6020E 1.9 J ug/L 77 025 MW-24-160 Aqueous Zinc 6020E 7.8 J ug/L 77 (266 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-001 Description: MW-3 Matrix: Aqueous Date Sampled:04/28/2020 1210 Date Received:04/29/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/30/2020 2221 JTH 52603 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 92 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 92 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/2020 0118 STM 52607 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 1.6 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 4.2 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 3.4 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.89 J 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 9.1 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 2.8 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.47 J 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis -1,2-Dichloroethene 156-59-2 8260D 0.99 J 1.0 0.40 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-001 Description: MW-3 Matrix: Aqueous Date Sampled:04/28/2020 1210 Date Received:04/29/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/2020 0118 STM 52607 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.91 J 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 0.98 J 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 99 70-130 1,2-Dichloroethane-d4 101 70-130 Toluene-d8 108 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 04/30/2020 2343 BNW 04/30/2020 1605 52485 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020E ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020E 240 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.17 J 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020E ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020E 16 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020E 28 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-001 Description: MW-3 Matrix: Aqueous Date Sampled:04/28/2020 1210 Date Received:04/29/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 04/30/2020 2343 BNW 04/30/2020 1605 52485 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020E ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020E ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020E 12 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-002 Description: MW-4 Matrix: Aqueous Date Sampled:04/28/2020 1035 Date Received:04/29/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/01/2020 1345 KFE 52672 1 (BOD, 5 day) SM 5210B-2011 1 05/04/2020 2018 SJL 04/29/2020 2320 13319 1 (Chloride) 9056A 1 04/30/2020 0904 AMR 52644 1 (COD) SM 5220D-2011 1 05/10/2020 1438 HET 53424 1 (Nitrate - N) 9056A 1 04/30/2020 0904 AMR 52651 1 (Sulfate) 9056A 1 04/30/2020 0904 AMR 52640 1 (Sulfide) SM 4500-S2 F-2011 1 05/05/2020 2146 HET 52970 1 (TOC) SM 531 OC-2011 1 05/04/2020 1151 DMA 52797 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity SM 23206- 440 20 20 mg/L 1 BOD, 5 day SM 52106- 2.0 7 2.0 0.18 mg/L 1 Chloride 9056A 67 1.0 0.20 mg/L 1 COD SM 5220D- ND 20 20 mg/L 1 Nitrate - N 9056A ND 0.020 0.0050 mg/L 1 Sulfate 9056A 24 1.0 0.20 mg/L 1 Sulfide 18496-25-8 SM 4500-S2 F- ND 1.0 0.99 mg/L 1 TOC SM 5310C- 6.2 1.0 1.0 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/30/2020 2245 JTH 52603 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 25 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 91 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/2020 0142 STM 52607 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 0.81 J 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-002 Description: MW-4 Matrix: Aqueous Date Sampled:04/28/2020 1035 Date Received:04/29/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/2020 0142 STM 52607 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.49 J 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 5.0 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 2.0 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.53 J 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 5.8 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 7.9 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.49 J 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis -1,2-Dichloroethene 156-59-2 8260D 15 1.0 0.40 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D 0.73 J 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 2.3 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-002 Description: MW-4 Matrix: Aqueous Date Sampled:04/28/2020 1035 Date Received:04/29/2020 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 101 70-130 1,2-Dichloroethane-d4 103 70-130 Toluene-d8 106 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 04/30/2020 2349 BNW 04/30/2020 1605 52485 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 610 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020E 0.50 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 74 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020E ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020E 96 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020E ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020E ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 18 10 2.5 ug/L 1 Footnote(s): 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-003 Description: MW-5 Matrix: Aqueous Date Sampled:04/28/2020 1010 Date Received:04/29/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/30/2020 2310 JTH 52603 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 65 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 96 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/2020 0205 STM 52607 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 0.68 J 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 9.1 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 1.2 J 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 6.8 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.68 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 16 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-003 Description: MW-5 Matrix: Aqueous Date Sampled:04/28/2020 1010 Date Received:04/29/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/2020 0205 STM 52607 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 101 70-130 1,2-Dichloroethane-d4 103 70-130 Toluene-d8 106 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 04/30/2020 2355 BNW 04/30/2020 1605 52485 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020E ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020E 140 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020E ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020E 9.5 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020E 16 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 17 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-003 Description: MW-5 Matrix: Aqueous Date Sampled:04/28/2020 1010 Date Received:04/29/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 04/30/2020 2355 BNW 04/30/2020 1605 52485 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020E ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020E ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020E 5.7 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 18 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-004 Description: MW-6 Matrix: Aqueous Date Sampled:04/28/2020 1320 Date Received:04/29/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/01/2020 1354 KFE 52672 1 (BOD, 5 day) SM 5210B-2011 1 05/04/2020 2018 SJL 04/29/2020 2320 13319 1 (Chloride) 9056A 1 04/30/2020 0927 AMR 52644 1 (COD) SM 5220D-2011 1 05/10/2020 1439 HET 53424 2 (Nitrate - N) 9056A 5 05/07/2020 0947 HKL 53190 1 (Sulfate) 9056A 1 04/30/2020 0927 AMR 52640 1 (Sulfide) SM 4500-S2 F-2011 1 05/05/2020 2146 HET 52970 1 (TOC) SM 531 OC-2011 1 05/04/2020 1204 DMA 52797 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity SM 23206- 550 20 20 mg/L 1 BOD, 5 day SM 52106- 8.2 7 2.0 0.18 mg/L 1 Chloride 9056A 140 1.0 0.20 mg/L 1 COD SM 5220D- 37 20 20 mg/L 1 Nitrate - N 9056A ND H 0.10 0.025 mg/L 2 Sulfate 9056A 1.3 1.0 0.20 mg/L 1 Sulfide 18496-25-8 SM 4500-S2 F- ND 1.0 0.99 mg/L 1 TOC SM 5310C- 10 1.0 1.0 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/30/2020 2334 JTH 52603 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 28 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 95 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/2020 0228 STM 52607 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 5.5 J 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 1.4 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 19 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-004 Description: MW-6 Matrix: Aqueous Date Sampled:04/28/2020 1320 Date Received:04/29/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/2020 0228 STM 52607 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 10 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 4.2 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 4.2 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 2.5 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis -1,2-Dichloroethene 156-59-2 8260D 0.60 J 1.0 0.40 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D 0.40 J 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 20 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-004 Description: MW-6 Matrix: Aqueous Date Sampled:04/28/2020 1320 Date Received:04/29/2020 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 105 70-130 1,2-Dichloroethane-d4 103 70-130 Toluene-d8 108 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/01/2020 0001 BNW 04/30/2020 1605 52485 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 1500 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020E ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020E ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.4 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020E ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020E 11 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020E ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020E ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 2.6 J 10 2.5 ug/L 1 Footnote(s): 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 21 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-005 Description: MW-6-192 Matrix: Aqueous Date Sampled:04/28/2020 1500 Date Received:04/29/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 5030B 8260D (SIM) 1 05/05/2020 1038 TML 52884 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 5.2 3.0 1.0 ug/L 2 Run 2 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 98 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/2020 0251 STM 52607 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 8.5 J 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 1.3 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.77 J 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.55 J 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.69 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 22 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-005 Description: MW-6-192 Matrix: Aqueous Date Sampled:04/28/2020 1500 Date Received:04/29/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/2020 0251 STM 52607 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 100 70-130 1,2-Dichloroethane-d4 106 70-130 Toluene-d8 106 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/01/2020 0007 BNW 04/30/2020 1605 52485 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020E ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020E 64 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020E ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020E ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020E 2.6 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 23 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-005 Description: MW-6-192 Matrix: Aqueous Date Sampled:04/28/2020 1500 Date Received:04/29/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/01/2020 0007 BNW 04/30/2020 1605 52485 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020E ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020E ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020E 2.8 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 24 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-006 Description: MW-15 Matrix: Aqueous Date Sampled:04/28/2020 1500 Date Received:04/29/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/01/2020 0023 JTH 52603 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 94 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/2020 0314 STM 52607 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 9.4 J 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 2.3 J 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 25 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-006 Description: MW-15 Matrix: Aqueous Date Sampled:04/28/2020 1500 Date Received:04/29/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/2020 0314 STM 52607 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 100 70-130 1,2-Dichloroethane-d4 103 70-130 Toluene-d8 106 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/01/2020 0012 BNW 04/30/2020 1605 52485 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020E ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020E 170 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 21 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020E ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.88 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020E 5.4 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 26 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-006 Description: MW-15 Matrix: Aqueous Date Sampled:04/28/2020 1500 Date Received:04/29/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/01/2020 0012 BNW 04/30/2020 1605 52485 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020E ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020E ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020E 2.9 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 27 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-007 Description: MW-18-78 Matrix: Aqueous Date Sampled:04/28/2020 1630 Date Received:04/29/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/01/2020 1401 KFE 52672 1 (BOD, 5 day) SM 5210B-2011 1 05/04/2020 2018 SJL 04/29/2020 2320 13319 1 (Chloride) 9056A 1 04/30/2020 0950 AMR 52644 1 (COD) SM 5220D-2011 1 05/10/2020 1439 HET 53424 1 (Nitrate - N) 9056A 1 04/30/2020 0950 AMR 52651 1 (Sulfate) 9056A 1 04/30/2020 0950 AMR 52640 1 (Sulfide) SM 4500-S2 F-2011 1 05/05/2020 2146 HET 52970 1 (TOC) SM 531 OC-2011 1 05/04/2020 1217 DMA 52797 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity SM 23206- 300 20 20 mg/L 1 BOD, 5 day SM 52106- 2.9 76 2.0 0.18 mg/L 1 Chloride 9056A 130 1.0 0.20 mg/L 1 COD SM 5220D- 25 20 20 mg/L 1 Nitrate - N 9056A ND 0.020 0.0050 mg/L 1 Sulfate 9056A 1.4 1.0 0.20 mg/L 1 Sulfide 18496-25-8 SM 4500-S2 F- ND 1.0 0.99 mg/L 1 TOC SM 5310C- 7.6 1.0 1.0 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/01/2020 0047 JTH 52603 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 50 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 94 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/2020 0337 STM 52607 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 5.9 J 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 28 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-007 Description: MW-18-78 Matrix: Aqueous Date Sampled:04/28/2020 1630 Date Received:04/29/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/2020 0337 STM 52607 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 3.3 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.70 J 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 2.5 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.96 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis -1,2-Dichloroethene 156-59-2 8260D 0.99 J 1.0 0.40 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.58 J 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 29 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-007 Description: MW-18-78 Matrix: Aqueous Date Sampled:04/28/2020 1630 Date Received:04/29/2020 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 104 70-130 1,2-Dichloroethane-d4 103 70-130 Toluene-d8 108 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/01/2020 0018 BNW 04/30/2020 1605 52485 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 73 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020E ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020E ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020E ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020E 6.4 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020E ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020E ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 Footnote(s): 6-D.O. depletion < 2.00 mg/L 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 30 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-008 Description: MW-19-75 Matrix: Aqueous Date Sampled:04/28/2020 1630 Date Received:04/29/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/01/2020 1409 KFE 52672 1 (BOD, 5 day) SM 5210B-2011 1 05/04/2020 2018 SJL 04/29/2020 2320 13319 1 (Chloride) 9056A 1 04/30/2020 1012 AMR 52644 1 (COD) SM 5220D-2011 1 05/10/2020 1439 HET 53424 1 (Nitrate - N) 9056A 1 04/30/2020 1012 AMR 52651 1 (Sulfate) 9056A 1 04/30/2020 1012 AMR 52640 1 (Sulfide) SM 4500-S2 F-2011 1 05/05/2020 2146 HET 52970 1 (TOC) SM 531 OC-2011 1 05/04/2020 1230 DMA 52797 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity SM 23206- 400 20 20 mg/L 1 BOD, 5 day SM 52106- 2.2 7 2.0 0.18 mg/L 1 Chloride 9056A 160 1.0 0.20 mg/L 1 COD SM 5220D- 38 20 20 mg/L 1 Nitrate - N 9056A ND 0.020 0.0050 mg/L 1 Sulfate 9056A 14 1.0 0.20 mg/L 1 Sulfide 18496-25-8 SM 4500-S2 F- ND 1.0 0.99 mg/L 1 TOC SM 5310C- 13 1.0 1.0 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/01/2020 0112 JTH 52603 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 96 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 95 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/2020 0400 STM 52607 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 J 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 31 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-008 Description: MW-19-75 Matrix: Aqueous Date Sampled:04/28/2020 1630 Date Received:04/29/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/2020 0400 STM 52607 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 5.1 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 5.1 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.69 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 32 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-008 Description: MW-19-75 Matrix: Aqueous Date Sampled:04/28/2020 1630 Date Received:04/29/2020 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 103 70-130 Toluene-d8 104 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/01/2020 0024 BNW 04/30/2020 1605 52485 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 130 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020E ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020E ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 3.2 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020E ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020E 24 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020E ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020E ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.5 J 10 2.5 ug/L 1 Footnote(s): 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 33 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-009 Description: MW-19-110 Matrix: Aqueous Date Sampled:04/28/2020 1330 Date Received:04/29/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/01/2020 1417 KFE 52672 1 (BOD, 5 day) SM 5210B-2011 1 05/04/2020 2018 SJL 04/29/2020 2320 13319 1 (Chloride) 9056A 1 04/30/2020 1035 AMR 52644 1 (COD) SM 5220D-2011 1 05/10/2020 1439 HET 53424 1 (Nitrate - N) 9056A 1 04/30/2020 1035 AMR 52651 1 (Sulfate) 9056A 1 04/30/2020 1035 AMR 52640 1 (Sulfide) SM 4500-S2 F-2011 1 05/05/2020 2146 HET 52970 1 (TOC) SM 531 OC-2011 1 05/04/2020 1243 DMA 52797 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity SM 23206- 160 20 20 mg/L 1 BOD, 5 day SM 52106- ND 7 2.0 0.18 mg/L 1 Chloride 9056A 38 1.0 0.20 mg/L 1 COD SM 5220D- ND 20 20 mg/L 1 Nitrate - N 9056A ND 0.020 0.0050 mg/L 1 Sulfate 9056A 12 1.0 0.20 mg/L 1 Sulfide 18496-25-8 SM 4500-S2 F- ND 1.0 0.99 mg/L 1 TOC SM 5310C- 2.0 1.0 1.0 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/01/2020 0136 JTH 52603 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 29 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 96 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/2020 0424 STM 52607 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 34 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-009 Description: MW-19-110 Matrix: Aqueous Date Sampled:04/28/2020 1330 Date Received:04/29/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/2020 0424 STM 52607 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.58 J 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.44 J 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis -1,2-Dichloroethene 156-59-2 8260D 0.46 J 1.0 0.40 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 35 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-009 Description: MW-19-110 Matrix: Aqueous Date Sampled:04/28/2020 1330 Date Received:04/29/2020 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 100 70-130 1,2-Dichloroethane-d4 102 70-130 Toluene-d8 106 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/01/2020 0042 BNW 04/30/2020 1605 52485 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 10 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020E ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020E ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020E ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020E 3.7 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020E ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020E ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 Footnote(s): 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 36 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-011 Description: MW-12-25 Matrix: Aqueous Date Sampled:04/28/2020 1440 Date Received:04/29/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/01/2020 0201 JTH 52603 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 91 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/2020 0447 STM 52607 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 37 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-011 Description: MW-12-25 Matrix: Aqueous Date Sampled:04/28/2020 1440 Date Received:04/29/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/2020 0447 STM 52607 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 103 70-130 1,2-Dichloroethane-d4 102 70-130 Toluene-d8 108 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/01/2020 0048 BNW 04/30/2020 1605 52485 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020E ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020E 69 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020E ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020E ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020E 18 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 38 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-011 Description: MW-12-25 Matrix: Aqueous Date Sampled:04/28/2020 1440 Date Received:04/29/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/01/2020 0048 BNW 04/30/2020 1605 52485 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020E ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020E ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020E 11 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 39 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-012 Description: MW-13-35 Matrix: Aqueous Date Sampled:04/28/2020 1635 Date Received:04/29/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/01/2020 0225 JTH 52603 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 95 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/20201159 JM1 52686 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 1.8 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 7.2 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 5.0 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 23 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis -1,2-Dichloroethene 156-59-2 8260D 3.1 1.0 0.40 ug/L 1 trans -1,2-Dichloroethene 156-60-5 8260D 0.40 J 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 40 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-012 Description: MW-13-35 Matrix: Aqueous Date Sampled:04/28/2020 1635 Date Received:04/29/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/20201159 JM1 52686 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.64 J 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 102 70-130 Toluene-d8 105 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/01/2020 0054 BNW 04/30/2020 1605 52485 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020E ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020E 180 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020E ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020E 1.3 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020E 4.5 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 41 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-012 Description: MW-13-35 Matrix: Aqueous Date Sampled:04/28/2020 1635 Date Received:04/29/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/01/2020 0054 BNW 04/30/2020 1605 52485 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020E ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020E ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020E 3.1 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 42 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-013 Description: MW-13-132 Matrix: Aqueous Date Sampled:04/28/2020 1520 Date Received:04/29/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/01/2020 1422 KFE 52672 1 (BOD, 5 day) SM 5210B-2011 1 05/04/2020 2018 SJL 04/29/2020 2320 13319 1 (Chloride) 9056A 1 04/30/2020 1144 AMR 52644 1 (COD) SM 5220D-2011 1 05/10/2020 1440 HET 53424 1 (Nitrate - N) 9056A 1 04/30/2020 1144 AMR 52651 1 (Sulfate) 9056A 1 04/30/2020 1144 AMR 52640 1 (Sulfide) SM 4500-S2 F-2011 1 05/05/2020 2146 HET 52970 1 (TOC) SM 531 OC-2011 1 05/04/2020 1256 DMA 52797 Parameter CAS Analytical Number Method Result Q LOQ DL Units Run Alkalinity SM 23206- 150 20 20 mg/L 1 BOD, 5 day SM 52106- ND 7 2.0 0.18 mg/L 1 Chloride 9056A 4.8 1.0 0.20 mg/L 1 COD SM 5220D- ND 20 20 mg/L 1 Nitrate - N 9056A ND 0.020 0.0050 mg/L 1 Sulfate 9056A 8.2 1.0 0.20 mg/L 1 Sulfide 18496-25-8 SM 4500-S2 F- 1.1 1.0 0.99 mg/L 1 TOC SM 5310C- ND 1.0 1.0 mg/L 1 Volatile Oraanic Compounds by GC/MS (SIM Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/01/2020 0250 JTH 52603 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 94 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/20201222 JM1 52686 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 1.8 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 43 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-013 Description: MW-13-132 Matrix: Aqueous Date Sampled:04/28/2020 1520 Date Received:04/29/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/20201222 JM1 52686 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 1.2 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 1.2 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis -1,2-Dichloroethene 156-59-2 8260D 8.4 1.0 0.40 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 2.3 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 44 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-013 Description: MW-13-132 Matrix: Aqueous Date Sampled:04/28/2020 1520 Date Received:04/29/2020 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 104 70-130 1,2-Dichloroethane-d4 105 70-130 Toluene-d8 108 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/01/2020 0100 BNW 04/30/2020 1605 52485 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 40 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020E ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020E ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020E ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020E ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020E ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020E ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 2.9 J 10 2.5 ug/L 1 Footnote(s): 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 45 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-014 Description: MW-4A Matrix: Aqueous Date Sampled:04/29/2020 0915 Date Received:04/30/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/01/2020 1420 BWS 52646 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 15 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 88 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20201347 TML 53020 2 5030B 8260D 1 05/08/20201134 TML 53315 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 54 20 5.0 ug/L 2 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 5.9 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 140 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 16 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 6.7 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 56 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis -1,2-Dichloroethene 156-59-2 8260D 1.2 1.0 0.40 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260D 0.46 J 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 46 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-014 Description: MW-4A Matrix: Aqueous Date Sampled:04/29/2020 0915 Date Received:04/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20201347 TML 53020 2 5030B 8260D 1 05/08/20201134 TML 53315 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D 11 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D 32 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D 3.3 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L Vinyl chloride 75-01-4 8260D 1.2 1.0 0.40 ug/L Xylenes (total) 1330-20-7 8260D 19 1.0 0.40 ug/L Run 1 Acceptance Run 2 Acceptance Surrogate Q % Recovery Limits Q % Recovery Limits Bromofluorobenzene 102 70-130 101 70-130 1,2-Dichloroethane-d4 101 70-130 94 70-130 Toluene-d8 109 70-130 101 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/07/2020 0745 LLL 05/05/2020 1554 52779 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020E ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 840 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020E ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020E ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 56 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 3.5 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 47 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-014 Description: MW-4A Matrix: Aqueous Date Sampled:04/29/2020 0915 )ate Received:04/30/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/07/2020 0745 LLL 05/05/2020 1554 52779 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Lead 7439-92-1 6020E ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 12 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020E ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020E ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 2.8 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 48 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-015 Description: MW-17-60 Matrix: Aqueous Date Sampled:04/29/2020 1055 Date Received:04/30/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/01/2020 1445 BWS 52646 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 24 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 91 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20201414 TML 53020 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 1.3 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 1.2 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis -1,2-Dichloroethene 156-59-2 8260D 1.8 1.0 0.40 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 49 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-015 Description: MW-17-60 Matrix: Aqueous Date Sampled:04/29/2020 1055 Date Received:04/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20201414 TML 53020 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.78 J 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 101 70-130 1,2-Dichloroethane-d4 101 70-130 Toluene-d8 108 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/07/2020 0803 LLL 05/05/2020 1554 52779 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020E ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020E 24 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020E ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020E ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020E ND 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 50 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-015 Description: MW-17-60 Matrix: Aqueous Date Sampled:04/29/2020 1055 )ate Received:04/30/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/07/2020 0803 LLL 05/05/2020 1554 52779 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020E ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020E ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020E ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 51 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-016 Description: MW-17-137 Matrix: Aqueous Date Sampled:04/29/2020 1140 Date Received:04/30/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/01/2020 1509 BWS 52646 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 32 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 91 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20201442 TML 53020 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.49 J 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.73 J 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.80 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 52 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-016 Description: MW-17-137 Matrix: Aqueous Date Sampled:04/29/2020 1140 Date Received:04/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20201442 TML 53020 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.52 J 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 0.46 J 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 100 70-130 1,2-Dichloroethane-d4 101 70-130 Toluene-d8 107 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/07/2020 0808 LLL 05/05/2020 1554 52779 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020E ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020E 26 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020E ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020E ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020E ND 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 53 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-016 Description: MW-17-137 Matrix: Aqueous Date Sampled:04/29/2020 1140 )ate Received:04/30/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/07/2020 0808 LLL 05/05/2020 1554 52779 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020E ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020E ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020E ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 54 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-017 Description: MW-17-310 Matrix: Aqueous Date Sampled:04/29/2020 1255 Date Received:04/30/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/01/2020 1534 BWS 52646 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 92 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20201509 TML 53020 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 5.2 J 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 55 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-017 Description: MW-17-310 Matrix: Aqueous Date Sampled:04/29/2020 1255 Date Received:04/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20201509 TML 53020 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 101 70-130 Toluene-d8 106 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/07/2020 0814 LLL 05/05/2020 1554 52779 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020E ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020E 3.5 J 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020E ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020E ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.53 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020E ND 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 56 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-017 Description: MW-17-310 Matrix: Aqueous Date Sampled:04/29/2020 1255 )ate Received:04/30/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/07/2020 0814 LLL 05/05/2020 1554 52779 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020E ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020E ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020E 4.6 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 57 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-018 Description: Equip Bilk Matrix: Aqueous Date Sampled:04/29/2020 1400 Date Received:04/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/20201025 JM1 52686 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 58 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-018 Description: Equip Bilk Matrix: Aqueous Date Sampled:04/29/2020 1400 Date Received:04/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/20201025 JM1 52686 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 101 70-130 Toluene-d8 107 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/07/2020 0820 LLL 05/05/2020 1554 52779 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020E ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020E 4.5 J 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020E ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020E ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.6 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020E ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020E ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020E ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 59 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-019 Description: MW-2 Matrix: Aqueous Date Sampled:04/29/2020 1345 Date Received:04/30/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/01/2020 1428 KFE 52672 1 (BOD, 5 day) SM 5210B-2011 1 05/05/2020 1840 SJL 04/30/2020 2106 13321 1 (Chloride) 9056A 1 05/01/2020 1101 AMR 52727 1 (COD) SM 5220D-2011 1 05/10/2020 1441 HET 53424 1 (Nitrate - N) 9056A 1 05/01/2020 1101 AMR 52728 1 (Sulfate) 9056A 1 05/01/2020 1101 AMR 52726 1 (Sulfide) SM 4500-S2 F-2011 1 05/05/2020 2146 HET 52970 1 (TOC) SM 531 OC-2011 1 05/04/2020 1309 DMA 52797 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity SM 23206- 61 20 20 mg/L 1 BOD, 5 day SM 52106- ND 7 2.0 0.18 mg/L 1 Chloride 9056A 2.1 1.0 0.20 mg/L 1 COD SM 5220D- ND 20 20 mg/L 1 Nitrate - N 9056A 0.014 J 0.020 0.0050 mg/L 1 Sulfate 9056A 2.9 1.0 0.20 mg/L 1 Sulfide 18496-25-8 SM 4500-S2 F- ND 1.0 0.99 mg/L 1 TOC SM 5310C- ND 1.0 1.0 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/01/2020 1558 BWS 52646 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 93 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20201535 TML 53020 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 60 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-019 Description: MW-2 Matrix: Aqueous Date Sampled:04/29/2020 1345 Date Received:04/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/20201535 TML 53020 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 61 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-019 Description: MW-2 Matrix: Aqueous Date Sampled:04/29/2020 1345 Date