FA-916_17217_CA_MRP_20150804_ECS Final MW Install and GW Sampling Report

9001 Glenwood Avenue, Raleigh, NC 27617 • T: 919-861-9910 • F: 800-327-5832 • www.ecslimited.com
ECS Mid-Atlantic, LLC • ECS Carolinas, LLP • ECS Florida, LLC • ECS Illinois, LLC • ECS Southeast, LLC • ECS Texas, LLP

August 4, 2015

Mr. Mark Petermann
NCDENR, Division of Waste Management, UST Section
1637 Mail Service Center
Raleigh, North Carolina 27699-1637

Reference: Report of Environmental Services – Flowers Store Property
4181 NC Highway 42 East
Clayton, Johnson County, North Carolina
NCDENR Incident: 17217
NCDENR Contract: N14007i-C
ECS Project: 06:21858-A

Dear Mr. Petermann:

As authorized by your acceptance of ECS Carolinas, LLP (ECS) Task Authorization Request #2
(TAR #2) dated January 21, 2015, ECS has completed the Report of Environmental Services for
the above-referenced site. Included in this report is a description of the field activities, the results
obtained, and our conclusions and recommendations. Information regarding the owner of former
underground storage tank (UST), current property owner, contacts, consultant, laboratory, release
information, and latitude and longitude are presented below.

ECS appreciates the opportunity to provide our environmental consulting services to you on this
project. If you have any questions concerning this report or this project, please contact us at (919)
861-9910.

Sincerely,

ECS CAROLINAS, LLP

Jessica Stearns Matthew Gillis
Environmental Scientist Environmental Project Manager

C. Brian Smith, P.G.
Principal Geologist

Report of Environmental Services – Flowers Store Property
4181 NC Highway 42 East
Clayton, Johnson County, North Carolina
NCDENR Incident: 17217
NCDENR Contract: N14007i-C
August 4, 2015

SITE INFORMATION

Date of Report: August 4, 2015

Facility I.D.: Unknown
UST Incident No.: 12704
Site Rank: High
Land Use Category: Vacant – Two Buildings are located on the property

Site Name and Location: Flowers Store Property
4181 NC Highway 42 East
Clayton, Johnson County, North Carolina

Location Method: Google Earth
Latitude and Longitude: 36.651793 North, -78.360938 West
Contacts

Primary Contact: Ms. Jana Guertler
526 Powell Road
Raleigh, North Carolina 27606
[phone]

Consultant: ECS Carolinas, LLP
9001 Glenwood Avenue
Raleigh, North Carolina 27617
[phone]
Attn: Matthew Gillis

Laboratory: Pace Analytical Services, Inc.
9800 Kincey Ave, Suite 100
Huntersville, North Carolina 28078
[phone]
NC Certification No. 12

Report of Environmental Services – Flowers Store Property
4181 NC Highway 42 East
Clayton, Johnson County, North Carolina
NCDENR Incident: 17217
NCDENR Contract: N14007i-C
August 4, 2015

EXECUTIVE SUMMARY

The subject site is known as the Flowers Store Property and is located at 4181 NC Highway 42
East in Clayton, Johnson County, North Carolina. The subject site is further identified by Johnson
County Geographic Information Systems (GIS) Parcel Identification Number (PIN) 168900-92-
5990.

On June 11 and 12, 2015, ECS installed three monitoring wells, collected groundwater samples
from the three existing monitoring wells, and each of the three new monitoring wells. ECS also
collected groundwater samples from two water supply wells. The properties associated with the
three additional water supply wells were unoccupied; therefore groundwater samples were not
collected.

On June 25, 2015 ECS contracted with Bateman Civil Survey to survey the monitoring wells. During
surveying activities, ECS identified bulldozing had occurred near the location of monitoring well
MW-3 and had damaged the well.

Laboratory analysis reported naphthalene at a concentration above its North Carolina 2L
Groundwater Quality Standards (NC2LGWQS) but below its Gross Contamination Level (GCL) in
the groundwater sample collected from monitoring well MW-9.

Laboratory analysis reported bromodichloromethane and dibromochloromethane at concentrations
above their respective NC2LGWQS but below their respective GCLs in the groundwater sample
collected from water supply well WSW-4.

Laboratory analysis reported 1,2-dichloropropane at a concentration above its NC2LGWQS but
below its GCL in the groundwater sample collected from water supply well WSW-5.

Laboratory analysis reported several additional targeted analytes above their respective laboratory
reporting limits but below their NC2LGWQS in the groundwater samples collected from monitoring
wells MW-8 and MW-9 and water supply well WSW-4.

Laboratory analysis did not report targeted analytes at concentrations above the laboratory
reporting limits in the groundwater samples collected from monitoring wells MW-3, MW-5, MW-7,
and MW-10.

ECS recommends conducting one additional groundwater sampling event at the site to confirm
groundwater flow direction and if petroleum constituents above the NC2LGWQS remain in the
groundwater beneath the site. According to previous soil sampling conducted at the site, an
additional soil assessment does not appear necessary at the site. ECS recommends that a copy of
this report be submitted to the current property owner.

Report of Environmental Services – Flowers Store Property
4181 NC Highway 42 East
Clayton, Johnson County, North Carolina
NCDENR Incident: 17217
NCDENR Contract: N14007i-C
August 4, 2015

TABLE OF CONTENTS
SITE HISTORY ............................................................................................................... 1 
FIELD ACTIVITIES ......................................................................................................... 4 
CONCLUSIONS .............................................................................................................. 5 
RECOMMENDATIONS ................................................................................................... 6 

FIGURES

Figure 1 Site Location Map
Figure 2 Site Aerial Map
Figure 3 Monitoring Well Location Map
Figure 4 Groundwater Elevation Map
Figure 5 Groundwater Concentration Map
Figure 6 Naphthalene Isoconcentration Map
Figure 7 Water Supply Well Location Map
TABLES

Table 1 UST Information
Table 2 Well Construction and Groundwater Elevation Details
Table 3 Summary of Current Groundwater Analytical Results
Table 4 Summary of Historical Groundwater Analytical Results
Table 5 Summary of Current and Historical Water Supply Well Analytical Results
Table 6 Summary of Historical Soil Sample Analytical Results
Table 7 Water Supply Well Survey

APPENDICIES

Appendix A Well Construction Records
Appendix B Bateman’s Survey Information
Appendix C Laboratory Analytical Data Sheets and Chain of Custody Records
Appendix D ECS Personnel Field Notes
Appendix E Site Photographs
Report of Environmental Services – Flowers Store Property
4181 NC Highway 42 East
Clayton, Johnson County, North Carolina
NCDENR Incident: TF-17217
NCDENR Contract: N14007i-C
August 4, 2015

1
SITE HISTORY

The Flowers Store Property is located at 4181 NC Highway 42 East in Clayton, Johnson
County, North Carolina (Figures 1 and 2). According to a 1994 UST Closure Report prepared by
Froehling & Robertson Inc. (F&R), the site was formerly utilized as a gasoline station and auto
repair service facility. On August 29, 1994, one 8,000-gallon gasoline UST (UST-1), one 1,000-
gallon kerosene/diesel UST (UST-2), and one 6,000-gallon diesel UST (UST-3), along with
associated piping/equipment were removed by Action Oil Equipment Company. A summary of
the former UST information for the site is included in Table 1. Based on the analytical results of
the soil samples, releases were reported beneath UST-2 and UST-3. The laboratory reported
Total Petroleum Hydrocarbons – Gasoline Range Organics (TPH-GRO) and TPH-Diesel Range
Organics (TPH-DRO) at concentrations above their respective North Carolina Department of
Environment and Natural Resources (NCDENR) UST Section’s Action Level of 10 mg/kg. TPH-
GRO was reported at concentrations ranging from 567 mg/kg to 2,900 mg/kg. TPH-DRO
concentrations ranged from 18.6 mg/kg to 11,100 mg/kg. Contaminated soils were not removed
from the site and groundwater samples were not collected during UST closure activities.

