RA-748_5392_CA_RPTS_20200220

2725 E. Millbrook Road., Suite 121
Raleigh, North Carolina 27604
Telephone [phone]
Fax [phone]
www.atcgroupservices.com

1

February 20, 2020

Ms. Linda Blalock
North Carolina Department of Environmental Quality
Division of Waste Management – Underground Storage Tank Section
1646 Mail Service Center
Raleigh, North Carolina 27699

Re: Water Supply Well Sampling Letter Report
Selma Perkinson Property
1825 US Highway 1 North
Wise, Warren County, North Carolina
NCDEQ Incident # 5392
ATC Project No. SLP0539207

Dear Ms. Blalock:

ATC Associates of North Carolina, P.C. (ATC) is pleased to submit the results of a water supply well
sampling event conducted on November 13, 2019, for the former Selma Perkinson Property located at
1825 US Highway 1 North in Wise, North Carolina. A site topographic map is included as Figure 1.
Currently on-site is a single-story building used as a sweepstakes center. A site map is included as
Figure 2. Previous assessment activities have indicated concentrations of 1,2-dibromoethane (EDB)
and 1,2-dichloropropane in water supply wells in the site vicinity. Water supply well locations are
shown on Figure 3.

The sampling event was performed based on an October 17, 2019, Task Authorization (TA-7) by the
Trust Fund Branch of the Underground Storage Tank (UST) Section, Division of Waste Management,
North Carolina Department of Environmental Quality (NCDEQ). The work is being performed as
part of State Lead Contract #N17004 between NCDEQ and ATC.

ATC mobilized to the site on November 13, 2019, to collect samples from water supply wells WSW-
7 and WSW-12. The samples were collected in laboratory-supplied, preserved containers; entered
into chain of custody control; placed on ice; and shipped to North Carolina-accredited SGS North
America Inc. (SGS) in Scott, Louisiana. The samples were analyzed for volatile organic compounds
by EPA Method 6200B. Based on the results, 1,2-dichloropropane was detected above North
Carolina Groundwater Quality Standards (2L Standards) in WSW-7. Chloroform, methyl-tertiary
butyl ether (MTBE), and total xylene were detected in WSW-7 at concentrations below their
respective 2L Standards. No compounds were detected in WSW-12. Water supply well information
is included as Table 1. Current and historical water supply well analytical results are included on
Table 2. Field notes from the sampling event are included as Appendix A. The laboratory analytical
report is included in Appendix B.

Water Supply Well Sampling Letter Report February 20, 2020
Selma Perkinson Property – Incident # 5392 ATC Project Number SLP0539207
2

ATC contacted the owner of water supply well WSW-7 regarding connecting to the municipal water
supply and abandoning their water supply well. The owner of WSW-7 contacted ATC by telephone
and indicated he was not interested in abandoning his well.

Based on the analytical results, groundwater concentrations above 2L standards continue to impact
water supply wells located in the vicinity of the site. ATC recommends quarterly sampling of water
supply wells in the area.

If you have any questions or require additional information, please contact our office at (919) 871-
0999.

Sincerely,

ATC Associates of North Carolina, P.C.

Elizabeth A. Allyn Ashley M. Winkelman, P.G.
Project Manager Senior Project Manager

TABLES

TABLE 1
WATER SUPPLY WELL INFORMATION

FORMER SELMA PERKINSON PROPERTY
1825 U.S. HIGHWAY 1 NORTH
WISE, WARREN COUNTY, NORTH CAROLINA
INCIDENT #5392
Water Supply
Well Property Owner(s)Property Address Distance from Source (feet)Connected to Municipal
Water Usage
WSW-1
Awad Steven LLC
1865 US Highway 1N
Wise, NC 27563
Phone number not available
1826 US Highway 1 N 215 Yes Unknown
WSW-2
Luther Paynter
PO Box 142
Wise, NC 27594
Phone number not available
1825 US Highway 1 N 90 No Drinking
WSW-3
William and Tommie Thompson
1807 US Highwy 1 N
Wise, NC 27563
Phone number not available
1807 US Highway 1 N
(also supplies water to 1799
US Highway 1 N)
430 No Drinking
WSW-4
Joyce Leonard
112 Carries Dunn Road
Norlina, NC 27563
Phone number not available
112 Carrie Dunn Road 570 No Drinking (assumed)
WSW-5
Harriet Daniel
1815 US Highway 1 N
Wise, NC 27563
Phone number not available
1815 US Highway 1 N 240 Yes Unknown
WSW-6
Richard Thompson, Jr.
PO Box 515
Norlina, NC 27563
Phone number not available
1799 US Highway 1 N
590
Property supplied water from
WSW-3
No Inactive
WSW-7
Wilson and Judy Poteat
PO Box 41
Wise, NC 27594
Phone number not available
1791 US Highway 1 N 750 No Drinking (assumed)
WSW-8
F.R. and Nancy Gustkey
120 Carries Dunn Road
Norlinga, NC 27563
Phone number not available
120 Carrie Dunn Road 820 No Drinking (assumed)
WSW-9
Ashraf Lamy
PO Box 1001
Norlina, NC 27563
Phone number not available
1865 US Highway 1 N 725 No Drinking (assumed)
WSW-10
John and Phyllis Hatcher
113 Carrie Dunn Road
Norlina, NC 27563
Phone number not available
113 Carrie Dunn Road 450 Yes Unknown
WSW-11
Davis and Rebecca Parham
1847 US Highway 1 N
Norlina, NC 27563
252-432-9779
1847 US Highway 1 N 450 No Drinking
WSW-12
Sheryl P. Noles
1785 US Highway 1 N
Norlina, NC 27563
Phone number not available
1785 US Highway 1 N 890 No Drinking (assumed)
WSW-13
Elizabeth Sherbert & Others
1409 Hardimont Road, Apt 3
Raleigh, NC 27609
Phone number not available
1853 US Highway 1 N 850 No Drinking (assumed)
WSW-14
Alice and Thomas Phillips
110 Old Wise School Ext.
Warrenton, NC 27589
Phone number not available
110 Old Wise School Ext.745 No Drinking (assumed)
WSW-15
Ashley White & Others
807 Rooker Dairy Court
Norlina, NC 27563
252-213-0336
1804 US Highway 1 N 670 Yes Inactive
WSW-16
Myranda Carroll and CK Patel
1873 US Highway 1 N
Norlina, NC 27563
Phone number not available
1873 US Highway 1 N 920 Yes Inactive
WSW-17 580 Yes Unknown
WSW-18 400 Yes Unknown
1. Only water supply wells within 1,000 feet are included on this table.
Wise Baptist Church
PO Box 38
Wise, NC 27594
252-456-3898
1840 US Highway 1 N
Notes:
2. Ownership information updated November 21, 2019 using Warren County, NC GIS website.
Page 1 of 1
TABLE 2
WATER SUPPLY WELL ANALYTICAL DATA

