RA-918_6174_CA_MRP_20200318

Groundwater Monitoring Report – Former Middleburg Grocery Property
NCDEQ Incident No. TF-6174
UST No. RA-918
ECS Project No. 49:1638-E
March 18, 2020

Mr. Mark Petermann
NCDEQ, Division of Waste Management, UST Section
1646 Mail Service Center
Raleigh, North Carolina 27699-1646

Reference: Groundwater Monitoring Report – Former Middleburg Grocery
NW Corner of US Highway 1/NC Highway 158 and North Hawkins Avenue
Middleburg, Vance County, North Carolina
NCDEQ Incident: TF-6174
UST No: RA-918
NCDEQ Contract No. N17006
ECS Project No. 49:1638-E

Dear Mr. Petermann:

As authorized by your acceptance on January 27, 2020 of ECS Southeast, LLP (ECS) to Task Authorization
Request No. 5 (TAR No. 5) dated January 22, 2020, ECS has completed the Groundwater Monitoring and
Modeling Report for the above-referenced site. Included in this report is a description of the field activities,
the results obtained, and our conclusions and recommendations. Information regarding the owner of
former underground storage tank (UST), current property owner, contacts, consultant, laboratory, release
information, and latitude and longitude are presented below.

ECS appreciates the opportunity to provide our environmental consulting services to you on this project. If
you have any questions concerning this report or this project, please contact us.

Sincerely,

ECS SOUTHEAST, LLP

Samantha M. Szakasits, G.I.T. Matthew H. McDuffie, P.G.
Assistant Staff Project Manager Principal Geologist
[e-mail] NC License No. 2269
919-861-9832 [e-mail]
704-525-5152

Groundwater Monitoring Report – Former Middleburg Grocery Property
NCDEQ Incident No. TF-6174
UST No. RA-918
ECS Project No. 49:1638-E
SITE INFORMATION

Facility I.D.: Unknown
UST Incident No.: 6174
UST No.: RA-918
Site Rank: H1102D
Land Use Category: Commercial – Vacant Land

Site Name and Location: Former Middleburg Grocery Property
NW Corner of US Highway 1/NC Highway 158 and North
Hawkins Avenue Middleburg, Vance County, North Carolina

Latitude and Longitude: 36.398464° North, -78.323876° West
Contacts

Primary Contact: William G. Wortham
179 Beaver Dam Road
Henderson, North Carolina 27537
[phone]

Consultant: ECS Southeast, LLP
9001 Glenwood Avenue
Raleigh, North Carolina 27617
[phone]
Attn: Matthew Gillis

Laboratory: Con-Test Analytical Laboratory
39 Spruce Street
East Longmeadow, MA 01028
[phone]
NC Certification No. 625

Groundwater Monitoring Report – Former Middleburg Grocery Property
NCDEQ Incident No. TF-6174
UST No. RA-918
ECS Project No. 49:1638-E
EXECUTIVE SUMMARY

The subject site is known as the Former Middleburg Grocery Property located at the northwest corner of
US Highway 1/NC Highway 158 and North Hawkins Avenue in Middleburg, Vance County, North Carolina.
The subject site is further identified by Vance County GIS Parcel Identification Number (PIN) 060404003.

INCIDENT RISK EVALUATION SUMMARY
SOURCE INFORMATION
Source & Nature of Release 3 x 1,000-gal. UST (gasoline), 2 x 550-gal. USTs (gasoline), & 1 x
280-gal UST (kerosene)
Each Known Source Removed? April 1991 and June 2004
Additional Sources Likely Present? No
Each Known Source Assessed? Yes
FREE PRODUCT
Free Product Present? Currently, No. Historically, Yes.
SITE SOIL CONDITIONS
TPH Soil Data Available? Yes
Risk-Based Soil Data Available? Yes
Extent of Soil Impact Delineated? Yes
SITE GROUNDWATER CONDITIONS
Average Depth to Groundwater? 17 feet btoc
Contaminants Present Above NC2LGWQS? Yes (Monitoring wells MW-1R, MW-4R, and MW-12)
Contaminants Present Above GCLs? No
Groundwater Plume Delineated? Not delineated to the south (calculated down-gradient
direction)
Groundwater Plume Migrated Off-Site? Yes – Potential Co-mingled Plume with Middleburg Variety site.
Contaminant Level Trend Decreasing
RECEPTOR INFORMATION
Date of Most Current Receptor Survey December 2016
Potable Water Supply Wells within 1,000’? Yes – Several water supply wells
Municipal Water Available to Each Property within 1,000’? No
Non-Potable Wells within 250’? No
Site within Wellhead Protection Area? No
Surface Water Bodies within 500’? No
REMEDIAL ACTIVITIES
What active remedial activities have been conducted? O-Sox Remedial Devices/AFVR Events
Are active remedial activities working? No
VAPOR INTRUSION
Dissolved Phase Contaminants exceeding Groundwater Screening
Levels for Vapors present within 5’ of Ground Surface? No
Occupied Structures on the Site? Vacant store building

Groundwater Monitoring Report – Former Middleburg Grocery Property
NCDEQ Incident No. TF-6174
UST No. RA-918
ECS Project No. 49:1638-E
On February 18, 2020, ECS collected a field blank and groundwater samples from monitoring wells MW-
1R, MW-2R, MW-4R, MW-6, MW-12, MW-13, and DW-1. Monitoring wells MW-5 and MW-11R were
both measured dry and therefore, groundwater samples could not be collected. Additionally, ECS
collected groundwater samples from water supply wells WSW-1, WSW-2, and WSW-13.

Laboratory analysis reported several targeted analytes at concentrations above their respective North
Carolina 2L Groundwater Quality Standard (NC2LGWQS) but below their respective Gross Contamination
Levels (GCLs) in the groundwater samples collected from monitoring wells MW-1R, MW-4R, and MW-12.
Laboratory analysis reported several additional targeted analytes above their respective laboratory
reporting limits but below their respective NC2LGWQS in the groundwater samples collected from
monitoring wells MW-1R, MW-4R, and MW-12.

Based on the results of this assessment, ECS concludes the following:

• Since the previous O-Sox deployment on June 16, 2019, benzene and ethylene dibromide (EDB)
concentrations have decreased by 76.9 and 74.7 percent (%), respectively, in the groundwater
samples collected from monitoring well MW-1R. Successfully reducing EDB below its GCL.

• Laboratory analysis detected chloroform at a concentration above the laboratory detection limit
but below its NC2LGWQS in the groundwater sample collected from water supply well WSW-1. The
chloroform detection was denoted with a J-Flag which indicates the compound was detected but
below the reporting limit; therefore, it is an estimated concentration. It is ECS’s opinion that the
result is due to a laboratory contaminant and not a contaminant of the site.

• Based on groundwater elevation data, groundwater flows towards the east – southeast away from
the closest active water supply well WSW-1.

• Previous predictive computer modeling using conservative input values indicated the existing plume
of petroleum-related compounds is not expected to be present above laboratory reporting limits or
applicable NC2LGWQS no more than 600 feet from the ‘source area’ (monitoring well MW-1R) over
a period of 100 years. Therefore, the model demonstrated water supply well WSW-16, located
approximately 700 feet downgradient and southeast of the site, is not expected to be impacted by
this release.

Based on the results and conclusions of this assessment, ECS recommends conducting two additional
groundwater monitoring events for a total of three consecutive groundwater monitoring events to
determine if concentrations remain below the GCLs along with continual redeployment of new O-SOX
remedial devices in monitoring wells MW-1R and MW-12. If concentrations continue to remain below
the GCLs after the after three consecutive groundwater monitoring events, ECS recommends the
NCDEQ consider issuing a Notice of Residual Petroleum (NRP) for soil and groundwater contamination
and the NCDEQ should consider issuing a letter of No Further Action (NFA). Additionally, if a NFA is
issued ECS recommends abandoning the monitoring wells associated with the site.

Groundwater Monitoring Report – Former Middleburg Grocery Property
NCDEQ Incident No. TF-6174
UST No. RA-918
ECS Project No. 49:1638-E

TABLE OF CONTENTS

1.0 SITE HISTORY ................................................................................................................... 1
2.0 SITE GEOLOGY AND HYDROGEOLOGY .............................................................................. 4
3.0 POTABLE WATER SUPPLY SOURCES .................................................................................. 5
4.0 FIELD ACTIVITIES .............................................................................................................. 5
5.0 LABORATORY ANALYTICAL RESULTS .................................................................................. 6
6.0 CONCLUSIONS ................................................................................................................. 7
7.0 RECOMMENDATIONS ...................................................................................................... 7

FIGURES

Figure 1 Site Location Map
Figure 2 Aerial Site Map
Figure 3 Soil Sample Concentration Map
Figure 4 Water Supply Well Location Map
Figure 5 Monitoring Well Location Map
Figure 6 Groundwater Elevation Map
Figure 7 Groundwater Concentration Map
Figure 8 Benzene Isoconcentration Map

TABLES

Table 1 UST Information
Table 2 Summary of Current and Historical Soil Sample Analytical Results
Table 3 Water Supply Well Survey
Table 4 Monitoring Well Construction & Groundwater Elevation Details
Table 5 Summary of Current Groundwater Analytical Results
Table 6 Summary of Historical Groundwater Analytical Results
Table 7 Summary of Historical Water Supply Well Groundwater Analytical Results

APPENDICIES

Appendix A Photograph Log
Appendix B ECS Personnel Field Notes & Sampling Forms
Appendix C Laboratory Analytical Data Sheets and Chain of Custody (COC) Records
Groundwater Monitoring Report – Former Middleburg Grocery Property
NCDEQ Incident No. TF-6174
UST No. RA-918
ECS Project No. 49:1638-E
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1.0 SITE HISTORY

The subject site is known as the Former Middleburg Grocery Property and is located at the northwest
corner of US Highway 1/NC Highway 158 and North Hawkins Avenue in Middleburg, Vance County, North
Carolina (Figures 1 and 2). According to information provided to ECS by the North Carolina Department of
Environmental Quality (NCDEQ), three 1,000-gallon and two 550-gallon underground storage tanks (USTs)
containing gasoline were removed from the site in April 1991. Additionally a 280-gallon kerosene UST was
removed in June 2004 (Table 1). Laboratory analysis of soil samples collected from the UST basins
following UST removal identified petroleum-related contamination originating from four of the five USTs.

In December 1990, the NCDEQ identified the Middleburg Grocery Site and the Middleburg Variety as
potential sources of petroleum contamination due to the operation of USTs and aboveground storage
tanks (ASTs) at each of the sites. The Middleburg Variety is located approximately 290 feet northeast of
the subject site.

In May 1992, Environmental Aspects, Inc. (EAI) removed one 6,000-gallon gasoline UST, one 1,000-gallon
kerosene UST, and one 1,000-gallon diesel UST from the Middleburg Variety. Additionally, EAI removed
approximately 20 cubic yards of soil from the vicinity of the kerosene UST. In August 1992, EAI removed
280 cubic yards of soil from the vicinity of the dispenser island and product lines at the Middleburg Variety.

In July 1992, Geophex, Ltd. conducted a magnetic and ground penetrating radar (GPR) survey at the
subject site and the former Fogg Property, which is located adjacent to the subject site, across North
Hawkins Avenue. The survey identified two anomalies on the Fogg Property. The anomalies included one
UST on the northern portion of the Fogg Property and one septic tank. In May 1994, ATEC Associates, Inc.
(ATEC) observed stockpiled soils on the Fogg Property. The soil was stockpiled on black plastic in the center
of the property. ATEC also observed one kerosene AST at the Middleburg Variety Store.

In 1994, a water supply well sampling event was conducted. Ten water supply wells were sampled and
targeted analytes were reported in six of the ten wells. In 1996, a study was conducted to determine the
feasibility to connect one of the residences with an impacted water supply well to the municipal water
supply. ECS is not aware of the outcome of this study.

In May and June 2001, a soil and groundwater assessment was conducted. Twelve (12) soil borings were
advanced to a depth of approximately 20 feet below the ground surface (ft bgs) in the vicinity of the
former USTs. From the twelve borings, six (6) soil samples and three groundwater samples were collected.
Laboratory analysis of three of the 6 soil samples and each of the groundwater samples reported targeted
analytes at concentrations above their respective laboratory reporting limits.

In July 2003, a receptor survey was completed. The receptor survey identified twenty-four (24) water
supply wells within 1,500 feet of the site. Nine (9) of the twenty four (24) water supply wells were
subsequently sampled. Analytical results from four of the water supply wells identified petroleum-related
impact. Also at that time, ten soil borings were advanced on the site and adjacent properties. Soil borings
SB-1, SB-3, SB-7, SB-9, and SB-10 were converted into groundwater monitoring wells (MW-1 through MW-
5) and subsequently sampled. Laboratory analysis of three (3) of the five (5) groundwater monitoring wells
reported targeted analytes at concentrations above their respective laboratory reporting limits. The
highest concentration of groundwater impacts was noted in monitoring well MW-1.
Groundwater Monitoring Report – Former Middleburg Grocery Property
NCDEQ Incident No. TF-6174
UST No. RA-918
ECS Project No. 49:1638-E
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In June 2004, contaminated soil was excavated from the vicinity of the former tank pit. During excavation
activities, an approximate 280-gallon kerosene UST was encountered and subsequently removed.
Approximately 393 tons of soil was excavated and disposed. Laboratory analysis of closure soil samples
collected from the vicinity of the kerosene UST reported total petroleum hydrocarbons-diesel range
organics (TPH-DRO) at concentrations above the NCDEQ UST Section’s Action Level.

In August 2004, soil borings were advanced on adjacent properties. Four (4) of the six (6) borings were
converted into monitoring wells (MW-6 through MW-9) and were subsequently sampled along with site
monitoring wells MW-1 through MW-5. Laboratory analysis of the groundwater samples collected from
monitoring wells MW-1, MW-5, and MW-7 reported targeted analytes at concentrations above their
respective NC2LGWQS with the highest concentrations reported in monitoring well MW-1.

In September 2006, monitoring wells MW-1R, MW-2R, MW-4R, and MW-7R were installed to replace
monitoring wells MW-1, MW-2, MW-4, and MW-7 which were dry during the May 2006 sampling event.
Upon installation, a groundwater monitoring event was conducted at the site. Laboratory analysis of the
groundwater samples collected from monitoring wells MW-1R, MW-4R, MW-5, and MW-7R reported
targeted analytes at concentrations above their respective NC2LGWQS. Laboratory analysis of
groundwater samples collected from water supply wells sampled during this sampling event did not report
targeted analytes at concentrations above their respective laboratory reporting limits.

In July 2009, Terraquest conducted a groundwater monitoring event of monitoring wells MW-1R, MW-2R,
MW-4R through MW-7R, and from water supply wells WSW-1, WSW-2, WSW-4, WSW-5, WSW-6, WSW-8,
WSW-10, and WSW-11. Laboratory analysis of the groundwater samples collected from monitoring wells
MW-1R, MW-4R, MW-5, and MW-7R reported targeted analytes at concentrations above their respective
NC2LGWQS with benzene reported above its GCL in groundwater collected from monitoring well MW-1R.
Laboratory analysis of the water supply well samples did not report targeted analytes at concentrations
above their respective laboratory reporting limits.

In December 2009, Terraquest conducted a mobile multi-phase extraction event (MMPE) on the site using
monitoring well MW-1R as an extraction point. In March 2010, monitoring wells MW-10 through MW-13
were installed and the monitoring well network was sampled. Free product at a thickness of 0.02 inches
was discovered in monitoring wells MW-1R and MW-4R. Laboratory analysis of the groundwater samples
collected from monitoring wells MW-5R, MW-7R, and MW-12 reported targeted analytes at
concentrations above their respective NC2LGWQS.

In February 2013, Terraquest conducted a monitoring well sampling event of the monitoring well network.
Free product was discovered in monitoring wells MW-1R and MW-2R and monitoring wells MW-5 and
MW-11 were dry. Laboratory analysis of the groundwater samples collected from monitoring wells MW-
4R, MW-7R, MW-14, and DW-1 reported targeted analytes at concentrations above their respective
NC2LGWQS. Terraquest recommended that an MMPE event be conducted to remove free product from
monitoring wells MW-1R and MW-2R, to install a Type II monitoring well on the off-site property across
North Lee Street from the site to further delineate the contaminant plume, to connect properties
containing water supply wells WSW-1, WSW-2, WSW-4, WSW-5, and WSW-13 to the municipal water
supply, and to continue groundwater sampling of the monitoring well network.

Groundwater Monitoring Report – Former Middleburg Grocery Property
NCDEQ Incident No. TF-6174
UST No. RA-918
ECS Project No. 49:1638-E
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On October 17, 2014, ECS collected twelve (12) groundwater samples from monitoring wells MW-1R,
MW-2R, MW-4R, MW-5, MW-6, MW-7R, MW-11 through MW-15, and DW-1 and one groundwater
sample from water supply well WSW-13. Laboratory analysis of the groundwater samples collected from
monitoring wells MW-1R and MW-12 reported 1,2-dibromoethane (EDB) at a concentration above its
NC2LGWQS and its GCL.

On May 1, 2015, ECS contracted CCI to conduct an aggressive fluid and vapor recovery (AFVR) event on
monitoring wells MW-1R and MW-12. The AFVR activities lasted eight hours and were performed in
general accordance with the Guidelines. Prior to the AFVR event, free product was not observed in
monitoring wells MW-1R and MW-12. CCI connected the AFVR recovery pump to monitoring wells MW-
1R and MW-12 and ran the vacuum from 9:00 AM on May 1, 2015 through 5:00 PM on May 1, 2015
(approximately 8 hours). A total of 600 gallons of water was removed from the monitoring wells. ECS
recorded readings and tracked the progress of the AFVR event. Depth to groundwater readings from
monitoring wells MW-2, DW-1, MW-11, and MW-13 were recorded.

On May 15, 2015, ECS collected eleven (11) groundwater samples from site monitoring wells and
collected a groundwater sample from water supply well WSW-13. In addition, ECS contracted with
Bateman Civil Survey to survey the site monitoring wells. Laboratory analysis reported EDB at a
concentration above its NC2LGWQS and its GCL in the groundwater sample collected from monitoring well
MW-12.

On March 10, 2016, ECS collected ten (10) groundwater samples from monitoring wells MW-1R, MW-
2R, MW-4R, MW-5, MW-6, MW-11 through MW-14, and DW-1, and a groundwater sample from water
supply well WSW-13. ECS installed O-SOX in monitoring wells MW-1R, MW-4R, MW-5, MW-11, and
MW-12. Laboratory analysis reported EDB at a concentration above its NC2LGWQS and its GCL in the
groundwater sample collected from monitoring well MW-12.

On June 14, 2017, ECS collected a field blank and groundwater samples from monitoring wells MW-1R,
MW-4R, MW-5, MW-11, MW-12, and DW-1. ECS removed O-SOX from monitoring wells MW-1R, MW-
4R, MW-5, MW-11, and MW-12 and installed new O-SOX in monitoring well MW-1R, MW-4R, MW-5,
and MW-12. Laboratory analysis reported EDB at a concentration above its NC2LGWQS and its GCL in the
sample collected from monitoring well MW-1R.

On June 26, 2018, ECS collected a field blank and groundwater samples from monitoring wells MW-1R,
MW-2R, MW-4R, MW-5, MW-6, MW-12, MW-13, and DW-1 and from water supply wells WSW-1,
WSW-2, and WSW-13. ECS removed O-SOX from monitoring wells MW-1R, MW-4R, MW-5, and MW-12
and installed new O-SOX in monitoring well MW-1R, MW-4R, MW-5, and MW-12. Laboratory analysis
reported EDB at a concentration above its NC2LGWQS and its GCL in the sample collected from monitoring
well MW-1R.

On July 16, 2018, ECS contracted with Quantex to advance six (6) soil borings to characterize the
horizontal and vertical extent of possible soil contamination near monitoring wells MW-1R and MW-12.
Laboratory analysis reported several targeted analytes at concentrations above their respective Soil-to-
Water Maximum Soil Contaminant Concentrations (MSCCs) but below their respective residential MSCCs
(Table 2) in soil samples SS-1-15, SS-2-15, SS-3-15, SS-5-10, and SS-5-15 (Figure 3).

Groundwater Monitoring Report – Former Middleburg Grocery Property
NCDEQ Incident No. TF-6174
UST No. RA-918
ECS Project No. 49:1638-E
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On February 14, 2019, ECS contracted with Zebra Environmental & Industrial Services (Zebra) to
conduct an AFVR event at the site using monitoring wells MW-1R and MW-12 as extraction points. On
February 22, 2019, Quantex, on behalf of ECS, installed one (1) Type II groundwater monitoring well
MW-11R. On February 27 and 28, 2019, ECS collected a field blank and groundwater samples from
monitoring wells MW-1R, MW-2R, MW-4R, MW-6, MW-11R, MW-12, MW-13, and DW-1. Additionally,
ECS collected groundwater samples from water supply wells WSW-1, WSW-2, and WSW-13. Laboratory
analysis reported benzene and EDB at a concentration above their respective NC2LGWQS and their
respective GCLs in the groundwater samples collected from monitoring well MW-1R. Laboratory analysis
reported several targeted analytes at concentrations above their respective NC2LGWQS but below their
respective GCLs in the groundwater samples collected from monitoring wells MW-1R, MW-4R, MW-11R,
and MW-12.

On July 16, 2019, ECS collected a field blank and groundwater samples from monitoring wells MW-1R,
MW-2R, MW-4R, MW-6, MW-12, MW-13, and DW-1 and from water supply wells WSW-1, WSW-2, and
WSW-13. Laboratory analysis reported EDB at a concentration above its NC2LGWQS, and its GCL in the
groundwater sample collected from monitoring well MW-1R. Laboratory analysis reported several
targeted analytes at concentrations above their respective NC2LGWQS but below their respective GCLs in
the groundwater samples collected from monitoring wells MW-1R, MW-4R, MW-11R, and MW-12.

On July 17, 2019, ECS conducted a falling and rising head slug test on monitoring wells MW-1R and MW-
12. Based on the data collected during the slug test, predictive computer modeling using conservative
input values indicate that the existing plume of petroleum-related compounds is not expected to be
present above laboratory reporting limits or applicable NC2LGWQS no more than 600 feet from the
‘source area’ (monitoring well MW-1R) over a period of 100 years. Therefore, this model demonstrates
water supply well WSW-16, located approximately 700 feet downgradient and southeast of the site, is
not expected to be impacted by this release.

2.0 SITE GEOLOGY AND HYDROGEOLOGY

As determined from the USGS Topographic Map, Middleburg, North Carolina Quadrangle dated 1970
(Figure 1), the site is located at an approximate elevation of 475 feet above mean sea level. Surface
runoff on the site is generally to the southeast.

The subject site is situated in the Piedmont Physiographic Province. The soils encountered in this area
are the residual product of in-place chemical weathering of rock presently underlying the site and/or
historic depositional events. In general, shallow unconfined groundwater movement within the
overlying soils is controlled largely by topographic gradients. However, as the groundwater percolates
downward, it becomes controlled by the subsurface geologic conditions. Thus, the direction of
groundwater movement in the deeper aquifers may not be consistent with the reflecting topography.

In general, shallow unconfined groundwater movement within the overlying soils is controlled largely by
topographic gradients. Recharge occurs primarily by infiltration along higher elevations and typically
discharges into streams or other surface water bodies. The elevation of the shallow water table is
transient and can vary with seasonal fluctuations in precipitation. Movement of shallow groundwater is
generally from higher to lower elevations.

Groundwater Monitoring Report – Former Middleburg Grocery Property
NCDEQ Incident No. TF-6174
UST No. RA-918
ECS Project No. 49:1638-E
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3.0 POTABLE WATER SUPPLY SOURCES

ECS previously conducted a receptor survey of the surrounding area to determine area receptors. ECS
observed several water supply well houses within 1,000 feet of the site. According to the Vance County
Water Department, municipal water is provided to the subject site and available to the surrounding
areas. Water supply well survey questionnaires were mailed via USPS to the property owners located
within 1,000 feet of the source area. ECS received returned surveys from Mr. Ray Bullock (45 N. Lee St.)
and Mr. Jay Taylor (6867 Broad Street) stating the properties are connected to municipal water and do
not contain water supply wells. ECS received a return survey from Ms. Destry Herring (156 Walnut St.)
stating the property is connected to municipal water and contains an inactive water supply well. ECS
also received returned surveys from Ms. Dorothy Terry (35 N. Plummer Ave. – WSW-13), Mr. Gary
Plummer (88 S. Carroll St. – WSW-10), and Ms. Destry Herring (150 S. Hawkins Ave. – WSW-15) stating
the properties contain water supply wells and are not connected to municipal water. According to Mr.
Gary Plummer there are two water supply wells located at 88 S. Carroll St. The properties associated
with water supply wells WSW-6 and WSW-7 are vacant and the water supply wells are inactive. In
addition to the returned water supply well survey letters, information provided by the Vance County
Water Department, and historical NCDEQ reports, ECS identified eleven (11) active water supply wells
and three (3) inactive water supply wells within 1,000 feet of the source area.

A summary of the water supply wells is provided on Table 3 and their locations are shown on Figure 4.

4.0 FIELD ACTIVITIES

Monitoring Well Sampling Activities

On February 18, 2020, ECS collected a field blank and groundwater samples from monitoring wells MW-
1R, MW-2R, MW-4R, MW-6, MW-12, MW-13, and DW-1. Monitoring wells MW-5 and MW-11R were
both observed to be dry and therefore, groundwater samples could not be collected. The locations of
the wells are shown on Figure 5. Site photographs documenting field activities are included in Appendix
A.

Prior to sampling, ECS removed O-SOX from monitoring wells MW-1R and MW-12. Once the O-SOX were
removed, ECS allowed the monitoring wells to equilibrate. Then, the static groundwater elevation was
measured in each monitoring well using a decontaminated water level meter. A summary of monitoring
well construction details and groundwater elevation data are included on Table 4. Based on the
groundwater elevations, groundwater flow was determined to be generally to the southeast as shown
on Figure 6. Prior to beginning groundwater sampling activities, ECS collected a field blank by pouring DI
water over the water level meter probe and into the laboratory prepared sample containers.

Purging and sampling were accomplished using a dedicated disposable bailer and nylon string. During
purging, ECS collected geochemical measurements from the monitoring wells for each well volume purged
using an YSI-556 multi-parameter meter. Immediately after collection, the groundwater samples were
transferred into sample containers provided by the laboratory. The geochemical measurements were
recorded and included in the monitoring well sampling forms provided in Appendix B.

Subsequent to sampling, ECS deployed two (2) new O-SOXs in monitoring wells MW-1R and MW-12.
Groundwater Monitoring Report – Former Middleburg Grocery Property
NCDEQ Incident No. TF-6174
UST No. RA-918
ECS Project No. 49:1638-E
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Water Supply Well Sampling Activities

On February 18, 2020, ECS collected groundwater samples from water supply wells WSW-1, WSW-2, and
WSW-13. The locations of the water supply wells are shown on Figure 4. The water supply wells were
purged by discharging water from the wells for approximately 10-15 minutes. After purging was
completed, the sampler wearing a new pair of disposable nitrile gloves for each sampling point collected a
sample from the exterior spigot on the well. Immediately after collection, the groundwater samples were
transferred into sample containers provided by the laboratory.

Sample Preparation

The sample containers were labeled with ECS project number, sample identification, sample date and
time, and requested analytical analysis. The containers were placed into protective packaging material
and placed into a cooler with ice to maintain the samples at approximately 4° Celsius (°C). The samples
were submitted to Con-Test Analytical Laboratory, a North Carolina certified laboratory located in East
Longmeadow, Massachusetts for chemical analysis for Volatile Organic Compounds (VOCs) using
Standard Method 6200B. ECS maintained proper chain of custody (COC) procedures throughout the
sample collection and transportation process. The laboratory analytical data and the COC are included in
Appendix C.

5.0 LABORATORY ANALYTICAL RESULTS

Monitoring Well Analytical Results

Laboratory analysis reported several targeted analytes at concentrations above their respective
NC2LGWQS but below their respective GCLs in the groundwater samples collected from monitoring wells
MW-1R, MW-4R, and MW-12. Laboratory analysis reported several additional targeted analytes above
their respective laboratory reporting limits but below their respective NC2LGWQS in the groundwater
samples collected from monitoring wells MW-1R, MW-4R, and MW-12.

