RA-2456_15929_CA_LSA_20110912_Berryman Property Phase II LSA

Phase II Limited Site Assessment Report S&ME Project No. 1354-09-276D
TF-15929 – Charles Berryman Property, Moncure, Chatham County, NC September 12, 2011

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TABLE OF CONTENTS
SITE IDENTIFICATION .......................................................................................... III
1.0 SCOPE OF SERVICES .................................................................................... 1
2.0 SITE HISTORY ................................................................................................... 2
2.0 RECEPTOR INFORMATION ......................................................................... 4
2.1 WATER SUPPLY WELLS ............................................................................................ 4
2.2 PUBLIC WATER SUPPLIES ......................................................................................... 4
2.3 SURFACE WATER ..................................................................................................... 5
2.4 WELLHEAD PROTECTION AREAS .............................................................................. 5
2.5 SUBSURFACE STRUCTURES ...................................................................................... 5
2.7 RISK CLASSIFICATION.............................................................................................. 6
3.0 SITE GEOLOGY AND HYDROGEOLOGY ............................................... 6
3.1 SOIL LITHOLOGY ..................................................................................................... 6
3.2 GROUNDWATER FLOW AND HYDRAULIC GRADIENT ................................................. 7
4.0 SAMPLING RESULTS ..................................................................................... 8
4.1 SOIL SAMPLING METHODOLOGY .............................................................................. 8
4.2 SOIL SAMPLING RESULTS ......................................................................................... 9
4.3 GROUNDWATER SAMPLING METHODOLOGY ............................................................ 9
4.4 GROUNDWATER SAMPLING RESULTS ..................................................................... 10
5.0 CONCLUSIONS AND RECOMMENDATIONS ..................................... 11

TABLES

TABLE 1 RECEPTOR INFORMATION AND ADJACENT PROPERTY OWNERS/OCCUPANTS
TABLE 2 GROUNDWATER ELEVATIONS (JULY 13&14, 2011)
TABLE 3 SOIL ANALYTICAL RESULTS
TABLE 4 MONITORING WELL CONSTRUCTION DETAILS
TABLE 5 GROUNDWATER ANALYTICAL RESULTS – (JULY 13, 2011)

FIGURES

FIGURE 1 VICINITY MAP
FIGURE 2 SITE MAP WITH MONITOR WELL LOCATIONS
FIGURE 3 RECEPTOR SURVEY MAP WITH ADJACENT PROPERTY OWNER/OCCUPANT INFO
FIGURE 4 POTENTIOMETRIC MAP (JULY 14, 2011)
FIGURE 5 GROUNDWATER CONSTITUENT MAP (JULY 13, 2011)
Phase II Limited Site Assessment Report S&ME Project No. 1354-09-276D
TF-15929 – Charles Berryman Property, Moncure, Chatham County, NC September 12, 2011

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TABLE OF CONTENTS (CON'T)

APPENDICES

APPENDIX I LIMITED SITE ASSESSMENT RISK CLASSIFICATION AND LAND USE FORM
APPENDIX II PHOTOGRAPHIC LOG
APPENDIX III REQUEST FOR WATER SUPPLY WELL INFORMATION LETTER AND RESPONSES
APPENDIX IV BORING LOGS AND WELL CONSTRUCTION RECORDS
APPENDIX V LABORATORY ANALYTICAL REPORT
APPENDIX VI FIELD MEASUREMENT SHEETS

Phase II Limited Site Assessment Report S&ME Project No. 1354-09-276D
TF-15929 – Charles Berryman Property, Moncure, Chatham County, NC September 12, 2011
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1.0 SCOPE OF SERVICES

The scope of services performed for this report were performed in general accordance
with S&ME’s Proposal No. P4930D-09V, dated June 3, 2011, and as authorized by
NCDENR’s Task Authorization No. 05, dated June 6, 2011, within NCDENR’s Contract
No. 16-1713-2C for the Central Region.

S&ME’s approved Scope of Services for this Task Authorization was to complete a
Phase II Limited Site Assessment (LSA), which included preparing a health and safety
plan, conducting a receptor survey, installing five groundwater monitor wells (two source
area monitor wells (MW-1 and MW-2), one up-gradient monitor well (MW-3) and two
down-gradient monitor wells (MW-4 and MW-5)), collecting soil samples from each
source area borehole (MW-1 and MW-2), collecting one groundwater sample from each
monitor well, measuring elevations of the five newly installed groundwater monitoring
wells and preparing this Phase II LSA report. S&ME completed the following scope of
services:

 Installed five groundwater monitor wells (MW-1 to 34.6 ft. bgs, MW-2 to
31.15 ft. bgs, MW-3 to 26.10 ft. bgs, MW-4 to 28.40 ft. bgs, and MW-5 to
31.15 ft. bgs);
 Collected two soil samples from each source area boring (MW-1 and MW-
2);
 Sampled five groundwater monitoring wells (MW-1 through MW-5);
 measured elevations of five groundwater monitoring wells (MW-1 through
MW-5);
 Conducted a site reconnaissance and receptor survey; and,
 Prepared this Phase II LSA Report.

Phase II Limited Site Assessment Report S&ME Project No. 1354-09-276D
TF-15929 – Charles Berryman Property, Moncure, Chatham County, NC September 12, 2011
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2.0 SITE HISTORY

The Charles Berryman Property site is located at 898 Old Highway US-1 in Moncure,
Chatham County, North Carolina. The site is a residential property with no indications of
a gasoline retail facility. The approximate central coordinates of the site are 35º 37’
22.40” north latitude and 79º 04’ 36.70” west longitude. A vicinity map of the site is
shown on Figure 1, and the site and pertinent features are shown on Figure 2.

According to a letter from the Chatham County Public Works to the North Carolina
Department of Transportation on November 6, 1992, Chatham County personnel
encountered an abandoned underground storage tank (UST), and potentially petroleum-
contaminated soil during installation of a fiber optic telephone line on September 9, 1992.
Since the encountered UST was adjacent to a 6-inch PVC water line, water samples were
collected from the adjacent residences, and analyzed for benzene, toluene, ethylbenzene,
and total xylenes. According to the letter, the tests showed no appreciable levels in the
water samples. Addresses of the adjacent residences, water sample collection locations
and laboratory results of the water samples were not included in the information provided
to S&ME.

A letter report prepared on February 2, 1993 by SGI Associates states that on January 12,
1993, one hand auger boring (B-1) was advanced to a depth of 6 feet below ground
surface (ft. bgs) between the UST and the Chatham County Water Line. Soil samples
were collected at depths of 3 and 5 ft. bgs, respectively. The soil samples were analyzed
for total petroleum hydrocarbons (TPH) gasoline range organics (GRO). The laboratory
analytical results of these soil samples indicated that TPH-GRO was detected in the 3-
foot soil sample at a concentration of 9.93 milligrams per kilogram (mg/Kg), and in the
5-foot soil sample at a concentration of 218 mg/Kg. The letter report recommended
removing the UST.

The SGI report also stated that a second area of suspected contamination was identified.
The abandoned country store (Dupree’s Grocery) had a fuel dispenser in front of the store
and it was not known whether a UST remained at the facility. Two additional soil
borings were advanced to a depth of six ft. bgs in the area of the abandoned store.
According to the report, “soil generated from the borings did not exhibit any apparent
characteristics of petroleum hydrocarbons”. Therefore soil samples from the borings
were not submitted for laboratory analysis.

In an effort to determine the existence of a gasoline service station associated with the
former country store, S&ME obtained historical aerial photographs (1955, 1960 and
1991) of the site. Historical aerial photographs of the site indicated the presence of two
buildings on the property in 1955 and 1960. The 1991 aerial photograph only depicted
one building on the property.

On December 15, 2009, S&ME completed a time domain electromagnetic (TDEM) and a
ground penetrating radar (GPR) survey of the suspected tank location and adjacent area.
S&ME identified two subsurface anomalies based on TDEM and GPR data. Anomaly #1
Phase II Limited Site Assessment Report S&ME Project No. 1354-09-276D
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was indicative of a petroleum-type UST and was indicated to be approximately 17 feet
from the curb at a depth of 2.5 feet bgs. Anomaly #2 was indicative of a small UST,
possibly kerosene or heating oil and is located approximately 30 feet from the curb.
Hand auger probes in the vicinity of anomaly #1 confirmed the presence of a metal
structure below the surface. This information was presented to NCDENR in S&ME’s
report, Limited Geophysical Survey Report, Dated January 29, 2010.

Between April 5 and 7, 2010, two 550-gallon petroleum USTs (UST-2 and UST-3) and
one 15,000-gallon gasoline UST (UST-1) were excavated and removed from the site by
EVO Corporation under the direction of S&ME. The fuel dispensing product supply/vent
lines were also removed at this time. During the removal of the USTs, approximately
9,875 gallons of residual liquids that were pumped from the USTs were properly
disposed of by EVO. Approximately 144.60 tons of petroleum contaminated soils were
excavated and removed from the site. The soils were disposed at Soilworks, Inc., in
Selma, North Carolina. The limits of the excavation associated with UST-2 and UST-3
were approximately 16 feet long by approximately 10 feet wide by five feet deep. The
limits of the excavation associated with UST-1 were approximately 29 feet long by
approximately 15 feet wide by 13 feet deep. Following the removal of the USTs, S&ME
collected eight post-excavation confirmatory soil samples (two beneath each of the 550-
gallon USTs and four from the excavation sidewalls around UST-1). Accumulated water
in the excavation precluded the collection of soil samples beneath the large UST (UST-1)
as required by the guidelines. The laboratory analytical results of the soil samples
indicated TPH-DRO was present in the sample collected on the south side beneath UST-3
(UST-3B) at a concentration (10.3 mg/Kg) slightly exceeding the NCDENR Action Level
of 10. Additional laboratory analyses of this sample indicated that one carbon fraction
was detected in concentrations well below the Residential MSCCs.
Phase II Limited Site Assessment Report S&ME Project No. 1354-09-276D
TF-15929 – Charles Berryman Property, Moncure, Chatham County, NC September 12, 2011
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2.0 RECEPTOR INFORMATION

S&ME, Inc., (S&ME) performed a receptor study in general accordance with the
NCDENR Guidelines for Assessment and Correction Action, December 2008
(Guidelines). The Limited Site Assessment Risk Classification and Land Use Form is
included in Appendix I. Information pertaining to the receptors identified within 1,500
feet of the subject site is summarized below. Figure 3 shows the locations of receptors
located within approximately 1,500 feet of the former UST location. A photograph log of
the site is included in Appendix II.

2.1 Water Supply Wells

On July 13, 2011, S&ME personnel conducted a site reconnaissance and receptor survey
for the Charles Berryman Property. During the receptor survey, S&ME identified 22
water supply wells within 1,500 feet of the source area. The results of the receptor
survey indicated that; 6 of the 22 water supply wells appear to be used as a source of
potable water (WSW-5, WSW-8, WSW-9, WSW-10, WSW-19 and WSW-20), three
wells are reportedly used for irrigation only (WSW-11, WSW-15 and WSW-16), nine
wells are/appear to be inactive (WSW-2, WSW-3, WSW-4, WSW-6, WSW-12, WSW-
13, WSW-14, WSW-17, WSW-18, WSW-20 and WSW-21) and one well (WSW-1) was
identified, but the wells use could not be confirmed. According to one of the letters
returned to S&ME, two unused water supply wells are located on a parcel of land (Parcel
ID No. 9678-62-7543) located to the northwest of the subject site (WSW-21 and WSW-
22). On August 31, 2011, S&ME personnel returned to the site in an attempt to locate the
water supply wells indicted in the letter. The indicated water supply wells were not
located. Municipal water connections and fire hydrants were identified throughout the
search radius of the receptor survey. No additional water supply wells were noted during
the receptor survey update.

The letters requesting water supply well information were mailed to 110 addresses
located within 1,500 feet of the subject site. To date, 39 responses have been received. If
information is received by S&ME that requires an update to the receptor survey, S&ME
will submit an addendum to this report. A copy of the Request for Water Supply Well
Information Letter and the responses to the letter received by S&ME are included in
Appendix III. Information pertaining to the water supply wells and adjacent property
owner information is included in Table 1.

2.2 Public Water Supplies

S&ME personnel observed water meters and fire hydrants along all roadways located
within 1,500 feet of the subject property. According to the Chatham County Public
Works - Utilities and Water Division, potable water is available to all properties within
1,500 feet of the site. Chatham County purchases water for consumption from the City of
Phase II Limited Site Assessment Report S&ME Project No. 1354-09-276D
TF-15929 – Charles Berryman Property, Moncure, Chatham County, NC September 12, 2011
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Sanford and also obtains water from Jordan Lake. None of these municipal water supply
sources are located within 1,500 feet of the subject property.
2.3 Surface Water

According to the 1993 Moncure NC and 1993 Merry Oaks NC USGS Quadrangle Maps
and site reconnaissance completed as part of the receptor survey completed on July 13,
2011, two fresh water ponds and one intermittent tributary of the Deep River were
located within 1,500 feet of the subject property. The first pond is located approximately
760 feet to the north-northeast of the subject site. The second smaller pond is located
approximately 1,350 to the southeast of the subject site. Two branches of the Goldmine
Branch Creek are located within 1,500 feet of the subject site. The nearest branch of the
creek is located approximately 330 ft. to the east with the other branch located
approximately 1,080 feet to the east of the subject site. The Deep River is located
approximately 3,300 feet to the South of the subject site. The surface water locations are
indicated on Figure 1 and Figure 3.

2.4 Wellhead Protection Areas

On September 6, 2011, S&ME personnel accessed the NCDENR Wellhead Protection
Program website at <http://swap.deh.enr.state.nc.us/swap_app/viewer.htm>. No SWAP
reports exist for the small community of Moncure. According to the ARC IMS Viewer
map for the community of Moncure, the site is not located within a designated protected
wellhead area. The nearest public water supply well (Jordan Lake) is located
approximately five 1.5 miles north of the subject site at its nearest point.

2.5 Subsurface Structures

Shallow drainage ditches are present on the western portion of the property. Municipal
water and sewer lines are located along US Old Highway 1 to the north of the subject
property. No additional subsurface structures other than the USTs, such as vaults or
basements, were identified on the site and adjoining properties.

2.6 Property Owners and Occupants

The names and addresses of the property owners and occupants within and contiguous to
the site are summarized in Table 1. These properties are identified numerically on the
receptor survey map which is included as Figure 3.

According to the Chatham County GIS website, the site is zoned as B-1 Mixed
residential-small business. The properties surrounding the site are zoned as RA-1
residential and include single-family residences.

Phase II Limited Site Assessment Report S&ME Project No. 1354-09-276D
TF-15929 – Charles Berryman Property, Moncure, Chatham County, NC September 12, 2011
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2.7 Risk Classification

Based on the information from the receptor survey and the laboratory data present in this
report, the site meets NCDENR’s criteria for a classification as High Risk site, as three
water supply wells (WSW-1, WSW-2 and WSW-3) were located within 250 feet of the
source area and three water supply wells (WSW-5, WSW-8 and WSW-9) were identified
as sources of drinking water located within 1,000 feet of the source area.

3.0 SITE GEOLOGY AND HYDROGEOLOGY

According to the Geologic Map of North Carolina, dated 1985, the site is located within
the Triassic basin of the Piedmont Physiographical Region of North Carolina, which is
located between the Carolina Slate Belt and the Coastal Plain Region. More specifically,
the site is located within the Pekin Formation of the Chatham Group. The primary rock
type of this formation is sandstone, but conglomerates and mudstone can be found in the
area of the project site.

The subject site is located near Moncure, North Carolina which is situated approximately
three miles east of the Carolina Slate Belt and approximately 40 miles west of the Fall
Line or boundary between the Piedmont Upland and the Coastal Plain. The site is located
within the Triassic Basin where the Pekin Formation is comprised of conglomerate,
sandstone, and mudstone. The Triassic Age Pekin Formation is overlain by yellow
orange brown sands, silts and clays. Groundwater occurs in perched zones above the
bedrock or in the more permeable sandstone and conglomerate units. Groundwater also
occurs in mudstone units; however, groundwater mobility is slower unless weathered
zones, joints, or fractures are present.

During the current site investigation, groundwater was encountered much deeper than
expected for this area. A very hard silt with alternating layers of partially weathered rock
was encountered at depths ranging from 24 to 32 ft. bgs across the site. Air rotary
drilling was used to reach groundwater across the site to termination depths ranging from
26 to 35 ft. bgs. Upon termination of drilling, groundwater came into the borehole
(presumably through fractures) to depths ranging from 12.82 ft. bgs in MW-3 to 17.36 ft.
bgs in MW-5, thus indicating that groundwater in this area appears to be connected to the
water table aquifer under confined conditions. The groundwater measurements from the
July 13, 2011 sampling event are summarized in Table 4.

3.1 Soil Lithology

According to the Soil Survey of Chatham County, North Carolina, prepared by the United
States Department of Agriculture and the Natural Resources Conservation Service
(2006), surficial soils in the vicinity of the site have been classified as Mayodan fine
sandy loam. The Mayodan series consists of somewhat well drained soils with slopes of
six to ten percent.
Phase II Limited Site Assessment Report S&ME Project No. 1354-09-276D
TF-15929 – Charles Berryman Property, Moncure, Chatham County, NC September 12, 2011
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Soils encountered during the removal of the USTs consisted of mainly fill material. As
the excavation continued in the eastern direction, native soils were encountered that were
fairly consistent with the description of the series described above. A tan to light brown
fine sandy loam was encountered between two feet bgs and thirteen ft. bgs at the base of
the excavation. Both during the excavation and upon removal of the large UST, it was
assumed that groundwater was identified at the base of the UST (approximately 13 ft.
bgs). Based upon the soils encountered during drilling activities, it is now believed that
the water encountered in the excavation was likely from the former UST that was full of
water at the time of removal. The soils encountered across the site were similar between
well locations. Typically, brownish/orange silty sand was encountered between the
ground surface and approximately two-three ft. bgs. A light red to orange clayey silt was
observed at a depth extending between three to twenty ft. bgs, changing over to a fine
grey to tan silt to depths ranging from 21 ft. bgs in MW-1 to 32 ft. bgs in MW-5. S&ME
drillers encountered auger refusal on partially weathered rock at 24.5 ft. bgs in MW-1, at
21 ft. bgs in MW-2, at 27’ in MW-3, at 32 ft. bgs in MW-4 and at 25 ft. bgs in MW-5.
After allowing a period of time for groundwater to enter the wells, no indications of
groundwater were indicated in the wells with the exception of MW-4 (32 ft. bgs). To
obtain groundwater samples, an air hammer was retrofitted to the Geoprobe to air rotor
through the hard silt/partially weathered rock. Drilling continued at these locations until
indications of water were observed in MW-1, MW-2 MW-3 and MW-5. It is believed
that a water bearing zone/rock fracture was encountered across the site at approximately
29 ft. bgs.

During this investigation a total of five soil borings were completed. The five borings
were converted to groundwater monitor wells (MW-1 through MW-5). Soil Samples
were collected during the installation of monitoring wells MW-1 and MW-2. No soil
samples were collected from MW-3, MW-4 and MW-5. The location of soil borings and
corresponding monitor wells are indicated on Figure 2. The soil boring logs and well
construction records are included in Appendix IV.

3.2 Groundwater Flow and Hydraulic Gradient

S&ME personnel used an electronic water level indicator to measure the depth-to-
groundwater from the top of the groundwater monitoring wells MW-1 through MW-5 on
July 13, 2011. Groundwater was measured at a range of 17.82 feet below the top of casing
(MW-3) and 17.36 feet below the top of casing (MW-5). Depth to groundwater
measurements were obtained by lowering the device into the well until the audible tone
indicated that the water surface had been encountered, at which point a measurement was
taken at the top of the riser pipe or top of casing (T.O.C.). All measurements were recorded
to the nearest 0.01 foot.

The groundwater level measurements from the July 13, 2011 sampling event are
summarized in Table 2. S&ME returned to the site on July 14, 2011 to obtain another full
round of stabilized water levels after allowing the groundwater in the newly installed
wells to equilibrate. The water level measurements collected on July 14, 2011 were used to
Phase II Limited Site Assessment Report S&ME Project No. 1354-09-276D
TF-15929 – Charles Berryman Property, Moncure, Chatham County, NC September 12, 2011
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prepare the groundwater potentiometric map (Figure 4). Based on the groundwater
elevations, the groundwater flow direction is generally to the southeast (towards MW-5)
with a gradient of approximately 0.0485 ft/ft.

4.0 SAMPLING RESULTS

The project was performed under a site-specific health and safety plan prepared by
S&ME. Field activities were performed in general accordance with the procedures
outlined in the Guidelines. The investigative derived wastes (IDW), such as soil cuttings,
decon water, and purge water, that were generated during the field activities were
disposed in accordance with the procedures specified in the Guidelines. The purge water
and soil cuttings were spread on the ground at the site.

Equipment used to advance the borings and to collect samples was decontaminated
before and after its use to minimize the potential transfer of contaminated media.

4.1 Soil Sampling Methodology

Between July 11th &13th, 2011, the soil borings for monitor wells MW-1 through MW-5
were advanced using a track-mounted Geoprobe® using 4-1/4-inch hollow-stem augers.
The soil boring for MW-1 was advanced in the vicinity of the former 15,000-gallon
gasoline UST (UST-1). The soil boring for MW-2 was advanced in the vicinity of the
former 550-gallon USTs (UST-2 and UST-3). The soil boring for MW-3 was located
along the eastern edge of the Berryman property as an assumed up-gradient location.
The soil borings for MW-4 and MW-5 were located to the south and southeast of the
former USTs to act as down-gradient well locations.

During the installation of the soil borings for MW-1 and MW-2, subsurface soil samples
were continuously collected in four-foot long macro core samplers that were advanced
prior to drilling with the hollow stem augers. Soil recovered in the sample tubes was
classified on-site by S&ME personnel. The first soil samples encountered beneath the
former USTs (native soil beneath the fill material) were collected (SB-1 at 11-13 ft. bgs
and SB-2 at 6-8 ft. bgs). A second set of samples were also collected for laboratory
analysis approximately 10 feet below this sample depth (SB-1 at 21-23 ft. bgs and SB-2
at 16-18 ft. bgs) to satisfy the LSA requirements. The four soil samples were shipped
under standard Chain-of-Custody procedures to Environmental Science Corporation
laboratories (ESC) of Mount Juliet Tennessee, a North Carolina certified laboratory.

The soil samples associated with SB-1 were analyzed for VOCs using EPA Method
8260B and volatile petroleum hydrocarbons (VPH) using Massachusetts Department of
Environmental Protection (MADEP) Methods. The soil samples associated with SB-2
were analyzed for VOCs using EPA Method 8260B, for semi-volatile organic compounds
(SVOCs) by EPA Method 8270C, for VPH and extractable petroleum hydrocarbons
(EPH) using MADEP Methods.
Phase II Limited Site Assessment Report S&ME Project No. 1354-09-276D
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4.2 Soil Sampling Results

Laboratory analytical results indicated that no VOCs or SVOCs were detected above the
laboratory method detection limits. Concentrations of the VPH aliphatics C5-C8 (3.1
mg/Kg), C9-C12 (30.1 mg/Kg) and the VPH aromatics C9-C10 (5.1 mg/Kg) were
detected in the soil sample SB-1 (MW-1) collected from 11-13 ft bgs above the
laboratory method detection limit, but below their respective soil-to-groundwater
maximum soil contaminant concentrations (MSCCs) of 72 mg/Kg, 3,300 mg/Kg and 34
mg/Kg. No other VOCs, SVOCs, and VPH/EPH concentrations were detected in any of
the soil samples collected during this investigation.

A summary of the laboratory analytical results for the soil samples collected during this
investigation are presented in Table 3. The laboratory analytical report for the soil
samples is included in Appendix V.

4.3 Groundwater Sampling Methodology

Between July 11-13, 2011, S&ME personnel directed the drill crew to continue to
advance each of the soil borings into the groundwater table. At several locations, a
resistive unit (partially weathered rock) was encountered and drilled through to obtain
ground water. Due to the possibility that fractures with deep groundwater under pressure
could be encountered that may force water up into the wells, a longer section of well
screen was installed at each location to ensure that groundwater could be sampled from
within the screened interval of the monitor well. The soil borings were converted into
groundwater monitoring wells (MW-1 through MW-5) by installing either a fifteen or
twenty-foot long section of two-inch diameter polyvinyl chloride (PVC) slotted (0.010-
inch) screen and sufficient riser pipe to bring the well to ground surface. The wells were
completed by placing #2 type filter sand in the boring annulus to approximately two feet
above the screen section (sand pack). Approximately one foot of hydrated bentonite was
tremied above the sand pack, and neat cement grout was then tremied from the top of the
bentonite to approximately six inches bgs. The new wells extend to the ground surface
where they were encased with a flush mount protective steel casing with bolted manhole
cover. A four-inch thick concrete pad was used to finish the surface of the wells. The
monitoring well construction details are summarized in Table 4.

Monitoring well MW-1 was installed to a depth of 31 ft bgs, MW-2 to 29 ft bgs, MW-3
to 27 ft bgs, MW-4 to 32 ft bgs and MW-5 to 35 ft bgs.

Upon completion of the well installation, S&ME personnel developed the monitor wells
using new polyethylene bailers and peristaltic pumps wherever possible to remove
sediment accumulation in the well and surrounding sand pack caused during the well
installation.

On July 13, 2011, S&ME personnel measured groundwater levels and collected
groundwater samples from the five newly installed wells (MW-1 through MW-5). Prior
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to sampling, the monitor wells were purged by evacuating groundwater from the well
until the groundwater became relatively clear using new polyethylene bailers. A
minimum of three volumes of groundwater was purged from the monitor wells to remove
stagnant water. Field parameters were measured after each well volume was purged for
pH, temperature, and specific conductance. Groundwater samples were collected from
the monitor wells using a new polyethylene bailer. S&ME returned to the site on July 14,
2011 to obtain another full round of stabilized water levels after allowing the
groundwater in the newly installed wells to equilibrate.

Containers provided by the laboratory were filled directly from the bailer, labeled, and
placed in an insulated cooler with ice for transport to the laboratory for analysis.

Sample management was documented from collection through delivery to ESC for
analysis following standard chain-of-custody procedures. The laboratory analysis
requested varied between monitor wells based upon historical sampling data obtained
during tank closure activities and from the location of the previously identified USTs.
The groundwater sample from MW-1 was analyzed for VOCs by EPA Method 6200B,
for VPH by MADEP Methods and lead by extraction Method 3030C. The groundwater
sample from MW-2 was analyzed for VOCs by EPA Method 6200B, SVOCs by EPA
Method 625 and VPH and EPH. The groundwater samples from the remaining wells
(MW-3, MW-4 and MW-5) were only analyzed for VOCs by EPA Method 6200B.

4.4 Groundwater Sampling Results

The laboratory analytical results of the groundwater samples collected on July 13, 2011
indicated that the following Constituents of Concern (COCs) were detected at
concentrations greater than the NCAC 2L Standard:

 Benzene: in MW-1, MW-2, MW-3, MW-4 and MW-5;
 Naphthalene: in MW-1, MW-2 and MW-4;
 1,2-Dichloroethane: in MW-1, MW-2, MW-3, MW-4 and MW-5; and,
 Diisopropyl ether: in MW-1 and MW-2.

Several other constituents were detected above the laboratory method detection limits,
but below the 2L Standards in monitoring wells MW-1, MW-2, MW-3, MW-4 and MW-
5. No constituents were detected above their respective GCLs. A summary of current
and historical groundwater analytical results and a comparison to NCDENR’s regulatory
standards is included on Table 5. The groundwater constituent concentrations are
presented on Figure 5. A copy of the laboratory analytical results and chain-of-custody
form is included in Appendix V. A copy of the Sample Collection Summary Sheet is
included in Appendix VI.

Phase II Limited Site Assessment Report S&ME Project No. 1354-09-276D
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5.0 CONCLUSIONS AND RECOMMENDATIONS

A Phase II LSA was conducted at the Charles Berryman Property located at 898 Old
Highway US-1 in Moncure, Chatham County, North Carolina to assess potential
petroleum impact to soil and groundwater from a former 15,000-gallon gasoline UST and
two 550-gallon USTs (unknown contents). The findings at the site are as follows:

 The results of the receptor survey indicated that municipal water is available to the
site and most properties within 1,500 feet of the site. Based on the results of the
receptor survey, the site meets the criteria to be ranked as a “High” risk site. Three
water supply wells (WSW-1, WSW-2 and WSW-3) were located within 250 feet of
the source area and three water supply wells (WSW-5, WSW-8 and WSW-9) were
identified as sources of drinking water located within 1,000 feet of the source area.

 Between July 11-13, 2011, S&ME personnel installed a total of five soil borings. The
five borings were converted to groundwater monitor wells (MW-1 through MW-5).
Monitoring well MW-1 was installed to a depth of 31 ft bgs, MW-2 to 29 ft bgs,
MW-3 to 27 ft bgs, MW-4 to 32 ft bgs and MW-5 to 35 ft bgs. Soil Samples were
collected during the installation of monitoring wells MW-1 and MW-2. No soil
samples were collected from MW-3, MW-4 and MW-5.

 A total of four soil samples (SB-1 at 11-13 ft. bgs, SB-1 at 21-23 ft. bgs, SB-2 at 6-8
ft. bgs and SB-2 at 13.5-15 ft. bgs) were collected during the installation of the two
monitor wells located in the former UST pits (MW-1 and MW-2). The Laboratory
analytical data indicated that no VOCs or SVOCs were detected above the laboratory
method detection limits. Concentrations of the VPH aliphatics C5-C8 (3.1 mg/Kg),
C9-C12 (30.1 mg/Kg) and the VPH aromatics C9-C10 (5.1 mg/Kg) were detected in
the soil sample SB-1 (MW-1) collected from 11-13 ft bgs above the laboratory
method detection limit, but below their respective soil-to-groundwater MSCCs. No
other VOCs, SVOCs, and VPH/EPH concentrations were detected in any of the soil
samples collected during this investigation.

 On July 13, 2011, S&ME collected groundwater samples from five newly installed
groundwater monitor wells (MW-1, MW-2, MW-3, MW-4 and MW-5). Laboratory
analytical results of the groundwater samples indicated that several COCs were
detected at concentrations greater than the NCAC 2L Standards in all five monitor
wells.

This information is provided to allow the NCDENR to conduct an evaluation of
environmental risk and to determine a risk ranking. The risk ranking number will
determine whether or not NCDENR will direct further assessment activities.

S&ME recommends:

 Install additional monitor wells to delineate the horizontal extent of petroleum
contamination in groundwater.
Phase II Limited Site Assessment Report S&ME Project No. 1354-09-276D
TF-15929 – Charles Berryman Property, Moncure, Chatham County, NC September 12, 2011
12

 Conduct water supply well sampling of nearby selected wells.

To reduce the risk at the site, it may be beneficial to contact the owners of the near-by
water supply wells that are in use, and explain the benefits of connecting to a municipal
water supply. If the water supply well owners agree, water supply wells may then be
abandoned, and the site risk ranking reduced.