FORMER SELMA PERKINSON PROPERTY
1825 U.S. HIGHWAY 1 NORTH
WISE, WARREN COUNTY, NORTH CAROLINA
INCIDENT #5392
504.1
1,2-Dichloropropane1,2-DibromoethaneChloroformMTBE1,2,3-Trichloropropane1,2,4-Trimethylbenzene1,2-Dibromoethane6/21/2004 ------------2.2
11/10/2005 ------------1.18
6/21/2004 ------------<0.019
11/10/2005 ------------<0.019
7/19/2016 ------------0.021
11/14/2016 <0.5 <0.5 <0.5 <0.50 <1.0 <0.50 0.047
3/20/2018 <0.20 <0.10 <0.50 <0.50 <0.10 <0.50 0.069
2/18/2019 <0.30 <0.50 <0.50 <0.50 <0.50 0.67 NA
6/21/2004 ------------0.69
11/10/2005 ------------0.383
7/19/2015 ------------0.35
5/4/2016 1.1 ----------0.54
11/14/2016 1.0 0.40 J <0.5 <0.50 <1.0 <1.0 0.55
6/21/2004 ------------<0.019
11/10/2005 ------------<0.019
WSW-5 11/10/2005 ------------<0.019
WSW-6 11/10/2005 ------------2.7
11/10/2005 ------------0.318
2/18/2019 2.2 0.73 <0.50 <0.50 <0.50 <0.50 NA
5/1/2019 1.7 <0.50 0.89 15.0 <0.50 <0.50 NA
8/12/2019 1.4 <0.50 0.60 15.6 <0.50 <0.50 NA
11/13/2019 1.3 <0.50 0.57 11.1 <0.50 <0.50 NA
WSW-8 11/10/2005 ------------0.034
WSW-9 11/10/2005 ------------<0.019
4/22/1992 ------------<5
1/19/1999 ------------ND
April 1999 ------------ND
July 1999 ------------ND
February 2000 ------------ND
5/15/2015 ------------NA
11/14/2016*<0.5 <0.5 0.77 <0.50 <1.0 <0.50 <0.022
3/20/2018 <0.20 <0.10 0.70 <0.50 0.15 <0.50 <0.021
2/18/2019 <0.30 <0.50 <0.50 <0.50 <0.50 <0.50 NA
WSW-12 11/13/2019 <0.30 <0.50 <0.50 <0.50 <0.50 <0.50 NA
0.6 0.02 70 20 0.005 400 0.02
600 50 70,000 20,000 NE 28,500 50
Notes:
1. "<" = Not detected at or above the laboratory detection limit or reporting limit
2. Concentrations are reported in micrograms per liter (ug/l) = parts per billion (ppb)
4. GCL = Gross Contamination Level
5. ND = Not Detected
6. NA = Not Analyzed
7. * = Sample is labeled 1843 US 1 N in associated laboratory report
8. -- = Not reported in historical reports
3. Concentrations highlighted and in bold print equal or exceed the NCDEQ 15A 2L NCAC Groundwater Standard (2L Standard).
2L GW Standard
GCL
Water Supply
Well Date
WSW-1
WSW-2
WSW-4
WSW-10
WSW-3
6200B
WSW-11
WSW-7

FIGURES

2725 E. Millbrook Road, Suite 121Raleigh, NC 27604(919) 871-0999
FIGURE 1
SITE TOPOGRAPHIC MAP
PROJECT NO: SLP0539204
REVIEWED BY: AW SCALE: 1” = 840’DATE: 5/27/16
SELMA PERKINSON PROPERTY–INCIDENT #5392
1825 U.S. HIGHWAY 1 NORTH
WISE, NORTH CAROLINA
Source: My Free Topo
N
Site
2725 E. Millbrook Road, Suite 121Raleigh, NC 27604(919) 871-0999
FIGURE 3
POTENTIAL RECEPTOR SURVEY MAP
PROJECT NO: SLP0539205
REVIEWED BY: AW SCALE: 1” = 300’DATE: 5/27/16
SELMA PERKINSON PROPERTY–INCIDENT #5392
1825 U.S. HIGHWAY 1 NORTH
WISE, NORTH CAROLINA
Source: Warren County NC GIS
Potable Water Supply Well
Inactive Water Supply Well
Water supply well with an Unknown Use –Property Connected to Municipal Water
500 Foot Radius
1,000 Foot Radius
Note: Only water supply wells located within 1,000 feet of the site are shown on the figure.
Site
WSW-2
WSW-3
WSW-7
WSW-12
WSW-8
WSW-9
WSW-14
WSW-6
WSW-15
WSW-1
WSW-5
WSW-17
N
WSW-4
WSW-11
WSW-10
WSW-16
WSW-13
WSW-18