Laboratory analysis did not report targeted analytes at concentrations above laboratory reporting limits in
the field blank or from monitoring wells MW-2R, MW-6, MW-13 and DW-1.

A summary of the current groundwater analytical results from the monitoring wells is included in Table 5
and shown on Figure 6 and an isoconcentration map illustrating the horizontal extent of benzene is shown
in Figure 8. Historical groundwater analytical results from the monitoring wells is summarized in Table 6.
The laboratory analytical data sheets and COC are included in Appendix C.

Water Supply Well Analytical Results

Laboratory analysis detected chloroform at a concentration above the laboratory detection limit but
below its NC2LGWQS in the groundwater sample collected from water supply well WSW-1. The
chloroform detection was denoted with a J-Flag which indicates the compound was detected but below
the reporting limit; therefore, it is an estimated concentration.

Groundwater Monitoring Report – Former Middleburg Grocery Property
NCDEQ Incident No. TF-6174
UST No. RA-918
ECS Project No. 49:1638-E
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Laboratory analysis did not report targeted analytes at concentrations above laboratory reporting limits
from water supply wells WSW-2 and WSW-13.

A summary of the current and historical water supply well analytical results is included in Table 7. The
laboratory analytical data sheets and COC are included in Appendix C.

6.0 CONCLUSIONS

Based on the results of this assessment, ECS concludes the following:

• Since the previous O-Sox deployment on June 16, 2019, benzene and EDB concentrations have
decreased by 76.9 and 74.7 percent (%), respectively, in the groundwater samples collected from
monitoring well MW-1R. Successfully reducing EDB below its GCL.

• Laboratory analysis detected chloroform at a concentration above the laboratory detection limit
but below its NC2LGWQS in the groundwater sample collected from water supply well WSW-1. The
chloroform detection was denoted with a J-Flag which indicates the compound was detected but
below the reporting limit; therefore, it is an estimated concentration. It is ECS’s opinion that the
result is due to a laboratory contaminant and not a contaminant of the site.

• Based on groundwater elevation data, groundwater flows towards the east – southeast away from
the closest active water supply well WSW-1.

• Previous predictive computer modeling using conservative input values indicated the existing plume
of petroleum-related compounds is not expected to be present above laboratory reporting limits or
applicable NC2LGWQS no more than 600 feet from the ‘source area’ (monitoring well MW-1R) over
a period of 100 years. Therefore, the model demonstrated water supply well WSW-16, located
approximately 700 feet downgradient and southeast of the site, is not expected to be impacted by
this release.

7.0 RECOMMENDATIONS

Based on the results and conclusions of this assessment, ECS recommends conducting two additional
groundwater monitoring events for a total of three consecutive groundwater monitoring events to
determine if concentrations remain below the GCLs along with continual redeployment of new O-SOX
remedial devices in monitoring wells MW-1R and MW-12. If concentrations continue to remain below
the GCLs after the after three consecutive groundwater monitoring events, ECS recommends the
NCDEQ consider issuing a NRP for soil and groundwater contamination and the NCDEQ should consider
issuing a letter of NFA. Additionally, if a NFA is issued ECS recommends abandoning the monitoring
wells associated with the site.

FIGURES
SOURCE:
USGS TOPOGRAPHIC MAPMIDDLEBURGNC QUADRANGLEDATED 1970
SCALE: 1 : 24,000
FIGURE 1
SITE LOCATION MAP
FORMER MIDDLEBURG GROCERY PROPERTY
NW CORNER OF US HIGHWAY 1/NC HIGHWAY
158 AND NORTH HAWKINS AVENUE
MIDDLEBURG, VANCE COUNTY,
NORTH CAROLINA
NCDEQ INCIDENT NO. TF-6174
ECS PROJECT NO. 49:1638-E
SITE
FIGURE 2
AERIAL SITE MAP
FORMER MIDDLEBURG GROCERY PROPERTY
NW CORNER OF US HIGHWAY 1/NC HIGHWAY
158 AND NORTH HAWKINS AVENUE
MIDDLEBURG, VANCE COUNTY,
NORTH CAROLINA
NCDEQ INCIDENT NO. TF-6174
ECS PROJECT NO. 49:1638-E
SOURCE:
VANCE COUNTY GIS
DATED 2013
SCALE AS SHOWN
SITE
SINGLE-FAMILY RESIDENCES
AGRICULTURAL LAND
AGRICULTURAL
LAND
FOGG PROPERTY
MIDDLEBURG
VARIETY
SOURCE:
VANCE COUNTY GISDATED 2013
SCALE AS SHOWN
FIGURE 3SOIL SAMPLE CONCENTRATION MAP
FORMER MIDDLEBURG GROCERY PROPERTY
NW CORNER OF US HIGHWAY 1/NC HIGHWAY
158 AND NORTH HAWKINS AVENUE
MIDDLEBURG, VANCE COUNTY,
NORTH CAROLINA
NCDEQ INCIDENT NO. TF-6174
ECS PROJECT NO. 49:1638-E
LEGEND
Approximate Location of Soil Sample
0.085 Concentration Above the Soil-to-Water MSCC
SS-1-10
SS-1-10
Below
MSCCs
SS-1-15
tert-Butyl Alcohol 0.085 SS-2-10
Below
MSCCs
SS-2-15
Benzene 0.34
p-Isopropyltoluene 0.26J
MTBE 0.26J
Naphthalene 4.7
Toluene 4.5
1,2,4-Trimethylbenzene 21
Total Xylenes 27.1
1-Methylnaphthalene 0.29J
C9-C22 Aromatics 146
SS-3-10
Below
MSCCs
SS-3-15
Naphthalene 0.95
C9-C22 Aromatics 76
SS-4-10
SS-4-15
Below
MSCCs
SS-5-10
SS-5-15
Benzene 0.052
1,2-Dibromoethane 0.0035
1,2-Dichloroethane 0.011
Naphthalene 4.7
Toluene 4.5
1,2,4-Trimethylbenzene 21
Total Xylenes 27.1
1-Methylnaphthalene 0.29J
C9-C22 Aromatics 146
1,2-Dichloroethane 0.0027
SS-6-10
SS-6-15
Below MSCCs
FIGURE 4
WATER SUPPLY WELL LOCATION MAP
FORMER MIDDLEBURG GROCERY PROPERTY
NW CORNER OF US HIGHWAY 1/NC HIGHWAY
158 AND NORTH HAWKINS AVENUE
MIDDLEBURG, VANCE COUNTY,
NORTH CAROLINA
NCDEQ INCIDENT NO. TF-6174
ECS PROJECT NO. 49:1638-E
SOURCE:
VANCE COUNTY GIS
DATED 2013
SCALE AS SHOWN
LEGEND
Approximate Location of Active Water Supply Well
Approximate Location of Inactive Water Supply Well
NOTES:1.) *Two (2) Water Supply Wells located on the property.
500 ft.
Radius
1,000 ft. Radius
WSW-1
SITE
WSW-6
WSW-7
WSW-1
WSW-13
WSW-2
WSW-14
WSW-15
WSW-10*WSW-9
WSW-8
WSW-6
WSW-3
WSW-11
WSW-12
WSW-16
SOURCE:
VANCE COUNTY GISDATED 2013
SCALE AS SHOWN
FIGURE 5
MONITORING WELL LOCATION MAP
FORMER MIDDLEBURG GROCERY PROPERTY
NW CORNER OF US HIGHWAY 1/NC HIGHWAY
158 AND NORTH HAWKINS AVENUE
MIDDLEBURG, VANCE COUNTY,
NORTH CAROLINA
NCDEQ INCIDENT NO. TF-6174
ECS PROJECT NO. 49:1638-E
LEGEND
Approximate Location of Monitoring Well
Former Location of USTs
Former Location of Kerosene UST
MW-6
MW-4R
MW-1R
MW-14
MW-5
MW-7R
MW-6
MW-2R
MW-15
MW-10
MW-12
MW-13
DW-1
FOGG
PROPERTY
MIDDLEBURG
VARIETY
MW-11R
SOURCE:
VANCE COUNTY GISDATED 2013
SCALE AS SHOWN
FIGURE 6
GROUNDWATER ELEVATION MAP
FORMER MIDDLEBURG GROCERY PROPERTY
NW CORNER OF US HIGHWAY 1/NC HIGHWAY
158 AND NORTH HAWKINS AVENUE
MIDDLEBURG, VANCE COUNTY,
NORTH CAROLINA
NCDEQ INCIDENT NO. TF-6174
ECS PROJECT NO. 49:1638-E
MW-7R
CNL
MW-2R
455.36 MW-10
CNL
MW-15
CNL
MW-14
NM
MW-6
454.63
MW-4R
452.45
DW-1*
452.09
MW-1R
454.59
MW-12
454.47MW-13
453.20
MW-5
DRY
MW-11R
DRY
LEGEND
Approximate Location of Monitoring Well
(454.00)Groundwater Elevation
Groundwater Contour Line
Estimated Direction of Groundwater Flow
NM Not Measured
CNL Could Not Locate
NOTES:
1.) The site vertical datum is based on NAV88 and the horizontal datum is
based on NAD83.2.) *Deep monitoring well DW-1 was not included in determining
the groundwater flow direction.
MW-2R
SOURCE:
VANCE COUNTY GISDATED 2013
SCALE AS SHOWN
FIGURE 7
GROUNDWATER CONCENTRATION MAP
FORMER MIDDLEBURG GROCERY PROPERTY
NW CORNER OF US HIGHWAY 1/NC HIGHWAY
158 AND NORTH HAWKINS AVENUE
MIDDLEBURG, VANCE COUNTY,
NORTH CAROLINA
NCDEQ INCIDENT NO. TF-6174
ECS PROJECT NO. 49:1638-E
MW-14
NSMW-5
DRY
MW-6
BRL
MW-11
DRY
LEGEND
Approximate Location of Monitoring Well
28 Concentration Above the Laboratory Reporting Limit (µg/L)
970 Concentration Above the NC2LGWQS (µg/L)
BRL Below Laboratory Reporting Limit
NS Not Sampled
J Estimated concentration
MW-5
DW-1
BRL
MW-13
BRL
MW-2R
BRL
MW-1R
Benzene 970
Toluene 2,500
Ethylbenzene 230
Total Xylenes 2,650
n-Butylbenzene 9.2 J
1,2-Dibromeoethane 38
Diisopropyl ether 28
Isopropylbenzene 12 J
Methyl-tert-butyl ether 34
Naphthalene 360
n-Propropylbenzene 20
Styrene 6.0 J
1,2,4-Trimethylbenzene 460
1,3,5-Trimethylbenzene 220
MW-4R
Benzene 63
Toluene 2.2
Ethylbenzene 16
Total Xylenes 12
n-Butylbenzene 5.0
sec-Butylbenzene 1.8
1,2-Dichloroethane 0.93 J
Diisopropyl ether 1.2
Isopropylbenzene 11
p-Isopropyltoluene 1.2
Methyl-tert-butyl ether 0.92
Naphthalene 47
n-Propropylbenzene 12
Styrene 0.42 J
1,2,4-Trimethylbenzene 4.8
1,3,5-Trimethylbenzene 5.9
MW-12
Benzene 1,700
Toluene 3,400
Ethylbenzene 1,200
Total Xylenes 7,400
n-Butylbenzene 16 J
1,2-Dichloroethane 120
Diisopropyl ether 150
Isopropylbenzene 35
Methyl-tert-butyl ether 290Naphthalene500
n-Propropylbenzene 86
Styrene 24 J1,2,4-Trimethylbenzene 1,000
1,3,5-Trimethylbenzene 330
SOURCE:
VANCE COUNTY GIS
DATED 2013
SCALE AS SHOWN
FIGURE 8BENZENE ISOCONCENTRATION MAP
FORMER MIDDLEBURG GROCERY PROPERTY
NW CORNER OF US HIGHWAY 1/NC HIGHWAY
158 AND NORTH HAWKINS AVENUE
MIDDLEBURG, VANCE COUNTY,
NORTH CAROLINA
NCDEQ INCIDENT NO. TF-6174
ECS PROJECT NO. 49:1638-E
MW-14
NS
MW-7R
CNL
MW-6
BRL
MW-15
CNL
MW-10
CNL
LEGEND
Approximate Location of Monitoring Well
Benzene Isoconcentration Contour (µg/L)
1,700 Bold Concentration Above the NC2LGWQS
BRL Below Laboratory Reporting Limit
CNL Could Not Locate
NS Not Sampled
NOTES:
1.) *Deep monitoring well DW-1 was not included in determining the
horizontal extent of benzene.
MW-5
MW-5
Dry
MW-4R
63
MW-11
Dry
MW-13
BRL
1,000
*DW-1
BRL
MW-2R
BRL
10
MW-12
1,700
MW-1R
970