Received:04/30/2020 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 100 70-130 1,2-Dichloroethane-d4 102 70-130 Toluene-d8 107 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/07/2020 0826 LLL 05/05/2020 1554 52779 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 23 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020E ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020E ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 2.1 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020E 0.63 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 2.9 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020E ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020E ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 5.0 J 10 2.5 ug/L 1 Footnote(s): 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 62 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-020 Description: MW-7 Matrix: Aqueous Date Sampled:04/29/2020 1605 Date Received:04/30/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/01/2020 1623 BWS 52646 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 91 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/05/2020 2310 ALR1 52963 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 5.1 J 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 1.5 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 7.4 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 2.4 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 3.4 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 3.2 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis -1,2-Dichloroethene 156-59-2 8260D 19 1.0 0.40 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 63 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-020 Description: MW-7 Matrix: Aqueous Date Sampled:04/29/2020 1605 Date Received:04/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/05/2020 2310 ALR1 52963 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D 0.81 J 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 0.42 J 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 118 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 119 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/07/2020 0832 LLL 05/05/2020 1554 52779 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020E ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020E 220 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.19 J 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.20 J 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020E ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020E 200 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 11 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020E 70 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 64 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-020 Description: MW-7 Matrix: Aqueous Date Sampled:04/29/2020 1605 )ate Received:04/30/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/07/2020 0832 LLL 05/05/2020 1554 52779 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020E ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020E ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020E 17 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 65 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-021 Description: MW-B Matrix: Aqueous Date Sampled:04/29/2020 1305 Date Received:04/30/2020 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/01/2020 1647 BWS 52646 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 34 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 92 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/05/2020 2337 ALR1 52963 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 2.2 J 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 1.1 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.65 J 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 1.9 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 1.7 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis -1,2-Dichloroethene 156-59-2 8260D 23 1.0 0.40 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 66 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-021 Description: MW-B Matrix: Aqueous Date Sampled:04/29/2020 1305 Date Received:04/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/05/2020 2337 ALR1 52963 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 7.7 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 112 70-130 1,2-Dichloroethane-d4 103 70-130 Toluene-d8 114 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/07/2020 0838 LLL 05/05/2020 1554 52779 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020E ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020E 180 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020E ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020E ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020E 1.3 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 67 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-021 Description: MW-B Matrix: Aqueous Date Sampled:04/29/2020 1305 )ate Received:04/30/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/07/2020 0838 LLL 05/05/2020 1554 52779 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020E ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020E ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020E ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 68 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-022 Description: MW-21-21 Matrix: Aqueous Date Sampled:04/29/2020 1045 Date Received:04/30/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/01/2020 1438 KFE 52672 1 (BOD, 5 day) SM 5210B-2011 1 05/05/2020 1840 SJL 04/30/2020 2106 13321 1 (Chloride) 9056A 1 05/01/2020 0912 AMR 52727 1 (COD) SM 5220D-2011 1 05/10/2020 1441 HET 53424 2 (Nitrate - N) 9056A 5 05/07/2020 1119 HKL 53190 1 (Sulfate) 9056A 1 05/01/2020 0912 AMR 52726 1 (Sulfide) SM 4500-S2 F-2011 1 05/05/2020 2146 HET 52970 1 (TOC) SM 531 OC-2011 1 05/04/2020 1349 DMA 52797 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity SM 23206- 680 20 20 mg/L 1 BOD, 5 day SM 52106- 3.1 7 2.0 0.18 mg/L 1 Chloride 9056A 50 1.0 0.20 mg/L 1 COD SM 5220D- 33 20 20 mg/L 1 Nitrate - N 9056A ND H 0.10 0.025 mg/L 2 Sulfate 9056A 38 1.0 0.20 mg/L 1 Sulfide 18496-25-8 SM 4500-S2 F- ND 1.0 0.99 mg/L 1 TOC SM 5310C- 12 1.0 1.0 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/01/2020 1712 BWS 52646 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 18 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 93 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/2020 0004 ALR1 52963 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 2.1 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 69 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-022 Description: MW-21-21 Matrix: Aqueous Date Sampled:04/29/2020 1045 Date Received:04/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/2020 0004 ALR1 52963 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 18 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 3.1 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 9.7 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 2.9 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis -1,2-Dichloroethene 156-59-2 8260D 6.5 1.0 0.40 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D 0.43 J 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 1.6 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 70 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-022 Description: MW-21-21 Matrix: Aqueous Date Sampled:04/29/2020 1045 Date Received:04/30/2020 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 113 70-130 1,2-Dichloroethane-d4 105 70-130 Toluene-d8 114 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/07/2020 0843 LLL 05/05/2020 1554 52779 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 120 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020E ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020E ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 13 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020E ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020E 3.5 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020E ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020E ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 Footnote(s): 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 71 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-023 Description: MW-21-94 Matrix: Aqueous Date Sampled:04/29/2020 0950 Date Received:04/30/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/01/2020 1445 KFE 52672 1 (BOD, 5 day) SM 5210B-2011 1 05/05/2020 1840 SJL 04/30/2020 2106 13321 1 (Chloride) 9056A 1 05/01/2020 0850 AMR 52727 1 (COD) SM 5220D-2011 1 05/10/2020 1441 HET 53424 1 (Nitrate - N) 9056A 1 05/01/2020 0850 AMR 52728 1 (Sulfate) 9056A 1 05/01/2020 0850 AMR 52726 1 (Sulfide) SM 4500-S2 F-2011 1 05/05/2020 2146 HET 52970 1 (TOC) SM 531 OC-2011 1 05/04/2020 1402 DMA 52797 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity SM 23206- 320 20 20 mg/L 1 BOD, 5 day SM 52106- 2.2 7 2.0 0.18 mg/L 1 Chloride 9056A 99 1.0 0.20 mg/L 1 COD SM 5220D- 20 20 20 mg/L 1 Nitrate - N 9056A ND 0.020 0.0050 mg/L 1 Sulfate 9056A 2.2 1.0 0.20 mg/L 1 Sulfide 18496-25-8 SM 4500-S2 F- ND 1.0 0.99 mg/L 1 TOC SM 5310C- 7.3 1.0 1.0 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/01/2020 1736 BWS 52646 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 48 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 94 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/2020 0031 ALR1 52963 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 72 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-023 Description: MW-21-94 Matrix: Aqueous Date Sampled:04/29/2020 0950 Date Received:04/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/2020 0031 ALR1 52963 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 1.5 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 2.8 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 2.7 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.81 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.47 J 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis -1,2-Dichloroethene 156-59-2 8260D 2.5 1.0 0.40 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.92 J 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 73 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-023 Description: MW-21-94 Matrix: Aqueous Date Sampled:04/29/2020 0950 Date Received:04/30/2020 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 114 70-130 1,2-Dichloroethane-d4 105 70-130 Toluene-d8 115 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/07/2020 0849 LLL 05/05/2020 1554 52779 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 53 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020E ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020E ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020E ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020E 8.5 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020E ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020E ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 Footnote(s): 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 74 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-025 Description: MW-24-160 Matrix: Aqueous Date Sampled:04/29/2020 1125 Date Received:04/30/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/01/2020 1506 KFE 52672 1 (BOD, 5 day) SM 5210B-2011 1 05/05/2020 1840 SJL 04/30/2020 2106 13321 1 (Chloride) 9056A 1 05/01/2020 1038 AMR 52727 1 (COD) SM 5220D-2011 1 05/10/2020 1441 HET 53424 1 (Nitrate - N) 9056A 1 05/01/2020 1038 AMR 52728 1 (Sulfate) 9056A 1 05/01/2020 1038 AMR 52726 1 (Sulfide) SM 4500-S2 F-2011 1 05/05/2020 2146 HET 52970 1 (TOC) SM 531 OC-2011 1 05/04/2020 1442 DMA 52797 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity SM 23206- 60 20 20 mg/L 1 BOD, 5 day SM 52106- 5.8 7 2.0 0.18 mg/L 1 Chloride 9056A 7.4 1.0 0.20 mg/L 1 COD SM 5220D- ND 20 20 mg/L 1 Nitrate - N 9056A ND 0.020 0.0050 mg/L 1 Sulfate 9056A 23 1.0 0.20 mg/L 1 Sulfide 18496-25-8 SM 4500-S2 F- ND 1.0 0.99 mg/L 1 TOC SM 5310C- 2.6 1.0 1.0 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/01/2020 1801 BWS 52646 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 93 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/2020 0058 ALR1 52963 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 75 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-025 Description: MW-24-160 Matrix: Aqueous Date Sampled:04/29/2020 1125 Date Received:04/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/06/2020 0058 ALR1 52963 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 76 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-025 Description: MW-24-160 Matrix: Aqueous Date Sampled:04/29/2020 1125 Date Received:04/30/2020 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 110 70-130 1,2-Dichloroethane-d4 106 70-130 Toluene-d8 114 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 05/07/2020 0855 LLL 05/05/2020 1554 52779 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 18 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020E ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020E ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 4.3 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020E 1.0 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 1.9 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020E ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020E ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 7.8 J 10 2.5 ug/L 1 Footnote(s): 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 77 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-026 Description: Trip Bilk Matrix: Aqueous Date Sampled:04/29/2020 Date Received:04/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/20201049 JM1 52686 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans-1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans-1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis-1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans-1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 78 of 191 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:VD29085-026 Description: Trip Bilk Matrix: Aqueous Date Sampled:04/29/2020 )ate Received:04/30/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/01/20201049 JM1 52686 Parameter CAS Number Analytical Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 99 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 106 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 79 of 191 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 80 of 191 Inorganic non-metals - MB Sample ID: VQ52640-001 Matrix: Aqueous Batch:52640 Analvtical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Sulfate ND 1 1.0 0.20 mg/L 04/30/2020 0755 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 81 of 191 Inorganic non-metals - LCS Sample ID: VQ52640-002 Matrix: Aqueous Batch:52640 Analvtical Method: 9056A Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 20 20 1 99 80-120 04/30/2020 0841 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 82 of 191 Inorganic non-metals - MS Sample ID: VD29085-009MS Matrix: Aqueous Batch:52640 Analvtical Method: 9056A Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 12 20 31 1 95 80-120 04/30/20201058 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 83 of 191 Inorganic non-metals - MSD Sample ID: VD29085-009MD Matrix: Aqueous Batch:52640 Analvtical Method: 9056A Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Sulfate 12 20 30 1 91 2.6 80-120 20 04/30/20201121 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 84 of 191 Inorganic non-metals - MB Sample ID: VQ52644-001 Matrix: Aqueous Batch:52644 Analvtical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Chloride ND 1 1.0 0.20 mg/L 04/30/2020 0755 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 85 of 191 Inorganic non-metals - LCS Sample ID: VQ52644-002 Matrix: Aqueous Batch:52644 Analvtical Method: 9056A Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Chloride 20 20 1 102 80-120 04/30/2020 0841 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 86 of 191 Inorganic non-metals - MS Sample ID: VD29085-009MS Matrix: Aqueous Batch:52644 Analvtical Method: 9056A Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Chloride 38 20 57 1 95 80-120 04/30/20201058 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 87 of 191 Inorganic non-metals - MSD Sample ID: VD29085-009MD Matrix: Aqueous Batch:52644 Analvtical Method: 9056A Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Chloride 38 20 57 1 91 1.4 80-120 20 04/30/20201121 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 88 of 191 Inorganic non-metals - MB Sample ID: VQ52651-001 Matrix: Aqueous Batch:52651 Analvtical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Nitrate - N ND 1 0.020 0.0050 mg/L 04/30/2020 0755 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 89 of 191 Inorganic non-metals - LCS Sample ID: VQ52651-002 Matrix: Aqueous Batch:52651 Analvtical Method: 9056A Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Nitrate - N 0.80 0.75 1 94 80-120 04/30/2020 0841 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 90 of 191 Inorganic non-metals - MS Sample ID: VD29085-009MS Matrix: Aqueous Batch:52651 Analvtical Method: 9056A Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Nitrate - N ND 0.80 0.72 1 90 80-120 04/30/2020 1058 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 91 of 191 Inorganic non-metals - MSD Sample ID: VD29085-009MD Matrix: Aqueous Batch:52651 Analvtical Method: 9056A Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Nitrate - N ND 0.80 0.69 1 86 4.3 80-120 20 04/30/2020 1121 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 92 of 191 Inorganic non-metals - MB Sample ID: VQ52672-001 Matrix: Aqueous Batch:52672 Analvtical Method: SM 2320B-2011 Parameter Result Q Dil LOQ DL Units Analysis Date Alkalinity ND 1 20 20 mg/L 05/01/20201214 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 93 of 191 Inorganic non-metals - LCS Sample ID: VQ52672-002 Matrix: Aqueous Batch:52672 Analvtical Method: SM 2320B-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 100 100 1 100 90-110 05/01/20201231 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 94 of 191 Inorganic non-metals - MB Sample ID: VQ52726-001 Matrix: Aqueous Batch:52726 Analvtical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Sulfate ND 1 1.0 0.20 mg/L 05/01/2020 0741 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 95 of 191 Inorganic non-metals - LCS Sample ID: VQ52726-002 Matrix: Aqueous Batch:52726 Analvtical Method: 9056A Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 20 20 1 100 80-120 05/01/2020 0827 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 96 of 191 Inorganic non-metals - MS Sample ID: VD29085-019MS Matrix: Aqueous Batch:52726 Analvtical Method: 9056A Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 2.9 20 22 1 93 80-120 05/01/20201124 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 97 of 191 Inorganic non-metals - MSD Sample ID: VD29085-019MD Matrix: Aqueous Batch:52726 Analvtical Method: 9056A Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Sulfate 2.9 20 22 1 94 0.46 80-120 20 05/01/20201147 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 98 of 191 Inorganic non-metals - MB Sample ID: VQ52727-001 Matrix: Aqueous Batch:52727 Analvtical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Chloride ND 1 1.0 0.20 mg/L 05/01/2020 0741 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 99 of 191 Inorganic non-metals - LCS Sample ID: VQ52727-002 Matrix: Aqueous Batch:52727 Analvtical Method: 9056A Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Chloride 20 20 1 102 80-120 05/01/2020 0827 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 100 of 191 Inorganic non-metals - MS Sample ID: VD29085-019MS Matrix: Aqueous Batch:52727 Analvtical Method: 9056A Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Chloride 2.1 20 21 1 96 80-120 05/01/20201124 