RA-3888_23409_CA_MRP_20200107

Groundwater Monitoring Report
Cary Beverage
526 E. Chatham Street
Cary, Wake County, North Carolina
NCDEQ Incident #23409
ATC Project No. SLP2340904
January 7, 2020

TABLE OF CONTENTS

1.0 SITE IDENTIFICATION ......................................................................................1
2.0 EXECUTIVE SUMMARY .....................................................................................2
3.0 SITE DESCRIPTION .............................................................................................3
3.1 Site Characterization ................................................................................3
3.2 Site Background .......................................................................................3
4.0 GROUNDWATER CHARACTERIZATION......................................................6
4.1 Groundwater Sampling ............................................................................6
4.2 Laboratory Analytical Results .................................................................7
5.0 CONCLUSIONS .....................................................................................................8

TABLES
Table 1 Well Construction and Groundwater Elevation Data
Table 2 Groundwater Analytical Results
Table 3 Historical Groundwater Analytical Results
Table 4 Natural Attenuation Parameters

FIGURES
Figure 1 Site Topographic Map
Figure 2 Site Plan
Figure 3 Groundwater Elevation Contour Map
Figure 4 Dissolved Benzene Isoconcentration Contour Map
Figure 5 Other Contaminants of Concern Map

APPENDICES

Appendix A Field Notes
Appendix B Laboratory Analytical Results

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2.0 EXECUTIVE SUMMARY

ATC Associates of North Carolina, P.C. (ATC) has completed a Groundwater Monitoring Report
(GMR) for the former Cary Beverage site. This report documents a groundwater sampling event
conducted at the site on September 17, 2019. The GMR is being performed based on an August 28,
2019 Task Authorization (TA-04) by the Trust Fund Branch of the Underground Storage Tank
(UST) Section, Division of Waste Management, North Carolina Department of Environmental
Quality (NCDEQ). The work is performed as part of State Lead Contract #N14007 between
NCDEQ and ATC.

The former Cary Beverage site is located at 526 East Chatham Street, in Cary, Wake County, North
Carolina. The former store is currently divided into two sections operated as a commercial hair
salon (Alberto’s Hair Salon) and a church (Iglesia Bethel). Eight monitoring wells (MW-1 through
MW-6, MW-8, and DMW-1) are located on the site, and one monitoring well (MW-7) is located
off-site, across the adjacent roadway. A receptor survey of the surrounding area, conducted during
the previous sampling event, indicated that no water supply wells were identified within 1,000 ft of
the site. In August 2015, the location of two on-site USTs (UST-4 and UST-5) was confirmed via
geophysical designating and ground penetrating radar (GPR) activities. The USTs are located
adjacent to an existing underground fiber optics conduit, a private water line to the on-site building
and overhead utilities and are located beneath the sidewalk that runs parallel to East Chatham Street.

On September 17, 2019, ATC personnel mobilized to the site to collect groundwater samples and
measure groundwater elevations. Groundwater elevations and samples were collected from
monitoring wells MW-1 through MW-8, and DMW-1.

Groundwater elevations, measured during the groundwater sampling event on September 17,
2019, indicate the local groundwater flows in a southwesterly direction across the site.

The laboratory analytical results indicated the presence of petroleum hydrocarbon compounds at
concentrations above 2L Standards in monitoring wells MW-1, MW-2, MW-4, MW-5, MW-6,
MW-7 and MW-8. Additionally, benzene concentrations detected in MW-1 and MW-2 exceed
the Gross Contamination Level (GCL) of 5,000 micrograms per liter (ug/L). Concentrations of
1,2-Dichloroethane were also detected above GCLs in MW-1 and MW-2. Methyl Tertiary Butyl
Ether (MTBE) concentrations in MW-2 were also detected above the GCL. LNAPL was not
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detected during this sampling event. The horizontal and vertical extent of the contaminant plume
has been defined to the GCL standards.

Although the Town of Cary previously requested the removal of the two orphan USTs in lieu of
abandonment in place, ATC believes that this effort would not be cost effective and could
damage portions of the East Chatham Street right of way. Costly site restoration would then be
required. ATC recommends postponement of the UST closure activities and instead focus on
site remedial efforts for site closure. ATC recommends the installation of an air sparge well and
performing enhanced air sparge and AFVR events to reduce the VOC concentrations in MW-1
and MW-2. Groundwater monitoring would be performed subsequent to the air sparge and
AFVR events.
3.0 SITE DESCRIPTION

3.1 Site Characterization
The former Cary Beverage site is located at 526 East Chatham Street, in Cary, North Carolina.
Currently, the site consists of a single one-story building (former store) that is divided into two
sections operated as a commercial hair salon (Alberto’s Hair Salon) and a church (Iglesia Bethel).
The remaining area of the property is covered with asphalt, which serves as the parking area.

A site topographic map is included as Figure 1 and a site map depicting monitoring well locations
and other pertinent site features is included as Figure 2.

3.2 Site Background
The former underground storage tank (UST) system consisted of one 3,000-gallon (UST-1), one
6,000-gallon (UST-2), and one 10,000-gallon gasoline (UST-3) USTs, a dispenser island, and
associated product lines. UST-1, UST-2, and UST-3 were each located in a single UST basin
along the west side of the site. These USTs were closed by removal in November 1993. Soil
samples collected during the UST closure identified total petroleum hydrocarbon (TPH) gasoline
range organics (GRO) concentrations exceeding the regulatory standards at the former dispenser
island, located on the north side of the site.

In August 2001, an orphan UST (UST-4) was identified along the north side of the site, beneath
the concrete sidewalk, within the NCDOT right-of-way. The size and contents of the orphan UST
are unknown.

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In 2004 and 2005, four Type II monitoring wells (MW-1, MW-2, MW-3, and MW-4) and one
Type III monitoring well (DMW-1) were installed at the site as part of a Phase II Limited Site
Assessment. Petroleum constituents were detected in soil and groundwater samples collected
from the former dispenser location exceeding their respective regulatory standards.
Additionally, benzene concentrations identified in MW-1 exceeded the GCL of 5,000 ug/L. A
receptor survey of the surrounding area identified one active water supply well, approximately
750 ft from the site. The site was subsequently ranked as High Risk by NCDEQ.

In 2001, a second orphan tank (UST-5) was identified beneath the sidewalk, within the NCDOT
right-of-way, along the north side of the site.

In May and June 2010, a comprehensive site assessment (CSA) was performed at the site. Four
additional type II monitoring wells (MW-5 through MW-8) were installed at, and adjacent to, the
site. LNAPL was identified in MW-1 (0.4 ft) during the associated groundwater sampling event.
Petroleum constituent concentrations identified in MW-2, MW-4, MW-5, MW-6, MW-7, and
MW-8 exceeded their respective NCAC 2L Groundwater Standards (2L Standards).
Additionally, concentrations identified in MW-2, MW-5, and MW-6 exceeded their respective
GCLs. Several soil borings were advanced at the site during the CSA activities. Petroleum
constituent concentrations were identified in several soil samples, exceeding their respective soil-
to-groundwater maximum soil contaminant concentrations (MSCCs). Two soil samples,
collected between the locations of MW-1 and MW-2, at depths ranging from 3 ft to 10 ft bgs
(below ground surface) contained petroleum constituents exceeding their respective residential
MSCC standards. Three additional soil samples, collected at depths ranging from 18 ft to 24 ft
bgs, also contained petroleum constituents exceeding their respective residential MSCC
standard; however, it is likely that these samples were likely collected from within the smear
zone, caused by seasonal fluctuations of the impacted water table.

A 96-hour mobile multi-phase extraction (MMPE) event was performed at the site between
February 25, 2013 and March 1, 2013. The MMPE event included the removal of LNAPL and
petroleum impacted water from wells MW-1, MW-2, and MW-8. On March 19, 2013, LNAPL
was identified in MW-1 (0.05 ft), MW-5 (0.4 ft), and MW-6 (0.4 ft).

A second MMPE event was conducted at the site between August 19, 2013 and August 23, 2013.
The MMPE event included the removal of LNAPL and petroleum impacted water from wells
MW-1, MW-5, and MW-6. On September 5, 2013, during a groundwater sampling event,
LNAPL was identified in MW-2 (0.13 ft) following the purging process. No LNAPL was
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identified in the monitoring wells during the sampling event. Laboratory analysis identified
petroleum constituent concentrations exceeding their respective 2L standards in wells MW-1,
MW-4, MW-5, MW-6, and MW-8. Petroleum constituents were also detected in MW-1, MW-5,
and MW-6 exceeding their respective GCLs.

On September 4, 2014, ATC personnel mobilized to the site to measure groundwater elevations and
collect groundwater samples. Groundwater elevations and samples were collected from monitoring
wells MW-1, MW-3 through MW-8, and DMW-1. LNAPL was identified in MW-2 (0.25 ft), and
therefore a groundwater sample could not be collected from the well. An updated receptor survey
was also performed for the site and surrounding properties during this period. Public water is
available to the site and surrounding properties. One previously identified water supply well
(WSW-1) was confirmed to have been abandoned by the Town of Cary in January of 2014. No
other public or private water supply wells were identified within 1,000 ft of the site.

On July 1, 2015, Cardno EES conducted geophysical designating and ground penetrating radar
(GPR) activities at the site. Two on-site USTs were identified on the site (Figure 2). The two
USTs partially extend into the Town of Cary right-of-way and partially overlain by a concrete
sidewalk. The USTs are approximately 6 to 8 ft from the adjacent road curb. A private water line
was identified between the two USTs, running from the water meter to the onsite building.
Furthermore, an underground fiber optics line was identified running beneath the concrete sidewalk
and overhead utilities were observed above the USTs.

ATC conducted a groundwater sampling event at the site in October 11 and 13, 2016. ATC
submitted the results of the sampling event in a report dated January 3, 2017. The report
recommended the abandonment-in-place of two orphan USTs located at the site, performing an
AFVR event on monitoring wells MW-1, MW-2, MW-5, and MW-6, and continuing to sample
the existing monitoring wells and select water supply wells.

ATC submitted a Groundwater Monitoring Report on February 16, 2018 documenting a December
11, 2017 8-hour AFVR event and groundwater sampling event. Concentrations above 2L Standards
were present in monitoring wells MW-1, MW-4, MW-5, MW-6, MW-7 and MW-8. Additionally,
benzene was detected in MW-1, MW-5, and MW-6 in excess of the GCL. Concentrations of 1,2-
Dichloroethane were detected above the GCL in MW-1. The horizontal extent of the contaminant
plume has not been defined to the 2L Standard to the north, south, or west. Additionally, the extent
of benzene has not been defined to the GCL in the westerly direction. ATC recommended that the
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two orphan USTs located at the site be closed in place due to the presence of underground and
above ground utilities and their proximity to the roadway. ATC also recommended performing at
least two quarterly AFVR events to reduce the VOC concentrations in MW-1, MW-2, MW-5, and
MW-6. Although the owner of the adjacent property to the west of the site previously denied access
for the purpose of installing additional monitoring wells, ATC recommended further attempts to
gain access with the adjacent property owner.

ATC contacted and met with the Town of Cary officials regarding the abandonment of the orphan
USTs. The Town officials indicated that the orphan USTs should be removed rather than closed in
place. ATC attempted to confirm if the UST removal could be negotiated with Town of Cary.
ATC will notify NCDEQ with the Town of Cary’s response.

4.0 GROUNDWATER CHARACTERIZATION

4.1 Groundwater Sampling
ATC personnel conducted a groundwater sampling event at the former Cary Beverage site on
September 17, 2019. Groundwater level measurements were collected from monitoring wells MW-
1 through MW-8, and DMW-1, using an oil-water interface probe, as LNAPL has been detected
onsite in past sampling events. Depth to groundwater measurements ranged from 25.27 feet in
MW-3 to 28.32 feet in MW-7. Monitoring well construction details and current and historical
groundwater elevation data are summarized in Table 1.

A groundwater elevation contour map generated using the September 17, 2019 groundwater
elevation data is included as Figure 3. This figure indicates that the direction of groundwater flow
at the site is generally to the southwest, and is consistent with historical data. Field notes from the
September 17, 2019 site visit are included in Appendix A.

Prior to sampling, MW-1 through MW-8, and DMW-1 were purged of groundwater, three times
their well volumes, using new disposable polyethylene bailers. All groundwater samples were
collected from the monitoring wells using the same disposable bailer used to purge the well.
Samples were collected in laboratory-approved containers, packed in ice and delivered under
chain of custody protocol to SGS North America Inc. (SGS) in Scott, Louisiana for analyses.
Groundwater samples were analyzed for volatile organic compounds (VOCs) by Environmental
Protection Agency (EPA) Method 6200B.

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4.2 Laboratory Analytical Results
The laboratory analytical results indicated the presence of benzene concentrations above the
GCLs in monitoring wells MW-1 and MW-2. Concentrations of 1,2-dicholorethane also
exceeded the GCLs in MW-1 and MW-2. MTBE was also detected in a concentration that
exceeds the GCL in MW-2. Several petroleum constituent concentrations exceeded the 2L
Standards in monitoring wells MW-1, MW-2, MW-4, MW-5, MW-6, MW-7, and MW-8.
Compounds detected above NC 2L Standards in the sampled monitoring wells include benzene,
toluene, ethylbenzene, total xylenes, MTBE, IPE, naphthalene, 2-hexanone, isopropylbenzene, p-
isopropyltoluene, n-propylbenzene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, methyl
chloride, 1,2,3-trichloropropane, and 1,2-dicholorethane.

A comparison of the laboratory analytical results from the current sampling event (9/17/19) to
the previous sampling event (1/11/18) indicates a decrease in benzene in monitoring wells MW-
1, MW-4, MW-5, and MW-6. LNAPL was not detected during this sampling event.
Concentrations of benzene increased in monitoring wells MW-7 and MW-8; however,
concentrations remain below the GCLs.

Current groundwater analytical data is summarized in Table 2 and historical groundwater
analytical data is summarized in Table 3. Natural attenuation parameters were collected during
the groundwater sampling event and are summarized in Table 4. The laboratory analytical report
and chain-of-custody forms are included in Appendix B. Maps showing contaminants of
concern including dissolved benzene and additional contaminants of concern are included as
Figures 4 and 5, respectively.

As part of ATC’s quality assurance and quality control (QA and QC) measures, a data review of
the laboratory report was conducted. During the review, it was concluded that samples were
received by the laboratory in acceptable condition and properly preserved. The samples were
analyzed within the correct holding times, and the chain of custody was properly completed by
all parties. The laboratory QC report shows an internal blank was analyzed for each method that
was used for the original samples. The laboratory fortified blank (LFB) and laboratory control
sample (LCS) data results were also provided for each analytical method. Refer to the laboratory
reports in Appendix B for details regarding QA results for the laboratory samples and any noted
exceptions. Overall, ATC concludes that the laboratory results are usable and any exceptions do
not significantly impact the conclusions presented in this report.

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5.0 CONCLUSIONS

On behalf of the Trust Fund Branch of the UST Section, ATC has completed a GMR
documenting a September 17, 2019, monitoring event for the former Cary Beverage site, located
at 526 East Chatham Street, in Cary, North Carolina. Previous investigations at the site have
identified two orphan USTs located underneath the sidewalk, within the NCDOT right-of-way,
adjacent to the site.

Results from the September groundwater monitoring event indicated the presence of benzene
concentrations above the GCL in monitoring wells MW-1 and MW-2. Concentrations of 1,2-
dicholorethane also exceeded the GCL in MW-1 and MW-2. MTBE was also detected in a
concentration that exceeds the GCL in MW-2. Several petroleum constituent concentrations
exceeded the 2L Standards in monitoring wells MW-1, MW-2, MW-4, MW-5, MW-6, MW-7,
and MW-8.

Dissolved petroleum concentrations have decreased in monitoring wells MW-1, MW-4, MW-5,
and MW-6. Concentrations of benzene increased in monitoring wells MW-7 and MW-8 since the
last event. The horizontal and vertical extent of the contaminant plume has been defined to GCL
standard.

Although the Town of Cary previously requested the removal of the two orphan USTs in lieu of
abandonment in place, ATC believes that this effort would not be cost effective and could
damage portions of the East Chatham Street right of way. Costly site restoration would then be
required. ATC recommends postponement of the UST closure activities and instead focus on
site remedial efforts for site closure. ATC recommends the installation of an air sparge well (see
Figure 4) and performing enhanced air sparge and AFVR events to reduce the VOC
concentrations in MW-1 and MW-2. Groundwater monitoring would be performed subsequent
to the air sparge and AFVR events.