TABLES
UST ID
Number Last Contents Previous
Contents
Capacity
(in Gallons)
Construction
Details
Tank
Dimensions
Installation
Date
Removal
Date Status
1 Gasoline Gasoline 1,000 Unknown 12'1"x3'10"Unknown April 1991 Removed
2 Gasoline Gasoline 1,000 Unknown 12'1"x3'10"Unknown April 1991 Removed
3 Gasoline Gasoline 1,000 Unknown 10'8"x4'Unknown April 1991 Removed
4 Gasoline Gasoline 550 Unknown 7'9"x3'6"Unknown April 1991 Removed
5 Gasoline Gasoline 550 Unknown 7'9"x3'6"Unknown April 1991 Removed
6 Kerosene Kerosene 280 Unknown Unknown Unknown June 2004 Removed
Middleburg, Vance County, North Carolina
ECS Project No. 49:1638-E
Table 1
UST Information
Former Middleburg Grocery Property
NW Corner of US Highway 1/NC Highway 158 and North Hawkins Avenue
NCDEQ Incident No. TF-6174
EPA Method 5030 EPA Method 3550
S-1 4/20/1991 NA 163 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NSS-2 4/20/1991 NA 0.61 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NSS-3 4/20/1991 NA 220 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NSS-4 4/20/1991 NA 153 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NSS-5 4/20/1991 NA 199 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NSS-6 4/20/1991 NA 204 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NSS-7 4/20/1991 NA 32.3 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NSS-8 4/20/1991 NA 214 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NSS-9 4/20/1991 NA 3.7 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NSS-10 4/20/1991 NA BRL NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS1-1 3/9/1992 NA BRL BRL NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS1-2 3/9/1992 NA BRL BRL NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS1-3 3/9/1992 NA BRL BRL NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS2-1 3/9/1992 NA BRL BRL NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS2-2 3/9/1992 NA BRL BRL NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS3-1 3/9/1992 NA BRL 4,280 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS3-2 3/9/1992 NA BRL 553 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS3-3 3/9/1992 NA BRL 63.2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS2-3 3/9/1992 NA BRL BRL NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NSSP-1 6/2/1994 NA NT BRL NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NSSP-2 6/2/1994 NA NT BRL NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS1010----------------------------------------------------0.0056 4.3 3.3 0.000098 0.0019 0.37 4.9 1.7 0.12 0.091 0.16 1.7 0.04 4.3 8.5 8.3 4.6 0.004 3.6 0.16 68 540 NE 31----18 626 626 0.31 7 156 1,560 1,564 100 350 313 626 213 1,200 782 782 3,129 20 63 313 939 1,500 31,000 469
NOTES:NCDEQ = North Carolina Department of Environmental Quality
MSCC = Maximum Soil-to-Groundwater Contaminant Concentration Levels
mg/kg = milligrams per kilogram
ft. bgs = feet below the ground surface
TPH-GRO = Total Petroleum Hydrocarbons-Gasoline Range Organics
TPH-DRO = Total Petroleum Hydrocarbons-Diesel Range Organics
Bold = Detected above the NCDEQ Action Level or Soil-to-Groundwater MSCC
Underlined = Detected above the Soil-to-Groundwater MSCC and the Residential MSCC
NA = Not ApplicableNS = Not Sampled
BRL = Below Reporting Limit
NCDEQ UST Section's Action Level (mg/kg)Soil-to-Groundwater MSCC (mg/kg)Residential MSCC (mg/kg)
J = Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
ECS Project No. 49:1638-E
Analytical Method MADEP EPH/VPH
1,3,5-Trimethylbenzene1,2,4-TrimethlbenzeneTolueneSample ID Total XylenesC5-C8 AliphaticsEPA Method 8260
Methyl-tert-butyl etherTPH-GROBenzeneC9-C18 AliphaticsDate Collected Diispropyl etherTable 2Summary of Current and Historical Soil Sample Analytical ResultsFormer Middleburg Grocery Property
Middleburg, Vance County, North CarolinaNCDEQ Incident No. TF-6174
Contaminant of Concern (mg/kg)
NW Corner of US Highway 1/NC Highway 158 and North Hawkins Avenue
n-PropylbenzeneNaphthaleneEthylbenzenen-Butylbenzenesec-ButylbenzeneIsopropylbenzenep-IsopropyltolueneDepth Collected (ft.bgs)
EPA Method 8270
1,2-Dichloroethane1,2-DibromoethaneC9-C22 AromaticsNaphthaleneTPH-DRO1-Methylnaphthalene2-MethylnaphthaleneC19-C36 Aliphaticstert-Butyl Alcohol
EPA Method 5030 EPA Method 3550
B2 5/31/2001 16 NS NS BRL 8,800 BRL BRL BRL BRL 4,700 BRL BRL BRL 21,000 5,700 BRL BRL 55,000 16,000 34,000 340 1,600 BRL 340 1,600 BRL 170B35/31/2001 16 NS NS BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRLB55/31/2001 16 NS NS BRL 7,300 BRL BRL BRL BRL 5,900 BRL BRL BRL 17,000 5,500 BRL 4,000 47,000 14,000 37,000 400 770 BRL 400 770 BRL 86B75/31/2001 16 NS NS BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRLB85/31/2001 16 NS NS BRL BRL BRL BRL BRL BRL BRL BRL BRL 22 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRLB95/31/2001 16 NS NS BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRLSS-1-10 7/16/2018 10 NS NS BRL BRL BRL BRL BRL BRL BRL BRL BRL 0.0066 BRL BRL BRL BRL BRL 0.0032 0.00545 BRL BRL BRL BRL BRL 30 20SS-1-15 7/16/2018 15 NS NS BRL BRL BRL BRL BRL BRL BRL BRL BRL 0.0061 0.0031J BRL 0.085 0.0026 0.0037 0.0038 0.0114 BRL BRL BRL BRL BRL 27 19SS-2-10 7/16/2018 10 NS NS BRL 0.0027 BRL BRL BRL BRL BRL BRL BRL BRL 0.013 0.0027 BRL BRL 0.0068 0.0056 0.006 BRL BRL BRL BRL 21 BRL BRLSS-2-15 7/16/2018 15 NS NS 0.34 2.7 0.38 BRL BRL BRL 3.6 0.64 0.26J 0.26J 4.7 2.4 BRL 4.5 21 6.8 27.1 0.29J 0.62 0.27J BRL 38 BRL 146SS-3-10 7/16/2018 10 NS NS 0.0011J BRL BRL BRL BRL 0.00069J BRL BRL BRL 0.0077 BRL 0.0025 BRL 0.0023 0.00093J 0.0036 0.0083 BRL BRL BRL BRL BRL 22 19SS-3-15 7/16/2018 15 NS NS 0.039J 0.39 0.037J BRL BRL BRL 0.16 0.032J 0.032J 0.082 0.95 0.14 BRL 0.32 2.1 0.67 1.63 BRL BRL BRL 38 16 BRL 76SS-4-10 7/16/2018 10 NS NS BRL BRL BRL BRL BRL BRL BRL BRL BRL 0.0034J BRL BRL BRL BRL BRL 0.0033 BRL BRL BRL BRL BRL BRL BRL BRLSS-4-15 7/16/2018 15 NS NS 0.0032 BRL BRL BRL BRL 0.0015 BRL BRL BRL 0.0078 BRL BRL BRL 0.0059 0.0022J 0.004 0.0137 BRL BRL BRL BRL BRL BRL BRLSS-5-10 7/16/2018 10 NS NS BRL BRL BRL BRL 0.0027 0.0025 BRL BRL BRL 0.0094 BRL BRL BRL BRL BRL 0.0032 0.0013 BRL BRL BRL BRL BRL 27 20SS-5-15 7/16/2018 15 NS NS 0.052 0.00076J BRL 0.0035 0.011 0.012 0.0078 BRL BRL 0.045 0.0077 0.0028 BRL 0.091 0.018 0.0087 0.078 BRL BRL BRL BRL BRL BRL BRLSS-6-10 7/16/2018 10 NS NS BRL BRL BRL BRL BRL 0.0012J BRL BRL BRL 0.0031J BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRLSS-6-15 7/16/2018 15 NS NS BRL BRL BRL BRL 0.0013J 0.0012 BRL BRL BRL 0.0052 BRL BRL BRL BRL BRL 0.0027 BRL BRL BRL BRL BRL BRL BRL BRL1010----------------------------------------------------0.0056 4.3 3.3 0.000098 0.0019 0.37 4.9 1.7 0.12 0.091 0.16 1.7 0.04 4.3 8.5 8.3 4.6 0.004 3.6 0.16 68 540 NE 31----18 626 626 0.31 7 156 1,560 1,564 100 350 313 626 213 1,200 782 782 3,129 20 63 313 939 1,500 31,000 469
NOTES:NCDEQ = North Carolina Department of Environmental Quality
MSCC = Maximum Soil-to-Groundwater Contaminant Concentration Levels
mg/kg = milligrams per kilogram
ft. bgs = feet below the ground surface
TPH-GRO = Total Petroleum Hydrocarbons-Gasoline Range Organics
TPH-DRO = Total Petroleum Hydrocarbons-Diesel Range Organics
Bold = Detected above the NCDEQ Action Level or Soil-to-Groundwater MSCC
Underlined = Detected above the Soil-to-Groundwater MSCC and the Residential MSCCNA = Not Applicable
NS = Not Sampled
BRL = Below Reporting Limit C9-C18 AliphaticsC19-C36 AliphaticsC9-C22 AromaticsSample ID Date Collected Depth Collected (ft.bgs)1,3,5-TrimethylbenzeneTotal Xylenes1-Methylnaphthalene2-MethylnaphthaleneNaphthaleneC5-C8 AliphaticsMethyl-tert-butyl etherNaphthalenen-Propylbenzenetert-Butyl AlcoholToluene1,2,4-Trimethlbenzene1,2-Dibromoethane1,2-DichloroethaneDiispropyl etherEthylbenzeneIsopropylbenzenep-IsopropyltolueneAnalytical Method EPA Method 8260 EPA Method 8270 MADEP EPH/VPHContaminant of Concern (mg/kg)TPH-GROTPH-DROBenzenen-Butylbenzenesec-ButylbenzeneMiddleburg, Vance County, North CarolinaNCDEQ Incident No. TF-6174ECS Project No. 49:1638-E
Residential MSCC (mg/kg)
J = Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
Soil-to-Groundwater MSCC (mg/kg)
Table 2 (continued)Summary of Current and Historical Soil Sample Analytical ResultsFormer Middleburg Grocery Property
NCDEQ UST Section's Action Level (mg/kg)
NW Corner of US Highway 1/NC Highway 158 and North Hawkins Avenue
Water Supply
Well ID Well Owner / Address Well Address Well Use Well Depth
(ft bgs)Type of Well
Approximate Distance from
Source Area of Release
WSW-1
Kim Lofton
33 North Hawkins Avenue Middleburg, NC 27556
33 North Hawkins Avenue Middleburg, NC 27556 Active Unknown Drilled 250 feet northwest
WSW-2
Middleburg Baptist Church
c/o Marsha Lougee PO Box 57 Middleburg, NC 27556
80 North Plummer Avenue Middleburg, NC 27556 Active Unknown Drilled 490 feet northwest
WSW-3 Annie Fudge PO Box 344 Middleburg, NC 27556
54 North Hawkins Drive
Middleburg, NC 27556 Active Unknown Drilled 330 feet
northeast
WSW-6
Raymond Glasco Jr.
3295 Viero Drive Colorado Springs, CO 80916
30 South Hawkins Avenue Middleburg, NC 27556 Inactive Unknown Drilled 270 feet south
WSW-7 Kristy Stainbeck PO Box 219
Middleburg, NC 27556
Corner of South Hawkins & Chestnut Street
Middleburg, NC 27556
Inactive Unknown Drilled 245 feet southeast
WSW-8 Ronald & Nancy Stainback PO Box 41
Middleburg, NC 27556
175 Chestnut Street
Middleburg, NC 27556 Active Unknown Drilled 800 feet
southeast
WSW-9
Charlie Plummer
PO Box 21137 Durham, NC 27703
321 Chestnut Street
Middleburg, NC 27556 Active Unknown Drilled 800 feet
southwest
WSW-10*
Andrew & Eva Plummer
PO Box 85
Middleburg, NC 27556
88 South Carroll Street Middleburg, NC 27556 Active 265.00 Drilled 850 feet southwest
WSW-11 Michael Jones PO Box 262
Middleburg, NC 27556
123 Chestnut Street
Middleburg, NC 27556 Active Unknown Drilled 840 feet
southeast
WSW-12
Kristy Stainbeck
PO Box 219 Middleburg, NC 27556
98 Chestnut Street
Middleburg, NC 27556 Active Unknown Drilled 915 feet
southeast
WSW-13
William & Dorothy Terry
PO Box 122
Middleburg, NC 27556
35 North Plummer Avenue Middleburg, NC 27556 Active Unknown Drilled 440 feet west
WSW-14 Middleburg Baptist Church 156 Walnut Street
Middleburg, NC 27556
156 Walnut Street
Middleburg, NC 27556 Inactive Unknown Drilled 720 feet northeast
WSW-15 Destry Herring 150 South Hawkins Avenue Middleburg, NC 27556
150 South Hawkins
Middleburg, NC 27556 Active Unknown Drilled 900 feet
southeast
WSW-16
Kenneth Moody
PO Box 296 Middleburg, NC 27556
120 South Hawkins Avenue Middleburg, NC 27556 Active Unknown Drilled 700 feet southeast
NOTES:
ECS Project No. 49:1638-E
* = 2 Water Supply Wells located on the property
Table 3
Water Supply Well Survey
Former Middleburg Grocery Property
NW Corner of US Highway 1/NC Highway 158 and North Hawkins Avenue
Middleburg, Vance County, North Carolina
NCDEQ Incident No. TF-6174
Monitoring
Well ID
Date
Measured
Depth to
Groundwater
(ft. btoc)
Casing Inner
Diameter
(I.D. in.)
Date
Installed
Total Well
Depth
(ft. btoc)
Screen
Interval
(ft. btoc)
TOC
Elevation*
Groundwater
Elevation
MW-1R 19.42 2 8/29/2006 30 15-30 474.01 454.59
MW-2R 18.87 2 8/29/2006 30 15-30 474.23 455.36
MW-4R 19.87 2 8/29/2006 29 14-29 472.32 452.45
MW-5 Dry 2 Unknown 22 12-22 472.46 --
MW-6 13.52 2 Unknown 23 13-23 468.15 454.63
MW-7R CNL 2 Unknown Unknown Unknown NM --
MW-10 CNL 2 Unknown Unknown Unknown NM --
MW-11R Dry 2 2/22/2019 21 11-21 NM --
MW-12 18.93 2 3/30/2010 25 15-25 473.40 454.47
MW-13 20.82 2 3/30/2010 30 10-30 474.02 453.20
MW-14 NM 2 10/25/2011 29 14-29 469.45 --
MW-15 CNL 2 10/25/2011 25 10-25 464.75 --
DW-1 21.98 2 10/25/2011 50 45-50 474.33 452.35
NOTES:
I.D. in. = Inside Diameter in Inches
NM = Not Measured
Table 4
Monitoring Well Construction and Groundwater Elevation Details
Former Middleburg Grocery Property
NW Corner of US Highway 1/NC Highway 158 and North Hawkins Avenue
Middleburg, Vance County, North Carolina
ECS Project No. 49:1638-E
CNL = Could Not Locate
NCDEQ Incident No. TF-6174
*Survey performed by Bateman Civil Survey on May 15, 2015. The site vertical datum is based on NAV88 and the horizontal
datum is based on NAD83.
ft. btoc = Feet Below Top of Casing
TOC = Top of Casing
2/18/2020
Sample ID Sample Date
BenzeneTolueneEthylbenzeneTotal Xylenesn-Butylbenzenesec-ButylbenzeneChloroform1,2-Dibromoethane (EDB)1,2-DichloroethaneDiisopropyl ether (DIPE or IPE)Isopropylbenzenep-IsopropyltolueneMethyl-tert-butyl ether (MTBE)Naphthalenen-PropylbenzeneStyrene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneMW-1R 970 2,500 230 2,650 9.2 J BRL BRL 38 BRL 28 12 J BRL 34 360 20 6.0 J 460 220
MW-2R BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL
MW-4R 63 2.2 16 12 5.0 1.8 BRL BRL 0.93 J 1.2 11 1.2 0.92 47 12 0.42 J 4.8 5.9MW-5
MW-6 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRLMW-11R
MW-12 1,700 3,400 1,200 7,400 16 J BRL BRL BRL 120 150 35 BRL 290 500 86 24 J 1,000 330
MW-13 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRLDW-1 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL
WSW-1 BRL BRL BRL BRL BRL BRL 0.38 J BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRLWSW-2 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL
WSW-13 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL
Field Blank BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL16006005007070700.02 100 70 70 25 20 6 70 70 400 4005,000 260,000 84,500 85,500 6,900 8,500 70,000 50 100,000 70,000 25,000 11,700 20,000 6,000 30,000 70,000 28,500 25,000
NOTES:
NC2LGWQS = North Carolina 2L Groundwater Quality Standard as of April 1, 2013
GCL = NCDEQ's Gross Contamination Levels for Groundwater as of April 16, 2012
Bold = Detected above the NC2LGWQS
Underlined = Detected above both the NC2LGWQS and the GCL
µg/L = Micrograms per Liter
BRL = Below Reporting Limit
J = Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
Contaminant of Concern (µg/L)Analytical Method
Summary of Current Groundwater Analytical Results
Middleburg, Vance County, North Carolina
NCDEQ Incident No. TF-6174
GCL (µg/L) NC2LGWQS (µg/L)
Table 5
Former Middleburg Grocery Property
NW Corner of US Highway 1/NC Highway 158 and North Hawkins Avenue
ECS Project No. 49:1638-E
2/18/2020
Dry
Dry
Standard Method 6200B
Sample ID Date
BenzeneTolueneEthylbenzeneTotal XylenesAcetone2-Butanone (MEK)Bromoethanen-Butylbenzenesec-ButylbenzeneChloroform1,3-Dichlorobenzene1,4-Dichlorobenzene1,1-Dichloroethane1,2-Dichloroethane1,1-Dichloropropylene1,1-Dichloroporpane1,2-Dichloropropoane1,3-Dichloropropane1,2-Dibromoethane (EDB)cis-1,2- DichloroetheneDiisopropyl ether (DIPE or IPE)2-HexanoneIsopropylbenzenep-IsopropyltolueneMethyl Isobutyl Ketone (MIBK)Methyl-tert-butyl ether (MTBE)Naphthalenen-PropylbenzeneStyreneTetrachloroetheneTrichloroethene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene9/12/2006 9,840 12,900 2,680 13,680 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 1,910 960 BRL BRL BRL BRL 2,520 600
7/28/2009 13,000 19,000 1,900 9,800 BRL BRL BRL BRL BRL BRL BRL BRL BRL 320 BRL BRL BRL BRL 310 BRL 370 BRL 64 BRL BRL 2,800 410 200 57 BRL BRL 1,700 4503/31/20102/19/201310/17/2014 3,920 7,220 768 4,930 BRL BRL BRL BRL 4.7 BRL BRL BRL BRL 163 BRL BRL BRL BRL 163 BRL 122 BRL 31.7 BRL BRL 521 323 93.4 29.8 BRL BRL 846 2045/14/2015 1,090 3,100 419 2,904 BRL BRL BRL BRL BRL BRL BRL BRL BRL 16.3 BRL BRL BRL BRL 27.7 BRL 17.7 BRL 20.4 BRL BRL 61.5 221 59.9 12.9 BRL BRL 683 1723/10/2016 170 410 130 1,500 BRL BRL BRL 13 2.1 BRL BRL BRL BRL 3.8 BRL BRL BRL BRL 4.4 BRL 3.6 BRL 16 1.4 BRL BRL 230 35 2.2 BRL BRL 320 926/14/2017 2,560 3,430 205 3,510 BRL BRL BRL BRL BRL BRL BRL BRL BRL 59.4 BRL BRL BRL BRL 77.4 BRL 74.2 BRL BRL BRL BRL 238 179 BRL BRL BRL BRL 494 BRL6/26/2018 3,200 7,400 750 7,700 BRL BRL BRL 100 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 110 BRL 88 BRL 39 10J BRL 310 350 BRL BRL BRL BRL 1,700 5302/14/2019*2,700 6,600 700 6,700 BRL BRL BRL 89 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 110 BRL 84 BRL 45 J BRL BRL 150 350 140 BRL BRL BRL 1,500 5002/28/2019**7,300 19,000 1600 11,400 BRL BRL BRL 34 J BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 190 BRL 120 BRL 54 J BRL BRL 180 930 150 58 J BRL BRL 1,900 470
7/16/2019 4,200 12,000 980 8,200 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 150 BRL 84 J BRL 48 J BRL BRL 350 1,300 130 BRL BRL BRL 1,300 4302/18/2020 970 2,500 230 2,650 BRL BRL BRL 9.2 J BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 38 BRL 28 BRL 12 J BRL BRL 34 360 12 0.42 J BRL BRL 460 2209/12/2006 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL7/28/2009 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL3/31/2010 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL10/26/2011 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL2/19/201310/17/2014 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL5/14/2015 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL3/10/2016 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL6/26/2018 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL2/28/2019 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL7/16/2019 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 0.85 BRL BRL BRL BRL BRL BRL2/18/2020 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL9/12/2006 179 17 82 213 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 54 BRL BRL BRL BRL 195 1297/28/2009 19 4 40 99 BRL BRL BRL 22 6 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 10 3.3 BRL BRL 37 27 BRL BRL BRL 120 733/31/20102/19/2013 110 92 130 340 BRL BRL BRL 81 9.7 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 2.5 BRL 2.5 7.7 BRL 5.8 78 51 BRL BRL BRL 360 17010/17/2014 24.3 1.6 3.5 5.2 BRL BRL BRL 2.8 0.69 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 0.65 BRL 1.2 BRL BRL 0.80 6.2 1.8 BRL BRL BRL 7.0 5.65/14/2015 13.8 0.71 1.3 6.7 BRL BRL BRL 0.88 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 1.8 BRL BRL BRL 6.7 0.51 BRL BRL BRL 1.6 1.53/10/2016 15 BRL 3.2 3.6 BRL BRL BRL 0.67 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 2.4 BRL BRL BRL 15 0.71 BRL BRL BRL BRL BRL6/14/2017 66 1.7 76.4 BRL BRL BRL BRL BRL 1.0 BRL BRL BRL BRL 0.58 BRL BRL BRL BRL BRL BRL 0.67 BRL 10.4 BRL BRL BRL 85.2 15.8 BRL BRL BRL BRL 11.76/26/2018 25 0.33 14 0.76 BRL BRL BRL 2.5 0.73 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 0.50 BRL 4.5 0.54 BRL 1.3 27 5.5 BRL BRL BRL 1.1 3.72/28/2019 14 0.17 J 4.4 0.62 J BRL BRL BRL 2.5 0.77 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 4.40 BRL 3.1 0.52 BRL 0.40 J 16 3.4 BRL BRL BRL 1.1 3.57/16/2019 6.6 BRL 1.0 BRL BRL BRL BRL 1.9 0.35 J BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 1.5 0.28 J BRL BRL 6.8 2.0 BRL BRL BRL 0.49 J 1.82/18/2020 63 2.2 16 12 BRL BRL BRL 5.0 1.8 BRL BRL BRL BRL 0.93 J BRL BRL BRL BRL BRL BRL 1.2 BRL 11 1.2 BRL 0.92 47 12 0.42 J BRL BRL 4.8 5.99/12/2006 5.5 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 33.2 BRL BRL BRL BRL BRL 77/28/2009 50 27 110 149 BRL BRL BRL 2.6 1.2 BRL BRL BRL BRL 1.4 BRL BRL BRL BRL BRL BRL 3.2 BRL 9.7 0.88 BRL 1.1 20 17 1.9 BRL BRL 2.8 723/31/2010 88.7 14.6 86.1 45.3 BRL BRL BRL BRL BRL BRL BRL BRL BRL 1.4 BRL BRL BRL BRL BRL BRL 3.1 BRL 12.6 BRL BRL BRL 92.5 21.1 1 BRL BRL BRL 49.72/19/201310/17/2014 19.2 BRL BRL BRL BRL BRL BRL BRL 0.91 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 6.1 BRL BRL BRL 34.7 1.7 BRL BRL BRL BRL 5.35/14/2015 2.9 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 1.5 BRL BRL BRL 10.4 BRL BRL BRL BRL 0.71 BRL3/10/2016 BRL BRL BRL BRL BRL BRL BRL 0.57 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 4.2 BRL BRL BRL BRL BRL BRL6/14/2017 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 4.0 BRL BRL BRL BRL BRL BRL6/26/2018 2.7 BRL BRL 0.42 BRL 8.6 BRL 0.63 0.38 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 1.7 BRL BRL BRL 13 BRL BRL BRL BRL BRL 0.752/28/20197/16/20192/18/20209/12/2006 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL7/28/2009 BRL BRL BRL BRL BRL BRL BRL BRL BRL 2.4 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL3/31/2010 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL10/26/2011 BRL BRL BRL BRL BRL BRL BRL BRL BRL 3 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL2/19/2013 BRL BRL BRL BRL BRL BRL BRL BRL BRL 2.4 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 2.3 BRL BRL BRL BRL BRL BRL BRL10/17/2014 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL5/14/2015 BRL BRL BRL BRL BRL BRL BRL BRL BRL 2.6 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 6.9 BRL BRL BRL BRL BRL BRL BRL3/10/2016 BRL BRL BRL BRL BRL BRL BRL BRL BRL 3.6 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 13 BRL BRL BRL BRL BRL BRL BRL6/26/2018 BRL BRL BRL BRL BRL BRL BRL BRL BRL 3.8 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 26 BRL BRL BRL BRL BRL BRL BRL2/28/2019 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 0.20 J BRL BRL BRL BRL BRL BRL BRL7/16/2019 BRL BRL BRL BRL BRL BRL BRL BRL BRL 2.8 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 15 BRL BRL BRL BRL BRL BRL BRL2/18/2020 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL9/12/2006 5.5 BRL 2.7 13.1 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 4.8 BRL BRL BRL BRL 16.7 5.27/28/2009 3 BRL 1.4 6.64 BRL BRL BRL 0.95 J 0.69 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 1 0.77 BRL BRL 5.6 0.81 BRL BRL BRL 13 4.73/31/2010 1.3 BRL 0.5 6.64 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 1.9 BRL BRL BRL BRL BRL 2.8 1.310/26/2011 35 BRL 4.6 2.8 BRL BRL BRL BRL 1.1 BRL BRL BRL BRL 6.7 BRL BRL BRL BRL BRL BRL 7.9 BRL 2.5 BRL BRL 1.9 12.7 1.8 BRL BRL BRL 5.6 13.52/19/2013 1.2 BRL 0.18 BRL BRL BRL BRL BRL BRL BRL BRL BRL 0.31 BRL BRL BRL BRL BRL BRL BRL 0.22 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 0.18 0.3910/17/2014 21.2 BRL 3.8 12.6 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 6.6 6.1 BRL 1.8 BRL BRL 2.5 14.0 2.6 BRL BRL BRL 11.7 8.216006005006,000 40 NE 70 70 70 200 6 6 0.4 NE NE 0.6 100 0.02 70 70 40 70 25 100 20 6 70 100 0.7 3 400 4005,000 260,000 84,500 85,500 6,000,000 40,000 NE 6,900 8,500 70,000 61,500 6,000 6,000 400 NE NE 600 100,000 50 7,000 70,000 40,000 25,000 11,700 100,000 20,000 6,000 30,000 100,000 700 3,000 28,500 25,000
NOTES:NC2LGWQS = North Carolina 2L Groundwater Quality Standard as of April 1, 2013 GCL = NCDEQ's Gross Contamination Levels for Groundwater as of April 16, 2012Bold = Detected above the NC2LGWQS Underlined = Detected above both the NC2LGWQS and GCL
µg/L = Micrograms per LiterBRL = Below Reporting LimitJ = Estimated concentration above the adjusted method detection limit and below the adjusted reporting limitNE = Not Established
Analytical Method
Free ProductFree Product
Free Product
MW-1R
MW-2R
MW-4R
MW-5
Table 6
Summary of Historical Groundwater Analytical Results
Former Middleburg Grocery PropertyNW Corner of US Highway 1/NC Highway 158 and North Hawkins Avenue
Middleburg, Vance County, North Carolina
ECS Project No. 49:1638-E
Dry
MW-6
MW-7R
Standard Method 6200B (or equivalent)
Dry
GCL (µg/L)NC2LGWQS (µg/L)
NCDEQ Incident No. TF-6174
Free Product
Contaminant of Concern (µg/L)
DryDry
Sample ID Date
BenzeneTolueneEthylbenzeneTotal XylenesAcetone2-Butanone (MEK)Bromoethanen-Butylbenzenesec-ButylbenzeneChloroform1,3-Dichlorobenzene1,4-Dichlorobenzene1,1-Dichloroethane1,2-Dichloroethane1,1-Dichloropropylene1,1-Dichloroporpane1,2-Dichloropropoane1,3-Dichloropropane1,2-Dibromoethane (EDB)cis-1,2- DichloroetheneDiisopropyl ether (DIPE or IPE)2-HexanoneIsopropylbenzenep-IsopropyltolueneMethyl Isobutyl Ketone (MIBK)Methyl-tert-butyl ether (MBTE)Naphthalenen-PropylbenzeneStyreneTetrachloroetheneTrichloroethene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene3/31/2010 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL10/26/2011 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL2/19/2013 BRL 0.19 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 0.47 0.143/31/20102/19/201310/17/2014 357 129 148 882 BRL BRL BRL BRL BRL BRL BRL BRL BRL 32.1 BRL BRL BRL BRL 3.2 BRL 45.9 BRL 7.0 BRL BRL 27.6 157 19.9 BRL BRL BRL 258 75.35/14/2015 1,290 993 404 3,150 BRL BRL BRL BRL BRL BRL BRL BRL BRL 89.7 BRL BRL BRL BRL 16.8 BRL 124 BRL 20.0 BRL BRL 116 352 55.9 BRL BRL BRL 840 2213/10/2016 790 560 160 1,000 73 310 0.67J BRL BRL BRL BRL BRL BRL 98 0.69 BRL BRL BRL 24 BRL 110 BRL 4.6 BRL 110 230 150 9.6 BRL BRL BRL 110 416/14/2017 6.7 3.9 8.6 7.5 BRL BRL BRL BRL BRL BRL BRL BRL BRL 6.3 BRL BRL BRL BRL 3.0 BRL 17.2 BRL 0.74 BRL BRL 60.7 22.0 1.1 BRL BRL BRL 2.4 1.52/22/2019
2/28/2019 400 100 400 1,970 BRL BRL BRL 28 8.2 J BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 22 32 J 29 5.0 J BRL 39 340 100 4.4 J BRL BRL 1,000 2607/16/2019 580 140 480 2,260 BRL BRL BRL 47 6.8 J BRL BRL BRL BRL 12 BRL BRL BRL BRL BRL BRL 18 93 J 36 5.6 J BRL 17 350 110 BRL BRL 880 2702/18/2020
3/31/2010 3,780 10,300 2,060 10,960 BRL BRL BRL 122 BRL 60.8 57.5 55.7 63 292 BRL 50.6 51.7 207 BRL 56.2 368 BRL 135 BRL BRL 493 913 275 105 62.5 71 1,820 52110/26/2011 2,650 7,810 2,080 11,140 BRL BRL BRL BRL BRL BRL BRL BRL BRL 153 BRL BRL BRL BRL 52.1 BRL 187 BRL 73.2 BRL BRL 306 595 149 BRL BRL BRL 1,680 4462/19/2013 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL
10/17/2014 4,280 6,640 1,320 7,700 BRL BRL BRL BRL BRL BRL BRL BRL BRL 292 BRL BRL BRL BRL 95.8 BRL 350 BRL 35.5 BRL BRL 684 606 99.9 38.2 BRL BRL 1,160 2825/14/2015 3,390 5,820 1,230 7,360 BRL BRL BRL BRL BRL BRL BRL BRL BRL 135 BRL BRL BRL BRL 87.3 BRL 182 BRL 38.8 BRL BRL 366 698 105 35 BRL BRL 1,260 3323/10/2016 4,500 8,800 1,800 9,600 BRL BRL BRL 13 5.2 BRL BRL BRL BRL 110 BRL BRL BRL BRL 85 BRL 130 BRL 43 BRL 18 400 640 130 39 BRL BRL 1,500 3506/14/2017 3,100 5,110 687 4,590 BRL BRL BRL BRL BRL BRL BRL BRL BRL 63.6 BRL BRL BRL BRL BRL BRL 84.1 BRL BRL BRL BRL 366 265 BRL BRL BRL BRL 508 BRL6/26/2018 3,000 7,700 2,800 16,000 BRL BRL BRL 160 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 120 BRL 110 44J BRL 560 1,100 340 BRL BRL BRL 3,100 850
2/14/2019*2,100 3,500 1,400 7,900 BRL 150 J BRL 45 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 22 J BRL 150 BRL 42 BRL BRL 390 570 110 BRL BRL BRL 1,200 3602/28/2019**2,300 4,300 1,500 9,200 BRL BRL BRL 25 J BRL BRL BRL BRL BRL 110 BRL BRL BRL BRL BRL BRL 120 BRL 45 J BRL BRL 340 940 120 38 J BRL BRL 1,700 3907/16/2019 2,500 3,700 1,200 7,000 BRL BRL BRL 37 J BRL BRL BRL BRL BRL 130 BRL BRL BRL BRL BRL BRL 190 BRL 37 J BRL BRL 500 570 94 BRL BRL BRL 1,200 3402/18/2020 1,700 3,400 1,200 7,400 BRL BRL BRL 16 J BRL BRL BRL BRL BRL 120 BRL BRL BRL BRL BRL BRL 150 BRL 35 BRL BRL 290 500 86 24 J BRL BRL 1,000 330
3/31/2010 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL
10/26/2011 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL
2/19/2013 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 2.7 BRL BRL BRL BRL BRL BRL BRL 2.1 BRL 0.37 BRL BRL 10 3 BRL BRL BRL BRL BRL BRL
10/17/2014 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL5/14/2015 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL3/10/2016 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL6/26/2018 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL2/28/2019 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL
7/16/2019 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL2/18/2020 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL10/26/2011 40.4 0.96 BRL BRL BRL BRL BRL BRL BRL 2.3 BRL BRL BRL 5.1 BRL BRL BRL BRL BRL BRL 8.6 BRL 2.1 BRL BRL 26.2 7.5 BRL BRL BRL BRL BRL BRL2/19/2013 8.2 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL10/17/2014 BRL BRL BRL 2.2 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 0.53 BRL5/14/2015 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL
3/10/2016 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL10/26/2011 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL2/19/2013 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL10/17/2014 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL5/14/2015 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL10/26/2011 168 522 193 754 BRL BRL BRL BRL BRL BRL BRL BRL BRL 7 BRL BRL BRL BRL 2.5 BRL 8.2 BRL 7.9 BRL BRL 33.6 128 18.7 BRL BRL BRL 159 44.22/19/2013 1 0.11 0.5 1.09 BRL BRL BRL 0.23 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 1.7 BRL BRL BRL BRL 7.2 BRL BRL BRL BRL BRL 2.6 0.8510/17/2014 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 0.87 BRL BRL BRL BRL BRL BRL BRL5/14/2015 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 0.69 BRL BRL BRL BRL BRL BRL BRL3/10/2016 1.8 12 2.6 20 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 0.69J 4.4 0.64 BRL BRL BRL 7.0 2.06/14/2017 0.76 3.6 0.84 4.5 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 1.3 BRL6/26/2018 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL2/28/2019 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 0.26 J BRL BRL BRL BRL BRL BRL BRL7/16/2019 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL2/18/2020 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL
1 600 600 500 6,000 40 NE 70 70 70 200 6 6 0.4 NE NE 0.6 100 0.02 70 70 40 70 25 100 20 6 70 100 0.7 3 400 4005,000 260,000 84,500 85,500 6,000,000 40,000 NE 6,900 8,500 70,000 61,500 6,000 6,000 400 NE NE 600 100,000 50 7,000 70,000 40,000 25,000 11,700 100,000 20,000 6,000 30,000 100,000 700 3,000 28,500 25,000
NOTES:
NC2LGWQS = North Carolina 2L Groundwater Quality Standard as of April 1, 2013 GCL = NCDEQ's Gross Contamination Levels for Groundwater as of April 16, 2012Bold = Detected above the NC2LGWQS Underlined = Detected above both the NC2LGWQS and GCLµg/L = Micrograms per LiterBRL = Below Reporting LimitJ = Estimated concentration above the adjusted method detection limit and below the adjusted reporting limitNE = Not Established
Dry
MW-11R
Dry
Contaminant of Concern (µg/L)Analytical Method
Dry
MW-15
Well Abandoned
Standard Method 6200B (or equivalent)
Table 6 (continued)Summary of Historical Groundwater Analytical Results
Former Middleburg Grocery Property
MW-14
NC2LGWQS (µg/L)
ECS Project No. 49:1638-E
MW-12
MW-13
DW-1
GCL (µg/L)
MW-11
MW-10
Middleburg, Vance County, North Carolina
NCDEQ Incident No. TF-6174
NW Corner of US Highway 1/NC Highway 158 and North Hawkins Avenue
Sample ID Date Collected
BenzeneTolueneEthylbenzeneTotal XylenesBromodichloromethaneChloroform1,2-DichloroethaneDiisopropyl ether (DIPE or IPE)IsopropylbenzeneMethyl-tert-butyl ether (MTBE)Naphthalenen-Propylbenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene6/7/2004 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL
7/28/2009 BRL BRL BRL BRL NT BRL BRL BRL BRL BRL BRL BRL BRL BRL
6/26/2018 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL
3/1/2019 BRL BRL BRL BRL BRL 0.30 J BRL BRL BRL BRL BRL BRL BRL BRL7/16/2019 BRL BRL BRL BRL BRL 1.1 BRL BRL BRL BRL BRL BRL BRL BRL2/18/2020 BRL BRL BRL BRL BRL 0.38 J BRL BRL BRL BRL BRL BRL BRL BRL9/12/2006 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL
7/28/2009 BRL BRL BRL BRL NT BRL BRL BRL BRL BRL BRL BRL BRL BRL
6/26/2018 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL3/1/2019 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL7/16/2019 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL2/18/2020 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL
WSW-3 6/7/2004 BRL BRL BRL 1.7 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL
WSW-4 7/28/2009 BRL BRL BRL BRL NT BRL BRL BRL BRL BRL BRL BRL BRL BRL
6/7/2004 BRL 0.79 BRL 1.6 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL
9/12/2006 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL7/28/2009 BRL BRL BRL BRL NT BRL BRL BRL BRL BRL BRL BRL BRL BRL
6/7/2004 BRL 0.76 BRL BRL BRL BRL BRL BRL BRL 4.2 BRL BRL BRL BRL7/28/2009 BRL BRL BRL BRL NT BRL BRL BRL BRL BRL BRL BRL BRL BRL
WSW-7 6/7/2004 BRL 0.76 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL
6/7/2004 300 1.9 28 287.9 BRL BRL 38 24 5.1 160 50 5.6 27 9
9/12/2006 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL7/28/2009 BRL BRL BRL BRL NT BRL BRL BRL BRL BRL BRL BRL BRL BRL
6/7/2004 150 0.66 BRL 3 BRL BRL 12 7.5 3.7 23 4.1 BRL BRL BRL7/28/2009 BRL BRL BRL BRL NT BRL BRL BRL BRL BRL BRL BRL BRL BRL
6/7/2004 260 0.87 BRL 0.59 BRL BRL 28 18 4.2 45 BRL BRL BRL BRL9/12/2006 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL7/28/2009 BRL BRL BRL BRL NT BRL BRL BRL BRL BRL BRL BRL BRL BRL
10/17/2014 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL5/14/2015 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL
3/10/2016 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL
6/26/2018 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL3/1/2019 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL7/16/2019 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL2/18/2020 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL
WSW-18 6/7/2004 BRL BRL BRL BRL 22 55 BRL BRL BRL BRL BRL BRL BRL BRL
WSW-22 8/3/2004 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL
WSW-24 8/3/2004 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL
1 600 600 500 NE 70 0.4 70 70 200 6 70 400 400
5,000 260,000 84,500 85,500 NE 70,000 400 70,000 25,000 20,000 6,000 30,000 28,500 25,000
NOTES:
NC2LGWQS = North Carolina 2L Groundwater Quality Standard as of April 1, 2013
GCL = NCDEQ's Gross Contamination Levels for Groundwater as of April 16, 2012Bold = Detected above the NC2LGWQSµg/L = Micrograms per LiterNE = Not Established
BRL = Below Laboratory Reporting Limit
Analytical Method
WSW-1
WSW-5
WSW-6
WSW-8
Standard Method 6200B (or equivalent)
Contaminant of Concern (ug/L)
GCL (µg/L)
NC2LGWQS
WSW-10
WSW-11
WSW-13
WSW-2
NW Corner of US Highway 1/NC Highway 158 and North Hawkins Avenue
Middleburg, Vance County, North Carolina
Table 7
Summary of Historical Water Supply Well Groundwater Analytical Results
ECS Project No. 49:1638-E
Former Middleburg Grocery Property
NCDEQ Incident No. TF-6174

APPENDIX A
SITE PHOTOGRAPHS
FORMER MIDDLEBURG GROCERY PROPERTY
NW CORNER OF US HIGHWAY 1/NC HIGHWAY
MIDDLEBURG, VANCE COUNTY, NORTH CAROLINA
NCDEQ INCIDENT NO. TF-6174
ECS PROJECT NO. 49:1638-E
Photograph 1: View of the subject site. View is to the northwest.
Photograph 2: View of the monitoring wells MW-1R and DW-1. View is to the northwest.
SITE PHOTOGRAPHS
FORMER MIDDLEBURG GROCERY PROPERTY
NW CORNER OF US HIGHWAY 1/NC HIGHWAY
MIDDLEBURG, VANCE COUNTY, NORTH CAROLINA
NCDEQ INCIDENT NO. TF-6174
ECS PROJECT NO. 49:1638-E
Photograph 3: View of monitoring well MW-2R. View is to the northwest.
Photograph 4: View of the monitoring well MW-4R. View is to the northeast.
SITE PHOTOGRAPHS
FORMER MIDDLEBURG GROCERY PROPERTY
NW CORNER OF US HIGHWAY 1/NC HIGHWAY
MIDDLEBURG, VANCE COUNTY, NORTH CAROLINA
NCDEQ INCIDENT NO. TF-6174
ECS PROJECT NO. 49:1638-E
Photograph 5: View of monitoring well MW-5. View is to the northeast.
Photograph 6: View of the monitoring well MW-6. View is to the southwest.
SITE PHOTOGRAPHS
FORMER MIDDLEBURG GROCERY PROPERTY
NW CORNER OF US HIGHWAY 1/NC HIGHWAY
MIDDLEBURG, VANCE COUNTY, NORTH CAROLINA
NCDEQ INCIDENT NO. TF-6174
ECS PROJECT NO. 49:1638-E
Photograph 7: View of monitoring well MW-11. View is to the northeast.
Photograph 8: View of the monitoring well MW-12. View is to the northeast.
SITE PHOTOGRAPHS
FORMER MIDDLEBURG GROCERY PROPERTY
NW CORNER OF US HIGHWAY 1/NC HIGHWAY
MIDDLEBURG, VANCE COUNTY, NORTH CAROLINA
NCDEQ INCIDENT NO. TF-6174
ECS PROJECT NO. 49:1638-E
Photograph 9: View of the monitoring well MW-13. View is to the northeast.
Photograph 10: View of water supply well WSW-1. View is to the southeast.
SITE PHOTOGRAPHS
FORMER MIDDLEBURG GROCERY PROPERTY
NW CORNER OF US HIGHWAY 1/NC HIGHWAY
MIDDLEBURG, VANCE COUNTY, NORTH CAROLINA
NCDEQ INCIDENT NO. TF-6174
ECS PROJECT NO. 49:1638-E
Photograph 11: View of water supply well WSW-2. View is to the northeast.
Photograph 12: View of the residence associated with water supply well WSW-13. View is to the southwest.