TABLES
Adjacent Property Owners Page 1 of 1
Map ID Parcel Number Owner Address Usage
Distance from source
area of release
(feet)
Site 9678-71-1577 805 Cool Springs Road
Sanford, NC 27559 Vacant Residental Lot Site
1 9678-71-2427 P.O. BOX 145
Moncure, NC 27559
Vacant Residental
Property 130 South
2 9678-71-2598 P.O. BOX 155
Moncure, NC 27559 Residence 80 East
3 9678-71-2777 P.O. BOX 124
Moncure, NC 27559 Vacant Lot 125 Northeast
4 9678-71-1797 805 Cool Springs RoadSanford, NC 27559 Gas Station 60 North
5 9678-62-7543 5204 Rembert Drive
Raleigh, NC 27612 Vacant Wooded Lot 110 Northeast
6 9678-71-0403 208 Manning Drive
Charlotte, NC 28209 Residence 70 West
Private Water Supply Wells
Map ID
/Well ID Parcel Number Well Owner Property Address Owner Address Phone Number Well Use Well Depth
(ft bgs)
Well Casing
Depth(ft. bgs)
Well Screen Interval
(x to yft. bgs)
Distance from source
area of release(feet)Comment
WSW-1 9678-71-1577 Judd, Raymond Heirs 890 Old US 1
Moncure, NC 27559
P.O. BOX 145
Moncure, NC 27559 919-545-0058 Unknown Unknown Unknown Unknown 120 South Propertyappears to be connected to
municipal water.
WSW-2 9678-71-1577 Judd, Raymond Heirs 890 Old US 1
Moncure, NC 27559
P.O. BOX 145
Moncure, NC 27559 919-545-0058 Not in use - DryWell 15 Hand Dug Well NA 175 Southeast Propertyappears to be connected to
municipal water.
WSW-3 9678-71-1577 Judd, Raymond Heirs 890 Old US 1
Moncure, NC 27559
P.O. BOX 145
Moncure, NC 27559 919-545-0058 Unknown Unknown Unknown Unknown 200 Southeast Propertyappears to be connected to
municipal water.
WSW-4 9678-71-4543 Brown, William Ronald Old US 1
Moncure, NC 27559
P.O. BOX 347
Moncure, NC 27559 919-542-3779 Not in use Unknown Unknown Unknown 290 Southeast Abandoned property
WSW-5 9678-71-5917 Berryman, Roy& Marilyn 983 Old US 1
Moncure, NC 27559
981 Old US 1
Moncure, NC 27559 919-542-2657 Drinking Unknown Unknown Unknown 575 East-northeast House in the back of the propertyis
using the well (983 Old US 1).
WSW-6 9678-71-2908 Ray, Billie T.38 Moncure SchoolRoad Moncure, NC P.O. BOX 124Moncure, NC 27559 919-542-3040 Not in use Unknown Unknown Unknown 325 Northeast Propertyconnected to municipalwater.
WSW-7 9678-72-2295 Brown, William Ronald 104 Moncure School
Road Moncure, NC
P.O. BOX 347
Moncure, NC 27559 919-542-3779 Bathing/Dishes Unknown Unknown Unknown 600 North Reportedlydrinks bottled water.
Second well on the propertywas
WSW-8 9678-72-1540 Jefferies, Kenneth 140 Moncure School
Road Moncure, NC
140 Moncure School Road
Moncure, NC 27559 919-542-7205 Drinking Approximately80' Approximately60' Unknown 825 North-northeast Well installed in the 1950's.
WSW-9 9678-70-0828 Dixon, Marietta Moore 145 Post Office Road
Moncure, NC 27559
150 Fairview Forest Drive Fairview,
NC 28730 919-545-0578 Drinking Deep well, owner
not sure of total Unknown Unknown 810 Southwest Tennant use well for drinking
(Anna Wilder 919-545-0578)
WSW-10 9678-70-2631 Courter, Edward K.52 George RayRoad
Moncure, NC 27559
220 Plank Road Bloomingdale, NY
12913 518-946-2565 Drinking/Irrigation 50 Unknown Unknown 1,030 South-southwest Well installed in the 1960's.
WSW-11 9678-70-1444 Courter, Edward K.42 George RayRoad
Moncure, NC 27559
220 Plank Road Bloomingdale, NY
12913 518-946-2565 Irrigation 25 Unknown Unknown 1,100 South-southwest Propertyis connected to municipal
water.
WSW-12 9678-61-5088 Wilson, Noah Jr.70 Post Office Road
Moncure, NC 27559
268 Log Barn Road Pittsboro, NC
27312 Unknown Not in use Unknown Unknown Unknown 790 Southwest Connected to municipal water.
WSW-13 9678-61-5250 Tiede, Karen E.48 Post Office RoadMoncure, NC 27559 48 Post Office Road Moncure, NC27559 919-545-0799 Not in use(Non-functional)Unknown Unknown Unknown 750 West-southwest Well installed in the 1940's.Connected to municipal water.
WSW-14 9678-61-5250 Tiede, Karen E.48 Post Office Road
Moncure, NC 27559
48 Post Office Road Moncure, NC
27559 919-545-0799 Not in use
(Non-functional)Unknown Unknown Unknown 735 West-southwest Well iInstalled in the 1940's. Well
has been capped. Connected to
WSW-15 9678-60-0725 Fiks, Gerald B.72 Jones Road
Moncure, NC 27559
P.O. BOX 312
Moncure, NC 27559 919-389-2585 Irrigation Unknown Unknown Unknown 1,300 Southwest Connected to municipal water.
WSW-16 9678-50-9940 Hunter, Jane Chruchfield 44 Jones Road
Moncure, NC 27559
P.O. BOX 282
Moncure, NC 27559 919-542-2990 Irrigation Unknown Unknown Unknown 1,230 West-southwest Connected to municipal water.
WSW-17 9678-61-4960 Cotten, PeggyAnn Trustee 47 cotten Acre RoadMoncure, NC 27599 P.O. BOX 4Moncure, NC 27559 919-542-3812 or919-542-1685 Reported as not in use bythe park manager Unknown Unknown Unknown 650 West-northwest Reportedlyconnected to municipalwater.
WSW-18 9678-62-4298 Cotten, Thomas Rudolph
Trust
145 cotten Acre Road
Moncure, NC 27599
P.O. BOX 4
Moncure, NC 27559
919-542-3812 or
919-542-1685
Reported as not in use by
the park manager Unknown Unknown Unknown 750 West-northwest Reportedlyconnected to municipal
water.
WSW-19 9678-62-4887 Goins Janette L.10 Goins Road
Moncure, NC 27559
P.O. BOX 101
Moncure, NC 27559 919-545-4715 Drinking Unknown Unknown Unknown 1,400 Northwest Well installed in 1981.
WSW-20 9678-52-7692 Cotten, PeggyAnn Trustee 390 cotten Acre RoadMoncure, NC 27599 P.O. BOX 4Moncure, NC 27559 919-542-3812 or919-542-1685 Drinking Unknown Unknown Unknown 1,490 Northwest
WSW-21 9678-62-7543 Lowery& Webster
Properties, LLC.
Moncure School Road
Moncure, NC 27599
5204 Rembert Drive
Raleigh, NC 27612 919-781-3539 Unknown Unknown Unknown Unknown Northwest / Unknown
WSW-22 9678-62-7543 Lowery& Webster
Properties, LLC.
Moncure School Road
Moncure, NC 27599
5204 Rembert Drive
Raleigh, NC 27612 919-781-3539 Unknown Unknown Unknown Unknown Northwest / Unknown
Notes:
1. ft. bgs - Feet Below Ground Surface
2. Refer toFigure 3for Adjacent Property Owner Map.3. Property address information obtained from Chatham County GIS Website on September 2, 2011.
Vacant Lot Ray, Billie T.
According to the propertyowner two
old unused wells exist on theproperty. These wells were not
located during the receptor survey.
Commercial - Ray's Supermarket (Citgo Gas
Station) / 901 Old US 1 Moncure, NC 27559 Stone, Ronald Kevin
Residential / 832 Old US 1 Moncure, NC 27559 Goodwin & Goodwin Enterprises, LLC.
Lowery& Webster Properties, LLC.Vacant Wooded Lot
Residential / 890 Old US 1 Moncure, NC 27559 Judd, Raymond Heirs
Residential / 916 Old US 1 Moncure, NC 27559 Dupree, Beatrice Heirs - C/O Dupree, James
S&ME Project No. 1354-09-276D
Description/Property Address Contact/Telephone Number Comment
Residential / 898 Old US 1 Moncure, NC 27559 Stone, Ronald Kevin
Table 1
Receptor Information and Adjacent Property OwnersCharles Berryman Property898 Old US-1 (SR 1011)Moncure, Chatham County, North CarolinaNCDENR Incident No. 15929
Well ID Date Top of Casing Elevation
(ft-rel)
Depth to Water
(ft-BTOC)
Free Product Thickness
(ft)
Groundwater Elevation
(ft-rel)
7/13/2011 14.68 ND 84.94
7/14/2011 14.31 ND 85.31
7/13/2011 14.25 ND 84.74
7/14/2011 13.85 ND 85.14
7/13/2011 12.82 ND 85.19
7/14/2011 12.53 ND 85.48
7/13/2011 14.35 ND 85.19
7/14/2011 14.15 ND 85.39
7/13/2011 17.36 ND 81.30
7/14/2011 17.11 ND 81.55
Notes:
1. Ft-bgs = feet below ground surface
2. Ft-BTOC = feet below top of casing
3. Ft-rel = feet relative to an assumed datum
4. ND = Not Detected
5. The groundwater elevations collected on July 14, 2011 were used to calculate the groundwater flow direction indicated on Figure 4.
S&ME Project No. 1354-09-276D
Moncure, Chatham County, North Carolina
NCDENR Incident No. 15929
Table 2
Groundwater Elevations
Charles Berryman Property
898 Old US-1 (SR 1011)
99.62
MW-5
MW-1
MW-2
MW-3
MW-4
98.66
99.54
98.01
98.99
VOCs by
EPA 8260
SVOCs by
EPA 8270
ConstituentSpecificConstituentSpecificC5-C8AliphaticsC9-C18AliphaticsC9-C22AromaticsC5-C8AliphaticsC9-C18AliphaticsC19-C36AliphaticsC9-C22AromaticsDate Depth (ft-bgs)
11 - 13D BDL BDL 3.1 30.1 5.1 NA NA NA NA
21-23 BDL BDL <2.5 <2.5 <2.5 NA NA NA NA
6 - 8 BDL BDL <2.9 <2.9 <2.9 <2.9 <12.6 <12.6 <12.6
16 - 18 BDL BDL <2.6 <2.6 <2.6 <2.6 <11.3 <11.3 <11.3
Constituent
Specific
Constituent
Specific 68 540 31 68 540 Considered
Immobile 31
Constituent
Specific
Constituent
Specific 939 1,500 469 939 1,500 31,000 469
Constituent
Specific
Constituent
Specific 24,528 40,000 12,264 24,528 40,000 810000 12,264
Notes:1. Analytes that are not shown were not detected by the method indicated.2. All concentrations are reported in milligrams per kilogram (mg/Kg).
3. MSCC: Maximum Soil Contaminant Concentration
4. Ft-bgs: Feet below ground surface
5. D: The sample was analyzed at a dilution by the laboratory.6. VOCs: Volatile Organic Compounds7. SVOCs: Semi Volatile Organic Compounds
8. MADEP: Massachusetts Department of Environmental Protection
9. VPH: Volatile Petroleum Hydrocarbons
10. EPH: Extractable Petroleum Hydrocarbons11. All samples that exceed the soil-to-groundwater MSCC are shown in Shaded and BOLD fields.12. Concentrations exceeding the laboratory's reporting limits are shown in BOLD fields.
13. NA = Not Analyzed
14. BDL: Below Detection Limits
MADEP VPH/EPH
SB-2
(MW-2)7/12/2011
Contaminant of Concern
Industrial/Commercial Soil Cleanup Levels
Method
Soil to Water MSCCs
Residential Soil Cleanup Levels
Sample ID
SB-1
(MW-1)7/12/2011
S&ME Project No. 1354-09-276D
Charles Berryman Property
Summary of Soil Analytical Results
Table 3
NCDENR Incident No. 15929
Moncure, Chatham County, North Carolina
898 Old US-1 (SR 1011)
MADEP VPH
Well ID Date Installed
(m/dd/yy)
Well Casing Depth
(ft-bgs)
Screened Interval
(x to y ft-bgs)
Total Well Depth
from Top of Casing
(ft.)
Top of Casing
Elevation
(ft-rel)
Well Material Well Diameter
(inches)
MW-1 5/13/2009 0-11.0 11.0-31.0 31 99.62 PVC 2
MW-2 5/14/2009 0-9.0 9.0-29.0 29 98.99 PVC 2
MW-3 7/11/2011 0-12.0 12.0-27.0 27 98.01 PVC 2
MW-4 5/14/2009 0-17.0 17.0-32.0 32 99.54 PVC 2
MW-5 5/14/2009 0-15.0 15.0-35.0 35 98.66 PVC 2
Notes:
1. Ft-bgs: feet below ground surface
2. Ft-BTOC: feet below top of casing
3. ND: Not Detected
4. Ft-rel: feet relative to an assumed datum
5. Elevations measured by S&ME on 7/13/2011 to assumed benchmark elevation of 100 feet (concrete pad next to telephone pole at the northwest corner of the property).
S&ME Project No. 1354-09-276D
Table 4
Monitor Well Construction Details
NCDENR Incident No. 15929
Moncure, Chatham County, North Carolina
898 Old US-1 (SR 1011)
Charles Berryman Property
SVOCs by
EPA 625
Metals by
Method
3030C
Contaminant of
Concern BenzeneChloromethaneEthylbenzeneNaphthaleneMTBE1,2-DichloroethaneDiispropyletherIsopropylbenzenen-Propylbenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenetert-ButylbenzeneTolueneTotalXylenesConstituentSpecificLeadC5-C8AliphaticsC9-C18AliphaticsC9-C22AromaticsC5-C8AliphaticsC9-C18AliphaticsC19-C36AliphaticsC9-C22AromaticsDate
MW-1 7/13/2011 73.1 <1.0 1.5 7.0 <0.50 8.7 87.6 2.5 <0.50 25 4.6 <0.50 <0.50 22.5 NA <5.0 240 327 60.7 NA NA NA NA
MW-2 7/13/2011 70.8 2.8 10.1 6.3 1.7 11.8 93.9 2.8 1.2 15.9 <0.50 <0.50 2.3 57.9 BDL NA - - -331 425 <100 56.3
MW-3 7/13/2011 64.4 <1.0 <0.50 4.3 <0.50 2.7 17.0 2.0 <0.50 <0.50 <0.50 <0.50 <0.50 <1.0 NA NA NA NA NA NA NA NA NA
MW-4 7/13/2011 153 <1.0 8.6 21.8 <0.50 7.1 46.3 9.0 16.9 36 <0.50 1.6 <0.50 17 NA NA NA NA NA NA NA NA NA
MW-5 7/13/2011 8.7 <1.0 <0.50 <2.0 <0.50 6.5 46.9 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <1.0 NA NA NA NA NA NA NA NA NA
1 3 600 6 20 0.4 70 70 70 400 400 70 600 500 Constituent
Specific 15 400 700 200 400 700 10,000 200
5,000 3,000 84,500 6,000 20,000 400 70,000 25,000 30,000 28,500 25,000 15,000 260,000 85,000 Constituent
Specific 15,000 NE NE NE NE NE NE NE
Notes:
1. Analytes that are not shown were not detected for the method.
2. All concentrations are reported in micrograms per liter (µg/L).
3. 2L Standard: North Carolina Groundwater Quality Standards: 15A NCAC 2L.0202
4. VOCs: Volatile Organic Compounds
5. SVOCs: Semi-Volatile Organic Compounds
6. MADEP: Massachusetts Department of Environmental Protection
7. VPH: Volatile Petroleum Hydrocarbons
8. EPH: Extractable Petroleum Hydrocarbons
9. NE: Regulatory standard not established for contaminant
10. All samples that exceed the 2L Standards are shown in Shaded and BOLDfields.
11. Concentrations exceeding the laboratory's reporting limits are shown in BOLDfields.
12. Analysis not requested for parameter.
Summary of Groundwater Sampling Results
Table 5
NCDENR Incident No. 15929
Moncure, Chatham County, North Carolina
898 Old US-1 (SR 1011)
Charles Berryman Property
MADEP VPH MADEP VPH/EPH
Gross Contamination Levels
Sample ID
S&ME Project No. 1354-09-276D
2L Standards
VOCs by EPA 6200B

FIGURES

APPENDIX I

LIMITED SITE ASSESSMENT RISK CLASSIFICATION AND LAND
USE FORM
1
Appendix I Limited Site Assessment Risk Classification and Land Use Form
CHARLES BERRYMAN PROPERTY
898 OLD US 1
MONCURE, CHATHAM COUNTY, NORTH CAROLINA
NCDENR INCIDENT NO. 15929
S&ME PROJECT NO. 1354-09276D
Part I – Groundwater/Surface water/Vapor Impacts
High Risk
1.Has the discharge or release contaminated any water supply well including any used for non-
drinking purposes?UNKNOWN
22 water supply wells were identified within 1,500 feet of the site during site reconnaissance.
It is not known if any of these wells have been sampled.
2.Is a water supply well used for drinking water located within 1,000 feet of the source area the
discharge or release?UNKNOWN
Three confirmed water supply wells were identified as being used for drinking water within
1,000 feet of the site during site reconnaissance.
3.Is a water supply well used for any purpose (e.g., irrigation, washing cars, industrial cooling
water, filling swimming pools) located within 250 feet of the source area of the release or
discharge?YES
Three water supply wells were identified within 250 feet of the source area. The use of these
wells was not confirmed.
4.Does groundwater within 500 feet of the source area of the discharge or release have the
potential for future use in that there is no other source of water supply other than the
groundwater?NO
According to the Town of Moncure Public Utilities Department, municipal water is available to
all residents within the vicinity of the release.
5.Do vapors from the discharge or release pose a threat of explosion because of accumulation
of the vapors in a confined space or pose any other serious threat to public health, public
safety or the environment?UNKNOWN
No vaults or basements were not identified on the site or on adjoining properties. An active
convenience store/gas station is located across old US from the source area. The structure is
block construction on a slab foundation with no contained crawl space. The soil and groundwater
contamination has not been delineated.
2
6.Are there any other factors that would cause the discharge or release to pose an imminent
danger to public health, public safety, or the environment?NO
Intermediate Risk
1.Is a surface water body located within 500 feet of the source area of the discharge or release?
YES
According to the 1993 Moncure NC and 1993 Merry Oaks NC USGS Quadrangle Maps and site
reconnaissance completed as part of the receptor survey completed on July 13, 2011, two fresh
water ponds and one intermittent tributary of the Deep River were located within 1,500 feet of
the subject property. The first pond is located approximately 760 feet to the north-northeast of
the subject site. The second smaller pond is located approximately 1,350 to the southeast of the
subject site. Two branches of the Goldmine Branch Creek are located within 1,500 feet of the
subject site. The nearest branch of the creek is located approximately 330 ft. to the east with the
other branch located approximately 1,080 feet to the east of the subject site. The Deep River is
located approximately 3,300 feet to the South of the subject site.
2.Is the source area of the discharge or release located within a designated wellhead protection
area as defined in 42 USC 300h-7(e)?NO
3.Is the discharge or release located in the Coastal Plain physiographic region as designated on
a map entitled “Geology of North Carolina” published by the department in 1985?NO
As stated in the attached Limited Site Assessment Report, the site is located within the Triassic
basin of the Piedmont Physiographical Region of North Carolina (See Section 3.0).
4.Do the levels of groundwater contamination for any contaminant exceed the gross
contamination levels established by the Department?NO
Part II – Land Use
Property Containing Source Area of Discharge or Release
The questions below pertain to the property containing the source area of the release.
1. Does the property contain one or more primary or secondary residences (permanent or
temporary)?NO
The property is currently vacant.
3
2. Does the property contain a school, daycare center, hospital, playground, park, recreation
area, church, nursing home, or other place of public assembly?NO
3. Does the property contain a commercial (e.g., retail, warehouse, office/business space, etc.)
or industrial (e.g., manufacturing, utilities, industrial research and development,
chemical/petroleum bulk storage, etc.) enterprise, an inactive commercial or industrial
enterprise, or is the land undeveloped?NO
Describe:
4. Do children visit the property?YES
Explain:
There are no protective barriers to prevent children from entering the site.
5. Is access to the property reliably restricted consistent with its use (e.g., by fences, security
personnel, or both)?NO
6. Do pavement, buildings, or other structures cap the contaminated soil?YES
Explain:
The former UST pits are covered by a gravel parking lot. The groundwater contamination has
not been delineated.
If yes, what mechanisms are in place or can be put into place to ensure that the contaminated
soil will remain capped in the foreseeable future? Explain:
7. What is the zoning status of the property?
According to the Chatham County GIS website, the site is zoned as B-1 Mixed residential-small
business. The properties surrounding the site are zoned as RA-1 residential and include single-
family residences.
8. Is the use of the property likely to change in the next 20 years?NO
Explain:
The property is located in front of a residential structure and is not likely to be changed unless
the property is sold and the land is developed.
4
Property Surrounding Source Area of Discharge or Release
The questions below pertain to the area within 1,500 feet of the source area of the discharge or
release (excludes property containing source area of the release):
1. What is the distance from the source area of the release to the nearest primary or secondary
residence (permanent or temporary)?
A residential home is located approximately 150 feet to the south of the source area.
2.What is the distance from the source area of the release to the nearest school, daycare center,
hospital, playground, park, recreation area, church, nursing home, or other place of public
assembly?
The Moncure United Methodist Church is located approximately 630 feet to the southwest of the
site.
3. What is the zoning status of properties in the surrounding area?
According to the Chatham County GIS website, the site is zoned as B-1 Mixed residential-small
business. The properties surrounding the site are zoned as RA-1 residential and include single-
family residences.
4. Briefly characterize the use and activities of the land in the surrounding area:
The site is currently a vacant lot in front of a residential structure. Properties surrounding the
subject site are mainly residential with several undeveloped wooded properties to the southeast.

APPENDIX II

PHOTOGRAPHIC LOG
Phase II Limited Site Assessment Report
Charles Berryman Property - 898 Old US-1 (SR-1011)
Moncure, Chatham County, North Carolina
S&ME Project No. 1354-09-276D
Taken by: G. Paul Date Taken:
7/11/2011 thru 7/14/2011
1
1 Front of Charles Berryman Property
(Facing South).
2 Front of Charles Berryman Property
(Facing Southeast).
3 Front of Charles Berryman Property
(Facing West).
4 Center of site – Setting up on MW-4 location
(Facing Northwest).
Phase II Limited Site Assessment Report
Charles Berryman Property - 898 Old US-1 (SR-1011)
Moncure, Chatham County, North Carolina
S&ME Project No. 1354-09-276D
Taken by: G. Paul Date Taken: 7/11-7/14/2011
2
5 Charles Berryman property left side
(Facing Northwest).
6 Underground utilities around former UST-1
(Facing East).
7 Underground utilities around former UST-1
(Facing West).
8 S&ME driller set-up on MW-4 location
(Facing North).
Phase II Limited Site Assessment Report
Charles Berryman Property - 898 Old US-1 (SR-1011)
Moncure, Chatham County, North Carolina
S&ME Project No. 1354-09-276D
Taken by: G. Paul Date Taken: 7/11-7/14/2011
3
9 Auger refusal at MW-3 location – Waiting for water to
enter the bore hole (Facing East).
10 Proposed location of MW-5
(Facing Southeast).
11 S&ME drillers set-up on MW-1 location
(Facing North).
12 Drilling at MW-2 location
(Facing Northwest).
Phase II Limited Site Assessment Report
Charles Berryman Property - 898 Old US-1 (SR-1011)
Moncure, Chatham County, North Carolina
S&ME Project No. 1354-09-276D
Taken by: G. Paul Date Taken: 7/11-7/14/2011
4
13 Air rotary drilling at MW-4 location
(Facing East).
14 Checking for water at MW-4 location
(Facing East).
15 Air rotary drilling at MW-2 location
(Facing East).
16 S&ME drillers set-up on MW-5 location
(Facing Southeast).
Phase II Limited Site Assessment Report
Charles Berryman Property - 898 Old US-1 (SR-1011)
Moncure, Chatham County, North Carolina
S&ME Project No. 1354-09-276D
Taken by: G. Paul Date Taken: 7/11-7/14/2011
5
17 Off-set from proposed location of MW-4 to avoid utilities.18 Completed MW-3
(Facing East).
19 Developing MW-4 to reduce silt accumulation in the newly
installed monitor well (Facing North).
20 Developing MW-4 to reduce silt accumulation in the newly
installed monitor well (Facing North).
Phase II Limited Site Assessment Report
Charles Berryman Property - 898 Old US-1 (SR-1011)
Moncure, Chatham County, North Carolina
S&ME Project No. 1354-09-276D
Taken by: G. Paul Date Taken: 7/11-7/14/2011
6
21 Completed Monitor Well MW-1
(Facing West).
22 Completed Monitor Well MW-2
(Facing West).
23 Completed Monitor Well MW-3
(Facing East).
24 Completed Monitor Well MW-4
(Facing South).
Phase II Limited Site Assessment Report
Charles Berryman Property - 898 Old US-1 (SR-1011)
Moncure, Chatham County, North Carolina
S&ME Project No. 1354-09-276D
Taken by: G. Paul Date Taken: 7/11-7/14/2011
7
25 Completed Monitor Well MW-5
(Facing Southeast).
26 View of the back of the site showing the location of water
supply well WSW-1 (Facing South).
27 Inside of water supply well WSW-1.28 Location of water supply well WSW-2
(Facing East).
Phase II Limited Site Assessment Report
Charles Berryman Property - 898 Old US-1 (SR-1011)
Moncure, Chatham County, North Carolina
S&ME Project No. 1354-09-276D
Taken by: G. Paul Date Taken: 7/11-7/14/2011
8
29 Inside of water supply well WSW-2.30 Location of water supply well WSW-3
(Facing Southeast).
31 Location of water supply well WSW-4
(Facing Northwest).
32 Cotton’s Camp Ground located to the
Northwest of the subject site.

APPENDIX III

REQUEST FOR WATER SUPPLY WELL INFORMATION
LETTER AND RESPONSES

APPENDIX IV

BORING LOGS AND WELL CONSTRUCTION RECORDS
BORING LOG Project Name:
Job No.
Boring Number:MW-1
Sampling Personnel:Jerry Paul
Date Drilled/Method:7/13/2011 / Geoprobe with Hollow Stem Augers and Air Hammer
Depth to Groundwater:15.2 feet below ground surface
Total Boring Depth:31 feet below ground surface
STRATIFICATION
From To PID FID
0.0 0.5 -- --
0.5 11.0 -- --
11.0 17.0 -- --
17.0 24.5 -- --
24.5 31.0 -- --
Notes:
ft. bgs = Depth in feet below ground surface Depth to water = 15.2 ft. bgs
ft. BTOC = Depth in feet below the top of well casing Total Well Length = 31 ft
PID = Photo-ionization detector (readings in parts per million or ppm) Screen length = 20 ft
FID = Flame-ionization detector (readings in parts per million or ppm) Riser length = 11 ft
-- = No data or parameter not collected Date GW Sample Collected = 7/13/2011
ORGANIC VAPOR
READINGS (ppm)
Gravel
Charles Berryman Property
1354-09-276D
Screen = 20' from 11-31 feet below ground surface.
Riser = 11' from 0-11 feet below ground surface.
Depth (Feet)
Total Well Depth = 31 feet below top of casing.
H2O at TOB = 15.2 feet below top of casing
Soil samples collected beneath the fill material (SB-1 @ 11'-13') and (SB-1 @ 21'-23').
Switched to Air Drilling - Hard grey SILT to partially weathered rock (Conglomerate)
Tan/orange fine SILT Auger refusal @24.5 ft. bgs (Petroleum odor noted from 21'-23')
Tan fine silty CLAY
Tan silty CLAY (Fill material)
SOIL DESCRIPTION
BORING LOG Project Name:
Job No.
Boring Number:MW-2
Sampling Personnel:Jerry Paul
Date Drilled/Method:7/13/2011 / Geoprobe with Hollow Stem Augers and Air Hammer
Depth to Groundwater:14 feet below ground surface
Total Boring Depth:29 feet below ground surface
STRATIFICATION
From To PID FID
0.0 0.5 -- --
0.5 6.0 -- --
6.0 21.0 -- --
21.0 23.0 -- --
23.0 29.0 -- --
Notes:
ft. bgs = Depth in feet below ground surface Depth to water = 14 ft. bgs
ft. BTOC = Depth in feet below the top of well casing Total Well Length = 29 ft
PID = Photo-ionization detector (readings in parts per million or ppm) Screen length = 20 ft
FID = Flame-ionization detector (readings in parts per million or ppm) Riser length = 9 ft
-- = No data or parameter not collected Date GW Sample Collected = 7/13/2011
ORGANIC VAPOR
READINGS (ppm)
Gravel
Charles Berryman Property
1354-09-276D
Screen = 20' from 9-29 feet below ground surface.
Riser = 91' from 0-9 feet below ground surface.
Depth (Feet)
Total Well Depth = 29 feet below top of casing.
H2O at TOB = 14 feet below top of casing
Soil samples collected beneath the fill material (SB-2 @ 6'-8') and (SB-2 @ 16'-18').
Hard grey SILT to partially weathered rock (Conglomerate)
Switched to Air Drilling - Orange clayey SILT
Orange clayey SILT Auger refusal @ 21 ft. bgs (Petroleum odor noted from 6'-8')
Dark brown silty CLAY w/gravel
SOIL DESCRIPTION
BORING LOG Project Name:
Job No.
Boring Number:MW-3
Sampling Personnel:Jerry Paul
Date Drilled/Method:7/12/2011 / Geoprobe with Hollow Stem Augers
Depth to Groundwater:14 feet below ground surface
Total Boring Depth:27 feet below ground surface
STRATIFICATION
From To PID FID
0.0 0.5 -- --
0.5 3.0 -- --
3.0 11.0 -- --
11.0 13.0 -- --
13.0 16.0 -- --
16.0 22.0 -- --
22.0 25.0 -- --
25.0 27.0 -- --
Screen = 150' from 12-27 feet below ground surface.
Riser = 12' from 0-12 feet below ground surface.
Notes:
ft. bgs = Depth in feet below ground surface Depth to water = 142 ft. bgs
ft. BTOC = Depth in feet below the top of well casing Total Well Length = 27 ft
PID = Photo-ionization detector (readings in parts per million or ppm) Screen length = 15 ft
FID = Flame-ionization detector (readings in parts per million or ppm) Riser length = 12 ft
-- = No data or parameter not collected Date GW Sample Collected = 7/13/2011
Grey/brown silty CLAY
SOIL DESCRIPTION
ORGANIC VAPOR
READINGS (ppm)Depth (Feet)
* No soil samples were collected during the monitor well installation.
Tan/grey clayey SILT
Red/orange clayey SILT
Brownish/red silty CLAY
Red/orange silty CLAY
Red/orange clayey SILT
Grass/topsoil
Charles Berryman Property
1354-09-276D
H2O at TOB = 14 feet below top of casing
Grey clayey SILT Auger refusal at 27 ft. bgs
Total Well Depth = 27 feet below top of casing.
BORING LOG Project Name:
Job No.
Boring Number:MW-4
Sampling Personnel:Jerry Paul
Date Drilled/Method:7/11/2011 / Geoprobe with Hollow Stem Augers
Depth to Groundwater:23.5 feet below ground surface
Total Boring Depth:32 feet below ground surface
STRATIFICATION
From To PID FID
0.0 0.5 -- --
0.5 3.0 -- --
3.0 5.0 -- --
5.0 8.0 -- --
8.0 11.0 -- --
11.0 19.0 -- --
19.0 26.0 -- --
26.0 29.0 -- --
29.0 32.0 -- --
Riser = 17' from 0-17 feet below ground surface.
Notes:
ft. bgs = Depth in feet below ground surface Depth to water = 23.5 ft. bgs
ft. BTOC = Depth in feet below the top of well casing Total Well Length = 32 ft
PID = Photo-ionization detector (readings in parts per million or ppm) Screen length = 15 ft
FID = Flame-ionization detector (readings in parts per million or ppm) Riser length = 17 ft
-- = No data or parameter not collected Date GW Sample Collected = 7/13/2011
Charles Berryman Property
1354-09-276D
Total Well Depth = 32 feet below top of casing.
* No soil samples were collected during the monitor well installation.
Tan/grey fine SILT
H2O at TOB = 23.5 feet below top of casing
ORGANIC VAPOR
READINGS (ppm)
Gravel
Depth (Feet)
Grey SILT w/alternating layers of partially weathered rock Auger refusal at 32 ft. bgs
Tan fine SILT
Red/orange SILT
Red/orange clayey SILT (Slight Petroleum odor noted from 9'-10')
Tan silty SAND
Dark brown silty CLAY w/rock fragments
Tan silty CLAY w/rock fragments
SOIL DESCRIPTION
Screen = 15' from 17-32 feet below ground surface.
BORING LOG Project Name:
Job No.
Boring Number:MW-5
Sampling Personnel:Jerry Paul
Date Drilled/Method:7/13/2011 / Geoprobe with Hollow Stem Augers and Air Hammer
Depth to Groundwater:29.5 feet below ground surface
Total Boring Depth:35 feet below ground surface
STRATIFICATION
From To PID FID
0.0 0.5 -- --
0.5 1.0 -- --
1.0 1.5 -- --
1.5 3.0 -- --
3.0 6.0 -- --
6.0 8.0 -- --
8.0 13.0 -- --
13.0 18.5 -- --
18.5 25.0 -- --
25.0 27.0 -- --
27.0 32.0 ----
Notes:
ft. bgs = Depth in feet below ground surface Depth to water = 29.5 ft. bgs
ft. BTOC = Depth in feet below the top of well casing Total Well Length = 35 ft
PID = Photo-ionization detector (readings in parts per million or ppm) Screen length = 20 ft
FID = Flame-ionization detector (readings in parts per million or ppm) Riser length = 15 ft
-- = No data or parameter not collected Date GW Sample Collected = 7/13/2011
Depth (Feet)
Switched to Air Drilling - Hard grey SILT to partially weathered rock (Conglomerate)
Hard grey SILT
Red/orange clayey SILT
Tan sandy SILT
Red sandy SILT
Orange/tan silty SAND
Orange silty SAND w/gravel
Brown/orange silty SAND
SOIL DESCRIPTION
Riser = 15' from 0-15 feet below ground surface.
Screen = 20' from 15-35 feet below ground surface.
Total Well Depth = 35 feet below top of casing.
H2O at TOB = 29.5 feet below top of casing
* No soil samples were collected during the monitor well installation.
Charles Berryman Property
1354-09-276D
Orange clayey SILT Wet at 30 ft. bgs
Tan sandy SILT
ORGANIC VAPOR
READINGS (ppm)
Topsoil