TABLES
TABLE 1
WELL CONSTRUCTION AND GROUNDWATER ELEVATION DATA
CARY BEVERAGE
526 E. CHATHAM STREET
CARY, WAKE COUNTY, NORTH CAROLINA
NCDEQ INCIDENT #23409
Well ID Date
Installed
Well Casing
Depth (ft.)
Screened
Interval (ft.)
Depth of
Well (ft.)
Top of Casing
Elevation (ft.)
Ground
Elevation (ft.)
Date Water
Level
Measured
Depth to
Water
(ft.)
Depth to
LNAPL
(ft.)
LNAPL
Thickness (ft.)
Groundwater
Elevation
2/23/2006 25.42 75.59
3/19/2013 27.95 0.05 73.10
8/19/2013 26.30 0.05 74.75
9/5/2013 27.58 73.43
9/4/2014 27.65 72.86
12/9/2015 26.10 74.41
10/11/2016 26.24 74.27
12/11/2017
Pre-AFVR 30.03 70.48
12/11/2017
Post-AFVR 30.31 70.20
1/11/2018 29.84 70.67
9/17/2019 25.95 74.56
2/23/2006 26.36 74.82
3/19/2013 29.02 72.16
9/5/2013 28.00 0.13 72.79
9/4/2014 28.33 28.08 0.25 72.56
12/9/2015 21.83 78.85
10/11/2016 26.77 26.70 0.07 73.97
12/11/2017
Pre-AFVR 30.58 30.37 0.21 70.28
12/11/2017
Post-AFVR 31.30 69.38
1/11/2018 30.50 30.31 0.19 70.34
9/17/2019 26.43 74.25
2/23/2006 23.05 77.66
3/19/2013 24.97 75.74
9/5/2013 26.54 74.17
9/4/2014 26.62 73.38
12/9/2015 23.77 76.23
10/11/2016 24.80 75.20
1/11/2018 28.50 71.50
9/17/2019 25.24 74.76
2/23/2006 25.41 74.30
3/19/2013 27.76 71.95
9/5/2013 27.20 72.51
9/4/2014 27.26 71.96
12/9/2015 26.92 72.30
10/11/2016 25.87 73.35
1/11/2018 29.78 69.44
9/17/2019 25.70 73.52
3/19/2013 NM 0.4 NM
8/19/2013 27.72 1.32 74.02
9/5/2013 28.2 72.41
9/4/2014 28.09 71.81
12/9/2015 26.98 72.92
10/11/2016 26.80 73.10
12/11/2017
Pre-AFVR 30.65 69.25
12/11/2017
Post-AFVR 32.42 67.48
1/11/2018 30.69 69.21
9/17/2019 26.53 73.37
3/19/2013 NM 0.4 NM
8/19/2013 26.6 0.82 75.18
9/5/2013 28.27 72.81
9/4/2014 28.07 72.29
12/9/2015 27.10 73.26
10/11/2016 26.71 73.65
12/11/2017
Pre-AFVR 30.45 69.91
12/11/2017
Post-AFVR 32.58 67.78
1/11/2018 30.32 70.04
9/17/2019 26.55 73.81
18 18-38
5/12/10 18 18-38MW-6
5/12/10
100.71
99.71
100.61
101.01
101.18
101.08
10 10-30 29.71
MW-5 37
MW-3 34.7
7/24/04MW-1
MW-2 9/23/04 20 20-35
MW-4 9/23/04 20 20-35
20-35
35
34.5
9/23/04 20
36.5
100.51 100.79
100.68 100.99
100.00 100.32
99.22 99.51
99.90 100.21
100.36 100.76
Page 1 of 2
TABLE 1
WELL CONSTRUCTION AND GROUNDWATER ELEVATION DATA
CARY BEVERAGE
526 E. CHATHAM STREET
CARY, WAKE COUNTY, NORTH CAROLINA
NCDEQ INCIDENT #23409
Well ID Date
Installed
Well Casing
Depth (ft.)
Screened
Interval (ft.)
Depth of
Well (ft.)
Top of Casing
Elevation (ft.)
Ground
Elevation (ft.)
Date Water
Level
Measured
Depth to
Water
(ft.)
Depth to
LNAPL
(ft.)
LNAPL
Thickness (ft.)
Groundwater
Elevation
3/16/2013 30.80 72.96
9/5/2013 30.11 73.65
9/4/2014 30.22 72.84
12/9/2015 28.78 74.28
10/11/2016 28.90 74.16
1/11/2018 32.37 70.69
9/17/2019 28.32 74.74
3/19/2013 26.85 74.27
9/5/2013 27.17 73.95
9/4/2014 27.31 73.10
12/9/2015 25.29 75.12
10/11/2016 25.80 74.61
1/11/2018 29.33 71.08
9/17/2019 25.66 74.75
2/23/2006 24.10 76.74
3/16/2013 26.74 74.10
9/5/2013 18.81 82.03
9/4/2014 26.39 73.96
12/9/2015 26.74 73.61
10/11/2016 14.40 85.95
1/11/2018 28.84 71.51
9/17/2019 26.00 74.35
Notes:
3. NA = Not Applicable
4. Previous groundwater calculations obtained from the Groundwater Monitoring Report (September 2013), prepared by Crawford Environmental Services.
5. Current groundwater elevation adjusted for the presence of LNAPL using the following equation: Casing Elevation - Water Level + (Free Product thickness x specific gravity of gasoline).
6. Specific Gravity of free product used = 0.8581.
7. Top of casing elevations were re-surveyed on 9/4/14.
8. LNAPL = Light Non-Aqueous Phase Liquid.
60-65
3/9/10 20 20-40
1. NM = Not Measured
2. NS = Not Surveyed
DMW-1 60 (Inner
Casing)60
MW-7 40
9/23/04
103.76
101.12
MW-8 3/9/10 18 18-38 36
103.06 103.6
100.41 100.79
100.35 100.72
100.84
Page 2 of 2
TABLE 2
GROUNDWATER ANALYTICAL RESULTS
CARY BEVERAGE
526 E. CHATHAM STREET
CARY, WAKE COUNTY, NORTH CAROLINA
NCDEQ INCIDENT #23409
MW-1 9/17/2019 13,000 31,900 3,390 19,100 2,160 905 <250 1,530 <5000 <250 <250 <500 <250 <250 619 <250 5,120 1,400 <250 595 <250
MW-2 9/17/2019 23,700 35,700 3,400 18,000 24,200 512 <250 2,220 <5000 <250 <250 <500 <250 <250 612 <250 4,990 1,280 307 743 <250
MW-3 9/17/2019 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <10 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.20 <0.50
MW-4 9/17/2019 598 2,540 1,090 4,970 <25 <25 <25 275 <500 <25 <25 <25 67.0 <25 196 <25 1,330 366 <25 <10 <25
MW-5 9/17/2019 754 19,400 251 1,230 90.2 <5.0 <5.0 59.7 <100 <5.0 <5.0 29.2 10.7 <5.0 28.0 <5.0 221 56.8 <5.0 3.7 <5.0
MW-6 9/17/2019 3,860 20,900 2,930 9,760 <25 <25 <25 884 659 31.7 <25 <25 109 <25 305 38.1 2,310 589 73.3 10.5 42.3
MW-7 9/17/2019 2.2 <0.50 <0.50 2.0 <0.50 <0.50 <0.50 <0.50 72.6 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 4.8 <0.20 <0.50
MW-8 9/17/2019 902 2,880 2,070 7,750 <5.0 84.8 <5.0 762 881 45.3 27.4 280 159 30.3 324 <5.0 <5.0 725 <5.0 57.0 <5.0
DMW-1 9/17/2019 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <10 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.20 <0.50
1 600 600 500 20 70 0.02 6 6,000 70 70 100 70 25 70 70 400 400 3 0.04 0.005
5,000 260,000 84,500 85,500 20,000 70,000 50 6,000 6,000,000 6,900 8,500 100,000 25,000 11,700 30,000 70,000 28,500 25,000 3,000 400 NE
Notes:
1. MTBE = Methyl Tertiary Butyl Ether.
2. DIPE = Diisopropyl Ether.
3. EDB = Ethylene dibromide
4. "<" or ND = Not detected at or above the laboratory detection limit.
5. Concentrations are reported in micrograms per liter (ug/l) = parts per billion (ppb).
6. Concentrations in bold equal or exceed the corresponding NCDEQ Groundwater Quality 2L Standard (2L Standard).
7. Concentrations in italics equal or exceed the corresponding NCDEQ Gross Contamination Limit (GCL).
8. NE = Not established
ANALYTICAL METHOD
WELL ID Date Collected
6200B
NaphthaleneMethyl ChlorideAcetoneCONTAMINANTS OF CONCERN/CONCENTRATION (µg/L)n-Propylbenzene1,2,4-TrimethylbenzeneBenzene1,2-Dichloroethane Xylenes (Total)p-IsopropyltolueneIsopropylbenzene2-HexanoneTolueneMTBE1,3,5-Trimethylbenzene9. J = Indicates constituent was detected above laboratory detection limit but below laboratory reporting limit.EthylbenzeneEDBGCL (µg/L)
2L Standard (µg/L)1,2,3-TrichloropropaneStyreneDIPEn-Butylbenzenesec-Butylbenzene
TABLE 3
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
CARY BEVERAGE
526 E. CHATHAM STREET
CARY, WAKE COUNTY, NORTH CAROLINA
NCDEQ INCIDENT #23409
504.1
7/28/2004 14,500 36,200 2,980 14,200 322 162 223 785 ND ND ND ND NA ND 267 ND 1,830 ND NA 559 NA NA NA NA NA NA NA
2/23/2006 16,000 44,000 4,500 24,800 570 590 ND 2,300 ND ND ND ND NA ND ND ND ND ND NA ND NA NA NA NA NA NA NA
5/19/2010
3/19/2013
9/5/2013 8,800 22000 2,300 12,800 900 330 130 1,000 1200 120 28 ND 110 ND 340 ND 3,200 720 ND 420 NA NA NA NA NA NA NA
9/4/2014 8,800 26,000 2,500 13,100 370J <180 <0.089 <120 <2400 <54 <84 <1500 180J <120 490J <120 2,600 600 <140 ND NA NA NA NA NA NA NA
12/9/2015 16,000 38,000 2,900 17,800 1,100 480 160J 1,100 <1200 120J <55 <760 160 J <62 440 <75 4,000 1,000 <110 <97 NA NA NA NA NA NA NA
10/11/2016 19,000 44,000 3,800 21,900 2,100 960 250J 1,300 <5000 360J <500 <5000 <500 <500 770 <1000 5,300 1,400 <500 720 NA NA NA NA NA NA NA
1/11/2018 14,900 39,100 4,050 21,600 1,010 463 <50 1,290 <13000 <250 <250 <500 <250 <250 611 <250 4,420 1,150 <250 434 NA NA NA NA NA NA NA
9/17/2019 13,000 31,900 3,390 19,100 2,160 905 <250 1,530 <13,000 <250 <250 <500 <250 <250 619 <250 5,120 1,400 <250 595 NA NA NA NA NA NA NA
2/23/2006 32,000 42,000 2,200 11,400 4,300 1,100 ND 680 ND ND ND ND ND ND ND ND ND ND ND 996 NA NA NA NA NA NA NA
5/19/2010 31,000 36,600 1,930 7,510 6,320 404 165 633 ND ND ND ND ND 74 227 ND 1,600 ND ND 765 136,000 ND 8,790 NA ND ND ND
3/19/2013 34,400 40,400 3,520 17,760 5,310 307 168 1,190 ND ND ND ND 157 ND 458 499 3,500 786 ND 591 NA NA NA NA NA NA NA
9/5/2013
9/4/2014
12/9/2015 28,000 45,000 4,200 20,600 12,000 400 <44 1,100 <1200 170 J 65 J <760 230 J <62 710 <75 4,600 1,300 <110 <97 NA NA NA NA NA NA NA
10/11/2016
1/11/2018
9/17/2019 23,700 35,700 3,400 18,000 24,200 512 <250 2,220 <13,000 <250 <250 <500 <250 <250 612 <250 4,990 1,280 <250 743 NA NA NA NA NA NA NA
2/23/2006 ND ND ND ND 2.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA NA NA NA NA NA
5/19/2010 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA ND ND ND
3/19/2013 ND 0.68 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA NA NA NA NA
9/5/2013 0.24J 0.70 ND 0.52J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA NA NA NA NA NA
9/4/2014 <0.079 <0.090 <0.092 <0.18 <0.090 <0.18 <0.89 <0.12 <2.4 <0.054 <0.096 <1.5 <0.11 <0.12 <0.094 <0.12 <0.18 <0.010 <0.14 <0.19 NA NA NA NA NA NA NA
12/9/2015 <0.079 <0.10 <0.13 <0.38 <0.090 <0.18 <0.089 <0.12 <2.4 <0.10 <0.11 <1.5 <0.12 <0.12 <0.11 <0.15 <0.18 <0.10 <0.22 <0.19 NA NA NA NA NA NA NA
10/11/2016 <0.50 <0.50 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50 <5.0 <0.50 <0.50 <5.0 <0.50 <0.50 <0.50 <1.0 <0.50 <1.0 <0.50 <0.50 NA NA NA NA NA NA NA
1/11/2018 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.10 <0.50 <25 <0.50 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.20 NA NA NA NA NA NA NA
9/17/2019 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <25 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.20 NA NA NA NA NA NA NA
2/23/2006 3,500 10,000 2,100 25,900 ND ND ND 540 ND ND ND ND ND ND ND ND ND ND ND ND NA NA NA NA NA NA NA
5/19/2010 3,620 8,720 968 4,300 ND 17.9 9.5 537 ND ND ND ND ND 74.2 238 ND 964 ND ND ND 5,030 ND ND NA ND ND ND
3/19/2013 2,440 9,030 2,400 11,160 ND ND ND 645 ND ND ND ND 83.7 ND 234 123 1,720 403 ND ND NA NA NA NA NA NA NA
9/5/2013 1,500 5,800 1,600 7,600 ND ND ND 250 290 44 12J 86J 66 9J 180 ND 1,400 370 ND ND NA NA NA NA NA NA NA
9/4/2014 880 4,300 1,600 8,100 <9.0 <18 <8.9 <12 <240 35J 12J <150 79 <12 220 <12 1,500 380 <14 <19 NA NA NA NA NA NA NA
12/9/2015 1,600 7,000 2,000 9,200 <9.0 <18 <8.9 430 <240 25J 15J <150 83 <12 230 21J 1,600 420 <22 <19 NA NA NA NA NA NA NA
10/11/2016 530 2,300 1,500 8,100 <25 <25 <25 290 <250 54 16J <250 180 9.5J 200 <50 1,400 370 <25 <25 NA NA NA NA NA NA NA
1/11/2018 2,140 6,980 2,040 9,640 <50 <50 <10 448 <2500 <50 <50 <100 71.1 <50 207 <50 1,410 346 <50 <20 NA NA NA NA NA NA NA
9/17/2019 598 2,540 1,090 4,970 <25 <25 <25 275 <1,300 <25 <25 <25 67.0 <25 196 <25 1,330 366 <25 <10 NA NA NA NA NA NA NA
1 600 600 500 20 70 0.02 6 4,000 70 70 100 70 25 70 70 400 400 70 0.04 40 128 10 0.02 400 700 200
5,000 260,000 84,500 85,500 20000 70,000 50 6,000 4,000,000 6,900 8,500 100,000 25,000 11,700 30,000 70,000 28,500 25,000 70,000 400 40,000 12,800 10,000 50 NE NE NE
Notes:
1. MTBE = Methyl Tertiary Butyl Ether.
2. IPE = Isopropyl Ether.
3. ND = Not detected at or above the laboratory detection limit.
4. Concentrations are reported in micrograms per liter (ug/l) = parts per billion (ppb).
5. Concentrations in bold equal or exceed the corresponding NCDEQ Groundwater Quality 2L Standard (2L Standard).
6. GCL = Gross Contamination Limit.
7. NE = Not established.
8. LNAPL = Light Non-Aqueous Phase Liquid.
Not Sampled - LNAPL
Not Sampled - LNAPL
2L Standard (µg/L)
GCL (µg/L)
MW-4
MADEP VPH
C5-C8 AliphaticsC9-C1 AliphaticsC9-C10 AliphaticsMTBEBenzeneEthylbenzeneIsopropylbenzeneMW-1 p-IsopropyltolueneNot Sampled - LNAPL
MW-2
MW-3
ANALYTICAL METHOD
WELL ID Date Collected IPE82606200B
n-PropylbenzeneTolueneChloroformsec-ButylbenzeneNot Sampled - LNAPLEDB 1,2,4-Trimethylbenzene2-Hexanone (MBK)1,3,5-TrimethylbenzeneXylenes (Total)tert-Amyl Alcoholtert-Buyl-AlcoholStyrenen-ButylbenzeneNot Sampled - LNAPL
Not Sampled - LNAPL2-Butanone (MEK)tert-Amylmethyl etherEDB1,2-DichloroethaneNaphthalenePage 1 of 2
TABLE 3
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
CARY BEVERAGE
526 E. CHATHAM STREET
CARY, WAKE COUNTY, NORTH CAROLINA
NCDEQ INCIDENT #23409
504.1 MADEP VPH
C5-C8 AliphaticsC9-C1 AliphaticsC9-C10 AliphaticsMTBEBenzeneEthylbenzeneIsopropylbenzenep-IsopropyltolueneANALYTICAL METHOD
WELL ID Date Collected IPE82606200B
n-PropylbenzeneTolueneChloroformsec-ButylbenzeneEDB1,2,4-Trimethylbenzene2-Hexanone (MBK)1,3,5-TrimethylbenzeneXylenes (Total)tert-Amyl Alcoholtert-Buyl-AlcoholStyrenen-Butylbenzene2-Butanone (MEK)tert-Amylmethyl etherEDB1,2-DichloroethaneNaphthalene5/19/2010 17,300 28,000 2,600 11,790 1,860 318 75.4 600 ND ND 15.2 ND ND 97.3 181 75.2 2050 ND ND 222 ND ND ND 73.7 78,300 49,700 ND
3/19/2013
9/5/2013 15,000 5,800 2,200 11,600 1,700 240 46 J 460 3,900 67 17 J 260 J 90 ND 260 ND 2,100 500 ND 540 NA NA NA NA NA NA NA
9/4/2014 13,000 27,000 2,500 12,800 1,200 <90 <44 <60 4,300 <27 <42 <760 95J <62 260 <60 2,000 500 <72 <97 NA NA NA NA NA NA NA
12/9/2015 14,000 20,000 2,900 14,200 1,600 80 <8.9 590 3,700 41 J 22 J 370 J 110 <12 300 <15 2,300 590 <22 <19 NA NA NA NA NA NA NA
10/11/2016 12,000 28,000 3,200 18,600 1,400 62J <100 690 2,900 160 36J 480J 610 <100 420 <200 3,000 790 <100 58J NA NA NA NA NA NA NA
1/11/2018 15,100 30,700 2,680 13,200 893 <250 <50 762 <13000 <250 <250 <500 <250 <250 303 <250 2,000 508 <250 <100 NA NA NA NA NA NA NA
9/17/2019 754 19,400 251 1,230 90.2 <5.0 <5.0 59.7 <250 <5.0 <5.0 29.2 10.7 <5.0 28.0 <5.0 221 56.8 <5.0 3.7 NA NA NA NA NA NA NA
5/19/2010 15,800 26,500 1,830 6,570 1,180 292 94.2 958 ND ND ND ND ND 182 653 ND 1,740 ND ND 428 36,600 ND 2,650 107 8,260 53,300 ND
3/19/2013
9/5/2013 13,000 26,000 2,200 12,000 780 120 45 340 1000 66 14 J 78 J 94 10 J 280 ND 2,000 520 9.5 J 430 NA NA NA NA NA NA NA
9/4/2014 20,000 35,000 2,800 14,600 740 180 89 <120 2400J <54 <84 <1500 <110 <120 310J <120 2,000 490J <140 <190 NA NA NA NA NA NA NA
12/9/2015 22,000 48,000 3,700 18,900 160 J <90 <44 890 <1200 110 J <55 <760 170 J <62 520 <75 3,400 880 <110 <97 NA NA NA NA NA NA NA
10/13/2016 19,000 51,000 3,900 21,800 <250 <250 <250 960 <2500 180J <250 <2500 1,300 <250 530 <500 3,300 840 <250 <250 NA NA NA NA NA NA NA
1/11/2018 13,100 40,000 3,440 17,100 <250 <250 <50 1,020 <13000 <250 <250 <500 <250 <250 383 <250 2,640 673 <250 <100 NA NA NA NA NA NA NA
9/17/2019 3,860 20,900 2,930 9,760 <25 <25 <25 884 <1,300 31.7 <25 <25 109 <25 305 38.1 2,310 589 <25 10.5 NA NA NA NA NA NA NA
5/19/2010 5.9 15.4 3.3 13.7 ND ND ND ND ND ND ND ND ND ND 1 ND 2.8 ND ND ND ND ND ND ND 1,130 ND ND
3/19/2013 ND ND ND 0.56 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA NA NA NA NA NA
9/5/2013 0.39 0.53 ND 0.65 ND ND ND ND ND ND ND ND ND ND ND ND ND 0.10 J ND ND NA NA NA NA NA NA NA
9/4/2014 <0.079 <0.090 <0.092 <0.18 <0.090 <0.18 <0.89 <0.12 <2.4 <0.054 <0.096 <1.5 <0.11 <0.12 <0.094 <0.12 <0.18 <0.010 <0.14 <0.19 NA NA NA NA NA NA NA
12/9/2015 1.8 1.1 0.22 J 2.29 J <0.090 <0.18 <0.089 <0.12 <2.4 <0.10 <0.11 <1.5 <0.12 <0.12 <0.11 <0.15 0.31 J 0.24 J <0.22 <0.19 NA NA NA NA NA NA NA
10/11/2016 1.1 0.41 0.15J 1.2 <0.50 <0.50 <0.50 <0.50 <5.0 <0.50 <0.50 <5.0 <0.50 <0.50 <0.50 <1.0 0.19J <1.0 <0.50 <0.50 NA NA NA NA NA NA NA
1/11/2018 2.0 0.81 <0.50 2.6 <0.50 <0.50 <0.10 <0.50 <25 <0.50 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.20 NA NA NA NA NA NA NA
9/17/2019 2.2 <0.50 <0.50 2.0 <0.50 <0.50 <0.50 <0.50 <25 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.20 NA NA NA NA NA NA NA
5/19/2010 760 2,990 1,280 4,250 4.4 32.6 1.4 448 ND ND ND ND ND 83.1 149 59.1 1,100 ND ND 21.8 ND ND ND 0.79 19,800 38,200 3,660
3/19/2013 143 3,020 2,690 13,620 ND ND ND 2,820 ND ND 318 ND 1,150 ND 2,860 52.9 6,380 1,950 ND ND NA NA NA NA NA NA NA
9/5/2013 120 940 270 4,100 ND 12 ND 190 100 J 35 5 J 46 J 22 13 27 ND 1,100 310 ND 12 J NA NA NA NA NA NA NA
9/4/2014 240 1,300 890 4,400 <0.090 <0.18 <0.089 420 <2.4 31J 8.0J <1.5 65 10J 130 <0.12 1,200 330 <0.14 <0.19 NA NA NA NA NA NA NA
12/9/2015 460 1,900 1,700 6,000 <4.5 26 <4.4 530 <120 46 22 J <76 130 25 290 <7.5 2,300 650 <11 <9.7 NA NA NA NA NA NA NA
10/11/2016 730 2,800J 1,700 7,900J <25 41 <25 600 290 76 22J 250 240 19J 260 <50 2,600 670 <25 <25 NA NA NA NA NA NA NA
1/11/2018 587 1,720 1,910 5,550 <25 29.5 <5.0 662 <1300 120 33.0 <50 166 32.0 428 <25 2,960 814 <25 23.3 NA NA NA NA NA NA NA
9/17/2019 902 2,880 2,070 7,750 <5.0 84.8 <5.0 762 <250 45.3 27.4 280 159 30.3 324 <5.0 <5.0 725 <5.0 57.0 NA NA NA NA NA NA NA
2/23/2006 ND ND ND ND ND ND ND NA ND ND ND ND ND ND ND ND ND ND ND ND NA NA NA NA NA NA NA
5/19/2010 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
3/19/2013 ND 0.44 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA NA NA NA NA NA
9/5/2013 1 2.3 0.23 J 1.89 ND ND ND ND ND ND ND ND ND ND ND ND 0.49 J 0.14 J ND ND NA NA NA NA NA NA NA
9/4/2014 <0.079 <0.090 <0.092 <0.18 <0.090 <0.18 <0.89 <0.12 <2.4 <0.054 <0.096 <1.5 <0.11 <0.12 <0.094 <0.12 <0.18 <0.010 <0.14 <0.19 NA NA NA NA NA NA NA
12/9/2015
10/11/2016 <0.50 <0.50 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50 <5.0 <0.50 <0.50 <5.0 <0.50 <0.50 <0.50 <1.0 <0.50 <1.0 <0.50 <0.50 NA NA NA NA NA NA NA
1/11/2018 0.77 2.1 <0.50 1.8 <0.50 <0.50 <0.10 0.67 <25 <0.50 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50 0.50 <0.50 <0.50 <0.20 NA NA NA NA NA NA NA
9/17/2019 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <25 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.20 NA NA NA NA NA NA NA
1 600 600 500 20 70 0.02 6 4,000 70 70 100 70 25 70 70 400 400 70 0.04 40 128 10 0.02 400 700 200
5,000 260,000 84,500 85,500 20000 70,000 50 6,000 4,000,000 6,900 8,500 100,000 25,000 11,700 30,000 70,000 28,500 25,000 70,000 400 40,000 12,800 10,000 50 NE NE NE
Notes:
1. MTBE = Methyl Tertiary Butyl Ether.
2. IPE = Isopropyl Ether.
3. ND = Not detected at or above the laboratory detection limit.
4. Concentrations are reported in micrograms per liter (ug/l) = parts per billion (ppb).
5. Concentrations in bold equal or exceed the corresponding NCDEQ Groundwater Quality 2L Standard (2L Standard).
6. GCL = Gross Contamination Limit.
7. NES = Not established Standard
7. NE = Not established.
8. LNAPL = Light Non-Aqueous Phase Liquid.
DMW-1
MW-7
MW-8
MW-5
MW-6
Not Sampled - Dry - Well blocked at 33 feet
Not Sampled - LNAPL
Not Sampled - LNAPL
GCL (µg/L)
2L Standard (µg/L)
Page 2 of 2
TABLE 4
NATURAL ATTENUATION PARAMETERS
CARY BEVERAGE
526 E. CHATHAM STREET
CARY, WAKE COUNTY, NORTH CAROLINA
INCIDENT #23409
10/13/2016 18.62 1.56 194 4.68 102.8 >1.2
1/11/2018 20.7 1.20 32.7 4.41 216.6 NA
9/17/2019 23.5 0.86 44.6 4.45 -52.1 NA
10/13/2016 18.09 1.77 343 4.89 12.9 >1.2
1/11/2018 19.1 1.87 118 4.49 282.2 NA
9/17/2019 24.8 0.63 132.2 4.49 -16.7 NA
10/13/2016 18.57 5.83 117 4.63 169.9 >1.2
1/11/2018 20.2 0.86 53.5 5.25 95.7 NA
9/17/2019 25.2 0.45 68.1 4.99 -57.9 NA
10/13/2016 20.03 4.91 392 6.62 183.7 >1.2
1/11/2018 17 1.96 184.8 7.29 85.9 NA
9/17/2019 24.1 5.12 366.2 10.50 -56.3 NA
NA - Not Analyzed
MW-8
Analytical Method 6200B
WELL ID Date
Collected
Temperature (oC)pHConductivity (ms/cm)DMW-1 Dissolved Oxygen (mg/L)ORP (mV)Total IronMW-6
MW-7
Page 1 of 1

