10003T_YanceyMitchell_DIN25755_20160314

2211 West Meadowview Rd. Boone Building, Suite 101 Greensboro, NC 27407 tel: [phone] fax: [phone]
www.JoyceEngineering.com
March 14, 2016

Ms. Jackie Drummond
North Carolina Department of Environment and Natural Resources
Division of Waste Management/ Solid Waste Section
1646 Mail Service Center
Raleigh, North Carolina 27699-1646 Re: Soil Assessment Report
Yancey-Mitchell Transfer Facility; Permit No. 100-03T.
JOYCE Project No. 890.1601.12, Tasks No. 04
Dear Ms. Drummond:

On behalf of Republic Services of North Carolina, Joyce Engineering (JOYCE) presents this
report on the results of a soil assessment conducted at the Yancey-Mitchell Transfer Station, Permit # 100-03T in response to a Notice of Violation (NOV) issued by the North Carolina
Department of Environmental Quality (DEQ) on December 4, 2015.

BACKGROUND
The Yancey and Mitchell Counties Transfer Facility is owned by Yancey County and operated by Republic Services, Inc. (d.b.a. Garbage Disposal Services, Inc. (GDS)). The transfer station is
located near Burnsville, North Carolina. During an inspection of the facility on December 4,
2015, the DEQ inspector observed a release of leachate from the north end of the transfer station
receiving bay across the access road and into to the stormwater ditch. The December 4th NOV
called for the Owners/Operator to Submit a Plan for review and approval to the Solid Waste Section that details a proposed soil assessment for the area impacted by the leachate release. A
soil assessment Plan was submitted on February 12, 2016 and was approved by the NCDEQ on
the same day February 12, 2016.

SOIL SAMPLING
JOYCE collected soil samples from the site in accordance with the approved Soil Assessment
Plan on February 18, 2016. The attached (Figure 1) shows the locations of the four soil samples.
Soil samples were collected from three locations in and about the apparent leachate impact area.
At the three locations (SS-1, SS-2, and SS-3), JOYCE collected samples from a depth of approximately 16 to 20 inches below the ground surface. In addition, JOYCE collected one soil sample from an upgradient location (SS-4) to represent background soil conditions, thus a total
of four soil samples were collected. All sampling was conducted under the supervision of a
licensed professional geologist.
Ms. Jackie Drummond
March 14, 2016
Page 1 of 3

The soil samples were collected using a stainless-steel hand auger. The sampling equipment was
decontaminated before sampling and between samples using standard decontamination
procedures. The background sample was collected first. The apparent impact area was sampled
in presumed order from the least to most contaminated soil. The sequenced sampling locations are shown on Figure 1. The samples were placed in laboratory-prepared containers and put immediately into a cooler with ice for transport to the laboratory.

SOIL ANALYSES
The samples were transported to Pace Analytical Services, Inc. in Huntersville, North Carolina under chain-of-custody control for analysis. The soil samples were analyzed for the NC
Appendix I list of solid waste constituents, including total metals by EPA Method 6010, and
volatile organic compounds (VOCs) by EPA Method 5035/8260, as well as for laboratory pH.
The results are summarized in the attached table (Table 1A) and the complete laboratory
analytical report and chain of custody are also attached.
DISCUSSION
There were no VOCs detected in any of the soil samples. If the soil samples were significantly
impacted by leachate, one would expect to see at least some evidence of VOCs. These results
indicate that either there was no VOC impact, or possible VOCs have volatilized between the time of the spill and the sampling event. The pH of the soil samples ranged from 5.06 to 6.49.
The slightly acidic pH of the samples is within normal range indicates no significant impact by
leachate.

Four metals cadmium, chromium, cobalt, and vanadium, were detected in the samples; however, these were total metals analyses and the metals are typically naturally occurring in the
mineralogy of the soils (Reid, 1993). Although all results for detected metals were above the
NC Preliminary Soil Remediation Goals (PSRG) comparison of the metals concentrations in the
soils from the impact area (SS-1, SS-2, and SS-3) with the background sample (SS-4) shows
similar concentrations (within an order of magnitude) for all the metals except chromium which was not detected in the background sample (Table 1A). Naturally occurring concentrations of
the detected metals from Reid (1993) are shown on the right-most column on Table 1A. The
values on Table 1B represent concentrations in the impact area samples divided by the
concentration in the background sample.
The laboratory test results do not support contamination of the apparent impact area by the
leachate release noted in the Notice of Violation (NOV) issued by the North Carolina
Department of Environmental Quality (DEQ) on December 4, 2015. It is possible that the
elevated metals concentrations in the soil are a result of impact from the leachate spill; however,
the fact that the background metals concentrations are high, there were no VOCs, and no anomalous pH values, makes this unlikely.

Ms. Jackie Drummond
March 14, 2016
Page 2 of 3

The apparent impact area is by a paved road with daily truck traffic to the transfer station; there is no nearby surface water or storm water discharge that could feasibly be impacted; the nearest
surface water is the North Toe River located over 2,000 feet northeast of the apparent impact
area, and groundwater is estimated at 60 feet deep in the vicinity of the apparent impact. Based
on the information presented herein, we believe there is little or no chance of the metals in the soil impacting either surface water or groundwater.
We recommend no further action with regard to this incident. Please feel free to contact me at
[phone] if you have any questions or comments.
Respectfully, JOYCE ENGINEERING

Hannu Kemppinen, P.G. Senior Project Consultant

Attachments: Tables 1A & 1B
Figure 1 ASI Laboratory Report

Ref.: Reid, Jeffery C. A Geochemical Atlas of North Carolina. North Carolina
Geological Survey, Bulletin 93. Raleigh, NC. 1993.
Copy: Ray Hoffman, Republic Services

Metals SS-1 SS-2 SS-3 SS-4 (BG) PSRG Natural
Cadmium 6.34 7.21 5.87 53.8 3 0.1-1.0
Chromium 62 ND 121 ND 3.8 12-3,010
Cobalt 51.8 38.9 39.6 34.4 0.9 10
Vanadium 153 187 117 65.4 6 90-1,500
VOC Compounds ND ND ND ND
pH 5.81 5.85 6.49 5.06 5-7
PSRG = Preliminary Soil Remediation Goals (2015).
Natural = Range reported in Reid (1993).
All concentrations in miligrams per kilogram (mg/Kg = ppm).
ND = Not detected above the method detection limit.
Total Metals Analyses by Method 6010.
Soil samples collected February 18, 2016.
Metals SS-1 SS-2 SS-3 SS-4 (BG)
Cadmium 0.12 0.13 0.11 53.8
Chromium 5.17 ND 10.08 ND
Cobalt 1.51 1.13 1.15 34.4
Vanadium 2.34 2.86 1.79 65.4
Values represent the concentrations in the impact area samples divided by
the concentration in the background (SS-4).
Values for chromium represent concentrations divided by natural concentration.
Soil Sample Anlytical Results - Detected Inorganic Constituents
TABLE 1 A
TABLE 1B
Spill Area/Background Concentraion Ratios
ASI ANALYTICAL SERVICES, INC.
Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
Republic Services of North Carolina, LLC
Project: Yancey-Mitchell TS
Conover, NC 28613
1220 Commerce Street, SW
Mr. Ray Hoffman
We appreciate the opportunity to provide the analytical support for your project. The analytical results in this report are
based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this
data package, please do not hesitate to call.
Laboratory Report
Project #:[none]
Prepared For:
Attention:
March 09, 2016
Report Number:AZB0541
Approved:
This report may not be reproduced, except in full, without written approval from Analytical Services, Inc.
Analytical Services, Inc. certifies that the following analytical results meet all requirements of the National
Environmental Laboratory Accreditation Conference(NELAC).
All test results relate only to the samples analyzed.
