RA-2181_13379_CA_RPTS_20191209_2019 QTR 2 LETTER REPORT

 
WithersRavenel
Our People. Your Success. 
115 MacKenan Drive | Cary, NC 27511 
t: 919.469.3340 | f: 919.467.6008 | www.withersravenel.com | License No. C‐0832 
Cary | Greensboro | Pittsboro | Raleigh | Wilmington

December 9, 2019 

State of North Carolina 
Department of Environmental Quality 
Federal & State Lead Program 
Division of Waste Management‐Underground Storage Tank Section 
1646 Mail Service Center 
Raleigh, North Carolina 27699‐1646 

Attn: Mr. Mark Petermann 

Reference:   Letter Report – Small Scale Injection Follow‐up Monitoring &  
Supply Well Sampling 
Arvin Oil Company 
5837 & 5839 Fayetteville Road (US Hwy. 401) 
Raleigh, Wake County, North Carolina  
Groundwater Incident Number: 13379 
UST Number: RA‐2181 
Facility ID No.: 00‐0‐0000025743 
WR Project Number:  02140217.69 

Mr. Petermann: 

WithersRavenel, Inc. (WR) has prepared this letter report to document the performance of follow‐
up groundwater monitoring at the Arvin Oil Company site, located at 5837‐5839 Fayetteville Road 
in Raleigh, Wake County, North Carolina.  These activities were performed in association with TA‐
08 for the site, under Contract # N17005, authorized by NCDEQ on October 15, 2019.     

WR was tasked with the completion of a limited groundwater sampling event at the facility, as 
follow‐up to small‐scale injection events conducted at the site during November 2017 and January 
2019.  This limited groundwater sampling event was performed on October 22, 2019 and included 
the purging and sampling of monitoring wells MW‐1, MW‐3R, MW‐4, MWD‐5, MW‐8 and MWD‐
9.  WR was also tasked with the collection of supply well samples from WSW‐2, WSW‐20, WSW‐
21 and WSW‐22.   

Limited Groundwater Sampling Event   
Prior to purging and sampling, WR personnel opened and gauged each well with an electronic 
water level indicator.  Depths to groundwater measured in these wells ranged from 27.63 ft 
beneath the top of casing (BTOC) in MW‐3R to 29.61 ft BTOC in MW‐1.  Groundwater levels 
within the wells gauged in October 2019 averaged 2.7 ft deeper than levels measured in April 
2019.   

Following gauging, each well was purged with a separate disposable bailer until three well volumes 
had been purged from the well(s).  Wells were samples with the bailers after adequate purge had 
been completed.  Samples from the monitoring wells obtained on October 22, 2019 were 
submitted for laboratory analysis by SM6200B.   

WithersRavenel
Our People. Your Success. 
Former Arvin Oil Company Incident #13379 WR Project # 02170214.69 
Letter Report – Small Scale Injection Follow‐up Monitoring December 2019 
Page 2 of 4 

At the time of sampling, WR personnel monitored levels of dissolved oxygen (DO), pH, water 
temperature (temp), specific conductance and oxidation‐reduction potential (ORP) in the wells.   
Monitoring of these parameters was performed to determine the effect the injectant material was 
having on groundwater chemistry.  These measurements for each of the wells monitored are 
shown in the following table, which includes measurements obtained from the same wells during 
previous monitoring activities: 

DO Temp. Conductivity pH ORP
mg/L °C µS/cm Std. Units mV
2/26/2018 2.41 17.35 0.169 8.95 214.6
6/8/2018 2.14 18.49 0.081 8.78 419.2
10/23/2018 2.32 16.83 0.068 6.04 217.3
4/23/2019 4.36 19.81 0.072 5.44 257.8
10/22/2019 2.43 18.08 0.122 7.66 226.1
11/13/2017 1.14 17.52 0.186 5.15 134.3
11/20/2017 5.67 17.88 0.131 4.40 313.1
2/26/2018 1.44 19.03 0.138 8.71 214.6
6/8/2018 4.01 20.00 0.253 8.89 406.5
10/23/2018 1.63 18.28 0.376 6.16 214.1
1/29/2019 3.23 19.76 0.127 6.55 122.1
4/23/2019 2.14 20.73 0.146 4.98 143.5
10/22/2019 1.44 19.24 0.205 5.24 164.3
11/13/2017 0.94 17.44 1.470 6.36 -1.6
11/20/2017 25.56 17.92 0.936 11.79 112.8
2/26/2018 24.61 18.29 3.129 8.97 66.2
6/8/2018 1.19 18.66 0.410 8.70 420.8
10/23/2018 21.21 17.88 0.469 11.02 215.2
1/29/2019 47.71 18.54 0.693 11.75 32.2
4/23/2019 19.02 19.78 0.256 10.43 43.3
10/22/2019 15.56 18.41 0.424 8.77 244.5
11/13/2017 1.20 18.70 0.142 5.09 69.9
11/20/2017 17.93 18.73 0.207 11.19 132.1
2/26/2018 2.60 18.63 0.131 8.79 189.5
6/8/2018 2.64 18.97 0.143 8.69 420.1
10/23/2018 2.82 17.44 0.119 7.64 206.9
1/29/2019 30.33 19.52 0.082 8.88 85.4
4/23/2019 1.88 19.87 0.120 6.41 83.8
10/22/2019 5.41 18.33 0.148 5.98 18.9
11/13/2017 0.94 12.91 0.155 4.99 119.2
11/20/2017 29.70 12.61 4.882 12.59 68.2
2/26/2018 29.04 18.17 5.280 9.01 57.1
6/8/2018 18.33 19.08 4.651 9.08 404.3
10/23/2018 22.22 17.73 6.047 11.47 215.2
1/29/2019 39.12 18.72 6.704 12.84 20.1
4/23/2019 33.20 19.51 7.600 12.47 -32.6
10/22/2019 27.29 18.62 6.470 12.27 -45.6
11/13/2017 1.01 17.32 0.084 5.27 63.6
11/20/2017 33.49 17.25 0.082 6.81 258.4
2/26/2018 14.84 18.15 0.066 8.76 251.1
6/8/2018 15.43 18.79 0.076 8.71 419.0
10/23/2018 20.16 17.57 0.074 6.36 221.2
1/29/2019 35.48 19.44 0.091 8.92 102.6
4/23/2019 26.34 20.25 0.074 6.14 124.0
10/22/2019 18.98 17.99 0.069 5.74 134.1
Summary of Field Measurements
Well ID Date
MWD-9
MW-8
MWD-5
MW-4
MW-3R
MW-1
WithersRavenel
Our People. Your Success. 
Former Arvin Oil Company Incident #13379 WR Project # 02170214.69 
Letter Report – Small Scale Injection Follow‐up Monitoring December 2019 
Page 3 of 4 

Measurements obtained in October 2019 when compared to data from April 2019 showed the 
following: 

 Dissolved Oxygen – A substantial decrease in DO was seen in well MWD‐5, while a moderate 
drop was shown in MW‐8.  Levels of DO in MW‐4 and MWD‐9 also dropped, only slightly.  
DO in MW‐1 increased slightly. 

 pH – A substantial decrease in pH was seen in MW‐4, while levels of pH in MW‐8 remained 
high (>12).  Levels of pH remained relatively stable in the remaining wells.    

 Specific Conductance – Specific conductance remained relatively stable in the wells, with the 
exception of a slight decrease measured in MW‐8.      

 Oxidation‐Reduction Potential ‐ ORP measurements remained generally stable over the April 
– October 2019 period, excepting a substantial increase in MW‐4 and moderate decrease in 
MWD‐5.   

Analytical results for the groundwater samples obtained from site monitoring wells on October 
22, 2019 showed one or more petroleum compounds in each of the wells sampled at 
concentrations exceeding their respective 2L Standards.  Samples from each of the wells showed 
general increases in contaminants (based on total BTEX concentrations) over the April 2019 data.  
Total BTEX increases in MW‐8 were substantial over the April 2019 results.  Charts showing total 
BTEX concentrations in over time are included as an attachment.   

The increase in contaminants identified in the wells sampled during October 2019 may relate to 
contaminant rebounding in association with groundwater level fluctuations (as previously noted, 
groundwater levels averaged 2.7 ft deeper than those measured in April 2019).  Notably, benzene 
was reported in the sample from MW‐8 at a concentration exceeding the 2L Standard for the 
compound.  This is the highest level of benzene reported in the well to date, and may be an 
indication that injection activities have liberated contaminants once bound to soils at the location.   

On balance, comparison of values for the parameters measured and analytical results obtained in 
association with sampling of the wells show that groundwater chemistry has been affected in such 
a way as to promote continued degradation of targeted petroleum contaminants in the several 
wells on the property, however, as is the case for injections of the nature completed at the site, 
rebounding of contaminants appears to be occurring, possibly based on changes in groundwater 
levels at the site.  .   

Supply Well Sampling   
WR also purged and sampled supply wells WSW‐2, WSW‐20, WSW‐21 and WSW‐22 in 
association with this TA. 

Supply well samples were collected from these wells following a minimum 10‐minute purge and 
submitted for laboratory analysis by SM6200B.  Laboratory results for the samples showed the 
presence of 1,2‐DCA and MTBE in WSW‐2 (the on‐site supply well) at levels above the NC 2L 
WithersRavenel
Our People. Your Success. 
Former Arvin Oil Company Incident #13379 WR Project # 02170214.69 
Letter Report – Small Scale Injection Follow‐up Monitoring December 2019 
Page 4 of 4 

Standards for these compounds, and IPE at a concentration below the 2L Standard.  Data for 
WSW‐22 showed acetone at a concentration of 14 ug/L, well beneath the 2L Standard for the 
compound.  WR believes the presence of acetone in the well to be an artifact, as the compound is 
a known laboratory cross‐contaminant.   

The laboratory report associated with the supply well samples and those obtained from site 
monitoring wells in October 2019 is included as an attachment.   

WR recommends the performance of a limited groundwater monitoring event to be conducted 
during January to verify contaminant trends in select monitoring wells and the sampling of on‐site 
supply well WSW‐2.   

If you have any questions or concerns regarding this report, please contact us at (919) 469‐3340. 