FIGURES
.

2725 E. Millbrook Road, Ste 121
Raleigh, NC 27604
[phone]
PROJECT NO: SLP2340903
DATE: 10/2019 REVIEWED BY: GA
Cary Beverage –Incident #23409
526 E. Chatham Street
Raleigh, Wake County, North Carolina
SOURCE: MyTopoMap.com
SCALE: 1” = 1,350’
FIGURE 1: SITE TOPOGRAPHIC MAP
SITE
N

APPENDIX A

FIELD NOTES

APPENDIX B

LABORATORY ANALYTICAL RESULTS

10/01/19
Technical Report for
ATC Group Services LLC
Cary Beverage 526 E. Chatham Street, Cary, NC
SLP2340904
SGS Job Number: LA57817
Sampling Date: 09/17/19
Report to:
ATC Group Services LLC.
2725 East Millbrook Road Suite 121
Raleigh, NC 27604
[e-mail]
ATTN: Liz Allyn
Total number of pages in report:
Certifications: LDEQ(2048), LDHH(LA150012), AR(14-045-04), AZ(AZ0805), FL(E87657), IL(200082), KY(#31),
NC(487), SC(73004001), NJ(LA007), TX(T104704186-18-16), WV(257)
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 500 Ambassador Caffery • Scott, LA 70583 • tel: [phone]
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Amy Jackson 337-237-4775
Ron Benjamin
Lab Director
Scott, LA 10/01/19
e-Hardcopy 2.0
Automated Report
50
SGS is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions
The results set forth herein are provided by SGS North America Inc.
Please share your ideas about
how we can serve you better at:
[e-mail]
1 of 50
LA57817
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................7
3.1: LA57817-1: MW1 ........................................................................................................8
3.2: LA57817-2: MW2 ........................................................................................................10
3.3: LA57817-3: MW3 ........................................................................................................12
3.4: LA57817-4: MW4 ........................................................................................................15
3.5: LA57817-5: MW5 ........................................................................................................17
3.6: LA57817-6: MW6 ........................................................................................................20
3.7: LA57817-7: MW7 ........................................................................................................23
3.8: LA57817-8: MW8 ........................................................................................................25
3.9: LA57817-9: DMW1 .....................................................................................................27
Section 4: Misc. Forms ............................................................................................................29
4.1: Chain of Custody ...........................................................................................................30
Section 5: MS Volatiles - QC Data Summaries .....................................................................33
5.1: Method Blank Summary ................................................................................................34
5.2: Blank Spike/Blank Spike Duplicate Summary ..............................................................40
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................46 123452 of 50
LA57817
SGS North America Inc.
Sample Summary
ATC Group Services LLC
Job No:LA57817
Cary Beverage 526 E. Chatham Street, Cary, NC
Project No: SLP2340904
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
This report contains results reported as ND = Not detected. The following applies:
Organics ND = Not detected above the RL
LA57817-1 09/17/19 14:30 TJ 09/19/19 AQ Ground Water MW1
LA57817-2 09/17/19 15:05 TJ 09/19/19 AQ Ground Water MW2
LA57817-3 09/17/19 10:40 TJ 09/19/19 AQ Ground Water MW3
LA57817-4 09/17/19 12:10 TJ 09/19/19 AQ Ground Water MW4
LA57817-5 09/17/19 12:45 TJ 09/19/19 AQ Ground Water MW5
LA57817-6 09/17/19 13:20 TJ 09/19/19 AQ Ground Water MW6
LA57817-7 09/17/19 10:05 TJ 09/19/19 AQ Ground Water MW7
LA57817-8 09/17/19 13:55 TJ 09/19/19 AQ Ground Water MW8
LA57817-9 09/17/19 11:40 TJ 09/19/19 AQ Ground Water DMW1
3 of 50
LA578171
Summary of Hits Page 1 of 3
Job Number:LA57817
Account:ATC Group Services LLC
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
Collected:09/17/19
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
LA57817-1 MW1
Benzene 13000 250 ug/l SM 6200B
1,2-Dichloroethane 595 100 ug/l SM 6200B
Di-Isopropyl Ether 905 250 ug/l SM 6200B
Ethylbenzene 3390 250 ug/l SM 6200B
Methyl Tert Butyl Ether 2160 250 ug/l SM 6200B
Naphthalene 1530 250 ug/l SM 6200B
n-Propylbenzene 619 250 ug/l SM 6200B
Toluene 31900 250 ug/l SM 6200B
1,2,4-Trimethylbenzene 5120 250 ug/l SM 6200B
1,3,5-Trimethylbenzene 1400 250 ug/l SM 6200B
m,p-Xylene 13000 500 ug/l SM 6200B
o-Xylene 6120 250 ug/l SM 6200B
Xylene (total)19100 250 ug/l SM 6200B
LA57817-2 MW2
Benzene 23700 250 ug/l SM 6200B
1,2-Dichloroethane 743 100 ug/l SM 6200B
Di-Isopropyl Ether 512 250 ug/l SM 6200B
Ethylbenzene 3400 250 ug/l SM 6200B
Methyl Chloride 307 250 ug/l SM 6200B
Methyl Tert Butyl Ether 24200 250 ug/l SM 6200B
Naphthalene 2220 250 ug/l SM 6200B
n-Propylbenzene 612 250 ug/l SM 6200B
Toluene 35700 250 ug/l SM 6200B
1,2,4-Trimethylbenzene 4990 250 ug/l SM 6200B
1,3,5-Trimethylbenzene 1280 250 ug/l SM 6200B
m,p-Xylene 12300 500 ug/l SM 6200B
o-Xylene 5710 250 ug/l SM 6200B
Xylene (total)18000 250 ug/l SM 6200B
LA57817-3 MW3
No hits reported in this sample.
LA57817-4 MW4
Benzene 598 25 ug/l SM 6200B
Ethylbenzene 1090 25 ug/l SM 6200B
Isopropylbenzene 67.0 25 ug/l SM 6200B
Naphthalene 275 25 ug/l SM 6200B
n-Propylbenzene 196 25 ug/l SM 6200B
Toluene 2540 25 ug/l SM 6200B
4 of 50
LA578172
Summary of Hits Page 2 of 3
Job Number:LA57817
Account:ATC Group Services LLC
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
Collected:09/17/19
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
1,2,4-Trimethylbenzene 1330 25 ug/l SM 6200B
1,3,5-Trimethylbenzene 366 25 ug/l SM 6200B
m,p-Xylene 3580 50 ug/l SM 6200B
o-Xylene 1390 25 ug/l SM 6200B
Xylene (total)4970 25 ug/l SM 6200B
LA57817-5 MW5
Benzene 754 5.0 ug/l SM 6200B
1,2-Dichloroethane 3.7 2.0 ug/l SM 6200B
Ethylbenzene 251 5.0 ug/l SM 6200B
2-Hexanone 29.2 10 ug/l SM 6200B
Isopropylbenzene 10.7 5.0 ug/l SM 6200B
Methyl Tert Butyl Ether 90.2 5.0 ug/l SM 6200B
Naphthalene 59.7 5.0 ug/l SM 6200B
n-Propylbenzene 28.0 5.0 ug/l SM 6200B
Toluene 19400 250 ug/l SM 6200B
1,2,4-Trimethylbenzene 221 5.0 ug/l SM 6200B
1,3,5-Trimethylbenzene 56.8 5.0 ug/l SM 6200B
m,p-Xylene 842 10 ug/l SM 6200B
o-Xylene 392 5.0 ug/l SM 6200B
Xylene (total)1230 5.0 ug/l SM 6200B
LA57817-6 MW6
Acetone 659 500 ug/l SM 6200B
Benzene 3860 250 ug/l SM 6200B
n-Butylbenzene 31.7 25 ug/l SM 6200B
1,2-Dichloroethane 10.5 10 ug/l SM 6200B
Ethylbenzene 2930 25 ug/l SM 6200B
Isopropylbenzene 109 25 ug/l SM 6200B
Methyl Chloride 73.3 25 ug/l SM 6200B
Naphthalene 884 25 ug/l SM 6200B
n-Propylbenzene 305 25 ug/l SM 6200B
Styrene 38.1 25 ug/l SM 6200B
Toluene 20900 250 ug/l SM 6200B
1,2,3-Trichloropropane 42.3 25 ug/l SM 6200B
1,2,4-Trimethylbenzene 2310 25 ug/l SM 6200B
1,3,5-Trimethylbenzene 589 25 ug/l SM 6200B
m,p-Xylene 6420 500 ug/l SM 6200B
o-Xylene 4630 25 ug/l SM 6200B
Xylene (total)9760 250 ug/l SM 6200B
5 of 50
LA578172
Summary of Hits Page 3 of 3
Job Number:LA57817
Account:ATC Group Services LLC
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
Collected:09/17/19
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
LA57817-7 MW7
Acetone 72.6 10 ug/l SM 6200B
Benzene 2.2 0.50 ug/l SM 6200B
Methyl Chloride 4.8 0.50 ug/l SM 6200B
m,p-Xylene 1.6 1.0 ug/l SM 6200B
Xylene (total)2.0 0.50 ug/l SM 6200B
LA57817-8 MW8
Acetone 881 100 ug/l SM 6200B
Benzene 902 25 ug/l SM 6200B
n-Butylbenzene 45.3 5.0 ug/l SM 6200B
sec-Butylbenzene 27.4 5.0 ug/l SM 6200B
1,2-Dichloroethane 57.0 2.0 ug/l SM 6200B
Di-Isopropyl Ether 84.8 5.0 ug/l SM 6200B
Ethylbenzene 2070 25 ug/l SM 6200B
2-Hexanone 280 10 ug/l SM 6200B
Isopropylbenzene 159 5.0 ug/l SM 6200B
p-Isopropyltoluene 30.3 5.0 ug/l SM 6200B
Naphthalene 762 5.0 ug/l SM 6200B
n-Propylbenzene 324 5.0 ug/l SM 6200B
Toluene 2880 25 ug/l SM 6200B
1,3,5-Trimethylbenzene 725 5.0 ug/l SM 6200B
m,p-Xylene 4740 50 ug/l SM 6200B
o-Xylene 3010 25 ug/l SM 6200B
Xylene (total)7750 25 ug/l SM 6200B
LA57817-9 DMW1
No hits reported in this sample.
6 of 50
LA578172
SGS North America Inc.
Sample Results
Report of Analysis
Scott, LA
Section 3
7 of 50
LA578173
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW1
Lab Sample ID:LA57817-1 Date Sampled:09/17/19
Matrix:AQ - Ground Water Date Received:09/19/19
Method:SM 6200B Percent Solids:n/a
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 2K0118058.D 500 09/26/19 13:02 CP n/a n/a V2K2097
Run #2
Purge Volume
Run #1 25.0 ml
Run #2
VOA List for NC, May 2012
CAS No.Compound Result RL Units Q
67-64-1 Acetone ND 5000 ug/l
71-43-2 Benzene 13000 250 ug/l
108-86-1 Bromobenzene ND 250 ug/l
74-97-5 Bromochloromethane ND 250 ug/l
75-27-4 Bromodichloromethane ND 250 ug/l
75-25-2 Bromoform ND 250 ug/l
104-51-8 n-Butylbenzene ND 250 ug/l
135-98-8 sec-Butylbenzene ND 250 ug/l
98-06-6 tert-Butylbenzene ND 250 ug/l
56-23-5 Carbon Tetrachloride ND 100 ug/l
108-90-7 Chlorobenzene ND 250 ug/l
75-00-3 Chloroethane ND 250 ug/l
67-66-3 Chloroform ND 250 ug/l
95-49-8 o-Chlorotoluene ND 250 ug/l
106-43-4 p-Chlorotoluene ND 250 ug/l
124-48-1 Dibromochloromethane ND 100 ug/l
106-93-4 1,2-Dibromoethane ND 250 ug/l
75-71-8 Dichlorodifluoromethane ND 250 ug/l
541-73-1 m-Dichlorobenzene ND 250 ug/l
95-50-1 o-Dichlorobenzene ND 250 ug/l
106-46-7 p-Dichlorobenzene ND 250 ug/l
75-34-3 1,1-Dichloroethane ND 250 ug/l
107-06-2 1,2-Dichloroethane 595 100 ug/l
75-35-4 1,1-Dichloroethylene ND 250 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 250 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 250 ug/l
78-87-5 1,2-Dichloropropane ND 150 ug/l
142-28-9 1,3-Dichloropropane ND 250 ug/l
594-20-7 2,2-Dichloropropane ND 250 ug/l
563-58-6 1,1-Dichloropropene ND 250 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 100 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 100 ug/l
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
8 of 50
LA5781733.1
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW1
Lab Sample ID:LA57817-1 Date Sampled:09/17/19
Matrix:AQ - Ground Water Date Received:09/19/19
Method:SM 6200B Percent Solids:n/a
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
VOA List for NC, May 2012
CAS No.Compound Result RL Units Q
108-20-3 Di-Isopropyl Ether 905 250 ug/l
64-17-5 Ethyl Alcohol ND 25000 ug/l
100-41-4 Ethylbenzene 3390 250 ug/l
591-78-6 2-Hexanone ND 500 ug/l
98-82-8 Isopropylbenzene ND 250 ug/l
99-87-6 p-Isopropyltoluene ND 250 ug/l
74-83-9 Methyl Bromide ND 250 ug/l
74-87-3 Methyl Chloride ND 250 ug/l
75-09-2 Methylene Chloride ND 250 ug/l
78-93-3 Methyl Ethyl Ketone ND 13000 ug/l
108-10-1 4-Methyl-2-pentanone ND 250 ug/l
1634-04-4 Methyl Tert Butyl Ether 2160 250 ug/l
91-20-3 Naphthalene 1530 250 ug/l
103-65-1 n-Propylbenzene 619 250 ug/l
100-42-5 Styrene ND 250 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 250 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 100 ug/l
127-18-4 Tetrachloroethylene ND 250 ug/l
108-88-3 Toluene 31900 250 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 250 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 250 ug/l
71-55-6 1,1,1-Trichloroethane ND 250 ug/l
79-00-5 1,1,2-Trichloroethane ND 150 ug/l
79-01-6 Trichloroethylene ND 250 ug/l
75-69-4 Trichlorofluoromethane ND 250 ug/l
96-18-4 1,2,3-Trichloropropane ND 250 ug/l
95-63-6 1,2,4-Trimethylbenzene 5120 250 ug/l
108-67-8 1,3,5-Trimethylbenzene 1400 250 ug/l
108-05-4 Vinyl Acetate ND 250 ug/l
75-01-4 Vinyl Chloride ND 50 ug/l
m,p-Xylene 13000 500 ug/l
95-47-6 o-Xylene 6120 250 ug/l
1330-20-7 Xylene (total)19100 250 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 92%70-130%
2037-26-5 Toluene-D8 96%70-130%
460-00-4 4-Bromofluorobenzene 98%70-130%
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
9 of 50
LA5781733.1
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW2
Lab Sample ID:LA57817-2 Date Sampled:09/17/19
Matrix:AQ - Ground Water Date Received:09/19/19
Method:SM 6200B Percent Solids:n/a
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 2K0118059.D 500 09/26/19 13:34 CP n/a n/a V2K2097
Run #2
Purge Volume
Run #1 25.0 ml
Run #2
VOA List for NC, May 2012
CAS No.Compound Result RL Units Q
67-64-1 Acetone ND 5000 ug/l
71-43-2 Benzene 23700 250 ug/l
108-86-1 Bromobenzene ND 250 ug/l
74-97-5 Bromochloromethane ND 250 ug/l
75-27-4 Bromodichloromethane ND 250 ug/l
75-25-2 Bromoform ND 250 ug/l
104-51-8 n-Butylbenzene ND 250 ug/l
135-98-8 sec-Butylbenzene ND 250 ug/l
98-06-6 tert-Butylbenzene ND 250 ug/l
56-23-5 Carbon Tetrachloride ND 100 ug/l
108-90-7 Chlorobenzene ND 250 ug/l
75-00-3 Chloroethane ND 250 ug/l
67-66-3 Chloroform ND 250 ug/l
95-49-8 o-Chlorotoluene ND 250 ug/l
106-43-4 p-Chlorotoluene ND 250 ug/l
