MO-3418_8608_CA_MRP_20200520

Monitoring Report
Ray's Gulf
NCDEQ Incident #8608
1501 South Mint Street
Charlotte, Mecklenburg County, North Carolina
ATC Project No. 199RAA2001
Submittal Date:
May 20, 2020
Prepared for:
Ray's Amoco
Attn: Mr. Larry Welch
17817 McKee Road
Charlotte, North Carolina 28278
Prepared By:
ATC Associates of North Carolina, P. C.
7606 Whitehall Executive Center Drive, Suite 800
Charlotte, North Carolina, 28273
p: [phone] / f. [phone]
www.atcaroLapservices.com

;ETC
7606 Whitehall Executive Center Drive, Suite 800
Charlotte, NC 28273
Tel: [phone]
Fax: [phone]
ENVIRONMENTAL GEOTECHNICAL www.atcassociates.com
BUILDING SCIENCES • MATERIALS TESTING
LETTER OF TRANSMITTAL
May 20, 2020
TO: FROM:
Ron Taraban Mr. Al Quarles, L.G.
NCDEQ, DWM, UST Section ATC Associates of North Carolina
610 East Center Ave, Suite 301 7606 Whitehall Exec Ctr Dr, Ste 800
Mooresville, NC 28115 Charlotte, NC 28732
PROJECT/SUBJECT INFORMATION:
Project Name: Ray's Gulf, Incident No. 8608
ATC Project No.: 199RAA2001
Address: 1501 South Mint Street
Charlotte, Mecklenburg Co, NC
Submittal Date Description
Report 5/20/2020 Monitoring Report
Comments:
The attached report is associated with a Notice of Regulatory Requirements, dated February
20, 2020, issued by NCDEQ.
Copy to: Mr. Larry Welch, Ray's Amoco, 17817 McKee Road, Charlotte, NC 28278
Signature:

Iff
Ar
NkTc
ATC ASSOCIATES OF NORTH CAROLINA, P.C.
Engineering Individual Solutions
May 20, 2020
Ray's Amoco
Attn: Mr. Larry Welch
17817 McKee Road
Charlotte, North Carolina 28278
Re: Monitoring Report
Ray's Gulf
1501 South Mint Street
Charlotte, Mecklenburg County, North Carolina
NCDEQ Incident #8608
ATC Project #199RAA1902
Dear Mr. Welch:
7606 Whitehall Executive Center Drive
Suite 800
Charlotte, NC 28273
Telephone [phone]
Fax [phone]
www.ategroupservices.com
On behalf of Ray's Amoco, Inc. (Ray's Amoco), ATC Associates of North Carolina, P.C. (ATC),
submits this Monitoring Report for the referenced facility. The report presents investigative
procedures, field activities, and laboratory analytical results for a sampling event conducted in April
2020. If you have any questions or require additional information, please contact our office at (704)
529-3200.
Sincerely,
ATC Associates of North Carolina, P.C.
Erin Greene eQ?arles, P.G.
Project Scientist Senior Project Manager
c: Ron Taraban, NCDEQ, DWM, UST Section, Mooresville Regional Office

Monitoring Report
Ray's Gulf
TABLE OF CONTENTS
May 20, 2020
ATC Project # 199RAA2001
1.0 SITE IDENTIFICATION.................................................................................... I
2.0 EXECUTIVE SUMMARY..................................................................................2
3.0 SITE DESCRIPTION..........................................................................................3
3.1 Site Characterization............................................................................3
3.2 Site Background...................................................................................3
3.3 Site and Regional Geology...................................................................4
3.4 Site and Regional Hydrogeology.......................................................... 5
4.0 RECEPTOR SURVEY........................................................................................6
5.0 MOBILE MULTI -PHASE EXTRACTION EVENT.........................................6
6.0 GROUNDWATER CHARACTERIZATION.................................................... 7
6.1 Groundwater Levels............................................................................. 7
6.2 Groundwater Quality............................................................................ 7
7.0 CONCLUSIONS AND RECOMMENDATIONS..............................................8
TABLES
Table B 1
UST System and Release Information
Table B2
UST Owner/Operator Information
Table B3
Soil Analytical Results
Table B4
Groundwater Analytical Results
Table B5
Water Supply Wells and Other Receptor Information
Table B6
Adjoining Property Owners
Table B7
Groundwater Monitoring Well Information
FIGURES
Figure 1
Site Location Map
Figure 2
Site Map
Figure 3
Groundwater Elevation Contours
Figure 4
Contaminants of Concern
APPENDICES
Appendix A Field Notes
Appendix B MMPE and Waste Disposal Manifest
Appendix C Laboratory Analytical Report

Monitoring Report
Ray's Gulf
1.0 SITE IDENTIFICATION
May 20, 2020
ATC Project # 199RAA2001
1. Site Identification
Date of Report: May 20, 2020
Facility I.D.: 0-014633 UST Incident Number (if known): 8608
Site Risk: Intermediate Site Rank: Unknown Land Use Category: Commercial
Site Name: Ray's Gulf
Site Street Address: 1501South Mint Street (Formerly addressed as 1501 Cliffwood Place)
City/Town: Charlotte Zip Code: 28203 County: Mecklenburg
Description of Geographical Data Point: Former UST Basin
Location Method: Google Earth
Latitude (decimal degrees): 35.219044' Longitude (decimal degrees):-80.860556'
2. Information about Contacts Associated with the Leaking UST System
UST Owner/Operator: Ray's Amoco Inc.
Address: 17817 McKee Road, Charlotte, North Carolina 28278 Tel: [phone]
Property Owner: Beverly Welch c/o Larry Welch
Address: 17817 McKee Road, Charlotte, North Carolina 28278 Tel: [phone]
Property Occupant: Leased for commercial use
Consultant/Contractor: ATC Associates of North Carolina, P.C.
Address: 7606 Whitehall Exec Ctr Dr, Ste 800, Charlotte, NC 28273 Tel: [phone]
Analytical Laboratory: Pace Analytical Services, IL,LC State Certification No. 12
Address: 9800 Kincey Avenue Suite 100, Huntersville, NC Tel: [phone]
3. Information about Release
Date Discovered: May 29, 1990
Estimated Quantity of Release: Unknown
Cause of Release: Unknown
Source of Release (Dispenser/Piping/UST): UST System
Sizes and contents of UST system(s) from which the release occurred: Three (3) 3,000- alg lon
gasoline USTs and one (1) 3,000-gallon Diesel UST.
Criteria Used to Classify Risk: Exceedances of the Gross Contamination Levels in groundwater.
4. Information about the Monitoring Report
Date of MMPE Event: March 30, 2020 —April 4, 2020
Date of Monitoring Well Sampling Event: April 14, 2020
5. Certification �oyp�9n�t��ie,,,
I, Al Quarles, a Professional Geoloig_st for ATC Associates of •x.�► CARQ�,��.,
North Carolina, P.C., do certify that the information contained in 0
this report is correct and accurate to the best of my knowledge. A
SEAL
ATC Associates of North Carolina, P.C. is licensed to practice 1-133
engineering and geology in North Carolina The certification Q�0-,
number of the company or corporation is C-1598 for engineering
and C-294 for geology.

Monitoring Report May 20, 2020
Ray's Gulf ATC Project # 199RAA2001
2.0 EXECUTIVE SUMMARY
ATC Associates of North Carolina, P.C. (ATC) has completed a Monitoring Report (MR), which
included a 96-hour Mobile Multi -Phase Extraction (MMPE) event and groundwater sampling at
the former Ray's Gulf facility. The site is located at 1501 South Mint Street, in Charlotte,
Mecklenburg County, North Carolina. The MR was performed based on the Notice of Regulatory
Requirements (NORR), dated February 20, 2020, and the subsequent Pre -Approval Task
Authorization (PATA-03) by the North Carolina Department of Environmental Quality (NCDEQ),
Division of Waste Management (DWM), Underground Storage Tank (UST) Section.
The site is located at the south corner of South Mint Street and Summit Avenue. As part of the site
activities associated with this MR, ATC subcontracted Advanced Environmental Services
(Advanced) to conduct a 96-hour MMPE event on well MW-1.
Approximately ten days after the MMPE event, the site monitoring wells were gauged for depth to
water, purged of three standing water columns, and sampled. The groundwater samples were
submitted to Pace Analytical Services, LLC (Pace) laboratory in Huntersville, North Carolina, and
analyzed for volatile organic compounds (VOCs) by Standard Method 6200B. The site conditions
based on prior and recent activities are summarized below:
• No water supply wells or surface water bodies have been identified within 1,500 feet of the
site;
• Light non -aqueous phase liquid (LNAPL) was not measured in the wells before or after the
MMPE, nor at the time of sampling. However, during the post-MMPE sampling event a
film of LNAPL was observed in the bailer while purging monitoring well MW-1;
• Approximately 4,782 gallons of water and approximately 15.86 pounds (2.58 gallons) of
VOCs in the vapor phase were removed from MW-1 during the MMPE event. Monitoring
well DMW-1 was connected to the MMPE system for four hours on the second day of the
MMPE event;
• During the MMPE event, groundwater levels in wells MW-2 and MW-3 decreased by 0.6
feet and 5.05 feet, respectively, suggesting groundwater flow toward well MW-1 during the
MMPE event.
• After the MMPE event, the concentration of benzene exceeded the Gross Contamination
Level (GCL) in monitoring well MW-1 and the concentration of methyl tert butyl ether
(MTBE) exceeded the GCL in DMW-1;
• Other contaminants were detected at concentrations exceeding their 2L Standards in all
wells sampled;
• The depth to groundwater ranged from approximately 11.5 to 12 feet below ground surface
(ft-bgs) on April 14, 2020; and
• Groundwater is estimated to flow to the northwest.
The concentrations of benzene in MW-1 increased slightly from the prior sampling event, while
MTBE in DMW-1 increased by approximately 1.7 times from the September 2019 sampling result,
to a concentration slightly higher than that detected in May 30, 2019. The total concentrations of
VOCs in wells MW-1, MW-2, MW-3, and MW-4 decreased by 28%, 45%, 59%, and 36%,
respectively. However, based on the benzene in MW-1 and MTBE in DMW-1, the MMPE alone

Monitoring Report May 20, 2020
Ray's Gulf ATC Project # 199RAA2001
was not effective in reducing concentrations. The LNAPL sheen observed in MW-1 suggests the
presence of residual LNAPL in the subsurface in the area. Note that the depth to groundwater in
well MW-1 has been above the top of the screened interval, by approximately 3.15 to 7.3 feet over
the course of the historical monitoring events. The concentrations of MTBE detected in the deep
monitoring well DMW-1 are higher than those detected in well MW-1 by approximately 14 to 28
times. Based on the results of the recent MMPE and sampling event, ATC recommends additional
assessment prior to conducting additional remedial actions.
3.0 SITE DESCRIPTION
3.1 Site Characterization
ATC, under contract with Ray's Amoco, Inc., the current property owner, provided environmental
services at the former Ray's Gulf facility, located at 1501 South Mint Street, Charlotte,
Mecklenburg County, North Carolina. Figure I depicts the site on a topographic map. Three
buildings currently exist on the property identified by Parcel ID 11908314, including a former
service station building constructed in 1953, a former service station garage constructed in 1955,
and a warehouse constructed in 1957. Municipal water is available to the site and surrounding area
by Charlotte Water.
3.2 Site Background
According to the NCDEQ's registered UST database, three 3,000-gallon gasoline and one 3,000-
gallon diesel USTs were installed on March 5, 1956. According to the April 1990 UST closure
report, the USTs were removed on March 23, 1990; however, note that the UST database
indicates a permanent closure date of January 24, 1990. The former USTs were located in the
area of the current 6,000-gallon gasoline USTs (Figure 2). The UST database also indicates that
the current gasoline USTs and current 6,000-gallon diesel UST were installed in January 1990.
UST system information is included in Table B1. UST owner and operator information is
included in Table B2.
Following removal of the former 3,000-gallon USTs, two soil samples were collected from
beneath each of the four USTs and analyzed for Total Petroleum Hydrocarbons Gasoline and
Diesel Range Organics (TPH-GRO and TPH-DRO, respectively), and for benzene, ethylbenzene,
toluene, and total xylenes. The greatest TPH-GRO and TPH-DRO results were 8,400 milligrams
per kilogram (mg/kg) and 2,700 mg/kg, respectively, with both results associated with the Diesel
UST #4. No soil samples were collected from beneath the four dispensers or associated piping.
In July and August 2018, ATC completed a Phase I Limited Site Assessment (LSA), which
included conducting a receptor survey, installing groundwater monitoring well MW-1, and
collecting soil and groundwater samples for laboratory analysis. The LSA findings indicated
water supply wells or surface water bodies were not identified within 1,500 feet of the source
area. Soil samples collected during the installation of well MW-1 contained naphthalene above
the Soil -to -Groundwater Maximum Soil Contaminant Concentration (MSCC). The groundwater
sample collected from well MW-1 contained benzene at a concentration of 7,720 µg/L, exceeding
the GCL of 5,000 µg/L. Other contaminants were detected at concentrations exceeding 2L
Standards.
3

Monitoring Report May 20, 2020
Ray's Gulf ATC Project # 199RAA2001
In May 2019, ATC completed field activities for a Rapid Risk Assessment (RRA), which included
the installation of monitoring wells MW-2, MW-3, MW-4, and DMW-1, conducting a rising -head
aquifer slug test, and a comprehensive groundwater sampling event. Based on the slug testing
results, the hydraulic conductivity is estimated to be 1.7 feet per day (ft/d) or 6.0x10-4 centimeters
per second (cm/s) and the groundwater flow rate would be approximately 0.13 ft/d or 46 feet per
year, to the northwest. The laboratory analytical results indicated benzene and MTBE were detected
at concentrations exceeding GCLs in wells MW-1 and DMW-1, respectively, and other
contaminants were detected at concentrations exceeding their 2L Standards in all wells sampled.
ATC recommended conducting an aggressive fluid -vapor recovery (AFVR) event to remove
contaminated groundwater and reduce the concentration of petroleum constituents in the
groundwater.
On August 12, 2019, an 8-hour AFVR event was conducted using MW-1 as the extraction well,
with 363 gallons of water removed. The deep monitoring well DMW-1 was connected to the
AFVR system for approximately 30 minutes to ensure a thorough development of the well. The
post-AFVR sampling of the monitoring wells indicated a slight reduction in the benzene
concentration in well MW-1 from 9,750 µg/L to 7,200 µg/L, and a significant reduction in the
MTBE concentration in well DMW-1 from 29,400 µg/L to 17,900 µg/L (less than the GCL).
Based on the reduction in concentrations, an MMPE event was recommended to evaluate further
reduction using a longer total fluid extraction method.
3.3 Site and Regional Geology
The Geologic Map of the Charlotte I' X 2° Quadrangle, North Carolina and South Carolina, by
Richard Goldsmith, et. al. (1988) indicates that the property is located within the Charlotte Belt
of the Piedmont Physiographic Province. Rocks of the Piedmont are crystalline igneous and
metamorphic rocks that were formed during Appalachian mountain building events during the
Paleozoic Era, several hundred million years ago. The rock type beneath the site is reported as
granodiorite and related granitoids, gray, medium -grained, massive to weakly foliated igneous
rock. The shallow subsurface in most areas of the Piedmont contains residual soil overburden,
including structure -free residuum, saprolite, and partially weathered rock (PWR), that derive
from in -place weathering of the crystalline bedrock. Occasional areas containing recent deposits
of alluvium in the uppermost subsurface are found near streams and rivers. Saprolite and PWR
typically contain some relict structures from the original rock material. Depth to rock ranges
from ground surface at occasional outcrops to depths of up to 100 feet in areas of easily
weathered rock.
Soil encountered at the site during installation of monitoring wells MW-1 and DMW-1 consisted of
primarily sandy and silty clays, and sandy silts to a depth of approximately 27 ft-bgs and rock to the
termination depths of 34 ft-bgs and 52 ft-bgs, respectively. Soils encountered during the installation
of wells MW-2 and MW-3 were observed to be primarily clayey silts to depths of 25 and 24.5 ft-
bgs, respectively, where the borings were terminated. Soil encountered during the installation of
well MW-4 consisted of primarily silt, to a depth of approximately 25 ft-bgs, where the boring was
terminated.
4

Monitoring Report May 20, 2020
Ray's Gulf ATC Project # 199RAA2001
3.4 Site and Regional Hydrogeology
The shallow aquifer occurrence varies in depth from ground surface at springs, creeks, and rivers
to as deep as 50 feet or more beneath upland surfaces in some parts of the Piedmont.
Groundwater in the alluvium or unconsolidated residual material, including saprolite and
partially weathered rock (PWR) or regolith, usually behaves as an unconfined, or water table,
aquifer and will yield water with head elevation equivalent to the first elevation where water was
encountered. Permeability varies with lithology and is typically relatively low in residual soils,
with higher permeability in saprolite or PWR due to relict rock texture and variable susceptibility
to weathering exhibited by different minerals in the rock. Groundwater flow in residual soils or
alluvium is usually in rough concurrence with local topographic conditions and is toward local
drainage features.
The bedrock fractures or other planar features generally constitute the bedrock aquifer, with the
surrounding rock material being effectively impermeable. Along with fractures, contacts between
rock bodies probably constitute zones of significant groundwater occurrence in the bedrock. The
surrounding material and overlying residuum tend to make the bedrock aquifer a semi -confined
aquifer. That is, the overlying water and soil weight normally results in pressure that causes
water in a borehole which intersects a fracture or other feature to rise above the elevation of the
fracture or feature. Such features may not occur on predicable trends, at the same elevations, or
even be present or directly connected in separate boreholes. In areas adjacent to creeks the
bedrock groundwater generally discharges to the residuum or alluvium and then into the surface
water. In upland areas away from surface water drainages, the bedrock aquifer is generally
recharged by downward infiltration of residuum aquifer water at locations where fractures
intersect the bedrock surface.
The depth to groundwater was measured to be approximately 15.85 feet below the top of well
casing (TOC) in monitoring well MW-1 on July 18, 2018, following the monitoring well
installation. During the drilling of the boring for the well, there was no apparent indication of
groundwater until 30 to 34 ft-bgs, within the bedrock. Based on historical depth to groundwater
measurements in well MW-1, the static groundwater level has ranged from approximately 3.15
to 7.30 feet above the top of the screen. The depth to groundwater in the shallow monitoring
wells has ranged from approximately 11.4 to 16.6 feet below TOC. The groundwater elevations
in the deeper well DMW-1 have ranged from 0.02 to 0.52 feet deeper than in the shallow well
MW-1, indicating a slight downward component of groundwater flow, with vertical gradients of
0.0048 to 0.022 feet/foot.
For sites in the Piedmont, groundwater flow can be approximated based on topography with the
groundwater surface being a subdued reflection of the land surface. Groundwater flow is
generally from areas of higher topographic elevation (upgradient) to areas of lower topographic
elevation (downgradient). Based on groundwater elevations on April 14, 2020, groundwater flow
is to the northwest, with a horizontal gradient of approximately 0.016 feet/foot. The vertical
gradient between MW-1 and DMW-1 was 0.0048 feet per foot, indicating the horizontal gradient
being approximately 3.1 times that of the vertical gradient.
5

Monitoring Report May 20, 2020
Ray's Gulf ATC Project # 199RAA2001
4.0 RECEPTOR SURVEY
During the Phase I LSA, ATC mailed water supply well forms via certified mail to property
owners identified within 500 feet of the source area by the Mecklenburg County GIS website,
and conducted a visual site reconnaissance within a 1,500 foot radius of the site to identify the
existence of water supply wells or other potential receptors in the area. Based on information
obtained from the receptor survey, no water supply wells were identified during site
reconnaissance or from the returned water supply well forms, as summarized in Table B5. In
addition, no surface water bodies were identified within 1,500 feet of the site.
Properties within 1,500 feet of the site are generally commercial and residential. Properties
adjacent to the site consist of commercial properties to the northwest, north, northeast, and
southwest. A parking lot area is located to the southeast. Adjoining property owners are
documented in Table B6.
5.0 MOBILE MULTI -PHASE EXTRACTION EVENT
Between March 30, 2020 and April 4, 2020, Advanced performed a 96-hour MMPE event, and
ATC personnel provided onsite supervision during startup and shutdown. Monitoring well MW-
1 was used as the target extraction well for the 96-hour MMPE event. Deep well DMW-1 was
also connected to the vacuum for approximately 4 hours to see if a reduction in MTBE could be
achieved similar to that observed following the 8-hour AFVR event.
The monitoring well network (MW-1 through MW-4, and DMW-1) was gauged for liquid levels
with an electronic oil -water interface probe prior to starting the MMPE event. LNAPL was not
detected in any of the wells gauged.
During MMPE activities, a liquid ring vacuum pump unit is plumbed to the designated extraction
points, and a drop pipe is extended into the well through an airtight seal at the TOC and into the
water column. Throughout the MMPE process, a cone of depression forms around the designated
recovery points by drawing down the groundwater surface levels, thus causing impacted water
surrounding the recovery point to be extracted. Petroleum -impacted soil vapor within the cone of
depression and the overlying vadose zone is removed as part of the MMPE extraction process.
The effluent air stream was monitored by Advanced. Organic vapor concentrations ranged from
500 parts per million (ppm) to 3,200 ppm over the course of the event. The MMPE event
removed approximately 4,782 gallons of groundwater and approximately 15.82 pounds (2.58
gallons) of hydrocarbons as vapor.
Upon completion of the MMPE event, liquid levels were gauged in the monitoring well network
immediately after the system was turned off. LNAPL was not detected in any of the wells
gauged. The groundwater levels in wells MW-2 and MW-3 decreased by 0.6 feet and 5.05 feet,
respectively, suggesting groundwater flow toward well MW-1 during the MMPE event. The
decreased groundwater levels in wells MW-2 and MW-3 indicate the radius of influence from
the MMPE event encompassed the area of contamination on site.
6

