RA-2070_12610_CA_MRP_20091005_Terraine GW MonitoringReport

Groundwater Monitoring Report

Four Corners Store

6154 West Mount Dr.
Intersection of SR 1603 (S. Old Carriage Rd.) and SR 1717 (W. Mount Dr.)
(Langley Crossroads)
Nash County
Nashville, NC
Incident No. 12610

Prepared For:

North Carolina Department of
Environment and Natural Resources
Division of Waste Management
1637 Mail Service Center
Raleigh, NC 27699-1637

Prepared By:

Terraine, Inc.
Long View Center
118 South Person Street
Raleigh, North Carolina 27601

Terraine Project No. 13-NCSL09-010
NCDENR Contract No. 16-1713-5C

October 5, 2009

Groundwater Monitoring Report – October 5, 2009 NCDENR Incident No. 12610
Four Corners Store Page 1
Nash County, NC
Table of Contents

Signature Page _____________________________________________________________________ 2
I. Introduction _____________________________________________________________________ 3 
II. Groundwater Sampling ____________________________________________________________ 5 
III. Groundwater Sampling Results ______________________________________________________ 6 
IV. Conclusions and Recommendations __________________________________________________ 7 
V. References _____________________________________________________________________ 8 

List of Tables

Table 1 Monitoring Well Information __________________________________________ App A
Table 2 Water Supply Well Information _______________________________________ App A
Table 3 Summary of Groundwater Analytical Results _____________________________ App A

List of Figures

Figure 1 Topographic Map __________________________________________________ App B
Figure 2 Site Map _________________________________________________________ App B
Figure 3 Aerial Site Photograph ______________________________________________ App B
Figure 4 Potentiometric Surface Map _________________________________________ App B
Figure 5 Groundwater Monitoring Well Locations and Analytical Data Map ____________ App B

Appendices

Appendix A Tables
Appendix B Figures
Appendix C Chain of Custody Record
Cooler Receipt Form
Laboratory Certificates of Analysis
Quality Control Certificate

Groundwater Monitoring Report – October 5, 2009 NCDENR Incident No. 12610
Four Corners Store Page 2
Nash County, NC
Signature Page

We, the undersigned, do hereby affirm that the information contained in this report is accurate and correct
to the best of our knowledge and belief.

10/5/2009
Laura R. Robertson Date
Staff Geologist
Terraine, Inc.

10/5/2009
Brian J. Wright, L.G. Date
North Carolina Licensed Geologist # 1944
Project Manager
Terraine, Inc.

10/5/2009
Kimberly S. Caudill, L.G. Date
North Carolina Licensed Geologist # 2074
Senior Geologist
Terraine, Inc.

Groundwater Monitoring Report – October 5, 2009 NCDENR Incident No. 12610
Four Corners Store Page 3
Nash County, NC
I. Introduction

This report documents groundwater sampling activities performed in accordance with the North Carolina
State Lead Contract Task Authorization number 13-NCSL09-010-1, authorized on June 12, 2009.
The former Four Corners Store is located at the intersection of South Old Carriage Road and West Mount
Drive, which is locally referred to as Langley Crossroads, in Nashville, Nash County, North Carolina
(Figure 1). The site is currently used as an office for Claude’s Construction, Inc. The area surrounding
the site is considered residential, and there is no municipal water available. All drinking water within 1500
feet is supplied by private potable wells. The site meets the criteria for “High Risk” classification because
a water supply well used for drinking water is located within 1000 feet of the source area of a confirmed
release and the groundwater within 500 feet of the source area of a confirmed release has the potential
for future use in that there is no source of water supply other than groundwater. Three water supply wells
used for drinking water are located within 500 feet of source area. The closest surface water is a stream
1600 feet west of the site, and the Tar River is approximately one mile southeast of the site.
On March 12, 1994, ENSCI Engineering Group, P.A. performed an Underground Storage Tank (UST)
Closure event during which two 6000-gallon USTs were removed from the site. The total depth of the
excavation of the tank pit was approximately 10 feet below ground surface (bgs), and groundwater was
seen entering the excavation. Free product was not identified, but a sheen of petroleum was identified on
groundwater located on the south side of the excavation. Analytical results indicated concentrations of
total petroleum hydrocarbons above state standards in the area of the former USTs, product lines, and
dispensers.
According to a Monitoring Well Installation, Groundwater and Water Supply Well Sampling Report
prepared by Schnabel Engineering on behalf of Force Environmental Service Company (Force) in July
2006, three monitoring wells (MW-3, MW-4, and MW-5) were installed on May 23, 2006. Monitoring wells
MW-1, MW-1D, and MW-2 had been previously installed on February 1, 2006 (Table 1 and Figure 2).
Monitoring wells MW-3, MW-4, and MW-5 did not recharge within 24 hours during a Post Installation
Sampling Event, so only monitoring wells MW-1, MW-1D, and MW-2 were sampled on May 24, 2006.
Groundwater samples from monitoring wells MW-1 and MW-1D contained contaminant concentrations
above 15A NCAC 2L .0202 (2L) Standards, while the sample collected from monitoring well MW-2 only
contained contaminant concentrations above method detection limits. Water supply wells WSW-1
(onsite), WSW-2, and WSW-3 were also sampled on May 24, 2006 (Table 2 and Figure 3). Water supply
well WSW-4 was not sampled because the home was abandoned. None of the groundwater samples
from the three water supply wells (WSW-1, WSW-2, and WSW-3) contained contaminant concentrations
above method detection limits.

Groundwater Monitoring Report – October 5, 2009 NCDENR Incident No. 12610
Four Corners Store Page 4
Nash County, NC
A 2008 Groundwater Monitoring Report by Force included results of a groundwater sampling event
conducted on May 13, 2008. Six monitoring wells (MW-1, MW-1D, MW-2, MW-3, MW-4, and MW-5) and
two water supply wells (WSW-2 and WSW-3) were sampled. Water supply well WSW-1 was not sampled
because Force personnel were unable to gain access to a water spigot. This report concluded that
monitoring wells MW-1 and MW-5 contained concentrations of petroleum contaminants above the 2L
Standards. Contaminant concentrations were not detected above method detection limits in groundwater
samples collected from water supply wells WSW-2 or WSW-3.
The following report details the results of a groundwater monitoring event conducted by Terraine, Inc.
(Terraine) on July 1, 2009.

Groundwater Monitoring Report – October 5, 2009 NCDENR Incident No. 12610
Four Corners Store Page 5
Nash County, NC
II. Groundwater Sampling

On July 1, 2009, Terraine personnel mobilized to the site to collect groundwater samples from monitoring
wells MW-1, MW-1D, MW-2, MW-3, MW-4, and MW-5, and water supply wells WSW-2 and WSW-3 to
evaluate current groundwater quality conditions. Monitoring well locations are shown on the site map
(Figure 2), and water supply well locations are shown on the aerial site photograph (Figure 3).
Prior to sampling, depth to groundwater measurements were obtained from each monitoring well using a
decontaminated water level indicator (Table 1). Based on groundwater data collected on July 1, 2009,
groundwater appears to flow to the south (Figure 4). After obtaining depth to water measurements, each
well was purged in excess of three well volumes and sampled using new disposable bailers.
Claude's Construction Company was not open on July 1, 2009. Terraine could not gain access to
monitoring wells MW-2 and MW-5; the wells are located behind fencing and the access gates were
locked at the time of the site visit. Terraine attempted to contact site representatives; however, no one
was available. As a result, monitoring wells MW-2 and MW-5 were not sampled. Monitoring wells MW-1,
MW-1D, MW-3, and MW-4 and water supply wells WSW-2 and WSW-3 were sampled.
The groundwater samples from water supply wells WSW-2 and WSW-3 were collected from spigots on
the back of each house (Table 2). Prior to collecting the samples, water was allowed to run from the
spigots for at least 15 minutes to purge the wells and associated piping.
All groundwater samples obtained on July 1, 2009 were collected into laboratory prepared containers,
placed immediately on ice, and submitted under proper chain of custody control to the Pace Analytical
Services, Inc. laboratory in Huntersville, North Carolina, for chemical analyses using Standard Method
6200B for volatile organic compounds, the Massachusetts Department of Environmental Protection
method for the determination of volatile petroleum hydrocarbons, and Standard Method 3030C for total
lead.

Groundwater Monitoring Report – October 5, 2009 NCDENR Incident No. 12610
Four Corners Store Page 6
Nash County, NC
III. Groundwater Sampling Results
Table 3 provides a summary of current and historical analytical results. Groundwater monitoring well
locations and corresponding analytical data from the July 1, 2009 sampling event are shown in Figure 5.
A complete laboratory report and chain of custody form for all groundwater samples obtained July 1, 2009
are included in Appendix C.

Groundwater samples collected from the following wells contained concentrations of contaminants above
the 2L Standards on July 1, 2009:

 MW-1 : benzene; toluene; ethylbenzene; xylenes; 1,2,4-trimethylbenzene; 1,3,5-
trimethylbenzene; naphthalene; n-butylbenzene; n-propylbenzene; and C5-C8 aliphatics
 MW-3 : lead
 MW-4 : lead

Groundwater samples collected from the following wells contained concentrations of contaminants above
method detection limits but below 2L Standards on July 1, 2009:

 MW-1 : C9-C12 aliphatics and C9-C10 aromatics
 MW-3 : methyl tert-butyl ether and diisopropyl ether

The groundwater sample collected from monitoring well MW-1D contained no concentrations of
contaminants above method detection limits. Monitoring wells MW-2 and MW-5 were not sampled due to
a locked gate that prevented entry. The groundwater samples collected from water supply wells WSW-2
and WSW-3 contained no concentrations of contaminants above method detection limits.

Groundwater Monitoring Report – October 5, 2009 NCDENR Incident No. 12610
Four Corners Store Page 7
Nash County, NC
IV. Conclusions and Recommendations

A. Conclusions
Based on the analytical results of the July 1, 2009 groundwater sampling event conducted at the former
Four Corners Store site, groundwater collected from monitoring well MW-1 showed the highest
contaminant concentrations above the 2L Standards, while groundwater collected from monitoring wells
MW-3 and MW-4 only had concentrations of lead above the 2L Standards. Groundwater samples from
monitoring well MW-1D and water supply wells WSW-2 and WSW-3 contained no concentrations of
contaminants above method detection limits. Topography as well as groundwater elevation data from the
four monitoring wells sampled indicate that monitoring wells MW-2 and MW-5 are upgradient of the
release source area.

B. Recommendations
Continued monitoring of the site monitoring wells may help confirm groundwater flow direction and
delineate contaminant levels. Terraine recommends the following:
 Semi-annual sampling of monitoring wells MW-1, MW-1D, MW-2, MW-3, MW-4, and MW-5 and
water supply wells WSW-1, WSW-2, and WSW-3. The next event is proposed for early January
2010. Arrangements will have to be made with the property owner to gain access to the gated
monitoring wells MW-2 and MW-5 and an interior spigot to collect a groundwater sample from
water supply well WSW-1.
 Installing a PRP® Well Boom in monitoring well MW-1. The recommended Well Booms are
manufactured by Universal Remediation, Inc. and contain powdered beeswax that stimulates
indigenous microbes and promotes rapid bio-degradation of petroleum contaminants.