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 101 of 191 Inorganic non-metals - MSD Sample ID: VD29085-019MD Matrix: Aqueous Batch:52727 Analvtical Method: 9056A Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Chloride 2.1 20 21 1 96 0.47 80-120 20 05/01/20201147 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 102 of 191 Inorganic non-metals - MB Sample ID: VQ52728-001 Matrix: Aqueous Batch:52728 Analvtical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Nitrate - N ND 1 0.020 0.0050 mg/L 05/01/2020 0741 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 103 of 191 Inorganic non-metals - LCS Sample ID: VQ52728-002 Matrix: Aqueous Batch:52728 Analvtical Method: 9056A Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Nitrate - N 0.80 0.74 1 93 80-120 05/01/2020 0827 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 104 of 191 Inorganic non-metals - MS Sample ID: VD29085-019MS Matrix: Aqueous Batch:52728 Analvtical Method: 9056A Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Nitrate - N 0.014 0.80 0.72 1 88 80-120 05/01/2020 1124 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 105 of 191 Inorganic non-metals - MSD Sample ID: VD29085-019MD Matrix: Aqueous Batch:52728 Analvtical Method: 9056A Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Nitrate - N 0.014 0.80 0.73 1 89 1.4 80-120 20 05/01/2020 1147 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 106 of 191 Inorganic non-metals - MB Sample ID: VQ52797-001 Matrix: Aqueous Batch:52797 Analvtical Method: SM 531OC-2011 Parameter Result Q Dil LOQ DL Units Analysis Date TOC ND 1 1.0 1.0 mg/L 05/04/20201125 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 107 of 191 Inorganic non-metals - LCS Sample ID: VQ52797-002 Matrix: Aqueous Batch:52797 Analvtical Method: SM 531OC-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date TOC 20 19 1 94 90-110 05/04/20201138 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 108 of 191 Inorganic non-metals - MS Sample ID: VD29085-023MS Matrix: Aqueous Batch:52797 Analvtical Method: SM 531OC-2011 Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date TOC 7.3 20 27 1 97 70-130 05/04/20201415 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 109 of 191 Inorganic non-metals - MSD Sample ID: VD29085-023MD Matrix: Aqueous Batch:52797 Analvtical Method: SM 531OC-2011 Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date TOC 7.3 20 27 1 97 0.15 70-130 20 05/04/20201428 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 110 of 191 Inorganic non-metals - MB Sample ID: VQ52970-001 Matrix: Aqueous Batch:52970 Analvtical Method: SM 4500-S2 F-2011 Parameter Result Q Dil LOQ DL Units Analysis Date Sulfide ND 1 1.0 0.99 mg/L 05/05/2020 2146 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 111 of 191 Inorganic non-metals - LCS Sample ID: VQ52970-002 Matrix: Aqueous Batch:52970 Analvtical Method: SM 4500-S2 F-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfide 10 10 1 101 80-120 05/05/2020 2146 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 112 of 191 Inorganic non-metals - MB Sample ID: VQ53190-001 Matrix: Aqueous Batch:53190 Analvtical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Nitrate - N ND 1 0.020 0.0050 mg/L 05/07/2020 0147 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 113 of 191 Inorganic non-metals - LCS Sample ID: VQ53190-002 Matrix: Aqueous Batch:53190 Analvtical Method: 9056A Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Nitrate - N 0.80 0.77 1 96 80-120 05/07/2020 0101 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 114 of 191 Inorganic non-metals - MB Sample ID: VQ53424-001 Matrix: Aqueous Batch:53424 Analvtical Method: SM 5220D-2011 Parameter Result Q Dil LOQ DL Units Analysis Date COD ND 1 20 20 mg/L 05/10/20201437 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 115 of 191 Inorganic non-metals - LCS Sample ID: VQ53424-002 Matrix: Aqueous Batch:53424 Analvtical Method: SM 5220D-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date COD 40 42 1 104 95-105 05/10/20201437 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 116 of 191 Inorganic non-metals - MS Sample ID: VD29085-013MS Matrix: Aqueous Batch:53424 Analvtical Method: SM 5220D-2011 Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date COD ND 40 38 1 94 90-110 05/10/20201440 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 117 of 191 Inorganic non-metals - MSD Sample ID: VD29085-013MD Matrix: Aqueous Batch:53424 Analvtical Method: SM 5220D-2011 Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date COD ND 40 37 1 94 0.85 90-110 20 05/10/20201440 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 118 of 191 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: VQ52603-001 Matrix: Aqueous Batch:52603 Prep Method: 5030B Analvtical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 04/30/2020 2110 Surrogate 1,2-Dich loroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection Acceptance Q % Rec Limit 96 40-170 P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 119 of 191 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: VQ52603-002 Matrix: Aqueous Batch:52603 Prep Method: 5030B Analvtical Method: 8260D (SIM) Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 52 1 104 70-130 04/30/2020 2009 Acceptance Surrogate Q % Rec Limit 1,2-Dich loroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection 113 40-170 P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 120 of 191 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ52607-001 Matrix: Aqueous Batch: 52607 Prep Method: 5030B Analvtical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 04/30/2020 2155 Acrylonitrile ND 1 20 0.80 ug/L 04/30/2020 2155 Benzene ND 1 1.0 0.40 ug/L 04/30/2020 2155 Bromochloromethane ND 1 1.0 0.40 ug/L 04/30/2020 2155 Bromodichloromethane ND 1 1.0 0.40 ug/L 04/30/2020 2155 Bromoform ND 1 1.0 0.40 ug/L 04/30/2020 2155 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 04/30/2020 2155 2-Butanone (MEK) ND 1 10 2.0 ug/L 04/30/2020 2155 Carbon disulfide ND 1 1.0 0.40 ug/L 04/30/2020 2155 Carbon tetrachloride ND 1 1.0 0.40 ug/L 04/30/2020 2155 Chlorobenzene ND 1 1.0 0.40 ug/L 04/30/2020 2155 Chloroethane ND 1 2.0 0.40 ug/L 04/30/2020 2155 Chloroform ND 1 1.0 0.40 ug/L 04/30/2020 2155 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 04/30/2020 2155 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 04/30/2020 2155 Dibromochloromethane ND 1 1.0 0.40 ug/L 04/30/2020 2155 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 04/30/2020 2155 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 04/30/2020 2155 trans-1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 04/30/2020 2155 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 04/30/2020 2155 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 04/30/2020 2155 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 04/30/2020 2155 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 04/30/2020 2155 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 04/30/2020 2155 cis-1,2-Dichloroethene ND 1 1.0 0.40 ug/L 04/30/2020 2155 trans-1,2-Dichloroethene ND 1 1.0 0.40 ug/L 04/30/2020 2155 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 04/30/2020 2155 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 04/30/2020 2155 trans-1,3-Dichloropropene ND 1 1.0 0.40 ug/L 04/30/2020 2155 Ethylbenzene ND 1 1.0 0.40 ug/L 04/30/2020 2155 2-Hexanone ND 1 10 2.0 ug/L 04/30/2020 2155 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 04/30/2020 2155 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 04/30/2020 2155 Methylene chloride ND 1 1.0 0.40 ug/L 04/30/2020 2155 Styrene ND 1 1.0 0.41 ug/L 04/30/2020 2155 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 04/30/2020 2155 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 04/30/2020 2155 Tetrachloroethene ND 1 1.0 0.40 ug/L 04/30/2020 2155 Toluene ND 1 1.0 0.40 ug/L 04/30/2020 2155 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 04/30/2020 2155 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 04/30/2020 2155 Trichloroethene ND 1 1.0 0.40 ug/L 04/30/2020 2155 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 04/30/2020 2155 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 04/30/2020 2155 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 121 of 191 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ52607-001 Matrix: Aqueous Batch:52607 Prep Method: 5030B Analvtical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 04/30/2020 2155 Vinyl chloride ND 1 1.0 0.40 ug/L 04/30/2020 2155 Xylenes (total) ND 1 1.0 0.40 ug/L 04/30/2020 2155 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 102 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 106 70-130 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 122 of 191 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ52607-002 Matrix: Aqueous Batch:52607 Prep Method: 5030B Analvtical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 130 1 125 60-140 04/30/2020 2056 Acrylonitrile 100 94 1 94 70-130 04/30/2020 2056 Benzene 50 50 1 99 70-130 04/30/2020 2056 Bromochloromethane 50 45 1 90 70-130 04/30/2020 2056 Bromodichloromethane 50 48 1 97 70-130 04/30/2020 2056 Bromoform 50 42 1 84 70-130 04/30/2020 2056 Bromomethane (Methyl bromide) 50 46 1 92 70-130 04/30/2020 2056 2-Butanone (MEK) 100 110 1 106 70-130 04/30/2020 2056 Carbon disulfide 50 53 1 105 70-130 04/30/2020 2056 Carbon tetrachloride 50 43 1 87 70-130 04/30/2020 2056 Chlorobenzene 50 49 1 99 70-130 04/30/2020 2056 Chloroethane 50 46 1 93 70-130 04/30/2020 2056 Chloroform 50 46 1 91 70-130 04/30/2020 2056 Chloromethane (Methyl chloride) 50 44 1 88 60-140 04/30/2020 2056 1,2-Dibromo-3-chloropropane (DBCP) 50 44 1 88 70-130 04/30/2020 2056 Dibromochloromethane 50 50 1 100 70-130 04/30/2020 2056 1,2-Dibromoethane (EDB) 50 48 1 95 70-130 04/30/2020 2056 Dibromomethane (Methylene bromide) 50 46 1 91 70-130 04/30/2020 2056 trans-1,4-Dichloro-2-butene 50 48 1 97 70-130 04/30/2020 2056 1,2-Dichlorobenzene 50 47 1 94 70-130 04/30/2020 2056 1,4-Dichlorobenzene 50 49 1 97 70-130 04/30/2020 2056 1,1-Dichloroethane 50 47 1 95 70-130 04/30/2020 2056 1,2-Dichloroethane 50 47 1 93 70-130 04/30/2020 2056 1,1-Dichloroethene 50 52 1 104 70-130 04/30/2020 2056 cis-1,2-Dichloroethene 50 47 1 94 70-130 04/30/2020 2056 trans-1,2-Dichloroethene 50 47 1 95 70-130 04/30/2020 2056 1,2-Dichloropropane 50 50 1 99 70-130 04/30/2020 2056 cis- 1,3-Dichloropropene 50 50 1 101 70-130 04/30/2020 2056 trans-1,3-Dichloropropene 50 52 1 104 70-130 04/30/2020 2056 Ethylbenzene 50 52 1 104 70-130 04/30/2020 2056 2-Hexanone 100 94 1 94 70-130 04/30/2020 2056 Methyl iodide (lodomethane) 50 48 1 97 70-130 04/30/2020 2056 4-Methyl-2-pentanone 100 100 1 104 70-130 04/30/2020 2056 Methylene chloride 50 46 1 93 70-130 04/30/2020 2056 Styrene 50 50 1 100 70-130 04/30/2020 2056 1,1,1,2-Tetrachloroethane 50 51 1 101 70-130 04/30/2020 2056 1,1,2,2-Tetrachloroethane 50 48 1 96 70-130 04/30/2020 2056 Tetrachloroethene 50 52 1 104 70-130 04/30/2020 2056 Toluene 50 52 1 103 70-130 04/30/2020 2056 1,1,1-Trichloroethane 50 49 1 98 70-130 04/30/2020 2056 1,1,2-Trichloroethane 50 48 1 95 70-130 04/30/2020 2056 Trichloroethene 50 49 1 98 70-130 04/30/2020 2056 Trichlorofluoromethane 50 44 1 88 70-130 04/30/2020 2056 1,2,3-Trichloropropane 50 50 1 101 70-130 04/30/2020 2056 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 123 of 191 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ52607-002 Matrix: Aqueous Batch:52607 Prep Method: 5030B Analvtical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 42 1 85 60-140 04/30/2020 2056 Vinyl chloride 50 47 1 95 70-130 04/30/2020 2056 Xylenes (total) 100 100 1 102 70-130 04/30/2020 2056 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 90 70-130 1,2-Dichloroethane-d4 87 70-130 Toluene-d8 91 70-130 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 124 of 191 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: VQ52646-001 Matrix: Aqueous Batch:52646 Prep Method: 5030B Analvtical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 05/01/2020 0940 Surrogate 1,2-Dich loroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection Acceptance Q % Rec Limit 94 40-170 P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 125 of 191 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: VQ52646-002 Matrix: Aqueous Batch:52646 Prep Method: 5030B Analvtical Method: 8260D (SIM) Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 54 1 109 70-130 05/01/2020 0841 Surrogate 1,2-Dich loroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection Acceptance Q % Rec Limit 115 40-170 P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 126 of 191 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ52686-001 Matrix: Aqueous Batch: 52686 Prep Method: 5030B Analvtical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 05/01/2020 0916 Acrylonitrile ND 1 20 0.80 ug/L 05/01/2020 0916 Benzene ND 1 1.0 0.40 ug/L 05/01/2020 0916 Bromochloromethane ND 1 1.0 0.40 ug/L 05/01/2020 0916 Bromodichloromethane ND 1 1.0 0.40 ug/L 05/01/2020 0916 Bromoform ND 1 1.0 0.40 ug/L 05/01/2020 0916 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 05/01/2020 0916 2-Butanone (MEK) ND 1 10 2.0 ug/L 05/01/2020 0916 Carbon disulfide ND 1 1.0 0.40 ug/L 05/01/2020 0916 Carbon tetrachloride ND 1 1.0 0.40 ug/L 05/01/2020 0916 Chlorobenzene ND 1 1.0 0.40 ug/L 05/01/2020 0916 Chloroethane ND 1 2.0 0.40 ug/L 05/01/2020 0916 Chloroform ND 1 1.0 0.40 ug/L 05/01/2020 0916 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 05/01/2020 0916 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 05/01/2020 0916 Dibromochloromethane ND 1 1.0 0.40 ug/L 05/01/2020 0916 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 05/01/2020 0916 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 05/01/2020 0916 trans-1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 05/01/2020 0916 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/01/2020 0916 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/01/2020 0916 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 05/01/2020 0916 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 05/01/2020 0916 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 05/01/2020 0916 cis-1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/01/2020 0916 trans-1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/01/2020 0916 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 05/01/2020 0916 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/01/2020 0916 trans-1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/01/2020 0916 Ethylbenzene ND 1 1.0 0.40 ug/L 05/01/2020 0916 2-Hexanone ND 1 10 2.0 ug/L 05/01/2020 0916 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 05/01/2020 0916 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 05/01/2020 0916 Methylene chloride ND 1 1.0 0.40 ug/L 05/01/2020 0916 Styrene ND 1 1.0 0.41 ug/L 05/01/2020 0916 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/01/2020 0916 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/01/2020 0916 Tetrachloroethene ND 1 1.0 0.40 ug/L 05/01/2020 0916 Toluene ND 1 1.0 0.40 ug/L 05/01/2020 0916 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 05/01/2020 0916 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 05/01/2020 0916 Trichloroethene ND 1 1.0 0.40 ug/L 05/01/2020 0916 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 05/01/2020 0916 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 05/01/2020 0916 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 127 of 191 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ52686-001 Matrix: Aqueous Batch:52686 Prep Method: 5030B Analvtical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 05/01/2020 0916 Vinyl chloride ND 1 1.0 0.40 ug/L 05/01/2020 0916 Xylenes (total) ND 1 1.0 0.40 ug/L 05/01/2020 0916 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 102 70-130 Toluene-d8 104 70-130 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 128 of 191 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ52686-002 Matrix: Aqueous Batch:52686 Prep Method: 5030B Analvtical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 110 1 114 60-140 05/01/2020 0807 Acrylonitrile 100 100 1 101 70-130 05/01/2020 0807 Benzene 50 52 1 105 70-130 05/01/2020 0807 Bromochloromethane 50 49 1 98 70-130 05/01/2020 0807 Bromodichloromethane 50 51 1 102 70-130 05/01/2020 0807 Bromoform 50 43 1 87 70-130 05/01/2020 0807 Bromomethane (Methyl bromide) 50 48 1 95 70-130 05/01/2020 0807 2-Butanone (MEK) 100 110 1 106 70-130 05/01/2020 0807 Carbon disulfide 50 56 1 111 70-130 05/01/2020 0807 Carbon tetrachloride 50 44 1 88 70-130 05/01/2020 0807 Chlorobenzene 50 53 1 105 70-130 05/01/2020 0807 Chloroethane 50 49 1 98 70-130 05/01/2020 0807 Chloroform 50 49 1 97 70-130 05/01/2020 0807 Chloromethane (Methyl chloride) 50 45 1 89 60-140 05/01/2020 0807 1,2-Dibromo-3-chloropropane (DBCP) 50 46 1 92 70-130 05/01/2020 0807 Dibromochloromethane 50 53 1 105 70-130 05/01/2020 0807 1,2-Dibromoethane (EDB) 50 52 1 103 70-130 05/01/2020 0807 Dibromomethane (Methylene bromide) 50 50 1 99 70-130 05/01/2020 0807 trans-1,4-Dichloro-2-butene 50 50 1 100 70-130 05/01/2020 0807 1,2-Dichlorobenzene 50 52 1 103 70-130 05/01/2020 0807 1,4-Dichlorobenzene 50 52 1 105 70-130 05/01/2020 0807 1,1-Dichloroethane 50 51 1 101 70-130 05/01/2020 0807 1,2-Dichloroethane 50 50 1 100 70-130 05/01/2020 0807 1,1-Dichloroethene 50 53 1 107 70-130 05/01/2020 0807 cis-1,2-Dichloroethene 50 50 1 100 70-130 05/01/2020 0807 trans-1,2-Dichloroethene 50 49 1 99 70-130 05/01/2020 0807 1,2-Dichloropropane 50 53 1 106 70-130 05/01/2020 0807 cis- 1,3-Dichloropropene 50 54 1 108 70-130 05/01/2020 0807 trans-1,3-Dichloropropene 50 56 1 111 70-130 05/01/2020 0807 Ethylbenzene 50 55 1 109 70-130 05/01/2020 0807 2-Hexanone 100 100 1 100 70-130 05/01/2020 0807 Methyl iodide (lodomethane) 50 52 1 105 70-130 05/01/2020 0807 4-Methyl-2-pentanone 100 110 1 110 70-130 05/01/2020 0807 Methylene chloride 50 51 1 102 70-130 05/01/2020 0807 Styrene 50 53 1 106 70-130 05/01/2020 0807 1,1,1,2-Tetrachloroethane 50 54 1 108 70-130 05/01/2020 0807 1,1,2,2-Tetrachloroethane 50 53 1 106 70-130 05/01/2020 0807 Tetrachloroethene 50 53 1 105 70-130 05/01/2020 0807 Toluene 50 54 1 108 70-130 05/01/2020 0807 1,1,1-Trichloroethane 50 51 1 103 70-130 05/01/2020 0807 1,1,2-Trichloroethane 50 52 1 103 70-130 05/01/2020 0807 Trichloroethene 50 51 1 103 70-130 05/01/2020 0807 Trichlorofluoromethane 50 42 1 83 70-130 05/01/2020 0807 1,2,3-Trichloropropane 50 54 1 109 70-130 05/01/2020 0807 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 129 of 191 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ52686-002 Matrix: Aqueous Batch:52686 Prep Method: 5030B Analvtical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 46 1 92 60-140 05/01/2020 0807 Vinyl chloride 50 46 1 92 70-130 05/01/2020 0807 Xylenes (total) 100 110 1 107 70-130 05/01/2020 0807 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 96 70-130 Toluene-d8 97 70-130 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 130 of 191 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: VQ52884-001 Matrix: Aqueous Batch:52884 Prep Method: 5030B Analvtical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 05/05/20201013 Surrogate 1,2-Dich loroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection Acceptance Q % Rec Limit 98 40-170 P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 131 of 191 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: VQ52884-002 Matrix: Aqueous Batch:52884 Prep Method: 5030B Analvtical Method: 8260D (SIM) Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 47 1 94 70-130 05/05/2020 0910 Surrogate 1,2-Dich loroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection Acceptance Q % Rec Limit 112 40-170 P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 132 of 191 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ52963-001 Matrix: Aqueous Batch: 52963 Prep Method: 5030B Analvtical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 05/05/2020 2200 Acrylonitrile ND 1 20 0.80 ug/L 05/05/2020 2200 Benzene ND 1 1.0 0.40 ug/L 05/05/2020 2200 Bromochloromethane