APPENDIX A

FIELD NOTES

APPENDIX B

LABORATORY ANALYTICAL REPORT

11/21/19
Technical Report for
ATC Group Services LLC
Selma Perkinson 1825 US Hwy 1 N, Wise, NC
SLP0539207
SGS Job Number: LA59401
Sampling Date: 11/13/19
Report to:
ATC Group Services LLC.
2725 East Millbrook Road Suite 121
Raleigh, NC 27604
[e-mail]
ATTN: Ashley Winkelman
Total number of pages in report:
Certifications: LDEQ(2048), LDHH(LA150012), AR(14-045-04), AZ(AZ0805), FL(E87657), IL(200082), KY(#31),
NC(487), SC(73004001), NJ(LA007), TX(T104704186-18-16), WV(257)
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 500 Ambassador Caffery • Scott, LA 70583 • tel: [phone]
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Amy Jackson 337-237-4775
Ron Benjamin
Lab Director
Scott, LA 11/21/19
e-Hardcopy 2.0
Automated Report
25
SGS is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions
The results set forth herein are provided by SGS North America Inc.
Please share your ideas about
how we can serve you better at:
[e-mail]
1 of 25
LA59401
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................5
3.1: LA59401-1: WSW-7 .....................................................................................................6
3.2: LA59401-2: WSW-12 ...................................................................................................9
Section 4: Misc. Forms ............................................................................................................12
4.1: Chain of Custody ...........................................................................................................13
Section 5: MS Volatiles - QC Data Summaries .....................................................................16
5.1: Method Blank Summary ................................................................................................17
5.2: Blank Spike/Blank Spike Duplicate Summary ..............................................................20
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................23 123452 of 25
LA59401
SGS North America Inc.
Sample Summary
ATC Group Services LLC
Job No:LA59401
Selma Perkinson 1825 US Hwy 1 N, Wise, NC
Project No: SLP0539207
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
This report contains results reported as ND = Not detected. The following applies:
Organics ND = Not detected above the RL
LA59401-1 11/13/19 10:25 BB 11/15/19 AQ Water WSW-7
LA59401-2 11/13/19 10:50 BB 11/15/19 AQ Water WSW-12
3 of 25
LA594011
Summary of Hits Page 1 of 1
Job Number:LA59401
Account:ATC Group Services LLC
Project:Selma Perkinson 1825 US Hwy 1 N, Wise, NC
Collected:11/13/19
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
LA59401-1 WSW-7
Chloroform 0.57 0.50 ug/l SM 6200B
1,2-Dichloropropane 1.3 0.30 ug/l SM 6200B
Methyl Tert Butyl Ether 11.1 0.50 ug/l SM 6200B
Xylene (total)0.69 0.50 ug/l SM 6200B
LA59401-2 WSW-12
No hits reported in this sample.
4 of 25
LA594012
SGS North America Inc.
Sample Results
Report of Analysis
Scott, LA
Section 3
5 of 25
LA594013
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:WSW-7
Lab Sample ID:LA59401-1 Date Sampled:11/13/19
Matrix:AQ - Water Date Received:11/15/19
Method:SM 6200B Percent Solids:n/a
Project:Selma Perkinson 1825 US Hwy 1 N, Wise, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 2K0119849.D 1 11/20/19 05:02 CP n/a n/a V2K2171
Run #2
Purge Volume
Run #1 25.0 ml
Run #2
VOA Special List
CAS No.Compound Result RL Units Q
67-64-1 Acetone ND 10 ug/l
71-43-2 Benzene ND 0.50 ug/l
108-86-1 Bromobenzene ND 0.50 ug/l
74-97-5 Bromochloromethane ND 0.50 ug/l
75-27-4 Bromodichloromethane ND 0.50 ug/l
75-25-2 Bromoform ND 0.50 ug/l
104-51-8 n-Butylbenzene ND 0.50 ug/l
135-98-8 sec-Butylbenzene ND 0.50 ug/l
98-06-6 tert-Butylbenzene ND 0.50 ug/l
56-23-5 Carbon Tetrachloride ND 0.20 ug/l
108-90-7 Chlorobenzene ND 0.50 ug/l
75-00-3 Chloroethane ND 0.50 ug/l
67-66-3 Chloroform 0.57 0.50 ug/l
95-49-8 o-Chlorotoluene ND 0.50 ug/l
106-43-4 p-Chlorotoluene ND 0.50 ug/l
124-48-1 Dibromochloromethane ND 0.20 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 ug/l
541-73-1 m-Dichlorobenzene ND 0.50 ug/l
95-50-1 o-Dichlorobenzene ND 0.50 ug/l
106-46-7 p-Dichlorobenzene ND 0.50 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 ug/l
107-06-2 1,2-Dichloroethane ND 0.20 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 ug/l
78-87-5 1,2-Dichloropropane 1.3 0.30 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.20 ug/l
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 of 25
LA5940133.1
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:WSW-7