Groundwater Monitoring Report – October 5, 2009 NCDENR Incident No. 12610
Four Corners Store Page 8
Nash County, NC
V. References

ENSCI Engineering Group, P.A. (1994). UST Closure Report.
Force Environmental Service Company, LLC. (2008). Groundwater Monitoring Report. Lexington, SC.
Schnabel Engineering South, LLC. (2005). Groundwater and WSW Sampling Event and GPR Survey.
West Columbia, SC:
Schnabel Engineering South, LLC. (2006). Monitoring Well Installation, Groundwater and WSW Sampling
Report.

Groundwater Monitoring Report – October 5, 2009 NCDENR Incident No. 12610 Four Corners Store Nash County, NC
Appendix A

Table 1 Monitoring Well Information
Table 2 Water Supply Well Information
Table 3 Summary of Groundwater Analytical Results

Table 1Monitoring Well InformationFour Corners Store6154 West Mount DriveNashville, NCNash CountyNCDENR Incident No. 12610WELL ID INSTALLATION DATETOC ELEVATION SCREEN INTERVALWELL DIAMETER (IN.)DEPTH TO WATER GROUNDWATER ELEVATIONMW-1 2/1/2006 100.00 3 to 13 2 2.20 97.80MW-1D 2/1/2006 100.02 40 to 45 2 7.43 92.59MW-2 2/1/2006 99.24 2 to 12 2 NM NMMW-3 5/23/2006 100.04 5 to 15 2 4.77 95.27MW-4 5/23/2006 100.96 2 to 12 2 3.15 97.81MW-5 5/23/2006 99.88 2 to 12 2NM NMTOC - Top of casingDepth to water measurements made on July 1, 2009Units measured in feet unless otherwise noted. Groundwater elevations based on arbitrary 100.00 foot benchmark established as TOC for MW-1NM - not measured
Table 2Water Supply Well InformationFour Corners Store6154 West Mount DriveNashville, NCNash CountyNCDENR Incident No. 12610WELL ID PARCEL ID PROPERTY OWNER PROPERTY ADDRESS WATER USEDISTANCE FROM SOURCE AREAWSW-1* 019512 Troy L Langley6154 West Mount Drive Nashville, NC 27856drinkingApproximately 60 ft SouthwestWSW-2 019512 Troy L Langley6232 West Mount Drive Nashville, NC 27856 drinking 500 ft EastWSW-3 021889 Floyd Thompson6191 West Mount Drive Nashville, NC 27856drinking 350 ft SoutheastInformation from June 2006 Monitoring Well Installation and Groundwater Sampling Report conducted by Schnabel Engineering,Confirmed by Nash County GIS website, at http://gis.co.nash.nc.us/connectgis/nash/*WSW-1 = onsite water supply well
Table 3Summary of Groundwater Analytical Results 1 of 3Four Corners Store6154 West Mount DriveNashville, NCNash CountyNCDENR Incident No. 126101 1000 550 530 200 70 0.0004 350 350 21 0.38 70 2.6 70 70 70 420 4200 210 155000 257500 84500 87500 200000 70000 50 28500 25000 15500 380 6900 2600 70000 25000 30000 NE NE NE 15000Notes:All concentrations reported in micrograms per liter NE = None EstablishedND = None Detected above method detection limit NS = Not Sampled2L Standard = Title 15A NCAC 2L .0202 Groundwater Standard MTBE = Methyl tert-butyl etherGCL = Gross Contamination Level established by NCDENR IPE = Diisopropyl etherValues in bold and italicized indicate levels above 2L Groundwater Standards EDB = 1,2-dibromoethaneSample DateWell ID2L STANDARDGCLC5-C8 AliphaticsC9-C12 AliphaticsEthylbenzeneTolueneBenzeneMTBEC9-C10 AromaticsND ND ND NDXylenes1,2,4-TrimethylbenzeneEDBIPEChloromethaneND ND2400 680NDn-Butyl benzene1,2-DichloroethaneNaphthalene1,3,5-TrimethylbenzeneLeadMW-12/1/20061600 1500 1900 6100ND7332ND NDND7/1/20091310 1930 2490ND5/24/200617009/7/2006NSNSNS NSNDNDNDNDND3255/24/200626083.81811510ND2400 766298ND5/22/200711/2/20075/13/20081030154020001400NDND160NDND63002500980750NDND660ND68002600NDND8202400180029302990NDNDNDND25002500100NDNDNDNDND975082817520NDND28102520362017101800 2800NSNSNSNSNDND389NSNSNSNSChloroformIsopropylbenzenen-PropylbenzeneND360NSNS120NS65ND230100ND290130NDND250NDNDND ND1636077357278281020NDND680690NSNSNSNS920890ND3860NSNSNSNSNSMW-22/1/2006 ND ND ND14 945/22/2007 ND 1.1120 2.7 2.8 ND 140 8.334 5.00ND ND ND 9.4 11.0 NS NS NS NS9/7/2006 ND ND ND ND12.0ND ND ND2.5 2.4 ND ND ND NDNS NSND 0.31 J ND ND ND NDND NDND ND ND NS NSNS NSNS11/2/2007 ND ND ND ND ND ND NDNDND ND ND ND ND ND ND ND ND NS NS NS NS5/13/2008 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NS NS NS NS7/1/2009 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDMW-1D2/1/2006 ND 0.6 ND ND ND ND ND ND NDNSND ND ND ND ND ND NSND ND ND NDND NS NSNSND ND ND ND ND ND ND ND ND NS NS NS NS5/24/2006 ND ND ND 1.1 ND ND ND ND ND ND ND ND ND ND ND ND NS NS NS NS9/7/2006 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NS NS NS NS5/22/2007 ND ND ND ND ND ND ND ND ND .65 J ND ND ND ND ND ND NS NS NSNDNS11/2/2007 ND ND ND NDND0.8ND NDNDNS NSND ND ND NDND NDNS NS NS NSND ND NDNDNSNDND NDNSNSND ND NDNDND7/1/2009 NS NS NS NSNS5/13/2008 ND NDNS NS NS NS NSNDNSNDNSNSNSNS NS NSNS NS
Table 3 ContinuedSummary of Groundwater Analytical Results 2 of 3Four Corners Store6154 West Mount DriveNashville, NCNash CountyNCDENR Incident No. 126101 1000 550 530 200 70 0.0004 350 350 21 0.38 70 2.6 70 70 70 420 4200 210 155000 257500 84500 87500 200000 70000 50 28500 25000 15500 380 6900 2600 70000 25000 30000 NE NE NE 15000Notes:All concentrations reported in micrograms per liter NE = None EstablishedND = None Detected above method detection limit NS = Not Sampled2L Standard = Title 15A NCAC 2L .0202 Groundwater Standard MTBE = Methyl tert-butyl etherGCL = Gross Contamination Level established by NCDENR IPE = Diisopropyl etherValues in bold and italicized indicate levels above 2L Groundwater Standards EDB = 1,2-dibromoethaneSample DateWell IDGCL2L STANDARDMW-5MW-3MW-47/1/200911/2/20075/24/2006NS NS NSNSNS NSNSNS NS NS NS NS NS NS NSNSND NS NS NSND ND NS7/1/2009 NS NS NS NSND0.98ND ND11.5 ND ND ND NDND3.0ND ND ND NS NS NS NS5/13/2008 ND ND ND NDND ND6.8 0.8 ND ND NDND NS NS NS NS11/2/2007 ND ND ND NDND1.6ND ND ND ND10.0 0.7 ND ND NDNDND ND6.1ND NS NS NS NS5/22/2007 0.7 ND ND NDND ND15.0 ND ND ND NDND NS NS NS NS9/7/2006 ND ND ND NDND ND ND ND ND NDND ND ND ND NDNDND ND ND NDND ND64.55/24/200614.0ND ND NDND NDNDNS NS NS NS7/1/2009 ND ND ND NDNDND ND ND ND NDND ND ND NDNDND ND ND ND ND NDNS NS NS NS5/13/2008 ND ND ND NDND ND ND ND ND NDND ND ND ND ND NDNS NS NS NS11/2/2007 ND ND ND NDND ND ND ND ND NDND ND ND ND ND NDNS NS NS NS5/22/2007 ND ND ND NDND ND7.1ND ND NDND ND ND ND ND NDNS NS NS NS9/7/2006 ND ND ND NDND ND ND ND ND NDND ND ND ND ND NDND ND ND37.45/24/2006 ND ND ND NDND ND ND ND ND ND5.0 3.2 ND ND ND NDND ND ND NDNDNDND 3.2 ND NDNS NSND ND ND ND NDNDND NS NSND NDND NS NSNS NS5/13/2008 ND ND NDND ND ND ND0.9 ND NDNSND NDNS NS NSND ND ND ND ND NDND ND ND NDNDND12.0 1.8 ND9.3ND NS NSND ND ND NS NS5/22/2007 0.34 J ND ND NDND ND ND7.6 ND ND ND NDNDND ND7.7ND NS NS NS NS9/7/2006 ND ND ND NDND ND6.9 ND ND ND ND1.9ND ND NDC9-C12 AliphaticsIPEEDB1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneNaphthaleneC9-C10 AromaticsLeadn-Butyl benzeneChloromethaneChloroformIsopropylbenzenen-PropylbenzeneC5-C8 Aliphatics1,2-DichloroethaneBenzeneTolueneEthylbenzeneXylenesMTBE
Table 3 ContinuedSummary of Groundwater Analytical Results 3 of 3Four Corners Store6154 West Mount DriveNashville NCNash CountyNCDENR Incident No. 126101 1000 550 530 200 70 0.0004 350 350 21 0.38 70 2.6 70 70 70 420 4200 210 155000 257500 84500 87500 200000 70000 50 28500 25000 15500 380 6900 2600 70000 25000 30000 NE NE NE 15000Notes:All concentrations reported in micrograms per liter NE = None Established *WSW-1 = onsite water supply well ND = None Detected above method detection limit NS = Not Sampled2L Standard = Title 15A NCAC 2L .0202 Groundwater Standard MTBE = Methyl tert-butyl etherGCL = Gross Contamination Level established by NCDENR IPE = Diisopropyl etherValues in bold and italicized indicate levels above 2L Groundwater Standards EDB = 1,2-dibromoethaneNS NS NSNS NS NS NS NS NSNS NS NS NS NS NSNS NS NS NS7/1/2009 NS NS NS NS NSNS NS NS NS NS NSNS NS NS NS NS NSNS NS NS NS NS5/13/2008 NS NS NS NSNS NS NS NS NS NSNS NS NS NS NS NSND ND ND ND ND NDND ND ND ND ND NDNS5/22/2007 ND ND ND ND ND ND ND NDNS NS NS NS NS NSNS NS NS NS NS NSND ND11/7/2006 NS NS NS NS NS NS NSND ND ND ND ND NDND ND ND ND ND NDND ND ND9/7/2006 ND ND ND ND ND NDND ND ND ND ND NDND ND ND ND ND NDND ND ND ND5/24/2006 ND ND ND ND NDND ND ND ND ND NDND ND ND ND ND NDWSW-1*2/1/2006 ND ND ND ND11/2/2007 NS NS NSBenzeneTolueneEthylbenzeneXylenesMTBELeadn-Butyl benzeneChloromethaneChloroformIsopropylbenzenen-PropylbenzeneC5-C8 AliphaticsC9-C12 AliphaticsIPEEDB1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneC9-C10 AromaticsNaphthalene1,2-DichloroethaneND NDWSW-22/1/2006 ND ND NDND NS NS NS NSND ND ND ND ND5/24/2006 ND ND ND NDNDNDND ND NDND ND ND ND ND ND ND ND ND ND ND NDNDNS NS NS NS9/7/2006 ND ND ND NDND14ND ND NDND ND ND ND NDNS NS NS NS11/7/2006 ND ND ND NDNDND ND ND ND ND ND ND ND ND ND ND NDNDNS NS NS NS5/22/2007 ND ND ND NDND ND ND ND NDND ND ND ND NDNS NS NS NS11/2/2007 ND ND ND NDNDND ND ND ND ND ND ND ND ND ND ND NDNDNS NS NS NS5/13/2008 ND ND ND NDND ND ND ND NDND ND ND ND NDNS NS NS NS7/1/2009 ND ND ND NDNDND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDWSW-32/1/2006 ND ND ND NDNDND ND ND ND NDNS NS NS NS5/24/2006 ND ND ND NDNDND ND ND ND NDNDND ND ND NDND ND ND ND ND ND ND NS NS NS NS9/7/2006 ND ND ND NDNDND ND ND ND NDNS NS NS NS11/7/2006 ND ND ND NDNDND ND ND ND NDNDND ND5.4NDND ND ND ND ND ND ND NS NS NS NS5/22/2007 ND ND ND NDNDND ND ND ND NDNS NS NS NS11/2/2007 ND ND ND NDNDND ND ND ND NDNDND ND ND NDNS NS5/13/2008 ND ND ND NDND ND NDNDND NS NSND ND NDND NS NSND ND ND NDNDNDND ND ND NDNS NSND ND ND ND NDND ND2L STANDARDND ND ND ND ND ND7/1/2009Sample DateWell IDGCLND ND NDND ND ND ND