124-48-1 Dibromochloromethane ND 100 ug/l
106-93-4 1,2-Dibromoethane ND 250 ug/l
75-71-8 Dichlorodifluoromethane ND 250 ug/l
541-73-1 m-Dichlorobenzene ND 250 ug/l
95-50-1 o-Dichlorobenzene ND 250 ug/l
106-46-7 p-Dichlorobenzene ND 250 ug/l
75-34-3 1,1-Dichloroethane ND 250 ug/l
107-06-2 1,2-Dichloroethane 743 100 ug/l
75-35-4 1,1-Dichloroethylene ND 250 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 250 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 250 ug/l
78-87-5 1,2-Dichloropropane ND 150 ug/l
142-28-9 1,3-Dichloropropane ND 250 ug/l
594-20-7 2,2-Dichloropropane ND 250 ug/l
563-58-6 1,1-Dichloropropene ND 250 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 100 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 100 ug/l
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
10 of 50
LA5781733.2
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW2
Lab Sample ID:LA57817-2 Date Sampled:09/17/19
Matrix:AQ - Ground Water Date Received:09/19/19
Method:SM 6200B Percent Solids:n/a
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
VOA List for NC, May 2012
CAS No.Compound Result RL Units Q
108-20-3 Di-Isopropyl Ether 512 250 ug/l
64-17-5 Ethyl Alcohol ND 25000 ug/l
100-41-4 Ethylbenzene 3400 250 ug/l
591-78-6 2-Hexanone ND 500 ug/l
98-82-8 Isopropylbenzene ND 250 ug/l
99-87-6 p-Isopropyltoluene ND 250 ug/l
74-83-9 Methyl Bromide ND 250 ug/l
74-87-3 Methyl Chloride 307 250 ug/l
75-09-2 Methylene Chloride ND 250 ug/l
78-93-3 Methyl Ethyl Ketone ND 13000 ug/l
108-10-1 4-Methyl-2-pentanone ND 250 ug/l
1634-04-4 Methyl Tert Butyl Ether 24200 250 ug/l
91-20-3 Naphthalene 2220 250 ug/l
103-65-1 n-Propylbenzene 612 250 ug/l
100-42-5 Styrene ND 250 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 250 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 100 ug/l
127-18-4 Tetrachloroethylene ND 250 ug/l
108-88-3 Toluene 35700 250 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 250 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 250 ug/l
71-55-6 1,1,1-Trichloroethane ND 250 ug/l
79-00-5 1,1,2-Trichloroethane ND 150 ug/l
79-01-6 Trichloroethylene ND 250 ug/l
75-69-4 Trichlorofluoromethane ND 250 ug/l
96-18-4 1,2,3-Trichloropropane ND 250 ug/l
95-63-6 1,2,4-Trimethylbenzene 4990 250 ug/l
108-67-8 1,3,5-Trimethylbenzene 1280 250 ug/l
108-05-4 Vinyl Acetate ND 250 ug/l
75-01-4 Vinyl Chloride ND 50 ug/l
m,p-Xylene 12300 500 ug/l
95-47-6 o-Xylene 5710 250 ug/l
1330-20-7 Xylene (total)18000 250 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 93%70-130%
2037-26-5 Toluene-D8 98%70-130%
460-00-4 4-Bromofluorobenzene 101%70-130%
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
11 of 50
LA5781733.2
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:MW3
Lab Sample ID:LA57817-3 Date Sampled:09/17/19
Matrix:AQ - Ground Water Date Received:09/19/19
Method:SM 6200B Percent Solids:n/a
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 2K0118087.D 1 09/27/19 12:46 CP n/a n/a V2K2099
Run #2 a 2K0118060.D 10 09/26/19 14:05 CP n/a n/a V2K2097
Purge Volume
Run #1 25.0 ml
Run #2 25.0 ml
VOA List for NC, May 2012
CAS No.Compound Result RL Units Q
67-64-1 Acetone ND 10 ug/l
71-43-2 Benzene ND 0.50 ug/l
108-86-1 Bromobenzene ND 0.50 ug/l
74-97-5 Bromochloromethane ND 0.50 ug/l
75-27-4 Bromodichloromethane ND 0.50 ug/l
75-25-2 Bromoform ND 0.50 ug/l
104-51-8 n-Butylbenzene ND 0.50 ug/l
135-98-8 sec-Butylbenzene ND 0.50 ug/l
98-06-6 tert-Butylbenzene ND 0.50 ug/l
56-23-5 Carbon Tetrachloride ND 0.20 ug/l
108-90-7 Chlorobenzene ND 0.50 ug/l
75-00-3 Chloroethane ND 0.50 ug/l
67-66-3 Chloroform ND 0.50 ug/l
95-49-8 o-Chlorotoluene ND 0.50 ug/l
106-43-4 p-Chlorotoluene ND 0.50 ug/l
124-48-1 Dibromochloromethane ND 0.20 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 ug/l
541-73-1 m-Dichlorobenzene ND 0.50 ug/l
95-50-1 o-Dichlorobenzene ND 0.50 ug/l
106-46-7 p-Dichlorobenzene ND 0.50 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 ug/l
107-06-2 1,2-Dichloroethane ND 0.20 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 ug/l
78-87-5 1,2-Dichloropropane ND 0.30 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.20 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.20 ug/l
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
12 of 50
LA5781733.3
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:MW3
Lab Sample ID:LA57817-3 Date Sampled:09/17/19
Matrix:AQ - Ground Water Date Received:09/19/19
Method:SM 6200B Percent Solids:n/a
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
VOA List for NC, May 2012
CAS No.Compound Result RL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 ug/l
64-17-5 Ethyl Alcohol ND 50 ug/l
100-41-4 Ethylbenzene ND 0.50 ug/l
591-78-6 2-Hexanone ND 1.0 ug/l
98-82-8 Isopropylbenzene ND 0.50 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 ug/l
74-83-9 Methyl Bromide ND 0.50 ug/l
74-87-3 Methyl Chloride ND 0.50 ug/l
75-09-2 Methylene Chloride ND 0.50 ug/l
78-93-3 Methyl Ethyl Ketone ND 25 ug/l
108-10-1 4-Methyl-2-pentanone ND 0.50 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 ug/l
91-20-3 Naphthalene ND 0.50 ug/l
103-65-1 n-Propylbenzene ND 0.50 ug/l
100-42-5 Styrene ND 0.50 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.20 ug/l
127-18-4 Tetrachloroethylene ND 0.50 ug/l
108-88-3 Toluene ND 0.50 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.30 ug/l
79-01-6 Trichloroethylene ND 0.50 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 ug/l
108-05-4 Vinyl Acetate ND 0.50 ug/l
75-01-4 Vinyl Chloride ND 0.10 ug/l
m,p-Xylene ND 1.0 ug/l
95-47-6 o-Xylene ND 0.50 ug/l
1330-20-7 Xylene (total)ND 0.50 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 90%91%70-130%
2037-26-5 Toluene-D8 93%94%70-130%
460-00-4 4-Bromofluorobenzene 97%94%70-130%
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
13 of 50
LA5781733.3
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:MW3
Lab Sample ID:LA57817-3 Date Sampled:09/17/19
Matrix:AQ - Ground Water Date Received:09/19/19
Method:SM 6200B Percent Solids:n/a
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
VOA List for NC, May 2012
CAS No.Compound Result RL Units Q
(a) rr o/d Sample used for QC purposes only.
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
14 of 50
LA5781733.3
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW4
Lab Sample ID:LA57817-4 Date Sampled:09/17/19
Matrix:AQ - Ground Water Date Received:09/19/19
Method:SM 6200B Percent Solids:n/a
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 2K0118061.D 50 09/26/19 14:37 CP n/a n/a V2K2097
Run #2
Purge Volume
Run #1 25.0 ml
Run #2
VOA List for NC, May 2012
CAS No.Compound Result RL Units Q
67-64-1 Acetone ND 500 ug/l
71-43-2 Benzene 598 25 ug/l
108-86-1 Bromobenzene ND 25 ug/l
74-97-5 Bromochloromethane ND 25 ug/l
75-27-4 Bromodichloromethane ND 25 ug/l
75-25-2 Bromoform ND 25 ug/l
104-51-8 n-Butylbenzene ND 25 ug/l
135-98-8 sec-Butylbenzene ND 25 ug/l
98-06-6 tert-Butylbenzene ND 25 ug/l
56-23-5 Carbon Tetrachloride ND 10 ug/l
108-90-7 Chlorobenzene ND 25 ug/l
75-00-3 Chloroethane ND 25 ug/l
67-66-3 Chloroform ND 25 ug/l
95-49-8 o-Chlorotoluene ND 25 ug/l
106-43-4 p-Chlorotoluene ND 25 ug/l
124-48-1 Dibromochloromethane ND 10 ug/l
106-93-4 1,2-Dibromoethane ND 25 ug/l
75-71-8 Dichlorodifluoromethane ND 25 ug/l
541-73-1 m-Dichlorobenzene ND 25 ug/l
95-50-1 o-Dichlorobenzene ND 25 ug/l
106-46-7 p-Dichlorobenzene ND 25 ug/l
75-34-3 1,1-Dichloroethane ND 25 ug/l
107-06-2 1,2-Dichloroethane ND 10 ug/l
75-35-4 1,1-Dichloroethylene ND 25 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 25 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 25 ug/l
78-87-5 1,2-Dichloropropane ND 15 ug/l
142-28-9 1,3-Dichloropropane ND 25 ug/l
594-20-7 2,2-Dichloropropane ND 25 ug/l
563-58-6 1,1-Dichloropropene ND 25 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 10 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 10 ug/l
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
15 of 50
LA5781733.4
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW4
Lab Sample ID:LA57817-4 Date Sampled:09/17/19
Matrix:AQ - Ground Water Date Received:09/19/19
Method:SM 6200B Percent Solids:n/a
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
VOA List for NC, May 2012
CAS No.Compound Result RL Units Q
108-20-3 Di-Isopropyl Ether ND 25 ug/l
64-17-5 Ethyl Alcohol ND 2500 ug/l
100-41-4 Ethylbenzene 1090 25 ug/l
591-78-6 2-Hexanone ND 50 ug/l
98-82-8 Isopropylbenzene 67.0 25 ug/l
99-87-6 p-Isopropyltoluene ND 25 ug/l
74-83-9 Methyl Bromide ND 25 ug/l
74-87-3 Methyl Chloride ND 25 ug/l
75-09-2 Methylene Chloride ND 25 ug/l
78-93-3 Methyl Ethyl Ketone ND 1300 ug/l
108-10-1 4-Methyl-2-pentanone ND 25 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 25 ug/l
91-20-3 Naphthalene 275 25 ug/l
103-65-1 n-Propylbenzene 196 25 ug/l
100-42-5 Styrene ND 25 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 25 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 10 ug/l
127-18-4 Tetrachloroethylene ND 25 ug/l
108-88-3 Toluene 2540 25 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 25 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 25 ug/l
71-55-6 1,1,1-Trichloroethane ND 25 ug/l
79-00-5 1,1,2-Trichloroethane ND 15 ug/l
79-01-6 Trichloroethylene ND 25 ug/l
75-69-4 Trichlorofluoromethane ND 25 ug/l
96-18-4 1,2,3-Trichloropropane ND 25 ug/l
95-63-6 1,2,4-Trimethylbenzene 1330 25 ug/l
108-67-8 1,3,5-Trimethylbenzene 366 25 ug/l
108-05-4 Vinyl Acetate ND 25 ug/l
75-01-4 Vinyl Chloride ND 5.0 ug/l
m,p-Xylene 3580 50 ug/l
95-47-6 o-Xylene 1390 25 ug/l
1330-20-7 Xylene (total)4970 25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 91%70-130%
2037-26-5 Toluene-D8 98%70-130%
460-00-4 4-Bromofluorobenzene 96%70-130%
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
16 of 50
LA5781733.4
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:MW5
Lab Sample ID:LA57817-5 Date Sampled:09/17/19
Matrix:AQ - Ground Water Date Received:09/19/19
Method:SM 6200B Percent Solids:n/a
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 2K0118089.D 10 09/27/19 13:50 CP n/a n/a V2K2099
Run #2 a 2K0118104.D 100 09/30/19 13:34 CP n/a n/a V2K2100
Run #3 2K0118062.D 500 09/26/19 15:08 CP n/a n/a V2K2097
Purge Volume
Run #1 25.0 ml
Run #2 25.0 ml
Run #3 25.0 ml
VOA List for NC, May 2012
CAS No.Compound Result RL Units Q
67-64-1 Acetone ND 100 ug/l
71-43-2 Benzene 754 5.0 ug/l
108-86-1 Bromobenzene ND 5.0 ug/l
74-97-5 Bromochloromethane ND 5.0 ug/l
75-27-4 Bromodichloromethane ND 5.0 ug/l
75-25-2 Bromoform ND 5.0 ug/l
104-51-8 n-Butylbenzene ND 5.0 ug/l
135-98-8 sec-Butylbenzene ND 5.0 ug/l
98-06-6 tert-Butylbenzene ND 5.0 ug/l
56-23-5 Carbon Tetrachloride ND 2.0 ug/l
108-90-7 Chlorobenzene ND 5.0 ug/l
75-00-3 Chloroethane ND 5.0 ug/l
67-66-3 Chloroform ND 5.0 ug/l
95-49-8 o-Chlorotoluene ND 5.0 ug/l
106-43-4 p-Chlorotoluene ND 5.0 ug/l
124-48-1 Dibromochloromethane ND 2.0 ug/l
106-93-4 1,2-Dibromoethane ND 5.0 ug/l
75-71-8 Dichlorodifluoromethane ND 5.0 ug/l
541-73-1 m-Dichlorobenzene ND 5.0 ug/l
95-50-1 o-Dichlorobenzene ND 5.0 ug/l
106-46-7 p-Dichlorobenzene ND 5.0 ug/l
75-34-3 1,1-Dichloroethane ND 5.0 ug/l
107-06-2 1,2-Dichloroethane 3.7 2.0 ug/l
75-35-4 1,1-Dichloroethylene ND 5.0 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 5.0 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 5.0 ug/l
78-87-5 1,2-Dichloropropane ND 3.0 ug/l
142-28-9 1,3-Dichloropropane ND 5.0 ug/l
594-20-7 2,2-Dichloropropane ND 5.0 ug/l
563-58-6 1,1-Dichloropropene ND 5.0 ug/l
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
17 of 50
LA5781733.5
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:MW5
Lab Sample ID:LA57817-5 Date Sampled:09/17/19
Matrix:AQ - Ground Water Date Received:09/19/19
Method:SM 6200B Percent Solids:n/a
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
VOA List for NC, May 2012
CAS No.Compound Result RL Units Q
10061-01-5 cis-1,3-Dichloropropene ND 2.0 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 2.0 ug/l
108-20-3 Di-Isopropyl Ether ND 5.0 ug/l
64-17-5 Ethyl Alcohol ND 500 ug/l
100-41-4 Ethylbenzene 251 5.0 ug/l
591-78-6 2-Hexanone 29.2 10 ug/l
98-82-8 Isopropylbenzene 10.7 5.0 ug/l
99-87-6 p-Isopropyltoluene ND 5.0 ug/l
74-83-9 Methyl Bromide ND 5.0 ug/l
74-87-3 Methyl Chloride ND 5.0 ug/l
75-09-2 Methylene Chloride ND 5.0 ug/l
78-93-3 Methyl Ethyl Ketone ND 250 ug/l
108-10-1 4-Methyl-2-pentanone ND 5.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 90.2 5.0 ug/l
91-20-3 Naphthalene 59.7 5.0 ug/l
103-65-1 n-Propylbenzene 28.0 5.0 ug/l
100-42-5 Styrene ND 5.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 5.0 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 2.0 ug/l
127-18-4 Tetrachloroethylene ND 5.0 ug/l
108-88-3 Toluene 19400 b 250 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 5.0 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 5.0 ug/l
71-55-6 1,1,1-Trichloroethane ND 5.0 ug/l
79-00-5 1,1,2-Trichloroethane ND 3.0 ug/l
79-01-6 Trichloroethylene ND 5.0 ug/l
