RA-1070_6969_CA_MRP_20200115_GWMR 12-2019

WithersRavenel

Our People. Your Success. 
i115 MacKenan Drive | Cary, NC 27511 
t: 919.469.3340 | f: 919.467.6008 | www.withersravenel.com | License No. C‐0832 
Cary | Greensboro | Pittsboro | Raleigh | Wilmington

January 15, 2020 

State of North Carolina 
Department of Environmental Quality 
Federal & State Lead Program 
Division of Waste Management‐Underground Storage Tank Section  
1646 Mail Service Center 
Raleigh, North Carolina 27699‐1646 

Attn: Mr. Mark Petermann 

RE: SUBSEQUENT MONITORING REPORT 
Former Pernell Grocery 
561 Schloss Road 
Louisburg, Franklin County, North Carolina 
Groundwater Incident Number: 6969 
UST Number RA‐1070 
WR Project Number:  02170214.67 

Mr. Petermann: 

WithersRavenel, Inc. (WR) has completed groundwater and supply well sampling activities at the 
above referenced site associated with TA‐02 under NCDEQ Contract # N17005, approved by 
the UST Section on November 12, 2019.  The enclosed report summarizes the results of these 
recently completed activities.    

WR appreciates the opportunity to be of service to the Federal & State Lead Program.  Should 
you have any questions regarding the attached, please contact Matthew James at (919) 238‐
0335. 

Cordially, 
WithersRavenel
Kevin B. Buchanan G. Matthew James, PG 
Staff Environmental Scientist II Senior Geologist 

Former Pernell Grocery Incident # 6969 WR Project # 02170214.67 
Subsequent Monitoring Report  January 2020 
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TABLE OF CONTENTS 

A. SITE INFORMATION ....................................................................................................................................................... 1 
B. EXECUTIVE SUMMARY ................................................................................................................................................. 2 
C. SITE HISTORY AND CHARACTERIZATION ............................................................................................................. 5 
D. PRESENTATION OF CURRENT/COMPARISON TO HISTORICAL ASSESSMENT INFORMATION ...... 10 
E. CONCLUSIONS AND RECOMMENDATIONS ...................................................................................................... 12 

FIGURES 

Figure 1 General Location Map 
Figure 2 Site Map  
Figure 3 Groundwater Hydraulic Gradient Map (ft) – December 2019 
Figure 4 Groundwater Analytical Results – December 2019 
Figure 5 Groundwater Benzene Isoconcentration Map ‐ December 2019 
Figure 6 Total BTEX Isoconcentration Map – December 2019 
Figure 7 Receptor Map with Supply Well Analytical Results – December 2019 

TABLES 

Table B‐1 Site History – UST/AST System and Other Release Information 
Table B‐4 Summary of Groundwater Analytical Results  
Table B‐5 Public & Private Water Supply Well Information 
Table B‐7 Monitoring and Remediation Well Construction Information 
Table B‐9 Current & Historical Groundwater Elevations and Free Product Thickness’ 

APPENDICES 

Appendix A  Laboratory Analytical Report and Chain‐of‐Custody 
Appendix B    Copy of Field Notes 
Appendix C  Photographic Documentation 
Appendix D  General Standard Operating Procedures 

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B. EXECUTIVE SUMMARY 

1. Summary of Activities Associated with Current TA 

WithersRavenel, Inc. (WR) obtained groundwater samples from site monitoring wells and supply 
well samples from water supply wells located in proximity to the site during December 2019, in 
association with task authorization TA‐02.  

2. Soil, Groundwater and Free Product Assessment Information 

Soils 
No soil samples were collected in association with the current TA, however, data for soil samples 
collected during July 2015, in addition to data for samples retrieved during November 2014, 
show compounds at levels exceeding their respective Soil‐to‐Water Maximum Soil Contaminant 
Concentrations (MSCCs) extending from an area roughly northwest of MW‐7 and south of MW‐
8, to the southwestern corner of the property.  Benzene was reported in a single sample (WR‐
106, 17.5‐20 ft.) at a concentration in excess of the Residential MSCC for the chemical.  The 
highest concentrations of contaminants appear in near proximity to MW‐6.  Contaminants 
appear to extend into areas beneath the paved roadway surfaces of Ed Faulkner Road (west of 
the source area) and Schloss Road (south of the source area).  Soil contaminants do not appear to 
pose a vapor intrusion threat to the structure (home) located on the site. 

Groundwater 
Analytical data for groundwater samples tested for volatile organic compounds (VOCs) by 
SM6200B indicated the presence of one or more target compounds in samples obtained from 
wells MW‐7, MW‐8, MW‐9 and MW‐11.  One or more compounds identified in these wells 
were reported at concentrations exceeding their respective 2L Standards defined by NCAC Title 
15A, Subchapter 2L, Section .0202 (Water Quality Standards for Class GA Groundwater).  No 
compounds were reported at concentrations in excess of their respective Gross Contamination 
Levels (GCL); however, the presence of free product in monitoring well MW‐6 represents a GCL 
violation.   

The greatest concentrations of contaminants (during December 2019) were noted in the vicinity 
of monitoring wells MW‐6, MW‐7 and MW‐9, in proximity to, and hydraulically downgradient of, 
the former UST area.  Leaching of contaminants from impacted soils in the vicinity of these wells 
is likely contributing to the continued presence of groundwater contaminants at elevated 
concentrations.  Based on current data for groundwater samples obtained from site monitoring 
wells, the downgradient extent of contamination has not been defined to levels equivalent to the 
2L Standards to the north and east of MW‐11.   

Based on groundwater elevation measurements from December 27, 2019, groundwater flow 
appears to trend to the northeast through the site, consistent with previous assertions as to 
groundwater flow.   

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Free Product 

Free product has been measured in monitoring well MW‐6 in past monitoring events. Free 
product was also measured within monitoring well MW‐6 (0.67 ft) during the performance of the 
December 2019 groundwater sampling event.  This represents an increase observed in the well 
over that measured in May 2018 (0.11 ft).    

3. Receptor Information 

Several sampling events have been conducted in the past that have indicated chemical impact(s) 
to one or more water supply wells in proximity to the release area on site.  Petroleum 
compounds were detected in the original water supply well on the subject property in May 1996.  
The well was abandoned, and a new well (WSW‐5) was installed in February 1997.  Sampling of 
WSW‐5 in July 1997 indicated a benzene concentration above the 2L Standard.  No targeted 
compounds were detected in a sample collected from WSW‐5 that was utilized as drinking water 
for the animals kept on the property in October 2008.  WSW‐5 is currently inactive and not 
utilized for any purpose.  Data for samples obtained from supply wells in July 2015 indicated the 
presence of n‐butylbenzene in WSW‐3 and MTBE in WSW‐9.  Levels of these compounds did 
not exceed their respective 2L Standards.   

Analytical data for supply well samples collected from WSW‐3, WSW‐7, WSW‐8 and WSW‐9 in 
December 2019 did not indicate the presence of targeted compounds at concentrations 
exceeding laboratory method detection limit (MDL) for SM6200B.  While tasked with the 
collection of a supply well sample from WSW‐1, WR personnel found the well to be inactive and 
the property unoccupied during December 2019.   

4. Remediation Activities 

Two gasoline UST systems formerly located on the property were permanently closed by 
removal in May 1997.  These activities included the removal of the USTs, product lines, and 
former pump island.  WR supervised the performance of an Aggressive Fluid Vapor Recovery 
(AFVR) event during February 2016, during which a total of 1,426 gallons of petroleum‐impacted 
groundwater were recovered from monitoring wells MW‐6 and MW‐7.  While performance of 
the AFVR event resulted in the removal of free product and/or contaminated groundwater from 
areas near the source location, free product persists in MW‐6.   

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5. Recommendations 

Based on the results of assessment and monitoring activities conducted at the site in association 
with this TA, WR recommends the following: 

 Install a Type II monitoring well to the east of MW‐11 and north of MW‐12 in an effort 
to determine the downgradient extent of groundwater contamination. 
 As a precursor to remedial actions, perform a free product survey utilizing laser‐induced 
fluorescence (LIF) or through the installation and sampling of temporary monitoring wells 
focused on assessment of soils and groundwater surrounding MW‐6.   
 Following adequate assessment of free product at the location, perform a surfactant 
injection surrounding and to the northeast of monitoring well MW‐6 followed by an 
MMPE event to recover surfactant and free product.   
 Continue periodic monitoring of groundwater conditions at the site through collection 
and analysis of groundwater samples.  
 Continue periodic monitoring of supply wells located in proximity to the site through 
collection and analysis of supply well samples from wells WSW‐1 (if active), WSW‐3, 
WSW‐7, WSW‐8 and WSW‐9.  
 In the absence of other remedial actions, perform an additional AFVR event in the vicinity 
of the former tank pit area on MW‐6, MW‐7 and MW‐9, and as an interim measure, 
emplace Provectus® PRP™ Well Booms in MW‐7, MW‐8 and MW‐9.   

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C. SITE HISTORY AND CHARACTERIZATION 

WR completed interim remedial, sampling and assessment activities at the site on December 27, 
2019.  The following information summarizes the site history and characterization.   

1 UST Information 

Two gasoline USTs, of 560 and 300‐gallon capacities, were permanently closed by removal in 
May 1997.  A soil sample obtained beneath the former 560‐gallon UST location indicated 
gasoline range organics (GRO) as total petroleum hydrocarbons (TPH) at a level exceeding the 
minimum reportable concentration (RC) for TPH‐GRO.  Removal of the USTs was prompted by 
impact to the on‐site supply well by one or more petroleum compounds at levels above their 
respective 2L Standard(s).  The discovery of the impact to the supply well was made during May 
1996, and the USTs were identified during a subsequent soil boring investigation performed on 
the site by Mid‐Atlantic Associates (MAA).    

WR is not aware of any aboveground storage tanks (ASTs) located on the subject site.  Table B‐1 
includes information regarding the USTs reportedly formerly located on the property.  The 
location of the site imposed on the USGS Topographic Map for the vicinity is included as Figure 
1.  Site improvements, including former structures, USTs and monitoring wells installed in 
association with the site are depicted on Figure 2.  Photographs of site conditions during 
December 2019 are included in Appendix C.   

2.  Description of Release/General Assessment History 

Subsequent to closure of the USTs at the facility in May 1997, the following assessment 
activities have been performed at the location: 

 As presented in the August 28, 1997, "Report of Environmental Services for the Pernell 
Grocery Site", prepared by MAA, petroleum fuel compounds were detected in a former 
onsite water supply well.  A point‐of‐entry (POE) system was subsequently installed on the 
well on May 18, 1996.  In February 1997, a new supply well was installed on site (WSW‐5), 
the original well was abandoned and the POE system was removed.  Soil borings were 
advanced by MAA at this time to locate potential USTs on the southwest portion of the 
property. Two USTs and associated underground piping were identified,  
 On May 6, 1997, MAA supervised the removal of a 560‐gallon gasoline UST and 300‐gallon 
gasoline UST and the associated piping. Post closure soil samples indicated TPH‐GRO above 
the RC below the former 560‐gallon UST. A water sample was collected from the onsite 
supply well (WSW‐5) at the kitchen sink.  Analytical results indicated benzene at a 
concentration of 8 microgram per liter (µg/L).  The supply well was re‐sampled at the 
wellhead and at the kitchen sink on June 11, 1997.  Analytical results indicated targeted 
compounds above 2L Standards in each of these samples.  On July 3, 1997, the water supply 
well was extended to a depth of 585 ft below the land surface (bls) with an outer casing set 
at 500 ft bls.  Subsequent sampling at the kitchen sink continued to indicate benzene at 
levels above the 2L Standard, 
 MAA prepared a "Report of Environmental Services for the Pernell Grocery Site" dated April 
28, 1998.  Five monitoring wells were installed and sampled, and the onsite and four offsite 
supply wells were sampled.  Analytical results indicated targeted compounds above 2L 
Standards and GCLs in MW‐2 located in the vicinity of the former tank bed.  No targeted 
compounds were identified in the three water supply well samples obtained at the time, 

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 According to a June 3, 1999, NCDENR correspondence, bottled water service was supplied 
to the onsite residence beginning on June 4, 1999,  
 In June 2003, WR supervised the installation of a new water supply well (WSW‐7) located 
approximately 700 ft east‐northeast of the source area on site, on an adjacent parcel owned 
by Ms. Hill.  The property is currently vacant and undeveloped.  Water Supply Well WSW‐5 
was disconnected and is no longer used.  The new well (WSW‐7) is presently used on site 
and bottled water is no longer necessary.  Bottled water service was discontinued in August 
2003, 
 WR personnel were onsite on November 14, 2003 and May 24, 2005 to collect groundwater 
samples from the water supply wells (WSW‐1 through WSW‐4 and WSW‐6 and WSW‐7) 
located in the vicinity of the site.  Based on the laboratory analytical report, no targeted 
compounds were detected in the samples collected from WSW‐1, WSW‐2, WSW‐3, WSW‐6 
and WSW‐7. During the 2005 sampling event, it was determined that WSW‐2 is no longer in 
use and WSW‐4 had been properly abandoned. 
 WR completed a groundwater sampling event and receptor survey update on October 30, 
2008. Eight active supply wells were identified within 1000 ft of the site. Water samples 
were collected from WSW‐1, WSW‐3, WSW‐5 and WSW‐7.  During the sampling event, it 
was noted that the property owner of the site has numerous animals onsite and used WSW‐
5 for drinking water for the animals.  Analytical data for the supply well samples did not 
indicate the presence of targeted compounds at levels above the laboratory MDLs.  Samples 
were also collected from monitoring well MW‐5. Monitoring well MW‐1 was destroyed, and 
MW‐3 appears to be covered by an animal cage. Monitoring wells MW‐2 and MW‐4 were 
dry.  Data for MW‐5 did not show targeted compounds at levels above the laboratory MDL,   
 The monitoring well network and offsite water supply wells were sampled generally on an 
annual basis between 1999 and 2005 with MW‐2 being the only monitoring well with 
targeted compounds detected,  
 S&ME prepared a "Groundwater Monitoring Report" dated January 12, 2011.  Monitoring 
well MW‐5 was sampled.  Monitoring wells MW‐2 and MW‐4 were dry, while MW‐3 was 
not located and MW‐1 had been destroyed.  In addition, water supply wells WSW‐1, WSW‐3 
and WSW‐7 were sampled.  No targeted compounds were identified in any of the samples,  
 Crawford Environmental Services (CES) prepared a "Groundwater Monitoring Event 
Letter/Report", dated January 9, 2013.  Monitoring wells MW‐1 and MW‐3 could not be 
located and monitoring wells MW‐2, MW‐4 and MW‐5 were dry.  Water supply wells WSW‐
1, WSW‐3 and WSW‐7 were sampled.  Water supply well WSW‐5 could not be sampled as it 
was inactive.  The analytical report associated with the samples did not identify any targeted 
compounds.  CES performed a receptor survey for properties surrounding the site. Results of 
the survey included the following: 

o The site is currently utilized as a residence where exotic birds and other animals are 
raised on the property.  Groundcover is predominantly grass with some gravel driveways, 
o The adjacent properties to the northwest, west, and southeast consist of sparse 
residential land use.  The adjacent properties to the north, east, and south are 
characterized as agricultural and wooded properties,  
o No basements were observed in the vicinity of the site,  
o No schools, churches, daycares, locations of public assembly or other sensitive use 
properties are located within 1,500 ft of the site,  
o Eleven water supply wells have been observed within 1,000 ft of the site.  Of the eleven 
wells, seven were determined to be potable wells, three were determined to be inactive 
and one has been abandoned,  
o Municipal water is not available in the vicinity of the site,  

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o Un‐named surface water bodies (ponds) are located approximately 1,050 ft northwest, 
1,300 ft east‐northeast, 1,500 ft east‐southeast, and 1,500 ft west of the source area,  
o The site is not located in the Coast Plain Physiographic Region,  
o No wellhead protection areas were identified in the vicinity of the site. 

 CES returned to the site in August 2013 to install monitoring wells MW‐6 through MW‐9.  
Exploratory soil borings were used to select the source area well location (MW‐6).  
Monitoring wells MW‐2, MW‐4 and MW‐5 were abandoned.  MW‐1 was previously 
destroyed and MW‐3 could not be located.  Petroleum compounds were detected above the 
2L Standards in samples collected from MW‐6, MW‐7, MW‐8 and MW‐9 with GCL 
violations in MW‐6, MW‐7 and MW‐9, 
 During November 2014, WR supervised the installation of Type II monitoring wells MW‐10, 
MW‐11, MW‐12 and MW‐13, followed by the purging and sampling of wells MW‐7 through 
MW‐13, inclusive.  WR also supervised the installation of air sparge well AS‐1, observation 
wells OW‐1, OW‐2 and OW‐3, and soil vapor extraction (SVE) wells SVE‐1, SVE‐2 and SVE‐
3.  Four (4) soil samples were retrieved from discrete intervals within each of these soil 
borings for laboratory analysis.  Free product (0.58 ft.) was measured within MW‐6.  
Laboratory analytical results for soil samples obtained in association with the installation of 
AS‐1 and SVE‐3 revealed the presence of several targeted compounds in samples AS‐1 (14’), 
AS‐1 (20’), SVE‐3 (10’) and SVE‐3 (20’).  Benzene, reported at a level of 0.37 ppm in sample 
SVE‐3 (20’) was the only compound identified at a level exceeding the Soil‐to‐Water MSCC.  
Data for remaining samples did not show the presence of targeted compounds at levels 
above the laboratory MDLs for EPA Method 8260.  Analytical data for groundwater samples 
showed one or more targeted compounds at levels exceeding their respective 2L Standards 
in monitoring wells MW‐7, MW‐8, MW‐9, MW‐10, MW‐11 and MW‐12.  Two compounds ‐ 
1,2‐dibromoethane (EDB) and 1,2‐dichloroethane were reported at concentrations exceeding 
their respective GCLs in the sample retained from MW‐9.  Data for total lead analysis of 
samples by SM 6010C showed lead levels in excess of the 2L Standard for the element in 
each of the wells sampled.  These levels ranged from 61 µg/L (MW‐8) to 380 µg/L (MW‐13).  
The elevated lead levels in these samples may be related to increased turbidity relating to the 
hand‐bailing of the wells, in addition to the potential for naturally occurring lead in the soils 
of the site.   
 WR supervised the installation of eleven soil borings (WR‐100 through WR‐110) during July 
2015, followed by the installation of monitoring wells MW‐14, MW‐15 and MW‐16, gauging, 
purging and sampling of all available monitoring wells at the site, and the purging and 
sampling of supply wells WSW‐1, WSW‐3, WSW‐7, WSW‐8 and WSW‐9.  Data for soil 
samples obtained from locations at the site indicated one or more targeted compounds in 37 
of the samples analyzed by EPA Method 8620.  Levels of one or more compounds detected 
in 21 of these samples were reported at concentrations exceeding their respective Soil‐to‐
Water MSCCs.  Benzene was reported in a single sample (WR‐106, 17.5‐20 ft.) at a 
concentration in excess of the Residential MSCC for the chemical.  The highest 
concentrations of soil contaminants appear in near proximity to MW‐6, extending to the 
north and southwest of the well.  Data for groundwater samples obtained from site wells 
showed one or more compounds targeted by SM6200B at levels exceeding their respective 
2L Standards in monitoring wells MW‐7, MW‐8, MW‐9 and MW‐11.  No compounds were 
reported at concentrations exceeding their respective GCLs; however, the presence of free 
product in MW‐6 (0.48 ft) represents a GCL violation.  Data for total lead analysis of samples 

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by SM 6010C showed lead levels in excess of the 2L Standard for the element in the sample 
from MW‐9 only.  Analytical data for the supply well samples obtained from wells WSW‐1, 
WSW‐7 and WSW‐8 on July 15, 2015 did not indicate the presence of any targeted 
compounds at levels above the MDL for SM6200B.  Data for wells WSW‐3 and WSW‐9 
showed the presence of n‐butylbenzene (WSW‐3) and MTBE (WSW‐9).  Levels of these 
compounds detected in the wells were beneath their respective 2L Standards.   
 WR obtained supply well samples from WSW‐3 and WSW‐9 to assess contaminant trends 
based on data for the July 2015 sampling of the wells.  Data for the sampling of these wells 
in October 2015 did not reveal the presence of targeted compounds at levels above the 
MDL for SM6200B.  
 Between February 23 and April 5, 2016, WR supervised the performance of an AFVR event, 
obtained groundwater samples from site monitoring wells, supply well samples from wells 
located in proximity to the site, and conducted SVE and AS pilot tests at the facility.  
Analytical data for groundwater samples tested for VOCs by SM6200B indicated the 
presence of one or more target compounds in samples obtained from wells MW‐6, MW‐7, 
MW‐8, MW‐9, MW‐11 and MW‐12.  One or more compounds identified in each of these 
wells were reported at concentrations exceeding their respective 2L Standards.  Benzene, 
1,2‐dibromoethane and 1,2‐dichloroethane were reported in the sample retained from MW‐
6 at concentrations exceeding their respective GCLs.   
 WR conducted a groundwater and supply well sampling event during April 2017.  Analytical 
data for groundwater samples tested for VOCs by SM6200B indicated the presence of one 
or more target compounds in samples obtained from wells MW‐7, MW‐8, MW‐9, MW‐11, 
MW‐12 and MW‐13.  One or more compounds identified in wells MW‐7, MW‐8, MW‐9 and 
MW‐11 were reported at concentrations exceeding their respective 2L Standards.  No 
compounds were reported at concentrations in excess of their respective GCLs; however, 
the presence of free product in monitoring well MW‐6 represents a GCL violation.  Data for 
SM6010C analysis of total lead showed the element present in samples obtained from wells 
MW‐7through MW‐16.  Levels of lead reported in samples from MW‐7through MW‐13 
were in excess of the 2L Standard for the element.  Analytical data for supply well samples 
obtained from WSW‐1, WSW‐3, WSW‐7, WSW‐8 and WSW‐9 did not indicate the presence 
of targeted compounds at levels above the MDL for SM6200B.   
 WR completed a groundwater and supply well sampling event at the site during May 2018.  
Free product measuring 0.11 ft was measured in monitoring well MW‐6.  Analytical data for 
groundwater samples tested for VOCs by SM6200B indicated the presence of one or more 
target compounds in samples obtained from wells MW‐7, MW‐8, MW‐9 and MW‐11.  One 
or more compounds identified in these samples were reported at concentrations exceeding 
their respective 2L Standards.  No compounds were reported at concentrations in excess of 
their respective GCLs; however, the presence of free product in monitoring well MW‐6 
represents a GCL violation.  Data for SM6010C analysis of total lead showed the element 
present in samples obtained from wells MW‐7through MW‐16.  Levels of lead reported in 
samples from these wells were in excess of the 2L Standard for the element.  WR believes 
the presence of lead in these samples to be representative of naturally occurring conditions 
at the site.  Analytical data for supply well samples obtained from WSW‐1, WSW‐3, WSW‐7, 
WSW‐8 and WSW‐9 did not indicate the presence of targeted compounds at levels above 
the MDL for SM6200B.   