Monitoring Report May 20, 2020
Ray's Gulf ATC Project # 199RAA2001
Field notes from the MMPE supervision are presented in Appendix A. Information provided by
Advanced, which includes monitoring data and waste disposal manifests is provided in Appendix
B.
6.0 GROUNDWATER CHARACTERIZATION
6.1 Groundwater Levels
On April 14, 2020 monitoring wells MW-1, MW-2, MW-3, MW-4, and DMW-1 were gauged
for depth to groundwater and total well depth. A site map showing the well locations is presented
as Figure 2. An interface probe was used to measure the depth to groundwater from the TOC,
and no LNAPL was indicated in any of the wells. However, while purging well MW-1, an
apparent sheen of LNAPL was observed in the bailer. The measured depth to groundwater in the
shallow wells ranged from 11.60 feet from TOC in well MW-3, to 12.05 feet from TOC in well
MW-4. Based on these measurements, and measured TOC elevations, the shallow groundwater
is estimated to flow to the northwest with a horizontal hydraulic gradient of approximately 0.016
feet per foot. Table B7 summarizes monitoring well construction details, depth to water
measurements, and groundwater elevation calculations. A groundwater contour map is presented
as Figure 3.
6.2 Groundwater Quality
On April 14, 2020, groundwater samples were collected from wells MW-1 through MW-4 and
DMW-1. A three -volume well purge was implemented prior to groundwater sample collection to
ensure the collection of a representative groundwater sample. The groundwater samples were
collected in laboratory -supplied preserved containers; entered into chain -of -custody control; placed
on ice; and shipped to Pace Analytical Services, LLC in Huntersville, North Carolina. The
groundwater samples were analyzed for petroleum constituents including volatile organic
compounds (VOCs) via EPA Method 6200B. The analytical report for groundwater is included in
Appendix C.
Groundwater analytical results are summarized in Table B4. The groundwater analytical results
were compared to the 2L Standards and GCLs, as summarized below.
• The groundwater sample collected from well MW-1 contained benzene at a concentration of
7,250 µg/L, exceeding the GCL of 5,000 µg/L. The concentration increased slightly since
the September 19, 2019 concentration of 7,200 µg/L.
• The groundwater sample from DMW-1 contained MTBE at a concentration of 30,600 µg/L,
greater than the September 13, 2019 concentration of 17,900 µg/L, and slightly higher than
the May 30, 2019 concentration of 29,400 µg/L. The concentrations of MTBE in the deep
monitoring well DMW-1 are higher than those detected in well MW-1 by approximately 14
to 28 times.
• Other contaminants were detected at concentrations exceeding their 2L Standards. The total
concentrations of VOCs in wells MW-1, MW-2, MW-3, and MW-4 decreased by 28%,
45%, 59%, and 36%, respectively.
Based on the benzene in MW-1 and MTBE in DMW-1, the MMPE alone was not effective in
reducing concentrations. The LNAPL sheen observed in MW-1 suggest the presence of residual

Monitoring Report May 20, 2020
Ray's Gulf ATC Project # 199RAA2001
LNAPL in the subsurface in the area. Note that the depth to groundwater in well MW-1 has been
above the top of the screened interval, by approximately 3.15 to 7.3 feet over the course of the
historical monitoring events.
As part of ATC's quality assurance and quality control (QA and QC) measures, a data review of the
laboratory reports was conducted. During the data review, it was found that the samples were
received from the laboratory in acceptable condition and properly preserved. The samples were
analyzed within correct holding times and reported within the lab report, and the chain -of -custody
was properly completed by all parties. The laboratory QC report shows that an internal blank was
analyzed for each method that was used for the original samples. The laboratory fortified blank
(LFB) and laboratory control sample (LCS) data results were also provided for each analytical
method. Refer to the laboratory reports in Appendix C for details regarding QA results for the
laboratory samples and any noted exceptions. Overall, ATC concludes that the laboratory results are
usable and any exceptions do not significantly impact the conclusions presented in this report.
7.0 CONCLUSIONS AND RECOMMENDATIONS
On behalf of Ray's Amoco, Inc., ATC has completed a Monitoring Report for the Ray's Gulf
site, UST Incident Number 8608, which included a 96-hour MMPE event and groundwater
sampling at the former Ray's Gulf facility. The site conditions based on prior and recent activities
are summarized below:
• No water supply wells or surface water bodies have been identified within 1,500 feet of the
site;
• LNAPL was not measured in the wells before or after the MMPE, nor at the time of
sampling. However, during the post MMPE sampling event a film of LNAPL was observed
in the bailer while purging monitoring well MW-1;
• Approximately 4,782 gallons of water and approximately 15.86 pounds (2.58 gallons) of
VOCs in the vapor phase were removed from MW-1 during the MMPE event. Monitoring
well DMW-1 was connected to the MMPE system for four hours on the second day of the
MMPE event;
• During the MMPE event, groundwater levels in wells MW-2 and MW-3 decreased by 0.6
feet and 5.05 feet, respectively, suggesting groundwater flow toward well MW-1 during the
MMPE event.
• The concentration of benzene exceeded the GCL in monitoring well MW-1 and the
concentration of MTBE exceeded the GCL in DMW-1;
• Other contaminants were detected at concentrations exceeding their 2L Standards in all
wells sampled;
• The depth to groundwater ranged from approximately 11.5 to 12 ft-bgs on April 14, 2020;
and
• Groundwater is estimated to flow to the northwest.
Based on the results of the recent MMPE and sampling event, ATC recommends additional
assessment prior to conducting additional remedial actions.
8

TABLES

TABLE B1
UST SYSTEM AND RELEASE INFORMATION
RAY'S GULF
1501 South Mint Street
Charlotte, Mecklenburg County, North Carolina
NCDEQ Incident #8608
UST ID Number
Contents
Capacity
allons
Date Tank Installed
Status of UST
Was Release Associated With UST System?
Y/N
1
Gasoline
3,000
3/5/1956
Removed
Y
2
Gasoline
3,000
3/5/1956
Removed
Y
3
Gasoline
3,000
3/5/1956
Removed
Y
4
Diesel
3,000
3/5/1956
Removed
Y
Al
Gasoline
6,000
1/24/1990
Temporarily Closed
N
A2
Gasoline
6,000
1/24/1990
Temporaril Closed
N
A3
Diesel
6,000
1/24/1990
Temporarily Closed
N
Incident
Material
Date of
Description of Release
Number
Released
Release
8608
Gasoline/Diesel
Unknown
Unknown

TABLE B2
UST OWNER/OPERATOR INFORMATION
RAY'S GULF
1501 South Mint Street
Charlotte, Mecklenburg County, North Carolina
NCDEQ Incident #8608
r
UST ID Number 1,2,3,4
Facility ID Number
0-0-014633
Name of Owner
Dates of Operation
(mm/dd/yy to mm/dd/yy)
Ray's Amoco Inc. - William Welch
3/5/59 to 1/24/90
Street Address
1501 S. Mint Street (Formerly 1501 Cliffwood Place)
City
State
Zip
Telephone Number
Charlotte
INC
28203
jUnknown
Name of Operator
Dates of Operation
(mm/dd/yy to mm/dd/yy)
Ray's Amoco Inc.
04/06/2007 to present
Street Address
1501 S. Mint Street (Formerly 1501 Cliffwood Place)
City
IState
Zip
ITelephone Number
Charlotte
INC
128203
jUnknown
r
UST ID Number Al, A2, A3
Facility ID Number
0-0-014633
Name of Owner
Dates of Operation
(mm/dd/yy to mm/dd/yy)
Ray's Amoco Inc. - William Welch
1/24/90 to present
Street Address
1501 S. Mint Street (Formerly 1501 Cliffwood Place)
City
State
Zip
Telephone Number
Charlotte
INC
28203
jUnknown
Name of Operator
Dates of Operation
(mm/dd/yy to mm/dd/yy)
Ray's Amoco Inc.
1/24/90 to present
Street Address
1501 S. Mint Street (Formerly 1501 Cliffwood Place)
City
IState
Zip
ITelephone Number
Charlotte
INC
128054
jUnknown

TABLE B3
SOIL ANALYTICAL RESULTS
RAY'S GULF
1501 South Mint Street
Charlotte, Mecklenburg County, North Carolina
NCDEQ Incident #8608
d
C
d
C
N
N
N
N
N
N
0
y
N
C
N
y
d
y
N
JZ
N
G1
C
V
R
t '6E
V
f0
N
C
G7
Gf
R
N
t
t
T
—
a
N
R
a
Sample
Sample
Sample
C
�_
T
=
H
E
E
X
Q
Q
�
Q 7
Q
Of
J
N
Depth
m
3
°�
O
v
Q
v
N
ID
(ft b9s)
Date
w
Z
L
v
U
a
N
ai
U
U
EPA
EPA
EPA Method 8260
Method
MADEP VPH/EPH
Method
(ppm)
8270
6010
SS-1
18
7/10/2018
<0.143
0.310
0.511
0.441
0.519
<0.143
3.030
0.943
0.577
ND
60.7
14.4
25
0.62
1633
SS-2
27
7/10/2018
<0.0043
10.0043
<0.0043
10.0043
1 <0.0043
10.0043
<0.0043
10.0043
<0.0085
I ND
<2.7
149.34
23.6
0.66
19.3
MSCC - Soil -to -Groundwater
0.0056
4.3
4.9
0.16
1.70
4.3
8.5
8.3
4.6
Varies
68
540
31
N/A
MSCC- Residential
18
626
1,560
313
626
1,200
782
782
3,129
Varies
939
1,500
469
lil
N/A
MSCC - Industrial/Commercial
164
16,350
40,000
8,176
16,350
32,000
20,440
20,440
81,760
Varies
24,528
40,000
12,264
N/A
Notes:
Concentrations in milligrams per kilogram (mg/kg), except for PID Readings in parts per million (ppm)
PID = Photoionization Detection
MSCC = Maximum Soil Contaminant Concentration
ND = Not Detected
Values in BOLD print indicate levels exceeding the Soil -to -Groundwater MSCCs
ft-bgs = feet below ground surface
N/A = Not Applicable
<# = Less than method reporting limit

TABLE B4
GROUNDWATER ANALYTICAL RESULTS
RAY'S GULF
1501 South Mint Street
Charlotte, North Carolina
NCDEQ Incident #8608
Well ID
Sample
Date
or-
N
W
O
C
N
C
4)
T
�
°
O
s
U
s
a
O
O
N
a
O
n
s
N
n 0
T E
0 7
O` ()
N
�
U
N
y
T
r2
m
O
a
y
'
T
N
N
m o
E O
s
fa0 v
z
N
° u�
y N
s
fa0
z
N
�
C
C
m
Z'
d
3
C
~
N
N
a s
N
L_
N
f
N
N
m
M
L_
N
H
y
N
X
Analytical Method
SM 6200B / EPA Method 625
7/18/2018
7�20
NA
<25.0
<25.0
<25.0
2,300
145
<100
3,110
1,040
908
441
<25.0
5,820
2,910
738
8,600
5/30/2019
9�50
<250
66.8
<25.0
<25.0
3,080
159
<100
1,060
1,050
NA
<25.0
<25.0
8,060
2,830
<25.0
8,450
MW-1
9/13/2019
7�00
<250
185
13.0 J
<25.0
2,900
158
<100
990
1,600
NA
<25.0
<25.0
7,350
4,220
<25.0
10,800
4/14/2020
7�50
<250
<25.0
<25.0
<25.0
1,870
108
<100
2,160
829
NA
<25.0
<25.0
5,540
2,010
<25.0
5,750
5/30/2019
859
<25.0
<1.2
3.9
<1.2
77.6
14.1
<5.0
993
50.9
NA
13.4
<1.2
28.3
57.4
13.6
146
9/13/2019
264
<12.5
<1.2
<1.2
<1.2
108
28.7
<5.0
12.7
235
NA
<1.2
2.7
9.6
233
<1.2
281
MW-2
4/14/2020
175
<1.0
<1.0
<1.0
<1.0
60.8
19.4
<4.0
75.9
142
NA
30.2
<1.0
3.8
127
<1.0
14.4
5/30/2019
95.2
<12.5
2.7
1.2 J
2.1
317
21.2
2.6 J
324
85.9
NA
32.1
<0.62
12.1
262
32.7
322
9/13/2019
167
104
117
<5.0
<5.0
1,370
181
<20.0
11.1
1,600
NA
471
<5.0
71.7
1,290
511
1,790
MW-3
4/14/2020
163
<50.0
<5.0
<5.0
<5.0
841
84.9
<20.0
8.6
468
NA
171
<5.0
11.7
1,110
<5.0
270
5/30/2019
2.6
<25.0
<1.2
<1.2
<1.2
127
49.8
<5.0
1.6 J
196
NA
117
<2.5
32
874
221
597
9/13/2019
<2.5
<25.0
<2.5
<2.5
<2.5
50.8
57.1
<10.0
2.4 J
186
NA
<2.5
<2.5
<2.5
867
261
103
MW-4
4/14/2020
<2.5
<25.0
<2.5
<2.5
<2.5
19.6
24.1
<10.0
<2.5
132
NA
63.3
<2.5
4.0
716
<2.5
15.9
5/30/2019
111 J
<1250
<62.5
<62.5
<62.5
<62.5
<62.5
313 J
29,400
<250
NA
<62.5
<62.5
<62.5
<62.5
<62.5
<125
9/13/2019
<62.5
<625
<62.5
<62.5
<62.5
<62.5
<62.5
<62.5
17,900
<250
NA
<62.5
<62.5
<62.5
<62.5
<62.5
<125
DMW-1
4/14/2020
<125
<1250
<125
<125
<125
<125
<125
<125
30,600
<500
NA
<125
<125
78.1J
<125
<125
<125
2L Standard
1
4,000
1 70
0.4
70
600
70
5
20
6
6
70
70
600
1 400
400
500
GCL
5,000
4,000,000
1 6,900
400
70,000
84,500
25,000
5,000
20,000
6,000
6,000
30,000
70,000
260,000
1 28,500
25,000
85,500
Page 1 of 2

TABLE B4
GROUNDWATER ANALYTICAL RESULTS
RAY'S GULF
1501 South Mint Street
Charlotte, North Carolina
NCDEQ Incident #8608
U
U
V
V
V
2
U
U
r
L:a
E
r
Q
E
L
18
E
Well ID
Sample
a
a
¢
Q
¢
°
¢
e m
¢ o
o m
¢ o
m
v
Date
N 6
C
M
N
N tZ_.
.
J
N
U
U
U
U
tj
U
U
U
Analytical Method
MADEP VPH /EPH
EPA Method 6010
MW-1 1 7/18/2018
28,700
30,700
11,000
3,660
<400
2,330
34,360
13,330
54
2L Standard
400
See Total
See Total
See Total
10,000
See Total
700
200
15
GCL
NE
NE
NE
NE
NE
NE
NE
NE
15,000
Notes:
Values in micrograms per liter (pg/L)
2L Standard = 15A NCAC 02L .0202 Groundwater Quality Standard
GCL = Gross Contamination Level
NA = Not Analyzed
NE = Not Established
Values in BOLD print indicate levels exceeding the 2L Standards
Values in UNDERLINED BOLD print indicate levels exceeding the GCLs
J = Estimated value between the method detection limit and reporting limit.
Page 2 of 2

TABLE B5
WATER SUPPLY WELLS AND OTHER RECEPTOR INFORMATION
RAY'S GULF
1501 South Mint Street
Charlotte, Mecklenburg County, North Carolina
NCDEQ Incident #8608
Distance
Municipal
Well Use
From
Water
Well
Well Owners / Well Users
Property Address
Owner Address
(P/I/N)
Source Area
Connection
(feet)
(Y/N)
NONE IDENTIFIED
Notes:
P / I / N = Potable water supply / Irrigation / Not in use

TABLE B6
ADJOINING PROPERTY OWNERS
RAY'S GULF
1501 South Mint Street
Charlotte, Mecklenburg County, North Carolina
NCDEQ Incident #8608
Figure 2
Tax Parcel
Map Number
Identification
Owner Name
Owner Address
Property Address
Number (PIN)
M
IN
Merrell & Merrell LLC
1430 Montibello Dr., Charlotte, NC 28226
07326233 through
TBH Properties LLC
1430 S Mint St. #102, Charlotte, NC 28203
1430 S. Mint Street
1
07326238
Sage Real Estate Investment Co. LLC
1027 Court Dr., Charlotte, NC 28211
Charlotte, NC 28203
Motus Development LLC
1430-105 S Mint St., Charlotte, NC 28203
1430 S Mint LLC
1430 S Mint St. #106, Charlotte, NC 28203
2
7310103
1445 LLC
1445 S Mint Street, Charlotte, NC 28203
1445 S. Mint Street
Charlotte, NC 28203
3
11908313
Beverly S Welch; c/o Larry Welch
17817 McKee Road, Charlotte, NC 28278
317 W. Summit Avenue
Charlotte, NC 28203
4
11908315
Irish Mac Properties LLC
206 Blue Heron Way, Belmont, NC 28012
1513 S. Mint Street
Charlotte, NC 28203
5
11908218
Dorylu-Mint Place LLC
301 Glenwood Avenue, Suite 280
1508 S. Mint Street
Raleigh, NC 27603
Charlotte, NC 28203

TABLE B7
GROUNDWATER MONITORING WELL INFORMATION
RAY'S GULF
1501 South Mint Street
Charlotte, Mecklenburg, North Carolina
NCDEQ Incident #8608
Well ID
Well
Installation
Date
Total Well
Depth
(ft-bgs)
Screen
Interval
(ft-bgs)
Well
Diameter
(inches)
TOC
Elevation
(ft-relative)
Gauging
Date
Depth to
Groundwater
(ft-TOC)
Groundwater
Elevation
(ft-relative)
MW-1
7/17/2018
34
19 - 34
2
100.00
7/18/2018
15.85
84.15
5/30/2019
11.79
88.22
8/12/2019
13.12
86.88
9/13/2019
13.82
86.18
3/30/2020
11.70
88.30
4/4/2020
22.13
77.87
4/14/2020
11.95
88.05
MW-2
5/24/2019
25
10 - 25
2
100.14
5/30/2019
11.88
88.26
8/12/2019
13.29
86.85
9/13/2019
13.95
86.19
3/30/2020
11.41
88.73
4/4/2020
12.01
88.13
4/14/2020
11.96
88.18
MW-3
5/24/2019
24
9 - 24
2
99.62
5/30/2019
11.52
88.10
8/12/2019
13.18
86.44
9/13/2019
13.63
85.99
3/30/2020
11.50
88.12
4/4/2020
16.55
83.07
4/14/2020
11.60
88.02
Page 1 of 2

TABLE B7
GROUNDWATER MONITORING WELL INFORMATION
RAY'S GULF
1501 South Mint Street
Charlotte, Mecklenburg, North Carolina
NCDEQ Incident #8608
Well ID
Well
Installation
Date
Total Well
Depth
(ft-bgs)
Screen
Interval
(ft-bgs)
Well
Diameter
(inches)
TOC
Elevation
(ft-relative)
Gauging
Date
Depth to
Groundwater
(ft-TOC)
Groundwater
Elevation
(ft-relative)
MW-4
5/24/2019
25
10 - 25
2
101.24
5/30/2019
12.20
89.04
8/12/2019
13.70
87.54
9/13/2019
14.29
86.95
3/30/2020
11.78
89.46
4/14/2020
12.05
89.19
DMW-1
5/24/2019
52
47 - 52
1.5
100.08
5/30/2019
12.38
87.70
8/12/2019
13.70
86.38
9/13/2019
14.24
85.84
3/30/2020
11.80
88.28
4/4/2020
14.52
85.56
4/14/2020
1 12.14
87.94
Notes:
ft-bgs = feet below ground surface
ft-relative = feet relative to an arbitrary site benchmark (well MW-1 TOC)
ft-TOC = feet below monitoring well's top of casing
TOC = Top of Casing
Page 2 of 2

FIGURES

MW-1 MONITORING WELL
"-- Well Identification
DMW-1 TYPE III MONITORING WELL
-- Well Identification
---- SITE PROPERTY LINE
PARCEL LINE
c— GAS
WW— STORM SEWER
0,E— SANITARY SEWER
—T—T— TELECOMMUNICATION
—P—P— PRODUCT PIPING
© UTILITY POLE
NOTE: ALL LOCATIONS ARE APPROXIMATE
Y
r
r:
! A,.
�j11
1%, I%kmm. A6 -
OP
k
* 0 +
/ / \
OP z",
MW-2
cO
/
;� /
MW-3
Z
DISPENSE
/ s
Q
00,
\ \ O
\ C\
\ /
y UST
i BASIN
Zm\ t
SERVICE
` STATION
GARAGE
sR
.`
/' MW-1 +
DMW-1� <'o \ \ UST
BASIN
y C9s�po,\\\ \`\�FC9!\ \ \ ♦ vV�
OR
lie
G/
-�MW 4
G
O G \
y
�yF SITE
R
/
f /
/
} /
ow
df
m
"I �-, .
. -IIA041hy
a
-m
�f
{
4
40
a1
d
m = m cr m o
o a
o U Q U
L
J
W
E O \
z \\
w
a` o
w
w
w
� LL
}
a w
4
C N
C M
o �
0 LL
w
g
a
`o w
L �
J a
m
c �
m
0 Z
>. J
N ` of
3 w U
0
d m w00
N a Z
m m Z M
/j lL (00
z 0<
% Q
. lip Z
F- 0
W
W
Q
U
to 2
Z IX
a �°
(D0o
Lu U) W
H o
U)��U
+ Date:
{ 4 5/20
f '+ L
0 10 20 30 Scale:
AS SHOWN
� � i Figure:
SCALE: 1" = 30'

