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HomeMy WebLinkAbout7407_Pitt_C&DLandfillInc_CDLF_Phase1_Phase2_CAP_FID1419623_20200710SUMMIT DESIGN AND ENGINEERING SERVICES July 9, 2020 Ms. Jaclynne Drummond Hydrogeologist, Solid Waste Section Division of Waste Management North Carolina Department of Environmental Quality Reference: Groundwater Corrective Action Plan C&D Landfill, Inc., Phases 1 and 2 Greenville (Pitt County), North Carolina Permits 7407- CDLF- 2001 and 7407- CDLF- 2009 Dear Ms. Drummond: 100 East Six Forks Road, Suite 320 Raleigh, North Carolina 27609 Telephone (919) 732-3261 On behalf of C&D Landfill, Inc., I am pleased to present this Groundwater Corrective Action Plan, featuring Monitored Natural Attenuation and CDLF Closure as the selected remedy. This document was prepared by me, pursuant to completing the requirements for a CAP submittal begun by Wood Environmental, where I was formerly the project manager for all aspects of compliance for this Facility. The staff and I have maintained a cordial relationship; thus, preparation of this submittal represents a continuum of project understanding and planning. This document contains a thorough characterization of site conditions; a Water Quality Monitoring Plan intended to serve the next 5 years of Corrective Action; highlights of a Final Closure Plan for Phase 1; a Contingency Plan for action required if the data do not support the underlying premises upon which this plan is based; and a Financial Assurance calculation for the next 5 years of groundwater monitoring. The WQMP and Closure Plan documents are presented as appendices, such that there is inherent flexibility to make program changes as needed based on review of the data with the SWS. I appreciate your cooperation and input to the preparation of this CAP. Please contact me at your earliest convenience if you require further information. �N„CARo, Sincerely, ' GODavi� G rett, P.G., P.E. Senior Geotechnical Engineer cc: Judson Whitehurst — C&D Landfill Inc. • ; gill�o GA,,,0:,� My contact information is (919) 418-4375, Mobile, or david.garrett@summitde.net C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) NC Solid Waste Corrective Action Plan (CAP) Report Rev. 0 July 9, 2020 Page 2 Contents Chapter1 Introduction......................................................................................................................... 1.1 Site Background................................................................................................................... 1.2 Aquifer Characteristics........................................................................................................ 1.3 Contaminant Distribution.................................................................................................... Chapter 2 Site Conceptual Model........................................................................................................ 2.1 Regulatory Status................................................................................................................ 2.2 Contaminant Characterization............................................................................................ 2.2.1 Volatile Organic Compounds.................................................................................. 2.2.2 Appendix I and II Metals......................................................................................... 2.2.3 Suspected Legacy Contaminants............................................................................ 2.3 Contaminant Source Confirmation...................................................................................... 2.4 Source Control Measures.................................................................................................... 2.5 Groundwater End Use......................................................................................................... 2.6 Sensitive Receptor Pathways.............................................................................................. 2.7 Human Exposure Pathways................................................................................................. 2.7.1 Surface Water Pathway.......................................................................................... 2.7.2 Groundwater/Soil Pathway.................................................................................... 2.8 Background Concentrations................................................................................................ 2.9 Exceedances of Groundwater Quality Standards................................................................ 2.10 Exceedances of Surface Water Quality Standards.............................................................. 2.11 Landfill Gas Monitoring Results........................................................................................... 2.12 Media of Concern................................................................................................................ Chapter 3 Selected Remedy Technical Approach................................................................................ 3.1 Design and Specifications of Remedy.................................................................................. 3.2 Monitored Natural Attenuation.......................................................................................... 3.3 Phase 1 CDLF Unit Closure.................................................................................................. Chapter 4 Groundwater and Surface Water Monitoring..................................................................... 4.1 Revised Water Quality Monitoring Plan.............................................................................. 4.2 Revised Landfill Gas Monitoring Plan.................................................................................. 4.3 Special Monitoring Provisions............................................................................................. Chapter 5 Evaluation of Effectiveness and Report Submittals............................................................ 5.1 Corrective Action Performance Objectives......................................................................... .5 .5 .9 11 13 13 14 14 23 24 24 24 24 25 25 25 25 26 28 29 29 30 31 31 31 32 33 33 33 33 34 34 C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev. 0 Page 3 5.2 Physical Changes in Aquifer Conditions.................................................................................. 34 5.3 Chemical Changes in Aquifer Conditions................................................................................ 35 5.4 Physical Changes in Plume Characteristics.............................................................................. 35 5.5 Chemical Changes in The Plume.............................................................................................. 35 5.6 Refining the Site Conceptual Model........................................................................................ 36 5.7 CAP Modification.....................................................................................................................36 Chapter6 Contingency Plan.....................................................................................................................37 6.1 Factors that Could Affect MNA Performance Data.................................................................37 6.2 Triggering Events and Established Responses......................................................................... 37 Chapter 7 Schedule and Maintenance.....................................................................................................40 7.1 Timeline and Schedule............................................................................................................40 7.2 Operation, Monitoring & Maintenance..................................................................................41 7.3 Performing Operations............................................................................................................41 7.4 Longterm mechanical maintenance.......................................................................................41 7.5 Monitoring of the site equipment associated with the remedial measure ............................41 7.6 Corrective Action Oversight.................................................................................................... 41 7.7 Responsible Parties.................................................................................................................41 7.8 Notifications............................................................................................................................ 42 7.9 Safeguard Measures and Site Security....................................................................................42 7.10 Plan Modifications...................................................................................................................42 Chapter 8 Financial Assurance.................................................................................................................43 8.1 Basis of Calculation..................................................................................................................43 8.2 CA Monitoring for 5-year period............................................................................................. 43 Chapter 9 Completion of Groundwater Corrective Action......................................................................44 Chapter10 Bibliography.............................................................................................................................44 C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev. 0 Page 4 List of Tables Table 1 Monitoring Well Construction Data.......................................................................................... 7 Table 2 Historic Groundwater Elevation Data.....................................................................................10 Table 3 Aquifer Physical Properties.....................................................................................................11 Table 4 Horizontal Groundwater Characteristics................................................................................11 Table 5 Vertical Groundwater Characteristics.....................................................................................11 Table 6 Summary of Detections........................................................................................................... 12 Table 7 Metals in Background Samples...............................................................................................26 Table 8 Metals in Background Geochemistry...................................................................................... 27 Table 9 Selected VOCs in Background Samples................................................................................... 28 Table 10 Metals Exceeding 2L Groundwater Standards........................................................................ 28 Table 11 VOCs Exceeding 2L Groundwater Standards........................................................................... 28 Table 12 Constituents Exceeding 2B Surface Water Standards............................................................. 29 Table 13 Landfill Gas Readings............................................................................................................... 29 List of Figures Figure 1 Regional Topography Figure 2 Facility Plan/Local Topo Figure 3 Monitoring Locations Figure 4 Top of Confining Unit Figure 5 Groundwater Contours — Shallow Figure 6 Groundwater Contours — Deep Figure 7 Cross Section A Figure 8 Cross Sections B & D Figure 9 Cross Section C Figure 10 VOC Distribution — Shallow Detections AOC Figure 11 VOC Distribution — Deep Detections AOC Figure 12 Changes with Time (Benzene) Figure 13 Changes with Time (Vinyl Chloride) Figure 14 Surface Water Quality Figure 15 TBD Appendices Appendix 1 Excerpts from June 2019 Sampling Report (Wood statistical analysis) Appendix 2 Cumulative Detections Data Tables Appendix 3 Documentation of Phase 1 Closure Conditions Appendix 4 Remaining Phase 1 Closure Plans and Specs Appendix 5 WQMP Appendix 6 LFGMP C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev. 0 Page 5 Chapter 1 Introduction 1.1 Site Background C&D Landfill, Inc. owns and operates a Construction and Demolition Debris Landfill (CDLF), located at 802 Recycling Lane, Greenville (Pitt County), North Carolina. The Facility was developed in two non-contiguous footprints, Phases 1 and 2 approximately midway between US 264, i.e., a localized topographic divide, and Grindle Creek (Figure 1). The phases became operational in May 2001 and August 2009, respectively. Phase 1 was the regional repository for flood -damage debris after Hurricane Floyd in 1999. Phase 2 was a staging area, where flood -debris was stored temporarily. Both areas were used for agriculture, and a former railroad corridor traverses the site, including the northern Phase 2 footprint. Phases 1 and 2 are situated on slightly elevated mounds separated by a partially channelized, "central" drainage feature that originates onsite (Figure 2) and predates the landfill. Phase 2 is north and west of the central drainage feature, while Phase 1 is south and east. Both phases are isolated from their surroundings by deeply incised tributaries to Grindle Creek and associated wetlands, referred to as the "west" stream and the "south" stream. The drainage features converge just south of the site and flow south to Grindle Creek. Permitting studies have established the three water bodies as on -site discharge points for the uppermost aquifer. No downgradient groundwater users have been identified. The site is in the Coastal Plain physiographic and geologic province of North Carolina.' Immediate topography consists of a broad, gently sloping ridge varying from Elevations 22 to 26, along which US 264 divides surface flow between north and south. The site is located along the south side, adjacent to a several -mile wide floodplain with wetlands, occupied by Grindle Creek and further south by Tar River. The Facility Owner controls several hundred acres, extending from US 264 to the tributaries of Grindle Creek. The Facility contains scattered pockets of wetlands. Near the south Facility boundary, the ground surface elevations decrease by 6 to 10 feet into the stream bottoms. Downstream (south) areas are wooded marshlands with sluggish surface flow and scattered wetlands all the way to Grindle Creek. To the east and west exists farmland with scattered woods. To the north is farmland and the recycling yard/transfer station, separated from the Facility by an area of wetlands. Regulatory Changes Since Opening — Important events have occurred since the opening of Phase 1. Groundwater regulations were adopted in 2007 with lowered analytical and reporting limits for certain constituents. Newly added constituents, i.e., tetrahydrofuran and 1,4-dioxane, appear to be nearly ubiquitous and enforcement limits have yet to be established. Compliance standards (NCAC 2L) for some constituents have changed, including some currently being watched at this site. New threat -based Maximum Contaminant Levels (MCL's) may influence regulatory thresholds for corrective action. In time, emerging contaminants of concern for the solid waste industry may require future evaluation. A rule revision in 2007 resulted in more stringent final closure requirements for landfills receiving waste after June 30, 2008. In theory, those landfills were supposed to meet the new rules, but operating landfills undergoing incremental closure (as they were encouraged by the regulatory agency) were caught in a predicament with significant investment having been expended on the partial cover installation. That, and legislation (after commencement of operations) concerning waste acceptance criteria for unlined landfills, ostensibly complicates decisions pertaining to corrective action for this landfill. 1 North Carolina Geological Map, Scale 1:62,500, NC Geological Survey, 1985. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) NC Solid Waste Corrective Action Plan (CAP) Report Rev July 9, 2020 Page 6 Detection Monitoring - Groundwater is monitored at the following monitoring wells (Figure 3): Phase 1 MW-1d, MW-1s (background), MW-2d, MW-2s, MW-3d, MW-3s, MW-3A, MW-4, MW-5, MW-6, MW-7, MW-8, Phase 2 MW-9A (background), MW-10, MW-11, MW-12s, MW-14d, MW-14s, MW-15, MW-16, MW-17. Surface water is monitored on the boundary streams at the following locations: "South" SW-1 (background), SW-2, "East" SW-3, SW-4 (background, activated with Phase 2). Well Construction Data and hydrogeologic data are presented on Table I. Both phases have undergone detection -stage monitoring for metals and volatile organic compounds (VOCs), analytes on the US -EPA Appendix I list and field parameters, in accordance with North Carolina Solid Waste Section (SWS) protocols. Metals were detected from the beginning, indicating they occur in the background. The effect of turbidity was demonstrated early on, leading to adoption of "low -flow" sampling techniques. Benzene and vinyl chloride were first detected at MW-3s beginning in 2007, with concentrations slightly above the North Carolina 2L ground water quality standards (15A NCAC 2L) and/or then applicable Solid Waste Section Limits (SWSLs). The timing roughly coincides with early construction activities at Phase 2 but also the lower analytical reporting requirements. Other Appendix I VOCs, including acetone, 1,2-dichloroethane, cis-1,2-dichloroethene, ethylbenzene and toluene, were detected at concentrations below the SWSL at MW-3s. Later, concentrations of VOCs below SWSLs became detected intermittently and with less frequency at MW-8 and, after Phase 2 opened, at MW-12s. Over time, concentrations of detected constituents ("detects") have been gradually increasing but showing an apparent seasonality. Later the low concentrations of VOCs have spread to spread to MW-10 and MW-11 and occasionally other wells, including MW-5, MW-6, and MW-7. During the time of monitoring this facility, the regulations have added several new parameters, e.g., iron, tin, manganese, chloride, sulfide, tetrahydrofuran (THF) and 1,4-dioxane. Some of these are naturally in the background. Assessment Monitoring - C&D Landfill, Inc., initiated a ground water assessment monitoring program in August 2009, in accordance with North Carolina Solid Waste regulation 15A NCAC 13B .0545 (a) and (b). This included baseline sampling for a broader set of analytes on the US -EPA Appendix II list at all active wells, including a new well, MW-3A, located between MW-3s and the south Facility boundary. After the baseline sampling, the monitoring program returned to detection -stage monitoring, except wells MW-3s, MW-3A, MW-8, later MW-12s, and MW-1s (as background), where Appendix II sampling was continued. Low concentrations of a semi-volatiles, pesticides and herbicides have been detected sporadically. Since 2009, benzene and other petroleum -derived constituents (BTEX) have been detected above the 2L standards in wells MW-3s, MW-8 and MW-12s. Benzene has shown a steady or slightly increasing trend at MW-3s, while the "TEX" constituents have steadily decreased. Acetone, 1,2-dichloroethane, cis-1,2- dichloroethene and other chlorinated solvents have been reported with decreasing frequently and/or lower concentrations, while vinyl chloride has been increasing in MW-3s and MW-3A. Since May 2011, THE has been widely detected, as has 1,4-dioxane since monitoring began in May 2018. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) NC Solid Waste Corrective Action Plan (CAP) Report Table 1 Monitoring Well Construction Data July 9, 2020 Page 7 Elevation Data Piezometer Construction Data Hydrology Boring Number Boring Date PVC Pipe Elev. Ground El- Total Depth, ft. Yorktown Fm. Castle Hayne Fm. Beaufort Fm. Confining Layer Top of Screen Bot. of Screen Stickup ft. Monitored Unit Purpose Depth, ft. Elev. Depth, ft. Elev. Depth, ft. Elev. Depth, ft. Elev. Depth, ft. Elev. Depth, ft. Elev. MN-1d 10/12/2000 21.14 17.40 50.0 7.5 9.9 30.5 -13.1 7.5 9.9 40.0 -22.6 50.0 -32.6 3.74 AU-2 BG for Phase 1 MN-1s 5/2/2001 20.91 17.59 13.0 -- 3.0 14.6 13.0 4.6 3.32 AU-1 BG for Phase 1 WV-2d 10/9/2000 21.80 17.97 70.0 12.5 5.5 33.5 -15.5 61.5 -43.5 12.5 5.5 39.0 -21.0 49.0 -31.0 3.83 ALL2 MN-2s 5/3/2001 21.44 18.45 13.0 -- 3.0 15.5 13.0 5.5 2.99 AU-1 WV-3d 10/12/2000 22.83 19.37 50.0 14.0 5.4 27.5 -8.1 14.0 40.0 -20.6 50.0 -30.6 3.46 AU-2 MW-3s 8/6/2007 22.76 19.37 20.0 12.9 6.5 -- 5.0 14.4 20.0 -0.6 3.39 ALL1 MN-3A 8/10/2009 21.93 19.13 20.0 -- 5.0 14.1 20.0 -0.9 2.80 AU-1 MW-4 5/3/2001 18.42 14.83 13.0 -- 3.0 11.8 13.0 1.8 3.59 AU-1 MW-5 11/18/2002 17.90 14.80 18.0 18.4 -3.6 18.0 3.0 11.8 18.0 -3.2 3.10 AU-1 MN-6 5/5/2001 20.03 16.87 13.0 -- 3.0 13.9 13.0 3.9 3.16 AU-1 MW-7 5/5/2001 19.40 16.03 13.0 -- 3.0 13.0 13.0 3.0 3.37 AU-1 MW-8 11/18/2002 21.21 18.30 18.0 17.6 0.7 17.8 3.0 15.3 18.0 0.3 2.91 AU-1 MW-9A 8/7/2009 20.58 17.64 20.0 13.3 3.4 5.0 12.6 20.0 -2.4 2.94 AU-1 BG for Phase 2 MW-10 8/6/2009 16.61 14.16 20.0 13.3 3.4 5.0 9.2 20.0 -5.8 2.45 AU-1 MW-11 8/6/2009 14.49 11.60 20.0 15.5 2.1 5.0 6.6 20.0 -8.4 2.89 AU-1 MN-12s 8/10/2009 16.18 13.72 20.0 10.9 4.3 5.0 8.7 20.0 -6.3 2.46 ALL1 MW-13 8/7/2009 20.69 18.12 20.0 17.9 -1.2 5.0 13.1 20.0 -1.9 2.57 AU-1 MN-14d 12/17/2002 17.45 14.54 40.0 12.7 1.8 33.8 -19.3 1 j 12.7 35.0 -20.5 40.0 -25.5 2.91 CLL1 Old B-23d MW-14s 12/18/2002 16.60 13.90 20.0 13.0 0.9 5.0 8.9 20.0 -6.1 2.70 ALL1 Old B-23s MW-15s 12/18/2002 19.67 17.00 20.0 8.1 7.8 13 4 15.0 3.8 20.0 -1.20 2.8 AU-1 Old B-17s MW-16 6/16/2017 19.16 17 20.0 17.0 0.0 5.0 12 20.0 -2 TBD AU-1 MW-17 12/9/2002 20.74 18.18 20.0 17.0 1.3 18.1 0.1 15.0 3.2 20.0 -1.80 2.6 AU-1 Old B-20 Old B-1d 12/7/2001 20.23 17.33 80.0 17.0 1.3 23 -5.7 55.0 -37.7 65.0 -47.70 2.9 AU-2 Supplemental BG Old B-1s 12/14/2001 20.06 17.19 15.0 17.0 1.3 -- 10.0 7.2 15.0 2.20 2.9 AU-1 Supplemental BG AU-1 = Uppermost Aquifer CLL1 = Confining Layer AU-2 = Lower Aquifer Surface Water Sampling Locations Sampling Point Purpose Location Description Field Marker? SW-1 Background "South" stream At property line northeast of Phase 1 Y SW-2 Compliance "South" stream At property line southeast of Phase 1 Y SW-3 Compliance "West" stream Below convergence with ditch between Phases 1 and 2 Y SW-4 Background "West" stream Northwest of Phase 2 along former railroad corridor Y C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev. 0 Page 8 Alternate Source Demonstration — A study was performed in 2014-15, focusing on the soils within and near the central drainage feature with inconclusive results. No spills or incidents are known to have occurred. The study pointed out at least a few constituents, (acetone, 2-butanone, THF, and toluene) have been detected in the background samples from the "south" tributary. The literature suggests that benzene is the last of the BTEX group of compounds to degrade under natural conditions, as benzene is a stable "building block" for many common chemicals. Vinyl chloride, another "building block" constituent, is known to result from the degradation of chlorinated solvents and due to the breakdown of PVC and other polymers. While offsite sources could not be clearly identified, it is possible the detected contaminants were introduced inadvertently from the storm debris or soils brought into the facility. Assessment of Corrective Measures — A study was completed in 2017 to evaluate the extent and concentrations of detected contaminants. That study defined an Area of Concern (AOC) between the phases, i.e. the groundwater impact zone centered on the central drainage feature and/or a buried relict channel (of natural sources), possibly influenced by both phases. The AOC extends south from the channelized drainage feature near MW-8 to the southwest corner of Phase 1, near MW-3s where the first detections were observed. The AOC originates north of the drainage feature, along the south side of Phase 2, first detected at MW-12s but now showing at MW-11 and MW-10. Two principal Constituents of Concern (COC), benzene and vinyl chloride, were identified based on 2L or SWSL exceedances, along with minor constituents (detected below the 2L standards or SWSLs) occurring in the same plume. The timing and location of the first detections point to Phase 2, possibly influenced by prior site activity. Data from earlier wells, MW-9s and MW-9d, long since abandoned and replaced by MW-3s and MW-3d, indicated no impact at the southwest corner of Phase 1. However, MW-3s showed an immediate impact during the initial sampling in November 2007, prior to construction of the last cell in Phase 1 but after early stage ground improvements had begun in Phase 2. The ACM also discussed the likelihood of inherent changes in aquifer chemistry, e.g., reduced oxygen levels beneath the landfill units, and natural differences between recharge and discharge zones, as influences on groundwater quality. Monitored Natural Attenuation — Based on the preliminary indications of the ACM, a study was conducted in 2018-19 to further evaluate the groundwater chemistry pursuant to selecting an appropriate remedy. The study included four semi-annual sampling events that identified favorable concentrations of constituents that promote biological activity, along with other conditions that will likely reduce the concentrations of the COCs, including various dissolved gases, fatty acids, nitrate, alkalinity, total organic carbon and oxygen demand. Excerpts of the June 2019 sampling report are found in Appendix 1. Corrective Action Permit Modification — The results were reported in the October 2019 groundwater monitoring report, followed by a letter request in December 2019, which states "... the primary remedy selected for VOCs in [the site] groundwater is MNA ... appropriate because VOC concentrations are limited to the shallow aquifer, groundwater monitoring data indicates that natural attenuation of VOCs is occurring, and concentrations near the perimeter of the site are not increasing." In the approval letter, SWS officials acknowledged "... C&D Landfill, Inc. has selected the following groundwater correction action remedy: • Monitored Natural Attenuation (MNA), and • Landfill Capping. In accordance with 15A NCAC 13B .0545(e)(2), the selected remedy must: C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) NC Solid Waste Corrective Action Plan (CAP) Report Rev. 0 July 9, 2020 Page 9 (A) be protective of human health and the environment. (B) attain the approved ground -water protection standards. (C) control the source(s) of releases to reduce or eliminate, to the maximum extent practicable, further releases of constituents into the environment that may pose a threat to human health or the environment; and (D) comply with standards for management of wastes." As a result, this document is the required Corrective Action Plan (CAP) prepared in accordance with 15A NCAC 13B .0545, 15A NCAC 2L, and the NC Solid Waste Section Guidelines for Corrective Action at Solid Waste Management Facilities. This plan details the remedy approved by the SWS, i.e., specific plans and schedule for final closure of C&D Landfill, Inc. (Closed Phase I and Active Phase II) and a Water Quality Monitoring Plan. This plan also a discusses financial assurance, a tentative contingency plan, and a timeline/schedule for activities during the next five years following the approval of the CAP. This plan will be reviewed on a 5-year recurring cycle, and based on data and future regulatory changes, the plan may require revision and update. This overarching plan contains many parts and is intended to be flexible. 1.2 Aquifer Characteristics The following discussion is consistent with the 2017 ACM report. Published literature indicates that upland areas throughout the region are underlain by relatively thin, undifferentiated Quaternary surface deposits,z characterized as stratified fluvial deposits containing layers or pockets of low permeability and high permeability horizons. Test borings confirm the surficial deposits (uppermost aquifer) consist of poorly stratified terrestrial sand and clay layers, extending to depths varying between 12 to 30 feet. The author believes the uppermost formation contains relict channels, i.e. buried "oxbows" that form preferential pathways for groundwater movement, based on drilling data and morphological features. One such feature may pass through the site, based on surface morphology (Figure 4), possibly aligning with the central drainage feature between the phases. The upper sands are underlain by the Yorktown Formation, presenting as a sticky, silty clay, easily identified by a deep green -gray color and a distinctive turritella fossil -marker bed. A two -aquifer system is shown in map view (Figures 5 and 6) and in cross sections based on site characterization studies (Figures 7 — 9), i.e. upper and lower sandy units separated by the silt -clay confining layer. Ground water flow in both aquifers is toward the south and west, with upper unit contours that subtly reflect the surface topography. Groundwater depths vary from approximately 3 to 9 feet beneath the surface (El. 15 to El. 10 feet, MSL), deeper in the higher elevations and subject to seasonal variation. Horizontal hydraulic gradients in the upper aquifer are slight and generally directed south and west (Figure 5). In the deep aquifer, the horizontal gradient is nearly flat and toward the south (Figure 6). The early data show an upward vertical gradient (intermittently) in piezometers and some well couplets. Generalized aquifers and flow conditions from the permitting studies follow. Historical Groundwater Elevation Data is found on Table 2. z Hydrogeologic Framework of the North Carolina Coastal Plain Aquifer System, U.S. Geological Survey Open File Report 87-690, USGS. C&DLandfU. Inc. Phases and 2(7407-CDLF-2001-2X09) NC Solid Waste Corrective Action Plan (CAP) Report Rev Table Historic Groundwater Elevation Data July 9.2020 C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) NC Solid Waste Corrective Action Plan (CAP) Report Rev. 0 July 9, 2020 Page 11 The upper sand aquifer is approximately 8 to 15 feet thick. The silt -clay is approximately 8 to 15 feet thick and is present at each test boring. The deeper aquifer thickness is 25 to 30 feet (observed). The deeper clay is 10's or 100's of feet thick (literature). Physical properties are summarized as follows: Table 3 Aquifer Physical Properties Hydrogeologic Flow Grain Size Distribution Unit Regime % Gravel %Sand %Silt %Clay AU-1 Upper Sand 0 - 0.3 65 - 97 3 - 30 5-9 CU-1 Confining Clay 0 40 - 50 37 - 49 10 - 13 AU-2 Lower Sand 0 62 34 4 CU-2 Confining Clay 1 31 31 37 Table 4 Horizontal Groundwater Characteristics Hydrogeologic Effective Horizontal Conductivity Typ. Ground Water Velocity Unit Porosity Gradients cm/sec inches/day feet/year AU-1 0.5 0.05 — 0.039 10-3 to 10-4 0.505 15 CU-1 0.5 0.002 — 0.01 10-6 to 10-' 0.014 0.4 AU-2 0.4 0.001— 0.005 10-4 to 10-5 0.018 0.5 CU-2 0.35 0.008 10"6 0.004 0.1 Table 5 Vertical Groundwater Characteristics Monitoring Nearest CDLF Observed Indicated Well Borings Phase Gradients Direction MW-2 pair B2s/B2d 1 -0.030 to -0.035 Upward MW-4 616/1318 1 0.040 Down MW-6 1315/1317 1 -0.018 Up MW-10 68/138A 11 -0.018 to -0.76 Up MW-11 B15s/B15d 11 0.042 to 0.061 Up MW-14 pair B23s/B23d 11 -0.095 to 0.042 Varies MW-15 B17s/B17d 11 0.024 to 0.072 Up MW-16 135/135A 11 0.066 to 0.428 Down 1.3 Contaminant Distribution The following data represent "full disclosure" of all detections, condensed from the Cumulative Detections Tables, found in Appendix 2. Some detections represent legacy effects of prior activities at the site and/or traces of residuals from laboratory equipment cleaning. Refer to Section 2.1. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) NC Solid Waste Corrective Action Plan (CAP) Report Table 6 Summary of Detections July 9, 2020 Page 12 Analy to J w 7 Jv N Q � > > 0 It O N Cn cn N > M > (a > CQ I� 00 m Q O> CD N (M LO CO f� N L U 0 U) U m N CO C9 m N Acetone 6000 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Acenaphthene 80 Y Y Y Y Benzene 5 1 Y Y Y Y Y Y Y Y Y Y Y 2-Butanone 4000 Y Y Y Y Y Y Y Y Y Y Y Y Carbon Disulfide 700 Y Y Y Y Y Y Y Y Y Y Y Chlorobenzene 50 Y Chloroethane 3000 Y Y Y Y Chloromethane 3 Y Y Y Y Y Y Y Y Y Y Y Y 1,2-Dichloroethane 0.4 Y Y Y Y Y Cis- 1,2-Dichloroethene 70 Y Y Y Y Y Y Y Y Ethylbenzene 600 Y Y Y Y Y Y Y Methylene Chloride 5 Y Y Y Y Y Y Y Y Y Y Naphthalene 6 Y Y Y Y Y Y Y Tetrahydrofuran NA NA Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Trichloroethene 3 Y Y Toluene 600 Y Y Y Y Y Y Y Y Y Vinyl chloride 2 0.03 Y Y Y Y Y Y Y Y Y Y Y Xylene 500 Y Y Y Y 2-4-D 70 Y Y Y Y Y Dinoseb 7 Y Y Y Y Y 2,4,5-TP 50 Y Y Y Y Y 2,4,5-T NE Y Y Y Y Y beta-BHC 0.02 Y Y Y Y Y Aldrin 0.05 Y Y Y Y Y Dibenzofuran 28 Y Y Y Y Y Endrin Aldehyde 2 Y Y Y Y Y 114-Dioxane 3 Y Y Y Y Y Y Y Y Y Y Y Antimony 6 1 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Arsenic 10 10 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Barium 2000 700 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Beryllium 4 4 Y Y Y Y Y Y Y Y Y Y Cadmium 1 2 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Chromium 100 10 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Cobalt IMAC = 1 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Copper 1300 1000 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Lead 15 15 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Mercury 2 1 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Nickel 100 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Selenium 50 20 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Silver 20 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Thallium 20 0.2 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Tin IMAC = 2000 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Vanadium IMAC = 0.3 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Zinc 1000 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 13 Chapter 2 Site Conceptual Model A three-dimensional representation of site conditions that represent what is known (or suspected) about the physical, chemical, and biological processes that determine the transport of contaminants, from the source, through environmental media, to potential receptors, is based on the discussion in Section 1.2. Graphical depicture is in the form of the maps and sections found in the Figures. A two -aquifer system is conceptualized, with the upper aquifer described as a relatively isolated, shallow closed -loop, unconfined porous media contained within near -surface fluvial sands with interspersed clay, separated from a deeper regional sandy aquifer by a partial confining layer. Groundwater depths typically vary from 3 to 9 feet. Horizontal gradients and velocities are slow; vertical gradients are upward. The uppermost sand aquifer (AU-1) is characterized as unconfined porous media, which recharges on -site beginning at a divide coinciding with US 264. Discharge occurs at the blue -line streams that comprise the south and west facility boundaries, and the central drainage feature discussed in Section 1.1. Groundwater contour mapping indicates local convergence of groundwater flow, a subtle reflection of the surface streams, which come together just south of the Facility. Undeveloped, low-lying lands to the south are wooded, marshy and contain numerous small streams serving as the discharge features. Groundwater velocities in the lower sand are estimated as approximately 15 feet per year. The deeper sand aquifer (AU-2) is characterized as partially confined, porous media with a lower conductivity and hydraulic gradient than the upper sand. The deeper aquifer is more regional and is recharged from several miles distant, with some expected contribution from the upper aquifer, i.e., a "leaky" aquifer system. The interstitial silt -clay imparts sufficient separation to result in upward gradients. The gradients also suggest the discharge zone for the regional aquifer is nearby, interpreted as numerous streams within the floodplain south of the site, the larger streams (i.e., Grindle Creek) and Tar River. Groundwater velocities in the lower sand are estimated as approximately 0.5 feet (6 inches) per year. Test borings reveal the upper sand contains significant interspersed organic content, i.e., decayed plant debris, roots, and peat. The wooded marshland into which the shallow groundwater beneath the Facility discharges is expected to have a high organic content. Highly organic soils, often but not exclusively associated with wetlands, are recognized as natural groundwater filters, providing "treatment" for low concentrations of many common contaminants. Based on topographic relationships, it is unlikely that the Facility influences shallow groundwater beyond a radius of a few hundred feet. Based on the conceptual model, discharge from the uppermost aquifer is filtered through natural organic deposits before reaching surface waters. Due to the upward vertical gradients, the Facility is believed to have minimal influence on the deep aquifer. Regional groundwater use is sparse, and municipal water is widely available. Suspected local ground water users are more than one thousand feet southeast of the Facility, considered cross gradient from the Facility (not down gradient). To the south is one suspected ground water user, separated from the Facility by several thousand feet and a major stream (Grindle Creek), so this groundwater user is not considered down gradient either. Refer to Figures 1 and 2. 2.1 Regulatory Status The ACM recommendations of Monitored Natural Attenuation and future landfill closure have been approved. Neither of the CDLF phases are certified closed. There is no apparent risk to the public. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 2.2 Contaminant Characterization July 9, 2020 Page 14 The following is excerpted from the June 2019 Water Quality Monitoring Report (used with permission). That report, dated October 2019 (DIN 1359974), presented a summary of four semi-annual sampling events focused on Appendix II and MINA parameters. Contaminants of concern identified in the 2017 ACM Report are discussed with historical context and relative to natural attenuation parameters. Mann - Kendall statistical analyses were used to assess trends in selected VOC concentrations over time since November 2015. Graphical depiction of the data confirms the findings of the statistical analyses. 2.2.1 Volatile Organic Compounds Benzene has historically been reported in samples from wells MW-3A, MW-3S, MW-8, and MW-12S at concentrations that exceed the 2L Groundwater Standard. Benzene has also been reported in samples from MW-10 since May 2016 and MW-11 since December 2017. Mann -Kendall trend analysis of concentrations in samples from MW-3A, MW-3s, MW-8, and MW-12s since November 2015 indicate that concentrations are probably increasing in MW-12s, stable at MW-3s and MW-8, and that trends cannot be identified at MW-3A (i.e., similar to stable). While reports of benzene in samples from MW-10 and MW-11 are a recent occurrence, Mann Kendall analysis indicates that since benzene was first reported in the wells no trend is evident at MW-10, and concentrations at MW-11 are stable. Field measurements and natural attenuation parameters reported during the June 2019 monitoring event suggest that groundwater conditions at wells where benzene is reported are somewhat reducing and not conducive to aerobic biodegradation of benzene; however the absence of increasing concentration trends (with the possible exception of MW-12s) suggests that benzene is naturally attenuating at these locations at a rate roughly equivalent to the "input" of mass to the aquifer system. Graphical trends covering 2001 — 2019 (Charts 1A, 1B, 1C and 1D) confirm the concentrations may be leveling out at MW-3s, MW-3A, MW-8, and still rising at MW-10, MW-11, and MW-12s. Vinyl chloride (VC) concentrations that exceed the 2L Groundwater Standard have been reported consistently in samples from MW-12s since 2012 and MW-10 since 2016. Mann -Kendall trend analysis indicates that VC concentrations over the past three years are stable at MW-12s and a trend cannot be identified at MW-10. Sporadic exceedances have also been reported in samples from MW-3A, MW-3s, MW-6, MW-7, and MW-8. VC was reported in the samples from MW-11 and MW-14s for the first time in June 2019. VC in groundwater is often the result of the reduction of larger chlorinated ethenes and ethanes, such as trichloroethylene (TCE) and cis-1,2-dichloroethylene (cis-1,2-DCE). Based on the historical presence of these compounds at the site (not observed recently) and considering the reducing groundwater conditions observed, this reduction appears to be the source of VC and is evidence of natural attenuation processes taking place. The current absence (or decreasing concentration) of larger chlorinated ethenes in groundwater samples and the lack of increasing VC concertation trends suggests that additional VC source mass may not be present, and that the VC is attenuating naturally. Graphical trends covering 2001— 2019 (Charts 2A, 2B, 2C and 2D) confirm the concentrations may be still be gradually rising at MW-3s, MW-3A, MW-8. At MW-12s the data shows an apparent peak and may be trending downward. These findings are not conclusive, but the data may warrant cautious optimism. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Chart 1A -- Benzene CAS 71-43-2 MCL = 5 UG/L (2018) m m m — 3.0 ` 2.00 0 2s 2.10 2 0 2.10 2,0 n 1.0o 1.90 n A �SO/ � 1. 1.60 0 y =-2E-O8x2 + 0.0013x - 25.812 1,17 13 1, 0 0 2L STD = 1 UG/L 0 7o 60 v=-zE-oax2+o.002X -43so6 So 0 So 0, os o.ao o. — 0 30 MDL = 0.24 UG/L (2018) 0.00 0.00 0.00 o.00 o.00 oo o.o0 0.00 ®.00 o.o -A-0- 00 0. 00 z° a -— o 7 0�j i —— Z a .� LL o o ¢' Z BMW 3S BMW 8 Poly. (MW 3S) Poly. (MW-6) July 9, 2020 Page 15 C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 16 MCL = 5 UG/L (2018) 4.5 4.0 3,5 3,0 0 2,5 2.0 1.5 Chart 1B -- Benzene CAS 71-43-2 2.52 2.56 mm 1.10 1.10 ml im 1.0 2L STD = 1 UG/L V a'0 0 0,50 0,4 o,s o. MDL = 0.24 UG/L (2018) 0. 0.00 0.000.00 0.00 0.40.00 0.00 0.00 0.00 0.00 0.00 0.00 0. 0.00 0.00 0. 00 0. o,o BMW-10 BMW-11 BMW-12S C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 MCL = 5 UG/L (2018) 4.5 4.0 3.5 3.0 0 25 2.0 1.5 1.0 2L STD = 1 UG/L Chart 1C -- Benzene CAS 71-43-2 !�9 ME 0m m 0.5 0.40 0. 40 MDL = 0.24 UG/L (2018) 30 0 0 01 30 0.31 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 00 0.00 0.00 m 00 0.00 0.0m000 ®.00 0.0 0.00 0.00 0.00 0.00 0 0 0.00 0.00 00 0.00 0.00 .00 0.00 0.00 0.0 0.00 00 0.0 rvo ory BMW-6 BMW-7 BMW-8 Poly. (MW-0) y = -2 E-08x2 + 0.002x - 43.506 July 9, 2020 Page 17 C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Chart 1D -- Benzene CAS 71-43-2 MCL = 5 UG/L (2018) 4.5 4.0 3.5 3. 0 3,0 2.6000 2,5 2,10 2 0 2,10 2. 2.0 1.81 1,70 1 1.69 50 50 1 49 1.5 30 30 1, 20 1. 20 Y ' -2 E-08x2 + 0.0013X - 25.812 1. 1.10 ^ 1. 0 1,00 100 w 1.0 + 0 1.0 2L STD = 1 UG/L 07 a6o aeo 0,s0 o. 0,s M DL = 0.24 UG/L (2018) 0 0,00 0,0� o BMW-3S BMW-3A Po1y.(MW-3S) July 9, 2020 Page 18 C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 19 Chart 2A --Vinyl Chloride CAS 75-01-4 4.5 4.0 3,5 3,0 O 2,5 MCL= 2 UG/L (2018) zoo w 6m 0,5 2L = 0.3 UG/L (2018) 0.10 y=6E-05x-2.1317 MDL = 0.12 UG/L (2018) y = 5E-05x - 1.9659 0,0 BMW-35 BMW-8 L—r(MW-35) Ll—(MW-B) C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 20 Chart 213 --Vinyl Chloride CAS 75-01-4 n0 3,5 3,0 0 25 2.0 1.5 1.0 0,5 0,0 , . . BMW-10 BMW-11 BMW-125 Pdy.(MW-125) C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 21 Chart 2C -- Vinyl Chloride CAS 75-01-4 4.5 4.0 3,5 3,0 O 2,5 MCL = 2 UG/L (2018) 20 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . _ am 1.5 1,40 1.0 oneo 0,5 2L = 0.3 UG/L (2018) — 1 MDL=0.12UG/L(2018) 0,0 r1 r1 rl1 r1�r1Ti—i—r1 S r BMW-6 BMW-] BMW-8 Lin-r(MW-0) L—.r(MW-7) y = 5 E-05x-1.9659 y = 3 E-05x - 0.9906 C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 22 Chart 2D -- Vinyl Chloride CAS 75-01-4 MCL = 2 UG/L (2018) zoo 2.0 — — — — — — — — — — — — — — — — — — — — �r m 0,5 2L = 0.3 UG/L (2018) MDL = 0.12 UG/L (2018) 00 mm BMW-3S BMW-3A L-1(MW-3S) an y = 6 E-05x - 2.2317 C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 23 1,4-Dioxane concentrations exceeded the 2L Groundwater Standard in shallow samples from across the site, including once in a background stream sample, with the exceptions of the wells on the western and northern sides of Phase 2. The highest concentrations thus far have been reported at MW-3s (326 µg/L) and MW-8 (218 µg/L) in December 2019. 1,4-dioxane was once used as stabilizer for other VOCs, but the compound can be found in glues, inks, personal care products and cleansing agents. 1,4-dioxane is highly soluble and resistant to degradation, however published research is showing promising indications of naturally occurring microbial improvement.' The compound has only been sampled three times as of this writing, thus a trend analysis cannot be established. Due to the ubiquitous nature of 1,4-dioxane, regulatory directives have not been determined, thus it is an "emerging contaminant of concern." 2.2.2 Appendix I and II Metals Each of the metals discussed below occur naturally at the site and are present in background samples. Changes in the concentrations of these metals likely reflect changing groundwater conditions beneath the landfill, i.e., a potential shift toward reducing (not oxidizing) conditions indicated by field measurements and other natural attenuation parameters. Arsenic has been reported in samples from each monitoring well and surface water sampling location, including those monitoring background conditions. Concentrations exceeding the 2L Groundwater Standard have been reported in MW-3s, MW-3A, MW-5, MW-6, MW-7, MW-8, and MW-12s. Currently, samples from MW-3s, MW-3A, MW-6, MW-8, and MW-12s were reported to contain arsenic concentrations above its 2L Standard. Barium has been reported in samples from each monitoring well and surface water sampling location, including those monitoring background conditions. Concentrations exceeding the 2L Groundwater Standard have been reported in MW-3s, MW-6, MW-7, and MW-12s. Currently, samples from MW-6 and MW-12s were reported to contain barium concentrations above its 2L Standard. Chromium has been reported in samples from each monitoring well and surface water sampling location, including those monitoring background conditions. Historically, elevated chromium concentrations reported in samples from several wells decreased overtime to below the 2L Groundwater Standard. More recently, chromium concentrations reported in samples from MW-3s, MW-5, MW-7, MW-8, MW-10, and MW-12s have exceeded the 2L Groundwater Standard. Currently, samples from MW-3S, MW-7, MW-8, MW-10, and MW-12s were reported to contain chromium concentrations above its 2L Standard. Cobalt has been reported in samples from each monitoring well and surface water sampling location, including those monitoring background conditions. Reported cobalt concentrations typically exceed the 1.0 IMAC in samples from MW-2s, MW-3s, MW-3A, MW-5, MW-6, MW-7, MW-8, MW-12s, and MW-14s. Currently, samples from MW-2s, MW-3s, MW-3A, MW-5, MW-6, MW-7, MW-8, MW-10, and MW-12s were reported to contain cobalt concentrations above its 2L Standard. Vanadium has been reported in samples from each monitoring well and surface water sampling location, including those monitoring background conditions. Reported concentrations fluctuate over time and generally exceed the 0.3 µg/L IMAC; however, exceedances are less frequent in the deep wells. Higher concentrations are reported in samples from MW-12s more consistently than in samples from other wells. 