75-69-4 Trichlorofluoromethane ND 5.0 ug/l
96-18-4 1,2,3-Trichloropropane ND 5.0 ug/l
95-63-6 1,2,4-Trimethylbenzene 221 5.0 ug/l
108-67-8 1,3,5-Trimethylbenzene 56.8 5.0 ug/l
108-05-4 Vinyl Acetate ND 5.0 ug/l
75-01-4 Vinyl Chloride ND 1.0 ug/l
m,p-Xylene 842 10 ug/l
95-47-6 o-Xylene 392 5.0 ug/l
1330-20-7 Xylene (total)1230 5.0 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Run# 3 Limits
17060-07-0 1,2-Dichloroethane-D4 94%101%93%70-130%
2037-26-5 Toluene-D8 97%98%97%70-130%
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
18 of 50
LA5781733.5
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:MW5
Lab Sample ID:LA57817-5 Date Sampled:09/17/19
Matrix:AQ - Ground Water Date Received:09/19/19
Method:SM 6200B Percent Solids:n/a
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
VOA List for NC, May 2012
CAS No.Surrogate Recoveries Run# 1 Run# 2 Run# 3 Limits
460-00-4 4-Bromofluorobenzene 98%98%100%70-130%
(a) Sample used for QC purposes only.
(b) Result is from Run# 3
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
19 of 50
LA5781733.5
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:MW6
Lab Sample ID:LA57817-6 Date Sampled:09/17/19
Matrix:AQ - Ground Water Date Received:09/19/19
Method:SM 6200B Percent Solids:n/a
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 2K0118090.D 50 09/27/19 14:22 CP n/a n/a V2K2099
Run #2 2K0118063.D 500 09/26/19 15:40 CP n/a n/a V2K2097
Purge Volume
Run #1 25.0 ml
Run #2 25.0 ml
VOA List for NC, May 2012
CAS No.Compound Result RL Units Q
67-64-1 Acetone 659 500 ug/l
71-43-2 Benzene 3860 a 250 ug/l
108-86-1 Bromobenzene ND 25 ug/l
74-97-5 Bromochloromethane ND 25 ug/l
75-27-4 Bromodichloromethane ND 25 ug/l
75-25-2 Bromoform ND 25 ug/l
104-51-8 n-Butylbenzene 31.7 25 ug/l
135-98-8 sec-Butylbenzene ND 25 ug/l
98-06-6 tert-Butylbenzene ND 25 ug/l
56-23-5 Carbon Tetrachloride ND 10 ug/l
108-90-7 Chlorobenzene ND 25 ug/l
75-00-3 Chloroethane ND 25 ug/l
67-66-3 Chloroform ND 25 ug/l
95-49-8 o-Chlorotoluene ND 25 ug/l
106-43-4 p-Chlorotoluene ND 25 ug/l
124-48-1 Dibromochloromethane ND 10 ug/l
106-93-4 1,2-Dibromoethane ND 25 ug/l
75-71-8 Dichlorodifluoromethane ND 25 ug/l
541-73-1 m-Dichlorobenzene ND 25 ug/l
95-50-1 o-Dichlorobenzene ND 25 ug/l
106-46-7 p-Dichlorobenzene ND 25 ug/l
75-34-3 1,1-Dichloroethane ND 25 ug/l
107-06-2 1,2-Dichloroethane 10.5 10 ug/l
75-35-4 1,1-Dichloroethylene ND 25 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 25 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 25 ug/l
78-87-5 1,2-Dichloropropane ND 15 ug/l
142-28-9 1,3-Dichloropropane ND 25 ug/l
594-20-7 2,2-Dichloropropane ND 25 ug/l
563-58-6 1,1-Dichloropropene ND 25 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 10 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 10 ug/l
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
20 of 50
LA5781733.6
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:MW6
Lab Sample ID:LA57817-6 Date Sampled:09/17/19
Matrix:AQ - Ground Water Date Received:09/19/19
Method:SM 6200B Percent Solids:n/a
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
VOA List for NC, May 2012
CAS No.Compound Result RL Units Q
108-20-3 Di-Isopropyl Ether ND 25 ug/l
64-17-5 Ethyl Alcohol ND 2500 ug/l
100-41-4 Ethylbenzene 2930 25 ug/l
591-78-6 2-Hexanone ND 50 ug/l
98-82-8 Isopropylbenzene 109 25 ug/l
99-87-6 p-Isopropyltoluene ND 25 ug/l
74-83-9 Methyl Bromide ND 25 ug/l
74-87-3 Methyl Chloride 73.3 25 ug/l
75-09-2 Methylene Chloride ND 25 ug/l
78-93-3 Methyl Ethyl Ketone ND 1300 ug/l
108-10-1 4-Methyl-2-pentanone ND 25 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 25 ug/l
91-20-3 Naphthalene 884 25 ug/l
103-65-1 n-Propylbenzene 305 25 ug/l
100-42-5 Styrene 38.1 25 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 25 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 10 ug/l
127-18-4 Tetrachloroethylene ND 25 ug/l
108-88-3 Toluene 20900 a 250 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 25 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 25 ug/l
71-55-6 1,1,1-Trichloroethane ND 25 ug/l
79-00-5 1,1,2-Trichloroethane ND 15 ug/l
79-01-6 Trichloroethylene ND 25 ug/l
75-69-4 Trichlorofluoromethane ND 25 ug/l
96-18-4 1,2,3-Trichloropropane 42.3 25 ug/l
95-63-6 1,2,4-Trimethylbenzene 2310 25 ug/l
108-67-8 1,3,5-Trimethylbenzene 589 25 ug/l
108-05-4 Vinyl Acetate ND 25 ug/l
75-01-4 Vinyl Chloride ND 5.0 ug/l
m,p-Xylene 6420 a 500 ug/l
95-47-6 o-Xylene 4630 25 ug/l
1330-20-7 Xylene (total)9760 a 250 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 98%93%70-130%
2037-26-5 Toluene-D8 100%97%70-130%
460-00-4 4-Bromofluorobenzene 98%97%70-130%
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
21 of 50
LA5781733.6
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:MW6
Lab Sample ID:LA57817-6 Date Sampled:09/17/19
Matrix:AQ - Ground Water Date Received:09/19/19
Method:SM 6200B Percent Solids:n/a
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
VOA List for NC, May 2012
CAS No.Compound Result RL Units Q
(a) Result is from Run# 2
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
22 of 50
LA5781733.6
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW7
Lab Sample ID:LA57817-7 Date Sampled:09/17/19
Matrix:AQ - Ground Water Date Received:09/19/19
Method:SM 6200B Percent Solids:n/a
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 2K0118088.D 1 09/27/19 13:18 CP n/a n/a V2K2099
Run #2
Purge Volume
Run #1 25.0 ml
Run #2
VOA List for NC, May 2012
CAS No.Compound Result RL Units Q
67-64-1 Acetone 72.6 10 ug/l
71-43-2 Benzene 2.2 0.50 ug/l
108-86-1 Bromobenzene ND 0.50 ug/l
74-97-5 Bromochloromethane ND 0.50 ug/l
75-27-4 Bromodichloromethane ND 0.50 ug/l
75-25-2 Bromoform ND 0.50 ug/l
104-51-8 n-Butylbenzene ND 0.50 ug/l
135-98-8 sec-Butylbenzene ND 0.50 ug/l
98-06-6 tert-Butylbenzene ND 0.50 ug/l
56-23-5 Carbon Tetrachloride ND 0.20 ug/l
108-90-7 Chlorobenzene ND 0.50 ug/l
75-00-3 Chloroethane ND 0.50 ug/l
67-66-3 Chloroform ND 0.50 ug/l
95-49-8 o-Chlorotoluene ND 0.50 ug/l
106-43-4 p-Chlorotoluene ND 0.50 ug/l
124-48-1 Dibromochloromethane ND 0.20 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 ug/l
541-73-1 m-Dichlorobenzene ND 0.50 ug/l
95-50-1 o-Dichlorobenzene ND 0.50 ug/l
106-46-7 p-Dichlorobenzene ND 0.50 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 ug/l
107-06-2 1,2-Dichloroethane ND 0.20 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 ug/l
78-87-5 1,2-Dichloropropane ND 0.30 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.20 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.20 ug/l
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
23 of 50
LA5781733.7
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW7
Lab Sample ID:LA57817-7 Date Sampled:09/17/19
Matrix:AQ - Ground Water Date Received:09/19/19
Method:SM 6200B Percent Solids:n/a
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
VOA List for NC, May 2012
CAS No.Compound Result RL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 ug/l
64-17-5 Ethyl Alcohol ND 50 ug/l
100-41-4 Ethylbenzene ND 0.50 ug/l
591-78-6 2-Hexanone ND 1.0 ug/l
98-82-8 Isopropylbenzene ND 0.50 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 ug/l
74-83-9 Methyl Bromide ND 0.50 ug/l
74-87-3 Methyl Chloride 4.8 0.50 ug/l
75-09-2 Methylene Chloride ND 0.50 ug/l
78-93-3 Methyl Ethyl Ketone ND 25 ug/l
108-10-1 4-Methyl-2-pentanone ND 0.50 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 ug/l
91-20-3 Naphthalene ND 0.50 ug/l
103-65-1 n-Propylbenzene ND 0.50 ug/l
100-42-5 Styrene ND 0.50 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.20 ug/l
127-18-4 Tetrachloroethylene ND 0.50 ug/l
108-88-3 Toluene ND 0.50 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.30 ug/l
79-01-6 Trichloroethylene ND 0.50 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 ug/l
108-05-4 Vinyl Acetate ND 0.50 ug/l
75-01-4 Vinyl Chloride ND 0.10 ug/l
m,p-Xylene 1.6 1.0 ug/l
95-47-6 o-Xylene ND 0.50 ug/l
1330-20-7 Xylene (total)2.0 0.50 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 92%70-130%
2037-26-5 Toluene-D8 95%70-130%
460-00-4 4-Bromofluorobenzene 101%70-130%
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
24 of 50
LA5781733.7
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW8
Lab Sample ID:LA57817-8 Date Sampled:09/17/19
Matrix:AQ - Ground Water Date Received:09/19/19
Method:SM 6200B Percent Solids:n/a
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 2K0118117.D 10 09/30/19 20:28 CP n/a n/a V2K2100
Run #2 2K0118065.D 50 09/26/19 16:45 CP n/a n/a V2K2097
Purge Volume
Run #1 25.0 ml
Run #2 25.0 ml
VOA List for NC, May 2012
CAS No.Compound Result RL Units Q
67-64-1 Acetone 881 100 ug/l
71-43-2 Benzene 902 a 25 ug/l
108-86-1 Bromobenzene ND 5.0 ug/l
74-97-5 Bromochloromethane ND 5.0 ug/l
75-27-4 Bromodichloromethane ND 5.0 ug/l
75-25-2 Bromoform ND 5.0 ug/l
104-51-8 n-Butylbenzene 45.3 5.0 ug/l
135-98-8 sec-Butylbenzene 27.4 5.0 ug/l
98-06-6 tert-Butylbenzene ND 5.0 ug/l
56-23-5 Carbon Tetrachloride ND 2.0 ug/l
108-90-7 Chlorobenzene ND 5.0 ug/l
75-00-3 Chloroethane ND 5.0 ug/l
67-66-3 Chloroform ND 5.0 ug/l
95-49-8 o-Chlorotoluene ND 5.0 ug/l
106-43-4 p-Chlorotoluene ND 5.0 ug/l
124-48-1 Dibromochloromethane ND 2.0 ug/l
106-93-4 1,2-Dibromoethane ND 5.0 ug/l
75-71-8 Dichlorodifluoromethane ND 5.0 ug/l
541-73-1 m-Dichlorobenzene ND 5.0 ug/l
95-50-1 o-Dichlorobenzene ND 5.0 ug/l
106-46-7 p-Dichlorobenzene ND 5.0 ug/l
75-34-3 1,1-Dichloroethane ND 5.0 ug/l
107-06-2 1,2-Dichloroethane 57.0 2.0 ug/l
75-35-4 1,1-Dichloroethylene ND 5.0 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 5.0 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 5.0 ug/l
78-87-5 1,2-Dichloropropane ND 3.0 ug/l
142-28-9 1,3-Dichloropropane ND 5.0 ug/l
594-20-7 2,2-Dichloropropane ND 5.0 ug/l
563-58-6 1,1-Dichloropropene ND 5.0 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 2.0 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 2.0 ug/l
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
25 of 50
LA5781733.8
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW8
Lab Sample ID:LA57817-8 Date Sampled:09/17/19
Matrix:AQ - Ground Water Date Received:09/19/19
Method:SM 6200B Percent Solids:n/a
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
VOA List for NC, May 2012
CAS No.Compound Result RL Units Q
108-20-3 Di-Isopropyl Ether 84.8 5.0 ug/l
64-17-5 Ethyl Alcohol ND 500 ug/l
100-41-4 Ethylbenzene 2070 a 25 ug/l
591-78-6 2-Hexanone 280 10 ug/l
98-82-8 Isopropylbenzene 159 5.0 ug/l
99-87-6 p-Isopropyltoluene 30.3 5.0 ug/l
74-83-9 Methyl Bromide ND 5.0 ug/l
74-87-3 Methyl Chloride ND 5.0 ug/l
75-09-2 Methylene Chloride ND 5.0 ug/l
78-93-3 Methyl Ethyl Ketone ND 250 ug/l
108-10-1 4-Methyl-2-pentanone ND 5.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 5.0 ug/l
91-20-3 Naphthalene 762 5.0 ug/l
103-65-1 n-Propylbenzene 324 5.0 ug/l
100-42-5 Styrene ND 5.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 5.0 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 2.0 ug/l
127-18-4 Tetrachloroethylene ND 5.0 ug/l
108-88-3 Toluene 2880 a 25 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 5.0 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 5.0 ug/l
71-55-6 1,1,1-Trichloroethane ND 5.0 ug/l
79-00-5 1,1,2-Trichloroethane ND 3.0 ug/l
79-01-6 Trichloroethylene ND 5.0 ug/l
75-69-4 Trichlorofluoromethane ND 5.0 ug/l
96-18-4 1,2,3-Trichloropropane ND 5.0 ug/l
108-67-8 1,3,5-Trimethylbenzene 725 5.0 ug/l
108-05-4 Vinyl Acetate ND 5.0 ug/l
75-01-4 Vinyl Chloride ND 1.0 ug/l
m,p-Xylene 4740 a 50 ug/l
95-47-6 o-Xylene 3010 a 25 ug/l
1330-20-7 Xylene (total)7750 a 25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 110%98%70-130%
2037-26-5 Toluene-D8 100%99%70-130%
460-00-4 4-Bromofluorobenzene 103%107%70-130%
(a) Result is from Run# 2
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
26 of 50
LA5781733.8
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:DMW1
Lab Sample ID:LA57817-9 Date Sampled:09/17/19
Matrix:AQ - Ground Water Date Received:09/19/19
Method:SM 6200B Percent Solids:n/a
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 2K0118057.D 1 09/26/19 12:31 CP n/a n/a V2K2097
Run #2
Purge Volume
Run #1 25.0 ml
Run #2
VOA List for NC, May 2012
CAS No.Compound Result RL Units Q
67-64-1 Acetone ND 10 ug/l
71-43-2 Benzene ND 0.50 ug/l
108-86-1 Bromobenzene ND 0.50 ug/l
74-97-5 Bromochloromethane ND 0.50 ug/l
75-27-4 Bromodichloromethane ND 0.50 ug/l
75-25-2 Bromoform ND 0.50 ug/l
104-51-8 n-Butylbenzene ND 0.50 ug/l
135-98-8 sec-Butylbenzene ND 0.50 ug/l
98-06-6 tert-Butylbenzene ND 0.50 ug/l
56-23-5 Carbon Tetrachloride ND 0.20 ug/l
108-90-7 Chlorobenzene ND 0.50 ug/l
75-00-3 Chloroethane ND 0.50 ug/l
67-66-3 Chloroform ND 0.50 ug/l
95-49-8 o-Chlorotoluene ND 0.50 ug/l
106-43-4 p-Chlorotoluene ND 0.50 ug/l
124-48-1 Dibromochloromethane ND 0.20 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 ug/l
541-73-1 m-Dichlorobenzene ND 0.50 ug/l
95-50-1 o-Dichlorobenzene ND 0.50 ug/l