APPENDIX V

LABORATORY ANALYTICAL RESULTS

July 25, 2011
LIMS USE: FR - LINDA BLALOCK
LIMS OBJECT ID: 9298263
9298263
Project:
Pace Project No.:
RE:
Ms. Linda Blalock
NCDENR-UST Section
1637 Mail Service Center
Raleigh, NC 276991637
15929-BERRYMAN PROPERTY
Dear Ms. Blalock:
Enclosed are the analytical results for sample(s) received by the laboratory on July 14, 2011. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards, where applicable, unless otherwise narrated in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
CERTIFICATIONS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001South Carolina Drinking Water Cert. #: 99006003Virginia Drinking Water Certification #: 00213
Connecticut Certification #: PH-0104Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84Louisiana DHH Drinking Water # LA 100031West Virginia Certification #: 357Virginia/VELAP Certification #: 460144
Asheville Certification IDs
2225 Riverside Dr., Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030North Carolina Bioassay Certification #: 9
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001Virginia Certification #: 00072West Virginia Certification #: 356
Virgina/VELAP Certification #: 460147
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
9298263001 SB-1 (11-13)MADEP VPH 5 PASI-CKJM
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CJEA
9298263002 SB-1 (21-23)MADEP VPH 5 PASI-CKJM
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CJEA
9298263003 SB-2 (6-8)MADEP EPH 7 PASI-CRES
MADEP VPH 5 PASI-CKJM
EPA 8270 74 PASI-CPPM
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CJEA
9298263004 SB-2 (16-18)MADEP EPH 7 PASI-CRES
MADEP VPH 5 PASI-CKJM
EPA 8270 74 PASI-CPPM
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CJEA
9298263005 MW-1 MADEP VPH 5 PASI-CKJM
EPA 200.7 1 PASI-AJMW
SM 6200B 64 PASI-CMCK
9298263006 MW-2 MADEP EPH 7 PASI-CRES
MADEP VPH 5 PASI-CKJM
EPA 625 58 PASI-CPPM
SM 6200B 64 PASI-CMCK
9298263007 MW-3 SM 6200B 64 PASI-CMCK
9298263008 MW-4 SM 6200B 64 PASI-CMCK
9298263009 MW-5 SM 6200B 64 PASI-CMCK
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
HITS ONLY
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
9298263001 SB-1 (11-13)
Aliphatic (C05-C08)3.1 mg/kg 07/15/11 22:02 N22.9MADEP VPH
Aliphatic (C09-C12)30.1 mg/kg 07/15/11 22:02 N22.9MADEP VPH
Aromatic (C09-C10)5.1 mg/kg 07/15/11 22:02 N22.9MADEP VPH
Acetone <4710 ug/kg 07/18/11 21:244710EPA 8260
Toluene <235 ug/kg 07/18/11 21:24235EPA 8260
1,2,4-Trimethylbenzene <235 ug/kg 07/18/11 21:24235EPA 8260
Percent Moisture 19.7 %07/15/11 17:380.10ASTM D2974-87
9298263002 SB-1 (21-23)
Percent Moisture 11.4 %07/15/11 17:390.10ASTM D2974-87
9298263003 SB-2 (6-8)
Benzo(a)anthracene <416 ug/kg 07/20/11 16:13416EPA 8270
Benzo(a)pyrene <416 ug/kg 07/20/11 16:13416EPA 8270
Benzo(b)fluoranthene <416 ug/kg 07/20/11 16:13416EPA 8270
Benzo(k)fluoranthene <416 ug/kg 07/20/11 16:13416EPA 8270
Benzoic Acid <2080 ug/kg 07/20/11 16:132080EPA 8270
Butylbenzylphthalate <416 ug/kg 07/20/11 16:13416EPA 8270
Chrysene <416 ug/kg 07/20/11 16:13416EPA 8270
Dibenz(a,h)anthracene <416 ug/kg 07/20/11 16:13416EPA 8270
3,3'-Dichlorobenzidine <2080 ug/kg 07/20/11 16:132080EPA 8270
Di-n-octylphthalate <416 ug/kg 07/20/11 16:13416EPA 8270
bis(2-Ethylhexyl)phthalate <416 ug/kg 07/20/11 16:13416EPA 8270
Indeno(1,2,3-cd)pyrene <416 ug/kg 07/20/11 16:13416EPA 8270
4-Nitrophenol <2080 ug/kg 07/20/11 16:132080EPA 8270
Pentachlorophenol <2080 ug/kg 07/20/11 16:132080EPA 8270
Percent Moisture 20.6 %07/15/11 17:390.10ASTM D2974-87
9298263004 SB-2 (16-18)
Benzo(a)anthracene <372 ug/kg 07/20/11 16:42372EPA 8270
Benzo(b)fluoranthene <372 ug/kg 07/20/11 16:42372EPA 8270
Benzo(k)fluoranthene <372 ug/kg 07/20/11 16:42372EPA 8270
Chrysene <372 ug/kg 07/20/11 16:42372EPA 8270
4-Nitrophenol <1860 ug/kg 07/20/11 16:421860EPA 8270
Pentachlorophenol <1860 ug/kg 07/20/11 16:421860EPA 8270
Percent Moisture 11.8 %07/15/11 17:390.10ASTM D2974-87
9298263005 MW-1
Aliphatic (C05-C08)240 ug/L 07/22/11 19:17 N250.0MADEP VPH
Aliphatic (C09-C12)327 ug/L 07/22/11 19:17 N250.0MADEP VPH
Aromatic (C09-C10)60.7 ug/L 07/22/11 19:17 N250.0MADEP VPH
Benzene 73.1 ug/L 07/20/11 01:570.50SM 6200B
1,2-Dichloroethane 8.7 ug/L 07/20/11 01:570.50SM 6200B
Diisopropyl ether 87.6 ug/L 07/20/11 01:570.50SM 6200B
Ethylbenzene 1.5 ug/L 07/20/11 01:570.50SM 6200B
Isopropylbenzene (Cumene)2.5 ug/L 07/20/11 01:570.50SM 6200B
Naphthalene 7.0 ug/L 07/20/11 01:572.0SM 6200B
1,2,4-Trimethylbenzene 25.0 ug/L 07/20/11 01:570.50SM 6200B
1,3,5-Trimethylbenzene 4.6 ug/L 07/20/11 01:570.50SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
HITS ONLY
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
9298263005 MW-1
m&p-Xylene 15.7 ug/L 07/20/11 01:571.0SM 6200B
o-Xylene 6.8 ug/L 07/20/11 01:570.50SM 6200B
9298263006 MW-2
Aliphatic (C05-C08)331 ug/L 07/18/11 19:58 N250.0MADEP VPH
Aliphatic (C09-C12)425 ug/L 07/18/11 19:58 N250.0MADEP VPH
Aromatic (C09-C10)53.6 ug/L 07/18/11 19:58 N250.0MADEP VPH
Benzo(a)pyrene <5.0 ug/L 07/21/11 20:275.0EPA 625
Benzo(b)fluoranthene <5.0 ug/L 07/21/11 20:275.0EPA 625
Benzo(g,h,i)perylene <5.0 ug/L 07/21/11 20:275.0EPA 625
Benzo(k)fluoranthene <5.0 ug/L 07/21/11 20:275.0EPA 625
Dibenz(a,h)anthracene <5.0 ug/L 07/21/11 20:275.0EPA 625
Naphthalene <5.0 ug/L 07/21/11 20:275.0EPA 625
Benzene 70.8 ug/L 07/20/11 02:190.50SM 6200B
Chloromethane 2.8 ug/L 07/20/11 02:191.0SM 6200B
1,2-Dichloroethane 11.8 ug/L 07/20/11 02:190.50SM 6200B
Diisopropyl ether 93.9 ug/L 07/20/11 02:190.50SM 6200B
Ethylbenzene 10.1 ug/L 07/20/11 02:190.50SM 6200B
Isopropylbenzene (Cumene)2.8 ug/L 07/20/11 02:190.50SM 6200B
Methyl-tert-butyl ether 1.7 ug/L 07/20/11 02:190.50SM 6200B
Naphthalene 6.3 ug/L 07/20/11 02:192.0SM 6200B
n-Propylbenzene 1.2 ug/L 07/20/11 02:190.50SM 6200B
Toluene 2.3 ug/L 07/20/11 02:190.50SM 6200B
1,2,4-Trimethylbenzene 15.9 ug/L 07/20/11 02:190.50SM 6200B
m&p-Xylene 38.2 ug/L 07/20/11 02:191.0SM 6200B
o-Xylene 19.7 ug/L 07/20/11 02:190.50SM 6200B
9298263007 MW-3
Benzene 64.4 ug/L 07/20/11 02:420.50SM 6200B
1,2-Dichloroethane 2.7 ug/L 07/20/11 02:420.50SM 6200B
Diisopropyl ether 17.0 ug/L 07/20/11 02:420.50SM 6200B
Isopropylbenzene (Cumene)2.0 ug/L 07/20/11 02:420.50SM 6200B
Naphthalene 4.3 ug/L 07/20/11 02:422.0SM 6200B
9298263008 MW-4
Benzene 153 ug/L 07/20/11 03:050.50SM 6200B
tert-Butylbenzene 1.6 ug/L 07/20/11 03:050.50SM 6200B
1,2-Dichloroethane 7.1 ug/L 07/20/11 03:050.50SM 6200B
Diisopropyl ether 46.3 ug/L 07/20/11 03:050.50SM 6200B
Ethylbenzene 8.6 ug/L 07/20/11 03:050.50SM 6200B
Isopropylbenzene (Cumene)9.0 ug/L 07/20/11 03:050.50SM 6200B
Naphthalene 21.8 ug/L 07/20/11 03:052.0SM 6200B
n-Propylbenzene 16.9 ug/L 07/20/11 03:050.50SM 6200B
1,2,4-Trimethylbenzene 36.0 ug/L 07/20/11 03:050.50SM 6200B
m&p-Xylene 6.3 ug/L 07/20/11 03:051.0SM 6200B
o-Xylene 10.7 ug/L 07/20/11 03:050.50SM 6200B
9298263009 MW-5
Benzene 8.7 ug/L 07/20/11 03:280.50SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 5 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
HITS ONLY
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
9298263009 MW-5
1,2-Dichloroethane 6.5 ug/L 07/20/11 03:280.50SM 6200B
Diisopropyl ether 46.9 ug/L 07/20/11 03:280.50SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 6 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Method:
Client:S&ME_FTF_RDU
MADEP EPH
Date:July 25, 2011
Description:MADEP EPH NC Soil
General Information:
2 samples were analyzed for MADEP EPH. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with MADEP EPH with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: OEXT/14234
N2: The lab does not hold TNI accreditation for this parameter.
• BLANK (Lab ID: 635041)
• Aliphatic (C09-C18)
• Aliphatic (C19-C36)
• Aromatic (C11-C22)
• LCS (Lab ID: 635042)
• Aliphatic (C09-C18)
• Aliphatic (C19-C36)
• Aromatic (C11-C22)
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 7 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Method:
Client:S&ME_FTF_RDU
MADEP EPH
Date:July 25, 2011
Description:MADEP EPH NC Soil
Analyte Comments:
QC Batch: OEXT/14234
N2: The lab does not hold TNI accreditation for this parameter.
• LCSD (Lab ID: 635043)
• Aliphatic (C09-C18)
• Aliphatic (C19-C36)
• Aromatic (C11-C22)
• SB-2 (16-18) (Lab ID: 9298263004)
• Aliphatic (C09-C18)
• Aliphatic (C19-C36)
• Aromatic (C11-C22)
• SB-2 (6-8) (Lab ID: 9298263003)
• Aliphatic (C09-C18)
• Aliphatic (C19-C36)
• Aromatic (C11-C22)
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 8 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Method:
Client:S&ME_FTF_RDU
MADEP EPH
Date:July 25, 2011
Description:MADEP EPH NC Water
General Information:
1 sample was analyzed for MADEP EPH. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with MADEP EPH with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: OEXT/14244
N2: The lab does not hold TNI accreditation for this parameter.
• BLANK (Lab ID: 635295)
• Aliphatic (C09-C18)
• Aliphatic (C19-C36)
• Aromatic (C11-C22)
• LCS (Lab ID: 635296)
• Aliphatic (C09-C18)
• Aliphatic (C19-C36)
• Aromatic (C11-C22)
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 9 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Method:
Client:S&ME_FTF_RDU
MADEP EPH
Date:July 25, 2011
Description:MADEP EPH NC Water
Analyte Comments:
QC Batch: OEXT/14244
N2: The lab does not hold TNI accreditation for this parameter.
• LCSD (Lab ID: 635297)
• Aliphatic (C09-C18)
• Aliphatic (C19-C36)
• Aromatic (C11-C22)
• MW-2 (Lab ID: 9298263006)
• Aliphatic (C09-C18)
• Aliphatic (C19-C36)
• Aromatic (C11-C22)
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 10 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Method:
Client:S&ME_FTF_RDU
MADEP VPH
Date:July 25, 2011
Description:VPH NC Soil
General Information:
4 samples were analyzed for MADEP VPH. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with MADEP VPH with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
QC Batch: GCV/5205
S3: Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated samples. Results
unaffected by high bias.
• SB-1 (21-23) (Lab ID: 9298263002)
• 2,5-Dibromotoluene (PID)(S)
• SB-2 (16-18) (Lab ID: 9298263004)
• 2,5-Dibromotoluene (FID)(S)
• 2,5-Dibromotoluene (PID)(S)
• SB-2 (6-8) (Lab ID: 9298263003)
• 2,5-Dibromotoluene (FID)(S)
• 2,5-Dibromotoluene (PID)(S)
Method Blank:
All analytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 11 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Method:
Client:S&ME_FTF_RDU
MADEP VPH
Date:July 25, 2011
Description:VPH NC Soil
Additional Comments:
Analyte Comments:
QC Batch: GCV/5205
1g: Surrogate recovery outside laboratory control limits after moisture correction for methanol.
• SB-1 (11-13) (Lab ID: 9298263001)
• 2,5-Dibromotoluene (PID)(S)
• 2,5-Dibromotoluene (FID)(S)
• SB-1 (21-23) (Lab ID: 9298263002)
• 2,5-Dibromotoluene (FID)(S)
N2: The lab does not hold TNI accreditation for this parameter.
• BLANK (Lab ID: 633579)
• Aliphatic (C05-C08)
• Aliphatic (C09-C12)
• Aromatic (C09-C10)
• LCS (Lab ID: 633580)
• Aliphatic (C05-C08)
• Aliphatic (C09-C12)
• Aromatic (C09-C10)
• LCSD (Lab ID: 633581)
• Aliphatic (C05-C08)
• Aliphatic (C09-C12)
• Aromatic (C09-C10)
• SB-1 (11-13) (Lab ID: 9298263001)
• Aliphatic (C05-C08)
• Aliphatic (C09-C12)
• Aromatic (C09-C10)
• SB-1 (21-23) (Lab ID: 9298263002)
• Aromatic (C09-C10)
• Aliphatic (C05-C08)
• Aliphatic (C09-C12)
• SB-2 (16-18) (Lab ID: 9298263004)
• Aliphatic (C05-C08)
• Aliphatic (C09-C12)
• Aromatic (C09-C10)
• SB-2 (6-8) (Lab ID: 9298263003)
• Aliphatic (C05-C08)
• Aliphatic (C09-C12)
• Aromatic (C09-C10)
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 12 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Method:
Client:S&ME_FTF_RDU
MADEP VPH
Date:July 25, 2011
Description:VPH NC Water
General Information:
2 samples were analyzed for MADEP VPH. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: GCV/5213
N2: The lab does not hold TNI accreditation for this parameter.
• BLANK (Lab ID: 635110)
• Aliphatic (C05-C08)
• Aliphatic (C09-C12)
• Aromatic (C09-C10)
• LCS (Lab ID: 635111)
• Aliphatic (C05-C08)
• Aliphatic (C09-C12)
• Aromatic (C09-C10)
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 13 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Method:
Client:S&ME_FTF_RDU
MADEP VPH
Date:July 25, 2011
Description:VPH NC Water
Analyte Comments:
QC Batch: GCV/5213
N2: The lab does not hold TNI accreditation for this parameter.
• LCSD (Lab ID: 635112)
• Aliphatic (C05-C08)
• Aliphatic (C09-C12)
• Aromatic (C09-C10)
• MW-2 (Lab ID: 9298263006)
• Aliphatic (C05-C08)
• Aliphatic (C09-C12)
• Aromatic (C09-C10)
QC Batch: GCV/5226
N2: The lab does not hold TNI accreditation for this parameter.
• BLANK (Lab ID: 636848)
• Aliphatic (C05-C08)
• Aliphatic (C09-C12)
• Aromatic (C09-C10)
• LCS (Lab ID: 636849)
• Aliphatic (C05-C08)
• Aliphatic (C09-C12)
• Aromatic (C09-C10)
• LCSD (Lab ID: 636850)
• Aliphatic (C05-C08)
• Aliphatic (C09-C12)
• Aromatic (C09-C10)
• MW-1 (Lab ID: 9298263005)
• Aliphatic (C05-C08)
• Aliphatic (C09-C12)
• Aromatic (C09-C10)
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 14 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Method:
Client:S&ME_FTF_RDU
EPA 200.7
Date:July 25, 2011
Description:200.7 MET ICP, 3030C
General Information:
1 sample was analyzed for EPA 200.7. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with SM 3030C with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 15 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Method:
Client:S&ME_FTF_RDU
EPA 625
Date:July 25, 2011
Description:625 MSSV
General Information:
1 sample was analyzed for EPA 625. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 625 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: OEXT/14221
A matrix spike and matrix spike duplicate (MS/MSD) were performed on the following sample(s): 9298209001
M0: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
• MS (Lab ID: 634389)
• Pentachlorophenol
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 634389)
• Pentachlorophenol
R1: RPD value was outside control limits.
• MSD (Lab ID: 634390)
• 4,6-Dinitro-2-methylphenol
• Pentachlorophenol
• Phenol
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 16 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Method:
Client:S&ME_FTF_RDU
EPA 625
Date:July 25, 2011
Description:625 MSSV
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 17 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Method:
Client:S&ME_FTF_RDU
EPA 8270
Date:July 25, 2011
Description:8270 MSSV Microwave
General Information:
2 samples were analyzed for EPA 8270. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3546 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 18 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Method:
Client:S&ME_FTF_RDU
SM 6200B
Date:July 25, 2011
Description:6200B MSV
General Information:
5 samples were analyzed for SM 6200B. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MSV/16054
A matrix spike and matrix spike duplicate (MS/MSD) were performed on the following sample(s): 9298285020
M0: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
• MS (Lab ID: 635835)
• Bromomethane
• Diisopropyl ether
• Methyl-tert-butyl ether
• MSD (Lab ID: 635836)
• Bromomethane
• Diisopropyl ether
• Methyl-tert-butyl ether
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 19 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Method:
Client:S&ME_FTF_RDU
EPA 8260
Date:July 25, 2011
Description:8260/5035A Volatile Organics
General Information:
4 samples were analyzed for EPA 8260. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
QC Batch: MSV/16029
L3: Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.
• LCS (Lab ID: 635170)
• Vinyl acetate
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: MSV/16029
D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• SB-1 (11-13) (Lab ID: 9298263001)
• Dichlorodifluoromethane
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 20 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Method:
Client:S&ME_FTF_RDU
EPA 8260
Date:July 25, 2011
Description:8260/5035A Volatile Organics
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 21 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Sample:SB-1 (11-13)Lab ID:9298263001 Collected:07/12/11 10:00 Received:07/14/11 14:28 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)3.1 mg/kg 1 07/15/11 22:02 N207/15/11 08:442.9
Aliphatic (C09-C12)30.1 mg/kg 1 07/15/11 22:02 N207/15/11 08:442.9
Aromatic (C09-C10)5.1 mg/kg 1 07/15/11 22:02 N207/15/11 08:442.9
2,5-Dibromotoluene (PID)(S)134 %1 07/15/11 22:02 1g07/15/11 08:4470-130
2,5-Dibromotoluene (FID)(S)151 %1 07/15/11 22:02 1g07/15/11 08:4470-130
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone <4710 ug/kg 50 07/18/11 21:24 67-64-14710
Benzene <235 ug/kg 50 07/18/11 21:24 71-43-2235
Bromobenzene <235 ug/kg 50 07/18/11 21:24 108-86-1235
Bromochloromethane <235 ug/kg 50 07/18/11 21:24 74-97-5235
Bromodichloromethane <235 ug/kg 50 07/18/11 21:24 75-27-4235
Bromoform <235 ug/kg 50 07/18/11 21:24 75-25-2235
Bromomethane <471 ug/kg 50 07/18/11 21:24 74-83-9471
2-Butanone (MEK)<4710 ug/kg 50 07/18/11 21:24 78-93-34710
n-Butylbenzene <235 ug/kg 50 07/18/11 21:24 104-51-8235
sec-Butylbenzene <235 ug/kg 50 07/18/11 21:24 135-98-8235
tert-Butylbenzene <235 ug/kg 50 07/18/11 21:24 98-06-6235
Carbon tetrachloride <235 ug/kg 50 07/18/11 21:24 56-23-5235
Chlorobenzene <235 ug/kg 50 07/18/11 21:24 108-90-7235
Chloroethane <471 ug/kg 50 07/18/11 21:24 75-00-3471
Chloroform <235 ug/kg 50 07/18/11 21:24 67-66-3235
Chloromethane <471 ug/kg 50 07/18/11 21:24 74-87-3471
2-Chlorotoluene <235 ug/kg 50 07/18/11 21:24 95-49-8235
4-Chlorotoluene <235 ug/kg 50 07/18/11 21:24 106-43-4235
1,2-Dibromo-3-chloropropane <235 ug/kg 50 07/18/11 21:24 96-12-8235
Dibromochloromethane <235 ug/kg 50 07/18/11 21:24 124-48-1235
1,2-Dibromoethane (EDB)<235 ug/kg 50 07/18/11 21:24 106-93-4235
Dibromomethane <235 ug/kg 50 07/18/11 21:24 74-95-3235
1,2-Dichlorobenzene <235 ug/kg 50 07/18/11 21:24 95-50-1235
1,3-Dichlorobenzene <235 ug/kg 50 07/18/11 21:24 541-73-1235
1,4-Dichlorobenzene <235 ug/kg 50 07/18/11 21:24 106-46-7235
Dichlorodifluoromethane <471 ug/kg 50 07/18/11 21:24 75-71-8 D3471
1,1-Dichloroethane <235 ug/kg 50 07/18/11 21:24 75-34-3235
1,2-Dichloroethane <235 ug/kg 50 07/18/11 21:24 107-06-2235
1,1-Dichloroethene <235 ug/kg 50 07/18/11 21:24 75-35-4235
cis-1,2-Dichloroethene <235 ug/kg 50 07/18/11 21:24 156-59-2235
trans-1,2-Dichloroethene <235 ug/kg 50 07/18/11 21:24 156-60-5235
1,2-Dichloropropane <235 ug/kg 50 07/18/11 21:24 78-87-5235
1,3-Dichloropropane <235 ug/kg 50 07/18/11 21:24 142-28-9235
2,2-Dichloropropane <235 ug/kg 50 07/18/11 21:24 594-20-7235
1,1-Dichloropropene <235 ug/kg 50 07/18/11 21:24 563-58-6235
cis-1,3-Dichloropropene <235 ug/kg 50 07/18/11 21:24 10061-01-5235
trans-1,3-Dichloropropene <235 ug/kg 50 07/18/11 21:24 10061-02-6235
Diisopropyl ether <235 ug/kg 50 07/18/11 21:24 108-20-3235
Ethylbenzene <235 ug/kg 50 07/18/11 21:24 100-41-4235
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 22 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Sample:SB-1 (11-13)Lab ID:9298263001 Collected:07/12/11 10:00 Received:07/14/11 14:28 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Hexachloro-1,3-butadiene <235 ug/kg 50 07/18/11 21:24 87-68-3235
2-Hexanone <2350 ug/kg 50 07/18/11 21:24 591-78-62350
Isopropylbenzene (Cumene)<235 ug/kg 50 07/18/11 21:24 98-82-8235
p-Isopropyltoluene <235 ug/kg 50 07/18/11 21:24 99-87-6235
Methylene Chloride <942 ug/kg 50 07/18/11 21:24 75-09-2942
4-Methyl-2-pentanone (MIBK)<2350 ug/kg 50 07/18/11 21:24 108-10-12350
Methyl-tert-butyl ether <235 ug/kg 50 07/18/11 21:24 1634-04-4235
Naphthalene <235 ug/kg 50 07/18/11 21:24 91-20-3235
n-Propylbenzene <235 ug/kg 50 07/18/11 21:24 103-65-1235
Styrene <235 ug/kg 50 07/18/11 21:24 100-42-5235
1,1,1,2-Tetrachloroethane <235 ug/kg 50 07/18/11 21:24 630-20-6235
1,1,2,2-Tetrachloroethane <235 ug/kg 50 07/18/11 21:24 79-34-5235
Tetrachloroethene <235 ug/kg 50 07/18/11 21:24 127-18-4235
Toluene <235 ug/kg 50 07/18/11 21:24 108-88-3235
1,2,3-Trichlorobenzene <235 ug/kg 50 07/18/11 21:24 87-61-6235
1,2,4-Trichlorobenzene <235 ug/kg 50 07/18/11 21:24 120-82-1235
1,1,1-Trichloroethane <235 ug/kg 50 07/18/11 21:24 71-55-6235
1,1,2-Trichloroethane <235 ug/kg 50 07/18/11 21:24 79-00-5235
Trichloroethene <235 ug/kg 50 07/18/11 21:24 79-01-6235
Trichlorofluoromethane <235 ug/kg 50 07/18/11 21:24 75-69-4235
1,2,3-Trichloropropane <235 ug/kg 50 07/18/11 21:24 96-18-4235
1,2,4-Trimethylbenzene <235 ug/kg 50 07/18/11 21:24 95-63-6235
1,3,5-Trimethylbenzene <235 ug/kg 50 07/18/11 21:24 108-67-8235
Vinyl acetate <2350 ug/kg 50 07/18/11 21:24 108-05-42350
Vinyl chloride <471 ug/kg 50 07/18/11 21:24 75-01-4471
Xylene (Total)<471 ug/kg 50 07/18/11 21:24 1330-20-7471
m&p-Xylene <471 ug/kg 50 07/18/11 21:24 179601-23-1471
o-Xylene <235 ug/kg 50 07/18/11 21:24 95-47-6235
Dibromofluoromethane (S)107 %50 07/18/11 21:24 1868-53-770-130
Toluene-d8 (S)105 %50 07/18/11 21:24 2037-26-570-130
4-Bromofluorobenzene (S)95 %50 07/18/11 21:24 460-00-470-130
1,2-Dichloroethane-d4 (S)102 %50 07/18/11 21:24 17060-07-070-132
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 19.7 %1 07/15/11 17:380.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 23 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Sample:SB-1 (21-23)Lab ID:9298263002 Collected:07/12/11 10:45 Received:07/14/11 14:28 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)<2.5 mg/kg 1 07/21/11 12:45 N207/15/11 08:442.5
Aliphatic (C09-C12)<2.5 mg/kg 1 07/21/11 12:45 N207/15/11 08:442.5
Aromatic (C09-C10)<2.5 mg/kg 1 07/21/11 12:45 N207/15/11 08:442.5
2,5-Dibromotoluene (PID)(S)156 %1 07/21/11 12:45 S307/15/11 08:4470-130
2,5-Dibromotoluene (FID)(S)148 %1 07/21/11 12:45 1g07/15/11 08:4470-130
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone <81.2 ug/kg 1 07/18/11 18:43 67-64-181.2
Benzene <4.1 ug/kg 1 07/18/11 18:43 71-43-24.1
Bromobenzene <4.1 ug/kg 1 07/18/11 18:43 108-86-14.1
Bromochloromethane <4.1 ug/kg 1 07/18/11 18:43 74-97-54.1
Bromodichloromethane <4.1 ug/kg 1 07/18/11 18:43 75-27-44.1
Bromoform <4.1 ug/kg 1 07/18/11 18:43 75-25-24.1
Bromomethane <8.1 ug/kg 1 07/18/11 18:43 74-83-98.1
2-Butanone (MEK)<81.2 ug/kg 1 07/18/11 18:43 78-93-381.2
n-Butylbenzene <4.1 ug/kg 1 07/18/11 18:43 104-51-84.1
sec-Butylbenzene <4.1 ug/kg 1 07/18/11 18:43 135-98-84.1
tert-Butylbenzene <4.1 ug/kg 1 07/18/11 18:43 98-06-64.1