LEGEND:
MW-1
86.16
MONITORING WELL
Well Identification
Relative Groundwater Elevation (ft)
DMW-1
85.84
TYPE III MONITORING WELL
Well Identification
Relative Groundwater Elevation (ft)
----
SITE PROPERTY LINE
PARCEL LINE
—G—G—
GAS
wW— STORM SEWER
oHE—
SANITARY SEWER
r—T—
TELECOMMUNICATION
—P—P—
PRODUCT PIPING
©
UTILITY POLE
GROUNDWATER ELEVATION CONTOUR
�9.00— (DASHED WHERE INFERRED)
GROUNDWATER FLOW DIRECTION
NOTE: ALL LOCATIONS ARE APPROXIMATE
y
- 1111110", i +
Ilk
Y + ,
y �k
5:)O
G
MW-*
`�/ 88.02
j `/
0 \ DISPENSI
11100,
Q d \ \
\♦
\
\ y `UST
♦
o BASIN
s
t
i
-.,- -4& .
MW-2 `Yh
18o`b \
MW-1
8.05 / \\ \\ Cb•
MW-1 / < �' s \ �� LIST `
\9s oo\ \r BASIN �\
p p\\ \ 9 \
6. \ \ tb.
P
o \�///Sb
m
W IF r S
• N
�00 JV-
E Q
U Q U
■L * i
k
M�
Y
� LL
W
J
W 1
. z
m w
a S
W
Lu
w
C LL
d
* a w
0
C °OV
O M
o a
U N LL
N
w
> o Z
' o nd o
L Q ° W
Co
° c H
�E Q
T E Z
J
c W Q
o coU
w 3 3 w W
N => Q Z
mmo� z�
6611 2 00
z� Nt7 Oz
��k
i
z
l J
LLI O
of
� Q
U
CO T-
.— 1--
0
Z
Imp
LIj � U O
# (n<oU
�#
Date:
5/20
30 0 10 20 30 Scale:
AS SHOWN
Figure: SCALE: 1" = 30' 3

LEGEND:
MW-1 MONITORING WELL
Well Identification
DMW-1 TYPE III MONITORING WELL
Well Identification
-- SITE PROPERTY LINE
PARCEL LINE
—c—c— GAS
—W—W— STORM SEWER
—OHE— SANITARY SEWER
—T—T— TELECOMMUNICATION
—P—P— PRODUCT PIPING
© UTILITY POLE
NOTE: ALL LOCATIONS ARE APPROXIMATE
>
F—
0
--Irv
w�
4
A
�x
low
_7
a
V
MW-3
Sample Date
4/14/2020
Benzene
163
Ethylbenzene
841
Isopropylbenzene
84.9
Naphthalene
468
n-Propylbenzene
171
1,2,4-Trimethylbenzene
1,110
VRI -- , -
DMW-1!
Date 4/14/2020 op
ert-butyl ether 1 30,600
MW-3
DISPENSER
oy
/�
�\ \ o
N y UST
�\ O� BASIN
Oy vvl
•
r ft
qp
J-1
<'�G\\\\s°ltiC\\\\ UST
BASIN
t\\\PO`oo
y
o
K yF\
a
4
a
MW-2
Sample Date
4/14/2020
Benzene
175
Methyl-tert-butyl ether
76
Naphthalene
142
MW-1
Sample Date
4/14/2020
Benzene
7,250
Ethylbenzene
1,870
Isopropylbenzene
108
Methyl-tert-butyl ether
2,160
Naphthalene
829
Toluene
5,540
1,2,4-Trimethylbenzene
2,010
Total Xylenes
5,750
MW-4
Sample Date
4/14/2020
Naphthalene
132
1,2,4-Trimethylbenzene
716
1
io
r
R
V
g w 1
Z LL J 11
w
w
a o
° w
N W
C }
w
d a >O N 0
to
£ O E U
m £ m
g rn \ rn o
M
4 o x d a
ao Z
g
a
a9'E m a
o W
d N c Z3 Q
N N� E N o
y0 U Z V C7 9 N Z
c o a a" d a J
d u1 N c m N O
l0 >.a V'O N
U E o N J N N w Q
3�wccE�viU
m 3 0
6 £ }
� oa � Cl)
a 3 m 3 E w
d N N E U Q O
d 2 m m o 2 u0 ZLu
aiLLmC7»UC7�a�rn
Op
Z N Ili 7 � C) 16 0 Z
NZ
I L
LU
U
Z
O
LL- z
U o
(n _U of
Er Q
U
Z CO =
N Z Zof
�o
Z
w
Z °
U) of
O } o Q
Date:
4 5/20
�, ## 30 0 10 20 30 Scale:
AS SHOWN
+ SCALE: 1" = 30' Figure: 4

APPENDIX A
FIELD NOTES

28
it Location
Project / Client
701 r 1 PC
000
rwsr
S hAJf f A R
Sc and 3� i
A8v0�A1 C 0
Tali �o F ��«fie
coil A I &W
Date 3130lwZV
on
c
Tt✓D SZ
ZLI,$j, ID -US
zH.L9 4 -2L)
�rcorn -0 5� 60��
ton
��' s1 s o-v i�
sfi�-110
„"�- I I i
�L �/ 3Z 24vzo zs
Location CAA iO ��T ✓rDate
Project./Client a Awe Z Df
AD f
/U � Ct./ • v c�
eh

��®��e����������
����e�����������
���
����
�����r��►����
�mae�®®®��������
���w■�������������
z�s��e � ty �
'4
Y-

APPENDIX B
MMPE DATA AND WASTE DISPOSAL MANIFIEST

3 L
ADVANCED
ENVIRONMENTAL SERVICES, INC.
"Your Environmental Solutions Partner"
MOBILE
MULTI -PHASE
EXTRACTION REPORT
Site Location:
Ray's Amoco
1501 South Mint Street
Charlotte, NC
Prepared for:
ATC Group Services, LLC
7606 Whitehall Executive Center Dr. Suite 800
Charlotte, NC 28273
PM — Mr. Al Quarles, PG
April 13, 2020

TABLE OF CONTENTS
EVENT SUMMARY
MMPE FIELD LOG
MASS -REMOVAL CALCULATION
FIELD NOTES
DISPOSAL MANIFESTS

MOBILE MULTI -PHASE EXTRACTION
EVENT SUMMARY
April 13, 2020
Location:
Ray's Amoco
1501 South Mint Street
Charlotte, NC
Client:
ATC Group Services, LLC
7606 Whitehall Executive Center Dr. Suite 800
Charlotte, NC 28273
Event Dates:
March 30 - April 4, 2020
Advanced Job # 03 - 2016
Advanced Personnel:
Scott Crook, Brian Overman and Gary McDaniel
MMPE System:
MMPE system rated 24"hg at 140 CFM
4' discharge stack - 2" diameter
5,000 - gallon tanker
120 ft. piping 2.0" hose to 2 wells
Extraction Well: MW-1 and DMW-1
Well Initial FP / WL(ft) Final FP / WL(ft) Stinger depth(ft) Run Time
/ Changed To
MW-1 11.70 22.13 12/14/21 96.0 hours
DMW-1 11.80 14.52 10 4.0 hours
Description of Event:
The MMPE event ran from 11:15 March 30, through 10:30 April 4, 2020. The MMPE system
was active for 96.0 hours. During the event vacuum at the recovery pump ranged from 15.0 to
22.0 inches of mercury (hg) and stabilized at approximately 21.0 inches of mercury. Airflow
rates ranged from 2,600 to 3,200 feet per minute and stabilized at approximately 2,700 feet per
minute. System temperature ranged from 104 — 134 degrees F and humidity ranged from 64 to 99
percent. Field gauged volatile organic compounds (VOC's) emissions decreased from 3,200 to
1,400 parts per -million (PPM) throughout the event.
Groundwater / Product Mix Recovered:
During the event a total of 4,782 gallons of product/water mix were removed from the site and
properly disposed at a certified North Carolina disposal facility. No free product was observed
in tanker. Total fluids recovered, was measured based on stick readings conducted during and
following the event. Based on 96.0 hours of operation and a total of 4,782 gallons recovered, the
average groundwater recovery rate was calculated to be approximately 49.81 gallons per hour.
Events Results:
Based on mass -removal calculations 15.86 pounds or 2.58 gallons of VOC's were removed as
vapor. Using Dwyer magnehelic gauges, vacuum influence (inches of water) was measured at
monitoring points MW-2 and MW-3. No measurable vacuum influence was identified at any
monitoring point. Maximum draw -down was identified in MW-2 and MW-3 at 0.60 and
5.05 feet respectively. Following the event, no free product was identified in any well.

MMPE FIELD LOG:
CLIENT: ATC
JOB NAME: Ray's Amoco
LOCATION: Charlotte, NC
MMPE EVENT DATES: March 30 - April 4, 2020
EXTRACTION POINTS: MW-1 and DMW-1
AES JOB NUMBER: 03 - 2016
DATE
TIME
FLOW (f/m)
HUM.(%)
TEMP. (F)
VOC's(ppm)
VAC. (hg")
GALLONS
STINGERIWL's
EXTRACTION POINTS (hg")
MW-1
DMW-1
Stinger(ft)
12,14,21
10
Start
11:15
Initial WL's
11.70
11.80
03/30/20
11:40
1 3,200
99.0
118
1,400
20.0
17.0
off-line
12:40
3,100
64.0
134
1,400
20.0
17.0
off-line
16:20
3,100
64.0
134
900
20.0
17.0
off-line
17:20
3,100
64.0
134
850
20.0
224 gal.
17.0
off-line
03/31/20
9:30
3,100
70.0
130
500
20.0
1,005 gal.
17.0
off-line
10:40
2,900
70.0
130
800
21.0
18.0
18.0
14:00
1 2,900
66.0
134
800
21.0
18.0
18.0
17:10
3,000
68.0
132
800
21.0
1,461 gal.
18.0
off-line
04/01/20
9.30
2,900
70.0
132
700
21.0
2,067 gal.
18.0
off-line
10:30
2,900
70.0
132
700
21.0
18.0
off-line
14:30
2,700
68.0
134
900
22.0
19.0
off-line
15:30
2,700
70.0
132
3,200
22.0
2,305 gal.
19.0
off-line
04/02/20
8:10
1 2,700
74.0
130
2,800
22.0
19.0
off-line
9:10
2,700
72.0
132
2,800
22.0
18.0
off-line
04/03/20
12:50
2,600
99.0
104
2,400
17.0
3,787 gal.
15.0
off-line
14:10
2,600
99.0
114
2,100
17.0
15.0
off-line
17:50
2,800
99.0
114
1,900
16.0
14.0
off-line
18:50
2,800
99.0
112
1,900
16.0
14.0
off-line
04/04/20
9.30
2,900
99.0
110
1,400
15.0
4,590 gal.
13.0
off-Iline
End
10:30
Total fluids:
41782 gal.
Final WL's
22.13
14.52
Total free product:
0
DATE
TIME
STINGERIWL's
EXTRACTION POINTS
VACUUM INFLUENCE (h2o")
WELL GAUGING (ft)
MW-2
MW-3
MW-2
MW-3
Start
11:15
Stinge►(ft)
Initial WL's
11.41
11.50
03/30/20
1 16:20
0.00
0.00
03/31/20
10:10
0.00
0.00
11.47
15.50
04/01/20
10:20
0.00
0.00
11.70
16.05
04/02/20
8:00
0.00
0.00
11.72
16.10
04/03/20
12:50
0.00
0.00
11.60
12.70
04/04/20
9:30
0.00
0.00
12.01
16.55
End
10:30

Page 1 of 1
MOBILE MULTI -PHASE EXTRACTION EVENT
SITE NAME: RAY'S AMOCO
CLIENT: ATC
INCIDENT NUMBER:
AVERAGE DEPTH TO GROUNDWATER: 11 - 12 ft.
DESCRIBE SOIL IN THE SATURATED ZONE:
AVERAGE HYDRAULIC CONDUCTIVITY if known):
EXTRACTION WELLS USED FOR MMPE: MW-1 and DMW-1
SPECIFICATIONS OF THE MMPE SYSTEM cfm in H : 140 cfm 24.0"H
DRY STANDARD CUBIC FEET PER MINUTE(DSCFM
AIR FLOW CALCULATIONS Qstd
Date
Hours
Vacuum
Velocity
Pipe ID
Temp
Rel Humid
Water
Water
Qstd
inches of H
ft/min)
(in
°F
%
Vapor %
Vapor Vol%
flow
3/30/20
24.00
20.00
3125.00
2
130
73.0
0.077
0.110
54
3/31/20
48.00
21.00
2975.00
2
132
68.0
0.075
0.107
52
4/1 /20
72.00
21.50
2800.00
2
133
70.0
0.080
0.114
48
4/2/20
1 96.00
1 18.00
1 2729.00
1 2
1 116
1 92.0
1 0.065
0.094
49
4/4/20
NOTES
Qstd = Flow at DSCFM
Vacuum = The level of vacuum being applied should be recorded from the MMPE system inches of H
Velocity = The rate at which air flows is measured at the blower discharge piping (anemometer or pitot tube
Pipe ID = The inside diameter of the blower discharge piping (from the MMPE system)
Temperature = The temperature of the air stream exiting the blower discharge piping (drybulb tem ., in de .°F
Relative humidity = The % relative humidity of the air stream exiting the blower discharge piping
Bwsw = water vapor % by weight, i.e., pounds of water per pound of dry air, derived from the Psychrometric chart (temp Vs relative humidity)
Bws = water vapor % by volume
EQUATIONS
Bws = (Bwsw/18 lb -mole H20)/[(1/28.84 lb -mole dry air) + (13wsw/18 lb -mole H20A
Qstd = (1-Water Vapor)' velocity' (PI * (diameter/24)2)(528°R/(Temp + 460))
EMISSION CALCULATIONS
-Elapsed
Time
Flow
PPMmeasumd
PPMwat
PPMd
K
PPMconc
Cc:m
Cc
PMRc
PM
PMR
hour
DSCFM
m
#C -gas)
m /dsm3
Ib/dscf(lb/hour)
(lb/hour)
(lb)
24
54
1138
1138
1278
1
1278
638
3.9822E-05
0.13
0.15
3.60
48
52
725
725
812
1
812
405
2.5298E-05
0.08
0.09
2.18
72
48
1375
1375
1551
1
1551
774
4.8322E-05
0.14
0.16
3.88
96
49
2186
2186
2414
1
2414
1204
7.5186E-05
0.22
0.26
6.19
Total emissions in pounds
15.86
Total emissions as gallons(pounds 16.152)
2.58
NOTES
PPMmeasumd = Actual measurements (ppm) taken with a OVA or TVA at the blower discharge
piping
PPMWet = "wet" concentration
PPMd = "dry" concentration
K = Number of carbons in calibration as: Methane K = 1, or Propane K = 3, or Hexane K = 6
PPMc= PPM", Volumetric concentration of VOC emissions as carbon, dry basis at STP
Cc.m = mg/dsm3, mass concentration of VOC emissions as carbon
Mc = 12.01 mg/mg-mole, molecular weight of carbon
K3 = 24.07 dsm3/106 mg -mole, mass to volume conversion factor at STP
Cc = Ib/dcsf, mass concentration of VOC emissions as carbon, dry basis at STP
PMRc = Ib/hr, pollutant mass removal rate of VOC's as carbon
PMR = Ib/hr, pollutant mass removal rate of of VOC's as gasoline
PMR = lb, pollutant mass removal of VOC's as gasoline
EQUATIONS
PPMwet = PPMmeasumd
PPMd = (PPMwety(1-Bws)
PPMc = (PPMAK)
Cc:m = (PPMc)(Mc / K3)
Cc = (Cc;m)(62.43x10.9 Ib-m3/mg-ft3)
PMRc = (Cc)(Qstd)(60 minute/hour)
PMR = (PMRc)(M /Mc )
PMR = (PM )(#hours)

MMPE Field Log
Client- /)7-C
Site Name: 2A'i 'S A M o c o
E%traction Webs: mca- 1 Dmcv -
Job Number:
Event Dates: 013a - W/3 �? a
Ta A6A)-T i
D.w .G7/r/$W - / r TUC TA /'..w r.. ..., _ . I"
- . w ry - r N rre- / A.J <
9=5c� Z,<nb/ntilcr �Z�a� Drvtts-i 5ac,rl� — G�ce
__ Al-LL-
Page#_L

MMPE Field Log
Qient: /47
Site Name: I�+i 'S i� r1oc�
Extraction Wells: m w - I , A rnw -
r ascr c
Job Number: 0 3- Z o I CP
Event Dates: 3/3o

MMPE Field Log
Client: Job Number.,53
Site Name:' -, A .> Event Dates: 3/30
ib;thardam P-Ir E>
Page#-2—

NON -HAZARDOUS
1, Generator ID Number
2. Pay 1 of
1
,i,Emevoggv Rea na Phone
/W ZIa 7SYY
4. Waste Trnkin jugb% 7 1
L t
WASTE MANIFEST
S. rAR10C0 Mailing Address
Generators Site Address (t different than mailing address)
iCharic�s kdStreet
NC
Gemandor's Phone:
6. Transpoder 1 Company Name
U S. EPA ID Number
Contamieiant Control, INC.
N C R 0 0
0 1 6 9
3 9 1
7. Transporter 2 Company Name
U.S. EPA ID Number
8. ENTAM1ktMoRfilofem
U.S. EPA ID Number
2811 Lane Parkway
SNialrtuy NC 28146
704 273-1500
N C R 0 0
0 1 0 9
3 9 1
Fad1i's Phone:
10. Containers
11. Total
12. Unit
9. Waste Shipping Name and Description
Quantity
Wt.,Nd.
No.
Type
1.
O
¢
R
0 0 1
TT
!r
G
W
W
2.
3.
4.
13. Special Harding Instructions and Additional Intormalion
14, GENERATOR'SIOFPEROR'S CERTIFICATION: I hereoy dadmit that the contents of this consignment are fully and accurately described above by the proper shipping name, and are classified.
Packaged.
marked and labeledlplecarded, and are in all respects in proper condition for transport acowding to applicable intemerional and national governmental regulations.
GeneratoesrOfferurs PdntediTypad Name
Signature
Month
Day Yea
16, Irrtamationel Shipments ❑ Import 10 U.S.
❑ Expert 1. U.& Port of entrylexit:
z
Trans der Signature for eM2 Lts only):
Date leavinq U.S.:
¢
16, Transporter Acknowledgment of Receipt of Materials
w
Trdnspartec 1 dnletllTyped Na
Sign lure
Month
Day Yea
d
1
i l 4.V'VV e>J
• "2't
aTransporter
2 Printed/Typed Name
Signs
Monti
Day Yea
H
17. Discreparwy
178. Discreparoy Indication Space ❑ Quemoy
❑ Type ❑ Residue
❑ Partial Rejection
ff--11
L!
Furl
17b. Alternate Facility tot Generator)
;i.5. EPA C.
-
U
LL
Facility's Phone:
W
17c. Signature of Alternate Facility (or Generator)
Month
Day Yea!
z
n
WS
O
1& Designated Facility Own Or 2",: Certification of receipt of materials covered by the manifest except as noted in Item 17a
PdnledlTyped N
(�
Sig re
Month
Day Year
I WBLC-O 6 10498 (Rev. Sl
DESIGNATED FACILITY TO GENERAT01