ND 1 1.0 0.40 ug/L 05/05/2020 2200 Bromodichloromethane ND 1 1.0 0.40 ug/L 05/05/2020 2200 Bromoform ND 1 1.0 0.40 ug/L 05/05/2020 2200 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 05/05/2020 2200 2-Butanone (MEK) ND 1 10 2.0 ug/L 05/05/2020 2200 Carbon disulfide ND 1 1.0 0.40 ug/L 05/05/2020 2200 Carbon tetrachloride ND 1 1.0 0.40 ug/L 05/05/2020 2200 Chlorobenzene ND 1 1.0 0.40 ug/L 05/05/2020 2200 Chloroethane ND 1 2.0 0.40 ug/L 05/05/2020 2200 Chloroform ND 1 1.0 0.40 ug/L 05/05/2020 2200 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 05/05/2020 2200 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 05/05/2020 2200 Dibromochloromethane ND 1 1.0 0.40 ug/L 05/05/2020 2200 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 05/05/2020 2200 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 05/05/2020 2200 trans-1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 05/05/2020 2200 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/05/2020 2200 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/05/2020 2200 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 05/05/2020 2200 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 05/05/2020 2200 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 05/05/2020 2200 cis-1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/05/2020 2200 trans-1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/05/2020 2200 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 05/05/2020 2200 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/05/2020 2200 trans-1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/05/2020 2200 Ethylbenzene ND 1 1.0 0.40 ug/L 05/05/2020 2200 2-Hexanone ND 1 10 2.0 ug/L 05/05/2020 2200 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 05/05/2020 2200 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 05/05/2020 2200 Methylene chloride ND 1 1.0 0.40 ug/L 05/05/2020 2200 Styrene ND 1 1.0 0.41 ug/L 05/05/2020 2200 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/05/2020 2200 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/05/2020 2200 Tetrachloroethene ND 1 1.0 0.40 ug/L 05/05/2020 2200 Toluene ND 1 1.0 0.40 ug/L 05/05/2020 2200 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 05/05/2020 2200 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 05/05/2020 2200 Trichloroethene ND 1 1.0 0.40 ug/L 05/05/2020 2200 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 05/05/2020 2200 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 05/05/2020 2200 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 133 of 191 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ52963-001 Matrix: Aqueous Batch:52963 Prep Method: 5030B Analvtical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 05/05/2020 2200 Vinyl chloride ND 1 1.0 0.40 ug/L 05/05/2020 2200 Xylenes (total) ND 1 1.0 0.40 ug/L 05/05/2020 2200 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 122 70-130 1,2-Dichloroethane-d4 112 70-130 Toluene-d8 118 70-130 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 134 of 191 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ52963-002 Matrix: Aqueous Batch:52963 Prep Method: 5030B Analvtical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 92 1 92 60-140 05/05/2020 1945 Acrylonitrile 100 96 1 96 70-130 05/05/2020 1945 Benzene 50 47 1 94 70-130 05/05/2020 1945 Bromochloromethane 50 46 1 93 70-130 05/05/2020 1945 Bromodichloromethane 50 47 1 95 70-130 05/05/2020 1945 Bromoform 50 49 1 99 70-130 05/05/2020 1945 Bromomethane (Methyl bromide) 50 47 1 94 70-130 05/05/2020 1945 2-Butanone (MEK) 100 100 1 103 70-130 05/05/2020 1945 Carbon disulfide 50 48 1 97 70-130 05/05/2020 1945 Carbon tetrachloride 50 49 1 97 70-130 05/05/2020 1945 Chlorobenzene 50 47 1 93 70-130 05/05/2020 1945 Chloroethane 50 47 1 95 70-130 05/05/2020 1945 Chloroform 50 46 1 93 70-130 05/05/2020 1945 Chloromethane (Methyl chloride) 50 47 1 95 60-140 05/05/2020 1945 1,2-Dibromo-3-chloropropane (DBCP) 50 50 1 100 70-130 05/05/2020 1945 Dibromochloromethane 50 48 1 97 70-130 05/05/2020 1945 1,2-Dibromoethane (EDB) 50 48 1 97 70-130 05/05/2020 1945 Dibromomethane (Methylene bromide) 50 47 1 95 70-130 05/05/2020 1945 trans-1,4-Dichloro-2-butene 50 50 1 100 70-130 05/05/2020 1945 1,2-Dichlorobenzene 50 47 1 95 70-130 05/05/2020 1945 1,4-Dichlorobenzene 50 47 1 94 70-130 05/05/2020 1945 1,1-Dichloroethane 50 47 1 95 70-130 05/05/2020 1945 1,2-Dichloroethane 50 46 1 92 70-130 05/05/2020 1945 1,1-Dichloroethene 50 49 1 97 70-130 05/05/2020 1945 cis-1,2-Dichloroethene 50 47 1 94 70-130 05/05/2020 1945 trans-1,2-Dichloroethene 50 48 1 95 70-130 05/05/2020 1945 1,2-Dichloropropane 50 46 1 93 70-130 05/05/2020 1945 cis- 1,3-Dichloropropene 50 48 1 97 70-130 05/05/2020 1945 trans-1,3-Dichloropropene 50 49 1 98 70-130 05/05/2020 1945 Ethylbenzene 50 48 1 95 70-130 05/05/2020 1945 2-Hexanone 100 100 1 101 70-130 05/05/2020 1945 Methyl iodide (lodomethane) 50 48 1 95 70-130 05/05/2020 1945 4-Methyl-2-pentanone 100 98 1 98 70-130 05/05/2020 1945 Methylene chloride 50 46 1 92 70-130 05/05/2020 1945 Styrene 50 49 1 98 70-130 05/05/2020 1945 1,1,1,2-Tetrachloroethane 50 48 1 96 70-130 05/05/2020 1945 1,1,2,2-Tetrachloroethane 50 48 1 95 70-130 05/05/2020 1945 Tetrachloroethene 50 48 1 97 70-130 05/05/2020 1945 Toluene 50 48 1 95 70-130 05/05/2020 1945 1,1,1-Trichloroethane 50 49 1 97 70-130 05/05/2020 1945 1,1,2-Trichloroethane 50 47 1 95 70-130 05/05/2020 1945 Trichloroethene 50 47 1 95 70-130 05/05/2020 1945 Trichlorofluoromethane 50 49 1 99 70-130 05/05/2020 1945 1,2,3-Trichloropropane 50 48 1 96 70-130 05/05/2020 1945 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 135 of 191 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ52963-002 Matrix: Aqueous Batch:52963 Prep Method: 5030B Analvtical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 46 1 92 60-140 05/05/2020 1945 Vinyl chloride 50 49 1 97 70-130 05/05/2020 1945 Xylenes (total) 100 96 1 96 70-130 05/05/2020 1945 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 94 70-130 1,2-Dichloroethane-d4 94 70-130 Toluene-d8 95 70-130 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 136 of 191 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ53020-001 Matrix: Aqueous Batch: 53020 Prep Method: 5030B Analvtical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 05/06/2020 0934 Acrylonitrile ND 1 20 0.80 ug/L 05/06/2020 0934 Benzene ND 1 1.0 0.40 ug/L 05/06/2020 0934 Bromochloromethane ND 1 1.0 0.40 ug/L 05/06/2020 0934 Bromodichloromethane ND 1 1.0 0.40 ug/L 05/06/2020 0934 Bromoform ND 1 1.0 0.40 ug/L 05/06/2020 0934 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 05/06/2020 0934 2-Butanone (MEK) ND 1 10 2.0 ug/L 05/06/2020 0934 Carbon disulfide ND 1 1.0 0.40 ug/L 05/06/2020 0934 Carbon tetrachloride ND 1 1.0 0.40 ug/L 05/06/2020 0934 Chlorobenzene ND 1 1.0 0.40 ug/L 05/06/2020 0934 Chloroethane ND 1 2.0 0.40 ug/L 05/06/2020 0934 Chloroform ND 1 1.0 0.40 ug/L 05/06/2020 0934 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 05/06/2020 0934 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 05/06/2020 0934 Dibromochloromethane ND 1 1.0 0.40 ug/L 05/06/2020 0934 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 05/06/2020 0934 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 05/06/2020 0934 trans-1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 05/06/2020 0934 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/06/2020 0934 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/06/2020 0934 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 05/06/2020 0934 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 05/06/2020 0934 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2020 0934 cis-1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2020 0934 trans-1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/06/2020 0934 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 05/06/2020 0934 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/06/2020 0934 trans-1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/06/2020 0934 Ethylbenzene ND 1 1.0 0.40 ug/L 05/06/2020 0934 2-Hexanone ND 1 10 2.0 ug/L 05/06/2020 0934 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 05/06/2020 0934 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 05/06/2020 0934 Methylene chloride ND 1 1.0 0.40 ug/L 05/06/2020 0934 Styrene ND 1 1.0 0.41 ug/L 05/06/2020 0934 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/06/2020 0934 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/06/2020 0934 Tetrachloroethene ND 1 1.0 0.40 ug/L 05/06/2020 0934 Toluene ND 1 1.0 0.40 ug/L 05/06/2020 0934 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 05/06/2020 0934 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 05/06/2020 0934 Trichloroethene ND 1 1.0 0.40 ug/L 05/06/2020 0934 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 05/06/2020 0934 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 05/06/2020 0934 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 137 of 191 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ53020-001 Matrix: Aqueous Batch:53020 Prep Method: 5030B Analvtical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 05/06/2020 0934 Vinyl chloride ND 1 1.0 0.40 ug/L 05/06/2020 0934 Xylenes (total) ND 1 1.0 0.40 ug/L 05/06/2020 0934 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 101 70-130 1,2-Dichloroethane-d4 101 70-130 Toluene-d8 108 70-130 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 138 of 191 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ53020-002 Matrix: Aqueous Batch:53020 Prep Method: 5030B Analvtical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 95 1 95 60-140 05/06/2020 0814 Acrylonitrile 100 100 1 104 70-130 05/06/2020 0814 Benzene 50 50 1 101 70-130 05/06/2020 0814 Bromochloromethane 50 49 1 99 70-130 05/06/2020 0814 Bromodichloromethane 50 52 1 103 70-130 05/06/2020 0814 Bromoform 50 53 1 107 70-130 05/06/2020 0814 Bromomethane (Methyl bromide) 50 48 1 95 70-130 05/06/2020 0814 2-Butanone (MEK) 100 110 1 110 70-130 05/06/2020 0814 Carbon disulfide 50 51 1 102 70-130 05/06/2020 0814 Carbon tetrachloride 50 52 1 104 70-130 05/06/2020 0814 Chlorobenzene 50 51 1 102 70-130 05/06/2020 0814 Chloroethane 50 48 1 96 70-130 05/06/2020 0814 Chloroform 50 50 1 100 70-130 05/06/2020 0814 Chloromethane (Methyl chloride) 50 50 1 100 60-140 05/06/2020 0814 1,2-Dibromo-3-chloropropane (DBCP) 50 54 1 108 70-130 05/06/2020 0814 Dibromochloromethane 50 53 1 107 70-130 05/06/2020 0814 1,2-Dibromoethane (EDB) 50 52 1 104 70-130 05/06/2020 0814 Dibromomethane (Methylene bromide) 50 51 1 103 70-130 05/06/2020 0814 trans-1,4-Dichloro-2-butene 50 55 1 111 70-130 05/06/2020 0814 1,2-Dichlorobenzene 50 51 1 102 70-130 05/06/2020 0814 1,4-Dichlorobenzene 50 51 1 103 70-130 05/06/2020 0814 1,1-Dichloroethane 50 51 1 102 70-130 05/06/2020 0814 1,2-Dichloroethane 50 50 1 100 70-130 05/06/2020 0814 1,1-Dichloroethene 50 51 1 101 70-130 05/06/2020 0814 cis-1,2-Dichloroethene 50 51 1 101 70-130 05/06/2020 0814 trans-1,2-Dichloroethene 50 51 1 101 70-130 05/06/2020 0814 1,2-Dichloropropane 50 51 1 103 70-130 05/06/2020 0814 cis- 1,3-Dichloropropene 50 53 1 106 70-130 05/06/2020 0814 trans-1,3-Dichloropropene 50 54 1 108 70-130 05/06/2020 0814 Ethylbenzene 50 52 1 104 70-130 05/06/2020 0814 2-Hexanone 100 110 1 110 70-130 05/06/2020 0814 Methyl iodide (lodomethane) 50 50 1 101 70-130 05/06/2020 0814 4-Methyl-2-pentanone 100 110 1 106 70-130 05/06/2020 0814 Methylene chloride 50 50 1 100 70-130 05/06/2020 0814 Styrene 50 53 1 107 70-130 05/06/2020 0814 1,1,1,2-Tetrachloroethane 50 52 1 104 70-130 05/06/2020 0814 1,1,2,2-Tetrachloroethane 50 52 1 104 70-130 05/06/2020 0814 Tetrachloroethene 50 52 1 104 70-130 05/06/2020 0814 Toluene 50 51 1 103 70-130 05/06/2020 0814 1,1,1-Trichloroethane 50 51 1 103 70-130 05/06/2020 0814 1,1,2-Trichloroethane 50 51 1 103 70-130 05/06/2020 0814 Trichloroethene 50 51 1 103 70-130 05/06/2020 0814 Trichlorofluoromethane 50 49 1 98 70-130 05/06/2020 0814 1,2,3-Trichloropropane 50 52 1 105 70-130 05/06/2020 0814 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 139 of 191 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ53020-002 Matrix: Aqueous Batch:53020 Prep Method: 5030B Analvtical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 51 1 101 60-140 05/06/2020 0814 Vinyl chloride 50 50 1 100 70-130 05/06/2020 0814 Xylenes (total) 100 110 1 105 70-130 05/06/2020 0814 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 96 70-130 Toluene-d8 98 70-130 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 140 of 191 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ53315-001 Matrix: Aqueous Batch: 53315 Prep Method: 5030B Analvtical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 05/08/20201015 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 94 70-130 Toluene-d8 101 70-130 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 141 of 191 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ53315-002 Matrix: Aqueous Batch: 53315 Prep Method: 5030B Analvtical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 100 1 104 60-140 05/08/2020 0919 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 94 70-130 Toluene-d8 96 70-130 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 142 of 191 ICP-MS Metals - MB Sample ID: VQ52485-001 Matrix: Aqueous Batch:52485 Prep Method: 3005A Analvtical Method: 6020B Prep Date: 04/30/2020 1605 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 04/30/2020 2331 Arsenic ND 1 2.0 1.3 ug/L 04/30/2020 2331 Barium ND 1 5.0 1.3 ug/L 04/30/2020 2331 Beryllium ND 1 0.40 0.15 ug/L 04/30/2020 2331 Cadmium ND 1 0.50 0.13 ug/L 04/30/2020 2331 Chromium ND 1 5.0 1.3 ug/L 04/30/2020 2331 Cobalt ND 1 5.0 1.3 ug/L 04/30/2020 2331 Copper ND 1 5.0 1.3 ug/L 04/30/2020 2331 Lead ND 1 1.0 0.25 ug/L 04/30/2020 2331 Nickel ND 1 5.0 1.3 ug/L 04/30/2020 2331 Selenium ND 1 5.0 1.3 ug/L 04/30/2020 2331 Silver ND 1 1.0 0.25 ug/L 04/30/2020 2331 Thallium ND 1 0.50 0.15 ug/L 04/30/2020 2331 Vanadium ND 1 5.0 2.5 ug/L 04/30/2020 2331 Zinc ND 1 10 2.5 ug/L 04/30/2020 2331 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 143 of 191 ICP-MS Metals - LCS Sample ID: VQ52485-002 Matrix: Aqueous Batch:52485 Prep Method: 3005A Analvtical Method: 6020B Prep Date: 04/30/2020 1605 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 94 1 94 80-120 04/30/2020 2337 Arsenic 100 97 1 97 80-120 04/30/2020 2337 Barium 100 98 1 98 80-120 04/30/2020 2337 Beryllium 100 110 1 108 80-120 04/30/2020 2337 Cadmium 100 96 1 96 80-120 04/30/2020 2337 Chromium 100 97 1 97 80-120 04/30/2020 2337 Cobalt 100 96 1 96 80-120 04/30/2020 2337 Copper 100 96 1 96 80-120 04/30/2020 2337 Lead 100 99 1 99 80-120 04/30/2020 2337 Nickel 100 95 1 95 80-120 04/30/2020 2337 Selenium 100 94 1 94 80-120 04/30/2020 2337 Silver 100 95 1 95 80-120 04/30/2020 2337 Thallium 100 98 1 98 80-120 04/30/2020 2337 Vanadium 100 93 1 93 80-120 04/30/2020 2337 Zinc 100 100 1 100 80-120 04/30/2020 2337 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 144 of 191 ICP-MS Metals - MS Sample ID: VD29085-013MS Matrix: Aqueous Batch:52485 Prep Method: 3005A Analvtical Method: 6020B Prep Date: 04/30/2020 1605 Sample Spike Amount Amount Result % Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony ND 100 94 1 94 70-130 05/01/2020 0105 Arsenic ND 100 100 1 101 70-130 05/01/2020 0105 Barium 40 100 140 1 97 70-130 05/01/2020 0105 Beryllium ND 100 110 1 107 70-130 05/01/2020 0105 Cadmium ND 100 96 1 96 70-130 05/01/2020 0105 Chromium ND 100 98 1 98 70-130 05/01/2020 0105 Cobalt ND 100 96 1 96 70-130 05/01/2020 0105 Copper ND 100 95 1 95 70-130 05/01/2020 0105 Lead ND 100 99 1 99 70-130 05/01/2020 0105 Nickel ND 100 95 1 95 70-130 05/01/2020 0105 Selenium ND 100 92 1 92 70-130 05/01/2020 0105 Silver ND 100 94 1 94 70-130 05/01/2020 0105 Thallium ND 100 99 1 99 70-130 05/01/2020 0105 Vanadium ND 100 95 1 95 70-130 05/01/2020 0105 Zinc 2.9 100 96 1 93 70-130 05/01/2020 0105 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 145 of 191 ICP-MS Metals - MSD Sample ID: VD29085-013MD Matrix: Aqueous Batch:52485 Prep Method: 3005A Analvtical Method: 6020B Prep Date: 04/30/2020 1605 Sample Spike Amount Amount Result % Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Antimony ND 100 94 1 94 0.78 70-130 20 05/01/2020 0111 Arsenic ND 100 100 1 102 1.4 70-130 20 05/01/2020 0111 Barium 40 100 140 1 99 1.1 70-130 20 05/01/2020 0111 Beryllium ND 100 110 1 106 1.5 70-130 20 05/01/2020 0111 Cadmium ND 100 96 1 96 0.38 70-130 20 05/01/2020 0111 Chromium ND 100 96 1 96 1.9 70-130 20 05/01/2020 0111 Cobalt ND 100 96 1 96 0.22 70-130 20 05/01/2020 0111 Copper ND 100 95 1 95 0.25 70-130 20 05/01/2020 0111 Lead ND 100 99 1 99 0.46 70-130 20 05/01/2020 0111 Nickel ND 100 95 1 95 0.19 70-130 20 05/01/2020 0111 Selenium ND 100 97 1 97 5.2 70-130 20 05/01/2020 0111 Silver ND 100 95 1 95 1.0 70-130 20 05/01/2020 0111 Thallium ND 100 99 1 99 0.11 70-130 20 05/01/2020 0111 Vanadium ND 100 95 1 95 0.23 70-130 20 05/01/2020 0111 Zinc 2.9 100 96 1 93 0.010 70-130 20 05/01/2020 0111 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 146 of 191 ICP-MS Metals - MB Sample ID: VQ52779-001 Matrix: Aqueous Batch:52779 Prep Method: 3005A Analvtical Method: 6020B Prep Date: 05/05/2020 1554 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 05/07/2020 0733 Arsenic ND 1 2.0 1.3 ug/L 05/07/2020 0733 Barium ND 1 5.0 1.3 ug/L 05/07/2020 0733 Beryllium ND 1 0.40 0.15 ug/L 05/07/2020 0733 Cadmium ND 1 0.50 0.13 ug/L 05/07/2020 0733 Chromium ND 1 5.0 1.3 ug/L 05/07/2020 0733 Cobalt ND 1 5.0 1.3 ug/L 05/07/2020 0733 Copper ND 1 5.0 1.3 ug/L 05/07/2020 0733 Lead ND 1 1.0 0.25 ug/L 05/07/2020 0733 Nickel ND 1 5.0 1.3 ug/L 05/07/2020 0733 Selenium ND 1 5.0 1.3 ug/L 05/07/2020 0733 Silver ND 1 1.0 0.25 ug/L 05/07/2020 0733 Thallium ND 1 0.50 0.15 ug/L 05/07/2020 0733 Vanadium ND 1 5.0 2.5 ug/L 05/07/2020 0733 Zinc ND 1 10 2.5 ug/L 05/07/2020 0733 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 147 of 191 ICP-MS Metals - LCS Sample ID: VQ52779-002 Matrix: Aqueous Batch:52779 Prep Method: 3005A Analvtical Method: 6020B Prep Date: 05/05/2020 1554 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 97 1 97 80-120 05/07/2020 0739 Arsenic 100 100 1 104 80-120 05/07/2020 0739 Barium 100 100 1 101 80-120 05/07/2020 0739 Beryllium 100 98 1 98 80-120 05/07/2020 0739 Cadmium 100 98 1 98 80-120 05/07/2020 0739 Chromium 100 100 1 100 80-120 05/07/2020 0739 Cobalt 100 99 1 99 80-120 05/07/2020 0739 Copper 100 95 1 95 80-120 05/07/2020 0739 Lead 100 100 1 103 80-120 05/07/2020 0739 Nickel 100 98 1 98 80-120 05/07/2020 0739 Selenium 100 100 1 104 80-120 05/07/2020 0739 Silver 100 97 1 97 80-120 05/07/2020 0739 Thallium 100 100 1 101 80-120 05/07/2020 0739 Vanadium 100 99 1 99 80-120 05/07/2020 0739 Zinc 100 100 1 104 80-120 05/07/2020 0739 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 148 of 191 ICP-MS Metals - MS Sample ID: VD29085-025MS Matrix: Aqueous Batch:52779 Prep Method: 3005A Analvtical Method: 6020B Prep Date: 05/05/2020 1554 Sample Spike Amount Amount Result % Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony ND 100 97 1 97 70-130 05/07/2020 0913 Arsenic ND 100 100 1 105 70-130 05/07/2020 0913 Barium 18 100 120 1 103 70-130 05/07/2020 0913 Beryllium ND 100 71 1 71 70-130 05/07/2020 0913 Cadmium ND 100 98 1 98 70-130 05/07/2020 0913 Chromium ND 100 98 1 98 70-130 05/07/2020 0913 Cobalt ND 100 98 1 98 70-130 05/07/2020 0913 Copper 4.3 100 100 1 96 70-130 05/07/2020 0913 Lead 1.0 100 100 1 101 70-130 05/07/2020 0913 Nickel 1.9 100 98 1 96 70-130 05/07/2020 0913 Selenium ND 100 100 1 100 70-130 05/07/2020 0913 Silver ND 100 95 1 95 70-130 05/07/2020 0913 Thallium ND 100 100 1 100 70-130 05/07/2020 0913 Vanadium ND 100 99 1 99 70-130 05/07/2020 0913 Zinc 7.8 100 110 1 103 70-130 05/07/2020 0913 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 149 of 191 ICP-MS Metals - MSD Sample ID: VD29085-025MD Matrix: Aqueous Batch:52779 Prep Method: 3005A Analvtical Method: 6020B Prep Date: 05/05/2020 1554 Sample Spike Amount Amount Result % Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Antimony ND 100 96 1 96 1.4 70-130 20 05/07/2020 0919 Arsenic ND 100 100 1 102 3.2 70-130 20 05/07/2020 0919 Barium 18 100 120 1 100 2.2 70-130 20 05/07/2020 0919 Beryllium ND 100 73 1 73 2.0 70-130 20 05/07/2020 0919 Cadmium ND 100 98 1 98 0.82 70-130 20 05/07/2020 0919 Chromium ND 100 97 1 97 0.91 70-130 20 05/07/2020 0919 Cobalt ND 100 97 1 97 1.1 70-130 20 05/07/2020 0919 Copper 4.3 100 99 1 95 0.84 70-130 20 05/07/2020 0919 Lead 1.0 100 100 1 99 2.0 70-130 20 05/07/2020 0919 Nickel 1.9 100 97 1 95 0.49 70-130 20 05/07/2020 0919 Selenium ND 100 96 1 96 3.7 70-130 20 05/07/2020 0919 Silver ND 100 96 1 96 0.83 70-130 20 05/07/2020 0919 Thallium ND 100 98 1 98 1.4 70-130 20 05/07/2020 0919 Vanadium ND 100 100 1 100 0.54 70-130 20 05/07/2020 0919 Zinc 7.8 100 110 1 101 1.7 70-130 20 05/07/2020 0919 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 150 of 191 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 151 of 191 rn n G CD a) D 7 3 :) N m -0 o. 