106-46-7 p-Dichlorobenzene ND 0.50 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 ug/l
107-06-2 1,2-Dichloroethane ND 0.20 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 ug/l
78-87-5 1,2-Dichloropropane ND 0.30 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.20 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.20 ug/l
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
27 of 50
LA5781733.9
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:DMW1
Lab Sample ID:LA57817-9 Date Sampled:09/17/19
Matrix:AQ - Ground Water Date Received:09/19/19
Method:SM 6200B Percent Solids:n/a
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
VOA List for NC, May 2012
CAS No.Compound Result RL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 ug/l
64-17-5 Ethyl Alcohol ND 50 ug/l
100-41-4 Ethylbenzene ND 0.50 ug/l
591-78-6 2-Hexanone ND 1.0 ug/l
98-82-8 Isopropylbenzene ND 0.50 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 ug/l
74-83-9 Methyl Bromide ND 0.50 ug/l
74-87-3 Methyl Chloride ND 0.50 ug/l
75-09-2 Methylene Chloride ND 0.50 ug/l
78-93-3 Methyl Ethyl Ketone ND 25 ug/l
108-10-1 4-Methyl-2-pentanone ND 0.50 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 ug/l
91-20-3 Naphthalene ND 0.50 ug/l
103-65-1 n-Propylbenzene ND 0.50 ug/l
100-42-5 Styrene ND 0.50 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.20 ug/l
127-18-4 Tetrachloroethylene ND 0.50 ug/l
108-88-3 Toluene ND 0.50 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.30 ug/l
79-01-6 Trichloroethylene ND 0.50 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 ug/l
108-05-4 Vinyl Acetate ND 0.50 ug/l
75-01-4 Vinyl Chloride ND 0.10 ug/l
m,p-Xylene ND 1.0 ug/l
95-47-6 o-Xylene ND 0.50 ug/l
1330-20-7 Xylene (total)ND 0.50 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 84%70-130%
2037-26-5 Toluene-D8 95%70-130%
460-00-4 4-Bromofluorobenzene 94%70-130%
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
28 of 50
LA5781733.9
SGS North America Inc.
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Scott, LA
Section 4
29 of 50
LA578174
LA57817: Chain of Custody
Page 1 of 3
30 of 50
LA5781744.1
LA57817: Chain of Custody
Page 2 of 3
31 of 50
LA5781744.1
SGS Sample Receipt Summary
Job Number:LA57817 Client:ATC
Date / Time Received:9/19/2019 9:40:00 AM Delivery Method:FedEx
Project:CARY BEVERAGE
4. No. Coolers:1
Airbill #'s:491386905630
Cooler Security
1. Custody Seals Present:
Y or N
2. Custody Seals Intact:
3. COC Present:
4. Smpl Dates/Time OK
2. Thermometer ID:
Cooler Temperature Y or N
1. Temp criteria achieved:
3. Cooler media:
DV440;
Ice (direct contact)
Quality Control Preservation Y or N N/A
1. Trip Blank present / cooler:
2. Trip Blank listed on COC:
3. Samples preserved properly:
4. VOCs headspace free:
Sample Integrity - Documentation Y or N
1. Sample labels present on bottles:
2. Container labeling complete:
3. Sample container label / COC agree:
Sample Integrity - Condition Y or N
1. Sample recvd within HT:
3. Condition of sample:
2. All containers accounted for:
Sample Integrity - Instructions
1. Analysis requested is clear:
2. Bottles received for unspecified tests
3. Sufficient volume recvd for analysis:
4. Compositing instructions clear:
5. Filtering instructions clear:
Intact
Y or N
Comments
Y or N N/A
Cooler Temps (Initial/Adjusted):#1: (0.3/0.3);
LA57817: Chain of Custody
Page 3 of 3
32 of 50
LA5781744.1
SGS North America Inc.
MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Scott, LA
Section 5
33 of 50
LA578175
Method Blank Summary Page 1 of 2
Job Number:LA57817
Account:ATCNCR ATC Group Services LLC
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2K2097-MB1 2K0118056.D 1 09/26/19 CP n/a n/a V2K2097
The QC reported here applies to the following samples:Method: SM 6200B
LA57817-1, LA57817-2, LA57817-4, LA57817-5, LA57817-6, LA57817-8, LA57817-9
CAS No.Compound Result RL Units Q
67-64-1 Acetone ND 10 ug/l
71-43-2 Benzene ND 0.50 ug/l
108-86-1 Bromobenzene ND 0.50 ug/l
74-97-5 Bromochloromethane ND 0.50 ug/l
75-27-4 Bromodichloromethane ND 0.50 ug/l
75-25-2 Bromoform ND 0.50 ug/l
104-51-8 n-Butylbenzene ND 0.50 ug/l
135-98-8 sec-Butylbenzene ND 0.50 ug/l
98-06-6 tert-Butylbenzene ND 0.50 ug/l
56-23-5 Carbon Tetrachloride ND 0.20 ug/l
108-90-7 Chlorobenzene ND 0.50 ug/l
75-00-3 Chloroethane ND 0.50 ug/l
67-66-3 Chloroform ND 0.50 ug/l
95-49-8 o-Chlorotoluene ND 0.50 ug/l
106-43-4 p-Chlorotoluene ND 0.50 ug/l
124-48-1 Dibromochloromethane ND 0.20 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 ug/l
541-73-1 m-Dichlorobenzene ND 0.50 ug/l
95-50-1 o-Dichlorobenzene ND 0.50 ug/l
106-46-7 p-Dichlorobenzene ND 0.50 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 ug/l
107-06-2 1,2-Dichloroethane ND 0.20 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 ug/l
78-87-5 1,2-Dichloropropane ND 0.30 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.20 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.20 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 ug/l
64-17-5 Ethyl Alcohol ND 50 ug/l
100-41-4 Ethylbenzene ND 0.50 ug/l
591-78-6 2-Hexanone ND 1.0 ug/l
34 of 50
LA5781755.1.1
Method Blank Summary Page 2 of 2
Job Number:LA57817
Account:ATCNCR ATC Group Services LLC
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2K2097-MB1 2K0118056.D 1 09/26/19 CP n/a n/a V2K2097
The QC reported here applies to the following samples:Method: SM 6200B
LA57817-1, LA57817-2, LA57817-4, LA57817-5, LA57817-6, LA57817-8, LA57817-9
CAS No.Compound Result RL Units Q
98-82-8 Isopropylbenzene ND 0.50 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 ug/l
74-83-9 Methyl Bromide ND 0.50 ug/l
74-87-3 Methyl Chloride ND 0.50 ug/l
75-09-2 Methylene Chloride ND 0.50 ug/l
78-93-3 Methyl Ethyl Ketone ND 25 ug/l
108-10-1 4-Methyl-2-pentanone ND 0.50 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 ug/l
91-20-3 Naphthalene 0.46 0.50 ug/l J
103-65-1 n-Propylbenzene ND 0.50 ug/l
100-42-5 Styrene ND 0.50 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.20 ug/l
127-18-4 Tetrachloroethylene ND 0.50 ug/l
108-88-3 Toluene ND 0.50 ug/l
87-61-6 1,2,3-Trichlorobenzene 0.36 0.50 ug/l J
120-82-1 1,2,4-Trichlorobenzene 0.32 0.50 ug/l J
71-55-6 1,1,1-Trichloroethane ND 0.50 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.30 ug/l
79-01-6 Trichloroethylene ND 0.50 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 ug/l
108-05-4 Vinyl Acetate ND 0.50 ug/l
75-01-4 Vinyl Chloride ND 0.10 ug/l
m,p-Xylene ND 1.0 ug/l
95-47-6 o-Xylene ND 0.50 ug/l
1330-20-7 Xylene (total)ND 0.50 ug/l
CAS No.Surrogate Recoveries Limits
17060-07-0 1,2-Dichloroethane-D4 92%70-130%
2037-26-5 Toluene-D8 96%70-130%
460-00-4 4-Bromofluorobenzene 97%70-130%
35 of 50
LA5781755.1.1
Method Blank Summary Page 1 of 2
Job Number:LA57817
Account:ATCNCR ATC Group Services LLC
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2K2099-MB1 2K0118086.D 1 09/27/19 CP n/a n/a V2K2099
The QC reported here applies to the following samples:Method: SM 6200B
LA57817-3, LA57817-5, LA57817-6, LA57817-7
CAS No.Compound Result RL Units Q
67-64-1 Acetone ND 10 ug/l
71-43-2 Benzene ND 0.50 ug/l
108-86-1 Bromobenzene ND 0.50 ug/l
74-97-5 Bromochloromethane ND 0.50 ug/l
75-27-4 Bromodichloromethane ND 0.50 ug/l
75-25-2 Bromoform ND 0.50 ug/l
104-51-8 n-Butylbenzene ND 0.50 ug/l
135-98-8 sec-Butylbenzene ND 0.50 ug/l
98-06-6 tert-Butylbenzene ND 0.50 ug/l
56-23-5 Carbon Tetrachloride ND 0.20 ug/l
108-90-7 Chlorobenzene ND 0.50 ug/l
75-00-3 Chloroethane ND 0.50 ug/l
67-66-3 Chloroform ND 0.50 ug/l
95-49-8 o-Chlorotoluene ND 0.50 ug/l
106-43-4 p-Chlorotoluene ND 0.50 ug/l
124-48-1 Dibromochloromethane ND 0.20 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 ug/l
541-73-1 m-Dichlorobenzene ND 0.50 ug/l
95-50-1 o-Dichlorobenzene ND 0.50 ug/l
106-46-7 p-Dichlorobenzene ND 0.50 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 ug/l
107-06-2 1,2-Dichloroethane ND 0.20 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 ug/l
78-87-5 1,2-Dichloropropane ND 0.30 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.20 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.20 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 ug/l
64-17-5 Ethyl Alcohol ND 50 ug/l
100-41-4 Ethylbenzene ND 0.50 ug/l
591-78-6 2-Hexanone ND 1.0 ug/l
36 of 50
LA5781755.1.2
Method Blank Summary Page 2 of 2
Job Number:LA57817
Account:ATCNCR ATC Group Services LLC
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2K2099-MB1 2K0118086.D 1 09/27/19 CP n/a n/a V2K2099
The QC reported here applies to the following samples:Method: SM 6200B
LA57817-3, LA57817-5, LA57817-6, LA57817-7
CAS No.Compound Result RL Units Q
98-82-8 Isopropylbenzene ND 0.50 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 ug/l
74-83-9 Methyl Bromide ND 0.50 ug/l
74-87-3 Methyl Chloride ND 0.50 ug/l
75-09-2 Methylene Chloride ND 0.50 ug/l
78-93-3 Methyl Ethyl Ketone ND 25 ug/l
108-10-1 4-Methyl-2-pentanone ND 0.50 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 ug/l
91-20-3 Naphthalene 0.39 0.50 ug/l J
103-65-1 n-Propylbenzene ND 0.50 ug/l
100-42-5 Styrene ND 0.50 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.20 ug/l
127-18-4 Tetrachloroethylene ND 0.50 ug/l
108-88-3 Toluene ND 0.50 ug/l
87-61-6 1,2,3-Trichlorobenzene 0.37 0.50 ug/l J
120-82-1 1,2,4-Trichlorobenzene 0.31 0.50 ug/l J
71-55-6 1,1,1-Trichloroethane ND 0.50 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.30 ug/l
79-01-6 Trichloroethylene ND 0.50 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 ug/l
108-05-4 Vinyl Acetate ND 0.50 ug/l
75-01-4 Vinyl Chloride ND 0.10 ug/l
m,p-Xylene ND 1.0 ug/l
95-47-6 o-Xylene ND 0.50 ug/l
1330-20-7 Xylene (total)ND 0.50 ug/l
CAS No.Surrogate Recoveries Limits
17060-07-0 1,2-Dichloroethane-D4 91%70-130%
2037-26-5 Toluene-D8 94%70-130%
460-00-4 4-Bromofluorobenzene 93%70-130%
37 of 50
LA5781755.1.2
Method Blank Summary Page 1 of 2
Job Number:LA57817
Account:ATCNCR ATC Group Services LLC
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2K2100-MB1 2K0118101.D 1 09/30/19 CP n/a n/a V2K2100
The QC reported here applies to the following samples:Method: SM 6200B
LA57817-8
CAS No.Compound Result RL Units Q
67-64-1 Acetone ND 10 ug/l
108-86-1 Bromobenzene ND 0.50 ug/l
74-97-5 Bromochloromethane ND 0.50 ug/l
75-27-4 Bromodichloromethane ND 0.50 ug/l
75-25-2 Bromoform ND 0.50 ug/l
104-51-8 n-Butylbenzene 0.12 0.50 ug/l J
135-98-8 sec-Butylbenzene ND 0.50 ug/l
98-06-6 tert-Butylbenzene ND 0.50 ug/l
56-23-5 Carbon Tetrachloride ND 0.20 ug/l
108-90-7 Chlorobenzene ND 0.50 ug/l
75-00-3 Chloroethane ND 0.50 ug/l
67-66-3 Chloroform ND 0.50 ug/l
95-49-8 o-Chlorotoluene ND 0.50 ug/l
106-43-4 p-Chlorotoluene ND 0.50 ug/l
124-48-1 Dibromochloromethane ND 0.20 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 ug/l
541-73-1 m-Dichlorobenzene ND 0.50 ug/l
95-50-1 o-Dichlorobenzene ND 0.50 ug/l
106-46-7 p-Dichlorobenzene ND 0.50 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 ug/l
107-06-2 1,2-Dichloroethane ND 0.20 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 ug/l
78-87-5 1,2-Dichloropropane ND 0.30 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.20 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.20 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 ug/l
64-17-5 Ethyl Alcohol ND 50 ug/l
591-78-6 2-Hexanone ND 1.0 ug/l
98-82-8 Isopropylbenzene ND 0.50 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 ug/l
38 of 50
LA5781755.1.3
Method Blank Summary Page 2 of 2
Job Number:LA57817
Account:ATCNCR ATC Group Services LLC
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2K2100-MB1 2K0118101.D 1 09/30/19 CP n/a n/a V2K2100
The QC reported here applies to the following samples:Method: SM 6200B
LA57817-8
CAS No.Compound Result RL Units Q
74-83-9 Methyl Bromide ND 0.50 ug/l
74-87-3 Methyl Chloride ND 0.50 ug/l
75-09-2 Methylene Chloride ND 0.50 ug/l
78-93-3 Methyl Ethyl Ketone ND 25 ug/l
108-10-1 4-Methyl-2-pentanone ND 0.50 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 ug/l
91-20-3 Naphthalene a 0.61 0.50 ug/l
103-65-1 n-Propylbenzene ND 0.50 ug/l
100-42-5 Styrene ND 0.50 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.20 ug/l
127-18-4 Tetrachloroethylene ND 0.50 ug/l
87-61-6 1,2,3-Trichlorobenzene b 0.39 0.50 ug/l J
120-82-1 1,2,4-Trichlorobenzene b 0.27 0.50 ug/l J
71-55-6 1,1,1-Trichloroethane ND 0.50 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.30 ug/l
79-01-6 Trichloroethylene ND 0.50 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 ug/l
108-05-4 Vinyl Acetate ND 0.50 ug/l
75-01-4 Vinyl Chloride ND 0.10 ug/l
CAS No.Surrogate Recoveries Limits
17060-07-0 1,2-Dichloroethane-D4 97%70-130%
2037-26-5 Toluene-D8 94%70-130%
460-00-4 4-Bromofluorobenzene 96%70-130%
(a) Concentration > RL.
(b) Concentration > 1/2 RL.
39 of 50
LA5781755.1.3
Blank Spike/Blank Spike Duplicate Summary Page 1 of 2
Job Number:LA57817
Account:ATCNCR ATC Group Services LLC
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2K2097-BS1 2K0118053.D 1 09/26/19 CP n/a n/a V2K2097