Page 1 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Sample ID Laboratory ID Matrix Date Sampled
ANALYTICAL REPORT FOR SAMPLES
Date Received
SS-1 AZB0541-01 02/18/16 11:27 02/19/16 09:00Soil
SS-2 AZB0541-02 02/18/16 11:43 02/19/16 09:00Soil
SS-3 AZB0541-03 02/18/16 11:50 02/19/16 09:00Soil
BG(SS-4)AZB0541-04 02/18/16 10:48 02/19/16 09:00Soil
Trip Blank AZB0541-05 02/18/16 00:00 02/19/16 09:00Water
Page 2 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Client ID: SS-1
Date/Time Sampled: 2/18/2016 11:27:00AM
Matrix: Soil
Lab Number ID: AZB0541-01
Date/Time Received: 2/19/2016 9:00:00AM
Project:Yancey-Mitchell TS
Analyte Result RL
Preparation
Date
Analytical
DateMethodQual. DFUnits Init.BatchMDL
General Chemistry
EPA 9045DpH
Units
1 JSpH602049202/19/16 11:0002/19/16 11:005.81
SOP
Moisture
% by
Weight
10.04 DDN% Solids 60205310.04 02/25/16 14:0202/25/16 14:0278.1
Metals, Total
EPA 6010Cmg/kg
dry
16.40 J FBSAntimony60300231.04 03/02/16 14:3003/08/16 12:232.63
EPA 6010Cmg/kg
dry
13.84 FBSArsenic60300231.60 03/02/16 14:3003/08/16 12:23ND
EPA 6010Cmg/kg
dry
11.28 FBSBarium60300230.05 03/02/16 14:3003/08/16 12:23258
EPA 6010Cmg/kg
dry
11.28 FBSBeryllium60300230.18 03/02/16 14:3003/08/16 12:233.94
EPA 6010Cmg/kg
dry
11.28 FBSCadmium60300230.05 03/02/16 14:3003/08/16 12:236.34
EPA 6010Cmg/kg
dry
11.28 FBSChromium60300230.45 03/02/16 14:3003/08/16 12:2362.0
EPA 6010Cmg/kg
dry
15.12 FBSCobalt60300230.17 03/02/16 14:3003/08/16 12:2351.8
EPA 6010Cmg/kg
dry
12.56 FBSCopper60300230.81 03/02/16 14:3003/08/16 12:2362.4
EPA 6010Cmg/kg
dry
13.20 FBSLead60300230.49 03/02/16 14:3003/08/16 12:2319.5
EPA 6010Cmg/kg
dry
12.56 B-01 FBSNickel60300230.13 03/02/16 14:3003/08/16 12:2349.2
EPA 6010Cmg/kg
dry
15.12 FBSSelenium60300231.46 03/02/16 14:3003/08/16 12:23ND
EPA 6010Cmg/kg
dry
11.28 FBSSilver60300230.11 03/02/16 14:3003/08/16 12:23ND
EPA 6010Cmg/kg
dry
125.6 FBSThallium60300231.09 03/02/16 14:3003/08/16 12:23ND
EPA 6010Cmg/kg
dry
12.56 FBSVanadium60300230.20 03/02/16 14:3003/08/16 12:23153
EPA 6010Cmg/kg
dry
12.56 FBSZinc60300230.38 03/02/16 14:3003/08/16 12:23157
Volatile Organic Compounds by EPA 8260
EPA 8260Bug/kg
dry
176 GCNAcetone60204942.1 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
138 GCNAcrylonitrile60204940.5 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
13.8 GCNBenzene60204940.09 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
17.6 GCNBromochloromethane60204940.2 02/19/16 16:0002/19/16 18:53ND
Page 3 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Client ID: SS-1
Date/Time Sampled: 2/18/2016 11:27:00AM
Matrix: Soil
Lab Number ID: AZB0541-01
Date/Time Received: 2/19/2016 9:00:00AM
Project:Yancey-Mitchell TS
Analyte Result RL
Preparation
Date
Analytical
DateMethodQual. DFUnits Init.BatchMDL
Volatile Organic Compounds by EPA 8260
EPA 8260Bug/kg
dry
17.6 GCNBromodichloromethane60204940.3 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
17.6 GCNBromoform60204940.3 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
17.6 GCNBromomethane60204940.3 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
17.6 GCNCarbon Disulfide 60204940.3 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
13.8 GCNCarbon Tetrachloride 60204940.2 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
17.6 GCNChlorobenzene60204940.2 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
13.8 GCNChloroethane60204940.6 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
13.8 GCNChloroform60204940.1 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
17.6 GCNChloromethane60204940.08 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
13.8 GCNDibromochloromethane60204940.2 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
17.6 GCN1,2-Dibromo-3-chloropropane 60204940.4 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
17.6 GCN1,2-Dibromoethane 60204940.2 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
17.6 GCNDibromomethane60204940.1 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
17.6 GCN1,2-Dichlorobenzene 60204940.2 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
17.6 GCN1,4-Dichlorobenzene 60204940.1 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
13.8 GCN1,1-Dichloroethane 60204940.2 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
13.8 GCN1,2-Dichloroethane 60204940.1 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
13.8 GCN1,1-Dichloroethene 60204940.2 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
13.8 GCNcis-1,2-Dichloroethene 60204940.1 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
13.8 GCNtrans-1,2-Dichloroethene 60204940.3 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
13.8 GCN1,2-Dichloropropane 60204940.1 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
13.8 GCNcis-1,3-Dichloropropene 60204940.4 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
13.8 GCNtrans-1,3-Dichloropropene 60204940.3 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
13.8 GCNEthylbenzene60204940.1 02/19/16 16:0002/19/16 18:53ND
Page 4 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Client ID: SS-1
Date/Time Sampled: 2/18/2016 11:27:00AM
Matrix: Soil
Lab Number ID: AZB0541-01
Date/Time Received: 2/19/2016 9:00:00AM
Project:Yancey-Mitchell TS
Analyte Result RL
Preparation
Date
Analytical
DateMethodQual. DFUnits Init.BatchMDL
Volatile Organic Compounds by EPA 8260
EPA 8260Bug/kg
dry
138 GCNMethyl Butyl Ketone (2-Hexanone)60204940.9 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
17.6 GCNMethylene Chloride 60204940.2 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
176 GCNMethyl Ethyl Ketone (2-Butanone)60204941.3 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
138 GCN4-Methyl-2-pentanone (MIBK)60204940.4 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
13.8 GCNStyrene60204940.4 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
17.6 GCN1,1,1,2-Tetrachloroethane 60204940.2 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
13.8 GCN1,1,2,2-Tetrachloroethane 60204940.2 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
13.8 GCNTetrachloroethene60204940.2 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
13.8 GCNToluene60204940.1 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
13.8 GCN1,1,1-Trichloroethane 60204940.1 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
13.8 GCN1,1,2-Trichloroethane 60204940.3 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
13.8 GCNTrichloroethene60204940.2 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
17.6 GCNTrichlorofluoromethane60204940.2 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
17.6 GCN1,2,3-Trichloropropane 60204940.5 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
17.6 GCNVinyl Acetate 60204940.2 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
17.6 GCNVinyl Chloride 60204940.3 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
13.8 GCNXylenes, total 60204940.3 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
1190 GCNtrans-1,4-Dichloro-2-butene 60204940.8 02/19/16 16:0002/19/16 18:53ND
EPA 8260Bug/kg
dry
17.6 GCNIodomethane60204940.9 02/19/16 16:0002/19/16 18:53ND
EPA 8260B80-121102 %Surrogate: Dibromofluoromethane 602049402/19/16 16:0002/19/16 18:53
EPA 8260B70-131106 %Surrogate: 1,2-Dichloroethane-d4 602049402/19/16 16:0002/19/16 18:53
EPA 8260B79-12090 %Surrogate: Toluene-d8 602049402/19/16 16:0002/19/16 18:53
EPA 8260B80-121104 %Surrogate: 4-Bromofluorobenzene 602049402/19/16 16:0002/19/16 18:53