On February 17, 2006, Agra Environmental, Inc. (AGRA) conducted an Initial Site Visit and Site
Receptor Survey. Agra identified one building on the subject site that was used as a repair garage
and was being used for storage. A sump was observed, which possibly was used as an oil/water
separator, near the rear of the garage. Metal debris, including appliances, tanks, and vehicles were
scattered throughout the wooded area along the northern boundary of the subject site. AGRA also
documented that an additional UST (UST-4) was discovered near the southeastern corner of the
subject site. AGRA identified four potential water supply wells within 1,500 feet of the subject site
and a pond located on the adjacent property to the northeast of the site.

A 2006 UST Closure Report, prepared by AGRA, indicates AGRA removed one 1,000-gallon UST
from the southeastern corner of the subject site. AGRA did not observe contaminated soil in the
UST excavation. However, two 55-gallon drums of contaminated soil associated with spillage of
residual sludge from the UST were removed from the subject site. The remaining soils and clean fill
were used to backfill the UST excavation. Soil samples were not collected prior to backfill.

AGRA performed a door-to-door survey of the surrounding area on May 22, 2008. A total of six
water supply wells (WSW-1, WSW-2, WSW-3, WSW-4, WSW-5, and WSW-6) were identified
approximately 525 feet (ft), 525 ft, 1,100 ft, 900 ft, 550 ft, and 1,400 ft from the subject site,
respectively. An interview with the owners of water supply wells WSW-1 and WSW-4, indicated that
both water supply wells were used as a primary drinking water source and the residence was not
connected to the public water supply at that time. An interview with the owners of water supply wells
WSW-2 and WSW-3 indicated that both wells were currently disconnected and the properties were
connected to the public water supply. Additionally, two water supply wells (WSW-5 and WSW-6)
were observed at 160 Motorcycle Road and 270 Motorcycle Road, respectively. The property
owners could not be contacted during the site visit or during follow up interviews. AGRA identified
160 Motorcycle Road as a residential property and 270 Motorcycle Road as Pineville Chapel
Church.

On June 17, 2008, AGRA conducted an Initial Groundwater Site Investigation and collected
groundwater samples from water supply wells WSW-1 and WSW-4. The laboratory reported bis (2-
ethylhexyl) phthalate in water supply well WSW-1 at a concentration above its North Carolina
Report of Environmental Services – Flowers Store Property
4181 NC Highway 42 East
Clayton, Johnson County, North Carolina
NCDENR Incident: TF-17217
NCDENR Contract: N14007i-C
August 4, 2015

2
Department of Environment and Natural Resources 2L Groundwater Quality Standard
(NC2LGWQS) but below its Gross Contamination Level (GCL). However, AGRA stated that bis (2-
ethylhexyl) phthalate is not a petroleum constituent and was believed to be a laboratory
contaminant. Bis (2-ethylhexyl) phthalate was also reported above its laboratory reporting limit but
below its NC2LGWQS in water supply well WSW-4.

On August 28, 2008, Regional Probing Services installed four temporary monitoring wells (TW-1,
TW-2, TW-3 (MW-3), and TW-4) on the subject site using a Geoprobe. The temporary wells were
each installed to a depth of 35 feet below the ground surface (ft. bgs) with a screened interval of 15
linear feet. Soil encountered during the well installations was very tight red clay. Soil samples were
collected during the installation of each temporary monitoring well at depths of 10 ft. and 20 ft. bgs.
The laboratory reported methyl chloride in the soil samples collected from temporary wells TW-3
and TW-4 at concentrations above the Soil-To-Groundwater Maximum Soil Contaminant
Concentration (MSCC) standard of 0.02 milligrams per kilogram (mg/kg). Diethyl phthalate was
reported in the soil samples collected from TW-2 and TW-3. Di-n-butyl phthalate was reported in
soil sample TW-3. Diethyl phthalate and di-n-butyl phthalate do not have an established MSCC
standard.

On September 2, 2008, AGRA personnel collected groundwater samples from temporary wells TW-
1 through TW-4. Temporary well TW-1 was analyzed for volatile organic compounds (VOCs) using
EPA Method 6200B, for semi-volatile organic compounds (SVOCs) using EPA Method 625, and
Massachusetts Department of Environmental Protection Extractable Petroleum Hydrocarbons
(MADEP EPH), MADEP Volatile Petroleum Hydrocarbons (MADEP VPH), and lead using EPA
Method 6010/303C. Groundwater samples were also collected from temporary wells TW-2, TW-3,
and TW 4 to be analyzed for VOCs using EPA Method 6200B and MADEP VPH. The laboratory
reported lead at a concentration of 250 micrograms per liter (µg/L) in the groundwater sample
collected from temporary well TW-1, which exceeds the NC2LGWQS of 15 µg/L. Di-n-butyl
phthalate was detected in temporary well TW-1 at a concentration of 6.68 µg/L; however di-n-butyl
phthalate does not have a NC2LGWQS. The laboratory did not report additional targeted analytes
from the groundwater samples at concentrations exceeding their respective NC2LGWQS.

On February 5, 19, and 25, 2009, Cohesion, Inc. (Cohesion) collected soil samples from numerous
locations at the subject site in an attempt to confirm that contaminated soils remain at the subject
site. Laboratory analysis reported TPH above the Action Level of 10 mg/kg in soil samples collected
near the rear of the garage, adjacent to an old CITGO petroleum tanker that had been discarded in
the rear of the property, and near two hydraulic pumps located inside the garage.

On September 30, 2009, AGRA personnel conducted a soil and groundwater sampling event at the
site. Three soil borings were advanced in the former UST locations (UST-1 to 12 ft bgs, UST-2 to 8
ft bgs, and UST-3 to 10 ft bgs). Additionally, soil borings were advanced adjacent to the previously
installed soil borings B-15 and B-8. Soil samples were collected from B-15 and B-8 at depths of 2 ft
bgs and 8 ft bgs. As part of the sampling event, AGRA personnel attempted to collect groundwater
samples from the four on-site temporary monitoring wells TW-1, TW-2, TW-3, and TW-4. The
temporary wells were previously installed with PVC risers, which extended approximately 1.5 ft
above the ground surface. The aboveground risers of temporary wells TW-1 and TW-2 were broken
and TW-4 was dry. The laboratory reported targeted analytes at the subject site in the soil samples
collected near the former locations of UST-2 and UST-3, as well as adjacent to the discarded tanker
on the rear of the property. However, the analytes reported were below their respective MSCC
Report of Environmental Services – Flowers Store Property
4181 NC Highway 42 East
Clayton, Johnson County, North Carolina
NCDENR Incident: TF-17217
NCDENR Contract: N14007i-C
August 4, 2015

3
standards or did not have established MSCC standards. The laboratory reported tetrachloroethene
at concentrations of 0.89 µg/L and 0.71 µg/L in the groundwater samples collected from TW-1 and
TW-2, respectively, which were above the NC2LGWQS of 0.70 µg/L. Temporary well TW-4 was
not sampled. However, targeted analytes were not reported in TW-4 during the sampling event
performed on September 2, 2008. Additionally, 1,2-dichloropropane was reported at a
concentration of 0.51 µg/L in water supply well WSW-5, which is below the NC2LGWQS of 0.60
µg/L.

On October 4, 2012, Crawford Environmental Services (CES) conducted a groundwater monitoring
event at the subject site. Temporary monitoring wells TW-1, TW-2, and TW-4 were not located and
were presumed destroyed. CES observed six water supply wells within 1,500 feet of the subject
site (WSW-1 through WSW-6). Based on discussions with the property owner, the home associated
with water supply well WSW-1 had been connected to municipal water and the well had been
abandoned. The properties utilizing water supply wells WSW-2 and WSW-3 were also connected
to municipal water. Water supply wells WSW-4 through WSW-6 were still actively used as a water
supply source. CES collected a groundwater sample from temporary well TW-3 and the laboratory
did not report targeted analytes above the laboratory reporting limit.