V2K2097-BSD1 2K0118054.D 1 09/26/19 CP n/a n/a V2K2097
The QC reported here applies to the following samples:Method: SM 6200B
LA57817-1, LA57817-2, LA57817-4, LA57817-5, LA57817-6, LA57817-8, LA57817-9
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
67-64-1 Acetone 50 43.0 86 42.1 84 2 70-130/30
71-43-2 Benzene 20 18.4 92 18.7 94 2 70-130/30
108-86-1 Bromobenzene 20 18.8 94 18.8 94 0 70-130/30
74-97-5 Bromochloromethane 20 17.2 86 17.0 85 1 70-130/30
75-27-4 Bromodichloromethane 20 18.8 94 18.6 93 1 70-130/30
75-25-2 Bromoform 20 21.3 107 20.3 102 5 70-130/30
104-51-8 n-Butylbenzene 20 18.0 90 18.0 90 0 70-130/30
135-98-8 sec-Butylbenzene 20 18.1 91 18.1 91 0 70-130/30
98-06-6 tert-Butylbenzene 20 18.2 91 18.3 92 1 70-130/30
56-23-5 Carbon Tetrachloride 20 18.7 94 18.8 94 1 70-130/30
108-90-7 Chlorobenzene 20 20.3 102 20.6 103 1 70-130/30
75-00-3 Chloroethane 20 16.5 83 16.8 84 2 60-140/30
67-66-3 Chloroform 20 17.6 88 17.3 87 2 70-130/30
95-49-8 o-Chlorotoluene 20 18.0 90 17.8 89 1 70-130/30
106-43-4 p-Chlorotoluene 20 17.4 87 17.3 87 1 70-130/30
124-48-1 Dibromochloromethane 20 20.4 102 20.4 102 0 70-130/30
106-93-4 1,2-Dibromoethane 20 19.0 95 18.7 94 2 70-130/30
75-71-8 Dichlorodifluoromethane 20 16.6 83 16.7 84 1 60-140/30
541-73-1 m-Dichlorobenzene 20 18.0 90 17.8 89 1 70-130/30
95-50-1 o-Dichlorobenzene 20 18.1 91 18.1 91 0 70-130/30
106-46-7 p-Dichlorobenzene 20 17.4 87 17.3 87 1 70-130/30
75-34-3 1,1-Dichloroethane 20 18.6 93 18.2 91 2 70-130/30
107-06-2 1,2-Dichloroethane 20 17.9 90 17.9 90 0 70-130/30
75-35-4 1,1-Dichloroethylene 20 18.7 94 18.5 93 1 70-130/30
156-59-2 cis-1,2-Dichloroethylene 20 18.1 91 17.7 89 2 70-130/30
156-60-5 trans-1,2-Dichloroethylene 20 17.6 88 17.4 87 1 70-130/30
78-87-5 1,2-Dichloropropane 20 18.8 94 19.2 96 2 70-130/30
142-28-9 1,3-Dichloropropane 20 19.0 95 18.5 93 3 70-130/30
594-20-7 2,2-Dichloropropane 20 19.6 98 19.3 97 2 70-130/30
563-58-6 1,1-Dichloropropene 20 18.2 91 18.1 91 1 70-130/30
10061-01-5 cis-1,3-Dichloropropene 20 21.2 106 21.5 108 1 70-130/30
10061-02-6 trans-1,3-Dichloropropene 20 21.3 107 21.7 109 2 70-130/30
108-20-3 Di-Isopropyl Ether 20 18.6 93 18.6 93 0 70-130/30
64-17-5 Ethyl Alcohol 400 326 82 338 85 4 70-130/30
100-41-4 Ethylbenzene 20 19.3 97 19.3 97 0 70-130/30
591-78-6 2-Hexanone 50 43.5 87 48.0 96 10 70-130/30
* = Outside of Control Limits.
40 of 50
LA5781755.2.1
Blank Spike/Blank Spike Duplicate Summary Page 2 of 2
Job Number:LA57817
Account:ATCNCR ATC Group Services LLC
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2K2097-BS1 2K0118053.D 1 09/26/19 CP n/a n/a V2K2097
V2K2097-BSD1 2K0118054.D 1 09/26/19 CP n/a n/a V2K2097
The QC reported here applies to the following samples:Method: SM 6200B
LA57817-1, LA57817-2, LA57817-4, LA57817-5, LA57817-6, LA57817-8, LA57817-9
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
98-82-8 Isopropylbenzene 20 18.9 95 18.8 94 1 70-130/30
99-87-6 p-Isopropyltoluene 20 18.2 91 18.4 92 1 70-130/30
74-83-9 Methyl Bromide 20 15.7 79 16.1 81 3 60-140/30
74-87-3 Methyl Chloride 20 16.5 83 16.4 82 1 60-140/30
75-09-2 Methylene Chloride 20 17.6 88 17.8 89 1 70-130/30
78-93-3 Methyl Ethyl Ketone 50 40.9 82 41.9 84 2 70-130/30
108-10-1 4-Methyl-2-pentanone 50 45.8 92 46.8 94 2 70-130/30
1634-04-4 Methyl Tert Butyl Ether 20 18.8 94 18.4 92 2 70-130/30
91-20-3 Naphthalene 20 20.3 102 20.5 103 1 70-130/30
103-65-1 n-Propylbenzene 20 17.3 87 17.2 86 1 70-130/30
100-42-5 Styrene 20 19.1 96 19.3 97 1 70-130/30
630-20-6 1,1,1,2-Tetrachloroethane 20 21.1 106 21.3 107 1 70-130/30
79-34-5 1,1,2,2-Tetrachloroethane 20 17.8 89 17.7 89 1 70-130/30
127-18-4 Tetrachloroethylene 20 19.6 98 19.6 98 0 70-130/30
108-88-3 Toluene 20 19.0 95 18.9 95 1 70-130/30
87-61-6 1,2,3-Trichlorobenzene 20 20.6 103 20.5 103 0 70-130/30
120-82-1 1,2,4-Trichlorobenzene 20 20.0 100 19.8 99 1 70-130/30
71-55-6 1,1,1-Trichloroethane 20 17.9 90 18.0 90 1 70-130/30
79-00-5 1,1,2-Trichloroethane 20 19.0 95 19.1 96 1 70-130/30
79-01-6 Trichloroethylene 20 18.8 94 19.0 95 1 70-130/30
75-69-4 Trichlorofluoromethane 20 17.8 89 17.8 89 0 60-140/30
96-18-4 1,2,3-Trichloropropane 20 19.1 96 18.3 92 4 70-130/30
95-63-6 1,2,4-Trimethylbenzene 20 17.6 88 17.4 87 1 70-130/30
108-67-8 1,3,5-Trimethylbenzene 20 18.1 91 18.0 90 1 70-130/30
108-05-4 Vinyl Acetate 20 19.7 99 19.0 95 4 70-130/30
75-01-4 Vinyl Chloride 20 17.9 90 17.7 89 1 60-140/30
m,p-Xylene 40 37.9 95 37.8 95 0 70-130/30
95-47-6 o-Xylene 20 18.6 93 18.6 93 0 70-130/30
1330-20-7 Xylene (total)60 56.5 94 56.4 94 0 70-130/30
CAS No.Surrogate Recoveries BSP BSD Limits
17060-07-0 1,2-Dichloroethane-D4 92%93%70-130%
2037-26-5 Toluene-D8 98%101%70-130%
460-00-4 4-Bromofluorobenzene 100%102%70-130%
* = Outside of Control Limits.
41 of 50
LA5781755.2.1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 2
Job Number:LA57817
Account:ATCNCR ATC Group Services LLC
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2K2099-BS1 2K0118083.D 1 09/27/19 CP n/a n/a V2K2099
V2K2099-BSD1 2K0118084.D 1 09/27/19 CP n/a n/a V2K2099
The QC reported here applies to the following samples:Method: SM 6200B
LA57817-3, LA57817-5, LA57817-6, LA57817-7
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
67-64-1 Acetone 50 38.5 77 37.2 74 3 70-130/30
71-43-2 Benzene 20 16.9 85 17.7 89 5 70-130/30
108-86-1 Bromobenzene 20 17.2 86 18.1 91 5 70-130/30
74-97-5 Bromochloromethane 20 16.3 82 16.2 81 1 70-130/30
75-27-4 Bromodichloromethane 20 17.1 86 18.3 92 7 70-130/30
75-25-2 Bromoform 20 18.9 95 19.5 98 3 70-130/30
104-51-8 n-Butylbenzene 20 16.1 81 17.2 86 7 70-130/30
135-98-8 sec-Butylbenzene 20 16.1 81 17.3 87 7 70-130/30
98-06-6 tert-Butylbenzene 20 16.4 82 17.4 87 6 70-130/30
56-23-5 Carbon Tetrachloride 20 17.3 87 18.5 93 7 70-130/30
108-90-7 Chlorobenzene 20 18.4 92 20.1 101 9 70-130/30
75-00-3 Chloroethane 20 17.5 88 16.7 84 5 60-140/30
67-66-3 Chloroform 20 16.2 81 16.9 85 4 70-130/30
95-49-8 o-Chlorotoluene 20 16.1 81 16.9 85 5 70-130/30
106-43-4 p-Chlorotoluene 20 15.6 78 16.2 81 4 70-130/30
124-48-1 Dibromochloromethane 20 18.1 91 20.0 100 10 70-130/30
106-93-4 1,2-Dibromoethane 20 17.1 86 18.0 90 5 70-130/30
75-71-8 Dichlorodifluoromethane 20 15.7 79 14.9 75 5 60-140/30
541-73-1 m-Dichlorobenzene 20 16.0 80 16.9 85 5 70-130/30
95-50-1 o-Dichlorobenzene 20 16.2 81 17.1 86 5 70-130/30
106-46-7 p-Dichlorobenzene 20 15.4 77 16.5 83 7 70-130/30
75-34-3 1,1-Dichloroethane 20 16.8 84 17.7 89 5 70-130/30
107-06-2 1,2-Dichloroethane 20 16.7 84 17.3 87 4 70-130/30
75-35-4 1,1-Dichloroethylene 20 17.0 85 17.9 90 5 70-130/30
156-59-2 cis-1,2-Dichloroethylene 20 16.2 81 17.4 87 7 70-130/30
156-60-5 trans-1,2-Dichloroethylene 20 16.2 81 17.1 86 5 70-130/30
78-87-5 1,2-Dichloropropane 20 17.3 87 18.3 92 6 70-130/30
142-28-9 1,3-Dichloropropane 20 17.2 86 17.7 89 3 70-130/30
594-20-7 2,2-Dichloropropane 20 18.1 91 18.8 94 4 70-130/30
563-58-6 1,1-Dichloropropene 20 16.7 84 17.7 89 6 70-130/30
10061-01-5 cis-1,3-Dichloropropene 20 19.4 97 20.0 100 3 70-130/30
10061-02-6 trans-1,3-Dichloropropene 20 19.7 99 20.2 101 3 70-130/30
108-20-3 Di-Isopropyl Ether 20 16.9 85 17.9 90 6 70-130/30
64-17-5 Ethyl Alcohol 400 295 74 298 75 1 70-130/30
100-41-4 Ethylbenzene 20 17.7 89 18.6 93 5 70-130/30
591-78-6 2-Hexanone 50 39.3 79 45.0 90 14 70-130/30
* = Outside of Control Limits.
42 of 50
LA5781755.2.2
Blank Spike/Blank Spike Duplicate Summary Page 2 of 2
Job Number:LA57817
Account:ATCNCR ATC Group Services LLC
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2K2099-BS1 2K0118083.D 1 09/27/19 CP n/a n/a V2K2099
V2K2099-BSD1 2K0118084.D 1 09/27/19 CP n/a n/a V2K2099
The QC reported here applies to the following samples:Method: SM 6200B
LA57817-3, LA57817-5, LA57817-6, LA57817-7
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
98-82-8 Isopropylbenzene 20 17.3 87 18.4 92 6 70-130/30
99-87-6 p-Isopropyltoluene 20 16.3 82 17.4 87 7 70-130/30
74-83-9 Methyl Bromide 20 15.5 78 15.2 76 2 60-140/30
74-87-3 Methyl Chloride 20 16.5 83 16.0 80 3 60-140/30
75-09-2 Methylene Chloride 20 16.2 81 16.5 83 2 70-130/30
78-93-3 Methyl Ethyl Ketone 50 38.2 76 38.3 77 0 70-130/30
108-10-1 4-Methyl-2-pentanone 50 40.9 82 43.2 86 5 70-130/30
1634-04-4 Methyl Tert Butyl Ether 20 16.9 85 18.1 91 7 70-130/30
91-20-3 Naphthalene 20 18.1 91 19.3 97 6 70-130/30
103-65-1 n-Propylbenzene 20 15.6 78 16.6 83 6 70-130/30
100-42-5 Styrene 20 17.7 89 18.7 94 5 70-130/30
630-20-6 1,1,1,2-Tetrachloroethane 20 19.4 97 20.7 104 6 70-130/30
79-34-5 1,1,2,2-Tetrachloroethane 20 15.8 79 16.8 84 6 70-130/30
127-18-4 Tetrachloroethylene 20 17.9 90 19.0 95 6 70-130/30
108-88-3 Toluene 20 17.4 87 18.6 93 7 70-130/30
87-61-6 1,2,3-Trichlorobenzene 20 17.8 89 19.2 96 8 70-130/30
120-82-1 1,2,4-Trichlorobenzene 20 17.8 89 19.0 95 7 70-130/30
71-55-6 1,1,1-Trichloroethane 20 17.0 85 17.6 88 3 70-130/30
79-00-5 1,1,2-Trichloroethane 20 17.4 87 18.2 91 4 70-130/30
79-01-6 Trichloroethylene 20 17.4 87 18.1 91 4 70-130/30
75-69-4 Trichlorofluoromethane 20 18.3 92 17.5 88 4 60-140/30
96-18-4 1,2,3-Trichloropropane 20 16.8 84 17.4 87 4 70-130/30
95-63-6 1,2,4-Trimethylbenzene 20 15.6 78 16.8 84 7 70-130/30
108-67-8 1,3,5-Trimethylbenzene 20 16.1 81 17.1 86 6 70-130/30
108-05-4 Vinyl Acetate 20 18.0 90 19.0 95 5 70-130/30
75-01-4 Vinyl Chloride 20 17.8 89 17.3 87 3 60-140/30
m,p-Xylene 40 34.9 87 37.1 93 6 70-130/30
95-47-6 o-Xylene 20 17.0 85 18.2 91 7 70-130/30
1330-20-7 Xylene (total)60 51.9 87 55.3 92 6 70-130/30
CAS No.Surrogate Recoveries BSP BSD Limits
17060-07-0 1,2-Dichloroethane-D4 94%89%70-130%
2037-26-5 Toluene-D8 100%100%70-130%
460-00-4 4-Bromofluorobenzene 103%104%70-130%
* = Outside of Control Limits.
43 of 50
LA5781755.2.2
Blank Spike/Blank Spike Duplicate Summary Page 1 of 2
Job Number:LA57817
Account:ATCNCR ATC Group Services LLC
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2K2100-BS1 2K0118098.D 1 09/30/19 CP n/a n/a V2K2100
V2K2100-BSD1 2K0118099.D 1 09/30/19 CP n/a n/a V2K2100
The QC reported here applies to the following samples:Method: SM 6200B
LA57817-8
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
67-64-1 Acetone 50 59.1 118 59.9 120 1 70-130/30
108-86-1 Bromobenzene 20 19.6 98 19.7 99 1 70-130/30
74-97-5 Bromochloromethane 20 19.4 97 19.1 96 2 70-130/30
75-27-4 Bromodichloromethane 20 20.3 102 20.2 101 0 70-130/30
75-25-2 Bromoform 20 21.5 108 21.7 109 1 70-130/30
104-51-8 n-Butylbenzene 20 19.8 99 18.6 93 6 70-130/30
135-98-8 sec-Butylbenzene 20 19.4 97 18.5 93 5 70-130/30
98-06-6 tert-Butylbenzene 20 19.7 99 18.7 94 5 70-130/30
56-23-5 Carbon Tetrachloride 20 21.3 107 20.9 105 2 70-130/30
108-90-7 Chlorobenzene 20 21.3 107 21.7 109 2 70-130/30
75-00-3 Chloroethane 20 16.9 85 16.4 82 3 60-140/30
67-66-3 Chloroform 20 19.4 97 19.6 98 1 70-130/30
95-49-8 o-Chlorotoluene 20 18.7 94 18.1 91 3 70-130/30
106-43-4 p-Chlorotoluene 20 18.3 92 17.8 89 3 70-130/30
124-48-1 Dibromochloromethane 20 21.8 109 20.8 104 5 70-130/30
106-93-4 1,2-Dibromoethane 20 19.4 97 19.3 97 1 70-130/30
75-71-8 Dichlorodifluoromethane 20 14.8 74 14.2 71 4 60-140/30
541-73-1 m-Dichlorobenzene 20 18.9 95 18.2 91 4 70-130/30
95-50-1 o-Dichlorobenzene 20 19.0 95 18.5 93 3 70-130/30
106-46-7 p-Dichlorobenzene 20 18.1 91 17.6 88 3 70-130/30
75-34-3 1,1-Dichloroethane 20 20.3 102 20.2 101 0 70-130/30
107-06-2 1,2-Dichloroethane 20 19.6 98 19.2 96 2 70-130/30
75-35-4 1,1-Dichloroethylene 20 20.7 104 20.4 102 1 70-130/30
156-59-2 cis-1,2-Dichloroethylene 20 19.5 98 19.8 99 2 70-130/30
156-60-5 trans-1,2-Dichloroethylene 20 19.9 100 19.5 98 2 70-130/30
78-87-5 1,2-Dichloropropane 20 20.2 101 20.1 101 0 70-130/30
142-28-9 1,3-Dichloropropane 20 19.4 97 19.4 97 0 70-130/30
594-20-7 2,2-Dichloropropane 20 22.5 113 22.0 110 2 70-130/30
563-58-6 1,1-Dichloropropene 20 20.6 103 20.3 102 1 70-130/30
10061-01-5 cis-1,3-Dichloropropene 20 22.7 114 22.4 112 1 70-130/30
10061-02-6 trans-1,3-Dichloropropene 20 22.6 113 22.4 112 1 70-130/30
108-20-3 Di-Isopropyl Ether 20 20.4 102 21.1 106 3 70-130/30
64-17-5 Ethyl Alcohol 400 381 95 357 89 7 70-130/30
591-78-6 2-Hexanone 50 50.5 101 50.8 102 1 70-130/30
98-82-8 Isopropylbenzene 20 20.4 102 19.8 99 3 70-130/30
99-87-6 p-Isopropyltoluene 20 19.6 98 18.6 93 5 70-130/30
* = Outside of Control Limits.
44 of 50
LA5781755.2.3
Blank Spike/Blank Spike Duplicate Summary Page 2 of 2
Job Number:LA57817
Account:ATCNCR ATC Group Services LLC
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2K2100-BS1 2K0118098.D 1 09/30/19 CP n/a n/a V2K2100
V2K2100-BSD1 2K0118099.D 1 09/30/19 CP n/a n/a V2K2100
The QC reported here applies to the following samples:Method: SM 6200B
LA57817-8
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
74-83-9 Methyl Bromide 20 15.0 75 15.4 77 3 60-140/30
74-87-3 Methyl Chloride 20 15.6 78 15.6 78 0 60-140/30
75-09-2 Methylene Chloride 20 19.0 95 19.4 97 2 70-130/30
78-93-3 Methyl Ethyl Ketone 50 51.0 102 52.9 106 4 70-130/30
108-10-1 4-Methyl-2-pentanone 50 49.6 99 49.4 99 0 70-130/30