Page 5 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Client ID: SS-2
Date/Time Sampled: 2/18/2016 11:43:00AM
Matrix: Soil
Lab Number ID: AZB0541-02
Date/Time Received: 2/19/2016 9:00:00AM
Project:Yancey-Mitchell TS
Analyte Result RL
Preparation
Date
Analytical
DateMethodQual. DFUnits Init.BatchMDL
General Chemistry
EPA 9045DpH
Units
1 JSpH602049202/19/16 11:0002/19/16 11:005.85
SOP
Moisture
% by
Weight
10.04 DDN% Solids 60205310.04 02/25/16 14:0202/25/16 14:0280.1
Metals, Total
EPA 6010Cmg/kg
dry
15.68 J FBSAntimony60300230.92 03/02/16 14:3003/08/16 12:401.53
EPA 6010Cmg/kg
dry
13.41 FBSArsenic60300231.42 03/02/16 14:3003/08/16 12:40ND
EPA 6010Cmg/kg
dry
11.14 FBSBarium60300230.05 03/02/16 14:3003/08/16 12:40282
EPA 6010Cmg/kg
dry
11.14 FBSBeryllium60300230.16 03/02/16 14:3003/08/16 12:403.55
EPA 6010Cmg/kg
dry
11.14 FBSCadmium60300230.04 03/02/16 14:3003/08/16 12:407.21
EPA 6010Cmg/kg
dry
11.14 FBSChromium60300230.40 03/02/16 14:3003/08/16 12:4028.5
EPA 6010Cmg/kg
dry
14.54 FBSCobalt60300230.15 03/02/16 14:3003/08/16 12:4038.9
EPA 6010Cmg/kg
dry
12.27 FBSCopper60300230.72 03/02/16 14:3003/08/16 12:4032.8
EPA 6010Cmg/kg
dry
12.84 FBSLead60300230.43 03/02/16 14:3003/08/16 12:4010.2
EPA 6010Cmg/kg
dry
12.27 B-01 FBSNickel60300230.12 03/02/16 14:3003/08/16 12:4036.2
EPA 6010Cmg/kg
dry
14.54 FBSSelenium60300231.30 03/02/16 14:3003/08/16 12:40ND
EPA 6010Cmg/kg
dry
11.14 FBSSilver60300230.10 03/02/16 14:3003/08/16 12:40ND
EPA 6010Cmg/kg
dry
122.7 J FBSThallium60300230.97 03/02/16 14:3003/08/16 12:403.79
EPA 6010Cmg/kg
dry
12.27 FBSVanadium60300230.17 03/02/16 14:3003/08/16 12:40187
EPA 6010Cmg/kg
dry
12.27 FBSZinc60300230.33 03/02/16 14:3003/08/16 12:40165
Volatile Organic Compounds by EPA 8260
EPA 8260Bug/kg
dry
163 GCNAcetone60204941.7 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
131 GCNAcrylonitrile60204940.4 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
13.1 GCNBenzene60204940.08 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
16.3 GCNBromochloromethane60204940.2 02/19/16 16:0002/19/16 19:23ND
Page 6 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Client ID: SS-2
Date/Time Sampled: 2/18/2016 11:43:00AM
Matrix: Soil
Lab Number ID: AZB0541-02
Date/Time Received: 2/19/2016 9:00:00AM
Project:Yancey-Mitchell TS
Analyte Result RL
Preparation
Date
Analytical
DateMethodQual. DFUnits Init.BatchMDL
Volatile Organic Compounds by EPA 8260
EPA 8260Bug/kg
dry
16.3 GCNBromodichloromethane60204940.2 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
16.3 GCNBromoform60204940.2 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
16.3 GCNBromomethane60204940.2 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
16.3 GCNCarbon Disulfide 60204940.3 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
13.1 GCNCarbon Tetrachloride 60204940.2 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
16.3 GCNChlorobenzene60204940.2 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
13.1 GCNChloroethane60204940.5 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
13.1 GCNChloroform60204940.1 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
16.3 GCNChloromethane60204940.06 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
13.1 GCNDibromochloromethane60204940.1 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
16.3 GCN1,2-Dibromo-3-chloropropane 60204940.4 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
16.3 GCN1,2-Dibromoethane 60204940.1 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
16.3 GCNDibromomethane60204940.1 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
16.3 GCN1,2-Dichlorobenzene 60204940.1 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
16.3 GCN1,4-Dichlorobenzene 60204940.1 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
13.1 GCN1,1-Dichloroethane 60204940.2 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
13.1 GCN1,2-Dichloroethane 60204940.1 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
13.1 GCN1,1-Dichloroethene 60204940.1 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
13.1 GCNcis-1,2-Dichloroethene 60204940.09 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
13.1 GCNtrans-1,2-Dichloroethene 60204940.2 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
13.1 GCN1,2-Dichloropropane 60204940.1 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
13.1 GCNcis-1,3-Dichloropropene 60204940.3 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
13.1 GCNtrans-1,3-Dichloropropene 60204940.2 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
13.1 GCNEthylbenzene60204940.1 02/19/16 16:0002/19/16 19:23ND
Page 7 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Client ID: SS-2
Date/Time Sampled: 2/18/2016 11:43:00AM
Matrix: Soil
Lab Number ID: AZB0541-02
Date/Time Received: 2/19/2016 9:00:00AM
Project:Yancey-Mitchell TS
Analyte Result RL
Preparation
Date
Analytical
DateMethodQual. DFUnits Init.BatchMDL
Volatile Organic Compounds by EPA 8260
EPA 8260Bug/kg
dry
131 GCNMethyl Butyl Ketone (2-Hexanone)60204940.8 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
16.3 GCNMethylene Chloride 60204940.1 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
163 GCNMethyl Ethyl Ketone (2-Butanone)60204941.1 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
131 GCN4-Methyl-2-pentanone (MIBK)60204940.3 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
13.1 GCNStyrene60204940.3 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
16.3 GCN1,1,1,2-Tetrachloroethane 60204940.2 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
13.1 GCN1,1,2,2-Tetrachloroethane 60204940.1 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
13.1 GCNTetrachloroethene60204940.1 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
13.1 GCNToluene60204940.1 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
13.1 GCN1,1,1-Trichloroethane 60204940.1 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
13.1 GCN1,1,2-Trichloroethane 60204940.2 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
13.1 GCNTrichloroethene60204940.2 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
16.3 GCNTrichlorofluoromethane60204940.2 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
16.3 GCN1,2,3-Trichloropropane 60204940.4 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
16.3 GCNVinyl Acetate 60204940.2 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
16.3 GCNVinyl Chloride 60204940.2 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
13.1 GCNXylenes, total 60204940.3 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
1160 GCNtrans-1,4-Dichloro-2-butene 60204940.7 02/19/16 16:0002/19/16 19:23ND
EPA 8260Bug/kg
dry
16.3 GCNIodomethane60204940.7 02/19/16 16:0002/19/16 19:23ND
EPA 8260B80-121101 %Surrogate: Dibromofluoromethane 602049402/19/16 16:0002/19/16 19:23
EPA 8260B70-131106 %Surrogate: 1,2-Dichloroethane-d4 602049402/19/16 16:0002/19/16 19:23
EPA 8260B79-12091 %Surrogate: Toluene-d8 602049402/19/16 16:0002/19/16 19:23
EPA 8260B80-12194 %Surrogate: 4-Bromofluorobenzene 602049402/19/16 16:0002/19/16 19:23
Page 8 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Client ID: SS-3
Date/Time Sampled: 2/18/2016 11:50:00AM
Matrix: Soil
Lab Number ID: AZB0541-03
Date/Time Received: 2/19/2016 9:00:00AM
Project:Yancey-Mitchell TS
Analyte Result RL
Preparation
Date
Analytical
DateMethodQual. DFUnits Init.BatchMDL
General Chemistry
EPA 9045DpH
Units
1 JSpH602049202/19/16 11:0002/19/16 11:006.49
SOP