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3.  Brief Description of Site Characteristics 

The property is located at 561 Schloss Road (SR‐1407) in an unincorporated rural 
residential/agricultural area of Louisburg, Franklin County, North Carolina (Figure 1).  The site 
includes a single‐story manufactured home of wood‐framed construction, several wood and 
aluminum outbuildings, and a mobile home (currently out‐of‐use).  A concrete slab (the former 
location of a mobile home) is located to the north of the house on the property.  The former UST 
area was located at the front of the site, southwest of the house onsite, near the intersection of 
Schloss Road and Ed Faulkner Road (SR 1410).  The site is covered primarily with a mixture of 
grass and bare (dirt and gravel) areas.  Several large trees are located across the site.  Site 
features, the former UST area, and monitoring well locations are depicted on Figure 2.  The 
Franklin County, NC Tax Department identifies the parcel comprising the site as PIN 2940‐14‐
2655.  The site and adjoining parcel to the east are both currently owned by Ms. Jannette Hill.   

4.  Information on Receptors/Potential Receptors 

CES performed an updated receptor survey in October 2012 and identified eleven water supply 
wells within 1,000 ft of the site.  Of the eleven wells, seven were determined to be potable wells, 
three to be inactive and one (WSW‐4) as having been abandoned.  Municipal water was not 
found to be available in the vicinity of the site.  Un‐named surface water bodies (ponds) are 
located approximately 1,050 ft northwest, 1,300 ft east‐northeast, 1,500 ft east‐southeast and 
1,500 ft west of the source area, respectively.  The site does not lie within the Coastal Plain 
Physiographic Region, and no wellhead protection areas were identified in the vicinity of the site.  
As properties within 1,000 ft of the source area rely on potable supply wells as their sole means 
of water supply, the site risk remains high.   

Private water supply well information is included in Table B‐5, and supply well locations are 
depicted on Figure 7.   

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D. PRESENTATION OF CURRENT/COMPARISON TO HISTORICAL 
ASSESSMENT INFORMATION 

On December 27, 2019, WR personnel mobilized to the subject site to perform assessment and 
sampling activities in accordance with task authorization TA‐02 under NCDEQ Contract # 
N17005.  Activities included those outlined below and described more thoroughly in the 
following sections: 

1 Groundwater Sampling and Analytical Results 

Monitoring Well Gauging  

On December 27, 2019, prior to the purging and sampling of monitoring wells, as described 
below, WR personnel opened and gauged the wells with an electronic water level indicator to 
determine the depth to groundwater within each of the wells.  In the performance of these 
activities, free product was measured within monitoring well MW‐6 (0.67 ft) gauged in 
association with groundwater sampling.    

The depth to groundwater measurements in these monitoring wells ranged from 30.56 ft below 
the top of casing (ft‐BTOC) in monitoring well MW‐14 to 40.69 ft‐BTOC in monitoring well 
MW‐10.  Based on groundwater elevation measurements from December 27, 2019, 
groundwater flow through the site appears to trend to the northeast.  These data confirm the 
trends identified by WR and previous consultants.  Groundwater elevation measurement data for 
the gauging of monitoring wells on the site are presented in Table B‐7.  Historical groundwater 
elevation measurements are included in Table B‐9.     

Monitoring Well Sampling  

WR personnel collected groundwater samples from monitoring wells MW‐7, MW‐8, MW‐9, 
MW‐10, MW‐11, MW‐12, MW‐13, MW‐14, MW‐15 and MW‐16 on December 27, 2019, 
following gauging and purging.  WR did not obtain a sample from MW‐6 due to the presence of 
free product in the well. Each well sampled was purged using separate disposable bailers as 
described in the procedures outlined in Appendix E.  Copies of field notes are included in 
Appendix B.  Following purging and adequate recharge of groundwater within each well, samples 
were decanted directly from the bailer(s) into laboratory‐prepared sample containers holding 
appropriate preservative(s) as required.  Groundwater samples obtained from site monitoring 
wells were submitted to Waypoint Analytical, LLC (Waypoint), formerly Prism Laboratories, Inc. 
for analysis by SM6200B (VOCs).  The laboratory analytical report and chain‐of‐custody record 
associated with these samples are included in Appendix A.  

Laboratory Results 

Analytical data for groundwater samples tested for VOCs by SM6200B indicated the presence of 
one or more target compounds in samples obtained from wells MW‐7, MW‐8, MW‐9 and MW‐
11.  One or more compounds identified in these samples were reported at concentrations 
exceeding their respective 2L Standards.  No compounds were reported at concentrations in 
excess of their respective GCLs; however, the presence of free product in monitoring well MW‐6 
represents a GCL violation.   

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The groundwater analytical results are summarized in Table B‐4 and shown on Figure 4.  
Isoconcentration maps depicting the estimated lateral extents of benzene and total BTEX in 
groundwater are included as Figures 5 and 6, respectively.  In general, based on total BTEX 
values for this groundwater sampling event compared to that conducted in May 2018, 
contaminant concentrations as reported through laboratory analysis increased moderately in 
MW‐8 and slightly in MW‐9,  but showed  a slight decrease in MW‐7, and substantial decrease 
in MW11. The changes in total BTEX in groundwater from May 2018 to December 2019 are 
shown in the following table: 

Change in Total BTEX Between May 2019 and December 2019 

Well ID Total BTEX May 2018 Total BTEX Dec. 2019 Change Percent Change 
MW‐6 Free Product Present Free Product Present 0.56 ft increase N/A 
MW‐7 31,190 30,600 Decrease ‐1.89 
MW‐8 3,898 4,920 Increase 26.22 
MW‐9 27,290 29,700 Increase 8.83 
MW‐11 402.88 150.3 Decrease -62.69 
MW‐12 ND ND Stable --- 
MW‐13 ND ND Stable --- 

Based on current data for groundwater samples obtained from site monitoring wells, the 
downgradient extent of contamination has not been defined to levels equivalent to the 2L 
Standards to the north and east of MW‐11.  Water levels measured at the location during 
December 2019 were generally consistent with those measured in May 2018.    

2 Supply Well Sampling and Analytical Results 

Supply Well Sampling  

WR personnel obtained supply well samples from wells WSW‐3, WSW‐7, WSW‐8 and WSW‐9 
on May 7, 2018, following purging.  As previously stated, WSW‐1 was out of service and the 
property unoccupied in December 2019, and, therefore, not sampled.  Each well was purged by 
allowing the associated well pump to run continuously for a minimum of ten minutes, after which 
samples were decanted directly from the sample point(s) into laboratory prepared sample 
containers holding appropriate preservative(s) as required.  Supply well samples were submitted 
to Waypoint for analysis by SM6200B.  The laboratory analytical report and chain‐of‐custody 
record associated with these samples are included in Appendix A.  

Laboratory Results 

Analytical data for supply well samples obtained from WSW‐3, WSW‐7, WSW‐8 and WSW‐9 
did not indicate the presence of targeted compounds at levels above the MDL for SM6200B.   

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E.  CONCLUSIONS AND RECOMMENDATIONS 

This report documents the results of field activities conducted at the site during December 2019, 
which included the performance of a site‐wide groundwater monitoring event and the collection 
and analysis of supply well samples from WSW‐3, WSW‐7, WSW‐8 and WSW‐9. Data obtained 
during these assessment and sampling activities combined with historical information show the 
following: 

 The site and surrounding properties rely exclusively on private water supply wells for 
provision of potable water.  Ten water supply wells have been identified within a 1,000‐foot 
(ft) radius of the site.  Of these ten supply wells, six are actively utilized as potable supplies 
and four are inactive.  Note: WSW‐1 may now be inactive as well.  No county or municipally‐
operated water supply system provides water service to the area surrounding the site.    
 Analytical data for supply well samples obtained during December 2019 did not indicate the 
presence of targeted compounds at levels above the MDL for SM6200B in any of the 
samples submitted for analysis. 
 On December 29, 2019, free product was measured in monitoring well MW‐6 (0.67 ft), 
which represents a GCL violation.  MW‐6 was not sampled because free product was 
present. 
 Gradient as modeled based on groundwater elevations measured on December 27, 2019 
appears to flow to the northeast through the site.  This trend is generally consistent with 
gradient as measured in previous monitoring events.  Based on this gradient, it appears that 
only WSW‐7 is located in a downgradient direction within 1,000 ft. 
 Data for groundwater samples obtained from site monitoring wells on December 27, 2019 
indicated the presence of one or more targeted VOCs in samples from wells MW‐7, MW‐8, 
MW‐9 and MW‐11 at concentrations exceeding their respective 2L Standards, 
 In general, based on total BTEX values for this groundwater sampling event compared to that 
conducted in May 2018, contaminant concentrations as reported through laboratory analysis 
have decreased slightly (1.9%) in MW‐7 but showed moderate to slight increases in MW‐8 
(26.2%) and MW‐9 (8.8%). 
 Based on current data for groundwater samples obtained from site monitoring wells, the 
downgradient extent of contamination has not been defined to levels equivalent to the 2L 
Standards to the north and east of MW‐11. 

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Based on the results of assessment and monitoring activities conducted at the site in association 
with this TA, WR recommends the following: 

 Install a Type II monitoring well to the east of MW‐11 and north of MW‐12 in an effort to 
determine the downgradient extent of groundwater contamination. 
 As a precursor to remedial actions, perform a free product survey utilizing laser‐induced 
fluorescence (LIF) or through the installation and sampling of temporary monitoring wells 
focused on assessment of soils and groundwater surrounding MW‐6.   
 Following adequate assessment of free product at the location, perform a surfactant injection 
surrounding and to the northeast of monitoring well MW‐6 followed by an MMPE event to 
recover surfactant and free product.   
 Continue periodic monitoring of groundwater conditions at the site through collection and 
analysis of groundwater samples.  
 Continue periodic monitoring of supply wells located in proximity to the site through 
collection and analysis of supply well samples from wells WSW‐1 (if active), WSW‐3, WSW‐
7, WSW‐8 and WSW‐9.  
 In the absence of other remedial actions, perform an additional AFVR event in the vicinity of 
the former tank pit area on MW‐6, MW‐7 and MW‐9, and as an interim measure, emplace 
Provectus® PRP™ Well Booms in MW‐7, MW‐8 and MW‐9.   