APPENDIX C
LABORATORY ANALYTICAL REPORT

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
April 21, 2020
Erin Greene
ATC Group
7606 Whitehall Executive Cente
Suite 800
Charlotte, NC 28273
RE: Project: Rays Gulf
Pace Project No.: 92473667
Dear Erin Greene:
Enclosed are the analytical results for sample(s) received by the laboratory on April 14, 2020. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor Ezell
[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 33

lacmnalyfica('
www,pacelabs.com
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Project: Rays Gulf
Pace Project No.: 92473667
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Rays Gulf
Pace Project No.: 92473667
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92473667001
MW-1
Water
04/14/2013:15
04/14/2014:35
92473667002
MW-2
Water
04/14/2010:45
04/14/2014:35
92473667003
MW-3
Water
04/14/2010:15
04/14/2014:35
92473667004
MW-4
Water
04/14/20 09:30
04/14/20 14:35
92473667005
DMW-1
Water
04/14/2013:45
04/14/2014:35
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: Rays Gulf
Pace Project No.: 92473667
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
92473667001 MW-1
SM 6200B
SAS
66
PASI-C
92473667002 MW-2
SM 6200B
SAS
66
PASI-C
92473667003 MW-3
SM 6200B
SAS
66
PASI-C
92473667004 MW-4
SM 6200B
SAS
66
PASI-C
92473667005 DMW-1
SM 6200B
SAS
66
PASI-C
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Rays Gulf
Pace Project No.: 92473667
Sample: MW-1
Lab ID:
92473667001
Collected:
04/14/20
13:15
Received: 04/14/20 14:35 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
6200B MSV
Analytical
Method: SM 6200B
Pace Analytical
Services - Charlotte
Benzene
7250
ug/L
25.0
12.0
50
04/17/20 21:45
71-43-2
Bromobenzene
<10.8
ug/L
25.0
10.8
50
04/17/20 21:45
108-86-1
Bromochloromethane
<12.9
ug/L
25.0
12.9
50
04/17/20 21:45
74-97-5
Bromodichloromethane
<9.2
ug/L
25.0
9.2
50
04/17/20 21:45
75-27-4
Bromoform
<20.2
ug/L
25.0
20.2
50
04/17/20 21:45
75-25-2
Bromomethane
<86.0
ug/L
250
86.0
50
04/17/20 21:45
74-83-9 M1
2-Butanone (MEK)
<180
ug/L
250
180
50
04/17/20 21:45
78-93-3
n-Butylbenzene
<17.6
ug/L
25.0
17.6
50
04/17/20 21:45
104-51-8
sec-Butylbenzene
<12.3
ug/L
25.0
12.3
50
04/17/20 21:45
135-98-8
tert-Butyl benzene
<12.5
ug/L
25.0
12.5
50
04/17/20 21:45
98-06-6
Carbon tetrachloride
<11.6
ug/L
25.0
11.6
50
04/17/20 21:45
56-23-5
Chlorobenzene
<11.2
ug/L
25.0
11.2
50
04/17/20 21:45
108-90-7
Chloroethane
<29.2
ug/L
50.0
29.2
50
04/17/20 21:45
75-00-3
Chloroform
<17.6
ug/L
25.0
17.6
50
04/17/20 21:45
67-66-3
Chloromethane
<20.8
ug/L
50.0
20.8
50
04/17/20 21:45
74-87-3
2-Chlorotoluene
<10.4
ug/L
25.0
10.4
50
04/17/20 21:45
95-49-8
4-Chlorotoluene
<10.3
ug/L
25.0
10.3
50
04/17/20 21:45
106-43-4
1,2-Dibromo-3-chloropropane
<19.2
ug/L
50.0
19.2
50
04/17/20 21:45
96-12-8
Dibromochloromethane
<20.1
ug/L
25.0
20.1
50
04/17/20 21:45
124-48-1
1,2-Dibromoethane (EDB)
<11.6
ug/L
25.0
11.6
50
04/17/20 21:45
106-93-4
Dibromomethane
<15.5
ug/L
25.0
15.5
50
04/17/20 21:45
74-95-3
1,2-Dichlorobenzene
<12.0
ug/L
25.0
12.0
50
04/17/20 21:45
95-50-1
1,3-Dichlorobenzene
<12.5
ug/L
25.0
12.5
50
04/17/20 21:45
541-73-1
1,4-Dichlorobenzene
<12.4
ug/L
25.0
12.4
50
04/17/20 21:45
106-46-7
Dichlorodifluoromethane
<14.2
ug/L
25.0
14.2
50
04/17/20 21:45
75-71-8
1,1-Dichloroethane
<12.2
ug/L
25.0
12.2
50
04/17/20 21:45
75-34-3
1,2-Dichloroethane
<13.2
ug/L
25.0
13.2
50
04/17/20 21:45
107-06-2
1,1-Dichloroethene
<10.9
ug/L
25.0
10.9
50
04/17/20 21:45
75-35-4
cis-1,2-Dichloroethene
<10.4
ug/L
25.0
10.4
50
04/17/20 21:45
156-59-2
trans-1,2-Dichloroethene
<12.8
ug/L
25.0
12.8
50
04/17/20 21:45
156-60-5
1,2-Dichloropropane
<9.2
ug/L
25.0
9.2
50
04/17/20 21:45
78-87-5
1,3-Dichloropropane
<17.0
ug/L
25.0
17.0
50
04/17/20 21:45
142-28-9
2,2-Dichloropropane
<14.0
ug/L
25.0
14.0
50
04/17/20 21:45
594-20-7
1,1-Dichloropropene
<17.4
ug/L
25.0
17.4
50
04/17/20 21:45
563-58-6
cis-1,3-Dichloropropene
<17.8
ug/L
25.0
17.8
50
04/17/20 21:45
10061-01-5
trans- 1,3-Dichloropropene
<19.7
ug/L
25.0
19.7
50
04/17/20 21:45
10061-02-6
Diisopropyl ether
<16.7
ug/L
25.0
16.7
50
04/17/20 21:45
108-20-3
Ethylbenzene
1870
ug/L
25.0
12.0
50
04/17/20 21:45
100-41-4
Hexachloro-1,3-butadiene
<60.0
ug/L
100
60.0
50
04/17/20 21:45
87-68-3
2-Hexanone
<30.2
ug/L
250
30.2
50
04/17/20 21:45
591-78-6
Isopropylbenzene (Cumene)
108
ug/L
25.0
11.9
50
04/17/20 21:45
98-82-8
Methylene Chloride
<75.0
ug/L
100
75.0
50
04/17/20 21:45
75-09-2
Methyl-tert-butyl ether
2160
ug/L
25.0
22.2
50
04/17/20 21:45
1634-04-4
Naphthalene
829
ug/L
100
33.0
50
04/17/20 21:45
91-20-3
n-Propylbenzene
<12.0
ug/L
25.0
12.0
50
04/17/20 21:45
103-65-1 M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/21 /2020 02:02 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Rays Gulf
Pace Project No.: 92473667
Sample: MW-1 Lab ID: 92473667001 Collected: 04/14/20 13:15 Received: 04/14/20 14:35 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
6200B MSV
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
<12.8
ug/L
25.0
<21.1
ug/L
25.0
<9.6
ug/L
25.0
<11.6
ug/L
25.0
5540
ug/L
25.0
<39.0
ug/L
100
<21.8
ug/L
100
<13.9
ug/L
25.0
<11.6
ug/L
25.0
<11.6
ug/L
25.0
<16.8
ug/L
50.0
<13.6
ug/L
25.0
2010
ug/L
25.0
<11.4
ug/L
25.0
<20.4
ug/L
50.0
5750
ug/L
50.0
4130
ug/L
50.0
1610
ug/L
25.0
105
%
70-130
100
%
70-130
101
%
70-130
12.8
50
04/17/20 21:45
100-42-5
21.1
50
04/17/20 21:45
630-20-6
9.6
50
04/17/20 21:45
79-34-5
11.6
50
04/17/20 21:45
127-18-4
11.4
50
04/17/20 21:45
108-88-3
39.0
50
04/17/20 21:45
87-61-6
21.8
50
04/17/20 21:45
120-82-1
13.9
50
04/17/20 21:45
71-55-6
11.6
50
04/17/20 21:45
79-00-5
11.6
50
04/17/20 21:45
79-01-6
16.8
50
04/17/20 21:45
75-69-4
13.6
50
04/17/20 21:45
96-18-4
9.6
50
04/17/20 21:45
95-63-6
11.4
50
04/17/20 21:45
108-67-8 M1
20.4
50
04/17/20 21:45
75-01-4
25.0
50
04/17/20 21:45
1330-20-7
22.0
50
04/17/20 21:45
179601-23-1
11.8
50
04/17/20 21:45
95-47-6
50 04/17/20 21:45 17060-07-0
50 04/17/20 21:45 460-00-4
50 04/17/20 21:45 2037-26-5
Sample: MW-2 Lab ID: 92473667002 Collected: 04/14/20 10:45 Received: 04/14/20 14:35 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
6200B MSV
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
n-Butylbenzene
sec-Butylbenzene
tert-Butyl benzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Date: 04/21 /2020 02:02 PM
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
175
ug/L
1.0
<0.43
ug/L
1.0
<0.52
ug/L
1.0
<0.37
ug/L
1.0
<0.81
ug/L
1.0
<3.4
ug/L
10.0
<7.2
ug/L
10.0
<0.71
ug/L
1.0
<0.49
ug/L
1.0
<0.50
ug/L
1.0
<0.46
ug/L
1.0
<0.45
ug/L
1.0
<1.2
ug/L
2.0
<0.71
ug/L
1.0
0.48
2
04/21/20 11:05
71-43-2
0.43
2
04/21/20 11:05
108-86-1
0.52
2
04/21/20 11:05
74-97-5
0.37
2
04/21/20 11:05
75-27-4
0.81
2
04/21/20 11:05
75-25-2
3.4
2
04/21/20 11:05
74-83-9
7.2
2
04/21/20 11:05
78-93-3
0.71
2
04/21/20 11:05
104-51-8
0.49
2
04/21/20 11:05
135-98-8
0.50
2
04/21/20 11:05
98-06-6
0.46
2
04/21/20 11:05
56-23-5
0.45
2
04/21/20 11:05
108-90-7
1.2
2
04/21/20 11:05
75-00-3
0.71
2
04/21/20 11:05
67-66-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Rays Gulf
Pace Project No.: 92473667
Sample: MW-2 Lab ID: 92473667002 Collected: 04/14/20 10:45 Received: 04/14/20 14:35 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Chloromethane
<0.83
ug/L
2.0
0.83
2
04/21/20 11:05
74-87-3
2-Chlorotoluene
<0.41
ug/L
1.0
0.41
2
04/21/20 11:05
95-49-8
4-Chlorotoluene
<0.41
ug/L
1.0
0.41
2
04/21/20 11:05
106-43-4
1,2-Dibromo-3-chloropropane
<0.77
ug/L
2.0
0.77
2
04/21/20 11:05
96-12-8
Dibromochloromethane
<0.80
ug/L
1.0
0.80
2
04/21/20 11:05
124-48-1
1,2-Dibromoethane (EDB)
<0.46
ug/L
1.0
0.46
2
04/21/20 11:05
106-93-4
Dibromomethane
<0.62
ug/L
1.0
0.62
2
04/21/20 11:05
74-95-3
1,2-Dichlorobenzene
<0.48
ug/L
1.0
0.48
2
04/21/20 11:05
95-50-1
1,3-Dichlorobenzene
<0.50
ug/L
1.0
0.50
2
04/21/20 11:05
541-73-1
1,4-Dichlorobenzene
<0.50
ug/L
1.0
0.50
2
04/21/20 11:05
106-46-7
Dichlorodifluoromethane
<0.57
ug/L
1.0
0.57
2
04/21/20 11:05
75-71-8
1,1-Dichloroethane
<0.49
ug/L
1.0
0.49
2
04/21/20 11:05
75-34-3
1,2-Dichloroethane
<0.53
ug/L
1.0
0.53
2
04/21/20 11:05
107-06-2
1,1-Dichloroethene
<0.44
ug/L
1.0
0.44
2
04/21/20 11:05
75-35-4
cis-1,2-Dichloroethene
<0.41
ug/L
1.0
0.41
2
04/21/20 11:05
156-59-2
trans-1,2-Dichloroethene
<0.51
ug/L
1.0
0.51
2
04/21/20 11:05
156-60-5
1,2-Dichloropropane
<0.37
ug/L
1.0
0.37
2
04/21/20 11:05
78-87-5
1,3-Dichloropropane
<0.68
ug/L
1.0
0.68
2
04/21/20 11:05
142-28-9
2,2-Dichloropropane
<0.56
ug/L
1.0
0.56
2
04/21/20 11:05
594-20-7
1,1-Dichloropropene
<0.70
ug/L
1.0
0.70
2
04/21/20 11:05
563-58-6
cis-1,3-Dichloropropene
<0.71
ug/L
1.0
0.71
2
04/21/20 11:05
10061-01-5
trans- 1,3-Dichloropropene
<0.79
ug/L
1.0
0.79
2
04/21/20 11:05
10061-02-6
Diisopropyl ether
<0.67
ug/L
1.0
0.67
2
04/21/20 11:05
108-20-3
Ethylbenzene
60.8
ug/L
1.0
0.48
2
04/21/20 11:05
100-41-4
Hexachloro-1,3-butadiene
<2.4
ug/L
4.0
2.4
2
04/21/20 11:05
87-68-3
2-Hexanone
<1.2
ug/L
10.0
1.2
2
04/21/20 11:05
591-78-6
Isopropylbenzene (Cumene)
19.4
ug/L
1.0
0.48
2
04/21/20 11:05
98-82-8
Methylene Chloride
<3.0
ug/L
4.0
3.0
2
04/21/20 11:05
75-09-2
Methyl-tert-butyl ether
75.9
ug/L
1.0
0.89
2
04/21/20 11:05
1634-04-4
Naphthalene
142
ug/L
4.0
1.3
2
04/21/20 11:05
91-20-3
n-Propylbenzene
30.2
ug/L
1.0
0.48
2
04/21/20 11:05
103-65-1
Styrene
<0.51
ug/L
1.0
0.51
2
04/21/20 11:05
100-42-5
1,1,1,2-Tetrachloroethane
<0.84
ug/L
1.0
0.84
2
04/21/20 11:05
630-20-6
1,1,2,2-Tetrachloroethane
<0.39
ug/L
1.0
0.39
2
04/21/20 11:05
79-34-5
Tetrachloroethene
<0.46
ug/L
1.0
0.46
2
04/21/20 11:05
127-18-4
Toluene
3.8
ug/L
1.0
0.46
2
04/21/20 11:05
108-88-3
1,2,3-Trichlorobenzene
<1.6
ug/L
4.0
1.6
2
04/21/20 11:05
87-61-6
1,2,4-Trichlorobenzene
<0.87
ug/L
4.0
0.87
2
04/21/20 11:05
120-82-1
1,1,1-Trichloroethane
<0.56
ug/L
1.0
0.56
2
04/21/20 11:05
71-55-6
1,1,2-Trichloroethane
<0.46
ug/L
1.0
0.46
2
04/21/20 11:05
79-00-5
Trichloroethene
<0.46
ug/L
1.0
0.46
2
04/21/20 11:05
79-01-6
Trichlorofluoromethane
<0.67
ug/L
2.0
0.67
2
04/21/20 11:05
75-69-4
1,2,3-Trichloropropane
<0.54
ug/L
1.0
0.54
2
04/21/20 11:05
96-18-4
1,2,4-Trimethylbenzene
127
ug/L
1.0
0.39
2
04/21/20 11:05
95-63-6
1,3,5-Trimethylbenzene
<0.45
ug/L
1.0
0.45
2
04/21/20 11:05
108-67-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/21 /2020 02:02 PM without the written consent of Pace Analytical Services, LLC.
Page 7 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Rays Gulf
Pace Project No.: 92473667
Sample: MW-2 Lab ID: 92473667002 Collected: 04/14/20 10:45 Received: 04/14/20 14:35 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
6200B MSV
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
<0.81
ug/L
2.0
14.4
ug/L
2.0
8.8
ug/L
2.0
5.5
ug/L
1.0
107
%
70-130
99
%
70-130
100
%
70-130
0.81
2
04/21/20 11:05
75-01-4
1.0
2
04/21/20 11:05
1330-20-7
0.88
2
04/21/20 11:05
179601-23-1
0.47
2
04/21/20 11:05
95-47-6
2
04/21/20 11:05
17060-07-0
2
04/21/20 11:05
460-00-4
2
04/21/20 11:05
2037-26-5
Sample: MW-3 Lab ID: 92473667003 Collected: 04/14/20 10:15 Received: 04/14/20 14:35 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
6200B MSV
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
n-Butylbenzene
sec-Butylbenzene
tert-Butyl benzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
Date: 04/21 /2020 02:02 PM
Analytical Method: SM 6200B
Pace Analytical Services
- Charlotte
163
ug/L
5.0
2.4
10
04/17/20 21:09
71-43-2
<2.2
ug/L
5.0
2.2
10
04/17/20 21:09
108-86-1
<2.6
ug/L
5.0
2.6
10
04/17/20 21:09
74-97-5
<1.8
ug/L
5.0
1.8
10
04/17/20 21:09
75-27-4
<4.0
ug/L
5.0
4.0
10
04/17/20 21:09
75-25-2
<17.2
ug/L
50.0
17.2
10
04/17/20 21:09
74-83-9
<35.9
ug/L
50.0
35.9
10
04/17/20 21:09
78-93-3
<3.5
ug/L
5.0
3.5
10
04/17/20 21:09
104-51-8
<2.5
ug/L
5.0
2.5
10
04/17/20 21:09
135-98-8
<2.5
ug/L
5.0
2.5
10
04/17/20 21:09
98-06-6
<2.3
ug/L
5.0
2.3
10
04/17/20 21:09
56-23-5
<2.2
ug/L
5.0
2.2
10
04/17/20 21:09
108-90-7
<5.8
ug/L
10.0
5.8
10
04/17/20 21:09
75-00-3
<3.5
ug/L
5.0
3.5
10
04/17/20 21:09
67-66-3
<4.2
ug/L
10.0
4.2
10
04/17/20 21:09
74-87-3
<2.1
ug/L
5.0
2.1
10
04/17/20 21:09
95-49-8
<2.1
ug/L
5.0
2.1
10
04/17/20 21:09
106-43-4
<3.8
ug/L
10.0
3.8
10
04/17/20 21:09
96-12-8
<4.0
ug/L
5.0
4.0
10
04/17/20 21:09
124-48-1
<2.3
ug/L
5.0
2.3
10
04/17/20 21:09
106-93-4
<3.1
ug/L
5.0
3.1
10
04/17/20 21:09
74-95-3
<2.4
ug/L
5.0
2.4
10
04/17/20 21:09
95-50-1
<2.5
ug/L
5.0
2.5
10
04/17/20 21:09
541-73-1
<2.5
ug/L
5.0
2.5
10
04/17/20 21:09
106-46-7
<2.8
ug/L
5.0
2.8
10
04/17/20 21:09
75-71-8
<2.4
ug/L
5.0
2.4
10
04/17/20 21:09
75-34-3
<2.6
ug/L
5.0
2.6
10
04/17/20 21:09
107-06-2
<2.2
ug/L
5.0
2.2
10
04/17/20 21:09
75-35-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Rays Gulf
Pace Project No.: 92473667
Sample: MW-3 Lab ID: 92473667003 Collected: 04/14/20 10:15 Received: 04/14/20 14:35 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
6200B MSV
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
Isopropylbenzene (Cumene)
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
Date: 04/21 /2020 02:02 PM
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
<2.1
ug/L
5.0
2.1
10
04/17/20 21:09
156-59-2
<2.6
ug/L
5.0
2.6
10
04/17/20 21:09
156-60-5
<1.8
ug/L
5.0
1.8
10
04/17/20 21:09
78-87-5
<3.4
ug/L
5.0
3.4
10
04/17/20 21:09
142-28-9
<2.8
ug/L
5.0
2.8
10
04/17/20 21:09
594-20-7
<3.5
ug/L
5.0
3.5
10
04/17/20 21:09
563-58-6
<3.6
ug/L
5.0
3.6
10
04/17/20 21:09
10061-01-5
<3.9
ug/L
5.0
3.9
10
04/17/20 21:09
10061-02-6
<3.3
ug/L
5.0
3.3
10
04/17/20 21:09
108-20-3
841
ug/L
5.0
2.4
10
04/17/20 21:09
100-41-4
<12.0
ug/L
20.0
12.0
10
04/17/20 21:09
87-68-3
<6.0
ug/L
50.0
6.0
10
04/17/20 21:09
591-78-6
84.9
ug/L
5.0
2.4
10
04/17/20 21:09
98-82-8
<15.0
ug/L
20.0
15.0
10
04/17/20 21:09
75-09-2
8.6
ug/L
5.0
4.4
10
04/17/20 21:09
1634-04-4
468
ug/L
20.0
6.6
10
04/17/20 21:09
91-20-3
171
ug/L
5.0
2.4
10
04/17/20 21:09
103-65-1
<2.6
ug/L
5.0
2.6
10
04/17/20 21:09
100-42-5
<4.2
ug/L
5.0
4.2
10
04/17/20 21:09
630-20-6
<1.9
ug/L
5.0
1.9
10
04/17/20 21:09
79-34-5
<2.3
ug/L
5.0
2.3
10
04/17/20 21:09
127-18-4
11.7
ug/L
5.0
2.3
10
04/17/20 21:09
108-88-3
<7.8
ug/L
20.0
7.8
10
04/17/20 21:09
87-61-6
<4.4
ug/L
20.0
4.4
10
04/17/20 21:09
120-82-1
<2.8
ug/L
5.0
2.8
10
04/17/20 21:09
71-55-6
<2.3
ug/L
5.0
2.3
10
04/17/20 21:09
79-00-5
<2.3
ug/L
5.0
2.3
10
04/17/20 21:09
79-01-6
<3.4
ug/L
10.0
3.4
10
04/17/20 21:09
75-69-4
<2.7
ug/L
5.0
2.7
10
04/17/20 21:09
96-18-4
1110
ug/L
5.0
1.9
10
04/17/20 21:09
95-63-6
<2.3
ug/L
5.0
2.3
10
04/17/20 21:09
108-67-8
<4.1
ug/L
10.0
4.1
10
04/17/20 21:09
75-01-4
270
ug/L
10.0
5.0
10
04/17/20 21:09
1330-20-7
237
ug/L
10.0
4.4
10
04/17/20 21:09
179601-23-1
33.2
ug/L
5.0
2.4
10
04/17/20 21:09
95-47-6
105
%
70-130
10
04/17/20 21:09
17060-07-0
101
%
70-130
10
04/17/20 21:09
460-00-4
99
%
70-130
10
04/17/20 21:09
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Rays Gulf
Pace Project No.: 92473667
Sample: MW-4 Lab ID: 92473667004 Collected: 04/14/20 09:30 Received: 04/14/20 14:35 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Benzene
<1.2
ug/L
2.5
1.2
5
04/17/20 20:51
71-43-2
Bromobenzene
<1.1
ug/L
2.5
1.1
5
04/17/20 20:51
108-86-1
Bromochloromethane
<1.3
ug/L
2.5
1.3
5
04/17/20 20:51
74-97-5
Bromodichloromethane
<0.92
ug/L
2.5
0.92
5
04/17/20 20:51
75-27-4
Bromoform
<2.0
ug/L
2.5
2.0
5
04/17/20 20:51
75-25-2
Bromomethane
<8.6
ug/L
25.0
8.6
5
04/17/20 20:51
74-83-9
2-Butanone (MEK)
<18.0
ug/L
25.0
18.0
5
04/17/20 20:51
78-93-3
n-Butylbenzene
<1.8
ug/L
2.5
1.8
5
04/17/20 20:51
104-51-8
sec-Butylbenzene
<1.2
ug/L
2.5
1.2
5
04/17/20 20:51
135-98-8
tert-Butyl benzene
<1.2
ug/L
2.5
1.2
5
04/17/20 20:51
98-06-6
Carbon tetrachloride
<1.2
ug/L
2.5
1.2
5
04/17/20 20:51
56-23-5
Chlorobenzene
<1.1
ug/L
2.5
1.1
5
04/17/20 20:51
108-90-7
Chloroethane
<2.9
ug/L
5.0
2.9
5
04/17/20 20:51
75-00-3
Chloroform
<1.8
ug/L
2.5
1.8
5
04/17/20 20:51
67-66-3
Chloromethane
<2.1
ug/L
5.0
2.1
5
04/17/20 20:51
74-87-3
2-Chlorotoluene
<1.0
ug/L
2.5
1.0
5
04/17/20 20:51
95-49-8
4-Chlorotoluene
<1.0
ug/L
2.5
1.0
5
04/17/20 20:51
106-43-4
1,2-Dibromo-3-chloropropane
<1.9
ug/L
5.0
1.9
5
04/17/20 20:51
96-12-8
Dibromochloromethane
<2.0
ug/L
2.5
2.0
5
04/17/20 20:51
124-48-1
1,2-Dibromoethane (EDB)
<1.2
ug/L
2.5
1.2
5
04/17/20 20:51
106-93-4
Dibromomethane
<1.6
ug/L
2.5
1.6
5
04/17/20 20:51
74-95-3
1,2-Dichlorobenzene
<1.2
ug/L
2.5
1.2
5
04/17/20 20:51
95-50-1
1,3-Dichlorobenzene
<1.2
ug/L
2.5
1.2
5
04/17/20 20:51
541-73-1
1,4-Dichlorobenzene
<1.2
ug/L
2.5
1.2
5
04/17/20 20:51
106-46-7
Dichlorodifluoromethane
<1.4
ug/L
2.5
1.4
5
04/17/20 20:51
75-71-8
1,1-Dichloroethane
<1.2
ug/L
2.5
1.2
5
04/17/20 20:51
75-34-3
1,2-Dichloroethane
0.3
ug/L
2.5
1.3
5
04/17/20 20:51
107-06-2
1,1-Dichloroethene
<1.1
ug/L
2.5
1.1
5
04/17/20 20:51
75-35-4
cis-1,2-Dichloroethene
<1.0
ug/L
2.5
1.0
5
04/17/20 20:51
156-59-2
trans-1,2-Dichloroethene
<1.3
ug/L
2.5
1.3
5
04/17/20 20:51
156-60-5
1,2-Dichloropropane
<0.92
ug/L
2.5
0.92
5
04/17/20 20:51
78-87-5
1,3-Dichloropropane
<1.7
ug/L
2.5
1.7
5
04/17/20 20:51
142-28-9
2,2-Dichloropropane
<1.4
ug/L
2.5
1.4
5
04/17/20 20:51
594-20-7
1,1-Dichloropropene
<1.7
ug/L
2.5
1.7
5
04/17/20 20:51
563-58-6
cis-1,3-Dichloropropene
<1.8
ug/L
2.5
1.8
5
04/17/20 20:51
10061-01-5
trans- 1,3-Dichloropropene
<2.0
ug/L
2.5
2.0
5
04/17/20 20:51
10061-02-6
Diisopropyl ether
<1.7
ug/L
2.5
1.7
5
04/17/20 20:51
108-20-3
Ethylbenzene
19.6
ug/L
2.5
1.2
5
04/17/20 20:51
100-41-4
Hexachloro-1,3-butadiene
<6.0
ug/L
10.0
6.0
5
04/17/20 20:51
87-68-3
2-Hexanone
<3.0
ug/L
25.0
3.0
5
04/17/20 20:51
591-78-6
Isopropylbenzene (Cumene)
24.1
ug/L
2.5
1.2
5
04/17/20 20:51
98-82-8
Methylene Chloride
<7.5
ug/L
10.0
7.5
5
04/17/20 20:51
75-09-2
Methyl-tert-butyl ether
<2.2
ug/L
2.5
2.2
5
04/17/20 20:51
1634-04-4
Naphthalene
132
ug/L
10.0
3.3
5
04/17/20 20:51
91-20-3
n-Propylbenzene
63.3
ug/L
2.5
1.2
5
04/17/20 20:51
103-65-1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/21 /2020 02:02 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Rays Gulf
Pace Project No.: 92473667
Sample: MW-4 Lab ID: 92473667004 Collected: 04/14/20 09:30 Received: 04/14/20 14:35 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
6200B MSV
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
<1.3
ug/L
2.5
<2.1
ug/L
2.5
<0.96
ug/L
2.5
<1.2
ug/L
2.5
4.0
ug/L
2.5
<3.9
ug/L
10.0
<2.2
ug/L
10.0
<1.4
ug/L
2.5
<1.2
ug/L
2.5
<1.2
ug/L
2.5
<1.7
ug/L
5.0
<1.4
ug/L
2.5
716
ug/L
2.5
<1.1
ug/L
2.5
<2.0
ug/L
5.0
15.9
ug/L
5.0
10.7
ug/L
5.0
5.2
ug/L
2.5
104
%
70-130
99
%
70-130
98
%
70-130
1.3
5
04/17/20 20:51
100-42-5
2.1
5
04/17/20 20:51
630-20-6
0.96
5
04/17/20 20:51
79-34-5
1.2
5
04/17/20 20:51
127-18-4
1.1
5
04/17/20 20:51
108-88-3
3.9
5
04/17/20 20:51
87-61-6
2.2
5
04/17/20 20:51
120-82-1
1.4
5
04/17/20 20:51
71-55-6
1.2
5
04/17/20 20:51
79-00-5
1.2
5
04/17/20 20:51
79-01-6
1.7
5
04/17/20 20:51
75-69-4
1.4
5
04/17/20 20:51
96-18-4
0.96
5
04/17/20 20:51
95-63-6
1.1
5
04/17/20 20:51
108-67-8
2.0
5
04/17/20 20:51
75-01-4
2.5
5
04/17/20 20:51
1330-20-7
2.2
5
04/17/20 20:51
179601-23-1
1.2
5
04/17/20 20:51
95-47-6
5 04/17/20 20:51 17060-07-0
5 04/17/20 20:51 460-00-4
5 04/17/20 20:51 2037-26-5
Sample: DMW-1 Lab ID: 92473667005 Collected: 04/14/20 13:45 Received: 04/14/20 14:35 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
6200B MSV
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
n-Butylbenzene
sec-Butylbenzene
tert-Butyl benzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Date: 04/21 /2020 02:02 PM
Analytical Method: SM 6200B
Pace Analytical Services
- Charlotte
<60.0
ug/L
125
60.0
250
04/20/20 19:08
71-43-2
<53.8
ug/L
125
53.8
250
04/20/20 19:08
108-86-1
<64.5
ug/L
125
64.5
250
04/20/20 19:08
74-97-5
<46.2
ug/L
125
46.2
250
04/20/20 19:08
75-27-4
<101
ug/L
125
101
250
04/20/20 19:08
75-25-2
<430
ug/L
1250
430
250
04/20/20 19:08
74-83-9
<898
ug/L
1250
898
250
04/20/20 19:08
78-93-3
<88.2
ug/L
125
88.2
250
04/20/20 19:08
104-51-8
<61.5
ug/L
125
61.5
250
04/20/20 19:08
135-98-8
<62.5
ug/L
125
62.5
250
04/20/20 19:08
98-06-6
<58.0
ug/L
125
58.0
250
04/20/20 19:08
56-23-5
<56.2
ug/L
125
56.2
250
04/20/20 19:08
108-90-7
<146
ug/L
250
146
250
04/20/20 19:08
75-00-3
<88.2
ug/L
125
88.2
250
04/20/20 19:08
67-66-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Rays Gulf
Pace Project No.: 92473667
Sample: DMW-1 Lab ID: 92473667005 Collected: 04/14/20 13:45 Received: 04/14/20 14:35 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Chloromethane
<104
ug/L
250
104
250
04/20/20 19:08
74-87-3
2-Chlorotoluene
<51.8
ug/L
125
51.8
250
04/20/20 19:08
95-49-8
4-Chlorotoluene
<51.5
ug/L
125
51.5
250
04/20/20 19:08
106-43-4
1,2-Dibromo-3-chloropropane
<96.2
ug/L
250
96.2
250
04/20/20 19:08
96-12-8
Dibromochloromethane
<100
ug/L
125
100
250
04/20/20 19:08
124-48-1
1,2-Dibromoethane (EDB)
<57.8
ug/L
125
57.8
250
04/20/20 19:08
106-93-4
Dibromomethane
<77.5
ug/L
125
77.5
250
04/20/20 19:08
74-95-3
1,2-Dichlorobenzene
<60.0
ug/L
125
60.0
250
04/20/20 19:08
95-50-1
1,3-Dichlorobenzene
<62.5
ug/L
125
62.5
250
04/20/20 19:08
541-73-1
1,4-Dichlorobenzene
<62.2
ug/L
125
62.2
250
04/20/20 19:08
106-46-7
Dichlorodifluoromethane
<71.0
ug/L
125
71.0
250
04/20/20 19:08
75-71-8
1,1-Dichloroethane
<61.0
ug/L
125
61.0
250
04/20/20 19:08
75-34-3
1,2-Dichloroethane
<65.8
ug/L
125
65.8
250
04/20/20 19:08
107-06-2
1,1-Dichloroethene
<54.5
ug/L
125
54.5
250
04/20/20 19:08
75-35-4
cis-1,2-Dichloroethene
<51.8
ug/L
125
51.8
250
04/20/20 19:08
156-59-2
trans-1,2-Dichloroethene
<64.2
ug/L
125
64.2
250
04/20/20 19:08
156-60-5
1,2-Dichloropropane
<45.8
ug/L
125
45.8
250
04/20/20 19:08
78-87-5
1,3-Dichloropropane
<85.2
ug/L
125
85.2
250
04/20/20 19:08
142-28-9
2,2-Dichloropropane
<70.2
ug/L
125
70.2
250
04/20/20 19:08
594-20-7
1,1-Dichloropropene
<87.0
ug/L
125
87.0
250
04/20/20 19:08
563-58-6
cis-1,3-Dichloropropene
<89.2
ug/L
125
89.2
250
04/20/20 19:08
10061-01-5
trans- 1,3-Dichloropropene
<98.5
ug/L
125
98.5
250
04/20/20 19:08
10061-02-6
Diisopropyl ether
<83.5
ug/L
125
83.5
250
04/20/20 19:08
108-20-3
Ethylbenzene
<60.0
ug/L
125
60.0
250
04/20/20 19:08
100-41-4
Hexachloro-1,3-butadiene
<300
ug/L
500
300
250
04/20/20 19:08
87-68-3
2-Hexanone
<151
ug/L
1250
151
250
04/20/20 19:08
591-78-6
Isopropylbenzene (Cumene)
<59.5
ug/L
125
59.5
250
04/20/20 19:08
98-82-8
Methylene Chloride
<375
ug/L
500
375
250
04/20/20 19:08
75-09-2
Methyl-tert-butyl ether
30600
ug/L
125
111
250
04/20/20 19:08
1634-04-4
Naphthalene
<165
ug/L
500
165
250
04/20/20 19:08
91-20-3
n-Propylbenzene
<60.2
ug/L
125
60.2
250
04/20/20 19:08
103-65-1
Styrene
<64.0
ug/L
125
64.0
250
04/20/20 19:08
100-42-5
1,1,1,2-Tetrachloroethane
<106
ug/L
125
106
250
04/20/20 19:08
630-20-6
1,1,2,2-Tetrachloroethane
<48.2
ug/L
125
48.2
250
04/20/20 19:08
79-34-5
Tetrachloroethene
<58.0
ug/L
125
58.0
250
04/20/20 19:08
127-18-4
Toluene
78.1J
ug/L
125
57.0
250
04/20/20 19:08
108-88-3
1,2,3-Trichlorobenzene
<195
ug/L
500
195
250
04/20/20 19:08
87-61-6
1,2,4-Trichlorobenzene
<109
ug/L
500
109
250
04/20/20 19:08
120-82-1
1,1,1-Trichloroethane
<69.5
ug/L
125
69.5
250
04/20/20 19:08
71-55-6
1,1,2-Trichloroethane
<58.0
ug/L
125
58.0
250
04/20/20 19:08
79-00-5
Trichloroethene
<58.0
ug/L
125
58.0
250
04/20/20 19:08
79-01-6
Trichlorofluoromethane
<84.0
ug/L
250
84.0
250
04/20/20 19:08
75-69-4
1,2,3-Trichloropropane
<67.8
ug/L
125
67.8
250
04/20/20 19:08
96-18-4
1,2,4-Trimethylbenzene
<48.2
ug/L
125
48.2
250
04/20/20 19:08
95-63-6
1,3,5-Trimethylbenzene
<56.8
ug/L
125
56.8
250
04/20/20 19:08
108-67-8
REPORT OF LABORATORY ANALYSIS
M1
This report shall not be reproduced, except in full,
Date: 04/21 /2020 02:02 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Rays Gulf
Pace Project No.: 92473667
Sample: DMW-1
Lab ID:
92473667005
Collected:
04/14/20 13:45
Received: 04/14/20 14:35 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
6200B MSV
Analytical
Method: SM 6200B
Pace Analytical
Services - Charlotte
Vinyl chloride
<102
ug/L
250
102
250
04/20/20 19:08
75-01-4
Xylene (Total)
<125
ug/L
250
125
250
04/20/20 19:08
1330-20-7
m&p-Xylene
<110
ug/L
250
110
250
04/20/20 19:08
179601-23-1
o-Xylene
<59.2
ug/L
125
59.2
250
04/20/20 19:08
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
105
%
70-130
250
04/20/20 19:08
17060-07-0
4-Bromofluorobenzene (S)
99
%
70-130
250
04/20/20 19:08
460-00-4
Toluene-d8 (S)
103
%
70-130
250
04/20/20 19:08
2037-26-5
Date: 04/21 /2020 02:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Rays Gulf
Pace Project No.: 92473667
QC Batch: 536703 Analysis Method: SM 6200B
QC Batch Method: SM 6200B Analysis Description: 6200E MSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92473667001, 92473667003, 92473667004
METHOD BLANK: 2862958 Matrix:
Associated Lab Samples: 92473667001, 92473667003, 92473667004
Blank
Parameter Units Result
Water
Reporting
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
<0.42
0.50
0.42
04/17/20 16:04
1,1,1-Trichloroethane
ug/L
<0.28
0.50
0.28
04/17/20 16:04
1,1,2,2-Tetrachloroethane
ug/L
<0.19
0.50
0.19
04/17/20 16:04
1,1,2-Trichloroethane
ug/L
<0.23
0.50
0.23
04/17/20 16:04
1,1-Dichloroethane
ug/L
<0.24
0.50
0.24
04/17/20 16:04
1,1-Dichloroethene
ug/L
<0.22
0.50
0.22
04/17/20 16:04
1,1-Dichloropropene
ug/L
<0.35
0.50
0.35
04/17/20 16:04
1,2,3-Trichlorobenzene
ug/L
<0.78
2.0
0.78
04/17/20 16:04
1,2,3-Trichloropropane
ug/L
<0.27
0.50
0.27
04/17/20 16:04
1,2,4-Trichlorobenzene
ug/L
<0.44
2.0
0.44
04/17/20 16:04
1,2,4-Trimethylbenzene
ug/L
<0.19
0.50
0.19
04/17/20 16:04
1,2-Dibromo-3-chloropropane
ug/L
<0.38
1.0
0.38
04/17/20 16:04
1,2-Dibromoethane (EDB)
ug/L
<0.23
0.50
0.23
04/17/20 16:04
1,2-Dichlorobenzene
ug/L
<0.24
0.50
0.24
04/17/20 16:04
1,2-Dichloroethane
ug/L
<0.26
0.50
0.26
04/17/20 16:04
1,2-Dichloropropane
ug/L
<0.18
0.50
0.18
04/17/20 16:04
1,3,5-Trimethylbenzene
ug/L
<0.23
0.50
0.23
04/17/20 16:04
1,3-Dichlorobenzene
ug/L
<0.25
0.50
0.25
04/17/20 16:04
1,3-Dichloropropane
ug/L
<0.34
0.50
0.34
04/17/20 16:04
1,4-Dichlorobenzene
ug/L
<0.25
0.50
0.25
04/17/20 16:04
2,2-Dichloropropane
ug/L
<0.28
0.50
0.28
04/17/20 16:04
2-Butanone (MEK)
ug/L
<3.6
5.0
3.6
04/17/20 16:04
2-Chlorotoluene
ug/L
<0.21
0.50
0.21
04/17/20 16:04
2-Hexanone
ug/L
<0.60
5.0
0.60
04/17/20 16:04
4-Chlorotoluene
ug/L
<0.21
0.50
0.21
04/17/20 16:04
Benzene
ug/L
<0.24
0.50
0.24
04/17/20 16:04
Bromobenzene
ug/L
<0.22
0.50
0.22
04/17/20 16:04
Bromochloromethane
ug/L
<0.26
0.50
0.26
04/17/20 16:04
Bromodichloromethane
ug/L
<0.18
0.50
0.18
04/17/20 16:04
Bromoform
ug/L
<0.40
0.50
0.40
04/17/20 16:04
Bromomethane
ug/L
<1.7
5.0
1.7
04/17/20 16:04
Carbon tetrachloride
ug/L
<0.23
0.50
0.23
04/17/20 16:04
Chlorobenzene
ug/L
<0.22
0.50
0.22
04/17/20 16:04
Chloroethane
ug/L
<0.58
1.0
0.58
04/17/20 16:04
Chloroform
ug/L
<0.35
0.50
0.35
04/17/20 16:04
Chloromethane
ug/L
<0.42
1.0
0.42
04/17/20 16:04
cis-1,2-Dichloroethene
ug/L
<0.21
0.50
0.21
04/17/20 16:04
cis-1,3-Dichloropropene
ug/L
<0.36
0.50
0.36
04/17/20 16:04
Dibromochloromethane
ug/L
<0.40
0.50
0.40
04/17/20 16:04
Dibromomethane
ug/L
<0.31
0.50
0.31
04/17/20 16:04
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/21 /2020 02:02 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Rays Gulf
Pace Project No.: 92473667
METHOD BLANK: 2862958 Matrix:
Associated Lab Samples: 92473667001, 92473667003, 92473667004
Blank
Parameter Units Result
Water
Reporting
Limit
MDL
Analyzed
Dichlorodifluoromethane
ug/L
<0.28
0.50
0.28
04/17/20 16:04
Diisopropyl ether
ug/L
<0.33
0.50
0.33
04/17/20 16:04
Ethylbenzene
ug/L
<0.24
0.50
0.24
04/17/20 16:04
Hexachloro-1,3-butadiene
ug/L
<1.2
2.0
1.2
04/17/20 16:04
Isopropylbenzene (Cumene)
ug/L
<0.24
0.50
0.24
04/17/20 16:04
m&p-Xylene
ug/L
<0.44
1.0
0.44
04/17/20 16:04
Methyl-tert-butyl ether
ug/L
<0.44
0.50
0.44
04/17/20 16:04
Methylene Chloride
ug/L
<1.5
2.0
1.5
04/17/20 16:04
n-Butylbenzene
ug/L
<0.35
0.50
0.35
04/17/20 16:04
n-Propylbenzene
ug/L
<0.24
0.50
0.24
04/17/20 16:04
Naphthalene
ug/L
<0.66
2.0
0.66
04/17/20 16:04
o-Xylene
ug/L
<0.24
0.50
0.24
04/17/20 16:04
sec-Butylbenzene
ug/L
<0.25
0.50
0.25
04/17/20 16:04
Styrene
ug/L
<0.26
0.50
0.26
04/17/20 16:04
tert-Butyl benzene
ug/L
<0.25
0.50
0.25
04/17/20 16:04
Tetrachloroethene
ug/L
<0.23
0.50
0.23
04/17/20 16:04
Toluene
ug/L
<0.23
0.50
0.23
04/17/20 16:04
trans-1,2-Dichloroethene
ug/L
<0.26
0.50
0.26
04/17/20 16:04
trans- 1,3-Dichloropropene
ug/L
<0.39
0.50
0.39
04/17/20 16:04
Trichloroethene
ug/L
<0.23
0.50
0.23
04/17/20 16:04
Trichlorofluoromethane
ug/L
<0.34
1.0
0.34
04/17/20 16:04
Vinyl chloride
ug/L
<0.41
1.0
0.41
04/17/20 16:04
Xylene (Total)
ug/L
<0.50
1.0
0.50
04/17/20 16:04
1,2-Dichloroethane-d4 (S)
%
101
70-130
04/17/20 16:04
4-Bromofluorobenzene (S)
%
99
70-130
04/17/20 16:04
Toluene-d8 (S)
%
103
70-130
04/17/20 16:04
LABORATORY CONTROL SAMPLE:
Parameter
2862959
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1,2-Tetrachloroethane
ug/L
50
54.8
110
60-140
1,1,1-Trichloroethane
ug/L
50
54.9
110
60-140
1,1,2,2-Tetrachloroethane
ug/L
50
47.5
95
60-140
1,1,2-Trichloroethane
ug/L
50
53.7
107
60-140
1,1-Dichloroethane
ug/L
50
48.6
97
60-140
1,1-Dichloroethene
ug/L
50
50.4
101
60-140
1,1-Dichloropropene
ug/L
50
54.8
110
60-140
1,2,3-Trichlorobenzene
ug/L
50
58.2
116
60-140
1,2,3-Trichloropropane
ug/L
50
47.2
94
60-140
1,2,4-Trichlorobenzene
ug/L
50
54.9
110
60-140
1,2,4-Trimethylbenzene
ug/L
50
50.3
101
60-140
1,2-Dibromo-3-chloropropane
ug/L
50
53.1
106
60-140
1,2-Dibromoethane (EDB)
ug/L
50
52.5
105
60-140
1,2-Dichlorobenzene
ug/L
50
52.1
104
60-140
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/21 /2020 02:02 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Rays Gulf
Pace Project No.: 92473667
LABORATORY CONTROL SAMPLE:
Parameter
2862959
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,2-Dichloroethane
ug/L
50
48.8
98
60-140
1,2-Dichloropropane
ug/L
50
48.0
96
60-140
1,3,5-Trimethylbenzene
ug/L
50
51.5
103
60-140
1,3-Dichlorobenzene
ug/L
50
52.0
104
60-140
1,3-Dichloropropane
ug/L
50
49.5
99
60-140
1,4-Dichlorobenzene
ug/L
50
51.6
103
60-140
2,2-Dichloropropane
ug/L
50
54.0
108
60-140
2-Butanone (MEK)
ug/L
100
92.8
93
60-140
2-Chlorotoluene
ug/L
50
51.5
103
60-140
2-Hexanone
ug/L
100
92.9
93
60-140
4-Chlorotoluene
ug/L
50
52.9
106
60-140
Benzene
ug/L
50
51.9
104
60-140
Bromobenzene
ug/L
50
51.1
102
60-140
Bromochloromethane
ug/L
50
53.8
108
60-140
Bromodichloromethane
ug/L
50
51.4
103
60-140
Bromoform
ug/L
50
53.0
106
60-140
Bromomethane
ug/L
50
57.6
115
60-140
Carbon tetrachloride
ug/L
50
59.4
119
60-140
Chlorobenzene
ug/L
50
51.8
104
60-140
Chloroethane
ug/L
50
44.0
88
60-140
Chloroform
ug/L
50
53.3
107
60-140
Chloromethane
ug/L
50
43.4
87
60-140
cis-1,2-Dichloroethene
ug/L
50
49.6
99
60-140
cis-1,3-Dichloropropene
ug/L
50
51.4
103
60-140
Dibromochloromethane
ug/L
50
54.8
110
60-140
Dibromomethane
ug/L
50
53.6
107
60-140
Dichlorodifluoromethane
ug/L
50
54.5
109
60-140
Diisopropyl ether
ug/L
50
48.8
98
60-140
Ethylbenzene
ug/L
50
50.5
101
60-140
Hexachloro-1,3-butadiene
ug/L
50
57.7
115
60-140
Isopropylbenzene (Cumene)
ug/L
50
52.9
106
60-140
m&p-Xylene
ug/L
100
104
104
60-140
Methyl-tert-butyl ether
ug/L
50
48.4
97
60-140
Methylene Chloride
ug/L
50
46.5
93
60-140
n-Butylbenzene
ug/L
50
50.2
100
60-140
n-Propylbenzene
ug/L
50
49.8
100
60-140
Naphthalene
ug/L
50
50.8
102
60-140
o-Xylene
ug/L
50
52.1
104
60-140
sec-Butylbenzene
ug/L
50
50.5
101
60-140
Styrene
ug/L
50
51.7
103
60-140
tert-Butyl benzene
ug/L
50
43.8
88
60-140
Tetrachloroethene
ug/L
50
51.2
102
60-140
Toluene
ug/L
50
50.6
101
60-140
trans-1,2-Dichloroethene
ug/L
50
49.9
100
60-140
trans- 1,3-Dichloropropene
ug/L
50
53.3
107
60-140
Trichloroethene
ug/L
50
54.8
110
60-140
Trichlorofluoromethane
ug/L
50
49.6
99
