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HomeMy WebLinkAbout1302_Cabarrus_MSWLF_Unit1_May20GW_FID1417254_20200625Cabarrus County Sanitary Landfill — Unit 1 Semi -Annual Sampling Report Facilit� Permit # 1302-MSWLF-1974 (May 2020 Sampling Event) prepared June 2020 I pEN CUBE ONLY: I OPapsx Report DElectrunic Data- Email Go (data baited: Yes/No) DorJEverd#: C DENR Environmental Monitoring Division of Waste Management - Solid Waste ReDoRino Form Notice: This form and any information attached to it am'Public Records as defined in NC General Smbde 132-1. As such, these documents are available for inspection and examination by any person upon request INC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. • Please type or print legibly. • Attach a nofification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existirg condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceetl the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any shuctures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). • Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitorina Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner) Consultant - CDM Smith Inc. Contact for Questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Matlmw F. Galore Phone: (919) 325-3500 E-mail- wick mNix in mithcore Facility name: Cabanus County La ditfi UnN 1 NC Landfill Rule: Actual sampling dates (e.g., Permit # (.0500 or.1600) October 20-24, 2006) 4441 Irish Potato Road 1974 MSWLF I .0500 I May 18 19, 2020 Concord, North Carolina 28025 11 Environmental Status: (Check all that apply) ❑ IngiaDBackground Monitoring ❑x Detection Monitoring Assessment Monitoring ❑ Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring he ❑ Methane gas monitoring data Groundwater monitoring data from private water supply wells ❑ Corrective action data (specify) Leachate monitoring data ❑ OMer(spacify) Sun.. water moni ems, data NolNlcatio i attached? No. No groundwater or surface water standards were exceeded. x Yes, a notification of values exceeding a groundwater or surface water standard is attached. It Includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. it includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachmaMs are true and correct. Furthermore, 1 have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certilcation including the possibility of a Tine and Imprisonment. F _ Represe^'��Name(Prirtd TO. (Area Code) Telephone Number All. NCR*��rsipedl P fe oraly� cologist Seal Signature Date/'ih'_Mfl Il, Y!l. /1 .P v 5400 Gianwootl Avenue Suite 400 Raleigh North Carolina 27612 Facility Representative Address NC PE Flnn License Number (if applicable efincfive May 1, 2D09) Revised 612009� �ZC I27� CDM Smith 5400 Glenwood Avenue, Suite 400 Raleigh, North Carolina 27612 tel: 919 325-3500 fax: 919 781-5730 June 26, 2020 Ms. Jaclynne Drummond North Carolina Department of Environmental Quality Division of Waste Management Solid Waste Section 2090 U.S. 70 Highway Swannanoa, North Carolina 28778 Subject: May 2020 Semi -Annual Sampling Report Cabarrus County Unit 1 Landfill Facility Permit No. 1302-MSWLF-1974 Dear Ms. Drummond: CDM Smith Inc., on behalf of Cabarrus County, is submitting an electronic copy of the May 2020 semi- annual sampling report for the recent event completed at the Cabarrus County Unit 1 Landfill. This letter report constitutes the first semi-annual sampling event for 2020. The approved monitoring well network consists of compliance wells MW-5, -7, -8A, -10, -11, and background wells CD-1s and -1d. The monitoring network also includes surface water sample locations SW-1 and -2. Field activities and sampling results for the groundwater and surface water samples are discussed below. Field Activities Groundwater and surface water samples from the Cabarrus County Unit 1 Landfill were collected on May 18-19, 2020. Groundwater samples were collected from the monitoring wells by use of disposable, laboratory decontaminated TeflonT" bailers or a QED bladder pump system using low -flow sampling techniques. Monitoring well and surface water sample locations for the Unit 1 landfill are provided on Figure 1. Groundwater elevations were measured at each well prior to sampling and are presented in Table 1. Well construction details for each monitoring well are also provided in Table 1. These groundwater elevations were used to construct potentiometric contours for this sampling event and are presented on Figure 1. After depth to groundwater was measured, each well was purged prior to sampling to provide fresh formation water within the well water column. Each purge volume was measured for pH, conductivity, turbidity, temperature, dissolved oxygen, and oxidation-reduction potential using a YSI Pro Plus multi -parameter water quality meter and Micro TPI or TPW turbidity meters. The water quality parameters at the time of sampling are presented in Table 2. The headspace of each monitoring well was screened for methane gas using a RKI Eagle multi -gas monitor. Screening results are provided in Appendix A. 0 WATER + ENVIRONMENT +TRANSPORTATION + ENERGY + FACILITIES Smith Ms. Jaclynne Drummond June 26, 2020 Page 2 Sampling Results Pace Analytical Services, Inc., located in Peachtree Corners, Georgia, analyzed the groundwater samples for North Carolina Appendix I volatile organic compounds (VOCs) and metals. In a letter dated May 28, 2019, the Solid Waste Section requested that all groundwater and surface water samples collected from landfills be analyzed for 1,4-dioxane after July 1, 2018. On July 1, 2019, the Solid Waste Section approved the removal of 1,4-dioxane from the sampling program for CD-1s and -1d due to two consecutive non -detect events (January and May 2019). However, samples were collected from MW-5, -7, -8A, -10, -11, and SW-1 and -2 during the May 2020 sampling event and analyzed for 1,4- dioxane due to previous detections of 1,4-dioxane. Sample results are provided below. The analytical results were reported to the laboratory specific method detection limit (MDL) and are quantifiable at or below the method reporting limit (MRL). All monitoring wells for the Unit I Landfill had detections of analytes above the MDL but below the MRL. These detections were qualified as estimated or "J" flags. Samples collected from MW-5 had a detection of arsenic qualified with a "B" flag, indicating that the analyte was detected in the method blank. The following list indicates the VOCs and metals detected above the MRL at each sampling location. No "J" flag detections are provided. Underlined analytes exceeded the 15A NCAC 02L .020 (NC 2L) Groundwater Quality Standard, Interim Maximum Allowable Concentration (IMAC), or 15A NCAC 02B or North Carolina In -Stream Target Value Surface Water Quality Standards for Class C Waters. A complete summary of all detected and estimated concentrations from the May 2011 through the May 2020 sampling events is presented in Table 3. Laboratory data reports are provided in Appendix A. CD -Is (Background) Metals: Barium Volatile Organic Compounds: None Detected CD-1d (Background) Metals: Barium Volatile Organic Compounds: None Detected MW-S Metals: Barium, Cobalt, Nickel Volatile Organic Compounds: 1,4-Dioxane MW-7 Metals: Barium, Cobalt, Nickel Volatile Organic Compounds: 1,4-Dioxane 0 Smith Ms. Jaclynne Drummond June 26, 2020 Page 3 MW-8A Metals: Volatile Organic Compounds MW-10 Metals: Volatile Organic Compounds MW-11 Metals: Volatile Organic Compounds SW-1 Metals: Volatile Organic Compounds SW-2 Metals: Volatile Organic Compounds Barium, Cobalt, Copper, Lead, Nickel, Zinc None Detected Arsenic, Barium, Cobalt, Nickel Chlorobenzene, 1,4-Dioxane Barium, Cobalt, Nickel, Zinc 1,4-Dioxane Barium 1,4-Dioxane Barium, Lead, Nickel, Zinc 1,4-Dioxane "J" flags were not included in the previous list, but several locations had "J" flag detections that exceeded the standards. These constituents along with their location are listed below. Antimony: MW-8A Cobalt: SW-1 and -2 Copper: SW-2 Vanadium: CD-1s, -1d, MW-5, -8A, -10, SW-1, and -2 A trip blank and duplicate sample were analyzed for quality control. The trip blank did not have any detections above the MDLs. The duplicate sample, identified as Dup1, was collected from MW-8A, and had similar analyte concentrations as those detected in MW-8A. Metals detected above the standards are likely naturally occurring based on concentrations in the background monitoring wells or are from elevated turbidity at the time of sample collection. VOCs detected above the standards in several of the compliance wells will continue to be monitored. Table 4 presents a summary of all analytes detected during the May 2020 sampling event that exceeded the NC 2L or IMAC Groundwater Standards. The next semi-annual sampling event will be completed in the fall of 2020. iD Smith Ms. Jaclynne Drummond June 26, 2020 Page 4 If you have any questions or require further explanation, do not hesitate to call me at (919) 325-3500 or by email at colonemf@cdmsmith.com. Very truly yours, Mathew F. Colone, P.G. CDM Smith Inc. cc: Kevin Grant, Cabarrus County iD Table 1 Monitoring Well Construction Summary and Groundwater Elevations May 2020 Semi -Annual Sampling Event Unit 1- Cabarrus County Landfill Facility Permit Number 1302-MSWLF-1974 Notes: 1. BTOC - Below Top of Casing 2. bgs - Below Ground Surface 3. PWR - Partially Weathered Rock Smith Page 1 of 1 June 2020 Table 2 Water Quality Measurements May 2020 Semi -Annual Sampling Event Unit 1- Cabarrus County Landfill Facility Permit Number 1302-MSWLF-1974 Water Quality Measurements Facility Permit Monitoring Well Code Dissolved pH Conductivity Temperatures) Turbidity ORP (degrees CD-1s 1302-MSWLF-1974 6.1 122 20.3 9 4.3 -32.4 (background well) CD-1d 1302-MSWLF-1974 6.2 118 20.4 3 2.4 31.5 (background well) 1302-MSWLF-1974 MW-5 6.4 1,785 15.1 8 2.9 13.6 1302-MSWLF-1974 MW-7 6.5 2,636 16.7 24 1.9 14.1 1302-MSWLF-1974 MW-8A 6.3 359 16.9 6 5.7 195.0 1302-MSWLF-1974 MW-10 6.7 1,898 16.1 48 3.1 11.3 1302-MSWLF-1974 MW-11 6.4 759 15.5 8 3.2 12.0 Surface Water Sample Locations 1302-MSWLF-1974 SW-1 7.4 400.3 16.6 13 5.9 13.1 1302-MSWLF-1974 SW-2 7.0 373.9 17.2 109 5.1 66.9 Notes: 1. Water quality measurements were taken on May 18-19, 2020. 2. µS/cm - Microsiemens per centimeter 3. mg/L - Milligrams per liter 4. ORP - Oxidation -Reduction Potential 5. NTUs - Nephelometric Turbidity Units 6. mVs - Millivolts 7. S.U. - Standard Units Smith Page 1 of 1 June 2020 Table 3a Detected Groundwater Constituents - Metals May 2020 Semi -Annual Sampling Event Cabarrus County Unit 1 Landfill Facility Permit Number 1302-MSWLF-1974 rUFFAW-TRILIA,,, „ CD -Is 9-Nov-11 59.7J 0.25B-01,J 4.461 2.67J 12.4 1.901 4.411 0.081 11.21 1 18.2 CD -Is 28-Nov-12 63.8J OIL 5.65J 3.05J 11.6 1.431 4.66J 17.L 16.9 CD-1s 7-May-13 0.941 2.4OB1 35.6J 0.881 0.671 4.041 0.391 1.781 0.131 6.061 5.081 CD -Is 5-Nov-13 46.8J 0.12J 3.59J 1.63J 10.2 1.351 3.50J 18.4BJ 15.4E CD-1s 6-May-14 28.8J 4.1481 1.481 0.111 1.031 0.311 3.40J 2.98B1 CD -Is 4-Nov-14 28.7J 0.13J 1.311 0.061 1.04J 0.11i 2.57B-01,J 1.581 CD-ls 5-May-15 1.631 29.5B-01,J 1.331 0.151 1.171 2.40J 2.75B-01,J CD -Is 27-Oct-15 28.41 0.801 O.39J 0.751 0.121 1.21J 4.19CN,J 0.151 4.10J 3.36E-01,J 1302-MSWLF-1974 CD-1s 17-May-16 29.1 0.941 0.991 0.121 1.011 4.70J 1.931 CD -Is 1-Nov-16 3O.5J 1.231 1.361 0.281 1.35J 4.30J CD-1s 9-May-17 34.1 1.171 1.261 0.201 0.971 1.821 b.bW CD-1s 31-Oct-17 0.52J 36.31 1.81J 0.541 2.871 0.371 1.41J 6.91J 4.0J CD-ls 11-Jun-18 28.9J 4.31 4.4J CD -Is 17-Dec-18 26.7J 0.601 3.6J 15.01 7.01 9.5J CD-1s 7-May-19 29.8 1.3J 7.01 5.1J CD-ls 6-Nov-19 31.9 1.0J 1.81E 0.O7OJ 0.73J 5.01 7.3JB CD-1s 18-May-20 0.46J 34.5 2.2J 0.92J 0.23J 1.4J 6.41 6.91 CD-1d 8-Nov-11 74.5J 0.511 4.08J 26.8 2.84J 5.68J 24.6J 26.3 0.941 CD-ld 28-Nov-12 0.331 37.7J 0.07J 2.38J 12.6 1.14J 2.5OJ 8.90J 13 CD-1d 8-May-13 0.88J 1.02B1 31.2J 0.07J 0.781 4.501 0.49J 1.921 6.18J 13.1 CD-ld 5-Nov-13 35.0J 0.861 4.34J 1.13J 1.901 17.181 10.8B CD-1d 6-May-14 1.14J 37.8J 0.07J 0.05J 3.22B1 7.341 0.811 2.74J 0.121 6.16J 9.41B1 CD-ld 4-Nov-14 43.1J 0.16J 0.111 9.091 0.87J 2.881 1O.2B-01,J 10.7 CD-1d 5-May-15 34.5B-01,J 0.841 3.63J 0.39J 1.42J 5.181 3.68E-01,J CD-ld 27-Oct-15 0.42J 42.3J 0.13J 1.87J 2 8.181 0.97J 2.491 4.37CN,J 0.061 10.91 14.0B-01 1302-MSWLF-1974 CD-1d 17-May-16 81.31 0.46J 4.86J 26.0 3.13J 7.11J 2.11J 0.071 29.3 29.7 CD-ld 1-Nov-16 32.6J 1.191 0.77J 2.82J 0.33J 1.241 7.961 4.291 CD-ld 9-May-17 33.9J 1.27J 0.521 1.811 6.921 1.091 6.95J 3.12J CD-1d 31-Oct-17 29.5J 0.68J 0.61J 0.111 0.641 5.381 1.24J CD-ld 12-Jun-18 32.4J 2.5J 1.01 6.9J 3.21 CD-1d 17-Dec-18 31.9J 9.3J 2.3J 0.411 3.0J 6.81 4.1J CD-ld 7-May-19 30.7 1.4J 7.4J 2.91 CD-1d 5-Nov-19 0.481 30.1 1.91 1.11B 0.131 1.8J 4.7J 8.2JB CD -Id 18-May-20 29.1 0.64J 0.331 5.61 I 2.0J SDm th 1 of 7 June 2020 Table 3a Detected Groundwater Constituents - Metals May 2020 Semi -Annual Sampling Event Cabarrus County Unit 1 Landfill Facility Permit Number 1302-MSWLF-1974 ,,, 1 1.5 1.00 ,,, MW-5 8-Nov-11 1.981 108 0.19131 0.111 0.54J 4.391 0.38J 37.7J 3.431 10.1 MW-5 9-May-12 0.191 29.2J 0.14J 3.2281 0.78J 5.9581 0.811 6.221 0.92J 2.40J 9.6481 MW-5 28-Nov-12 0.291 4.571 173 0.081 21.8 2.851 0.131 46.21 3.451 6.661 MW-5 10-May-13 34.1 0.15J 0.07J 1.94J 6.00J 4.611 0.461 16.41 5.151 4.12.1 6.791 MW-5 5-Nov-13 1.021 160 0.081 16.6 2.881 0.401 39.81 2.831 7.591 5.90131 MW-5 6-May-14 2.41J 91.81 0.05J 0.091 11.8 2.841 0.3481 23.11 8.85J 5.261 MW-5 4-Nov-14 5.381 173 19.5 2.611 0.411 52.2 3.881 3.771 3.1613-01) MW-5 5-May-15 2.39J 93.2E-03,J 18.8 2.591 0.411 29.11 3.911 3.838-01,1 MW-5 27-Oct-15 5.491 163 0.101 16.3 1.971 0.331 47.91 2.721 3.01CN,J 2.181 3.221 1302-MSWLF-1974 MW-5(dup) 27-Oct-15 5.60J 174 0.16J 16.5 2.321 0.641 48.41 3.381 3.53CN,J 3.35.1 5.081 MW-5 17-May-16 1.401 158 0.741 18.7 1.171 0.181 36.31 1.001 2.421 MW-5 1-Nov-16 1.75J 166 1.091 19.3 0.631 0.201 47.11 3.281 MW-5 9-May-17 0.951 91.01 0.151 0.081 1.591 2.221 0.771 26.51 1.561 3.671 3.831 MW-5 31-Oct-17 1.981 165 1.14J 19.4 1.101 0.331 43.51 5.181 MW-5 6-Jun-18 2.41 198 0.069J 26.9 0.28J 46.6J 4.31 MW-5 20-Dec-18 102 14.5 2.21 0.321 24.31 5.91 MW-5 8-May-19 0.62J 144 0.13J 0.901 19.3 4.81 0.29J 41.3 9.5113 MW-5 5-Nov-19 0.70J 1.11 164 0.95J 18.1 1.216 0.251 46.3 7.618 MW-5 19-May-20 1.3JB 161 0.86J 17.5 0.84J 0.24J 43.5 4.7J MW-7 8-Nov-11 0.1661 0.07131 62.1 1.701 13.OJ 0.081 6.971 MW-7 9-May-12 0.23J 9.14J 0.10J 0.30J 0.74131 29.5 3.15131 1.11J 85.5 5.361 17.76 MW-7 28-Nov-12 0.51 9.85J 437 45.9 1.271 30.4J 5.011 MW-7 10-May-13 6.73J 300 0.081 49.1 1.96J 0.461 11.01 0.791 0.091 6.361 MW-7 5-Nov-13 448 0.12J 0.41J 45.4 2.571 1.331 33.2J 2.71J 13.5J 6.7961 MW-7 6-May-14 9.34J 460 0.20J 0.79J 2.2361 47.6 4.391 4.55B1 44.41 5.941 16 17.3 MW-7 4-Nov-14 5.74J 391 0.13J 46.0 1.541 0.411 31.9J 1.69J 1.988-01,J MW-7 5-May-15 5.77J 398B-01,1 0.31J 49.4 2.351 1.211 31.2J 3.52J 3.238-01,1 MW-7 27-Oct-15 323 48.2 0.671 0.091 11.91 1.25CN,J 0.071 3.541 MW-7 17-May-16 0.26J 3.90J 646 0.33J 1.38 6.26J 45.2 5.791 7.011 76.8 3.46J 0.131 23.2 12.4 1302-MSWLF-1974 MW-7(dup) 17-May-16 0.26J 4.08J 604 0.32J 1.37 5.64J 47.6 5.731 6.131 63.1 3.031 0.131 21.3 13.1 MW-7 1-Nov-16 2.331 390 0.14J 51.9 0.271 27.41 2.241 3.081 MW-7 9-May-17 2.86J 0.361 48.8 0.301 0.381 18.41 2.32J 0.091 MW-7 31-Oct-17 3.17J 383 0.70J 42.3 0.431 0.451 25.OJ 0.071 2.04J MW-7 6-Jun-18 4.01 551 42.1 0.761 45.7J 5.8J MW-7 20-Dec-18 3.11 451 43.5 37.81 11.5 MW-7 8-May-19 1.61 606 0.61J 35.1 0.351 0.121 77.6 1.11 4.618 MW-7(dup) 8-May-19 1.21 603 0.85J 34.0 0.751 0.271 77.1 1.71 1.81 7.2113 MW-7 4-Nov-19 0.32J 5.0 320 0.44J 40.2 0.2416 0.0651 9.9 0.066J 6.81E MW-7(dup) 4-Nov-19 4.1J 304 38.3 0.0671 9.4 0.0601 6.8113 MW-7 19-May-20 1 1.61 1 646 1 1 1 1.01 1 35.0 1 0.781 1 0.321 1 82.6 1 2.91 1 0.0861 4.41 SDMth 2 of 7 June 2020 Table 3a Detected Groundwater Constituents - Metals May 2020 Semi -Annual Sampling Event Cabarrus County Unit 1 Landfill Facility Permit Number 1302-MSWLF-1974 ,,, 15 100 ,,, MW-8A 8-Nov-11 0.42131 112 0.07131 0.951 16.3 24.1 0.46J 52.5 1.591 178 MW-8A 9-May-12 0.30J 59.4J 1.12J 13.2 5.781 0.471 34.6J 93.68 MW-8A 28-Nov-12 80.11 0.38J 5.451 5.171 0.351 10.71 1.821 5.801 28.6 MW-8A 7-May-13 0.30J 1.0881 48.7J 0.20J 7.54J 6.181 0.291 9.81J 5.161 31.4 MW-8A 5-Nov-13 0.341 64.61 0.20J 5.641 6.721 0.391 10.61 2.211 14.7J 24.113 MW-8A 6-May-14 41.7J 0.07J 7.881 3.841 0.0881 6.00J 1.87J 4.271 13.1 MW-8A 4-Nov-14 64.61 0.171 5.761 8.181 0.271 11.41 5.661 4.62J 17.213-01 MW-8A 5-May-15 31.4B-03,J 5.88J 3.51.1 5.91J 2.861 7.41E-01,1 MW-8A 27-Oct-15 54.41 0.181 11.2 10.4 0.121 17.51 2.17J 2.80CN,J 47.8 MW-8A 17-May-16 35.8J 0.12J 8.08J 4.03J 9.051 27.2 1302-M5WLF-1974 MW-8A 1-Nov-16 61.81 0.14J 18.7 4.401 0.181 27.91 119 MW-8A(dup) 1-Nov-16 64.4J 0.16J 20.1 4.34.1 0.15.1 28.5J 125 MW-8A 9-May-17 3.841 1.161 61.01 0.661 12.9 58.5 80.7 6.401 247 MW-8A 31-Oct-17 1.991 2.77J 88.7J 0.87J 0.67J 13.0 29.3 13.5 30.5J 0.061 3.65J 241 MW-8A 6-Jun-18 2.71 0.94J 65.5J 0.0591 0.591 11.1 29.0 3.01 84.5 4.4J 490 MW-8A(dup) 6-Jun-18 2.81 1.01 69.7J 0.075J 0.86J 10.9 30.5 3.41 86.6 5.4J 530 MW-8A 21-Dec-18 2.61 2.71 104 1.1 8.01 25.9 7.5J 45.OJ 4.4J 246 MW-8A 8-May-19 3.51 2.31 77.9 0.67 6.1 11.8 2.2 33.2 3.6J 88.1 MW-8A 5-Nov-19 1.51 173 0.11J 13.3 28.113 1.9 189 0.086J 4.OJ 671 MW-8A 19-May-20 4.11 0.62J 91.1 0.24J 0.931 8.3 22.1 2.5 94.7 0.161 2.OJ 260 MW-8A(dup) 19-May-20 4.01 0.57J 91.8 0.23J 0.791 8.7 21.0 2.9 96.5 0.069J 2.5J 277 MW-10 8-Nov-11 0.25BJ 14.7 219 0.4761 25.1 4.09J 123 6.66J 0.111 5.221 MW-10 9-May-12 0.231 24.5 194 0.40J 0.781 36.8 3.59J 0.131 168 9.441 2.251 6.20BJ MW-10 28-Nov-12 0.33J 16.8 193 0.41J 0.721 25.9 3.261 0.25J 129 8.60J 0.241 2.331 MW-10 10-May-13 0.251 16.7 174 0.511 1.981 32.6 4.10J 0.37J 153 7.771 0.07J 5.10J MW-10 5-Nov-13 0.37J 10.6 195 0.49J 22.8 3.641 0.301 111 6.99J 0.151 13.91 5.2881 MW-10 6-May-14 15.4 165 0.41J 33.8 3.09J 0.21131 146 8.011 6.05J 2.42.1 MW-10 4-Nov-14 16.2 166 0.51 1.31B-03,J 25.5 3.591 1.27J 122 7.15J 5.421 5.77E-01,J MW-10 5-May-15 17.1 157B-01 0.48J 29.2 2.64.1 0.421 140 10.4 2.241 2.768-01,J MW-10 27-Oct-15 0.25J 12.8 167 0.52J 25.2 2.521 0.26J 122 6.911 2.56CN,J 0.10J 2.96J 2.471 1302-MSWLF-1974 MW-10 17-May-16 16.7 166 0.39J 1.67J 31.6 0.72J 0.211 147 1.061 2.88.1 MW-10 1-Nov-16 14.6 157 0.49J 1.98 32.2 0.711 0.27J 146 3.711 MW-10 9-May-17 7.93J 138 0.29J 1.811 20.9 1.28.1 0.35J 92.0 1.63J 0.061 2.87.1 2.74.1 MW-10 31-Oct-17 162 0.54J 2.82J 27.1 0.561 133 0. 