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HomeMy WebLinkAbout3405_Forsyth_RJRRuralHall_Indus_April20GW_FID1418219_20200707Signature v I-, L Date ERM NC, Inc. - 300 Summit Avenue, Suite 330, Charlotte, NC 28203 Facility Representative Address NC Professional Geologic Corporation # C-470 NC PE Firm License Number (if applicable effective May 1, 2009) DENR USE ONL)_I ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: 'NC DENR Environmental Monitoring Division of Waste Management - Solid Waste Reportina Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): ERM NC, Inc. (consultant) Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Alan Martin Phone: 704-541-8345 E-mail: alan.martin@erm.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) R.J. Reynolds Industrial Landfill Edwards Road (S.R. 1903) 34-05 0.0503 March 31-April 2, 2020 Rural Hall, Forsyth County Environmental Status: (Check all that apply) Initial/Background Monitoring Detection Monitoring Assessment Monitoring 0 Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells Leachate monitoring data ❑ Surface water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Alan Martin, PG Project Manager 704-541-8345 Facility Representativ^ me, Print) , __L Title (Area Code) Telephone Number 1Uly 7, 2020 NC Licensed/ Professional Geologist Seal ��GAR� L JN4' � 00 Ef) •. Z' '+ gCAN�• Revised 6/2009 t� Groundwater &Surface Water Monitoring Semi- (fRlReynolds Annual Summary Report — April 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina July 2020 Project No.: 0551517 The business of sustainability ERM ERM ERM, NC, Inc. Telephone: +1 704 541 8345 300 West Summit Avenue Fax: +1 704 624 7928 Suite 330 www.erm.com Charlotte, NC 28203 July 7, 2020 North Carolina Department of Environmental Quality Division of Waste Management 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Attention: Ms. Jaclynne Drummond jaclynne.drummond@ncdenr.gov Via Email Subject: Groundwater and Surface Water Monitoring Semi -Annual Summary Report — April 2020 Permit #34-05 - Edwards Road Landfill Edwards Road Rural Hall, Forsyth County, North Carolina Dear Ms. Drummond: On behalf of R.J. Reynolds Tobacco Company, ERM NC, Inc. (ERM) is submitting the summary report for the April 2020 groundwater and surface water monitoring event associated with the subject property. As outlined in Section 5.0 of the report, ERM is requesting NCDEQ authorization to discontinue analyzing groundwater samples from piezometers at the subject property due to inconsistent results attributable to frequently elevated turbidity in these samples. The piezometer groundwater samples will continue to be analyzed for sulfates, the primary indicator of landfill -related impacts, and total dissolved solids. If acceptable, please provide written authorization to omit future metals analyses for the piezometer groundwater samples. Please contact Mr. Scott Snow of R.J. Reynolds Tobacco Company at 336-741-2236 or me if you have any questions or comments. Sincerely, �&� Alan M rtin, P.G. Project Manager Attachments: Environmental Monitoring Reporting Form Groundwater and Surface Water Monitoring Semi -Annual Summary Report cc: Mr. Scott Snow - R.J. Reynolds Tobacco Company Mr. Max Hopkins - R.J. Reynolds Tobacco Company Mr. Tom Wilson - ERM Mr. Dave Wasiela - ERM Signature Page July 2020 Groundwater & Surface Water Monitoring Semi -Annual Summary Report — April 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina Alan Martin P.G! Project Manager NSE� •'•.�9 L uit:Q�tl_ �11'11 • homas M. Wilson, P.G. Principal in Charge ERM NC, Inc. 300 West Summit Avenue, Suite 330 Charlotte, North Carolina 28203 Phone: +1-704-541-8345 © Copyright 2020 by ERM Worldwide Group Ltd and / or its affiliates ("ERM"). All rights reserved. No part of this work may be reproduced or transmitted in any form, or by any means, without the prior written permission of ERM www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. July 2020 2020-04 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING CONTENTS SEMI-ANNUAL SUMMARY REPORT — APRIL 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina CONTENTS 1. INTRODUCTION................................................................................................................................1 2. HISTORICAL GROUNDWATER AND SURFACE WATER QUALITY.............................................1 3. SUMMARY OF MONITORING PROGRAM.......................................................................................1 4. DESCRIPTION OF WATER QUALITY CONDITIONS...................................................................... 3 4.1 Site Hydrogeology................................................................................................................................3 4.2 Groundwater.........................................................................................................................................4 4.3 Surface Water.......................................................................................................................................5 5. PRELIMINARY ANALYSIS................................................................................................................6 6. REFERENCES...................................................................................................................................8 List of Figures Figure 1 Site Location Plan ....................................................... Figure2 Site Plan..................................................................... Figure 3 Groundwater Flow Directions .................................... Figure 4 Groundwater Sampling Results — September 2019.. Figure 5 Surface Water Sampling Results — September 2019 Figure 6 Sulfate Isocontour Map - Groundwater ...................... Figure 7 Hydrogeologic Conceptual Model .............................. Figure 8 Sulfate Trends - Groundwater ................................... Figure 9 Sulfate Trends — Surface Water ................................ List of Tables 9 9 9 9 9 9 9 9 9 Table 1 Monitor Well Construction Details................................................................................................... 9 Table 2 Groundwater Elevations..................................................................................................................9 Table 3 Groundwater and Surface Water Sampling Event Summary Data.................................................9 Table 4 Groundwater Field Parameters.......................................................................................................9 APPENDIX A HISTORICAL GROUNDWATER AND SURFACE WATER QUALITY ANALYTICAL DATA APPENDIX B LABORATORY DATA SHEETS APPENDIX C GROUNDWATER SAMPLING LOGS www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. July 2020 Page i 2020-04 Edwards Rd LF Rural Hall GW Repon.docx GROUNDWATER & SURFACE WATER MONITORING SEMI-ANNUAL SUMMARY REPORT — APRIL 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina INTRODUCTION INTRODUCTION In accordance with the February 4, 2014 Corrective Action Plan (ERM NC, Inc.) and the Industrial Solid Waste Landfill Facility Permit No. 34-05-indus-1986 as amended through August 12, 2011, this report presents the results of the April 2020 groundwater and surface water sampling event conducted at the closed Edwards Road Landfill previously operated by R.J. Reynolds Tobacco Company. The closed landfill is located northeast of the jurisdictional boundaries of Rural Hall, Forsyth County, North Carolina and the location of the Site along with topographic map coverage of the vicinity are shown on Figure 1. Historical monitoring data indicate the occurrence of certain inorganic compounds in excess of the North Carolina Groundwater Standards (15A NCAC 2L) and Surface Water Standards (15A NCAC 213) in portions of the landfill site. A Corrective Action Plan (ERM) to restore groundwater quality beyond the compliance boundary, to stop unacceptable impacts to the adjacent surface waters, and to reduce the overall groundwater contamination at the facility was approved by the North Carolina Department of Environmental Quality (NCDEQ, formerly known as Department of Environment and Natural Resources) on February 19, 2014. The selected remedy includes source area contaminant control via the previous installation of the synthetic liner (cap) over the limits of waste plus drainage improvements (completed in 2012) to minimize rainfall infiltration, leachate generation and discharge of constituents to groundwater, to allow intrinsic remediation of the existing affected -groundwater. Groundwater and surface water monitoring has been conducted semi-annually at the site since the completion of the synthetic cap installation and the drainage improvements in 2012. 2. HISTORICAL GROUNDWATER AND SURFACE WATER QUALITY Groundwater and surface water quality monitoring has been conducted in the vicinity of the Edwards Road Landfill since 1989 in accordance with the conditions of Permit Number 34-05 and subsequent to the closure of the landfill, in accordance with the approved Post Closure Monitoring Plan. An updated water quality monitoring plan presented in the February 2014 CAP (ERM) was approved by NCDEQ on February 19, 2014 and is summarized in Section 3. Figure 2 depicts the locations of the groundwater monitor wells and surface water sampling locations and Table 1 presents a summary of available well construction details. Historical laboratory analytical results for available groundwater and surface water samples are summarized in Appendix A. 3. SUMMARY OF MONITORING PROGRAM Routine groundwater and surface water monitoring activities were conducted on March 31 -April 3, 2020 and are summarized in the following table: www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. July 2020 Page 1 2020-04 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING SEMI-ANNUAL SUMMARY REPORT — APRIL 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina Sampling and Analvses Plan SUMMARY OF MONITORING PROGRAM Analytical Parameters Sample Metals a Sulfate Total Dissolved Field Location I.D. (EPA 6020B/ Solids b (EPA 300Parameters .0) 7074) (SM 2540C) Groundwater: W-1 ✓ ✓ ✓ ✓ W-2 ✓ ✓ ✓ ✓ W-3 ✓ ✓ ✓ ✓ W-31B ✓ ✓ ✓ ✓ W-5 -- ✓ ✓ ✓ W-6 ✓ W-7 ✓ ✓ ✓ ✓ W-8 ✓ ✓ ✓ ✓ W-9 ✓ ✓ ✓ ✓ PW-1 ✓ ✓ ✓ ✓ PZ-1 ° Dry, no sample collected PZ-2 ✓ ✓ ✓ ✓ PZ-3 c Dry, no sample collected PZ-4 ✓ ✓ ✓ ✓ PZ-5 ✓ ✓ ✓ ✓ L-O PZ-7 d -- -- -- -- PZ-8 d -- -- -- -- PZ-9 d -- -- -- -- PZ-10 d -- -- -- -- Subtotal 12 12 12 12 Surface Water: SS-01 ✓ ✓ ✓ ✓ oo-u I t 150 d -- -- -- -- SS-01+550 d -- -- -- -- SS-01+850 d -- -- -- -- SS-02 ✓ ✓ ✓ ✓ SS-10 -- -- -- -- SS-15 -- -- -- -- SS-20 ✓ ✓ ✓ ✓ SS-25 ✓ ✓ ✓ ✓ SS-30 ✓ ✓ ✓ ✓ SS-40 ✓ ✓ ✓ ✓ SS-50 ✓ ✓ ✓ ✓ SS-60 ✓ ✓ ✓ ✓ SS-70 ✓ ✓ ✓ ✓ SS-80 ✓ ✓ ✓ ✓ SS-90 ✓ ✓ ✓ ✓ Subtotal 11 11 11 11 TOTAL 23 23 23 23 3 Aluminum, barium, cadmium, chromium (total), iron, lead, manganese and selenium. b Field parameters include temperature, pH, specific conductivity, turbidity, dissolved oxygen, and oxidation-reduction potential. PZ-1 and PZ-3 were dry during the April 2020 sampling event. d Temporary point not included in routine sampling. The groundwater and surface water monitoring activities were performed in general accordance with the techniques presented in the February 2014 CAP. Depth -to -water measurements and groundwater elevations for available monitor wells from the April 2020 sampling event are presented in Table 2. Groundwater flow directions are presented on Figure 3. Groundwater and surface water analytical data from the April 2020 sampling are presented in Table 3. Field collection parameters are provided in Table www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. July 2020 Page 2 2020-04 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING SEMI-ANNUAL SUMMARY REPORT — APRIL 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina DESCRIPTION OF WATER QUALITY CONDITIONS 4. Historical analytical data for both groundwater and surface water are presented in Appendix A. Laboratory data sheets for the April 2020 sampling event are presented in Appendix B. Copies of the sample logs are provided in Appendix C. Groundwater and surface water sample analytical results from the April 2020 sampling event are presented on Figures 4 and 5, respectively. Figure 6 depicts the isoconcentration contours of sulfates in groundwater at the site and Figure 7 presents a hydrogeologic conceptual site model and cross-section. Sulfate concentrations in groundwater and surface water over time are presented graphically on Figures 8 and 9, respectively. 4. DESCRIPTION OF WATER QUALITY CONDITIONS The following sections highlight key findings from the analytical results. 4.1 Site Hydrogeology The Site geology consists of fractured bedrock (gneiss and schist) overlain by partially weathered rock and a mantle of residual soils near the surface. The depth to bedrock beneath the Site generally ranges from 10 to 50 feet bgs. The first occurrence of groundwater beneath the upper portion of the site is within the fractured bedrock. In the lower portions of the site near the streams, groundwater is encountered within the partially weathered rock above the top of hard bedrock (transition zone). Shallow groundwater beneath the Site migrates either along the top of bedrock or along the permeable zones within the shallow fractured bedrock zone and discharges into nearby creeks, namely Leak Creek and its tributaries. The regional groundwater flow regime within the lower portion of the deep bedrock aquifer is north-eastward toward the nearest regional drainage feature, Town Fork Creek. The depth to groundwater in the top -of -rock aquifer zone ranges from approximately 0 feet at the creeks to 13 feet in shallow monitor wells. The depth to water in the bedrock aquifer ranges from artesian conditions to approximately 110 feet below ground surface in the measured wells. Using recent depth to water measurements, Site groundwater elevations and hydraulic gradients for the Site were calculated as summarized below. Horizontal Hydraulic Gradient - Saprolite/PWR March 31, 2020 Well Reference Depth to Head Head Distance Hydraulic Designation Elevation Water Elevation Change Change Gradient ft MSL ft ft ft) (ft)ft/ft W-1 822.68 13.28 809.40 29.40 180 0.1633 Leak Creek a 780.0 0.00 780.0 W-3 804.43 3.43 801.00 15.50 80 0.1938 Leak Creek a 785.5 0.00 785.5 Average Hydraulic Gradient 0.1786 a Leak Creek bed elevation represents groundwater discharge line Based on the April 2020 hydraulic gradients, the groundwater flow rate (seepage velocity) in the saprolite/PWR aquifer zone was calculated as summarized below. www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. July 2020 Page 3 2020-04 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING SEMI-ANNUAL SUMMARY REPORT — APRIL 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina Groundwater 5eepacie Velocity calculation = Ki/ne DESCRIPTION OF WATER QUALITY CONDITIONS where: K = hydraulic conductivity 0.080 ft/day (estimated) i = horizontal hydraulic gradient 0.1786 ft/ft (measured) ne = effective porosity 0.25 estimated Groundwater Seepage Velocity (Saprolite/PWR) = _ (0.08) ( 0.1786) / (0.25) = 5.72 x 10-2 ft/day or 20 ft/year The widely spaced locations of the bedrock monitor wells at the Site do not allow for calculation of the hydraulic gradient and groundwater flow rate of the bedrock aquifer. 4.2 Groundwater During the April 2020 groundwater sampling event, nine monitor wells were sampled utilizing a low flow, low volume sample collection technique. During the event, three piezometers were sampled using a bailer due to insufficient volume for low flow sampling procedures. Piezometers PZ-1 and PZ-3 were dry during the sampling event. Presently, samples from groundwater monitoring wells at the the Site contain concentrations of sulfates, total dissolved solids, and three metals above the applicable North Carolina groundwater standards (NC 2L standard). Sulfate, the primary constituent related to the landfill, was detected in two groundwater samples in excess of the NC 2L standard. Iron was detected in four of the nine groundwater monitoring well samples in excess of the NC 2L standard. Manganese was detected in five of the nine groundwater monitoring well samples in excess of the NC 2L standard. Selenium was detected in one groundwater monitoring well sample in excess of the NC 2L standard. Dissolved solids were detected in three of the groundwater monitoring well samples in excess of the NC 2L standard. The elevated concentrations of iron and manganese in samples from the Site monitor wells may be attributable to their natural occurrence in groundwater as indicated by historical sample results from onsite background monitor wells (W-6 and former W-4). Seven metals were detected in groundwater from the three piezometers sampled in concentrations above the applicable NC 2L standards. Concentrations of aluminum, cadmium, chromium (total), iron, and manganese exceed the applicable standards in PZ-02, PZ-04 and PZ-05. Barium and lead exceeded the applicable standards in PZ-02 and PZ-04. The elevated concentrations of metals in the piezometer samples are likely attributed to very high turbidity and the inability to sample utilizing low flow procedures, due to insufficient water volume. Elevated turbidity conditions common to samples from piezometers installed via hand auger are attributed to insufficient sand pack to properly filter suspended soil particles from water migrating into the screened interval. Sulfate levels in groundwater samples from the piezometers do not exceed the applicable standard. As noted in Section 1, installation of the synthetic cap and construction of drainage improvements over the limits of waste were completed in September 2012. The April 2020 samples were collected approximately 7.5 years after the cap installation. Sulfate concentrations from the April 2020 samples from shallow monitor wells W-1 and W-2, located near the limits of waste, indicate a continuing overall trend of stable or decreasing sulfate levels since the installation of the synthetic landfill cap in 2012. The April 2020 sulfate concentrations from shallow monitor well W-3, also near the limits of waste, indicate a continuing trend of fluctuating to decreasing sulfate levels since completion of the landfill cap installation in September 2012. During the same period, sulfate concentrations at bedrock monitor well W-313, located adjacent to W-3, continue to show an overall stable or decreasing trend. At W-1, a trend of fluctuating concentrations of iron is shown, while manganese and total dissolved solids concentrations remained stable compared to historical sample results prior to installation of the synthetic cap. At W-3, www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. July 2020 Page 4 2020-04 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING DESCRIPTION OF WATER QUALITY CONDITIONS SEMI-ANNUAL SUMMARY REPORT — APRIL 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina iron concentrations remained below the NC 2L standard and total dissolved solids concentrations have decreased from 2018 to 2020. Manganese concentrations at W-3 trended upward following the installation of the synthetic cap in 2012, but have decreased since 2018 and remain within the range of the historical analytical results. Overall, the April 2020 groundwater quality results and the historical concentration trends indicate that groundwater quality improvements are evident in most monitor wells located at the perimeter of the landfill. 4.3 Surface Water During the April 2020 sampling event, 11 surface water samples were collected. The April 2020 surface water monitoring results indicate there are no surface water quality impacts directly attributable to the landfill. Concentrations of sulfates and total dissolved solids in all of the samples collected during the April 2020 sampling event were below the applicable North Carolina surface water standards (NC 2B standards). Manganese was below the applicable North Carolina surface water standards in all of the surface water samples. Iron was reported in four surface water samples above the North Carolina surface water standard however each of the samples was collected from upgradient of the landfill (SS-20, SS-25, SS-30, and SS-50). Sulfate concentrations from the surface water samples with historical results display a generally declining to stable trend when compared to the September 2012 surface water results. Overall, April 2020 surface water quality results confirm that the corrective actions at the site have been effective for the remediation of the surface water quality at the site. Compared to upstream surface water quality, there have been four confirmed on -site exceedances of surface water quality standards in the streams since 2014. There have been no exceedances of surface water quality standards downstream of the landfill (SS-40, SS-80 or SS-90) since installation of the synthetic landfill cap in 2012. www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. July 2020 Page 5 2020-04 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING PRELIMINARY ANALYSIS SEMI-ANNUAL SUMMARY REPORT — APRIL 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina 5. PRELIMINARY ANALYSIS The April 2020 monitoring results demonstrate: ■ Sulfate, total dissolved solids, iron, manganese and selenium in groundwater monitoring well samples exceed the NC 2L standards. Concentrations of all detected analytes in groundwater were within the normal range of historical fluctuations. ■ Overall, the groundwater quality data indicate that the concentration trends and area of affected groundwater have been stabilized or reduced at the Site. Using sulfate as a primary indicator of landfill -related impacts, the sulfate concentration trends in groundwater, since completion of the landfill cap installation in September 2012, are generally decreasing including at the PW-1. ■ Seven metals in the groundwater samples from piezometer groundwater samples exceed the NC 2L standards. The elevated concentrations of aluminum, barium, cadmium, chromium, iron, lead manganese in the piezometer samples are not considered representative because the levels are attributed to very high turbidity and the inability to sample utilizing low flow procedures, due to insufficient water volume. ERM recommends discontinuing metals analysis of the piezometer groundwater samples due to the inconsistent results attributed to turbidity in these samples. Sulfate, the primary indicator of landfill -related impacts, and total dissolved solids will continue to be analyzed in the piezometer groundwater samples. ■ No elevated concentrations of sulfates, metals or total dissolved solids have been detected in the off - site groundwater sample. The April 2020 groundwater sample collected from off -site monitoring well W-9, located to the southeast and side gradient of the landfill, contained a sulfate concentration (12,000 pg/L) which is well below the NC 2L standard (250,000 pg/L) and is consistent with background levels observed in the upgradient monitoring well W-6 (10,000 pg/L). ■ Concentrations of sulfates, total dissolved solids, manganese and selenium in all 11 surface water samples did not exceed the applicable NC 2B standards. Iron was detected in the four upgradient, background surface water samples above the NC 2B standard. Concentrations of other detected analytes in surface water were within the normal range of historical fluctuations. ■ Sulfate, manganese, and total dissolved solids concentrations in surface water samples from the Site have generally trended downward or remained stable compared to historical results. There have been no exceedances of surface water quality standards downstream of the landfill since the installation of the synthetic landfill cap in 2012. ■ Installation of the synthetic cap and construction of drainage improvements over the limits of waste were completed in September 2012. The April 2020 samples were collected approximately 7.5 years after the cap installation and indicate that groundwater quality improvements are evident in the monitoring wells located at the landfill perimeter. The April 2020 surface water quality results indicate that there are no exceedances of the NC 2B standards at any of the 11 surface water monitoring locations. The water quality improvements at the site indicate that the cap installation and the drainage improvements at the landfill are effective remedial measures. The schedule for routine monitoring activities is summarized below. www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. July 2020 Page 6 2020-04 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING SEMI-ANNUAL SUMMARY REPORT — APRIL 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina PRELIMINARY ANALYSIS Target Activity Completion Date Conduct Semi -Annual Water Quality Monitoring Event Submit Water Quality Monitoring Summary Report to NCDEQ Conduct Semi -Annual Water Quality Monitoring Event Submit Water Quality Monitoring Summary Report to NCDEQ September 2020 December 2020 March 2021 June 2021 www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. July 2020 Page 7 2020-04 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING REFERENCES SEMI-ANNUAL SUMMARY REPORT — APRIL 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina 6. REFERENCES Date Title Source 1986-05-29 Solid Waste Permit No. 34-05 issued to R.J. Reynolds Tobacco Company NCDENR 1999-10-19 R. J. Reynolds Tobacco Company Ash Landfill Transition Plan Geo-Environmental Consultants, Inc. 2000-01-25 Work Plan for Upgrading Groundwater Monitoring, Phase 11 Ash Fill Area Geo-Environmental Consultants, Inc. 2000-03-13 Upgrade of Groundwater Monitoring Program, Phase 11 Ash Fill Area Shield Environmental Associates, Inc. 2001-01-02 Modifications to Transition Plan, Permit #34-05 Shield Environmental Associates, Inc. 2003-12-23 Post Closure Cover Maintenance Plan, Permit #34-05 Shield Environmental Associates, Inc. 2009-04-17 Compliance Order with Administrative Penalty, Facility #34-05 NCDENR 2009-07-17 Preliminary Site Assessment Work Plan, Facility #34-05 ERM 2009-10-29 Summary Report — Preliminary Site Assessment, Facility #34-05 ERM 2010-11-15 Letter correspondence to NCDENR DWM regarding Off -Site Well ERM Locations, Facility #34-05 2011-03-10 Summary Report — Phase 11 Site Assessment ERM 2011-06-14 Proposed Closure Modification - Edwards Road Landfill, Permit No. 34-05 ERM 2011-08-12 Regulatory approval Letter Of Closure Modification, Permit No. 34-05 NCDENR 2012-04-30 Summary Report — Groundwater Modelling for Site Assessment ERM 2012-09-21 Construction Quality Assurance for Closure Modification, Permit No. 34- ERM 05 2012-10-09 Letter correspondence to NCDENR regarding Groundwater Modelling & ERM Water Quality Monitoring, Facility #34-05 2012-11-07 Groundwater Corrective Action Permit Modification Application ERM 2013-10-01 Groundwater Corrective Action Application and Revised Groundwater ERM Modelling Scenarios 2013-10-10 Regulatory approval of Groundwater Corrective Action Application NCDENR 2013-10-11 Regulatory approval of Construction Quality Assurance for Closure NCDENR Modification, Permit No. 34-05 2014-02-04 Corrective Action Plan, Permit No. 34-05 ERM 2014-02-19 Regulatory approval of Corrective Action Plan NCDENR Various Groundwater and Surface Water Monitoring Summary Reports — 2010- ERM present www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. July 2020 Page 8 2020-04 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING SEMI-ANNUAL SUMMARY REPORT — APRIL 2020 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina Figures Figure 1 Site Location Plan Figure 2 Site Plan Figure 3 Groundwater Flow Directions Figure 4 Groundwater Sampling Results — September 2019 Figure 5 Surface Water Sampling Results — September 2019 Figure 6 Sulfate Isocontour Map - Groundwater Figure 7 Hydrogeologic Conceptual Model Figure 8 Sulfate Trends - Groundwater Figure 9 Sulfate Trends — Surface Water Tables Table 1 Monitor Well Construction Details Table 2 Groundwater Elevations Table 3 Groundwater and Surface Water Sampling Event Summary Data Table 4 Groundwater Field Parameters REFERENCES www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. July 2020 Page 9 2020-04 Edwards Rd LF Rural Hall GW Report.docx 918 BrowderCe SJU = ; ass - % _ �_ •� ��� ��, TO F.S�CO IF T 977 Li e , ���``�,€�;�,''���. `=�-�;�ii.��..���1;� �>�'� � /fit': ����zd���`=--�, ; •-�. h0 mill U-7z' IN 2,000 000011—�� Feet Legend Figure 1 r PCompliance Boundary ±_ � Limits of Permit Site Location Map Edwards Road Landfill Permit #34-05 n R.J. Reynolds Tobacco Co. $ ERM NC, Inc. L ERM www.erm.com 1:24,000 1 inch = 2,000 feet Rural Hall, North Carolina L Rnur— Cnnvrinht (c)9n93 NatlnnAI rannranhir Rnriaty --h-1 16) r,$ -7 '7 Tz� Johnston � Legend Saprolite/PWR Monitor Well ,s Bedrock Monitor Well Beck ' h f l B°O Ss -so O Abandoned Monitor Well SS-90 k Piezometer VV_8 0 Soil Boring/Piezometer �yio Pz-a p Pz of Boring �t _ Soil B ng n _ SS 40 oo� w 7 Pz-5 Surface Water Sample Location r p SS-60 As -Built Landfill Contours (20') ��� ; , y Compliance Boundary r JI ' ' Pa ne ., ., �,`. Limits of Permit r �. 100 =:�t�'"" �� � °°s Streams 4.