60-140
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/21 /2020 02:02 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Rays Gulf
Pace Project No.: 92473667
LABORATORY CONTROL SAMPLE:
2862959
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits
Vinyl chloride
ug/L
50 52.5 105
60-140
Xylene (Total)
ug/L
150 156 104
60-140
1,2-Dichloroethane-d4 (S)
%
101
70-130
4-Bromofluorobenzene (S)
%
103
70-130
Toluene-d8 (S)
%
99
70-130
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2864596
MS
92473667001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
2864597
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1, 1, 1,2-Tetrachloroethane
ug/L
<21.1
1000
1000
1200
1150
120
115
60-140
4
30
1,1,1-Trichloroethane
ug/L
<13.9
1000
1000
1240
1300
124
130
60-140
4
30
1,1,2,2-Tetrachloroethane
ug/L
<9.6
1000
1000
1000
1020
100
102
60-140
1
30
1,1,2-Trichloroethane
ug/L
<11.6
1000
1000
1150
1160
115
116
60-140
1
30
1,1-Dichloroethane
ug/L
<12.2
1000
1000
1110
1140
111
114
60-140
3
30
1,1-Dichloroethene
ug/L
<10.9
1000
1000
1110
1190
111
119
60-140
7
30
1,1-Dichloropropene
ug/L
<17.4
1000
1000
1300
1270
130
127
60-140
3
30
1,2,3-Trichlorobenzene
ug/L
<39.0
1000
1000
1330
1150
133
115
60-140
15
30
1,2,3-Trichloropropane
ug/L
<13.6
1000
1000
1060
1050
106
105
60-140
0
30
1,2,4-Trichlorobenzene
ug/L
<21.8
1000
1000
1270
1150
127
115
60-140
10
30
1,2,4-Trimethyl benzene
ug/L
2010
1000
1000
3200
3140
119
113
60-140
2
30
1,2-Dibromo-3-
ug/L
<19.2
1000
1000
1180
1150
118
115
60-140
3
30
chloropropane
1,2-Dibromoethane(EDB)
ug/L
<11.6
1000
1000
1100
1090
110
109
60-140
1
30
1,2-Dichlorobenzene
ug/L
<12.0
1000
1000
1090
1110
109
111
60-140
3
30
1,2-Dichloroethane
ug/L
<13.2
1000
1000
1100
1130
110
113
60-140
3
30
1,2-Dichloropropane
ug/L
<9.2
1000
1000
1090
1070
109
107
60-140
2
30
1,3,5-Trimethyl benzene
ug/L
<11.4
1000
1000
1700
1630
170
163
60-140
4
30 M1
1,3-Dichlorobenzene
ug/L
<12.5
1000
1000
1150
1080
115
108
60-140
6
30
1,3-Dichloropropane
ug/L
<17.0
1000
1000
1050
1040
105
104
60-140
1
30
1,4-Dichlorobenzene
ug/L
<12.4
1000
1000
1120
1100
112
110
60-140
3
30
2,2-Dichloropropane
ug/L
<14.0
1000
1000
1270
1270
127
127
60-140
0
30
2-Butanone (MEK)
ug/L
<180
2000
2000
1850
2110
93
106
60-140
13
30
2-Chlorotoluene
ug/L
<10.4
1000
1000
1190
1170
119
117
60-140
1
30
2-Hexanone
ug/L
<30.2
2000
2000
1990
1980
99
99
60-140
0
30
4-Chlorotoluene
ug/L
<10.3
1000
1000
1170
1130
117
113
60-140
3
30
Benzene
ug/L
7250
1000
1000
8400
8050
115
79
60-140
4
30
Bromobenzene
ug/L
<10.8
1000
1000
1150
1090
115
109
60-140
6
30
Bromochloromethane
ug/L
<12.9
1000
1000
1170
1200
117
120
60-140
3
30
Bromodichloromethane
ug/L
<9.2
1000
1000
1170
1140
117
114
60-140
3
30
Bromoform
ug/L
<20.2
1000
1000
1120
1080
112
108
60-140
3
30
Bromomethane
ug/L
<86.0
1000
1000
1610
1580
161
158
60-140
1
30 M1
Carbon tetrachloride
ug/L
<11.6
1000
1000
1350
1350
135
135
60-140
0
30
Chlorobenzene
ug/L
<11.2
1000
1000
1120
1100
112
110
60-140
1
30
Chloroethane
ug/L
<29.2
1000
1000
1070
1070
107
107
60-140
0
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/21 /2020 02:02 PM without the written consent of Pace Analytical Services, LLC.
Page 17 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Rays Gulf
Pace Project No.: 92473667
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2864596
MS
92473667001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
2864597
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
Chloroform
ug/L
<17.6
1000
1000
1180
1150
118
115
60-140
2
30
Chloromethane
ug/L
<20.8
1000
1000
972
1000
97
100
60-140
3
30
cis-1,2-Dichloroethene
ug/L
<10.4
1000
1000
1140
1160
114
116
60-140
1
30
cis-1,3-Dichloropropene
ug/L
<17.8
1000
1000
1180
1120
118
112
60-140
5
30
Dibromochloromethane
ug/L
<20.1
1000
1000
1170
1180
117
118
60-140
1
30
Dibromomethane
ug/L
<15.5
1000
1000
1230
1180
123
118
60-140
4
30
Dichlorodifluoromethane
ug/L
<14.2
1000
1000
1000
990
100
99
60-140
1
30
Diisopropyl ether
ug/L
<16.7
1000
1000
1060
1090
106
109
60-140
2
30
Ethylbenzene
ug/L
1870
1000
1000
3030
2940
116
107
60-140
3
30
Hexachloro-1,3-butadiene
ug/L
<60.0
1000
1000
1340
1200
134
120
60-140
11
30
Isopropylbenzene
ug/L
108
1000
1000
1280
1240
117
114
60-140
3
30
(Cumene)
m&p-Xylene
ug/L
4130
2000
2000
6550
6400
121
114
60-140
2
30
Methyl-tert-butyl ether
ug/L
2160
1000
1000
3340
3460
118
130
60-140
4
30
Methylene Chloride
ug/L
<75.0
1000
1000
1060
1070
101
102
60-140
1
30
n-Butylbenzene
ug/L
<17.6
1000
1000
1230
1180
123
118
60-140
4
30
n-Propylbenzene
ug/L
<12.0
1000
1000
1440
1370
144
137
60-140
5
30 M1
Naphthalene
ug/L
829
1000
1000
2040
2000
121
117
60-140
2
30
o-Xylene
ug/L
1610
1000
1000
2780
2730
116
112
60-140
2
30
sec-Butylbenzene
ug/L
<12.3
1000
1000
1150
1090
115
109
60-140
5
30
Styrene
ug/L
<12.8
1000
1000
1070
1090
107
109
60-140
2
30
tert-Butylbenzene
ug/L
<12.5
1000
1000
979
953
98
95
60-140
3
30
Tetrachloroethene
ug/L
<11.6
1000
1000
1110
1100
111
110
60-140
0
30
Toluene
ug/L
5540
1000
1000
6720
6520
118
98
60-140
3
30
trans-1,2-Dichloroethene
ug/L
<12.8
1000
1000
1160
1180
116
118
60-140
2
30
trans-1,3-Dichloropropene
ug/L
<19.7
1000
1000
1170
1180
117
118
60-140
1
30
Trichloroethene
ug/L
<11.6
1000
1000
1190
1220
119
122
60-140
2
30
Trichlorofluoromethane
ug/L
<16.8
1000
1000
1150
1160
115
116
60-140
1
30
Vinyl chloride
ug/L
<20.4
1000
1000
1170
1160
117
116
60-140
1
30
Xylene (Total)
ug/L
5750
3000
3000
9330
9130
119
113
60-140
2
30
1,2-Dichloroethane-d4 (S)
%
103
108
70-130
4-Bromofluorobenzene (S)
%
100
100
70-130
Toluene-d8 (S)
%
100
100
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/21 /2020 02:02 PM without the written consent of Pace Analytical Services, LLC.
Page 18 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Rays Gulf
Pace Project No.: 92473667
QC Batch: 537146 Analysis Method: SM 6200B
QC Batch Method: SM 6200B Analysis Description: 6200E MSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92473667005
METHOD BLANK: 2864931
Associated Lab Samples: 92473667005
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
<0.42
0.50
0.42
04/20/20 11:57
1,1,1-Trichloroethane
ug/L
<0.28
0.50
0.28
04/20/20 11:57
1,1,2,2-Tetrachloroethane
ug/L
<0.19
0.50
0.19
04/20/20 11:57
1,1,2-Trichloroethane
ug/L
<0.23
0.50
0.23
04/20/20 11:57
1,1-Dichloroethane
ug/L
<0.24
0.50
0.24
04/20/20 11:57
1,1-Dichloroethene
ug/L
<0.22
0.50
0.22
04/20/20 11:57
1,1-Dichloropropene
ug/L
<0.35
0.50
0.35
04/20/20 11:57
1,2,3-Trichlorobenzene
ug/L
<0.78
2.0
0.78
04/20/20 11:57
1,2,3-Trichloropropane
ug/L
<0.27
0.50
0.27
04/20/20 11:57
1,2,4-Trichlorobenzene
ug/L
<0.44
2.0
0.44
04/20/20 11:57
1,2,4-Trimethylbenzene
ug/L
<0.19
0.50
0.19
04/20/20 11:57
1,2-Dibromo-3-chloropropane
ug/L
<0.38
1.0
0.38
04/20/20 11:57
1,2-Dibromoethane (EDB)
ug/L
<0.23
0.50
0.23
04/20/20 11:57
1,2-Dichlorobenzene
ug/L
<0.24
0.50
0.24
04/20/20 11:57
1,2-Dichloroethane
ug/L
<0.26
0.50
0.26
04/20/20 11:57
1,2-Dichloropropane
ug/L
<0.18
0.50
0.18
04/20/20 11:57
1,3,5-Trimethylbenzene
ug/L
<0.23
0.50
0.23
04/20/20 11:57
1,3-Dichlorobenzene
ug/L
<0.25
0.50
0.25
04/20/20 11:57
1,3-Dichloropropane
ug/L
<0.34
0.50
0.34
04/20/20 11:57
1,4-Dichlorobenzene
ug/L
<0.25
0.50
0.25
04/20/20 11:57
2,2-Dichloropropane
ug/L
<0.28
0.50
0.28
04/20/20 11:57
2-Butanone (MEK)
ug/L
<3.6
5.0
3.6
04/20/20 11:57
2-Chlorotoluene
ug/L
<0.21
0.50
0.21
04/20/20 11:57
2-Hexanone
ug/L
<0.60
5.0
0.60
04/20/20 11:57
4-Chlorotoluene
ug/L
<0.21
0.50
0.21
04/20/20 11:57
Benzene
ug/L
<0.24
0.50
0.24
04/20/20 11:57
Bromobenzene
ug/L
<0.22
0.50
0.22
04/20/20 11:57
Bromochloromethane
ug/L
<0.26
0.50
0.26
04/20/20 11:57
Bromodichloromethane
ug/L
<0.18
0.50
0.18
04/20/20 11:57
Bromoform
ug/L
<0.40
0.50
0.40
04/20/20 11:57
Bromomethane
ug/L
<1.7
5.0
1.7
04/20/20 11:57
Carbon tetrachloride
ug/L
<0.23
0.50
0.23
04/20/20 11:57
Chlorobenzene
ug/L
<0.22
0.50
0.22
04/20/20 11:57
Chloroethane
ug/L
<0.58
1.0
0.58
04/20/20 11:57
Chloroform
ug/L
<0.35
0.50
0.35
04/20/20 11:57
Chloromethane
ug/L
<0.42
1.0
0.42
04/20/20 11:57
cis-1,2-Dichloroethene
ug/L
<0.21
0.50
0.21
04/20/20 11:57
cis-1,3-Dichloropropene
ug/L
<0.36
0.50
0.36
04/20/20 11:57
Dibromochloromethane
ug/L
<0.40
0.50
0.40
04/20/20 11:57
Dibromomethane
ug/L
<0.31
0.50
0.31
04/20/20 11:57
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/21 /2020 02:02 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Rays Gulf
Pace Project No.: 92473667
METHOD BLANK: 2864931
Associated Lab Samples: 92473667005
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Dichlorodifluoromethane
ug/L
<0.28
0.50
0.28
04/20/20 11:57
Diisopropyl ether
ug/L
<0.33
0.50
0.33
04/20/20 11:57
Ethylbenzene
ug/L
<0.24
0.50
0.24
04/20/20 11:57
Hexachloro-1,3-butadiene
ug/L
<1.2
2.0
1.2
04/20/20 11:57
Isopropylbenzene (Cumene)
ug/L
<0.24
0.50
0.24
04/20/20 11:57
m&p-Xylene
ug/L
<0.44
1.0
0.44
04/20/20 11:57
Methyl-tert-butyl ether
ug/L
<0.44
0.50
0.44
04/20/20 11:57
Methylene Chloride
ug/L
<1.5
2.0
1.5
04/20/20 11:57
n-Butylbenzene
ug/L
<0.35
0.50
0.35
04/20/20 11:57
n-Propylbenzene
ug/L
<0.24
0.50
0.24
04/20/20 11:57
Naphthalene
ug/L
<0.66
2.0
0.66
04/20/20 11:57
o-Xylene
ug/L
<0.24
0.50
0.24
04/20/20 11:57
sec-Butylbenzene
ug/L
<0.25
0.50
0.25
04/20/20 11:57
Styrene
ug/L
<0.26
0.50
0.26
04/20/20 11:57
tert-Butyl benzene
ug/L
<0.25
0.50
0.25
04/20/20 11:57
Tetrachloroethene
ug/L
<0.23
0.50
0.23
04/20/20 11:57
Toluene
ug/L
<0.23
0.50
0.23
04/20/20 11:57
trans-1,2-Dichloroethene
ug/L
<0.26
0.50
0.26
04/20/20 11:57
trans- 1,3-Dichloropropene
ug/L
<0.39
0.50
0.39
04/20/20 11:57
Trichloroethene
ug/L
<0.23
0.50
0.23
04/20/20 11:57
Trichlorofluoromethane
ug/L
<0.34
1.0
0.34
04/20/20 11:57
Vinyl chloride
ug/L
<0.41
1.0
0.41
04/20/20 11:57
Xylene (Total)
ug/L
<0.50
1.0
0.50
04/20/20 11:57
1,2-Dichloroethane-d4 (S)
%
106
70-130
04/20/20 11:57
4-Bromofluorobenzene (S)
%
98
70-130
04/20/20 11:57
Toluene-d8 (S)
%
104
70-130
04/20/20 11:57
LABORATORY CONTROL SAMPLE:
Parameter
2864932
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1,2-Tetrachloroethane
ug/L
50
55.2
110
60-140
1,1,1-Trichloroethane
ug/L
50
53.5
107
60-140
1,1,2,2-Tetrachloroethane
ug/L
50
49.2
98
60-140
1,1,2-Trichloroethane
ug/L
50
55.4
111
60-140
1,1-Dichloroethane
ug/L
50
48.3
97
60-140
1,1-Dichloroethene
ug/L
50
48.2
96
60-140
1,1-Dichloropropene
ug/L
50
52.6
105
60-140
1,2,3-Trichlorobenzene
ug/L
50
60.5
121
60-140
1,2,3-Trichloropropane
ug/L
50
48.9
98
60-140
1,2,4-Trichlorobenzene
ug/L
50
57.8
116
60-140
1,2,4-Trimethylbenzene
ug/L
50
49.9
100
60-140
1,2-Dibromo-3-chloropropane
ug/L
50
56.5
113
60-140
1,2-Dibromoethane (EDB)
ug/L
50
52.9
106
60-140
1,2-Dichlorobenzene
ug/L
50
52.5
105
60-140
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/21 /2020 02:02 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Rays Gulf
Pace Project No.: 92473667
LABORATORY CONTROL SAMPLE:
Parameter
2864932
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,2-Dichloroethane
ug/L
50
50.6
101
60-140
1,2-Dichloropropane
ug/L
50
48.3
97
60-140
1,3,5-Trimethylbenzene
ug/L
50
50.1
100
60-140
1,3-Dichlorobenzene
ug/L
50
52.8
106
60-140
1,3-Dichloropropane
ug/L
50
49.4
99
60-140
1,4-Dichlorobenzene
ug/L
50
51.4
103
60-140
2,2-Dichloropropane
ug/L
50
53.0
106
60-140
2-Butanone (MEK)
ug/L
100
107
107
60-140
2-Chlorotoluene
ug/L
50
50.0
100
60-140
2-Hexanone
ug/L
100
106
106
60-140
4-Chlorotoluene
ug/L
50
52.2
104
60-140
Benzene
ug/L
50
50.1
100
60-140
Bromobenzene
ug/L
50
49.8
100
60-140
Bromochloromethane
ug/L
50
54.0
108
60-140
Bromodichloromethane
ug/L
50
52.1
104
60-140
Bromoform
ug/L
50
55.9
112
60-140
Bromomethane
ug/L
50
61.6
123
60-140
Carbon tetrachloride
ug/L
50
57.3
115
60-140
Chlorobenzene
ug/L
50
50.3
101
60-140
Chloroethane
ug/L
50
44.1
88
60-140
Chloroform
ug/L
50
51.9
104
60-140
Chloromethane
ug/L
50
40.5
81
60-140
cis-1,2-Dichloroethene
ug/L
50
49.4
99
60-140
cis-1,3-Dichloropropene
ug/L
50
52.4
105
60-140
Dibromochloromethane
ug/L
50
57.5
115
60-140
Dibromomethane
ug/L
50
55.3
111
60-140
Dichlorodifluoromethane
ug/L
50
47.9
96
60-140
Diisopropyl ether
ug/L
50
53.3
107
60-140
Ethylbenzene
ug/L
50
48.8
98
60-140
Hexachloro-1,3-butadiene
ug/L
50
57.0
114
60-140
Isopropylbenzene (Cumene)
ug/L
50
51.5
103
60-140
m&p-Xylene
ug/L
100
101
101
60-140
Methyl-tert-butyl ether
ug/L
50
56.3
113
60-140
Methylene Chloride
ug/L
50
45.9
92
60-140
n-Butylbenzene
ug/L
50
49.1
98
60-140
n-Propylbenzene
ug/L
50
48.3
97
60-140
Naphthalene
ug/L
50
54.2
108
60-140
o-Xylene
ug/L
50
50.1
100
60-140
sec-Butylbenzene
ug/L
50
47.9
96
60-140
Styrene
ug/L
50
50.7
101
60-140
tert-Butyl benzene
ug/L
50
41.5
83
60-140
Tetrachloroethene
ug/L
50
48.6
97
60-140
Toluene
ug/L
50
48.6
97
60-140
trans-1,2-Dichloroethene
ug/L
50
50.1
100
60-140
trans- 1,3-Dichloropropene
ug/L
50
53.5
107
60-140
Trichloroethene
ug/L
50
54.1
108
60-140
Trichlorofluoromethane
ug/L
50
46.2
92
60-140
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/21 /2020 02:02 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Rays Gulf
Pace Project No.: 92473667
LABORATORY CONTROL SAMPLE:
2864932
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits
Vinyl chloride
ug/L
50 49.7 99
60-140
Xylene (Total)
ug/L
150 151 101
60-140
1,2-Dichloroethane-d4 (S)
%
103
70-130
4-Bromofluorobenzene (S)
%
103
70-130
Toluene-d8 (S)
%
99
70-130
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2864933
MS
92473667005 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
2864934
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1, 1, 1,2-Tetrachloroethane
ug/L
<106
5000
5000
5640
5850
113
117
60-140
4
30
1,1,1-Trichloroethane
ug/L
<69.5
5000
5000
5890
6260
118
125
60-140
6
30
1,1,2,2-Tetrachloroethane
ug/L
<48.2
5000
5000
4940
5280
99
106
60-140
7
30
1,1,2-Trichloroethane
ug/L
<58.0
5000
5000
5570
6040
111
121
60-140
8
30
1,1-Dichloroethane
ug/L
<61.0
5000
5000
5300
5610
106
112
60-140
6
30
1,1-Dichloroethene
ug/L
<54.5
5000
5000
5540
5910
111
118
60-140
6
30
1,1-Dichloropropene
ug/L
<87.0
5000
5000
5720
6100
114
122
60-140
6
30
1,2,3-Trichlorobenzene
ug/L
<195
5000
5000
5870
6060
117
121
60-140
3
30
1,2,3-Trichloropropane
ug/L
<67.8
5000
5000
5030
5440
101
109
60-140
8
30
1,2,4-Trichlorobenzene
ug/L
<109
5000
5000
5740
6100
115
122
60-140
6
30
1,2,4-Trimethyl benzene
ug/L
<48.2
5000
5000
5380
5550
108
111
60-140
3
30
1,2-Dibromo-3-
ug/L
<96.2
5000
5000
4820
5320
96
106
60-140
10
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
<57.8
5000
5000
5280
5690
106
114
60-140
7
30
1,2-Dichlorobenzene
ug/L
<60.0
5000
5000
5490
5620
110
112
60-140
2
30
1,2-Dichloroethane
ug/L
<65.8
5000
5000
5240
5630
105
113
60-140
7
30
1,2-Dichloropropane
ug/L
<45.8
5000
5000
5180
5510
104
110
60-140
6
30
1,3,5-Trimethyl benzene
ug/L
<56.8
5000
5000
5460
5520
109
110
60-140
1
30
1,3-Dichlorobenzene
ug/L
<62.5
5000
5000
5530
5780
111
116
60-140
4
30
1,3-Dichloropropane
ug/L
<85.2
5000
5000
5220
5380
104
108
60-140
3
30
1,4-Dichlorobenzene
ug/L
<62.2
5000
5000
5300
5770
106
115
60-140
8
30
2,2-Dichloropropane
ug/L
<70.2
5000
5000
4890
5390
98
108
60-140
10
30
2-Butanone (MEK)
ug/L
<898
10000
10000
9470
10300
95
103
60-140
9
30
2-Chlorotoluene
ug/L
<51.8
5000
5000
5350
5610
107
112
60-140
5
30
2-Hexanone
ug/L
<151
10000
10000
10000
11200
100
112
60-140
11
30
4-Chlorotoluene
ug/L
<51.5
5000
5000
5600
5840
112
117
60-140
4
30
Benzene
ug/L
<60.0
5000
5000
5490
5800
110
116
60-140
5
30
Bromobenzene
ug/L
<53.8
5000
5000
5500
5690
110
114
60-140
3
30
Bromochloromethane
ug/L
<64.5
5000
5000
5540
5920
111
118
60-140
7
30
Bromodichloromethane
ug/L
<46.2
5000
5000
5440
5710
109
114
60-140
5
30
Bromoform
ug/L
<101
5000
5000
4960
5400
99
108
60-140
9
30
Bromomethane
ug/L
<430
5000
5000
4810
5930
96
119
60-140
21
30
Carbon tetrachloride
ug/L
<58.0
5000
5000
5970
6370
119
127
60-140
6
30
Chlorobenzene
ug/L
<56.2
5000
5000
5370
5610
107
112
60-140
4
30
Chloroethane
ug/L
<146
5000
5000
5220
5130
104
103
60-140
2
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/21 /2020 02:02 PM without the written consent of Pace Analytical Services, LLC.
Page 22 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Rays Gulf
Pace Project No.: 92473667
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2864933
MS
92473667005 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
2864934
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
Chloroform
ug/L
<88.2
5000
5000
5620
5980
112
120
60-140
6
30
Chloromethane
ug/L
<104
5000
5000
4140
4640
83
93
60-140
11
30
cis-1,2-Dichloroethene
ug/L
<51.8
5000
5000
5270
5720
105
114
60-140
8
30
cis-1,3-Dichloropropene
ug/L
<89.2
5000
5000
5250
5500
105
110
60-140
5
30
Dibromochloromethane
ug/L
<100
5000
5000
5460
5800
109
116
60-140
6
30
Dibromomethane
ug/L
<77.5
5000
5000
5510
5980
110
120
60-140
8
30
Dichlorodifluoromethane
ug/L
<71.0
5000
5000
5840
6200
117
124
60-140
6
30
Diisopropyl ether
ug/L
<83.5
5000
5000
5310
5690
106
114
60-140
7
30
Ethylbenzene
ug/L
<60.0
5000
5000
5360
5520
107
110
60-140
3
30
Hexachloro-1,3-butadiene
ug/L
<300
5000
5000
5570
5980
111
120
60-140
7
30
Isopropylbenzene
ug/L
<59.5
5000
5000
5630
5850
113
117
60-140
4
30
(Cumene)
m&p-Xylene
ug/L
<110
10000
10000
11000
11400
110
114
60-140
3
30
Methyl-tert-butyl ether
ug/L
30600
5000
5000
37000
38700
128
162
60-140
4
30 M1
Methylene Chloride
ug/L
<375
5000
5000
5160
5430
103
109
60-140
5
30
n-Butylbenzene
ug/L
<88.2
5000
5000
5040
5300
101
106
60-140
5
30
n-Propylbenzene
ug/L
<60.2
5000
5000
5270
5530
105
111
60-140
5
30
Naphthalene
ug/L
<165
5000
5000
5120
5470
101
108
60-140
6
30
o-Xylene
ug/L
<59.2
5000
5000
5370
5590
107
112
60-140
4
30
sec-Butylbenzene
ug/L
<61.5
5000
5000
5250
5500
105
110
60-140
5
30
Styrene
ug/L
<64.0
5000
5000
5220
5510
104
110
60-140
6
30
tert-Butylbenzene
ug/L
<62.5
5000
5000
4610
4820
92
96
60-140
4
30
Tetrachloroethene
ug/L
<58.0
5000
5000
5340
5550
107
111
60-140
4
30
Toluene
ug/L
78.1J
5000
5000
5390
5530
106
109
60-140
3
30
trans-1,2-Dichloroethene
ug/L
<64.2
5000
5000
5370
5700
107
114
60-140
6
30
trans-1,3-Dichloropropene
ug/L
<98.5
5000
5000
5290
5610
106
112
60-140
6
30
Trichloroethene
ug/L
<58.0
5000
5000
5620
5880
112
118
60-140
5
30
Trichlorofluoromethane
ug/L
<84.0
5000
5000
5490
5860
110
117
60-140
7
30
Vinyl chloride
ug/L
<102
5000
5000
5430
5820
109
116
60-140
7
30
Xylene (Total)
ug/L
<125
15000
15000
16400
17000
109
113
60-140
3
30
1,2-Dichloroethane-d4 (S)
%
105
110
70-130
4-Bromofluorobenzene (S)
%
104
103
70-130
Toluene-d8 (S)
%
98
99
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/21 /2020 02:02 PM without the written consent of Pace Analytical Services, LLC.
Page 23 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Rays Gulf
Pace Project No.: 92473667
QC Batch: 537331 Analysis Method: SM 6200B
QC Batch Method: SM 6200B Analysis Description: 6200E MSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92473667002
METHOD BLANK: 2865622
Associated Lab Samples: 92473667002
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
<0.42
0.50
0.42
04/21/20 10:47
1,1,1-Trichloroethane
ug/L
<0.28
0.50
0.28
04/21/20 10:47
1,1,2,2-Tetrachloroethane
ug/L
<0.19
0.50
0.19
04/21/20 10:47
1,1,2-Trichloroethane
ug/L
<0.23
0.50
0.23
04/21/20 10:47
1,1-Dichloroethane
ug/L
<0.24
0.50
0.24
04/21/20 10:47
1,1-Dichloroethene
ug/L
<0.22
0.50
0.22
04/21/20 10:47
1,1-Dichloropropene
ug/L
<0.35
0.50
0.35
04/21/20 10:47
1,2,3-Trichlorobenzene
ug/L
<0.78
2.0
0.78
04/21/20 10:47
1,2,3-Trichloropropane
ug/L
<0.27
0.50
0.27
04/21/20 10:47
1,2,4-Trichlorobenzene
ug/L
<0.44
2.0
0.44
04/21/20 10:47
1,2,4-Trimethylbenzene
ug/L
<0.19
0.50
0.19
04/21/20 10:47
1,2-Dibromo-3-chloropropane
ug/L
<0.38
1.0
0.38
04/21/20 10:47
1,2-Dibromoethane (EDB)
ug/L
<0.23
0.50
0.23
04/21/20 10:47
1,2-Dichlorobenzene
ug/L
<0.24
0.50
0.24
04/21/20 10:47
1,2-Dichloroethane
ug/L
<0.26
0.50
0.26
04/21/20 10:47
1,2-Dichloropropane
ug/L
<0.18
0.50
0.18
04/21/20 10:47
1,3,5-Trimethylbenzene
ug/L
<0.23
0.50
0.23
04/21/20 10:47
1,3-Dichlorobenzene
ug/L
<0.25
0.50
0.25
04/21/20 10:47
1,3-Dichloropropane
ug/L
<0.34
0.50
0.34
04/21/20 10:47
1,4-Dichlorobenzene
ug/L
<0.25
0.50
0.25
04/21/20 10:47
2,2-Dichloropropane
ug/L
<0.28
0.50
0.28
04/21/20 10:47
2-Butanone (MEK)
ug/L
<3.6
5.0
3.6
04/21/20 10:47
2-Chlorotoluene
ug/L
<0.21
0.50
0.21
04/21/20 10:47
2-Hexanone
ug/L
<0.60
5.0
0.60
04/21/20 10:47
4-Chlorotoluene
ug/L
<0.21
0.50
0.21
04/21/20 10:47
Benzene
ug/L
<0.24
0.50
0.24
04/21/20 10:47
Bromobenzene
ug/L
<0.22
0.50
0.22
04/21/20 10:47
Bromochloromethane
ug/L
<0.26
0.50
0.26
04/21/20 10:47
Bromodichloromethane
ug/L
<0.18
0.50
0.18
04/21/20 10:47
Bromoform
ug/L
<0.40
0.50
0.40
04/21/20 10:47
Bromomethane
ug/L
<1.7
5.0
1.7
04/21/20 10:47
Carbon tetrachloride
ug/L
<0.23
0.50
0.23
04/21/20 10:47
Chlorobenzene
ug/L
<0.22
0.50
0.22
04/21/20 10:47
Chloroethane
ug/L
<0.58
1.0
0.58
04/21/20 10:47
Chloroform
ug/L
<0.35
0.50
0.35
04/21/20 10:47
Chloromethane
ug/L
<0.42
1.0
0.42
04/21/20 10:47
cis-1,2-Dichloroethene
ug/L
<0.21
0.50
0.21
04/21/20 10:47
cis-1,3-Dichloropropene
ug/L
<0.36
0.50
0.36
04/21/20 10:47
Dibromochloromethane
ug/L
<0.40
0.50
0.40
04/21/20 10:47
Dibromomethane
ug/L
<0.31
0.50
0.31
04/21/20 10:47
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/21 /2020 02:02 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Rays Gulf
Pace Project No.: 92473667
METHOD BLANK: 2865622
Associated Lab Samples: 92473667002
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Dichlorodifluoromethane
ug/L
<0.28
0.50
0.28
04/21/20 10:47
Diisopropyl ether
ug/L
<0.33
0.50
0.33
04/21/20 10:47
Ethylbenzene
ug/L
<0.24
0.50
0.24
04/21/20 10:47
Hexachloro-1,3-butadiene
ug/L
<1.2
2.0
1.2
04/21/20 10:47
Isopropylbenzene (Cumene)
ug/L
<0.24
0.50
0.24
04/21/20 10:47
m&p-Xylene
ug/L
<0.44
1.0
0.44
04/21/20 10:47
Methyl-tert-butyl ether
ug/L
<0.44
0.50
0.44
04/21/20 10:47
Methylene Chloride
ug/L
<1.5
2.0
1.5
04/21/20 10:47
n-Butylbenzene
ug/L
<0.35
0.50
0.35
04/21/20 10:47
n-Propylbenzene
ug/L
<0.24
0.50
0.24
04/21/20 10:47
Naphthalene
ug/L
<0.66
2.0
0.66
04/21/20 10:47
o-Xylene
ug/L
<0.24
0.50
0.24
04/21/20 10:47
sec-Butylbenzene
ug/L
<0.25
0.50
0.25
04/21/20 10:47
Styrene
ug/L
<0.26
0.50
0.26
04/21/20 10:47
tert-Butyl benzene
ug/L
<0.25
0.50
0.25
04/21/20 10:47
Tetrachloroethene
ug/L
<0.23
0.50
0.23
04/21/20 10:47
Toluene
ug/L
<0.23
0.50
0.23
04/21/20 10:47
trans-1,2-Dichloroethene
ug/L
<0.26
0.50
0.26
04/21/20 10:47
trans- 1,3-Dichloropropene
ug/L
<0.39
0.50
0.39
04/21/20 10:47
Trichloroethene
ug/L
<0.23
0.50
0.23
04/21/20 10:47
Trichlorofluoromethane
ug/L
<0.34
1.0
0.34
04/21/20 10:47
Vinyl chloride
ug/L
<0.41
1.0
0.41
04/21/20 10:47
Xylene (Total)
ug/L
<0.50
1.0
0.50
04/21/20 10:47
1,2-Dichloroethane-d4 (S)
%
105
70-130
04/21/20 10:47
4-Bromofluorobenzene (S)
%
100
70-130
04/21/20 10:47
Toluene-d8 (S)
%
104
70-130
04/21/20 10:47
LABORATORY CONTROL SAMPLE:
Parameter
2865623
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1,2-Tetrachloroethane
ug/L
50
56.4
113
60-140
1,1,1-Trichloroethane
ug/L
50
57.6
115
60-140
1,1,2,2-Tetrachloroethane
ug/L
50
51.4
103
60-140
1,1,2-Trichloroethane
ug/L
50
56.9
114
60-140
1,1-Dichloroethane
ug/L
50
51.0
102
60-140
1,1-Dichloroethene
ug/L
50
51.1
102
60-140
1,1-Dichloropropene
ug/L
50
56.6
113
60-140
1,2,3-Trichlorobenzene
ug/L
50
59.5
119
60-140
1,2,3-Trichloropropane
ug/L
50
52.0
104
60-140
1,2,4-Trichlorobenzene
ug/L
50
58.1
116
60-140
1,2,4-Trimethylbenzene
ug/L
50
51.3
103
60-140
1,2-Dibromo-3-chloropropane
ug/L
50
56.2
112
60-140
1,2-Dibromoethane (EDB)
ug/L
50
55.4
111
60-140
1,2-Dichlorobenzene
ug/L
50
54.3
109
60-140
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/21 /2020 02:02 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Rays Gulf
Pace Project No.: 92473667
LABORATORY CONTROL SAMPLE:
Parameter
2865623
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,2-Dichloroethane
ug/L
50
52.2
104
60-140
1,2-Dichloropropane
ug/L
50
53.5
107
60-140
1,3,5-Trimethylbenzene
ug/L
50
52.4
105
60-140
1,3-Dichlorobenzene
ug/L
50
54.5
109
60-140
1,3-Dichloropropane
ug/L
50
53.0
106
60-140
1,4-Dichlorobenzene
ug/L
50
53.2
106
60-140
2,2-Dichloropropane
ug/L
50
55.0
110
60-140
2-Butanone (MEK)
ug/L
100
103
103
60-140
2-Chlorotoluene
ug/L
50
53.5
107
60-140
2-Hexanone
ug/L
100
106
106
60-140
4-Chlorotoluene
ug/L
50
54.8
110
60-140
Benzene
ug/L
50
54.4
109
60-140
Bromobenzene
ug/L
50
54.6
109
60-140
Bromochloromethane
ug/L
50
56.9
114
60-140
Bromodichloromethane
ug/L
50
55.5
111
60-140
Bromoform
ug/L
50
55.3
111
60-140
Bromomethane
ug/L
50
57.6
115
60-140
Carbon tetrachloride
ug/L
50
60.0
120
60-140
Chlorobenzene
ug/L
50
53.0
106
60-140
Chloroethane
ug/L
50
43.4
87
60-140
Chloroform
ug/L
50
55.1
110
60-140
Chloromethane
ug/L
50
44.0
88
60-140
cis-1,2-Dichloroethene
ug/L
50
51.9
104
60-140
cis-1,3-Dichloropropene
ug/L
50
56.5
113
60-140
Dibromochloromethane
ug/L
50
57.9
116
60-140
Dibromomethane
ug/L
50
57.9
116
60-140
Dichlorodifluoromethane
ug/L
50
46.1
92
60-140
Diisopropyl ether
ug/L
50
54.1
108
60-140
Ethylbenzene
ug/L
50
51.9
104
60-140
Hexachloro-1,3-butadiene
ug/L
50
56.7
113
60-140
Isopropylbenzene(Cumene)
ug/L
50
54.3
109
60-140
m&p-Xylene
ug/L
100
106
106
60-140
Methyl-tert-butyl ether
ug/L
50
55.9
112
60-140
Methylene Chloride
ug/L
50
49.9
100
60-140
n-Butylbenzene
ug/L
50
51.5
103
60-140
n-Propylbenzene
ug/L
50
51.4
103
60-140
Naphthalene
ug/L
50
54.8
110
60-140
o-Xylene
ug/L
50
53.2
106
60-140
sec-Butylbenzene
ug/L
50
50.4
101
60-140
Styrene
ug/L
50
53.1
106
60-140
tert-Butyl benzene
ug/L
50
44.4
89
60-140
Tetrachloroethene
ug/L
50
52.6
105
60-140
Toluene
ug/L
50
51.9
104
60-140
trans-1,2-Dichloroethene
ug/L
50
53.0
106
60-140
trans- 1,3-Dichloropropene
ug/L
50
57.7
115
60-140
Trichloroethene
ug/L
50
55.9
112
60-140
Trichlorofluoromethane
ug/L
50
48.6
97
60-140
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/21 /2020 02:02 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Rays Gulf
Pace Project No.: 92473667
LABORATORY CONTROL SAMPLE:
2865623
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits
Vinyl chloride
ug/L
50 50.9 102
60-140
Xylene (Total)
ug/L
150 159 106
60-140
1,2-Dichloroethane-d4 (S)
%
100
70-130
4-Bromofluorobenzene (S)
%
102
70-130
Toluene-d8 (S)
%
98
70-130
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2865624
MS
92473945010 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
2865625
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1, 1, 1,2-Tetrachloroethane
ug/L
ND
100
100
116
115
116
115
60-140
1
30
1,1,1-Trichloroethane
ug/L
ND
100
100
121
121
121
121
60-140
0
30
1,1,2,2-Tetrachloroethane
ug/L
ND
100
100
101
105
101
105
60-140
4
30
1,1,2-Trichloroethane
ug/L
ND
100
100
113
114
113
114
60-140
1
30
1,1-Dichloroethane
ug/L
ND
100
100
111
110
111
110
60-140
0
30
1,1-Dichloroethene
ug/L
ND
100
100
110
112
110
112
60-140
2
30
1,1-Dichloropropene
ug/L
ND
100
100
120
119
120
119
60-140
1
30
1,2,3-Trichlorobenzene
ug/L
ND
100
100
119
121
119
121
60-140
2
30
1,2,3-Trichloropropane
ug/L
ND
100
100
104
106
104
106
60-140
3
30
1,2,4-Trichlorobenzene
ug/L
ND
100
100
115
115
115
115
60-140
0
30
1,2,4-Trimethyl benzene
ug/L
4.0
100
100
102
104
98
100
60-140
2
30
1,2-Dibromo-3-
ug/L
ND
100
100
105
109
105
109
60-140
3
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
100
100
106
113
106
113
60-140
6
30
1,2-Dichlorobenzene
ug/L
ND
100
100
102
99.2
102
99
60-140
2
30
1,2-Dichloroethane
ug/L
ND
100
100
108
109
108
109
60-140
1
30
1,2-Dichloropropane
ug/L
ND
100
100
107
107
107
107
60-140
0
30
1,3,5-Trimethyl benzene
ug/L
ND
100
100
104
104
104
104
60-140
0
30
1,3-Dichlorobenzene
ug/L
ND
100
100
104
105
104
105
60-140
1
30
1,3-Dichloropropane
ug/L
ND
100
100
103
107
103
107
60-140
4
30
1,4-Dichlorobenzene
ug/L
ND
100
100
103
102
103
102
60-140
0
30
2,2-Dichloropropane
ug/L
ND
100
100
110
116
110
116
60-140
5
30
2-Butanone (MEK)
ug/L
63.1
200
200
272
286
104
111
60-140
5
30
2-Chlorotoluene
ug/L
ND
100
100
103
102
103
102
60-140
2
30
2-Hexanone
ug/L
18.6J
200
200
230
237
106
109
60-140
3
30
4-Chlorotoluene
ug/L
ND
100
100
106
107
106
107
60-140
1
30
Benzene
ug/L
ND
100
100
112
113
112
113
60-140
1
30
Bromobenzene
ug/L
ND
100
100
103
104
103
104
60-140
1
30
Bromochloromethane
ug/L
ND
100
100
116
114
116
114
60-140
1
30
Bromodichloromethane
ug/L
ND
100
100
111
112
111
112
60-140
1
30
Bromoform
ug/L
ND
100
100
103
104
103
104
60-140
1
30
Bromomethane
ug/L
ND
100
100
127
143
127
143
60-140
12
30 M1
Carbon tetrachloride
ug/L
ND
100
100
125
133
125
133
60-140
6
30
Chlorobenzene
ug/L
ND
100
100
110
107
110
107
60-140
2
30
Chloroethane
ug/L
ND
100
100
97.2
106
97
106
60-140
8
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/21 /2020 02:02 PM without the written consent of Pace Analytical Services, LLC.
Page 27 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Rays Gulf
Pace Project No.: 92473667
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2865624
MS
92473945010 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
2865625
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
Chloroform
ug/L
ND
100
100
116
120
116
120
60-140
4
30
Chloromethane
ug/L
ND
100
100
93.2
94.7
93
95
60-140
2
30
cis-1,2-Dichloroethene
ug/L
ND
100
100
110
112
110
112
60-140
2
30
cis-1,3-Dichloropropene
ug/L
ND
100
100
115
112
115
112
60-140
3
30
Dibromochloromethane
ug/L
ND
100
100
113
116
113
116
60-140
2
30
Dibromomethane
ug/L
ND
100
100
113
120
113
120
60-140
6
30
Dichlorodifluoromethane
ug/L
ND
100
100
113
112
113
112
60-140
0
30
Diisopropyl ether
ug/L
ND
100
100
108
112
108
112
60-140
4
30
Ethylbenzene
ug/L
ND
100
100
106
108
106
108
60-140
2
30
Hexachloro-1,3-butadiene
ug/L
ND
100
100
116
117
116
117
60-140
1
30
Isopropylbenzene
ug/L
ND
100
100
110
110
110
110
60-140
0
30
(Cumene)
m&p-Xylene
ug/L
ND
200
200
215
218
107
109
60-140
1
30
Methyl-tert-butyl ether
ug/L
512
100
100
636
648
124
136
60-140
2
30
Methylene Chloride
ug/L
ND
100
100
106
110
106
110
60-140
4
30
n-Butylbenzene
ug/L
ND
100
100
101
100
101
100
60-140
0
30
n-Propylbenzene
ug/L
ND
100
100
101
103
101
103
60-140
2
30
Naphthalene
ug/L
28.3
100
100
106
107
78
79
60-140
1
30
o-Xylene
ug/L
ND
100
100
103
106
103
106
60-140
3
30
sec-Butylbenzene
ug/L
ND
100
100
101
103
101
103
60-140
2
30
Styrene
ug/L
ND
100
100
104
104
104
104
60-140
1
30
tert-Butylbenzene
ug/L
ND
100
100
89.6
89.4
90
89
60-140
0
30
Tetrachloroethene
ug/L
ND
100
100
102
110
102
110
60-140
7
30
Toluene
ug/L
ND
100
100
111
109
111
109
60-140
3
30
trans-1,2-Dichloroethene
ug/L
ND
100
100
108
112
108
112
60-140
3
30
trans-1,3-Dichloropropene
ug/L
ND
100
100
116
112
116
112
60-140
3
30
Trichloroethene
ug/L
ND
100
100
118
118
118
118
60-140
0
30
Trichlorofluoromethane
ug/L
ND
100
100
107
110
107
110
60-140
2
30
Vinyl chloride
ug/L
ND
100
100
114
115
114
115
60-140
1
30
Xylene (Total)
ug/L
ND
300
300
318
324
106
108
60-140
2
30
1,2-Dichloroethane-d4 (S)
%
107
109
70-130
4-Bromofluorobenzene (S)
%
103
104
70-130
Toluene-d8 (S)
%
102
100
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/21 /2020 02:02 PM without the written consent of Pace Analytical Services, LLC.
Page 28 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: Rays Gulf
Pace Project No.: 92473667
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/21 /2020 02:02 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Rays Gulf
Pace Project No.: 92473667
Lab ID
Sample ID
QC
Batch Method
QC Batch
92473667001
MW-1
SM
6200B
536703
92473667002
MW-2
SM
6200B
537331
92473667003
MW-3
SM
6200B
536703
92473667004
MW-4
SM
6200B
536703
92473667005
DMW-1
SM
6200E
537146
Date: 04/21 /2020 02:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical Method
Analytical
Batch
Page 30 of 33