Lab Sample ID:LA59401-1 Date Sampled:11/13/19
Matrix:AQ - Water Date Received:11/15/19
Method:SM 6200B Percent Solids:n/a
Project:Selma Perkinson 1825 US Hwy 1 N, Wise, NC
VOA Special List
CAS No.Compound Result RL Units Q
10061-02-6 trans-1,3-Dichloropropene ND 0.20 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 ug/l
64-17-5 Ethyl Alcohol ND 50 ug/l
100-41-4 Ethylbenzene ND 0.50 ug/l
591-78-6 2-Hexanone ND 1.0 ug/l
87-68-3 Hexachlorobutadiene ND 0.20 ug/l
98-82-8 Isopropylbenzene ND 0.50 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 ug/l
74-83-9 Methyl Bromide ND 0.50 ug/l
74-87-3 Methyl Chloride ND 0.50 ug/l
74-95-3 Methylene Bromide ND 0.50 ug/l
75-09-2 Methylene Chloride ND 0.50 ug/l
78-93-3 Methyl Ethyl Ketone ND 25 ug/l
108-10-1 4-Methyl-2-pentanone ND 0.50 ug/l
1634-04-4 Methyl Tert Butyl Ether 11.1 0.50 ug/l
91-20-3 Naphthalene ND 0.50 ug/l
103-65-1 n-Propylbenzene ND 0.50 ug/l
100-42-5 Styrene ND 0.50 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.20 ug/l
127-18-4 Tetrachloroethylene ND 0.50 ug/l
108-88-3 Toluene ND 0.50 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.30 ug/l
79-01-6 Trichloroethylene ND 0.50 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 ug/l
108-05-4 Vinyl Acetate ND 0.50 ug/l
75-01-4 Vinyl Chloride ND 0.10 ug/l
m,p-Xylene ND 1.0 ug/l
95-47-6 o-Xylene ND 0.50 ug/l
1330-20-7 Xylene (total)0.69 0.50 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 99%70-130%
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
7 of 25
LA5940133.1
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:WSW-7
Lab Sample ID:LA59401-1 Date Sampled:11/13/19
Matrix:AQ - Water Date Received:11/15/19
Method:SM 6200B Percent Solids:n/a
Project:Selma Perkinson 1825 US Hwy 1 N, Wise, NC
VOA Special List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
2037-26-5 Toluene-D8 94%70-130%
460-00-4 4-Bromofluorobenzene 90%70-130%
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
8 of 25
LA5940133.1
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:WSW-12
Lab Sample ID:LA59401-2 Date Sampled:11/13/19
Matrix:AQ - Water Date Received:11/15/19
Method:SM 6200B Percent Solids:n/a
Project:Selma Perkinson 1825 US Hwy 1 N, Wise, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 2K0119850.D 1 11/20/19 05:33 CP n/a n/a V2K2171
Run #2
Purge Volume
Run #1 25.0 ml
Run #2
VOA Special List
CAS No.Compound Result RL Units Q
67-64-1 Acetone ND 10 ug/l
71-43-2 Benzene ND 0.50 ug/l
108-86-1 Bromobenzene ND 0.50 ug/l
74-97-5 Bromochloromethane ND 0.50 ug/l
75-27-4 Bromodichloromethane ND 0.50 ug/l
75-25-2 Bromoform ND 0.50 ug/l
104-51-8 n-Butylbenzene ND 0.50 ug/l
135-98-8 sec-Butylbenzene ND 0.50 ug/l
98-06-6 tert-Butylbenzene ND 0.50 ug/l
56-23-5 Carbon Tetrachloride ND 0.20 ug/l
108-90-7 Chlorobenzene ND 0.50 ug/l
75-00-3 Chloroethane ND 0.50 ug/l
67-66-3 Chloroform ND 0.50 ug/l
95-49-8 o-Chlorotoluene ND 0.50 ug/l
106-43-4 p-Chlorotoluene ND 0.50 ug/l
124-48-1 Dibromochloromethane ND 0.20 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 ug/l
541-73-1 m-Dichlorobenzene ND 0.50 ug/l
95-50-1 o-Dichlorobenzene ND 0.50 ug/l
106-46-7 p-Dichlorobenzene ND 0.50 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 ug/l
107-06-2 1,2-Dichloroethane ND 0.20 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 ug/l
78-87-5 1,2-Dichloropropane ND 0.30 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.20 ug/l
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
9 of 25
LA5940133.2
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:WSW-12
Lab Sample ID:LA59401-2 Date Sampled:11/13/19
Matrix:AQ - Water Date Received:11/15/19
Method:SM 6200B Percent Solids:n/a
Project:Selma Perkinson 1825 US Hwy 1 N, Wise, NC
VOA Special List
CAS No.Compound Result RL Units Q
10061-02-6 trans-1,3-Dichloropropene ND 0.20 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 ug/l
64-17-5 Ethyl Alcohol ND 50 ug/l
100-41-4 Ethylbenzene ND 0.50 ug/l
591-78-6 2-Hexanone ND 1.0 ug/l
87-68-3 Hexachlorobutadiene ND 0.20 ug/l
98-82-8 Isopropylbenzene ND 0.50 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 ug/l
74-83-9 Methyl Bromide ND 0.50 ug/l
74-87-3 Methyl Chloride ND 0.50 ug/l
74-95-3 Methylene Bromide ND 0.50 ug/l
75-09-2 Methylene Chloride ND 0.50 ug/l
78-93-3 Methyl Ethyl Ketone ND 25 ug/l
108-10-1 4-Methyl-2-pentanone ND 0.50 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 ug/l
91-20-3 Naphthalene ND 0.50 ug/l
103-65-1 n-Propylbenzene ND 0.50 ug/l
100-42-5 Styrene ND 0.50 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.20 ug/l
127-18-4 Tetrachloroethylene ND 0.50 ug/l