APPENDIX B

APPENDIX C

39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
February 28, 2020
Matt Gillis
ECS Southeast - Raleigh, NC
9001 Glenwood Avenue
Raleigh, NC 27617
Project Location: Middleburg, Vance County, NC
Client Job Number:
Project Number: 49:1638-E
Laboratory Work Order Number: 20B0870
Enclosed are results of analyses for samples received by the laboratory on February 19, 2020. If you have any questions
concerning this report, please feel free to contact me.
Sincerely,
Kerry K. McGee
Project Manager
Page 1 of 45
Table of Contents
Table of Contents
Sample Summary 3
Hits Only Report 4
Case Narrative 7
Sample Results 8
20B0870-01 8
20B0870-02 10
20B0870-03 12
20B0870-04 14
20B0870-05 16
20B0870-06 18
20B0870-07 20
20B0870-08 22
20B0870-09 24
20B0870-10 26
20B0870-11 28
Sample Preparation Information 30
QC Data 31
Volatile Organic Compounds by GC/MS 31
B252791 31
B252860 35
Flag/Qualifier Summary 39
Certifications 40
Chain of Custody/Sample Receipt 42
Page 2 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL SUMMARY
2/28/2020
ECS Southeast - Raleigh, NC
9001 Glenwood Avenue
Raleigh, NC 27617
ATTN: Matt Gillis
49:1638-E
20B0870
The results of analyses performed on the following samples submitted to the CON-TEST Analytical Laboratory are found in this report.
PROJECT LOCATION:
PURCHASE ORDER NUMBER:
PROJECT NUMBER:
REPORT DATE:
WORK ORDER NUMBER:
FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB
Middleburg, Vance County, NC
field blank 20B0870-01 Field Blank SM21-22 6200B
MW-6 20B0870-02 Ground Water SM21-22 6200B
MW-4R 20B0870-03 Ground Water SM21-22 6200B
MW-2R 20B0870-04 Ground Water SM21-22 6200B
MW-13 20B0870-05 Ground Water SM21-22 6200B
MW-1R 20B0870-06 Ground Water SM21-22 6200B
MW-12 20B0870-07 Ground Water SM21-22 6200B
DW-1 20B0870-08 Ground Water SM21-22 6200B
WSW-1 20B0870-09 Ground Water SM21-22 6200B
WSW-2 20B0870-10 Ground Water SM21-22 6200B
WSW-13 20B0870-11 Ground Water SM21-22 6200B
[TOC_1]Sample Summary[TOC]
Page 3 of 45
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
[TOC_1]Hits Only Report[TOC]EXECUTIVE SUMMARY
Client ID:Lab ID:20B0870-01field blank
No Results Detected
Client ID:Lab ID:20B0870-02MW-6
No Results Detected
Client ID:Lab ID:20B0870-04MW-2R
No Results Detected
Client ID:Lab ID:20B0870-05MW-13
No Results Detected
Client ID:Lab ID:20B0870-08DW-1
No Results Detected
Client ID:Lab ID:20B0870-10WSW-2
No Results Detected
Client ID:Lab ID:20B0870-11WSW-13
No Results Detected
Con-Test does not accept liability for the consequences of any actions taken solely on the basis of the information provided in the Executive Summary
section of this report. Users must review this report in its entirety to determine data usability and assessment.
Page 4 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
EXECUTIVE SUMMARY
Client ID:Lab ID:
Analyte Results/Qual RL Units Method
20B0870-03MW-4R
DL
1,2,4-Trimethylbenzene 4.8 0.50 g/L SM21-22 6200B0.18
1,2-Dichloroethane 0.93 1.0 g/L SM21-22 6200BJ0.41
1,3,5-Trimethylbenzene 5.9 0.50 g/L SM21-22 6200B0.14
Benzene 63 0.50 g/L SM21-22 6200B0.18
Diisopropyl Ether (DIPE)1.2 0.50 g/L SM21-22 6200B0.17
Ethylbenzene 16 0.50 g/L SM21-22 6200B0.13
Isopropylbenzene (Cumene)11 0.50 g/L SM21-22 6200B0.17
m+p Xylene 11 1.0 g/L SM21-22 6200B0.30
Methyl tert-Butyl Ether (MTBE)0.92 0.50 g/L SM21-22 6200B0.25
Naphthalene 47 5.0 g/L SM21-22 6200B0.31
n-Butylbenzene 5.0 0.50 g/L SM21-22 6200B0.21
n-Propylbenzene 12 0.50 g/L SM21-22 6200B0.13
o-Xylene 1.0 0.50 g/L SM21-22 6200B0.17
p-Isopropyltoluene (p-Cymene)1.2 0.50 g/L SM21-22 6200B0.20
sec-Butylbenzene 1.8 0.50 g/L SM21-22 6200B0.16
Styrene 0.42 0.50 g/L SM21-22 6200BJ0.11
Toluene 2.2 0.50 g/L SM21-22 6200B0.14
Client ID:Lab ID:
Analyte Results/Qual RL Units Method
20B0870-06MW-1R
DL
1,2,4-Trimethylbenzene 460 20 g/L SM21-22 6200B7.2
1,2-Dibromoethane (EDB)38 20 g/L SM21-22 6200B7.6
1,3,5-Trimethylbenzene 220 20 g/L SM21-22 6200B5.6
Benzene 970 20 g/L SM21-22 6200B7.2
Diisopropyl Ether (DIPE)28 20 g/L SM21-22 6200B6.8
Ethylbenzene 230 20 g/L SM21-22 6200B5.2
Isopropylbenzene (Cumene)12 20 g/L SM21-22 6200BJ6.8
m+p Xylene 1700 40 g/L SM21-22 6200B12
Methyl tert-Butyl Ether (MTBE)34 20 g/L SM21-22 6200BL-04 10
Naphthalene 360 200 g/L SM21-22 6200B12
n-Butylbenzene 9.2 20 g/L SM21-22 6200BJ8.4
n-Propylbenzene 20 20 g/L SM21-22 6200B5.2
o-Xylene 950 20 g/L SM21-22 6200B6.8
Styrene 6.0 20 g/L SM21-22 6200BJ4.4
Toluene 2500 20 g/L SM21-22 6200B5.6
Page 5 of 45
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Client ID:Lab ID:
Analyte Results/Qual RL Units Method
20B0870-07MW-12
DL
1,2,4-Trimethylbenzene 1000 25 g/L SM21-22 6200B9.0
1,2-Dichloroethane 120 50 g/L SM21-22 6200B20
1,3,5-Trimethylbenzene 330 25 g/L SM21-22 6200B7.0
Benzene 1700 25 g/L SM21-22 6200B9.0
Diisopropyl Ether (DIPE)150 25 g/L SM21-22 6200B8.5
Ethylbenzene 1200 25 g/L SM21-22 6200B6.5
Isopropylbenzene (Cumene)35 25 g/L SM21-22 6200B8.5
m+p Xylene 5000 50 g/L SM21-22 6200B15
Methyl tert-Butyl Ether (MTBE)290 25 g/L SM21-22 6200B12
Naphthalene 500 250 g/L SM21-22 6200B16
n-Butylbenzene 16 25 g/L SM21-22 6200BJ10
n-Propylbenzene 86 25 g/L SM21-22 6200B6.5
o-Xylene 2400 25 g/L SM21-22 6200B8.5
Styrene 24 25 g/L SM21-22 6200BJ5.5
Toluene 3400 25 g/L SM21-22 6200B7.0
Client ID:Lab ID:
Analyte Results/Qual RL Units Method
20B0870-09WSW-1
DL
Chloroform 0.38 0.50 g/L SM21-22 6200BJ0.17
Con-Test does not accept liability for the consequences of any actions taken solely on the basis of the information provided in the Executive Summary
section of this report. Users must review this report in its entirety to determine data usability and assessment.
Page 6 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CASE NARRATIVE SUMMARY
All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report.
For method 6200B elevated reporting limit for samples 20B0870-06+07 due to high concentrations of target compounds.
[TOC_1]Case Narrative[TOC]
SM21-22 6200B
Qualifications:
Laboratory fortified blank/laboratory control sample recovery and duplicate recoveries outside of control limits. Data validation is not
affected since all results are "not detected" for associated samples in this batch and bias is on the high side.
Analyte & Samples(s) Qualified:
L-02
Vinyl Chloride
B252791-BS1, B252791-BSD1, B252860-BS1, B252860-BSD1
Laboratory fortified blank/laboratory control sample recovery and duplicate recovery are outside of control limits. Reported value for this
compound is likely to be biased on the low side.
Analyte & Samples(s) Qualified:
L-04
Methyl tert-Butyl Ether (MTBE)
20B0870-06[MW-1R], B252860-BLK1, B252860-BS1, B252860-BSD1
Either laboratory fortified blank/laboratory control sample or duplicate recovery is outside of control limits, but the other is within limits. RPD
between the two LFB/LCS results is within method specified criteria.Analyte & Samples(s) Qualified:
L-07
Ethanol
B252791-BS1
Elevated reporting limit due to high concentration of target compounds.
Analyte & Samples(s) Qualified:
RL-11
20B0870-06[MW-1R], 20B0870-07[MW-12]
The results of analyses reported only relate to samples submitted to the Con-Test Analytical Laboratory for testing.
I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed
in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the
best of my knowledge and belief, accurate and complete.
Lisa A. Worthington
Technical Representative
Page 7 of 45
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/19/2020
Work Order: 20B0870Sample Description:Project Location: Middleburg, Vance County, NC
Sample ID: 20B0870-01
Field Sample #: field blank
Sample Matrix: Field Blank
Sampled: 2/18/2020 11:17
[TOC_2]20B0870-01[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 2/22/20 20:43 EEHg/L3.8 2/21/20SM21-22 6200B1Acetone
ND 0.50 2/22/20 20:43 EEHg/L0.18 2/21/20SM21-22 6200B1Benzene
ND 0.50 2/22/20 20:43 EEHg/L0.15 2/21/20SM21-22 6200B1Bromobenzene
ND 0.50 2/22/20 20:43 EEHg/L0.32 2/21/20SM21-22 6200B1Bromochloromethane
ND 0.50 2/22/20 20:43 EEHg/L0.16 2/21/20SM21-22 6200B1Bromodichloromethane
ND 0.50 2/22/20 20:43 EEHg/L0.46 2/21/20SM21-22 6200B1Bromoform
ND 1.0 2/22/20 20:43 EEHg/L0.78 2/21/20SM21-22 6200B1Bromomethane
ND 5.0 2/22/20 20:43 EEHg/L1.9 2/21/20SM21-22 6200B12-Butanone (MEK)
ND 0.50 2/22/20 20:43 EEHg/L0.21 2/21/20SM21-22 6200B1n-Butylbenzene
ND 0.50 2/22/20 20:43 EEHg/L0.16 2/21/20SM21-22 6200B1sec-Butylbenzene
ND 0.50 2/22/20 20:43 EEHg/L0.17 2/21/20SM21-22 6200B1tert-Butylbenzene
ND 0.50 2/22/20 20:43 EEHg/L0.11 2/21/20SM21-22 6200B1Carbon Tetrachloride
ND 0.50 2/22/20 20:43 EEHg/L0.15 2/21/20SM21-22 6200B1Chlorobenzene
ND 50 2/22/20 20:43 EEHg/L11 2/21/20SM21-22 6200B1Ethanol
ND 0.50 2/22/20 20:43 EEHg/L0.21 2/21/20SM21-22 6200B1Chlorodibromomethane
ND 0.50 2/22/20 20:43 EEHg/L0.35 2/21/20SM21-22 6200B1Chloroethane
ND 0.50 2/22/20 20:43 EEHg/L0.17 2/21/20SM21-22 6200B1Chloroform
ND 1.0 2/22/20 20:43 EEHg/L0.45 2/21/20SM21-22 6200B1Chloromethane
ND 0.50 2/22/20 20:43 EEHg/L0.12 2/21/20SM21-22 6200B12-Chlorotoluene
ND 0.50 2/22/20 20:43 EEHg/L0.14 2/21/20SM21-22 6200B14-Chlorotoluene
ND 0.50 2/22/20 20:43 EEHg/L0.19 2/21/20SM21-22 6200B11,2-Dibromoethane (EDB)
ND 0.50 2/22/20 20:43 EEHg/L0.16 2/21/20SM21-22 6200B11,2-Dichlorobenzene
ND 0.50 2/22/20 20:43 EEHg/L0.12 2/21/20SM21-22 6200B11,3-Dichlorobenzene
ND 0.50 2/22/20 20:43 EEHg/L0.13 2/21/20SM21-22 6200B11,4-Dichlorobenzene
ND 0.50 2/22/20 20:43 EEHg/L0.26 2/21/20SM21-22 6200B1Dichlorodifluoromethane (Freon 12)
ND 0.50 2/22/20 20:43 EEHg/L0.16 2/21/20SM21-22 6200B11,1-Dichloroethane
ND 1.0 2/22/20 20:43 EEHg/L0.41 2/21/20SM21-22 6200B11,2-Dichloroethane
ND 0.50 2/22/20 20:43 EEHg/L0.32 2/21/20SM21-22 6200B11,1-Dichloroethylene
ND 0.50 2/22/20 20:43 EEHg/L0.13 2/21/20SM21-22 6200B1cis-1,2-Dichloroethylene
ND 0.50 2/22/20 20:43 EEHg/L0.31 2/21/20SM21-22 6200B1trans-1,2-Dichloroethylene
ND 0.50 2/22/20 20:43 EEHg/L0.20 2/21/20SM21-22 6200B11,2-Dichloropropane
ND 0.50 2/22/20 20:43 EEHg/L0.11 2/21/20SM21-22 6200B11,3-Dichloropropane
ND 0.50 2/22/20 20:43 EEHg/L0.20 2/21/20SM21-22 6200B12,2-Dichloropropane
ND 0.50 2/22/20 20:43 EEHg/L0.16 2/21/20SM21-22 6200B11,1-Dichloropropene
ND 0.50 2/22/20 20:43 EEHg/L0.13 2/21/20SM21-22 6200B1cis-1,3-Dichloropropene
ND 0.50 2/22/20 20:43 EEHg/L0.23 2/21/20SM21-22 6200B1trans-1,3-Dichloropropene
ND 0.50 2/22/20 20:43 EEHg/L0.17 2/21/20SM21-22 6200B1Diisopropyl Ether (DIPE)
ND 0.50 2/22/20 20:43 EEHg/L0.13 2/21/20SM21-22 6200B1Ethylbenzene
ND 5.0 2/22/20 20:43 EEHg/L1.5 2/21/20SM21-22 6200B12-Hexanone (MBK)
ND 0.50 2/22/20 20:43 EEHg/L0.17 2/21/20SM21-22 6200B1Isopropylbenzene (Cumene)
ND 0.50 2/22/20 20:43 EEHg/L0.20 2/21/20SM21-22 6200B1p-Isopropyltoluene (p-Cymene)
ND 0.50 2/22/20 20:43 EEHg/L0.25 2/21/20SM21-22 6200B1Methyl tert-Butyl Ether (MTBE)
ND 5.0 2/22/20 20:43 EEHg/L0.34 2/21/20SM21-22 6200B1Methylene Chloride
ND 5.0 2/22/20 20:43 EEHg/L1.7 2/21/20SM21-22 6200B14-Methyl-2-pentanone (MIBK)
[TOC_1]Sample Results[TOC]
Page 8 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/19/2020
Work Order: 20B0870Sample Description:Project Location: Middleburg, Vance County, NC
Sample ID: 20B0870-01
Field Sample #: field blank
Sample Matrix: Field Blank
Sampled: 2/18/2020 11:17
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 5.0 2/22/20 20:43 EEHg/L0.31 2/21/20SM21-22 6200B1Naphthalene
ND 0.50 2/22/20 20:43 EEHg/L0.13 2/21/20SM21-22 6200B1n-Propylbenzene
ND 0.50 2/22/20 20:43 EEHg/L0.11 2/21/20SM21-22 6200B1Styrene
ND 0.50 2/22/20 20:43 EEHg/L0.22 2/21/20SM21-22 6200B11,1,2,2-Tetrachloroethane
ND 0.50 2/22/20 20:43 EEHg/L0.18 2/21/20SM21-22 6200B1Tetrachloroethylene
ND 0.50 2/22/20 20:43 EEHg/L0.14 2/21/20SM21-22 6200B1Toluene
ND 2.0 2/22/20 20:43 EEHg/L0.57 2/21/20SM21-22 6200B11,2,3-Trichlorobenzene
ND 0.50 2/22/20 20:43 EEHg/L0.40 2/21/20SM21-22 6200B11,2,4-Trichlorobenzene
ND 0.50 2/22/20 20:43 EEHg/L0.20 2/21/20SM21-22 6200B11,1,1-Trichloroethane
ND 0.50 2/22/20 20:43 EEHg/L0.16 2/21/20SM21-22 6200B11,1,2-Trichloroethane
ND 0.50 2/22/20 20:43 EEHg/L0.24 2/21/20SM21-22 6200B1Trichloroethylene
ND 0.50 2/22/20 20:43 EEHg/L0.33 2/21/20SM21-22 6200B1Trichlorofluoromethane (Freon 11)
ND 0.50 2/22/20 20:43 EEHg/L0.25 2/21/20SM21-22 6200B11,2,3-Trichloropropane
ND 0.50 2/22/20 20:43 EEHg/L0.18 2/21/20SM21-22 6200B11,2,4-Trimethylbenzene
ND 0.50 2/22/20 20:43 EEHg/L0.14 2/21/20SM21-22 6200B11,3,5-Trimethylbenzene
ND 20 2/22/20 20:43 EEHg/L10 2/21/20SM21-22 6200B1Vinyl Acetate
ND 0.50 2/22/20 20:43 EEHg/L0.45 2/21/20SM21-22 6200B1Vinyl Chloride
ND 1.0 2/22/20 20:43 EEHg/L0.30 2/21/20SM21-22 6200B1m+p Xylene
ND 0.50 2/22/20 20:43 EEHg/L0.17 2/21/20SM21-22 6200B1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 89.4 2/22/20 20:4370-130
Toluene-d8 99.6 2/22/20 20:4370-130
4-Bromofluorobenzene 93.6 2/22/20 20:4370-130
Page 9 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/19/2020
Work Order: 20B0870Sample Description:Project Location: Middleburg, Vance County, NC
Sample ID: 20B0870-02
Field Sample #: MW-6
Sample Matrix: Ground Water
Sampled: 2/18/2020 11:38
[TOC_2]20B0870-02[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 2/23/20 0:35 EEHg/L3.8 2/21/20SM21-22 6200B1Acetone
ND 0.50 2/23/20 0:35 EEHg/L0.18 2/21/20SM21-22 6200B1Benzene
ND 0.50 2/23/20 0:35 EEHg/L0.15 2/21/20SM21-22 6200B1Bromobenzene
ND 0.50 2/23/20 0:35 EEHg/L0.32 2/21/20SM21-22 6200B1Bromochloromethane
ND 0.50 2/23/20 0:35 EEHg/L0.16 2/21/20SM21-22 6200B1Bromodichloromethane
ND 0.50 2/23/20 0:35 EEHg/L0.46 2/21/20SM21-22 6200B1Bromoform
ND 1.0 2/23/20 0:35 EEHg/L0.78 2/21/20SM21-22 6200B1Bromomethane
ND 5.0 2/23/20 0:35 EEHg/L1.9 2/21/20SM21-22 6200B12-Butanone (MEK)
ND 0.50 2/23/20 0:35 EEHg/L0.21 2/21/20SM21-22 6200B1n-Butylbenzene
ND 0.50 2/23/20 0:35 EEHg/L0.16 2/21/20SM21-22 6200B1sec-Butylbenzene
ND 0.50 2/23/20 0:35 EEHg/L0.17 2/21/20SM21-22 6200B1tert-Butylbenzene
ND 0.50 2/23/20 0:35 EEHg/L0.11 2/21/20SM21-22 6200B1Carbon Tetrachloride
ND 0.50 2/23/20 0:35 EEHg/L0.15 2/21/20SM21-22 6200B1Chlorobenzene
ND 50 2/23/20 0:35 EEHg/L11 2/21/20SM21-22 6200B1Ethanol
ND 0.50 2/23/20 0:35 EEHg/L0.21 2/21/20SM21-22 6200B1Chlorodibromomethane
ND 0.50 2/23/20 0:35 EEHg/L0.35 2/21/20SM21-22 6200B1Chloroethane
ND 0.50 2/23/20 0:35 EEHg/L0.17 2/21/20SM21-22 6200B1Chloroform
ND 1.0 2/23/20 0:35 EEHg/L0.45 2/21/20SM21-22 6200B1Chloromethane
ND 0.50 2/23/20 0:35 EEHg/L0.12 2/21/20SM21-22 6200B12-Chlorotoluene
ND 0.50 2/23/20 0:35 EEHg/L0.14 2/21/20SM21-22 6200B14-Chlorotoluene
ND 0.50 2/23/20 0:35 EEHg/L0.19 2/21/20SM21-22 6200B11,2-Dibromoethane (EDB)
ND 0.50 2/23/20 0:35 EEHg/L0.16 2/21/20SM21-22 6200B11,2-Dichlorobenzene
ND 0.50 2/23/20 0:35 EEHg/L0.12 2/21/20SM21-22 6200B11,3-Dichlorobenzene
ND 0.50 2/23/20 0:35 EEHg/L0.13 2/21/20SM21-22 6200B11,4-Dichlorobenzene
ND 0.50 2/23/20 0:35 EEHg/L0.26 2/21/20SM21-22 6200B1Dichlorodifluoromethane (Freon 12)
ND 0.50 2/23/20 0:35 EEHg/L0.16 2/21/20SM21-22 6200B11,1-Dichloroethane
ND 1.0 2/23/20 0:35 EEHg/L0.41 2/21/20SM21-22 6200B11,2-Dichloroethane
ND 0.50 2/23/20 0:35 EEHg/L0.32 2/21/20SM21-22 6200B11,1-Dichloroethylene
ND 0.50 2/23/20 0:35 EEHg/L0.13 2/21/20SM21-22 6200B1cis-1,2-Dichloroethylene
ND 0.50 2/23/20 0:35 EEHg/L0.31 2/21/20SM21-22 6200B1trans-1,2-Dichloroethylene
ND 0.50 2/23/20 0:35 EEHg/L0.20 2/21/20SM21-22 6200B11,2-Dichloropropane
ND 0.50 2/23/20 0:35 EEHg/L0.11 2/21/20SM21-22 6200B11,3-Dichloropropane
ND 0.50 2/23/20 0:35 EEHg/L0.20 2/21/20SM21-22 6200B12,2-Dichloropropane
ND 0.50 2/23/20 0:35 EEHg/L0.16 2/21/20SM21-22 6200B11,1-Dichloropropene
ND 0.50 2/23/20 0:35 EEHg/L0.13 2/21/20SM21-22 6200B1cis-1,3-Dichloropropene
ND 0.50 2/23/20 0:35 EEHg/L0.23 2/21/20SM21-22 6200B1trans-1,3-Dichloropropene
ND 0.50 2/23/20 0:35 EEHg/L0.17 2/21/20SM21-22 6200B1Diisopropyl Ether (DIPE)
ND 0.50 2/23/20 0:35 EEHg/L0.13 2/21/20SM21-22 6200B1Ethylbenzene
ND 5.0 2/23/20 0:35 EEHg/L1.5 2/21/20SM21-22 6200B12-Hexanone (MBK)
ND 0.50 2/23/20 0:35 EEHg/L0.17 2/21/20SM21-22 6200B1Isopropylbenzene (Cumene)
ND 0.50 2/23/20 0:35 EEHg/L0.20 2/21/20SM21-22 6200B1p-Isopropyltoluene (p-Cymene)
ND 0.50 2/23/20 0:35 EEHg/L0.25 2/21/20SM21-22 6200B1Methyl tert-Butyl Ether (MTBE)
ND 5.0 2/23/20 0:35 EEHg/L0.34 2/21/20SM21-22 6200B1Methylene Chloride
ND 5.0 2/23/20 0:35 EEHg/L1.7 2/21/20SM21-22 6200B14-Methyl-2-pentanone (MIBK)
Page 10 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/19/2020
Work Order: 20B0870Sample Description:Project Location: Middleburg, Vance County, NC
Sample ID: 20B0870-02
Field Sample #: MW-6
Sample Matrix: Ground Water
Sampled: 2/18/2020 11:38
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 5.0 2/23/20 0:35 EEHg/L0.31 2/21/20SM21-22 6200B1Naphthalene
ND 0.50 2/23/20 0:35 EEHg/L0.13 2/21/20SM21-22 6200B1n-Propylbenzene
ND 0.50 2/23/20 0:35 EEHg/L0.11 2/21/20SM21-22 6200B1Styrene
ND 0.50 2/23/20 0:35 EEHg/L0.22 2/21/20SM21-22 6200B11,1,2,2-Tetrachloroethane
ND 0.50 2/23/20 0:35 EEHg/L0.18 2/21/20SM21-22 6200B1Tetrachloroethylene
ND 0.50 2/23/20 0:35 EEHg/L0.14 2/21/20SM21-22 6200B1Toluene
ND 2.0 2/23/20 0:35 EEHg/L0.57 2/21/20SM21-22 6200B11,2,3-Trichlorobenzene
ND 0.50 2/23/20 0:35 EEHg/L0.40 2/21/20SM21-22 6200B11,2,4-Trichlorobenzene
ND 0.50 2/23/20 0:35 EEHg/L0.20 2/21/20SM21-22 6200B11,1,1-Trichloroethane
ND 0.50 2/23/20 0:35 EEHg/L0.16 2/21/20SM21-22 6200B11,1,2-Trichloroethane
ND 0.50 2/23/20 0:35 EEHg/L0.24 2/21/20SM21-22 6200B1Trichloroethylene
ND 0.50 2/23/20 0:35 EEHg/L0.33 2/21/20SM21-22 6200B1Trichlorofluoromethane (Freon 11)
ND 0.50 2/23/20 0:35 EEHg/L0.25 2/21/20SM21-22 6200B11,2,3-Trichloropropane
ND 0.50 2/23/20 0:35 EEHg/L0.18 2/21/20SM21-22 6200B11,2,4-Trimethylbenzene
ND 0.50 2/23/20 0:35 EEHg/L0.14 2/21/20SM21-22 6200B11,3,5-Trimethylbenzene
ND 20 2/23/20 0:35 EEHg/L10 2/21/20SM21-22 6200B1Vinyl Acetate
ND 0.50 2/23/20 0:35 EEHg/L0.45 2/21/20SM21-22 6200B1Vinyl Chloride
ND 1.0 2/23/20 0:35 EEHg/L0.30 2/21/20SM21-22 6200B1m+p Xylene