FIGURES 

TABLES 
UST IDNumberCurrent/LastContentsPreviousContentsCapacity(in gallons)ConstructionDetailsTankDimensions (diameter x length) (ft)Description ofAssociatedPiping & PumpsDate of TankInstallationStatus ofUSTWas release associated with UST System? (Y/N)1 Gasoline Unknown 560Single Walled Steel3.5 x 7.6 Not Provided UnknownPermanently Closed by Removal (5/6/97)Y2 Gasoline Unknown 300Single Walled Steel3 x 5.6 Not Provided UnknownPermanently Closed by Removal (5/6/97)YAST IDNumberCurrent/LastContentsPreviousContentsCapacity(in gallons)ConstructionDetailsTankDimensions (diameter x length) (ft)Description ofAssociatedPiping & PumpsDate of TankInstallationStatus ofASTWas release associated with AST System? (Y/N)N/A N/A N/A N/A N/A N/A N/A N/A N/A‐‐‐IncidentNumberMaterialReleasedDateofRelease6969 GASOLINE UnknownNotes:1.) Incident Number: 6969Description of ReleaseWR is not aware of any ASTs currently or formerly associated with the subject site.Table B‐1Site History:  UST/AST System & Other Release InformationPERNELL GROCERYA release of petroleum product was discovered in 1996 when a water sample obtained from the on‐site supply well was found to contain petroleum compounds.  A release was confirmed when analysis of soil samples obtained during UST closure proceedings in May 1997 showed gasoline range TPH at levels exceeding the minimum reportable concentration.561 Schloss RoadLouisburg, Franklin County, North CarolinaPage 1 of 1
       6010CCalculatedLeadBenzenen‐Butylbenzenesec‐Butylbenzenetert‐Butylbenzene1,2‐Dibromoethane1,2‐DichloroethaneDi‐isopropyl etherEthylbenzene2‐HexanoneIsopropylbenzenep‐Isopropyltoluene2‐Butanone (MEK)4‐Methyl‐2‐pentanone (MIBK)Methyl tert‐butyl etherNaphthalenen‐PropylbenzeneStyreneToluene1,2,4‐Trimethylbenzene1,3,5‐TrimethylbenzeneTotal Xylene7439‐92‐171‐43‐2104‐51‐8135‐98‐898‐06‐6106‐93‐4107‐06‐2 108‐20‐3100‐41‐4591‐78‐698‐82‐899‐87‐678‐93‐3108‐10‐1 1634‐04‐491‐20‐3103‐65‐1100‐42‐5108‐88‐395‐63‐6 108‐67‐8NA7/15/20153/15/201642119700<50 <50 <508871670377 2480NR72.1<501130<500 <50619 195<5020400 1460 430 100904/20/20175/7/201812/27/201911/24/2014130 390<50 <50 <50 <50 <50 <501600NR62<50 <500 <500 <50600 96<507800 890 320 71007/15/201512 200<100 <100 <100 <100 <100 <1001400NR <100 <100 <1000 <1000 <100 <500100<1006400 860 280 65003/15/201613.6 2650<50 <50 <50 <50110<501420NR56<50 <500 <500 <50427 89.4<5010000 767 256 61904/20/201769.8 1100 9.14<20 <20 <2012.9<201560NR57 11<200 <200 <20588 103<2015700 917 275 68205/7/201865.7 2040<200 <200 <200 <200 <200 <2001830<2000 <200 <200 <2000 <2000 <200 <1000 <200 <20018700 974 296 862012/27/2019NA1400<7.6 <7.6 <8.8 <5.1 <6.6 <5.0 2200 140 84<8.9 <24 <100 <4.2 560 130<5017000 1100 340 1000011/24/201461 55 6.4 5.3<5.0 <5.0 <5.0 <5.0520NR55 7.8<50 <50 <5.0300 75<5.0420 580 210 22407/15/201512<3.3 <10 <10 <10 <10 <10 <10240NR42 13<100 <100 <10130 50<1082 410 150 11603/15/201613.9 47.2<20 <20 <20 <20 <20 <20459NR60.7<20 <200 <200 <20252 88.9<20431 660 238 21724/20/201715.54.665.225.35<10 <10 <10 <10411NR57 9.17<100 <100 <10258 83.6<1078.4 658 231 20175/7/201873.8 86<25 <25 <25 <25 <25 <25562<25068.5<25 <250 <250 <25289 93.4<25347 762 276 290312/27/2019NA130 8.6 9.1<5 <0.51 <0.66 <0.50 700 92 83 16<2.4 42<0.42 340 120 5.9 490 900 320 360011/24/201491 2700 270 130 54200090002300 1300NR1600 200<5003000<50 <10002500 790 12000 730 6800 63007/15/201531 1800<50 <50 <50 <50 <50 <50910NR <50 <50 <500 <500 <50330 54<508300 570 180 44003/15/201623.8 2330<20 <20 <2041.5 109 24.6 1140NR49.1<20 <200 <200 <20419 85.5<209980 818 264 52604/20/201738.6 1860<100 <100 <100 <10064.5<1001160NR42.9<100 <1000 <1000 <100472 76.1<10010600 683 217 58705/7/2018177 2750<25 <25 <2537.3 97.9<251570<25059.4<25 <250 <250 <25501 87.8 29.9 15000 857 267 797012/27/2019NA3200<7.6 <7.6 <8.8 <50110<501900 150 66<8.9 <24 <100 <4.2 480 110<5016000 910 290 860011/24/2014220<1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NR <1.0 <1.0 <10 <10 <1.0 <5.0 <1.0 <1.0 <5.0 <1.01.2<2.07/15/2015<5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NR <1.0 <1.0 <10 <10 <1.0 <5.0 <1.0 <1.0 <5.0 <1.0 <1.0 <2.03/15/20165.17<1 <1 <1 <1 <1 <1 <1 <1 NR <1 <1 <10 <10 <1 <5 <1 <1 <5 <1 <1 <14/20/20179.23<1 <1 <1 <1 <1 <1 <1 <1 NR <1 <1 <10 <10 <1 <5 <1 <1 <1 <1 <1 <25/7/2018105<1 <1 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <10 <1 <5 <1 <1 <1 <1 <1 <212/27/2019NA <0.048 <0.076 <0.076 <0.088 <0.051 <0.066 <0.050 <0.061 <0.065 <0.054 <0.089 <0.24 <0.078 <0.042 <1 <0.087 <0.047 <0.044 <0.054 <0.076 <0.15 11/24/2014160 2.4<1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NR <1.0 <1.0 <10 <10 <1.0 <5.0 <1.0 <1.0 <5.0 <1.0 <1.03.87/15/2015<5.013<1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NR <1.0 <1.0 <10 <10 <1.0 <5.0 <1.0 <1.0 <5.05.6 1.9 26.43/15/20165.05 48<1 <1 <1 <12.7<17.61NR1.31<1 <10 <10 <18.02<1 <1 <518.8 6.88 94.14/20/20172.15 36<1 <1 <1 <11.27<15.88NR1.58<1 <10 <10 <18.23 0.613<11.14 23.6 9.25 95.45/7/201849.5 106<5 <5 <5 <5 <5 <531<50 <5 <5 <50 <50 <525.3<5 <55.68 52.8 20 260.212/27/2019NA50<0.076 <0.50 <0.088 0.66 2<0.5011 1.2 1.4<0.50 <0.24 <1 <0.042 7.6 1.1<0.047 1.3188.68811/24/2014200 7.4<1.0<1.0<1.0<1.0<1.0<1.0<1.0 NR1.1<1.0 <10 <10 <1.08.1<1.0 <1.0 <5.017 5.7 837/15/2015<5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NR <1.0 <1.0 <10 <10 <1.0 <5.0 <1.0 <1.0 <5.0 <1.0 <1.0 <2.03/15/201610.3 4.78<1 <1 <1 <1 <1 <1 <1 NR <1 <1 <10 <10 <15.25<1 <1 <512.3 3.48 56.14/20/201715.3<1 <1 <1 <1 <1 <1 <1 <1 NR <1 <1 <10 <10 <11.53<1 <10.775 0.375<1 <25/7/2018104<1 <1 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <10 <1 <5 <1 <1 <1 <1 <1 <212/27/2019NA <0.048 <0.076 <0.076 <0.088 <0.051 <0.066 <0.050 <0.061 <0.065 <0.054 <0.089 <0.24 <0.078 <0.042 <1 <0.087 <0.047 <0.044 <0.054 <0.076 <0.15 11/24/2014380<1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NR <1.0 <1.0 <10 <10 <1.0 <5.0 <1.0 <1.0 <5.0 <1.0 <1.02.37/15/2015<5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NR <1.0 <1.0 <10 <10 <1.0 <5.0 <1.0 <1.0 <5.0 <1.0 <1.0 <2.03/15/2016<5 <1 <1 <1 <1 <1 <1 <1 <1 NR <1 <1 <10 <10 <1 <5 <1 <1 <5 <1 <1 <24/20/201732.9<1 <1 <1 <1 <1 <1 <1 <1 NR <1 <1 <10 <10 <1 <5 <1 <10.479<1 <1 <25/7/2018285<1 <1 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <10 <1 <5 <1 <1 <1 <1 <1 <212/27/2019NA <0.048 <0.076 <0.076 <0.088 <0.051 <0.066 <0.050 <0.061 <0.065 <0.054 <0.089 <0.24 <0.078 <0.042 <1 <0.087 <0.047 <0.044 <0.054 <0.076 <0.15 15 1 70 70 70 0.02 0.4 70 600 40 70 25 4000 100 20 6 70 70 600 400 400 50015,000 5,000 6,900 8,500 15,000 50 400 70,000 84,500 40,000 25,000 11,700 4,000,000 100,000 20,000 6,000 3,000 70,000 260,000 28,500 25,000 85,500Notes:Result= Result Exceeds Laboratory Detection LimitsResult= Result Exceeds 2L StandardResult= Result Exceeds GCL ValueTABLE B‐4SUMMARY OF GROUNDWATER ANALYTICAL RESULTSPERNELL GROCERYIncident Number: 6969561 Schloss RoadNot Sampled ‐ Free Product Present in WellLouisburg, Franklin County, North CarolinaAnalytical MethodSampleIDDateCollectedNot Sampled ‐ Free Product Present in Well6200B ‐ Volatile Organic CompoundsMW‐10MW‐6MW‐7MW‐8MW‐9Not Sampled ‐ Free Product Present in WellMW‐11MW‐12MW‐13NC 2L Standard GCLs for Groundwater   1.) All results provided in ug/L (micrograms per liter) or parts per billion   2.) Compounds analyzed for by laboratory but not listed were not detected above laboratory detection limits. See the laboratory report included  in the Appendix for a full list of constituents.    3.) NC 2L Standard ‐ North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L   4.) GCLs for Groundwater = NCDEQ UST Section Gross Contamination Levels for GroundwaterPage 1 of 2
       6010CCalculatedLeadBenzenen‐Butylbenzenesec‐Butylbenzenetert‐Butylbenzene1,2‐Dibromoethane1,2‐DichloroethaneDi‐isopropyl etherEthylbenzene2‐HexanoneIsopropylbenzenep‐Isopropyltoluene2‐Butanone (MEK)4‐Methyl‐2‐pentanone (MIBK)Methyl tert‐butyl etherNaphthalenen‐PropylbenzeneStyreneToluene1,2,4‐Trimethylbenzene1,3,5‐TrimethylbenzeneTotal Xylene7439‐92‐171‐43‐2104‐51‐8135‐98‐898‐06‐6106‐93‐4107‐06‐2 108‐20‐3100‐41‐4591‐78‐698‐82‐899‐87‐678‐93‐3108‐10‐1 1634‐04‐491‐20‐3103‐65‐1100‐42‐5108‐88‐395‐63‐6 108‐67‐8NATABLE B‐4SUMMARY OF GROUNDWATER ANALYTICAL RESULTSPERNELL GROCERYIncident Number: 6969561 Schloss RoadLouisburg, Franklin County, North CarolinaAnalytical MethodSampleIDDateCollected6200B ‐ Volatile Organic Compounds7/15/2015<5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NR <1.0 <1.0 <10 <10 <1.0 <5.0 <1.0 <1.0 <5.0 <1.0 <1.0 <2.03/15/2016<5 <1 <1 <1 <1 <1 <1 <1 <1 NR <1 <1 <10 <10 <1 <5 <1 <1 <5 <1 <1 <24/20/201712.5<1 <1 <1 <1 <1 <1 <1 <1 NR <1 <1 <10 <10 <1 <5 <1 <1 <1 <1 <1 <25/7/201870.8<1 <1 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <10 <1 <5 <1 <1 <1 <1 <1 <212/27/2019NA <0.048 <0.076 <0.076 <0.088 <0.051 <0.066 <0.050 <0.061 <0.065 <0.054 <0.089 <0.24 <0.078 <1 <1 <0.087 <0.047 <0.044 <0.054 <0.076 <0.15 7/15/2015<5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NR <1.0 <1.0 <10 <10 <1.0 <5.0 <1.0 <1.0 <5.0 <1.0 <1.0 <2.03/15/2016<5 <1 <1 <1 <1 <1 <1 <1 <1 NR <1 <1 <10 <10 <1 <5 <1 <1 <5 <1 <1 <24/20/20176.25<1 <1 <1 <1 <1 <1 <1 <1 NR <1 <1 <10 <10 <1 <5 <1 <1 <1 <1 <1 <25/7/2018306<1 <1 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <10 <1 <5 <1 <1 <1 <1 <1 <212/27/2019NA <0.048 <0.076 <0.076 <0.088 <0.051 <0.066 <0.050 <0.061 <0.065 <0.054 <0.089 <0.24 <0.078 <0.042 <1 <0.087 <0.047 <0.044 <0.054 <0.076 <0.15 7/15/2015<5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NR <1.0 <1.0 <10 <10 <1.0 <5.0 <1.0 <1.0 <5.0 <1.0 <1.0 <2.03/15/2016<5 <1 <1 <1 <1 <1 <1 <1 <1 NR <1 <1 <10 <10 <1 <5 <1 <1 <5 <1 <1 <24/20/20173.07<1 <1 <1 <1 <1 <1 <1 <1 NR <1 <1 <10 <10 <1 <5 <1 <1 <1 <1 <1 <25/7/201836.4<1 <1 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <10 <1 <5 <1 <1 <1 <1 <1 <212/27/2019NA <0.048 <0.076 <0.076 <0.088 <0.051 <0.066 <0.050 <0.061 <0.065 <0.054 <0.089 <0.24 <0.078 <0.042 <1 <0.087 <0.047 <0.044 <0.054 <0.076 <0.15 7/15/2015NA <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NR <1.0 <1.0 <10 <10 <1.0 <5.0 <1.0 <1.0 <5.0 <1.0 <1.0 <2.03/15/2016NA <1 <1 <1 <1 <1 <1 <1 <1 NR <1 <1 <10 <10 <1 <5 <1 <1 <5 <1 <1 <24/20/2017NA <1 <1 <1 <1 <1 <1 <1 <1 NR <1 <1 <10 <10 <1 <5 <1 <1 <5 <1 <1 <25/7/2018NA <1 <1 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <10 <1 <5 <1 <1 <1 <1 <1 <211/24/2014NA <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NR <1.0 <1.0 <10 <10 <1.0 <5.0 <1.0 <1.0 <5.0 <1.0 <1.0 <2.07/15/2015NA <1.01.2<1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NR <1.0 <1.0 <10 <10 <1.0 <5.0 <1.0 <1.0 <5.022.6<2.010/6/2015NA <1 <1 <1 <1 <1 <1 <1 <1 NR <1 <1 <10 <10 <1 <5 <1 <1 <5 <1 <1 <23/15/2016NA <1 <1 <1 <1 <1 <1 <1 <1 NR <1 <1 <10 <10 <1 <5 <1 <1 <5 <1 <1 <24/20/2017NA <1 <1 <1 <1 <1 <1 <1 <1 NR <1 <1 <10 <10 <1 <5 <1 <1 <5 <1 <1 <25/7/2018NA <1 <1 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <10 <1 <5 <1 <1 <1 <1 <1 <212/27/2019NA <0.048 <0.076 <0.076 <0.088 <0.051 <0.066 <0.050 <0.061 <0.065 <0.054 <0.089 <0.24 <0.078 <0.042 <1 <0.087 <0.047 <0.044 <0.054 <0.076 <0.15 11/24/2014NA <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NR <1.0 <1.0 <10 <10 <1.0 <5.0 <1.0 <1.0 <5.0 <1.0 <1.0 <2.07/15/2015NA <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NR <1.0 <1.0 <10 <10 <1.0 <5.0 <1.0 <1.0 <5.0 <1.0 <1.0 <2.03/15/20164/20/2017NA <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NR <1.0 <1.0 <10 <10 <1.0 <5.0 <1.0 <1.0 <5.0 <1.0 <1.0 <2.05/7/2018NA <1 <1 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <10 <1 <5 <1 <1 <1 <1 <1 <212/27/2019NA <0.048 <0.076 <0.076 <0.088 <0.051 <0.066 <0.050 <0.061 <0.065 <0.054 <0.089 <0.24 <0.078 <0.042 <1 <0.087 <0.047 <0.044 <0.054 <0.076 <0.15 11/24/2014NA <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NR <1.0 <1.0 <10 <10 <1.0 <5.0 <1.0 <1.0 <5.0 <1.0 <1.0 <2.07/15/2015NA <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NR <1.0 <1.0 <10 <10 <1.0 <5.0 <1.0 <1.0 <5.0 <1.0 <1.0 <2.03/15/2016NA <1 <1 <1 <1 <1 <1 <1 <1 NR <1 <1 <10 <10 <1 <5 <1 <1 <5 <1 <1 <24/20/2017NA <1 <1 <1 <1 <1 <1 <1 <1 NR <1 <1 <10 <10 <1 <5 <1 <1 <5 <1 <1 <25/7/2018NA <1 <1 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <10 <1 <5 <1 <1 <1 <1 <1 <212/27/2019NA <0.048 <0.076 <0.076 <0.088 <0.051 <0.066 <0.050 <0.061 <0.065 <0.054 <0.089 <0.24 <0.078 <0.042 <1 <0.087 <0.047 <0.044 <0.054 <0.076 <0.15 7/15/2015NA <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NR <1.0 <1.0 <10 <101.1<5.0 <1.0 <1.0 <5.0 <1.0 <1.0 <2.010/6/2015NA <1 <1 <1 <1 <1 <1 <1 <1 NR <1 <1 <10 <10 <1 <5 <1 <1 <5 <1 <1 <23/15/2016NA <1 <1 <1 <1 <1 <1 <1 <1 NR <1 <1 <10 <10 <1 <5 <1 <1 <5 <1 <1 <24/20/2017NA <1 <1 <1 <1 <1 <1 <1 <1 NR <1 <1 <10 <10 <1 <5 <1 <1 <5 <1 <1 <25/7/2018NA <1 <1 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <10 <1 <5 <1 <1 <1 <1 <1 <212/27/2019NA <0.048 <0.076 <0.076 <0.088 <0.051 <0.066 <0.050 <0.061 <0.065 <0.054 <0.089 <0.24 <0.078 <0.042 <1 <0.087 <0.047 <0.044 <0.054 <0.076 <0.15 15 1 70 70 70 0.02 0.4 70 600 40 70 25 4000 100 20 6 70 70 600 400 400 50015,000 5,000 6,900 8,500 15,000 50 400 70,000 84,500 40,000 25,000 11,700 4,000,000 100,000 20,000 6,000 3,000 70,000 260,000 28,500 25,000 85,500NL 5 NLNL 5 NL 7 NLNLNLNLNLNL100NLNL 51,000510,000NLNLNotes:Result= Result Exceeds Laboratory Detection LimitsResult= Result Exceeds 2L StandardResult= Result Exceeds GCL ValueWSW‐8WSW‐9WSW‐1MW‐14MW‐15WSW‐3WSW‐7Not Sampled   4.) GCLs for Groundwater = NCDEQ UST Section Gross Contamination Levels for GroundwaterNC 2L Standard    1.) All results provided in ug/L (micrograms per liter) or parts per billion   2.) Compounds analyzed for by laboratory but not listed were not detected above laboratory detection limits. See the laboratory report included  in the Appendix for a full list of constituents.    3.) NC 2L Standard ‐ North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02LMW‐16   5.) US EPA Region IV MCL = Maximum Contaminant Level defined by US EPA Region IV, December 2009.  Standard as shown hereon applies only to supply well samples.US EPA Region IV MCLGCLs for GroundwaterPage 2 of 2
Easting NorthingWSW-1 011809525 Schloss Road Louisburg, NC 27549Ralton Harris525 Schloss Road Louisburg, NC 27549Potable(Active)Unknown Unknown 225 Upgradient 2240867.82 904719.10WSW-2 011793527 Schloss Road Louisburg, NC 27549The Fred Harris FamilyLLC527 Schloss Road Louisburg, NC 27549Potable(Inactive)Unknown Unknown 200 Upgradient 2241065.55 904499.75WSW-3 011793527 Schloss Road Louisburg, NC 27549The Fred Harris FamilyLLC527 Schloss Road Louisburg, NC 27549Potable(Active)Unknown Unknown 200 Upgradient 2241111.77 904468.57WSW-4 011796580 Schloss Road Louisburg, NC 27549The Fred Harris FamilyLLC527 Schloss Road Louisburg, NC 27549Abandoned Unknown Unknown 300WSW-5 012323561 Schloss Road Louisburg, NC 27549Jannette Hill561 schloss Road Louisburg, NC 27549Inactive Unknown Unknown 150 Downgradient 2241229.98 904708.81WSW-6 011917136 Harris LaneLouisburg, NC 27549Craig Salvesen & Aelish McKenna136 Harris LaneLouisburg, NC 27549Inactive Unknown Unknown 300 Upgradient 2241043.27 904292.64WSW-7 012334561 Schloss Road Louisburg, NC 27549Jannette Hill561 Schloss Road Louisburg, NC 27549Potable(Active)Unknown Unknown 350 Downgradient 2241866.24 904820.18WSW-8 012195514 Schloss RoadLouisburg, NC 27549Evelyn Pernell514 Schloss RoadLouisburg, NC 27549Potable(Active)Unknown Unknown 450 Upgradient 2240971.51 904176.91WSW-9 04117426 Harris LaneLouisburg, NC 27549Craig Salvesen & Aelish McKenna136 Harris LaneLouisburg, NC 27549Potable(Active)Unknown Unknown 550 Upgradient 2241008.39 904078.23WSW-10 011917136 Harris LaneLouisburg, NC 27549Craig Salvesen & Aelish McKenna136 Harris LaneLouisburg, NC 27549Inactive Unknown Unknown 450 Upgradient 2241093.31 904129.62WSW-11 01157213 Dement LaneLouisburg, NC 27549Ruby Dement13 Dement LaneLouisburg, NC 27549Potable(Active)Unknown Unknown 750 Upgradient 2240755.80 904030.28Incident Number: 6969Notes: 1.) Well location addresses and property owner information was obtained from the Franklin County GIS Department. Data current as of January 2, 2020.Well Coordinates(NC State Plane NAD 83 Feet)Property Owner AddressAbandonedTABLE B-5PUBLIC & PRIVATE WATER SUPPLY WELL INFORMATIONPERNELL GROCERY561 Schloss RoadLouisburg, Franklin County, North CarolinaWell Distance from Source Area(feet)ParcelNumberWell IDWell Depth(feet)Location Relative to Groundwater Flow 2.) Information regarding the water supply well's use and location was obtained from the field observations and previous consultants reports. 3.) WR did not perform a receptor survey in association with the current task authorization and thus the information provided above has not been verified. Well Screen Interval(feet)Well UseProperty Address Property OwnerPage 1 of 1
Easting NorthingMW‐1 2/19/1998 N/A 45 25 25 ‐ 45 100.00MW‐2 2/20/1998 N/A 33 23 23 ‐ 33 95.48MW‐3 2/20/1998 N/A 41 26 26 ‐ 41 99.13MW‐4 2/20/1998 N/A 33 23 23 ‐ 33 92.79MW‐5 2/23/1998 N/A 38 23 23 ‐ 38 96.96MW‐6 8/28/2013 2 50 30 30 ‐ 50 99.25 12/27/2019 32.89 0.67 66.93 2241239.89 904531.98MW‐7 8/28/2013 2 50 30 30 ‐ 50 99.23 12/27/2019 32.82‐‐‐66.41 2241264.14 904555.89MW‐8 8/28/2013 2 50 30 30 ‐ 50 101.30 12/27/2019 34.82‐‐‐66.48 2241215.22 904591.40MW‐9 8/28/2013 2 50 30 30 ‐ 50 99.25 12/27/2019 33.50‐‐‐65.75 2241272.43 904592.89MW‐10 11/20/2014 2 45 30 30 ‐ 45 104.43 12/27/2019 40.69‐‐‐63.74 2241200.37 904705.78MW‐11 11/21/2014 2 45 30 30 ‐ 45 101.08 12/27/2019 36.87‐‐‐64.21 2241284.56 904670.91MW‐12 11/21/2014 2 45 30 30 ‐ 45 98.09 12/27/2019 34.49‐‐‐63.60 2241378.19 904655.76MW‐13 11/21/2014 2 45 30 30 ‐ 45 99.23 12/27/2019 33.40‐‐‐65.83 2241378.68 904589.03MW‐14 7/14/2015 2 40 25 25 ‐ 40 97.82 12/27/2019 30.56‐‐‐67.26 2241282.05 904469.67MW‐15 7/14/2015 2 40 25 25 ‐ 40 101.46 12/27/2019 32.41‐‐‐69.05 2241152.93 904488.55MW‐16 7/14/2015 2 40 25 25 ‐ 40 102.41 12/27/2019 35.18‐‐‐67.23 2241137.84 904585.15AS‐1 11/22/2014 1 55 50 50‐55 NM‐‐‐NM‐‐‐ ‐‐‐2241244.69 904573.24SVE‐1 11/22/2014 2 30 5 5‐30 NM‐‐‐NM‐‐‐ ‐‐‐2241261.71 904572.87SVE‐2 11/22/2014 2 30 5 5‐30 NM‐‐‐NM‐‐‐ ‐‐‐2241252.47 904565.30SVE‐3 11/22/2014 2 30 5 5‐30 NM‐‐‐NM‐‐‐ ‐‐‐2241240.78 904548.29OW‐1 11/22/2014 2 45 40 40‐45 NM‐‐‐NM‐‐‐ ‐‐‐2241246.06 904584.35OW‐2 11/22/2014 2 45 40 40‐45 NM‐‐‐NM‐‐‐ ‐‐‐2241226.85 904581.14Well Reportedly DestroyedWell Reportedly AbandonedWell Reportedly AbandonedWell Reportedly AbandonedWell Reportedly AbandonedTABLE B‐7561 Schloss RoadMONITORING & REMEDIATION WELL CONSTRUCTION INFORMATIONWell Casing Diameter(inches)Free Product Thickness(feet)Screened Interval     (feet)PERNELL GROCERYGroundwaterElevation       (feet)Louisburg, Franklin County, North CarolinaWell Casing Depth (feet)Incident Number: 6969Date InstalledWell Coordinates(NC State Plane NAD 83 Feet)       4.) NM = Not MeasuredTotal Depth     (feet)       1.) Well construction information for MW‐1 through MW‐9 was obtained from previous consultants reports.       3.) Groundwater elevation calculated by: (Top‐of‐Casing ‐ Depth‐to‐Water) + (Free Product Thickness x 0.8581)Date Water Level MeasuredWell IDDepth‐to‐Water from Top‐of‐Casing(feet)Notes:        2.) Top‐of‐Casing elevations for MW‐10 through MW‐16 based on surveys performed by WR. Elevations of remaining wells adjusted based on current and previous surveys.Top‐of‐Casing Elevation      (feet)Page 1 of 1
Well ID Screened 
Interval
Top‐of‐Casing 
Elevation
Date Water Level 
Measured Depth‐to‐Product Depth‐to‐Water
(Beneath TOC)
Free Product 
Thickness
Groundwater 
Surface
Elevation          
(corrected)
MW‐125 ‐ 45 100.00
8/28/2013 ‐‐‐32.44 ‐‐‐66.81
11/24/2014 29.80 30.38 0.58 69.37
7/15/2015 26.35 26.83 0.48 72.83
3/15/2017 ‐‐‐26.33 ‐‐‐72.92
4/20/2017 30.73 31.10 0.37 68.47
5/7/2018 32.61 32.72 0.11 66.62
12/27/2019 32.22 32.89 0.67 66.93
8/28/2013 ‐‐‐32.52 ‐‐‐66.71
11/24/2014 ‐‐‐30.42 ‐‐‐68.81
7/15/2015 ‐‐‐26.84 ‐‐‐72.39
3/15/2017 ‐‐‐26.81 ‐‐‐72.42
4/20/2017 ‐‐‐31.22 ‐‐‐68.01
5/7/2018 ‐‐‐33.02 ‐‐‐66.21
12/27/2019 ‐‐‐32.82 ‐‐‐66.41
8/28/2013 ‐‐‐34.64 ‐‐‐66.66
11/24/2014 ‐‐‐32.16 ‐‐‐69.14
7/15/2015 ‐‐‐28.70 ‐‐‐72.60
3/15/2017 ‐‐‐28.41 ‐‐‐72.89
4/20/2017 ‐‐‐33.09 ‐‐‐68.21
5/7/2018 ‐‐‐34.87 ‐‐‐66.43
12/27/2019 ‐‐‐34.82 ‐‐‐66.48
8/28/2013 ‐‐‐33.36 ‐‐‐65.89
11/24/2014 ‐‐‐30.93 ‐‐‐68.32
7/15/2015 ‐‐‐27.45 ‐‐‐71.80
3/15/2017 ‐‐‐28.24 ‐‐‐71.01
4/20/2017 ‐‐‐31.81 ‐‐‐67.44
5/7/2018 ‐‐‐33.66 ‐‐‐65.59
12/27/2019 ‐‐‐33.50 ‐‐‐65.75
11/24/2014 ‐‐‐37.58 ‐‐‐66.85
7/15/2015 ‐‐‐34.25 ‐‐‐70.18
3/15/2017 ‐‐‐34.32 ‐‐‐70.11
4/20/2017 ‐‐‐38.63 ‐‐‐65.80
5/7/2018 ‐‐‐40.50 ‐‐‐63.93
12/27/2019 ‐‐‐40.69 ‐‐‐63.74
11/24/2014 ‐‐‐34.13 ‐‐‐66.95
7/15/2015 ‐‐‐30.60 ‐‐‐70.48
3/15/2017 ‐‐‐30.72 ‐‐‐70.36
4/20/2017 ‐‐‐35.02 ‐‐‐66.06
5/7/2018 ‐‐‐37.00 ‐‐‐64.08
12/27/2019 ‐‐‐36.87 ‐‐‐64.21
11/24/2014 ‐‐‐31.96 ‐‐‐66.13
7/15/2015 ‐‐‐28.44 ‐‐‐69.65
3/15/2017 ‐‐‐28.60 ‐‐‐69.49
4/20/2017 ‐‐‐32.77 ‐‐‐65.32
5/7/2018 ‐‐‐34.57 ‐‐‐63.52
12/27/2019 ‐‐‐34.49 ‐‐‐63.60
11/24/2014 ‐‐‐31.02 ‐‐‐68.21
7/15/2015 ‐‐‐27.52 ‐‐‐71.71
3/15/2017 ‐‐‐27.53 ‐‐‐71.70
4/20/2017 ‐‐‐31.84 ‐‐‐67.39
5/7/2018 ‐‐‐33.57 ‐‐‐65.66
12/27/2019 ‐‐‐33.40 ‐‐‐65.83
7/15/2015 ‐‐‐24.86 ‐‐‐72.96
3/15/2017 ‐‐‐25.02 ‐‐‐72.80
4/20/2017 ‐‐‐29.24 ‐‐‐68.58
5/7/2018 ‐‐‐31.03 ‐‐‐66.79
12/27/2019 ‐‐‐30.56 ‐‐‐67.26
7/15/2015 ‐‐‐26.54 ‐‐‐74.92
3/15/2017 ‐‐‐26.57 ‐‐‐74.89
4/20/2017 ‐‐‐31.00 ‐‐‐70.46
5/7/2018 ‐‐‐32.89 ‐‐‐68.57
12/27/2019 ‐‐‐32.41 ‐‐‐69.05
7/15/2015 ‐‐‐29.07 ‐‐‐73.34
3/15/2017 ‐‐‐29.99 ‐‐‐72.42
4/20/2017 ‐‐‐33.56 ‐‐‐68.85
5/7/2018 ‐‐‐35.28 ‐‐‐67.13
12/27/2019 ‐‐‐35.18 ‐‐‐67.23
1)
2)
3)
4)
5)
101.08
104.43
99.25
101.30
99.23
99.25
25 ‐ 40
25 ‐ 40 101.46
97.82
99.23
98.09
MW‐7
MW‐630 ‐ 50
30 ‐ 50
30 ‐ 50
30 ‐ 50
NM = Not Measured
MW‐16 25 ‐ 40 102.41
MW‐15
MW‐14
All measurements shown in feet
Notes: 
Groundwater elevation calculated by: (Top‐of‐Casing ‐ Depth‐to‐Water) + (Free Product Thickness x 0.8581)
Well construction information for MW‐1 through MW‐9 was obtained from previous consultants reports.
Top‐of‐Casing elevations for MW‐10 through MW‐16 based on surveys performed by WR. Elevations of remaining wells adjusted 
based on current and previous surveys.
TABLE B‐9
CURRENT & HISTORICAL GROUNDWATER ELEVATIONS & FREE PRODUCT THICKNESS
PERNELL GROCERY
561 Schloss Road
Louisburg, Franklin County, North Carolina
23 ‐ 33 92.79
WELL ABANDONEDMW‐2
Incident Number: 6969
Destroyed
23 ‐ 33 95.48
23 ‐ 38 96.96
MW‐3
WELL ABANDONED
Destroyed
MW‐4
MW‐5
99.13
WELL ABANDONED
26 ‐ 41
MW‐11
MW‐10
MW‐9
MW‐8
MW‐13
MW‐12
30 ‐ 45
30 ‐ 45
30 ‐ 45
30 ‐ 45
Page 1 of 1