Information contained in a March 26, 2013 Groundwater Monitoring Report prepared by CES,
indicates that on February 13 and 14, 2013, CES installed two permanent monitoring wells (MW-5
and MW-7) at the subject site. CES collected groundwater samples from temporary well TW-3 and
monitoring wells MW-5, and MW-7. The laboratory reported several targeted analytes at
concentrations above their respective laboratory reporting limits, but below their respective
NC2LGWQS. Additionally, CES collected soil samples at depths of 8 ft bgs, 13 ft bgs, and 23 ft bgs
during the installation of monitoring well MW-5. The laboratory reported C9-C22 Aromatics at a
concentration above the MSCC in the soil sample collected from MW-5 at 23 ft bgs. The laboratory
reported several additional targeted analytes at concentrations above the laboratory reporting limits,
but below their respective MSCCs. The results of this soil sampling are summarized in Table 6.

On August 13, 2014, ECS collected two groundwater samples from monitoring wells MW-5 and
MW-7. Monitoring well MW-3 was filled with dirt; therefore, a groundwater sample was not
collected. Additionally, ECS collected groundwater samples from water supply wells WSW-4,
WSW-5, and WSW-6. The laboratory reported several analytes at concentrations above their
respective laboratory reporting limit in the groundwater samples collected from the site
monitoring wells. Additionally, the laboratory reported several analytes at concentrations above
the laboratory reporting limit in the groundwater samples collected from water supply wells
WSW-4 and WSW-5.

SITE GEOLOGY AND HYDROGEOLOGY

As determined from the USGS Topographic Map, Flowers, North Carolina Quadrangle dated
1998 (Figure 1), the site is at an approximate elevation of 275 feet above mean sea level.
Surface runoff on the site is generally to the west.

The subject site is situated in the Coastal Plain Physiographic Province. The soils encountered
in this area are the residual product of in-place chemical weathering of rock presently underlying
the site and/or historic depositional events. In general, shallow unconfined groundwater
movement within the overlying soils is controlled largely by topographic gradients. However, as
Report of Environmental Services – Flowers Store Property
4181 NC Highway 42 East
Clayton, Johnson County, North Carolina
NCDENR Incident: TF-17217
NCDENR Contract: N14007i-C
August 4, 2015

4
the groundwater percolates downward, it becomes controlled by the subsurface geologic
conditions. Thus, the direction of groundwater movement in the deeper aquifers may not be
consistent with the reflecting topography.

In general, shallow unconfined groundwater movement within the overlying soils is controlled
largely by topographic gradients. Recharge occurs primarily by infiltration along higher
elevations and typically discharges into streams or other surface water bodies. The elevation of
the shallow water table is transient and can vary with seasonal fluctuations in precipitation.
Movement of shallow groundwater is generally from higher to lower elevations.

Water Supply Wells

Six previously identified water supply wells are located within 1,500 feet of the source area.
ECS received a completed water supply well questionnaire from Ms. Sarah Blanchard, the
property owner of the residence associated with water supply well WSW-4. ECS also received
verbal permission from the resident of the home associated with water supply well WSW-5 to
collect a groundwater sample. ECS has not received completed water supply well
questionnaires from the remaining property owners within 1,000 feet of the site. The names and
addresses of the property owners with water supply wells located within 1,000 feet of the site
are included in Table 7 and shown on Figure 7.

FIELD ACTIVITIES

On June 11 and 12, 2015, ECS contracted with Quantex to install three monitoring wells (MW-8
through MW-10) to a depth of 30 ft bgs, 30 ft bgs, and 49 ft bgs, respectively. The monitoring
wells were constructed with two-inch inner diameter Schedule 40 PVC flush-threaded casing and
screen. The PVC screen and casing were lowered into the open borehole. A ten-foot length of
slotted well screen with machined 0.010-inch slot widths and a threaded bottom plug were installed
at the bottom of each well. A solid section of PVC casing was placed above the screened interval
and extended to a point just above the ground surface. The annular space around each well was
filled with a washed and graded medium sand to approximately two feet above the top of the
screen.

ECS collected groundwater samples from monitoring wells MW-3, MW-5, MW-7 and each of the
three new monitoring wells. The monitoring well construction records are included in Appendix A.

Prior to the sampling activities, the static groundwater elevation was measured in each monitoring
well. Well construction details and groundwater elevation data is summarized in Table 2 and
shown of Figure 4. Based on these measurements, ECS determined groundwater flows
generally to the west. Purging and sampling were accomplished using a peristaltic pump and
dedicated tubing. Immediately after collection, the groundwater samples were transferred into
sample containers provided by the laboratory.

ECS also collected groundwater samples from water supply wells WSW-4 and WSW-5.
Historically, it was reported that the properties associated with water supply wells WSW-2 and
WSW-3 are connected to the municipal water supply; therefore groundwater samples were not
collected. The property associated with water supply well WSW-6 was unoccupied; therefore a
groundwater sample was not collected.
Report of Environmental Services – Flowers Store Property
4181 NC Highway 42 East
Clayton, Johnson County, North Carolina
NCDENR Incident: TF-17217
NCDENR Contract: N14007i-C
August 4, 2015

5

Prior to water supply well sampling activities, ECS opened the spigots attached to the outside of
the residences for three to five minutes allowing the groundwater to purge from the water supply
wells and associated water lines. After allowing the water supply wells to purge, ECS collected
the groundwater samples from the spigots into sample containers provided by the laboratory.

The sample containers were labeled with ECS project number, sample identification, sample
date and time, and requested analytical analysis. The containers were placed into protective
packaging material and placed into a cooler with ice to maintain the samples at approximately
4 Celsius (C). The samples were submitted to Pace Analytical Services, Inc. located in
Huntersville, North Carolina for chemical analysis for VOCs using EPA Method 6200B. ECS
maintained proper COC procedures throughout the sample collection and transportation process.

On June 25, 2015 ECS contracted with Bateman Civil Survey (Bateman) to survey the monitoring
wells. During surveying activities, ECS identified bulldozing had occurred near the location of
monitoring well MW-3 and had damaged the well. Bateman’s survey information is included in
Appendix B.

LABORATORY ANALYTICAL RESULTS

Laboratory analysis reported naphthalene at a concentration above its NC2LGWQS but below its
GCL in the groundwater sample collected from monitoring well MW-9.

Laboratory analysis reported bromodichloromethane and dibromochloromethane at concentrations
above their respective NC2LGWQS but below their respective GCLs in the groundwater sample
collected from water supply well WSW-4.

Laboratory analysis reported 1,2-dichloropropane at a concentration above its NC2LGWQS but
below its GCL in the groundwater sample collected from water supply well WSW-5.

Laboratory analysis reported several additional targeted analytes above their respective laboratory
reporting limits but below their NC2LGWQS in the groundwater samples collected from monitoring
wells MW-8 and MW-9 and water supply well WSW-4.

Laboratory analysis did not report targeted analytes at concentrations above the laboratory
reporting limits in the groundwater samples collected from monitoring wells MW-3, MW-5, MW-7,
and MW-10.

A summary of the laboratory analytical results is included in Table 3 and shown on Figures 5 and 6.
Historical groundwater data is summarized in Tables 4 and 5.

The laboratory analytical data sheets and COCs are included in Appendix C.

CONCLUSIONS

Based on the results of this Groundwater Sampling Event, ECS concludes the following:

 ECS installed three new monitoring wells (MW-8 through MW-10) at the site;
Report of Environmental Services – Flowers Store Property
4181 NC Highway 42 East
Clayton, Johnson County, North Carolina
NCDENR Incident: TF-17217
NCDENR Contract: N14007i-C
August 4, 2015

6

 Historically, it was reported that water supply wells WSW-2 and WSW-3 are connected to
the municipal water supply; therefore groundwater samples were not collected;

 During surveying activities, ECS observed, monitoring well MW-3 had been damaged during
bulldozing activities at the site;

 Naphthalene was reported at a concentration above its NC2LGWQS in the groundwater sample
from monitoring well MW-9;

 Laboratory analysis did not report targeted analytes at concentrations above the NC2LGWQS
in the remaining groundwater samples collected from site monitoring wells;

 Laboratory analysis reported bromodichloromethane and dibromochloromethane in water
supply well WSW-4 at concentrations above their respective NC2LGWQS.
Bromodichloromethane and dibromochloromethane are common laboratory reagents and are
not considered analytes of concern of the site. Additionally, WSW-4 is located approximately
975 feet southeast and topographically cross-gradient of the site. Therefore, ECS does not
consider these detections associated with the Flowers Store Property; and

 Laboratory analysis reported 1,2-dichloropropane in water supply well WSW-5 at a
concentration above its NC2LGWQS. WSW-5 is located approximately 525 feet northwest and
topographically cross-gradient of the site. Therefore, ECS does not consider this detection
associated with Flowers Store Property.

