5002_Jackson_MSWLF_March20GW_FID1414272_20200604

ENR USE,ON_LY: ❑Pa er Report []Electronic Data - Email CD data loaded: Yes / No Doe/Event #:
NC DENR I I Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are 'Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
• Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
• Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
• Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
Anchor QEA of North Carolina, PLLC
Contact for questions about data formatting. Include data preparers name, telephone number and E-mail address:
Name: Alec Macbeth
E-mail: [e-mail]
Phone:[phone]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Jackson County Municipal Solid US Highway 441 58-02 .1600 March 17 through 18, 2020
Waste Landfill Dillsboro, North Carolina 28725
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring ❑ Detection Monitoring QX Assessment Monitoring Corrective Action
T e of data submitted: (Check all that apply)
X Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells X❑
X Leachate monitoring data
X Surface water monitoring data ❑
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Natural Attenuation Parameters
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, 1 have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Alec Macbeth, PG Senior Scientist 828-281-3350
Representative Name (Print) Title (Area Code) Telel
June 4, 2020 Affix
Signature Date
231 Haywood Street, Asheville, North Carolina 28801
Facility Representative Address
P-1649
NC PE Firm License Number (if applicable effective May 1, 2009)
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June 2020 ANCHOR
Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 INZ QEA�""
Spring 2020
Semiannual Water Quality Monitoring Report
Prepared for Jackson County Solid Waste Department

June 2020
Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02
Spring 2020
Semiannual Water Quality Monitoring Report
Prepared for
Jackson County Solid Waste Department
401 Grindstaff Cove Road
Sylva, North Carolina 28779
Alec Macbeth, PG
Project Geologist
Project Number: C91480-01.01
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Prepared by
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
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Text\Semiannual Water Quality Report 060120.docx

TABLE OF CONTENTS
1 Introduction
1
2 Semiannual Monitoring...........................................................................................................2
2.1 Groundwater, Surface Water, Domestic Well, and Leachate Sampling..........................................2
2.1.1 Monitoring Well Purging and Sampling Methods.................................................................2
2.1.2 Surface Water Sampling Methods................................................................................................3
2.1.3 Leachate Sampling Methods..........................................................................................................3
2.1.4 Domestic Well Sampling Methods...............................................................................................4
2.2 Sample Handling, Documentation, and Analysis....................................................................................4
3 Findings........................................................................................................................................6
3.1
Groundwater.........................................................................................................................................................6
3.1.1 Field Parameters..................................................................................................................................7
3.1.2 Appendix I Metals...............................................................................................................................7
3.1.3 Appendix I VOCs and 1,4-Dioxane...............................................................................................8
3.1.4 Natural Attenuation Parameters....................................................................................................9
3.2
Surface Water.......................................................................................................................................................9
3.2.1 Field Parameters..................................................................................................................................9
3.2.2 Appendix I Metals...............................................................................................................................9
3.2.3 Appendix I VOCs and 1,4-Dioxane............................................................................................10
3.3
Leachate...............................................................................................................................................................10
3.4
Domestic Well....................................................................................................................................................10
3.4.1 Field Parameters...............................................................................................................................10
3.4.2 VOCs......................................................................................................................................................11
3.5
Groundwater Flow Directions......................................................................................................................11
4 Summary....................................................................................................................................12
4.1 Groundwater Quality....................................................................................................................................... 12
4.1.1 Appendix I Metals............................................................................................................................ 12
4.1.2 Appendix I Volatile Organic Compounds and 1,4-Dioxane............................................. 12
4.1.3 Field Parameters and Other Constituents............................................................................... 12
4.2 Surface Water Quality..................................................................................................................................... 12
4.3 Leachate Quality............................................................................................................................................... 13
4.4 Domestic Well Water Quality...................................................................................................................... 13
Spring 2020 Semiannual
Water Quality Monitoring Report i June 2020

5 Future Activities.......................................................................................................................14
6 References.................................................................................................................................15
TABLES
Table 1 Summary of Laboratory Analyses Performed on Samples
Table 2 Well Construction Details and Corresponding Elevations
Table 3 Summary of Analytical Results
Table 4 Mass Removal Calculations for Volatile Organic Compounds (VOCs) Detected in
the Leachate Sample (LT-01)
FIGURES
Figure 1 Site Location Map
Figure 2 Site Layout Map
Figure 3 Generalized Groundwater Flow Direction
Figure 4 Hydrograph and 1,4-Dichlorobenzene Concentration vs. Time
(Monitoring Well MW-01)
Figure 5 Hydrograph and Benzene Concentration vs. Time (Monitoring Well MW-01)
Figure 6
Hydrograph and 1,4-Dioxane Concentration vs. Time (Monitoring Well MW-02)
Figure 7
Hydrograph and 1,4-Dichlorobenzene Concentration vs. Time
(Monitoring Well MW-05R)
Figure 8
Hydrograph and 1,4-Dioxane Concentration vs. Time (Monitoring Well MW-05R)
Figure 9
Hydrograph and Benzene Concentration vs. Time (Monitoring Well MW-05R)
Figure 10
Hydrograph and Vinyl Chloride Concentration vs. Time
(Monitoring Well MW-05R)
Figure 11
Hydrograph and 1,4-Dioxane Concentration vs. Time (Monitoring Well MW-07)
Figure 12
Hydrograph and Benzene Concentration vs. Time (Monitoring Well MW-07)
APPENDICES
Appendix A Well Sampling Logs, and Equipment Documentation and Instrument Calibration
Data Sheets
Appendix B Reports of Laboratory Analysis, Chain -of -Custody Documentation,
and Certificates of Analysis
Spring 2020 Semiannual
Water Quality Monitoring Report ii June 2020

ABBREVIATIONS
pg/L micrograms per liter
PS/cm microsiemens per centimeter
AM Analytical Method
bgs below ground surface
BOD biochemical oxygen demand
CAER Corrective Action Evaluation Report
CAP Corrective Action Plan
CFR Code of Federal Regulations
COD chemical oxygen demand
DENR North Carolina Department of Environment and Natural Resources
DEQ North Carolina Department of Environmental Quality
DO dissolved oxygen
DWM Division of Waste Management
EPA U.S. Environmental Protection Agency
IMAC interim maximum allowable concentration
MDL method detection limit
mg/L milligrams per liter
MNA monitored natural attenuation
MSWLF Municipal Solid Waste Landfill
mV millivolts
NCAC North Carolina Administrative Code
NTU nephelometric turbidity unit
ORP oxidation reduction potential
PWR partially weathered rock
SC specific conductivity
Site Closed Municipal Solid Waste Landfill, approximately 0.75 miles west of Dillsboro,
North Carolina, on the northeast side of Old Dillsboro Road (Old U.S. Highway 74)
SM Standard Method
SU standard unit
SWS Solid Waste Section
TOC total organic carbon
TWSA Tuckasegee Water & Sewer Authority
VOC volatile organic compound
Waypoint Waypoint Analytical Laboratories
Spring 2020 Semiannual
Water Quality Monitoring Report iii June 2020

Introduction
The Jackson County Solid Waste Department maintains a closed Municipal Solid Waste Landfill (the
Site) approximately 0.75 mile west of Dillsboro, North Carolina, on the northeast side of
Old Dillsboro Road (Old U.S. Highway 74; Figure 1). Water quality monitoring at the landfill is
governed by the North Carolina Department of Environmental Quality (DEQ), Division of Waste
Management (DWM), Solid Waste Section (SWS), under Permit No. 50-02 issued to Jackson County.
The landfill permit requires semiannual monitoring of groundwater and surface water quality.
Since October 2007, when Anchor QEA of North Carolina, PLLC, began performing water quality
monitoring events at the Site, groundwater quality monitoring has indicated persistent low-level
concentrations of constituents that exceed groundwater quality standards. In response to the
continued exceedances of the analyzed constituents, an Assessment of Corrective Measures was
submitted to the North Carolina Department of Environment and Natural Resources (DENR; now the
DEQ) on September 7, 2010 (Altamont 2010). A Corrective Action Plan (CAP; Altamont 2011) was
implemented upon approval by the DENR, as recorded in the September 1, 2011 letter regarding
"Approval of the County's Corrective Action Plan" (DENR 2011). The implemented remedy includes the
extraction of leachate through dedicated submersible pumps installed within landfill gas extraction
wells and disposal of the leachate into the Tuckasegee Water & Sewer Authority (TWSA) collection
system. In addition to the leachate extraction, groundwater natural attenuation parameters are
monitored, and natural attenuation processes are evaluated. As discussed in the CAP, a corrective
action evaluation report is prepared every 5 years. The evaluation report analyzes the progress of the
approved corrective action remedy based on semiannual water quality monitoring data. The remedy
was implemented in a phased approach, with full implementation occurring on September 6, 2013. The
first Five -Year Corrective Action Evaluation Report (CAER), submitted by Altamont on October 31, 2016
(Altamont 2016), concluded that the current conditions of the monitored natural attenuation (MNA)
parameters and Site geochemical parameters allow for the slow degradation of the select contaminants
identified in the CAER. The second CAER is scheduled to be submitted in the fall of 2021.
This report serves as the first semiannual water quality monitoring report for 2020. The report
provides an evaluation of groundwater and surface water quality. The water quality monitoring
network is presented in Figure 2. The generalized groundwater flow direction in the upper parts of
the underlying aquifer system is provided in Figure 3. In addition to groundwater and surface water
monitoring, this report includes MNA analysis of the extracted leachate and one domestic water well.
The water samples collected from selected monitoring points during the spring sampling event were
analyzed for a range of parameters, as presented in Section 2.2 and Table 1. The spring 2020
sampling event was performed on March 17 and 18, 2020, and is being reported in accordance with
requirements stipulated in the DEQ Solid Waste Management Rules codified under Title 15A,
Subchapter 13B of the North Carolina Administrative Code (NCAC).
Spring 2020 Semiannual
Water Quality Monitoring Report 1 June 2020

2 Semiannual Monitoring
2.1 Groundwater, Surface Water, Domestic Well, and Leachate
Sampling
The Site monitoring wells (MW-01, MW-02, MW-03, MW-04, MW-05R, MW-06, and MW-07), surface
water sample locations (SW-01 and SW-02), leachate sample location (LT-01), and domestic well
(DW-01) were sampled on March 17 and 18, 2020, by Anchor QEA. Static groundwater level
measurements and field parameter data are included on the sampling logs presented in Appendix A.
Field equipment calibration logs for the YSI Professional Plus Multiparameter Water Quality Meter
and the Hach 2100Q Turbidimeter are also provided in Appendix A. The full suite of groundwater
and surface water laboratory analytical results is presented in the laboratory analysis reports in
Appendix B.
Monitoring wells MW-01 and MW-06 are considered to be the Site's upgradient monitoring wells;
MW-03 and MW-05R are located in the midgradient portion of the Site; and MW-02, MW-04, and
MW-07 monitor downgradient portions of the Site. As summarized in Table 2, the total depths of the
monitoring wells range from 40 to 110 feet below ground surface (bgs). The geology of the screened
intervals of the monitoring wells is as follows:
• Saprolite': MW-04 and MW-05R
• Partially Weathered Rock (PWR)Z: MW-03
• Bedrock3: MW-01, MW-02, MW-06, and MW-07
The locations of the monitoring wells, surface water samples, leachate, and domestic well sample
locations are shown in Figure 2.
2. 7. 7 Monitoring Well Purging and Sampling Methods
Before the monitoring wells were sampled, the static water level was gauged in each well, and an
initial round of field parameters was measured (consisting of pH, specific conductivity [SC], dissolved
oxygen [DO], turbidity, temperature, and oxidation reduction potential [ORP]).
Anchor QEA personnel used either low -flow techniques or disposable bailers to purge the
monitoring wells and collect groundwater samples. The total depth, condition of the casing, and
groundwater recharge rate determined the purging and sample collection method employed at each
monitoring well.
Saprolite is the result of in -place weathering that produces soil -like material that retains relict features of the parent rock.
z PWR is generally found above the bedrock and is softer than bedrock, but not as soft as saprolite.
s Bedrock is solid competent rock that underlies saprolite and partially weathered rock.
Spring 2020 Semiannual
Water Quality Monitoring Report 2 June 2020

2.1.1.1 Monitoring Wells
Four of the monitoring wells (MW-03, MW-04, MW-06, and MW-07) were purged using low -flow
techniques in accordance with the procedures described by the U.S. Environmental Protection
Agency (EPA) in Low -Flow (Minimal Drawdown) Ground -Water Sampling Procedures (EPA 1996).
During purging, the field parameters (pH, SC, DO, ORP, turbidity, and temperature) were measured
and recorded approximately every 3 minutes. Well purging continued until these parameters had
generally stabilized for three consecutive readings. The required stabilization criteria are determined
by the EPA Region 4 Science and Ecosystem Support Division in Operating Procedure: Groundwater
Sampling (EPA 2017) and are summarized as follows:
• pH values within ±0.1 standard unit (SU)
• SC values within ±5%
• Temperature, DO, and turbidity values within ±10%
• ORP values within ±10 millivolts (mV)
Once the parameters had stabilized, a groundwater sample was collected by field personnel wearing
a new pair of nitrile gloves, using laboratory -supplied sample containers.
Because of their slow recharge rates, monitoring wells MW-01, MW-02, and MW-05R were purged
and sampled using disposable bailers. The wells were purged of three successive well volumes or
purged dry, whichever occurred first. Monitoring wells MW-5R and MW-02 were purged dry on
March 17 and sampled on March 18, 2020after the wells had had sufficient time to recharge.
Monitoring well MW-01 was purged and sampled on March 18, 2020. A round of field parameters
was measured and recorded at the start of purging and after each consecutive well volume had been
purged.
Field parameter data are shown in the well sampling logs included in Appendix A.
2.1.2 Surface Water Sampling Methods
Surface water samples SW-01 and SW-02 were collected on March 17, 2020, at designated locations
from the Tuckasegee River, which is adjacent to and southwest of the landfill (Figure 2). Sampling
location SW-01 is assumed to represent surface water quality upstream of the landfill, and sampling
location SW-02 is assumed to represent surface water quality downstream of the landfill. One round
of field parameters was measured and recorded at each surface water sampling location immediately
prior to collecting the sample (Appendix A). The surface water samples were collected in
laboratory -provided sample containers by a technician wearing a new pair of nitrile gloves.
2. 7.3 Leachate Sampling Methods
Dedicated bottom -loading air -powered pumps, air pressure lines, and a leachate force main
collection system are installed at the landfill. Pumps are installed in landfill gas extraction wells
Spring 2020 Semiannual
Water Quality Monitoring Report 3 June 2020

EW-1 R, EW-2R, EW-3R, EW-4, EW-5, EW-6, EW-7, EW-8, EW-9, and EW-10. The gas extraction well
locations are presented in Figure 2. The leachate is pumped from the wells into a flow equalization
tank, which is connected to the TWSA wastewater collection system.
The flow equalization tank is east of the landfill, adjacent to the existing landfill gas flare. A grab
sample of leachate (LT-01) was acquired on March 18, 2020, by collecting a sample as the leachate
entered the flow equalization tank. One round of field parameters was measured and recorded after
the sample was collected (Appendix A).
2.7.4 Domestic Well Sampling Methods
The domestic well water sample (DW-01, owned by Mr. Frank Wilkie) was collected on March 18,
2020, from an outside spigot at the residence located at 318 Joe Wilkey Road, bordering the
northern boundary of the landfill (Figure 2). The well was purged of 30 gallons prior to sample
collection. One round of field parameters was measured and recorded after the 30 gallons had been
purged. The domestic well water sample was collected in laboratory -provided sample containers by
field personnel wearing a new pair of nitrile gloves.
Attempts to sample the second domestic water well (DW-2, owned by Mr. Joshua Bulla at
138 Joe Wilkey Road) were unsuccessful because the owner could not be contacted.
2.2 Sample Handling, Documentation, and Analysis
Field parameters and additional observations pertaining to the Site sampling locations are provided
in the sampling logs (Appendix A). Following sample collection, each groundwater, surface water,
leachate, and domestic well water sample was immediately placed on ice in a sample cooler for
transport to Waypoint Analytical Laboratories (Waypoint), a North Carolina -certified laboratory in
Charlotte, North Carolina. The groundwater samples collected from the monitoring wells were
analyzed for the following parameters (Table 1):
• Appendix I metals, including mercury, using EPA Methods 6020B and 7470A
• Appendix I volatile organic compounds (VOCs), using EPA Method 8260D
• 1,4-Dioxane, using EPA Method 8260DSIM
• MNA parameters:
— Alkalinity, using Standard Method (SM) 2320B
— Biochemical oxygen demand (BOD; 5-day), using SM 5210B
— Carbon dioxide, ethane, ethene, and methane, using Analytical Method (AM) 20GAX
— Hydrogen (only in MW-03, MW-04, and MW-07), using AM20GAX
• Hydrogen was not collected in MW-06 because of broken microseep needles
— Chemical oxygen demand (COD), using SM 5220D
— Chloride, nitrate, and sulfate, using EPA Method 9056A
Spring 2020 Semiannual
Water Quality Monitoring Report 4 June 2020

- Ferrous iron, using SM 3500-Fe D
- Sulfide, using SM 4500-5 F
- Total organic carbon (TOC), using SM 5310B
- Volatile fatty acids, using AM23G
The surface water samples were analyzed for the following parameters:
• Appendix I metals, including mercury, using EPA Methods 6020B and 7470A
• Appendix I VOCs, using EPA Method 8260D
• 1,4-Dioxane, using EPA Method 8260DSIM
• Hardness, using SM2340C
The leachate sample was analyzed for the following parameters:
• Appendix I VOCs, using EPA Method 8260D
• 1,4-Dioxane, using EPA Method 8260DSIM
The domestic well sample was analyzed for the following parameters:
• VOCs, using EPA Method 524.2
The SWS issued the memorandum "1,4-Dioxane Analysis, Solid Waste Section Limits, and Laboratory
Analytical Methods" dated May 29, 2018, which requires the analysis of 1,4-dioxane at landfills after
July 1, 2018 (DEQ 2018a). Per this memorandum, 1,4-dioxane was included in the sampling suite for
Site monitoring wells and surface water samples beginning with the October 2018 sampling event.
Appendix I parameters are identified in Appendix I of the Code of Federal Regulations (CFR), Title 40,
Part 258.
Proper chain -of -custody documentation procedures were followed during collection and
transportation of each sample (Appendix B). Two trip blank samples for quality control/quality
assurance purposes were included in the sample coolers and analyzed for Appendix I VOCs when
applicable. The reports of the laboratory analyses are provided in Appendix B. Laboratory analyses
performed on the samples are summarized in Table 1.
Spring 2020 Semiannual
Water Quality Monitoring Report 5 June 2020

3 Findings
The field parameter data and laboratory analytical results for the groundwater samples (from
monitoring wells MW-01 through MW-07), surface water samples (SW-01 and SW-02), leachate
sample (LT-01), and domestic well sample (DW-01) collected at the landfill are included in
Appendices A and B. The results are also submitted separately to the DEQ DWM SWS in the
Electronic Data Deliverable format (DENR 2014).
The laboratory analytical results were reported and appropriately qualified as follows:
• Non -Detections: Non -detections are values reported by the laboratory as less than the method
detection limits (MDLs). They are tabulated in Table 3 and flagged with a "U" qualifier. The MDL is
the minimum concentration of a substance that can be measured and reported by a laboratory
with 99% confidence that the constituent concentration is greater than zero.
• Estimated or "J" Qualified: A "Y' qualifier is used by the laboratory for parameters that are
detected at estimated concentrations greater than the MDL but less than the laboratory's
method reporting limit. The method reporting limit is the minimum concentration of a target
analyte that can be accurately determined by the referenced method.
• Groundwater Quality Standard: Detected concentrations of constituents in groundwater
samples were compared to applicable North Carolina groundwater quality standards. For
most constituents, this standard is the 2L standard, defined in 15A NCAC 2L .0202. Detected
concentrations of analytes in groundwater with no established 2L standard were compared to
the interim maximum allowable concentrations (IMACs) for Class GA and GSA groundwater (in
accordance with 15A NCAC 02L .0202 [c]). For the purposes of this report, groundwater
standards were taken from the October 15, 2018 list published by the North Carolina SWS
(DEQ 2018b).
2B Standard: Detections of analytes in surface water samples were compared to the
surface -water quality standards 2B standards, defined in 15A NCAC 2B. Hardness -dependent
2B surface water standards were calculated using the average analyzed hardness value
(calculated from the upstream and downstream surface water sampling location results) via
the most stringent hardness -dependent metal calculation.
Table 3 summarizes detected concentrations of analytes that exceeded their respective 2L standard,
IMAC, or 2B standard.
3.1 Groundwater
Measured field parameters and analytical results for groundwater samples collected from the
monitoring wells during the spring 2020 sampling event are discussed in the following sections and
summarized in Table 3.
Spring 2020 Semiannual
Water Quality Monitoring Report 6 June 2020

3.7. 7 Field Parameters
Field parameter measurements were obtained from monitoring wells MW-01, MW-02, MW-03,
MW-04, MW-05R, MW-06, and MW-07. The pH readings ranged from 5.14 SU in MW-06 to 7.12 SU
in MW-05R. Of these monitoring wells, the pH values for MW-01, MW-02, MW-04, MW-06, and
MW-07 were less than the 2L Standard pH range of 6.5 to 8.5 SU.
The measured turbidity was measured at 0.61 to 98.9 nephelometric turbidity units (NTU). Generally,
the higher values were measured at the monitoring wells (MW-1, MW-02, and MW-05R) that were
purged and sampled using the bailer method (Section 2.1.1). The bailers were lowered gently to
minimize water column disturbance when the samples were collected. The lowest turbidity
(0.61 NTU) was measured in the groundwater sample collected from monitoring well MW-04.
Dissolved oxygen (DO) concentrations at the Site ranged from 0.82 milligram per liter (mg/L) in
monitoring well MW-07 to 8 mg/L in monitoring well MW-03. SC concentrations at the Site ranged
from 56.4 microsiemens per centimeter (pS/cm) in monitoring well MW-06 to 756 pS/cm in
monitoring well MW-07. ORP concentrations at the Site ranged from -96.1 mV in monitoring well
MW-05R to 506.2 mV in monitoring well MW-04. Groundwater standards are not established for DO,
SC, or ORP.
These measured field parameter values are consistent with historical data.
3.7.2 Appendix 1 Metals
Eleven metals (arsenic, barium, cadmium, chromium, cobalt copper, lead, nickel, selenium, vanadium,
and zinc) were detected in the monitoring well samples. Two of these metals, cobalt and vanadium,
were detected at concentrations that exceeded their respective IMAC water quality standards in the
groundwater samples collected from one or more of the monitoring wells during the spring 2020
water quality monitoring event.
Cobalt was detected at a concentration that exceeded its IMAC (1 microgram per liter [pg/L]) in
groundwater samples collected from each of the monitoring wells. Cobalt concentrations in these
samples ranged from an estimated 1.5 pg/L (MW-07) to 130 pg/L (MW-01). As noted in Section 2.1,
the latter monitoring well is considered to represent upgradient conditions. The second upgradient
well (MW-06) also showed an exceedance of cobalt (6.9 pg/L). Historically, cobalt has been present at
concentrations that exceed its applicable water quality standard in groundwater samples from each
of the seven monitoring wells.
Vanadium was detected in the groundwater samples collected from MW-02 (13 pg/L) and MW-05R
(estimated at 3.1 pg/L) at levels exceeding its IMAC standard of 0.3 pg/L. Historically, vanadium has
been present at concentrations that exceed its water quality standard in samples collected from
multiple groundwater monitoring wells at the Site.
Spring 2020 Semiannual
Water Quality Monitoring Report 7 June 2020

3.1.3 Appendix 1 VOCs and 1,4-Dioxane
Thirteen VOCs (1,1-dichloroethane; cis-1,2-dichloroethene; 1,4-dichlorobenzene; 1,4-dioxane;
2-hexanone; acetone; benzene; chlorobenzene; m,p-xylene; tetrachloroethene; tetrahydrofuran;
trichloroethene; and vinyl chloride) were detected in one or more of the monitoring wells. Four of these
VOCs (1,4-dichlorobenzene; 1,4-dioxane; benzene; and vinyl chloride) were detected at concentrations
that exceeded their respective 2L standards in the groundwater samples collected from one or more
monitoring wells. Concentration -versus -time graphs (trend plots) were created for the monitoring wells
that have historically exhibited VOC concentrations that exceed the associated 2L standards (Figures 4
through 12).
The detected concentration of 1,4-dichlorobenzene exceeded its 2L standard (6 pg/L) in monitoring
wells MW-01 (10 pg/L) and MW-05R (6.6 pg/L). The historical 1,4-dichlorobenzene concentration
trend in MW-01 remains relatively stable (Figure 4).
The detected concentrations of 1,4-dioxane equaled or exceeded its 2L standard (3 pg/L) in MW-02
(3.6 pg/L) , MW-04 (3 pg/L), MW-05R (4.9 pg/L), and MW-07 (17 pg/L). 1,4-Dioxane was not detected
in monitoring wells MW-01, MW-03 or MW-06. Trend plots for 1,4-dioxane concentrations in MW-2,
MW-05R, and MW-07 show stable concentrations (Figures 6, 8, and 11).
Benzene was detected at concentrations that slightly exceed the 2L standard of 1 pg/L in three
monitoring wells: MW-01 (1.4 pg/L), MW-05R (2.1 pg/L), and MW-07 (1.1 pg/L). Overall, historical
benzene concentration trends in monitoring wells MW-01, MW-05R, and MW-07 have been stable
and slightly exceed the 2L standard (Figures 5, 9, and 12).
The concentration of vinyl chloride in the sample collected from one monitoring well, MW-05R,
(2.5 pg/L) exceeded the compound's 2L standard (0.03 pg/L). A trend plot for vinyl chloride
concentrations in MW-05R is presented in Figure 10 and shows slightly higher concentrations of the
compound relative to the October 2016 to October 2018 time frame. Vinyl chloride was not detected
in the other monitoring wells during this sampling event (Table 3). Historically, vinyl chloride has
exceeded its 2L standard in monitoring wells MW-04, MW-05R, and MW-07, located in the
southwestern part of the landfill.
A review of historical groundwater data indicates that the VOCs (1,4-dichlorobenzene; 1,4-dioxane,
benzene; and vinyl chloride) exhibiting concentrations that exceed the 2L standards during the
spring 2020 sampling event have been detected at relatively consistent concentrations for the past
several years. As described in Section 3.2.3, historical surface water samples from the Tuckasegee
River, which likely receives discharge from the saprolite groundwater -bearing zone, have consistently
shown no detections of these compounds, or other VOCs.
Spring 2020 Semiannual
Water Quality Monitoring Report 8 June 2020

3.7.4 Natural Attenuation Parameters
During this sampling event, the groundwater samples were analyzed for MNA parameters as
described in Section 2.2 (Table 1). The results of these analyses are summarized in Table 3. These
parameters were detected in one or more groundwater samples collected from the monitoring wells.
Many of these parameters do not have established groundwater standards. Of the parameters that
do have established groundwater standards, chloride and sulfate, there were no exceedances. An in-
depth analysis of the MNA parameters that apply to the Site's select contaminants was presented in
the first Five -Year CAER (Altamont 2016). The CAER concluded that the MNA data provide evidence
that reductive degradation and aerobic degradation are occurring in different portions of the Site.
The current data on the MNA parameters will be used in the second Five -Year CAER (scheduled for
fall 2021) to evaluate the degradation processes at the Site.
3.2 Surface Water
The following sections summarize the measured field parameters and analytical results associated
with the two surface water samples collected during the spring 2020 sampling event.
3.2.7 Field Parameters
The pH readings for the upstream (SW-1) and downstream (SW-2) surface water samples collected
during the spring 2020 sampling event were 7.31 and 7.27 SU, respectively. The pH readings for both
surface water samples were within the 2B standard range of 6 to 9 SU.
The turbidity values measured in SW-01 (40.1 NTU) and SW-02 (40.3 NTU) were less than the
2B standard, which is established at less than or equal to 50 NTU for the receiving water in streams
not designated as trout waters. The samples were collected about 1 hour after a heavy rain event.
DO was measured at a concentration of 13.02 mg/L in SW-01 and 10.63 mg/L in SW-02. The
2B standard is established as greater than or equal to 6 mg/L; thus, each sample is within the
acceptable DO range.
SC concentrations in surface water samples SW-01 and SW-02 were recorded at 39.1 and
33.5 pS/cm, respectively. ORP values for SW-01 and SW-02 were 145.9 and 171.7 mV, respectively.
These concentrations of SC and ORP are consistent with historical data for both surface water
samples. 2B standards do not exist for these parameters.
3.2.2 Appendix 1 Metals
Seven metals (barium, chromium, cobalt, lead, nickel, vanadium, and zinc) were detected in both
surface water sampling locations. Of these metals, only one (lead) was detected at a concentration
that slightly exceeded its 2B standard of 0.2 pg/L. Lead was detected in SW-1 at 1.8 pg/L and SW-2
at 1.4 pg/L.
Spring 2020 Semiannual
Water Quality Monitoring Report 9 June 2020

3.2.3 Appendix 1 VOCs and 1,4-Dioxane
No VOCs were detected in either of the surface water sampling locations.
3.3 Leachate
Ten VOCs (1,4-dichlorobenzene [5.6 pg/L]; 1,4-dioxane [60 pg/L]; methyl isobutyl ketone [estimated
0.79 pg/L]; acetone [6.4 pg/L]; benzene [1.3 pg/L]; chlorobenzene [3.2 pg/L]; ethylbenzene [2.7 pg/L];
m,p-xylenes [estimated 0.89 pg/L]; o-xylene [1.2 pg/L]; and toluene [0.7 pg/L]) were detected in the
leachate sample (LT-01).
On September 1, 2012, leachate extraction was initiated following installation of leachate extraction
pumps in the 10 landfill gas extraction wells at the Site (Figure 2). Due to a temporary malfunction
with the leachate flow meter between October 2017 and March 2018, there is a gap in the mass
removal calculations represented in Table 4. Therefore, the total volume of leachate removed since
September 2012 is not known. However, based on readings taken from the leachate totalizer during
the March 2020 monitoring events, approximately 94,032 gallons of leachate were discharged
through a permanent connection to the TWSA between October 22, 2019 and March 18, 2020
(Table 4).
In fall 2013, the active portion of the approved corrective action remedy was initiated. Based on the
leachate analytical results for the sample collected on March 18, 2020, Anchor QEA estimates that
approximately 0.06 pound of VOCs was removed with the extracted leachate between the
October 2019 and the March 2020 sampling events. Mass removal calculations are included in
Table 4.
3.4 Domestic Well
The following sections summarize measured field parameters and analytical results associated with
the domestic well water sample collected during the spring 2020 sampling event.
3.4. 7 Field Parameters
The pH reading for the domestic well sample (DW-01) was 6.99 SU, which is within the 2L standard
range of 6.5 to 8.5 SU.
Turbidity measured in DW-01 was 4.3 NTU. DO was measured at a concentration of 4.96 mg/L in
DW-01. SC and ORP values in DW-01 were recorded at 78 pS/cm and 68.7 mV, respectively. These
parameters do not have established water quality standards.
Spring 2020 Semiannual
Water Quality Monitoring Report 10 June 2020

3.4.2 VOCs
No VOCs were detected at concentrations that exceeded their respective MDLs in the domestic well
water samples.
3.5 Groundwater Flow Directions
Groundwater levels in the saprolite, PWR, and bedrock are monitored at the Site. Three of the
bedrock monitoring wells (MW-01, MW-02, and MW-06) are located in the northern and
northwestern portions of the Site (Figure 3; Table 2). The fourth bedrock monitoring well (MW-07) is
located southwest of the landfill (Figure 3). The spring 2020 water level data collected from these
four bedrock wells were used to determine the generalized bedrock groundwater flow direction,
which is to the southwest (Figure 3).
PWR monitoring well MW-03 and saprolite monitoring wells MW-04 and MW-05R (Figure 3) are
located in the south-central and southern parts of the landfill, respectively. The spring 2020 water
level data collected from monitoring wells MW-03, MW-04, and MW-05R (Table 2) indicate that
groundwater flow direction in the combined saprolite and PWR zones is generally to the south-
southwest, toward the Tuckasegee River (Figure 3).
Spring 2020 Semiannual
Water Quality Monitoring Report 11 June 2020

4 Summary
The first semiannual water quality monitoring event of 2020 for the Site was performed on March 17
and 18, 2020. Appendices A and B and Table 3 provide detailed analytical results and field data
summarizing the groundwater, surface water, and leachate quality at the landfill.
4.1 Groundwater Quality
4. 7.1 Appendix 1 Metals
Two metals (cobalt and vanadium) were detected at concentrations that exceeded their associated
groundwater quality standards in one or more of the monitoring wells (Table 3). Cobalt
concentrations exceeded its 2L standard in all of the collected groundwater samples, including the
upgradient monitoring wells, MW-01 and MW-06. These results are consistent with historical data.
4. 7.2 Appendix 1 Volatile Organic Compounds and 1,4-Dioxane
Four VOCs (1,4-dichlorobenzene; benzene; vinyl chloride; and 1,4-dioxane) were detected at
concentrations that exceeded their respective 2L standards (Table 3) in one or more monitoring
wells, including 1,4-dichlorobenzene and benzene in the upgradient monitoring well MW-01.
Concentration -versus -time graphs were created for samples from monitoring wells that had VOC
concentrations that exceeded their 2L standards. The graphs are provided as Figures 4 through 12.
4. 7.3 Field Parameters and Other Constituents
Five of the seven of the samples collected from the monitoring wells had pH readings outside of the
2L standard range (6.5 to 8.5 SU). These results are consistent with historical data and are
characteristic of the natural groundwater quality of the region. Turbidity readings ranged from
0.61 NTU (MW-04) to 98.9 NTU (MW-05R).
Natural attenuation parameters (alkalinity, BOD, chloride, carbon dioxide, hydrogen, ferrous iron,
methane, nitrate, sulfate, and TOC) were detected at various concentrations in groundwater samples
collected from one or more of the monitoring wells. Natural attenuation parameters are being
monitored to fulfill CAP requirements; further evaluation of these parameters will be performed in
the second Five -Year CAER (scheduled for fall 2021).
4.2 Surface Water Quality
One metal, lead, was detected at a concentration that exceeded its applicable 2B standard for surface
water during this monitoring event. Concentrations in the upstream sample exceeded concentrations
in the downstream sample for all metals that were detected. No VOCs were detected at
concentrations that exceeded the applicable surface water standards. Field parameters measured in
both surface water samples, including pH, turbidity, and DO, were within the 2B standards
Spring 2020 Semiannual
Water Quality Monitoring Report 12 June 2020

established for these parameters. Based on these data, the groundwater migrating from the landfill
toward the Tuckasegee River does not appear to be impacting surface water quality with regard to
metals and VOCs.
4.3 Leachate Quality
The leachate sample (LT-01) was collected from the flow equalization tank and analyzed for
Appendix I VOCs and 1,4-dioxane. Ten VOCs were detected in the leachate sample (Table 3). There
are no established water quality standards for leachate. 1,4-Dioxane was detected at 60 pg/L, which
is higher than the detected concentrations of the compound in the monitoring well groundwater
samples. This is the first sampling event where 1,4 dioxane was analyzed for in the leachate.
4.4 Domestic Well Water Quality
No VOCs were detected at concentrations that exceeded their respective MDLs in the domestic well
water samples.
Spring 2020 Semiannual
Water Quality Monitoring Report 13 June 2020

5 Future Activities
Anchor QEA will continue to monitor the water quality on a semiannual basis at the Site. During fall
2020, domestic well owners will be contacted, and groundwater samples will be collected from
domestic wells if permitted by the well owner, and if possible, based on well pump operability.
Domestic well samples will be analyzed for VOCs only. Samples will be collected from the monitoring
wells, surface water monitoring points, and leachate flow equalization tank during fall 2020 and
spring 2021. In addition to the MNA parameters that were added to the monitoring requirements as
part of the CAP, the analytical suites associated with the current and future sampling events are
outlined in the 2011 CAP (Altamont 2011) and the first Five -Year CAER (Altamont 2016). The
upcoming sampling event parameters are as follows:
Analytical Suite
Sampling Event (not inclusive of natural attenuation parameters)
Appendix II VOCs (including 1,4-dioxane)
Appendix II Metals
Fall 2020 Appendix II Herbicides
Appendix II Pesticides
Appendix II Semi -Volatile Organic Compounds (SVOCs)
Sulfide
Appendix I VOCs (including 1,4-dioxane)
Spring 2021 Appendix I Metals
Sulfide
Spring 2020 Semiannual
Water Quality Monitoring Report 14 June 2020

6 References
Altamont (Altamont Environmental, Inc.), 2010. Assessment of Corrective Measures. Prepared for the
North Carolina Department of Environment and Natural Resources. September 7, 2010.
Altamont, 2011. Corrective Action Plan. Prepared for the North Carolina Department of Environment
and Natural Resources. June 30, 2011.
Altamont, 2016. Five -Year Corrective Action Evaluation Report. Prepared for the North Carolina
Department of Environmental Quality. October 31, 2016.
DENR (North Carolina Department of Environmental and Natural Resources), 2011. Letter to:
Altamont Environmental, Inc. Regarding: Approval of the County's Corrective Action Plan.
September 1, 2011.
DENR, 2014. Memorandum Re: Groundwater, Surface Water, Soil, Sediment, and Landfill Gas
Electronic Document Submittal, November 5, 2014.
DEQ (North Carolina Department of Environmental Quality), 2018a. Memorandum to: Solid Waste
Directors, Landfill Owners/Operators, and North Carolina Certified Laboratories. Regarding:
1,4-Dioxane Analysis, Solid Waste Section Limits, and Laboratory Analytical Methods.
May 29, 2018.
DEQ, 2018b. "Groundwater Protection Compliance Standards — Constituents List". Last modified
October 15, 2018. Available at:
https://edocs.deq.nc.gov/WasteManagement/0/edoc/l 257181/SWS_EnviroMonitoring_Const
ituents_List.pdf?searchid=13f8efbl -eel l-485a-b03f-718f2287b271
EPA (U.S. Environmental Protection Agency), 1996. Low -Flow (Minimal Drawdown) Ground -Water
Sampling Procedures. OSWER, EPA/540/5-95/504.
EPA, 2017. Science and Ecosystem Support Division. Operating Procedure: Groundwater Sampling.
April 26, 2017.
Spring 2020 Semiannual
Water Quality Monitoring Report 15 June 2020

Tables

Table 1
Summary of Laboratory Analyses Performed on Samples
Groundwater Samples
Location ID
Date
Collected
Sample ID
Appendix I VOCs
1,4-Dioxane
Appendix I
Metals
Mercury
COD
EPA 8260D
EPA 8260D SIM
EPA 6020B
EPA 7470A
SM 5220D
MW-01
03/18/2020
MW-01-20200318
X
X
X
X
X
MW-02
03/18/2020
MW-02-20200318
X
X
X
X
X
MW-03
03/17/2020
MW-03-20200317
X
X
X
X
X
MW-04
03/17/2020
MW-04-20200317
X
X
X
X
X
MW-05R
03/18/2020
MW-05R-20200318
X
X
X
X
X
MW-06
03/18/2020
MW-06-20200318
X
X
X
X
X
MW-07
03/17/2020
MW-07-20200317
X
X
X
X
X
Surface Water, Leachate, Domestic Well, and Quality Control Samples
Location ID
Date
Collected
Sample ID
Appendix I
Metals
Mercury
Hardness
Appendix I VOCs
1,4-Dioxane
VOCs
EPA 6020B
EPA 7470A
SM2340 C
EPA 8260D
EPA 8260D SIM
EPA 524.2
DW-01
03/18/2020
DW-01-20200318
X
SW-01
03/17/2020
SW-01-20200317
X
X
X
X
X
SW-02
03/17/2020
SW-02-20200317
X
X
X
X
X
LT-01
03/18/2020
LT-01-20200318
X
X
TB-01
03/17/2020
TB-20200317
X
TB-02
03/18/2020
TB-20200318
X
Groundwater Samples: Natural Attenuation Parameters
Location ID
Date
Collected
Sample ID
BOD
Ferrous Iron
Total Alkalinity
to pH 4.5
Nitrate
as N
Chloride
Sulfate
TOC
Sulfide
Volatile Fatty
Acids
Carbon Dioxide
Ethane, Ethene,
Methane
Dissolved
Hydrogen
SM 5210B
SM 3500-Fe D
SM 2320B
EPA 9056A
SM 5310B
SM4500-S F
AM23G
AM20GAX
MW-01
03/18/2020
MW-01-20200318
X
X
X
X
X
X
X
X
X
X
X
MW-02
03/18/2020
MW-02-20200318
X
X
X
X
X
X
X
X
X
X
X
MW-03
03/17/2020
MW-03-20200317
X
X
X
X
X
X
X
X
X
X
X
X
MW-04
03/17/2020
MW-04-20200317
X
X
X
X
X
X
X
X
X
X
X
X
MW-05R
03/18/2020
MW-05R-20200318
X
X
X
X
X
X
X
X
X
X
X
MW-06
03/18/2020
MW-06-20200318
X
X
X
X
X
X
X
X
X
X
X
MW-07
03/17/2020
MW-07-20200317
X
X
X
X
X
X
X
X
X
X
X
X
Notes:
Appendix I constituents were analyzed per Title 40 Code of Federal Regulations, Part 258.
Blank cell: Analysis was not performed on that sample.
AM: Analytical Method
BOD: biochemical oxygen demand
COD: chemical oxygen demand
EPA: U.S. Environmental Protection Agency (method)
SIM: Selective Ion Monitoring
SM: Standard Method
TB: Trip Blank
TOO total organic carbon
VOC: volatile organic compound
Spring 2020 Semiannual Water Quality Monitoring Report Page 1 of 1
Jackson County Closed Municipal Solid Waste Landfill June 2020

Table 2
Well Construction Details and Corresponding Elevations
Stick Up
Depth to
Depth to
Elevation of
Ground
(feet
Depth To
Approximate
Approximate
Top of
Bottom of
Top Elevation
Bottom of
Surface
TOC
above
Total Well
Water
Depth to
Top of Bedrock
Screened
Screened
of Screened
Screened
Geology of
Source of Well
Facility
Elevation
Elevation
ground
Depth
(feet below
Groundwater
Bedrock
Elevation
Interval
Interval
Interval
Interval
Screened
Construction
Permit
Well ID
Date Drilled
(feet)
(feet)
surface)
(feet bgs)
TOC)
Elevation (feet)
(feet bgs)
(feet)
(feet bgs)
(feet bgs)
(feet)
(feet)
Interval
Information
MW-01
04/23/1992
2,169.40
1 2,171.42
2.0
110.5
96.54
2,074.88
83.0
2,086.40
95.0
1 110.0
2,074.40
2,059.40
Bedrock
MW-02
04/22/1992
2,013.15
2,015.38
2.3
60.7
36.50
1,978.88
13.0
2,000.15
45.0
60.0
1,968.15
1,953.15
Bedrock
Partially
S&ME, Inc.
MW-03
04/21/1992
2,044.16
2,045.53
1.3
65.5
40.44
2,005.09
57.0
1,987.16
48.5
63.5
1,995.66
1,980.66
50-02
Weathered Rock
MW-04
04/21/1992
1,978.68
1,980.77
2.0
43.0
25.00
1,955.77
NA
NA
25.0
40.0
1,953.68
1,938.68
Saprolite
MW-05R
01/26/2012
2,027.98
2,030.95
2.8
54.0
45.31
1,985.64
NA
NA
44.0
54.0
1,983.98
1,973.98
Saprolite
MW-06
03/23/2004
2,136.58
2,139.57
3.0
94.0
76.97
2,062.60
47.6
2,088.98
84.6
94.6
2,051.98
2,041.98
Bedrock
Altamont
Environmental, Inc.
MW-07
07/30/2010
1,978.71
1,981.29
2.6
95.0
33.19
1,948.10
44.0
1,935.00
70.0
95.0
1,908.71
1,883.71
Bedrock
Notes:
Elevations associated with wells MW-01, MW-02, MW-03, MW-04, and MW-06 are measured relative to mean sea level and are based on surveying completed by Davenport & Associates, Inc.
Elevations associated with wells MW-05R and MW-07 are measured relative to horizontal North American Datum 83 and are based on surveying completed by Wes Cole Land Surveyinq, PA.
Depth to water was measured on March 17 and 18, 2020 (Appendix A).
Depth to bedrock and screened interval for MW-01 through MW-04 was taken from S&ME, Inc., boring logs completed April 21 through 23, 1992.
Depth to bedrock and screened interval for MW-06 was taken from an Altamont Environmental, Inc., boring log completed March 23, 2004.
Depth to bedrock and screened interval for MW-07 was taken from an Altamont Environmental, Inc., boring log completed July 30, 2010.
Depth to bedrock and screened interval for MW-05R was taken from an Altamont Environmental, Inc., borinq loq completed January 26, 2012.
Monitoring well MW-05 was abandoned on January 26, 2012, by NYEG Drilling, LLC. Monitoring well MW-05R was installed by NYEG Drilling, LLC, on January 26, 2012, as a replacement to MW-05.
Monitorinq well MW-05R was surveyed by Wes Cole Land Surveyinq, PA, on September 28, 2012.
bgs: below ground surface
NA: not applicable
TOC: top of casing
Spring 2020 Semiannual Water Quality Monitoring Report Page 1 of 1
Jackson County Closed Municipal Solid Waste Landfill June 2020

Table 3
Analytical Summary
Domestic Well
Sample
Leachate Sample
Monitoring Well Samples
Location ID
DW-01
LT-01
MW-01
MW-02
MW-03
MW-04
MW-05R
Sample ID
DW-01-20200318
LT-01-20200318
MW-01-20200318
MW-02-20200318
MW-03-20200317
MW-04-20200317
MW-05R-20200318
Sample Date
3/18/2020
3/18/2020
3/18/2020
3/18/2020
3/17/2020
3/17/2020
3/18/2020
Sample Type
N
N
N
N
N
N
N
Matrix
WG
WG
WG
WG
WG
WG
WG
Method
NC2L
�NUL IMAC
NC213
Conventional Parameters (ft)
Water Level Depth Field Measure -- -- 96.54 36.5 40.44 25 45.31
Conventional Parameters
Temperature (field) (°C)
Field Measure
15.1
15.1
16.1
14.5
14.7
14.5
18
pH (field) (SU)
Field Measure
6.5-8.5
6-9
6.99
7
6.05
6.09
6.79
5.84
7.12
Turbidity (field) (NTU)
Field Measure
50
4.3
5.1
10.2
15.5
10.8
0.61
98.9
Dissolved oxygen (field)
Field Measure
>_6
4.96
2.58
2.94
5.44
8.00
2.02
1.5
Specific Conductivity (field) (pS/cm)
Field Measure
78
4052
182.3
223.4
339.5
524.1
676
ORP (mV)
i Field Measure
68.7
-66
21.6
261.9
242.1
r 506.2
-96.1
Monitored Natural Attenuation Results
Total organic carbon (p /L)
SM5310B
--
--
9.07
2.97
6.16
5.85
20.9
Acetic acid
AM23G
--
--
49 J
440
48 J
43 U
210
Biochemical oxygen demand (m /L)
SM5210B
--
--
10
2.5
0.3 J
0.21 U
6.5
Carbon dioxide (m /L)
AM20GAX
--
--
270 N
60 N
49 N
220 N
56 N
Chemical oxygen demand (m /L)
SM5220C
--
--
38 J
22 J
22 J
74
85
Chloride (m /L)
SW9056A
250
--
--
1.1
29
15
30
53
Ethane (m /L)
AM20GAX
--
--
0.000088 JN
0.000005 UN
0.000005 UN
0.000018 JN
0.00034 N
Ethene (m /L)
AM20GAX
--
--
0.000056 JN
0.0000082 JN
0.000013 JN
0.000004 UN
0.00018 N
Ferrous iron
SM3500FEB
--
--
35000
59 J
51 U
51 U
1500
Formic acid
AM23G
--
--
120 U
120 U
120 U
120 U
120 J
Hardness as CaCO3 (mg/L)
SM2340C
--
--
--
--
--
--
--
Methane (mg/L)
AM20GAX
--
--
2.7 N
0.0001 JN
0.0002 JN
0.083 N
4.8 N
Nitrate as nitrogen (mg/L)
SW9056A
10
--
--
0.054 U
0.53
0.43
8.3
0.059 J
Pentanoic acid
AM23G
--
--
5 U
5 U
5 U
5 U
5 U
Propionic acid
AM23G
--
--
5.7 J
15 J
4.5 J
3 J
27 J
Sulfate (mg/L)
SW9056
250
--
--
0.48 U
15
1 6.2
1 110
0.48 U
Appendix I Metals (Ng/L)
Arsenic
SW6020
10
10
--
--
0.34 U
1.5
0.37 J
0.34 U
0.51 J
Barium
SW6020
700
21000
--
--
120
75
130
83
110
Cadmium
SW6020
2
*0.08
--
--
0.22 U
0.22 U
0.22 U
0.23 J
0.33 J
Chromium
SW6020
10
*11.70
--
--
0.9 U
9.7
1.7 J
0.9 U
3.1
Cobalt
SW6020
1
--
--
130
14
1.8 J
1.7 J
8.2
Copper
SW6020
1000
*1.31
--
--
4.7 U
9.1 J
5 J
4.7 U
5.1 J
Lead
SW6020
15
*0.20
--
--
0.44 U
2.8
0.44 U
0.44 U
1.1
Nickel
SW6020
100
*7.73
--
--
15
6.4
1.2 J
0.83 U
4.4
Selenium
SW6020
20
5
--
--
0.98 U
6
0.98 U
1.3 J
1.5 J
Vanadium
SW6020
0.3
--
--
7.5 U
13
7.5 U
7.5 U
3.1 J
Zinc
SW6020
1000
*17.36
--
--
10 U
29
1 10 U
10 U
17 J
Spring 2020 Semiannual Water Quality Monitoring Report Page 1 of 5
Jackson County Closed Municipal Solid Waste Landfill June 2020