101 MW-10 6-Jun-18 170 0.35J 3.61 26.1 0.67J 120 8.21 MW-30 20-Dec-18 23.5J 3.7J 8.OJ 3.1.1 MW-10(dup) 20-Dec-18 22.1J 3.41 7.61 2.51 MW-30 8-May-19 14.1 116 0.22J 1.31 20.9 3.6J 0.101 1.61 4.016 MW-10 5-Nov-19 12.0 172 0.38J 1.61 22.6 0.47J 0.21.1 95.3 0.0681 4.5J 8.41 MW-10 19-May-20 131 0.36J 1.31 1 27.0 1 0.49.1 1 0.15.1 0.054J 2.41 D th 3 of 7 June 2020 Table 3a Detected Groundwater Constituents - Metals May 2020 Semi -Annual Sampling Event Cabarrus County Unit 1 Landfill Facility Permit Number 1302-MSWLF-1974 ,,, 1 15 1.00 ,,, MW-11 8-Nov-11 0.29131 509 0.06131 0.12J 24.2 27.2 0.201 37.91 7.701 10.6 MW-11 9-May-12 79.5J 18.2 3.791 0.421 10.6J 1.10J 50.1E MW-11 28-Nov-12 494 0.151 35.8 6.621 0.301 38.11 9.361 9.481 MW-11 10-May-13 52.9J 2.56J 0.431 1.711 2.56J 1.101 55.7 MW-11 5-Nov-13 1.321 503 0.061 34.5 11.9 0.471 38.71 8.261 0.31J 5.79BJ 11.713 MW-11 6-May-14 1.75J 144 0.07J 6.721 3.921 0.178J 13.0J 5.16J 5.12.1 23.1 MW-11 4-Nov-14 4.001 449 35.1 11.3 0.371 39.81 3.541 4.09.1 2.38B-01,J MW-11 5-May-15 2186-01 13.0 11.9 0.541 20.6J 9.531 39.5E-01 MW-11 27-Oct-15 2.121 503 37.0 16.4 0.621 44.81 3.771 2.89CN,J 2.411 4.681 1302-MSWLF-1974 MW-11 17-May-16 163 10.9 2.121 11.7J 5.561 19.4 MW-11 1-Nov-16 455 0.111 41.7 15.2 0.561 40AJ 5.711 MW-11 9-May-17 151 7.92J 3.191 0.091 10.81 2.79.1 18.9 MW-11 9-May-17 150 0.081 7.851 3.201 0.101 10.71 2.90.1 19.5 MW-11 31-Oct-17 515 0.18J 35.7 8.441 0.291 37.8J MW-11 (dup) 31-Oct-17 0.87J 498 0.16J 1.181 34.7 7.601 0.321 37.01 3.301 MW-11 6-Jun-18 1.3.1 438 27.1 6.5.1 32.9J 15.0 MW-11 20-Dec-18 SOS 3.51 1.6J 4.31 26.1 MW-11 9-May-19 191 0.084J 12.5 1.6.1 0.191 12.8 8.11E MW-11 5-Nov-19 530 34.4 3.9J 0.411 36.0 1.11 8.31 MW-11 19-May-20 189 0.471 1 18.0 1 2.2J 1 0.281 11.3 12.5 Notes: 1. All units are in micrograms per liter (parts per billion). 2. * - Interim Maximum Allowable Concentration (IMAC) 3. dup - Duplicate Sample 4. J - Indicates the analytical result is an established concentration between the method detection limit and the adjusted reporting limit. 5. B, B-01-The analyte concentration detected in the method blank was greaterthan the method detection limit. 6. CN - Detected silver concentrations were determined to be the result of contamination from the preservative acid. - Concentration exceeds the 15A NCAC 02L .0202 (North Carolina 2L) or IMAC Standard - Indicates the result is below the detection limit. SDMth 4 of 7 June 2020 Table 3b Detected Groundwater Constituents - Volatile Organic Compounds May 2020 Semi -Annual Sampling Event Cabarrus County Unit 1 Landfill Facility Permit Number 1302-MSWLF-1974 ard ,,, CD-15 8-Nov-11 CD-ls 27-Nov-12 0.4J 0.21 CD -Is 7-May-13 CD-ls 5-Nov-13 CD -Is 6-May-14 CD-ls 4-Nov-14 CD-ls 5-May-15 CD-ls 27-0ct-15 1302-MSWLF-1974 CD-ls 17-May-16 CD-ls 1-Nov-16 CD-ls 9-May-17 CD-ls 31-Oct-17 CD-ls 11-Jun-18 CD-ls 17-Dec-18 1.2 CD-ls 7-May-19 CD-ls 6-Nov-19 CD-ls 18-May-20 CD -Id 11/8/2011 CD-ld 27-Nov-12 CD-ld 7-May-13 CD-ld 5-Nov-13 CD-ld 6-May-14 CD-ld 4-Nov-14 CD-ld 5-May-15 1302-MSWLF-1974 CD-ld 27-0ct-15 CD -Id 17-May-16 CD-ld 1-Nov-16 CD-ld 31-Oct-17 CD-ld 12-Jun-18 CD-ld 17-Dec-18 CD-ld 7-May-19 CD -Id 5-Nov-19 CD -Id 18-May-20 MW-5 7-Nov-11 0.8J 7.6 6.2 MW-5 8-May-12 0.31 MW-5 27-Nov-12 18 0.6BJ 14 0.31 0.21 0.3J MW-5 9-May-13 1.7J 4.2 3.4 MW-5 4-Nov-13 1.5 18 0.6J 13 0.61 MW-5 5-May-14 1.01 11 0.3J 7.4 MW-5 3-Nov-14 1.6 23 0.7J 16 0.21 MW-5 4-May-15 0.91 16 0.5J 30 MW-5 26-Oct-15 1.1 21 0.6J 14 1302-MSWLF-1974 MW-5)dup) 26-Oct-15 1.0 20 0.6J 13 MW-5 16-May-16 1.2 19 0.51 12 MW-5 31-Oct-16 1.4 26 0.7J 15 2.6J MW-5 8-May-17 0.81 16 9.1 MW-5 30-Oct-17 1.2 23 0.5J 14 MW-5 6-Jun-18 1.1 21.6 0.60J 12.3 1.5 MW-5 20-Dec-18 0.521 12.4 5.9 87.7 MW-5 7-May-19 1.2 18.2 9.9 142 MW-5 4-Nov-19 1.5 29.2 0.6J 14.1 142 5.IJ MW-5 19-May-20 0.62J 126 3.2J MW-7 7-Nov-11 2.3 24 0.81 13 0.81 0.51 0.61 1.11 MW-7 8-May-12 0.91 11 0.81 8.5 0.6J 1.01 0.4J MW-7 27-Nov-12 2.3 29 0.8BJ 14 0.71 0.3J 0.41 0.5J MW-7 9-May-13 1.81 2.2 24 0.81 15 0.7J 0.3J 0.4J 6.3 MW-7 5-Nov-13 2.4 17 0.8J 11 0.61 0.51 0.41 MW-7 5-May-14 1.7 16 0.6J 13 0.71 0.41 0.31 MW-7 3-Nov-14 1.6 29 0.91 0.51 0.21 MW-7 4-May-15 1.6 33 0.81 0.31 MW-7 26-Oct-15 2.9 38 0.91 16 0.3J MW-7 16-May-16 1.0 19 0.7J 12 0.61 1302-MSWLF-1974 MW-7)dup) 16-May-16 0.81 17 0.81 11 0.61 0.61 MW-7 31-0ct-16 1.4 31 0.91 14 0.41 2.5J MW-7 8-May-17 2.5 32 0.801 14.0 MW-7 30-Oct-17 1.5 29 0.901 13.0 MW-7 6-Jun-18 2.9 32.2 0.96J 12.7 0.97J MW-7 20-Dec-18 1.5 16.7 4.8 76.6 MW-7 7-May-19 1.0 20.9 0.74J 9.80 1.7 0.541 130 9.7J MW-7)dup) 7-May-19 1.2 21.1 0.83J 10.3 1.4 0.541 131 9.41 MW-7 4-Nov-19 2 45.8 0.96J 14.8 66.5 13.9 0.86J MW-7)dup) 4-Nov-19 2.7 0.53J 0.851 16.5 61.5 12.1 0.41 MW-7 19-May-20 0.861 0.621 0.SL 105 TOM 5 of 7 June 2020 Table 3b Detected Groundwater Constituents - Volatile Organic Compounds May 2020 Semi -Annual Sampling Event Cabarrus County Unit 1 Landfill Facility Permit Number 1302-MSWLF-1974 North Carolina 2L INIACitandard 000 1 4,000 50 3 20 6 70 IF 6 3 40 5 NS 600 0.03 r 500 or VW-8A 7-Nov-11 MW-8A 8-May-12 MW-8A 27-Nov-12 MW-8A 6-May-13 MW-8A 4-Nov-13 MW-8A 5-May-14 MW-8A 3-Nov-14 MW-8A 4-May-15 3.8J MW-8A 26-0ct-15 MW-8A 16-May-16 1302-MSWLF-1974 MW-8A 31-Oct-16 MW-8A(dup) 31-0ct-16 MW-8A 8-May-17 MW-8A 30-Oct-17 MW-8A 6-Jun-18 0.731 MW-SA(dup) 6-Jun-18 MW-8A 20-Dec-18 MW-8A 7-May-19 2.4 MW-8A 4-Nov-19 MW-8A 19-May-20 MW-8A(dup) 19-May-20 MW-10 7-Nov-11 8.2J 1.3 31 0.81 8.4 MW-10 8-May-12 1.3 32 1.01 8.9 0.2J MW-10 27-Nov-12 1.3 35 1.1BJ 9.5 0.3J MW-10 9-May-13 5.01 1.1 6.01 31 0.91 8.2 MW-10 4-Nov-13 73J 1.2 4.2J 39 1.11 30 0.91 MW-10 5-May-14 1.1 7.91 39 1.21 30 0.51 MW-10 3-Nov-14 23J 1.3 42 1.3J 31 0.4J MW-10 4-May-15 8.51 1.1 40 1.2J 31 0.4J MW-10 26-Oct-IS 1.2 41 1.11 9.8 0.3J 1302-MSWLF-1974 MW-10 16-May-16 1.0 39 1.01 9.6 MW-10 31-Oct-16 1.2 44.0 1.3J 30 0.4J MW-10 8-May-17 1.01 41.0 1.2J 9.2 0.31 MW-10 30-Oct-17 1.0 1.01 9.0 MW-30 6-Jun-18 1.2 41.7 1.11 8.7 10.2J MW-10 20-Dec-18 1AJ MW-10 dup 20-Dec-18 MW-10 8-May-19 1.1 43.8 1.1 8.6 104 24.6 MW-10 4-Nov-19 1.4 1.4 10.2 85.6 31.5 33.6 MW-10 19-May-20 0.931 0.94J 82.8 MW-11 7-Nov-11 1.3 13 7.6 0.51 OAJ 0.51 MW-11 8-May-12 MW-11 27-Nov-12 1.3 18 0.713J 8.4 0.4J 0.3J 0.4J MW-11 9-May-13 1.01 MW-11 4-Nov-13 1.1 16 0.5J 7.6 0.4J MW-11 5-May-14 0.41 4.5 1.7 MW-11 3-Nov-14 1.4 19 0.7J 9.4 0.51 MW-11 4-May-15 0.4J 6.0 1.8 MW-11 26-Oct-15 0.91 16 0.6J 9.0 0AJ 1302-MSWLF-1974 MW-11 16-May-16 0.3J 4.6 1.6 MW-11 31-Oct-16 1.2 18 0.7J 8.8 2.5J MW-11 8-May-17 3.8 MW-11(dup) 8-May-17 2.9J MW-11 30-Oct-17 18 0.7J 8.6 MW-11(dup) 30-Oct-17 16 0.7J 8.0 MW-11 6-Jun-18 13.5J 0.901 14.0 5.5 MW-11 20-Dec-18 2.1 MW-11 8-May-19 0.57J 6.8 2.1 26.2 3AJ MW-11 4-Nov-19 18.6 0.75J 0.671 46.2 10.8 MW-11 19-May-20 12.1 Notes: 1. All units are in micrograms per liter (parts per billion). 2. • - Interim Maximum Allowable Concentration (IMAC) 3. dup - Duplicate Sample 4. J - Indicates the analytical result is an established concentration between the method detection limit and the adjusted reporting limit. S. B - The analyte concentration detected in the method blank was greater than the method detection limit. - Concentration exceeds the 15A NCAC 02L.0202 (North Carolina 2L) or IMAC Standard - Indicates the result is below the detection limit. CDM 6 of 7 June 2020 Table 3c Detected Surface Water Constituents - Metals and Volatile Organic Compounds May 2020 Semi -Annual Sampling Event Cabarrus County Unit 1 Landfill Facility Permit Number 1302-MSWLF-1974 North Carolina 2B or In Stream SW-1 9-Nov-11 94M 0. 17J 2.601 0.231 5.32) 1.741 SW-1 9-May-12 DRY DRY SW -I 28-Nov-12 DRY DRY SW-1 10-May-13 82.11 0.061 3.791 2.011 0.161 6.301 2.051 4.931 SW-1 5-Nov-13 1.061 139 9.52J 1.751 0.091 8.511 2.851 0.121 2.OJ 0.31 SW-1 5-May-14 1.801 146 0.371 4.63B1 11.7 6.341 BMW 9.791 2.831 14.41 SW-1 3-Nov-14 DR V DRY SW-1 5-May-15 DRY DRY 1302-MSWLF-1974 I61 I I 1.2.371 I 2.93CN,1 2I I65.2 W- 19-M 'ay-" 3525737.2 15 7.21 5.331 . 161S1 SW-1 1-Nov-16 DRY DRY SW-1 10-May-17 I I 66.61 I I 3.691 2.041 1.04) I 0.071 5.92J SW-1 31-Oct-17 DRY DRY SW-1 71 a_18 DRY SW-1 18-Dec-8 ,11 4.434.91 44 2.1 SW-1 9-May-19 669 0.763.01 1,31 0161 53.918 . 1.31 8.7 SW-1 6-Nov-19 .DRY 00.3418 S.O.S.06412.008 .99SW-1 19-May-20 711038J 64 0.1.91 151 0.21J 4.91 3.11 9 SW-2 9-Nov-11 DRY DRY SW-2 9-May-12 I 65.31 I I 1.06) I 0.881 I 1.681 0.851 I 3.331 I 1.331 SW-2 28-Nov-12 DRY DRY SW-2 10-May-13 0.971 78.91 I 1 I 0.63) I 2.531 I 2.201 I 0.841 6.361 I 3.02I I 6.051 SW-2 5-Nov-13 DRY DRY SW-2 6-May-14 1.451 137 0.051 .291 3.6W I.S2BJ 6.991 3.681 7.11J 24.5 SW-2 3-Nov-14 1.881 67.01 12.7 0.571 0.051 1.421 1.081 5.158-01,1 6.01 1.8 SW-2 5-May-15 73.2B-01,1 3.16J 1.211 6.341 3.40J 1.361 1302-MSWLF-1974 SW-2 29-0ct-15 1.681 81.1) 0.101 0.691 3.64J 0.951 4.601 1.501 3.28CN,J 1.931 5.481 SW-2 19-May-16 2.351 89.0) 0.941 12.2 7.211 11.9 8.731 8.331 3.401 32.7 SW-2 1-Nov-16 DRY DRY SW-2 10-May-17 I I 94.71 I I I I 2.221 I 0.89) I 0.31J 4.811 SW-2 31-Oct-17 DRY DRY SW-2 71un-18 0.991 42.91 1.41 0.371 2.51 SW-2 18-Dec-18 0.631 71.81 0.111 1.91 1.81 1.91 0.9. 3.11 4.31 3.61 2.5 1.8 SW-2 10-May-19 83.1 2.3J 1.71 1.1 2.81B 7.3 SW-2 6-Nov- 19 0.62) 83.9 0.661 0.351 3.3JB 0.22JB 2.71 1.31 7.11E 3.8 SW-2 19-May-20 0.691 100 0.23) 3.51 3.2J 4.11 2.2 5.4 1.]1 11 61 10.2 6.7 Notes. 1. All units are in micrograms per Iiler (parts per billion). 2. Standards obtained from section 15A NCAC 02B .0211(North Carolina 28) or In -Stream Target Value Surface Water Standards for Class C Waters (June 2019). 3.13) - A Standard for total chromium has not been established. The value provided is for chromium (III). 4. NS - No Standard 5.' -North Carolina In -Stream Target Value 6.1-Indicates the analytical result is an estimated concentration between the method detection limit and the limit of quantitation. 7.8-The analyteconcentration detected in the method blank was greater than the method detection limit. 8. CN - Detected silver concentrations were determined to be the result of contamination from the preservative acid. Concentration exceeds the North Carolina 2B or In -Stream Target Value Freshwater Aquatic Life Standard for Class C Waters -June 2019 Indicates the result is below the detection limit. SDMth 7 of 7 June 2020 Table 4 Constituents Detected Above Standards May 2020 Semi -Annual Sampling Event Unit 1- Cabarrus County Landfill Facility Permit Number 1302-MSWLF-1974 Monitoring Well Parameters Exceeding North Carolina 2L or IMAC Standard Facility Permit Number Code Assessment Monitoring - May 2020 CD-1s 1302-MSWLF-1974 Vanadium* (background well) CD-1d 1302-MSWLF-1974 Vanadium* (background well) 1302-MSWLF-1974 MW-5 Cobalt*, Vanadium*, 1,4-Dioxane 1302-MSWLF-1974 MW-7 Cobalt*, 1,4-Dioxane 1302-MSWLF-1974 MW-8A Antimony*, Cobalt*, Vanadium* 1302-MSWLF-1974 MW-10 Arsenic, Cobalt*, Nickel, Vanadium*, 1,4-Dioxane 1302-MSWLF-1974 MW-11 Cobalt*, 1,4-Dioxane Notes. 1. * - Constituent exceeded the Interim Maximum Allowable Concentration (IMAC) 2. Bold - "J" Flag - Indicates the analytical result is an estimated concentration between the method detection limit and the method reporting limit. Smith Page 1 of 1 dune 2020 N WE r .. S MGW-15 MGW-1 n 733.6 46 i � MGW-14 " SW-3 r CD-ld 0. v 1 733.22 4 0 1 ft d&D CD-4 Rep 744.48 Epp y8 CD-\ Lartdfif 72210 A . �r 'o CD-7 x ----_� 714.97 MGW -13 CD-9 _ _ - 120 706.59� ---- MGW 17 Unit 2 o MW-1 689.50 Unit1 _ MGW.12 MW-g` MGW-2 / - 710 _ 00.9 1 MW-8A 69262 709.08 MW-7 700® sMGW-11 I / 695.34 P MGW-16 MW-A /MW-G MW-5 \ 707.17 t / 685.98 681.25 MW-11 690 MW-X Unit 3/' i -' _ 678.41 699.85 MW-e 679.35 \600: Borrow Area MGW-3� _ - / IMW-E Repl / 1 687.49 l SW-1 690� MW-D MW-E deep, t MW-F Mw-C \ 697.33 676.69 / 672.76 �. 687.16 / - - - -670 MGW-8 MGW-9 MW-K l 682.86 / MW-1 MGW-4 AMW-1d / 666.42 - - - 660 680�677.82 ' AMW-1s MW-H SW-2 MGW-7 676.86 675.40 MW-H deep AMW-2s MW-3 yy0 676.56 674.80 657.93/ 670 AMW-2d 0� / MW-M 678.00 6y 659.18 yy0 649.83 MW-3 deep MGW-6 MW-L deep 659.88 660.93 MGW-5 Scale in Feet 0 Soo 1000 Map Data Source; 2015 Aerial Photograph, Cabarrus County, North Carolina OneMap. MGW--10 7 • AXH:11Iww, Groundwater Monitoring Well Surface Water Sample Location ♦ Landfill Gas Well Location Potentiometric Contour 680 - (dashed where inferred( Contour Interval = 10 Feet Appendix A leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 June 08, 2020 Mathew Colone CDM Smith Inc. - Raleigh 5400 Glenwood Avenue Suite 400 Raleigh, NC 27612 RE: Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Dear Mathew Colone: Enclosed are the analytical results for sample(s) received by the laboratory on May 20, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Charlotte • Pace Analytical Services - Atlanta, GA If you have any questions concerning this report, please feel free to contact me. Sincerely, "& ��aA Maiya Parks maiya.parks@pacelabs.com (770)734-4200 Project Manager Enclosures cc: Janelle Farley, CDM Smith REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Pace Analytical Services Atlanta 110 Technology Parkway Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 Georgia DW Microbiology Certification #: 812 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 CERTIFICATIONS North Carolina Certification #: 381 South Carolina Certification #: 98011001 Virginia Certification #: 460204 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE SUMMARY Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Lab ID Sample ID Matrix Date Collected Date Received 92478353001 1302-MW-5 Water 05/19/2012:00 05/20/20 12:55 92478353002 1302-MW-7 Water 05/19/2010:10 05/20/20 12:55 92478353003 1302-MW-8A Water 05/19/20 09:15 05/20/20 12:55 92478353004 1302-MW-10 Water 05/19/2011:20 05/20/20 12:55 92478353005 1302-MW-11 Water 05/19/2010:40 05/20/20 12:55 92478353006 1302-Dup1 Water 05/19/20 09:15 05/20/20 12:55 92478353007 1302-SW-1 Water 05/19/2015:20 05/20/20 12:55 92478353008 1302-SW-2 Water 05/19/20 09:30 05/20/20 12:55 92478353009 Trip Blank Water 05/19/20 00:00 05/20/20 12:55 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: Pace Project No.: Cabarrus Co Unit 1 MSW 92478353 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92478353001 1302-MW-5 EPA 6020E CSW 15 PASI-GA EPA 8260D SAS 51 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92478353002 1302-MW-7 EPA 6020E CSW 15 PASI-GA EPA 8260D SAS 51 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92478353003 1302-MW-8A EPA 6020E CSW 15 PASI-GA EPA 8260D SAS 51 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92478353004 1302-MW-10 EPA 6020E CSW 15 PASI-GA EPA 8260D SAS 51 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92478353005 1302-MW-11 EPA 6020E CSW 15 PASI-GA EPA 8260D SAS 51 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92478353006 1302-Dup1 EPA 6020E CSW 15 PASI-GA EPA 8260D SAS 51 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92478353007 1302-SW-1 EPA 6020E CSW 15 PASI-GA EPA 8260D SAS 51 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92478353008 1302-SW-2 EPA 6020E CSW 15 PASI-GA EPA 8260D SAS 51 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92478353009 Trip Blank EPA 8260D SAS 51 PASI-C EPA 8260D Mod. LMB 3 PASI-C PASI-C = Pace Analytical Services - Charlotte PASI-GA = Pace Analytical Services - Atlanta, GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Lab Sample ID Method 92478353001 EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 8260D EPA 8260D EPA 8260D Mod. 92478353002 EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 8260D EPA 8260D EPA 8260D EPA 8260D Mod. 92478353003 SUMMARY OF DETECTION Client Sample ID Parameters Result Units Report Limit Analyzed 1302-MW-5 Field pH 6.4 Std. Units 05/19/20 12:00 Field Temperature 15.1 deg C 05/19/20 12:00 Field Specific Conductance 1,785 umhos/cm 05/19/20 12:00 Field Turbidity 8.4 NTU 05/19/20 12:00 Field Oxidation Potential 13.6 mV 05/19/20 12:00 Oxygen, Dissolved 2.9 mg/L 05/19/20 12:00 Depth to Water 32.60 feet 05/19/20 12:00 Arsenic 1.3J ug/L 5.0 06/02/20 20:56 Barium 161 ug/L 5.0 06/02/20 20:56 Chromium 0.86J ug/L 5.0 06/02/20 20:56 Cobalt 17.5 ug/L 5.0 06/02/20 20:56 Copper 0.84J ug/L 5.0 06/02/20 20:56 Lead 0.24J ug/L 1.0 06/02/20 20:56 Nickel 43.5 ug/L 5.0 06/02/20 20:56 Vanadium 1.1 J ug/L 10.0 06/02/20 20:56 Zinc 4.7J ug/L 10.0 06/02/20 20:56 Benzene 0.62J ug/L 1.0 06/01/20 23:32 Tetrahydrofuran 3.2J ug/L 10.0 06/01/20 23:32 1,4-Dioxane (p-Dioxane) 126 ug/L 5.0 05/29/20 18:34 1302-MW-7 Field pH 6.5 Std. Units 05/19/20 10:10 Field Temperature 16.7 deg C 05/19/20 10:10 Field Specific Conductance 2,636 umhos/cm 05/19/20 10:10 Field Turbidity 23.8 NTU 05/19/20 10:10 Field Oxidation Potential 14.1 mV 05/19/20 10:10 Oxygen, Dissolved 1.9 mg/L 05/19/20 10:10 Depth to Water 21.95 feet 05/19/20 10:10 Arsenic 1.6J ug/L 5.0 06/02/2017:12 Barium 646 ug/L 5.0 06/02/2017:12 Chromium 1.0J ug/L 5.0 06/02/2017:12 Cobalt 35.0 ug/L 5.0 06/02/2017:12 Copper 0.78J ug/L 5.0 06/02/2017:12 Lead 0.32J ug/L 1.0 06/02/2017:12 Nickel 82.6 ug/L 5.0 06/02/2017:12 Selenium 2.9J ug/L 5.0 06/02/2017:12 Thallium 0.086J ug/L 1.0 06/02/2017:12 Zinc 4AJ ug/L 10.0 06/02/2017:12 Benzene 0.86J ug/L 1.0 06/01/20 23:50 1,2-Dichlorobenzene 0.62J ug/L 1.0 06/01/20 23:50 cis-1,2-Dichloroethene 0.51J ug/L 1.0 06/01/20 23:50 1,4-Dioxane (p-Dioxane) 105 ug/L 4.0 05/29/20 18:53 1302-MW-8A Field pH 6.3 Std. Units 05/19/20 09:15 Field Temperature 16.9 deg C 05/19/20 09:15 Field Specific Conductance 358.8 umhos/cm 05/19/20 09:15 Field Turbidity 6.2 NTU 05/19/20 09:15 REPORT OF LABORATORY ANALYSIS N2 B N2 Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Lab Sample ID Method 92478353003 EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B 92478353004 EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 8260D EPA 8260D EPA 8260D EPA 8260D Mod. 92478353005 SUMMARY OF DETECTION Client