APPENDIX A 

LABORATORY ANALYTICAL REPORT AND CHAIN‐OF‐
CUSTODY 
This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample
Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed
according to the referenced methods.
Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case
narrative.
NC Certification No. 402
NC Drinking Water Cert No. 37735
SC Certification No. 99012
Case Narrative
1/13/20 15:24
Withers & Ravenel
Kevin Buchanan
115 Mackenan Dr. BUILDING 117
Cary, NC 27511
Project: Pernell Grocery
Lab Submittal Date: 01/03/2020
Work Order: 0010028
Please call if you have any questions relating to this analytical report.
Respectfully,
WAYPOINT ANALYTICAL
Project Management Manager
Reviewed ByAngela D. Overcash Terri W. Cole For Angela D. Overcash
Project Manager
Data Qualifiers Key Reference:
Method Detection LimitMDL
Below Reporting LimitBRL
Relative Percent DifferenceRPD
*Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and
reporting limit indicated with a J.
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 1 of 43
Sample Receipt Summary
01/13/2020
Work Order: 0010028
Client Sample ID MatrixLab Sample ID Date/Time Sampled Date/Time Received
0010028-01 12/27/19 13:40MW-7 01/03/20 14:10Water
0010028-02 12/27/19 13:10MW-8 01/03/20 14:10Water
0010028-03 12/27/19 13:25MW-9 01/03/20 14:10Water
0010028-04 12/27/19 10:55MW-10 01/03/20 14:10Water
0010028-05 12/27/19 11:15MW-11 01/03/20 14:10Water
0010028-06 12/27/19 11:45MW-12 01/03/20 14:10Water
0010028-07 12/27/19 12:00MW-13 01/03/20 14:10Water
0010028-08 12/27/19 12:05MW-14 01/03/20 14:10Water
0010028-09 12/27/19 12:30MW-15 01/03/20 14:10Water
0010028-10 12/27/19 12:35MW-16 01/03/20 14:10Water
0010028-11 12/27/19 14:17WSW-7 01/03/20 14:10Water
0010028-12 12/27/19 14:28WSW-3 01/03/20 14:10Water
0010028-13 12/27/19 14:49WSW-8 01/03/20 14:10Water
0010028-14 12/27/19 14:55WSW-9 01/03/20 14:10Water
Samples were received in good condition at 2.2 degrees C unless otherwise noted.
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 2 of 43
Client ID ResultParameterMethod UnitsWaypoint ID
Work Order: 0010028
01/13/2020
Summary of Detections
1100 ug/L0010028-01 MW-7 1,2,4-Trimethylbenzene *SM6200 B
340 ug/L0010028-01 MW-7 1,3,5-Trimethylbenzene *SM6200 B
1400 ug/L0010028-01 MW-7 Benzene *SM6200 B
2200 ug/L0010028-01 MW-7 Ethylbenzene *SM6200 B
84 ug/L0010028-01 MW-7 Isopropylbenzene (Cumene)*SM6200 B
6900 ug/L0010028-01 MW-7 m,p-Xylenes *SM6200 B
140 ug/L0010028-01 MW-7 Methyl Butyl Ketone (2-Hexanone)*SM6200 B
560 ug/L0010028-01 MW-7 Naphthalene *SM6200 B
130 ug/L0010028-01 MW-7 n-Propylbenzene *SM6200 B
3100 ug/L0010028-01 MW-7 o-Xylene *SM6200 B
17000 ug/L0010028-01 MW-7 Toluene *SM6200 B
10000 ug/L0010028-01 MW-7 Xylenes, total *SM6200 B
900 ug/L0010028-02 MW-8 1,2,4-Trimethylbenzene *SM6200 B
320 ug/L0010028-02 MW-8 1,3,5-Trimethylbenzene *SM6200 B
16 ug/L0010028-02 MW-8 4-Isopropyltoluene *SM6200 B
130 ug/L0010028-02 MW-8 Benzene *SM6200 B
700 ug/L0010028-02 MW-8 Ethylbenzene *SM6200 B
83 ug/L0010028-02 MW-8 Isopropylbenzene (Cumene)*SM6200 B
2700 ug/L0010028-02 MW-8 m,p-Xylenes *SM6200 B
92 ug/L0010028-02 MW-8 Methyl Butyl Ketone (2-Hexanone)*SM6200 B
42 ug/L0010028-02 MW-8 Methyl Isobutyl Ketone *SM6200 B
340 ug/L0010028-02 MW-8 Naphthalene *SM6200 B
8.6 ug/L0010028-02 MW-8 n-Butylbenzene *SM6200 B
120 ug/L0010028-02 MW-8 n-Propylbenzene *SM6200 B
900 ug/L0010028-02 MW-8 o-Xylene *SM6200 B
9.1 ug/L0010028-02 MW-8 sec-Butylbenzene *SM6200 B
5.9 ug/L0010028-02 MW-8 Styrene *SM6200 B
490 ug/L0010028-02 MW-8 Toluene *SM6200 B
3600 ug/L0010028-02 MW-8 Xylenes, total *SM6200 B
910 ug/L0010028-03 MW-9 1,2,4-Trimethylbenzene *SM6200 B
110 ug/L0010028-03 MW-9 1,2-Dichloroethane *SM6200 B
290 ug/L0010028-03 MW-9 1,3,5-Trimethylbenzene *SM6200 B
3200 ug/L0010028-03 MW-9 Benzene *SM6200 B
1900 ug/L0010028-03 MW-9 Ethylbenzene *SM6200 B
66 ug/L0010028-03 MW-9 Isopropylbenzene (Cumene)*SM6200 B
5900 ug/L0010028-03 MW-9 m,p-Xylenes *SM6200 B
150 ug/L0010028-03 MW-9 Methyl Butyl Ketone (2-Hexanone)*SM6200 B
480 ug/L0010028-03 MW-9 Naphthalene *SM6200 B
110 ug/L0010028-03 MW-9 n-Propylbenzene *SM6200 B
2700 ug/L0010028-03 MW-9 o-Xylene *SM6200 B
16000 ug/L0010028-03 MW-9 Toluene *SM6200 B
8600 ug/L0010028-03 MW-9 Xylenes, total *SM6200 B
18 ug/L0010028-05 MW-11 1,2,4-Trimethylbenzene *SM6200 B
0.66 ug/L0010028-05 MW-11 1,2-Dibromoethane *SM6200 B
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 3 of 43
Client ID ResultParameterMethod UnitsWaypoint ID
Work Order: 0010028
01/13/2020
Summary of Detections
2.0 ug/L0010028-05 MW-11 1,2-Dichloroethane *SM6200 B
8.6 ug/L0010028-05 MW-11 1,3,5-Trimethylbenzene *SM6200 B
50 ug/L0010028-05 MW-11 Benzene *SM6200 B
11 ug/L0010028-05 MW-11 Ethylbenzene *SM6200 B
1.4 ug/L0010028-05 MW-11 Isopropylbenzene (Cumene)*SM6200 B
61 ug/L0010028-05 MW-11 m,p-Xylenes *SM6200 B
1.2 ug/L0010028-05 MW-11 Methyl Butyl Ketone (2-Hexanone)*SM6200 B
7.6 ug/L0010028-05 MW-11 Naphthalene *SM6200 B
1.1 ug/L0010028-05 MW-11 n-Propylbenzene *SM6200 B
27 ug/L0010028-05 MW-11 o-Xylene *SM6200 B
1.3 ug/L0010028-05 MW-11 Toluene *SM6200 B
88 ug/L0010028-05 MW-11 Xylenes, total *SM6200 B
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 4 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-7
Sample ID: 0010028-01
Work Order: 0010028
Time Collected: 12/27/19 13:40
Time Submitted: 01/03/20 14:10
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 111,1,1,2-Tetrachloroethane
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 6.11,1,1-Trichloroethane
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 3.61,1,2,2-Tetrachloroethane
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 6.61,1,2-Trichloroethane
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 8.31,1-Dichloroethane
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 8.31,1-Dichloroethylene
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 5.11,1-Dichloropropylene
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 401,2,3-Trichlorobenzene
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 141,2,3-Trichloropropane
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 131,2,4-Trichlorobenzene
1100 *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 5.41,2,4-Trimethylbenzene
BRL *SM6200 B P0A00971002001/7/20 20:41 ANGug/L 171,2-Dibromo-3-chloropropane
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 5.11,2-Dibromoethane
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 7.61,2-Dichlorobenzene
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 6.61,2-Dichloroethane
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 111,2-Dichloropropane
340 *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 7.61,3,5-Trimethylbenzene
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 5.41,3-Dichlorobenzene
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 4.31,3-Dichloropropane
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 5.01,4-Dichlorobenzene
BRL *SM6200 B P0A00971002001/7/20 20:41 ANGug/L 112,2-Dichloropropane
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 6.62-Chlorotoluene
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 5.04-Chlorotoluene
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 8.94-Isopropyltoluene
BRL *SM6200 B P0A009710010001/7/20 20:41 ANGug/L 31Acetone
1400 *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 4.8Benzene
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 5.7Bromobenzene
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 14Bromochloromethane
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 6.2Bromodichloromethane
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 4.0Bromoform
BRL *SM6200 B P0A00971001001/7/20 20:41 ANGug/L 18Bromomethane
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 11Carbon Tetrachloride
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 6.2Chlorobenzene
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 22Chloroethane
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 7.6Chloroform
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 7.9Chloromethane
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 5.6cis-1,2-Dichloroethylene
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 7.9cis-1,3-Dichloropropylene
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 8.1Dibromochloromethane
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 6.5Dibromomethane
BRL *SM6200 B P0A00971001001/7/20 20:41 ANGug/L 11Dichlorodifluoromethane
BRL *SM6200 B P0A0097100200001/7/20 20:41 ANGug/L 2700Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 5 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-7
Sample ID: 0010028-01
Work Order: 0010028
Time Collected: 12/27/19 13:40
Time Submitted: 01/03/20 14:10
2200 *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 6.1Ethylbenzene
BRL *SM6200 B P0A00971002001/7/20 20:41 ANGug/L 16Hexachlorobutadiene
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 5.0Isopropyl Ether
84 *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 5.4Isopropylbenzene (Cumene)
6900 *SM6200 B P0A00971001001/7/20 20:41 ANGug/L 12m,p-Xylenes
140 *SM6200 B P0A00971001001/7/20 20:41 ANGug/L 6.5Methyl Butyl Ketone (2-Hexanone)
BRL *SM6200 B P0A00971005001/7/20 20:41 ANGug/L 24Methyl Ethyl Ketone (2-Butanone)
BRL *SM6200 B P0A00971001001/7/20 20:41 ANGug/L 7.8Methyl Isobutyl Ketone
BRL *SM6200 B P0A00971002001/7/20 20:41 ANGug/L 8.3Methylene Chloride
BRL *SM6200 B P0A00971001001/7/20 20:41 ANGug/L 4.2Methyl-tert-Butyl Ether
560 *SM6200 B P0A00971001001/7/20 20:41 ANGug/L 19Naphthalene
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 7.6n-Butylbenzene
130 *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 8.7n-Propylbenzene
3100 *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 4.4o-Xylene
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 7.6sec-Butylbenzene
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 4.7Styrene
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 8.8tert-Butylbenzene
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 9.8Tetrachloroethylene
17000 *SM6200 B P0A009710005001/7/20 21:07 ANGug/L 44Toluene
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 7.0trans-1,2-Dichloroethylene
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 12trans-1,3-Dichloropropylene
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 7.8Trichloroethylene
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 6.2Trichlorofluoromethane
BRL *SM6200 B P0A00971005001/7/20 20:41 ANGug/L 6.0Vinyl acetate
BRL *SM6200 B P0A0097100501/7/20 20:41 ANGug/L 9.7Vinyl chloride
10000 *SM6200 B P0A00971001501/7/20 20:41 ANGug/L 15Xylenes, total
Surrogate Recovery Control Limits
70-13098 %4-Bromofluorobenzene
70-130100 %Dibromofluoromethane
70-130100 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 6 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-8
Sample ID: 0010028-02
Work Order: 0010028
Time Collected: 12/27/19 13:10
Time Submitted: 01/03/20 14:10
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 1.11,1,1,2-Tetrachloroethane
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.611,1,1-Trichloroethane
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.361,1,2,2-Tetrachloroethane
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.661,1,2-Trichloroethane
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.831,1-Dichloroethane
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.831,1-Dichloroethylene
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.511,1-Dichloropropylene
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 4.01,2,3-Trichlorobenzene
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 1.41,2,3-Trichloropropane
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 1.31,2,4-Trichlorobenzene
900 *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.541,2,4-Trimethylbenzene
BRL *SM6200 B P0A009710201/7/20 19:49 ANGug/L 1.71,2-Dibromo-3-chloropropane
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.511,2-Dibromoethane
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.761,2-Dichlorobenzene
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.661,2-Dichloroethane
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 1.11,2-Dichloropropane
320 *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.761,3,5-Trimethylbenzene
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.541,3-Dichlorobenzene
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.431,3-Dichloropropane
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.501,4-Dichlorobenzene
BRL *SM6200 B P0A009710201/7/20 19:49 ANGug/L 1.12,2-Dichloropropane
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.662-Chlorotoluene
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.504-Chlorotoluene
16 *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.894-Isopropyltoluene
BRL *SM6200 B P0A0097101001/7/20 19:49 ANGug/L 3.1Acetone
130 *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.48Benzene
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.57Bromobenzene
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 1.4Bromochloromethane
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.62Bromodichloromethane
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.40Bromoform
BRL *SM6200 B P0A009710101/7/20 19:49 ANGug/L 1.8Bromomethane
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 1.1Carbon Tetrachloride
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.62Chlorobenzene
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 2.2Chloroethane
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.76Chloroform
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.79Chloromethane
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.56cis-1,2-Dichloroethylene
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.79cis-1,3-Dichloropropylene
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.81Dibromochloromethane
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.65Dibromomethane
BRL *SM6200 B P0A009710101/7/20 19:49 ANGug/L 1.1Dichlorodifluoromethane
BRL *SM6200 B P0A00971020001/7/20 19:49 ANGug/L 270Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 7 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-8
Sample ID: 0010028-02
Work Order: 0010028
Time Collected: 12/27/19 13:10
Time Submitted: 01/03/20 14:10
700 *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.61Ethylbenzene
BRL *SM6200 B P0A009710201/7/20 19:49 ANGug/L 1.6Hexachlorobutadiene
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.50Isopropyl Ether
83 *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.54Isopropylbenzene (Cumene)
2700 *SM6200 B P0A00971001001/7/20 20:15 ANGug/L 12m,p-Xylenes
92 *SM6200 B P0A009710101/7/20 19:49 ANGug/L 0.65Methyl Butyl Ketone (2-Hexanone)
BRL *SM6200 B P0A009710501/7/20 19:49 ANGug/L 2.4Methyl Ethyl Ketone (2-Butanone)
42 *SM6200 B P0A009710101/7/20 19:49 ANGug/L 0.78Methyl Isobutyl Ketone
BRL *SM6200 B P0A009710201/7/20 19:49 ANGug/L 0.83Methylene Chloride
BRL *SM6200 B P0A009710101/7/20 19:49 ANGug/L 0.42Methyl-tert-Butyl Ether
340 *SM6200 B P0A009710101/7/20 19:49 ANGug/L 1.9Naphthalene
8.6 *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.76n-Butylbenzene
120 *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.87n-Propylbenzene
900 *SM6200 B P0A0097100501/7/20 20:15 ANGug/L 4.4o-Xylene
9.1 *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.76sec-Butylbenzene
5.9 *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.47Styrene
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.88tert-Butylbenzene
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.98Tetrachloroethylene
490 *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.44Toluene
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.70trans-1,2-Dichloroethylene
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 1.2trans-1,3-Dichloropropylene
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.78Trichloroethylene
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.62Trichlorofluoromethane
BRL *SM6200 B P0A009710501/7/20 19:49 ANGug/L 0.60Vinyl acetate
BRL *SM6200 B P0A0097105.0 1/7/20 19:49 ANGug/L 0.97Vinyl chloride
3600 *SM6200 B P0A00971001501/7/20 20:15 ANGug/L 15Xylenes, total
Surrogate Recovery Control Limits
70-13099 %4-Bromofluorobenzene
70-130100 %Dibromofluoromethane
70-130100 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 8 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-9
Sample ID: 0010028-03
Work Order: 0010028
Time Collected: 12/27/19 13:25
Time Submitted: 01/03/20 14:10
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 111,1,1,2-Tetrachloroethane
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 6.11,1,1-Trichloroethane
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 3.61,1,2,2-Tetrachloroethane
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 6.61,1,2-Trichloroethane
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 8.31,1-Dichloroethane
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 8.31,1-Dichloroethylene
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 5.11,1-Dichloropropylene
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 401,2,3-Trichlorobenzene
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 141,2,3-Trichloropropane
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 131,2,4-Trichlorobenzene
910 *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 5.41,2,4-Trimethylbenzene
BRL *SM6200 B P0A00971002001/7/20 21:33 ANGug/L 171,2-Dibromo-3-chloropropane
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 5.11,2-Dibromoethane
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 7.61,2-Dichlorobenzene
110 *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 6.61,2-Dichloroethane
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 111,2-Dichloropropane
290 *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 7.61,3,5-Trimethylbenzene
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 5.41,3-Dichlorobenzene
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 4.31,3-Dichloropropane
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 5.01,4-Dichlorobenzene
BRL *SM6200 B P0A00971002001/7/20 21:33 ANGug/L 112,2-Dichloropropane
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 6.62-Chlorotoluene
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 5.04-Chlorotoluene
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 8.94-Isopropyltoluene
BRL *SM6200 B P0A009710010001/7/20 21:33 ANGug/L 31Acetone
3200 *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 4.8Benzene
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 5.7Bromobenzene
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 14Bromochloromethane
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 6.2Bromodichloromethane
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 4.0Bromoform
BRL *SM6200 B P0A00971001001/7/20 21:33 ANGug/L 18Bromomethane
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 11Carbon Tetrachloride
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 6.2Chlorobenzene
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 22Chloroethane
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 7.6Chloroform
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 7.9Chloromethane
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 5.6cis-1,2-Dichloroethylene
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 7.9cis-1,3-Dichloropropylene
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 8.1Dibromochloromethane
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 6.5Dibromomethane
BRL *SM6200 B P0A00971001001/7/20 21:33 ANGug/L 11Dichlorodifluoromethane
BRL *SM6200 B P0A0097100200001/7/20 21:33 ANGug/L 2700Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 9 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-9
Sample ID: 0010028-03
Work Order: 0010028
Time Collected: 12/27/19 13:25
Time Submitted: 01/03/20 14:10
1900 *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 6.1Ethylbenzene
BRL *SM6200 B P0A00971002001/7/20 21:33 ANGug/L 16Hexachlorobutadiene
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 5.0Isopropyl Ether
66 *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 5.4Isopropylbenzene (Cumene)
5900 *SM6200 B P0A00971001001/7/20 21:33 ANGug/L 12m,p-Xylenes
150 *SM6200 B P0A00971001001/7/20 21:33 ANGug/L 6.5Methyl Butyl Ketone (2-Hexanone)
BRL *SM6200 B P0A00971005001/7/20 21:33 ANGug/L 24Methyl Ethyl Ketone (2-Butanone)
BRL *SM6200 B P0A00971001001/7/20 21:33 ANGug/L 7.8Methyl Isobutyl Ketone
BRL *SM6200 B P0A00971002001/7/20 21:33 ANGug/L 8.3Methylene Chloride
BRL *SM6200 B P0A00971001001/7/20 21:33 ANGug/L 4.2Methyl-tert-Butyl Ether
480 *SM6200 B P0A00971001001/7/20 21:33 ANGug/L 19Naphthalene
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 7.6n-Butylbenzene
110 *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 8.7n-Propylbenzene
2700 *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 4.4o-Xylene
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 7.6sec-Butylbenzene
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 4.7Styrene
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 8.8tert-Butylbenzene
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 9.8Tetrachloroethylene
16000 *SM6200 B P0A009710005001/7/20 22:00 ANGug/L 44Toluene
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 7.0trans-1,2-Dichloroethylene
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 12trans-1,3-Dichloropropylene
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 7.8Trichloroethylene
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 6.2Trichlorofluoromethane
BRL *SM6200 B P0A00971005001/7/20 21:33 ANGug/L 6.0Vinyl acetate
BRL *SM6200 B P0A0097100501/7/20 21:33 ANGug/L 9.7Vinyl chloride
8600 *SM6200 B P0A00971001501/7/20 21:33 ANGug/L 15Xylenes, total
Surrogate Recovery Control Limits
70-13099 %4-Bromofluorobenzene
70-130101 %Dibromofluoromethane
70-130100 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 10 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-10
Sample ID: 0010028-04
Work Order: 0010028
Time Collected: 12/27/19 10:55
Time Submitted: 01/03/20 14:10
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.111,1,1,2-Tetrachloroethane
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.0611,1,1-Trichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.0361,1,2,2-Tetrachloroethane
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.0661,1,2-Trichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.0831,1-Dichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.0831,1-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.0511,1-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.401,2,3-Trichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.141,2,3-Trichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.131,2,4-Trichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.0541,2,4-Trimethylbenzene
BRL *SM6200 B P0A009712.0 1/7/20 15:02 ANGug/L 0.171,2-Dibromo-3-chloropropane
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.0511,2-Dibromoethane
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.0761,2-Dichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.0661,2-Dichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.111,2-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.0761,3,5-Trimethylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.0541,3-Dichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.0431,3-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.0501,4-Dichlorobenzene
BRL *SM6200 B P0A009712.0 1/7/20 15:02 ANGug/L 0.112,2-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.0662-Chlorotoluene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.0504-Chlorotoluene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.0894-Isopropyltoluene
BRL *SM6200 B P0A00971101/7/20 15:02 ANGug/L 0.31Acetone
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.048Benzene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.057Bromobenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.14Bromochloromethane
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.062Bromodichloromethane
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.040Bromoform
BRL *SM6200 B P0A009711.0 1/7/20 15:02 ANGug/L 0.18Bromomethane
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.11Carbon Tetrachloride
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.062Chlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.22Chloroethane
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.076Chloroform
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.079Chloromethane
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.056cis-1,2-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.079cis-1,3-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.081Dibromochloromethane
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.065Dibromomethane
BRL *SM6200 B P0A009711.0 1/7/20 15:02 ANGug/L 0.11Dichlorodifluoromethane
BRL *SM6200 B P0A009712001/7/20 15:02 ANGug/L 27Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 11 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-10