Table 3
Analytical Summary
Domestic Well
Sample
Leachate Sample
Monitoring Well Samples
Location ID
DW-01
LT-01
MW-01
MW-02
MW-03
MW-04
MW-05R
Sample ID
DW-01-20200318
LT-01-20200318
MW-01-20200318
MW-02-20200318
MW-03-20200317
MW-04-20200317
MW-05R-20200318
Sample Date
3/18/2020
3/18/2020
3/18/2020
3/18/2020
3/17/2020
3/17/2020
3/18/2020
Sample Type
N
N
N
N
N
N
N
Matrix
WG
WG
WG
WG
WG
WG
WG
Method
NUL
�NUL IMAC
NC213
Atmenclix
I Volatile Orcianics and 1 4-Dioxane L
1,1-Dichloroethane
SW8260
6
100
--
0.29 U
2.7
0.3 J
0.29 U
0.29 U
0.29 U
1,2-Dichloroethene, cis-
SW8260
70
720
--
0.4 U
5.1
0.4 U
0.4 U
0.4 U
1.8
1,4-Dichlorobenzene
SW8260
6
56
--
5.6
10
0.42 U
0.42 U
1.3
6.6
1,4-Dioxane
SW8260
3
--
60
0.14 U
3.6
0.14 U
3
4.9
2-Hexanone (Methyl butyl ketone)
SW8260
40
--
0.29 U
16
0.29 U
0.29 U
0.29 U
0.29 U
4-Meth I-2-pentanone (Methyl isobut I ketone)
SW8260
100
26000
--
0.79 J
0.4 U
0.4 U
0.4 U
0.4 U
0.4 U
Acetone
SW8260
6000
2000
--
6.4
7.3
0.7 U
0.7 U
0.7 U
2.7 J
Benzene
SW8260
1
51
--
1.3
1.4
0.34 U
0.34 U
0.34 U
2.1
Chlorobenzene
SW8260
50
140
--
3.2
1.8
0.34 U
0.34 U
0.86
8.1
Eth (benzene
SW8260
600
97
--
2.7
0.31 U
0.31 U
0.31 U
0.31 U
0.31 U
m,p-X lene
SW8260
500
550
--
0.89 J
0.87 J
0.73 U
0.73 U
0.73 U
0.73 U
o-X lene
SW8260
500
400
--
1.2
0.4 U
0.4 U
0.4 U
0.4 U
0.4 U
Tetrachloroethene (PCE)
SW8260
0.7
3.3
--
0.31 U
0.48 J
0.31 U
0.31 U
0.31 U
0.31 U
Tetrah drofuran
SW8260
--
--
--
--
0.68 U
0.68 U
--
Toluene
SW8260
600
0.36
--
0.7
0.35 U
0.35 U
0.35 U
0.35 U
0.35 U
Total X lene
SW8260
--
2
1.1 U
1.1 U
1.1 U
1.1 U
1.1 U
Trichloroethene (TCE)
SW8260
3
30
--
0.46 U
0.61
0.46 U
0.46 U
0.46 U
0.46 U
Vinyl chloride
SW8260
0.03
2.4
--
0.47 U
0.47 U
0.47 U
0.47 U
0.47 U
2.5
Spring 2020 Semiannual Water Quality Monitoring Report Page 2 of 5
Jackson County Closed Municipal Solid Waste Landfill June 2020

Table 3
Analytical Summary
Surface Water Samples
QC Samples
Location ID
MW-06
MW-07
SW-01
SW-02
FieIdQC
FieIdQC
Sample ID
MW-06-20200318
MW-07-20200317
SW-01-20200317
SW-02-20200317
TB-20200317
TB-20200318
Sample Date
3/18/2020
3/17/2020
3/17/2020
3/17/2020
3/17/2020
3/18/2020
Sample Type
N
N
N
N
TB
TB
Matrix
WG
WG
WS
WS
WQ
WQ
Method
NC2L
NC2L IMAC
NC213
Conventional Parameters (ft)
Water Level Depth Field Measure
76.97
33.19
--
--
--
--
Conventional Parameters
Temperature (field) (°C)
Field Measure
14.3
15.1
12
12.3
--
--
pH (field) (SU)
Field Measure
6.5-8.5
6-9
5.14
6.08
7.31
7.27
--
--
Turbidity (field) (NTU)
Field Measure
50
1.44
2.98
40.1
40.3
--
--
Dissolved oxygen (field)
Field Measure
>_6
5.81
0.82
1 13.02
10.63
--
--
Specific Conductivity (field) (pS/cm)
Field Measure
56.4
756
39.1
33.5
--
--
ORP (mV)
Field Measure
279
174.2
145.9
171.7
--
--
Monitored Natural Attenuation Results
Total organic carbon (p /L)
SM5310B
3.34
7.11
--
--
--
--
Acetic acid
AM23G
43 U
43 U
--
--
--
--
Biochemical oxygen demand (m /L)
SM5210B
0.54 J
0.21 U
--
--
--
--
Carbon dioxide (m /L)
AM20GAX
280 N
360 N
--
--
--
--
Chemical oxygen demand (m /L)
SM5220C
10 U
191
--
--
--
--
Chloride (m /L)
SW9056A
250
1
79
--
--
--
--
Ethane (m /L)
AM20GAX
0.000005 UN
0.00011 N
--
--
--
--
Ethene (m /L)
AM20GAX
0.000043 JN
0.000093 JN
--
--
--
--
Ferrous iron
SM3500FEB
51 U
51 U
--
--
--
--
Formic acid
AM23G
120 U
120 U
--
--
--
--
Hardness as CaCO3 (mg/L)
SM2340C
--
--
11
10
--
--
Methane (mg/L)
AM20GAX
0.0037 N
0.28 N
--
--
--
--
Nitrate as nitrogen (mg/L)
SW9056A
10
0.15 J
0.094 J
--
--
--
--
Pentanoic acid
AM23G
5 U
16 J
--
--
--
--
Propionic acid
AM23G
3.2 J
2.3 J
--
--
--
--
Sulfate (mg/L)
SW9056
250
0.56 J
28
--
--
--
--
Appendix I Metals (Ng/L)
Arsenic
SW6020
10
10
0.34 U
0.34 U
0.34 U
0.34 U
--
--
Barium
SW6020
700
21000
47
460
42
34
--
--
Cadmium
SW6020
2
*0.08
0.22 U
0.22 U
0.22 U
0.22 U
--
--
Chromium
SW6020
10
*11.70
0.9 U
0.9 U
4.1
3.1
--
--
Cobalt
SW6020
1
6.9
1.5 J
1.5 J
1.2 J
--
--
Copper
SW6020
1000
*1.31
4.7 U
4.7 U
4.7 U
4.7 U
--
--
Lead
SW6020
15
*0.20
1.2
0.44 U
1.8
1.4
--
--
Nickel
SW6020
100
*7.73
4.1
6.9
2.6 J
1.9 J
--
--
Selenium
SW6020
20
5
11
0.98 U
0.98 U
0.98 U
--
--
Vanadium
SW6020
0.3
7.5 U
7.5 U
5.7
4.5 J
--
--
Zinc
SW6020
1000
*17.36
14 J
1 10 U
1151
12 J
--
--
Spring 2020 Semiannual Water Quality Monitoring Report Page 3 of 5
Jackson County Closed Municipal Solid Waste Landfill June 2020

Table 3
Analytical Summary
Surface Water Samples
QC Samples
Location ID
MW-06
MW-07
SW-01
SW-02
FieldQC
FieIdQC
Sample ID
MW-06-20200318
MW-07-20200317
SW-01-20200317
SW-02-20200317
TB-20200317
TB-20200318
Sample Date
3/18/2020
3/17/2020
3/17/2020
3/17/2020
3/17/2020
3/18/2020
Sample Type
N
N
N
N
TB
TB
Matrix
WG
WG
WS
WS
WQ
WQ
Method
NC2L
�NULIMACI
NC213
Atmendix
I Volatile Orcianics and 1 4-Dioxane L
1,1-Dichloroethane
SW8260
6
100
1.2
0.29 U
0.29 U
0.29 U
0.29 U
0.29 U
1,2-Dichloroethene, cis-
SW8260
70
720
1
1.8
0.4 U
0.4 U
0.4 U
0.4 U
1,4-Dichlorobenzene
SW8260
6
56
0.42 U
3.6
0.42 U
0.42 U
0.42 U
0.42 U
1,4-Dioxane
SW8260
3
0.14 U
17
0.14 U
0.14 U
--
--
2-Hexanone (Methyl butyl ketone)
SW8260
40
0.29 U
0.29 U
0.29 U
0.29 U
0.29 U
0.29 U
4-Meth I-2-pentanone (Methyl isobut I ketone)
SW8260
100
26000
0.4 U
0.4 U
0.4 U
0.4 U
0.4 U
0.4 U
Acetone
SW8260
6000
2000
0.7 U
0.7 U
0.7 U
0.7 U
0.7 U
0.7 U
Benzene
SW8260
1
51
0.34 U
1.1
0.34 U
0.34 U
0.34 U
0.34 U
Chlorobenzene
SW8260
50
140
0.34 U
3.8
0.34 U
0.34 U
0.34 U
0.34 U
Eth (benzene
SW8260
600
97
0.31 U
0.31 U
0.31 U
0.31 U
0.31 U
0.31 U
m,p-X lene
SW8260
500
550
0.73 U
0.73 U
0.73 U
0.73 U
0.73 U
0.73 U
o-X lene
SW8260
500
400
0.4 U
0.4 U
0.4 U
0.4 U
0.4 U
0.4 U
Tetrachloroethene (PCE)
SW8260
0.7
3.3
0.31 U
0.31 U
0.31 U
0.31 U
0.31 U
0.31 U
Tetrah drofuran
SW8260
--
2.3 J
0.68 U
0.68 U
0.68 U
--
Toluene
SW8260
600
0.36
0.35 U
0.35 U
0.35 U
0.35 U
0.35 U
0.35 U
Total X lene
SW8260
1.1 U
1.1 U
1.1 U
1.1 U
1.1 U
1.1 U
Trichloroethene (TCE)
SW8260
3
30
0.46 U
0.46 U
0.46 U
0.46 U
0.46 U
0.46 U
Vinyl chloride
SW8260
0.03
2.4
0.47 U
0.47 U
0.41 U
0.41 U
0.47 U
0.47 U
Spring 2020 Semiannual Water Quality Monitoring Report Page 4 of 5
Jackson County Closed Municipal Solid Waste Landfill June 2020

Table 3
Analytical Summary
Notes:
Detected concentration is greater than NC2L or NC2L IMAC standard
Detected concentration is greater than NC2B standard
Bold: Detected result
Italicized: Non -detected concentration is above one or more identified NC2L standard
*: 2B surface water standard calculated using average analyzed hardness value (calculated from the upstream and downstream sampling location results) via the most stringent hardness -dependent metal calculation, per North Carolina Administrative Code, Title 15A:
Department of Environmental Quality, Subchapter 2B - Surface Water and Wetland Standards (last amended September 2017).
NC213: surface water standard per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2B — Surface Water and Wetland Standards (last amended in September 2017), or the standard obtained from the EPA Nationally
Recommended Water Quality Criteria for Aquatic Life and Human Health.
NC2L: Subchapter 2L — Groundwater Classifications and Standards, Department of Environmental Quality (Amended April 1, 2013)
All nondetect results are reported at the method detection limit.
Appendix I: indicates volatile organic compounds and metals per 40 Code of Federal Regulations Part 258
Horizontal coordinate datum is NAD 1983 State Plane North Carolina FIPS 3200 (US Survey Feet).
--: not sampled
°C: degrees Celsius
pg/L: micrograms per liter
ft: feet
GW: groundwater
IMAC: Interim Maximum Allowable Concentration. IMAC concentrations are listed in Appendix #1 of the 2L.
N: The laboratory does not hold NELAP/TNI accreditation for thi method or analyte
J: Estimated value
mg/L: milligrams per liter
mv: millivolts
N: normal environmental sample
NTU: nephelometric turbidity unit
ORP: oxidation-reduction potential
SU: standard unit
SW: surface water
TB: Trip Blank
U: Compound analyzed for, but not detected above minimum detection limit
WG: groundwater sample
WQ: water quality
Groundwater standard from North Carolina Administrative Code, Title 15A.
Spring 2020 Semiannual Water Quality Monitoring Report Page 5 of 5
Jackson County Closed Municipal Solid Waste Landfill June 2020

Table 4
Mass Removal Calculations for Volatile Organic Compounds (VOCs) Detected in the Leachate Sample (LT-01)
Sample Dates
Detected Volatile Organic
Compounds
Concentration
in LT-01
(mg/L)
Cumulative
Flow at Gauge
(gallons)
Differential
Flow
(gallons)
Mass
Removed
(pounds)
Estimated Cumulative
Mass Removed
(pounds)
Beginning
Ending
09/01/2012
10/25/2012
1,4-Dichlorobenzene
0.0034
11,500
11,500
0.00033
4-Meth I-2- entanone (MIBK)
0.0021
J
0.00020
Acetone
0.0292
0.00280
Benzene
0.0021
0.00020
Chlorobenzene
0.0029
0.00028
cis-1,2-Dichloroethene
0.00063
J
0.00006
Dichlorodifluoro-methane
0.00093
J
0.00009
Eth (benzene
0.0102
0.00098
Naphthalene
0.0069
0.00066
Styrene
0.00033
J
0.00003
Toluene
0.003
0.00029
X lene (Total)
10.0094
0.00090
Total
0.00682
0.00682
10/26/2012
04/11/2013
1,4-Dichlorobenzene
0.006
65,500
54,000
0.00270
Acetone
0.012
J
0.00540
Benzene
0.0011
0.00049
Carbon disulfide
0.0067
J
0.00301
Chlorobenzene
0.0024
J
0.00108
cis-1,2-Dichloroethene
0.00058
J
0.00026
Eth (benzene
0.0083
0.00373
Toluene
0.00059
J
0.00027
X lene (Total)
0.0078
0.00351
Total
0.02045
0.02727
04/12/2013
10/08/2013
1,4-Dichlorobenzene
0.0055
114,737
1
49,237
0.00226
4-Meth I-2- entanone (MIBK)
0.0012
J
0.00049
Benzene
0.0020
0.00082
Chlorobenzene
0.0039
0.00160
cis-1,2-Dichloroethene
0.00080
J
0.00033
Eth (benzene
10.0151
1
0.00619
Naphthalene
0.0184
0.00754
Toluene
0.0012
0.00049
X lene (Total)
0.0090
0.00369
Total
0.02341
0.05068
10/09/2013
04/08/2014
1,4-Dichlorobenzene
0.0056
168,821
54,084
0.00252
Benzene
0.0018
0.00081
Chlorobenzene
0.0051
0.00230
cis- 1,2-Dichloroethene
0.00049
J
0.00022
Eth (benzene
0.0047
0.00212
Toluene
10.00041
1 J
0.00018
X lene (Total)
10.0021
1 J
0.00095
Total
0.00910
0.05978
04/08/2014
10/23/2014
1,4-Dichlorobenzene
0.0053
179,652
10,831
0.00048
Benzene
0.0014
0.00013
Chlorobenzene
0.003
0.00027
cis- 1,2-Dichloroethene
0.00049
J
0.00004
Eth (benzene
0.0027
0.00024
Toluene
10.00051
1 J
0.00005
X lene (Total)
10.0014
1 J
0.00013
Total
0.00133
0.06111
10/23/2014
04/21/2015
1,2,3-Trimethyl benzene
0.00062
219,965
40,313
0.00021
1,2,4-Trimethyl benzene
0.00076
0.00026
2-C h to roto I u ene
0.00067
0.00022
1,4-Dichlorobenzene
0.0059
0.00198
Acetone
0.00790
0.00265
Benzene
0.0022
0.00074
Chlorobenzene
0.003
0.00101
Eth (benzene
0.0056
0.00188
Isopropyl benzene
0.0013
0.00044
Methy Tert-but I -Ether
0.0013
0.00044
Na thalene
0.024
0.00806
n-Propylbenzene
0.00088
0.00030
Tetrah drofuran
0.089
0.02988
Toluene
0.00054
J
0.00018
Vinyl Chloride
0.00038
J
0.00013
X lene (Total)
10.0030
J
0.00101
Total
0.04937
0.11048
04/21/2015
10/13/2015
1,4-Dichlorobenzene
0.00600
256,685
36,720
0.00183
2-Butanone
0.00960
J
0.00294
Benzene
0.00210
0.00064
Chlorobenzene
0.0040
0.00122
Eth (benzene
0.00710
0.00217
m, -X lenes
0.0014
0.00043
Naphthalene
0.021
0.00642
o-X lene
0.0017
0.00052
Tetrah drofuran
0.062
0.01896
Toluene
0.00058
J
0.00018
Total X lenes
10.0031
J
0.00095
Total
0.03626
0.14674
10/13/2015
04/05/2016
1,4-Dichlorobenzene
0.00590
315,663
58,978
0.00290
Benzene
0.00170
0.00083
Chlorobenzene
0.0038
0.00187
Eth (benzene
0.00500
0.00246
m, -X lenes
0.0010
0.00049
o-X lene
0.0015
0.00074
Toluene
0.00063
J
0.00031
Total X lenes
0.0025
J
0.00123
Total
0.01082
0.15756
04/05/2016 10/11/20161 No detected compounds. 1 331,010 15,347
0.00000
Total
0.00000
0.15756
Spring 2020 Semiannual Water Quality Monitoring Report Page 1 of 2
Jackson County Closed Municipal Solid Waste Landfill June 2020

Table 4
Mass Removal Calculations for Volatile Organic Compounds (VOCs) Detected in the Leachate Sample (LT-01)
Sample Dates
Detected Volatile Organic
Compounds
Concentration
in LT-01
(mg/L)
Cumulative
Flow at Gauge
(gallons)
Differential
Flow
(gallons)
Mass
Removed
(pounds)
Estimated Cumulative
Mass Removed
(pounds)
Beginning
Ending
10/11/2016
03/21/2017
1,4-Dichlorobenzene
0.0046
334,212
3,202
0.00012
Acetone
0.0094
J
0.00025
Benzene
0.0015
0.00004
Chlorobenzene
0.0043
0.00011
Eth (benzene
0.0014
0.00004
m, -X lenes
0.0006
J
0.00002
o-X lene
0.00092
0.00002
Tetrah drofuran
0.066
0.00176
Total X lenes
0.0015
J
0.00004
Total
0.00241
0.15997
03/21/2017
10/11/2017
1,4-Dichlorobenzene
0.0041
364,760 30,548
0.00104
Acetone
0.0067
J
1
0.00170
Acetonitrile
0.008
J
0.00204
Benzene
0.00061
0.00016
Chlorobenzene
0.0012
0.00031
Eth (benzene
10.00087
1
0.00022
Naphthalene
10.0012
1
0.00031
Tetrah drofuran
10.12
1
0.03053
Total
0.03630
0.19627
Issue with totalizer
between October 2017 and March 2018
03/21/2018
10/18/2018
1,4-Dichlorobenzene
0.0028
1,784,710 159,341
0.00372
Acetone
0.017
1
0.02256
Benzene
0.0012
0.00159
Chlorobenzene
0.0024
0.00318
Eth (benzene
0.0018
0.00239
m, -X lenes
10.00038
1 J
0.00050
Methylene Chloride
0.00034
J
0.00045
o-X lene
0.00060
0.00080
X lenes, Total
0.00098
J
0.00130
Total
0.04
0.23
10/18/2018
10/22/2019
1,4-Dichlorobenzene
0.0037
2,045,960 261,250
0.00805
Acetone
0.006
0.01305
Benzene
0.0017
0.00370
Chlorobenzene
0.0038
0.00827
Eth (benzene
0.0016
0.00348
o-X lene
0.00110
0.00239
Toluene
0.00039
J
0.00085
X lenes, Total
0.0017
J
0.00370
Total
0.04
0.28
10/22/2019
03/18/2020
1,4-Dichlorobenzene
0.0056
2,139,992 94,032
0.00438
1,4-Dioxane
0.06
0.04697
Acetone
0.0064
0.00501
Benzene
0.0013
0.00102
Chlorobenzene
0.0032
0.00250
Eth (benzene
0.0027
0.00211
m, -X lenes
0.00089
J
0.00070
Methyl isobut I ketone
0.00079
J
0.00062
o-X lene
0.00120
0.00094
Toluene
10.00070
0.00055
Total
0.06
0.34
Notes:
1. No VOCs were detected in the leachate sample collected during the October 2016 sampling event.
Only detected volatile organic compounds (VOCs) in leachate sample LT-01 are included in the mass removal calculation.
Leachate extraction at the landfill was initiated on September 1, 2012.
Extraction volume measurements were recorded and provided by Jackson County staff.
Anchor QEA bases mass removal calculations on the assumption that the VOCs concentration in one sampling event is representative of leachate quality until the next sampling event occurs,
and that the leachate removal system has a 100% removal and treatment efficiency.
Due to a malfunction with the leachate totalizer, there is a gap in total volume calcuations between October 11, 2017 and March 21, 2018.
Represents the total flow between the LT-01 sample dates.
Estimated cumulative mass removed and treated is estimated based upon a conversion of milligrams to pounds and liters to gallons and the multiplication of the concentration by the
differential flow for the specified period.
mg/L: milligrams per liter
J: Indicates laboratory estimated concentration is above the adjusted method detection limit and below the adjusted reporting limit.
Spring 2020 Semiannual Water Quality Monitoring Report Page 2 of 2
Jackson County Closed Municipal Solid Waste Landfill June 2020

Figures

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LEGEND: SOURCES:
1. Bas® p: USGS Topographic Maps Greens Site Parcel Boundary Creek
and Whittier 7.5-minute Quadrangles
2. Parcel: Jackson County GIS
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Feet
Publish Date: 2020/05/01, 9:38 AM I User: alesueur
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'*ZANCHOR Figure 1
QEA Site Location Map
Spring 2020 Semiannual Water Quality Monitoring Report
Jackson County Closed Municipal Solid Waste Landfill

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MW-01
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LEGEND:
Monitoring Well Road
Landfill Gas Extraction Well Elevation Contour (20-Foot Interval)
® Domestic Well Sample Location Property Boundary
Leachate Sample Location and
Flow Equalization Tank
Surface Water Sample Location
0 DW-01
b Y MW-03 F LT-01
oa
Po.
• QP0
y � .
M-0R1�-0�8
MW-07 MW-04•
0
�0
�P0
0
\I�
Iv
NOTE:
Sample locations are approximate.
SOURCES:
0
Aerial Imagery: Esri Online Services
Contours, Roads, and Parcels: Jackson County GIS
Publish Date: 2020/05/01, 9:43 AM I User: alesueur
Filepath:\\orcas\gis\Jobs\JacksonCounty_NC_1480\Maps\2020\AQ_Fig02_JacksonCounty_SpringWQ2020_Sample Location Map.mxd
0 500
Feet
fe
a
� }� ANCHOR Figure 2
lam► QEA
Site Layout Map
Anchor QEA of North Carolina, PLLC
Spring 2020 Semiannual Water Quality Monitoring Report
Jackson County Closed Municipal Solid Waste Landfill

2�
60
LEGEND:
Saprolite Monitoring Well — Stream
PWR Monitoring Well Road
Bedrock Monitoring Well Elevation Contour (20-Foot Interval)
0 Property Boundary (2,005.09) Groundwater Elevation
(March 17 and 18, 2020)
Connor
JOE WILKEY RD
z,00
Y
2t20
�ll
201
2O'
O O � V � a�
NCO ¢
' MW-07 \
(1,948.10)
MW-04
(1,955.77)
NOTES:
1. Monitoring well locations are approximate.
2. Groundwater elevations and flow direction are updated on a semiannual basis following sample collection events
in March and October.
3. Groundwater flow direction is based on groundwater elevations from all Site monitoring wells. Direction is
calculated based on depth to water measured on March 17 and 18, 2020.
4. Last names of property owners are shown in parcels that border the landfill property.
5. PWR: partially weathered rock
6. Groundwater elevation in feet (North American Vertical Datum 1988)
Publish Date: 2020/05/01, 9:59 AM I User: alesueur
Filepath: \\orcas\gis\Jobs\Jackson County_NC_1480\Maps\2020\AQ_Fig03_JacksonCounty_SpringWQ2020_GroundwaterElevationMap.mxd
ANCHOR
QEA`'`'`�
Anchor QEA of North Carolina, PLLC
C
10
0
N
SOURCES:
1. Elevation contours, roads, and parcels: Jackson County GIS
2. Groundwater elevations: calculated from surveys
performed by Davenport & Associates, Inc. (MW-01, MW-02,
MW-03, MW-04, and MW-06) and Wes Cole Land Surveying,
PA (MW-05R and MW-07)
0
0 200
Feet
Figure 3
Generalized Groundwater Flow Direction
Spring 2020 Semiannual Water Quality Monitoring Report
Jackson County Closed Municipal Solid Waste Landfill

Figure 4
Hydrograph and 1,4-Dichlorobenzene Concentration vs. Time
(Monitoring Well MW-01)
20
W.
16
2
I
r- r- 00 00 M M O O
O O O O O O
N N
— —
M M ":T ',I-
— — — —
Ln Ln
— —
(.0 1,0
— —
r r- 00 00 M
—
M O
N
O O O O O O O O O O
N N N N N N N N N N
O O
N N
O O O O
N N N N
O O
N N
O O
N N
O O O O O
N N N N .
O O
N N
Q v Q V Q v Q V Q v
a o Q o a o Q o a o
Q V
Q o
Q v Q V
a o a o
Q v
a o
Q V
Q o
(a V (o V (o
o o
V (o
o
Notes:
1. NC2L (2013) Standard= 6 micrograms per liter (µg/L )
Sampling lin Date
01,4-Dichlorobenzene
2. "J" indicates result is estimated by laboratory.
NC21- (2013) Standard
3. "<" indicates result is less than method detection limit.
4. Oct 2017 result reported in semivolatile organic compound list.
—Groundwater Elevation
2078
2076
2074
0
.w
M
2072
W
L
d
�a
3
2070 =
3
O
,L^
V
2068
2066
2064
Spring 2020 Semiannual Water Quality Monitoring Report
Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 June 2020

Figure 5
Hydrograph and Benzene Concentration vs. Time
(Monitoring Well MW-01)
12
10
4
2
I
r- r` 00 00 Cn CY) O O
O O O O O O
N N
M M 'IT
— — —
Ln Ln
— —
(.0 "0
—
r
r` 00 CO M M O
— N
O O O O O O O O O O
N N N N N N N N N N
O O
N N
O O O O
N N N N
O O
N N
O O
N N
O
N
O O O O O O
N N N . N N
Q U Q V Q U Q V Q U
a o Q o a o Q o a o
Q V
Q o
Q U Q U
a o Q o
Q U
a o
0- V
Q o
(Q
U (6 U f0 U l6
o o o
Notes:
1. NC21- (2013) Standard = 1 microgram per liter (µg/L)
Sampling Date
O Benzene
2. "J' indicates result is estimated by laboratory.
NC2L (2013) Standard
3. "U" indicates result is less than method detection limit.
*Groundwater Elevation
2078.00
2076.00
2074.00
2072.00
2070.00
2068.00
2066.00
2064.00
Spring 2020 Semiannual Water Quality Monitoring Report
Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 June 2020

Figure 6
Hydrograph and 1,4-Dioxane Concentration vs. Time
(Monitoring Well MW-02)
10
9
8
7
I
O O O
N N N
U
V (6 V
0 0
Notes:
1. NC21- (2013) Standard = 3 micrograms per liter (µg/L) Sampling Date
2. "J" indicates result is estimated by laboratory
Spring 2020 Semiannual Water Quality Monitoring Report
Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02
O
N
O
N
L
C6
G
1,4-Dioxane
NC2L (2013) Standard
t Groundwater Elevation
1982
1980
1978
1976
1974
1972
1970
M
1968
June 2020

Figure 7
Hydrograph and 1,4-Dichlorobenzene Concentration vs. Time
(Monitoring Well MW-05R)
12
10
I
I
N N M M V IT
O O O O O O
N N N N N N
++
Q V Q V Q V
Notes: Q O Q O Q O
Constituent concentration after January 2012 was found in MW-05R.
Constituent concentration before January 2012 was found in MW-05.
Groundwater elevation in October 2011 was interpolated.
NC2L (2013) Standard = 6 micrograms per liter (µg/L)
"J" indicates result is estimated by laboratory
"<" indicates result is less than method detection limit
Oct, 2017 result reported in semi -volatile organic compound list
Spring 2020 Semiannual Water Quality Monitoring Report
Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02
Ln
i11
l0
l0
I� �
O
O
O
O
O O
N
N
N
N
N N
Q
V
Q
V
a
(6 U
Q
O
Q
O
O
Sampling Date
OD 00 Ol Ql CD
N
O O O O O
N N N N N
(6 V cO V [6
g O O g
01,4-Dichlorobenzene
NC2L (2013) Standard
--$— Groundwater Elevation
WE
•:.
4,
W
1984
O
M
1982 `i
a
3
C
3
O
1980 tD
1978
1976
June 2020

Figure 8
Hydrograph and 1,4-Dioxane Concentration vs. Time
(Monitoring Well MW-0511)
10.0
9.0
8.0
7.0
-j
J
66.0
s
c
.2 5.0
R
4.0
u
c
O
u 3.0
a�
C
62.0
G
Iz 1.0
MI
O O O
N N N
V (6 V
O O
Notes:
1. NC21- (2013) Standard = 3 micrograms per liter (µg/L) Sampling Date
2. "J" indicates result is estimated by laboratory
Spring 2020 Semiannual Water Quality Monitoring Report
Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02
1987
1986
1985
1984
M
1983
d
d
1982
O
1981
_d
W
1980
r
co
1979 =
O
1978 0
1977
O
N
O
N
0 Depth to Water (feet below TOC)
NC21- (2013) Standard
4 Groundwater Elevation
June 2020

Figure 9
Hydrograph and Benzene Concentration vs. Time
(Monitoring Well MW-0511)
3
2.5
1
0.5
I
N
N
m_
�2
ILn
�2
�2 r
O
O
O
_m
O
O
O
O
O
O
O O
N
N
N
N
N
N
N
N
N
N N
Q
V
Q
V
Q
V
Q
V
Q
V l6
Q
o
Q
o
a
o
Q
o
Q
o
Notes: Sampling Date
1. NC21- (2013) Standard = 1 microgram per liter (µg/L)
2. "<" indicates result is less than method detection limit.
Spring 2020 Semiannual Water Quality Monitoring Report
Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02
I� CO
6l 6l O
N
O O
O O O O
N N
N N N N
V [p
o
V [6 V c6
o o
Benzene
NC2L (2013) Standard
-Groundwater Elevation
.;e
1987
1985
1979
1977
1975
June 2020

Figure 10
Hydrograph and Vinyl Chloride Concentration vs. Time
(Monitoring Well MW-0511)
4
3.5
3
0.5
I
N N f2 M i � L2 L2
O O O O O O O O
N N N N N N N N
Q U Q U Q U Q U
Q o a o a o a o
Notes:
1. NC2L (2013) Standard = 0.03 microgram per liter (µg/L)
2. "J" indicates result is estimated by laboratory.
3. "<" indicates result is less than method detection limit.
Spring 2020 Semiannual Water Quality Monitoring Report
Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02
�O r` r 00 a1 a1 CD
N
O O O O O O O O O
N N N N N N N N N
Q U cO U (6 U cD U (6
Q o g o o o
Vinyl Chloride
Sampling Date NC21- (2013) Standard
Groundwater Elevation
•::
1986
1984
1980
Q
1978
1976
June 2020

Figure 11
Hydrograph and 1,4-Dioxane Concentration vs. Time
(Monitoring Well MW-07)
30
25
20
I
w rn _rn O
N
O O O O
N N N N
v co v c6
O 0
Notes:
1. NC21- (2013) Standard = 3 micrograms per liter (µg/L)
Spring 2020 Semiannual Water Quality Monitoring Report
Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02
Sampling Date d1,4-Dioxane
NC2L (2013) Standard
+Groundwater Elevation
1951
1951
1950
1950
1949
1949
1948
1948
June 2020

Figure 12
Hydrograph and Benzene Concentration vs. Time
(Monitoring Well MW-07)
2
IW.
1:
0.4
0.2
I
N
N
m_
m
'IT�_
�
L_n
�
� r
O O
O
O
O
O
O
O
O
O
O
O O
N N
N
N
N
N
N
N
N
N
N
N N
L +
Q V
L
Q
Y
V
L
Q
Y
V
L
Q
Y
V
L
Q
Y
V
L
Q
+
V (6
a o
Q
o
Q
o
a
o
a
o
a
o
Notes: Sampling Date
1. NC21- (2013) Standard = 1 microgram per liter (µg/L)
2. "<" indicates result is less than method detection limit.
I-- 00 00 Ol 0')
O
N
O O O O O
O
N N N N N
N
Y Y Y
V f6 V f0 V
o o o
(6
O Benzene
NC21- (2013) Standard
4 Groundwater Elevation
1951
1951
1950
1950 Lu
L
N
3
0
1949
0
1949
1948
Spring 2020 Semiannual Water Quality Monitoring Report
Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02
June 2020

Appendix A
Well Sampling Logs, and Equipment
Documentation and Instrument
Calibration Data Sheets

ANCHOR
QEA
Well Sampling Log
Date:-3)151)-V Well Name: M VJ� d 1
Project Name:
Jackson County GW Monitoring
Dillsboro, NC
Project Number.
C91480-01.01
Weather. ''
Sampling Personnel:
V"V" C'G
Sample Time: -
Well Information:
Well Depth in Feet (WD): 11 0 I
Well Diameter:
Water Level in Feet (WL):
Type of Casing:
PVC-1
Length of Water Column: `%, �Gj feet
Screen
�J
_
(WD) - (WL) = (LWC)Flush
ntel
Mount /
One Casing Volume: �,� gallons
Comments:
(LWC) x (WCV)
Three Casing Volumes: �1 gallons
Tagged
Actual Volume Purged: gallons
bottom at:
Well Casing Volumes (WCV)
1" = 0.041 Gal/Ft 2" = 0.17 Gal/Ft Y = 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2.6 Gal/Ft 12" = 5.8 Gal/Ft
Purge Method:
Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other.
Sample Method:
Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other.
Oxidation
Gallons
Temp
Dissolved
Specific Cond. pH (S.U.)
Reduction Turbidity
Reading
Time
Purged
(°C)
Oxygen (mg/L)
(PS/cm) report to 0.1 S.U.
Potential (mV) (NTU)
Comments
1
t
Z0, �
S
32.-7
142)
2
:
a .01
is �� 6
2�-> 9;
1-3
3
��'
���5L,V
2.�o1
2 '-i
s.q
2-7.S
IL•2,
4
N
3
5
6
7
8
9
10
Notes:
Samples are analyzed immediately upon collection.
°C: degrees Celsius
pS/cm: micro-Siemen per centimeter
mg/L: milligrams per liter
mV: millivolt
NTU: nephelometric turbidity units
S.U.: Standard Units
Protective Casing: Pad: /r'v Lock: " Vegetation: C� Access: 01a I
Sampling Personnel Signature: Date:
initial if well information and sampling data has been verified
well was tagged after sampling was complete

ANCHOR
QEA
Well Sampling Log
3/a-170
Date: 3 l nl ?-o Well Name: &AW'0 a -
Project Name:
Jackson County GW Monitoring
Dillsboro, NC
Project Number.
C91480-01.01 Weather.
'
Sampling Personnel:
My, , G (l- Sample Time:
IDS
D
Well Information:
Well Depth in Feet (WD):
U 0
(.•
Well Diameter:
Water Level in Feet (WL):
'''tj(,7•ij(�
Type of Casing:
Nell
Length of Water Column:
'�
feet
Screen Interval:
U
(WD) - (WL) = (LWC)
Flush Mount Stick-U
One Casing Volume:
�'
gallons
Comments:
(LWC) x (WCV)
Three Casing Volumes:
(�, 3+
gallons
Tagged
Actual Volume Purged:
ni{ D
gallons
bottom at:
l Well Casing Volumes (WCV)
1" = 0.041 GaI/F
2" = 0.17 Ga 3" = 0-38 Gal/ft 4" = 0.66 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2-6 GaI/Ft 12" = 5.8 Gai/Ft
Purge Method:
Bailer-Disp.
Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other:
Sample Method:
Bailer-Dis
Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other:
Oxidation
Gallons
Temp
Dissolved
Specific Cond.
pH (S.U.)
Reduction
Turbidity
Reading
Time
Purged
(°C)
Oxygen (mg/L)
(INS/cm)
report to 0.1 S.U.
Potential (m1)
(NTU)
Comments
1
d.
,ta
Eci
oOJ�r/
s -g
2
�/{'
{'�
�19
V
4
3
`/
�3
'tic)
7 9..,
55,19
4
(, ^19
5
OD
7
8
9
10
Notes:
Samples are analyzed immediately upon collection.
°C: degrees Celsius
pS/cm: micro-Siemen per centimeter
mg/L: milligrams per liter
mV: millivolt
NTU: nephelometric turbidity units
S.U: Standard Units
Protective Casing:t<� Pad: Lock: / Vegetation: L Access: ��
Sampling Personnel Signature:
Date: 1
initial if well information and sampling data has been verified
well was tagged after sampling was complete
n

ANCHOR
Low -Flow Sampling Log L
Date: 3j t If 2fV well Name: IUlVJ-6.3
Project Name: Jackson County GW Monitoring
Project Number:
C91480-01.01
Location: Pillsboro, NC
Personnel:' f C,L_
Weather:
y\
Well Information: 2 r
Screen Interval: ��� �p �+. `� bgs Arrive at Well:
Depth to Water: 140. 44 toc Start Time:
Well Diameter: L in Sample Time:
Pump Intake: () toc Finish Sample Time: L{ U
Drawdown Set: toc Leave Well: _ l�►
Pump Used (circle): Peristaltic Blp Other (description):
Comments:';TiU t kA&' iL4062 S[ y J& Purge Rate: N ,-_
Tagged bottom at: Total Purge Volume: `aj (,
Pump Speed: - 1� %V
Time
DTW
(feet)
Temp
VQ
DO
(mg/L)
Specific Cond.
(PS)
pH (S.U.)
report to 0.1.
ORP
(m1)
Turbidity
(NTU)
Comments
i
' C;
D .
t
V
aV V
3:3q
coAD
r
l
13 It,
-AI. tlsl
14
—
.4 , i
-1'0. �—
Time between recharge during sample collection:
Sampling Personnel Signature:
Date: 3 ti T/
Notes:
Stabilization
3 successive readings, 3 minutes apart:
within +/- 10% DO and turbidity, +/- 3% Conductivity, +/-
0.1 pH unit +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2010)
Samples are analyzed immediately upon collection.
NS: micro-Siemen -
mv: millivolt
°C: degrees Celsius
NTU: nephelometric turbidity units
bgs: below ground surface
ORP: oxidation reduction potential
DO: dissolved oxygen
S.U: standard units
mg/L: milligrams per liter
toc: top of casing
FA
initial if well information and sampling data has been verified
well was tagged after sampling was complete
wu"'i C GW QUOS.tmc �� cat &M7

ANCHOR
QEA`''
Low -Flow Sampling Log
Date:-31 J.-J1 31�1) Well Name: kA W —Q
Project Name:
Jackson County GW Monitoring
Project Number:
C91480-01.01
Location:
Dlllsboro, NC
Personnel: ��
Well Information:
Screen Interval:— ©
Depth to Water:
Well Diameter:
Pump Intake:
Drawdown Set:
Pump Used (circle): Peristaltic Bladder
Comments:
Tagged bottom at:
_ Weather: a
bgs Arrive at Well:
toc Start Time: A3 52
in Sample Time: 5
toc Finish Sample Time: VD.2t)
toc Leave Well:
Other (description):
Purge Rate: 2,Go mti
Total Purge Volume: (U
PumpSpeed:.c '1t ,f tI 25
Time
DTW Temp
(feet) VQ
DO
(mg/L)
Specific Cond.
(pS)
pH (S.U.)
report to 0.1.
ORP
(-V)
Turbidity
(NTU)
Comments
ge.a
jag5fqw
:L5 , 3U
i,5,0
&a
r
A It
�®
3a
ALko�:
9
q;,
3o
C 7'
..34
51
5 0,
d J
l q.
U
5
S,
(,. g-
Ca
Time between recharge during sample collection:
Sampling Personnel Signature:
Date:
Notes:
Stabilization
3 successive readings, 3 minutes apart:
within +/- 10% DO andturbidity,, +/- 3% Conductivity,- +/-
0.7 PH unit +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2010)
Samples are analyzed immediately upon collection.
NS: micro-Siemen
mv: millivolt
'C: degrees Celsius
NTU: nephelometric turbidity units
bgs: below ground surface
ORP: oxidation reduction potential
DO: dissolved oxygen
S.U.: standard units
mg/L: milligrams per liter
toc: top of casing
initial if well information and sampling data has been verified 7—
well was tagged after sampling was complete

ANCHOR
QEA
Well Sampling Log
Date: -31 i .17o Well Name: I VlVQ — 0 (; f--
Project Name:
Jackson County GW Monitoring Dillsboro, NC
Project Number.
C91480-01.01 Weather:
Sampling Personnel:
���
i� _ Sample Time:
Well Information:
Well Depth in Feet (WD): y, 0 t
Well Diameter.
011Y)
Water Level in Feet (WL): L445
Type of Casing:
Ty (:/
Length of Water Column: bet
feet
Screen Interval:
A
(WD) - (WL) = (LWC)
Flush Mount Stick-U
r-
One Casing Volume: , •�—
gallons
Comments:
(LWC) x (WCV)
Three Casing Volumes: [,�
gallons
Tagged
Actual Volume Purged: 1v S
gallons
bottom at:
~� Well Casing Volumes (WCV)
1" = 0.041
Gal/Ft
2" = 0.17 G 3'• = 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2.6 Gal/Ft 12" =
5-8 Gal/Ft
Purge Method:
Bailer-Disp.
Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other.
Sample Method:
Bailer-
Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other:
Oxidation
Gallons
Temp Dissolved Specific Cond.
pH (S.U.) Reduction Turbidity
Reading
Time
Purged
(°C) Oxygen (mg/L) (PS/cm)
report to 0.1 S.U. Potential (mV) (NTU)
Comments
2
3.tS
4
/
5
6
_ 7
8
9
10
Notes:
Samples are analyzed immediately upon collection.
'C: degrees Celsius
pS/cm: micro-Siemen per centimeter
mg/L: milligrams per liter
mV: millivolt
NTU: nephelometric turbidity units
S.U.: Standard Units
r► ,y ,r/�G
LUe
n.10 �t
Protective Casing: ,w/I Pad: f Lock: I Vegetation: ` f _Access: -/ J
Sampling Personnel Signature:
/ 2
Date:
initial if well information and sampling data has been verified J
well was tagged after sampling was complete

1ZANCHOR
QEA
Low -Flow Sampling Log Date: f Well Name:�A��Q
Project Name: Jackson County GW Monitoring
Project Number:
C91480-01.01
Location: Dillsboro, NC
Personnel:
Well Information:
Screen Interval: I— Q
Depth to Water: '77b Jq1
Well Diameter: L�
Pump Intake:
Drawdown Set: Q
Pump Used (circle): Peristalti Bladd r
Comments:
Tagged bottom at:
Weather:
bgs Arrive at Well:
toc Start Time:
in Sample Time:
toc Finish Sample Time: �v
toc Leave Well:
Other (description):
— Purge Rate: i`V%
Total Purge Volume: r L
Pump Speed:Q'i
Time
DTW
(feet)
Temp
VQ
DO
(mg/L)
Specific Cond.
(PS)
pH (S.UJ
report to 0.1.
ORP
(mV)
Turbidity
(NTU) Comments
0441
0.
I1 �
1 �
s
pro
�
s
s`.:
�• .�
1-3
7h 3
qq,
5r
79-:�
'.s
t
P
- . 9-
-,
(
��3 �.
11 Arr
Into
a
it .3
5��
-
Time between recharge during sample collection:
Sampling Personnel Signature:
Date: J LN
Notes:
Stabilization
3 successive readings, 3 minutes apart:
within +/- 70% DO and turbidity,' +/- 3% Conductivity, +/- 0.1 PH unit +/- 10 mV {or ORP
from EPA - Cow -Flow (Minimal Drowdown) Groundwater sampling Procedures, April 1996 (Rev 2010)
Samples are analyzed immediately upon collection.
NS: micro-Siemen mv: millivolt
°C: degrees Celsius NTU: nephelometric turbidity units
bgs: below ground surface ORP: oxidation reduction potential
DO: dissolved oxygen S.U.: standard units
mg1L: milligrams per liter toc: top of casing
initial if well information and sampling data has been verified �.
well was tagged after sampling was complete
l �l cGt CO occ� Ca
1

ANCHOR
QEA
Low -Flow Sampling Log
Date: 9M Well Name: IAVJ'—O—q""
Project Name:
Jackson County GW Monitoring
Project Number:
C91480-01.01
Location:
D•illsboro, NC
Personnel:
MCI,Weather:
8D v .e
mDA
Well Information:
Screen Interval:�f '� "J
Depth to Water:, i
Well Diameter:
Pump Intake:
Drawdown Set: 3 t iq 0
Pump Used (circle): Peristaltic Bladde
Comments: mL't MS —ir�l1
Tagged bottom at:
bgs Arrive at Well:
toc Start Time: + Q
in Sample Time:_11-31
toc Finish Sample Time: 0
toc Leave Well:
Other (description):
SCE IJV�S ���� Purge Rate:,.. Q NH &U
Total Purge Volume:
Pump Speed Dt 7 0 l k
Time
DTW
(feet)
Temp
VQ
DO
(mg/L)
Specific Cond.
(PS)
pH (S.U.) ORP
report to 0.7. (mv)
Turbidity
(NTU)
Comments
qb
-73
. 5
3i, n
I5.0
5
o
1-33 A
•
ital
3l1-10
Ik1q
L '16 n
91a
ta. --
1 4 d
Ala,
31�o .9
110
n
�,
� S:o
-��
-
3
91.
.b
0
S
108
� -
. 5 �-
13 •
31
JG' b
'0 sa
R44
2A 51-1
Time between recharge during sample collection:
Sampling Personnel Signature:
Date:
Notes: v
Stabilization
3 successive readings, 3 minutes apart:
within +/- 70% DO and turbidity, +/- 3% Conductivity; +/- 0.1
pH unify +/- 70 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2010)
Samples are analyzed immediately upon collection.
pS: micro-Siemen
mv: millivolt
°C: degrees Celsius
NTU: nephelometric turbidity units
bgs: below ground surface
ORP: oxidation reduction potential
DO: dissolved oxygen
S.U.: standard units
mg/L: milligrams per liter
toc: top of casing
initial if well information and sampling data has been verified
well was tagged after sampling was complete

