RA-2582_16143_CA_LAB_20121106_Pace Lab Report

November 15, 2012
LIMS USE: FR - LINDA BLALOCK
LIMS OBJECT ID: 92137875
92137875
Project:
Pace Project No.:
RE:
Ms. Linda Blalock
NCDENR - UST Section
1637 Mail Service Center
Raleigh, NC 276991637
Agrotec, Inc. Inc#16143
Dear Ms. Blalock:
Enclosed are the analytical results for sample(s) received by the laboratory on November 07, 2012.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Charles Hardin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
CERTIFICATIONS
Pace Project No.:
Project:
92137875
Agrotec, Inc. Inc#16143
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Dr., Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
SAMPLE SUMMARY
Pace Project No.:
Project:
92137875
Agrotec, Inc. Inc#16143
Lab ID Sample ID Matrix Date Collected Date Received
92137875001 WSW-4 Water 11/06/12 13:00 11/07/12 16:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92137875
Agrotec, Inc. Inc#16143
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92137875001 WSW-4 MADEP EPH 7 PASI-CMEJ
MADEP VPH 5 PASI-CRGF
EPA 200.7 1 PASI-AJDA
EPA 625 59 PASI-CPPM
SM 6200B 64 PASI-CMCK
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
HITS ONLY
Pace Project No.:
Project:
92137875
Agrotec, Inc. Inc#16143
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92137875001 WSW-4
bis(2-Ethylhexyl)phthalate 6.7 ug/L 11/13/12 05:455.0EPA 625
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 5 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92137875
Agrotec, Inc. Inc#16143
Sample:WSW-4 Lab ID:92137875001 Collected:11/06/12 13:00 Received:11/07/12 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND ug/L 1 11/14/12 20:50 N211/09/12 15:40100100
Aliphatic (C19-C36)ND ug/L 1 11/14/12 20:50 N211/09/12 15:40100100
Aromatic (C11-C22)ND ug/L 1 11/14/12 20:50 N211/09/12 15:40100100
Surrogates
Nonatriacontane (S)80 %1 11/14/12 20:50 7194-86-711/09/12 15:4040-140
o-Terphenyl (S)66 %1 11/14/12 20:50 84-15-111/09/12 15:4040-140
2-Fluorobiphenyl (S)78 %1 11/14/12 20:50 321-60-811/09/12 15:4040-140
2-Bromonaphthalene (S)92 %1 11/14/12 20:50 580-13-211/09/12 15:4040-140
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 11/13/12 21:48 N250.0 50.0
Aliphatic (C09-C12)ND ug/L 1 11/13/12 21:48 N250.0 50.0
Aromatic (C09-C10)ND ug/L 1 11/13/12 21:48 N250.0 50.0
Surrogates
4-Bromofluorobenzene (FID) (S)100 %1 11/13/12 21:48 460-00-470-130
4-Bromofluorobenzene (PID) (S)89 %1 11/13/12 21:48 460-00-470-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead ND ug/L 1 11/11/12 00:20 7439-92-111/08/12 15:305.0 4.0
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene ND ug/L 1 11/13/12 05:45 83-32-911/08/12 10:005.0 0.25
Acenaphthylene ND ug/L 1 11/13/12 05:45 208-96-811/08/12 10:005.0 0.21
Anthracene ND ug/L 1 11/13/12 05:45 120-12-711/08/12 10:005.0 0.14
Benzo(a)anthracene ND ug/L 1 11/13/12 05:45 56-55-311/08/12 10:005.0 0.33
Benzo(a)pyrene ND ug/L 1 11/13/12 05:45 50-32-811/08/12 10:005.0 0.30
Benzo(b)fluoranthene ND ug/L 1 11/13/12 05:45 205-99-211/08/12 10:005.0 0.28
Benzo(g,h,i)perylene ND ug/L 1 11/13/12 05:45 191-24-211/08/12 10:005.0 0.38
Benzo(k)fluoranthene ND ug/L 1 11/13/12 05:45 207-08-911/08/12 10:005.0 0.43
4-Bromophenylphenyl ether ND ug/L 1 11/13/12 05:45 101-55-311/08/12 10:005.0 0.82
Butylbenzylphthalate ND ug/L 1 11/13/12 05:45 85-68-711/08/12 10:005.0 0.79
4-Chloro-3-methylphenol ND ug/L 1 11/13/12 05:45 59-50-711/08/12 10:005.0 3.7
bis(2-Chloroethoxy)methane ND ug/L 1 11/13/12 05:45 111-91-111/08/12 10:0010.0 0.92
bis(2-Chloroethyl) ether ND ug/L 1 11/13/12 05:45 111-44-411/08/12 10:005.0 1.0
bis(2-Chloroisopropyl) ether ND ug/L 1 11/13/12 05:45 108-60-111/08/12 10:005.0 0.95
2-Chloronaphthalene ND ug/L 1 11/13/12 05:45 91-58-711/08/12 10:005.0 0.98
2-Chlorophenol ND ug/L 1 11/13/12 05:45 95-57-811/08/12 10:005.0 1.3
4-Chlorophenylphenyl ether ND ug/L 1 11/13/12 05:45 7005-72-311/08/12 10:005.0 0.87
Chrysene ND ug/L 1 11/13/12 05:45 218-01-911/08/12 10:005.0 0.21
Dibenz(a,h)anthracene ND ug/L 1 11/13/12 05:45 53-70-311/08/12 10:005.0 0.55
3,3'-Dichlorobenzidine ND ug/L 1 11/13/12 05:45 91-94-111/08/12 10:0025.0 2.1
2,4-Dichlorophenol ND ug/L 1 11/13/12 05:45 120-83-211/08/12 10:005.0 1.7
Diethylphthalate ND ug/L 1 11/13/12 05:45 84-66-211/08/12 10:005.0 0.58
2,4-Dimethylphenol ND ug/L 1 11/13/12 05:45 105-67-911/08/12 10:0010.0 1.2
Dimethylphthalate ND ug/L 1 11/13/12 05:45 131-11-311/08/12 10:005.0 0.76
Di-n-butylphthalate ND ug/L 1 11/13/12 05:45 84-74-211/08/12 10:005.0 0.75
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 11/15/2012 06:07 PM Page 6 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92137875
Agrotec, Inc. Inc#16143