3 Steffan, R., Biodegradation of 1,4-Dioxane, Strategic Environmental Research and Development Program (SERDP), Environmental Security Technology Certification Program (ESTCP), ER-1422, https://www.serdp-estcp.org/. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 24 2.2.3 Suspected Legacy Contaminants A few intermittent detections of pesticides (Aldrin, beta-BHC, Dibenzofuran and Endrin aldehyde) and herbicides (Dinseb"', Silvex"', 2-4-D and 2-4-5-T) have shown in the cumulative data (Appendix 2). None of these constituents have exceeded 2L Standards, but Aldrin and beta-BHC have exceeded 2L IMACs although the lab flagged these detections with "J". These constituents were all banned since before the landfill came into existence except 2-4-D. Most of the detections occurred prior to 2015 except pesticides were first observed at MW-3s and MW-12S in 2018. These constituents are relict of past agricultural activities and, hence, none are believed to be a concern. These constituents require a special sampling and analysis regimen, and plans are to petition the SWS to curtail these from future monitoring. Several Polycyclic Aromatic Hydrocarbons (PAHs) have shown in the cumulative data. These compounds (acenaphthene, benzo[]pyrelene, fluorene, indeno[]pyrene, and naphthalene) are known to result from incomplete combustion of organic materials. The occurrence is believed to result from a documented 2005 fire in Phase 1 and the intake of burned materials in the C&D waste stream in Phase 2. These constituents have been detected mostly after 2016 at MW-3, MW-3s, MW-8 and MW-12s. None of the detections exceed promulgated standards and, hence, none are believed to be a concern. These constituents require a special sampling and analysis regimen, and plans are to petition the SWS to curtail these from future monitoring. Petroleum -associated (BTEX) compounds have been detected intermittently, although it is undetermined if these are associated with past uses of the site. Benzene has been discussed as a COC (Section 2.2.1) and, in addition to fuels, benzene has applications as a solvent and for intermediary steps in the production of plastics, rubber, asphalt, glues, inks, paints and sealants, any of which could get into the C&D waste stream. The other compounds have similar industrial applications and have been detected below the 2L Standard at MW-3s (in the initial sampling event and intermittently thereafter) and later at MW-3A, MW-12s, MW-14s (all intermittently). Toluene has been detected in the background surface water samples. Ethylbenzene has been detected once at the background well MW-9A. Xylene has been mostly detected at MW-12s. 2.3 Contaminant Source Confirmation No other sources of contamination have been identified. Metals are naturally occurring, but detections may be indirectly associated with the altered geochemistry beneath the site. Some of the solvents discussed above have been detected in background wells and surface water samples. 2.4 Source Control Measures Planned source control measures include maintaining and enhancing the final caps, pursuant to reducing the quantity of surface water infiltration into the CDLF units. Said enhancements are part of the planned post -closure care requirements and have been described in earlier permit applications. 2.5 Groundwater End Use Based on the earlier site characterization studies, including a survey of groundwater users, the fate of groundwater at the site is discharge into surface streams and wetlands, where natural processes are available to mitigate the groundwater impact. No downgradient groundwater users have been identified. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 25 2.6 Sensitive Receptor Pathways Potential receptors for the two key COCs at the facility, benzene and vinyl chloride, are flora and fauna, and human. Exposure potential is via direct contact with groundwater or surface water downgradient of the landfill. Considerations for flora and fauna are incorporated into the Stream Classification and 2B Standards that apply. Based on the data, no organic contaminants that can be specifically tied to the landfill have been identified in the surface water sampling (THF is in the background sample). Metals have been generally below the stream standards except within the last couple of years, where background values show an increase. These trends and the risk to human population is discussed in Section 2.7. 2.7 Human Exposure Pathways Two exposure pathways have been identified for contact with the COCs. The first pathway involves contact with surface water that drains through the facility and discharges to the unnamed tributaries. The second pathway exists where direct contact could be made with the groundwater from the facility, including dermal contact, ingestion, or inhaling vapors from VOCs contained in the water. 2.7.1 Surface Water Pathway This pathway includes direct contact by facility employees or visitors with surface water in the unnamed tributaries downgradient of the CDLF units. Another possibility exists for direct contact by the general population in these tributaries (beyond the Facility boundary) or larger receiving streams downgradient of the site. All the surface water bodies are jurisdictional and carries Class C water quality classifications. Detected concentrations of metals and most VOCs are below North Carolina 2B surface water standards, except cadmium, copper, lead, vanadium, zinc exceed the hardness dependent chronic standards, and 1,4-dioxane exceeds the USEPA drinking water advisory value. The surface water detects with highest concentrations are observed at the background location on the "south" stream, SW-1. An evaluation of the sampling and analytical protocols (and/or the sampling location) may be warranted. 2.7.2 Groundwater/Soil Pathway Contact with the groundwater and/or soil can occur via groundwater sampling and/or well installation activities. This work is limited to outside -trained contractors, not Facility employees or visitors. All personnel likely to have contact with impacted groundwater or soil should have training defined in CFR Title 29 Part 1910.120, i.e., HAZWOPER training (a.k.a. 40-hour training). Said training prescribes safety protocols for personal protection on contaminated sites or working with potentially contaminated samples. There is a very slight chance of vapor inhalation when handling the samples. The likelihood of the public contacting with site -influenced groundwater is negligible. No groundwater users (domestic, industrial, or agricultural) have been identified downgradient of the site. Due to the nature of the lands south (downgradient) of the site, i.e., marshy ground beneath the mapped 100-year flood level of Tar River, it is unlikely that future development leading to potential groundwater use will occur. Vapors associated with groundwater are not expected to be problematic offsite. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 26 2.8 Background Concentrations In groundwater and surface water, background values of constituents detected at the site are as follows: Table 7 Metals in Background Samples Constituent Deep GW Shallow GW 2L Std/ Surface 2B Std A ug/I ug/I MCL Water, ug/I ug/I Antimony 0.2J - 9.0 0.03J -16 a 116 0.05 - 0.65 5,300 Arsenic 0.3.1 - 2.6 c 0.02.1 - 1.5 101150 1.2.1 - 30 150 Barium 11.1 -115 25J - 43 70012,000 33J -1725 21,000 Beryllium 0.07J - 0.38 0.03J -1.0 4 0.06J - 0.31 6.5 Cadmium 0.1J-1.0 0.07J-2.3 2/5 0.04J-2.0° 0.15 Chromium 0.13J - 83 0.2.1 -15 10 / 100 0.4.1 - 61 24 Cobalt 0.1J - 0.76 0.13J - 2.5J NE/1 0.3J - 8.9 16 Copper 0.4 -1.6 0.5J - 3.1 1,000 / 1,300 0.4J - 41 2.7 Lead 0.23.1 - 1.0 0.11.1 - 3.7 15 0.28.1 - 46 0.54 Mercury 0.06.1 - 0.12 0.04J13- 0.06 112 --- 0.012 Nickel 0.9J - 5.0 1.3J - 7.9 100 0.7J -13.7 16 Selenium 0.24J - 0.33 0.23J -1.9 20 / 50 0.2J - 5.4 5 Silver 0.06.1 - 0.52 0.1.1 - 0.2.1 20 0.05.1 - 0.2J 0.06 Sulfide 100-422 147 NE --- NE Thallium 0.03J 0.04.1 - 0.14 0.2 0.05J - 0.08 2 Tin 0.52.1 - 0.17 0.11.1 -1.8 NE / 800 --- 800 Vanadium 0.88J-46 0.16J-5.0 NE/0.3 1.1J-84 21 Zinc 3.8J - 51 1.2J - 91 1,000 2.3J - 202 36 A Hardness dependent chronic standards a Bold numbers represent 2L standard exceedance c Values flagged with J by the lab indicate detection above the PQL and below SWS Reporting Limit A recent upward trend in concentrations at SW-1 is shown in the cumulative data (Appendix 2). Published information discussed in the 2017 ACM and newly researched data indicate the following constituents are in the regional background (all values are ug/1): C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 27 Table 8 Metals in Background Geochemistry NURE4 NHIM 5 USGS 6 ppm ug/I (ppb) ppm Arsenic 4.4A 1.1-2.5B 0.7-6.1c Barium 12.5 — 25 ° 17 - 998 Beryllium 0.25 — 0.5 0.1— 4.5 Cadmium 0.1 0.1— 0.2 Chromium 2.5 — 5 2 - 64 Cobalt 5 0.2 — 27.4 Copper 1-4 12 — 36.7 Iron 20,000 0.05 —10.2 Lead 5-10 5-31.6 Manganese 150 — 250 25 - 1600 Nickel 2-5 0.9 — 38.4 Silver 0.05 — 0.25 <1 Vanadium 45 3 - 155 Zinc 5-12.5 2-106 A In soils (Shacklette, ca. 1976), published by USGS, https://pubs.usgs.gov/of/1997/492/guad/q rockmt.htm B In groundwater, based on 31 domestic wells in Pitt County sampled in 2009 by NCDHHS DPH C In 24 shallow soil samples (8 locations), USGS ca. 2010; data points correlated by latitude and longitude, typically representing sites with 15 miles Sediment samples in streams, sampled by NCGS and others ca. 1978 for the National Uranium Resource Evaluation (NURE), Open -file reports 93-1 through Open -file report 93-34, NC Geological Survey, 1993 4 The Geochemical Atlas of North Carolina, NC Geologic Survey, www.geology.enr.state.nc.us/NUREgeochem 5 Alison P. Sanders, et al, Arsenic in North Carolina: Public Health Implications, Environ Int. 2012 Jan; 38(1): 10-16. Published online 2011 Sep 10. doi: 10.1016/j.envint.2011.08.005. National Institutes of Health, NIHMSID: NIHMS320000. PMCID: PMC3539775. https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3539775/. 6 Smith, D.B., et al, 2013, Geochemical and Mineralogical Data for Soils of The Conterminous United States: U.S. Geological Survey Data Series 801, 19 p., https://pubs.usgs.gov/ds/801/. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 28 Table 9 Selected VOCs in Background Samples Constituent Deep GW Shallow GW 2L Std/ Surface 2B Std A ug/I ug/I MCL Water, ug/I ug/I Acetone 2.1.1 - 247 1.7 - 247 6000 4.5J - 12.5.1 2,000 Benzene --- 0.3 - 0.6 115 --- 51 2-Butanone 66J -129J 0.9 - 24.8 4,000 1.2J - 3.2J 26,000 Toluene --- 2.6 600 / 1,000 0.3.1 - 33.1 11 1,4-Dioxane --- 4.39 - 5.33 3 414 85 A Class C Standards, typically; USEPA drinking water advisory for dioxane 2.9 Exceedances of Groundwater Quality Standards In groundwater at the site, values of constituents exceeding 2L Standards are as follows: Table 10 Metals Exceeding 2L Groundwater Standards Constituent 2LStd/ MW2s MW3s MW3A MW4 MW5 MW6 MW7 MW8 MW10 MW11 MW12 MW14 MCL ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I Arsenic 10 / 16 27 21 11 22 15 28 55 54 150 Barium 700 / - - - - 776 819 - - 759 2,000 Chromium 10 / 85 32 15 42 13 22 40 122 21 44 14 100 Lead 15 83 - - 25 - - - - - - 21 Vanadium 0.3 / - 122 0.3 Table 11 VOCs Exceeding 2L Groundwater Standards Constituent A 2L Std/ MW2s MW3s MW3A MW5 MW6 MW7 MW8 MW10 MW11 MW12 MW14 MW15 MCL ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I Benzene 1 / - 3.1 2.7 1.9 2.26 2.56 2.52 1.47 - 5 Vinyl Chloride 0.3 / - 2 1.091 - 0.8J 1.25J 1.48J 2.2 0.69 4.3 2.53J - 2 1,4-Dioxane 3 129 329 257 74.2 40.1 18.2 218 10.7 25.2 32.8 3.71 3.69 A Highest reported value for constituent at selected well (Tables 8 and 9) C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 2.10 Exceedances of Surface Water Quality Standards In surface water, values of constituents exceeding 2L Standards are as follows: Table 12 Constituents Exceeding 2B Surface Water Standards Constituent 2B StclA SW1 SW2 SW3 SW4 ug/I ug/I ug/1 ug/I ug/1 Arsenic 150 - - - - Cadmium 0.15 2.0 2.0 1.0 - Chromium 24 61 - - - Copper 2.7 41 6.1J 8.4.1 4.8J Lead 0.54 46 14 2.5J 1.11 Vanadium 21 84 - - - Zinc 36 202 - 71 - 1,4-Dioxane 85 414 - - - A Class C Standards, typically; USEPA drinking water advisory for dioxane 2.11 Landfill Gas Monitoring Results July 9, 2020 Page 29 Table 13 Landfill Gas Readings LFG Nearest May 2019 Jul 2019 Sep 2019 Dec 2019 Monitoring Monitoring CH4 1-12S CH4 1-12S CH4 1-12S CH4 1-12S Location Well (%vol) (ppm) (%vol) (ppm) (%vol) (ppm) (%vol) (ppm) GP-01A MW9A - - - - - - - - GP-02 MW17 - 1 - 1 - 1 - - GP-03 MW16 - 1 - - - 1 - - G P-04 M W 15 0.1 1 - 1 - - 0.4 1 GP-05 MW14s - 1 - - - - - - SG-06 B M W12 - - - - - - 0.1 - SG-07 MW5 - - - 1 - 2 - - SG-08 MW2s - - - - - - - - GP-09 MW4 - 1 - - - - 0.1 - GP-10 MW1s - 1 - 1 - 1 0.1 - C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 30 GP-11 MW10 - - 0.3 8 1.5 9 0.5 1 SG-12 MW13 - - - - - 1 - - SG-13 MW12s - - - - - - - - SG-14 MW11 - - - - - - - - SG-15 MW8 - - - - - - - - SG-16 MW11 - 1 - - - - - - SG-17 MW3s - - - 1 - 1 - - SG-18 MW3A - - - 1 - 1 - - SG-19 MW2s - - - - - - - - SG-20 MW10 - - - - - 3 - - A Permanent Gas Probe B Soil Gas Probe / Flux Chamber A clear correlation between LFG monitoring sites showing methane and/or hydrogen sulfide and the pattern of contaminants observed at the monitoring wells cannot be drawn. The MINA parameters sampled at the monitoring does include certain dissolved gases, from which future correlations may be recognized. Albeit there may be a coincidence of data at GP-11 and MW-10, the separation is approximately 200 feet but, in fact, SG-20 is closer to MW-10 and shows little detection of methane and/or hydrogen sulfide. With respect to GP-04, located midway between MW-14s and MW-15, the groundwater constituents do not appear to be related. Recalling the regulatory ACTION LEVELS, Methane: > 1. 25% by volume (inside structures) and > 5% by volume (at facility boundary) Hydrogen Sulfide: > 1 % by volume (inside structures) and > 4% by volume (at facility boundary) It does not appear that Landfill Gas is an issue of concern at this Facility. 2.12 Media of Concern Based on current data, the media of concern at the Facility is groundwater and/or soil. No air quality issues are apparent (no landfill gas), and no surface water standards have been exceeded except for constituents that are present in the background. Should future additional information cause these conclusions to change, contingency activities will be considered for implementation (Chapter 6). C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Chapter 3 Selected Remedy Technical Approach 3.1 Design and Specifications of Remedy The following sections summarize the logistics of the two -pronged corrective action remedy: • Monitored Natural Attenuation (MNA), and • Landfill Capping. July 9, 2020 Page 31 These sections will describe how the remedy will meet the requirements of 15A NCAC 13B .0545(e)(2): (A) be protective of human health and the environment. (B) attain the approved ground -water protection standards. (C) control the source(s) of releases to reduce or eliminate, to the maximum extent practicable, further releases of constituents into the environment that may pose a threat to human health or the environment; and (D) comply with standards for management of wastes. 3.2 Monitored Natural Attenuation The following excerpt from the North Carolina Solid Waste Section MNA Guidance Document defines the purpose of this Corrective Action Plan: "Monitored natural attenuation (MNA) is the sum of natural processes that leads to the decreasing of contaminant concentrations in groundwater over time. The primary objective of MNA is to demonstrate that natural processes will reduce contaminant concentrations in groundwater to levels below regulatory standards before a point of compliance is reached." To that end, the following plan description is based on the findings and conclusions of data summary described in Chapters 1 and 2. An initial period of monitoring (four semiannual sampling events) of an approved monitoring well network has indicated the effectiveness of MNA as a remedial option. Sampling of the existing monitoring well network for MNA performance parameters indicates a favorable geochemistry for degrading the COCs. In addition, concentrations of COCs at key locations, MW-3s and MW-3A, appear to be leveling or possibly beginning to decline. Earlier detected chlorinated solvents appear to be declining and the pattern of observed impacts within the monitoring network appears to be stable. Paraphrasing the Guidance Document: after the baseline sampling events, an EPA approved MNA screening model shall be applied to facilitate a determination of which reactions and processes are driving the subsurface biogeochemistry. This includes a mass balance assessment to verify balance between source loading and plume attenuation capacity. Plume stability (chemical, biological, and physical) must be determined in evaluating trends along specific flow lines within the contaminant plume and along the contaminant plume boundary. The interpretation of the MNA performance parameters and the technical evaluation of MNA as a remedy shall be presented in a comprehensive MNA Corrective Action Evaluation Report at least once every five calendar years. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 32 In accordance with the November 8, 2019 approval letter concerning the MNA Sampling Frequency Modification Request (FID 1376883), the following MNA parameters have been approved to be monitored every three years during both semiannual events that year: carbon dioxide, total organic carbon, BOD, COD, ethene, ethane, volatile fatty acids, methane, hydrogen, ferrous iron, and chloride. In addition, the following MINA parameters are requested to be monitored semiannually: sulfate, sulfide, DO, ORP, nitrate, pH, conductivity, temperature, and alkalinity. This requirement is in addition to standard semi-annual sampling requirements. Adherence to the prescribed monitoring plan, including the building and maintaining the MNA screening model (to commence with the third -year sampling events), will facilitate an effective evaluation of the MNA geochemistry performance and predicting when the compliance will be achieved, in addition to verifying the COCs are decreasing as expected. In this manner, the monitoring program meets Parts A and B of the of the 15A NCAC 13B .0545(e)(2) requirements, i.e., be protective of human health and the environment, and attain the approved ground -water protection standards. 3.3 Phase 1 CDLF Unit Closure Closure documentation for two existing phases of C&D Landfill, Inc. are beyond the scope of this CAP. A brief description of existing conditions and proposed future action is described below. These issues will require input from the SWS Permitting Branch; as such, this portion of the CAP remains flexible and may not be included in the initial review/approval of this document. Regulatory changes enacted during Phase 1 operation flagged June 30, 2008 as the cutoff date for compliance with 15A NCAC 13B .0543 requirements for final covers. C&D Landfill, Inc. was following a prescriptive incremental closure protocol for Phase 1 operations, by which portions of the side slopes were closed (but not certified) prior to the cutoff. A test pit investigation of the Phase 1 final cover soils in April 2020 documented field density testing and soil classification (Appendix 3). The study determined the final cover thickness is at least 36 inches at investigated locations on the side slopes. Soil density acquired via nuclear moisture -density gauge indicated compaction in the lower 18 inches of the side slope cover varies from 66 to 92 percent of the standard Proctor maximum dry density (MDD). Visual soil classifications for the lower 18 inches of side slope cover are typically SM, ML, and some CL. Less than 36 inches of final cover was observed for the upper cap area, estimated at ±2 acres with approximately 2-5 percent slopes. The study concluded that the well vegetated side slopes should meet or exceed the original "pre-2008" final cover requirements of the time those areas operated. The upper cap area for Phase 1 does not meet either the "new" or "old" requirements, thus an upgrade of portions of the cover is warranted to certify the unit closed. In order to meet the CAP requirements, I am proposing a "post-2008" cover construction on the upper cap area of Phase 1 and leaving the side slopes as built with enhanced vegetation on the side slopes of Phase 1. Technical specifications for the proposed cover (Appendix 4) is subject to review and approval by the SWS. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 33 Chapter 4 Groundwater and Surface Water Monitoring 4.1 Revised Water Quality Monitoring Plan Earlier versions of the WQMP, prepared in accordance with 15A NCAC 13B .0544, defines the monitoring network, sampling parameters and protocols, and schedule for differing requirements for Spring and Fall sampling events. The WQMP includes semi-annual sampling and analysis for compliance with North Carolina ground water standards, i.e., 15A NCAC 2L .0300 (the "2L rules"). The sampling list has evolved over time to include RCRA metals and organic constituents on the Appendix 1 list, i.e., volatiles and semi-volatiles that are analyzed by US -EPA Method 8260 protocols; metals and organic constituents on the Appendix II list, i.e., US -EPA Method 8270 protocols, pesticides (8081 scan), herbicides (8151 scan); inorganic compounds and field parameters, e.g., chloride, sulfide, temperature, oxidation-reduction potential, total dissolved solids, and turbidity; emerging contaminants tetrahydrofuran and 1,4-dioxane; and during the last two years MNA performance parameters. As the Facility moves into Corrective Measures, the monitoring program will again be modified to incorporate the requirements of the MNA Guidance Document 7 and the November 8, 2019 letter approving the MNA Sampling Frequency Modification Request (FID 1376883). MNA parameters to be monitored every three years during both semiannual events that year: carbon dioxide, total organic carbon, BOD, COD, ethene, ethane, volatile fatty acids, methane, hydrogen, ferrous iron, and chloride. In addition, MNA parameters to be monitored semiannually: sulfate, sulfide, DO, ORP, nitrate, pH, conductivity, temperature, alkalinity, and groundwater elevations. A standalone Water Quality Monitoring Plan inclusive of the Corrective Action protocols is presented in Appendix 5. 4.2 Revised Landfill Gas Monitoring Plan Monitoring of landfill gas (LFG) has been performed in accordance with Solid Waste Rule 15A NCAC 13B .0544. Results of LFG monitoring to date have shown no obvious correlation between the gas and the groundwater, that is, the LFG does not appear to be a significant driver of the groundwater constituents. A standalone LFG monitoring plan prepared in accordance with the regulations is found in Appendix 6. 4.3 Special Monitoring Provisions • Field personnel shall be trained and certified (experienced) for specific sampling requirements. • Laboratory shall be required to maintain North Carolina Wastewater certification. • Background monitoring locations should be evaluated to verify that these locations are not being influenced by the groundwater impact. Locations may be adjusted with SWS approval. • Data evaluation and reporting will be performed by a qualified and duly licensed geologist or professional engineer. Reports shall be prepared in accordance with SWS requirements. • Well -heads shall be protected, and maintenance shall be performed as needed. Vegetation shall be mowed prior to each sampling event — no chemical weed control products shall be used. 7 NC Solid Waste Section, MNA Excerpt from Examples of Approved Groundwater Corrective Measures for Solid Waste Management Facilities, Rev 6-08. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 34 Chapter 5 Evaluation of Effectiveness and Report Submittals The following narrative outlines and demonstrates an understanding of the contents and format of future Corrective Action Evaluation Reports (CAERs), specifically the evaluation of performance parameters that indicate the success of the CA program. In accordance with the regulations and guidance, CAERs will be generated every 5 years. Data review will be performed after every sampling event, especially the evaluation of the MNA parameters every three years. The data will be evaluated using an EPA approved MNA screening model, including the ability to measure mass flux. The MNA performance parameters may be re-evaluated to determine if the sampling frequency may decrease for a specific MNA performance parameter or if a specific MNA performance parameter may be removed from the corrective action sampling program based upon its technical relevance (example anaerobic conditions instead of aerobic conditions). It is necessary to determine after the baseline sampling events, which reactions and processes are driving the subsurface biogeochemistry. A mass balance assessment must also be completed. There must be balance between source loading and plume attenuation capacity. Any changes to the MNA performance parameter list must be approved by the SWS. Several USEPA references have been researched that will provide specific data evaluation protocols to assist with the MNA performance evaluations. Refer to the Bibliography section following the text. 5.1 Corrective Action Performance Objectives MNA is not be considered a sole presumptive remedy, rather MNA is part of a Corrective Action process, defined in the document, with measurable performance objectives but also the flexibility to accommodate various natural and anthropomorphic factors. The goal is ultimate restoration of groundwater at the Facility to its designated beneficial use, considering cost, regional groundwater use, technical practicability, remedial objectives, and protection of human health and the environment. The objectives that will be evaluated on an initial reporting period and on a 5-year schedule the following: 1. The COC concentrations will stabilize (not increase) at the south facility boundary, based on a trend analysis acceptable to the Solid Waste Section. 2. No new constituents will be recognized as a COC at the south facility boundary, based on a trend analysis acceptable to the Solid Waste Section. 3. A reduction in concentrations of COCs due to MNA processes will be demonstrated with SWS- approved screening tools. 4. No degradation of surface water due to discharges of groundwater can be observed. 5.2 Physical Changes in Aquifer Conditions Changes in water levels and flow directions (e.g., gradient reversals) that could indicate differing conditions within the aquifer will be accomplished by mapping the groundwater elevation contours after every sampling event. Horizontal gradients drive groundwater velocities, and vertical gradients reflect groundwater pressures and can indicate the likelihood of cross -contamination between aquifers, thus tracking the gradients is important. Both gradient types indicate flow directions, an obvious concern for contaminant transport, but the position of the water table within the soil column affects which of the many MNA mechanisms, anaerobic vs. aerobic, oxidizing vs. reducing, are operative. The groundwater elevation data will be used to construct potentiometric maps and flow nets, to be updated periodically. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 35 5.3 Chemical Changes in Aquifer Conditions Changes in geochemistry may influence the effectiveness of the remedy and can be indexed with measurements of pH, Eh, temperature, turbidity, and TDS in the normal monitoring protocol. MNA parameters such as dissolved oxygen, BOD/COD and the presence of certain dissolved gases are paramount to evaluating whether conditions are favorable for microbial activity, upon which the MNA processes depend. These parameters are inputs to periodic evaluations via modeling, e.g., BIOPLUME, BIOCHLOR, BIOSCREEN. These predictive models and their derivatives are popular means of evaluating solute transport using convection, dispersion, mixing, and biodegradation effects. These models may be applied as part of evaluating fate and transport of contaminants in the subsurface, and they can be used to predict the effect of injecting oxygen or other MNA enhancements. $ 5.4 Physical Changes in Plume Characteristics Measuring the concentrations and extent of the contaminants is a principle means of being protective of human health and the environment. For the subject Facility, the south property line is the point of compliance, with MW-3A installed nearby as a sentinel to contaminant migration. Several processes cause reductions in contaminant concentrations and apparent reductions in the total mass of contaminant in a system. Processes causing apparent reductions in contaminant mass include dilution, sorption, and hydrodynamic dispersion. To determine the mass of contaminant removed from the system, it is necessary to correct the observed concentrations for the effects of these processes into a comprehensive solute transport model. Iso-concentration maps of contaminants and daughter products allow both quantitative and qualitative interpretation of the distribution and the relative transport and degradation rates. The maps are necessary so that contaminant concentrations can be input to a numerical model. 9 5.5 Chemical Changes in The Plume The measurement of dissolved oxygen, nitrate, manganese, iron, sulfate, and sulfide along the axis of the plume, as well as transverse to it, are used to characterize biological activity with respect to the redox state at those locations. This information will allow an estimation of the current redox state at various parts of the plume, thereby defining the types of reactions that may take place. These data will also help characterize the abundance of the principal electron acceptors, oxygen, nitrate, and sulfate, to allow an estimate of how long natural attenuation will remain a viable remedial alternative. Another approach is using the hydrogen (1-12) concentration to indicate the which terminal electron acceptor (TEA) process in play, e.g., denitrification, ferric iron (iii) reduction, sulfate reduction, methanogenesis (Chapelle et al., 1995). Then, there is biological action that depends on a source of organic nutrients, i.e., dissolved organic carbon, in the optimal conditions of temperature, pH, redox potential (Eh), and alkalinity. The microbial activities of a site are thus determined by the dissolved organic 8 United States Environmental Protection Agency, Ground Water Modeling Research, September 13, 2016, https://www.epa.gov/land-research/ground-water-modeling-research 9 Wiedemeier, T.H., et al, Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Ground Water, National Risk Management Research Laboratory Office of Research And Development, IAG #RW57936164, EPA/600/R-98/128, September 1998. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 36 carbon, presence of macro- and micronutrients and the TEA (Semprini et al., 1995). The presence and concentration of each will determine not only the activity, but the predominant microbe population.lo 5.6 Refining the Site Conceptual Model The Corrective Action Evaluation Reports (CAERs) will focus on the following: 1. Proving that a reduction in contaminant concentrations is occurring. 2. Demonstrating that contaminant reduction is caused by chemical or biologic attenuation of the COCs. 3. Proving that the plume has stabilized or is decreasing within the horizontal and vertical extent. To that extent, the data are correlated to the modeling and, if needed, the model inputs are adjusted to reflect what the data are showing. The purpose is to improve confidence in of the site model for making long-term performance predictions. US EPA states the following: "The conceptual site model for MNA and the monitoring program are continually refined as new data are gathered and interpreted. Each new round of data should help develop a better understanding of the site and site processes, including plume shape, location, stability, and dynamics; attenuation rates; geochemical regimes; and site hydrogeology. The criteria used for site -related decision -making are usually based on either presence of specific contaminant concentrations (e.g., MCLs at a specified group of wells), or spatial and temporal trends in concentrations (e.g., a decreasing trend in contaminant concentrations that indicates progress toward contaminant reduction objectives). Other site -related data (e.g., geochemical and ground -water flow data) are important for corroborating contaminant migration, fate, and attenuation processes. These data may be used to provide evidence for contaminant degradation and the continuation of appropriate conditions for attenuation at acceptable rates." 11 5.7 CAP Modification This CAP is intentionally flexible to allow amendment as warranted by changing conditions or other factors discussed above. Should the need arise, alternative correction action will be evaluated, including but not limited to enhanced attenuation or active remediation options. The conditions that might trigger such alternatives are discussed in the contingency plan (Chapter 6). No changes to this CAP may be made with express authorization of the Solid Waste Section. 10 Azad pou r-Keeley, A., et al, Microbial Processes Affecting Monitored Natural Attenuation of Contaminants in the Subsurface, Office of Solid Waste and Emergency Response, EPA/540/S-99/001, September 1999. 11 Pope, D.F., et al, Performance Monitoring of MNA Remedies for VOCs in Ground Water, prepared under contract to Dynamac Corporation, Contract Numbers 68-C-99-256 and 68-C-02-092, U.S. EPA National Risk Management Research Laboratory Office of Research and Development, EPA/600/R-04/027, April 2004. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Chapter 6 Contingency Plan 6.1 Factors that Could Affect MNA Performance Data July 9, 2020 Page 37 If the approved corrective action does not appear to be effectively reducing the COC concentrations in either horizontal or vertical dimensions, factors that could affect the data should first be evaluated. Possible influences on the data, which is considered a first step in evaluating trends or sudden changes in the data, though not necessarily triggering a program change, include the following: Changes in land or ground -water use — development near the site could potentially result in hydrologic changes that affect plume stability, e.g., new pumping wells, clearing, ditching or dewatering for surface mining (present on the area), with an increased possibility of exposure via contact with the water; geochemical changes that affect biotransformation processes, e.g., application of nitrogen -containing fertilizers could cause an influx of nitrate to ground water and possibly inhibit reductive dichlorination; these institutional controls may require evaluation or amending the site model. Laboratory error or sample contamination — verification by the analytical laboratory that sampling and analysis protocols did not introduce an error; have the laboratory to analyze another aliquot of the same sample, if available (prearrange for the lab to retain samples until data evaluation has been completed); resample the well and analyze the detected constituent, evaluate consistency. Seasonal variation — the effects of seasonal groundwater flux can affect dilution and can mobilize contaminants previously held in the vadose zone, possibly resulting in data "spikes;" an understanding of these effects will be developed over time through data review; trends will be considered when developing (and, perhaps, reevaluating) the CA goals for the site. Transient changes — a sudden release of new contaminants, e.g., a fuel spill, fire, damage to a final cover, or even a prolonged drought or wet climatic spell, can result in a short-term effect on the data; these conditions may warrant adjusting the site model or perhaps reevaluating the CA goals. Long-term changes —the formation of toxic transformation products or secondary contaminants can alter the geochemistry, e.g., reduction of electron acceptors or donors, influx of substances such as oxygen or nitrate, a change in oxidation-reduction potential, can hinder MNA processes, requiring alternative CA. Other sources of contaminants — the site characterization has identified factors that could influence the data, including past agricultural activities, the nature of the early wastes disposed at the site, the presence of a former railroad corridor through the property, and more than one former fuel stations or automobile service facilities; none are currently suspected as influences on the data. 6.2 Triggering Events and Established Responses Per the requirements of the MNA Guidance Document, if MNA is not performing in accordance with the objectives set forth in the approved CAP (Section 5.1) after the first five consecutive calendar years, the contingency plan must be implemented immediately. If contaminants migrate off site, active remediation shall be initiated, and adjacent property owners notified. Also, if the contingency plan is found not to be effective at the facility, then the public participation process pursuant to 15A NCAC 13B .1635 may be required and a new CAP shall be submitted for approval. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 38 Based on US EPA literature and SWS Guidance, uncertainty associated with estimated rates of attenuation over extended periods of time is a major consideration with MNA. Hydrologic and geochemical conditions amenable to MNA can change due to (1) natural or anthropogenic causes, and (2) changes in the mobility of a plume over time. 12 Situations that may warrant implementation of a contingency and the appropriate responses largely depend on site conditions and include, but not limited to, these hypothetical examples: 1) Contaminant concentrations in soil or ground water at specified locations exhibit an increasing trend not originally predicted during remedy selection. Response: Evaluate travel times to potential receptors and consider the source and duration of the data increase for the COC. A low-level increase near the source area does not necessarily mean that remediation time frames will be expanded or concentration of the COC will exceed limits at the compliance boundary. If contaminants will not reach receptors for several years, it may be possible to allow verification procedures to continue, with time for making informed decisions. If the increased concentration is close to the leading edge of the plume, i.e., there is a shorter travel time, and/or receptors are at risk, Enhanced Attenuation (EA) techniques will be evaluated. If a transient condition is indicated, that is the "spike" is followed by one or more detections in the normal range for that COC and location, no action may be warranted. 2) Near -source wells exhibit large concentration increases indicative of a new or renewed release. Response: A new COC or sudden and large increase in an existing COC near the landfill boundary, i.e., the source, increased sampling frequency and locations may be warranted to define the changes in the plume. The expanded data would be incorporated into the site model to determine the influence on meeting the CA objectives. Further remedial action might include implementing EA techniques or some type of active remediation. 3) Contaminants are identified in monitoring wells located outside the original plume boundary or other specified compliance boundary. Response: This condition could indicate the plume is expanding. The response might include increased sampling frequency and locations to define the changes; the data will be evaluated to determine the long-term influence on meeting the CA objectives. Additional action may or may not be warranted, depending on the potential influence on the timeframe or target concentration at the compliance boundary. Consideration would be given to implementing EA techniques. 4) Contaminant concentrations are not decreasing at the rate previously determined to be necessary to meet the remediation objectives. Response: A comparison of data trends with earlier predictions will be used to evaluate new trend projections. The CA objectives may be reevaluated, or alternative CA technologies may be implemented. A staged approach may be appropriate, depending on the data, such as first 12 Use of Monitored Natural Attenuation at Superfund, RCRA Corrective Action, and Underground Storage Tank Sites, U.S. EPA, Office of Solid Waste and Emergency Response (OSWER), Directive 9200.4-17P, April 1999. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 39 implementing EA via injection of oxygenators, nutrients, emulsified oil, or biological agents (bacteria), then moving to more aggressive treatment methods such as air sparging or pumping. 5) Changes in land and/or ground -water use will adversely affect the protectiveness of the MNA remedy, and Response: This involves the institutional controls; for land controlled by the Facility owner, the ramifications of altering the land use should be clearly understood. For land outside of the control of the owner, however unlikely the prospects, negotiations may be warranted to minimize changes near the Facility. Most of the usable, non -controlled downgradient land is across major streams. Land -use changes that cannot be helped will warrant adjusting the site model and, perhaps, defining the CA objectives, or moving to more aggressive technologies. 6) Contaminants are identified in locations posing unacceptable risk to human or ecological receptors. Response: This condition would likely warrant a move to active remediation; a first step is to determine if conditions are Immediately Dangerous to Health or Life (IDHL). An Emergency Response would be coordinated with local authorities (fire, rescue) and the SWS. Other mitigating activities might be appropriate, e.g., providing drinking water to at -risk populations. Close monitoring of the data, i.e., semi-annual update of the COC concentrations, would provide a basis for quickly deciding a remedy. Modeling would facilitate prediction of the nature, extent, and timeframe that unacceptable risks would likely prevail; EA method, now considered "active" remediation, or one of the more aggressive methods would be selected. It might be prudent to develop this and any other contingency activities into a more implementable course of action, once the CA has been in operation for sufficient time to more completely understand the performance of the selected MINA remedy (and the final closure of the CDLF units). Once the mass balance relationships of the COCs are known, at a future time, specific injectable EA treatments can be developed. Any such plan modifications will require SWS approval. Based on the known conditions at the Facility, it is highly unlikely that conditions requiring more aggressive Active Remediation will be encountered. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Chapter 7 Schedule and Maintenance 7.1 Timeline and Schedule Initial Target Date 1 Groundwater Monitoring 1a Finalize WQMP Within 90 days of CAP Submittal to SWS 1b Well Head Inspection A Week of Nov 16, 2020 1c Mowing Access Paths Week of Nov 23, 2020 1d Semi -Annual Sampling Events Week of Dec 1, 2020 Week of Jun 1, 2021 Week of Dec 1, 2021 1e Sampling MNA Parameters Week of Jun 1, 2023 Week of Dec 1, 2023 1f Data Review and Reporting 120 days after sampling 1g CA Performance Review 120 days after Dec 1, 2025 A Repairs as needed (Section 7.2) 2 LFG Monitoring 2a Screening Events 2b Data Review and Reporting 2c Plan Revision 3 Alternate Final Cover 3a Design/Plan Approval 3b Installation/Upgrade 3c Inspection 3d Maintenance 3e Mowing Cover 3f Data Review and Reporting 3g Plan Revision A Repairs as needed (Section 7.2) Week of June 1, 2020 30 days after sampling TBD Within 90 days of CAP Submittal to SWS 180 days after approval Covered in separate plan Covered in separate plan Covered in separate plan 30 days after sampling TBD July 9, 2020 Page 40 Ongoing Target Dates Two weeks before every event One week before every event Every 180 days for next 5 years Etc. Every 3 years thereafter Every 3 years thereafter Every 90 days thereafter Every 90 days for next 5 years Every 180 days or as required A Yearly Yearly C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 41 7.2 Operation, Monitoring & Maintenance Requirements — For the selected remedy, the OM&M activities do not exceed the normal activities associated with disposal operations and facility maintenance, which are addressed fully in other documents. With respect to CA performance, the issues of final cover maintenance are essential, including vegetation health, periodic mowing, erosion and sedimentation control, and facility monitoring. Typical issues — The MNA monitoring appurtenances prescribed for this facility typically require no maintenance aside from routine well -head issues, e.g., access, ID tags, hinges, locks, incidental damage. These subjects will be addressed more thoroughly in the WQMP separate submission. 7.3 Performing Operations Requirements — The selected Corrective Action essentially has no "operations" except for the monitoring and reporting activities and the final cover construction and maintenance (addressed elsewhere). The CA should not affect routine landfill disposal activities; likewise, the operation of the landfill should be performed carefully, such that no influence or damage to the MNA program. Responsible parties — The Owner is ultimately responsible for facility maintenance and compliance. Facility staff may assume the duties of well -head maintenance and LFG monitoring. In the future, the Owner may wish to engage the services of a caretaker (individual or firm) for post -closure facility maintenance. A third -party laboratory will be contracted for groundwater sampling and analysis. A workable relationship is already in place. 7.4 Long term mechanical maintenance Specific maintenance requirements include the well -heads, discussed above. This aspect could change depending on the CA performance and the potential implementation of more aggressive technologies. 7.5 Monitoring of the site equipment associated with the remedial measure At present, the equipment required for the selected CA program includes LFG meters and other water quality meters measuring devices utilized by the sampling crew. Said equipment will be maintained and calibrated by the equipment supplier (for rentals) or the lab (for use in the service provided). 7.6 Corrective Action Oversight A "program manager" (individual or firm) may be designated by the Owner to oversee the CA monitoring requirements and compliance. Tasks would involve coordinating the schedules, performing a review of the sampling activities, curating/reporting the data, and interacting with SWS officials. Said entity would need to be a licensed geologist and/or a professional engineer to address some of the technical issues. 