Cordially, 
WithersRavenel 
  Kevin Buchanan Matt James, PG 
Staff Environmental Scientist II Senior Geologist 

Attachments:  

Table B‐4 (Abbreviated),  
Total BTEX Contaminant Charts ‐ Select Monitoring Wells, 
Water Supply Well Analytical Results (Table) 
Field Notes, 
Laboratory Analytical Report 

TABLE B‐4 (ABBREVIATED) 

SUMMARY OF GROUNDWATER ANALYTICAL RESULTS  

CalculatedSampleIDDateCollectedAcetoneBenzeneIsopropyl EtherEthylbenzene2‐HEXANONEIsopropylbenzene2‐Butanone (MEK)4‐Methyl‐2‐pentanone (MIBK)Methyl tert‐butyl etherNaphthalenen‐PropylbenzeneToluene1,2,4‐Trimethylbenzene1,3,5‐TrimethylbenzeneTotal XylenesMW‐1 10/22/2019<0.31 4.8<0.050 0.51<0.065 <0.054 <0.24 <0.078 <0.042 <0.19 <0.087 <0.044 <0.054 <0.076 1.9MW‐3R 10/22/2019<31 4900<5.0 3400 400 110<500 <7.8 2000 760 320 29000 2900 800 19000MWD‐5 10/22/2019470 340<0.50 210 320 7.3 250 150 28 180 18 2100 510 140 2600MW‐8 10/22/2019<31 1200064 1100<6.5 <50 <24 <7.8 12000 260 83 7800 810 200 5700MWD‐9 10/22/2019<0.31 2.3<0.5 <0.061 <0.065 <0.054 <0.24 <0.078 99<0.19 <0.087 <0.044 <0.054 <0.076 <1.56000 1 70 600 NL 70 4000 100 20 6 70 600 400 400 5006,000,000 5,000 70,000 84,500 NL 25,000 4,000,000 100,000 20,000 6,000 3,000 260,000 28,500 25,000 85,500Notes:1)2)3)4) US EPA MCL = US EPA Region IV Maximum Contaminant Level5)NL= Not ListedResult= Result Exceeds Laboratory Detection LimitsResult= Result Exceeds 2L StandardResult= Result Exceeds GCL ValueAnalytical MethodSM6200B ‐ Volatile Organic CompoundsTABLE B‐4 (ABBREVIATED)SUMMARY OF GROUNDWATER ANALYTICAL RESULTSArvin Oil CompanyIncident Number: 133795837‐5839 Fayettville RoadRaleigh, Wake County, North CarolinaGCLs for Groundwater = NCDENR UST Section Gross Contamination Levels for GroundwaterOnly those compounds detected in one or more samples are shown hereon. NC 2L Standard GCLs for GroundwaterAll results provided in ug/L (micrograms per liter) or parts per billionNC 2L Standard ‐ Water Quality Standards for Class GA Groundwater, defined by NCAC Title 15A, Subchapter 02L, Section .0202Page 1 of 1

TOTAL BTEX CONTAMINANT CHARTS 

SELECT MONITORING WELLS 
38,60053,50032,09043,41052,54061,45059,90023,40056,300010,00020,00030,00040,00050,00060,00070,000Jun‐14 Dec‐14 Jul‐15 Jan‐16 Aug‐16 Mar‐17 Sep‐17 Apr‐18 Oct‐18 May‐19 Dec‐19 Jun‐20Total BTEX (ug/L) ‐ MW‐3R
43,70050,5008,25632,06032,0408,6878,89054811,340010,00020,00030,00040,00050,00060,00010‐Jun 27‐Dec 15‐Jul 31‐Jan 18‐Aug 6‐Mar 22‐Sep 10‐Apr 27‐Oct 15‐May 1‐Dec 18‐JunTotal BTEX (ug/L) ‐ MW‐4
39,80051,87040,72042,6805172,4062,6161025,250‐10,000010,00020,00030,00040,00050,00060,000Jun‐14 Dec‐14 Jul‐15 Jan‐16 Aug‐16 Mar‐17 Sep‐17 Apr‐18 Oct‐18 May‐19 Dec‐19 Jun‐20Total BTEX (ug/L) ‐ MWD‐5
37,08020,9003,02828,86025,19010,8802,56026,60005,00010,00015,00020,00025,00030,00035,00040,000Dec‐14 Jul‐15 Jan‐16 Aug‐16 Mar‐17 Sep‐17 Apr‐18 Oct‐18 May‐19 Dec‐19 Jun‐20Total BTEX (ug/L) ‐ MW‐8

WATER SUPPLY WELL ANALYTICAL RESULTS (TABLE) 

1,2‐Dichloroethane1.3 0.4 400 5Isopropyl Ether0.83 70 70,000 NLRaleigh, NC 27606 Raleigh, NC 27606Methyl tert‐butyl ether35 20 20,000 NL1700 Pinedale Drive1700 Pinedale DriveRaleigh, NC 27606 Raleigh, NC 276061704 Pinedale Drive1704 Pinedale DriveRaleigh, NC 27606 Raleigh, NC 276061708 Pinedale Drive1708 Pinedale DriveRaleigh, NC 27606 Raleigh, NC 276061)2)3)4)5)6)7)NC GCL  (µg/L)US EPA MCL  (µg/L)WATER SUPPLY WELL ANALYTICAL RESULTS ‐ OCTOBER 22, 2019Arvin Oil CompanyIncident Number: 133795837‐5839 Fayettville RoadRaleigh, Wake County, North CarolinaWell ID Property ID Property AddressWSW‐22 0790891307Well Use Compound NameLevel Detected (µg/L)NC 2L Standard  (µg/L)Property Owner Property Owner AddressWSW‐2 07907952855837 Fayetteville RoadArvin, James L.7600 Lake Wheeler RoadPotable SupplyNotes: Supply well designations and property locations from Crawford Environmental Services Groundwater Monitoring Report: June 2013, Table 2, Summary of Water Supply Well Information.  Property ownership information from Wake County, NC, iMAPS.  Data current as of October 31, 2019.NC 2L Standard defined by NCAC Title 15A, Suchapter 2L, Section .0202 (Water Quality Standards for Class GA Groundwater)GCL Denotes "Gross Contaminant Level"US EPA MCL is Maximum Contaminant Level for drinking water defined by Region IV, Environmental Protection Agency, June 2018.  0790891206 Eutsler, David L. Potable SupplyNLBDL Denotes "Beneath Detection Limit(s)"WSW‐20 0790891116 Lee, Ashlyn Styne Potable SupplyWSW‐21All CompoundsBDLBDL‐‐‐‐‐‐Casey A. Nesbitt Potable Supply‐‐‐‐‐‐‐‐‐‐‐‐Shaded cells indicate compound reported at concentration exceeding NC 2L Standard.Acetone14 6000 6,000,000All Compounds