RECOMMENDATIONS

 ECS recommends conducting a groundwater monitoring event in six months;

 An additional soil assessment does not appear necessary at the site; and

 ECS recommends that a copy of this report be submitted to the current property owner.

FIGURES
SOURCE:
USGS TOPOGRAPHIC MAP
FLOWERS
NORTH CAROLINA QUADRANGLE
DATED 1998
SCALE: 1 : 24,000
FIGURE 1
SITE LOCATION MAP
FLOWERS STORE PROPERTY
4181 NC HIGHWAY 42 EAST
CLAYTON, JOHNSTON COUNTY,
NORTH CAROLINA
NCDENR INCIDENT: 17217
ECS PROJECT: 06:21858-A
SITE
FIGURE 2
SITE AERIAL MAP
FLOWERS STORE PROPERTY
4181 NC HIGHWAY 42 EAST
CLAYTON, JOHNSTON COUNTY,
NORTH CAROLINA
NCDENR INCIDENT: 17217
ECS PROJECT: 06:21858-A
SOURCE:
JOHNSTON COUNTY GIS
DATED 2013
SCALE AS SHOWN
SITE
SINGLE-FAMILY
RESIDENCES
SINGLE-FAMILY
RESIDENCES
SINGLE-FAMILY
RESIDENCES
Scale: 1 inch = 197 feet
SOURCE:
JOHNSTON COUNTY GIS
DATED 2013
SCALE AS SHOWN
FIGURE 3
MONITORING WELL LOCATION MAP
FLOWERS STORE PROPERTY
4181 NC HIGHWAY 42 EAST
CLAYTON, JOHNSTON COUNTY,
NORTH CAROLINA
NCDENR INCIDENT: 17217
ECS PROJECT: 06:21858-A
LEGEND
Approximate Location of Monitoring Well
Approximate Location of Former UST
MW-3
MW-7
MW-3
MW-5
Scale: 1 inch = 60 feet
MW-8
MW-9
MW-10
SOURCE:
JOHNSTON COUNTY GIS
DATED 2013
SCALE AS SHOWN
FIGURE 4
GROUNDWATER ELEVATION MAP
FLOWERS STORE PROPERTY
4181 NC HIGHWAY 42 EAST
CLAYTON, JOHNSTON COUNTY,
NORTH CAROLINA
NCDENR INCIDENT: 17217
ECS PROJECT: 06:21858-A
Scale: 1 inch = 60 feet
MW-7
256.21
260255245250
MW-8
259.77
MW-3
256.32
MW-5
249.49MW-9
247.36
MW-10
251.81
LEGEND
Approximate Location of Monitoring Well
Groundwater Elevation
Groundwater Contour Line
Estimated Groundwater Contour Line
Estimated Direction of Groundwater Flow
* The site vertical datum is based on NAV88 and the horizontal
datum is based on NAD83.
MW-3
256.32
SOURCE:
JOHNSTON COUNTY GIS
DATED 2013
SCALE AS SHOWN
FIGURE 5
GROUNDWATER CONCENTRATION MAP
FLOWERS STORE PROPERTY
4181 NC HIGHWAY 42 EAST
CLAYTON, JOHNSTON COUNTY,
NORTH CAROLINA
NCDENR INCIDENT: 17217
ECS PROJECT: 06:21858-A
Scale: 1 inch = 60 feet
MW-7
BRL
MW-3
BRL
MW-5
BRL
MW-8MW-9
MW-10
BRL
sec-Butylbenzene 2.1
Isopropylbenzene 1.6
Naphthalene 17.1
n-Propylbenzene 3.3
1,2,4-Trimethylbenzene 15.7
1,3,5-Trimethylbenzene 27.7
Total Xylenes 3.7
1,4-Dichlorobenzene 0.61
LEGEND
Approximate Location of Monitoring Well
1.6 Concentrations Above Laboratory Reporting
Limits (µg/L)
17.1 Bold Concentrations Above the NCDENR
GWQS and/or NC2LGWQS (µg/L)
BRL Below Laboratory Reporting Limit
MW-3
SOURCE:
JOHNSTON COUNTY GIS
DATED 2013
SCALE AS SHOWN
FIGURE 6
NAPHTHALENE ISOCONCENTRATION MAP
FLOWERS STORE PROPERTY
4181 NC HIGHWAY 42 EAST
CLAYTON, JOHNSTON COUNTY,
NORTH CAROLINA
NCDENR INCIDENT: 17217
ECS PROJECT: 06:21858-A
Scale: 1 inch = 60 feet
MW-7
BRL
MW-3
BRL
MW-5
BRL
MW-8
BRL
MW-9
17.1
MW-10
BRL
LEGEND
Approximate Location of Monitoring Well
Naphthalene Isoconcentration Contour
17.1 Bold Concentrations Above NCDENR GWQS
BRL Below Laboratory Reporting Limit
MW-3
6
SOURCE:
JOHNSTON COUNTY GIS
DATED 2013
SCALE AS SHOWN
FIGURE 7
WATER SUPPLY WELL LOCATION MAP
FLOWERS STORE PROPERTY
4181 NC HIGHWAY 42 EAST
CLAYTON, JOHNSTON COUNTY,
NORTH CAROLINA
NCDENR INCIDENT: 17217
ECS PROJECT: 06:21858-A
LEGEND
Approximate Location
of Water Supply Well
500 ft.
Radius
1,000 ft.
Radius
WSW-5
SITE
0 361
Scale: 1 inch = 361 feet
WSW-6
WSW-4
WSW-5