7.7 Responsible Parties This section will be left incomplete for the initial submittal of this CAP. The Owner/Operator of the Facility is known (C&D Landfill, Inc., Judson T. Whitehurst, President). Name(s) and contact numbers for those critical site personnel on whom responsibility for overseeing the OM&M operations will fall, including the laboratory, caretaker, and program manager (as appropriate) will be designated during the SWS review of this document, and those parties will be listed within a future revision of this document. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 42 7.8 Notifications In the event of the discovery of any deficiency or failure of the selected CA operating system, the Owner/Operator will notify the Solid Waste Section within 24 hours of the discovery and provide a written report documenting the cause of the deficiency or breakdown within 15-days of completing repairs. 7.9 Safeguard Measures and Site Security In its present form, and if no site changes or damage occurs, the selected CA program will operate with little attention except for monitoring and maintenance activities. Said changes to the site include those related to land use, e.g., vegetation, drainage, the installation of wells or the application of agricultural chemicals near the Facility. The site comprises several hundred acres, but it is isolated there are pathways for casual access by curiosity seekers or those with malicious intent. The Owner will be encouraged to develop strategies to limit public access, which dovetails with routing Operations requirements for the CDLF. Use recreational motor vehicles and hunting activities within the CDLF facility should be prevented. 7.10 Plan Modifications Any requests for modifications of the approved corrective action and the implementation schedule must be submitted in writing to the Solid Waste Section and may not modify the schedule until approved in writing by the Division of Waste Management. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Chapter 8 Financial Assurance July 9, 2020 Page 43 Minimum requirements for financial assurance relative to the selected CA will include lust the costs of groundwater monitoring (third -party sampling and analysis) and professional oversight costs. It should be realized that the costs of groundwater monitoring are already included in the Closure and Post Closure bond calculation for the two separate phases, along with LFG monitoring and final cover maintenance for the 30-year post closure care period and $1,000,000 of PACA. The Closure and Post Closure bond now in place is $3,544,876, based on documentation furnished with the approved December 6, 2019 Corrective Action Permit Modification application (Wood). That amount is subject to annual multipliers since 2014. 8.1 Basis of Calculation Environment 1, Inc. provided tentative estimated costs per sampling event for the current number of wells (22) and surface waters (4) : Appendix I +Appendix II Detects + landfill specific parameters (June 2020 event) A = $12,810 Appendix I +full Appendix II + landfill specific parameters (December 2020 event) = $17,400 Appendix I +Appendix II Detects + landfill specific parameters + MNA parameters B = $22,233 A Surface waters only receive Appendix I parameters each sampling event. B MNA Parameters : Hydrogen* Methane* Ethane* Ethene* Low Level Volatile Fatty Acids* *(sub -contracted to Pace Laboratories in Baton Rouge, LA) BOD Hardness COD Ferrous Iron TOC Carbon Dioxide 8.2 CA Monitoring for 5-year period For the Corrective Action requirement, the calculation for yearly sampling and analysis costs, over a Sampling/Analysis Oversight/Reporting Event Cost Year 0 2020 A Fall $17,400 $3,500 $20,900 Year 1 2021 Spring $12,810 $2,500 $15,310 Fall $17,400 $3,500 $20,900 Year 2 2022 Spring $12,810 $2,500 $15,310 Fall $17,400 $3,500 $20,900 Year 3 2023 Spring $22,233 $7,500 $29,833 Fall $22,233 $7,500 $29,833 Year 4 2024 Spring $12,810 $2,500 $15,310 Fall $17,400 $3,500 $20,900 Year 5 2025 Spring $12,810 $2,500 $15,310 Fall $17,400 $6,000 $23,400 Total Monitoring Costs for 5-Year Period $227,906 A Included with the 5-year calculation C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 44 Chapter 9 Completion of Groundwater Corrective Action The SWS considers attaining the goal of compliance with 2L Standards for all COCs, and maintaining that status for 5 years, as the endpoint of the Corrective Action. A timeframe has not been specified, other than demonstration of improvement at the end of the initial 5-year monitoring period and, ostensibly, for each successive 5-year reporting cycle. After termination of the Corrective Action, which is expected to occur before the end of the post -closure care period, the Facility would revert to a negotiated sentinel monitoring program with fewer parameters or an alternate monitoring schedule for the remainder of the minimum 30 years. Chapter 10 Bibliography Use of Monitored Natural Attenuation at Superfund, RCRA Corrective Action, and Underground Storage Tank Sites, U.S. EPA, Office of Solid Waste and Emergency Response (OSWER), Directive 9200.4-17P, April 1999. Pope, D.F., et al, Performance Monitoring of MNA Remedies for VOCs in Ground Water, prepared under contract to Dynamac Corporation, Contract Numbers 68-C-99-256 and 68-C-02-092, U.S. EPA National Risk Management Research Laboratory Office of Research and Development, EPA/600/R-04/027, April 2004. Azad pou r-Keeley, A., et al, Microbial Processes Affecting Monitored Natural Attenuation of Contaminants in the Subsurface, Office of Solid Waste and Emergency Response, EPA/540/S-99/001, September 1999. Wiedemeier, T.H., et al, Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Ground Water, National Risk Management Research Laboratory Office of Research and Development, IAG #RW57936164, EPA/600/R-98/128, September 1998. United States Environmental Protection Agency, Office of Solid Waste, Waste Management Area and Supplemental Well Guidance, FINAL, June 1993. Ford, R.G. (Ed.) et al, Monitored Natural Attenuation of Inorganic Contaminants in Ground Water, Volumes 1 and 2, U.S. Environmental Protection Agency, Office of Research and Development, National Risk Management Research Laboratory, EPA/600/R-07/139, October 2007. Borden, R.C., et al, Anaerobic Biodegradation of BTEX in Aquifer Material, Environmental Research Brief, U.S. Environmental Protection Agency, Office of Research and Development, National Risk Management Research Laboratory, EPA/600/S-97/003, August 1997. Groundwater Technologies, U.S. Environmental Protection Agency, Office of Land and Emergency Management (OLEM), Office of Superfund Remediation and Technology Innovation (OSRTI), Last update Sep 2019, https://www.epa.gov/superfund/groundwater-technologies#main-content. Guidance for Cleaning Up Groundwater, Soil and Air at Corrective Action Facilities, U.S. Environmental Protection Agency, Office of Land and Emergency Management (OLEM), Office of Resource Conservation and Recovery (ORCR), Last update Feb 2020, https://www.epa.gov/hw/guidance-cleaning-groundwater-soil-and-air-corrective-action- facilities#main-content. Monitored Natural Attenuation, U.S. Environmental Protection Agency, Office of Research and Development, National Risk Management Research Laboratory, Ground Water and Ecosystems Restoration, Ground Water and Ecosystems Restoration Research (Archived), Last Updated Aug 2015, https://archive.epa.gov/ada/web/html/mna.html. Ground Water Modeling Research, U.S. Environmental Protection Agency, Office of Research and Development, National Risk Management Research Laboratory, September 13, 2016, https://www.ei)a.gov/land-research/ground- water-modeling-research. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 45 MNA Excerpt from Examples of Approved Groundwater Corrective Measures for Solid Waste Management Facilities, NCDEQ Division of Waste Management, Solid Waste Section, Rev 6-08. Solid Waste Section Guidelines for Groundwater, Soil, and Surface Water Sampling, NCDENR Division of Waste Management, Solid Waste Section, Rev 4-08. Smith, D.B., et al, 2013, Geochemical and Mineralogical Data for Soils of The Conterminous United States: U.S. Geological Survey Data Series 801, 19 p., https://pubs.usgs.gov/ds/801/. The Geochemical Atlas of North Carolina, NC Geologic Survey, www.geology. enr.state.nc.us/NUREgeochem Alison P. Sanders, et al, Arsenic in North Carolina: Public Health Implications, Environ Int. 2012 Jan; 38(1): 10-16. Published online 2011 Sep 10. doi: 10.1016/j.envint.2011.08.005. National Institutes of Health, NIHMSID: NIHMS320000. PMCID: PMC3539775. https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3539775/. Steffan, R., Biodegradation of 1,4-Dioxane, Strategic Environmental Research and Development Program (SERDP), Environmental Security Technology Certification Program (ESTCP), ER-1422, https://www.serdp-estcp.org/. Hydrogeologic Framework of the North Carolina Coastal Plain Aquifer System, U.S. Geological Survey Open File Report 87-690, USGS. North Carolina Geological Map, Scale 1:62,500, NC Geological Survey, 1985. Corrective Action Plan for Greenway Waste Solutions at North Meck, LLC, prepared by Civil & Environmental Consultants, Inc., Charlotte, NC, Rev. Oct 2019, Permit 6012-CDLF-1993, FID1358899. 15A NCAC 13B .0547 EXISTING C&DLF UNITS AS OF JANUARY 1. 2007. _ MW-14D MW-13x MW-14S Phase 2 MW-12S; •� mw-u r d'r" *., 1 MW-2S - MW-6 -. Legend SW ®Surface Water Sampling Location • Shallow Monitoring Well Deep Monitoring Well y 0 200 400 Approximate Stream Location I Feet Site Boundary Source. Esri, Digi 'I'�I � oEye, Earthstar Geographics, CNES/Airbus D AeroGRID, IGN, nd the GISa��ser Community SITE: Figure TITLE: FI C&D Landfill 9 802 RECYCLING LANE GREENVILLE, NC 27834 MONITORING WELL AND SURFACE WATER SAMPLING LOCATION MAP CLIENT: ^ W 0 do C&D LANDFILL INC. SCALE: 1 " = 200 ' DATE: 05/01 /2019 PROJECT: 6480199035 Wood Environment & Infrastructure Solutions, Inc. 4021 Stirrup Creek Drive, Suite 100 DRAWN BY: D. Hriciga CHECKED BY: D. Hriciga Durham, NC 27703 (919) 381-9900 LOCATION: 56548 emmerr R\Figures C DENR DSCA\DSCA Projects\DC640004 - CleanCleanDrycleaners\ 565480142_PAR\Figures C&D Landfill 802 RECYCLING LANE GREENVILLE, NC 27834 CLIENT: wood* C&D LANDFILL INC. Wood Environment & Infrastructure Solutions, Inc. 4021 Stirrup Creek Drive, Suite 100 Durham, NC 27703 (919) 381-9900 TITLE: Figure GROUNDWATER ELEVATION MAP - DECEMBER 2018 3 SCALE: 1 " = 2001 DATE: 04/30/2019 1 PROJECT: 6480199035 DRAWN BY: D. Hriciga I CHECKED BY: D. Hriciga LOCATION: P:\Government\State\NC\NC DENR DSCA\DSCA Projects\DC640004 - CleanCleanDrycleaners\ 565480142PAR\Figures Notes: Metals concentrations in excess of standards are not illustrated. Units are micrograms per liter (mg/L). BRL = Contaminant concentrations were below reporting limits. NE = No exceedances of applicable groundwater or surface water standards were reported.. e - NS = Not Sampled J = Estimated value below the laboratory reporting limit IM MW-17 ; r r. ...... .� � ,�. BRL _ :� ''•� z YMW-15 BRL f 5 4' q MW-14S BRL •i - �.�� + MW-14D �f BRL MW-13,' +NJ / "' BRL # 4 Phase 2 AN. MW-12S jr Benzene 1.48 Vinyl Chloride 2.21 MW-11 1,4-Dioxane 8.82 1,4-Dioxane 8.15 .1 -F .�M BRL — " MW-3S Benzene 1.3 MW-3D Vinyl Chloride 1.82 - 1,4-Dioxane 184 Dibenzofuran 9.19 J Beta-BHC 0.04 J MW-3A Benzene 1.69 r� Vinyl Chloride 1.09 1,4-Dioxane 87 _ Ort MW-10 Benzene 1.57 Vinyl Chloride 2.2 1,4-Dioxane 5.4 i t W=1 D'VolA' M MW-1 1,4-DioxanSe 5.33 MW-8 Vinyl Chloride 1.48 1 4-Dioxane 49.3 7-1 - • � ' k F' 4 F i r rww Na k- Phase 1 MW-4 BRL MW-5 1,4-Dioxane 16.4 I< Vinyl Chloride 0.18 J 1,4-Dioxane 13.5 N MW-7 SW-1 Vinyl Chloride 1.25 NE 1,4-Dioxane 18.2 -r1 2S or !T• -rt ,k M1 .7 w 1,4-Dioxane 6.2MW- s Raw Legend i4;'j�"► l`NIr. # s�. ® Surface Water Sampling Location 40,' ; , • Shallow Monitoring Well 3 IN L y SW-2 Deep Monitoring Well BRL 0 200 400 - Approximate Stream Location ��t'%._ Feet Site Boundary"` ,It' �-'r, +► Source Esri, DI,gi 1111 • L � ,Earth tar Geographic§, CNES/Airbus DS, SDA, G AeroGRID, IGN, d the G1= r ' mmu it SITE: Figure TITLE: FI C&D Landfill 9 802 RECYCLING LANE GREENVILLE, NC 27834 GROUNDWATER AND SURFACE WATER STANDARD EXCEEDANCE MAP - DECEMBER 2018 CLIENT: w wood* C&D LANDFILL INC. SCALE: 1 " = 200 ' DATE: 04/24/2019 PROJECT: 6480199035 Wood Environment & Infrastructure Solutions, Inc. 4021 Stirrup Creek Drive, Suite 100 DRAWN BY: D. Hriciga CHECKED BY: D. Hriciga Durham, NC 27703 (919) 381-9900 LOCATION: 56548 142P t RTig\NC\NC DENR DSCA\DSCA Projects\DC640004 - CleanCleanDrycleaners\ 565480142_PAR\Figures Water Quality Monitoring Report December 2017 Semiannual Sampling Event Amec Foster Wheeler Project No. 6468-17-7152 Attachment C Mann -Kendall Trend Analyses amec foster wheeler TOOLKIT Trendfor Constituent Analysis Evaluation Date: 8-Mar-18 Job ID: Facility Name: C&D Landfill Constituerrt: Benzene Conducted By: DH Concentration Units: Ng/L SarroingPoint ID:l MW-3S MW-3A MW-8 MW-12S 1 1-Nov-07 1 0.7 2 1-May-08 1.1 0.5 3 1-Nov-08 2.1 0.5 4 1-May-09 1.5 0.3 5 1-Aug-09 1.3 0.07 1.9 0.07 6 1-Jan-10 0.24 0.24 0.24 0.24 7 1-May-10 3.1 0.24 0.24 0.24 8 1-Nov-10 2.1 0.9 0.24 0.24 9 1-May-11 1 0.24 0.4 0.24 10 1-Nov-11 1.1 0.6 0.4 0.3 11 1-May-12 1 0.6 1.1 1.2 12 1-Nov-12 1.2 0.7 1.6 0.7 13 1-May-13 0.24 0.3 0.24 1.1 14 1-May-14 1.1 0.24 1.9 0.4 15 1-Nov-14 2.1 0.5 0.8 1.1 16 1-May-15 1.5 0.24 0.24 0.5 17 1-Nov-15 1.7 1.7 0.24 0.24 18 1-May-16 1.3 0.24 0.9 1.4 19 1-Nov-16 1.2 0.8 1.5 1 1.9 20 1-May-17 2.8 2 1.2 1.7 21 1-Dec-17 1.7 2.7 0.6 2 22 23 24 25 Coefficient of Variation: Mann -Kendall Statistic (S): Confidence Factor. Concentration Trend: . -- 10 �MW35 � 1 c O 1� O L 0.1 d c O U 0.01 10106 02/08 07/09 11/10 04/12 08/13 12114 05116 09/17 02/19 Sampling Date Notes: 1. At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples. 2. Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing; >_ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S50, and COV >_ 1 = No Trend; < 90% and COV < 1 = Stable. 3. Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales, Ground Water, 41(3):355-367, 2003. 4 MDL value used for ND concentrations. DISCL4llvER The GSI Nbnn-Kendall Toolldt is available as is" Considerable care has been exerdsed in preparing this software product,- hoKeve; no party, including without limitation GSI Environmental Inc., makes any representation or wanantyregarding the accuracy, erectness, or completeness of the infom ation contained herein, and no such party shall be liable for any dined, indirect consequential, incidental or other damages resulting from the use of this product or the infomration contained hereinlnfomBtion in this publication is subject to change without notice. GSI Environmental Inc., d/sdaims any responsibility or obligation to update the infornution c dained herein. GSI Bmron edallnc., www.gsi-net.con MANN-KENDALL TOOLKIT for • • Analysis Evaluation Date: 8-Mar-18 Job ID. Facility Name: C&D Landfill Constituent: Vinyl Chloride Conducted By DH Concentration Units: Ng/L San-oing Point ID I MW-10 MW-12S 1 1-Ma -12 0.8 2 1-Nov-12 1.9 3 1-Ma -13 3 4 1-Ma -14 1.1 5 1-Nov-14 3.4 6 1-Ma -15 1.7 7 1-Nov-15 0.63 8 1-Ma -16 1.9 3.7 9 1-Nov-16 1.7 4.3 10 1-Ma -17 1.1 4.3 11 1-Dec-17 0.9 3.7 12 13 14 15 16 17 18 19 20 Coeffiaent of Variation: 0.34 Mann -Kendall Statistic (S): Confidence Factor: c Concentration Trend: Deaxwing Irmwing 10 � M W-12S J C O 1 a=. R L U r_ O U 0.1 11/10 04/12 08113 12/14 05r16 0W17 02/19 Sampling Date Notes: 1. At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples. 2. Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing; >_ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S!50, and COV >_ 1 = No Trend; < 90% and COV < 1 = Stable. 3. Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales, Ground Water, 41(3):355-367, 2003. DISCLAI&ER The GSI A&m-Kendall Toolldt is available 3s is" Caisiderable care has been exercised in preparing this soUav product, hovtever, no party, inducing without limitation GS1 Ermronmental Inc., rrekes any representation or waarrairty regarding the accuracy, correctness, or completeness of the infanretion ocr#alned irereln, and no such party shall be liable for any drect, incired, consequential, incidental or other darreges rescdting from the use of this product or the information contained herein. Infarretion in this publication is sLged to dwW witha rt notice. GS/ Eriororurental Inc., dsdaims any responsibility or obligation to update the intbanation contained herein. GSI EnOrorurental Inc., www.grd-net com Table 4 Summary of Natural Attenuation Parameters - December 2017 Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina Analyte Group Parameter MDL Compliance Limit Phase I Monitoring Wells SWSL 2L Standard MW-IS (Well #1) MW-2S (Well #2) MW-3S (Well #3) MW-3A MW-4 MW-5 MW-6 MW-7 MW-8 MW-16 MW-11) MW-2D MW-31) Carbon Dioxide 1,000 1,000 NE 68,000 241,000 313,000 363,000 60,000 44,000 326,000 106,000 346,000 255,000 27,000 9,000 71000 Dissolved Gasses Hydrogen (nM) 0.2 NE NE 0.0049 J 0.074 J 0.13 0.11 0.22 0.0094 J 0.017 0.011 0.018 1.4 - 1.7 1.5 (µg/L; unless Methane 0.02 NE NE 30 1,500 1,600 1,900 160 4.9 860 160 940 380 1,300 64 27 noted) Ethene 0.007 NE NE 0.0049 J 0.074 J 0.13 0.11 0.22 0.0094 J 0.017 0.011 0.018 0.0082 J 0.52 0.036 0.0083 J Ethane 0.005 NE NE 0.0023 J 0.038 J 0.24 0.17 0.071 J 0.0033 J 0.014 0.0078 J 0.07 0.0045 J 0.33 0.042 0.03 Acetic Acid 100 50 88** 44 J 54 J 310 J - 99 J 42 J 23 J 20 J - 28 J 47 J 46 J 48 J Butyric Acid 14 NE NE - 450 - 1,300 - - 410 17 J 1,400 - - - - Hexanoic Acid 38 NE NE - 41 J - 93 J - - 66 J 73 J 94 J - - - - Lactic Acid 41 NE NE 28 J - - - - 59 J - - - - 70 J 95 J 58 J Fatty Acids (µ Acids Pentanoic Acid 5.5 NE NE - 15 J - 67 J - - - - 35 J - - - - Propionic Acid 6.1 NE NE 6.3 J - - - - - - - - - - - - Pyruvic Acid 16 NE NE - 24 J - 38 J - - - - 51 J - - - - i-Hexanoic Acid 41 NE NE - - - - - - - - - - - - - i-Pentanoic Acid 5.5 NE NE - - - - - - - - - - - - - Chloride 5,000 5,000 250,000 8,000 162,000 242,000 214,000 73,000 66,000 99,000 180,000 202,000 26,000 10,000 13,000 25,000 Sulfate 1,040 250,000 250,000 98,000 J 82,300 J 15,400 J 161,000 J 59,100 J 232,000 J - - 342,000 14,800 - 35,400 J - Nitrate (as N) 3.0 10,000 10,000 80 J 530 J 1,440 J 260 J 90 J 12,440 820 J - 530 J - - - 80 J Iron 13.27 300 300 120 J 14,436 16,923 31,757 2,471 491 15,716 1,371 26,539 18,941 12,620 627 83 J Manganese 1.28 50 50 6.7 J 660 1,155 1,104 65 38 J 592 85 629 99 605 41 J 8.2 J Other Natural Attenuation Alkalinity (CaCO3) 1,000 NE NE 152,000 670,000 1,380,000 1,000,000 90,000 388,000 1,100,000 740,000 1,190,000 212,000 NA 168,000 215,000 Parameters Hardness (mg/L) 252 736 780 744 132 540 704 628 956 112 NA 136 76 (µg/L; unless noted) Total Dissolved Residue (TDR) 1,000 10,000 500,000 322,000 1,200,000 2,090,000 1,010,000 228,000 968,000 1,310,000 1,350,000 1,850,000 473,000 4,610,000 263,000 306,000 Total Organic Carbon (TOC) 120 NE NE 7,140 103,000 169,000 104,000 9,840 25,200 94,900 45,500 99,520 49,900 26,800 1,410 3,550 Biological Oxygen Demand (BOD) 2,000 NE NE - 52,000 8,700 4,600 3,700 7,500 7,500 12,000 6,000 2,000 NA - 2,100 Chemical Oxygen Demand (COD) 840 NE NE 23,000 255,000 425,000 339,000 26,000 63,000 251,000 97,000 370,000 96,000 184,000 , - - pH (S.U.) NA NE 6.5 - 8.5 6.1 6.1 6.5 6.6 6.1 7.1 6.6 6.8 6.7 5.8 7.1 7.1 7.1 Conductivity at 25°C (µ6/ci 1.0 NE NE 481 1,278 3,660 1,931 298 986 1,660 1,546 3,410 407 639 398 453 Field Dissolved Oxygen (µg/L) NE NE NE 3,660 220 370 400 1,240 3,180 560 460 600 600 3,800 1,030 3,660 Parameters ORP (mV) NE NE NE 40 -10 -33 -93 41 57 -56 100 -77 37 178 36 70 Temperature (°C) NE NE NE 15 17 20 17 15 15 18 16 18 18 16 17 18 Turbidity NTU 1.0 NE NE 4.61 80 22 30.8 205 17.2 31.7 18.2 12.8 110 5.01 20 4.52 Page 1 of 3 Table 4 Summary of Natural Attenuation Parameters - December 2017 Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina r Analyte Group Parameter MDL Compliance Limit Phase II Monitoring Wells SWSL 2L Standard MW-9A MW-10 MW-11 MW-12S MW-13 MW-14S MW-15 MW-16 MW-17 MW-14D Carbon Dioxide 1,000 1,000 NE 61,000 336,000 315,000 442,000 149,000 140,000 193,000 255,000 103,000 14,000 Dissolved Gasses Hydrogen (nM) 0.2 NE NE 2.6 1.500 1.6 - 1.7 1.1 1.8 1.4 1.5 4.5 (µg/L; unless Methane 0.02 NE NE 37 3,100 120 3,100 140 320 600 380 180 3.6 noted) Ethene 0.007 NE NE 0.0064 J 0.054 0.089 0.44 0.0046 J 0.079 0.0069 J 0.0082 0.0048 J 0.016 Ethane 0.005 NE NE 0.0074 J 0.042 0.014 0.096 J 0.0024 J 0.013 0.021 0.0045 0.026 0.01 Acetic Acid 100 50 88** 23 J 20 J 40 J - 35 J 57 J 37 J 28 J 24 J 34 J Butyric Acid 14 NE NE - 79 J 42 J 580 - - - - - - Hexanoic Acid 38 NE NE - - - 66 J - - - - - - Lactic Acid 41 NE NE 22 J - 25 J - - - 78 J - 22 J 87 J Fatty Acids (µg/L) Pentanoic Acid 5.5 NE NE - - - 65 J - - - - - - Propionic Acid 6.1 NE NE - - - - - - - - - - Pyruvic Acid 16 NE NE - - - 30 J - - - - - - i-Hexanoic Acid 41 NE NE - - - - - - - - - - i-Pentanoic Acid 5.5 NE NE - - - - - - - - - - Chloride 5,000 5,000 250,000 13,000 97,000 96,000 7,000 58,000 18,000 71000 26,000 14,000 16,000 Sulfate 1,040 250,000 250,000 136,000 J - 268,000 - - 15,200 J 6,900 J 14800 J 218,000 J - Nitrate (as N) 3.0 10,000 10,000 - - - - 1,430 J 270 J - - - 140 J Iron 13.27 300 300 7,393 2,122 9,453 4,384 2,640 12,852 12,329 18,941 4,969 139 J Manganese 1.28 50 50 207 242 388 697 14 J 58 74 99 195 9.4 J Other Natural Attenuation Alkalinity (CaCO3) 1,000 NE NE 210,000 416,000 552,000 816,000 164,000 240,000 65,000 212,000 40,000 230 000 ' Parameters Hardness (mg/L) 328 436 728 664 236 172 92 112 308 156 (µg/L; unless noted) Total Dissolved Residue (TDR) 1,000 10,000 500,000 463,000 763,000 980,000 1,520,000 309,000 654,000 201,000 473,000 549,000 312,000 Total Organic Carbon (TOC) 120 NE NE 7,720 62,300 37,000 10,620 13,490 119,000 27,000 49,900 23,960 2,380 Biological Oxygen Demand (BOD) 2,000 NE NE - 3,500 2,900 28,000 - 15,000 - - - - Chemical Oxygen Demand (COD) 840 NE NE 24,000 143,000 109,000 439,000 32,000 299,000 55,000 96,000 50,000 - pH (S.U.) NA NE 6.5 - 8.5 7.2 6.2 6.7 6.8 6.3 6.0 5.5 5.8 5.5 7.1 Conductivity at 25°C (µ&ci 1.0 NE NE 425 858 962 2,710 449 185 220 407 561 433 Field Dissolved Oxygen (µg/L) NE NE NE 130 370 330 450 190 620 240 600 260 730 Parameters ORP (mV) NE NE NE 85 113 60 11 43 111 79 37 64 123 Temperature (°C) NE NE NE 12 13 11 15 17 13 17 18 18 16 L Turbidity NTU 1.0 NE NE 60 12 110.00 14.00 20.00 300 70.0 110.0 60 2.3 Page 2 of 3 Water Quality Monitoring Report December 2018 Semiannual Sampling Event Wood Project No. 6468-19-9035 Attachment C Mann -Kendall Trend Analyses wood. TOOLKIT for Constituent• Analysis Evaluation Date: 26-Apr-19 Job ID: 6480199035 Facility Name: C&D Landfill Constituent: Benzene Conducted By: DH Concentration Units: N /L Sampling Point ID: MW-31S I MW-3A I MW-8 I MW-12S BENZENE • • 1 1-Nov-15 1.1 1.1 0.24 0.24 2 1-Ma -16 1.3 0.24 0.9 1.4 3 1-Nov-16 1.2 0.8 1.5 1.9 4 1-May-17 2.8 2 1.2 1.7 5 1-Dec-17 1.7 2.7 0.6 2 6 1-Jun-1 8 1.2 0.5 0.3 1.4 7 1-Dec-19 1.3 1.69 0.48 1.48 8 9 10 11 12 13 14 15 16 17 18 19 20 Coefficient of Variation: �fii• Mann -Kendall Statistic (S): Confidence Factor: Concentration Trend: 10 �MW35 �MW3A 0M 1 or L d V C O U 0.1 07115 01116 08116 03117 09117 04118 10118 05119 12119 06120 Sampling Date Notes: 1. At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples. 2. Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing; >_ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S<_0, and COV >_ 1 = No Trend; < 90% and COV < 1 = Stable. 3. Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales, Ground Water, 41(3):355-367, 2003. 4 MDL value used for ND concentrations. DISCLAIMER: The GSI Mann -Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein. GSI Environmental Inc., www.gsi-net.com TOOLKIT for • • Analysis Evaluation Date: 26-Apr-19 Job ID: 6480199035 Facility Name: C&D Landfill Constituent: Vinyl Chloride Conducted By: DH Concentration Units: N IL VINYL CHLORIDE CONCENTRATION (N9Coefficient of / U) Variation: Confidence Concentration I 0.43 I 61.4% �end Stable I I I I Table 4 Summary of Natural Attenuation Parameters Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina December 2018 Analyte Group Parameter Phase I Monitoring Wells GWPS MW-is (Well #1 ) MW-2S (Well #2) MW-3S (Well #3) MW-3A MW-4 MW-5 MW-6 MW-7 MW-8 MW-16 MW-1D MW-2D MW-3D Carbon Dioxide NE 72,000 119,000 346,000 214,000 46,000 164,000 278,000 354,000 348,000 346,000 22,000 8,000 6,000 Dissolved Ethane NE 0.0039 Jn 0.015 n 0.10 n 0.056 n 0.015 n 0.060 n 0.011 n 0.024 n 0.16 n 0.011 n 1.4 n 0.018 n 0.045 n Gasses (pg/L; Ethene NE 0.0050 Jn 0.0075 Jn 0.020 n 0.013 n 0.0089 Jn 0.0030 Un 0.019 n 0.017 n 0.0030 Un 0.0074 Jn 0.0030 Un 0.032 n 0.011 n unless noted) Methane NE 6.5 n 440 n 590 n 440 n 320 n 890 n 620 n 760 n 2,000 n 650 n 5600 n 45 n 54 n Hydrogen(nM) NE 2.1n 2.3n 3.3n 3.3n 2.5n 2.4n 2.8n 2.5n 3.0n 3.3n 4.8n 2.8n 2.1n Acetic Acid 5,000' 110 150 270 200 170 240 230 170 200 44 J 220 130 180 Butyric Acid NE 14 J 4.7 U 79 J 13 J 20 J 8 J 520 920 24 J 12 J 13 J 13 J Hexanoic Acid NE 12 U 17 J 220 160 J 12 U 28 J 100 J 250 180 J 12 U 12 U 12 U 12 U i-Hexanoic Acid NE 4.9U 4.9U 4.9U 4.9U 4.9U 4.9U 4.9U 4.9U 4g1J 4.9U 4.9U 4.9U 4.9U Fatty Acids (pg/L) i-Pentanoic Acid NE 7.5U 7.5U 9.7J 111 7.5U 7.5U 7.5U 7.5U J 7.5U 7.5U 7.5U 7.5U Lactic Acid NE 14 U 14 U 14 U 58 J 14 U 14 U 14 U 14 U 1 27 J 20 J 55 J 27 J Pentanoic Acid NE 12 U 12 U 33 J 30 J 12 U 12 U 12 U 12 U 26 J 12 U 12 U 12 U 12 U Propionic Acid NE 55 J 71 J 110 120 81 J 89 J 93 J 80 J 89 J 4.4 U 60 J 66 J 86 J Pyruvic Acid NE 5.1 - 12 J 72 J 57 J 5.7 U 9.11 16 J 36 J 57 J 6.5 J 5.7 U 5.7 U Chloride 250,000 33,000 54,000 190,000 178,000 5,000 59,000 34,000 88,000 144,000 30,000 13,000 13,000 21,000 Nitrate (as N) NE 9 U 1,200 9 U 9 U 9 U 290 4,540 480 410 9 U 9 U 9 U 50 Total Dissolved Residue (TDR) 500,000 457,000 732,000 2,300,000 1,520,000 162,000 695,000 1,120,000 1,350,000 1,650,000 440,000 232,000 243,000 312,000 Sulfate 250,000 127,000 214,000 256,000 136,000 5,600 138,000 5,600 5,700 234,000 110,000 5,000 U 17,500 5,700 Other Natural Attenuation Biolo Biological Oxygen Demand NE 2,000 U 2,000 U 12,000 4,700 2,000 U 2,000 U 2,700 4,600 4,000 2,000 U 6,600 2,000 U 2,000 U Parameters Chemical Oxygen Demand (COD) NE 27,000 69,000 474,000 333,000 34,000 72,000 111,000 124,000 335,000 113,000 33,000 840 U 840 U (pg/L) Alkalinity (CaCO3) NE 154,000 256,000 1,600,000 1,080,000 88,000 336,000 975,000 396,000 1,070,000 164,000 158,000 168,000 208,000 Iron 300 573 3,908 19,510 32,980 1,098 8,810 10,890 40,540 31,400 25,860 5,405 174 152 Manganese 50 12 284 642 954 36 172 436 578 1,093 117 273 30 0.31 U Total Organic Carbon (TOC) NE 7,710 22,860 164,000 115,000 10,540 22,580 38,480 74,560 90,280 41,000 8,270 1,700 2,350 Ferrous Iron NE 345 3,510 19,170 30,200 764 3,950 11,080 28,600 30,700 23,000 5,100 50 U 50 U Total Hardness NE 339 453 917 620 94 420 938 771 910 180 139 139 126 pH (S.U.) 6.5 - 8.5 6.5 6.6 6.9 6.7 6.9 6.6 6.8 6.7 6.7 6.1 7.0 8.1 8.2 Conductivity at 25°C (pS/cm) NE 773 688 1,390 1,488 233 773 984 1,964 1,249 370 420 414 511 Field Temperature (°C) NE 14 17 19 17 15 14 16 16 16 17 16 17 19 Parameters Turbidity (NTU) NE 6.11 7.25 3.31 4.38 25.8 8.12 1.26 6.23 7.42 7.82 7.58 3.50 1 U ORP (mV) NE 43 79 -51 -68 44 44 80 70 -25 97 78 22 31 Dissolved Oxygen ( /L) NE 630 850 950 5,480 330 810 330 180 800 180 1,220 120 360 Page 1 of 3 Table 4 Summary of Natural Attenuation Parameters Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina December 2018 Analyte Group Parameter Phase II Monitoring Wells GWPS MW-9A MW-10 MW-11 MW-12S MW-13 MW-14S MW-15 MW-16 MW-17 MW-14D Carbon Dioxide NE 42,000 444,000 180,000 318,000 122,000 30,000 35,000 346,000 110,000 13,000 Dissolved Ethane NE 0.012 n 0.060 n 0.012 n 0.026 n 0.0032 Jn 0.0037 Jn 0.014 n 0.011 n 0.013 n 0.015 n Gasses (Ng/L; unless Ethene NE 0.0038 Jn 0.16 n 0.045 n 0.15 n 0.0068 Jn 0.011 n 0.0047 Jn 0.0074 Jn 0.0038 Jn 0.0085 Jn noted) Methane NE 30 n 6,400 n 140 n 920 n 200 n 170 n 460 n 650 n 120 n 8.8 n Hydrogen(nM) NE 2.9n 2.6n 3.2n 3.4n 3.0n 2.9n 3.0n 3.3n 3.1n 3.0n Acetic Acid 5,000' 45 J 24 U 45 J 130 46 J 52 J 37 J 44 J 32 J 42 J Butyric Acid NE 4.7 U 380 4.7 U 660 4.7 U 4.7 U 18 J 24 J 4.7 U 4.7 U Hexanoic Acid NE 12 U 250 24 J 12 U 12 U 12 U 12 U 12 U 12 U 12 U i-Hexanoic Acid NE 4.9 U 4.9 U 4.9 U 4.9 U 4.9 U 4.9 U 4.9 U 4.9 U 4.9 U 4.9 U Fatty Acids (Ng/L) i-Pentanoic Acid NE 7.5 U 7.5 U 7.5 U 7.5 U 7.5 U 7.5 U 7.5 U 7.5 U 7.5 U 7.5 U Lactic Acid NE 32J 95J 191 991 17J 18J 31J 27J 18J 52J Pentanoic Acid NE 12U 12U 12U 60J 12U 12U 12U 12U 12U 12U Propionic Acid NE 5.5 J 111 4.4 U 21 J 5.8 J 4.4 U 4.4 U 4.4 U 4.4 U 4.4 U Pyruvic Acid NE 5.7 U 130 5.7 U 140 5.7 U 5.7 U 5.7 U 6.5 J 5.7 U 5.7 U Chloride 250,000 9,000 52,000 14,000 117,000 5,000 U 5,000 U 10,000 30,000 14,000 14,000 Nitrate (as N) NE 9 U 9 U 9 U 250 50 9 U 9 U 9 U 90 Total Dissolved Residue (TDR) 500,000 373,000 1,670,000 691,000 1,290,000 379,000 196,000 260,000 440,000 654,000 287,000 Sulfate 250,000 63,700 211,000 146,000 6,100 10,100 67,100 103,000 110,000 383,000 6,100 Other Natural Attenuation Biolo Biological Oxygen Demand NE 2,000 U 6,200 2,000 U 6,600 2,000 U 2,000 U 2,000 U 2,000 U 2,000 U 2,000 U Parameters Chemical Oxygen Demand (COD) NE 840 U 259,000 54,000 317,000 45,000 23,000 36,000 113,000 54,000 840 U (pg/L) Alkalinity (CaCO3) NE 244,000 1,320,000 550,000 630,000 292,000 74,000 63,000 164,000 36,000 258,000 Iron 300 557 363 13,560 2,075 917 2,303 2,645 25,860 1,470 12.08 U Manganese 50 74 253 284 460 22 237 83 117 170 6.9 J Total Organic Carbon (TOC) NE 4,700 99,200 20,920 114,000 20,520 8,360 12,800 41,000 21,800 2,310 Ferrous Iron NE 464 302 13,070 1,951 802 1,198 2,200 23,000 1,382 50 U Total Hardness NE 278 1,030 498 451 306 129 153 180 384 149 pH (S.U.) 6.5 - 8.5 6.9 6.5 6.8 6.6 6.0 6.4 6.5 6.1 5.8 7.8 Conductivity at 25°C (pS/cm) NE 529 1,607 857 941 558 246 401 370 775 522 Field Temperature (°C) NE 13 11 11 13 16 13 16 17 17 17 Parameters Turbidity (NTU) NE 8.62 2.29 18.6 2.33 1 U 38.8 6.42 7.82 2.76 1 U ORP (mV) NE 99 108 64 105 72 99 85 97 71 94 Dissolved Oxygen ( /L) NE 340 280 210 330 300 100 U 250 180 320 100 U Page 2 of 3 Water Quality Monitoring Report June 2018 Semiannual Sampling Event Wood Project No. 6468-17-7152 Attachment C Mann -Kendall Trend Analyses wood. TOOLKIT for • • Analysis Evaluation Date: 21-Aug-18 Job ID: 6468177152 Facility Name: C&D Landfill Constituent: Benzene Conducted By: DH Concentration Units: Ng/L Sampling Point ID: MW-3S MW-3A MW-8 MW-12S 1 1-Nov-07 1 0.7 2 1-Ma -08 1.1 0.5 3 1-Nov-08 2.1 0.5 4 1-Ma -09 1.5 0.3 5 1-Au -09 1.3 0.07 1.9 0.07 6 1-Jan-10 0.24 0.24 0.24 0.24 7 1-Ma -10 3.1 0.24 0.24 0.24 8 1-Nov-10 2.1 0.9 0.24 0.24 9 1-May-11 1 0.24 0.4 0.24 10 1-Nov-11 1.1 0.6 0.4 0.3 11 1-Ma -12 1 0.6 1.1 1.2 12 1-Nov-12 1.2 0.7 1.6 0.7 13 1-Ma -13 0.24 0.3 0.24 1.1 14 1-May-14 1.1 0.24 1.9 0.4 15 1-Nov-14 2.1 0.5 0.8 1.1 16 1-Ma -15 1.5 0.24 0.24 0.5 17 1-Nov-15 1.7 1.7 0.24 0.24 18 1-Ma -16 1.3 0.24 0.9 1.4 19 1-Nov-16 1.2 0.8 1.5 1.9 20 1-Ma -17 2.8 2 1.2 1.7 21 1-Dec-17 1.7 2.7 0.6 2 22 1-Jun-18 1.2 0.5 0.3 1.4 23 24 25 Coefficient of Variation: Mann -Kendall Statistic (S): Confidence Factor: Concentration Trend: � M W-3S BMW-3A J ` -8 4k 12S O M L 41 C 0 U 0.01 10106 02108 07/09 11/10 04112 08113 12114 05116 09/17 02/19 Sampling Date An Notes: 1. At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples. 2. Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing; >_ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S<_0, and COV >_ 1 = No Trend; < 90% and COV < 1 = Stable. 3. Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales, Ground Water, 41(3):355-367, 2003. 4 MDL value used for ND concentrations. DISCLAIMER: The GSI Mann -Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein. GSI Environmental Inc., www.gsi-net.com TOOLKIT for • - Analysis Evaluation Date: 21-Aug-18 Job ID: 6468177152 Facility Name: C&D Landfill Constituent: Benzene Conducted By: DH Concentration Units: Ng/L Sampling Point ID: MW-3S MW-3A MW-8 MW-12S 1 1-Nov-07 2 1-Ma -08 3 1-Nov-08 4 1-Ma -09 5 1-Au -09 6 1-Jan-10 7 1-Ma -10 8 1-Nov-10 9 1-May-11 10 1-Nov-11 11 1-Ma -12 12 1-Nov-12 13 1-Ma -13 14 1-May-14 15 1-Nov-14 16 1-Ma -15 17 1-Nov-15 1.7 1.7 0.24 0.24 18 1-Ma -16 1.3 0.24 0.9 1.4 19 1-Nov-16 1.2 0.8 1.5 1.9 20 1-Ma -17 2.8 2 1.2 1.7 21 1-Dec-17 1.7 2.7 0.6 2 22 1-Jun-18 1.2 0.5 0.3 1.4 23 24 25 Coefficient of Variation: Mann -Kendall Statistic (S): Confidence Factor: Concentration Trend: � M W-3S BMW-M J � �MW-8 -MW-12S 1 i c d c 0 O U 0.1 10106 02108 07109 11/10 04112 08113 12114 05116 09117 02119 Sampling Date A& Notes: 1. At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples. 2. Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing; >_ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S<_0, and COV >_ 1 = No Trend; < 90% and COV < 1 = Stable. 3. Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales, Ground Water, 41(3):355-367, 2003. 4 MDL value used for ND concentrations. DISCLAIMER: The GSI Mann -Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein. GSI Environmental Inc., www.gsi-net.com TOOLKIT for • • Analysis Evaluation Date: 8-Mar-18 Job ID: 6468177152 Facility Name: C&D Landfill Constituent: Vinyl Chloride Conducted By: DH Concentration Units: N /LCoefficient of VINYL CHLORIDE CONCENTRATION (HgIL) TOOLKIT for • • Analysis Evaluation Date: 8-Mar-18 Job ID: 6468177152 Facility Name: C&D Landfill Constituent: Vinyl Chloride Conducted By: DH Concentration Units: N /L VINYL CHLORIDE CONCENTRATION (Coefficient of Mann -Kendall Statistic (S): 1 Confidence Factor: 50.0% p gIL) Variation: Concentration Trend: 0.43 Table 4 Summary of Natural Attenuation Parameters - July 2018 Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina r Analyte Group Parameter Phase I Monitoring Wells 2L Standard MW-1S (Well #1) MW-2S (Well #2) MW-3S (Well #3) MW-3A MW-4 MW-5 MW-6 MW-7 MW-8 MW-16 MW-1D MW-2D MW-3D Carbon Dioxide NE 62,000 97,000 310,000 81,000 103,000 79,000 188,000 100,000 146,000 197,000 14,000 7,000 6,000 Dissolved Gasses Ethane NE 0.0028 Jn 0.0036 Jn 0.15 n 1 0.028 n 0.014 n 0.0052 Jn 0.0025 Jn 0.0081 Jn 0.045 n 0.0062 Jn 0.24 n 0.0082 Jn 0.0014 Jn (pg/L; unless Ethene NE 0.005 Jn 0.0052 Jn 0.068 Jn 0.0082 Jn 0.002 Un 0.0094 Jn 0.0048 Jn 0.0066 Jn 0.019 n 0.009 Jn 0.025 n 0.0069 Jn 0.0047 Jn noted) Hydrogen(nM) NE 3.7n 4.4n NA 3.1n 3.4n 2.7n 3.1n 2.4n 9.1n 3.4n 4.4n 1.9n 3.4n Methane NE 5.3 n 65 n 1,900 n 420 n 480 n 63 n 140 n 290 n 660 n 480 n 700 n 22 n 0.4 n Acetic Acid 5,000" 57 J 40 J 92 J 160 911 79 J 26 J 240 84 J 52 J 120 44 J 59 J Butyric Acid NE 5.5 U 36 J 5.5 U 190 46 J 47 J 74 J 100 29 J 5.5 U 5.5 U 5.5 U 5.5 U Hexanoic Acid NE 9.5U 9.5U 9.5U 9.5U 9.5U 9.5U 9.5U 9.8J 9.5U 9.5U 9.5U 9.5U 9.5U i-Hexanoic Acid NE 11U 11U 11U 11U 11U 11U 11U 11U 11U 11U 11U 11U 11U Fatty Acids (pg/L) i-Pentanoic Acid NE 9.8 U 9.8 U 9.8 U 9.8 U 9.8 U 111 9.8 U 9.8 U 9.8 U 9.8 U 9.8 U 9.8 U 9.8 U Lactic Acid NE 18 J 16 J 11 U 21 J 3,300 20 J 28 J 27 J 30 J 27 J 120 J 55 J 77 J Pentanoic Acid NE 8.2U 8.2U 8.2U 8.2U 8.2U 8.2U 8.2U 8.2U 8.2U 8.2U 8.2U 8.2U 8.2U Propionic Acid NE 5.5 U 5.5 U 5.5 U 8.3 J 5.5 U 5.5 U 5.5 U 12 J 6.7 J 5.5 U 14 J 6.4 J 5.5 U Pyruvic Acid NE 8.9U 8.9U 8.9U 8.9U 8.9U 8.9U 12J 8.9U 8.9U 8.9U 8.9U 8.9U 8.9U Alkalinity (CaCO3) NE 185,000 196,000 1,800,000 332,000 123,000 350,000 690,000 404,000 470,000 168,000 173,000 216,000 230,000 Biological Oxygen Demand (BOD) NE 2000 U 3,400 9,700 2000 U 2000 U 3600 5800 3400 3,500 14,000 2,000 U 2,000 U Chloride 250,000 5,000 U 51,000 216,000 46000 9000 33,000 27000 24000 62000 18000 12,000 13,000 21,000 Other Natural Chemical Oxygen Demand (COD) NE 24,000 39,000 496,000 94000 36,000 56000 71,000 59,000 121,000 87,000 29,000 840 U 840 U Attenuation Iron 300 1,257 3,727 16,526 12,617 3,613 3,603 765 5,969 16,301 11,080 4,887 2,513 2,035 Parameters Manganese 50 0.31 U 105 938 179 71 81 265 141 815 85 410 41 J 16 J (pg/L; unless noted) Nitrate (as N) 10,000 9 U 370 J 9 U 9 U 170 J 9 U 2,270 J 9 U 140 J 60 J 370 J Sulfate 250,000 27,100 190,000 66,000 23,300 19,000 93,900 25,200 30,700 108,000 11,300 5,000 U 30,700 18,500 Total Dissolved Residue (TDR) 500,000 283,000 623,000 2,250,000 439,000 234,000 592,000 707,000 472,000 745,000 359,000 253,000 326,000 346,000 Total Hardness (mg/L) NE 220 320 840 190 132 370 450 300 370 136 100 176 92 Total Organic Carbon (TOC) NE 8,320 13,240 172,000 26,670 11,950 14,020 22,750 19,380 29,850 39,500 7,970 2,410 3,790 pH (S.U.) 6.5 - 8.5 6.6 6.7 6.8 6.8 6.5 7.0 6.6 6.6 6.6 5.9 7.3 7.8 8.0 Conductivity at 25°C (pS/cm NE 484 847 3,570 398 402 562 1,109 778 710 394 400 447 524 Field Dissolved Oxygen (pg/L) NE 420 180 680 540 530 510 710 730 420 590 580 1,190 350 Parameters ORP (mV) NE 1 31 1 -31 1 -92 1 -38 1 18 42 1 102 1 -18 1 -14 1 96 1 97 1 17 1 87 Temperature (°C) NE 23 22 23 18 22 21 19 20 20 25 20 22 22 Turbidity (NTU) NE 10 13.8 6.8 47.4 72.0 71.5 5.4 12.1 15.5 35.9 9.55 45.5 32.4 Page 1 of 3 Table 4 Summary of Natural Attenuation Parameters - July 2018 Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina r. Analyte Group Parameter Phase II Monitoring Wells 2L Standard MW-9A MW-10 MW-11 MW-12S MW-13 MW-14S MW-15 MW-16 MW-17 MW-14D Dissolved Gasses (Ng/L; unless noted) Carbon Dioxide NE 60,000 380,000 168,000 250,000 99,000 67,000 16,000 197,000 95,000 11,000 Ethane NE 0.015 n 0.046 n 0.013 n 0.048 Jn 0.0033 Jn 0.02 n 0.02 n 0.0062 Jn 0.026 n 0.0062 Jn Ethene NE 0.0045 Jn 0.064 n 0.081 n 0.33 n 0.016 n 0.0074 Jn 0.0061 Jn 0.009 Jn 0.014 Jn 0.011 n Hydrogen (nM) NE 3.3 n 3.8 n 3.6 n NS 2.8 n 3.7 n 3.6 n 3.4 n 3.7 n 3.4 n Methane NE 98 n 3400 n 110 n 2300 n 83 n 210 n 430 n 480 n 160 n 6.3 n Fatty Acids (Ng/L) Acetic Acid 5,000* 46 J 47 J 47 J 12 U 53 J 60 J 51 J 52 J 39 J 60 J Butyric Acid NE 5.5 U 180 25 J 470 5.5 U 5.5 U 5.5 U 5.5 U 5.5 U 5.5 U Hexanoic Acid NE 9.5U 9.5U 9.5U 76J 9.5U 9.5U 9.5U 9.5U 9.5U 9.5U i-Hexanoic Acid NE 11U 11U 11U 11U 11U 11U 11U 11U 11U 11U i-Pentanoic Acid NE 9.8 U 9.8 U 9.8 U 9.8 U 9.8 U 9.8 U 9.8 U 9.8 U 9.8 U 9.8 U Lactic Acid NE 40 J 25 J 24 J 190 J 61 J 100 J 14 J 27 J 33 J 100 J Pentanoic Acid NE 8.2U 8.2U 8.2U 58J 8.2U 8.2U 8.2U 8.2U 8.2U 8.2U Propionic Acid NE 5.5 U 5.5 U 5.5 U 5.5 U 6.9 J 5.5 U 5.5 U 5.5 U 5.5 U 5.5 U Pyruvic Acid NE 8.9 U 8.9 U 8.9 U 86 J 8.9 U 8.9 U 8.9 U 8.9 U 8.9 U 8.9 U Other Natural Attenuation Parameters (Ng/L; unless noted) Alkalinity (CaCO3) NE 170,000 492,000 480,000 980,000 163,000 114,000 58,000 168,000 39,000 261,000 Biological Oxygen Demand (BOD) NE 2,000 U 4,100 6,700 6,300 2,000 U 2,000 L 2,000 U 2,000 U 2,000 U 2,000 U Chloride 250,000 8,000 92,000 17,000 98,000 5,000 U 5,000 U 5,000 U 18,000 17,000 14,000 Chemical Oxygen Demand (COD) NE 25,000 134,000 82,000 302,000 42,000 80,000 47,000 87,000 72,000 840 U Iron 300 5,463 1,568 17,196 6,240 9,822 1,736 6,510 11,080 3,081 176 J Manganese 50 166 291 325 570 53 353 75 85 191 21 J Nitrate (as N) 10,000 9 U 9 U 180 J 9 U 980 J 9 U 40 J 9 U C J 210 J Sulfate 250,000 94,200 58,200 271,000 5,000 U 5,000 U 5,000 U 45,400 11,300 144,000 5,000 U Total Dissolved Residue (TD R) 500,000 348,000 822,000 907,000 1,200,000 271,000 185,000 164,000 359,000 677,000 324,000 Total Hardness (mg/L) NE 240 424 640 580 200 100 76 136 368 156 Total Organic Carbon (TOC) NE 5,860 89,680 28,840 90,760 18,100 14,600 16,800 39,500 29,800 2,710 Field Parameters L pH (S.U.) 6.5 - 8.5 7.6 6.4 6.9 6.8 6.5 6.4 7.6 5.9 5.4 6.0 Conductivity at 25°C (pS/cm NE 375 717 866 1,502 322 194 491 394 628 197 Dissolved Oxygen (pg/L) NE 390 570 640 540 530 270 670 590 490 1,630 ORP (mV) NE 14 106 -48 -23 -7 93 80 96 91 79 Temperature (°C) NE I 25 21 24 1 23 1 24 24 25 25 23 24 Turbidity (NTU) NE 38.2 7.6L__L 56.1 1 5.93 1 26.1 17.6 63.0 35.9 41.3 3.5 Page 2 of 3 Water Quality Monitoring Report December 2019 Semiannual Sampling Event Wood Project No. 6468-19-9035 Attachment C Mann -Kendall Trend Analyses wood. TOOLKIT for • - Analysis Evaluation Date: 22-Mar-20 Job ID: 6480199035 Facility Name: C&D Landfill Constituent: Benzene Conducted By: DH Concentration Units: N /L Sampling Point ID: MW-31S I MW-3A I MW-8 I MW-10 I MW-11 MW-12S 1 1-Nov-15 1.7 1.7 0.24 0.24 2 1-Ma -16 1.3 0.24 0.9 0.5 1.4 3 1-Nov-16 1.2 0.8 1.5 0.6 1.9 4 1-May-17 2.8 2 1.2 0.4 1.7 5 1-Dec-17 1.7 2.7 0.6 0.24 1 2 6 1-Jun-18 1.2 0.5 0.3 0.24 0.9 1.4 7 1-Dec-18 1.3 1.69 0.48 1.57 0.48 1.48 8 1-Jun-19 0.89 1 1.17 2.26 1.89 2.52 9 1-Dec-19 1.81 1.49 1.13 1.28 2.56 2.12 10 11 12 13 14 15 16 17 18 19 20 Coefficient of Variation: Mann -Kendall Statistic (S): Confidence Factor: ' Concentration Trend: Stable No Trend No Trend No Trend No Trend Increasing 10 --4- M W-3S ^` --41-- M W-3A J \ MW-8 _ M W-10 v _ MW-11 O1 MW-12S L d V _ O U 0.1 07115 01116 08116 03117 09117 04118 10118 05119 12119 06120 Sampling Date Notes: 1. At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples. 2. Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing; >_ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S<_0, and COV >_ 1 = No Trend; < 90% and COV < 1 = Stable. 3. Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales, Ground Water, 41(3):355-367, 2003. 4 MDL value used for ND concentrations. DISCLAIMER: The GSI Mann -Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein. GSI Environmental Inc., www.gsi-net.com TOOLKIT for • • Analysis Evaluation Date: 22-Mar-20 Job ID: 6480199035 Facility Name: C&D Landfill Constituent: Vinyl Chloride Conducted By: DH Concentration Units: N IL VINYL CHLORIDE CONCENTRATION (N9Coefficient of Variation: Mann -Kendall Statistic (S): Confidence Factor: Concentration Trend: l�end / U) Water Quality Monitoring Report June 2019 Semiannual Sampling Event Wood Project No. 6468-19-9035 Attachment C Mann -Kendall Trend Analyses wood. TOOLKIT for • - Analysis Evaluation Date: 29-Aug-19 Job ID: 6480199035 Facility Name: C&D Landfill Constituent: Benzene Conducted By: DH Concentration Units: N /L Sampling Point ID: MW-31S I MW-3A I MW-8 I MW-10 I MW-11 MW-12S 1 1-Nov-15 1.7 1.7 0.24 0.24 2 1-Ma -16 1.3 0.24 0.9 0.5 1.4 3 1-Nov-16 1.2 0.8 1.5 0.6 1.9 4 1-May-17 2.8 2 1.2 0.4 1.7 5 1-Dec-17 1.7 2.7 0.6 0.24 1 2 6 1-Jun-18 1.2 0.5 0.3 0.24 0.9 1.4 7 1-Dec-18 1.3 1.69 0.48 1.57 0.48 1.48 8 1-Jun-19 0.89 1 1.17 2.26 1.89 2.52 9 10 11 12 13 14 15 16 17 18 19 20 Coefficient of Variation: Mann -Kendall Statistic (S): Confidence Factor: Concentration Trend: Stable No Trend Stable No Trend Stable Prob. Increasing 10 M W-3S t M W-3A J M W-8 ai - MW-io v -ix- M W-11 O1 MW-12S i+ d V _ O U 0.1 07115 011161F 08116 03117 09117 04118 10118 05119 12119 Sampling Date Notes: 1. At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples. 2. Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing; >_ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S<_0, and COV >_ 1 = No Trend; < 90% and COV < 1 = Stable. 3. Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales, Ground Water, 41(3):355-367, 2003. 4 MDL value used for ND concentrations. DISCLAIMER: The GSI Mann -Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein. GSI Environmental Inc., www.gsi-net.com TOOLKIT for • • Analysis Evaluation Date: 29-Aug-19 Job ID: 6480199035 Facility Name: C&D Landfill Constituent: Vinyl Chloride Conducted By: DH Concentration Units: N IL VINYL CHLORIDE CONCENTRATION (N9/ U) Concentration Trend: Wo Trend Stable Table 6 Summary of Natural Attenuation Parameters - June 2019 Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina Analyte Group Parameter Carbon Dioxide GWPS NE (Well #1) 68,000 (Well #2) 121,000 (Well #3) 3,000,000 240,000 Phase I Monitoring Wells 130,000 299,000 304,000 342,000 389,000 13,000 6,000 6,000 Dissolved Ethane NE 0.006 Udn 0.018 n 0.069 n 0.24 n 0.038 n 0.15 n 0.039 Jn 0.043 Jn 0.23 n 0.53 n 0.0046 Jn 0.0061 Jn Gasses (Ng/L; Ethene NE 0.010 Udn 0.005 Un 0.005 Un 0.012 n 0.0097 Jn 0.005 Un 0.065 Jn 0.049 Jn 0.068 Jn 0.005 Un 0.005 Un 0.005 Un unless noted) Methane NE 27 do 430 n 440 n 1,100 n 1,900 n 960 n 2,400 n 1,800 n 3,000 n 4,300 n 12 n 9.7 n Hydrogen (nM) NE 1.5 Udn 1.1 n 1.2 n 1 n 0.86 Jn 0.98 Jn NS NS 5.5 n 1 n 0.91 Jn Acetic Acid 5,000* 33 J 55 J 28 U 280 U 58 J 280 U 280 U 290 J 280 U 230 42 J 47 J Butyric Acid NE 11 U 98 J 11 U 370 J 24 J 230 J 380 J 330 J 980 J 11 U 11 U 11 U Hexanoic Acid NE 10 U 10 U 1101 160 J 10 U 160 J 210 J 100 U 1101 10 U 10 U 10 U i-Hexanoic Acid NE 29 U 29 U 29 U 290 U 29 U 290 U 290 U 290 U 290 U 29 U 29 U 29 U Fatty Acids iNgAc i-Pentanoic Acid NE 6 U 6 U 6 U 60 U 6 U 60 U 60 U 60 U 60 U 6 U 6 U 6 U Lactic Acid NE 43 U 43 U 43 U 430 U 43 U 430 U 430 U 430 U 430 U 43 U 43 U 43 U Pentanoic Acid NE 7 U 7 U 36 J 70 U 7 U 70 U 70 U 70 U 79 J 7 U 7 U 7 U Propionic Acid NE 4U 4U 4U 40U 4U 40U 40U 40U 40U 25J 4U 4U Pyruvic Acid NE 5 U 5 U 48 J 50 U 5 U 50 U 50 U 50 U 64 J 5 U 5 U 5 U Nitrate (as N) 10,000 170 100 9 U 9 U D U 9 U 190 2,710 170 9 U 110 350 Biological Oxygen Demand (BOD) NE 2000 U 2000 U 7,500 2000 U 2000 U 3,100 4,100 7,600 13,000 2,000 2000 U 2000 U Other Natural Attenuation Chemical Oxygen Demand (COD) NE 36,000 67,000 423,000 198,000 67,000 148,000 294,000 291,000 432,000 28,000 840 U 840 U Parameters Alkalinity (CaCO3) NE 165,000 280,000 1,610,000 810,000 342,000 912,000 1,500,000 1,360,000 1,620,000 171,000 182,000 236,000 Iron (Ferrous) NE 371 8,136 24,655 27,430 3,957 7,394 20,872 27,011 39,673 2,258 50 U 50 U Total Organic Carbon (TOC) NE 13,000 26,080 164,600 75,200 27,480 50,360 108,500 104,800 275,800 7,140 2,240 2,420 Total Hardness NE 1 316 548 1 856 596 268 896 1,020 720 1 1,032 140 164 92 Page 1 of 3 Table 6 Summary of Natural Attenuation Parameters - June 2019 Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina re Group Parameter Carbon Dioxide GWPS NE •A 48,000 408,000 246,000 Phase 11 Monitoring Wells 151,000 462,000 306,000 66,000 332,000 80,000 14,000 Dissolved Ethane NE 0.076 n 0.04 n 0.0078 Jn 0.17 n 0.0066 Jn 0.039 n 0.0079 Jn 0.01 n 0.022 n 0.009 Jn Gasses (Ng/L; Ethene NE 0.005 Un 0.19 n 0.058 n 0.5 n 0.027 n 0.1 n 0.005 Un 0.022 n 0.005 Un 0.0064 Jn unless noted) Methane NE 92 n 3,900 n 130 n 4,600 n 190 n 3,000 n 200 n 660 n 160 n 12 n Hydrogen (nM) NE 0.82 Jn 1.1 n 1.2 n NS 1.5 n 0.84 Jn 0.98 Jn 1.2 n 1.1 n 0.9 Jn Acetic Acid 5,000' 31 J 28 U 63 J 730 J 52 J 44 J 40 J 74 J 46 J 45 J Butyric Acid NE 11 U 240 55 J 1,100 11 U 11 U 11 U 70 J 11 U 11 U Hexanoic Acid NE 10 U 10 U 76 J 100 U 14 J 10 U 10 U 10 U 10 U 10 U i-Hexanoic Acid NE 29 U 29 U 29 U 290 U 29 U 29 U 29 U 29 U 29 U 29 U Fatty Acids (NgAc) i-Pentanoic Acid NE 6 U 6 U 6 U 60 U 6 U 6 U 6 U 6 U 6 U 6 U Lactic Acid NE 43 U 43 U 43 L 430 U 70 J 43 U 43 U 43 U 43 U 43 U Pentanoic Acid NE 7 U 7 U 9.9 J 180 J 7 U 7 U 7 U 7 U 7 U 7 U Propionic Acid NE 4 U 4 U 40 U 4 U 4 U 4 U 4.2 J 4 U 4 U Pyruvic Acid NE 5 U 5 U 17 J 50 U 14 J 15 J 5 U 5.8 J 5 U 5 U Nitrate (as N) 10,000 9 U 9 U 9 U U 460 9 U 9 U 9 U 9 U 240 Biological Oxygen Demand (BOD) NE 2000 U 11,000 2000 U 8,500 2000 U 3,100 2000 U 4,000 2000 U 2000 U Other Natural Attenuation Chemical Oxygen Demand (COD) NE 22,000 276,000 67,000 620,000 55,000 96,000 39,000 141,000 43,000 840 U Parameters Alkalinity (CaCO3) NE 196,000 1,340,000 528,000 1,730,000 232,000 520,000 49,000 240,000 71,000 248,000 Iron (Ferrous) NE 2,394 50 U 19,045 1,887 5,026 5,629 5,962 25,400 2,511 Total Organic Carbon (TOC) NE 4,960 106,300 26,760 220,000 22,320 29,760 15,260 76,400 18,320 2,680 Total Hardness NE 267 1,120 659 749 263 353 114 713 302 161 Page 2 of 3 Appendix 2 Historical Data For Selected Analytes Parameter: Antimony CAS No. 7440-36-0 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Asst. BG Met. old B-20 Fac. BG BG BG Date MCL IMAC 2B Std pg/L MW-ID MW-iS MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MIN-5 MIN-6 MW-7 MW-8 MW-9A MW-10 MIN-11 MW-12S MW-13 MW-14D MW-14S MW-15 MW-16 MW-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 NO NO NO 0.05 U 0.1 J 0.1 J 0.44 U 0.05 U 0.11 0.06 J 0.06 J NO NO NO 2.95 U 2.95 U 2.95 U 2.95 U 2.95 U 2.95 U 2.95 U 0.4 J 0.06 J 0.06 J 0.06 J 0.06 J 0.1 J 0.2 J 0.3 J 0.06 J 0.22 U 0.22 U 0.7 J 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.8 J 0.22 U 0.22 U 0.14U 0.14U 0.14U 0.47J 0.14U 0.14U 0.14U 0.14U 0.14U 0.511 0.14U 0.14U 0.14U 0.03 J 0.04 J 0.061 0.24 J 0.101 0.34 J 0.06 J 0.09 J 0.08 J 0.3 J 0.10 J 0.9 1 0.14 J 0.04 J 0.04 J 0.05 J 0.18 J 0.03 J 0.4 J 0.15 J NO NO Nov-01 NO NO NO NO NO NO NO NO May-02 NO NO NO NO NO NO NO Nov-02 NO NO NO NO NO NO NO NO NO NO May-03 NO NO NO NO NO NO NO NO NO NO NO Nov-03 NO NO NO NO NO NO NO NO NO NO NO May-04 NO NO NO NO NO NO NO NO NO NO Nov-04 NO NO NO NO NO NO NO NO NO NO May-05 Damaged NO NO NO NO NO NO NO NO NO NO Nov-05 NO NO NO NO NO NO NO NO NO NO May-06 Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.05 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U Nov-2007 0.05 E 0.05 U 0.4 J 0.05 U 0.05 U 0.2 J 0.05 U 0.05 U Dry 0.05 U 0.05 U May-2008 0.08 0.2 J 0.44 U 0.44 U 0.44 U 0.11 0.5 J 0.2 J 0.2 J 0.1 J 0.2 J 0.44 U 0.44 U Nov-2008 0.05E 0.1 J 0.11 0.1 J 0.1 J 0.2 J 0.11 0.05 U Dry 0.6 J 0.11 May-2009 0.06 0.1 J 0.06 J 0.1 J 0.7 J 0.2 J 0.11 0.06 J 0.06 J 0.11 0.06 J 0.06 J Aug-2009 Begin Assessment+ Phase 2 2.95 2.95 U 2.95 U 2.95 U Jan-2010 6 1 0.06 0.06 J 0.11 0.06 J 0.06 J 0.06 J 0.50 0.06 J 0.06 J 0.06 J 0.1 J 0.11 0.6 J 0.2 J May-2010 0.22 0.22 U 0.7 J 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U Nov-2010 0.22 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.6 J 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U May-2011 0.14 0.19J 0.14U 0.14U 0.14U 0.14U 0.4J 0. 