FIELD NOTES 

LABORATORY ANALYTICAL REPORT 

This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample
Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed
according to the referenced methods.
Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case
narrative.
NC Certification No. 402
NC Drinking Water Cert No. 37735
SC Certification No. 99012
Case Narrative
10/31/19 12:57
Withers & Ravenel
Kevin Buchanan
115 Mackenan Dr. BUILDING 117
Cary, NC 27511
Project: Arvin Oil Company
Project No.: 02170214.69
Lab Submittal Date: 10/23/2019
Prism Work Order: 9100376
Please call if you have any questions relating to this analytical report.
Respectfully,
PRISM LABORATORIES, INC.
President/Project Manager
Reviewed ByRobbi A. Jones Robbi A. Jones
President/Project Manager
Data Qualifiers Key Reference:
Method Detection LimitMDL
Below Reporting LimitBRL
Relative Percent DifferenceRPD
*Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and
reporting limit indicated with a J.
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 1 of 31
Sample Receipt Summary
10/31/2019
Prism Work Order: 9100376
Client Sample ID MatrixLab Sample ID Date/Time Sampled Date/Time Received
9100376-01 10/22/19 12:10MW-1 10/23/19 17:10Water
9100376-02 10/22/19 9:50MW-3R 10/23/19 17:10Water
9100376-03 10/22/19 11:20MW-4 10/23/19 17:10Water
9100376-04 10/22/19 11:00MWD-5 10/23/19 17:10Water
9100376-05 10/22/19 11:50MW-8 10/23/19 17:10Water
9100376-06 10/22/19 10:30MWD-9 10/23/19 17:10Water
9100376-07 10/22/19 12:25WSW-2 10/23/19 17:10Water
9100376-08 10/22/19 12:50WSW-20 10/23/19 17:10Water
9100376-09 10/22/19 12:55WSW-21 10/23/19 17:10Water
9100376-10 10/22/19 13:10WSW-22 10/23/19 17:10Water
Samples were received in good condition at 2.7 degrees C unless otherwise noted.
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 2 of 31
Client ID ResultParameterMethod UnitsPrism ID
Prism Work Order: 9100376
10/31/2019
Summary of Detections
4.8 ug/L9100376-01 MW-1 Benzene *SM6200 B
0.51 ug/L9100376-01 MW-1 Ethylbenzene *SM6200 B
1.6 ug/L9100376-01 MW-1 m,p-Xylenes *SM6200 B
1.9 ug/L9100376-01 MW-1 Xylenes, total *SM6200 B
2900 ug/L9100376-02 MW-3R 1,2,4-Trimethylbenzene *SM6200 B
800 ug/L9100376-02 MW-3R 1,3,5-Trimethylbenzene *SM6200 B
4900 ug/L9100376-02 MW-3R Benzene *SM6200 B
3400 ug/L9100376-02 MW-3R Ethylbenzene *SM6200 B
110 ug/L9100376-02 MW-3R Isopropylbenzene (Cumene)*SM6200 B
13000 ug/L9100376-02 MW-3R m,p-Xylenes *SM6200 B
400 ug/L9100376-02 MW-3R Methyl Butyl Ketone (2-Hexanone)*SM6200 B
2000 ug/L9100376-02 MW-3R Methyl-tert-Butyl Ether *SM6200 B
760 ug/L9100376-02 MW-3R Naphthalene *SM6200 B
320 ug/L9100376-02 MW-3R n-Propylbenzene *SM6200 B
6400 ug/L9100376-02 MW-3R o-Xylene *SM6200 B
29000 ug/L9100376-02 MW-3R Toluene *SM6200 B
19000 ug/L9100376-02 MW-3R Xylenes, total *SM6200 B
670 ug/L9100376-03 MW-4 1,2,4-Trimethylbenzene *SM6200 B
220 ug/L9100376-03 MW-4 1,3,5-Trimethylbenzene *SM6200 B
1200 ug/L9100376-03 MW-4 Acetone *SM6200 B
1000 ug/L9100376-03 MW-4 Benzene *SM6200 B
340 ug/L9100376-03 MW-4 Ethylbenzene *SM6200 B
3100 ug/L9100376-03 MW-4 m,p-Xylenes *SM6200 B
290 ug/L9100376-03 MW-4 Methyl Butyl Ketone (2-Hexanone)*SM6200 B
680 ug/L9100376-03 MW-4 Methyl Ethyl Ketone (2-Butanone)*SM6200 B
180 ug/L9100376-03 MW-4 Methyl Isobutyl Ketone *SM6200 B
160 ug/L9100376-03 MW-4 Naphthalene *SM6200 B
1900 ug/L9100376-03 MW-4 o-Xylene *SM6200 B
5000 ug/L9100376-03 MW-4 Toluene *SM6200 B
5000 ug/L9100376-03 MW-4 Xylenes, total *SM6200 B
510 ug/L9100376-04 MWD-5 1,2,4-Trimethylbenzene *SM6200 B
140 ug/L9100376-04 MWD-5 1,3,5-Trimethylbenzene *SM6200 B
470 ug/L9100376-04 MWD-5 Acetone *SM6200 B
340 ug/L9100376-04 MWD-5 Benzene *SM6200 B
210 ug/L9100376-04 MWD-5 Ethylbenzene *SM6200 B
7.3 ug/L9100376-04 MWD-5 Isopropylbenzene (Cumene)*SM6200 B
1600 ug/L9100376-04 MWD-5 m,p-Xylenes *SM6200 B
320 ug/L9100376-04 MWD-5 Methyl Butyl Ketone (2-Hexanone)*SM6200 B
250 ug/L9100376-04 MWD-5 Methyl Ethyl Ketone (2-Butanone)*SM6200 B
150 ug/L9100376-04 MWD-5 Methyl Isobutyl Ketone *SM6200 B
28 ug/L9100376-04 MWD-5 Methyl-tert-Butyl Ether *SM6200 B
180 ug/L9100376-04 MWD-5 Naphthalene *SM6200 B
18 ug/L9100376-04 MWD-5 n-Propylbenzene *SM6200 B
960 ug/L9100376-04 MWD-5 o-Xylene *SM6200 B
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 3 of 31
Client ID ResultParameterMethod UnitsPrism ID
Prism Work Order: 9100376
10/31/2019
Summary of Detections
2100 ug/L9100376-04 MWD-5 Toluene *SM6200 B
2600 ug/L9100376-04 MWD-5 Xylenes, total *SM6200 B
810 ug/L9100376-05 MW-8 1,2,4-Trimethylbenzene *SM6200 B
200 ug/L9100376-05 MW-8 1,3,5-Trimethylbenzene *SM6200 B
12000 ug/L9100376-05 MW-8 Benzene *SM6200 B
1100 ug/L9100376-05 MW-8 Ethylbenzene *SM6200 B
64 ug/L9100376-05 MW-8 Isopropyl Ether *SM6200 B
4000 ug/L9100376-05 MW-8 m,p-Xylenes *SM6200 B
12000 ug/L9100376-05 MW-8 Methyl-tert-Butyl Ether *SM6200 B
260 ug/L9100376-05 MW-8 Naphthalene *SM6200 B
83 ug/L9100376-05 MW-8 n-Propylbenzene *SM6200 B
1700 ug/L9100376-05 MW-8 o-Xylene *SM6200 B
7800 ug/L9100376-05 MW-8 Toluene *SM6200 B
5700 ug/L9100376-05 MW-8 Xylenes, total *SM6200 B
2.3 ug/L9100376-06 MWD-9 Benzene *SM6200 B
99 ug/L9100376-06 MWD-9 Methyl-tert-Butyl Ether *SM6200 B
1.3 ug/L9100376-07 WSW-2 1,2-Dichloroethane *SM6200 B
0.83 ug/L9100376-07 WSW-2 Isopropyl Ether *SM6200 B
35 ug/L9100376-07 WSW-2 Methyl-tert-Butyl Ether *SM6200 B
14 ug/L9100376-10 WSW-22 Acetone *SM6200 B
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 4 of 31
Laboratory Report
10/31/2019
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117 Project No.:
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-1
Prism Sample ID: 9100376-01
Prism Work Order: 9100376
Time Collected: 10/22/19 12:10
Time Submitted: 10/23/19 17:10
02170214.69
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.111,1,1,2-Tetrachloroethane
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.0611,1,1-Trichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.0361,1,2,2-Tetrachloroethane
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.0661,1,2-Trichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.0831,1-Dichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.0831,1-Dichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.0511,1-Dichloropropylene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.401,2,3-Trichlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.141,2,3-Trichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.131,2,4-Trichlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.0541,2,4-Trimethylbenzene
BRL *SM6200 B P9J050212.0 10/29/19 13:43 KDMug/L 0.171,2-Dibromo-3-chloropropane
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.0511,2-Dibromoethane
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.0761,2-Dichlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.0661,2-Dichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.111,2-Dichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.0761,3,5-Trimethylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.0541,3-Dichlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.0431,3-Dichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.0501,4-Dichlorobenzene
BRL *SM6200 B P9J050212.0 10/29/19 13:43 KDMug/L 0.112,2-Dichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.0662-Chlorotoluene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.0504-Chlorotoluene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.0894-Isopropyltoluene
BRL *SM6200 B P9J050211010/29/19 13:43 KDMug/L 0.31Acetone
4.8 *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.048Benzene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.057Bromobenzene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.14Bromochloromethane
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.062Bromodichloromethane
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.040Bromoform
BRL *SM6200 B P9J050211.0 10/29/19 13:43 KDMug/L 0.18Bromomethane
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.11Carbon Tetrachloride
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.062Chlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.22Chloroethane
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.076Chloroform
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.079Chloromethane
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.056cis-1,2-Dichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.079cis-1,3-Dichloropropylene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.081Dibromochloromethane
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.065Dibromomethane
BRL *SM6200 B P9J050211.0 10/29/19 13:43 KDMug/L 0.11Dichlorodifluoromethane
BRL *SM6200 B P9J0502120010/29/19 13:43 KDMug/L 27Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 5 of 31
Laboratory Report
10/31/2019
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117 Project No.:
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-1
Prism Sample ID: 9100376-01
Prism Work Order: 9100376
Time Collected: 10/22/19 12:10
Time Submitted: 10/23/19 17:10
02170214.69
0.51 *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.061Ethylbenzene
BRL *SM6200 B P9J050212.0 10/29/19 13:43 KDMug/L 0.16Hexachlorobutadiene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.050Isopropyl Ether
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.054Isopropylbenzene (Cumene)
1.6 *SM6200 B P9J050211.0 10/29/19 13:43 KDMug/L 0.12m,p-Xylenes
BRL *SM6200 B P9J050211.0 10/29/19 13:43 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)
BRL *SM6200 B P9J050215.0 10/29/19 13:43 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)
BRL *SM6200 B P9J050211.0 10/29/19 13:43 KDMug/L 0.078Methyl Isobutyl Ketone
BRL *SM6200 B P9J050212.0 10/29/19 13:43 KDMug/L 0.083Methylene Chloride
BRL *SM6200 B P9J050211.0 10/29/19 13:43 KDMug/L 0.042Methyl-tert-Butyl Ether
BRL *SM6200 B P9J050211.0 10/29/19 13:43 KDMug/L 0.19Naphthalene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.076n-Butylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.087n-Propylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.044o-Xylene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.076sec-Butylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.047Styrene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.088tert-Butylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.098Tetrachloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.044Toluene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.070trans-1,2-Dichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.12trans-1,3-Dichloropropylene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.078Trichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.062Trichlorofluoromethane
BRL *SM6200 B P9J050215.0 10/29/19 13:43 KDMug/L 0.060Vinyl acetate
BRL *SM6200 B P9J050210.50 10/29/19 13:43 KDMug/L 0.097Vinyl chloride
1.9 *SM6200 B P9J050211.5 10/29/19 13:43 KDMug/L 0.15Xylenes, total
Surrogate Recovery Control Limits
70-13099 %4-Bromofluorobenzene
70-130109 %Dibromofluoromethane
70-13099 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 6 of 31
Laboratory Report
10/31/2019
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117 Project No.:
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-3R
Prism Sample ID: 9100376-02
Prism Work Order: 9100376
Time Collected: 10/22/19 09:50
Time Submitted: 10/23/19 17:10
02170214.69
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 111,1,1,2-Tetrachloroethane
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 6.11,1,1-Trichloroethane
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 3.61,1,2,2-Tetrachloroethane
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 6.61,1,2-Trichloroethane
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 8.31,1-Dichloroethane
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 8.31,1-Dichloroethylene
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 5.11,1-Dichloropropylene
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 401,2,3-Trichlorobenzene
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 141,2,3-Trichloropropane
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 131,2,4-Trichlorobenzene
2900 *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 5.41,2,4-Trimethylbenzene
BRL *SM6200 B P9J050210020010/29/19 20:29 KDMug/L 171,2-Dibromo-3-chloropropane
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 5.11,2-Dibromoethane
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 7.61,2-Dichlorobenzene