Groundwater Monitoring Report – October 5, 2009 NCDENR Incident No. 12610 Four Corners Store Nash County, NC
Appendix B

Figure 1 Topographic Map
Figure 2 Site Map
Figure 3 Aerial Site Photograph
Figure 4 Potentiometric Surface Map
Figure 5 Groundwater Monitoring Locations & Analytical Data Map

Groundwater Monitoring Report – October 5, 2009 NCDENR Incident No. 12610 Four Corners Store Nash County, NC
Appendix C

Chain of Custody Record
Cooler Receipt Form
Laboratory Certificates of Analysis
Quality Control Certificate

July 16, 2009
LIMS USE: FR - JAD BEAN
LIMS OBJECT ID: 9247853
9247853
Project:
Pace Project No.:
RE:
Mr. Jad BeanTerraine, Inc1230 Hamilton CourtApt. ACary, NC 27511
FOUR CORNERS STORE 12610
Dear Mr. Bean:
Enclosed are the analytical results for sample(s) received by the laboratory on July 02, 2009. The
results relate only to the samples included in this report. Results reported herein conform to the
most current NELAC standards, where applicable, unless otherwise narrated in the body of thereport.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory andOrganic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Renee Spencer
[e-mail] Manager
Enclosures
cc:Mr. Burke Cathey, Terraine, Inc
Mr. David Lowery, Terraine, Inc
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 23
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
Pace Project No.:
Project:
9247853
FOUR CORNERS STORE 12610
Charlotte Certification IDsWest Virginia Certification #: 357Virginia Certification #: 00213Tennessee Certification #: 04010South Carolina Drinking Water Cert. #: 990060003South Carolina Certification #: 990060001Pennsylvania Certification #: 68-00784Connecticut Certification #: PH-0104
North Carolina Field Services Certification #: 5342North Carolina Drinking Water Certification #: 37706New Jersey Certification #: NC012Louisiana/LELAP Certification #: 04034Kentucky UST Certification #: 84Florida/NELAP Certification #: E87627North Carolina Wastewater Certification #: 12
Asheville Certification IDsWest Virginia Certification #: 356Virginia Certification #: 00072Connecticut Certification #: PH-0106Florida/NELAP Certification #: E87648Tennessee Certification #: 2980South Carolina Certification #: 99030001South Carolina Bioassay Certification #: 99030002
Pennsylvania Certification #: 68-03578North Carolina Wastewater Certification #: 40North Carolina Drinking Water Certification #: 37712North Carolina Bioassay Certification #: 9New Jersey Certification #: NC011Massachusetts Certification #: M-NC030Louisiana/LELAP Certification #: 03095
Eden Certification IDsNorth Carolina Wastewater Certification #: 633Virginia Drinking Water Certification #: 00424 North Carolina Drinking Water Certification #: 37738
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 23
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
9247853
FOUR CORNERS STORE 12610
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
9247853001 MW-1 EPA 200.7 1 PASI-ASHB
MADEP VPH 5 PASI-CDHW
SM 6200B 65 PASI-CPPM
9247853002 MW-1D EPA 200.7 1 PASI-ASHB
MADEP VPH 5 PASI-CDHW
SM 6200B 65 PASI-CPPM
9247853003 MW-3 EPA 200.7 1 PASI-ASHB
MADEP VPH 5 PASI-CDHW
SM 6200B 65 PASI-CPPM
9247853004 MW-4 EPA 200.7 1 PASI-ASHB
MADEP VPH 5 PASI-CDHW
SM 6200B 65 PASI-CPPM
9247853005 WSW-2 EPA 200.7 1 PASI-ASHB
MADEP VPH 5 PASI-CDHW
SM 6200B 65 PASI-CPPM
9247853006 WSW-3 EPA 200.7 1 PASI-ASHB
MADEP VPH 5 PASI-CDHW
SM 6200B 65 PASI-CPPM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 23
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9247853
FOUR CORNERS STORE 12610
Sample:MW-1 Lab ID:9247853001 Collected:07/01/09 10:10 Received:07/02/09 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)1510 ug/L 1 07/15/09 04:37100
Aliphatic (C09-C12)3860 ug/L 1 07/15/09 04:37100
Aromatic (C09-C10)181 ug/L 1 07/15/09 04:37100
2,5-Dibromotoluene (PID)(S)96 %1 07/15/09 04:3770-130
2,5-Dibromotoluene (FID)(S)113 %1 07/15/09 04:3770-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead ND ug/L 1 07/06/09 20:33 7439-92-107/04/09 08:005.0
6200B MSV Analytical Method: SM 6200B
Benzene 1310 ug/L 25 07/10/09 03:22 71-43-212.5
Bromobenzene ND ug/L 25 07/10/09 03:22 108-86-112.5
Bromochloromethane ND ug/L 25 07/10/09 03:22 74-97-512.5
Bromodichloromethane ND ug/L 25 07/10/09 03:22 75-27-412.5
Bromoform ND ug/L 25 07/10/09 03:22 75-25-212.5
Bromomethane ND ug/L 25 07/10/09 03:22 74-83-925.0
n-Butylbenzene 83.8 ug/L 25 07/10/09 03:22 104-51-812.5
sec-Butylbenzene ND ug/L 25 07/10/09 03:22 135-98-812.5
tert-Butylbenzene ND ug/L 25 07/10/09 03:22 98-06-612.5
Carbon tetrachloride ND ug/L 25 07/10/09 03:22 56-23-512.5
Chlorobenzene ND ug/L 25 07/10/09 03:22 108-90-712.5
Chloroethane ND ug/L 25 07/10/09 03:22 75-00-325.0
Chloroform ND ug/L 25 07/10/09 03:22 67-66-312.5
Chloromethane ND ug/L 25 07/10/09 03:22 74-87-325.0
2-Chlorotoluene ND ug/L 25 07/10/09 03:22 95-49-812.5
4-Chlorotoluene ND ug/L 25 07/10/09 03:22 106-43-412.5
1,2-Dibromo-3-chloropropane ND ug/L 25 07/10/09 03:22 96-12-825.0
Dibromochloromethane ND ug/L 25 07/10/09 03:22 124-48-112.5
1,2-Dibromoethane (EDB)ND ug/L 25 07/10/09 03:22 106-93-412.5
Dibromomethane ND ug/L 25 07/10/09 03:22 74-95-312.5
1,2-Dichlorobenzene ND ug/L 25 07/10/09 03:22 95-50-112.5
1,3-Dichlorobenzene ND ug/L 25 07/10/09 03:22 541-73-112.5
1,4-Dichlorobenzene ND ug/L 25 07/10/09 03:22 106-46-712.5
Dichlorodifluoromethane ND ug/L 25 07/10/09 03:22 75-71-812.5
1,1-Dichloroethane ND ug/L 25 07/10/09 03:22 75-34-312.5
1,2-Dichloroethane ND ug/L 25 07/10/09 03:22 107-06-212.5
1,1-Dichloroethene ND ug/L 25 07/10/09 03:22 75-35-412.5
cis-1,2-Dichloroethene ND ug/L 25 07/10/09 03:22 156-59-212.5
trans-1,2-Dichloroethene ND ug/L 25 07/10/09 03:22 156-60-512.5
1,2-Dichloropropane ND ug/L 25 07/10/09 03:22 78-87-512.5
1,3-Dichloropropane ND ug/L 25 07/10/09 03:22 142-28-912.5
2,2-Dichloropropane ND ug/L 25 07/10/09 03:22 594-20-712.5
1,1-Dichloropropene ND ug/L 25 07/10/09 03:22 563-58-612.5
cis-1,3-Dichloropropene ND ug/L 25 07/10/09 03:22 10061-01-512.5
trans-1,3-Dichloropropene ND ug/L 25 07/10/09 03:22 10061-02-612.5
Diisopropyl ether ND ug/L 25 07/10/09 03:22 108-20-312.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/16/2009 10:46 AM Page 4 of 23
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9247853
FOUR CORNERS STORE 12610
Sample:MW-1 Lab ID:9247853001 Collected:07/01/09 10:10 Received:07/02/09 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Ethylbenzene 2490 ug/L 25 07/10/09 03:22 100-41-412.5
Hexachloro-1,3-butadiene ND ug/L 25 07/10/09 03:22 87-68-350.0
Isopropylbenzene (Cumene)ND ug/L 25 07/10/09 03:22 98-82-812.5
p-Isopropyltoluene ND ug/L 25 07/10/09 03:22 99-87-612.5
Methylene Chloride ND ug/L 25 07/10/09 03:22 75-09-250.0
Methyl-tert-butyl ether ND ug/L 25 07/10/09 03:22 1634-04-412.5
Naphthalene 766 ug/L 25 07/10/09 03:22 91-20-350.0
n-Propylbenzene 298 ug/L 25 07/10/09 03:22 103-65-112.5
Styrene ND ug/L 25 07/10/09 03:22 100-42-512.5
1,1,1,2-Tetrachloroethane ND ug/L 25 07/10/09 03:22 630-20-612.5
1,1,2,2-Tetrachloroethane ND ug/L 25 07/10/09 03:22 79-34-512.5
Tetrachloroethene ND ug/L 25 07/10/09 03:22 127-18-412.5
Toluene 1930 ug/L 25 07/10/09 03:22 108-88-312.5
1,2,3-Trichlorobenzene ND ug/L 25 07/10/09 03:22 87-61-650.0
1,2,4-Trichlorobenzene ND ug/L 25 07/10/09 03:22 120-82-150.0
1,1,1-Trichloroethane ND ug/L 25 07/10/09 03:22 71-55-612.5
1,1,2-Trichloroethane ND ug/L 25 07/10/09 03:22 79-00-512.5
Trichloroethene ND ug/L 25 07/10/09 03:22 79-01-612.5