Sample ID Parameters Result Units Report Limit Analyzed Qualifiers 1302-MW-8A Field Oxidation Potential 195.0 mV 05/19/20 09:15 Oxygen, Dissolved 5.7 mg/L 05/19/20 09:15 N2 Depth to Water 25.51 feet 05/19/20 09:15 Antimony 4.1J ug/L 5.0 06/02/2017:35 Arsenic 0.62J ug/L 5.0 06/02/2017:35 Barium 91.1 ug/L 5.0 06/02/2017:35 Cadmium 0.24J ug/L 0.50 06/02/2017:35 Chromium 0.93J ug/L 5.0 06/02/2017:35 Cobalt 8.3 ug/L 5.0 06/02/2017:35 Copper 22.1 ug/L 5.0 06/02/2017:35 Lead 2.5 ug/L 1.0 06/02/2017:35 Nickel 94.7 ug/L 5.0 06/02/2017:35 Thallium 0.16J ug/L 1.0 06/02/2017:35 Vanadium 2.OJ ug/L 10.0 06/02/2017:35 Zinc 260 ug/L 10.0 06/02/2017:35 1302-MW-10 Field pH 6.7 Std. Units 05/19/20 11:20 Field Temperature 16.1 deg C 05/19/20 11:20 Field Specific Conductance 1,898 umhos/cm 05/19/20 11:20 Field Turbidity 48.4 NTU 05/19/20 11:20 Field Oxidation Potential 11.3 mV 05/19/20 11:20 Oxygen, Dissolved 3.1 mg/L 05/19/20 11:20 N2 Depth to Water 35.56 feet 05/19/20 11:20 Arsenic 15.4 ug/L 5.0 06/02/2017:40 Barium 131 ug/L 5.0 06/02/2017:40 Beryllium 0.36J ug/L 0.50 06/02/2017:40 Chromium 1.3J ug/L 5.0 06/02/2017:40 Cobalt 27.0 ug/L 5.0 06/02/2017:40 Copper 0.49J ug/L 5.0 06/02/2017:40 Lead 0.151 ug/L 1.0 06/02/2017:40 Nickel 126 ug/L 5.0 06/02/2017:40 Thallium 0.054J ug/L 1.0 06/02/2017:40 Vanadium 2.1 J ug/L 10.0 06/02/20 17:40 Zinc 2AJ ug/L 10.0 06/02/2017:40 Benzene 0.93J ug/L 1.0 06/02/20 00:26 Chlorobenzene 33.6 ug/L 1.0 06/02/20 00:26 1,2-Dichlorobenzene 0.94J ug/L 1.0 06/02/20 00:26 1,4-Dioxane (p-Dioxane) 82.8 ug/L 2.0 05/29/20 19:33 1302-MW-11 Field pH 6.4 Std. Units 05/19/20 10:40 Field Temperature 15.5 deg C 05/19/20 10:40 Field Specific Conductance 759 umhos/cm 05/19/20 10:40 Field Turbidity 8.4 NTU 05/19/20 10:40 Field Oxidation Potential 12.0 mV 05/19/20 10:40 Oxygen, Dissolved 3.2 mg/L 05/19/20 10:40 N2 Depth to Water 25.51 feet 05/19/20 10:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SUMMARY OF DETECTION Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92478353005 1302-MW-11 EPA 6020B Barium 189 ug/L 5.0 06/02/20 17:46 EPA 6020B Chromium 0.47J ug/L 5.0 06/02/20 17:46 EPA 6020B Cobalt 18.0 ug/L 5.0 06/02/20 17:46 EPA 6020B Copper 2.2J ug/L 5.0 06/02/20 17:46 EPA 6020B Lead 0.28J ug/L 1.0 06/02/20 17:46 EPA 6020B Nickel 11.3 ug/L 5.0 06/02/20 17:46 EPA 6020B Zinc 12.5 ug/L 10.0 06/02/20 17:46 EPA8260D Mod. 1,4-Dioxane (p-Dioxane) 12.1 ug/L 2.0 05/29/20 19:52 92478353006 1302-Dup1 EPA 6020B Antimony 4.OJ ug/L 5.0 06/02/20 17:52 EPA 6020B Arsenic 0.57J ug/L 5.0 06/02/20 17:52 EPA 6020B Barium 91.8 ug/L 5.0 06/02/20 17:52 EPA 6020B Cadmium 0.23J ug/L 0.50 06/02/20 17:52 EPA 6020B Chromium 0.79J ug/L 5.0 06/02/20 17:52 EPA 6020B Cobalt 8.7 ug/L 5.0 06/02/20 17:52 EPA 6020B Copper 21.0 ug/L 5.0 06/02/20 17:52 EPA 6020B Lead 2.9 ug/L 1.0 06/02/20 17:52 EPA 6020B Nickel 96.5 ug/L 5.0 06/02/20 17:52 EPA 6020B Thallium 0.069J ug/L 1.0 06/02/20 17:52 EPA 6020B Vanadium 2.5J ug/L 10.0 06/02/20 17:52 EPA 6020B Zinc 277 ug/L 10.0 06/02/20 17:52 92478353007 1302-SW-1 Field pH 7.4 Std. Units 05/19/20 15:20 Field Temperature 16.6 deg C 05/19/20 15:20 Field Specific Conductance 400.3 umhos/cm 05/19/20 15:20 Field Turbidity 13.1 NTU 05/19/20 15:20 Field Oxidation Potential -18.0 mV 05/19/20 15:20 Oxygen, Dissolved 5.9 mg/L 05/19/20 15:20 N2 EPA 6020B Barium 65.4 ug/L 5.0 06/02/20 18:09 EPA 6020B Chromium 0.71J ug/L 5.0 06/02/20 18:09 EPA 6020B Cobalt 1.91 ug/L 5.0 06/02/20 18:09 EPA 6020B Copper 1.51 ug/L 5.0 06/02/20 18:09 EPA 6020B Lead 0.21 J ug/L 1.0 06/02/20 18:09 EPA 6020B Nickel 4.5J ug/L 5.0 06/02/20 18:09 EPA 6020B Zinc 3.1 J ug/L 10.0 06/02/20 18:09 EPA8260D Mod. 1,4-Dioxane (p-Dioxane) 9.9 ug/L 2.0 05/30/20 16:52 92478353008 1302-SW-2 Field pH 7.0 Std. Units 05/19/20 09:30 Field Temperature 17.2 deg C 05/19/20 09:30 Field Specific Conductance 373.9 umhos/cm 05/19/20 09:30 Field Turbidity 108.9 NTU 05/19/20 09:30 Field Oxidation Potential 66.9 mV 05/19/20 09:30 Oxygen, Dissolved 5.1 mg/L 05/19/20 09:30 N2 EPA 6020B Arsenic 0.69J ug/L 5.0 06/02/20 18:15 EPA 6020B Barium 100 ug/L 5.0 06/02/20 18:15 EPA 6020B Beryllium 0.23J ug/L 0.50 06/02/20 18:15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SUMMARY OF DETECTION Project: Pace Project No.: Cabarrus Co Unit 1 MSW 92478353 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92478353008 1302-SW-2 EPA 6020B Chromium 3.5J ug/L 5.0 06/02/20 18:15 EPA 6020B Cobalt 3.2J ug/L 5.0 06/02/20 18:15 EPA 6020B Copper 4.1 J ug/L 5.0 06/02/20 18:15 EPA 6020B Lead 2.2 ug/L 1.0 06/02/20 18:15 EPA 6020B Nickel 5.4 ug/L 5.0 06/02/20 18:15 EPA 6020B Selenium 1.7J ug/L 5.0 06/02/20 18:15 EPA 6020B Vanadium 8.6J ug/L 10.0 06/02/20 18:15 EPA 6020B Zinc 10.2 ug/L 10.0 06/02/20 18:15 EPA8260D Mod. 1,4-Dioxane (p-Dioxane) 6.7 ug/L 2.0 05/30/20 17:12 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Sample: 1302-MW-5 Lab ID: 92478353001 Collected: 05/19/20 12:00 Received: 05/20/20 12:55 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Pace Analytical Services - Atlanta, GA Field pH 6.4 Std. Units 1 05/19/20 12:00 Field Temperature 15.1 deg C 1 05/19/20 12:00 Field Specific 1,785 umhos/c 1 05/19/20 12:00 Conductance m Field Turbidity 8.4 NTU 1 05/19/20 12:00 Field Oxidation Potential 13.6 mV 1 05/19/20 12:00 Oxygen, Dissolved 2.9 mg/L 1 05/19/20 12:00 7782-44-7 N2 Depth to Water 32.60 feet 1 05/19/20 12:00 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Atlanta, GA Antimony ND ug/L 5.0 0.27 1 06/01/20 17:17 06/02/20 20:56 7440-36-0 Arsenic 1.3J ug/L 5.0 0.35 1 06/01/20 17:17 06/02/20 20:56 7440-38-2 B Barium 161 ug/L 5.0 0.49 1 06/01/20 17:17 06/02/20 20:56 7440-39-3 Beryllium ND ug/L 0.50 0.074 1 06/01/20 17:17 06/02/20 20:56 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 06/01/20 17:17 06/02/20 20:56 7440-43-9 Chromium 0.86J ug/L 5.0 0.39 1 06/01/20 17:17 06/02/20 20:56 7440-47-3 Cobalt 17.5 ug/L 5.0 0.30 1 06/01/20 17:17 06/02/20 20:56 7440-48-4 Copper 0.84J ug/L 5.0 0.19 1 06/01/20 17:17 06/02/20 20:56 7440-50-8 Lead 0.24J ug/L 1.0 0.046 1 06/01/20 17:17 06/02/20 20:56 7439-92-1 Nickel 43.5 ug/L 5.0 0.31 1 06/01/20 17:17 06/02/20 20:56 7440-02-0 Selenium ND ug/L 5.0 1.3 1 06/01/20 17:17 06/02/20 20:56 7782-49-2 Silver ND ug/L 5.0 0.28 1 06/01/20 17:17 06/02/20 20:56 7440-22-4 Thallium ND ug/L 1.0 0.052 1 06/01/20 17:17 06/02/20 20:56 7440-28-0 Vanadium 1AJ ug/L 10.0 0.71 1 06/01/20 17:17 06/02/20 20:56 7440-62-2 Zinc 4.7J ug/L 10.0 1.5 1 06/01/20 17:17 06/02/20 20:56 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 06/01/20 23:32 67-64-1 Acrylonitrile ND ug/L 50.0 0.90 1 06/01/20 23:32 107-13-1 Benzene 0.62J ug/L 1.0 0.15 1 06/01/20 23:32 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 06/01/20 23:32 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 06/01/20 23:32 75-27-4 Bromoform ND ug/L 1.0 0.62 1 06/01/20 23:32 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 06/01/20 23:32 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 06/01/20 23:32 78-93-3 Carbon disulfide ND ug/L 10.0 0.40 1 06/01/20 23:32 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 06/01/20 23:32 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 06/01/20 23:32 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 06/01/20 23:32 75-00-3 Chloroform ND ug/L 5.0 2.3 1 06/01/20 23:32 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 06/01/20 23:32 74-87-3 1,2-Dibromo-3- ND ug/L 5.0 0.26 1 06/01/20 23:32 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Sample: 1302-MW-5 Lab ID: 92478353001 Collected: 05/19/20 12:00 Received: 05/20/20 12:55 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 06/08/2020 04:58 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.41 1 06/01/20 23:32 124-48-1 ND ug/L 2.0 0.26 1 06/01/20 23:32 106-93-4 ND ug/L 1.0 0.46 1 06/01/20 23:32 74-95-3 ND ug/L 1.0 0.29 1 06/01/20 23:32 95-50-1 ND ug/L 1.0 0.26 1 06/01/20 23:32 106-46-7 ND ug/L 5.0 0.54 1 06/01/20 23:32 110-57-6 ND ug/L 1.0 0.27 1 06/01/20 23:32 75-34-3 ND ug/L 1.0 0.34 1 06/01/20 23:32 107-06-2 ND ug/L 1.0 0.24 1 06/01/20 23:32 75-35-4 ND ug/L 1.0 0.29 1 06/01/20 23:32 156-59-2 ND ug/L 1.0 0.25 1 06/01/20 23:32 156-60-5 ND ug/L 1.0 0.19 1 06/01/20 23:32 78-87-5 ND ug/L 1.0 0.30 1 06/01/20 23:32 10061-01-5 ND ug/L 1.0 0.31 1 06/01/20 23:32 10061-02-6 ND ug/L 1.0 0.26 1 06/01/20 23:32 100-41-4 ND ug/L 5.0 0.57 1 06/01/20 23:32 591-78-6 ND ug/L 20.0 12.5 1 06/01/20 23:32 74-88-4 ND ug/L 5.0 3.7 1 06/01/20 23:32 75-09-2 ND ug/L 5.0 4.5 1 06/01/20 23:32 108-10-1 ND ug/L 1.0 0.27 1 06/01/20 23:32 100-42-5 ND ug/L 1.0 0.34 1 06/01/20 23:32 630-20-6 ND ug/L 1.0 0.22 1 06/01/20 23:32 79-34-5 ND ug/L 1.0 0.16 1 06/01/20 23:32 127-18-4 3.2J ug/L 10.0 1.9 1 06/01/20 23:32 109-99-9 ND ug/L 1.0 0.24 1 06/01/20 23:32 108-88-3 ND ug/L 1.0 0.18 1 06/01/20 23:32 71-55-6 ND ug/L 1.0 0.24 1 06/01/20 23:32 79-00-5 ND ug/L 1.0 0.22 1 06/01/20 23:32 79-01-6 ND ug/L 1.0 0.31 1 06/01/20 23:32 75-69-4 ND ug/L 1.0 0.35 1 06/01/20 23:32 96-18-4 ND ug/L 2.0 1.4 1 06/01/20 23:32 108-05-4 ND ug/L 1.0 0.24 1 06/01/20 23:32 75-01-4 ND ug/L 2.0 0.63 1 06/01/20 23:32 1330-20-7 98 % 70-130 1 06/01/20 23:32 460-00-4 103 % 70-130 1 06/01/20 23:32 17060-07-0 102 % 70-130 1 06/01/20 23:32 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 126 ug/L 5.0 2.9 2.5 05/29/2018:34 123-91-1 101 % 50-150 2.5 05/29/2018:34 17060-07-0 100 % 50-150 2.5 05/29/2018:34 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 10 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Sample: 1302-MW-7 Lab ID: 92478353002 Collected: 05/19/20 10:10 Received: 05/20/20 12:55 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Pace Analytical Services - Atlanta, GA Field pH 6.5 Std. Units 1 05/19/20 10:10 Field Temperature 16.7 deg C 1 05/19/20 10:10 Field Specific 2,636 umhos/c 1 05/19/20 10:10 Conductance m Field Turbidity 23.8 NTU 1 05/19/20 10:10 Field Oxidation Potential 14.1 mV 1 05/19/20 10:10 Oxygen, Dissolved 1.9 mg/L 1 05/19/20 10:10 7782-44-7 N2 Depth to Water 21.95 feet 1 05/19/20 10:10 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Atlanta, GA Antimony ND ug/L 5.0 0.27 1 06/01/2019:48 06/02/2017:12 7440-36-0 Arsenic 1.6J ug/L 5.0 0.35 1 06/01/2019:48 06/02/2017:12 7440-38-2 Barium 646 ug/L 5.0 0.49 1 06/01/2019:48 06/02/2017:12 7440-39-3 Beryllium ND ug/L 0.50 0.074 1 06/01/2019:48 06/02/2017:12 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 06/01/2019:48 06/02/2017:12 7440-43-9 Chromium 1.OJ ug/L 5.0 0.39 1 06/01/2019:48 06/02/2017:12 7440-47-3 Cobalt 35.0 ug/L 5.0 0.30 1 06/01/2019:48 06/02/2017:12 7440-48-4 Copper 0.78J ug/L 5.0 0.19 1 06/01/2019:48 06/02/2017:12 7440-50-8 Lead 0.32J ug/L 1.0 0.046 1 06/01/2019:48 06/02/2017:12 7439-92-1 Nickel 82.6 ug/L 5.0 0.31 1 06/01/2019:48 06/02/2017:12 7440-02-0 Selenium 2.9J ug/L 5.0 1.3 1 06/01/2019:48 06/02/2017:12 7782-49-2 Silver ND ug/L 5.0 0.28 1 06/01/2019:48 06/02/2017:12 7440-22-4 Thallium 0.086J ug/L 1.0 0.052 1 06/01/2019:48 06/02/2017:12 7440-28-0 Vanadium ND ug/L 10.0 0.71 1 06/01/2019:48 06/02/2017:12 7440-62-2 Zinc 4.4J ug/L 10.0 1.5 1 06/01/2019:48 06/02/2017:12 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 06/01/20 23:50 67-64-1 Acrylonitrile ND ug/L 50.0 0.90 1 06/01/20 23:50 107-13-1 Benzene 0.86J ug/L 1.0 0.15 1 06/01/20 23:50 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 06/01/20 23:50 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 06/01/20 23:50 75-27-4 Bromoform ND ug/L 1.0 0.62 1 06/01/20 23:50 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 06/01/20 23:50 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 06/01/20 23:50 78-93-3 Carbon disulfide ND ug/L 10.0 0.40 1 06/01/20 23:50 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 06/01/20 23:50 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 06/01/20 23:50 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 06/01/20 23:50 75-00-3 Chloroform ND ug/L 5.0 2.3 1 06/01/20 23:50 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 06/01/20 23:50 74-87-3 1,2-Dibromo-3- ND ug/L 5.0 0.26 1 06/01/20 23:50 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Sample: 1302-MW-7 Lab ID: 92478353002 Collected: 05/19/20 10:10 Received: 05/20/20 12:55 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 06/08/2020 04:58 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.41 1 06/01/20 23:50 124-48-1 ND ug/L 2.0 0.26 1 06/01/20 23:50 106-93-4 ND ug/L 1.0 0.46 1 06/01/20 23:50 74-95-3 0.62J ug/L 1.0 0.29 1 06/01/20 23:50 95-50-1 ND ug/L 1.0 0.26 1 06/01/20 23:50 106-46-7 ND ug/L 5.0 0.54 1 06/01/20 23:50 110-57-6 ND ug/L 1.0 0.27 1 06/01/20 23:50 75-34-3 ND ug/L 1.0 0.34 1 06/01/20 23:50 107-06-2 ND ug/L 1.0 0.24 1 06/01/20 23:50 75-35-4 0.51 J ug/L 1.0 0.29 1 06/01/20 23:50 156-59-2 ND ug/L 1.0 0.25 1 06/01/20 23:50 156-60-5 ND ug/L 1.0 0.19 1 06/01/20 23:50 78-87-5 ND ug/L 1.0 0.30 1 06/01/20 23:50 10061-01-5 ND ug/L 1.0 0.31 1 06/01/20 23:50 10061-02-6 ND ug/L 1.0 0.26 1 06/01/20 23:50 100-41-4 ND ug/L 5.0 0.57 1 06/01/20 23:50 591-78-6 ND ug/L 20.0 12.5 1 06/01/20 23:50 74-88-4 ND ug/L 5.0 3.7 1 06/01/20 23:50 75-09-2 ND ug/L 5.0 4.5 1 06/01/20 23:50 108-10-1 ND ug/L 1.0 0.27 1 06/01/20 23:50 100-42-5 ND ug/L 1.0 0.34 1 06/01/20 23:50 630-20-6 ND ug/L 1.0 0.22 1 06/01/20 23:50 79-34-5 ND ug/L 1.0 0.16 1 06/01/20 23:50 127-18-4 ND ug/L 10.0 1.9 1 06/01/20 23:50 109-99-9 ND ug/L 1.0 0.24 1 06/01/20 23:50 108-88-3 ND ug/L 1.0 0.18 1 06/01/20 23:50 71-55-6 ND ug/L 1.0 0.24 1 06/01/20 23:50 79-00-5 ND ug/L 1.0 0.22 1 06/01/20 23:50 79-01-6 ND ug/L 1.0 0.31 1 06/01/20 23:50 75-69-4 ND ug/L 1.0 0.35 1 06/01/20 23:50 96-18-4 ND ug/L 2.0 1.4 1 06/01/20 23:50 108-05-4 ND ug/L 1.0 0.24 1 06/01/20 23:50 75-01-4 ND ug/L 2.0 0.63 1 06/01/20 23:50 1330-20-7 97 % 70-130 1 06/01/20 23:50 460-00-4 103 % 70-130 1 06/01/20 23:50 17060-07-0 101 % 70-130 1 06/01/20 23:50 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 105 ug/L 4.0 2.3 2 05/29/2018:53 123-91-1 102 % 50-150 2 05/29/2018:53 17060-07-0 100 % 50-150 2 05/29/2018:53 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 12 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Sample: 1302-MW-8A Lab ID: 92478353003 Collected: 05/19/20 09:15 Received: 05/20/20 12:55 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Pace Analytical Services - Atlanta, GA Field pH 6.3 Std. Units 1 05/19/20 09:15 Field Temperature 16.9 deg C 1 05/19/20 09:15 Field Specific 358.8 umhos/c 1 05/19/20 09:15 Conductance m Field Turbidity 6.2 NTU 1 05/19/20 09:15 Field Oxidation Potential 195.0 mV 1 05/19/20 09:15 Oxygen, Dissolved 5.7 mg/L 1 05/19/20 09:15 7782-44-7 N2 Depth to Water 25.51 feet 1 05/19/20 09:15 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Atlanta, GA Antimony 4.1J ug/L 5.0 0.27 1 06/01/2019:48 06/02/2017:35 7440-36-0 Arsenic 0.62J ug/L 5.0 0.35 1 06/01/2019:48 06/02/2017:35 7440-38-2 Barium 91.1 ug/L 5.0 0.49 1 06/01/2019:48 06/02/2017:35 7440-39-3 Beryllium ND ug/L 0.50 0.074 1 06/01/2019:48 06/02/2017:35 7440-41-7 Cadmium 0.24J ug/L 0.50 0.11 1 06/01/2019:48 06/02/2017:35 7440-43-9 Chromium 0.93J ug/L 5.0 0.39 1 06/01/2019:48 06/02/2017:35 7440-47-3 Cobalt 8.3 ug/L 5.0 0.30 1 06/01/2019:48 06/02/2017:35 7440-48-4 Copper 22.1 ug/L 5.0 0.19 1 06/01/2019:48 06/02/2017:35 7440-50-8 Lead 2.5 ug/L 1.0 0.046 1 06/01/2019:48 06/02/2017:35 7439-92-1 Nickel 94.7 ug/L 5.0 0.31 1 06/01/2019:48 06/02/2017:35 7440-02-0 Selenium ND ug/L 5.0 1.3 1 06/01/2019:48 06/02/2017:35 7782-49-2 Silver ND ug/L 5.0 0.28 1 06/01/2019:48 06/02/2017:35 7440-22-4 Thallium 0.16J ug/L 1.0 0.052 1 06/01/2019:48 06/02/2017:35 7440-28-0 Vanadium 2.OJ ug/L 10.0 0.71 1 06/01/2019:48 06/02/2017:35 7440-62-2 Zinc 260 ug/L 10.0 1.5 1 06/01/2019:48 06/02/2017:35 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 06/02/20 00:08 67-64-1 Acrylonitrile ND ug/L 50.0 0.90 1 06/02/20 00:08 107-13-1 Benzene ND ug/L 1.0 0.15 1 06/02/20 00:08 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 06/02/20 00:08 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 06/02/20 00:08 75-27-4 Bromoform ND ug/L 1.0 0.62 1 06/02/20 00:08 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 06/02/20 00:08 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 06/02/20 00:08 78-93-3 Carbon disulfide ND ug/L 10.0 0.40 1 06/02/20 00:08 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 06/02/20 00:08 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 06/02/20 00:08 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 06/02/20 00:08 75-00-3 Chloroform ND ug/L 5.0 2.3 1 06/02/20 00:08 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 06/02/20 00:08 74-87-3 1,2-Dibromo-3- ND ug/L 5.0 0.26 1 06/02/20 00:08 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Sample: 1302-MW-8A Lab ID: 92478353003 Collected: 05/19/20 09:15 Received: 05/20/20 12:55 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 06/08/2020 04:58 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.41 1 06/02/20 00:08 124-48-1 ND ug/L 2.0 0.26 1 06/02/20 00:08 106-93-4 ND ug/L 1.0 0.46 1 06/02/20 00:08 74-95-3 ND ug/L 1.0 0.29 1 06/02/20 00:08 95-50-1 ND ug/L 1.0 0.26 1 06/02/20 00:08 106-46-7 ND ug/L 5.0 0.54 1 06/02/20 00:08 110-57-6 ND ug/L 1.0 0.27 1 06/02/20 00:08 75-34-3 ND ug/L 1.0 0.34 1 06/02/20 00:08 107-06-2 ND ug/L 1.0 0.24 1 06/02/20 00:08 75-35-4 ND ug/L 1.0 0.29 1 06/02/20 00:08 156-59-2 ND ug/L 1.0 0.25 1 06/02/20 00:08 156-60-5 ND ug/L 1.0 0.19 1 06/02/20 00:08 78-87-5 ND ug/L 1.0 0.30 1 06/02/20 00:08 10061-01-5 ND ug/L 1.0 0.31 1 06/02/20 00:08 10061-02-6 ND ug/L 1.0 0.26 1 06/02/20 00:08 100-41-4 ND ug/L 5.0 0.57 1 06/02/20 00:08 591-78-6 ND ug/L 20.0 12.5 1 06/02/20 00:08 74-88-4 ND ug/L 5.0 3.7 1 06/02/20 00:08 75-09-2 ND ug/L 5.0 4.5 1 06/02/20 00:08 108-10-1 ND ug/L 1.0 0.27 1 06/02/20 00:08 100-42-5 ND ug/L 1.0 0.34 1 06/02/20 00:08 630-20-6 ND ug/L 1.0 0.22 1 06/02/20 00:08 79-34-5 ND ug/L 1.0 0.16 1 06/02/20 00:08 127-18-4 ND ug/L 10.0 1.9 1 06/02/20 00:08 109-99-9 ND ug/L 1.0 0.24 1 06/02/20 00:08 108-88-3 ND ug/L 1.0 0.18 1 06/02/20 00:08 71-55-6 ND ug/L 1.0 0.24 1 06/02/20 00:08 79-00-5 ND ug/L 1.0 0.22 1 06/02/20 00:08 79-01-6 ND ug/L 1.0 0.31 1 06/02/20 00:08 75-69-4 ND ug/L 1.0 0.35 1 06/02/20 00:08 96-18-4 ND ug/L 2.0 1.4 1 06/02/20 