Moisture
% by
Weight
10.04 DDN% Solids 60205310.04 02/25/16 14:0202/25/16 14:0280.3
Metals, Total
EPA 6010Cmg/kg
dry
15.99 J FBSAntimony60300230.97 03/02/16 14:3003/08/16 12:442.83
EPA 6010Cmg/kg
dry
13.59 FBSArsenic60300231.49 03/02/16 14:3003/08/16 12:44ND
EPA 6010Cmg/kg
dry
11.20 FBSBarium60300230.05 03/02/16 14:3003/08/16 12:44268
EPA 6010Cmg/kg
dry
11.20 FBSBeryllium60300230.17 03/02/16 14:3003/08/16 12:442.21
EPA 6010Cmg/kg
dry
11.20 FBSCadmium60300230.04 03/02/16 14:3003/08/16 12:445.87
EPA 6010Cmg/kg
dry
11.20 FBSChromium60300230.43 03/02/16 14:3003/08/16 12:44121
EPA 6010Cmg/kg
dry
14.79 FBSCobalt60300230.16 03/02/16 14:3003/08/16 12:4439.6
EPA 6010Cmg/kg
dry
12.39 FBSCopper60300230.75 03/02/16 14:3003/08/16 12:4426.5
EPA 6010Cmg/kg
dry
12.99 FBSLead60300230.46 03/02/16 14:3003/08/16 12:4412.3
EPA 6010Cmg/kg
dry
12.39 B-01 FBSNickel60300230.13 03/02/16 14:3003/08/16 12:4476.9
EPA 6010Cmg/kg
dry
14.79 FBSSelenium60300231.37 03/02/16 14:3003/08/16 12:44ND
EPA 6010Cmg/kg
dry
11.20 FBSSilver60300230.10 03/02/16 14:3003/08/16 12:44ND
EPA 6010Cmg/kg
dry
123.9 FBSThallium60300231.02 03/02/16 14:3003/08/16 12:44ND
EPA 6010Cmg/kg
dry
12.39 FBSVanadium60300230.18 03/02/16 14:3003/08/16 12:44117
EPA 6010Cmg/kg
dry
12.39 FBSZinc60300230.35 03/02/16 14:3003/08/16 12:44173
Volatile Organic Compounds by EPA 8260
EPA 8260Bug/kg
dry
161 GCNAcetone60204941.7 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
131 GCNAcrylonitrile60204940.4 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
13.1 GCNBenzene60204940.07 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
16.1 GCNBromochloromethane60204940.2 02/19/16 16:0002/19/16 19:52ND
Page 9 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Client ID: SS-3
Date/Time Sampled: 2/18/2016 11:50:00AM
Matrix: Soil
Lab Number ID: AZB0541-03
Date/Time Received: 2/19/2016 9:00:00AM
Project:Yancey-Mitchell TS
Analyte Result RL
Preparation
Date
Analytical
DateMethodQual. DFUnits Init.BatchMDL
Volatile Organic Compounds by EPA 8260
EPA 8260Bug/kg
dry
16.1 GCNBromodichloromethane60204940.2 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
16.1 GCNBromoform60204940.2 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
16.1 GCNBromomethane60204940.2 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
16.1 GCNCarbon Disulfide 60204940.2 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
13.1 GCNCarbon Tetrachloride 60204940.1 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
16.1 GCNChlorobenzene60204940.2 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
13.1 GCNChloroethane60204940.5 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
13.1 GCNChloroform60204940.1 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
16.1 GCNChloromethane60204940.06 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
13.1 GCNDibromochloromethane60204940.1 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
16.1 GCN1,2-Dibromo-3-chloropropane 60204940.4 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
16.1 GCN1,2-Dibromoethane 60204940.1 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
16.1 GCNDibromomethane60204940.1 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
16.1 GCN1,2-Dichlorobenzene 60204940.1 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
16.1 GCN1,4-Dichlorobenzene 60204940.1 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
13.1 GCN1,1-Dichloroethane 60204940.2 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
13.1 GCN1,2-Dichloroethane 60204940.1 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
13.1 GCN1,1-Dichloroethene 60204940.1 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
13.1 GCNcis-1,2-Dichloroethene 60204940.09 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
13.1 GCNtrans-1,2-Dichloroethene 60204940.2 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
13.1 GCN1,2-Dichloropropane 60204940.1 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
13.1 GCNcis-1,3-Dichloropropene 60204940.3 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
13.1 GCNtrans-1,3-Dichloropropene 60204940.2 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
13.1 GCNEthylbenzene60204940.1 02/19/16 16:0002/19/16 19:52ND
Page 10 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Client ID: SS-3
Date/Time Sampled: 2/18/2016 11:50:00AM
Matrix: Soil
Lab Number ID: AZB0541-03
Date/Time Received: 2/19/2016 9:00:00AM
Project:Yancey-Mitchell TS
Analyte Result RL
Preparation
Date
Analytical
DateMethodQual. DFUnits Init.BatchMDL
Volatile Organic Compounds by EPA 8260
EPA 8260Bug/kg
dry
131 GCNMethyl Butyl Ketone (2-Hexanone)60204940.8 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
16.1 GCNMethylene Chloride 60204940.1 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
161 GCNMethyl Ethyl Ketone (2-Butanone)60204941.1 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
131 GCN4-Methyl-2-pentanone (MIBK)60204940.3 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
13.1 GCNStyrene60204940.3 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
16.1 GCN1,1,1,2-Tetrachloroethane 60204940.2 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
13.1 GCN1,1,2,2-Tetrachloroethane 60204940.1 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
13.1 GCNTetrachloroethene60204940.1 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
13.1 GCNToluene60204940.1 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
13.1 GCN1,1,1-Trichloroethane 60204940.1 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
13.1 GCN1,1,2-Trichloroethane 60204940.2 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
13.1 GCNTrichloroethene60204940.1 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
16.1 GCNTrichlorofluoromethane60204940.2 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
16.1 GCN1,2,3-Trichloropropane 60204940.4 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
16.1 GCNVinyl Acetate 60204940.1 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
16.1 GCNVinyl Chloride 60204940.2 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
13.1 GCNXylenes, total 60204940.3 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
1150 GCNtrans-1,4-Dichloro-2-butene 60204940.7 02/19/16 16:0002/19/16 19:52ND
EPA 8260Bug/kg
dry
16.1 GCNIodomethane60204940.7 02/19/16 16:0002/19/16 19:52ND
EPA 8260B80-121103 %Surrogate: Dibromofluoromethane 602049402/19/16 16:0002/19/16 19:52
EPA 8260B70-131107 %Surrogate: 1,2-Dichloroethane-d4 602049402/19/16 16:0002/19/16 19:52
EPA 8260B79-12091 %Surrogate: Toluene-d8 602049402/19/16 16:0002/19/16 19:52
EPA 8260B80-121106 %Surrogate: 4-Bromofluorobenzene 602049402/19/16 16:0002/19/16 19:52
Page 11 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Client ID: BG(SS-4)
Date/Time Sampled: 2/18/2016 10:48:00AM
Matrix: Soil
Lab Number ID: AZB0541-04
Date/Time Received: 2/19/2016 9:00:00AM
Project:Yancey-Mitchell TS
Analyte Result RL
Preparation
Date
Analytical
DateMethodQual. DFUnits Init.BatchMDL
General Chemistry
EPA 9045DpH
Units
1H-01 JSpH602049202/19/16 11:0002/19/16 11:005.06
SOP
Moisture
% by
Weight
10.04 DDN% Solids 60205310.04 02/25/16 14:0202/25/16 14:0279.2
Metals, Total
EPA 6010Cmg/kg
dry
15.74 J FBSAntimony60300230.93 03/02/16 14:3003/08/16 12:481.22
EPA 6010Cmg/kg
dry
13.45 FBSArsenic60300231.43 03/02/16 14:3003/08/16 12:48ND
EPA 6010Cmg/kg
dry
11.15 FBSBarium60300230.05 03/02/16 14:3003/08/16 12:48134
EPA 6010Cmg/kg
dry
11.15 FBSBeryllium60300230.16 03/02/16 14:3003/08/16 12:482.20