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 6.61,2-Dichloroethane
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 111,2-Dichloropropane
800 *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 7.61,3,5-Trimethylbenzene
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 5.41,3-Dichlorobenzene
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 4.31,3-Dichloropropane
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 5.01,4-Dichlorobenzene
BRL *SM6200 B P9J050210020010/29/19 20:29 KDMug/L 112,2-Dichloropropane
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 6.62-Chlorotoluene
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 5.04-Chlorotoluene
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 8.94-Isopropyltoluene
BRL *SM6200 B P9J0502100100010/29/19 20:29 KDMug/L 31Acetone
4900 *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 4.8Benzene
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 5.7Bromobenzene
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 14Bromochloromethane
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 6.2Bromodichloromethane
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 4.0Bromoform
BRL *SM6200 B P9J050210010010/29/19 20:29 KDMug/L 18Bromomethane
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 11Carbon Tetrachloride
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 6.2Chlorobenzene
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 22Chloroethane
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 7.6Chloroform
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 7.9Chloromethane
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 5.6cis-1,2-Dichloroethylene
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 7.9cis-1,3-Dichloropropylene
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 8.1Dibromochloromethane
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 6.5Dibromomethane
BRL *SM6200 B P9J050210010010/29/19 20:29 KDMug/L 11Dichlorodifluoromethane
BRL *SM6200 B P9J05021002000010/29/19 20:29 KDMug/L 2700Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 7 of 31
Laboratory Report
10/31/2019
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117 Project No.:
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-3R
Prism Sample ID: 9100376-02
Prism Work Order: 9100376
Time Collected: 10/22/19 09:50
Time Submitted: 10/23/19 17:10
02170214.69
3400 *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 6.1Ethylbenzene
BRL *SM6200 B P9J050210020010/29/19 20:29 KDMug/L 16Hexachlorobutadiene
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 5.0Isopropyl Ether
110 *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 5.4Isopropylbenzene (Cumene)
13000 *SM6200 B P9J050210010010/29/19 20:29 KDMug/L 12m,p-Xylenes
400 *SM6200 B P9J050210010010/29/19 20:29 KDMug/L 6.5Methyl Butyl Ketone (2-Hexanone)
BRL *SM6200 B P9J050210050010/29/19 20:29 KDMug/L 24Methyl Ethyl Ketone (2-Butanone)
BRL *SM6200 B P9J050210010010/29/19 20:29 KDMug/L 7.8Methyl Isobutyl Ketone
BRL *SM6200 B P9J050210020010/29/19 20:29 KDMug/L 8.3Methylene Chloride
2000 *SM6200 B P9J050210010010/29/19 20:29 KDMug/L 4.2Methyl-tert-Butyl Ether
760 *SM6200 B P9J050210010010/29/19 20:29 KDMug/L 19Naphthalene
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 7.6n-Butylbenzene
320 *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 8.7n-Propylbenzene
6400 *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 4.4o-Xylene
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 7.6sec-Butylbenzene
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 4.7Styrene
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 8.8tert-Butylbenzene
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 9.8Tetrachloroethylene
29000 *SM6200 B P9J0502100050010/29/19 21:03 KDMug/L 44Toluene
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 7.0trans-1,2-Dichloroethylene
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 12trans-1,3-Dichloropropylene
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 7.8Trichloroethylene
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 6.2Trichlorofluoromethane
BRL *SM6200 B P9J050210050010/29/19 20:29 KDMug/L 6.0Vinyl acetate
BRL *SM6200 B P9J05021005010/29/19 20:29 KDMug/L 9.7Vinyl chloride
19000 *SM6200 B P9J050210015010/29/19 20:29 KDMug/L 15Xylenes, total
Surrogate Recovery Control Limits
70-13097 %4-Bromofluorobenzene
70-130105 %Dibromofluoromethane
70-13097 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 8 of 31
Laboratory Report
10/31/2019
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117 Project No.:
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-4
Prism Sample ID: 9100376-03
Prism Work Order: 9100376
Time Collected: 10/22/19 11:20
Time Submitted: 10/23/19 17:10
02170214.69
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 111,1,1,2-Tetrachloroethane
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 6.11,1,1-Trichloroethane
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 3.61,1,2,2-Tetrachloroethane
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 6.61,1,2-Trichloroethane
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 8.31,1-Dichloroethane
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 8.31,1-Dichloroethylene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 5.11,1-Dichloropropylene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 401,2,3-Trichlorobenzene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 141,2,3-Trichloropropane
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 131,2,4-Trichlorobenzene
670 *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 5.41,2,4-Trimethylbenzene
BRL *SM6200 B P9J050210020010/29/19 18:48 KDMug/L 171,2-Dibromo-3-chloropropane
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 5.11,2-Dibromoethane
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 7.61,2-Dichlorobenzene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 6.61,2-Dichloroethane
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 111,2-Dichloropropane
220 *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 7.61,3,5-Trimethylbenzene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 5.41,3-Dichlorobenzene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 4.31,3-Dichloropropane
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 5.01,4-Dichlorobenzene
BRL *SM6200 B P9J050210020010/29/19 18:48 KDMug/L 112,2-Dichloropropane
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 6.62-Chlorotoluene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 5.04-Chlorotoluene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 8.94-Isopropyltoluene
1200 *SM6200 B P9J0502100100010/29/19 18:48 KDMug/L 31Acetone
1000 *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 4.8Benzene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 5.7Bromobenzene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 14Bromochloromethane
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 6.2Bromodichloromethane
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 4.0Bromoform
BRL *SM6200 B P9J050210010010/29/19 18:48 KDMug/L 18Bromomethane
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 11Carbon Tetrachloride
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 6.2Chlorobenzene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 22Chloroethane
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 7.6Chloroform
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 7.9Chloromethane
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 5.6cis-1,2-Dichloroethylene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 7.9cis-1,3-Dichloropropylene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 8.1Dibromochloromethane
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 6.5Dibromomethane
BRL *SM6200 B P9J050210010010/29/19 18:48 KDMug/L 11Dichlorodifluoromethane
BRL *SM6200 B P9J05021002000010/29/19 18:48 KDMug/L 2700Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 9 of 31
Laboratory Report
10/31/2019
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117 Project No.:
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-4
Prism Sample ID: 9100376-03
Prism Work Order: 9100376
Time Collected: 10/22/19 11:20
Time Submitted: 10/23/19 17:10
02170214.69
340 *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 6.1Ethylbenzene
BRL *SM6200 B P9J050210020010/29/19 18:48 KDMug/L 16Hexachlorobutadiene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 5.0Isopropyl Ether
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 5.4Isopropylbenzene (Cumene)
3100 *SM6200 B P9J050210010010/29/19 18:48 KDMug/L 12m,p-Xylenes
290 *SM6200 B P9J050210010010/29/19 18:48 KDMug/L 6.5Methyl Butyl Ketone (2-Hexanone)
680 *SM6200 B P9J050210050010/29/19 18:48 KDMug/L 24Methyl Ethyl Ketone (2-Butanone)
180 *SM6200 B P9J050210010010/29/19 18:48 KDMug/L 7.8Methyl Isobutyl Ketone
BRL *SM6200 B P9J050210020010/29/19 18:48 KDMug/L 8.3Methylene Chloride
BRL *SM6200 B P9J050210010010/29/19 18:48 KDMug/L 4.2Methyl-tert-Butyl Ether
160 *SM6200 B P9J050210010010/29/19 18:48 KDMug/L 19Naphthalene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 7.6n-Butylbenzene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 8.7n-Propylbenzene
1900 *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 4.4o-Xylene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 7.6sec-Butylbenzene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 4.7Styrene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 8.8tert-Butylbenzene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 9.8Tetrachloroethylene
5000 *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 4.4Toluene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 7.0trans-1,2-Dichloroethylene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 12trans-1,3-Dichloropropylene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 7.8Trichloroethylene
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 6.2Trichlorofluoromethane
BRL *SM6200 B P9J050210050010/29/19 18:48 KDMug/L 6.0Vinyl acetate
BRL *SM6200 B P9J05021005010/29/19 18:48 KDMug/L 9.7Vinyl chloride
5000 *SM6200 B P9J050210015010/29/19 18:48 KDMug/L 15Xylenes, total
Surrogate Recovery Control Limits
70-13098 %4-Bromofluorobenzene
70-130106 %Dibromofluoromethane
70-13097 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 10 of 31
Laboratory Report
10/31/2019
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117 Project No.:
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MWD-5
Prism Sample ID: 9100376-04
Prism Work Order: 9100376
Time Collected: 10/22/19 11:00
Time Submitted: 10/23/19 17:10
02170214.69
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 1.11,1,1,2-Tetrachloroethane
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.611,1,1-Trichloroethane
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.361,1,2,2-Tetrachloroethane
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.661,1,2-Trichloroethane
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.831,1-Dichloroethane
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.831,1-Dichloroethylene
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.511,1-Dichloropropylene
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 4.01,2,3-Trichlorobenzene
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 1.41,2,3-Trichloropropane
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 1.31,2,4-Trichlorobenzene
510 *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.541,2,4-Trimethylbenzene
BRL *SM6200 B P9J0502102010/29/19 19:22 KDMug/L 1.71,2-Dibromo-3-chloropropane
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.511,2-Dibromoethane
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.761,2-Dichlorobenzene
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.661,2-Dichloroethane
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 1.11,2-Dichloropropane
140 *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.761,3,5-Trimethylbenzene
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.541,3-Dichlorobenzene
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.431,3-Dichloropropane
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.501,4-Dichlorobenzene
BRL *SM6200 B P9J0502102010/29/19 19:22 KDMug/L 1.12,2-Dichloropropane
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.662-Chlorotoluene
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.504-Chlorotoluene
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.894-Isopropyltoluene