ANCHOR
QEA
Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name: Jackson County GW Monitoring
Project Number. C91480-01.01
Sampling Personnel:
Sample Name: —LT:: -
Date:
weather. Y1
Comments:
Sample Method:
Grab
Syringe
Pump
Bailer-Disp. Other.
Time
Temp
VC)
Specific Cond.
(µS)
Dissolved
Oxygen
(mg/L)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (m1)
Turbidity
(NTU) Comments
'O0
��td
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
250 mL Plastic
125 mL Plastic
40 mL Glass
W
1 L Glass
Other
Vegetation: Access:
Sampling Personnel Signature:
Notes:
NS: micro-Siemen per cubic centimeter
"C: degrees Celsius
mg/L: milligrams per liter
mV: millivolt
NTU: nephelometric turbidity units
S.U.: standard units
Date:
Method Reference:
Temperature: SM 2550 B-2010
Specific conductivity: EPA Method 120.1, Rev. 1982
DO: SM 4500 O G-2011
PH: SM 4500-H' B-2011
Page 1 of 1

,kZ ANCHOR111C A t..e..c�
;urface Water Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name: Jackson County GW Monitoring
Project Number. C91480-01.01
Sampling Personnel: aw
Sample Name: e\/V—
Comments:
Date:
Weather.
-3 n- "
1A"t
/`- fin✓' 0,
v,\k4,' w o—z_ 64
Sample Method:
Grab
Syringe Pump
Bailer-Disp.
Other.
Time
Temp (°C)
Dissolved
Oxygen (mg/L)
Specific Cond.
(PS/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (mV)
Turbidity
(NTU)
Comments
I?q,5 12. 0
13.
-7 31
I LI S
Lip -1 �
Sampling Container
Number of Containers
Requested Analysis
.00 mL Plastic
aNL�S�
250 mL Plastic
125 mL Plastic
40mLGlass
1 L Glass
Other
Vegetation:
Access: Q<—
Sampling Personnel Signature: Date: 3 J (Vr].,p
� � VV
Notes:
Samples are analyzed immediately upon collection.
°C: degrees Celsius
pS/cm: micro-Siemen per cubic centimeter
mg/L: milligrams per liter
mv: millivolt
NTU: nephelometric turbidity units
S.U.: standard units
IVI-1-u RCIC—C.
Temperature: SM 2550 B-2010
Specific conductivity: EPA Method 120.1, Rev. 1982
DO: SM 4500 O G-2011
pH: SM 4500-H' B-2011
Page 1 of"1

ANCHOR
111C A 4.4.096.01
surface Water Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name: Jackson County GW Monitoring
Project Number. C91480-01.01
Sampling Personnel:
Sample Name:
Comments: 6,oyyv% st rem , L f
Date: 2 E
Weather. r'✓ ���
r o, V',
YMi V
Sample Method: ®ra' Syringe
Pump
Bailer-Disp. Other.
Time
Temp ('C)
Dissolved
Oxygen (mg/L)
Specific Cand.
OAS/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (mV)
Turbidity
(NTU)
Comments
�01'
t 2_ 3
10.63
33 . �5
7.2-77
I ? I 7
qa 3
Sampling Container
Number of Containers
Requested Analysis
00 mL Plastic
1
6
250 mL Plastic
125 mL Plastic
40 mL Glass
�j
'Mo i r uv--� L"
1 LGlass
Other
Vegetation: 16� Access: O)L
Sampling Personnel Signature: - Date: �I
Notes: 1-1/ Method Reference:
Samples are analyzed immediately upon collection.
'C: degrees Celsius
pS/cm: micro-Siemen per cubic centimeter
mg/L: milligrams per liter
mV: millivolt
NTU: nephelometric turbidity units
S.U.: standard units
Temperature: SM 2550 B-2010
Specific conductivity: EPA Method 120.1, Rev. 1982
DO: SM 4500 O G-2011
PH: SM 4500-H' B-2011
Page 1 of 1

Itz ANCHOR
Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name: Jackson County GW Monitoring
Project Number. C91480-01.01
Sampling Personnel: f P■LW
Sample Name: -pW 0'
Date:
Weather
—
Comments: ��f7 Q"'� 'Aoi/
Sample Method: �Grab Syringe
Pump
Bailer-Disp.
Other.
Time
Temp Specific Cond.
VC) (PS)
Dissolved
Oxygen
(mg/L)
pH (S.U.)
reportto 0.1 S.U.
Oxidation
Reduction
Potential (m1)
Turbidity
(NTU)
Comments
0 d0 a'.r' 4(
l!r'r q1
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
J
250 mL Plastic
125 mL Plastic
40 mL Glass
1 L Glass
Other
Vegetation:
Access:
Sampling Personnel Signature:^ Date:
Notes: LI
NS: micro-Siemen per cubic centimeter
°C: degrees Celsius
mg/L: milligrams per liter
mV: millivolt
NTU: nephelometric turbidity units
S.U.: standard units
Method Reference:
Temperature: SM 2550 B-2010
Specific conductivity. EPA Method 120.1, Rev. 1982
DO: SM 4500 O G-2011
PH: SM 4500-H' B-2011
Page 1 of 1

ANCHOR
QEA
Equipment Documentation and Instrument Calibration Data Sheet
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
CALIBRATION DOCUMENTATION
Project Name: Jackson County GW Monitoring Person Conducting Calibration:
Project Number. C91480-01.01 Date of Calibration: ;%
Project Location: Dillsboro, NC Date of Field Measurements: 7y
EQUIPMENT DOCUMENTATION
Equipment or meters used to take measurements (e.g., water level meters, survey equipment):
Equipment Type
Serial Number
Brand
Date of Use
150-ft Water Level
26154
Solinist
150-ft Water Level
22754
Solinist
150-ft Water Level
150
Testwell
150-ft Drawdown
MP30-1527
QED
Other
Select Turbidimeter. Hach 2100Q (s/n 151006045207)
HF Scientific MicroTPW (s/n 200601045)
Instrument Reading Instrument Reading
(Hach 2100Q) (HP Scientific MicroTPW)
Calibration 20 NTU 100 NTU 800 NTU 1,000 NTU 10.0 NTU 0.02 NTU
Expiration Date:
Cal- , Cal.' Cal: v Cal: Cal: Cal:
—Ti
im`*.TimeTime Time: Time: ime:
VV jj yL'�� I/' R �T
Verification (10 NTU): ( 0 � Verification: Verifi on: Verification:
s'
Time . 0 NTU 1C I. Ex it ion Date: Time: Time: Time:
�. 60 1,
YSI Professional Plus Multiparameter Meter (s/n 11813701802)
Instrument Readings
Calibration Expiration Date
Dissolved Oxygen
Im ial:
( Z.
Cal:
Ir
10"
mmHg:
, `e �
Temperature CC):
� fC' d
Time:
�f
NA
J
y�
PH 7 S.U.
Initial:
pHmV:
­1PH
Cal:
pHmV:
Time:
1,(�
report to 0. 7 S. U.
4
Ini)i :' ,` -
�{
pHmV:
Cal: s_ 4)
pHmV:
Time:
p
t
report to 0.1JS.U.
r�
pH 10 S.U.
Initia •
.
pHmV:
Cal
o �
pHmV:
`.�
Time:
�'.
I1 L j.��
v
report to 0.1 S.U.
16
c
• I'
V/�
QC* H 7 S.U.
AN} T'
M { //
Mid Da Time:
y
Check:
PM Time:
Check
1210
report to 0.1 S.U.
4y
V
Spec. Cond.
lio
Initial:
� Cl
Cal:
I OD 0
Time:
31
o
pS/cm**
QC*:
AM Time:
� �
Meas:�(%�
DU
Mid Day Time:
Check:
PM Time:
Check
�
LJ
p5/cm
ORP mV
Inl ial:
C 1 i�
Cal: �}
` '
Temperature CC),
�l r
Time:
}
1i f
Signature: Date: 31 it
Notes:
1. Electronic equipment calibrated according to the manufacturer's operation manual.
2. Specific Conductivity should be calibrated according to values representative of historic range.
3. Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, pH 10, DO, ORP, QC checks.
4. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated
S. * Indicates that a QC check must be performed in the morning, afternoon, and the end of the day, or every four hours.
6. ** Indicates to choose a Specific Conductivity buffer of 1413, 447, 84, or 23 mS which is closest to historical readings from the project location.
Method Reference: Temperature: SM 2550 B-2070 I Specific conductivity: EPA Method 120.7, Rev. 1982 1 DO: SM 4500 0 G-2071 I pH: SM 4500-H+ B-2077
Page 1 of 1

ANCHOR
QEA
Equipment Documentation and Instrument Calibration Data Sheet
CALIBRATION DOCUMENTATION
Project Name:( Person Conducting Calibration:
Project Number. Date of Calibration:
Project Location: �g►_ Yf" Date of Field Measurements: j
EQUIPMENT DOCUMENTATION
Equipment or meters used to take measurements (e.g., water level meters, survey equipment):
EquiTy{)e',`"DateofUse"`;;i_�1,�i��-
150ftWater Level
26154
,l �`;
150-ft Water Level
22754MTestwell
150-ft Water Level
150150-ft
Drawdown
MP30-1527Other
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Select Turbidimeter.
Hach 2100Q (s/n 151006045207)
HF Scientific MicroTPW (s/n 200601045)
IinggumentT3eadiAg 4 `
lnstrumen#Reeding.
s
(liach.2l O.i1Q) _
ZHI: Scieptifit MicroTPYlf7 ., .
calibration'.
20 NT 1
1DD NTU _ 800 NTU'
f:;000 NTU; '
a l:U 1+ITU OtX 2 NTU .
Expiration Date:.
Cal: J
'7 , ,
Cal: `'�, u� Cal: `�
Cal:
Cal: Cal:
Time: _ A -
Tim(e�Lt-Time:
Time:
Time: Time:
Verification (10 NTU): C
s
Verification:
VpM Mcation: Verification:
Time:
10 NTU Cal. 1xpiratiQn�Drate:
Time:
Time: Time:
"` �
ALL`
;'"_ `. ' ' YS1=profe3sipnaLPlus Mu tiparameter
INcter (s/r 1:8f3i01803) .„
'
_:. Instrument Readin s `
9
„. s
Calibration Expiration Date.
Dissolved Oxygen
Initial:
(�lpi
Cal:
qq, `?
(y
mmHg:
v
Temperature (°C):
f (a
Time:
�7
Iv / y)
NA
PH 7 S.U.
Initial:
pHmV:
Cal:
pHmV:
Time:
report to 0. 7 S.U.
-3,01,
Lv
an
Ini J.
f-�4
pHmV
Cal:
C
Cull
pHmV:
Time:
_�
V
(6z
report to 0.7 S.U.
"0
e r a
PH 10 S.U.
Initial:
pHmV:
Cal:
pHmV:
Timei
report to 0.7 S.U.
QC* pH 7 S.U.
A e:
Meas:
Mid Day Time:
Check:
PM Time.
Check:
report to 0.1 S.U.
2,64
by
SpecrCond.
Initial:
Cal:
Time:
p5/cm**
! 6 :J7✓ ,
1001
6
11 GZf
QC*: /�
t ow
AM Time::
Meas:(�
J
Mid Day Time:
Check:
PM Time:
Check:
0
ps/cm
,;(a
ll�
ORP mV
Initial: ryry
`���
Cal:
A�r�
Temperature (°C):
og
Time::
%1
l
I ab7
,
(i 'i? �`�
Signature:�I Date: ? f I V r jt
' v
Notes: %_�,
1. Electronic equipment calibrated according to the manufacturer's operation manual.
2. Specific Conductivity should be calibrated according to values representative of historic range.
3. Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, pH 10, DO, ORP, QC checks.
4. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated
5. * Indicates that a QC check must be performed in the morning, afternoon, and the end of the day, or every four hours.
6. ** Indicates to choose a Specific Conductivity buffer of 1413, 447, 84, or 23 mS which is closest to historical readings from the project location.
Method Reference: Temperature: SM 2550 B-2010 1 Specific conductivity: EPA Method 720. 7, Rev. 1982 1 DO: SM 4500 0 G-2077 i pH: SM 4500-H+ 8-2077
Page 1 of 1

Appendix B
Reports of Laboratory Analysis,
Chain -of -Custody Documentation,
and Certificates of Analysis

Way poi nt
ANALYTICAL
Anchor QEA of North Carolina, PLLC
Alec Macbeth
231 Haywood Street
Asheville, NC 28801
NC Certification No. 402
NC Drinking Water Cert No. 37735
SC Certification No. 99012
Project: Jackson Cty Landfill 2020 Spring
Project No.: 50-02
Lab Submittal Date: 03/18/2020
Work Order: 0030253
Case Narrative
3/27/20 10:49
This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample
Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed
according to the referenced methods.
Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case
narrative.
Narrative Notes:
TOC analysis was subcontracted to Pace/GCAL. Laboratory report is attached.
Waypoint Summary of Detections does not include subcontracted data.
Please call if you have any questions relating to this analytical report.
Respectfully,
WAYPOINT ANALYTICAL
a,-1
Angela D. Overcash
Senior Project Manager
Data Qualifiers Key Reference:
BB Blank value is outside of the control limits. Validity of the data not affected.
HT Sample received and analyzed outside of the hold time.
J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag).
M Matrix spike outside of the control limits.
BRL Below Reporting Limit
MDL Method Detection Limit
RPD Relative Percent Difference
* Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and
reporting limit indicated with a J.
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

0Sample
Receipt Summary
Waypoi nt..
03/27/2020
ANALYTICAL
Work Order: 0030253
Client Sample ID
Lab Sample ID
Matrix
Date/Time Sampled
Date/Time Received
MW-03-20200317
0030253-01
Water
03/17/20 13:46
03/18/20 8:55
MW-04-20200317
0030253-02
Water
03/17/20 9:59
03/18/20 8:55
MW-07-20200317
0030253-03
Water
03/17/20 11:39
03/18/20 8:55
SW-01-20200317
0030253-04
Water
03/17/20 12:45
03/18/20 8:55
SW-02-20200317
0030253-05
Water
03/17/20 13:00
03/18/20 8:55
TB-20200317
0030253-06
Water
03/17/20 0:00
03/18/20 8:55
Samples were received in good condition at 2.0 degrees C unless otherwise noted.
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Way po i nt .
ANALYTICAL
Summary of Detections
03/27/202C
Work Order: 0030253
Prism ID
Client ID
Parameter
Method
Result
Units
0030253-01
MW-03-20200317
Chloride
9056A
15000
ug/L
0030253-01
MW-03-20200317
Nitrate as N
9056A
430
ug/L
0030253-01
MW-03-20200317
Sulfate
9056A
6200
ug/L
0030253-01
MW-03-20200317
Biochemical Oxygen Demand
SM5210 B
300
BB, J
ug/L
0030253-01
MW-03-20200317
Chemical Oxygen Demand
SM5220 D
22000
J
ug/L
0030253-01
MW-03-20200317
Total Alkalinity to pH 4.5
SM2320 B
150000
ug/L
0030253-01
MW-03-20200317
Arsenic
6020B
0.37
J
ug/L
0030253-01
MW-03-20200317
Barium
6020B
130
ug/L
0030253-01
MW-03-20200317
Chromium
6020B
1.7
J
ug/L
0030253-01
MW-03-20200317
Cobalt
6020E
1.8
J
ug/L
0030253-01
MW-03-20200317
Copper
6020B
5.0
J
ug/L
0030253-01
MW-03-20200317
Nickel
6020B
1.2
J
ug/L
0030253-02
MW-04-20200317
Chloride
9056A
30000
ug/L
0030253-02
MW-04-20200317
Nitrate as N
9056A
8300
ug/L
0030253-02
MW-04-20200317
Sulfate
9056A
110000
ug/L
0030253-02
MW-04-20200317
Chemical Oxygen Demand
SM5220 D
74000
ug/L
0030253-02
MW-04-20200317
Total Alkalinity to pH 4.5
SM2320 B
82000
ug/L
0030253-02
MW-04-20200317
Barium
6020B
83
ug/L
0030253-02
MW-04-20200317
Cadmium
6020B
0.23
J
ug/L
0030253-02
MW-04-20200317
Cobalt
6020B
1.7
J
ug/L
0030253-02
MW-04-20200317
Selenium
6020B
1.3
J
ug/L
0030253-02
MW-04-20200317
1,4-Dichlorobenzene
8260D
1.3
ug/L
0030253-02
MW-04-20200317
Chlorobenzene
8260D
0.86
ug/L
0030253-02
MW-04-20200317
cis-1,2-Dichloroethylene
8260D
0.40
J
ug/L
0030253-02
MW-04-20200317
1,4-Dioxane
8260D SIM
3.0
ug/L
0030253-03
MW-07-20200317
Chloride
9056A
79000
ug/L
0030253-03
MW-07-20200317
Nitrate as N
9056A
94
J
ug/L
0030253-03
MW-07-20200317
Sulfate
9056A
28000
ug/L
0030253-03
MW-07-20200317
Chemical Oxygen Demand
SM5220 D
19000
J
ug/L
0030253-03
MW-07-20200317
Total Alkalinity to pH 4.5
SM2320 B
250000
ug/L
0030253-03
MW-07-20200317
Barium
6020B
460
ug/L
0030253-03
MW-07-20200317
Cobalt
6020B
1.5
J
ug/L
0030253-03
MW-07-20200317
Nickel
6020B
6.9
ug/L
0030253-03
MW-07-20200317
1,4-Dichlorobenzene
8260D
3.6
ug/L
0030253-03
MW-07-20200317
Benzene
8260D
1.1
ug/L
0030253-03
MW-07-20200317
Chlorobenzene
8260D
3.8
ug/L
0030253-03
MW-07-20200317
cis-1,2-Dichloroethylene
8260D
1.8
ug/L
0030253-03
MW-07-20200317
Tetrahydrofuran
8260D
2.3
J
ug/L
0030253-03
MW-07-20200317
1,4-Dioxane
8260D SIM
17
ug/L
0030253-04
SW-01-20200317
Hardness
SM2340 C
11000
ug/L
0030253-04
SW-01-20200317
Barium
6020B
42
ug/L
0030253-04
SW-01-20200317
Chromium
6020B
4.1
ug/L
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

(D
Way po 0nt.
ANALYTICAL
Summary of Detections
03/27/202C
Work Order: 0030253
Prism ID
Client ID
Parameter
Method
Result
Units
0030253-04
SW-01-20200317
Cobalt
6020B
1.5
J
ug/L
0030253-04
SW-01-20200317
Lead
6020B
1.8
ug/L
0030253-04
SW-01-20200317
Nickel
6020B
2.6
J
ug/L
0030253-04
SW-01-20200317
Vanadium
6020B
5.7
ug/L
0030253-04
SW-01-20200317
Zinc
6020B
15
J
ug/L
0030253-05
SW-02-20200317
Hardness
SM2340 C
10000
ug/L
0030253-05
SW-02-20200317
Barium
6020B
34
ug/L
0030253-05
SW-02-20200317
Chromium
6020B
3.1
ug/L
0030253-05
SW-02-20200317
Cobalt
6020B
1.2
J
ug/L
0030253-05
SW-02-20200317
Lead
6020B
1.4
ug/L
0030253-05
SW-02-20200317
Nickel
6020B
1.9
.1
ug/L
0030253-05
SW-02-20200317
Vanadium
6020B
4.5
J
ug/L
0030253-05
SW-02-20200317
Zinc
6020B
12
J
ug/L
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
IL A i • . 0 03/27/2020
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: MW-03-20200317
Attn: Alec Macbeth Spring Sample ID: 0030253-01
231 Haywood Street Project No.: 50-02 Work Order: 0030253
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/17/20 13:46
Time Submitted: 03/18/20 08:55
Parameter
Result
Units
SWSL
Report
MDL
Dilution
Method
Analysis Analyst
Batch
Limit
Factor
Date/Time
ID
Anions by Ion Chromatography
Chloride
15000
ug/L
NE
1000
380
1
9056A
3/18/20 12:33 BMS
P000366
Nitrate as N
430
ug/L
10000
200
54
1
9056A
3/18/20 12:33 BMS
P000366
Sulfate
6200
ug/L
250000
2000
480
1
9056A
3118/20 12:33 BMS
P000366
General Chemistry Parameters
Biochemical Oxygen Demand
300
BB,
ug/L
NE
2000
210
1
SM5210 B
3118/20 13:53 SLS
P000359
J
Chemical Oxygen Demand
22000
J
ug/L
NE
50000
10000
1
SM5220 D
3/19/20 12:08 SLS
P000397
Ferrous Iron
<51
HT
ug/L
NE
200
51
1
SM3500-Fe B
3/18/20 9:50 BMS
P000340
Sulfide
<830
ug/L
1000
2000
830
1
SM4500-S F
3/20/20 10:55 CBM
P000429
Total Alkalinity to pH 4.5
150000
ug/L
NE
5000
770
1
SM2320 B
3/20/20 10:00 CLB
P000387
Total Metals
Mercury
<0.034
ug/L
0.2
0.20
0.034
1
7470A
3/20/20 16:35 JAB
P000417
Antimony
<0.93
ug/L
6
3.0
0.93
1
6020B
3/19/20 21:57 MMR
P000369
Arsenic
0.37
J
ug/L
10
1.0
0.34
1
6020B
3/19/20 21:57 MMR
P000369
Barium
130
ug/L
100
10
3.2
1
6020B
3/19/20 21:57 MMR
P000369
Beryllium
<0.30
ug/L
1
1.0
0.30
1
6020B
3/19/20 21:57 MMR
P000369
Cadmium
<0.22
ug/L
1
1.0
0.22
1
6020B
3/19/20 21:57 MMR
P000369
Chromium
1.7
J
ug/L
10
3.0
0.90
1
6020B
3/19/20 21:57 MMR
P000369
Cobalt
1.8
J
ug/L
10
2.0
0.70
1
6020B
3/19/20 21:57 MMR
P000369
Copper
5.0
J
ug/L
10
10
4.7
1
6020B
3/19/20 21:57 MMR
P000369
Lead
<0.44
ug/L
10
1.0
0.44
1
6020B
3/19/20 21:57 MMR
P000369
Nickel
1.2
J
ug/L
50
3.0
0.83
1
6020B
3119/20 21:57 MMR
P000369
Selenium
<0.98
ug/L
10
5.0
0.98
1
6020B
3/19/20 21:57 MMR
P000369
Silver
<0.34
ug/L
10
1.0
0.34
1
6020B
3/19/20 21:57 MMR
P000369
Thallium
<0.84
ug/L
5.5
2.0
0.84
1
6020B
3/19/20 21:57 MMR
P000369
Vanadium
<1.5
ug/L
25
5.0
1.5
1
6020B
3/19/20 21:57 MMR
P000369
Zinc
<10
ug/L
10
20
10
1
6020B
3/19/20 21:57 MMR
P000369
Volatile Organic Compounds by GC/MS
1, 1, 1,2-Tetrachloroethane
<0.35
ug/L
5
0.50
0.35
1
8260D
3/19/20 18:38 JLB
P000392
1, 1, 1 -Trichloroethane
<0.31
ug/L
1
0.50
0.31
1
8260D
3/19/20 18:38 JLB
P000392
1,1,2,2-Tetrachloroethane
<0.34
ug/L
3
0.50
0.34
1
8260D
3/19/20 18:38 JLB
P000392
1,1,2-Trichloroethane
<0.42
ug/L
1
0.50
0.42
1
8260D
3/19/20 18:38 JLB
P000392
1,1-Dichloroethane
<0.29
ug/L
5
0.50
0.29
1
8260D
3/19/20 18:38 JLB
P000392
1,1-Dichloroethylene
<0.35
ug/L
5
0.50
0.35
1
8260D
3/19/20 18:38 JLB
P000392
1,2,3-Trichloropropane
<0.34
ug/L
1
1.0
0.34
1
8260D
3/19/20 18:38 JLB
P000392
1,2-Dibromo-3-chloropropane
<0.59
ug/L
13
2.0
0.59
1
8260D
3/19/20 18:38 JLB
P000392
1,2-Dibromoethane
<0.37
ug/L
1
0.50
0.37
1
8260D
3/19/20 18:38 JLB
P000392
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
A i • .0 03/27/2020
- -ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: MW-03-20200317
Attn: Alec Macbeth Spring Sample ID: 0030253-01
231 Haywood Street Project No.: 50-02 Work Order: 0030253
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/17/20 13:46
Time Submitted: 03/18/20 08:55
Parameter
Result
Units
SWSL
Report
Limit
MDL
Dilution
Factor
Method
Analysis Analyst
Date/Time
Batch
ID
1,2-Dichlorobenzene
<0.28
ug/L
5
0.50
0.28
1
8260D
3/19/20 18:38 JLB
P000392
1,2-Dichloroethane
<0.41
ug/L
1
0.50
0.41
1
8260D
3/19/20 18:38 JLB
P000392
1,2-Dichloropropane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/19/20 18:38 JLB
P000392
1,4-Dichlorobenzene
<0.42
ug/L
1
0.50
0.42
1
8260D
3/19/20 18:38 JLB
P000392
Acetone
<0.70
ug/L
100
5.0
0.70
1
8260D
3/19/20 18:38 JLB
P000392
Acrylonitrile
<0.85
ug/L
200
20
0.85
1
8260D
3/19/20 18:38 JLB
P000392
Benzene
<0.34
ug/L
1
0.50
0.34
1
8260D
3/19/20 18:38 JLB
P000392
Bromochloromethane
<0.53
ug/L
3
2.0
0.53
1
8260D
3/19/20 18:38 JLB
P000392
Bromodichloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/19/20 18:38 JLB
P000392
Bromoform
<0.26
ug/L
3
1.0
0.26
1
8260D
3/19/20 18:38 JLB
P000392
Bromomethane
<0.48
ug/L
10
1.0
0.48
1
8260D
3/19/20 18:38 JLB
P000392
Carbon disulfide
<0.36
ug/L
100
5.0
0.36
1
8260D
3/19/20 18:38 JLB
P000392
Carbon Tetrachloride
<0.55
ug/L
1
2.0
0.55
1
8260D
3/19/20 18:38 JLB
P000392
Chlorobenzene
<0.34
ug/L
3
0.50
0.34
1
8260D
3/19/20 18:38 JLB
P000392
Chloroethane
<0.43
ug/L
10
0.50
0.43
1
8260D
3/19/20 18:38 JLB
P000392
Chloroform
<0.48
ug/L
5
0.50
0.48
1
8260D
3/19/20 18:38 JLB
P000392
Chloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/19/20 18:38 JLB
P000392
cis- 1,2-Dichloroethylene
<0.40
ug/L
5
0.50
0.40
1
8260D
3/19/20 18:38 JLB
P000392
cis- 1,3-Dichloropropylene
<0.36
ug/L
1
0.50
0.36
1
8260D
3/19/20 18:38 JLB
P000392
Dibromochloromethane
<0.42
ug/L
3
0.50
0.42
1
8260D
3/19/20 18:38 JLB
P000392
Dibromomethane
<0.54
ug/L
10
2.0
0.54
1
8260D
3/19/20 18:38 JLB
P000392
Ethylbenzene
<0.31
ug/L
1
0.50
0.31
1
8260D
3/19/20 18:38 JLB
P000392
m,p-Xylenes
<0.73
ug/L
NE
1.0
0.73
1
8260D
3/19/20 18:38 JLB
P000392
Methyl Butyl Ketone (2-Hexanone)
<0.29
ug/L
50
5.0
0.29
1
8260D
3/19/20 18:38 JLB
P000392
Methyl Ethyl Ketone (2-Butanone)
<0.78
ug/L
100
5.0
0.78
1
8260D
3/19/20 18:38 JLB
P000392
Methyl Iodide
<0.41
ug/L
10
5.0
0.41
1
8260D
3/19/20 18:38 JLB
P000392
Methyl Isobutyl Ketone
<0.40
ug/L
100
5.0
0.40
1
8260D
3/19/20 18:38 JLB
P000392
Methylene Chloride
<0.40
ug/L
1
1.0
0.40
1
8260D
3/19/20 18:38 JLB
P000392
o-Xylene
<0.40
ug/L
NE
0.50
0.40
1
8260D
3/19/20 18:38 JLB
P000392
Styrene
<0.26
ug/L
1
0.50
0.26
1
8260D
3/19/20 18:38 JLB
P000392
Tetrachloroethylene
<0.31
ug/L
1
0.50
0.31
1
8260D
3/19/20 18:38 JLB
P000392
Tetrahydrofuran
<0.68
ug/L
NE
10
0.68
1
8260D
3/19/20 18:38 JLB
P000392
Toluene
<0.35
ug/L
1
0.50
0.35
1
8260D
3/19/20 18:38 JLB
P000392
trans- 1,2-Dichloroethylene
<0.27
ug/L
5
0.50
0.27
1
8260D
3/19/20 18:38 JLB
P000392
trans- 1,3-Dichloropropylene
<0.49
ug/L
1
0.50
0.49
1
8260D
3/19/20 18:38 JLB
P000392
trans- 1,4-Dichloro-2-butene
<0.22
ug/L
100
10
0.22
1
8260D
3/19/20 18:38 JLB
P000392
Trichloroethylene
<0.46
ug/L
1
0.50
0.46
1
8260D
3/19/20 18:38 JLB
P000392
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
• � 03/27/2020
PA Waynt.�
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: MW-03-20200317
Attn: Alec Macbeth Spring Sample ID: 0030253-01
231 Haywood Street Project No.: 50-02 Work Order: 0030253
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/17/20 13:46
Time Submitted: 03/18/20 08:55
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
Trichlorofluoromethane
<0.24
Vinyl acetate
<0.26
Vinyl chloride
<0.41
Xylenes, total
<1.1
ug/L
1
0.50
0.24 1
8260D
3/19/20 18:38 JLB
P000392
ug/L
50
2.0
0.26 1
8260D
3/19/20 18:38 JLB
P000392
ug/L
1
0.50
0.41 1
8260D
3/19/20 18:38 JLB
P000392
ug/L
5
1.5
1.1 1
8260D
3/19/20 18:38 JLB
P000392
Surrogate
Recovery Control Limits
4-Bromofluorobenzene 100 % 80-124
Dibromofluoromethane 104 % 75-129
Toluene-d8 98 % 77-123
Volatile Organic Compounds by GUMS SIM
1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 3/18/20 17:24 TBL P000356
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