1634-04-4 Methyl Tert Butyl Ether 20 20.3 102 20.5 103 1 70-130/30
91-20-3 Naphthalene 20 21.3 107 21.0 105 1 70-130/30
103-65-1 n-Propylbenzene 20 18.5 93 17.6 88 5 70-130/30
100-42-5 Styrene 20 20.3 102 20.1 101 1 70-130/30
630-20-6 1,1,1,2-Tetrachloroethane 20 22.3 112 22.2 111 0 70-130/30
79-34-5 1,1,2,2-Tetrachloroethane 20 18.0 90 17.8 89 1 70-130/30
127-18-4 Tetrachloroethylene 20 20.8 104 20.4 102 2 70-130/30
87-61-6 1,2,3-Trichlorobenzene 20 21.6 108 21.4 107 1 70-130/30
120-82-1 1,2,4-Trichlorobenzene 20 21.1 106 20.2 101 4 70-130/30
71-55-6 1,1,1-Trichloroethane 20 20.6 103 20.3 102 1 70-130/30
79-00-5 1,1,2-Trichloroethane 20 19.6 98 19.7 99 1 70-130/30
79-01-6 Trichloroethylene 20 20.5 103 20.0 100 2 70-130/30
75-69-4 Trichlorofluoromethane 20 17.9 90 17.4 87 3 60-140/30
96-18-4 1,2,3-Trichloropropane 20 19.0 95 19.0 95 0 70-130/30
108-67-8 1,3,5-Trimethylbenzene 20 19.2 96 18.3 92 5 70-130/30
108-05-4 Vinyl Acetate 20 21.1 106 21.2 106 0 70-130/30
75-01-4 Vinyl Chloride 20 16.9 85 16.4 82 3 60-140/30
CAS No.Surrogate Recoveries BSP BSD Limits
17060-07-0 1,2-Dichloroethane-D4 92%96%70-130%
2037-26-5 Toluene-D8 100%98%70-130%
460-00-4 4-Bromofluorobenzene 102%104%70-130%
* = Outside of Control Limits.
45 of 50
LA5781755.2.3
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 3
Job Number:LA57817
Account:ATCNCR ATC Group Services LLC
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
LA57817-3MS 2K0118067.D 20 09/26/19 CP n/a n/a V2K2097
LA57817-3MSD 2K0118068.D 20 09/26/19 CP n/a n/a V2K2097
LA57817-3 a 2K0118060.D 10 09/26/19 CP n/a n/a V2K2097
The QC reported here applies to the following samples:Method: SM 6200B
LA57817-1, LA57817-2, LA57817-4, LA57817-5, LA57817-6, LA57817-8, LA57817-9
LA57817-3 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
67-64-1 Acetone ND 1000 536 54*1000 493 49*8 70-130/20
71-43-2 Benzene ND 400 386 97 400 336 84 14 70-130/20
108-86-1 Bromobenzene ND 400 383 96 400 337 84 13 70-130/20
74-97-5 Bromochloromethane ND 400 360 90 400 312 78 14 70-130/20
75-27-4 Bromodichloromethane ND 400 380 95 400 331 83 14 70-130/20
75-25-2 Bromoform ND 400 411 103 400 370 93 10 70-130/20
104-51-8 n-Butylbenzene ND 400 342 86 400 310 78 10 70-130/20
135-98-8 sec-Butylbenzene ND 400 358 90 400 321 80 11 70-130/20
98-06-6 tert-Butylbenzene ND 400 366 92 400 329 82 11 70-130/20
56-23-5 Carbon Tetrachloride ND 400 385 96 400 333 83 14 70-130/20
108-90-7 Chlorobenzene ND 400 423 106 400 366 92 14 70-130/20
75-00-3 Chloroethane ND 400 334 84 400 324 81 3 60-140/20
67-66-3 Chloroform ND 400 367 92 400 314 79 16 70-130/20
95-49-8 o-Chlorotoluene ND 400 361 90 400 318 80 13 70-130/20
106-43-4 p-Chlorotoluene ND 400 350 88 400 316 79 10 70-130/20
124-48-1 Dibromochloromethane ND 400 414 104 400 360 90 14 70-130/20
106-93-4 1,2-Dibromoethane ND 400 379 95 400 336 84 12 70-130/20
75-71-8 Dichlorodifluoromethane ND 400 313 78 400 297 74 5 60-140/20
541-73-1 m-Dichlorobenzene ND 400 357 89 400 322 81 10 70-130/20
95-50-1 o-Dichlorobenzene ND 400 365 91 400 329 82 10 70-130/20
106-46-7 p-Dichlorobenzene ND 400 346 87 400 312 78 10 70-130/20
75-34-3 1,1-Dichloroethane ND 400 381 95 400 324 81 16 70-130/20
107-06-2 1,2-Dichloroethane ND 400 371 93 400 314 79 17 70-130/20
75-35-4 1,1-Dichloroethylene ND 400 380 95 400 331 83 14 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 400 371 93 400 320 80 15 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 400 362 91 400 313 78 15 70-130/20
78-87-5 1,2-Dichloropropane ND 400 396 99 400 336 84 16 70-130/20
142-28-9 1,3-Dichloropropane ND 400 384 96 400 342 86 12 70-130/20
594-20-7 2,2-Dichloropropane ND 400 349 87 400 303 76 14 70-130/20
563-58-6 1,1-Dichloropropene ND 400 371 93 400 321 80 14 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 400 421 105 400 363 91 15 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 400 422 106 400 369 92 13 70-130/20
108-20-3 Di-Isopropyl Ether ND 400 386 97 400 339 85 13 70-130/20
64-17-5 Ethyl Alcohol ND 8000 5510 69*8000 5310 66*4 70-130/20
100-41-4 Ethylbenzene ND 400 394 99 400 342 86 14 70-130/20
591-78-6 2-Hexanone ND 1000 801 80 1000 703 70 13 70-130/20
* = Outside of Control Limits.
46 of 50
LA5781755.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 3
Job Number:LA57817
Account:ATCNCR ATC Group Services LLC
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
LA57817-3MS 2K0118067.D 20 09/26/19 CP n/a n/a V2K2097
LA57817-3MSD 2K0118068.D 20 09/26/19 CP n/a n/a V2K2097
LA57817-3 a 2K0118060.D 10 09/26/19 CP n/a n/a V2K2097
The QC reported here applies to the following samples:Method: SM 6200B
LA57817-1, LA57817-2, LA57817-4, LA57817-5, LA57817-6, LA57817-8, LA57817-9
LA57817-3 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
98-82-8 Isopropylbenzene ND 400 386 97 400 339 85 13 70-130/20
99-87-6 p-Isopropyltoluene ND 400 359 90 400 324 81 10 70-130/20
74-83-9 Methyl Bromide ND 400 259 65 400 290 73 11 60-140/20
74-87-3 Methyl Chloride ND 400 322 81 400 309 77 4 60-140/20
75-09-2 Methylene Chloride ND 400 370 93 400 323 81 14 70-130/20
78-93-3 Methyl Ethyl Ketone ND 1000 775 78 1000 661 66*16 70-130/20
108-10-1 4-Methyl-2-pentanone ND 1000 922 92 1000 802 80 14 70-130/20
1634-04-4 Methyl Tert Butyl Ether ND 400 375 94 400 339 85 10 70-130/20
91-20-3 Naphthalene 4.4 400 398 98 400 372 92 7 70-130/20
103-65-1 n-Propylbenzene ND 400 345 86 400 313 78 10 70-130/20
100-42-5 Styrene ND 400 393 98 400 344 86 13 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 400 443 111 400 377 94 16 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 400 360 90 400 331 83 8 70-130/20
127-18-4 Tetrachloroethylene ND 400 390 98 400 344 86 13 70-130/20
108-88-3 Toluene ND 400 395 99 400 339 85 15 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 400 385 96 400 364 91 6 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 400 379 95 400 355 89 7 70-130/20
71-55-6 1,1,1-Trichloroethane ND 400 373 93 400 327 82 13 70-130/20
79-00-5 1,1,2-Trichloroethane ND 400 385 96 400 349 87 10 70-130/20
79-01-6 Trichloroethylene ND 400 378 95 400 333 83 13 70-130/20
75-69-4 Trichlorofluoromethane ND 400 349 87 400 331 83 5 60-140/20
96-18-4 1,2,3-Trichloropropane ND 400 363 91 400 327 82 10 70-130/20
95-63-6 1,2,4-Trimethylbenzene ND 400 357 89 400 316 79 12 70-130/20
108-67-8 1,3,5-Trimethylbenzene ND 400 365 91 400 326 82 11 70-130/20
108-05-4 Vinyl Acetate ND 400 408 102 400 369 92 10 70-130/20
75-01-4 Vinyl Chloride ND 400 352 88 400 331 83 6 60-140/20
m,p-Xylene ND 800 784 98 800 685 86 13 70-130/20
95-47-6 o-Xylene ND 400 384 96 400 336 84 13 70-130/20
1330-20-7 Xylene (total)ND 1200 1170 98 1200 1020 85 14 70-130/20
CAS No.Surrogate Recoveries MS MSD LA57817-3 Limits
17060-07-0 1,2-Dichloroethane-D4 91%90%91%70-130%
2037-26-5 Toluene-D8 99%99%94%70-130%
460-00-4 4-Bromofluorobenzene 103%100%94%70-130%
* = Outside of Control Limits.
47 of 50
LA5781755.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number:LA57817
Account:ATCNCR ATC Group Services LLC
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
LA57817-3MS 2K0118067.D 20 09/26/19 CP n/a n/a V2K2097
LA57817-3MSD 2K0118068.D 20 09/26/19 CP n/a n/a V2K2097
LA57817-3 a 2K0118060.D 10 09/26/19 CP n/a n/a V2K2097
The QC reported here applies to the following samples:Method: SM 6200B
LA57817-1, LA57817-2, LA57817-4, LA57817-5, LA57817-6, LA57817-8, LA57817-9
(a) rr o/d Sample used for QC purposes only.
* = Outside of Control Limits.
48 of 50
LA5781755.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:LA57817
Account:ATCNCR ATC Group Services LLC
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
LA57817-5MS 2K0118107.D 100 09/30/19 CP n/a n/a V2K2100
LA57817-5MSD 2K0118108.D 100 09/30/19 CP n/a n/a V2K2100
LA57817-5 a 2K0118104.D 100 09/30/19 CP n/a n/a V2K2100
The QC reported here applies to the following samples:Method: SM 6200B
LA57817-8
LA57817-5 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
67-64-1 Acetone 133 5000 3140 60* b 5000 3000 57* b 5 70-130/20
108-86-1 Bromobenzene ND 2000 1600 80 2000 1610 81 1 70-130/20
74-97-5 Bromochloromethane ND 2000 1840 92 2000 1720 86 7 70-130/20
75-27-4 Bromodichloromethane ND 2000 1720 86 2000 1710 86 1 70-130/20
75-25-2 Bromoform ND 2000 1740 87 2000 1720 86 1 70-130/20
104-51-8 n-Butylbenzene 45.5 2000 1310 63* b 2000 1360 66* b 4 70-130/20
135-98-8 sec-Butylbenzene 25.5 2000 1480 73 2000 1470 72 1 70-130/20
98-06-6 tert-Butylbenzene ND 2000 1550 78 2000 1530 77 1 70-130/20
56-23-5 Carbon Tetrachloride ND 2000 1940 97 2000 1880 94 3 70-130/20
108-90-7 Chlorobenzene ND 2000 1760 88 2000 1710 86 3 70-130/20
75-00-3 Chloroethane ND 2000 1940 97 2000 1860 93 4 60-140/20
67-66-3 Chloroform ND 2000 1860 93 2000 1790 90 4 70-130/20
95-49-8 o-Chlorotoluene ND 2000 1500 75 2000 1490 75 1 70-130/20
106-43-4 p-Chlorotoluene ND 2000 1400 70 2000 1390 70 1 70-130/20
124-48-1 Dibromochloromethane ND 2000 1780 89 2000 1750 88 2 70-130/20
106-93-4 1,2-Dibromoethane ND 2000 1670 84 2000 1600 80 4 70-130/20
75-71-8 Dichlorodifluoromethane ND 2000 1490 75 2000 1430 72 4 60-140/20
541-73-1 m-Dichlorobenzene ND 2000 1460 73 2000 1440 72 1 70-130/20
95-50-1 o-Dichlorobenzene ND 2000 1560 78 2000 1530 77 2 70-130/20
106-46-7 p-Dichlorobenzene ND 2000 1390 70 2000 1380 69* b 1 70-130/20
75-34-3 1,1-Dichloroethane ND 2000 1940 97 2000 1870 94 4 70-130/20
107-06-2 1,2-Dichloroethane 35.4 2000 1700 83 2000 1610 79 5 70-130/20
75-35-4 1,1-Dichloroethylene ND 2000 1850 93 2000 1730 87 7 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 2000 1840 92 2000 1780 89 3 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 2000 1690 85 2000 1580 79 7 70-130/20
78-87-5 1,2-Dichloropropane ND 2000 1770 89 2000 1700 85 4 70-130/20
142-28-9 1,3-Dichloropropane ND 2000 1630 82 2000 1610 81 1 70-130/20
594-20-7 2,2-Dichloropropane ND 2000 231 12* b 2000 207 10* b 11 70-130/20
563-58-6 1,1-Dichloropropene ND 2000 1750 88 2000 1680 84 4 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 2000 1360 68* b 2000 1300 65* b 5 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 2000 1290 65* b 2000 1260 63* b 2 70-130/20
108-20-3 Di-Isopropyl Ether 43.0 2000 2030 99 2000 1950 95 4 70-130/20
64-17-5 Ethyl Alcohol ND 40000 31400 79 40000 31700 79 1 70-130/20
591-78-6 2-Hexanone ND 5000 3830 77 5000 3790 76 1 70-130/20
98-82-8 Isopropylbenzene 114 2000 1750 82 2000 1730 81 1 70-130/20
99-87-6 p-Isopropyltoluene 13.8 2000 1470 73 2000 1470 73 0 70-130/20
* = Outside of Control Limits.
49 of 50
LA5781755.3.2
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:LA57817
Account:ATCNCR ATC Group Services LLC
Project:Cary Beverage 526 E. Chatham Street, Cary, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
LA57817-5MS 2K0118107.D 100 09/30/19 CP n/a n/a V2K2100
LA57817-5MSD 2K0118108.D 100 09/30/19 CP n/a n/a V2K2100
LA57817-5 a 2K0118104.D 100 09/30/19 CP n/a n/a V2K2100
The QC reported here applies to the following samples:Method: SM 6200B
LA57817-8
LA57817-5 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
74-83-9 Methyl Bromide ND 2000 1400 70 2000 1600 80 13 60-140/20
74-87-3 Methyl Chloride ND 2000 1840 92 2000 1780 89 3 60-140/20
75-09-2 Methylene Chloride 16.5 2000 1890 94 2000 1810 90 4 70-130/20
78-93-3 Methyl Ethyl Ketone 925 5000 4850 79 5000 4620 74 5 70-130/20
108-10-1 4-Methyl-2-pentanone ND 5000 4070 81 5000 4030 81 1 70-130/20
1634-04-4 Methyl Tert Butyl Ether 949 2000 3070 106 2000 2930 99 5 70-130/20
91-20-3 Naphthalene 618 2000 2360 87 2000 2410 90 2 70-130/20
103-65-1 n-Propylbenzene 300 2000 1690 70 2000 1680 69* b 1 70-130/20
100-42-5 Styrene ND 2000 1660 83 2000 1600 80 4 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 2000 1860 93 2000 1810 91 3 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 2000 1520 76 2000 1500 75 1 70-130/20
127-18-4 Tetrachloroethylene ND 2000 1500 75 2000 1500 75 0 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 2000 1620 81 2000 1690 85 4 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 2000 1520 76 2000 1520 76 0 70-130/20
71-55-6 1,1,1-Trichloroethane ND 2000 1930 97 2000 1850 93 4 70-130/20
79-00-5 1,1,2-Trichloroethane ND 2000 1740 87 2000 1660 83 5 70-130/20
79-01-6 Trichloroethylene ND 2000 1650 83 2000 1610 81 2 70-130/20
75-69-4 Trichlorofluoromethane ND 2000 1990 100 2000 1910 96 4 60-140/20
96-18-4 1,2,3-Trichloropropane ND 2000 1670 84 2000 1570 79 6 70-130/20
108-67-8 1,3,5-Trimethylbenzene 612 2000 2060 72 2000 2050 72 0 70-130/20
108-05-4 Vinyl Acetate ND 2000 1780 89 2000 1690 85 5 70-130/20
75-01-4 Vinyl Chloride ND 2000 1920 96 2000 1780 89 8 60-140/20
CAS No.Surrogate Recoveries MS MSD LA57817-5 Limits
17060-07-0 1,2-Dichloroethane-D4 107%100%101%70-130%
2037-26-5 Toluene-D8 99%100%98%70-130%
460-00-4 4-Bromofluorobenzene 101%100%98%70-130%
(a) Sample used for QC purposes only.
(b) Outside control limits biased high. Blank spike passed criteria.
* = Outside of Control Limits.
50 of 50
LA5781755.3.2