Trichlorofluoromethane ND ug/L 25 07/10/09 03:22 75-69-425.0
1,2,3-Trichloropropane ND ug/L 25 07/10/09 03:22 96-18-412.5
1,2,4-Trimethylbenzene 2400 ug/L 25 07/10/09 03:22 95-63-612.5
1,3,5-Trimethylbenzene 607 ug/L 25 07/10/09 03:22 108-67-812.5
Vinyl chloride ND ug/L 25 07/10/09 03:22 75-01-425.0
m&p-Xylene 6510 ug/L 25 07/10/09 03:22 1330-20-725.0
o-Xylene 822 ug/L 25 07/10/09 03:22 95-47-612.5
1,2-Dichloroethane-d4 (S)91 %25 07/10/09 03:22 17060-07-070-130
Dibromofluoromethane (S)96 %25 07/10/09 03:22 1868-53-770-130
4-Bromofluorobenzene (S)103 %25 07/10/09 03:22 460-00-470-130
Toluene-d8 (S)99 %25 07/10/09 03:22 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/16/2009 10:46 AM Page 5 of 23
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9247853
FOUR CORNERS STORE 12610
Sample:MW-1D Lab ID:9247853002 Collected:07/01/09 09:15 Received:07/02/09 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 07/15/09 02:39100
Aliphatic (C09-C12)ND ug/L 1 07/15/09 02:39100
Aromatic (C09-C10)ND ug/L 1 07/15/09 02:39100
2,5-Dibromotoluene (PID)(S)91 %1 07/15/09 02:3970-130
2,5-Dibromotoluene (FID)(S)108 %1 07/15/09 02:3970-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead ND ug/L 1 07/06/09 20:26 7439-92-107/04/09 08:005.0
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 07/10/09 20:59 71-43-20.50
Bromobenzene ND ug/L 1 07/10/09 20:59 108-86-10.50
Bromochloromethane ND ug/L 1 07/10/09 20:59 74-97-50.50
Bromodichloromethane ND ug/L 1 07/10/09 20:59 75-27-40.50
Bromoform ND ug/L 1 07/10/09 20:59 75-25-20.50
Bromomethane ND ug/L 1 07/10/09 20:59 74-83-91.0
n-Butylbenzene ND ug/L 1 07/10/09 20:59 104-51-80.50
sec-Butylbenzene ND ug/L 1 07/10/09 20:59 135-98-80.50
tert-Butylbenzene ND ug/L 1 07/10/09 20:59 98-06-60.50
Carbon tetrachloride ND ug/L 1 07/10/09 20:59 56-23-50.50
Chlorobenzene ND ug/L 1 07/10/09 20:59 108-90-70.50
Chloroethane ND ug/L 1 07/10/09 20:59 75-00-31.0
Chloroform ND ug/L 1 07/10/09 20:59 67-66-30.50
Chloromethane ND ug/L 1 07/10/09 20:59 74-87-31.0
2-Chlorotoluene ND ug/L 1 07/10/09 20:59 95-49-80.50
4-Chlorotoluene ND ug/L 1 07/10/09 20:59 106-43-40.50
1,2-Dibromo-3-chloropropane ND ug/L 1 07/10/09 20:59 96-12-81.0
Dibromochloromethane ND ug/L 1 07/10/09 20:59 124-48-10.50
1,2-Dibromoethane (EDB)ND ug/L 1 07/10/09 20:59 106-93-40.50
Dibromomethane ND ug/L 1 07/10/09 20:59 74-95-30.50
1,2-Dichlorobenzene ND ug/L 1 07/10/09 20:59 95-50-10.50
1,3-Dichlorobenzene ND ug/L 1 07/10/09 20:59 541-73-10.50
1,4-Dichlorobenzene ND ug/L 1 07/10/09 20:59 106-46-70.50
Dichlorodifluoromethane ND ug/L 1 07/10/09 20:59 75-71-80.50
1,1-Dichloroethane ND ug/L 1 07/10/09 20:59 75-34-30.50
1,2-Dichloroethane ND ug/L 1 07/10/09 20:59 107-06-20.50
1,1-Dichloroethene ND ug/L 1 07/10/09 20:59 75-35-40.50
cis-1,2-Dichloroethene ND ug/L 1 07/10/09 20:59 156-59-20.50
trans-1,2-Dichloroethene ND ug/L 1 07/10/09 20:59 156-60-50.50
1,2-Dichloropropane ND ug/L 1 07/10/09 20:59 78-87-50.50
1,3-Dichloropropane ND ug/L 1 07/10/09 20:59 142-28-90.50
2,2-Dichloropropane ND ug/L 1 07/10/09 20:59 594-20-70.50
1,1-Dichloropropene ND ug/L 1 07/10/09 20:59 563-58-60.50
cis-1,3-Dichloropropene ND ug/L 1 07/10/09 20:59 10061-01-50.50
trans-1,3-Dichloropropene ND ug/L 1 07/10/09 20:59 10061-02-60.50
Diisopropyl ether ND ug/L 1 07/10/09 20:59 108-20-30.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/16/2009 10:46 AM Page 6 of 23
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9247853
FOUR CORNERS STORE 12610
Sample:MW-1D Lab ID:9247853002 Collected:07/01/09 09:15 Received:07/02/09 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Ethylbenzene ND ug/L 1 07/10/09 20:59 100-41-40.50
Hexachloro-1,3-butadiene ND ug/L 1 07/10/09 20:59 87-68-32.0
Isopropylbenzene (Cumene)ND ug/L 1 07/10/09 20:59 98-82-80.50
p-Isopropyltoluene ND ug/L 1 07/10/09 20:59 99-87-60.50
Methylene Chloride ND ug/L 1 07/10/09 20:59 75-09-22.0
Methyl-tert-butyl ether ND ug/L 1 07/10/09 20:59 1634-04-40.50
Naphthalene ND ug/L 1 07/10/09 20:59 91-20-32.0
n-Propylbenzene ND ug/L 1 07/10/09 20:59 103-65-10.50
Styrene ND ug/L 1 07/10/09 20:59 100-42-50.50
1,1,1,2-Tetrachloroethane ND ug/L 1 07/10/09 20:59 630-20-60.50
1,1,2,2-Tetrachloroethane ND ug/L 1 07/10/09 20:59 79-34-50.50
Tetrachloroethene ND ug/L 1 07/10/09 20:59 127-18-40.50
Toluene ND ug/L 1 07/10/09 20:59 108-88-30.50
1,2,3-Trichlorobenzene ND ug/L 1 07/10/09 20:59 87-61-62.0
1,2,4-Trichlorobenzene ND ug/L 1 07/10/09 20:59 120-82-12.0
1,1,1-Trichloroethane ND ug/L 1 07/10/09 20:59 71-55-60.50
1,1,2-Trichloroethane ND ug/L 1 07/10/09 20:59 79-00-50.50
Trichloroethene ND ug/L 1 07/10/09 20:59 79-01-60.50
Trichlorofluoromethane ND ug/L 1 07/10/09 20:59 75-69-41.0
1,2,3-Trichloropropane ND ug/L 1 07/10/09 20:59 96-18-40.50
1,2,4-Trimethylbenzene ND ug/L 1 07/10/09 20:59 95-63-60.50
1,3,5-Trimethylbenzene ND ug/L 1 07/10/09 20:59 108-67-80.50
Vinyl chloride ND ug/L 1 07/10/09 20:59 75-01-41.0
m&p-Xylene ND ug/L 1 07/10/09 20:59 1330-20-71.0
o-Xylene ND ug/L 1 07/10/09 20:59 95-47-60.50
1,2-Dichloroethane-d4 (S)95 %1 07/10/09 20:59 17060-07-070-130
Dibromofluoromethane (S)97 %1 07/10/09 20:59 1868-53-770-130
4-Bromofluorobenzene (S)98 %1 07/10/09 20:59 460-00-470-130
Toluene-d8 (S)96 %1 07/10/09 20:59 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/16/2009 10:46 AM Page 7 of 23
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9247853
FOUR CORNERS STORE 12610
Sample:MW-3 Lab ID:9247853003 Collected:07/01/09 10:45 Received:07/02/09 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 07/15/09 03:08100
Aliphatic (C09-C12)ND ug/L 1 07/15/09 03:08100
Aromatic (C09-C10)ND ug/L 1 07/15/09 03:08100
2,5-Dibromotoluene (PID)(S)90 %1 07/15/09 03:0870-130
2,5-Dibromotoluene (FID)(S)108 %1 07/15/09 03:0870-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead 37.4 ug/L 1 07/06/09 20:41 7439-92-107/04/09 08:005.0
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 07/10/09 04:10 71-43-20.50
Bromobenzene ND ug/L 1 07/10/09 04:10 108-86-10.50
Bromochloromethane ND ug/L 1 07/10/09 04:10 74-97-50.50
Bromodichloromethane ND ug/L 1 07/10/09 04:10 75-27-40.50
Bromoform ND ug/L 1 07/10/09 04:10 75-25-20.50
Bromomethane ND ug/L 1 07/10/09 04:10 74-83-91.0
n-Butylbenzene ND ug/L 1 07/10/09 04:10 104-51-80.50
sec-Butylbenzene ND ug/L 1 07/10/09 04:10 135-98-80.50
tert-Butylbenzene ND ug/L 1 07/10/09 04:10 98-06-60.50
Carbon tetrachloride ND ug/L 1 07/10/09 04:10 56-23-50.50
Chlorobenzene ND ug/L 1 07/10/09 04:10 108-90-70.50
Chloroethane ND ug/L 1 07/10/09 04:10 75-00-31.0
Chloroform ND ug/L 1 07/10/09 04:10 67-66-30.50
Chloromethane ND ug/L 1 07/10/09 04:10 74-87-31.0
2-Chlorotoluene ND ug/L 1 07/10/09 04:10 95-49-80.50
4-Chlorotoluene ND ug/L 1 07/10/09 04:10 106-43-40.50
1,2-Dibromo-3-chloropropane ND ug/L 1 07/10/09 04:10 96-12-81.0
Dibromochloromethane ND ug/L 1 07/10/09 04:10 124-48-10.50
1,2-Dibromoethane (EDB)ND ug/L 1 07/10/09 04:10 106-93-40.50
Dibromomethane ND ug/L 1 07/10/09 04:10 74-95-30.50
1,2-Dichlorobenzene ND ug/L 1 07/10/09 04:10 95-50-10.50
1,3-Dichlorobenzene ND ug/L 1 07/10/09 04:10 541-73-10.50
1,4-Dichlorobenzene ND ug/L 1 07/10/09 04:10 106-46-70.50
Dichlorodifluoromethane ND ug/L 1 07/10/09 04:10 75-71-80.50
1,1-Dichloroethane ND ug/L 1 07/10/09 04:10 75-34-30.50
1,2-Dichloroethane ND ug/L 1 07/10/09 04:10 107-06-20.50
1,1-Dichloroethene ND ug/L 1 07/10/09 04:10 75-35-40.50
cis-1,2-Dichloroethene ND ug/L 1 07/10/09 04:10 156-59-20.50