TABLES
Monitoring Well IDDate MeasuredDepth to Groundwater (ft. btoc)Date InstalledTotal Well Depth (ft. btoc)Screen Interval (ft. btoc)TOC Elevation *Groundwater Elevation MW-3 6/11/2015 18.91 2/13/2013 35 20-35 275.23 256.32MW-5 6/11/2015 26.73 2/13/2013 38 23-38 276.22 249.49MW-7 6/12/2015 14.97 2/13/2013 40 20-40 271.18 256.21MW-8 6/12/2015 17.01 6/10/2015 30 20-30 276.78 259.77MW-9 6/12/2015 26.81 6/10/2015 30 20-30 274.17 247.36MW-10 6/12/2015 27.39 6/10/2015 49 39-49 279.20 251.81ft. btoc = Feet Below Top of Casing Clayton, Johnston County, North CarolinaECS Project 06:21858-ATOC = Top of Casing* = Survey performed by Bateman Civil Survey on June 25, 2015. The site vertical datum is based on NAV88 and the horizontal datum is based on NAD83.Table 2Well Construction and Groundwater Elevation DetailsFlowers Store Property4181 NC Highway 42 EastNCDENR Incident: 17217
Sample ID Sample DateBromodichloromethanesec-ButylbenzeneChloroformDibromochloromethaneIsopropylbenzeneNaphthalenen-Propylbenzene1,2-Dichloropropane1,4- Dichlorobenzene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneTotal XylenesMW-3 6/11/2015BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRLMW-5 6/11/2015BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRLMW-7 6/12/2015BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRLMW-8 6/12/2015BRL BRL BRL BRL BRL BRL BRL BRL0.61BRL BRL BRLMW-9 6/12/2015BRL2.1BRL BRL1.617.13.3BRL BRL15.7 27.7 3.7MW-10 6/12/2015BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRLWSW-4 6/11/201512.4BRL24.14.6BRL BRL BRL BRL BRL BRL BRL BRLWSW-5 6/11/2015BRL BRL BRL BRL BRL BRL BRL2.1BRL BRL BRL BRL0.6 70 70 0.4 70 6 70 0.6 6 400 400 500NE 8,500 70,000 400 25,000 6,000 30,000 600 6,000 28,500 25,000 85,500BRL = Below Laboratory Reporting LimitTable 3Summary of Current Groundwater Analytical ResultsFlowers Store Property4181 NC Highway 42 EastNC2LGWS (µg/L)GCL (µg/L) Clayton, Johnston County, North CarolinaECS Project 06:21858-AAnalytical MethodNCDENR Incident: 17217NC2LGWQS = North Carolina 2L Groundwater Quality Standard as of April 1, 2013 GCL = NCDENR's Gross Contamination Levels for Groundwater as of April 16, 2012Bold = Detected above NC2LGWQSµg/L = Micrograms per LiterStandard Method 6200BNE = Not Established
EPA Method 625 EPA Method 6010Monitoring Well IDDate9/2/2008BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL6.68 67 91 350 2509/30/2009BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL0.89BRL BRL BRL BRL BRL10/4/20129/2/2008BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL9/30/2009BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL0.71BRL BRL BRL BRL BRL10/4/20129/2/2008BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL9/30/2009BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL1110/4/2012BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRLBRL2/19/2013BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL0.15 JBRL BRL BRL BRL7.28/13/20146/11/2015BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL NS NS NS NS NS9/2/2008BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL9/30/200910/4/20122/19/2013 0.27 J 0.46 JBRL5.2 J 1.2 0.29BRL0.49 JBRL BRL BRL BRL BRL110BRL BRL158/13/2014BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL1,746.7BRL649 21.56/11/2015BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL NS NS NS NS NS2/19/2013BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL0.538/13/2014BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL6/12/2015BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL NS NS NS NS NSMW-86/12/2015BRL BRL0.61BRL BRL BRL BRL BRL BRL BRL BRL BRL NS NS NS NS NSMW-96/12/2015 15.7 27.7BRL BRL BRL2.1 1.6BRL3.317.13.7BRL NS NS NS NS NSMW-106/12/2015BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL NS NS NS NS NS210 15NCDENR Incident: 17217di-n-Butyl phthalateC9-C18 Aliphatics1,2,4-Trimethylbenzenesec-ButylbenzeneNENE 15,000NC2LGWQS (µg/L)GCL (µg/L)254,2006,000,000 6,9006,0001,3,5-Trimethylbenzene1,4-DichlorobenzeneIsopropylbenzeneNaphthaleneTotal Xylenes400 400 6Destroyed42,000NE8,5006 50030,000700Contaminant of Concern (µg/L)TW-1Table 4Summary of Historical Groundwater Analytical ResultsFlowers Store Property4181 NC Highway 42 EastClayton, Johnston County, North CarolinaAcetoneAnalytical MethodTetrachloroetheneECS Project 06:21858-AStandard Method 6200B (or equivalent)MADEP EPH/VPHWell DryDestroyedp-IsopropyltolueneC19-C36Aliphaticsn-ButylbenzeneMW-3 (TW-3)n-PropylbenzeneNC2LGWQS = North Carolina 2L Groundwater Quality Standard as of April 1, 2013 GCL = NCDENR's Gross Contamination Levels for Groundwater as of April 16, 201270TW-21706,000TW-4Destroyed85,500NE = Not EstablishedNS = Not SampledMW-7MW-5Bold = Detected above the NC2LGWQS µg/L = Micrograms per LiterBRL = Below Laboratory Reporting LimitJ = Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit28,500 25,000 6,0007025,00070DestroyedC9-C22 AromaticsLead NE70011,700
WSW-1 6/17/2008BRL10.4BRL BRL BRL59 160 1606/17/2008BRL1.22BRL BRL BRL56 1301508/13/201412.6BRL39.44.3BRL NS NSNS6/11/201512.4BRL24.14.6BRL NS NSNS8/13/2014BRL BRL BRL BRL1.4NS NSNS6/11/2015BRL BRL BRL BRL2.1NS NSNSWSW-68/13/2014BRL BRL BRL BRL BRL NS NSNSNE 3 70 0.4 0.6 700 10,000200NE 170 70,000 400 600 NE NENENC2LGWQS = North Carolina 2L Groundwater Quality Standard as of April 1, 2013 GCL = NCDENR's Gross Contamination Levels for Groundwater as of April 16, 2012Bold = Detected above the NC2LGWQSµg/L = Micrograms per LiterBRL = Below Laboratory Reporting LimitNS = Not SampledNE = Not EstablishedChloroformDibromochloromethaneContaminant of Concern (ug/L)Water Supply Well IDBis (2-ethylhexyl) PhthalateWSW-4WSW-5C19-C36 AliphaticsTable 5Summary of Current Historical Water Supply Well Analytical ResultsFlowers Store Property4181 NC Highway 42 EastClayton, Johnston County, North CarolinaECS Project 06:21858-AC11-C22 AromaticsNCDENR Incident: 17217GCL (µg/L)NC2LGWQSAnalytical Method1,2-DichloropropaneDate CollectedBromodichloromethaneStandard Method 6200B (or equivalent) MADEP EPH/VPHC9-C18 Aliphatics
SB-5 1 2/13/13BRL BRL BRL BRL BRL BRL BRL BRLSB-5 13 2/13/13BRL BRL BRL BRL BRL BRL BRL BRLSB-5 18 2/13/13BRL BRL BRL BRL0.26BRL39BRLSB-5 23 2/13/13 0.0020 0.0049 0.0011J 0.22 3.7 128 46758.3 4.3 3.3 6.6 120 540 Immobile 31782 626 626 46 62,571 1,500 31,000 46920,440 16,350 16,350 410 1,635,200 40,000 810,000 12,264mg/kg = milligrams per kilogramBRL = Below Laboratory Reporting LimitC19-C36 AliphaticsDate CollectedResidential MSCCContaminant of Concern (mg/kg)Depth Collected (Ft.)1,3,5-Trimethylbenzenen-ButylbenzeneIndustrial/Commercial MSCCSample IDsec-ButylbenzeneSoil to Groundwater MSCCNCDENR = North Carolina Department of Environment and Natural Resbis(2-Ethylhexyl)phthalateBenzoic AcidC9-C18 AliphaticsC9-C22 AromaticsECS Project 06:21858-AMSCC = Maximum Soil Contaminant Concentration LevelsAnalytical Method EPA Method 8260B EPA Method 8270D MADEP EPH/VPHTable 6Summary of Historical Soil Sample Analytical ResultsFlowers Store Property4181 NC Highway 42 EastClayton, Johnston County, North CarolinaNCDENR Incident: 17217
Water Supply Well Parcel Address Owner Owner Address Water Well StatusApproximate Distance from Source AreaWSW-44300 NC Highway 42 Clayton, NC 27527Valcourt, Richard J and Blanchard, Sarah4709 Chickpay Dr Raleigh NC, 27610Potable 975 feet southeastWSW-5160 Motorcycle Rd Clayton, NC 27527Robertson, Drake160 Motorcycle Rd Clayton, NC 27527Potable 525 feet northwestWSW-6270 Motorcycle Rd Clayton, NC 27527Pineville Chapel Church270 Motorcycle Road Clayton, NC 27527Unknown 1,000+ feet northwestTable 7Water Supply Well SurveyFlowers Store Property4181 NC Highway 42 EastClayton, Johnson County, North CarolinaECS Project 06:21858-ANCDENR Incident: 17217

APPENDIX A

APPENDIX B
WELL GROUND/RIM TOP OF CASING
NUMBER NORTHING EASTING ELEVATION ELEVATION
MW‐3 692802.26 2189825.74 275.49 275.23
MW‐5 692724.79 2189806.66 276.53 276.22
MW‐7 692864.97 2189918.53 271.75 271.18
MW‐8 692742.66 2189933.60 277.28 276.78
MW‐9 692703.69 2189690.19 274.55 274.17
MW‐10 692635.47 2189843.03 279.63 279.20