Carbon tetrachloride <4.1 ug/kg 1 07/18/11 18:43 56-23-54.1
Chlorobenzene <4.1 ug/kg 1 07/18/11 18:43 108-90-74.1
Chloroethane <8.1 ug/kg 1 07/18/11 18:43 75-00-38.1
Chloroform <4.1 ug/kg 1 07/18/11 18:43 67-66-34.1
Chloromethane <8.1 ug/kg 1 07/18/11 18:43 74-87-38.1
2-Chlorotoluene <4.1 ug/kg 1 07/18/11 18:43 95-49-84.1
4-Chlorotoluene <4.1 ug/kg 1 07/18/11 18:43 106-43-44.1
1,2-Dibromo-3-chloropropane <4.1 ug/kg 1 07/18/11 18:43 96-12-84.1
Dibromochloromethane <4.1 ug/kg 1 07/18/11 18:43 124-48-14.1
1,2-Dibromoethane (EDB)<4.1 ug/kg 1 07/18/11 18:43 106-93-44.1
Dibromomethane <4.1 ug/kg 1 07/18/11 18:43 74-95-34.1
1,2-Dichlorobenzene <4.1 ug/kg 1 07/18/11 18:43 95-50-14.1
1,3-Dichlorobenzene <4.1 ug/kg 1 07/18/11 18:43 541-73-14.1
1,4-Dichlorobenzene <4.1 ug/kg 1 07/18/11 18:43 106-46-74.1
Dichlorodifluoromethane <8.1 ug/kg 1 07/18/11 18:43 75-71-88.1
1,1-Dichloroethane <4.1 ug/kg 1 07/18/11 18:43 75-34-34.1
1,2-Dichloroethane <4.1 ug/kg 1 07/18/11 18:43 107-06-24.1
1,1-Dichloroethene <4.1 ug/kg 1 07/18/11 18:43 75-35-44.1
cis-1,2-Dichloroethene <4.1 ug/kg 1 07/18/11 18:43 156-59-24.1
trans-1,2-Dichloroethene <4.1 ug/kg 1 07/18/11 18:43 156-60-54.1
1,2-Dichloropropane <4.1 ug/kg 1 07/18/11 18:43 78-87-54.1
1,3-Dichloropropane <4.1 ug/kg 1 07/18/11 18:43 142-28-94.1
2,2-Dichloropropane <4.1 ug/kg 1 07/18/11 18:43 594-20-74.1
1,1-Dichloropropene <4.1 ug/kg 1 07/18/11 18:43 563-58-64.1
cis-1,3-Dichloropropene <4.1 ug/kg 1 07/18/11 18:43 10061-01-54.1
trans-1,3-Dichloropropene <4.1 ug/kg 1 07/18/11 18:43 10061-02-64.1
Diisopropyl ether <4.1 ug/kg 1 07/18/11 18:43 108-20-34.1
Ethylbenzene <4.1 ug/kg 1 07/18/11 18:43 100-41-44.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 24 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Sample:SB-1 (21-23)Lab ID:9298263002 Collected:07/12/11 10:45 Received:07/14/11 14:28 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Hexachloro-1,3-butadiene <4.1 ug/kg 1 07/18/11 18:43 87-68-34.1
2-Hexanone <40.6 ug/kg 1 07/18/11 18:43 591-78-640.6
Isopropylbenzene (Cumene)<4.1 ug/kg 1 07/18/11 18:43 98-82-84.1
p-Isopropyltoluene <4.1 ug/kg 1 07/18/11 18:43 99-87-64.1
Methylene Chloride <16.2 ug/kg 1 07/18/11 18:43 75-09-216.2
4-Methyl-2-pentanone (MIBK)<40.6 ug/kg 1 07/18/11 18:43 108-10-140.6
Methyl-tert-butyl ether <4.1 ug/kg 1 07/18/11 18:43 1634-04-44.1
Naphthalene <4.1 ug/kg 1 07/18/11 18:43 91-20-34.1
n-Propylbenzene <4.1 ug/kg 1 07/18/11 18:43 103-65-14.1
Styrene <4.1 ug/kg 1 07/18/11 18:43 100-42-54.1
1,1,1,2-Tetrachloroethane <4.1 ug/kg 1 07/18/11 18:43 630-20-64.1
1,1,2,2-Tetrachloroethane <4.1 ug/kg 1 07/18/11 18:43 79-34-54.1
Tetrachloroethene <4.1 ug/kg 1 07/18/11 18:43 127-18-44.1
Toluene <4.1 ug/kg 1 07/18/11 18:43 108-88-34.1
1,2,3-Trichlorobenzene <4.1 ug/kg 1 07/18/11 18:43 87-61-64.1
1,2,4-Trichlorobenzene <4.1 ug/kg 1 07/18/11 18:43 120-82-14.1
1,1,1-Trichloroethane <4.1 ug/kg 1 07/18/11 18:43 71-55-64.1
1,1,2-Trichloroethane <4.1 ug/kg 1 07/18/11 18:43 79-00-54.1
Trichloroethene <4.1 ug/kg 1 07/18/11 18:43 79-01-64.1
Trichlorofluoromethane <4.1 ug/kg 1 07/18/11 18:43 75-69-44.1
1,2,3-Trichloropropane <4.1 ug/kg 1 07/18/11 18:43 96-18-44.1
1,2,4-Trimethylbenzene <4.1 ug/kg 1 07/18/11 18:43 95-63-64.1
1,3,5-Trimethylbenzene <4.1 ug/kg 1 07/18/11 18:43 108-67-84.1
Vinyl acetate <40.6 ug/kg 1 07/18/11 18:43 108-05-440.6
Vinyl chloride <8.1 ug/kg 1 07/18/11 18:43 75-01-48.1
Xylene (Total)<8.1 ug/kg 1 07/18/11 18:43 1330-20-78.1
m&p-Xylene <8.1 ug/kg 1 07/18/11 18:43 179601-23-18.1
o-Xylene <4.1 ug/kg 1 07/18/11 18:43 95-47-64.1
Dibromofluoromethane (S)112 %1 07/18/11 18:43 1868-53-770-130
Toluene-d8 (S)109 %1 07/18/11 18:43 2037-26-570-130
4-Bromofluorobenzene (S)98 %1 07/18/11 18:43 460-00-470-130
1,2-Dichloroethane-d4 (S)98 %1 07/18/11 18:43 17060-07-070-132
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 11.4 %1 07/15/11 17:390.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 25 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Sample:SB-2 (6-8)Lab ID:9298263003 Collected:07/12/11 11:15 Received:07/14/11 14:28 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
MADEP EPH NC Soil Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)<12.6 mg/kg 1 07/21/11 20:43 N207/18/11 09:0012.6
Aliphatic (C19-C36)<12.6 mg/kg 1 07/21/11 20:43 N207/18/11 09:0012.6
Aromatic (C11-C22)<12.6 mg/kg 1 07/21/11 20:43 N207/18/11 09:0012.6
Nonatriacontane (S)85 %1 07/21/11 20:43 7194-86-707/18/11 09:0040-140
o-Terphenyl (S)76 %1 07/21/11 20:43 84-15-107/18/11 09:0040-140
2-Fluorobiphenyl (S)101 %1 07/21/11 20:43 321-60-807/18/11 09:0040-140
2-Bromonaphthalene (S)101 %1 07/21/11 20:43 580-13-207/18/11 09:0040-140
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)<2.9 mg/kg 1 07/15/11 22:52 N207/15/11 08:442.9
Aliphatic (C09-C12)<2.9 mg/kg 1 07/15/11 22:52 N207/15/11 08:442.9
Aromatic (C09-C10)<2.9 mg/kg 1 07/15/11 22:52 N207/15/11 08:442.9
2,5-Dibromotoluene (PID)(S)177 %1 07/15/11 22:52 S307/15/11 08:4470-130
2,5-Dibromotoluene (FID)(S)169 %1 07/15/11 22:52 S307/15/11 08:4470-130
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene <416 ug/kg 1 07/20/11 16:13 83-32-907/15/11 10:30416
Acenaphthylene <416 ug/kg 1 07/20/11 16:13 208-96-807/15/11 10:30416
Aniline <416 ug/kg 1 07/20/11 16:13 62-53-307/15/11 10:30416
Anthracene <416 ug/kg 1 07/20/11 16:13 120-12-707/15/11 10:30416
Benzo(a)anthracene <416 ug/kg 1 07/20/11 16:13 56-55-307/15/11 10:30416
Benzo(a)pyrene <416 ug/kg 1 07/20/11 16:13 50-32-807/15/11 10:30416
Benzo(b)fluoranthene <416 ug/kg 1 07/20/11 16:13 205-99-207/15/11 10:30416
Benzo(g,h,i)perylene <416 ug/kg 1 07/20/11 16:13 191-24-207/15/11 10:30416
Benzo(k)fluoranthene <416 ug/kg 1 07/20/11 16:13 207-08-907/15/11 10:30416
Benzoic Acid <2080 ug/kg 1 07/20/11 16:13 65-85-007/15/11 10:302080
Benzyl alcohol <831 ug/kg 1 07/20/11 16:13 100-51-607/15/11 10:30831
4-Bromophenylphenyl ether <416 ug/kg 1 07/20/11 16:13 101-55-307/15/11 10:30416
Butylbenzylphthalate <416 ug/kg 1 07/20/11 16:13 85-68-707/15/11 10:30416
4-Chloro-3-methylphenol <831 ug/kg 1 07/20/11 16:13 59-50-707/15/11 10:30831
4-Chloroaniline <2080 ug/kg 1 07/20/11 16:13 106-47-807/15/11 10:302080
bis(2-Chloroethoxy)methane <416 ug/kg 1 07/20/11 16:13 111-91-107/15/11 10:30416
bis(2-Chloroethyl) ether <416 ug/kg 1 07/20/11 16:13 111-44-407/15/11 10:30416
bis(2-Chloroisopropyl) ether <416 ug/kg 1 07/20/11 16:13 108-60-107/15/11 10:30416
2-Chloronaphthalene <416 ug/kg 1 07/20/11 16:13 91-58-707/15/11 10:30416
2-Chlorophenol <416 ug/kg 1 07/20/11 16:13 95-57-807/15/11 10:30416
4-Chlorophenylphenyl ether <416 ug/kg 1 07/20/11 16:13 7005-72-307/15/11 10:30416
Chrysene <416 ug/kg 1 07/20/11 16:13 218-01-907/15/11 10:30416
Dibenz(a,h)anthracene <416 ug/kg 1 07/20/11 16:13 53-70-307/15/11 10:30416
Dibenzofuran <416 ug/kg 1 07/20/11 16:13 132-64-907/15/11 10:30416
1,2-Dichlorobenzene <416 ug/kg 1 07/20/11 16:13 95-50-107/15/11 10:30416
1,3-Dichlorobenzene <416 ug/kg 1 07/20/11 16:13 541-73-107/15/11 10:30416
1,4-Dichlorobenzene <416 ug/kg 1 07/20/11 16:13 106-46-707/15/11 10:30416
3,3'-Dichlorobenzidine <2080 ug/kg 1 07/20/11 16:13 91-94-107/15/11 10:302080
2,4-Dichlorophenol <416 ug/kg 1 07/20/11 16:13 120-83-207/15/11 10:30416
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 26 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Sample:SB-2 (6-8)Lab ID:9298263003 Collected:07/12/11 11:15 Received:07/14/11 14:28 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Diethylphthalate <416 ug/kg 1 07/20/11 16:13 84-66-207/15/11 10:30416
2,4-Dimethylphenol <416 ug/kg 1 07/20/11 16:13 105-67-907/15/11 10:30416
Dimethylphthalate <416 ug/kg 1 07/20/11 16:13 131-11-307/15/11 10:30416
Di-n-butylphthalate <416 ug/kg 1 07/20/11 16:13 84-74-207/15/11 10:30416
4,6-Dinitro-2-methylphenol <831 ug/kg 1 07/20/11 16:13 534-52-107/15/11 10:30831
2,4-Dinitrophenol <2080 ug/kg 1 07/20/11 16:13 51-28-507/15/11 10:302080
2,4-Dinitrotoluene <416 ug/kg 1 07/20/11 16:13 121-14-207/15/11 10:30416
2,6-Dinitrotoluene <416 ug/kg 1 07/20/11 16:13 606-20-207/15/11 10:30416
Di-n-octylphthalate <416 ug/kg 1 07/20/11 16:13 117-84-007/15/11 10:30416
bis(2-Ethylhexyl)phthalate <416 ug/kg 1 07/20/11 16:13 117-81-707/15/11 10:30416
Fluoranthene <416 ug/kg 1 07/20/11 16:13 206-44-007/15/11 10:30416
Fluorene <416 ug/kg 1 07/20/11 16:13 86-73-707/15/11 10:30416
Hexachloro-1,3-butadiene <416 ug/kg 1 07/20/11 16:13 87-68-307/15/11 10:30416
Hexachlorobenzene <416 ug/kg 1 07/20/11 16:13 118-74-107/15/11 10:30416
Hexachlorocyclopentadiene <416 ug/kg 1 07/20/11 16:13 77-47-407/15/11 10:30416
Hexachloroethane <416 ug/kg 1 07/20/11 16:13 67-72-107/15/11 10:30416
Indeno(1,2,3-cd)pyrene <416 ug/kg 1 07/20/11 16:13 193-39-507/15/11 10:30416
Isophorone <416 ug/kg 1 07/20/11 16:13 78-59-107/15/11 10:30416
1-Methylnaphthalene <416 ug/kg 1 07/20/11 16:13 90-12-007/15/11 10:30416
2-Methylnaphthalene <416 ug/kg 1 07/20/11 16:13 91-57-607/15/11 10:30416
2-Methylphenol(o-Cresol)<416 ug/kg 1 07/20/11 16:13 95-48-707/15/11 10:30416
3&4-Methylphenol(m&p Cresol)<416 ug/kg 1 07/20/11 16:1307/15/11 10:30416
Naphthalene <416 ug/kg 1 07/20/11 16:13 91-20-307/15/11 10:30416
2-Nitroaniline <2080 ug/kg 1 07/20/11 16:13 88-74-407/15/11 10:302080
3-Nitroaniline <2080 ug/kg 1 07/20/11 16:13 99-09-207/15/11 10:302080
4-Nitroaniline <831 ug/kg 1 07/20/11 16:13 100-01-607/15/11 10:30831
Nitrobenzene <416 ug/kg 1 07/20/11 16:13 98-95-307/15/11 10:30416
2-Nitrophenol <416 ug/kg 1 07/20/11 16:13 88-75-507/15/11 10:30416
4-Nitrophenol <2080 ug/kg 1 07/20/11 16:13 100-02-707/15/11 10:302080
N-Nitrosodimethylamine <416 ug/kg 1 07/20/11 16:13 62-75-907/15/11 10:30416
N-Nitroso-di-n-propylamine <416 ug/kg 1 07/20/11 16:13 621-64-707/15/11 10:30416
N-Nitrosodiphenylamine <416 ug/kg 1 07/20/11 16:13 86-30-607/15/11 10:30416
Pentachlorophenol <2080 ug/kg 1 07/20/11 16:13 87-86-507/15/11 10:302080
Phenanthrene <416 ug/kg 1 07/20/11 16:13 85-01-807/15/11 10:30416
Phenol <416 ug/kg 1 07/20/11 16:13 108-95-207/15/11 10:30416
Pyrene <416 ug/kg 1 07/20/11 16:13 129-00-007/15/11 10:30416
1,2,4-Trichlorobenzene <416 ug/kg 1 07/20/11 16:13 120-82-107/15/11 10:30416
2,4,5-Trichlorophenol <416 ug/kg 1 07/20/11 16:13 95-95-407/15/11 10:30416
2,4,6-Trichlorophenol <416 ug/kg 1 07/20/11 16:13 88-06-207/15/11 10:30416
Nitrobenzene-d5 (S)49 %1 07/20/11 16:13 4165-60-007/15/11 10:3023-110
2-Fluorobiphenyl (S)46 %1 07/20/11 16:13 321-60-807/15/11 10:3030-110
Terphenyl-d14 (S)55 %1 07/20/11 16:13 1718-51-007/15/11 10:3028-110
Phenol-d6 (S)47 %1 07/20/11 16:13 13127-88-307/15/11 10:3022-110
2-Fluorophenol (S)45 %1 07/20/11 16:13 367-12-407/15/11 10:3013-110
2,4,6-Tribromophenol (S)52 %1 07/20/11 16:13 118-79-607/15/11 10:3027-110
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 27 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Sample:SB-2 (6-8)Lab ID:9298263003 Collected:07/12/11 11:15 Received:07/14/11 14:28 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone <89.2 ug/kg 1 07/18/11 19:03 67-64-189.2
Benzene <4.5 ug/kg 1 07/18/11 19:03 71-43-24.5
Bromobenzene <4.5 ug/kg 1 07/18/11 19:03 108-86-14.5
Bromochloromethane <4.5 ug/kg 1 07/18/11 19:03 74-97-54.5
Bromodichloromethane <4.5 ug/kg 1 07/18/11 19:03 75-27-44.5
Bromoform <4.5 ug/kg 1 07/18/11 19:03 75-25-24.5
Bromomethane <8.9 ug/kg 1 07/18/11 19:03 74-83-98.9
2-Butanone (MEK)<89.2 ug/kg 1 07/18/11 19:03 78-93-389.2
n-Butylbenzene <4.5 ug/kg 1 07/18/11 19:03 104-51-84.5
sec-Butylbenzene <4.5 ug/kg 1 07/18/11 19:03 135-98-84.5
tert-Butylbenzene <4.5 ug/kg 1 07/18/11 19:03 98-06-64.5
Carbon tetrachloride <4.5 ug/kg 1 07/18/11 19:03 56-23-54.5
Chlorobenzene <4.5 ug/kg 1 07/18/11 19:03 108-90-74.5
Chloroethane <8.9 ug/kg 1 07/18/11 19:03 75-00-38.9
Chloroform <4.5 ug/kg 1 07/18/11 19:03 67-66-34.5
Chloromethane <8.9 ug/kg 1 07/18/11 19:03 74-87-38.9
2-Chlorotoluene <4.5 ug/kg 1 07/18/11 19:03 95-49-84.5
4-Chlorotoluene <4.5 ug/kg 1 07/18/11 19:03 106-43-44.5
1,2-Dibromo-3-chloropropane <4.5 ug/kg 1 07/18/11 19:03 96-12-84.5
Dibromochloromethane <4.5 ug/kg 1 07/18/11 19:03 124-48-14.5
1,2-Dibromoethane (EDB)<4.5 ug/kg 1 07/18/11 19:03 106-93-44.5
Dibromomethane <4.5 ug/kg 1 07/18/11 19:03 74-95-34.5
1,2-Dichlorobenzene <4.5 ug/kg 1 07/18/11 19:03 95-50-14.5
1,3-Dichlorobenzene <4.5 ug/kg 1 07/18/11 19:03 541-73-14.5
1,4-Dichlorobenzene <4.5 ug/kg 1 07/18/11 19:03 106-46-74.5
Dichlorodifluoromethane <8.9 ug/kg 1 07/18/11 19:03 75-71-88.9
1,1-Dichloroethane <4.5 ug/kg 1 07/18/11 19:03 75-34-34.5
1,2-Dichloroethane <4.5 ug/kg 1 07/18/11 19:03 107-06-24.5
1,1-Dichloroethene <4.5 ug/kg 1 07/18/11 19:03 75-35-44.5
cis-1,2-Dichloroethene <4.5 ug/kg 1 07/18/11 19:03 156-59-24.5
trans-1,2-Dichloroethene <4.5 ug/kg 1 07/18/11 19:03 156-60-54.5
1,2-Dichloropropane <4.5 ug/kg 1 07/18/11 19:03 78-87-54.5
1,3-Dichloropropane <4.5 ug/kg 1 07/18/11 19:03 142-28-94.5
2,2-Dichloropropane <4.5 ug/kg 1 07/18/11 19:03 594-20-74.5
1,1-Dichloropropene <4.5 ug/kg 1 07/18/11 19:03 563-58-64.5
cis-1,3-Dichloropropene <4.5 ug/kg 1 07/18/11 19:03 10061-01-54.5
trans-1,3-Dichloropropene <4.5 ug/kg 1 07/18/11 19:03 10061-02-64.5
Diisopropyl ether <4.5 ug/kg 1 07/18/11 19:03 108-20-34.5
Ethylbenzene <4.5 ug/kg 1 07/18/11 19:03 100-41-44.5
Hexachloro-1,3-butadiene <4.5 ug/kg 1 07/18/11 19:03 87-68-34.5
2-Hexanone <44.6 ug/kg 1 07/18/11 19:03 591-78-644.6
Isopropylbenzene (Cumene)<4.5 ug/kg 1 07/18/11 19:03 98-82-84.5
p-Isopropyltoluene <4.5 ug/kg 1 07/18/11 19:03 99-87-64.5
Methylene Chloride <17.8 ug/kg 1 07/18/11 19:03 75-09-217.8
4-Methyl-2-pentanone (MIBK)<44.6 ug/kg 1 07/18/11 19:03 108-10-144.6
Methyl-tert-butyl ether <4.5 ug/kg 1 07/18/11 19:03 1634-04-44.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 28 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Sample:SB-2 (6-8)Lab ID:9298263003 Collected:07/12/11 11:15 Received:07/14/11 14:28 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Naphthalene <4.5 ug/kg 1 07/18/11 19:03 91-20-34.5
n-Propylbenzene <4.5 ug/kg 1 07/18/11 19:03 103-65-14.5
Styrene <4.5 ug/kg 1 07/18/11 19:03 100-42-54.5
1,1,1,2-Tetrachloroethane <4.5 ug/kg 1 07/18/11 19:03 630-20-64.5
1,1,2,2-Tetrachloroethane <4.5 ug/kg 1 07/18/11 19:03 79-34-54.5
Tetrachloroethene <4.5 ug/kg 1 07/18/11 19:03 127-18-44.5
Toluene <4.5 ug/kg 1 07/18/11 19:03 108-88-34.5
1,2,3-Trichlorobenzene <4.5 ug/kg 1 07/18/11 19:03 87-61-64.5
1,2,4-Trichlorobenzene <4.5 ug/kg 1 07/18/11 19:03 120-82-14.5
1,1,1-Trichloroethane <4.5 ug/kg 1 07/18/11 19:03 71-55-64.5
1,1,2-Trichloroethane <4.5 ug/kg 1 07/18/11 19:03 79-00-54.5
Trichloroethene <4.5 ug/kg 1 07/18/11 19:03 79-01-64.5
Trichlorofluoromethane <4.5 ug/kg 1 07/18/11 19:03 75-69-44.5
1,2,3-Trichloropropane <4.5 ug/kg 1 07/18/11 19:03 96-18-44.5
1,2,4-Trimethylbenzene <4.5 ug/kg 1 07/18/11 19:03 95-63-64.5
1,3,5-Trimethylbenzene <4.5 ug/kg 1 07/18/11 19:03 108-67-84.5
Vinyl acetate <44.6 ug/kg 1 07/18/11 19:03 108-05-444.6
Vinyl chloride <8.9 ug/kg 1 07/18/11 19:03 75-01-48.9
Xylene (Total)<8.9 ug/kg 1 07/18/11 19:03 1330-20-78.9
m&p-Xylene <8.9 ug/kg 1 07/18/11 19:03 179601-23-18.9
o-Xylene <4.5 ug/kg 1 07/18/11 19:03 95-47-64.5
Dibromofluoromethane (S)111 %1 07/18/11 19:03 1868-53-770-130
Toluene-d8 (S)101 %1 07/18/11 19:03 2037-26-570-130
4-Bromofluorobenzene (S)97 %1 07/18/11 19:03 460-00-470-130
1,2-Dichloroethane-d4 (S)96 %1 07/18/11 19:03 17060-07-070-132
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 20.6 %1 07/15/11 17:390.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 29 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Sample:SB-2 (16-18)Lab ID:9298263004 Collected:07/12/11 11:45 Received:07/14/11 14:28 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
MADEP EPH NC Soil Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)<11.3 mg/kg 1 07/21/11 21:20 N207/18/11 09:0011.3
Aliphatic (C19-C36)<11.3 mg/kg 1 07/21/11 21:20 N207/18/11 09:0011.3
Aromatic (C11-C22)<11.3 mg/kg 1 07/21/11 21:20 N207/18/11 09:0011.3
Nonatriacontane (S)81 %1 07/21/11 21:20 7194-86-707/18/11 09:0040-140
o-Terphenyl (S)62 %1 07/21/11 21:20 84-15-107/18/11 09:0040-140
2-Fluorobiphenyl (S)84 %1 07/21/11 21:20 321-60-807/18/11 09:0040-140
2-Bromonaphthalene (S)83 %1 07/21/11 21:20 580-13-207/18/11 09:0040-140
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)<2.6 mg/kg 1 07/15/11 23:17 N207/15/11 08:442.6
Aliphatic (C09-C12)<2.6 mg/kg 1 07/15/11 23:17 N207/15/11 08:442.6
Aromatic (C09-C10)<2.6 mg/kg 1 07/15/11 23:17 N207/15/11 08:442.6
2,5-Dibromotoluene (PID)(S)171 %1 07/15/11 23:17 S307/15/11 08:4470-130
2,5-Dibromotoluene (FID)(S)163 %1 07/15/11 23:17 S307/15/11 08:4470-130
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene <372 ug/kg 1 07/20/11 16:42 83-32-907/15/11 10:30372
Acenaphthylene <372 ug/kg 1 07/20/11 16:42 208-96-807/15/11 10:30372
Aniline <372 ug/kg 1 07/20/11 16:42 62-53-307/15/11 10:30372
Anthracene <372 ug/kg 1 07/20/11 16:42 120-12-707/15/11 10:30372
Benzo(a)anthracene <372 ug/kg 1 07/20/11 16:42 56-55-307/15/11 10:30372
Benzo(a)pyrene <372 ug/kg 1 07/20/11 16:42 50-32-807/15/11 10:30372
Benzo(b)fluoranthene <372 ug/kg 1 07/20/11 16:42 205-99-207/15/11 10:30372
Benzo(g,h,i)perylene <372 ug/kg 1 07/20/11 16:42 191-24-207/15/11 10:30372
Benzo(k)fluoranthene <372 ug/kg 1 07/20/11 16:42 207-08-907/15/11 10:30372
Benzoic Acid <1860 ug/kg 1 07/20/11 16:42 65-85-007/15/11 10:301860
Benzyl alcohol <743 ug/kg 1 07/20/11 16:42 100-51-607/15/11 10:30743
4-Bromophenylphenyl ether <372 ug/kg 1 07/20/11 16:42 101-55-307/15/11 10:30372
Butylbenzylphthalate <372 ug/kg 1 07/20/11 16:42 85-68-707/15/11 10:30372
4-Chloro-3-methylphenol <743 ug/kg 1 07/20/11 16:42 59-50-707/15/11 10:30743
4-Chloroaniline <1860 ug/kg 1 07/20/11 16:42 106-47-807/15/11 10:301860
bis(2-Chloroethoxy)methane <372 ug/kg 1 07/20/11 16:42 111-91-107/15/11 10:30372
bis(2-Chloroethyl) ether <372 ug/kg 1 07/20/11 16:42 111-44-407/15/11 10:30372
bis(2-Chloroisopropyl) ether <372 ug/kg 1 07/20/11 16:42 108-60-107/15/11 10:30372
2-Chloronaphthalene <372 ug/kg 1 07/20/11 16:42 91-58-707/15/11 10:30372
2-Chlorophenol <372 ug/kg 1 07/20/11 16:42 95-57-807/15/11 10:30372
4-Chlorophenylphenyl ether <372 ug/kg 1 07/20/11 16:42 7005-72-307/15/11 10:30372
Chrysene <372 ug/kg 1 07/20/11 16:42 218-01-907/15/11 10:30372
Dibenz(a,h)anthracene <372 ug/kg 1 07/20/11 16:42 53-70-307/15/11 10:30372
Dibenzofuran <372 ug/kg 1 07/20/11 16:42 132-64-907/15/11 10:30372
1,2-Dichlorobenzene <372 ug/kg 1 07/20/11 16:42 95-50-107/15/11 10:30372
1,3-Dichlorobenzene <372 ug/kg 1 07/20/11 16:42 541-73-107/15/11 10:30372
1,4-Dichlorobenzene <372 ug/kg 1 07/20/11 16:42 106-46-707/15/11 10:30372
3,3'-Dichlorobenzidine <1860 ug/kg 1 07/20/11 16:42 91-94-107/15/11 10:301860
2,4-Dichlorophenol <372 ug/kg 1 07/20/11 16:42 120-83-207/15/11 10:30372
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 30 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Sample:SB-2 (16-18)Lab ID:9298263004 Collected:07/12/11 11:45 Received:07/14/11 14:28 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Diethylphthalate <372 ug/kg 1 07/20/11 16:42 84-66-207/15/11 10:30372
2,4-Dimethylphenol <372 ug/kg 1 07/20/11 16:42 105-67-907/15/11 10:30372
Dimethylphthalate <372 ug/kg 1 07/20/11 16:42 131-11-307/15/11 10:30372
Di-n-butylphthalate <372 ug/kg 1 07/20/11 16:42 84-74-207/15/11 10:30372
4,6-Dinitro-2-methylphenol <743 ug/kg 1 07/20/11 16:42 534-52-107/15/11 10:30743
2,4-Dinitrophenol <1860 ug/kg 1 07/20/11 16:42 51-28-507/15/11 10:301860
2,4-Dinitrotoluene <372 ug/kg 1 07/20/11 16:42 121-14-207/15/11 10:30372
2,6-Dinitrotoluene <372 ug/kg 1 07/20/11 16:42 606-20-207/15/11 10:30372
Di-n-octylphthalate <372 ug/kg 1 07/20/11 16:42 117-84-007/15/11 10:30372
bis(2-Ethylhexyl)phthalate <372 ug/kg 1 07/20/11 16:42 117-81-707/15/11 10:30372
Fluoranthene <372 ug/kg 1 07/20/11 16:42 206-44-007/15/11 10:30372
Fluorene <372 ug/kg 1 07/20/11 16:42 86-73-707/15/11 10:30372
Hexachloro-1,3-butadiene <372 ug/kg 1 07/20/11 16:42 87-68-307/15/11 10:30372
Hexachlorobenzene <372 ug/kg 1 07/20/11 16:42 118-74-107/15/11 10:30372
Hexachlorocyclopentadiene <372 ug/kg 1 07/20/11 16:42 77-47-407/15/11 10:30372
Hexachloroethane <372 ug/kg 1 07/20/11 16:42 67-72-107/15/11 10:30372
Indeno(1,2,3-cd)pyrene <372 ug/kg 1 07/20/11 16:42 193-39-507/15/11 10:30372
Isophorone <372 ug/kg 1 07/20/11 16:42 78-59-107/15/11 10:30372
1-Methylnaphthalene <372 ug/kg 1 07/20/11 16:42 90-12-007/15/11 10:30372
2-Methylnaphthalene <372 ug/kg 1 07/20/11 16:42 91-57-607/15/11 10:30372
2-Methylphenol(o-Cresol)<372 ug/kg 1 07/20/11 16:42 95-48-707/15/11 10:30372
3&4-Methylphenol(m&p Cresol)<372 ug/kg 1 07/20/11 16:4207/15/11 10:30372
Naphthalene <372 ug/kg 1 07/20/11 16:42 91-20-307/15/11 10:30372
2-Nitroaniline <1860 ug/kg 1 07/20/11 16:42 88-74-407/15/11 10:301860
3-Nitroaniline <1860 ug/kg 1 07/20/11 16:42 99-09-207/15/11 10:301860
4-Nitroaniline <743 ug/kg 1 07/20/11 16:42 100-01-607/15/11 10:30743
Nitrobenzene <372 ug/kg 1 07/20/11 16:42 98-95-307/15/11 10:30372
2-Nitrophenol <372 ug/kg 1 07/20/11 16:42 88-75-507/15/11 10:30372
4-Nitrophenol <1860 ug/kg 1 07/20/11 16:42 100-02-707/15/11 10:301860
N-Nitrosodimethylamine <372 ug/kg 1 07/20/11 16:42 62-75-907/15/11 10:30372
N-Nitroso-di-n-propylamine <372 ug/kg 1 07/20/11 16:42 621-64-707/15/11 10:30372
N-Nitrosodiphenylamine <372 ug/kg 1 07/20/11 16:42 86-30-607/15/11 10:30372
Pentachlorophenol <1860 ug/kg 1 07/20/11 16:42 87-86-507/15/11 10:301860
Phenanthrene <372 ug/kg 1 07/20/11 16:42 85-01-807/15/11 10:30372
Phenol <372 ug/kg 1 07/20/11 16:42 108-95-207/15/11 10:30372
Pyrene <372 ug/kg 1 07/20/11 16:42 129-00-007/15/11 10:30372
1,2,4-Trichlorobenzene <372 ug/kg 1 07/20/11 16:42 120-82-107/15/11 10:30372
2,4,5-Trichlorophenol <372 ug/kg 1 07/20/11 16:42 95-95-407/15/11 10:30372
2,4,6-Trichlorophenol <372 ug/kg 1 07/20/11 16:42 88-06-207/15/11 10:30372
Nitrobenzene-d5 (S)49 %1 07/20/11 16:42 4165-60-007/15/11 10:3023-110
2-Fluorobiphenyl (S)47 %1 07/20/11 16:42 321-60-807/15/11 10:3030-110
Terphenyl-d14 (S)57 %1 07/20/11 16:42 1718-51-007/15/11 10:3028-110
Phenol-d6 (S)50 %1 07/20/11 16:42 13127-88-307/15/11 10:3022-110
2-Fluorophenol (S)45 %1 07/20/11 16:42 367-12-407/15/11 10:3013-110
2,4,6-Tribromophenol (S)52 %1 07/20/11 16:42 118-79-607/15/11 10:3027-110
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 31 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Sample:SB-2 (16-18)Lab ID:9298263004 Collected:07/12/11 11:45 Received:07/14/11 14:28 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone <97.1 ug/kg 1 07/18/11 19:24 67-64-197.1