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Yes ❑ 1# 0 LNA 18_ W,-yc all cyFwjde I;lrtlple.,; reejycd at a ON f 12 a133 n1F[iie sz,mplereceived et N $F Yes ❑ P#o ❑ 1+lA J .Were F,11 appals able ] 3 K +cyawi plur,Dllb25 { 0.5 n x'h i— CI1lorins:2 ? ) S�,lples trey of rC3rdnal C Yes UN. ONA 20. arc rhatire;t�orks/requcsts 0-- nquestcd dilutions, tNiSAISD des igntrtions nc,,,j corregtly rran3rzAbed frurr. thst Coo into The CDMrUnt rw[j t in UNIS? ❑ Yes Ala 21 . Was the qooze Ml iber listed On tha oorr�in� li6, uaw ;V NA ample PEvur vatian CMLL-iI be omrnplated for ally sainpie(s) JicvwTenLjy pnes4r4cd or with lu:xtsjspa.�r,) . $Xnp`xtis) NA were nece;vcd incurre£,1YP1: ser4«I and were arijl;sred Wcordingly in s mple Teceiv"tTg tvhh NA mL nfcircic ax, � 1 St , h'hiU3, Hsi, N QH �Siag SR NA pirne of Presea wrr[ion NA_ If mo!e [hen cne p;r¢servativL.1S ncedar, ]}learn na*e ill the tUmmerrlfi eluw, arnple(s) MA )Mm tcceiwd with NibbJes>o r„rr. in djams#er_ Samples(s) VA _ wrlp reani v,;d with TRC > 0.5 r_ig)L (if >+i 4 is pro) and were a1)tr5ted txtisordingly in s&mPiereceivi-gTAIth todiwrt 1? iasr~IFate (MRI5203) wi0s Shealy ID: NA ER bw-mde laWis appCied by. !$H Daac, 0 +729r'2020 C4-,Tr r ]g�rl l s. pRP I dr SamlpleReceipt Checkfist. (5 Rq FFI;:tti, Nicrari+zol8 i [Aer lnspccnd hy{dtlte ❑tr { li l 91 Q2 tit i;: �+D3s?11 5 ST � — — — - Clier[ 1� ] . V4+e:-c cus�ltatE.y Seals Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 154 of 191 rn n G CD v D � 3 ,v C CD -0 o. N m o� ro CD� r r m 0 o o � c 3 CD �t �co �C �M � 3 �l C N 0 CD � 3 CD fn (D on ro O >v N x N 00 O o V to �� Ch,3in of Custody Record GS�o! pr,Q�ccr r,4rrm� {i are,j i. 7 P, kf Gz5 kE d�� �GX1dmI�r fEf 25R7 s7o44i k{rf �9 Nd4 M 0.'C ��'+C',� fL/ - {- k I] f kI 1v SHEALY ENVIRONMENTAL SERVICES, INC. 1oG Vantage F00 Dri-= • WA&t Cclumblo. SC 291T2 Telephone ND. 791-WMD Fax Mo. 8DO�-791-9111 ww-dv,shealylab,com P1aax7 m 99� Tu -- �.'I�IfPri144KIP P, a %i3- j Msmx CVO Lip},Yam py PfF art'uoolla ?!YM' (� TI r11r_ p p i�raAraiwd7frneJdeoWed?5iorrdlliw-wavr"lyfee vjp rlydLU-) aisffW*Diwsal fl Sraihrl&r�l ❑ T sr#rr;SA ITk'j I 1 r7ahrr rL, -Ar r- RMS f,Ra gidsf4*�rry Daft► 7;l 2. Rnli' oui5had ty orra Tara 3. Rsalirwladby maw Time 619G517r¢LVSh6dGlr Dare 7rmc Nofs: AN sgTAr fps aye retafttad for Foai r wkg Pram rgLoor Zf ,fBSw 911rar arranij Pmkwlf 3 are rwde. pi8ilFhar�rno►rr wf+r. t €I YFlf_O;N-Igato- - -bb-ay WHI Jd xfgfsl, PTrWY h'ar+rCWy izlp90 w ft. i E Nmfr Humber 1056,63 �Vrslys+s iAff;tlq ITyt � rne�a �xarr. is rieSdedJ 1 114, lk y I Ub D OW— D rlrmlfAhl3 rl 9Wn ,-rriank p paho-1 7 jIIA_AIYR 4. Rer�- �. n&xo Aad by �- Fecafrrc3i by a. L, wrarflry i by LAB ME OWLY R�a-AV&6 w ce Cock .I&. ' Pap—.- cr ± _ V029085 LJO Ha-wkis?C,-nkr i. U. t CC Reglr'ra neraf� fwl�sar}j aim Th" e Tuna cwfa rune 1w ray J'asfi Aem'pr T'ww. C _ DdwzranrU-wits. Feu -TX. EYaef7 a ± �a . t zava D 0 M Z I— n D cn M M r 0 rn 0 G CD v D 7 3 :)C CD -0 0 m oz CDCD N r r CD C. 0) o o � c 3 CD o, t n y �C �M � 3 �l C N 0 3 a m � 3 m y m O CD ro oy N x G 0 o 4 to � drain of custody Reo Ao4rMe GUY 8rs!e 210 Lbda F'raX�Cr errs FrGJf['t N0• PM No. fCaals'rrsrs .@r eac# %wrb IWVIW acmmsd I),' "Apr l SHEALY EPIVIF ONmENTAL SERVICES, INC. 1:0 Varlage Pain- Drive - WPM Columbia, SC 29172 Tek-p[wr.e No. S05-791-97f]O fax No. 800-791-011 wA'n',9r_eedyllab.com Poorr ro Canhel �ernq�er'a 5,Sra Prir,,r:ti NLA•nP ��' �$„�, AbdCrnhirreia I G `i 4 •�,Fci I/ Dumber IL06162 Tal5pF.Vnr? M /$,ma9 AnRJ ;,'AII Yah ft- ffRXWR itMtS?O J,m, V D29085 UO Fdhfi�dlf5.' �31$i ��, I � TirmAFOvvdTirnaFieWAnM(F•ParfaRgsFrovaJx "I"Lxk-dgdDTT-1 o'FgV-PO'*oas.' Foss.ovF",wL rdfoYmgan equSrema�es�—yp I�d�rL+ I I ftgn 5pa€r5f E.r�efirA �J4dfit d L1k umf &} .jf+ I I rhn-Hint' Q Pm=We Q Sk'n Irri;aid n MMM D Uri mri Y. Dsta 7Onv 1.R8a9Rti+i'LJ �nfi—. PlprB f. ResrreuWX)abig D N rr d . P,xci�nrdaF �n o Tura a. FDc67ern: nrDO&rR�� a RdertA,ad by 4�969 Tag Daterrue , �.�r,�.�f3.f..r y n nv,PP N", AWsampfasare refoFad iarfour wpau frfmU wd-Ypt LAB b.9EMLy vfkfess oPher arr m]aments are r aQV ReeeoMd crr i99 (Caere) 7J�_ fr.,- i GOWr %ago. nrsaxx Ln w - V re a VELLOW Frclw+s re lstcf-gvy-, irr;rfi S2woWs;; P.AW-FfOEdrWF Coo OLLiJYIBfIC fMKIDCf � YQ-T Sh e7Yaed: o ?ere tufiu r,�vr D M D Z r n D r M M Cn r ^r `+ PACE ANALYTICAL SERVICES, LLC She* L-n:iNuiueilal SCrYkCA ]rIC- DCCL,nF2,AHurlLe-WR:kl IS CZ-4 t°W n' I �ilecJitiw nnic- &'�QQ]S Sample Receipt Checlikfigt (SRC) CJre7i: 13LE Conler in ectt rd h}rdate::Sli 0=4,3G120?C Lot*, VD29085 f"rece'pt, ® FST C1iedA ❑ U1x5 Fc�Far t tliar. PpHStknrip ® N(I I_ Were castody seals present an the cooler'] ltio NA 2- IJ-c�:ssells were ;—E,t"were 4h intact vad Lin broken? lJ7:-[i'�p9 Chlurinc Strip TU; ZO-027 _ T-ostrd by; BN10 (}rigirla4 felnper4l1LUO _ Upny M00ipt I DefiYcd (Ca�racted) 1 Ri»1at4irrc '-1pon receipt D/q) ;d snap-Ctip ID' 2.4 1 2.4 °C 2-1 0.5 °C NA !NA aC. NA "C e#1loLl; _;NA ! ampOrrhire 13;unk DAgaimt Bodes I Gen IDS � I Cnn CortmCt.on Factor: 4 _ McthodoFuxrlrna: 0 Wctloe El 1-.aJ}acks ❑ Dry Ten ❑ ltiour -- ❑ Yes ©Na A NA 3, If tempetatwr of tmy cnnlcr ar.-cee" 6-0'C, agar Pnojoct [Manager 3Vatified? ]�'1 wet 1�lotifird ay: pbnne 1 cTiai� 1 face-�o-face (circI� ❑ No ONA 4- Is LLr<aornrrMialc0uriel"a Dackin slip aftaehcu Ia this fort? riTo 5. Were 4aroPrcr c0godv i.-oceduic (rcliRquishcd{�-eceivel) foll0lved? rlyc No 6, Wcrc sarnplr. IDS listed on fhe CQC? N0 7- Vk+ere sample IDS listed 4n all santplo co-nta]oem? © No 8- Was Ca4lectinr, drtte & link listed on the CIDC? Yea 9- Was C016dicin date & (imc list -Ed On al I wmplc containers? ® Yes ❑No JI},1?id,7llkornainor labclill Ccrinmdon(ID,d:te.tin]e)agrCe"J'ith115aOOC'.' Yes d N0 i 1. Were tests to L'r performed fasted an the C:UC.'± ❑ No 12. laid all samples arrive in the proper cooiia-rr.rs for ea.h tvsr andlr)r _2l good ou„diticn (unl>•rakcn,l ids an, chc.)'� _ ' s ❑ >hia 13, Was adequate sainplo %%i lkirae ayai 114blC? Yos TNo I4_ WL,Lra all s2rr,pies LwalYt-,d w%iin :4 the=]0lding tune or 49 TlQUYS, whic'Uver comes f[rst? YEN No 15. VVer any sampiL s containers missin rwn}ss ircle one) 2jurrl plos Nm listed 1 C7C3C$ Q Yes No ❑ NA16. For VOA and RSIC-l75 sarupinsa wel,� bUbblss ]yretnnt > peFi izc" (!"or 6mm in d:arrLtriY:r) in any of"il:n iFC�l4 vi;A5? Yes; No NA 17. ihfcxe al l DR. Ur'mwtalslilUtrient Samples received at a pJ4 of < 27 ® yr s ❑ No l� NA I fi. Were.0II cyanide earl les rVcr:ived ac a -1 > 12 and sulfide samples received at a -! � 9? ,�� ❑f� NA I . Wcrc a i a LOa [e NIi;(11 f4'cyanide p ienkf!ld S f<0 Ing{L)sslmp a3 tree Of i-caicuat I CJ Y4Ls ❑ Nel O NA 20. Wek� olierr *%itta_-ksJrcque�sls (i.e. requested dilutions, NISI SD designations, e1c...] GOn-eaUy irmn.5C17b2d Pram the COC intp iBe C*tltFr. eni socriou in LIMS? ❑ Yes Nol 2 1 - IyVas theuuw number 1iUcd m tlir wilta'ner TAW? if }y s, tt0te A N,f Srimple Preservatun (Must be cxornfArted for tiny sarnpl,(s) iltcprrQC0y preservod or xviOi headspAcm.) Sarniple(�) NA were received iryCUrrecllp trn:sen�a� Arid ,ware adj�rsted a ordinal} in sample rweivinu with L A nil -of circle one; H2SO4. TdNO3, I-IC1, NaO1-1 nsinZ 5R 4.NA 15me of preser vntitir. ]+!A _ _ If more tot tone preRcrvative is riurited„ please note in the commonts be tu-w. tramples NA �YLxc received widf bubbles >6mm in aiamcter. iamp]es aj NA weu'-D received with TRC 0"5 mg1L (If p l 9 is uo 1 ?nd were 1INS 4�Ll UCCOdingly hi skin. rdn. receiving lih sudium thiosulf W a2S3C)3) Witti Shealy [L3 Nr1 5R barcodc labelsaprilied 4;y. JSI-I I7awtt: O4341ZIM C omrn nts: EXU!ss. TRTI' RLA NK Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 157 of 191 lacmnalyficalo May 22, 2020 Lucas Odom Pace Analytical Services South Carolina 106 Vantage Point Drive West Columbia, SC 29172 RE: Buncombe Landfill Pace Workorder. 33618 Dear Lucas Odom: Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Enclosed are the analytical results for sample(s) received by the laboratory on Monday, May 04, 2020. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Emma Louis 05/22/2020 Emma.Louis@pacelabs.com Customer Service Representative Enclosures As a valued client we would appreciate your comments on our service. Please email PAESfeedback@pacelabs.com. Report ID: 33618 - 1283034 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Total Number of Pages 35 Page 1 of 33 Pace Analytical Energy Services LLC 220 William Pitt Way A „ 1, X__ f � Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 LABORATORY ACCREDITATIONS & CERTIFICATIONS Accreditor: Pennsylvania Department of Environmental Protection, Bureau of Laboratories Accreditation ID: 02-00538 Scope: NELAP Non -Potable Water Accreditor: West Virginia Department of Environmental Protection, Division of Water and Waste Management Accreditation ID: 395 Scope: Non -Potable Water Accreditor: South Carolina Department of Health and Environmental Control, Office of Environmental Laboratory Certification Accreditation ID: 89009003 Scope: Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA) Accreditor: State of Virginia Accreditation ID: 460201 Scope: Non -Potable Water Accreditor: NELAP: New Jersey, Department of Environmental Protection Accreditation ID: PA026 Scope: Non -Potable Water Accreditor: NELAP: New York, Department of Health Wadsworth Center Accreditation ID: 11815 Scope: Non -Potable Water Accreditor: State of Connecticut, Department of Public Health, Division of Environmental Health Accreditation ID: PH-0263 Scope: Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA) Accreditor: NELAP: Texas, Commission on Environmental Quality Accreditation ID: T104704453-09-TX Scope: Non -Potable Water Accreditor: State of New Hampshire Accreditation ID: 299409 Scope: Non -potable water Accreditor: State of Georgia Accreditation ID: Chapter 391-3-26 Scope: As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is accredited by the Pennsylvania Department of Environmental Protection Bureau of Laboratories under the National Environmental Laboratory Approval Program (NELAC). Report ID: 33618 - 1283034 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 2 of 33 lacmnalyficalo SAMPLE SUMMARY Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID Sample ID Matrix Date Collected Date Received 336180001 MW-4 Water 4/28/202010:35 5/4/2020 13:13 336180002 MW-6 Water 4/28/202013:20 5/4/2020 13:13 336180003 MW-18-78 Water 4/28/2020 16:30 5/4/2020 13:13 336180004 MW-19-75 Water 4/28/2020 16:30 5/4/2020 13:13 336180005 MW-19-110 Water 4/28/202013:30 5/4/2020 13:13 336180006 MW-13-132 Water 4/28/202015:20 5/4/2020 13:13 336180007 MW-2 Water 4/29/202013:45 5/4/2020 13:13 336180008 MW-21-21 Water 4/29/202010:45 5/4/2020 13:13 336180009 MW-21-94 Water 4/29/2020 09:50 5/4/2020 13:13 336180010 MW-24-160 Water 4/29/202011:25 5/4/2020 13:13 336180011 MW-4 Bubble Strip 4/28/2020 10:35 5/4/2020 13:13 336180012 MW-6 Bubble Strip 4/28/2020 13:20 5/4/2020 13:13 336180013 MW-18-78 Bubble Strip 4/28/2020 16:30 5/4/2020 13:13 336180014 MW-19-75 Bubble Strip 4/28/2020 16:30 5/4/2020 13:13 336180015 MW-19-110 Bubble Strip 4/28/2020 13:30 5/4/2020 13:13 336180016 MW-13-132 Bubble Strip 4/28/2020 15:20 5/4/2020 13:13 336180017 MW-2 Bubble Strip 4/29/2020 13:45 5/4/2020 13:13 336180018 MW-21-21 Bubble Strip 4/29/2020 10:45 5/4/2020 13:13 336180019 MW-21-94 Bubble Strip 4/29/2020 09:50 5/4/2020 13:13 336180020 MW-24-160 Bubble Strip 4/29/2020 11:25 5/4/2020 13:13 Report ID: 33618 - 1283034 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 3 of 33 lacmnalyficalo PROJECT SUMMARY Workorder: 33618 Buncombe Landfill Workorder Comments This report is being re -issued on 5-22-20 to process the results as MDL level reporting. Report ID: 33618 - 1283034 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Page 4 of 33 lacmnalyficalo ANALYTICAL RESULTS Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 336180001 Sample ID: MW-4 Date Received: 5/4/2020 13:13 Matrix: Water Date Collected: 4/28/2020 10:35 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.0851.11 mg/I 0.20 0.085 1 5/8/2020 12:27 KB Acetic Acid 0.0431.11 mg/I 0.10 0.043 1 5/8/2020 12:27 KB Propionic Acid 0.0018J mg/I 0.10 0.0010 1 5/8/2020 12:27 KB Formic Acid 0.121.11 mg/I 0.50 0.12 1 5/8/2020 12:27 KB Butyric Acid 0.00901.11 mg/I 0.10 0.0090 1 5/8/2020 12:27 KB Pyruvic Acid 0.0141.11 mg/I 0.10 0.014 1 5/8/2020 12:27 KB i-Pentanoic Acid 0.00701.11 mg/I 0.10 0.0070 1 5/8/2020 12:27 KB Pentanoic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/8/2020 12:27 KB i-Hexanoic Acid 0.0101.11 mg/I 0.20 0.010 1 5/8/2020 12:27 KB Hexanoic Acid 0.0201.11 mg/I 0.20 0.020 1 5/8/2020 12:27 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 0.20J ug/I 0.50 0.023 1 5/6/202015:46 BW n Ethane 0.0101.11 ug/I 0.10 0.010 1 5/6/202015:46 BW n Ethene 0.059J ug/I 0.10 0.0090 1 5/6/202015:46 BW n Carbon Dioxide 4.4J mg/I 5.0 0.27 1 5/6/2020 15:46 BW n Report ID: 33618 - 1283034 Page 5 of 33 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. lacmnalyficalo ANALYTICAL RESULTS Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 336180002 Sample ID: MW-6 Date Received: 5/4/2020 13:13 Matrix: Water Date Collected: 4/28/2020 13:20 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.0851.11 mg/I 0.20 0.085 1 5/8/2020 13:20 KB Acetic Acid 0.0431.11 mg/I 0.10 0.043 1 5/8/2020 13:20 KB Propionic Acid 0.0030J mg/I 0.10 0.0010 1 5/8/2020 13:20 KB Formic Acid 0.121.11 mg/I 0.50 0.12 1 5/8/2020 13:20 KB Butyric Acid 0.00901.11 mg/I 0.10 0.0090 1 5/8/2020 13:20 KB Pyruvic Acid 0.016J mg/I 0.10 0.014 1 5/8/2020 13:20 KB i-Pentanoic Acid 0.00701.11 mg/I 0.10 0.0070 1 5/8/2020 13:20 KB Pentanoic Acid 0.052J mg/I 0.10 0.0050 1 5/8/2020 13:20 KB i-Hexanoic Acid 0.0101.11 mg/I 0.20 0.010 1 5/8/2020 13:20 KB Hexanoic Acid 0.0201.11 mg/I 0.20 0.020 1 5/8/2020 13:20 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 1600 ug/I 0.50 0.023 1 5/6/202015:56 BW n Ethane 0.38 ug/I 0.10 0.010 1 5/6/202015:56 BW n Ethene 0.21 ug/I 0.10 0.0090 1 5/6/202015:56 BW n Carbon Dioxide 120 mg/I 5.0 0.27 1 5/6/2020 15:56 BW n Report ID: 33618 - 1283034 Page 6 of 33 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. lacmnalyficalo ANALYTICAL RESULTS Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 336180003 Sample ID: MW-18-78 Date Received: 5/4/2020 13:13 Matrix: Water Date Collected: 4/28/2020 16:30 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.0851.11 mg/I 0.20 0.085 1 5/8/2020 14:14 KB Acetic Acid 0.0431.11 mg/I 0.10 0.043 1 5/8/2020 14:14 KB Propionic Acid 0.0036J mg/I 0.10 0.0010 1 5/8/2020 14:14 KB Formic Acid 0.13J mg/I 0.50 0.12 1 5/8/2020 14:14 KB Butyric Acid 0.00901.11 mg/I 0.10 0.0090 1 5/8/2020 14:14 KB Pyruvic Acid 0.016J mg/I 0.10 0.014 1 5/8/2020 14:14 KB i-Pentanoic Acid 0.00701.11 mg/I 0.10 0.0070 1 5/8/2020 14:14 KB Pentanoic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/8/2020 14:14 KB i-Hexanoic Acid 0.0101.11 mg/I 0.20 0.010 1 5/8/2020 14:14 KB Hexanoic Acid 0.0201.11 mg/I 0.20 0.020 1 5/8/2020 14:14 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 1400 ug/I 0.50 0.023 1 5/6/202016:05 BW n Ethane 0.078J ug/I 0.10 0.010 1 5/6/202016:05 BW n Ethene 0.30 ug/I 0.10 0.0090 1 5/6/202016:05 BW n Carbon Dioxide 360 mg/I 5.0 0.27 1 5/6/2020 16:05 BW n Report ID: 33618 - 1283034 Page 7 of 33 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. lacmnalyficalo ANALYTICAL RESULTS Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 336180004 Sample ID: MW-19-75 Date Received: 5/4/2020 13:13 Matrix: Water Date Collected: 4/28/2020 16:30 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.0851.11 mg/I 0.20 0.085 1 5/8/2020 15:08 KB Acetic Acid 0.0431.11 mg/I 0.10 0.043 1 5/8/2020 15:08 KB Propionic Acid 0.0040J mg/I 0.10 0.0010 1 5/8/2020 15:08 KB Formic Acid 0.121.11 mg/I 0.50 0.12 1 5/8/2020 15:08 KB Butyric Acid 0.00901.11 mg/I 0.10 0.0090 1 5/8/2020 15:08 KB Pyruvic Acid 0.026J mg/I 0.10 0.014 1 5/8/2020 15:08 KB i-Pentanoic Acid 0.0085J mg/I 0.10 0.0070 1 5/8/2020 15:08 KB Pentanoic Acid 0.019J mg/I 0.10 0.0050 1 5/8/2020 15:08 KB i-Hexanoic Acid 0.0101.11 mg/I 0.20 0.010 1 5/8/2020 15:08 KB Hexanoic Acid 0.0201.11 mg/I 0.20 0.020 1 5/8/2020 15:08 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 0.28J ug/I 0.50 0.023 1 5/6/202016:16 BW n Ethane 0.0101.11 ug/I 0.10 0.010 1 5/6/202016:16 BW n Ethene 0.019J ug/I 0.10 0.0090 1 5/6/202016:16 BW n Carbon Dioxide 59 mg/I 5.0 0.27 1 5/6/2020 16:16 BW n Report ID: 33618 - 1283034 Page 8 of 33 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. lacmnalyficalo ANALYTICAL RESULTS Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 336180005 Sample ID: MW-19-110 Date Received: 5/4/2020 13:13 Matrix: Water Date Collected: 4/28/2020 13:30 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.0851.11 mg/I 0.20 0.085 1 5/8/2020 16:01 KB Acetic Acid 0.0431.11 mg/I 0.10 0.043 1 5/8/2020 16:01 KB Propionic Acid 0.0015J mg/I 0.10 0.0010 1 5/8/2020 16:01 KB Formic Acid 0.121.11 mg/I 0.50 0.12 1 5/8/2020 16:01 KB Butyric Acid 0.00901.11 mg/I 0.10 0.0090 1 5/8/2020 16:01 KB Pyruvic Acid 0.0141.11 mg/I 0.10 0.014 1 5/8/2020 16:01 KB i-Pentanoic Acid 0.00701.11 mg/I 0.10 0.0070 1 5/8/2020 16:01 KB Pentanoic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/8/2020 16:01 KB i-Hexanoic Acid 0.0101.11 mg/I 0.20 0.010 1 5/8/2020 16:01 KB Hexanoic Acid 0.0201.11 mg/I 0.20 0.020 1 5/8/2020 16:01 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 690 ug/I 0.50 0.023 1 5/6/202016:26 BW n Ethane 0.16 ug/I 0.10 0.010 1 5/6/202016:26 BW n Ethene 1.6 ug/I 0.10 0.0090 1 5/6/202016:26 BW n Carbon Dioxide 31 mg/I 5.0 0.27 1 5/6/2020 16:26 BW n Report ID: 33618 - 1283034 Page 9 of 33 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. lacmnalyficalo ANALYTICAL RESULTS Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 336180006 Sample ID: MW-13-132 Date Received: 5/4/2020 13:13 Matrix: Water Date Collected: 4/28/2020 15:20 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.0851.11 mg/I 0.20 0.085 1 5/8/2020 16:55 KB Acetic Acid 0.0431.11 mg/I 0.10 0.043 1 5/8/2020 16:55 KB Propionic Acid 0.0013J mg/I 0.10 0.0010 1 5/8/2020 16:55 KB Formic Acid 0.121.11 mg/I 0.50 0.12 1 5/8/2020 16:55 KB Butyric Acid 0.00901.11 mg/I 0.10 0.0090 1 5/8/2020 16:55 KB Pyruvic Acid 0.0141.11 mg/I 0.10 0.014 1 5/8/2020 16:55 KB i-Pentanoic Acid 0.00701.11 mg/I 0.10 0.0070 1 5/8/2020 16:55 KB Pentanoic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/8/2020 16:55 KB i-Hexanoic Acid 0.0101.11 mg/I 0.20 0.010 1 5/8/2020 16:55 KB Hexanoic Acid 0.0201.11 mg/I 0.20 0.020 1 5/8/2020 16:55 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 240 ug/I 0.50 0.023 1 5/6/202016:38 BW n Ethane 0.072J ug/I 0.10 0.010 1 5/6/202016:38 BW n Ethene 0.057J ug/I 0.10 0.0090 1 5/6/202016:38 BW n Carbon Dioxide 8.5 mg/I 5.0 0.27 1 5/6/2020 16:38 BW n Report ID: 33618 - 1283034 Page 10 of 33 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. lacmnalyficalo ANALYTICAL RESULTS Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 336180007 Sample ID: MW-2 Date Received: 5/4/2020 13:13 Matrix: Water Date Collected: 4/29/2020 13:45 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.0851.11 mg/I 0.20 0.085 1 5/8/2020 17:48 KB Acetic Acid 0.0431.11 mg/I 0.10 0.043 1 5/8/2020 17:48 KB Propionic Acid 0.0014J mg/I 0.10 0.0010 1 5/8/2020 17:48 KB Formic