00:08 108-05-4 ND ug/L 1.0 0.24 1 06/02/20 00:08 75-01-4 ND ug/L 2.0 0.63 1 06/02/20 00:08 1330-20-7 98 % 70-130 1 06/02/20 00:08 460-00-4 106 % 70-130 1 06/02/20 00:08 17060-07-0 102 % 70-130 1 06/02/20 00:08 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 1.2 1 05/29/2019:13 123-91-1 99 % 50-150 1 05/29/2019:13 17060-07-0 98 % 50-150 1 05/29/2019:13 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 14 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Sample: 1302-MW-10 Lab ID: 92478353004 Collected: 05/19/20 11:20 Received: 05/20/20 12:55 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Pace Analytical Services - Atlanta, GA Field pH 6.7 Std. Units 1 05/19/20 11:20 Field Temperature 16.1 deg C 1 05/19/20 11:20 Field Specific 1,898 umhos/c 1 05/19/20 11:20 Conductance m Field Turbidity 48.4 NTU 1 05/19/20 11:20 Field Oxidation Potential 11.3 mV 1 05/19/20 11:20 Oxygen, Dissolved 3.1 mg/L 1 05/19/20 11:20 7782-44-7 N2 Depth to Water 35.56 feet 1 05/19/20 11:20 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Atlanta, GA Antimony ND ug/L 5.0 0.27 1 06/01/2019:48 06/02/2017:40 7440-36-0 Arsenic 15.4 ug/L 5.0 0.35 1 06/01/2019:48 06/02/2017:40 7440-38-2 Barium 131 ug/L 5.0 0.49 1 06/01/2019:48 06/02/2017:40 7440-39-3 Beryllium 0.36J ug/L 0.50 0.074 1 06/01/2019:48 06/02/2017:40 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 06/01/2019:48 06/02/2017:40 7440-43-9 Chromium 1.3J ug/L 5.0 0.39 1 06/01/2019:48 06/02/2017:40 7440-47-3 Cobalt 27.0 ug/L 5.0 0.30 1 06/01/2019:48 06/02/2017:40 7440-48-4 Copper 0.49J ug/L 5.0 0.19 1 06/01/2019:48 06/02/2017:40 7440-50-8 Lead 0.15J ug/L 1.0 0.046 1 06/01/2019:48 06/02/2017:40 7439-92-1 Nickel 126 ug/L 5.0 0.31 1 06/01/2019:48 06/02/2017:40 7440-02-0 Selenium ND ug/L 5.0 1.3 1 06/01/2019:48 06/02/2017:40 7782-49-2 Silver ND ug/L 5.0 0.28 1 06/01/2019:48 06/02/2017:40 7440-22-4 Thallium 0.054J ug/L 1.0 0.052 1 06/01/2019:48 06/02/2017:40 7440-28-0 Vanadium 2.1J ug/L 10.0 0.71 1 06/01/2019:48 06/02/2017:40 7440-62-2 Zinc 2.4J ug/L 10.0 1.5 1 06/01/2019:48 06/02/2017:40 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 06/02/20 00:26 67-64-1 Acrylonitrile ND ug/L 50.0 0.90 1 06/02/20 00:26 107-13-1 Benzene 0.93J ug/L 1.0 0.15 1 06/02/20 00:26 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 06/02/20 00:26 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 06/02/20 00:26 75-27-4 Bromoform ND ug/L 1.0 0.62 1 06/02/20 00:26 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 06/02/20 00:26 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 06/02/20 00:26 78-93-3 Carbon disulfide ND ug/L 10.0 0.40 1 06/02/20 00:26 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 06/02/20 00:26 56-23-5 Chlorobenzene 33.6 ug/L 1.0 0.23 1 06/02/20 00:26 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 06/02/20 00:26 75-00-3 Chloroform ND ug/L 5.0 2.3 1 06/02/20 00:26 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 06/02/20 00:26 74-87-3 1,2-Dibromo-3- ND ug/L 5.0 0.26 1 06/02/20 00:26 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Sample: 1302-MW-10 Lab ID: 92478353004 Collected: 05/19/20 11:20 Received: 05/20/20 12:55 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 06/08/2020 04:58 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.41 1 06/02/20 00:26 124-48-1 ND ug/L 2.0 0.26 1 06/02/20 00:26 106-93-4 ND ug/L 1.0 0.46 1 06/02/20 00:26 74-95-3 0.94J ug/L 1.0 0.29 1 06/02/20 00:26 95-50-1 ND ug/L 1.0 0.26 1 06/02/20 00:26 106-46-7 ND ug/L 5.0 0.54 1 06/02/20 00:26 110-57-6 ND ug/L 1.0 0.27 1 06/02/20 00:26 75-34-3 ND ug/L 1.0 0.34 1 06/02/20 00:26 107-06-2 ND ug/L 1.0 0.24 1 06/02/20 00:26 75-35-4 ND ug/L 1.0 0.29 1 06/02/20 00:26 156-59-2 ND ug/L 1.0 0.25 1 06/02/20 00:26 156-60-5 ND ug/L 1.0 0.19 1 06/02/20 00:26 78-87-5 ND ug/L 1.0 0.30 1 06/02/20 00:26 10061-01-5 ND ug/L 1.0 0.31 1 06/02/20 00:26 10061-02-6 ND ug/L 1.0 0.26 1 06/02/20 00:26 100-41-4 ND ug/L 5.0 0.57 1 06/02/20 00:26 591-78-6 ND ug/L 20.0 12.5 1 06/02/20 00:26 74-88-4 ND ug/L 5.0 3.7 1 06/02/20 00:26 75-09-2 ND ug/L 5.0 4.5 1 06/02/20 00:26 108-10-1 ND ug/L 1.0 0.27 1 06/02/20 00:26 100-42-5 ND ug/L 1.0 0.34 1 06/02/20 00:26 630-20-6 ND ug/L 1.0 0.22 1 06/02/20 00:26 79-34-5 ND ug/L 1.0 0.16 1 06/02/20 00:26 127-18-4 ND ug/L 10.0 1.9 1 06/02/20 00:26 109-99-9 ND ug/L 1.0 0.24 1 06/02/20 00:26 108-88-3 ND ug/L 1.0 0.18 1 06/02/20 00:26 71-55-6 ND ug/L 1.0 0.24 1 06/02/20 00:26 79-00-5 ND ug/L 1.0 0.22 1 06/02/20 00:26 79-01-6 ND ug/L 1.0 0.31 1 06/02/20 00:26 75-69-4 ND ug/L 1.0 0.35 1 06/02/20 00:26 96-18-4 ND ug/L 2.0 1.4 1 06/02/20 00:26 108-05-4 ND ug/L 1.0 0.24 1 06/02/20 00:26 75-01-4 ND ug/L 2.0 0.63 1 06/02/20 00:26 1330-20-7 97 % 70-130 1 06/02/20 00:26 460-00-4 101 % 70-130 1 06/02/20 00:26 17060-07-0 100 % 70-130 1 06/02/20 00:26 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 82.8 ug/L 2.0 1.2 1 05/29/2019:33 123-91-1 98 % 50-150 1 05/29/2019:33 17060-07-0 98 % 50-150 1 05/29/2019:33 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 16 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Sample: 1302-MW-11 Lab ID: 92478353005 Collected: 05/19/20 10:40 Received: 05/20/20 12:55 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Pace Analytical Services - Atlanta, GA Field pH 6.4 Std. Units 1 05/19/20 10:40 Field Temperature 15.5 deg C 1 05/19/20 10:40 Field Specific 759 umhos/c 1 05/19/20 10:40 Conductance m Field Turbidity 8.4 NTU 1 05/19/20 10:40 Field Oxidation Potential 12.0 mV 1 05/19/20 10:40 Oxygen, Dissolved 3.2 mg/L 1 05/19/20 10:40 7782-44-7 N2 Depth to Water 25.51 feet 1 05/19/20 10:40 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Atlanta, GA Antimony ND ug/L 5.0 0.27 1 06/01/2019:48 06/02/2017:46 7440-36-0 Arsenic ND ug/L 5.0 0.35 1 06/01/2019:48 06/02/2017:46 7440-38-2 Barium 189 ug/L 5.0 0.49 1 06/01/2019:48 06/02/2017:46 7440-39-3 Beryllium ND ug/L 0.50 0.074 1 06/01/2019:48 06/02/2017:46 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 06/01/2019:48 06/02/2017:46 7440-43-9 Chromium 0.47J ug/L 5.0 0.39 1 06/01/2019:48 06/02/2017:46 7440-47-3 Cobalt 18.0 ug/L 5.0 0.30 1 06/01/2019:48 06/02/2017:46 7440-48-4 Copper 2.2J ug/L 5.0 0.19 1 06/01/2019:48 06/02/2017:46 7440-50-8 Lead 0.28J ug/L 1.0 0.046 1 06/01/2019:48 06/02/2017:46 7439-92-1 Nickel 11.3 ug/L 5.0 0.31 1 06/01/2019:48 06/02/2017:46 7440-02-0 Selenium ND ug/L 5.0 1.3 1 06/01/2019:48 06/02/2017:46 7782-49-2 Silver ND ug/L 5.0 0.28 1 06/01/2019:48 06/02/2017:46 7440-22-4 Thallium ND ug/L 1.0 0.052 1 06/01/2019:48 06/02/2017:46 7440-28-0 Vanadium ND ug/L 10.0 0.71 1 06/01/2019:48 06/02/2017:46 7440-62-2 Zinc 12.5 ug/L 10.0 1.5 1 06/01/2019:48 06/02/2017:46 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 06/02/20 00:44 67-64-1 Acrylonitrile ND ug/L 50.0 0.90 1 06/02/20 00:44 107-13-1 Benzene ND ug/L 1.0 0.15 1 06/02/20 00:44 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 06/02/20 00:44 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 06/02/20 00:44 75-27-4 Bromoform ND ug/L 1.0 0.62 1 06/02/20 00:44 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 06/02/20 00:44 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 06/02/20 00:44 78-93-3 Carbon disulfide ND ug/L 10.0 0.40 1 06/02/20 00:44 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 06/02/20 00:44 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 06/02/20 00:44 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 06/02/20 00:44 75-00-3 Chloroform ND ug/L 5.0 2.3 1 06/02/20 00:44 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 06/02/20 00:44 74-87-3 1,2-Dibromo-3- ND ug/L 5.0 0.26 1 06/02/20 00:44 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Sample: 1302-MW-11 Lab ID: 92478353005 Collected: 05/19/20 10:40 Received: 05/20/20 12:55 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 06/08/2020 04:58 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.41 1 06/02/20 00:44 124-48-1 ND ug/L 2.0 0.26 1 06/02/20 00:44 106-93-4 ND ug/L 1.0 0.46 1 06/02/20 00:44 74-95-3 ND ug/L 1.0 0.29 1 06/02/20 00:44 95-50-1 ND ug/L 1.0 0.26 1 06/02/20 00:44 106-46-7 ND ug/L 5.0 0.54 1 06/02/20 00:44 110-57-6 ND ug/L 1.0 0.27 1 06/02/20 00:44 75-34-3 ND ug/L 1.0 0.34 1 06/02/20 00:44 107-06-2 ND ug/L 1.0 0.24 1 06/02/20 00:44 75-35-4 ND ug/L 1.0 0.29 1 06/02/20 00:44 156-59-2 ND ug/L 1.0 0.25 1 06/02/20 00:44 156-60-5 ND ug/L 1.0 0.19 1 06/02/20 00:44 78-87-5 ND ug/L 1.0 0.30 1 06/02/20 00:44 10061-01-5 ND ug/L 1.0 0.31 1 06/02/20 00:44 10061-02-6 ND ug/L 1.0 0.26 1 06/02/20 00:44 100-41-4 ND ug/L 5.0 0.57 1 06/02/20 00:44 591-78-6 ND ug/L 20.0 12.5 1 06/02/20 00:44 74-88-4 ND ug/L 5.0 3.7 1 06/02/20 00:44 75-09-2 ND ug/L 5.0 4.5 1 06/02/20 00:44 108-10-1 ND ug/L 1.0 0.27 1 06/02/20 00:44 100-42-5 ND ug/L 1.0 0.34 1 06/02/20 00:44 630-20-6 ND ug/L 1.0 0.22 1 06/02/20 00:44 79-34-5 ND ug/L 1.0 0.16 1 06/02/20 00:44 127-18-4 ND ug/L 10.0 1.9 1 06/02/20 00:44 109-99-9 ND ug/L 1.0 0.24 1 06/02/20 00:44 108-88-3 ND ug/L 1.0 0.18 1 06/02/20 00:44 71-55-6 ND ug/L 1.0 0.24 1 06/02/20 00:44 79-00-5 ND ug/L 1.0 0.22 1 06/02/20 00:44 79-01-6 ND ug/L 1.0 0.31 1 06/02/20 00:44 75-69-4 ND ug/L 1.0 0.35 1 06/02/20 00:44 96-18-4 ND ug/L 2.0 1.4 1 06/02/20 00:44 108-05-4 ND ug/L 1.0 0.24 1 06/02/20 00:44 75-01-4 ND ug/L 2.0 0.63 1 06/02/20 00:44 1330-20-7 98 % 70-130 1 06/02/20 00:44 460-00-4 107 % 70-130 1 06/02/20 00:44 17060-07-0 101 % 70-130 1 06/02/20 00:44 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 12.1 ug/L 2.0 1.2 1 05/29/2019:52 123-91-1 98 % 50-150 1 05/29/2019:52 17060-07-0 98 % 50-150 1 05/29/2019:52 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 18 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Sample: 1302-Dup1 Lab ID: 92478353006 Collected: 05/19/20 09:15 Received: 05/20/20 12:55 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Atlanta, GA Antimony 4.OJ ug/L 5.0 0.27 1 06/01/2019:48 06/02/2017:52 7440-36-0 Arsenic 0.57J ug/L 5.0 0.35 1 06/01/2019:48 06/02/2017:52 7440-38-2 Barium 91.8 ug/L 5.0 0.49 1 06/01/2019:48 06/02/2017:52 7440-39-3 Beryllium ND ug/L 0.50 0.074 1 06/01/2019:48 06/02/2017:52 7440-41-7 Cadmium 0.23J ug/L 0.50 0.11 1 06/01/2019:48 06/02/2017:52 7440-43-9 Chromium 0.79J ug/L 5.0 0.39 1 06/01/2019:48 06/02/2017:52 7440-47-3 Cobalt 8.7 ug/L 5.0 0.30 1 06/01/2019:48 06/02/2017:52 7440-48-4 Copper 21.0 ug/L 5.0 0.19 1 06/01/2019:48 06/02/2017:52 7440-50-8 Lead 2.9 ug/L 1.0 0.046 1 06/01/2019:48 06/02/2017:52 7439-92-1 Nickel 96.5 ug/L 5.0 0.31 1 06/01/2019:48 06/02/2017:52 7440-02-0 Selenium ND ug/L 5.0 1.3 1 06/01/2019:48 06/02/2017:52 7782-49-2 Silver ND ug/L 5.0 0.28 1 06/01/2019:48 06/02/2017:52 7440-22-4 Thallium 0.069J ug/L 1.0 0.052 1 06/01/2019:48 06/02/2017:52 7440-28-0 Vanadium 2.5J ug/L 10.0 0.71 1 06/01/2019:48 06/02/2017:52 7440-62-2 Zinc 277 ug/L 10.0 1.5 1 06/01/2019:48 06/02/2017:52 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 06/02/20 19:18 67-64-1 Acrylonitrile ND ug/L 50.0 0.90 1 06/02/20 19:18 107-13-1 Benzene ND ug/L 1.0 0.15 1 06/02/20 19:18 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 06/02/20 19:18 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 06/02/20 19:18 75-27-4 Bromoform ND ug/L 1.0 0.62 1 06/02/20 19:18 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 06/02/20 19:18 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 06/02/20 19:18 78-93-3 Carbon disulfide ND ug/L 10.0 0.40 1 06/02/20 19:18 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 06/02/20 19:18 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 06/02/20 19:18 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 06/02/20 19:18 75-00-3 Chloroform ND ug/L 5.0 2.3 1 06/02/20 19:18 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 06/02/20 19:18 74-87-3 1,2-Dibromo-3- ND ug/L 5.0 0.26 1 06/02/20 19:18 96-12-8 chloropropane Dibromochloromethane ND ug/L 1.0 0.41 1 06/02/20 19:18 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.26 1 06/02/20 19:18 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 06/02/20 19:18 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 06/02/20 19:18 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 06/02/20 19:18 106-46-7 trans-1,4-Dichloro-2- ND ug/L 5.0 0.54 1 06/02/20 19:18 110-57-6 v2 butene 1,1-Dichloroethane ND ug/L 1.0 0.27 1 06/02/20 19:18 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 06/02/20 19:18 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 06/02/20 19:18 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.29 1 06/02/20 19:18 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Sample: 1302-Dup1 Lab ID: 92478353006 Collected: 05/19/20 09:15 Received: 05/20/20 12:55 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 06/08/2020 04:58 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.25 1 06/02/20 19:18 156-60-5 ND ug/L 1.0 0.19 1 06/02/20 19:18 78-87-5 ND ug/L 1.0 0.30 1 06/02/20 19:18 10061-01-5 ND ug/L 1.0 0.31 1 06/02/20 19:18 10061-02-6 ND ug/L 1.0 0.26 1 06/02/20 19:18 100-41-4 ND ug/L 5.0 0.57 1 06/02/20 19:18 591-78-6 ND ug/L 20.0 12.5 1 06/02/20 19:18 74-88-4 ND ug/L 5.0 3.7 1 06/02/20 19:18 75-09-2 ND ug/L 5.0 4.5 1 06/02/20 19:18 108-10-1 ND ug/L 1.0 0.27 1 06/02/20 19:18 100-42-5 ND ug/L 1.0 0.34 1 06/02/20 19:18 630-20-6 ND ug/L 1.0 0.22 1 06/02/20 19:18 79-34-5 ND ug/L 1.0 0.16 1 06/02/20 19:18 127-18-4 ND ug/L 10.0 1.9 1 06/02/20 19:18 109-99-9 ND ug/L 1.0 0.24 1 06/02/20 19:18 108-88-3 ND ug/L 1.0 0.18 1 06/02/20 19:18 71-55-6 ND ug/L 1.0 0.24 1 06/02/20 19:18 79-00-5 ND ug/L 1.0 0.22 1 06/02/20 19:18 79-01-6 ND ug/L 1.0 0.31 1 06/02/20 19:18 75-69-4 ND ug/L 1.0 0.35 1 06/02/20 19:18 96-18-4 ND ug/L 2.0 1.4 1 06/02/20 19:18 108-05-4 ND ug/L 1.0 0.24 1 06/02/20 19:18 75-01-4 ND ug/L 2.0 0.63 1 06/02/20 19:18 1330-20-7 100 % 70-130 1 06/02/20 19:18 460-00-4 104 % 70-130 1 06/02/20 19:18 17060-07-0 103 % 70-130 1 06/02/20 19:18 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 1.2 1 05/29/20 20:12 123-91-1 99 % 50-150 1 05/29/20 20:12 17060-07-0 98 % 50-150 1 05/29/20 20:12 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Sample: 1302-SW-1 Lab ID: 92478353007 Collected: 05/19/20 15:20 Received: 05/20/20 12:55 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Pace Analytical Services - Atlanta, GA Field pH 7.4 Std. Units 1 05/19/20 15:20 Field Temperature 16.6 deg C 1 05/19/20 15:20 Field Specific 400.3 umhos/c 1 05/19/20 15:20 Conductance m Field Turbidity 13.1 NTU 1 05/19/20 15:20 Field Oxidation Potential -18.0 mV 1 05/19/20 15:20 Oxygen, Dissolved 5.9 mg/L 1 05/19/20 15:20 7782-44-7 N2 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Atlanta, GA Antimony ND ug/L 5.0 0.27 1 06/01/2019:48 06/02/2018:09 7440-36-0 Arsenic ND ug/L 5.0 0.35 1 06/01/2019:48 06/02/2018:09 7440-38-2 Barium 65.4 ug/L 5.0 0.49 1 06/01/2019:48 06/02/2018:09 7440-39-3 Beryllium ND ug/L 0.50 0.074 1 06/01/2019:48 06/02/2018:09 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 06/01/2019:48 06/02/2018:09 7440-43-9 Chromium 0.71J ug/L 5.0 0.39 1 06/01/2019:48 06/02/2018:09 7440-47-3 Cobalt 1.9J ug/L 5.0 0.30 1 06/01/2019:48 06/02/2018:09 7440-48-4 Copper 1.5J ug/L 5.0 0.19 1 06/01/2019:48 06/02/2018:09 7440-50-8 Lead 0.21J ug/L 1.0 0.046 1 06/01/2019:48 06/02/2018:09 7439-92-1 Nickel 4.5J ug/L 5.0 0.31 1 06/01/2019:48 06/02/2018:09 7440-02-0 Selenium ND ug/L 5.0 1.3 1 06/01/2019:48 06/02/2018:09 7782-49-2 Silver ND ug/L 5.0 0.28 1 06/01/2019:48 06/02/2018:09 7440-22-4 Thallium ND ug/L 1.0 0.052 1 06/01/2019:48 06/02/2018:09 7440-28-0 Vanadium ND ug/L 10.0 0.71 1 06/01/2019:48 06/02/2018:09 7440-62-2 Zinc 3.1J ug/L 10.0 1.5 1 06/01/2019:48 06/02/2018:09 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 06/02/20 19:36 67-64-1 Acrylonitrile ND ug/L 50.0 0.90 1 06/02/20 19:36 107-13-1 Benzene ND ug/L 1.0 0.15 1 06/02/20 19:36 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 06/02/20 19:36 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 06/02/20 19:36 75-27-4 Bromoform ND ug/L 1.0 0.62 1 06/02/20 19:36 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 06/02/20 19:36 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 06/02/20 19:36 78-93-3 Carbon disulfide ND ug/L 10.0 0.40 1 06/02/20 19:36 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 06/02/20 19:36 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 06/02/20 19:36 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 06/02/20 19:36 75-00-3 Chloroform ND ug/L 5.0 2.3 1 06/02/20 19:36 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 06/02/20 19:36 74-87-3 1,2-Dibromo-3- ND ug/L 5.0 0.26 1 06/02/20 19:36 96-12-8 chloropropane Dibromochloromethane ND ug/L 1.0 0.41 1 06/02/20 19:36 124-48-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Sample: 1302-SW-1 Lab ID: 92478353007 Collected: 05/19/20 15:20 Received: 05/20/20 12:55 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 06/08/2020 04:58 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 2.0 0.26 1 06/02/20 19:36 106-93-4 ND ug/L 1.0 0.46 1 06/02/20 19:36 74-95-3 ND ug/L 1.0 0.29 1 06/02/20 19:36 95-50-1 ND ug/L 1.0 0.26 1 06/02/20 19:36 106-46-7 ND ug/L 5.0 0.54 1 06/02/20 19:36 110-57-6 ND ug/L 1.0 0.27 1 06/02/20 19:36 75-34-3 ND ug/L 1.0 0.34 1 06/02/20 19:36 107-06-2 ND ug/L 1.0 0.24 1 06/02/20 19:36 75-35-4 ND ug/L 1.0 0.29 1 06/02/20 19:36 156-59-2 ND ug/L 1.0 0.25 1 06/02/20 19:36 156-60-5 ND ug/L 1.0 0.19 1 06/02/20 19:36 78-87-5 ND ug/L 1.0 0.30 1 06/02/20 19:36 10061-01-5 ND ug/L 1.0 0.31 1 06/02/20 19:36 10061-02-6 ND ug/L 1.0 0.26 1 06/02/20 19:36 100-41-4 ND ug/L 5.0 0.57 1 06/02/20 19:36 591-78-6 ND ug/L 20.0 12.5 1 06/02/20 19:36 74-88-4 ND ug/L 5.0 3.7 1 06/02/20 19:36 75-09-2 ND ug/L 5.0 4.5 1 06/02/20 19:36 108-10-1 ND ug/L 1.0 0.27 1 06/02/20 19:36 100-42-5 ND ug/L 1.0 0.34 1 06/02/20 19:36 630-20-6 ND ug/L 1.0 0.22 1 06/02/20 19:36 79-34-5 ND ug/L 1.0 0.16 1 06/02/20 19:36 127-18-4 ND ug/L 10.0 1.9 1 06/02/20 19:36 109-99-9 ND ug/L 1.0 0.24 1 06/02/20 19:36 108-88-3 ND ug/L 1.0 0.18 1 06/02/20 19:36 71-55-6 ND ug/L 1.0 0.24 1 06/02/20 19:36 79-00-5 ND ug/L 1.0 0.22 1 06/02/20 19:36 79-01-6 ND ug/L 1.0 0.31 1 06/02/20 19:36 75-69-4 ND ug/L 1.0 0.35 1 06/02/20 19:36 96-18-4 ND ug/L 2.0 1.4 1 06/02/20 19:36 108-05-4 ND ug/L 1.0 0.24 1 06/02/20 19:36 