Benzene <4.9 ug/kg 1 07/18/11 19:24 71-43-24.9
Bromobenzene <4.9 ug/kg 1 07/18/11 19:24 108-86-14.9
Bromochloromethane <4.9 ug/kg 1 07/18/11 19:24 74-97-54.9
Bromodichloromethane <4.9 ug/kg 1 07/18/11 19:24 75-27-44.9
Bromoform <4.9 ug/kg 1 07/18/11 19:24 75-25-24.9
Bromomethane <9.7 ug/kg 1 07/18/11 19:24 74-83-99.7
2-Butanone (MEK)<97.1 ug/kg 1 07/18/11 19:24 78-93-397.1
n-Butylbenzene <4.9 ug/kg 1 07/18/11 19:24 104-51-84.9
sec-Butylbenzene <4.9 ug/kg 1 07/18/11 19:24 135-98-84.9
tert-Butylbenzene <4.9 ug/kg 1 07/18/11 19:24 98-06-64.9
Carbon tetrachloride <4.9 ug/kg 1 07/18/11 19:24 56-23-54.9
Chlorobenzene <4.9 ug/kg 1 07/18/11 19:24 108-90-74.9
Chloroethane <9.7 ug/kg 1 07/18/11 19:24 75-00-39.7
Chloroform <4.9 ug/kg 1 07/18/11 19:24 67-66-34.9
Chloromethane <9.7 ug/kg 1 07/18/11 19:24 74-87-39.7
2-Chlorotoluene <4.9 ug/kg 1 07/18/11 19:24 95-49-84.9
4-Chlorotoluene <4.9 ug/kg 1 07/18/11 19:24 106-43-44.9
1,2-Dibromo-3-chloropropane <4.9 ug/kg 1 07/18/11 19:24 96-12-84.9
Dibromochloromethane <4.9 ug/kg 1 07/18/11 19:24 124-48-14.9
1,2-Dibromoethane (EDB)<4.9 ug/kg 1 07/18/11 19:24 106-93-44.9
Dibromomethane <4.9 ug/kg 1 07/18/11 19:24 74-95-34.9
1,2-Dichlorobenzene <4.9 ug/kg 1 07/18/11 19:24 95-50-14.9
1,3-Dichlorobenzene <4.9 ug/kg 1 07/18/11 19:24 541-73-14.9
1,4-Dichlorobenzene <4.9 ug/kg 1 07/18/11 19:24 106-46-74.9
Dichlorodifluoromethane <9.7 ug/kg 1 07/18/11 19:24 75-71-89.7
1,1-Dichloroethane <4.9 ug/kg 1 07/18/11 19:24 75-34-34.9
1,2-Dichloroethane <4.9 ug/kg 1 07/18/11 19:24 107-06-24.9
1,1-Dichloroethene <4.9 ug/kg 1 07/18/11 19:24 75-35-44.9
cis-1,2-Dichloroethene <4.9 ug/kg 1 07/18/11 19:24 156-59-24.9
trans-1,2-Dichloroethene <4.9 ug/kg 1 07/18/11 19:24 156-60-54.9
1,2-Dichloropropane <4.9 ug/kg 1 07/18/11 19:24 78-87-54.9
1,3-Dichloropropane <4.9 ug/kg 1 07/18/11 19:24 142-28-94.9
2,2-Dichloropropane <4.9 ug/kg 1 07/18/11 19:24 594-20-74.9
1,1-Dichloropropene <4.9 ug/kg 1 07/18/11 19:24 563-58-64.9
cis-1,3-Dichloropropene <4.9 ug/kg 1 07/18/11 19:24 10061-01-54.9
trans-1,3-Dichloropropene <4.9 ug/kg 1 07/18/11 19:24 10061-02-64.9
Diisopropyl ether <4.9 ug/kg 1 07/18/11 19:24 108-20-34.9
Ethylbenzene <4.9 ug/kg 1 07/18/11 19:24 100-41-44.9
Hexachloro-1,3-butadiene <4.9 ug/kg 1 07/18/11 19:24 87-68-34.9
2-Hexanone <48.5 ug/kg 1 07/18/11 19:24 591-78-648.5
Isopropylbenzene (Cumene)<4.9 ug/kg 1 07/18/11 19:24 98-82-84.9
p-Isopropyltoluene <4.9 ug/kg 1 07/18/11 19:24 99-87-64.9
Methylene Chloride <19.4 ug/kg 1 07/18/11 19:24 75-09-219.4
4-Methyl-2-pentanone (MIBK)<48.5 ug/kg 1 07/18/11 19:24 108-10-148.5
Methyl-tert-butyl ether <4.9 ug/kg 1 07/18/11 19:24 1634-04-44.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 32 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Sample:SB-2 (16-18)Lab ID:9298263004 Collected:07/12/11 11:45 Received:07/14/11 14:28 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Naphthalene <4.9 ug/kg 1 07/18/11 19:24 91-20-34.9
n-Propylbenzene <4.9 ug/kg 1 07/18/11 19:24 103-65-14.9
Styrene <4.9 ug/kg 1 07/18/11 19:24 100-42-54.9
1,1,1,2-Tetrachloroethane <4.9 ug/kg 1 07/18/11 19:24 630-20-64.9
1,1,2,2-Tetrachloroethane <4.9 ug/kg 1 07/18/11 19:24 79-34-54.9
Tetrachloroethene <4.9 ug/kg 1 07/18/11 19:24 127-18-44.9
Toluene <4.9 ug/kg 1 07/18/11 19:24 108-88-34.9
1,2,3-Trichlorobenzene <4.9 ug/kg 1 07/18/11 19:24 87-61-64.9
1,2,4-Trichlorobenzene <4.9 ug/kg 1 07/18/11 19:24 120-82-14.9
1,1,1-Trichloroethane <4.9 ug/kg 1 07/18/11 19:24 71-55-64.9
1,1,2-Trichloroethane <4.9 ug/kg 1 07/18/11 19:24 79-00-54.9
Trichloroethene <4.9 ug/kg 1 07/18/11 19:24 79-01-64.9
Trichlorofluoromethane <4.9 ug/kg 1 07/18/11 19:24 75-69-44.9
1,2,3-Trichloropropane <4.9 ug/kg 1 07/18/11 19:24 96-18-44.9
1,2,4-Trimethylbenzene <4.9 ug/kg 1 07/18/11 19:24 95-63-64.9
1,3,5-Trimethylbenzene <4.9 ug/kg 1 07/18/11 19:24 108-67-84.9
Vinyl acetate <48.5 ug/kg 1 07/18/11 19:24 108-05-448.5
Vinyl chloride <9.7 ug/kg 1 07/18/11 19:24 75-01-49.7
Xylene (Total)<9.7 ug/kg 1 07/18/11 19:24 1330-20-79.7
m&p-Xylene <9.7 ug/kg 1 07/18/11 19:24 179601-23-19.7
o-Xylene <4.9 ug/kg 1 07/18/11 19:24 95-47-64.9
Dibromofluoromethane (S)109 %1 07/18/11 19:24 1868-53-770-130
Toluene-d8 (S)100 %1 07/18/11 19:24 2037-26-570-130
4-Bromofluorobenzene (S)94 %1 07/18/11 19:24 460-00-470-130
1,2-Dichloroethane-d4 (S)92 %1 07/18/11 19:24 17060-07-070-132
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 11.8 %1 07/15/11 17:390.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 33 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Sample:MW-1 Lab ID:9298263005 Collected:07/13/11 16:15 Received:07/14/11 14:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)240 ug/L 1 07/22/11 19:17 N250.0
Aliphatic (C09-C12)327 ug/L 1 07/22/11 19:17 N250.0
Aromatic (C09-C10)60.7 ug/L 1 07/22/11 19:17 N250.0
2,5-Dibromotoluene (PID)(S)109 %1 07/22/11 19:1770-130
2,5-Dibromotoluene (FID)(S)106 %1 07/22/11 19:1770-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead <5.0 ug/L 1 07/21/11 16:19 7439-92-107/16/11 10:005.0
6200B MSV Analytical Method: SM 6200B
Benzene 73.1 ug/L 1 07/20/11 01:57 71-43-20.50
Bromobenzene <0.50 ug/L 1 07/20/11 01:57 108-86-10.50
Bromochloromethane <0.50 ug/L 1 07/20/11 01:57 74-97-50.50
Bromodichloromethane <0.50 ug/L 1 07/20/11 01:57 75-27-40.50
Bromoform <0.50 ug/L 1 07/20/11 01:57 75-25-20.50
Bromomethane <5.0 ug/L 1 07/20/11 01:57 74-83-95.0
n-Butylbenzene <0.50 ug/L 1 07/20/11 01:57 104-51-80.50
sec-Butylbenzene <0.50 ug/L 1 07/20/11 01:57 135-98-80.50
tert-Butylbenzene <0.50 ug/L 1 07/20/11 01:57 98-06-60.50
Carbon tetrachloride <0.50 ug/L 1 07/20/11 01:57 56-23-50.50
Chlorobenzene <0.50 ug/L 1 07/20/11 01:57 108-90-70.50
Chloroethane <1.0 ug/L 1 07/20/11 01:57 75-00-31.0
Chloroform <0.50 ug/L 1 07/20/11 01:57 67-66-30.50
Chloromethane <1.0 ug/L 1 07/20/11 01:57 74-87-31.0
2-Chlorotoluene <0.50 ug/L 1 07/20/11 01:57 95-49-80.50
4-Chlorotoluene <0.50 ug/L 1 07/20/11 01:57 106-43-40.50
1,2-Dibromo-3-chloropropane <1.0 ug/L 1 07/20/11 01:57 96-12-81.0
Dibromochloromethane <0.50 ug/L 1 07/20/11 01:57 124-48-10.50
1,2-Dibromoethane (EDB)<0.50 ug/L 1 07/20/11 01:57 106-93-40.50
Dibromomethane <0.50 ug/L 1 07/20/11 01:57 74-95-30.50
1,2-Dichlorobenzene <0.50 ug/L 1 07/20/11 01:57 95-50-10.50
1,3-Dichlorobenzene <0.50 ug/L 1 07/20/11 01:57 541-73-10.50
1,4-Dichlorobenzene <0.50 ug/L 1 07/20/11 01:57 106-46-70.50
Dichlorodifluoromethane <0.50 ug/L 1 07/20/11 01:57 75-71-80.50
1,1-Dichloroethane <0.50 ug/L 1 07/20/11 01:57 75-34-30.50
1,2-Dichloroethane 8.7 ug/L 1 07/20/11 01:57 107-06-20.50
1,1-Dichloroethene <0.50 ug/L 1 07/20/11 01:57 75-35-40.50
cis-1,2-Dichloroethene <0.50 ug/L 1 07/20/11 01:57 156-59-20.50
trans-1,2-Dichloroethene <0.50 ug/L 1 07/20/11 01:57 156-60-50.50
1,2-Dichloropropane <0.50 ug/L 1 07/20/11 01:57 78-87-50.50
1,3-Dichloropropane <0.50 ug/L 1 07/20/11 01:57 142-28-90.50
2,2-Dichloropropane <0.50 ug/L 1 07/20/11 01:57 594-20-70.50
1,1-Dichloropropene <0.50 ug/L 1 07/20/11 01:57 563-58-60.50
cis-1,3-Dichloropropene <0.50 ug/L 1 07/20/11 01:57 10061-01-50.50
trans-1,3-Dichloropropene <0.50 ug/L 1 07/20/11 01:57 10061-02-60.50
Diisopropyl ether 87.6 ug/L 1 07/20/11 01:57 108-20-30.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 34 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Sample:MW-1 Lab ID:9298263005 Collected:07/13/11 16:15 Received:07/14/11 14:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Ethylbenzene 1.5 ug/L 1 07/20/11 01:57 100-41-40.50
Hexachloro-1,3-butadiene <2.0 ug/L 1 07/20/11 01:57 87-68-32.0
Isopropylbenzene (Cumene)2.5 ug/L 1 07/20/11 01:57 98-82-80.50
Methylene Chloride ND ug/L 1 07/20/11 01:57 75-09-23.0
Methyl-tert-butyl ether <0.50 ug/L 1 07/20/11 01:57 1634-04-40.50
Naphthalene 7.0 ug/L 1 07/20/11 01:57 91-20-32.0
n-Propylbenzene <0.50 ug/L 1 07/20/11 01:57 103-65-10.50
Styrene <0.50 ug/L 1 07/20/11 01:57 100-42-50.50
1,1,1,2-Tetrachloroethane <0.50 ug/L 1 07/20/11 01:57 630-20-60.50
1,1,2,2-Tetrachloroethane <0.50 ug/L 1 07/20/11 01:57 79-34-50.50
Tetrachloroethene <0.50 ug/L 1 07/20/11 01:57 127-18-40.50
Toluene <0.50 ug/L 1 07/20/11 01:57 108-88-30.50
1,2,3-Trichlorobenzene <2.0 ug/L 1 07/20/11 01:57 87-61-62.0
1,2,4-Trichlorobenzene <2.0 ug/L 1 07/20/11 01:57 120-82-12.0
1,1,1-Trichloroethane <0.50 ug/L 1 07/20/11 01:57 71-55-60.50
1,1,2-Trichloroethane <0.50 ug/L 1 07/20/11 01:57 79-00-50.50
Trichloroethene <0.50 ug/L 1 07/20/11 01:57 79-01-60.50
Trichlorofluoromethane <1.0 ug/L 1 07/20/11 01:57 75-69-41.0
1,2,3-Trichloropropane <0.50 ug/L 1 07/20/11 01:57 96-18-40.50
1,2,4-Trimethylbenzene 25.0 ug/L 1 07/20/11 01:57 95-63-60.50
1,3,5-Trimethylbenzene 4.6 ug/L 1 07/20/11 01:57 108-67-80.50
Vinyl chloride <1.0 ug/L 1 07/20/11 01:57 75-01-41.0
m&p-Xylene 15.7 ug/L 1 07/20/11 01:57 179601-23-11.0
o-Xylene 6.8 ug/L 1 07/20/11 01:57 95-47-60.50
1,2-Dichloroethane-d4 (S)116 %1 07/20/11 01:57 17060-07-070-130
Dibromofluoromethane (S)108 %1 07/20/11 01:57 1868-53-770-130
4-Bromofluorobenzene (S)97 %1 07/20/11 01:57 460-00-470-130
Toluene-d8 (S)97 %1 07/20/11 01:57 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 35 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Sample:MW-2 Lab ID:9298263006 Collected:07/13/11 10:05 Received:07/14/11 14:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)<100 ug/L 1 07/20/11 14:46 N207/18/11 14:00100
Aliphatic (C19-C36)<100 ug/L 1 07/20/11 14:46 N207/18/11 14:00100
Aromatic (C11-C22)<100 ug/L 1 07/20/11 14:46 N207/18/11 14:00100
Nonatriacontane (S)87 %1 07/20/11 14:46 7194-86-707/18/11 14:0040-140
o-Terphenyl (S)78 %1 07/20/11 14:46 84-15-107/18/11 14:0040-140
2-Fluorobiphenyl (S)94 %1 07/20/11 14:46 321-60-807/18/11 14:0040-140
2-Bromonaphthalene (S)97 %1 07/20/11 14:46 580-13-207/18/11 14:0040-140
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)331 ug/L 1 07/18/11 19:58 N250.0
Aliphatic (C09-C12)425 ug/L 1 07/18/11 19:58 N250.0
Aromatic (C09-C10)53.6 ug/L 1 07/18/11 19:58 N250.0
2,5-Dibromotoluene (PID)(S)111 %1 07/18/11 19:5870-130
2,5-Dibromotoluene (FID)(S)108 %1 07/18/11 19:5870-130
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene <5.0 ug/L 1 07/21/11 20:27 83-32-907/15/11 10:005.0
Acenaphthylene <5.0 ug/L 1 07/21/11 20:27 208-96-807/15/11 10:005.0
Anthracene <5.0 ug/L 1 07/21/11 20:27 120-12-707/15/11 10:005.0
Benzo(a)anthracene <5.0 ug/L 1 07/21/11 20:27 56-55-307/15/11 10:005.0
Benzo(a)pyrene <5.0 ug/L 1 07/21/11 20:27 50-32-807/15/11 10:005.0
Benzo(b)fluoranthene <5.0 ug/L 1 07/21/11 20:27 205-99-207/15/11 10:005.0
Benzo(g,h,i)perylene <5.0 ug/L 1 07/21/11 20:27 191-24-207/15/11 10:005.0
Benzo(k)fluoranthene <5.0 ug/L 1 07/21/11 20:27 207-08-907/15/11 10:005.0
4-Bromophenylphenyl ether <5.0 ug/L 1 07/21/11 20:27 101-55-307/15/11 10:005.0
Butylbenzylphthalate <5.0 ug/L 1 07/21/11 20:27 85-68-707/15/11 10:005.0
4-Chloro-3-methylphenol <5.0 ug/L 1 07/21/11 20:27 59-50-707/15/11 10:005.0
bis(2-Chloroethoxy)methane <10.0 ug/L 1 07/21/11 20:27 111-91-107/15/11 10:0010.0
bis(2-Chloroethyl) ether <5.0 ug/L 1 07/21/11 20:27 111-44-407/15/11 10:005.0
bis(2-Chloroisopropyl) ether <5.0 ug/L 1 07/21/11 20:27 108-60-107/15/11 10:005.0
2-Chloronaphthalene <5.0 ug/L 1 07/21/11 20:27 91-58-707/15/11 10:005.0
2-Chlorophenol <5.0 ug/L 1 07/21/11 20:27 95-57-807/15/11 10:005.0
4-Chlorophenylphenyl ether <5.0 ug/L 1 07/21/11 20:27 7005-72-307/15/11 10:005.0
Chrysene <5.0 ug/L 1 07/21/11 20:27 218-01-907/15/11 10:005.0
Dibenz(a,h)anthracene <5.0 ug/L 1 07/21/11 20:27 53-70-307/15/11 10:005.0
3,3'-Dichlorobenzidine <25.0 ug/L 1 07/21/11 20:27 91-94-107/15/11 10:0025.0
2,4-Dichlorophenol <5.0 ug/L 1 07/21/11 20:27 120-83-207/15/11 10:005.0
Diethylphthalate <5.0 ug/L 1 07/21/11 20:27 84-66-207/15/11 10:005.0
2,4-Dimethylphenol <10.0 ug/L 1 07/21/11 20:27 105-67-907/15/11 10:0010.0
Dimethylphthalate <5.0 ug/L 1 07/21/11 20:27 131-11-307/15/11 10:005.0
Di-n-butylphthalate <5.0 ug/L 1 07/21/11 20:27 84-74-207/15/11 10:005.0
4,6-Dinitro-2-methylphenol <20.0 ug/L 1 07/21/11 20:27 534-52-107/15/11 10:0020.0
2,4-Dinitrophenol <50.0 ug/L 1 07/21/11 20:27 51-28-507/15/11 10:0050.0
2,4-Dinitrotoluene <5.0 ug/L 1 07/21/11 20:27 121-14-207/15/11 10:005.0
2,6-Dinitrotoluene <5.0 ug/L 1 07/21/11 20:27 606-20-207/15/11 10:005.0
Di-n-octylphthalate <5.0 ug/L 1 07/21/11 20:27 117-84-007/15/11 10:005.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 36 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Sample:MW-2 Lab ID:9298263006 Collected:07/13/11 10:05 Received:07/14/11 14:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
bis(2-Ethylhexyl)phthalate <5.0 ug/L 1 07/21/11 20:27 117-81-707/15/11 10:005.0
Fluoranthene <5.0 ug/L 1 07/21/11 20:27 206-44-007/15/11 10:005.0
Fluorene <5.0 ug/L 1 07/21/11 20:27 86-73-707/15/11 10:005.0
Hexachloro-1,3-butadiene <5.0 ug/L 1 07/21/11 20:27 87-68-307/15/11 10:005.0
Hexachlorobenzene <5.0 ug/L 1 07/21/11 20:27 118-74-107/15/11 10:005.0
Hexachlorocyclopentadiene <10.0 ug/L 1 07/21/11 20:27 77-47-407/15/11 10:0010.0
Hexachloroethane <5.0 ug/L 1 07/21/11 20:27 67-72-107/15/11 10:005.0
Indeno(1,2,3-cd)pyrene <5.0 ug/L 1 07/21/11 20:27 193-39-507/15/11 10:005.0
Isophorone <10.0 ug/L 1 07/21/11 20:27 78-59-107/15/11 10:0010.0
Naphthalene <5.0 ug/L 1 07/21/11 20:27 91-20-307/15/11 10:005.0
Nitrobenzene <5.0 ug/L 1 07/21/11 20:27 98-95-307/15/11 10:005.0
2-Nitrophenol <5.0 ug/L 1 07/21/11 20:27 88-75-507/15/11 10:005.0
4-Nitrophenol <50.0 ug/L 1 07/21/11 20:27 100-02-707/15/11 10:0050.0
N-Nitrosodimethylamine <5.0 ug/L 1 07/21/11 20:27 62-75-907/15/11 10:005.0
N-Nitroso-di-n-propylamine <5.0 ug/L 1 07/21/11 20:27 621-64-707/15/11 10:005.0
N-Nitrosodiphenylamine <10.0 ug/L 1 07/21/11 20:27 86-30-607/15/11 10:0010.0
Pentachlorophenol <25.0 ug/L 1 07/21/11 20:27 87-86-507/15/11 10:0025.0
Phenanthrene <5.0 ug/L 1 07/21/11 20:27 85-01-807/15/11 10:005.0
Phenol <5.0 ug/L 1 07/21/11 20:27 108-95-207/15/11 10:005.0
Pyrene <5.0 ug/L 1 07/21/11 20:27 129-00-007/15/11 10:005.0
1,2,4-Trichlorobenzene <5.0 ug/L 1 07/21/11 20:27 120-82-107/15/11 10:005.0
2,4,6-Trichlorophenol <10.0 ug/L 1 07/21/11 20:27 88-06-207/15/11 10:0010.0
Nitrobenzene-d5 (S)74 %1 07/21/11 20:27 4165-60-007/15/11 10:0010-120
2-Fluorobiphenyl (S)72 %1 07/21/11 20:27 321-60-807/15/11 10:0015-120
Terphenyl-d14 (S)75 %1 07/21/11 20:27 1718-51-007/15/11 10:0011-131
Phenol-d6 (S)36 %1 07/21/11 20:27 13127-88-307/15/11 10:0010-120
2-Fluorophenol (S)50 %1 07/21/11 20:27 367-12-407/15/11 10:0010-120
2,4,6-Tribromophenol (S)80 %1 07/21/11 20:27 118-79-607/15/11 10:0010-137
6200B MSV Analytical Method: SM 6200B
Benzene 70.8 ug/L 1 07/20/11 02:19 71-43-20.50
Bromobenzene <0.50 ug/L 1 07/20/11 02:19 108-86-10.50
Bromochloromethane <0.50 ug/L 1 07/20/11 02:19 74-97-50.50
Bromodichloromethane <0.50 ug/L 1 07/20/11 02:19 75-27-40.50
Bromoform <0.50 ug/L 1 07/20/11 02:19 75-25-20.50
Bromomethane <5.0 ug/L 1 07/20/11 02:19 74-83-95.0
n-Butylbenzene <0.50 ug/L 1 07/20/11 02:19 104-51-80.50
sec-Butylbenzene <0.50 ug/L 1 07/20/11 02:19 135-98-80.50
tert-Butylbenzene <0.50 ug/L 1 07/20/11 02:19 98-06-60.50
Carbon tetrachloride <0.50 ug/L 1 07/20/11 02:19 56-23-50.50
Chlorobenzene <0.50 ug/L 1 07/20/11 02:19 108-90-70.50
Chloroethane <1.0 ug/L 1 07/20/11 02:19 75-00-31.0
Chloroform <0.50 ug/L 1 07/20/11 02:19 67-66-30.50
Chloromethane 2.8 ug/L 1 07/20/11 02:19 74-87-31.0
2-Chlorotoluene <0.50 ug/L 1 07/20/11 02:19 95-49-80.50
4-Chlorotoluene <0.50 ug/L 1 07/20/11 02:19 106-43-40.50
1,2-Dibromo-3-chloropropane <1.0 ug/L 1 07/20/11 02:19 96-12-81.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 37 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Sample:MW-2 Lab ID:9298263006 Collected:07/13/11 10:05 Received:07/14/11 14:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Dibromochloromethane <0.50 ug/L 1 07/20/11 02:19 124-48-10.50
1,2-Dibromoethane (EDB)<0.50 ug/L 1 07/20/11 02:19 106-93-40.50
Dibromomethane <0.50 ug/L 1 07/20/11 02:19 74-95-30.50
1,2-Dichlorobenzene <0.50 ug/L 1 07/20/11 02:19 95-50-10.50
1,3-Dichlorobenzene <0.50 ug/L 1 07/20/11 02:19 541-73-10.50
1,4-Dichlorobenzene <0.50 ug/L 1 07/20/11 02:19 106-46-70.50
Dichlorodifluoromethane <0.50 ug/L 1 07/20/11 02:19 75-71-80.50
1,1-Dichloroethane <0.50 ug/L 1 07/20/11 02:19 75-34-30.50
1,2-Dichloroethane 11.8 ug/L 1 07/20/11 02:19 107-06-20.50
1,1-Dichloroethene <0.50 ug/L 1 07/20/11 02:19 75-35-40.50
cis-1,2-Dichloroethene <0.50 ug/L 1 07/20/11 02:19 156-59-20.50
trans-1,2-Dichloroethene <0.50 ug/L 1 07/20/11 02:19 156-60-50.50
1,2-Dichloropropane <0.50 ug/L 1 07/20/11 02:19 78-87-50.50
1,3-Dichloropropane <0.50 ug/L 1 07/20/11 02:19 142-28-90.50
2,2-Dichloropropane <0.50 ug/L 1 07/20/11 02:19 594-20-70.50
1,1-Dichloropropene <0.50 ug/L 1 07/20/11 02:19 563-58-60.50
cis-1,3-Dichloropropene <0.50 ug/L 1 07/20/11 02:19 10061-01-50.50
trans-1,3-Dichloropropene <0.50 ug/L 1 07/20/11 02:19 10061-02-60.50
Diisopropyl ether 93.9 ug/L 1 07/20/11 02:19 108-20-30.50
Ethylbenzene 10.1 ug/L 1 07/20/11 02:19 100-41-40.50
Hexachloro-1,3-butadiene <2.0 ug/L 1 07/20/11 02:19 87-68-32.0
Isopropylbenzene (Cumene)2.8 ug/L 1 07/20/11 02:19 98-82-80.50
Methylene Chloride <2.0 ug/L 1 07/20/11 02:19 75-09-22.0
Methyl-tert-butyl ether 1.7 ug/L 1 07/20/11 02:19 1634-04-40.50
Naphthalene 6.3 ug/L 1 07/20/11 02:19 91-20-32.0
n-Propylbenzene 1.2 ug/L 1 07/20/11 02:19 103-65-10.50
Styrene <0.50 ug/L 1 07/20/11 02:19 100-42-50.50
1,1,1,2-Tetrachloroethane <0.50 ug/L 1 07/20/11 02:19 630-20-60.50
1,1,2,2-Tetrachloroethane <0.50 ug/L 1 07/20/11 02:19 79-34-50.50
Tetrachloroethene <0.50 ug/L 1 07/20/11 02:19 127-18-40.50
Toluene 2.3 ug/L 1 07/20/11 02:19 108-88-30.50
1,2,3-Trichlorobenzene <2.0 ug/L 1 07/20/11 02:19 87-61-62.0
1,2,4-Trichlorobenzene <2.0 ug/L 1 07/20/11 02:19 120-82-12.0
1,1,1-Trichloroethane <0.50 ug/L 1 07/20/11 02:19 71-55-60.50
1,1,2-Trichloroethane <0.50 ug/L 1 07/20/11 02:19 79-00-50.50
Trichloroethene <0.50 ug/L 1 07/20/11 02:19 79-01-60.50
Trichlorofluoromethane <1.0 ug/L 1 07/20/11 02:19 75-69-41.0
1,2,3-Trichloropropane <0.50 ug/L 1 07/20/11 02:19 96-18-40.50
1,2,4-Trimethylbenzene 15.9 ug/L 1 07/20/11 02:19 95-63-60.50
1,3,5-Trimethylbenzene <0.50 ug/L 1 07/20/11 02:19 108-67-80.50
Vinyl chloride <1.0 ug/L 1 07/20/11 02:19 75-01-41.0
m&p-Xylene 38.2 ug/L 1 07/20/11 02:19 179601-23-11.0
o-Xylene 19.7 ug/L 1 07/20/11 02:19 95-47-60.50
1,2-Dichloroethane-d4 (S)116 %1 07/20/11 02:19 17060-07-070-130
Dibromofluoromethane (S)107 %1 07/20/11 02:19 1868-53-770-130
4-Bromofluorobenzene (S)97 %1 07/20/11 02:19 460-00-470-130
Toluene-d8 (S)97 %1 07/20/11 02:19 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 38 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Sample:MW-3 Lab ID:9298263007 Collected:07/13/11 12:45 Received:07/14/11 14:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Benzene 64.4 ug/L 1 07/20/11 02:42 71-43-20.50
Bromobenzene <0.50 ug/L 1 07/20/11 02:42 108-86-10.50
Bromochloromethane <0.50 ug/L 1 07/20/11 02:42 74-97-50.50
Bromodichloromethane <0.50 ug/L 1 07/20/11 02:42 75-27-40.50
Bromoform <0.50 ug/L 1 07/20/11 02:42 75-25-20.50
Bromomethane <5.0 ug/L 1 07/20/11 02:42 74-83-95.0
n-Butylbenzene <0.50 ug/L 1 07/20/11 02:42 104-51-80.50
sec-Butylbenzene <0.50 ug/L 1 07/20/11 02:42 135-98-80.50
tert-Butylbenzene <0.50 ug/L 1 07/20/11 02:42 98-06-60.50
Carbon tetrachloride <0.50 ug/L 1 07/20/11 02:42 56-23-50.50
Chlorobenzene <0.50 ug/L 1 07/20/11 02:42 108-90-70.50
Chloroethane <1.0 ug/L 1 07/20/11 02:42 75-00-31.0
Chloroform <0.50 ug/L 1 07/20/11 02:42 67-66-30.50
Chloromethane <1.0 ug/L 1 07/20/11 02:42 74-87-31.0
2-Chlorotoluene <0.50 ug/L 1 07/20/11 02:42 95-49-80.50
4-Chlorotoluene <0.50 ug/L 1 07/20/11 02:42 106-43-40.50
1,2-Dibromo-3-chloropropane <1.0 ug/L 1 07/20/11 02:42 96-12-81.0
Dibromochloromethane <0.50 ug/L 1 07/20/11 02:42 124-48-10.50
1,2-Dibromoethane (EDB)<0.50 ug/L 1 07/20/11 02:42 106-93-40.50
Dibromomethane <0.50 ug/L 1 07/20/11 02:42 74-95-30.50
1,2-Dichlorobenzene <0.50 ug/L 1 07/20/11 02:42 95-50-10.50
1,3-Dichlorobenzene <0.50 ug/L 1 07/20/11 02:42 541-73-10.50
1,4-Dichlorobenzene <0.50 ug/L 1 07/20/11 02:42 106-46-70.50
Dichlorodifluoromethane <0.50 ug/L 1 07/20/11 02:42 75-71-80.50
1,1-Dichloroethane <0.50 ug/L 1 07/20/11 02:42 75-34-30.50
1,2-Dichloroethane 2.7 ug/L 1 07/20/11 02:42 107-06-20.50
1,1-Dichloroethene <0.50 ug/L 1 07/20/11 02:42 75-35-40.50
cis-1,2-Dichloroethene <0.50 ug/L 1 07/20/11 02:42 156-59-20.50
trans-1,2-Dichloroethene <0.50 ug/L 1 07/20/11 02:42 156-60-50.50
1,2-Dichloropropane <0.50 ug/L 1 07/20/11 02:42 78-87-50.50
1,3-Dichloropropane <0.50 ug/L 1 07/20/11 02:42 142-28-90.50
2,2-Dichloropropane <0.50 ug/L 1 07/20/11 02:42 594-20-70.50
1,1-Dichloropropene <0.50 ug/L 1 07/20/11 02:42 563-58-60.50
cis-1,3-Dichloropropene <0.50 ug/L 1 07/20/11 02:42 10061-01-50.50
trans-1,3-Dichloropropene <0.50 ug/L 1 07/20/11 02:42 10061-02-60.50
Diisopropyl ether 17.0 ug/L 1 07/20/11 02:42 108-20-30.50
Ethylbenzene <0.50 ug/L 1 07/20/11 02:42 100-41-40.50
Hexachloro-1,3-butadiene <2.0 ug/L 1 07/20/11 02:42 87-68-32.0
Isopropylbenzene (Cumene)2.0 ug/L 1 07/20/11 02:42 98-82-80.50
Methylene Chloride <2.0 ug/L 1 07/20/11 02:42 75-09-22.0
Methyl-tert-butyl ether <0.50 ug/L 1 07/20/11 02:42 1634-04-40.50
Naphthalene 4.3 ug/L 1 07/20/11 02:42 91-20-32.0
n-Propylbenzene <0.50 ug/L 1 07/20/11 02:42 103-65-10.50
Styrene <0.50 ug/L 1 07/20/11 02:42 100-42-50.50
1,1,1,2-Tetrachloroethane <0.50 ug/L 1 07/20/11 02:42 630-20-60.50
1,1,2,2-Tetrachloroethane <0.50 ug/L 1 07/20/11 02:42 79-34-50.50
Tetrachloroethene <0.50 ug/L 1 07/20/11 02:42 127-18-40.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 39 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Sample:MW-3 Lab ID:9298263007 Collected:07/13/11 12:45 Received:07/14/11 14:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Toluene <0.50 ug/L 1 07/20/11 02:42 108-88-30.50
1,2,3-Trichlorobenzene <2.0 ug/L 1 07/20/11 02:42 87-61-62.0
1,2,4-Trichlorobenzene <2.0 ug/L 1 07/20/11 02:42 120-82-12.0
1,1,1-Trichloroethane <0.50 ug/L 1 07/20/11 02:42 71-55-60.50
1,1,2-Trichloroethane <0.50 ug/L 1 07/20/11 02:42 79-00-50.50
Trichloroethene <0.50 ug/L 1 07/20/11 02:42 79-01-60.50
Trichlorofluoromethane <1.0 ug/L 1 07/20/11 02:42 75-69-41.0
1,2,3-Trichloropropane <0.50 ug/L 1 07/20/11 02:42 96-18-40.50
1,2,4-Trimethylbenzene <0.50 ug/L 1 07/20/11 02:42 95-63-60.50
1,3,5-Trimethylbenzene <0.50 ug/L 1 07/20/11 02:42 108-67-80.50
Vinyl chloride <1.0 ug/L 1 07/20/11 02:42 75-01-41.0
m&p-Xylene <1.0 ug/L 1 07/20/11 02:42 179601-23-11.0
o-Xylene <0.50 ug/L 1 07/20/11 02:42 95-47-60.50