Acid 0.121.11 mg/I 0.50 0.12 1 5/8/2020 17:48 KB Butyric Acid 0.00901.11 mg/I 0.10 0.0090 1 5/8/2020 17:48 KB Pyruvic Acid 0.0141.11 mg/I 0.10 0.014 1 5/8/2020 17:48 KB i-Pentanoic Acid 0.00701.11 mg/I 0.10 0.0070 1 5/8/2020 17:48 KB Pentanoic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/8/2020 17:48 KB i-Hexanoic Acid 0.0101.11 mg/I 0.20 0.010 1 5/8/2020 17:48 KB Hexanoic Acid 0.0201.11 mg/I 0.20 0.020 1 5/8/2020 17:48 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 3.0 ug/I 0.50 0.023 1 5/6/202017:10 BW n Ethane 0.0101.11 ug/I 0.10 0.010 1 5/6/202017:10 BW n Ethene 0.024J ug/I 0.10 0.0090 1 5/6/202017:10 BW n Carbon Dioxide 58 mg/I 5.0 0.27 1 5/6/2020 17:10 BW n Report ID: 33618 - 1283034 Page 11 of 33 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. lacmnalyficalo ANALYTICAL RESULTS Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 336180008 Sample ID: MW-21-21 Date Received: 5/4/2020 13:13 Matrix: Water Date Collected: 4/29/2020 10:45 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.0851.11 mg/I 0.20 0.085 1 5/8/2020 18:42 KB Acetic Acid 0.0431.11 mg/I 0.10 0.043 1 5/8/2020 18:42 KB Propionic Acid 0.00101.11 mg/I 0.10 0.0010 1 5/8/2020 18:42 KB Formic Acid 0.121.11 mg/I 0.50 0.12 1 5/8/2020 18:42 KB Butyric Acid 0.00901.11 mg/I 0.10 0.0090 1 5/8/2020 18:42 KB Pyruvic Acid 0.0141.11 mg/I 0.10 0.014 1 5/8/2020 18:42 KB i-Pentanoic Acid 0.00701.11 mg/I 0.10 0.0070 1 5/8/2020 18:42 KB Pentanoic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/8/2020 18:42 KB i-Hexanoic Acid 0.0101.11 mg/I 0.20 0.010 1 5/8/2020 18:42 KB Hexanoic Acid 0.0201.11 mg/I 0.20 0.020 1 5/8/2020 18:42 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 1100 ug/I 0.50 0.023 1 5/6/202017:22 BW n Ethane 0.39 ug/I 0.10 0.010 1 5/6/202017:22 BW n Ethene 0.068J ug/I 0.10 0.0090 1 5/6/202017:22 BW n Carbon Dioxide 220 mg/I 5.0 0.27 1 5/6/2020 17:22 BW n Report ID: 33618 - 1283034 Page 12 of 33 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. lacmnalyficalo ANALYTICAL RESULTS Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 336180009 Sample ID: MW-21-94 Date Received: 5/4/2020 13:13 Matrix: Water Date Collected: 4/29/2020 09:50 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.0851.11 mg/I 0.20 0.085 1 5/8/2020 19:35 KB Acetic Acid 0.0431.11 mg/I 0.10 0.043 1 5/8/2020 19:35 KB Propionic Acid 0.0023J mg/I 0.10 0.0010 1 5/8/2020 19:35 KB Formic Acid 0.121.11 mg/I 0.50 0.12 1 5/8/2020 19:35 KB Butyric Acid 0.00901.11 mg/I 0.10 0.0090 1 5/8/2020 19:35 KB Pyruvic Acid 0.0141.11 mg/I 0.10 0.014 1 5/8/2020 19:35 KB i-Pentanoic Acid 0.00701.11 mg/I 0.10 0.0070 1 5/8/2020 19:35 KB Pentanoic Acid 0.039J mg/I 0.10 0.0050 1 5/8/2020 19:35 KB i-Hexanoic Acid 0.0101.11 mg/I 0.20 0.010 1 5/8/2020 19:35 KB Hexanoic Acid 0.0201.11 mg/I 0.20 0.020 1 5/8/2020 19:35 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 3700 ug/I 0.50 0.023 1 5/6/202017:31 BW n Ethane 0.70 ug/I 0.10 0.010 1 5/6/202017:31 BW n Ethene 0.28 ug/I 0.10 0.0090 1 5/6/202017:31 BW n Carbon Dioxide 580 mg/I 5.0 0.27 1 5/6/2020 17:31 BW n Report ID: 33618 - 1283034 Page 13 of 33 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. lacmnalyficalo ANALYTICAL RESULTS Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 336180010 Sample ID: MW-24-160 Date Received: 5/4/2020 13:13 Date Collected: 4/29/2020 11:25 Matrix: Water Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.0851.11 mg/I 0.20 0.085 1 5/8/2020 20:29 KB Acetic Acid 0.050J mg/I 0.10 0.043 1 5/8/2020 20:29 KB Propionic Acid 0.0048J mg/I 0.10 0.0010 1 5/8/2020 20:29 KB Formic Acid 0.121.11 mg/I 0.50 0.12 1 5/8/2020 20:29 KB Butyric Acid 0.00901.11 mg/I 0.10 0.0090 1 5/8/2020 20:29 KB Pyruvic Acid 0.0141.11 mg/I 0.10 0.014 1 5/8/2020 20:29 KB i-Pentanoic Acid 0.00701.11 mg/I 0.10 0.0070 1 5/8/2020 20:29 KB Pentanoic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/8/2020 20:29 KB i-Hexanoic Acid 0.0101.11 mg/I 0.20 0.010 1 5/8/2020 20:29 KB Hexanoic Acid 0.0201.11 mg/I 0.20 0.020 1 5/8/2020 20:29 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 490 ug/I 0.50 0.023 1 5/6/2020 17:41 BW n Ethane 0.11 ug/I 0.10 0.010 1 5/6/2020 17:41 BW n Ethene 0.14 ug/I 0.10 0.0090 1 5/6/2020 17:41 BW n Carbon Dioxide 390 mg/I 5.0 0.27 1 5/6/2020 17:41 BW n Report ID: 33618 - 1283034 Page 14 of 33 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. lacmnalyficalo Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 336180011 Date Received: 5/4/2020 13:13 Matrix: Bubble Strip Sample ID: MW-4 Date Collected: 4/28/2020 10:35 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 21 nM 1.0 1.0 1 5/6/202011:58 MM n Report ID: 33618 - 1283034 Page 15 of 33 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. lacmnalyficalo Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 336180012 Date Received: 5/4/2020 13:13 Matrix: Bubble Strip Sample ID: MW-6 Date Collected: 4/28/2020 13:20 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 8.2 nM 1.0 1.0 1 5/6/202012:16 MM n Report ID: 33618 - 1283034 Page 16 of 33 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. lacmnalyficalo Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 336180013 Date Received: 5/4/2020 13:13 Matrix: Bubble Strip Sample ID: MW-18-78 Date Collected: 4/28/2020 16:30 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 4.6 nM 1.0 1.0 1 5/6/202012:29 MM n Report ID: 33618 - 1283034 Page 17 of 33 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. lacmnalyficalo Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 336180014 Date Received: 5/4/2020 13:13 Matrix: Bubble Strip Sample ID: MW-19-75 Date Collected: 4/28/2020 16:30 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 5.0 nM 1.0 1.0 1 5/6/202012:44 MM n Report ID: 33618 - 1283034 Page 18 of 33 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. lacmnalyficalo Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 336180015 Date Received: 5/4/2020 13:13 Matrix: Bubble Strip Sample ID: MW-19-110 Date Collected: 4/28/2020 13:30 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 5.4 nM 1.0 1.0 1 5/6/202013:01 MM n Report ID: 33618 - 1283034 Page 19 of 33 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. lacmnalyficalo Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 336180016 Date Received: 5/4/2020 13:13 Matrix: Bubble Strip Sample ID: MW-13-132 Date Collected: 4/28/2020 15:20 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 3.0 nM 1.0 1.0 1 5/6/202013:14 MM n Report ID: 33618 - 1283034 Page 20 of 33 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. lacmnalyficalo Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 336180017 Date Received: 5/4/2020 13:13 Matrix: Bubble Strip Sample ID: MW-2 Date Collected: 4/29/2020 13:45 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 51 nM 4.0 4.0 4 5/7/2020 12:16 MM d,n Report ID: 33618 - 1283034 Page 21 of 33 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. lacmnalyficalo Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 336180018 Date Received: 5/4/2020 13:13 Matrix: Bubble Strip Sample ID: MW-21-21 Date Collected: 4/29/2020 10:45 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 7.7 nM 1.0 1.0 1 5/6/202013:40 MM n Report ID: 33618 - 1283034 Page 22 of 33 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. lacmnalyficalo Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 336180019 Date Received: 5/4/2020 13:13 Matrix: Bubble Strip Sample ID: MW-21-94 Date Collected: 4/29/2020 09:50 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 3.6 nM 1.0 1.0 1 5/6/202014:00 MM n Report ID: 33618 - 1283034 Page 23 of 33 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. lacmnalyficalo Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 336180020 Date Received: 5/4/2020 13:13 Matrix: Bubble Strip Sample ID: MW-24-160 Date Collected: 4/29/2020 11:25 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 27 nM 1.0 1.0 1 5/6/202014:14 MM n Report ID: 33618 - 1283034 Page 24 of 33 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. lacmnalyficalo ANALYTICAL RESULTS QUALIFIERS Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 DEFINITIONS/QUALIFIERS MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection. PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation. ND Not detected at or above reporting limit. DF Dilution Factor. S Surrogate. RPD Relative Percent Difference. % Rec Percent Recovery. U Indicates the compound was analyzed for, but not detected at or above the noted concentration. J Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL). n The laboratory does not hold NELAP/TNI accreditation for this method or analyte. d The analyte concentration was determined from a dilution. Report ID: 33618 - 1283034 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 25 of 33 lacmnalyficalo Workorder: 33618 Buncombe Landfill QUALITY CONTROL DATA Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: DISG/8235 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 336180001, 336180002, 336180003, 336180004, 336180005, 336180006, 336180007, 336180008, 336180009, 336180010 METHOD BLANK: 66994 Blank Reporting Parameter Units Result Limit Qualifiers RISK Methane ug/I 0.023U 0.023 n Ethane ug/I 0.010U 0.010 n Ethene ug/I 0.0090U 0.0090 n METHOD BLANK: 66995 Blank Reporting Parameter Units Result Limit Qualifiers RISK Carbon Dioxide mg/I 0.27U 0.27 n LABORATORY CONTROL SAMPLE & LCSD: 66996 66998 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Methane ug/I 750 740 720 98 96 80-120 2.6 20 n Ethane ug/I 38 38 38 100 100 80-120 0.25 20 n Ethene ug/I 35 36 36 102 102 80-120 0.4 20 n LABORATORY CONTROL SAMPLE & LCSD: 66997 66999 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Carbon Dioxide mg/I 120 110 120 98 100 80-120 2.1 20 n MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 67018 67019 Original: 336150006 Original Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers RISK Report ID: 33618 - 1283034 Page 26 of 33 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. lacmnalyficalo QUALITY CONTROL DATA Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 67018 67019 Original: 336150006 Original Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Result Result % Rec % Rec Limit RPD RPD Qualifiers Methane ug/I 0.15 40 38 37 93 92 70-130 0.66 20 n Ethane ug/I 0 76 70 69 92 91 70-130 1.2 20 n Ethene ug/I 0.015 71 67 66 95 93 70-130 1.3 20 n Report ID: 33618 - 1283034 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 27 of 33 lacmnalyficalo QUALITY CONTROL DATA Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: EDON/4431 Analysis Method: AM23G QC Batch Method: AM23G Associated Lab Samples: 336180001, 336180002, 336180003, 336180004, 336180005, 336180006, 336180007, 336180008, 336180009, 336180010 METHOD BLANK: 67022 Blank Reporting Parameter Units Result Limit Qualifiers EDonors Lactic Acid mg/I 0.085U 0.085 Acetic Acid mg/I 0.043U 0.043 Propionic Acid mg/I 0.0010U 0.0010 Formic Acid mg/I 0.12U 0.12 Butyric Acid mg/I 0.0090U 0.0090 Pyruvic Acid mg/I 0.014U 0.014 i-Pentanoic Acid mg/I 0.0070U 0.0070 Pentanoic Acid mg/I 0.0050U 0.0050 i-Hexanoic Acid mg/I 0.010U 0.010 Hexanoic Acid mg/I 0.020U 0.020 LABORATORY CONTROL SAMPLE: 67023 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lactic Acid mg/I 2 2.2 110 70-130 Acetic Acid mg/I 2 2.2 110 70-130 Propionic Acid mg/I 2 2.2 109 70-130 Formic Acid mg/I 2 2.2 108 70-130 Butyric Acid mg/I 2 2.2 109 70-130 Pyruvic Acid mg/I 2 2.0 102 70-130 i-Pentanoic Acid mg/I 2 2.2 108 70-130 Pentanoic Acid mg/I 2 2.1 104 70-130 i-Hexanoic Acid mg/I 2 2.1 107 70-130 Hexanoic Acid mg/I 2 2.0 98 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 67024 67025 Original: 336050001 Original Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers EDonors Lactic Acid mg/I 0.018 2 2.1 2.2 105 107 70-130 1.9 30 Report ID: 33618 - 1283034 Page 28 of 33 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. lacmnalyficalo QUALITY CONTROL DATA Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: Parameter Units 67024 Original Result Spike Cone. 67025 MS Result MSD Result Original: MS % Rec 336050001 MSD % Rec % Rec Limit RPD Max RPD Qualifiers Acetic Acid mg/I 0.047 2 2.3 2.3 111 111 70-130 0.47 30 Propionic Acid mg/I 0.0029 2 2.2 2.2 111 110 70-130 1.1 30 Formic Acid mg/I 0.048 2 2.2 2.2 109 109 70-130 0.06 30 Butyric Acid mg/I 0.0011 2 2.2 2.2 112 110 70-130 1.8 30 Pyruvic Acid mg/I 0.0018 2 2.0 2.0 101 102 70-130 0.89 30 i-Pentanoic Acid mg/I 0.0008 2 2.2 2.2 112 109 70-130 2.2 30 Pentanoic Acid mg/I 0.0014 2 2.2 2.2 111 108 70-130 3 30 i-Hexanoic Acid mg/I 0 2 2.4 2.3 120 115 70-130 4.5 30 Hexanoic Acid mg/I 0.0009 2 2.3 2.2 114 110 70-130 4.2 30 Report ID: 33618 - 1283034 Page 29 of 33 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. lacmnalyficalo QUALITY CONTROL DATA Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: DISG/8238 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 336180011, 336180012, 336180013, 336180014, 336180015, 336180016, 336180018, 336180019, 336180020 METHOD BLANK: 67026 Blank Reporting Parameter Units Result Limit Qualifiers RISK Hydrogen nM 1.0U 1.0 n LABORATORY CONTROL SAMPLE & LCSD: 67027 67028 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Hydrogen nM 25 26 26 104 104 80-120 0.42 20 n Report ID: 33618 - 1283034 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 30 of 33 lacmnalyficalo QUALITY CONTROL DATA Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: DISG/8241 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 336180017 METHOD BLANK: 67051 Blank Reporting Parameter Units Result Limit Qualifiers RISK Hydrogen nM 1.0U 1.0 n LABORATORY CONTROL SAMPLE & LCSD: 67052 67053 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Hydrogen nM 25 26 26 106 106 80-120 0.24 20 n Report ID: 33618 - 1283034 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 31 of 33 lacmnalyficalo QUALITY CONTROL DATA QUALIFIERS Workorder: 33618 Buncombe Landfill QUALITY CONTROL PARAMETER QUALIFIERS The laboratory does not hold NELAP/TNI accreditation for this method or analyte. Report ID: 33618 - 1283034 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Page 32 of 33 lacmnalyficalo QUALITY CONTROL DATA CROSS REFERENCE TABLE Workorder: 33618 Buncombe Landfill Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID Sample ID Prep Method Prep Batch Analysis Method Analysis Batch 336180001 MW-4 AM20GAX DISG/8235 336180002 MW-6 AM20GAX DISG/8235 336180003 MW-18-78 AM20GAX DISG/8235 336180004 MW-19-75 AM20GAX DISG/8235 336180005 MW-19-110 AM20GAX DISG/8235 336180006 MW-13-132 AM20GAX DISG/8235 336180007 MW-2 AM20GAX DISG/8235 336180008 MW-21-21 AM20GAX DISG/8235 336180009 MW-21-94 AM20GAX DISG/8235 336180010 MW-24-160 AM20GAX DISG/8235 336180001 MW-4 AM23G EDON/4431 336180002 MW-6 AM23G EDON/4431 336180003 MW-18-78 AM23G EDON/4431 336180004 MW-19-75 AM23G EDON/4431 336180005 MW-19-110 AM23G EDON/4431 336180006 MW-13-132 AM23G EDON/4431 336180007 MW-2 AM23G EDON/4431 336180008 MW-21-21 AM23G EDON/4431 336180009 MW-21-94 AM23G EDON/4431 336180010 MW-24-160 AM23G EDON/4431 336180011 MW-4 AM20GAX DISG/8238 336180012 MW-6 AM20GAX DISG/8238 336180013 MW-18-78 AM20GAX DISG/8238 336180014 MW-19-75 AM20GAX DISG/8238 336180015 MW-19-110 AM20GAX DISG/8238 336180016 MW-13-132 AM20GAX DISG/8238 336180018 MW-21-21 AM20GAX DISG/8238 336180019 MW-21-94 AM20GAX DISG/8238 336180020 MW-24-160 AM20GAX DISG/8238 336180017 MW-2 AM20GAX DISG/8241 Report ID: 33618 - 1283034 F` CERTIFICATE OF ANALYSIS "`~ This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 33 of 33 MAIN Chain of Custody Record Shealy Environmental Services, Inc.0 1.9- 106 Vantage Point Drive West Columbia, South Carolina 29172 Telephone No. (803) 791-9700 Fax No. (803) 791-9111 www.shealylab.com Number Client Report to Contact Telephone No. / E-mail Quote No. Pace Analytical - Columbia Lucas Odom 803-206-9537/lodom @ shealylab.com Address Sampler's Signature Analysis (Attach list if more space is needed) Page 106 Vantage Point Dr. X 1 of 1 City State Zip Code O West Columbia SC 29172 Printed Name U Project Name Laboratory Lot Number Closed Buncombe County Landfill Wells � W � Project Number P.0 No. Matrix No of Containers b y -o 0_ Preservative Type o Sample ID / Description Date Time o 0 11 o � o � O o ? �' O � z U O Y Q = Q Remarks / cooler I.D. (Containers for each sample may be combined on one line) U W Z _ _ = Z co CDm ai L.L Q LO 0 MW-4 4/28/2020 1035 G X X X X X VD29085-002 MW-6 4/28/2020 1320 G X X X X VD29085-004 MW-18-78 4/28/2020 1630 G X X X X X VD29085-007 MW-19-75 4/28/2020 1630 G X X X X X VD29085-008 MW-19-110 4/28/2020 1330 G X X X X X VD29085-009 MW-13-132 4/28/2020 1520 G X X X X X VD29085-013 MW-2 4/29/2020 1345 G X X X X X VD29085-019 MW-21-21 4/29/2020 1045 G X X X X X VD29085-022 MW-21-94 4/29/2020 950 G X X X X X VD29085-023 VD29085-025 MW-24-160 4/29/2020 1125 G X X X X X Turn Around Time Required (Prior lab approval required for expedited TAT) Sample Disposal Possible Hazard Identification (List any known hazards in the remarks) )C Requirements X Standard Rush ❑ Return to Client ®Disposal by Lab ❑ Non -Hazardous []Flammable [IS kin Irritant IDS provided D nknown 1. Relinquished by Date Time 1. Received by Date Time A ry /1 / W o t q C; C-) �W h � - 0 �4_jr� ) 2. Relinquished by J Date Time 2. Received by Date Time 3. Relinquished by Date Time 3. Received by Date Time 4. Relinquished by Date Time 4. Laboratory Received by Date Time Note: All samples are retained for four weeks from receipt LAB USE ONLY unless other arrangements are made. Received on Ice (Check) []Y ❑v []ce Pack Receipt Temp. °C Document Number: ME002OW-01 Cooler Receipt Form Client Name: LC' Project:��9 ,r ,µ'7 l',1T�i',Vl .�is2 Lab Work Order: - A. Shipping/Container Information (circle appropriate response) Courier: FedEx UPS USPS Client Other: Air bill Present: 'Ze) No Tracking Number: t.Q L03 3,-1 CC Custody Seal on Cooler/Box Present: Yes No . Seals Intact: Yes No Cooler/Box Packing Material: Bubble Wrap Absorbent Foam Other:_ Type of Ice::: Wet :Blue None Ice Intact: Yes Melted Cooler Temperature:_ Radiation Screened: Yes No Chain of Custody Present: Yes No Comments: B. Laboratory Assignment/Log-in (check appropriate response) Chain of Custody properly filled out Chain of Custody relinquished Sampler Name & Signature on COC Containers intact Were samples in separate bags YES NO N/A Comment Reference non -Conformance Sample container !abets match COC Sample name/date and time collected Sufficient volume provided PAES containers used Are containers properly preserved for the requested testing? (as labeled) If an unknown preservation state, were containers checked? Exception: VOA's coliform If yes, see pH form. Was volume for dissolved testing tielq tilterea, as notea on the COC? Was volume received in a preserved container? Headspace present? Comments: Cooler contents examinede.