trans-1,2-Dichloroethene ND ug/L 1 07/10/09 04:10 156-60-50.50
1,2-Dichloropropane ND ug/L 1 07/10/09 04:10 78-87-50.50
1,3-Dichloropropane ND ug/L 1 07/10/09 04:10 142-28-90.50
2,2-Dichloropropane ND ug/L 1 07/10/09 04:10 594-20-70.50
1,1-Dichloropropene ND ug/L 1 07/10/09 04:10 563-58-60.50
cis-1,3-Dichloropropene ND ug/L 1 07/10/09 04:10 10061-01-50.50
trans-1,3-Dichloropropene ND ug/L 1 07/10/09 04:10 10061-02-60.50
Diisopropyl ether 3.2 ug/L 1 07/10/09 04:10 108-20-30.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/16/2009 10:46 AM Page 8 of 23
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9247853
FOUR CORNERS STORE 12610
Sample:MW-3 Lab ID:9247853003 Collected:07/01/09 10:45 Received:07/02/09 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Ethylbenzene ND ug/L 1 07/10/09 04:10 100-41-40.50
Hexachloro-1,3-butadiene ND ug/L 1 07/10/09 04:10 87-68-32.0
Isopropylbenzene (Cumene)ND ug/L 1 07/10/09 04:10 98-82-80.50
p-Isopropyltoluene ND ug/L 1 07/10/09 04:10 99-87-60.50
Methylene Chloride ND ug/L 1 07/10/09 04:10 75-09-22.0
Methyl-tert-butyl ether 5.0 ug/L 1 07/10/09 04:10 1634-04-40.50
Naphthalene ND ug/L 1 07/10/09 04:10 91-20-32.0
n-Propylbenzene ND ug/L 1 07/10/09 04:10 103-65-10.50
Styrene ND ug/L 1 07/10/09 04:10 100-42-50.50
1,1,1,2-Tetrachloroethane ND ug/L 1 07/10/09 04:10 630-20-60.50
1,1,2,2-Tetrachloroethane ND ug/L 1 07/10/09 04:10 79-34-50.50
Tetrachloroethene ND ug/L 1 07/10/09 04:10 127-18-40.50
Toluene ND ug/L 1 07/10/09 04:10 108-88-30.50
1,2,3-Trichlorobenzene ND ug/L 1 07/10/09 04:10 87-61-62.0
1,2,4-Trichlorobenzene ND ug/L 1 07/10/09 04:10 120-82-12.0
1,1,1-Trichloroethane ND ug/L 1 07/10/09 04:10 71-55-60.50
1,1,2-Trichloroethane ND ug/L 1 07/10/09 04:10 79-00-50.50
Trichloroethene ND ug/L 1 07/10/09 04:10 79-01-60.50
Trichlorofluoromethane ND ug/L 1 07/10/09 04:10 75-69-41.0
1,2,3-Trichloropropane ND ug/L 1 07/10/09 04:10 96-18-40.50
1,2,4-Trimethylbenzene ND ug/L 1 07/10/09 04:10 95-63-60.50
1,3,5-Trimethylbenzene ND ug/L 1 07/10/09 04:10 108-67-80.50
Vinyl chloride ND ug/L 1 07/10/09 04:10 75-01-41.0
m&p-Xylene ND ug/L 1 07/10/09 04:10 1330-20-71.0
o-Xylene ND ug/L 1 07/10/09 04:10 95-47-60.50
1,2-Dichloroethane-d4 (S)93 %1 07/10/09 04:10 17060-07-070-130
Dibromofluoromethane (S)99 %1 07/10/09 04:10 1868-53-770-130
4-Bromofluorobenzene (S)98 %1 07/10/09 04:10 460-00-470-130
Toluene-d8 (S)98 %1 07/10/09 04:10 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/16/2009 10:46 AM Page 9 of 23
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9247853
FOUR CORNERS STORE 12610
Sample:MW-4 Lab ID:9247853004 Collected:07/01/09 10:50 Received:07/02/09 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 07/15/09 03:38100
Aliphatic (C09-C12)ND ug/L 1 07/15/09 03:38100
Aromatic (C09-C10)ND ug/L 1 07/15/09 03:38100
2,5-Dibromotoluene (PID)(S)90 %1 07/15/09 03:3870-130
2,5-Dibromotoluene (FID)(S)108 %1 07/15/09 03:3870-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead 64.5 ug/L 1 07/06/09 20:45 7439-92-107/04/09 08:005.0
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 07/10/09 04:34 71-43-20.50
Bromobenzene ND ug/L 1 07/10/09 04:34 108-86-10.50
Bromochloromethane ND ug/L 1 07/10/09 04:34 74-97-50.50
Bromodichloromethane ND ug/L 1 07/10/09 04:34 75-27-40.50
Bromoform ND ug/L 1 07/10/09 04:34 75-25-20.50
Bromomethane ND ug/L 1 07/10/09 04:34 74-83-91.0
n-Butylbenzene ND ug/L 1 07/10/09 04:34 104-51-80.50
sec-Butylbenzene ND ug/L 1 07/10/09 04:34 135-98-80.50
tert-Butylbenzene ND ug/L 1 07/10/09 04:34 98-06-60.50
Carbon tetrachloride ND ug/L 1 07/10/09 04:34 56-23-50.50
Chlorobenzene ND ug/L 1 07/10/09 04:34 108-90-70.50
Chloroethane ND ug/L 1 07/10/09 04:34 75-00-31.0
Chloroform ND ug/L 1 07/10/09 04:34 67-66-30.50
Chloromethane ND ug/L 1 07/10/09 04:34 74-87-31.0
2-Chlorotoluene ND ug/L 1 07/10/09 04:34 95-49-80.50
4-Chlorotoluene ND ug/L 1 07/10/09 04:34 106-43-40.50
1,2-Dibromo-3-chloropropane ND ug/L 1 07/10/09 04:34 96-12-81.0
Dibromochloromethane ND ug/L 1 07/10/09 04:34 124-48-10.50
1,2-Dibromoethane (EDB)ND ug/L 1 07/10/09 04:34 106-93-40.50
Dibromomethane ND ug/L 1 07/10/09 04:34 74-95-30.50
1,2-Dichlorobenzene ND ug/L 1 07/10/09 04:34 95-50-10.50
1,3-Dichlorobenzene ND ug/L 1 07/10/09 04:34 541-73-10.50
1,4-Dichlorobenzene ND ug/L 1 07/10/09 04:34 106-46-70.50
Dichlorodifluoromethane ND ug/L 1 07/10/09 04:34 75-71-80.50
1,1-Dichloroethane ND ug/L 1 07/10/09 04:34 75-34-30.50
1,2-Dichloroethane ND ug/L 1 07/10/09 04:34 107-06-20.50
1,1-Dichloroethene ND ug/L 1 07/10/09 04:34 75-35-40.50
cis-1,2-Dichloroethene ND ug/L 1 07/10/09 04:34 156-59-20.50
trans-1,2-Dichloroethene ND ug/L 1 07/10/09 04:34 156-60-50.50
1,2-Dichloropropane ND ug/L 1 07/10/09 04:34 78-87-50.50
1,3-Dichloropropane ND ug/L 1 07/10/09 04:34 142-28-90.50
2,2-Dichloropropane ND ug/L 1 07/10/09 04:34 594-20-70.50
1,1-Dichloropropene ND ug/L 1 07/10/09 04:34 563-58-60.50
cis-1,3-Dichloropropene ND ug/L 1 07/10/09 04:34 10061-01-50.50
trans-1,3-Dichloropropene ND ug/L 1 07/10/09 04:34 10061-02-60.50
Diisopropyl ether ND ug/L 1 07/10/09 04:34 108-20-30.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/16/2009 10:46 AM Page 10 of 23
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9247853
FOUR CORNERS STORE 12610
Sample:MW-4 Lab ID:9247853004 Collected:07/01/09 10:50 Received:07/02/09 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Ethylbenzene ND ug/L 1 07/10/09 04:34 100-41-40.50
Hexachloro-1,3-butadiene ND ug/L 1 07/10/09 04:34 87-68-32.0
Isopropylbenzene (Cumene)ND ug/L 1 07/10/09 04:34 98-82-80.50
p-Isopropyltoluene ND ug/L 1 07/10/09 04:34 99-87-60.50
Methylene Chloride ND ug/L 1 07/10/09 04:34 75-09-22.0
Methyl-tert-butyl ether ND ug/L 1 07/10/09 04:34 1634-04-40.50
Naphthalene ND ug/L 1 07/10/09 04:34 91-20-32.0
n-Propylbenzene ND ug/L 1 07/10/09 04:34 103-65-10.50
Styrene ND ug/L 1 07/10/09 04:34 100-42-50.50
1,1,1,2-Tetrachloroethane ND ug/L 1 07/10/09 04:34 630-20-60.50
1,1,2,2-Tetrachloroethane ND ug/L 1 07/10/09 04:34 79-34-50.50
Tetrachloroethene ND ug/L 1 07/10/09 04:34 127-18-40.50
Toluene ND ug/L 1 07/10/09 04:34 108-88-30.50
1,2,3-Trichlorobenzene ND ug/L 1 07/10/09 04:34 87-61-62.0
1,2,4-Trichlorobenzene ND ug/L 1 07/10/09 04:34 120-82-12.0
1,1,1-Trichloroethane ND ug/L 1 07/10/09 04:34 71-55-60.50
1,1,2-Trichloroethane ND ug/L 1 07/10/09 04:34 79-00-50.50
Trichloroethene ND ug/L 1 07/10/09 04:34 79-01-60.50
Trichlorofluoromethane ND ug/L 1 07/10/09 04:34 75-69-41.0
1,2,3-Trichloropropane ND ug/L 1 07/10/09 04:34 96-18-40.50
1,2,4-Trimethylbenzene ND ug/L 1 07/10/09 04:34 95-63-60.50
1,3,5-Trimethylbenzene ND ug/L 1 07/10/09 04:34 108-67-80.50
Vinyl chloride ND ug/L 1 07/10/09 04:34 75-01-41.0
m&p-Xylene ND ug/L 1 07/10/09 04:34 1330-20-71.0
o-Xylene ND ug/L 1 07/10/09 04:34 95-47-60.50
1,2-Dichloroethane-d4 (S)97 %1 07/10/09 04:34 17060-07-070-130
Dibromofluoromethane (S)103 %1 07/10/09 04:34 1868-53-770-130
4-Bromofluorobenzene (S)99 %1 07/10/09 04:34 460-00-470-130
Toluene-d8 (S)96 %1 07/10/09 04:34 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/16/2009 10:46 AM Page 11 of 23
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9247853
FOUR CORNERS STORE 12610
Sample:WSW-2 Lab ID:9247853005 Collected:07/01/09 11:30 Received:07/02/09 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 07/15/09 04:07100
Aliphatic (C09-C12)ND ug/L 1 07/15/09 04:07100
Aromatic (C09-C10)ND ug/L 1 07/15/09 04:07100
2,5-Dibromotoluene (PID)(S)98 %1 07/15/09 04:0770-130