00.14U 0.14U 0.14U 0.2J 0.14U 0.29J Nov-2011 0.14 Damaged 0.14U 0.14U 0.14U 0.14U 0.14U 0.14U 0.14U 0.551 0.14U 0.14U 0.14U 0.14U 0.14U 0.14U 0.14U May-2012 0.02 0.121 0.12 J 0.27 J 0.101 0.151 0.36 J 0.17J 0.16 J 0.13 J 0.13 J 0.091 0.051 0.04 J Nov-2012 0.02 Damaged 0.14 J 0.1 J 0.28 J 0.17 J 0.16 J 0.50 J 0.14 J 0.5 1 0.07 J 0.151 0.16 J 0.02 U 0.02 U 0.02 U 0.02 U May-2013 0.02 Damaged 0.07 J 0.04 J 0.09 J 0.03 J 0.02 U 0.07 J 0.02 U 0.34 J 0.07 J 0.02 U 0.14 J 0.14 J 0.04 J 0.03 J Dry Nov-2013 Not Sampled May-2014 2B values verified as of 9/22/2017 in -stream target values except bold values are hardness related 0.12 0.19 J 0.02 U 0.02 U 0.03 J 0.02 U 0.34 J 0.02 U 0.12 J 0.07 J 0.02 U 0.02 U 0.02 U 0.10 J 0.02 U 0.17 J 0.101 0.06U 0.02 U 0.02 U 0.02 U Dry Nov-2014 0.02 16.00 0.16 J 0.14 J 0.12 U 0.78 J Damaged 0.18 J 0.22 J 0.20 J 0.12 U 0.24 J 0.24 J 0.34 J 0.12 U 0.21 J 0.12 U 0.12 U 0.46 J Dry May-2015 0.02 0.57 J 0.26 J 0.21 J 0.03 J 0.05 J 0.06 J 0.02 U 0.23 J 0.52 J 0.08 J 0.22 J 0.111 0.02 U 0.02 U 0.02 U 0.70 J 0.02 U 0.06 J 0.18 J 0.65 J 0.18 J 0.06 J 0.04 J Nov-2015 0.05 0.951 0.151 0.161 0.24 J 0.191 1.4 J 0.24 J 0.27 J 0.32 J 0.20 J 0.17 J 0.12 J 0.14 J 0.161 0.12 J 0.101 0.091 0.061 0.86 J May-2016 0.05 0.56 J 0.05 U 0.10 J 0.05 U 0.05 U DRY 0.12 J 0.13 J 0.12 J 0.05 U 0.27 J 0.05 U 0.26 J 0.12 J 0.12 J 0.05 U 0.09 J 0.05 U 0.05 U Nov-2016 0.05 0.45 J 0.07 J 0.19 J 0.111 0.05 U DRY 0.08 J 0.12 J 0.24 J 0.05 U 0.21 J 0.05 U 0.28 J 0.111 0.08 J 0.05 U 0.05 U 0.06 J Dry May-2017 0.06 0.3J 0.66 J 0.081 0.08 J O.06U 0.15 J 0.19 J O.06U 0.44 J 0.061.1 0.08 J 0.19 J O.06U 0.31 J 0.07 J 0.29 J 0.16 J 0.091 0.14 J O.06U O.06U O.06U O.06U Dec-2017 chronic value at Hardness =25 mgll 0.06 0.26 J 0.37 J 0.06 U 0.17 J 0.06 U 0.19 J 0.2 J 0.06 J 0.69 J 0.111 0.12 J 0.26 J 0.11 0.15 J 0.07 J 0.25 J 0.13 J 0.08 J 0.111 0.08 J 0.14 J 0.09 J Dry 0.06 U 0.06 U 0.07 J Jun-2018 5300 0.03 0.08 J 0.41 J 0.04 J 0.07 J 0.07 J 0.21 J 0.06 J 0.07 J 0.18 J 0.06 J 0.09 J 0.04 J 0.12 J 0.10 J 0.18 J 0.13 J -- U -- U 0.04 J 0.04 J 0.04 J Dry 0.07 J 0.05 J Dry Dec-2018 0.03 0.11 J 0.52 J -- U 0.16 J 0.04 J 0.12 J 0.20 J 0.18 J 0.17 J0.22 J 0.10J--U006 J 0.17 J 0.13 J 0.04 J 0.06 J 0.05 J 0.05 J 0.04 J 0.17J040.05J 0.04 J Jun-2019 0.03 9.00 0.67 J 0.03 J 0.09 J 0.04 J 0.17 J 0.14 J 0.26 rulioo J 0.10 J0.24 J -- U 0.21 J 0.03 J 2.90 0.10 J 0.04 J 0.06 J 0.04 J 0.46 J -- U 0.05 J 0.05 J 0.07 J 006 JDeo-2019 0.03 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U 0.05 J 0.18 J 0.36 J 0.31 J 0.11 J 0.22 J 0.18 J 0.06 J 0.18 J 0.06 J 0.41 0.05 J 0.09 J 0.04 J 0.04 0.00 0.16 0.00 0.07 0.00 0.21 0.00 0.20 0.00 0.07 0.00 0.50 0.00 0.19 0.00 0.17 0.00 0.24 0.00 0.10 0.00 0.21 0.00 0.36 0.00 2.90 0.00 0.13 0.00 0.22 0.00 0.18 0.00 0.06 0.00 0.46 0.00 0.06 0.00 0.00 0.41 0.00 0.07 0.00 0.09 0.00 0.06 0.00 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. INS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 21- Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)' in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 1 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Arsenic CAS No. 7440-38-2 sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Asst. BG Asst. old B-20 Fac. BG BG BG Date 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MIN-7 MW-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MW-15 MIN-16 MW-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 50 -- NO NO NO 0.6 J 6.7 J 7.3J 0.4J 0.2 J 8.4 J 0.51 7.0J NO NO NO 4.9 U 4.9 U 4.9 U 4.9 U 4.9 U 4.9 U 4.9 U 1.3J 0.51 0.17U 0.17U 2.4J 0.2J 1.3J 3.6J 0.5J 0.3J 0.51 0.04U 0.4J 1.4J 0.04U 0.61 1.11 0.61 5.3J 1.81 1.61 0.601 0.52J 0.10U 5.91 0.29J 1.51 0.501 2.5 J 0.23 J 11.00 0.52 J 0.32 J 1.7 J 0.501 1.11 0.41J 24.00 0.62J 4.0J 0.17 J 1.S J 0.82 J 15.00 0.76 J 0.24 J 3.7 J 0.151 0.74 J 0.581 19.00 0.34 J 0.081 5.O J NO NO Nov-01 NO NO NO NO NO NO NO NO May-02 NO NO NO NO NO NO NO Nov-02 NO NO NO NO NO NO NO NO NO NO May-03 NO NO NO NO NO NO NO 13.00 NO NO NO Nov-03 NO NO NO NO NO NO NO NO NO NO NO May-04 NO NO NO NO NO 6.41 NO NO NO NO Nov-04 NO NO NO NO 14.00 3.60 NO NO NO NO May-05 Damaged NO NO NO NO NO NO NO NO NO NO Nov-05 NO NO NO NO 22.00 NO NO NO NO NO May-06 Damaged NO NO NO NO 5.30 NO NO NO NO NO NO Nov-06 NO NO NO 5 J NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.47 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 10 Nov-2007 0.47 E 0.47 U 4.2 J 1.3 J 5.3 J 16.00 6.4 J 0.47 U Dry 2.0 J 0.5 J May-2008 0.47 0.3J 0.51 0.4J 1.3J 1.01 5.0J 5.3J 3.61 4.5J 11.00 1.11 0.11 Nov-2008 0.47 E 1.1 1 5.61 0.3 J 2.1 J 11.00 3.3 J 2.7 J Dry 5.3 J 0.91 May-2009 0.47 1.81 1.2J 2.2J 2.8J 1.3J 2.9J 1.01 1.61 6.3J 1.4J 0.81 Aug-2009 Begin Assessment + Phase 2 4.91 6.4 J 4.9 U 4.9 U Jan-2010 10 0.17 2.1J 0.81 6.8J 2.6J 2.8J 5.81 6.4J 0.51 4.0J 3.9J 0.3J 0.17U 0.2J May-2010 0.04 0.7J 1.7J 9.2J 1.01 2.6J 3.9J 6.11 4.5J 7.5J 0.91 1.3J 0.4J 0.61 Nov-2010 0.04 1.91 5.61 0.04U 5.4J 2.3J 0.04U 4.8J 0.91 4.0J 2J 1.11 0.61 0.51 May-2011 0.10 0.36J 3.1J 3.8J 0.93J 1.61 6.4J 2.2J 1.51 3.2J 3.1J 0.82J 1.11 1.3J Nov-2011 0.10 Damaged 1.11 0.48 J 0.91 0.36 J 4.9 J 2.2 J 1.91 3.3 J 2.4 J 0.811 2.7 J 2.O J 2.5 J 0.991 0.511 May-2012 0.13 0.881 6.11 4.2J 2.8J 2.9J 6.81 2.2J 2.3J 5.8J 4.7J 2.0J 1.01 0.92J Nov-2012 0.13 Damaged 0.74 J 0.35 J 9 J 0.33 J 5.7 J 5.51 0.91 1.9 J 2.4 J 0.72 J 8.O 1 0.93 J 0.681 0.501 0.82 J May-2013 0.05 Damaged 0.02 J 0.86 J 5.3 J 0.51 J 3.7 J 2.4 J 0.831 2.4 J 2.4 J 5.0 J 6.2 J 1.2 J 0.81 J 0.35 J Dry Nov-2013 Not Sampled May-2014 0.05 0.05 U 0.12 J 3.8 J 0.05 U 0.05 U 0.28 J 0.05 U 2.1 J 5.8 J 0.05 U 0.05 U 0.05 U 11.00 0.05 U 0.30 J 6.4J 0.41J 0.67 Jfi0147 J 0.26 J Dry Nov-2014 0.14 0.86 J 7 J 9 J 4.5 J 0.66 J Damaged 3.4 J 4.1 J 10.00 0.14 U 0.84 J 0.17 J 36.00 0.37 J 6.9 J 0.78 JJ 0.33 J Dry May-2015 0.14 0.49J 2.2J 0.391 0.15J 0.26J 6.1J 0.14U 1.7J 11.00 1.3J SJ 4.3J 0.14U 0.73J 0.46J 15.00 0.41J 0.23J 1.2J 0.82JJ 0.71J 0.80J Nov-2015 0.14 1.01 1.2J 11.00 81 3.6J 3.5J 3.6J 2.9J 2.1J 0.14U 1.2J 0.24J 2.8J 0.26J 2.4J 0.71J1 0.52J 0.39J May-2016 0.66 2.7 J 0.66 U 10.00 1.5 J 2.1 J DRY 5.2 J 5.6 J 11.00 0.66 U 10.00 0.66 U 38.00 0.66 U 0.84 J 0.92 JJ 0.88 J 0.66 U Nov-2016 0.66 1.9 J 1.2 J 7.00 6.8 J 0.91J DRY 13.00 5.1J 21.00 0.66 U 7 J 1.3 J 42.00 0.85 J 2.1 J 1.2 JJ 0.72 J Dry May-2017 0.07 0.07U 0.31J 0.07U 1.2 J 0.401 11.00 11.00 0.75 J 5.1J 6.4 J 4.0 J 16.00 0.21 J 8 J 0.44 J 52.00 1.3 J 0.07U 0.90 J 1.8 JJ1.1J 1.2 J Deo-2017 0.07 4.9 J 0.42 J 0.79 J 8.0 J 0.41 J 14.00 13.00 0.74 J 2.1 J 10.00 0.47 U 15.00 0.36 J 2.6 J 2.2 J 41.00 1.5 J 0.58 J 2.6 J 2.8 J 3.2 J 2.4 J Dry J 0.49 J 0.14J Jun-2018 0.03 2.60 J 1.50 J 1.30 J 2.00 J 0.68 J 25.00 4.40 J 1.10 J 5.00 J 1.20 J 1.90 J 5.50 J 0.64 J 2.20 J 3.60 J 37.00 J 5.00J -- U 2.40 J 3 J 2.4 J 0.54 J Dry J 1.70 J Dry Deo-2018 2.50 J 0.96 J 0.91 J 4.10 J 0.12 J 27.00 21.00 0.48 J 4.10 5.70 15.00 15.00 0.03 J 9.00 3.20 J 22.00 1.10 J -- U 0.59J1.40 J 3.2 J -- U 1.60 J 0.44 J 0.16 J Jun-20191.50 J 0.68 J 0.06 J 5.30 0.27 J 20.00 11.00 1.50 J 7.00 11.00 9.00 19.00U 9.00 55002.30 J 0.18 J 2.20 J 1.60 J 5 0.03 J 1.50 J 1.90 J 1.10 J Deo-2019 Effective 11/1/2019 150 0.08 -- U-- U -- U 16.00 -- U 22.00 2000 -- U 3.20 J 10.00 2.80 J 28.00 -- U 5.50 4.61 J 29.00 -- U -- U 0.58 J 0.10 J 39J-- U 30.00U 2.30 J -- U 1.30 0.00 16.00 0.00 0.68 0.00 27.00 0.00 21.00 0.00 1.50 0.00 11.00 0.00 22.00 0.00 15.00 0.00 28.00 0.00 0.64 0.00 10.00 0.00 55.00 0.00 54.00 0.00 5.00 0.00 0.18 0.00 2.40 0.00 3.00 0.00 5.00 0.00 0.91 0.00 0.00 30.00 0.00 1.30 0.00 2.30 0.00 1.10 0.00 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyle detected above Method Detection Limit. 12. Bold red font indicates analyle detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyle detected above 21- Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 2 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Barium CAS No. 7440-393 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Asst. BG Asst. old B-20 Fac. BG BG BG Date MCL 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MIN-7 MW-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MW-15 MIN-16 MW-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 NO NO NO 4.6 J 357.00 394.00 4 J 5 J 447.00 5.3 J 460.00 NO NO NO 112 B 76.1 B 39.8 B 56.6 B 41 1 JB 13.9 JBME 55.4 J 113.00 23.4 J 98.5 J 82.8 J 13.1 J 51.5 J 54.8 J 29.4 J 129.00 14.2 J 39.2 J 86.7 J 32.9 J 63.2 J 31.4 J 177.00 106.00 50.7 J 89.2 J 19.2 J 346.00 92.3 J 43.6 J 43.6 J 17.3 J 467.00 67.8 J 9.9 J 48.9 J 87.5 J 23.9 J 291.00 74.2 J 36.5 J 132.00 19.31 504.00 76.6 J 11.2 J 39.5 J 169.00 19.8 J 342.00 69.7 J 10.2 J NO NO Nov-01 NO NO NO NO NO NO NO NO May-02 NO NO NO NO NO NO NO Nov-02 NO NO NO NO NO NO NO NO NO NO May-03 NO NO NO NO NO NO NO NO NO NO NO Nov-03 NO NO NO NO NO NO NO NO NO NO NO May-04 NO NO NO NO NO NO NO NO NO NO Nov-04 NO NO NO NO NO NO NO NO NO NO May-05 Damaged NO NO NO NO NO NO NO NO NO NO Nov-05 NO NO NO NO NO NO NO NO NO NO May-06 Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.04 0.04 U 0.04 U 0.04 U 0.04 U 100.00 0.04 U 112.00 144.00 0.04 U 0.04 U 0.04 U 0.04 U Nov-2007 0.11 E 62.4 J 96.9 J 207.00 115.00 233.00 136.00 214.00 Dry 126.00 571.00 May-2008 0.11 111 27.5 J 16 J 51.8 J 203.00 101.00 65 J 311 127.00 174.00 71.2 J 63 J Nov-2008 0.11 E 62.5 J 165.00 196.00 48.3 J 161.00 103.00 121.00 Dry 268.00 75.1 J May-2009 0.04 26 J 1.8 J 6.9 J 266.00 117.00 56.10 31 J 113.00 181.00 61.6 J 78.7 J Aug-2009 Begin Assessment + Phase 2 2.06 701 B 125 B 127 B Jan-2010 2000 700 0.04 77.4 J 15.4 J 492.00 84.2 J 165.00 83.8 J 137.00 29.1 J 169.00 89.2 J 71.3 J 76.1 J 70.9 J May-2010 0.03 23.5 J 47.5 J 527.00 42.7 J 202.00 92.1 J 215.00 266.00 140.00 33.3 J 79.4 J 69.2 J 82.1 J Nov-2010 0.03 56.6 J 149.00 254.00 100.00 141.00 129.00 155.00 34.3 J 164.00 49.8 J 59.11 75.5 J 94.2 J May-2011 0.02 36 J 101.00 242.00 36 J 174.00 80.5 J 124.00 174.00 124.00 70.8 J 71.6 J 77.8 J 137.00 Nov-2011 0.02 Damaged 58.7 J 2.0 J 34.3 J 7.6 J 484.00 70.7 J 183.00 150.00 157.00 67.4 J 184.00 48.7 J 69.4 J 73.3 J 81.2 J May-2012 0.07 68.3 J 166.00 342.00 86.6 J 278.00 122.00 128.00 294.00 142.00 78.8 J 84.8 J 60.8 J 74.3 J Nov-2012 0.07 Damaged 37.1 J 1.8 J 152.00 7.0 J 425.00 120.00 151.00 117.00 53.4 J 100.00 133.00 38.0 J 49.1 J 74.1 J 70.6 J May-2013 0.06 Damaged 73.9 J 16.5 J 80.2 J 7.8 J 288.00 62.5 J 108.00 115.00 209.00 560.00 144.00 50.2 J 64.6 J 30.3 J Dry Nov-2013 Not Sampled May-2014 21000 0.12 20.3 J 33.0 J 343.00 28.6 J 80.2 J 67.9 J 110.00 291.00 157.00 29.3 J 58.9 J 18.3 J 368.00 52.4 J 90.9 J 88.7J 136.0 94.3 J 72.9 J 37.9 J Dry Nov-2014 0.01 64.5 J 273.00 675.00 123.00 7.3 J Damaged 246.00 398.00 189.00 32.1 J 100.00 19.7 J 515.00 69.9 J 207.00 86.6 J 57.7 J 46.6 J Dry May-2015 0.01 71.1 J 19.9 J 6.1 J 34.3 J 10.8 J 412.00 17.9 J 151.00 130.00 271.00 819.00 202.00 25.8 J 63.2 J 24.4 J 292.00 57.1 J 10.7 J 54.3 J 57.6 J 59.7 J 54.2 J 78.3 J Nov-2015 0.02 21.4 J 34.6 J 625.00 145.00 109.00 233.00 131.00 294.00 131.00 54.3 J 119.00 21.3 J 69.2 J 57.7 J 93.8 J 55.8 J 44.7 J 63.2 J 74.0 J May-2016 0.02 24.6 J 89.5 J 648.00 78.9 J 68.11 DRY 561.00 751.00 325.00 51.0 J 344.00 23.6 J 550.00 46.2 J 52.1 J 56.3 J 51.8 J 75.1 J 76.1 J Nov-2016 0.02 49.4 J 55.2 J 945.00 198.00 123.00 DRY 336.00 411.00 285.00 45.3 J 260.00 31.3 J 654.00 53.1 J 73.1 J 50.0 J 65.8 J 99.1 J Dry 0.07 74.6J 31.4 J 15.iJ 39.9 J 11.8J 515.00 191.00 149.00 187.00 98.1 J 367.00 340.00 39.0 J 200.00 20.3 J 507.00 36.3 J 9.90J 75.0 J 128.00 77.5 J 65.7 J 83.3 J 0.07 115.00 25 J 16.7 J 281.00 11.1 J 709.00 253.00 68.7 J 76.1 J 633.00 312.00 323.00 68.4 J 184.00 42.4 J 541.00 56.3 J 10.9 J 92.0 J 134.0 251.0 84.2 J Dry 54.4 J 79.0 J 83.0 J 0.03 35.60 33.70 19.80 J 62.60 J 11.40 J 879.00 56.10 J 93.20 J 82.50 J 348.00 132.00 328.00 56.80 161.00 78.30 466.00 38.70 10.20 65.0099.5 196 89.1 Dry 58.30 117.00 Dry Nay201187 35.50 38.50 15.60 135.00 10.10 J 689.00 312.00 525.00 140.00 470.00 566.00 358.0048.80 368.00 55.00 398.00 47.50 8.50 J 49.30 95.231.30 15.20 94.70920 J 502.00 238.00 167.00 280.00 776.00 524.00 608.004770321.00 72.20 759.0045.80 10.00 98.90 25.00 43.00 13.00 331.00 8.00 J 650.00 299.00 7; 119.00 535.00 234.00 475.00 62.00 267.00 131.00 589.00 77.00 9.00 J 32.20 255 394 49.20 1725.00 48.40 155.00 60.00 19.80 0.00 331.00 0.00 394.00 0.00 945.00 0.00 312.00 0.00 525.00 0.00 280.00 0.00 776.00 0.00 819.00 0.00 608.00 0.00 62.00 0.00 368.00 0.00 131.00 0.00 759.00 0.00 106.00 0.00 10.20 0.00 223.00 0.00 255.00 0.00 418.00 0.00 256.00 0.00 0.00 1725.00 0.00 268.00 0.00 571.00 0.00 137.00 0.00 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyle detected above Method Detection Limit. 12. Bold red font indicates analyle detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyle detected above 21- Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 3 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Beryllium CAS No. 744041-7 sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Asst. BG Asst. old B-20 Fac. BG BG BG Date MCL IMAC 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MW-7 MIN-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MIN-15 MW-16 MW-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 NO NO NO 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U NO NO NO 0.44 U 0.44 U10-44 0.44 U 0.44 U 0.44 U 0.44 U 0.2J 0.2J 0.06U 0.3J O.06U O.6J 10 0.3J 0.02 U 0.1 1 0.11 0.3 J 0.1 1 0.02 U 0.1 1 0.11 0.3 J 0.2 J 0.02 U 0.29 J 0.02 U 0.12 J 0.2 J 0.02 U 0.16 J 0.02 U 0.14 J 0.02 U 0.29 J 0.07 U 0.09 J 0.07 U 0.12 J 2.00 0.07 U 0.08 J 0.07 U 0.13 J 0.07 U 0.39 J 0.Z U 0.08 J 0.03 J 0.12 J 0.03 U 0.48 J NO NO Nov-01 NO NO NO NO NO NO NO NO May-02 NO NO NO NO NO NO NO Nov-02 NO NO NO NO NO NO NO NO NO NO May-03 NO NO NO 2.00 NO NO NO NO NO NO NO Nov-03 NO NO NO NO NO NO NO NO NO NO NO May-04 NO NO NO NO NO NO NO NO NO NO Nov-04 NO NO NO NO NO NO NO NO NO NO May-05 Damaged NO NO NO NO NO NO NO NO NO NO Nov-05 NO NO NO NO NO NO NO NO NO NO May-06 Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.08 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 6.5 Nov-2007 0.06 E 0.6 J 0.06 U 0.8 J 0.11 0.9 J 0.11 0.11 Dry 0.06 U 0.11 May-2008 0.06 0.06 U 1.00 0.06 U 0.11 0.4 J 0.11 0.1 J 0.11 0.11 Nov-2008 0.06 E 0.7 J 0.06 U 0.2 J 0.1 J 0.11 0.11 0.06 U Dry 0.4 J 0.11 May-2009 0.06 2.60 0.06 U 0.06 U 0.9 J 0.5 J 0.11 0.11 0.06 U 0.6 J 0.06 U 0.11 Aug-2009 Begin Assessment + Phase 2 0.44 0.44 U 0.44 U 0.44 U Jan-2010 4 4 0.06 0.2J 0.91 O.06U 0.11 1.00 1.00 0.11 0.06U 0.11 0.2J O.06U 0.2J 0.11 May-2010 0.02 0.51 0.11 0.02 U 0.02 U O.81 0.51 0.11 0.11 0.4 J 0.11 0.11 0.11 0.11 Nov-2010 0.02 0.3 J 0.11 0.11 0.11 0.7 J 1.00 0.11 0.11 0.2 J 0.11 0.11 0.11 0.11 May-2011 0.02 0.16 J 0.1J 0.02 U 0.02 U 0.57 J 0.92 J 0.02 U 0.02 U 0.06 J 0.12 J 0.06 J 0.02 U 0.57 J Nov-2011 0.02 Damaged 0.26 J 0.02 U 0.07 J 0.02 U 0.02 U 0.02 U 0.65 J 0.24 J 0.06 J 0.06 J 0.24 J 0.02 .09 J 0.10 J May-2012 007 0.19 J 017 J 0.07 U 0.07 U 0.50 J 0.50 J 0.07 U 0.07 U 0.13 J 0.19 .07 U 0.15 J0.07 Damaged 0.18 J 0.07 U 0.09 J 0.07 U 0.07 U 0.07 U 0.47 J 0.13 J 0.09 J 0.07 U 0.09 J 0.07 M .07 U 112J 3 Damaged 0.04 J 0.03 J 0.10 J 0.03 U 0.09 J 0.03 U 0.03 U 0.23 J 0.16 J 0.03 U 0.03 U 0.12 .11 J Dry Nov-2013 Not Sampled May-2014 0.03 0.03 U 0.06 J 0.03 U 0.03 U 0.23 J 0.03 U 0.05 J 0.04 J 0.12 J 0.03 U 0.04 J 0.03 U 0.03 U 0.04 J 0.03 U 0.42J 0.13J 0.16 J 0.04 J 0.04 J Dry Nov-2014 0.04 0.04 U 0.111 0.04 U 0.04 U 0.04 U Damaged 0.04 U 0.04 U 0.04 J 0.04 U 0.04 J 0.24 J 0.04 U 0.08 J 0.08 J 0.04 U 0.04 U 0.08 J Dry May-2015 0.02 0.02 U 0.03 J 0.02 U 0.08 J 0.02 U 0.04 J 0.02 U 0.55 J 0.02 U 0.15 J 0.06 J 0.26 J 0.02 U 0.04 J 0.18 J 0.02 U 0.02 U 0.02 U 0.04 J 0.06 J 0.05 J 0.111 0.04 J Nov-2015 0.02 0.04 U 0.07 J 0.04 J 0.04 J 0.30 J 0.08 J 0.05 J 0.05 J 0.02 U 0.02 U 0.05 J 0.06 J 0.04 J 0.03 J 0.48 J 0.02 U 0.03 J 0.13 J 0.09 J May-2016 0.04 0.07 J 0.08 J 0.06 J 0.05 J 0.18 J DRY 0.07 J 0.07 J 0.06 J 0.04 U 0.05 J 0.05 J 0.04 U 0.06 J 0.13 J 0.04 U 0.04 U 0.10 J 0.04 U Nov-2016 0.04 0.051 0.04 U 0.14 J 0.081 0.15 J DRY 0.13 J 0.101 0.24 J 0.04 U 0.101 0.12 J 0.101 0.04 U 0.061 0.051 0.04 U 0.091 Dry May-2017 0.07 0.071J 0.071.1 0.071J 0.071.1 0.071J 0.08 J 0.09 J 0.17 J 0.46 J 0.18 J 0.07 J 0.18 J 0.071J 0.071J 0.071J 0.071J 0.071J 0.071J 0.10 J 0.07U 0.071J 0.071J 0.07U Deo-2017 0.07 0.07 J 0.07 U 0.07 U 0.18 J 0.07 U 0.08 J 0.07 J 0.311 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.09 J 0.07 U 0.07 U 0.07 U 0.32 J 0.33 J 0.16 J 0.311 Dry 0.07 U 0.071J 0.071J Jun-2018 0.05 -- U 0.05 J 0.10 J 0.06 J 0.06 J -- U 0.12 J 0.26 J 0.13 J -- U -- U 0.09 J -- U 0.06 J 0.10 J 0.07 J 0.06 J -- U -- U 0.27 J 0.07 J 0.16 J Dry 0.05 J 0..09 J Dry Deo-2018 0.05 -- U -- U -- U -- U -- U -- U -- U 0.10 J -- U -- U 0.07 J 0.06 J -- U 0.05 J -- U -- U -- U -- U -- U 0.05 J 0.09 J 0.05 J J-U 0.05 J 0.11 JJun-2019 005 -- U -- U -- U 005 J -- U 0.06 J 0.06 J 01 J 0.09 J 0.07 J 0.06 J 0.08 J -- U 0.12 J 0.22 J 008 J 0.06 J -- U 0.07 J 0.11 J 0.16 J -- U �S3 J 0.08 J 0.12 J 0.12 J Deo-2019 Effective 11/1/2019 6.5 0.05 0.38 J 0.42 J 0.32 J -- U -- U -- U -- U 0.36 J -- U -- U -- U -- U -- U 0.02 J 0.04 J -- U -- U -- U 0.02 J 0.12 J 0.05 J 0.04 J 1 -- U 0.28 J 0.06 J NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyle detected above Method Detection Limit. 12. Bold red font indicates analyle detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyle detected above 21- Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity 1.00 0.00 0.08 0.00 0.28 0.00 0.12 0.00 Page 4 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Cadmium CAS No. 744043-9 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Asst. BG Asst. old B-20 Fac. BG BG BG Data MCL 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW4 MW-5 MW-6 MIN-7 MIN-8 MW-9A MIN-10 MIN-11 MW-12S MW-13 MW-14D MW-14S MIN-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 1.75 NO NO NO 0.51 0.7 J 0.1 1 1.00 0.04 U 0.04 U 0.1 J 0.11 NO NO NO 0.16 J 0.17J 0.31 0.158 U 0.16 J 0.4 J 0.23 J 0.11 0.04U 0.2J 0.2J 0.2J 1.00 0.2J 1 2.0 1 1 0.1J 0.2J 1.00 0.11 0.2J 0.4J 0.11 0.11 0.11 0.2J 0.11 0.2J 0.3J 0.051 0.81 0.17 J 0.11 0.161 0.12 J 0.08 J 0.08 J 0.13 J 0.06 J 0.13 J 0.43 J 0.29 J 0.14 J 0.051 0.22 J 0.05 J 0.18 J 0.18 J 0.04 J 0.08 J 0.64 J 0.13 J 0.12 J 0.43 J 0.36 J 0.64 J 0.06 J 0.97 J 0.68 J 0.21 J 2.00 0.18 J NO NO Nov-01 NO NO NO NO NO NO NO NO May-02 NO NO NO NO NO NO NO Nov-02 NO NO NO NO NO NO NO NO NO NO May-03 NO NO NO NO NO NO NO NO NO NO NO Nov-03 NO NO NO NO NO NO NO NO NO NO NO May-04 NO NO NO NO NO NO NO 4.000 NO NO Nov-04 NO NO NO NO NO NO NO NO NO NO May-05 Damaged NO NO NO NO NO NO NO NO NO NO Nov-05 NO NO NO NO NO NO NO 1.000 NO NO May-06 Damaged NO NO NO NO NO NO NO 1.00 3.000 NO NO Nov-06 1.00 1.00 NO NO NO 1.00 NO 5.000 2.000 1.000 May-07 Mandated Analytical Changes 0.06 1.00 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 1.000 2 Nov-2007 0.06 E 0.7 J 0.3 J 0.5 1 0.61 0.61 0.4 J 0.3 J Dry 0.11 0.2 J May-2008 0.04 0.1 1 0.6 J 0.351 0.11 0.2 J 0.1 1 0.4 J 0.04 U Nov-2008 0.04 E 0.3 J 0.11 0.3 J 0.04 U 0.4 J 0.04 U 0.1 J Dry 0.3 J 0.04 U May-2009 0.04 2.30 3.60 0.04 U 0.9 J 0.3 J 0.9 J 0.8 J 0.2 J 0.7 J 0.04 U 0.04 U Aug-2009 Begin Assessment + Phase 2 0.16 0.16 J 0.18 J 0.3 J Jan-2010 5 2 0.04 0.2J 0.4J 0.04U 0.2J 0.3J 0.61 0.3J 0.2J 0.2J 1.90 1.20 0.3J 0.11 May-2010 0.02 0.2J 0.81 0.3J 0.11 1.20 0.3J 2.20 2.00 0.2J 0.2J 0.11 0.11 0.11 Nov-2010 0.02 0.2J O.6J 0.11 0.11 0.51 2.00 0.61 0.4J 0.3J 0.11 0.11 0.11 0.2J May-2011 0.02 0.11 1 0.29 J 0.07 J 0.1 J 0.351 0.64 J 0.43 J 0.4 J 0.061 0.22 J 0.111 0.29 J 0.14 J Nov-2011 0.02 Damaged 0.37 J 0.09 J 0.17 J 0.24 J 0.12 J 0.36 J 0.43 J 0.69 J 0.29 J 0.38 J 0.13 J 0.02 J 0.02 J 0.14 J 0.05 J May-2012 0.03 0.03 U 0.25 J 0.04 J 0.081 0.16 J 0.22 J 0.27 J 0.12 J O.O6 J 0.17 J 0.03 U 0.03 U 0.03 U Nov-2012 0.03 Damaged 0.16 J 0.03 J 0.18 J 0.03 U 0.05 J 0.34 J 0.22 J 0.12 J 0.12 J 0.16 J 0.04 J 0.07 J 0.03 J 0.04 J 0.07 J May-2013 0.05 Damaged 0.15 J 0.39 J 0.29 J 0.48 J 0.11 J 0.07 J 0.09 J 0.20 J 0.31 J 0.14 J 0.13 J 0.08 J 0.05 J 0.08 J Dry Nov-2013 Not Sampled May-2014 Water Dissolved Effects Ratio' metals Hardness dependent 'WER 0.04 0.11 J 0.14 J 0.19 J 0.15 J 0.08 J 0.05 J 0,311 0.29 J 0.39 J 1.00 0.17 J 0.25 J 0.09 J 1.00 2.00 0.20J 0.14J 0.22 J 0.05 U 0.05 U Dry Nov-2014 0.01 0.12 J 0.44 J 0.17 J 0.12 J 0.04 U Damaged 0.20 J 0.26 J 0.08 J 0.311 0.21 J 0.58 J 0.26 J 0.18 J 0.26 J 0.05 J 0.04 J 0.04 J Dry May-2015 0.01 0.85 J 0.13 J 0.23 J 0.13 J 0.18 1 0.03 J 0.011 0.33 J 0.62 J 0.48 J 0.44 J 0.101 0.101 0.081 0.33 J 0.091 0.101 0.50 1 0.861 0.07 J 0.02 J 0.03 J 0.03 1 Nov-2015 0.05 0.08 J 0.26 J 0.04 J 0.15 J 0.21 J 0.38 J 0.45 J 0.35 J 0.12 J 0.18 J 0.62 J 0.45 J 1.00 1.00 0.66 J 0.04 J 0.04 J 0.07 J 0.08 J May-2016 0.05 0.12 J 0.10 J 0.05 U 0.07 J 0.08 J DRY 0.48 J 0.15 J 0.05 U 0.12 J 0.13 J 0.16 J 0.14 J 0.23 J 0.44 J 0.05 U 0.05 U 0.05 U 0.05 U Nov-2016 0.05 0.13 J 0.10 J 0.05 U 0.08 J 0.09 J DRY 0.18 J 0.30 J 0.20 J 0.13 J 0.09 J 0.50 J 0.15 J 0.05 J 0.29 J 0.05 U 0.05 U 0.05 U Dry May-2017 0.08 0.60J 0.1J 0.23J 0.13J 0.40J 0.08U 0.08U 0.091 0.881 0.25J 0.1J 0.11J 0.08U 0.1"0.151 0.08U 0.08U 0.25J 0.611 0.08U 0.081.1 0.081.1 0.08U Deo-2017 0.08 0.55 J 0.08 U 0.08 U 0.17 J 0.08 U 0.08 U 0.09 J 0.111 0.08 U 0.08 U 0.09 J 0.08 U 0.09 J 0.15 J 0.08 U 0.15 J 0.08 U 0.19 J 0.44 J 0.12 J 0.21 J 0.08 U Dry 0.08U 0.08U 0.08U Jun-2018 0.02 0.27 J 0.05 J 0.09 J 0.06 J 0.26 J -- U 0.06 J 0.09 J 0.12 J 0.15 J 0.06 J 0.06 J 0.04 J 0.04 J 0.08 J 0.13 J 0.04 J 0.22 J 0.10 J 0.17 J 0.13 J 0.11 J Dry -- U 0.03 J Dry Deo-2018 0.02 0.11 J 0.14 J -- U 0.11 J -- U 0.11 J 0.04 J 0.14 J 0.08 J 0.17 J 0.16 J 0.08 J 0.02 J 0.14 J 1.00 J -- U 0.06 J 0.06 J 0.07 J 0.08 J 0.15 J 0.04 J 0.51 J -- U 0.02 J 0.04 J Jun-2019 0.02 -- U 0.07 J -- U 0.05 J -- U -- U -- U 0.07 J 0.14 J 0.13 J -- U -- U -- U 0.11 J 1.20 J -- U 0.05 J 0.06 J 0.05 J 0.07 J 0.13 J 0.04 J 0.06 J 0.02 J 0.03 J -- U Deo-2019 EffecOve it/1/2019 0.15 0.04 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U 0.05 J -- U -- U -- U 0.06 J -- U -- U -- U -- U 2.00 -- U 0.12 J -- U NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyle detected above Method Detection Limit. 12. Bold red font indicates analyle detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyle detected above 21- Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity 5.00 0.00 2.00 0.00 1.00 0.00 0.04 0.00 Page 5 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Chromium CAS No. 744047-3 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Asst. BG Asst. old B-20 Fac. BG BG BG Date MCL 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MIN-6 MIN-7 MIN-8 MW-9A MW-10 MIN-11 MW-12S MW-13 MW-14D MW-14S MIN-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 NO 29.00 NO 0.24 U 1.2 J 1.51 0.2J 0.11 U 1.4 J 0.10U 1.61 NO NO NO 3 JB 3 JB 3.09 JB 2.48 JB 1.77 JB 4.24 JB 2.8 JB 2.7J 0.91 0.10U 0.10U 0.7J 1.81 2.6J 3.3J 1.5J 0.3J 0.61 0.3J 0.61 0.81 0.51 0.03U 0.11 0.11 1.7J 0.91 0.51 0.17 J 0.83 J 0.23 J 2.6 J 0.51 J 0.48 J 0.23 J 0.86 J 0.04 J 14.00 0.57 J 0.04 U 1.3 J 0.18U 0.501 0.18U 6.5J 0.61J 2.0J 0.18 U 0.801 0.25 J 16.00 0.68 J 0.4 J 1.2 J 0.131 1.1 1 0.78 J 19.00 0.59 J 0.27 J 5.8 1 NO NO Nov-01 83.00 NO NO 29.00 NO 15.00 NO NO May-02 NO 85.00 42.00 NO NO NO NO Nov-02 NO 69.00 13.00 NO NO NO NO NO NO NO May-03 NO 24.00 NO NO NO NO NO NO NO NO NO Nov-03 22.00 15.00 NO NO NO 11.00 NO 122.00 NO NO NO May-04 NO 42.00 12.00 NO 11.00 NO 10.00 NO NO NO Nov-04 NO 33.00 25.00 NO 22.00 NO 25.00 NO NO NO May-05 Damaged NO 33.00 30.00 NO 20.00 NO NO NO NO NO Nov-05 NO 15.00 NO NO 11.00 40.00 NO NO NO NO May-06 Damaged NO 11.00 ND NO NO NO NO NO NO NO NO Nov-06 NO ND NO NO 12.00 NO NO NO NO NO May-07 Mandated Analytical Changes 0.24 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U Nov-2007 0.24 E 0.3 J 0.5 J 2.7 J 0.4 J 13.00 1.3 J 1.0 J Dry 1.5 J 0.24 U May-2008 0.11 0.3J 0.2J 0.3J O.6J 1.2J 1.2J 3.11 1.11 1.11 8.01 1.11 0.4J Nov-2008 0.11 E 0.51 1.7 J 1.0 1 1.11 4.7 J 1.11 0.4 J Dry 5.O 1 0.3 J May-2009 0.10 0.10U 1.7J 0.7J 2.1J 0.7J 2.5J 0.51 0.1J 5.iJ 0.51 0.51 Aug-2009 Begin Assessment+ Phase 2 1.46 8.8 JB 3.36 JB 4.76 JB Jan-2010 100 10 0.10 0.10U 0.10U 11 0.10U 2.8J 2.7J 0.81 0.10U 0.10U 2.iJ 0.7J 0.4J 0.3J May-2010 0.03 0.51 0.7J 2J 0.11 2.1J 2.3J 4.2J 2.5J 0.81 0.4J 0.91 0.4J 0.91 Nov-2010 0.03 0.51 0.61 1.7J 0.3J 3.11 11.00 2J 0.4J 0.81 0.51 0.51 0.2J 0.3J May-2011 0.04 0.44 J 0.62 J 0.76 J 0.3 J 3 J 6.2 J 2.4 J 1.2 J 0.84 J 1.81 0.581 0.991 3.1 J Nov-2011 0.04 Damaged 0.66 J 0.04 U 0.29 J 0.15 J 1.7 J 0.67 J 3.7 J 9.5 J 2.7 J 0.92 J 2.1 J 0.74 J 1.2 J 0.63 J 0.46 J May-2012 0.18 0.91J 1.7J 1.0J 1.51 5.7J 6.11 2.5J 2.0J 1.7J 2.6J 1.4J 0.38J 1.001 Nov-2012 0.18 Damaged 0.45 J 0.18 U 1.9 J 0.18 U 1.5 J 2.31 3.61 5.2 J 1.81 1.51 3.O J 0.54 J 0.545 J 0.181 1.1 1 May-2013 0.04 Damaged 0.50 J 0.7 J 0.57 J 0.38 J 0.50 J 1.0 1 2.2 J 4.8 J 3.2 J 7.4 J 2.2 1 2.4 J 1.6 J 1.6 J Dry Nov-2013 Not Sampled May-2014 W ER 0.14 0.45 J 0.81 1 1.8 1 0.29 J 1.9 1 3.1 1 0.381 6.1 J 3.8 J 0.04 U 0.83 1 0.20 J 9.0 1 0.46 J 2.1 J 2.9J 1.51 1.9 1 0.951 0.51 1 Dry Nov-2014 0.12 1.6 J 3.5 J 5.11 2.8 J 0.14 U Damaged 2.6 J 11.00 5.8 J 0.14 U 1.11 0.34 J 21.00 0.35 J 14.00 0.98 J 0.81 J 0.14 U Dry May-2015 0.12 0.24J 0.17J 0.31J 0.14J 0.40J 2.6J 0.12U 3.0J 9.3J 0.861 18.00 2.9J 0.181 1.4J 1.11 8.91 0.63J 0.12U 0.82J 1.2J 1.11 1.2J 0.951 Nov-2015 0.06 0.12U 1.2J 7.3J 5.11 3.3J 9.8J 1.3J 9.91 1.3J 0.12U 1.7J 0.65J 2.7J 0.42J 8.4J 0.86J 0.43J 0.851 0.531 May-2016 0.06 0.52 J 0.70 J 9.8 J 1.0 J 1.9 J DRY 4.0 J 18.00 8.7 J 0.08 J 9.2 J 0.85 J 27.00 0.811 3.0 J 1.6 J 0.80 J 1.11 0.71 J Nov-2016 0.06 0.53 J 0.37 J 18.00 4.1 J 2.0 J DRY 4.8 J 8.8 J 9.3 J 0.06 U 11.00 0.43 J 28.00 0.26 J 1.2 J 0.95 J 1.0 J 0.61 J Dry May-2017 0.08 0.13J 0.17 J 0.63J 0.82 J 0.581 13.00 8.7 J 2.0 J 13.00 3.4 J 8.9 J 12.00 0.08U 12.00 0.08U 28.00 0.15 J 0.08U 2.1 J 1.3 J 0.46 J 0.08U 3.1 J Da 2017 0.08 2.1J 0.11J 0.57J 7.6J 0.08U 17.00 10.00 3.2J 6.7J 7.7J 8.2J 17.00 0.36J 4.7J 0.81 31.00 0.4J 0.081 9.1J 2.9J 6.9J 2.4J Dry 0.64J 0.4J 0.081 Ju-218 0.15 -- U -- U 2.00 J 0.43 J 4.60 J 24.00 2.50 J 2.40 J 4.50 J 1.30 J 2.70 J 3.90 J -- U 4.10 J 1.30 J 26.00 -- U -- U 0.84 J 2.6 J 2.5 J 2.9 J Dry -- U 1.20 J Dry Deo-2018 0.15 1.40 J 0.77 J 0.35 J 3.00 J 0.08 J 32.00 13.00 4.40 J 3.30 J 4.30 J 12.00 15.00 -- U 14.00 0.56 J 24.00 0.31 J -- U 0.48 J -- U 1.5 J 0.94 J 0.53 J 0.37 J 0.60 J Jun-2019 jiD.n.20019 0.15 -- U 0.18 J 0.09 J 1.30 -- U 2.90 6.00 0.57 J 4.00 3.50 8.00 3.80 0.11 J 1.90 0.90 J 3.20 0.75 J 0.01 J 0. is J 0.26 J 0.94 J 0.20 J �6J 0.33 J 0.67 J 0.36 J Effective it/1/2019 24 0.15 1.30 J 3.00 J 4.00 J 5.70 1.00 J 25.00 15.00 3.00 J 11.00 1.20 15.00 23.00 -- U 21.00 -- U 44.00 -- U -- U 1.10 J -- U 5 1.20 J -- U -- U -- U 29.00 0.00 85.00 0.00 4.60 0.00 32.00 0.00 15.00 0.00 42.00 0.00 13.00 0.00 22.00 0.00 40.00 0.00 122.00 0.00 0.11 0.00 21.00 0.00 1.30 0.00 44.00 0.00 0.75 0.00 0.01 0.00 14.00 0.00 2.60 0.00 5.00 0.00 2.90 0.00 0.00 61.00 0.00 0.53 0.00 1.20 0.00 0.60 0.00 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyle detected above Method Detection Limit. 12. Bold red font indicates analyle detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyle detected above 21- Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 6 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Cobalt CAS No. 744048-4 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Asst. BG Asst. old B-20 Fac. BG BG BG Data IMAC 21- Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MW-15 MW-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 -- NO NO NO 0.41 U 9.4 J 13.00 0.11 0.11 17.00 0.11 12.60 NO NO NO 1.72 U 1.72 U 1.72 U 1.72 U 1.72 U 1.72 U 1.72 U 0.7J 0.3J 0.51 0.2J 1.3J 0.2J 0.4J 1.2J 0.3J 0.2J 0.2J 0.3J 0.2J 0.91 0.2J 0.2 J 0.3 J 0.3 J 0.81 1.O 1 0.3 J 0.091 2.2 J 0.26 J 1.51 1.2 J 0.181 0.111 0.26 J 0.20 J 0.84 J 0.60 J 0.08 J 0.42 J 0.06 J 0.45 J 0.22 J 0.72 J 1.5 J 3.4 J 0.08 J 0.86 J 0.53 J 1.11 0.46 J 0.10 J 1.6 J 0.04 J 0.33 J 0.73 J 0.88 J 0.47 J 0.04 J 2.4 J NO NO Nov-01 NO NO NO NO NO NO NO NO May-02 NO NO NO NO NO NO NO Nov-02 NO 19.00 NO NO NO NO NO NO NO NO May-03 NO NO 16.00 NO NO 11.00 17.00 NO NO NO NO Nov-03 NO NO NO NO NO 52.00 NO NO NO NO NO May-04 NO NO NO NO 23.00 NO NO NO NO NO Nov-04 NO 11.00 NO 21.00 NO NO NO NO NO NO May-05 Damaged NO NO NO 12.00 15.00 NO NO NO NO NO Nov-05 NO 13.00 NO 29.00 NO NO NO NO NO NO May-06 Damaged NO NO NO NO 17.00 11.00 NO NO NO NO NO Nov-06 NO NO NO NO NO NO 43.00 NO NO NO May-07 Mandated Analytical Changes 0.41 0.41 U 0.41 U 0.41 U 0.41 U 0.41 U 0.41 U 0.41 U 12.00 38.00 0.41 U 0.41 U 0.41 U 4 Nov-2007 0.41 E 1.5 J 9.3 J 1.0 J 2.3 J 6.3 J 17.00 0.41 U Dry 0.8 J 0.7 J May-2008 0.03 0.1 J 0.8 J 0.1 J 1.3 J 1.0 J 1.7 J 1.7 J 2.6 J 19.00 1.2 J 0.8 J 1.0 J Nov-2008 0.03 E 0.9 J 10.00 0.4 J 0.5 J 4.4 J 2.8 J 12.00 Dry 1.9 J 5.11 May-2009 0.02 1.2J 0.4J 5.81 1.3J 1.2J 1.11 2.3J 8.4J 1.01 0.4J 1.3J Aug-2009 Begin Assessment + Phase 2 1.72 10.60 19.90 12.30 Jan-2010 1 0.02 2.5J 0.4J 5.7J 15.00 0.91 1.61 0.61 1.11 10.00 0.61 0.3J 1.2J 0.2J May-2010 0.10 0.7J 1.11 18.00 3.8J 0.91 2.8J 5.4J 9.01 21.00 0.3J 0.61 0.61 0.51 Nov-2010 0.10 0.81 3.3 J 37.00 17.00 1.11 7.8 J 0.7 J 0.81 24.00 0.4 J 0.51 1.O 1 0.7 J May-2011 0.03 0.41 J 3.7 J 14.00 7.7 J 0.581 1.51 1.41 4.2 J 31.00 0.84 J 1.51 0.42 J 1.61 Nov-2011 0.03 Damaged 0.48 J 0.03 U 1.11 0.05 J 6.8 J 15.00 0.76 J 1.6 J 1.11 1.2 J 17.00 0.50 J 0.75 J 1.3 J 0.86 J May-2012 0.02 0.38 J 7.0 J 2.6 J 25.00 0.63 J 1.7 J 1.3 J 3.6 J 31.00 0.89 J 0.79 J 0.76 J 0.72 J Nov-2012 0.02 Damaged 0.31 J 0.04 J 8.6 J 0.03 J 15.00 28.00 0.38 J 1.1 J 0.55 J 1.3 J 27.00 0.42 J 0.31 J 0.89 J 1.7 J May-2013 0.02 1 Damaged 0.20 J 0.26 J 2.0 J 0.08 J 2.2 J 18.00 0.35 J 1.6 J 3.0 J 9.2 J 24.00 0.73 J 0.52 J 0.48 J Dry Nov-2013 Not sampled May-2014 16 0.12 0.13 J 1.0 J 5.9 J 0.28 J 0.30 J 0.34 J 0.22 J 5.2 J 22.00 0.05 J 0.44 J 0.19 J 0.82 J 0.32 J 0.24 J 0.3 T0.33J 0.38 JEO.20 0.31 J Dry Nov-2014 0.03 0.33 J 5.6 J 2.6 J 15.00 0.13 J Damaged 2.8 J 5.0 J 12.00 0.12 U 0.49 J 0.66 J 1.1 J 0.47 J 1.8 J 0.41 J 0.75 J Dry May-2015 0.03 0.22 J 0.44 J 0.04 J 0.29 J 0.051 0.89 J 0.12 J 0.80 J 2.6 J 0.911 18.00 14.00 0.06 J 0.31 J 0.43 J 0.811 0.28 J 0.05 J 0.79 J 0.33 J 0.48 J 0.34 J Nov-2015 0.04 0.30 J 0.39 J 2.7 J 11.00 1.3 J 1.5 J 1.11 4.1 J 4.0 J 0.10 J 0.38 J 0.52 J 0.30 J 0.35 J 1.6 J 0.26 J 0.74 J 0.26 J May-2016 0.04 0.20 J 0.49 J 3.1J 7.6 J 0.38 J DRY 4.5 J 16.00 11.00 0.07 J 0.92 J 0.30 J 1.7 J 0.26 J 0.61J 0.27 J 0.72 J 0.18 J Nov-2016 0.04 0.31 J 1.7 J 3.O J 6.2 J 0.331 DRY 2.5 J 3.3 J 9.81 0.113 J 1.O 1 0.70 J 2.O J 0.94 J 1.3 J 0.34 JJ 0.47 J Dry May-2017 0.24 0.38J 0.24U 0.24U 1.1J 0.24U 2.5 J 8.6 J 0.36 J 2.9 J 1.4 J 8.3 J 8.0 J 0.24U 0.87 J 0.28 J 1.8 J 0.50 J 0.24 U 0.74 J 0.35 JJ 0.36 J 0.47 J Deo-2017 0.24 0.57 J 0.24 U 0.24 U 4.1 J 0.24 U 3.9 J 9.51 0.511 0.99 J 2.9 J 3.5 J 3.3 J 0.29 J 0.561 0.73 J 2.O J 0.37 J 0.24 U 1.61 0.36 J 0.861 DryJ 0.51 J 0.24 U Jun-2018 0.03 0.22 J 0.20 J 0.51 J 1.10 J 026 J 4.70 J 2.10 J 0.46 J 1.10 J 1.60 J 2.40 J 3.20 J 0.21 J 0.42 J1.40 J 1.90 J 0.85 J 0.09 J 0.59 J 0.33 J 0.55 J Dry J 0.65 JDry Deo-2018 0.27 J 0.27 J 0.12 J 1.40 0.08 J 3.00 J 8.30 0.22 J 1.20 2.90 12.00 3.40 0.12 J 1.80 1.00 J 1.60 0.54 J 0.07 J -- U 0.15 J 0.53 J 0.79 J 0.32 J 0.62 J Jun-2019 0.07 J 0.37 J -- U 2.00 J -- U 24.00 J 9.30 3.80 J 7.50 7.10 14.00 21.00 -- U 19.00 0.77 J 55.00 0.30 J -- U 2.00 J 0.46 J 2.9 J 5.1 0.74 J 2.5 J 0.72 J Deo-2019 0.32 0.76 J -- U 1.00 3.40 1.00 6.00 J 7.00 0.82 J 2.00 4.00 4.00 4.10 0.51 J 2.60 2.40 J 3.30 0.49 J 0.14 J 1.80 0.71 J 0.9 J 8.9 0.26 J 8.4 J 0.44 J 0.76 0.00 0.37 0.00 1.00 0.00 19.00 0.00 13.00 0.00 37.00 0.00 28.00 0.00 3.80 0.00 29.00 0.00 52.00 0.00 18.00 0.00 43.00 0.00 0.51 0.00 19.00 0.00 2.40 0.00 55.00 0.00 0.85 0.00 0.14 0.00 2.00 0.00 0.71 0.00 2.90 0.00 0.80 0.00 0.00 8.90 0.00 0.74 0.00 8.40 0.00 0.72 0.00 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyle detected above Method Detection Limit. 12. Bold red font indicates analyle detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyle detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 7 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Copper CAS No. 7440-50-8 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Asst. BG Asst. old B-20 Fac. BG BG BG Data MCL 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MW-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 1000 NO NO NO 1.30 1.80 1.30 0.80 1.30 1.30 0.70 1.40 NO NO NO 2.13 J 2.34J 2.44J 1.86J 1.33 J 1.29 U 1.34 J 1.3J 1.01 0.81 0.7J 1.2J 2.4J 2.4J 4.8J 1.5J 0.11 0.61 0.2J 0.3J 0.51 0.11 0.03 U 0.03 U 0.03 U 1.1 1 0.81 0.11 0.29J 1.7J 0.67J 1.51 2.1J 0.811 0.05 J 0.18 J 0.09 J 0.53 J 0.82 J 0.66 J 0.59 J 0.111 0.37 J 0.501 0.87 J 0.77 J 1.91 0.501 0.64 J 0.70 J 0.91 1 1.O 1 1.2 J 0.571 0.351 0.68 J 1.4 J 1.5 J 0.63 J 0.84 J 1.8 1 NO NO Nov-01 NO NO NO NO NO NO NO NO May-02 NO NO NO NO NO NO NO Nov-02 NO NO NO NO NO NO NO NO NO NO May-03 NO NO NO NO NO NO NO NO NO NO NO Nov-03 NO NO NO NO NO NO NO NO NO NO NO May-04 NO NO NO NO NO NO NO NO NO NO Nov-04 NO NO NO NO NO NO NO NO NO NO May-05 Damaged NO NO NO NO NO NO NO NO NO NO Nov-05 NO NO NO NO NO NO NO NO NO NO May-06 Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.2 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U Nov-2007 0.05 E 1.70 2.00 2.31 1.60 6.70 2.70 1.60 Dry 1.90 1.60 May-2008 0.05 0.40 1.50 0.70 1.00 0.70 0.90 2.10 2.00 0.90 5.50 0.80 0.60 Nov-2008 0.04 E 1.30 1.20 0.90 3.30 2.80 3.00 0.80 Dry 5.60 1.10 May-2009 0.04 0.70 5.50 1.90 1.80 2.60 2.30 1.60 0.60 4.90 1.50 0.40 Aug-2009 Begin Assessment + Phase 2 1.29 3.64 J 2.35 J 2.31 J 2.7 J 0.8 J 0.8 J 0.7 J Jan-2010 1300 1000 0.04 0.91 1.2J 1.91 1.3J 1.81 1.61 1.11 2.4J 0.7J 0.4J 0.4J 0.3J 0.51 May-2010 0.03 0.7J 0.91 1.11 4.0J 1.4J 1.11 2.4J 2.9J 1.11 0.3J 0.11 0.11 0.3J Nov-2010 0.03 0.51 1.11 1.11 0.51 1.3 J 3.9 J 1.51 0.81 0.81 1.7 J 0.94 J 1.11 1.51 May-2011 0.02 1.1J 1.5J 1.3J 1.1J 1.91 4.4J 1.61 1.51 1.3J 0.17J 0.46J 0.30J 0.02U Nov-2011 0.02 Damaged 0.89 J 0.15 J 0.49 J 0.52 J 1.5 J 0.88 J 1.11 7.1 J 1.7 J 0.93 J 0.69 J 2.3 J 1.2 J 0.34 J 0.42 J May-2012 0.06 0.87 J 1.3 J 0.911 0.851 1.81 3.4 J 2.2 J 1.91 1.1 1 2.1 J 0.36 J 0.581 1.2 J Nov-2012 0.06 Damaged 1.O 1 0.76 J 1.31 1.3 J 1.61 1.4 J 0.881 4.2 J 1.2 J 1.91 1.4 J 1.31 1.4 J 1.1 1 Dry May-2013 0.06 Damaged 0.96 J 2.0 J 1.6 J 1.6 J 0.77 J 1.0 0.61 J 4.8 J 1.8 1 1.9 1 1.3 J 2.4 J 0.46 J 0.40 J Dry Nov-2013 Not Sampled May-2014 WER 0.06 1.0 J 0/8 U 1.1 J 0.54 J 0.31 J 4.0 J 0.52 J 1.7 J 2.0 J 0.67 J 0.38 J 0.37 J 0.63 J 1.0 J 1.8 J 1.4J 0.35J 0.46 J 0.37 J 0.41 J Dry Nov-2014 0.02 0.94 J 2.0 J 1.5 J 0.74 J 5.5 J Damaged 0.611 4.8 J 1.2 J 0.51 J 0.76 J 0.96 J 1.2 J 0.40 J 1.11 0.80 J 0.62 J 0.72 J 0.60 J May-2015 0.02 4.8 J 0.60 J 1.5 J 0.36 J 0.92 J 0.56 J 0.12 J 0.911 3.5 J 0.84 J 1.6 J 0.66 J 0.23 J 0.27 J 0.90 J 0.35 J 0.60 J 1.3 J 0.55 J 0.66 J 0.87 J 0.72 J 0.74 J Nov-2015 0.07 1.61 2.7 J 2.3 J 1.3 J 1.01 4.9 J 1.91 5.6 J 0.71 J 0.46 J 0.75 J 1.11 1.51 2.O J 3.61 0.681 0.52 J 0.64 J 0.601 May-2016 0.09 3.O J 1.2 J 2.2 J 1.3 J 0.50 J DRY 2.5 J 1.91 1.7 J 0.43 J 0.97 J 0.511 1.6 J 1.31 1.81 0.48 J 0.34 J 0.39 J Dry Nov-2016 0.07 1.81 0.34 J 1.7 J 1.11 0.36 J DRY 1.O 1 4.1 J 1.81 0.16 J 0.70 J 0.35 J 1.51 0.50 J 0.62 J 0.45 J 0.561 0.57 J 1.61 May-2017 0.09 4.1J 3.0J 1.4J 1.3J 1.61 2.0J 1.5J 0.531 5.5J 1.51 1.2J 1.81 0.22J 0.70J 3.5J 1.11 0.691 1.2J 1.4J 0.45J 0.561 0.57J 1.61 Deo-2017 0.09 3.1J 1.7J 0.55J 2.7J 0.861 2.71 2.2J 0.92J 3.6J 1.61 4.6J 2.0J 0.68J 0.951 0.661 2.4J 0.7J 0.61 3.8J 0.6J 2.6J 0.771 Dry 0.43J 0.47J 0.68J Jun-2018 10 0.03 1.50 J 1.30 J 1.10 J 1.30 J 1.80 J 2.60 J 1.10 J 1.00 J 1.60 J 1.40 J 0.6 J 1.00 J 0.35 J 0.69 J 0.46 J 0.76 J 0.89 J 0.77 J 0.56 J 1.1 J 1.2 J 0.88 J Dry D.ry 05 J 1.50 J 1.20 J 0.65 J 0.87 J 1.30 J 1.20 J 1.1 J 0.38 J 0.96 J 0.30 0.38 J 0.41 .52 0.44 J 0.25 J 0.12 J 3.10 0.1 2 . 0.46 0Deo-2018 .43 J 1.6 J 6 05 5 J 7 J 220 1.10 0.84 0 50 J 0.40 1.4 0.17 J 2.20 J 0.62 J 0.6 J 1.103 J5 Effectie 11/1/2019 2.7 . 147 U U 1.47U 7.80 J U400 J 2.00 J -- U 2.00 J -- U J 2.00 J 5 2.00 J 3.00 J U 2.00 J 2.00 J U 2 J 5 J 41.00 6.10 J 8.40 48 JDo- 1.60 0.00 3.10 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyle detected above Method Detection Limit. 12. Bold red font indicates analyle detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyle detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity 41.00 0.00 6.10 0.00 8.40 0.00 4.80 0.00 Page 8 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Lead CAS No. 7439-92-1 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Asst. BG Asst. old B-20 Fac. BG BG BG Date 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MIN-7 MW-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MW-15 MIN-16 MW-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 15 NO NO 29.00 0.10 0.10 0.10 0.04 U 0.10 0.10 0.04 U 0.04 U NO NO NO 6.79 U 6.79 U 6.79 U 6.79 U 6.79 U 6.79 U 6.79 U 1.8J 1.4J 0.2J 0.4J 3.2J 1.2J 21.00 5.3J O.SJ 0.11 2.0J 0.2J 1.11 1.81 1.51 0.01U 1.11 0.2J 1.91 3.1J 2.2J 0.161 1.2J 0.11 0.83J 0.81 4.4J 0.161 1.91 0.12 J 0.64 J 0.93 J 0.17 J 3.2 J 0.08 U 0.74 J 0.09 J 0.90 J 1.0 J 11.00 0.12 J 0.43 J 0.49 J 0.65 J 1.5 J 0.22 J 7.9 J 0.12 J 0.23 J 0.53 J 0.07 J 0.93 J 0.07 J 0.75 J NO NO Nov-01 NO NO 27.00 11.00 NO NO NO NO May-02 NO NO 13.00 NO NO NO NO Nov-02 NO NO NO NO NO NO NO NO NO NO May-03 NO NO NO NO NO NO NO 2.8J NO NO NO Nov-03 NO NO 22.00 NO NO NO NO NO NO NO NO May-04 NO 20.00 25.00 NO NO NO NO NO NO NO Nov-04 NO NO 19.00 NO NO NO NO NO NO NO May-05 Damaged NO NO NO NO NO NO NO 14.000 NO NO Nov-05 NO NO 14.00 NO NO NO NO NO NO NO May-06 Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.07 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U Nov-2007 0.04 E 1.30 0.30 7.20 0.40 5.90 0.30 0.30 Dry 1.60 0.20 May-2008 0.04 0.04 U 1.60 0.20 0.50 4.80 0.40 0.50 0.70 0.20 25.00 0.70 0.30 Nov-2008 0.04E 2.80 0.40 3.40 0.60 0.40 0.30 0.20 Dry 14.00 0.90 May-2009 0.04 3.70 0.70 0.50 11.00 0.20 0.30 0.10 0.10 23.00 0.50 0.20 Aug-2009 Begin Assessment+ Phase 2 6.79 6.79 U 6.79 U 6.79 U Jan-2010 15 0.04 0.81 3.91 0.11 0.2J 14.00 1.51 0.51 0.11 0.4J 8.OJ 0.3J 0.61 0.31 May-2010 0.01 3.0J 1.11 0.11 0.01U 6.3J 0.7J 0.2J 0.11 0.4J 0.91 0.51 0.61 1.6J Nov-2010 0.01 2.0J 0.51 0.11 0.2J 6.4J 3.9J 0.3J 0.2J 0.4J 11 0.11 0.5J 0.2J May-2011 0.02 0.61 0.92J 0.16J 0.151 4.8J 3.0J 0.181 0.12J 0.131 4.3J 0.51 0.28J 5.7J Nov-2011 0.02 Damaged 1.7 J 0.06 J O.68 J 0.08 J 0.42 J 0.171 7.3 J 2.1 J 0.24 J 0.29 J 1.2 J 0.951 0.79 J 1.11 0.29 J May-2012 0.08 1.1 J 1.3 J 0.22 J 0.25 J 7.6 J 3.5 J 0.39 J 0.33 J 0.20 J 7.0 J 2.1 J 0.46 J 1.3 J Nov-2012 0.08 Damaged 1.1 J 0.07 J 0.64 J 0.08 U 0.31 J 0.35 J 3.11 1.4 J 0.55 J 0.20 J 0.19 J 0.45 J 0.43 J 0.111 1.3 J May-2013 0.02 Damaged 0.14 J 0.33 J 0.55 J .13' 0.03 J 0.04 J 0.29 J 1.5 J 0.05 J 0.08 J 0.06 J 1.6 J 1.2 J 3.0 J Dry Nov-2013 Not Sampled May-2014 WER 0.13 0.11 1 0.19 1 0.16 J 0.06 J 0.74 J 0.51 1 0.04 J 0.14 J 0.19 J 0.07 J 0.101 0.04 J 0.02 U 0.40 1 0.42 J 10.0 0.34J 5.2 J 0.39 1 1.2 1 Dry Nov-2014 0.03 0.18 J 83.00 0.13 U 0.13 U 0.31 J Damaged 0.13 U 0.22 J 0.13 U 0.13 U 0.13 U 0.13 U 0.13 U 0.52 J 1.4 J 0.30 J 0.21 J 0.78 J Dry May-2015 0.03 0.27 J 0.34 J 0.05 J 0.27 J 0.07 J 0.16 J 0.06 J 3.8 J 3.9 J 0.09 J 0.25 J 0.39 J 0.03 U 0.05 J 0.10 J 0.03 U 0.111 0.05 J 0.56 J 0.69 J 0.53 J 2.5 J 0.84 J Nov-2015 0.06 0.26 J 2.6 J 0.091 0.28 J 2.0 J 0.65 J 0.191 0.35 J 0.16 J 0.16 J 0.111 0.091 0.191 1.O 1 13.00 0.38 J 0.46 J 11 0.681 May-2016 0.06 1.8 J 0.32 J 0.24 J 0.34 J 0.87 J DRY 0.14 J 0.27 J 0.20 J 0.19 J 0.12 J 0.07 J 0.07 J 2.1 J 2.7 J 0.82 J 0.62 J 1.0 J 0.60 J Nov-2016 0.06 0.69 J 0.13 J 0.19 J 0.26 J 0.45 J DRY 0.66 J 0.24 J 0.69 J 0.06 J 0.06 U 0.24 J 0.06 J 0.08 J 1.0 J 0.32 J 0.40 J 0.42 J Dry 0.08 0.29J 0.56 J .27J 0.37 J 0.16J 0.30 J 0.42 J 1.7 J 7.8 J 2.2 J 0.44 J 0.22 J 0.08U 0.08U 0.08U 0.08U 0.17 J 0.08U 2.1 J 0.28 J 0.42 J 0.56 J 4.3 J 0.082.1J 0.19J 0.24J 1.8J 0.11J 0.46J 0.78J 1.9J 0.3J 0.35J 0.24J 0.14J 0.35J 0.76J 0.111 0.24J 1.11 0.181 8.61 5.6J 3.1J 1.7J Dry 0.33J 0.41J 0.24J 0.030.53 J 0.48 J 0.98 J 0.48 J 0.60 J 0.13 J 0.91 J 1.80 J 1.10 J 0.07 J 0.14 J 0.26 J 0.11 J 0.18 J 0.13 J 0.60 J 2.80 J 0.12 J 0.69 J 6.8 J 0.8 J 0.97 J Dry 0.01 J 1.10 J Dry tDe]011dl 0.031.00J0.28J -- U 0.41 J -- U 0.03 J 0.04 J 0.28 J 0.16 J -- U 0.02 J - U -- U 0.03 J 0.04 J -- U 0.16 J -- U 0.73 J 0.10 J 0.12 J 0.06 J 9.600.65 J 032 J 0.38 J 0.03-- U 0.60 J -- U 0.04 J -- U -- U -- U 0.05 J -- U -- U -- U 0.08 J -- U -- U -- U -- U 011 J -- U 0.72 J -- U 0.71 J -- U 3.90 J 0.682.50 J 1.1 J Effective 11/1/2019 0.54 0.03 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U 0.06 J 0.05 J 0.05 J -- U 0.16 J 0.06 J 0.22 J 0.32 J 0.08 J 0.12 J 46.00 0.3 J -- U 0.64 J 1.00 0.00 3.70 0.98 0.00 83.00 0.00 0.60 0.00 0.13 0.00 0.91 0.00 25.00 0.00 1.10 0.00 5.90 0.00 0.70 0.00 0.30 0.00 0.19 0.00 0.18 0.00 0.13 0.00 0.60 0.00 2.80 0.00 0.12 0.00 21.00 0.00 10.00 0.00 0.80 0.00 0.97 0.00 0.00 46.00 0.00 14.00 0.00 2.50 0.00 1.10 0.00 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyle detected above Method Detection Limit. 12. Bold red font indicates analyle detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyle detected above 21- Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 9 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Mercury CAS No. 7439-97-6 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Asst. BG Asst. old B-20 Fac. BG BG BG Date MCL 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MW-15 MW-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 0.024 U 0.024 U 0.024 U Nov-01 May-02 Nov-02 May-03 Nov-03 May-04 Nov-04 May-05 Nov-05 May-06 Nov-06 May-07 Mandated Analytical Changes 0.04 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U Nov-2007 May-2008 Nov-2008 May-2009 Aug-2009 Begin Assessment + Phase 2 0.02 0.024 U 0.024 U 0.024 U Jan-2010 2 1 0.03 0.03 U 0.09 0.03 U May-2010 0.08 0.08 U 0.08 U 0.08 U Nov-2010 0.08 0.08 U 0.08 U 0.08 U May-2011 0.05 0.05 U 0.05 J 0.08 J Nov-2011 0.05 0.05 U 0.05 J 0.05 U May-2012 0.02 0.09 J 0.04 J 0.04 J Nov-2012 0.02 1 1 1 0.02 U 0.07 J 0.03 J 0.02 J 0.05 J 0.02 U May-2013 0.01 1 1 1 0.04 J 0.04 J 0.05 J 0.03 J 0.03 J 0.03 J Nov-2013 Not Sampled May-2014 0.012 0.01 0.01U 0.01U 0.01U 0.01U 0.01 U 0.07U--] 0.07 U Nov-2014 0.06 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U May-2015 0.05 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U Nov-2015 0.05 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U May-2016 0.04 0.04 U 0.04 J 0.04 U 0.04 J 0.04 J Nov-2016 0.04 0.04 U 4.93 0.04 U 0.04 U 0.04 U May-2017 0.07 0.07 U NA 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U Deo-2017 0.07 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U Jun-2018 0.2 0.05 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U - U NA NA NA NA Deo-2018 0.05 -- U -- U -- U - U -- U -- U -- U -- U -- U 0.06 J -- U -- U 0.05 J -- U -- U -- U -- U -- U 0.05 J -- U -- U -- U NA NA NA NA Jun-2019 0.05 0.12 J 0.06 J 0.07 J 0.08 J 0.06 J 0.13 J -- U 0.10 J 0.10 J 0.16 J 0.05 J 0.08 J -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U NA NA NA NA Deo-2019 Effective 11/1/2019 0.012 0.05 0.06 J -- U 0.06 J -- U -- U -- U -- U -- U 0..05 J 0.05 J 0.05 J -- U -- U 0.05 J -- U -- U -- U -- U -- U -- U - U -- U NA NA NA NA NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard = NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 10 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Nickel CAS No. 7440-02-0 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Asst. BG Asst. old B-20 Fac. BG BG BG Date 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MIN-7 MIN-8 MW-9A MW-10 MIN-11 MW-12S MW-13 MW-14D MW-14S MW-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 100 NO NO NO 1.6 J 5.9 1 7.4J 0.51 0.61 7.1J 0.4J 5.4J NO NO NO 2.36 U 2.36 U 2.75J 2.43J 2.44 J 2.36 U 2.36 U 2.5J 0.81 2.2J 0.91 1.61 2.14J 1.01 5.2J 0.8J 2.0J 1.51 1.81 0.91 1.7J 1.11 1.81 4.1J 1.61 4.1J 2.2J 1.91 0.77J 1.11 1.2J 6.81 2.1J 0.861 0.78J 1.3J 1.2J 7.6J 1.3J 1.4J 2J 0.23J 2.3J 3.4J 5.61 3.4J 5.2J 1.3J 1.6J 2.3J 7.3J 1.7J 1.7J 1.9J 0.981 1.51 2.4J 4.SJ 0.84J 0.96J 4.4J NO NO Nov-01 NO NO NO NO NO NO NO NO May-02 NO NO NO NO NO NO NO Nov-02 NO NO NO NO NO NO NO NO NO NO May-03 NO NO NO NO NO NO NO NO NO NO NO Nov-03 NO NO NO NO NO NO NO NO NO NO NO May-04 NO NO NO NO NO NO NO NO NO NO Nov-04 NO NO NO NO NO NO NO NO NO NO May-05 Damaged NO NO NO NO NO NO NO NO NO NO Nov-05 NO NO NO NO NO NO NO NO NO NO May-06 Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.66 0.66 U 0.66 U 0.66 U 0.66 U 0.66 U 0.66 U 0.66 U 0.66 U 0.66 U 0.66 U 0.66 U 0.66 U 88 Nov-2007 0.06 E 3.3 J 3.6 J 2.7 J 9.11 9.11 7.5 J 5.3 J Dry 2.9 J 0.7 J May-2008 0.06 0.91 5.21 1.4J 2.1J 2.3J 4.3J 3.2J 2.0J 7.SJ 3.5J 1.4J O.SJ Nov-2008 0.06E 4J 6J 1.7J 3.4J 6.1J 4.6J 4.7J Dry 4.2J 1.3J May-2009 0.04 2.1J 1.7J 1.81 1.2J 2.5J 1.01 0.91 3.3J 1.91 0.2J 0.4J Aug-2009 Begin Assessment + Phase 2 2.36 3.47 J 2.36 U 3.91 J Jan-2010 100 0.04 1.7J 3.11 5.81 2.6J 2.1J 4.8J 1.11 0.61 5.1J 1.3J 0.91 0.81 0.6J May-2010 0.05 3.2J 1.7J 10.81 1.51 2.0J 7.1J 7.5J 10.4J 9.2J 0.4J 1.2J 0.81 0.81 Nov-2010 0.05 3.9J 6.2J 12.1J 6.4J 2.1J 16.81 5.7J 1.7J 9.11 0.7J 1.6J 0.81 0.81 May-2011 0.04 1.2J 3.1J 3.3J 1.61 1.4J 5.51 2J 2.3J 5.2J 1.31 1.81 1.11 1.51 Nov-2011 0.04 Damaged 1.4J 0.3J 1.2J 0.71J 4.3J 3.6J 1.81 6.91 2.7J 1.51 5.4J 0.881 0.991 0.76J 0.551 May-2012 0.06 2.6J 4.4J 3.61 4.8J 1.7J 4.7J 2.9J 4.3J 7.2J 3.8J 2.9J 5.0J 6.1J Nov-2012 0.06 Damaged 2.6J 1.iJ 6.61 0.88J 5.81 8.81 1.8J 5.4J 1.4J 2.5J 8.61 0.46J 0.46J 0.78J 1.1J May-2013 0.45 Damaged 1.8J 1.6J 4.6J 0.90J 3.5J 5.O1 1.SJ 5.6J 4.3J 5.51 9.3J 0.97J 0.65J 0.47J Dry Nov-2013 Not Sampled May-2014 WER 0.12 1.3J 1.6J 3.1J 1.51 0.87J 22J 0.71J 3.5J 7.8J 1.3J 1.01 2.7J 5.91 1.2J 1.6J 1.1J 3.OJ 0.98J 0.89J 0.45U Dry Nov-2014 0.01 2.6J 5.91 5.7J 6.7J 1.51 Damaged 3.1J 6.01 8.4J 1.2J 1.81 4.5J 6.7J 1.11 6.9J 1.21 1.41 0.53J Dry May-2015 0.01 3.4 J 1.61 1.51 0.57 J 0.68 J 2.3 J 0.43 J 2.O J 6.4 J 1.7 J 6.8 J 4.4 J 0.87 J 1.20 J 3.20 J 4.90 J 1.40 J 1.1 J 1.601 0.67 J 0.70 J 0.601 0.74 J Nov-2015 0.06 2.9J 1.3J 5.7J 9.7J 2.5J 10.11 2.3J 5.4J 2.5J 1.91 1.7J 4.1J 2.3J 2.5J 4.1J 0.801 0.74J 0.881 0.75J May-2016 0.06 2.0J 2.0J 4.5J 2.6J 1.3J DRY 5.51 6.3J 6.4J 1.2J 4.1J 3.6J 6.6J 1.4J 2.5J 0.92J 0.861 0.75J 0.78J Nov-2016 0.06 3.8J 2.6J 8.51 5.5J 2.4J DRY 3.6J 10.4J 10.4J 1.81 6.7J 5.2J 8.91 3.4J 3.0J 0.72J 1.01 0.64J Dry May-2017 0.08 4.4J 2.4J 1.31 2.5J 0.83J 4.7J 6.2J 2.1J 8.7J 1.81 4.2J 8.3J 1.5J 6.3J 9.3J 7.6J 1.81 1.7J 2.6J 1.4J 1.2J 1.11 1.4J Deo-2017 0.08 4.4J 2.7J 1.2J 6.OJ 0.68J 6.4J 7.4J 1.51 4.4J 4.9J 5.1 J 8.01 2.1 J 3.4J 4.8J 6.91 2.3J 3.0J 4.5J 0.94J 1.7J 2.2J Dry 0.61 0.67J 0.94J Jun-2018 50 0.03 2.00 J 2.00 J 2.00 J 3.30 J 1.50 J 7.90 J 1.80 J 1.70 J 3.60 J 3.60 J 2.00 J 3.10 J 1.80 J 3.30 J 5.30 J 5.60 J 2.10 J 0.99 J 1.50 J 1 J 0.97 J 2.4 J Dry 0.73 J 1.10 J Dry Deo-2018 1.60 J 3.10 J 1.10 J 3.90 J 1.00 J 8.10 J 7.10 J 1.50 J 3.90 J 6.30 J 6.30 J 7.4 J 12.10 5.70 J 6.60 J 3.90 J 1..40 J 1.80 J 2.10 J 1.50 J 5.20 J 2.10 0.65 J 079 J 0.75 J Jun-2019 J 1.10 J 0.55 J 5.60 J 4.90 J 1.90 6 J 4.90 J T. 1.70 J 9.3 J 3.80 J 9.10 J 2.20 J 180 J 4000J 1.30 J 7.00 J 1.40 J 1.80 J 0.88 J 1.60 J 0.81 J Effectie 11/1/2019 J 5.00 5.00 J 5.00 J 3.00 J 14.70 J 8.2 J 142 2.80 2.J 6016 2.90 J 1.00 JDeo-2019 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyle detected above Method Detection Limit. 