EPA 6010Cmg/kg
dry
11.15 FBSCadmium60300230.04 03/02/16 14:3003/08/16 12:483.96
EPA 6010Cmg/kg
dry
11.15 FBSChromium60300230.41 03/02/16 14:3003/08/16 12:4853.8
EPA 6010Cmg/kg
dry
14.59 FBSCobalt60300230.15 03/02/16 14:3003/08/16 12:4834.4
EPA 6010Cmg/kg
dry
12.30 FBSCopper60300230.72 03/02/16 14:3003/08/16 12:4842.0
EPA 6010Cmg/kg
dry
12.87 FBSLead60300230.44 03/02/16 14:3003/08/16 12:4815.9
EPA 6010Cmg/kg
dry
12.30 B-01 FBSNickel60300230.12 03/02/16 14:3003/08/16 12:4843.0
EPA 6010Cmg/kg
dry
14.59 FBSSelenium60300231.31 03/02/16 14:3003/08/16 12:48ND
EPA 6010Cmg/kg
dry
11.15 FBSSilver60300230.10 03/02/16 14:3003/08/16 12:48ND
EPA 6010Cmg/kg
dry
123.0 J FBSThallium60300230.98 03/02/16 14:3003/08/16 12:481.20
EPA 6010Cmg/kg
dry
12.30 FBSVanadium60300230.18 03/02/16 14:3003/08/16 12:4865.4
EPA 6010Cmg/kg
dry
12.30 FBSZinc60300230.34 03/02/16 14:3003/08/16 12:48153
Volatile Organic Compounds by EPA 8260
EPA 8260Bug/kg
dry
182 GCNAcetone60204942.2 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
141 GCNAcrylonitrile60204940.6 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
14.1 GCNBenzene60204940.1 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
18.2 GCNBromochloromethane60204940.3 02/19/16 16:0002/19/16 20:22ND
Page 12 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Client ID: BG(SS-4)
Date/Time Sampled: 2/18/2016 10:48:00AM
Matrix: Soil
Lab Number ID: AZB0541-04
Date/Time Received: 2/19/2016 9:00:00AM
Project:Yancey-Mitchell TS
Analyte Result RL
Preparation
Date
Analytical
DateMethodQual. DFUnits Init.BatchMDL
Volatile Organic Compounds by EPA 8260
EPA 8260Bug/kg
dry
18.2 GCNBromodichloromethane60204940.3 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
18.2 GCNBromoform60204940.3 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
18.2 GCNBromomethane60204940.3 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
18.2 GCNCarbon Disulfide 60204940.3 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
14.1 GCNCarbon Tetrachloride 60204940.2 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
18.2 GCNChlorobenzene60204940.3 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
14.1 GCNChloroethane60204940.6 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
14.1 GCNChloroform60204940.2 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
18.2 GCNChloromethane60204940.08 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
14.1 GCNDibromochloromethane60204940.2 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
18.2 GCN1,2-Dibromo-3-chloropropane 60204940.5 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
18.2 GCN1,2-Dibromoethane 60204940.2 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
18.2 GCNDibromomethane60204940.1 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
18.2 GCN1,2-Dichlorobenzene 60204940.2 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
18.2 GCN1,4-Dichlorobenzene 60204940.1 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
14.1 GCN1,1-Dichloroethane 60204940.2 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
14.1 GCN1,2-Dichloroethane 60204940.1 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
14.1 GCN1,1-Dichloroethene 60204940.2 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
14.1 GCNcis-1,2-Dichloroethene 60204940.1 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
14.1 GCNtrans-1,2-Dichloroethene 60204940.3 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
14.1 GCN1,2-Dichloropropane 60204940.1 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
14.1 GCNcis-1,3-Dichloropropene 60204940.4 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
14.1 GCNtrans-1,3-Dichloropropene 60204940.3 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
14.1 GCNEthylbenzene60204940.1 02/19/16 16:0002/19/16 20:22ND
Page 13 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Client ID: BG(SS-4)
Date/Time Sampled: 2/18/2016 10:48:00AM
Matrix: Soil
Lab Number ID: AZB0541-04
Date/Time Received: 2/19/2016 9:00:00AM
Project:Yancey-Mitchell TS
Analyte Result RL
Preparation
Date
Analytical
DateMethodQual. DFUnits Init.BatchMDL
Volatile Organic Compounds by EPA 8260
EPA 8260Bug/kg
dry
141 GCNMethyl Butyl Ketone (2-Hexanone)60204941.0 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
18.2 GCNMethylene Chloride 60204940.2 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
182 GCNMethyl Ethyl Ketone (2-Butanone)60204941.4 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
141 GCN4-Methyl-2-pentanone (MIBK)60204940.4 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
14.1 GCNStyrene60204940.4 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
18.2 GCN1,1,1,2-Tetrachloroethane 60204940.2 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
14.1 GCN1,1,2,2-Tetrachloroethane 60204940.2 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
14.1 GCNTetrachloroethene60204940.2 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
14.1 GCNToluene60204940.1 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
14.1 GCN1,1,1-Trichloroethane 60204940.1 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
14.1 GCN1,1,2-Trichloroethane 60204940.3 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
14.1 GCNTrichloroethene60204940.2 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
18.2 GCNTrichlorofluoromethane60204940.2 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
18.2 GCN1,2,3-Trichloropropane 60204940.5 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
18.2 GCNVinyl Acetate 60204940.2 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
18.2 GCNVinyl Chloride 60204940.3 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
14.1 GCNXylenes, total 60204940.4 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
1200 GCNtrans-1,4-Dichloro-2-butene 60204940.9 02/19/16 16:0002/19/16 20:22ND
EPA 8260Bug/kg
dry
18.2 GCNIodomethane60204940.9 02/19/16 16:0002/19/16 20:22ND
EPA 8260B80-121101 %Surrogate: Dibromofluoromethane 602049402/19/16 16:0002/19/16 20:22
EPA 8260B70-131104 %Surrogate: 1,2-Dichloroethane-d4 602049402/19/16 16:0002/19/16 20:22
EPA 8260B79-12090 %Surrogate: Toluene-d8 602049402/19/16 16:0002/19/16 20:22
EPA 8260B80-121106 %Surrogate: 4-Bromofluorobenzene 602049402/19/16 16:0002/19/16 20:22
Page 14 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Client ID: Trip Blank
Date/Time Sampled: 2/18/2016 12:00:00AM
Matrix: Water
Lab Number ID: AZB0541-05
Date/Time Received: 2/19/2016 9:00:00AM
Project:Yancey-Mitchell TS
Analyte Result RL
Preparation
Date
Analytical
DateMethodQual. DFUnits Init.BatchMDL
Volatile Organic Compounds by EPA 8260