470 *SM6200 B P9J05021010010/29/19 19:22 KDMug/L 3.1Acetone
340 *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.48Benzene
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.57Bromobenzene
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 1.4Bromochloromethane
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.62Bromodichloromethane
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.40Bromoform
BRL *SM6200 B P9J0502101010/29/19 19:22 KDMug/L 1.8Bromomethane
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 1.1Carbon Tetrachloride
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.62Chlorobenzene
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 2.2Chloroethane
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.76Chloroform
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.79Chloromethane
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.56cis-1,2-Dichloroethylene
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.79cis-1,3-Dichloropropylene
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.81Dibromochloromethane
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.65Dibromomethane
BRL *SM6200 B P9J0502101010/29/19 19:22 KDMug/L 1.1Dichlorodifluoromethane
BRL *SM6200 B P9J050210200010/29/19 19:22 KDMug/L 270Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 11 of 31
Laboratory Report
10/31/2019
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117 Project No.:
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MWD-5
Prism Sample ID: 9100376-04
Prism Work Order: 9100376
Time Collected: 10/22/19 11:00
Time Submitted: 10/23/19 17:10
02170214.69
210 *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.61Ethylbenzene
BRL *SM6200 B P9J0502102010/29/19 19:22 KDMug/L 1.6Hexachlorobutadiene
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.50Isopropyl Ether
7.3 *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.54Isopropylbenzene (Cumene)
1600 *SM6200 B P9J0502101010/29/19 19:22 KDMug/L 1.2m,p-Xylenes
320 *SM6200 B P9J0502101010/29/19 19:22 KDMug/L 0.65Methyl Butyl Ketone (2-Hexanone)
250 *SM6200 B P9J0502105010/29/19 19:22 KDMug/L 2.4Methyl Ethyl Ketone (2-Butanone)
150 *SM6200 B P9J0502101010/29/19 19:22 KDMug/L 0.78Methyl Isobutyl Ketone
BRL *SM6200 B P9J0502102010/29/19 19:22 KDMug/L 0.83Methylene Chloride
28 *SM6200 B P9J0502101010/29/19 19:22 KDMug/L 0.42Methyl-tert-Butyl Ether
180 *SM6200 B P9J0502101010/29/19 19:22 KDMug/L 1.9Naphthalene
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.76n-Butylbenzene
18 *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.87n-Propylbenzene
960 *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.44o-Xylene
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.76sec-Butylbenzene
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.47Styrene
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.88tert-Butylbenzene
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.98Tetrachloroethylene
2100 *SM6200 B P9J05021005010/29/19 19:55 KDMug/L 4.4Toluene
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.70trans-1,2-Dichloroethylene
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 1.2trans-1,3-Dichloropropylene
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.78Trichloroethylene
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.62Trichlorofluoromethane
BRL *SM6200 B P9J0502105010/29/19 19:22 KDMug/L 0.60Vinyl acetate
BRL *SM6200 B P9J0502105.0 10/29/19 19:22 KDMug/L 0.97Vinyl chloride
2600 *SM6200 B P9J0502101510/29/19 19:22 KDMug/L 1.5Xylenes, total
Surrogate Recovery Control Limits
70-13095 %4-Bromofluorobenzene
70-130108 %Dibromofluoromethane
70-13097 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 12 of 31
Laboratory Report
10/31/2019
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117 Project No.:
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-8
Prism Sample ID: 9100376-05
Prism Work Order: 9100376
Time Collected: 10/22/19 11:50
Time Submitted: 10/23/19 17:10
02170214.69
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 111,1,1,2-Tetrachloroethane
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 6.11,1,1-Trichloroethane
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 3.61,1,2,2-Tetrachloroethane
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 6.61,1,2-Trichloroethane
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 8.31,1-Dichloroethane
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 8.31,1-Dichloroethylene
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 5.11,1-Dichloropropylene
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 401,2,3-Trichlorobenzene
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 141,2,3-Trichloropropane
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 131,2,4-Trichlorobenzene
810 *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 5.41,2,4-Trimethylbenzene
BRL *SM6200 B P9J050210020010/29/19 21:37 KDMug/L 171,2-Dibromo-3-chloropropane
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 5.11,2-Dibromoethane
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 7.61,2-Dichlorobenzene
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 6.61,2-Dichloroethane
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 111,2-Dichloropropane
200 *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 7.61,3,5-Trimethylbenzene
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 5.41,3-Dichlorobenzene
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 4.31,3-Dichloropropane
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 5.01,4-Dichlorobenzene
BRL *SM6200 B P9J050210020010/29/19 21:37 KDMug/L 112,2-Dichloropropane
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 6.62-Chlorotoluene
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 5.04-Chlorotoluene
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 8.94-Isopropyltoluene
BRL *SM6200 B P9J0502100100010/29/19 21:37 KDMug/L 31Acetone
12000 *SM6200 B P9J0502100050010/29/19 22:10 KDMug/L 48Benzene
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 5.7Bromobenzene
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 14Bromochloromethane
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 6.2Bromodichloromethane
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 4.0Bromoform
BRL *SM6200 B P9J050210010010/29/19 21:37 KDMug/L 18Bromomethane
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 11Carbon Tetrachloride
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 6.2Chlorobenzene
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 22Chloroethane
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 7.6Chloroform
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 7.9Chloromethane
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 5.6cis-1,2-Dichloroethylene
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 7.9cis-1,3-Dichloropropylene
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 8.1Dibromochloromethane
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 6.5Dibromomethane
BRL *SM6200 B P9J050210010010/29/19 21:37 KDMug/L 11Dichlorodifluoromethane
BRL *SM6200 B P9J05021002000010/29/19 21:37 KDMug/L 2700Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 13 of 31
Laboratory Report
10/31/2019
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117 Project No.:
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-8
Prism Sample ID: 9100376-05
Prism Work Order: 9100376
Time Collected: 10/22/19 11:50
Time Submitted: 10/23/19 17:10
02170214.69
1100 *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 6.1Ethylbenzene
BRL *SM6200 B P9J050210020010/29/19 21:37 KDMug/L 16Hexachlorobutadiene
64 *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 5.0Isopropyl Ether
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 5.4Isopropylbenzene (Cumene)
4000 *SM6200 B P9J050210010010/29/19 21:37 KDMug/L 12m,p-Xylenes
BRL *SM6200 B P9J050210010010/29/19 21:37 KDMug/L 6.5Methyl Butyl Ketone (2-Hexanone)
BRL *SM6200 B P9J050210050010/29/19 21:37 KDMug/L 24Methyl Ethyl Ketone (2-Butanone)
BRL *SM6200 B P9J050210010010/29/19 21:37 KDMug/L 7.8Methyl Isobutyl Ketone
BRL *SM6200 B P9J050210020010/29/19 21:37 KDMug/L 8.3Methylene Chloride
12000 *SM6200 B P9J05021000100010/29/19 22:10 KDMug/L 42Methyl-tert-Butyl Ether
260 *SM6200 B P9J050210010010/29/19 21:37 KDMug/L 19Naphthalene
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 7.6n-Butylbenzene
83 *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 8.7n-Propylbenzene
1700 *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 4.4o-Xylene
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 7.6sec-Butylbenzene
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 4.7Styrene
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 8.8tert-Butylbenzene
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 9.8Tetrachloroethylene
7800 *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 4.4Toluene
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 7.0trans-1,2-Dichloroethylene
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 12trans-1,3-Dichloropropylene
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 7.8Trichloroethylene
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 6.2Trichlorofluoromethane
BRL *SM6200 B P9J050210050010/29/19 21:37 KDMug/L 6.0Vinyl acetate
BRL *SM6200 B P9J05021005010/29/19 21:37 KDMug/L 9.7Vinyl chloride
5700 *SM6200 B P9J050210015010/29/19 21:37 KDMug/L 15Xylenes, total
Surrogate Recovery Control Limits
70-13097 %4-Bromofluorobenzene
70-130105 %Dibromofluoromethane
70-13097 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 14 of 31
Laboratory Report
10/31/2019
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117 Project No.:
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MWD-9
Prism Sample ID: 9100376-06
Prism Work Order: 9100376
Time Collected: 10/22/19 10:30
Time Submitted: 10/23/19 17:10
02170214.69
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.111,1,1,2-Tetrachloroethane
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.0611,1,1-Trichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.0361,1,2,2-Tetrachloroethane
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.0661,1,2-Trichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.0831,1-Dichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.0831,1-Dichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.0511,1-Dichloropropylene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.401,2,3-Trichlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.141,2,3-Trichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.131,2,4-Trichlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.0541,2,4-Trimethylbenzene
BRL *SM6200 B P9J050212.0 10/29/19 14:17 KDMug/L 0.171,2-Dibromo-3-chloropropane
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.0511,2-Dibromoethane
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.0761,2-Dichlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.0661,2-Dichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.111,2-Dichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.0761,3,5-Trimethylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.0541,3-Dichlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.0431,3-Dichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.0501,4-Dichlorobenzene
BRL *SM6200 B P9J050212.0 10/29/19 14:17 KDMug/L 0.112,2-Dichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.0662-Chlorotoluene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.0504-Chlorotoluene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.0894-Isopropyltoluene
BRL *SM6200 B P9J050211010/29/19 14:17 KDMug/L 0.31Acetone
2.3 *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.048Benzene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.057Bromobenzene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.14Bromochloromethane
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.062Bromodichloromethane
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.040Bromoform
BRL *SM6200 B P9J050211.0 10/29/19 14:17 KDMug/L 0.18Bromomethane
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.11Carbon Tetrachloride
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.062Chlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.22Chloroethane
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.076Chloroform
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.079Chloromethane