Sample ID: 0010028-04
Work Order: 0010028
Time Collected: 12/27/19 10:55
Time Submitted: 01/03/20 14:10
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.061Ethylbenzene
BRL *SM6200 B P0A009712.0 1/7/20 15:02 ANGug/L 0.16Hexachlorobutadiene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.050Isopropyl Ether
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.054Isopropylbenzene (Cumene)
BRL *SM6200 B P0A009711.0 1/7/20 15:02 ANGug/L 0.12m,p-Xylenes
BRL *SM6200 B P0A009711.0 1/7/20 15:02 ANGug/L 0.065Methyl Butyl Ketone (2-Hexanone)
BRL *SM6200 B P0A009715.0 1/7/20 15:02 ANGug/L 0.24Methyl Ethyl Ketone (2-Butanone)
BRL *SM6200 B P0A009711.0 1/7/20 15:02 ANGug/L 0.078Methyl Isobutyl Ketone
BRL *SM6200 B P0A009712.0 1/7/20 15:02 ANGug/L 0.083Methylene Chloride
BRL *SM6200 B P0A009711.0 1/7/20 15:02 ANGug/L 0.042Methyl-tert-Butyl Ether
BRL *SM6200 B P0A009711.0 1/7/20 15:02 ANGug/L 0.19Naphthalene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.076n-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.087n-Propylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.044o-Xylene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.076sec-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.047Styrene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.088tert-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.098Tetrachloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.044Toluene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.070trans-1,2-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.12trans-1,3-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.078Trichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.062Trichlorofluoromethane
BRL *SM6200 B P0A009715.0 1/7/20 15:02 ANGug/L 0.060Vinyl acetate
BRL *SM6200 B P0A009710.50 1/7/20 15:02 ANGug/L 0.097Vinyl chloride
BRL *SM6200 B P0A009711.5 1/7/20 15:02 ANGug/L 0.15Xylenes, total
Surrogate Recovery Control Limits
70-130100 %4-Bromofluorobenzene
70-130102 %Dibromofluoromethane
70-130100 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 12 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-11
Sample ID: 0010028-05
Work Order: 0010028
Time Collected: 12/27/19 11:15
Time Submitted: 01/03/20 14:10
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.111,1,1,2-Tetrachloroethane
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.0611,1,1-Trichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.0361,1,2,2-Tetrachloroethane
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.0661,1,2-Trichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.0831,1-Dichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.0831,1-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.0511,1-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.401,2,3-Trichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.141,2,3-Trichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.131,2,4-Trichlorobenzene
18 *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.0541,2,4-Trimethylbenzene
BRL *SM6200 B P0A009712.0 1/7/20 15:28 ANGug/L 0.171,2-Dibromo-3-chloropropane
0.66 *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.0511,2-Dibromoethane
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.0761,2-Dichlorobenzene
2.0 *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.0661,2-Dichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.111,2-Dichloropropane
8.6 *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.0761,3,5-Trimethylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.0541,3-Dichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.0431,3-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.0501,4-Dichlorobenzene
BRL *SM6200 B P0A009712.0 1/7/20 15:28 ANGug/L 0.112,2-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.0662-Chlorotoluene
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.0504-Chlorotoluene
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.0894-Isopropyltoluene
BRL *SM6200 B P0A00971101/7/20 15:28 ANGug/L 0.31Acetone
50 *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.048Benzene
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.057Bromobenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.14Bromochloromethane
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.062Bromodichloromethane
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.040Bromoform
BRL *SM6200 B P0A009711.0 1/7/20 15:28 ANGug/L 0.18Bromomethane
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.11Carbon Tetrachloride
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.062Chlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.22Chloroethane
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.076Chloroform
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.079Chloromethane
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.056cis-1,2-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.079cis-1,3-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.081Dibromochloromethane
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.065Dibromomethane
BRL *SM6200 B P0A009711.0 1/7/20 15:28 ANGug/L 0.11Dichlorodifluoromethane
BRL *SM6200 B P0A009712001/7/20 15:28 ANGug/L 27Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 13 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-11
Sample ID: 0010028-05
Work Order: 0010028
Time Collected: 12/27/19 11:15
Time Submitted: 01/03/20 14:10
11 *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.061Ethylbenzene
BRL *SM6200 B P0A009712.0 1/7/20 15:28 ANGug/L 0.16Hexachlorobutadiene
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.050Isopropyl Ether
1.4 *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.054Isopropylbenzene (Cumene)
61 *SM6200 B P0A009711.0 1/7/20 15:28 ANGug/L 0.12m,p-Xylenes
1.2 *SM6200 B P0A009711.0 1/7/20 15:28 ANGug/L 0.065Methyl Butyl Ketone (2-Hexanone)
BRL *SM6200 B P0A009715.0 1/7/20 15:28 ANGug/L 0.24Methyl Ethyl Ketone (2-Butanone)
BRL *SM6200 B P0A009711.0 1/7/20 15:28 ANGug/L 0.078Methyl Isobutyl Ketone
BRL *SM6200 B P0A009712.0 1/7/20 15:28 ANGug/L 0.083Methylene Chloride
BRL *SM6200 B P0A009711.0 1/7/20 15:28 ANGug/L 0.042Methyl-tert-Butyl Ether
7.6 *SM6200 B P0A009711.0 1/7/20 15:28 ANGug/L 0.19Naphthalene
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.076n-Butylbenzene
1.1 *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.087n-Propylbenzene
27 *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.044o-Xylene
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.076sec-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.047Styrene
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.088tert-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.098Tetrachloroethylene
1.3 *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.044Toluene
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.070trans-1,2-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.12trans-1,3-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.078Trichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.062Trichlorofluoromethane
BRL *SM6200 B P0A009715.0 1/7/20 15:28 ANGug/L 0.060Vinyl acetate
BRL *SM6200 B P0A009710.50 1/7/20 15:28 ANGug/L 0.097Vinyl chloride
88 *SM6200 B P0A009711.5 1/7/20 15:28 ANGug/L 0.15Xylenes, total
Surrogate Recovery Control Limits
70-13099 %4-Bromofluorobenzene
70-130101 %Dibromofluoromethane
70-130100 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 14 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-12
Sample ID: 0010028-06
Work Order: 0010028
Time Collected: 12/27/19 11:45
Time Submitted: 01/03/20 14:10
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.111,1,1,2-Tetrachloroethane
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.0611,1,1-Trichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.0361,1,2,2-Tetrachloroethane
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.0661,1,2-Trichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.0831,1-Dichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.0831,1-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.0511,1-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.401,2,3-Trichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.141,2,3-Trichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.131,2,4-Trichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.0541,2,4-Trimethylbenzene
BRL *SM6200 B P0A009712.0 1/7/20 15:54 ANGug/L 0.171,2-Dibromo-3-chloropropane
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.0511,2-Dibromoethane
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.0761,2-Dichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.0661,2-Dichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.111,2-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.0761,3,5-Trimethylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.0541,3-Dichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.0431,3-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.0501,4-Dichlorobenzene
BRL *SM6200 B P0A009712.0 1/7/20 15:54 ANGug/L 0.112,2-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.0662-Chlorotoluene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.0504-Chlorotoluene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.0894-Isopropyltoluene
BRL *SM6200 B P0A00971101/7/20 15:54 ANGug/L 0.31Acetone
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.048Benzene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.057Bromobenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.14Bromochloromethane
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.062Bromodichloromethane
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.040Bromoform
BRL *SM6200 B P0A009711.0 1/7/20 15:54 ANGug/L 0.18Bromomethane
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.11Carbon Tetrachloride
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.062Chlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.22Chloroethane
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.076Chloroform
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.079Chloromethane
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.056cis-1,2-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.079cis-1,3-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.081Dibromochloromethane
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.065Dibromomethane
BRL *SM6200 B P0A009711.0 1/7/20 15:54 ANGug/L 0.11Dichlorodifluoromethane
BRL *SM6200 B P0A009712001/7/20 15:54 ANGug/L 27Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 15 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-12
Sample ID: 0010028-06
Work Order: 0010028
Time Collected: 12/27/19 11:45
Time Submitted: 01/03/20 14:10
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.061Ethylbenzene
BRL *SM6200 B P0A009712.0 1/7/20 15:54 ANGug/L 0.16Hexachlorobutadiene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.050Isopropyl Ether
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.054Isopropylbenzene (Cumene)
BRL *SM6200 B P0A009711.0 1/7/20 15:54 ANGug/L 0.12m,p-Xylenes
BRL *SM6200 B P0A009711.0 1/7/20 15:54 ANGug/L 0.065Methyl Butyl Ketone (2-Hexanone)
BRL *SM6200 B P0A009715.0 1/7/20 15:54 ANGug/L 0.24Methyl Ethyl Ketone (2-Butanone)
BRL *SM6200 B P0A009711.0 1/7/20 15:54 ANGug/L 0.078Methyl Isobutyl Ketone
BRL *SM6200 B P0A009712.0 1/7/20 15:54 ANGug/L 0.083Methylene Chloride
BRL *SM6200 B P0A009711.0 1/7/20 15:54 ANGug/L 0.042Methyl-tert-Butyl Ether
BRL *SM6200 B P0A009711.0 1/7/20 15:54 ANGug/L 0.19Naphthalene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.076n-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.087n-Propylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.044o-Xylene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.076sec-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.047Styrene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.088tert-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.098Tetrachloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.044Toluene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.070trans-1,2-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.12trans-1,3-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.078Trichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.062Trichlorofluoromethane
BRL *SM6200 B P0A009715.0 1/7/20 15:54 ANGug/L 0.060Vinyl acetate
BRL *SM6200 B P0A009710.50 1/7/20 15:54 ANGug/L 0.097Vinyl chloride
BRL *SM6200 B P0A009711.5 1/7/20 15:54 ANGug/L 0.15Xylenes, total
Surrogate Recovery Control Limits
70-130100 %4-Bromofluorobenzene
70-130102 %Dibromofluoromethane
70-130100 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 16 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-13
Sample ID: 0010028-07
Work Order: 0010028
Time Collected: 12/27/19 12:00
Time Submitted: 01/03/20 14:10
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.111,1,1,2-Tetrachloroethane
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.0611,1,1-Trichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.0361,1,2,2-Tetrachloroethane
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.0661,1,2-Trichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.0831,1-Dichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.0831,1-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.0511,1-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.401,2,3-Trichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.141,2,3-Trichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.131,2,4-Trichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.0541,2,4-Trimethylbenzene
BRL *SM6200 B P0A009712.0 1/7/20 16:20 ANGug/L 0.171,2-Dibromo-3-chloropropane
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.0511,2-Dibromoethane
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.0761,2-Dichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.0661,2-Dichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.111,2-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.0761,3,5-Trimethylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.0541,3-Dichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.0431,3-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.0501,4-Dichlorobenzene
BRL *SM6200 B P0A009712.0 1/7/20 16:20 ANGug/L 0.112,2-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.0662-Chlorotoluene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.0504-Chlorotoluene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.0894-Isopropyltoluene
BRL *SM6200 B P0A00971101/7/20 16:20 ANGug/L 0.31Acetone
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.048Benzene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.057Bromobenzene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.14Bromochloromethane
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.062Bromodichloromethane
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.040Bromoform
BRL *SM6200 B P0A009711.0 1/7/20 16:20 ANGug/L 0.18Bromomethane
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.11Carbon Tetrachloride
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.062Chlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.22Chloroethane
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.076Chloroform
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.079Chloromethane
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.056cis-1,2-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.079cis-1,3-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.081Dibromochloromethane
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.065Dibromomethane
BRL *SM6200 B P0A009711.0 1/7/20 16:20 ANGug/L 0.11Dichlorodifluoromethane
BRL *SM6200 B P0A009712001/7/20 16:20 ANGug/L 27Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 17 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-13
Sample ID: 0010028-07
Work Order: 0010028
Time Collected: 12/27/19 12:00
Time Submitted: 01/03/20 14:10
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.061Ethylbenzene
BRL *SM6200 B P0A009712.0 1/7/20 16:20 ANGug/L 0.16Hexachlorobutadiene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.050Isopropyl Ether
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.054Isopropylbenzene (Cumene)
BRL *SM6200 B P0A009711.0 1/7/20 16:20 ANGug/L 0.12m,p-Xylenes
BRL *SM6200 B P0A009711.0 1/7/20 16:20 ANGug/L 0.065Methyl Butyl Ketone (2-Hexanone)
BRL *SM6200 B P0A009715.0 1/7/20 16:20 ANGug/L 0.24Methyl Ethyl Ketone (2-Butanone)
BRL *SM6200 B P0A009711.0 1/7/20 16:20 ANGug/L 0.078Methyl Isobutyl Ketone
BRL *SM6200 B P0A009712.0 1/7/20 16:20 ANGug/L 0.083Methylene Chloride
BRL *SM6200 B P0A009711.0 1/7/20 16:20 ANGug/L 0.042Methyl-tert-Butyl Ether
BRL *SM6200 B P0A009711.0 1/7/20 16:20 ANGug/L 0.19Naphthalene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.076n-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.087n-Propylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.044o-Xylene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.076sec-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.047Styrene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.088tert-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.098Tetrachloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.044Toluene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.070trans-1,2-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.12trans-1,3-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.078Trichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.062Trichlorofluoromethane
BRL *SM6200 B P0A009715.0 1/7/20 16:20 ANGug/L 0.060Vinyl acetate
BRL *SM6200 B P0A009710.50 1/7/20 16:20 ANGug/L 0.097Vinyl chloride
BRL *SM6200 B P0A009711.5 1/7/20 16:20 ANGug/L 0.15Xylenes, total
Surrogate Recovery Control Limits
70-13099 %4-Bromofluorobenzene
70-130101 %Dibromofluoromethane
70-130100 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 18 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-14
Sample ID: 0010028-08
Work Order: 0010028
Time Collected: 12/27/19 12:05
Time Submitted: 01/03/20 14:10
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.111,1,1,2-Tetrachloroethane
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.0611,1,1-Trichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.0361,1,2,2-Tetrachloroethane
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.0661,1,2-Trichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.0831,1-Dichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.0831,1-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.0511,1-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.401,2,3-Trichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.141,2,3-Trichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.131,2,4-Trichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.0541,2,4-Trimethylbenzene
BRL *SM6200 B P0A009712.0 1/7/20 16:46 ANGug/L 0.171,2-Dibromo-3-chloropropane
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.0511,2-Dibromoethane
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.0761,2-Dichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.0661,2-Dichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.111,2-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.0761,3,5-Trimethylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.0541,3-Dichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.0431,3-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.0501,4-Dichlorobenzene
BRL *SM6200 B P0A009712.0 1/7/20 16:46 ANGug/L 0.112,2-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.0662-Chlorotoluene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.0504-Chlorotoluene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.0894-Isopropyltoluene
BRL *SM6200 B P0A00971101/7/20 16:46 ANGug/L 0.31Acetone
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.048Benzene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.057Bromobenzene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.14Bromochloromethane
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.062Bromodichloromethane
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.040Bromoform
BRL *SM6200 B P0A009711.0 1/7/20 16:46 ANGug/L 0.18Bromomethane
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.11Carbon Tetrachloride
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.062Chlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.22Chloroethane
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.076Chloroform
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.079Chloromethane
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.056cis-1,2-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.079cis-1,3-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.081Dibromochloromethane
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.065Dibromomethane
BRL *SM6200 B P0A009711.0 1/7/20 16:46 ANGug/L 0.11Dichlorodifluoromethane
BRL *SM6200 B P0A009712001/7/20 16:46 ANGug/L 27Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 19 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-14
Sample ID: 0010028-08
Work Order: 0010028
Time Collected: 12/27/19 12:05
Time Submitted: 01/03/20 14:10
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.061Ethylbenzene
BRL *SM6200 B P0A009712.0 1/7/20 16:46 ANGug/L 0.16Hexachlorobutadiene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.050Isopropyl Ether
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.054Isopropylbenzene (Cumene)
BRL *SM6200 B P0A009711.0 1/7/20 16:46 ANGug/L 0.12m,p-Xylenes
BRL *SM6200 B P0A009711.0 1/7/20 16:46 ANGug/L 0.065Methyl Butyl Ketone (2-Hexanone)
BRL *SM6200 B P0A009715.0 1/7/20 16:46 ANGug/L 0.24Methyl Ethyl Ketone (2-Butanone)
BRL *SM6200 B P0A009711.0 1/7/20 16:46 ANGug/L 0.078Methyl Isobutyl Ketone
BRL *SM6200 B P0A009712.0 1/7/20 16:46 ANGug/L 0.083Methylene Chloride
BRL *SM6200 B P0A009711.0 1/7/20 16:46 ANGug/L 0.042Methyl-tert-Butyl Ether
BRL *SM6200 B P0A009711.0 1/7/20 16:46 ANGug/L 0.19Naphthalene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.076n-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.087n-Propylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.044o-Xylene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.076sec-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.047Styrene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.088tert-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.098Tetrachloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.044Toluene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.070trans-1,2-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.12trans-1,3-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.078Trichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.062Trichlorofluoromethane
BRL *SM6200 B P0A009715.0 1/7/20 16:46 ANGug/L 0.060Vinyl acetate
BRL *SM6200 B P0A009710.50 1/7/20 16:46 ANGug/L 0.097Vinyl chloride
BRL *SM6200 B P0A009711.5 1/7/20 16:46 ANGug/L 0.15Xylenes, total
Surrogate Recovery Control Limits
70-130100 %4-Bromofluorobenzene
70-130101 %Dibromofluoromethane
70-130101 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 20 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-15
Sample ID: 0010028-09
Work Order: 0010028
Time Collected: 12/27/19 12:30
Time Submitted: 01/03/20 14:10
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.111,1,1,2-Tetrachloroethane
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.0611,1,1-Trichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.0361,1,2,2-Tetrachloroethane
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.0661,1,2-Trichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.0831,1-Dichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.0831,1-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.0511,1-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.401,2,3-Trichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.141,2,3-Trichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.131,2,4-Trichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.0541,2,4-Trimethylbenzene
BRL *SM6200 B P0A009712.0 1/7/20 17:12 ANGug/L 0.171,2-Dibromo-3-chloropropane
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.0511,2-Dibromoethane
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.0761,2-Dichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.0661,2-Dichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.111,2-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.0761,3,5-Trimethylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.0541,3-Dichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.0431,3-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.0501,4-Dichlorobenzene
BRL *SM6200 B P0A009712.0 1/7/20 17:12 ANGug/L 0.112,2-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.0662-Chlorotoluene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.0504-Chlorotoluene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.0894-Isopropyltoluene
BRL *SM6200 B P0A00971101/7/20 17:12 ANGug/L 0.31Acetone
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.048Benzene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.057Bromobenzene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.14Bromochloromethane