Sample:WSW-4 Lab ID:92137875001 Collected:11/06/12 13:00 Received:11/07/12 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
4,6-Dinitro-2-methylphenol ND ug/L 1 11/13/12 05:45 534-52-111/08/12 10:0020.0 2.6
2,4-Dinitrophenol ND ug/L 1 11/13/12 05:45 51-28-511/08/12 10:0050.0 9.0
2,4-Dinitrotoluene ND ug/L 1 11/13/12 05:45 121-14-211/08/12 10:005.0 0.90
2,6-Dinitrotoluene ND ug/L 1 11/13/12 05:45 606-20-211/08/12 10:005.0 0.98
Di-n-octylphthalate ND ug/L 1 11/13/12 05:45 117-84-011/08/12 10:005.0 0.66
bis(2-Ethylhexyl)phthalate 6.7 ug/L 1 11/13/12 05:45 117-81-711/08/12 10:005.0 0.79
Fluoranthene ND ug/L 1 11/13/12 05:45 206-44-011/08/12 10:005.0 0.21
Fluorene ND ug/L 1 11/13/12 05:45 86-73-711/08/12 10:005.0 0.21
Hexachloro-1,3-butadiene ND ug/L 1 11/13/12 05:45 87-68-311/08/12 10:005.0 0.94
Hexachlorobenzene ND ug/L 1 11/13/12 05:45 118-74-111/08/12 10:005.0 0.72
Hexachlorocyclopentadiene ND ug/L 1 11/13/12 05:45 77-47-411/08/12 10:0010.0 0.88
Hexachloroethane ND ug/L 1 11/13/12 05:45 67-72-111/08/12 10:005.0 1.1
Indeno(1,2,3-cd)pyrene ND ug/L 1 11/13/12 05:45 193-39-511/08/12 10:005.0 0.29
Isophorone ND ug/L 1 11/13/12 05:45 78-59-111/08/12 10:0010.0 0.89
2-Methylnaphthalene ND ug/L 1 11/13/12 05:45 91-57-611/08/12 10:005.0 0.28
Naphthalene ND ug/L 1 11/13/12 05:45 91-20-311/08/12 10:005.0 0.34
Nitrobenzene ND ug/L 1 11/13/12 05:45 98-95-311/08/12 10:005.0 1.1
2-Nitrophenol ND ug/L 1 11/13/12 05:45 88-75-511/08/12 10:005.0 0.91
4-Nitrophenol ND ug/L 1 11/13/12 05:45 100-02-711/08/12 10:0050.0 4.1
N-Nitrosodimethylamine ND ug/L 1 11/13/12 05:45 62-75-911/08/12 10:005.0 0.91
N-Nitroso-di-n-propylamine ND ug/L 1 11/13/12 05:45 621-64-711/08/12 10:005.0 0.99
N-Nitrosodiphenylamine ND ug/L 1 11/13/12 05:45 86-30-611/08/12 10:0010.0 1.0
Pentachlorophenol ND ug/L 1 11/13/12 05:45 87-86-511/08/12 10:0025.0 4.6
Phenanthrene ND ug/L 1 11/13/12 05:45 85-01-811/08/12 10:005.0 0.22
Phenol ND ug/L 1 11/13/12 05:45 108-95-211/08/12 10:005.0 1.9
Pyrene ND ug/L 1 11/13/12 05:45 129-00-011/08/12 10:005.0 0.19
1,2,4-Trichlorobenzene ND ug/L 1 11/13/12 05:45 120-82-111/08/12 10:005.0 0.98
2,4,6-Trichlorophenol ND ug/L 1 11/13/12 05:45 88-06-211/08/12 10:0010.0 1.3
Surrogates
Nitrobenzene-d5 (S)73 %1 11/13/12 05:45 4165-60-011/08/12 10:0010-120
2-Fluorobiphenyl (S)72 %1 11/13/12 05:45 321-60-811/08/12 10:0015-120
Terphenyl-d14 (S)98 %1 11/13/12 05:45 1718-51-011/08/12 10:0011-131
Phenol-d6 (S)27 %1 11/13/12 05:45 13127-88-311/08/12 10:0010-120
2-Fluorophenol (S)37 %1 11/13/12 05:45 367-12-411/08/12 10:0010-120
2,4,6-Tribromophenol (S)80 %1 11/13/12 05:45 118-79-611/08/12 10:0010-137
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 11/09/12 17:37 71-43-20.50 0.50
Bromobenzene ND ug/L 1 11/09/12 17:37 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 11/09/12 17:37 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 11/09/12 17:37 75-27-40.50 0.50
Bromoform ND ug/L 1 11/09/12 17:37 75-25-20.50 0.50
Bromomethane ND ug/L 1 11/09/12 17:37 74-83-95.0 1.0
n-Butylbenzene ND ug/L 1 11/09/12 17:37 104-51-80.50 0.50
sec-Butylbenzene ND ug/L 1 11/09/12 17:37 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 11/09/12 17:37 98-06-60.50 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 11/15/2012 06:07 PM Page 7 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92137875
Agrotec, Inc. Inc#16143
Sample:WSW-4 Lab ID:92137875001 Collected:11/06/12 13:00 Received:11/07/12 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Carbon tetrachloride ND ug/L 1 11/09/12 17:37 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 11/09/12 17:37 108-90-70.50 0.50
Chloroethane ND ug/L 1 11/09/12 17:37 75-00-31.0 1.0
Chloroform ND ug/L 1 11/09/12 17:37 67-66-30.50 0.50
Chloromethane ND ug/L 1 11/09/12 17:37 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 11/09/12 17:37 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 11/09/12 17:37 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 11/09/12 17:37 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 11/09/12 17:37 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 11/09/12 17:37 106-93-40.50 0.50
Dibromomethane ND ug/L 1 11/09/12 17:37 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 11/09/12 17:37 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 11/09/12 17:37 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 11/09/12 17:37 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 11/09/12 17:37 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 11/09/12 17:37 75-34-30.50 0.50