APPENDIX C

#=CL#
June 22, 2015
LIMS USE: FR - MATTHEW GILLIS
LIMS OBJECT ID: 92254444
92254444
Project:
Pace Project No.:
RE:
Matthew Gillis
ECS
9001 Glenwood Avenue
Raleigh, NC 27617
FLOWERS STORE 21858-A
Dear Matthew Gillis:
Enclosed are the analytical results for sample(s) received by the laboratory on June 15, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
The laboratory report is being resubmitted on June 22, 2015, to correct the project ID.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
cc:Matthew Gillis, ECS
Brian Smith, ECS Carolinas LLP
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 33
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 33
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92254444004 MW-8
1,4-Dichlorobenzene 0.61 ug/L 06/19/15 04:120.50SM 6200B
92254444005 MW-9
sec-Butylbenzene 2.1 ug/L 06/19/15 16:380.50SM 6200B
Isopropylbenzene (Cumene)1.6 ug/L 06/19/15 16:380.50SM 6200B
Naphthalene 17.1 ug/L 06/19/15 16:382.0SM 6200B
n-Propylbenzene 3.3 ug/L 06/19/15 16:380.50SM 6200B
1,2,4-Trimethylbenzene 15.7 ug/L 06/19/15 16:380.50SM 6200B
1,3,5-Trimethylbenzene 27.7 ug/L 06/19/15 16:380.50SM 6200B
m&p-Xylene 1.3 ug/L 06/19/15 16:381.0SM 6200B
o-Xylene 2.4 ug/L 06/19/15 16:380.50SM 6200B
92254444007 WSW-5
1,2-Dichloropropane 2.1 ug/L 06/19/15 02:160.50SM 6200B
92254444008 WSW-4
Bromodichloromethane 12.4 ug/L 06/19/15 02:330.50SM 6200B
Chloroform 24.1 ug/L 06/19/15 02:330.50SM 6200B
Dibromochloromethane 4.6 ug/L 06/19/15 02:330.50SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Sample:MW-3 Lab ID:92254444001 Collected:06/11/15 09:42 Received:06/15/15 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 06/19/15 03:55 71-43-20.50 1
Bromobenzene ND ug/L 06/19/15 03:55 108-86-10.50 1
Bromochloromethane ND ug/L 06/19/15 03:55 74-97-50.50 1
Bromodichloromethane ND ug/L 06/19/15 03:55 75-27-40.50 1
Bromoform ND ug/L 06/19/15 03:55 75-25-20.50 1
Bromomethane ND ug/L 06/19/15 03:55 74-83-95.0 1
n-Butylbenzene ND ug/L 06/19/15 03:55 104-51-80.50 1
sec-Butylbenzene ND ug/L 06/19/15 03:55 135-98-80.50 1
tert-Butylbenzene ND ug/L 06/19/15 03:55 98-06-60.50 1
Carbon tetrachloride ND ug/L 06/19/15 03:55 56-23-50.50 1
Chlorobenzene ND ug/L 06/19/15 03:55 108-90-70.50 1
Chloroethane ND ug/L 06/19/15 03:55 75-00-31.0 1
Chloroform ND ug/L 06/19/15 03:55 67-66-30.50 1
Chloromethane ND ug/L 06/19/15 03:55 74-87-31.0 1
2-Chlorotoluene ND ug/L 06/19/15 03:55 95-49-80.50 1
4-Chlorotoluene ND ug/L 06/19/15 03:55 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 06/19/15 03:55 96-12-81.0 1
Dibromochloromethane ND ug/L 06/19/15 03:55 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 06/19/15 03:55 106-93-40.50 1
Dibromomethane ND ug/L 06/19/15 03:55 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 06/19/15 03:55 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 06/19/15 03:55 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 06/19/15 03:55 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 06/19/15 03:55 75-71-80.50 1
1,1-Dichloroethane ND ug/L 06/19/15 03:55 75-34-30.50 1
1,2-Dichloroethane ND ug/L 06/19/15 03:55 107-06-20.50 1
1,1-Dichloroethene ND ug/L 06/19/15 03:55 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 06/19/15 03:55 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 06/19/15 03:55 156-60-50.50 1
1,2-Dichloropropane ND ug/L 06/19/15 03:55 78-87-50.50 1
1,3-Dichloropropane ND ug/L 06/19/15 03:55 142-28-90.50 1
2,2-Dichloropropane ND ug/L 06/19/15 03:55 594-20-70.50 1
1,1-Dichloropropene ND ug/L 06/19/15 03:55 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 06/19/15 03:55 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 06/19/15 03:55 10061-02-60.50 1
Diisopropyl ether ND ug/L 06/19/15 03:55 108-20-30.50 1
Ethylbenzene ND ug/L 06/19/15 03:55 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 06/19/15 03:55 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 06/19/15 03:55 98-82-80.50 1
Methylene Chloride ND ug/L 06/19/15 03:55 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 06/19/15 03:55 1634-04-40.50 1
Naphthalene ND ug/L 06/19/15 03:55 91-20-32.0 1
n-Propylbenzene ND ug/L 06/19/15 03:55 103-65-10.50 1
Styrene ND ug/L 06/19/15 03:55 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 06/19/15 03:55 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 06/19/15 03:55 79-34-50.50 1
Tetrachloroethene ND ug/L 06/19/15 03:55 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Sample:MW-3 Lab ID:92254444001 Collected:06/11/15 09:42 Received:06/15/15 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B6200B MSV
Toluene ND ug/L 06/19/15 03:55 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 06/19/15 03:55 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 06/19/15 03:55 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 06/19/15 03:55 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 06/19/15 03:55 79-00-50.50 1
Trichloroethene ND ug/L 06/19/15 03:55 79-01-60.50 1
Trichlorofluoromethane ND ug/L 06/19/15 03:55 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 06/19/15 03:55 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 06/19/15 03:55 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 06/19/15 03:55 108-67-80.50 1
Vinyl chloride ND ug/L 06/19/15 03:55 75-01-41.0 1
m&p-Xylene ND ug/L 06/19/15 03:55 179601-23-11.0 1
o-Xylene ND ug/L 06/19/15 03:55 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)98 %06/19/15 03:55 17060-07-070-130 1
4-Bromofluorobenzene (S)101 %06/19/15 03:55 460-00-470-130 1
Toluene-d8 (S)101 %06/19/15 03:55 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Sample:MW-5 Lab ID:92254444002 Collected:06/11/15 10:32 Received:06/15/15 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 06/19/15 01:43 71-43-20.50 1
Bromobenzene ND ug/L 06/19/15 01:43 108-86-10.50 1
Bromochloromethane ND ug/L 06/19/15 01:43 74-97-50.50 1
Bromodichloromethane ND ug/L 06/19/15 01:43 75-27-40.50 1
Bromoform ND ug/L 06/19/15 01:43 75-25-20.50 1
Bromomethane ND ug/L 06/19/15 01:43 74-83-95.0 1
n-Butylbenzene ND ug/L 06/19/15 01:43 104-51-80.50 1
sec-Butylbenzene ND ug/L 06/19/15 01:43 135-98-80.50 1
tert-Butylbenzene ND ug/L 06/19/15 01:43 98-06-60.50 1
Carbon tetrachloride ND ug/L 06/19/15 01:43 56-23-50.50 1
Chlorobenzene ND ug/L 06/19/15 01:43 108-90-70.50 1
Chloroethane ND ug/L 06/19/15 01:43 75-00-31.0 1
Chloroform ND ug/L 06/19/15 01:43 67-66-30.50 1
Chloromethane ND ug/L 06/19/15 01:43 74-87-31.0 1
2-Chlorotoluene ND ug/L 06/19/15 01:43 95-49-80.50 1
4-Chlorotoluene ND ug/L 06/19/15 01:43 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 06/19/15 01:43 96-12-81.0 1
Dibromochloromethane ND ug/L 06/19/15 01:43 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 06/19/15 01:43 106-93-40.50 1
Dibromomethane ND ug/L 06/19/15 01:43 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 06/19/15 01:43 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 06/19/15 01:43 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 06/19/15 01:43 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 06/19/15 01:43 75-71-80.50 1
1,1-Dichloroethane ND ug/L 06/19/15 01:43 75-34-30.50 1
1,2-Dichloroethane ND ug/L 06/19/15 01:43 107-06-20.50 1
1,1-Dichloroethene ND ug/L 06/19/15 01:43 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 06/19/15 01:43 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 06/19/15 01:43 156-60-50.50 1
1,2-Dichloropropane ND ug/L 06/19/15 01:43 78-87-50.50 1
1,3-Dichloropropane ND ug/L 06/19/15 01:43 142-28-90.50 1