0
Way poi nt.
ANALYTICAL
Anchor QEA of North Carolina, PLLC
Attn: Alec Macbeth
231 Haywood Street
Asheville, NC 28801
Laboratory Report
03/27/2020
Project: Jackson Cty Landfill 2020 Client Sample ID: MW-04-20200317
Spring Sample ID: 0030253-02
Project No.: 50-02 Work Order: 0030253
Sample Matrix: Water Time Collected: 03/17/20 09:59
Time Submitted: 03/18/20 08:55
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
Anions by Ion Chromatography
Chloride 30000 ug/L NE 1000 380 1 9056A 3/18/20 11:32 BMS P000366
Nitrate as N 8300 ug/L 10000 200 54 1 9056A 3/18/20 11:32 BMS P000366
Sulfate 110000 ug/L 250000 2000 480 1 9056A 3/18/20 11:32 BMS P000366
General Chemistry Parameters
Biochemical Oxygen Demand
<210 BB
ug/L
NE
2000
210
1
SM5210 B
3/18/20 13:53 SLS
P000359
Chemical Oxygen Demand
74000
ug/L
NE
50000
10000
1
SM5220 D
3/19/20 12:08 SLS
P000397
Ferrous Iron
<51 HT
ug/L
NE
200
51
1
SM3500-Fe B
3/18/20 9:50 BMS
P000340
Sulfide
<830
ug/L
1000
2000
830
1
SM4500-S F
3/20/20 10:55 CBM
P000429
Total Alkalinity to pH 4.5
82000
ug/L
NE
5000
770
1
SM2320 B
3/20/20 10:00 CLB
P000387
Total Metals
Mercury
<0.034
ug/L
0.2
0.20
0.034
1
7470A
3/20/20 16:39 JAB
P000417
Antimony
<0.93
ug/L
6
3.0
0.93
1
6020B
3/19/20 22:30 MMR
P000369
Arsenic
<0.34
ug/L
10
1.0
0.34
1
6020B
3/19/20 22:30 MMR
P000369
Barium
83
ug/L
100
10
3.2
1
6020B
3/19/20 22:30 MMR
P000369
Beryllium
<0.30
ug/L
1
1.0
0.30
1
6020B
3/19/20 22:30 MMR
P000369
Cadmium
0.23 j
ug/L
1
1.0
0.22
1
6020B
3/19/20 22:30 MMR
P000369
Chromium
<0.90
ug/L
10
3.0
0.90
1
6020B
3/19/20 22:30 MMR
P000369
Cobalt
1.7 j
ug/L
10
2.0
0.70
1
6020B
3/19/20 22:30 MMR
P000369
Copper
<4.7
ug/L
10
10
4.7
1
6020B
3/19/20 22:30 MMR
P000369
Lead
<0.44
ug/L
10
1.0
0.44
1
6020B
3/19/20 22:30 MMR
P000369
Nickel
<0.83
ug/L
50
3.0
0.83
1
6020B
3/19/20 22:30 MMR
P000369
Selenium
1.3 j
ug/L
10
5.0
0.98
1
6020B
3/19/20 22:30 MMR
P000369
Silver
<0.34
ug/L
10
1.0
0.34
1
6020B
3/19/20 22:30 MMR
P000369
Thallium
<0.84
ug/L
5.5
2.0
0.84
1
6020B
3/19/20 22:30 MMR
P000369
Vanadium
<1.5
ug/L
25
5.0
1.5
1
6020B
3/19/20 22:30 MMR
P000369
Zinc
<10
ug/L
10
20
10
1
6020B
3/19/20 22:30 MMR
P000369
Volatile Organic Compounds by GC/MS
1,1,1,2-Tetrachloroethane
<0.35
ug/L
5
0.50
0.35
1
8260D
3/19/20 19:02 JLB
P000392
1, 1, 1 -Trichloroethane
<0.31
ug/L
1
0.50
0.31
1
8260D
3/19/20 19:02 JLB
P000392
1,1,2,2-Tetrachloroethane
<0.34
ug/L
3
0.50
0.34
1
8260D
3/19/20 19:02 JLB
P000392
1,1,2-Trichloroethane
<0.42
ug/L
1
0.50
0.42
1
8260D
3/19/20 19:02 JLB
P000392
1,1-Dichloroethane
<0.29
ug/L
5
0.50
0.29
1
8260D
3/19/20 19:02 JLB
P000392
1,1-Dichloroethylene
<0.35
ug/L
5
0.50
0.35
1
8260D
3/19/20 19:02 JLB
P000392
1,2,3-Trichloropropane
<0.34
ug/L
1
1.0
0.34
1
8260D
3/19/20 19:02 JLB
P000392
1,2-Dibromo-3-chloropropane
<0.59
ug/L
13
2.0
0.59
1
8260D
3/19/20 19:02 JLB
P000392
1,2-Dibromoethane
<0.37
ug/L
1
0.50
0.37
1
8260D
3/19/20 19:02 JLB
P000392
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
A i • .0 03/27/2020
- -ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: MW-04-20200317
Attn: Alec Macbeth Spring Sample ID: 0030253-02
231 Haywood Street Project No.: 50-02 Work Order: 0030253
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/17/20 09:59
Time Submitted: 03/18/20 08:55
Parameter
Result
Units
SWSL
Report
Limit
MDL
Dilution
Factor
Method
Analysis Analyst
Date/Time
Batch
ID
1,2-Dichlorobenzene
<0.28
ug/L
5
0.50
0.28
1
8260D
3/19/20 19:02 JLB
P000392
1,2-Dichloroethane
<0.41
ug/L
1
0.50
0.41
1
8260D
3/19/20 19:02 JLB
P000392
1,2-Dichloropropane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/19/20 19:02 JLB
P000392
1,4-Dichlorobenzene
1.3
ug/L
1
0.50
0.42
1
8260D
3/19/20 19:02 JLB
P000392
Acetone
<0.70
ug/L
100
5.0
0.70
1
8260D
3/19/20 19:02 JLB
P000392
Acrylonitrile
<0.85
ug/L
200
20
0.85
1
8260D
3/19/20 19:02 JLB
P000392
Benzene
<0.34
ug/L
1
0.50
0.34
1
8260D
3/19/20 19:02 JLB
P000392
Bromochloromethane
<0.53
ug/L
3
2.0
0.53
1
8260D
3/19/20 19:02 JLB
P000392
Bromodichloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/19/20 19:02 JLB
P000392
Bromoform
<0.26
ug/L
3
1.0
0.26
1
8260D
3/19/20 19:02 JLB
P000392
Bromomethane
<0.48
ug/L
10
1.0
0.48
1
8260D
3/19/20 19:02 JLB
P000392
Carbon disulfide
<0.36
ug/L
100
5.0
0.36
1
8260D
3/19/20 19:02 JLB
P000392
Carbon Tetrachloride
<0.55
ug/L
1
2.0
0.55
1
8260D
3/19/20 19:02 JLB
P000392
Chlorobenzene
0.86
ug/L
3
0.50
0.34
1
8260D
3/19/20 19:02 JLB
P000392
Chloroethane
<0.43
ug/L
10
0.50
0.43
1
8260D
3/19/20 19:02 JLB
P000392
Chloroform
<0.48
ug/L
5
0.50
0.48
1
8260D
3/19/20 19:02 JLB
P000392
Chloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/19/20 19:02 JLB
P000392
cis-1,2-Dichloroethylene
0.40 J
ug/L
5
0.50
0.40
1
8260D
3/19/20 19:02 JLB
P000392
cis- 1,3-Dichloropropylene
<0.36
ug/L
1
0.50
0.36
1
8260D
3/19/20 19:02 JLB
P000392
Dibromochloromethane
<0.42
ug/L
3
0.50
0.42
1
8260D
3/19/20 19:02 JLB
P000392
Dibromomethane
<0.54
ug/L
10
2.0
0.54
1
8260D
3/19/20 19:02 JLB
P000392
Ethylbenzene
<0.31
ug/L
1
0.50
0.31
1
8260D
3/19/20 19:02 JLB
P000392
m,p-Xylenes
<0.73
ug/L
NE
1.0
0.73
1
8260D
3/19/20 19:02 JLB
P000392
Methyl Butyl Ketone (2-Hexanone)
<0.29
ug/L
50
5.0
0.29
1
8260D
3/19/20 19:02 JLB
P000392
Methyl Ethyl Ketone (2-Butanone)
<0.78
ug/L
100
5.0
0.78
1
8260D
3/19/20 19:02 JLB
P000392
Methyl Iodide
<0.41
ug/L
10
5.0
0.41
1
8260D
3/19/20 19:02 JLB
P000392
Methyl Isobutyl Ketone
<0.40
ug/L
100
5.0
0.40
1
8260D
3/19/20 19:02 JLB
P000392
Methylene Chloride
<0.40
ug/L
1
1.0
0.40
1
8260D
3/19/20 19:02 JLB
P000392
o-Xylene
<0.40
ug/L
NE
0.50
0.40
1
8260D
3/19/20 19:02 JLB
P000392
Styrene
<0.26
ug/L
1
0.50
0.26
1
8260D
3/19/20 19:02 JLB
P000392
Tetrachloroethylene
<0.31
ug/L
1
0.50
0.31
1
8260D
3/19/20 19:02 JLB
P000392
Tetrahydrofuran
<0.68
ug/L
NE
10
0.68
1
8260D
3/19/20 19:02 JLB
P000392
Toluene
<0.35
ug/L
1
0.50
0.35
1
8260D
3/19/20 19:02 JLB
P000392
trans- 1,2-Dichloroethylene
<0.27
ug/L
5
0.50
0.27
1
8260D
3/19/20 19:02 JLB
P000392
trans- 1,3-Dichloropropylene
<0.49
ug/L
1
0.50
0.49
1
8260D
3/19/20 19:02 JLB
P000392
trans- 1,4-Dichloro-2-butene
<0.22
ug/L
100
10
0.22
1
8260D
3/19/20 19:02 JLB
P000392
Trichloroethylene
<0.46
ug/L
1
0.50
0.46
1
8260D
3/19/20 19:02 JLB
P000392
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
• � 03/27/2020
PA Waynt.�
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: MW-04-20200317
Attn: Alec Macbeth Spring Sample ID: 0030253-02
231 Haywood Street Project No.: 50-02 Work Order: 0030253
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/17/20 09:59
Time Submitted: 03/18/20 08:55
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
Trichlorofluoromethane
<0.24
Vinyl acetate
<0.26
Vinyl chloride
<0.41
Xylenes, total
<1.1
ug/L
1
0.50
0.24 1
8260D
3/19/20 19:02 JLB
P000392
ug/L
50
2.0
0.26 1
8260D
3/19/20 19:02 JLB
P000392
ug/L
1
0.50
0.41 1
8260D
3/19/20 19:02 JLB
P000392
ug/L
5
1.5
1.1 1
8260D
3/19/20 19:02 JLB
P000392
Surrogate
Recovery Control Limits
4-Bromofluorobenzene 102 % 80-124
Dibromofluoromethane 105 % 75-129
Toluene-d8 98 % 77-123
Volatile Organic Compounds by GUMS SIM
1,4-Dioxane 3.0 ug/L 10 2.0 0.14 1 8260D SIM 3/18/20 17:49 TBL P000356
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
• � 03/27/2020
PA Waynt.�
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: MW-07-20200317
Attn: Alec Macbeth Spring Sample ID: 0030253-03
231 Haywood Street Project No.: 50-02 Work Order: 0030253
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/17/20 11:39
Time Submitted: 03/18/20 08:55
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
Anions by Ion Chromatography
Chloride
79000
ug/L
NE
1000
380
1
9056A
3/18/20 12:18 BMS
P000366
Nitrate as N
94
J
ug/L
10000
200
54
1
9056A
3/18/20 12:18 BMS
P000366
Sulfate
28000
ug/L
250000
2000
480
1
9056A
3/18/20 12:18 BMS
P000366
General Chemistry Parameters
Biochemical Oxygen Demand
<210
BB
ug/L
NE
2000
210
1
SM5210 B
3/18/20 13:53 SLS
P000359
Chemical Oxygen Demand
19000
J
ug/L
NE
50000
10000
1
SM5220 D
3/19/20 12:08 SLS
P000397
Ferrous Iron
<51
HT
ug/L
NE
200
51
1
SM3500-Fe B
3/18/20 9:50 BMS
P000340
Sulfide
<830
ug/L
1000
2000
830
1
SM4500-S F
3/20/20 10:55 CBM
P000429
Total Alkalinity to pH 4.5
250000
ug/L
NE
5000
770
1
SM2320 B
3/20/20 10:00 CLB
P000387
Total Metals
Mercury
<0.034
ug/L
0.2
0.20
0.034
1
7470A
3/20/20 17:06 JAB
P000418
Antimony
<0.93
ug/L
6
3.0
0.93
1
6020B
3/19/20 22:37 MMR
P000369
Arsenic
<0.34
ug/L
10
1.0
0.34
1
6020B
3/19/20 22:37 MMR
P000369
Barium
460
ug/L
100
10
3.2
1
6020B
3/19/20 22:37 MMR
P000369
Beryllium
<0.30
ug/L
1
1.0
0.30
1
6020B
3/19/20 22:37 MMR
P000369
Cadmium
<0,22
ug/L
1
1.0
0.22
1
6020B
3/19/20 22:37 MMR
P000369
Chromium
<0.90
ug/L
10
3.0
0.90
1
6020B
3/19/20 22:37 MMR
P000369
Cobalt
1.5 J
ug/L
10
2.0
0.70
1
6020B
3/19/20 22:37 MMR
P000369
Copper
<4.7
ug/L
10
10
4.7
1
6020B
3/19/20 22:37 MMR
P000369
Lead
<0.44
ug/L
10
1.0
0.44
1
6020B
3/19/20 22:37 MMR
P000369
Nickel
6.9
ug/L
50
3.0
0.83
1
6020B
3/19/20 22:37 MMR
P000369
Selenium
<0.98
ug/L
10
5.0
0.98
1
6020B
3/19/20 22:37 MMR
P000369
Silver
<0.34
ug/L
10
1.0
0.34
1
6020B
3/19/20 22:37 MMR
P000369
Thallium
<0.84
ug/L
5.5
2.0
0.84
1
6020B
3/19/20 22:37 MMR
P000369
Vanadium
<1.5
ug/L
25
5.0
1.5
1
6020B
3/19/20 22:37 MMR
P000369
Zinc
<10
ug/L
10
20
10
1
6020B
3/19/20 22:37 MMR
P000369
Volatile Organic Compounds by GUMS
1, 1, 1,2-Tetrachloroethane
<0.35
ug/L
5
0.50
0.35
1
8260D
3/19/20 19:27 JLB
P000392
1, 1, 1 -Trichloroethane
<0.31
ug/L
1
0.50
0.31
1
8260D
3/19/20 19:27 JLB
P000392
1,1,2,2-Tetrachloroethane
<0.34
ug/L
3
0.50
0.34
1
8260D
3/19/20 19:27 JLB
P000392
1,1,2-Trichloroethane
<0.42
ug/L
1
0.50
0.42
1
8260D
3/19/20 19:27 JLB
P000392
1,1-Dichloroethane
<0.29
ug/L
5
0.50
0.29
1
8260D
3/19/20 19:27 JLB
P000392
1,1-Dichloroethylene
<0.35
ug/L
5
0.50
0.35
1
8260D
3/19/20 19:27 JLB
P000392
1,2,3-Trichloropropane
<0.34
ug/L
1
1.0
0.34
1
8260D
3/19/20 19:27 JLB
P000392
1,2-Dibromo-3-chloropropane
<0.59
ug/L
13
2.0
0.59
1
8260D
3/19/20 19:27 JLB
P000392
1,2-Dibromoethane
<0.37
ug/L
1
0.50
0.37
1
8260D
3/19/20 19:27 JLB
P000392
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
A i • .0 03/27/2020
- -ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: MW-07-20200317
Attn: Alec Macbeth Spring Sample ID: 0030253-03
231 Haywood Street Project No.: 50-02 Work Order: 0030253
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/17/20 11:39
Time Submitted: 03/18/20 08:55
Parameter
Result
Units
SWSL
Report
Limit
MDL
Dilution
Factor
Method
Analysis Analyst
Date/Time
Batch
ID
1,2-Dichlorobenzene
<0.28
ug/L
5
0.50
0.28
1
8260D
3/19/20 19:27 JLB
P000392
1,2-Dichloroethane
<0.41
ug/L
1
0.50
0.41
1
8260D
3/19/20 19:27 JLB
P000392
1,2-Dichloropropane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/19/20 19:27 JLB
P000392
1,4-Dichlorobenzene
3.6
ug/L
1
0.50
0.42
1
8260D
3/19/20 19:27 JLB
P000392
Acetone
<0.70
ug/L
100
5.0
0.70
1
8260D
3/19/20 19:27 JLB
P000392
Acrylonitrile
<0.85
ug/L
200
20
0.85
1
8260D
3/19/20 19:27 JLB
P000392
Benzene
1.1
ug/L
1
0.50
0.34
1
8260D
3119/20 19:27 JLB
P000392
Bromochloromethane
<0.53
ug/L
3
2.0
0.53
1
8260D
3/19/20 19:27 JLB
P000392
Bromodichloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/19/20 19:27 JLB
P000392
Bromoform
<0.26
ug/L
3
1.0
0.26
1
8260D
3/19/20 19:27 JLB
P000392
Bromomethane
<0.48
ug/L
10
1.0
0.48
1
8260D
3/19/20 19:27 JLB
P000392
Carbon disulfide
<0.36
ug/L
100
5.0
0.36
1
8260D
3/19/20 19:27 JLB
P000392
Carbon Tetrachloride
<0.55
ug/L
1
2.0
0.55
1
8260D
3/19/20 19:27 JLB
P000392
Chlorobenzene
3.8
ug/L
3
0.50
0.34
1
8260D
3/19/20 19:27 JLB
P000392
Chloroethane
<0.43
ug/L
10
0.50
0.43
1
8260D
3/19/20 19:27 JLB
P000392
Chloroform
<0.48
ug/L
5
0.50
0.48
1
8260D
3/19/20 19:27 JLB
P000392
Chloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/19/20 19:27 JLB
P000392
cis-1,2-Dichloroethylene
1.8
ug/L
5
0.50
0.40
1
8260D
3/19/20 19:27 JLB
P000392
cis- 1,3-Dichloropropylene
<0.36
ug/L
1
0.50
0.36
1
8260D
3/19/20 19:27 JLB
P000392
Dibromochloromethane
<0.42
ug/L
3
0.50
0.42
1
8260D
3/19/20 19:27 JLB
P000392
Dibromomethane
<0.54
ug/L
10
2.0
0.54
1
8260D
3/19/20 19:27 JLB
P000392
Ethylbenzene
<0.31
ug/L
1
0.50
0.31
1
8260D
3/19/20 19:27 JLB
P000392
m,p-Xylenes
<0.73
ug/L
NE
1.0
0.73
1
8260D
3/19/20 19:27 JLB
P000392
Methyl Butyl Ketone (2-Hexanone)
<0.29
ug/L
50
5.0
0.29
1
8260D
3/19/20 19:27 JLB
P000392
Methyl Ethyl Ketone (2-Butanone)
<0.78
ug/L
100
5.0
0.78
1
8260D
3/19/20 19:27 JLB
P000392
Methyl Iodide
<0.41
ug/L
10
5.0
0.41
1
8260D
3/19/20 19:27 JLB
P000392
Methyl Isobutyl Ketone
<0.40
ug/L
100
5.0
0.40
1
8260D
3/19/20 19:27 JLB
P000392
Methylene Chloride
<0.40
ug/L
1
1.0
0.40
1
8260D
3/19/20 19:27 JLB
P000392
o-Xylene
<0.40
ug/L
NE
0.50
0.40
1
8260D
3/19/20 19:27 JLB
P000392
Styrene
<0.26
ug/L
1
0.50
0.26
1
8260D
3/19/20 19:27 JLB
P000392
Tetrachloroethylene
<0.31
ug/L
1
0.50
0.31
1
8260D
3/19/20 19:27 JLB
P000392
Tetrahydrofuran
2.3 J
ug/L
NE
10
0.68
1
8260D
3/19/20 19:27 JLB
P000392
Toluene
<0.35
ug/L
1
0.50
0.35
1
8260D
3/19/20 19:27 JLB
P000392
trans- 1,2-Dichloroethylene
<0.27
ug/L
5
0.50
0.27
1
8260D
3/19/20 19:27 JLB
P000392
trans- 1,3-Dichloropropylene
<0.49
ug/L
1
0.50
0.49
1
8260D
3/19/20 19:27 JLB
P000392
trans- 1,4-Dichloro-2-butene
<0.22
ug/L
100
10
0.22
1
8260D
3/19/20 19:27 JLB
P000392
Trichloroethylene
<0.46
ug/L
1
0.50
0.46
1
8260D
3/19/20 19:27 JLB
P000392
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
• � 03/27/2020
PA Waynt.�
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: MW-07-20200317
Attn: Alec Macbeth Spring Sample ID: 0030253-03
231 Haywood Street Project No.: 50-02 Work Order: 0030253
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/17/20 11:39
Time Submitted: 03/18/20 08:55
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
Trichlorofluoromethane
<0.24
Vinyl acetate
<0.26
Vinyl chloride
<0.41
Xylenes, total
<1.1
ug/L
1
0.50
0.24 1
8260D
3/19/20 19:27 JLB
P000392
ug/L
50
2.0
0.26 1
8260D
3/19/20 19:27 JLB
P000392
ug/L
1
0.50
0.41 1
8260D
3/19/20 19:27 JLB
P000392
ug/L
5
1.5
1.1 1
8260D
3/19/20 19:27 JLB
P000392
Surrogate
Recovery Control Limits
4-Bromofluorobenzene 101 % 80-124
Dibromofluoromethane 104 % 75-129
Toluene-d8 100 % 77-123
Volatile Organic Compounds by GUMS SIM
1,4-Dioxane 17 ug/L 10 2.0 0.14 1 8260D SIM 3/18/20 18:14 TBL P000356
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
• � 03/27/2020
PA Waynt.�
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: SW-01-20200317
Attn: Alec Macbeth Spring Sample ID: 0030253-04
231 Haywood Street Project No.: 50-02 Work Order: 0030253
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/17/20 12:45
Time Submitted: 03/18/20 08:55
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
General Chemistry Parameters
Hardness 11000 ug/L 5000 570 1 SM2340 C 3/18/20 12:36 BMS P000351
Total Metals
Mercury
<0.034
ug/L
0.2
0.20
0.034
1
7470A
3/20/20 17:17 JAB
P000418
Antimony
<0.93
ug/L
6
3.0
0.93
1
6020B
3/19/20 22:44 MMR
P000369
Arsenic
<0.34
ug/L
10
1.0
0.34
1
6020B
3/19/20 22:44 MMR
P000369
Barium
42
ug/L
100
10
3.2
1
6020B
3/19/20 22:44 MMR
P000369
Beryllium
<0.30
ug/L
1
1.0
0.30
1
6020B
3/19/20 22:44 MMR
P000369
Cadmium
<0.22
ug/L
1
1.0
0.22
1
6020B
3/19/20 22:44 MMR
P000369
Chromium
4.1
ug/L
10
3.0
0.90
1
6020B
3/19/20 22:44 MMR
P000369
Cobalt
1.5 1
ug/L
10
2.0
0.70
1
6020B
3/19/20 22:44 MMR
P000369
Copper
<4.7
ug/L
10
10
4.7
1
6020B
3/19/20 22:44 MMR
P000369
Lead
1.8
ug/L
10
1.0
0.44
1
6020B
3/19/20 22:44 MMR
P000369
Nickel
2.6 1
ug/L
50
3.0
0.83
1
6020B
3/19/20 22:44 MMR
P000369
Selenium
<0.98
ug/L
10
5.0
0.98
1
6020B
3/19/20 22:44 MMR
P000369
Silver
<0.34
ug/L
10
1.0
0.34
1
6020B
3/19/20 22:44 MMR
P000369
Thallium
<0.84
ug/L
5.5
2.0
0.84
1
6020B
3/19/20 22:44 MMR
P000369
Vanadium
5.7
ug/L
25
5.0
1.5
1
6020B
3/19/20 22:44 MMR
P000369
Zinc
15 1
ug/L
10
20
10
1
6020B
3/19/20 22:44 MMR
P000369
Volatile Organic Compounds by GUMS
1, 1, 1,2-Tetrachloroethane
<0.35
ug/L
5
0.50
0.35
1
8260D
3/19/20 17:26 JLB
P000398
1, 1, 1 -Trichloroethane
<0.31
ug/L
1
0.50
0.31
1
8260D
3/19/20 17:26 JLB
P000398
1,1,2,2-Tetrachloroethane
<0.34
ug/L
3
0.50
0.34
1
8260D
3/19/20 17:26 JLB
P000398
1,1,2-Trichloroethane
<0.42
ug/L
1
0.50
0.42
1
8260D
3/19/20 17:26 JLB
P000398
1,1-Dichloroethane
<0.29
ug/L
5
0.50
0.29
1
8260D
3/19/20 17:26 JLB
P000398
1,1-Dichloroethylene
<0.35
ug/L
5
0.50
0.35
1
8260D
3/19/20 17:26 JLB
P000398
1,2,3-Trichloropropane
<0.34
ug/L
1
1.0
0.34
1
8260D
3/19/20 17:26 JLB
P000398
1,2-Dibromo-3-chloropropane
<0.59
ug/L
13
2.0
0.59
1
8260D
3/19/20 17:26 JLB
P000398
1,2-Dibromoethane
<0.37
ug/L
1
0.50
0.37
1
8260D
3/19/20 17:26 JLB
P000398
1,2-Dichlorobenzene
<0.28
ug/L
5
0.50
0.28
1
8260D
3/19/20 17:26 JLB
P000398
1,2-Dichloroethane
<0.41
ug/L
1
0.50
0.41
1
8260D
3/19/20 17:26 JLB
P000398
1,2-Dichloropropane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/19/20 17:26 JLB
P000398
1,4-Dichlorobenzene
<0.42
ug/L
1
0.50
0.42
1
8260D
3/19/20 17:26 JLB
P000398
Acetone
<0.70
ug/L
100
5.0
0.70
1
8260D
3/19/20 17:26 JLB
P000398
Acrylonitrile
<0.85
ug/L
200
20
0.85
1
8260D
3/19/20 17:26 JLB
P000398
Benzene
<0.34
ug/L
1
0.50
0.34
1
8260D
3/19/20 17:26 JLB
P000398
Bromochloromethane
<0.53
ug/L
3
2.0
0.53
1
8260D
3/19/20 17:26 JLB
P000398
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
A i • .0 03/27/2020
- -ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: SW-01-20200317
Attn: Alec Macbeth Spring Sample ID: 0030253-04
231 Haywood Street Project No.: 50-02 Work Order: 0030253
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/17/20 12:45
Time Submitted: 03/18/20 08:55
Parameter
Result
Units
SWSL
Report
Limit
MDL
Dilution
Factor
Method
Analysis Analyst
Date/Time
Batch
ID
Bromodichloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/19/20 17:26 JLB
P000398
Bromoform
<0.26
ug/L
3
1.0
0.26
1
8260D
3/19/20 17:26 JLB
P000398
Bromomethane
<0.48
ug/L
10
1.0
0.48
1
8260D
3/19/20 17:26 JLB
P000398
Carbon disulfide
<0.36
ug/L
100
5.0
0.36
1
8260D
3/19/20 17:26 JLB
P000398
Carbon Tetrachloride
<0.55
ug/L
1
2.0
0.55
1
8260D
3/19/20 17:26 JLB
P000398
Chlorobenzene
<0.34
ug/L
3
0.50
0.34
1
8260D
3/19/20 17:26 JLB
P000398
Chloroethane
<0.43
ug/L
10
0.50
0.43
1
8260D
3/19/20 17:26 JLB
P000398
Chloroform
<0.48
ug/L
5
0.50
0.48
1
8260D
3/19/20 17:26 JLB
P000398
Chloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/19/20 17:26 JLB
P000398
cis- 1,2-Dichloroethylene
<0.40
ug/L
5
0.50
0.40
1
8260D
3/19/20 17:26 JLB
P000398
cis- 1,3-Dichloropropylene
<0.36
ug/L
1
0.50
0.36
1
8260D
3/19/20 17:26 JLB
P000398
Dibromochloromethane
<0.42
ug/L
3
0.50
0.42
1
8260D
3/19/20 17:26 JLB
P000398
Dibromomethane
<0.54
ug/L
10
2.0
0.54
1
8260D
3/19/20 17:26 JLB
P000398
Ethylbenzene
<0.31
ug/L
1
0.50
0.31
1
8260D
3/19/20 17:26 JLB
P000398
m,p-Xylenes
<0.73
ug/L
NE
1.0
0.73
1
8260D
3/19/20 17:26 JLB
P000398
Methyl Butyl Ketone (2-Hexanone)
<0.29
ug/L
50
5.0
0.29
1
8260D
3/19/20 17:26 JLB
P000398
Methyl Ethyl Ketone (2-Butanone)
<0.78
ug/L
100
5.0
0.78
1
8260D
3/19/20 17:26 JLB
P000398
Methyl Iodide
<0.41
ug/L
10
5.0
0.41
1
8260D
3/19/20 17:26 JLB
P000398
Methyl Isobutyl Ketone
<0.40
ug/L
100
5.0
0.40
1
8260D
3/19/20 17:26 JLB
P000398
Methylene Chloride
<0.40
ug/L
1
1.0
0.40
1
8260D
3/19/20 17:26 JLB
P000398
o-Xylene
<0.40
ug/L
NE
0.50
0.40
1
8260D
3/19/20 17:26 JLB
P000398
Styrene
<0.26
ug/L
1
0.50
0.26
1
8260D
3/19/20 17:26 JLB
P000398
Tetrachloroethylene
<0.31
ug/L
1
0.50
0.31
1
8260D
3/19/20 17:26 JLB
P000398
Tetrahydrofuran
<0.68
ug/L
NE
10
0.68
1
8260D
3/19/20 17:26 JLB
P000398
Toluene
<0.35
ug/L
1
0.50
0.35
1
8260D
3/19/20 17:26 JLB
P000398
trans- 1,2-Dichloroethylene
<0.27
ug/L
5
0.50
0.27
1
8260D
3/19/20 17:26 JLB
P000398
trans- 1,3-Dichloropropylene
<0.49
ug/L
1
0.50
0.49
1
8260D
3/19/20 17:26 JLB
P000398
trans- 1,4-Dichloro-2-butene
<0.22
ug/L
100
10
0.22
1
8260D
3/19/20 17:26 JLB
P000398
Trichloroethylene
<0.46
ug/L
1
0.50
0.46
1
8260D
3/19/20 17:26 JLB
P000398
Trichlorofluoromethane
<0.24
ug/L
1
0.50
0.24
1
8260D
3/19/20 17:26 JLB
P000398
Vinyl acetate
<0.26
ug/L
50
2.0
0.26
1
8260D
3/19/20 17:26 JLB
P000398
Vinyl chloride
<0.41
ug/L
1
0.50
0.41
1
8260D
3/19/20 17:26 JLB
P000398
Xylenes, total
<1.1
ug/L
5
1.5
1.1
1
8260D
3/19/20 17:26 JLB
P000398
Surrogate
Recovery Control Limits
4-Bromofluorobenzene
100 % 80-124
Dibromofluoromethane
102 % 75-129
Toluene-d8
106 % 77-123
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
• � 03/27/2020
PA Waynt.�
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: SW-01-20200317
Attn: Alec Macbeth Spring Sample ID: 0030253-04
231 Haywood Street Project No.: 50-02 Work Order: 0030253
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/17/20 12:45
Time Submitted: 03/18/20 08:55
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
Volatile Organic Compounds by GC/MS SIM
1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 3/18/20 18:40 TBL P000356
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
• � 03/27/2020
PA Waynt.�
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: SW-02-20200317
Attn: Alec Macbeth Spring Sample ID: 0030253-05
231 Haywood Street Project No.: 50-02 Work Order: 0030253
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/17/20 13:00
Time Submitted: 03/18/20 08:55
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
General Chemistry Parameters
Hardness 10000 ug/L 5000 570 1 SM2340 C 3/18/20 12:36 BMS P000351
Total Metals
Mercury
<0.034
ug/L
0.2
0.20
0.034
1
7470A
3/20/20 17:21 JAB
P000418
Antimony
<0.93
ug/L
6
3.0
0.93
1
6020B
3/19/20 22:50 MMR
P000369
Arsenic
<0.34
ug/L
10
1.0
0.34
1
6020B
3/19/20 22:50 MMR
P000369
Barium
34
ug/L
100
10
3.2
1
6020B
3/19/20 22:50 MMR
P000369
Beryllium
<0.30
ug/L
1
1.0
0.30
1
6020B
3/19/20 22:50 MMR
P000369
Cadmium
<0.22
ug/L
1
1.0
0.22
1
6020B
3/19/20 22:50 MMR
P000369
Chromium
3.1
ug/L
10
3.0
0.90
1
6020B
3/19/20 22:50 MMR
P000369
Cobalt
1.2
J
ug/L
10
2.0
0.70
1
6020B
3/19/20 22:50 MMR
P000369
Copper
<4.7
ug/L
10
10
4.7
1
6020B
3/19/20 22:50 MMR
P000369
Lead
1.4
ug/L
10
1.0
0.44
1
6020B
3/19/20 22:50 MMR
P000369
Nickel
1.9
1
ug/L
50
3.0
0.83
1
6020B
3/19/20 22:50 MMR
P000369
Selenium
<0.98
ug/L
10
5.0
0.98
1
6020B
3/19/20 22:50 MMR
P000369
Silver
<0.34
ug/L
10
1.0
0.34
1
6020B
3/19/20 22:50 MMR
P000369
Thallium
<0.84
ug/L
5.5
2.0
0.84
1
6020B
3/19/20 22:50 MMR
P000369
Vanadium
4.5
1
ug/L
25
5.0
1.5
1
6020B
3/19/20 22:50 MMR
P000369
Zinc
12
J
ug/L
10
20
10
1
6020B
3119/20 22:50 MMR
P000369
Volatile Organic Compounds by GC/MS
1, 1, 1,2-Tetrachloroethane
<0.35
ug/L
5
0.50
0.35
1
8260D
3/19/20 17:01 JLB
P000398
1, 1, 1 -Trichloroethane
<0.31
ug/L
1
0.50
0.31
1
8260D
3/19/20 17:01 JLB
P000398
1,1,2,2-Tetrachloroethane
<0.34
ug/L
3
0.50
0.34
1
8260D
3/19/20 17:01 JLB
P000398
1,1,2-Trichloroethane
<0.42
ug/L
1
0.50
0.42
1
8260D
3/19/20 17:01 JLB
P000398
1,1-Dichloroethane
<0,29
ug/L
5
0.50
0.29
1
8260D
3/19/20 17:01 JLB
P000398
1,1-Dichloroethylene
<0.35
ug/L
5
0.50
0.35
1
8260D
3/19/20 17:01 JLB
P000398
1,2,3-Trichloropropane
<0.34
ug/L
1
1.0
0.34
1
8260D
3/19/20 17:01 JLB
P000398
1,2-Dibromo-3-chloropropane
<0.59
ug/L
13
2.0
0.59
1
8260D
3/19/20 17:01 JLB
P000398
1,2-Dibromoethane
<0.37
ug/L
1
0.50
0.37
1
8260D
3/19/20 17:01 JLB
P000398
1,2-Dichlorobenzene
<0.28
ug/L
5
0.50
0.28
1
8260D
3/19/20 17:01 JLB
P000398
1,2-Dichloroethane
<0.41
ug/L
1
0.50
0.41
1
8260D
3/19/20 17:01 JLB
P000398
1,2-Dichloropropane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/19/20 17:01 JLB
P000398
1,4-Dichlorobenzene
<0.42
ug/L
1
0.50
0.42
1
8260D
3/19/20 17:01 JLB
P000398
Acetone
<0.70
ug/L
100
5.0
0.70
1
8260D
3/19/20 17:01 JLB
P000398
Acrylonitrile
<0.85
ug/L
200
20
0.85
1
8260D
3/19/20 17:01 JLB
P000398
Benzene
<0.34
ug/L
1
0.50
0.34
1
8260D
3/19/20 17:01 JLB
P000398
Bromochloromethane
<0.53
ug/L
3
2.0
0.53
1
8260D
3/19/20 17:01 JLB
P000398
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
A i • .0 03/27/2020
- -ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: SW-02-20200317
Attn: Alec Macbeth Spring Sample ID: 0030253-05
231 Haywood Street Project No.: 50-02 Work Order: 0030253
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/17/20 13:00
Time Submitted: 03/18/20 08:55
Parameter
Result
Units
SWSL
Report
Limit
MDL
Dilution
Factor
Method
Analysis Analyst
Date/Time
Batch
ID
Bromodichloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/19/20 17:01 JLB
P000398
Bromoform
<0.26
ug/L
3
1.0
0.26
1
8260D
3/19/20 17:01 JLB
P000398
Bromomethane
<0.48
ug/L
10
1.0
0.48
1
8260D
3/19/20 17:01 JLB
P000398
Carbon disulfide
<0.36
ug/L
100
5.0
0.36
1
8260D
3/19/20 17:01 JLB
P000398
Carbon Tetrachloride
<0.55
ug/L
1
2.0
0.55
1
8260D
3/19/20 17:01 JLB
P000398
Chlorobenzene
<0.34
ug/L
3
0.50
0.34
1
8260D
3/19/20 17:01 JLB
P000398
Chloroethane
<0.43
ug/L
10
0.50
0.43
1
8260D
3/19/20 17:01 JLB
P000398
Chloroform
<0.48
ug/L
5
0.50
0.48
1
8260D
3/19/20 17:01 JLB
P000398
Chloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/19/20 17:01 JLB
P000398
cis- 1,2-Dichloroethylene
<0.40
ug/L
5
0.50
0.40
1
8260D
3/19/20 17:01 JLB
P000398
cis- 1,3-Dichloropropylene
<0.36
ug/L
1
0.50
0.36
1
8260D
3/19/20 17:01 JLB
P000398
Dibromochloromethane
<0.42
ug/L
3
0.50
0.42
1
8260D
3/19/20 17:01 JLB
P000398
Dibromomethane
<0.54
ug/L
10
2.0
0.54
1
8260D
3/19/20 17:01 JLB
P000398
Ethylbenzene
<0.31
ug/L
1
0.50
0.31
1
8260D
3/19/20 17:01 JLB
P000398
m,p-Xylenes
<0.73
ug/L
NE
1.0
0.73
1
8260D
3/19/20 17:01 JLB
P000398
Methyl Butyl Ketone (2-Hexanone)
<0.29
ug/L
50
5.0
0.29
1
8260D
3/19/20 17:01 JLB
P000398
Methyl Ethyl Ketone (2-Butanone)
<0.78
ug/L
100
5.0
0.78
1
8260D
3/19/20 17:01 JLB
P000398
Methyl Iodide
<0.41
ug/L
10
5.0
0.41
1
8260D
3/19/20 17:01 JLB
P000398
Methyl Isobutyl Ketone
<0.40
ug/L
100
5.0
0.40
1
8260D
3/19/20 17:01 JLB
P000398
Methylene Chloride
<0.40
ug/L
1
1.0
0.40
1
8260D
3/19/20 17:01 JLB
P000398
o-Xylene
<0.40
ug/L
NE
0.50
0.40
1
8260D
3/19/20 17:01 JLB
P000398
Styrene
<0.26
ug/L
1
0.50
0.26
1
8260D
3/19/20 17:01 JLB
P000398
Tetrachloroethylene
<0.31
ug/L
1
0.50
0.31
1
8260D
3/19/20 17:01 JLB
P000398
Tetrahydrofuran
<0.68
ug/L
NE
10
0.68
1
8260D
3/19/20 17:01 JLB
P000398
Toluene
<0.35
ug/L
1
0.50
0.35
1
8260D
3/19/20 17:01 JLB
P000398
trans- 1,2-Dichloroethylene
<0.27
ug/L
5
0.50
0.27
1
8260D
3/19/20 17:01 JLB
P000398
trans- 1,3-Dichloropropylene
<0.49
ug/L
1
0.50
0.49
1
8260D
3/19/20 17:01 JLB
P000398
trans- 1,4-Dichloro-2-butene
<0.22
ug/L
100
10
0.22
1
8260D
3/19/20 17:01 JLB
P000398
Trichloroethylene
<0.46
ug/L
1
0.50
0.46
1
8260D
3/19/20 17:01 JLB
P000398
Trichlorofluoromethane
<0.24
ug/L
1
0.50
0.24
1
8260D
3/19/20 17:01 JLB
P000398
Vinyl acetate
<0.26
ug/L
50
2.0
0.26
1
8260D
3/19/20 17:01 JLB
P000398
Vinyl chloride
<0.41
ug/L
1
0.50
0.41
1
8260D
3/19/20 17:01 JLB
P000398
Xylenes, total
<1.1
ug/L
5
1.5
1.1
1
8260D
3/19/20 17:01 JLB
P000398
Surrogate
Recovery Control Limits
4-Bromofluorobenzene
101 % 80-124
Dibromofluoromethane
104 % 75-129
Toluene-d8
105 % 77-123
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
• � 03/27/2020
PA Waynt.�
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: SW-02-20200317
Attn: Alec Macbeth Spring Sample ID: 0030253-05
231 Haywood Street Project No.: 50-02 Work Order: 0030253
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/17/20 13:00
Time Submitted: 03/18/20 08:55
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
Volatile Organic Compounds by GC/MS SIM
1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 3/18/20 19:05 TBL P000356
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
• � 03/27/2020
PA Waynt.�
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: TB-20200317
Attn: Alec Macbeth Spring Sample ID: 0030253-06
231 Haywood Street Project No.: 50-02 Work Order: 0030253
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/17/20 00:00
Time Submitted: 03/18/20 08:55
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
Volatile Organic Compounds by GC/MS
1, 1, 1,2-Tetrachloroethane
<0.35
ug/L
5
0.50
0.35
1
8260D
3/19/20 16:37 JLB
P000398
1, 1, 1 -Trichloroethane
<0.31
ug/L
1
0.50
0.31
1
8260D
3/19/20 16:37 JLB
P000398
1,1,2,2-Tetrachloroethane
<0.34
ug/L
3
0.50
0.34
1
8260D
3/19/20 16:37 JLB
P000398
1,1,2-Trichloroethane
<0.42
ug/L
1
0.50
0.42
1
8260D
3/19/20 16:37 JLB
P000398
1,1-Dichloroethane
<0.29
ug/L
5
0.50
0.29
1
8260D
3/19/20 16:37 JLB
P000398
1,1-Dichloroethylene
<0.35
ug/L
5
0.50
0.35
1
8260D
3/19/20 16:37 JLB
P000398
1,2,3-Trichloropropane
<0.34
ug/L
1
1.0
0.34
1
8260D
3/19/20 16:37 JLB
P000398
1,2-Dibromo-3-chloropropane
<0.59
ug/L
13
2.0
0.59
1
8260D
3/19/20 16:37 JLB
P000398
1,2-Dibromoethane
<0.37
ug/L
1
0.50
0.37
1
8260D
3/19/20 16:37 JLB
P000398
1,2-Dichlorobenzene
<0.28
ug/L
5
0.50
0.28
1
8260D
3/19/20 16:37 JLB
P000398
1,2-Dichloroethane
<0.41
ug/L
1
0.50
0.41
1
8260D
3/19/20 16:37 JLB
P000398
1,2-Dichloropropane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/19/20 16:37 JLB
P000398
1,4-Dichlorobenzene
<0.42
ug/L
1
0.50
0.42
1
8260D
3/19/20 16:37 JLB
P000398
Acetone
<0.70
ug/L
100
5.0
0.70
1
8260D
3/19/20 16:37 JLB
P000398
Acrylonitrile
<0.85
ug/L
200
20
0.85
1
8260D
3/19/20 16:37 JLB
P000398
Benzene
<0.34
ug/L
1
0.50
0.34
1
8260D
3/19/20 16:37 JLB
P000398
Bromochloromethane
<0.53
ug/L
3
2.0
0.53
1
8260D
3/19/20 16:37 JLB
P000398
Bromodichloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/19/20 16:37 JLB
P000398
Bromoform
<0.26
ug/L
3
1.0
0.26
1
8260D
3/19/20 16:37 JLB
P000398
Bromomethane
<0.48
ug/L
10
1.0
0.48
1
8260D
3/19/20 16:37 JLB
P000398
Carbon disulfide
<0.36
ug/L
100
5.0
0.36
1
8260D
3/19/20 16:37 JLB
P000398
Carbon Tetrachloride
<0.55
ug/L
1
2.0
0.55
1
8260D
3/19/20 16:37 JLB
P000398
Chlorobenzene
<0.34
ug/L
3
0.50
0.34
1
8260D
3/19/20 16:37 JLB
P000398
Chloroethane
<0.43
ug/L
10
0.50
0.43
1
8260D
3/19/20 16:37 JLB
P000398
Chloroform
<0.48
ug/L
5
0.50
0.48
1
8260D
3/19/20 16:37 JLB
P000398
Chloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/19/20 16:37 JLB
P000398
cis- 1,2-Dichloroethylene
<0.40
ug/L
5
0.50
0.40
1
8260D
3/19/20 16:37 JLB
P000398
cis- 1,3-Dichloropropylene
<0.36
ug/L
1
0.50
0.36
1
8260D
3/19/20 16:37 JLB
P000398
Dibromochloromethane
<0.42
ug/L
3
0.50
0.42
1
8260D
3/19/20 16:37 JLB
P000398
Dibromomethane
<0.54
ug/L
10
2.0
0.54
1
8260D
3/19/20 16:37 JLB
P000398
Ethylbenzene
<0.31
ug/L
1
0.50
0.31
1
8260D
3/19/20 16:37 JLB
P000398
m,p-Xylenes
<0.73
ug/L
NE
1.0
0.73
1
8260D
3/19/20 16:37 JLB
P000398
Methyl Butyl Ketone (2-Hexanone)
<0.29
ug/L
50
5.0
0.29
1
8260D
3/19/20 16:37 JLB
P000398
Methyl Ethyl Ketone (2-Butanone)
<0.78
ug/L
100
5.0
0.78
1
8260D
3/19/20 16:37 JLB
P000398
Methyl Iodide
<0.41
ug/L
10
5.0
0.41
1
8260D
3/19/20 16:37 JLB
P000398
Methyl Isobutyl Ketone
<0.40
ug/L
100
5.0
0.40
1
8260D
3/19/20 16:37 JLB
P000398
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

.
Laboratory Report
• �
Waynt..
03/27/2020
poi
ANALYTICAL
Anchor QEA of North Carolina, PLLC
Project: Jackson Cty Landfill 2020
Client Sample ID: TB-20200317
Attn: Alec Macbeth
Spring
Sample ID: 0030253-06
231 Haywood Street
Project No.:
50-02
Work Order: 0030253
Asheville, NC 28801
Sample Matrix:
Water
Time Collected: 03/17/20 00:00
Time Submitted: 03/18/20 08:55
Parameter
Result
Units
SWSL
Report
MDL
Dilution Method Analysis Analyst
Batch
Limit
Factor Date/Time
ID
Methylene Chloride
<0.40
ug/L
1
1.0
0.40
1 8260D 3/19/20 16:37 JLB
P000398
o-Xylene
<0.40
ug/L
NE
0.50
0.40
1 8260D 3/19/20 16:37 JLB
P000398
Styrene
<0.26
ug/L
1
0.50
0.26
1 8260D 3/19/20 16:37 JLB
P000398
Tetrachloroethylene
<0.31
ug/L
1
0.50
0.31
1 8260D 3/19/20 16:37 JLB
P000398
Tetrahydrofuran
<0.68
ug/L
NE
10
0.68
1 8260D 3/19/20 16:37 JLB
P000398
Toluene
<0.35
ug/L
1
0.50
0.35
1 8260D 3/19/20 16:37 JLB
P000398
trans- 1,2-Dichloroethylene
<0.27
ug/L
5
0.50
0.27
1 8260D 3/19/20 16:37 JLB
P000398
trans- 1,3-Dichloropropylene
<0.49
ug/L
1
0.50
0.49
1 8260D 3/19/20 16:37 JLB
P000398
trans- 1,4-Dichloro-2-butene
<0.22
ug/L
100
10
0.22
1 8260D 3/19/20 16:37 JLB
P000398
Trichloroethylene
<0.46
ug/L
1
0.50
0.46
1 8260D 3/19/20 16:37 JLB
P000398
Trichlorofluoromethane
<0.24
ug/L
1
0.50
0.24
1 8260D 3/19/20 16:37 JLB
P000398
Vinyl acetate
<0.26
ug/L
50
2.0
0.26
1 8260D 3/19/20 16:37 JLB
P000398
Vinyl chloride
<0.41
ug/L
1
0.50
0.41
1 8260D 3/19/20 16:37 JLB
P000398
Xylenes, total
<1.1
ug/L
5
1.5
1.1
1 8260D 3/19/20 16:37 JLB
P000398
Surrogate
Recovery Control Limits
4-Bromofluorobenzene
100 % 80-124
Dibromofluoromethane
103 % 75-129
Toluene-d8
105 % 77-123
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

(2)
Way po Int
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Spring
Attn: Alec Macbeth
231 Haywood Street Project No: 50-02
Asheville, NC 28801
Volatile Organic Compounds by GC/MS - Quality Control
Level II QC Report
3/27/20
Work Order: 0030253
Time Submitted: 3/18/2020 8:55:OOAM
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P000392 - SM6200 B
Blank (P000392-BLK1)
Prepared &Analyzed: 03/19/20
1,1,1,2-Tetrachloroethane
BRL
0.50
ug/L
1,1,1-Trichloroethane
BRL
0.50
ug/L
1,1,2,2-Tetrachloroethane
BRL
0.50
ug/L
1,1,2-Trichloroethane
BRL
0.50
ug/L
1,1-Dichloroethane
BRL
0.50
ug/L
1,1-Dichloroethylene
BRL
0.50
ug/L
1,2,3-Trichloropropane
BRL
1.0
ug/L
1,2-Dibromo-3-chloropropane
BRL
2.0
ug/L
1,2-Dibromoethane
BRL
0.50
ug/L
1,2-Dichlorobenzene
BRL
0.50
ug/L
1,2-Dichloroethane
BRL
0.50
ug/L
1,2-Dichloropropane
BRL
0.50
ug/L
1,4-Dichlorobenzene
BRL
0.50
ug/L
Acetone
BRL
5.0
ug/L
Acrylonitrile
BRL
20
ug/L
Benzene
BRL
0.50
ug/L
Bromochloromethane
BRL
2.0
ug/L
Bromodichloromethane
BRL
0.50
ug/L
Bromoform
BRL
1.0
ug/L
Bromomethane
BRL
1.0
ug/L
Carbon disulfide
BRL
5.0
ug/L
Carbon Tetrachloride
BRL
2.0
ug/L
Chlorobenzene
BRL
0.50
ug/L
Chloroethane
BRL
0.50
ug/L
Chloroform
BRL
0.50
ug/L
Chloromethane
BRL
0.50
ug/L
cis-1,2-Dichloroethylene
BRL
0.50
ug/L
cis-1,3-Dichloropropylene
BRL
0.50
ug/L
Dibromochloromethane
BRL
0.50
ug/L
Dibromomethane
BRL
2.0
ug/L
Ethylbenzene
BRL
0.50
ug/L
m,p-Xylenes
BRL
1.0
ug/L
Methyl Butyl Ketone (2-Hexanone)
BRL
5.0
ug/L
Methyl Ethyl Ketone (2-Butanone)
BRL
5.0
ug/L
Methyl Iodide
BRL
5.0
ug/L
Methyl Isobutyl Ketone
BRL
5.0
ug/L
Methylene Chloride
BRL
1.0
ug/L
o-Xylene
BRL
0.50
ug/L
Styrene
BRL
0.50
ug/L
Tetrachloroethylene
BRL
0.50
ug/L
Tetrahydrofuran
BRL
10
ug/L
Toluene
BRL
0.50
ug/L
trans-1,2-Dichloroethylene
BRL
0.50
ug/L
trans-1,3-Dichloropropylene
BRL
0.50
ug/L
trans-1,4-Dichloro-2-butene
BRL
10
ug/L
Trichloroethylene
BRL
0.50
ug/L
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Waypoint '
ANALYTICAL
Level II QC Report
3/27/20
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Spring Work Order: 0030253
Attn: Alec Macbeth Time Submitted: 3/18/2020 8:55:OOAM
231 Haywood Street Project No: 50-02
Asheville, NC 28801
Volatile Organic Compounds by GC/MS - Quality Control
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P000392 - SM6200 B
Blank (P000392-BLK1)
Prepared & Analyzed: 03/19/20
Trichlorofluoromethane
BRL
0.50
ug/L
Vinyl acetate
BRL
2.0
ug/L
Vinyl chloride
BRL
0.50
ug/L
Xylenes, total
BRL
1.5
ug/L
Surrogate:4-Bromofluorobenzene
50.9
ug/L
50.00
102
80-124
Surrogate: Dibromofluoromethane
51.4
ug/L
50.00
103
75-129
Surrogate: Toluene-d8
49.8
ug/L
50.00
100
77-123
LCS (P000392-BSI)
Prepared &Analyzed: 03/19/20
1,1,1,2-Tetrachloroethane
19.0
0.50
ug/L
20.00
95
79-134
1,1,1-Trichloroethane
19.2
0.50
ug/L
20.00
96
75-136
1,1,2,2-Tetrachloroethane
18.6
0.50
ug/L
20.00
93
62-127
1,1,2-Trichloroethane
19.2
0.50
ug/L
20.00
96
70-140
1,1-Dichloroethane
19.8
0.50
ug/L
20.00
99
78-130
1,1-Dichloroethylene
18.6
0.50
ug/L
20.00
93
70-154
1,2,3-Trichloropropane
18.3
1.0
ug/L
20.00
92
71-127
1,2-Dibromo-3-chloropropane
19.9
2.0
ug/L
20.00
100
63-134
1,2-Dibromoethane
19.1
0.50
ug/L
20.00
95
77-135
1,2-Dichlorobenzene
20.7
0.50
ug/L
20.00
103
78-128
1,2-Dichloroethane
18.0
0.50
ug/L
20.00
90
68-131
1,2-Dichloropropane
19.2
0.50
ug/L
20.00
96
77-130
1,4-Dichlorobenzene
19.5
0.50
ug/L
20.00
98
75-126
Acetone
29.1
5.0
ug/L
40.00
73
40-166
Acrylonitrile
36.5
20
ug/L
40.00
91
81-127
Benzene
19.4
0.50
ug/L
20.00
97
77-128
Bromochloromethane
20.1
2.0
ug/L
20.00
100
78-135
Bromodichloromethane
18.7
0.50
ug/L
20.00
94
76-138
Bromoform
19.0
1.0
ug/L
20.00
95
71-135
Bromomethane
22.6
1.0
ug/L
20.00
113
41-168
Carbon disulfide
19.4
5.0
ug/L
20.00
97
59-135
Carbon Tetrachloride
19.6
2.0
ug/L
20.00
98
72-142
Chlorobenzene
19.0
0.50
ug/L
20.00
95
78-119
Chloroethane
20.8
0.50
ug/L
20.00
104
57-142
Chloroform
19.5
0.50
ug/L
20.00
98
77-130
Chloromethane
21.5
0.50
ug/L
20.00
107
47-145
cis-1,2-Dichloroethylene
18.5
0.50
ug/L
20.00
93
76-141
cis-1,3-Dichloropropylene
19.9
0.50
ug/L
20.00
99
65-140
Dibromochloromethane
18.8
0.50
ug/L
20.00
94
75-134
Dibromomethane
19.0
2.0
ug/L
20.00
95
76-138
Ethylbenzene
19.2
0.50
ug/L
20.00
96
80-127
m,p-Xylenes
39.6
1.0
ug/L
40.00
99
77-133
Methyl Butyl Ketone (2-Hexanone)
18.6
5.0
ug/L
20.00
93
64-137
Methyl Ethyl Ketone (2-Butanone)
18.5
5.0
ug/L
20.00
93
71-134
Methyl Iodide
19.1
5.0
ug/L
20.00
96
70-130
Methyl Isobutyl Ketone
19.1
5.0
ug/L
20.00
95
69-134
Methylene Chloride
17.1
1.0
ug/L
20.00
85
73-131
o-Xylene
19.2
0.50
ug/L
20.00
96
78-128
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

1 0
Waypoint
ANALYTICAL
Level II QC Report
3/27/20
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Spring Work Order: 0030253
Attn: Alec Macbeth Time Submitted: 3/18/2020 8:55:OOAM
231 Haywood Street Project No: 50-02
Asheville, NC 28801
Volatile Organic Compounds by GC/MS - Quality Control
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P000392 - SM6200 B
LCS (P000392-BSI)
Prepared &Analyzed: 03/19/20
Styrene
19.7
0.50
ug/L
20.00
99
78-129
Tetrachloroethylene
20.0
0.50
ug/L
20.00
100
80-129
Tetrahydrofuran
17.8
10
ug/L
20.00
89
70-130
Toluene
19.6
0.50
ug/L
20.00
98
76-131
trans-1,2-Dichloroethylene
19.1
0.50
ug/L
20.00
96
76-135
trans-1,3-Dichloropropylene
19.2
0.50
ug/L
20.00
96
67-140
trans-1,4-Dichloro-2-butene
14.7
10
ug/L
20.00
73
70-130
Trichloroethylene
19.5
0.50
ug/L
20.00
98
77-133
Trichlorofluoromethane
21.3
0.50
ug/L
20.00
107
62-148
Vinyl acetate
19.2
2.0
ug/L
20.00
96
34-167
Vinyl chloride
19.5
0.50
ug/L
20.00
97
57-141
Xylenes, total
58.9
1.5
ug/L
60.00
98
77-133
Surrogate:4-Bromofluorobenzene
50.1
ug/L
50.00
100
80-124
Surrogate: Dibromofluoromethane
51.7
ug/L
50.00
103
75-129
Surrogate: Toluene-d8
49.8
ug/L
50.00
100
77-123
Batch P000398 - 5030B
Blank (P000398-BLK1)
1,1,1,2-Tetrachloroethane
BRL
0.50
ug/L
1,1,1-Trichloroethane
BRL
0.50
ug/L
1,1,2,2-Tetrachloroethane
BRL
0.50
ug/L
1,1,2-Trichloroethane
BRL
0.50
ug/L
1,1-Dichloroethane
BRL
0.50
ug/L
1,1-Dichloroethylene
BRL
0.50
ug/L
1,2,3-Trichloropropane
BRL
1.0
ug/L
1,2-Dibromo-3-chloropropane
BRL
2.0
ug/L
1,2-Dibromoethane
BRL
0.50
ug/L
1,2-Dichlorobenzene
BRL
0.50
ug/L
1,2-Dichloroethane
BRL
0.50
ug/L
1,2-Dichloropropane
BRL
0.50
ug/L
1,4-Dichlorobenzene
BRL
0.50
ug/L
Acetone
0.710
5.0
ug/L
Acrylonitrile
BRL
20
ug/L
Benzene
BRL
0.50
ug/L
Bromochloromethane
BRL
2.0
ug/L
Bromodichloromethane
BRL
0.50
ug/L
Bromoform
BRL
1.0
ug/L
Bromomethane
BRL
1.0
ug/L
Carbon disulfide
BRL
5.0
ug/L
Carbon Tetrachloride
BRL
2.0
ug/L
Chlorobenzene
BRL
0.50
ug/L
Chloroethane
BRL
0.50
ug/L
Chloroform
BRL
0.50
ug/L
Chloromethane
BRL
0.50
ug/L
cis-1,2-Dichloroethylene
BRL
0.50
ug/L
cis-1,3-Dichloropropylene
BRL
0.50
ug/L
Prepared & Analyzed: 03/19/20
J
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Waypoint '
ANALYTICAL
Level II QC Report
3/27/20
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Spring Work Order: 0030253
Attn: Alec Macbeth Time Submitted: 3/18/2020 8:55:OOAM
231 Haywood Street Project No: 50-02
Asheville, NC 28801
Volatile Organic Compounds by GC/MS - Quality Control
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P000398 - 5030B
Blank (P000398-BLK1)
Prepared & Analyzed: 03/19/20
Dibromochloromethane
BRL
0.50
ug/L
Dibromomethane
BRL
2.0
ug/L
Ethylbenzene
BRL
0.50
ug/L
m,p-Xylenes
BRL
1.0
ug/L
Methyl Butyl Ketone (2-Hexanone)
BRL
5.0
ug/L
Methyl Ethyl Ketone (2-Butanone)
BRL
5.0
ug/L
Methyl Iodide
BRL
5.0
ug/L
Methyl Isobutyl Ketone
BRL
5.0
ug/L
Methylene Chloride
BRL
1.0
ug/L
o-Xylene
BRL
0.50
ug/L
Styrene
BRL
0.50
ug/L
Tetrachloroethylene
BRL
0.50
ug/L
Tetrahydrofuran
BRL
10
ug/L
Toluene
BRL
0.50
ug/L
trans- 1,2-Dichloroethylene
BRL
0.50
ug/L
trans- 1,3-Dichloropropylene
BRL
0.50
ug/L
trans-1,4-Dichloro-2-butene
BRL
10
ug/L
Trichloroethylene
BRL
0.50
ug/L
Trichlorofluoromethane
BRL
0.50
ug/L
Vinyl acetate
BRL
2.0
ug/L
Vinyl chloride
BRL
0.50
ug/L
Xylenes, total
BRL
1.5
ug/L
Surrogate:4-Bromofluorobenzene
49.3
ug/L
50.00
99
80-124
Surrogate: Dibromofluoromethane
51.4
ug/L
50.00
103
75-129
Surrogate: Toluene-d8
52.2
ug/L
50.00
104
77-123
LCS (P000398-BSI)
Prepared &Analyzed: 03/19/20
1,1,1,2-Tetrachloroethane
20.9
0.50
ug/L
20.00
104
79-134
1,1,1-Trichloroethane
19.9
0.50
ug/L
20.00
99
75-136
1,1,2,2-Tetrachloroethane
22.0
0.50
ug/L
20.00
110
62-127
1,1,2-Trichloroethane
20.0
0.50
ug/L
20.00
100
70-140
1,1-Dichloroethane
20.0
0.50
ug/L
20.00
100
78-130
1,1-Dichloroethylene
18.4
0.50
ug/L
20.00
92
70-154
1,2,3-Trichloropropane
21.8
1.0
ug/L
20.00
109
71-127
1,2-Dibromo-3-chloropropane
23.3
2.0
ug/L
20.00
116
63-134
1,2-Dibromoethane
21.8
0.50
ug/L
20.00
109
77-135
1,2-Dichlorobenzene
22.2
0.50
ug/L
20.00
ill
78-128
1,2-Dichloroethane
19.0
0.50
ug/L
20.00
95
68-131
1,2-Dichloropropane
20.1
0.50
ug/L
20.00
101
77-130
1,4-Dichlorobenzene
21.5
0.50
ug/L
20.00
107
75-126
Acetone
31.1
5.0
ug/L
40.00
78
40-166
Acrylonitrile
39.9
20
ug/L
40.00
100
81-127
Benzene
19.5
0.50
ug/L
20.00
97
77-128
Bromochloromethane
20.3
2.0
ug/L
20.00
101
78-135
Bromodichloromethane
19.4
0.50
ug/L
20.00
97
76-138
Bromoform
19.2
1.0
ug/L
20.00
96
71-135
Bromomethane
17.5
1.0
ug/L
20.00
87
41-168
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

1 0
Waypoint
ANALYTICAL
Level II QC Report
3/27/20
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Spring Work Order: 0030253
Attn: Alec Macbeth Time Submitted: 3/18/2020 8:55:OOAM
231 Haywood Street Project No: 50-02
Asheville, NC 28801
Volatile Organic Compounds by GC/MS - Quality Control
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P000398 - 5030B
LCS (P000398-BSI)
Prepared &Analyzed: 03/19/20
Carbon disulfide
19.0
5.0
ug/L
20.00
95
59-135
Carbon Tetrachloride
20.2
2.0
ug/L
20.00
101
72-142
Chlorobenzene
20.5
0.50
ug/L
20.00
102
78-119
Chloroethane
16.0
0.50
ug/L
20.00
80
57-142
Chloroform
19.7
0.50
ug/L
20.00
99
77-130
Chloromethane
22.1
0.50
ug/L
20.00
110
47-145
cis-1,2-Dichloroethylene
19.2
0.50
ug/L
20.00
96
76-141
cis-1,3-Dichloropropylene
21.4
0.50
ug/L
20.00
107
65-140
Dibromochloromethane
22.6
0.50
ug/L
20.00
113
75-134
Dibromomethane
20.4
2.0
ug/L
20.00
102
76-138
Ethylbenzene
20.7
0.50
ug/L
20.00
104
80-127
m,p-Xylenes
42.9
1.0
ug/L
40.00
107
77-133
Methyl Butyl Ketone (2-Hexanone)
22.4
5.0
ug/L
20.00
112
64-137
Methyl Ethyl Ketone (2-Butanone)
18.3
5.0
ug/L
20.00
91
71-134
Methyl Iodide
18.4
5.0
ug/L
20.00
92
70-130
Methyl Isobutyl Ketone
21.6
5.0
ug/L
20.00
108
69-134
Methylene Chloride
18.6
1.0
ug/L
20.00
93
73-131
o-Xylene
21.2
0.50
ug/L
20.00
106
78-128
Styrene
21.9
0.50
ug/L
20.00
110
78-129
Tetrachloroethylene
21.1
0.50
ug/L
20.00
106
80-129
Tetrahydrofuran
20.2
10
ug/L
20.00
101
70-130
Toluene
19.7
0.50
ug/L
20.00
99
76-131
trans-1,2-Dichloroethylene
19.2
0.50
ug/L
20.00
96
76-135
trans- 1,3-Dichloropropylene
21.2
0.50
ug/L
20.00
106
67-140
trans-1,4-Dichloro-2-butene
16.5
10
ug/L
20.00
83
70-130
Trichloroethylene
19.5
0.50
ug/L
20.00
98
77-133
Trichlorofluoromethane
21.0
0.50
ug/L
20.00
105
62-148
Vinyl acetate
20.8
2.0
ug/L
20.00
104
34-167
Vinyl chloride
20.3
0.50
ug/L
20.00
102
57-141
Xylenes, total
64.0
1.5
ug/L
60.00
107
77-133
Surrogate:4-Bromofluorobenzene
50.0
ug/L
50.00
100
80-124
Surrogate: Dibromofluoromethane
50.3
ug/L
50.00
101
75-129
Surrogate: Toluene-d8
52.2
ug/L
50.00
104
77-123
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