• N - E G R. J. PW 1 7 / W 1 SS 01+850 ;, 0 Parcels m �: Reynolds „ J 1 I,,.Guthne w� Erosion�0�1 Eros ion-02 D G 'CIA S 01 B� DO Notes u W \ Q' W-6 0 1. Contour Interval Is 20 ft. B-5 Pa ne Sprinkle �,`� 2. Limps of landfill are approximate based on Sediment Boil-01 Q W-3 Freeman G available historic data. ME,! PZ-06 ^ 3. Streams estimated based on NC Floodplain B 9 �= ' B 8 PZ 07 SS-95 Mapping Program, 2008 B-10 ` W-3B w �, . ` ' . B 7 SS-01+150 f Frierson R }olds 113-12 o SS-01 Phipps � t 2 -4 , _1SS-25�r�� yy_g Wagner s' W B-11 SS-20 . _ � INS i AS/-' 1000 Boyd =y'-: O Phipps Kleitchens W-5 SS-30 y �0- Ken Stewart B14 °t y Ken Stewart 10°° -,00 o SS-10 Don Stewart S o g Hawks Dave O 1:7,200 1 inch = 600 feet o Stewart �p00 _ SS-15'� FM Don Stewa Freedom rt P�CZ` Baptist Mozelle < Figure 2 cnuron Stewart Site Area Map - Freedom z ? Baptist 900 Edwards Road Landfill Chin r Permit #34-05 R.J. Reynolds Tobacco Co. O RJR Rural Hall, North Carolina Sao A� NA��; W 0 300 600 900 r GMANTpN Rp V ERM NC, Inc. J Feet A _ g°° 9�0 WWW.erm.COm 900 ERM 1Source: NCOneMap Data Services (Imagery, parcels), Forsyth County GIs Data Download (Streets, buildings) 00 0 1000 L-1j,Mir OG U) 0 3 0 W 0 300 600 900 Feet ,�. 900 10 p0dl1, �''Air. T N tr ,,IIII yg �r+� �O,(,�� lip, I , IIyQ 900 600 oo SS-80 a Beck PZ 3 SS-90 SS.70 O PZ-2 a W 7 i4SS 7 (839.77) SS 65 ��S-4� ` ► Ss ode •a �� SS-50 (881.71) � S=.O B-9 ------ B-10 101 IN] R. J. Reynolds W-4 B-11 J0000 Boyd O Z�' PZ-5 1 +SS60 �wolf -, , ; PZ 1 �SS-35 i �) .` ., /' � (814.07)xd^aSr�So-0�2 y� PW-1 / /rW-1 .O �I/ 0 R. J. (854.28)1 1 1 9 4) `SS-01+850 e U Guthne Reynolds O` Erosion-010 (RETENTION.. �B-4 P POND MW-001, 1 B_� \ Spry Sediment 1Boil-01 PZ-10 ' B-8 �\ PZ-0 W 3 BI 07'> SS-95\550 I 7 �" �k . (801) B-12 SS 01+1150 \ Phipps, SS-20 SS-25Wrirk W-9 O Phipps W-5 SS-30 B-14 Ken Stewart SS-10 Payne �o Freeman. G� is Frierson o�s Payne • Legend O Saprolite/PWR Monitor Well O Bedrock Monitor Well O Abandoned Monitor Well Piezometer 0 Soil Boring/Piezometer 1�1 Soil Boring Surface Water Sample Location Streams — As -Built Landfill Contours (20') Compliance Boundary _ Limits of Permit 0 Parcels Regional groundwater flow Local shallow groundwater flow __�j ' 6 Notes + 1. Contour interval is 20-ft. 2. Limits of landfill are approximate based on available historic data. 3. Streams estimated based on NC Floodplain Mapping Program, 2008 4. Regional and Local Shallow Groundwater Flow based on groundwater modeling \ (ERM, 2012) Don Stewart Hawks Dave Stewart SS-15 Don Stewart Freedom �P Mozelle Baptist �. Church Stewart Freedom Baptist 900 Church 0 RtJ�E NA<<`GE w o Lu RMANTON Rp C) t g00 9�0 900 1:7,200 1 inch = 600 feet Figure 3 Groundwater Flow Direction Edwards Road Landfill Permit #34-05 R.J. Reynolds Tobacco Co. Rural Hall, North Carolina ERM NC, Inc. �b www.erm.com ERM 900 t ! Y -' Hluminum Barium Cadmium Chromium Iron Lead Manganese Selenium Sulfate cl I Compound 040212020 Aluminum 250 3 Barium 36 u Cadmium < 0.50 Chromium <5.0 i Iron 3,300 Lead < 1.0 Manganese 2,700 Selenium 21 Sulfate 830,000 u Dissolved Solids, Total 1,700,000 W-06 r Compound 04/03/2020 n Aluminum 180 N Barium 43 Cadmium < 0.50 rChromium 7.2 Iron 190 Lead < 1.0 1' Manganese 5.6 Selenium < 5.0 Sulfate 10,000 Dissolved Solids, Total 250,000 nd W-07 F - Compound 0410212020 130 75 < 0.50 6.1 1,200 PZ-05 04/01/202 Aluminum 11000 Barium 180 Cadmium 8.1 < 1.0 72'* < 5.0 5,400 190,000 \ I Chromium 17 Iron 51000 Lead 4.7 Manganese 770 s, Total Selenium < 5.0 Sulfate 35,000 Dissolved Solids, Total 150,000 60,9 Beck PZ-3 W r SS 70-\-PZ-4. 0 �� W PZ�III` /Y SS-40 o� O SS-60 PZ-1 SS-02 W-2 ;+ R. J. 1 PW;17 j �i ,SS-01+850 Guthrie \VVVI W-0 Jonnston Reynolds O:` Erosion-01 F 00 4 rosion-02 SS-50 W"6 0 Sprinkle u��: Sediment Boii-01 R. J. Reynolds W-4 1 2 �{ 000 U N • �Ofl NC 2L Ground Water Standard m Aluminum NE Barium 700 o Cadmium 2 0 Chromium (Total) 10 Iron 300 Lead 15 0 Manganese 50 T Selenium 20 2Sulfate 50 0,000 \ ' Dissolved Solids 500,000 rNE = Not Evaluated o A i 0 300 600 900 i Feet 7NJ - v W-3 Freem /fit\ �i PZ-06 -95\ CB-9 ------ B-10?► ,y B-8 1bC4 PZ 07 SS-01+150 B-12A* r ,r SS-01. Phipps 0 ` B-11 SS-20 e�SS-25�rW-9 IN Boyd O Phipps Kle 0 Wes, �/ 0 �� I B-14 Ken SS-10 Hawks I SS-15 Ru�E\NA <<'GER II l TO At � RD Don Stewart Compound W-09 041021202O Aluminum 42 Barium 170 Cadmium < 0.50 Chromium < 5.0 Iron < 50 Lead < 1.0 Manganese < 5.0 Selenium Sulfate 12,000 Dissolved Solids, Total 230,000 U 's1 020 i 1 $ Compound PZ-02 0410112020 Aluminum 69000 Barium 710 Cadmium 20 Chromium 80 1 ron 130000 Lead 38 Manganese 7200 Selenium 7.4 Sulfate 33,000 Dissolved Solids, Total 1 160,000 N M Compound W-02 W-02 (FD) 03/31/2020 03/31/2020 Aluminum 1,300 990 Barium 140 150 Cadmium < 0.50 < 0.50 Chromium 49 < 5.0 Iron 1,900 1,300 Lead < 1.0 < 1.0 Manganese 22 20 Selenium < 5.0 < 5.0 Sulfate 22,000 22,000 Dissolved Solids, Total 82,000 76,000 Paj Compound W-01 0313112020 Aluminum 180 Barium 29 Cadmium < 0.50 Chromium <5.0 Iron 450 Lead < 1.0 Manganese 4,000 Selenium 18 Sulfate 970,000 Dissolved Solids, Total 2,200,000 4, / Compound W-03 03131120201 Aluminum < 40 Barium 26 Cadmium < 0.50 Chromium < 5.0 Iron <50 Lead < 1.0 Manganese 170 Selenium 9.8 Sulfate 190,000 Dissolved Solids, Total 1 510.000 D Ste zelle art b, Compound W-03B ;. 03/31/2020 Aluminum < 40 Barium 59 Cadmium < 0.50 Chromium <5.0 Iron <50 Lead < 1.0 Manganese 87 Selenium < 5.0 Sulfate 23,000 Dissolved Solids, Total 240,000 y 9Q0 _7� w 10 Legend O Saprolite/PWR Monitor Well O Bedrock Monitor Well O Abandoned Monitor Well Piezometer 0 Soil Boring/Piezometer � Soil Boring Surface Water Sample Location Streams µ - As -Built Landfill Contours (20') triCompliance Boundary _J Limits of Permit 0 Parcels Notes 1. Contour interval is 20-ft. 2. Limits of landfill are approximate based on available historic data. 3. Streams estimated based on NC Floodplain Mapping Program, 2008 4. All concentrations in micrograms per liter (ug/L) 1:7,200 1 inch = 600 feet Figure 4 Groundwater Sampling Results - April 2020 Edwards Road Landfill Permit #34-05 R.J. Reynolds Tobacco Co. Rural Hall, North Carolina ERM NC, Inc. 90 www.erm.com ERM O source: NUUneMap Uata Services (Imagery, parcels), Forsyth County GIS Uata Download (Streets, buildings) 900 �14 Compound SS-60 04/01/2020 Aluminum 650 Barium 54 Cadmium < 0.50 Chromium < 5.0 Iron 690 Lead < 1.0 Manganese 7.3 Selenium Sulfate < 5.0 62,000 Dissolved Solids, Total 160,000 SS-50 Compound 04/01/2020 660 Aluminum Barium 47 Cadmium < 0.50 Chromium < 5.0 Iron 2,300 Lead < 1.0 Selenium < 5.0 Sulfate 2,800 Dissolved Solids, Total 1 74,000 o; ayj•`• l:' Q Compound SS-20 04/01/2020 Aluminum 1,800 Barium 47 Cadmium < 0.50 Chromium < 5.0 C�N! Lead !Ctp Manganese l' Selenium • Sulfate Y ",� Dissolved Solids, Total 7 f 2 �... y NC 2B Surface Water Standard < 1.0 13 < 5.0 Aluminum 8,OOC Barium 21,OOC Cadmium 0.0 Chromium (Total) 50.1 1 ron 1, OOC Lead 1.4`: Manganese 10C Selenium Sulfate 250, OOC u R. J.-'% Reynolds W-4 10O 6 Compound SS-70 04/01/2020 Aluminum 630 Barium 43 Cadmium < 0.50 Chromium < 5.0 Iron 840 Lead < 1.0 Manganese 14 Selenium < 5.0 Sulfate 12,000 Dissolved Solids, Total 77,000 Compound SS-80 04/01/2020 Aluminum 510 Barium 50 Cadmium < 0.50 Chromium < 5.0 Iron 680 Lead < 1.0 Manganese 5.8 Selenium < 5.0 Sulfate 10,000 Di Compound SS-90 04/01/2020 Aluminum 200 Barium 47 Cadmium < 0.50 Chromium < 5.0 Iron 300 Lead < 1.0 Manganese 8.3 Selenium < 5.0 Sulfate 22,000 Dissolved Solids, Total 110,000 ssolved Solids, Total 76,000 1'a s, K,,,., ,Johnston 0 BOo SS-80 PZ-3 � � -90 �0 W-8 SAS-70 PZ-4. � �PZ;-2PZ-5?w � i SS-60. ® PZ-1 v r J . Payne �SS-02 y VV_2 r��---� -//5�I R. J. PW-1 /�� SS-01+850t Reynolds A O' Erosion-01, ®�A�1ri\ S Erosion-02 B 4 O yt� Sprinkle Sediment Boil-01 W 3 <Boyd PZ-06�A,k SS-95\ B-8 ' PZ-071B_7 W-3BSS-01+150B_12,� SppsS-20 4WSS-25 N r WO' W_9 'dO Dissolved Solids 500,000 m 0 300 600 900 Feet W-5 SS-30 B-14 Ken Stewart 1.1 ��, SS-10 646116- / Hawks Compound SS-25 04/01/2020 Aluminum 1,700 Barium 48 Cadmium < 0.50 Chromium < 5.0 Iron 1,500 Lead < 1.0 Manganese 9.5 Selenium < 5.0 Sulfate 9,200 Dissolved Solids, Total 70,000 SS-15 Freedom V I Baptist Church NTpN RD Don I Guthrie Compound SS-30 04/01/2020 Aluminum 1,300 Barium 59 Cadmium < 0.50 Chromium < 5.0 Iron 1,800 Lead < 1.0 Manganese 18 Selenium < 5.0 Sulfate 31,000 Dissolved Solids, Total 160,000 Iu gp0 Freeman kv r Compound SS-40 04101/2020 Aluminum 280 Barium 48 Cadmium < 0.50 Chromium < 5.0 Iron 400 Lead < 1.0 Manganese 9.0 Selenium < 5.0 Sulfate Dissolved Solids, Total 24,000 11,000 Compound SS-02 SS-02 (FD) 04/01/2020 04/01/2020 Aluminum 450 400 Barium 47 46 Cadmium < 0.50 < 0.50 Chromium < 5.0 < 5.0 Iron 580 600 Lead < 1.0 < 1.0 Manganese 18 18 Selenium < 5.0 < 5.0 Sulfate 38,000 38,000 Dissolved Solids, Total 150,000 160,000 h Compound SS-01 04/01/2020 Aluminum 490 Barium 59 Cadmium < 0.50 Chromium < 5.0 Iron 690 Lead < 1.0 Manganese 8.6 Selenium < 5.0 Sulfate 26,000 Dissolved Solids, Total 150,000 1. W 900 d Legend O Saprolite/PWR Monitor Well O Bedrock Monitor Well O Abandoned Monitor Well Piezometer 0 Soil Boring/Piezometer f!IiiI Soil Boring Surface Water Sample Location Streams As -Built Landfill Contours (20') triCompliance Boundary _J Limits of Permit 0 Parcels Notes 1. Contour interval is 20-ft. 2. Limits of landfill are approximate based on available historic data. 3. Streams estimated based on NC Floodplain Mapping Program, 2008 4. All concentrations in micrograms per liter (ug/L) 1:7,200 1 inch = 600 feet Figure 5 Surface Water Sampling Results - April 2020 Edwards Road Landfill Permit #34-05 R.J. Reynolds Tobacco Co. Rural Hall, North Carolina ERM NC, Inc. �d www.erm.com ERM Source: NCOneMap Data Services (Imagery, parcels), Forsyth County GIs Data Download (Streets, buildings) NCDOT GIs Unit 900 I SULFATE CONCENTRATIONS - MOST RECENT (ug/L) MONITORING WELLS PIEZOMETERS SURFACE WATER W-1 W-2 W-3 W-3 B W-6 W-7 W-8 W-9 PW-1 SS-01 SS-02 SS-1 0* SS-15* SS-20 SS-25 SS-30 SS-40 SS-50 SS-60 SS-70 NC Groundwater & Surface Water Stan dard = 250,000 pg/L SS-80 Sample collected in APRIL 2020 unless otherwise noted SS-90 *Sample collected in August 2009 - No sample collected. Previ 1000 -: ' 1 d 970,000 22,000 190,000 23,000 10,000 5,400 69,000 12,000 830,000 0 300 600 900 Feet PZ-1 ** PZ-2 PZ-3** PZ-4 PZ-5 11,000 33,000 18,000 37,000 35,000 1000 Boyd 26,000 38,000 11,000 7,500 9,300 9,200 31,000 24,000 2,800 62,000 12,000 10,000 22,000 T N 0 / N, 01 I —� hnston - i SS-90 (22,000) W-08 (69,000) PZ-02 ' 000, `� SS-40 i ` (24,000) ik J r ¢ Payne 1 N-02 jj n 22,000) 0 S-02 38 000 °O6 1< I/ ( ) 70,600) Guthrie dift - O��O �O 0 Sprinkle Payne t Q��' . \ FrAK eeman I'd G I _ \hipps SS-20 `� SS-25 I ftr (9,300) (9,200)UN0�� W-09_ SS-30 � O \ (31,000) Ken Stewart Y \ Don Stewart• Frierrgoon ,ner Phipps Kleitchens Al ?t: kyy Legend O Saprolite/PWR Monitor Well 0 Bedrock Monitor Well Piezometer Surface Water Sample Location Water Supply Well Streams - As -Built Landfill Contours (20') trjCompliance Boundary _ Limits of Permit 0 Parcels Notes 1. Contour interval is 20-ft. 2. Limits of landfill are approximate based on available historic data. 3. Streams estimated based on NC Floodplain Mapping Program, 2008 1:7,200 1 inch = 600 feet \ Hawks Dave O/ Don Stewart Stewart - Figure 6 Freedom Baptist Mozelle1 �P�C�� �' Sulfate Isocontour Map Church Stewart �P Groundwater Freedom Baptist 900 Edwards Road Landfill Church Permit #34-05 R.J. Reynolds Tobacco Co. A Rural Hall, North Carolina oRljRq` m gao Hq �A <<:GF , • W �d r RMANTpN Rp - V ERM NC, Inc. v 900 900 900 www.erm.com ERM ;}rapt, h,iHdin ) A NORTHWEST LU 0 900 x N J N H W LL 700 z O Q LLI J w 600 SYNTHETIC CAP INSTALLATION COQAPLETE 3Q2012 LOCAL PERCHED WATER FLOW �j LOCAL GROUND WATER FLOW %rti�ti W-3 M M BEDROCK SULFATES LEAK 190,000 pg/L CREEK c = ARTESIAN WELL \ 000 l0 V )738 SL \ \9/ BEDROCK AQUIFEX i G T � W-3B W-7 PW-1 /A ` �s 02F `»>111 SULFATES SULFATES SULFATES ``, ° / 23,000 /L 5,400 Ng/L >17830,000 Ng/L ug UNNAMED ♦ TRIBUTARY SS-60 SULFATES 62,000 Ng/L X SOUTHEAST 238 FT� \ W-9 SULFATES 12,000 Ng/L 0 200 400 600 800 1000 1200 1400 1600 1800 2000 DISTANCE (FEET) CROSS SECTION LOCATION® A w-7 W-8 N SULFATE CONCENTRATIONS - MOST RECENT {VglQ r� )i MONITORING WELLS PIEZOMETERS SURFACE WATER i SCALE IN FEET 0 150 300 600 moo`` 14, s w-I N30E 33SE �N_3 - B N20E15SE (ARTESIAN) W-9 A' 1 I W-1 970,ON PZ-1** 110000 SS-01 215000 W-2 W-3 W-3 B War W-7 W-8 W-9 PW-1 22,000 190,000 23,000 10,000 5,400 69,000 12,000 830,000 PZ-2 33,000 PZ-3- 18,000 PZ-4 37,000 PZ-5 35,000 NC Groundwater & Surface Water Standard = 250,000 µgfL Sample collected in March and April 2020 unless otherwise noted Sample collected in August 2009 No sample collected. Previous sample results presented. See tables and appendices. SS-02 38,000 SS-1 0* 11,000 SS-15' 7,500 SS-20 9,300 SS-25 9,200 Figure 7 SS-30 31,000 SS-40 24,000 Hydrogeologic SS-50 2,800 Conceptual Model SS-60 62,000 Edwards Road Landfill SS-70 12,000 Permit #34-05 SS-80 10,000 SS-90 22,000 R.J. Reynolds Tobacco Co. Rural Hall, North Carolina ERM NC, Inc. www.erm.com ERM ft ug/L MONITORING WELL W-1 ^AMSL ug/L MONITORING WELL W-2 AMSL ug/L MONITORING WELL W-3 AMSL 41000,000 3,500,000 3,000,000 2,500,000 2,000,000 1,500,000 1,000,000 500'000 n OMAN - s I I SAPROLITE / PWR AQUIFER Synthetic cap SAPROLITE / PWR AQUIFER Synthetic cap VV r SAPROLITE / PWR AQUIFER Synthetic cap 814 s,soo,000 installed 3Q2012 816 1,aoo,000 installed 3Q2012 804 813 814 803 3,000,000 � 1,200,000 812 $12 $02 - 811 2,500,000 1,000,000 - $10 $01 810 2,000,000 - 800,000 so$ soo 809 1,500,000 - - 600,000 806 799 808 1,000,000 804 400,000 798 - 807 806 soo,000 Qnc n J - I 802 zoo,000 unn - - 797 roc 00 00 O`1 Ob 0r° 00 ,111 n6 ,.0 �O 00 O`1. 9b 06 00 00 O`l' OP 00 00 11, �0 ^0 r10 90 0`L OP OHO 00 00 0`l. OC` 06 00 �p - - - ,�0 �O �O �O ^9 ^9 �O �O �O ry0 �O �O �O ry0 �O ry0 ry0 �O ^9 �O �O ^O �O ry0 ,y0 �O �O ry0 �O �O �O �O �O �O �O ^0 ,�O ,�9 �O �O �O �O ry0 �O �O �O �O �O ry0 ft UWL MONITORING WELL W-3B AMSL Ug/L BACKGROUND MONITORING WELL W-4 & W-6 AMSL �L MONITORING WELL W-7 AMSL 1,200,000 BEDROCK AQUIFER Synthetic cap 810 800,000 BEDROCK AQUIFER Synthetic cap 000 250,000 BEDROCK AQUIFER, Installed 4Q2010 Synthetic cap 841 nstalled 3Q2012 809 installed 3Q2012 installed 3Q2012 840 700,000 886 1,000,000 808 W-4: 1995-2003 W-6 2003-Present 200,000 - 839 soo,000 884 800,000 - 807 838 GW Elevation 500,000 >804.53 (artesian) 806 882 150,000 837 500,000 r 400,000 � 805 880 836 300,000 100,000 400,000 - s 804 • 835 878 803 200,000 -� - - 834 • 50,000 200,000 802 100,000 876 K 833 0 801 0 874 0 - 832 l OOb ti 006 000 0,�0 O^�L ti ti ti ti Or�DO^�o O^0 OHO ti ti ti ti pi°j6 oi0'1 ^ ^ 1@ 00'� 00`h 0ll 0 ^ ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti 'WL MONITORING WELL W-8 AMSL ug/L MONITORING WELL W-9 AMSLL MONITORING WELL PW-1 ft AMSL 350,000 812 350,000 810 3,500,000 866 PWR AQUIFER, SAPROLITF AOLJIFFR BEDROCK AQUIFER 300,000 Installed 4Q2010 810 300,000 Synthetic cap 808 3,000,000 Synthetic cap 864 Synthetic cap installed 3Q2012 installed 3Q2012 installed 3Q2012 862 250,000 - 808 250,000 806 2,500,000 860 200,000 AL 806 200,000 804 2,000,000 / 858 150,000 - - 804 150,000 802 1,500,000 • / 856 100,000 802 100,000 800 1,000,000 854 50,000 � 800 50,000 798 852 500,000 0000p-850 0 798 0 796 0 900 910 41 16^^ ry0,�'3 �O^0 �0,�'1 �O,�O �0,��. �0,�'h �O^0 �0,�'� �0,�9 "R, 1^Og0 1000 le", I0N`L le'o I000 I'll,I'll, 1 sell lel:' IpNb lf§P LEGEND NC2L GW STD NC213 SW STD FIGURE Sulfates 250,000 ug/L 250,000 ug/L SULFATE TRENDS - GROUNDWATER ❑ Total Dissolved Solids 500,000 ug/L 500,000 ug/L ERM NC, Inc. EDWARDS ROAD LANDFILL - PERMIT # 34-05 8 Groundwater Table Elevation (above Mean Sea Level) ERM RURAL HALL, NORTH CAROLINA ug/L SURFACE WATER SS-01 1,400,000 1,200,000 Synthetic installed cap 3Q2012 1,000,000 - 800,000 600,000 400,000 200,000 0 owns A 10, 1000 14P 141 1 10 le 000 ellOOP 000 000 ti ti ti ti ti O^O O^� O ti ti ti O^O O^O OHO ti ti ti ug/L SURFACE WATER SS-30 400,000 Synthetic cap 350,000 installed 3Q2012 300,000 250,000 � 200,000 - - V 150,000 100,000 50,000 0 do do �o do ryo do ryo �o ,alb �yo ryo ,yo ryoti ug/L 250,000 200,000 150,000 100,000 50,000 SURFACE WATER SS-70 ug/L SURFACE WATER SS-02 1,000,000 Synthetic cap 900,000 installed 3Q2012 800,000 700,000 600,000 500,000 - 400,000 -- 300,000 200,000 100,000 - 0 I000 I'll, I'll,000 IOpu6 000 ", ti ti ti 11 000 000 OHO O�ti Orb 1ti ti ti ti ti O^0 O^0 IP ti ti ti ug/L SURFACE WATER SS-40 800,000 Synthetic cap 700,000 installed 3Q2012 600,000 500,000 400,000 / 1 300,000 200,000 Y 100,000 0 ,yo ,yo ,yo ,yo yo do ,yo ,yo yo ,�o ,yo ryoti ug/L 300,000 250,000 200,000 150,000 100,000 50,000 SURFACE WATER SS-80 Synthetic cap installed 3Q2012 0 1 `r 1 0 1 00 ,�O ,�� ^�L ^0 ,�P ^0 ,�O ^'1 ,�0 ,�9 ,yo 09 ,�O ,�� �o do �o yo ryo do ryo �o y ryo do �yo no �yo yo yo yo yo �o yo yo no yo tio� LEGEND NC21- GW STD NC213 SW STD Sulfates 250,000 ug/L 250,000 ug/L 0 Total Dissolved Solids 500,000 ug/L 500,000 ug/L ug/L SURFACE WATER SS-25 180,000 160,000 140,000 120,000 100,000 80,000 60,000 40,000 20,000 0 oe o ^ry �o a 0 �6 A ,LO ry0 ry0 ry0 ry0 ry0 ry0 ry0 ,P ry0 ry0 ry0�' ug/L SURFACE WATER SS-60 800,000 700,000 600,000 500,000 400,000 300,000 200,000 100,000 0 OO ^O ,�^ ,ry ^g ,�b ^h �o do yo tio` '0 yo yo yo yo yo do noti ug/L SURFACE WATER SS-90 600,000 500,000 400,000 300,000 200,000 100,000 0 TABLE 1 MONITOR WELL CONSTRUCTION DETAILS EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 1 of 1 Outer Ground TOC Boring Casing Screened Geologic Well Install Elevation Elevation Depth Depth Interval Zone ID Date Latitude Longitude (ft MSL) (ft MSL) (ft BGL) (ft BGL) (ft BGL) Screened Comments Former supply well, pump removed (8/09): 6 inch dia. gals. casing; Construction details per 405 Clayton Well Drilling log and video inspection by ERM (8/09 & 4/10); Open rock to 405 ft, Total PW-1 5/26/87 36.2499455° -80.2779362° 920.51 920.66 (soft bottom 21.5 21.5-405 Bedrock well yield 25 gpm with no other obvious water -bearing zones below 103 ft (Clayton). Silted in to 819.69 at 326) 326 ft (video). W-1 10/13/87 36.2500121° -80.2757441' 822.68 20.5 NA 10-20 Saprolite 2 inch dia. PVC, Well replaced 11/93, DWM permit -required sample location W-2 12/6/89 36.2504070° -80.2753700' 824.21 827.30 17 NA 7-17 Sap/PWR 2 inch dia. PVC, DWM permit -required sample location, (alternate IDs MW-1A, RH-MW-002) W-3 12/7/89 36.2486237' -80.2761346' 802.00 804.43 17 NA 7-17 Sap/PWR 2 inch dia. PVC, DWM permit -required sample location, (alternate IDs W-3A, W-2A, RH-MW-003) W-3B 5/14/04 36.2485693° -80.2761875' 801.23 804.32 210 Unknown 190-210 Bedrock 2 inch dia. PVC, DWM permit -required sample location, Artesian well W-4 6/8/93 36.24693455' -80.28491769° � NE NE 188 NA 138-188 Bedrock 2 inch dia. PVC, damaged, abandoned 8127103, former background well, replaced with W-6 in 2003. W-5 5/17/93 36.24629033° " -80.27862892° * NE NE 24 NA 13-23.5 Bedrock 2 inch dia PVC, Phase 3 permanent MW W-6 8/22/03 36.2490276' -80.2819968' 977.93 980.71 200 NA 170-200 Bedrock 2 inch dia. PVC, DWM permit -required sample location, (alternate IDs MW-6), current background well, replaced W-4 as background well in 2003 W-7 12/15/10 36.2517944° -80.2798058' 929.51 931.58 341 NA 42-341 Bedrock 6 inch dia. open -rock hole, 6" galavanized casing to 42 ft bgs, TOC value for 6" casing W-8 12/14/10 36.2524760° -80.2744895' 859.39 861.67 129 NA 45-65 PWR 2 inch dia. PVC W-9 12/13/10 36.2469581° -80.2750675' 909.35 911.38 259 NA 229-259 Bedrock 2 inch dia. PVC, Ken Stewart's pasture, B-9 5/20/93 36.24819778' " -80.28420462° " NE NE 23 NA 18-22.5 Saprolite 2 inch dia PVC, Phase 3 temporary piezometer, abandoned Dec. 2019 B-10 5/19/93 36.24815194' ` -80.28243419' * NE NE 14 NA 9-13.5 Saprolite 2 inch dia PVC, Phase 3 temporary piezometer, not located Oct. 2009 or Dec. 2019 B-11 5/20/93 36.24695712' " -80.28385595° ' NE NE 54 NA 48-53 Saprolite 2 inch dia PVC, Phase 3 temporary piezometer, not located Dec. 2019 B-12 5/19/93 36.24765518° -80.28079913° * NE NE 8.5 NA 3.5-8 Saprolite 2 inch dia PVC, Phase 3 temporary piezometer, no protective well box around well B-14 5/20/93 36.2461299° * -80.28188639° " NE I NE 54 NA 48-53 Saprolite 2 inch dia PVC, Phase 3 temporary piezometer, abandoned Dec. 2019 PZ-1 3/15/16 36.25134616' -80.2740505' ' NE NE 1.5 NA 1.0 - 1.5 Alluvium 1 inch dia PVC temporary piezometer. Originally installed 12/2010. Replaced 3/2016 PZ-2 12/15/10 36.25229952' ' -80.27330537' ' NE NE 4.0 NA 3.0 - 4.0 Alluvium 1 inch dia PVC temporary piezometer PZ-3 12/15/10 36.25292715' -80.27477259' ' NE NE 1.5 NA 0.5 - 1.5 Alluvium 1 inch dia PVC temporary piezometer PZ-4 12/16/10 36.25225065' ' -80.27644449' ' NE NE 5.0 NA 4.2 - 5.0 Alluvium 1 inch dia PVC temporary piezometer PZ-5 12/16/10 36.25178958' -80.27767072' ' NE NE 5.0 NA 3.0 - 5.0 Alluvium 1 inch dia PVC temporary piezometer PZ-6 2/18/20 NE NE NE 834.3' 3.5 NA 1.5 - 3.5 Fill/Saprolit 1 inch dia PVC temporary piezometer installed for boil evaluation at ST-1 PZ-7 2/18/20 NE NE NE 833.7 * 4.5 NA 1.5-4.5 Fill/Saprolit 1 inch dia PVC temporary piezometer installed for boil evaluation at ST-1 PZ-8 2/18/20 NE NE NE 830.7' 5.0 NA 2.0 - 5.0 Fill/Saprolit 1 inch dia PVC temporary piezometer installed for boil evaluation at ST-1 PZ-9 2/18/20 NE NE NE 834.6 * 4.5 NA 1.5-4.5 Fill/Saprolit 1 inch dia PVC temporary piezometer installed for boil evaluation at ST-1 PZ-10 2/24/20 NE NE NE 839.9' 4.0 NA 1.0 - 4.0 Fill/Saprolit 1 inch dia PVC temporary piezometer installed for boil evaluation at ST-1 NE - Not Established BGL - Below ground level NM - Not Measured MSL - above mean sea level BTOC - Below top of casing " - Estimated value RJRTI Tables RJRT Ash LF.xlsAl. Well Construction PWR = Partially Weathered Rock Survey data by Lawrence Associates, P.A., January 4, 2010, January 4, 2011 & February 28, 2011 TABLE 2 GROUNDWATER ELEVATIONS EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Monitor Well ID TOC Elevation Start Screen Depth End Screen Depth Geologic Unit PW-01 W-01 W-02 W-03 W-03B W-05 920.66 822.68 827.30 804.43 804.32 21.5 10 7 7 190 13 405 20 17 17 210 23.5 Bedrock Saprolite Saprolite/PWR Saprolite/PWR Bedrock - Artesian Bedrock Date Depth to Water ft BTOC Groundwater Elev ft MSL Depth to Water ft BTOC Groundwater Elev ft MSL Depth to Water ft BTOC Groundwater Elev ft MSL Depth to Water ft BTOC Groundwater Elev ft MSL Depth to Water ft BTOC Groundwater Elev ft MSL Depth to Water ft BTOC Groundwater Elev ft MSL 2006-10-19 11.59 811.09 13.32 813.98 7.54 796.89 Artesian 2007-04-27 10.88 811.80 13.96 813.34 6.98 797.45 Artesian 2007-11-19 13.29 809.39 16.08 811.22 7.78 796.65 Artesian 2008-04-30 12.84 809.84 14.68 812.62 7.04 797.39 Artesian 2009-04-30 -- -- 13.23 809.45 15.18 812.12 7.12 797.31 Artesian -- -- 2009-10-12 72.00 848.66 14.53 808.15 17.50 809.80 7.63 796.80 -1.22 805.54 10.08 2010-04-19 67.00 853.66 10.75 811.93 14.16 813.14 6.37 798.06 -1.05 805.37 8.38 2010-10-11 -- -- 12.04 810.64 15.85 811.45 6.99 797.44 -0.89 805.21 9.73 2011-01-05 -- -- 11.97 810.71 13.53 813.77 6.88 797.55 -0.98 805.30 9.67 2011-02-28 65.30 855.36 11.66 811.02 14.57 812.73 6.65 797.78 -1.37 805.69 9.50 2011-04-20 64.75 855.91 10.92 811.76 14.05 813.25 6.25 798.18 -1.63 805.95 7.85 2011-10-17 -- -- 12.55 810.13 15.18 812.12 7.24 797.19 -1.36 805.68 -- 2012-02-06 64.96 855.70 11.97 810.71 13.52 813.78 6.52 797.91 Artesian -- 2012-03-16 -- -- 11.95 810.73 15.45 811.85 6.64 797.79 Artesian 2012-09-24 66.03 854.63 11.93 810.75 15.36 811.94 4.87 799.56 Artesian 2013-04-17 65.80 854.86 11.98 810.70 14.03 813.27 4.51 799.92 Artesian 2013-09-10 66.75 853.91 13.01 809.67 15.75 811.55 3.45 800.98 Artesian 2014-04-07 56.15 864.51 11.74 810.94 16.76 810.54 3.29 801.14 Artesian 2014-09-03 67.28 853.38 14.37 808.31 16.65 810.65 3.29 801.14 Artesian 2015-04-02 64.75 855.91 13.29 809.39 13.93 813.37 3.78 800.65 Artesian 2015-09-08 -- -- -- -- - -- -- -- -- -- -- -- 2015-09-10 65.49 855.17 15.18 807.50 17.01 810.29 4.20 800.23 Artesian 2016-03-08 62.75 857.91 12.42 810.26 13.32 813.98 2.80 801.63 Artesian 2016-09-06 67.21 853.45 14.92 807.76 16.68 810.62 3.31 801.12 Artesian 2017-03-27 65.34 855.32 15.50 807.18 15.33 811.97 3.89 800.54 Artesian 2017-09-25 65.50 855.16 16.02 806.66 16.89 810.41 3.32 801.11 Artesian 2018-03-05 66.00 854.66 16.10 806.58 11.90 815.40 4.45 799.98 Artesian 2018-09-12 65.44 855.22 15.88 806.80 16.95 810.35 4.24 800.19 Artesian 2019-03-19 61.00 859.66 11.20 811.48 6.23 821.07 1.88 802.55 0.00 804.32 2019-03-20 -- -- -- -- -- -- -- -- -- -- -- -- 2019-09-03 65.50 855.16 15.05 807.63 16.23 811.07 3.19 801.24 0.00 804.32 2020-02-13 67.61 853.05 10.31 812.37 5.03 822.27 2.98 801.45 0.21 804.11 2020-02-18 (gauged twice this date 67.00 67.02 853.66 853.64 11.76 11.8 810.92 810.88 6.11 6.12 821.19 821.18 3.24 3.24 801.19 801.19 0.07 0.08 804.25 804.24 2020-02-24 66.70 853.96 12.81 809.87 6.13 821.17 3.38 801.05 0.20 804.12 2020-03-04 66.82 853.84 12.29 810.39 6.29 821.01 3.43 801.00 0.21 804.11 2020-03-31 66.38 854.28 13.28 809.40 13.23 814.07 3.43 801.00 1.05 803.27 Page 1 of 3 TABLE 2 GROUNDWATER ELEVATIONS EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Monitor Well ID TOC Elevation Start Screen Depth End Screen Depth Geologic Unit W-06 W-07 W-08 W-09 B-09 B-12 980.71 931.58 861.67 911.38 170 42 45 229 18 3.5 200 341 65 259 22.5 8 Bedrock Bedrock PWR Bedrock Saprolite Saprolite Date Depth to Water ft BTOC Groundwater Elev ft MSL Depth to Water ft BTOC Groundwater Elev ft MSL Depth to Water ft BTOC Groundwater Elev ft MSL Depth to Water ft BTOC Groundwater Elev ft MSL Depth to Water ft BTOC Groundwater Elev ft MSL Depth to Water ft BTOC Groundwater Elev ft MSL 2006-10-19 99.00 881.71 2007-04-27 94.48 886.23 2007-11-19 105.00 875.71 2008-04-30 99.29 881.42 2009-04-30 98.28 882.43 2009-10-12 99.64 881.07 20.40 10.26 2010-04-19 98.29 882.42 18.78 6.18 2010-10-11 98.93 881.78 -- -- -- -- -- -- 21.63 9.40 2011-01-05 98.92 881.79 94.73 836.85 52.67 809.00 110.47 800.91 22.05 9.05 2011-02-28 99.01 881.70 94.59 836.99 53.45 808.22 112.03 799.35 22.63 -- 2011-04-20 98.42 882.29 94.20 837.38 53.54 808.13 110.03 801.35 21.45 5.46 2011-10-17 99.41 881.30 -- -- -- -- -- -- -- -- 2012-02-06 99.22 881.49 94.71 836.87 54.74 806.93 109.84 801.54 2012-03-16 99.05 881.66 -- -- -- -- -- -- 2012-09-24 99.63 881.08 96.05 835.53 55.47 806.20 110.26 801.12 2013-04-17 99.04 881.67 95.80 835.78 57.40 804.27 108.62 802.76 2013-09-10 98.86 881.85 94.71 836.87 54.20 807.47 110.23 801.15 2014-04-07 98.23 882.48 95.26 836.32 54.01 807.66 110.86 800.52 2014-09-03 98.93 881.78 94.90 836.68 52.78 808.89 110.68 800.70 2015-04-02 99.45 881.26 94.52 837.06 56.22 805.45 110.50 800.88 2015-09-08 -- -- -- -- 58.22 803.45 110.50 800.88 2015-09-10 99.51 881.20 95.23 836.35 -- -- -- -- -- 2016-03-08 98.62 882.09 93.95 837.63 59.01 802.66 110.06 801.32 -- 2016-09-06 98.90 881.81 94.05 837.53 53.19 808.48 110.11 801.27 2017-03-27 99.10 881.61 94.41 837.17 56.00 805.67 109.90 801.48 -- 2017-09-25 99.68 881.03 95.01 836.57 56.96 804.71 109.30 802.08 -- 2018-03-05 99.94 880.77 94.60 836.98 60.60 801.07 110.30 801.08 2018-09-12 100.05 880.66 94.83 836.75 61.60 800.07 110.33 801.05 2019-03-19 -- -- -- -- -- -- -- -- -- -- -- -- 2019-03-20 98.59 882.12 92.07 839.51 58.35 803.32 110.06 801.32 2019-09-03 99.46 881.25 92.98 838.60 52.28 809.39 109.54 801.84 2020-02-13 93.41 887.30 91.72 839.86 53.37 808.30 -- -- 2020-02-18 (gauged twice this date 99.14 99.12 881.57 881.59 92.08 92.09 839.5 839.49 53.34 53.33 808.33 808.34 2020-02-24 99.13 881.58 92.25 839.33 53.45 808.22 2020-03-04 99.14 881.57 92.23 839.35 53.49 808.18 - 2020-03-31 99.00 881.71 91.81 839.77 52.99 808.68 110.00 801.38 Page 2 of 3 TABLE 2 GROUNDWATER ELEVATIONS EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Monitor Well ID TOC Elevation Start Screen Depth End Screen Depth Geologic Unit PZ-06 PZ-07 PZ-08 PZ-09 PZ-10 834.3 (est.) 833.7 (est.) 830.7 (est.) 834.6 (est.) 839.9 (est.) 1.5 1.5 2.0 1.5 1.0 3.5 4.5 5.0 4.5 4.0 Fill Soil/Saprolite Fill Soil/Saprolite Fill Soil/Saprolite Fill Soil/Saprolite Fill Soil/Saprolite Date Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) 2006-10-19 2007-04-27 2007-11-19 2008-04-30 2009-04-30 2009-10-12 2010-04-19 2010-10-11 2011-01-05 2011-02-28 2011-04-20 2011-10-17 2012-02-06 2012-03-16 2012-09-24 2013-04-17 2013-09-10 2014-04-07 2014-09-03 2015-04-02 2015-09-08 2015-09-10 2016-03-08 2016-09-06 2017-03-27 2017-09-25 2018-03-05 2018-09-12 2019-03-19 2019-03-20 2019-09-03 2020-02-13 Dry Dry 2020-02-18 (gauged twice this date Dry Dry Dry Dry Dry Dry Dry Dry Dry D -- 2020-02-24 Dry -- Dry -- Dry Dry 9.25 830.6 2020-03-04 8.87 825.4 9.69 1 824.0 Dry -- Dry 8.64 831.3 2020-03-31 8.84 825.4 9.39 1 824.3 Dry -- Dry 8.70 831.2 Notes: NE = Not Established PWR = Partially Weathered Rock Artesian condition - Value represents water level above permanent TOC. MSL = above mean sea level BGL - Below ground level Measured via temporary standpipe installed on permanent casing. BTOC = Below Top of Casing Page 3 of 3 TABLE 3 GROUNDWATER AND SURFACE WATER ANALYTICAL RESULTS EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA 1 of 1 N N O Cn 3 CE 3 R E d £ 7 E -a p L O -a C _ C N w O (n ru Anal Y to Q m U U � _ J � N N Ln O F NC 2L Groundwater Standard 3,500 700 2 10 300 15 50 20 250,000 500,000 NC 26 Surface Water Standard 8,000 21,000 0.3 50.1 1,000 1.49 100 5 250,000 500,000 Sample I Location/ID Sample Date Groundwater Monitoring Wells PW-01 4/2/2020 250 36 < 0.5 < 5 3,300 < 1 2,700 21 830,000 1,700,000 W-01 3/31/2020 180 29 < 0.5 < 5 450 < 1 4,000 18 970,000 2,200,000 W-02 3/31/2020 970 150 < 0.5 < 5 1,100 < 1 20 < 5 22,000 82,000 W-02 (FD) 3/31/2020 990 150 < 0.5 < 5 1,300 < 1 20 < 5 22,000 76,000 W-03 3/31/2020 < 40 26 < 0.5 < 5 < 50 < 1 170 9.8 190,000 510,000 W-03B 3/31/2020 < 40 59 < 0.5 < 5 < 50 < 1 87 < 5 23,000 240,000 W-06 4/3/2020 180 43 < 0.5 7.2 190 < 1 5.6 < 5 10,000 250,000 W-07 4/2/2020 130 75 < 0.5 6.1 1,200 < 1 72 < 5 5,400 190,000 W-08 4/2/2020 64 150 < 0.5 5.1 97 < 1 < 5 < 5 69,000 170,000 W-09 4/2/2020 42 170 < 0.5 < 5 < 50 < 1 < 5 < 5 12,000 230,000 PZ-02 4/1/2020 69,000 710 20 80 130,000 38 7,200 7.4 33,000 160,000 PZ-04 4/1/2020 95,000 1,600 4.8 130 160,000 34 3,400 <5 37,000 130,000 PZ-05 4/1/2020 11,000 180 8.1 17 51,000 4.7 770 <5 35,000 150,000 Surface Water SS-01 4/1/2020 490 59 < 0.5 < 5 690 < 1 8.6 < 5 26,000 150,000 SS-02 4/1/2020 450 47 < 0.5 < 5 580 < 1 18 < 5 38,000 150,000 SS-02 (FD) 4/1/2020 400 46 < 0.5 < 5 600 < 1 18 < 5 38,000 160,000 SS-20 4/1/2020 1,800 47 < 0.5 < 5 1,600 < 1 13 < 5 9,300 76,000 SS-25 4/1/2020 1,700 48 < 0.5 < 5 1,500 < 1 9.5 < 5 9,200 70,000 SS-30 4/1/2020 1,300 59 <0.5 <5 1,800 <1 18 <5 31,000 160,000 SS-40 4/1/2020 280 48 < 0.5 < 5 400 < 1 9 < 5 24,000 110,000 SS-50 4/1/2020 660 47 < 0.5 < 5 2,300 < 1 96 < 5 2,800 74,000 SS-60 4/1/2020 650 54 < 0.5 < 5 690 < 1 7.3 < 5 62,000 160,000 SS-70 4/1/2020 630 43 < 0.5 < 5 840 < 1 14 < 5 12,000 77,000 SS-80 4/1/2020 510 50 < 0.5 < 5 680 < 1 5.8 < 5 10,000 76,000 SS-90 4/1/2020 200 47 < 0.5 < 5 300 < 1 8.3 < 5 22,000 110,000 Notes: All concentrations in micrograms per liter (pg/L) unless otherwise noted. NE - Not established No freshwater aquatic life standard established for barium, manganese, sulfate, and dissolved solids. Water Supply criteria presented. Bold with gray background indicates exceedance of applicable NC Groundwater or Surface Water Standard TABLE 4 GROUNDWATER AND SURFACE WATER FIELD PARAMETER RESULTS EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Temperature Oxidation - (degrees Conductivity Reduction Dissolved Analyte pH (SU) Celsius) (US/CM) Turbidity (NTUs) Potential (mV) Oxygen (mg/L) NC 2L Groundwater Standard 6.5-8.5 NE NE NE NE NE NC 213 Surface Water Standard 6.0-9.0 NE NE NE NE NE Sample I Location/ID Sample Date Groundwater Monitoring Wells PW-01 4/2/2020 6.4 15.2 2088 4.1 -1.6 0.3 W-01 3/31 /2020 6.4 14.4 2635 6.0 45 0.3 W-02 3/31 /2020 5.5 13.1 101 19.4 84 2.6 W-03 3/31 /2020 6.2 12.8 712 0.4 3819 0.9 W-03B 3/31/2020 7.5 12.8 400 0.2 25 0.4 W-06 4/3/2020 9.4 15.6 397 7.4 -57 0.4 W-07 4/2/2020 7.3 13.8 339 31.1 0.5 0.4 W-08 4/2/2020 5.6 18.3 239 4.9 118 6.8 W-09 4/2/2020 11.4 18.1 758 0.9 -400 0.2 Surface Water SS-01 4/1/2020 8.5 11.7 225 34.2 49.5 8.6 SS-02 4/1/2020 9.1 12.4 245 13.5 42.7 9.1 SS-20 4/1/2020 6.6 11.8 88 23.4 73.1 9.4 SS-25 4/1/2020 6.9 11.7 89 20.8 71.0 9.8 SS-30 4/1/2020 7.4 11.8 262 24.1 63.3 10.1 SS-40 4/1/2020 8.7 11.9 192 10.9 29.2 10.0 SS-50 4/1/2020 7.6 12.4 74 31.5 22.1 9.8 SS-60 4/1/2020 7.4 11.4 232 13.7 78.9 7.9 SS-70 4/1/2020 7.2 11.9 87 14.4 62.9 9.7 SS-80 4/1/2020 7.2 11.7 87 13.3 83.4 10.9 SS-90 4/1/2020 8.7 11.3 155 10.7 59.2 12.6 Notes: All concentrations in micrograms per liter (Ng/L) unless otherwise noted. NE - Not established No freshwater aquatic life standard established for barium, manganese, sulfate, and dissolved solids. Water Supply criteria presented. Bold with gray background indicates exceedance of applicable NC Groundwater or Surface Water Standard 1 of 1 APPENDIX A HISTORICAL GROUNDWATER AND SURFACE WATER QUALITY ANALYTICAL DATA www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. July 2020 2020-04 Edwards Rd LF Rural Hall GW Report.docx APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 1 of 10 Anal to Y 7 E Q m y Q 3 'C `0 m E E -a `6 U 3 o L U a O- O U C o L '0 m d J N a� C 0 i E c 41 m N d > in V = N Z R R i '= z ,� `� s cn rn .O N N O y .