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.056cis-1,2-Dichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.079cis-1,3-Dichloropropylene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.081Dibromochloromethane
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.065Dibromomethane
BRL *SM6200 B P9J050211.0 10/29/19 14:17 KDMug/L 0.11Dichlorodifluoromethane
BRL *SM6200 B P9J0502120010/29/19 14:17 KDMug/L 27Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 15 of 31
Laboratory Report
10/31/2019
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117 Project No.:
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MWD-9
Prism Sample ID: 9100376-06
Prism Work Order: 9100376
Time Collected: 10/22/19 10:30
Time Submitted: 10/23/19 17:10
02170214.69
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.061Ethylbenzene
BRL *SM6200 B P9J050212.0 10/29/19 14:17 KDMug/L 0.16Hexachlorobutadiene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.050Isopropyl Ether
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.054Isopropylbenzene (Cumene)
BRL *SM6200 B P9J050211.0 10/29/19 14:17 KDMug/L 0.12m,p-Xylenes
BRL *SM6200 B P9J050211.0 10/29/19 14:17 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)
BRL *SM6200 B P9J050215.0 10/29/19 14:17 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)
BRL *SM6200 B P9J050211.0 10/29/19 14:17 KDMug/L 0.078Methyl Isobutyl Ketone
BRL *SM6200 B P9J050212.0 10/29/19 14:17 KDMug/L 0.083Methylene Chloride
99 *SM6200 B P9J050211.0 10/29/19 14:17 KDMug/L 0.042Methyl-tert-Butyl Ether
BRL *SM6200 B P9J050211.0 10/29/19 14:17 KDMug/L 0.19Naphthalene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.076n-Butylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.087n-Propylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.044o-Xylene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.076sec-Butylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.047Styrene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.088tert-Butylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.098Tetrachloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.044Toluene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.070trans-1,2-Dichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.12trans-1,3-Dichloropropylene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.078Trichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.062Trichlorofluoromethane
BRL *SM6200 B P9J050215.0 10/29/19 14:17 KDMug/L 0.060Vinyl acetate
BRL *SM6200 B P9J050210.50 10/29/19 14:17 KDMug/L 0.097Vinyl chloride
BRL *SM6200 B P9J050211.5 10/29/19 14:17 KDMug/L 0.15Xylenes, total
Surrogate Recovery Control Limits
70-13099 %4-Bromofluorobenzene
70-130107 %Dibromofluoromethane
70-13098 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 16 of 31
Laboratory Report
10/31/2019
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117 Project No.:
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: WSW-2
Prism Sample ID: 9100376-07
Prism Work Order: 9100376
Time Collected: 10/22/19 12:25
Time Submitted: 10/23/19 17:10
02170214.69
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.111,1,1,2-Tetrachloroethane
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.0611,1,1-Trichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.0361,1,2,2-Tetrachloroethane
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.0661,1,2-Trichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.0831,1-Dichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.0831,1-Dichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.0511,1-Dichloropropylene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.401,2,3-Trichlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.141,2,3-Trichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.131,2,4-Trichlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.0541,2,4-Trimethylbenzene
BRL *SM6200 B P9J050212.0 10/29/19 14:51 KDMug/L 0.171,2-Dibromo-3-chloropropane
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.0511,2-Dibromoethane
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.0761,2-Dichlorobenzene
1.3 *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.0661,2-Dichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.111,2-Dichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.0761,3,5-Trimethylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.0541,3-Dichlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.0431,3-Dichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.0501,4-Dichlorobenzene
BRL *SM6200 B P9J050212.0 10/29/19 14:51 KDMug/L 0.112,2-Dichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.0662-Chlorotoluene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.0504-Chlorotoluene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.0894-Isopropyltoluene
BRL *SM6200 B P9J050211010/29/19 14:51 KDMug/L 0.31Acetone
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.048Benzene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.057Bromobenzene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.14Bromochloromethane
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.062Bromodichloromethane
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.040Bromoform
BRL *SM6200 B P9J050211.0 10/29/19 14:51 KDMug/L 0.18Bromomethane
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.11Carbon Tetrachloride
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.062Chlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.22Chloroethane
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.076Chloroform
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.079Chloromethane
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.056cis-1,2-Dichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.079cis-1,3-Dichloropropylene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.081Dibromochloromethane
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.065Dibromomethane
BRL *SM6200 B P9J050211.0 10/29/19 14:51 KDMug/L 0.11Dichlorodifluoromethane
BRL *SM6200 B P9J0502120010/29/19 14:51 KDMug/L 27Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 17 of 31
Laboratory Report
10/31/2019
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117 Project No.:
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: WSW-2
Prism Sample ID: 9100376-07
Prism Work Order: 9100376
Time Collected: 10/22/19 12:25
Time Submitted: 10/23/19 17:10
02170214.69
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.061Ethylbenzene
BRL *SM6200 B P9J050212.0 10/29/19 14:51 KDMug/L 0.16Hexachlorobutadiene
0.83 *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.050Isopropyl Ether
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.054Isopropylbenzene (Cumene)
BRL *SM6200 B P9J050211.0 10/29/19 14:51 KDMug/L 0.12m,p-Xylenes
BRL *SM6200 B P9J050211.0 10/29/19 14:51 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)
BRL *SM6200 B P9J050215.0 10/29/19 14:51 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)
BRL *SM6200 B P9J050211.0 10/29/19 14:51 KDMug/L 0.078Methyl Isobutyl Ketone
BRL *SM6200 B P9J050212.0 10/29/19 14:51 KDMug/L 0.083Methylene Chloride
35 *SM6200 B P9J050211.0 10/29/19 14:51 KDMug/L 0.042Methyl-tert-Butyl Ether
BRL *SM6200 B P9J050211.0 10/29/19 14:51 KDMug/L 0.19Naphthalene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.076n-Butylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.087n-Propylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.044o-Xylene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.076sec-Butylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.047Styrene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.088tert-Butylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.098Tetrachloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.044Toluene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.070trans-1,2-Dichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.12trans-1,3-Dichloropropylene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.078Trichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.062Trichlorofluoromethane
BRL *SM6200 B P9J050215.0 10/29/19 14:51 KDMug/L 0.060Vinyl acetate
BRL *SM6200 B P9J050210.50 10/29/19 14:51 KDMug/L 0.097Vinyl chloride
BRL *SM6200 B P9J050211.5 10/29/19 14:51 KDMug/L 0.15Xylenes, total
Surrogate Recovery Control Limits
70-13096 %4-Bromofluorobenzene
70-130108 %Dibromofluoromethane
70-13099 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 18 of 31
Laboratory Report
10/31/2019
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117 Project No.:
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: WSW-20
Prism Sample ID: 9100376-08
Prism Work Order: 9100376
Time Collected: 10/22/19 12:50
Time Submitted: 10/23/19 17:10
02170214.69
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.111,1,1,2-Tetrachloroethane
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.0611,1,1-Trichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.0361,1,2,2-Tetrachloroethane
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.0661,1,2-Trichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.0831,1-Dichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.0831,1-Dichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.0511,1-Dichloropropylene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.401,2,3-Trichlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.141,2,3-Trichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.131,2,4-Trichlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.0541,2,4-Trimethylbenzene
BRL *SM6200 B P9J050212.0 10/29/19 15:25 KDMug/L 0.171,2-Dibromo-3-chloropropane
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.0511,2-Dibromoethane
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.0761,2-Dichlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.0661,2-Dichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.111,2-Dichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.0761,3,5-Trimethylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.0541,3-Dichlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.0431,3-Dichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.0501,4-Dichlorobenzene
BRL *SM6200 B P9J050212.0 10/29/19 15:25 KDMug/L 0.112,2-Dichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.0662-Chlorotoluene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.0504-Chlorotoluene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.0894-Isopropyltoluene
BRL *SM6200 B P9J050211010/29/19 15:25 KDMug/L 0.31Acetone
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.048Benzene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.057Bromobenzene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.14Bromochloromethane
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.062Bromodichloromethane
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.040Bromoform
BRL *SM6200 B P9J050211.0 10/29/19 15:25 KDMug/L 0.18Bromomethane
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.11Carbon Tetrachloride
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.062Chlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.22Chloroethane
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.076Chloroform
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.079Chloromethane
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.056cis-1,2-Dichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.079cis-1,3-Dichloropropylene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.081Dibromochloromethane
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.065Dibromomethane
BRL *SM6200 B P9J050211.0 10/29/19 15:25 KDMug/L 0.11Dichlorodifluoromethane
BRL *SM6200 B P9J0502120010/29/19 15:25 KDMug/L 27Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 19 of 31
Laboratory Report
10/31/2019
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117 Project No.:
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: WSW-20
Prism Sample ID: 9100376-08
Prism Work Order: 9100376
Time Collected: 10/22/19 12:50
Time Submitted: 10/23/19 17:10
02170214.69
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.061Ethylbenzene
BRL *SM6200 B P9J050212.0 10/29/19 15:25 KDMug/L 0.16Hexachlorobutadiene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.050Isopropyl Ether
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.054Isopropylbenzene (Cumene)
BRL *SM6200 B P9J050211.0 10/29/19 15:25 KDMug/L 0.12m,p-Xylenes
BRL *SM6200 B P9J050211.0 10/29/19 15:25 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)
BRL *SM6200 B P9J050215.0 10/29/19 15:25 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)