75-01-4 ND ug/L 2.0 0.63 1 06/02/20 19:36 1330-20-7 98 % 70-130 1 06/02/20 19:36 460-00-4 104 % 70-130 1 06/02/20 19:36 17060-07-0 102 % 70-130 1 06/02/20 19:36 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 9.9 ug/L 2.0 1.2 1 05/30/2016:52 123-91-1 104 % 50-150 1 05/30/2016:52 17060-07-0 96 % 50-150 1 05/30/2016:52 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 22 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Sample: 1302-SW-2 Lab ID: 92478353008 Collected: 05/19/20 09:30 Received: 05/20/20 12:55 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Pace Analytical Services - Atlanta, GA Field pH 7.0 Std. Units 1 05/19/20 09:30 Field Temperature 17.2 deg C 1 05/19/20 09:30 Field Specific 373.9 umhos/c 1 05/19/20 09:30 Conductance m Field Turbidity 108.9 NTU 1 05/19/20 09:30 Field Oxidation Potential 66.9 mV 1 05/19/20 09:30 Oxygen, Dissolved 5.1 mg/L 1 05/19/20 09:30 7782-44-7 N2 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Atlanta, GA Antimony ND ug/L 5.0 0.27 1 06/01/2019:48 06/02/2018:15 7440-36-0 Arsenic 0.69J ug/L 5.0 0.35 1 06/01/2019:48 06/02/2018:15 7440-38-2 Barium 100 ug/L 5.0 0.49 1 06/01/2019:48 06/02/2018:15 7440-39-3 Beryllium 0.23J ug/L 0.50 0.074 1 06/01/2019:48 06/02/2018:15 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 06/01/2019:48 06/02/2018:15 7440-43-9 Chromium 3.5J ug/L 5.0 0.39 1 06/01/2019:48 06/02/2018:15 7440-47-3 Cobalt 3.2J ug/L 5.0 0.30 1 06/01/2019:48 06/02/2018:15 7440-48-4 Copper 4.1J ug/L 5.0 0.19 1 06/01/2019:48 06/02/2018:15 7440-50-8 Lead 2.2 ug/L 1.0 0.046 1 06/01/2019:48 06/02/2018:15 7439-92-1 Nickel 5.4 ug/L 5.0 0.31 1 06/01/2019:48 06/02/2018:15 7440-02-0 Selenium 1.7J ug/L 5.0 1.3 1 06/01/2019:48 06/02/2018:15 7782-49-2 Silver ND ug/L 5.0 0.28 1 06/01/2019:48 06/02/2018:15 7440-22-4 Thallium ND ug/L 1.0 0.052 1 06/01/2019:48 06/02/2018:15 7440-28-0 Vanadium 8.6J ug/L 10.0 0.71 1 06/01/2019:48 06/02/2018:15 7440-62-2 Zinc 10.2 ug/L 10.0 1.5 1 06/01/2019:48 06/02/2018:15 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 06/02/20 19:54 67-64-1 Acrylonitrile ND ug/L 50.0 0.90 1 06/02/20 19:54 107-13-1 Benzene ND ug/L 1.0 0.15 1 06/02/20 19:54 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 06/02/20 19:54 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 06/02/20 19:54 75-27-4 Bromoform ND ug/L 1.0 0.62 1 06/02/20 19:54 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 06/02/20 19:54 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 06/02/20 19:54 78-93-3 Carbon disulfide ND ug/L 10.0 0.40 1 06/02/20 19:54 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 06/02/20 19:54 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 06/02/20 19:54 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 06/02/20 19:54 75-00-3 Chloroform ND ug/L 5.0 2.3 1 06/02/20 19:54 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 06/02/20 19:54 74-87-3 1,2-Dibromo-3- ND ug/L 5.0 0.26 1 06/02/20 19:54 96-12-8 chloropropane Dibromochloromethane ND ug/L 1.0 0.41 1 06/02/20 19:54 124-48-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Sample: 1302-SW-2 Lab ID: 92478353008 Collected: 05/19/20 09:30 Received: 05/20/20 12:55 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 06/08/2020 04:58 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 2.0 0.26 1 06/02/20 19:54 106-93-4 ND ug/L 1.0 0.46 1 06/02/20 19:54 74-95-3 ND ug/L 1.0 0.29 1 06/02/20 19:54 95-50-1 ND ug/L 1.0 0.26 1 06/02/20 19:54 106-46-7 ND ug/L 5.0 0.54 1 06/02/20 19:54 110-57-6 ND ug/L 1.0 0.27 1 06/02/20 19:54 75-34-3 ND ug/L 1.0 0.34 1 06/02/20 19:54 107-06-2 ND ug/L 1.0 0.24 1 06/02/20 19:54 75-35-4 ND ug/L 1.0 0.29 1 06/02/20 19:54 156-59-2 ND ug/L 1.0 0.25 1 06/02/20 19:54 156-60-5 ND ug/L 1.0 0.19 1 06/02/20 19:54 78-87-5 ND ug/L 1.0 0.30 1 06/02/20 19:54 10061-01-5 ND ug/L 1.0 0.31 1 06/02/20 19:54 10061-02-6 ND ug/L 1.0 0.26 1 06/02/20 19:54 100-41-4 ND ug/L 5.0 0.57 1 06/02/20 19:54 591-78-6 ND ug/L 20.0 12.5 1 06/02/20 19:54 74-88-4 ND ug/L 5.0 3.7 1 06/02/20 19:54 75-09-2 ND ug/L 5.0 4.5 1 06/02/20 19:54 108-10-1 ND ug/L 1.0 0.27 1 06/02/20 19:54 100-42-5 ND ug/L 1.0 0.34 1 06/02/20 19:54 630-20-6 ND ug/L 1.0 0.22 1 06/02/20 19:54 79-34-5 ND ug/L 1.0 0.16 1 06/02/20 19:54 127-18-4 ND ug/L 10.0 1.9 1 06/02/20 19:54 109-99-9 ND ug/L 1.0 0.24 1 06/02/20 19:54 108-88-3 ND ug/L 1.0 0.18 1 06/02/20 19:54 71-55-6 ND ug/L 1.0 0.24 1 06/02/20 19:54 79-00-5 ND ug/L 1.0 0.22 1 06/02/20 19:54 79-01-6 ND ug/L 1.0 0.31 1 06/02/20 19:54 75-69-4 ND ug/L 1.0 0.35 1 06/02/20 19:54 96-18-4 ND ug/L 2.0 1.4 1 06/02/20 19:54 108-05-4 ND ug/L 1.0 0.24 1 06/02/20 19:54 75-01-4 ND ug/L 2.0 0.63 1 06/02/20 19:54 1330-20-7 98 % 70-130 1 06/02/20 19:54 460-00-4 106 % 70-130 1 06/02/20 19:54 17060-07-0 103 % 70-130 1 06/02/20 19:54 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 6.7 ug/L 2.0 1.2 1 05/30/2017:12 123-91-1 105 % 50-150 1 05/30/2017:12 17060-07-0 96 % 50-150 1 05/30/2017:12 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 24 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus Co Units 2/3 MSW Pace Project No.: 92478136 Sample: 1302-CD-1s Lab ID: 92478136001 Collected: 05/18/20 14:20 Received: 05/19/20 08:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Pace Analytical Services - Atlanta, GA Field pH 6.1 Std. Units 1 05/18/20 14:20 Field Temperature 20.3 deg C 1 05/18/20 14:20 Field Specific 122.3 umhos/c 1 05/18/20 14:20 Conductance m Field Turbidity 9.3 NTU 1 05/18/20 14:20 Field Oxidation Potential -32.4 mV 1 05/18/20 14:20 Oxygen, Dissolved 4.3 mg/L 1 05/18/20 14:20 7782-44-7 N2 Depth to Water 29.02 feet 1 05/18/20 14:20 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Atlanta, GA Antimony ND ug/L 5.0 0.27 1 05/26/2015:30 05/27/2019:07 7440-36-0 Arsenic 0.46J ug/L 5.0 0.35 1 05/26/2015:30 05/27/2019:07 7440-38-2 Barium 34.5 ug/L 5.0 0.49 1 05/26/2015:30 05/27/2019:07 7440-39-3 Beryllium ND ug/L 0.50 0.074 1 05/26/2015:30 05/27/2019:07 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 05/26/2015:30 05/27/2019:07 7440-43-9 Chromium 2.2J ug/L 5.0 0.39 1 05/26/2015:30 05/27/2019:07 7440-47-3 Cobalt ND ug/L 5.0 0.30 1 05/26/2015:30 05/27/2019:07 7440-48-4 Copper 0.92J ug/L 5.0 0.19 1 05/26/2015:30 05/27/2019:07 7440-50-8 Iron 437 ug/L 40.0 9.7 1 05/26/2015:30 05/27/2019:07 7439-89-6 Lead 0.23J ug/L 1.0 0.046 1 05/26/2015:30 05/27/2019:07 7439-92-1 Manganese 11.3 ug/L 10.0 0.57 1 05/26/2015:30 05/27/2019:07 7439-96-5 Nickel 1.4J ug/L 5.0 0.31 1 05/26/2015:30 05/27/2019:07 7440-02-0 Selenium ND ug/L 5.0 1.3 1 05/26/2015:30 05/27/2019:07 7782-49-2 Silver ND ug/L 5.0 0.28 1 05/26/2015:30 05/27/2019:07 7440-22-4 Thallium ND ug/L 1.0 0.052 1 05/26/2015:30 05/27/2019:07 7440-28-0 Vanadium 6.4J ug/L 10.0 0.71 1 05/26/2015:30 05/27/2019:07 7440-62-2 Zinc 6.9J ug/L 10.0 1.5 1 05/26/2015:30 05/27/2019:07 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services - Atlanta, GA Mercury ND ug/L 0.20 0.14 1 06/04/2015:42 06/05/2012:09 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 05/29/20 22:21 67-64-1 Acrylonitrile ND ug/L 50.0 0.90 1 05/29/20 22:21 107-13-1 Benzene ND ug/L 1.0 0.15 1 05/29/20 22:21 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 05/29/20 22:21 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 05/29/20 22:21 75-27-4 Bromoform ND ug/L 1.0 0.62 1 05/29/20 22:21 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 05/29/20 22:21 74-83-9 IK 2-Butanone (MEK) ND ug/L 5.0 3.3 1 05/29/20 22:21 78-93-3 Carbon disulfide ND ug/L 10.0 0.40 1 05/29/20 22:21 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 05/29/20 22:21 56-23-5 Date: 06/09/2020 08:56 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 238 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus Co Units 2/3 MSW Pace Project No.: 92478136 Sample: 1302-CD-1s Lab ID: 92478136001 Collected: 05/18/20 14:20 Received: 05/19/20 08:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 06/09/2020 08:56 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.23 1 05/29/20 22:21 108-90-7 ND ug/L 1.0 0.49 1 05/29/20 22:21 75-00-3 IK,v1 ND ug/L 5.0 2.3 1 05/29/20 22:21 67-66-3 ND ug/L 1.0 0.39 1 05/29/20 22:21 74-87-3 ND ug/L 5.0 0.26 1 05/29/20 22:21 96-12-8 ND ug/L 1.0 0.41 1 05/29/20 22:21 124-48-1 ND ug/L 2.0 0.26 1 05/29/20 22:21 106-93-4 ND ug/L 1.0 0.46 1 05/29/20 22:21 74-95-3 ND ug/L 1.0 0.29 1 05/29/20 22:21 95-50-1 ND ug/L 1.0 0.26 1 05/29/20 22:21 106-46-7 ND ug/L 5.0 0.54 1 05/29/20 22:21 110-57-6 v1 ND ug/L 1.0 0.27 1 05/29/20 22:21 75-34-3 ND ug/L 1.0 0.34 1 05/29/20 22:21 107-06-2 ND ug/L 1.0 0.24 1 05/29/20 22:21 75-35-4 ND ug/L 1.0 0.29 1 05/29/20 22:21 156-59-2 ND ug/L 1.0 0.25 1 05/29/20 22:21 156-60-5 ND ug/L 1.0 0.19 1 05/29/20 22:21 78-87-5 ND ug/L 1.0 0.30 1 05/29/20 22:21 10061-01-5 ND ug/L 1.0 0.31 1 05/29/20 22:21 10061-02-6 ND ug/L 1.0 0.26 1 05/29/20 22:21 100-41-4 ND ug/L 5.0 0.57 1 05/29/20 22:21 591-78-6 v1 ND ug/L 20.0 12.5 1 05/29/20 22:21 74-88-4 ND ug/L 5.0 3.7 1 05/29/20 22:21 75-09-2 ND ug/L 5.0 4.5 1 05/29/20 22:21 108-10-1 v1 ND ug/L 1.0 0.27 1 05/29/20 22:21 100-42-5 ND ug/L 1.0 0.34 1 05/29/20 22:21 630-20-6 ND ug/L 1.0 0.22 1 05/29/20 22:21 79-34-5 ND ug/L 1.0 0.16 1 05/29/20 22:21 127-18-4 ND ug/L 10.0 1.9 1 05/29/20 22:21 109-99-9 ND ug/L 1.0 0.24 1 05/29/20 22:21 108-88-3 ND ug/L 1.0 0.18 1 05/29/20 22:21 71-55-6 ND ug/L 1.0 0.24 1 05/29/20 22:21 79-00-5 ND ug/L 1.0 0.22 1 05/29/20 22:21 79-01-6 ND ug/L 1.0 0.31 1 05/29/20 22:21 75-69-4 ND ug/L 1.0 0.35 1 05/29/20 22:21 96-18-4 ND ug/L 2.0 1.4 1 05/29/20 22:21 108-05-4 ND ug/L 1.0 0.24 1 05/29/20 22:21 75-01-4 ND ug/L 2.0 0.63 1 05/29/20 22:21 1330-20-7 100 % 70-130 1 05/29/20 22:21 460-00-4 95 % 70-130 1 05/29/20 22:21 17060-07-0 104 % 70-130 1 05/29/20 22:21 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 238 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus Co Units 2/3 MSW Pace Project No.: 92478136 Sample: 1302-CD-1d Lab ID: 92478136002 Collected: 05/18/20 13:05 Received: 05/19/20 08:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Pace Analytical Services - Atlanta, GA Field pH 6.2 Std. Units 1 05/18/20 13:05 Field Temperature 20.4 deg C 1 05/18/20 13:05 Field Specific 118.1 umhos/c 1 05/18/20 13:05 Conductance m Field Turbidity 3.0 NTU 1 05/18/20 13:05 Field Oxidation Potential 31.5 mV 1 05/18/20 13:05 Oxygen, Dissolved 2.4 mg/L 1 05/18/20 13:05 7782-44-7 N2 Depth to Water 52.21 feet 1 05/18/20 13:05 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Atlanta, GA Antimony ND ug/L 5.0 0.27 1 05/26/2015:30 05/27/2019:13 7440-36-0 Arsenic ND ug/L 5.0 0.35 1 05/26/2015:30 05/27/2019:13 7440-38-2 Barium 29.1 ug/L 5.0 0.49 1 05/26/2015:30 05/27/2019:13 7440-39-3 Beryllium ND ug/L 0.50 0.074 1 05/26/2015:30 05/27/2019:13 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 05/26/2015:30 05/27/2019:13 7440-43-9 Chromium 0.64J ug/L 5.0 0.39 1 05/26/2015:30 05/27/2019:13 7440-47-3 Cobalt ND ug/L 5.0 0.30 1 05/26/2015:30 05/27/2019:13 7440-48-4 Copper ND ug/L 5.0 0.19 1 05/26/2015:30 05/27/2019:13 7440-50-8 Iron 27.2J ug/L 40.0 9.7 1 05/26/2015:30 05/27/2019:13 7439-89-6 Lead ND ug/L 1.0 0.046 1 05/26/2015:30 05/27/2019:13 7439-92-1 Manganese 2.OJ ug/L 10.0 0.57 1 05/26/2015:30 05/27/2019:13 7439-96-5 Nickel 0.33J ug/L 5.0 0.31 1 05/26/2015:30 05/27/2019:13 7440-02-0 Selenium ND ug/L 5.0 1.3 1 05/26/2015:30 05/27/2019:13 7782-49-2 Silver ND ug/L 5.0 0.28 1 05/26/2015:30 05/27/2019:13 7440-22-4 Thallium ND ug/L 1.0 0.052 1 05/26/2015:30 05/27/2019:13 7440-28-0 Vanadium 5.6J ug/L 10.0 0.71 1 05/26/2015:30 05/27/2019:13 7440-62-2 Zinc 2.OJ ug/L 10.0 1.5 1 05/26/2015:30 05/27/2019:13 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services - Atlanta, GA Mercury ND ug/L 0.20 0.14 1 06/04/2015:42 06/05/2012:11 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 05/29/20 21:46 67-64-1 Acrylonitrile ND ug/L 50.0 0.90 1 05/29/20 21:46 107-13-1 Benzene ND ug/L 1.0 0.15 1 05/29/20 21:46 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 05/29/20 21:46 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 05/29/20 21:46 75-27-4 Bromoform ND ug/L 1.0 0.62 1 05/29/20 21:46 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 05/29/20 21:46 74-83-9 IK 2-Butanone (MEK) ND ug/L 5.0 3.3 1 05/29/20 21:46 78-93-3 Carbon disulfide ND ug/L 10.0 0.40 1 05/29/20 21:46 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 05/29/20 21:46 56-23-5 Date: 06/09/2020 08:56 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 26 of 238 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus Co Units 2/3 MSW Pace Project No.: 92478136 Sample: 1302-CD-1d Lab ID: 92478136002 Collected: 05/18/20 13:05 Received: 05/19/20 08:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 06/09/2020 08:56 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.23 1 05/29/20 21:46 108-90-7 ND ug/L 1.0 0.49 1 05/29/20 21:46 75-00-3 IK,v1 ND ug/L 5.0 2.3 1 05/29/20 21:46 67-66-3 ND ug/L 1.0 0.39 1 05/29/20 21:46 74-87-3 ND ug/L 5.0 0.26 1 05/29/20 21:46 96-12-8 ND ug/L 1.0 0.41 1 05/29/20 21:46 124-48-1 ND ug/L 2.0 0.26 1 05/29/20 21:46 106-93-4 ND ug/L 1.0 0.46 1 05/29/20 21:46 74-95-3 ND ug/L 1.0 0.29 1 05/29/20 21:46 95-50-1 ND ug/L 1.0 0.26 1 05/29/20 21:46 106-46-7 ND ug/L 5.0 0.54 1 05/29/20 21:46 110-57-6 v1 ND ug/L 1.0 0.27 1 05/29/20 21:46 75-34-3 ND ug/L 1.0 0.34 1 05/29/20 21:46 107-06-2 ND ug/L 1.0 0.24 1 05/29/20 21:46 75-35-4 ND ug/L 1.0 0.29 1 05/29/20 21:46 156-59-2 ND ug/L 1.0 0.25 1 05/29/20 21:46 156-60-5 ND ug/L 1.0 0.19 1 05/29/20 21:46 78-87-5 ND ug/L 1.0 0.30 1 05/29/20 21:46 10061-01-5 ND ug/L 1.0 0.31 1 05/29/20 21:46 10061-02-6 ND ug/L 1.0 0.26 1 05/29/20 21:46 100-41-4 ND ug/L 5.0 0.57 1 05/29/20 21:46 591-78-6 v1 ND ug/L 20.0 12.5 1 05/29/20 21:46 74-88-4 ND ug/L 5.0 3.7 1 05/29/20 21:46 75-09-2 ND ug/L 5.0 4.5 1 05/29/20 21:46 108-10-1 v1 ND ug/L 1.0 0.27 1 05/29/20 21:46 100-42-5 ND ug/L 1.0 0.34 1 05/29/20 21:46 630-20-6 ND ug/L 1.0 0.22 1 05/29/20 21:46 79-34-5 ND ug/L 1.0 0.16 1 05/29/20 21:46 127-18-4 ND ug/L 10.0 1.9 1 05/29/20 21:46 109-99-9 ND ug/L 1.0 0.24 1 05/29/20 21:46 108-88-3 ND ug/L 1.0 0.18 1 05/29/20 21:46 71-55-6 ND ug/L 1.0 0.24 1 05/29/20 21:46 79-00-5 ND ug/L 1.0 0.22 1 05/29/20 21:46 79-01-6 ND ug/L 1.0 0.31 1 05/29/20 21:46 75-69-4 ND ug/L 1.0 0.35 1 05/29/20 21:46 96-18-4 ND ug/L 2.0 1.4 1 05/29/20 21:46 108-05-4 ND ug/L 1.0 0.24 1 05/29/20 21:46 75-01-4 ND ug/L 2.0 0.63 1 05/29/20 21:46 1330-20-7 99 % 70-130 1 05/29/20 21:46 460-00-4 95 % 70-130 1 05/29/20 21:46 17060-07-0 102 % 70-130 1 05/29/20 21:46 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 238 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Sample: Trip Blank Lab ID: 92478353009 Collected: 05/19/20 00:00 Received: 05/20/20 12:55 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrach loroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Date: 06/08/2020 04:58 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 6.2 1 06/02/20 05:31 67-64-1 ND ug/L 50.0 0.90 1 06/02/20 05:31 107-13-1 ND ug/L 1.0 0.15 1 06/02/20 05:31 71-43-2 ND ug/L 1.0 0.34 1 06/02/20 05:31 74-97-5 ND ug/L 1.0 0.26 1 06/02/20 05:31 75-27-4 ND ug/L 1.0 0.62 1 06/02/20 05:31 75-25-2 ND ug/L 2.0 0.62 1 06/02/20 05:31 74-83-9 ND ug/L 5.0 3.3 1 06/02/20 05:31 78-93-3 ND ug/L 10.0 0.40 1 06/02/20 05:31 75-15-0 ND ug/L 1.0 0.22 1 06/02/20 05:31 56-23-5 ND ug/L 1.0 0.23 1 06/02/20 05:31 108-90-7 ND ug/L 1.0 0.49 1 06/02/20 05:31 75-00-3 ND ug/L 5.0 2.3 1 06/02/20 05:31 67-66-3 ND ug/L 1.0 0.39 1 06/02/20 05:31 74-87-3 ND ug/L 5.0 0.26 1 06/02/20 05:31 96-12-8 ND ug/L 1.0 0.41 1 06/02/20 05:31 124-48-1 ND ug/L 2.0 0.26 1 06/02/20 05:31 106-93-4 ND ug/L 1.0 0.46 1 06/02/20 05:31 74-95-3 ND ug/L 1.0 0.29 1 06/02/20 05:31 95-50-1 ND ug/L 1.0 0.26 1 06/02/20 05:31 106-46-7 ND ug/L 5.0 0.54 1 06/02/20 05:31 110-57-6 ND ug/L 1.0 0.27 1 06/02/20 05:31 75-34-3 ND ug/L 1.0 0.34 1 06/02/20 05:31 107-06-2 ND ug/L 1.0 0.24 1 06/02/20 05:31 75-35-4 ND ug/L 1.0 0.29 1 06/02/20 05:31 156-59-2 ND ug/L 1.0 0.25 1 06/02/20 05:31 156-60-5 ND ug/L 1.0 0.19 1 06/02/20 05:31 78-87-5 ND ug/L 1.0 0.30 1 06/02/20 05:31 10061-01-5 ND ug/L 1.0 0.31 1 06/02/20 05:31 10061-02-6 ND ug/L 1.0 0.26 1 06/02/20 05:31 100-41-4 ND ug/L 5.0 0.57 1 06/02/20 05:31 591-78-6 ND ug/L 20.0 12.5 1 06/02/20 05:31 74-88-4 ND ug/L 5.0 3.7 1 06/02/20 05:31 75-09-2 ND ug/L 5.0 4.5 1 06/02/20 05:31 108-10-1 ND ug/L 1.0 0.27 1 06/02/20 05:31 100-42-5 ND ug/L 1.0 0.34 1 06/02/20 05:31 630-20-6 ND ug/L 1.0 0.22 1 06/02/20 05:31 79-34-5 ND ug/L 1.0 0.16 1 06/02/20 05:31 127-18-4 ND ug/L 10.0 1.9 1 06/02/20 05:31 109-99-9 ND ug/L 1.0 0.24 1 06/02/20 05:31 108-88-3 ND ug/L 1.0 0.18 1 06/02/20 05:31 71-55-6 ND ug/L 1.0 0.24 1 06/02/20 05:31 79-00-5 ND ug/L 1.0 0.22 1 06/02/20 05:31 79-01-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 25 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 Sample: Trip Blank Lab ID: 92478353009 Collected: 05/19/20 00:00 Received: 05/20/20 12:55 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Trichlorofluoromethane ND ug/L 1.0 0.31 1 06/02/20 05:31 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 06/02/20 05:31 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 06/02/20 05:31 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 06/02/20 05:31 75-01-4 Xylene (Total) ND ug/L 2.0 0.63 1 06/02/20 05:31 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 06/02/20 05:31 460-00-4 1,2-Dichloroethane-d4 (S) 103 % 70-130 1 06/02/20 05:31 17060-07-0 Toluene-d8 (S) 102 % 70-130 1 06/02/20 05:31 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.2 1 05/30/20 15:13 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 104 % 50-150 1 05/30/20 15:13 17060-07-0 Toluene-d8 (S) 96 % 50-150 1 05/30/20 15:13 2037-26-5 Date: 06/08/2020 04:58 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 26 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 QC Batch: 46847 QC Batch Method: EPA 3005A Associated Lab Samples: 92478353001 QUALITY CONTROL DATA Analysis Method: EPA 6020B Analysis Description: 6020E MET Laboratory: Pace Analytical Services - Atlanta, GA METHOD BLANK: 218181 Associated Lab Samples: 92478353001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 5.0 0.27 06/02/2018:22 Arsenic ug/L 0.42J 5.0 