�+ o s N V i .�+ o cn x a N 7 y N U y 4) 41 y 3 u E m E 2 (n O -- ' .5 O U 5 d a cn Z Y 3 H E � C O a C O •U a O � x O J 0 E a 41 T O N o y y G NC 2L Ground Water Standard 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 109000 250,000 5009000 NE 6.5-8.5 NE NE NE NE NE Sample Location Date W-01 4/29/1988 8,030 235 8 16 17,400 1,100 31 -- 130,000 156,000 2,240 5.9 W-01 7/13/1989 -- 100 -- -- -- 5 -- -- -- -- -- -- W-01 9/24/1990 5,620 189 8,900 150 59 13,500 185,000 13,000 6.27 19.3 195 W-01 10/24/1991 161 346 150 97 23.9 126,000 303,000 12,000 6.24 20.3 425 W-01 3/26/1992 2,850 736 833 1,830 0.32 21.9 38 123,000 482,000 14,000 6.62 9.3 682 W-01 9/30/1992 -- 120 -- 310 32 292,000 798,000 5,000 5.87 17.8 1,153 W-01 3/31/1993 364 137 1,130 2,230 13.2 33 486,000 1,169,000 33,000 5.49 16.1 1,587 W-01 9/17/1993 28,600 697 3.8 44 59,700 13 3,490 5.1 195 565,000 1,643,000 6,000 5.93 18 2,310 W-01 3/30/1994 5,320 545 -2 20 18,800 8 505 6 107 633,000 1,680,000 -- 5.63 15.2 1,250 W-01 9/30/1994 1,810 <2 22 9,960 5 4,470 13 19 758,000 2,420,000 123,000 6.02 18.1 3,010 W-01 3/31/1995 24,000 1,250 <2 26 53,900 11 1,580 12 115 797,000 2,140,000 -- 5.89 15.8 2,820 W-01 9/29/1995 7,650 367 4 < <' 24 18,800 10 4,020 12 -- 464,000 2,780,000 4,040 4.49 16.2 3,720 W-01 3/20/1996 149,000 960 50 200 220 -- 63 11,400 695 2,320,000 2,670,000 8,750 1 6.48 15 3,060 W-01 9/27/1996 7,110 -- 22,600 7 2,300 51 1,320,000 2,970,000 3,810 6.09 19 3,350 W-01 3/29/1997 2,990 < -- 16 2,340 72 1,360,000 2,860,000 6,870 6.01 14 1,890 W-01 9/17/1997 2,940 3 12,900 6 3,680 33 136 1,300,000 3,110,000 5,290 6.3 17 3,540 W-01 3/27/1998 2,400 7,830 2,340 16 1,060,000 3,040,000 3,640 6.49 19.6 627 W-01 9/30/1998 2,350 2 5,180 15 2,710 21 1,030,000 3,210,000 17,500 6.2 20 1,250 6.36 20.8 W-01 9/30/1998 1,250 4,980 i 2,720 30 1,040,000 3,320,000 9,250 1 -- -- -- -- -- W-01 3/31/1999 1,820 4,690 10 2,450 15 1,830,000 3,230,000 8,820 5.6 17 1,610 W-01 (FD) 3/31/1999 1,170 D.002 4,200 ^ ^ 2,560 18 1,920,000 3,230,000 3,730 W-01 9/29/1999 1,650 <2 4,780 8 2,790 31 2,060 3,440,000 3,730 5.71 19 1,980 W-01 3/16/2000 1,820 3,360 6 2,840 31 1,390,000 3,330,000 3,930 -- -- -- W-01 9/15/2000 979 3,200 8 2,930 22 1,540,000 3,480,000 13,300 5.82 18 1,040 W-01 3/23/2001 226 2 1,860 10 3,180 1,260,000 3,320,000 6,130 6.2 17 1,090 W-01 10/4/2001 728 2 3,140 9 2,890 37 1,420,000 3,380,000 31,000 8 21 3,300 W-01 3/28/2002 1,010 20 3,600 8 3,270 48 1,220,000 3,310,000 3,430 6.04 15 1,090 W-01 (FD) 3/28/2002 002 5,450 3,580 1,050,000 2,920,000 3,430 6.04 15 1,090 W-01 10/3/2002 8,960 2 14,000 8 3,910 51 1,330,000 3,210,000 3,190 6.33 18 1,280 W-01 3/25/2003 1,420 2,770 7 3,540 25 1,130,000 3,310,000 3,210 6.43 19 910 W-01 10/2/2003 402 414 2,330 5 1 3,840 1 1,350,000 3,470,000 3,520 5.94 20 3,210 W-01 4/28/2004 1,440 - 6,890 12 3,920 1,350,000 3,580,000 5,130 -- 15.1 3,670 W-01 10/26/2004 7,450 21 20,100 10 4,800 1,310,000 3,630,000 3,100 3,510 W-01 4/27/2005 697 2 3,990 10 4,080 1,820,000 3,601,000 3,450 3,610 W-01 10/20/2005 9,030 283 18,400 15 3,920 104 790,000 3,520,000 52,000 2,370 W-01 10/19/2006 214 926 6 4,160 56 1,790,000 3,310,000 3,740 2,120 W-01 4/27/2007 787 1,250 1 3,550 1,300,000 3,390,000 6,350 4,510 W-01 11/19/2007 186 778 4,080 1,950,000 3,430,000 3,950 3,460 W-01 4/30/2008 291 536 3,870 1,920,000 3,410,000 2,990 3,590 W-01 (FD) 4/30/2008 349 698 3,910 1,860,000 3,380,000 2,850 3,600 W-01 10/29/2008 25.8 0.32 427 4.9 3,990 1,640,000 3,310,000 4,950 3,840 W-01 4/30/2009 30.5 3.44 4.9 599 13.1 1 4,560 1.44 1,890,000 3,370,000 6,060 3,860 W-01 10/12/2009 98 J 2.9 J 22 J 1 2 J 1.1 1 410 4,000 0.5 J 280 1,500,000 3,100,000 -- 6.1 14.93 4,620 14 87 3.32 W-01 4/20/2010 3,500 130 12 6,000 4,200 -- 1,500,000 3,100,000 56,500 6.1 16.5 11,800 57.9 119 <0.01 W-01 10/11/2010 63 J 1 6.7 27 1 0.9 J 300 1.3 J 5,000 33 1.3 J 12 780 1,400,000 3,100,000 -- 6.12 20.43 2,990 110 147 < 0.01 W-01 4/22/2011 470 6.8 43 15 2,900 4,800 30 530 1,300,000 3,000,000 3,400 6.15 13.13 2,780 406 150 0.58 W-01 10/17/2011 1,550 66.2 51.7 2,640 4,400 0 1,150,000 2,620,000 25,700 6.67 20.14 3,740 73 130 0.64 APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 2 of 10 Anal to Y 7 E Q m y a 3 'C `0 m E E -a `6 U 3 o L U a CL O U C o L � m d J N a� C 0 i E c 41 m N d > in V = N Z R R i '= z ,� `� s cn rn .O N N O y .�+ o s N V i .�+ o cn x a N 3 y N U y 4) 41 y 3 u E m E 2 (n O -- ' .5 O U 5 d a cn Z Y 3 E � C O a C O •U a O � x O J 0 E a 41 T O N o y y o NC 2L Ground Water Standard 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 109000 250,000 5009000 NE 6.5-8.5 NE NE NE NE NE Sample Location Date W-01 3/16/2012 24.4 4,480 6.8 270 1,190,000 3,860,000 21,700 6.24 18.19 3,547 0.8 43.5 0.48 W-01 9/24/2012 279 32.2 494 4,580 450 1,500,000 2,890,000 -- 6.54 19.62 3,750 9.6 312 W-01 4/18/2013 501 35.2 692 4,590 357 1,380,000 2,610,000 23,500 6.3 17.49 3,354 8.03 -441.5 0.32 W-01 9/10/2013 117 34 290 4,920 -- 1,370,000 2,900,000 27,600 6.19 22.49 3,067 7.29 49.4 0.29 W-01 4/7/2014 156 24.8 360 4,750 1,160,000 2,850,000 32,300 6.22 11.9 3,406 7.87 374.4 1.46 W-01 9/4/2014 __ 5.9 297 4,600 61.2 1,450,000 2,950,000 -- 6.15 19.97 2,940 6.1 83.7 0.75 W-01 (FD) 4/l/2015 126 21 300 4,540 53.7 1,210,000 2,710,000 -- -- -- -- -- -- W-01 4/3/2015 212 24.5 500 5.3 4,510 50.4 1,260,000 241,000 6.37 17.91 2,676 1 5.09 76.9 0.66 W-01 (FD) 4/3/2015 126 21 300 4,540 53.7 1,210,000 2,710,000 6.37 17.91 2,676 5.09 76.9 0.66 W-01 9/10/2015 330 J 38 1 J 0.88 J 850 4,900 < 20 1,200,000 2,700,000 E 6.37 22.97 3,220 0 225 1.13 W-01 3/8/2016 "" 37 0.24 2,000 5,300 28 1,200,000 2,600,000 6.35 20.5 3,176 8.29 63.1 0.38 W-01 9/8/2016 22 0.38 1,400 4,800 < 1 1,100,000 2,500,000 6.8 22.3 2,905 1.8 -1.5 0.8 W-01 3/29/2017 280 39 1,900 5,100 4.1 J 1,200,000 2,600,000 E 6.38 18.7 3,060 9.7 142.5 0.34 W-01 9/27/2017 190 B 32 860 5,200 - 1,200,000 2,700,000 6.44 22.9 3,020 5.6 139 0 W-01 3/6/2018 930 56 1.8 J 7,200 2.4 1 4,700 5.6 1,200,000 2,600,000 6.59 12.7 3,182 28 260 0.38 W-01 9/12/2018 26 920 5,200 1,200,000 2,700,000 6.19 23.8 2,949 2.53 74.5 0.6 W-01 3/19/2019 20 1,300 3,100 11 940,000 2,200,000 6.31 14.9 2,740 1.39 -109.6 0.67 W-01 9/3/2019 180 24 340 3,800 14 970,000 2,200,000 6.11 20.8 2,553 5.63 -1.2 0.26 W-01 3/31/2020 180 29 450 4,000 18 970,000 2,200,000 6.35 14.4 2,635 6.01 45.4 0.3 W-02 1/16/1990 -- 210 -- -- 0.2 -- -- 6.1 -- -- W-02 9/24/1990 850 219 8.3 1,400 9,900 41,000 533,000 1 14,000 6.17 16.7 717 W-02 10/24/1991 169 82 9,300 7.4 16,500 1,150,000 1,937,000 15,000 1 5.97 18.7 2,080 W-02 3/26/1992 2,790 3.4 38,400 16 -- 1,860,000 2,611,000 12,000 5.83 13.8 2,880 W-02 9/30/1992 -- -- 21,300 1,320,000 2,525,000 6,000 6.06 17.9 2,670 W-02 3/31/1993 417 1 177 1,280 1 7.6 53 1 40 600,000 948,000 2,000 5.64 15.2 167 W-02 9/17/1993 5,650 508 3.8 79 34,700 12 22,300 62 1,570,000 3,350,000 12,000 6.41 20.8 4,030 W-02 3/30/1994 18,700 2,770 3 76 50,900 34 2,400 25 200,000 555,000 -- 5.72 16 1,640 W-02 9/30/1994 21,400 942 37 58 362 13 1 3,710 88 415,000 969,000 15,900 6.23 18.3 1,440 W-02 3/31/1995 45,000 1,710 78 58 5,050 28 3,660 172 155,000 460,000 -- 6.24 13.7 930 W-02 9/29/1995 109,000 3,950 30 209 1 142 206,000 68 3,750 5 292 379,000 944,000 7,370 5.58 16.4 1,345 W-02 3/30/1996 66,500 1,250 12 105 78 96,600 44 3,610 183 12,600 127,000 4,680 5.61 14 316 W-02 9/27/1996 89,100 1,510 < 2 < 21 8.8 150,000 15 3,060 98 -- 373,000 9,220 7.04 21 840 W-02 3/29/1997 64,400 1,100 20 102 72 98,000 47 2,500 150 1,010,000 2,020,000 10,800 6.44 14 1,300 W-02 9/17/1997 56,500 1,620 13 87 88 99,900 35 1 20,200 201 1,410,000 3,600,000 11,300 1 6.6 17 3,780 W-02 3/27/1998 10,900 584 < 21 _0 26,000 6,160 _0 116,000 1,130,000 6,340 6.83 19.9 743 W-02 9/30/1998 15,400 518 39 34 28,800 22 15,000 60 762,000 3,380,000 15,700 6.4 21 753 W-02 3/31/1999 2,380 852 45 35 47,000 21 6,920 73 26,300 262,000 1,410 6.2 18 126 W-02 9/29/1999 9,700 296 36 -0 26,900 9 203 293,000 458,000 15,300 6.19 20 182 W-02 3/16/2000 12,700 434 28 25 19,400 2,160 28 281,000 642,000 7,360 -- -- -- W-02 9/15/2000 5,490 508 1,600 1 7 1,140 93,400 374,000 1,890 6.63 19 170 W-02 3/23/2001 2,600 4,740 6 234 37 26,300 173,000 6,820 6.5 18 270 W-02 3/28/2002 17,900 47 46 45,300 16 3,030 88 23,400 219,000 11,900 6.72 14 140 W-02 10/3/2002 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- W-02 1 3/25/2003 6,070 264 1 8,420 115 25 14,400 118,000 5,290 6.11 18 140 W-02 10/2/2003 4,630 277 < 2 10,900 8 11,100 < 20 1,270,000 3,380,000 7,780 6.11 20 3,020 W-02 4/28/2004 3,600 <2 <21 11,000 6 2,630 36 233,000 634,000 8,130 14.4 1,460 APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 3 of 10 Anal to Y 7 E Q m y a 3 'C `0 m E E -a `6 U 3 o L U a O- O U C o L � m d J N a� C 0 i E c 41 m N d > in V = N Z R R i '= z ,� `� s cn rn .O N N O y .�+ o s N V i .�+ o cn x a N 3 y N U y 4) 41 y 3 u E m E 2 (n O -- ' .5 O U 5 d a cn Z Y 3 E � C O a C O •U a O � x O J 0 E a 41 T O N o y y o NC 2L Ground Water Standard 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 109000 250,000 5009000 NE 6.5-8.5 NE NE NE NE NE Sample Location Date W-02 10/26/2004 30,200 2,140 9 112 83 65,600 21 5,080 144 -- 1,710,000 3,800,000 7,220 3,690 W-02 4/27/2005 2,750 6 9,150 8 8,950 26 1,260,000 2,868,000 13,800 3,170 W-02 10/20/2005 9,380 377 2 20 203 26,200 9 6,800 116 1,510,000 1,700,000 22,000 1,110 W-02 10/19/2006 3,630 8,080 6 1,900 44 749,000 1,210,000 8,990 1,050 W-02 4/27/2007 46,500 451 2 0 55,900 -- -- 46 1,570,000 2,800,000 9,010 1,880 W-02 11/19/2007 5,750 12,000 8 3,030 1,330,000 1,310,000 9,710 1,330 W-02 4/30/2008 4,450 1 5 334 72 246,000 330,000 7,260 609 W-02 4/30/2009 5,170 268 13.9 11.3 12,500 11.8 441 37.5 10,400 157,000 7,570 93.7 W-02 10/15/2009 30,000 13 1,600 4.8 110 67 200,000 36 3,400 42 410 -- -- -- 6.37 15.88 900 30 -145 1.21 W-02 4/20/2010 430 180 1 < 10 490 2,400 <. 830,000 1,900,000 48,800 8.02 13.81 1,880 411 15 5.88 W-02 10/11/2010 2,300 2.4 J 240 0.68 J 8.7 11 J 6,600 1.7 J 2,300 11 -- 210 660,000 1,400,000 -- 6.33 17.02 1,340 712 46 3.99 W-02 4/22/2011 170 2.3 150 1.8 2,100 4,000 14 33 760,000 1,700,000 8,600 -- -- -- -- -- -- W-02 10/17/2011 2,180 113 6.1 2,710 1 4,020 5.8 365,000 842,000 18,700 -- -- -- -- -- -- W-02 3/16/2012 2,540 122 6.1 3,270 45.4 30,000 153,000 7,700 6.52 16.14 1,144 8.4 -8.6 5.75 W-02 9/24/2012 2,020 119 3,910 2,870 430 276,000 2,030,000 -- -- -- -- -- -- -- W-02 4/18/2013 192 339 182 425 56,800 149,000 5,000 - -- -- -- W-02 4/18/2013 -- -- -- -- -- -- -- -- -- 6.48 16.73 261 97.2 7.37 W-02 9/10/2013 451 315 1 676 21 44,600 135,000 10,200 -- -- -- -- -- -- W-02 4/7/2014 1,800 291 2,450 18.8 37,000 -_ 7,600 5.79 10.79 247 54.9 252 4.81 W-02 9/4/2014 5,930 183 6.3 7,950 163 39,000 182,000 - 5.53 20.05 168 28.2 126.4 3.08 W-02 4/3/2015 114 255 148 43,900 134,000 7.62 16.31 256 8.74 19.8 6.94 W-02 9/10/2015 6,800 220 9.5 J 8,800 93 18,000 190,000 B 5.29 22.4 155 30 272 1.38 W-02 3/8/2016 860 280 1,300 29 41,000 130,000 5.68 21.2 193.1 29.7 136.2 5.59 W-02 9/8/2016 1,900 190 3,200 31 14,000 230,000 6.6 17.15 116 -- 101 1.91 W-02 3/29/2017 140 220 200 2.5 J 46,000 100,000 B 7.01 15.2 294.3 5.76 206.2 6.94 W-02 9/27/2017 -- -- -- -- -- -- 5.55 21.15 114 22 176 0 W-02 3/6/2018 100 230 150 7.4 1.3 J 47,000 130,000 6.21 10.6 185 7.47 220 3.7 W-02 9/12/2018 380 170 530 6.5 24,000 99,000 5.68 19.7 184 27.6 1 120.7 2.16 W-02 3/19/2019 230 150 320 11 28,000 94,000 5.29 10.9 125.7 9.39 142.3 0.69 W-02 9/3/2019 5,100 170 4,800 29 18,000 160,000 5.13 22.3 122 -- 53 -- W-02 3/31/2020 970 150 1,100 20 22,000 82,000 5.52 13.1 100.7 19.4 83.9 2.57 W-02 (FD) 3/31/2020 990 150 1,300 20 -- 22,000 76,000 -- -- -- -- -- -- W-03 1/16/1990 -- 300 -- -- -- -- 7 W-03 9/6/1990 -- 8,990 20 810 -- 330 -- 0.5 5.9 -- -- 6.7 W-03 9/21/1990 2,170 134 8.1 2,000 1 80 8,500 174,000 12,000 6.52 16.2 238 W-03 10/23/1991 213 149 240 330 1 116 214,000 1 12,000 6.7 19.7 207 W-03 3/25/1992 119 22,500 136,000 10,000 1 6.12 13.1 307 W-03 9/29/1992 670 120 580 410 0.3 1 20,000 189,000 1,000 5.86 17.1 1 223 W-03 3/31/1993 1,170 180 2,300 1 55 14,900 163,000 2,000 5.53 15.7 207 W-03 9/17/1993 9,460 444 2.8 71 20,700 10 173 106 12,000 207,000 2,000 6.23 18.3 282 W-03 3/30/1994 4,420 259 24 10,700 150 264 107 17,000 180,000 5.74 15.9 180 W-03 9/30/1994 25,400 485 26 67 32,000 17 526 86 21 193,000 26,100 6.28 18 202 W-03 3/31/1995 31,300 466 27 55 36,400 25 430 186 133,000 206,000 ' ` 6.64 12.7 220 W-03 1 9/29/1995 55,400 813 7 51 122 1 70,100 42 1,020 183 139,000 302,000 1,320 5.42 15.4 245 W-03 3/30/1996 17,100 436 2 20 46 25,900 19 409 100 19,500 217,000 3,410 5.61 13 285 W-03 9/27/1996 11,200 257 <20 16,400 15 235 94 59,800 215,000 1,100 7.81 18 243 APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 4 of 10 to 7 E a m E E U o U a O- O U o L '0 m d J N a� C 0 Ec 41 m N d > in V = N Z R = z s cn rn .O N N O s N V �a a to 3 y 4)(n U y 4) 41 y 3 u E m E 2 O -- ' .5 O 5 4) a cn Z E � C O a C O •U a x O J 0 E a 41 T O 4) oE U)6 U)Anal o NC 2L Ground Water Standard 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 109000 250,000 5009000 NE 6.5-8.5 NE NE NE NE NE Sample Location Date W-03 3/29/1997 16,400 347 3 43 23,000 13 384 51 -- 21,100 223,000 7,860 6.57 12 153 W-03 9/17/1997 32,200 478 4 27 67 40,200 24 590 280 88,900 262,000 1,290 6.9 16 366 W-03 3/27/1998 12,200 491 21,300 604 19,100 248,000 1,260 6.06 19.9 542 W-03 9/30/1998 4,150 5,690 151 39 5,050 238,000 1,340 6.8 20 276 W-03 3/31/1999 2,380 3,930 126 73 26,300 262,000 1,410 6.2 18 126 W-03 9/29/1999 2,130 4,230 90 27,300 272,000 1,710 6.77 19 315 W-03 3/16/2000 11,700 356 35 15,700 7 1 334 16 36 17,800 193,000 2,630 -- -- -- W-03 9/15/2000 6,590 323 26 1 9,900 11 309 17 20,900 187,000 1,530 6.69 18 390 W-03 3/23/2001 828 1,020 9 45 23 27,400 175,000 1,560 6.7 17 310 W-03 10/4/2001 3,640 6,020 8 221 13 24,700 186,000 3,200 6.13 17 200 W-03 3/28/2002 1,720 2,820 100 38,500 203,000 1,450 6.71 14 470 W-03 3/28/2002 2,370 2,820 100 17 25,600 177,000 , I -- -- 238 W-03 10/3/2002 8,770 387 2 22 16,400 450 35 58,200 231,000 1,020 8.12 19 210 W-03 3/25/2003 15,300 362 26 23,800 8 622 45 42,600 194,000 < ^ 6.19 19 210 W-03 10/2/2003 2,460 646 4,080 212 28,300 199,000 6.67 17 243 W-03 4/28/2004 1,490 2,820 80 13 1,350,000 171,000 - 14.6 225 W-03 10/26/2004 2,370 3,490 129 17 25,600 177,000 -- 238 W-03 4/27/2005 874 < 2 1,580 66 16 40 34,400 192,000 740 277 W-03 10/20/2005 3,500 252 107 4,230 72 30 71 44,000 218,000 18,000 317 W-03 10/19/2006 553 277 1,020 37 48 70,400 237,000 690 330 W-03 4/27/2007 262 - 2 708 :10 -- 89,400 251,000 1,510 388 W-03 11/19/2007 124 263 156 < 10 65 53,000 293,000 860 403 W-03 11/19/2007 139 254 158 12 65 64,200 278,000 880 402 W-03 4/30/2008 261 148 94 91,000 331,000 760 470 W-03 10/29/2008 274 0.33 10.6 216 3.3 124 0.1 95.5 5.15 96,000 360,000 1,040 571 W-03 4/30/2009 442 368 638 8.5 61.6 154 68.2 199,000 399,000 940 603 W-03 (FD) 4/30/2009 571 268 2.5 332 7.1 30.8 153 < 0.01 32.4 203,000 389,000 1,070 617 W-03 10/12/2009 26 J 2.7 J 160 0.9 J 16 J 0.08 J 150 < n 19 1 740 140,000 430,000 -- 5.88 15.2 -- 8.6 121 2.82 W-03 4/20/2010 870 280 940 49 100 -- 100,000 380,000 9,000 5.96 12.52 644 23.2 264 3.74 W-03 10/11/2010 110 1.3 J 21 J 1.6 J 77 20 790 89,000 310,000 -- 5.89 18.03 497 6.7 256 1.39 W-03 4/21/2011 2.1 140 210 6.7 100 850 120,000 330,000 1,000 5.8 13.07 399 299 3.68 W-03 10/18/2011 380 195 262 22.1 102 1,100 360,000 413,000 7,700 6.85 17.47 764 6.3 128 1.76 W-03 3/16/2012 97.5 101 10.2 112 5.8 1 1,700 220,000 1,070,000 7,800 5.51 1 14.27 755 1.4 1 125.8 2.36 W-03 9/24/2012 1 87.4 49.1 51.9 1,000 418,000 719,000 -- 5.81 17.76 1,110 1.6 521 "- W-03 4/18/2013 56.2 75.7 29.6 844 401,000 852,000 10,600 5.74 13.98 1,146 1.11 -443.1 0.54 W-03 9/10/2013 45.8 98.4 20 -- 447,000 852,000 9,290 5.88 18.91 959 1.13 221.7 0.44 W-03 4/7/2014 39.8 88.4 20.4 338,000 796,000 10,100 5.85 10.71 1,109 0.71 537.7 2.39 W-03 9/3/2014 34 135 23.4 364,000 895,000 -- 5.73 20.62 1,049 2.78 501.6 0.74 W-03 4/2/2015 32.8 155 25 449,000 932,000 6.06 15.68 1 960 2.11 327.6 1.48 W-03 9/9/2015 38 280 11 J 530,000 1,000,000 E 5.92 26.15 1,410 0 485 1.02 W-03 3/8/2016 30 190 170 12 320,000 750,000 4.98 13.1 1,018 0.62 550 1.5 W-03 9/8/2016 29 300 320 2.7 360,000 840,000 6.36 20.8 1,048 0.46 88.2 1 W-03 3/29/2017 15 J 43 310 290 410,000 880,000 B 6.32 15.1 1,218 2.22 180.2 0.79 W-03 9/26/2017 13 BJ 32 190 320 390,000 860,000 6.29 23.28 1,080 2.9 371 0 W-03 3/6/2018 35 130 590 8.8 520,000 1100000 6.7 1 11 149 0.61 481 0.7 W-03 (FD) 3/6/2018 34 140 550 7.6 530,000 1:100:000 -- W-03 9/12/2018 26 170 510 400,000 900,000 6.17 20.2 1,131 0.64 1 195.6 3.2 APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 5 of 10 Anal to Y 7 E Q m y a 3 'C `0 m E E -a `6 U 3 o L U a O- O U C o L � m d J N a� C 0 i E c 41 m N d > in V = N Z R R i '= z ,� `� s cn rn .O N N O y .�+ o s N V i .�+ o cn x a N 3 y N U y 4) 41 y 3 u E m E 2 (n O -- ' .5 O U 5 d a cn Z Y 3 E � C O a C O •U a O � x O J 0 E a 41 T O N o y y o NC 2L Ground Water Standard 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 109000 250,000 5009000 NE 6.5-8.5 NE NE NE NE NE Sample Location Date W-03 3/19/2019 -- 28 -- 230 180 -- 7.4 -- -- -- 250,000 600,000 6.24 13.5 858 2.04 291 1.77 W-03 9/3/2019 27 110 5.4 200,000 500,000 5.96 20.9 680 0.16 177 1.11 W-03 3/31/2020 26 170 9.8 -- 190,000 510,000 6.17 12.8 712 0.37 3,819.1 0.89 W-03B 10/26/2004 2,330 3,170 157 24 174,000 545,000 2,710 -- -- 862 -- -- -- W-03B 4/27/2005 203 2 _- 1,830 15 907 41 36 590,000 840,000 10,100 1,180 W-03B 10/20/2005 3,630 29 4,290 5 68 < 10 75 146,000 627,000 30,000 550 W-03B 10/19/2006 135 950 5 811 < 10 42 318,000 1 750,000 5,240 739 W-03B 4/27/2007 238 901 1,280 < 10 475,000 1,050,000 2,570 1,240 W-03B 11/19/2007 1,170 1,270 582,000 101,000 22,600 1,310 W-03B 4/30/2008 505 1,010 570,000 955,000 1,180 1,270 W-03B 10/29/2008 48 4.9 1,950 946 0.07 - iu 10.5 305,000 760,000 830 1,080 W-03B 4/30/2009 42.6 490 1 10.5 999 <2 1 9.7 1.5 8.7 185,000 827,000 5,560 1,150 W-03B 10/12/2009 39 J 3.6 J 43 J 0.9 J 330 < C, - 880 - - - - - < " � - 250,000 780,000 -- 7.17 14.64 -- 14.4 -42 3.4 W-03B 4/20/2010 49 500 970 280,000 770,000 11,200 6.75 17.46 2,320 108 -51 0.23 W-03B 10/11/2010 2.4 J 45 0.95 J 500 980 9.9 6 J 140 J 300,000 830,000 -- 6.66 17.49 1,010 41.3 -25 W-03B 4/21/2011 2.5 51 970 1,200 12 85 370,000 890,000 1,100 6.63 15.39 956 -72 0.48 W-03B 10/18/2011 52 606 1,320 0.2 1 460,000 1,090,000 9,700 9.49 15.03 1,750 9.4 -86 < 0.01 W-03B (FD) 10/18/2011 50.9 587 1,280 0.2 408,000 1,050,000 8,000 9.49 15.03 1,750 9.4 -86 < 0.01 W-03B 3/16/2012 48.5 472 1,560 47.6 0.2 559,000 533,000 9,800 6.7 14.5 1,474 2.9 -35 0.79 W-03B 9/24/2012 45.1 537 1,340 27.1 0.02 422,000 1,050,000 -- 7.14 16.04 1,650 3.6 -26 < 0.01 W-03B 4/18/2013 40.3 397 743 20 248,000 623,000 16,800 6.64 1 14.86 961 0 -71 0.47 W-03B 9/10/2013 43.2 1 258 448 1 -- 120,000 421,000 6,580 7.23 19.33 1,380 9.2 -43 ). W-03B 4/7/2014 46.6 772 540 -- 123,000 396,000 49,000 6.86 16.07 987 0 -92 0.38 W-03B 9/3/2014 48.4 321 452 12.5 18,100 403,000 -- 6.85 16.21 988 1.4 -87 2.01 W-03B 4/2/2015 47.8 3,070 520 79,400 415,000 7.21 15.95 500 8.5 122.7 0.74 W-03B 9/9/2015 42 170 570 110,000 390,000 B 6.69 27.24 670 0 -7 0.96 W-03B 3/8/2016 50 680 440 2.3 73,000 390,000 7.28 1 13 596.4 6.02 62 0.23 W-03B 9/8/2016 45 340 380 71,000 380,000 7.3 21.35 538 0.44 62 0.7 W-03B (FD) 9/8/2016 46 350 380 1.1 74,000 370,000 -- -- -- -- -- -- W-03B 3/29/2017 8.9 J 44 400 440 110,000 410,000 B 7.28 13.7 687 0.58 156.6 0.52 W-03B (FD) 3/29/2017 8.2 J 46 400 470 110,000 360,000 B -- -- -- -- -- -- W-03B 9/26/2017 19 BJ 55 820 310 65,000 370,000 7.22 20.23 453 2.7 28 1 0 W-03B 3/6/2018 - "" 45 210 330 100,000 440,000 8 1 10 652 0.1 -28 0.55 W-03B 9/12/2018 47 240 230 61,000 340,000 -- 23 504 0.18 -36 0.65 W-03B 3/19/2019 47 650 48 39,000 290,000 7.18 10.7 459.9 3.63 71.3 3.17 W-03B 9/3/2019 42 35 24,000 260,000 7.15 19.1 385 0.39 -11.5 0.59 W-03B 3/31/2020 59 87 23,000 240,000 7.53 12.8 400.3 0.2 24.9 0.44 W-04 4/4/1995 9,720 15,600 7 564 1 58 7,880 231,000 136,000 6.07 19 234 -- -- -- W-04 9/17/1997 4,420 2 10,000 6 406 190 8,860 212,000 3,190 7.5 18 366 W-04 3/27/1998 3,410 6,250 -- 44 7,120 226,000 2,690 6.72 19.2 390 W-04 9/30/1998 219 1,610 299 6,420 200,000 7,260 5.9 21 322 W-04 3/31/1999 637 2,150 1 285 5,710 202,000 8,530 6.5 16 279 W-04 9/29/1999 127 1,440 5 271 24 207,000 2,850 6.38 18 315 W-04 3/16/2000 <0.1 1,470 298 191,000 6,050 -- -- -- W-04 9/15/2000 165 ' 1,090 252 5,300 241,000 15,500 6.22 17 310 APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 6 of 10 Anal to Y 7 E Q m y a 3 'C `0 m E E -a `6 U 3 o L U a O- O U C o L � m d J N a� C 0 i E c 41 m N d > in V = N Z R R i '= z ,� `� s cn rn .O N N O y .�+ o s N V i .�+ o cn x a N 3 y N U y 4) 41 y 3 u E m E 2 (n O -- ' .5 O U 5 d a cn Z Y 3 E � C O a C O •U a O � x O J 0 E a 41 T O N o y y o NC 2L Ground Water Standard 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 109000 250,000 5009000 NE 6.5-8.5 NE NE NE NE NE Sample Location Date W-04 3/23/2001 2,750 4 9,910 16 447 28 -- 6,530 219,000 5,990 6.4 16 240 W-04 10/4/2001 204 915 7 229 186,000 7,800 6.28 20 300 W-04 3/28/2002 1,460 212 5,160 196,000 1,680 6.18 14 190 W-04 10/3/2002 1,130 237 29 5,080 202,000 4,070 6.11 19 280 W-04 3/25/2003 976 212 6,050 185,000 1,610 6.17 16 260 W-06 10/2/2003 1,920 268 24 3,220 1 154 440 95,000 466,000 34,000 7.25 19 661 W-06 4/28/2004 1,160 30 26 1 917 7 37 149 370,000 1 692,000 139,000 -- 14.7 937 W-06 10/26/2004 790 89 32 259 12 87 116,000 630,000 79,200 917 W-06 4/27/2005 389 < 20 5 56 87,500 565,000 13,200 932 W-06 10/20/2005 - " " 40 355.7 60 35,400 553,000 27,000 939 W-06 10/19/2006 529 <<' 77 1 12 66 46,400 471,000 29,300 655 W-06 4/27/2007 2,660 29 2,790 106 168 29,500 442,000 8,840 776 W-06 11/19/2007 627 711 24 38 11,200 1 431,000 8,980 694 W-06 4/30/2008 37 392,000 5,610 615 W-06 10/29/2008 235 35.8 0.41 6.8 268 9.3 67 393,000 4,130 724 W-06 (FD) 10/29/2008 222 293 1 2.7 460 4.9 84.6 0.16 101 98,800 384,000 860 574 W-06 4/30/2009 139 36.6 7 33.1 2.9 1.5 8.1 33.2 10,500 463,000 10,300 807 W-06 10/12/2009 140 2.3 J 28 5.5 4.3 J 44 J 1.7 J 0.2 17,000 J 380,000 -- 10.55 18.86 1,020 33.1 -243 0.16 W-06 4/20/2010 1,700 59 400 14 3,200 87 69 16,000 450,000 9,100 10.74 18.92 930 209 -227 0.03 W-06 10/11/2010 320 37 420 19 J 2,800 56 -- 120 J 13,000 410,000 -- 10.57 17.7 816 35.7 -250 ' 1 - W-06 4/22/2011 260 1.2 33 190 7 1,000 1.3 28 1.1 17 21 16,000 410,000 3,800 11.07 13.85 562 9.6 -189 1.01 W-06 10/17/2011 421 26.9 60.9 89 311 6.8 60.1 0.2 11,000 414,000 6,100 -- -- -- -- -- -- W-06 10/18/2011 421 26.9 60.9 89 311 6.8 60.1 -- 11,000 414,000 6,100 12.24 18.13 1,040 8.6 -313 0.37 W-06 3/16/2012 221 44.7 8.5 83 10.1 0.2 11,400 499,000 5,200 11.16 17.26 845 1.9 -234 0.38 W-06 9/26/2012 202 37.3 23.6 162 14.1 0.02 12,200 317,000 -- 11.44 16.32 667 1 8.9 -21 W-06 4/19/2013 517 41.1 18.3 277 6.4 21.2 12,200 334,000 4,920 -- -- -- -- -- -- W-06 4/19/2013 -- -- 18.3 277 6.4 21.2 -- 12,200 334,000 4,900 10.44 15.8 620 8.6 -450.5 0.4 W-06 9/11/2013 312 46.9 21.7 397 7.7 19.4 12,100 335,000 4,390 10.63 17.85 506 6.87 82.6 0.71 W-06 4/9/2014 154 42.2 6.9 141 -- 12,400 304,000 4,700 10.85 15.07 634 4.23 -43.1 1.23 W-06 9/5/2014 33.7 11,800 337,000 -- 10.81 15.7 637 3.87 -37.4 1.19 W-06 4/2/2015 - ,- 35.4 9.4 72.6 -- 11,700 314,000 10.26 16.31 555 2.62 -142.1 2.74 W-06 9/8/2015 570 37 110 900 23 11,000 280,000 10.22 21.3 496 22.7 -59 1.95 W-06 3/9/2016 35 18 230 - 12,000 270,000 10.08 16.4 464.5 7.29 -80.9 0.48 W-06 9/6/2016 62 37 110 9,900 260,000 10.1 16.4 754 2 -106 0.7 W-06 3/28/2017 530 76 36 990 0.5 J 17 10,000 220,000 9.75 15.5 437.1 9.85 -67.2 0.59 W-06 9/27/2017 220 B 41 14 220 0.58 J 6.5 11,000 270,000 9.86 16.8 360 4.48 82 1.26 W-06 3/6/2018 100 39 32 620 9.4 11,000 260,000 9.56 11.86 0.399 11.4 -29 1.5 W-06 9/13/2018 2,100 200 42 2,900 1.6 330 57,000 270,000 9.9 18.2 475 7.38 124 0.67 W-06 3/20/2019 42 5.5 100 10,000 270,000 9.51 15.6 435.2 3.18 80.7 0.68 W-06 9/4/2019 100 38 100 12,000 270,000 9.01 19.7 398 -- -109.5 0.37 W-06 4/3/2020 180 43 7.2 190 5.6 10,000 250,000 9.4 15.6 397 7.36 -56.6 0.42 W-07 1/6/2011 -- 110 200 120 9,300 200,000 7.1 15.4 298 5.2 83 2 W-07 4/21/2011 92 80 520 1 160 44 6,600 190,000 7.26 15.24 301 12 0.62 W-07 9/25/2012 318 77.3 628 173 0.02 1 6,200 206,000 8.09 15.07 403 18.2 46 3. W-07 4/18/2013 403 140 6 1,460 146 20 1 10,200 173,000 29,000 6.89 15.68 271 17.1 -448.1 1.7 APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 7 of 10 to 7 E a m E E U o U a O- O U o L '0 m 4) J N a� C 0 Ec 41 m N d > in V = N Z R = z s cn rn .O N N O s N V �a a N 3 y 4)(n U y 4) 41 y 3 u E m E 2 O -- ' .5 O 5 4) a cn Z E � C O a C O •U a x O J 0 E a 41 T O 4) oE U)6 U)Anal o NC 2L Ground Water Standard 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 109000 250,000 5009000 NE 6.5-8.5 NE NE NE NE NE Sample Location Date W-07 9/11/2013 257 112 950 124 -- 8,100 3,310 7.43 16.19 271 7.7 4.3 0.87 W-07 4/9/2014 427 -- 131 -- 1,830 97.1 -- -- -- 11,200 181,000 3,500 6.79 15.55 265 21.3 119.1 2.87 W-07 9/5/2014 797 81.1 1,580 189 6,400 220,000 7.5 15.93 289 8.08 10.3 1.35 W-07 4/2/2015 402 136 1,970 69.6 10,800 169,000 7.5 15.87 284 9.37 6.3 2.19 W-07 9/9/2015 380 J 78 28 1,600 150 5,700 170,000 B 6.73 18.73 349 5.9 23 4.64 W-07 3/9/2016 800 140 16 3,800 100 11,000 110,000 6.98 14.1 283.5 40.4 114.9 1.87 W-07 9/6/2016 260 130 1,800 53 9,800 89,000 7.1 16.8 206 20.5 89 3.1 W-07 3/28/2017 500 130 28 3,600 0.93 J 110 8,900 160,000 B 6.92 15.3 280.2 42.9 12.3 1.9 W-07 9/27/2017 2,200 B 100 11 4,400 0.99 J 800 5,400 160,000 B 7.53 16.32 281 9.24 50 0.5 W-07 (FD) 9/27/2017 200 B 71 4.1 J 1,100 0.67 J 93 5,400 230,000 7.53 16.32 281 9.24 50 0.5 W-07 3/5/2018 240 73 7.9 1,600 0.43 220 5,600 210,000 7.25 13.82 341 29.4 16 1.22 W-07 3/6/2018 240 73 7.9 1,600 0.43 J 220 5,600 210,000 -- -- -- -- -- -- W-07 9/12/2018 310 81 9.6 2,800 190 6,300 210,000 7.3 17.7 327 56.3 32.4 0.74 W-07 9/12/2018 310 81 9.6 2,800 190 6,300 210,000 - -- -- -- -- -- W-07 3/20/2019 96 100 1,400 29 11,000 180,000 6.5 15.7 267 21.3 134.7 2.28 W-07 (FD) 3/20/2019 140 110 1,600 32 11,000 180,000 6.5 15.7 267 21.3 134.7 2.28 W-07 9/4/2019 280 78 1,800 150 6,000 220,000 6.75 15.4 322 26.1 -73.3 0.27 W-07 4/2/2020 130 75 6.1 1,200 72 5,400 190,000 7.34 13.8 339.2 31.1 0.5 0.36 W-08 1/6/2011 -- 330 0.12 2,900 65 -- -- 73,000 210,000 7.47 14.8 300 49.6 182 7.88 W-08 4/20/2011 390 1.2 180 940 20 8.9 1 240 68,000 240,000 1,100 5.68 15.1 391 133 203 7.06 W-08 9/26/2012 643 166 25.2 7.7 777 63.6 151 250 86,800 242,000 -- 6.08 20.48 382 6.2 158 5.86 W-08 4/18/2013 5,940 465 86.4 85.6 9,760 220 122 292 95,000 247,000 5,160 5.83 19.45 330 9.6 -428 5.3 W-08 9/10/2013 1,180 407 41.7 40 1,900 37.1 67.1 -- 101,000 244,000 5,600 5.69 21.81 310 9.3 95.3 6.02 W-08 4/9/2014 1,670 147 7.5 -- 2,940 86.5 -- 98,800 263,000 4,900 5.58 18.13 371 11.91 195.4 5.87 W-08 9/3/2014 318 136 463 23 13.4 114,000 300,000 -- 5.37 14.79 329 8.4 154.3 5.91 W-08 4/2/2015 873 206 42.7 1,410 26.9 11.5 62,700 219,000 5.93 21.58 340 39.9 68.4 4.64 W-08 9/9/2015 840 160 84 1,200 180 96,000 240,000 B 5.8 31.23 322 35.6 125 1 3.55 W-08 3/9/2016 2,700 290 310 4,800 1.9 290 6.4 65,000 230,000 6.19 15.6 332 87 84.8 5.24 W-08 9/7/2016 1,900 280 7.9 4,100 60 4 64,000 200,000 6.3 20.1 240 9.6 98 6.5 W-08 3/28/2017 1,700 380 99 3,300 1 58 6.7 66,000 170,000 B 5.73 19.9 1 275.2 21.5 177 5.74 W-08 9/26/2017 2,600 B 290 51 2,500 2.5 120 6.4 53,000 210,000 6.02 16.32 211 33.1 128 7.91 W-08 3/5/2018 560 150 20 1,100 0.56 J 67 4 J 56,000 190,000 5.66 18.95 221 41 203 18.32 W-08 9/12/2018 62 36 12 230 11,000 260,000 6.94 18.5 394 91.3 1 119 5.87 W-08 3/20/2019 450 240 20 730 17 17,000 130,000 5.39 12.7 127.8 20.6 157.8 6.89 W-08 9/4/2019 270 300 370 11 61,000 180,000 5.13 16.3 205.7 9.8 61.6 6.47 W-08 4/2/2020 64 150 5.1 97 69,000 170,000 5.57 18.3 239 4.9 118.1 6.78 W-09 1/5/2011 -- 27 440 32 16,000 150,000 8.39 15.9 274 119 22 W-09 1/5/2011 -- 27 440 32 16,000 150,000 8.39 15.9 274 119 22 W-09 4/20/2011 83 39 170 23 42 10,000 130,000 8.83 16.78 286 121 -10 0.45 W-09 9/26/2012 116 102 10 108 10.1 8,800 149,000 -- 10.98 16.25 350 7.9 12 W-09 4/19/2013 281 115 8.5 157 8 9,270 155,000 2,400 9.62 16.48 286 9.7 -455 0.22 W-09 9/10/2013 114 94 1 68.6 -- 9,100 169,000 2,410 10.45 16.52 272 3.97 -73.4 1 0.27 W-09 4/9/2014 - �. � 54.8 11,100 204,000 3,100 9.44 14.36 257 4.7 -421 0.18 W-09 9/4/2014 134 60.2 222 7.3 11,100 212,000 -- 9.74 19.92 303 11.2 32.8 3.54 W-09 4/3/2015 < 100 113 5 9,100 279,000 -- 11.66 16.84 982 3.57 -184.4 0.7 APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 8 of 10 Anal to Y 7 E Q m y a 3 'C `0 m E E -a `6 U 3 o L U a CL O U C o L � m d J N a� C 0 i E c 41 m N d > in V = N Z R R i '= z ,� `� s cn rn .O N N O y .