1,2-Dichloroethane ND ug/L 1 11/09/12 17:37 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 11/09/12 17:37 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 11/09/12 17:37 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 11/09/12 17:37 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 11/09/12 17:37 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 11/09/12 17:37 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 11/09/12 17:37 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 11/09/12 17:37 563-58-60.50 0.50
cis-1,3-Dichloropropene ND ug/L 1 11/09/12 17:37 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 11/09/12 17:37 10061-02-60.50 0.50
Diisopropyl ether ND ug/L 1 11/09/12 17:37 108-20-30.50 0.50
Ethylbenzene ND ug/L 1 11/09/12 17:37 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 11/09/12 17:37 87-68-32.0 2.0
Isopropylbenzene (Cumene)ND ug/L 1 11/09/12 17:37 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 11/09/12 17:37 75-09-22.0 2.0
Methyl-tert-butyl ether ND ug/L 1 11/09/12 17:37 1634-04-40.50 0.50
Naphthalene ND ug/L 1 11/09/12 17:37 91-20-32.0 2.0
n-Propylbenzene ND ug/L 1 11/09/12 17:37 103-65-10.50 0.50
Styrene ND ug/L 1 11/09/12 17:37 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 11/09/12 17:37 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 11/09/12 17:37 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 11/09/12 17:37 127-18-40.50 0.50
Toluene ND ug/L 1 11/09/12 17:37 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 11/09/12 17:37 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 11/09/12 17:37 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 11/09/12 17:37 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 11/09/12 17:37 79-00-50.50 0.50
Trichloroethene ND ug/L 1 11/09/12 17:37 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 11/09/12 17:37 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 11/09/12 17:37 96-18-40.50 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 11/15/2012 06:07 PM Page 8 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92137875
Agrotec, Inc. Inc#16143
Sample:WSW-4 Lab ID:92137875001 Collected:11/06/12 13:00 Received:11/07/12 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
1,2,4-Trimethylbenzene ND ug/L 1 11/09/12 17:37 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 11/09/12 17:37 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 11/09/12 17:37 75-01-41.0 1.0
m&p-Xylene ND ug/L 1 11/09/12 17:37 179601-23-11.0 1.0
o-Xylene ND ug/L 1 11/09/12 17:37 95-47-60.50 0.50
Surrogates
1,2-Dichloroethane-d4 (S)93 %1 11/09/12 17:37 17060-07-070-130
Dibromofluoromethane (S)98 %1 11/09/12 17:37 1868-53-770-130
4-Bromofluorobenzene (S)94 %1 11/09/12 17:37 460-00-470-130
Toluene-d8 (S)99 %1 11/09/12 17:37 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 11/15/2012 06:07 PM Page 9 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92137875
Agrotec, Inc. Inc#16143
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/6401
MADEP VPH
MADEP VPH
VPH NC Water
Associated Lab Samples:92137875001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:870354
Associated Lab Samples:92137875001
Matrix:Water
Analyzed
Aliphatic (C05-C08)ug/L ND 50.0 N211/13/12 13:47
Aliphatic (C09-C12)ug/L ND 50.0 N211/13/12 13:47
Aromatic (C09-C10)ug/L ND 50.0 N211/13/12 13:47
4-Bromofluorobenzene (FID) (S)%98 70-130 11/13/12 13:47
4-Bromofluorobenzene (PID) (S)%88 70-130 11/13/12 13:47
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
870355LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
870356
Aliphatic (C05-C08)ug/L 324 N230010870-13098295 10 25
Aliphatic (C09-C12)ug/L 338 N230011330-130115346 2 25
Aromatic (C09-C10)ug/L 111 N210011170-130104104 6 25
4-Bromofluorobenzene (FID) (S)%95 70-13089
4-Bromofluorobenzene (PID) (S)%105 70-13098
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 11/15/2012 06:07 PM Page 10 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92137875
Agrotec, Inc. Inc#16143
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/11927
SM 3030C
EPA 200.7
200.7 MET 3030C
Associated Lab Samples:92137875001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:868512
Associated Lab Samples:92137875001
Matrix:Water
Analyzed
Lead ug/L ND 5.0 11/10/12 23:46
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
868513LABORATORY CONTROL SAMPLE:
LCSSpike
Lead ug/L 478500 96 85-115
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
868514MATRIX SPIKE SAMPLE:
MSSpike
Result
92137724001
Lead ug/L 467500 93 70-130ND
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
868516MATRIX SPIKE SAMPLE:
MSSpike
Result
92137879007
Lead ug/L 458500 92 70-130ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92137724002
868515SAMPLE DUPLICATE:
Lead ug/L ND 20ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92137879008
868517SAMPLE DUPLICATE:
Lead ug/L ND 20ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 11/15/2012 06:07 PM Page 11 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92137875
Agrotec, Inc. Inc#16143
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/21051
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92137875001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:869440
Associated Lab Samples:92137875001
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 11/09/12 15:45
1,1,1-Trichloroethane ug/L ND 0.50 11/09/12 15:45
1,1,2,2-Tetrachloroethane ug/L ND 0.50 11/09/12 15:45
1,1,2-Trichloroethane ug/L ND 0.50 11/09/12 15:45
1,1-Dichloroethane ug/L ND 0.50 11/09/12 15:45
1,1-Dichloroethene ug/L ND 0.50 11/09/12 15:45
1,1-Dichloropropene ug/L ND 0.50 11/09/12 15:45
1,2,3-Trichlorobenzene ug/L ND 2.0 11/09/12 15:45
1,2,3-Trichloropropane ug/L ND 0.50 11/09/12 15:45
1,2,4-Trichlorobenzene ug/L ND 2.0 11/09/12 15:45
1,2,4-Trimethylbenzene ug/L ND 0.50 11/09/12 15:45
1,2-Dibromo-3-chloropropane ug/L ND 1.0 11/09/12 15:45
1,2-Dibromoethane (EDB)ug/L ND 0.50 11/09/12 15:45
1,2-Dichlorobenzene ug/L ND 0.50 11/09/12 15:45
1,2-Dichloroethane ug/L ND 0.50 11/09/12 15:45
1,2-Dichloropropane ug/L ND 0.50 11/09/12 15:45
1,3,5-Trimethylbenzene ug/L ND 0.50 11/09/12 15:45
1,3-Dichlorobenzene ug/L ND 0.50 11/09/12 15:45
1,3-Dichloropropane ug/L ND 0.50 11/09/12 15:45
1,4-Dichlorobenzene ug/L ND 0.50 11/09/12 15:45
2,2-Dichloropropane ug/L ND 0.50 11/09/12 15:45
2-Chlorotoluene ug/L ND 0.50 11/09/12 15:45
4-Chlorotoluene ug/L ND 0.50 11/09/12 15:45
Benzene ug/L ND 0.50 11/09/12 15:45
Bromobenzene ug/L ND 0.50 11/09/12 15:45
Bromochloromethane ug/L ND 0.50 11/09/12 15:45
Bromodichloromethane ug/L ND 0.50 11/09/12 15:45
Bromoform ug/L ND 0.50 11/09/12 15:45
Bromomethane ug/L ND 5.0 11/09/12 15:45
Carbon tetrachloride ug/L ND 0.50 11/09/12 15:45
Chlorobenzene ug/L ND 0.50 11/09/12 15:45
Chloroethane ug/L ND 1.0 11/09/12 15:45
Chloroform ug/L ND 0.50 11/09/12 15:45
Chloromethane ug/L ND 1.0 11/09/12 15:45
cis-1,2-Dichloroethene ug/L ND 0.50 11/09/12 15:45
cis-1,3-Dichloropropene ug/L ND 0.50 11/09/12 15:45
Dibromochloromethane ug/L ND 0.50 11/09/12 15:45
Dibromomethane ug/L ND 0.50 11/09/12 15:45
Dichlorodifluoromethane ug/L ND 0.50 11/09/12 15:45
Diisopropyl ether ug/L ND 0.50 11/09/12 15:45
Ethylbenzene ug/L ND 0.50 11/09/12 15:45
Hexachloro-1,3-butadiene ug/L ND 2.0 11/09/12 15:45
Isopropylbenzene (Cumene)ug/L ND 0.50 11/09/12 15:45
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 11/15/2012 06:07 PM Page 12 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92137875
Agrotec, Inc. Inc#16143
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:869440
Associated Lab Samples:92137875001
Matrix:Water
Analyzed
m&p-Xylene ug/L ND 1.0 11/09/12 15:45
Methyl-tert-butyl ether ug/L ND 0.50 11/09/12 15:45
Methylene Chloride ug/L ND 2.0 11/09/12 15:45
n-Butylbenzene ug/L ND 0.50 11/09/12 15:45
n-Propylbenzene ug/L ND 0.50 11/09/12 15:45
Naphthalene ug/L ND 2.0 11/09/12 15:45
o-Xylene ug/L ND 0.50 11/09/12 15:45
sec-Butylbenzene ug/L ND 0.50 11/09/12 15:45
Styrene ug/L ND 0.50 11/09/12 15:45
tert-Butylbenzene ug/L ND 0.50 11/09/12 15:45
Tetrachloroethene ug/L ND 0.50 11/09/12 15:45
Toluene ug/L ND 0.50 11/09/12 15:45
trans-1,2-Dichloroethene ug/L ND 0.50 11/09/12 15:45
trans-1,3-Dichloropropene ug/L ND 0.50 11/09/12 15:45
Trichloroethene ug/L ND 0.50 11/09/12 15:45
Trichlorofluoromethane ug/L ND 1.0 11/09/12 15:45
Vinyl chloride ug/L ND 1.0 11/09/12 15:45
1,2-Dichloroethane-d4 (S)%93 70-130 11/09/12 15:45
4-Bromofluorobenzene (S)%95 70-130 11/09/12 15:45
Dibromofluoromethane (S)%96 70-130 11/09/12 15:45
Toluene-d8 (S)%99 70-130 11/09/12 15:45
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
869441LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 54.050 108 60-140
1,1,1-Trichloroethane ug/L 46.850 94 60-140
1,1,2,2-Tetrachloroethane ug/L 48.450 97 60-140
1,1,2-Trichloroethane ug/L 52.350 105 60-140
1,1-Dichloroethane ug/L 44.750 89 60-140
1,1-Dichloroethene ug/L 37.550 75 60-140
1,1-Dichloropropene ug/L 40.450 81 60-140
1,2,3-Trichlorobenzene ug/L 48.850 98 60-140
1,2,3-Trichloropropane ug/L 50.150 100 60-140
1,2,4-Trichlorobenzene ug/L 49.150 98 60-140
1,2,4-Trimethylbenzene ug/L 48.450 97 60-140
1,2-Dibromo-3-chloropropane ug/L 48.150 96 60-140
1,2-Dibromoethane (EDB)ug/L 52.350 105 60-140
1,2-Dichlorobenzene ug/L 48.050 96 60-140
1,2-Dichloroethane ug/L 41.250 82 60-140
1,2-Dichloropropane ug/L 44.950 90 60-140
1,3,5-Trimethylbenzene ug/L 47.550 95 60-140
1,3-Dichlorobenzene ug/L 49.350 99 60-140
1,3-Dichloropropane ug/L 46.450 93 60-140
1,4-Dichlorobenzene ug/L 47.650 95 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 11/15/2012 06:07 PM Page 13 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92137875