1 0
Waypoint
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Spring
Attn: Alec Macbeth
231 Haywood Street Project No: 50-02
Asheville, NC 28801
Volatile Organic Compounds by GC/MS SIM - Quality Control
Level II QC Report
3/27/20
Work Order: 0030253
Time Submitted: 3/18/2020 8:55:OOAM
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P000356 - 5030B
Blank (P000356-BLK1) Prepared & Analyzed: 03/18/20
1,4-Dioxane BRL 2.0 ug/L
LCS (P000356-BS1) Prepared &Analyzed: 03/18/20
1,4-Dioxane 50.0 2.0 ug/L 50.00 100 55-145
Matrix Spike (P000356-MS1) Source: 0030253-01 Prepared & Analyzed: 03/18/20
1,4-Dioxane 48.6 2.0 ug/L 50.00 BRL 97 55-145
Matrix Spike Dup (P000356-MSD1) Source: 0030253-01 Prepared & Analyzed: 03/18/20
1,4-Dioxane 50.4 2.0 ug/L 50.00 BRL 101 55-145 4 30
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

1 0
Waypoint
ANALYTICAL
Anchor QEA of North Carolina, PLLC
Attn: Alec Macbeth
231 Haywood Street
Asheville, NC 28801
Total Metals - Quality Control
Analyte
Project: Jackson Cty Landfill 2020 Spring
Project No: 50-02
Level II QC Report
3/27/20
Work Order: 0030253
Time Submitted: 3/18/2020 8:55:OOAM
Reporting Spike Source %REC RPD
Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P000369 - 3005A
Blank (P000369-BLK1)
Prepared & Analyzed: 03/19/20
Antimony
BRL
3.0
ug/L
Arsenic
BRL
1.0
ug/L
Barium
BRL
10
ug/L
Beryllium
BRL
1.0
ug/L
Cadmium
BRL
1.0
ug/L
Chromium
BRL
3.0
ug/L
Cobalt
BRL
2.0
ug/L
Copper
BRL
10
ug/L
Lead
BRL
1.0
ug/L
Nickel
BRL
3.0
ug/L
Selenium
BRL
5.0
ug/L
Silver
BRL
1.0
ug/L
Thallium
BRL
2.0
ug/L
Vanadium
BRL
5.0
ug/L
Zinc
BRL
20
ug/L
LCS (P000369-BSI)
Prepared &Analyzed: 03/19/20
Antimony
107
3.0
ug/L
100.0 107
80-120
Arsenic
101
1.0
ug/L
100.0 101
80-120
Barium
104
10
ug/L
100.0 104
80-120
Beryllium
104
1.0
ug/L
100.0 104
80-120
Cadmium
103
1.0
ug/L
100.0 103
80-120
Chromium
103
3.0
ug/L
100.0 103
80-120
Cobalt
102
2.0
ug/L
100.0 102
80-120
Copper
100
10
ug/L
100.0 100
80-120
Lead
104
1.0
ug/L
100.0 104
80-120
Nickel
101
3.0
ug/L
100.0 101
80-120
Selenium
101
5.0
ug/L
100.0 101
80-120
Silver
103
1.0
ug/L
100.0 103
80-120
Thallium
101
2.0
ug/L
100.0 101
80-120
Vanadium
104
5.0
ug/L
100.0 104
80-120
Zinc
102
20
ug/L
100.0 102
80-120
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

1 0
Waypoint
ANALYTICAL
Anchor QEA of North Carolina, PLLC
Attn: Alec Macbeth
231 Haywood Street
Asheville, NC 28801
Total Metals - Quality Control
Analyte
Batch P000369 - 3005A
Project: Jackson Cty Landfill 2020 Spring
Project No: 50-02
Level II QC Report
3/27/20
Work Order: 0030253
Time Submitted: 3/18/2020 8:55:OOAM
Reporting Spike Source %REC RPD
Result Limit Units Level Result %REC Limits RPD Limit Notes
Matrix Spike (P000369-MS1)
Source: 0030253-01
Prepared & Analyzed: 03/19/20
Antimony
111
3.0
ug/L
100.0
BRL
111
75-125
Arsenic
102
1.0
ug/L
100.0
0.368
102
75-125
Barium
235
10
ug/L
100.0
130
105
75-125
Beryllium
107
1.0
ug/L
100.0
BRL
107
75-125
Cadmium
106
1.0
ug/L
100.0
BRL
106
75-125
Chromium
104
3.0
ug/L
100.0
1.75
102
75-125
Cobalt
103
2.0
ug/L
100.0
1.76
101
75-125
Copper
104
10
ug/L
100.0
4.97
99
75-125
Lead
104
1.0
ug/L
100.0
BRL
104
75-125
Nickel
100
3.0
ug/L
100.0
1.24
99
75-125
Selenium
103
5.0
ug/L
100.0
BRL
103
75-125
Silver
104
1.0
ug/L
100.0
BRL
104
75-125
Thallium
103
2.0
ug/L
100.0
BRL
103
75-125
Vanadium
105
5.0
ug/L
100.0
BRL
105
75-125
Zinc
105
20
ug/L
100.0
BRL
105
75-125
Matrix Spike Dup (P000369-MSD1)
Source: 0030253-01
Prepared
& Analyzed: 03/19/20
Antimony
111
3.0
ug/L
100.0
BRL
111
75-125
0.2
20
Arsenic
102
1.0
ug/L
100.0
0.368
102
75-125
0.3
20
Barium
232
10
ug/L
100.0
130
102
75-125
1
20
Beryllium
108
1.0
ug/L
100.0
BRL
108
75-125
2
20
Cadmium
106
1.0
ug/L
100.0
BRL
106
75-125
0.5
20
Chromium
103
3.0
ug/L
100.0
1.75
101
75-125
1
20
Cobalt
102
2.0
ug/L
100.0
1.76
100
75-125
0.7
20
Copper
104
10
ug/L
100.0
4.97
99
75-125
0.3
20
Lead
105
1.0
ug/L
100.0
BRL
105
75-125
0.1
20
Nickel
100
3.0
ug/L
100.0
1.24
99
75-125
0.06
20
Selenium
108
5.0
ug/L
100.0
BRL
108
75-125
5
20
Silver
104
1.0
ug/L
100.0
BRL
104
75-125
0.8
20
Thallium
102
2.0
ug/L
100.0
BRL
102
75-125
0.4
20
Vanadium
104
5.0
ug/L
100.0
BRL
104
75-125
1
20
Zinc
105
20
ug/L
100.0
BRL
105
75-125
0.7
20
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

1 0
Waypoint
ANALYTICAL
Anchor QEA of North Carolina, PLLC
Attn: Alec Macbeth
231 Haywood Street
Asheville, NC 28801
Total Metals - Quality Control
Analyte
Project: Jackson Cty Landfill 2020 Spring
Project No: 50-02
Level II QC Report
3/27/20
Work Order: 0030253
Time Submitted: 3/18/2020 8:55:OOAM
Reporting Spike Source %REC RPD
Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P000369 - 3005A
Post Spike (P000369-PS1)
Source: 0030253-01
Prepared
& Analyzed:
03/19/20
Antimony
108
ug/L
100.0
0.187
107
80-120
Arsenic
101
ug/L
100.0
0.368
101
80-120
Barium
231
ug/L
100.0
130
101
80-120
Beryllium
109
ug/L
100.0
0.00400
109
80-120
Cadmium
106
ug/L
100.0
0.0720
106
80-120
Chromium
104
ug/L
100.0
1.75
102
80-120
Cobalt
102
ug/L
100.0
1.76
100
80-120
Copper
103
ug/L
100.0
4.97
98
80-120
Lead
104
ug/L
100.0
0.167
104
80-120
Nickel
98.8
ug/L
100.0
1.24
98
80-120
Selenium
104
ug/L
100.0
-0.191
104
80-120
Silver
104
ug/L
100.0
0.00800
104
80-120
Thallium
102
ug/L
100.0
0.181
102
80-120
Vanadium
105
ug/L
100.0
0.418
104
80-120
Zinc
106
ug/L
100.0
4.44
101
80-120
Batch P000417 - 7470A
Blank (P000417-BLK1)
Prepared &Analyzed: 03/20/20
Mercury
LCS (P000417-BSI)
BRL 0.20 ug/L
Prepared &Analyzed: 03/20/20
Mercury
Batch P000418 - 7470A
9.47 0.20 ug/L 9.375 101 80-120
Blank (P000418-BLK1)
Prepared & Analyzed: 03/20/20
Mercury
BRL 0.20 ug/L
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

1 0
Waypoint
ANALYTICAL
Anchor QEA of North Carolina, PLLC
Attn: Alec Macbeth
231 Haywood Street
Asheville, NC 28801
Total Metals - Quality Control
Analyte
Project: Jackson Cty Landfill 2020 Spring
Project No: 50-02
Level II QC Report
3/27/20
Work Order: 0030253
Time Submitted: 3/18/2020 8:55:OOAM
Reporting Spike Source %REC RPD
Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P000418 - 7470A
LCS (P000418-BSI) Prepared &Analyzed: 03/20/20
Mercury 9.59 0.20 ug/L 9.375 102 80-120
Matrix Spike (P000418-MS1) Source: 0030253-03 Prepared & Analyzed: 03/20/20
Mercury 2.82 0.20 ug/L 9.375 BRL 30 80-120 M
Matrix Spike Dup (P000418-MSD1) Source: 0030253-03 Prepared & Analyzed: 03/20/20
Mercury 2.73 0.20 ug/L 9.375 BRL 29 80-120 3 20 M
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

1 0
Waypoint
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Spring
Attn: Alec Macbeth
231 Haywood Street Project No: 50-02
Asheville, NC 28801
Anions by Ion Chromatography - Quality Control
Level II QC Report
3/27/20
Work Order: 0030253
Time Submitted: 3/18/2020 8:55:OOAM
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P000366 - NO PREP
Blank (P000366-BLK1)
Prepared & Analyzed: 03/18/20
Chloride
BRL
1000
ug/L
Nitrate as N
BRL
200
ug/L
Sulfate
BRL
2000
ug/L
LCS (P000366-BSI)
Prepared &Analyzed: 03/18/20
Chloride
41100
1000
ug/L
40000 103
80-120
Nitrate as N
4100
210
ug/L
4000 102
80-120
Sulfate
40800
2100
ug/L
40000 102
80-120
Matrix Spike (P000366-MSI)
Source: 0030253-02
Prepared & Analyzed: 03/18/20
Chloride
69800
1000
ug/L
40000 30200 99
80-120
Nitrate as N
12300
210
ug/L
4000 8350 99
80-120
Sulfate
144000
2100
ug/L
40000 106000 95
80-120
Matrix Spike Dup (P000366-MSD1)
Source: 0030253-02
Prepared & Analyzed: 03/18/20
Chloride
71000
1000
ug/L
40000 30200 102
80-120 2 15
Nitrate as N
12500
210
ug/L
4000 8350 103
80-120 1 15
Sulfate
146000
2100
ug/L
40000 106000 99
80-120 1 15
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Level II QC Report
0int 3/27/2°
Waypo
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Spring Work Order: 0030253
Attn: Alec Macbeth Time Submitted: 3/18/2020 8:55:OOAM
231 Haywood Street Project No: 50-02
Asheville, NC 28801
General Chemistry Parameters - Quality Control
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P000340 - NO PREP
Blank (P000340-BLK1)
Prepared & Analyzed: 03/18/20
Ferrous Iron
BRL 200 ug/L
LCS (P000340-BS1)
Prepared &Analyzed: 03/18/20
Ferrous Iron
1850 200 ug/L
2000 92 90-110
Matrix Spike (P000340-MS1)
Source: 0030253-03
Prepared & Analyzed: 03/18/20
Ferrous Iron
1990 200 ug/L
2000 BRL 99 80-120
Matrix Spike Dup (P000340-MSD1)
Source: 0030253-03
Prepared & Analyzed: 03/18/20
Ferrous Iron
1950 200 ug/L
2000 BRL 98 80-120 2 20
Batch P000351 - NO PREP
Blank (P000351-BLK1)
Prepared &Analyzed: 03/18/20
Hardness
BRL 5000 ug/L
LCS (P000351-BSI)
Prepared &Analyzed: 03/18/20
Hardness
50000 5000 ug/L
50000 100 90-110
Matrix Spike (P000351-MSI)
Source: 0030253-05
Prepared & Analyzed: 03/18/20
Hardness
20500 5000 ug/L
10000 10000 105 80-120
Matrix Spike Dup (P000351-MSD1)
Source: 0030253-05
Prepared & Analyzed: 03/18/20
Hardness
20000 5000 ug/L
10000 10000 100 80-120 2 20
Batch P000359 - NO PREP
Blank (P000359-BLK1) Prepared & Analyzed: 03/18/20
Biochemical Oxygen Demand BRL 2000 ug/L BB
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

1 0
Waypoint
ANALYTICAL
Anchor QEA of North Carolina, PLLC
Attn: Alec Macbeth
231 Haywood Street
Asheville, NC 28801
General Chemistry Parameters - Quality Control
Analyte
Project: Jackson Cty Landfill 2020 Spring
Project No: 50-02
Level II QC Report
3/27/20
Work Order: 0030253
Time Submitted: 3/18/2020 8:55:OOAM
Reporting Spike Source %REC RPD
Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P000359 - NO PREP
LCS (P000359-BSI)
Prepared &Analyzed: 03/18/20
Biochemical Oxygen Demand
180000
2000
ug/L
198000 92 84.6-115.4 BB
Batch P000387 - NO PREP
Blank (P000387-BLK1)
Prepared: 03/19/20 Analyzed: 03/20/20
Total Alkalinity to pH 4.5
BRL
5000
ug/L
LCS (P000387-BS1)
Prepared: 03/19/20 Analyzed: 03/20/20
Total Alkalinity to pH 4.5
249000
5000
ug/L
250000 100 90-110
Batch P000397 - NO PREP
Blank (P000397-BLK1)
Prepared & Analyzed: 03/19/20
Chemical Oxygen Demand
BRL
50000
ug/L
LCS (P000397-BSI)
Prepared &Analyzed: 03/19/20
Chemical Oxygen Demand
517000
50000
ug/L
500000 103 90-110
Batch P000429 - SM4500-S C
Blank (P000429-BLK1) Prepared &Analyzed: 03/20/20
Sulfide BRL 2000 ug/L
LCS (P000429-BS1) Prepared &Analyzed: 03/20/20
Sulfide 7100 2000 ug/L 10000 71 70-130
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Sample Extraction Data
Prep Method: SM4500-S C
Lab Number
Batch
Initial
Final
Date/Time
0030253-01
P000429
200
mL
200 mL
03/20/20 10:55
0030253-02
P000429
200
mL
200 mL
03/20/20 10:55
0030253-03
P000429
200
mL
200 mL
03/20/20 10:55
Prep Method: 3005A
Lab Number
Batch
Initial
Final
Date/Time
0030253-01
P000369
50
mL
50 mL
03/19/20 8:17
0030253-02
P000369
50
mL
50 mL
03/19/20 8:17
0030253-03
P000369
50
mL
50 mL
03/19/20 8:17
0030253-04
P000369
50
mL
50 mL
03/19/20 8:17
0030253-05
P0O0369
50
mL
50 mL
03/19/20 8:17
Prep Method: 7470A
Lab Number
Batch
Initial
Final
Date/Time
0030253-01
P000417
20
mL
30 mL
03/20/20 10:24
0030253-02
P000417
20
mL
30 mL
03/20/20 10:24
0030253-03
P000418
20
mL
30 mL
03/20/20 10:24
0030253-04
P0O0418
20
mL
30 mL
03/20/20 10:24
0030253-05
P0O0418
20
mL
30 mL
03/20/20 10:24
Prep Method: 5030E
Lab Number
Batch
Initial
Final
Date/Time
0030253-04
P000398
10
mL
10 mL
03/19/20 10:00
0030253-05
P000398
10
mL
10 mL
03/19/20 10:00
0030253-06
P0O0398
10
mL
10 mL
03/19/20 10:00
Prep Method: SM6200 B
Lab Number
Batch
Initial
Final
Date/Time
0030253-01
P000392
10
mL
10 mL
03/19/20 10:00
0030253-02
P000392
10
mL
10 mL
03/19/20 10:00
0030253-03
P000392
10
mL
10 mL
03/19/20 10:00
Prep Method: 5030E
Lab Number
Batch
Initial
Final
Date/Time
0030253-01
P000356
5
mL
5 mL
03/18/20 13:46
0030253-02
P000356
5
mL
5 mL
03/18/20 13:46
0030253-03
P000356
5
mL
5 mL
03/18/20 13:46
0030253-04
P000356
5
mL
5 mL
03/18/20 13:46
0030253-05
P0O0356
5
mL
5 mL
03/18/20 13:46
Subcontracted Analyses
The following analyses
were subcontracted
to Pace Analytical Gulf Coast
Lab Number
Analysis
0030253-01
TOC (Sub)
0030253-02
TOC (Sub)
0030253-03
TOC (Sub)
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

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ACCESS
ANALYTICAL, INC.
ANALYTICAL REPORT
CLIENT
Waypoint Analytical
PO BOX 240543
Charlotte, NC 28224
ATTENTION
Angela Overcash
PROJECTID
0030253
LABORATORY REPORT NUMBER
220031922
DATE
03/20/2020
Primary Data Review By
f
Authorized Signature
PLEASE NOTE.
Secondary Data Review By
Ashl y B. Amick
Project Manager, Access Analytical, Inc.
[e-mail]
- Unless otherwise noted, all analysis on this report performed at Pace Analytical Gulf Coast, 7979
Innovation Park Dr., Baton Rouge, LA 70820.
- Pace Gulf Coast is SCDHEC certified laboratory # 73006, NCDENR certified lab # 618, GA certified lab #
LA-01955, NELAP certified laboratory # 01955
- Local support services for this project are provided by Access Analytical, Inc.. Access Analytical is a
representative of Pace Guld Coast serving clients in the SC/NC/GA areas. All questions regarding this report
should be directed to your local Access Analytical representative at 803.781.4243 or toll free at 888.315.4243.
Lab Report#: 220031922 Page 1 of 11

aceAnalytical
LELAP CERTIFICATE NUMBER: 01955
DOD -FLAP ACCREDITATION NUMBER: 74960
ANALYTICAL RESULTS
Deliver To
Angela Overcash
Waypoint Analytical
PO BOX 240543
Charlotte, NC 28224
706-529-6364
Q
PJLA
TcstIng
r>00 1A Ar
PERFORMED BY
Pace Analytical Gulf Coast
7979 Innovation Park Dr.
Baton Rouge, LA 70820
[phone]
Report Date 03/20/2020
Report # 220031922
I1111�1
Illnllll11�11l
Project 0030253
Additional Recipients
NONE
*: ISO7
`0 17025�#f
Lab Report#: 220031922 Page 2 of 11

�PaceArralyfrcar
Report#: 220031922
Project ID: 0030253
Report Date: 03/20/2020
Laboratory Endorsement
Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized
agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this
retention period the samples will be disposed in accordance with Pace Gulf Coast's Standard Operating Procedures.
Common Abbreviations that may be Utilized in this Report
ND Indicates the result was Not Detected at the specified reporting limit
NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030
DO Indicates the result was Diluted Out
MI Indicates the result was subject to Matrix Interference
TNTC Indicates the result was Too Numerous To Count
SUBC Indicates the analysis was Sub -Contracted
FLD Indicates the analysis was performed in the Field
DL Detection Limit
LOD Limit of Detection
LOQ Limit of Quantitation
RE Re -analysis
CIF HPLC or GC Confirmation
00:01 Reported as a time equivalent to 12:00 AM
Reporting Flags that may be Utilized in this Report
J or I Indicates the result is between the MDL and LOQ
J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria
U Indicates the compound was analyzed for but not detected
B or V Indicates the analyte was detected in the associated Method Blank
Q Indicates a non -compliant QC Result (See Q Flag Application Report)
Indicates a non -compliant or not applicable QC recovery or RPD — see narrative
E Organics - The result is estimated because it exceeded the instrument calibration range
E Metals - % diference for the serial dilution is > 10%
L Reporting Limits adjusted to meet risk -based limit.
P RPD between primary and confirmation result is greater than 40
DL Diluted analysis — when appended to Client Sample ID
Sample receipt at Pace Gulf Coast is documented through the attached chain of custody. In accordance with NELAC, this report shall be
reproduced only in full and with the written permission of Pace Gulf Coast. The results contained within this report relate only to the samples
reported. The documented results are presented within this report.
This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results
contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited.
I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and
Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this
hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee,
as verified by the following signature.
Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if
applicable.
Authorized Signature
Pace Gulf Coast Report 220031922
Lab Report#: 220031922 Page 3 of 11

Report#: 220031922
ace�lfh71}+hCr91
Project ID: 0030253 Report Date: 03/20/2020
Certifications
Certification
Certification Number
DOD ELAP
74960
Alabama
01955
Arkansas
88-0655
Colorado
01955
Delaware
01955
Florida
E87854
Georgia
01955
Hawaii
01955
Idaho
01955
Illinois
200048
Indiana
01955
Kansas
E-10354
Kentucky
95
Louisiana
01955
Maryland
01955
Massachusetts
01955
Michigan
01955
Mississippi
01955
Missouri
01955
Montana
N/A
Nebraska
01955
New Mexico
01955
North Carolina
618
North Dakota
R-195
Oklahoma
9403
South Carolina
73006001
South Dakota
01955
Tennessee
01955
Texas
T104704178
Vermont
01955
Virginia
460215
Washington
C929
USDA Soil Permit
P330-16-00234
Lab Report#: 220031922 Page 4 of 11

Report#: 220031922
CE���lCr7i
Project ID: 0030253 Report Date: 03/20/2020
Case Narrative
Client: Access Analytical Report: 220031922
Pace Analytical Gulf Coast received and analyzed the sample(s) listed
on the Report Sample Summary page of this report. Receipt of the sample(s) is documented
by the attached chain of custody. This applies only to the sample(s) listed in this report.
No sample integrity or quality control exceptions were identified unless noted below.
No anomalies were found for the analyzed sample(s).
Lab Report#: 220031922 Page 5 of 11

,�eArla�ic��l
I
LAB ID
Client ID
Report#: 220031922
Project ID: 0030253
Sample Summary
Matrix Collect Date(Time
22003192201 MW-03-20200317 Water 03/17/202013:46
22003192202 MW-04-20200317 Water 03/17/2020 09:59
22003192203 MW-07-20200317 Water 03/17/202011:39
Report Date: 03/20/2020
Receive Date/Time
03/19/2020 09:35
03/19/2020 09:35
03/19/2020 09:35
Lab Report#: 220031922 Page 6 of 11

..�aeeElr�aly�tira/
MW-03-20200317
Report#: 220031922
Project ID: 0030253 Report Date: 03/20/2020
Summary of Compounds Detected
Collect Date 03/17/2020 13:46 LAB ID 22nn31922n1
Receive Date 03/19/2020 09:35 Matrix Water
SM 5310 B-2011
CAS# Parameter Result DL LOQ Units
C-012 Total Organic Carbon 6.16 0.300 2.00 mg/L
VIW-04-20200317 Collect Date 03/17/2020 09:59 LAB ID 22003192202
Receive Date 03/19/2020 09:35 Matrix Water
SM 5310 B-2011
CAS# Parameter
C-012 Total Organic Carbon
Collect Date 03/17/2020 11:39
Fmw-o
7-20200317
Receive Date 03/19/2020 09:35
Result DL LOQ Units
5.85 0.300 2.00 mg/L
LAB ID 22003192203
Matrix Water
SM 5310 B-2011
CAS# Parameter Result DL LOQ Units
C-012 Total Organic Carbon 7.11 0.600 4.00 mg/L
Lab Report#: 220031922 Page 7 of 11

Report#: 220031922
.. ace.4rialyricar
Project ID: 0030253 Report Date: 03/20/2020
Sample Results
MW-03-20200317 Collect Date 03/17/2020 13:46 LAB ID 22003192201
Receive Date 03/19/2020 09:35 Matrix Water
SM 5310 B-2011
Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch
NA NA NA 1 03/19/2020 23:25 PLH 680065
CAS#
Parameter
Result
DL
LOQ
Units
C-012
Total Organic Carbon
6.16
0.300
2.00
mg/L
W-04-20200317 Collect Date 03/17/2020 09:59 LAB ID 22003192202
Receive Date 03/19/2020 09:35 Matrix Water
SM 5310 B-2011
Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch
NA NA NA 1 03/19/2020 23:41 PLH 680065
CAS# Parameter
C-012 Total Organic Carbon
Collect Date 03/17/2020 11:39
MW-07-20200317
Receive Date 03/19/2020 09:35
SM 5310 B-2011
Result DL LOQ Units
5.85 0.300 2.00 mg/L
LAB ID 22003192203
Matrix Water
Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch
NA NA NA 2 03/20/202011:47 PLH 680065
CAS# Parameter
C-012 Total Organic Carbon
Result DL LOQ Units
7.11 0.600 4.00 mg/L
Lab Report#: 220031922 Page 8 of 11

Report#: 220031922
Project ID: 0030253 Report Date: 03/20/2020
General Chemistry QC Summary
Analytical Batch Client ID
MB680065
LCS680065
LCSD680065
680065 LAB ID
2023204
2023205
2023546
Sample Type
MB
LCS
LCSD
Prep Date
NA
NA
NA
Analysis Date
03/19/2020 22:30
03/19/2020 21:38
03/20/2020 12:26
Matrix
Water
Water
Water
SM 5310 B-2011
Units
mg/L
Spike
Result
I %R
Control
Spike
Result
%R RPD
RPD
Result
DL
Added
Limits%R
Added
I
Limit
Total Organic Carbon C-012
0.3000
0.300
50.0
50.1
100
90 - 110
50.0
49.6
99 1
20
Lab Report#: 220031922 Page 9 of 11

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Lab _:220031922 Page 10, 11

f eeAnalydcal'
SAMPLE RECEIVING CHECKLIST
IBINIININII IIII�I
R 2 2 0 0 3
IIIINII I II
1 v 2 2
SAMPLE DELIVERY GROUP 220031922
CHECKLIST
YES
NO
Client PM CLH
Transport Method
Samples received with proper thermal preservation?
V❑
❑
4565 - Access Analytical
FEDB(
Radioactiuty is <1600 cpm? If no, record cpm value in notes section.
v❑
[]
Profile Number
Received W
COC relinquished and complete (including samplelDs, collect times, and sampler)?
0
❑
80251
Savage, Tiffany R
All containers received in good condition and within hold time?
❑v
❑
Line Item(s)
%ceive Date(s)
Al sample labels and containers received match the chain of custody?
v❑
❑
1 - Water
03J19/20
Preserbative added to any containers?
❑
If received, was headspace for VOC water containers < 6mm?
R
❑
Samples collected in containers provided by Pace Gulf Coast?
❑
❑d
COOLERS
DISCREPANCIES
LAB PRESERVATIONS
Airbill Thermometer IQ E34
Temp °C
N ne
Nx1e
T700-5452-4614
4 3
NOTES
Revision 1.6
Lab Report#: 220031922
Page 1 of 1
Page 11 of 11

Way poi nt
ANALYTICAL
Anchor QEA of North Carolina, PLLC
Alec Macbeth
231 Haywood Street
Asheville, NC 28801
NC Certification No. 402
NC Drinking Water Cert No. 37735
SC Certification No. 99012
Project: Jackson Cty Landfill 2020 Spring
Project No.: 50-02
Lab Submittal Date: 03/19/2020
Work Order: 0030270
Case Narrative
3/27/20 12:18
This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample
Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed
according to the referenced methods.
Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case
narrative.
Narrative Notes:
TOC analysis was subcontracted to Pace/GCAL. Laboratory report is attached.
Waypoint Summary of Detections does not include subcontracted data.
Please call if you have any questions relating to this analytical report.
Respectfully,
WAYPOINT ANALYTICAL
a,-1
Angela D. Overcash
Senior Project Manager
Data Qualifiers Key Reference:
HT Sample received and analyzed outside of the hold time.
J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag).
BRL Below Reporting Limit
MDL Method Detection Limit
RPD Relative Percent Difference
* Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and
reporting limit indicated with a J.
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

0Sample
Receipt Summary
Waypoi nt..
03/27/2020
ANALYTICAL
Work Order: 0030270
Client Sample ID
Lab Sample ID
Matrix
Date/Time Sampled
Date/Time Received
MW-01-20200318
0030270-01
Water
03/18/20 11:39
03/19/20 9:05
MW-02-20200318
0030270-02
Water
03/18/20 8:55
03/19/20 9:05
MW-05R-20200318
0030270-03
Water
03/18/20 12:45
03/19/20 9:05
MW-06-20200318
0030270-04
Water
03/18/20 10:13
03/19/20 9:05
LT-01-20200318
0030270-05
Water
03/18/20 12:02
03/19/20 9:05
TB-20200318
0030270-06
Water
03/18/20 0:00
03/19/20 9:05
Samples were received in good condition at 1.5 degrees C unless otherwise noted.
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Way po i nt .
ANALYTICAL
Summary of Detections
03/27/202C
Work Order: 0030270
Prism ID
Client ID
Parameter
Method
Result
Units
0030270-01
MW-01-20200318
Chloride
9056A
1100
ug/L
0030270-01
MW-01-20200318
Biochemical Oxygen Demand
SM5210 B
10000
ug/L
0030270-01
MW-01-20200318
Chemical Oxygen Demand
SM5220 D
38000
J
ug/L
0030270-01
MW-01-20200318
Ferrous Iron
SM3500-Fe B
35000
HT
ug/L
0030270-01
MW-01-20200318
Total Alkalinity to pH 4.5
SM2320 B
120000
ug/L
0030270-01
MW-01-20200318
Barium
6020B
120
ug/L
0030270-01
MW-01-20200318
Cobalt
6020B
130
ug/L
0030270-01
MW-01-20200318
Nickel
6020B
15
ug/L
0030270-01
MW-01-20200318
1,1-Dichloroethane
8260D
2.7
ug/L
0030270-01
MW-01-20200318
1,4-Dichlorobenzene
8260D
10
ug/L
0030270-01
MW-01-20200318
Acetone
8260D
7.3
ug/L
0030270-01
MW-01-20200318
Benzene
8260D
1.4
ug/L
0030270-01
MW-01-20200318
Chlorobenzene
8260D
1.8
ug/L
0030270-01
MW-01-20200318
cis-1,2-Dichloroethylene
8260D
5.1
ug/L
0030270-01
MW-01-20200318
m,p-Xylenes
8260D
0.87
J
ug/L
0030270-01
MW-01-20200318
Methyl Butyl Ketone (2-Hexanone)
8260D
16
ug/L
0030270-01
MW-01-20200318
Tetrachloroethylene
8260D
0.48
J
ug/L
0030270-01
MW-01-20200318
Trichloroethylene
8260D
0.61
ug/L
0030270-01
MW-01-20200318
Xylenes, total
8260D
1.1
J
ug/L
0030270-02
MW-02-20200318
Chloride
9056A
29000
ug/L
0030270-02
MW-02-20200318
Nitrate as N
9056A
530
ug/L
0030270-02
MW-02-20200318
Sulfate
9056A
15000
ug/L
0030270-02
MW-02-20200318
Biochemical Oxygen Demand
SM5210 B
2500
ug/L
0030270-02
MW-02-20200318
Chemical Oxygen Demand
SM5220 D
22000
J
ug/L
0030270-02
MW-02-20200318
Ferrous Iron
SM3500-Fe B
59
HT, ,1
ug/L
0030270-02
MW-02-20200318
Total Alkalinity to pH 4.5
SM2320 B
44000
ug/L
0030270-02
MW-02-20200318
Arsenic
6020B
1.5
ug/L
0030270-02
MW-02-20200318
Barium
6020B
75
ug/L
0030270-02
MW-02-20200318
Chromium
6020B
9.7
ug/L
0030270-02
MW-02-20200318
Cobalt
6020B
14
ug/L
0030270-02
MW-02-20200318
Copper
6020B
9.1
J
ug/L
0030270-02
MW-02-20200318
Lead
6020B
2.8
ug/L
0030270-02
MW-02-20200318
Nickel
6020B
6.4
ug/L
0030270-02
MW-02-20200318
Selenium
6020B
6.0
ug/L
0030270-02
MW-02-20200318
Vanadium
6020B
13
ug/L
0030270-02
MW-02-20200318
Zinc
6020B
29
ug/L
0030270-02
MW-02-20200318
1,1-Dichloroethane
8260D
0.30
J
ug/L
0030270-02
MW-02-20200318
1,4-Dioxane
8260D SIM
3.6
ug/L
0030270-03
MW-05R-20200318
Chloride
9056A
53000
ug/L
0030270-03
MW-05R-20200318
Nitrate as N
9056A
59
J
ug/L
0030270-03
MW-05R-20200318
Biochemical Oxygen Demand
SM5210 B
6500
ug/L
0030270-03
MW-05R-20200318
Chemical Oxygen Demand
SM5220 D
85000
ug/L
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Way po l nt .
ANALYTICAL
Summary of Detections
03/27/202C
Work Order: 0030270
Prism ID
Client ID
Parameter
Method
Result
Units
0030270-03
MW-05R-20200318
Ferrous Iron
SM3500-Fe B
1500
HT
ug/L
0030270-03
MW-05R-20200318
Total Alkalinity to pH 4.5
SM2320 B
250000
ug/L
0030270-03
MW-05R-20200318
Arsenic
6020B
0.51
J
ug/L
0030270-03
MW-05R-20200318
Barium
6020B
110
ug/L
0030270-03
MW-05R-20200318
Cadmium
6020B
0.33
J
ug/L
0030270-03
MW-05R-20200318
Chromium
6020B
3.1
ug/L
0030270-03
MW-05R-20200318
Cobalt
6020B
8.2
ug/L
0030270-03
MW-05R-20200318
Copper
6020B
5.1
J
ug/L
0030270-03
MW-05R-20200318
Lead
6020B
1.1
ug/L
0030270-03
MW-05R-20200318
Nickel
6020B
4.4
ug/L
0030270-03
MW-05R-20200318
Selenium
6020B
1.5
J
ug/L
0030270-03
MW-05R-20200318
Vanadium
6020B
3.1
J
ug/L
0030270-03
MW-05R-20200318
Zinc
6020B
17
J
ug/L
0030270-03
MW-05R-20200318
1,4-Dichlorobenzene
8260D
6.6
ug/L
0030270-03
MW-05R-20200318
Acetone
8260D
2.7
J
ug/L
0030270-03
MW-05R-20200318
Benzene
8260D
2.1
ug/L
0030270-03
MW-05R-20200318
Chlorobenzene
8260D
8.1
ug/L
0030270-03
MW-05R-20200318
cis-1,2-Dichloroethylene
8260D
1.8
ug/L
0030270-03
MW-05R-20200318
Vinyl chloride
8260D
2.5
ug/L
0030270-03
MW-05R-20200318
1,4-Dioxane
8260D SIM
4.9
ug/L
0030270-04
MW-06-20200318
Chloride
9056A
1000
ug/L
0030270-04
MW-06-20200318
Nitrate as N
9056A
150
J
ug/L
0030270-04
MW-06-20200318
Sulfate
9056A
560
J
ug/L
0030270-04
MW-06-20200318
Biochemical Oxygen Demand
SM5210 B
540
J
ug/L
0030270-04
MW-06-20200318
Total Alkalinity to pH 4.5
SM2320 B
24000
ug/L
0030270-04
MW-06-20200318
Barium
6020B
47
ug/L
0030270-04
MW-06-20200318
Cobalt
6020B
6.9
ug/L
0030270-04
MW-06-20200318
Lead
6020B
1.2
ug/L
0030270-04
MW-06-20200318
Nickel
6020B
4.1
ug/L
0030270-04
MW-06-20200318
Selenium
6020B
1.0
J
ug/L
0030270-04
MW-06-20200318
Zinc
6020B
14
J
ug/L
0030270-04
MW-06-20200318
1,1-Dichloroethane
8260D
1.2
ug/L
0030270-04
MW-06-20200318
cis-1,2-Dichloroethylene
8260D
1.0
ug/L
0030270-05
LT-01-20200318
1,4-Dichlorobenzene
8260D
5.6
ug/L
0030270-05
LT-01-20200318
Acetone
8260D
6.4
ug/L
0030270-05
LT-01-20200318
Benzene
8260D
1.3
ug/L
0030270-05
LT-01-20200318
Chlorobenzene
8260D
3.2
ug/L
0030270-05
LT-01-20200318
Ethylbenzene
8260D
2.7
ug/L
0030270-05
LT-01-20200318
m,p-Xylenes
8260D
0.89
J
ug/L
0030270-05
LT-01-20200318
Methyl Isobutyl Ketone
8260D
0.79
J
ug/L
0030270-05
LT-01-20200318
o-Xylene
8260D
1.2
ug/L
0030270-05
LT-01-20200318
Toluene
8260D
0.70
ug/L
0030270-05
LT-01-20200318
Xylenes, total
8260D
2.0
ug/L
0030270-05
LT-01-20200318
1,4-Dioxane
8260D SIM
60
ug/L
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

0
Way po� nt..
ANALYTICAL
Anchor QEA of North Carolina, PLLC
Attn: Alec Macbeth
231 Haywood Street
Asheville, NC 28801
Project: Jackson Cty Landfill 2020
Spring
Project No.: 50-02
Sample Matrix: Water
Laboratory Report
03/27/2020
Client Sample ID: MW-01-20200318
Sample ID: 0030270-01
Work Order: 0030270
Time Collected: 03/18/20 11:39
Time Submitted: 03/19/20 09:05
Parameter
Result
Units
SWSL
Report
Limit
MDL
Dilution
Factor
Method
Analysis Analyst
Date/Time
Batch
ID
Anions by Ion Chromatography
Chloride
1100
ug/L
NE
1000
380
1
9056A
3/19/20 14:55 BMS
P000403
Nitrate as N
<54
ug/L
10000
200
54
1
9056A
3/19/20 14:55 BMS
P000403
Sulfate
<480
ug/L
250000
2000
480
1
9056A
3/19/20 14:55 BMS
P000403
General Chemistry Parameters
Biochemical Oxygen Demand
10000
ug/L
NE
2000
210
1
SM5210 B
3/19/20 15:13 SLS
P000401
Chemical Oxygen Demand
38000 J
ug/L
NE
50000
10000
1
SM5220 D
3/23/20 11:06 SLS
P000457
Ferrous Iron
35000 HT
ug/L
NE
5000
1300
1
SM3500-Fe B
3/19/20 12:52 BMS
P000391
Sulfide
<830
ug/L
1000
2000
830
1
SM4500-S F
3/20/20 10:55 CBM
P000429
Total Alkalinity to pH 4.5
120000
ug/L
NE
5000
770
1
SM2320 B
3/20/20 10:00 CLB
P000387
Total Metals
Mercury
<0.034
ug/L
0.2
0.20
0.034
1
7470A
3/20/20 17:33 JAB
P000418
Antimony
<0.93
ug/L
6
3.0
0.93
1
6020B
3/23/20 15:47 MMR
P000414
Arsenic
<0.34
ug/L
10
1.0
0.34
1
6020B
3/23/20 15:47 MMR
P000414
Barium
120
ug/L
100
10
3.2
1
6020B
3/23/20 15:47 MMR
P000414
Beryllium
<0.30
ug/L
1
1.0
0.30
1
6020B
3/23/20 15:47 MMR
P000414
Cadmium
<0.22
ug/L
1
1.0
0.22
1
6020B
3/23/20 15:47 MMR
P000414
Chromium
<0.90
ug/L
10
3.0
0.90
1
6020B
3/23/20 15:47 MMR
P000414
Cobalt
130
ug/L
10
2.0
0.70
1
6020B
3/23/20 15:47 MMR
P000414
Copper
<4.7
ug/L
10
10
4.7
1
6020B
3/23/20 15:47 MMR
P000414
Lead
<0.44
ug/L
10
1.0
0.44
1
6020B
3/23/20 15:47 MMR
P000414
Nickel
15
ug/L
50
3.0
0.83
1
6020B
3/23/20 15:47 MMR
P000414
Selenium
<0.98
ug/L
10
5.0
0.98
1
6020B
3/23/20 15:47 MMR
P000414
Silver
<0.34
ug/L
10
1.0
0.34
1
6020B
3/23/20 15:47 MMR
P000414
Thallium
<0.84
ug/L
5.5
2.0
0.84
1
6020B
3/23/20 15:47 MMR
P000414
Vanadium
<1.5
ug/L
25
5.0
1.5
1
6020B
3/23/20 15:47 MMR
P000414
Zinc
<10
ug/L
10
20
10
1
6020B
3/23/20 15:47 MMR
P000414
Volatile Organic Compounds by GC/MS
1, 1, 1,2-Tetrachloroethane
<0.35
ug/L
5
0.50
0.35
1
8260D
3/23/20 20:29 JLB
P000456
1, 1, 1 -Trichloroethane
<0.31
ug/L
1
0.50
0.31
1
8260D
3/23/20 20:29 JLB
P000456
1,1,2,2-Tetrachloroethane
<0.34
ug/L
3
0.50
0.34
1
8260D
3/23/20 20:29 JLB
P000456
1,1,2-Trichloroethane
<0.42
ug/L
1
0.50
0.42
1
8260D
3/23/20 20:29 JLB
P000456
1,1-Dichloroethane
2.7
ug/L
5
0.50
0.29
1
8260D
3/23/20 20:29 JLB
P000456
1,1-Dichloroethylene
<0.35
ug/L
5
0.50
0.35
1
8260D
3/23/20 20:29 JLB
P000456
1,2,3-Trichloropropane
<0.34
ug/L
1
1.0
0.34
1
8260D
3/23/20 20:29 JLB
P000456
1,2-Dibromo-3-chloropropane
<0.59
ug/L
13
2.0
0.59
1
8260D
3/23/20 20:29 JLB
P000456
1,2-Dibromoethane
<0.37
ug/L
1
0.50
0.37
1
8260D
3/23/20 20:29 JLB
P000456
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
A i • .0 03/27/2020
- -ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: MW-01-20200318
Attn: Alec Macbeth Spring Sample ID: 0030270-01
231 Haywood Street Project No.: 50-02 Work Order: 0030270
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/18/20 11:39
Time Submitted: 03/19/20 09:05
Parameter
Result
Units
SWSL
Report
Limit
MDL
Dilution
Factor
Method
Analysis Analyst
Date/Time
Batch
ID
1,2-Dichlorobenzene
<0.28
ug/L
5
0.50
0.28
1
8260D
3/23/20 20:29 JLB
P000456
1,2-Dichloroethane
<0.41
ug/L
1
0.50
0.41
1
8260D
3/23/20 20:29 JLB
P000456
1,2-Dichloropropane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/23/20 20:29 JLB
P000456
1,4-Dichlorobenzene
10
ug/L
1
0.50
0.42
1
8260D
3/23/20 20:29 JLB
P000456
Acetone
7.3
ug/L
100
5.0
0.70
1
8260D
3/23/20 20:29 JLB
P000456
Acrylonitrile
<0.85
ug/L
200
20
0.85
1
8260D
3/23/20 20:29 JLB
P000456
Benzene
1.4
ug/L
1
0.50
0.34
1
8260D
3/23/20 20:29 JLB
P000456
Bromochloromethane
<0.53
ug/L
3
2.0
0.53
1
8260D
3/23/20 20:29 JLB
P000456
Bromodichloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/23/20 20:29 JLB
P000456
Bromoform
<0.26
ug/L
3
1.0
0.26
1
8260D
3/23/20 20:29 JLB
P000456
Bromomethane
<0.48
ug/L
10
1.0
0.48
1
8260D
3/23/20 20:29 JLB
P000456
Carbon disulfide
<0.36
ug/L
100
5.0
0.36
1
8260D
3/23/20 20:29 JLB
P000456
Carbon Tetrachloride
<0.55
ug/L
1
2.0
0.55
1
8260D
3/23/20 20:29 JLB
P000456
Chlorobenzene
1.8
ug/L
3
0.50
0.34
1
8260D
3/23/20 20:29 JLB
P000456
Chloroethane
<0.43
ug/L
10
0.50
0.43
1
8260D
3/23/20 20:29 JLB
P000456
Chloroform
<0.48
ug/L
5
0.50
0.48
1
8260D
3/23/20 20:29 JLB
P000456
Chloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/23/20 20:29 JLB
P000456
cis-1,2-Dichloroethylene
5.1
ug/L
5
0.50
0.40
1
8260D
3/23/20 20:29 JLB
P000456
cis- 1,3-Dichloropropylene
<0.36
ug/L
1
0.50
0.36
1
8260D
3/23/20 20:29 JLB
P000456
Dibromochloromethane
<0.42
ug/L
3
0.50
0.42
1
8260D
3/23/20 20:29 JLB
P000456
Dibromomethane
<0.54
ug/L
10
2.0
0.54
1
8260D
3/23/20 20:29 JLB
P000456
Ethylbenzene
<0.31
ug/L
1
0.50
0.31
1
8260D
3/23/20 20:29 JLB
P000456
m,p-Xylenes
0.87 J
ug/L
NE
1.0
0.73
1
8260D
3/23/20 20:29 JLB
P000456
Methyl Butyl Ketone (2-Hexanone)
16
ug/L
50
5.0
0.29
1
8260D
3/23/20 20:29 JLB
P000456
Methyl Ethyl Ketone (2-Butanone)
<0.78
ug/L
100
5.0
0.78
1
8260D
3/23/20 20:29 JLB
P000456
Methyl Iodide
<0.41
ug/L
10
5.0
0.41
1
8260D
3/23/20 20:29 JLB
P000456
Methyl Isobutyl Ketone
<0.40
ug/L
100
5.0
0.40
1
8260D
3/23/20 20:29 JLB
P000456
Methylene Chloride
<0.40
ug/L
1
1.0
0.40
1
8260D
3/23/20 20:29 JLB
P000456
o-Xylene
<0.40
ug/L
NE
0.50
0.40
1
8260D
3/23/20 20:29 JLB
P000456
Styrene
<0.26
ug/L
1
0.50
0.26
1
8260D
3/23/20 20:29 JLB
P000456
Tetrachloroethylene
0.48 J
ug/L
1
0.50
0.31
1
8260D
3/23/20 20:29 JLB
P000456
Toluene
<0.35
ug/L
1
0.50
0.35
1
8260D
3/23/20 20:29 JLB
P000456
trans- 1,2-Dichloroethylene
<0.27
ug/L
5
0.50
0.27
1
8260D
3/23/20 20:29 JLB
P000456
trans- 1,3-Dichloropropylene
<0.49
ug/L
1
0.50
0.49
1
8260D
3/23/20 20:29 JLB
P000456
trans- 1,4-Dichloro-2-butene
<0.22
ug/L
100
10
0.22
1
8260D
3/23/20 20:29 JLB
P000456
Trichloroethylene
0.61
ug/L
1
0.50
0.46
1
8260D
3/23/20 20:29 JLB
P000456
Trichlorofluoromethane
<0.24
ug/L
1
0.50
0.24
1
8260D
3/23/20 20:29 JLB
P000456
Vinyl acetate
<0.26
ug/L
50
2.0
0.26
1
8260D
3/23/20 20:29 JLB
P000456
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
• � 03/27/2020
PA Waynt.�
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: MW-01-20200318
Attn: Alec Macbeth Spring Sample ID: 0030270-01
231 Haywood Street Project No.: 50-02 Work Order: 0030270
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/18/20 11:39
Time Submitted: 03/19/20 09:05
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
Vinyl chloride
<0.41 ug/L 1 0.50 0.41 1 8260D 3/23/20 20:29 JLB P000456
1.1 J ug/L 5 1.5 1.1 1 8260D 3/23/20 20:29 JLB P000456
Surrogate Recovery Control Limits
4-Bromofluorobenzene 101 % 80-124
Dibromofluoromethane 103 % 75-129
Toluene-d8 99 % 77-123
Volatile Organic Compounds by GC/MS SIM
1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 3/19/20 16:42 TBL P000385
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