1,2-Dichloroethane-d4 (S)116 %1 07/20/11 02:42 17060-07-070-130
Dibromofluoromethane (S)107 %1 07/20/11 02:42 1868-53-770-130
4-Bromofluorobenzene (S)94 %1 07/20/11 02:42 460-00-470-130
Toluene-d8 (S)97 %1 07/20/11 02:42 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 40 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Sample:MW-4 Lab ID:9298263008 Collected:07/13/11 08:40 Received:07/14/11 14:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Benzene 153 ug/L 1 07/20/11 03:05 71-43-20.50
Bromobenzene <0.50 ug/L 1 07/20/11 03:05 108-86-10.50
Bromochloromethane <0.50 ug/L 1 07/20/11 03:05 74-97-50.50
Bromodichloromethane <0.50 ug/L 1 07/20/11 03:05 75-27-40.50
Bromoform <0.50 ug/L 1 07/20/11 03:05 75-25-20.50
Bromomethane <5.0 ug/L 1 07/20/11 03:05 74-83-95.0
n-Butylbenzene <0.50 ug/L 1 07/20/11 03:05 104-51-80.50
sec-Butylbenzene <0.50 ug/L 1 07/20/11 03:05 135-98-80.50
tert-Butylbenzene 1.6 ug/L 1 07/20/11 03:05 98-06-60.50
Carbon tetrachloride <0.50 ug/L 1 07/20/11 03:05 56-23-50.50
Chlorobenzene <0.50 ug/L 1 07/20/11 03:05 108-90-70.50
Chloroethane <1.0 ug/L 1 07/20/11 03:05 75-00-31.0
Chloroform <0.50 ug/L 1 07/20/11 03:05 67-66-30.50
Chloromethane <1.0 ug/L 1 07/20/11 03:05 74-87-31.0
2-Chlorotoluene <0.50 ug/L 1 07/20/11 03:05 95-49-80.50
4-Chlorotoluene <0.50 ug/L 1 07/20/11 03:05 106-43-40.50
1,2-Dibromo-3-chloropropane <1.0 ug/L 1 07/20/11 03:05 96-12-81.0
Dibromochloromethane <0.50 ug/L 1 07/20/11 03:05 124-48-10.50
1,2-Dibromoethane (EDB)<0.50 ug/L 1 07/20/11 03:05 106-93-40.50
Dibromomethane <0.50 ug/L 1 07/20/11 03:05 74-95-30.50
1,2-Dichlorobenzene <0.50 ug/L 1 07/20/11 03:05 95-50-10.50
1,3-Dichlorobenzene <0.50 ug/L 1 07/20/11 03:05 541-73-10.50
1,4-Dichlorobenzene <0.50 ug/L 1 07/20/11 03:05 106-46-70.50
Dichlorodifluoromethane <0.50 ug/L 1 07/20/11 03:05 75-71-80.50
1,1-Dichloroethane <0.50 ug/L 1 07/20/11 03:05 75-34-30.50
1,2-Dichloroethane 7.1 ug/L 1 07/20/11 03:05 107-06-20.50
1,1-Dichloroethene <0.50 ug/L 1 07/20/11 03:05 75-35-40.50
cis-1,2-Dichloroethene <0.50 ug/L 1 07/20/11 03:05 156-59-20.50
trans-1,2-Dichloroethene <0.50 ug/L 1 07/20/11 03:05 156-60-50.50
1,2-Dichloropropane <0.50 ug/L 1 07/20/11 03:05 78-87-50.50
1,3-Dichloropropane <0.50 ug/L 1 07/20/11 03:05 142-28-90.50
2,2-Dichloropropane <0.50 ug/L 1 07/20/11 03:05 594-20-70.50
1,1-Dichloropropene <0.50 ug/L 1 07/20/11 03:05 563-58-60.50
cis-1,3-Dichloropropene <0.50 ug/L 1 07/20/11 03:05 10061-01-50.50
trans-1,3-Dichloropropene <0.50 ug/L 1 07/20/11 03:05 10061-02-60.50
Diisopropyl ether 46.3 ug/L 1 07/20/11 03:05 108-20-30.50
Ethylbenzene 8.6 ug/L 1 07/20/11 03:05 100-41-40.50
Hexachloro-1,3-butadiene <2.0 ug/L 1 07/20/11 03:05 87-68-32.0
Isopropylbenzene (Cumene)9.0 ug/L 1 07/20/11 03:05 98-82-80.50
Methylene Chloride <2.0 ug/L 1 07/20/11 03:05 75-09-22.0
Methyl-tert-butyl ether <0.50 ug/L 1 07/20/11 03:05 1634-04-40.50
Naphthalene 21.8 ug/L 1 07/20/11 03:05 91-20-32.0
n-Propylbenzene 16.9 ug/L 1 07/20/11 03:05 103-65-10.50
Styrene <0.50 ug/L 1 07/20/11 03:05 100-42-50.50
1,1,1,2-Tetrachloroethane <0.50 ug/L 1 07/20/11 03:05 630-20-60.50
1,1,2,2-Tetrachloroethane <0.50 ug/L 1 07/20/11 03:05 79-34-50.50
Tetrachloroethene <0.50 ug/L 1 07/20/11 03:05 127-18-40.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 41 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Sample:MW-4 Lab ID:9298263008 Collected:07/13/11 08:40 Received:07/14/11 14:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Toluene <0.50 ug/L 1 07/20/11 03:05 108-88-30.50
1,2,3-Trichlorobenzene <2.0 ug/L 1 07/20/11 03:05 87-61-62.0
1,2,4-Trichlorobenzene <2.0 ug/L 1 07/20/11 03:05 120-82-12.0
1,1,1-Trichloroethane <0.50 ug/L 1 07/20/11 03:05 71-55-60.50
1,1,2-Trichloroethane <0.50 ug/L 1 07/20/11 03:05 79-00-50.50
Trichloroethene <0.50 ug/L 1 07/20/11 03:05 79-01-60.50
Trichlorofluoromethane <1.0 ug/L 1 07/20/11 03:05 75-69-41.0
1,2,3-Trichloropropane <0.50 ug/L 1 07/20/11 03:05 96-18-40.50
1,2,4-Trimethylbenzene 36.0 ug/L 1 07/20/11 03:05 95-63-60.50
1,3,5-Trimethylbenzene <0.50 ug/L 1 07/20/11 03:05 108-67-80.50
Vinyl chloride <1.0 ug/L 1 07/20/11 03:05 75-01-41.0
m&p-Xylene 6.3 ug/L 1 07/20/11 03:05 179601-23-11.0
o-Xylene 10.7 ug/L 1 07/20/11 03:05 95-47-60.50
1,2-Dichloroethane-d4 (S)116 %1 07/20/11 03:05 17060-07-070-130
Dibromofluoromethane (S)106 %1 07/20/11 03:05 1868-53-770-130
4-Bromofluorobenzene (S)97 %1 07/20/11 03:05 460-00-470-130
Toluene-d8 (S)96 %1 07/20/11 03:05 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 42 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Sample:MW-5 Lab ID:9298263009 Collected:07/13/11 16:00 Received:07/14/11 14:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Benzene 8.7 ug/L 1 07/20/11 03:28 71-43-20.50
Bromobenzene <0.50 ug/L 1 07/20/11 03:28 108-86-10.50
Bromochloromethane <0.50 ug/L 1 07/20/11 03:28 74-97-50.50
Bromodichloromethane <0.50 ug/L 1 07/20/11 03:28 75-27-40.50
Bromoform <0.50 ug/L 1 07/20/11 03:28 75-25-20.50
Bromomethane <5.0 ug/L 1 07/20/11 03:28 74-83-95.0
n-Butylbenzene <0.50 ug/L 1 07/20/11 03:28 104-51-80.50
sec-Butylbenzene <0.50 ug/L 1 07/20/11 03:28 135-98-80.50
tert-Butylbenzene <0.50 ug/L 1 07/20/11 03:28 98-06-60.50
Carbon tetrachloride <0.50 ug/L 1 07/20/11 03:28 56-23-50.50
Chlorobenzene <0.50 ug/L 1 07/20/11 03:28 108-90-70.50
Chloroethane <1.0 ug/L 1 07/20/11 03:28 75-00-31.0
Chloroform <0.50 ug/L 1 07/20/11 03:28 67-66-30.50
Chloromethane <1.0 ug/L 1 07/20/11 03:28 74-87-31.0
2-Chlorotoluene <0.50 ug/L 1 07/20/11 03:28 95-49-80.50
4-Chlorotoluene <0.50 ug/L 1 07/20/11 03:28 106-43-40.50
1,2-Dibromo-3-chloropropane <1.0 ug/L 1 07/20/11 03:28 96-12-81.0
Dibromochloromethane <0.50 ug/L 1 07/20/11 03:28 124-48-10.50
1,2-Dibromoethane (EDB)<0.50 ug/L 1 07/20/11 03:28 106-93-40.50
Dibromomethane <0.50 ug/L 1 07/20/11 03:28 74-95-30.50
1,2-Dichlorobenzene <0.50 ug/L 1 07/20/11 03:28 95-50-10.50
1,3-Dichlorobenzene <0.50 ug/L 1 07/20/11 03:28 541-73-10.50
1,4-Dichlorobenzene <0.50 ug/L 1 07/20/11 03:28 106-46-70.50
Dichlorodifluoromethane <0.50 ug/L 1 07/20/11 03:28 75-71-80.50
1,1-Dichloroethane <0.50 ug/L 1 07/20/11 03:28 75-34-30.50
1,2-Dichloroethane 6.5 ug/L 1 07/20/11 03:28 107-06-20.50
1,1-Dichloroethene <0.50 ug/L 1 07/20/11 03:28 75-35-40.50
cis-1,2-Dichloroethene <0.50 ug/L 1 07/20/11 03:28 156-59-20.50
trans-1,2-Dichloroethene <0.50 ug/L 1 07/20/11 03:28 156-60-50.50
1,2-Dichloropropane <0.50 ug/L 1 07/20/11 03:28 78-87-50.50
1,3-Dichloropropane <0.50 ug/L 1 07/20/11 03:28 142-28-90.50
2,2-Dichloropropane <0.50 ug/L 1 07/20/11 03:28 594-20-70.50
1,1-Dichloropropene <0.50 ug/L 1 07/20/11 03:28 563-58-60.50
cis-1,3-Dichloropropene <0.50 ug/L 1 07/20/11 03:28 10061-01-50.50
trans-1,3-Dichloropropene <0.50 ug/L 1 07/20/11 03:28 10061-02-60.50
Diisopropyl ether 46.9 ug/L 1 07/20/11 03:28 108-20-30.50
Ethylbenzene <0.50 ug/L 1 07/20/11 03:28 100-41-40.50
Hexachloro-1,3-butadiene <2.0 ug/L 1 07/20/11 03:28 87-68-32.0
Isopropylbenzene (Cumene)<0.50 ug/L 1 07/20/11 03:28 98-82-80.50
Methylene Chloride <2.0 ug/L 1 07/20/11 03:28 75-09-22.0
Methyl-tert-butyl ether <0.50 ug/L 1 07/20/11 03:28 1634-04-40.50
Naphthalene <2.0 ug/L 1 07/20/11 03:28 91-20-32.0
n-Propylbenzene <0.50 ug/L 1 07/20/11 03:28 103-65-10.50
Styrene <0.50 ug/L 1 07/20/11 03:28 100-42-50.50
1,1,1,2-Tetrachloroethane <0.50 ug/L 1 07/20/11 03:28 630-20-60.50
1,1,2,2-Tetrachloroethane <0.50 ug/L 1 07/20/11 03:28 79-34-50.50
Tetrachloroethene <0.50 ug/L 1 07/20/11 03:28 127-18-40.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 43 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Sample:MW-5 Lab ID:9298263009 Collected:07/13/11 16:00 Received:07/14/11 14:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Toluene <0.50 ug/L 1 07/20/11 03:28 108-88-30.50
1,2,3-Trichlorobenzene <2.0 ug/L 1 07/20/11 03:28 87-61-62.0
1,2,4-Trichlorobenzene <2.0 ug/L 1 07/20/11 03:28 120-82-12.0
1,1,1-Trichloroethane <0.50 ug/L 1 07/20/11 03:28 71-55-60.50
1,1,2-Trichloroethane <0.50 ug/L 1 07/20/11 03:28 79-00-50.50
Trichloroethene <0.50 ug/L 1 07/20/11 03:28 79-01-60.50
Trichlorofluoromethane <1.0 ug/L 1 07/20/11 03:28 75-69-41.0
1,2,3-Trichloropropane <0.50 ug/L 1 07/20/11 03:28 96-18-40.50
1,2,4-Trimethylbenzene <0.50 ug/L 1 07/20/11 03:28 95-63-60.50
1,3,5-Trimethylbenzene <0.50 ug/L 1 07/20/11 03:28 108-67-80.50
Vinyl chloride <1.0 ug/L 1 07/20/11 03:28 75-01-41.0
m&p-Xylene <1.0 ug/L 1 07/20/11 03:28 179601-23-11.0
o-Xylene <0.50 ug/L 1 07/20/11 03:28 95-47-60.50
1,2-Dichloroethane-d4 (S)116 %1 07/20/11 03:28 17060-07-070-130
Dibromofluoromethane (S)106 %1 07/20/11 03:28 1868-53-770-130
4-Bromofluorobenzene (S)92 %1 07/20/11 03:28 460-00-470-130
Toluene-d8 (S)96 %1 07/20/11 03:28 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 44 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/14234
MADEP EPH
MADEP EPH
MADEP EPH NC Soil
Associated Lab Samples:9298263003, 9298263004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:635041
Associated Lab Samples:9298263003, 9298263004
Matrix:Solid
Analyzed
Aliphatic (C09-C18)mg/kg <10.0 10.0 N207/21/11 16:11
Aliphatic (C19-C36)mg/kg <10.0 10.0 N207/21/11 16:11
Aromatic (C11-C22)mg/kg <10.0 10.0 N207/21/11 16:11
2-Bromonaphthalene (S)%89 40-140 07/21/11 16:11
2-Fluorobiphenyl (S)%90 40-140 07/21/11 16:11
Nonatriacontane (S)%74 40-140 07/21/11 16:11
o-Terphenyl (S)%69 40-140 07/21/11 16:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
635042LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
635043
Aliphatic (C09-C18)mg/kg <10.0 N2108140-14077<10.0 50
Aliphatic (C19-C36)mg/kg 11.2 N213.3 84 40-1408611.5 3 50
Aromatic (C11-C22)mg/kg 24.9 N228.3 88 40-1409326.5 6 50
2-Bromonaphthalene (S)%87 40-14095
2-Fluorobiphenyl (S)%91 40-140104
Nonatriacontane (S)%79 40-14091
o-Terphenyl (S)%81 40-14086
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 45 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/14244
MADEP EPH
MADEP EPH
MADEP EPH NC Water
Associated Lab Samples:9298263006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:635295
Associated Lab Samples:9298263006
Matrix:Water
Analyzed
Aliphatic (C09-C18)ug/L <100 100 N207/20/11 14:10
Aliphatic (C19-C36)ug/L <100 100 N207/20/11 14:10
Aromatic (C11-C22)ug/L <100 100 N207/20/11 14:10
2-Bromonaphthalene (S)%89 40-140 07/20/11 14:10
2-Fluorobiphenyl (S)%96 40-140 07/20/11 14:10
Nonatriacontane (S)%90 40-140 07/20/11 14:10
o-Terphenyl (S)%84 40-140 07/20/11 14:10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
635296LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
635297
Aliphatic (C09-C18)ug/L 193 N23006440-14072217 12 50
Aliphatic (C19-C36)ug/L 303 N24007640-14082327 7 50
Aromatic (C11-C22)ug/L 684 N28508040-14078667 3 50
2-Bromonaphthalene (S)%86 40-14091
2-Fluorobiphenyl (S)%92 40-14097
Nonatriacontane (S)%88 40-14093
o-Terphenyl (S)%75 40-14075
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 46 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/5205
MADEP VPH
MADEP VPH
VPH NC Soil
Associated Lab Samples:9298263001, 9298263002, 9298263003, 9298263004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:633579
Associated Lab Samples:9298263001, 9298263002, 9298263003, 9298263004
Matrix:Solid
Analyzed
Aliphatic (C05-C08)mg/kg <2.5 2.5 N207/15/11 16:16
Aliphatic (C09-C12)mg/kg <2.5 2.5 N207/15/11 16:16
Aromatic (C09-C10)mg/kg <2.5 2.5 N207/15/11 16:16
2,5-Dibromotoluene (FID)(S)%112 70-130 07/15/11 16:16
2,5-Dibromotoluene (PID)(S)%118 70-130 07/15/11 16:16
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
633580LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
633581
Aliphatic (C05-C08)mg/kg 13.7 N2159170-1308612.9 6 25
Aliphatic (C09-C12)mg/kg 18.8 N21512530-13011517.2 9 25
Aromatic (C09-C10)mg/kg 5.2 N2510470-1301005.0 4 25
2,5-Dibromotoluene (FID)(S)%111 70-130110
2,5-Dibromotoluene (PID)(S)%118 70-130114
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 47 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/5213
MADEP VPH
MADEP VPH
VPH NC Water
Associated Lab Samples:9298263006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:635110
Associated Lab Samples:9298263006
Matrix:Water
Analyzed
Aliphatic (C05-C08)ug/L <50.0 50.0 N207/18/11 21:37
Aliphatic (C09-C12)ug/L <50.0 50.0 N207/18/11 21:37
Aromatic (C09-C10)ug/L <50.0 50.0 N207/18/11 21:37
2,5-Dibromotoluene (FID)(S)%118 70-130 07/18/11 21:37
2,5-Dibromotoluene (PID)(S)%124 70-130 07/18/11 21:37
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
635111LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
635112
Aliphatic (C05-C08)ug/L 265 N23008870-13084252 5 25
Aliphatic (C09-C12)ug/L 347 N230011630-130115344 1 25
Aromatic (C09-C10)ug/L 101 N210010170-1309998.6 3 25
2,5-Dibromotoluene (FID)(S)%116 70-130106
2,5-Dibromotoluene (PID)(S)%122 70-130110
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 48 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/5226
MADEP VPH
MADEP VPH
VPH NC Water
Associated Lab Samples:9298263005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:636848
Associated Lab Samples:9298263005
Matrix:Water
Analyzed
Aliphatic (C05-C08)ug/L <50.0 50.0 N207/22/11 17:38
Aliphatic (C09-C12)ug/L <50.0 50.0 N207/22/11 17:38
Aromatic (C09-C10)ug/L <50.0 50.0 N207/22/11 17:38
2,5-Dibromotoluene (FID)(S)%124 70-130 07/22/11 17:38
2,5-Dibromotoluene (PID)(S)%127 70-130 07/22/11 17:38
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
636849LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
636850
Aliphatic (C05-C08)ug/L 261 N23008770-13083250 4 25
Aliphatic (C09-C12)ug/L 368 N230012330-130122365 1 25
Aromatic (C09-C10)ug/L 105 N210010570-130103103 2 25
2,5-Dibromotoluene (FID)(S)%121 70-130113
2,5-Dibromotoluene (PID)(S)%122 70-130113
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 49 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/8744
SM 3030C
EPA 200.7
200.7 MET 3030C
Associated Lab Samples:9298263005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:634939
Associated Lab Samples:9298263005
Matrix:Water
Analyzed
Lead ug/L <5.0 5.0 07/21/11 16:13
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
634940LABORATORY CONTROL SAMPLE:
LCSSpike
Lead ug/L 510500 102 85-115
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
634941MATRIX SPIKE SAMPLE:
MSSpike
Result
9298263005
Lead ug/L 504500 100 70-130<5.0
Parameter Units
Dup
Result QualifiersRPDResult
9298382001
634942SAMPLE DUPLICATE:
Lead ug/L <5.0ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 50 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/14221
EPA 625
EPA 625
625 MSS
Associated Lab Samples:9298263006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:634387
Associated Lab Samples:9298263006
Matrix:Water
Analyzed
1,2,4-Trichlorobenzene ug/L <5.0 5.0 07/21/11 10:18
2,4,6-Trichlorophenol ug/L <10.0 10.0 07/21/11 10:18
2,4-Dichlorophenol ug/L <5.0 5.0 07/21/11 10:18
2,4-Dimethylphenol ug/L <10.0 10.0 07/21/11 10:18
2,4-Dinitrophenol ug/L <50.0 50.0 07/21/11 10:18
2,4-Dinitrotoluene ug/L <5.0 5.0 07/21/11 10:18
2,6-Dinitrotoluene ug/L <5.0 5.0 07/21/11 10:18
2-Chloronaphthalene ug/L <5.0 5.0 07/21/11 10:18
2-Chlorophenol ug/L <5.0 5.0 07/21/11 10:18
2-Nitrophenol ug/L <5.0 5.0 07/21/11 10:18
3,3'-Dichlorobenzidine ug/L <25.0 25.0 07/21/11 10:18
4,6-Dinitro-2-methylphenol ug/L <20.0 20.0 07/21/11 10:18
4-Bromophenylphenyl ether ug/L <5.0 5.0 07/21/11 10:18
4-Chloro-3-methylphenol ug/L <5.0 5.0 07/21/11 10:18
4-Chlorophenylphenyl ether ug/L <5.0 5.0 07/21/11 10:18
4-Nitrophenol ug/L <50.0 50.0 07/21/11 10:18
Acenaphthene ug/L <5.0 5.0 07/21/11 10:18
Acenaphthylene ug/L <5.0 5.0 07/21/11 10:18
Anthracene ug/L <5.0 5.0 07/21/11 10:18
Benzo(a)anthracene ug/L <5.0 5.0 07/21/11 10:18
Benzo(a)pyrene ug/L <5.0 5.0 07/21/11 10:18
Benzo(b)fluoranthene ug/L <5.0 5.0 07/21/11 10:18
Benzo(g,h,i)perylene ug/L <5.0 5.0 07/21/11 10:18
Benzo(k)fluoranthene ug/L <5.0 5.0 07/21/11 10:18
bis(2-Chloroethoxy)methane ug/L <10.0 10.0 07/21/11 10:18
bis(2-Chloroethyl) ether ug/L <5.0 5.0 07/21/11 10:18
bis(2-Chloroisopropyl) ether ug/L <5.0 5.0 07/21/11 10:18
bis(2-Ethylhexyl)phthalate ug/L <5.0 5.0 07/21/11 10:18
Butylbenzylphthalate ug/L <5.0 5.0 07/21/11 10:18
Chrysene ug/L <5.0 5.0 07/21/11 10:18
Di-n-butylphthalate ug/L <5.0 5.0 07/21/11 10:18
Di-n-octylphthalate ug/L <5.0 5.0 07/21/11 10:18
Dibenz(a,h)anthracene ug/L <5.0 5.0 07/21/11 10:18
Diethylphthalate ug/L <5.0 5.0 07/21/11 10:18
Dimethylphthalate ug/L <5.0 5.0 07/21/11 10:18
Fluoranthene ug/L <5.0 5.0 07/21/11 10:18
Fluorene ug/L <5.0 5.0 07/21/11 10:18
Hexachloro-1,3-butadiene ug/L <5.0 5.0 07/21/11 10:18
Hexachlorobenzene ug/L <5.0 5.0 07/21/11 10:18
Hexachlorocyclopentadiene ug/L <10.0 10.0 07/21/11 10:18
Hexachloroethane ug/L <5.0 5.0 07/21/11 10:18
Indeno(1,2,3-cd)pyrene ug/L <5.0 5.0 07/21/11 10:18
Isophorone ug/L <10.0 10.0 07/21/11 10:18
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 51 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:634387
Associated Lab Samples:9298263006
Matrix:Water
Analyzed
N-Nitroso-di-n-propylamine ug/L <5.0 5.0 07/21/11 10:18
N-Nitrosodimethylamine ug/L <5.0 5.0 07/21/11 10:18
N-Nitrosodiphenylamine ug/L <10.0 10.0 07/21/11 10:18
Naphthalene ug/L <5.0 5.0 07/21/11 10:18
Nitrobenzene ug/L <5.0 5.0 07/21/11 10:18
Pentachlorophenol ug/L <25.0 25.0 07/21/11 10:18
Phenanthrene ug/L <5.0 5.0 07/21/11 10:18
Phenol ug/L <5.0 5.0 07/21/11 10:18
Pyrene ug/L <5.0 5.0 07/21/11 10:18
2,4,6-Tribromophenol (S)%80 10-137 07/21/11 10:18
2-Fluorobiphenyl (S)%65 15-120 07/21/11 10:18
2-Fluorophenol (S)%51 10-120 07/21/11 10:18
Nitrobenzene-d5 (S)%72 10-120 07/21/11 10:18
Phenol-d6 (S)%40 10-120 07/21/11 10:18
Terphenyl-d14 (S)%77 11-131 07/21/11 10:18
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
634388LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 37.650 75 44-142
2,4,6-Trichlorophenol ug/L 49.650 99 37-144
2,4-Dichlorophenol ug/L 47.550 95 1-191
2,4-Dimethylphenol ug/L 34.050 68 32-119
2,4-Dinitrophenol ug/L 252250 101 1-181
2,4-Dinitrotoluene ug/L 48.250 96 39-139
2,6-Dinitrotoluene ug/L 45.850 92 50-158
2-Chloronaphthalene ug/L 43.950 88 60-118
2-Chlorophenol ug/L 48.150 96 23-134
2-Nitrophenol ug/L 44.350 89 29-182
3,3'-Dichlorobenzidine ug/L 90.9100 91 1-262
4,6-Dinitro-2-methylphenol ug/L 105100 105 1-181
4-Bromophenylphenyl ether ug/L 46.250 92 53-127
4-Chloro-3-methylphenol ug/L 97.9100 98 22-147
4-Chlorophenylphenyl ether ug/L 46.450 93 25-158
4-Nitrophenol ug/L 139250 56 1-132
Acenaphthene ug/L 46.750 93 47-145
Acenaphthylene ug/L 45.350 91 33-145
Anthracene ug/L 48.450 97 1-166
Benzo(a)anthracene ug/L 45.750 91 33-143
Benzo(a)pyrene ug/L 39.150 78 17-163
Benzo(b)fluoranthene ug/L 39.250 78 24-159
Benzo(g,h,i)perylene ug/L 40.050 80 1-219
Benzo(k)fluoranthene ug/L 38.950 78 11-162
bis(2-Chloroethoxy)methane ug/L 45.850 92 33-184
bis(2-Chloroethyl) ether ug/L 49.150 98 12-158
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 52 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
634388LABORATORY CONTROL SAMPLE:
LCSSpike
bis(2-Chloroisopropyl) ether ug/L 49.150 98 36-166
bis(2-Ethylhexyl)phthalate ug/L 47.350 95 8-158
Butylbenzylphthalate ug/L 46.550 93 1-152
Chrysene ug/L 44.850 90 17-168
Di-n-butylphthalate ug/L 47.850 96 1-118
Di-n-octylphthalate ug/L 45.850 92 4-146
Dibenz(a,h)anthracene ug/L 41.150 82 1-227
Diethylphthalate ug/L 47.750 95 1-114
Dimethylphthalate ug/L 45.650 91 1-112
Fluoranthene ug/L 48.450 97 26-137
Fluorene ug/L 48.350 97 59-121
Hexachloro-1,3-butadiene ug/L 33.950 68 24-116
Hexachlorobenzene ug/L 44.350 89 1-152
Hexachlorocyclopentadiene ug/L 38.750 77 25-150
Hexachloroethane ug/L 35.850 72 40-113
Indeno(1,2,3-cd)pyrene ug/L 40.250 80 1-171
Isophorone ug/L 47.050 94 21-196
N-Nitroso-di-n-propylamine ug/L 49.750 99 1-230
N-Nitrosodimethylamine ug/L 31.150 62 25-150
N-Nitrosodiphenylamine ug/L 43.750 87 25-150
Naphthalene ug/L 43.850 88 21-133
Nitrobenzene ug/L 44.050 88 35-180
Pentachlorophenol ug/L 70.8100 71 14-176
Phenanthrene ug/L 48.550 97 54-120
Phenol ug/L 28.250 56 5-112
Pyrene ug/L 47.750 95 52-115
2,4,6-Tribromophenol (S)%71 10-137
2-Fluorobiphenyl (S)%91 15-120
2-Fluorophenol (S)%47 10-120
Nitrobenzene-d5 (S)%85 10-120
Phenol-d6 (S)%34 10-120
Terphenyl-d14 (S)%91 11-131
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
634389MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9298209001
634390
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/L 100 68 44-14275 10100ND68.1 75.2
2,4,6-Trichlorophenol ug/L 100 64 37-14486 28100ND64.2 85.5
2,4-Dichlorophenol ug/L 100 80 1-19188 10100ND79.9 88.4
2,4-Dimethylphenol ug/L 100 81 32-11987 7100ND81.4 87.3
2,4-Dinitrophenol ug/L 500 2 1-18157500ND<100 285
2,4-Dinitrotoluene ug/L 100 84 39-13991 9100ND83.6 91.4
2,6-Dinitrotoluene ug/L 100 80 50-15890 11100ND80.3 89.5
2-Chloronaphthalene ug/L 100 71 60-11879 10100ND70.9 78.6
2-Chlorophenol ug/L 100 79 23-13486 9100ND78.7 86.0
2-Nitrophenol ug/L 100 77 29-18285 9100ND77.1 84.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 53 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
634389MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9298209001
634390
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
3,3'-Dichlorobenzidine ug/L 200 88 1-26290 3200ND175180
4,6-Dinitro-2-methylphenol ug/L R1200251-181101 120200ND50.2 201
4-Bromophenylphenyl ether ug/L 100 79 53-12787 9100ND79.5 87.0
4-Chloro-3-methylphenol ug/L 200 85 22-147100 16200ND169199
4-Chlorophenylphenyl ether ug/L 100 83 25-15890 8100ND83.1 90.0
4-Nitrophenol ug/L 500 14 1-13286500ND<100 428
Acenaphthene ug/L 100 83 47-14590 9100ND82.5 90.0
Acenaphthylene ug/L 100 81 33-14588 8100ND80.7 87.8
Anthracene ug/L 100 86 1-16692 7100ND86.5 92.4
Benzo(a)anthracene ug/L 100 83 33-14391 9100ND83.1 90.7
Benzo(a)pyrene ug/L 100 71 17-16379 10100ND70.8 78.5
Benzo(b)fluoranthene ug/L 100 71 24-15980 13100ND70.9 80.5
Benzo(g,h,i)perylene ug/L 100 71 1-21978 9100ND70.9 77.7
Benzo(k)fluoranthene ug/L 100 71 11-16276 6100ND71.2 75.8
bis(2-Chloroethoxy)methane ug/L 100 79 33-18487 9100ND79.4 86.9
bis(2-Chloroethyl) ether ug/L 100 80 12-15885 7100ND79.6 84.9
bis(2-Chloroisopropyl) ether ug/L 100 83 36-16689 7100ND82.8 89.1
bis(2-Ethylhexyl)phthalate ug/L 100 82 8-15891 101001.00J 83.3 92.3
Butylbenzylphthalate ug/L 100 82 1-15290 10100ND81.7 90.0
Chrysene ug/L 100 81 17-16888 7100ND81.3 87.6
Di-n-butylphthalate ug/L 100 83 1-11890 8100ND83.0 90.3
Di-n-octylphthalate ug/L 100 82 4-14690 9100ND82.0 89.8
Dibenz(a,h)anthracene ug/L 100 74 1-22782 11100ND73.7 82.4
Diethylphthalate ug/L 100 87 1-11492 6100ND86.5 91.8