Agrotec, Inc. Inc#16143
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
869441LABORATORY CONTROL SAMPLE:
LCSSpike
2,2-Dichloropropane ug/L 48.250 96 60-140
2-Chlorotoluene ug/L 45.050 90 60-140
4-Chlorotoluene ug/L 45.750 91 60-140
Benzene ug/L 46.950 94 60-140
Bromobenzene ug/L 43.750 87 60-140
Bromochloromethane ug/L 43.650 87 60-140
Bromodichloromethane ug/L 52.450 105 60-140
Bromoform ug/L 43.450 87 60-140
Bromomethane ug/L 32.650 65 60-140
Carbon tetrachloride ug/L 50.850 102 60-140
Chlorobenzene ug/L 49.950 100 60-140
Chloroethane ug/L 46.850 94 60-140
Chloroform ug/L 44.350 89 60-140
Chloromethane ug/L 44.850 90 60-140
cis-1,2-Dichloroethene ug/L 42.150 84 60-140
cis-1,3-Dichloropropene ug/L 53.350 107 60-140
Dibromochloromethane ug/L 59.050 118 60-140
Dibromomethane ug/L 52.650 105 60-140
Dichlorodifluoromethane ug/L 45.950 92 60-140
Diisopropyl ether ug/L 37.750 75 60-140
Ethylbenzene ug/L 48.550 97 60-140
Hexachloro-1,3-butadiene ug/L 48.850 98 60-140
Isopropylbenzene (Cumene)ug/L 51.050 102 60-140
m&p-Xylene ug/L 101100 101 60-140
Methyl-tert-butyl ether ug/L 41.550 83 60-140
Methylene Chloride ug/L 35.450 71 60-140
n-Butylbenzene ug/L 48.150 96 60-140
n-Propylbenzene ug/L 45.350 91 60-140
Naphthalene ug/L 49.050 98 60-140
o-Xylene ug/L 48.250 96 60-140
sec-Butylbenzene ug/L 48.150 96 60-140
Styrene ug/L 54.050 108 60-140
tert-Butylbenzene ug/L 47.350 95 60-140
Tetrachloroethene ug/L 51.150 102 60-140
Toluene ug/L 48.350 97 60-140
trans-1,2-Dichloroethene ug/L 35.750 71 60-140
trans-1,3-Dichloropropene ug/L 56.850 114 60-140
Trichloroethene ug/L 49.050 98 60-140
Trichlorofluoromethane ug/L 39.150 78 60-140
Vinyl chloride ug/L 36.250 72 60-140
1,2-Dichloroethane-d4 (S)%87 70-130
4-Bromofluorobenzene (S)%106 70-130
Dibromofluoromethane (S)%98 70-130
Toluene-d8 (S)%101 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 11/15/2012 06:07 PM Page 14 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92137875
Agrotec, Inc. Inc#16143
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
869442MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92137871011
869443
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 115 60-140114 0 3020ND22.9 22.9
1,1,1-Trichloroethane ug/L 20 106 60-140106 0 3020ND21.2 21.2
1,1,2,2-Tetrachloroethane ug/L 20 97 60-14098 1 3020ND19.4 19.7
1,1,2-Trichloroethane ug/L 20 110 60-140111 1 3020ND22.1 22.3
1,1-Dichloroethane ug/L 20 99 60-140102 3 3020ND19.9 20.5
1,1-Dichloroethene ug/L 20 91 60-14090 1 3020ND18.3 18.0
1,1-Dichloropropene ug/L 20 91 60-14090 1 3020ND18.2 17.9
1,2,3-Trichlorobenzene ug/L 20 108 60-140109 1 3020ND21.7 21.8
1,2,3-Trichloropropane ug/L 20 101 60-140104 2 3020ND20.2 20.7
1,2,4-Trichlorobenzene ug/L 20 106 60-140108 2 3020ND21.1 21.6
1,2,4-Trimethylbenzene ug/L 20 105 60-140106 0 3020ND21.0 21.1
1,2-Dibromo-3-chloropropane ug/L 20 99 60-140100 0 3020ND19.8 19.9
1,2-Dibromoethane (EDB)ug/L 20 111 60-140111 0 3020ND22.2 22.3
1,2-Dichlorobenzene ug/L 20 106 60-140106 0 3020ND21.2 21.3
1,2-Dichloroethane ug/L 20 91 60-14092 2 3020ND18.2 18.5
1,2-Dichloropropane ug/L 20 99 60-140100 1 3020ND19.8 20.0
1,3,5-Trimethylbenzene ug/L 20 105 60-140104 0 3020ND20.9 20.9
1,3-Dichlorobenzene ug/L 20 107 60-140107 0 3020ND21.3 21.4
1,3-Dichloropropane ug/L 20 99 60-140100 1 3020ND19.9 20.0
1,4-Dichlorobenzene ug/L 20 104 60-140105 1 3020ND20.8 21.0
2,2-Dichloropropane ug/L 20 60 60-14061 1 3020ND12.0 12.2
2-Chlorotoluene ug/L 20 100 60-140101 1 3020ND20.0 20.3
4-Chlorotoluene ug/L 20 100 60-140102 3 3020ND19.9 20.5
Benzene ug/L 20 105 60-140105 0 3020ND20.9 21.0
Bromobenzene ug/L 20 96 60-14099 3 3020ND19.3 19.8
Bromochloromethane ug/L 20 110 60-140113 3 3020ND22.0 22.6
Bromodichloromethane ug/L 20 111 60-140111 1 3020ND22.1 22.2
Bromoform ug/L 20 95 60-14096 1 3020ND18.9 19.1
Bromomethane ug/L 20 78 60-14084 8 3020ND15.5 16.9
Carbon tetrachloride ug/L 20 111 60-140109 2 3020ND22.3 21.9
Chlorobenzene ug/L 20 110 60-140111 1 3020ND21.9 22.1
Chloroethane ug/L 20 116 60-140112 3 3020ND23.2 22.4
Chloroform ug/L 20 98 60-140104 6 3020ND19.6 20.8
Chloromethane ug/L 20 82 60-14084 1 3020ND16.5 16.7
cis-1,2-Dichloroethene ug/L 20 95 60-14096 2 3020ND19.0 19.3
cis-1,3-Dichloropropene ug/L 20 98 60-140100 2 3020ND19.6 19.9
Dibromochloromethane ug/L 20 116 60-140118 1 3020ND23.3 23.5
Dibromomethane ug/L 20 112 60-140114 1 3020ND22.5 22.8
Dichlorodifluoromethane ug/L 20 79 60-14079 0 3020ND15.7 15.7
Diisopropyl ether ug/L 20 83 60-14084 1 3020ND16.9 17.0
Ethylbenzene ug/L 20 105 60-140106 0 3020ND21.1 21.1
Hexachloro-1,3-butadiene ug/L 20 107 60-140108 1 3020ND21.4 21.6