ND 0.50 2/23/20 0:35 EEHg/L0.17 2/21/20SM21-22 6200B1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 89.8 2/23/20 0:3570-130
Toluene-d8 97.5 2/23/20 0:3570-130
4-Bromofluorobenzene 94.4 2/23/20 0:3570-130
Page 11 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/19/2020
Work Order: 20B0870Sample Description:Project Location: Middleburg, Vance County, NC
Sample ID: 20B0870-03
Field Sample #: MW-4R
Sample Matrix: Ground Water
Sampled: 2/18/2020 11:56
[TOC_2]20B0870-03[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 2/23/20 3:28 EEHg/L3.8 2/21/20SM21-22 6200B1Acetone
63 0.50 2/23/20 3:28 EEHg/L0.18 2/21/20SM21-22 6200B1Benzene
ND 0.50 2/23/20 3:28 EEHg/L0.15 2/21/20SM21-22 6200B1Bromobenzene
ND 0.50 2/23/20 3:28 EEHg/L0.32 2/21/20SM21-22 6200B1Bromochloromethane
ND 0.50 2/23/20 3:28 EEHg/L0.16 2/21/20SM21-22 6200B1Bromodichloromethane
ND 0.50 2/23/20 3:28 EEHg/L0.46 2/21/20SM21-22 6200B1Bromoform
ND 1.0 2/23/20 3:28 EEHg/L0.78 2/21/20SM21-22 6200B1Bromomethane
ND 5.0 2/23/20 3:28 EEHg/L1.9 2/21/20SM21-22 6200B12-Butanone (MEK)
5.0 0.50 2/23/20 3:28 EEHg/L0.21 2/21/20SM21-22 6200B1n-Butylbenzene
1.8 0.50 2/23/20 3:28 EEHg/L0.16 2/21/20SM21-22 6200B1sec-Butylbenzene
ND 0.50 2/23/20 3:28 EEHg/L0.17 2/21/20SM21-22 6200B1tert-Butylbenzene
ND 0.50 2/23/20 3:28 EEHg/L0.11 2/21/20SM21-22 6200B1Carbon Tetrachloride
ND 0.50 2/23/20 3:28 EEHg/L0.15 2/21/20SM21-22 6200B1Chlorobenzene
ND 50 2/23/20 3:28 EEHg/L11 2/21/20SM21-22 6200B1Ethanol
ND 0.50 2/23/20 3:28 EEHg/L0.21 2/21/20SM21-22 6200B1Chlorodibromomethane
ND 0.50 2/23/20 3:28 EEHg/L0.35 2/21/20SM21-22 6200B1Chloroethane
ND 0.50 2/23/20 3:28 EEHg/L0.17 2/21/20SM21-22 6200B1Chloroform
ND 1.0 2/23/20 3:28 EEHg/L0.45 2/21/20SM21-22 6200B1Chloromethane
ND 0.50 2/23/20 3:28 EEHg/L0.12 2/21/20SM21-22 6200B12-Chlorotoluene
ND 0.50 2/23/20 3:28 EEHg/L0.14 2/21/20SM21-22 6200B14-Chlorotoluene
ND 0.50 2/23/20 3:28 EEHg/L0.19 2/21/20SM21-22 6200B11,2-Dibromoethane (EDB)
ND 0.50 2/23/20 3:28 EEHg/L0.16 2/21/20SM21-22 6200B11,2-Dichlorobenzene
ND 0.50 2/23/20 3:28 EEHg/L0.12 2/21/20SM21-22 6200B11,3-Dichlorobenzene
ND 0.50 2/23/20 3:28 EEHg/L0.13 2/21/20SM21-22 6200B11,4-Dichlorobenzene
ND 0.50 2/23/20 3:28 EEHg/L0.26 2/21/20SM21-22 6200B1Dichlorodifluoromethane (Freon 12)
ND 0.50 2/23/20 3:28 EEHg/L0.16 2/21/20SM21-22 6200B11,1-Dichloroethane
0.93 1.0 2/23/20 3:28 EEHg/L0.41 2/21/20SM21-22 6200B1J1,2-Dichloroethane
ND 0.50 2/23/20 3:28 EEHg/L0.32 2/21/20SM21-22 6200B11,1-Dichloroethylene
ND 0.50 2/23/20 3:28 EEHg/L0.13 2/21/20SM21-22 6200B1cis-1,2-Dichloroethylene
ND 0.50 2/23/20 3:28 EEHg/L0.31 2/21/20SM21-22 6200B1trans-1,2-Dichloroethylene
ND 0.50 2/23/20 3:28 EEHg/L0.20 2/21/20SM21-22 6200B11,2-Dichloropropane
ND 0.50 2/23/20 3:28 EEHg/L0.11 2/21/20SM21-22 6200B11,3-Dichloropropane
ND 0.50 2/23/20 3:28 EEHg/L0.20 2/21/20SM21-22 6200B12,2-Dichloropropane
ND 0.50 2/23/20 3:28 EEHg/L0.16 2/21/20SM21-22 6200B11,1-Dichloropropene
ND 0.50 2/23/20 3:28 EEHg/L0.13 2/21/20SM21-22 6200B1cis-1,3-Dichloropropene
ND 0.50 2/23/20 3:28 EEHg/L0.23 2/21/20SM21-22 6200B1trans-1,3-Dichloropropene
1.2 0.50 2/23/20 3:28 EEHg/L0.17 2/21/20SM21-22 6200B1Diisopropyl Ether (DIPE)
16 0.50 2/23/20 3:28 EEHg/L0.13 2/21/20SM21-22 6200B1Ethylbenzene
ND 5.0 2/23/20 3:28 EEHg/L1.5 2/21/20SM21-22 6200B12-Hexanone (MBK)
11 0.50 2/23/20 3:28 EEHg/L0.17 2/21/20SM21-22 6200B1Isopropylbenzene (Cumene)
1.2 0.50 2/23/20 3:28 EEHg/L0.20 2/21/20SM21-22 6200B1p-Isopropyltoluene (p-Cymene)
0.92 0.50 2/23/20 3:28 EEHg/L0.25 2/21/20SM21-22 6200B1Methyl tert-Butyl Ether (MTBE)
ND 5.0 2/23/20 3:28 EEHg/L0.34 2/21/20SM21-22 6200B1Methylene Chloride
ND 5.0 2/23/20 3:28 EEHg/L1.7 2/21/20SM21-22 6200B14-Methyl-2-pentanone (MIBK)
Page 12 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/19/2020
Work Order: 20B0870Sample Description:Project Location: Middleburg, Vance County, NC
Sample ID: 20B0870-03
Field Sample #: MW-4R
Sample Matrix: Ground Water
Sampled: 2/18/2020 11:56
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
47 5.0 2/23/20 3:28 EEHg/L0.31 2/21/20SM21-22 6200B1Naphthalene
12 0.50 2/23/20 3:28 EEHg/L0.13 2/21/20SM21-22 6200B1n-Propylbenzene
0.42 0.50 2/23/20 3:28 EEHg/L0.11 2/21/20SM21-22 6200B1JStyrene
ND 0.50 2/23/20 3:28 EEHg/L0.22 2/21/20SM21-22 6200B11,1,2,2-Tetrachloroethane
ND 0.50 2/23/20 3:28 EEHg/L0.18 2/21/20SM21-22 6200B1Tetrachloroethylene
2.2 0.50 2/23/20 3:28 EEHg/L0.14 2/21/20SM21-22 6200B1Toluene
ND 2.0 2/23/20 3:28 EEHg/L0.57 2/21/20SM21-22 6200B11,2,3-Trichlorobenzene
ND 0.50 2/23/20 3:28 EEHg/L0.40 2/21/20SM21-22 6200B11,2,4-Trichlorobenzene
ND 0.50 2/23/20 3:28 EEHg/L0.20 2/21/20SM21-22 6200B11,1,1-Trichloroethane
ND 0.50 2/23/20 3:28 EEHg/L0.16 2/21/20SM21-22 6200B11,1,2-Trichloroethane
ND 0.50 2/23/20 3:28 EEHg/L0.24 2/21/20SM21-22 6200B1Trichloroethylene
ND 0.50 2/23/20 3:28 EEHg/L0.33 2/21/20SM21-22 6200B1Trichlorofluoromethane (Freon 11)
ND 0.50 2/23/20 3:28 EEHg/L0.25 2/21/20SM21-22 6200B11,2,3-Trichloropropane
4.8 0.50 2/23/20 3:28 EEHg/L0.18 2/21/20SM21-22 6200B11,2,4-Trimethylbenzene
5.9 0.50 2/23/20 3:28 EEHg/L0.14 2/21/20SM21-22 6200B11,3,5-Trimethylbenzene
ND 20 2/23/20 3:28 EEHg/L10 2/21/20SM21-22 6200B1Vinyl Acetate
ND 0.50 2/23/20 3:28 EEHg/L0.45 2/21/20SM21-22 6200B1Vinyl Chloride
11 1.0 2/23/20 3:28 EEHg/L0.30 2/21/20SM21-22 6200B1m+p Xylene
1.0 0.50 2/23/20 3:28 EEHg/L0.17 2/21/20SM21-22 6200B1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 88.5 2/23/20 3:2870-130
Toluene-d8 98.3 2/23/20 3:2870-130
4-Bromofluorobenzene 101 2/23/20 3:2870-130
Page 13 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/19/2020
Work Order: 20B0870Sample Description:Project Location: Middleburg, Vance County, NC
Sample ID: 20B0870-04
Field Sample #: MW-2R
Sample Matrix: Ground Water
Sampled: 2/18/2020 12:16
[TOC_2]20B0870-04[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 2/23/20 1:32 EEHg/L3.8 2/21/20SM21-22 6200B1Acetone
ND 0.50 2/23/20 1:32 EEHg/L0.18 2/21/20SM21-22 6200B1Benzene
ND 0.50 2/23/20 1:32 EEHg/L0.15 2/21/20SM21-22 6200B1Bromobenzene
ND 0.50 2/23/20 1:32 EEHg/L0.32 2/21/20SM21-22 6200B1Bromochloromethane
ND 0.50 2/23/20 1:32 EEHg/L0.16 2/21/20SM21-22 6200B1Bromodichloromethane
ND 0.50 2/23/20 1:32 EEHg/L0.46 2/21/20SM21-22 6200B1Bromoform
ND 1.0 2/23/20 1:32 EEHg/L0.78 2/21/20SM21-22 6200B1Bromomethane
ND 5.0 2/23/20 1:32 EEHg/L1.9 2/21/20SM21-22 6200B12-Butanone (MEK)
ND 0.50 2/23/20 1:32 EEHg/L0.21 2/21/20SM21-22 6200B1n-Butylbenzene
ND 0.50 2/23/20 1:32 EEHg/L0.16 2/21/20SM21-22 6200B1sec-Butylbenzene
ND 0.50 2/23/20 1:32 EEHg/L0.17 2/21/20SM21-22 6200B1tert-Butylbenzene
ND 0.50 2/23/20 1:32 EEHg/L0.11 2/21/20SM21-22 6200B1Carbon Tetrachloride
ND 0.50 2/23/20 1:32 EEHg/L0.15 2/21/20SM21-22 6200B1Chlorobenzene
ND 50 2/23/20 1:32 EEHg/L11 2/21/20SM21-22 6200B1Ethanol
ND 0.50 2/23/20 1:32 EEHg/L0.21 2/21/20SM21-22 6200B1Chlorodibromomethane
ND 0.50 2/23/20 1:32 EEHg/L0.35 2/21/20SM21-22 6200B1Chloroethane
ND 0.50 2/23/20 1:32 EEHg/L0.17 2/21/20SM21-22 6200B1Chloroform
ND 1.0 2/23/20 1:32 EEHg/L0.45 2/21/20SM21-22 6200B1Chloromethane
ND 0.50 2/23/20 1:32 EEHg/L0.12 2/21/20SM21-22 6200B12-Chlorotoluene
ND 0.50 2/23/20 1:32 EEHg/L0.14 2/21/20SM21-22 6200B14-Chlorotoluene
ND 0.50 2/23/20 1:32 EEHg/L0.19 2/21/20SM21-22 6200B11,2-Dibromoethane (EDB)
ND 0.50 2/23/20 1:32 EEHg/L0.16 2/21/20SM21-22 6200B11,2-Dichlorobenzene
ND 0.50 2/23/20 1:32 EEHg/L0.12 2/21/20SM21-22 6200B11,3-Dichlorobenzene
ND 0.50 2/23/20 1:32 EEHg/L0.13 2/21/20SM21-22 6200B11,4-Dichlorobenzene
ND 0.50 2/23/20 1:32 EEHg/L0.26 2/21/20SM21-22 6200B1Dichlorodifluoromethane (Freon 12)
ND 0.50 2/23/20 1:32 EEHg/L0.16 2/21/20SM21-22 6200B11,1-Dichloroethane
ND 1.0 2/23/20 1:32 EEHg/L0.41 2/21/20SM21-22 6200B11,2-Dichloroethane
ND 0.50 2/23/20 1:32 EEHg/L0.32 2/21/20SM21-22 6200B11,1-Dichloroethylene
ND 0.50 2/23/20 1:32 EEHg/L0.13 2/21/20SM21-22 6200B1cis-1,2-Dichloroethylene
ND 0.50 2/23/20 1:32 EEHg/L0.31 2/21/20SM21-22 6200B1trans-1,2-Dichloroethylene
ND 0.50 2/23/20 1:32 EEHg/L0.20 2/21/20SM21-22 6200B11,2-Dichloropropane
ND 0.50 2/23/20 1:32 EEHg/L0.11 2/21/20SM21-22 6200B11,3-Dichloropropane
ND 0.50 2/23/20 1:32 EEHg/L0.20 2/21/20SM21-22 6200B12,2-Dichloropropane
ND 0.50 2/23/20 1:32 EEHg/L0.16 2/21/20SM21-22 6200B11,1-Dichloropropene
ND 0.50 2/23/20 1:32 EEHg/L0.13 2/21/20SM21-22 6200B1cis-1,3-Dichloropropene
ND 0.50 2/23/20 1:32 EEHg/L0.23 2/21/20SM21-22 6200B1trans-1,3-Dichloropropene
ND 0.50 2/23/20 1:32 EEHg/L0.17 2/21/20SM21-22 6200B1Diisopropyl Ether (DIPE)
ND 0.50 2/23/20 1:32 EEHg/L0.13 2/21/20SM21-22 6200B1Ethylbenzene
ND 5.0 2/23/20 1:32 EEHg/L1.5 2/21/20SM21-22 6200B12-Hexanone (MBK)
ND 0.50 2/23/20 1:32 EEHg/L0.17 2/21/20SM21-22 6200B1Isopropylbenzene (Cumene)
ND 0.50 2/23/20 1:32 EEHg/L0.20 2/21/20SM21-22 6200B1p-Isopropyltoluene (p-Cymene)
ND 0.50 2/23/20 1:32 EEHg/L0.25 2/21/20SM21-22 6200B1Methyl tert-Butyl Ether (MTBE)
ND 5.0 2/23/20 1:32 EEHg/L0.34 2/21/20SM21-22 6200B1Methylene Chloride
ND 5.0 2/23/20 1:32 EEHg/L1.7 2/21/20SM21-22 6200B14-Methyl-2-pentanone (MIBK)
Page 14 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/19/2020
Work Order: 20B0870Sample Description:Project Location: Middleburg, Vance County, NC
Sample ID: 20B0870-04
Field Sample #: MW-2R
Sample Matrix: Ground Water
Sampled: 2/18/2020 12:16
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 5.0 2/23/20 1:32 EEHg/L0.31 2/21/20SM21-22 6200B1Naphthalene
ND 0.50 2/23/20 1:32 EEHg/L0.13 2/21/20SM21-22 6200B1n-Propylbenzene
ND 0.50 2/23/20 1:32 EEHg/L0.11 2/21/20SM21-22 6200B1Styrene
ND 0.50 2/23/20 1:32 EEHg/L0.22 2/21/20SM21-22 6200B11,1,2,2-Tetrachloroethane
ND 0.50 2/23/20 1:32 EEHg/L0.18 2/21/20SM21-22 6200B1Tetrachloroethylene
ND 0.50 2/23/20 1:32 EEHg/L0.14 2/21/20SM21-22 6200B1Toluene
ND 2.0 2/23/20 1:32 EEHg/L0.57 2/21/20SM21-22 6200B11,2,3-Trichlorobenzene
ND 0.50 2/23/20 1:32 EEHg/L0.40 2/21/20SM21-22 6200B11,2,4-Trichlorobenzene
ND 0.50 2/23/20 1:32 EEHg/L0.20 2/21/20SM21-22 6200B11,1,1-Trichloroethane
ND 0.50 2/23/20 1:32 EEHg/L0.16 2/21/20SM21-22 6200B11,1,2-Trichloroethane
ND 0.50 2/23/20 1:32 EEHg/L0.24 2/21/20SM21-22 6200B1Trichloroethylene
ND 0.50 2/23/20 1:32 EEHg/L0.33 2/21/20SM21-22 6200B1Trichlorofluoromethane (Freon 11)
ND 0.50 2/23/20 1:32 EEHg/L0.25 2/21/20SM21-22 6200B11,2,3-Trichloropropane
ND 0.50 2/23/20 1:32 EEHg/L0.18 2/21/20SM21-22 6200B11,2,4-Trimethylbenzene
ND 0.50 2/23/20 1:32 EEHg/L0.14 2/21/20SM21-22 6200B11,3,5-Trimethylbenzene
ND 20 2/23/20 1:32 EEHg/L10 2/21/20SM21-22 6200B1Vinyl Acetate
ND 0.50 2/23/20 1:32 EEHg/L0.45 2/21/20SM21-22 6200B1Vinyl Chloride
ND 1.0 2/23/20 1:32 EEHg/L0.30 2/21/20SM21-22 6200B1m+p Xylene
ND 0.50 2/23/20 1:32 EEHg/L0.17 2/21/20SM21-22 6200B1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 89.7 2/23/20 1:3270-130
Toluene-d8 96.6 2/23/20 1:3270-130
4-Bromofluorobenzene 92.4 2/23/20 1:3270-130
Page 15 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/19/2020
Work Order: 20B0870Sample Description:Project Location: Middleburg, Vance County, NC
Sample ID: 20B0870-05
Field Sample #: MW-13
Sample Matrix: Ground Water
Sampled: 2/18/2020 12:30
[TOC_2]20B0870-05[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 2/23/20 2:01 EEHg/L3.8 2/21/20SM21-22 6200B1Acetone
ND 0.50 2/23/20 2:01 EEHg/L0.18 2/21/20SM21-22 6200B1Benzene
ND 0.50 2/23/20 2:01 EEHg/L0.15 2/21/20SM21-22 6200B1Bromobenzene
ND 0.50 2/23/20 2:01 EEHg/L0.32 2/21/20SM21-22 6200B1Bromochloromethane
ND 0.50 2/23/20 2:01 EEHg/L0.16 2/21/20SM21-22 6200B1Bromodichloromethane
ND 0.50 2/23/20 2:01 EEHg/L0.46 2/21/20SM21-22 6200B1Bromoform
ND 1.0 2/23/20 2:01 EEHg/L0.78 2/21/20SM21-22 6200B1Bromomethane
ND 5.0 2/23/20 2:01 EEHg/L1.9 2/21/20SM21-22 6200B12-Butanone (MEK)
ND 0.50 2/23/20 2:01 EEHg/L0.21 2/21/20SM21-22 6200B1n-Butylbenzene
ND 0.50 2/23/20 2:01 EEHg/L0.16 2/21/20SM21-22 6200B1sec-Butylbenzene
ND 0.50 2/23/20 2:01 EEHg/L0.17 2/21/20SM21-22 6200B1tert-Butylbenzene
ND 0.50 2/23/20 2:01 EEHg/L0.11 2/21/20SM21-22 6200B1Carbon Tetrachloride
ND 0.50 2/23/20 2:01 EEHg/L0.15 2/21/20SM21-22 6200B1Chlorobenzene
ND 50 2/23/20 2:01 EEHg/L11 2/21/20SM21-22 6200B1Ethanol
ND 0.50 2/23/20 2:01 EEHg/L0.21 2/21/20SM21-22 6200B1Chlorodibromomethane
ND 0.50 2/23/20 2:01 EEHg/L0.35 2/21/20SM21-22 6200B1Chloroethane
ND 0.50 2/23/20 2:01 EEHg/L0.17 2/21/20SM21-22 6200B1Chloroform
ND 1.0 2/23/20 2:01 EEHg/L0.45 2/21/20SM21-22 6200B1Chloromethane
ND 0.50 2/23/20 2:01 EEHg/L0.12 2/21/20SM21-22 6200B12-Chlorotoluene
ND 0.50 2/23/20 2:01 EEHg/L0.14 2/21/20SM21-22 6200B14-Chlorotoluene
ND 0.50 2/23/20 2:01 EEHg/L0.19 2/21/20SM21-22 6200B11,2-Dibromoethane (EDB)
ND 0.50 2/23/20 2:01 EEHg/L0.16 2/21/20SM21-22 6200B11,2-Dichlorobenzene
ND 0.50 2/23/20 2:01 EEHg/L0.12 2/21/20SM21-22 6200B11,3-Dichlorobenzene
ND 0.50 2/23/20 2:01 EEHg/L0.13 2/21/20SM21-22 6200B11,4-Dichlorobenzene
ND 0.50 2/23/20 2:01 EEHg/L0.26 2/21/20SM21-22 6200B1Dichlorodifluoromethane (Freon 12)
ND 0.50 2/23/20 2:01 EEHg/L0.16 2/21/20SM21-22 6200B11,1-Dichloroethane
ND 1.0 2/23/20 2:01 EEHg/L0.41 2/21/20SM21-22 6200B11,2-Dichloroethane
ND 0.50 2/23/20 2:01 EEHg/L0.32 2/21/20SM21-22 6200B11,1-Dichloroethylene
ND 0.50 2/23/20 2:01 EEHg/L0.13 2/21/20SM21-22 6200B1cis-1,2-Dichloroethylene
ND 0.50 2/23/20 2:01 EEHg/L0.31 2/21/20SM21-22 6200B1trans-1,2-Dichloroethylene
ND 0.50 2/23/20 2:01 EEHg/L0.20 2/21/20SM21-22 6200B11,2-Dichloropropane
ND 0.50 2/23/20 2:01 EEHg/L0.11 2/21/20SM21-22 6200B11,3-Dichloropropane
ND 0.50 2/23/20 2:01 EEHg/L0.20 2/21/20SM21-22 6200B12,2-Dichloropropane
ND 0.50 2/23/20 2:01 EEHg/L0.16 2/21/20SM21-22 6200B11,1-Dichloropropene
ND 0.50 2/23/20 2:01 EEHg/L0.13 2/21/20SM21-22 6200B1cis-1,3-Dichloropropene
ND 0.50 2/23/20 2:01 EEHg/L0.23 2/21/20SM21-22 6200B1trans-1,3-Dichloropropene
ND 0.50 2/23/20 2:01 EEHg/L0.17 2/21/20SM21-22 6200B1Diisopropyl Ether (DIPE)
ND 0.50 2/23/20 2:01 EEHg/L0.13 2/21/20SM21-22 6200B1Ethylbenzene
ND 5.0 2/23/20 2:01 EEHg/L1.5 2/21/20SM21-22 6200B12-Hexanone (MBK)
ND 0.50 2/23/20 2:01 EEHg/L0.17 2/21/20SM21-22 6200B1Isopropylbenzene (Cumene)
ND 0.50 2/23/20 2:01 EEHg/L0.20 2/21/20SM21-22 6200B1p-Isopropyltoluene (p-Cymene)
ND 0.50 2/23/20 2:01 EEHg/L0.25 2/21/20SM21-22 6200B1Methyl tert-Butyl Ether (MTBE)
ND 5.0 2/23/20 2:01 EEHg/L0.34 2/21/20SM21-22 6200B1Methylene Chloride
ND 5.0 2/23/20 2:01 EEHg/L1.7 2/21/20SM21-22 6200B14-Methyl-2-pentanone (MIBK)
Page 16 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/19/2020
Work Order: 20B0870Sample Description:Project Location: Middleburg, Vance County, NC
Sample ID: 20B0870-05
Field Sample #: MW-13
Sample Matrix: Ground Water
Sampled: 2/18/2020 12:30
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 5.0 2/23/20 2:01 EEHg/L0.31 2/21/20SM21-22 6200B1Naphthalene
ND 0.50 2/23/20 2:01 EEHg/L0.13 2/21/20SM21-22 6200B1n-Propylbenzene
ND 0.50 2/23/20 2:01 EEHg/L0.11 2/21/20SM21-22 6200B1Styrene
ND 0.50 2/23/20 2:01 EEHg/L0.22 2/21/20SM21-22 6200B11,1,2,2-Tetrachloroethane
ND 0.50 2/23/20 2:01 EEHg/L0.18 2/21/20SM21-22 6200B1Tetrachloroethylene
ND 0.50 2/23/20 2:01 EEHg/L0.14 2/21/20SM21-22 6200B1Toluene
ND 2.0 2/23/20 2:01 EEHg/L0.57 2/21/20SM21-22 6200B11,2,3-Trichlorobenzene
ND 0.50 2/23/20 2:01 EEHg/L0.40 2/21/20SM21-22 6200B11,2,4-Trichlorobenzene
ND 0.50 2/23/20 2:01 EEHg/L0.20 2/21/20SM21-22 6200B11,1,1-Trichloroethane
ND 0.50 2/23/20 2:01 EEHg/L0.16 2/21/20SM21-22 6200B11,1,2-Trichloroethane
ND 0.50 2/23/20 2:01 EEHg/L0.24 2/21/20SM21-22 6200B1Trichloroethylene
ND 0.50 2/23/20 2:01 EEHg/L0.33 2/21/20SM21-22 6200B1Trichlorofluoromethane (Freon 11)
ND 0.50 2/23/20 2:01 EEHg/L0.25 2/21/20SM21-22 6200B11,2,3-Trichloropropane
ND 0.50 2/23/20 2:01 EEHg/L0.18 2/21/20SM21-22 6200B11,2,4-Trimethylbenzene
ND 0.50 2/23/20 2:01 EEHg/L0.14 2/21/20SM21-22 6200B11,3,5-Trimethylbenzene
ND 20 2/23/20 2:01 EEHg/L10 2/21/20SM21-22 6200B1Vinyl Acetate
ND 0.50 2/23/20 2:01 EEHg/L0.45 2/21/20SM21-22 6200B1Vinyl Chloride
ND 1.0 2/23/20 2:01 EEHg/L0.30 2/21/20SM21-22 6200B1m+p Xylene
ND 0.50 2/23/20 2:01 EEHg/L0.17 2/21/20SM21-22 6200B1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 88.6 2/23/20 2:0170-130
Toluene-d8 97.8 2/23/20 2:0170-130
4-Bromofluorobenzene 93.8 2/23/20 2:0170-130
Page 17 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/19/2020
Work Order: 20B0870Sample Description:Project Location: Middleburg, Vance County, NC
Sample ID: 20B0870-06
Field Sample #: MW-1R
Sample Matrix: Ground Water
Sampled: 2/18/2020 12:52
[TOC_2]20B0870-06[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Sample Flags: RL-11 Volatile Organic Compounds by GC/MS
ND 2000 2/25/20 8:49 EEHg/L150 2/24/20SM21-22 6200B40Acetone
970 20 2/25/20 8:49 EEHg/L7.2 2/24/20SM21-22 6200B40Benzene
ND 20 2/25/20 8:49 EEHg/L6.0 2/24/20SM21-22 6200B40Bromobenzene
ND 20 2/25/20 8:49 EEHg/L13 2/24/20SM21-22 6200B40Bromochloromethane
ND 20 2/25/20 8:49 EEHg/L6.4 2/24/20SM21-22 6200B40Bromodichloromethane
ND 20 2/25/20 8:49 EEHg/L18 2/24/20SM21-22 6200B40Bromoform
ND 40 2/25/20 8:49 EEHg/L31 2/24/20SM21-22 6200B40Bromomethane
ND 200 2/25/20 8:49 EEHg/L78 2/24/20SM21-22 6200B402-Butanone (MEK)
9.2 20 2/25/20 8:49 EEHg/L8.4 2/24/20SM21-22 6200B40Jn-Butylbenzene
ND 20 2/25/20 8:49 EEHg/L6.4 2/24/20SM21-22 6200B40sec-Butylbenzene
ND 20 2/25/20 8:49 EEHg/L6.8 2/24/20SM21-22 6200B40tert-Butylbenzene
ND 20 2/25/20 8:49 EEHg/L4.4 2/24/20SM21-22 6200B40Carbon Tetrachloride
ND 20 2/25/20 8:49 EEHg/L6.0 2/24/20SM21-22 6200B40Chlorobenzene
ND 2000 2/25/20 8:49 EEHg/L420 2/24/20SM21-22 6200B40Ethanol
ND 20 2/25/20 8:49 EEHg/L8.4 2/24/20SM21-22 6200B40Chlorodibromomethane
ND 20 2/25/20 8:49 EEHg/L14 2/24/20SM21-22 6200B40Chloroethane
ND 20 2/25/20 8:49 EEHg/L6.8 2/24/20SM21-22 6200B40Chloroform
ND 40 2/25/20 8:49 EEHg/L18 2/24/20SM21-22 6200B40Chloromethane
ND 20 2/25/20 8:49 EEHg/L4.8 2/24/20SM21-22 6200B402-Chlorotoluene
ND 20 2/25/20 8:49 EEHg/L5.6 2/24/20SM21-22 6200B404-Chlorotoluene
38 20 2/25/20 8:49 EEHg/L7.6 2/24/20SM21-22 6200B401,2-Dibromoethane (EDB)