2,5-Dibromotoluene (FID)(S)116 %1 07/15/09 04:0770-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead ND ug/L 1 07/06/09 20:48 7439-92-107/04/09 08:005.0
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 07/10/09 04:57 71-43-20.50
Bromobenzene ND ug/L 1 07/10/09 04:57 108-86-10.50
Bromochloromethane ND ug/L 1 07/10/09 04:57 74-97-50.50
Bromodichloromethane ND ug/L 1 07/10/09 04:57 75-27-40.50
Bromoform ND ug/L 1 07/10/09 04:57 75-25-20.50
Bromomethane ND ug/L 1 07/10/09 04:57 74-83-91.0
n-Butylbenzene ND ug/L 1 07/10/09 04:57 104-51-80.50
sec-Butylbenzene ND ug/L 1 07/10/09 04:57 135-98-80.50
tert-Butylbenzene ND ug/L 1 07/10/09 04:57 98-06-60.50
Carbon tetrachloride ND ug/L 1 07/10/09 04:57 56-23-50.50
Chlorobenzene ND ug/L 1 07/10/09 04:57 108-90-70.50
Chloroethane ND ug/L 1 07/10/09 04:57 75-00-31.0
Chloroform ND ug/L 1 07/10/09 04:57 67-66-30.50
Chloromethane ND ug/L 1 07/10/09 04:57 74-87-31.0
2-Chlorotoluene ND ug/L 1 07/10/09 04:57 95-49-80.50
4-Chlorotoluene ND ug/L 1 07/10/09 04:57 106-43-40.50
1,2-Dibromo-3-chloropropane ND ug/L 1 07/10/09 04:57 96-12-81.0
Dibromochloromethane ND ug/L 1 07/10/09 04:57 124-48-10.50
1,2-Dibromoethane (EDB)ND ug/L 1 07/10/09 04:57 106-93-40.50
Dibromomethane ND ug/L 1 07/10/09 04:57 74-95-30.50
1,2-Dichlorobenzene ND ug/L 1 07/10/09 04:57 95-50-10.50
1,3-Dichlorobenzene ND ug/L 1 07/10/09 04:57 541-73-10.50
1,4-Dichlorobenzene ND ug/L 1 07/10/09 04:57 106-46-70.50
Dichlorodifluoromethane ND ug/L 1 07/10/09 04:57 75-71-80.50
1,1-Dichloroethane ND ug/L 1 07/10/09 04:57 75-34-30.50
1,2-Dichloroethane ND ug/L 1 07/10/09 04:57 107-06-20.50
1,1-Dichloroethene ND ug/L 1 07/10/09 04:57 75-35-40.50
cis-1,2-Dichloroethene ND ug/L 1 07/10/09 04:57 156-59-20.50
trans-1,2-Dichloroethene ND ug/L 1 07/10/09 04:57 156-60-50.50
1,2-Dichloropropane ND ug/L 1 07/10/09 04:57 78-87-50.50
1,3-Dichloropropane ND ug/L 1 07/10/09 04:57 142-28-90.50
2,2-Dichloropropane ND ug/L 1 07/10/09 04:57 594-20-70.50
1,1-Dichloropropene ND ug/L 1 07/10/09 04:57 563-58-60.50
cis-1,3-Dichloropropene ND ug/L 1 07/10/09 04:57 10061-01-50.50
trans-1,3-Dichloropropene ND ug/L 1 07/10/09 04:57 10061-02-60.50
Diisopropyl ether ND ug/L 1 07/10/09 04:57 108-20-30.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/16/2009 10:46 AM Page 12 of 23
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9247853
FOUR CORNERS STORE 12610
Sample:WSW-2 Lab ID:9247853005 Collected:07/01/09 11:30 Received:07/02/09 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Ethylbenzene ND ug/L 1 07/10/09 04:57 100-41-40.50
Hexachloro-1,3-butadiene ND ug/L 1 07/10/09 04:57 87-68-32.0
Isopropylbenzene (Cumene)ND ug/L 1 07/10/09 04:57 98-82-80.50
p-Isopropyltoluene ND ug/L 1 07/10/09 04:57 99-87-60.50
Methylene Chloride ND ug/L 1 07/10/09 04:57 75-09-22.0
Methyl-tert-butyl ether ND ug/L 1 07/10/09 04:57 1634-04-40.50
Naphthalene ND ug/L 1 07/10/09 04:57 91-20-32.0
n-Propylbenzene ND ug/L 1 07/10/09 04:57 103-65-10.50
Styrene ND ug/L 1 07/10/09 04:57 100-42-50.50
1,1,1,2-Tetrachloroethane ND ug/L 1 07/10/09 04:57 630-20-60.50
1,1,2,2-Tetrachloroethane ND ug/L 1 07/10/09 04:57 79-34-50.50
Tetrachloroethene ND ug/L 1 07/10/09 04:57 127-18-40.50
Toluene ND ug/L 1 07/10/09 04:57 108-88-30.50
1,2,3-Trichlorobenzene ND ug/L 1 07/10/09 04:57 87-61-62.0
1,2,4-Trichlorobenzene ND ug/L 1 07/10/09 04:57 120-82-12.0
1,1,1-Trichloroethane ND ug/L 1 07/10/09 04:57 71-55-60.50
1,1,2-Trichloroethane ND ug/L 1 07/10/09 04:57 79-00-50.50
Trichloroethene ND ug/L 1 07/10/09 04:57 79-01-60.50
Trichlorofluoromethane ND ug/L 1 07/10/09 04:57 75-69-41.0
1,2,3-Trichloropropane ND ug/L 1 07/10/09 04:57 96-18-40.50
1,2,4-Trimethylbenzene ND ug/L 1 07/10/09 04:57 95-63-60.50
1,3,5-Trimethylbenzene ND ug/L 1 07/10/09 04:57 108-67-80.50
Vinyl chloride ND ug/L 1 07/10/09 04:57 75-01-41.0
m&p-Xylene ND ug/L 1 07/10/09 04:57 1330-20-71.0
o-Xylene ND ug/L 1 07/10/09 04:57 95-47-60.50
1,2-Dichloroethane-d4 (S)95 %1 07/10/09 04:57 17060-07-070-130
Dibromofluoromethane (S)102 %1 07/10/09 04:57 1868-53-770-130
4-Bromofluorobenzene (S)97 %1 07/10/09 04:57 460-00-470-130
Toluene-d8 (S)97 %1 07/10/09 04:57 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/16/2009 10:46 AM Page 13 of 23
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9247853
FOUR CORNERS STORE 12610
Sample:WSW-3 Lab ID:9247853006 Collected:07/01/09 11:50 Received:07/02/09 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 07/15/09 05:06100
Aliphatic (C09-C12)ND ug/L 1 07/15/09 05:06100
Aromatic (C09-C10)ND ug/L 1 07/15/09 05:06100
2,5-Dibromotoluene (PID)(S)98 %1 07/15/09 05:0670-130
2,5-Dibromotoluene (FID)(S)115 %1 07/15/09 05:0670-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead ND ug/L 1 07/06/09 21:01 7439-92-107/04/09 08:005.0
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 07/10/09 05:21 71-43-20.50
Bromobenzene ND ug/L 1 07/10/09 05:21 108-86-10.50
Bromochloromethane ND ug/L 1 07/10/09 05:21 74-97-50.50
Bromodichloromethane ND ug/L 1 07/10/09 05:21 75-27-40.50
Bromoform ND ug/L 1 07/10/09 05:21 75-25-20.50
Bromomethane ND ug/L 1 07/10/09 05:21 74-83-91.0
n-Butylbenzene ND ug/L 1 07/10/09 05:21 104-51-80.50
sec-Butylbenzene ND ug/L 1 07/10/09 05:21 135-98-80.50
tert-Butylbenzene ND ug/L 1 07/10/09 05:21 98-06-60.50
Carbon tetrachloride ND ug/L 1 07/10/09 05:21 56-23-50.50
Chlorobenzene ND ug/L 1 07/10/09 05:21 108-90-70.50
Chloroethane ND ug/L 1 07/10/09 05:21 75-00-31.0
Chloroform ND ug/L 1 07/10/09 05:21 67-66-30.50
Chloromethane ND ug/L 1 07/10/09 05:21 74-87-31.0
2-Chlorotoluene ND ug/L 1 07/10/09 05:21 95-49-80.50
4-Chlorotoluene ND ug/L 1 07/10/09 05:21 106-43-40.50
1,2-Dibromo-3-chloropropane ND ug/L 1 07/10/09 05:21 96-12-81.0
Dibromochloromethane ND ug/L 1 07/10/09 05:21 124-48-10.50
1,2-Dibromoethane (EDB)ND ug/L 1 07/10/09 05:21 106-93-40.50
Dibromomethane ND ug/L 1 07/10/09 05:21 74-95-30.50
1,2-Dichlorobenzene ND ug/L 1 07/10/09 05:21 95-50-10.50
1,3-Dichlorobenzene ND ug/L 1 07/10/09 05:21 541-73-10.50
1,4-Dichlorobenzene ND ug/L 1 07/10/09 05:21 106-46-70.50
Dichlorodifluoromethane ND ug/L 1 07/10/09 05:21 75-71-80.50
1,1-Dichloroethane ND ug/L 1 07/10/09 05:21 75-34-30.50
1,2-Dichloroethane ND ug/L 1 07/10/09 05:21 107-06-20.50
1,1-Dichloroethene ND ug/L 1 07/10/09 05:21 75-35-40.50
cis-1,2-Dichloroethene ND ug/L 1 07/10/09 05:21 156-59-20.50
trans-1,2-Dichloroethene ND ug/L 1 07/10/09 05:21 156-60-50.50
1,2-Dichloropropane ND ug/L 1 07/10/09 05:21 78-87-50.50
1,3-Dichloropropane ND ug/L 1 07/10/09 05:21 142-28-90.50
2,2-Dichloropropane ND ug/L 1 07/10/09 05:21 594-20-70.50
1,1-Dichloropropene ND ug/L 1 07/10/09 05:21 563-58-60.50
cis-1,3-Dichloropropene ND ug/L 1 07/10/09 05:21 10061-01-50.50
trans-1,3-Dichloropropene ND ug/L 1 07/10/09 05:21 10061-02-60.50
Diisopropyl ether ND ug/L 1 07/10/09 05:21 108-20-30.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/16/2009 10:46 AM Page 14 of 23
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9247853
FOUR CORNERS STORE 12610
Sample:WSW-3 Lab ID:9247853006 Collected:07/01/09 11:50 Received:07/02/09 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Ethylbenzene ND ug/L 1 07/10/09 05:21 100-41-40.50
Hexachloro-1,3-butadiene ND ug/L 1 07/10/09 05:21 87-68-32.0
Isopropylbenzene (Cumene)ND ug/L 1 07/10/09 05:21 98-82-80.50
p-Isopropyltoluene ND ug/L 1 07/10/09 05:21 99-87-60.50
Methylene Chloride ND ug/L 1 07/10/09 05:21 75-09-22.0
Methyl-tert-butyl ether ND ug/L 1 07/10/09 05:21 1634-04-40.50
Naphthalene ND ug/L 1 07/10/09 05:21 91-20-32.0