EPA 8260Bug/L 1100 GCNAcetone60205504.9 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 150 GCNAcrylonitrile60205501.8 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 12.0 GCNBenzene60205500.2 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 110 GCNBromochloromethane60205500.7 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 110 GCNBromodichloromethane60205500.6 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 110 GCNBromoform60205500.5 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 110 GCNBromomethane60205500.8 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 110 GCNCarbon Disulfide 60205500.9 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 12.0 GCNCarbon Tetrachloride 60205500.6 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 110 GCNChlorobenzene60205500.4 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 15.0 GCNChloroethane60205500.6 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 12.0 GCNChloroform60205500.3 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 110 GCNChloromethane60205500.4 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 110 GCNDibromochloromethane60205500.4 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 110 GCN1,2-Dibromo-3-chloropropane 60205502.0 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 110 GCN1,2-Dibromoethane 60205500.7 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 110 GCNDibromomethane60205500.7 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 110 GCN1,2-Dichlorobenzene 60205500.5 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 110 GCN1,4-Dichlorobenzene 60205500.2 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 15.0 GCNtrans-1,4-Dichloro-2-butene 60205501.5 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 12.0 GCN1,1-Dichloroethane 60205500.4 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 12.0 GCN1,2-Dichloroethane 60205500.3 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 12.0 GCN1,1-Dichloroethene 60205500.5 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 12.0 GCNcis-1,2-Dichloroethene 60205500.5 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 12.0 GCNtrans-1,2-Dichloroethene 60205500.5 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 12.0 GCN1,2-Dichloropropane 60205500.5 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 12.0 GCNcis-1,3-Dichloropropene 60205500.4 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 12.0 GCNtrans-1,3-Dichloropropene 60205500.4 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 12.0 GCNEthylbenzene60205500.3 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 110 GCNIodomethane60205500.6 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 110 GCNMethyl Butyl Ketone (2-Hexanone)60205500.9 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 15.0 GCNMethylene Chloride 60205500.5 02/23/16 13:0002/23/16 13:27ND
Page 15 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Client ID: Trip Blank
Date/Time Sampled: 2/18/2016 12:00:00AM
Matrix: Water
Lab Number ID: AZB0541-05
Date/Time Received: 2/19/2016 9:00:00AM
Project:Yancey-Mitchell TS
Analyte Result RL
Preparation
Date
Analytical
DateMethodQual. DFUnits Init.BatchMDL
Volatile Organic Compounds by EPA 8260
EPA 8260Bug/L 1100 GCNMethyl Ethyl Ketone (2-Butanone)60205501.1 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 110 GCN4-Methyl-2-pentanone (MIBK)60205501.7 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 15.0 GCNStyrene60205500.4 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 12.0 GCN1,1,1,2-Tetrachloroethane 60205500.5 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 12.0 GCN1,1,2,2-Tetrachloroethane 60205500.5 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 12.0 GCNTetrachloroethene60205500.4 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 12.0 GCNToluene60205500.3 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 12.0 GCN1,1,1-Trichloroethane 60205500.4 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 12.0 GCN1,1,2-Trichloroethane 60205500.8 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 12.0 GCNTrichloroethene60205500.4 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 110 GCNTrichlorofluoromethane60205500.5 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 110 GCN1,2,3-Trichloropropane 60205500.7 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 110 GCNVinyl Acetate 60205500.6 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 12.0 GCNVinyl Chloride 60205500.7 02/23/16 13:0002/23/16 13:27ND
EPA 8260Bug/L 15.0 GCNXylenes, total 60205500.4 02/23/16 13:0002/23/16 13:27ND
EPA 8260B80-12093 %Surrogate: Dibromofluoromethane 602055002/23/16 13:0002/23/16 13:27
EPA 8260B78-12095 %Surrogate: 1,2-Dichloroethane-d4 602055002/23/16 13:0002/23/16 13:27
EPA 8260B80-12097 %Surrogate: Toluene-d8 602055002/23/16 13:0002/23/16 13:27
EPA 8260B80-120110 %Surrogate: 4-Bromofluorobenzene 602055002/23/16 13:0002/23/16 13:27
Page 16 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Result RL Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
General Chemistry - Quality Control
MDL
Batch 6020492 - EPA 9045D
Duplicate (6020492-DUP1)Prepared & Analyzed: 02/19/16 Source: AZB0541-01
pH pH Units5.84 5.81 50.5
Batch 6020531 - % Solids
Duplicate (6020531-DUP1)Prepared & Analyzed: 02/25/16 Source: AZB0541-04
% Solids % by Weight79.5 0.04 79.2 100.40.04
Page 17 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Result RL Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Metals, Total - Quality Control
MDL
Batch 6030023 - EPA 3050B
Blank (6030023-BLK1)Prepared: 03/02/16 Analyzed: 03/08/16
Antimony mg/kg wetND5.00 0.81
Arsenic mg/kg wetND3.00 1.25
Barium mg/kg wetND1.00 0.04
Beryllium mg/kg wetND1.00 0.14
Cadmium mg/kg wetND1.00 0.04
Chromium mg/kg wetND1.00 0.36
Cobalt mg/kg wetND4.00 0.13
Copper mg/kg wetND2.00 0.63
Lead mg/kg wetND2.50 0.38
Nickel mg/kg wet0.13 2.00 J0.10
Selenium mg/kg wetND4.00 1.14
Silver mg/kg wetND1.00 0.09
Thallium mg/kg wetND20.0 0.85
Vanadium mg/kg wetND2.00 0.15
Zinc mg/kg wetND2.00 0.30
LCS (6030023-BS1)Prepared: 03/02/16 Analyzed: 03/08/16
Antimony mg/kg wet1025.00 100.00 80-1201020.81
Arsenic mg/kg wet99.6 3.00 100.00 80-1201001.25
Barium mg/kg wet1021.00 100.00 80-1201020.04
Beryllium mg/kg wet99.0 1.00 100.00 80-120990.14
Cadmium mg/kg wet1001.00 100.00 80-1201000.04
Chromium mg/kg wet1021.00 100.00 80-1201020.36
Cobalt mg/kg wet1024.00 100.00 80-1201020.13
Copper mg/kg wet1012.00 100.00 80-1201010.63
Lead mg/kg wet1012.50 100.00 80-1201010.38
Nickel mg/kg wet1012.00 100.00 80-1201010.10
Selenium mg/kg wet99.6 4.00 100.00 80-1201001.14
Silver mg/kg wet1041.00 100.00 80-1201040.09
Thallium mg/kg wet10220.0 100.00 80-1201020.85
Vanadium mg/kg wet1032.00 100.00 80-1201030.15
Zinc mg/kg wet99.8 2.00 100.00 80-1201000.30
Page 18 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Result RL Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Metals, Total - Quality Control
MDL
Batch 6030023 - EPA 3050B
Matrix Spike (6030023-MS1)Prepared: 03/02/16 Analyzed: 03/08/16 Source: AZB0541-01
Antimony mg/kg dry64.4 6.40 128.04 2.63 QM-0575-125481.04
Arsenic mg/kg dry1183.84 128.04 ND 75-125921.60
Barium mg/kg dry3451.28 128.04 258 QM-0275-125680.05
Beryllium mg/kg dry1321.28 128.04 3.94 75-1251000.18
Cadmium mg/kg dry1271.28 128.04 6.34 75-125940.05
Chromium mg/kg dry1851.28 128.04 62.0 75-125960.45
Cobalt mg/kg dry1645.12 128.04 51.8 75-125880.17
Copper mg/kg dry1792.56 128.04 62.4 75-125910.81
Lead mg/kg dry1363.20 128.04 19.5 75-125910.49
Nickel mg/kg dry1712.56 128.04 49.2 75-125950.13
Selenium mg/kg dry1165.12 128.04 ND 75-125911.46
Silver mg/kg dry1301.28 128.04 ND 75-1251010.11
Thallium mg/kg dry10325.6 128.04 ND 75-125811.09
Vanadium mg/kg dry2482.56 128.04 153 75-125750.20
Zinc mg/kg dry2582.56 128.04 157 75-125800.38
Matrix Spike Dup (6030023-MSD1)Prepared: 03/02/16 Analyzed: 03/08/16 Source: AZB0541-01
Antimony mg/kg dry63.3 6.40 128.04 2.63 20 QM-0575-12547 21.04
Arsenic mg/kg dry1163.84 128.04 ND 2075-12591 11.60
Barium mg/kg dry3601.28 128.04 258 2075-12580 40.05
Beryllium mg/kg dry1311.28 128.04 3.94 2075-12599 0.50.18
Cadmium mg/kg dry1271.28 128.04 6.34 2075-12594 0.40.05
Chromium mg/kg dry1851.28 128.04 62.0 2075-12596 0.10.45