ND 20 2/25/20 8:49 EEHg/L6.4 2/24/20SM21-22 6200B401,2-Dichlorobenzene
ND 20 2/25/20 8:49 EEHg/L4.8 2/24/20SM21-22 6200B401,3-Dichlorobenzene
ND 20 2/25/20 8:49 EEHg/L5.2 2/24/20SM21-22 6200B401,4-Dichlorobenzene
ND 20 2/25/20 8:49 EEHg/L10 2/24/20SM21-22 6200B40Dichlorodifluoromethane (Freon 12)
ND 20 2/25/20 8:49 EEHg/L6.4 2/24/20SM21-22 6200B401,1-Dichloroethane
ND 40 2/25/20 8:49 EEHg/L16 2/24/20SM21-22 6200B401,2-Dichloroethane
ND 20 2/25/20 8:49 EEHg/L13 2/24/20SM21-22 6200B401,1-Dichloroethylene
ND 20 2/25/20 8:49 EEHg/L5.2 2/24/20SM21-22 6200B40cis-1,2-Dichloroethylene
ND 20 2/25/20 8:49 EEHg/L12 2/24/20SM21-22 6200B40trans-1,2-Dichloroethylene
ND 20 2/25/20 8:49 EEHg/L8.0 2/24/20SM21-22 6200B401,2-Dichloropropane
ND 20 2/25/20 8:49 EEHg/L4.4 2/24/20SM21-22 6200B401,3-Dichloropropane
ND 20 2/25/20 8:49 EEHg/L8.0 2/24/20SM21-22 6200B402,2-Dichloropropane
ND 20 2/25/20 8:49 EEHg/L6.4 2/24/20SM21-22 6200B401,1-Dichloropropene
ND 20 2/25/20 8:49 EEHg/L5.2 2/24/20SM21-22 6200B40cis-1,3-Dichloropropene
ND 20 2/25/20 8:49 EEHg/L9.2 2/24/20SM21-22 6200B40trans-1,3-Dichloropropene
28 20 2/25/20 8:49 EEHg/L6.8 2/24/20SM21-22 6200B40Diisopropyl Ether (DIPE)
230 20 2/25/20 8:49 EEHg/L5.2 2/24/20SM21-22 6200B40Ethylbenzene
ND 200 2/25/20 8:49 EEHg/L61 2/24/20SM21-22 6200B402-Hexanone (MBK)
12 20 2/25/20 8:49 EEHg/L6.8 2/24/20SM21-22 6200B40JIsopropylbenzene (Cumene)
ND 20 2/25/20 8:49 EEHg/L8.0 2/24/20SM21-22 6200B40p-Isopropyltoluene (p-Cymene)
34 20 2/25/20 8:49 EEHg/L10 2/24/20SM21-22 6200B40L-04Methyl tert-Butyl Ether (MTBE)
ND 200 2/25/20 8:49 EEHg/L14 2/24/20SM21-22 6200B40Methylene Chloride
ND 200 2/25/20 8:49 EEHg/L67 2/24/20SM21-22 6200B404-Methyl-2-pentanone (MIBK)
Page 18 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/19/2020
Work Order: 20B0870Sample Description:Project Location: Middleburg, Vance County, NC
Sample ID: 20B0870-06
Field Sample #: MW-1R
Sample Matrix: Ground Water
Sampled: 2/18/2020 12:52
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Sample Flags: RL-11 Volatile Organic Compounds by GC/MS
360 200 2/25/20 8:49 EEHg/L12 2/24/20SM21-22 6200B40Naphthalene
20 20 2/25/20 8:49 EEHg/L5.2 2/24/20SM21-22 6200B40n-Propylbenzene
6.0 20 2/25/20 8:49 EEHg/L4.4 2/24/20SM21-22 6200B40JStyrene
ND 20 2/25/20 8:49 EEHg/L8.8 2/24/20SM21-22 6200B401,1,2,2-Tetrachloroethane
ND 20 2/25/20 8:49 EEHg/L7.2 2/24/20SM21-22 6200B40Tetrachloroethylene
2500 20 2/25/20 8:49 EEHg/L5.6 2/24/20SM21-22 6200B40Toluene
ND 80 2/25/20 8:49 EEHg/L23 2/24/20SM21-22 6200B401,2,3-Trichlorobenzene
ND 20 2/25/20 8:49 EEHg/L16 2/24/20SM21-22 6200B401,2,4-Trichlorobenzene
ND 20 2/25/20 8:49 EEHg/L8.0 2/24/20SM21-22 6200B401,1,1-Trichloroethane
ND 20 2/25/20 8:49 EEHg/L6.4 2/24/20SM21-22 6200B401,1,2-Trichloroethane
ND 20 2/25/20 8:49 EEHg/L9.6 2/24/20SM21-22 6200B40Trichloroethylene
ND 20 2/25/20 8:49 EEHg/L13 2/24/20SM21-22 6200B40Trichlorofluoromethane (Freon 11)
ND 20 2/25/20 8:49 EEHg/L10 2/24/20SM21-22 6200B401,2,3-Trichloropropane
460 20 2/25/20 8:49 EEHg/L7.2 2/24/20SM21-22 6200B401,2,4-Trimethylbenzene
220 20 2/25/20 8:49 EEHg/L5.6 2/24/20SM21-22 6200B401,3,5-Trimethylbenzene
ND 800 2/25/20 8:49 EEHg/L410 2/24/20SM21-22 6200B40Vinyl Acetate
ND 20 2/25/20 8:49 EEHg/L18 2/24/20SM21-22 6200B40Vinyl Chloride
1700 40 2/25/20 8:49 EEHg/L12 2/24/20SM21-22 6200B40m+p Xylene
950 20 2/25/20 8:49 EEHg/L6.8 2/24/20SM21-22 6200B40o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 88.5 2/25/20 8:4970-130
Toluene-d8 98.5 2/25/20 8:4970-130
4-Bromofluorobenzene 97.4 2/25/20 8:4970-130
Page 19 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/19/2020
Work Order: 20B0870Sample Description:Project Location: Middleburg, Vance County, NC
Sample ID: 20B0870-07
Field Sample #: MW-12
Sample Matrix: Ground Water
Sampled: 2/18/2020 13:00
[TOC_2]20B0870-07[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Sample Flags: RL-11 Volatile Organic Compounds by GC/MS
ND 2500 2/23/20 4:55 EEHg/L190 2/21/20SM21-22 6200B50Acetone
1700 25 2/23/20 4:55 EEHg/L9.0 2/21/20SM21-22 6200B50Benzene
ND 25 2/23/20 4:55 EEHg/L7.5 2/21/20SM21-22 6200B50Bromobenzene
ND 25 2/23/20 4:55 EEHg/L16 2/21/20SM21-22 6200B50Bromochloromethane
ND 25 2/23/20 4:55 EEHg/L8.0 2/21/20SM21-22 6200B50Bromodichloromethane
ND 25 2/23/20 4:55 EEHg/L23 2/21/20SM21-22 6200B50Bromoform
ND 50 2/23/20 4:55 EEHg/L39 2/21/20SM21-22 6200B50Bromomethane
ND 250 2/23/20 4:55 EEHg/L97 2/21/20SM21-22 6200B502-Butanone (MEK)
16 25 2/23/20 4:55 EEHg/L10 2/21/20SM21-22 6200B50Jn-Butylbenzene
ND 25 2/23/20 4:55 EEHg/L8.0 2/21/20SM21-22 6200B50sec-Butylbenzene
ND 25 2/23/20 4:55 EEHg/L8.5 2/21/20SM21-22 6200B50tert-Butylbenzene
ND 25 2/23/20 4:55 EEHg/L5.5 2/21/20SM21-22 6200B50Carbon Tetrachloride
ND 25 2/23/20 4:55 EEHg/L7.5 2/21/20SM21-22 6200B50Chlorobenzene
ND 2500 2/23/20 4:55 EEHg/L530 2/21/20SM21-22 6200B50Ethanol
ND 25 2/23/20 4:55 EEHg/L10 2/21/20SM21-22 6200B50Chlorodibromomethane
ND 25 2/23/20 4:55 EEHg/L18 2/21/20SM21-22 6200B50Chloroethane
ND 25 2/23/20 4:55 EEHg/L8.5 2/21/20SM21-22 6200B50Chloroform
ND 50 2/23/20 4:55 EEHg/L22 2/21/20SM21-22 6200B50Chloromethane
ND 25 2/23/20 4:55 EEHg/L6.0 2/21/20SM21-22 6200B502-Chlorotoluene
ND 25 2/23/20 4:55 EEHg/L7.0 2/21/20SM21-22 6200B504-Chlorotoluene
ND 25 2/23/20 4:55 EEHg/L9.5 2/21/20SM21-22 6200B501,2-Dibromoethane (EDB)
ND 25 2/23/20 4:55 EEHg/L8.0 2/21/20SM21-22 6200B501,2-Dichlorobenzene
ND 25 2/23/20 4:55 EEHg/L6.0 2/21/20SM21-22 6200B501,3-Dichlorobenzene
ND 25 2/23/20 4:55 EEHg/L6.5 2/21/20SM21-22 6200B501,4-Dichlorobenzene
ND 25 2/23/20 4:55 EEHg/L13 2/21/20SM21-22 6200B50Dichlorodifluoromethane (Freon 12)
ND 25 2/23/20 4:55 EEHg/L8.0 2/21/20SM21-22 6200B501,1-Dichloroethane
120 50 2/23/20 4:55 EEHg/L20 2/21/20SM21-22 6200B501,2-Dichloroethane
ND 25 2/23/20 4:55 EEHg/L16 2/21/20SM21-22 6200B501,1-Dichloroethylene
ND 25 2/23/20 4:55 EEHg/L6.5 2/21/20SM21-22 6200B50cis-1,2-Dichloroethylene
ND 25 2/23/20 4:55 EEHg/L16 2/21/20SM21-22 6200B50trans-1,2-Dichloroethylene
ND 25 2/23/20 4:55 EEHg/L10 2/21/20SM21-22 6200B501,2-Dichloropropane
ND 25 2/23/20 4:55 EEHg/L5.5 2/21/20SM21-22 6200B501,3-Dichloropropane
ND 25 2/23/20 4:55 EEHg/L10 2/21/20SM21-22 6200B502,2-Dichloropropane
ND 25 2/23/20 4:55 EEHg/L8.0 2/21/20SM21-22 6200B501,1-Dichloropropene
ND 25 2/23/20 4:55 EEHg/L6.5 2/21/20SM21-22 6200B50cis-1,3-Dichloropropene
ND 25 2/23/20 4:55 EEHg/L12 2/21/20SM21-22 6200B50trans-1,3-Dichloropropene
150 25 2/23/20 4:55 EEHg/L8.5 2/21/20SM21-22 6200B50Diisopropyl Ether (DIPE)
1200 25 2/23/20 4:55 EEHg/L6.5 2/21/20SM21-22 6200B50Ethylbenzene
ND 250 2/23/20 4:55 EEHg/L76 2/21/20SM21-22 6200B502-Hexanone (MBK)
35 25 2/23/20 4:55 EEHg/L8.5 2/21/20SM21-22 6200B50Isopropylbenzene (Cumene)
ND 25 2/23/20 4:55 EEHg/L10 2/21/20SM21-22 6200B50p-Isopropyltoluene (p-Cymene)
290 25 2/23/20 4:55 EEHg/L12 2/21/20SM21-22 6200B50Methyl tert-Butyl Ether (MTBE)
ND 250 2/23/20 4:55 EEHg/L17 2/21/20SM21-22 6200B50Methylene Chloride
ND 250 2/23/20 4:55 EEHg/L84 2/21/20SM21-22 6200B504-Methyl-2-pentanone (MIBK)
Page 20 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/19/2020
Work Order: 20B0870Sample Description:Project Location: Middleburg, Vance County, NC
Sample ID: 20B0870-07
Field Sample #: MW-12
Sample Matrix: Ground Water
Sampled: 2/18/2020 13:00
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Sample Flags: RL-11 Volatile Organic Compounds by GC/MS
500 250 2/23/20 4:55 EEHg/L16 2/21/20SM21-22 6200B50Naphthalene
86 25 2/23/20 4:55 EEHg/L6.5 2/21/20SM21-22 6200B50n-Propylbenzene
24 25 2/23/20 4:55 EEHg/L5.5 2/21/20SM21-22 6200B50JStyrene
ND 25 2/23/20 4:55 EEHg/L11 2/21/20SM21-22 6200B501,1,2,2-Tetrachloroethane
ND 25 2/23/20 4:55 EEHg/L9.0 2/21/20SM21-22 6200B50Tetrachloroethylene
3400 25 2/23/20 4:55 EEHg/L7.0 2/21/20SM21-22 6200B50Toluene
ND 100 2/23/20 4:55 EEHg/L28 2/21/20SM21-22 6200B501,2,3-Trichlorobenzene
ND 25 2/23/20 4:55 EEHg/L20 2/21/20SM21-22 6200B501,2,4-Trichlorobenzene
ND 25 2/23/20 4:55 EEHg/L10 2/21/20SM21-22 6200B501,1,1-Trichloroethane
ND 25 2/23/20 4:55 EEHg/L8.0 2/21/20SM21-22 6200B501,1,2-Trichloroethane
ND 25 2/23/20 4:55 EEHg/L12 2/21/20SM21-22 6200B50Trichloroethylene
ND 25 2/23/20 4:55 EEHg/L16 2/21/20SM21-22 6200B50Trichlorofluoromethane (Freon 11)
ND 25 2/23/20 4:55 EEHg/L12 2/21/20SM21-22 6200B501,2,3-Trichloropropane
1000 25 2/23/20 4:55 EEHg/L9.0 2/21/20SM21-22 6200B501,2,4-Trimethylbenzene
330 25 2/23/20 4:55 EEHg/L7.0 2/21/20SM21-22 6200B501,3,5-Trimethylbenzene
ND 1000 2/23/20 4:55 EEHg/L510 2/21/20SM21-22 6200B50Vinyl Acetate
ND 25 2/23/20 4:55 EEHg/L22 2/21/20SM21-22 6200B50Vinyl Chloride
5000 50 2/23/20 4:55 EEHg/L15 2/21/20SM21-22 6200B50m+p Xylene
2400 25 2/23/20 4:55 EEHg/L8.5 2/21/20SM21-22 6200B50o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 91.1 2/23/20 4:5570-130
Toluene-d8 97.7 2/23/20 4:5570-130
4-Bromofluorobenzene 96.8 2/23/20 4:5570-130
Page 21 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/19/2020
Work Order: 20B0870Sample Description:Project Location: Middleburg, Vance County, NC
Sample ID: 20B0870-08
Field Sample #: DW-1
Sample Matrix: Ground Water
Sampled: 2/18/2020 13:28
[TOC_2]20B0870-08[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 2/23/20 1:04 EEHg/L3.8 2/21/20SM21-22 6200B1Acetone
ND 0.50 2/23/20 1:04 EEHg/L0.18 2/21/20SM21-22 6200B1Benzene
ND 0.50 2/23/20 1:04 EEHg/L0.15 2/21/20SM21-22 6200B1Bromobenzene
ND 0.50 2/23/20 1:04 EEHg/L0.32 2/21/20SM21-22 6200B1Bromochloromethane
ND 0.50 2/23/20 1:04 EEHg/L0.16 2/21/20SM21-22 6200B1Bromodichloromethane
ND 0.50 2/23/20 1:04 EEHg/L0.46 2/21/20SM21-22 6200B1Bromoform
ND 1.0 2/23/20 1:04 EEHg/L0.78 2/21/20SM21-22 6200B1Bromomethane
ND 5.0 2/23/20 1:04 EEHg/L1.9 2/21/20SM21-22 6200B12-Butanone (MEK)
ND 0.50 2/23/20 1:04 EEHg/L0.21 2/21/20SM21-22 6200B1n-Butylbenzene
ND 0.50 2/23/20 1:04 EEHg/L0.16 2/21/20SM21-22 6200B1sec-Butylbenzene
ND 0.50 2/23/20 1:04 EEHg/L0.17 2/21/20SM21-22 6200B1tert-Butylbenzene
ND 0.50 2/23/20 1:04 EEHg/L0.11 2/21/20SM21-22 6200B1Carbon Tetrachloride
ND 0.50 2/23/20 1:04 EEHg/L0.15 2/21/20SM21-22 6200B1Chlorobenzene
ND 50 2/23/20 1:04 EEHg/L11 2/21/20SM21-22 6200B1Ethanol
ND 0.50 2/23/20 1:04 EEHg/L0.21 2/21/20SM21-22 6200B1Chlorodibromomethane
ND 0.50 2/23/20 1:04 EEHg/L0.35 2/21/20SM21-22 6200B1Chloroethane
ND 0.50 2/23/20 1:04 EEHg/L0.17 2/21/20SM21-22 6200B1Chloroform
ND 1.0 2/23/20 1:04 EEHg/L0.45 2/21/20SM21-22 6200B1Chloromethane
ND 0.50 2/23/20 1:04 EEHg/L0.12 2/21/20SM21-22 6200B12-Chlorotoluene
ND 0.50 2/23/20 1:04 EEHg/L0.14 2/21/20SM21-22 6200B14-Chlorotoluene
ND 0.50 2/23/20 1:04 EEHg/L0.19 2/21/20SM21-22 6200B11,2-Dibromoethane (EDB)
ND 0.50 2/23/20 1:04 EEHg/L0.16 2/21/20SM21-22 6200B11,2-Dichlorobenzene
ND 0.50 2/23/20 1:04 EEHg/L0.12 2/21/20SM21-22 6200B11,3-Dichlorobenzene
ND 0.50 2/23/20 1:04 EEHg/L0.13 2/21/20SM21-22 6200B11,4-Dichlorobenzene
ND 0.50 2/23/20 1:04 EEHg/L0.26 2/21/20SM21-22 6200B1Dichlorodifluoromethane (Freon 12)
ND 0.50 2/23/20 1:04 EEHg/L0.16 2/21/20SM21-22 6200B11,1-Dichloroethane
ND 1.0 2/23/20 1:04 EEHg/L0.41 2/21/20SM21-22 6200B11,2-Dichloroethane
ND 0.50 2/23/20 1:04 EEHg/L0.32 2/21/20SM21-22 6200B11,1-Dichloroethylene
ND 0.50 2/23/20 1:04 EEHg/L0.13 2/21/20SM21-22 6200B1cis-1,2-Dichloroethylene
ND 0.50 2/23/20 1:04 EEHg/L0.31 2/21/20SM21-22 6200B1trans-1,2-Dichloroethylene
ND 0.50 2/23/20 1:04 EEHg/L0.20 2/21/20SM21-22 6200B11,2-Dichloropropane
ND 0.50 2/23/20 1:04 EEHg/L0.11 2/21/20SM21-22 6200B11,3-Dichloropropane
ND 0.50 2/23/20 1:04 EEHg/L0.20 2/21/20SM21-22 6200B12,2-Dichloropropane
ND 0.50 2/23/20 1:04 EEHg/L0.16 2/21/20SM21-22 6200B11,1-Dichloropropene
ND 0.50 2/23/20 1:04 EEHg/L0.13 2/21/20SM21-22 6200B1cis-1,3-Dichloropropene
ND 0.50 2/23/20 1:04 EEHg/L0.23 2/21/20SM21-22 6200B1trans-1,3-Dichloropropene
ND 0.50 2/23/20 1:04 EEHg/L0.17 2/21/20SM21-22 6200B1Diisopropyl Ether (DIPE)
ND 0.50 2/23/20 1:04 EEHg/L0.13 2/21/20SM21-22 6200B1Ethylbenzene
ND 5.0 2/23/20 1:04 EEHg/L1.5 2/21/20SM21-22 6200B12-Hexanone (MBK)
ND 0.50 2/23/20 1:04 EEHg/L0.17 2/21/20SM21-22 6200B1Isopropylbenzene (Cumene)
ND 0.50 2/23/20 1:04 EEHg/L0.20 2/21/20SM21-22 6200B1p-Isopropyltoluene (p-Cymene)
ND 0.50 2/23/20 1:04 EEHg/L0.25 2/21/20SM21-22 6200B1Methyl tert-Butyl Ether (MTBE)
ND 5.0 2/23/20 1:04 EEHg/L0.34 2/21/20SM21-22 6200B1Methylene Chloride
ND 5.0 2/23/20 1:04 EEHg/L1.7 2/21/20SM21-22 6200B14-Methyl-2-pentanone (MIBK)
Page 22 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/19/2020
Work Order: 20B0870Sample Description:Project Location: Middleburg, Vance County, NC
Sample ID: 20B0870-08
Field Sample #: DW-1
Sample Matrix: Ground Water
Sampled: 2/18/2020 13:28
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 5.0 2/23/20 1:04 EEHg/L0.31 2/21/20SM21-22 6200B1Naphthalene
ND 0.50 2/23/20 1:04 EEHg/L0.13 2/21/20SM21-22 6200B1n-Propylbenzene
ND 0.50 2/23/20 1:04 EEHg/L0.11 2/21/20SM21-22 6200B1Styrene
ND 0.50 2/23/20 1:04 EEHg/L0.22 2/21/20SM21-22 6200B11,1,2,2-Tetrachloroethane
ND 0.50 2/23/20 1:04 EEHg/L0.18 2/21/20SM21-22 6200B1Tetrachloroethylene
ND 0.50 2/23/20 1:04 EEHg/L0.14 2/21/20SM21-22 6200B1Toluene
ND 2.0 2/23/20 1:04 EEHg/L0.57 2/21/20SM21-22 6200B11,2,3-Trichlorobenzene
ND 0.50 2/23/20 1:04 EEHg/L0.40 2/21/20SM21-22 6200B11,2,4-Trichlorobenzene
ND 0.50 2/23/20 1:04 EEHg/L0.20 2/21/20SM21-22 6200B11,1,1-Trichloroethane
ND 0.50 2/23/20 1:04 EEHg/L0.16 2/21/20SM21-22 6200B11,1,2-Trichloroethane
ND 0.50 2/23/20 1:04 EEHg/L0.24 2/21/20SM21-22 6200B1Trichloroethylene
ND 0.50 2/23/20 1:04 EEHg/L0.33 2/21/20SM21-22 6200B1Trichlorofluoromethane (Freon 11)
ND 0.50 2/23/20 1:04 EEHg/L0.25 2/21/20SM21-22 6200B11,2,3-Trichloropropane
ND 0.50 2/23/20 1:04 EEHg/L0.18 2/21/20SM21-22 6200B11,2,4-Trimethylbenzene
ND 0.50 2/23/20 1:04 EEHg/L0.14 2/21/20SM21-22 6200B11,3,5-Trimethylbenzene
ND 20 2/23/20 1:04 EEHg/L10 2/21/20SM21-22 6200B1Vinyl Acetate
ND 0.50 2/23/20 1:04 EEHg/L0.45 2/21/20SM21-22 6200B1Vinyl Chloride
ND 1.0 2/23/20 1:04 EEHg/L0.30 2/21/20SM21-22 6200B1m+p Xylene
ND 0.50 2/23/20 1:04 EEHg/L0.17 2/21/20SM21-22 6200B1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 90.8 2/23/20 1:0470-130
Toluene-d8 99.1 2/23/20 1:0470-130
4-Bromofluorobenzene 95.0 2/23/20 1:0470-130
Page 23 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/19/2020
Work Order: 20B0870Sample Description:Project Location: Middleburg, Vance County, NC
Sample ID: 20B0870-09
Field Sample #: WSW-1
Sample Matrix: Ground Water
Sampled: 2/18/2020 15:00
[TOC_2]20B0870-09[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 2/22/20 21:12 EEHg/L3.8 2/21/20SM21-22 6200B1Acetone
ND 0.50 2/22/20 21:12 EEHg/L0.18 2/21/20SM21-22 6200B1Benzene
ND 0.50 2/22/20 21:12 EEHg/L0.15 2/21/20SM21-22 6200B1Bromobenzene
ND 0.50 2/22/20 21:12 EEHg/L0.32 2/21/20SM21-22 6200B1Bromochloromethane
ND 0.50 2/22/20 21:12 EEHg/L0.16 2/21/20SM21-22 6200B1Bromodichloromethane
ND 0.50 2/22/20 21:12 EEHg/L0.46 2/21/20SM21-22 6200B1Bromoform
ND 1.0 2/22/20 21:12 EEHg/L0.78 2/21/20SM21-22 6200B1Bromomethane
ND 5.0 2/22/20 21:12 EEHg/L1.9 2/21/20SM21-22 6200B12-Butanone (MEK)
ND 0.50 2/22/20 21:12 EEHg/L0.21 2/21/20SM21-22 6200B1n-Butylbenzene
ND 0.50 2/22/20 21:12 EEHg/L0.16 2/21/20SM21-22 6200B1sec-Butylbenzene
ND 0.50 2/22/20 21:12 EEHg/L0.17 2/21/20SM21-22 6200B1tert-Butylbenzene
ND 0.50 2/22/20 21:12 EEHg/L0.11 2/21/20SM21-22 6200B1Carbon Tetrachloride
ND 0.50 2/22/20 21:12 EEHg/L0.15 2/21/20SM21-22 6200B1Chlorobenzene
ND 50 2/22/20 21:12 EEHg/L11 2/21/20SM21-22 6200B1Ethanol
ND 0.50 2/22/20 21:12 EEHg/L0.21 2/21/20SM21-22 6200B1Chlorodibromomethane
ND 0.50 2/22/20 21:12 EEHg/L0.35 2/21/20SM21-22 6200B1Chloroethane
0.38 0.50 2/22/20 21:12 EEHg/L0.17 2/21/20SM21-22 6200B1JChloroform
ND 1.0 2/22/20 21:12 EEHg/L0.45 2/21/20SM21-22 6200B1Chloromethane
ND 0.50 2/22/20 21:12 EEHg/L0.12 2/21/20SM21-22 6200B12-Chlorotoluene
ND 0.50 2/22/20 21:12 EEHg/L0.14 2/21/20SM21-22 6200B14-Chlorotoluene
ND 0.50 2/22/20 21:12 EEHg/L0.19 2/21/20SM21-22 6200B11,2-Dibromoethane (EDB)
ND 0.50 2/22/20 21:12 EEHg/L0.16 2/21/20SM21-22 6200B11,2-Dichlorobenzene
ND 0.50 2/22/20 21:12 EEHg/L0.12 2/21/20SM21-22 6200B11,3-Dichlorobenzene
ND 0.50 2/22/20 21:12 EEHg/L0.13 2/21/20SM21-22 6200B11,4-Dichlorobenzene
ND 0.50 2/22/20 21:12 EEHg/L0.26 2/21/20SM21-22 6200B1Dichlorodifluoromethane (Freon 12)
ND 0.50 2/22/20 21:12 EEHg/L0.16 2/21/20SM21-22 6200B11,1-Dichloroethane
ND 1.0 2/22/20 21:12 EEHg/L0.41 2/21/20SM21-22 6200B11,2-Dichloroethane
ND 0.50 2/22/20 21:12 EEHg/L0.32 2/21/20SM21-22 6200B11,1-Dichloroethylene
ND 0.50 2/22/20 21:12 EEHg/L0.13 2/21/20SM21-22 6200B1cis-1,2-Dichloroethylene
ND 0.50 2/22/20 21:12 EEHg/L0.31 2/21/20SM21-22 6200B1trans-1,2-Dichloroethylene
ND 0.50 2/22/20 21:12 EEHg/L0.20 2/21/20SM21-22 6200B11,2-Dichloropropane
ND 0.50 2/22/20 21:12 EEHg/L0.11 2/21/20SM21-22 6200B11,3-Dichloropropane
ND 0.50 2/22/20 21:12 EEHg/L0.20 2/21/20SM21-22 6200B12,2-Dichloropropane
ND 0.50 2/22/20 21:12 EEHg/L0.16 2/21/20SM21-22 6200B11,1-Dichloropropene
ND 0.50 2/22/20 21:12 EEHg/L0.13 2/21/20SM21-22 6200B1cis-1,3-Dichloropropene
ND 0.50 2/22/20 21:12 EEHg/L0.23 2/21/20SM21-22 6200B1trans-1,3-Dichloropropene
ND 0.50 2/22/20 21:12 EEHg/L0.17 2/21/20SM21-22 6200B1Diisopropyl Ether (DIPE)
ND 0.50 2/22/20 21:12 EEHg/L0.13 2/21/20SM21-22 6200B1Ethylbenzene
ND 5.0 2/22/20 21:12 EEHg/L1.5 2/21/20SM21-22 6200B12-Hexanone (MBK)
ND 0.50 2/22/20 21:12 EEHg/L0.17 2/21/20SM21-22 6200B1Isopropylbenzene (Cumene)
ND 0.50 2/22/20 21:12 EEHg/L0.20 2/21/20SM21-22 6200B1p-Isopropyltoluene (p-Cymene)
ND 0.50 2/22/20 21:12 EEHg/L0.25 2/21/20SM21-22 6200B1Methyl tert-Butyl Ether (MTBE)
ND 5.0 2/22/20 21:12 EEHg/L0.34 2/21/20SM21-22 6200B1Methylene Chloride
ND 5.0 2/22/20 21:12 EEHg/L1.7 2/21/20SM21-22 6200B14-Methyl-2-pentanone (MIBK)
Page 24 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/19/2020
Work Order: 20B0870Sample Description:Project Location: Middleburg, Vance County, NC