108-88-3 Toluene ND 0.50 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.30 ug/l
79-01-6 Trichloroethylene ND 0.50 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 ug/l
108-05-4 Vinyl Acetate ND 0.50 ug/l
75-01-4 Vinyl Chloride ND 0.10 ug/l
m,p-Xylene ND 1.0 ug/l
95-47-6 o-Xylene ND 0.50 ug/l
1330-20-7 Xylene (total)ND 0.50 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 98%70-130%
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
10 of 25
LA5940133.2
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:WSW-12
Lab Sample ID:LA59401-2 Date Sampled:11/13/19
Matrix:AQ - Water Date Received:11/15/19
Method:SM 6200B Percent Solids:n/a
Project:Selma Perkinson 1825 US Hwy 1 N, Wise, NC
VOA Special List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
2037-26-5 Toluene-D8 93%70-130%
460-00-4 4-Bromofluorobenzene 87%70-130%
ND = Not detected J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
11 of 25
LA5940133.2
SGS North America Inc.
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Scott, LA
Section 4
12 of 25
LA594014
LA59401: Chain of Custody
Page 1 of 3
13 of 25
LA5940144.1
LA59401: Chain of Custody
Page 2 of 3
14 of 25
LA5940144.1
SGS Sample Receipt Summary
Job Number:LA59401 Client:ATC
Date / Time Received:11/15/2019 8:30:00 AM Delivery Method:FedEx
Project:FORMER SELMA PERKINSON
4. No. Coolers:1
Airbill #'s:4920 8690 9251
Cooler Security
1. Custody Seals Present:
Y or N
2. Custody Seals Intact:
3. COC Present:
4. Smpl Dates/Time OK
2. Thermometer ID:
Cooler Temperature Y or N
1. Temp criteria achieved:
3. Cooler media:
DV439;
Ice (direct contact)
Quality Control Preservation Y or N N/A
1. Trip Blank present / cooler:
2. Trip Blank listed on COC:
3. Samples preserved properly:
4. VOCs headspace free:
Sample Integrity - Documentation Y or N
1. Sample labels present on bottles:
2. Container labeling complete:
3. Sample container label / COC agree:
Sample Integrity - Condition Y or N
1. Sample recvd within HT:
3. Condition of sample:
2. All containers accounted for:
Sample Integrity - Instructions
1. Analysis requested is clear:
2. Bottles received for unspecified tests
3. Sufficient volume recvd for analysis:
4. Compositing instructions clear:
5. Filtering instructions clear:
Intact
Y or N
Comments
Y or N N/A
Cooler Temps (Initial/Adjusted):#1: (1.8/1.8); DV439
LA59401: Chain of Custody
Page 3 of 3
15 of 25
LA5940144.1
SGS North America Inc.
MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Scott, LA
Section 5
16 of 25
LA594015
Method Blank Summary Page 1 of 3
Job Number:LA59401
Account:ATCNCR ATC Group Services LLC
Project:Selma Perkinson 1825 US Hwy 1 N, Wise, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2K2171-MB2 2K0119840.D 1 11/20/19 CP n/a n/a V2K2171
The QC reported here applies to the following samples:Method: SM 6200B
LA59401-1, LA59401-2
CAS No.Compound Result RL Units Q
67-64-1 Acetone ND 10 ug/l
71-43-2 Benzene ND 0.50 ug/l
108-86-1 Bromobenzene ND 0.50 ug/l
74-97-5 Bromochloromethane ND 0.50 ug/l
75-27-4 Bromodichloromethane ND 0.50 ug/l
75-25-2 Bromoform ND 0.50 ug/l
104-51-8 n-Butylbenzene ND 0.50 ug/l
135-98-8 sec-Butylbenzene ND 0.50 ug/l
98-06-6 tert-Butylbenzene ND 0.50 ug/l
56-23-5 Carbon Tetrachloride ND 0.20 ug/l
108-90-7 Chlorobenzene ND 0.50 ug/l
75-00-3 Chloroethane ND 0.50 ug/l
67-66-3 Chloroform ND 0.50 ug/l
95-49-8 o-Chlorotoluene ND 0.50 ug/l
106-43-4 p-Chlorotoluene ND 0.50 ug/l
124-48-1 Dibromochloromethane ND 0.20 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 ug/l
541-73-1 m-Dichlorobenzene ND 0.50 ug/l
95-50-1 o-Dichlorobenzene ND 0.50 ug/l
106-46-7 p-Dichlorobenzene ND 0.50 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 ug/l
107-06-2 1,2-Dichloroethane ND 0.20 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 ug/l
78-87-5 1,2-Dichloropropane ND 0.30 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.20 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.20 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 ug/l
64-17-5 Ethyl Alcohol ND 50 ug/l
100-41-4 Ethylbenzene ND 0.50 ug/l
17 of 25
LA5940155.1.1
Method Blank Summary Page 2 of 3
Job Number:LA59401
Account:ATCNCR ATC Group Services LLC
Project:Selma Perkinson 1825 US Hwy 1 N, Wise, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2K2171-MB2 2K0119840.D 1 11/20/19 CP n/a n/a V2K2171
The QC reported here applies to the following samples:Method: SM 6200B
LA59401-1, LA59401-2
CAS No.Compound Result RL Units Q
591-78-6 2-Hexanone ND 1.0 ug/l
87-68-3 Hexachlorobutadiene 0.33 0.20 ug/l
98-82-8 Isopropylbenzene ND 0.50 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 ug/l