BRL *SM6200 B P9J050211.0 10/29/19 15:25 KDMug/L 0.078Methyl Isobutyl Ketone
BRL *SM6200 B P9J050212.0 10/29/19 15:25 KDMug/L 0.083Methylene Chloride
BRL *SM6200 B P9J050211.0 10/29/19 15:25 KDMug/L 0.042Methyl-tert-Butyl Ether
BRL *SM6200 B P9J050211.0 10/29/19 15:25 KDMug/L 0.19Naphthalene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.076n-Butylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.087n-Propylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.044o-Xylene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.076sec-Butylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.047Styrene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.088tert-Butylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.098Tetrachloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.044Toluene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.070trans-1,2-Dichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.12trans-1,3-Dichloropropylene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.078Trichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.062Trichlorofluoromethane
BRL *SM6200 B P9J050215.0 10/29/19 15:25 KDMug/L 0.060Vinyl acetate
BRL *SM6200 B P9J050210.50 10/29/19 15:25 KDMug/L 0.097Vinyl chloride
BRL *SM6200 B P9J050211.5 10/29/19 15:25 KDMug/L 0.15Xylenes, total
Surrogate Recovery Control Limits
70-13097 %4-Bromofluorobenzene
70-130107 %Dibromofluoromethane
70-13099 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 20 of 31
Laboratory Report
10/31/2019
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117 Project No.:
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: WSW-21
Prism Sample ID: 9100376-09
Prism Work Order: 9100376
Time Collected: 10/22/19 12:55
Time Submitted: 10/23/19 17:10
02170214.69
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.111,1,1,2-Tetrachloroethane
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.0611,1,1-Trichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.0361,1,2,2-Tetrachloroethane
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.0661,1,2-Trichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.0831,1-Dichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.0831,1-Dichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.0511,1-Dichloropropylene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.401,2,3-Trichlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.141,2,3-Trichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.131,2,4-Trichlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.0541,2,4-Trimethylbenzene
BRL *SM6200 B P9J050212.0 10/29/19 15:59 KDMug/L 0.171,2-Dibromo-3-chloropropane
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.0511,2-Dibromoethane
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.0761,2-Dichlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.0661,2-Dichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.111,2-Dichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.0761,3,5-Trimethylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.0541,3-Dichlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.0431,3-Dichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.0501,4-Dichlorobenzene
BRL *SM6200 B P9J050212.0 10/29/19 15:59 KDMug/L 0.112,2-Dichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.0662-Chlorotoluene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.0504-Chlorotoluene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.0894-Isopropyltoluene
BRL *SM6200 B P9J050211010/29/19 15:59 KDMug/L 0.31Acetone
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.048Benzene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.057Bromobenzene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.14Bromochloromethane
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.062Bromodichloromethane
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.040Bromoform
BRL *SM6200 B P9J050211.0 10/29/19 15:59 KDMug/L 0.18Bromomethane
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.11Carbon Tetrachloride
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.062Chlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.22Chloroethane
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.076Chloroform
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.079Chloromethane
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.056cis-1,2-Dichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.079cis-1,3-Dichloropropylene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.081Dibromochloromethane
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.065Dibromomethane
BRL *SM6200 B P9J050211.0 10/29/19 15:59 KDMug/L 0.11Dichlorodifluoromethane
BRL *SM6200 B P9J0502120010/29/19 15:59 KDMug/L 27Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 21 of 31
Laboratory Report
10/31/2019
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117 Project No.:
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: WSW-21
Prism Sample ID: 9100376-09
Prism Work Order: 9100376
Time Collected: 10/22/19 12:55
Time Submitted: 10/23/19 17:10
02170214.69
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.061Ethylbenzene
BRL *SM6200 B P9J050212.0 10/29/19 15:59 KDMug/L 0.16Hexachlorobutadiene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.050Isopropyl Ether
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.054Isopropylbenzene (Cumene)
BRL *SM6200 B P9J050211.0 10/29/19 15:59 KDMug/L 0.12m,p-Xylenes
BRL *SM6200 B P9J050211.0 10/29/19 15:59 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)
BRL *SM6200 B P9J050215.0 10/29/19 15:59 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)
BRL *SM6200 B P9J050211.0 10/29/19 15:59 KDMug/L 0.078Methyl Isobutyl Ketone
BRL *SM6200 B P9J050212.0 10/29/19 15:59 KDMug/L 0.083Methylene Chloride
BRL *SM6200 B P9J050211.0 10/29/19 15:59 KDMug/L 0.042Methyl-tert-Butyl Ether
BRL *SM6200 B P9J050211.0 10/29/19 15:59 KDMug/L 0.19Naphthalene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.076n-Butylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.087n-Propylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.044o-Xylene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.076sec-Butylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.047Styrene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.088tert-Butylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.098Tetrachloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.044Toluene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.070trans-1,2-Dichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.12trans-1,3-Dichloropropylene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.078Trichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.062Trichlorofluoromethane
BRL *SM6200 B P9J050215.0 10/29/19 15:59 KDMug/L 0.060Vinyl acetate
BRL *SM6200 B P9J050210.50 10/29/19 15:59 KDMug/L 0.097Vinyl chloride
BRL *SM6200 B P9J050211.5 10/29/19 15:59 KDMug/L 0.15Xylenes, total
Surrogate Recovery Control Limits
70-13095 %4-Bromofluorobenzene
70-130105 %Dibromofluoromethane
70-13097 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 22 of 31
Laboratory Report
10/31/2019
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117 Project No.:
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: WSW-22
Prism Sample ID: 9100376-10
Prism Work Order: 9100376
Time Collected: 10/22/19 13:10
Time Submitted: 10/23/19 17:10
02170214.69
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.111,1,1,2-Tetrachloroethane
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.0611,1,1-Trichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.0361,1,2,2-Tetrachloroethane
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.0661,1,2-Trichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.0831,1-Dichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.0831,1-Dichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.0511,1-Dichloropropylene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.401,2,3-Trichlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.141,2,3-Trichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.131,2,4-Trichlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.0541,2,4-Trimethylbenzene
BRL *SM6200 B P9J050212.0 10/29/19 16:33 KDMug/L 0.171,2-Dibromo-3-chloropropane
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.0511,2-Dibromoethane
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.0761,2-Dichlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.0661,2-Dichloroethane
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.111,2-Dichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.0761,3,5-Trimethylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.0541,3-Dichlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.0431,3-Dichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.0501,4-Dichlorobenzene
BRL *SM6200 B P9J050212.0 10/29/19 16:33 KDMug/L 0.112,2-Dichloropropane
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.0662-Chlorotoluene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.0504-Chlorotoluene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.0894-Isopropyltoluene
14 *SM6200 B P9J050211010/29/19 16:33 KDMug/L 0.31Acetone
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.048Benzene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.057Bromobenzene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.14Bromochloromethane
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.062Bromodichloromethane
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.040Bromoform
BRL *SM6200 B P9J050211.0 10/29/19 16:33 KDMug/L 0.18Bromomethane
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.11Carbon Tetrachloride
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.062Chlorobenzene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.22Chloroethane
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.076Chloroform
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.079Chloromethane
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.056cis-1,2-Dichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.079cis-1,3-Dichloropropylene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.081Dibromochloromethane
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.065Dibromomethane
BRL *SM6200 B P9J050211.0 10/29/19 16:33 KDMug/L 0.11Dichlorodifluoromethane
BRL *SM6200 B P9J0502120010/29/19 16:33 KDMug/L 27Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 23 of 31
Laboratory Report
10/31/2019
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117 Project No.:
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: WSW-22
Prism Sample ID: 9100376-10
Prism Work Order: 9100376
Time Collected: 10/22/19 13:10
Time Submitted: 10/23/19 17:10
02170214.69
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.061Ethylbenzene
BRL *SM6200 B P9J050212.0 10/29/19 16:33 KDMug/L 0.16Hexachlorobutadiene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.050Isopropyl Ether
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.054Isopropylbenzene (Cumene)
BRL *SM6200 B P9J050211.0 10/29/19 16:33 KDMug/L 0.12m,p-Xylenes
BRL *SM6200 B P9J050211.0 10/29/19 16:33 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)
BRL *SM6200 B P9J050215.0 10/29/19 16:33 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)
BRL *SM6200 B P9J050211.0 10/29/19 16:33 KDMug/L 0.078Methyl Isobutyl Ketone
BRL *SM6200 B P9J050212.0 10/29/19 16:33 KDMug/L 0.083Methylene Chloride
BRL *SM6200 B P9J050211.0 10/29/19 16:33 KDMug/L 0.042Methyl-tert-Butyl Ether
BRL *SM6200 B P9J050211.0 10/29/19 16:33 KDMug/L 0.19Naphthalene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.076n-Butylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.087n-Propylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.044o-Xylene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.076sec-Butylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.047Styrene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.088tert-Butylbenzene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.098Tetrachloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.044Toluene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.070trans-1,2-Dichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.12trans-1,3-Dichloropropylene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.078Trichloroethylene
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.062Trichlorofluoromethane
BRL *SM6200 B P9J050215.0 10/29/19 16:33 KDMug/L 0.060Vinyl acetate