Sample ID: 20B0870-09
Field Sample #: WSW-1
Sample Matrix: Ground Water
Sampled: 2/18/2020 15:00
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 5.0 2/22/20 21:12 EEHg/L0.31 2/21/20SM21-22 6200B1Naphthalene
ND 0.50 2/22/20 21:12 EEHg/L0.13 2/21/20SM21-22 6200B1n-Propylbenzene
ND 0.50 2/22/20 21:12 EEHg/L0.11 2/21/20SM21-22 6200B1Styrene
ND 0.50 2/22/20 21:12 EEHg/L0.22 2/21/20SM21-22 6200B11,1,2,2-Tetrachloroethane
ND 0.50 2/22/20 21:12 EEHg/L0.18 2/21/20SM21-22 6200B1Tetrachloroethylene
ND 0.50 2/22/20 21:12 EEHg/L0.14 2/21/20SM21-22 6200B1Toluene
ND 2.0 2/22/20 21:12 EEHg/L0.57 2/21/20SM21-22 6200B11,2,3-Trichlorobenzene
ND 0.50 2/22/20 21:12 EEHg/L0.40 2/21/20SM21-22 6200B11,2,4-Trichlorobenzene
ND 0.50 2/22/20 21:12 EEHg/L0.20 2/21/20SM21-22 6200B11,1,1-Trichloroethane
ND 0.50 2/22/20 21:12 EEHg/L0.16 2/21/20SM21-22 6200B11,1,2-Trichloroethane
ND 0.50 2/22/20 21:12 EEHg/L0.24 2/21/20SM21-22 6200B1Trichloroethylene
ND 0.50 2/22/20 21:12 EEHg/L0.33 2/21/20SM21-22 6200B1Trichlorofluoromethane (Freon 11)
ND 0.50 2/22/20 21:12 EEHg/L0.25 2/21/20SM21-22 6200B11,2,3-Trichloropropane
ND 0.50 2/22/20 21:12 EEHg/L0.18 2/21/20SM21-22 6200B11,2,4-Trimethylbenzene
ND 0.50 2/22/20 21:12 EEHg/L0.14 2/21/20SM21-22 6200B11,3,5-Trimethylbenzene
ND 20 2/22/20 21:12 EEHg/L10 2/21/20SM21-22 6200B1Vinyl Acetate
ND 0.50 2/22/20 21:12 EEHg/L0.45 2/21/20SM21-22 6200B1Vinyl Chloride
ND 1.0 2/22/20 21:12 EEHg/L0.30 2/21/20SM21-22 6200B1m+p Xylene
ND 0.50 2/22/20 21:12 EEHg/L0.17 2/21/20SM21-22 6200B1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 91.4 2/22/20 21:1270-130
Toluene-d8 98.7 2/22/20 21:1270-130
4-Bromofluorobenzene 95.2 2/22/20 21:1270-130
Page 25 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/19/2020
Work Order: 20B0870Sample Description:Project Location: Middleburg, Vance County, NC
Sample ID: 20B0870-10
Field Sample #: WSW-2
Sample Matrix: Ground Water
Sampled: 2/18/2020 15:19
[TOC_2]20B0870-10[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 2/22/20 22:10 EEHg/L3.8 2/21/20SM21-22 6200B1Acetone
ND 0.50 2/22/20 22:10 EEHg/L0.18 2/21/20SM21-22 6200B1Benzene
ND 0.50 2/22/20 22:10 EEHg/L0.15 2/21/20SM21-22 6200B1Bromobenzene
ND 0.50 2/22/20 22:10 EEHg/L0.32 2/21/20SM21-22 6200B1Bromochloromethane
ND 0.50 2/22/20 22:10 EEHg/L0.16 2/21/20SM21-22 6200B1Bromodichloromethane
ND 0.50 2/22/20 22:10 EEHg/L0.46 2/21/20SM21-22 6200B1Bromoform
ND 1.0 2/22/20 22:10 EEHg/L0.78 2/21/20SM21-22 6200B1Bromomethane
ND 5.0 2/22/20 22:10 EEHg/L1.9 2/21/20SM21-22 6200B12-Butanone (MEK)
ND 0.50 2/22/20 22:10 EEHg/L0.21 2/21/20SM21-22 6200B1n-Butylbenzene
ND 0.50 2/22/20 22:10 EEHg/L0.16 2/21/20SM21-22 6200B1sec-Butylbenzene
ND 0.50 2/22/20 22:10 EEHg/L0.17 2/21/20SM21-22 6200B1tert-Butylbenzene
ND 0.50 2/22/20 22:10 EEHg/L0.11 2/21/20SM21-22 6200B1Carbon Tetrachloride
ND 0.50 2/22/20 22:10 EEHg/L0.15 2/21/20SM21-22 6200B1Chlorobenzene
ND 50 2/22/20 22:10 EEHg/L11 2/21/20SM21-22 6200B1Ethanol
ND 0.50 2/22/20 22:10 EEHg/L0.21 2/21/20SM21-22 6200B1Chlorodibromomethane
ND 0.50 2/22/20 22:10 EEHg/L0.35 2/21/20SM21-22 6200B1Chloroethane
ND 0.50 2/22/20 22:10 EEHg/L0.17 2/21/20SM21-22 6200B1Chloroform
ND 1.0 2/22/20 22:10 EEHg/L0.45 2/21/20SM21-22 6200B1Chloromethane
ND 0.50 2/22/20 22:10 EEHg/L0.12 2/21/20SM21-22 6200B12-Chlorotoluene
ND 0.50 2/22/20 22:10 EEHg/L0.14 2/21/20SM21-22 6200B14-Chlorotoluene
ND 0.50 2/22/20 22:10 EEHg/L0.19 2/21/20SM21-22 6200B11,2-Dibromoethane (EDB)
ND 0.50 2/22/20 22:10 EEHg/L0.16 2/21/20SM21-22 6200B11,2-Dichlorobenzene
ND 0.50 2/22/20 22:10 EEHg/L0.12 2/21/20SM21-22 6200B11,3-Dichlorobenzene
ND 0.50 2/22/20 22:10 EEHg/L0.13 2/21/20SM21-22 6200B11,4-Dichlorobenzene
ND 0.50 2/22/20 22:10 EEHg/L0.26 2/21/20SM21-22 6200B1Dichlorodifluoromethane (Freon 12)
ND 0.50 2/22/20 22:10 EEHg/L0.16 2/21/20SM21-22 6200B11,1-Dichloroethane
ND 1.0 2/22/20 22:10 EEHg/L0.41 2/21/20SM21-22 6200B11,2-Dichloroethane
ND 0.50 2/22/20 22:10 EEHg/L0.32 2/21/20SM21-22 6200B11,1-Dichloroethylene
ND 0.50 2/22/20 22:10 EEHg/L0.13 2/21/20SM21-22 6200B1cis-1,2-Dichloroethylene
ND 0.50 2/22/20 22:10 EEHg/L0.31 2/21/20SM21-22 6200B1trans-1,2-Dichloroethylene
ND 0.50 2/22/20 22:10 EEHg/L0.20 2/21/20SM21-22 6200B11,2-Dichloropropane
ND 0.50 2/22/20 22:10 EEHg/L0.11 2/21/20SM21-22 6200B11,3-Dichloropropane
ND 0.50 2/22/20 22:10 EEHg/L0.20 2/21/20SM21-22 6200B12,2-Dichloropropane
ND 0.50 2/22/20 22:10 EEHg/L0.16 2/21/20SM21-22 6200B11,1-Dichloropropene
ND 0.50 2/22/20 22:10 EEHg/L0.13 2/21/20SM21-22 6200B1cis-1,3-Dichloropropene
ND 0.50 2/22/20 22:10 EEHg/L0.23 2/21/20SM21-22 6200B1trans-1,3-Dichloropropene
ND 0.50 2/22/20 22:10 EEHg/L0.17 2/21/20SM21-22 6200B1Diisopropyl Ether (DIPE)
ND 0.50 2/22/20 22:10 EEHg/L0.13 2/21/20SM21-22 6200B1Ethylbenzene
ND 5.0 2/22/20 22:10 EEHg/L1.5 2/21/20SM21-22 6200B12-Hexanone (MBK)
ND 0.50 2/22/20 22:10 EEHg/L0.17 2/21/20SM21-22 6200B1Isopropylbenzene (Cumene)
ND 0.50 2/22/20 22:10 EEHg/L0.20 2/21/20SM21-22 6200B1p-Isopropyltoluene (p-Cymene)
ND 0.50 2/22/20 22:10 EEHg/L0.25 2/21/20SM21-22 6200B1Methyl tert-Butyl Ether (MTBE)
ND 5.0 2/22/20 22:10 EEHg/L0.34 2/21/20SM21-22 6200B1Methylene Chloride
ND 5.0 2/22/20 22:10 EEHg/L1.7 2/21/20SM21-22 6200B14-Methyl-2-pentanone (MIBK)
Page 26 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/19/2020
Work Order: 20B0870Sample Description:Project Location: Middleburg, Vance County, NC
Sample ID: 20B0870-10
Field Sample #: WSW-2
Sample Matrix: Ground Water
Sampled: 2/18/2020 15:19
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 5.0 2/22/20 22:10 EEHg/L0.31 2/21/20SM21-22 6200B1Naphthalene
ND 0.50 2/22/20 22:10 EEHg/L0.13 2/21/20SM21-22 6200B1n-Propylbenzene
ND 0.50 2/22/20 22:10 EEHg/L0.11 2/21/20SM21-22 6200B1Styrene
ND 0.50 2/22/20 22:10 EEHg/L0.22 2/21/20SM21-22 6200B11,1,2,2-Tetrachloroethane
ND 0.50 2/22/20 22:10 EEHg/L0.18 2/21/20SM21-22 6200B1Tetrachloroethylene
ND 0.50 2/22/20 22:10 EEHg/L0.14 2/21/20SM21-22 6200B1Toluene
ND 2.0 2/22/20 22:10 EEHg/L0.57 2/21/20SM21-22 6200B11,2,3-Trichlorobenzene
ND 0.50 2/22/20 22:10 EEHg/L0.40 2/21/20SM21-22 6200B11,2,4-Trichlorobenzene
ND 0.50 2/22/20 22:10 EEHg/L0.20 2/21/20SM21-22 6200B11,1,1-Trichloroethane
ND 0.50 2/22/20 22:10 EEHg/L0.16 2/21/20SM21-22 6200B11,1,2-Trichloroethane
ND 0.50 2/22/20 22:10 EEHg/L0.24 2/21/20SM21-22 6200B1Trichloroethylene
ND 0.50 2/22/20 22:10 EEHg/L0.33 2/21/20SM21-22 6200B1Trichlorofluoromethane (Freon 11)
ND 0.50 2/22/20 22:10 EEHg/L0.25 2/21/20SM21-22 6200B11,2,3-Trichloropropane
ND 0.50 2/22/20 22:10 EEHg/L0.18 2/21/20SM21-22 6200B11,2,4-Trimethylbenzene
ND 0.50 2/22/20 22:10 EEHg/L0.14 2/21/20SM21-22 6200B11,3,5-Trimethylbenzene
ND 20 2/22/20 22:10 EEHg/L10 2/21/20SM21-22 6200B1Vinyl Acetate
ND 0.50 2/22/20 22:10 EEHg/L0.45 2/21/20SM21-22 6200B1Vinyl Chloride
ND 1.0 2/22/20 22:10 EEHg/L0.30 2/21/20SM21-22 6200B1m+p Xylene
ND 0.50 2/22/20 22:10 EEHg/L0.17 2/21/20SM21-22 6200B1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 89.7 2/22/20 22:1070-130
Toluene-d8 98.1 2/22/20 22:1070-130
4-Bromofluorobenzene 93.6 2/22/20 22:1070-130
Page 27 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/19/2020
Work Order: 20B0870Sample Description:Project Location: Middleburg, Vance County, NC
Sample ID: 20B0870-11
Field Sample #: WSW-13
Sample Matrix: Ground Water
Sampled: 2/18/2020 15:30
[TOC_2]20B0870-11[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 2/22/20 21:41 EEHg/L3.8 2/21/20SM21-22 6200B1Acetone
ND 0.50 2/22/20 21:41 EEHg/L0.18 2/21/20SM21-22 6200B1Benzene
ND 0.50 2/22/20 21:41 EEHg/L0.15 2/21/20SM21-22 6200B1Bromobenzene
ND 0.50 2/22/20 21:41 EEHg/L0.32 2/21/20SM21-22 6200B1Bromochloromethane
ND 0.50 2/22/20 21:41 EEHg/L0.16 2/21/20SM21-22 6200B1Bromodichloromethane
ND 0.50 2/22/20 21:41 EEHg/L0.46 2/21/20SM21-22 6200B1Bromoform
ND 1.0 2/22/20 21:41 EEHg/L0.78 2/21/20SM21-22 6200B1Bromomethane
ND 5.0 2/22/20 21:41 EEHg/L1.9 2/21/20SM21-22 6200B12-Butanone (MEK)
ND 0.50 2/22/20 21:41 EEHg/L0.21 2/21/20SM21-22 6200B1n-Butylbenzene
ND 0.50 2/22/20 21:41 EEHg/L0.16 2/21/20SM21-22 6200B1sec-Butylbenzene
ND 0.50 2/22/20 21:41 EEHg/L0.17 2/21/20SM21-22 6200B1tert-Butylbenzene
ND 0.50 2/22/20 21:41 EEHg/L0.11 2/21/20SM21-22 6200B1Carbon Tetrachloride
ND 0.50 2/22/20 21:41 EEHg/L0.15 2/21/20SM21-22 6200B1Chlorobenzene
ND 50 2/22/20 21:41 EEHg/L11 2/21/20SM21-22 6200B1Ethanol
ND 0.50 2/22/20 21:41 EEHg/L0.21 2/21/20SM21-22 6200B1Chlorodibromomethane
ND 0.50 2/22/20 21:41 EEHg/L0.35 2/21/20SM21-22 6200B1Chloroethane
ND 0.50 2/22/20 21:41 EEHg/L0.17 2/21/20SM21-22 6200B1Chloroform
ND 1.0 2/22/20 21:41 EEHg/L0.45 2/21/20SM21-22 6200B1Chloromethane
ND 0.50 2/22/20 21:41 EEHg/L0.12 2/21/20SM21-22 6200B12-Chlorotoluene
ND 0.50 2/22/20 21:41 EEHg/L0.14 2/21/20SM21-22 6200B14-Chlorotoluene
ND 0.50 2/22/20 21:41 EEHg/L0.19 2/21/20SM21-22 6200B11,2-Dibromoethane (EDB)
ND 0.50 2/22/20 21:41 EEHg/L0.16 2/21/20SM21-22 6200B11,2-Dichlorobenzene
ND 0.50 2/22/20 21:41 EEHg/L0.12 2/21/20SM21-22 6200B11,3-Dichlorobenzene
ND 0.50 2/22/20 21:41 EEHg/L0.13 2/21/20SM21-22 6200B11,4-Dichlorobenzene
ND 0.50 2/22/20 21:41 EEHg/L0.26 2/21/20SM21-22 6200B1Dichlorodifluoromethane (Freon 12)
ND 0.50 2/22/20 21:41 EEHg/L0.16 2/21/20SM21-22 6200B11,1-Dichloroethane
ND 1.0 2/22/20 21:41 EEHg/L0.41 2/21/20SM21-22 6200B11,2-Dichloroethane
ND 0.50 2/22/20 21:41 EEHg/L0.32 2/21/20SM21-22 6200B11,1-Dichloroethylene
ND 0.50 2/22/20 21:41 EEHg/L0.13 2/21/20SM21-22 6200B1cis-1,2-Dichloroethylene
ND 0.50 2/22/20 21:41 EEHg/L0.31 2/21/20SM21-22 6200B1trans-1,2-Dichloroethylene
ND 0.50 2/22/20 21:41 EEHg/L0.20 2/21/20SM21-22 6200B11,2-Dichloropropane
ND 0.50 2/22/20 21:41 EEHg/L0.11 2/21/20SM21-22 6200B11,3-Dichloropropane
ND 0.50 2/22/20 21:41 EEHg/L0.20 2/21/20SM21-22 6200B12,2-Dichloropropane
ND 0.50 2/22/20 21:41 EEHg/L0.16 2/21/20SM21-22 6200B11,1-Dichloropropene
ND 0.50 2/22/20 21:41 EEHg/L0.13 2/21/20SM21-22 6200B1cis-1,3-Dichloropropene
ND 0.50 2/22/20 21:41 EEHg/L0.23 2/21/20SM21-22 6200B1trans-1,3-Dichloropropene
ND 0.50 2/22/20 21:41 EEHg/L0.17 2/21/20SM21-22 6200B1Diisopropyl Ether (DIPE)
ND 0.50 2/22/20 21:41 EEHg/L0.13 2/21/20SM21-22 6200B1Ethylbenzene
ND 5.0 2/22/20 21:41 EEHg/L1.5 2/21/20SM21-22 6200B12-Hexanone (MBK)
ND 0.50 2/22/20 21:41 EEHg/L0.17 2/21/20SM21-22 6200B1Isopropylbenzene (Cumene)
ND 0.50 2/22/20 21:41 EEHg/L0.20 2/21/20SM21-22 6200B1p-Isopropyltoluene (p-Cymene)
ND 0.50 2/22/20 21:41 EEHg/L0.25 2/21/20SM21-22 6200B1Methyl tert-Butyl Ether (MTBE)
ND 5.0 2/22/20 21:41 EEHg/L0.34 2/21/20SM21-22 6200B1Methylene Chloride
ND 5.0 2/22/20 21:41 EEHg/L1.7 2/21/20SM21-22 6200B14-Methyl-2-pentanone (MIBK)
Page 28 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/19/2020
Work Order: 20B0870Sample Description:Project Location: Middleburg, Vance County, NC
Sample ID: 20B0870-11
Field Sample #: WSW-13
Sample Matrix: Ground Water
Sampled: 2/18/2020 15:30
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 5.0 2/22/20 21:41 EEHg/L0.31 2/21/20SM21-22 6200B1Naphthalene
ND 0.50 2/22/20 21:41 EEHg/L0.13 2/21/20SM21-22 6200B1n-Propylbenzene
ND 0.50 2/22/20 21:41 EEHg/L0.11 2/21/20SM21-22 6200B1Styrene
ND 0.50 2/22/20 21:41 EEHg/L0.22 2/21/20SM21-22 6200B11,1,2,2-Tetrachloroethane
ND 0.50 2/22/20 21:41 EEHg/L0.18 2/21/20SM21-22 6200B1Tetrachloroethylene
ND 0.50 2/22/20 21:41 EEHg/L0.14 2/21/20SM21-22 6200B1Toluene
ND 2.0 2/22/20 21:41 EEHg/L0.57 2/21/20SM21-22 6200B11,2,3-Trichlorobenzene
ND 0.50 2/22/20 21:41 EEHg/L0.40 2/21/20SM21-22 6200B11,2,4-Trichlorobenzene
ND 0.50 2/22/20 21:41 EEHg/L0.20 2/21/20SM21-22 6200B11,1,1-Trichloroethane
ND 0.50 2/22/20 21:41 EEHg/L0.16 2/21/20SM21-22 6200B11,1,2-Trichloroethane
ND 0.50 2/22/20 21:41 EEHg/L0.24 2/21/20SM21-22 6200B1Trichloroethylene
ND 0.50 2/22/20 21:41 EEHg/L0.33 2/21/20SM21-22 6200B1Trichlorofluoromethane (Freon 11)
ND 0.50 2/22/20 21:41 EEHg/L0.25 2/21/20SM21-22 6200B11,2,3-Trichloropropane
ND 0.50 2/22/20 21:41 EEHg/L0.18 2/21/20SM21-22 6200B11,2,4-Trimethylbenzene
ND 0.50 2/22/20 21:41 EEHg/L0.14 2/21/20SM21-22 6200B11,3,5-Trimethylbenzene
ND 20 2/22/20 21:41 EEHg/L10 2/21/20SM21-22 6200B1Vinyl Acetate
ND 0.50 2/22/20 21:41 EEHg/L0.45 2/21/20SM21-22 6200B1Vinyl Chloride
ND 1.0 2/22/20 21:41 EEHg/L0.30 2/21/20SM21-22 6200B1m+p Xylene
ND 0.50 2/22/20 21:41 EEHg/L0.17 2/21/20SM21-22 6200B1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 90.3 2/22/20 21:4170-130
Toluene-d8 97.6 2/22/20 21:4170-130
4-Bromofluorobenzene 94.4 2/22/20 21:4170-130
Page 29 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Sample Extraction Data
Prep Method: SW-846 5030B-SM21-22 6200B
Lab Number [Field ID]Batch DateInitial [mL]Final [mL]
B252791 02/21/2055.0020B0870-01 [field blank]
B252791 02/21/2055.0020B0870-02 [MW-6]
B252791 02/21/2055.0020B0870-03 [MW-4R]
B252791 02/21/2055.0020B0870-04 [MW-2R]
B252791 02/21/2055.0020B0870-05 [MW-13]
B252791 02/21/200.1 5.0020B0870-07 [MW-12]
B252791 02/21/2055.0020B0870-08 [DW-1]
B252791 02/21/2055.0020B0870-09 [WSW-1]
B252791 02/21/2055.0020B0870-10 [WSW-2]
B252791 02/21/2055.0020B0870-11 [WSW-13]
Prep Method: SW-846 5030B-SM21-22 6200B
Lab Number [Field ID]Batch DateInitial [mL]Final [mL]
B252860 02/24/200.125 5.0020B0870-06 [MW-1R]
[TOC_1]Sample Preparation Information[TOC]
Page 30 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
[TOC_2]Volatile Organic Compounds by GC/MS[TOC]
Batch B252791 - SW-846 5030B
[TOC_3]B252791[TOC]
Blank (B252791-BLK1) Prepared: 02/21/20 Analyzed: 02/22/20
Acetone g/L50ND
Benzene g/L0.50ND
Bromobenzene g/L0.50ND
Bromochloromethane g/L0.50ND
Bromodichloromethane g/L0.50ND
Bromoform g/L0.50ND
Bromomethane g/L1.0ND
2-Butanone (MEK)g/L5.0ND
n-Butylbenzene g/L0.50ND
sec-Butylbenzene g/L0.50ND
tert-Butylbenzene g/L0.50ND
Carbon Tetrachloride g/L0.50ND
Chlorobenzene g/L0.50ND
Ethanol g/L50ND
Chlorodibromomethane g/L0.50ND
Chloroethane g/L0.50ND
Chloroform g/L0.50ND
Chloromethane g/L0.60ND
2-Chlorotoluene g/L0.50ND
4-Chlorotoluene g/L0.50ND
1,2-Dibromoethane (EDB)g/L0.50ND
1,2-Dichlorobenzene g/L0.50ND
1,3-Dichlorobenzene g/L0.50ND
1,4-Dichlorobenzene g/L0.50ND
Dichlorodifluoromethane (Freon 12)g/L0.50ND
1,1-Dichloroethane g/L0.50ND
1,2-Dichloroethane g/L0.50ND
1,1-Dichloroethylene g/L0.50ND
cis-1,2-Dichloroethylene g/L0.50ND
trans-1,2-Dichloroethylene g/L0.50ND
1,2-Dichloropropane g/L0.50ND
1,3-Dichloropropane g/L0.50ND
2,2-Dichloropropane g/L0.50ND
1,1-Dichloropropene g/L0.50ND
cis-1,3-Dichloropropene g/L0.50ND
trans-1,3-Dichloropropene g/L0.50ND
Diisopropyl Ether (DIPE)g/L0.50ND
Ethylbenzene g/L0.50ND
2-Hexanone (MBK)g/L5.0ND
Isopropylbenzene (Cumene)g/L0.50ND
p-Isopropyltoluene (p-Cymene)g/L0.50ND
Methyl tert-Butyl Ether (MTBE)g/L0.50ND
Methylene Chloride g/L5.0ND
4-Methyl-2-pentanone (MIBK)g/L5.0ND
Naphthalene g/L0.50ND
n-Propylbenzene g/L0.50ND
Styrene g/L0.50ND
1,1,2,2-Tetrachloroethane g/L0.50ND
Tetrachloroethylene g/L0.50ND
Toluene g/L0.50ND
1,2,3-Trichlorobenzene g/L1.0ND
1,2,4-Trichlorobenzene g/L0.50ND
[TOC_1]QC Data[TOC]
Page 31 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B252791 - SW-846 5030B
Blank (B252791-BLK1) Prepared: 02/21/20 Analyzed: 02/22/20
1,1,1-Trichloroethane g/L0.50ND
1,1,2-Trichloroethane g/L0.50ND
Trichloroethylene g/L0.50ND
Trichlorofluoromethane (Freon 11)g/L0.50ND
1,2,3-Trichloropropane g/L0.50ND
1,2,4-Trimethylbenzene g/L0.50ND
1,3,5-Trimethylbenzene g/L0.50ND
Vinyl Acetate g/L20ND
Vinyl Chloride g/L0.50ND
m+p Xylene g/L1.0ND
o-Xylene g/L0.50ND
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 90.422.6
g/L 25.0 70-130Surrogate: Toluene-d8 98.624.6
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 96.024.0
LCS (B252791-BS1) Prepared: 02/21/20 Analyzed: 02/22/20
Acetone g/L50 100 70-13085.585.5
Benzene g/L0.50 10.0 70-13088.38.83
Bromobenzene g/L0.50 10.0 70-13010110.1
Bromochloromethane g/L0.50 10.0 70-13095.79.57
Bromodichloromethane g/L0.50 10.0 70-13099.69.96
Bromoform g/L0.50 10.0 70-13097.89.78
Bromomethane g/L1.0 10.0 60-14010610.6
2-Butanone (MEK)g/L5.0 100 70-13080.180.1
n-Butylbenzene g/L0.50 10.0 70-13010910.9
sec-Butylbenzene g/L0.50 10.0 70-13011011.0
tert-Butylbenzene g/L0.50 10.0 70-13010910.9
Carbon Tetrachloride g/L0.50 10.0 70-13098.69.86
Chlorobenzene g/L0.50 10.0 70-13010510.5
Ethanol g/L50 100 L-0770-130132*132
Chlorodibromomethane g/L0.50 10.0 70-13096.09.60
Chloroethane g/L0.50 10.0 60-14093.69.36
Chloroform g/L0.50 10.0 70-13088.38.83
Chloromethane g/L0.60 10.0 60-14085.38.53
2-Chlorotoluene g/L0.50 10.0 70-13010010.0
4-Chlorotoluene g/L0.50 10.0 70-13010910.9
1,2-Dibromoethane (EDB)g/L0.50 10.0 70-13093.29.32
1,2-Dichlorobenzene g/L0.50 10.0 70-13010310.3
1,3-Dichlorobenzene g/L0.50 10.0 70-13010410.4
1,4-Dichlorobenzene g/L0.50 10.0 70-13010410.4
Dichlorodifluoromethane (Freon 12)g/L0.50 10.0 60-14075.17.51
1,1-Dichloroethane g/L0.50 10.0 70-13090.49.04
1,2-Dichloroethane g/L0.50 10.0 70-13098.59.85
1,1-Dichloroethylene g/L0.50 10.0 70-13098.49.84
cis-1,2-Dichloroethylene g/L0.50 10.0 70-13094.39.43
trans-1,2-Dichloroethylene g/L0.50 10.0 70-13097.49.74
1,2-Dichloropropane g/L0.50 10.0 70-13097.19.71
1,3-Dichloropropane g/L0.50 10.0 70-13096.19.61
2,2-Dichloropropane g/L0.50 10.0 70-13080.28.02
1,1-Dichloropropene g/L0.50 10.0 70-13094.39.43
cis-1,3-Dichloropropene g/L0.50 10.0 70-13099.39.93
trans-1,3-Dichloropropene g/L0.50 10.0 70-13095.69.56
Page 32 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B252791 - SW-846 5030B
LCS (B252791-BS1) Prepared: 02/21/20 Analyzed: 02/22/20
Diisopropyl Ether (DIPE)g/L0.50 10.0 70-13098.69.86
Ethylbenzene g/L0.50 10.0 70-13010610.6
2-Hexanone (MBK)g/L5.0 100 70-13096.996.9
Isopropylbenzene (Cumene)g/L0.50 10.0 70-13011011.0
p-Isopropyltoluene (p-Cymene)g/L0.50 10.0 70-13010610.6
Methyl tert-Butyl Ether (MTBE)g/L0.50 10.0 70-13070.67.06
Methylene Chloride g/L5.0 10.0 70-13097.69.76
4-Methyl-2-pentanone (MIBK)g/L5.0 100 70-130102102
Naphthalene g/L0.50 10.0 70-13091.39.13
n-Propylbenzene g/L0.50 10.0 70-13010910.9
Styrene g/L0.50 10.0 70-13010510.5