0
Way poi nt.
ANALYTICAL
Anchor QEA of North Carolina, PLLC
Attn: Alec Macbeth
231 Haywood Street
Asheville, NC 28801
Laboratory Report
03/27/2020
Project: Jackson Cty Landfill 2020 Client Sample ID: MW-02-20200318
Spring Sample ID: 0030270-02
Project No.: 50-02 Work Order: 0030270
Sample Matrix: Water Time Collected: 03/18/20 08:55
Time Submitted: 03/19/20 09:05
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
Anions by Ion Chromatography
Chloride 29000 ug/L NE 1000 380 1 9056A 3/19/20 15:10 BMS P000403
Nitrate as N 530 ug/L 10000 200 54 1 9056A 3/19/20 15:10 BMS P000403
Sulfate 15000 ug/L 250000 2000 480 1 9056A 3/19/20 15:10 BMS P000403
General Chemistry Parameters
Biochemical Oxygen Demand
Chemical Oxygen Demand
Ferrous Iron
Sulfide
Total Alkalinity to pH 4.5
Total Metals
2500
22000
59
<830
44000
J
HT,
J
ug/L
ug/L
ug/L
ug/L
ug/L
NE
NE
NE
1000
NE
2000
50000
200
2000
5000
210
10000
51
830
770
1
1
1
1
1
SM5210 B
SM5220 D
SM3500-Fe B
SM4500-S F
SM2320 B
3/19/20 15:13 SLS
3/23/20 11:06 SLS
3/19/20 12:52 BMS
3/20/20 10:55 CBM
3/25/20 11:40 CLB
P000401
P000457
P000391
P000429
P000503
Mercury
<0.034
ug/L
0.2
0.20
0.034
1
7470A
3/20/20 17:37 JAB
P000418
Antimony
<0.93
ug/L
6
3.0
0.93
1
6020B
3/23/20 16:07 MMR
P000414
Arsenic
1.5
ug/L
10
1.0
0.34
1
6020B
3/23/20 16:07 MMR
P000414
Barium
75
ug/L
100
10
3.2
1
6020B
3/23/20 16:07 MMR
P000414
Beryllium
<0.30
ug/L
1
1.0
0.30
1
6020B
3/23/20 16:07 MMR
P000414
Cadmium
<0.22
ug/L
1
1.0
0.22
1
6020B
3/23/20 16:07 MMR
P000414
Chromium
9.7
ug/L
10
3.0
0.90
1
6020B
3/23/20 16:07 MMR
P000414
Cobalt
14
ug/L
10
2.0
0.70
1
6020B
3/23/20 16:07 MMR
P000414
Copper
9.1
J
ug/L
10
10
4.7
1
6020B
3/23/20 16:07 MMR
P000414
Lead
2.8
ug/L
10
1.0
0.44
1
6020B
3/23/20 16:07 MMR
P000414
Nickel
6.4
ug/L
50
3.0
0.83
1
6020B
3/23/20 16:07 MMR
P000414
Selenium
6.0
ug/L
10
5.0
0.98
1
6020B
3/23/20 16:07 MMR
P000414
Silver
<0.34
ug/L
10
1.0
0.34
1
6020B
3/23/20 16:07 MMR
P000414
Thallium
<0.84
ug/L
5.5
2.0
0.84
1
6020B
3/23/20 16:07 MMR
P000414
Vanadium
13
ug/L
25
5.0
1.5
1
6020B
3/23/20 16:07 MMR
P000414
Zinc
29
ug/L
10
20
10
1
6020B
3/23/20 16:07 MMR
P000414
Volatile Organic Compounds by GUMS
1, 1, 1,2-Tetrachloroethane
<0.35
ug/L
5
0.50
0.35
1
8260D
3/23/20 20:54 JLB
P000456
1, 1, 1 -Trichloroethane
<0.31
ug/L
1
0.50
0.31
1
8260D
3/23/20 20:54 JLB
P000456
1,1,2,2-Tetrachloroethane
<0.34
ug/L
3
0.50
0.34
1
8260D
3/23/20 20:54 JLB
P000456
1,1,2-Trichloroethane
<0.42
ug/L
1
0.50
0.42
1
8260D
3/23/20 20:54 JLB
P000456
1,1-Dichloroethane
0.30
J
ug/L
5
0.50
0.29
1
8260D
3/23/20 20:54 JLB
P000456
1,1-Dichloroethylene
<0.35
ug/L
5
0.50
0.35
1
8260D
3/23/20 20:54 JLB
P000456
1,2,3-Trichloropropane
<0.34
ug/L
1
1.0
0.34
1
8260D
3/23/20 20:54 JLB
P000456
1,2-Dibromo-3-chloropropane
<0.59
ug/L
13
2.0
0.59
1
8260D
3/23/20 20:54 JLB
P000456
1,2-Dibromoethane
<0.37
ug/L
1
0.50
0.37
1
8260D
3/23/20 20:54 JLB
P000456
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
A i • .0 03/27/2020
- -ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: MW-02-20200318
Attn: Alec Macbeth Spring Sample ID: 0030270-02
231 Haywood Street Project No.: 50-02 Work Order: 0030270
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/18/20 08:55
Time Submitted: 03/19/20 09:05
Parameter
Result
Units
SWSL
Report
Limit
MDL
Dilution
Factor
Method
Analysis Analyst
Date/Time
Batch
ID
1,2-Dichlorobenzene
<0.28
ug/L
5
0.50
0.28
1
8260D
3/23/20 20:54 JLB
P000456
1,2-Dichloroethane
<0.41
ug/L
1
0.50
0.41
1
8260D
3/23/20 20:54 JLB
P000456
1,2-Dichloropropane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/23/20 20:54 JLB
P000456
1,4-Dichlorobenzene
<0.42
ug/L
1
0.50
0.42
1
8260D
3/23/20 20:54 JLB
P000456
Acetone
<0.70
ug/L
100
5.0
0.70
1
8260D
3/23/20 20:54 JLB
P000456
Acrylonitrile
<0.85
ug/L
200
20
0.85
1
8260D
3/23/20 20:54 JLB
P000456
Benzene
<0.34
ug/L
1
0.50
0.34
1
8260D
3/23/20 20:54 JLB
P000456
Bromochloromethane
<0.53
ug/L
3
2.0
0.53
1
8260D
3/23/20 20:54 JLB
P000456
Bromodichloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/23/20 20:54 JLB
P000456
Bromoform
<0.26
ug/L
3
1.0
0.26
1
8260D
3/23/20 20:54 JLB
P000456
Bromomethane
<0.48
ug/L
10
1.0
0.48
1
8260D
3/23/20 20:54 JLB
P000456
Carbon disulfide
<0.36
ug/L
100
5.0
0.36
1
8260D
3/23/20 20:54 JLB
P000456
Carbon Tetrachloride
<0.55
ug/L
1
2.0
0.55
1
8260D
3/23/20 20:54 JLB
P000456
Chlorobenzene
<0.34
ug/L
3
0.50
0.34
1
8260D
3/23/20 20:54 JLB
P000456
Chloroethane
<0.43
ug/L
10
0.50
0.43
1
8260D
3/23/20 20:54 JLB
P000456
Chloroform
<0.48
ug/L
5
0.50
0.48
1
8260D
3/23/20 20:54 JLB
P000456
Chloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/23/20 20:54 JLB
P000456
cis- 1,2-Dichloroethylene
<0.40
ug/L
5
0.50
0.40
1
8260D
3/23/20 20:54 JLB
P000456
cis- 1,3-Dichloropropylene
<0.36
ug/L
1
0.50
0.36
1
8260D
3/23/20 20:54 JLB
P000456
Dibromochloromethane
<0.42
ug/L
3
0.50
0.42
1
8260D
3/23/20 20:54 JLB
P000456
Dibromomethane
<0.54
ug/L
10
2.0
0.54
1
8260D
3/23/20 20:54 JLB
P000456
Ethylbenzene
<0.31
ug/L
1
0.50
0.31
1
8260D
3/23/20 20:54 JLB
P000456
m,p-Xylenes
<0.73
ug/L
NE
1.0
0.73
1
8260D
3/23/20 20:54 JLB
P000456
Methyl Butyl Ketone (2-Hexanone)
<0.29
ug/L
50
5.0
0.29
1
8260D
3/23/20 20:54 JLB
P000456
Methyl Ethyl Ketone (2-Butanone)
<0.78
ug/L
100
5.0
0.78
1
8260D
3/23/20 20:54 JLB
P000456
Methyl Iodide
<0.41
ug/L
10
5.0
0.41
1
8260D
3/23/20 20:54 JLB
P000456
Methyl Isobutyl Ketone
<0.40
ug/L
100
5.0
0.40
1
8260D
3/23/20 20:54 JLB
P000456
Methylene Chloride
<0.40
ug/L
1
1.0
0.40
1
8260D
3/23/20 20:54 JLB
P000456
o-Xylene
<0.40
ug/L
NE
0.50
0.40
1
8260D
3/23/20 20:54 JLB
P000456
Styrene
<0.26
ug/L
1
0.50
0.26
1
8260D
3/23/20 20:54 JLB
P000456
Tetrachloroethylene
<0.31
ug/L
1
0.50
0.31
1
8260D
3/23/20 20:54 JLB
P000456
Toluene
<0.35
ug/L
1
0.50
0.35
1
8260D
3/23/20 20:54 JLB
P000456
trans- 1,2-Dichloroethylene
<0.27
ug/L
5
0.50
0.27
1
8260D
3/23/20 20:54 JLB
P000456
trans- 1,3-Dichloropropylene
<0.49
ug/L
1
0.50
0.49
1
8260D
3/23/20 20:54 JLB
P000456
trans- 1,4-Dichloro-2-butene
<0.22
ug/L
100
10
0.22
1
8260D
3/23/20 20:54 JLB
P000456
Trichloroethylene
<0.46
ug/L
1
0.50
0.46
1
8260D
3/23/20 20:54 JLB
P000456
Trichlorofluoromethane
<0.24
ug/L
1
0.50
0.24
1
8260D
3/23/20 20:54 JLB
P000456
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
• � 03/27/2020
PA Waynt.�
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: MW-02-20200318
Attn: Alec Macbeth Spring Sample ID: 0030270-02
231 Haywood Street Project No.: 50-02 Work Order: 0030270
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/18/20 08:55
Time Submitted: 03/19/20 09:05
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
Vinyl acetate
Vinyl chloride
Xylenes, total
<0.26
<0.41
<1.1
ug/L
ug/L
ug/L
50
1
5
2.0 0.26 1
0.50 0.41 1
1.5 1.1 1
8260D 3/23/20 20:54 JLB
8260D 3/23/20 20:54 JLB
8260D 3/23/20 20:54 JLB
P000456
P000456
P000456
Surrogate
Recovery Control Limits
4-Bromofluorobenzene
102 % 80-124
Dibromofluoromethane
104 % 75-129
Toluene-d8
100 % 77-123
Volatile Organic Compounds by GC/MS SIM
1,4-Dioxane
3.6
ug/L
10
2.0 0.14 1
8260D SIM 3/19/20 17:08 TBL
P000385
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

0
Way poi nt.
ANALYTICAL
Anchor QEA of North Carolina, PLLC
Attn: Alec Macbeth
231 Haywood Street
Asheville, NC 28801
Laboratory Report
03/27/2020
Project: Jackson Cty Landfill 2020 Client Sample ID: MW-05R-20200318
Spring Sample ID: 0030270-03
Project No.: 50-02 Work Order: 0030270
Sample Matrix: Water Time Collected: 03/18/20 12:45
Time Submitted: 03/19/20 09:05
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
Anions by Ion Chromatography
Chloride 53000 ug/L NE 1000 380 1 9056A 3/19/20 14:35 BMS P000403
Nitrate as N 59 J ug/L 10000 200 54 1 9056A 3/19/20 14:35 BMS P000403
Sulfate <480 ug/L 250000 2000 480 1 9056A 3/19/20 14:35 BMS P000403
General Chemistry Parameters
Biochemical Oxygen Demand
6500
ug/L
NE
2000
210
1
SM5210 B
3/19/20 15:13 SLS
P000401
Chemical Oxygen Demand
85000
ug/L
NE
50000
10000
1
SM5220 D
3/23/20 11:06 SLS
P000457
Ferrous Iron
1500 HT
ug/L
NE
200
51
1
SM3500-Fe B
3/19/20 12:52 BMS
P000391
Sulfide
<830
ug/L
1000
2000
830
1
SM4500-S F
3/20/20 10:55 CBM
P000429
Total Alkalinity to pH 4.5
250000
ug/L
NE
5000
770
1
SM2320 B
3/25/20 11:40 CLB
P000503
Total Metals
Mercury
<0.034
ug/L
0.2
0.20
0.034
1
7470A
3/20/20 17:40 JAB
P000418
Antimony
<0.93
ug/L
6
3.0
0.93
1
6020B
3/23/20 16:14 MMR
P000414
Arsenic
0.51
J
ug/L
10
1.0
0.34
1
6020B
3/23/20 16:14 MMR
P000414
Barium
110
ug/L
100
10
3.2
1
6020B
3/23/20 16:14 MMR
P000414
Beryllium
<0.30
ug/L
1
1.0
0.30
1
6020B
3/23/20 16:14 MMR
P000414
Cadmium
0.33
J
ug/L
1
1.0
0.22
1
6020B
3/23/20 16:14 MMR
P000414
Chromium
3.1
ug/L
10
3.0
0.90
1
6020B
3/23/20 16:14 MMR
P000414
Cobalt
8.2
ug/L
10
2.0
0.70
1
6020B
3/23/20 16:14 MMR
P000414
Copper
5.1
J
ug/L
10
10
4.7
1
6020B
3/23/20 16:14 MMR
P000414
Lead
1.1
ug/L
10
1.0
0.44
1
6020B
3/23/20 16:14 MMR
P000414
Nickel
4.4
ug/L
50
3.0
0.83
1
6020B
3/23/20 16:14 MMR
P000414
Selenium
1.5
J
ug/L
10
5.0
0.98
1
6020B
3/23/20 16:14 MMR
P000414
Silver
<0.34
ug/L
10
1.0
0.34
1
6020B
3/23/20 16:14 MMR
P000414
Thallium
<0.84
ug/L
5.5
2.0
0.84
1
6020B
3/23/20 16:14 MMR
P000414
Vanadium
3.1
J
ug/L
25
5.0
1.5
1
6020B
3/23/20 16:14 MMR
P000414
Zinc
17
J
ug/L
10
20
10
1
6020B
3/23/20 16:14 MMR
P000414
Volatile Organic Compounds by GC/MS
1, 1, 1,2-Tetrachloroethane
<0.35
ug/L
5
0.50
0.35
1
8260D
3/23/20 21:18 JLB
P000456
1, 1, 1 -Trichloroethane
<0.31
ug/L
1
0.50
0.31
1
8260D
3/23/20 21:18 JLB
P000456
1,1,2,2-Tetrachloroethane
<0.34
ug/L
3
0.50
0.34
1
8260D
3/23/20 21:18 JLB
P000456
1,1,2-Trichloroethane
<0.42
ug/L
1
0.50
0.42
1
8260D
3/23/20 21:18 JLB
P000456
1,1-Dichloroethane
<0.29
ug/L
5
0.50
0.29
1
8260D
3/23/20 21:18 JLB
P000456
1,1-Dichloroethylene
<0.35
ug/L
5
0.50
0.35
1
8260D
3/23/20 21:18 JLB
P000456
1,2,3-Trichloropropane
<0.34
ug/L
1
1.0
0.34
1
8260D
3/23/20 21:18 JLB
P000456
1,2-Dibromo-3-chloropropane
<0.59
ug/L
13
2.0
0.59
1
8260D
3/23/20 21:18 JLB
P000456
1,2-Dibromoethane
<0.37
ug/L
1
0.50
0.37
1
8260D
3/23/20 21:18 JLB
P000456
1,2-Dichlorobenzene
<0.28
ug/L
5
0.50
0.28
1
8260D
3/23/20 21:18 JLB
P000456
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
A i • .0 03/27/2020
- -ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: MW-05R-20200318
Attn: Alec Macbeth Spring Sample ID: 0030270-03
231 Haywood Street Project No.: 50-02 Work Order: 0030270
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/18/20 12:45
Time Submitted: 03/19/20 09:05
Parameter
Result
Units
SWSL
Report
Limit
MDL
Dilution
Factor
Method
Analysis Analyst
Date/Time
Batch
ID
1,2-Dichloroethane
<0.41
ug/L
1
0.50
0.41
1
8260D
3/23/20 21:18 JLB
P000456
1,2-Dichloropropane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/23/20 21:18 JLB
P000456
1,4-Dichlorobenzene
6.6
ug/L
1
0.50
0.42
1
8260D
3/23/20 21:18 JLB
P000456
Acetone
2.7 J
ug/L
100
5.0
0.70
1
8260D
3/23/20 21:18 JLB
P000456
Acrylonitrile
<0.85
ug/L
200
20
0.85
1
8260D
3/23/20 21:18 JLB
P000456
Benzene
2.1
ug/L
1
0.50
0.34
1
8260D
3/23/20 21:18 JLB
P000456
Bromochloromethane
<0.53
ug/L
3
2.0
0.53
1
8260D
3/23/20 21:18 JLB
P000456
Bromodichloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/23/20 21:18 JLB
P000456
Bromoform
<0.26
ug/L
3
1.0
0.26
1
8260D
3/23/20 21:18 JLB
P000456
Bromomethane
<0.48
ug/L
10
1.0
0.48
1
8260D
3/23/20 21:18 JLB
P000456
Carbon disulfide
<0.36
ug/L
100
5.0
0.36
1
8260D
3/23/20 21:18 JLB
P000456
Carbon Tetrachloride
<0.55
ug/L
1
2.0
0.55
1
8260D
3/23/20 21:18 JLB
P000456
Chlorobenzene
8.1
ug/L
3
0.50
0.34
1
8260D
3/23/20 21:18 JLB
P000456
Chloroethane
<0.43
ug/L
10
0.50
0.43
1
8260D
3/23/20 21:18 JLB
P000456
Chloroform
<0.48
ug/L
5
0.50
0.48
1
8260D
3/23/20 21:18 JLB
P000456
Chloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/23/20 21:18 JLB
P000456
cis-1,2-Dichloroethylene
1.8
ug/L
5
0.50
0.40
1
8260D
3/23/20 21:18 JLB
P000456
cis- 1,3-Dichloropropylene
<0.36
ug/L
1
0.50
0.36
1
8260D
3/23/20 21:18 JLB
P000456
Dibromochloromethane
<0.42
ug/L
3
0.50
0.42
1
8260D
3/23/20 21:18 JLB
P000456
Dibromomethane
<0.54
ug/L
10
2.0
0.54
1
8260D
3/23/20 21:18 JLB
P000456
Ethylbenzene
<0.31
ug/L
1
0.50
0.31
1
8260D
3/23/20 21:18 JLB
P000456
m,p-Xylenes
<0.73
ug/L
NE
1.0
0.73
1
8260D
3/23/20 21:18 JLB
P000456
Methyl Butyl Ketone (2-Hexanone)
<0.29
ug/L
50
5.0
0.29
1
8260D
3/23/20 21:18 JLB
P000456
Methyl Ethyl Ketone (2-Butanone)
<0.78
ug/L
100
5.0
0.78
1
8260D
3/23/20 21:18 JLB
P000456
Methyl Iodide
<0.41
ug/L
10
5.0
0.41
1
8260D
3/23/20 21:18 JLB
P000456
Methyl Isobutyl Ketone
<0.40
ug/L
100
5.0
0.40
1
8260D
3/23/20 21:18 JLB
P000456
Methylene Chloride
<0.40
ug/L
1
1.0
0.40
1
8260D
3/23/20 21:18 JLB
P000456
o-Xylene
<0.40
ug/L
NE
0.50
0.40
1
8260D
3/23/20 21:18 JLB
P000456
Styrene
<0.26
ug/L
1
0.50
0.26
1
8260D
3/23/20 21:18 JLB
P000456
Tetrachloroethylene
<0.31
ug/L
1
0.50
0.31
1
8260D
3/23/20 21:18 JLB
P000456
Toluene
<0.35
ug/L
1
0.50
0.35
1
8260D
3/23/20 21:18 JLB
P000456
trans- 1,2-Dichloroethylene
<0.27
ug/L
5
0.50
0.27
1
8260D
3/23/20 21:18 JLB
P000456
trans- 1,3-Dichloropropylene
<0.49
ug/L
1
0.50
0.49
1
8260D
3/23/20 21:18 JLB
P000456
trans- 1,4-Dichloro-2-butene
<0.22
ug/L
100
10
0.22
1
8260D
3/23/20 21:18 JLB
P000456
Trichloroethylene
<0.46
ug/L
1
0.50
0.46
1
8260D
3/23/20 21:18 JLB
P000456
Trichlorofluoromethane
<0.24
ug/L
1
0.50
0.24
1
8260D
3/23/20 21:18 JLB
P000456
Vinyl acetate
<0.26
ug/L
50
2.0
0.26
1
8260D
3/23/20 21:18 JLB
P000456
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
• � 03/27/2020
PA Waynt.�
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: MW-05R-20200318
Attn: Alec Macbeth Spring Sample ID: 0030270-03
231 Haywood Street Project No.: 50-02 Work Order: 0030270
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/18/20 12:45
Time Submitted: 03/19/20 09:05
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
Vinyl chloride 2.5 ug/L 1 0.50 0.41 1 8260D 3/23/20 21:18 JLB P000456
Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 3/23/20 21:18 JLB P000456
Volatile Organic Compounds by GC/MS SIM
1,4-Dioxane 4.9
Surrogate
Recovery Control Limits
4-Bromofluorobenzene
101 %
80-124
Dibromofluoromethane
104 %
75-129
Toluene-d8
99 %
77-123
ug/L 10 2.0 0.14 1 8260D SIM 3/19/20 17:33 TBL P000385
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
A i • .0 03/27/2020
- -ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: MW-06-20200318
Attn: Alec Macbeth Spring Sample ID: 0030270-04
231 Haywood Street Project No.: 50-02 Work Order: 0030270
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/18/20 10:13
Time Submitted: 03/19/20 09:05
Parameter
Result
Units
SWSL
Report
MDL
Dilution
Method
Analysis Analyst
Batch
Limit
Factor
Date/Time
ID
Anions by Ion Chromatography
Chloride
1000
ug/L
NE
1000
380
1
9056A
3/19/20 13:49 BMS
P000403
Nitrate as N
150
J
ug/L
10000
200
54
1
9056A
3/19/20 13:49 BMS
P000403
Sulfate
560
J
ug/L
250000
2000
480
1
9056A
3/19/20 13:49 BMS
P000403
General Chemistry Parameters
Biochemical Oxygen Demand
540
J
ug/L
NE
2000
210
1
SM5210 B
3/19/20 15:13 SLS
P000401
Chemical Oxygen Demand
<10000
ug/L
NE
50000
10000
1
SM5220 D
3/23/20 11:06 SLS
P000457
Ferrous Iron
<51
HT
ug/L
NE
200
51
1
SM3500-Fe B
3/19/20 12:52 BMS
P000391
Sulfide
<830
ug/L
1000
2000
830
1
SM4500-S F
3/20/20 10:55 CBM
P000429
Total Alkalinity to pH 4.5
24000
ug/L
NE
5000
770
1
SM2320 B
3/25/20 11:40 CLB
P000503
Total Metals
Mercury
<0.034
ug/L
0.2
0.20
0.034
1
7470A
3/20/20 17:44 JAB
P000418
Antimony
<0.93
ug/L
6
3.0
0.93
1
6020B
3/23/20 16:20 MMR
P000414
Arsenic
<0.34
ug/L
10
1.0
0.34
1
6020B
3/23/20 16:20 MMR
P000414
Barium
47
ug/L
100
10
3.2
1
6020B
3/23/20 16:20 MMR
P000414
Beryllium
<0.30
ug/L
1
1.0
0.30
1
6020B
3/23/20 16:20 MMR
P000414
Cadmium
<0.22
ug/L
1
1.0
0.22
1
6020B
3/23/20 16:20 MMR
P000414
Chromium
<0.90
ug/L
10
3.0
0.90
1
6020B
3/23/20 16:20 MMR
P000414
Cobalt
6.9
ug/L
10
2.0
0.70
1
6020B
3/23/20 16:20 MMR
P000414
Copper
<4.7
ug/L
10
10
4.7
1
6020B
3/23/20 16:20 MMR
P000414
Lead
1.2
ug/L
10
1.0
0.44
1
6020B
3/23/20 16:20 MMR
P000414
Nickel
4.1
ug/L
50
3.0
0.83
1
6020B
3/23/20 16:20 MMR
P000414
Selenium
1.0
J
ug/L
10
5.0
0.98
1
6020B
3/23/20 16:20 MMR
P000414
Silver
<0.34
ug/L
10
1.0
0.34
1
6020B
3/23/20 16:20 MMR
P000414
Thallium
<0.84
ug/L
5.5
2.0
0.84
1
6020B
3/23/20 16:20 MMR
P000414
Vanadium
<1.5
ug/L
25
5.0
1.5
1
6020B
3/23/20 16:20 MMR
P000414
Zinc
14
J
ug/L
10
20
10
1
6020B
3/23/20 16:20 MMR
P000414
Volatile Organic Compounds by GC/MS
1,1,1,2-Tetrachloroethane
<0.35
ug/L
5
0.50
0.35
1
8260D
3/23/20 21:43 JLB
P000456
1, 1, 1 -Trichloroethane
<0.31
ug/L
1
0.50
0.31
1
8260D
3/23/20 21:43 JLB
P000456
1,1,2,2-Tetrachloroethane
<0.34
ug/L
3
0.50
0.34
1
8260D
3/23/20 21:43 JLB
P000456
1,1,2-Trichloroethane
<0.42
ug/L
1
0.50
0.42
1
8260D
3/23/20 21:43 JLB
P000456
1,1-Dichloroethane
1.2
ug/L
5
0.50
0.29
1
8260D
3/23/20 21:43 JLB
P000456
1,1-Dichloroethylene
<0.35
ug/L
5
0.50
0.35
1
8260D
3/23/20 21:43 JLB
P000456
1,2,3-Trichloropropane
<0.34
ug/L
1
1.0
0.34
1
8260D
3/23/20 21:43 JLB
P000456
1,2-Dibromo-3-chloropropane
<0.59
ug/L
13
2.0
0.59
1
8260D
3/23/20 21:43 JLB
P000456
1,2-Dibromoethane
<0.37
ug/L
1
0.50
0.37
1
8260D
3/23/20 21:43 JLB
P000456
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
A i • .0 03/27/2020
- -ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: MW-06-20200318
Attn: Alec Macbeth Spring Sample ID: 0030270-04
231 Haywood Street Project No.: 50-02 Work Order: 0030270
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/18/20 10:13
Time Submitted: 03/19/20 09:05
Parameter
Result
Units
SWSL
Report
Limit
MDL
Dilution
Factor
Method
Analysis Analyst
Date/Time
Batch
ID
1,2-Dichlorobenzene
<0.28
ug/L
5
0.50
0.28
1
8260D
3/23/20 21:43 JLB
P000456
1,2-Dichloroethane
<0.41
ug/L
1
0.50
0.41
1
8260D
3/23/20 21:43 JLB
P000456
1,2-Dichloropropane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/23/20 21:43 JLB
P000456
1,4-Dichlorobenzene
<0.42
ug/L
1
0.50
0.42
1
8260D
3/23/20 21:43 JLB
P000456
Acetone
<0.70
ug/L
100
5.0
0.70
1
8260D
3/23/20 21:43 JLB
P000456
Acrylonitrile
<0.85
ug/L
200
20
0.85
1
8260D
3/23/20 21:43 JLB
P000456
Benzene
<0.34
ug/L
1
0.50
0.34
1
8260D
3/23/20 21:43 JLB
P000456
Bromochloromethane
<0.53
ug/L
3
2.0
0.53
1
8260D
3/23/20 21:43 JLB
P000456
Bromodichloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/23/20 21:43 JLB
P000456
Bromoform
<0.26
ug/L
3
1.0
0.26
1
8260D
3/23/20 21:43 JLB
P000456
Bromomethane
<0.48
ug/L
10
1.0
0.48
1
8260D
3/23/20 21:43 JLB
P000456
Carbon disulfide
<0.36
ug/L
100
5.0
0.36
1
8260D
3/23/20 21:43 JLB
P000456
Carbon Tetrachloride
<0.55
ug/L
1
2.0
0.55
1
8260D
3/23/20 21:43 JLB
P000456
Chlorobenzene
<0.34
ug/L
3
0.50
0.34
1
8260D
3/23/20 21:43 JLB
P000456
Chloroethane
<0.43
ug/L
10
0.50
0.43
1
8260D
3/23/20 21:43 JLB
P000456
Chloroform
<0.48
ug/L
5
0.50
0.48
1
8260D
3/23/20 21:43 JLB
P000456
Chloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/23/20 21:43 JLB
P000456
cis-1,2-Dichloroethylene
1.0
ug/L
5
0.50
0.40
1
8260D
3/23/20 21:43 JLB
P000456
cis- 1,3-Dichloropropylene
<0.36
ug/L
1
0.50
0.36
1
8260D
3/23/20 21:43 JLB
P000456
Dibromochloromethane
<0.42
ug/L
3
0.50
0.42
1
8260D
3/23/20 21:43 JLB
P000456
Dibromomethane
<0.54
ug/L
10
2.0
0.54
1
8260D
3/23/20 21:43 JLB
P000456
Ethylbenzene
<0.31
ug/L
1
0.50
0.31
1
8260D
3/23/20 21:43 JLB
P000456
m,p-Xylenes
<0.73
ug/L
NE
1.0
0.73
1
8260D
3/23/20 21:43 JLB
P000456
Methyl Butyl Ketone (2-Hexanone)
<0.29
ug/L
50
5.0
0.29
1
8260D
3/23/20 21:43 JLB
P000456
Methyl Ethyl Ketone (2-Butanone)
<0.78
ug/L
100
5.0
0.78
1
8260D
3/23/20 21:43 JLB
P000456
Methyl Iodide
<0.41
ug/L
10
5.0
0.41
1
8260D
3/23/20 21:43 JLB
P000456
Methyl Isobutyl Ketone
<0.40
ug/L
100
5.0
0.40
1
8260D
3/23/20 21:43 JLB
P000456
Methylene Chloride
<0.40
ug/L
1
1.0
0.40
1
8260D
3/23/20 21:43 JLB
P000456
o-Xylene
<0.40
ug/L
NE
0.50
0.40
1
8260D
3/23/20 21:43 JLB
P000456
Styrene
<0.26
ug/L
1
0.50
0.26
1
8260D
3/23/20 21:43 JLB
P000456
Tetrachloroethylene
<0.31
ug/L
1
0.50
0.31
1
8260D
3/23/20 21:43 JLB
P000456
Toluene
<0.35
ug/L
1
0.50
0.35
1
8260D
3/23/20 21:43 JLB
P000456
trans- 1,2-Dichloroethylene
<0.27
ug/L
5
0.50
0.27
1
8260D
3/23/20 21:43 JLB
P000456
trans- 1,3-Dichloropropylene
<0.49
ug/L
1
0.50
0.49
1
8260D
3/23/20 21:43 JLB
P000456
trans- 1,4-Dichloro-2-butene
<0.22
ug/L
100
10
0.22
1
8260D
3/23/20 21:43 JLB
P000456
Trichloroethylene
<0.46
ug/L
1
0.50
0.46
1
8260D
3/23/20 21:43 JLB
P000456
Trichlorofluoromethane
<0.24
ug/L
1
0.50
0.24
1
8260D
3/23/20 21:43 JLB
P000456
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
• � 03/27/2020
PA Waynt.�
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: MW-06-20200318
Attn: Alec Macbeth Spring Sample ID: 0030270-04
231 Haywood Street Project No.: 50-02 Work Order: 0030270
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/18/20 10:13
Time Submitted: 03/19/20 09:05
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
Vinyl acetate
Vinyl chloride
Xylenes, total
<0.26
<0.41
<1.1
ug/L
ug/L
ug/L
50
1
5
2.0 0.26 1
0.50 0.41 1
1.5 1.1 1
8260D 3/23/20 21:43 JLB
8260D 3/23/20 21:43 JLB
8260D 3/23/20 21:43 JLB
P000456
P000456
P000456
Surrogate
Recovery Control Limits
4-Bromofluorobenzene
101 % 80-124
Dibromofluoromethane
103 % 75-129
Toluene-d8
100 % 77-123
Volatile Organic Compounds by GC/MS SIM
1,4-Dioxane
<0.14
ug/L
10
2.0 0.14 1
8260D SIM 3/19/20 17:58 TBL
P000385
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
• � 03/27/2020
PA Waynt.�
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: LT-01-20200318
Attn: Alec Macbeth Spring Sample ID: 0030270-05
231 Haywood Street Project No.: 50-02 Work Order: 0030270
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/18/20 12:02
Time Submitted: 03/19/20 09:05
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
Volatile Organic Compounds by GC/MS
1, 1, 1,2-Tetrachloroethane
<0.35
ug/L
5
0.50
0.35
1
8260D
3/23/20 22:07 JLB
P000456
1, 1, 1 -Trichloroethane
<0.31
ug/L
1
0.50
0.31
1
8260D
3/23/20 22:07 JLB
P000456
1,1,2,2-Tetrachloroethane
<0.34
ug/L
3
0.50
0.34
1
8260D
3/23/20 22:07 JLB
P000456
1,1,2-Trichloroethane
<0.42
ug/L
1
0.50
0.42
1
8260D
3/23/20 22:07 JLB
P000456
1,1-Dichloroethane
<0.29
ug/L
5
0.50
0.29
1
8260D
3/23/20 22:07 JLB
P000456
1,1-Dichloroethylene
<0.35
ug/L
5
0.50
0.35
1
8260D
3/23/20 22:07 JLB
P000456
1,2,3-Trichloropropane
<0.34
ug/L
1
1.0
0.34
1
8260D
3/23/20 22:07 JLB
P000456
1,2-Dibromo-3-chloropropane
<0.59
ug/L
13
2.0
0.59
1
8260D
3/23/20 22:07 JLB
P000456
1,2-Dibromoethane
<0.37
ug/L
1
0.50
0.37
1
8260D
3/23/20 22:07 JLB
P000456
1,2-Dichlorobenzene
<0.28
ug/L
5
0.50
0.28
1
8260D
3/23/20 22:07 JLB
P000456
1,2-Dichloroethane
<0.41
ug/L
1
0.50
0.41
1
8260D
3/23/20 22:07 JLB
P000456
1,2-Dichloropropane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/23/20 22:07 JLB
P000456
1,4-Dichlorobenzene
5.6
ug/L
1
0.50
0.42
1
8260D
3/23/20 22:07 JLB
P000456
Acetone
6.4
ug/L
100
5.0
0.70
1
8260D
3/23/20 22:07 JLB
P000456
Acrylonitrile
<0.85
ug/L
200
20
0.85
1
8260D
3/23/20 22:07 JLB
P000456
Benzene
1.3
ug/L
1
0.50
0.34
1
8260D
3/23/20 22:07 JLB
P000456
Bromochloromethane
<0.53
ug/L
3
2.0
0.53
1
8260D
3/23/20 22:07 JLB
P000456
Bromodichloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/23/20 22:07 JLB
P000456
Bromoform
<0.26
ug/L
3
1.0
0.26
1
8260D
3/23/20 22:07 JLB
P000456
Bromomethane
<0.48
ug/L
10
1.0
0.48
1
8260D
3/23/20 22:07 JLB
P000456
Carbon disulfide
<0.36
ug/L
100
5.0
0.36
1
8260D
3/23/20 22:07 JLB
P000456
Carbon Tetrachloride
<0.55
ug/L
1
2.0
0.55
1
8260D
3/23/20 22:07 JLB
P000456
Chlorobenzene
3.2
ug/L
3
0.50
0.34
1
8260D
3/23/20 22:07 JLB
P000456
Chloroethane
<0.43
ug/L
10
0.50
0.43
1
8260D
3/23/20 22:07 JLB
P000456
Chloroform
<0.48
ug/L
5
0.50
0.48
1
8260D
3/23/20 22:07 JLB
P000456
Chloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/23/20 22:07 JLB
P000456
cis- 1,2-Dichloroethylene
<0.40
ug/L
5
0.50
0.40
1
8260D
3/23/20 22:07 JLB
P000456
cis- 1,3-Dichloropropylene
<0.36
ug/L
1
0.50
0.36
1
8260D
3/23/20 22:07 JLB
P000456
Dibromochloromethane
<0.42
ug/L
3
0.50
0.42
1
8260D
3/23/20 22:07 JLB
P000456
Dibromomethane
<0.54
ug/L
10
2.0
0.54
1
8260D
3/23/20 22:07 JLB
P000456
Ethylbenzene
2.7
ug/L
1
0.50
0.31
1
8260D
3/23/20 22:07 JLB
P000456
m,p-Xylenes
0.89 J
ug/L
NE
1.0
0.73
1
8260D
3/23/20 22:07 JLB
P000456
Methyl Butyl Ketone (2-Hexanone)
<0.29
ug/L
50
5.0
0.29
1
8260D
3/23/20 22:07 JLB
P000456
Methyl Ethyl Ketone (2-Butanone)
<0.78
ug/L
100
5.0
0.78
1
8260D
3/23/20 22:07 JLB
P000456
Methyl Iodide
<0.41
ug/L
10
5.0
0.41
1
8260D
3/23/20 22:07 JLB
P000456
Methyl Isobutyl Ketone
0.79 J
ug/L
100
5.0
0.40
1
8260D
3/23/20 22:07 JLB
P000456
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
• � 03/27/2020
PA Waynt.�
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: LT-01-20200318
Attn: Alec Macbeth Spring Sample ID: 0030270-05
231 Haywood Street Project No.: 50-02 Work Order: 0030270
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/18/20 12:02
Time Submitted: 03/19/20 09:05
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
Methylene Chloride
<0.40
ug/L
1
1.0
0.40
1
8260D
3/23/20 22:07 JLB
P000456
o-Xylene
1.2
ug/L
NE
0.50
0.40
1
8260D
3/23/20 22:07 JLB
P000456
Styrene
<0.26
ug/L
1
0.50
0.26
1
8260D
3/23/20 22:07 JLB
P000456
Tetrachloroethylene
<0.31
ug/L
1
0.50
0.31
1
8260D
3/23/20 22:07 JLB
P000456
Toluene
0.70
ug/L
1
0.50
0.35
1
8260D
3/23/20 22:07 JLB
P000456
trans- 1,2-Dichloroethylene
<0.27
ug/L
5
0.50
0.27
1
8260D
3/23/20 22:07 JLB
P000456
trans- 1,3-Dichloropropylene
<0.49
ug/L
1
0.50
0.49
1
8260D
3/23/20 22:07 JLB
P000456
trans- 1,4-Dichloro-2-butene
<0.22
ug/L
100
10
0.22
1
8260D
3/23/20 22:07 JLB
P000456
Trichloroethylene
<0.46
ug/L
1
0.50
0.46
1
8260D
3/23/20 22:07 JLB
P000456
Trichlorofluoromethane
<0.24
ug/L
1
0.50
0.24
1
8260D
3/23/20 22:07 JLB
P000456
Vinyl acetate
<0.26
ug/L
50
2.0
0.26
1
8260D
3/23/20 22:07 JLB
P000456
Vinyl chloride
<0.41
ug/L
1
0.50
0.41
1
8260D
3/23/20 22:07 JLB
P000456
Xylenes, total
2.0
ug/L
5
1.5
1.1
1
8260D
3/23/20 22:07 JLB
P000456
Surrogate
Recovery Control Limits
4-Bromofluorobenzene
102 % 80-124
Dibromofluoromethane
105 % 75-129
Toluene-d8
99 %
77-123
Volatile Organic Compounds by GUMS SIM
1,4-Dioxane
60
ug/L
10
2.0
0.14
1
8260D SIM
3/19/20 18:23 TBL
P000385
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
• � 03/27/2020
PA Waynt.�
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Client Sample ID: TB-20200318
Attn: Alec Macbeth Spring Sample ID: 0030270-06
231 Haywood Street Project No.: 50-02 Work Order: 0030270
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/18/20 00:00
Time Submitted: 03/19/20 09:05
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
Volatile Organic Compounds by GC/MS
1, 1, 1,2-Tetrachloroethane
<0.35
ug/L
5
0.50
0.35
1
8260D
3/23/20 15:59 JLB
P000456
1, 1, 1 -Trichloroethane
<0.31
ug/L
1
0.50
0.31
1
8260D
3/23/20 15:59 JLB
P000456
1,1,2,2-Tetrachloroethane
<0.34
ug/L
3
0.50
0.34
1
8260D
3/23/20 15:59 JLB
P000456
1,1,2-Trichloroethane
<0.42
ug/L
1
0.50
0.42
1
8260D
3/23/20 15:59 JLB
P000456
1,1-Dichloroethane
<0.29
ug/L
5
0.50
0.29
1
8260D
3/23/20 15:59 JLB
P000456
1,1-Dichloroethylene
<0.35
ug/L
5
0.50
0.35
1
8260D
3/23/20 15:59 JLB
P000456
1,2,3-Trichloropropane
<0.34
ug/L
1
1.0
0.34
1
8260D
3/23/20 15:59 JLB
P000456
1,2-Dibromo-3-chloropropane
<0.59
ug/L
13
2.0
0.59
1
8260D
3/23/20 15:59 JLB
P000456
1,2-Dibromoethane
<0.37
ug/L
1
0.50
0.37
1
8260D
3/23/20 15:59 JLB
P000456
1,2-Dichlorobenzene
<0.28
ug/L
5
0.50
0.28
1
8260D
3/23/20 15:59 JLB
P000456
1,2-Dichloroethane
<0.41
ug/L
1
0.50
0.41
1
8260D
3/23/20 15:59 JLB
P000456
1,2-Dichloropropane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/23/20 15:59 JLB
P000456
1,4-Dichlorobenzene
<0.42
ug/L
1
0.50
0.42
1
8260D
3/23/20 15:59 JLB
P000456
Acetone
<0.70
ug/L
100
5.0
0.70
1
8260D
3/23/20 15:59 JLB
P000456
Acrylonitrile
<0.85
ug/L
200
20
0.85
1
8260D
3/23/20 15:59 JLB
P000456
Benzene
<0.34
ug/L
1
0.50
0.34
1
8260D
3/23/20 15:59 JLB
P000456
Bromochloromethane
<0.53
ug/L
3
2.0
0.53
1
8260D
3/23/20 15:59 JLB
P000456
Bromodichloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/23/20 15:59 JLB
P000456
Bromoform
<0.26
ug/L
3
1.0
0.26
1
8260D
3/23/20 15:59 JLB
P000456
Bromomethane
<0.48
ug/L
10
1.0
0.48
1
8260D
3/23/20 15:59 JLB
P000456
Carbon disulfide
<0.36
ug/L
100
5.0
0.36
1
8260D
3/23/20 15:59 JLB
P000456
Carbon Tetrachloride
<0.55
ug/L
1
2.0
0.55
1
8260D
3/23/20 15:59 JLB
P000456
Chlorobenzene
<0.34
ug/L
3
0.50
0.34
1
8260D
3/23/20 15:59 JLB
P000456
Chloroethane
<0.43
ug/L
10
0.50
0.43
1
8260D
3/23/20 15:59 JLB
P000456
Chloroform
<0.48
ug/L
5
0.50
0.48
1
8260D
3/23/20 15:59 JLB
P000456
Chloromethane
<0.29
ug/L
1
0.50
0.29
1
8260D
3/23/20 15:59 JLB
P000456
cis- 1,2-Dichloroethylene
<0.40
ug/L
5
0.50
0.40
1
8260D
3/23/20 15:59 JLB
P000456
cis- 1,3-Dichloropropylene
<0.36
ug/L
1
0.50
0.36
1
8260D
3/23/20 15:59 JLB
P000456
Dibromochloromethane
<0.42
ug/L
3
0.50
0.42
1
8260D
3/23/20 15:59 JLB
P000456
Dibromomethane
<0.54
ug/L
10
2.0
0.54
1
8260D
3/23/20 15:59 JLB
P000456
Ethylbenzene
<0.31
ug/L
1
0.50
0.31
1
8260D
3/23/20 15:59 JLB
P000456
m,p-Xylenes
<0.73
ug/L
NE
1.0
0.73
1
8260D
3/23/20 15:59 JLB
P000456
Methyl Butyl Ketone (2-Hexanone)
<0.29
ug/L
50
5.0
0.29
1
8260D
3/23/20 15:59 JLB
P000456
Methyl Ethyl Ketone (2-Butanone)
<0.78
ug/L
100
5.0
0.78
1
8260D
3/23/20 15:59 JLB
P000456
Methyl Iodide
<0.41
ug/L
10
5.0
0.41
1
8260D
3/23/20 15:59 JLB
P000456
Methyl Isobutyl Ketone
<0.40
ug/L
100
5.0
0.40
1
8260D
3/23/20 15:59 JLB
P000456
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

.
Laboratory Report
• �
Waynt..
03/27/2020
poi
ANALYTICAL
Anchor QEA of North Carolina, PLLC
Project: Jackson Cty Landfill 2020
Client Sample ID: TB-20200318
Attn: Alec Macbeth
Spring
Sample ID: 0030270-06
231 Haywood Street
Project No.:
50-02
Work Order: 0030270
Asheville, NC 28801
Sample Matrix:
Water
Time Collected: 03/18/20 00:00
Time Submitted: 03/19/20 09:05
Parameter
Result
Units
SWSL
Report
MDL
Dilution Method Analysis Analyst
Batch
Limit
Factor Date/Time
ID
Methylene Chloride
<0.40
ug/L
1
1.0
0.40
1 8260D 3/23/20 15:59 JLB
P000456
o-Xylene
<0.40
ug/L
NE
0.50
0.40
1 8260D 3/23/20 15:59 JLB
P000456
Styrene
<0.26
ug/L
1
0.50
0.26
1 8260D 3/23/20 15:59 JLB
P000456
Tetrachloroethylene
<0.31
ug/L
1
0.50
0.31
1 8260D 3/23/20 15:59 JLB
P000456
Toluene
<0.35
ug/L
1
0.50
0.35
1 8260D 3/23/20 15:59 JLB
P000456
trans- 1,2-Dichloroethylene
<0.27
ug/L
5
0.50
0.27
1 8260D 3/23/20 15:59 JLB
P000456
trans- 1,3-Dichloropropylene
<0.49
ug/L
1
0.50
0.49
1 8260D 3/23/20 15:59 JLB
P000456
trans- 1,4-Dichloro-2-butene
<0.22
ug/L
100
10
0.22
1 8260D 3/23/20 15:59 JLB
P000456
Trichloroethylene
<0.46
ug/L
1
0.50
0.46
1 8260D 3/23/20 15:59 JLB
P000456
Trichlorofluoromethane
<0.24
ug/L
1
0.50
0.24
1 8260D 3/23/20 15:59 JLB
P000456
Vinyl acetate
<0.26
ug/L
50
2.0
0.26
1 8260D 3/23/20 15:59 JLB
P000456
Vinyl chloride
<0.41
ug/L
1
0.50
0.41
1 8260D 3/23/20 15:59 JLB
P000456
Xylenes, total
<1.1
ug/L
5
1.5
1.1
1 8260D 3/23/20 15:59 JLB
P000456
Surrogate
Recovery Control Limits
4-Bromofluorobenzene
101 % 80-124
Dibromofluoromethane
102 % 75-129
Toluene-d8
98 % 77-123
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