-,to Dater "� Co received by : / Project Manager Review: Date:' ENV-FRM-PITTS-0006 Rev 00 0 aceAnalytical Report of Analysis Bunnell-Lammons Engineering, Inc. 6004 Ponders Court Greenville, SC 29615 Attention: Andy Alexander Project Name: Closed Buncombe County Landfill Surface Water Project Number: J20-14175-02 Lot Number:VD28083 Date Completed:05/05/2020 N N NO � � J 05/08/2020 9:54 AM Approved and released by: Lab Director - Greenville: Lucas Odom PC. F O 24rA SOA / ANSI National Accreditation Board A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 33 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Bunnell-Lammons Engineering, Inc. Lot Number: VD28083 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Pace policies. Any exceptions to the NELAC standards, the QAMP, SOPS or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 2 of 33 PACE ANALYTICAL SERVICES, LLC Sample Summary Bunnell-Lammons Engineering, Inc. Lot Number: VD28083 Sample Number Sample ID Matrix Date Sampled Date Received 001 SW-1 Aqueous 04/27/20201545 04/28/2020 002 SW-2 Aqueous 04/27/20201525 04/28/2020 003 SW-2A Aqueous 04/27/20201515 04/28/2020 004 SW-3 Aqueous 04/27/20201435 04/28/2020 005 SW-4 Aqueous 04/27/20201500 04/28/2020 (5 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 33 PACE ANALYTICAL SERVICES, LLC Detection Summary Bunnell-Lammons Engineering, Inc. Lot Number: VD28083 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 SW-1 Aqueous Hardness (total) SM 2340C- 12 mg/L 5 001 SW-1 Aqueous Barium 6020B 13 ug/L 7 001 SW-1 Aqueous Lead 6020B 0.37 J ug/L 7 001 SW-1 Aqueous Zinc 6020B 7.2 J ug/L 7 002 SW-2 Aqueous Hardness (total) SM 2340C- 12 mg/L 8 002 SW-2 Aqueous Barium 6020B 14 ug/L 10 002 SW-2 Aqueous Lead 6020B 0.42 J ug/L 10 002 SW-2 Aqueous Zinc 6020B 4.1 J ug/L 10 003 SW-2A Aqueous Hardness (total) SM 2340C- 110 mg/L 11 003 SW-2A Aqueous 1,4-Dioxane 8260D (SIM) 7.9 ug/L 11 003 SW-2A Aqueous Barium 6020B 32 ug/L 13 003 SW-2A Aqueous Nickel 6020B 1.5 J ug/L 13 004 SW-3 Aqueous Hardness (total) SM 2340C- 170 mg/L 14 004 SW-3 Aqueous 1,4-Dioxane 8260D (SIM) 36 ug/L 14 004 SW-3 Aqueous Barium 6020B 110 ug/L 16 004 SW-3 Aqueous Cobalt 6020B 3.1 J ug/L 16 004 SW-3 Aqueous Nickel 6020B 4.8 J ug/L 16 004 SW-3 Aqueous Zinc 6020B 3.0 J ug/L 16 005 SW-4 Aqueous Hardness (total) SM 2340C- 390 mg/L 17 005 SW-4 Aqueous 1,4-Dioxane 8260D (SIM) 61 ug/L 17 005 SW-4 Aqueous Acetone 8260D 5.7 J ug/L 17 005 SW-4 Aqueous Barium 6020B 120 ug/L 19 005 SW-4 Aqueous Cobalt 6020B 11 ug/L 19 005 SW-4 Aqueous Nickel 6020B 21 ug/L 19 005 SW-4 Aqueous Selenium 6020B 1.5 J ug/L 19 (25 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 33 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VD28083-001 Description: SW-1 Matrix: Aqueous Date Sampled:04/27/2020 1545 Date Received:04/28/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Hardness (to) SM 2340C-2011 1 05/05/2020 1035 KFE 52892 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Hardness (total) SM 2340C- 12 10 2.0 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/29/2020 1405 BWS 52410 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 115 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/30/20201525 PAP 52561 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 33 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VD28083-001 Description: SW-1 Matrix: Aqueous Date Sampled:04/27/2020 1545 Date Received:04/28/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/30/20201525 PAP 52561 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 89 70-130 1,2-Dichloroethane-d4 96 70-130 Toluene-d8 101 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/30/2020 1902 BNW 04/29/2020 1605 52428 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 33 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VD28083-001 Description: SW-1 Matrix: Aqueous Date Sampled:04/27/2020 1545 Date Received:04/28/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/30/2020 1902 BNW 04/29/2020 1605 52428 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Barium 7440-39-3 6020B 13 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.37 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 7.2 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 33 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VD28083-002 Description: SW-2 Matrix: Aqueous Date Sampled:04/27/2020 1525 Date Received:04/28/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Hardness (to) SM 2340C-2011 1 05/05/2020 1035 KFE 52892 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Hardness (total) SM 2340C- 12 10 2.0 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/29/2020 1429 BWS 52410 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 114 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/30/20201550 PAP 52561 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 33 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VD28083-002 Description: SW-2 Matrix: Aqueous Date Sampled:04/27/2020 1525 Date Received:04/28/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/30/20201550 PAP 52561 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 89 70-130 1,2-Dichloroethane-d4 95 70-130 Toluene-d8 100 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/30/2020 1920 BNW 04/29/2020 1605 52428 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 33 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VD28083-002 Description: SW-2 Matrix: Aqueous Date Sampled:04/27/2020 1525 Date Received:04/28/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/30/2020 1920 BNW 04/29/2020 1605 52428 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Barium 7440-39-3 6020B 14 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.42 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 4.1 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 33 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VD28083-003 Description: SW-2A Matrix: Aqueous Date Sampled:04/27/2020 1515 Date Received:04/28/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Hardness (to) SM 2340C-2011 1 05/05/2020 1035 KFE 52892 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Hardness (total) SM 2340C- 110 10 2.0 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/29/2020 1454 BWS 52410 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 7.9 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 114 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/30/20201615 PAP 52561 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 33 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VD28083-003 Description: SW-2A Matrix: Aqueous Date Sampled:04/27/2020 1515 Date Received:04/28/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/30/20201615 PAP 52561 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 87 70-130 1,2-Dichloroethane-d4 96 70-130 Toluene-d8 99 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/30/2020 1925 BNW 04/29/2020 1605 52428 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 33 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VD28083-003 Description: SW-2A Matrix: Aqueous Date Sampled:04/27/2020 1515 Date Received:04/28/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/30/2020 1925 BNW 04/29/2020 1605 52428 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Barium 7440-39-3 6020B 32 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 1.5 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 33 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VD28083-004 Description: SW-3 Matrix: Aqueous Date Sampled:04/27/2020 1435 Date Received:04/28/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Hardness (to) SM 2340C-2011 1 05/05/2020 1035 KFE 52892 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Hardness (total) SM 2340C- 170 10 2.0 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/29/2020 1518 BWS 52410 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 36 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 113 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/30/20201640 PAP 52561 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 33 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VD28083-004 Description: SW-3 Matrix: Aqueous Date Sampled:04/27/2020 1435 Date Received:04/28/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/30/20201640 PAP 52561 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 86 70-130 1,2-Dichloroethane-d4 94 70-130 Toluene-d8 99 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/30/2020 1931 BNW 04/29/2020 1605 52428 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of 33 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VD28083-004 Description: SW-3 Matrix: Aqueous Date Sampled:04/27/2020 1435 Date Received:04/28/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/30/2020 1931 BNW 04/29/2020 1605 52428 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Barium 7440-39-3 6020B 110 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 3.1 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 4.8 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.0 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 16 of 33 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VD28083-005 Description: SW-4 Matrix: Aqueous Date Sampled:04/27/2020 1500 Date Received:04/28/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Hardness (to) SM 2340C-2011 1 05/05/2020 1035 KFE 52892 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Hardness (total) SM 2340C- 390 10 2.0 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/29/2020 1543 BWS 52410 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 61 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 116 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/30/20201705 PAP 52561 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 5.7 J 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 17 of 33 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VD28083-005 Description: SW-4 Matrix: Aqueous Date Sampled:04/27/2020 1500 Date Received:04/28/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/30/20201705 PAP 52561 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 91 70-130 1,2-Dichloroethane-d4 101 70-130 Toluene-d8 100 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/30/2020 1937 BNW 04/29/2020 1605 52428 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 18 of 33 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID: VD28083-005 Description: SW-4 Matrix: Aqueous Date Sampled:04/27/2020 1500 Date Received:04/28/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/30/2020 1937 BNW 04/29/2020 1605 52428 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Barium 7440-39-3 6020B 120 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 11 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 21 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 1.5 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 19 of 33 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 20 of 33 Inorganic non-metals - MB Sample ID: VQ52892-001 Matrix: Aqueous Batch: 52892 Analytical Method: SM 2340C-2011 Parameter Result Q Dil LOQ DL Units Analysis Date Hardness (total) ND 1 10 2.0 mg/L 05/05/2020 1035 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 21 of 33 Inorganic non-metals - LCS Sample ID: VQ52892-002 Matrix: Aqueous Batch: 52892 Analytical Method: SM 2340C-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Hardness (total) 100 100 1 100 90-110 05/05/2020 1035 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 22 of 33 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: VQ52410-001 Matrix: Aqueous Batch: 52410 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 04/29/2020 0917 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection Acceptance Q % Rec Limit 112 40-170 P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 23 of 33 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: VQ52410-002 Matrix: Aqueous Batch: 52410 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 45 1 90 70-130 04/29/2020 0816 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection Acceptance Q % Rec Limit 108 40-170 P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 24 of 33 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ52561-001 Matrix: Aqueous Batch: 52561 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 04/30/2020 0948 Acrylonitrile ND 1 20 0.80 ug/L 04/30/2020 0948 Benzene ND 1 1.0 0.40 ug/L 04/30/2020 0948 Bromochloromethane ND 1 1.0 0.40 ug/L 04/30/2020 0948 Bromodichloromethane ND 1 1.0 0.40 ug/L 04/30/2020 0948 Bromoform ND 1 1.0 0.40 ug/L 04/30/2020 0948 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 04/30/2020 0948 2-Butanone (MEK) ND 1 10 2.0 ug/L 04/30/2020 0948 Carbon disulfide ND 1 1.0 0.40 ug/L 04/30/2020 0948 Carbon tetrachloride ND 1 1.0 0.40 ug/L 04/30/2020 0948 Chlorobenzene ND 1 1.0 0.40 ug/L 04/30/2020 0948 Chloroethane ND 1 2.0 0.40 ug/L 04/30/2020 0948 Chloroform ND 1 1.0 0.40 ug/L 04/30/2020 0948 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 04/30/2020 0948 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 04/30/2020 0948 Dibromochloromethane ND 1 1.0 0.40 ug/L 04/30/2020 0948 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 04/30/2020 0948 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 04/30/2020 0948 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 04/30/2020 0948 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 04/30/2020 0948 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 04/30/2020 0948 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 04/30/2020 0948 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 04/30/2020 0948 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 04/30/2020 0948 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 04/30/2020 0948 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 04/30/2020 0948 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 04/30/2020 0948 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 04/30/2020 0948 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 04/30/2020 0948 Ethylbenzene ND 1 1.0 0.40 ug/L 04/30/2020 0948 2-Hexanone ND 1 10 2.0 ug/L 04/30/2020 0948 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 04/30/2020 0948 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 04/30/2020 0948 Methylene chloride ND 1 1.0 0.40 ug/L 04/30/2020 0948 Styrene ND 1 1.0 0.41 ug/L 04/30/2020 0948 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 04/30/2020 0948 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 04/30/2020 0948 Tetrachloroethene ND 1 1.0 0.40 ug/L 04/30/2020 0948 Toluene ND 1 1.0 0.40 ug/L 04/30/2020 0948 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 04/30/2020 0948 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 04/30/2020 0948 Trichloroethene ND 1 1.0 0.40 ug/L 04/30/2020 0948 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 04/30/2020 0948 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 04/30/2020 0948 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 25 of 33 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ52561-001 Matrix: Aqueous Batch: 52561 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 04/30/2020 0948 Vinyl chloride ND 1 1.0 0.40 ug/L 04/30/2020 0948 Xylenes (total) ND 1 1.0 0.40 ug/L 04/30/2020 0948 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 90 70-130 1,2-Dichloroethane-d4 100 70-130 Toluene-d8 97 70-130 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 26 of 33 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ52561-002 Matrix: Aqueous Batch: 52561 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 96 1 96 60-140 04/30/2020 0805 Acrylonitrile 100 100 1 102 70-130 04/30/2020 0805 Benzene 50 46 1 91 70-130 04/30/2020 0805 Bromochloromethane 50 44 1 88 70-130 04/30/2020 0805 Bromodichloromethane 50 46 1 92 70-130 04/30/2020 0805 Bromoform 50 46 1 92 70-130 04/30/2020 0805 Bromomethane (Methyl bromide) 50 45 1 89 70-130 04/30/2020 0805 2-Butanone (MEK) 100 100 1 105 70-130 04/30/2020 0805 Carbon disulfide 50 44 1 88 70-130 04/30/2020 0805 Carbon tetrachloride 50 47 1 93 70-130 04/30/2020 0805 Chlorobenzene 50 44 1 89 70-130 04/30/2020 0805 Chloroethane 50 48 1 96 70-130 04/30/2020 0805 Chloroform 50 45 1 91 70-130 04/30/2020 0805 Chloromethane (Methyl chloride) 50 46 1 93 60-140 04/30/2020 0805 1,2-Dibromo-3-chloropropane (DBCP) 50 49 1 98 70-130 04/30/2020 0805 Dibromochloromethane 50 46 1 93 70-130 04/30/2020 0805 1,2-Dibromoethane (EDB) 50 46 1 93 70-130 04/30/2020 0805 Dibromomethane (Methylene bromide) 50 44 1 89 70-130 04/30/2020 0805 trans- 1,4-Dichloro-2-butene 50 49 1 98 70-130 04/30/2020 0805 1,2-Dichlorobenzene 50 45 1 90 70-130 04/30/2020 0805 1,4-Dichlorobenzene 50 44 1 87 70-130 04/30/2020 0805 1,1-Dichloroethane 50 45 1 91 70-130 04/30/2020 0805 1,2-Dichloroethane 50 46 1 92 70-130 04/30/2020 0805 1,1-Dichloroethene 50 45 1 91 70-130 04/30/2020 0805 cis- 1,2-Dichloroethene 50 45 1 89 70-130 04/30/2020 0805 trans- 1,2-Dichloroethene 50 44 1 88 70-130 04/30/2020 0805 1,2-Dichloropropane 50 46 1 92 70-130 04/30/2020 0805 cis- 1,3-Dichloropropene 50 49 1 98 70-130 04/30/2020 0805 trans- 1,3-Dichloropropene 50 49 1 98 70-130 04/30/2020 0805 Ethylbenzene 50 47 1 94 70-130 04/30/2020 0805 2-Hexanone 100 110 1 107 70-130 04/30/2020 0805 Methyl iodide (lodomethane) 50 44 1 88 70-130 04/30/2020 0805 4-Methyl-2-pentanone 100 100 1 103 70-130 04/30/2020 0805 Methylene chloride 50 43 1 86 70-130 04/30/2020 0805 Styrene 50 49 1 98 70-130 04/30/2020 0805 1,1,1,2-Tetrachloroethane 50 47 1 93 70-130 04/30/2020 0805 1,1,2,2-Tetrachloroethane 50 49 1 97 70-130 04/30/2020 0805 Tetrachloroethene 50 45 1 90 70-130 04/30/2020 0805 Toluene 50 46 1 92 70-130 04/30/2020 0805 1,1,1-Trichloroethane 50 46 1 92 70-130 04/30/2020 0805 1,1,2-Trichloroethane 50 46 1 92 70-130 04/30/2020 0805 Trichloroethene 50 44 1 88 70-130 04/30/2020 0805 Trichlorofluoromethane 50 47 1 95 70-130 04/30/2020 0805 1,2,3-Trichloropropane 50 47 1 94 70-130 04/30/2020 0805 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 27 of 33 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ52561-002 Matrix: Aqueous Batch: 52561 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 46 1 91 60-140 04/30/2020 0805 Vinyl chloride 50 48 1 97 70-130 04/30/2020 0805 Xylenes (total) 100 93 1 93 70-130 04/30/2020 0805 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 89 70-130 1,2-Dichloroethane-d4 92 70-130 Toluene-d8 94 70-130 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 28 of 33 ICP-MS Metals - MB Sample ID: VQ52428-001 Matrix: Aqueous Batch: 52428 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/29/2020 1605 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 04/30/20201711 Arsenic ND 1 2.0 1.3 ug/L 04/30/20201711 Barium ND 1 5.0 1.3 ug/L 04/30/20201711 Beryllium ND 1 0.40 0.15 ug/L 04/30/20201711 Cadmium ND 1 0.50 0.13 ug/L 04/30/20201711 Chromium ND 1 5.0 1.3 ug/L 04/30/20201711 Cobalt ND 1 5.0 1.3 ug/L 04/30/20201711 Copper ND 1 5.0 1.3 ug/L 04/30/20201711 Lead ND 1 1.0 0.25 ug/L 04/30/20201711 Nickel ND 1 5.0 1.3 ug/L 04/30/20201711 Selenium ND 1 5.0 1.3 ug/L 04/30/20201711 Silver ND 1 1.0 0.25 ug/L 04/30/20201711 Thallium ND 1 0.50 0.15 ug/L 04/30/20201711 Vanadium ND 1 5.0 2.5 ug/L 04/30/20201711 Zinc ND 1 10 2.5 ug/L 04/30/20201711 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 29 of 33 ICP-MS Metals - LCS Sample ID: VQ52428-002 Matrix: Aqueous Batch: 52428 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/29/2020 1605 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 98 1 98 80-120 04/30/20201717 Arsenic 100 100 1 105 80-120 04/30/20201717 Barium 100 100 1 103 80-120 04/30/20201717 Beryllium 100 110 1 111 80-120 04/30/20201717 Cadmium 100 100 1 102 80-120 04/30/20201717 Chromium 100 100 1 104 80-120 04/30/20201717 Cobalt 100 100 1 103 80-120 04/30/20201717 Copper 100 110 1 106 80-120 04/30/20201717 Lead 100 110 1 105 80-120 04/30/20201717 Nickel 100 100 1 104 80-120 04/30/20201717 Selenium 100 100 1 104 80-120 04/30/20201717 Silver 100 100 1 100 80-120 04/30/20201717 Thallium 100 100 1 104 80-120 04/30/20201717 Vanadium 100 100 1 101 80-120 04/30/20201717 Zinc 100 110 1 108 80-120 04/30/20201717 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 30 of 33 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 31 of 33 �0 < fo m D >v v CD C 0 °� rn m v� o m N � r r N C) o O � C N 3 Q N co 1 3 n N V C N 0 � CDo� V � CD y 4 o CD oID y T O N n co W V CO w O E3 SHEALY EhJWR4NMENTAL SERVICES, INC, SHEALr hajq of C.Ustodyj?gCorrd ICfi VaWago PloIn; orim *West CaAumbla, 3C 0172 7eiOPhorle NO. 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Was 1h> t� num'�eu lis[�d ar dale coutuinar iala ycs Q to P. so3 1 Sample Prrwir pAtion (NILLSt be el-"PleW Fcr arty saMPIC(s) icicc}rrect] rep' Y R Cued or wi6 hcadsjLwL:.) Satrplc(e r f�1,4eviving will is camp le I 'A y"" reee'VCd "LC0i7eCt]Y PL-4MeJVCdAn %VeM ddiasted aCcor�lir[gty mL ofvircle ore; H2fioq, UNC)3, H{;I, NADII LurirLS Sly y NATime of rlr.su'1�ation NA ]! more ih,�s One preseFyEd re is naedecl, plta5e [tote in the Gornntt�Ftts below. umpre(s) NA WC1e =-Pived u'JtJt buUirep �,6 Jton in diamew, Smxtp]es(S 'IA - wery received Wilk 9"IJ{-> A.5 mgJl (If �J� it ,ro) and were :uflusled aocprdilsgly ir[sxrrJP=e JvccivirlgwitJ15odiam thiosumvei�a',S,()a}with Sisc�,]y ID: NA Sly L=Dde J�Lbcls appI[ed iiy: rikiri ]7ttte; 4i38,'2(�30 Cornrearlts� Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 33 of 33