12. Bold red font indicates analyle detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyle detected above 21- Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity 13.70 0.00 1.20 0.00 2.90 0.00 1.00 0.00 Page 11 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Selenium CAS No. 778249-2 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Asst. BG Asst. old B-20 Fac. BG BG BG Data MCL 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MIN-7 MW-8 MW-9A MW-10 MIN-11 MW-12S MW-13 MW-14D MW-14S MW-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 50 NO NO NO 0.14U 5.6J 0.14U 0.3J 0.3J 9.81 0.3J 8.2J NO NO NO 6.61 J NO 4.22J 2.78 U 2.78 U 2.78 U 2.78 U 0.12U 0.2J 0.12U 0.2J 0.51 0.12U 0.4J 2.8J 0.12U 0.32 U 0.61 0.32 U 0.32 U 0.32 U 0.32 U 0.32 U 0.32 U 0.32 U 1.3 J 0.81 0.32 U 0.20U 1.11 0.20U 1.7J 0.38J 0.44J 0.20 U 0.62 J 0.20 U 2.5 J 0.78 J 0.20 U 0.33 J 0.17U 0.93J 0.72J 3.7J 0.64J 1.4J 0.21 J 2.1 J 1.1 J 4.1 J 1.0 J 0.23 J 0.94 J 0.08 J 1.7 J 1.I 1 5.7 J 0.83 J 0.27 J 5.5 J NO NO is Nov-01 NO NO NO NO NO NO NO NO May-02 NO NO NO NO NO NO NO Nov-02 NO NO NO NO NO NO NO NO NO NO May-03 NO NO NO NO NO NO NO NO NO NO NO Nov-03 NO NO NO NO NO NO NO NO NO NO NO May-04 NO NO NO NO NO NO NO NO NO NO Nov-04 NO NO NO NO NO NO NO NO NO NO May-05 Damaged NO NO NO NO NO NO NO NO NO NO Nov-05 NO NO NO NO NO NO NO NO NO NO May-06 Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.35 0.35 U 0.35 U 0.35 U 0.35 U 0.35 U 0.35 U 0.35 U 0.35 U 0.35 U 0.35 U 0.35 U 0.35 U 5 Nov-2007 0.14E 1.91 2.3J 0.14U 2.3J 7.9J 6.0J 4.7J Dry 2.2J 0.14U May-2008 0.14 0.3J 1.91 0.2J 1.2J 0.91 2.5J 1.7J 1.7J 5.9J 1.3J 0.9J 0.2J Nov-2008 0.14E 1.61 4.8J 0.14U 1.2J 5.3J 5.9J 3.5J Dry 3.0J 0.3J May-2009 0.12 5.2J 0.12U 2.5J 0.5J 1.51 0.51 0.81 2.2J 0.81 0.12U 0.12U Aug-2009 Begin Assessment + Phase 2 2.78 17.00 4.14 J 4.59 J Jan-2010 50 20 0.12 5.2J 1.91 0.12U 2.7J 0.2J 5.0J 2.0J 0.2J 3.0J 0.12U 0.12U 0.12U 0.12U May-2010 0.32 1.O 1 3.5 J 11.00 1.O 1 1.11 7.3 J 7.5 J 9.81 4.4 J 0.32 U 0.7 J 0.32 U 0.32 U Nov-2010 0.32 1.81 0.32 U 0.32 U 8.81 0.7 J 0.32 U 7.2 J 1.11 4.7 J 0.32 U 0.61 0.32 U 0.32 U May-2011 0.20 0.46J 0.20U 3.5J 1.11 0.73J 4.9J 1.3J 31 3.0J 0.3J 0.22J 0.64J 0.331 Nov-2011 0.20 Damaged 1.2 J 0.38 J 1.3 J 0.20 U 6.6 J 2.3 J 0.61 J 5.9 J 1.6 J 1.11 1.9 J 0.20 J 0.29 J 0.21 J 0.20 U May-2012 0.17 1.7J 13.00 3.8J 4.3J 1.61 5.01 1.51 4.3J 4.5J 0.41J 0.57J 0.17U 0.17U Nov-2012 0.17 Damaged 1.2 J 0.55 J 15.00 0.52 J 0.3 J 11.00 1.2 J 4.3 J 0.64 J 1.9 J 6.9 J 0.17 J 0.30 J 0.26 J 0.17 U May-2013 0.06 Damaged 1.6 J 0.06 J 14.00 0.23 J 5.4 J 4.9 J 1.1 1 4.4 J 2.7 J 9.9 J 6.S J 0.39 J 0.38 J 0 191 Dry Nov-2013 Not Sampled May-2014 5 0.06 0.06 U 0.38 J 2.9 J 0.06 U 0.06 U 0.06 U 0.06 U 3.4 J 4.9 J 0.06 U 0.06 U 0.06 U 1.3 J 0.06 U 0.06 U 1.81 0.51U 0.06 U 0.06 U 0.0XUDry Nov-2014 0.44 3.0J 0.16U 0.16U 7.2J 2.6J Damaged 1.7J 0.44U 0.16U 0.44U 1.81 0.44U 0.44U 0.62J 0.16U 0.16U 0.16U 0.1 May-2015 0.53 0.24 J 0.35 J 0.71 J 0.22 U 0.22 U 9.4 J 0.53 U 1.4 J 0.53 U 0.46 J 0.53 U 4.3 J 0.22 U 1.10 J 1.40 J 3.40 J 0.59 J 0.22 U 0.28 J 0.22 U 0.29 J 0.2 Nov-2015 0.22 0.23 J 0.26 J 0.79 J 0.22 U 1.8 J 10.00 0.811 9.6 J 1.7 J 0.22 U 2.5 J 0.911 0.911 0.63 J 0.22 U 0.46 J 0.22 U 0.2 May-2016 0.54 0.54 U 1.3 J 2 J 1.11 0.76 J DRY 3.2 J 9.9 J 8.6 J 0.54 U 4.6 J 0.77 J 6.7 J 0.73 J 0.54 U 0.54 U 0.54 U 0.5U Nov-2016 0.62 1.6 J 2.6 J 0.62 U 9.7 J 1.7 J DRY 6.3 J 0.62 U 0.62 U 0.62 U 9.4 U 1.4 J 0.62 U 1.11 0.69 J 0.54 U 0.76 J 0.5May-2017 0.51 0.51U 0.51U 0.51U 1.3J 0.51U 0.51U 0.51U 1.O1 3.6J 0.52J 5.O1 0.51U 0.51U 5.11 0.74J 9.91 0.77J 0.51U 0.51U 0.95J 0.891 NDeo-2017 0.51 0.63J 0.71J 0.51U 0.5U 0.74J 0.51U 0.5U 0.591 3.81 0.5U 0.5U 0.5U 0.5U 3.1J 1.81 0.5U 0.77J 0.51 U 0.57J 1.81 3.0J 1.21 Dry 0.861 0.5UJun-2018 0.05 0.33 J 0.56 J 0.31 J 2.10 J 0.30 J -- U 2.50 J 0.79 J 2.20 J 2.50 J 2.70 J 4.50 J 0.38 J 4.30 J 2.00 J -- U 1.20 J 0.36 J 1.00 J 0.96 J 2.7 J 0.89 J 0.60 J 0. Deo-2018 0.05 0.30 J 1.90 J 0.19 J -- U 0.60 J NS NS 0.74 J 4.40 J 3.70 J NS NS -- U 7.90 J 1.10 J 8.10 J 0.85 J -- U -- U -- U 2.1 J -- U �O�D Jun-2019 0.05 0.29 J 0.70 J -- U -- U 0.06 J 14.00 4.00 J 1.10 J 3.80 J 4.00 J 5.60 J 8.40 J 0.35 J 4.10 J 1.20 J 1.00 J 0.73 J 0.35 J 1.10 J 0.51 J 4.3 J 0.68 J J 0.45 J 0.65Deo-2019 Effective it/1/2019 5 0.05 -- U -- U -- U 0.44 J -- U 27.00 19.00 2.20 J 5.80 J 10.00 9.20 J 17.00 0.62 J 7.40 J 3.50 J 16.00 1.40 J 0.31 J 2.70 J 4.10 J 3.4 J 0.65 J J 0.54 J 0.99 J 0.26 J NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyle detected above Method Detection Limit. 12. Bold red font indicates analyle detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyle detected above 21- Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity 5.40 0.00 0.60 0.00 0.99 0.00 0.38 0.00 Page 12 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Silver CAS No. 7440-224 sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Asst. BG Asst. old B-20 Fac. BG BG BG Data 2L Std 2B Std pg/L MW-1D MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MW-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 18 NO NO NO 0.04 U 0.04 U 0.1 J 0.04 U 0.04 U 0.11 0.04 U 0.04 U NO NO NO ETECTED IN TRIP BLANK 7.15 JB 6.95JB 6.92JB 6.87J6 6.91 JB 6.77 JB 7.2 JB 0.11 0.11 0.04U 0.11 0.11 1.11 0.11 0.2J 0.1J 0.03 U 0.03 U 0.11 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.11 0.03 U 0.03 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1U 0.1U 0.1U 0.1U 0.1U 0.1U 0.1U 0.03 U 0.03 U 0.03 J 0.03 U 0.03 U 0.03 U 0.03 U NO NO Nov-01 NO NO NO NO NO NO NO NO May-02 NO NO NO NO NO NO NO Nov-02 NO NO NO NO NO NO NO NO NO NO May-03 NO NO NO NO NO NO NO NO NO NO NO Nov-03 NO NO NO NO NO NO NO NO NO NO NO May-04 NO NO NO NO NO NO NO NO NO NO Nov-04 NO NO NO NO NO NO NO NO NO NO May-05 Damaged NO NO NO NO NO NO NO NO NO NO Nov-05 NO NO NO NO NO NO NO NO NO NO May-06 Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.52 0.52 U 0.52 U 0.52 U 0.52 U 0.52 U 0.52 U 0.52 U 0.52 U 0.52 U 0.52 U 0.52 U 0.52 U 0.06 Nov-2007 0.04 E 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U Dry 0.04 U 0.04 U May-2008 0.04 0.04 U 0.2 J 0.04 U 0.11 0.11 0.11 0.11 0.04 U 0.04 U 0.1 J 0.04 U 0.1 J Nov-2008 0.04 E 0.04 U 0.04 U 0.04 U 0.11 0.04 U 0.11 0.04 U Dry 0.11 0.11 May-2009 0.04 0.04 U 0.04 U 0.04 U 0.11 0.04 U 0.04 U 0.04 U 0.04 U 0.11 0.11 0.04 U Aug-2009 Begin Assessment + Phase 2 0.66 8.22 JB 7.15 JB 7.77 JB Jan-2010 20 0.04 0.11 0.2J 0.2J 0.11 0.11 0.11 0.11 0.3J 0.3J 0.2J 0.11 0.2J 0.11 May-2010 0.03 0.1 J 0.03 U 0.11 0.03 U 0.11 0.11 0.03 U 0.03 U 0.11 0.03 U 0.11 0.03 U 0.03 U Nov-2010 0.03 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.11 0.11 0.11 0.11 0.03 U 0.03 U 0.03 U 0.03 U May-2011 0.02 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.04 J 0.02 U Nov-2011 0.02 Damaged 0.02 U 0.02 U 0.02 U 0.02 U 0.04 J 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U May-2012 0.10 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U Nov-2012 0.10 Damaged 0.1U 0.1U 0.1U 0.1U 0.1U 0.1U 0.1U 0.1U 0.1U 0.1U 0.1U 0.1U 0.1U 0.1U 0.1U May-2013 0.03 Damaged 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U Dry Nov-2013 Not Sampled May-2014 WER=050252U 0.03 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.20U 0.20 U 0.03 U 0.03 U 0.03 U Dry Nov-2014 0.04 0.04 U 0.04 U 0.04 U 0.04 U 0.06 J Damaged 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.04 J 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U Dry May-2015 0.01 0.01U 0.01U 0.01U 0.01U 0.01U 0.01U 0.01U 0.02J 0.02J 0.01U 0.02J 0.01U 0.01U 0.01U 0.01U 0.01U 0.01U 0.01U 0.01U 0.01U 0.01U 0.01U 0.01U Nov-2015 0.01 0.01 U 0.01 U 0.01 U 0.03 J 0.02 J 0.031 0.011 0.01 U 0.02 J 0.01 U 0.01 U 0.01 U 0.03 J 0.01 U 0.02 J 0.01 U 0.01 U 0.01 U 0.03 J May-2016 0.06 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U DRY 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U Nov-2016 0.06 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U DRY 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U 0.06 U Dry May-2017 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20Deo-2017 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U 0.20 U Dry 0.20U 0.20U 0.20UJun-2018 J -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U - U -- U Dry -- U -- U Dry Deo-2018 J -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U - U -- U0.05 J -- U -- U -- U Jun-2019 U -- U 0.06 J -- U -- U -- U -- U 0.07 J -- U -- U 0.06 J -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U Deo-2019 Effective 11/1/2019 0.06 J -- U 1.30 J -- U 1.00 J - U -- U 1.00 J 1.00 J 0.06 J -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- IJ -- U NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyle detected above Method Detection Limit. 12. Bold red font indicates analyle detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyle detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity 0.05 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Page 13 of 48 Appendix 2 Historical Data For Selected Analytes Parameter : Sulfide CAS No. 18496-25-8 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Assmt. BG Assmt. old B-20 Fac. BG BG BG Date 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MIN-7 MW-8 MW-9A MW-10 MIN-11 MW-12S MW-13 MW-14D MW-14S MW-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 U U U U Nov-01 May-02 Nov-02 May-03 Nov-03 May-04 Nov-04 May-05 Nov-05 May-06 Nov-06 May-07 Mandated Analytical Changes Jun-2007 0.21 Nov-2007 May-2008 Nov-2008 May-2009 Aug-2009 Begin Assessment + Phase 2 50 134 J U U Jan-2010 NE 100 100 U 100 U 100 U May-2010 100 100 U 100 U 100 U Nov-2010 100 1380.00 100 U 100 U May-2011 100 544 J 100 U 100 U Nov-2011 100 2795.00 100 U 100 U May-2012 100 137 J 100 U 100 U Nov-2012 100 1 1 1 100 U 100 U 100 U 644 J 100 U 100 U May-2013 100 1 1 1 100 U 100 U 100 U 272 J 100 U 100 U DRY Nov-2013 Not Sampled May-2014 0.21 100 100 U 467 J 100 U 100 U 230 J 1000 1000 DRY Nov-2014 100 100 U 100 U 100 U 100 U 100 U DRY May-2015 100 104 J 100 U 100 U 100 U 100 U Nov-2015 100 100 U 100 U 100 U 100 U 100 U May-2016 100 100 U 100 U 100 U 100 U INN 100 U 346 J Nov-2016 100 100 U 100 U 100 U 100 U 240 J DRY May-2017 100 1000 1000 100U 1000 1000 100U 100U NA NA NA 100U 100U 4790.00 1000 537J 1000 1000 1000 NA NA NA NA Deo-2017 100 100 Ulil U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U NA NA NA NA Jun-2018 100 100.00 00 J J -- U -- U -- U -- U -- U -- U -- Deo-2018 100 -- UU P16110.00 -- U -- U -- U -- U -- U -- UUJun-2019 100 -- UU -- U -- U -- UU -- UDeo-2019 100 422.00 UU -- U -- U NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard = NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 21- Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 14 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Thallium CAS No. 7440-28-0 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Asst. BG Asst. old B-20 Fac. BG BG BG Date IMAC 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MW-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 NO NO NO 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.03 U 0.03 U NO NO NO 0.198 U 0.198 U 0.198 U 0.198 U 0.198 U 0.198 U 0.198 U 0.03U 0.03U 0.03U 0.03U 0.03U 0.03U 0.03U 0.03U 0.03U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.02 U 0.05 J 0.02 U 0.08 J 0.04 J 0.04 J 0.08 J 0.05 J 0.12 J 0.04 J 0.07 J 0.02 U 0.05 J 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.02 U 0.02 U 0.14 J 0.02 U 0.02 U 0.02 U 0.30 J NO NO is Nov-01 NO NO NO NO NO NO NO NO May-02 NO NO NO NO NO NO NO Nov-02 NO NO NO NO NO NO NO NO NO NO May-03 NO NO NO NO NO NO NO NO NO NO NO Nov-03 NO NO NO NO NO NO NO NO NO NO NO May-04 NO NO NO NO NO NO NO NO NO NO Nov-04 NO NO NO NO NO NO NO NO NO NO May-05 Damaged NO NO NO NO NO NO NO NO NO NO Nov-05 NO NO NO NO NO NO NO NO NO NO May-06 Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.07 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U Nov-2007 0.04 E 0.04 U 0.2 J 0.04 U 0.04 U 0.2 J 0.04 U 0.04 U Dry 0.04 U 0.04 U May-2008 0.04 NO 0.11 0.04 U 0.1 J 0.11 0.11 0.2 J 0.11 0.04 U 0.2 J 0.04 U 0.04 U Nov-2008 0.04 E 0.04 U 0.11 0.04 U 0.04 U 0.11 0.11 0.04 U Dry 0.11 NO May-2009 0.03 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U Aug-2009 Begin Assessment + Phase 2 0.20 0.198 U 0.198 U 0.198 U Jan-2010 2 0.2 0.03 0.11 0.03U 0.03U 0.11 0.11 0.11 0.03U 0.03U 0.03U 0.1J 0.11 0.11 0.03U May-2010 0.05 0.05 U 0.05 U 0.05 U 0.05 U 0.11 0.05 U 0.05 U 0.5 J 0.11 0.05 U 0.05 U 0.05 U 0.05 U Nov-2010 0.05 0.05 U 0.11 0.05 U 0.05 U 0.11 0.5 J 0.11 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U May-2011 0.02 0.02 U 0.11 0.02 U 0.02 U 0.03 J 0.07 J 0.9 J 0.24 J 0.02 U 0.05 J 0.02 U 0.02 U 0.09 J Nov-2011 0.02 U 0.02 U 0.07 J 0.02 U 0.24 J 0.14 J 0.05 J 0.16 J 0.08 J 0.08 J 0.02 U 0.02 U 0.02 U 0.12 J 0.09 J 0.35 J 0.22 J 0.07 U 0.10 J 0.07 U 0.07 U 0.10 J 0.26 J 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U �02Damaged Damaged 0.07 U 0.07 U 0.10 J 0.07 U 0.07 U 0.13 J 0.07 U 0.07 U 0.07 U 0.29 J 0.07 U 0.07 U 0.07 U 0.07 U 0.07 U Damaged 0.04 J 0.02 U 0.07 J 0.18 J 0.02 U 0.08 J 0.02 U 0.07 J 0.10 J 0.20 J 0.06 J 0.05 J 0.02 U 0.06 J Dry Nov-2013 Not Sampled May-2014 2B Std Class C and SC (fish) 2 0.02 0.02 U 0.07 J 0.02 U 0.06 J 0.02 U 0.02 J 0.02 U 0.26 J 0.03 J 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.13 J 0.081.1 0.081.1 0.02 J 0.02 U 0.02 U Dry Nov-2014 0.13 0.13U 0.13U 0.13U 0.13U 0.13U Damaged 0.13U 0.13U 0.13U 0.13U 0.13U 0.13U 0.13U 0.13U 0.151 0.13U 0.13U 0.13U Dry May-2015 0.02 0.03 J 0.02 U 0.04 J 0.06 J 0.03 J 0.02 U 0.02 U 0.05 J 0.07 J 0.10 J 0.10 J 0.06 J 0.02 U 0.02 U 0.30 J 0.02 U 0.03 J 0.02 U 0.02 J 0.03 J 0.02 J 0.03 J 0.04 J Nov-2015 0.02 0.02 U 0.07 J 0.02 U 0.16 J 0.05 J 0.09 J 0.06 J 0.04 J 0.18 J 0.02 U 0.02 U 0.03 J 0.07 J 0.06 J 0.13 J 0.02 U 0.02 U 0.04 J 0.07 J May-2016 0.05 0.05 U 0.07 J 0.05 U 0.05 U 0.05 U DRY 0.18 J 0.09 J 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.07 J 0.07 J 0.05 U 0.06 J 0.05 U 0.05 U Nov-2016 0.05 0.05 U 0.10 J 0.05 U 0.05 U 0.05 U DRY 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 J Dry May-2017 0.08 0.081.1 0.081.1 0.081.1 O.OBU 0.081.1 0.081.1 0.081.1 O.OBU 0.111 0.081.1 0.081.1 0.081.1 0.081.1 0.081.1 0.081.1 0.081.1 0.08 J 0.081.1 0.081.1 0.081.1 0.081.1 0.081.1 0.10 J Deo-2017 0.08 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 J 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.12 J 0.08 U 0.13 J 0.08 U Dry 0.08 U 0.08 U 0.08 U Jun-2018 0.05 -- U -- U 0.11 J -- U -- U -- U -- U 0.06 J -- U 0.10 J 0.06 J -- U -- U -- I U 0.06 J -- U -- U -- U 0.06 J 0.07 J 0.1 J -- U Dry -- U -- U Dry Deo-2018 0.05 -- U -- U -- U 0.08 J -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U 0.08 -- U -- U 0.07 J Jun-2019 0.05 -- U 0.14 J 0.10 J -- U -- U -- U -- U 0.16 J 0.12 J -- U -- U -- U -- U U 0.07 J 0.12 J -- U 0.05 J -- U 0.09 J 0.06 J -- U -- U -- U -- U Deo-2019 0.02 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U 0.06 J 0.05 J 0.02 J -- U 0.04 J 0.02 J 0.31 J 0.10 J 0.09 J 0.06 J 0.46 J -- U 0.11 J 0.02 J NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyle detected above Method Detection Limit. 12. Bold red font indicates analyle detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyle detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity 0.46 0.00 0.00 0.00 0.11 0.00 0.07 0.00 Page 15 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Tin CAS No. 744031-5 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Asst. BG Asst. old B-20 Fac. BG BG BG Date IMAC 2L Std 2B Std pg/L MW-1D MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MIN-7 MW-8 MW-9A MW-10 MIN-11 MW-12S MW-13 MW-14D MIN-14S MW-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 B = DETECTED IN TRIP BLANK 5.36 JB 6.02 JB 4 JB Ell Nov-01 May-02 Nov-02 May-03 Nov-03 May-04 Nov-04 May-05 Nov-05 May-06 Nov-06 May-07 Mandated Analytical Changes Nov-2007 May-2008 Nov-2008 May-2009 Aug-2009 Begin AssessmentPhase 2 1.80 12.9 JB 5.34 JB 5.12 JB Jan-2010 2000 0.08 0.08 U 0.08 U 0.08 U May-2010 0.11 1.5 J 3.9 J 0.4 J Nov-2010 0.11 0.5 J 0.6 J 0.5 J May-2011 0.16 0.23 J 0.32 J 0.95 J Nov-2011 0.16 0.26 J 0.47 J 0.24 J May-2012 0.10 0.15 J 0.24 J 0.10 U Nov-2012 0.10 1 1 1 0.1 U 0.1 U 0.17 J 0.13 J 0.28 J 0.92 J May-2013 0.06 1 1 10.24 J 0.24 J 0.20 J 0.08 J Nov-2013_7 m Not SapledIm May-2014 2B Std Class C and SC 2B Std Class C and SC (fish) 800 0.06 0.06 U 0.06 U 0.06 J 0.06 U 0.06 U 0.13U 0.13U Nov-2014 0.05 0.05 U 0.96 J 0.05 U 0.22 J 0.18 J May-2015 0.06 0.6 U 0.13 J 0.06 U 0.06 J 0.12 J Nov-2015 0.06 0.11 J 0.14 J 0.35 J 0.20 J 0.35 J May-2016 0.06 0.6 U 0.111 0.06 U 0.09 J 0.33 J [a. Nov-2016 0.06 0.6 U 0.06 U 0.06 U 0.06 U 0.06 U May-2017 0.13 0.52J 0.13 U 0.14J 0.13U 0.28J 0.22 J 0.21 J NA NA NA NA 0.20 J 0.13U 0.13U 0.13U 0.13U 0.13U 0.13U NA NA NA NA Deo-2017 0.13 0.91J 0.13U 0.13U 0.13U 0.13U 0.23J 0.24J 0.13U 0.13U 0.14J 0.13U 0.13U 0.13U 0.13U 0.13U 0.24J 0.13U 0.21J 0.13U 0.181 0.221 NA NA NA NA Jun-2018 0.05 0.10 J -- U -- -- 1.20 J -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- -- U 0.07 J 0.1 J -- U Dry NA NA Dry Deo-2018 0.05 0.17 J 1.80 J -- U -- U -- U -- U -- U 0.24 J 0.55 J -- U -- U -- U -- U -- U -- U - U -- U -- U -- U -- U -- U -- U NA NA NA NA Jun-2019 0.05 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U - U NA NA NA NA Deo-2019 0.05 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U 0.16 J -- U 0.19 J 0.60 J -- U 0.20 J 0.16 J 0.10 J - U -- U NA NA NA NA NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 16 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Vanadium CAS No. 7440-62-2 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Asst. BG Asst. old B-20 Fee. BG BG BG Date IMAC 2L Sld 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MIN-7 MW-8 MW-9A MW-10 MIN-11 MW-12S MW-13 MW-14D MW-14S MW-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 NO NO NO 0.7 J 1.7 J 1.11 0.07 U 0.1 1 1.51 1.0 1 2.7 J NO NO NO 0.586 U 0.586 U 0.586 U 0.586 U 0.586 U 0.586 U 0.586 U 4.9J 4.5J 1.3J 2.4J 4.9J 1.4J 35.00 15-7J 3.0J 0.61 3.2J 1.01 3.7J 2.4J 3.3J 0.91 1.91 0.61 4.4J 3.6J 8.51 1.2J 3.1J 0.54J 2.9J 1.01 11.81 1.3J 9.2J 0.55J 4.8J 1.4J 0.3J 8.4J 0.961 5.9J 0.78J 6.91 2.2J 31.00 0.25J 4.1J 0.44J 6.4J 3.O1 0.41J 22.7J 0.07J 4.6J 0.35J 7.SJ 2.OJ 0.07U 8.2J NO NO Nov-01 48.00 NO NO NO NO NO NO NO May-02 NO 124.00 NO NO NO NO NO Nov-02 NO 98.00 NO NO NO NO NO NO NO NO May-03 NO NO NO NO NO NO NO 115.00 NO NO NO Nov-03 NO NO NO NO NO NO NO NO NO NO NO May-04 NO NO NO NO NO NO NO NO NO NO Nov-04 NO 44.00 45.00 NO NO NO NO NO NO NO May-05 Damaged NO NO NO NO NO NO NO NO NO NO Nov-05 NO NO NO NO NO NO NO NO NO NO May-06 Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.42 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U NO NO NO Nov-2007 0.42 E 1.51 0.91 6.9 J 1.61 17 J 2.5 J 1.4 J Dry 2.O J 0.71 May-2008 0.07 0.07 U 0.8 J 0.07 U 0.07 U 3.4 J 1.2 J 4.6 J 3.11 1.0 J 40.00 1.4 J 0.8 J Nov-2008 0.07 E 2.6 J 1.3 J 3.11 1.81 4.2 J 1.3 J 0.81 Dry 9.2 J 1.2 J May-2009 0.28 3.5 J 2.6 J 1.81 10.O 1 1.61 7.5 J 1.81 1.3 J 30.00 2.3 J 1.91 Aug-2009 Begin Assessment + Phase 2 0.59 0.586 U 0.586 U 0.586 U Jan-2010 0.3 0.28 11 3.5J 2.3J 2.1J 11.4J 5.1J 11.61 0.81 0.91 18.9J 0.81 0.91 0.6J May-2010 0.03 3.8J 2.1J 2J 0.81 8.3J 2.3J 5.81 1.3J 1.61 2.0J 1.51 1.4J 3.0J Nov-2010 0.03 3.3J 0.61 2.6J 1.61 9.4J 3.2J 4.4J 1.11 1.91 3.1J 1.11 0.91 0.91 May-2011 0.14 1.2J 0.94J 1.4J 0.69J 7.5J 4.3J 3.9J 0.75J 0.76J 6.8JjV2 0.93J 7.2J Nov-2011 0.14 Damaged 2.5J 2.OJ 0.75J 0.4J 3J 0.881 8.51 2.4J 3.3J 1.2J 4.1J 2.2J11JO.881 May-2012 0.10 1.7J 2.OJ 1.4J 2.0J 7.2J S.6J 3.0J 1.3J 1.3J 9.5J 1.O1 3.OJ Nov-2012 010 Damaged 1.2J 1.51 1.7J 0.1U 1.81 1.61 5.8J 2.OJ 4.7J 0.52J 1.2J 1.51 0.67J 2.3J May-2013 0.07 Damaged 1.OJ 1.3J 0.62J 0.93J 1.9J 0.39J 3.3J 3.5J 1.5J 1.3J 1.3J 3.1J 3.4J Dry Nov-2013 Not Sampled MI May-2014 -- 0.06 0.16J 0.07U 1.3J 0.07U 3.2J 1.11 0.34J 1.3J 1.01 0.07U 2.9J 0.07U 4.1J 1.4J 1.4J 71.0 4.5J 6.0J 0.481 1.2J Dry Nov-2014 0.22 0.96J 2.3J 2.5J 0.14J 0.44J Damaged 1.2J 1.3J 1.11 0.48J 4.4J 0.34J 11.01 1.3J 4.3J 0.30J 0.06U 1.3J Dry May-2015 0.22 0.88 J 1.01 1.9 1 0.59 J 0.26 J 2.2 J 0.46 J 6.3 J 5.5 1 1.11 2.9 J 0.94 J 0.22 U 4.90 J 0.22 U 5.101 1.20 J 0.22 U 1.61 1.11 0.94 J 2.5 J 1.1 1 Nov-2015 0.36 2.3J 2.8J 3.2J 1.51 5.3J 1.2J 4.1J 1.91 1.2J 0.911 5.3J 0.54J 3.2J 5.8J 27.00 1.3J 0.84J 1.7J 1.51 May-2016 0.36 4.O J 0.36 U 3.4 J 1.51 3.4 J DRY 4.9 J 3.0 J 1.81 0.36 U 8.7 J 0.36 U 16.51 10.51 5.7 J 1.61 0.70 J 1.7 J 0.531 Nov-2016 0.36 2.O J 0.39 J 3.3 J 1.91 2.7 J DRY 5.61 1.61 3.0 J 0.36 U 8.51 0.591 16.4 J 1.51 2.6 J 0.57 J 0.54 J 1.O 1 Dry May-2017 0.24 2.2J 2.8J 2.0J 2.4J 1.61 5.3J 4.3J 5.9J 17.2J 17.9J 4.3J 3.7J 0.241J 8.51 0.241J 17.9J 0.911 1.4.1 5.91 0.74J 0.71J 0.95J 5.6J Deo-2017 0.24 4.1J 1.11 0.98J 5.3J 0.35J 5.2J 4.1J 4.6J 3.01 7.5J 1.11 2.7J 1.51 9.11 1.51 21.3J 6.6J 0.591 20.1J 34.0 12.0J 7.1J 1.3J 1.31 1.11 Jun-2018 0.03 1.40 J 1.20 2.70 J 0.83 J 3.00 J 5.80 J 4.00 J 5.10 J 4.60 J 1.20 J 1.30 J 1.70 J 1.20 J 8.00 J 2.70 J 16.00 J 15.00 J 0.05 J 2.10 21.2 J 8.8 J 5.2 J 1.40 J 1.80 J Dry Deo-2018 UPEPA Drinking Water Guideline 0.03 2.00 1.80 -- U 1.20 -- U 7.20 3.10 5.00 1.30 2.00 2.40 1.60 -- U 8.10 1.50 17.50 1.30 -- U 2.30 3.5 9.1 1.2 n.4 0.11 J 0.57 J 0.7 J Jun-2019 21 0.03 -- U 1.50 -- U 0.60 J -- U 5.90 2.50 2.70 2.80 6.20 2.90 3.10 0.54 J 9.50 3.20 40.00 1.50 -- U 4.20 5.7 11.9 2.9 0.92 J 2.4 3.2 Deo-2019 0.07 -- U 5.00 0.39 J 4.00 -- U 5.00 4.00 3.00 5.00 7.00 0.86 J 5.00 1.00 J 11.00 3.00 40.00 1.00 0.05 J 4.00 15 11.2 3.3 0.90 J 11 2 2.70 0.00 124.00 0.00 3.00 0.00 7.20 0.00 4.00 0.00 45.00 0.00 5.00 0.00 7.00 0.00 2.90 0.00 115.00 0.00 1.20 0.00 11.00 0.00 3.20 0.00 40.00 0.00 15.00 0.00 0.05 0.00 35.00 0.00 71.00 0.00 11.90 0.00 5.20 0.00 0.00 84.00 0.00 1.40 0.00 11.00 0.00 3.20 0.00 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyle detected above Method Detection Limit. 12. Bold red font indicates analyle detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyle detected above 21- Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 17 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Zinc CAS No. 7440-66-6 sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Asst. BG Asst. old B-20 Fac. BG BG BG Date 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MIN-7 MW-8 MW-9A MW-10 MIN-11 MIN-12S MW-13 MW-14D MW-14S MW-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 1050 NO NO NO 3.6 J 8 J 2.6 J 1.6 J 3.3 J 3.3 J 5.9 J 5.9 J NO NO NO 1.66 JB 1.29 U 1.29 U 1.29 U 4.63 JB 1.29 U 1.48 JB 7.5 J 2.6 J 2.9 J 2.8 J 8.51 21.00 4.7 J 15.0 11.000 1.51 4.0J 2.0J 1.11 7.5J 1.2J 2.6J 2.1J 3.2J 3.1J 8.51 2.6J 3.2J 3.51 2.1J 3.5J 32.00 2.6J 2.31 1.7J 1.91 1.81 3.2J 3.2J 4.7J 0.661 0.48U 1.7J 0.48U 8.11 6.2J 4.4J 3.iJ 6.4J 4.iJ 3.3J 6.iJ 4.6J 3.7J 2.iJ 3.SJ 1.9J 3.5J 4.2J 5.6J NO NO Nov-01 53.00 NO NO NO NO NO NO NO May-02 NO 99.00 NO NO NO NO NO Nov-02 NO 57.00 NO NO NO NO NO NO NO NO May-03 NO NO NO NO NO NO NO 134.00 NO NO NO Nov-03 NO NO NO NO NO NO NO NO NO NO NO May-04 NO NO NO NO NO NO NO NO NO NO Nov-04 NO NO NO NO NO NO NO NO NO NO May-05 Damaged NO NO NO NO NO NO NO NO NO NO Nov-05 NO NO NO NO NO NO NO NO NO NO May-06 Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.2 16.00 0.2 U 19.00 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 26.000 0.2 U 15.000 Nov-2007 0.04 E 7.9 J 3.3 J 16.00 5.9 J 20.00 3.4 J 5.1 J Dry 24.00 71.00 May-2008 0.04 1.00 4.5 J 2.20 1.9 J 7.8 J 4.1 J 3.0 J 3.4 J 2.7 J 43.00 7.8 J 19.00 Nov-2008 0.14 E 5.1 J 2.4 J 5.3 J 3.9 J 3.6 J 3.0 J 1.7 J Dry 96.00 36.00 May-2009 0.14 9.4 J 14.00 5 J 12.00 3.3 J 2.5 J 2.8 J 3.2 J 21.00 4.8 J 18.00 Aug-2009 Begin Assessment + Phase 2 1.29 1.29 U 1.29 U 1.29 U Jan-2010 1000 0.14 2.2 J 3 J 1.3 J 3.1 J 16.00 4.8 J 3.9 J 1.51 3.1 J 15.00 8.11 14.00 8.81 May-2010 0.08 2.2J 5.81 2.3J 2.9J 8.51 4.3J 3.3J 3.81 6.3J 2.3J 5.31 11.00 3.0J Nov-2010 0.08 5.61 3.51 3.4J 4.1J 8.11 14.00 4.5J 4.3J 5.4J 5.61 6.81 17.00 3.9J May-2011 0.24 2.6J 3.11 3.61 3.2J 6.1J 7.4J 1.81 2.4J 5.4J 9.6J 12.00 5.8J 9.41 Nov-2011 0.24 Damaged 3.2J 1.11 2.0J 1.7J 2.7J 4.7J 9.4J 7.7J 3.3J 1.8J 5.3J 1.91 8.2J 16.00 2.4J May-2012 0.48 1.4J 2.OJ 0.72J 5.7J 4.7J 6.6J 0.91J 0.66J 3.2J 6.4J 18.00 6.0J 0.70J Nov-2012 0.48 Damaged 4.7J 1.8J 4.6J 2.5J 7.6J 8.4J 6.7J 5.8J 4.9J 4.6J 5.SJ 4.SJ 6.SJ 8.2J 11.00 May-2013 0.47 Damaged 0.76J 5.4J 2.4J 5.OJ 1.2J 3.8J 1.6J 6.1J 0.911 1.01 2.9J 4.iJ 5.2J fi.BJ Dry Nov-2013 Not Sampled MI May-2014 WER 0.53 0.881 1.11 2.6J 1.4J 1.8J 2.0 0.84J 1.9J 3.4J 3.4J 1.3J 1.3J 2.0J 2.4J 2.6J 4.91 3.2J 9.9J 2.3J 2.7J Dry Nov-2014 0.20 1.2 J 3.2 J 2.4 J 3.01 50.00 Damaged 0t4 J 1.4 J 2.8 J 1.3 J 1.4 J 3.1 1 1.91 4.6 J 5.7 J 3.7 J 2.O J 5.7 J Dry May-2015 0.20 16.00 3.3 J 3.5 J 0.37 J 3.3 J 0.94 J 0.27 J 8.3 J 15.00 2.5 J 2.5 J 1.51 2.O J 1.101 3.O 1 13.00 1.30 J 11.00 16.00 2.31 3.O 1 6.4 J 5.2 J Nov-2015 0.20 1.7J 3.2J 1.7J 6.91 5.91 6.61 6.2J 6.1J 1.3J 4.8J 2.8J 4.5J 6.0J 3.6J 35.00 4.7J 4.8J 9.4J 9.81 May-2016 1.61 3.4J 2.5J 3.81 3.7J 3.4J DRY 3.2J 2.3J 1.91 3.11 2.1J 1.91 2.0J 4.5J 12.00 3.6J 2.4J 5.2J 6.3J Nov-2016 1.61 1.81 1.61 U 2.5J 2.6 J 1.81 DRY 1.91 2.7J 3.5J 1.91 1.61 U 2.4J 2.0J 1.61 U 6.81 2.4J 2.9J 5.0J Dry ay-2017 0.66 11.00 1.81 5.4J 3.4J 5..2J 2.6J 3.7J 3.3J 27.00 6.1J 2.8J 2.9J 2.5J 1.91 2..5J 1.51 1.91 8.4J 13..00 0.76J 1.8.1 2..6J 8.1J eo-2017 0.66 51.00 4.3J 2.7J 4.0J 2.1J 4.2J 8.2J 5.6J 2.7J 2.8J 1.11 1.91 3.7J 3.81 3.2J 5.51 2.3J 7.4J 2100 5.8J 6.9J 5.O1 Dry 2.1J 4.6J 10.00 Jun-2018 0.11 6.50 J 1.10 J 5.70 J 5.20 J 6.80 J 1.10 J 3.20 J 3.30 J 4.50 J -- U 0.19 J 1.50 J 1.60 J 0.32 J 2.20 J 2.00 J 1.60 J 4.70 J 5.00 J 2.4 J 5.4 J 8.J Dry 1.60 J 5.20 J Dry 14.00 91.0 450 3Deo-2018 J 3.400 J 3.00 3.230 460 087 J 0.4 J 1.5 J 22.00 1.7 J 360 J 4.5 J 3.80 J 1.50 4.70 J 230 J 210 J 2 J 310 J J 20 J so 2.70 J 600 J 4.40 J 4.70 J 970un-2019 6. J 5. to J 5 J 3 J 13.00 5 J 8.20 J 4.8 J D 1.00 J 4.00 J 00 1.40 J 8.00 J 7.00 J 2.4 Jti 18 J 202.00 42 J 31 3 J20 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyle detected above Method Detection Limit. 12. Bold red font indicates analyle detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyle detected above 21- Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)' in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity 202.00 0.00 96.00 0.00 71.00 0.00 11.00 0.00 Page 18 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Acetone CAS No. 67-64-1 Sample Compliance Limit (pglL) MDL BG BG Assessment Wells Assmt. BG Assmt. old B-20 Fac. BG BG BG Date 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MW-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 -- NO NO NO NO U 3.30 J 3.50 J 5.60 J U 4.50 J U 2.10 J NO NO NO U U U U U U U U U U U U U U U 29.00 J U U U U U UKUU U U U U U U U U 10.10 J U U U U U U U U U U U flUU NO NO Nov-01 - NO NO NO NO NO NO NO May-02 - NO NO NO NO NO NO NO Nov-02 - NO NO NO NO NO NO NO NO NO NO May-03 - NO NO NO NO NO NO NO NO NO NO NO NO Nov-03 - NO NO NO NO NO NO NO NO NO NO May-04 - NO NO NO NO NO NO NO NO NO NO Nov-04 - NO NO NO NO NO NO NO NO NO NO May-05 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-05 - NO NO NO NO NO NO NO NO NO NO May-06 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 - NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 1.20 E 247.00 J U U U U U U U U U U U Jun-2007 1.20 20.20 J U U U U U U U U U U U Nov-2007 1.20 E U 2.20 J U 1.80 J 2.70 J 1.70 J 2.30 J Dry 2.30 J 2.20 J May-2008 1.21 2.10 J 3.30 J 2.50 J 2.70 J 3.10 J 4.10 J 4.50 J 3.40 J 4.50 J 4.50 J 5.50 J 3.80 J Nov-2008 1.2 E 1.70 J 3.40 J 1.30 J 1.50 J 2.70 J 2.40 J 2.80 J U 3.70 J 5.30 J May-2009 1.21 3.00 J U U U U U U U U 1.30 J U Aug-2009 Begin Assessment +Phase 2 2.18 NS NS U U NS NS NS NS U NS NS NS Jan-2010 6000 9.06 U U U U U U U U U U U U U U May-2010 9.06 U U U U U U U U U U U U Nov-2010 9.06 U U U U U U U U U U U U May-2011 9.06 U U U U U U U U U U U U Ii Nov-2011 9.06 U U U U U U U U U U U U U U 9.06 U U U U U U U U U U U U U U U 9.06 U U U U il U U U U U U U U9.06 U U U U U UUU U U UUUUUU U U U Nov-2013 Not Sampled May-2014 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06U 9.O6U 9.06 U 9.06 U 9.06 U Dry Nov-2014 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U Damaged 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 12.50 J J 9.06 U 9.06 U Dry May-2015 9.06 9.06 U 9.06 U 9.50 J 9.06 U 9.06 U 9.10 J 9.06 U 9.06 U 22.00 J 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 16.40 J 9.06 U 9.06 U 9.06 U 9.06 U 9.20 J 9.06 U 9.06 U Nov-2015 9.06 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U May-2016 9.06 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U DRY 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U Nov-2016 9.06 9.06 U 9.06 U 9.60 J 12.00 J 9.06 U DRY 9.06 U 9.06 U 17.20 J 9.06 U 9.06 U 9.06 U 12.30 J 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U NS May-2017 9.06 9.061.1 9.061.1 9.061.1 9.061.1 9.061.1 9.061.1 9.06U 9.061.1 9.061.1 9.061.1 9.061.1 10.30 J 9.06U 9.06U 9.06U 9.06U 9.06U 9.061.1 9.06U 9.061.1 9.061.1 9.061J 9.061-1 D9 2017 9.06 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 12.20 J 9.06 U 9.06 U 9.06 U 13.30 J 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U Dry 9.06U 9.06U 9.06U Jun-2018 2000 9.06 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U - U -- U -- U -- U -- U -- U -- U -- U -- U -- U - U Dry -- U -- U Dry Deo-2018 9.06 -- U -- U -- U -- U -- U U -- U -- U -- U 10.30 J 9.63 J -- U -- U -- U 11.80 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U Jun-2019 Deo-2019 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyle detected above Method Detection Limit. 12. Bold red font indicates analyle detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyle detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity 4.50 0.00 9.20 0.00 5.30 0.00 0.00 0.00 Page 19 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Benzene CAS No. 71-43-2 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Assort. BG Assort. old B-20 Fac. BG BG BG Date 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MW-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 1 1 -- NO NO NO NO U 1.00 U 1.10 U 2.10 U 1.50 NO NO NO U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U 0.30 J U U U U U U 1.20 U U U U U 0.70 J U U U U U U 1.10 U U 0.40 J NO NO Nov-01 - NO NO NO NO NO NO NO May-02 - NO NO NO NO NO NO NO Nov-02 - NO NO NO NO NO NO NO NO NO NO May-03 - NO NO NO NO NO NO NO NO NO NO NO NO Nov-03 - NO NO NO NO NO NO NO NO NO NO May-04 - NO NO NO NO NO NO NO NO NO NO Nov-04 - NO NO NO NO NO NO NO NO NO NO May-05 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-05 - NO NO NO NO NO NO NO NO NO NO May-06 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 - NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.16 E U U U U U U U U U U U U Jun-2007 0.16 U U U U U U U U U U U U Nov-2007 0.16 E U U U U 0.20 J 0.30 J 0.70 J Dry U U May-2008 0.16 U U U U U U U U 0.50 J U U U Nov-2008 0.16 E U U U U U U 0.50 J U U U May-2009 0.16 U U U U U U U 0.30 J U U U Aug-2009 Begin Assessment +Phase 2 0.07 NS NS 1.30 U NS NS NS NS 1.90 NS NS NS NS Jan-2010 1 0.24 U U U U U U U U U U U U U U U May-2010 0.24 U U 3.10 U U U U U U U U U U Nov-2010 0.24 0.60 J U 2.10 0.90 J U U U U U U U U U May-2011 0.24 0.30 J U 1.00 U U U U U 0.40 J U U U U Nov-2011 0.24 U U U U 1.10 0.60 J U U U U 0.40 J U U U U May-2012 0.24 U U 1.00 0.60 J U U U U 1.10 U U U U Nov-2012 0.24 U U 0.60 J U 1.20 0.70 J U U U U 1.60 U U U U May-2013 0.24 U U U U U 0.30 J U U U U U U U U Dry Nov-2013 Not sampled May-2014 51 0.24 0.24 U 0.24 U 1.10 0.24 U 0.24 U 0.24 U 0.24 U 0.30 J 1.90El U 0.24 U 0.24 U 0.40 J U U 0.24U 0.24U U U U Dry Nov-2014 0.24 0.24 U 0.60 J 2.10 0.50 J 0.24 U Damaged 0.24 U 0.30 J 0.80 U 0.24 U 0.24 U 1.10 0.24 U 0.50 J 0.24 U 0.24 U 0.24 U Dry May-2015 0.24 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U 1.50 0.24 U 0.24 U 0.24 U 0.24 U 0.60 J 0.24 UU 0.24 U 0.24 U 0.50 J 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U Nov-2015 0.24 0.24 U 0.24 U 1.70 1.70 0.24 U 0.24 U 0.24 U 0.24 U 0.24 UU 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U May-2016 0.24 0.24 U 0.24 U 1.30 0.24 U 0.24 U DRY 0.24 U 0.40 J 0.90 U 0.50 J 0.24 U 1.40 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U Nov-2016 0.24 0.24 U 0.24 U 1.20 0.80 J 0.24 U DRY 0.24 U 0.40 J 1.50U 0.60 J 0.24 U 1.90 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U Dry May-2017 0.24 0.24U 0.24U 0.24U 0.24U 0.24U 2.80 2.00 0.24U 0.24U 0.24U 0.24U 1.20U 0.40 J 0.24U 1.70 0.24U 0.24U 0.24U 0.24U 0.24U 0.24U 0.24U Deo-2017 0.24 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U 1.70 2.70 0.24 U 0.24 U 0.24 U 0.24 U 0.60 U 0.24 U 1.00 2.00 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U Dry 0.24 U 0.24 U 0.24 U 0.24 -- U -- U -- U -- U -- U 1.20 -- U -- U -- U -- U -- U 0.30 U I -- I U 0.90 J 1.40 -- U -- U -- U -- U -- U -- U Dry -- U -- U Dry Deo-2018 MCI= 5 (NEW) 0.24 -- U -- U -- U -- U -- U 1.30 1.68 -- U -- U -- U -- U 0.48 J -- U 1.57 0.48 J 1.48 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- 0.24 -- U -- U -- U -- U -- U -- U 1.00 0.30 J -- U -- U 0.31 J 1.17 -- U 2.26 1.38 2.52 -- U -- U -- U -- U -- UU -- U -- U U0.24 AU -- U -- U -- U 0.44 J -- U 1.81 1.48 -- U -- U -- U -- U 1.13 -- U 1.28 2.56 2.12 -- U -- U 1.47 -- U -- U -- U -- U -- U -- U -- 0.00 0.00 0.60 0.00 0.00 0.00 3.10 0.00 2.70 0.00 0.30 0.00 0.00 0.00 0.20 0.00 0.60 0.00 1.90 0.00 0.00 0.00 2.26 0.00 2.56 0.00 2.52 0.00 0.00 0.00 0.00 0.00 1.47 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyle detected above Method Detection Limit. 12. Bold red font indicates analyle detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyle detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 20 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: 2-Butanone CAS No. 78-93-3 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Assmt. BG Assmt. old B-20 Fee. BG BG BG Date 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MW-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 100 4200 -- NO NO NO NO U U 1.00 J 1.10 J U U U U NO NO NO U U U U U U U U U U U U U U U U U U U U U U U U U 8.90 J U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U NO NO Nov-01 - NO NO NO NO NO NO NO May-02 - NO NO NO NO NO NO NO Nov-02 - NO NO NO NO NO NO NO NO NO NO May-03 - NO NO NO NO NO NO NO NO NO NO NO NO Nov-03 - NO NO NO NO NO NO NO NO NO NO May-04 - NO NO NO NO NO NO NO NO NO NO Nov-04 - NO NO NO NO NO NO NO NO NO NO May-05 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-05 - NO NO NO NO NO NO NO NO NO NO May-06 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-O6 - NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.85 E 129.00 J U U U U U U U U U U U Jun-2007 0.85 66.30 J U U U U U U U U U U U Nov-2007 0.85 E U U U U U U U U Dry U U May-2008 0.85 E U 0.90 J 0.90 J U U U U U 1.10 J 1.20 J 1.70 J U Nov-2008 0.85 E U U 1.10 J 1.50 J 1.00 J 1.00 J U U U U May-2009 0.85 24.80 J U U U U U U U U U U Aug-2009 Begin Assessment +Phase 2 0.54 NS NS U U NS NS NS NS U NS NS NS NS Jan-2010 4000 2.21 U U U U U U U U U U U U U U U May-2010 2.21 U U U U U U U U U U U U U Nov-2010 2.21 U U U U U U U U U U U U U May-2011 2.21 U U U U U U U U U U U U U Nov-2011 2.21 U U U U U U U U U U U U U U U May-2012 2.21 U U U U U U U U U U U U U Nov-2012 2.21 U U U U U U U U U U U U U U U May-2013 2.21 U U U U U U U U U U U U U U Dry Nov-2013 Not Sampled May-2014 2.21 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.30 J 2.21U 2.21U Dry Nov-2014 2.21 2.21 U 2.21 U 2.21 U 2.21 U 2.21 U Damaged 2.21 U 2.21 U 2.21 U 2.21 U 2.21 U 2.21 U 2.21 U 2.21 U 2.21 U 2.21 U 2.21 U 2.21 U Dry May-2015 2.21 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 4.20 J 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21 U Nov-2015 2.21 2.21U 2.21U 2.21U 2.21U 17.70 J 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U May-2016 2.21 2.21 U 2.21 U 2.21 U 2.21 U 2.21 U DRY 2.21 U 2.21 U 2.21 U 2.21 U 2.21 U 2.21 U 2.21 U 2.21 U 2.21 U 2.21 U 2.21 U 2.21 U 2.21 U Nov-2016 2.21 2.21U 2.21U 2.21U 2.21U 2.21U DRY 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 3.20 J 2.21U 2.21U Dry May-2017 2.21 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U Deo-2017 2.21 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U 2.21U Dry 2.21U 2.21U 2.21U Jun-2018 26000 2.21 -- U -- U -- U -- U -- U -- U 0.50 J -- U -- U -- U -- U 3.50 J -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U Dry -- U -- U Dry Deo-2018 2.21 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U Jun-2019 Deo-2019 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard = NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 21 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Carbon Disulfide CAS No. 75-15-0 sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Assmt. BG Assmt. old B-20 Fac. BG BG BG Data 2L Std 2B Sld pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MW-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 -- NO NO NO NO U U U U U U U U NO NO NO U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U NO NO Nov-01 - NO NO NO NO NO NO NO May-02 - NO NO NO NO NO NO NO Nov-02 - NO NO NO NO NO NO NO NO NO NO May-03 - NO NO NO NO NO NO NO NO NO NO NO NO Nov-03 - NO NO NO NO NO NO NO NO NO NO May-04 - NO NO NO NO NO NO NO NO NO NO Nov-04 - NO NO NO NO NO NO NO NO NO NO May-05 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-05 - NO NO NO NO NO NO NO NO NO NO May-06 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 - NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.14 E U U U U U U U U U U U U Jun-2007 0.14 U U U U U U U U U U U U Nov-2007 0.14 E U U U U U U U Dry U U May-2008 0.14 E U U NO U U U U U NO U U U Nov-2008 0.14 E U U U U U U NO U U U May-2009 0.14 U U U U U U U 0.20 J U U U Aug-2009 Begin Assessment +Phase 2 0.07 NS NS U U NS NS NS NS U NS NS NS NS Jan-2010 700 0.23 U U U U U U U U U U U U U U U May-2010 0.23 U U U U U U U U U U U U U Nov-2010 0.23 U U U U U U U U U U U U U May-2011 0.23 U U U U U U U U U U U U U Nov-2011 0.23 U U U U U U U U U U U U U U May-2012 0.23 U U U U U U U U U U U U U Nov-2012 0.23 U U U U U U U U U U U U U U Dry May-2013 0.23 U U U U U U U U U U U U U U Dry Nov-2013 Not Sampled May-2014 0.23 0.40 J 0.30 J 0.23 U 0.23 U 0.30 U 0.30 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.39U 0.39U 0.23 U 0.23 U 0.23 U Dry Nov-2014 0.23 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U Damaged 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U May-2015 0.23 0.23 U 0.23 U 0.30 J 0.23 U 0.23 U 0.23 U 0.23 U 0.50 J 0.40 J 0.30 J 0.23 U 0.23 U 0.40 J 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.50 J 0.23 U 0.23 U 0.23 U 0.23 U Nov-2015 0.23 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.30 J 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U May-2016 0.23 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U DRY 0.23 U 0.23 U 0.23 U 0.23 U 0.30 J 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U Nov-2016 0.23 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U DRY 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U Dry May-2017 0.39 0.39U 0.39U 0.39U 0.39U 0.39U 0.39U 0.39U 0.39U 0.39U 0.39U 0.39U 0.39U 0.391.1 0.30 J 0.39U 1.30 J 0.39U 0.39U 0.39U 0.39U 0.39U 0.39U 0.39U Deo-2017 0.23 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.40 J 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U Dry 0.23 U 0.23 U 0.23 U Jun-2018 0.23 -- U -- U -- U -- U -- U -- U 0.40 J -- U -- U 0.40 J -- U 0.70 J -- U 0.40 J -- U -- U -- U -- U -- U -- U -- U -- U Dry -- U -- U Dry Deo-2018 0.23 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U - U -- U Jun-2019 Deo-2019 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 22 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Chlorobenzene CAS No. 108-90-7 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Assort. BG Assort. old B-20 Fac. BG BG BG Date 2L Std 2B Sld pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MW-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 -- NO NO NO NO U U U U U U U U NO NO NO U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U NO NO Nov-01 - NO NO NO NO NO NO NO May-02 - NO NO NO NO NO NO NO Nov-02 - NO NO NO NO NO NO NO NO NO NO May-03 - NO NO NO NO NO NO NO NO NO NO NO NO Nov-03 - NO NO NO NO NO NO NO NO NO NO May-04 - NO NO NO NO NO NO NO NO NO NO Nov-04 - NO NO NO NO NO NO NO NO NO NO May-05 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-05 - NO NO NO NO NO NO NO NO NO NO May-06 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 - NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.13 E U U U U U U U U U U U U Jun-2007 50 0.13 U U U U U U U U U U U U Nov-2007 0.13 E U U U U U U U Dry U U May-2008 0.13 E U U NO U U U U U U U U U Nov-2008 0.13 E U U U U U U U U U U May-2009 0.13 E- U NO U U U U U U U U U Aug-2009 Begin Assessment+Phase 2 0.08 NS NS U U NS NS NS NS U NS NS NS NS Jan-2010 50 0.30 U U U U U U U U U U U U U U U May-2010 0.30 U U U U U U U U U U U U U Nov-2010 0.30 U U U U U U U U U U U U U May-2011 0.30 U U U U U U U U U U U U U Nov-2011 0.30 U U U U U U U U U U U U U U U May-2012 0.30 U U U U U U U U U U U U U Nov-2012 0.30 U U U U U U U U U U U U U U U May-2013 0.30 U U U U U U U U U U U U U U Dry Nov-2013 Not Sampled May-2014 140 0.30 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U F 0.30 U 0.30 U 0.30 U 0.30 U Dry Nov-2014 0.30 0.30 U 0.30 U 0.30 J 0.30 U 0.30 U Damaged 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U Dry May-2015 0.30 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U Nov-2015 0.30 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U May-2016 0.30 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U DRY 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U Nov-2016 0.30 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U DRY 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U Dry May-2017 0.30 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U Deo-2017 0.30 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U 0.30 U Dry 0.30 U 0.30 U 0.30 U Jun-2018 0.3 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U Dry -- U -- U Dry Deo-2018 0.3 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U Jun-2019 Deo-2019 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 23 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Chloroethane CAS No. 75-00-3 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Assmt. BG Assmt. old B-20 Fac. BG BG BG Date 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MW-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 -- NO NO NO NO U 0.70 J U U U U U U NO NO NO U U U U U U U U U NO U NO U NO U U U U U U U U U U U U U U U U U U U U U 1.10 J U U U U U U U U U U U U U U U U NO NO Nov-01 - NO NO NO NO NO NO NO May-02 - NO NO NO NO NO NO NO Nov-02 - NO NO NO NO NO NO NO NO NO NO May-03 - NO NO NO NO NO NO NO NO NO NO NO NO Nov-03 - NO NO NO NO NO NO NO NO NO NO May-04 - NO NO NO NO NO NO NO NO NO NO Nov-04 - NO NO NO NO NO NO NO NO NO NO May-05 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-05 - NO NO NO NO NO NO NO NO NO NO May-06 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 - NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.29 E U U U U U I U U U U U U U Jun-2007 0.29 U U U U U U U U U U U U Nov-2007 0.29 E 0.30 J 0.40 J U 0.30 J U U U Dry U U May-2008 0.29 E U U U U U U U U U U U U Nov-2008 0.29 E U U U U U U U U U U May_2009 0.29 U U U U U U U U U U U Aug-2009 Begin Assessment +Phase 2 0.11 NS NS 0.17 J U NS NS NS NS U NS NS NS NS Jan-2010 3000 0.48 U U U U U U U U U U U U U U U May-2010 0.48 U U U U U U U U U U U U Nov-2010 0.48 U U U U U U U U U U U U May-2011 0.48 U U U U U U U U U U U U Nov-2011 0.48 U U U U U U U U U U U U U U May-2012 0.48 U U U U U U U U U Nov-2012 0.48 U U U U U U U U U U U U U U U May-2013 0.48 U U U U U U U U U U U U U U Dry Nov-2013 Not Sampled May-2014 -- 0.48 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U Dry Nov-2014 0.48 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U Damaged 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U Dry May-2015 0.48 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 1.70 J 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U Nov-2015 0.48 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U May-2016 0.48 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U DRY 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U Nov-2016 0.48 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U DRY 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U Dry May-2017 0.48 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U Deo-2017 0.48 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U 0.48 U Dry 0.48 U 0.48 U 0.48 U Jun-2018 0.48 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U 0.5 J -- U -- U Dry -- U -- U Dry Deo-2018 0.48 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U - U -- U Jun-2019 Deo-2019 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 24 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Chloromethane CAS No. 74-87-3 sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Assmt. BG Assmt. old B-20 Fac. BG BG BG Date 2L Std 2B Sld pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MW-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 1 2.6 -- NO NO NO NO U U 0.20 J U U 0.50 J U U NO NO NO 3.30 Uj2,9J U U 0.21 J U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U NO NO Nov-01 - NO NO NO NO NO NO NO May-02 - NO NO NO NO NO NO NO Nov-02 - NO NO NO NO NO NO NO NO NO NO May-03 - NO NO NO NO NO NO NO NO NO NO NO NO Nov-03 - NO NO NO NO NO NO NO NO NO NO May-04 - NO NO NO NO NO NO NO NO NO NO Nov-04 - NO NO NO NO NO NO NO NO NO NO May-05 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-05 - NO NO NO NO NO NO NO NO NO NO May-06 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 - NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.18 E U U U U U U U U U U U U Jun-2007 0.18 U U U U U U U U U U U U Nov-2007 0.18 E U U U 0.20 J U U U Dry U U May-2008 0.18 E 0.30 J U U U 0.20 J U 0.20 J U U U 0.30 J U Nov-2008 0.18 E U U U U U 0.20 J U U 0.20 J U May-2009 0.18 U U U U U U U U U U U Aug-2009 Begin Assessment +Phase 2 0.15 NS NS U 0.15 J NS NS NS NS U NS NS NS U Jan-2010 3 0.77 U U U U U U U U U U U U U U U May-2010 0.77 U U U U U U U U U U U U U Nov-2010 0.77 U U U U U U U U U U U U U May-2011 0.77 U U U U U U U U U U U U U Nov-2011 0.77 U U U U U U U U U U U U U U U May-2012 0.77 U U U U U U U U U U U U U Nov-2012 0.77 U U U U U U U U U U U U U U U May-2013 0.77 U U U U U U U U U U U U U U Dry Nov-2013 Not Sampled May-2014 -- 0.77 