�+ o s N V i .�+ o cn x a N 3 y N U y 4) 41 y 3 u E m E 2 (n O -- ' .5 O U 5 d a cn Z Y 3 E � C O a C O •U a O � x O J 0 E a 41 T O N o y y o NC 2L Ground Water Standard 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 109000 250,000 5009000 NE 6.5-8.5 NE NE NE NE NE Sample Location Date W-09 9/8/2015 110 J -- 100 3.7 J -- 41 J 1.4 J -- -- -- -- 9,100 280,000 11.77 19.18 856 7 -177 1.67 W-09 3/8/2016 90 89 83 10,000 290,000 12.22 16.9 888 3.16 -166.7 0.35 W-09 9/6/2016 74 97 39 8,400 260,000 11.8 16.6 754 2 -106 0.7 W-09 3/28/2017 99 100 11 81 1.3 J 9,300 260,000 11.61 17.6 862 2.68 47.9 0.22 W-09 9/26/2017 140 B 100 5.9 96 0.41 J 2 J 11,000 230,000 11.59 16.95 655 1.85 -147.2 0.94 W-09 3/6/2018 61 110 3.8 J 51 11,000 270,000 11.36 11.6 690 3.7 -36 2.03 W-09 9/11/2018 130 11,000 190,000 10.78 17.2 487 0.82 90.7 0.33 W-09 3/20/2019 110 12,000 270,000 11.34 17.9 798 1.51 -230.1 0.31 W-09 9/4/2019 130 13,000 180,000 9.59 17 292.4 0.5 -139.4 0.15 W-09 4/2/2020 42 170 12,000 230,000 11.37 18.1 1 758 0.87 -400 0.19 PW-01 4/29/1988 152 59 8 57 57 314 u.v w 576 37,000 500,000 1,280 6.9 -- -- -- -- -- PW-01 7/13/1989 -- 100 -- -- -- < 0.006 - -- -- -- -- -- -- -- -- -- -- PW-01 9/6/1990 -- 90 -- 9.9 -- < 5 - -- -- -- -- 6.8 PW-01 10/23/1991 130 0 620 1,230 < 5 3,310 460,000 850,000 8,000 6.41 15.1 1,247 -- -- -- PW-01 8/10/2009 -- 35 4,800 1,800 -- 680,000 -- -- 6.98 1 15.3 2,860 32.1 1 13 PW-01 5/13/2010 46 6,800 1 2,500 1 5,100 1,000,000 2,100,000 6.68 16.47 2,580 215 -54 13.5 PW-01 5/13/2010 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- PW-01 5/14/2010 44 6,300 9.4 2,400 21,000 940,000 2,100,000 6.76 16.09 2,570 166 -50 13.2 PW-01 5/14/2010 34 2,900 2,000 560 800,000 1,900,000 6.76 15.03 2,430 217 -20 14.9 PW-01 4/21/2011 280 11 46 4,400 3,000 54 920,000 2,000,000 2,100 6.2 16.58 2,250 24 0.6 PW-01 9/26/2012 1,060 52.2 4,280 2,780 < 10 1 13.5 450 1,190,000 2,980,000 -- 6.8 15.91 2,890 8.7 2 - PW-01 4/18/2013 1,080 55.4 3,830 1 2,700 < 10 10.1 626 1,080,000 1,940,000 14,200 6.2 16.23 2,401 3.03 -453.1 0.6 PW-01 9/10/2013 1,010 52.4 5,680 2,990 0.01 18.8 -- 1,150,000 2,240,000 20,500 6.21 17.72 2,191 5.24 44.1 0.4 PW-01 4/7/2014 628 48.9 4,780 3,130 < 10 -- 914,000 1,980,000 16,600 6.23 15.34 2,689 3.2 40.7 0.83 PW-01 9/5/2014 1,370 32.3 8.4 6,160 3,080 49.9 1,010,000 2,260,000 -- 6.14 16.72 2,552 5.69 -16.2 3.93 PW-01 4/2/2015 195 45 435 595 62.3 1,010,000 187,000 5.98 21.63 241 6.6 332 4.59 PW-01 9/9/2015 410 54 0.8 J 8.3 J 5,000 3,400 990,000 2,100,000 E 6.34 26.1 2,220 0 1 0.49 PW-01 3/8/2016 420 51 8.8 5,000 3,500 940,000 2,100,000 6.39 14.3 2,524 3.12 39.2 0.4 PW-01 9/6/2016 250 42 0.12 5,300 3,300 2.5 840,000 1,900,000 6.7 17.9 2,080 1.6 -2 0.8 PW-01 3/28/2017 61 39 19 4,200 3,300 3.8 J 840,000 1,900,000 E 6.38 15.8 2,342 3.39 42.3 0.31 PW-01 9/26/2017 180 B 48 5.3 4,700 1.3 3,600 - 780,000 1,900,000 6.36 16.82 1,880 1 14.3 0.48 PW-01 3/6/2018 870 48 3.8 J 6,500 0.85 J 3,100 3.6 J 760,000 1,800,000 6.09 13.55 2,420 39.1 98 1.01 PW-01 9/13/2018 160 37 4,500 3,100 r 750,000 1,700,000 6.43 15.5 1,709 9.76 74.4 1 0.26 PW-01 (FD) 9/13/2018 150 37 4,500 3,300 770,000 1,700,000 6.43 15.5 1,709 9.76 74.4 0.26 PW-01 3/19/2019 430 38 5,300 2,700 7.8 670,000 1,500,000 6.41 14.7 1,984 5.73 3.2 0.49 PW-01 9/4/2019 330 35 3,000 3,000 20 750,000 1,700,000 5.8 15.6 1,963 3.82 -56.1 0.17 PW-01 (FD) 9/4/2019 170 35 3,300 3,100 740,000 1,700,000 -- -- -- -- -- -- PW-01 4/2/2020 250 36 3,300 2,700 21 830,000 1,700,000 6.39 15.2 2,088 4.14 -1.6 0.25 PZ-01 1/4/2011 -- 81 1,600 78 98,000 180,000 PZ-01 4/20/2011 1,600 63 1.9 2,700 1.6 110 110 30,000 100,000 4,200 PZ-01 9/25/2012 �0 99.7 138 119 1,900 319,000 806,000 - PZ-01 4/17/2013 182 64.3 200 1 55.6 240 95,500 217,000 4,960 PZ-01 9/10/2013 1 82.7 1 72.1 17.8 -- 1 179,000 485,000 6,530 PZ-01 4/6/2014 56.7 148 28.3 98,900 1,430,000 5,000 PZ-01 9/3/2014 52,800 778 280 69,200 27 3,130 162,000 503,000 - APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 9 of 10 Anal to Y 7 E Q m y a 3 'C `0 m E E -a `6 U 3 o L U a O- O U C o L � m d J N a� C 0 i E c 41 m N d > in V = N Z R R i '= z ,� `� s cn rn .O N N O y .�+ o s N V i .�+ o cn x a N 3 y N U y 4) 41 y 3 u E m E 2 (n O -- ' .5 O U 5 d a cn Z Y 3 E � C O a C O •U a O � x O J 0 E a 41 T O N o y y o NC 2L Ground Water Standard 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 109000 250,000 5009000 NE 6.5-8.5 NE NE NE NE NE Sample Location Date PZ-01 4/l/2015 -- 60.1 -- 87 11.4 -- -- -- -- 91,900 290,000 8.13 16.48 509 2.19 17.4 7.51 PZ-01 9/8/2015 -- -- -- -- -- -- -- -- -- - -- -- PZ-01 3/7/2016 72,000 1,100 220 110,000 58 2,800 110,000 260,000 PZ-01 9/7/2016 -- -- -- -- -- -- -- -- PZ-01 3/27/2017 -- -- -- -- -- -- -- -- PZ-01 9/25/2017 PZ-01 3/5/2018 -- -- -- -- -- -- -- PZ-01 9/11 /2018 PZ-02 1/4/2011 -- 120 770 410 180,000 360,000 PZ-02 4/20/2011 4,200 99 6.9 2.7 7,400 3.4 410 0.14 100 82,000 250,000 6,700 PZ-02 9/25/2012 113 106 38.9 2,000 306,000 767,000 - PZ-02 4/17/2013 222 63.7 247 28.4 180 98,200 197,000 4,630 PZ-02 9/10/2013 - 83.9 83.8 13.8 -- 169,000 455,000 6,250 PZ-02 4/6/2014 114 54 180 12 93,800 255,000 4,000 PZ-02 9/4/2014 4,250 122 5.7 7,330 464 159,000 511,000 - PZ-02 4/l/2015 58.4 159 9.7 82,200 267,000 8.15 15.93 466 3.17 18.7 8.05 PZ-02 9/8/2015 41,000 560 9.5 66 85,000 30 9,600 97,000 340,000 -- -- -- -- -- -- PZ-02 3/7/2016 49,000 810 3.4 69 110,000 34 16,000 38,000 140,000 PZ-02 9/7/2016 1,900 230 1.3 E 19,000 8.5 4,500 59,000 240,000 PZ-02 3/27/2017 11,000 270 7.5 20 33,000 8.1 6,400 63,000 210,000 B PZ-02 9/25/2017 15,000 B 200 6.2 21 24,000 8.4 2,600 55,000 250,000 7.51 21.29 373 4.84 -18.8 14.52 PZ-02 3/5/2018 3,100 220 9.3 5.3 26,000 6.8 2,700 66,000 240,000 -- -- -- -- -- -- PZ-02 9/11/2018 14,000 280 9.5 31 45,000 16 1,800 57,000 280,000 -- -- -- -- -- -- PZ-02 3/19/2019 55 36 1.7 390 17 25,000 120,000 5.96 8.3 191.5 60.9 157 6.2 PZ-02 9/3/2019 160 62 5.3 770 450 < 46,000 230,000 -- -- PZ-02 4/l/2020 69,000 710 20 80 130,000 38 7,200 7.4 33,000 160,000 PZ-03 1/5/2011 -- 140 9.4 14,000 1,700 24,000 140,000 PZ-03 4/21/2011 55 6,700 560 1 49 25,000 100,000 3,000 PZ-03 9/25/2012 -- -- -- -- -- -- -- -- -- -- -- PZ-03 4/17/2013 914 55.7 1,090 1 10.2 1 30,500 87,000 3,230 PZ-03 9/9/2013 < 0.1 68.6 179 7.2 45,200 158,000 13,300 PZ-03 4/6/2014 205 51.2 265 25,200 119,000 2,500 PZ-03 9/4/2014 80 233 62.5 37,300 177,000 -- PZ-03 4/l/2015 143 57.9 335 5.4 30,400 105,000 10.39 10.78 178 4.58 12 9.91 PZ-03 9/8/2015 110 J 82 180 17 56,000 210,000 -- -- PZ-03 3/7/2016 16,000 200 1.9 20 56,000 10 400 18,000 49,000 PZ-03 9/7/2016 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- PZ-03 3/27/2017 PZ-03 9/25/2017 -- -- -- -- -- -- -- PZ-03 3/5/2018 -- -- -- -- -- -- -- PZ-03 9/11 /2018 PZ-04 1/5/2011 -- 170 12 10,000 89 46,000 190,000 PZ-04 4/21/2011 170 58 450 15 52 24,000 78,000 2,300 PZ-04 9/25/2012 168 81.7 285 40.5 0.0" 58,400 181,000 -- APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 10 of 10 E N ' E � - y N 2 (n C J rn U y O -- O a 0 .O o m 41 c O E N s N y ' .5 •U a 41 N V a T N Z O 3 O U Z O 7 3 E 3 E R y i Y O N E m y 'C E -a o L a O- C � M a� C 0 i c 41 d > V R i ,� `� .�+ .�+ � u E o d � o y Anal to Y Q a `0 m `6 U U O U o L d -1 m N in = N '= Z S rn o o x a m a rn 3 H x O y a NC 2L Ground Water Standard 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 109000 250,000 5009000 NE 6.5-8.5 NE NE NE NE NE Sample Location Date PZ-04 4/17/2013 889 53.7 1,050 12.4 30,000 89,000 3,280 -- - -- - -- - PZ-04 9/9/2013 155 61.7 307 15.8 -- 31,500 131,000 3,530 - - - - - - PZ-04 4/6/2014 295 - 53.3 399 5.1 - -- 24,200 113,000 2,500 - - - - - - PZ-04 9/4/2014 - 77.5 394 52.4 - - 41,200 183,000 -- - - - - - - PZ-04 4/1/2015 133 - 54.6 - 249 - - 27,200 105,000 - - 9.98 162 4.21 16.6 8.91 PZ-04 9/8/2015 -- -- -- -- -- -- -- - -- -- PZ-04 3/7/2016 160,000 - 2,500 14 200 - 160,000 51 1 3,000 - - 45,000 160,000 - - - - - - - PZ-04 9/7/2016 -- -- -- -- -- - PZ-04 3/27/2017 - - - - - - - - - - - - PZ-04 9/25/2017 - - - - - - - - - PZ-04 3/5/2018 PZ-04 9/11/2018 2,200 - 240 1.4 29800 33 - - - 94,000 280,000 - - -- -- -- -- -- PZ-04 3/19/2019 130 79 1 200 12 -- - -- 31,000 120,000 - 7.22 8.3 171.1 15.7 182.5 5.06 PZ-04 4/1/2020 95,000 19600 4.8 130 1609000 34 3,400 - - - 37,000 130,000 - -- -- -- -- - -- PZ-05 1/5/2011 -- - 92 19300 19300 - - 130,000 5109000 - - - - - - - PZ-05 4/21/2011 5,300 81 10 14 13,000 2.9 710 2.2 20 60 85,000 230,000 11,000 - - - - - - PZ-05 9/25/2012 -- - -- - -- -- -- -- -- -- -- - - - - PZ-05 4/17/2013 - - - - - - - - - PZ-05 9/9/2013 - - - - - - - - - - - PZ-05 4/6/2014 -- 66 128 - -- 115,000 270,000 3,500 -- - -- - -- - PZ-05 9/4/2014 143 129 877 567 12.9 - - 306,000 7659000 -- PZ-05 4/1/2015 494 -- 83.4 769 82.3 - - 153,000 339,000 - 7.04 10.53 516 1.06 34 7.17 PZ-05 9/8/2015 -- -- -- -- -- -- -- -- - -- -- PZ-05 3/7/2016 41,000 - 2,500 52 1 1,300,000 27 32,000 - - 63,000 150,000 - - - - - - - PZ-05 9/7/2016 740 58 0.27 69800 120 - - 28,000 110,000 - - - - - - - PZ-05 3/27/2017 10,000 - 510 5.8 30 300,000 5.8 1,100 - - 150,000 -- - - - - - - - PZ-05 9/25/2017 6,000IS 380 0.93 11 2509000 2.7 880 - - - 210,000 450,000 - 6.86 18.75 581 1,268 46 2.52 PZ-05 3/5/2018 630 370 1 1.6 3.2 J -- 230,000 1.6 2,000 2.5 J -- - -- 140,000 340,000 - 6.96 11.01 447 -- 149 11.89 PZ-05 9/11/2018 89000 - 410 8 17 L1709000 3.7 59300 - - - 140,000 360,000 - -- -- -- -- -- -- PZ-05 3/19/2019 2,000 55 3.2 3,400 37 -- -- - -- 55,000 160,000 - 5.78 8 210.6 120 173.5 4.39 PZ-05 9/3/2019 270 -- 75 7.6 19100 470 - - - - 170,000 400,000 - -- -- -- -- - - PZ-05 4/1/2020 11,000 - 180 8.1 17 51,000 4.7 770 - - - - 35,000 150,000 - - - - - - - Notes: All concentrations in micrograms per liter (ug/L) unless otherwise noted NE - Not established -- - Not sampled B - Detected in the method blank J - Estimated result < LOQ and > DL Bold with gray background indicates exceedance of NC Groundwater Standard Analysis for arsenic, copper, mercury, silver, zinc, nitrates & TOC discontinued in 2014 per Corrective Action Plan (ERM, 2/2014). NSA - Location inaccessible; no sample collected NSB - Obstruction in well; no sample collected NSC - Well dry; no sample collected NSD - Insufficient volume; no sample collected NSE - Well damaged; no sample collected NSF - Pump broken; no sample collected NSG - Surface water location dry; no sample collected APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 1 of 9 Analyte 7 E E Q y L Q L lC oo = E 'O <6 U o L L U L CL Q. O U C O - N y J G1 y N C 0 L N 2 E c d d (n m i V a N Z R R L �= z �; ,� `� 7 cn O O y G +�+ O =O m V i O ram+ O H N 2 a Ul _ A N U d d d d d O E d E t� in 7 w > U C O U V y Q N ? w o 7 E � - C N O C O 5 3 N O +_ x O J E C G7 � x O N o y N G NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE Sample Location Date SS-01 4/29/1988 118 8 86 15 220 64,000 220,000 2,810 6.8 -- SS-01 7/13/1989 -- 100 -- -- -- -- -- -- -- -- -- SS-01 9/6/1990 -- 64 -- -- -- -- -- -- -- 7.9 -- -- SS-01 9/21/1990 140 4.8 200 520 40,000 352,000 12,000 7.18 11.6 490 SS-01 10/23/1991 10920 0.2 150 108,000 248,000 12,000 7.9 17.2 381 SS-01 3/25/1992 4,150 3.4 20 5,000 15.8 64 0.2 "j 250 9,400 185,000 14,000 5.8 11.3 126 SS-01 9/29/1992 40 160 85 0.2 190 84,000 241,000 2,000 5.73 13.8 356 SS-01 3/31/1993 20 400 1 77 0.2 29 1,340 70,400 127,000 2,000 5.89 13 207 SS-01 9/17/1993 240 - 10 20 598 28 0.2 10 450 77,400 251,000 3,000 7.07 20.9 360 SS-01 3/30/1994 220 < 10 20 873 30 0.2 :10 250 30,600 108,000 5,000 5.88 14 380 SS-01 9/30/1994 1,300 < 10 20 1,690 6 84 0.2 430 64,800 255,000 30,000 7.05 19.1 332 SS-01 3/31/1995 3,580 < 10 20 2,440 106 0.2 246 190 48,900 211,000 7.75 13.9 290 SS-01 9/29/1995 200 < 10 20 358 7 38 500 70,000 264,000 3,740 5.16 13.9 458 SS-01 3/30/1996 279 < 10 20 547 14 185 31,300 129,000 1,790 6.68 11 193 SS-01 9/27/1996 125 < 10 20 300 5 21 95 290 56,100 225,000 2,360 7.65 19 336 SS-01 3/29/1997 307 < 10 552 16 13 225 30,000 138,000 3,040 7.63 16 94 SS-01 9/17/1997 476 < 10 835 40 169 625 47,400 224,000 1,670 7.9 19 319 SS-01 3/27/1998 190 < 10 20 685 12 0.2 61 680 38,700 163,000 5,230 7.64 18.6 473 SS-01 9/30/1998 126 < 10 20 540 6 33 0.2 300 28,000 177,000 4,090 7.2 18 322 SS-01 3/31/1999 239 < 10 20 332 E 44 0.2 120 63,200 191,000 2,490 7.1 16 247 SS-01 9/29/1999 1,530 ' 10 20 3,330 5 88 0.2 90 23,200 143,000 8,810 7.83 16 308 SS-01 3/16/2000 117 20 1,940 922 0.2 10 199 50,900 202,000 3,780 -- -- -- SS-01 9/15/2000 327 J 20 166 38 0.2 ; 10 160 26,100 157,000 5,080 7.32 19 410 SS-01 3/23/2001 ,r 20 158 10 " " :10 -" 26,100 113,000 2,810 6.9 16 150 SS-01 10/4/2001 116 20 29 ; 10 300 99,000 343,000 5,300 7.39 19 440 SS-01 3/28/2002 J 201 10 27 320 41,900 177,000 3,180 7.03 11 400 SS-01 10/3/2002 317 "9 767 52 750 73,300 300,000 3,070 -- 19 330 SS-01 3/25/2003 673 20 607 24 = 10 115 31,600 119,000 2,080 6.87 18 440 SS-01 10/2/2003 l J 20 705 72 446 29,400 181,000 2,380 6.33 15 249 SS-01 4/28/2004 20 179 80 374 70,400 176,000 2,060 -- 11.7 281 SS-01 10/26/2004 145 20 132 36 0.2 ; 10 209 58,800 217,000 2,620 -- 397 SS-01 4/27/2005 < 10 10 20 105 11 0.2 :10 149 41,400 174,000 2,150 294 SS-01 10/20/2005 347 20 84 453 15 0.2 55 288 47,600 213,000 9,500 232 SS-01 10/19/2006 937 20 1,630 130 0.2 22 226 59,200 168,000 2,970 423 SS-01 4/27/2007 446 '10 20 1,240 18 0.2 188 27,400 128,000 31600 209 SS-01 11/19/2007 < 10 < 10 20 104 11 :10 117 61,500 243,000 3,540 371 SS-01 4/30/2008 170 - 20 242 21 - 238 56,300 171,000 2,690 260 SS-01 10/29/2008 56.4 0.3 1n 3 20.6 6 0.05 50.9 229 76,300 254,000 2,870 392 SS-01 4/30/2009 64.8 77.8 5.4 8.3 9.9 15.9 302 52,300 211,000 4,470 - -- 325 SS-01 8/26/2009 -- -- 72 -- 160 14 -- -- -- -- 45,000 -- -- 8.1 22 1,490 10 94 9.05 SS-01 10/12/2009 89 J 2.7 J 63 0.8 J 1.1 J 86 7.3 J 0084 < 2 A 0.12 370 49,000 240,000 -- 7.83 13.1 2,380 8.9 160 12.7 SS-01 4/19/2010 190 64 240 12 0.2 < 5 < �. 400 33,000 190,000 4,900 8.12 11.97 557 63.1 199 10.68 SS-01 10/11/2010 52 J 1.1 J 71 1.6 J 160 16 J ).20 5.0 36 640 40,000 240,000 -- 7.8 16.54 455 8 107 12.77 SS-01 4/20/2011 62 66 5.0 280 13 0.1 1.0 < ^' 300 30,000 140,000 3,400 7.59 17.98 270 4 211 9.71 SS-01 10/18/2011 153 76.7 '5 190 9.6 0.2 < 5 250 39,200 210,000 5,700 7.54 16.94 289 8.3 236 9.56 SS-01 3/16/2012 170 82.5 238 11 0.2 < 5 -0.2 1 37,400 1 221,000 4,800 7.8 15.73 359 2.46 -27 11.3 SS-01 9/24/2012 147 94.1 146 10.2 0.2 < 5 450 1 47,700 1 257,000 -- 7.71 15.68 589 21.3 153 8.65 APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 2 of 9 Anal to 7 E E Q y L Q L lC m = E 'O <6 U o L L U L CL Q. O U C O - N y J G1 y N C 0 L N 2 E c d d cn m i in V a N Z R R L �= z �; ,� `� 7 cn O dV O y G +�+ O =O s i O ram+ O H N 2 a Ul _ A N U d d d d d O E d E t� in 7 w U C O U V y Q N ? w o 7 E � - C N O C O 5 3 N O +_ x O J E C d � x O N o y N G NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE Sample Location Date SS-01 4/17/2013 366 73.5 492 12.4 141 29,000 131,000 4,410 8.03 20.89 297 4.9 76.3 6.87 SS-01 9/9/2013 179 87.1 <5 240 18.1 0 < 470 41,700 203,000 7,210 8.36 20.64 347 5.4 -173 9.4 SS-01 4/6/2014 62.2 1 <5 137 60.6 10 -- -- 70,000 224,000 4,100 7.93 9.59 381 5.1 142.2 11.65 SS-01 9/3/2014 0.122 0.0826 "010 < 0.0050 0.264 0.0647 0.0100 -- 93,400 339,000 -- 7.99 21.12 396 8.01 47.4 7.32 SS-01 4/1/2015 0.146 0.0722 )10 < 0.0050 0.291 0.0586 n ninn __ 69,100 216,000 7.75 17.09 552 3.1 39.6 9.74 SS-01 9/9/2015 7,600 0.19 )50 0.011 12,000 0.0062 J 0.66 93,000 280,000 B -- -- -- -- -- -- SS-01 3/8/2016 240 63 < 5.0 350 20 29,000 93,000 8.88 9.1 439.5 98.1 12.3 SS-01 9/7/2016 71 67 < 5.0 220 6.3 35,000 200,000 -- -- -- -- -- SS-01 9/7/2016 57 72 < 5.0 210 5.2 32,000 210,000 8.6 21.9 298 3.6 49 8.1 SS-01 3/27/2017 160 61 < 5.0 1,400 800 3.6 J 460,000 1,000,000 E 7.58 16.95 1.31 -- 68 10.6 SS-01 5/8/2017 590 B 57 < 5.0 660 6.8 23,000 150,000 -- -- -- -- -- -- SS-01 9/25/2017 130 B 84 < 5.0 250 8.6 40,000 240,000 8.03 20.21 322 3.33 61 8.23 SS-01 3/5/2018 55 69 < 5.0 140 9.2 38,000 190,000 8.06 11.11 289 3.2 186 10.28 SS-01 9/11/2018 150 84 < 5.0 470 22 36,000 1,200,000 8.07 21.8 380 6.07 101 5.84 SS-01 3/18/2019 230 51 u < 5.0 590 7.4 20,000 150,000 7.72 11.7 211.8 9.98 212.9 13.45 SS-01 9/4/2019 250 77 < 5.0 380 11 32,000 200,000 8.11 19.6 292.7 12.4 -28.6 6.39 SS-01 2/17/2020 3,100 64 < 5.0 3,400 1.2 26 23,000 150,000 7.79 10.38 219 34.9 216 9.58 SS-01 2/24/2020 1,200 63 < 5.0 1,600 16 25,000 170,000 8.64 7.74 233 16.2 192 10.95 SS-01 4/1/2020 490 59 < 5.0 690 8.6 26,000 150,000 8.53 11.7 224.9 34.2 49.5 8.58 SS-01+150 2/17/2020 2,700 61 <5.0 3,400 1.2 24 21,000 150,000 7.84 10.42 208 33.1 232 9.76 SS-01+150 2/24/2020 1,500 67 < 5.0 1,700 49 34,000 180,000 8.16 7.77 198 17.8 209 12.08 SS-01+550 2/17/2020 2,400 60 < 5.0 2,700 1.0 32 26,000 160,000 7.71 10.19 207 26.4 234 10.26 SS-01+550 2/24/2020 1,300 65 )U < 5.0 1,400 33 33,000 170,000 8.32 7.9 256 13.2 205 10.26 SS-01+850 2/17/2020 2,500 59 -5.0 2,700 36 29,000 160,000 7.69 10.01 221 25.2 243 9.42 SS-01+850 2/24/2020 1,100 66 5.0 1,300 27 33,000 180,000 8.18 7.94 249 13.9 207 12.28 SS-02 9/21/1990 130 94 4.6 20 100 -- 1,140 47,000 141,000 15,000 7.52 14.6 607 -- -- -- SS-02 10/23/1991 -- 170 20 820 1 711 80 1,020 490,000 806,000 10,000 7.82 18 1,280 SS-02 3/26/1992 7,650 2.1 20 8,070 12.9 130 250 13,100 149,000 12,000 6.04 11.5 111 SS-02 9/30/1992 330 < 10 20 -- - 7.3 :10 550 183,000 474,000 3,000 6.07 15.1 778 SS-02 3/31/1993 208 - 10 20 675 327 10 350 70,400 185,000 4,000 5.81 14.1 341 SS-02 9/17/1993 470 < 20 1,270 722 1 2,300 154,000 523,000 4,000 7.48 22.2 754 SS-02 3/30/1994 220 J < 2,1 32 1,120 117 165 320 40,000 143,000 -- 5.99 14.4 692 SS-02 9/30/1994 120 < 10 - 20 28 470 1 356 24 325 135,000 397,000 37,900 7.39 18.6 573 SS-02 3/31/1995 165 < 10 20 526 332 41 750 102,000 342,000 -- 7.87 14.5 496 SS-02 9/29/1995 406 1,020 6 598 1,030 155,000 505,000 2,680 5.6 13.5 1,095 SS-02 3/30/1996 426 i < 2,1 787 250 190 30,600 198,000 2,990 6.53 12 282 SS-02 9/27/1996 61 < 10 < 20 227 10 262 0.2 47 1 750 147,000 409,000 3,190 7.59 20 613 SS-02 3/29/1997 209 < 10 20 644 246 0.2 10 450 72,800 255,000 2,470 7.83 16 224 SS-02 9/17/1997 165 < 10 20 428 6 1 333 0.2 153 2,210 160,000 562,000 2,430 7.8 18 826 SS-02 3/27/1998 220 2,1 20 960 363 0.2 32 550 94,200 324,000 3,960 7.75 17.5 724 SS-02 9/30/1998 100 <2! 20 595 351 0.2 1,550 89,200 444,000 6,850 7.4 19 368 SS-02 3/31/1999 129 J 20 947 587 0.2 1,550 1 204,000 420,000 3,260 7.4 17 340 SS-02 9/29/1999 1,380 10 20 3,030 147 0.2 21 160 1 45,700 173,000 8,100 7.62 17 623 APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 3 of 9 Anal to 7 E E Q y L Q L lC m = E 'O <6 U o L L U L CL Q. O U C O - N y J G1 y N C 0 L N 2 E c d d cn m i in V a N Z R R L �= z �; ,� `� 7 cn O dV O y G +�+ O =O m i O ram+ O H N 2 a Ul _ A N U d d d d d O E d E t� in 7 w > U C O U V y Q N ? w o 7 E � - C N O C O 5 3 N O +_ x O J E C G7 � x O N o y N G NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE Sample Location Date SS-02 3/16/2000 960 464 1,180 175,000 500,000 3,750 -- -- -- -- SS-02 9/15/2000 283 < 10 < 2E 225 416 10 1,240 170,000 439,000 6,580 7.44 20 640 SS-02 3/23/2001 108 <2! 260 7 135 34 103 71,900 224,000 3,080 6.6 16 170 SS-02 10/4/2001 166 < 2,1 746 8 910 6,320 421,000 1,250,000 27,000 7.21 19 680 SS-02 3/28/2002 121 < 10 < ?f20 502 206 -- ; 10 1 320 127,000 405,000 2,970 7.39 11 510 SS-02 10/3/2002 220 < 10 20 494 549 0.2 :10 1,110 266,000 517,000 4,280 5.84 18 130 SS-02 3/25/2003 1,570 < 10 20 1,280 6 264 0.2 24 162 90,300 234,000 1,910 6.03 18 1,260 SS-02 (FD) 3/25/2003 1,750 '10 20 1,320 265 0.2 24 194 94,600 235,000 2,000 6.03 18 1,260 SS-02 10/2/2003 20 1 1,010 546 0.2 610 115,000 395,000 2,500 6.51 14 556 SS-02 4/28/2004 109 J 20 400 417 0.2 :10 608 220,000 394,000 2,260 -- 12.7 623 SS-02 10/26/2004 216 -10 20 839 582 0.2 ; 10 2,000 276,000 554,000 3,060 -- 807 SS-02 4/27/2005 20 356 272 0.2 ; 10 648 37,600 460,000 2,480 737 SS-02 10/20/2005 J 20 72 1,120 330 48 546 240,000 571,000 3,400 419 SS-02 10/19/2006 530 „) 20 1 1,060 534 32 299 204,000 422,000 3,490 550 SS-02 4/27/2007 389 < 20 811 488 333 439,000 303,000 4,420 511 SS-02 11/19/2007 .0 136 308 23 258 300,000 647,000 3,540 908 SS-02 4/30/2008 278 254 1 1 46 285 159,000 371,000 2,740 569 SS-02 10/29/2008 56.3 0.24 128 318 14.2 407 342,000 708,000 3,430 1,070 SS-02 4/30/2009 60.8 1 89.4 222 19.2 499 201,000 518,000 3,390 821 SS-02 8/26/2009 -- -- 71 110 220 - -- -- 310,000 -- -- 7.78 21.55 2,120 6.4 101 6.38 SS-02 10/12/2009 43 J 5.1 J 60 0.8 J 45 J 48 ^ 12 320 210,000 510,000 -- 7.8 13.29 3,360 8.7 123 12.95 SS-02 4/19/2010 64 '5 260 1 260 < U., 420 150,000 390,000 6,300 7.61 10.57 632 60.1 181 10.21 SS-02 10/11/2010 1.1 J 69 1.4 J 270 310 8.9 j 6.4 J 1,200 250,000 660,000 -- 7.62 15.24 999 -- 113 8.29 SS-02 4/20/2011 63 5.0 270 150 4.0 1.0 "" 630 120,000 360,000 3,000 7.55 18.62 602 1 4.2 241 9.7 SS-02 10/18/2011 74.9 '5 1 181 266 U.2 < 5 470 202,000 582,000 7,300 7.36 17.63 536 4.6 248 9.7 SS-02 3/16/2012 71.8 171 65.8 <5 1,600 152,000 614,000 6,300 7.55 15.36 781 3.4 14.5 11.52 SS-02 9/25/2012 97.6 236 301 < 5 1,600 400,000 858,000 -- 8.46 16.16 1,420 9.7 181 9.08 SS-02 4/17/2013 194 71.4 242 110 1 < 5 214 79,100 207,000 5,030 8.14 1 20.8 382 4.7 79.6 7.97 SS-02 9/10/2013 83 135 102 <5 1,160 167,000 493,000 6,290 8.03 19.79 657 8.2 99.8 7.11 SS-02 4/6/2014 133 56.4 < 5 194 21.2 0 -- -- 87,000 277,000 5,000 8.88 13.98 445 7.52 138.1 12.13 SS-02 9/3/2014 < 0.100 -- 0.0837 0.0010 < 0.0050 0.0686 < 0.0050 0.0111 0.0100 158,000 526,000 -- 8.14 23.42 733 2.45 61.3 5.09 SS-02 4/1/2015 < 0.100 -- 0.0590 0.0010 < 0.0050 0.0961 < 0.0050 0.0167 0.0100 -- 92,200 297,000 8.13 15.03 508 1.81 9.6 8.13 SS-02 9/8/2015 0.26 J 0.10 0.0011 J 0.45 < 0.010 0.070 160,000 460,000 -- -- -- -- -- -- SS-02 3/8/2016 150 65 5.0 260 " " 36 1.7 61,000 180,000 8.41 8.5 368.4 -- 227.1 11.32 SS-02 9/7/2016 150 81 5.0 490 44 86,000 300,000 8.5 21.8 452 4.6 89 8.4 SS-02 3/27/2017 65 74 5.0 210 11 68,000 250,000 B 7.2 16.14 403 1.8 169 9.62 SS-02 9/25/2017 86 B 88 5.0 200 43 88,000 310,000 7.95 19.7 458 1.18 183.9 8.41 SS-02 3/5/2018 37 J 69 5.0 160 27 92,000 300,000 7.99 9.93 457 4.6 179 11.75 SS-02 9/11/2018 83 5.0 250 52 89,000 320,000 7.86 22.1 533 4.8 110 5.12 SS-02 3/18/2019 150 47 5.0 530 23 34,000 170,000 6.89 10.7 249.7 7.68 175.3 12.34 SS-02 9/3/2019 150 80 5.0 240 30 60,000 250,000 7.43 22.6 375.8 8.62 -15.4 6.3 SS-02 2/17/2020 1,900 60 5.0 2,400 34 30,000 160,000 7.64 9.95 216 24.8 265 9.28 SS-02 2/24/2020 1,100 68 1 5.0 1,300 40 42,000 190,000 7.99 8.12 294 21.4 208 11.96 SS-02 4/1/2020 450 47 5.0 580 18 38,000 150,000 9.13 12.4 245.4 13.5 42.7 9.13 SS-02 (FD) 4/1/2020 400 46 5.0 600 18 38,000 160,000 -- -- -- -- -- APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 4 of 9 Anal to 7 E E Q y L Q L lC m = E 'O <6 U o L L U L CL Q. O U C O - N y J G1 y N C 0 L N 2 E c d d cn m i in V a N Z R R L �= z �; ,� `� 7 cn O dV O y G +�+ O =O s i O ram+ O H N 2 a Ul _ A N U d d d d d O E d E t� in 7 w U C O U V y Q N ? w o 7 E � - C N O C O 5 3 N O +_ x O J E C d � x O N o y N G NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE Sample Location Date SS-10 8/11/2009 -- -- 65 -- 12,000 400 -- -- -- 11,000 -- 7.13 20.63 1,890 42.9 -40 3.38 SS-15 8/11/2009 52 900 35 7,500 7.84 20.7 1,840 52.5 114 9.65 SS-20 8/11/2009 58 800 46 -- 8,200 -- 8.35 23.85 1,112 27.3 58 7.63 SS-20 4/21/2011 190 54 550 17 100 4,800 96,000 1,900 7.66 14.64 87 14.2 128 9.4 SS-20 9/24/2012 378 51.4 1,580 51.1 < 5 3,600 89,000 -- 7.3 15.55 146 10.3 159 8.55 SS-20 4/17/2013 788 56 1,050 19.8 < 5 5,590 55,000 2,760 7.53 19.76 283 7.2 158 8.7 SS-20 9/9/2013 456 60.3 1,170 48.4 < 5 1 274 3,610 78,000 2,280 7.37 21.69 97 9.7 24.2 8.37 SS-20 4/6/2014 126 54.2 <5 269 6 -- -- 5,200 68,000 1,900 8.05 9.56 212 14.4 134.7 10.32 SS-20 9/3/2014 0.818 0.0737 0.0010 < 0.0050 2,450 < 0.0714 0.0100 -- 3,600 97,000 -- 7.35 20.59 100 20.9 -12.5 5.33 SS-20 4/1/2015 2,320 0.105 0.0010 < 0.0050 4,840 < 0.vvvv 0.0991 0.0100 -- 5,000 66,000 7.72 14.85 103 7.26 7.2 7.59 SS-20 9/9/2015 4,700 0.13 0.0058 J 7,600 0.17 3,900 90,000 B -- -- -- -- -- -- SS-20 3/8/2016 470 53 5.0 450 8.9 4,300 65,000 7.91 12.1 73.5 -- 113.9 8.72 SS-20 9/7/2016 310 59 5.0 1,100 36 1,600 89,000 7.6 19.4 80 3.2 59 8.4 SS-20 3/27/2017 2,400 120 5.0 4,700 1.4 280 3,100 62,000 B 7.49 16.29 179 9.7 97.8 8.97 SS-20 9/25/2017 3,200 B 110 4.6 J 5,500 1.6 140 2,900 69,000 6.87 20.41 84 16.1 -22.3 6.04 SS-20 3/5/2018 120 57 5.0 420 23 4,100 80,000 7.62 10.77 74 7 201 9.63 SS-20 9/11/2018 370 67 5.0 1,600 85 3,300 75,000 7.56 21.3 116.5 24.3 70 5.11 SS-20 3/18/2019 550 54 5.0 680 8.1 - 4,300 84,000 7.48 10.5 70.3 13.2 219.4 8.86 SS-20 9/3/2019 3,700 110 5.0 5,300 2.0 130 -- 3,100 94,000 6.03 20.7 101.4 23.9 16.8 6.56 SS-20 2/17/2020 2,200 51 5.0 2,500 1.0 19 8,700 79,000 7.53 9,020 86 23 227 8.96 SS-20 2/24/2020 1,400 49 5.0 1,800 16 - 8,800 86,000 8.56 7.1 97 15.8 190 9.83 SS-20 4/1/2020 1,800 47 5.0 1,600 13 -- 9,300 76,000 6.59 11.8 88.1 23.4 73.1 9.41 SS-25 8/11/2009 -- 60 590 53 -- -- 28,000 -- 8.35 22.07 1,830 32.1 75 7.57 SS-25 4/21/2011 150 50 470 8.2 1.0 40 5,000 100,000 1,900 7.59 14.79 89 15.5 128 9.66 SS-25 9/24/2012 508 52.2 1,580 103 < 5 22 39,800 156,000 -- 7.19 15.94 257 13.6 145 8.44 SS-25 4/17/2013 820 54.9 1,170 32.6 < 5 5,810 62,000 2,940 7.49 19.64 336 6.8 163 8.9 SS-25 9/9/2013 345 54.3 809 23.8 60.9 3,650 82,000 2,590 7.39 20.34 134 5.9 23.7 8.26 SS-25 4/6/2014 310 51.1 555 13.8 -- -- 5,500 75,000 2,000 7.12 9.64 83 11.9 86.6 10.42 SS-25 9/3/2014 2,000 0.0833 ..,--- 3,880 0.0793 3,400 100,000 -- 7.41 21.37 92 32.1 -11.9 5.63 SS-25 4/1/2015 0.292 0.0534 0.0010 < 0.0050 0.649 < 0.0050 0.0106 5,200 74,000 7.14 14.95 89 9.45 16.3 5.93 SS-25 9/9/2015 0.66 0.063 " - ' 0.010 1,500 " -10 0.058 - 3,700 85,000 B -- -- -- -- -- -- -- SS-25 3/8/2016 1,700 92 5.0 2,500 1.8 90 4,700 83,000 8.29 12.8 72.9 -- 63 11.8 SS-25 9/7/2016 1,400 77 5.0 3,200 81 1,700 86,000 8 19.7 64 2.9 43 8.2 SS-25 3/27/2017 390 62 - - 590 9.4 3,100 73,000 B 7.55 16.72 121 7.4 101 8.02 SS-25 9/25/2017 780 B 56 1.6 J 1,200 0.29 J 27 2,500 74,000 7.13 19.99 1 88 11.5 15.3 6.9 SS-25 3/5/2018 210 47 400 15 4,200 78,000 7.77 11.44 78 13.5 191 8.84 SS-25 9/11/2018 270 53 5.0 1,100 32 2,600 88,000 7.19 21.4 122.7 18.3 82.8 5.04 SS-25 3/18/2019 610 51 5.0 700 5.5 4,400 69,000 7.84 10.3 70.3 14.4 226.5 8.44 SS-25 9/3/2019 1,700 70 5.0 2,700 45 3,200 100,000 6.2 21.2 99.8 60.12 8.9 6.02 SS-25 2/17/2020 2,800 55 5.0 3,600 1.5 1 25 8,500 81,000 7.5 9.62 79 33.5 251 8.82 SS-25 2/24/2020 1,300 46 5.0 1,500 < ^ 9.8 8,700 93,000 8.42 7.3 86 24.9 199 10.2 SS-25 4/1/2020 1,700 48 5.0 1,500 9.5 9,200 70,000 6.85 11.7 88.7 20.8 71 9.8 APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 5 of 9 Anal to 7 E E Q y L Q L lC m = E 'O <6 U o L L U L CL Q. O U C O - N y J G1 y N C 0 L N 2 E c d d cn m i in V a N Z R R L �= z �; ,� `� 7 cn O dV O y G +�+ O =O s i O ram+ O H N 2 a Ul _ A N U d d d d d O E d E t� in 7 w U C O U V y Q N ? w o 7 E � - C N O C O 5 3 N O +_ x O J E C d � x O N o y N G NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE Sample Location Date SS-30 8/11/2009 -- -- 72 -- 150 25 -- - -- -- 95,000 -- 8.53 22.82 5,250 21.7 57 8.1 SS-30 1/5/2011 -- 77 330 130 -- -- 63,000 370,000 -- 8.63 3.9 388 6.9 132 10.43 SS-30 4/20/2011 67 220 8.9 1.0 330 27,000 160,000 2,800 7.35 17.87 283 3.9 238 9.47 SS-30 9/24/2012 163 88 175 19.8 < 5 280 84,700 312,000 -- 7.76 15.38 567 14.9 152 8.77 SS-30 4/17/2013 352 76.4 455 13.2 < 5 194 31,000 144,000 18,200 7.82 21.06 268 8.7 62.1 6.24 SS-30 9/9/2013 158 86.2 237 18.6 498 45,600 220,000 4,990 8.06 20.44 318 4.59 17.9 7.13 SS-30 4/6/2014 '0 61.6 <5 159 -- -- 33,200 170,000 4,000 7.97 9.47 270 5.52 159.3 16.21 SS-30 9/3/2014 0.145 0.0843 1) 0010 < 0.0050 0.277 < 0.0050 0.0164 11 0100 -- 43,600 253,000 -- 8.41 21.41 308 11 16.6 6.96 SS-30 4/1/2015 0.173 0.0671 110 < 0.0050 0.291 < 0.0050 0.0112 100 -- 43,200 191,000 7.92 16.48 348 6.3 6.2 7.66 SS-30 9/9/2015 ..4 0.086 )50 < 0.010 0.11 < 0.010 0.0058 J 120 -- 98,000 280,000 B -- -- -- -- -- -- SS-30 3/8/2016 870 67 < 5.0 1,000 < " " 32 .0 -- 31,000 150,000 8.49 9.3 275 -- 164.2 12.04 SS-30 9/7/2016 470 70 < 5.0 970 44 < 1.0 -- 48,000 270,000 8.5 21.6 357 2.8 48 8.5 SS-30 3/27/2017 160 