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.062Bromodichloromethane
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.040Bromoform
BRL *SM6200 B P0A009711.0 1/7/20 17:12 ANGug/L 0.18Bromomethane
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.11Carbon Tetrachloride
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.062Chlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.22Chloroethane
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.076Chloroform
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.079Chloromethane
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.056cis-1,2-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.079cis-1,3-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.081Dibromochloromethane
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.065Dibromomethane
BRL *SM6200 B P0A009711.0 1/7/20 17:12 ANGug/L 0.11Dichlorodifluoromethane
BRL *SM6200 B P0A009712001/7/20 17:12 ANGug/L 27Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 21 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-15
Sample ID: 0010028-09
Work Order: 0010028
Time Collected: 12/27/19 12:30
Time Submitted: 01/03/20 14:10
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.061Ethylbenzene
BRL *SM6200 B P0A009712.0 1/7/20 17:12 ANGug/L 0.16Hexachlorobutadiene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.050Isopropyl Ether
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.054Isopropylbenzene (Cumene)
BRL *SM6200 B P0A009711.0 1/7/20 17:12 ANGug/L 0.12m,p-Xylenes
BRL *SM6200 B P0A009711.0 1/7/20 17:12 ANGug/L 0.065Methyl Butyl Ketone (2-Hexanone)
BRL *SM6200 B P0A009715.0 1/7/20 17:12 ANGug/L 0.24Methyl Ethyl Ketone (2-Butanone)
BRL *SM6200 B P0A009711.0 1/7/20 17:12 ANGug/L 0.078Methyl Isobutyl Ketone
BRL *SM6200 B P0A009712.0 1/7/20 17:12 ANGug/L 0.083Methylene Chloride
BRL *SM6200 B P0A009711.0 1/7/20 17:12 ANGug/L 0.042Methyl-tert-Butyl Ether
BRL *SM6200 B P0A009711.0 1/7/20 17:12 ANGug/L 0.19Naphthalene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.076n-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.087n-Propylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.044o-Xylene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.076sec-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.047Styrene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.088tert-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.098Tetrachloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.044Toluene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.070trans-1,2-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.12trans-1,3-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.078Trichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.062Trichlorofluoromethane
BRL *SM6200 B P0A009715.0 1/7/20 17:12 ANGug/L 0.060Vinyl acetate
BRL *SM6200 B P0A009710.50 1/7/20 17:12 ANGug/L 0.097Vinyl chloride
BRL *SM6200 B P0A009711.5 1/7/20 17:12 ANGug/L 0.15Xylenes, total
Surrogate Recovery Control Limits
70-13099 %4-Bromofluorobenzene
70-130101 %Dibromofluoromethane
70-130101 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 22 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-16
Sample ID: 0010028-10
Work Order: 0010028
Time Collected: 12/27/19 12:35
Time Submitted: 01/03/20 14:10
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.111,1,1,2-Tetrachloroethane
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.0611,1,1-Trichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.0361,1,2,2-Tetrachloroethane
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.0661,1,2-Trichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.0831,1-Dichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.0831,1-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.0511,1-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.401,2,3-Trichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.141,2,3-Trichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.131,2,4-Trichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.0541,2,4-Trimethylbenzene
BRL *SM6200 B P0A009712.0 1/7/20 17:38 ANGug/L 0.171,2-Dibromo-3-chloropropane
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.0511,2-Dibromoethane
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.0761,2-Dichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.0661,2-Dichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.111,2-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.0761,3,5-Trimethylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.0541,3-Dichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.0431,3-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.0501,4-Dichlorobenzene
BRL *SM6200 B P0A009712.0 1/7/20 17:38 ANGug/L 0.112,2-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.0662-Chlorotoluene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.0504-Chlorotoluene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.0894-Isopropyltoluene
BRL *SM6200 B P0A00971101/7/20 17:38 ANGug/L 0.31Acetone
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.048Benzene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.057Bromobenzene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.14Bromochloromethane
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.062Bromodichloromethane
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.040Bromoform
BRL *SM6200 B P0A009711.0 1/7/20 17:38 ANGug/L 0.18Bromomethane
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.11Carbon Tetrachloride
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.062Chlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.22Chloroethane
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.076Chloroform
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.079Chloromethane
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.056cis-1,2-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.079cis-1,3-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.081Dibromochloromethane
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.065Dibromomethane
BRL *SM6200 B P0A009711.0 1/7/20 17:38 ANGug/L 0.11Dichlorodifluoromethane
BRL *SM6200 B P0A009712001/7/20 17:38 ANGug/L 27Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 23 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: MW-16
Sample ID: 0010028-10
Work Order: 0010028
Time Collected: 12/27/19 12:35
Time Submitted: 01/03/20 14:10
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.061Ethylbenzene
BRL *SM6200 B P0A009712.0 1/7/20 17:38 ANGug/L 0.16Hexachlorobutadiene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.050Isopropyl Ether
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.054Isopropylbenzene (Cumene)
BRL *SM6200 B P0A009711.0 1/7/20 17:38 ANGug/L 0.12m,p-Xylenes
BRL *SM6200 B P0A009711.0 1/7/20 17:38 ANGug/L 0.065Methyl Butyl Ketone (2-Hexanone)
BRL *SM6200 B P0A009715.0 1/7/20 17:38 ANGug/L 0.24Methyl Ethyl Ketone (2-Butanone)
BRL *SM6200 B P0A009711.0 1/7/20 17:38 ANGug/L 0.078Methyl Isobutyl Ketone
BRL *SM6200 B P0A009712.0 1/7/20 17:38 ANGug/L 0.083Methylene Chloride
BRL *SM6200 B P0A009711.0 1/7/20 17:38 ANGug/L 0.042Methyl-tert-Butyl Ether
BRL *SM6200 B P0A009711.0 1/7/20 17:38 ANGug/L 0.19Naphthalene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.076n-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.087n-Propylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.044o-Xylene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.076sec-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.047Styrene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.088tert-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.098Tetrachloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.044Toluene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.070trans-1,2-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.12trans-1,3-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.078Trichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.062Trichlorofluoromethane
BRL *SM6200 B P0A009715.0 1/7/20 17:38 ANGug/L 0.060Vinyl acetate
BRL *SM6200 B P0A009710.50 1/7/20 17:38 ANGug/L 0.097Vinyl chloride
BRL *SM6200 B P0A009711.5 1/7/20 17:38 ANGug/L 0.15Xylenes, total
Surrogate Recovery Control Limits
70-130101 %4-Bromofluorobenzene
70-130102 %Dibromofluoromethane
70-130101 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 24 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: WSW-7
Sample ID: 0010028-11
Work Order: 0010028
Time Collected: 12/27/19 14:17
Time Submitted: 01/03/20 14:10
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.111,1,1,2-Tetrachloroethane
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.0611,1,1-Trichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.0361,1,2,2-Tetrachloroethane
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.0661,1,2-Trichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.0831,1-Dichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.0831,1-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.0511,1-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.401,2,3-Trichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.141,2,3-Trichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.131,2,4-Trichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.0541,2,4-Trimethylbenzene
BRL *SM6200 B P0A009712.0 1/7/20 18:04 ANGug/L 0.171,2-Dibromo-3-chloropropane
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.0511,2-Dibromoethane
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.0761,2-Dichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.0661,2-Dichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.111,2-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.0761,3,5-Trimethylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.0541,3-Dichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.0431,3-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.0501,4-Dichlorobenzene
BRL *SM6200 B P0A009712.0 1/7/20 18:04 ANGug/L 0.112,2-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.0662-Chlorotoluene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.0504-Chlorotoluene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.0894-Isopropyltoluene
BRL *SM6200 B P0A00971101/7/20 18:04 ANGug/L 0.31Acetone
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.048Benzene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.057Bromobenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.14Bromochloromethane
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.062Bromodichloromethane
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.040Bromoform
BRL *SM6200 B P0A009711.0 1/7/20 18:04 ANGug/L 0.18Bromomethane
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.11Carbon Tetrachloride
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.062Chlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.22Chloroethane
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.076Chloroform
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.079Chloromethane
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.056cis-1,2-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.079cis-1,3-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.081Dibromochloromethane
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.065Dibromomethane
BRL *SM6200 B P0A009711.0 1/7/20 18:04 ANGug/L 0.11Dichlorodifluoromethane
BRL *SM6200 B P0A009712001/7/20 18:04 ANGug/L 27Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 25 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: WSW-7
Sample ID: 0010028-11
Work Order: 0010028
Time Collected: 12/27/19 14:17
Time Submitted: 01/03/20 14:10
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.061Ethylbenzene
BRL *SM6200 B P0A009712.0 1/7/20 18:04 ANGug/L 0.16Hexachlorobutadiene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.050Isopropyl Ether
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.054Isopropylbenzene (Cumene)
BRL *SM6200 B P0A009711.0 1/7/20 18:04 ANGug/L 0.12m,p-Xylenes
BRL *SM6200 B P0A009711.0 1/7/20 18:04 ANGug/L 0.065Methyl Butyl Ketone (2-Hexanone)
BRL *SM6200 B P0A009715.0 1/7/20 18:04 ANGug/L 0.24Methyl Ethyl Ketone (2-Butanone)
BRL *SM6200 B P0A009711.0 1/7/20 18:04 ANGug/L 0.078Methyl Isobutyl Ketone
BRL *SM6200 B P0A009712.0 1/7/20 18:04 ANGug/L 0.083Methylene Chloride
BRL *SM6200 B P0A009711.0 1/7/20 18:04 ANGug/L 0.042Methyl-tert-Butyl Ether
BRL *SM6200 B P0A009711.0 1/7/20 18:04 ANGug/L 0.19Naphthalene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.076n-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.087n-Propylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.044o-Xylene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.076sec-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.047Styrene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.088tert-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.098Tetrachloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.044Toluene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.070trans-1,2-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.12trans-1,3-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.078Trichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.062Trichlorofluoromethane
BRL *SM6200 B P0A009715.0 1/7/20 18:04 ANGug/L 0.060Vinyl acetate
BRL *SM6200 B P0A009710.50 1/7/20 18:04 ANGug/L 0.097Vinyl chloride
BRL *SM6200 B P0A009711.5 1/7/20 18:04 ANGug/L 0.15Xylenes, total
Surrogate Recovery Control Limits
70-13099 %4-Bromofluorobenzene
70-130101 %Dibromofluoromethane
70-130100 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 26 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: WSW-3
Sample ID: 0010028-12
Work Order: 0010028
Time Collected: 12/27/19 14:28
Time Submitted: 01/03/20 14:10
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.111,1,1,2-Tetrachloroethane
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.0611,1,1-Trichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.0361,1,2,2-Tetrachloroethane
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.0661,1,2-Trichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.0831,1-Dichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.0831,1-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.0511,1-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.401,2,3-Trichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.141,2,3-Trichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.131,2,4-Trichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.0541,2,4-Trimethylbenzene
BRL *SM6200 B P0A009712.0 1/7/20 18:30 ANGug/L 0.171,2-Dibromo-3-chloropropane
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.0511,2-Dibromoethane
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.0761,2-Dichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.0661,2-Dichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.111,2-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.0761,3,5-Trimethylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.0541,3-Dichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.0431,3-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.0501,4-Dichlorobenzene
BRL *SM6200 B P0A009712.0 1/7/20 18:30 ANGug/L 0.112,2-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.0662-Chlorotoluene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.0504-Chlorotoluene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.0894-Isopropyltoluene
BRL *SM6200 B P0A00971101/7/20 18:30 ANGug/L 0.31Acetone
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.048Benzene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.057Bromobenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.14Bromochloromethane
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.062Bromodichloromethane
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.040Bromoform
BRL *SM6200 B P0A009711.0 1/7/20 18:30 ANGug/L 0.18Bromomethane
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.11Carbon Tetrachloride
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.062Chlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.22Chloroethane
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.076Chloroform
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.079Chloromethane
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.056cis-1,2-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.079cis-1,3-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.081Dibromochloromethane
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.065Dibromomethane
BRL *SM6200 B P0A009711.0 1/7/20 18:30 ANGug/L 0.11Dichlorodifluoromethane
BRL *SM6200 B P0A009712001/7/20 18:30 ANGug/L 27Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 27 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: WSW-3
Sample ID: 0010028-12
Work Order: 0010028
Time Collected: 12/27/19 14:28
Time Submitted: 01/03/20 14:10
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.061Ethylbenzene
BRL *SM6200 B P0A009712.0 1/7/20 18:30 ANGug/L 0.16Hexachlorobutadiene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.050Isopropyl Ether
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.054Isopropylbenzene (Cumene)
BRL *SM6200 B P0A009711.0 1/7/20 18:30 ANGug/L 0.12m,p-Xylenes
BRL *SM6200 B P0A009711.0 1/7/20 18:30 ANGug/L 0.065Methyl Butyl Ketone (2-Hexanone)
BRL *SM6200 B P0A009715.0 1/7/20 18:30 ANGug/L 0.24Methyl Ethyl Ketone (2-Butanone)
BRL *SM6200 B P0A009711.0 1/7/20 18:30 ANGug/L 0.078Methyl Isobutyl Ketone
BRL *SM6200 B P0A009712.0 1/7/20 18:30 ANGug/L 0.083Methylene Chloride
BRL *SM6200 B P0A009711.0 1/7/20 18:30 ANGug/L 0.042Methyl-tert-Butyl Ether
BRL *SM6200 B P0A009711.0 1/7/20 18:30 ANGug/L 0.19Naphthalene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.076n-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.087n-Propylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.044o-Xylene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.076sec-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.047Styrene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.088tert-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.098Tetrachloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.044Toluene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.070trans-1,2-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.12trans-1,3-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.078Trichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.062Trichlorofluoromethane
BRL *SM6200 B P0A009715.0 1/7/20 18:30 ANGug/L 0.060Vinyl acetate
BRL *SM6200 B P0A009710.50 1/7/20 18:30 ANGug/L 0.097Vinyl chloride
BRL *SM6200 B P0A009711.5 1/7/20 18:30 ANGug/L 0.15Xylenes, total
Surrogate Recovery Control Limits
70-130100 %4-Bromofluorobenzene
70-130102 %Dibromofluoromethane
70-130101 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 28 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: WSW-8
Sample ID: 0010028-13
Work Order: 0010028
Time Collected: 12/27/19 14:49
Time Submitted: 01/03/20 14:10
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.111,1,1,2-Tetrachloroethane
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.0611,1,1-Trichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.0361,1,2,2-Tetrachloroethane
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.0661,1,2-Trichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.0831,1-Dichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.0831,1-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.0511,1-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.401,2,3-Trichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.141,2,3-Trichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.131,2,4-Trichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.0541,2,4-Trimethylbenzene
BRL *SM6200 B P0A009712.0 1/7/20 18:57 ANGug/L 0.171,2-Dibromo-3-chloropropane
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.0511,2-Dibromoethane
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.0761,2-Dichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.0661,2-Dichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.111,2-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.0761,3,5-Trimethylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.0541,3-Dichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.0431,3-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.0501,4-Dichlorobenzene
BRL *SM6200 B P0A009712.0 1/7/20 18:57 ANGug/L 0.112,2-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.0662-Chlorotoluene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.0504-Chlorotoluene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.0894-Isopropyltoluene
BRL *SM6200 B P0A00971101/7/20 18:57 ANGug/L 0.31Acetone
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.048Benzene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.057Bromobenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.14Bromochloromethane
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.062Bromodichloromethane
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.040Bromoform
BRL *SM6200 B P0A009711.0 1/7/20 18:57 ANGug/L 0.18Bromomethane
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.11Carbon Tetrachloride
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.062Chlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.22Chloroethane
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.076Chloroform
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.079Chloromethane
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.056cis-1,2-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.079cis-1,3-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.081Dibromochloromethane
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.065Dibromomethane
BRL *SM6200 B P0A009711.0 1/7/20 18:57 ANGug/L 0.11Dichlorodifluoromethane
BRL *SM6200 B P0A009712001/7/20 18:57 ANGug/L 27Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 29 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: WSW-8
Sample ID: 0010028-13
Work Order: 0010028
Time Collected: 12/27/19 14:49
Time Submitted: 01/03/20 14:10
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.061Ethylbenzene
BRL *SM6200 B P0A009712.0 1/7/20 18:57 ANGug/L 0.16Hexachlorobutadiene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.050Isopropyl Ether
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.054Isopropylbenzene (Cumene)
BRL *SM6200 B P0A009711.0 1/7/20 18:57 ANGug/L 0.12m,p-Xylenes
BRL *SM6200 B P0A009711.0 1/7/20 18:57 ANGug/L 0.065Methyl Butyl Ketone (2-Hexanone)
BRL *SM6200 B P0A009715.0 1/7/20 18:57 ANGug/L 0.24Methyl Ethyl Ketone (2-Butanone)
BRL *SM6200 B P0A009711.0 1/7/20 18:57 ANGug/L 0.078Methyl Isobutyl Ketone
BRL *SM6200 B P0A009712.0 1/7/20 18:57 ANGug/L 0.083Methylene Chloride
BRL *SM6200 B P0A009711.0 1/7/20 18:57 ANGug/L 0.042Methyl-tert-Butyl Ether
BRL *SM6200 B P0A009711.0 1/7/20 18:57 ANGug/L 0.19Naphthalene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.076n-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.087n-Propylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.044o-Xylene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.076sec-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.047Styrene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.088tert-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.098Tetrachloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.044Toluene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.070trans-1,2-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.12trans-1,3-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.078Trichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.062Trichlorofluoromethane
BRL *SM6200 B P0A009715.0 1/7/20 18:57 ANGug/L 0.060Vinyl acetate
BRL *SM6200 B P0A009710.50 1/7/20 18:57 ANGug/L 0.097Vinyl chloride
BRL *SM6200 B P0A009711.5 1/7/20 18:57 ANGug/L 0.15Xylenes, total
Surrogate Recovery Control Limits
70-130101 %4-Bromofluorobenzene
70-130102 %Dibromofluoromethane
70-130101 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 30 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: WSW-9
Sample ID: 0010028-14
Work Order: 0010028
Time Collected: 12/27/19 14:55
Time Submitted: 01/03/20 14:10
Volatile Organic Compounds by GC/MS
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.111,1,1,2-Tetrachloroethane
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.0611,1,1-Trichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.0361,1,2,2-Tetrachloroethane
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.0661,1,2-Trichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.0831,1-Dichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.0831,1-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.0511,1-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.401,2,3-Trichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.141,2,3-Trichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.131,2,4-Trichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.0541,2,4-Trimethylbenzene
BRL *SM6200 B P0A009712.0 1/7/20 19:23 ANGug/L 0.171,2-Dibromo-3-chloropropane