Dimethylphthalate ug/L 100 80 1-11287 9100ND79.6 86.9
Fluoranthene ug/L 100 87 26-13795 9100ND86.8 94.8
Fluorene ug/L 100 86 59-12193 8100ND86.3 93.2
Hexachloro-1,3-butadiene ug/L 100 64 24-11671 11100ND63.9 71.4
Hexachlorobenzene ug/L 100 76 1-15283 9100ND76.3 83.2
Hexachlorocyclopentadiene ug/L 100 69 25-15078 12100ND69.5 78.1
Hexachloroethane ug/L 100 63 40-11371 13100ND62.8 71.3
Indeno(1,2,3-cd)pyrene ug/L 100 73 1-17179 8100ND72.8 79.1
Isophorone ug/L 100 83 21-19692 10100ND83.4 92.2
N-Nitroso-di-n-propylamine ug/L 100 86 1-23089 4100ND85.7 89.0
N-Nitrosodimethylamine ug/L 100 55 25-15071 25100ND55.4 71.4
N-Nitrosodiphenylamine ug/L 100 79 25-15085 8100ND78.7 85.4
Naphthalene ug/L 100 78 21-13385 8100ND77.7 84.5
Nitrobenzene ug/L 100 76 35-18082 8100ND75.8 82.2
Pentachlorophenol ug/L M0,M1,R12001014-17674200ND<50.0 149
Phenanthrene ug/L 100 86 54-12092 7100ND86.0 92.4
Phenol ug/L R1100545-11274 31100ND54.1 74.2
Pyrene ug/L 100 84 52-11587 4100ND84.1 87.2
2,4,6-Tribromophenol (S)%55 10-13768
2-Fluorobiphenyl (S)%74 15-12080
2-Fluorophenol (S)%39 10-12052
Nitrobenzene-d5 (S)%75 10-12080
Phenol-d6 (S)%34 10-12048
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 54 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
634389MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9298209001
634390
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Terphenyl-d14 (S)%82 11-13184
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 55 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/14224
EPA 3546
EPA 8270
8270 Solid MSSV Microwave
Associated Lab Samples:9298263003, 9298263004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:634412
Associated Lab Samples:9298263003, 9298263004
Matrix:Solid
Analyzed
1,2,4-Trichlorobenzene ug/kg <330 330 07/20/11 19:34
1,2-Dichlorobenzene ug/kg <330 330 07/20/11 19:34
1,3-Dichlorobenzene ug/kg <330 330 07/20/11 19:34
1,4-Dichlorobenzene ug/kg <330 330 07/20/11 19:34
1-Methylnaphthalene ug/kg <330 330 07/20/11 19:34
2,4,5-Trichlorophenol ug/kg <330 330 07/20/11 19:34
2,4,6-Trichlorophenol ug/kg <330 330 07/20/11 19:34
2,4-Dichlorophenol ug/kg <330 330 07/20/11 19:34
2,4-Dimethylphenol ug/kg <330 330 07/20/11 19:34
2,4-Dinitrophenol ug/kg <1650 1650 07/20/11 19:34
2,4-Dinitrotoluene ug/kg <330 330 07/20/11 19:34
2,6-Dinitrotoluene ug/kg <330 330 07/20/11 19:34
2-Chloronaphthalene ug/kg <330 330 07/20/11 19:34
2-Chlorophenol ug/kg <330 330 07/20/11 19:34
2-Methylnaphthalene ug/kg <330 330 07/20/11 19:34
2-Methylphenol(o-Cresol)ug/kg <330 330 07/20/11 19:34
2-Nitroaniline ug/kg <1650 1650 07/20/11 19:34
2-Nitrophenol ug/kg <330 330 07/20/11 19:34
3&4-Methylphenol(m&p Cresol)ug/kg <330 330 07/20/11 19:34
3,3'-Dichlorobenzidine ug/kg <1650 1650 07/20/11 19:34
3-Nitroaniline ug/kg <1650 1650 07/20/11 19:34
4,6-Dinitro-2-methylphenol ug/kg <660 660 07/20/11 19:34
4-Bromophenylphenyl ether ug/kg <330 330 07/20/11 19:34
4-Chloro-3-methylphenol ug/kg <660 660 07/20/11 19:34
4-Chloroaniline ug/kg <1650 1650 07/20/11 19:34
4-Chlorophenylphenyl ether ug/kg <330 330 07/20/11 19:34
4-Nitroaniline ug/kg <660 660 07/20/11 19:34
4-Nitrophenol ug/kg <1650 1650 07/20/11 19:34
Acenaphthene ug/kg <330 330 07/20/11 19:34
Acenaphthylene ug/kg <330 330 07/20/11 19:34
Aniline ug/kg <330 330 07/20/11 19:34
Anthracene ug/kg <330 330 07/20/11 19:34
Benzo(a)anthracene ug/kg <330 330 07/20/11 19:34
Benzo(a)pyrene ug/kg <330 330 07/20/11 19:34
Benzo(b)fluoranthene ug/kg <330 330 07/20/11 19:34
Benzo(g,h,i)perylene ug/kg <330 330 07/20/11 19:34
Benzo(k)fluoranthene ug/kg <330 330 07/20/11 19:34
Benzoic Acid ug/kg <1650 1650 07/20/11 19:34
Benzyl alcohol ug/kg <660 660 07/20/11 19:34
bis(2-Chloroethoxy)methane ug/kg <330 330 07/20/11 19:34
bis(2-Chloroethyl) ether ug/kg <330 330 07/20/11 19:34
bis(2-Chloroisopropyl) ether ug/kg <330 330 07/20/11 19:34
bis(2-Ethylhexyl)phthalate ug/kg <330 330 07/20/11 19:34
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 56 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:634412
Associated Lab Samples:9298263003, 9298263004
Matrix:Solid
Analyzed
Butylbenzylphthalate ug/kg <330 330 07/20/11 19:34
Chrysene ug/kg <330 330 07/20/11 19:34
Di-n-butylphthalate ug/kg <330 330 07/20/11 19:34
Di-n-octylphthalate ug/kg <330 330 07/20/11 19:34
Dibenz(a,h)anthracene ug/kg <330 330 07/20/11 19:34
Dibenzofuran ug/kg <330 330 07/20/11 19:34
Diethylphthalate ug/kg <330 330 07/20/11 19:34
Dimethylphthalate ug/kg <330 330 07/20/11 19:34
Fluoranthene ug/kg <330 330 07/20/11 19:34
Fluorene ug/kg <330 330 07/20/11 19:34
Hexachloro-1,3-butadiene ug/kg <330 330 07/20/11 19:34
Hexachlorobenzene ug/kg <330 330 07/20/11 19:34
Hexachlorocyclopentadiene ug/kg <330 330 07/20/11 19:34
Hexachloroethane ug/kg <330 330 07/20/11 19:34
Indeno(1,2,3-cd)pyrene ug/kg <330 330 07/20/11 19:34
Isophorone ug/kg <330 330 07/20/11 19:34
N-Nitroso-di-n-propylamine ug/kg <330 330 07/20/11 19:34
N-Nitrosodimethylamine ug/kg <330 330 07/20/11 19:34
N-Nitrosodiphenylamine ug/kg <330 330 07/20/11 19:34
Naphthalene ug/kg <330 330 07/20/11 19:34
Nitrobenzene ug/kg <330 330 07/20/11 19:34
Pentachlorophenol ug/kg <1650 1650 07/20/11 19:34
Phenanthrene ug/kg <330 330 07/20/11 19:34
Phenol ug/kg <330 330 07/20/11 19:34
Pyrene ug/kg <330 330 07/20/11 19:34
2,4,6-Tribromophenol (S)%66 27-110 07/20/11 19:34
2-Fluorobiphenyl (S)%67 30-110 07/20/11 19:34
2-Fluorophenol (S)%68 13-110 07/20/11 19:34
Nitrobenzene-d5 (S)%70 23-110 07/20/11 19:34
Phenol-d6 (S)%75 22-110 07/20/11 19:34
Terphenyl-d14 (S)%73 28-110 07/20/11 19:34
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
634413LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/kg 10301670 62 39-101
1,2-Dichlorobenzene ug/kg 12201670 73 36-110
1,3-Dichlorobenzene ug/kg 12101670 73 35-110
1,4-Dichlorobenzene ug/kg 12301670 74 35-110
1-Methylnaphthalene ug/kg 11101670 66 45-105
2,4,5-Trichlorophenol ug/kg 12701670 76 48-109
2,4,6-Trichlorophenol ug/kg 12801670 77 45-111
2,4-Dichlorophenol ug/kg 11501670 69 51-116
2,4-Dimethylphenol ug/kg 11201670 67 42-103
2,4-Dinitrophenol ug/kg 69008330 83 28-103
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 57 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
634413LABORATORY CONTROL SAMPLE:
LCSSpike
2,4-Dinitrotoluene ug/kg 12901670 77 46-114
2,6-Dinitrotoluene ug/kg 13001670 78 48-112
2-Chloronaphthalene ug/kg 13201670 79 44-105
2-Chlorophenol ug/kg 13401670 80 36-110
2-Methylnaphthalene ug/kg 11101670 67 39-112
2-Methylphenol(o-Cresol)ug/kg 14001670 84 39-101
2-Nitroaniline ug/kg 27803330 83 44-111
2-Nitrophenol ug/kg 11201670 67 41-100
3&4-Methylphenol(m&p Cresol)ug/kg 13601670 82 43-103
3,3'-Dichlorobenzidine ug/kg 27003330 81 10-150
3-Nitroaniline ug/kg 26103330 78 35-110
4,6-Dinitro-2-methylphenol ug/kg 28303330 85 38-118
4-Bromophenylphenyl ether ug/kg 12801670 77 47-115
4-Chloro-3-methylphenol ug/kg 23803330 71 43-127
4-Chloroaniline ug/kg 22303330 67 34-109
4-Chlorophenylphenyl ether ug/kg 12801670 77 44-115
4-Nitroaniline ug/kg 25803330 78 37-111
4-Nitrophenol ug/kg 77208330 93 21-152
Acenaphthene ug/kg 13001670 78 38-117
Acenaphthylene ug/kg 13101670 78 46-107
Aniline ug/kg 12701670 76 29-110
Anthracene ug/kg 13501670 81 50-110
Benzo(a)anthracene ug/kg 13901670 83 47-116
Benzo(a)pyrene ug/kg 13501670 81 47-106
Benzo(b)fluoranthene ug/kg 15101670 90 47-109
Benzo(g,h,i)perylene ug/kg 14501670 87 39-115
Benzo(k)fluoranthene ug/kg 13901670 83 45-117
Benzoic Acid ug/kg 47508330 57 16-110
Benzyl alcohol ug/kg 29303330 88 38-105
bis(2-Chloroethoxy)methane ug/kg 14501670 87 39-110
bis(2-Chloroethyl) ether ug/kg 13501670 81 19-119
bis(2-Chloroisopropyl) ether ug/kg 13601670 81 21-110
bis(2-Ethylhexyl)phthalate ug/kg 13201670 79 35-116
Butylbenzylphthalate ug/kg 13401670 80 38-110
Chrysene ug/kg 13401670 81 49-110
Di-n-butylphthalate ug/kg 12701670 76 43-109
Di-n-octylphthalate ug/kg 12501670 75 37-109
Dibenz(a,h)anthracene ug/kg 14801670 89 43-116
Dibenzofuran ug/kg 13201670 79 45-106
Diethylphthalate ug/kg 12201670 73 41-114
Dimethylphthalate ug/kg 12201670 73 43-110
Fluoranthene ug/kg 13401670 80 50-114
Fluorene ug/kg 13101670 79 46-114
Hexachloro-1,3-butadiene ug/kg 10201670 61 28-111
Hexachlorobenzene ug/kg 12701670 76 46-120
Hexachlorocyclopentadiene ug/kg 12901670 78 18-119
Hexachloroethane ug/kg 13401670 80 33-110
Indeno(1,2,3-cd)pyrene ug/kg 14201670 85 42-115
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 58 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
634413LABORATORY CONTROL SAMPLE:
LCSSpike
Isophorone ug/kg 11201670 67 44-109
N-Nitroso-di-n-propylamine ug/kg 13001670 78 43-104
N-Nitrosodimethylamine ug/kg 12901670 77 29-110
N-Nitrosodiphenylamine ug/kg 12701670 76 48-113
Naphthalene ug/kg 11001670 66 41-110
Nitrobenzene ug/kg 10501670 63 38-110
Pentachlorophenol ug/kg 27203330 81 32-128
Phenanthrene ug/kg 13501670 81 50-110
Phenol ug/kg 15401670 93 28-106
Pyrene ug/kg 13101670 79 45-114
2,4,6-Tribromophenol (S)%58 27-110
2-Fluorobiphenyl (S)%74 30-110
2-Fluorophenol (S)%59 13-110
Nitrobenzene-d5 (S)%64 23-110
Phenol-d6 (S)%63 22-110
Terphenyl-d14 (S)%74 28-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
634414MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9298272008
634415
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/kg 1950 54 18-11960 111950ND10601180
1,2-Dichlorobenzene ug/kg 1950 62 50-11067 71950ND12101300
1,3-Dichlorobenzene ug/kg 1950 61 27-11067 101950ND11801300
1,4-Dichlorobenzene ug/kg 1950 62 28-11067 81950ND12101300
1-Methylnaphthalene ug/kg 1950 60 24-11665 81950ND11701260
2,4,5-Trichlorophenol ug/kg 1950 68 28-11077 121950ND13401510
2,4,6-Trichlorophenol ug/kg 1950 67 17-11775 121950ND13001460
2,4-Dichlorophenol ug/kg 1950 62 21-12866 61950ND12101280
2,4-Dimethylphenol ug/kg 1950 38 10-12035 81950ND737678
2,4-Dinitrophenol ug/kg 9750 71 10-10782 149750ND69207950
2,4-Dinitrotoluene ug/kg 1950 68 36-10975 111950ND13201470
2,6-Dinitrotoluene ug/kg 1950 68 32-11076 101950ND13301480
2-Chloronaphthalene ug/kg 1950 71 30-10784 161950ND13901640
2-Chlorophenol ug/kg 1950 69 14-10674 71950ND13401440
2-Methylnaphthalene ug/kg 1950 60 10-13564 71950ND11701250
2-Methylphenol(o-Cresol)ug/kg 1950 65 10-12461 51950ND12601200
2-Nitroaniline ug/kg 3900 74 26-11684 133900ND28903280
2-Nitrophenol ug/kg 1950 59 28-10365 91950ND11601270
3&4-Methylphenol(m&p
Cresol)ug/kg 1950 67 10-10965 31950ND13101260
3,3'-Dichlorobenzidine ug/kg 3900 38 10-150343900ND<1930 <1930
3-Nitroaniline ug/kg 3900 64 22-11071 103900ND24902760
4,6-Dinitro-2-methylphenol ug/kg 3900 74 13-12186 153900ND28703340
4-Bromophenylphenyl ether ug/kg 1950 68 31-10975 91950ND13301460
4-Chloro-3-methylphenol ug/kg 3900 61 13-12863 33900ND23802470
4-Chloroaniline ug/kg 3900 49 18-102503900ND<1930 1960
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 59 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
634414MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9298272008
634415
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
4-Chlorophenylphenyl ether ug/kg 1950 68 29-11278 131950ND13301510
4-Nitroaniline ug/kg 3900 65 16-11176 153900ND25502960
4-Nitrophenol ug/kg 9750 69 14-13584 199750ND67608150
Acenaphthene ug/kg 1950 70 26-11480 141950ND13701570
Acenaphthylene ug/kg 1950 71 32-10880 121950ND13801560
Aniline ug/kg 1950 25 10-107181950ND486<386
Anthracene ug/kg 1950 70 32-11180 131950ND13701560
Benzo(a)anthracene ug/kg 1950 65 25-11773 121950ND12601420
Benzo(a)pyrene ug/kg 1950 63 25-10670 101950ND12301360
Benzo(b)fluoranthene ug/kg 1950 66 24-11071 71950ND12901390
Benzo(g,h,i)perylene ug/kg 1950 69 19-11277 111950ND13401510
Benzo(k)fluoranthene ug/kg 1950 60 24-11468 131950ND11601330
Benzoic Acid ug/kg 9750 49 10-11047 49750ND47904620
Benzyl alcohol ug/kg 3900 76 24-10679 53900ND29503090
bis(2-Chloroethoxy)methane ug/kg 1950 76 13-11985 121950ND14801660
bis(2-Chloroethyl) ether ug/kg 1950 68 10-13472 51950ND13301400
bis(2-Chloroisopropyl) ether ug/kg 1950 70 10-11374 61950ND13601430
bis(2-Ethylhexyl)phthalate ug/kg 1950 66 10-12577 141950ND13001500
Butylbenzylphthalate ug/kg 1950 66 18-11085 251950ND12801660
Chrysene ug/kg 1950 66 30-11074 121950ND12901450
Di-n-butylphthalate ug/kg 1950 66 19-11274 111950ND12801440
Di-n-octylphthalate ug/kg 1950 64 17-10573 121950ND12601420
Dibenz(a,h)anthracene ug/kg 1950 68 23-11178 141950ND13201520
Dibenzofuran ug/kg 1950 70 35-10380 131950ND13701550
Diethylphthalate ug/kg 1950 66 27-11374 121950ND12801450
Dimethylphthalate ug/kg 1950 65 26-11172 111950ND12601410
Fluoranthene ug/kg 1950 64 33-10975 161950ND12401460
Fluorene ug/kg 1950 70 32-11380 141950ND13601560
Hexachloro-1,3-butadiene ug/kg 1950 52 16-11658 111950ND10101130
Hexachlorobenzene ug/kg 1950 66 27-12069 51950ND12801350
Hexachlorocyclopentadiene ug/kg 1950 67 10-10883 221950ND13001620
Hexachloroethane ug/kg 1950 69 10-11776 91950ND13501480
Indeno(1,2,3-cd)pyrene ug/kg 1950 68 10-12276 111950ND13301490
Isophorone ug/kg 1950 61 28-11468 101950ND11901320
N-Nitroso-di-n-propylamine ug/kg 1950 72 27-11374 31950ND14001440
N-Nitrosodimethylamine ug/kg 1950 58 10-10963 81950ND11301230
N-Nitrosodiphenylamine ug/kg 1950 66 10-12870 61950ND12901370
Naphthalene ug/kg 1950 58 25-11064 101950ND11301250
Nitrobenzene ug/kg 1950 55 18-11461 91950ND10801180
Pentachlorophenol ug/kg 3900 61 10-12273 173900ND23802830
Phenanthrene ug/kg 1950 70 30-11479 111950ND13701540
Phenol ug/kg 1950 75 11-10276 11950ND14701480
Pyrene ug/kg 1950 73 25-11690 211950ND14201760
2,4,6-Tribromophenol (S)%49 27-11053
2-Fluorobiphenyl (S)%64 30-11076
2-Fluorophenol (S)%47 13-11050
Nitrobenzene-d5 (S)%54 23-11062
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 60 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
634414MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9298272008
634415
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Phenol-d6 (S)%51 22-11053
Terphenyl-d14 (S)%69 28-11084
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 61 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/16054
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:9298263005, 9298263006, 9298263007, 9298263008, 9298263009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:635833
Associated Lab Samples:9298263005, 9298263006, 9298263007, 9298263008, 9298263009
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L <0.50 0.50 07/19/11 23:39
1,1,1-Trichloroethane ug/L <0.50 0.50 07/19/11 23:39
1,1,2,2-Tetrachloroethane ug/L <0.50 0.50 07/19/11 23:39
1,1,2-Trichloroethane ug/L <0.50 0.50 07/19/11 23:39
1,1-Dichloroethane ug/L <0.50 0.50 07/19/11 23:39
1,1-Dichloroethene ug/L <0.50 0.50 07/19/11 23:39
1,1-Dichloropropene ug/L <0.50 0.50 07/19/11 23:39
1,2,3-Trichlorobenzene ug/L <2.0 2.0 07/19/11 23:39
1,2,3-Trichloropropane ug/L <0.50 0.50 07/19/11 23:39
1,2,4-Trichlorobenzene ug/L <2.0 2.0 07/19/11 23:39
1,2,4-Trimethylbenzene ug/L <0.50 0.50 07/19/11 23:39
1,2-Dibromo-3-chloropropane ug/L <1.0 1.0 07/19/11 23:39
1,2-Dibromoethane (EDB)ug/L <0.50 0.50 07/19/11 23:39
1,2-Dichlorobenzene ug/L <0.50 0.50 07/19/11 23:39
1,2-Dichloroethane ug/L <0.50 0.50 07/19/11 23:39
1,2-Dichloropropane ug/L <0.50 0.50 07/19/11 23:39
1,3,5-Trimethylbenzene ug/L <0.50 0.50 07/19/11 23:39
1,3-Dichlorobenzene ug/L <0.50 0.50 07/19/11 23:39
1,3-Dichloropropane ug/L <0.50 0.50 07/19/11 23:39
1,4-Dichlorobenzene ug/L <0.50 0.50 07/19/11 23:39
2,2-Dichloropropane ug/L <0.50 0.50 07/19/11 23:39
2-Chlorotoluene ug/L <0.50 0.50 07/19/11 23:39
4-Chlorotoluene ug/L <0.50 0.50 07/19/11 23:39
Benzene ug/L <0.50 0.50 07/19/11 23:39
Bromobenzene ug/L <0.50 0.50 07/19/11 23:39
Bromochloromethane ug/L <0.50 0.50 07/19/11 23:39
Bromodichloromethane ug/L <0.50 0.50 07/19/11 23:39
Bromoform ug/L <0.50 0.50 07/19/11 23:39
Bromomethane ug/L <5.0 5.0 07/19/11 23:39
Carbon tetrachloride ug/L <0.50 0.50 07/19/11 23:39
Chlorobenzene ug/L <0.50 0.50 07/19/11 23:39
Chloroethane ug/L <1.0 1.0 07/19/11 23:39
Chloroform ug/L <0.50 0.50 07/19/11 23:39
Chloromethane ug/L <1.0 1.0 07/19/11 23:39
cis-1,2-Dichloroethene ug/L <0.50 0.50 07/19/11 23:39
cis-1,3-Dichloropropene ug/L <0.50 0.50 07/19/11 23:39
Dibromochloromethane ug/L <0.50 0.50 07/19/11 23:39
Dibromomethane ug/L <0.50 0.50 07/19/11 23:39
Dichlorodifluoromethane ug/L <0.50 0.50 07/19/11 23:39
Diisopropyl ether ug/L <0.50 0.50 07/19/11 23:39
Ethylbenzene ug/L <0.50 0.50 07/19/11 23:39
Hexachloro-1,3-butadiene ug/L <2.0 2.0 07/19/11 23:39
Isopropylbenzene (Cumene)ug/L <0.50 0.50 07/19/11 23:39
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 62 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:635833
Associated Lab Samples:9298263005, 9298263006, 9298263007, 9298263008, 9298263009
Matrix:Water
Analyzed
m&p-Xylene ug/L <1.0 1.0 07/19/11 23:39
Methyl-tert-butyl ether ug/L <0.50 0.50 07/19/11 23:39
Methylene Chloride ug/L ND 3.0 07/19/11 23:39
n-Butylbenzene ug/L <0.50 0.50 07/19/11 23:39
n-Propylbenzene ug/L <0.50 0.50 07/19/11 23:39
Naphthalene ug/L <2.0 2.0 07/19/11 23:39
o-Xylene ug/L <0.50 0.50 07/19/11 23:39
sec-Butylbenzene ug/L <0.50 0.50 07/19/11 23:39
Styrene ug/L <0.50 0.50 07/19/11 23:39
tert-Butylbenzene ug/L <0.50 0.50 07/19/11 23:39
Tetrachloroethene ug/L <0.50 0.50 07/19/11 23:39
Toluene ug/L <0.50 0.50 07/19/11 23:39
trans-1,2-Dichloroethene ug/L <0.50 0.50 07/19/11 23:39
trans-1,3-Dichloropropene ug/L <0.50 0.50 07/19/11 23:39
Trichloroethene ug/L <0.50 0.50 07/19/11 23:39
Trichlorofluoromethane ug/L <1.0 1.0 07/19/11 23:39
Vinyl chloride ug/L <1.0 1.0 07/19/11 23:39
1,2-Dichloroethane-d4 (S)%114 70-130 07/19/11 23:39
4-Bromofluorobenzene (S)%92 70-130 07/19/11 23:39
Dibromofluoromethane (S)%106 70-130 07/19/11 23:39
Toluene-d8 (S)%96 70-130 07/19/11 23:39
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
635834LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 55.950 112 60-140
1,1,1-Trichloroethane ug/L 50.150 100 60-140
1,1,2,2-Tetrachloroethane ug/L 49.850 100 60-140
1,1,2-Trichloroethane ug/L 48.650 97 60-140
1,1-Dichloroethane ug/L 49.550 99 60-140
1,1-Dichloroethene ug/L 48.750 97 60-140
1,1-Dichloropropene ug/L 46.650 93 60-140
1,2,3-Trichlorobenzene ug/L 57.550 115 60-140
1,2,3-Trichloropropane ug/L 46.950 94 60-140
1,2,4-Trichlorobenzene ug/L 57.950 116 60-140
1,2,4-Trimethylbenzene ug/L 55.350 111 60-140
1,2-Dibromo-3-chloropropane ug/L 58.350 117 60-140
1,2-Dibromoethane (EDB)ug/L 47.750 95 60-140
1,2-Dichlorobenzene ug/L 52.750 105 60-140
1,2-Dichloroethane ug/L 49.050 98 60-140
1,2-Dichloropropane ug/L 46.650 93 60-140
1,3,5-Trimethylbenzene ug/L 55.550 111 60-140
1,3-Dichlorobenzene ug/L 51.950 104 60-140
1,3-Dichloropropane ug/L 48.050 96 60-140
1,4-Dichlorobenzene ug/L 50.250 100 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 63 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
635834LABORATORY CONTROL SAMPLE:
LCSSpike
2,2-Dichloropropane ug/L 47.550 95 60-140
2-Chlorotoluene ug/L 53.750 107 60-140
4-Chlorotoluene ug/L 54.750 109 60-140
Benzene ug/L 45.450 91 60-140
Bromobenzene ug/L 50.650 101 60-140
Bromochloromethane ug/L 47.150 94 60-140
Bromodichloromethane ug/L 51.150 102 60-140
Bromoform ug/L 48.550 97 60-140
Bromomethane ug/L 52.450 105 60-140
Carbon tetrachloride ug/L 52.550 105 60-140
Chlorobenzene ug/L 47.850 96 60-140
Chloroethane ug/L 50.050 100 60-140
Chloroform ug/L 49.150 98 60-140
Chloromethane ug/L 43.750 87 60-140
cis-1,2-Dichloroethene ug/L 48.750 97 60-140
cis-1,3-Dichloropropene ug/L 52.550 105 60-140
Dibromochloromethane ug/L 54.950 110 60-140
Dibromomethane ug/L 45.250 90 60-140
Dichlorodifluoromethane ug/L 38.750 77 60-140
Diisopropyl ether ug/L 51.050 102 60-140
Ethylbenzene ug/L 47.950 96 60-140
Hexachloro-1,3-butadiene ug/L 54.350 109 60-140
Isopropylbenzene (Cumene)ug/L 54.550 109 60-140
m&p-Xylene ug/L 100100 100 60-140
Methyl-tert-butyl ether ug/L 49.850 100 60-140
Methylene Chloride ug/L 50.950 102 60-140
n-Butylbenzene ug/L 58.450 117 60-140
n-Propylbenzene ug/L 54.250 108 60-140
Naphthalene ug/L 50.950 102 60-140
o-Xylene ug/L 50.750 101 60-140
sec-Butylbenzene ug/L 57.750 115 60-140
Styrene ug/L 54.750 109 60-140
tert-Butylbenzene ug/L 57.850 116 60-140
Tetrachloroethene ug/L 46.950 94 60-140
Toluene ug/L 45.450 91 60-140
trans-1,2-Dichloroethene ug/L 48.150 96 60-140
trans-1,3-Dichloropropene ug/L 53.350 107 60-140
Trichloroethene ug/L 47.350 95 60-140
Trichlorofluoromethane ug/L 46.050 92 60-140
Vinyl chloride ug/L 47.050 94 60-140
1,2-Dichloroethane-d4 (S)%105 70-130
4-Bromofluorobenzene (S)%97 70-130
Dibromofluoromethane (S)%104 70-130
Toluene-d8 (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 64 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
635835MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9298285020
635836
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 123 60-140115 720ND24.6 23.0
1,1,1-Trichloroethane ug/L 20 120 60-140113 620ND24.0 22.7
1,1,2,2-Tetrachloroethane ug/L 20 106 60-14097 820ND21.2 19.4
1,1,2-Trichloroethane ug/L 20 106 60-14098 920ND21.3 19.5
1,1-Dichloroethane ug/L 20 122 60-140115 620ND24.4 23.1
1,1-Dichloroethene ug/L 20 124 60-140114 820ND24.7 22.8
1,1-Dichloropropene ug/L 20 111 60-140103 720ND22.2 20.7
1,2,3-Trichlorobenzene ug/L 20 101 60-14096 520ND20.2 19.2
1,2,3-Trichloropropane ug/L 20 107 60-14092 1520ND21.3 18.4
1,2,4-Trichlorobenzene ug/L 20 99 60-14092 720ND19.8 18.4
1,2,4-Trimethylbenzene ug/L 20 122 60-140110 1120ND24.6 22.1
1,2-Dibromo-3-chloropropane ug/L 20 109 60-140104 520ND21.8 20.8
1,2-Dibromoethane (EDB)ug/L 20 105 60-14097 720ND20.9 19.5
1,2-Dichlorobenzene ug/L 20 110 60-140103 620ND22.1 20.7
1,2-Dichloroethane ug/L 20 115 60-140108 620ND23.0 21.6
1,2-Dichloropropane ug/L 20 108 60-140100 720ND21.5 20.1
1,3,5-Trimethylbenzene ug/L 20 122 60-140114 720ND24.4 22.7
1,3-Dichlorobenzene ug/L 20 112 60-140105 720ND22.4 20.9
1,3-Dichloropropane ug/L 20 105 60-14099 520ND20.9 19.9
1,4-Dichlorobenzene ug/L 20 109 60-140102 720ND21.9 20.5
2,2-Dichloropropane ug/L 20 99 60-14092 720ND19.8 18.4
2-Chlorotoluene ug/L 20 118 60-140112 520ND23.6 22.4
4-Chlorotoluene ug/L 20 120 60-140113 620ND24.1 22.6
Benzene ug/L 20 108 60-140100 820ND21.6 19.9
Bromobenzene ug/L 20 113 60-140106 720ND22.6 21.1
Bromochloromethane ug/L 20 107 60-140102 520ND21.4 20.4
Bromodichloromethane ug/L 20 112 60-140103 820ND22.3 20.6
Bromoform ug/L 20 109 60-140104 520ND21.9 20.8
Bromomethane ug/L M02014760-140165 1220ND29.3 32.9
Carbon tetrachloride ug/L 20 123 60-140115 720ND24.7 22.9
Chlorobenzene ug/L 20 109 60-140103 620ND21.8 20.6
Chloroethane ug/L 20 134 60-140123 820ND26.8 24.7