70 < 5.0 370 10 0 -- 41,000 200,000 B 7.76 16.05 343 2.8 114 10.33 SS-30 9/25/2017 200B 91 <5.0 360 11 .0 -- 41,000 220,000 7.89 20.88 335 3.76 66.3 7.84 SS-30 3/5/2018 66 64 < 5.0 180 9.8 < 5.0 -- 51,000 240,000 7.96 16.99 357 9.7 197 10.97 SS-30 9/11/2018 130 71 < 5.0 480 26 0 -- 52,000 260,000 8.1 21.3 442 10.2 106 6.1 SS-30 3/18/2019 360 54 < 5.0 880 19 .0 -- 24,000 150,000 7.89 11.5 238.7 13 216.7 10.14 SS-30 9/4/2019 350 86 < 5.0 570 14 < 5.0 -- 34,000 220,000 7.99 19.5 301.4 14.4 -28.6 6.39 SS-30 2/17/2020 3,200 64 < 5.0 3,600 1.5 1 62 0 -- 27,000 200,000 7.59 10.08 240 9.65 259 9.85 SS-30 2/24/2020 1,800 66 < 5.0 2,500 65 .0 -- 32,000 210,000 8.45 7.58 269 24.2 202 10.23 SS-30 4/1/2020 1,300 59 < 5.0 1,800 18 -5.0 -- 31,000 160,000 7.36 11.8 261.9 24.1 63.3 10.12 SS-35 9/8/2015 0.10 < 0.010 0.072 J 0.028 J20 -- 170,000 470,000 -- -- -- -- -- -- SS-40 8/26/2009 -- 91 < 5 80 22 0 -- 300,000 -- 7.82 21.33 2,050 7.1 89 7.89 SS-40 4/20/2011 57 59 < 5.0 330 59 0.25 2.1 < 1.0 810 110,000 270,000 2,900 7.3 17.54 494 4.6 223 10.23 SS-40 9/25/2012 112 < 5 139 39 0 < 5 2,000 297,000 755,000 -- 8 14.75 1,260 9.8 174 9.28 SS-40 4/17/2013 221 60.7 < 5 294 25.7 0 < 179 73,200 195,000 4,980 8.23 19.9 329 4.9 68.9 6.94 SS-40 9/10/2013 89.6 <5 92.5 15.5 0 20.4 1,440 165,000 450,000 6,230 7.92 19.75 610 5.7 87.8 8.43 SS-40 4/6/2014 53.2 <5 185 11.5 0 -- -- 81,600 256,000 16,200 9.18 13.95 397 8.31 138.7 11.39 SS-40 9/3/2014 < 0.100 0.0865 0.0010 < 0.0050 0.0581 < 0.0050 0.0095 0.0100 152,000 473,000 -- 8.06 23.72 689 2.45 69.4 4.91 SS-40 4/1/2015 < 0.100 - 0.0585 0.0010 < 0.0050 0.154 < 0.0050 0.0108 0.0100 -- 84,200 264,000 8.01 18.32 469 4.19 13.5 8.25 SS-40 9/8/2015 0.21 J 0.11 1010 0.37 < 0.010 0.048 160,000 440,000 -- -- -- - -- -- SS-40 3/8/2016 220 62 5.0 310 " " 12 57,000 180,000 8.41 8.9 332.7 -- 238.2 13.44 SS-40 9/7/2016 540 94 5.0 1,300 100 78,000 290,000 8.2 21 427 3.2 121 7.7 SS-40 3/27/2017 91 67 5.0 240 7.9 65,000 230,000 B 7.98 16.88 357 1.8 154 111.1 SS-40 9/25/2017 100 B 85 5.0 210 17 80,000 280,000 8.07 19.85 425 3.24 121 8.57 SS-40 3/5/2018 45 64 5.0 130 5.8 84,000 290,000 8.19 9.79 417 2.6 190 11.82 SS-40 9/11/2018 79 5.0 210 14 78,000 300,000 7.73 22 498 5.03 99.5 4.91 SS-40 3/18/2019 160 47 5.0 480 9.3 32,000 150,000 7.44 10.4 230.8 7.92 175.8 12.25 SS-40 9/3/2019 75 77 5.0 190 10 51,000 230,000 7.04 21.9 336.2 4.27 -1.4 5.58 SS-40 2/17/2020 2,600 60 5.0 3,000 1.0 29 27,000 150,000 7.67 8.96 200 11.13 248 11.18 SS-40 2/24/2020 1,200 66 5.0 1,300 17 37,000 190,000 7.85 7.52 268 10.3 207 13.79 SS-40 4/1/20201 280 48 1 400 1 9.0 24,000 110,000 8.65 1 11.9 192.4 10.9 29.2 9.97 APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 6 of 9 Anal to 7 E E Q y L Q L lC m = E 'O <6 U o L L U L CL Q. O U C O - N y J G1 y N C 0 L N 2 E c d d cn m i in V a N Z R R L �= z �; ,� `� 7 cn O dV O y G +�+ O =O s i O ram+ O H N 2 a Ul _ A N U d d d d d O E d E t� in 7 w U C O U V y Q N ? w o 7 E � - C N O C O 5 3 N O +_ x O J E C d � x O N o y N G NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE Sample Location Date SS-50 8/11/2009 -- -- 29 -- 2,900 180 -- -- -- -- 5,600 -- -- 7.79 25.4 1,180 32 -21 8.52 SS-50 4/21/2011 120 36 1,100 85 1.0 130 3,700 71,000 2,000 6.91 14.66 85 16.3 92 9.88 SS-50 9/25/2012 410 41.9 1,640 110 140 72,000 -- 8.65 17.58 161 9.6 16 8.76 SS-50 4/17/2013 - SS-50 9/9/2013 SS-50 4/6/2014 -- SS-50 9/3/2014 -- SS-50 4/1/2015 0.886 0.0494 4,620 0.168 - 2,900 63,000 7 13.5 90 18.8 -6.3 13.7 SS-50 9/9/2015 160,000 2,900 0.0016 J 0.25 850,000 0.10 16,000 -- 0.64 J 75,000 B -- -- -- -- -- -- SS-50 3/8/2016 930 46 < 5.0 1,700 46 -- -- -- 7.89 12.5 71.9 -- 111.8 9.84 SS-50 9/7/2016 410 49 < 5.0 2,900 180 -- 99,000 8 22.8 121 3.6 50 6.9 SS-50 3/27/2017 230 46 < 5.0 650 13 -- 1,600 130,000 6.46 18.32 9 47.4 195 11.54 SS-50 9/25/2017 960 B 52 2.1 J 2,200 0.56 J 93 -- 1,300 23,000 6.86 20.27 84 1 14.7 13.2 7.71 SS-50 3/5/2018 86 40 i0 < 5.0 530 22 -- 2,900 68,000 7.38 1 11.41 74 14.8 213 11.87 SS-50 9/11/2018 -- -- - -- -- -- -- -- -- -- -- -- -- -- -- -- SS-50 3/18/2019 240 40 < 5.0 740 25 -- 3,700 72,000 7.45 9.7 73 11.8 145.8 8.69 SS-50 9/3/2019 1,400 54 < 5.0 3,000 93 -- 1,400 78,000 5.22 22 104.2 24.8 6.8 6.85 SS-50 4/1/2020 660 47 < 5.0 2,300 96 -- 2,800 74,000 7.6 12.4 74.3 31.5 22.1 9.81 SS-60 8/26/2009 -- 140 < 5 280 980 -- -- 350,000 -- 7.06 20.34 4,040 65.9 10 6.69 SS-60 4/21/2011 68 61 < 5.0 240 11 4.1 1.0 120 130,000 270,000 2,700 7.15 15.9 446 14.3 177 8.89 SS-60 9/25/2012 120 75.9 < 5 312 85 < 5 58,100 191,000 -- 8.43 12.53 337 11.7 179 8.75 SS-60 4/17/2013 534 63.4 < 5 667 43.8 0.2 < 5 164,000 274,000 4,170 7.8 20.15 380 8.6 70.6 10.79 SS-60 9/10/2013 103 120 < 5 116 75.5 0.2 2,120 275,000 663,000 6,150 7.47 20.97 423 8.4 87.6 8.17 SS-60 4/6/2014 154 64.9 <5 175 5.7 -- < iv -- 119,000 234,000 3,300 7.59 13.63 421 5.94 186.4 12.81 SS-60 9/4/2014 0.127 )10 < 0.0050 0.709 0.537 0.0168 290,000 717,000 -- 7.13 20.84 845 7.26 -3.4 4.53 SS-60 4/1/2015 1,320 0.0930 J10 < 0.0050 2,140 < 0.0695 159,000 359,000 7.07 9.72 538 18.8 1.56 6.6 SS-60 9/8/2015 0.19 J 0.057 ri nnrn < 0.010 0.41 < 0.033 13,000 110,000 -- -- -- -- -- -- SS-60 3/8/2016 510 68 5.0 410 8.6 3.0 120,000 270,000 7.83 9.3 375.2 -- 252.1 10.62 SS-60 9/7/2016 780 130 2,400 160 250,000 490,000 7.5 20.1 666 4.7 39 6.5 SS-60 3/27/2017 4,500 160 5.5 7,800 2.7 190 1.5 J 190,000 410,000 B 7.08 14.69 4 297 194 7.03 SS-60 9/25/2017 34 BJ 130 .,.., 260 89 270,000 570,000 7.31 18.92 763 1.16 54 3.31 SS-60 3/5/2018 140 93 5.0 280 19 170,000 370,000 7.13 10.08 522 44.7 156 12.41 SS-60 9/11/2018 120 5.0 810 330 240,000 620,000 7.33 21.5 916 4.97 76.3 2.06 SS-60 3/18/2019 560 41 5.0 750 7.9 13,000 78,000 7.19 11.2 90.7 12.6 213 1 12.51 SS-60 4/1/2020 650 54 5.0 690 7.3 62,000 160,000 7.4 11.4 231.7 13.7 78.9 7.91 SS-65 9/8/2015 0.78 0.080 0.0013 J 1,300 0.096 44,000 150,000 -- -- -- -- -- -- SS-70 8/26/2009 -- 120 1,100 250 65,000 -- 6.94 20.55 2,520 6.8 91 6.44 SS-70 4/21/2011 160 50 380 5.8 0.12 1.0 53 23,000 92,000 2,300 6.99 16.39 138 8.3 189 1 10.27 SS-70 9/25/2012 120 82.4 303 58.7 <5 1 61,300 203,000 -- 8.15 12.58 367 10.1 143 8.34 SS-70 4/17/2013 694 51.3 1 986 13.4 1 0.2 1 1 24,100 89,000 3,330 7.98 19.28 129 7.3 60.9 7.67 SS-70 9/10/20131 135 58.8 1 299 13.6 1 0.2 1 1 1,390 1 28,600 1 123,000 3,510 1 7.89 20.87 419 1 7.6 85.3 1 8.07 APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 7 of 9 Anal to 7 E E Q y L Q L lC m = E 'O <6 U o L L v L CL Q. O U C O - N y J G1 y N C 0 L N 2 E c d d cn m i in V a N Z R R L �= z �; ,� `� 7 (n O dV O y G +�+ O =O s i O ram+ O t- N 2 a Ul _ A N U d d d d d O E d E t� in 7 w U C O U V y Q U) ? w o 7 E � - C N O C O 5 3 N O +_ x O J E C d � x O N o y N G NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE Sample Location Date SS-70 4/6/2014 374 -- 47.7 -- 479 5.3 -- -- -- -- 21,000 86,000 2,300 7.5 13.28 125 8.3 165 9.85 SS-70 9/4/2014 0.0799 0.0010 < 0.0050 0.305 < 0.0050 0.0711 0.0100 35,000 146,000 -- 7.7 21.04 217 3.68 22.3 7.26 SS-70 4/1/2015 0.147 0.0551 0.0010 < 0.0050 0.282 < 0.0050 0.0084 100 -- 27,300 93,000 7.36 11.13 159 1.56 5.01 8.21 SS-70 9/8/2015 0.095 J 0.071 0.010 0.26 < 0.027 )20 -- 33,000 160,000 -- -- -- -- -- -- SS-70 3/8/2016 640 47 5.0 540 5.7 < 1.0 -- 18,000 90,000 8.17 10 112.5 -- 244.2 11.35 SS-70 9/7/2016 160 52 5.0 470 18 0 1,600 81,000 7.5 19.9 93 5.3 26 7.6 SS-70 3/27/2017 170 56 270 4.2 J .0 21,000 93,000 B 7.5 16.52 722 6.2 170 7.92 SS-70 9/25/2017 350 B 62 1.3 J 530 28 < 5.0 11,000 74,000 7.53 19.21 122 7.69 158.8 7.14 SS-70 3/5/2018 78 44 150 7.2 0 20,000 91,000 7.32 10.96 120 1.4 197 7.9 SS-70 9/11/2018 86 60 5.0 480 31 ..0 8,000 97,000 7.67 21.4 152 4.94 111 5.3 SS-70 3/18/2019 360 45 5.0 500 5.7 14,000 83,000 7.5 11 96 10.2 209.7 10.53 SS-70 9/3/2019 91 55 5.0 410 27 16,000 110,000 6.72 22 137.7 4.27 2.3 5.14 SS-70 4/1/2020 630 43 5.0 840 14 12,000 77,000 7.21 11.9 86.7 14.4 62.9 9.74 SS-75 9/8/2015 0.078 1.010 0.23 0.026 0.0099 J 41,000 170,000 -- -- -- -- -- -- SS-80 8/26/2009 -- 120 '5 250 25 82,000 -- 7.13 20.63 5,190 5.8 100 8.34 SS-80 4/21/2011 110 56 5.0 310 0.1 < 1.0 99 27,000 120,000 2,100 6.8 15.52 161 6.8 92 10.61 SS-80 9/25/2012 192 87 '5 263 15.9 0.2 < < 5 74,600 270,000 -- 8.53 11.69 399 4.8 205 9.08 SS-80 4/17/2013 643 52.5 -5 921 7.5 0.2 < 10 < 5 27,600 88,000 3,170 7.43 20.14 139 7.6 70.8 7.14 SS-80 9/10/2013 110 71.5 '5 211 8.3 ^ ^ ' �^ ' ` 265 47,600 152,000 3,430 7.67 21.64 417 6.9 87.9 7.92 SS-80 4/6/2014 180 53.7 < 5 328 17,500 84,000 2,400 7.39 13.87 106 8.7 136.2 11.78 SS-80 9/4/2014 0.149 0.0811 110 < 0.0050 0.436 < 0.0050 0.0168 30,100 155,000 -- 8.09 21.23 245 11.3 17.5 6.98 SS-80 4/1/2015 0.246 0.0581 J10 < 0.0050 0.382 < 0.0050 0.0071 25,500 89,000 7.88 12.8 162 4.37 4.37 9.57 SS-80 9/8/2015 0.084 u.0050 < 0.010 0.18 < 0.010 0.014 J 41,000 170,000 -- -- -- -- -- -- SS-80 3/8/2016 640 54 5.0 530 6.4 24,000 110,000 8.45 8.8 124.3 -- 236.8 11.32 SS-80 9/7/2016 140 63 5.0 430 9.7 13,000 110,000 7.7 21 98 2.7 53 8.2 SS-80 3/27/2017 100 62 5.0 200 2.5 J 21,000 110,000 B 7.97 16.04 156 1.7 165 8.96 SS-80 9/25/2017 98 B 71 5.0 250 6.8 21,000 110,000 7.68 18.95 158 2.97 146.5 8.89 SS-80 3/5/2018 74 51 5.0 190 10 21,000 96,000 7.57 10.92 127 0.9 185 15.18 SS-80 9/11/2018 490 73 5.0 1,200 34 16,000 110,000 8.19 21 191 5.55 109 5.72 SS-80 3/18/2019 400 45 5.0 560 13,000 90,000 7.64 9.9 96.8 9.89 196.2 9.74 SS-80 9/3/2019 240 67 5.0 500 9.9 13,000 130,000 6.65 21.7 142.6 6.32 8.1 5.64 SS-80 4/1/2020 510 50 5.0 680 5.8 10,000 76,000 7.24 11.7 87.3 13.3 83.4 10.86 SS-90 1/4/2011 -- 44 1,200 16 26,000 97,000 8.42 3 390 4.2 152 10.55 SS-90 1/4/2011 -- 44 1,200 16 26,000 97,000 8.42 3 390 4.2 152 10.55 SS-90 4/20/2011 83 57 330 21 2.1 u 330 56,000 130,000 2,600 6.69 16.92 292 4.6 293 11.68 SS-90 9/25/2012 121 115 212 30.4 980 202,000 511,000 -- 8.14 11.93 840 12.1 207 8.96 SS-90 4/17/2013 491 56 709 17.4 34.9 38,900 127,000 3,690 7.94 19.71 203 6.9 66 7.59 SS-90 9/10/2013 148 86.6 '5 265 32.4 642 121,000 1 283,000 4,920 7.86 22.19 429 7.9 91.6 7.26 SS-90 4/6/2014 154 48.5 < 5 274 9.4 -- -- 45,300 151,000 3,300 8.87 1 15.09 255 5.62 120.9 15.44 SS-90 9/3/2014 < 0.11 0.0908 0.0010 < 0.0050 0.0775 < 0.0050 0.0160 - 94,500 357,000 -- 7.48 1 23.51 518 5.56 65.3 6.43 SS-90 4/1/2015 0.125 0.0580 ^ - ' ^ ^^`^ 0.189 < 0.0050 0.0090 - 51,400 166,000 8.81 11.35 318 5.95 5.95 9.92 SS-90 9/8/2015 0.29 J 0.10 0.0010 J 0.53 < 0.010 0.080 -- 110,000 340,000 -- -- -- I -- -- SS-90 3/8/2016 390 58 470 < 1.0 11 -- 33,000 110,000 8.35 8.5 210.3 1 -- 239.3 13.08 APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 8 of 9 Anal to 7 E E Q y L Q L lC m = E 'O <6 U o L L U L CL Q. O U C O - N y J G1 y N C 0 L N 2 E c d d cn m i in V a N Z R R L �= z �; ,� `� 7 cn O dV O y G +�+ O =O m i O ram+ O H N 2 a Ul _ A N U d d d d d O E d E t� in 7 w > U C O U V y Q N ? w o 7 E � - C N O C O 5 3 N O +_ x O J E C G7 � x O N o y N G NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE Sample Location Date SS-90 9/7/2016 40 -- 73 -- 230 17 -- -- -- 49,000 200,000 8 20.8 2,886 1.8 48 9 SS-90 3/27/2017 160 62 5.0 340 12 40,000 100,000 B 8.2 16.52 256 1.9 152 11.09 SS-90 9/25/2017 72 B 79 5.0 160 10 48,000 200,000 7.88 19.1 284 1.47 153.2 8.7 SS-90 3/5/2018 51 54 5.0 120 5.8 48,000 170,000 7.78 9.59 262 2.2 192 10.09 SS-90 9/11/2018 54 72 5.0 280 15 46,000 210,000 8.66 21.2 387 4.95 114 6.8 SS-90 3/18/2019 140 45 5.0 340 7.4 20,000 110,000 7.54 9.8 150.9 8.02 170.9 12.29 SS-90 9/3/2019 71 69 5.0 230 8.2 31,000 160,000 6.59 22.2 229.1 12.9 12.9 6.44 SS-90 2/17/2020 1,900 49 5.0 1,900 1 11 17,000 120,000 7.52 8.37 129 12.8 234 11.43 SS-90 2/24/2020 780 52 5.0 850 8.6 22,000 130,000 8.1 7.44 162 5.3 198 16.19 SS-90 4/1/2020 200 47 5.0 300 8.3 22,000 110,000 8.68 11.3 154.5 10.7 59.2 12.61 SS-95 2/17/2020 360 62 5.0 660 330 94,000 270,000 7.34 9.51 378 8.2 165 8.55 SS-95 2/24/2020 140 66 5.0 650 540 5.1 -- -- 160,000 390,000 8.08 7.51 599 18.5 200 10.12 MW-001 9/30/1994 2,580 16 20 44 23,200 6,490 35 2,950 787,000 2,230,000 1 258,000 7.39 22.5 3,140 -- -- -- MW-001 3/31/1995 660 1 5,150 2,360 155 8,880 794,000 2,540,000 459,000 7.8 17.5 3,680 MW-001 9/29/1995 156 < 10 5,240 8 4,880 1,030 801,000 2,660,000 4,950 5.41 14.8 4,220 MW-001 3/30/1996 112 < 10 2 20 5,020 5,400 0.2 2,080 -- 2,340,000 6,650 7.18 15 3,050 MW-001 9/27/1996 167 < 10 20 -- 9 4,530 1 0.2 1 66 1,700 1,010,000 2,700,000 4,040 7.32 23 1,510 MW-001 3/17/1997 164 < 10 20 3,660 5,400 0.2 1 55 608 1,160,000 3,000,000 6,430 7.2 22 3,660 MW-001 3/29/1997 97 ' 10 20 6,180 5,460 0.2 10 1,290 1,050,000 2,460,000 4,310 7.5 22 1,770 MW-001 3/27/1998 10 1 20 11,400 5,900 0.2 21 290 942,000 2,780,000 4,430 7.19 23.4 1,419 MW-001 9/30/1998 274 J 20 -- 4,940 0.2 -- 666,000 2,700,000 15,400 7.6 20 1,200 MW-001 3/31/1999 - < 10 20 7,550 6 4,450 0.2 600 1,560,000 2,930,000 7,920 7.3 18 1,021 MW-001 9/29/1999 877 < 10 20 6,770 862 0.2 80 3,360 330,000 715,000 13,300 7.08 18 2,930 MW-001 3/16/2000 410 20 72,000 4,540 1,090 948,000 2,610,000 10,600 -- -- -- MW-001 9/15/2000 20 2,020 3,480 ; 10 6,270 894,000 2,470,000 5,210 6.57 19 980 MW-001 3/23/2001 144 < 10 < 21 4 20 35,900 12 4,070 = 10 480 926,000 2,630,000 5,850 6.5 17 480 MW-001 (FD) 3/23/2001 < 10 < 2! 20 6,900 7 4,190 350 939,000 2,640,000 7,520 6.5 17 480 MW-001 10/4/2001 204 20 915 7 229 )5 186,000 7,800 6.28 20 300 MW-001 3/28/2002 20 5,100 3,660 -- ; 10 280 1,000,000 3,010,000 3,770 6.44 12 1,080 MW-001 10/3/2002 10 2 20 27 1,520 3,340 0.2 :10 1 1,820 1,030,000 2,940,000 4,940 6.67 18 370 MW-001 (FD) 10/3/2002 2 20 24 1,580 3,330 0.2 ; 10 1,780 1,040,000 2,860,000 5,120 5.67 18 370 MW-001 3/25/2003 20 6,690 6 3,560 0.2 10 25 406 846,000 2,530,000 3,720 6.62 17 330 MW-001 10/2/2003 10 20 11,300 7 3,880 0.2 42 174 916,000 2,710,000 3,920 5.59 15 3,050 MW-001 (FD) 10/2/2003 l 20 11,400 1 6 3,880 958,000 2,690,000 3,900 5.59 15 3,170 MW-001 4/28/2004 < 2! 20 11,100 6 6,080 ; 10 1,460,000 2,550,000 5,360 -- 17.3 2,860 MW-001 10/26/2004 < 10 < 2! 20 5,250 4,550 :10 1 287 1,190,000 2,950,000 3,640 -- 3,480 MW-001 4/27/2005 2 7,630 7 5,730 ; 10 1,100,000 2,550,000 4,710 2,870 MW-001 10/20/2005 1,630 i 4 28 103,000 6 4,880 57 428 403,000 3,010,000 89,000 529 MW-001 10/19/2006 172 e 10 2 20 1 347 27,400 3,600 0.2 27 139 1,320,000 2,850,000 4,370 2,000 MW-001 4/27/2007 20 5,360 2,380 0.2 287 1,380,000 2,750,000 4,010 ,830 MW-001 11/19/2007 42 2 20 48,200 3,280 0.2 25 < 50 1,560,000 3,060,000 3,820 ,300 MW-001 4/30/2008 ''^ 20 9,680 2,990 0.2 22 155 1,100,000 2,910,000 3,380 r4,880 MW-001 10/29/2008 68.7 10 4,840 3.5 2,880 0.2 < 188,000 3,060,000 3,510 ,200 MW-001 4/30/2009 77.4 1.8 10 3.6 4,080 4.4 3,100 0.2 264 37,700 2,904,000 3,940 ,070 APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 9 of 9 E Ul _ E � - A N t� in C N J =O U d 7 w O C E O s d > O 5 C d U 3 G7 � G1 Z dV O d C O ? N x O 7 = L y N E R y i U w O N E E E 'O o CL 0 c d m V R �; ,� `� G O N d O V o +_ o y Anal to Q y L Q L lC m <6 U L L U Q. O U C O - N y J C L N 2 d rn i in a N L �= Z 7 cn +�+ O H ram+ O H 2 a E d H y Q rn 7 H x O N G NC 213 Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE Sample Location Date MW-003 9/30/1994 1,770 113 3,370 2,200 96 200 159,000 415,000 20,100 6.89 19.6 519 -- MW-003 3/31/1995 -- 4,860 5,980 32 100 294,000 625,000 -- 7.56 13.6 896 - MW-003 9/29/1995 1,640 3,420 7 2,940 104 463 314,000 740,000 3,740 4.89 14 1,040 - MW-003 3/30/1996 11,400 2 1 23,300 9 3,160 126 130 222,000 552,000 3,830 7.18 12 750 - MW-003 9/27/1996 110 1,010 7 2,360 30 1 160 283,000 737,000 6,730 7.6 20 974 -- MW-003 3/29/1997 238 1,930 3,050 13 20 180 809,000 807,000 4,170 7.76 16 590 - MW-003 9/17/1997 169 715 5 3,060 6 212 330 562,000 1,290,000 5,290 7.7 19 1,650 - MW-003 3/27/1998 270 2,500 3,370 13 41 250 -- 929,000 6,980 7.2 20 1,214 - - MW-003 9/30/1998 353 1,380 -- 17 780 367,000 1,280,000 10,100 6.9 19 920 - - MW-003 3/31/1999 4,830 5,550 190 482,000 842,000 7,580 7.1 16 592 - - - MW-003 9/29/1999 677 1,940 894 1 100 258,000 413,000 8,140 7.65 19 741 -- - -- MW-003 9/15/2000 224 2,380 2,800 160 550,000 1,260,000 8,580 7.06 21 680 - - - MW-003 3/23/2001 3,690 10 2,250 30 230 530,000 1,230,000 5,720 6.6 17 640 - - - MW-003 10/4/2001 4,240 6 3,650 80 592,000 1,440,000 30,000 7 1 20 600 - - - MW-003 3/28/2002 5,620 2,180 110 682,000 1,590,000 5,360 6.37 13 680 - - - MW-003 10/3/2002 2 1 6,510 5,290 932,000 1,900,000 8,510 6.22 19 150 - - - MW-003 3/25/2003 3,280 6,170 8 4,290 78 1 88 784,000 1,520,000 1,340 6.36 18 110 - - - MW-003 10/2/2003 634 1 5,950 8 6,750 50 174 765,000 1 1,420,000 3,970 6.12 14 1,460 - - - MW-003 4/28/2004 152 8,370 6,720 224 1,040,000 1,810,000 3,890 1 -- 12.1 2,030 - - - MW-003 10/26/2004 554 5 16,300 4,220 36 289 1,070,000 2,140,000 5,160 - -- 2,150 - - - MW-003 4/27/2005 2 4,470 6,110 246 1,075,000 2,090,000 4,050 - - 2,320 - - - MW-003 10/20/2005 5 27 7,900 5,870 44 279 1,300,000 2,090,000 30,000 - - 1,060 - - - MW-003 10/19/2006 1,460 6,040 4,550 21 281 1,170,000 1,920,000 4,200 - - 1,370 - - - MW-003 4/27/2007 8,330 4,190 290 1,130,000 2,130,000 3,830 - - 2,230 - - - MW-003 11/19/2007 8,200 6,000 64 1,680,000 2,550,000 4,590 - - 2,710 - - - MW-003 4/30/2008 3,360 1 1 3,800 37 297 2,090,000 2,110,000 3,560 - - 2,290 - - - MW-003 10/29/2008 59.3 2,880 2.3 4,360 171 988,000 2,360,000 3,480 - - 2,740 - -- - MW-003 4/30/2009 53.2 1 1 4,620 7.2 4,960 14.6 1 337 1 261,000 2,460,000 4,110 - 2,930 - -- I- Notes: All concentrations in micrograms per liter (ug/L) unless otherwise noted NE - Not established -- - Not sampled B - Detected in the method blank J - Estimated result < LOQ and > DL Bold with gray background indicates exceedance of NC Surface Water Standard Analysis for arsenic, copper, mercury, silver, zinc, nitrates & TOC discontinued in 2014 per Corrective Action Plan (ERM, 2/2014). NSA - Location inaccessible; no sample collected NSB - Obstruction in well; no sample collected NSC - Well dry; no sample collected NSD - Insufficient volume; no sample collected NSE - Well damaged; no sample collected NSF - Pump broken; no sample collected NSG - Surface water location dry; no sample collected APPENDIX A3 QA/QC ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 1 of 2 Analto Y 7E C E a _ = a� a 7 _ m m 3 _ E f6 c� £ o c� � o c� o m -j N N m Z a) Z £ cn in N Z f6 CD z �; cn N6 - o CD > y y o F- = o � m U u = l6 O F- Groundwater Standard 3.5 0.01 0.7 0.002 0.01 1 0.3 0.015 0.05 0.001 0.02 0.02 1 10 250 500 NE Date Field Blank 9/30/1998 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 1 3/31/1999 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.19 < 5 < 5 2.18 9/15/2000 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 1 3/23/2001 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 0.006 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 14 < 1 10/4/2001 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 0.006 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.3 < 5 15 < 2 3/28/2002 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 -- < 0.01 < 0.01 < 0.02 < 0.05 < 5 14 < 1 10/3/2002 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 6 < 1 3/25/2003 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.198 < 5 < 5 < 1 10/2/2003 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 1 4/28/2004 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 6 < 1 10/26/2004 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.151 < 5 10 2.18 4/27/2005 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 12 1.79 10/20/2005 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.101 < 5 < 5 < 0.5 10/19/2006 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 0.5 4/27/2007 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 0.5 11/19/2007 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 0.5 4/30/2008 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.336 < 5 < 5 < 0.5 10/29/2008 < 0.1 < 0.01 0.0031 < 0.001 < 0.01 < 0.01 < 0.05 < 0.01 < 0.01 0.00002 < 0.01 0.0022 0.01 < 0.05 < 10 < 5 < 0.5 4/30/2009 < 0.1 1 < 0.01 1 0.0077 1 < 0.001 1 < 0.01 1 < 0.01 1 < 0.05 1 0.0045 1 0.008 1 < 0.0002 1 < 0.01 1 < 0.01 < 0.01 < 0.05 < 10 90 < 0.5 Trip Blank 9/30/1998 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 1 3/31/1999 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.22 < 5 15 < 1 9/15/2000 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 1 3/23/2001 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 14 1.03 10/4/2001 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.4 < 5 12 2 3/28/2002 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 -- < 0.01 < 0.01 < 0.02 < 0.05 < 5 14 1.03 10/3/2002 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 0.5 3/25/2003 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.197 < 5 7 < 1 10/2/2003 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 7 < 1 4/28/2004 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 16 < 1 10/26/2004 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 8 1.29 4/27/2005 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 14 1.76 10/20/2005 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 6 < 0.5 APPENDIX A3 QA/QC ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 2 of 2 N6 = - o o � M m U > u d Z o N E C V _7 E _ 3 7 M �; o O E _ a� _ E o a = .. _ _ Analto Y a a M m f6 c� c� o c� o CDs -j M Z a) Z Cn in nl z Cn Groundwater Standard 3.5 0.01 0.7 0.002 0.01 1 0.3 0.015 0.05 0.001 0.02 0.02 1 10 250 500 NE Date 10/19/2006 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 0.5 4/27/2007 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 0.5 11 /19/2007 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 0.5 4/30/2008 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 0.5 10/29/2008 < 0.1 < 0.01 0.0046 < 0.001 < 0.01 < 0.01 < 0.05 < 0.01 < 0.01 0.00001 < 0.01 < 0.01 < 0.01 < 0.05 < 10 < 5 < 0.5 4/30/2009 < 0.1 < 0.01 0.0086 0.0003 < 0.01 < 0.01 < 0.05 < 0.01 0.0071 < 0.0002 < 0.01 < 0.01 < 0.01 < 0.05 < 10 85 < 0.5 9/8/2016 < 0.1 1 < 0.01 0.0086 0.0003 < 0.01 < 0.01 < 0.05 < 0.01 1 0.0071 < 0.0002 < 0.01 < 0.01 < 0.01 < 0.05 < 10 85 < 0.5 Notes: All concentrations in milligrams per liter (mg/L) unless otherwise noted NE - Not established -- - Not sampled Bold with gray background indicates exceedance of NC Groundwater Standard Analysis for arsenic, copper, mercury, silver, zinc, nitrates & TOC discontinued in 2014 per Corrective Action Plan (ERM, 2/2014). APPENDIX B LABORATORY DATA SHEETS www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. July 2020 2020-04 Edwards Rd LF Rural Hall GW Report.docx (��a'neAnalyfical Report of Analysis ERM INC, Inc. 300 West Summit Avenue Suite 330 Charlotte, NC 28203 Attention: Alan Martin Project Name: RJRT Project Number: 0502068 Lot Number:VD04003 Date Completed:04/15/2020 Revision Date: 06/25/2020 J . i 06/25/2020 10:22 AM Approved and released by: Project Manager: Kelly M. Nance .rc o a�Er�,w�uw,w�w The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel: 803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 92 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative ERM NC, Inc. Lot Number: VD04003 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Pace Analytical Services, LLC ('Pace") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Pace policies. Any exceptions to the NELAC standards, the QAMP, SOPS or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. This report supersedes and replaces any prior reports issued under this lot number. Metals results for samples -001 through -012 were revised to report the initial prep results. The sample ID and collection date for sample -024 were revised, as per client instruction. ICP-MS Metals The matrix spike/matrix spike duplicate (MS/MSD) associated with samples -024 and -012 had aluminum recovered outside of the acceptance limits. The laboratory control sample (LCS) were recovered within the required acceptance limits; therefore, this likely demonstrates a matrix effect. The MS associated with sample -013 was not spiked due to laboratory error. As a result, all RPDs exceeded the acceptance limits. The MSD had aluminum recovered outside of the acceptance limits. The LCS was recovered within the required acceptance limits; therefore, this likely demonstrates a matrix effect. Inorganic Non -Metals The MS/MSD associated with sample -004 had sulfate recovered outside of the acceptance limits. The LCS was recovered within the required acceptance limits; therefore, this likely demonstrates a matrix effect. Pace Analytical Services, LLC (rormerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 v—pacelabs.com Page 2 of 92 PACE ANALYTICAL SERVICES, LLC Sample Summary ERM INC, Inc. Lot Number: VD04003 Sample Number Sample ID Matrix Date Sampled Date Received 001 PW-01-WG-20200402 Aqueous 04/02/2020 1440 D4/03/2020 002 W-01-WG-20200331 Aqueous 03/31/20201440 04/03/2020 003 W-02-WG-20200331 Aqueous 03/31/2020 1440 04/03/2020 004 W-03-WG-20200331 Aqueous 03/31/20201305 04/03/2020 005 W-03B-WG-20200331 Aqueous 03/31120201210 04/03/2020 006 W-06-WG-20200403 Aqueous 04/03/20201130 04/03/2020 007 W-07-WG-20200402 Aqueous 04/02/20201030 04/03/2020 008 W-08-WG-20200402 Aqueous 04/02/20201325 04/03/2020 009 W-09-WG-20200402 Aqueous 04/02/20201205 04/03/2020 010 PZ-02-WG-20200401 Aqueous 04/01/20201315 04/03/2020 011 SS-01-WS-20200401 Aqueous 04/01/2020 0900 04/03/2020 012 SS-02-WS-20200401 Aqueous 04/01/20200910 04/03/2020 013 SS-20-WS-20200401 Aqueous 04/01/20200920 04/03/2020 014 SS-25-WS-20200401 Aqueous 04/01/2020 0930 04/03/2020 015 SS-30-WS-20200401 Aqueous 04/01120201015 04/03/2020 016 SS-40-WS-20200401 Aqueous 04/01120201015 04/03/2020 017 SS-50-WS-20200401 Aqueous 04/01/2020 0115 04/03/2020 018 SS-60-WS-20200401 Aqueous 04/01120201215 04/03/2020 019 SS-70-WS-20200401 Aqueous 04/01/2020 1245 04/03/2020 020 SS-80-WS-20200401 Aqueous 04/01120201345 04/03/2020 021 SS-90-WS-20200401 Aqueous 04/01/2020 1500 04/03/2020 022 PZ-04-WG-20200401 Aqueous 04/01120201230 04/03/2020 023 PZ-05-WG-20200401 Aqueous 04/01/20201200 04/03/2020 024 FD-01-WG-20200331 Aqueous 03/31/2020 04/03/2020 025 FD-02-WG-20200401 Aqueous 04/01/2020 04/03/2020 (25 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelabs.com Page 3 of 92 PACE ANALYTICAL SERVICES, LLC Detection Summary ERM INC, Inc. Lot Number: VD04003 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 PW-01-WG-20200402 Aqueous Sulfate 300.0 830 mg/L 8 001 PW-01-WG-20200402 Aqueous TDS SM 2540C- 1700 mg/L 8 001 PW-01-WG-20200402 Aqueous Aluminum 6020B 250 ug/L 9 001 PW-01-WG-20200402 Aqueous Barium 6020B 36 ug/L 9 001 PW-01-WG-20200402 Aqueous Iron 6020B 3300 ug/L 9 001 PW-01-WG-20200402 Aqueous Manganese 6020B 2700 ug/L 9 001 PW-01-WG-20200402 Aqueous Selenium 6020B 21 ug/L 9 002 W-01-WG-20200331 Aqueous Sulfate 300.0 970 mg/L 10 002 W-01-WG-20200331 Aqueous TDS SM 2540C- 2200 mg/L 10 002 W-01-WG-20200331 Aqueous Aluminum 6020B 180 ug/L 11 002 W-01-WG-20200331 Aqueous Barium 6020B 29 ug/L 11 002 W-01-WG-20200331 Aqueous Iron 6020E 450 ug/L 11 002 W-01-WG-20200331 Aqueous Manganese 6020B 4000 ug/L 11 002 W-01-WG-20200331 Aqueous Selenium 6020E 18 ug/L 11 003 W-02-WG-20200331 Aqueous Sulfate 300.0 22 mg/L 12 003 W-02-WG-20200331 Aqueous TDS SM 2540C- 82 mg/L 12 003 W-02-WG-20200331 Aqueous Aluminum 6020E 970 ug/L 13 003 W-02-WG-20200331 Aqueous Barium 6020B 150 ug/L 13 003 W-02-WG-20200331 Aqueous Iron 6020E 1100 ug/L 13 003 W-02-WG-20200331 Aqueous Manganese 6020E 20 ug/L 13 004 W-03-WG-20200331 Aqueous Sulfate 300.0 190 mg/L 14 004 W-03-WG-20200331 Aqueous TDS SM 2540C- 510 mg/L 14 004 W-03-WG-20200331 Aqueous Barium 6020E 26 ug/L 15 004 W-03-WG-20200331 Aqueous Manganese 6020B 170 ug/L 15 004 W-03-WG-20200331 Aqueous Selenium 6020E 9.8 ug/L 15 005 W-03B-WG-20200331 Aqueous Sulfate 300.0 23 mg/L 16 005 W-03B-WG-20200331 Aqueous TDS SM 2540C- 240 mg/L 16 005 W-03B-WG-20200331 Aqueous Barium 6020E 59 ug/L 17 005 W-03B-WG-20200331 Aqueous Manganese 6020B 87 ug/L 17 006 W-06-WG-20200403 Aqueous Sulfate 300.0 10 mg/L 18 006 W-06-WG-20200403 Aqueous TDS SM 2540C- 250 mg/L 18 006 W-06-WG-20200403 Aqueous Aluminum 6020E 180 ug/L 19 006 W-06-WG-20200403 Aqueous Barium 6020B 43 ug/L 19 006 W-06-WG-20200403 Aqueous Chromium 6020B 7.2 ug/L 19 006 W-06-WG-20200403 Aqueous Iron 6020B 190 ug/L 19 006 W-06-WG-20200403 Aqueous Manganese 6020B 5.6 ug/L 19 007 W-07-WG-20200402 Aqueous Sulfate 300.0 5.4 mg/L 20 007 W-07-WG-20200402 Aqueous TDS SM 2540C- 190 mg/L 20 007 W-07-WG-20200402 Aqueous Aluminum 6020B 130 ug/L 21 007 W-07-WG-20200402 Aqueous Barium 6020B 75 ug/L 21 007 W-07-WG-20200402 Aqueous Chromium 6020B 6.1 ug/L 21 007 W-07-WG-20200402 Aqueous Iron 6020B 1200 ug/L 21 007 W-07-WG-20200402 Aqueous Manganese 6020B 72 ug/L 21 008 W-08-WG-20200402 Aqueous Sulfate 300.0 69 mg/L 22 008 W-08-WG-20200402 Aqueous TDS SM 2540C- 170 mg/L 22 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelab—nn Page 4 of 92 Detection Summary (Continued) Lot Number: VD04003 Detection Summary (Continued) Lot Number: VD04003 Sample Sample ID Matrix Parameter Method Result Q Units Page Sample Sample ID Matrix Parameter Method Result Q Units Page 008 W-08-WG-20200402 Aqueous Aluminum 6020B 64 ug/L 23 016 SS-40-WS-20200401 Aqueous Sulfate 300.0 24 mg/L 38 008 W-08-WG-20200402 Aqueous Barium 6020B 150 ug/L 23 016 SS40-WS-20200401 Aqueous TDS SM 2540C- 110 mg/L 38 008 W-08-WG-20200402 Aqueous Chromium 6020B 5.1 ug/L 23 016 SS-40-WS-20200401 Aqueous Aluminum 6020B 280 ug/L 39 008 W-08-WG-20200402 Aqueous Iron 6020E 97 ug/L 23 016 SS-40-WS-20200401 Aqueous Barium 6020B 48 ug/L 39 009 W-09-WG-20200402 Aqueous Sulfate 300.0 12 mg/L 24 016 SS40-WS-20200401 Aqueous Iron 6020B 400 ug/L 39 009 W-09-WG-20200402 Aqueous TDS SM 2540C- 230 mg/L 24 016 SS-40-WS-20200401 Aqueous Manganese 6020B 9.0 ug/L 39 009 W-09-WG-20200402 Aqueous Aluminum 6020B 42 ug/L 25 017 SS-50-WS-20200401 Aqueous Sulfate 300.0 2.8 mg/L 40 009 W-09-WG-20200402 Aqueous Barium 6020B 170 ug/L 25 017 SS-50-WS-20200401 Aqueous TDS SM 2540C- 74 mg/L 40 010 PZ-02-WG-20200401 Aqueous