74-83-9 Methyl Bromide ND 0.50 ug/l
74-87-3 Methyl Chloride ND 0.50 ug/l
74-95-3 Methylene Bromide ND 0.50 ug/l
75-09-2 Methylene Chloride ND 0.50 ug/l
78-93-3 Methyl Ethyl Ketone ND 25 ug/l
108-10-1 4-Methyl-2-pentanone ND 0.50 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 ug/l
91-20-3 Naphthalene ND 0.50 ug/l
103-65-1 n-Propylbenzene ND 0.50 ug/l
100-42-5 Styrene ND 0.50 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.20 ug/l
127-18-4 Tetrachloroethylene ND 0.50 ug/l
108-88-3 Toluene ND 0.50 ug/l
87-61-6 1,2,3-Trichlorobenzene 0.39 0.50 ug/l J
120-82-1 1,2,4-Trichlorobenzene 0.30 0.50 ug/l J
71-55-6 1,1,1-Trichloroethane ND 0.50 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.30 ug/l
79-01-6 Trichloroethylene ND 0.50 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 ug/l
108-05-4 Vinyl Acetate ND 0.50 ug/l
75-01-4 Vinyl Chloride ND 0.10 ug/l
m,p-Xylene ND 1.0 ug/l
95-47-6 o-Xylene ND 0.50 ug/l
1330-20-7 Xylene (total)ND 0.50 ug/l
18 of 25
LA5940155.1.1
Method Blank Summary Page 3 of 3
Job Number:LA59401
Account:ATCNCR ATC Group Services LLC
Project:Selma Perkinson 1825 US Hwy 1 N, Wise, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2K2171-MB2 2K0119840.D 1 11/20/19 CP n/a n/a V2K2171
The QC reported here applies to the following samples:Method: SM 6200B
LA59401-1, LA59401-2
CAS No.Surrogate Recoveries Limits
17060-07-0 1,2-Dichloroethane-D4 100%70-130%
2037-26-5 Toluene-D8 93%70-130%
460-00-4 4-Bromofluorobenzene 90%70-130%
19 of 25
LA5940155.1.1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 3
Job Number:LA59401
Account:ATCNCR ATC Group Services LLC
Project:Selma Perkinson 1825 US Hwy 1 N, Wise, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2K2171-BS2 2K0119837.D 1 11/19/19 CP n/a n/a V2K2171
V2K2171-BSD2 2K0119838.D 1 11/19/19 CP n/a n/a V2K2171
The QC reported here applies to the following samples:Method: SM 6200B
LA59401-1, LA59401-2
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
67-64-1 Acetone 50 55.2 110 52.3 105 5 70-130/30
71-43-2 Benzene 20 17.3 87 17.9 90 3 70-130/30
108-86-1 Bromobenzene 20 20.7 104 21.1 106 2 70-130/30
74-97-5 Bromochloromethane 20 20.7 104 19.9 100 4 70-130/30
75-27-4 Bromodichloromethane 20 22.4 112 22.5 113 0 70-130/30
75-25-2 Bromoform 20 18.2 91 18.6 93 2 70-130/30
104-51-8 n-Butylbenzene 20 24.6 123 25.5 128 4 70-130/30
135-98-8 sec-Butylbenzene 20 23.8 119 24.5 123 3 70-130/30
98-06-6 tert-Butylbenzene 20 23.5 118 24.2 121 3 70-130/30
56-23-5 Carbon Tetrachloride 20 23.6 118 22.2 111 6 70-130/30
108-90-7 Chlorobenzene 20 20.5 103 20.9 105 2 70-130/30
75-00-3 Chloroethane 20 22.1 111 20.9 105 6 60-140/30
67-66-3 Chloroform 20 21.8 109 20.6 103 6 70-130/30
95-49-8 o-Chlorotoluene 20 21.7 109 22.6 113 4 70-130/30
106-43-4 p-Chlorotoluene 20 22.8 114 23.1 116 1 70-130/30
124-48-1 Dibromochloromethane 20 19.0 95 19.4 97 2 70-130/30
96-12-8 1,2-Dibromo-3-chloropropane 20 18.7 94 19.5 98 4 70-130/30
106-93-4 1,2-Dibromoethane 20 21.2 106 21.7 109 2 70-130/30
75-71-8 Dichlorodifluoromethane 20 20.5 103 19.1 96 7 60-140/30
541-73-1 m-Dichlorobenzene 20 20.0 100 20.6 103 3 70-130/30
95-50-1 o-Dichlorobenzene 20 20.0 100 20.8 104 4 70-130/30
106-46-7 p-Dichlorobenzene 20 19.7 99 20.3 102 3 70-130/30
75-34-3 1,1-Dichloroethane 20 22.2 111 21.2 106 5 70-130/30
107-06-2 1,2-Dichloroethane 20 19.1 96 19.3 97 1 70-130/30
75-35-4 1,1-Dichloroethylene 20 22.9 115 21.3 107 7 70-130/30
156-59-2 cis-1,2-Dichloroethylene 20 21.9 110 20.7 104 6 70-130/30
156-60-5 trans-1,2-Dichloroethylene 20 23.0 115 21.6 108 6 70-130/30
78-87-5 1,2-Dichloropropane 20 21.3 107 21.4 107 0 70-130/30
142-28-9 1,3-Dichloropropane 20 20.7 104 21.4 107 3 70-130/30
594-20-7 2,2-Dichloropropane 20 26.5 133*24.6 123 7 70-130/30
563-58-6 1,1-Dichloropropene 20 23.3 117 21.9 110 6 70-130/30
10061-01-5 cis-1,3-Dichloropropene 20 19.8 99 20.1 101 2 70-130/30
10061-02-6 trans-1,3-Dichloropropene 20 19.6 98 20.3 102 4 70-130/30
108-20-3 Di-Isopropyl Ether 20 22.9 115 21.8 109 5 70-130/30
64-17-5 Ethyl Alcohol 400 471 118 412 103 13 70-130/30
100-41-4 Ethylbenzene 20 21.5 108 21.9 110 2 70-130/30
* = Outside of Control Limits.
20 of 25
LA5940155.2.1
Blank Spike/Blank Spike Duplicate Summary Page 2 of 3
Job Number:LA59401
Account:ATCNCR ATC Group Services LLC
Project:Selma Perkinson 1825 US Hwy 1 N, Wise, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2K2171-BS2 2K0119837.D 1 11/19/19 CP n/a n/a V2K2171
V2K2171-BSD2 2K0119838.D 1 11/19/19 CP n/a n/a V2K2171
The QC reported here applies to the following samples:Method: SM 6200B