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.0511,2-Dibromoethane
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.0761,2-Dichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.0661,2-Dichloroethane
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.111,2-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.0761,3,5-Trimethylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.0541,3-Dichlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.0431,3-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.0501,4-Dichlorobenzene
BRL *SM6200 B P0A009712.0 1/7/20 19:23 ANGug/L 0.112,2-Dichloropropane
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.0662-Chlorotoluene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.0504-Chlorotoluene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.0894-Isopropyltoluene
BRL *SM6200 B P0A00971101/7/20 19:23 ANGug/L 0.31Acetone
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.048Benzene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.057Bromobenzene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.14Bromochloromethane
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.062Bromodichloromethane
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.040Bromoform
BRL *SM6200 B P0A009711.0 1/7/20 19:23 ANGug/L 0.18Bromomethane
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.11Carbon Tetrachloride
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.062Chlorobenzene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.22Chloroethane
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.076Chloroform
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.079Chloromethane
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.056cis-1,2-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.079cis-1,3-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.081Dibromochloromethane
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.065Dibromomethane
BRL *SM6200 B P0A009711.0 1/7/20 19:23 ANGug/L 0.11Dichlorodifluoromethane
BRL *SM6200 B P0A009712001/7/20 19:23 ANGug/L 27Ethanol
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 31 of 43
Laboratory Report
01/13/2020
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Sample Matrix: Water
Client Sample ID: WSW-9
Sample ID: 0010028-14
Work Order: 0010028
Time Collected: 12/27/19 14:55
Time Submitted: 01/03/20 14:10
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.061Ethylbenzene
BRL *SM6200 B P0A009712.0 1/7/20 19:23 ANGug/L 0.16Hexachlorobutadiene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.050Isopropyl Ether
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.054Isopropylbenzene (Cumene)
BRL *SM6200 B P0A009711.0 1/7/20 19:23 ANGug/L 0.12m,p-Xylenes
BRL *SM6200 B P0A009711.0 1/7/20 19:23 ANGug/L 0.065Methyl Butyl Ketone (2-Hexanone)
BRL *SM6200 B P0A009715.0 1/7/20 19:23 ANGug/L 0.24Methyl Ethyl Ketone (2-Butanone)
BRL *SM6200 B P0A009711.0 1/7/20 19:23 ANGug/L 0.078Methyl Isobutyl Ketone
BRL *SM6200 B P0A009712.0 1/7/20 19:23 ANGug/L 0.083Methylene Chloride
BRL *SM6200 B P0A009711.0 1/7/20 19:23 ANGug/L 0.042Methyl-tert-Butyl Ether
BRL *SM6200 B P0A009711.0 1/7/20 19:23 ANGug/L 0.19Naphthalene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.076n-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.087n-Propylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.044o-Xylene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.076sec-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.047Styrene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.088tert-Butylbenzene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.098Tetrachloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.044Toluene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.070trans-1,2-Dichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.12trans-1,3-Dichloropropylene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.078Trichloroethylene
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.062Trichlorofluoromethane
BRL *SM6200 B P0A009715.0 1/7/20 19:23 ANGug/L 0.060Vinyl acetate
BRL *SM6200 B P0A009710.50 1/7/20 19:23 ANGug/L 0.097Vinyl chloride
BRL *SM6200 B P0A009711.5 1/7/20 19:23 ANGug/L 0.15Xylenes, total
Surrogate Recovery Control Limits
70-130100 %4-Bromofluorobenzene
70-130101 %Dibromofluoromethane
70-130100 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 32 of 43
1/13/20
Level II QC Report
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Work Order: 0010028
Time Submitted: 1/3/2020 2:10:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P0A0097 - SM6200 B
Blank (P0A0097-BLK1)Prepared & Analyzed: 01/07/20
1,1,1,2-Tetrachloroethane ug/LBRL0.50
1,1,1-Trichloroethane ug/LBRL0.50
1,1,2,2-Tetrachloroethane ug/LBRL0.50
1,1,2-Trichloroethane ug/LBRL0.50
1,1-Dichloroethane ug/LBRL0.50
1,1-Dichloroethylene ug/LBRL0.50
1,1-Dichloropropylene ug/LBRL0.50
1,2,3-Trichlorobenzene ug/LBRL0.50
1,2,3-Trichloropropane ug/LBRL0.50
1,2,4-Trichlorobenzene ug/LBRL0.50
1,2,4-Trimethylbenzene ug/LBRL0.50
1,2-Dibromo-3-chloropropane ug/LBRL2.0
1,2-Dibromoethane ug/LBRL0.50
1,2-Dichlorobenzene ug/LBRL0.50
1,2-Dichloroethane ug/LBRL0.50
1,2-Dichloropropane ug/LBRL0.50
1,3,5-Trimethylbenzene ug/LBRL0.50
1,3-Dichlorobenzene ug/LBRL0.50
1,3-Dichloropropane ug/LBRL0.50
1,4-Dichlorobenzene ug/LBRL0.50
2,2-Dichloropropane ug/LBRL2.0
2-Chlorotoluene ug/LBRL0.50
4-Chlorotoluene ug/LBRL0.50
4-Isopropyltoluene ug/LBRL0.50
Acetone ug/LBRL10
Benzene ug/LBRL0.50
Bromobenzene ug/LBRL0.50
Bromochloromethane ug/LBRL0.50
Bromodichloromethane ug/LBRL0.50
Bromoform ug/LBRL0.50
Bromomethane ug/LBRL1.0
Carbon Tetrachloride ug/LBRL0.50
Chlorobenzene ug/LBRL0.50
Chloroethane ug/LBRL0.50
Chloroform ug/LBRL0.50
Chloromethane ug/LBRL0.50
cis-1,2-Dichloroethylene ug/LBRL0.50
cis-1,3-Dichloropropylene ug/LBRL0.50
Dibromochloromethane ug/LBRL0.50
Dibromomethane ug/LBRL0.50
Dichlorodifluoromethane ug/LBRL1.0
Ethanol ug/LBRL200
Ethylbenzene ug/LBRL0.50
Hexachlorobutadiene ug/LBRL2.0
Isopropyl Ether ug/LBRL0.50
Isopropylbenzene (Cumene)ug/LBRL0.50
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 33 of 43
1/13/20
Level II QC Report
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Work Order: 0010028
Time Submitted: 1/3/2020 2:10:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P0A0097 - SM6200 B
Blank (P0A0097-BLK1)Prepared & Analyzed: 01/07/20
m,p-Xylenes ug/LBRL1.0
Methyl Butyl Ketone (2-Hexanone)ug/LBRL1.0
Methyl Ethyl Ketone (2-Butanone)ug/LBRL5.0
Methyl Isobutyl Ketone ug/LBRL1.0
Methylene Chloride ug/LBRL2.0
Methyl-tert-Butyl Ether ug/LBRL1.0
Naphthalene ug/LBRL1.0
n-Butylbenzene ug/LBRL0.50
n-Propylbenzene ug/LBRL0.50
o-Xylene ug/LBRL0.50
sec-Butylbenzene ug/LBRL0.50
Styrene ug/LBRL0.50
tert-Butylbenzene ug/LBRL0.50
Tetrachloroethylene ug/LBRL0.50
Toluene ug/LBRL0.50
trans-1,2-Dichloroethylene ug/LBRL0.50
trans-1,3-Dichloropropylene ug/LBRL0.50
Trichloroethylene ug/LBRL0.50
Trichlorofluoromethane ug/LBRL0.50
Vinyl acetate ug/LBRL5.0
Vinyl chloride ug/LBRL0.50
Xylenes, total ug/LBRL1.5
ug/L 50.00 70-130Surrogate: 4-Bromofluorobenzene 10050.2
ug/L 50.00 70-130Surrogate: Dibromofluoromethane 10150.7
ug/L 50.00 70-130Surrogate: Toluene-d8 9949.7
LCS (P0A0097-BS1)Prepared & Analyzed: 01/07/20
1,1,1,2-Tetrachloroethane ug/L21.2 0.50 20.00 70-130106
1,1,1-Trichloroethane ug/L22.4 0.50 20.00 70-130112
1,1,2,2-Tetrachloroethane ug/L21.6 0.50 20.00 70-130108
1,1,2-Trichloroethane ug/L21.6 0.50 20.00 70-130108
1,1-Dichloroethane ug/L22.1 0.50 20.00 70-130110
1,1-Dichloroethylene ug/L22.3 0.50 20.00 70-130112
1,1-Dichloropropylene ug/L23.0 0.50 20.00 70-130115
1,2,3-Trichlorobenzene ug/L22.7 0.50 20.00 70-130113
1,2,3-Trichloropropane ug/L22.0 0.50 20.00 70-130110
1,2,4-Trichlorobenzene ug/L22.3 0.50 20.00 70-130111
1,2,4-Trimethylbenzene ug/L21.2 0.50 20.00 70-130106
1,2-Dibromo-3-chloropropane ug/L23.0 2.0 20.00 70-130115
1,2-Dibromoethane ug/L21.9 0.50 20.00 70-130109
1,2-Dichlorobenzene ug/L21.4 0.50 20.00 70-130107
1,2-Dichloroethane ug/L20.5 0.50 20.00 70-130102
1,2-Dichloropropane ug/L22.0 0.50 20.00 70-130110
1,3,5-Trimethylbenzene ug/L21.3 0.50 20.00 70-130107
1,3-Dichlorobenzene ug/L21.2 0.50 20.00 70-130106
1,3-Dichloropropane ug/L22.2 0.50 20.00 70-130111
1,4-Dichlorobenzene ug/L21.4 0.50 20.00 70-130107
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 34 of 43
1/13/20
Level II QC Report
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Work Order: 0010028
Time Submitted: 1/3/2020 2:10:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P0A0097 - SM6200 B
LCS (P0A0097-BS1)Prepared & Analyzed: 01/07/20
2,2-Dichloropropane ug/L22.8 2.0 20.00 70-130114
2-Chlorotoluene ug/L20.7 0.50 20.00 70-130103
4-Chlorotoluene ug/L20.8 0.50 20.00 70-130104
4-Isopropyltoluene ug/L22.2 0.50 20.00 70-130111
Acetone ug/L35.5 10 40.00 40-16089
Benzene ug/L21.9 0.50 20.00 70-130110
Bromobenzene ug/L21.7 0.50 20.00 70-130108
Bromochloromethane ug/L22.0 0.50 20.00 70-130110
Bromodichloromethane ug/L21.6 0.50 20.00 70-130108
Bromoform ug/L22.4 0.50 20.00 70-130112
Bromomethane ug/L18.6 1.0 20.00 60-14093
Carbon Tetrachloride ug/L22.5 0.50 20.00 70-130112
Chlorobenzene ug/L21.5 0.50 20.00 70-130108
Chloroethane ug/L17.0 0.50 20.00 60-14085
Chloroform ug/L22.0 0.50 20.00 70-130110
Chloromethane ug/L18.1 0.50 20.00 60-14091
cis-1,2-Dichloroethylene ug/L21.0 0.50 20.00 70-130105
cis-1,3-Dichloropropylene ug/L22.9 0.50 20.00 70-130115
Dibromochloromethane ug/L21.6 0.50 20.00 70-130108
Dibromomethane ug/L22.2 0.50 20.00 70-130111
Dichlorodifluoromethane ug/L18.4 1.0 20.00 60-14092
Ethanol ug/L555 200 500.0 60-140111
Ethylbenzene ug/L21.5 0.50 20.00 70-130107
Hexachlorobutadiene ug/L23.5 2.0 20.00 70-130117
Isopropyl Ether ug/L21.0 0.50 20.00 70-130105
Isopropylbenzene (Cumene)ug/L22.3 0.50 20.00 70-130111
m,p-Xylenes ug/L44.1 1.0 40.00 70-130110
Methyl Butyl Ketone (2-Hexanone)ug/L20.8 1.0 20.00 60-140104
Methyl Ethyl Ketone (2-Butanone)ug/L20.5 5.0 20.00 60-140103
Methyl Isobutyl Ketone ug/L21.2 1.0 20.00 60-140106
Methylene Chloride ug/L21.1 2.0 20.00 70-130105
Methyl-tert-Butyl Ether ug/L22.3 1.0 20.00 70-130111
Naphthalene ug/L20.6 1.0 20.00 70-130103
n-Butylbenzene ug/L21.7 0.50 20.00 70-130108
n-Propylbenzene ug/L21.5 0.50 20.00 70-130107
o-Xylene ug/L21.4 0.50 20.00 70-130107
sec-Butylbenzene ug/L22.2 0.50 20.00 70-130111
Styrene ug/L22.1 0.50 20.00 70-130110
tert-Butylbenzene ug/L22.0 0.50 20.00 70-130110
Tetrachloroethylene ug/L22.9 0.50 20.00 70-130114
Toluene ug/L21.4 0.50 20.00 70-130107
trans-1,2-Dichloroethylene ug/L21.5 0.50 20.00 70-130107
trans-1,3-Dichloropropylene ug/L22.6 0.50 20.00 70-130113
Trichloroethylene ug/L21.6 0.50 20.00 70-130108
Trichlorofluoromethane ug/L22.2 0.50 20.00 60-140111
Vinyl acetate ug/L21.4 5.0 20.00 60-140107
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 35 of 43
1/13/20
Level II QC Report
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Work Order: 0010028
Time Submitted: 1/3/2020 2:10:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P0A0097 - SM6200 B
LCS (P0A0097-BS1)Prepared & Analyzed: 01/07/20
Vinyl chloride ug/L21.9 0.50 20.00 60-140109
Xylenes, total ug/L65.5 1.5 60.00 70-130109
ug/L 50.00 70-130Surrogate: 4-Bromofluorobenzene 9849.2
ug/L 50.00 70-130Surrogate: Dibromofluoromethane 10050.0
ug/L 50.00 70-130Surrogate: Toluene-d8 10150.3
LCS Dup (P0A0097-BSD1)Prepared & Analyzed: 01/07/20
1,1,1,2-Tetrachloroethane ug/L20.9 0.50 20.00 2070-130104 1
1,1,1-Trichloroethane ug/L21.4 0.50 20.00 2070-130107 4
1,1,2,2-Tetrachloroethane ug/L21.1 0.50 20.00 2070-130106 2
1,1,2-Trichloroethane ug/L21.3 0.50 20.00 2070-130106 2
1,1-Dichloroethane ug/L21.4 0.50 20.00 2070-130107 3
1,1-Dichloroethylene ug/L20.9 0.50 20.00 2070-130104 7
1,1-Dichloropropylene ug/L21.8 0.50 20.00 2070-130109 6
1,2,3-Trichlorobenzene ug/L22.7 0.50 20.00 2070-130113 0.04
1,2,3-Trichloropropane ug/L21.6 0.50 20.00 2070-130108 2
1,2,4-Trichlorobenzene ug/L21.8 0.50 20.00 2070-130109 2
1,2,4-Trimethylbenzene ug/L20.7 0.50 20.00 2070-130104 2
1,2-Dibromo-3-chloropropane ug/L21.7 2.0 20.00 2070-130109 6
1,2-Dibromoethane ug/L21.5 0.50 20.00 2070-130107 2
1,2-Dichlorobenzene ug/L21.2 0.50 20.00 2070-130106 0.8
1,2-Dichloroethane ug/L20.0 0.50 20.00 2070-130100 2
1,2-Dichloropropane ug/L21.5 0.50 20.00 2070-130108 2
1,3,5-Trimethylbenzene ug/L20.8 0.50 20.00 2070-130104 3
1,3-Dichlorobenzene ug/L21.0 0.50 20.00 2070-130105 0.7
1,3-Dichloropropane ug/L22.1 0.50 20.00 2070-130110 0.4
1,4-Dichlorobenzene ug/L21.0 0.50 20.00 2070-130105 2
2,2-Dichloropropane ug/L21.5 2.0 20.00 2070-130107 6
2-Chlorotoluene ug/L20.3 0.50 20.00 2070-130102 2
4-Chlorotoluene ug/L20.5 0.50 20.00 2070-130102 2
4-Isopropyltoluene ug/L21.6 0.50 20.00 2070-130108 3
Acetone ug/L34.4 10 40.00 2040-16086 3
Benzene ug/L21.1 0.50 20.00 2070-130105 4
Bromobenzene ug/L21.3 0.50 20.00 2070-130106 2
Bromochloromethane ug/L21.6 0.50 20.00 2070-130108 2
Bromodichloromethane ug/L21.5 0.50 20.00 2070-130107 0.7
Bromoform ug/L21.6 0.50 20.00 2070-130108 4
Bromomethane ug/L18.2 1.0 20.00 2060-14091 2
Carbon Tetrachloride ug/L21.2 0.50 20.00 2070-130106 6
Chlorobenzene ug/L20.9 0.50 20.00 2070-130105 3
Chloroethane ug/L17.8 0.50 20.00 2060-14089 4
Chloroform ug/L21.5 0.50 20.00 2070-130108 2
Chloromethane ug/L17.8 0.50 20.00 2060-14089 2
cis-1,2-Dichloroethylene ug/L20.4 0.50 20.00 2070-130102 3
cis-1,3-Dichloropropylene ug/L22.2 0.50 20.00 2070-130111 3
Dibromochloromethane ug/L21.3 0.50 20.00 2070-130106 1
Dibromomethane ug/L21.5 0.50 20.00 2070-130107 3
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 36 of 43
1/13/20
Level II QC Report
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Work Order: 0010028
Time Submitted: 1/3/2020 2:10:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P0A0097 - SM6200 B
LCS Dup (P0A0097-BSD1)Prepared & Analyzed: 01/07/20
Dichlorodifluoromethane ug/L17.5 1.0 20.00 2060-14088 5
Ethanol ug/L541 200 500.0 2060-140108 3
Ethylbenzene ug/L20.6 0.50 20.00 2070-130103 4
Hexachlorobutadiene ug/L22.4 2.0 20.00 2070-130112 4
Isopropyl Ether ug/L20.6 0.50 20.00 2070-130103 2
Isopropylbenzene (Cumene)ug/L21.6 0.50 20.00 2070-130108 3
m,p-Xylenes ug/L42.8 1.0 40.00 2070-130107 3
Methyl Butyl Ketone (2-Hexanone)ug/L19.7 1.0 20.00 2060-14098 6
Methyl Ethyl Ketone (2-Butanone)ug/L19.4 5.0 20.00 2060-14097 6
Methyl Isobutyl Ketone ug/L20.4 1.0 20.00 2060-140102 4
Methylene Chloride ug/L20.6 2.0 20.00 2070-130103 2
Methyl-tert-Butyl Ether ug/L21.9 1.0 20.00 2070-130110 2
Naphthalene ug/L20.4 1.0 20.00 2070-130102 0.9
n-Butylbenzene ug/L20.8 0.50 20.00 2070-130104 4
n-Propylbenzene ug/L20.7 0.50 20.00 2070-130104 3
o-Xylene ug/L20.9 0.50 20.00 2070-130104 3
sec-Butylbenzene ug/L21.2 0.50 20.00 2070-130106 4
Styrene ug/L21.4 0.50 20.00 2070-130107 3
tert-Butylbenzene ug/L21.5 0.50 20.00 2070-130108 2
Tetrachloroethylene ug/L22.0 0.50 20.00 2070-130110 4
Toluene ug/L20.8 0.50 20.00 2070-130104 3
trans-1,2-Dichloroethylene ug/L20.9 0.50 20.00 2070-130105 2
trans-1,3-Dichloropropylene ug/L22.2 0.50 20.00 2070-130111 2
Trichloroethylene ug/L20.8 0.50 20.00 2070-130104 4
Trichlorofluoromethane ug/L21.0 0.50 20.00 2060-140105 6
Vinyl acetate ug/L20.9 5.0 20.00 2060-140105 2
Vinyl chloride ug/L20.6 0.50 20.00 2060-140103 6
Xylenes, total ug/L63.7 1.5 60.00 2070-130106 3
ug/L 50.00 70-130Surrogate: 4-Bromofluorobenzene 10049.9
ug/L 50.00 70-130Surrogate: Dibromofluoromethane 10050.0
ug/L 50.00 70-130Surrogate: Toluene-d8 10050.0
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 37 of 43
1/13/20
Level II QC Report
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Work Order: 0010028
Time Submitted: 1/3/2020 2:10:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P0A0097 - SM6200 B
Matrix Spike (P0A0097-MS1)Prepared & Analyzed: 01/07/20 Source: 0010028-04
1,1,1,2-Tetrachloroethane ug/L2065.0 200.0 BRL 70-130103
1,1,1-Trichloroethane ug/L2225.0 200.0 BRL 70-130111
1,1,2,2-Tetrachloroethane ug/L2035.0 200.0 BRL 70-130102
1,1,2-Trichloroethane ug/L2085.0 200.0 BRL 70-130104
1,1-Dichloroethane ug/L2185.0 200.0 BRL 70-130109
1,1-Dichloroethylene ug/L2175.0 200.0 BRL 70-130108
1,1-Dichloropropylene ug/L2265.0 200.0 BRL 70-130113
1,2,3-Trichlorobenzene ug/L1985.0 200.0 BRL 70-13099
1,2,3-Trichloropropane ug/L2115.0 200.0 BRL 70-130106
1,2,4-Trichlorobenzene ug/L2015.0 200.0 BRL 70-130101
1,2,4-Trimethylbenzene ug/L2045.0 200.0 BRL 70-130102
1,2-Dibromo-3-chloropropane ug/L19820 200.0 BRL 70-13099
1,2-Dibromoethane ug/L2105.0 200.0 BRL 70-130105
1,2-Dichlorobenzene ug/L2045.0 200.0 BRL 70-130102
1,2-Dichloroethane ug/L1985.0 200.0 BRL 70-13099
1,2-Dichloropropane ug/L2125.0 200.0 BRL 70-130106
1,3,5-Trimethylbenzene ug/L2095.0 200.0 BRL 70-130104
1,3-Dichlorobenzene ug/L2055.0 200.0 BRL 70-130102
1,3-Dichloropropane ug/L2155.0 200.0 BRL 70-130108
1,4-Dichlorobenzene ug/L2075.0 200.0 BRL 70-130104
2,2-Dichloropropane ug/L20020 200.0 BRL 70-130100
2-Chlorotoluene ug/L2025.0 200.0 BRL 70-130101
4-Chlorotoluene ug/L2065.0 200.0 BRL 70-130103
4-Isopropyltoluene ug/L2135.0 200.0 BRL 70-130107
Acetone ug/L325 100 400.0 BRL 40-16081
Benzene ug/L2145.0 200.0 BRL 70-130107
Bromobenzene ug/L2075.0 200.0 BRL 70-130103
Bromochloromethane ug/L2165.0 200.0 BRL 70-130108
Bromodichloromethane ug/L2095.0 200.0 BRL 70-130104
Bromoform ug/L2005.0 200.0 BRL 70-130100
Bromomethane ug/L18810 200.0 BRL 60-14094
Carbon Tetrachloride ug/L2205.0 200.0 BRL 70-130110
Chlorobenzene ug/L2115.0 200.0 BRL 70-130106
Chloroethane ug/L1785.0 200.0 BRL 60-14089
Chloroform ug/L2165.0 200.0 BRL 70-130108
Chloromethane ug/L1745.0 200.0 BRL 60-14087
cis-1,2-Dichloroethylene ug/L2065.0 200.0 BRL 70-130103
cis-1,3-Dichloropropylene ug/L2145.0 200.0 BRL 70-130107
Dibromochloromethane ug/L2055.0 200.0 BRL 70-130103
Dibromomethane ug/L2095.0 200.0 BRL 70-130104
Dichlorodifluoromethane ug/L17810 200.0 BRL 60-14089
Ethanol ug/L5040 2000 5000 BRL 60-140101
Ethylbenzene ug/L2095.0 200.0 BRL 70-130105
Hexachlorobutadiene ug/L20920 200.0 BRL 70-130105
Isopropyl Ether ug/L2065.0 200.0 BRL 70-130103
Isopropylbenzene (Cumene)ug/L2185.0 200.0 BRL 70-130109
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 38 of 43
1/13/20
Level II QC Report
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Work Order: 0010028
Time Submitted: 1/3/2020 2:10:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P0A0097 - SM6200 B
Matrix Spike (P0A0097-MS1)Prepared & Analyzed: 01/07/20 Source: 0010028-04
m,p-Xylenes ug/L43410 400.0 BRL 70-130109
Methyl Butyl Ketone (2-Hexanone)ug/L18910 200.0 BRL 60-14095
Methyl Ethyl Ketone (2-Butanone)ug/L19250 200.0 BRL 60-14096
Methyl Isobutyl Ketone ug/L19710 200.0 BRL 60-14098
Methylene Chloride ug/L20720 200.0 BRL 70-130103
Methyl-tert-Butyl Ether ug/L21610 200.0 BRL 70-130108
Naphthalene ug/L17710 200.0 BRL 70-13089
n-Butylbenzene ug/L2025.0 200.0 BRL 70-130101
n-Propylbenzene ug/L2085.0 200.0 BRL 70-130104
o-Xylene ug/L2115.0 200.0 BRL 70-130105
sec-Butylbenzene ug/L2155.0 200.0 BRL 70-130108
Styrene ug/L2145.0 200.0 BRL 70-130107
tert-Butylbenzene ug/L2155.0 200.0 BRL 70-130107
Tetrachloroethylene ug/L2245.0 200.0 BRL 70-130112
Toluene ug/L2105.0 200.0 BRL 70-130105
trans-1,2-Dichloroethylene ug/L2135.0 200.0 BRL 70-130106
trans-1,3-Dichloropropylene ug/L2115.0 200.0 BRL 70-130105
Trichloroethylene ug/L2125.0 200.0 BRL 70-130106
Trichlorofluoromethane ug/L2255.0 200.0 BRL 60-140112
Vinyl acetate ug/L20950 200.0 BRL 60-140104
Vinyl chloride ug/L2155.0 200.0 BRL 60-140108
Xylenes, total ug/L64515 600.0 BRL 70-130108
ug/L 50.00 70-130Surrogate: 4-Bromofluorobenzene 9949.4
ug/L 50.00 70-130Surrogate: Dibromofluoromethane 9949.4
ug/L 50.00 70-130Surrogate: Toluene-d8 10150.4
Matrix Spike Dup (P0A0097-MSD1)Prepared & Analyzed: 01/07/20 Source: 0010028-04
1,1,1,2-Tetrachloroethane ug/L2015.0 200.0 BRL 2070-130100 3
1,1,1-Trichloroethane ug/L2115.0 200.0 BRL 2070-130106 5
1,1,2,2-Tetrachloroethane ug/L2015.0 200.0 BRL 2070-130101 1
1,1,2-Trichloroethane ug/L2075.0 200.0 BRL 2070-130103 0.8
1,1-Dichloroethane ug/L2095.0 200.0 BRL 2070-130105 4
1,1-Dichloroethylene ug/L2075.0 200.0 BRL 2070-130104 4
1,1-Dichloropropylene ug/L2155.0 200.0 BRL 2070-130107 5
1,2,3-Trichlorobenzene ug/L2095.0 200.0 BRL 2070-130104 6
1,2,3-Trichloropropane ug/L2105.0 200.0 BRL 2070-130105 0.9
1,2,4-Trichlorobenzene ug/L2045.0 200.0 BRL 2070-130102 2
1,2,4-Trimethylbenzene ug/L1975.0 200.0 BRL 2070-13099 3
1,2-Dibromo-3-chloropropane ug/L20520 200.0 BRL 2070-130102 3
1,2-Dibromoethane ug/L2095.0 200.0 BRL 2070-130104 0.5
1,2-Dichlorobenzene ug/L2015.0 200.0 BRL 2070-130100 2
1,2-Dichloroethane ug/L1955.0 200.0 BRL 2070-13098 2
1,2-Dichloropropane ug/L2095.0 200.0 BRL 2070-130105 1
1,3,5-Trimethylbenzene ug/L1985.0 200.0 BRL 2070-13099 5
1,3-Dichlorobenzene ug/L1985.0 200.0 BRL 2070-13099 3
1,3-Dichloropropane ug/L2155.0 200.0 BRL 2070-130108 0.1
1,4-Dichlorobenzene ug/L2005.0 200.0 BRL 2070-130100 3
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 39 of 43
1/13/20
Level II QC Report
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Work Order: 0010028
Time Submitted: 1/3/2020 2:10:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P0A0097 - SM6200 B
Matrix Spike Dup (P0A0097-MSD1)Prepared & Analyzed: 01/07/20 Source: 0010028-04
2,2-Dichloropropane ug/L18820 200.0 BRL 2070-13094 7
2-Chlorotoluene ug/L1945.0 200.0 BRL 2070-13097 4
4-Chlorotoluene ug/L1955.0 200.0 BRL 2070-13098 6
4-Isopropyltoluene ug/L2025.0 200.0 BRL 2070-130101 5
Acetone ug/L333 100 400.0 BRL 2040-16083 2
Benzene ug/L2075.0 200.0 BRL 2070-130103 4
Bromobenzene ug/L2025.0 200.0 BRL 2070-130101 2
Bromochloromethane ug/L2145.0 200.0 BRL 2070-130107 0.6
Bromodichloromethane ug/L2075.0 200.0 BRL 2070-130103 1
Bromoform ug/L1995.0 200.0 BRL 2070-13099 0.6
Bromomethane ug/L17410 200.0 BRL 2060-14087 8
Carbon Tetrachloride ug/L2115.0 200.0 BRL 2070-130106 4
Chlorobenzene ug/L2045.0 200.0 BRL 2070-130102 4
Chloroethane ug/L1585.0 200.0 BRL 2060-14079 12
Chloroform ug/L2095.0 200.0 BRL 2070-130104 3
Chloromethane ug/L1705.0 200.0 BRL 2060-14085 3
cis-1,2-Dichloroethylene ug/L1985.0 200.0 BRL 2070-13099 4
cis-1,3-Dichloropropylene ug/L2105.0 200.0 BRL 2070-130105 2
Dibromochloromethane ug/L2015.0 200.0 BRL 2070-130101 2
Dibromomethane ug/L2095.0 200.0 BRL 2070-130105 0.2
Dichlorodifluoromethane ug/L16910 200.0 BRL 2060-14084 6
Ethanol ug/L5130 2000 5000 BRL 2060-140103 2
Ethylbenzene ug/L2025.0 200.0 BRL 2070-130101 4
Hexachlorobutadiene ug/L20420 200.0 BRL 2070-130102 2
Isopropyl Ether ug/L2015.0 200.0 BRL 2070-130100 3
Isopropylbenzene (Cumene)ug/L2065.0 200.0 BRL 2070-130103 6
m,p-Xylenes ug/L41510 400.0 BRL 2070-130104 5
Methyl Butyl Ketone (2-Hexanone)ug/L18810 200.0 BRL 2060-14094 0.5
Methyl Ethyl Ketone (2-Butanone)ug/L19250 200.0 BRL 2060-14096 0.1
Methyl Isobutyl Ketone ug/L19410 200.0 BRL 2060-14097 1
Methylene Chloride ug/L20020 200.0 BRL 2070-130100 3
Methyl-tert-Butyl Ether ug/L21310 200.0 BRL 2070-130106 2
Naphthalene ug/L19010 200.0 BRL 2070-13095 7
n-Butylbenzene ug/L1945.0 200.0 BRL 2170-13097 5
n-Propylbenzene ug/L1995.0 200.0 BRL 1870-13099 4
o-Xylene ug/L2025.0 200.0 BRL 2070-130101 4
sec-Butylbenzene ug/L2055.0 200.0 BRL 2070-130102 5
Styrene ug/L2075.0 200.0 BRL 2070-130104 3
tert-Butylbenzene ug/L2065.0 200.0 BRL 2070-130103 4
Tetrachloroethylene ug/L2125.0 200.0 BRL 2070-130106 5
Toluene ug/L2045.0 200.0 BRL 2070-130102 3
trans-1,2-Dichloroethylene ug/L2045.0 200.0 BRL 2070-130102 4
trans-1,3-Dichloropropylene ug/L2095.0 200.0 BRL 2070-130104 1
Trichloroethylene ug/L2065.0 200.0 BRL 2070-130103 3
Trichlorofluoromethane ug/L2045.0 200.0 BRL 2060-140102 10
Vinyl acetate ug/L21050 200.0 BRL 2060-140105 0.3
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 40 of 43
1/13/20
Level II QC Report
115 Mackenan Dr. BUILDING 117
Project: Pernell GroceryWithers & Ravenel
Cary, NC 27511
Attn: Kevin Buchanan
Work Order: 0010028
Time Submitted: 1/3/2020 2:10:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P0A0097 - SM6200 B
Matrix Spike Dup (P0A0097-MSD1)Prepared & Analyzed: 01/07/20 Source: 0010028-04
Vinyl chloride ug/L2045.0 200.0 BRL 2060-140102 6
Xylenes, total ug/L61615 600.0 BRL 2070-130103 5
ug/L 50.00 70-130Surrogate: 4-Bromofluorobenzene 9849.2
ug/L 50.00 70-130Surrogate: Dibromofluoromethane 9949.7
ug/L 50.00 70-130Surrogate: Toluene-d8 10150.4
Sample Extraction Data
Prep Method: SM6200 B
Lab Number Batch Date/TimeInitialFinal
P0A00970010028-01 01/07/20 10:0010 10mL mL
P0A00970010028-01 01/07/20 10:0010 10mL mL
P0A00970010028-02 01/07/20 10:0010 10mL mL
P0A00970010028-02 01/07/20 10:0010 10mL mL
P0A00970010028-03 01/07/20 10:0010 10mL mL
P0A00970010028-03 01/07/20 10:0010 10mL mL
P0A00970010028-04 01/07/20 10:0010 10mL mL
P0A00970010028-05 01/07/20 10:0010 10mL mL
P0A00970010028-06 01/07/20 10:0010 10mL mL
P0A00970010028-07 01/07/20 10:0010 10mL mL
P0A00970010028-08 01/07/20 10:0010 10mL mL
P0A00970010028-09 01/07/20 10:0010 10mL mL
P0A00970010028-10 01/07/20 10:0010 10mL mL
P0A00970010028-11 01/07/20 10:0010 10mL mL
P0A00970010028-12 01/07/20 10:0010 10mL mL
P0A00970010028-13 01/07/20 10:0010 10mL mL
P0A00970010028-14 01/07/20 10:0010 10mL mL
This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 41 of 43
Page 42 of 43
Page 43 of 43