n-Propylbenzene ND ug/L 1 07/10/09 05:21 103-65-10.50
Styrene ND ug/L 1 07/10/09 05:21 100-42-50.50
1,1,1,2-Tetrachloroethane ND ug/L 1 07/10/09 05:21 630-20-60.50
1,1,2,2-Tetrachloroethane ND ug/L 1 07/10/09 05:21 79-34-50.50
Tetrachloroethene ND ug/L 1 07/10/09 05:21 127-18-40.50
Toluene ND ug/L 1 07/10/09 05:21 108-88-30.50
1,2,3-Trichlorobenzene ND ug/L 1 07/10/09 05:21 87-61-62.0
1,2,4-Trichlorobenzene ND ug/L 1 07/10/09 05:21 120-82-12.0
1,1,1-Trichloroethane ND ug/L 1 07/10/09 05:21 71-55-60.50
1,1,2-Trichloroethane ND ug/L 1 07/10/09 05:21 79-00-50.50
Trichloroethene ND ug/L 1 07/10/09 05:21 79-01-60.50
Trichlorofluoromethane ND ug/L 1 07/10/09 05:21 75-69-41.0
1,2,3-Trichloropropane ND ug/L 1 07/10/09 05:21 96-18-40.50
1,2,4-Trimethylbenzene ND ug/L 1 07/10/09 05:21 95-63-60.50
1,3,5-Trimethylbenzene ND ug/L 1 07/10/09 05:21 108-67-80.50
Vinyl chloride ND ug/L 1 07/10/09 05:21 75-01-41.0
m&p-Xylene ND ug/L 1 07/10/09 05:21 1330-20-71.0
o-Xylene ND ug/L 1 07/10/09 05:21 95-47-60.50
1,2-Dichloroethane-d4 (S)94 %1 07/10/09 05:21 17060-07-070-130
Dibromofluoromethane (S)102 %1 07/10/09 05:21 1868-53-770-130
4-Bromofluorobenzene (S)99 %1 07/10/09 05:21 460-00-470-130
Toluene-d8 (S)98 %1 07/10/09 05:21 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/16/2009 10:46 AM Page 15 of 23
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9247853
FOUR CORNERS STORE 12610
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/7603
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:9247853001, 9247853002, 9247853003, 9247853004, 9247853005, 9247853006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:305783
Associated Lab Samples:9247853001, 9247853002, 9247853003, 9247853004, 9247853005, 9247853006
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 07/09/09 21:03
1,1,1-Trichloroethane ug/L ND 0.50 07/09/09 21:03
1,1,2,2-Tetrachloroethane ug/L ND 0.50 07/09/09 21:03
1,1,2-Trichloroethane ug/L ND 0.50 07/09/09 21:03
1,1-Dichloroethane ug/L ND 0.50 07/09/09 21:03
1,1-Dichloroethene ug/L ND 0.50 07/09/09 21:03
1,1-Dichloropropene ug/L ND 0.50 07/09/09 21:03
1,2,3-Trichlorobenzene ug/L ND 2.0 07/09/09 21:03
1,2,3-Trichloropropane ug/L ND 0.50 07/09/09 21:03
1,2,4-Trichlorobenzene ug/L ND 2.0 07/09/09 21:03
1,2,4-Trimethylbenzene ug/L ND 0.50 07/09/09 21:03
1,2-Dibromo-3-chloropropane ug/L ND 1.0 07/09/09 21:03
1,2-Dibromoethane (EDB)ug/L ND 0.50 07/09/09 21:03
1,2-Dichlorobenzene ug/L ND 0.50 07/09/09 21:03
1,2-Dichloroethane ug/L ND 0.50 07/09/09 21:03
1,2-Dichloropropane ug/L ND 0.50 07/09/09 21:03
1,3,5-Trimethylbenzene ug/L ND 0.50 07/09/09 21:03
1,3-Dichlorobenzene ug/L ND 0.50 07/09/09 21:03
1,3-Dichloropropane ug/L ND 0.50 07/09/09 21:03
1,4-Dichlorobenzene ug/L ND 0.50 07/09/09 21:03
2,2-Dichloropropane ug/L ND 0.50 07/09/09 21:03
2-Chlorotoluene ug/L ND 0.50 07/09/09 21:03
4-Chlorotoluene ug/L ND 0.50 07/09/09 21:03
Benzene ug/L ND 0.50 07/09/09 21:03
Bromobenzene ug/L ND 0.50 07/09/09 21:03
Bromochloromethane ug/L ND 0.50 07/09/09 21:03
Bromodichloromethane ug/L ND 0.50 07/09/09 21:03
Bromoform ug/L ND 0.50 07/09/09 21:03
Bromomethane ug/L ND 1.0 07/09/09 21:03
Carbon tetrachloride ug/L ND 0.50 07/09/09 21:03
Chlorobenzene ug/L ND 0.50 07/09/09 21:03
Chloroethane ug/L ND 1.0 07/09/09 21:03
Chloroform ug/L ND 0.50 07/09/09 21:03
Chloromethane ug/L ND 1.0 07/09/09 21:03
cis-1,2-Dichloroethene ug/L ND 0.50 07/09/09 21:03
cis-1,3-Dichloropropene ug/L ND 0.50 07/09/09 21:03
Dibromochloromethane ug/L ND 0.50 07/09/09 21:03
Dibromomethane ug/L ND 0.50 07/09/09 21:03
Dichlorodifluoromethane ug/L ND 0.50 07/09/09 21:03
Diisopropyl ether ug/L ND 0.50 07/09/09 21:03
Ethylbenzene ug/L ND 0.50 07/09/09 21:03
Hexachloro-1,3-butadiene ug/L ND 2.0 07/09/09 21:03
Isopropylbenzene (Cumene)ug/L ND 0.50 07/09/09 21:03
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/16/2009 10:46 AM Page 16 of 23
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9247853
FOUR CORNERS STORE 12610
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:305783
Associated Lab Samples:9247853001, 9247853002, 9247853003, 9247853004, 9247853005, 9247853006
Matrix:Water
Analyzed
m&p-Xylene ug/L ND 1.0 07/09/09 21:03
Methyl-tert-butyl ether ug/L ND 0.50 07/09/09 21:03
Methylene Chloride ug/L ND 2.0 07/09/09 21:03
n-Butylbenzene ug/L ND 0.50 07/09/09 21:03
n-Propylbenzene ug/L ND 0.50 07/09/09 21:03
Naphthalene ug/L ND 2.0 07/09/09 21:03
o-Xylene ug/L ND 0.50 07/09/09 21:03
p-Isopropyltoluene ug/L ND 0.50 07/09/09 21:03
sec-Butylbenzene ug/L ND 0.50 07/09/09 21:03
Styrene ug/L ND 0.50 07/09/09 21:03
tert-Butylbenzene ug/L ND 0.50 07/09/09 21:03
Tetrachloroethene ug/L ND 0.50 07/09/09 21:03
Toluene ug/L ND 0.50 07/09/09 21:03
trans-1,2-Dichloroethene ug/L ND 0.50 07/09/09 21:03
trans-1,3-Dichloropropene ug/L ND 0.50 07/09/09 21:03
Trichloroethene ug/L ND 0.50 07/09/09 21:03
Trichlorofluoromethane ug/L ND 1.0 07/09/09 21:03
Vinyl chloride ug/L ND 1.0 07/09/09 21:03
1,2-Dichloroethane-d4 (S)%98 70-130 07/09/09 21:03
4-Bromofluorobenzene (S)%99 70-130 07/09/09 21:03
Dibromofluoromethane (S)%99 70-130 07/09/09 21:03
Toluene-d8 (S)%97 70-130 07/09/09 21:03
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
305784LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.150 100 60-140
1,1,1-Trichloroethane ug/L 52.550 105 60-140
1,1,2,2-Tetrachloroethane ug/L 52.050 104 60-140
1,1,2-Trichloroethane ug/L 51.750 103 60-140
1,1-Dichloroethane ug/L 53.850 108 60-140
1,1-Dichloroethene ug/L 46.950 94 60-140
1,1-Dichloropropene ug/L 46.750 93 60-140
1,2,3-Trichlorobenzene ug/L 51.750 103 60-140
1,2,3-Trichloropropane ug/L 49.750 99 60-140
1,2,4-Trichlorobenzene ug/L 52.450 105 60-140
1,2,4-Trimethylbenzene ug/L 55.250 110 60-140
1,2-Dibromo-3-chloropropane ug/L 49.650 99 60-140
1,2-Dibromoethane (EDB)ug/L 51.650 103 60-140
1,2-Dichlorobenzene ug/L 50.350 101 60-140
1,2-Dichloroethane ug/L 53.250 106 60-140
1,2-Dichloropropane ug/L 54.650 109 60-140
1,3,5-Trimethylbenzene ug/L 55.150 110 60-140
1,3-Dichlorobenzene ug/L 50.150 100 60-140
1,3-Dichloropropane ug/L 52.650 105 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/16/2009 10:46 AM Page 17 of 23
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9247853
FOUR CORNERS STORE 12610
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
305784LABORATORY CONTROL SAMPLE:
LCSSpike
1,4-Dichlorobenzene ug/L 49.350 99 60-140
2,2-Dichloropropane ug/L 45.050 90 60-140
2-Chlorotoluene ug/L 54.450 109 60-140
4-Chlorotoluene ug/L 55.550 111 60-140
Benzene ug/L 52.950 106 60-140
Bromobenzene ug/L 52.850 106 60-140
Bromochloromethane ug/L 47.550 95 60-140
Bromodichloromethane ug/L 51.950 104 60-140
Bromoform ug/L 49.650 99 60-140
Bromomethane ug/L 51.150 102 60-140
Carbon tetrachloride ug/L 49.950 100 60-140
Chlorobenzene ug/L 50.950 102 60-140
Chloroethane ug/L 51.650 103 60-140
Chloroform ug/L 52.850 106 60-140
Chloromethane ug/L 49.250 98 60-140
cis-1,2-Dichloroethene ug/L 55.750 111 60-140
cis-1,3-Dichloropropene ug/L 46.350 93 60-140
Dibromochloromethane ug/L 50.550 101 60-140
Dibromomethane ug/L 52.150 104 60-140
Dichlorodifluoromethane ug/L 52.550 105 60-140
Diisopropyl ether ug/L 47.550 95 60-140
Ethylbenzene ug/L 52.050 104 60-140
Hexachloro-1,3-butadiene ug/L 55.550 111 60-140
Isopropylbenzene (Cumene)ug/L 54.150 108 60-140
m&p-Xylene ug/L 106100 106 60-140
Methyl-tert-butyl ether ug/L 48.750 97 60-140
Methylene Chloride ug/L 47.850 96 60-140
n-Butylbenzene ug/L 46.850 94 60-140
n-Propylbenzene ug/L 54.750 109 60-140