2,2-Dichloropropane ND ug/L 06/19/15 01:43 594-20-70.50 1
1,1-Dichloropropene ND ug/L 06/19/15 01:43 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 06/19/15 01:43 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 06/19/15 01:43 10061-02-60.50 1
Diisopropyl ether ND ug/L 06/19/15 01:43 108-20-30.50 1
Ethylbenzene ND ug/L 06/19/15 01:43 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 06/19/15 01:43 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 06/19/15 01:43 98-82-80.50 1
Methylene Chloride ND ug/L 06/19/15 01:43 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 06/19/15 01:43 1634-04-40.50 1
Naphthalene ND ug/L 06/19/15 01:43 91-20-32.0 1
n-Propylbenzene ND ug/L 06/19/15 01:43 103-65-10.50 1
Styrene ND ug/L 06/19/15 01:43 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 06/19/15 01:43 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 06/19/15 01:43 79-34-50.50 1
Tetrachloroethene ND ug/L 06/19/15 01:43 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Sample:MW-5 Lab ID:92254444002 Collected:06/11/15 10:32 Received:06/15/15 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B6200B MSV
Toluene ND ug/L 06/19/15 01:43 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 06/19/15 01:43 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 06/19/15 01:43 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 06/19/15 01:43 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 06/19/15 01:43 79-00-50.50 1
Trichloroethene ND ug/L 06/19/15 01:43 79-01-60.50 1
Trichlorofluoromethane ND ug/L 06/19/15 01:43 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 06/19/15 01:43 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 06/19/15 01:43 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 06/19/15 01:43 108-67-80.50 1
Vinyl chloride ND ug/L 06/19/15 01:43 75-01-41.0 1
m&p-Xylene ND ug/L 06/19/15 01:43 179601-23-11.0 1
o-Xylene ND ug/L 06/19/15 01:43 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)99 %06/19/15 01:43 17060-07-070-130 1
4-Bromofluorobenzene (S)102 %06/19/15 01:43 460-00-470-130 1
Toluene-d8 (S)100 %06/19/15 01:43 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Sample:MW-7 Lab ID:92254444003 Collected:06/12/15 10:48 Received:06/15/15 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 06/19/15 02:00 71-43-20.50 1
Bromobenzene ND ug/L 06/19/15 02:00 108-86-10.50 1
Bromochloromethane ND ug/L 06/19/15 02:00 74-97-50.50 1
Bromodichloromethane ND ug/L 06/19/15 02:00 75-27-40.50 1
Bromoform ND ug/L 06/19/15 02:00 75-25-20.50 1
Bromomethane ND ug/L 06/19/15 02:00 74-83-95.0 1
n-Butylbenzene ND ug/L 06/19/15 02:00 104-51-80.50 1
sec-Butylbenzene ND ug/L 06/19/15 02:00 135-98-80.50 1
tert-Butylbenzene ND ug/L 06/19/15 02:00 98-06-60.50 1
Carbon tetrachloride ND ug/L 06/19/15 02:00 56-23-50.50 1
Chlorobenzene ND ug/L 06/19/15 02:00 108-90-70.50 1
Chloroethane ND ug/L 06/19/15 02:00 75-00-31.0 1
Chloroform ND ug/L 06/19/15 02:00 67-66-30.50 1
Chloromethane ND ug/L 06/19/15 02:00 74-87-31.0 1
2-Chlorotoluene ND ug/L 06/19/15 02:00 95-49-80.50 1
4-Chlorotoluene ND ug/L 06/19/15 02:00 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 06/19/15 02:00 96-12-81.0 1
Dibromochloromethane ND ug/L 06/19/15 02:00 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 06/19/15 02:00 106-93-40.50 1
Dibromomethane ND ug/L 06/19/15 02:00 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 06/19/15 02:00 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 06/19/15 02:00 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 06/19/15 02:00 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 06/19/15 02:00 75-71-80.50 1
1,1-Dichloroethane ND ug/L 06/19/15 02:00 75-34-30.50 1
1,2-Dichloroethane ND ug/L 06/19/15 02:00 107-06-20.50 1
1,1-Dichloroethene ND ug/L 06/19/15 02:00 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 06/19/15 02:00 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 06/19/15 02:00 156-60-50.50 1
1,2-Dichloropropane ND ug/L 06/19/15 02:00 78-87-50.50 1
1,3-Dichloropropane ND ug/L 06/19/15 02:00 142-28-90.50 1
2,2-Dichloropropane ND ug/L 06/19/15 02:00 594-20-70.50 1
1,1-Dichloropropene ND ug/L 06/19/15 02:00 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 06/19/15 02:00 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 06/19/15 02:00 10061-02-60.50 1
Diisopropyl ether ND ug/L 06/19/15 02:00 108-20-30.50 1
Ethylbenzene ND ug/L 06/19/15 02:00 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 06/19/15 02:00 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 06/19/15 02:00 98-82-80.50 1
Methylene Chloride ND ug/L 06/19/15 02:00 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 06/19/15 02:00 1634-04-40.50 1
Naphthalene ND ug/L 06/19/15 02:00 91-20-32.0 1
n-Propylbenzene ND ug/L 06/19/15 02:00 103-65-10.50 1
Styrene ND ug/L 06/19/15 02:00 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 06/19/15 02:00 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 06/19/15 02:00 79-34-50.50 1
Tetrachloroethene ND ug/L 06/19/15 02:00 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Sample:MW-7 Lab ID:92254444003 Collected:06/12/15 10:48 Received:06/15/15 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B6200B MSV
Toluene ND ug/L 06/19/15 02:00 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 06/19/15 02:00 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 06/19/15 02:00 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 06/19/15 02:00 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 06/19/15 02:00 79-00-50.50 1
Trichloroethene ND ug/L 06/19/15 02:00 79-01-60.50 1
Trichlorofluoromethane ND ug/L 06/19/15 02:00 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 06/19/15 02:00 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 06/19/15 02:00 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 06/19/15 02:00 108-67-80.50 1
Vinyl chloride ND ug/L 06/19/15 02:00 75-01-41.0 1
m&p-Xylene ND ug/L 06/19/15 02:00 179601-23-11.0 1
o-Xylene ND ug/L 06/19/15 02:00 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)100 %06/19/15 02:00 17060-07-070-130 1
4-Bromofluorobenzene (S)101 %06/19/15 02:00 460-00-470-130 1
Toluene-d8 (S)100 %06/19/15 02:00 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Sample:MW-8 Lab ID:92254444004 Collected:06/12/15 10:07 Received:06/15/15 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 06/19/15 04:12 71-43-20.50 1
Bromobenzene ND ug/L 06/19/15 04:12 108-86-10.50 1
Bromochloromethane ND ug/L 06/19/15 04:12 74-97-50.50 1
Bromodichloromethane ND ug/L 06/19/15 04:12 75-27-40.50 1
Bromoform ND ug/L 06/19/15 04:12 75-25-20.50 1
Bromomethane ND ug/L 06/19/15 04:12 74-83-95.0 1
n-Butylbenzene ND ug/L 06/19/15 04:12 104-51-80.50 1
sec-Butylbenzene ND ug/L 06/19/15 04:12 135-98-80.50 1
tert-Butylbenzene ND ug/L 06/19/15 04:12 98-06-60.50 1
Carbon tetrachloride ND ug/L 06/19/15 04:12 56-23-50.50 1
Chlorobenzene ND ug/L 06/19/15 04:12 108-90-70.50 1
Chloroethane ND ug/L 06/19/15 04:12 75-00-31.0 1
Chloroform ND ug/L 06/19/15 04:12 67-66-30.50 1
Chloromethane ND ug/L 06/19/15 04:12 74-87-31.0 1
2-Chlorotoluene ND ug/L 06/19/15 04:12 95-49-80.50 1
4-Chlorotoluene ND ug/L 06/19/15 04:12 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 06/19/15 04:12 96-12-81.0 1
Dibromochloromethane ND ug/L 06/19/15 04:12 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 06/19/15 04:12 106-93-40.50 1