0.35 06/02/2018:22 Barium ug/L ND 5.0 0.49 06/02/2018:22 Beryllium ug/L ND 0.50 0.074 06/02/2018:22 Cadmium ug/L ND 0.50 0.11 06/02/2018:22 Chromium ug/L ND 5.0 0.39 06/02/2018:22 Cobalt ug/L ND 5.0 0.30 06/02/2018:22 Copper ug/L ND 5.0 0.19 06/02/2018:22 Lead ug/L ND 1.0 0.046 06/02/2018:22 Nickel ug/L ND 5.0 0.31 06/02/2018:22 Selenium ug/L ND 5.0 1.3 06/02/2018:22 Silver ug/L ND 5.0 0.28 06/02/2018:22 Thallium ug/L ND 1.0 0.052 06/02/2018:22 Vanadium ug/L ND 10.0 0.71 06/02/2018:22 Zinc ug/L ND 10.0 1.5 06/02/2018:22 LABORATORY CONTROL SAMPLE: Parameter 218182 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 100 101 101 80-120 Arsenic ug/L 100 102 102 80-120 Barium ug/L 100 99.8 100 80-120 Beryllium ug/L 100 101 101 80-120 Cadmium ug/L 100 98.4 98 80-120 Chromium ug/L 100 99.1 99 80-120 Cobalt ug/L 100 99.4 99 80-120 Copper ug/L 100 101 101 80-120 Lead ug/L 100 101 101 80-120 Nickel ug/L 100 98.1 98 80-120 Selenium ug/L 100 100 100 80-120 Silver ug/L 100 100 100 80-120 Thallium ug/L 100 99.9 100 80-120 Vanadium ug/L 100 98.6 99 80-120 Zinc ug/L 100 100 100 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Pace Project No.: Cabarrus Co Unit 1 MSW 92478353 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 218183 218184 MS MSD 92478136014 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L 1.11 100 100 98.5 97.0 97 96 75-125 2 20 Arsenic ug/L 1.5J 100 100 101 97.7 99 96 75-125 3 20 Barium ug/L 13.3 100 100 109 107 96 94 75-125 2 20 Beryllium ug/L 0.13J 100 100 95.9 94.2 96 94 75-125 2 20 Cadmium ug/L 0.13J 100 100 98.1 96.6 98 96 75-125 2 20 Chromium ug/L 11.9 100 100 109 107 97 95 75-125 2 20 Cobalt ug/L ND 100 100 95.2 96.6 95 96 75-125 1 20 Copper ug/L 1.01 100 100 101 99.6 100 99 75-125 1 20 Lead ug/L 0.20J 100 100 100 98.2 100 98 75-125 2 20 Nickel ug/L 7.4 100 100 102 102 94 95 75-125 1 20 Selenium ug/L ND 100 100 97.4 97.2 97 97 75-125 0 20 Silver ug/L ND 100 100 97.7 95.8 98 96 75-125 2 20 Thallium ug/L ND 100 100 99.5 97.9 99 98 75-125 2 20 Vanadium ug/L 4.7J 100 100 102 101 97 96 75-125 1 20 Zinc ug/L 7AJ 100 100 106 103 99 95 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 QC Batch: 46856 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Laboratory: Pace Analytical Services - Atlanta, GA Associated Lab Samples: 92478353002, 92478353003, 92478353004, 92478353005, 92478353006, 92478353007, 92478353008 METHOD BLANK: 218199 Associated Lab Samples: Parameter Matrix: Water 92478353002, 92478353003, 92478353004, 92478353005, 92478353006, 92478353007, 92478353008 Blank Reporting Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 5.0 0.27 06/02/2017:00 Arsenic ug/L ND 5.0 0.35 06/02/2017:00 Barium ug/L ND 5.0 0.49 06/02/2017:00 Beryllium ug/L ND 0.50 0.074 06/02/2017:00 Cadmium ug/L ND 0.50 0.11 06/02/2017:00 Chromium ug/L ND 5.0 0.39 06/02/2017:00 Cobalt ug/L ND 5.0 0.30 06/02/2017:00 Copper ug/L ND 5.0 0.19 06/02/2017:00 Lead ug/L ND 1.0 0.046 06/02/2017:00 Nickel ug/L ND 5.0 0.31 06/02/2017:00 Selenium ug/L ND 5.0 1.3 06/02/2017:00 Silver ug/L ND 5.0 0.28 06/02/2017:00 Thallium ug/L ND 1.0 0.052 06/02/2017:00 Vanadium ug/L ND 10.0 0.71 06/02/2017:00 Zinc ug/L ND 10.0 1.5 06/02/2017:00 LABORATORY CONTROL SAMPLE: Parameter 218200 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 100 102 102 80-120 Arsenic ug/L 100 98.8 99 80-120 Barium ug/L 100 97.9 98 80-120 Beryllium ug/L 100 104 104 80-120 Cadmium ug/L 100 99.0 99 80-120 Chromium ug/L 100 102 102 80-120 Cobalt ug/L 100 101 101 80-120 Copper ug/L 100 101 101 80-120 Lead ug/L 100 99.3 99 80-120 Nickel ug/L 100 99.6 100 80-120 Selenium ug/L 100 89.8 90 80-120 Silver ug/L 100 100 100 80-120 Thallium ug/L 100 98.1 98 80-120 Vanadium ug/L 100 102 102 80-120 Zinc ug/L 100 99.7 100 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 218201 218202 MS MSD 92478353002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 99.0 102 99 102 75-125 3 20 Arsenic ug/L 1.6J 100 100 98.5 102 97 100 75-125 4 20 Barium ug/L 646 100 100 751 768 105 122 75-125 2 20 Beryllium ug/L ND 100 100 80.7 83.3 81 83 75-125 3 20 Cadmium ug/L ND 100 100 94.9 97.5 95 97 75-125 3 20 Chromium ug/L 1.01 100 100 96.8 102 96 101 75-125 5 20 Cobalt ug/L 35.0 100 100 129 133 94 98 75-125 3 20 Copper ug/L 0.78J 100 100 92.6 96.3 92 95 75-125 4 20 Lead ug/L 0.32J 100 100 89.4 93.7 89 93 75-125 5 20 Nickel ug/L 82.6 100 100 172 179 90 97 75-125 4 20 Selenium ug/L 2.9J 100 100 94.0 99.8 91 97 75-125 6 20 Silver ug/L ND 100 100 89.1 92.0 89 92 75-125 3 20 Thallium ug/L 0.086J 100 100 89.5 94.1 89 94 75-125 5 20 Vanadium ug/L ND 100 100 100 104 100 104 75-125 4 20 Zinc ug/L 4AJ 100 100 95.9 99.1 92 95 75-125 3 20 SAMPLE DUPLICATE: 218213 92479476001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Antimony ug/L ND ND 20 Arsenic ug/L ND 1.6J 20 Barium ug/L ND 15.0 10 20 Beryllium ug/L ND 0.70 5 20 Cadmium ug/L ND ND 20 Chromium ug/L ND 1.6J 20 Cobalt ug/L ND 6.5 7 20 Copper ug/L ND 0.47J 20 Lead ug/L ND 0.38J 20 Nickel ug/L ND 5.6 10 20 Selenium ug/L ND ND 20 Silver ug/L ND ND 20 Thallium ug/L ND 0.064J 20 Vanadium ug/L ND 1.5J 20 Zinc ug/L ND 8.8J 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 QC Batch: 544331 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92478353009 METHOD BLANK: 2898823 Associated Lab Samples: 92478353009 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 06/02/20 03:08 1,1,1-Trichloroethane ug/L ND 1.0 0.18 06/02/20 03:08 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 06/02/20 03:08 1,1,2-Trichloroethane ug/L ND 1.0 0.24 06/02/20 03:08 1,1-Dichloroethane ug/L ND 1.0 0.27 06/02/20 03:08 1,1-Dichloroethene ug/L ND 1.0 0.24 06/02/20 03:08 1,2,3-Trichloropropane ug/L ND 1.0 0.35 06/02/20 03:08 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 06/02/20 03:08 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 06/02/20 03:08 1,2-Dichlorobenzene ug/L ND 1.0 0.29 06/02/20 03:08 1,2-Dichloroethane ug/L ND 1.0 0.34 06/02/20 03:08 1,2-Dichloropropane ug/L ND 1.0 0.19 06/02/20 03:08 1,4-Dichlorobenzene ug/L ND 1.0 0.26 06/02/20 03:08 2-Butanone (MEK) ug/L ND 5.0 3.3 06/02/20 03:08 2-Hexanone ug/L ND 5.0 0.57 06/02/20 03:08 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 06/02/20 03:08 Acetone ug/L ND 25.0 6.2 06/02/20 03:08 Acrylonitrile ug/L ND 10.0 0.90 06/02/20 03:08 Benzene ug/L ND 1.0 0.15 06/02/20 03:08 Bromochloromethane ug/L ND 1.0 0.34 06/02/20 03:08 Bromodichloromethane ug/L ND 1.0 0.26 06/02/20 03:08 Bromoform ug/L ND 1.0 0.62 06/02/20 03:08 Bromomethane ug/L ND 2.0 0.62 06/02/20 03:08 Carbon disulfide ug/L ND 2.0 0.40 06/02/20 03:08 Carbon tetrachloride ug/L ND 1.0 0.22 06/02/20 03:08 Chlorobenzene ug/L ND 1.0 0.23 06/02/20 03:08 Chloroethane ug/L ND 1.0 0.49 06/02/20 03:08 Chloroform ug/L ND 5.0 2.3 06/02/20 03:08 Chloromethane ug/L ND 1.0 0.39 06/02/20 03:08 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 06/02/20 03:08 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 06/02/20 03:08 Dibromochloromethane ug/L ND 1.0 0.41 06/02/20 03:08 Dibromomethane ug/L ND 1.0 0.46 06/02/20 03:08 Ethylbenzene ug/L ND 1.0 0.26 06/02/20 03:08 lodomethane ug/L ND 20.0 12.5 06/02/20 03:08 Methylene Chloride ug/L ND 5.0 3.7 06/02/20 03:08 Styrene ug/L ND 1.0 0.27 06/02/20 03:08 Tetrachloroethene ug/L ND 1.0 0.16 06/02/20 03:08 Tetrahydrofuran ug/L ND 10.0 1.9 06/02/20 03:08 Toluene ug/L ND 1.0 0.24 06/02/20 03:08 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 METHOD BLANK: 2898823 Associated Lab Samples: 92478353009 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.25 06/02/20 03:08 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 06/02/20 03:08 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 06/02/20 03:08 Trichloroethene ug/L ND 1.0 0.22 06/02/20 03:08 Trichlorofluoromethane ug/L ND 1.0 0.31 06/02/20 03:08 Vinyl acetate ug/L ND 2.0 1.4 06/02/20 03:08 Vinyl chloride ug/L ND 1.0 0.24 06/02/20 03:08 Xylene (Total) ug/L ND 1.0 0.63 06/02/20 03:08 1,2-Dichloroethane-d4 (S) % 106 70-130 06/02/20 03:08 4-Bromofluorobenzene (S) % 99 70-130 06/02/20 03:08 Toluene-d8 (S) % 101 70-130 06/02/20 03:08 LABORATORY CONTROL SAMPLE: 2898824 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 50.0 100 70-130 1,1,1-Trichloroethane ug/L 50 50.2 100 70-130 1,1,2,2-Tetrachloroethane ug/L 50 48.3 97 70-130 1,1,2-Trichloroethane ug/L 50 50.1 100 70-130 1,1-Dichloroethane ug/L 50 49.3 99 70-130 1,1-Dichloroethene ug/L 50 51.5 103 70-130 1,2,3-Trichloropropane ug/L 50 47.5 95 70-130 1,2-Dibromo-3-chloropropane ug/L 50 49.7 99 70-130 1,2-Dibromoethane (EDB) ug/L 50 50.4 101 70-130 1,2-Dichlorobenzene ug/L 50 51.5 103 70-130 1,2-Dichloroethane ug/L 50 49.3 99 70-130 1,2-Dichloropropane ug/L 50 50.4 101 70-130 1,4-Dichlorobenzene ug/L 50 51.3 103 70-130 2-Butanone (MEK) ug/L 100 110 110 64-135 2-Hexanone ug/L 100 103 103 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 105 105 70-130 Acetone ug/L 100 112 112 61-157 Acrylonitrile ug/L 250 265 106 61-143 Benzene ug/L 50 49.3 99 70-130 Bromochloromethane ug/L 50 54.8 110 70-130 Bromodichloromethane ug/L 50 50.2 100 70-130 Bromoform ug/L 50 49.4 99 70-130 Bromomethane ug/L 50 51.0 102 38-130 Carbon disulfide ug/L 50 51.7 103 68-130 Carbon tetrachloride ug/L 50 50.2 100 70-130 Chlorobenzene ug/L 50 50.8 102 70-130 Chloroethane ug/L 50 34.7 69 37-142 Chloroform ug/L 50 48.2 96 70-130 Chloromethane ug/L 50 43.6 87 48-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 LABORATORY CONTROL SAMPLE: Parameter 2898824 Units Spike Conc. LCS Result LCS % Rec % Rec Limits cis-1,2-Dichloroethene ug/L 50 49.5 99 70-130 cis-1,3-Dichloropropene ug/L 50 49.6 99 70-130 Dibromochloromethane ug/L 50 50.5 101 70-130 Dibromomethane ug/L 50 50.2 100 70-130 Ethylbenzene ug/L 50 46.8 94 70-130 lodomethane ug/L 100 98.0 98 40-130 Methylene Chloride ug/L 50 50.8 102 67-132 Styrene ug/L 50 52.6 105 70-130 Tetrachloroethene ug/L 50 48.7 97 69-130 Tetrahydrofuran ug/L 500 544 109 62-130 Toluene ug/L 50 46.4 93 70-130 trans-1,2-Dichloroethene ug/L 50 49.8 100 70-130 trans- 1,3-Dichloropropene ug/L 50 49.5 99 70-130 trans-1,4-Dichloro-2-butene ug/L 50 37.3 75 35-189 Trichloroethene ug/L 50 50.9 102 70-130 Trichlorofluoromethane ug/L 50 42.9 86 63-130 Vinyl acetate ug/L 100 114 114 55-143 Vinyl chloride ug/L 50 52.6 105 70-131 Xylene (Total) ug/L 150 144 96 70-130 1,2-Dichloroethane-d4 (S) % 96 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 99 70-130 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2898825 MS 2632210041 Spike Parameter Units Result Conc. MSD Spike Conc. 2898826 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 20.7 20.0 103 100 73-134 3 30 1,1,1-Trichloroethane ug/L ND 20 20 21.8 21.5 109 108 82-143 1 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 19.8 19.4 99 97 70-136 2 30 1,1,2-Trichloroethane ug/L ND 20 20 21.8 20.7 109 103 70-135 5 30 1,1-Dichloroethane ug/L ND 20 20 21.8 21.1 109 106 70-139 3 30 1,1-Dichloroethene ug/L ND 20 20 23.2 22.8 116 114 70-154 2 30 1,2,3-Trichloropropane ug/L ND 20 20 19.7 19.3 98 97 71-137 2 30 1,2-Dibromo-3- ug/L ND 20 20 20.0 20.3 100 102 65-134 2 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 20.8 20.7 104 103 70-137 1 30 1,2-Dichlorobenzene ug/L ND 20 20 20.3 20.4 101 102 70-133 1 30 1,2-Dichloroethane ug/L ND 20 20 21.1 20.0 106 100 70-137 6 30 1,2-Dichloropropane ug/L ND 20 20 21.6 21.1 108 106 70-140 2 30 1,4-Dichlorobenzene ug/L ND 20 20 20.5 20.3 103 101 70-133 1 30 2-Butanone (MEK) ug/L ND 40 40 48.6 48.1 121 120 60-139 1 30 2-Hexanone ug/L ND 40 40 44.7 43.3 112 108 65-138 3 30 4-Methyl-2-pentanone ug/L ND 40 40 46.7 44.9 117 112 65-135 4 30 (MIBK) Acetone ug/L ND 40 40 47.6 48.2 119 120 60-148 1 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result Date: 06/08/2020 04:58 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 33 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2898825 2898826 MS MSD 2632210041 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acrylonitrile ug/L ND 100 100 111 111 111 111 64-147 0 30 Benzene ug/L ND 20 20 21.6 21.0 108 105 70-151 3 30 Bromochloromethane ug/L ND 20 20 22.7 22.3 114 112 70-141 2 30 Bromodichloromethane ug/L ND 20 20 21.7 20.9 109 105 70-138 4 30 Bromoform ug/L ND 20 20 19.2 18.6 96 93 63-130 3 30 Bromomethane ug/L ND 20 20 25.0 25.0 125 125 15-152 0 30 Carbon disulfide ug/L ND 20 20 23.4 22.8 117 114 69-149 3 30 Carbon tetrachloride ug/L ND 20 20 23.1 22.1 115 110 70-143 5 30 Chlorobenzene ug/L ND 20 20 21.1 20.6 106 103 70-138 3 30 Chloroethane ug/L ND 20 20 19.3 19.6 97 98 52-163 1 30 Chloroform ug/L ND 20 20 20.9 20.3 105 102 70-139 3 30 Chloromethane ug/L ND 20 20 19.1 18.6 96 93 41-139 3 30 cis-1,2-Dichloroethene ug/L ND 20 20 21.6 21.4 108 107 70-141 1 30 cis-1,3-Dichloropropene ug/L ND 20 20 21.4 20.6 107 103 70-137 4 30 Dibromochloromethane ug/L ND 20 20 19.7 19.7 99 99 70-134 0 30 Dibromomethane ug/L ND 20 20 21.7 21.8 108 109 70-138 1 30 Ethylbenzene ug/L ND 20 20 20.0 19.6 100 98 66-153 3 30 lodomethane ug/L ND 40 40 41.8 42.3 105 106 20-138 1 30 Methylene Chloride ug/L ND 20 20 22.2 22.3 111 111 42-159 1 30 Styrene ug/L ND 20 20 20.9 20.3 104 101 70-135 3 30 Tetrachloroethene ug/L ND 20 20 21.1 20.7 105 104 59-143 2 30 Tetrahydrofuran ug/L ND 200 200 231 228 115 114 70-133 1 30 Toluene ug/L ND 20 20 20.9 20.7 104 104 59-148 1 30 trans-1,2-Dichloroethene ug/L ND 20 20 21.9 21.7 110 108 70-146 1 30 trans-1,3-Dichloropropene ug/L ND 20 20 21.3 20.3 107 102 70-135 5 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 14.8 13.7 74 68 47-135 8 30 v3 Trichloroethene ug/L ND 20 20 22.4 22.3 112 111 70-147 1 30 Trichlorofluoromethane ug/L ND 20 20 21.0 20.8 105 104 70-148 1 30 Vinyl acetate ug/L ND 40 40 47.8 47.2 120 118 49-151 1 30 Vinyl chloride ug/L ND 20 20 24.2 24.0 121 120 70-156 1 30 Xylene (Total) ug/L ND 60 60 60.3 59.2 100 99 63-158 2 30 1,2-Dichloroethane-d4 (S) % 95 103 70-130 4-Bromofluorobenzene (S) % 101 100 70-130 Toluene-d8 (S) % 101 101 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 QC Batch: 544333 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92478353001, 92478353002, 92478353003, 92478353004, 92478353005 METHOD BLANK: 2898831 Matrix: Water Associated Lab Samples: 92478353001, 92478353002, 92478353003, 92478353004, 92478353005 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 06/01/20 16:04 1,1,1-Trichloroethane ug/L ND 1.0 0.18 06/01/20 16:04 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 06/01/20 16:04 1,1,2-Trichloroethane ug/L ND 1.0 0.24 06/01/20 16:04 1,1-Dichloroethane ug/L ND 1.0 0.27 06/01/20 16:04 1,1-Dichloroethene ug/L ND 1.0 0.24 06/01/20 16:04 1,2,3-Trichloropropane ug/L ND 1.0 0.35 06/01/20 16:04 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 06/01/20 16:04 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 06/01/20 16:04 1,2-Dichlorobenzene ug/L ND 1.0 0.29 06/01/20 16:04 1,2-Dichloroethane ug/L ND 1.0 0.34 06/01/20 16:04 1,2-Dichloropropane ug/L ND 1.0 0.19 06/01/20 16:04 1,4-Dichlorobenzene ug/L ND 1.0 0.26 06/01/20 16:04 2-Butanone (MEK) ug/L ND 5.0 3.3 06/01/20 16:04 2-Hexanone ug/L ND 5.0 0.57 06/01/20 16:04 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 06/01/20 16:04 Acetone ug/L ND 25.0 6.2 06/01/20 16:04 Acrylonitrile ug/L ND 10.0 0.90 06/01/20 16:04 Benzene ug/L ND 1.0 0.15 06/01/20 16:04 Bromochloromethane ug/L ND 1.0 0.34 06/01/20 16:04 Bromodichloromethane ug/L ND 1.0 0.26 06/01/20 16:04 Bromoform ug/L ND 1.0 0.62 06/01/20 16:04 Bromomethane ug/L ND 2.0 0.62 06/01/20 16:04 Carbon disulfide ug/L ND 2.0 0.40 06/01/20 16:04 Carbon tetrachloride ug/L ND 1.0 0.22 06/01/20 16:04 Chlorobenzene ug/L ND 1.0 0.23 06/01/20 16:04 Chloroethane ug/L ND 1.0 0.49 06/01/20 16:04 Chloroform ug/L ND 5.0 2.3 06/01/20 16:04 Chloromethane ug/L ND 1.0 0.39 06/01/20 16:04 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 06/01/20 16:04 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 06/01/20 16:04 Dibromochloromethane ug/L ND 1.0 0.41 06/01/20 16:04 Dibromomethane ug/L ND 1.0 0.46 06/01/20 16:04 Ethylbenzene ug/L ND 1.0 0.26 06/01/20 16:04 lodomethane ug/L ND 20.0 12.5 06/01/20 16:04 Methylene Chloride ug/L ND 5.0 3.7 06/01/20 16:04 Styrene ug/L ND 1.0 0.27 06/01/20 16:04 Tetrachloroethene ug/L ND 1.0 0.16 06/01/20 16:04 Tetrahydrofuran ug/L ND 10.0 1.9 06/01/20 16:04 Toluene ug/L ND 1.0 0.24 06/01/20 16:04 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 METHOD BLANK: 2898831 Matrix: Water Associated Lab Samples: 92478353001, 92478353002, 92478353003, 92478353004, 92478353005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.25 06/01/20 16:04 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 06/01/20 16:04 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 06/01/20 16:04 v2 Trichloroethene ug/L ND 1.0 0.22 06/01/20 16:04 Trichlorofluoromethane ug/L ND 1.0 0.31 06/01/20 16:04 Vinyl acetate ug/L ND 2.0 1.4 06/01/20 16:04 Vinyl chloride ug/L ND 1.0 0.24 06/01/20 16:04 Xylene (Total) ug/L ND 1.0 0.63 06/01/20 16:04 1,2-Dichloroethane-d4 (S) % 102 70-130 06/01/20 16:04 4-Bromofluorobenzene (S) % 98 70-130 06/01/20 16:04 Toluene-d8 (S) % 103 70-130 06/01/20 16:04 LABORATORY CONTROL SAMPLE: 2898832 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 52.8 106 70-130 1,1,1-Trichloroethane ug/L 50 53.8 108 70-130 1,1,2,2-Tetrachloroethane ug/L 50 50.7 101 70-130 1,1,2-Trichloroethane ug/L 50 52.7 105 70-130 1,1-Dichloroethane ug/L 50 53.4 107 70-130 1,1-Dichloroethene ug/L 50 55.7 111 70-130 1,2,3-Trichloropropane ug/L 50 51.6 103 70-130 1,2-Dibromo-3-chloropropane ug/L 50 53.0 106 70-130 1,2-Dibromoethane (EDB) ug/L 50 53.6 107 70-130 1,2-Dichlorobenzene ug/L 50 55.6 111 70-130 1,2-Dichloroethane ug/L 50 51.7 103 70-130 1,2-Dichloropropane ug/L 50 52.4 105 70-130 1,4-Dichlorobenzene ug/L 50 55.5 111 70-130 2-Butanone (MEK) ug/L 100 113 113 64-135 2-Hexanone ug/L 100 102 102 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 102 102 70-130 Acetone ug/L 100 119 119 61-157 Acrylonitrile ug/L 250 261 104 61-143 Benzene ug/L 50 52.1 104 70-130 Bromochloromethane ug/L 50 58.2 116 70-130 Bromodichloromethane ug/L 50 54.0 108 70-130 Bromoform ug/L 50 52.2 104 70-130 Bromomethane ug/L 50 58.3 117 38-130 Carbon disulfide ug/L 50 52.8 106 68-130 