Sulfate 300.0 33 mg/L 26 017 SS-50-WS-20200401 Aqueous Aluminum 6020B 660 ug/L 41 010 PZ-02-WG-20200401 Aqueous TDS SM 2540C- 160 mg/L 26 017 SS-50-WS-20200401 Aqueous Barium 6020B 47 ug/L 41 010 PZ-02-WG-20200401 Aqueous Aluminum 6020B 69000 ug/L 27 017 SS-50-WS-20200401 Aqueous Iron 6020E 2300 ug/L 41 010 PZ-02-WG-20200401 Aqueous Barium 6020E 710 ug/L 27 017 SS-50-WS-20200401 Aqueous Manganese 6020E 96 ug/L 41 010 PZ-02-WG-20200401 Aqueous Cadmium 6020B 20 ug/L 27 018 SS-60-WS-20200401 Aqueous Sulfate 300.0 62 mg/L 42 010 PZ-02-WG-20200401 Aqueous Chromium 6020B 80 ug/L 27 018 SS-60-WS-20200401 Aqueous TDS SM 2540C- 160 mg/L 42 010 PZ-02-WG-20200401 Aqueous Iron 6020E 130000 ug/L 27 018 SS-60-WS-20200401 Aqueous Aluminum 6020E 650 ug/L 43 010 PZ-02-WG-20200401 Aqueous Lead 6020E 38 ug/L 27 018 SS-60-WS-20200401 Aqueous Barium 6020E 54 ug/L 43 010 PZ-02-WG-20200401 Aqueous Manganese 6020E 7200 ug/L 27 018 SS-60-WS-20200401 Aqueous Iron 6020E 690 ug/L 43 010 PZ-02-WG-20200401 Aqueous Selenium 6020E 7.4 ug/L 27 018 SS-60-WS-20200401 Aqueous Manganese 6020E 7.3 ug/L 43 011 SS-01-WS-20200401 Aqueous Sulfate 300.0 26 mg/L 28 019 SS-70-WS-20200401 Aqueous Sulfate 300.0 12 mg/L 44 011 SS-01-WS-20200401 Aqueous TDS SM 2540C- 150 mg/L 28 019 SS-70-WS-20200401 Aqueous TDS SM 2540C- 77 mg/L 44 011 SS-01-WS-20200401 Aqueous Aluminum 6020E 490 ug/L 29 019 SS-70-WS-20200401 Aqueous Aluminum 6020E 630 ug/L 45 011 SS-01-WS-20200401 Aqueous Barium 6020E 59 ug/L 29 019 SS-70-WS-20200401 Aqueous Barium 6020E 43 ug/L 45 011 SS-01-WS-20200401 Aqueous Iron 6020B 690 ug/L 29 019 SS-70-WS-20200401 Aqueous Iron 6020B 840 ug/L 45 011 SS-01-WS-20200401 Aqueous Manganese 6020E 8.6 ug/L 29 019 SS-70-WS-20200401 Aqueous Manganese 6020E 14 ug/L 45 012 SS-02-WS-20200401 Aqueous Sulfate 300.0 38 mg/L 30 020 SS-80-WS-20200401 Aqueous Sulfate 300.0 10 mg/L 46 012 SS-02-WS-20200401 Aqueous TDS SM 2540C- 150 mg/L 30 020 SS-80-WS-20200401 Aqueous TDS SM 2540C- 76 mg/L 46 012 SS-02-WS-20200401 Aqueous Aluminum 6020E 450 ug/L 31 020 SS-80-WS-20200401 Aqueous Aluminum 6020B 510 ug/L 47 012 SS-02-WS-20200401 Aqueous Barium 6020E 47 ug/L 31 020 SS-80-WS-20200401 Aqueous Barium 6020E 50 ug/L 47 012 SS-02-WS-20200401 Aqueous Iron 6020E 580 ug/L 31 020 SS-80-WS-20200401 Aqueous Iron 6020E 680 ug/L 47 012 SS-02-WS-20200401 Aqueous Manganese 6020B 18 ug/L 31 020 SS-80-WS-20200401 Aqueous Manganese 6020E 5.8 ug/L 47 013 SS-20-WS-20200401 Aqueous Sulfate 300.0 9.3 mg/L 32 021 SS-90-WS-20200401 Aqueous Sulfate 300.0 22 mg/L 48 013 SS-20-WS-20200401 Aqueous TDS SM 2540C- 76 mg/L 32 021 SS-90-WS-20200401 Aqueous TDS SM 2540C- 110 mg/L 48 013 SS-20-WS-20200401 Aqueous Aluminum 6020E 1800 ug/L 33 021 SS-90-WS-20200401 Aqueous Aluminum 6020E 200 ug/L 49 013 SS-20-WS-20200401 Aqueous Barium 6020E 47 ug/L 33 021 SS-90-WS-20200401 Aqueous Barium 6020E 47 ug/L 49 013 SS-20-WS-20200401 Aqueous Iron 6020E 1600 ug/L 33 021 SS-90-WS-20200401 Aqueous Iron 6020E 300 ug/L 49 013 SS-20-WS-20200401 Aqueous Manganese 6020E 13 ug/L 33 021 SS-90-WS-20200401 Aqueous Manganese 6020E 8.3 ug/L 49 014 SS-25-WS-20200401 Aqueous Sulfate 300.0 9.2 mg/L 34 022 PZ-04-WG-20200401 Aqueous Sulfate 300.0 37 mg/L 50 014 SS-25-WS-20200401 Aqueous TDS SM 2540C- 70 mg/L 34 022 PZ-04-WG-20200401 Aqueous TDS SM 2540C- 130 mg/L 50 014 SS-25-WS-20200401 Aqueous Aluminum 6020E 1700 ug/L 35 022 PZ-04-WG-20200401 Aqueous Aluminum 6020E 95000 ug/L 51 014 SS-25-WS-20200401 Aqueous Barium 6020B 48 ug/L 35 022 PZ-04-WG-20200401 Aqueous Barium 6020E 1600 ug/L 51 014 SS-25-WS-20200401 Aqueous Iron 6020E 1500 ug/L 35 022 PZ-04-WG-20200401 Aqueous Cadmium 6020E 4.8 ug/L 51 014 SS-25-WS-20200401 Aqueous Manganese 6020B 9.5 ug/L 35 022 PZ-04-WG-20200401 Aqueous Chromium 6020B 130 ug/L 51 015 SS-30-WS-20200401 Aqueous Sulfate 300.0 31 mg/L 36 022 PZ-04-WG-20200401 Aqueous Iron 6020B 160000 ug/L 51 015 SS-30-WS-20200401 Aqueous TDS SM 2540C- 160 mg/L 36 022 PZ-04-WG-20200401 Aqueous Lead 6020B 34 ug/L 51 015 SS-30-WS-20200401 Aqueous Aluminum 6020B 1300 ug/L 37 022 PZ-04-WG-20200401 Aqueous Manganese 6020B 3400 ug/L 51 015 SS-30-WS-20200401 Aqueous Barium 6020B 59 ug/L 37 023 PZ-05-WG-20200401 Aqueous Sulfate 300.0 35 mg/L 52 015 SS-30-WS-20200401 Aqueous Iron 6020E 1800 ug/L 37 023 PZ-05-WG-20200401 Aqueous TDS SM 2540C- 150 mg/L 52 015 SS-30-WS-20200401 Aqueous Manganese 6020B 18 ug/L 37 023 PZ-05-WG-20200401 Aqueous Aluminum 6020B 11000 ug/L 53 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.com Page 5 of 92 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.com Page 6 of 92 Detection Summary (Continued) Lot Number: VD04003 Sample Sample ID Matrix Parameter Method Result Q Units Page 023 PZ-05-WG-20200401 Aqueous Barium 6020B 180 ug/L 53 023 PZ-05-WG-20200401 Aqueous Cadmium 6020B 8.1 ug/L 53 023 PZ-05-WG-20200401 Aqueous Chromium 6020B 17 ug/L 53 023 PZ-05-WG-20200401 Aqueous Iron 6020B 51000 ug/L 53 023 PZ-05-WG-20200401 Aqueous Lead 6020B 4.7 ug/L 53 023 PZ-05-WG-20200401 Aqueous Manganese 6020B 770 ug/L 53 024 FD-01-WG-20200331 Aqueous Sulfate 300.0 22 mg/L 54 024 FD-01-WG-20200331 Aqueous TDS SM 2540C- 76 mg/L 54 024 FD-01-WG-20200331 Aqueous Aluminum 6020E 990 ug/L 55 024 FD-01-WG-20200331 Aqueous Barium 6020B 150 ug/L 55 024 FD-01-WG-20200331 Aqueous Iron 6020B 1300 ug/L 55 024 FD-01-WG-20200331 Aqueous Manganese 6020E 20 ug/L 55 025 FD-02-WG-20200401 Aqueous Sulfate 300.0 38 mg/L 56 025 FD-02-WG-20200401 Aqueous TDS SM 2540C- 160 mg/L 56 025 FD-02-WG-20200401 Aqueous Aluminum 6020E 400 ug/L 57 025 FD-02-WG-20200401 Aqueous Barium 6020B 46 ug/L 57 025 FD-02-WG-20200401 Aqueous Iron 6020E 600 ug/L 57 025 FD-02-WG-20200401 Aqueous Manganese 6020E 18 ug/L 57 (159 detections Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 92 Inorganic non-metals Client: ERM INC, Inc. Laboratory ID: VD04003-001 Description: PW-01-WG-20200402 Matrix: Aqueous Date Sampled:04/02/2020 1440 Date Received: 04/03/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate) 300.0 5 04/07/2020 1919 HKL 50294 1 (TDS) SM 254OC-2011 1 04/05/2020 1952 MOM 50031 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 830 5.0 mg/L 1 TDS SM 2540C- 1700 25 mg/L 1 LOQ =Limit of Quantilation B = Detected in the method blank E = Quanti.tion of —pound exceeded the calibaYon ange ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD be—n Iwo QC columns exceeds 4a% H = Out of holding tlme W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 92 ICP-MS Metals Client: ERM NC, Inc. Laboratory ID. V D04003-001 Description: PW-01-WG-20200402 Matrix: Aqueous Date Sampled:04/02/2020 1440 )ate Received: 04/03/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 04/08/2020 2307 BPK 04/07/2020 2301 50253 2 3005A 6020E 100 04/09/2020 1943 BPK 04/07/2020 2301 50253 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429.90.5 6020B 250 40 ug/L 1 Barium 744039-3 6020B 36 5.0 ug/L 1 Cadmium 7440-43-9 6020B NO 0.50 ug/L 1 Chromium 7440-47-3 6020E ND 5.0 ug/L 1 Iron 7439.89.6 6020E 3300 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 1 Manganese 7439-96-5 6020B 2700 500 ug/L 2 Selenium 7782.49.2 6020E 21 5.0 ug/L 1 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of —pound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of cntena P = The RPD beh — two QC column. exceed. 40% H = Out of holding tlme W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-002 Description: W-01-WG-20200331 Matrix: Aqueous Date Sampled:03/31/20201440 )ate Received: 04/03/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate) 300.0 5 04/07/2020 1942 HKL 50294 2 (TDS) SM 254OC-2011 1 04/07/2020 2256 MOM 50270 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 970 5.0 ni 1 TDS SM 2540C- 2200 25 mg/L 2 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibr4don range ND = Not tletected at or above the LOQ N = Recovery i. out of criteria P = The RPD behveen Iwo QC columns exceed. 40% H = Out of holding tlme W = Reported on wet weight boats Pace Analytical Services, LLC (fernerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 92 Page 10 of 92 ICP-MS Metals Client: ERM NC, Inc. Laboratory ID. V D04003-002 Description: W-01-WG-20200331 Matrix: Aqueous Date Sampled:03/31/20201440 )ate Received: 04/03/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 04/08/2020 2329 BPK 04/07/2020 2301 50253 2 3005A 6020E 100 04/09/2020 1950 BPK 04/07/2020 2301 50253 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429.90.5 6020B 180 40 ug/L 1 Barium 744039-3 6020B 29 5.0 ug/L 1 Cadmium 7440-43-9 6020B NO 0.50 ug/L 1 Chromium 7440-47-3 6020E ND 5.0 ug/L 1 Iron 7439.89.6 6020E 450 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 1 Manganese 7439-96-5 6020B 4000 500 ug/L 2 Selenium 7782.49.2 6020E 18 5.0 ug/L 1 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not tletected at or above the LOQ N = Recovery is out of enter. P = The RPD between two QC column. exceed. 40% H = Out of holding tlme W = Reported on wet weight boat. Pace Analytical Services, LLC (/orrnady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-003 Description: W-02-WG-20200331 Matrix: Aqueous Date Sampled:03/31/20201440 )ate Received: 04/03/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate)300.0 1 04/07/20202005 HKL 50294 1 (TDS) SM 254OC-2011 1 04/05/2020 1952 MOM 50031 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 22 1.0 mg/L 1 TDS SM 254OC- 82 25 di 1 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of —pound exceeded the calibration range ND = Not tletected at or above the LOQ N = Recovery i. out of criteria P = The RPD tale— twa QC columns exceed. 40% H = Out of holding tlme W = Reported on wet weight basis Pace Analytical Services, LLC (rormerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of92 Page 12 of92 ICP-MS Metals Client: ERM NC, Inc. Laboratory I D. V D04003-003 Description: W-02-WG-20200331 Matrix: Aqueous Date Sampled:03/31/20201440 Date Received: 04/03/2020 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-004 Description: W-03-WG-20200331 Matrix: Aqueous Date Sampled:03/31/20201305 Date Received:04/03/2020 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020E 1 04/08/2020 2336 BPK Prep Date Batch 04/07/2020 2301 50253 Run Prep Method 1 1 Analytical Method Dilution Analysis Date Analyst (Sulfate) 300.0 1 04/07/2020 2028 HKL SM 254OC-2011 1 04/05/2020 1952 MOM Prep Date Batch 50294 50031 CAS Analytical (TDS) Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 970 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 150 5.0 ug/L 1 Sulfate 300.0 190 1.0 ni 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 2540C- 510 25 ni 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 1100 50 ug/L 1 Lead 7439-92-1 6020E ND 1.0 ug/L 1 Manganese 7439-96-5 6020B 20 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not tlatected at or above the LOQ N = Recovery is out of enter. P = The RPD behveen two QC column. e—d. 40% H = Out of holding dme W = Reported on wet weight bawls Pace Analytical Services, LLC ff—ady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.00m Page 13 of92 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound ex ... dad the calibaYon range ND = Not tlatected at or above the LOQ N = Recovery i. out of crime P = The RPD tanw n two QC columns exceed. 40% H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of92 ICP-MS Metals Client: ERM NC, Inc. Laboratory I D. V D04003-004 Description: W-03-WG-20200331 Matrix: Aqueous Date Sampled:03131/20201305 Date Received: 04/03/2020 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-005 Description: W-03B-WG-20200331 Matrix: Aqueous Date Sampled:03/31/20201210 Date Received:04/03/2020 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020E 1 04/08/2020 2344 BPK Prep Date Batch 04/07/2020 2301 50253 Run Prep Method 1 1 Analytical Method Dilution Analysis Date Analyst (Sulfate) 300.0 1 04/07/2020 2136 HKL SM 254OC-2011 1 04/05/2020 1952 MOM Prep Date Batch 50294 50031 CAS Analytical (TDS) Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B ND 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 26 5.0 ug/L 1 Sulfate 300.0 23 1.0 ni 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 2540C- 240 25 mg/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89-6 6020B ND 50 ug/L 1 Lead 7439-92-1 6020E ND 1.0 ug/L 1 Manganese 7439-96-5 6020E 170 5.0 ug/L 1 Selenium 7782-49-2 6020B 9.8 5.0 ug/L 1 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of enter. P = The RPD behveen two QC column. e—d. 40% H = Out of holding dme W = Reported on wet weight baels Pace Analytical Services, LLC ff—ady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.00m Page 15 of92 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound ex ... dad the calibration range ND = Not detected at or above the LOQ N = Recovery i. out of cnlena P = The RPD tanw n twa QC calumna exceed. 40% H = Out of holding time W = Repotted on wet weight lasts Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 16 of92 ICP-MS Metals Client: ERM NC, Inc. Laboratory I D. V D04003-005 Description: W-03B-WG-20200331 Matrix: Aqueous Date Sampled:03/31/20201210 Date Received: 04/03/2020 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-006 Description: W-06-WG-20200403 Matrix: Aqueous Date Sampled:04/03/2020 1130 Date Received:04/03/2020 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020E 1 04/08/2020 2351 BPK Prep Date Batch 04/07/2020 2301 50253 Run Prep Method 1 1 Analytical Method Dilution Analysis Date Analyst (Sulfate) 300.0 1 04/07/2020 2245 HKL SM 254OC-2011 1 04/05/2020 1952 MOM Prep Date Batch 50294 50031 CAS Analytical (TDS) Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B ND 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 59 5.0 ug/L 1 Sulfate 300.0 10 1.0 ni 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 2540C- 250 25 ni 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89-6 6020B ND 50 ug/L 1 Lead 7439-92-1 6020E ND 1.0 ug/L 1 Manganese 7439-96-5 6020B 87 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration no. ND = Not tletected at or above the LOQ N = Recovery is out of enter. P = The RPD behveen two QC column. e—d. 40% H = Out of holding dme W = Reported on wet weight baels Pace Analytical Services, LLC ff—ady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.00m Page 17 of92 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound ex ... dad the calibaYon no. ND = Not tletected at or above the LOQ N = Recovery i. out of crime P = The RPD tanw n two QC columns exceed. 40% H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 18 of92 ICP-MS Metals Client: ERM NC, Inc. Laboratory I D. V D04003-006 Description: W-06-WG-20200403 Matrix: Aqueous Date Sampled:04/03/2020 1130 Date Received: 04/03/2020 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-007 Description: W-07-WG-20200402 Matrix: Aqueous Date Sampled:04/02/2020 1030 Date Received:04/03/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 04/08/2020 2359 BPK 04/07/2020 2301 50253 1 (Sulfate) 300.0 1 04/07/2020 2308 HKL 50294 1 (TDS) SM 254OC-2011 1 04/05/2020 1952 MOM 50031 CAS Analytical Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 180 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 43 5.0 ug/L 1 Sulfate 300.0 5.4 1.0 ni 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 2540C- 190 25 ni 1 Chromium 7440-47-3 6020B 7.2 5.0 ug/L 1 Iron 7439-89-6 6020B 190 50 ug/L 1 Lead 7439-92-1 6020E ND 1.0 ug/L 1 Manganese 7439-96-5 6020B 5.6 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of campound exceeded the calibration range ND = Not tlatected at or above the LOQ N = Recovery is out of enter. P = The RPD b—... two QC column. e—d. 40% H = Out of holding brae W = Reported on wet weight bawls Pace Analytical Services, LLC ff—ady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.00m Page 19 of92 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound ex ... deal the calibcu.n range ND= Not tlatected at or above the LOQ N= Recovery i. out of cried P=The RPD uatv..n two QC columns exceed. 40% H = Out of holding time W = Reported on wet weight boats Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 20 of 92 ICP-MS Metals Client: ERM NC, Inc. Laboratory I D. V D04003-007 Description: W-07-WG-20200402 Matrix: Aqueous Date Sampled:04/02/2020 1030 Date Received: 04/03/2020 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-008 Description: W-08-WG-20200402 Matrix: Aqueous Date Sampled:04/02/2020 1325 Date Received:04/03/2020 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020E 1 04/09/2020 0006 BPK Prep Date Batch 04/07/2020 2301 50253 Run Prep Method 1 1 Analytical Method Dilution Analysis Date Analyst (Sulfate) 300.0 1 04/07/2020 2330 HKL SM 254OC-2011 1 04/05/2020 1952 MOM Prep Date Batch 50294 50031 CAS Analytical (TDS) Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 130 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 75 5.0 ug/L 1 Sulfate 300.0 69 1.0 ni 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 2540C- 170 25 mg/L 1 Chromium 7440-47-3 6020B 6.1 5.0 ug/L 1 Iron 7439-89-6 6020B 1200 50 ug/L 1 Lead 7439-92-1 6020E ND 1.0 ug/L 1 Manganese 7439-96-5 6020B 72 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of campound exceeded the calibration no. ND = Not tlatected at or above the LOQ N = Recovery is out of enter. P = The RPD b—... two QC column. e—d. 40% H = Out of holding brae W = Reported on wet weight bawls Pace Analytical Services, LLC ff—ady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.00m Page 21 of 92 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound ex ... deal the calibcu.n range ND= Not tlatected at or above the LOQ N= Recovery i. out of cried P=The RPD uatv..n Iwa QC calumny exceed. 40% H = Out of holding time W = Reported on wet weight boats Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 22 of 92 ICP-MS Metals Client: ERM NC, Inc. Laboratory I D. V D04003-008 Description: W-08-WG-20200402 Matrix: Aqueous Date Sampled:04/02/2020 1325 Date Received: 04/03/2020 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-009 Description: W-09-WG-20200402 Matrix: Aqueous Date Sampled:04/02/2020 1205 Date Received:04/03/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 04/09/2020 0013 BPK 04/07/2020 2301 50253 1 (Sulfate) 300.0 1 04/07/2020 2353 HKL 50294 1 (TDS) SM 254OC-2011 1 04/05/2020 1952 MOM 50031 CAS Analytical Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 64 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 150 5.0 ug/L 1 Sulfate 300.0 12 1.0 ni 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 2540C- 230 25 ni 1 Chromium 7440-47-3 6020B 5.1 5.0 ug/L 1 Iron 7439-89-6 6020B 97 50 ug/L 1 Lead 7439-92-1 6020E ND 1.0 ug/L 1 Manganese 7439-96-5 6020B ND 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of —pound exceeded the calibration range ND = Not tletected u or above the LOQ N = Recovery i. out of enter. P = The RPD behveen two QC column. ex—d. 40% H = Out of holding tlme W = Reported on wet weight baels Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.00m Page 23 of92 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of wmpo.nd exceeded the calibr4don range ND=Not tletected uor above the LOQ N= Recovery i. out of cried P= The RPD behveen two QC column. exceed. 40% H = Out of holding tlme W = Reported on wet weight baels Pace Analytical Services, LLC (fernerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 24 of 92 ICP-MS Metals Client: ERM NC, Inc. Laboratory I D. V D04003-009 Description: W-09-WG-20200402 Matrix: Aqueous Date Sampled:04/02/2020 1205 Date Received: 04/03/2020 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-010 Description: PZ-02-WG-20200401 Matrix: Aqueous Date Sampled:04/01/20201315 Date Received:04/03/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 04/09/2020 0021 BPK 04/07/2020 2301 50253 1 (Sulfate) 300.0 1 04/08/2020 1923 HKL 50458 1 (TDS) SM 254OC-2011 1 04/05/2020 1952 MOM 50031 CAS Analytical Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 42 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 170 5.0 ug/L 1 Sulfate 300.0 33 1.0 ni 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 2540C- 160 25 ni 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89-6 6020B ND 50 ug/L 1 Lead 7439-92-1 6020E ND 1.0 ug/L 1 Manganese 7439-96-5 6020B NO 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of wnnp—d exceeded the calibration range ND = Not tlatected at or above the LOQ N = Recovery is out of enter. P = The RPD behveen two QC column. ex—d. 40% H = Out of holding dme W = Reported on wet weight bawls Pace Analytical Services, LLC ff—ady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.00m Page 25 of92 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of wmpo.nd ex ... dad the calibadon range ND = Not tlatected at or above the LOQ N = Recovery i. out of criteria P = The RPD tanw n two QC columns exceed. 40% H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 26 of 92 ICP-MS Metals Client: ERM NC, Inc. Laboratory ID: VD04003-010 Description: PZ-02-WG-20200401 Matrix: Aqueous Date Sampled:04/01/20201315 )ate Received: 04/03/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 04/09/2020 0028 BPK 04/07/2020 2301 50253 2 3005A 6020E 10 04/09/2020 2005 BPK 04/07/2020 2301 50253 CAS Analytical Parameter Number Method Result Q LOCI Units Run Aluminum 7429-90-5 6020B 69000 40 ug/L 1 Barium 7440-39-3 6020B 710 5.0 ug/L 1 Cadmium 7440-43-9 6020B 20 0.50 ug/L 1 Chromium 7440-47-3 6020E 80 5.0 ug/L 1 Iron 7439-89-6 6020E 130000 50 ug/L 1 Lead 7439-92-1 6020B 38 1.0 ug/L 1 Manganese 7439-96-5 6020E 7200 50 ug/L 2 Selenium 7782-49-2 6020B 7.4 5.0 ug/L 1 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibalan range ND = Not tlatected at cr above the LOQ N = Recovery is out of critana P = The RPD In—... two QC column. e—d. 40% H = Out of holding tlme W = Reported on wet weight baal. Pace Analytical Services, LLC (/omnady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-011 Description: SS-01-WS-20200401 Matrix: Aqueous Date Sampled:04/01/2020 0900 )ate Received: 04/03/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate) 300.0 1 04/08/2020 1942 HKL 50458 1 (TDS) SM 254OC-2011 1 04/05/2020 1952 MOM 50031 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 26 1.0 mg/L 1 TDS SM 2540C- 150 25 mg/L 1 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibah,n no. ND= Not tlatected at cr above the LOQ N= Recovery i. out of cdtena P=The RPD banes— twa QC columns exceed. 40% H = Out of holding tlme W = Reported on wet weight b..l. Pace Analytical Services, LLC (rormerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 27 of 92 Page 28 of 92 ICP-MS Metals Client: ERM NC, Inc. Laboratory I D. V D04003-011 Description: SS-01-WS-20200401 Matrix: Aqueous Date Sampled:04/01/2020 0900 Date Received: 04/03/2020 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-012 Description: SS-02-WS-20200401 Matrix: Aqueous Date Sampled:04/01/2020 0910 Date Received:04/03/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 04/09/2020 0036 BPK 04/07/2020 2301 50253 1 (Sulfate) 300.0 1 04/08/2020 2002 HKL 50458 1 (TDS) SM 254OC-2011 1 04/05/2020 1952 MOM 50031 CAS Analytical Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 490 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 59 5.0 ug/L 1 Sulfate 300.0 38 1.0 ni 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 2540C- 150 25 ni 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 690 50 ug/L 1 Lead 7439-92-1 6020E ND 1.0 ug/L 1 Manganese 7439-96-5 6020B 8.6 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibalan range ND = Not tlatected at or above the LOQ N = Recovery is out of enter. P = The RPD behveen two QC column. e—d. 40% H = Out of holding dme W = Reported on wet weight bawls Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—no Page 29 of 92 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound ex ... dad the calibaYon range ND = Not tlatected at or above the LOQ N = Recovery i. out of Cohen, P = The RPD tanw n two QC columns exceed. 40% H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 30 of 92 ICP-MS Metals Client: ERM NC, Inc. Laboratory I D. V D04003-012 Description: SS-02-WS-20200401 Matrix: Aqueous Date Sampled:04/01/2020 0910 Date Received: 04/03/2020 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-013 Description: SS-20-WS-20200401 Matrix: Aqueous Date Sampled:04/01/2020 0920 Date Received:04/03/2020 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020E 1 04/09/2020 0058 BPK Prep Date Batch 04/07/2020 2301 50253 Run Prep Method 1 1 Analytical Method Dilution Analysis Date Analyst (Sulfate) 300.0 1 04/08/2020 2022 HKL SM 254OC-2011 1 04/05/2020 1952 MOM Prep Date Batch 50458 50031 CAS Analytical (TDS) Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 450 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 47 5.0 ug/L 1 Sulfate 300.0 9.3 1.0 ni 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 254OC- 76 25 ni 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 580 50 ug/L 1 Lead 7439-92-1 6020E ND 1.0 ug/L 1 Manganese 7439-96-5 6020B 18 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of enter. P = The RPD behveen two QC column. e—d. 40% H = Out of holding dme W = Reported on wet weight beats Pace Analytical Services, LLC ff—ady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 31 of 92 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound ex ... dad the calibration range ND= Not tletected at or above the LOQ N= Recovery i. out of crime P=The RPD Wine— twa QC columns exceed. 40% H = Out of holding time W = Reported on wet weight beats Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 32 of 92 ICP-MS Metals Client: ERM NC, Inc. Laboratory I D. V D04003-013 Description: SS-20-WS-20200401 Matrix: Aqueous Date Sampled:04/01/2020 0920 Date Received: 04/03/2020 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-014 Description: SS-25-WS-20200401 Matrix: Aqueous Date Sampled:04/01/2020 0930 Date Received: 04/03/2020 Run Prep Method 2 3005A Analytical Method Dilution Analysis Date Analyst 6020E 1 04/14/20201531 BNW Prep Date Batch 04/14/2020 0709 50924 Run Prep Method 1 1 Analytical Method Dilution Analysis Date Analyst (Sulfate)300.0 1 04/08/20202122 HKL SM 254OC-2011 1 04/06/2020 2332 MOM Prep Date Batch 50458 50136 CAS Analytical (TDS) Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 1800 40 ug/L 2 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 47 5.0 ug/L 2 Sulfate 300.0 9.2 1.0 ni 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 2 TDS SM 2540C- 70 25 ni 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 2 Iron 7439-89.6 6020B 1600 50 ug/L 2 Lead 7439-92-1 6020E ND 1.0 ug/L 2 Manganese 7439-96-5 6020B 13 5.0 ug/L 2 Selenium 7782-49-2 6020E ND 5.0 ug/L 2 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not tlatected at or above the LOQ N = Recovery is out of enter. P = The RPD between two QC column. e—d. 40% H = Out of holding bme W = Reported on wet weight bawls Pace Analytical Services, LLC ff—ady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 33 of92 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound ex ... dad the calibaYon range ND = Not tlatected at or above the LOQ N = Recovery i. out of crime P = The RPD be—n two QC columns exceed. 40% H = Out of holding time W = Reported on wet weight beats Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 34 of 92 ICP-MS Metals Client: ERM NC, Inc. Laboratory I D. V D04003-014 Description: SS-25-WS-20200401 Matrix: Aqueous Date Sampled:04/01/2020 0930 Date Received: 04/03/2020 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-015 Description: SS-30-WS-20200401 Matrix: Aqueous Date Sampled:04/01/20201015 Date Received:04/03/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 3005A 6020E 1 04/14/20201549 BNW 04/14/2020 0709 50924 1 (Sulfate)300.0 1 04/08/20202222 HKL 50458 1 (TDS) SM 254OC-2011 1 04/06/2020 2332 MOM 50136 CAS Analytical Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 1700 40 ug/L 2 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 48 5.0 ug/L 2 Sulfate 300.0 31 1.0 ni 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 2 TDS SM 2540C- 160 25 mg/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 2 Iron 7439-89.6 6020B 1500 50 ug/L 2 Lead 7439-92-1 6020E ND 1.0 ug/L 2 Manganese 7439-96-5 6020B 9.5 5.0 ug/L 2 Selenium 7782-49-2 6020E ND 5.0 ug/L 2 LOO=unit of Quantitation B= Detected in the method blank E=Quantitation of —pound exceeded the.libation no. ND=Nut detected nor above the LOQ N= Recovery is out of enter. P=The RPD beh—two QC column.e—d. 40% H = Out of holding tlme W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.00m Page 35 of92 LOO=unit of Quantitation B= Detected in the method blank E=Quantitation of —pound exceeded the calibadon a no. ND=Nut tletected nor above the LOQ N= Recovery i. out of cnlena P= The RPD behveen two QC columns exceed.40% H = Out of holding tlme W = Reported on wet weight baels Pace Analytical Services, LLC (fernerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 36 of 92 ICP-MS Metals Client: ERM NC, Inc. Laboratory I D. V D04003-015 Description: SS-30-WS-20200401 Matrix: Aqueous Date Sampled:04/01/20201015 Date Received: 04/03/2020 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-016 Description: SS-40-WS-20200401 Matrix: Aqueous Date Sampled:04/01/20201015 Date Received:04/03/2020 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020E 1 04/09/20201512 BNW Prep Date Batch 04/08/2020 1547 50254 Run Prep Method 1 1 Analytical Method Dilution Analysis Date Analyst (Sulfate)300.0 1 04/08/20202242 HKL SM 254OC-2011 1 04/06/2020 2332 MOM Prep Date Batch 50458 50136 CAS Analytical (TDS) Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 1300 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 59 5.0 ug/L 1 Sulfate 300.0 24 1.0 ni 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 2540C- 110 25 ni 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 1800 50 ug/L 1 Lead 7439-92-1 6020E ND 1.0 ug/L 1 Manganese 7439-96-5 6020B 18 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not tlatected at or above the LOQ N = Recovery is out of enter. P = The RPD behveen two QC column. e—d. 40% H = Out of holding dme W = Reported on wet weight bawls Pace Analytical Services, LLC ff—ady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.00m Page 37 of 92 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound ex ... dad the calibaYon range ND = Not tlatected at or above the LOQ N = Recovery i. out of crime P = The RPD tanw n two QC columns exceed. 