Cobalt mg/kg dry1665.12 128.04 51.8 2075-12589 0.80.17
Copper mg/kg dry1862.56 128.04 62.4 2075-12596 40.81
Lead mg/kg dry1343.20 128.04 19.5 2075-12590 10.49
Nickel mg/kg dry1732.56 128.04 49.2 2075-12597 10.13
Selenium mg/kg dry1135.12 128.04 ND 2075-12588 31.46
Silver mg/kg dry1291.28 128.04 ND 2075-125101 0.50.11
Thallium mg/kg dry98.0 25.6 128.04 ND 2075-12577 51.09
Vanadium mg/kg dry2662.56 128.04 153 2075-12589 70.20
Zinc mg/kg dry2682.56 128.04 157 2075-12587 40.38
Page 19 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Result RL Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Metals, Total - Quality Control
MDL
Batch 6030023 - EPA 3050B
Post Spike (6030023-PS1)Prepared: 03/02/16 Analyzed: 03/08/16 Source: AZB0541-01
Antimony mg/L0.98 1.0000 0.02 80-12096
Arsenic mg/L0.91 1.0000 0.008 80-12090
Barium mg/L2.93 1.0000 2.01 80-12092
Beryllium mg/L1.02 1.0000 0.03 80-12099
Cadmium mg/L1.00 1.0000 0.05 80-12095
Chromium mg/L1.50 1.0000 0.48 80-120101
Cobalt mg/L1.29 1.0000 0.40 80-12089
Copper mg/L1.53 1.0000 0.49 80-120105
Lead mg/L1.05 1.0000 0.15 80-12090
Nickel mg/L1.35 1.0000 0.38 80-12097
Selenium mg/L0.89 1.0000 -0.02 80-12091
Silver mg/L1.01 1.0000 -0.004 80-120102
Thallium mg/L0.79 1.0000 0.0003 QM-0580-12079
Vanadium mg/L2.19 1.0000 1.19 80-120100
Zinc mg/L2.15 1.0000 1.22 80-12093
Page 20 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Result RL Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by EPA 8260 - Quality Control
MDL
Batch 6020494 - EPA 5035
Blank (6020494-BLK1)Prepared & Analyzed: 02/19/16
Acetone ug/kg wetND1002.7
Acrylonitrile ug/kg wetND500.7
Benzene ug/kg wetND5.0 0.1
Bromochloromethane ug/kg wetND100.3
Bromodichloromethane ug/kg wetND100.4
Bromoform ug/kg wetND100.4
Bromomethane ug/kg wetND100.4
Carbon Disulfide ug/kg wetND100.4
Carbon Tetrachloride ug/kg wetND5.0 0.2
Chlorobenzene ug/kg wetND100.3
Chloroethane ug/kg wetND5.0 0.8
Chloroform ug/kg wetND5.0 0.2
Chloromethane ug/kg wetND100.1
Dibromochloromethane ug/kg wetND5.0 0.2
1,2-Dibromo-3-chloropropane ug/kg wetND100.6
1,2-Dibromoethane ug/kg wetND100.2
Dibromomethane ug/kg wetND100.2
1,2-Dichlorobenzene ug/kg wetND100.2
1,4-Dichlorobenzene ug/kg wetND100.2
1,1-Dichloroethane ug/kg wetND5.0 0.3
1,2-Dichloroethane ug/kg wetND5.0 0.2
1,1-Dichloroethene ug/kg wetND5.0 0.2
cis-1,2-Dichloroethene ug/kg wetND5.0 0.2
trans-1,2-Dichloroethene ug/kg wetND5.0 0.4
1,2-Dichloropropane ug/kg wetND5.0 0.2
cis-1,3-Dichloropropene ug/kg wetND5.0 0.5
trans-1,3-Dichloropropene ug/kg wetND5.0 0.4
Ethylbenzene ug/kg wetND5.0 0.2
Methyl Butyl Ketone (2-Hexanone)ug/kg wetND501.2
Methylene Chloride ug/kg wet7.3 10 J0.2
Methyl Ethyl Ketone (2-Butanone)ug/kg wetND1001.8
4-Methyl-2-pentanone (MIBK)ug/kg wetND500.5
Styrene ug/kg wetND5.0 0.5
1,1,1,2-Tetrachloroethane ug/kg wetND100.3
1,1,2,2-Tetrachloroethane ug/kg wetND5.0 0.2
Tetrachloroethene ug/kg wetND5.0 0.2
Toluene ug/kg wetND5.0 0.2
1,1,1-Trichloroethane ug/kg wetND5.0 0.2
1,1,2-Trichloroethane ug/kg wetND5.0 0.4
Page 21 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Result RL Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by EPA 8260 - Quality Control
MDL
Batch 6020494 - EPA 5035
Blank (6020494-BLK1)Prepared & Analyzed: 02/19/16
Trichloroethene ug/kg wetND5.0 0.2
Trichlorofluoromethane ug/kg wetND100.3
1,2,3-Trichloropropane ug/kg wetND100.6
Vinyl Acetate ug/kg wetND100.2
Vinyl Chloride ug/kg wetND100.4
Xylenes, total ug/kg wetND5.0 0.4
trans-1,4-Dichloro-2-butene ug/kg wetND2501.1
Iodomethane ug/kg wetND101.1
ug/kg 50.000 80-121Surrogate: Dibromofluoromethane 9950
ug/kg 50.000 70-131Surrogate: 1,2-Dichloroethane-d4 9748
ug/kg 50.000 79-120Surrogate: Toluene-d8 9145
ug/kg 50.000 80-121Surrogate: 4-Bromofluorobenzene 9950
LCS (6020494-BS1)Prepared & Analyzed: 02/19/16
Benzene ug/kg47 50.000 71-12594
Chlorobenzene ug/kg51 50.000 70-120102
1,1-Dichloroethene ug/kg40 50.000 71-13981
Toluene ug/kg49 50.000 69-12097
Trichloroethene ug/kg50 50.000 75-12499
ug/kg 50.000 80-121Surrogate: Dibromofluoromethane 9949
ug/kg 50.000 70-131Surrogate: 1,2-Dichloroethane-d4 9748
ug/kg 50.000 79-120Surrogate: Toluene-d8 8844
ug/kg 50.000 80-121Surrogate: 4-Bromofluorobenzene 9749
Matrix Spike (6020494-MS1)Prepared & Analyzed: 02/19/16 Source: AZB0541-02
Benzene ug/kg38 50.000 ND 70-13776
Chlorobenzene ug/kg37 50.000 ND 33-13174
1,1-Dichloroethene ug/kg37 50.000 ND 48-14674
Toluene ug/kg37 50.000 ND 41-13374
Trichloroethene ug/kg37 50.000 ND 43-13874
ug/kg 50.000 80-121Surrogate: Dibromofluoromethane 10050
ug/kg 50.000 70-131Surrogate: 1,2-Dichloroethane-d4 10854
ug/kg 50.000 79-120Surrogate: Toluene-d8 9045
ug/kg 50.000 80-121Surrogate: 4-Bromofluorobenzene 10251
Page 22 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Result RL Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by EPA 8260 - Quality Control
MDL
Batch 6020494 - EPA 5035
Matrix Spike Dup (6020494-MSD1)Prepared & Analyzed: 02/19/16 Source: AZB0541-02
Benzene ug/kg35 50.000 ND 4170-13770 9
Chlorobenzene ug/kg33 50.000 ND 4633-13165 12
1,1-Dichloroethene ug/kg34 50.000 ND 5748-14669 8
Toluene ug/kg34 50.000 ND 6141-13368 9
Trichloroethene ug/kg33 50.000 ND 4943-13867 10
ug/kg 50.000 80-121Surrogate: Dibromofluoromethane 10050
ug/kg 50.000 70-131Surrogate: 1,2-Dichloroethane-d4 10754
ug/kg 50.000 79-120Surrogate: Toluene-d8 9045
ug/kg 50.000 80-121Surrogate: 4-Bromofluorobenzene 10150
Batch 6020550 - EPA 5030B
Blank (6020550-BLK1)Prepared & Analyzed: 02/23/16
Acetone ug/LND1004.9
Acrylonitrile ug/LND501.8
Benzene ug/LND2.0 0.2
Bromochloromethane ug/LND100.7
Bromodichloromethane ug/LND100.6
Bromoform ug/LND100.5
Bromomethane ug/LND100.8
Carbon Disulfide ug/LND100.9
Carbon Tetrachloride ug/LND2.0 0.6
Chlorobenzene ug/LND100.4
Chloroethane ug/LND5.0 0.6
Chloroform ug/LND2.0 0.3
Chloromethane ug/LND100.4
Dibromochloromethane ug/LND100.4
1,2-Dibromo-3-chloropropane ug/LND102.0
1,2-Dibromoethane ug/LND100.7
Dibromomethane ug/LND100.7
1,2-Dichlorobenzene ug/LND100.5
1,4-Dichlorobenzene ug/LND100.2
trans-1,4-Dichloro-2-butene ug/LND5.0 1.5
1,1-Dichloroethane ug/LND2.0 0.4
1,2-Dichloroethane ug/LND2.0 0.3
1,1-Dichloroethene ug/LND2.0 0.5
cis-1,2-Dichloroethene ug/LND2.0 0.5
trans-1,2-Dichloroethene ug/LND2.0 0.5
1,2-Dichloropropane ug/LND2.0 0.5
cis-1,3-Dichloropropene ug/LND2.0 0.4
Page 23 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Result RL Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by EPA 8260 - Quality Control
MDL
Batch 6020550 - EPA 5030B
Blank (6020550-BLK1)Prepared & Analyzed: 02/23/16
trans-1,3-Dichloropropene ug/LND2.0 0.4
Ethylbenzene ug/LND2.0 0.3
Iodomethane ug/LND100.6
Methyl Butyl Ketone (2-Hexanone)ug/LND100.9
Methylene Chloride ug/L0.5 5.0 J0.5
Methyl Ethyl Ketone (2-Butanone)ug/LND1001.1
4-Methyl-2-pentanone (MIBK)ug/LND101.7
Styrene ug/LND5.0 0.4
1,1,1,2-Tetrachloroethane ug/LND2.0 0.5
1,1,2,2-Tetrachloroethane ug/LND2.0 0.5
Tetrachloroethene ug/LND2.0 0.4
Toluene ug/LND2.0 0.3
1,1,1-Trichloroethane ug/LND2.0 0.4
1,1,2-Trichloroethane ug/LND2.0 0.8
Trichloroethene ug/LND2.0 0.4
Trichlorofluoromethane ug/LND100.5
1,2,3-Trichloropropane ug/LND100.7
Vinyl Acetate ug/LND100.6
Vinyl Chloride ug/LND2.0 0.7
Xylenes, total ug/LND5.0 0.4
ug/L 50.000 80-120Surrogate: Dibromofluoromethane 9347
ug/L 50.000 78-120Surrogate: 1,2-Dichloroethane-d4 9447
ug/L 50.000 80-120Surrogate: Toluene-d8 9648
ug/L 50.000 80-120Surrogate: 4-Bromofluorobenzene 10754
Blank (6020550-BLK2)Prepared & Analyzed: 02/24/16