LA59401-1, LA59401-2
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
591-78-6 2-Hexanone 50 52.1 104 52.1 104 0 70-130/30
87-68-3 Hexachlorobutadiene 20 21.4 107 21.8 109 2 70-130/30
98-82-8 Isopropylbenzene 20 20.3 102 20.6 103 1 70-130/30
99-87-6 p-Isopropyltoluene 20 23.3 117 23.9 120 3 70-130/30
74-83-9 Methyl Bromide 20 19.7 99 20.0 100 2 60-140/30
74-87-3 Methyl Chloride 20 21.5 108 20.4 102 5 60-140/30
74-95-3 Methylene Bromide 20 20.5 103 20.8 104 1 70-130/30
75-09-2 Methylene Chloride 20 19.8 99 18.6 93 6 70-130/30
78-93-3 Methyl Ethyl Ketone 50 46.3 93 43.9 88 5 70-130/30
108-10-1 4-Methyl-2-pentanone 50 46.1 92 47.9 96 4 70-130/30
1634-04-4 Methyl Tert Butyl Ether 20 22.1 111 21.3 107 4 70-130/30
91-20-3 Naphthalene 20 18.7 94 19.8 99 6 70-130/30
103-65-1 n-Propylbenzene 20 22.7 114 23.3 117 3 70-130/30
100-42-5 Styrene 20 20.2 101 20.6 103 2 70-130/30
630-20-6 1,1,1,2-Tetrachloroethane 20 22.4 112 22.8 114 2 70-130/30
79-34-5 1,1,2,2-Tetrachloroethane 20 19.2 96 20.0 100 4 70-130/30
127-18-4 Tetrachloroethylene 20 20.1 101 20.3 102 1 70-130/30
108-88-3 Toluene 20 20.3 102 20.7 104 2 70-130/30
87-61-6 1,2,3-Trichlorobenzene 20 22.7 114 23.8 119 5 70-130/30
120-82-1 1,2,4-Trichlorobenzene 20 22.9 115 23.8 119 4 70-130/30
71-55-6 1,1,1-Trichloroethane 20 23.6 118 22.1 111 7 70-130/30
79-00-5 1,1,2-Trichloroethane 20 19.9 100 20.3 102 2 70-130/30
79-01-6 Trichloroethylene 20 21.4 107 21.7 109 1 70-130/30
75-69-4 Trichlorofluoromethane 20 22.1 111 20.6 103 7 60-140/30
96-18-4 1,2,3-Trichloropropane 20 19.4 97 18.4 92 5 70-130/30
95-63-6 1,2,4-Trimethylbenzene 20 23.2 116 23.8 119 3 70-130/30
108-67-8 1,3,5-Trimethylbenzene 20 23.2 116 23.9 120 3 70-130/30
108-05-4 Vinyl Acetate 20 23.5 118 22.4 112 5 70-130/30
75-01-4 Vinyl Chloride 20 22.5 113 21.4 107 5 60-140/30
m,p-Xylene 40 44.7 112 45.5 114 2 70-130/30
95-47-6 o-Xylene 20 23.7 119 24.0 120 1 70-130/30
1330-20-7 Xylene (total)60 68.4 114 69.5 116 2 70-130/30
* = Outside of Control Limits.
21 of 25
LA5940155.2.1
Blank Spike/Blank Spike Duplicate Summary Page 3 of 3
Job Number:LA59401
Account:ATCNCR ATC Group Services LLC
Project:Selma Perkinson 1825 US Hwy 1 N, Wise, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2K2171-BS2 2K0119837.D 1 11/19/19 CP n/a n/a V2K2171
V2K2171-BSD2 2K0119838.D 1 11/19/19 CP n/a n/a V2K2171
The QC reported here applies to the following samples:Method: SM 6200B
LA59401-1, LA59401-2
CAS No.Surrogate Recoveries BSP BSD Limits
17060-07-0 1,2-Dichloroethane-D4 102%96%70-130%
2037-26-5 Toluene-D8 102%101%70-130%
460-00-4 4-Bromofluorobenzene 101%102%70-130%
* = Outside of Control Limits.
22 of 25
LA5940155.2.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 3
Job Number:LA59401
Account:ATCNCR ATC Group Services LLC
Project:Selma Perkinson 1825 US Hwy 1 N, Wise, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
LA59402-3MS 2K0119841.D 20 11/20/19 CP n/a n/a V2K2171
LA59402-3MSD 2K0119842.D 20 11/20/19 CP n/a n/a V2K2171
LA59402-3 2K0119853.D 20 11/20/19 CP n/a n/a V2K2171
The QC reported here applies to the following samples:Method: SM 6200B
LA59401-1, LA59401-2
LA59402-3 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
67-64-1 Acetone ND 1000 611 61*1000 610 61*0 70-130/20
71-43-2 Benzene ND 400 316 79 400 317 79 0 70-130/20
108-86-1 Bromobenzene ND 400 379 95 400 391 98 3 70-130/20
74-97-5 Bromochloromethane ND 400 382 96 400 383 96 0 70-130/20
75-27-4 Bromodichloromethane ND 400 406 102 400 406 102 0 70-130/20
75-25-2 Bromoform ND 400 337 84 400 347 87 3 70-130/20
104-51-8 n-Butylbenzene ND 400 438 110 400 449 112 2 70-130/20
135-98-8 sec-Butylbenzene ND 400 441 110 400 452 113 2 70-130/20
98-06-6 tert-Butylbenzene ND 400 443 111 400 450 113 2 70-130/20
56-23-5 Carbon Tetrachloride ND 400 425 106 400 425 106 0 70-130/20
108-90-7 Chlorobenzene ND 400 380 95 400 386 97 2 70-130/20
75-00-3 Chloroethane ND 400 399 100 400 398 100 0 60-140/20
67-66-3 Chloroform ND 400 383 96 400 387 97 1 70-130/20
95-49-8 o-Chlorotoluene ND 400 411 103 400 418 105 2 70-130/20
106-43-4 p-Chlorotoluene ND 400 423 106 400 429 107 1 70-130/20
124-48-1 Dibromochloromethane ND 400 350 88 400 357 89 2 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 400 339 85 400 351 88 3 70-130/20
106-93-4 1,2-Dibromoethane ND 400 391 98 400 403 101 3 70-130/20
75-71-8 Dichlorodifluoromethane ND 400 305 76 400 276 69 10 60-140/20
541-73-1 m-Dichlorobenzene ND 400 371 93 400 381 95 3 70-130/20
95-50-1 o-Dichlorobenzene ND 400 375 94 400 383 96 2 70-130/20
106-46-7 p-Dichlorobenzene ND 400 368 92 400 376 94 2 70-130/20