(2)
Way po Int
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Spring
Attn: Alec Macbeth
231 Haywood Street Project No: 50-02
Asheville, NC 28801
Volatile Organic Compounds by GC/MS - Quality Control
Level II QC Report
3/27/20
Work Order: 0030270
Time Submitted: 3/19/2020 9:O5:OOAM
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P000456 - 5030B
Blank (P000456-BLK1)
Prepared &Analyzed: 03/23/20
1,1,1,2-Tetrachloroethane
BRL
0.50
ug/L
1,1,1-Trichloroethane
BRL
0.50
ug/L
1,1,2,2-Tetrachloroethane
BRL
0.50
ug/L
1,1,2-Trichloroethane
BRL
0.50
ug/L
1,1-Dichloroethane
BRL
0.50
ug/L
1,1-Dichloroethylene
BRL
0.50
ug/L
1,2,3-Trichloropropane
BRL
1.0
ug/L
1,2-Dibromo-3-chloropropane
BRL
2.0
ug/L
1,2-Dibromoethane
BRL
0.50
ug/L
1,2-Dichlorobenzene
BRL
0.50
ug/L
1,2-Dichloroethane
BRL
0.50
ug/L
1,2-Dichloropropane
BRL
0.50
ug/L
1,4-Dichlorobenzene
BRL
0.50
ug/L
Acetone
BRL
5.0
ug/L
Acrylonitrile
BRL
20
ug/L
Benzene
BRL
0.50
ug/L
Bromochloromethane
BRL
2.0
ug/L
Bromodichloromethane
BRL
0.50
ug/L
Bromoform
BRL
1.0
ug/L
Bromomethane
BRL
1.0
ug/L
Carbon disulfide
BRL
5.0
ug/L
Carbon Tetrachloride
BRL
2.0
ug/L
Chlorobenzene
BRL
0.50
ug/L
Chloroethane
BRL
0.50
ug/L
Chloroform
BRL
0.50
ug/L
Chloromethane
BRL
0.50
ug/L
cis-1,2-Dichloroethylene
BRL
0.50
ug/L
cis-1,3-Dichloropropylene
BRL
0.50
ug/L
Dibromochloromethane
BRL
0.50
ug/L
Dibromomethane
BRL
2.0
ug/L
Ethylbenzene
BRL
0.50
ug/L
m,p-Xylenes
BRL
1.0
ug/L
Methyl Butyl Ketone (2-Hexanone)
BRL
5.0
ug/L
Methyl Ethyl Ketone (2-Butanone)
BRL
5.0
ug/L
Methyl Iodide
BRL
5.0
ug/L
Methyl Isobutyl Ketone
BRL
5.0
ug/L
Methylene Chloride
BRL
1.0
ug/L
o-Xylene
BRL
0.50
ug/L
Styrene
BRL
0.50
ug/L
Tetrachloroethylene
BRL
0.50
ug/L
Toluene
BRL
0.50
ug/L
trans-1,2-Dichloroethylene
BRL
0.50
ug/L
trans-1,3-Dichloropropylene
BRL
0.50
ug/L
trans-1,4-Dichloro-2-butene
BRL
10
ug/L
Trichloroethylene
BRL
0.50
ug/L
Trichlorofluoromethane
BRL
0.50
ug/L
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Waypoint '
ANALYTICAL
Level II QC Report
3/27/20
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Spring Work Order: 0030270
Attn: Alec Macbeth Time Submitted: 3/19/2020 9:05:OOAM
231 Haywood Street Project No: 50-02
Asheville, NC 28801
Volatile Organic Compounds by GC/MS - Quality Control
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P000456 - 5030B
Blank (P000456-BLK1)
Prepared & Analyzed: 03/23/20
Vinyl acetate
BRL
2.0
ug/L
Vinyl chloride
BRL
0.50
ug/L
Xylenes, total
BRL
1.5
ug/L
Surrogate:4-Bromofluorobenzene
50.7
ug/L
50.00
101
80-124
Surrogate: Dibromofluoromethane
51.0
ug/L
50.00
102
75-129
Surrogate: Toluene-d8
49.4
ug/L
50.00
99
77-123
LCS (P000456-BS1)
Prepared &Analyzed: 03/23/20
1,1,1,2-Tetrachloroethane
19.0
0.50
ug/L
20.00
95
79-134
1,1,1-Trichloroethane
18.1
0.50
ug/L
20.00
90
75-136
1,1,2,2-Tetrachloroethane
19.9
0.50
ug/L
20.00
99
62-127
1,1,2-Trichloroethane
19.8
0.50
ug/L
20.00
99
70-140
1,1-Dichloroethane
18.7
0.50
ug/L
20.00
93
78-130
1,1-Dichloroethylene
18.0
0.50
ug/L
20.00
90
70-154
1,2,3-Trichloropropane
19.3
1.0
ug/L
20.00
96
71-127
1,2-Dibromo-3-chloropropane
20.0
2.0
ug/L
20.00
100
63-134
1,2-Dibromoethane
19.2
0.50
ug/L
20.00
96
77-135
1,2-Dichlorobenzene
21.0
0.50
ug/L
20.00
105
78-128
1,2-Dichloroethane
18.2
0.50
ug/L
20.00
91
68-131
1,2-Dichloropropane
19.1
0.50
ug/L
20.00
95
77-130
1,4-Dichlorobenzene
19.8
0.50
ug/L
20.00
99
75-126
Acetone
39.3
5.0
ug/L
40.00
98
40-166
Acrylonitrile
38.3
20
ug/L
40.00
96
81-127
Benzene
18.9
0.50
ug/L
20.00
95
77-128
Bromochloromethane
20.3
2.0
ug/L
20.00
102
78-135
Bromodichloromethane
19.1
0.50
ug/L
20.00
95
76-138
Bromoform
19.3
1.0
ug/L
20.00
97
71-135
Bromomethane
18.4
1.0
ug/L
20.00
92
41-168
Carbon disulfide
18.4
5.0
ug/L
20.00
92
59-135
Carbon Tetrachloride
17.4
2.0
ug/L
20.00
87
72-142
Chlorobenzene
19.1
0.50
ug/L
20.00
95
78-119
Chloroethane
20.5
0.50
ug/L
20.00
102
57-142
Chloroform
18.8
0.50
ug/L
20.00
94
77-130
Chloromethane
17.2
0.50
ug/L
20.00
86
47-145
cis-1,2-Dichloroethylene
18.7
0.50
ug/L
20.00
93
76-141
cis-1,3-Dichloropropylene
19.3
0.50
ug/L
20.00
97
65-140
Dibromochloromethane
19.1
0.50
ug/L
20.00
96
75-134
Dibromomethane
19.2
2.0
ug/L
20.00
96
76-138
Ethylbenzene
18.4
0.50
ug/L
20.00
92
80-127
m,p-Xylenes
37.8
1.0
ug/L
40.00
94
77-133
Methyl Butyl Ketone (2-Hexanone)
19.3
5.0
ug/L
20.00
96
64-137
Methyl Ethyl Ketone (2-Butanone)
20.8
5.0
ug/L
20.00
104
71-134
Methyl Iodide
14.2
5.0
ug/L
20.00
71
70-130
Methyl Isobutyl Ketone
18.8
5.0
ug/L
20.00
94
69-134
Methylene Chloride
17.8
1.0
ug/L
20.00
89
73-131
o-Xylene
18.9
0.50
ug/L
20.00
95
78-128
Styrene
19.1
0.50
ug/L
20.00
96
78-129
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

1 0
Waypoint
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Spring
Attn: Alec Macbeth
231 Haywood Street Project No: 50-02
Asheville, NC 28801
Volatile Organic Compounds by GC/MS - Quality Control
Level II QC Report
3/27/20
Work Order: 0030270
Time Submitted: 3/19/2020 9:05:OOAM
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P000456 - 5030B
LCS (P000456-BSI)
Prepared &Analyzed: 03/23/20
Tetrachloroethylene
18.8
0.50
ug/L
20.00
94
80-129
Toluene
18.8
0.50
ug/L
20.00
94
76-131
trans-1,2-Dichloroethylene
18.6
0.50
ug/L
20.00
93
76-135
trans-1,3-Dichloropropylene
19.2
0.50
ug/L
20.00
96
67-140
trans-1,4-Dichloro-2-butene
16.3
10
ug/L
20.00
81
70-130
Trichloroethylene
18.8
0.50
ug/L
20.00
94
77-133
Trichlorofluoromethane
19.3
0.50
ug/L
20.00
97
62-148
Vinyl acetate
19.9
2.0
ug/L
20.00
100
34-167
Vinyl chloride
18.1
0.50
ug/L
20.00
90
57-141
Xylenes, total
56.7
1.5
ug/L
60.00
94
77-133
Surrogate:4-Bromofluorobenzene
50.5
ug/L
50.00
101
80-124
Surrogate: Dibromofluoromethane
50.6
ug/L
50.00
101
75-129
Surrogate: Toluene-d8
49.6
ug/L
50.00
99
77-123
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

1 0
Waypoint
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Spring
Attn: Alec Macbeth
231 Haywood Street Project No: 50-02
Asheville, NC 28801
Volatile Organic Compounds by GC/MS SIM - Quality Control
Level II QC Report
3/27/20
Work Order: 0030270
Time Submitted: 3/19/2020 9:05:OOAM
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P000385 - 5030B
Blank (P000385-BLK1) Prepared & Analyzed: 03/19/20
1,4-Dioxane BRL 2.0 ug/L
LCS (P000385-BS1) Prepared &Analyzed: 03/19/20
1,4-Dioxane 49.9 2.0 ug/L 50.00 100 55-145
Matrix Spike (P000385-MS1) Source: 0030270-01 Prepared & Analyzed: 03/19/20
1,4-Dioxane 51.9 2.0 ug/L 50.00 BRL 104 55-145
Matrix Spike Dup (P000385-MSD1) Source: 0030270-01 Prepared & Analyzed: 03/19/20
1,4-Dioxane 50.1 2.0 ug/L 50.00 BRL 100 55-145 4 30
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

1 0
Waypoint
ANALYTICAL
Anchor QEA of North Carolina, PLLC
Attn: Alec Macbeth
231 Haywood Street
Asheville, NC 28801
Total Metals - Quality Control
Analyte
Project: Jackson Cty Landfill 2020 Spring
Project No: 50-02
Level II QC Report
3/27/20
Work Order: 0030270
Time Submitted: 3/19/2020 9:05:OOAM
Reporting Spike Source %REC RPD
Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P000414 - 3005A
Blank (P000414-BLK1)
Prepared: 03/20/20 Analyzed: 03/23/20
Antimony
BRL
3.0
ug/L
Arsenic
BRL
1.0
ug/L
Barium
BRL
10
ug/L
Beryllium
BRL
1.0
ug/L
Cadmium
BRL
1.0
ug/L
Chromium
BRL
3.0
ug/L
Cobalt
BRL
2.0
ug/L
Copper
BRL
10
ug/L
Lead
BRL
1.0
ug/L
Nickel
BRL
3.0
ug/L
Selenium
BRL
5.0
ug/L
Silver
BRL
1.0
ug/L
Thallium
BRL
2.0
ug/L
Vanadium
BRL
5.0
ug/L
Zinc
BRL
20
ug/L
LCS (P000414-BSI)
Prepared: 03/20/20 Analyzed: 03/23/20
Antimony
102
3.0
ug/L
100.0
102
80-120
Arsenic
96.3
1.0
ug/L
100.0
96
80-120
Barium
96.6
10
ug/L
100.0
97
80-120
Beryllium
104
1.0
ug/L
100.0
104
80-120
Cadmium
99.3
1.0
ug/L
100.0
99
80-120
Chromium
98.8
3.0
ug/L
100.0
99
80-120
Cobalt
99.5
2.0
ug/L
100.0
99
80-120
Copper
98.1
10
ug/L
100.0
98
80-120
Lead
98.3
1.0
ug/L
100.0
98
80-120
Nickel
98.9
3.0
ug/L
100.0
99
80-120
Selenium
100
5.0
ug/L
100.0
100
80-120
Silver
100
1.0
ug/L
100.0
100
80-120
Thallium
96.3
2.0
ug/L
100.0
96
80-120
Vanadium
99.2
5.0
ug/L
100.0
99
80-120
Zinc
99.1
20
ug/L
100.0
99
80-120
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

1 0
Waypoint
ANALYTICAL
Anchor QEA of North Carolina, PLLC
Attn: Alec Macbeth
231 Haywood Street
Asheville, NC 28801
Total Metals - Quality Control
Analyte
Batch P000414 - 3005A
Project: Jackson Cty Landfill 2020 Spring
Project No: 50-02
Level II QC Report
3/27/20
Work Order: 0030270
Time Submitted: 3/19/2020 9:O5:OOAM
Reporting Spike Source %REC RPD
Result Limit Units Level Result %REC Limits RPD Limit Notes
Matrix Spike (P000414-MS1)
Source: 0030270-01
Prepared: 03/20/20 Analyzed: 03/23/20
Antimony
104
3.0
ug/L
100.0
BRL
104
75-125
Arsenic
98.9
1.0
ug/L
100.0
BRL
99
75-125
Barium
219
10
ug/L
100.0
117
103
75-125
Beryllium
96.5
1.0
ug/L
100.0
BRL
97
75-125
Cadmium
101
1.0
ug/L
100.0
BRL
101
75-125
Chromium
99.5
3.0
ug/L
100.0
BRL
99
75-125
Cobalt
234
2.0
ug/L
100.0
133
102
75-125
Copper
101
10
ug/L
100.0
BRL
101
75-125
Lead
99.1
1.0
ug/L
100.0
BRL
99
75-125
Nickel
114
3.0
ug/L
100.0
14.8
100
75-125
Selenium
104
5.0
ug/L
100.0
BRL
104
75-125
Silver
102
1.0
ug/L
100.0
BRL
102
75-125
Thallium
97.0
2.0
ug/L
100.0
BRL
97
75-125
Vanadium
101
5.0
ug/L
100.0
BRL
101
75-125
Zinc
105
20
ug/L
100.0
BRL
105
75-125
Matrix Spike Dup (P000414-MSD1)
Source: 0030270-01
Prepared:
03/20/20
Analyzed: 03/23/20
Antimony
103
3.0
ug/L
100.0
BRL
103
75-125
1
20
Arsenic
98.1
1.0
ug/L
100.0
BRL
98
75-125
0.9
20
Barium
216
10
ug/L
100.0
117
100
75-125
1
20
Beryllium
98.6
1.0
ug/L
100.0
BRL
99
75-125
2
20
Cadmium
100
1.0
ug/L
100.0
BRL
100
75-125
0.3
20
Chromium
98.4
3.0
ug/L
100.0
BRL
98
75-125
1
20
Cobalt
232
2.0
ug/L
100.0
133
100
75-125
0.8
20
Copper
100
10
ug/L
100.0
BRL
100
75-125
1
20
Lead
99.1
1.0
ug/L
100.0
BRL
99
75-125
0.007
20
Nickel
114
3.0
ug/L
100.0
14.8
99
75-125
0.2
20
Selenium
101
5.0
ug/L
100.0
BRL
101
75-125
3
20
Silver
101
1.0
ug/L
100.0
BRL
101
75-125
0.8
20
Thallium
98.0
2.0
ug/L
100.0
BRL
98
75-125
1
20
Vanadium
100
5.0
ug/L
100.0
BRL
100
75-125
0.7
20
Zinc
106
20
ug/L
100.0
BRL
106
75-125
0.7
20
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

1 0
Waypoint
ANALYTICAL
Anchor QEA of North Carolina, PLLC
Attn: Alec Macbeth
231 Haywood Street
Asheville, NC 28801
Total Metals - Quality Control
Analyte
Project: Jackson Cty Landfill 2020 Spring
Project No: 50-02
Level II QC Report
3/27/20
Work Order: 0030270
Time Submitted: 3/19/2020 9:05:OOAM
Reporting Spike Source %REC RPD
Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P000414 - 3005A
Post Spike (P000414-PS1)
Source: 0030270-01
Prepared:
03/20/20 Analyzed: 03/23/20
Antimony
102
ug/L
100.0
0.0610
102
80-120
Arsenic
97.6
ug/L
100.0
0.111
97
80-120
Barium
205
ug/L
100.0
117
88
80-120
Beryllium
102
ug/L
100.0
0.103
102
80-120
Cadmium
99.6
ug/L
100.0
0.162
99
80-120
Chromium
97.9
ug/L
100.0
0.294
98
80-120
Cobalt
231
ug/L
100.0
133
99
80-120
Copper
100
ug/L
100.0
0.825
99
80-120
Lead
97.6
ug/L
100.0
0.155
97
80-120
Nickel
113
ug/L
100.0
14.8
98
80-120
Selenium
102
ug/L
100.0
0.578
102
80-120
Silver
99.7
ug/L
100.0
0.0140
100
80-120
Thallium
95.7
ug/L
100.0
0.489
95
80-120
Vanadium
99.1
ug/L
100.0
-0.106
99
80-120
Zinc
109
ug/L
100.0
4.56
104
80-120
Batch P000418 - 7470A
Blank (P000418-BLK1) Prepared &Analyzed: 03/20/20
Mercury BRL 0.20 ug/L
LCS (P000418-BSI) Prepared &Analyzed: 03/20/20
Mercury 9.59 0.20 ug/L 9.375 102 80-120
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

1 0
Waypoint
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Spring
Attn: Alec Macbeth
231 Haywood Street Project No: 50-02
Asheville, NC 28801
Anions by Ion Chromatography - Quality Control
Level II QC Report
3/27/20
Work Order: 0030270
Time Submitted: 3/19/2020 9:05:OOAM
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P000403 - NO PREP
Blank (P000403-BLK1)
Prepared & Analyzed: 03/19/20
Chloride
BRL
1000
ug/L
Nitrate as N
BRL
200
ug/L
Sulfate
BRL
2000
ug/L
LCS (P000403-BSI)
Prepared &Analyzed: 03/19/20
Chloride
39800
1000
ug/L
40000 99
80-120
Nitrate as N
3920
210
ug/L
4000 98
80-120
Sulfate
39400
2100
ug/L
40000 98
80-120
Matrix Spike (P000403-MSI)
Source: 0030270-04
Prepared & Analyzed: 03/19/20
Chloride
46800
1000
ug/L
40000 1030 115
80-120
Nitrate as N
4630
210
ug/L
4000 152 112
80-120
Sulfate
46300
2100
ug/L
40000 555 114
80-120
Matrix Spike Dup (P000403-MSD1)
Source: 0030270-04
Prepared & Analyzed: 03/19/20
Chloride
41800
1000
ug/L
40000 1030 102
80-120 11 15
Nitrate as N
4070
210
ug/L
4000 152 98
80-120 13 15
Sulfate
41700
2100
ug/L
40000 555 103
80-120 10 15
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Level II QC Report
0int 3/27/2°
Waypo
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Spring Work Order: 0030270
Attn: Alec Macbeth Time Submitted: 3/19/2020 9:05:OOAM
231 Haywood Street Project No: 50-02
Asheville, NC 28801
General Chemistry Parameters - Quality Control
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P000387 - NO PREP
Blank (P000387-BLK1) Prepared: 03/19/20 Analyzed: 03/20/20
Total Alkalinity to pH 4.5 BRL 5000 ug/L
LCS (P000387-BS1) Prepared: 03/19/20 Analyzed: 03/20/20
Total Alkalinity to pH 4.5 249000 5000 ug/L 250000 100 90-110
Duplicate (P000387-DUP2) Source: 0030270-01 Prepared: 03/19/20 Analyzed: 03/20/20
Total Alkalinity to pH 4.5 118000 5000 ug/L 117000 1 20
Batch P000391 - NO PREP
Blank (P000391-BLK1)
Prepared &Analyzed: 03/19/20
Ferrous Iron
BRL 200 ug/L
LCS (P000391-BSI)
Prepared &Analyzed: 03/19/20
Ferrous Iron
1830 200 ug/L
2000 92 90-110
Matrix Spike (P000391-MSI)
Source: 0030270-02
Prepared & Analyzed: 03/19/20
Ferrous Iron
1810 200 ug/L
2000 59.0 88 80-120
Matrix Spike Dup (P000391-MSD1)
Source: 0030270-02
Prepared & Analyzed: 03/19/20
Ferrous Iron
1840 200 ug/L
2000 59.0 89 80-120 2 20
Batch P000401 - NO PREP
Blank (P000401-BLK1)
Prepared &Analyzed: 03/19/20
Biochemical Oxygen Demand
BRL 2000 ug/L
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Level II QC Report
0int 3/27/2°
Waypo
ANALYTICAL
Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Spring Work Order: 0030270
Attn: Alec Macbeth Time Submitted: 3/19/2020 9:05:OOAM
231 Haywood Street Project No: 50-02
Asheville, NC 28801
General Chemistry Parameters - Quality Control
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P000401 - NO PREP
LCS (P000401-BSI)
Prepared &Analyzed: 03/19/20
Biochemical Oxygen Demand
180000
2000
ug/L
198000 91 84.6-115.4
Batch P000429 - SM4500-S C
Blank (P000429-BLK1)
Prepared & Analyzed: 03/20/20
Sulfide
BRL
2000
ug/L
LCS (P000429-BS1)
Prepared &Analyzed: 03/20/20
Sulfide
7100
2000
ug/L
10000 71 70-130
Batch P000457 - NO PREP
Blank (P000457-BLK1)
Prepared & Analyzed: 03/23/20
Chemical Oxygen Demand
BRL
50000
ug/L
LCS (P000457-BSI)
Prepared &Analyzed: 03/23/20
Chemical Oxygen Demand
510000
50000
ug/L
500000 102 90-110
Matrix Spike (P000457-MS1)
Source: 0030270-04
Prepared & Analyzed: 03/23/20
Chemical Oxygen Demand
492000
50000
ug/L
500000 BRL 98 80-120
Matrix Spike Dup (P000457-MSD1)
Source: 0030270-04
Prepared & Analyzed: 03/23/20
Chemical Oxygen Demand
486000
50000
ug/L
500000 BRL 97 80-120 1 20
Batch P000503 - NO PREP
Blank (P000503-BLK1) Prepared & Analyzed: 03/25/20
Total Alkalinity to pH 4.5 BRL 5000 ug/L
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

1 0
Waypoint
ANALYTICAL
Anchor QEA of North Carolina, PLLC
Attn: Alec Macbeth
231 Haywood Street
Asheville, NC 28801
General Chemistry Parameters - Quality Control
Analyte
Project: Jackson Cty Landfill 2020 Spring
Project No: 50-02
Level II QC Report
3/27/20
Work Order: 0030270
Time Submitted: 3/19/2020 9:05:OOAM
Reporting Spike Source %REC RPD
Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P000503 - NO PREP
LCS (P000503-BSI) Prepared &Analyzed: 03/25/20
Total Alkalinity to pH 4.5 249000 5000 ug/L 250000 99 90-110
Duplicate (P000503-DUP1) Source: 0030270-04 Prepared & Analyzed: 03/25/20
Total Alkalinity to pH 4.5 24200 5000 ug/L 23600 3 20
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Sample Extraction Data
Prep Method: SM4500-S C
Lab Number
Batch
Initial
Final
Date/Time
0030270-01
P000429
200
mL
200 mL
03/20/20 10:55
0030270-02
P000429
200
mL
200 mL
03/20/20 10:55
0030270-03
P000429
200
mL
200 mL
03/20/20 10:55
0030270-04
P0O0429
200
mL
200 mL
03/20/20 10:55
Prep Method: 3005A
Lab Number
Batch
Initial
Final
Date/Time
0030270-01
P000414
50
mL
50 mL
03/20/20 8:27
0030270-02
P000414
50
mL
50 mL
03/20/20 8:27
0030270-03
P000414
50
mL
50 mL
03/20/20 8:27
0030270-04
P0O0414
50
mL
50 mL
03/20/20 8:27
Prep Method: 7470A
Lab Number
Batch
Initial
Final
Date/Time
0030270-01
P000418
20
mL
30 mL
03/20/20 10:24
0030270-02
P000418
20
mL
30 mL
03/20/20 10:24
0030270-03
P000418
20
mL
30 mL
03/20/20 10:24
0030270-04
P0O0418
20
mL
30 mL
03/20/20 10:24
Prep Method: 5030E
Lab Number
Batch
Initial
Final
Date/Time
0030270-01
P000456
10
mL
10 mL
03/23/20 10:00
0030270-02
P000456
10
mL
10 mL
03/23/20 10:00
0030270-03
P000456
10
mL
10 mL
03/23/20 10:00
0030270-04
P0O0456
10
mL
10 mL
03/23/20 10:00
0030270-05
P0O0456
10
mL
10 mL
03/23/20 10:00
0030270-06
P0O0456
10
mL
10 mL
03/23/20 10:00
Prep Method: 5030E
Lab Number
Batch
Initial
Final
Date/Time
0030270-01
P000385
5
mL
5 mL
03/19/20 12:49
0030270-02
P0O0385
5
mL
5 mL
03/19/20 12:49
0030270-03
P0O0385
5
mL
5 mL
03/19/20 12:49
0030270-04
P0O0385
5
mL
5 mL
03/19/20 12:49
0030270-05
P000385
5
mL
5 mL
03/19/20 12:49
The following analyses were subcontracted to Pace Analytical Gulf Coast
Lab Number Analysis
0030270-01
TOC (Sub)
0030270-02
TOC (Sub)
0030270-03
TOC (Sub)
0030270-04
TOC (Sub)
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

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ACCESS
ANALYTICAL, INC.
ANALYTICAL REPORT
CLIENT
Waypoint Analytical
PO BOX 240543
Charlotte, NC 28224
ATTENTION
Angela Overcash
PROJECTID
0030270
LABORATORY REPORT NUMBER
220032007
DATE
03/24/2020
Primary Data Review By
l
Authorized Signature
PLEASE NOTE:
Secondary Data Review By
Ashley B. Amick
Project Manager, Access Analytical, Inc.
[e-mail]
- Unless otherwise noted, all analysis on this report performed at Pace Analytical Gulf Coast, 7979
Innovation Park Dr., Baton Rouge, LA 70820.
Pace Gulf Coast is SCDHEC certified laboratory # 73006, NCDENR certified lab # 618, GA certified lab #
LA-01955, NELAP certified laboratory # 01955
- Local support services for this project are provided by Access Analytical, Inc.. Access Analytical is a
representative of Pace Guld Coast serving clients in the SC/NC/GA areas. All questions regarding this report
should be directed to your local Access Analytical representative at 803.781.4243 or toll free at 888.315.4243.
Lab Report#: 220032007 Page 1 of 11

(��a'ceAnalyfical
LELAP CERTIFICATE NUMBER: 01955
DOD -FLAP ACCREDITATION NUMBER: 74960
ANALYTICAL RESULTS
Deliver To
Angela Overcash
Waypoint Analytical
PO BOX 240543
Charlotte, NC 28224
706-529-6364
PERFORMED BY
Pace Analytical Gulf Coast
7979 Innovation Park Dr.
Baton Rouge, LA 70820
[phone]
Report Date 03/24/2020
Report
I�11 �1191�11II 111111111IIII
Project 0030270
Additional Recipients
NONE
ISO
17025
"LA $�
Tcfting
DOD NAP
Lab Report#: 220032007 Page 2 of 11

- ,,.PaC2,�r1<7�ytICa1
Report#: 220032007
Project ID: 0030270 Report Date: 03/24/2020
Laboratory Endorsement
Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized
agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this
retention period the samples will be disposed in accordance with Pace Gulf Coast's Standard Operating Procedures.
Common Abbreviations that may be Utilized in this Report
ND Indicates the result was Not Detected at the specified reporting limit
NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030
DO Indicates the result was Diluted Out
MI Indicates the result was subject to Matrix Interference
TNTC Indicates the result was Too Numerous To Count
SUBC Indicates the analysis was Sub -Contracted
FLD Indicates the analysis was performed in the Field
DL Detection Limit
LOD Limit of Detection
LOQ Limit of Quantitation
RE Re -analysis
CIF HPLC or GC Confirmation
00:01 Reported as a time equivalent to 12:00 AM
Reporting Flags that may be Utilized in this Report
J or I Indicates the result is between the MDL and LOQ
J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria
U Indicates the compound was analyzed for but not detected
B or V Indicates the analyte was detected in the associated Method Blank
Q Indicates a non -compliant QC Result (See Q Flag Application Report)
Indicates a non -compliant or not applicable QC recovery or RPD — see narrative
E Organics - The result is estimated because it exceeded the instrument calibration range
E Metals - % diference for the serial dilution is > 10%
L Reporting Limits adjusted to meet risk -based limit.
P RPD between primary and confirmation result is greater than 40
DL Diluted analysis — when appended to Client Sample ID
Sample receipt at Pace Gulf Coast is documented through the attached chain of custody. In accordance with NELAC, this report shall be
reproduced only in full and with the written permission of Pace Gulf Coast. The results contained within this report relate only to the samples
reported. The documented results are presented within this report.
This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results
contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited.
I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and
Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this
hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee,
as verified by the following signature.
Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if
applicable.
Authorized Signature
Pace Gulf Coast Report 220032007
Lab Report#: 220032007 Page 3 of 11

Report#:
- CBAfir3ljl�ICc31
Project ID:
220032007
0030270
Certifications
Report Date: 03/24/2020
Certification
Certification Number
DOD ELAP
74960
Alabama
01955
Arkansas
88-0655
Colorado
01955
Delaware
01955
Florida
E87854
Georgia
01955
Hawaii
01955
Idaho
01955
Illinois
200048
Indiana
01955
Kansas
E-10354
Kentucky
95
Louisiana
01955
Maryland
01955
Massachusetts
01955
Michigan
01955
Mississippi
01955
Missouri
01955
Montana
N/A
Nebraska
01955
New Mexico
01955
North Carolina
618
North Dakota
R-195
Oklahoma
9403
South Carolina
73006001
South Dakota
01955
Tennessee
01955
Texas
T104704178
Vermont
01955
Virginia
460215
Washin ton
C929
USDA Soil Permit
P330-16-00234
Lab Report#: 220032007 Page 4 of 11

Report#: 220032007
�a�eanalyr�car
Project ID: 0030270 Report Date: 03/24/2020
Case Narrative
Client: Access Analytical Report: 220032007
Pace Analytical Gulf Coast received and analyzed the sample(s) listed
on the Report Sample Summary page of this report. Receipt of the sample(s) is documented
by the attached chain of custody. This applies only to the sample(s) listed in this report.
No sample integrity or quality control exceptions were identified unless noted below.
No anomalies were found for the analyzed sample(s).
Lab Report#: 220032007 Page 5 of 11

,' ..-�aee�4rralytic�l
LAB ID Client ID
Report#: 220032007
Project ID: 0030270
22003200701
MW-01-20200318
22003200702
MW-02-20200318
22003200703
MW-05R-20200318
22003200704
MW-06-20200318
Report Date: 03/24/2020
Sample Summary
Matrix Collect Date/Time
Water
03/18/202011:39
Water
03/18/2020 08:55
Water
03/18/202012:45
Water
03/18/202010:13
Receive Date(Time
03/20/2020 09:26
03/20/2020 09:26
03/20/2020 09:26
03/20/2020 09:26
Lab Report#: 220032007 Page 6 of 11

:' ..-Pace,�ru�lyfi�al
Report#: 220032007
Project ID: 0030270
Report Date: 03/24/2020
Summary of Compounds Detected
Collect Date
MW-01-20200318
Receive Date
03/18/2020 11:39
03/20/2020 09:26
LAB ID
Matrix
22003200701
Water
111
SM 5310 B-2011
CAS# Parameter
Result
DL
LOQ
Units
C-012 Total Organic Carbon
9.07
0.600
4.00
mg/L
Collect Date
03/18/2020 08:55
LAB ID
22003200702
MW-02-20200318
Receive Date
03/20/2020 09:26
Matrix
Water
SM 5310 B-2011
CAS# Parameter
Result
DL
LOQ
Units
C-012 Total Organic Carbon
2.97
0.300
2.00
mg/L
Collect Date 03/18/2020 12:45 LAB ID 22003200703
MW-05R-20200318
Receive Date 03/20/2020 09:26 Matrix Water
SM 5310 B-2011
CAS# Parameter
Result
DL
LOQ
Units
C-012 Total Organic Carbon
20.9
0.300
2.00
mglL
Collect Date 03/18/2020 10:13
LAB ID
22003200704
MW-06-20200318
Receive Date 03/20/2020 09:26
Matrix
Water
SM 5310 B-2011
CAS# Parameter
Result
DL
LOQ
Units
C-012 Total Organic Carbon
3.34
0.300
2.00
mg/L
Lab Report#: 220032007 Page 7 of 11

-f r7Ce��fIr7�7Cr?/
MW-01-20200318
Report#: 220032007
Project ID: 0030270 Report Date: 03/24/2020
Sample Results
Collect Date 03/18/2020 11:39 LAB ID 22003200701
Receive Date 03/20/2020 09:26 Matrix Water
i Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch
NA NA 2 03/23/202014:40 PLH 680226
CAS# Parameter
C-012 Total Organic Carbon
MW-02-20200318
Collect Date 03/18/2020 08:55
Receive Date 03/20/2020 09:26
Result
DL
LOQ
Units
9.07
0.600
4.00
mg/L
LAB ID 22003200702
Matrix Water
Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch
NA NA 1 03/21/202016:48 PLH 680165
CAS#
Parameter
Result
DL
LOQ
Units
C-012
Total Organic Carbon
2.97
0.300
2.00
mg/L
W-05R-20200318 Collect Date 03/18/2020 12:45 LAB ID 22003200703
Receive Date 03/20/2020 09:26 Matrix Water
SM 5310 B-2011
Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch
NA NA NA 1 03121/202017:04 PLH 680165
CAS# Parameter
C-012 Total Organic Carbon
MW-06-20200318
L
SM 5310 B-2011
Collect Date 03/18/2020 10:13
Receive Date 03/20/2020 09:26
Result
DL
LOQ
Units
20A
0.300
2.00
mg/L
LAB ID 22003200704
Matrix Water
Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch
NA NA NA 1 03/21/202017:21 PLH 680165
CAS# Parameter Result DL LOQ Units
C-012 Total Organic Carbon 3.34 0.300 2.00 mg/L
Lab Report#: 220032007 Page 8 of 11

Report#: 220032007
r CF.fa17�1}+hC�?I
Project ID: 0030270 Report Date: 03/24/2020
General Chemistry QC Summary
Analytical Batch Client ID
MB680165
LCS680165
680165 LAB ID
2023698
2023699
Sample Type
MB
LCS
Prep Date
NA
NA
Analysis Date
03/21/2020 13:50
03/21/2020 13:07
Matrix
Water
Water
SM 5310 B-2011
Units
mg/L
Spike
Result
%R
Control
Result
DL
Added
Limits%R
Total Organic Carbon C-012
0.3000
0.300
50.0
J 51.0
102
90 - 110
Analytical Batch Client ID
MB680226
LCS680226
680226 LAB ID
2023886
2023887
Sample Type
MB
LCS
Prep Date
NA
NA
Analysis Date
03/23/2020 12:24
03/23/2020 11:26
Matrix
Water
Water
SM 5310 B-2011
Units
mg/L
Spikel
Result
%R
Control
Result
DL
Added
Limits%R
Total Organic Carbon C-012
0.3000
0.300
50.0
49.3
99
1 90 - 110
Lab Report#: 220032007 Page 9 of 11

11
III
U
V
a
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O N
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z
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COd T vRi N G1 O �
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Lab Report# 220032007 Page 10 of 11

ac /Inalytical'
SAMPLE RECEIVING CHECKLIST ININIINI
2
IINIIII�ININIINII
2 0 0 3 2
II II
0 0 7
SAMPLE DELIVERY GROUP
220032007
CHECKLIST
YES
NO
Client PM DLH
Transport Method
Samples received with proper thermal preservation?
R
114565
- Access Analytical
FEDEX
Radioactivity is <1600 cpm? If no, record cpm value in notes section.
COC relinquished and complete (including samplelDs, collect times, and sampler)?
❑v
❑�
❑
❑
Profile Number
Received By
80251
Savage, Tiffany R
All containers received in good condition and within hold time?
All sample labels and containers received match the chain of custody?
❑v
0
❑
❑
Dine Item(s)
%ceive Date(s)
1 - Water
03I2U20
Preservative added to any containers?
❑
Q
If received, was headspace for VOC water containers < 6mm?
R
❑
Samples collected in containers provided by Pace Gulf Coast?
❑
0
COOLERS
DISCREPANCIES
LAB PRESERVATIONS
Airbill Thermometer lot E34
Temp °C
None
None
7700-6408-1489
0.1
NOTES
Revision 1.6
Page 1 of 1
Lab Report#: 220032007 Page 11 of 11

(D
Waypoi nt
ANALYTICAL
Anchor QEA of North Carolina, PLLC
Alec Macbeth
231 Haywood Street
Asheville, NC 28801
NC Certification No. 402
NC Drinking Water Cert No. 37735
SC Certification No. 99012
Project: Jackson Cty Landfill 2020 Spring
Project No.: 50-02
Lab Submittal Date: 03/19/2020
Work Order: 0030271
Case Narrative
4/1 /20 12:27
This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample
Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed
according to the referenced methods.
Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case
narrative.
Narrative Notes:
524.2 analysis was subcontracted to Pace Analytycal. Laboratory report is attached with a total page
count of 14 pages.
Please call if you have any questions relating to this analytical report.
Respectfully,
WAYPOINT ANALYTICAL
Angela D. Overcash
Senior Project Manager
Data Qualifiers Key Reference:
BRL Below Reporting Limit
MDL Method Detection Limit
RPD Relative Percent Difference
* Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and
reporting limit indicated with a J.
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 - Fax: [phone]

i 0
Waypoint.
ANALYTICAL
Sample Receipt Summary
04/01/2020
Work Order: 0030271
Client Sample ID Lab Sample ID Matrix Date/Time Sampled Date/Time Received
DW-01-20200318
0030271-01 Drinking Water 03/18/20 12:25 03/19/20 9:05
Samples were received in good condition at 1.5 degrees C unless otherwise noted.
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical,
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

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,Pace Analytical F
f www.pacelabs,com
i
March 31, 2020
Robbi A. Jones
Prism Laboratories, Inc.
P.O. Box 240543
Charlotte, NC 28224
RE: Project: 0030271
Pace Project No.: 92470770
Dear Robbi Jones:
Pace Analytical Services, LLC
9800 Kincey Ave. Suite t00
Huntersville, NC 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on March 24, 2020. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Ormond Beach
If you have any questions concerning this report, please feel free to contact me_
Sincerely,
`-
Matthew Brainard
[e-mail]
[phone]
Project Manager
Enclosures
cc: Angela Overcash, Prism
F ACCR�
2` v REPORT OF LABORATORY ANALYSIS
TNI ; This report shall not be reproduced, except in full,
f without the written consent of Pace Analytical Services, LLC
7RQRA�g4
Page 1 of 11

ace Analytical
fi www.pacelabs.com
CERTIFICATIONS
Project: 0030271
Pace Project No.: 92470770
Pace Analytical Services, LLC
9800 Kincey Ave. Suite100
Huntersville, NC 28078
[phone]
Pace Analytical Services Ormond Beach
8 East Tower Circle, Ormond Beach, FL 32174
Missouri Certification #: 236
Alaska DEC- CS/UST/LUST
Montana Certification #: Cert 0074
Alabama Certification #: 41320
Nebraska Certification: NE-OS-28-14
Arizona Certification# AZO819
New Hampshire Certification #: 2958
Colorado Certification: FL NELAC Reciprocity
New Jersey Certification #: FL022
Connecticut Certification #: PH-0216
New York Certification #: 11608
Delaware Certification: FL NELAC Reciprocity
North Carolina Environmental Certificate #: 667
Florida Certification #: E83079
North Carolina Certification #: 12710
Georgia Certification #: 955
North Dakota Certification #: R-216
Guam Certification: FL NELAC Reciprocity
Oklahoma Certification #: D9947
Hawaii Certification: FL NELAC Reciprocity
Pennsylvania Certification #: 68-00547
Illinois Certification #: 200068
Puerto Rico Certification #: FLO1264
Indiana Certification: FL NELAC Reciprocity
South Carolina Certification: #96042001
Kansas Certification #: E-10383
Tennessee Certification #: TN02974
Kentucky Certification #: 90050
Texas Certification: FL NELAC Reciprocity
Louisiana Certification #: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Virginia Environmental Certification #: 460165
Maryland Certification: #346
West Virginia Certification #: 9962C
Michigan Certification #: 9911
Wisconsin Certification #: 399079670
Mississippi Certification: FL NELAC Reciprocity
Wyoming (EPA Region 8): FL NELAC Reciprocity
REPORT OF LABORATORY ANALYSIS
Tn!s rep:=t shall ne! be re:pnaduceo, xcetY in full,
w ihou! thre rd!er conscn! of Pace AnaMical Services. LLC Page 2 of 11

XPaceAnalXical e
' WYh4.�t3iY17�S.Ce}II
Project: 0030271
Pace Project No.: 92470770
Lab ID Sample ID
92470770001 0030271-01
PASI-O = Pace Analytical Services - Ormond Beach
SAMPLE ANALYTE COUNT
Method
EPA 524.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC,
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 26078
(704)8759092
Analytes
Analysts Reported Laboratory
JLR 24 PASI-O
Page 3 of 11

2aceAnalyfical
Y www.pacolabs.com
ANALYTICAL RESULTS
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: 0030271
Pace Project No.: 92470770
Sample: 0030271-01
Lab ID: 92470770001
Collected: 03118/20 12:25
Received: 03/24/20 09:09 Matrix: Water
Parameters
Results
Units
Report Limit
DF
Prepared Analyzed
CAS No. Qual
524.2 MSV
Analytical Method:
EPA524.2
Pace Analytical
Services -
Ormond Beach
Benzene
NO
mg/L
0.00050
1
03/30/20 22:37
71-43-2
Carbon tetrachloride
NO
mgiL
0.00050
1
03/30/20 22:37
56-23-5
Chlorobenzene
NO
mg/L
0.00050
1
03/30/20 22:37
108-90-7
1,2-Dichlorobenzene
NO
mg/L
0.00050
1
03/30/20 22:37
95-50-1
1,4-Dichlorobenzene
NO
mg/L
0.00050
1
03/30/20 22:37
106-46-7
1,2-Dichloroethane
NO
mg/L
0,00050
1
03/30/20 22:37
107-06-2
1,1-Dichloroethene
NO
mg/L
0.00050
1
03/30/20 22:37
75-35-4
cis-1,2-Dichloroethene
NO
mg/L
0.00050
1
03/30/20 22:37
156-59-2
trans-1,2-Dichloroethene
NO
mg/L
0.00050
1
03/30/20 22:37
156-60-5
1,2-Dichloropropane
NO
mg/L
0.00050
1
03/30/20 22:37
78-87-5
Ethylbenzene
NO
mg/L
0.00050
1
03/30/20 22:37
100-41-4
Methylene Chloride
NO
mg/L
0.0010
1
03/30/20 22:37
75-09-2
Styrene
NO
mg/L
0.00050
1
03/30/20 22:37
100-42-5
Tetrachloroethene
NO
mg/L
0.00050
1
03/30/20 22:37
127-18-4
Toluene
NO
mg/L
0.00050
1
03130/2022:37
108-88-3
1,2,4-Trichlorobenzene
NO
mg/L
0.00050
1
03/30/20 22:37
120-82-1
1,1,1-Trichloroethane
NO
mg/L
0.00050
1
0313012022:37
71-55-6
1,1,2-Trichloroethane
NO
mg/L
0.00050
1
03/30/20 22:37
79-00-5
Trichloroethene
NO
mg/L
0.00050
1
03/30/20 22:37
79-01-6
Vinyl chloride
NO
mg/L
0.00050
1
03/30/20 22:37
75-01-4
Xylene (Total)
NO
mg/L
0.0010
1
03/30/20 22:37
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
100
%
70-130
1
03/30/20 22:37
460-00-4
Toluene-d8 (S)
93
%
70-130
1
03/30/20 22:37
2037-26-5
1,2-Dichloroethane-d4(S)
06
%
70-130
1
03/3012022:37
17060-07-0
Date: 0313!12020 04:13 PNI
REPORT OF LABORATORY ANALYSIS
This repert shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC
Page 4 c1 11

/*PaceAnalytical
www.pat:elabs,corn
r
f
Project: 0030271
Pace Project No.. 92470770
QC Batch: 621879
QC Batch Method: EPA 524.2
Associated Lab Samples: 92470770001
METHOD BLANK: 3379101
Associated Lab Samples: 92470770001
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 524.2
Analysis Description: 524.2 MSV
Laboratory: Pace Analytical Services - Ormond Beach
Matrix: Water
Parameter
Units
Blank
Result
Reporting
Limit
Analyzed Qualifiers
1,1,1-Trichloroethane
mg/L
ND
0.00050
03/30120 22:15
1,1,2-Trichloroethane
mg/L
ND
0.00050
03/30/20 22:15
1,1-Dichloroethene
mg/L
ND
0.00050
03/30/20 22:15
1,2,4-Trichlorobenzene
mg1L
ND
0.00050
03/30/20 22:15
1,2-Dichlorobenzene
mg/L
ND
0.00050
03/30/20 22:15
1,2-Dichloroethene
mg/L
ND
0.00050
03/3012022:15
1,2-Dichloropropane
mg/L
ND
0.00050
03130/2022:15
1,4-Dichlorobenzene
mg/L
ND
0.00050
031=20 22:15
Benzene
mg/L
ND
0.00050
03/30/20 22:15
Carbon tetrachloride
mg/L
ND
0.00050
03/30/20 22:15
Chlorobenzene
mg/L
ND
0.00050
03/30/20 22:15
cis-1,2-Dichloroethene
mg/L
ND
0.00050
03/3012022:15
Ethylbenzene
mg/L
ND
0.00050
03/30/20 22:15
Methylene Chloride
mg/L
ND
0.0010
03/30/20 22:15
Styrene
mg/L
ND
0,00050
03/30/20 22:15
Tetrachloroethene
mg/L
ND
0.00050
03/30/20 22:15
Toluene
mg/L
ND
O.DO050
03/30/20 22:15
trans- 1,2-Dichloroethene
mg/L
ND
0.00050
03/30/20 22:15
Trichloroethene
mg/L
ND
0.00050
03/30/20 22:15
Vinyl chloride
mg/L
ND
0.00050
03/30120 22:15
Xylene (Total)
mg/L
ND
00010
03/30/20 22:15
1,2-Dichloroethane-d4 (S)
%
107
70-130
03/36/20 22:15
4-Bromofluorobenzene (S)
%
97
70-130
03130/20 22:15
Toluene-d8 (S)
%
96
70-130
03/30/20 22:15
LABORATORY CONTROL SAMPLE & LCSD:
3379102
3379103
Spike
LCS
LCSD
LCS
LCSD
% Rec
Max
Parameter
Units
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qualifiers
1,1,1-Trichloroethane
mg/I-
001
0.0088
0.0084
88
84
70-130
4
20
1,1,2-Trichloroethane
mg/L
0,01
00097
0 010
97
100
70-130
4
20
1,i-Dichloroethene
rng/L
0.01
0.0081
0.0086
81
86
70-130
5
20
1,2,4-Trichlorobenzene
mg/L
0.01
0.0086
0.0092
86
92
70-130
8
20
1,2-Dictiloroberizene
n g/L
001
00096
00098
96
98
70-130
3
20
1,2-Dichloroethane
ing/L
001
00082
0.0080
82
80
70-130
2
20
1,2-Dichloropropane
mg/L
001
0.0084
0,0084
84
84
70-130
0
20
1,4-Dichlorobenzene
mgll.
001
00090
0.0093
90
93
70-130
3
20
Benzene
mg/L
0 01
0.0089
0.0086
89
86
70-130
4
20
Carbon tetrachloride
mg/L
0 01
0.0087
00086
87
86
70-130
1
20
Chlorobenzene
nig/L
0 01
00092
0,0094
92
94
70-130
2
20
Results presented on this page are m the units indicated by the "Units" column except •.vhere an alternate unit is presented to the right or the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Dale: 03/3112020 04:13 PM without the wrilten consent of Pace Analytical Services, LLC Page 5 of 11

t'�GeAn*tical
www.pacelabs,ctxn
1
QUALITY CONTROL DATA
Project: 0030271
Pace Project No.: 92470770
LABORATORY CONTROL SAMPLE & LCSD:
3379102
3379103
Spike
LCS
LCSD
LCS
LCSD
% Rec
Parameter
Units
Conc.
Result
Result
% Rec
% Rec
Limits
cis- 1,2-Dichloroethene
mg/L
0.01
0.0083
0.0083
83
83
70-130
Ethylbenzene
mg1L
0.01
0.0094
0.0098
94
98
70-130
Methylene Chloride
mg/L
0.01
0.0075
0.0079
75
79
70-130
Styrene
mg/L
0.01
0.0092
0.0096
92
96
70-130
Tetrachloroethene
mg/L
0.01
0.0093
0.0099
93
99
70-130
Toluene
mg/L
0.01
0.0093
0.0097
93
97
70-130
trans- 1,2-Dichloroethene
mg/L
0.01
0.0081
0.0081
81
81
70-130
Trichloroethene
mg/L
0.01
0.0081
0.0084
81
84
70-130
Vinyl chloride
mg&
0.01
0.0092
0.0092
92
92
70-130
Xylene (Total)
mg/L
0.03
0 028
0.029
95
98
70-130
1,2-Dichloroethane-d4 (S)
%
103
103
70-130
4-Bromofluorobenzene (S)
%
100
103
70-130
Toluene-d8 (S)
%
93
96
70-130
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
RPD
Max
RPD Qualifiers
1
20
5
20
5
20
4
20
6
20
4
20
1
20
4
20
1
20
3
20
Results presented on this page are in the units indicated by the "Units- column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report s7a2H not to reproduced. except in. full,
Date: 03/31/2020 04:13 PM without the written consent of Pace Analytical Services, LLC.
Page 6 of 11