Document Name:
Document Revised: February 7, 2018
m
Sample Condition Upon Recelpt(SCUR)
Pagel of 2
Document No.:
Issuing Authority:
aceAnalytical
F-CAR-CS•033-Rev.06
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden[] Greenwood ❑ Huntersville Raleigh[] Mechanicsville[]
SampleClient Name: Project#: Wo# : 9247 366?
Courier:L_ Upon []Fed Ex -SUPS ❑U5P5 °Client I IN I 111 11111
❑ Commercial ❑Pate []Other:
_ 82473687
Custody Seal Present? ❑Yes ZN' o Seals Intact? ❑Yes Dina j 11 D
DateJlnttlals Person Examining Contents: j `i —I� —ZG .AAi
Packing Material: [—]Bubble Wrap ffBubble Bags ❑None ❑ Other Biological Tissue Frozen?
Thermometer: Type of Ice: Olivet ❑Yes []No❑IV No /A
❑IR Gun 10: 92TO61 ❑91ue ❑None
Cooler Temp (°C): 1 1 r � Correction Factor: Add/Subtract ('Cl +O.I
� , z Temp �should be above freezing to VC
Cooler Temp Corrected ("C): [3Sampies out of tern criteria. Samples an Ice, cooling process
hasbegun
USDA Regulated Sail (ON/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from aforelgn source (internalionaily,
I—Ivo. iiki� inriudinc Hawali and Puerto Ricol? FlYes FIND
Comments/ Dlscre ancy:
Chain of Custody Present?
Yes
[]No
[I N/A
1.
Samples Arrived within Hold Time?
❑fes
ND
❑N/A
2.
Short Hold Time Analysis (<72 hr.)?
(-]Yes
E%o
❑N/A
3,
Rush TumAra und Time Requested?
❑Yes
[�la
[]N/A
4.
Sufficient Volume?
Oes
[-]No
❑N/A
S.
Correct Containers Used?
-Pace Containers Used?
Yes
&Yes
❑No
❑No
❑N/A
❑N/A
6.
Containers Intact?
Yes
❑No
❑N/A
7.
Dissolved analysis: Samples field filtered?
❑Yes
[]No
N/A
S.
Yes
MNo
N A
9.
-Includes DatejTime/ID/Analysis Matrix:
L✓
Heads ace in VOA Vials >5-6mm ?
nyes
o
N A
10,
Trip Blank Present?
Trip Blank Custody Seals Present?
Yes
❑Yes
No
❑No
NjA
CffN/A
11.
COMMENTS/SAMPLE DISCREPANCY field Data Required? []Yes [:]No
Lot 0 of split containers;
CLIENT NOTI F I CATIOfd/RESOLUTIO N
Person contacted: Date/Time:
Project Manager SCURF Review: Date;
Project Manager SRF Review:
Date:
Page 31 of 33