BRL *SM6200 B P9J050210.50 10/29/19 16:33 KDMug/L 0.097Vinyl chloride
BRL *SM6200 B P9J050211.5 10/29/19 16:33 KDMug/L 0.15Xylenes, total
Surrogate Recovery Control Limits
70-13095 %4-Bromofluorobenzene
70-130104 %Dibromofluoromethane
70-13099 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 24 of 31
10/31/19
Level II QC Report
115 Mackenan Dr. BUILDING 117 Project No: 02170214.69
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Prism Work Order: 9100376
Time Submitted: 10/23/2019 5:10:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P9J0502 - SM6200 B
Blank (P9J0502-BLK1)Prepared & Analyzed: 10/29/19
1,1,1,2-Tetrachloroethane ug/LBRL0.50
1,1,1-Trichloroethane ug/LBRL0.50
1,1,2,2-Tetrachloroethane ug/LBRL0.50
1,1,2-Trichloroethane ug/LBRL0.50
1,1-Dichloroethane ug/LBRL0.50
1,1-Dichloroethylene ug/LBRL0.50
1,1-Dichloropropylene ug/LBRL0.50
1,2,3-Trichlorobenzene ug/LBRL0.50
1,2,3-Trichloropropane ug/LBRL0.50
1,2,4-Trichlorobenzene ug/LBRL0.50
1,2,4-Trimethylbenzene ug/LBRL0.50
1,2-Dibromo-3-chloropropane ug/LBRL2.0
1,2-Dibromoethane ug/LBRL0.50
1,2-Dichlorobenzene ug/LBRL0.50
1,2-Dichloroethane ug/LBRL0.50
1,2-Dichloropropane ug/LBRL0.50
1,3,5-Trimethylbenzene ug/LBRL0.50
1,3-Dichlorobenzene ug/LBRL0.50
1,3-Dichloropropane ug/LBRL0.50
1,4-Dichlorobenzene ug/LBRL0.50
2,2-Dichloropropane ug/LBRL2.0
2-Chlorotoluene ug/LBRL0.50
4-Chlorotoluene ug/LBRL0.50
4-Isopropyltoluene ug/LBRL0.50
Acetone ug/LBRL10
Benzene ug/LBRL0.50
Bromobenzene ug/LBRL0.50
Bromochloromethane ug/LBRL0.50
Bromodichloromethane ug/LBRL0.50
Bromoform ug/LBRL0.50
Bromomethane ug/LBRL1.0
Carbon Tetrachloride ug/LBRL0.50
Chlorobenzene ug/LBRL0.50
Chloroethane ug/LBRL0.50
Chloroform ug/LBRL0.50
Chloromethane ug/LBRL0.50
cis-1,2-Dichloroethylene ug/LBRL0.50
cis-1,3-Dichloropropylene ug/LBRL0.50
Dibromochloromethane ug/LBRL0.50
Dibromomethane ug/LBRL0.50
Dichlorodifluoromethane ug/LBRL1.0
Ethanol ug/LBRL200
Ethylbenzene ug/LBRL0.50
Hexachlorobutadiene ug/LBRL2.0
Isopropyl Ether ug/LBRL0.50
Isopropylbenzene (Cumene)ug/LBRL0.50
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 25 of 31
10/31/19
Level II QC Report
115 Mackenan Dr. BUILDING 117 Project No: 02170214.69
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Prism Work Order: 9100376
Time Submitted: 10/23/2019 5:10:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P9J0502 - SM6200 B
Blank (P9J0502-BLK1)Prepared & Analyzed: 10/29/19
m,p-Xylenes ug/LBRL1.0
Methyl Butyl Ketone (2-Hexanone)ug/LBRL1.0
Methyl Ethyl Ketone (2-Butanone)ug/LBRL5.0
Methyl Isobutyl Ketone ug/LBRL1.0
Methylene Chloride ug/LBRL2.0
Methyl-tert-Butyl Ether ug/LBRL1.0
Naphthalene ug/LBRL1.0
n-Butylbenzene ug/LBRL0.50
n-Propylbenzene ug/LBRL0.50
o-Xylene ug/LBRL0.50
sec-Butylbenzene ug/LBRL0.50
Styrene ug/LBRL0.50
tert-Butylbenzene ug/LBRL0.50
Tetrachloroethylene ug/LBRL0.50
Toluene ug/LBRL0.50
trans-1,2-Dichloroethylene ug/LBRL0.50
trans-1,3-Dichloropropylene ug/LBRL0.50
Trichloroethylene ug/LBRL0.50
Trichlorofluoromethane ug/LBRL0.50
Vinyl acetate ug/LBRL5.0
Vinyl chloride ug/LBRL0.50
Xylenes, total ug/LBRL1.5
ug/L 50.00 70-130Surrogate: 4-Bromofluorobenzene 9547.6
ug/L 50.00 70-130Surrogate: Dibromofluoromethane 10853.9
ug/L 50.00 70-130Surrogate: Toluene-d8 9748.7
LCS (P9J0502-BS1)Prepared & Analyzed: 10/29/19
1,1,1,2-Tetrachloroethane ug/L20.3 0.50 20.00 70-130102
1,1,1-Trichloroethane ug/L22.0 0.50 20.00 70-130110
1,1,2,2-Tetrachloroethane ug/L20.2 0.50 20.00 70-130101
1,1,2-Trichloroethane ug/L21.4 0.50 20.00 70-130107
1,1-Dichloroethane ug/L22.1 0.50 20.00 70-130110
1,1-Dichloroethylene ug/L23.0 0.50 20.00 70-130115
1,1-Dichloropropylene ug/L22.8 0.50 20.00 70-130114
1,2,3-Trichlorobenzene ug/L20.4 0.50 20.00 70-130102
1,2,3-Trichloropropane ug/L21.4 0.50 20.00 70-130107
1,2,4-Trichlorobenzene ug/L19.4 0.50 20.00 70-13097
1,2,4-Trimethylbenzene ug/L19.5 0.50 20.00 70-13098
1,2-Dibromo-3-chloropropane ug/L21.0 2.0 20.00 70-130105
1,2-Dibromoethane ug/L21.5 0.50 20.00 70-130107
1,2-Dichlorobenzene ug/L19.7 0.50 20.00 70-13098
1,2-Dichloroethane ug/L20.5 0.50 20.00 70-130102
1,2-Dichloropropane ug/L21.5 0.50 20.00 70-130107
1,3,5-Trimethylbenzene ug/L19.6 0.50 20.00 70-13098
1,3-Dichlorobenzene ug/L19.9 0.50 20.00 70-13099
1,3-Dichloropropane ug/L20.9 0.50 20.00 70-130104
1,4-Dichlorobenzene ug/L19.6 0.50 20.00 70-13098
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 26 of 31
10/31/19
Level II QC Report
115 Mackenan Dr. BUILDING 117 Project No: 02170214.69
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Prism Work Order: 9100376
Time Submitted: 10/23/2019 5:10:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P9J0502 - SM6200 B
LCS (P9J0502-BS1)Prepared & Analyzed: 10/29/19
2,2-Dichloropropane ug/L23.6 2.0 20.00 70-130118
2-Chlorotoluene ug/L19.2 0.50 20.00 70-13096
4-Chlorotoluene ug/L19.4 0.50 20.00 70-13097
4-Isopropyltoluene ug/L21.0 0.50 20.00 70-130105
Acetone ug/L42.6 10 40.00 40-160107
Benzene ug/L21.3 0.50 20.00 70-130106
Bromobenzene ug/L19.7 0.50 20.00 70-13099
Bromochloromethane ug/L22.1 0.50 20.00 70-130111
Bromodichloromethane ug/L21.6 0.50 20.00 70-130108
Bromoform ug/L23.3 0.50 20.00 70-130117
Bromomethane ug/L17.2 1.0 20.00 60-14086
Carbon Tetrachloride ug/L23.2 0.50 20.00 70-130116
Chlorobenzene ug/L20.4 0.50 20.00 70-130102
Chloroethane ug/L21.4 0.50 20.00 60-140107
Chloroform ug/L21.0 0.50 20.00 70-130105
Chloromethane ug/L18.2 0.50 20.00 60-14091
cis-1,2-Dichloroethylene ug/L20.4 0.50 20.00 70-130102
cis-1,3-Dichloropropylene ug/L22.6 0.50 20.00 70-130113
Dibromochloromethane ug/L21.7 0.50 20.00 70-130109
Dibromomethane ug/L21.5 0.50 20.00 70-130107
Dichlorodifluoromethane ug/L24.3 1.0 20.00 60-140121
Ethanol ug/L609 200 500.0 60-140122
Ethylbenzene ug/L21.1 0.50 20.00 70-130105
Hexachlorobutadiene ug/L19.6 2.0 20.00 70-13098
Isopropyl Ether ug/L20.7 0.50 20.00 70-130103
Isopropylbenzene (Cumene)ug/L20.6 0.50 20.00 70-130103
m,p-Xylenes ug/L42.4 1.0 40.00 70-130106
Methyl Butyl Ketone (2-Hexanone)ug/L19.2 1.0 20.00 60-14096
Methyl Ethyl Ketone (2-Butanone)ug/L19.6 5.0 20.00 60-14098
Methyl Isobutyl Ketone ug/L20.3 1.0 20.00 60-140102
Methylene Chloride ug/L20.5 2.0 20.00 70-130102
Methyl-tert-Butyl Ether ug/L21.1 1.0 20.00 70-130106
Naphthalene ug/L18.5 1.0 20.00 70-13093
n-Butylbenzene ug/L21.0 0.50 20.00 70-130105
n-Propylbenzene ug/L20.6 0.50 20.00 70-130103
o-Xylene ug/L19.7 0.50 20.00 70-13098
sec-Butylbenzene ug/L21.1 0.50 20.00 70-130106
Styrene ug/L20.7 0.50 20.00 70-130103
tert-Butylbenzene ug/L20.4 0.50 20.00 70-130102
Tetrachloroethylene ug/L21.6 0.50 20.00 70-130108
Toluene ug/L21.1 0.50 20.00 70-130105
trans-1,2-Dichloroethylene ug/L21.0 0.50 20.00 70-130105
trans-1,3-Dichloropropylene ug/L22.6 0.50 20.00 70-130113
Trichloroethylene ug/L21.4 0.50 20.00 70-130107
Trichlorofluoromethane ug/L25.1 0.50 20.00 60-140126
Vinyl acetate ug/L23.6 5.0 20.00 60-140118
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 27 of 31
10/31/19
Level II QC Report
115 Mackenan Dr. BUILDING 117 Project No: 02170214.69
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Prism Work Order: 9100376
Time Submitted: 10/23/2019 5:10:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P9J0502 - SM6200 B
LCS (P9J0502-BS1)Prepared & Analyzed: 10/29/19
Vinyl chloride ug/L22.6 0.50 20.00 60-140113
Xylenes, total ug/L62.0 1.5 60.00 70-130103
ug/L 50.00 70-130Surrogate: 4-Bromofluorobenzene 9446.9
ug/L 50.00 70-130Surrogate: Dibromofluoromethane 10451.9
ug/L 50.00 70-130Surrogate: Toluene-d8 9949.3
LCS Dup (P9J0502-BSD1)Prepared & Analyzed: 10/29/19
1,1,1,2-Tetrachloroethane ug/L20.5 0.50 20.00 2070-130102 0.7
1,1,1-Trichloroethane ug/L21.8 0.50 20.00 2070-130109 0.9
1,1,2,2-Tetrachloroethane ug/L20.8 0.50 20.00 2070-130104 3
1,1,2-Trichloroethane ug/L21.6 0.50 20.00 2070-130108 1
1,1-Dichloroethane ug/L21.7 0.50 20.00 2070-130109 2
1,1-Dichloroethylene ug/L22.5 0.50 20.00 2070-130113 2
1,1-Dichloropropylene ug/L22.4 0.50 20.00 2070-130112 2
1,2,3-Trichlorobenzene ug/L20.4 0.50 20.00 2070-130102 0.2
1,2,3-Trichloropropane ug/L21.3 0.50 20.00 2070-130106 0.7
1,2,4-Trichlorobenzene ug/L19.5 0.50 20.00 2070-13097 0.5
1,2,4-Trimethylbenzene ug/L19.3 0.50 20.00 2070-13096 1
1,2-Dibromo-3-chloropropane ug/L19.8 2.0 20.00 2070-13099 6
1,2-Dibromoethane ug/L21.4 0.50 20.00 2070-130107 0.7
1,2-Dichlorobenzene ug/L19.4 0.50 20.00 2070-13097 2
1,2-Dichloroethane ug/L20.3 0.50 20.00 2070-130101 1
1,2-Dichloropropane ug/L21.1 0.50 20.00 2070-130105 2
1,3,5-Trimethylbenzene ug/L19.4 0.50 20.00 2070-13097 0.9
1,3-Dichlorobenzene ug/L19.9 0.50 20.00 2070-130100 0.2
1,3-Dichloropropane ug/L21.6 0.50 20.00 2070-130108 3
1,4-Dichlorobenzene ug/L19.5 0.50 20.00 2070-13098 0.2
2,2-Dichloropropane ug/L22.6 2.0 20.00 2070-130113 4
2-Chlorotoluene ug/L18.9 0.50 20.00 2070-13095 2
4-Chlorotoluene ug/L19.6 0.50 20.00 2070-13098 0.7
4-Isopropyltoluene ug/L20.7 0.50 20.00 2070-130103 1
Acetone ug/L41.9 10 40.00 2040-160105 2
Benzene ug/L21.0 0.50 20.00 2070-130105 1
Bromobenzene ug/L19.3 0.50 20.00 2070-13096 2
Bromochloromethane ug/L22.3 0.50 20.00 2070-130111 0.7
Bromodichloromethane ug/L21.7 0.50 20.00 2070-130108 0.1
Bromoform ug/L22.6 0.50 20.00 2070-130113 3
Bromomethane ug/L18.1 1.0 20.00 2060-14090 5
Carbon Tetrachloride ug/L22.9 0.50 20.00 2070-130114 1
Chlorobenzene ug/L20.1 0.50 20.00 2070-130101 1
Chloroethane ug/L20.7 0.50 20.00 2060-140103 4
Chloroform ug/L20.3 0.50 20.00 2070-130102 3
Chloromethane ug/L17.2 0.50 20.00 2060-14086 6
cis-1,2-Dichloroethylene ug/L20.0 0.50 20.00 2070-130100 1
cis-1,3-Dichloropropylene ug/L22.4 0.50 20.00 2070-130112 1
Dibromochloromethane ug/L21.9 0.50 20.00 2070-130110 0.7
Dibromomethane ug/L22.0 0.50 20.00 2070-130110 3
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 28 of 31
10/31/19
Level II QC Report
115 Mackenan Dr. BUILDING 117 Project No: 02170214.69
Project: Arvin Oil CompanyWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Prism Work Order: 9100376
Time Submitted: 10/23/2019 5:10:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P9J0502 - SM6200 B
LCS Dup (P9J0502-BSD1)Prepared & Analyzed: 10/29/19
Dichlorodifluoromethane ug/L24.1 1.0 20.00 2060-140120 0.7
Ethanol ug/L640 200 500.0 2060-140128 5
Ethylbenzene ug/L21.3 0.50 20.00 2070-130106 0.9
Hexachlorobutadiene ug/L19.6 2.0 20.00 2070-13098 0.2
Isopropyl Ether ug/L20.5 0.50 20.00 2070-130102 1
Isopropylbenzene (Cumene)ug/L20.6 0.50 20.00 2070-130103 0.1
m,p-Xylenes ug/L42.2 1.0 40.00 2070-130105 0.4
Methyl Butyl Ketone (2-Hexanone)ug/L18.4 1.0 20.00 2060-14092 4
Methyl Ethyl Ketone (2-Butanone)ug/L18.7 5.0 20.00 2060-14094 4
Methyl Isobutyl Ketone ug/L20.0 1.0 20.00 2060-140100 2
Methylene Chloride ug/L20.5 2.0 20.00 2070-130102 0
Methyl-tert-Butyl Ether ug/L21.2 1.0 20.00 2070-130106 0.3
Naphthalene ug/L18.9 1.0 20.00 2070-13094 2
n-Butylbenzene ug/L20.5 0.50 20.00 2070-130103 2
n-Propylbenzene ug/L20.4 0.50 20.00 2070-130102 0.8
o-Xylene ug/L19.9 0.50 20.00 2070-13099 1
sec-Butylbenzene ug/L21.0 0.50 20.00 2070-130105 0.4
Styrene ug/L20.8 0.50 20.00 2070-130104 0.8
tert-Butylbenzene ug/L20.0 0.50 20.00 2070-130100 2
Tetrachloroethylene ug/L21.6 0.50 20.00 2070-130108 0.05
Toluene ug/L20.7 0.50 20.00 2070-130103 2
trans-1,2-Dichloroethylene ug/L20.7 0.50 20.00 2070-130104 2
trans-1,3-Dichloropropylene ug/L22.5 0.50 20.00 2070-130113 0.2
Trichloroethylene ug/L21.0 0.50 20.00 2070-130105 2
Trichlorofluoromethane ug/L24.6 0.50 20.00 2060-140123 2
Vinyl acetate ug/L23.5 5.0 20.00 2060-140117 0.3
Vinyl chloride ug/L22.3 0.50 20.00 2060-140112 1
Xylenes, total ug/L62.1 1.5 60.00 2070-130103 0.02
ug/L 50.00 70-130Surrogate: 4-Bromofluorobenzene 9246.2
ug/L 50.00 70-130Surrogate: Dibromofluoromethane 10452.1
ug/L 50.00 70-130Surrogate: Toluene-d8 9748.5
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 29 of 31
Sample Extraction Data
Prep Method: SM6200 B
Lab Number Batch Date/TimeInitialFinal
P9J05029100376-01 10/29/19 10:0210 10mL mL
P9J05029100376-02 10/29/19 10:0210 10mL mL
P9J05029100376-02 10/29/19 10:0210 10mL mL
P9J05029100376-03 10/29/19 10:0210 10mL mL
P9J05029100376-04 10/29/19 10:0210 10mL mL
P9J05029100376-04 10/29/19 10:0210 10mL mL
P9J05029100376-05 10/29/19 10:0210 10mL mL
P9J05029100376-05 10/29/19 10:0210 10mL mL
P9J05029100376-06 10/29/19 10:0210 10mL mL
P9J05029100376-07 10/29/19 10:0210 10mL mL
P9J05029100376-08 10/29/19 10:0210 10mL mL
P9J05029100376-09 10/29/19 10:0210 10mL mL
P9J05029100376-10 10/29/19 10:0210 10mL mL
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 30 of 31
Page 31 of 31