_ ceAnalXical R
www.pacelabs.com
QUALIFIERS
Project: 0030271
Pace Project No.: 92470770
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC -Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
Pace Analytical Services, LLC
9800 Kincey Ave. Suile 100
Hunlersville, NC 28078
[phone]
PQL- Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenyla mine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNf accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
REPORT OF LABORATORY ANALYSIS
This repo;t shall not be reproduced except it rLll.
Date: 03?3112020 04:13 PM w shout the written censer:! of Pace Ana1vtocal Scrv:ces LL Page 7 of 11

aceAnal}llcal
www.pacelabs.com
Project: OL ovc f .
Pace Project No.: 92470770
Lab ID Sample ID
92470770001 0030271-01
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
QC Batch Method QC Batch Analytical Method
EPA 524.2 621879
REPORT OF LABORATORY ANALYSIS
Analytical
Batch
This report shall not be reproduced, except in full,
Date: 0313 112020 04: 13 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 11

Document Name: Document Revised: February 7, 2018
o Sample Condition Upon RecelptlSCUR) Page 1 of 2
iICL'faflc�ilCill Document No.: Issuing Authority:
F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville Eden[:] Greenwood ❑
Huntersville 0"' Raleigh❑ Mechanicsville❑
Client Name:
WO# • 92470770
Project q:
Courler: ❑Fed Ex ❑UPS ❑USPS
❑Client
II
III
lull
III
❑ Commercial ❑Pace []Other:_IIIIIIOther:_
92470770
Custody Seal Present? ❑Yes ❑No Seals Intact? oyes
No
Date/Initlish Person Examining Contents:
Packing MBterlak ❑Bubble Wrap ❑Bubble Bags ❑None
❑ Other Hlologlcal Tissue Frozen?
Thermometer: ,• ❑Yes ❑No ❑N/A
❑IR Gun ID: 92TO60 Type of Ice; ❑Wet []Blue [:]None
Cooler Temp ('Cl.- Correction Factor: Add/Subtract (°C)
0.0
Temp should be above freezing to 6'C
Cooler Temp Corrected ('C): ''
❑Samples out of temp criteria. Samples on ice, cooling process
has begun
USDA Regulated Soil (❑ N/A, water sample)
Did samples oiiglaatc In a quarantine zone within the United States: CA, NY, or SC
(check maps)? Old samples originate from a foreign source tinternaIlona lly,
F—Ivn- lift.
Tactudirr Hawaii and puerrnmm-P 71s'rs I—I.L'o
Corn ments/Dlscrepa n cyi
Chain of Custody Present? -'
E)Yes
ON.
L]N/A
1.
Samples Arrived within Hold Time?
Yes
No
NIA
2.
;Short Hold Time Analysis (<72Fir, ?
❑Yes
QNo
N/A
3.
Rush Turn Around Time Requested?
❑Ycs
of -to
❑NIA
4.
Sufficient Volume? !
❑Yes
❑No
FIN/A
5.
Correct Containers Used?
"Pace Containers Used?
❑Yes
❑Yes
❑No
[]No
❑N/A
❑NIA
6.
Containers Intact?
OYes
DNo
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
❑No
❑rl/A
1 R. `
Sample Labels Match COC?
Dyes
[]NO
❑N/A
9.
-Includes Date/Time/(D/AnalVsls Matrix:
Headspace in VOA Vials 1�5-6mm)7
❑Yes
[:IN.
❑N/A
10,
Trip Blank Present?
I Trip Blank Custody Seals Present?
❑Yes
Dyes
❑Nc
Q No
❑N/A
N/A
11,
COMMENTS/SAMPLE 015CREPANCY Field Data Required? ❑Yes []NO
CLIENT NOTIFICATION/RESOLUTION
Person contacted: i DateJTime:
I
Project Manager SCURF Review:
Project Manager SRF Review:
Lot ID of split containers:
Date:
Date:
Page 9 of 11

Document Name:
Document Revised: February 7, 2018
:fGt Analytical a
Sample Condition Upon Recetpt(SCUR)
Fa e 1 of 2
Document No.;
Issuing Authority:
F-CAR-CS-033•Rev.06
Pare Carolinas quality Office
'Check mark top half of box If pH and/or dechlorination is Project N verified and within the acceptance range for preservation O ; 9247077o
samples. PM: MWB Due Date: W03/31/20
ExEeptlons: VOA, Coliform, TOC, Oil and Grease, DRO/801S (water) DOC, LLHg CLIENT: 92—Pr ism
.'*Bottom half of box Is to list number of bottle
o
a
2
a
v
=
v
Nf
m
A
z
7
v
d
,
ar
Z
ry
"
v
x
U
=
Z_'"
a
y
¢
2
z
m
a
z
Z
°'
?
z
n
c
n
c
7
n
c
a
O
utmu
=
x
ZoM
RO
_
E
y
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U
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'
>
M
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.y
N
n
�ya
d
E
a
E
d
E
n
`w
asn
E
E
d
E
—
E
o
a
E
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E
6
E
E
Q'
E
-C
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O
f
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p
E
O
aE
O
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7
a
L.�
is
�'
9
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rn
rn
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E
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E
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E
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ga
7
7
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7
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rl
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�J
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l7
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l7
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l7
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✓i
Cr
]
\
\
\NN
7
pH Adjustment Log for Preserved Samples j
5ample to I Type of Preservative pll upon receipt Date preservation adjusted 71me preservation Amount of Preservative Lot d 4
— I --
adjusted added
Note: rNhenever there Is a dis Crepaccy afieaing North Carolina compliance samples, a copy of this :'onu will be sent io the North Carolina DEHNR CertlnCaLon Office li e
Out of hod, Incorrect Preservative, out o'temp, incorrect containers
Page 10 of 11

AMAIN 1 ICAI_
SUBCONTRACT ORDER
Certificittion: NIELAC _ IUSACE
Waypoint Analytical NC_ Sc— Othcr
-
0030271
SFNDIING LABORATORY: RECEIVING LABORATORY:
Waypoiut Analytical Pace Analytical, Inc
1). U. BoN 4543 9800 KinceyAvenue Suite 100
Charlotte. NC 28224-0543 Huntersville, NC 28078
Phone: [phone] —Phone :[phone] — - --
Pox: 704-525-0409 Pax: (70I) 875-9091
Yri ject \ianagcr. Anuela 19. Overcash I
ra
Ana13-sis Duc Expires Laboratory Ill Comments ! }}"1 '•: �'
Sample 11 0030271-01 1Vater S:uupled:03/18/20 12:25
52-4.2 (Sub) 0zliuF20 12:25
(�Uufni�len�' �r��yflnJ:
7:1 M, 0lit 13.11 Ris 14\ I+;Ili
1 f%.-jI41A?i

Q)
Waypoint.
ANALYTICAL
Anchor QEA of North Carolina, PLLC
Alec Macbeth
231 Haywood Street
Asheville, NC 28801
NC Certification No. 402
NC Drinking Water Cent No. 37735
SC Certification No. 99012
Project: Jackson Cty Landfill 2020 Spring
Project No.: 50-02
Lab Submittal Date: 03/19/2020
Work Order: 0030272
Case Narrative
4/2/20 9:51
This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample
Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed
according to the referenced methods.
Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case
narrative.
Narrative Notes:
CO2, Hydrogen, Methane, Ethane, Ethene and VFA analysissubcontracted to Pace /Microseeps.
Laboratory report is attached with a total page count of 30 pages.
Please call if you have any questions relating to this analytical report.
Respectfully,
WAYPOINT ANALYTICAL
Angela D. Overcash
Senior Project Manager
Data Qualifiers Key Reference:
BRL Below Reporting Limit
MDL Method Detection Limit
RPD Relative Percent Difference
* Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and
reporting limit indicated with a J.
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Waypoint-
0
ANALYTICAL
Sample Receipt Summary
04/02/2020
Work Order: 0030272
Client Sample ID
Lab Sample ID
Matrix
Date/Time Sampled
Date/Time Received
MW-01-20200318
0030272-01
Water
03/18/20 11:39
03/19/20
9:05
MW-02-20200318
0030272-02
Water
03/18/20 8:55
03/19/20
9:05
MW-03-20200317
0030272-03
Water
03/17/20 13:46
03/19/20
9:05
MW-04-20200317
0030272-04
Water
03/17/20 9:59
03/19/20
9:05
MW-05R-20200318
0030272-05
Water
03/18/20 12:45
03/19/20
9:05
MW-06-20200318
0030272-06
Water
03/18/20 10:13
03/19/20
9:05
MW-07-20200317
0030272-07
Water
03/17/20 11:39
03/19/20
9:05
Samples were received in good condition at 1.5 degrees C unless otherwise noted.
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

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aceAnalytical
March 31, 2020
Angie Overcash
Waypoint Analytical
449 Springbrook Road
PO Box 240543
Charlotte, NC 28224
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
RE: 0030272
Pace Workorder.33309
Dear Angie Overcash:
Enclosed are the analytical results for sample(s) received by the laboratory on Friday, March 20, 2020. Results
reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in
the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Ruth Welsh 03/31/2020
[e-mail]
Customer Service Representative
Enclosures
As a valued client we would appreciate your comments on our service.
Please email [e-mail].
Report ID: 33309 - 1271913
CERTIFICATE OF ANALYSIS
nelac This repot shall not be reproduced, except in full,
wdhout the written consent of Pace Analytical Energy Services f_LC.
Total Number of Pages 27
Page 1 cf 22

r
aceAnalytical
LABORATORY ACCREDITATIONS & CERTIFICATIONS
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Accreditor:
Pennsylvania Department of Environmental Protection, Bureau of Laboratories
Accreditation ID:
02-00538
Scope:
NELAP Non -Potable Water
Accreditor:
West Virginia Department of Environmental Protection, Division of Water and Waste
Management
Accreditation ID:
395
Scope:
Non -Potable Water
Accreditor:
South Carolina Department of Health and Environmental Control, Office of Environmental
Laboratory Certification
Accreditation ID:
89009003
Scope:
Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA)
Accreditor: State of Virginia
Accreditation ID: 460201
Scope: Non -Potable Water
.Accreditor: NELAP: New Jersey, Department of Environmental Protection
Accreditation ID: PA026
Scope: Non -Potable Water
Accreditor: NELAP: New York, Department of Health Wadsworth Center
Accreditation ID: 11815
Scope: Non -Potable Water
Accreditor:
State of Connecticut, Department of Public Health, Division of Environmental Health
Accreditation ID:
PH-0263
Scope:
Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA)
Accreditor:
NELAP: Texas, Commission on Environmental Quality
Accreditation ID-
T104704453-09-TX
Scope:
Non -Potable Water
Accreditor:
State of New Hampshire
Accreditation ID:
299409
Scope:
Non -potable water
Accreditor:
State of Georgia
Accreditation ID:
Chapter 391-3-26
Scope:
As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is
accredited by the Pennsylvania Department of Environmental Protection Bureau of
Laboratories under the National Environmental Laboratory Approval Program (NELAC).
Report ID: 33309 - 1271913
CERTIFICATE OF ANALYSIS
'�]�'aC -. This report shall riot be reproduced, except in lull,
without the written consent of Pace Analytical Ener gy Services LLC
Page 2 of 22

P�1eAnar r'�r�1
SAMPLE SUMMARY
Workorder: 33309 0030272
Pace Analytical Energy Services LLC
220 William Pit[ Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID
Sample ID
Matrix
Date Collected
Date Received
333090001
MW-01-20200318
Water
3118/202011:39
3/20/2020 11:00
333090002
MW-02-20200318
Water
3/18/2020 08:55
3/20/2020 11:00
333090003
MW-03-20200317
Water
3/171202013:46
3/20/2020 11:00
333090004
MW-04-20200317
Water
3/17/2020 09:59
3/20/2020 11:00
333090005
MW-05R-20200318
Water
3/18/202012:45
3/20/2020 11:00
333090006
MW-06-20200318
Water
3/181202010:13
3/20/2020 11:00
333090007
MW-07-20200317
Water
3117/202011:39
3/20/2020 11:00
333090008
MW-03-20200317
Bubble Strip
3/17/2020 13:46
3/20/2020 11:00
333090009
MW-04-20200317
Bubble Strip
3/17/2020 09:59
3/20/2020 11:00
333090010
MW-07-20200317
Bubble Strip
3/17/2020 11:39
3120/2020 11:00
Report ID: 33309 - 1271913
CERTIFICATE OF ANALYSIS
����� •F This report shall not be reproduced, except in full
without the written consent of Pace Analytical Energy Services LLC.
Page 3 of 22

PaccAnalylical
PROJECT SUMMARY
Workorder: 33309 0030272
Workorder Comments
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
This report is being re -issued on 3-31-20 to correct the sample ID's for all samples per client request. The analytical results have not
been affected.
Report ID: 33309 - 1271913
CERTIFICATE OF ANALYSIS
��a� This report shall not be reproduced, except in full,
without the written consent of Pace Anatylical Energy Services LLC.
Page 4 of 22

2aeAnalytical
I
ANALYTICAL RESULTS
Workorder: 33309 0030272
Pace Analytical Energy Services LLC
220 William Pill. Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 333090001
Date Received: 3/20/2020 11:00 Matrix: Water
Sample ID: MW-01-20200318
Date Collected: 3/18/2020 11:39
Parameters
Results Units
PQL
MDL DF
Analyzed
By
Qualifiers
EDonors - PAES
Analysis Desc: AM23G
Analytical Method: AM23G
Lactic Acid
0.0851.11 mg/I
0.20
0.085 1
3/25/2020 18:47
KB
Acetic Acid
0.049J mg/I
0.10
0.043 1
3/25/2020 18:47
KB
PropionicAcid
0.0057J mg/I
0.10
0.0010 1
3/25/2020 18:47
KB
Formic Acid
0.121-1 mg/I
0.50
0.12 1
3/25/2020 18:47
KB
Butyric Acid
0.00901.11 mg/I
0.10
0.0090 1
3/25/2020 18:47
KB
PyruvicAcid
0.014U mg/I
0.10
0.014 1
3/25/202018.47
KB
i-Pentanoic Acid
0.0070U mg/I
0.10
0.0070 1
3/25/2020 18:47
KB
Pentanoic Acid
0.0050U mg/I
0.10
0.0050 1
3/25/2020 18:47
KB
i-HexanoicAcid
0.010U mg/I
0.20
0.010 1
3/25/2020 18:47
KB
HexanoicAcid
0.020U mg/I
020
0.020 1
3/25/2020 18:47
KB
RISK - PAES
Analysis DeSG: AM20GAX
Analytical Method: AM20GAX
Methane
2700 ug/l
0.50
0.046 1
3/24/202011:48
BW
n
Ethane
0.088J ug/l
0.10
0.0050 1
3/24/202011:48
BW
n
Ethene
0.056J ug/I
0.10
0.0040 1
3/24/202011:48
BW
n
Carbon Dioxide
270 mgA
5.0
0.45 1
3/24/2020 11:48
BW
n
Report ID: 33309 - 1271913
nelac
CERTIFICATE OF ANALYSIS
This repot shall not be reproduced, except in full
without the written consent of Pace Analytical Energy Services LLC
Page 5 of 22

Pace Analytical Energy Services LLC
220 William Pitt Way
ace 7tnj ytical
/ jl
Pittsburgh, PA 15238
LL l L
Phone: [phone]
I
Fax: [phone]
ANALYTICAL RESULTS
Workorder,. 33309 0030272
Lab ID: 333090002
Date Received: 3/20/2020 11:00
Matrix: Water
Sample ID: MW-02-20200318
Dale Collected: 3/18/2020 08:55
Parameters
Results Units
PQL
MDL DF
Analyzed
By
Qualifiers
EDonors - PAES
Analysis Desc: AM23G
Analytical Method: AM23G
Lactic Acid
0.0851.1 mg/I
0.20
0.085 1
3/25/2020 19:40
KB
Acetic Acid
0.44 mg/I
0.10
0.043 1
3/25/2020 19:40
KB
Propionic Acid
0.015J mg/I
0.10
0.0010 1
3/25/2020 19:40
KB
Formic Acid
0.121.1 mg/I
0.50
0.12 1
3125/202019:40
KB
Butyric Acid
0.00901.1 mg/I
0.10
0.0090 1
3/25/2020 19:40
KB
PyruvicAcid
0.014U mg/I
0.10
0.014 1
3/25/202019:40
KB
i-PentanoicAcid
0.00701-1 mg/I
0.10
0.0070 1
3/25/2020 19:40
KB
Pentanoic Acid
0.00501.1 mg/I
0.10
0.0050 1
3/25/2020 19:40
KB
i-Hexanoic Acid
0.0101.1 mg/I
0,20
0.010 1
3/25/2020 19:40
KB
Hexanoic Acid
0.0201.1 mg/I
0.20
0.020 1
3/25/2020 19:40
KB
RISK - PAES
Analysis Desc: AM20GAX
Analytical Method: AM20GAX
Methane
0.10J ug/I
0.50
0.046 1
3/24/202012:02
BW
n
Ethane
0.00501.1 ug/I
0.10
0.0050 1
3124/202012:02
BW
n
Ethene
0.0082J ug/I
0.10
0.0040 1
3/24/202012:02
BW
n
Carbon Dioxide
60 mg/l
5.0
0.45 1
3/24/2020 12:02
BW
n
Report ID: 33309 - 1271913 Page 6 of 22
CERTIFICATE OF ANALYSIS
nelaC ; This report shal€ nol be reproduced, except in cull
without the written consent of Pace Analytical Energy Services LLC

accAnalytical
ANALYTICAL RESULTS
Workorder: 33309 0030272
Pace Analytical Energy Services LLC
220 William Pill Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 333090003
Dale Received: 3/20/2020 11:00 Matrix: Water
Sample ID: MW-03-20200317
Date Collected: 3/17/2020 13:46
Parameters
Results Units
PQL
MDL DF
Analyzed
By
Qualifiers
EDonors - PAES
Analysis Desc: AM23G
Analytical Method: AM23G
Lactic Acid
0.085U mg/I
0.20
0.085 1
3/25/2020 20:33
KB
Acetic Acid
0.048J mg/I
0.10
0.043 1
3/25/2020 20:33
KB
PropionicAcid
0.0045J mg/I
0.10
0.0010 1
3/25/2020 20:33
KB
Formic Acid
0.12U mg/I
0.50
0.12 1
3125/2020 20:33
KB
Butyric Acid
0.0090U mg/I
0.10
0.0090 1
3/25/2020 20:33
KB
PyruvicAcid
0.0141.1 mg/I
0.10
0.014 1
3/25/2020 20:33
KB
i-PentanoicAcid
0.00701.1 mg/I
0.10
0.0070 1
3/25/2020 20:33
KB
Pentanoic Acid
0.0050U mg/I
0.10
0.0050 1
3/25/2020 20:33
KB
i-Hexanoic Acid
0.010U mg/I
0.20
0.010 1
3/25/2020 20:33
KB
Hexanoic Acid
0.0201.1 mg/I
0.20
0,020 T
3/25/2020 20:33
KB
RISK - PAES
Analysis Desc: AM20GAX
Analytical Method: AM20GAX
Methane
0.20J ug/I
0.50
0.046 1
3/24/202012:13
BW
n
Ethane
0.0050U ug/I
0.10
0.0050 1
3/24/202012:13
BW
n
Ethane
0.013J ug/1
0.10
0.0040 1
3/24/202012:13
BW
n
Carbon Dioxide
49 mg/I
5.0
0.45 1
3/24/2020 12:13
BW
n
Report ID: 33309 - 1271913 Page 7 of 22
CERTIFICATE OF ANALYSIS
nelat `_ This report shall not be reproduced, except in full
without ±he writler, consent of Pace Analytical Energy Services LLC

aceAnalyfical
ANALYTICAL RESULTS
Workorder: 33309 0030272
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 333090004
Sample ID: MW-04-20200317
Date Received: 3/20/2020 11:00 Matrix: Water
Date Collected: 3/17/2020 09:59
Parameters
Results Units
PQL
MDL DF
Analyzed
By
Qualifiers
EDonors - PAES
Analysis Desc: AM23G
Analytical Method: AM23G
Lactic Acid
0.085U mg/I
0.20
0.085 1
3/25/2020 21:27
KB
Acetic Acid
0.043U mg/I
0.10
0.043 1
3/25/2020 21:27
KB
Propionic Acid
0.0030J mgll
0.10
0.0010 1
3/25/2020 21:27
KB
Formic Acid
0.12U mg/I
0.50
0.12 1
3/25/2020 21:27
KB
Butyric Acid
0.0090U mg/I
0.10
0.0090 1
3/25/2020 21:27
KB
Pyruvic Acid
0.0141,11 mg/I
0.10
0.014 1
3/25/2020 21:27
KB
i-PentanoicAcid
0.0070U mg/I
0.10
0.0070 1
3125/202021:27
KB
Pentanoic Acid
0.00501.1 mg/I
0.10
0.0050 1
3/25/2020 21:27
KB
i-HexanoicAcid
0.0101.1 mg/I
0-20
0.010 1
3/25/2020 21:27
KB
Hexanoic Acid
0.020U mg/l
0.20
0.020 1
3/25/2020 21:27
KB
RISK - PAES
Analysis Desc: AM20GAX
Analytical Method: AM20GAX
Methane
83 ug/I
0.50
0.046 1
3/24/202012:23
BW
n
Ethane
0-018J ug/I
0.10
0.0050 1
3/24/202012:23
BW
n
Ethene
0.0040U ugh
0.10
0.0040 1
3/24/202012:23
BW
n
Carbon Dioxide
220 mg/I
5.0
0-45 1
3/24/2020 12:23
BW
n
Repor iD: 33309 - 1271913 Paoe 8 of 22
CERTIFICATE OF ANALYSIS
nelac I tis report shall not be reproduced, except in full
without the written consent of Pace Analytical Energy Services LLC

PaeeAnaVical
ANALYTICAL RESULTS
Workorder: 33309 0030272
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 333090005 Date Received: 3/20/2020 11:00 Matrix: Water
Sample ID: MW-05R-20200318 Date Collected: 3/1812020 12:45
Parameters Results Units PQL MDL DF Analyzed By Qualifiers
EDonors - PAES
Analysis Desc: AM23G
Analytical Method: AM23G
Lactic Acid
0.085U mg/I
0.20
0.085 1
3/25/2020 22:20
KB
Acetic Acid
0.21 mg/I
0.10
0.043 1
3/25/2020 22:20
KB
Propionic Acid
0.027J mgll
0.10
0.0010 1
3/25/2020 22:20
KB
Formic Acid
0.12J mgll
0.50
0.12 1
3/2512020 22:20
KB
Butyric Acid
0.0090U mg/I
0.10
0.0090 1
3125/2020 22:20
KB
Pyruvic Acid
0.014U mg/I
0.10
0.014 1
3/25/2020 22:20
KB
i-Pentanoic Acid
0.0070U mg/I
0.10
0.0070 1
3/25/2020 22:20
KB
Pentanoic Acid
0.0050U mg/I
0.10
0.0050 1
3/25/2020 22:20
KB
i-HexanoicAcid
0.010U mg/I
0.20
0.010 1
3/25/202022:20
KB
Hexanoic Acid
0.020U mg/I
0.20
0.020 1
3/25/2020 22:20
KB
RISK - PAES
Analysis Desc: AM20GAX
Analytical Method: AM20GAX
Methane
4800 ug/l
0.50
0.046 1
3/241202012:34
BW n
Ethane
0.34 ugh
0.10
0.0050 1
3124/202012:34
BW n
Ethene
0.18 ugh
0,10
0.0040 1
3124/202012:34
BW n
Carbon Dioxide
56 mg1l
5.0
0.45 1
3/24/2020 12:34
BW n
Report ID: 33509 - 1271913
CERTIFICATE OF ANALYSIS
t"lE lac . This report shall not be reproduced, except in lull,
wi!hou! the written consent of Pace Analytical Energy Services LLC
Page 9 of 22

r
f accAnall4ical
ANALYTICAL RESULTS
Workorder: 33309 0030272
Pace Analytical Energy Services LLC
220 William Pill Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 333090006 Date Received: 3/20/2020 11:00 Matrix: Water
Sample ID: MW-06-20200318 Date Collected: 3/1812020 10:13
Parameters Results Units PQL MDL DF Analyzed By Qualifiers
EDonors - PAES
Analysis Desc: AM23G
Analytical Method: AM23G
Lactic Acid
0.085U mg/I
0.20
0.085 1
3/25/2020 23:13
KB
Acetic Acid
0.043U mg/I
0.10
0.043 1
3/25/2020 23:13
KB
PropionicAcid
0.0032J mg/I
0.10
0.0010 1
3/25/2020 23:13
KB
Formic Acid
0.12U mgN
0.50
0.12 1
3/25/2020 23:13
KB
Butyric Acid
0.0090U mg/1
0.10
0.0090 1
3/2512020 23:13
KB
Pyruvic Acid
0.014U mg/1
0.10
0.014 1
3/25/2020 23:13
KB
i-PentanoicAcid
0.0070U mg/1
0.10
0.0070 1
3/25/202023:13
KB
Pentanoic Acid
0.0050U mg/1
0.10
0.0050 1
3125/2020 23:13
KB
i-HexanoicAcid
0.010U mg/1
0.20
0.010 1
3051202023:13
KB
Hexanoic Acid
0.020U mg/1
0.20
0.020 1
3i2512020 23:13
KB
RISK - PAES
Analysis Desc: AM20GAX
Analytical Method: AM20GAX
Methane
3.7 ug/I
0.50
0.046 1
3/24/202012:46
BW
Ethane
0.0050U ug11
0.10
0.0050 1
3124/202012:46
BW
Ethene
0.043J ugll
0.10
0,0040 1
3/241202012:46
BW
Carbon Dioxide
280 mg/I
5.0
0.45 1
3124/2020 12:46
BW
Report ID: 33309 - 1271913
CERTIFICATE OF ANALYSIS
nelac This report. shall not be reproduced, except in iuil.
without the written consent of Paw Analytical Energy Services LL C
n
n
n
n
Page 10 of 22

aceAnal;6cal
ANALYTICAL RESULTS
Workorder: 33309 0030272
Pace Analytical Energy Services LLC
220 William Pill Way
Pillsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 333090007
Sample ID: MW-07-20200317
Dale Received: 3/20/2020 11:0C Matrix: Water
Date Collected: 3/17/2020 11:39
Parameters
Results Units
PQL
MDL DF
Analyzed
By
Qualifiers
EDonors - PAES
Analysis Desc: AM23G
Analytical Method: AM23G
Lactic Acid
0.085U mg/I
0.20
0.085 1
3/26/2020 00:07
KB
Acetic Acid
0.043U mg/I
0.10
0.043 1
3/26/2020 00:07
KB
Propionic Acid
0.0023J mg/I
0.10
0.0010 1
3/26l2020 00:07
KB
Formic Acid
0.12U mg/I
0.50
0.12 1
3/26/2020 00:07
KB
Butyric Acid
0.0090U mg/I
0.10
0.0090 1
3/26/2020 00:07
KS
Pyruvic Acid
0.014U mg/I
0.10
0.014 1
3/26/2020 00:07
KB
i-Pentanoic Acid
0.0070U mg/I
0.10
0.0070 1
3/26/2020 00:07
KB
Pentanoic Acid
0.016J mg/I
0.10
0.0050 1
3/2612020 00:07
KB
i-Hexanoic Acid
0.010U mg/I
0.20
0.010 1
3/26/2020 00:07
KB
Hexanoic Acid
0.020U mg/I
0.20
0.020 1
3/26/2020 00:07
KB
RISK - PAES
Analysis Desc: AM20GAX
Analytical Method: AM20GAX
Methane
280 ug/l
0.50
0.046 1
3/25/202013:16
BW
n
Ethane
0.11 ug/l
0.10
0.0050 1
3/25/202013:16
BW
n
Ethene
0.093J ug/1
0.10
0.0040 1
3/25/202013:16
BW
n
Carbon Dioxide
360 mg/l
5.0
0.45 1
3/25/2020 13:16
BW
n
Report ID: 33309 - 1271913 Page 11 of 22
CERTIFICATE OF ANALYSIS
nelac This report shall not be reproduced, except n full
w,thou the written consent of Pace Analytical Energy Services LLC

aceAnalytical
ANALYTICAL RESULTS
Workorder: 33309 0030272
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone; [phone]
Fax: [phone]
Lab ID: 333090008 Date Received: 3/20/2020 11:00 Matrix: Bubble Strip
Sample ID: MW-03.20200317 Date Collected: 3/17/2020 13:46
Parameters Results Units PQL MDL DF Analyzed By Qualifiers
RISK - PAES
Analysis Dew AM20GAX Analytical Method: AM20GAX
Hydrogen 120 nM 20 15 20 3124/202012:49 MM d,n
Report ID: 33309 - 1271913 Page 12 of 22
CERTIFICATE OF ANALYSIS
nelac ; This report shall not be reproduced, except in lull;
without the wrillen consent of Pace Analytical Energy Services LL .

X5acEAnalyfical
i
ANALYTICAL RESULTS
Workorder: 33309 0030272
Pace Analytical Energy Services LLC
220 William Pill Way
Pittsburgh, PA15238
Phone: [phone]
Fax: [phone]
Lab ID: 333090009 Date Received: 3/20/2020 11:00 Matrix: Bubble Strip
Sample ID: MW-04-20200317 Date Collected: 3/17/2020 09:59
Parameters Results Units PQL MDL DF Analyzed By Qualifiers
RISK - PAES
Analysis Descr AM200AX Analytical Method: AM20GAX
Hydrogen 13 nM ix 0:75 1 3124/202012:16 MM n
Report ID: 33309 - 1271913 Page 13 of 22
CERTIFICATE OF ANALYSIS
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F ice Analytical
I
Workorder. 33309 0030272
ANALYTICAL RESULTS
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 333090010 Date Received: 3/20/2020 11:00 Matrix: Bubble Strip
Sample ID: MW-07-20200317 Date Collected: 3/17/2020 11:39
Parameters Results Units PQL MDL DF Analyzed By Qualifiers
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Hydrogen 52 nM 2 0 1.5 2 3/24/2020 13:02 MM
Report ID: 33309 - 1271913
CERTIFICATE OF ANALYSIS
1`1��aIC This report shall not be reproduced, except in full,
without the wrillen consent or Pace Analytical Energy Services LLC-
d,n
Page 14 of 22
11

2aceAnalytical
ANALYTICAL RESULTS QUALIFIERS
Workorder. 33309 0030272
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone; [phone]
Fax: [phone]
DEFINITIONS/QUALIFIERS
MDL Method Detection Llmit. Can be used synonymously with LOD; Limit Of Detection.
PQL Practical Quanilation Limit. Can be used synonymously with LOQ; Limit Of Quantitation.
ND Not detected at or above reporting limit.
DF Dilution Factor,
S Surrogate.
RPD Relative Percent Difference.
% Rec Percent Recovery.
U Indicates the compound was analyzed for, but not detected at or above the noted concentration.
J Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL).
n The laboratory does not hold NELAPlTNI accreditation for this method or analyte.
d The analyte concentration was determined from a dilution.
Report ID: 33309 - 1271913
CERTIFICATE OF ANALYSIS
I"lelac This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC
Page 15 of 22

f
ace Analytical
QUALITY CONTROL DATA
Workorder: 33309 0030272
Pace Analytical Energy Services LLC
220 William Pill Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
OC Batch: DISG/8166
Analysis Method:
AM20GAX
QC Batch Method: AM20GAX
Associated Lab Samples: 333090001, 333090002, 333090003, 333090004,
333090005, 333090006
METHOD BLANK: 66454
Blank
Reporting
Parameter Units
Result
Limit Qualifiers
RISK
Methane ug/I
0.046U
0.046 n
Ethane ugh
0.0050U
0.0050 n
Ethane ug/I
0.0040U
0.0040 n
METHOD BLANK: 66455
Blank
Reporting
Parameter Units
Result
Limit Qualifiers
RISK
Carbon Dioxide mg/I
0.45U
0.45 n
LABORATORY CONTROL SAMPLE & LCSD:
66456
66458
Spike LCS
LCSD LCS
LCSD
°% Rec
Max
Parameter Units
Cone. Result
Result % Rec
% Rec
Limit
RPD
RPD
Qualifiers
Methane ug/1
750 780
770 105
104
80-120
0.95
20
n
Ethane ug/1
38 39
38 103
101
80-120
1.4
20
n
Ethene ug/1
35 36
36 103
101
80-120
1,9
20
n
LABORATORY CONTROL SAMPLE & LCSD:
66457
66459
Spike LCS
LCSD LCS
LCSD
% Rec
Max
Parameter Units
Cone. Result
Result % Rec
% Rec
Limit
RPD
RPD
'Qualifiers
Carbon Dioxide mg/I 120 130 120 109 104 80-120 4.3 20 n
Report ID. 33309 - 1271.913 Page 16 of 22
CERTIFICATE OF ANALYSIS
1 �eIC1C ^r This reeorl shell not be reproduced, except in lull.
wilhoul the wntten consent of Pace Analytical Energy Services LLC

aceAnalyfical
r
I
QUALITY CONTROL DATA
Workorder: 33309 0030272
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: (412) a2&3433
QC Batch: DISG/8168
Analysis Method:
AM20GAX
OC Batch Method: AM20GAX
Associated Lab Samples: 333090007
METHOD BLANK: 66465
Blank
Reporting
Parameter Units
Result
Limit Qualifiers
RISK
Methane ug/I
0.046U
0.046 n
Ethane ug/I
0.0050U
0.0050 n
Ethene ug/I
0.0040U
0.0040 n
LABORATORY CONTROL SAMPLE & LCSD:
66466
66467
Spike LCS
LCSD
LCS
LCSD
% Rec
Max
Parameter Units
Conc. Result
Result % Rec % Rec
Limit
RPD
RPD
Qualifiers
Methane ug/1
750 780
770
104
103
80-120
14
20
n
Ethane ug/I
38 41
40
108
106
80-120
2,4
20
n
Ethene ug/1
35 38
37
108
105
80-120
32
20
n
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
66507
66508
Original:
332670003
Original Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter Units
Result Conc.
Result Result
% Rec
% Rec
Limit
RPD RPD
Qualifiers
RISK
Methane ugA
0.079 40
38
38
95
94
70-130
1.3 20
n
Ethane ugA
0.0052 76
71
70
94
92
70-130
2 20
n
Ethene ugA
0.013 71
65
64
92
91
70-130
0 98 20
n
Report ID: 33309 - 1271913
CERTIFICATE OF ANALYSIS
nelac -I This report shall not he reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC
Paae 17 of 22

aceAnalylical
QUALITY CONTROL DATA
Workorder: 33309 0030272
Pace Analytical Energy Services LLC
220 William Pill Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
QC Batch: DISG/8170 Analysis Method: AM20GAX
QC Batch Method: AM20GAX
Associated Lab Samples: 333090008, 333090009, 333090010
METHOD BLANK: 66480
Blank Reporting
Parameter Units Result Limit Qualifiers
RISK
Hydrogen nM 0.75U 0.75 rl
LABORATORY CONTROL SAMPLE 8 LCSD: 66481 66482
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Quallfiers
Hydrogen nM 25 23 23 92 93 80-120 1.4 20 n
Report ID: 33309 - 1271913
CERTIFICATE OF ANALYSIS
i 1��'dC This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 18 of 22

Z
9107
PaceAnalytical
QUALITY CONTROL DATA
Workorder: 33309 0030272
QC Batch: EDON/4396 Analysis Method: AM23G
QC Batch Method: AM23G
Associated Lab Samples: 333090001, 333090002, 333090003, 333090004, 333090005, 333090006, 333090007
Pace Analytical Energy Services LLC
220 William Pill Way
Pittsburgh. PA 15238
Phone: [phone]
Fax: [phone]
METHOD BLANK: 66483
Parameter
Units
Blank
Result
Reporting
Limit Qualifiers
EDonors
Lactic Acid
mg/I
0.085U
0.085
Acetic Acid
mg/I
0.043U
0.043
Propionic Acid
mg/l
0.0010U
0.0010
Formic Acid
mg/I
0.12U
0.12
Butyric Acid
mg/I
0.0090U
0.0090
PyruvicAcid
mg/I
0.014U
0.014
i-Pentanoic Acid
mg/I
0.0070U
0.0070
Pentanoic Acid
mg/I
0.0050U
0.0050
i-Hexanoic Acid
mg/I
0.0101-1
0.010
Hexanoic Acid
mg/I
0.020U
0.020
LABORATORY CONTROL SAMPLE: 66484
Spike
LCS
1-CS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Lactic Acid
mg/I
2
2.1
106
70-130
Acetic Acid
mg/I
2
2.2
108
70-130
Propionic Acid
mg/I
2
2.1
107
70-130
Formic Acid
mg/I
2
2.1
106
70-130
ButvricAcid
mg/I
2
2A
105
70-130
PyruvicAcid
mg/I
2
2.0
102
70-130
i-Pentanoic Acid
mg/I
2
2.1
104
70-130
Pentanoic Acid
mg/I
2
2.0
99
70-130
i-Hexanoic Acid
mg/I
2
2.0
101
70-130
Hexanoic Acid
mg/I
2
1,8
92
70-130
MATRIX SPIKE 8, MATRIX SPIKE DUPLICATE:
66485
66486
Original:
333050001
Original
Spike
MS
MSD MS
MSD
% Rec Max
Parameter
Units
Result
Conc.
Result
Result % Rec
% Rec
Limit RPD RPD Qualifiers
EDonors
Lactic Acid
mg/1
0.0077
2
2.0
2.1 100
107
70-130 6.3 30
Acetic Acid
mg/1
0.038
2
2.1
2.2 102
109
70-130 6.1 30
Report ID: 33309 - 1271913
Page 19 of 22
CERTIFICATE OF ANALYSIS
nelac This report shall not be reproduced, except in full.
without the wri!ler: consent of Pace Analytical Energy Services LLC

accAnalytical
QUALITY CONTROL DATA
Workorder: 33309 0030272
Pace Analytical Energy Services LLC
220 William Pill Way
Pittsburgh, PA 15238
Phone: [phone]
Fax:[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 66485
66486
Original:
333050001
Original Spike
MS
MSD MS
MSD % Rec Max
Parameter Units Result Conc.
Result
Result % Rec
% Rec Limit RPD RPD Qualifiers
Pro picnic Acid
mg/I
0.0024
2
2.0
2.2
102
108
70-130
6 30
Formic Acid
mg/I
0.046
2
2.0
2.2
100
107
70-130
5.9 3D
Butyric acid
mg/I
0.0015
2
2.0
2.2
102
108
70-130
6.2 30
Pyruvq; Acid
mg/I
0
2
1.9
2.1
97
104
70-130
6.5 30
r-Penlangic Arid
mg/I
0
2
2.0
2.2
102
108
70-130
6.4 30
Penianoic Acid
mg/I
0
2
2.0
2.1
99
106
70-130
7.2 30
I-Hexanoic Acid
mg/I
0
2
2.1
2.2
105
112
70-130
6.7 30
Hexannic Acid
mgA
0
2
2.0
2.2
101
108
70-130
6.6 30
Report ID: 33309 - 1271913
CERTIFICATE OF ANALYSIS
nelae This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 20 of 22

PaGeAnalytrcal
QUALITY CONTROL DATA QUALIFIERS
Workorder: 33309 0030272
QUALITY CONTROL PARAMETER QUALIFIERS
The laboratory does not hold NELAP/TNI accreditation for this method or analyte_
Report ID: 33309 - 1271913
CERTIFICATE OF ANALYSIS
nelac This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Pace Analytical Energy Services LLC
220 William Pill Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Page 21 of 22

/7 2aceAnapical
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Workorder: 33309 0030272
Pace Analytical Energy Services LLC
220 William Pilt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax:[phone]
Lab ID
Sample ID
Prep Method Prep Batch Analysis Method
Analysis
Batch
333090001
MW-01-20200318
AM20GAX
DISG/8166
333090002
MW-02-20200318
AM20GAX
DISG/8166
333090003
MW-03-20200317
AM20GAX
DISG/8166
333090004
MW-04-20200317
AM20GAX
DISG/8166
333090005
MW-05R-20200318
AM20GAX
DISG/8166
333090006
MW-06-20200318
AM20GAX
DISG/8166
333090007
MW-07-20200317
AM20GAX
DISG/8168
333090008
MW-03-20200317
AM20GAX
DISG/8170
333090009
MW-04-20200317
AM20GAX
DISG/8170
333D90010
MW-07-20200317
AM20GAX
DISG/8170
333090001
MW-01-20200318
AM23G
EDON/4396
333090002
MW-02-20200318
AM23G
EDON/4396
333090003
MW-03-20200317
AM23G
EDON/4396
333090004
MW-D4-2020D317
AM23G
EDONM396
333D90005
MW-05R-20200318
AM23G
EDON/4396
333090006
MIN-06-20200318
AM23G
EDON/4396
333090007
MW-07-20200317
AM23G
EDON/4396
Report ID: 33309 - 1271913 Page 22 of 22
CERTIFICATE OF ANALYSIS
11e�ciC This report shall net be reproduced, except in lull,
without the written consent of Pace Analytical Energy Services LLC.

ypoint
,"k� 1 AUl I If .:`
SUBCONTRAC•I. ORDER
Certification: \ LAC (1SACE
Wa_ypoint Analytical NC SC Odic
0030272 NIA _
Si:ND1NG LABORATORY: RECEIVING LABORATORY:
Waypoint Aralvrical Microseeps/1'ace
P. O. Box 240543 220 William Pitt Way
Charlonc, NC 28224-0543 Pittsburgh, PA 15238
Phone- 800-57..9-6364 Phoric :(d 12) 826-52,15
Fax: [phone] Fax: [phone]
Proiect Lianaper: Angela D. Overcash h
� `'
Analysis Due Expires Laburatory ID Comments
Sample 1T): 0030272-0I 1><%atcr Samplcd:03118/20 l 1:39
\•Icilmne, rtharc. Ethane (AM2 03/19/20 11:39
Volatile I <uly Acids (Sub) 03/25/20 11:39
carbon Dioxide AM20GA-X 04/01 /20 1139
Conrniners Supplied:
Smople ID: 0030272-02 Water Sampled:03/18/20 08:55 f v' 4/i-02 — 2_0
Carron DioxidcAlt,12OGAX 04:01/20 08:5i
I oliane, Ethane, Ethane (AN12 03/39l20 08:5
` olat lc Pau; Acids (Sul:) ;)i;25/20 08 55
C2.1r(HRtrB Supplied:
Sample ID: 00302'72-03
C.L'biart I)!nxici�;1:'.•120i.iri`i
1lydrrocii A?.120(_'! ,X
�i::th;u a, I'sll;anc. V.
Fihcnc (AA17_
'dc!18 €C r ;dlv Ackis f Sob"
-, �•rrr,n: err Jt��o� �lirrr
witer Sno-plyd:03i1T2013:40
0.::3.
l�tt)-0-;?62_003;�

SURC01\Ti2ACT ORDER
Certillcntion: NELAC USACF
Waypoint Analytical <;_ Sc- Otltcr
-
0030272 _
lnalysis Due Expires L:ilioritary ID Comments
Simple 1 D: 01130272-04 Water Sarnplcd:03/17l20 09:i9 AW —
Mc!nc ha. ethane, I:iihcne (AAd2 0.3/18/20 09:59
I lVdrogen AM20GAX 03!3 1/20 09:59
Volafile Fatly Acids (Sub) 03124/20 09:59
Carbon Dioxide AN120GAX 03/31/20 09:59
Comainers ,Supplied:
Sample ID_ 0030272-0-5 Water Sampled:03/18/20 12:45 r ' ~ � �G V !✓
Carbon DioxideA\•120GAX 04!01/20 12:45
Methane, Ethane, I-thene (Ab12 03/19/20 12:45
Volatile Fatty Acids (Sub) 03/25/20 12:45
f..'nrtrniiee�:r .Supplier!:
Sample lq: 0030272-06 Water Sampled:03/18/20 10:13 P vO(-, — 2.nz c) 03t�
Carbon Dioxide AM20GAX 04101!20 10:13
Mcliianc, Ethane, Eflicne (AM2 031/9/20 10:13
Volatile I=altyAcids (Sub) 03/25i20 10:13
Containers Applied:
Sample ID:0030272-07 !Water
Sampled:03/17/20 11:39
Volatile Fatty Acids (SuL)
03124120 11:39
Carbon Dioxide AM20GAX
03131i20 11:39
lyrogco :1\120CiAX
03/31 /20 1 1:39
\•!ethane, Ethane. Glhane (AM2
03%1&20 t 1:39
%arlivincrs Supplied
/
LI t,

Cooler- Receipt Form
Client Name: .'v f Project; X Lab Work Order
A. Shipping/Container Information (circle appropriate response)
Courier: - FedFx,. UPS USPS Client Other: Air bill Present Yes No
Tracking Number: ' L
Custody Seal on Cooler/Box Present. Yes (No Seals Intact: Yes No
Cooler/Box Packing Material: Bublfe Wrap Absorbent fF6am,, Other:
Type of Ice: Wvet.) Blue None Ice Intact: (;Yes: Melted
Cooler Temperature: r. Radiation Screened: Yes /No : Chain of Custody Present Yes No
B. Laboratory Assignment/Log-in (check appropriate response)
YES N
Chain of Custody properly filled out
Chain of Custody relinquished
Sampler Name & Signature on COC
Containers intact
•L,
Were samples in separate bags j
- E1
Sample container labels match CDC
Sample name/date and time collected j t'
Sufficient volume provided
PAES containers used
Are containers properly preserved for the requested testing?
(as abeled)
Comment
Reference non -Conformance
J
I '
I�
i
i an Jn nuwn pi eservaL Or str.te, were containers checked? i { I' yes, se pH fOrf^
VOA's co ]I
[:.c�.puo�:: iiform
Was volun-e for dissolved testing fi_Id filtered, as noted on k
the COC? Was olunie received in a pre-l:� red container? _
Fac:a spare ;?resent:' - —
Cor'nments:
Cooler contents examined/received by
Protect Manager Review : s
t0
Date:
Date-

NON-CONFORMANCE FORM
PAES Work Order
Date: 'rime ofReceipt; t DU Receiver.,
Client: Pmed L-co—'r—
REASON FOR NON-CONFORMANCE:
7-�
ACTION TAKEN:
Client name: Date: Time:
custonleserv:ce lnitials:,_ , :N .1j Date:
F-PAE-Q-0 i 4-rev.00, 20 Nov-2014

Page I of l
Joseph Ward - 0030272
From: Joseph Ward
To: [e-mail]
Subject: 0030272
Upon receiving your samples for the project referenced above, We noticed the following.
Samples 0030272-4 and 0030272-07 the hydrogen vials had a silver band, Per our SOP the recommended
vial used for the requested analysis is 122ml headspace vial with a blue band and a light grey thick (stopper)
septa. We can still run the analysis.
Thank you
Joseph Ward
Customer Service
Pace Analytical Energy Services
220 William Pitt Way
Pittsburgh PA 15238
412-826-5245/412-826-2384(Direct)
ahnut:blank 3/20"2020