1,1,2,2-Tetrachloroethane g/L0.50 10.0 70-13097.79.77
Tetrachloroethylene g/L0.50 10.0 70-13010710.7
Toluene g/L0.50 10.0 70-13010110.1
1,2,3-Trichlorobenzene g/L1.0 10.0 70-13092.49.24
1,2,4-Trichlorobenzene g/L0.50 10.0 70-13098.09.80
1,1,1-Trichloroethane g/L0.50 10.0 70-13097.29.72
1,1,2-Trichloroethane g/L0.50 10.0 70-13094.89.48
Trichloroethylene g/L0.50 10.0 70-13099.89.98
Trichlorofluoromethane (Freon 11)g/L0.50 10.0 70-13097.69.76
1,2,3-Trichloropropane g/L0.50 10.0 70-13093.79.37
1,2,4-Trimethylbenzene g/L0.50 10.0 70-13010410.4
1,3,5-Trimethylbenzene g/L0.50 10.0 70-13010910.9
Vinyl Acetate g/L20 100 70-13083.683.6
Vinyl Chloride g/L0.50 10.0 L-0260-140216*21.6
m+p Xylene g/L1.0 20.0 70-13010821.6
o-Xylene g/L0.50 10.0 70-13010810.8
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 90.522.6
g/L 25.0 70-130Surrogate: Toluene-d8 95.423.8
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 96.224.0
LCS Dup (B252791-BSD1) Prepared: 02/21/20 Analyzed: 02/22/20
Acetone g/L50 100 2570-13092.4 7.8192.4
Benzene g/L0.50 10.0 2570-13089.6 1.468.96
Bromobenzene g/L0.50 10.0 2570-130104 3.2110.4
Bromochloromethane g/L0.50 10.0 2570-13099.0 3.399.90
Bromodichloromethane g/L0.50 10.0 2570-130108 8.0910.8
Bromoform g/L0.50 10.0 2570-130103 4.7910.3
Bromomethane g/L1.0 10.0 2560-140108 2.3410.8
2-Butanone (MEK)g/L5.0 100 2570-13086.2 7.3086.2
n-Butylbenzene g/L0.50 10.0 2570-130111 1.7311.1
sec-Butylbenzene g/L0.50 10.0 2570-130111 0.63111.1
tert-Butylbenzene g/L0.50 10.0 2570-130110 0.54911.0
Carbon Tetrachloride g/L0.50 10.0 2570-13099.0 0.4059.90
Chlorobenzene g/L0.50 10.0 2570-130106 0.76010.6
Ethanol g/L50 100 2570-130127 3.76127
Chlorodibromomethane g/L0.50 10.0 2570-130102 6.5510.2
Chloroethane g/L0.50 10.0 2560-14091.1 2.719.11
Chloroform g/L0.50 10.0 2570-13089.9 1.808.99
Chloromethane g/L0.60 10.0 2560-14087.1 2.098.71
2-Chlorotoluene g/L0.50 10.0 2570-13099.4 0.6029.94
4-Chlorotoluene g/L0.50 10.0 2570-130110 1.2811.0
Page 33 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B252791 - SW-846 5030B
LCS Dup (B252791-BSD1) Prepared: 02/21/20 Analyzed: 02/22/20
1,2-Dibromoethane (EDB)g/L0.50 10.0 2570-130100 7.5410.0
1,2-Dichlorobenzene g/L0.50 10.0 2570-130106 2.9610.6
1,3-Dichlorobenzene g/L0.50 10.0 2570-130108 3.3910.8
1,4-Dichlorobenzene g/L0.50 10.0 2570-130106 1.8110.6
Dichlorodifluoromethane (Freon 12)g/L0.50 10.0 2560-14072.4 3.667.24
1,1-Dichloroethane g/L0.50 10.0 2570-13092.3 2.089.23
1,2-Dichloroethane g/L0.50 10.0 2570-130102 3.2010.2
1,1-Dichloroethylene g/L0.50 10.0 2570-13095.8 2.689.58
cis-1,2-Dichloroethylene g/L0.50 10.0 2570-13095.7 1.479.57
trans-1,2-Dichloroethylene g/L0.50 10.0 2570-13096.2 1.249.62
1,2-Dichloropropane g/L0.50 10.0 2570-13097.4 0.3089.74
1,3-Dichloropropane g/L0.50 10.0 2570-13098.6 2.579.86
2,2-Dichloropropane g/L0.50 10.0 2570-13080.3 0.1258.03
1,1-Dichloropropene g/L0.50 10.0 2570-13095.5 1.269.55
cis-1,3-Dichloropropene g/L0.50 10.0 2570-130101 1.7010.1
trans-1,3-Dichloropropene g/L0.50 10.0 2570-13097.1 1.569.71
Diisopropyl Ether (DIPE)g/L0.50 10.0 2570-130103 4.2710.3
Ethylbenzene g/L0.50 10.0 2570-130108 2.1510.8
2-Hexanone (MBK)g/L5.0 100 2570-130109 12.0109
Isopropylbenzene (Cumene)g/L0.50 10.0 2570-130113 2.6811.3
p-Isopropyltoluene (p-Cymene)g/L0.50 10.0 2570-130107 1.5010.7
Methyl tert-Butyl Ether (MTBE)g/L0.50 10.0 2570-13076.6 8.157.66
Methylene Chloride g/L5.0 10.0 2570-13097.1 0.5149.71
4-Methyl-2-pentanone (MIBK)g/L5.0 100 2570-130113 9.69113
Naphthalene g/L0.50 10.0 2570-130104 13.510.4
n-Propylbenzene g/L0.50 10.0 2570-130111 1.7211.1
Styrene g/L0.50 10.0 2570-130108 2.4510.8
1,1,2,2-Tetrachloroethane g/L0.50 10.0 2570-130105 7.1110.5
Tetrachloroethylene g/L0.50 10.0 2570-130110 2.3911.0
Toluene g/L0.50 10.0 2570-130102 1.3810.2
1,2,3-Trichlorobenzene g/L1.0 10.0 2570-130113 20.411.3
1,2,4-Trichlorobenzene g/L0.50 10.0 2570-130113 14.011.3
1,1,1-Trichloroethane g/L0.50 10.0 2570-13097.0 0.2069.70
1,1,2-Trichloroethane g/L0.50 10.0 2570-13098.1 3.429.81
Trichloroethylene g/L0.50 10.0 2570-13099.6 0.2019.96
Trichlorofluoromethane (Freon 11)g/L0.50 10.0 2570-13095.0 2.709.50
1,2,3-Trichloropropane g/L0.50 10.0 2570-130103 9.6510.3
1,2,4-Trimethylbenzene g/L0.50 10.0 2570-130106 2.5710.6
1,3,5-Trimethylbenzene g/L0.50 10.0 2570-130111 1.9111.1
Vinyl Acetate g/L20 100 2570-13089.4 6.7489.4
Vinyl Chloride g/L0.50 10.0 25 L-0260-140213 1.31*21.3
m+p Xylene g/L1.0 20.0 2570-130110 2.0622.0
o-Xylene g/L0.50 10.0 2570-130112 3.0011.2
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 93.623.4
g/L 25.0 70-130Surrogate: Toluene-d8 98.024.5
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 98.324.6
Page 34 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B252860 - SW-846 5030B
[TOC_3]B252860[TOC]
Blank (B252860-BLK1) Prepared: 02/24/20 Analyzed: 02/25/20
Acetone g/L50ND
Benzene g/L0.50ND
Bromobenzene g/L0.50ND
Bromochloromethane g/L0.50ND
Bromodichloromethane g/L0.50ND
Bromoform g/L0.50ND
Bromomethane g/L1.0ND
2-Butanone (MEK)g/L5.0ND
n-Butylbenzene g/L0.50ND
sec-Butylbenzene g/L0.50ND
tert-Butylbenzene g/L0.50ND
Carbon Tetrachloride g/L0.50ND
Chlorobenzene g/L0.50ND
Ethanol g/L50ND
Chlorodibromomethane g/L0.50ND
Chloroethane g/L0.50ND
Chloroform g/L0.50ND
Chloromethane g/L0.60ND
2-Chlorotoluene g/L0.50ND
4-Chlorotoluene g/L0.50ND
1,2-Dibromoethane (EDB)g/L0.50ND
1,2-Dichlorobenzene g/L0.50ND
1,3-Dichlorobenzene g/L0.50ND
1,4-Dichlorobenzene g/L0.50ND
Dichlorodifluoromethane (Freon 12)g/L0.50ND
1,1-Dichloroethane g/L0.50ND
1,2-Dichloroethane g/L0.50ND
1,1-Dichloroethylene g/L0.50ND
cis-1,2-Dichloroethylene g/L0.50ND
trans-1,2-Dichloroethylene g/L0.50ND
1,2-Dichloropropane g/L0.50ND
1,3-Dichloropropane g/L0.50ND
2,2-Dichloropropane g/L0.50ND
1,1-Dichloropropene g/L0.50ND
cis-1,3-Dichloropropene g/L0.50ND
trans-1,3-Dichloropropene g/L0.50ND
Diisopropyl Ether (DIPE)g/L0.50ND
Ethylbenzene g/L0.50ND
2-Hexanone (MBK)g/L5.0ND
Isopropylbenzene (Cumene)g/L0.50ND
p-Isopropyltoluene (p-Cymene)g/L0.50ND
Methyl tert-Butyl Ether (MTBE)g/L0.50 L-04ND
Methylene Chloride g/L5.0ND
4-Methyl-2-pentanone (MIBK)g/L5.0ND
Naphthalene g/L0.50ND
n-Propylbenzene g/L0.50ND
Styrene g/L0.50ND
1,1,2,2-Tetrachloroethane g/L0.50ND
Tetrachloroethylene g/L0.50ND
Toluene g/L0.50ND
1,2,3-Trichlorobenzene g/L1.0ND
1,2,4-Trichlorobenzene g/L0.50ND
Page 35 of 45
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B252860 - SW-846 5030B
Blank (B252860-BLK1) Prepared: 02/24/20 Analyzed: 02/25/20
1,1,1-Trichloroethane g/L0.50ND
1,1,2-Trichloroethane g/L0.50ND
Trichloroethylene g/L0.50ND
Trichlorofluoromethane (Freon 11)g/L0.50ND
1,2,3-Trichloropropane g/L0.50ND
1,2,4-Trimethylbenzene g/L0.50ND
1,3,5-Trimethylbenzene g/L0.50ND
Vinyl Acetate g/L20ND
Vinyl Chloride g/L0.50ND
m+p Xylene g/L1.0ND
o-Xylene g/L0.50ND
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 88.622.2
g/L 25.0 70-130Surrogate: Toluene-d8 96.624.2
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 90.122.5
LCS (B252860-BS1) Prepared & Analyzed: 02/24/20
Acetone g/L50 100 70-13085.785.7
Benzene g/L0.50 10.0 70-13080.48.04
Bromobenzene g/L0.50 10.0 70-13098.69.86
Bromochloromethane g/L0.50 10.0 70-13089.48.94
Bromodichloromethane g/L0.50 10.0 70-13095.99.59
Bromoform g/L0.50 10.0 70-13096.49.64
Bromomethane g/L1.0 10.0 60-14092.59.25
2-Butanone (MEK)g/L5.0 100 70-13080.480.4
n-Butylbenzene g/L0.50 10.0 70-13010110.1
sec-Butylbenzene g/L0.50 10.0 70-13010410.4
tert-Butylbenzene g/L0.50 10.0 70-13010510.5
Carbon Tetrachloride g/L0.50 10.0 70-13091.79.17
Chlorobenzene g/L0.50 10.0 70-13010110.1
Ethanol g/L50 100 70-130125125
Chlorodibromomethane g/L0.50 10.0 70-13095.49.54
Chloroethane g/L0.50 10.0 60-14081.78.17
Chloroform g/L0.50 10.0 70-13085.28.52
Chloromethane g/L0.60 10.0 60-14072.87.28
2-Chlorotoluene g/L0.50 10.0 70-13094.19.41
4-Chlorotoluene g/L0.50 10.0 70-13010310.3
1,2-Dibromoethane (EDB)g/L0.50 10.0 70-13093.99.39
1,2-Dichlorobenzene g/L0.50 10.0 70-13099.79.97
1,3-Dichlorobenzene g/L0.50 10.0 70-13099.89.98
1,4-Dichlorobenzene g/L0.50 10.0 70-13010110.1
Dichlorodifluoromethane (Freon 12)g/L0.50 10.0 60-14065.26.52
1,1-Dichloroethane g/L0.50 10.0 70-13085.38.53
1,2-Dichloroethane g/L0.50 10.0 70-13094.29.42
1,1-Dichloroethylene g/L0.50 10.0 70-13087.88.78
cis-1,2-Dichloroethylene g/L0.50 10.0 70-13089.18.91
trans-1,2-Dichloroethylene g/L0.50 10.0 70-13085.78.57
1,2-Dichloropropane g/L0.50 10.0 70-13095.39.53
1,3-Dichloropropane g/L0.50 10.0 70-13095.79.57
2,2-Dichloropropane g/L0.50 10.0 70-13083.28.32
1,1-Dichloropropene g/L0.50 10.0 70-13086.88.68
cis-1,3-Dichloropropene g/L0.50 10.0 70-13096.89.68
trans-1,3-Dichloropropene g/L0.50 10.0 70-13093.19.31
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B252860 - SW-846 5030B
LCS (B252860-BS1) Prepared & Analyzed: 02/24/20
Diisopropyl Ether (DIPE)g/L0.50 10.0 70-13096.59.65
Ethylbenzene g/L0.50 10.0 70-13010310.3
2-Hexanone (MBK)g/L5.0 100 70-13099.999.9
Isopropylbenzene (Cumene)g/L0.50 10.0 70-13010810.8
p-Isopropyltoluene (p-Cymene)g/L0.50 10.0 70-13099.79.97
Methyl tert-Butyl Ether (MTBE)g/L0.50 10.0 L-0470-13067.2 *6.72
Methylene Chloride g/L5.0 10.0 70-13093.09.30
4-Methyl-2-pentanone (MIBK)g/L5.0 100 70-130104104
Naphthalene g/L0.50 10.0 70-13093.09.30
n-Propylbenzene g/L0.50 10.0 70-13010410.4
Styrene g/L0.50 10.0 70-13010110.1
1,1,2,2-Tetrachloroethane g/L0.50 10.0 70-13098.99.89
Tetrachloroethylene g/L0.50 10.0 70-13010110.1
Toluene g/L0.50 10.0 70-13094.79.47
1,2,3-Trichlorobenzene g/L1.0 10.0 70-13096.59.65
1,2,4-Trichlorobenzene g/L0.50 10.0 70-13095.99.59
1,1,1-Trichloroethane g/L0.50 10.0 70-13093.49.34
1,1,2-Trichloroethane g/L0.50 10.0 70-13092.39.23
Trichloroethylene g/L0.50 10.0 70-13091.79.17
Trichlorofluoromethane (Freon 11)g/L0.50 10.0 70-13088.78.87
1,2,3-Trichloropropane g/L0.50 10.0 70-13093.99.39
1,2,4-Trimethylbenzene g/L0.50 10.0 70-13098.09.80
1,3,5-Trimethylbenzene g/L0.50 10.0 70-13010310.3
Vinyl Acetate g/L20 100 70-13078.178.1
Vinyl Chloride g/L0.50 10.0 L-0260-140168*16.8
m+p Xylene g/L1.0 20.0 70-13010320.6
o-Xylene g/L0.50 10.0 70-13010510.5
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 88.922.2
g/L 25.0 70-130Surrogate: Toluene-d8 97.824.4
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 98.324.6
LCS Dup (B252860-BSD1) Prepared & Analyzed: 02/24/20
Acetone g/L50 100 2570-13082.3 4.1282.3
Benzene g/L0.50 10.0 2570-13079.4 1.257.94
Bromobenzene g/L0.50 10.0 2570-13097.6 1.029.76
Bromochloromethane g/L0.50 10.0 2570-13088.3 1.248.83
Bromodichloromethane g/L0.50 10.0 2570-13094.1 1.899.41
Bromoform g/L0.50 10.0 2570-13095.2 1.259.52
Bromomethane g/L1.0 10.0 2560-14079.0 15.77.90
2-Butanone (MEK)g/L5.0 100 2570-13073.2 9.4373.2
n-Butylbenzene g/L0.50 10.0 2570-130100 1.2910.0
sec-Butylbenzene g/L0.50 10.0 2570-130104 0.48110.4
tert-Butylbenzene g/L0.50 10.0 2570-130104 0.76610.4
Carbon Tetrachloride g/L0.50 10.0 2570-13090.6 1.219.06
Chlorobenzene g/L0.50 10.0 2570-130101 0.0010.1
Ethanol g/L50 100 2570-130127 1.67127
Chlorodibromomethane g/L0.50 10.0 2570-13095.0 0.4209.50
Chloroethane g/L0.50 10.0 2560-14077.0 5.927.70
Chloroform g/L0.50 10.0 2570-13082.9 2.748.29
Chloromethane g/L0.60 10.0 2560-14065.8 10.16.58
2-Chlorotoluene g/L0.50 10.0 2570-13092.0 2.269.20
4-Chlorotoluene g/L0.50 10.0 2570-130102 1.2710.2
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B252860 - SW-846 5030B
LCS Dup (B252860-BSD1) Prepared & Analyzed: 02/24/20
1,2-Dibromoethane (EDB)g/L0.50 10.0 2570-13088.2 6.268.82
1,2-Dichlorobenzene g/L0.50 10.0 2570-13098.0 1.729.80
1,3-Dichlorobenzene g/L0.50 10.0 2570-13099.4 0.4029.94
1,4-Dichlorobenzene g/L0.50 10.0 2570-13099.8 1.209.98
Dichlorodifluoromethane (Freon 12)g/L0.50 10.0 2560-14062.7 3.916.27
1,1-Dichloroethane g/L0.50 10.0 2570-13084.6 0.8248.46
1,2-Dichloroethane g/L0.50 10.0 2570-13091.7 2.699.17
1,1-Dichloroethylene g/L0.50 10.0 2570-13085.6 2.548.56
cis-1,2-Dichloroethylene g/L0.50 10.0 2570-13086.7 2.738.67
trans-1,2-Dichloroethylene g/L0.50 10.0 2570-13083.8 2.248.38
1,2-Dichloropropane g/L0.50 10.0 2570-13092.8 2.669.28
1,3-Dichloropropane g/L0.50 10.0 2570-13090.8 5.259.08
2,2-Dichloropropane g/L0.50 10.0 2570-13082.1 1.338.21
1,1-Dichloropropene g/L0.50 10.0 2570-13084.9 2.218.49
cis-1,3-Dichloropropene g/L0.50 10.0 2570-13093.0 4.009.30
trans-1,3-Dichloropropene g/L0.50 10.0 2570-13087.8 5.868.78
Diisopropyl Ether (DIPE)g/L0.50 10.0 2570-13093.0 3.699.30
Ethylbenzene g/L0.50 10.0 2570-130100 3.3410.0
2-Hexanone (MBK)g/L5.0 100 2570-13093.4 6.7293.4
Isopropylbenzene (Cumene)g/L0.50 10.0 2570-130104 3.0210.4
p-Isopropyltoluene (p-Cymene)g/L0.50 10.0 2570-130101 1.2010.1
Methyl tert-Butyl Ether (MTBE)g/L0.50 10.0 25 L-0470-13059.6 12.0*5.96
Methylene Chloride g/L5.0 10.0 2570-13088.6 4.858.86
4-Methyl-2-pentanone (MIBK)g/L5.0 100 2570-13095.2 8.8995.2
Naphthalene g/L0.50 10.0 2570-13094.2 1.289.42
n-Propylbenzene g/L0.50 10.0 2570-130104 0.28910.4
Styrene g/L0.50 10.0 2570-130101 0.59510.1
1,1,2,2-Tetrachloroethane g/L0.50 10.0 2570-13094.7 4.349.47
Tetrachloroethylene g/L0.50 10.0 2570-13097.3 3.839.73
Toluene g/L0.50 10.0 2570-13092.4 2.469.24
1,2,3-Trichlorobenzene g/L1.0 10.0 2570-13098.9 2.469.89
1,2,4-Trichlorobenzene g/L0.50 10.0 2570-130101 4.7810.1
1,1,1-Trichloroethane g/L0.50 10.0 2570-13091.4 2.169.14
1,1,2-Trichloroethane g/L0.50 10.0 2570-13088.2 4.548.82
Trichloroethylene g/L0.50 10.0 2570-13089.1 2.888.91
Trichlorofluoromethane (Freon 11)g/L0.50 10.0 2570-13085.3 3.918.53
1,2,3-Trichloropropane g/L0.50 10.0 2570-13093.5 0.4279.35
1,2,4-Trimethylbenzene g/L0.50 10.0 2570-13096.2 1.859.62
1,3,5-Trimethylbenzene g/L0.50 10.0 2570-130101 2.0610.1
Vinyl Acetate g/L20 100 2570-13074.8 4.2874.8
Vinyl Chloride g/L0.50 10.0 25 L-0260-140170 1.54*17.0
m+p Xylene g/L1.0 20.0 2570-130101 1.2720.3
o-Xylene g/L0.50 10.0 2570-130104 1.1510.4
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 91.622.9
g/L 25.0 70-130Surrogate: Toluene-d8 97.624.4
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 98.524.6
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
*QC result is outside of established limits.
Wide recovery limits established for difficult compound.
Wide RPD limits established for difficult compound.
#Data exceeded client recommended or regulatory level
Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the
calculation which have not been rounded.
No results have been blank subtracted unless specified in the case narrative section.
FLAG/QUALIFIER SUMMARY
Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated
concentration (CLP J-Flag).
J
Laboratory fortified blank/laboratory control sample recovery and duplicate recoveries outside of control limits.
Data validation is not affected since all results are "not detected" for associated samples in this batch and bias is
on the high side.
L-02
Laboratory fortified blank/laboratory control sample recovery and duplicate recovery are outside of control limits.
Reported value for this compound is likely to be biased on the low side.
L-04
Either laboratory fortified blank/laboratory control sample or duplicate recovery is outside of control limits, but
the other is within limits. RPD between the two LFB/LCS results is within method specified criteria.
L-07
Elevated reporting limit due to high concentration of target compounds.RL-11
[TOC_1]Flag/Qualifier Summary[TOC]
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SM21-22 6200B in Water
NCAcetone
NCBenzene
NCBromobenzene
NCBromochloromethane
NCBromodichloromethane
NCBromoform
NCBromomethane
NC2-Butanone (MEK)
NCn-Butylbenzene
NCsec-Butylbenzene
NCtert-Butylbenzene
NCCarbon Tetrachloride
NCChlorobenzene
NCEthanol
NCChlorodibromomethane
NCChloroethane
NCChloroform
NCChloromethane
NC2-Chlorotoluene
NC4-Chlorotoluene
NC1,2-Dibromoethane (EDB)
NC1,2-Dichlorobenzene
NC1,3-Dichlorobenzene
NC1,4-Dichlorobenzene
NCDichlorodifluoromethane (Freon 12)
NC1,1-Dichloroethane
NC1,2-Dichloroethane
NC1,1-Dichloroethylene
NCcis-1,2-Dichloroethylene
NCtrans-1,2-Dichloroethylene
NC1,2-Dichloropropane
NC1,3-Dichloropropane
NC2,2-Dichloropropane
NC1,1-Dichloropropene
NCcis-1,3-Dichloropropene
NCtrans-1,3-Dichloropropene
NCDiisopropyl Ether (DIPE)
NCEthylbenzene
NC2-Hexanone (MBK)
NCIsopropylbenzene (Cumene)
NCp-Isopropyltoluene (p-Cymene)
NCMethyl tert-Butyl Ether (MTBE)
NCMethylene Chloride
NC4-Methyl-2-pentanone (MIBK)
NCNaphthalene
NCn-Propylbenzene
NCStyrene
[TOC_1]Certifications[TOC]
Page 40 of 45
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SM21-22 6200B in Water
NC1,1,2,2-Tetrachloroethane
NCTetrachloroethylene
NCToluene
NC1,2,3-Trichlorobenzene
NC1,2,4-Trichlorobenzene
NC1,1,1-Trichloroethane
NC1,1,2-Trichloroethane
NCTrichloroethylene
NCTrichlorofluoromethane (Freon 11)
NC1,2,3-Trichloropropane
NC1,2,4-Trimethylbenzene
NC1,3,5-Trimethylbenzene
NCVinyl Acetate
NCVinyl Chloride
NCm+p Xylene
NCo-Xylene
The CON-TEST Environmental Laboratory operates under the following certifications and accreditations:
Code Description Number Expires
100033AIHA-LAP, LLC - ISO17025:2017AIHA 03/1/2022
M-MA100Massachusetts DEPMA 06/30/2020
PH-0567Connecticut Department of Publilc HealthCT 09/30/2021
10899 NELAPNew York State Department of HealthNY 04/1/2020
2516 NELAPNew Hampshire Environmental LabNH-S 02/5/2021
LAO00112Rhode Island Department of HealthRI 12/30/2020
652North Carolina Div. of Water QualityNC 12/31/2020
MA007 NELAPNew Jersey DEPNJ 06/30/2020
E871027 NELAPFlorida Department of HealthFL 06/30/2020
LL015036Vermont Department of Health Lead LaboratoryVT 07/30/2020
2011028State of MaineME 06/9/2021
460217Commonwealth of VirginiaVA 12/14/2020
2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2020
VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2020
25703North Carolina Department of HealthNC-DW 07/31/2020
68-05812Commonwealth of Pennsylvania DEPPA 06/30/2020
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