APPENDIX B 

COPY OF FIELD NOTES 

APPENDIX C 

PHOTOGRAPHIC DOCUMENTATION 

 Photo 1 
MW‐6 

 Photo 2 
Free Phase Product from MW‐6 

 Photo 3 
MW‐7 

 Photo 4 
MW‐8 

 Photo 5 
MW‐9 

 Photo 6 
MW‐10 

 Photo 7 
MW‐11 

 Photo 8 
MW‐12 

 Photo 9 
MW‐13 

 Photo 10 
MW‐14  

 Photo 11 
MW‐15 (site in background) 

 Photo 12 
MW‐16 (site in background) 

APPENDIX D 

GENERAL STANDARD OPERATING PROCEDURES 

Generalized Standard Operating Procedures (Not All Inclusive)

WithersRavenel

Our People. Your Success.

Soil Sampling, Soil Boring and Monitor Well Installation, Well Development

Soil borings are installed utilizing a stainless-steel hand auger, direct-push hydraulic drill or auger rotary
drill using either a macro core™ sampler, hollow stem augers, or air rotary roller cone bit. Soil borings are
typically sampled at discrete intervals from the bucket of a clean stainless steel hand auger, direct push
stainless steel sampler with acetate sleeve, or a split barrel sampler. When appropriate, soil samples may
be collected from drill cuttings associated with the boring or well installation.

Monitor wells are constructed within select soil borings of one, two, or four-inch inside diameter PVC
casing and machine slotted screen in accordance with NCAC Title 15A, Subchapter 02C (Well
Construction Standards, Criteria and Standards Applicable to Water Supply and Certain Other Wells).
Clean-washed “#2 Torpedo Sand” is typically utilized to fill the boring annulus surrounding the well
screen, extending to a minimum of 1-foot above the well screen. A minimum 1-foot thick bentonite clay
seal is emplaced above the sand pack and hydrated. Neat cement grout is placed in the remaining annulus
space from the upper portion of the bentonite seal to within 1-foot of surface grade. In coastal plain areas
where shallow groundwater is encountered, a variance to construction standards may be employed to
ensure the upper portion of the well screen intersects the upper aquifer surface. Wellheads may be
completed with either concrete-set flush mounted traffic-bearing steel skirted manholes with bolt down
covers or steel above-ground “stick-up” well protectors set in a concrete pad. The monitoring wells are
secured with locking caps. Temporary wells or piezometers may be completed with the PVC riser cut at
or above grade, and are abandoned within 24-hours of their installation.

Wells may be developed using a bailer, electric submersible pump, pneumatic pump, or peristaltic pump,
dependent upon site conditions. When wells are developed by the driller, they may be developed with
any of the methods outlined above, in addition to air or water injection. Soil boring logs and well
construction details are typically prepared for presentation in a report appendix. Borings completed in
bedrock may be drilled using air rotary, coring, or sonic drilling methods.

Groundwater Depth to Water Measurements

Groundwater level measurements are typically obtained using an electronic water level indicator which
registers a tone and/or illuminated light when the probe contacts groundwater. Depth to groundwater
measurements are obtained by lowering the probe attached to a cable usually marked in 0.01 foot
intervals into the well until the probe of the meter intersects the water surface. The measurement from
the top of the riser pipe or top of casing (TOC) to the water level is recorded to the nearest 0.01 foot. The
electronic water level indicator probe and exposed probe cable is decontaminated between measurement
locations.

Generalized Standard Operating Procedures (Not All Inclusive)

WithersRavenel

Our People. Your Success.

Free Product Level Measurements

Light Non-Aqueous Phase Liquid (LNAPL) or “free product” present on the water table is measured using
an electronic oil/water interface probe. The interface probe has both an audible and illuminating light
that indicate when a liquid level is encountered. The oil/water interface probe registers a solid tone and
solidly lit light when LNAPL petroleum product is encountered and a beeping tone flashing light when
groundwater is encountered. Depth to LNAPL measurements are obtained by lowering the probe
attached to a cable marked in 0.01 foot intervals into the well until the probe of the meter intersects the
product or groundwater. The measurements from the top of the riser pipe or TOC to the liquid level are
recorded to the nearest 0.01 foot. The thickness of LNAPL is calculated by subtracting the depth to
LNAPL measurement from the depth to groundwater measurement. The electronic interface probe is
decontaminated between measurement locations.

Soil Sampling and Field Screening

Soil sampling is performed in general accordance with ASTM: 1586-84 where applicable. Sampling
procedures are followed to protect the chemical integrity of the soil samples and minimize the potential
for cross contamination between sample locations, including discarding of the exterior of the sample
which contacts the auger bucket, acetate sleeve, or split barrel sampler, the use of stainless steel sampling
equipment, and the thorough decontamination of sampling apparatus prior to use and between sample
locations.

Soil samples retained as a part of excavation or other intrusive “digging” activities may be collected from
the bucket of excavation equipment or using a hand shovel, if appropriate. Care to collect soil samples
from excavation equipment includes retrieving native soil from material that has not made contact with
the excavating equipment. Samples are collected in sealable bags or by directly filling sample containers
as described above.

Sampling is performed using new, disposable nitrile gloves for each sample location to ensure sample
integrity and minimize the potential for cross contamination or field personnel exposure to contaminants.
Sampling equipment such as hand auger extensions and buckets, direct push samplers, split spoons or
shovels, are decontaminated prior to their use in the collection of samples.

Samples are placed within laboratory grade sample containers provided by the laboratory to which the
samples are submitted, labeled, sealed, and placed in an ice filled cooler. An aliquot of the sample is
typically placed in a clean sealable bag and allowed to reach ambient air temperature for future screening
of volatile vapor content with a photoionization detector (PID), flame-ionization detector (FID) or other
portable screening device.

Screening of samples with a PID, FID or other field screening device is performed in accordance with
device manufacturer specifications for screening, following calibration of the instrument based on
manufacturer recommended procedures.

Generalized Standard Operating Procedures (Not All Inclusive)

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Groundwater Sampling

Groundwater samples are generally collected using one of three standard methods – through the use of a
dedicated, disposable bailer, a peristaltic pump or submersible electric pump.

When sampling with a bailer, a minimum of three well volumes of groundwater are extracted from the
well as a means of purging, unless the well is purged to a “dry” state prior to the removal of three volumes
of water. Prior to collection of the groundwater sample with the bailer, the water level is allowed to
recover to within 80% of the original level measured prior to purging.

When sampling with a peristaltic or submersible electric pump, polyethylene (PE) tubing (or equivalent) is
emplaced into the screened section of the monitoring well, and the pump is used to extract water through
the tubing. When using the either of these methods, general water quality measurements including but
not limited to pH, temperature, dissolved oxygen (DO), oxygen reductive potential (ORP), specific
conductivity and turbidity may be used as methods for determining when an adequate purge of the well
has been conducted. When water quality parameters are measured, the resulting data are included in
well purge forms or field notes specific to each site and sampling point.

Following the purging of three well volumes of groundwater (in the case of the bailed well) or stability of
monitored measurements (in the case of the peristaltic or submersible electric pump), the groundwater
sample(s) are introduced directly into sample containers provided by the laboratory to which samples are
ultimately submitted for analysis. Any samples requiring chemical preservation are contained in pre-
preserved container(s) provided by the laboratory.

Sampling is performed using new, disposable nitrile gloves for each sample location to ensure sample
integrity and minimize the potential for cross contamination of samples or field personnel exposure to
contaminants.

Water Supply Well Sampling

Sampling of water supply wells is accomplished through the collection of a representative sample from an
in-line water tap or other point accessible for sampling. Where possible, the sample is collected from a
point prior to any filtration or point of entry (POE) system which might be installed on a well. In some
cases, samples will be collected from both pre and post-POE locations. Prior to the collection of samples
through an in-place sampling point, the tap or sampling port is cleaned with an Alconox® and deionized
water solution, rinsed with deionized water, and again with an isopropyl alcohol (IPA) rinse.

In the case of active supply wells (e.g., a well with a useable well pump with an active power supply), the
well pump is energized and allowed to run for a minimum of ten (10) minutes time, after which a sample is
contained in laboratory grade sample containers as described in the previous section. Water quality
parameters may be (but are not necessarily) measured in association with the well purging.

Supply wells without active power supplies are not generally sampled, as the well seal cannot be
compromised by individuals not certified as a well contractor. However, in the case of a well with no
power supply or pump installed, samples could be obtained through the use of a bailer, peristaltic pump or
electric submersible pump.
Generalized Standard Operating Procedures (Not All Inclusive)

WithersRavenel

Our People. Your Success.

Decontamination Procedures

Decontamination procedures employed in the performance of field activities will vary dependent upon
the method(s) of sampling performed at any site, but will generally include the following:

• Remove excess soil/sludge from any sampling equipment as needed,
• Wash and scrub the equipment with a phosphate-free detergent such as Alconox® or Liquinox® in a
contaminant-free tap water solution. Use a brush to remove particulate matter and surface films as
necessary,
• Rinse thoroughly with tap water,
• Rinse thoroughly with analyte-free water (deionized water),
 Rinse thoroughly with isopropyl alcohol,
• Allow the equipment to air dry,
• Prevent inadvertent contamination during storage and transport (accomplished through storage of
equipment in foil or plastic bags/sheeting).

In the case of disposable bailers and tubing utilized for the purging and sampling of wells, these items may
be decontaminated prior to their disposal. In general, no decontamination of these items is necessary
prior to their use in sampling.