Carbon tetrachloride ug/L 50 54.7 109 70-130 Chlorobenzene ug/L 50 53.7 107 70-130 Chloroethane ug/L 50 36.6 73 37-142 Chloroform ug/L 50 51.3 103 70-130 Chloromethane ug/L 50 48.0 96 48-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 55 Pace Analytical Services, LLC ® 110 Technology Parkway leac, Analytrcal Peachtree Corners, GA 30092 www.pacolahs.com (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 LABORATORY CONTROL SAMPLE: Parameter 2898832 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,2-Dichloroethene ug/L 50 53.0 106 70-130 cis-1,3-Dichloropropene ug/L 50 53.6 107 70-130 Dibromochloromethane ug/L 50 53.3 107 70-130 Dibromomethane ug/L 50 53.3 107 70-130 Ethylbenzene ug/L 50 50.1 100 70-130 lodomethane ug/L 100 96.0 96 40-130 Methylene Chloride ug/L 50 54.0 108 67-132 Styrene ug/L 50 56.8 114 70-130 Tetrachloroethene ug/L 50 53.6 107 69-130 Tetrahydrofuran ug/L 500 530 106 62-130 Toluene ug/L 50 50.2 100 70-130 trans-1,2-Dichloroethene ug/L 50 54.2 108 70-130 trans- 1,3-Dichloropropene ug/L 50 53.0 106 70-130 trans-1,4-Dichloro-2-butene ug/L 50 79.0 158 35-189 v3 Trichloroethene ug/L 50 55.5 111 70-130 Trichlorofluoromethane ug/L 50 46.8 94 63-130 Vinyl acetate ug/L 100 121 121 55-143 Vinyl chloride ug/L 50 58.3 117 70-131 Xylene (Total) ug/L 150 155 104 70-130 1,2-Dichloroethane-d4 (S) % 97 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 99 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2898833 MS 92478353005 Spike Parameter Units Result Conc. MSD Spike Conc. 2898834 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 20.8 19.8 104 99 73-134 5 30 1,1,1-Trichloroethane ug/L ND 20 20 21.6 20.7 108 104 82-143 4 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 20.1 18.9 100 95 70-136 6 30 1,1,2-Trichloroethane ug/L ND 20 20 21.3 20.7 107 104 70-135 3 30 1,1-Dichloroethane ug/L ND 20 20 21.7 20.3 108 102 70-139 6 30 1,1-Dichloroethene ug/L ND 20 20 23.2 21.8 116 109 70-154 6 30 1,2,3-Trichloropropane ug/L ND 20 20 20.1 19.6 100 98 71-137 2 30 1,2-Dibromo-3- ug/L ND 20 20 20.7 20.1 104 101 65-134 3 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 21.3 20.3 106 102 70-137 4 30 1,2-Dichlorobenzene ug/L ND 20 20 20.7 19.7 103 98 70-133 5 30 1,2-Dichloroethane ug/L ND 20 20 20.8 20.1 104 100 70-137 3 30 1,2-Dichloropropane ug/L ND 20 20 21.7 21.0 109 105 70-140 3 30 1,4-Dichlorobenzene ug/L ND 20 20 21.1 20.5 106 103 70-133 3 30 2-Butanone (MEK) ug/L ND 40 40 48.9 46.3 122 116 60-139 6 30 2-Hexanone ug/L ND 40 40 44.7 41.8 112 104 65-138 7 30 4-Methyl-2-pentanone ug/L ND 40 40 46.7 44.5 117 111 65-135 5 30 (MIBK) Acetone ug/L ND 40 40 49.7 46.8 124 117 60-148 6 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result Date: 06/08/2020 04:58 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 37 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2898833 2898834 MS MSD 92478353005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acrylonitrile ug/L ND 100 100 113 107 113 107 64-147 5 30 Benzene ug/L ND 20 20 21.4 20.4 107 102 70-151 5 30 Bromochloromethane ug/L ND 20 20 22.8 22.2 114 111 70-141 3 30 Bromodichloromethane ug/L ND 20 20 21.6 20.3 108 102 70-138 6 30 Bromoform ug/L ND 20 20 19.3 18.3 97 92 63-130 5 30 Bromomethane ug/L ND 20 20 26.7 25.5 133 128 15-152 4 30 Carbon disulfide ug/L ND 20 20 23.3 22.1 116 110 69-149 5 30 Carbon tetrachloride ug/L ND 20 20 22.5 21.4 112 107 70-143 5 30 Chlorobenzene ug/L ND 20 20 22.8 21.9 114 110 70-138 4 30 Chloroethane ug/L ND 20 20 18.6 17.8 93 89 52-163 4 30 Chloroform ug/L ND 20 20 20.9 20.6 105 103 70-139 1 30 Chloromethane ug/L ND 20 20 19.0 18.4 95 92 41-139 3 30 cis-1,2-Dichloroethene ug/L ND 20 20 21.4 20.6 107 103 70-141 4 30 cis-1,3-Dichloropropene ug/L ND 20 20 21.6 20.4 108 102 70-137 6 30 Dibromochloromethane ug/L ND 20 20 20.2 18.8 101 94 70-134 7 30 Dibromomethane ug/L ND 20 20 21.9 21.3 109 107 70-138 3 30 Ethylbenzene ug/L ND 20 20 19.6 18.8 98 94 66-153 4 30 lodomethane ug/L ND 40 40 40.2 37.1 100 93 20-138 8 30 Methylene Chloride ug/L ND 20 20 22.8 21.7 114 109 42-159 5 30 Styrene ug/L ND 20 20 20.6 19.7 103 99 70-135 4 30 Tetrachloroethene ug/L ND 20 20 20.5 19.3 102 96 59-143 6 30 Tetrahydrofuran ug/L ND 200 200 242 229 121 114 70-133 5 30 Toluene ug/L ND 20 20 20.3 19.7 101 99 59-148 3 30 trans-1,2-Dichloroethene ug/L ND 20 20 22.2 21.0 111 105 70-146 6 30 trans-1,3-Dichloropropene ug/L ND 20 20 21.1 20.3 106 101 70-135 4 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 15.0 14.3 75 72 47-135 5 30 v3 Trichloroethene ug/L ND 20 20 22.8 21.7 114 108 70-147 5 30 Trichlorofluoromethane ug/L ND 20 20 20.7 19.9 104 99 70-148 4 30 Vinyl acetate ug/L ND 40 40 50.0 47.1 125 118 49-151 6 30 Vinyl chloride ug/L ND 20 20 24.0 22.7 120 114 70-156 5 30 Xylene (Total) ug/L ND 60 60 59.4 56.8 99 95 63-158 5 30 1,2-Dichloroethane-d4 (S) % 106 102 70-130 4-Bromofluorobenzene (S) % 100 99 70-130 Toluene-d8 (S) % 102 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 QC Batch: 544334 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92478353006, 92478353007, 92478353008 METHOD BLANK: 2898835 Matrix: Associated Lab Samples: 92478353006, 92478353007, 92478353008 Blank Parameter Units Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 06/02/20 18:42 1,1,1-Trichloroethane ug/L ND 1.0 0.18 06/02/20 18:42 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 06/02/20 18:42 1,1,2-Trichloroethane ug/L ND 1.0 0.24 06/02/20 18:42 1,1-Dichloroethane ug/L ND 1.0 0.27 06/02/20 18:42 1,1-Dichloroethene ug/L ND 1.0 0.24 06/02/20 18:42 1,2,3-Trichloropropane ug/L ND 1.0 0.35 06/02/20 18:42 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 06/02/20 18:42 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 06/02/20 18:42 1,2-Dichlorobenzene ug/L ND 1.0 0.29 06/02/20 18:42 1,2-Dichloroethane ug/L ND 1.0 0.34 06/02/20 18:42 1,2-Dichloropropane ug/L ND 1.0 0.19 06/02/20 18:42 1,4-Dichlorobenzene ug/L ND 1.0 0.26 06/02/20 18:42 2-Butanone (MEK) ug/L ND 5.0 3.3 06/02/20 18:42 2-Hexanone ug/L ND 5.0 0.57 06/02/20 18:42 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 06/02/20 18:42 Acetone ug/L ND 25.0 6.2 06/02/20 18:42 Acrylonitrile ug/L ND 10.0 0.90 06/02/20 18:42 Benzene ug/L ND 1.0 0.15 06/02/20 18:42 Bromochloromethane ug/L ND 1.0 0.34 06/02/20 18:42 Bromodichloromethane ug/L ND 1.0 0.26 06/02/20 18:42 Bromoform ug/L ND 1.0 0.62 06/02/20 18:42 Bromomethane ug/L ND 2.0 0.62 06/02/20 18:42 Carbon disulfide ug/L ND 2.0 0.40 06/02/20 18:42 Carbon tetrachloride ug/L ND 1.0 0.22 06/02/20 18:42 Chlorobenzene ug/L ND 1.0 0.23 06/02/20 18:42 Chloroethane ug/L ND 1.0 0.49 06/02/20 18:42 Chloroform ug/L ND 5.0 2.3 06/02/20 18:42 Chloromethane ug/L ND 1.0 0.39 06/02/20 18:42 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 06/02/20 18:42 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 06/02/20 18:42 Dibromochloromethane ug/L ND 1.0 0.41 06/02/20 18:42 Dibromomethane ug/L ND 1.0 0.46 06/02/20 18:42 Ethylbenzene ug/L ND 1.0 0.26 06/02/20 18:42 lodomethane ug/L ND 20.0 12.5 06/02/20 18:42 Methylene Chloride ug/L ND 5.0 3.7 06/02/20 18:42 Styrene ug/L ND 1.0 0.27 06/02/20 18:42 Tetrachloroethene ug/L ND 1.0 0.16 06/02/20 18:42 Tetrahydrofuran ug/L ND 10.0 1.9 06/02/20 18:42 Toluene ug/L ND 1.0 0.24 06/02/20 18:42 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 39 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 METHOD BLANK: 2898835 Matrix: Water Associated Lab Samples: 92478353006, 92478353007, 92478353008 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.25 06/02/20 18:42 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 06/02/20 18:42 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 06/02/20 18:42 v2 Trichloroethene ug/L ND 1.0 0.22 06/02/20 18:42 Trichlorofluoromethane ug/L ND 1.0 0.31 06/02/20 18:42 Vinyl acetate ug/L ND 2.0 1.4 06/02/20 18:42 Vinyl chloride ug/L ND 1.0 0.24 06/02/20 18:42 Xylene (Total) ug/L ND 1.0 0.63 06/02/20 18:42 1,2-Dichloroethane-d4 (S) % 103 70-130 06/02/20 18:42 4-Bromofluorobenzene (S) % 98 70-130 06/02/20 18:42 Toluene-d8 (S) % 103 70-130 06/02/20 18:42 LABORATORY CONTROL SAMPLE: 2898836 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 48.6 97 70-130 1,1,1-Trichloroethane ug/L 50 48.9 98 70-130 1,1,2,2-Tetrachloroethane ug/L 50 48.1 96 70-130 1,1,2-Trichloroethane ug/L 50 50.3 101 70-130 1,1-Dichloroethane ug/L 50 48.5 97 70-130 1,1-Dichloroethene ug/L 50 50.4 101 70-130 1,2,3-Trichloropropane ug/L 50 48.1 96 70-130 1,2-Dibromo-3-chloropropane ug/L 50 51.5 103 70-130 1,2-Dibromoethane (EDB) ug/L 50 49.9 100 70-130 1,2-Dichlorobenzene ug/L 50 51.5 103 70-130 1,2-Dichloroethane ug/L 50 48.4 97 70-130 1,2-Dichloropropane ug/L 50 49.6 99 70-130 1,4-Dichlorobenzene ug/L 50 51.9 104 70-130 2-Butanone (MEK) ug/L 100 117 117 64-135 2-Hexanone ug/L 100 108 108 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 111 111 70-130 Acetone ug/L 100 121 121 61-157 Acrylonitrile ug/L 250 265 106 61-143 Benzene ug/L 50 48.6 97 70-130 Bromochloromethane ug/L 50 53.1 106 70-130 Bromodichloromethane ug/L 50 50.0 100 70-130 Bromoform ug/L 50 48.1 96 70-130 Bromomethane ug/L 50 49.8 100 38-130 Carbon disulfide ug/L 50 51.7 103 68-130 Carbon tetrachloride ug/L 50 50.8 102 70-130 Chlorobenzene ug/L 50 49.6 99 70-130 Chloroethane ug/L 50 33.5 67 37-142 Chloroform ug/L 50 46.6 93 70-130 Chloromethane ug/L 50 42.8 86 48-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 55 Pace Analytical Services, LLC ® 110 Technology Parkway leac, Analytrcal Peachtree Corners, GA 30092 www.pacolahs.com (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 LABORATORY CONTROL SAMPLE: Parameter 2898836 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,2-Dichloroethene ug/L 50 48.9 98 70-130 cis-1,3-Dichloropropene ug/L 50 50.5 101 70-130 Dibromochloromethane ug/L 50 49.4 99 70-130 Dibromomethane ug/L 50 52.0 104 70-130 Ethylbenzene ug/L 50 46.3 93 70-130 lodomethane ug/L 100 95.5 96 40-130 Methylene Chloride ug/L 50 50.0 100 67-132 Styrene ug/L 50 51.5 103 70-130 Tetrachloroethene ug/L 50 48.6 97 69-130 Tetrahydrofuran ug/L 500 559 112 62-130 Toluene ug/L 50 47.4 95 70-130 trans-1,2-Dichloroethene ug/L 50 49.2 98 70-130 trans- 1,3-Dichloropropene ug/L 50 50.7 101 70-130 trans-1,4-Dichloro-2-butene ug/L 50 40.3 81 35-189 v2 Trichloroethene ug/L 50 52.2 104 70-130 Trichlorofluoromethane ug/L 50 41.7 83 63-130 Vinyl acetate ug/L 100 119 119 55-143 Vinyl chloride ug/L 50 52.5 105 70-131 Xylene (Total) ug/L 150 143 95 70-130 1,2-Dichloroethane-d4 (S) % 95 70-130 4-Bromofluorobenzene (S) % 101 70-130 Toluene-d8 (S) % 100 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2898837 MS 7328261017 Spike Parameter Units Result Conc. MSD Spike Conc. 2898838 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 21.2 21.0 106 105 73-134 1 30 1,1,1-Trichloroethane ug/L ND 20 20 22.8 23.0 114 115 82-143 1 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 19.9 19.9 99 100 70-136 0 30 1,1,2-Trichloroethane ug/L ND 20 20 21.0 21.8 105 109 70-135 4 30 1,1-Dichloroethane ug/L ND 20 20 22.4 22.7 112 114 70-139 2 30 1,1-Dichloroethene ug/L ND 20 20 24.6 24.7 123 124 70-154 0 30 1,2,3-Trichloropropane ug/L ND 20 20 20.5 20.4 103 102 71-137 1 30 1,2-Dibromo-3- ug/L ND 20 20 19.0 20.0 95 100 65-134 5 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 21.5 21.1 107 106 70-137 2 30 1,2-Dichlorobenzene ug/L ND 20 20 19.9 20.7 99 104 70-133 4 30 1,2-Dichloroethane ug/L ND 20 20 21.7 22.1 108 110 70-137 2 30 1,2-Dichloropropane ug/L ND 20 20 22.1 22.5 110 113 70-140 2 30 1,4-Dichlorobenzene ug/L ND 20 20 20.0 20.8 100 104 70-133 4 30 2-Butanone (MEK) ug/L ND 40 40 46.1 47.9 115 120 60-139 4 30 2-Hexanone ug/L ND 40 40 39.7 40.3 99 101 65-138 1 30 4-Methyl-2-pentanone ug/L ND 40 40 42.0 42.7 105 107 65-135 2 30 (MIBK) Acetone ug/L ND 40 40 46.6 49.7 117 124 60-148 6 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result Date: 06/08/2020 04:58 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 41 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2898837 2898838 MS MSD 7328261017 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acrylonitrile ug/L ND 100 100 104 108 104 108 64-147 4 30 Benzene ug/L ND 20 20 21.8 22.3 109 112 70-151 2 30 Bromochloromethane ug/L ND 20 20 23.4 24.1 117 121 70-141 3 30 Bromodichloromethane ug/L ND 20 20 21.9 22.3 110 111 70-138 2 30 Bromoform ug/L ND 20 20 19.0 19.4 95 97 63-130 2 30 Bromomethane ug/L ND 20 20 23.7 24.8 119 124 15-152 4 30 Carbon disulfide ug/L ND 20 20 22.1 22.0 110 110 69-149 0 30 Carbon tetrachloride ug/L ND 20 20 23.2 24.1 116 120 70-143 4 30 Chlorobenzene ug/L ND 20 20 21.4 21.5 107 108 70-138 1 30 Chloroethane ug/L ND 20 20 21.7 21.3 109 107 52-163 2 30 Chloroform ug/L ND 20 20 21.5 22.4 108 112 70-139 4 30 Chloromethane ug/L ND 20 20 19.1 20.1 96 100 41-139 5 30 cis-1,2-Dichloroethene ug/L ND 20 20 22.6 22.6 113 113 70-141 0 30 cis-1,3-Dichloropropene ug/L ND 20 20 21.0 21.8 105 109 70-137 4 30 Dibromochloromethane ug/L ND 20 20 20.1 20.9 101 105 70-134 4 30 Dibromomethane ug/L ND 20 20 21.4 22.6 107 113 70-138 5 30 Ethylbenzene ug/L ND 20 20 20.3 20.4 101 102 66-153 1 30 lodomethane ug/L ND 40 40 31.5 36.6 79 92 20-138 15 30 Methylene Chloride ug/L ND 20 20 23.3 23.9 117 119 42-159 2 30 Styrene ug/L ND 20 20 20.7 21.1 103 105 70-135 2 30 Tetrachloroethene ug/L ND 20 20 21.5 20.8 108 104 59-143 4 30 Tetrahydrofuran ug/L ND 200 200 210 217 105 109 70-133 3 30 Toluene ug/L ND 20 20 21.2 21.5 106 107 59-148 1 30 trans-1,2-Dichloroethene ug/L ND 20 20 23.0 23.0 115 115 70-146 0 30 trans-1,3-Dichloropropene ug/L ND 20 20 20.7 21.7 103 109 70-135 5 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 14.0 13.5 70 67 47-135 4 30 v3 Trichloroethene ug/L ND 20 20 22.9 23.9 114 119 70-147 4 30 Trichlorofluoromethane ug/L ND 20 20 22.9 23.3 115 116 70-148 2 30 Vinyl acetate ug/L ND 40 40 41.7 43.3 104 108 49-151 4 30 Vinyl chloride ug/L ND 20 20 25.1 26.0 126 130 70-156 3 30 Xylene (Total) ug/L ND 60 60 61.2 61.1 102 102 63-158 0 30 1,2-Dichloroethane-d4 (S) % 103 101 70-130 4-Bromofluorobenzene (S) % 103 101 70-130 Toluene-d8 (S) % 99 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 42 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 QC Batch: 544006 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92478353001, 92478353002, 92478353003, 92478353004, 92478353005, 92478353006 METHOD BLANK: 2897313 Matrix: Water Associated Lab Samples: 92478353001, 92478353002, 92478353003, 92478353004, 92478353005, 92478353006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.2 05/29/20 16:15 1,2-Dichloroethane-d4 (S) % 99 50-150 05/29/20 16:15 Toluene-d8 (S) % 100 50-150 05/29/20 16:15 LABORATORY CONTROL SAMPLE: 2897314 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 20.6 103 70-130 1,2-Dichloroethane-d4 (S) % 100 50-150 Toluene-d8 (S) % 100 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2897315 2897317 MS MSD 7328261019 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 19.6 20.7 97 102 50-150 5 30 1,2-Dichloroethane-d4 (S) % 98 97 50-150 30 Toluene-d8 (S) % 97 98 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 43 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 QC Batch: 544309 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92478353007, 92478353008, 92478353009 METHOD BLANK: 2898746 Matrix: Water Associated Lab Samples: 92478353007, 92478353008, 92478353009 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.2 05/30/20 13:55 1,2-Dichloroethane-d4 (S) % 105 50-150 05/30/20 13:55 Toluene-d8 (S) % 97 50-150 05/30/20 13:55 LABORATORY CONTROL SAMPLE: 2898747 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 19.5 98 70-130 1,2-Dichloroethane-d4 (S) % 104 50-150 Toluene-d8 (S) % 98 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2898748 2898749 MS MSD 92478136012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 20.2 18.5 99 91 50-150 9 30 1,2-Dichloroethane-d4 (S) % 109 105 50-150 30 Toluene-d8 (S) % 98 96 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALIFIERS Project: Cabarrus Co Unit 1 MSW Pace Project No.: 92478353 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. WORKORDER QUALIFIERS WO: 92478353 [1] Units 2/3, 1, and C&D all include indentical CD-1s and CD-1d data; charge only once [2] Facility Permit ID: 13-02; sample ID "1302-"well ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A complete list of accreditations/certifications is available upon request. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2020 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 55 leAnalytical" www.pacolahs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Cabarrus Co Unit 1 MSW 92478353 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92478353001 1302-MW-5 92478353002 1302-M W -7 92478353003 1302-MW-8A 92478353004 1302-MW-10 92478353005 1302-M W -11 92478353007 1302-SW-1 92478353008 1302-SW-2 92478353001 1302-MW-5 EPA 3005A 46847 EPA 6020B 46854 92478353002 1302-MW-7 EPA 3005A 46856 EPA 6020B 46858 92478353003 1302-MW-8A EPA 3005A 46856 EPA 6020B 46858 92478353004 1302-MW-10 EPA 3005A 46856 EPA 6020B 46858 92478353005 1302-MW-11 EPA 3005A 46856 EPA 6020B 46858 92478353006 1302-Dup1 EPA 3005A 46856 EPA 6020B 46858 92478353007 1302-SW-1 EPA 3005A 46856 EPA 6020B 46858 92478353008 1302-SW-2 EPA 3005A 46856 EPA 6020B 46858 92478353001 1302-MW-5 EPA 8260D 544333 92478353002 1302-MW-7 EPA 8260D 544333 92478353003 1302-MW-8A EPA 8260D 544333 92478353004 1302-MW-10 EPA 8260D 544333 92478353005 1302-MW-11 EPA 8260D 544333 92478353006 1302-Dup1 EPA 8260D 544334 92478353007 1302-SW-1 EPA 8260D 544334 92478353008 1302-SW-2 EPA 8260D 544334 92478353009 Trip Blank EPA 8260D 544331 92478353001 1302-MW-5 EPA 8260D Mod. 544006 92478353002 1302-MW-7 EPA 8260D Mod. 544006 92478353003 1302-MW-8A EPA 8260D Mod. 544006 92478353004 1302-MW-10 EPA 8260D Mod. 544006 92478353005 1302-MW-11 EPA 8260D Mod. 544006 92478353006 1302-Dup1 EPA 8260D Mod. 544006 92478353007 1302-SW-1 EPA 8260D Mod. 544309 92478353008 1302-SW-2 EPA 8260D Mod. 544309 92478353009 Trip Blank EPA 8260D Mod. 544309 Date: 06/08/2020 04:58 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 46 of 55 (wA) �I selduns w is M I Pelves A,onn (NIA) 901 uo PeNexa (N/A) a jmo IoePIeaM CIE, G21MO I •' rE ©-.