Naphthalene ug/L 47.950 96 60-140
o-Xylene ug/L 47.750 95 60-140
p-Isopropyltoluene ug/L 55.350 111 60-140
sec-Butylbenzene ug/L 54.650 109 60-140
Styrene ug/L 46.150 92 60-140
tert-Butylbenzene ug/L 54.950 110 60-140
Tetrachloroethene ug/L 49.650 99 60-140
Toluene ug/L 52.050 104 60-140
trans-1,2-Dichloroethene ug/L 53.750 107 60-140
trans-1,3-Dichloropropene ug/L 46.450 93 60-140
Trichloroethene ug/L 51.850 104 60-140
Trichlorofluoromethane ug/L 53.450 107 60-140
Vinyl chloride ug/L 53.450 107 60-140
1,2-Dichloroethane-d4 (S)%102 70-130
4-Bromofluorobenzene (S)%98 70-130
Dibromofluoromethane (S)%100 70-130
Toluene-d8 (S)%101 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/16/2009 10:46 AM Page 18 of 23
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9247853
FOUR CORNERS STORE 12610
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
305785MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9247657008
305786
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 81 60-14067 1920ND16.1 13.4
1,1,1-Trichloroethane ug/L 20 92 60-14081 1320ND18.4 16.1
1,1,2,2-Tetrachloroethane ug/L 20 75 60-14063 1720ND15.0 12.6
1,1,2-Trichloroethane ug/L 20 80 60-14067 1820ND16.0 13.4
1,1-Dichloroethane ug/L 20 100 60-14091 920ND19.9 18.2
1,1-Dichloroethene ug/L 20 81 60-14075 820ND16.3 15.0
1,1-Dichloropropene ug/L 20 79 60-14073 920ND15.9 14.5
1,2,3-Trichlorobenzene ug/L 20 82 60-14087 620ND16.4 17.5
1,2,3-Trichloropropane ug/L 20 75 60-14067 1220ND15.0 13.3
1,2,4-Trichlorobenzene ug/L 20 83 60-14081 320ND16.9 16.5
1,2,4-Trimethylbenzene ug/L 20 84 60-14073 1320ND16.8 14.6
1,2-Dibromo-3-chloropropane ug/L 20 74 60-14074 .820ND14.9 14.7
1,2-Dibromoethane (EDB)ug/L 20 79 60-14069 1420ND15.9 13.8
1,2-Dichlorobenzene ug/L 20 84 60-14073 1420ND16.7 14.5
1,2-Dichloroethane ug/L 20 78 60-14067 1620ND15.6 13.3
1,2-Dichloropropane ug/L 20 83 60-14068 2020ND16.6 13.6
1,3,5-Trimethylbenzene ug/L 20 83 60-14073 1320ND16.6 14.6
1,3-Dichlorobenzene ug/L 20 86 60-14074 1520ND17.2 14.7
1,3-Dichloropropane ug/L 20 81 60-14069 1620ND16.2 13.8
1,4-Dichlorobenzene ug/L 20 82 60-14072 1320ND16.4 14.3
2,2-Dichloropropane ug/L 20 71 60-14081 1320ND14.2 16.1
2-Chlorotoluene ug/L 20 83 60-14075 1120ND16.7 14.9
4-Chlorotoluene ug/L 20 89 60-14079 1220ND17.8 15.8
Benzene ug/L 20 87 60-14071 2120ND17.4 14.1
Bromobenzene ug/L 20 79 60-14073 820ND15.9 14.6
Bromochloromethane ug/L 20 93 60-14069 3020ND18.5 13.7
Bromodichloromethane ug/L 20 80 60-14066 1920ND16.0 13.3
Bromoform ug/L 20 78 60-14066 1720ND15.7 13.3
Bromomethane ug/L 20 68 60-14073 720ND13.7 14.7
Carbon tetrachloride ug/L 20 96 60-14078 2120ND19.3 15.6
Chlorobenzene ug/L 20 86 60-14071 1920ND17.2 14.2
Chloroethane ug/L 20 75 60-14066 1220ND14.9 13.2
Chloroform ug/L 20 83 60-14073 1220ND16.5 14.6
Chloromethane ug/L M0206260-14054 1420ND12.4 10.7
cis-1,2-Dichloroethene ug/L 20 84 60-14072 1520ND16.7 14.4
cis-1,3-Dichloropropene ug/L 20 73 60-14065 1120ND14.6 13.0
Dibromochloromethane ug/L 20 80 60-14065 2120ND16.0 13.0
Dibromomethane ug/L 20 92 60-14074 2220ND18.4 14.7
Dichlorodifluoromethane ug/L M0206360-14053 1720ND12.6 10.6
Diisopropyl ether ug/L 20 72 60-14067 820ND14.4 13.3
Ethylbenzene ug/L 20 84 60-14070 1820ND16.7 13.9
Hexachloro-1,3-butadiene ug/L 20 76 60-140100 2720ND15.2 19.9
Isopropylbenzene (Cumene)ug/L 20 82 60-14069 1720ND16.4 13.8
m&p-Xylene ug/L 40 83 60-14068 2040ND33.4 27.3
Methyl-tert-butyl ether ug/L 20 73 60-14067 820ND14.5 13.4
Methylene Chloride ug/L 20 87 60-14073 1720ND17.3 14.7
n-Butylbenzene ug/L 20 79 60-14082 420ND15.8 16.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/16/2009 10:46 AM Page 19 of 23
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9247853
FOUR CORNERS STORE 12610
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
305785MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9247657008
305786
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Propylbenzene ug/L 20 85 60-14079 820ND17.1 15.7
Naphthalene ug/L 20 73 60-14079 720ND14.6 15.7
o-Xylene ug/L 20 78 60-14067 1520ND15.5 13.3
p-Isopropyltoluene ug/L 20 85 60-14082 520ND17.1 16.3
sec-Butylbenzene ug/L 20 86 60-14083 320ND17.1 16.6
Styrene ug/L 20 76 60-14061 2220ND15.3 12.2
tert-Butylbenzene ug/L 20 87 60-14082 520ND17.3 16.5
Tetrachloroethene ug/L 20 90 60-14071 2320ND18.0 14.2
Toluene ug/L 20 81 60-14066 2020ND16.3 13.3
trans-1,2-Dichloroethene ug/L 20 79 60-14069 1320ND15.8 13.9
trans-1,3-Dichloropropene ug/L 20 75 60-14066 1220ND14.9 13.2
Trichloroethene ug/L 20 89 60-14071 2220ND17.8 14.2
Trichlorofluoromethane ug/L 20 71 60-14064 1020ND14.2 12.9
Vinyl chloride ug/L 20 77 60-14068 1220ND15.3 13.6
1,2-Dichloroethane-d4 (S)%92 70-13095
4-Bromofluorobenzene (S)%102 70-13097
Dibromofluoromethane (S)%97 70-13098
Toluene-d8 (S)%98 70-13099
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/16/2009 10:46 AM Page 20 of 23
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9247853
FOUR CORNERS STORE 12610
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/4686
SM 3030C
EPA 200.7
200.7 MET 3030C
Associated Lab Samples:9247853001, 9247853002, 9247853003, 9247853004, 9247853005, 9247853006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:303742
Associated Lab Samples:9247853001, 9247853002, 9247853003, 9247853004, 9247853005, 9247853006
Matrix:Water
Analyzed
Lead ug/L ND 5.0 07/06/09 20:20
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
303743LABORATORY CONTROL SAMPLE:
LCSSpike
Lead ug/L 528500 106 85-115
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
303744MATRIX SPIKE SAMPLE:
MSSpike
Result
9247853002
Lead ug/L 596500 119 70-130ND
Parameter Units
Dup
Result QualifiersRPDResult
9247853001
303745SAMPLE DUPLICATE:
Lead ug/L NDND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/16/2009 10:46 AM Page 21 of 23
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9247853
FOUR CORNERS STORE 12610
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/3352
MADEP VPH
MADEP VPH
VPH NC Water
Associated Lab Samples:9247853001, 9247853002, 9247853003, 9247853004, 9247853005, 9247853006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:307803
Associated Lab Samples:9247853001, 9247853002, 9247853003, 9247853004, 9247853005, 9247853006
Matrix:Water
Analyzed
Aliphatic (C05-C08)ug/L ND 100 07/15/09 01:11
Aliphatic (C09-C12)ug/L ND 100 07/15/09 01:11
Aromatic (C09-C10)ug/L ND 100 07/15/09 01:11
2,5-Dibromotoluene (FID)(S)%111 70-130 07/15/09 01:11
2,5-Dibromotoluene (PID)(S)%93 70-130 07/15/09 01:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
307804LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
307805
Aliphatic (C05-C08)ug/L 322300 107 70-13098295 9 25
Aliphatic (C09-C12)ug/L 247300 82 30-13076229 8 25
Aromatic (C09-C10)ug/L ND100 78 70-13075ND 25
2,5-Dibromotoluene (FID)(S)%105 70-130104
2,5-Dibromotoluene (PID)(S)%90 70-13089
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/16/2009 10:46 AM Page 22 of 23
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALIFIERS
Pace Project No.:
Project:
9247853
FOUR CORNERS STORE 12610
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution ofthe sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
U - Indicates the compound was analyzed for, but not detected.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery was outside laboratory control limits.M0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 07/16/2009 10:46 AM Page 23 of 23
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]