.✓ CeAnalxical
uccument Name:
;ondltlon Upon Rec
Document No.:
F-CAR-0-033-Rev.(
Document Revised: February 7, 2018
Page 1 of 2
Issuing Authority:
Pace Carolinas Quality Office
'Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Conform, TOC, Oil and Grease, 0110/8015 (water) DOC, LLHg.
"Bottom half of box is to list number of bottle
Y QJ
2 v m U
z z a " o ;
i ,
Z N CL 2
a
Z Z x x _ ej
v of d a V v n 2
GJ
m qJ S A d
c c a a O p ¢ o
7 j C N Y 2 c
U w V L. V U U L
Ydi
in
a a a ro n a a E E
J tl J J J Q
n a o ° E oo E E v
N 41 O r N V1 <l;}
v N ti rM a n
m In am14 m to coo 4
1
2
3
4
5
to
11
12
Project It WQ# f 92473667
PM: PTE Due Date: 04/21/20
CLIENT: 92-ATC
V
V
2
v
N i;
y
a a
_ C
M
E
¢ .¢a
tm7
¢ ¢
N
�
a
a
=
°
Q
0
4
V
2
Q
N
E
N
W
Q
U
S
m
E
uai
.Nt.
d
¢
a
a
}O
l�7
o
Q
2 `
m ¢ Z
o Z Q
rq O
N G
z j =
¢ ¢ ¢
O >>
q 4
4 I
t7 t7 �
y o
`
2
x
in
O
m
a`
�'
ka
P
>
2
Y
m
�
=
7
a
>
m
Q
z
u
n
m
uE
N
a
N
<
2
N
E
h
N
a
v,
41
NI
N
Z
a
E
M
N
a
0
�
¢ 7
d y
i
v `, t:
�
6
2 c
�� �
E c
'�
� 4
o E E
Q N q
0 R t7
42 7 a
PH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon recelpt
Date preservation adjusted
Time preservailon
adjusted
Amount of Preservative
added
Lot ff
o„.1 1.5 —1. L.-Pi HIC aonipMa, a 6wpg ui uns Twin wrr oe senc io ineNOrM Carolina DEHNR Certification Office [i.e.
Out of hold, Incorrect preservative, out of temp, Incorrect containers.
Page 32 of 33