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U Dry Nov-2014 0.77 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U Damaged 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U Dry May-2015 0.77 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U Nov-2015 0.77 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U May-2016 0.77 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U DRY 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U Nov-2016 0.77 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U DRY 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U Dry May-2017 0.77 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U DeP2017 0.77 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U Dry 0.77 U 0.77 U 0.77 U Jun-2018 0.77 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U - U Dry -- U -- U Dry Deo-2018 0.77 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U - U -- U Jun-2019 0.77 Deo-2019 0.77 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard = NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 25 of 48 Appendix 2 Historical Data For Selected Analytes Parameter : 1,2-Dichloroethane CAS No. 78-875 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Assort. BG Assort. old B-20 Fac. BG BG BG Date MCL 2L Std 2B Sld pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MW-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 -- NO NO NO NO U 0.40 U 0.40 U 0.70 U 0.50 NO NO NO U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U 0.60 U U U U U 0.40 U U U U U U 1.10 U U U U U U U U U U U U U U U NO NO Nov-01 - NO NO NO NO NO NO NO May-02 - NO NO NO NO NO NO NO Nov-02 - NO NO NO NO NO NO NO NO NO NO May-03 - NO NO NO NO NO NO NO NO NO NO NO NO Nov-03 - NO NO NO NO NO NO NO NO NO NO May-04 - NO NO NO NO NO NO NO NO NO NO Nov-04 - NO NO NO NO NO NO NO NO NO NO May-05 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-05 - NO NO NO NO NO NO NO NO NO NO May-06 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 - NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.12 E U U U U U U U U U U U U Jun-2007 0.12 U U U U U U U U U U U U Nov-2007 0.12 E U U U U U U U Dry U U May-2008 0.12 E U U U U U U U U U U U U Nov-2008 0.12 E U U U U U U U U U U May_2009 0.12 U U U U U U U U U U U Aug-2009 Begin Assessment +Phase 2 0.08 NS NS U U NS NS NS NS U NS U NS U Jan-2010 5 0.4 0.27 U U U U 0.40 U U U U U U U U U U May-2010 0.27 U U 0.50 U U U U U U U U U U Nov-2010 0.27 U U 0.30 J U U U U U U U U U U May-2011 0.27 U U U U U U U U U U U U U Nov-2011 0.27 U U U U U U U U U U U U U May-2012 0.27 U U U U U U U U U U U U Nov-2012 0.27 U U UUNUUTE U U U U U U U U U U U May-2013 0.27 U U 1.00 U U U U 0.40 1.20 U U U Dry Nov-2013 Not Sampled May-2014 100 0.27 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U Dry Nov-2014 0.27 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U Damaged 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U Dry May-2015 0.27 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U Nov-2015 0.27 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U May-2016 0.27 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U DRY 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U Nov-2016 0.27 0.27 U 0.27 U 0.30 J 0.27 U 0.27 U DRY 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U Dry May-2017 0.27 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U 0.27 U Deo-2017 0.21 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 UtO2 0.21 U0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U Dry 0.21 U 0.21 U 0.21 U Jun-2018 0.2 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U Dry -- U -- U Dry Deo-2018 MCL= 5 (NEW) 0.02 -- U -- U -- U -- U -- U 0.24 0.13U -- U -- U -- U -- U 0.34 J 0.08 J 0.13 J-- -- U -- U -- U -- U -- U -- U -- U -- U -- U 0.02 -- U -- U -- U -- U -- U 0.11 J 0.13 J 0.02 J 0.02 J 0.02 J 0.06 J -- U 0.40 0.18 J 0.19 J -- U U -- U -- U 0.04 J -- U -- U -- U -- U0.02 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U 0.21 0.27 J 0.15 J -- U -- U 0.11 J -- U -- U -- U -- U -- U -- U NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 26 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: cis-1,2-Dichlomethene CAS No. 156-59-2 Sample Compliance Limit (PgIL) MDL BG BG Assessment Wells Assort. BG Assort. old B-20 Fac. BG BG BG Date 2L Std 2B Sld PgIL MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MW-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 -- NO NO NO NO U 0.20 J U 0.20 J U 1.30 J U 0.20 J NO NO NO U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U 0.60 J U U U U U 1.20 J U U U U U U 8.50 J U U U U U 4.10 J U U U U U U 5.90 J U U 1.40 J NO NO Nov-01 - NO NO NO NO NO NO NO May-02 - NO NO NO NO NO NO NO Nov-02 - NO NO NO NO NO NO NO NO NO NO May-03 - NO NO NO NO NO NO NO NO NO NO NO NO Nov-03 - NO NO NO NO NO NO NO NO NO NO May-04 - NO NO NO NO NO NO NO NO NO NO Nov-04 - NO NO NO NO NO NO NO NO NO NO May-05 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-05 - NO NO NO NO NO NO NO NO NO NO May-06 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 - NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.14 E U U U U U U U U U U U U Jun-2007 0.14 U U U U U U U U U U U U Nov-2007 0.14 E U U U U U U 0.20 J Dry U U May-2008 0.14 E U U U U U U U U 0.20 J U U U Nov-2008 0.14 E 1.00 J 1.40 J U U U U 0.20 J U U 1.60 J May-2009 0.14 U U U U U U U U U U U Aug-2009 Begin Assessment +Phase 2 0.07 NS NS 0.67 J U NS NS NS NS 0.07 J NS NS NS NS Jan-2010 70 0.25 U U U U 0.30 J U U U U U U U U U U May-2010 0.25 U U 0.50 J U U U U U U U U U U Nov-2010 0.25 U U 0.30 J U U U U U U U U U U May-2011 0.25 U U 0.30 J U U U U U 0.40 J U U U U Nov-2011 0.25 U U U U U U U U U U U U U U U May-2012 0.25 U U U U U U U U U U U U U Nov-2012 0.25 U U U U U U U U U U U U U U U May-2013 0.25 U U U U U U U U U U U U U U Dry Nov-2013 Not Sampled May-2014 720 0.25 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.70 J 0.25 U 0.30 J 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U Dry Nov-2014 0.25 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U Damaged 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 1.70 J 0.25 U 1.60 J 0.25 U 0.25 U 0.25 U Dry May-2015 0.25 0.25 U 0.25 U 0.25 U 0.25 U 0.25U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.30 J 0.50 J 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U Nov-2015 0.25 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U May-2016 0.25 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U DRY 0.25 U 0.25 U 0.25 U 0.25 U 0.50 J 0.25 U 0.80 J 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U Nov-2016 0.25 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U DRY 0.25 U 0.25 U 0.25 U 0.25 U 0.40 J 0.30 J 1.60 J 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U Dry May-2017 0.25 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U Deo-2017 0.25 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.60 1.40 J 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U Dry 0.25 U 0.25 U 0.25 U Jun-2018 0.25 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U 0.40 J 0.50 J -- U -- U -- U -- U -- U -- U -- U Dry -- U -- U Dry Deo-2018 0.25 -- U -- U -- U -- U -- U -- U -- U -- U -- U U -- U -- U -- U 0.31 J -- U 0.34 J -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U Jun-2019 0.25 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U 0.35 J -- U 0.40 J -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U Deo-2019 0.25 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U 0.52 J 0.34 J -- U -- U 0.46 J -- U -- U -- U -- U -- U -- U -- U NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 27 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Ethylbenzene CAS No. 100414 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Assort. BG Assort. old B-20 Fac. BG BG BG Date 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW4 MW-5 MW-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MW-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 1 550 -- NO NO NO NO U 0.40 J U 0.30 J U 0.30 J U 0.20 J NO NO NO 0.95 J U U U U U U U U U U U U U U U U U U U U U U U U 2.00 J U U U U U U U U U U U 0.60 J U U U U U U 2.10 J U U U U U 1.50 J U U U U U U 1.20 J U U 0.30 J NO NO Nov-01 - NO NO NO NO NO NO NO May-02 - NO NO NO NO NO NO NO Nov-02 - NO NO NO NO NO NO NO NO NO NO May-03 - NO NO NO NO NO NO NO NO NO NO NO NO Nov-03 - NO NO NO NO NO NO NO NO NO NO May-04 - NO NO NO NO NO NO NO NO NO NO Nov-04 - NO NO NO NO NO NO NO NO NO NO May-05 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-05 - NO NO NO NO NO NO NO NO NO NO May-06 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-O6 - NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.16 E U U U U U U U U U U U U Jun-2007 0.16 U U U U U U U U U U U U Nov-2007 0.16 E U 0.30 J U U U U U Dry U U May-2008 0.16 E U U U U U U U U U U U Nov-2008 0.16 E U U U U U U U U U May-2009 0.16 U U U U U U U U U U Aug-2009 Begin Assessment +Phase 2 0.08 NS NS 0.48 J U NS NS IU NS U NS NS NS NS Jan-2010 600 0.21 U U U U U U U U U U U U U U May-2010 0.21 U U 0.70 J U U U U U U U U U Nov-2010 0.21 U U 0.30 J U U U U U U U U U May-2011 0.21 U U U U U U U U U U U U Nov-2011 0.21 U U U U U U U U U U U U U U U May-2012 0.21 U U U U U U U U U U U U Nov-2012 0.21 U U U U U U U U U U U U EFU U U U May-2013 0.21 U U U U U U U U U U U U U U Dry Nov-2013 Not Sampled May-2014 97 0.21 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U Dry Nov-2014 0.21 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U Damaged 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.50 J 0.21 U 0.60 J 0.21 U 0.21 U 0.21 U Dry May-2015 0.21 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U Nov-2015 0.21 0.21U 0.21U 0.80 J 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21 U 0.21 U 0.21U 0.21U May-2016 0.21 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U DRY 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U Nov-2016 0.21 0.21U 0.21U 0.30 J 0.21U 0.21U DRY 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21 U 0.21 U 0.21 U 0.21U Dry May-2017 0.21 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.30J 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U Deo-2017 0.21 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.40 J 0.21 U 0.21U 0.21 U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21U 0.21 U 0.21U 0.21U 0.21U 0.21U Dry 0.21U 0.21U 0.21U Jun-2018 0.21 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- I U -- U -- U -- U -- U -- U - U Dry -- Dry Deo-2018 0.21 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U 0.44 J -- U 0.23 J -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U Jun-2019 0.21 Deo-2019 0.21 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 28 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Methylene Chloride CAS No. 75-09-2 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Assmt. BG Assmt. old B-20 Fac. BG BG BG Date 2L Std 2B Sld pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MIN-7 MIN-8 MW-9A MW-10 MIN-11 MW-12S MW-13 MW-14D MW-14S MW-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 1 4.6 -- NO NO NO NO U 0.30 J 1.00 J 0.20 J U U U 0.20 J NO NO NO U U U U U U U U U U U U U U U U U U U U U U U U U 11.20 U U U U U 0.90 J U U U U U U U U U U U U U U U U U U U U U U U U U U U U U NO NO Nov-01 - NO NO NO NO NO NO NO May-02 - NO NO NO NO NO NO NO Nov-02 - NO NO NO NO NO NO NO NO NO NO May-03 - NO NO NO NO NO NO NO NO NO NO NO NO Nov-03 - NO NO NO NO NO NO NO NO NO NO May-04 - NO NO NO NO NO NO NO NO NO NO Nov-04 - NO NO NO NO NO NO NO NO NO NO May-05 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-05 - NO NO NO NO NO NO NO NO NO NO May-06 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 - NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.14 E U U U U U U U U U U U U Jun-2007 0.14 U U U U U U U U U U U U Nov-2007 0.14 E U U U U U U 0.20 J Dry U U May-2008 0.14 U U 0.20 J 0.20 J 0.20 J 0.20 J 0.20 J 0.20 J 0.20 J 0.20 J 0.20 J 0.20 J Nov-2008 0.14 E U U U U U U 0.20 J U U U May-2009 0.14 U U U U U U U 0.20 J U U UIII Aug-2009 Begin Assessment+Phase 2 0.10 INS INS U U INS INS INS INS U INS U INS U Jan-2010 5 0.64 U U U U U U U U U U U U U U U May-2010 0.64 U U U U U U U U U U U U U Nov-2010 0.64 U U U U U U U U U U U U U May-2011 0.64 U U U U U U U U U U U U U Nov-2011 0.64 U U U U U U U U U U U U U U U May-2012 0.64 U U U U U U U U U U U U U Nov-2012 0.64 U U U U 0.80 J U U U U U U U U U U May-2013 0.64 U U U U U U U U U U U U U U Dry Nov-2013 Not Sampled May-2014 11000 0.64 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U Dry Nov-2014 0.64 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U Damaged 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U Dry May-2015 0.64 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U Nov-2015 0.64 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U May-2016 0.64 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U DRY 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U Nov-2016 0.64 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U DRY 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U Dry May-2017 0.64 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U Deo-2017 0.64 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U 0.64 U Dry 0.64 U 0.64 U 0.64 U Jun-2018 0.64 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U - U Dry -- U -- U Dry Deo-2018 0.64 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U - U -- U -- U -- U -- U -- U Jun-2019 0.64 Deo-2019 0.64 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 21- Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 29 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Naphthalene CAS No. 91-203 PAH 8260 scan #61 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Assmt. BG Assmt. old B-20 Fac. BG BG BG Date 2L Std 2B Std pglL MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MIN-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MW-15 MW-16 MIN-17 old B-Is SW-1 SW-2 SW-3 SW4 May-01 0.849U L Nov-01 May-02 Nov-02 May-03 Nov-03 May-04 Nov-04 May-05 Nov-05 May-06 Nov-06 May-07 Mandated Analytical Changes Jun-2007 6 Nov-2007 May-2008 Nov-2008 May-2009 Aug-2009 Begin Assessment +Phase 2 0.83 0.805U 0.8671J 0.08671.1 0.8671.1 Jan-2010 6 0.47 NS NS NS May-2010 0.47 0.47 U 0.47 U 0.47 U Nov-2010 0.47 0.47 U 0.47 U 0.47 U May-2011 0.47 0.47 U 0.47 U 0.47 U Nov-2011 0.47 0.47 U 0.47 U 0.47 U May-2012 0.47 0.47U 0.47 U 0.47 U Nov-2012 0.47 May-2013 0.47 Nov-2013 0.5 May-2014 Added MW-12s to Assessment 0.47 0.47 U 0.47 U 0.47 U 0.47 U 0.47U 0.47 U 0.47 U Nov-2014 0.47 0.47 U 2.90 J 0.47 U 0.47 U 0.471.1 May-2015 0.47 Nov-2015 0.47 0.47 U 0.47U 0.47 U 0.47 U 0.471.1 May-2016 0.47 Nov-2016 0.47 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.80 J 0.47 U 0.47 U 0.60 J May-2017 0.47 0.47 U NS 0.47 U 0.47 U 0.47 U 7.70 J 1.80 J 0.47 U 0.47 U 0.47 U 0.47 U 0.90 J 0.47 U 0.47U 0.47 U Deo-2017 0.47 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.70 J 3.10 J 0.47 U 0.47 U 2.50 J 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.60 J 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U Jun-2018 0.47 0.47U 0.47U 0.471.1 0.47U 0.471.1 0.471.1 0.47U 0.47U 0.471.1 0.471.1 0.471.1 0.471.1 0.47U 0.471.1 0.471.1 1.60 J 0.47U 0.471.1 0.47U 0.47U 0.47U 0.471.1 12 0.47 0.47U 0.47U 0.47U 0.47U 0.47U 0.47U 0.47U 0.47U 0.47U 0.47U 0.47U 0.47U0.47U 0.47U 0.47U 1.08 J 0.47U 0.47U 0.47U 0.47U 0.47U 0.47U0.47 �e20118 0.47U 0.47U 0.47U 0.47U 0.47U 0.47U 0.47U 0.47U 0.47U 1.34 J 0.47U 0.47U 0.47U 1.14 J 0.47U 0.94 J 0.47U 0.47U 0.47U 0.47U 0.47U 0.47U 0.47 0.47U 0.47U 0.47U 4.14 J 0.47U 0.47U 0.47U 0.47U 0.47U 0.47U 0.47U 0.47U 0.47U 0.60 J 0.47U 1.56 J 0.47U 0.471.1 0.47U 0.47U 0.47U 0.471.1 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 30 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Tetrahydrofumn CAS No. 109-99-9 Sample Compliance Limit (pglL) MDL BG BG Assessment Wells A-t. BG Assmt. old B-20 Fac. BG BG BG Date 2L Std 2B Sld pglL MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MIN-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 U U 1.80 U U U U 0.70 U 2.40 8.50 1.80 U U U 2.50 6.70 4.40 4.60 5.60 U 3.30 5.10 3.80 2.40 U U 1.40 U U 0.90 U 1.70 U U 2.30 1.90 2.70 U 4.40 4.50 U 6.40 1.20 20.90 U 3.90 5.20 5.50 5.40 U U U U U U U U U U U U 18.40 6.20 U U 4.20 2.50 10.90 3.30 U U U U U NS U U U U 0.90 14.00 0.70 7.40 U U U U U U U U U U 0.60 U U U U U U U U Dry Nov-01 May-02 Nov-02 May-03 Nov-03 May-04 Nov-04 May-05 Nov-05 May-06 Nov-06 May-07 Mandated Analytical Changes Jun-2007 Nov-2007 May-2008 Nov-2008 May-2009 Aug-2009 Begin Assessment +Phase 2 Jan-2010 NE May-2010 Nov-2010 May-2011 0.39 Nov-2011 0.39 May-2012 0.39 Nov-2012 0.39 May-2013 0.39 Nov-2013 Not Sampled May-2014 110000t39 0.39 0.39 U 1.00 6.50 0.39 U 0.39 U 0.39 U 0.39 U 10.80 10.20 0.39 U 0.39 U 0.39 U 5.50 0.39 U 0.80 0.39U 0.39U 0.39 U 0.39 U 0.39 U Dry Nov-2014 0.39 0.39 U 17.70 15.60 5.70 0.39 U Damaged 3.40 7.10 7.70 0.39 U 0.39 U 2.70 10.00 0.39 U 17.30 0.39 U 0.39 U 0.39 U Dry May-2015 0.39 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 16.90 0.39 U 1.10 0.39 U 0.90 34.70 4.90 0.39 U 0.39 U 6.10 7.10 0.39 U 0.39 U 1.00 0.39 U 0.39 U 0.39 U 0.39 U Nov-2015 0.39 0.39 U 0.39 U 20.90 8.60 0.39 U 0.50 0.39 U 1.60 2.60 0.39 U 0.39 U 2.50 1.80 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U May-2016 0.39 0.39 U 0.39 U 14.40 1.30 0.39 U DRY 8.20 29.70 8.10 0.39 U 14.30 1.50 46.20 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U Nov-2016 0.39 0.39 U 0.39 U 10.60 6.10 0.50 DRY 5.60 16.30 11.70 0.39 U 8.80 0.39 U 49.00 0.39 U 0.60 0.70 0.90 0.39 U Dry May-2017 14.40 0.39U 0.39U 1.00 0.39U 19.10 12.70 0.50 1.50 0.50 12.80 15.00 0.39U 6.40 0.90 36.40 0.39U 0.39U 0.39U 0.39U 1.20 0.39U 0.39U Deo-2017 117.00 0.39 U 0.39 U 13.10 0.39 U 23.50 19.10 0.39 U 0.39 U 12.30 3.00 22.20 0.39 U 0.39 U 17.00 58.40 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U Dry 0.39 U 0.39 U 0.39 U 30.50 -- U -- U 1.10 -- U 28.80 4.50 -- U 1.30 5.60 6.30 10.50 -- U 3.40 16.00 32.70 -- U -- U -- U -- U -- U -- U Dry -- U -- U Dry 42.70 -- U -- U 4.85 -- U 35.30 24.40 -- U 2.27 6.88 32.00 21.20 -- U 25.42 8.02 38.75 -- U -- U -- U -- U -- U -- U -- U -- U -- U-43.30 0.62 J 0.51 J 3.94 0.52 J 26.60 8.44 2.44 6.80 14.40 27.00 28.10 0.67 J 29.00 17.30 64.90 1.47 -- U 0.81 J -- U 0.59 J -- U 0.73 J 1.10 1.14 0.40 J112.00 -- I U -- U 27.90 -- U 1 23.10 1 1 20.50 1 1 -- U 1 2.48 14.70 2.47 32.90 -- U 31.20 43.80 40.10 -- U -- U 10.50 -- U -- U 0.5 J 4.22 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyle detected above Method Detection Limit. 12. Bold red font indicates analyle detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyle detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity 4.22 0.00 1.20 0.00 1.14 0.00 0.40 0.00 Page 31 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Trichloroethene CAS No. 79-01-6 sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Assmt. BG Assmt. old B-20 Fac. BG BG BG Date 2L Std 2B Sld pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MW-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 -- NO NO NO NO U U U U U U U U NO NO NO u U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U 0.70 J U U U U U U U U U U U U 0.40 J U U U U U U U U U U U U UU U UU NO NO Nov-01 - NO NO NO NO NO NO NO May-02 - NO NO NO NO NO NO NO Nov-02 - NO NO NO NO NO NO NO NO NO NO May-03 - NO NO NO NO NO NO NO NO NO NO NO NO Nov-03 - NO NO NO NO NO NO NO NO NO NO May-04 - NO NO NO NO NO NO NO NO NO NO Nov-04 - NO NO NO NO NO NO NO NO NO NO May-05 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-05 - NO NO NO NO NO NO NO NO NO NO May-06 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 - NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.13 E U U U U U U U U U U U U Jun-2007 0.13 U U U U U U U U U U U U Nov-2007 0.13 E U U U U U U U DRY U U May-2008 0.13 U U U U U U U U U U U U Nov-2008 0.13 E U U U U U U U May-2009 013 U U U U U U U U UAug-2009 Begin Assessment+Phase2 0.05 NS NS U U NS NS NS NS U NS NS Jan-2010 3 0.23 U U U U U U U U U U U U U May-2010 0.23 U U 0.30 J U U U U U U U U Nov-2010 0.23 U U U U U U U U U MU U U May-2011 0.23 U U U U U U U U U Nov-2011 0.23 UUUU U U U U U U U U U May-2012 0.23 U U U U U U U U U U U Nov-2012 0.23 U U U U U U U U U U U U U May-2013 0.23 U U U U U U U U U U U DRY Nov-2013 Not Sampled May-2014 30 0.23 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23U 0.23U 0.23 U 0.23 U 0.23 U DRY Nov-2014 0.23 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U Damaged 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U DRY May-2015 0.23 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U Nov-2015 0.23 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U May-2016 0.23 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U DRY 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U Nov-2016 0.23 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U DRY 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U DRY May-2017 0.23 0.231.1 0.231.1 0.231.1 0.231.1 0.231.1 0.231.1 0.231J 0.231.1 0.231.1 0.231.1 0.231.1 0.231.1 0.231.1 0.231.1 0.231.1 0.231.1 0.231.1 0.231.1 0.231.1 0.231.1 0.231.1 0.231.1 0.23U Deo-2017 0.23 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U Jun-2018 0.23 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U - U Dry -- U -- U Dry Deo-2018 0.23 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U - U -- U Jun-2019 0.23 Deo-2019 0.23 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 32 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Toluene CAS No. 108-8" Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Assort. BG Assort. old B-20 Fac. BG BG BG Date MCL 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MW-15 MW-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 -- NO NO NO NO U 0.20 J U 0.30 J U 0.40 J U 0.20 J NO NO NO U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U 0.60 J U U U U U U U U U U U U U U U 0.30 J NO NO Nov-01 - NO NO NO NO NO NO NO May-02 - NO NO NO NO NO NO NO Nov-02 - NO NO NO NO NO NO NO NO NO NO May-03 - NO NO NO NO NO NO NO NO NO NO NO NO Nov-03 - NO NO NO NO NO NO NO NO NO NO May-04 - NO NO NO NO NO NO NO NO NO NO Nov-04 - NO NO NO NO NO NO NO NO NO NO May-05 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-05 - NO NO NO NO NO NO NO NO NO NO May-06 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 - NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.13 E U U U U U U U U U U U U Jun-2007 0.13 U U U U U U U U U U U U Nov-2007 0.13 E U U U U U U U DRY U U May-2008 0.13 U U U U U U U U U U U U Nov-2008 0.13 E U U U U U U U U 0.20 J May_2009 0.13 U U U U U U U U U U Aug-2009 Begin Assessment +Phase 2 0.08 NS NS 0.19 J 0.12 J NS NS NS U NS U NS U Jan-2010 1000 600 0.23 U U U U U U U U U U U U U U May-2010 0.23 U U U U U U U HU U U U U U Nov-2010 0.23 U U U U U U U U 0.30 J U U U May-2011 0.23 U U U U U U U U U U U U Nov-2011 0.23 U U U U U U U U U U U 0.40 J 0.40 J 0.40 J May-2012 0.23 U U U U U U U U 0.50 J U U U Nov-2012 0.23 U U U U U U U U U U U U U U U May-2013 0.23 U U U U U U U U U U U 0.30 J 1.30 J U DRY Nov-2013 Not Sampled May-2014 11 0.23 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.231.1 F 0.23U 3.30 J 3.00 J 0.23 U DRY Nov-2014 0.23 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U Damaged 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.30 J 0.23 U 0.23 U 0.23 U 0.30 J 0.23 U DRY May-2015 0.23 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.30 J 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.30 J 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U Nov-2015 0.23 0.23 U 0.23 U 0.40 J 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U May-2016 0.23 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U DRY 0.23 U 0.23 U 0.23 U 0.23 U 0.10 J 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U Nov-2016 0.23 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U DRY 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U DRY May-2017 0.23 0.231.1 0.231.1 0.231.1 0.231.1 0.231.1 0.231.1 0.23U 0.231.1 0.231.1 0.231.1 0.231.1 0.231J 0.231J 0.231J 0.231J 0.50 J 0.23U 0.231.1 0.23U 0.23U 0.23U 0.23U 0.231.1 Deo-2017 0.23 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.50 J 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U Jun-2018 0.23 -- U 2.60 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U 0.30 J -- U -- U -- U -- U -- U -- U Dry -- U -- U Dry Deo-2018 0.23 -- U 2.60 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U 0.24 J -- U -- U -- U -- U -- U -- U 0.38 J -- U -- U -- U Jun-2019 0.23 Deo-2019 Effective 11/1/2019 11 0.23 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyle detected above Method Detection Limit. 12. Bold red font indicates analyle detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyle detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity 3.30 0.00 3.00 0.00 0.40 0.00 0.40 0.00 Page 33 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Vinyl Chloride CAS No. 75-01.4 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Assort. BG Assmt. old B-20 Fac. BG BG BG Date MCL 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MW-7 MW-8 MW-9A MW-10 MW-II MW-12S MW-13 MW-14D MW-14S MW-15 MW-16 MW-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 0.015 - NO NO NO NO U 0.40 J U U U 0.50 J U U NO NO NO U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U 0.80 J U U U U U 1.90 J U U U U U U 3.00 J U U U NO NO Nov-01 - NO NO NO NO NO NO NO May-02 - NO NO NO NO NO NO NO Nov-02 - NO NO NO NO NO NO NO NO NO NO May-03 - NO NO NO NO NO NO NO NO NO NO NO NO Nov-03 - NO NO NO NO NO NO NO NO NO NO May-04 - NO NO NO NO NO NO NO NO NO NO Nov-04 - NO NO NO NO NO NO NO NO NO NO May-05 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-05 - NO NO NO NO NO NO NO NO NO NO May-06 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 - NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.34 E U U U U U U U U U U U U Jun-2007 0.34 U U U U U U U U U U U U Nov-2007 0.34 E U U U U U U U Dry U U May-2008 0.34 U U U U U U U U U U U U Nov-2008 0.34 E U U U U U U U U U U May_2009 0.34 U U U U U U U U U U U Aug-2009 Begin Assessment +Phase 2 0.15 INS INS U U INS INS INS INS U NS INS INS INS Jan-2010 0.63 U U U U U U U U U U U U U U U May-2010 0.63 U U U U U U U U U U U U U Nov-2010 0.63 U U U U U U U U U U U U U May-2011 0.63 U U U U U U U U U U U U U Nov-2011 0.63 U U U U U U U U U U U U U U U May-2012 0.63 U U U U U U U U U U U U U Nov-2012 0.63 U U U U U U U U U U U U U U U May-2013 0.63 U U U U U U U U U U U U U U Dry Nov-2013 Not Sampled May-2014 2 0.03 2.4 0.63 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 1.10 J 0.63 U 0.63 U 0.63U 0.63U 0.63 U 0.63 U 0.63 U Dry Nov-2014 0.63 0.63 U 0.63 U 2.00 0.63 U 0.63 U Damaged 0.63 U 0.63 U 1.40 0.63 U 0.63 U 0.63 U 3.40 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U Dry May-2015 0.63 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 1.70 J 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U Nov-2015 0.63 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.80 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U May-2016 0.63 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U DRY 0.63 U 0.63 U 0.63 U 0.63 U 1.90 J 0.63 U 3.70 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U Nov-2016 0.63 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U DRY 0.63 U 0.63 U 0.63 U 0.63 U 1.70 J 0.63 U 4.30 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U Dry May-2017 0.63 0.63U 0.63U 0.63U 0.63U 0.63U 0.63U 0.63U 0.63U 0.63U 0.63U 0.63U 0.63U 0.63U 1.10 J 0.63U 4.30 0.63U 0.63U 0.63U 0.63U 0.63U 0.63U 0.63U Deo-2017 0.63 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.90 J 0.63 U 3.70 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U 0.63 U Dry 0.63 U 0.63 U 0.63 U Jun-2018 0.63 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U 2.00 -- U -- U -- U -- U -- U -- U -- U -- U Dry -- U -- U Dry Deo-2018 MCL= 2 (NEW) 0.12 -- U -- U -- U -- U -- U 1.82 J 1.09 J -- U -- U 0.18 J 1.25 J 1.48 J -- U 2.20 -- U 2.21 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- Jun-2019 0.12 -- U -- UU -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U 1.77 0.69 3.33 -- U -- U 0.13 J -- U -- U -- U -- U -- U -- UDeo-2019 MU 0.12 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U-- U -- U 0.33 0.57 1.25 -- U -- U2.53 J -- U -- U -- U -- U -- U -- U -- 0.00 0.00 0.00 0.00 0.00 0.00 2.00 0.00 1.09 0.00 0.00 0.00 0.00 0.00 0.80 0.00 1.25 0.00 1.48 0.00 0.00 0.00 2.20 0.00 0.69 0.00 4.30 0.00 0.00 0.00 0.00 0.00 2.53 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyle detected above Method Detection Limit. 12. Bold red font indicates analyle detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyle detected above 21- Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 34 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Xylenes CAS No. 1330-20-7 Sample Compliance Limit (pg/L) MDL BG BG Assessment wells Assort. BG Assort. old B-20 Fac. BG BG BG Date MCL 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MW-13 MW-14D MW-14S MW-15 MW-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW-4 May-01 -- NO NO NO NO U U U U U U U U NO NO NO 2.77 J U U U U U U U U U U U U U U U U U U U U U U U U 11.70 J U U U U U U U U U U U U U U U U U U 3.30 J U U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68U 0.68 U NO NO Nov-01 - NO NO NO NO NO NO NO May-02 - NO NO NO NO NO NO NO Nov-02 - NO NO NO NO NO NO NO NO NO NO May-03 - NO NO NO NO NO NO NO NO NO NO NO NO Nov-03 - NO NO NO NO NO NO NO NO NO NO May-04 - NO NO NO NO NO NO NO NO NO NO Nov-04 - NO NO NO NO NO NO NO NO NO NO May-05 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-05 - NO NO NO NO NO NO NO NO NO NO May-06 - Damaged NO NO NO NO NO NO NO NO NO NO NO Nov-06 - NO NO NO NO NO NO NO NO NO NO May-07 Mandated Analytical Changes 0.48 E U U U U U U U U U U U U Jun-2007 0.48 U U U U U U U U U U U U Nov-2007 0.48 E NO U U U U U U Dry U U May-2008 0.48 E U NO U U U U U U U U U U Nov-2008 0.48 E NO U U U U U U U U U May-2009 0.48 U U U U U U U U U U U Aug-2009 Begin Assessment +Phase 2 0.07 NS NS 0.36 J U NS NS NS NS U NS NS NS NS Jan-2010 10,000 Soo 0.68 U U U U U U U U U U U U U U U May-2010 0.68 U U U U U U U U U U U U U Nov-2010 0.68 U U U U U U U U U U U U U May-2011 0.68 U U U U U U U U U U U U U Nov-2011 0.68 U U U U U U U U U U U U U U U May-2012 0.68 U U U U U U U U U U U U U Nov-2012 0.68 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U May-2013 0.68 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U Nov-2013 Not Sampled May-2014 0.68 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68U 0.68U 0.68 U 0.68 U 0.68 U Dry Nov-2014 0.68 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U Damaged 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.90 J 0.68 U 0.90 J 0.68 U 0.68 U 0.68 U Dry May-2015 0.68 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.681.1 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U Nov-2015 0.68 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U May-2016 0.68 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U DRY 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U Nov-2016 0.68 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U DRY 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.70 J 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U Dry May-2017 0.68 0.68U 0.68U 0.68U O.68U 0.68U 0.68U 0.68U O.68U 0.68U 0.68U 0.68U 0.68U 0.68U 0.68U 0.68U 1.50 J 0.68U 0.68U 0.68U 0.68U 0.68U 0.68U 0.681.1 Deo-2017 670 0.68 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 0.68 U 1.50 J 0.68 U 0.68 U 0.68 U 0.68 U o.68 U 0.68 U Dry 0.68 U 0.68 U 0.68 U Jun-2018 0.68 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U Dry -- U -- U Dry Deo-2018 0.68 -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U -- U - U -- U -- U -- U -- U -- U Jun-2019 0.68 Deo-2019 0.68 NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 35 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: 2,4-Dichlorophenoxyacetic acid (2,4-D) CAS No. 94-75-7 Herbicide/defoliant formerly a component of "Agent Orange" (still in widespread use) 8151 scan #1 Sample Compliance Limit (Pg/L) MDL BG BG Assessment Wells Assmt. BG Assmt. old B-20 Fac. BG BG BG Date 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MIN-4 MIN-5 MIN-6 MIN-7 MW-8 MW-9A MW-10 MIN-11 MW-12S MIN-13 MIN-14D MW-14S MIN-15 MIN-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW4 May-01 Nov-01 May-02 Nov-02 May-03 Nov-03 May-04 Nov-04 May-05 Nov-05 May-06 Nov-06 May-07 Mandated Analytical Changes Jun-2007 Nov-2007 May-2008 Nov-2008 May-2009 Aug-2009 Begin Assessment +Phase 2 0.61 0.6141J 0.630U 0.624U 0.613U 0.599U 0.6381.1 Jan-2010 70 0.36 - -- -- - May-2010 0.36 0.36U 0.361J 0.36U Nov-2010 0.36 0.36U 0.36U 0.36U May-2011 0.36 0.36U 0.361J 0.36U Nov-2011 0.36 0.36U 0.36U 0.36U May-2012 0.36 0.36U 0.361J 0.86 J Nov-2012 0.36 0.36U 0.36U 0.36U 0.36U 0.36U 0.36U May-2013 0.36 0.36U 0.36U 0.36U 0.36U 0.36U 0.36U Nov-2013 May-2014 0.36 0.36U 0.36U 0.36U 0.36U 0.36U 0.36 U 0.36 U Nov-2014 0.36 0.36U 0.36U 0.36U 0.36U 0.36U May-2015 0.36 0.36U 0.36U 0.36U 0.36U 0.36U Nov-2015 0.36 0.36U 0.36U 0.36U 0.36U 0.36U May-2016 0.36 0.36U 0.36U 0.36U 0.36U 0.36U Nov-2016 0.36 0.36U 0.36U 0.36U 0.36U 0.36U May-2017 0.36 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U Deo-2017 0.36 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U Jun-2018 0.36 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U Deo-2018 0.36 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U Jun-2019 0.36 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U Deo-2019 0.36 0.36 U 0.36 U 03611 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 36 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: 6-sec-butyl-2,4-dinitrophenol (Dinoseb) CAS No. 88-85-7 Herbicide/defoliant (banned since 1986) 8151 scan #2 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Assmt. BG Assmt. old B-20 Fac. BG BG BG Date IMAC 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MIN-6 MW-7 MW-8 MW-9A MW-10 MIN-11 MW-12S MW-13 MIN-14D MW-14S MW-15 MW-16 MIN-17 old B-1s SW-1 SW-2 SW-3 SW4 May-01 - - Nov-01 May-02 Nov-02 May-03 Nov-03 May-04 Nov-04 May-05 Nov-05 May-06 Nov-06 May-07 Mandated Analytical Changes Jun-2007 Nov-2007 May-2008 Nov-2008 May-2009 - Aug-2009 Begin Assessment +Phase 2 - Jan-2010 7 0.54 - -- -- May-2010 0.54 0.541J 0.541J 0.541J Nov-2010 0.54 0.541J 0.541J 0.541J May-2011 0.54 0.82 J 0.54U 0.54U EEI Nov-2011 0.54 0.541J 0.541J 0.541J May-2012 0.54 0.541J 0.541J 0.541J Nov-2012 0.54 0.54U 0.541J 0.541J 0.54U 0.541J 0.54U May-2013 0.54 0.54U 0.54U 0.54U 0.54U 0.54U 0.54U Nov-2013 AM May-2014 0.54 0.54U 0.54U 0.54U 0.54U 0.54U 0.54 U 0.54 U Nov-2014 0.54 0.54U 0.541J 0.541J 0.541J 0.541J May-2015 0.54 0.541J 0.541J 0.54U 0.541J 0.541J Nov-2015 0.54 0.54U 0.541J 0.541J 0.541J 0.541J May-2016 0.54 0.541J 0.541J 0.54U 0.541J 0.541J Nov-2016 0.54 0.54U 0.541J 0.541J 0.541J 0.541J May-2017 0.54 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U Deo-2017 0.54 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.42 U 0.54 U Jun-2018 0.54 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.42 U 0.54 U Deo-2018 0.54 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U Jun-2019 0.54 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U Deo-2019 0.54 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U 0.5411 0.54 U 0.54 U 0.54 U 0.54 U 0.54 U NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 21- Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 37 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: 2-(2,4,5-Trichlorophenoxy) propionic acid (2,4,5-TP), (Sil-) CAS No. 93-72-1 Herbicide/defoliant (banned since 1985) 8151 scan 43 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Assmt. BG Assmt. old B-20 Fac. BG BG BG Date 2L Std 2B Sld pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MIN-4 MW-5 MIN-6 MIN-7 MW-8 MW-9A MW-10 MIN-11 MW-12S MIN-13 MIN-14D MW-14S MIN-15 MIN-16 MIN-17 old B-is SW-1 SW-2 SW-3 SW4 May-01 Nov-01 May-02 Nov-02 May-03 Nov-03 May-04 Nov-04 May-05 Nov-o5 May-0 Nov-O66 May-07 Mandated Analytical Changes Jun-2007 Nov-2007 May-2008 Nov-2008 May-2009 Aug-2009 Begin Assessment +Phase 2 0.61 0.6141J 0.630U 0.624U 0.613U 0.5991J 0.6381.1 Jan-2010 50 0.42 - -- -- - May-2010 0.42 0.74 J 0.42U 0.42U Nov-2010 0.42 0.42U 0.42U 0.42U May-2011 0.42 0.42U 0.42U 0.42U Nov-2011 0.42 0.42U 0.42U 0.42U May-2012 0.42 0.42U 0.42U 0.42U Nov-2012 0.42 0.42U 0.42U 0.42U 0.42U 0.42U 0.42U May-2013 0.42 0.42U 0.42U 0.42U 0.42U 0.42U 0.42U Nov-2013 May-2014 0.42 0.42U 0.43 J 0.42U 0.42U 0.42U 0.42 U 0.42 U Nov-2014 0.42 0.42U 0.42U 0.42U 0.42U 0.42U May-2015 0.42 0.42U 0.42U 0.421J 0.42U 0.42U Nov-2015 0.42 0.42U 0.42U 0.42U 0.42U 0.42U May-2016 0.42 0.42U 0.42U 0.421J 0.45 J 0.42U Nov-2016 0.42 0.42U 0.42U 0.42U 0.42U 0.42U May-2017 0.42 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U o.42 U 0.42 U 0.42 U 0.42 U Deo-2017 0.42 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42EU 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U Jun-2018 0.42 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U Deo-2018 0.42 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 2.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U Jun-2019 0.42 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U o.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U Deo-2019 0.42 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U 0.42 U NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)' in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 38 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: 2,4,5-trichlorophenoxyacetic acid 2,4,5-T CAS No. 93-76-5 Herbicide/defoliant formerly a component of "Agent Orange" (banned since 1985) 8151 scan N4 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Assmt. BG Assmt. old B-20 Fac. BG BG BG Date 2L Std 2B Sld pgIL MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MIN-4 MIN-5 MIN-6 MIN-7 MW-8 MW-9A MW-10 MIN-11 MW-12S MIN-13 MIN-14D MW-14S MIN-15 MIN-16 MIN-17 old B-Is SW-1 SW-2 SW-3 SW-4 May-01 Lo4U Nov-01 May-02 Nov-02 May-03 Nov-03 May-04 Nov-04 May-05 Nov-05 May-06 Nov-06 May-07 Mandated Analytical Changes Jun-2007 Nov-2007 May-2008 Nov-2008 May-2009 Aug-2009 Begin Assessment +Phase 2 0.61 0.630U 1 0.624U 0.613U 0.599U 0.6381.1 Jan-2010 NE 1 0.47 - -- -- - May-2010 0.47 0.47U 0.47U 0.47U Nov-2010 0.47 0.47U 0.47U 0.47U May-2011 0.47 0.47U 0.47U 0.47U Nov-2011 0.47 0.47U 0.47U 0.47U May-2012 0.47 0.47U 0.47U 0.77 J Nov-2012 0.47 0.47U 0.47U 0.47U 0.47U 0.47U 0.47U May-2013 1 0.47 0.47U 0.47U 0.47U 0.47U 0.47U 1.14 J Nov-2013 AM May-2014 0.47 0.47U 0.47U 0.47U 0.47U 0.47U 0.47 U 0.47 U Nov-2014 0.47 0.47U 0.47U 0.47U 0.47U 0.47U May-2015 0.47 0.47U 0.47U 0.47U 0.47U 0.47U Nov-2015 0.47 0.47U 0.47U 0.47U 0.47U 0.47U May-2016 0.47 0.47U 0.47U 0.47U 0.47U 0.47U Nov-2016 0.47 0.47U 0.47U 0.47U 0.47U 0.47U May-2017 0.47 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U Deo-2017 0.47 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U Jun-2018 0.47 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U o-20180.47 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U n-20190.47 PD 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U c-2019 0.47 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)' in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 39 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: beta-BHC CAS No. 319.85.7 Byproduct of Lindane Pesticide banned in 1985 8081 scan 43 Sample Compliance Limit (pglL) MDL BG BG Assessment Wells Assmt. BG Assmt. old B-20 Fac. BG BG BG Date IMAC 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MIN-4 MW-5 MIN-6 MW-7 MW-8 MW-9A MW-10 MIN-11 MW-12S MW-13 MW-14D MW-14S MIN-15 MIN-16 MW-17 old B-Is SW-1 SW-2 SW-3 SW4 May-01 0.0165U L Nov-01 May-02 Nov-02 May-03 Nov-03 May-04 Nov-04 May-05 Nov-05 May-06 Nov-06 May-07 d Analytical Changes Jun-2007 Nov-2007 May-2008 Nov-2008 May-2009 Aug-2009 Begin Assessment +Phase 2 0.01 0.02 J 0.01701.1 0.0173U 0.0165U Jan-2010 0.02 0.03 May-2010 0.03 0.031 U 0.031 U 0.031 U Nov-2010 0.03 0.031 U 0.031 U 0.031 U May-2011 0.03 0.031 U 0.031 U 0.031 U Nov-2011 0.03 0.031 U 0.031 U 0.031 U May-2012 0.03 0.031 U 0.031 U 0.031 U Nov-2012 0.03 May-2013 0.03 Nov-2013 May-2014 0.03 0.31U 0.31U Nov-2014 0.03 0.031 U 0.031 U 0.031 U 0.031 U 0.031 U May-2015 0.03 Nov-2015 0.03 0.031 U 0.031 U 0.031 U 0.031 U 0.031 U May-2016 0.03 0.031 U 0.031 U 0.031 U 0.031 U 0.031 U Nov-2016 0.03 0.031 U 0.031 U 0.031 U 0.031 U 0.031 U May-2017 0.03 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31 U 0.31U 0.31U 0.31U 0.31U 0.31 U 0.31U 0.31U Dec-2017 0.03 0.31U 0.31U 0.316 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U Jun-2018 0.031 0.31U 0.31U 0.31U 0.31U 0.31U 0.04 J 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U o-2018 0.031 0.31U 0.31U 0.31U 0.31U 0.31U 0.04 J 0.31U 031U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 031U0.31U 0.31U n-2010.031 PD 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U o-2019 0.031 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.31U 0.07 J 0.31U 0.31U 0.3111 0.31U 0.31U 0.31U NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 21- Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 40 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Aldrin CAS No. 309-00-2 Pesticide (banned in 1990's) 8081 scan #1 Sample Compliance Limit (Pg/L) MDL BG BG Assessment Wells Assmt. BG Assmt. old B-20 Fac. BG BG BG Date IMAC 2L Std 2B Std Pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MIN-6 MW-7 MW-8 MW-9A MW-10 MIN-11 MW-12S MW-13 MIN-14D MW-14S MW-15 MW-16 MIN-17 old B-Is SW-1 SW-2 SW-3 SW4 May-01 0.0106U Nov-01 May-02 Nov-02 May-03 Nov-03 May-04 Nov-04 May-05 Nov-05 May-06 Nov-06 May-07 d Analytical Changes Jun-2007 Nov-2007 May-2008 Nov-2008 May-2009 Aug-2009 Begin Assessment +Phase 2 0.01 0.0106U 0.0108U 0.0110U 0.0111U 0.0106U Jan-2010 0.002 0.03 May-2010 0.03 0.029U 0.029U 0.029U Nov-2010 0.03 0.029U 0.029U 0.029U May-2011 0.03 0.029U 0.029U 0.029U Nov-2011 0.03 0.029U 0.029U 0.029U May-2012 0.03 0.029U 0.029U 0.029U Nov-2012 0.03 May-2013 0.03 Nov-2013 May-2014 0.03 0.029U 0.029U Nov-2014 0.03 0.029U 0.029U 0.029U 0.029U 0.029U May-2015 0.03 Nov-2015 0.03 0.029U 0.029U 0.029U 0.029U 0.029U May-2016 0.03 0.029U 0.029U 0.029U 0.029U 0.029U Nov-2016 0.03 0.029U 0.029U 0.029U 0.029U 0.029U May-2017 0.03 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U Deo-2017 0.03 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U Jun-2018 0.029 0.029U 0.029U 0.029U 0.029U 0.029U 0.03 J 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U Deo-2018 0.029 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U Jun-2019 0.029 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U Deo-2019 0.029 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U o.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U 0.029U NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 21- Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-1s is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 41 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Acenaphthene CAS No. 8332-9 PAH 8270 scan #1 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Assmt. BG Assmt. old B-20 Fac. BG BG BG Date 2L Std 2B Sld pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MW-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MIN-13 MIN-14D MW-14S MW-15 MIN-16 MIN-17 old B-1s sW-1 SW-2 SW-3 SW-4 May-01 Nov-01 May-02 Nov-02 May-03 Nov-03 May-04 Nov-04 May-05 Nov-05 May-06 Nov-06 May-07 Mandated Analytical Changes Jun-2007 Nov-2007 JL May-2008 Nov-2008 May-2009 Aug-2009 Begin Assessment + Phase 2 1.20 4.65 1.14 U 1.231.1 1.20U 1.201.1 Jan-2010 80 May-2010 2.66 2.66U 2.66U 2.66U Nov-2010 2.66 2.661.1 2.66U 2.66U May-2011 2.66 2.66U 2.66U 2.66U Nov-2011 2.66 2.66U 2.66U 2.66U May-2012 2.66 2.66U 2.66U 2.66U Nov-2012 2.66 May-2013 2.66 Nov-2013 AM May-2014 2.66 2.66U 2.66U 2.66U 2.66U 2.66U 2.66U 2.66U Nov-2014 2.66 2.66U 2.66U 2.66U 2.66U 2.66U May-2015 2.66 2.66U 2.66U 2.661.1 2.66U 2.66U Nov-2015 2.66 2.66U 2.66U 2.66U [12.66U 2.66U 2.66U May-2016 2.66 2.66U 4.04 J 2.66U 2.66U 2.66U Nov-2016 2.66 2.66U 10.24 J 2.66U 2.66U 2.66U May-2017 2.66 2.661.1 2.661.1 2.661.1 2.661.1 2.66U 2.66U 2.66U 2.661.1 2.661.1 2.661.1 2.661.1 2.661.1 2.66U 2.66U 2.66U Deo-2017 2.66 2.66U 2.80 J 2.66U 2.66U 2.66U 5.70 J 2.66U 2.66U 2.66U 2.66U 2.66U 2.66U 2.66U 2.66U 2.66U 2.66U 2.66U 2.66U 2.66U 2.66 UM324 Jun-2018 2.66 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 5.80 J 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U Deo-2018 2.66 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 24.30 3.10 J 2.66 U 2.66 U 2.66 U 2.6fl U 3.57 J 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U Jun-2019 2.66 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 8.10 J 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 UDeo-2019 2.66 2.66 U 2.66 U 2.66 U 2.88 J 2.66 U 3.57 J 3.30 J 2.66 U 266 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 42 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Benzo0perylene CAS No. 191-24-2 PAH 8270 scan #7 sample Compliance Limit (pglL) MDL BG BG Assessment Wells Assmt. BG Assmt. old B-20 Fac. BG BG BG Date 2L Std 2B Std pglL MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MIN-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MIN-13 MIN-14D MW-14S MW-15 MIN-16 MIN-17 old B-Is SW-1 SW-2 SW-3 SW4 May-01 1.21U 1.20U L Nov-01 May-02 Nov-02 May-03 Nov-03 May-04 Nov-04 May-05 Nov-05 May-06 Nov-06 May-07 d Analytical Changes Jun-2007 Nov-2007 May-2008 Nov-2008 May-2009 1.24U 1.061.1 1.061.1 Aug-2009 Begin Assessment +Phase 2 1.06 Jan-2010 200 May-2010 2.61 2.61U 2.61U 2.61U Nov-2010 2.61 2.61U 2.61U 2.61U May-2011 2.61 2.61U 2.61U 2.61U Nov-2011 2.61 2.61U 2.61U 2.61U May-2012 2.61 2.61U 2.61U 2.61U Nov-2012 2.61 May-2013 2.M Nov-2013 May-2014 2.61 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U Nov-2014 2.61 2.61U 2.61U 2.61U 2.61U 2.66U May-2015 2.61 Nov-2015 2.61 2.61U 2.61U 2.61U 2.61U 2.66U May-2016 2.61 2.61U 2.61U 2.61U 2.61U 2.61U Nov-2016 2.61 2.61U 2.61U 2.61U 2.61U 2.61U May-2017 2.61 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.611.1 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U Deo-2017 2.61 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U Jun-2018 2.61 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 161U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U Deo-2018 2.61 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 3.16 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U Jun-2019 2.61 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U Deo-2019 2.61 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U 2.61U NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 43 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Diberaofuran CAS No. 132-64-9 Coal -tar derivative, aromatic, used as insecticide 8270 scan #62 Sample Compliance Limit (pg/L) MDL BG BG Assessment Wells Assmt. BG Assmt. old B-20 Fao. BG BG BG Date IMAC 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MIN-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MIN-13 MW-14D MW-14S MIN-15 MIN-16 MIN-17 old B-Is SW-1 SW-2 SW-3 SW4 May-01 1.89 JL Nov-01 May-02 Nov-02 May-03 Nov-03 May-04 Nov-04 May-05 Nov-05 May-06 Nov-06 May-07 d Analytical Changes Jun-2007 Nov-2007 May-2008 Nov-2008 May-2009 Aug-2009 Begin Assessment +Phase 2 1.37 1.30U 1.401.1 1.37U 1.371.1 Jan-2010 28 May-2010 4.28 4.28U 4.28U 4.28U Nov-2010 4.28 4.28U 4.28U 4.28U May-2011 4.28 4.28U 4.28U 4.28U Nov-2011 4.28 4.28U 4.28U 4.28U May-2012 4.28 4.28U 4.28U 4.28U Nov-2012 4.28 May-2013 4.28 Nov-2013 May-2014 4.28 4.28U 4.28U 4.28U 4.28U 4.2BU 4.28U Nov-2014 4.28 4.28U 4.28U 4.281.1 4.28U 4.28U May-2015 4.28 Nov-2015 4.28 4.28U 4.28U 4.28U 4.28U 4.28U May-2016 4.28 4.28U 4.28U 4.281.1 14.28U,4.28U 4.28U 4.28U Nov-2016 4.28 4.28U 4.28U 4.28U 4.28U 4.28U May-2017 4.28 4.281.1 4.281.1 4.28U 4.281.1 4.281.1 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U Deo-2017 4.28 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U n-2018 4.28 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 184.28 4.28U 4.28U 4.28U 4.28U 4.28U 9.19 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U194.28 OD 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28U 4.28Uo-2019 4.28 4.28U 4.28U 4.28U 4.28U 4.281.1 4.281.1 4.28U 4.281.1 4.281.1 4.281.1 4.281.1 4.281.1 4.281.1 4.281.1 4.281.1 4.281.1 4.28U 4.281.1 4.281.1 4.281.1 4.281.1 4.28U NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)' in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 44 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Endrin Aldehyde CAS No. 7421-93-4 Breakdown product of pesticide Endrin, banned since 1986 8081 scan #15 sample Compliance Limit (PgIL) MDL BG BG Assessment Wells Assmt. BG Assmt. old B-20 Fac. BG BG BG Date 2L Std 2B Std pglL MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MIN-5 MIN-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MIN-13 MIN-14D MW-14S MIN-15 MIN-16 MIN-17 old B-Is SW-1 SW-2 SW-3 SW4 May-01 0.0477U L Nov-01 May-02 Nov-02 May-03 Nov-03 May-04 Nov-04 May-05 Nov-05 May-06 Nov-06 May-07 Jun-2007 Nov-2007 May-2008 Nov-2008 May-2009 Aug-2009 Begin Assessment+Phase 2 0.05 0.0474U 0.053U 0.05011.1 0.0477U Jan-2010 2 May-2010 0.05 0.0531.1 0.0531.1 0.053U Nov-2010 0.05 0.0531.1 0.0531.1 0.0531.1 May-2011 0.05 0.0531.1 0.0531.1 0.053U Nov-2011 0.05 0.0531.1 0.0531.1 0.0531.1 May-2012 0.05 0.0531.1 0.0531.1 0.053U Nov-2012 0.05 May-2013 0.05 Nov-2013 May-2014 0.05 Nov-2014 0.05 0.0531.1 0.0531.1 0.053U 0.0531.1 0.0531.1 May-2015 0.05 Nov-2015 0.05 0.0531.1 0.0531.1 0.0531.1 0.0531.1 0.0531.1 May-2016 0.05 0.0531.1 0.0531.1 0.0531.1 0.053U 0.053U Nov-2016 0.05 0.0531.1 0.0531.1 0.0531.1 0.0531.1 0.0531.1 May-2017 0.05 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U Deo-2017 0.05 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053UEO.