Isopropylbenzene (Cumene)ug/L 20 108 60-140107 1 3020ND21.7 21.3
m&p-Xylene ug/L 40 107 60-140108 1 3040ND43.0 43.3
Methyl-tert-butyl ether ug/L 20 89 60-14091 2 30206.2 24.0 24.4
Methylene Chloride ug/L 20 86 60-14087 1 3020ND17.2 17.4
n-Butylbenzene ug/L 20 104 60-140103 0 3020ND20.7 20.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 11/15/2012 06:07 PM Page 15 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92137875
Agrotec, Inc. Inc#16143
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
869442MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92137871011
869443
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
n-Propylbenzene ug/L 20 103 60-140102 1 3020ND20.6 20.3
Naphthalene ug/L 20 106 60-140107 2 3020ND21.1 21.5
o-Xylene ug/L 20 103 60-140103 0 3020ND20.6 20.6
sec-Butylbenzene ug/L 20 107 60-140107 0 3020ND21.3 21.3
Styrene ug/L 20 111 60-140112 1 3020ND22.3 22.4
tert-Butylbenzene ug/L 20 106 60-140105 2 3020ND21.3 21.0
Tetrachloroethene ug/L 20 111 60-140110 1 3020ND22.2 21.9
Toluene ug/L 20 107 60-140107 0 3020ND21.4 21.4
trans-1,2-Dichloroethene ug/L 20 88 60-14086 2 3020ND17.6 17.3
trans-1,3-Dichloropropene ug/L 20 104 60-140107 3 3020ND20.8 21.4
Trichloroethene ug/L 20 110 60-140107 2 3020ND21.9 21.4
Trichlorofluoromethane ug/L 20 98 60-14099 1 3020ND19.7 19.8
Vinyl chloride ug/L 20 85 60-14084 2 3020ND17.0 16.7
1,2-Dichloroethane-d4 (S)%89 70-13089
4-Bromofluorobenzene (S)%100 70-130100
Dibromofluoromethane (S)%98 70-130100
Toluene-d8 (S)%101 70-13099
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 11/15/2012 06:07 PM Page 16 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92137875
Agrotec, Inc. Inc#16143
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/19629
EPA 625
EPA 625
625 MSS
Associated Lab Samples:92137875001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:868576
Associated Lab Samples:92137875001
Matrix:Water
Analyzed
1,2,4-Trichlorobenzene ug/L ND 5.0 11/13/12 03:29
2,4,6-Trichlorophenol ug/L ND 10.0 11/13/12 03:29
2,4-Dichlorophenol ug/L ND 5.0 11/13/12 03:29
2,4-Dimethylphenol ug/L ND 10.0 11/13/12 03:29
2,4-Dinitrophenol ug/L ND 50.0 11/13/12 03:29
2,4-Dinitrotoluene ug/L ND 5.0 11/13/12 03:29
2,6-Dinitrotoluene ug/L ND 5.0 11/13/12 03:29
2-Chloronaphthalene ug/L ND 5.0 11/13/12 03:29
2-Chlorophenol ug/L ND 5.0 11/13/12 03:29
2-Methylnaphthalene ug/L ND 5.0 11/13/12 03:29
2-Nitrophenol ug/L ND 5.0 11/13/12 03:29
3,3'-Dichlorobenzidine ug/L ND 25.0 11/13/12 03:29
4,6-Dinitro-2-methylphenol ug/L ND 20.0 11/13/12 03:29
4-Bromophenylphenyl ether ug/L ND 5.0 11/13/12 03:29
4-Chloro-3-methylphenol ug/L ND 5.0 11/13/12 03:29
4-Chlorophenylphenyl ether ug/L ND 5.0 11/13/12 03:29
4-Nitrophenol ug/L ND 50.0 11/13/12 03:29
Acenaphthene ug/L ND 5.0 11/13/12 03:29
Acenaphthylene ug/L ND 5.0 11/13/12 03:29
Anthracene ug/L ND 5.0 11/13/12 03:29
Benzo(a)anthracene ug/L ND 5.0 11/13/12 03:29
Benzo(a)pyrene ug/L ND 5.0 11/13/12 03:29
Benzo(b)fluoranthene ug/L ND 5.0 11/13/12 03:29
Benzo(g,h,i)perylene ug/L ND 5.0 11/13/12 03:29
Benzo(k)fluoranthene ug/L ND 5.0 11/13/12 03:29
bis(2-Chloroethoxy)methane ug/L ND 10.0 11/13/12 03:29
bis(2-Chloroethyl) ether ug/L ND 5.0 11/13/12 03:29
bis(2-Chloroisopropyl) ether ug/L ND 5.0 11/13/12 03:29
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 11/13/12 03:29
Butylbenzylphthalate ug/L ND 5.0 11/13/12 03:29
Chrysene ug/L ND 5.0 11/13/12 03:29
Di-n-butylphthalate ug/L ND 5.0 11/13/12 03:29
Di-n-octylphthalate ug/L ND 5.0 11/13/12 03:29
Dibenz(a,h)anthracene ug/L ND 5.0 11/13/12 03:29
Diethylphthalate ug/L ND 5.0 11/13/12 03:29
Dimethylphthalate ug/L ND 5.0 11/13/12 03:29
Fluoranthene ug/L ND 5.0 11/13/12 03:29
Fluorene ug/L ND 5.0 11/13/12 03:29
Hexachloro-1,3-butadiene ug/L ND 5.0 11/13/12 03:29
Hexachlorobenzene ug/L ND 5.0 11/13/12 03:29
Hexachlorocyclopentadiene ug/L ND 10.0 11/13/12 03:29
Hexachloroethane ug/L ND 5.0 11/13/12 03:29
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 11/13/12 03:29
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 11/15/2012 06:07 PM Page 17 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92137875
Agrotec, Inc. Inc#16143
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:868576
Associated Lab Samples:92137875001
Matrix:Water
Analyzed
Isophorone ug/L ND 10.0 11/13/12 03:29
N-Nitroso-di-n-propylamine ug/L ND 5.0 11/13/12 03:29
N-Nitrosodimethylamine ug/L ND 5.0 11/13/12 03:29
N-Nitrosodiphenylamine ug/L ND 10.0 11/13/12 03:29
Naphthalene ug/L ND 5.0 11/13/12 03:29
Nitrobenzene ug/L ND 5.0 11/13/12 03:29
Pentachlorophenol ug/L ND 25.0 11/13/12 03:29
Phenanthrene ug/L ND 5.0 11/13/12 03:29
Phenol ug/L ND 5.0 11/13/12 03:29
Pyrene ug/L ND 5.0 11/13/12 03:29
2,4,6-Tribromophenol (S)%84 10-137 11/13/12 03:29