40% H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 38 of92 ICP-MS Metals Client: ERM NC, Inc. Laboratory I D. V D04003-016 Description: SS-40-WS-20200401 Matrix: Aqueous Date Sampled:04/01/20201015 Date Received: 04/03/2020 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-017 Description: SS-50-WS-20200401 Matrix: Aqueous Date Sampled:04/01/2020 0115 Date Received:04/03/2020 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020E 1 04/09/20201517 BNW Prep Date Batch 04/08/2020 1547 50254 Run Prep Method 1 1 Analytical Method Dilution Analysis Date Analyst (Sulfate)300.0 1 04/08/20202302 HKL SM 254OC-2011 1 04/06/2020 2332 MOM Prep Date Batch 50458 50136 CAS Analytical (TDS) Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 280 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 48 5.0 ug/L 1 Sulfate 300.0 2.8 1.0 ni 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 254OC- 74 25 ni 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 400 50 ug/L 1 Lead 7439-92-1 6020E ND 1.0 ug/L 1 Manganese 7439-96-5 6020B 9.0 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibalan range ND = Not tlatected at or on. the LOQ N = Recovery is out of enter. P = The RPD behveen two QC column. e—d. 40% H = Out of holding dme W = Reported on wet weight bawls Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—no Page 39 of 92 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound ex ... dad the calibaYon range ND = Not tlatected at or above the LOQ N = Recovery i. out of Cohen, P = The RPD tanw n two QC columns exceed. 40% H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 40 of 92 ICP-MS Metals Client: ERM NC, Inc. Laboratory I D. V D04003-017 Description: SS-50-WS-20200401 Matrix: Aqueous Date Sampled:04/01/2020 0115 Date Received: 04/03/2020 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-018 Description: SS-60-WS-20200401 Matrix: Aqueous Date Sampled:04/01/20201215 Date Received:04/03/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 04/09/20201529 BNW 04/08/2020 1547 50254 1 (Sulfate)300.0 1 04/08/20202322 HKL 50458 1 (TDS) SM 254OC-2011 1 04/06/2020 2332 MOM 50136 CAS Analytical Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 660 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 47 5.0 ug/L 1 Sulfate 300.0 62 1.0 ni 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 2540C- 160 25 ni 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 2300 50 ug/L 1 Lead 7439-92-1 6020E ND 1.0 ug/L 1 Manganese 7439-96-5 6020B 96 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not tlatected at or above the LOQ N = Recovery is out of enter. P = The RPD behveen two QC column. e—d. 40% H = Out of holding dme W = Reported on wet weight bawls Pace Analytical Services, LLC ff—ady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.00m Page 41 of 92 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound ex ... dad the calibaYon range ND = Not tlatected at or above the LOQ N = Recovery i. out of cnlena P = The RPD tanw n two QC columns exceed. 40% H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 42 of 92 ICP-MS Metals Client: ERM NC, Inc. Laboratory I D. V D04003-018 Description: SS-60-WS-20200401 Matrix: Aqueous Date Sampled:04/01/20201215 Date Received: 04/03/2020 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-019 Description: SS-70-WS-20200401 Matrix: Aqueous Date Sampled:04/01/20201245 Date Received:04/03/2020 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020E 1 04/09/20201535 BNW Prep Date Batch 04/08/2020 1547 50254 Run Prep Method 1 1 Analytical Method Dilution Analysis Date Analyst (Sulfate)300.0 1 04/08/20202341 HKL SM 254OC-2011 1 04/06/2020 2332 MOM Prep Date Batch 50458 50136 CAS Analytical (TDS) Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 650 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 54 5.0 ug/L 1 Sulfate 300.0 12 1.0 ni 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 254OC- 77 25 ni 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 690 50 ug/L 1 Lead 7439-92-1 6020E ND 1.0 ug/L 1 Manganese 7439-96-5 6020B 7.3 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not tlatected at or above the LOQ N = Recovery is out of enter. P = The RPD behveen two QC column. e—d. 40% H = Out of holding dme W = Reported on wet weight bawls Pace Analytical Services, LLC ff—ady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.00m Page 43 of92 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound ex ... dad the calibaYon range ND = Not tlatected at or above the LOQ N = Recovery i. out of crime P = The RPD tanw n two QC columns exceed. 40% H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 44 of 92 ICP-MS Metals Client: ERM NC, Inc. Laboratory I D. V D04003-019 Description: SS-70-WS-20200401 Matrix: Aqueous Date Sampled:04/01/20201245 Date Received: 04/03/2020 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-020 Description: SS-80-WS-20200401 Matrix: Aqueous Date Sampled:04/01/20201345 Date Received:04/03/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 04/09/20201541 BNW 04/08/2020 1547 50254 1 (Sulfate)300.0 1 04/09/20200121 HKL 50458 1 (TDS) SM 254OC-2011 1 04/06/2020 2332 MOM 50136 CAS Analytical Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 630 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 43 5.0 ug/L 1 Sulfate 300.0 10 1.0 ni 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 254OC- 76 25 ni 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 840 50 ug/L 1 Lead 7439-92-1 6020E ND 1.0 ug/L 1 Manganese 7439-96-5 6020B 14 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of wropound exceeded the calibration range ND = Not tlatected at or above the LOQ N = Recovery is out of enter. P = The RPD behveen two QC column. e—d. 40% H = Out of holding dme W = Reported on wet weight bawls Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—no Page 45 of92 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of —pound ex ... dad the calibaYon range ND = Not tlatected at or above the LOQ N = Recovery i. out of Cohen, P = The RPD tanw n two QC columns exceed. 40% H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 46 of 92 ICP-MS Metals Client: ERM NC, Inc. Laboratory ID: VD04003-020 Description: SS-80-WS-20200401 Matrix: Aqueous Date Sampled:04/01/20201345 Date Received: 04/03/2020 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-021 Description: SS-90-WS-20200401 Matrix: Aqueous Date Sampled:04/01/20201500 Date Received: 04/03/2020 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020E 1 04/09/20201547 BNW Prep Date Batch 04/08/2020 1547 50254 Run Prep Method 1 1 Analytical Method Dilution Analysis Date Analyst (Sulfate)300.0 1 04/09/20200141 HKL SM 254OC-2011 1 04/06/2020 2332 MOM Prep Date Batch 50458 50136 CAS Analytical (TDS) Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 510 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 50 5.0 ug/L 1 Sulfate 300.0 22 1.0 ro lL 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 2540C- 110 25 mg/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 680 50 ug/L 1 Lead 7439-92-1 6020E ND 1.0 ug/L 1 Manganese 7439-96-5 6020B 5.8 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibalan range ND = Not tlatected at or above the LOQ N = Recovery is out of criteria P = The RPD beh — two QC column. e—d. 40% H = Out of holding tlme W = Reported on wet weight baals Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.00m Page 47 of 92 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound ex ... dad the calibration range ND = Not tlatected at or above the LOQ N = Recovery i. out of criteria P = The RPD be—n twa QC columns exceed. 40% H = Out of holding tlme W = Repotted on wet weight beats Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 48 of 92 ICP-MS Metals Client: ERM NC, Inc. Laboratory I D. V D04003-021 Description: SS-90-WS-20200401 Matrix: Aqueous Date Sampled:04/01/20201500 Date Received: 04/03/2020 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-022 Description: PZ-04-WG-20200401 Matrix: Aqueous Date Sampled:04/01/20201230 Date Received:04/03/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 04/09/20201604 BNW 04/08/2020 1547 50254 1 (Sulfate)300.0 1 04/09/20200201 HKL 50458 1 (TDS) SM 254OC-2011 1 04/06/2020 2332 MOM 50136 CAS Analytical Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 200 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 47 5.0 ug/L 1 Sulfate 300.0 37 1.0 ni 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 2540C- 130 25 ni 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 300 50 ug/L 1 Lead 7439-92-1 6020E ND 1.0 ug/L 1 Manganese 7439-96-5 6020B 8.3 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not tlatected at or above the LOQ N = Recovery is out of enter. P = The RPD behveen two QC column. e—d. 40% H = Out of holding dme W = Reported on wet weight baals Pace Analytical Services, LLC ff—ady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.00m Page 49 of 92 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound ex ... dad the calibaYon range ND = Not tlatected at or above the LOQ N = Recovery i. out of cnlena P = Th. RPD tanw n two QC columns exceed. 40% H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 50 of92 ICP-MS Metals Client: ERM NC, Inc. Laboratory ID. V D04003-022 Description: PZ-04-WG-20200401 Matrix: Aqueous Date Sampled:04/01/20201230 )ate Received: 04/03/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 04/09/20201610 BNW 04/08/20201547 50254 2 3005A 6020E 10 04/09/20202138 BNW 04/08/20201547 50254 CAS Analytical Parameter Number Method Result Q LOCI Units Run Aluminum 7429-90-5 6020B 95000 40 ug/L 1 Barium 7440-39-3 6020B 1600 5.0 ug/L 1 Cadmium 7440-43-9 6020B 4.8 0.50 ug/L 1 Chromium 7440-47-3 6020E 130 5.0 ug/L 1 Iron 7439-89-6 6020E 160000 500 ug/L 2 Lead 7439-92-1 6020B 34 1.0 ug/L 1 Manganese 7439-96-5 6020B 3400 50 ug/L 2 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not tlatected at or above the LOQ N = Recovery is out of enter. P = The RPD In—... two QC column. ex—d. 40% H = Out of holding dme W = Reported on wet weight boat. Pace Analytical Services, LLC (/orrnady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-023 Description: PZ-05-WG-20200401 Matrix: Aqueous Date Sampled:04/01/20201200 )ate Received: 04/03/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Sulfate)300.0 1 04/09/20200221 HKL 50458 1 (TDS) SM 254OC-2011 1 04/06/2020 2332 MOM 50136 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 35 1.0 mg/L 1 TDS SM 2540C- 150 25 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of campound exceeded the calibration range ND = Not tlatected at or above the LOQ N = Recovery i. out of anlena P = The RPD be—n twa QC columns exceed. 40% H = Out of holding time W = Reported on wet weight boat. Pace Analytical Services, LLC (10rmerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 51 of92 Page 52 of92 ICP-MS Metals Client: ERM NC, Inc. Laboratory I D. V D04003-023 Description: PZ-05-WG-20200401 Matrix: Aqueous Date Sampled:04/01/20201200 Date Received: 04/03/2020 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-024 Description: FD-01-WG-20200331 Matrix: Aqueous Date Sampled:03/31/2020 Date Received: 04/03/2020 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020E 1 04/09/20201616 BNW Prep Date Batch 04/08/2020 1547 50254 Run Prep Method 1 1 Analytical Method Dilution Analysis Date Analyst (Sulfate)300.0 1 04/09/20200241 HKL SM 254OC-2011 1 04/06/2020 2332 MOM Prep Date Batch 50458 50136 CAS Analytical (TDS) Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 11000 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 180 5.0 ug/L 1 Sulfate 300.0 22 1.0 mg/L 1 Cadmium 7440-43-9 6020B 8.1 0.50 ug/L 1 TDS SM 254OC- 76 25 mg/L 1 Chromium 7440-47-3 6020B 17 5.0 ug/L 1 Iron 7439-89-6 6020E 51000 50 ug/L 1 Lead 7439-92-1 6020B 4.7 1.0 ug/L 1 Manganese 7439-96-5 6020B 770 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of ..pound exceeded the calibration range ND = Not tlatected at cr above the LOQ N = Recovery is out of enter. P = The RPD behveen two QC columns e—d. 40% H = Out of holding bme W = Reported on wet weight bawls Pace Analytical Services, LLC ff—ady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.00m Page 53 of92 LOQ =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound ex ... dad the calibaYon range ND = Not tlatected at cr above the LOQ N = Recovery is out of crime P = The RPD behveen two QC columns exceeds 40% H = Out of holding time W = Reported on wet weight beats Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 54 of92 ICP-MS Metals Client: ERM NC, Inc. Laboratory I D. V D04003-024 Description: FD-01-WG-20200331 Matrix: Aqueous Date Sampled:03/31/2020 Date Received: 04/03/2020 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: VD04003-025 Description: FD-02-WG-20200401 Matrix: Aqueous Date Sampled:04/01/2020 Date Received: 04/03/2020 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020E 1 04/09/20201622 BNW 04/08/2020 1547 50254 1 (Sulfate)300.0 1 04/09/20200301 HKL 50458 1 (TDS) SM 254OC-2011 1 04/06/2020 2332 MOM 50136 CAS Analytical Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 990 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 150 5.0 ug/L 1 Sulfate 300.0 38 1.0 ni 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 2540C- 160 25 ni 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 1300 50 ug/L 1 Lead 7439-92-1 6020E ND 1.0 ug/L 1 Manganese 7439-96-5 6020B 20 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not tlatected at or above the LOQ N = Recovery is out of enter. P = The RPD behveen two QC column. e—d. 40% H = Out of holding dme W = Reported on wet weight bawls Pace Analytical Services, LLC ff—ady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.00m Page 55 of92 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound ex ... dad the calibaYon range ND = Not tlatected at or above the LOQ N = Recovery i. out of cnlena P = The RPD tanw n two QC columns exceed. 40% H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 56 of92 ICP-MS Metals Client: ERM NC, Inc. Laboratory ID. V D04003-025 Description: FD-02-WG-20200401 Matrix: Aqueous Date Sampled:04/01/2020 )ate Received: 04/03/2020 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020E 1 04/09/20201651 BNW Prep Date Batch 04/08/20201547 50254 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020B 400 40 ug/L 1 Barium 7440-39-3 6020B 46 5.0 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 600 50 ug/L 1 Lead 7439-92-1 6020E ND 1.0 ug/L 1 Manganese 7439-96-5 6020B 18 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO=unit of 0... iitation B= Detected in the method blank E=Quantitation of.mpound exceeded the.libretion range ND = Not detected at or above the LOQ N = Recovery ii out cif enter. P = The RPD beh — two QC column. exceed. 40% H = Out of holding tlme W = Reported on wet weight basis Pace Analytical Services, LLC (/omnady Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 57 of92 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 58 of 92 Inorganic non-metals - MB Sample ID: VQ50031-001 Matrix: Aqueous Batch: 50031 Analytical Method: SM 2540C-2011 Parameter Result Q Dil LOQ TDS ND 1 25 Inorganic non-metals - LCS Sample ID: V050031-002 Matrix: Aqueous Batch: 50031 Analytical Method: SM 2540C-2011 Spike Amount Result % Roe Units Analysis Date Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date mg/L 04/05/2020 1952 TDS 1500 1500 1 101 90-110 04/05/2020 1952 LOQ = Limit of Quantitation P = The RPD between two GC columns excaetls 40% N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD Is out of criteria LOD = Limit of Detection ND = Not datacted at ar above the LOD Note: Calculations are performed before rounding to avoid round-offerrors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 caw mcelab—m Page 59 of 92 LOQ =Limit of Quantitstion P = The RPD betwaen two GC columns excaetls 40% N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD is out of criteria LOD = Limit of Detection ND = Not detected at ar above the LOD Note: Calculations are performed before rounding to avoid round-offerrors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.cam Page 60 of 92 Inorganic non-metals - MB Sample ID: VQ50136-001 Matrix: Aqueous Batch: 50136 Analytical Method: SM 2540C-2011 Parameter Result Q Dil LOQ TDS ND 1 25 Inorganic non-metals - LCS Sample ID: V050136-002 Matrix: Aqueous Batch: 50136 Analytical Method: SM 2540C-2011 Spike Amount Result % Roe Units Analysis Date Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date mg/L 04/06/2020 2332 TDS 1500 1500 1 100 90-110 04/06/2020 2332 LOQ = Limit of Quantitation P = The RPD between two GC columns excaetls 40% N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD Is out of criteria LOD = Limit of Detection ND = Not datacted at ar above the LOD Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 caw mcelab—m Page 61 of 92 LOQ =Limit of Quantitstion P = The RPD betwaen two GC columns excaetls 40% N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD is out of criteria LOD = Limit of Detection ND = Not detected at ar above the LOD Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.cam Page 62 of 92 Inorganic non-metals - Duplicate Sample ID: VD04003-021DU Matrix: Aqueous Batch: 50136 Analytical Method: SM 2540C-2011 Sample Amount Result % RPD Parameter (mg/L) (mg/L) Q Dil % RPD Limit Analysis Date TDS 110 120 1 5.2 20 04/06/2020 2332 LOQ = Limit of Quantitation P = The RPD between two GC columns excaetls 40% N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD Is out of criteria LOD = Limit of Detection ND = Not datacted at ar above the LOD Note: Calculations are performed before rounding to avoid round-offerrors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 caw mcelab—nn Page 63 of 92 Inorganic non-metals - MB Sample ID: V050270-001 Matrix: Aqueous Batch: 50270 Analytical Method: SM 2540C-2011 Parameter Result Q Dil LOQ Units Analysis Date TDS ND 1 25 mg/L 04/07/2020 2256 LOQ = Limit of Quantitstion P = The RPD between two GC columns excaetls 40% N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD is out of criteria LOD = Limit of Detection ND = Not detected at ar above the LOD Note: Calculations are performed before rounding to avoid round-offerrors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelab—nn Page 64 of 92 Inorganic non-metals - LCS Sample ID: VQ50270-002 Matrix: Aqueous Batch: 50270 Analytical Method: SM 2540C-2011 Spike Amount Result % Roe Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date TDS 1500 1500 1 100 90-110 04/07/2020 2256 LOQ = Limit of Quantitation P = The RPD between two GC columns excaetls 40% N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD Is out of criteria LOD = Limit of Detection ND = Not detected at ar above the LOD Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelab—nn Page 65 of 92 Inorganic non-metals - MB Sample ID: V050294-001 Matrix: Aqueous Batch: 50294 Analytical Method: 300.0 Parameter Result Q Dil LOQ Units Analysis Date Sulfate ND 1 1.0 mg/L 04/07/2020 1445 LOQ = Limit of Quantitation P = The RPD between two GC columns excaetls 40% N = Recovery is out of criteria DL=Detection Limit J= Estimated result LOD and >DL += RPD is out of.,Kda LOD = Limit of Detection ND = Not detected at ar above the LOD Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelab—nn Page 66 of 92 Inorganic non-metals - LCS Sample ID: VQ50294-002 Matrix: Aqueous Batch: 50294 Analytical Method: 300.0 Spike Amount Result % Roe Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 20 20 1 99 90-110 04/07/2020 1531 LOQ = Limit of Quantitation P = The RPD between two GC columns excaetls 40% N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD Is out of criteria LOD = Limit of Detection ND = Not detected at or above the LOD Note: Calculations are performed before rounding to avoid round-offerrors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 caw mcelabs.com Page 67 of 92 Inorganic non-metals - MS Sample ID: VD04003-004MS Matrix: Aqueous Batch: 50294 Analytical Method: 300.0 Sample Spike Amount Amount Result %Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil %Rec Limit Analysis Date Sulfate 190 20 210 N 1 70 90-110 04/07/2020 2050 LOQ = Limit of Quantitation P = The RPD between two GC columns excaetls 40% N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the LOD Note: Calculations are performed before rounding to avoid round-offerrors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.cam Page 68 of 92 Inorganic non-metals - MSD Sample ID: VD04003-004MD Matrix: Aqueous Batch: 50294 Analytical Method: 300.0 Sample Spike Amount Amount Result %Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Sulfate 190 20 210 N 1 70 0.00 90-110 20 04/07/2020 2113 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD Is out of criteria LOD = Limit of Detection ND = Not detected st or above the LOD Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelabs—nn Page 69 of 92 Inorganic non-metals - MB Sample ID: V050458-001 Matrix: Aqueous Batch: 50458 Analytical Method: 300.0 Parameter Result Q Dil LOQ Units Analysis Date Sulfate ND 1 1.0 mg/L 04/08/2020 1536 LOQ = Limit of Quantionion P = The RPD between two GC columns exceetls 40% N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD is out of criteria LOD = Limit of Detection ND = Not detected st or above the LOD Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelab—nn Page 70 of 92 Inorganic non-metals - LCS Sample ID: V050458-002 Matrix: Aqueous Batch: 50458 Analytical Method: 300.0 Spike Amount Result % Roe Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 20 21 1 105 90-110 04/08/20201616 LOQ = Limit of Quantitation P = The RPD between two GC columns excaetls 40% N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD Is out of criteria LOD = Limit of Detection ND = Not detected at or above the LOD Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 caw mcelabs.com Page 71 of 92 Inorganic non-metals - MS Sample ID: VD04003-014MS Matrix: Aqueous Batch: 50458 Analytical Method: 300.0 Sample Spike Amount Amount Result %Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 9.2 20 29 1 98 90-110 04/08/2020 2142 LOQ = Limit of Quantitation P = The RPD between two GC columns excaetls 40% N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD is out of criteria LOD = Limit of Detection ND = Not datuded at or above the LOD Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.cam Page 72 of 92 Inorganic non-metals - MSD Sample ID: VD04003-014MD Matrix: Aqueous Batch: 50458 Analytical Method: 300.0 Sample Spike Amount Amount Result %Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Sulfate 9.2 20 29 1 98 0.00 90-110 20 04/08/2020 2202 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD Is out of criteria LOD = Limit of Detection ND = Not detected st or above the LOD Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelabs—nn Inorganic non-metals - MS Sample ID: VD04003-019MS Matrix: Aqueous Batch: 50458 Analytical Method: 300.0 Sample Spike Amount Amount Result %Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil %Rec Limit Analysis Date Sulfate 12 20 31 1 99 90-110 04/09/2020 0001 LOQ = Limit of Quantionion P = The RPD between two GC columns exceetls 40% N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD is out of criteria LOD = Limit of Detection ND = Not detected st or above the LOD Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.com Page 73 .1792 Page 74 of 92 Inorganic non-metals - MSD Sample ID: VD04003-019MD Matrix: Aqueous Batch: 50458 Analytical Method: 300.0 Sample Spike Amount Amount Result %Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Sulfate 12 20 32 1 103 2.5 90-110 20 04/09/2020 0021 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD Is out of criteria LOD = Limit of Detection ND = Not dso,oted st or above the LOD Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelabs—nn Page 75 of92 ICP-MS Metals - MB Sample ID: V050253-001 Batch: 50253 Analytical Method: 6020E Matrix: Aqueous Prep Method: 3005A Prep Date: 04/07/2020 2301 Parameter Result Q Dil LOQ Units Analysis Date Aluminum ND 1 40 ug/L 04/08/2020 2252 Barium ND 1 5.0 ug/L 04/08/2020 2252 Cadmium ND 1 0.50 ug/L 04/08/2020 2252 Chromium ND 1 5.0 ug/L 04/08/2020 2252 Iron ND 1 50 ug/L 04/08/2020 2252 Lead ND 1 1.0 ug/L 04/08/2020 2252 Manganese ND 1 5.0 ug/L 04/08/2020 2252 Selenium ND 1 5.0 ug/L 04/08/2020 2252 LOQ = Limit of Quantitstion P = The RPD between two GC columns exceetls 40% N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD is out of criteria LOD = Limit of Detection ND = Not -oted st or above the LOD Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelab—nn Page 76 of 92 ICP-MS Metals - LCS ICP-MS Metals - MS Sample ID: V050253-002 Matrix: Aqueous Sample ID: VD04003-013MS Matrix: Aqueous Batch: 50253 Prep Method: 3005A Batch: 50253 Prep Method: 3005A Analytical Method: 6020E Prep Date: 04/07/2020 2301 Analytical Method: 6020E Prep Date: 04/07/2020 2301 Spike Sample Spike Amount Result %Roe Amount Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil %Rec Limit Analysis Date Parameter (ug/L) (ug/L) (ug/L) Q Dil %Rec Limit Analysis Date Aluminum 100 97 1 97 80-120 04/08/2020 2259 Aluminum 1200 100 1300 N 1 21 70-130 04/09/2020 0113 Barium 100 100 1 102 80-120 04/08/2020 2259 Barium 52 100 51 N 1 -0.87 70-130 04/09/2020 0113 Cadmium 100 100 1 105 80-120 04/08/2020 2259 Cadmium ND 100 0.0012 N 1 0.0012 70-130 04/09/2020 0113 Chromium 100 100 1 100 80-120 04/08/2020 2259 Chromium ND 100 1.3 N 1 1.3 70-130 04/09/2020 0113 Iron 1000 940 1 94 80-120 04/08/2020 2259 Iron 1400 1000 1400 N 1 1.2 70-130 04/09/2020 0113 Lead 100 100 1 105 80-120 04/08/2020 2259 Lead ND 100 0.52 N 1 0.52 70-130 04/09/2020 0113 Manganese 100 99 1 99 80-120 04/08/2020 2259 Manganese 14 100 14 N 1 -0.013 70-130 04/09/2020 0113 Selenium 100 100 1 100 80-120 04/08/2020 2259 Selenium ND 100 0.012 N 1 0.012 70-130 04/09/2020 0113 LOQ = Limit of Quantitation P = The RPD between two GC columns exceetls 40% N = Recovery is o of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD Is out of criteria LOD = Limit of Detection ND = Not tletected st or abave the LOD Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.com Page 77 of 92 LOQ = Limit of Quenntstion P = The RPD between two GC columns exceetls 40% N = Recovery is - of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD is out of criteria LOD = Limit of Detection ND = Not deteonx] st or abave the LOD Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelab—mi Page 78 of 92 ICP-MS Metals - MSD Sample ID: VD04003-013MD Matrix: Aqueous Batch: 50253 Prep Method: 3005A Analytical Method: 6020E Prep Dale: 04/07/2020 2301 Sample Spike Amount Amount Result %Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Aluminum 1200 100 2500 N,+ 1 1280 67 70-130 20 04/09/2020 0120 Barium 52 100 160 + 1 107 100 70-130 20 04/09/2020 0120 Cadmium ND 100 99 + 1 99 200 70-130 20 04/09/2020 0120 Chromium ND 100 99 + 1 99 200 70-130 20 04/09/2020 0120 Iron 1400 1000 2500 + 1 106 54 70-130 20 04/09/2020 0120 Lead ND 100 100 + 1 104 200 70-130 20 04/09/2020 0120 Manganese 14 100 110 + 1 101 160 70-130 20 04/09/2020 0120 Selenium ND 100 99 + 1 99 200 70-130 20 04/09/2020 0120 LOQ = Limit of Quantitation P = The RPD between two GC columns exceetls 40% N = Recovery is o of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD Is out of criteria LOD = Limit of Detection ND = Not —oted st or above the LOD Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelab—m Page 79 of 92 ICP-MS Metals - MB Sample ID: V050254-001 Batch: 50254 Analytical Method: 6020E Matrix: Aqueous Prep Method: 3005A Prep Date: 04/08/2020 1547 Parameter Result Q Dil LOQ Units Analysis Date Aluminum ND 1 40 ug/L 04/09/20201500 Barium ND 1 5.0 ug/L 04/09/20201500 Cadmium ND 1 0.50 ug/L 04/09/20201500 Chromium ND 1 5.0 ug/L 04/09/20201500 Iron ND 1 50 ug/L 04/09/20201500 Lead ND 1 1.0 ug/L 04/09/20201500 Manganese ND 1 5.0 ug/L 04/09/20201500 Selenium ND 1 5.0 ug/L 04/09/20201500 LOQ = Limit of Quanntstion P = The RPD between two GC columns exceetls 40% N = Recovery ie out of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD is out of criteria LOD = Limit of Detection ND = Not detected st or above the LOD Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelab—nn Page 80 of 92 ICP-MS Metals - LCS ICP-MS Metals - MS Sample ID: V050254-002 Matrix: Aqueous Sample ID: VD04003-024MS Matrix: Aqueous Batch:50254 Prep Method: 3005A Batch:50254 Prep Method: 3005A Analytical Method: 6020E Prep Date: 04/08/2020 1647 Analytical Method: 6020E Prep Date: 04/08/2020 1547 Spike Sample Spike Amount Result %Roe Amount Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Aluminum 100 99 1 99 80-120 04/09/2020 1506 Aluminum 990 100 1700 N 1 680 70-130 04/09/2020 1628 Barium 100 98 1 98 80-120 04/09/2020 1506 Barium 150 100 230 1 88 70-130 04/09/2020 1628 Cadmium 100 100 1 100 80-120 04/09/2020 1506 Cadmium ND 100 97 1 97 70-130 04/09/2020 1628 Chromium 100 95 1 95 80-120 04/09/2020 1506 Chromium ND 100 95 1 95 70-130 04/09/2020 1628 Iron 1000 1000 1 100 80-120 04/09/2020 1506 Iron 1300 1000 2200 1 93 70-130 04/09/2020 1628 Lead 100 100 1 102 80-120 04/09/2020 1506 Lead ND 100 97 1 97 70-130 04/09/2020 1628 Manganese 100 97 1 97 80-120 04/09/2020 1506 