75-34-3 1,1-Dichloroethane ND 400 401 100 400 405 101 1 70-130/20
107-06-2 1,2-Dichloroethane ND 400 346 87 400 349 87 1 70-130/20
75-35-4 1,1-Dichloroethylene ND 400 399 100 400 400 100 0 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 400 391 98 400 393 98 1 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 400 411 103 400 409 102 0 70-130/20
78-87-5 1,2-Dichloropropane ND 400 386 97 400 387 97 0 70-130/20
142-28-9 1,3-Dichloropropane ND 400 385 96 400 394 99 2 70-130/20
594-20-7 2,2-Dichloropropane ND 400 417 104 400 421 105 1 70-130/20
563-58-6 1,1-Dichloropropene ND 400 417 104 400 416 104 0 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 400 348 87 400 353 88 1 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 400 353 88 400 364 91 3 70-130/20
108-20-3 Di-Isopropyl Ether 52.2 400 467 104 400 476 106 2 70-130/20
64-17-5 Ethyl Alcohol ND 8000 7220 90 8000 7630 95 6 70-130/20
100-41-4 Ethylbenzene ND 400 399 100 400 405 101 1 70-130/20
* = Outside of Control Limits.
23 of 25
LA5940155.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 3
Job Number:LA59401
Account:ATCNCR ATC Group Services LLC
Project:Selma Perkinson 1825 US Hwy 1 N, Wise, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
LA59402-3MS 2K0119841.D 20 11/20/19 CP n/a n/a V2K2171
LA59402-3MSD 2K0119842.D 20 11/20/19 CP n/a n/a V2K2171
LA59402-3 2K0119853.D 20 11/20/19 CP n/a n/a V2K2171
The QC reported here applies to the following samples:Method: SM 6200B
LA59401-1, LA59401-2
LA59402-3 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
591-78-6 2-Hexanone ND 1000 798 80 1000 845 85 6 70-130/20
87-68-3 Hexachlorobutadiene ND 400 352 88 400 368 92 4 70-130/20
98-82-8 Isopropylbenzene ND 400 373 93 400 380 95 2 70-130/20
99-87-6 p-Isopropyltoluene ND 400 429 107 400 437 109 2 70-130/20
74-83-9 Methyl Bromide ND 400 336 84 400 379 95 12 60-140/20
74-87-3 Methyl Chloride ND 400 361 90 400 369 92 2 60-140/20
74-95-3 Methylene Bromide ND 400 372 93 400 375 94 1 70-130/20
75-09-2 Methylene Chloride 3.2 400 357 88 400 355 88 1 70-130/20
78-93-3 Methyl Ethyl Ketone ND 1000 680 68*1000 711 71 4 70-130/20
108-10-1 4-Methyl-2-pentanone ND 1000 839 84 1000 867 87 3 70-130/20
1634-04-4 Methyl Tert Butyl Ether 1220 400 1720 125 400 1750 133* a 2 70-130/20
91-20-3 Naphthalene 3.7 400 324 80 400 357 88 10 70-130/20
103-65-1 n-Propylbenzene ND 400 425 106 400 430 108 1 70-130/20
100-42-5 Styrene ND 400 370 93 400 379 95 2 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 400 415 104 400 426 107 3 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 400 384 96 400 397 99 3 70-130/20
127-18-4 Tetrachloroethylene ND 400 369 92 400 366 92 1 70-130/20
108-88-3 Toluene ND 400 375 94 400 379 95 1 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 400 385 96 400 418 105 8 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 400 398 100 400 425 106 7 70-130/20
71-55-6 1,1,1-Trichloroethane ND 400 423 106 400 423 106 0 70-130/20
79-00-5 1,1,2-Trichloroethane ND 400 370 93 400 374 94 1 70-130/20
79-01-6 Trichloroethylene ND 400 373 93 400 378 95 1 70-130/20
75-69-4 Trichlorofluoromethane ND 400 395 99 400 376 94 5 60-140/20
96-18-4 1,2,3-Trichloropropane ND 400 367 92 400 380 95 3 70-130/20
95-63-6 1,2,4-Trimethylbenzene 3.7 400 431 107 400 442 110 3 70-130/20
108-67-8 1,3,5-Trimethylbenzene ND 400 432 108 400 440 110 2 70-130/20
108-05-4 Vinyl Acetate ND 400 533 133*400 564 141*6 70-130/20
75-01-4 Vinyl Chloride ND 400 399 100 400 391 98 2 60-140/20
m,p-Xylene ND 800 827 103 800 836 105 1 70-130/20
95-47-6 o-Xylene ND 400 437 109 400 447 112 2 70-130/20
1330-20-7 Xylene (total)4.8 1200 1260 105 1200 1280 106 2 70-130/20
* = Outside of Control Limits.
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LA5940155.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number:LA59401
Account:ATCNCR ATC Group Services LLC
Project:Selma Perkinson 1825 US Hwy 1 N, Wise, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
LA59402-3MS 2K0119841.D 20 11/20/19 CP n/a n/a V2K2171
LA59402-3MSD 2K0119842.D 20 11/20/19 CP n/a n/a V2K2171
LA59402-3 2K0119853.D 20 11/20/19 CP n/a n/a V2K2171
The QC reported here applies to the following samples:Method: SM 6200B
LA59401-1, LA59401-2
CAS No.Surrogate Recoveries MS MSD LA59402-3 Limits
17060-07-0 1,2-Dichloroethane-D4 98%98%99%70-130%
2037-26-5 Toluene-D8 101%101%93%70-130%
460-00-4 4-Bromofluorobenzene 101%102%89%70-130%
(a) Outside control limits due to high level in sample relative to spike amount.
* = Outside of Control Limits.
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LA5940155.3.1