2-Fluorobiphenyl (S)%79 15-120 11/13/12 03:29
2-Fluorophenol (S)%43 10-120 11/13/12 03:29
Nitrobenzene-d5 (S)%79 10-120 11/13/12 03:29
Phenol-d6 (S)%34 10-120 11/13/12 03:29
Terphenyl-d14 (S)%94 11-131 11/13/12 03:29
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
868577LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 39.050 78 44-142
2,4,6-Trichlorophenol ug/L 45.150 90 37-144
2,4-Dichlorophenol ug/L 44.750 89 1-191
2,4-Dimethylphenol ug/L 42.750 85 32-119
2,4-Dinitrophenol ug/L 253250 101 1-181
2,4-Dinitrotoluene ug/L 43.250 86 39-139
2,6-Dinitrotoluene ug/L 41.750 83 50-158
2-Chloronaphthalene ug/L 42.850 86 60-118
2-Chlorophenol ug/L 42.250 84 23-134
2-Methylnaphthalene ug/L 47.450 95 25-150
2-Nitrophenol ug/L 45.850 92 29-182
3,3'-Dichlorobenzidine ug/L 108100 108 1-262
4,6-Dinitro-2-methylphenol ug/L 98.4100 98 1-181
4-Bromophenylphenyl ether ug/L 48.650 97 53-127
4-Chloro-3-methylphenol ug/L 102100 102 22-147
4-Chlorophenylphenyl ether ug/L 50.050 100 25-158
4-Nitrophenol ug/L 123250 49 1-132
Acenaphthene ug/L 49.750 99 47-145
Acenaphthylene ug/L 48.350 97 33-145
Anthracene ug/L 47.850 96 1-166
Benzo(a)anthracene ug/L 51.250 102 33-143
Benzo(a)pyrene ug/L 49.450 99 17-163
Benzo(b)fluoranthene ug/L 48.950 98 24-159
Benzo(g,h,i)perylene ug/L 47.350 95 1-219
Benzo(k)fluoranthene ug/L 44.850 90 11-162
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 11/15/2012 06:07 PM Page 18 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92137875
Agrotec, Inc. Inc#16143
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
868577LABORATORY CONTROL SAMPLE:
LCSSpike
bis(2-Chloroethoxy)methane ug/L 45.850 92 33-184
bis(2-Chloroethyl) ether ug/L 47.550 95 12-158
bis(2-Chloroisopropyl) ether ug/L 52.250 104 36-166
bis(2-Ethylhexyl)phthalate ug/L 50.150 100 8-158
Butylbenzylphthalate ug/L 48.250 96 1-152
Chrysene ug/L 48.850 98 17-168
Di-n-butylphthalate ug/L 46.650 93 1-118
Di-n-octylphthalate ug/L 56.750 113 4-146
Dibenz(a,h)anthracene ug/L 47.350 95 1-227
Diethylphthalate ug/L 48.250 96 1-114
Dimethylphthalate ug/L 46.450 93 1-112
Fluoranthene ug/L 52.950 106 26-137
Fluorene ug/L 50.550 101 59-121
Hexachloro-1,3-butadiene ug/L 39.050 78 24-116
Hexachlorobenzene ug/L 45.650 91 1-152
Hexachlorocyclopentadiene ug/L 43.350 87 25-150
Hexachloroethane ug/L 39.150 78 40-113
Indeno(1,2,3-cd)pyrene ug/L 49.450 99 1-171
Isophorone ug/L 40.150 80 21-196
N-Nitroso-di-n-propylamine ug/L 55.950 112 1-230
N-Nitrosodimethylamine ug/L 30.450 61 25-150
N-Nitrosodiphenylamine ug/L 48.050 96 25-150
Naphthalene ug/L 43.450 87 21-133
Nitrobenzene ug/L 36.850 74 35-180
Pentachlorophenol ug/L 78.2100 78 14-176
Phenanthrene ug/L 46.450 93 54-120
Phenol ug/L 20.050 40 5-112
Pyrene ug/L 47.250 94 52-115
2,4,6-Tribromophenol (S)%103 10-137
2-Fluorobiphenyl (S)%88 15-120
2-Fluorophenol (S)%48 10-120
Nitrobenzene-d5 (S)%90 10-120
Phenol-d6 (S)%34 10-120
Terphenyl-d14 (S)%102 11-131
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
868578MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92137751004
868579
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/L 1g,R11007744-14247 49 30100ND77.3 46.8
2,4,6-Trichlorophenol ug/L 100 87 37-14454 46 30100ND86.5 54.0
2,4-Dichlorophenol ug/L 100 88 1-19153 49 30100ND87.6 53.2
2,4-Dimethylphenol ug/L 100 86 32-11954 46 30100ND86.3 54.1
2,4-Dinitrophenol ug/L 500 102 1-1816 30500ND51029.4J
2,4-Dinitrotoluene ug/L 100 82 39-13951 46 30100ND81.7 50.9
2,6-Dinitrotoluene ug/L M0,M11007950-15849 47 30100ND79.2 49.0
2-Chloronaphthalene ug/L M0,M11008160-11851 46 30100ND81.2 50.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 11/15/2012 06:07 PM Page 19 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92137875
Agrotec, Inc. Inc#16143
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
868578MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92137751004
868579
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2-Chlorophenol ug/L 100 83 23-13452 46 30100ND82.6 51.9
2-Methylnaphthalene ug/L 100 90 25-15055 49 30100ND90.2 54.9
2-Nitrophenol ug/L 100 85 29-18253 45 30100ND84.7 53.4
3,3'-Dichlorobenzidine ug/L 200 91 1-26263 36 30200ND181126
4,6-Dinitro-2-methylphenol ug/L 200 96 1-18147 68 30200ND19194.2
4-Bromophenylphenyl ether ug/L 100 93 53-12757 48 30100ND92.6 56.9
4-Chloro-3-methylphenol ug/L 200 103 22-14764 47 30200ND206127
4-Chlorophenylphenyl ether ug/L 100 94 25-15857 48 30100ND93.6 57.4
4-Nitrophenol ug/L 500 69 1-13243 47 30500ND346215
Acenaphthene ug/L 100 91 47-14557 46 30100ND90.9 56.9
Acenaphthylene ug/L 100 91 33-14556 47 30100ND90.6 55.9
Anthracene ug/L 100 90 1-16656 46 30100ND90.1 56.2
Benzo(a)anthracene ug/L 100 99 33-14362 45 30100ND98.5 62.3