Manganese 20 100 110 1 94 70-130 04/09/2020 1628 Selenium 100 100 1 102 80-120 04/09/2020 1506 Selenium ND 100 98 1 98 70-130 04/09/2020 1628 LOQ = Limit of Quantitation P = The RPD between two GC columns exceetls 40% N = Recovery is - of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD Is out of criteria LOD = Limit of Detection ND = Not tletected st or abave the LOD Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.com Page 81 of 92 LOQ = Limit of Quentitation P = The RPD between two GC columns exceetls 40% N = Recovery ie out of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD is out of criteria LOD = Limit of Detection ND = Not deteonx] st or abave the LOD Note: Calculations are performed before rounding to avoid round-offerrors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelab—rn Page 82 of 92 ICP-MS Metals - MSD Sample ID: VD04003-024MD Matrix: Aqueous Batch: 50254 Prep Method: 3005A Analytical Method: 6020E Prep Dale: 04/08/2020 1647 Sample Spike Amount Amount Result %Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Aluminum 990 100 1700 N 1 700 1.2 70-130 20 04/09/2020 1634 Barium 150 100 240 1 95 3.1 70-130 20 04/09/2020 1634 Cadmium ND 100 100 1 100 3.2 70-130 20 04/09/2020 1634 Chromium ND 100 99 1 99 4.0 70-130 20 04/09/2020 1634 Iron 1300 1000 2300 1 99 2.6 70-130 20 04/09/2020 1634 Lead ND 100 100 1 102 5.3 70-130 20 04/09/2020 1634 Manganese 20 100 120 1 99 3.9 70-130 20 04/09/2020 1634 Selenium ND 100 100 1 101 3.0 70-130 20 04/09/2020 1634 LOQ = Limit of Quantionion P = The RPD between two GC columns exceetls 40% N = Recovery is o of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD Is out of criteria LOD = Limit of Detection ND = Not tletected st or above the LOD Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelab—m Page 83 of 92 ICP-MS Metals - MB Sample ID: VQ50924-001 Batch: 50924 Analytical Method: 6020E Matrix: Aqueous Prep Method: 3005A Prep Date: 04/14/2020 0709 Parameter Result Q Dil LOQ Units Analysis Date Aluminum ND 1 40 ug/L 04/14/20201328 Barium ND 1 5.0 ug/L 04/14/20201328 Cadmium ND 1 0.50 ug/L 04/14/20201328 Chromium ND 1 5.0 ug/L 04/14/20201328 Iron ND 1 50 ug/L 04/14/20201328 Lead ND 1 1.0 ug/L 04/14/20201328 Manganese ND 1 5.0 ug/L 04/14/20201328 Selenium ND 1 5.0 ug/L 04/14/20201328 LOQ = Limit of Quantitstion P = The RPD between two GC columns exceetls 40% N = Recovery ie out of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD is out of criteria LOD = Limit of Detection ND = Not detected st or above the LOD Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelab—nn Page 84 of 92 ICP-MS Metals - LCS Sample ID: VQ50924-002 Batch: 50924 Analytical Method: 6020B Spike Amount Result Parameter (ug/L) (ug/L) Aluminum 100 99 Barium 100 99 Cadmium 100 97 Chromium 100 100 Iron 1000 1000 Lead 100 100 Manganese 100 99 Selenium 100 100 ICP-MS Metals - MS Matrix: Aqueous Prep Method: 3005A Prep Date: 04/14/2020 0709 Sample ID: VD04003-012MS Batch:50924 Analytical Method: 6020E Matrix: Aqueous Prep Method: 3005A Prep Date: 04/14/2020 0709 Sample Spike %Roe Amount Amount Result %Rec Q Dil % Rec Limit Analysis Date Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1 99 80-120 04/14/2020 1334 Aluminum 440 100 810 N 1 369 70-130 04/14/2020 1508 1 99 80-120 04/14/2020 1334 Barium 44 100 140 1 97 70-130 04/14/2020 1508 1 97 80-120 04/14/2020 1334 Cadmium ND 100 96 1 96 70-130 04/14/2020 1508 1 100 80-120 04/14/2020 1334 Chromium ND 100 110 1 110 70-130 04/14/2020 1508 1 102 80-120 04/14/2020 1334 Iron 560 1000 1800 1 123 70-130 04/14/2020 1508 1 104 80-120 04/14/2020 1334 Lead ND 100 100 1 104 70-130 04/14/2020 1508 1 99 80-120 04/14/2020 1334 Manganese 18 100 120 1 98 70-130 04/14/2020 1508 1 101 80-120 04/14/2020 1334 Selenium ND 100 99 1 99 70-130 04/14/2020 1508 LOQ = Limit of Quantionion P = The RPD between two GC columns exceeds 40% N = Recovery is o of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD Is out of criteria LOD = Limit of Detection ND = Not —reed et or above the LOD Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.com Page 85 of 92 LOQ = Limit of Quentitetion P = The RPD between two GC columns exceetle 40% N = Recovery is o of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD is out of criteria LOD = Limit of Detection ND = Not —oted et or above the LOD Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.com Page 86 of 92 ICP-MS Metals - MSD Sample ID: VD04003-012MD Matrix: Aqueous Batch: 50924 Prep Method: 3005A Analytical Method: 6020B Prep Dale: 04/14/2020 0709 Sample Spike Amount Amount Result %Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Aluminum 440 100 810 N 1 369 0.099 70-130 20 04/14/2020 1514 Barium 44 100 140 1 94 2.0 70-130 20 04/14/2020 1514 Cadmium ND 100 95 1 95 0.66 70-130 20 04/14/2020 1514 Chromium ND 100 97 1 97 13 70-130 20 04/14/2020 1514 Iron 560 1000 1600 1 106 9.9 70-130 20 04/14/2020 1514 Lead ND 100 100 1 104 0.096 70-130 20 04/14/2020 1514 Manganese 18 100 110 1 96 1.6 70-130 20 04/14/2020 1514 Selenium ND 100 99 1 99 0.44 70-130 20 04/14/2020 1514 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40% N = Recovery is o of criteria DL = Detection Limit J = Estimated result < LOD and > DL += RPD Is out of criteria LOD = Limit of Detection ND = Not dstscted et or abave the LOD Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.com Page 87 of 92 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 v— pacelabs.com Page 88 of 92 N C1S co r- 0 a PACE ANALYTICAL SERVICES, LLC _ C Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 -pacelabs.com Page 89 of 92 PACE ANALYTICAL SERVICES, LLC Liz tV N �C C z Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vnvw.pacelabs.com Page 90 of 92 PACE ANALYTICAL SERVICES. LLC r co a V co C3 M 3 z SV �'t -A Z� A J7S `•G s our x s W w ❑ r= Uca� RN— _— — E � s 7S C] Q N ti G U g cuv Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vrn'w.pacelabs.com Page 91 of 92 PACE ANALYTICAL SERVICES, LLC ;n,.a. r .,•.,m.�na w.,- _.:° ram: I ,: . llw.unmt—nb,r[••kM --4 rr�rn.r rk, r,'�snlx Sample Receipt Checklist (SRC.) !`„alai• Inc„a-n.A h..rd ro• IXI I r 04.11714r20M , VF)44002 hdcaus of reec61i51 ❑ C11-1 ❑ UPS ❑ Ied:x [:I Other: ❑ Yes ®Nn 1. Wcru cuSlnd] Scu1S PNWFI( nn the cuulcr`7 Yes No NA 2. if cistody seals wem pr =t, wc-rc they intact and unbroken? pl. I limp IL): 20-0209 Chlorin- Ship Ill: NA 'I cstcd bp: LKE Original tcmperaturc upon receipt 1 Dcrivcd [Cnrre.�lcd] trmpe ,allre ,IPr'n NXipt 'a501id 51jqp-Ctlp ID; Nr1 4.2 ;4.2 eC 2.9 i2.8 'C NA rNA °C NA rNA aC _. Method: ®Tcmpctature Blank ❑Apainsl Roulcs TR Ctm III: 5 JR. Gun Coacuticni Factor:. 0 _ °C t'1Cl1AUd U:. WV1iYAl; ® Wet lee ❑ lce Packs ❑ Dry Ice ❑ Nate ❑ ]'as ❑ Na perannc of any cooler cscccdcd 6.01 C, arcs Project Mawgcr Notified? as Notified by: phone! email i race-tn-lace (circle one). ❑ Yea ❑ No commercial conrier•'s packing slip atmched to this =orm? 4'es ❑ No pruper cuslod� precedrucs [r linyuiyh:dr4,xrivcvl] followed? %W�, 0Yc8 NoSarnpleIDSlisted art theCOC? ® Yea ❑ No sample Ills listed on all sample containers ® Yas ❑ Nool:e•,tion date Fs lime limd ❑n the CDC? Ycs El No. 9. Wog call action date& l i nl e l Nwill n n sill ytlrnpl a vo maiuers? ❑ Yes ® Nol 10. l)id all container label infa•mation (ID, data time) agree will: the COC? ® 4'es ❑ No 11. W= tests to be perfornrod listed on the C)C? ® Yes ❑ No 12. Did tdl awuplea amine in Lhp.-apcon e cr luiners for each :est andror in gon ood cdition (onbroken, lids an, etc.)! ® Ye, ❑ No I,. Was adoyuatc sarupic vol— available': Ycs ❑ No 14. Were all :ampler received within'? the huldinc- limn nr 48 hours, •.vh'.ehn,-r comes first? Yes ® No 15. Wcrc anp samples containers missing�cxccss (circle one) samples Nnt lister) oa CC)C ❑ Yes El No ®N,1 16. For VOA and ASK-175 samples, were bubble; present>'pes-�i�e" (r++" r>c (»oar in diamcma) in any of the VOA vigils? ® Yes El Nol El NA 17. Were all ➢R0imxals1mnricnt samples rcccivrod at a pJ I of <2? ❑ Yes ❑ No 0 NA 18- V,rrrr. alI uyxuridu sacaplea n:cx:ivod al a pIi 12 and s1ilSd,: sa,n leg received at a pA.l 9`7 El Yes © Nu ® NA :vl; 19. Worc all applicable N11s7Kcsanide ph:no 625 O.S1ttd L) 46rirpl (rCG �I C['tl1dL!£d eh1crinu7 ❑ Yes ❑ No ® NA gyp- 1Lrere client re:rrnrksrreyueata (i.H n4w:sfcc dig ittivns, Ai/A95D desi.Guatinns, etc... ) correctly n•.•mscrihed from the CGC info t}rc wrmncmt dwlion in LI415P ❑ Yes Nu 21. 1Yaa the note nun,her Itsted nn the crmialner lah-1? 11 vGY, Qucrtc tl NA Sample Preaenatino (�fusf bo compltd far any samples) inrorre.-tly pseuned nr wilh-ruulapa�c.) Stnapk(s) KA Were Ireoelved i1100melly p—or-d and +vote a&-tcd acmrdir.c_ 1;.- in —aplu rwraving with NA mL of circle one: 142SO4. 11NO3, I €C:I, Na011 using SIi r -NA inre of preservarin:l MA [C rnurc ltran vac pacaar•auvc is nLvdcd, pl cast/ note in the coin meats he low. Salnplo(s) NA were mcivod vrith bubbles 16 ,»nt ht di alrierer. Sarr.ples(s) NA w r, r: n ed vith'IRC I C.5 mp/L (W419 is no) and were ,sd Listed aueordnlgly in sample rceciving vvitlr sodimn thiosul fate (N a2S201) with Shady ID1 NA SR hamode ahels appliedby: LKH Date: 04U4/2020 C:nmmenLs, Cnl[ua.irm times for smnplc's -SS-02" through "53-9d" on sarhple kxdtles du rrut maWh cullcctian times listed on ibe_ CUC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vnvw•.pacelabs.com Page 92 of 92 APPENDIX C GROUNDWATER SAMPLING LOGS www.erm.com Version: 1.0 Project No.: 0551517 Client: R.J. Reynolds Tobacco Co. July 2020 2020-04 Edwards Rd LF Rural Hall GW Report.docx WATER MATRIX SAMPLING 'I WATER MATRIX SAMPLING FIELD DATA FORMFIELD DATA FORM RM Site Name: RJRT Edwards Road Landfill Job •k: Sample Type: Circle one - ;Manl Wr Well, DPT, Surface Water, Potable WSW; other] 502068 Sam Ie ID: C _ Oats: L G Sampling Personnel: "drew H, M' Weather CanditWns: pe Clqud , C , Rain: oc+er Time:1W &> Wall e: mmF—sw—w--- ,s d up Conpw wl Well Tag Present: Yes. IiD Wall Locked: Yea. ck Present: Vea, Well ID Infe. on Ta : Yea, Well9olled: Ye R¢ Wall Cap: eo ND Well Cap Cono Man: Good, R Osier" Well Pad Condition: Cracked, , Omer Well Locatlon: Grass, ell NA+oma, Ctller, Addigonal Comments: Total Depth of Wall IT.D.I: l7 Screen Length: 5. 10, ls• 20 caner: Depth to Water D.T. :lit Well Diameter. 2, a, a i"crie"hw' Field Parameters measured with: 'ya PlIw Casing Typo; PVC, steer" Purge Rale: JOV Ml'wn Sampling DaWre: PenWelhq iAonsaon Moe, slier, one. CN— Tubing Type: p&vAws&w measuri Paint: TOC 0111er. Pump Intake (lt below M.P.)! j4 00 Color- Odor: Yea. No Time: min Volume Forged DTW: feet Temp pH aid units SpC uSkm D❑ m IL ORP mV Turb NTII Cammenls' fAM.11milm Cmerla° (gallons lave rope bdopy° +e- 0% •F 0.1 urk •t- 9% •F 10% •t. n0a1V .1. logo 14 i;_ t6l O f,. -'P zsnEj 0,61 15 -'i 16,1 +S 7. Ic 7 l� z Z S L z. t 8•d IU 6 is P. - 0,G '✓. y` as CG c f .3 G 5. 6.5 f zce r9-Lc - 1 vi.g 66, 19, 3Fi 86 C, —1. C, .Is Ofldal Samu4na Dale & Time: 01 to -'-to t rggc Sgmotes Cocecxed: AnalWs Reouested: Preservative- Hold Thne ldsysl: LW; rrol [I I - oo ra1'exunM V Nezr,d xrl,.+l Yr i'+Yrs w nrwM9 Y reYcr rru��pirN wrn ui� x.'1 e. rnwl nY. xN hm`n � - a.�eam..w,u owed a iare..ni Ikw amY..w•. nnrerwen W-+aYeiwek..wrenwwnrwnlntr.fxM rynrw Nwbwnen runw,aregera..k..�_... at m,av/' I, of ii. FR M Site Nance: RJRT Edwards Road Landfill JJ Job #: 5D2068 Sample Type: Circle one onitor well DPT, Surface Water, Potable WSW: other) Sam to ID: • .. 70 2 0,3 3 1 Date: Sampling Personnel: Andrew H k=l Weather Conditions: Su PwWclowjRain. ovlra Time: Well T Flush surlarx Comore M. 5rkk u Can Well TagPrasent: vest Na Well Locked: , Y a Lock Pros anlx ��No Well ID info. on Ta Yee; rro Well Baited: Yet, No. igW Weli Ca : r yak'. no Well Cap Conditlow Grad/ Re ace, 01he' Well Pad Condiaon: oa, Oeler. Well Location: Grass. MphBll Corlcfete" woods. 01her. Additional Comments: Total Depth of Well fT.D.I: 1 Screen Length: 5, 10, 5, 20 ("At thec Depth to Water D.T.W):I" ' Well Diameter. � e. a, a Indies -whet. Field Parameters measured uAlh: Casing Type: r PVC, Sisal oher- Pur eRate: Amin Sampling 6eyi00: a pefistafia elornaan Germ, Baker. PDB, Otlmr Tubing Type; pWralh Measuring Paint: TOC other. Pump Intake jtt below M.P.: Color: .1 , Odor. Yes, No, Terse: min Volume Purged DTW: ffeatl Temp M) pH (91d unital W lu&bmlm DO ORP mV Turb NTI! Comments: StabaltMo. Cnteda' akonsl ilea rwle tleWwl" .F ?% W. 03 una ♦I s% H• 10% 4. 10 rill .L tots' ,•F ICI. F ,"7 l ' r�L yJ6 p {, , 101 c L/ 6 1,G! i ❑ffictiz! Somollng Dale &Time- —rT—,a --� t U_-�flr't •._. C.' Samules Cokeded-. Analysis Reques(ed:l'� 7 40 Pteseraalhw Hold Time {days): LLw �: a...rmar.�.a..�.rr�.e..e..wvn�nr.wrw�+.. •.... mna..w,...www� rr,-ia�.wfe. wnr e..r srr.. na[ nw�e m+v+a.rrwinrla. de-i.W¢•e.¢nnnrbwrne non el mW�e q. P�efNrw�h.lrnre��+wmi,nebwwneeen¢ine.Ab WATER MATRIX SAMPLING FIELD DATA FORM FRM Site Name: RJRT Edwards Road Landfill Job S: 50206B Sample Type: Orcle one oniror Wel DPT, Surface Watet', Potallle WSW; otherl sam le Id: - c'r Date: 013,3fltr Sampling Personnel: codraw AD Micheal R. Weather Conditions: 3 Pa.dy Ckedi, Cloudy. OIM Time: L ac5 Well T e: Plush $wlaoe Cpmdeaon, u Com Wall Ta Present: E& No Well Locked: No Lock Present: Iya No 1Ne11 ID Info. on Te es Ho Well Bolted: Yes, N Well Ca No Wall Ca Cpndido G ftepleoe, Omer Well Pad Condition: Cracked, RaWam ohw: Well Location: draaa AsphaB, Concrete, wauA, dlhv Additional Comments: Total Depth of Well (TZ,I: 14 Screen LeagEh; 5..6 15. 20 Texadiv Depth to Water D.T. : nl Wall Diameter: {7j e, a. 0 Irrliea-olher Ftetd Parameters measured with: Casing Type: asset au.er: Purge Rate: rn m jmm Sampling Devica= s N Monsoon- Gruldfae. Bak+, PoS, Other Tubing Type: Paly6 ana Measurin Paint: TOC other. Pump Intake fH below f P-.1: 6- Color: Odor: Yes, No Tlme: min Volume Pumed DTW: rfeetl Temp M pH (W uniis 3PC 1 uSIM DO (MOIL) ORP mV Turb NTll Comments: Slahalirmion coisra, { lane lase nela t lo4 ♦i- 3% si• 6.1!MIX 10, 391 rr- TO% ar. 16mV .0, 10Y.� 141 JQ5 ^s. 13.3 3.[.- lyz, t •So :t3. L a l v c 3.L 5 Le.'Z tr-47 IK ob s6 �s.2 z•'o a 1.3 1-".o zdr .s z.9,0. LL5• 11A,�:3 0 0 SO �: 15 13 • I +� 5 1�: Z•5 � f3•sl t Olfidal Samalirm Qi)W 8 Time• U3 131 i-0 r I q `I C samples C4lfecled: l� Bold Time rdWj Lab: zso .L C.G1� p ov 3 Srx,K{- file rprl5 O -% M-01-Wf-tot7o33i ,ue:a)CP 63/3117-0 > *- rl] • ae �.rur.sy`nrw�n a x.rw.wrnw�a.s wrra n.w+.r.....enen we. ru.w..r. ra+r m r.er rr O . •.,tynr.n wrti o-sM uLw.etl" - ' e.wrawr wwYrwlr. pl. xiµ dwuw-M1,N.rr l.arnr a.wn.aztl PwV,Arrk4wW h�wyr rya..e.,.wuao.wPaim WATER MATRIX SAMPLING FIELD DATA FORM .Jame: RJRT Edwafda Road Landfill ipie Type: Circle one MonlWr web T, Surface Water, Potable WSW' le ID: f•TT ''C•`�it r.D" ipling Perspnn9k ea 0 R- Job M soma �0 e: Flesh $urtace cmnplsaan, va Cam span Wall Ta Present: Na .poked: No t,pck Present: No Well ID Info. on TaI No felted: yes, Na Well Ca No Well Cap Carldlflon: Replace. darer ad Condiden: Gbad, Cracked. ReWaC& ONar Well Locatlon: Grass, Aal1Rs, Concfeta• 011-er Iona$ Comments: Depth ofscreen Length: 14 vs, feetalher i to Water D.T. • nl 3 11 Well ➢lametel: r• p 9 inmes-0srr Parameters monsured with: y5I 7 Casing Type: Seel omer r Rate: SZ) mlJ.nin Sampling ➢eviea: Pad Monsoon, Qpew-. Bala.. PDB, ohm: i a: measuring Point: TOG ether: .Intake Vt below M.P.j' l Cohr: C.0 GR Odor. Y rpm off a aT e)Y1 311 sa 1 G3aS' Semmes CallerJed Analysis RmuestM' Preservalya: Hold Timn 4uk4 Lab,- '� sy11. w+ttxws lam T�$ �-rm.wMbnn vx wr wr,tim�nN�l rFn•W w�irfr�e�rww iw �rr�.brwbawnr`vd.i nla'a/1 WATER MATRIX SAMPLING WATER MATRIX SAMPLING {'t I... C4 FIELD DATA FORM L�il� FIELD DATA FORM ARM Site Nanm: RJRT Edwards Road Landfill Job d': 502068 Sampla Type: Cirde one (Munitor Well , Surface Water, Potable WSW; other; Sam le ID: W - 0 3 A " GCl Z ) r31' - IL Data: 03 3ol LGZ0 Sampling Personnel: Andrew H. dleal R. Weather Conditions: 5 • Pe CI Gluudy Raln: paw - Tim; Its ll-.�-�• +{i Wall? F1u>dl Compietlan, Com Well Ta Present= Y No Wall Locked: Yee, Lock Pmaont: Ye Well 10 Info. od Tag.(Yflg No Well Bolted: Yes. No. A4 Weil Cap, Yda, W011 Ca Cgnd Won: Good. Replays. 0a f2 L` Well Pad Condition CracIG.M, R IXhar Well LocaUanf-cxaes, ati Conaem, woods. oe+er, Additional Comments: f Total Depth ofWall (T.D.): L, c Y Screen Length: S. 10. 16. leecou.er- Depth to Water Q.T. :III 1 05-VAWag Diameter: 2 i. 6, a A1cmu-olher. Field Parameters measured wlih: Casing Typ®: PVC 9tad ealar: Purge Rate: X 10 mLynin Sampling Device: Ira Mensoom [itu wib llaww. Poe• Of" Tubin e: Pal- one Maim ring Point: TOG other: Pump Intake (ft below M,P,j: (,1 Color, Odur: Yss, Time' min Volume P ed 0TW1 fee! Temp pH s[d units Spc uSlcm DO m IL ORP mV Turb NTJ Comments: Slaba'Mla rwex 1 lolls (see pole bui.W sh 3% N- al Ira;[ # a% iF 10% H• 10 mV .F 10% fl l2. 3 Q- } Iti T 5 i. Z t? 11 •f '1, �j ri .-,6 o' dr .C�i Lr 3 Do 13 ,f-IH 4- z s t� r 35 Official SamiaWo Date & Time: 4 i_ Samples Collected: Analyw-ieqlle6lad: Preseruativr: Hum Time idaW Lab: Mm pr•m.a..,...srawwm,.r..a..w.w m" w••agswr.q...er.w�*w m•sere..�wwn..au....w,........a.._... PI•rw�awarM.wt•e.1ia.[rr0.lnp]oM Site Namei RJRT Edwards Road Landfill Job &- 502058 Sample Type: Circle one - 2onitor W OPT, surface Water, Potable WSW; other] Sam to ID: W • U - r - Ze7Lt: AJ i Uate: v41cJ jlGa Sampling Personnel: w - eai—R Weather CondTtions: 6jjW Pa* CkWy, Claedy. Rel.: 00.r Tlrna: jjj go Weill rlurn tiwfaoa jW Well Tag Present: MNa Well Lacked: No Lock Present: No Well ID info. on Ta No WBSI Bolted: Yes No, Wa11 Ca No Well Cap Condition: Oilier Well Pad Condition: Cracked. Rapiam. Olhar Well Location: re Concrete, Wacdx OV-r, Additional Comments: Total Depth of Wall (T.D.): '4L t1C7 Screen Length: a. is. 2a re"her Depth to Water QT.: "t 81y, 0 Weg Diameter: V. i, 6, a arrAlea•odw Flafd Parameters measured with: yy 7 e, casing Type: LFW .1 mbar: Purge Rate: 180 n,Lmwr. Sampling Device: QamMo Molls Gundlaa- eMler- PUB. Cher TuWn o: Fb1jMhftm CAeasu ring Point! TOC other: Pump Intake (fl below M-P-]: 11 Color: Odor. Yes, No Time: ONO Volume Purged DTW: creap Temp pH aid Urals SpC vShm DO mcUL ORP mV Twb NTII Comments: slabalwim Cr8-0 [ bns tsee role blow ri• 3% H• p-1-1 +A 3% r1- 10% .7- 10mv .i- 10%r t7r15 6 ior.01 i-t, g 1.PJ gor,o D. R qe 10 S (45L7,00 1 .L1r7 4 i°l. C. oR•gr l . 19 ■5 , j,. '- I ,41• 5 L ,q-7 I 1 Ll 3 3 917. 6. -5 7 4 4 y.L J. Z170 =56. 7.3 Orridat Sam -PI ne Pats. & Time : is r low-w i tf b Samples Collecw: AnaLGM Requested. Preaervalive• bold Time IdaY1 Lab. HWee ni-o+..x—u..+w m e...�,.awr.rr w w�ww...awe.rn•....�..rrs r...� �, w rwry..w.w rqm. m • wuwwn ww.e.w e.a.. r.a..w.. mwwvn• n.xrew... QI• Twl b.rh.n •.t u p.lru xr •t np.11 q rays Nl.na wrrw n.>aMna r..p pe.pr.r yarar m W p q WATER MATRIX SAMPLING FIELD DATA FORM Site Marne: RJRT Edwards Road Landfill Job it; 502066 Semple Type: Circle one • onitor We OPT, Surface Water, Potable WSW: other) Sem lelM,f-w-::] Lr [,•Za:-rknW Date: O 'L ti7 Sampling Personnel: rew Weather CondlBons: PAMycloWy2 Claud , Rein; Darin Time: nq Lf S Well Type; FlomSurtaceComde u es Well Looked: No Lock Presaptr flo Well TagPresent: Well ID info. on Tag:No ea. No Well Bolted,, ves, Ho. Well Cap: No Well Cap Condition: Replaces Omer, Well Pad Condition: ersdred, Replaces pine-: Well Location: wpndl" Conmme. Warne, other Ad didona I Comments: Total Dotnh of Well (T.D.y: Screen Length: S to. t5, 26 faetathar" Depth tD Water D.: n' Well Diameter: 2 a, a Irionee•o�nr Field Parameters measured with: ! 7AO Casing Types: PVC, dnx Purge Rate: rdLhw Sampling Device: Pe-tahk. NOnaaan. eeaer, Poo. Oder: Tubing e: PaiIr one Measurri Point: TOC other; Pump Intake (it below M.P.I: 3W Color: Odor: vac Ha Time: mm Volum Pu ed I OTW: fee[) Temp OCI pH gld ungs) SpC (uskrn) DO (mg'4-1 ORP mV Turb NTU Comments! Stabahlaow Cntaro' 101W.0 {see npe hNbr/t' 11. 3% rA 0"1 LWA N. a% r4 10% O. to mV r6 f09. tr?U z, La Z- I L,n 038 1S.G' 51-,;5 lj,3L% -4•!z 3-33-6 I.M a Z" , IX 'i -17 33,9 0 33. l !f .S 0 I3'g Cl •3E( Iq-j V.s7 41. Y 31 .c] 14-55 1rrfb6 T-36 0"14 —LI, f 'fcs.1 43 I3.R. 7,3 3341 :36e —0.6 7y.1 �Sr�i 13. .3f• - , � .3C pry 3 . Official Samolino Date S Time: (W Io l I w e I a -w Samples Callecled: Analvai5 RegLest4-A: Preservative Hold Time fdays): U& wA TER MA TR►x SAMPLING FIELD DATA FORM F R M Wfe Name: RJRT Edwards Road Landfill Job al: 502068 Sample Type: Circle one onitor W OPT, Surface Water, Potable WSW; other) Sample ID: raw - - 0 .4 UL Data: E- L u to Sampling personnel: Andrew H" Micheal WeallterCondilfdrta: PardrdaMy. Cioudr, win; auw Time: f::'f S Well f!kmh Slrface Sad1 u Cam o Welf 7a Present: Nv Well Locked: Ha Lock Present: Ho Welt f6 info. on Ta Ha We119olled: v Well Ca no Welf Ca Condition: soa, Oster Well Pad Condition: Getkad. Radom, ah". Well Location: Viift AaO W, Cnwala, LVwds, curer, Additional Comments: Total Depth of Well (T.D,I: Screen Length: s, to- 16. 9D raalalher Da ih to Weser O.T. • "l Well Dtalneter; i, S, a lwvj -0 : Field Parameters measured rrllh: $i Aytc3 Casing Type: Steal 0— Purge Rake: l' 'd .1-W. Sampling Device: Peristaltic, Min-.00n Balm, PDB, ether Tubing T ens MeasuNn Point: TOC alter: Porn Intake Ift 4elew M.P.): 60 Color: Odor: Veg, No Time: min Volume Pur DTW: feel¢ Temp pH sid units SpC u51an ❑O fL ORP mV Turb NTU Comments: $lahelvatlan cmwi,w fwgom tees rote below a1. 5% aF 0.1 uml rF $% N- 10% ♦1- 10 mV iF 1o%, f Ca L.3 6.1 5•.2C -ZZ6. 7.1 L 'S5-y '1Z,'3 -L-A i 5.6 U( . b x. a,4 I03,' Ixm r a.v 11 5�• 11L 11,r+ t-S-A 'G'IG,-4 .rid ljqpt "&• yo , its 4,6, S x +- !q •t-' I S. till . 7-a i1. f -0 . S'3 i 16rl $' G Z -Al. S 7,01 Ils.'I S. Z,3 gs 53.5'3 i. 3 S S,4 L .❑ 6 f' - r t. 11 Q Ofhdal UnoUna Date & Time fill rnLl Lv f 13 ZS Samples Collected: Analvake Requested: Pneservalive: Hold Time ldaval. taL rhea: lu- w.u,rw..drry srn.Irr re. tiw �.wra�r nrra rr.�way rn nn,wra r, W en re nrre«iwn p,-m.n..rnri.r...rar wwruerwr.m.,�n�+.rww�.. W,-feu h..ee.nFrr6rYulW arw�ssp.P.pa,W iebaxrrwrrrewnr.re 4.�lan, .. e., n,ovnl 4 WATER MATRIX SAMPLING WATER MATRIX SAMPLING FIELD DATA FORM FIELD DA TA FORM Site Name: RJRT Edwards Road Landfill Job #; 502068 Sample Type: Circle one onI[ar Wei OPT, Surface Water, Potable WSW; other] Sample ICI 11..a„ • - h]G-7-- . UcA caL ❑ass: Olt r ❑ L 1 r-t? SamplingPersonnel; q H. m Weather CondltlonS: pe.dyclo dy. Claud . Rehr; Haler Tim: ' • O Well Tye: Fiueh Swf-- cwn etion. 6;-UPCmaMq> WallTall Present: fQ No Well Locked: I& No Lock Present: "0 Well ID Irdo. on Ta : fio WeII Rotted: Yes, Rp, Well CaYes. no Well Ca Condition: wlpw, Other, WeII Pad Condition: C4a0e4. Replaw. Cmrrr. Well Location: . AephelL Cone Woods. Ohre+ Additional Comments: Total Depth of Well (T. D.I: 't, 5 471 Screen Length: 5, 10, is. 4 p lieei•aehar Da 1h to Water D.T.W : i'l 110. O WeII Diameter: fnchesmlher. Ffald Parametersmeasured wills M.i Y. ji-O Casing Type: glad cow. Purge Rate: 1 y mLeein Sampling Device: n netaldp. 10 u n. PDBer , out Tubin Typo: Pone ens MeaSurlh Point: TOC other.Beier. Pump Intake lit below M.P.): -L S Color: Odor: Yes, No Time min Volume Purged [fTW: (feet) Temp 9C pH S!d units SpC u81cm DO mil. ORP mV Tuft NTU C0m1nanls: Stakefaaiian Cfaw:h' eayre Isae r.Me i H• 0% H- 0.1 unit a4 Sib .4 10% a♦• 10mv a} tall' ti3ai u.3 Ls.l L"i.L7' i 3. -z•L to9, s 13.3 6 ❑ 10,F'i1 H •7 ❑r9L -sL.M 15.K p ll 16-6 1,11 Fi 173.`t5 ig.q 11•3$ 440 0.�Z t 3 ta3 u ,bCl 6•7- 11.34 k 'r-S -lc.•LC]j .'# t S tip.0L 184 ti. r6 v I, t s i. + he a• t - O o. Ofagl SaMWM Date&Time: ZV Analysis Raouesied: Preservative: Hold Time ldaysY I& ds�F: ro-or w.�: ,.,...e.w a,w.�w...�,.....,,...,..e..... .aern ERM Site Name: RJRT Edwards Road Landfill Job X; 502068 Sample Type: Circle one - {Monllor Well, OPT, Surface Water, Potable WSW; er Ir TC-TC Sam IeID: e j4> Date: Sampling Paraannel: ioheal R. Waadter Conditions: su 07oue , lran other Time: l 6 Well T e: Fkah armm Cwc1w n, l K Up CongdM Well Ta Present: Ye Well Lacked. no Lock Pmen No Wall tD info. m Ta : Yee. No Well 9olted: Yes, Well Ca No Wev Ca Condltlon. 11 Ou+ar, Well Pad Condition: Cana Crad:eo. EteTaaoe. aher Welt Localfon: c.aea, ' s, corrinle, s, Omer Additional Comments: Total Depth of WeII fT.D.p Screen Length.- & 10. 16. 20 rmt-"li r. Depth to Water AT.ft i I 7 WeD Diameter: 1I 2, a, a, a Inds asp Field Parameters measured WIN Casing Type: [Pve VAxN oNer Purge Rate! mu Sampling Device: P&issaic- M"m Crundtoa EIVe Milk Wwr Tubinge: Measuring Point: TOC other: Pump Intake (ft below M.P.): Color: Odor: Yea, No Time: min Volume Pu ed DTW: feel Temp r'c pH sid umisl SpC uSrcm DO m rl OPP mV Turb m Comments: sFa6aizenon Cdreria' [see nde 6BWv/i' 3% 01 up 7 alb 10% 10 mV � ' !� a !_ u �rT71 S P Official Samolino Data & Time. MH 1 21 -LO i 1315— Samples Collected: Analysis Reauesled: Press live, Hold Ti— fdaysk ,LW. irl-ws, iraw. i.� w wy..�y.A.eu �tirq udu.r�y>.,Yw.,u�.p�.fy w e,.� w e.,.Mnlur wewrw a-r.we..ar.iw.wvar.arnarnralr Al r..�arw,nw�,r.aH�.rnwme�v m«.rrr�wrai .i a.cn -%is WATER MATRIX SAMPLING FIELD DATA FORM ERM SO Name: RJRT Edwards Road Landfill Sample Type: Circle one - IMonitor Well, OPT, Surface Water, Potable WSW; Job $' 502M Sam IeID: }'2- 7,1 114c,• Dale: O [� Sampling Pendnnel: raw H, fcheal R Weather Conditions: Sunny, CIaNr, Ran; Ce+er Time: Weil T e: Flush yLdaoa Cots Bann, on Well Ts Present: Yes, WB11 Locked: � Na Lock Presen : Ha Well ID Info. on Ta Yea, No WeD Boiled: Yes. ROAD Well Ca No Well Cap Condigan: RepUca, Cora. Welt Pad Condition: Cwod, c.dkmd, R Other Well Locatlon: G s ,—AWaik Conuete ad-; m Additional Coments: Total Depth of Wall ITJ3.j: 1 7 Screen Length: s. io, is. 20 6si•carer, Depth to Water D.T. : n1 VI. Well Diameter, - 2. 6, a, $ Inchaaclhar- FIeld Parameters measured with: NA Casing Type: . Suer oars'. Purge Rate: N ml.lmin Sampling Device: Ponstalric- Monacan. GrwtNw, Ppg, Clhar TuNno jypc > dyelMb Measuring Po}nL• TCC other - Pump Intake Ift below M.P.): Color: Odor. Yas- No Time- min Volume Pu od I) W feel Temp C pH std units w uSkm OO CRP mV Turb NTU Comments: Stsbgk a lon CriWia' atrna lees noes below]' H. 99'e 0- 0.1uNr 1- SW, +1- 10% +r- 10mV +A 1d%r r rxrsi7 OfSdal Sometiae Dale & Tme: 0,11 d 11 ty r 14W, semek s Collected- Analvais Recuestea Preserva ft Hold Time Movak Lab- ff4lah trl- oe w....wa.pa m rs.err a»rs.n.rwwmw..rr�o k,rwr.•Mwrrwv rwn w car a ieniv wrw rx ie..�, pi-rerwr».s..x.r e W Mu.. _. at m W-1s q P.ru+e r..w s .wee u r,.rnr.rcp aey w«Arwi wxwal .� W.n.a WATER MATRIX SAMPLING l FIELD DATA FORM RM Sfte Name: RJRT Edwards Road Landfill Sample Type: Circle: one - (Monitor Well, CPT, Surface Water, Potable WSW; Job S; 502WIS Sample 10: -• w zip u' L Date- OLI I + jCJ 4U Sampling Personnel: - Micheal R Weather Conditions: S.+ary. and C im'lr, C , RaiiO Other Time: Well Type: Flush Surface Cwplebw. Up CampYSian Well Tag Present: vex Well Locked: No Lack Present No Well ID info. on Ta vas, Well Well Bolted- Yes Na Weli Cap-(ft No Well Ca cc nd Blan: Replace, Oil— Pad Condition: Good• rmcl, d, Reol c . Qther. Well Location: crass, Asphaa. C W= oa>er, AddNtonaI Comments: Total Dapth of Well [T,13 j: Screen Length. 5, 10, 15, 2p feet -carer De oth to Water O.T.W : 01 3,(.1 Well Diameter. 2, A. a, a uohasalnar F leld Pa ra mole rs measured with: wq Qning Typet g= Steel oerer: Purge Rafe- •— mfhain Sampling Device: r%tisleltk. Monwm. Gnindre%LBai19DPDl3. Omar. Tubing e: Measuring Pont: TOC olher: Pump Intake Ift below M.P.): "PF Color: Odor: Yea. No Tlme: min Volume Pu ed OTW: teal Temp cc) pH (std units SpC uSlcm d0 oRP mV Turb NTU CAmmenls- Gish wim Cni.ro' store tax rote helnaf' 'A 3% +ti o., uni. .I- 3% w. 10% r1- to my 1e4d' ,e r J r» ro z Official Sampling Dale & Timer 6'-jl1..r1 zz? r 1 Z (X,> Samples Collected- Analysis Reauestea Pn:senaiela: Held Time fdaysi: L N n rq • rae�ewavew Cry m rn rw.+r �. vrw�.a PI4 r.e.r rw w a Hrwre n mawre --ar ni 0.st k WATER MATRIX SAMPLING FIELD DATA FORM FIR AA She Name- RJRT Edwards Road LandkR Sample Type: Circle one - (Monitor Well, OPTr, urface Wata Job d: *table WSW; outer) 562M Sam leld: L•1.F►1C� =Je- date: r [-J� C c] I Ci Sampling Parsonnal: drawH. rhe5i•R- Weather Conditions: Swm. rd C Ckludy. Rain; vaw Tlma: •ct. Well ? NUMS&ldf Coen &kk U ccrn eeion Wan Tog Pr¢Gen1: Yes. No Well Locked: Ves, No Lack Present: Yes. No Wdi Id Info. on Tag: Yea No Well Bolted' Yn. No, too Well Cap; Yea No We11 Cap Condition: Good, e Cm—_ Woll Pad Condition: Good, Cracked, 0— Well Location: Grew A&Ftwk Ccaarele, woods. Olhw, Additional Comments: pA Total Depth of Well (T.D.): O A Screen Lenglh: 5, 10, 15. 20 feabad.ar 00 Ih to Water JDJ,ft r" pil Wall Dlameter: 2. 4, S. a eeiles.lhx: O} 9 Field Parameters measured with: Y&•'dC j'Tw-A Casing Type: PVC, Seed otw: Purge Rape: mU in Sampling Device: PerisiaMc. Monsoon. C—arm, Beier• POB, phar Tubin Meas LI(Ing Point. TOO olds' Pump Intake (it below M.P.): d.>q Co[ar: Odor: yes, Na Time, (mini Volume purged DTW,- feel Temp pH Std units SpC uSkm) DO (mgfL ORP my Turb NTu Comments. SfibalirAw CmErwl 11-6 (see r m h4 wl' +i- .1% "I 11.1 unit -1- 3% 4. 1095 N. 10 mV •1. lost' a - -11- a n.w A j 0 7c• r ao�ty G,qzd 7.3 & Oar I0.1.2 d3. Z41.4 �5.3e�. Lce2[7 rn u ps Lt - iI- J 6.S- xxy r Lf9. a 56•6 - i-Zvw010 , —11-A 13. IR f5 1Z.s -L 1O. S •r1a•4a - of n Tt'lb 1.1 13• Ss' fi7- z�wv�c I l'• f •c TrL RC, 4 %4 (C.' 1� .r $i-?0-W,%-w - - 65 K1Z. If1l# 2`l. SS-4r]-w5-dawnsal - L•�I 7,l •f 36 S »nL-w-aezcxr - t,'l ,de 91 Y•F �i. 31•a SS-3�-wS-yoLncKt �. -VI 9(9da15amolino Rate & TIMw 1 Samples CWWded: Analysis Reweeted: Presenahve: Hotd Time fdeval L& Ewa 1n •e.weur. a.pe w w•rerr..,el.� w V v`+.�K m wes. wr�pxw� rmv� b I. rwr�p m Mxw w.we fry.ww vm oerw. mw ir«I w...wnin.wuw.. ryiay�yp�ww,p ie C.I•�0.y 01e(auni eyrp rMwarawK..wwwryLYegdware wew0.lwµum ERM has over 160 offices across the following countries and territories worldwide Argentina The Netherlands ERM's Charlotte, NC Office Australia New Zealand ERM NC, Inc. 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