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U Jun-2018 0.053 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U Deo-2018 0.053 0.053U 0.053U 0.053U 0.053U 0.053U 0.10 J 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U0.053U 0.053U 0.053UJun-2019 0.053 0.053U 0.053U 0.053U 0.08 J 0.053U 0.053U 0.07 J 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053UDeo-2019 0.053 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0053U 0053U 0053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U 0.053U NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 45 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Fluorene CAS No. 86-73-7 Considered a PAH generated by incomplete combustion 8270 scan #26 sample Compliance Limit (Pg/L) MDL BG BG Assessment Wells Assmt. BG Assmt. old B-20 Fac. BG BG BG Date 2L Std 2B Std pg/L MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MW-5 MIN-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MIN-13 MIN-14D MW-14S MIN-15 MIN-16 MIN-17 old B-Is SW-1 SW-2 SW-3 SW4 May-01 1.38U L Nov-01 May-02 Nov-02 May-03 Nov-03 May-04 Nov-04 May-05 Nov-05 May-06 Nov-06 May-07 Jun-2007 Nov-2007 May-2008 Nov-2008 May-2009 Aug-2009 Begin Assessment + Phase 2 1.38 1.37U 1.41U 1.381.1 1.381.1 Jan-2010 300 May-2010 2.95 2.951J 2.95U 2.95U Nov-2010 2.95 2.95U 2.95U 2.95U May-2011 2.95 2.95U 2.95U 2.95U Nov-2011 2.95 2.95U 2.95U 2.95U May-2012 2.95 2.95U 2.95U 2.95U Nov-2012 2.95 May-2013 2.95 Nov-2013 May-2014 2.95 2.95U 2.95U 2.95U 2.95U 2.951-1 2.95U Nov-2014 2.95 2.95U 2.95U 2.951.1 2.951.1 2.951J May-2015 2.95 2.95U 2.951J 2.951.1 2.95U 2.951J Nov-2015 2.95 2.95U 2.95U 2.95U 2.951J 2.951J May-2016 2.95 2.95U 2.951J 2.951.1 2.95U 2.951J Nov-2016 2.95 2.95U 2.95U 2.95U 2.951J 2.951J May-2017 2.95 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.951.1 2.951.1 2.951.1 2.951.1 2.951.1 2.95U 2.951.1 2.951.1 2.95 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95UJun-20182.95 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 295U 2.95U 2.95U eo-20182.95 2.95U 2.95U 2.95U 2.95U 2.95U 13.90 J 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U Jun-20192.95 ii�De 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U eo-2019 2.95 2.95U 2.95U 2.95U 2.95U 2.95U 5.31 J 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U 2.95U NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 46 of 48 Appendix 2 Historical Data For Selected Analytes Parameter: Ideno[]pyrene CAS No. 193-395 PAH 8270 scan #29 sample Compliance Limit (pglL) MDL BG BG Assessment Wells Assmt. BG Assmt. old B-20 Fac. BG BG BG Date 2L Std 2B Sld pglL MW-ID MW-1S MW-2D MW-2S MW-3D MW-3S MW-3A MW-4 MIN-5 MIN-6 MW-7 MW-8 MW-9A MW-10 MW-11 MW-12S MIN-13 MIN-14D MW-14S MIN-15 MIN-16 MIN-17 old B-Is SW-1 SW-2 SW-3 SW4 May-01 1.12U 1.11U L Nov-01 May-02 Nov-02 May-03 Nov-03 May-04 Nov-04 May-05 Nov-05 May-06 Nov-06 May-07 Jun-2007 Nov-2007 May-2008 Nov-2008 May-2009 1.15U 1.12U 1.121.1 Aug-2009 Begin Assessment+Phase 2 1.12 Jan-2010 0.05 May-2010 2.91 2.91U 2.91U 2.91U Nov-2010 2.91 2.91U 2.91U 2.91U May-2011 2.91 2.91U 2.911J 2.91U Nov-2011 2.91 2.91U 2.91U 2.91U May-2012 2.91 2.91U 2.911J 2.91U Nov-2012 2.91 May-2013 2.95 Nov-2013 May-2014 2.91 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U Nov-2014 2.91 2.91U 2.91U 2.91U 2.91U 2.91U May-2015 2.91 2.91U 2.91U 2.91U 2.91U 2.91U Nov-2015 2.91 2.91U 2.91U 2.91U 2.91U 2.91U May-2016 2.91 2.91U 2.91U 2.91U 2.91U 2.91U Nov-2016 2.91 2.91U 2.91U 2.91U 2.91U 2.91U May-2017 2.91 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U Deo-2017 2.91 2.91U 2.91U 2.91U 2.91U 2.91U 2.911.1 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U Jun-2018 2.91 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U Deo-2018 2.91 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 3.06 J 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U Jun-2019 2.91 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U Deo-2019 2.91 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U 2.91U NOTES: 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard - NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)* in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 47 of 48 Appendix 2 Historical Data For Selected Analytes rr•Begin Assessment Phase 2 USEPA drinking water advisory 15 NOTES' 1. This table shows a historic summary of the monitoring data. With respect to VOC's, only those constituents that have been detected are included. 2. SWSL = Solid Waste Section Limit (June 13, 2011). 3. 2L Standard — NCAC Title 15A Subchapter 2L Classifications and Water Quality Standards Applicable to the GWs of North Carolina (April 1, 2013). 4. 2B Standard = Standards, criteria, or toxic concentrations either adopted per 15A NCAC 2B or National Criteria per EPA (Current as of 5/15/2013). 5. MDL = Method Detection Limit. 6. µg/L = micrograms per liter. mg/L = milligrams per liter. 7. ND = not detected above the method detection limit (MDL) under old analytical requirements. 8. < (Value) or (Value) U = not detected above MDL under new analytical requirements. 9. (Value) J = detected result is above MDL and below the Compliance limit. 10. NA = Not Analyzed or Not Applicable. NE = Not Established. NS = Not Sampled. 11. Red font indicates analyte detected above Method Detection Limit. 12. Bold red font indicates analyte detection above the SWSL but below the 2L Standard. 13. Yellow shading indicates analyte detected above 2L Standard. 14. Blank cell shaded blue indicates the well was not in the sampling program at the time of the sampling event. 15. Blank cell shaded green indicates the well was in the sampling program but not sampled. 16. Purple shading indicates initial Assessment Sampling event, including upgradient wells for delineation. 17. (Value)' in the 2L Standard column denotes a Groundwater Protection Standard assigned by Solid Waste Section (6/13/2011) 18. Old B-ls is located near the northeast facility boundary and is not influenced by any known solid waste activity Page 48 of 48 C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 1 Appendix 3 Final Cover Evaluation 1.1 Background C&D Landfill, Inc. operated Phase 1 after June 30, 2008, which technically put the Facility under Solid Waste Rule 15A NCAC 13B .0543. The rule requires capping the landfill with a 3-feet thick soil cover, the lower 18 inches of which is required to meet soil type, compaction, and permeability Requirements. A major portion of the cover, i.e., side slopes, was installed incrementally pursuant to Solid Waste Section guidance. Although the Operator in charge of the cover was an experienced, former earthwork contractor, unfortunately no portion of the final cover received professional oversight and testing, per the .0543 requirements. The Owner and Operator did understand the final cover thickness, soil type and density requirements. Summit performed a "retroactive" evaluation of the cover using test pits, in -situ density, direct measurement of layer thickness. A two -stage investigation program was outlined in a letter to the SWS (Attachment 1) requesting approval of the evaluation process. Originally, it was intended to field classify the soils from the excavations, collect samples for laboratory testing, and perform the field density testing. Based on the results of this stage, the samples would be tested in a geotechnical laboratory for grain size analysis and permeability testing. However, a decision was made based on the field evaluation (Attachment 2), not to perform the permeability tests because the sandy soils exhibited low compaction density and were not expected to pass the permeability requirements. 1.2 Alternative Cover Decision Process The existing cover has adequate thickness on the slope, but not on the flatter, upper cap area (approximately 2 acres). Vegetation is well established and appeared healthy and robust over most of the surface. The Owner acknowledged a "lot of work" had gone into maintaining and continually improving the vegetation. Photos of the cover conditions and vegetation (in May 2020) are presented following this text. There are several gently sloping erosion control benches that provide access to the slopes. Erosion issues are very minor, based on the Engineer's opinion. Conditions were very different on the upper cap area, where cover soil thicknesses were typically 12 to 18 inches, based on the test pits. The Engineer believes the final cover on the slopes is adequate for shedding water and isolating the waste. Whereas this portion of the landfill were "closed" before the cutoff date, on the Owner's behalf, a proposal is hereby made to install a .0543 cover on the 2-acre upper cap area and leave the side slopes with even more effort to enhance the vegetation. Final closure of Phase 1 is part of the selected remedy for the Correction Action Plan under which this document was prepared. A generalized closure plan borrowed from the Phase 2B Permit to Construct is included as Appendix 4, in the spirit of meeting CAP preparation guidance, which asks for plans, specifications, operations and maintenance for equipment or appurtenances installed to implement the remedy. It is realized the closure portion must undergo separate review and approval process. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 2 C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 3 C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 4 SUMMIT DESIGN AND ENGINEERING SERVICES March 18, 2020 NC DEQ - DWM Solid Waste Section 217 W Jones Street Raleigh, NC 27603 Attn: Sherri Stanley - Permitting Branch Head Attachment 1 320 Executive Court, Hillsborough, NC 27278 Phone // 919.732.3883 Web // www.summitde.net Ethan Caldwell, P.E., P.G. - Raleigh Central Office RE: C&D Landfill, Inc., Phase 1 CDLF Final Closure Advance Notification Dear Sherri and Ethan: On behalf of C&D Landfill, Inc., I am pleased to inform you that work is progressing toward the final closure of Phase 1 of the referenced site. Pursuant to prior conversations, I wish to inform you of necessary changes to the approved Final Closure and CQA Plans. Background C&D Landfill, Inc., Phase 1 covers an approximate rectangular area of a maximum 15 acres (as permitted), with 3H:1V side slopes and a 5% cap area covering approximately 2.2 acres. The permitted cover consists of an 18-inch thick layer of "topsoil" over 18 inches of compacted soil barrier, with a maximum hydraulic conductivity of 1 x 10-5 cm/sec. As permitted, the soil barrier is underlain by an interim cover soil, then inert wastes. The approved CQA Plan specifies a testing schedule for verification of in -situ soil density and hydraulic conductivity, discussed below, which is normally performed as the cover is installed. On this project, however, the cover soils have been placed without engineering oversight and testing, albeit by an experienced earthwork contractor, thus a retroactive investigation is needed to confirm the soils comply with the properties defined in the approved CQA Plan. An excerpt from the February 2014 Permit to Construct application (same as November 2014), i.e., the CQA Plan, can be found as Attachment 1. Table 4C in the attachment shows hydraulic conductivity testing at a rate of one per acre, and moisture -density testing at a rate of four per acre (total of 5 locations per acre) for each lift of the compacted soil barrier. Typically, the soil barrier is placed (and tested) in three lifts of 6 inches thickness (after compaction). Check plug samples are typically collected and returned to a soil lab for permeability testing in a triaxial cell. C&D Landfill Phase 1 Page 2 Field moisture -density testing is commonly performed with a nuclear density gauge, targeting 90 to 95% of the maximum dry density (MDD). Note #2 states that hydraulic conductivity (permeability) is the parameter used for pass/fail criteria, not density; that is, moisture -density (easily tested in the field) is used to reference a predetermined relationship with the permeability. The Engineer has the latitude to be flexible with the density readings, provided the test results are within the optimal range of the moisture -density -permeability relationship. Scope We are proposing that the cover be evaluated retroactively, facilitated with shallow test pits at the prescribed frequency to access the soils at depth intervals of 18, 24, and 30 inches. The soils below each depth interval will be visually classified in the field by a trained technician (ASTM D-2488) and representative samples will be collected, one per test pit location, providing the soils are consistent with depth in the technician's opinion. A calibrated nuclear density gauge will be used to measure the moisture and density of the soils at each interval (ASTM D-2922). At check plug sample will be collected every fifth test pit and returned to the lab; one sample is enough, providing the soils are consistent within the full 18-inch thickness of the barrier layer. Upon completing the testing and sampling —this is critically important —the test pits will be backfilled, and the barrier layer will be constructed in three compacted lifts with nuclear density testing on each lift. Barrier soils will be tamped to reflect the surrounding soil. Topsoil is not tested, but care should be taken not to mix the topsoil and the barrier soil when digging the test pit. A numbered wooden marker stake will be left at each test pit location. Each stake will be flagged with high visibility tape. Future surveying may be performed to verify final grades and topography. Figure 1 depicts the proposed test pit targets. The test pits are numbered sequentially 1 — 45 to provide 5 test pits per acre. Collecting a check plug every fifth test pit implies 8 soil density tests (ASTM D-2937), based on the standard Proctor curve (ASTM D-2922 and ASTM D-698), and 8 hydraulic conductivity tests (ASTM D-5084). In addition, the 45 soil samples from the barrier layer will be visually classified by a geotechnical engineer (ASTM D-2488). Depending on soil consistency, a representative subset of these samples will be submitted to the laboratory for classification (ASTM D-6913 and related procedures). Discussion This approach is not uncommon, especially with the older landfills closures a few years ago, but a flaw was recently noticed that we wish to avoid moving forward. The lack of density testing of the soils going back into the test pits was spawned disagreements with the SWS as to whether the final cover had been compromised. Without addressing the concerns on earlier projects, we are seeking the Section's approval, in advance, of the prescribed deviation from the approved CQA plan. Please contact me with questions or concerns. David Garrett, PE TABLE 4B CQA TESTING SCHEDULE FOR DRAINAGE AND FINAL COVER SOIL COMPONENT PROPERTY TEST METHOD MINIMUM TEST FREQUENCY RECORD TESTS: Coarse Aggregate: Confirm Gradation Visual 5,000 CY' Vegetative Soil Layer: (In -Situ Verification) Visual Classification ASTM D 2488 1 per acre Layer Thickness Direct measure 4 Survey Notes: A quarry certification is acceptable for aggregate from a commercial quarry. If a byproduct is used, i.e., crushed concrete aggregate, the gradation test frequency may be adjusted based on project specific conditions. The Engineer shall approve all materials and alternative test frequencies. Materials that do not meet relevant ASTM or ASHTO standard gradation specifications (either may be used at the discretion of the Engineer) shall be rejected. TABLE 4C CQA TESTING SCHEDULE FOR FINAL COVER COMPACTED SOIL BARRIER PROPERTY TEST METHOD MINIMUM TEST FREQUENCY RECORD TESTS: Lift Thickness Direct measure Survey4 Permeability ASTM D5084' 1 per acre per lift In -Place Density ASTM D 29222 4 per acre per lift Moisture Content ASTM D 30173 4 per acre per lift Notes: 1. Optionally use ASTM D6391. Maximum allowable soil permeability is I x I0"5 cm/sec; higher permeability results in a failed test and the lift must reworked and retested. 2. Optionally use ASTM D 1556, ASTM D 2167, or ASTM D 2937. For every 10 nuclear density tests perform at least 1 density test by ASTM D 1556, ASTM D 2167, or ASTM D 2937 as a verification of the accuracy of the nuclear device. Minimum required density is dependent on the moisture -density -permeability characteristic developed for the specific soil during initial construction; lower density or incorrect moisture may result in higher permeability. Permeability criteria shall govern the determination of a passing test. 3. Optionally use ASTM D 2216, ASTM D 4643, or ASTM D 4959. For every ten nuclear - moisture tests, perform at least 1 moisture test by ASTM D 2216, ASTM D 4643, or ASTM D 4959 as a verification of the accuracy of the nuclear testing device. 4. Topographic graphic survey by licensed surveyor C&D Landfill, Inc., Solid Waste Permit #74-07 (Rev. 3.0) February 2014 Phase 2A - PTO and Phase 213 - PTC Application Construction Plan Page 44 TPage 1 of 1 Attachment 2 SUMMIT 320 Executive Court, Hillsborough, NC 27278 DESIGN AND ENGINEERING SERVICES Phone // 919.732.3883 Web // www.summitde.net DAILY FIELD REPORT PROJECT NO: 19-0248.003 CLIENT: C&D Landfill, Inc. PROJECT: C&D Landfill Phase 1 WEATHER/TEMP: Clear/70s START END TOTAL DATE TIME TIME HOURS 4/29/20 0700 1600 9 FIELD TESTS PERFORMED Soil density REMARKS: Technician arrived on site as requested to observe placement of fill material in the following location: Phase 1 landfill cap. Tests were performed on this date using the nuclear density gauge method (ASTM D 6938). Compaction results indicated that the material in the areas and elevations tested did not achieve the minimum compaction requirement of 95% for the area tested. Test locations and elevations are based on information provided by others. TECHNICIAN'S NAME: Matt Lill TECHNICIAN'S SIGNATURE: ��_-— INFORMATION STATED ON THIS REPORT IS SUBJECT TO ENGINEERING REVIEW AND COMMENT. USUMMIT 320 Executive Court, Hillsborough, NC 27278 DESIGN AND ENGINEERING SERVICES Phone // 919.732.3883 Web // www.summitile.net Project: C&D Landfill Phase 1 Project No: 19-0248.003 Project Address: Client: C&D Landfill, Inc. Contractor: Equipment: Reviewed By: SUMMARY OF FIELD DENSITY TESTING AND COMPACTION Date: 4/29/2020 Technician: TEST INFORMATION METHOD IN -PLACE SOIL DATA PROCTOR DATA TEST RESULTS TEST NO. TEST DATE Elevation TEST LOCATION FIELD TESTING METHOD (ASTM) DRY DENSITY (lbs/ft� MOISTURE (%) CURVE NO.: MAX DRY DENSITY (Ibs/ft') OPTIMUM MOISTURE REQUIRED COMPACTION (%) RELATIVE COMPACTION (%) RELATIVE MOISTURE PASS/FAIL 1 04/29/20 SG Phase 1 location P-9 D 6938 75.7 20.9 S-905A 113.8 19.5 95.0 66.5 1.4 Fail 2 04/29/20 -0.5 Phase 1 location P-9 D 6938 89.2 17.8 S-905A 113.8 19.5 95.0 78.4 -1.7 Fail 3 04/29/20 -1.5 Phase 1 location P-9 D 6938 89.8 16.5 S-905A 113.8 19.5 95.0 78.9 -3.0 Fail 4 04/29/20 -1 Phase 1 location P4 D 6938 100.2 6.4 S-905A 113.8 19.5 95.0 88.0 -13.1 Fail 5 04/29/20 -1.4 Phase 1 location P-4 D 6938 106.4 8.8 S-905A 113.8 19.5 95.0 93.5 -10.7 Fail 6 04/29/20 -2 Phase 1 location P4 D 6938 98.1 9.8 S-905A 113.8 19.5 95.0 86.2 -9.7 Fail 7 04/29/20 -0.5 Phase 1 location P-3 D 6938 95.6 9.0 S-905A 113.8 19.5 95.0 84.0 -10.5 Fail 8 04/29/20 -1 Phase 1 location P-3 D 6938 60.9 27.6 S-905A 113.8 19.5 95.0 53.5 8.1 Fail 9 04/29/20 SG Phase 1 location P-1 D 6938 92.9 6.9 S-905A 113.8 19.5 95.0 81.6 -12.6 Fail 10 04/29/20 -1 Phase 1 location P-1 D 6938 95.6 9.0 S-905A 113.8 19.5 95.0 84.0 -10.5 Fail 11 04/29/20 -0.5 Phase 1 location P-2 D 6938 97.9 7.0 S-905A 113.8 19.5 95.0 86.0 -12.5 Fail 12 04/29/20 -1 Phase 1 location P-2 D 6938 78.4 7.6 S-905A 113.8 19.5 95.0 68.9 -11.9 Fail 13 04/29/20 -1 Phase 1 location P-6 D 6938 83.8 16.1 S-905A 113.8 19.5 95.0 73.6 -3.4 Fail 14 04/29/20 -2 Phase 1 location P-6 D 6938 83.0 21.9 S-905A 113.8 19.5 95.0 72.9 2.4 Fail 12 -1 4 11 3.3O 15 3�3 0 AC. PERN IT SHOWING FOOTPRINT MERCER FINAL COVER TES TIONS INAL COVER TES "o- \101,-6sb N/F ED ATON \ OB 70 PG\,268z C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 1 Appendix 4 Phase 1 Final Closure Plan 1.1 Background Capping a landfill, i.e., installing a final cover to promote runoff, thereby reducing the volume of water available to infiltrate the waste and, potentially, drive contaminants into the groundwater, is an accepted remedy for corrective action, in addition to monitored MNA and implementing institutional controls to supplement engineering controls. 1 As pointed out in Section 1.1, regulatory changes flagged June 30, 2008 as the cutoff date for compliance with 15A NCAC 13B .0543 requirements for final covers. C&D Landfill, Inc. was following a prescriptive incremental closure protocol, by which portions of the side slopes were closed (but not certified) prior to the cutoff. An investigation was performed in 2020 to evaluate the final cover on Phase 1. Documentation of that study is presented in Appendix 3. The study comprised test pits with field density testing and classification of the soils, performed by the author of this report. The study determined the final cover thickness is at least 36 inches at investigated locations on the side slopes. Soil density acquired via nuclear moisture - density gauge indicated compaction in the lower 18 inches of the side slope cover varies from 85 to 92 percent of the standard Proctor maximum dry density (MDD). Visual soil classifications for the lower 18 inches of side slope cover are typically SM, ML, and CL. Less than 36 inches of final cover was observed for the upper cap area, estimated at ±2 acres with approximately 2-5 percent slopes. The conclusion of that study is the well vegetated side slopes should meet or exceed the original final cover requirements at the time those areas operated. The upper cap area does not meet either the "new" or "old" requirements, thus an upgrade is warranted to certify the unit closed. Whereas the closure of Phase 1 (and eventually Phase 2) are included in the selected remedy specified in the 2019 Corrective Action Permit Modification application, plans are being drawn to build a "post-2008" cover on the upper cap area of Phase 1 and enhance the vegetation quality on the side slopes of Phase 1. Specifics of the planned final cover upgrade for Phase 1 is discussed in the following sections. A water - balance approach may be used to estimate the effect on the MNA screening model. 1.2 Final Cover Requirements The December 2014 Phase 213 PTC Application, Revision 3.2 (DIN 21812) contains a Closure and Post Closure Plan prepared in accordance with 15A NCAC 13B .0543. Relevant portions of that document are summarized here. It should be noted that the final cover design has already been approved by the SWS and applied to numerous prior permit applications, including the subject Facility. The description provided here is considered generic, whereas the SWS will need to review the proposed capping approach for Phase 1; thus, future amendments are likely. 1 EPA Publication 9203,1-021, SACM Bulletin, Presumptive Remedies for Municipal Landfill Sites, April 1992, Vol. 1, No. 1, referenced in Office of Emergency and Remedial Response, Hazardous Site Control Division 6203G, EPA 540-F-93-035, Sept. 1993. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 2 1) The final cap design ... shall conform to the minimum requirements of the Solid Waste Rules, i.e., the compacted soil barrier layer shall exhibit a thickness of 18 inches and a field permeability of not more than 1.0 x 10-5 cm/sec. The overlying vegetative support layer shall be 18 inches thick. 2) The CQA plan must be followed and all CQA documentation must be submitted to the Division. Post -settlement surface slopes must not be flatter than 5% on the upper cap. 3) Solid Waste rules require a gas venting system is required for the cap. A passive venting system will be specified, which will consist of a perforated pipe in crushed stone -filled trench — installed just below the final cap soil barrier layer — with a tentative minimum vent spacing of three vents per acre. LFG controls may not be necessary, and this requirement will be discussed with the SWS. 4) Solid Waste Rule .0543 makes a provision for an alternative cap design ... [if] the permeability requirements for the compacted soil barrier layer cannot be met. In such case, a synthetic liner barrier or GCL barrier will be considered. 1.3 Final Cap The following generic description of final cap design and construction is based on the 2014 update of the PTC for Phase 2B: 1.3.1 Elevations Final elevations of the landfill shall not exceed those depicted on Drawing E4 when it is closed, subject to approval of this closure plan. The elevations shown include the final cover. A periodic topographic survey shall be performed to verify elevations. 1.3.2 Slope Ratios All upper surfaces shall have at least a 5 percent slope, but not greater than a 10 percent slope. The cover shall be graded to promote positive drainage. Side slope ratios shall not exceed 3H:1V. A periodic topographic survey shall be performed to verify slope ratios. 1.3.3 Cover Section The terms "final cap" and "final cover" both apply. The final cover will subscribe to the minimum regulatory requirement for C&D landfills: o 18-inches of vegetated surface layer (VSL), the "erosion layer" over o 18-inches compacted soil barrier layer (CSB), i.e., the "infiltration layer," with a hydraulic conductivity not exceeding 1 x 10-5 cm/sec. 1.3.4 Construction All soils shall be graded to provide positive drainage away from the landfill area and compacted to meet applicable permeability requirements. Suitable materials for final cover soil shall meet C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 3 the requirements defined above. Care shall be taken to exclude rocks and debris that would hinder compaction efforts. The surface will then be seeded in order to establish vegetation. 1) Test Pad — The ability to compact the materials in the field to achieve the required strength and permeability values shall be verified with a field trial involving a test pad, to be sampled with drive tubes and laboratory density and/or permeability testing, prior to full-scale construction. The materials, equipment, and testing procedures should be representative of the anticipated actual final cover construction. 2) Compacted Barrier — Materials shall be blended to a uniform consistency and placed in three loose lifts no thicker than 9 inches and compacted by tamping, rolling, or other suitable method —the targeted final thickness is 18 inches minimum. a. The Contractor shall take care not to over -roll the cover such that the underlying waste materials would pump or rut, causing the overlying soil layers to crack — adequate subgrade compaction within the upper 36 inches of waste materials and/or the intermediate cover soil underlying the final cover is critical. b. All final cover soils shall be thoroughly compacted through the full depth to achieve the required maximum permeability required by Division regulations of 1.Ox 10-5 cm/sec, based on site -specific test criteria (see below). Compaction moisture control is essential for achieving adequate strength and permeability. 3) Vegetated Surface Layer — Soil shall be placed in two loose lifts no thicker than 12 inches and lightly compacted by tamping, rolling, or other suitable method. The final layer thickness is 18 inches minimum. A high organic content is desirable, so decayed wood mulch or other organic admixtures, e.g., WWTP sludge, with advance permission from the Division, is encouraged to provide nutrient and enhanced field capacity. The surface layer is not subject to a permeability requirement. a. The soils should be compacted sufficiently to promote stability and minimize susceptibility to erosion, but not over -compact the materials such that vegetation would be hindered. b. Finished surfaces should be vegetated immediately following the seed bed preparation. c. Follow the seeding and mulching procedures. 4) Inspection and Testing — Soils for the barrier layer are subject to the testing schedule outlined in the Construction Quality Assurance plan (see Section 4.0). a. The proposed testing program includes a minimum of one permeability test per lift per acre and four nuclear density gauge tests per lift per acre, to verify compaction of the compacted barrier layer. The moisture -density -permeability relationship of the materials has been established by the laboratory testing (discussed elsewhere in this report). b. The Contractor shall proof roll final cover subgrade materials (i.e., intermediate cover), which consist of essentially the same materials as the compacted barrier C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 4 layer (without the permeability requirements), to assure that these materials will support the final cover. 1.4 Construction Quality Assurance Section 4.0 of the December 2014 Phase 2B PTC Application specifies the number and frequencies for various tests required for the final cover construction. Relevant portions of that document are presented in Appendix 4. Excerpts are incorporated into the following summary: 1) CQA Testing for Drainage and Final Cover Soil a. Coarse Aggregate: Confirm Gradation Visual 5,000 CY b. Vegetative Soil Layer: Visual Classification ASTM D 2488 1 per acre c. Layer Thickness: Direct measure Survey 2) CQA Testing Schedule for Compacted Soil Barrier a. Lift Thickness: Direct measure Survey b. Permeability: ASTM D50841 1 per acre per lift c. In -Place Density: ASTM D 29222 4 per acre per lift d. Moisture Content: ASTM D 30173 4 per acre per lift e. Notes: Optionally use ASTM D6391. 1.5 Vegetation Enhancement Seedbed preparation, seeding, and mulching shall be performed accordance with specifications provided in the plans, unless approved otherwise in advance by the Engineer. 1) In areas to be seeded, fertilizer and lime typically should be distributed uniformly at a rate of 1,000 pounds per acre for fertilizer and 2,000 pounds per acre for lime, and incorporated into the soil to a depth of at least 3 inches by disking and harrowing. 2) Seeding shall be in accordance with a seeding schedule to be approved by the Engineer. 3) Distribution of seed and amendments by means of an approved seed drill or hydro seeder equipped to sow seed and distribute lime and fertilizer together will be acceptable. 4) All vegetated surfaces shall be mulched with wheat straw and a bituminous tack. Highly erosion prone areas may require stabilization with curled -wood excelsior, installed and pinned in accordance with the manufacturer's recommendations. 5) Other mulches such as ground wood mulch should not be used for protecting seeded areas. However, wood mulch may be incorporated into the topsoil to enhance water retention and nutrient value. 6) High velocity perimeter channels will require excelsior or turf -reinforcement mat (TRM). All rolled erosion control materials should be installed according to the generalized layout and staking plan found in the Construction Plans or the manufacturer's recommendations. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 5 1.6 Miscellaneous 1.6.1 Documentation The Owner shall complete an "as -built" survey to depict final elevations and to document any problems, amendments or deviations from the construction drawings. Records of all testing, including maps with test locations, shall be prepared by the third -party CQA testing firm. All materials pertaining to the closure shall be recorded in the Operational Record for the facility. 1.6.2 Maximum Areallolume Subject to Closure The largest anticipated area that will require final closure at any one time within the next 5-year period is 38 acres, including all of Phases 1, 2A and 2B. Intermediate cover shall be used on areas that have achieved final elevations until the final cover is installed. An annual adjustment of open area is required by the Division for a bond requirement. 1.6.3 Closure Schedule Refer to the requirements outlined in Section 6.1.5. 1.6.4 Closure Cost Estimate Note: The Facility already has a closure bond in place for the entire 15 acre footprint. 1.7 Post -Closure Plan 1.7.1 Term of Post -Closure Care The facility shall conduct post -closure care for a minimum of 30 years after final closure of the landfill, unless justification is provided for a reduced post -closure care period. 1.7.2 Maintenance of Closure Systems Inspections of the final cover systems and sediment and erosion control (S&EC) measures shall be conducted quarterly. Maintenance will be provided during post -closure care as needed to protect the integrity and effectiveness of the final cover. The cover will be repaired as necessary to correct the effects of settlement, subsidence, erosion, or other events. Refer to the Post Closure Monitoring and Maintenance Schedule (below). 1.7.3 Landfill Gas Monitoring — Refer to Appendix 4A. 1.7.4 Ground Water Monitoring — Refer to Appendix 3. 1.7.5 Record Keeping During the post closure period, maintenance and inspection records, i.e., a Post Closure Record, shall be kept as a continuation of the Operating Record that was kept during the operational period. The Post Closure Record shall include future inspection and engineering reports, as well as documentation of all routine and non -routine maintenance and/or amendments. The Post Closure Record shall include the ground water and gas monitoring records. 1.7.6 Certification of Completion At the end of the post -closure care period the facility manager shall contact the Division to schedule an inspection. The facility manager shall make the Post Closure Record available for C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 6 inspection. A certification that the post -closure plan has been completed, signed by a North Carolina registered professional engineer, shall be placed in the operating/post closure record. These records should be kept indefinitely. 1.8 Inspection and Maintenance (Final Cover) TABLE 6B POST -CLOSURE MONITORING AND MAINTENANCE SCHEDULE Activity General - Inspect access gates, locks, fences, signs, site security Maintain access roads, monitoring well access Final Cover Systems/Stability - Inspect cap and slope cover for erosion, sloughing, bare spots in vegetation, make corrections as needed (1) Storm Water/Erosion Control Systems — Inspect drainage swales, pipe drains, and sediment basin for erosion, excess sedimentation (1) Mow cover vegetation and remove thatch Inspect vegetation cover and remove trees Landfill Gas Monitoring Ground Water Monitoring System - Check well head security, visibility Ground Water Monitoring (4) Frequency Frequency Frequency Yrs. 1 - 5 Yrs. 6-15 Yrs. 16-30 Quarterly Quarterly Quarterly As needed As needed As needed Quarterly Semi- Annually Annually Quarterly Semi- Annually Annually Semi -Annually Annually None (2) Annually Annually Annually Quarterly (3) Quarterly (3) Quarterly (3) Semi- Semi- Semi - Annually Annually Annually Semi- Semi- Semi - Annually Annually Annually Notes: 1. Inspect after every major storm event, i.e., 25-year 24-hour design storm 2. Dependent on vegetation type, periodic mowing may be required 3. The Solid Waste Section may be petitioned for discontinuation of gas monitoring if no detections occur in gas sampling locations or on -site buildings 4. See current Ground Water Sampling and Analysis Plan C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 7 1.9 Responsible Party Contact C&D Landfill, Inc. Mr. Judson Whitehurst, Owner Mr. Wayne Bell, General Manager 802 Recycling Lane Tel 252-752-8274 Greenville, North Carolina 27834 Fax 252-752-9016 1.10 Planned Uses of Property Currently, there is no planned use for the landfill area following closure. The closed facility will be seeded with grass to prevent erosion. Any post -closure use of the property considered in the future will not disturb the integrity of the final cover. 1.11 Post -Closure Cost Estimate The following represents post -closure costs for Financial Assurance. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 1 Appendix 5 Water Quality Monitoring Plan 1.1. Sampling Protocols Monitoring the Facility has been conducted mostly by the same field staff and laboratory protocols for nearly 20 years. The work has been performed in accordance with SWS Guidelines for Groundwater, Soil, and Surface Water Sampling and other relevant documents listed on the SWS web site. 1 This protocol will be continued for the foreseeable future. Specific sampling protocols for the MNA parameters will be followed as they were in the 2017-2019 sampling events, performed by Environment 1, Inc. Personnel changes on the sampling crew will be reviewed with the Program Manager prior to the next upcoming sampling event. All protocols concerning sampling collection and handling are expected. 1.2. Monitoring Schedule Three distinct combinations of parameters and sampling protocols have been planned to meet the Corrective Action schedule requirements: Year 0 Dec 2020 Appendix I + full Appendix II + landfill specific parameters Year 1 Jun 2021 Appendix I + Appendix II Detects + landfill specific parameters Dec 2021 Appendix I + full Appendix II + landfill specific parameters Year 2 Jun 2022 Appendix I + Appendix II Detects + landfill specific parameters Dec 2022 Appendix I + full Appendix II + landfill specific parameters Year 3 Jun 2023 Appendix I + Appendix II Detects + landfill specific parameters + MINA parameters Dec 2023 Appendix I + Appendix II Detects + landfill specific parameters + MNA parameters Year 4 Jun 2024 Appendix I + Appendix II Detects + landfill specific parameters Dec 2024 Appendix I + full Appendix II + landfill specific parameters Year 5 Jun 2025 Appendix I + Appendix II Detects + landfill specific parameters Dec 2025 Appendix I + full Appendix II + landfill specific parameters Surface waters only receive Appendix I parameters each sampling event. 1.3. Appendix 1 and Appendix II Parameters These parameters are found in the document, NC Solid Waste Section Groundwater Protection Standards — Constituents List (updated October 15, 2018). Changes in the parameter list or standards that may occur during the reporting period will be incorporated as required by the SWS. 1 https:lldeg. nc.gov/aboutldivisions/waste-managementlwaste-management-permit-guidance/solid-waste- section/environmental-monitoring C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 2 1.4. MNA Parameters Hydrogen Methane EtheneA Ethane Carbon Dioxide Ferrous Iron Low Level Volatile Fatty Acids A, B Chloride c Sulfate c Manganese c Alkalinity c Hardness Nitrate/Nitrite Total Dissolved Residue TOC BOD COD pH Conductivity Dissolved Oxygen ORP Temperature Turbidity 1.5. C&D Specific Parameters Total Dissolved Solids Tetrahydrofuran 1,4-Dioxane Iron A sub -contracted to Pace Laboratories in Baton Rouge, LA B Acetic Acid Butyric Acid Hexanoic Acid Lactic Acid Pentanoic Acid Propionic Acid Pyruvic Acid i-Hexanoic Acid i-Pentanoic Acid c Overlaps with C&D Specific Parameters 1.6. Analysis and Reporting These issues are addressed in the main body of the CAP (Chapter 5). 1.7. Monitoring Locations Refer to Figure 3 in the Drawings section. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 Page 3 1.8. Special Provisions • Field personnel shall be trained and certified for specific sampling requirements. • Laboratory shall be required to maintain North Carolina Wastewater certification. • Professional oversight shall be provided by a qualified and duly licensed geologist or engineer. • Monitoring locations should be evaluated, especially background locations, to verify that these locations are not being influenced by the groundwater impact. Locations may be adjusted as appropriate with the express approval of the SWS. • Data evaluation and reporting will be performed by a qualified and duly licensed geologist or engineer. Reports shall be prepared in accordance with SWS requirements, including the annual analysis of MINA parameters and the CAERs discussed in Section 4.1.5. • Well -Head Management shall be performed as needed; a survey of the condition of the well heads shall be performed for every sampling event. For the time being, vegetation shall be mowed prior to the sampling event— no chemical weed control products shall be used. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 - DRAFT Page 1 Appendix 6 Landfill Gas Monitoring 1 Introduction The following plan has been prepared as a standalone document in accordance with current NCDENR Solid Waste Section (SWS) guidance. The monitoring locations, methods, and thresholds for action have not changed, but the 2010 guidance document requires that attention be given specifically to well construction, equipment calibration, sampling procedures, and data keeping, in a plan that is organized in a standardized format. Landfill staff and monitoring personnel should view the SWS document Landfill Gas Monitoring Guidance," November 2010, online at http://portal.ncdenr.org/c/document library/get file?uuid=da699f7e-8c13-4249-9012-16af8aefdc7b&groupld=38361. 1.1 Background Information Monitoring of landfill gas (LFG) is required at C&D landfills by Solid Waste Rule 15A NCAC 13B .0544. Landfill gas is a by-product from the decomposition of organic waste in a sanitary landfill, including certain C&D wastes. Landfill gas typically comprises about 50 percent methane, which can be explosive under certain conditions, as well as carbon dioxide, nitrogen, water, and small amounts of hydrogen sulfide. LFG has been known to promote the migration of contaminants into ground water. The Solid Waste Rules typically focus on the explosive properties from a public safety standpoint. Landfill gas migrates in soil above the ground water table and is restricted laterally by streams. Highly porous soils that tend to occur near the soil -rock interface within the Piedmont are a good pathway for gas migration. Past experience suggests that up -gradient areas should be targeted for monitoring, especially if porous soils are present. This zone typically is an aquifer, thus fluctuations in the water table will affect the gas migration pattern or rate, as does surface saturation, frozen soils, and variable barometric pressure. The ideal time to sample for subsurface gas is during times of low barometric pressure. Pipelines and utility trenches can serve as pathways for gas migration, with the potential to convey gas for considerable distances. Open landfills are not as likely to experience subsurface gas migration, but once a low permeability cover is installed, lateral migration into adjacent soils may be more likely. 1.2 Current Site Conditions Two unlined disposal units are situated on two rather flat knolls, separated by a shallow drainage feature. Topography slopes gently south from El. 20 at US Highway 264, to El. 16 - 18 at the disposal sites; then more abruptly into marshy drainage features that lead to Grindle Creek at approximately El. 4 - 6. The units are situated above grade with minimal base grade earthwork. Lateral separation to the streams is 50 feet minimum; the disposal area is isolated by other drainage features. Onsite soils are highly porous sand and silt mixtures extending to depths below the water table, typically underlain by a lower permeability silt -clay that serves as a partial confining layer. Ground water contours mimic the topography, with depths of 4 to 6 feet below the surface in the upper elevations, 2 feet or less within the lower elevations. The soil conditions and site geometry provide little opportunity for landfill gas to migrate C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 - DRAFT Page 2 either vertically or horizontally beyond the facility buffers. No structures exist within the facility buffers that would accumulate gas. No utility trenches are present. 1.3 Regulatory Requirements Thresholds that trigger responsive action are: Methane levels of 100 percent of the lower explosive limit (about 5 percent by volume) in soil -gas or air at the facility boundary; 25 percent of the LEL within onsite buildings, drainage structures and utility vaults; zero in off -site structures. The contingency plan (Section 5) discusses action required if a regulatory threshold is exceeded. 2 LFG Monitoring 2.1 Locations and Logistics LFG monitoring for this facility consists of sampling soil -gas adjacent to the landfill footprint via eleven (11) bar -hole punch test locations, labeled GP-1 through GP-11, spaced approximately 500 foot apart (see Drawing M1). The monitored locations reflect the emphasis on the east side of Phase 1 and the north side of Phase 2, the directions in which distant structures are located outside the facility boundary. The bar -hole punch test has been approved for other CDLF facilities; whereas the waste is typically non- putrescible, hence no significant methane migration is anticipated. Monitoring locations will be identified with permanent placards. Bar -hole punch tests are warranted at this stage because no gas migration has been detected, thus there is no data to guide the locations of permanent monitoring wells or gas probes. The waste is comprised of mostly inert materials with paper, wood, and other potentially combustible materials — the same kind of materials that can degrade slowly to form landfill gas — so it is conceivable that at some time in the future, the Solid Waste Section may require permanent gas monitoring wells. If subsurface methane is detected, additional sampling shall be performed delineate a migration pattern, and then permanent LFG monitoring wells may be installed. In anticipation of this requirement, this plan has been prepared with procedures for both bar -hole punch tests and sampling of future monitoring wells. A SWS-endorsed well construction schematic is provided, which includes sealed construction and a specialized port at the top to facilitate sampling. Presumably, the monitoring wells would be located near the same locations as currently monitored with the bar -hole punch test, for the same reasoning described above. This plan will be amended in the future to include data tables for the monitoring wells, if required. Data recording protocols will remain the same. The Solid Waste Rules require quarterly monitoring. Landfill gas monitoring will be performed during the active life of the landfill, estimated at 20 years, and throughout the post -closure care period, 30 years unless future data warrant a schedule revision, which will be subject to approval by the SWS. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 - DRAFT Page 3 2.2 Structures and Ambient Sampling Within offices and any buildings on -site, atmospheric sampling for methane shall be conducted. Methane is heavier than air and tends to accumulate in the lower zones with restricted circulations, i.e., crawlspaces, closets, and corners of rooms near the floor, cracks in walls, floor slabs, or foundations, crawlspace vents, drainage pipes, and utility vaults (excluding sanitary sewer manholes). Methane detection in and around the structures, though unlikely, would signify a problem — immediate action may be required — refer to the Contingency Plan (Section S). Ambient monitoring overlaps the building foundations and includes a "walk -around" at the toe of covered (vegetated) slopes to survey for gas that may be seeping through the cover. A key to potential side slope seepage includes stained soil, wetness with visible bubbling, or distressed (or absent) vegetation. Any detection of methane in the ambient monitoring should be noted on a site map and a special notation recorded in the monitoring report. Follow up sampling or close attention in future sampling events might be warranted. The site manager should be alerted to any ambient gas detection. 2.3 Sampling Schedule Quarterly methane monitoring will be conducted at all subsurface gas detection locations and in all occupied structures located on the landfill property. In addition, enclosed structures, such as manholes, utility vaults, and buried drainage pipes should be checked for gas prior to servicing, in addition to the routine monitoring. Passive gas vents for the final cover are not required to be monitored. Monitoring times are also important when conducting landfill gas monitoring. Proper landfill gas monitoring should include sampling during times when landfill gas is most likely to migrate. LFG monitoring should be conducted when the barometric pressure is low and soils are saturated. During the winter season when snow cover is just beginning to melt or when the ground is frozen or ice covered, landfill gas monitoring should be conducted when the barometric pressure is low. 3 LFG Sampling Program 3.1 Equipment and Calibration Monitoring will be performed with a specialized landfill gas monitoring instrument that meets the requirements of the SWS document, Landfill Gas Monitoring Guidance, with respect to detecting methane, oxygen, carbon dioxide, and hydrogen sulfide. Calibration shall occur prior to instrument use and according to the manufacturer's specifications. Should this element of the program change, this plan will be amended accordingly. 3.2 LFG Sampling Procedures The following procedure is recommended for conducting landfill gas monitoring well sampling and/or bar - hole punch testing (shown in italics). The sampling equipment shall consist of a good -quality gas meter capable of detecting methane (LEL) and oxygen levels — most modern meters include carbon monoxide or carbon dioxide, depending on the meter and hydrogen sulfide readings. In deference to professionals who C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 - DRAFT Page 4 have conducted LFG sampling for years, these procedures are guidelines; no changes to the current sampling program are warranted. Step 1— Calibrate the instrument according to the manufacturer's specifications. In addition, prepare the instrument for monitoring by allowing it to properly warm up as directed by the manufacturer. Make sure the static pressure shows a reading of zero on the instrument prior to taking the first sample. Step 2 — Purge sample tube for at least one minute prior to taking reading. Connect the instrument tubing to the landfill gas monitoring well cap fitted with a stopcock valve or quick connect coupling. Step 2 Alternate — Drive the bar into the ground to a depth of 3 feet at the sampling location using a hammer or backhoe bucket. Heavy gauge rebar is ideal for this task. The bar -hole needs to be near -vertical and free of obstructions. Drilling a hole with a modified concrete drill (an extension is required to reach the desired depth) has been demonstrated to expedite the making of a boring with less smearing of the side walls. Step 3 — Open the valve and record the initial reading and then the stabilized reading. A stable reading is one that does not vary more than 0.5 percent by volume on the instrument's scale. Step 3 Alternate — Cover the hole upon extraction of the drill to retain any gas present. Without completely lifting the cover, gently insert the sampling tube beneath the cover and obtain an initial reading. Allow time for a stabilized reading as described above. Step 4 — Record the stabilized reading including the oxygen concentration and barometric pressure. A proper reading should have two percent oxygen by volume or less. Higher oxygen levels may indicate that air is being drawn into the system, giving a false reading. Step 5 — Turn the stopcock valve to the off position and disconnect the tubing. Step 5 Alternate - eackfill the hole with cuttings or native soil, tamp the backfill with a rod or equipment handle. Step 6 — Proceed to the next landfill gas monitoring well and repeat Steps 2 — 5. 4 Record Keeping and Reporting The sampling technician shall record the date, time, location, sampling personnel, calibration data, gas pump rate, barometric pressure (from local weather reports), ambient temperature, general weather conditions at the time of sampling, initial and stabilized concentrations of methane (see the Landfill Gas Monitoring Data Form) following this text). These monitoring records shall be maintained in the landfill operating record. Should methane be detected at any sampling location, the facility manager should be C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 - DRAFT Page 5 notified and, depending on the concentrations, a report to the Solid Waste Section might be warranted. In any event a qualified engineer should be consulted. 5 Contingency Plan Solid Waste Rule .0544 (d) (3) requires the following responses in the event that methane concentrations are detected that exceed the foregoing methane concentration limits: (A) Immediately take all steps necessary to ensure protection of human health and notify the Division — at a minimum, occupied structures should be evacuated and ventilated until the methane concentrations subside; close monitoring of structures shall be implemented; for facility boundary violations, further evaluation is warranted, subject to notification and approval by the Division. (B) Within seven days of detection, document the methane or explosive gas levels in the operating record with a description of steps taken to protect human health. (C) Within 60 days of detection, implement a remediation plan for the methane or explosive gas releases, place a copy of the plan in the operating record, and notify the Division that the plan has been implemented. The plan must describe the nature and extent of the problem and the proposed remedy. (D) Based on the need for an extension demonstrated by the operator, the Division may establish alternative schedules for demonstrating compliance with the limits. (E) "Lower explosive limit" means the lowest percent by volume of a mixture of explosive gases in air that will propagate a flame at 25o C at atmospheric pressure. Beyond the regulatory mandated response outlined above, a close evaluation of the monitoring program is warranted in the event that methane is detected above the threshold values. Should this occur, an investigation to determine the direction and extent of the migration, involving additional bar -hole -punch tests, shall be performed under the supervision of a qualified professional geologist or engineer. Once a migration pattern is established, the data shall be used to establish locations for permanent monitoring wells. The frequency of monitoring or the field or structures may require adjustment. The data and proposed plan modifications should be reviewed with SWS staff. Other action may be required, e.g., some type of remedial activity, but those tasks cannot be anticipated at this time. Let it suffice to say that all steps to prevent the offsite migration of dangerous levels of methane shall be taken. However, based on the nature of the wastes and site conditions, which are generally unfavorable to the occurrence and migration of explosive gas, the likelihood that any sort of assessment or remedial action will be required is quite low. C&D Landfill, Inc. Phases 1 and 2 (7407-CDLF-2001-2009) July 9, 2020 NC Solid Waste Corrective Action Plan (CAP) Report Rev 0 - DRAFT Page 6 On the other hand, landfill gas can contain components that, while not explosive, could impact ground water quality. Should any LFG be detected, consideration should be given to what, if any, effects might be visible in the ground water data. 6 Professional Certification The certification statement below must be signed and sealed by a North Carolina Professional Geologist or Professional Engineer and submitted with the Landfill Gas Monitoring Plan. The landfill gas monitoring plan for this facility has been prepared by a qualified geologist or engineer who is licensed to practice in the State of North Carolina. The plan has been prepared based on first-hand knowledge of site conditions and familiarity with North Carolina regulations and industry standard protocol. This certification is made in accordance with North Carolina Solid Waste Regulations, indicating this Landfill Gas Monitoring Plan should provide reasonably early detection of an occurrence of landfill gas migration, so as to protect public health and the environment. No other warranties, expressed or implied, are made. Signed DRAFT, Printed G. David Garrett, PG, PE Date November 4, 2014 Not valid unless this document bears the seal of the above mentioned licensed professional. If wells are installed in the future, the well locations shall be shown on a topographic map that is signed and sealed by a registered surveyor. IIIIIIII�C ■ I I I I 2 3 4 5 GO o TTI-E 1 8 UU LO S > i "WEST" STREAM --�� ~`�' /,' \,.\ \\ v, \j EJE RECYCLING FACILITY \O� \ � � P\\ ` ' , ` � `� i---------- `J �- �\ Cam,/ `� / ( 1 S� o �' _ ,—'' ��� )/{ C� \// / �—,'��rf- —\--� GROUNDWATER USER (TYP.) Ile- C-� ---------- 1 PNPSE , ---', � ,,.r°f'i_. Yii4y . 'OY•t•FJ `. �:,.,.. \_ � / I / a / /''1 I � J/ - (' \`__\ L SOUTH STREAM 77 / 11 \ \1 \� '(\/1 \ \ I SUSPECTED RELICT CHANNEL ✓ \ , ` -ice I / \ \\\. _ � I -- -- / \ 22 � -� ' ' \ \ I ••_:_- Y�-== ,\-� ^ ( , � �, ✓, �1 • _ \ __ -- ,�\� � 'mil 100 YEAR FLOOD BOUNDARY > >� ; ,' — ,\` ,� ( �\ ( l ��QQ • - , ,,— � -'' /'� /i J /� \�,J%� i'�j Gam,-/�=.-J> `�� i / \\ i / � l � �1 ^ \\\ �\ �� 5 r' / •'•� �'�-' // f ` • _�' i;\ JY. \ r`\-,°' I i C -�/ ' y / • "r` J"" \ I 6 7 QQSS. fZ V. � ( `� �' , ,� % J f v ,-_ \Q'' \��'�`. i ` 0 i C&D LANDFILL INC. L 1 /L J I ) �-�_ ( •� f l / - i�/,� ; /mod �' ;'. \ - ~C.� \ \\`;\ ��'. �:'�� \. I i \ j ; 802 RECYCLING LANE GREENVILLE NC 27834 15 ' ( c .r�'' i -/ �� -� OFFICE TELEPHONE 252 752-8274 \ / / I GRINDLE CREEK __—'.�%'' ; /�� i �'��\' i y\ i == 1a i _�___J i ^� �i \/ ,� )' ! (�\ �j \\\ (,/�'\1� /---_— SCALE: `L --= --J ,i �`�—' �' % \ r c' — ' i \ \ 1� C� �'-'^� 0 250 500 750 i III ___' ` �/i ,'\��� ice' . ' J C� `� \\� �/ %' ^'��_' , ` : ^ / ' / / --\\ , / /. l ii�/ /-� ✓✓✓' �� -� l \ ' A; 100 E. Six Forks Road _: Suite 320 ,, ---- ------ ` �� / ;\���\ �-- ;_ �'�\� ` i �J \� Raleigh, NC 27609 TEL: (919) 322-0115 REV. A REFERENCE NOTES: 1. TOPOGRAPHY OUTSIDE THE FACILITY BOUNDARY TAKEN FROM 2006 NCDOT LIDAR DATA (NAVD 88) 2. ORIGINAL FACILITY DESIGN CA. 2000 BY JOHN TUCKER, PE 3. AS -BUILT DRAWING PREPARED BY DAVID GARRETT, PG, PE DURING 2009 PERMITTING CYCLE 4. SEDIMENT TRAPS AND DRAINAGE CHANNELS ARE DEPICTED AS SHOWN ON JOHN TUCKER DRAWING 1 OF 1, TITLED STORMWATER MANAGEMENT PLAN, SEPTEMBER 8, 2009 5. THE ARRANGEMENT OF WORKSPACES ON THE RECYCLING YARD MAY VARY FROM WHAT IS SHOWN ON THIS DRAWING 6. CURRENT WOODS AND OPEN SPACE TAKEN FROM PUBLIC DOMAIN AERIAL PHOTOGRAPHY DATED 2016 7. PLAT LINES OUTSIDE THE FACILITY BOUNDARY TAKEN FROM PITT COUNTY GIS TAX MAPS AND ARE APPROXIMATE. 8. NO CHANGES TO FACILITY LAYOUT, WASTE STREAM, STORMWATER DRAINAGE OR LEACHATE MANAGEMENT OR ANY DESIGN ASPECTS ARE PROPOSED AT THE TIME OF THIS DRAWING PREPARATION 9. FACILITY BOUNDARY AND SITE FEATURES SURVEYED AT VARIOUS TIMES BY A NC LICENSED SURVEYOR GROUND ELEVATION (FEET, NAVD 88) I I I I I I I I I I I I I I TREE LINE (FROM RECENT AERIAL PHOTO) CONCRETE PAVEMENT PAVED OR GRAVEL -HARDENED ---------- FACILITY BOUNDARY JURISDICTIONAL WATER FEATURE CHANNEL OR SWALE GROUNDWATER MONITORING WELL LANDFILL GAS MONITORING WELL - SURFACE WATER SAMPLING POINT LOCATION INFO: 1. USGS TOPOGRAPHIC MAPS GRIMESLAND AND LEGGETTS 2. LATTITUDE 35.621646 AT SCALEHOUSE LONGITUDE-77.182862 OWNER ADDRESS: 1000 FEET llA\ r7 D www. u m m I . n s �tde et DESIGN AND ENGINEERING SERVICES F C&D LANDFILL, INC. CORRECTIVE ACTION PLAN SEAL SCALE: AS NOTED DES: GDG RQ�� DWG TYPE: ANSI D 22"x34" DFTR : S IQ�•• �/ i JOB NO: 19-0248.004 CHKD: ASA ----- Q::--�\ r—__ i i ' ' `---- ---'\� \-��`\) ��\ `\. � '\\\� Dig y�•' DATE: 07-07-2020 ENGR: ASA :David Gab)467210-2020FILENAME: C&D LANDFILL ACM 125_2 APPD: GDG CD \ � �\ � /� ' ••• '.I/GINE • ' DRAWING NO - LOCATION REGIONAL TOPO Q I/ �.� ����`-__-_`--_--_`- `\\ ----�� A 07/25/2017 6468-17-7070 PERMIT RENEWAL GDG ASA ASA GDG ISSUED FOR REVIEW ���V7 D cj P� ��, REV DATE JOB NO. PROJECT TYPE DES DFTR CHKD ENGR APPD DESCRIPTION ,���������►,�p� 4 6 INCHES 1 2 3 TENTHS 10 20 30 5 1 8 9 1 0 I I I I I I 2 3 4 5 6 7 8 WOODED AREA WITH POCKET $ WETLANDS (NOT MAPPED) ACCESS ROAD A 1$ 1a NO KNOWN PLANS FOR FUTURE DEVELOPMENT 16 _\ j_ S -� 1 q. / i 1 16 16 L16 1 I PHASE 213 ACTIVE AREA I i � \� 14 -- ----0***000000000000PHASE 213 INACTIVE AREA co 000 I�I V FACILITY BOUNDARY000 J IREV. A REFERENCE NOTES: 1. TOPOGRAPHY OUTSIDE THE FACILITY BOUNDARY TAKEN FROM 2006 NCDOT LIDAR DATA (NAVD 88) 2. ORIGINAL FACILITY DESIGN CA. 2000 BY JOHN TUCKER, PE 3. AS -BUILT DRAWING PREPARED BY DAVID GARRETT, PG, PE DURING 2009 PERMITTING CYCLE 4. SEDIMENT TRAPS AND DRAINAGE CHANNELS ARE DEPICTED AS SHOWN ON JOHN TUCKER DRAWING 1 OF 1, TITLED STORMWATER MANAGEMENT PLAN, SEPTEMBER 8, 2009 5. THE ARRANGEMENT OF WORKSPACES ON THE RECYCLING YARD MAY VARY FROM WHAT IS SHOWN ON THIS DRAWING 6. CURRENT WOODS AND OPEN SPACE TAKEN FROM PUBLIC DOMAIN AERIAL PHOTOGRAPHY DATED 2016 7. PLAT LINES OUTSIDE THE FACILITY BOUNDARY TAKEN FROM PITT COUNTY GIS TAX MAPS AND ARE APPROXIMATE. 8. NO CHANGES TO FACILITY LAYOUT, WASTE STREAM, STORMWATER DRAINAGE OR LEACHATE MANAGEMENT OR ANY DESIGN ASPECTS ARE PROPOSED AT THE TIME OF THIS DRAWING PREPARATION 9. FACILITY BOUNDARY AND SITE FEATURES SURVEYED AT VARIOUS TIMES BY A NC LICENSED SURVEYOR GROUND ELEVATION (FEET, NAVD 88) I'I I I'I'I'I'I'I I I'I'I'I TREE LINE (FROM RECENT AERIAL PHOTO) 1A--� PHASE 1 UPPER CAP AREA CONCRETE PAVEMENT .. .�... /c�a'i PAVED OR GRAVEL -HARDENED � / / ��---------- FACILITY BOUNDARY C JURISDICTIONAL WATER FEATURE CHANNEL OR SWALE WEST STREAM `` ' ° GROUNDWATER MONITORING WELL '//III \� i/ r /� fi i/� /i/r \\\� ���� \\ ; \ ; \ .• . LANDFILL GAS MONITORING WELL _ \` \ --- ;--'� ��'`\ \` \`\ '_'-------------; = ` \ SURFACE WATER SAMPLING POINT 00-0 ------------- / / / ;, r //rrr♦♦ , r'r % /♦\\\\ \.` `\ \ \\. === ___ '`\ \.,\\ \\`.`\ `,`\.` LOCATION INFO: 1. USGS TOPOGRAPHIC MAPS GRIMESLAND AND LEGGETTS I \ 1 � / ����� / i � i♦ ,�i r r //r / /ir r r // i'/ / "--------------- \ � � _--------- �/ i /ii'i /%'/ / '//� "i � Q 2. LATTITUDE 35.621646 AT SCALEHOUSE ,♦ , ,;__, . ..., ../ ,r, ;:'/;;� ';: ; ' LONGITUDE 77182862 // rrr, ♦ , , ♦ ,�- � , ii , ,/, I' I 111 II I //// /// j i 000. / ,/rr ♦,, ,/r, / /r \-G'. ♦\` `` \` \\ IIIII IIII 1 j/ % i'ii % / 111 II„II II, Ij III1I ,/„ _ „/, / _ _ � OWNER ADDRESS: � � I I� If f 1, f � C&D LANDFILL, INC. ' 802 RECYCLING LANE \\ \\ �� �\\\\ \ \� \\ AREA OF CONCERN o \\\\\ \\\\\\ \�Q ; //; „ %' ; ;;; I r, \\ \\\ \ ;\\ \ // GREENVILLE7 NC 27834 \ \� \\\ / //� / /, // , /, / / /:< APPROXIMATE LIMITS CENTRAL STREAM OFFICE TELEPHONE (252) 752-8274 SCALE: "SOUTH" STREAM 0 125 250 375 500 FEET 100 YEAR FLOOD BOUNDARY HEAVY WOODS LIGHT WOODS AND OPEN / 1 — ���:���" %,%%;i% FARMLAND (MOSTLY DRY / / i /� \\ %;;%%,41 1 100 E. Six Forks Road HARDENED ALL-WEATHER ACCESS DRIVE / Suite 320 J / Raleigh, NC 27609 TEL: 919 322-0115 41 www.summitde.net DESIGN AND ENGINEERING SERVICES F F—A VEGETATED SLOPES WITH DRAINAGE NEGLIGIBLE LIKELIHOOD OF , BENCHES NOT DISPLAYED i FUTURE DEVELOPMENT OR / � � � I � 1 ♦ �� C&D LANDFILL, INC. GROUNDWATER USE / HEAVY WOODS /, , CORRECTIVE ACTION PLAN / / \ / / ♦ SEAL ���������SCALE: AS NOTED DES: GDG i� �N C ARO< ��i DWG TYPE: ANSI D 22"x34" DFTR LOWLYING AREA, IMPRACTICAL /6 ^ =�..•OF� SIO,�•. 9 JOB NO: 19-0248.004 CHKD: ASA / GROUNDWATER RECEPTOR FOR / / TO ACCESS EXCEPT THROUGH \ \ / = : �� SEAL ��': = DATE: 07-07-2010 ENGR: ASA UPPERMOST AQUIFER / SUBJECT FACILITY / I iigitaRy'_D ftr�bd bj FILENAME: C&D LANDFILL ACM 125_2 APPD: GDG Zvi Garret 771 -2Q20 DRAWING O N . A 07/25/2017 6468-17-7070 PERMIT RENEWAL GDG ASA ASA GDG ISSUED FOR REVIEW ��.G PVC, ��,,FACILITY PLAN / LOCAL TO PO • 2 I REV DATE JOB NO. PROJECT TYPE DES DFTR CHKD ENGR APPD DESCRIPTION �������►0tt 7777 INCHES 1 2 3 TENTHS 10 20 30 4 5 6 7 8 9 1 0 7 CDLF FOOTPRINTS; CONTOURS NOT 0100 _ _ I ' ♦ 14 \ :' 000 co mW 10 J .. ORIGINAL GROUND CONTOURS � i DISPLAYED FOR DATA CLARITY o 8 I IREV. A REFERENCE NOTES: 1. TOPOGRAPHY OUTSIDE THE FACILITY BOUNDARY TAKEN FROM 2006 NCDOT LIDAR DATA (NAVD 88) 2. ORIGINAL FACILITY DESIGN CA. 2000 BY JOHN TUCKER, PE 3. AS -BUILT DRAWING PREPARED BY DAVID GARRETT, PG, PE DURING 2009 PERMITTING CYCLE 4. SEDIMENT TRAPS AND DRAINAGE CHANNELS ARE DEPICTED AS SHOWN ON JOHN TUCKER DRAWING 1 OF 1, TITLED STORMWATER MANAGEMENT PLAN, SEPTEMBER 8, 2009 / 5. THE ARRANGEMENT OF WORKSPACES ON THE RECYCLING YARD MAY VARY FROM WHAT IS SHOWN ON THIS DRAWING 6. CURRENT WOODS AND OPEN SPACE TAKEN FROM PUBLIC DOMAIN Q AERIAL PHOTOGRAPHY DATED 2016 7. PLAT LINES OUTSIDE THE FACILITY BOUNDARY TAKEN FROM PITT \ COUNTY GIS TAX MAPS AND ARE APPROXIMATE. 8. NO CHANGES TO FACILITY LAYOUT, WASTE STREAM, STORMWATER DRAINAGE OR LEACHATE MANAGEMENT OR ANY DESIGN ASPECTS ARE PROPOSED AT THE TIME OF THIS DRAWING PREPARATION 9. FACILITY BOUNDARY AND SITE FEATURES SURVEYED AT VARIOUS TIMES BY A NC LICENSED SURVEYOR E&S MEASURES NOT DISPLAYED LEGEND: FOR DATA CLARITY GROUND ELEVATION (FEET, NAVD 88) I I I I I I I I I I I I I I TREE LINE (FROM RECENT AERIAL PHOTO) 1 A� CONCRETE PAVEMENT MW-14D MW-1 4S 180 M W- 1 D o PAVED OR GRAVEL -HARDENED / ® / CO m W-1 S /�� I ---------- FACILITY BOUNDARY / o/ o JURISDICTIONAL WATER FEATURE / 16 / X►> CHANNEL OR SWALE / 8 20 18 / I i 's..: °.b ♦ GROUNDWATER MONITORING WELL N—I3CID — LANDFILL GAS MONITORING WELL 18 1 / 16 - SURFACE WATER SAMPLING POINT I 1°' i MW-12sMW-8 LOCATION INFO: \ ,0 18 a MW-4 1. USGS TOPOGRAPHIC MAPS GRIMESLAND AND LEGGETTS N6 2. LATTITUDE 35.621646 AT SCALEHOUSE ORIGINAL GROUND CONTOURS S W-1 LONGITUDE-77.182862 � o _ l \ SW-3 " DISPLAYED FOR DATA CLARITY mW — ;` :,::: — OWNER ADDRESS: 7 � / 1 �••• D ��... � • � — C. 802RECYCLING INANE I ,o MW-3s r, GREENVILLE, NC 27834 � MW-3D � .•�o.•....••� OFFICE TELEPHONE (252) 752-8274 mw_5 I \ mw_3 SCALE: J /40t/ 0 125 250 375 500 FEET MW-6 100 E. Six Forks Road i Suite 320 MW-2D Raleigh, NC 27609 TEL: 919 322-0115 www.summitde.net DESIGN AND ENGINEERING SERVICES F MW-2S \ _ / C&D LANDFILL, INC. SW-2 CORRECTIVE ACTION PLAN / :,• SEAL ,����������SCALE: AS NOTED DES: GDG RO� ,, DWG TYPE: ANSI D 22"x34" DFTR 0�,•''��S �i�i JOB NO: 19-0248.004 CHKD: ASA / / \ Digi# y �i d b '; DATE: 07-07-2020 ENGR: ASA / = David G2�7710-2020= \ rFILENAME: C&D LANDFILL ACM 125_2 APPD: GDG � ( r,.� � � � � � � � =c • �.NGINEF'�' ••�� �DRAWING NO. - ` A 07/25/2017 6468-17-7070 PERMIT RENEWAL GDG I ASA ASA GDG ISSUED FOR REVIEW MONITORING LOCATIONS 3...j I REV DATE JOB NO. PROJECT TYPE DES DFTR CHKD ENGR APPD 0,118111 ,118111 ��►� INCHES 1 2 3 TENTHS 10 20 30 4 5 6 7 8 9 101 REV. A REFERENCE NOTES: 1. TOPOGRAPHY OUTSIDE THE FACILITY BOUNDARY TAKEN FROM 2006 NCDOT LIDAR DATA (NAVD 88) 2. ORIGINAL FACILITY DESIGN CA. 2000 BY JOHN TUCKER, PE 3. AS -BUILT DRAWING PREPARED BY DAVID GARRETT, PG, PE DURING 2009 PERMITTING CYCLE 4. SEDIMENT TRAPS AND DRAINAGE CHANNELS ARE DEPICTED AS SHOWN ON JOHN TUCKER DRAWING 1 OF 1, TITLED STORMWATER MANAGEMENT PLAN, SEPTEMBER 8, 2009 5. THE ARRANGEMENT OF WORKSPACES ON THE RECYCLING YARD MAY VARY FROM WHAT IS SHOWN ON THIS DRAWING 6. CURRENT WOODS AND OPEN SPACE TAKEN FROM PUBLIC DOMAIN AERIAL PHOTOGRAPHY DATED 2016 7. PLAT LINES OUTSIDE THE FACILITY BOUNDARY TAKEN FROM PITT COUNTY GIS TAX MAPS AND ARE APPROXIMATE. 8. NO CHANGES TO FACILITY LAYOUT, WASTE STREAM, STORMWATER DRAINAGE OR LEACHATE MANAGEMENT OR ANY DESIGN ASPECTS ARE PROPOSED AT THE TIME OF THIS DRAWING PREPARATION 9. FACILITY BOUNDARY AND SITE FEATURES SURVEYED AT VARIOUS TIMES BY A NC LICENSED SURVEYOR GROUND ELEVATION (FEET, NAVD 88) TREE LINE (FROM RECENT AERIAL PHOTO) CONCRETE PAVEMENT PAVED OR GRAVEL -HARDENED ---------- FACILITY BOUNDARY JURISDICTIONAL WATER FEATURE CHANNEL OR SWALE GROUNDWATER MONITORING WELL LANDFILL GAS MONITORING WELL - SURFACE WATER SAMPLING POINT LOCATION INFO: 1. USGS TOPOGRAPHIC MAPS GRIMESLAND AND LEGGETTS 2. LATTITUDE 35.621646 AT SCALEHOUSE LONGITUDE-77.182862 OWNER ADDRESS: C&D LANDFILL, INC. 802 RECYCLING LANE GREENVILLE, NC 27834 OFFICE TELEPHONE (252) 752-8274 SCALE: 0 125 250 375 500 FEET SUt*lt*11T 1A--� /4fwww.summitde.net DESIGN AND ENGINEERING SERVICES F softW— 2S C&D LANDFILL, INC. SW-2 CORRECTIVE ACTION PLAN SEAL ������������ SCALE: AS NOTED DES: GDG / 'l/ < l •`` C A ''• • �N RO� ,,i�i DWG TYPE: ANSI D 22"x34" DFTR �� / / / / / / ^ 0�,•''��S SIQ''•,�� �o JOB NO: 19-0248.004 CHKD: ASA SEAL ��': = DATE: 07-07-2020 ENGR: ASA / 4 Dijitally Sin; � FILENAME: C&D LANDFILL ACM 125_2 APPD: GDG Dlyi�Gq tt, 7-1��.Q2m DRAWING NO. .d� ���.VVGI NE • �� - ` A 07/25/2017 6468-17-7070 PERMIT RENEWAL GDG ASA ASA GDG ISSUED FOR REVIEW *" �[D G ,l••`••, TOP O F CONFINING UNIT 4 I REV DATE JOB NO. PROJECT TYPE DES DFTR CHKD ENGR APPD DESCRIPTION ���������►�•` 777 INCHES 1 2 3 TENTHS 10 20 30 4 5 6 7 8 9 101 6 7 8 I IREV. A TYPICAL GROUNDWATER CONTOURS IN THE UPPERMOST AQUIFER BASED ON 2017 OBSERVATIONS 1) MW-14S M W— I 4D mw_1 CO mw 1S � LU � 10 mw_1 3 � m�o'-11 \:j,—�WE13 ' MW-12s -m w M —4 Nbc W 18 ��/��-SW 1�0 �SW-3 mw_7 �, 70 MW-3s r1-11 <<��$ MW-3D mw 5 MW_3A�� 6 m w MW-2D 4'T100 Suite9320 cSix Forks Road h, NC 27609 t9+e)azz ons REFERENCE NOTES: 1. TOPOGRAPHY OUTSIDE THE FACILITY BOUNDARY TAKEN FROM 2006 NCDOT LIDAR DATA (NAVD 88) 2. ORIGINAL FACILITY DESIGN CA. 2000 BY JOHN TUCKER, PE 3. AS -BUILT DRAWING PREPARED BY DAVID GARRETT, PG, PE DURING 2009 PERMITTING CYCLE 4. SEDIMENT TRAPS AND DRAINAGE CHANNELS ARE DEPICTED AS SHOWN ON JOHN TUCKER DRAWING 1 OF 1, TITLED STORMWATER MANAGEMENT PLAN, SEPTEMBER 8, 2009 5. THE ARRANGEMENT OF WORKSPACES ON THE RECYCLING YARD MAY VARY FROM WHAT IS SHOWN ON THIS DRAWING 6. CURRENT WOODS AND OPEN SPACE TAKEN FROM PUBLIC DOMAIN AERIAL PHOTOGRAPHY DATED 2016 7. PLAT LINES OUTSIDE THE FACILITY BOUNDARY TAKEN FROM PITT COUNTY GIS TAX MAPS AND ARE APPROXIMATE. 8. NO CHANGES TO FACILITY LAYOUT, WASTE STREAM, STORMWATER DRAINAGE OR LEACHATE MANAGEMENT OR ANY DESIGN ASPECTS ARE PROPOSED AT THE TIME OF THIS DRAWING PREPARATION 9. FACILITY BOUNDARY AND SITE FEATURES SURVEYED AT VARIOUS TIMES BY A NC LICENSED SURVEYOR GROUND ELEVATION (FEET, NAVD 88) TREE LINE (FROM RECENT AERIAL PHOTO) CONCRETE PAVEMENT PAVED OR GRAVEL -HARDENED ---------- FACILITY BOUNDARY JURISDICTIONAL WATER FEATURE CHANNEL OR SWALE GROUNDWATER MONITORING WELL LANDFILL GAS MONITORING WELL - SURFACE WATER SAMPLING POINT LOCATION INFO: 1. USGS TOPOGRAPHIC MAPS GRIMESLAND AND LEGGETTS 2. LATTITUDE 35.621646 AT SCALEHOUSE LONGITUDE-77.182862 OWNER ADDRESS: C&D LANDFILL, INC. 802 RECYCLING LANE GREENVILLE, NC 27834 OFFICE TELEPHONE (252) 752-8274 SCALE: 0 125 250 375 500 FEET 1A--� www.summitde.net DESIGN AND ENGINEERING SERVICES F mw— S soft C&D LANDFILL, INC. SW-2 CO CTIVE RRE A N PLAN ACTION O SEAL 111111118"###,, SCALE: AS NOTED DES: GDG �N C ARO ��i, DWG TYPE: ANSI D 22"x34" DFTR : 0�.•FES It JOB NO: 19-0248.004 CHKD: ASA / Dlgtt�tl/ • =.mooy �Id byl ' +:. DATE: 07-07-2020 ENGR: ASA / \ : Da�Id (3pMe$ , 10-202C1_ FILENAME: C&D LANDFILL ACM 125_2 APPD: GDG DRAWING NO. ` A 07/25/2017 6468-17-7070 PERMIT RENEWAL GDG ASA ASA GDG ISSUED FOR REVIEW �� ID GPFz �` GROUNDWATER ELEVS (SHALLOW) 5 I REV DATE JOB NO. PROJECT TYPE DES DFTR CHKD ENGR APPD DESCRIPTION INCHES 1 2 3 TENTHS 10 20 30 4 5 6 7 8 9 10 I I 1 7 8 REV. A -A& � v �20> A 1 1 I 1 1 I ♦0100 110 _ 14 000 3 000000 000 ' J 040 MW-14D M W- 14 S / GWE 12.05 16 18 MW-13 to 0 N I 16� MW-1 2s 7", I S W — 3 INCHES 1 2 3 TENTHS 10 20 30 70 r( 1 1000 mw_3 MW-5 mw_3 GWE 10.71 QVV47 10 2 J � � / m w IS,GWE 9.94 1 � A 07/25/2017 6468-17-7070 / REV DATE JOB NO. n TYPICAL GROUNDWATER CONTOURS IN THE LOWER AQUIFER BASED ON 2017 OBSERVATIONS J) 1 �. / I SW-2 l PERMIT RENEWAL GDG ASA ASA GDG ISSUED FOR REVIEW PROJECT TYPE DES I DFTR CHKD ENGR APPD DESCRIPTION 7 100 E. Six Forks Road Suite 320 Raleigh, NC 27609 TEL: (919) 322-0115 REFERENCE NOTES: 1. TOPOGRAPHY OUTSIDE THE FACILITY BOUNDARY TAKEN FROM 2006 NCDOT LIDAR DATA (NAVD 88) 2. ORIGINAL FACILITY DESIGN CA. 2000 BY JOHN TUCKER, PE 3. AS -BUILT DRAWING PREPARED BY DAVID GARRETT, PG, PE DURING 2009 PERMITTING CYCLE 4. SEDIMENT TRAPS AND DRAINAGE CHANNELS ARE DEPICTED AS SHOWN ON JOHN TUCKER DRAWING 1 OF 1, TITLED STORMWATER MANAGEMENT PLAN, SEPTEMBER 8, 2009 5. THE ARRANGEMENT OF WORKSPACES ON THE RECYCLING YARD MAY VARY FROM WHAT IS SHOWN ON THIS DRAWING 6. CURRENT WOODS AND OPEN SPACE TAKEN FROM PUBLIC DOMAIN AERIAL PHOTOGRAPHY DATED 2016 7. PLAT LINES OUTSIDE THE FACILITY BOUNDARY TAKEN FROM PITT COUNTY GIS TAX MAPS AND ARE APPROXIMATE. 8. NO CHANGES TO FACILITY LAYOUT, WASTE STREAM, STORMWATER DRAINAGE OR LEACHATE MANAGEMENT OR ANY DESIGN ASPECTS ARE PROPOSED AT THE TIME OF THIS DRAWING PREPARATION 9. FACILITY BOUNDARY AND SITE FEATURES SURVEYED AT VARIOUS TIMES BY A NC LICENSED SURVEYOR LEGEND: GROUND ELEVATION (FEET, NAVD 88) I I I I I I I I I I I I I I TREE LINE (FROM RECENT AERIAL PHOTO) CONCRETE PAVEMENT PAVED OR GRAVEL -HARDENED ---------- FACILITY BOUNDARY JURISDICTIONAL WATER FEATURE CHANNEL OR SWALE GROUNDWATER MONITORING WELL LANDFILL GAS MONITORING WELL - SURFACE WATER SAMPLING POINT LOCATION INFO: 1. USGS TOPOGRAPHIC MAPS GRIMESLAND AND LEGGETTS 2. LATTITUDE 35.621646 AT SCALEHOUSE LONGITUDE -77.182862 OWNER ADDRESS: C&D LANDFILL, INC. 802 RECYCLING LANE GREENVILLE, NC 27834 OFFICE TELEPHONE (252) 752-8274 SCALE: 0 125 250 375 500 FEET A--� www.summitde.net DESIGN AND ENGINEERING SERVICES F C&D LANDFILL, INC. CORRECTIVE ACTION PLAN L i���� SCALE: AS NOTED DES: GDG \A C'� RQ�� DWG TYPE: ANSI D 22"x34" DFTR : ��•••O��S SjO�,. = JOB NO: 19-0248.004 CHKD: ASA -Digifa�y by •• DATE: 07-07-2020 ENGR: ASA �' Davkd G t46v10-2020= FILENAME: C&D LANDFILL ACM 125_2 APPD: GDG 'Al ft DRAWING NO. R NDWATER ELEVATIONS DEEP GROUNDWATER N os( ) 6 8 9 10 I 2 <uSS SEC TION REV. A lllllll I ON E ELEV., FT 26 24 22 20 18 16 14 12 10 8 6 4 2 0 -2 -4 -6 -8 -10 -12 -14 -16 -18 -20 - 22 - 24 -26 -28 -30 -32 -34 INCHES i I I I i I I I I 1 2 3 TENTHS 10 I ! I I I I I I I 1 1 20 30 A 07/25/2017 6468-17-7070 PERMIT RENEWAL GDG I ASA ASA GDG REV DATE JOB NO. PROJECT TYPE DES DFTR I CHKD ENGR APPD 4 5 6 I I I 7 ISSUED FOR REVIEW DESCRIPTION ELEV., FT LEGEND ................. •.r;. i E757&73i -C TION A -A GROUND SURFACE APPROX. UPPER BOUNDARY OF AQUIFER UNIT 1 OTHER STRATA BOUNDARIES MAX SEASONAL HIGH GROUND WATER OBSERVED WATER ELEVATION DATA POINT GROUNDWATER FLOW DIRECTION o- 50/.3 STANDARD PENETRATION TEST VALUE (N), BPF WELL SCREEN INTERVAL -ONE SCREEN PER WELL CROSS SECTION C -C .,,�\ +, SD .I � �.,t• " ;,� •aw.`rr.}"nai�.• . .raa+.xn s ,�{ � � .yamr PER. .n....w......,........•., lx. w.e.... J� _7 { ear eca::av Y ac as JGmN A.K.TIICKER. P.E. .cmxsl slsm nBULTING ERG 11 EER oas -fA.A/Gl: C PM YC lPP i'NlV tl" lYMM F71M iW Nl _ l.�JirJ OPDfM 4M -- ••- _ w ir �••.JPJf JkIHMM V-wrw. ...i ...... 100 E. Six Forks Road Suite 320 Raleigh, NC 27609 TEL: (919) 322-0115 www.summitde.net m D SuSlt4IT DESIGN AND ENGINEERING SERVICES F- C&D LANDFILL, INC. CORRECTIVE ACTION PLAN SEAL ,,�����►►►►►►►►►� SCALE: AS NOTED DES: GDG �-04%4 N CAR, Q DWG TYPE: ANSI D 22"x34" DFTR : �tS Z .�0 �,9•,.� JOB NO: 19-0248.004 CHKD: ASA DATE: 07-07-2020 ENGR: ASA = Dig' ly iced fS ; - David Cr,27-10:2029 FILENAME: C&D LANDFILL ACM 125 2 APPD: GDG DRAWING NO. CROSS SECTION A 8 I 9 I 10 I 7 T 2 T 3 r� _ :1■ 1 'NNE EROW EM iiii MEMMIMM OL MMMMEMMME ��� • IIBlum ^ • • • MIN►� ���■ll �� 1l � ■��Irl��1■�� NJ I �I 'O _ • ■ it I � _ � I � � ����ll� ��.._��i��►7l■■I■rJ/,�II�I all � �����Il�����■11��1 ®���■ Imo■ ■fir ■��I��■1 ��1����111 ■I���1 �� �����1�� ■IO�IIIOt��111l1��rl■��16i�1��1 NONN1� ■il �� •fillpin t •��■1!.®�I!■���■1 _■_ f ■ • STILT w�®lei ■R■ ■1■�111��111��■11©��1� ��� ���1���■11� t r , NONE s ' • ��trllliti��11�1�iI���tt►TTI`1�11►th►l.i.7f�'�'1J��1f�IJli�__ME__■��i ■�■�■_�■■_�1�■��I�i■ ■1%�■��1�NONE 1111111I____ I! , I MW"tMI new ON ONW : '. 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CONTOURS NOT DISPLAYED FOR DATA CLARITY TVOC 0.3 ��, EBZ=0.3J THE=6.4MW-14D co VCL=1.1 N10 41 v TVOC 9.8 0.5 0.5. . o � W� 1XI 16 � CO 110 � MW-11 CO THE=0.91. 18 p 1 � / mw(i 3 EPTUALI Ez o 18� TVOC 0.9 � r �` ` I I S CONTO S VINYL MW-4 � � � RID MG/L � THE-0.5 I �a N 2 05 o MW-8 6 ` TVOC 0.5/ 16 -, BZN=1.2 0-4 �. MW-12s ', 5� , � o .. � ACE=10.8J aFT - � -BZN -1.7 3 -,B 2 � THE=15.0 O � � CDS=1.3J ,� TVOC 26.5 CONCEPTUALIZED � CHEMICAL ABBREVIATIONS DCE=1.3J � ° � �ISOCONTOURS FOR � MW-7 \ � NPH-0.9J � � o . BENZENE IN MG/L , THF-12.8- XLN=XYLENE THE=36.4 � ���o ' �2.5 2 W TVOC 12.8 � VCL =VINYL CHLORIDE TLN=0.5J l � � _ M F51 5 0 O `�� TLN =TOLUENE VCL=4.3 I I \ �5 - �; TCE = TRICHLOROETHANE XLN=1.5 J � � MW_ TVOC 1.5 NPH =NAPHTHALENE TVOC 47.8 i m MEK = 2-BUUTANONE / BZN=2.0 MW-3s / i � � Suite 320 E. Six Forks Road DCE =CIS-1 2-DICHLOROETHENE � � � � � NPH=1.8J gZN = 2.8 � NO IMPACT BY COCs THE=12.7 � M W � � Raleigh, NC 27609 CLE = CHLOROETHANE _ � DETECTED IN NPH=7.7J � , � TEL: (919) 322-0115 REV. A REFERENCE NOTES: 1. TOPOGRAPHY OUTSIDE THE FACILITY BOUNDARY TAKEN FROM 2006 NCDOT LIDAR DATA (NAVD 88) 2. ORIGINAL FACILITY DESIGN CA. 2000 BY JOHN TUCKER, PE 3. AS -BUILT DRAWING PREPARED BY DAVID GARRETT, PG, PE DURING 2009 PERMITTING CYCLE 4. SEDIMENT TRAPS AND DRAINAGE CHANNELS ARE DEPICTED AS SHOWN ON JOHN TUCKER DRAWING 1 OF 1, TITLED STORMWATER MANAGEMENT PLAN, SEPTEMBER 8, 2009 5. THE ARRANGEMENT OF WORKSPACES ON THE RECYCLING YARD MAY VARY FROM WHAT IS SHOWN ON THIS DRAWING 6. CURRENT WOODS AND OPEN SPACE TAKEN FROM PUBLIC DOMAIN AERIAL PHOTOGRAPHY DATED 2016 7. PLAT LINES OUTSIDE THE FACILITY BOUNDARY TAKEN FROM PITT COUNTY GIS TAX MAPS AND ARE APPROXIMATE. 8. NO CHANGES TO FACILITY LAYOUT, WASTE STREAM, STORMWATER DRAINAGE OR LEACHATE MANAGEMENT OR ANY DESIGN ASPECTS ARE PROPOSED AT THE TIME OF THIS DRAWING PREPARATION 9. FACILITY BOUNDARY AND SITE FEATURES SURVEYED AT VARIOUS TIMES BY A NC LICENSED SURVEYOR GROUND ELEVATION (FEET, NAVD 88) TREE LINE (FROM RECENT AERIAL PHOTO) CONCRETE PAVEMENT PAVED OR GRAVEL -HARDENED ---------- FACILITY BOUNDARY JURISDICTIONAL WATER FEATURE CHANNEL OR SWALE GROUNDWATER MONITORING WELL LANDFILL GAS MONITORING WELL - SURFACE WATER SAMPLING POINT LOCATION INFO: 1. USGS TOPOGRAPHIC MAPS GRIMESLAND AND LEGGETTS 2. LATTITUDE 35.621646 AT SCALEHOUSE LONGITUDE-77.182862 OWNER ADDRESS: C&D LANDFILL, INC. 802 RECYCLING LANE GREENVILLE, NC 27834 OFFICE TELEPHONE (252) 752-8274 SCALE: 0 125 250 375 500 FEET A� SURFACE WATER TVOC-14.7 ' www.summitde.net DESIGN AND ENGINEERING SERVICES F CDS = CARBON DISULFIDE - - THE=19.1 BZN = BENZENE TVOC 29.6 ♦ C&D LANDFILL INC. ACE = ACETONE - • ♦ CORRECTIVE ACTION PLAN TVOC =TOTAL VOCs DETECTED VOC CONSTITUENT DATA FOR SEAL SCALE: AS NOTED DES: GDG J / MW-2S ��'� �.��,, `N C ARO��i, DWG TYPE: ANSI D 22"x34" DFTR : O ALL VALUES I N (ug/L) \ / / / : �� �FES Sj0•'•�'� JOB NO: 19-0248.004 CHKD: ASA MAY 2017 TH F=1.0 / ; z .o i / / QI�'DATE: 07-07-2020 ENGR: ASA � ^ � � _ Digitally ��I�Q by _ TVOC 1.0 : David c �1��-10;202Q FILENAME. C&D LANDFILL ACM 125_2 APPD: GDG ^•'•,n� �-•`�� DRAWING NO. / A 07/25/2017 6468-17-7070 PERMIT RENEWAL GDG ASA ASA GDG ISSUED FOR REVIEW ,�� I'I D VO C DISTRIBUTION -SHALLOW Q AL AA, rn REV DATE JOB NO. PROJECT TYPE DES DFTR CHKD ENGR APPD DESCRIPTION ,�����������,,, INCHES 1 2 3 TENTHS 10 20 30 4 5 6 7 8 9 10 2 3 4 5 6 7 8 1110 _/ &Aft e I . . : . . :.- -, % • 14 16 MW-1D woo 00 000 TH E=14.4 0*0 J 1TVOC 14.4 S �Mv� 14D�10 / I !' I 00 o / i ♦ ' o / IREV. A REFERENCE NOTES: 1. TOPOGRAPHY OUTSIDE THE FACILITY BOUNDARY TAKEN FROM 2006 NCDOT LIDAR DATA (NAVD 88) 2. ORIGINAL FACILITY DESIGN CA. 2000 BY JOHN TUCKER, PE 3. AS -BUILT DRAWING PREPARED BY DAVID GARRETT, PG, PE DURING 2009 PERMITTING CYCLE 4. SEDIMENT TRAPS AND DRAINAGE CHANNELS ARE DEPICTED AS SHOWN ON JOHN TUCKER DRAWING 1 OF 1, TITLED STORMWATER MANAGEMENT PLAN, SEPTEMBER 8, 2009 5. THE ARRANGEMENT OF WORKSPACES ON THE RECYCLING YARD MAY VARY FROM WHAT IS SHOWN ON THIS DRAWING 6. CURRENT WOODS AND OPEN SPACE TAKEN FROM PUBLIC DOMAIN AERIAL PHOTOGRAPHY DATED 2016 7. PLAT LINES OUTSIDE THE FACILITY BOUNDARY TAKEN FROM PITT COUNTY GIS TAX MAPS AND ARE APPROXIMATE. 8. NO CHANGES TO FACILITY LAYOUT, WASTE STREAM, STORMWATER DRAINAGE OR LEACHATE MANAGEMENT OR ANY DESIGN ASPECTS ARE PROPOSED AT THE TIME OF THIS DRAWING PREPARATION 9. FACILITY BOUNDARY AND SITE FEATURES SURVEYED AT VARIOUS TIMES BY A NC LICENSED SURVEYOR GROUND ELEVATION (FEET, NAVD 88) I I I I I I I I I I I I I I TREE LINE (FROM RECENT AERIAL PHOTO) CONCRETE PAVEMENT p '.a PAVED OR GRAVEL -HARDENED ---------- FACILITY BOUNDARY JURISDICTIONAL WATER FEATURE CHANNEL OR SWALE GROUNDWATER MONITORING WELL 1A--� �W 11 2 / �.. ..:..'. -10 LANDFILL GAS MONITORING WELL �-° SURFACE WATER SAMPLING POINT 1 W- 16 ,9 — LOCATION INFO: 16 i 12 1. USGS TOPOGRAPHIC MAPS GRIMESLAND AND LEGGETTS 18 a I 2. LATTITUDE 35.621646 AT SCALEHOUSE � 12 0 —-� LONGITUDE-77.182862 OWNER ADDRESS: CHEMICAL ABBREVIATIONS ti ;: _ C&D LANDFILL, INC. 802 RECYCLING LANE \ �f— — — GREENVILLE, NC 27834 r7 1 0 ` �� — XLN XYLENE ♦'o OFFICE TELEPHONE (252) 752 8274 VCL = VINYL CHLORIDE �� I \ � — � •� � �� �� SCALE: T L N — TOLUENE I 0 125 250 375 500 FEET TCE = TRICHLOROETHANE ` NPH = NAPHTHALENE iA m 5/ MEK = 2-BUUTANONE 100 E. Six Forks Road DCE =CIS-1 2-DICHLOR ETHENE 0 ��.: ': / Suite 320 i mW — I Raleigh, NC 27609 CLE — CHLOROETHANE — /' TEL: (919) 322-0115 CDS CARBON DISULFIDE — — � � � I J � � : . www.summltde.net DESIGN AND ENGINEERING SERVICES BZN = BENZENE ♦ C&D LANDFILL INC. ACE =ACETONE - CORRECTIVE ACTION PLAN TVOC =TOTAL VOCs / DETECTED VOC CONSTITUENT DATA FOR �: SEAL SCALE: AS NOTED DES: GDG RQ� DWG TYPE: ANSI D 22"x34" DFTR ALL VALUES I N (ug/L) / / =Q••,O��S Sj0�,• -7'�I JOB NO: 19-0248.004 CHKD: ASA i / / / : �� ��••: DATE: 07-07-2020 ENGR: ASA =Digitally y - /� .David 7 10-2020: FILENAME. C&D LANDFILL ACM 125_2 APPD: GDG / / / / / / \ C • •,�NG INC ��;•`�� :: DRAWING NO. A 07/25/2017 6468-17-7070= PERMIT RENEWAL GDG I ASA ASA GDG I ISSUED FOR REVIEW ��AID P ���,VO C CONCENTRATIONS (DEEP) 11 AA. rn REV DATE JOB NO. PROJECT TYPE DES I DFTR I CHKD I ENGR I APPD DESCRIPTION INCHES 1 2 3 TENTHS 10 20 30 4 5 6 7 8 9 1 0 F i 2 3 r a 1 t 1 M W-9A P ryp 8��-18 1 MW-16 I SW-4 MW-15 / 18 / 15 r / � O I 14 \�•, � ,8 I II ► MW-10 u i i� •'! MW-1D �_' M W-14SMW-14D is / MW-1 S .. - il/ �// .ry.;:'' 18 0 ••.ate \ c + l / / 1 M W-13 M W-11 e.• `` � — � . 0.90 — ,e�' MW 12s MW-8 MW 4 0. , � vs MW-3S /�'% , MW-3D - W_ MW-7 , M W- 3A IE % I i `. D �i♦ MW-6 ETHENE ��'/��-�i�/''` MW-2D °-.:� /�• -2S V. DETECTED VOC CONSTITUENT DATA FOR -7 I / SW-2 < C— BENZENE CONCENTRATIONS FOR \ l / / �� • JUN 2018, uG/L r 1 I r - W ,5 M 9 A I MW-16 ► ,-- I ,8 O _- M W-15 •� e� m � � ,S 00 14 M W-10 I Bi MW-1D :. MW-14S M W-14D,,.18 MW-1 S / 1 MW-13 / 18,g i I II .38 M 11� 1 M W-12 s 'ate M W- 8 %0 v MW-4 I _ 1 — , � - �"d. NJ 0.301 � SW-3 � , � I •:o ; � / � MW-3D � MW � W- .�,I �M 5 I MW-3A ♦ i MW-6 ETHENE �� / / / �''':; MW-2D DETECTED VOC CONSTITUENT DATA FOR / / 1 SW- 2 -7 _i }e BENZENE CONCENTRATIONS FOR JUN 2019, uG/L It INCHES 1 2 3 TENTHS 10 20 30 4 6 7 r MW-9A @.,8 I 1 is I I 'I ► / ' l� 18 I i � 1 � M W-15 :� '@� 78 \ 15 14 � I 18� I� � ► M W-10 I m J � 1.57 a - • m MW-1D W-14D .4MW-14S M .M.W-1S: .- / 1 M W-13 II m 0.48J M W-11 -° I ( MW-12s a MW-g l \ 1.48 12 /M W- 4 0.48J �.;:... S W_ NS , ` �� MW-3S :' _.♦-- -�, 1 � MW-7 , i3r MW-3D W_ MW-3A ♦ JE J I ) 1.69 ETHENE //��\—�/ �..� MW-2D MW-2S DETECTED VOC CONSTITUENT DATA FOR I / SW -2 - BENZENE CONCENTRATIONS FOR DEC 2018, r a 1 - r - MW 9A MW-16Ir it; i is O SW-4 - M W-15 15 I / / I MW-10 MW-14S ° MW-1S - ,q, \ o r A I m - M W-11 ' 2.56 1 MW-12s ,@ MW-8 l MW-4 2.12 12 1 13 a — \ 12� V SW / 1 100 E. Six Forks Road , J Suite 320 NS ��� �� '� MW-3S Raleigh, NC 27609 1 MW-7 �'TEL: (919) 322-0115 ` ` ► �,�V l 1.81 MW-3D ; ,► , MW_ 5 www.summitde.net I M W- 3 A 1.49 JE ► �/ i .�. M W- 6 7. ETHENE ��� /��—� j�/ ': MW-2D / ♦� SEAL MW-2S �' ♦ �� nrTrnTrn „nn //,1.If1TIT1 irIT / / 0.44J 1 • SW-2 qTA FOR BENZENE CONCENTRATIONS FOR DEC 2019 uG L A 07/25/2017 6468-17-7070 PERMIT RENEWAL GDG ASA ASA GDG ISSUED FOR REVIEW REV DATE JOB NO. PROJECT TYPE DES DFTR CHKD ENGR APPD DESCRIPTION 5 6 7 i 8 I IREV. A REFERENCE NOTES: 1. TOPOGRAPHY OUTSIDE THE FACILITY BOUNDARY TAKEN FROM 2006 NCDOT LIDAR DATA (NAVD 88) 2. ORIGINAL FACILITY DESIGN CA. 2000 BY JOHN TUCKER, PE 3. AS -BUILT DRAWING PREPARED BY DAVID GARRETT, PG, PE DURING 2009 PERMITTING CYCLE 4. SEDIMENT TRAPS AND DRAINAGE CHANNELS ARE DEPICTED AS SHOWN ON JOHN TUCKER DRAWING 1 OF 1, TITLED STORMWATER MANAGEMENT PLAN, SEPTEMBER 8, 2009 5. THE ARRANGEMENT OF WORKSPACES ON THE RECYCLING YARD MAY VARY FROM WHAT IS SHOWN ON THIS DRAWING 6. CURRENT WOODS AND OPEN SPACE TAKEN FROM PUBLIC DOMAIN AERIAL PHOTOGRAPHY DATED 2016 7. PLAT LINES OUTSIDE THE FACILITY BOUNDARY TAKEN FROM PITT COUNTY GIS TAX MAPS AND ARE APPROXIMATE. 8. NO CHANGES TO FACILITY LAYOUT, WASTE STREAM, STORMWATER DRAINAGE OR LEACHATE MANAGEMENT OR ANY DESIGN ASPECTS ARE PROPOSED AT THE TIME OF THIS DRAWING PREPARATION 9. FACILITY BOUNDARY AND SITE FEATURES SURVEYED AT VARIOUS TIMES BY A NC LICENSED SURVEYOR GROUND ELEVATION (FEET, NAVD 88) TREE LINE (FROM RECENT AERIAL PHOTO) CONCRETE PAVEMENT PAVED OR GRAVEL -HARDENED ---------- FACILITY BOUNDARY JURISDICTIONAL WATER FEATURE CHANNEL OR SWALE GROUNDWATER MONITORING WELL LANDFILL GAS MONITORING WELL - SURFACE WATER SAMPLING POINT LOCATION INFO: 1. USGS TOPOGRAPHIC MAPS GRIMESLAND AND LEGGETTS 2. LATTITUDE 35.621646 AT SCALEHOUSE LONGITUDE-77.182862 OWNER ADDRESS: C&D LANDFILL, INC. 802 RECYCLING LANE GREENVILLE, NC 27834 OFFICE TELEPHONE (252) 752-8274 SCALE: 0 125 250 375 500 FEET m SUS �IIT DESIGN AND ENGINEERING SERVICES F— C&D LANDFILL, INC. CORRECTIVE ACTION PLAN _ SCALE: AS NOTED DES: GDG ,.`C ARQ�� �i��, DWG TYPE: ANSI D 22"x34" DFTR : ' SIO�•• 9 CHKD. ASA JOB NO. 19-0248.004 ��••O��S i DATE: 07-07-2020 ENGR: ASA 'ate 7- • Digita•lly lb : _ DaVad Gar fq? 10 ,2020_ FILENAME: C&D LANDFILL ACM 125_2 APPD: GDG C '•,� ��;•` DRAWING NO. CHANGES WITH TIME (BENZENE) 8 9 10 12 m F 4 5 6 a ...... - \J M W-16 4 16 SW-4 MW-15 �f% M W-10 m r 1k m-J 2.00 � o MW-1D M W-14D 18 M W-14S MW-1S_ , v / M W-13 I@----,e �15 Im MW-11 MW-12s MW—g A . 12 1k 12 ,5 SW-1—\ vs MW MW-3D W— MW-7 �/— I MW 3A / IE % I ► �� ETHENE MW-2D MW-2S ` �/ VINYL CHLORIDE CONCENTRATIONS )R / / SW-2 FOR JUN 2018 uG L r I r - W .,g M 9 A 5 I MW-16 ,g ► ,-- ,@ i I '- - a16 k M W-15 e� ,@ s / 14 M W-10 I J 1.77 ,k a' MW-14S • m m MW-1 D MW-14D; MW-1 S i / M W-130.69 @� I 11 m MW-11 G M W-12 s 18� M IN— R 3.33 ,a SW-1 vs SW —3 MW-3S— 1 / MW-7 ��---- I M W— 3D :� W_ �M 5 I MW-3A ETHENE �� / / / �''':; MW-2D BMW-2S �• ---=---- -- -- --- - -- - --R / / < VINYL CHLORIDE CONCENTRATIONS / e FOR JUN 2019 INCHES 1 2 3 TENTHS 10 20 30 4 MW-16j SW-4 MW-15 �po O ► I ,t ► MW-9A I ► ,8 ► I , 1 m IIII I I� ► m 1 7 M W-10 J 2.20 •'! MW—ID MW-14S S. MW-14D is MW-1 S �.. / M W-13@r—,e I I m I :.. MW 12s MW-8 A 2.21 ,2 MW 4 I . 12 a ,g INS\\ \ SW 3 MW-3S I ,a 1.82J� MW-3D� 1.25J MW-7 �r— I� < < W— I M 5 JE % I 1.091 0.18JMW6 / ETHENE MW-2D MW-2S SW-2 �— C VINYL CHLORIDE CONCENTRATIONS l / FOR DEC 2018 uG L r a 1 - r - _ MW 9A MW-16 IsSw— is MW-15 is\ s ' S G m M W-10 I , . I m k m 0.33 M 1D ��' 1 MW-14DMW-14S' MW-1S i I - � � l •.:.I � 0.57 MW-11 11 , M W-12 s 18 i @ MW 8 MW-4 I ,5 A � 100 E. Six Forks Road SW_ 1 Suite 320 SW-3 Ns MW-3S _':::;:. _ _,� Raleigh, NC 27609 1 MW-7 ;'TEL: (919) 322-0115 W— ,► M 5 www.summitde.net I MW-3A / 0. JE i .. M W— 6 ETHENE MW-2D / /' SEAL VINYL CHLORIDE CONCENTRATIONS -J /�/// ' MW-2S )R / / 1 SW-2 — FOR DEC 2019, uG/L 7 / A 07/25/2017 1 6468-17-7070 PERMIT RENEWAL GDG ASA ASA GDG ISSUED FOR REVIEW REV DATE JOB NO. PROJECT TYPE DES DFTR I CHKD ENGR APPD DESCRIPTION 5 6 7 i 8 I IREV. A ,�%��.��������••,,. N CAR 'ES Sj O��'1,''', Digi ally b)� ; = David GiRff)c4i5Z 10-2020. �v REFERENCE NOTES: 1. TOPOGRAPHY OUTSIDE THE FACILITY BOUNDARY TAKEN FROM 2006 NCDOT LIDAR DATA (NAVD 88) 2. ORIGINAL FACILITY DESIGN CA. 2000 BY JOHN TUCKER, PE 3. AS -BUILT DRAWING PREPARED BY DAVID GARRETT, PG, PE DURING 2009 PERMITTING CYCLE 4. SEDIMENT TRAPS AND DRAINAGE CHANNELS ARE DEPICTED AS SHOWN ON JOHN TUCKER DRAWING 1 OF 1, TITLED STORMWATER MANAGEMENT PLAN, SEPTEMBER 8, 2009 5. THE ARRANGEMENT OF WORKSPACES ON THE RECYCLING YARD MAY VARY FROM WHAT IS SHOWN ON THIS DRAWING 6. CURRENT WOODS AND OPEN SPACE TAKEN FROM PUBLIC DOMAIN AERIAL PHOTOGRAPHY DATED 2016 7. PLAT LINES OUTSIDE THE FACILITY BOUNDARY TAKEN FROM PITT COUNTY GIS TAX MAPS AND ARE APPROXIMATE. 8. NO CHANGES TO FACILITY LAYOUT, WASTE STREAM, STORMWATER DRAINAGE OR LEACHATE MANAGEMENT OR ANY DESIGN ASPECTS ARE PROPOSED AT THE TIME OF THIS DRAWING PREPARATION 9. FACILITY BOUNDARY AND SITE FEATURES SURVEYED AT VARIOUS TIMES BY A NC LICENSED SURVEYOR GROUND ELEVATION (FEET, NAVD 88) I I I I I I I I I I I I I I TREE LINE (FROM RECENT AERIAL PHOTO) CONCRETE PAVEMENT q. PAVED OR GRAVEL -HARDENED ---------- FACILITY BOUNDARY JURISDICTIONAL WATER FEATURE CHANNEL OR SWALE GROUNDWATER MONITORING WELL LANDFILL GAS MONITORING WELL - SURFACE WATER SAMPLING POINT LOCATION INFO: 1. USGS TOPOGRAPHIC MAPS GRIMESLAND AND LEGGETTS 2. LATTITUDE 35.621646 AT SCALEHOUSE LONGITUDE -77.182862 OWNER ADDRESS: C&D LANDFILL, INC. 802 RECYCLING LANE GREENVILLE, NC 27834 OFFICE TELEPHONE (252) 752-8274 SCALE: 0 125 250 375 500 FEET m DESIGN AND ENGINEERING SERVICES F C&D LANDFILL, INC. CORRECTIVE ACTION PLAN SCALE: AS NOTED DES: GDG DWG TYPE: ANSI D 22"x34" DFTR : JOB NO: 19-0248.004 CHKD: ASA DATE: 07-07-2020 ENGR: ASA FILENAME: C&D LANDFILL ACM 125_2 APPD: GDG DRAWING NO. CHANGES W/ TIME (VINYL CHLORIDE) 13 9 1 10 F i 2 3 r a 1 ,t 1 M W-9A 11- P ryp a��-18 1 MW-16 I SW-4 MW-15 / 18 / 15 r / � O I 14 \�•, I ,8 I II ► MW-10 u i i� •'! MW-11D �_' M W-14S / MW-14D 14is MW-1 S .. — �/ �// ...•4.,:'' 18 0 '•,ate \ c + l M W-13 m MW-11 MW 12s MW-8 o SW-1\ vS SW-3 MW-3S � MW-7 �f---- �/ MW-3D � MW-5 MW-3A / IE ETHENE MW-2D °-.:� /�• —2S / C— nr7T nT,-n 1inr+ nnnloT\ 11rK1T DATA FOR // SW-2 VOC CONCENTRATIONS FOR `\�;: e } / / JUN 2018, uG/L \ / r , I r W .,a M — 9 A a I is MW-16 is ► ,-- I18A4/ 18 18 / SW_4 a THE 0.40J MW-15 e� 75 is / � / � 14 I 18- I 1 M W-10 I Bi MW-1D :. MW-14S M W-14D ,,4i 18 / ii j / I I . MW-1 S / MW-13 / 18,g i I 1110, M 11� 1: = MW-12S - 'THF1.10 _ VS \ SW 3 /� MW-3S F 0.73J C� I/BMW-3D W— �,I �M 5 I MW-3A ETHENE �� / / �''':; MW-2D —2S �• / DETECTED VOC CONSTITUENT DATA FOR / / 1�,_A­ SW— 2 <'/ _i VOC CONCENTRATIONS FOR - l i `�` THE 1.10 JUN 2019 uG L INCHES 1 2 3 TENTHS 10 20 30 4 6 7 r MW-9A 1 is I I 'I ► / ' l� 18 I i � 1 � M W-15 :� '@� 7815 \ 14 � I 18� I� � ► M W-10 I m J • m MW-1D � MW-14D .4MW-14S ,a— / MW-1S / M W-13 1g—,e ` I m� M W-11 I ( MW 8 MW-4 SW 3 NS �MW-3S TOL 0.38J MW-3D� MW-3A ♦ JE ETHENE MW-2D MW-2S ; . nFTF('.TFf1 \/n(.. (.nM.gTITI IFNT IIATA FOR / VOC CONCENTRATIONS FOR , DEC 2018, uG/L r _ a 1 1 ► - r — MW 9A MW-16 i SW-4 - is M W-15 'r is ,S ' S G MW-10 MW-14S ° MW-1S — I - i � MW-12s MW—g - MW-4. "� 100 E. Six Forks Road /,g SW 1 Suite 320 SW-3 � NS MW-3S �THIF 4 22 ,� Raleigh, NC 27609 1 MW-7 TEL: (919) 322-0115 I / MW-3D I (([� W_ 5 ,►, � M � www.summitde.net I MW-3A / 0: JE i .�. M W— 6 / ETHENE MW-2D / �' SEAL VOC CONCENTRATIONS FOR DATA FOR SW-2 DEC 2019 uG L -7 i / i THE 0.93J A 07/25/2017 6468-17-7070 PERMIT RENEWAL GDG ASA ASA GDG ISSUED FOR REVIEW REV DATE JOB NO. PROJECT TYPE DES DFTR CHKD ENGR APPD DESCRIPTION 5 6 7 i 8 I IREV. A REFERENCE NOTES: 1. TOPOGRAPHY OUTSIDE THE FACILITY BOUNDARY TAKEN FROM 2006 NCDOT LIDAR DATA (NAVD 88) 2. ORIGINAL FACILITY DESIGN CA. 2000 BY JOHN TUCKER, PE 3. AS -BUILT DRAWING PREPARED BY DAVID GARRETT, PG, PE DURING 2009 PERMITTING CYCLE 4. SEDIMENT TRAPS AND DRAINAGE CHANNELS ARE DEPICTED AS SHOWN ON JOHN TUCKER DRAWING 1 OF 1, TITLED STORMWATER MANAGEMENT PLAN, SEPTEMBER 8, 2009 5. THE ARRANGEMENT OF WORKSPACES ON THE RECYCLING YARD MAY VARY FROM WHAT IS SHOWN ON THIS DRAWING 6. CURRENT WOODS AND OPEN SPACE TAKEN FROM PUBLIC DOMAIN AERIAL PHOTOGRAPHY DATED 2016 7. PLAT LINES OUTSIDE THE FACILITY BOUNDARY TAKEN FROM PITT COUNTY GIS TAX MAPS AND ARE APPROXIMATE. 8. NO CHANGES TO FACILITY LAYOUT, WASTE STREAM, STORMWATER DRAINAGE OR LEACHATE MANAGEMENT OR ANY DESIGN ASPECTS ARE PROPOSED AT THE TIME OF THIS DRAWING PREPARATION 9. FACILITY BOUNDARY AND SITE FEATURES SURVEYED AT VARIOUS TIMES BY A NC LICENSED SURVEYOR GROUND ELEVATION (FEET, NAVD 88) TREE LINE (FROM RECENT AERIAL PHOTO) CONCRETE PAVEMENT PAVED OR GRAVEL -HARDENED ---------- FACILITY BOUNDARY JURISDICTIONAL WATER FEATURE CHANNEL OR SWALE GROUNDWATER MONITORING WELL LANDFILL GAS MONITORING WELL - SURFACE WATER SAMPLING POINT LOCATION INFO: 1. USGS TOPOGRAPHIC MAPS GRIMESLAND AND LEGGETTS m 2. LATTITUDE 35.621646 AT SCALEHOUSE LONGITUDE-77.182862 OWNER ADDRESS: C&D LANDFILL, INC. 802 RECYCLING LANE GREENVILLE, NC 27834 D OFFICE TELEPHONE (252) 752-8274 SCALE: 0 125 250 375 500 FEET SUS �IIT DESIGN AND ENGINEERING SERVICES F— C&D LANDFILL, INC. CORRECTIVE ACTION PLAN SCALE: AS NOTED DES: GDG �N C ARQ�iDWG TYPE: ANSI D 22"x34" DFTR �Q•..O��S SjO�•,+ 9 i JOB NO. 19-0248.004 CHKD. ASA DATE: 07-07-2020 ENGR: ASA Digita�ty s&by� : - David G@rj)46-e10-2020: FILENAME: C&D LANDFILL ACM 125_2 APPD: GDG DRAWING NO. SURFACE WATER QUALITY G P� 8 9 10 14