Benzo(a)pyrene ug/L 100 95 17-16360 45 30100ND95.2 60.2
Benzo(b)fluoranthene ug/L 100 93 24-15958 45 30100ND92.5 58.4
Benzo(g,h,i)perylene ug/L 100 91 1-21957 45 30100ND90.6 57.2
Benzo(k)fluoranthene ug/L 100 88 11-16255 46 30100ND88.1 55.0
bis(2-Chloroethoxy)methane ug/L 100 85 33-18452 49 30100ND85.5 52.1
bis(2-Chloroethyl) ether ug/L 100 88 12-15854 48 30100ND87.8 54.0
bis(2-Chloroisopropyl) ether ug/L 100 96 36-16658 49 30100ND95.9 58.2
bis(2-Ethylhexyl)phthalate ug/L 100 96 8-15864 41 30100ND96.3 63.5
Butylbenzylphthalate ug/L 100 92 1-15258 45 30100ND91.9 58.3
Chrysene ug/L 100 95 17-16859 46 30100ND94.8 59.3
Di-n-butylphthalate ug/L 100 89 1-11856 46 30100ND88.5 55.7
Di-n-octylphthalate ug/L 100 109 4-14667 48 30100ND10967.1
Dibenz(a,h)anthracene ug/L 100 93 1-22758 46 30100ND92.7 57.7
Diethylphthalate ug/L 100 91 1-11457 47 30100ND91.3 56.6
Dimethylphthalate ug/L 100 89 1-11255 47 30100ND89.0 55.0
Fluoranthene ug/L 100 101 26-13764 46 30100ND10163.5
Fluorene ug/L M0,M11009559-12158 48 30100ND94.5 58.1
Hexachloro-1,3-butadiene ug/L 100 80 24-11648 49 30100ND79.7 48.5
Hexachlorobenzene ug/L 100 87 1-15254 47 30100ND86.8 53.7
Hexachlorocyclopentadiene ug/L 100 82 25-15051 45 30100ND81.6 51.5
Hexachloroethane ug/L 100 76 40-11345 51 30100ND75.9 45.3
Indeno(1,2,3-cd)pyrene ug/L 100 95 1-17159 47 30100ND95.2 59.0
Isophorone ug/L 100 74 21-19645 48 30100ND74.4 45.4
N-Nitroso-di-n-propylamine ug/L 100 103 1-23065 45 30100ND10365.2
N-Nitrosodimethylamine ug/L 100 71 25-15043 48 30100ND70.8 43.4
N-Nitrosodiphenylamine ug/L 100 92 25-15057 47 30100ND91.6 56.7
Naphthalene ug/L 100 86 21-13351 51 30100ND85.6 50.8
Nitrobenzene ug/L 100 70 35-18042 50 30100ND70.0 42.1
Pentachlorophenol ug/L 200 89 14-17655 46 30200ND177111
Phenanthrene ug/L 100 87 54-12054 46 30100ND87.1 54.4
Phenol ug/L 100 67 5-11243 44 30100ND67.4 43.0
Pyrene ug/L 100 89 52-11558 42 30100ND89.2 58.2
2,4,6-Tribromophenol (S)%94 10-13759
2-Fluorobiphenyl (S)%77 15-12048
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 11/15/2012 06:07 PM Page 20 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92137875
Agrotec, Inc. Inc#16143
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
868578MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92137751004
868579
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2-Fluorophenol (S)%56 10-12035
Nitrobenzene-d5 (S)%79 10-12047
Phenol-d6 (S)%54 10-12035
Terphenyl-d14 (S)%91 11-13158
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 11/15/2012 06:07 PM Page 21 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92137875
Agrotec, Inc. Inc#16143
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/19661
MADEP EPH
MADEP EPH
MADEP EPH NC Water
Associated Lab Samples:92137875001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:869904
Associated Lab Samples:92137875001
Matrix:Water
Analyzed
Aliphatic (C09-C18)ug/L ND 100 N211/14/12 18:26
Aliphatic (C19-C36)ug/L ND 100 N211/14/12 18:26
Aromatic (C11-C22)ug/L ND 100 N211/14/12 18:26
2-Bromonaphthalene (S)%99 40-140 11/14/12 18:26
2-Fluorobiphenyl (S)%88 40-140 11/14/12 18:26
Nonatriacontane (S)%72 40-140 11/14/12 18:26
o-Terphenyl (S)%75 40-140 11/14/12 18:26
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
869905LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
869906
Aliphatic (C09-C18)ug/L 156 N23005240-14066199 24 50
Aliphatic (C19-C36)ug/L 298 N24007440-14079318 6 50
Aromatic (C11-C22)ug/L 569 N28506740-14073616 8 50
2-Bromonaphthalene (S)%85 40-14080
2-Fluorobiphenyl (S)%64 40-14071
Nonatriacontane (S)%79 40-14077
o-Terphenyl (S)%64 40-14069
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 11/15/2012 06:07 PM Page 22 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALIFIERS
Pace Project No.:
Project:
92137875
Agrotec, Inc. Inc#16143
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PRL - Pace Reporting Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
This comment applies to all compounds with a recovery >30%.1g
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold TNI accreditation for this parameter.N2
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 11/15/2012 06:07 PM Page 23 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92137875
Agrotec, Inc. Inc#16143
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92137875001 OEXT/19661 GCSV/13316WSW-4 MADEP EPH MADEP EPH
92137875001 GCV/6401WSW-4 MADEP VPH
92137875001 MPRP/11927 ICP/10914WSW-4 SM 3030C EPA 200.7
92137875001 OEXT/19629 MSSV/6975WSW-4 EPA 625 EPA 625
92137875001 MSV/21051WSW-4 SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 11/15/2012 06:07 PM Page 24 of 24
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]