m
a
a
m
3
0 D
0 a° CL
Cc z u
m
ti
m
04
w
N
-�
ITEM #
c
'm
=
d a
3 C
N
o
n
-
3
m
C =
❑
�
n
v
d 0
O
N
n
a N
n n n
o
m
m
m
��0
o
g
a b
a
y
O°
=�4 �3
x
m
0
x
z
c
m
n
0P�vo�95�g�O
a
3.
v°
vv d n
m
#
m
4
n 06 oa
8
MATRA CODE (see valid codes to left)
i
m
0 3
SAMPLETYPE (G=GRAB C=COMP)
❑
=
C
v
C
]
m b
mK
m
c
D
N
N
O
z
�
�'t1
0
z
m
m
m
m
D
z
z
0
❑
ti
o
m
m
�
c
t„
m
SAMPLE TEMP AT COLLECTION
m
m
m
Q
O n
0 OF CONTAINERS
1
0. G.
3
llnpreSBNed
-
D
W
p M
_
H2SO4
,m'
m
c
HNO3
d
HCI
m
NaOH
m
Na2S203
m
6
Methanol
m
ry
-
m
Other
'n
a
N
Analyses Test
YIN
--
-
voC by6200
m
u,
�
m
N
a
o.
➢
in•
n
z
�
3
rn
I
6�1
TEMP in C
n m
Residual Chlorfne (YIN)
rl
p
b
n
z
0
E
m
°
Received on
-
Ice
D
(YIN)
�n
t�
o'
m
o
Custody
Sealed
n
Cooler
YIN
y
Samples
Intact
(YIN}
-)
Page 33 of 33

Beverly, Trudy
From: Al Quarles <[e-mail]>
Sent: Wednesday, June 10, 2020 7:15 AM
To: Beverly, Trudy
Subject: [External] Ed Leach project - Ray's Gulf, Incident # 8608
Attachments: MO-3418_8608_CA_G M R_20200520. pdf
External emaiick links or open attachments unless you veri
[e-mail]
Trudy,
See attached. I am varying work from the office and home, so call my mobile if you have any questions or wish to discuss
the site.
Thank you,
Al
Al Quarles, P.G. I SENIOR PROJECT MANAGER I ATC Group Services LLC
Registered NC, SC
Office + 1 704 529 3200 1 Direct [phone] Mobile + 1 803 984 6764
ciTC
7606 Whitehall Executive Center Drive Suite 800 1 Charlotte, NC 28273
[e-mail] I www.atcgroupservices.com [atcgroupservices.coml
This email and its attachments may contain confidential and/or privileged information for the sole use of the intended recipient(s). If you are
not the intended recipient, any use, distribution or copying of the information contained in this email and its attachments is strictly prohibited.
If you have received this email in error, please notify the sender by replying to this message and immediately delete and destroy any copies
of this email and any attachments. The views or opinions expressed are the author's own and may not reflect the views or opinions of ATC.
From: Beverly, Trudy <[e-mail]>
Sent: Wednesday, June 10, 2020 7:04 AM
To: Al Quarles <[e-mail]>
Subject: RE: [External] Ed Leach project - Ray's Gulf, Incident # 8608
Good Morning Al - Email me a copy of the report for review.
Thanks,
Trudy

Trudy Beverly, L.G.
Hydrogeologist, Division of Waste Management
tr-��-D North Carolina Department of Environmental Quality
�EQ
Q ;
LMpjrLrmnt 0=U�mUtft. UST Section, Mooresville Regional Office
mMm704.235.2182 (Office)
Trudy. B everly_gncdenr. gov
Email correspondence to and from this address is subject to the
North Carolina Public Records Law and may be disclosed to third parties.
Office Mailing Address:
610 East Center Avenue, Suite 301
Mooresville, NC 28115
Branch's Underground Storage Tanks Website Address: hops://deq.nc.gov/about/divisions/waste-manaaement/ust
Branch's Above Ground Storage Tanks Website Address: hops://deg.nc.gov/about/divisions/waste-management/ust/ast-proeram
INTERACTIVE MAPS WITH DWM SITES AND PERMITTED FACILITIES:
https://deq.nc.gov/about/divisions/waste-management/waste-management-rules-data/waste-mana eg ment ig s=maps
File Review Procedures:
hops://deq.nc. gov/about/divisions/waste-management/ust/file-review-procedures#mooresville-regional-office
ONLINE ACCESS TO UST SECTION DOCUMENTS (Laserfiche):
httos: //dea.nc. gov/about/divisions/waste-management/laserfiche
Document Submittal & UST File Names for Laserfiche Policies:
https://files.nc.2ov/ncdeci[W aste%2OMana2ement/D WM/UST/W hatsNew/Final-Electronic-Document-Submittal-Policy.pdf
https:Hfiles.nc. gov/ncdeq/Waste%2OManagement/D WM/UST/Corrective%2OAction/UST%20file%20names%20for%2OLaserfiche.docx
From: Al Quarles [mailto:[e-mail]]
Sent: Tuesday, June 9, 2020 3:21 PM
To: Beverly, Trudy <[e-mail]>
Subject: [External] Ed Leach project - Ray's Gulf, Incident # 8608
rnal emailghmTr-Liclick links or open attachments unless you verify. Send all suspicious email as an attachment to
c.sov _ ML
Trudy,
I am preparing to send a Trust Fund claim for this site that includes the most recent report. The claim requires an
approval date for the report. Since I have not received a letter, I assume that you have not had a chance to review the
report. I will indicate that the review is in process by a new Incident Manager (you) on the claim forms.
When you have a chance to review, I would be happy to discuss the history and site conditions, and possible next
actions, prior to your NORR. Mr. Welch would also like to be in on the conversation if possible.
Thanks,
9
Al Quarles, P.G. I SENIOR PROJECT MANAGER I ATC Group Services LLC
Registered NC, SC
Office + 1 704 529 3200 1 Direct [phone] Mobile + 1 803 984 6764
IV
M T

7606 Whitehall Executive Center Drive Suite 800 1 Charlotte, NC 28273
al.quarles(o)atcgs.com I www.atcgroupservices.com fatcgroupservices.coml
This email and its attachments may contain confidential and/or privileged information for the sole use of the intended recipient(s). If you are
not the intended recipient, any use, distribution or copying of the information contained in this email and its attachments is strictly prohibited.
If you have received this email in error, please notify the sender by replying to this message and immediately delete and destroy any copies
of this email and any attachments. The views or opinions expressed are the author's own and may not reflect the views or opinions of ATC.
From: Taraban, Ron <[e-mail]>
Sent: Wednesday, June 3, 2020 6:29 AM
To: Al Quarles <[e-mail]>
Subject: RE: [External] Ed Leach project - Ray's Gulf, Incident # 8608
Hi Al,
This site has been assigned to Trudy Beverly Trudy. Trudy. [e-mail].
Trudy is on vacation this week. I do not know the status of the report. We are doing the best we can until we can fill the
position filled. I do not have the position posted yet.
Thanks -Ron
From: Al Quarles <[e-mail]>
Sent: Wednesday, May 27, 2020 9:12 AM
To: Taraban, Ron <[e-mail]>
Subject: [External] Ed Leach project - Ray's Gulf, Incident # 8608
External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to
[e-mail]
Ron,
The incident # is 8608. Looks like I named the file incorrectly with 8680.
I have a trust fund claim ready to send, pending approval of the report. Did you receive the report mailed last week?
And on a side note, have you filled Ed's position or are you still looking?
Thanks,
Al
Al Quarles, P.G. I SENIOR PROJECT MANAGER I ATC Group Services LLC
Registered NC, SC
Office + 1 704 529 3200 1 Direct [phone] Mobile + 1 803 984 6764
ATC

7606 Whitehall Executive Center Drive Suite 800 1 Charlotte, NC 28273
al.quarles(o)atcgs.com I www.atcgroupservices.com fatcgroupservices.coml
This email and its attachments may contain confidential and/or privileged information for the sole use of the intended recipient(s). If you are
not the intended recipient, any use, distribution or copying of the information contained in this email and its attachments is strictly prohibited.
If you have received this email in error, please notify the sender by replying to this message and immediately delete and destroy any copies
of this email and any attachments. The views or opinions expressed are the author's own and may not reflect the views or opinions of ATC.
From: Taraban, Ron <[e-mail]>
Sent: Wednesday, May 27, 2020 9:06 AM
To: Al Quarles <[e-mail]>
Subject: RE: [External] Ed Leach project - Ray's Gulf, Incident # 8608
Hi Al,
What in the incident number?
From: Al Quarles <[e-mail]>
Sent: Friday, May 15, 2020 2:39 PM
To: Taraban, Ron <[e-mail]>
Subject: [External] Ed Leach project - Ray's Gulf, Incident # 8608
External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to
[e-mail]
Ron,
I have a report to send (due today, but may be Monday before I get it out). Has this been assigned to another Incident
Manager, or should I send the report to you?
And how is it going with a replacement for Ed?
Thanks,
Al
Al Quarles, P.G. I SENIOR PROJECT MANAGER I ATC Group Services LLC
Registered NC, SC
Office + 1 704 529 3200 1 Direct [phone] Mobile + 1 803 984 6764
.ATC
7606 Whitehall Executive Center Drive Suite 800 1 Charlotte, NC 28273
[e-mail] I www.atcgroui3services.com fatcgroupservices.coml
This email and its attachments may contain confidential and/or privileged information for the sole use of the intended recipient(s). If you are
not the intended recipient, any use, distribution or copying of the information contained in this email and its attachments is strictly prohibited.

If you have received this email in error, please notify the sender by replying to this message and immediately delete and destroy any copies
of this email and any attachments. The views or opinions expressed are the author's own and may not reflect the views or opinions of ATC.