Acetone ug/LND1004.9
Acrylonitrile ug/LND501.8
Benzene ug/LND2.0 0.2
Bromochloromethane ug/LND100.7
Bromodichloromethane ug/LND100.6
Bromoform ug/LND100.5
Bromomethane ug/LND100.8
Carbon Disulfide ug/LND100.9
Carbon Tetrachloride ug/LND2.0 0.6
Chlorobenzene ug/LND100.4
Chloroethane ug/LND5.0 0.6
Chloroform ug/LND2.0 0.3
Chloromethane ug/LND100.4
Dibromochloromethane ug/LND100.4
Page 24 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Result RL Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by EPA 8260 - Quality Control
MDL
Batch 6020550 - EPA 5030B
Blank (6020550-BLK2)Prepared & Analyzed: 02/24/16
1,2-Dibromo-3-chloropropane ug/LND102.0
1,2-Dibromoethane ug/LND100.7
Dibromomethane ug/LND100.7
1,2-Dichlorobenzene ug/LND100.5
1,4-Dichlorobenzene ug/LND100.2
trans-1,4-Dichloro-2-butene ug/LND5.0 1.5
1,1-Dichloroethane ug/LND2.0 0.4
1,2-Dichloroethane ug/LND2.0 0.3
1,1-Dichloroethene ug/LND2.0 0.5
cis-1,2-Dichloroethene ug/LND2.0 0.5
trans-1,2-Dichloroethene ug/LND2.0 0.5
1,2-Dichloropropane ug/LND2.0 0.5
cis-1,3-Dichloropropene ug/LND2.0 0.4
trans-1,3-Dichloropropene ug/LND2.0 0.4
Ethylbenzene ug/LND2.0 0.3
Iodomethane ug/L4.2 10 J0.6
Methyl Butyl Ketone (2-Hexanone)ug/LND100.9
Methylene Chloride ug/LND5.0 0.5
Methyl Ethyl Ketone (2-Butanone)ug/LND1001.1
4-Methyl-2-pentanone (MIBK)ug/LND101.7
Styrene ug/LND5.0 0.4
1,1,1,2-Tetrachloroethane ug/LND2.0 0.5
1,1,2,2-Tetrachloroethane ug/LND2.0 0.5
Tetrachloroethene ug/LND2.0 0.4
Toluene ug/LND2.0 0.3
1,1,1-Trichloroethane ug/LND2.0 0.4
1,1,2-Trichloroethane ug/LND2.0 0.8
Trichloroethene ug/LND2.0 0.4
Trichlorofluoromethane ug/LND100.5
1,2,3-Trichloropropane ug/LND100.7
Vinyl Acetate ug/LND100.6
Vinyl Chloride ug/LND2.0 0.7
Xylenes, total ug/LND5.0 0.4
ug/L 50.000 80-120Surrogate: Dibromofluoromethane 9145
ug/L 50.000 78-120Surrogate: 1,2-Dichloroethane-d4 9246
ug/L 50.000 80-120Surrogate: Toluene-d8 9347
ug/L 50.000 80-120Surrogate: 4-Bromofluorobenzene 10753
Page 25 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report No.: AZB0541
Result RL Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by EPA 8260 - Quality Control
MDL
Batch 6020550 - EPA 5030B
LCS (6020550-BS1)Prepared & Analyzed: 02/23/16
Benzene ug/L54 50.000 67-134108
Chlorobenzene ug/L48 50.000 69-12297
1,1-Dichloroethene ug/L54 50.000 58-142108
Toluene ug/L52 50.000 68-127104
Trichloroethene ug/L54 50.000 72-132108
ug/L 50.000 80-120Surrogate: Dibromofluoromethane 11156
ug/L 50.000 78-120Surrogate: 1,2-Dichloroethane-d4 10351
ug/L 50.000 80-120Surrogate: Toluene-d8 8743
ug/L 50.000 80-120Surrogate: 4-Bromofluorobenzene 9145
Matrix Spike (6020550-MS1)Prepared & Analyzed: 02/23/16 Source: AZB0580-03
Benzene ug/L46 50.000 ND 67-13492
Chlorobenzene ug/L54 50.000 ND 69-122109
1,1-Dichloroethene ug/L38 50.000 ND 58-14276
Toluene ug/L48 50.000 ND 68-12797
Trichloroethene ug/L48 50.000 ND 72-13296
ug/L 50.000 80-120Surrogate: Dibromofluoromethane 8844
ug/L 50.000 78-120Surrogate: 1,2-Dichloroethane-d4 8844
ug/L 50.000 80-120Surrogate: Toluene-d8 9347
ug/L 50.000 80-120Surrogate: 4-Bromofluorobenzene 10251
Matrix Spike Dup (6020550-MSD1)Prepared & Analyzed: 02/23/16 Source: AZB0580-03
Benzene ug/L44 50.000 ND 967-13487 5
Chlorobenzene ug/L48 50.000 ND 1369-12295 13
1,1-Dichloroethene ug/L37 50.000 ND 958-14274 3
Toluene ug/L44 50.000 ND 9 QR-0268-12788 10
Trichloroethene ug/L44 50.000 ND 1172-13289 7
ug/L 50.000 80-120Surrogate: Dibromofluoromethane 8945
ug/L 50.000 78-120Surrogate: 1,2-Dichloroethane-d4 8945
ug/L 50.000 80-120Surrogate: Toluene-d8 9547
ug/L 50.000 80-120Surrogate: 4-Bromofluorobenzene 9950
Page 26 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Laboratory Certifications
Code Description Number Expires
02069Louisiana 06/30/2016LA
381North Carolina 12/31/2016NC
E87315FL DOH (Non-Pot. Water, Solids) Eff:: 07/01/2015 06/30/2016NELAC
98011001South Carolina 06/30/2016SC
T104704397-08-TXTexas 03/31/2016TX
1340Virginia 12/14/2016VA
Page 27 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Legend
Definition of Laboratory Terms
ND
TIC
CFU
SOP
RL
- Not Detected at levels equal to or greater than the MDL
- Tentatively Identified Compound
- Colony Forming Units
- Method run per ASI Standard Operating Procedure
- Reporting Limit
Definition of Qualifiers
Sample Information
N-Nitrosodiphenylamine breaks down to diphenylamine in the GCMS; both analytes are reported as
N-Nitrososdiphenylamine. ASI is not NELAC certified for N-Nitrososdiphenylamine.
Phthalic acid and phthalic anhydride are reported as dimethyl phthalate
Maleic acid and maleic anhydride are reported as dimethyl malate
1,2-Diphenylhydrazine breaks down to azobenzene in the GCMS; both analytes are reported as azobenzene
DF - Dilution Factor
* - Analyte not included in the NELAC list of certified analytes.
- Method Detection LimitMDL
- Not Detected at levels equal to or greater than the RLBRL
QR-02 The RPD result exceeded the QC control limits; however, both percent recoveries were acceptable. Sample
results for the QC batch were accepted based on percent recoveries.
QM-05 The spike recovery was outside acceptance limits for the MS and/or MSD and/or PDS due to suspected matrix
interference. Sample results for the QC batch were accepted based on acceptable LCS recoveries.
QM-02 The spike recovery is outside acceptance limits due to insignificant spike amount as compared to sample
concentration.
J Estimated value less than Reporting Limit (RL) but greater than Method Detection Limit(MDL) (CLP J-Flag).
H-01 Sample was received outside of the EPA recommended holding time or was received with insufficient time to run
sample within the EPA recommended holding time.
B-01 Analyte was detected in the associated method blank at an estimated level equal to or greater than the MDL.
Sample values reported as greater than the MDL and less than 10x the method blank value are reported as
estimated values.
Note: Unless otherwise noted, all results are reported on an as received basis.
Page 28 of 29
ASI Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Norcross, GA 30092
[phone] FAX [phone]
ANALYTICAL SERVICES, INC.
Republic Services of North Carolina, LLC
1220 Commerce Street, SW
Conover NC, 28613
Attention: Mr. Ray Hoffman March 09, 2016
Report Notes
The collection date and times were not listed on the COC and were taken from the container labels. CFH
COC Goes Here
Page 29 of 29
LOG-IN CHECKLIST
Republic Services of North Carolina, LLC
Yancey-Mitchell TSProject:
Client:
Printed: 3/9/2016 3:55:51PM
Environmental Monitoring & Laboratory Analysis
[phone] FAX [phone]
110 Technology Parkway, Norcross, GA 30092
ANALYTICAL SERVICES, INC.ASI
Date Received:02/19/16 09:00 Logged In By:Charles Hawks
Work Order:AZB0541
OBSERVATIONS
Attn: Mr. Ray Hoffman
#Samples: 5 #Containers: 26
3.0 3.0
YES
Minimum Temp(C):Maximum Temp(C):
CHECKLIST ITEMS
COC included with Samples
Sample Container(s) Intact
Chain of Custody Complete
Sample Container(s) Match COC
Custody seal Intact
Temperature in Compliance
Sufficient Sample Volume for Analysis
Zero Headspace Maintained for VOA Analyses
Samples labeled preserved (If Applicable)
Samples received within Allowable Hold Times
Samples Received on Ice
Preservation Confirmed
YES
NO
YES
YES
YES
YES
YES
YES
YES
YES
YES
Custody Seal(s) Used:Yes
The collection date and times were not listed on the COC and were taken from the container labels. CFH
Comments:
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