■mumnammummm oil t¢1;Y • kM 1pill p � a (dN00.0 9V110•'D) 3dA131dYM (wI o sem pm •+s) 3000 amn uw I S Q J fi a � 8 #W311 ©©W©W Page 47 of 55 Document Name: Wp# : 92478353 Sample Condition Upon Recelpt(SCUR) aC� Card Document No.: PH: MP Due Date: 06/08/20 F-CAR-0.033-Rev.06 CLIENT: 26—CDM laboratory receiving samples: Asheville ❑ Edens,, i Greenwood U Huntersvil.a I„ .•.•v.8••,.., •••••••••.••••�••••ou Client Name: C i�l'� sfft -h - g1-eI "h- Courie►: ❑F Ex PS LISPS CRe ❑ Commercial ace ❑Other: Custody Seal Present? [_-]Yes D Seals Intact? ❑Yes ;0/ �. Z�. �� Dste/laltieb Person Exemming Contents: Packing Materlal: ❑Bubble Wrap Bubble sags ❑None ❑ Other Thermometer: 92TTvpeofIcs: �M►at 0Blue ❑ IR Gun ID: 061 Cooler Tamp (•C): J'�) 1 1ricdon Factor: Add/Subtract ('C) +0.1 i Cooler Temp Corrected •15 ('C O � ` 3 USDA R egulated Soll ( N/A�, water sample) Did samples originate In a quarantine zone within the United States: CA, NY, or SC (check maps)? BIologWI Tlssite F en? ❑Yes ONO /A ❑mane Temp should be above freezing to-e•C ❑Samples out of temp criteria. Samples an Ice, cooling process has begun old samples originate from a knelgn source llntematlonally, Yes LINO muuamenauranand ruerw mw►r uTea LJ.w Comments/Dlacre Chain of Custody Present? Yn No QNJA 1. Sam les Arrived within Hold Time? K N/A 2. Short Hold Time Analysis Icn fir. Yes n A 3. Rush Turn Around Time R uested? Yes KAYo QNIA 4. Sufficient Volume? es 01Y. N A S. Correct Containers Used? ❑mo ❑N/A -Pace Containers Used? cs No NIA 6. Containers Intact? Dissolved ana s: Samples Field Filtered? ❑Y No /A B. 9. -Includes Date/nme/lO/AnalySis Matrbl Vv Headspace In VOA Vials >5-6mm)? Y /A 10. Trip Blank Presents &0el ❑No 13N/A Trip Blank Custody Seals Presets? a 13No N/A 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of spilt containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Date/fime: Project Manager SCURF Review: Project Nlsneger SRF Review: Date: Date: field Data Required? ❑Yes ❑No Page 48 of 55 Total Well Depth: �a• ft Static Water Level: i ft Height of Water Column: °�° 7 ft Document Name: Field data Sheet Document Numbix: F-CAR-FLD-001-rev.03 Name and Affiliation (Sampler(s): &" Q� Q Name and Affiliation (Inspector): . d o Well Information WPH iD- Kw 'WPII Unrkarl- Well Diameter: Construction: Multi Factor': 0. 1b,3 r(Radius/12)2 x 3.14 x 7.481 Casing Volume: 3.3 f gallons Cal. 3 Volumes: /0:0 gallons Date Issued: March 8, 2019 Page: 1 of f eg Authority: Pace Huntersviile Quality. Office . a"f 1". it' f�n�'�� Mira o M Data Sheet Review: Date: NO / Flushmount ) :eel/Stainless Steel) Pump Intake: - Et Purge Information Date Purged: / I `6_ _/ 00 Start: ! o9.0 Finish: 05S Purge Rate: Purging Method: fql fer Total Volume'Purged: ( on /mis/L) Sasnvlin¢ information Date Collected:4'5-, _ /11 1/ Q o Time Collected: (a0C] (am/0 Sampling Equipment Used: OQ1(er Instrument IDN-cm Bottle Type Preservation Analysis Required Field Measur tnent Observations Sample Temp (°C): Time: ) ®� Turbidity (ntu): 5,+ Time: ) a0O Diss Oxy (mg/L): off'• 9 Time: Fe 2+ mg/L: — Time:: Specific Cond. (uS): 1 -7$ Time: Res. Cl m L L . Time:. ( g/ y(µg/) Sample pH (s.u.): 4o - �'. Time: Odor: 'PUn Cn -t-- Time: ReDox (mV): 116 Time: Appearance: q4 W-le"Time: ReDox (EH vaIue):YSI ProPlus +200mV 3. is Other: Time: General/Weather Observations: . r (sunny/cloudy/ airi. Temp.(°F) Wind 0 ` (mph) Sampler Signature:7;4&1Date: l Stabilization Test Spec' Volume Time Purged Temp. Diss Oxy. Cond . pH (s.u.) ReDox Turbidity removed Water level Other (°C) (mg/L) (u5) (mV) (rttu) g�oa mis/ (ft) L p I�, S `i.`i 9!3 G -3.3.4 lloQ `.l�'� 3.3 I100 4 Page 49 of 55 Document Name: Field data Sheet Document Number: F-CAR-FLD-001-rev.03 Field Data Sheet Name and Affiliation (Sampler(s):_&g&- PCK-t Name and Affiliation (Inspector): . a Well Information WelliD: Well Locked: Well Diameter: . el I Total Well Depth: i ° 957 ft Static Water Level: ? ft Height of Water Column: 20 • ft Construction: Date Issued: March 8, 2019 page: 1 of _D Issuing Authority: Pace Huntersville Quality. Office . ject #: Grevs G. if 2 /(*v of o Data Sheet Review: Date: r) rlw), j ,Mu NO / Flushmount ) Steel) Multi Factor'`:a 163 [ (Radius/12)2x 3.14 x 7.481 Casing Volume: 3:3 gallons. Cal. 3 Volumes: `. gallons Pump Intake: . ft a U rA A 6 210 AM Purge Information Date Purged: Start: Finish: N 5b Purge Rate: Purging Method:_ B Total Volume Purged: )0 aIlons1240,13 $ �� Sampling Information Date Coliecfed: _ . _ / il/ D Time Collected:_ O o 40pm) Sampling Equipment Used:_ 8rke_0 ear--_ _ Instrument ID:_ VS-f% ewe i'u4 f c'a o7o'cto 'TPW e r� Bottle Type Preservati6n Analysis Required A Oil . Field Measur tnenit Observations Sample Temp (°C): Time: ) OI Turbidity (ntu): P _ Time: �060 Digs Oxy (mg/L): a �_ Time: Fe 2+ mg/L: y Time: Specific Cond. (uS): a�-3(P Time: Res. Cl (mg/L)/(µg/L): "' Timer Sarftole pH (s.u.): (Q `� Time: Odor: Ynu„ ReDox (mV): p Time: Appearance: Nk z V Pj ('Ae Time: ReDox (EH value):YSI ProPlus +200rnV Other: Time: General/Weather Observations_. (sunny/ oudy rainy) Temp.L-Y—(7) Wind (mph) Sampler Signature: "t"L Date. c Stabilization Test Time Purged Temp. (°C) Dias Oxy. (mg/L) Spec. Cond. pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed allo /mis/ Water level (ft) Other. 143a 1,0. �s �r 3,Dr3 45-a.$ 3? .._ `31.11 a3q.(0 Page 50 of 55 a1z'" 5M J Document Name: Field data Sheet Document [Number: F-CAR-FLD-001-rev.03 Field Data Sheet O hc.,,.J Air Name and Affiliation (Sampler(s):. Name and Affiliation (Inspector): 9 - Well Information Well ID: PAW Well Diameter: . oil Total Well Depth: a 5 ft Static Water Level: t!'.ci�' ft Height of Water Column: C) I -a ft Well Locked: Construction: Date Issued: March 8, 2019 Page: 1 of 1 Issuing Authority: Pace Huntersville Quality. Office eject #: u,5 111J a y o� ii„t 0 Data Sheet Review: Date: V NO / Flushmount ) Stainless Steel) Multi Factor': 0.-. i �, r(Radius/12)2 x 3.14 x 7.48] Casing Volume: -3 a gallons. Cal. 3 Volumes: J Q . 3S gallons Pump Intake: - ft Purge Information Date Purged: 5 / 1 ; /.-JP_ Start : _ PS o1 S Finish: l SS5 Purge Rate: 1'urgingMethod: lBcxy_ tr" Total Volume Purged: "' gallon mis/L) Sampling Information Date Collected: 5? / A `A / Time Collected: 0 i I S �pm) Sampling Equipment Used: _52 ui I CC Instruniient ID:. __5T- eLqRi4,S *to ao 7 LM Bottle Type Preservatidn Analysis Required It y Nn%I:QA V_ Field Measuretnerit Obbservations Sample Temp (°C): V • Time: 0 15 Turbidity (ntu): . �` w Time: ®1 15- Digs Oxy (mg/L): Time: Fe 2+ mg/L: "" Timer Specific Cond. (us): Time: Res. CI (mg/L)/(µg/L): Time:. Sample pH (s.u.): (Ss - Time: Odor: ime: ReDox (mV): 195o Time: Appearance: P� Time: _ ReDox (EH value):YSI ProPlus +200mV qS , 0 Other: Time: General/Weather Observations;_p_- (sunny/cloudy/ ain Temp.(°F) Wind 5" lb(mph) Sampler Signature: Date: Stabilization Test Time Purged Temp. (°C) Diss Oxy. (mg/L) Spec. (u5) Cond. pH (s.u.) ReDox (MV) Turbidity (ntu) Volume removed allo /mis/ Water level (ft) Other 65 50 1 S• 15 `i 3S'7. AL A 30-4 15 - 3 .0 Page 51 of 55 Document Name: Field data Sheet Date Issued: March 8, 2014 Page: I of Document [Number: F-CAR-FLD-001-rev.03 1 --- - - Issuing Authority: Pace Huntersville Quality, . Office . Field Data Sheet Client 1. Ivi _Location: (OrXQJ , l� _Project #: `lt�rrrr��i1rtJ mgld �2o Name and Affiliation (Sampler(s):_ P� — �GL�L� Field Data Sheet Review: Name and Affiliation (inspector): . Well Information Well ID: MUJ'-. )Q Well Diameter: ` Total Well Depth: 3 5."5-(z> ft Static Water Level: `3 �09 it Height of Water Column: a-7L Lj _7 ft Well Locked: Construction: Date: ud-A-�O�-o NO / Flushmount ) Steel) Multi Factor-; a_ 1 � 3 [(Radius/12)2 x 3.14 x 1.48). Casing Volume: '1. q T gallons, Cal. 3 Volumes: J S, q gallons Pump Intake: "" !•t Purge Information Date Purged: 5 / 15 start: 1315. ^ Finish. (33Ci Purge Rate: Purging Method:_Rja'% I!J)C _---Tot alVolume'Purged: lI (alto s/mis/L) Sampling Information Date Collected:. / } 9j/ Time Collected: (In pm) Sampling Equipment Used: Cr Instrument ID; Y_'= f'rs pik I W0007N Bottle Type Preservati6n Analysis Required At)v-) �- Field Measuretnerits/Observations Sample Temp (°C): Time- DO— Turbidity (ntu): q Time: 1 a U Digs Oxy (mg/L): 1 Time: I Fe 2+ mg/L:. "` - Time: Specific Cond. (uS)Time: , Res- Cl (mg/L)/(µg/L); Time:. Same' le pH (s.u.): �n. -7 Time; Odor: ?,,nzxc -i � Time: ReDox (mV): , I e Time: Appearance: Ha .�: ,, is • Time- ReDox (EH value):YSI ProPlus +200niV 11 r :3 Other: �" Time; General/Weather Observations: (suriny/cloud /rainy Temp.(0�4 (OF) Wind C}_ T (mph) Sampler Signature: Date: S� Stabilization Test Time Purged Temp. ( q Digs Oxy. (rng/L-) Spec' tom) . pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed a o - mis/ Water level (ft) Other D 16. to 1.3 IS93 , 7 — qq, S 473 9- t356 1 Page 52 of 55 I Document Name: Field data Sheet Date Issued: March 8, 2019 Page: 1 of Issuing Authority: Pace Huntersvilte Quality, Document Number; F-CAR-FLD-001-rev.03 Office Field Data Sheet Clienf: location: CQnCINC�I d� Ca Project#: a,"'W3 60, Lf 6/try - .my do,?o Name and Affiliation (Sampler(s):�� "'` �° Field Data Sheet Review: Name and Affiliation (Inspector): ------- Well Information Well ID: i~'i l l Well locked: Well Diameter: � Total Well Depth: Static Water Level: 69 it Height of Water Column: i- L1 0 ft Construction: Date: By: / NO / Flushmount ) Steel) Multi Factor'`: D "�0-3 r(Radius/12)2 x 3.14 it 7.481. Casing Volume: 3� 16 gallons. Cal. 3 Volumes: q, q q gallons Pump Intake: (t Purge Information Date Purged: / 15 / ;)O Start: P SO Finish. l "� _ Purge Rate:_ Purging Method:15G�t r _ Total Volume Purged: Jd' _ gallon /mIs/l) Sampling Information Date Collected:. � / )� / do Time Collected: AWO abm) Sampling Equipment Used: �A:���' Instrument ID: Vra Sao /;'1:—a7-P ,7f sc s Bottle Type Preservation Analysis Required ADD 1 1 i x Field Measurement Observations Sample Temp (OC): [ s Time: 10 Turbidity (ntu): --- Time: ,0 q O Digs Oxy (mg/L): e c� Time: Fe 2+ mg/L: Time:. Specific Cond. (uS): i 5 g Time: Res. Cl (mg/L)/(µg/L): Time:. Sample pH (s.u.): _ " ( 4 , Time: Odor: Time: ReDox (mV): I d. to Time: Appearance: C( ear �-' `f �l`�ime: ReDox (EH value):YSI ProPlus +200rnV 0 f a 0 Other: . Time: General/VVeather Observations: . (sunny/cloud)Einy) emp.-�t(°F) Wind S- /m (mph) Sampler Signature: _ + �i - Date: ' / `/ ` .2 - Stabilization Test Time Purged Temp. (°C) Digs Oxy. (mg/L) Spec. Eus) • pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed alto mis/ Ll Water level (ft) Other jis , 15.j I•S � ti Ia�.PL Qjq, /�d u3y�.. `f1? 6,.3 -31-5- 39i,!i- 4a,S Page 53 of 55 Document Name: Field data Sheet Date Issued: March 8, 2019 Page: 1 of C2 S P-CAR-Fi D-001-rev.03 Issuing Authority; Pace Huntersville Quality OfficeNum6Par: Office . Field Data sneer Name and Affiliation (Sampler(s): C-M 'PCLW- Name and Affiliation (Inspector): Well Information Well ID: sW11 Well Diameter: Total Well Depth: ft Static Water Level:- ft Height of Water Column: ft #: CoLp UW a �Z026 Data Sheet Review: Date: Q fl -n, By: Well Locked: ( t ) Consttuction: (PVt jSieeig a*!n ess Steel) Multi Factor*: ' (`(Radius/12)2 x 3.14 x 7.481. Casing Volume: '�— gallons. Cal. 3 Volumesgallons Pump Intake: ft Purge Information Date Purged: / / Start:-- Finish: Purge Rate: 10Y Purging Method: __TotalVolume•Purged: (gallons/mis/L) SaMling Information Date Collected;_O/ 262D Time Collected: 157,0 (am Sampling Equipment Used: C-*'O)P Instrument ID: Bottle Type Field Measuretnents/Observitions Preservati6n Analysis Required IdG Not °_ Voc 1. N Plowam Sample Temp (OC): 110-10 Time: sl 2A` Turbidity (ntu): Time: 15� Diss Oxy (mg/L):_ S 19 - Time: IS26 Fe 2+ mg/L: Time:. Specific Cond. (us): 400.3 Time:. 1520 Res. Cl (mg/L)/(µg/L): "' Time:. CQSjf9 - Sample pH (s.u.): Time: 1520 Odor: . ND Time: _152-0 - ReDox(mV): —184 Time: 1520 Appearance:_LtjWwiAnus Time: 1S2a ReDox (EH value);YSI ProPlus +200xnV . 0 Other: `�^ Time: ` General/Weather Observations: ` W _- _ {suriny/cloudy sin Temp. (0'( (°F) Wind S (mph) Sampler Signature SFaihli�aFinTt Tocf -------------- Time Purged Temp. o ( C) Diss Oxy. (mg/L) Spec. Con Cond. pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/mis/ L Water level (ft) Other Page 54 of 55 Document Name: Field data Sheet Document Number. F-CAR-FLD-001-eev.03 Issuing Date Issued: March 8, 2D19 Paze: 1 of! Office - Name and Affiliation (Sampler(s) Name and Affiliation (Inspector): Al 19 Well Information y Well ID: S L'i ` Well Diameter: Total Well Depth: ft Static Water Level: ft Height of Water Column: ft �c Project #: 6,%6n(f u 5- eC, i- Data Sheet Review: Date: p�a I-,)-nO BY vc Well Lacked: {<S / lal©� Flushmo� Construction: (P-VCfSteeltStaiiess tWl) Multi Factor': r(Radius/ 12)2 x 3.14 x 7.481 Casing Volume: gallons. Cal. 3 Volumes: gallons Pump Intake- ft Purge Iiiforma.tion Date Purged. Start: Finish: -Purge Rate: Purging Method:' Total Volume Purged: — (gallons/mis/L) Sampling Information Date Collected: 0 Time Collected: 0 `y � �m pm) Sampling Equipment Used: `—' Instrument ID: 5 - Bottle Type Preservation Analysis Required vo . - Field Measurement Obsery #ions _ Sample Temp (oq- Time: 0'130 Turbidity (ntu): 10 Time: Dins Oxy (rng/L):_ ? _ Time: 0 3 Q Fe 2+ mg/L: Time: Specific Cond. (6): 3.7 Time: 0q3 0 Res. Cl (mg/L)/(pg/L): Time:. Sample pH (s.u.): • V Time: 0 i 3 G - Odor: ,(44 Time: 09 36 ReDox (imV): Time: ' 0 Appearance: C�av ,pia+? • ime: 0�/ ReDox (EH value):YSI ProPlus +200mV `/ Other: Time: GeneraV/ Veather Observations: 5. 9 61/ % e/ S 13 57-0 (sunn�rainy) Temp.-6-q-('F) Wind�(mph) Sampler Signature: Date: Time Purged Tern (°C) Dins Ox (mg/L.) Spec. (uS} PH (s.u.) ReDox (mv) Turbidity (ntu) Volume removed (gallons/mrs/ Water level (ft) Other e Page 55 of 55 Document Name: Field data Sheet Date Issued: March 8, 2019 Page: 1 of 91, —'' Sr,E AnW34XX Issuing Authority: Pare Huntersville Quality, Document Number: F-CAR-FLD-001-rev.03 Office Field Data Sheet ' - Clienf: CT)M Sm _ka Location: K /J C Project #: CCA ix— �,S C 0 LF C4-D � a� Name atld Affiliation (Sampler(s): h Field Data Sheet Review: Name.and Affiliation (Inspector): l Date: OS -2.2- 20 By: C�f Well Information Well ID: C b - 15 Well Locked: YE / NO / Flushmount) ' Well Diameter: C' _ Construction: (6t/Steel/Stainless Steel) Total Well Depth: ft Muni Factor*; 0,163 r(Radius/ 12)2 x 3.14 is 7.48] Static Water Level: -), �. 5 �`{ ft Casing Volume: ) ' �a gallons. Height of Water Column: ft Cal. 3 Volumes: gallons Pump Intake: Purge. Information Date Purged, (IS- 17 /2c p Start: 1 00 Finish: `-ll 15 . Purge hate: Q r n U (Y � Purging Method: Si a d ri'str 2 vv c , Total Volume Purged: _ ) 4 Q O (gallons/eL) Sampling Information Date Collected: g5_ / l,9/_,), Ca Time Collected: 1 4-1 a-O (am/' m Sampling Equipment Used: 75(c 4 e&Acn� :pstruritent ID: ti I M ti cco�i� _;0 q Bottle Type ireservati�n Analysis Required Field Measurements/Observations Sample Temp (oq, ,3 Time; f Q Turbidity (ntu): Time: 1�:00 Dins Oxy (mg/L): 3 Time: 1 `� aQ Fe 2+ mg/ L: rJ D Time: 1 Ur3r Specific Cond. (uS): Time: 1 `1 d Res. Cl (mg/L)/(µg/L): Time:. SamplepH(s.u.): Time: Odor: N1r) _Time: ReDox (mV): Time: f `'t'Q Appearance: _ Inc' Time: ReDox (EH value):YSI ProPlus +200mV L6q Other: Time: General/Weather Observations: . I/ — — . (sunny/Lqafrainy) Ternp. ('F) Wind (r Sampler Signature Stabilization Test Time Temp. Diss Oxy. Spec. Co . pH (s.u.) ReDox Turbidityremoved Volume Purged (°C) (mg/L) S (mV) (ntu) (gallons/ Is �1 r 114 .a 4, 122.0 r31'3 a kOt .a 3 o a a. � Page 2 09.of 238 9ceAnalyllm ii Client: GI) rr) 5 r1q) Location: -Kan c\ck Do kS'S AJC- I Document Name: Field Data Sheet Document Number: F-CAR-FLD-001.rev.03 Project: Ca(AcvLA-3 COLE CID MglOa o Well ID: Gig Document issued: March 8, 2019 Page?V?L_ Issuaing Authority; Pace Huntersville Quality Office xkre-11, Df Arna U-1 mt3It[P.hCatkM Fwboe -1 _6 2-5 0.1080 0.16.3,0 4 OA,530 Temp. OC) Spec. Cond. (us)��■�rs■�■�■�r� Turbidity (ntu) Now, I Water level (ft) circle one ■ram Page 210 of 238 Document Name: Field data Sheet Date Issued: March 8, 2019 Pa • I of �r Issuing Authority: Pace Huntersville Quality. f Document Number: F-CAR-FLD-001-rev.03 Office . Field Data Sheet Client: GDNti SEn;kh Location: kk�j;<^ N1, Project#: Grlboyrr o LF (,tb Mky 2o2D Name and Affiliation (Sampler(s): MEp l "cp Field Data Sheet Review: Name and Affiliation (Inspector): NA Date: O Z2 Lo By: f `„� Well Information Well ID: G b ` Well Locked: / NO / Fluslunount) ' Well Diameter: `_ Construction: Steel/Stainless Steel) Total Well Depth: 5 2 Z 1 ft Multi Factor*: O U 3 r(Radius/12)2 X 3.14 X 7.4s] Static Water Level: 2-.4, l Height of Water Column: Z ° �3 ft Casing Volume: 5- 7 gallons. Cal. 3 Volumes- ' ! 3 , -1 1 gallons Pump Intake: 50 ---it Purge Information Date Purged: Stdrt : I. 3 5 Finish: ] 3 00 Purge Rate: ! 2 L Purging Method: 5Vc, P��p Total Volume'Purged: fl o () (gallons&s/L) Sampling Information Date Collected: 5 / Time Collected: 1 3 DS (am/,& Sampling tquipmentUsed:.--- C�zri sA kk-ic_ Pv w C Instruritent 1D: 7 5l 4 o.1G 1p [ TPLo 41- .SS3 ? Bottle Type Preservation Analysis Required APP I - Field MeasurementsDbsery lions Sample Terilp (°C): ZO `l Time: 13 Q 5 Turbidity (ntu): ..D Time:" l 05 Digs Oxy (mg/L): `� Time: Fe 2+ mg/L: I`I Time:. Specific Cond. (uS): l 1 % - l Time: Res. Cl (mg/L)&g/L): — Time:. Sample pH (s.u.): - Z. Time: Odor: 1J b Time: ReDox (m.V): 3l S Time: [--: Appearance: e 1 e c, Time; ReDox (FH value):YSI ProPlus +200riLV Other: Time: General/Weather Observations: . (sunny/ Sampler Signature Stabilization Test y/rainy) Temp. -7.3 (°F) Wind 3 (mph) Spec' Volume Time Temp. Dtss Oxy. pH (s.u.) ReDox Turbidity remove Water Other Purged (°C) (mg/L) S) (mV) (ntu) (gallons/1 level (ft) 12�D J.a�'3 a.Lu 11y.1 U.l C ovtt Lt,4 zS 17-its' 1�l•`i �.Sr l21.3 1 �1.4 a.q I Zoo- Z`t.25 t��� E. 121.1 �•1 3�1�`I 'a.� iSs;a �`i.ZS LitZ� ts �0,t 12 111.1. I '33 7-Ijob Zq.ZS' 1300 `ZD.3 Z4K 11W.3 &-t 31.7 -3-0 100o `Ztf.ZS Page 211 of 238