Chloroform ug/L 20 119 60-140112 720ND23.9 22.3
Chloromethane ug/L 20 113 60-140108 420ND22.6 21.6
cis-1,2-Dichloroethene ug/L 20 117 60-140111 620ND23.4 22.1
cis-1,3-Dichloropropene ug/L 20 100 60-14093 820ND20.0 18.5
Dibromochloromethane ug/L 20 114 60-140107 620ND22.8 21.5
Dibromomethane ug/L 20 104 60-14094 1020ND20.8 18.9
Dichlorodifluoromethane ug/L 20 114 60-140105 920ND22.8 20.9
Diisopropyl ether ug/L M02024760-140236 520ND49.5 47.2
Ethylbenzene ug/L 20 109 60-140102 720ND21.7 20.3
Hexachloro-1,3-butadiene ug/L 20 103 60-140101 220ND20.6 20.3
Isopropylbenzene (Cumene)ug/L 20 119 60-140110 820ND23.9 22.1
m&p-Xylene ug/L 40 112 60-140106 640ND44.8 42.2
Methyl-tert-butyl ether ug/L M02027260-140257 620ND54.5 51.5
Methylene Chloride ug/L 20 118 60-140112 620ND23.7 22.4
n-Butylbenzene ug/L 20 119 60-140108 920ND23.8 21.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 65 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
635835MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9298285020
635836
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Propylbenzene ug/L 20 121 60-140113 620ND24.2 22.7
Naphthalene ug/L 20 93 60-14086 920ND18.7 17.1
o-Xylene ug/L 20 109 60-140101 820ND21.8 20.2
sec-Butylbenzene ug/L 20 127 60-140119 720ND25.4 23.7
Styrene ug/L 20 113 60-140110 320ND22.7 21.9
tert-Butylbenzene ug/L 20 125 60-140116 820ND25.0 23.1
Tetrachloroethene ug/L 20 108 60-140100 820ND21.6 20.0
Toluene ug/L 20 104 60-14095 920ND20.7 19.0
trans-1,2-Dichloroethene ug/L 20 120 60-140112 720ND24.0 22.4
trans-1,3-Dichloropropene ug/L 20 106 60-14094 1220ND21.2 18.7
Trichloroethene ug/L 20 108 60-140101 720ND21.6 20.1
Trichlorofluoromethane ug/L 20 120 60-140112 620ND23.9 22.5
Vinyl chloride ug/L 20 123 60-140115 620ND24.5 23.0
1,2-Dichloroethane-d4 (S)%114 70-130110
4-Bromofluorobenzene (S)%97 70-13097
Dibromofluoromethane (S)%107 70-130106
Toluene-d8 (S)%98 70-13098
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 66 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/16028
EPA 8260
EPA 8260
8260 MSV 5035A Volatile Organics
Associated Lab Samples:9298263002, 9298263003, 9298263004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:635167
Associated Lab Samples:9298263002, 9298263003, 9298263004
Matrix:Solid
Analyzed
1,1,1,2-Tetrachloroethane ug/kg <5.0 5.0 07/18/11 11:43
1,1,1-Trichloroethane ug/kg <5.0 5.0 07/18/11 11:43
1,1,2,2-Tetrachloroethane ug/kg <5.0 5.0 07/18/11 11:43
1,1,2-Trichloroethane ug/kg <5.0 5.0 07/18/11 11:43
1,1-Dichloroethane ug/kg <5.0 5.0 07/18/11 11:43
1,1-Dichloroethene ug/kg <5.0 5.0 07/18/11 11:43
1,1-Dichloropropene ug/kg <5.0 5.0 07/18/11 11:43
1,2,3-Trichlorobenzene ug/kg <5.0 5.0 07/18/11 11:43
1,2,3-Trichloropropane ug/kg <5.0 5.0 07/18/11 11:43
1,2,4-Trichlorobenzene ug/kg <5.0 5.0 07/18/11 11:43
1,2,4-Trimethylbenzene ug/kg <5.0 5.0 07/18/11 11:43
1,2-Dibromo-3-chloropropane ug/kg <5.0 5.0 07/18/11 11:43
1,2-Dibromoethane (EDB)ug/kg <5.0 5.0 07/18/11 11:43
1,2-Dichlorobenzene ug/kg <5.0 5.0 07/18/11 11:43
1,2-Dichloroethane ug/kg <5.0 5.0 07/18/11 11:43
1,2-Dichloropropane ug/kg <5.0 5.0 07/18/11 11:43
1,3,5-Trimethylbenzene ug/kg <5.0 5.0 07/18/11 11:43
1,3-Dichlorobenzene ug/kg <5.0 5.0 07/18/11 11:43
1,3-Dichloropropane ug/kg <5.0 5.0 07/18/11 11:43
1,4-Dichlorobenzene ug/kg <5.0 5.0 07/18/11 11:43
2,2-Dichloropropane ug/kg <5.0 5.0 07/18/11 11:43
2-Butanone (MEK)ug/kg <100 100 07/18/11 11:43
2-Chlorotoluene ug/kg <5.0 5.0 07/18/11 11:43
2-Hexanone ug/kg <50.0 50.0 07/18/11 11:43
4-Chlorotoluene ug/kg <5.0 5.0 07/18/11 11:43
4-Methyl-2-pentanone (MIBK)ug/kg <50.0 50.0 07/18/11 11:43
Acetone ug/kg <100 100 07/18/11 11:43
Benzene ug/kg <5.0 5.0 07/18/11 11:43
Bromobenzene ug/kg <5.0 5.0 07/18/11 11:43
Bromochloromethane ug/kg <5.0 5.0 07/18/11 11:43
Bromodichloromethane ug/kg <5.0 5.0 07/18/11 11:43
Bromoform ug/kg <5.0 5.0 07/18/11 11:43
Bromomethane ug/kg <10.0 10.0 07/18/11 11:43
Carbon tetrachloride ug/kg <5.0 5.0 07/18/11 11:43
Chlorobenzene ug/kg <5.0 5.0 07/18/11 11:43
Chloroethane ug/kg <10.0 10.0 07/18/11 11:43
Chloroform ug/kg <5.0 5.0 07/18/11 11:43
Chloromethane ug/kg <10.0 10.0 07/18/11 11:43
cis-1,2-Dichloroethene ug/kg <5.0 5.0 07/18/11 11:43
cis-1,3-Dichloropropene ug/kg <5.0 5.0 07/18/11 11:43
Dibromochloromethane ug/kg <5.0 5.0 07/18/11 11:43
Dibromomethane ug/kg <5.0 5.0 07/18/11 11:43
Dichlorodifluoromethane ug/kg <10.0 10.0 07/18/11 11:43
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 67 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:635167
Associated Lab Samples:9298263002, 9298263003, 9298263004
Matrix:Solid
Analyzed
Diisopropyl ether ug/kg <5.0 5.0 07/18/11 11:43
Ethylbenzene ug/kg <5.0 5.0 07/18/11 11:43
Hexachloro-1,3-butadiene ug/kg <5.0 5.0 07/18/11 11:43
Isopropylbenzene (Cumene)ug/kg <5.0 5.0 07/18/11 11:43
m&p-Xylene ug/kg <10.0 10.0 07/18/11 11:43
Methyl-tert-butyl ether ug/kg <5.0 5.0 07/18/11 11:43
Methylene Chloride ug/kg <20.0 20.0 07/18/11 11:43
n-Butylbenzene ug/kg <5.0 5.0 07/18/11 11:43
n-Propylbenzene ug/kg <5.0 5.0 07/18/11 11:43
Naphthalene ug/kg <5.0 5.0 07/18/11 11:43
o-Xylene ug/kg <5.0 5.0 07/18/11 11:43
p-Isopropyltoluene ug/kg <5.0 5.0 07/18/11 11:43
sec-Butylbenzene ug/kg <5.0 5.0 07/18/11 11:43
Styrene ug/kg <5.0 5.0 07/18/11 11:43
tert-Butylbenzene ug/kg <5.0 5.0 07/18/11 11:43
Tetrachloroethene ug/kg <5.0 5.0 07/18/11 11:43
Toluene ug/kg <5.0 5.0 07/18/11 11:43
trans-1,2-Dichloroethene ug/kg <5.0 5.0 07/18/11 11:43
trans-1,3-Dichloropropene ug/kg <5.0 5.0 07/18/11 11:43
Trichloroethene ug/kg <5.0 5.0 07/18/11 11:43
Trichlorofluoromethane ug/kg <5.0 5.0 07/18/11 11:43
Vinyl acetate ug/kg <50.0 50.0 07/18/11 11:43
Vinyl chloride ug/kg <10.0 10.0 07/18/11 11:43
Xylene (Total)ug/kg <10.0 10.0 07/18/11 11:43
1,2-Dichloroethane-d4 (S)%103 70-132 07/18/11 11:43
4-Bromofluorobenzene (S)%93 70-130 07/18/11 11:43
Dibromofluoromethane (S)%102 70-130 07/18/11 11:43
Toluene-d8 (S)%102 70-130 07/18/11 11:43
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
635168LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/kg 52.050 104 70-131
1,1,1-Trichloroethane ug/kg 49.550 99 70-141
1,1,2,2-Tetrachloroethane ug/kg 54.050 108 70-130
1,1,2-Trichloroethane ug/kg 52.650 105 70-132
1,1-Dichloroethane ug/kg 47.750 95 70-143
1,1-Dichloroethene ug/kg 47.050 94 70-137
1,1-Dichloropropene ug/kg 46.450 93 70-135
1,2,3-Trichlorobenzene ug/kg 52.450 105 69-153
1,2,3-Trichloropropane ug/kg 50.150 100 70-130
1,2,4-Trichlorobenzene ug/kg 53.150 106 55-171
1,2,4-Trimethylbenzene ug/kg 52.050 104 70-149
1,2-Dibromo-3-chloropropane ug/kg 51.250 102 68-141
1,2-Dibromoethane (EDB)ug/kg 51.450 103 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 68 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
635168LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichlorobenzene ug/kg 51.850 104 70-140
1,2-Dichloroethane ug/kg 47.350 95 70-137
1,2-Dichloropropane ug/kg 50.650 101 70-133
1,3,5-Trimethylbenzene ug/kg 51.950 104 70-143
1,3-Dichlorobenzene ug/kg 51.750 103 70-144
1,3-Dichloropropane ug/kg 50.950 102 70-132
1,4-Dichlorobenzene ug/kg 51.750 103 70-142
2,2-Dichloropropane ug/kg 51.150 102 68-152
2-Butanone (MEK)ug/kg 106100 106 70-149
2-Chlorotoluene ug/kg 51.350 103 70-141
2-Hexanone ug/kg 108100 108 70-149
4-Chlorotoluene ug/kg 54.150 108 70-149
4-Methyl-2-pentanone (MIBK)ug/kg 105100 105 70-153
Acetone ug/kg 112100 112 70-157
Benzene ug/kg 46.350 93 70-130
Bromobenzene ug/kg 49.450 99 70-141
Bromochloromethane ug/kg 48.350 97 70-149
Bromodichloromethane ug/kg 49.550 99 70-130
Bromoform ug/kg 54.150 108 70-131
Bromomethane ug/kg 50.850 102 64-136
Carbon tetrachloride ug/kg 47.550 95 70-154
Chlorobenzene ug/kg 51.750 103 70-135
Chloroethane ug/kg 49.150 98 68-151
Chloroform ug/kg 51.550 103 70-130
Chloromethane ug/kg 47.950 96 70-132
cis-1,2-Dichloroethene ug/kg 46.950 94 70-140
cis-1,3-Dichloropropene ug/kg 51.950 104 70-137
Dibromochloromethane ug/kg 51.750 103 70-130
Dibromomethane ug/kg 49.750 99 70-136
Dichlorodifluoromethane ug/kg 50.850 102 36-148
Diisopropyl ether ug/kg 50.950 102 70-139
Ethylbenzene ug/kg 49.450 99 70-137
Hexachloro-1,3-butadiene ug/kg 50.450 101 70-145
Isopropylbenzene (Cumene)ug/kg 51.950 104 70-141
m&p-Xylene ug/kg 100100 100 70-140
Methyl-tert-butyl ether ug/kg 51.850 104 45-150
Methylene Chloride ug/kg 53.050 106 70-133
n-Butylbenzene ug/kg 53.850 108 65-155
n-Propylbenzene ug/kg 52.550 105 70-148
Naphthalene ug/kg 55.750 111 70-148
o-Xylene ug/kg 50.750 101 70-141
p-Isopropyltoluene ug/kg 53.150 106 70-148
sec-Butylbenzene ug/kg 52.750 105 70-145
Styrene ug/kg 54.250 108 70-138
tert-Butylbenzene ug/kg 52.050 104 70-143
Tetrachloroethene ug/kg 51.150 102 70-140
Toluene ug/kg 47.850 96 70-130
trans-1,2-Dichloroethene ug/kg 46.750 93 70-136
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 69 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
635168LABORATORY CONTROL SAMPLE:
LCSSpike
trans-1,3-Dichloropropene ug/kg 53.150 106 70-138
Trichloroethene ug/kg 49.650 99 70-132
Trichlorofluoromethane ug/kg 47.650 95 69-134
Vinyl acetate ug/kg 161100 161 24-161
Vinyl chloride ug/kg 50.950 102 55-140
Xylene (Total)ug/kg 151150 101 70-141
1,2-Dichloroethane-d4 (S)%105 70-132
4-Bromofluorobenzene (S)%102 70-130
Dibromofluoromethane (S)%99 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
635474MATRIX SPIKE SAMPLE:
MSSpike
Result
9297989006
1,1-Dichloroethene ug/kg 51.061.3 83 49-180ND
Benzene ug/kg 56.061.3 91 50-166ND
Chlorobenzene ug/kg 57.661.3 94 43-169ND
Toluene ug/kg 57.561.3 94 52-163ND
Trichloroethene ug/kg 58.961.3 96 49-167ND
1,2-Dichloroethane-d4 (S)%84 70-132
4-Bromofluorobenzene (S)%93 70-130
Dibromofluoromethane (S)%92 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
Dup
Result QualifiersRPDResult
9298152001
635475SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/kg <4.9<4.9
1,1,1-Trichloroethane ug/kg <4.9<4.9
1,1,2,2-Tetrachloroethane ug/kg <4.9<4.9
1,1,2-Trichloroethane ug/kg <4.9<4.9
1,1-Dichloroethane ug/kg <4.9<4.9
1,1-Dichloroethene ug/kg <4.9<4.9
1,1-Dichloropropene ug/kg <4.9<4.9
1,2,3-Trichlorobenzene ug/kg <4.9<4.9
1,2,3-Trichloropropane ug/kg <4.9<4.9
1,2,4-Trichlorobenzene ug/kg <4.9<4.9
1,2,4-Trimethylbenzene ug/kg <4.9<4.9
1,2-Dibromo-3-chloropropane ug/kg <4.9<4.9
1,2-Dibromoethane (EDB)ug/kg <4.9<4.9
1,2-Dichlorobenzene ug/kg <4.9<4.9
1,2-Dichloroethane ug/kg <4.9<4.9
1,2-Dichloropropane ug/kg <4.9<4.9
1,3,5-Trimethylbenzene ug/kg <4.9<4.9
1,3-Dichlorobenzene ug/kg <4.9<4.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 70 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameter Units
Dup
Result QualifiersRPDResult
9298152001
635475SAMPLE DUPLICATE:
1,3-Dichloropropane ug/kg <4.9<4.9
1,4-Dichlorobenzene ug/kg <4.9<4.9
2,2-Dichloropropane ug/kg <4.9<4.9
2-Butanone (MEK)ug/kg <97.1<98.7
2-Chlorotoluene ug/kg <4.9<4.9
2-Hexanone ug/kg <48.5<49.4
4-Chlorotoluene ug/kg <4.9<4.9
4-Methyl-2-pentanone (MIBK)ug/kg <48.5<49.4
Acetone ug/kg <97.1<98.7
Benzene ug/kg <4.9<4.9
Bromobenzene ug/kg <4.9<4.9
Bromochloromethane ug/kg <4.9<4.9
Bromodichloromethane ug/kg <4.9<4.9
Bromoform ug/kg <4.9<4.9
Bromomethane ug/kg <9.7<9.9
Carbon tetrachloride ug/kg <4.9<4.9
Chlorobenzene ug/kg <4.9<4.9
Chloroethane ug/kg <9.7<9.9
Chloroform ug/kg <4.9<4.9
Chloromethane ug/kg <9.7<9.9
cis-1,2-Dichloroethene ug/kg <4.9<4.9
cis-1,3-Dichloropropene ug/kg <4.9<4.9
Dibromochloromethane ug/kg <4.9<4.9
Dibromomethane ug/kg <4.9<4.9
Dichlorodifluoromethane ug/kg <9.7<9.9
Diisopropyl ether ug/kg <4.9<4.9
Ethylbenzene ug/kg <4.9<4.9
Hexachloro-1,3-butadiene ug/kg <4.9<4.9
Isopropylbenzene (Cumene)ug/kg <4.9<4.9
m&p-Xylene ug/kg <9.7<9.9
Methyl-tert-butyl ether ug/kg <4.9<4.9
Methylene Chloride ug/kg <19.4<19.7
n-Butylbenzene ug/kg <4.9<4.9
n-Propylbenzene ug/kg <4.9<4.9
Naphthalene ug/kg <4.9<4.9
o-Xylene ug/kg <4.9<4.9
p-Isopropyltoluene ug/kg <4.9<4.9
sec-Butylbenzene ug/kg <4.9<4.9
Styrene ug/kg <4.9<4.9
tert-Butylbenzene ug/kg <4.9<4.9
Tetrachloroethene ug/kg <4.9<4.9
Toluene ug/kg <4.9<4.9
trans-1,2-Dichloroethene ug/kg <4.9<4.9
trans-1,3-Dichloropropene ug/kg <4.9<4.9
Trichloroethene ug/kg <4.9<4.9
Trichlorofluoromethane ug/kg <4.9<4.9
Vinyl acetate ug/kg <48.5<49.4
Vinyl chloride ug/kg <9.7<9.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 71 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameter Units
Dup
Result QualifiersRPDResult
9298152001
635475SAMPLE DUPLICATE:
Xylene (Total)ug/kg <9.7<9.9
1,2-Dichloroethane-d4 (S)%87 1094
4-Bromofluorobenzene (S)%95 192
Dibromofluoromethane (S)%95 12105
Toluene-d8 (S)%100 2100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 72 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/16029
EPA 8260
EPA 8260
8260 MSV 5035A Volatile Organics
Associated Lab Samples:9298263001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:635169
Associated Lab Samples:9298263001
Matrix:Solid
Analyzed
1,1,1,2-Tetrachloroethane ug/kg <5.0 5.0 07/18/11 11:23
1,1,1-Trichloroethane ug/kg <5.0 5.0 07/18/11 11:23
1,1,2,2-Tetrachloroethane ug/kg <5.0 5.0 07/18/11 11:23
1,1,2-Trichloroethane ug/kg <5.0 5.0 07/18/11 11:23
1,1-Dichloroethane ug/kg <5.0 5.0 07/18/11 11:23
1,1-Dichloroethene ug/kg <5.0 5.0 07/18/11 11:23
1,1-Dichloropropene ug/kg <5.0 5.0 07/18/11 11:23
1,2,3-Trichlorobenzene ug/kg <5.0 5.0 07/18/11 11:23
1,2,3-Trichloropropane ug/kg <5.0 5.0 07/18/11 11:23
1,2,4-Trichlorobenzene ug/kg <5.0 5.0 07/18/11 11:23
1,2,4-Trimethylbenzene ug/kg <5.0 5.0 07/18/11 11:23
1,2-Dibromo-3-chloropropane ug/kg <5.0 5.0 07/18/11 11:23
1,2-Dibromoethane (EDB)ug/kg <5.0 5.0 07/18/11 11:23
1,2-Dichlorobenzene ug/kg <5.0 5.0 07/18/11 11:23
1,2-Dichloroethane ug/kg <5.0 5.0 07/18/11 11:23
1,2-Dichloropropane ug/kg <5.0 5.0 07/18/11 11:23
1,3,5-Trimethylbenzene ug/kg <5.0 5.0 07/18/11 11:23
1,3-Dichlorobenzene ug/kg <5.0 5.0 07/18/11 11:23
1,3-Dichloropropane ug/kg <5.0 5.0 07/18/11 11:23
1,4-Dichlorobenzene ug/kg <5.0 5.0 07/18/11 11:23
2,2-Dichloropropane ug/kg <5.0 5.0 07/18/11 11:23
2-Butanone (MEK)ug/kg <100 100 07/18/11 11:23
2-Chlorotoluene ug/kg <5.0 5.0 07/18/11 11:23
2-Hexanone ug/kg <50.0 50.0 07/18/11 11:23
4-Chlorotoluene ug/kg <5.0 5.0 07/18/11 11:23
4-Methyl-2-pentanone (MIBK)ug/kg <50.0 50.0 07/18/11 11:23
Acetone ug/kg <100 100 07/18/11 11:23
Benzene ug/kg <5.0 5.0 07/18/11 11:23
Bromobenzene ug/kg <5.0 5.0 07/18/11 11:23
Bromochloromethane ug/kg <5.0 5.0 07/18/11 11:23
Bromodichloromethane ug/kg <5.0 5.0 07/18/11 11:23
Bromoform ug/kg <5.0 5.0 07/18/11 11:23
Bromomethane ug/kg <10.0 10.0 07/18/11 11:23
Carbon tetrachloride ug/kg <5.0 5.0 07/18/11 11:23
Chlorobenzene ug/kg <5.0 5.0 07/18/11 11:23
Chloroethane ug/kg <10.0 10.0 07/18/11 11:23
Chloroform ug/kg <5.0 5.0 07/18/11 11:23
Chloromethane ug/kg <10.0 10.0 07/18/11 11:23
cis-1,2-Dichloroethene ug/kg <5.0 5.0 07/18/11 11:23
cis-1,3-Dichloropropene ug/kg <5.0 5.0 07/18/11 11:23
Dibromochloromethane ug/kg <5.0 5.0 07/18/11 11:23
Dibromomethane ug/kg <5.0 5.0 07/18/11 11:23
Dichlorodifluoromethane ug/kg <10.0 10.0 07/18/11 11:23
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 73 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:635169
Associated Lab Samples:9298263001
Matrix:Solid
Analyzed
Diisopropyl ether ug/kg <5.0 5.0 07/18/11 11:23
Ethylbenzene ug/kg <5.0 5.0 07/18/11 11:23
Hexachloro-1,3-butadiene ug/kg <5.0 5.0 07/18/11 11:23
Isopropylbenzene (Cumene)ug/kg <5.0 5.0 07/18/11 11:23
m&p-Xylene ug/kg <10.0 10.0 07/18/11 11:23
Methyl-tert-butyl ether ug/kg <5.0 5.0 07/18/11 11:23
Methylene Chloride ug/kg <20.0 20.0 07/18/11 11:23
n-Butylbenzene ug/kg <5.0 5.0 07/18/11 11:23
n-Propylbenzene ug/kg <5.0 5.0 07/18/11 11:23
Naphthalene ug/kg <5.0 5.0 07/18/11 11:23
o-Xylene ug/kg <5.0 5.0 07/18/11 11:23
p-Isopropyltoluene ug/kg <5.0 5.0 07/18/11 11:23
sec-Butylbenzene ug/kg <5.0 5.0 07/18/11 11:23
Styrene ug/kg <5.0 5.0 07/18/11 11:23
tert-Butylbenzene ug/kg <5.0 5.0 07/18/11 11:23
Tetrachloroethene ug/kg <5.0 5.0 07/18/11 11:23
Toluene ug/kg <5.0 5.0 07/18/11 11:23
trans-1,2-Dichloroethene ug/kg <5.0 5.0 07/18/11 11:23
trans-1,3-Dichloropropene ug/kg <5.0 5.0 07/18/11 11:23
Trichloroethene ug/kg <5.0 5.0 07/18/11 11:23
Trichlorofluoromethane ug/kg <5.0 5.0 07/18/11 11:23
Vinyl acetate ug/kg <50.0 50.0 07/18/11 11:23
Vinyl chloride ug/kg <10.0 10.0 07/18/11 11:23
Xylene (Total)ug/kg <10.0 10.0 07/18/11 11:23
1,2-Dichloroethane-d4 (S)%98 70-132 07/18/11 11:23
4-Bromofluorobenzene (S)%94 70-130 07/18/11 11:23
Dibromofluoromethane (S)%100 70-130 07/18/11 11:23
Toluene-d8 (S)%102 70-130 07/18/11 11:23
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
635170LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/kg 49.150 98 70-131
1,1,1-Trichloroethane ug/kg 47.050 94 70-141
1,1,2,2-Tetrachloroethane ug/kg 49.450 99 70-130
1,1,2-Trichloroethane ug/kg 47.050 94 70-132
1,1-Dichloroethane ug/kg 45.550 91 70-143
1,1-Dichloroethene ug/kg 45.550 91 70-137
1,1-Dichloropropene ug/kg 44.650 89 70-135
1,2,3-Trichlorobenzene ug/kg 49.550 99 69-153
1,2,3-Trichloropropane ug/kg 45.550 91 70-130
1,2,4-Trichlorobenzene ug/kg 49.950 100 55-171
1,2,4-Trimethylbenzene ug/kg 50.350 101 70-149
1,2-Dibromo-3-chloropropane ug/kg 44.650 89 68-141
1,2-Dibromoethane (EDB)ug/kg 49.150 98 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 74 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
635170LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichlorobenzene ug/kg 48.750 97 70-140
1,2-Dichloroethane ug/kg 44.650 89 70-137
1,2-Dichloropropane ug/kg 46.350 93 70-133
1,3,5-Trimethylbenzene ug/kg 49.450 99 70-143
1,3-Dichlorobenzene ug/kg 48.550 97 70-144
1,3-Dichloropropane ug/kg 47.150 94 70-132
1,4-Dichlorobenzene ug/kg 49.950 100 70-142
2,2-Dichloropropane ug/kg 50.050 100 68-152
2-Butanone (MEK)ug/kg <100100 97 70-149
2-Chlorotoluene ug/kg 48.750 97 70-141
2-Hexanone ug/kg 99.9100 100 70-149
4-Chlorotoluene ug/kg 50.750 101 70-149
4-Methyl-2-pentanone (MIBK)ug/kg 95.9100 96 70-153
Acetone ug/kg 103100 103 70-157
Benzene ug/kg 43.150 86 70-130
Bromobenzene ug/kg 46.250 92 70-141
Bromochloromethane ug/kg 46.150 92 70-149
Bromodichloromethane ug/kg 46.250 92 70-130
Bromoform ug/kg 49.450 99 70-131
Bromomethane ug/kg 48.050 96 64-136
Carbon tetrachloride ug/kg 50.950 102 70-154
Chlorobenzene ug/kg 48.550 97 70-135
Chloroethane ug/kg 45.250 90 68-151
Chloroform ug/kg 48.650 97 70-130
Chloromethane ug/kg 45.150 90 70-132
cis-1,2-Dichloroethene ug/kg 45.250 90 70-140
cis-1,3-Dichloropropene ug/kg 47.550 95 70-137
Dibromochloromethane ug/kg 47.750 95 70-130
Dibromomethane ug/kg 45.850 92 70-136
Dichlorodifluoromethane ug/kg 48.450 97 36-148
Diisopropyl ether ug/kg 48.450 97 70-139
Ethylbenzene ug/kg 46.650 93 70-137
Hexachloro-1,3-butadiene ug/kg 47.150 94 70-145
Isopropylbenzene (Cumene)ug/kg 49.250 98 70-141
m&p-Xylene ug/kg 95.1100 95 70-140
Methyl-tert-butyl ether ug/kg 48.250 96 45-150
Methylene Chloride ug/kg 49.550 99 70-133
n-Butylbenzene ug/kg 51.950 104 65-155
n-Propylbenzene ug/kg 50.250 100 70-148
Naphthalene ug/kg 51.250 102 70-148
o-Xylene ug/kg 48.050 96 70-141
p-Isopropyltoluene ug/kg 50.950 102 70-148
sec-Butylbenzene ug/kg 50.250 100 70-145
Styrene ug/kg 51.450 103 70-138
tert-Butylbenzene ug/kg 48.950 98 70-143
Tetrachloroethene ug/kg 48.350 97 70-140
Toluene ug/kg 44.850 90 70-130
trans-1,2-Dichloroethene ug/kg 44.650 89 70-136
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 75 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
635170LABORATORY CONTROL SAMPLE:
LCSSpike
trans-1,3-Dichloropropene ug/kg 48.350 97 70-138
Trichloroethene ug/kg 45.950 92 70-132
Trichlorofluoromethane ug/kg 45.850 92 69-134
Vinyl acetate ug/kg 169 L310016924-161
Vinyl chloride ug/kg 48.050 96 55-140
Xylene (Total)ug/kg 143150 95 70-141
1,2-Dichloroethane-d4 (S)%99 70-132
4-Bromofluorobenzene (S)%101 70-130
Dibromofluoromethane (S)%99 70-130
Toluene-d8 (S)%99 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 76 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
PMST/4061
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples:9298263001, 9298263002, 9298263003, 9298263004
Parameter Units
Dup
Result QualifiersRPDResult
9298270001
634485SAMPLE DUPLICATE:
Percent Moisture %10.4 79.6
Parameter Units
Dup
Result QualifiersRPDResult
9298324003
634486SAMPLE DUPLICATE:
Percent Moisture %53.8 053.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 77 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALIFIERS
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Surrogate recovery outside laboratory control limits after moisture correction for methanol.1g
Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3
Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.L3
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold TNI accreditation for this parameter.N2
RPD value was outside control limits.R1
Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated samples.
Results unaffected by high bias.S3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 78 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
9298263
15929-BERRYMAN PROPERTY
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
9298263003 OEXT/14234 GCSV/10177SB-2 (6-8)MADEP EPH MADEP EPH
9298263004 OEXT/14234 GCSV/10177SB-2 (16-18)MADEP EPH MADEP EPH
9298263006 OEXT/14244 GCSV/10167MW-2 MADEP EPH MADEP EPH
9298263001 GCV/5205 GCV/5217SB-1 (11-13)MADEP VPH MADEP VPH
9298263002 GCV/5205 GCV/5225SB-1 (21-23)MADEP VPH MADEP VPH
9298263003 GCV/5205 GCV/5217SB-2 (6-8)MADEP VPH MADEP VPH
9298263004 GCV/5205 GCV/5217SB-2 (16-18)MADEP VPH MADEP VPH
9298263005 GCV/5226MW-1 MADEP VPH
9298263006 GCV/5213MW-2 MADEP VPH
9298263005 MPRP/8744 ICP/8072MW-1 SM 3030C EPA 200.7
9298263006 OEXT/14221 MSSV/5170MW-2 EPA 625 EPA 625
9298263003 OEXT/14224 MSSV/5160SB-2 (6-8)EPA 3546 EPA 8270
9298263004 OEXT/14224 MSSV/5160SB-2 (16-18)EPA 3546 EPA 8270
9298263005 MSV/16054MW-1 SM 6200B
9298263006 MSV/16054MW-2 SM 6200B
9298263007 MSV/16054MW-3 SM 6200B
9298263008 MSV/16054MW-4 SM 6200B
9298263009 MSV/16054MW-5 SM 6200B
9298263001 MSV/16029SB-1 (11-13)EPA 8260
9298263002 MSV/16028SB-1 (21-23)EPA 8260
9298263003 MSV/16028SB-2 (6-8)EPA 8260
9298263004 MSV/16028SB-2 (16-18)EPA 8260
9298263001 PMST/4061SB-1 (11-13)ASTM D2974-87
9298263002 PMST/4061SB-1 (21-23)ASTM D2974-87
9298263003 PMST/4061SB-2 (6-8)ASTM D2974-87
9298263004 PMST/4061SB-2 (16-18)ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/25/2011 03:27 PM Page 79 of 79
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]

APPENDIX VI

FIELD MEASUREMENT SHEETS