Dibromomethane ND ug/L 06/19/15 04:12 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 06/19/15 04:12 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 06/19/15 04:12 541-73-10.50 1
1,4-Dichlorobenzene 0.61 ug/L 06/19/15 04:12 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 06/19/15 04:12 75-71-80.50 1
1,1-Dichloroethane ND ug/L 06/19/15 04:12 75-34-30.50 1
1,2-Dichloroethane ND ug/L 06/19/15 04:12 107-06-20.50 1
1,1-Dichloroethene ND ug/L 06/19/15 04:12 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 06/19/15 04:12 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 06/19/15 04:12 156-60-50.50 1
1,2-Dichloropropane ND ug/L 06/19/15 04:12 78-87-50.50 1
1,3-Dichloropropane ND ug/L 06/19/15 04:12 142-28-90.50 1
2,2-Dichloropropane ND ug/L 06/19/15 04:12 594-20-70.50 1
1,1-Dichloropropene ND ug/L 06/19/15 04:12 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 06/19/15 04:12 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 06/19/15 04:12 10061-02-60.50 1
Diisopropyl ether ND ug/L 06/19/15 04:12 108-20-30.50 1
Ethylbenzene ND ug/L 06/19/15 04:12 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 06/19/15 04:12 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 06/19/15 04:12 98-82-80.50 1
Methylene Chloride ND ug/L 06/19/15 04:12 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 06/19/15 04:12 1634-04-40.50 1
Naphthalene ND ug/L 06/19/15 04:12 91-20-32.0 1
n-Propylbenzene ND ug/L 06/19/15 04:12 103-65-10.50 1
Styrene ND ug/L 06/19/15 04:12 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 06/19/15 04:12 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 06/19/15 04:12 79-34-50.50 1
Tetrachloroethene ND ug/L 06/19/15 04:12 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Sample:MW-8 Lab ID:92254444004 Collected:06/12/15 10:07 Received:06/15/15 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B6200B MSV
Toluene ND ug/L 06/19/15 04:12 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 06/19/15 04:12 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 06/19/15 04:12 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 06/19/15 04:12 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 06/19/15 04:12 79-00-50.50 1
Trichloroethene ND ug/L 06/19/15 04:12 79-01-60.50 1
Trichlorofluoromethane ND ug/L 06/19/15 04:12 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 06/19/15 04:12 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 06/19/15 04:12 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 06/19/15 04:12 108-67-80.50 1
Vinyl chloride ND ug/L 06/19/15 04:12 75-01-41.0 1
m&p-Xylene ND ug/L 06/19/15 04:12 179601-23-11.0 1
o-Xylene ND ug/L 06/19/15 04:12 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)99 %06/19/15 04:12 17060-07-070-130 1
4-Bromofluorobenzene (S)99 %06/19/15 04:12 460-00-470-130 1
Toluene-d8 (S)99 %06/19/15 04:12 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Sample:MW-9 Lab ID:92254444005 Collected:06/12/15 09:30 Received:06/15/15 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 06/19/15 16:38 71-43-20.50 1
Bromobenzene ND ug/L 06/19/15 16:38 108-86-10.50 1
Bromochloromethane ND ug/L 06/19/15 16:38 74-97-50.50 1
Bromodichloromethane ND ug/L 06/19/15 16:38 75-27-40.50 1
Bromoform ND ug/L 06/19/15 16:38 75-25-20.50 1
Bromomethane ND ug/L 06/19/15 16:38 74-83-95.0 1
n-Butylbenzene ND ug/L 06/19/15 16:38 104-51-80.50 1
sec-Butylbenzene 2.1 ug/L 06/19/15 16:38 135-98-80.50 1
tert-Butylbenzene ND ug/L 06/19/15 16:38 98-06-60.50 1
Carbon tetrachloride ND ug/L 06/19/15 16:38 56-23-50.50 1
Chlorobenzene ND ug/L 06/19/15 16:38 108-90-70.50 1
Chloroethane ND ug/L 06/19/15 16:38 75-00-31.0 1
Chloroform ND ug/L 06/19/15 16:38 67-66-30.50 1
Chloromethane ND ug/L 06/19/15 16:38 74-87-31.0 1
2-Chlorotoluene ND ug/L 06/19/15 16:38 95-49-80.50 1
4-Chlorotoluene ND ug/L 06/19/15 16:38 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 06/19/15 16:38 96-12-81.0 1
Dibromochloromethane ND ug/L 06/19/15 16:38 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 06/19/15 16:38 106-93-40.50 1
Dibromomethane ND ug/L 06/19/15 16:38 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 06/19/15 16:38 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 06/19/15 16:38 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 06/19/15 16:38 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 06/19/15 16:38 75-71-80.50 1
1,1-Dichloroethane ND ug/L 06/19/15 16:38 75-34-30.50 1
1,2-Dichloroethane ND ug/L 06/19/15 16:38 107-06-20.50 1
1,1-Dichloroethene ND ug/L 06/19/15 16:38 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 06/19/15 16:38 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 06/19/15 16:38 156-60-50.50 1
1,2-Dichloropropane ND ug/L 06/19/15 16:38 78-87-50.50 1
1,3-Dichloropropane ND ug/L 06/19/15 16:38 142-28-90.50 1
2,2-Dichloropropane ND ug/L 06/19/15 16:38 594-20-70.50 1
1,1-Dichloropropene ND ug/L 06/19/15 16:38 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 06/19/15 16:38 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 06/19/15 16:38 10061-02-60.50 1
Diisopropyl ether ND ug/L 06/19/15 16:38 108-20-30.50 1
Ethylbenzene ND ug/L 06/19/15 16:38 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 06/19/15 16:38 87-68-32.0 1
Isopropylbenzene (Cumene)1.6 ug/L 06/19/15 16:38 98-82-80.50 1
Methylene Chloride ND ug/L 06/19/15 16:38 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 06/19/15 16:38 1634-04-40.50 1
Naphthalene 17.1 ug/L 06/19/15 16:38 91-20-32.0 1
n-Propylbenzene 3.3 ug/L 06/19/15 16:38 103-65-10.50 1
Styrene ND ug/L 06/19/15 16:38 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 06/19/15 16:38 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 06/19/15 16:38 79-34-50.50 1
Tetrachloroethene ND ug/L 06/19/15 16:38 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Sample:MW-9 Lab ID:92254444005 Collected:06/12/15 09:30 Received:06/15/15 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B6200B MSV
Toluene ND ug/L 06/19/15 16:38 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 06/19/15 16:38 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 06/19/15 16:38 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 06/19/15 16:38 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 06/19/15 16:38 79-00-50.50 1
Trichloroethene ND ug/L 06/19/15 16:38 79-01-60.50 1
Trichlorofluoromethane ND ug/L 06/19/15 16:38 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 06/19/15 16:38 96-18-40.50 1
1,2,4-Trimethylbenzene 15.7 ug/L 06/19/15 16:38 95-63-60.50 1
1,3,5-Trimethylbenzene 27.7 ug/L 06/19/15 16:38 108-67-80.50 1
Vinyl chloride ND ug/L 06/19/15 16:38 75-01-41.0 1
m&p-Xylene 1.3 ug/L 06/19/15 16:38 179601-23-11.0 1
o-Xylene 2.4 ug/L 06/19/15 16:38 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)100 %06/19/15 16:38 17060-07-070-130 1
4-Bromofluorobenzene (S)100 %06/19/15 16:38 460-00-470-130 1
Toluene-d8 (S)101 %06/19/15 16:38 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Sample:MW-10 Lab ID:92254444006 Collected:06/12/15 08:53 Received:06/15/15 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 06/19/15 04:29 71-43-20.50 1
Bromobenzene ND ug/L 06/19/15 04:29 108-86-10.50 1
Bromochloromethane ND ug/L 06/19/15 04:29 74-97-50.50 1
Bromodichloromethane ND ug/L 06/19/15 04:29 75-27-40.50 1
Bromoform ND ug/L 06/19/15 04:29 75-25-20.50 1
Bromomethane ND ug/L 06/19/15 04:29 74-83-95.0 1
n-Butylbenzene ND ug/L 06/19/15 04:29 104-51-80.50 1
sec-Butylbenzene ND ug/L 06/19/15 04:29 135-98-80.50 1
tert-Butylbenzene ND ug/L 06/19/15 04:29 98-06-60.50 1
Carbon tetrachloride ND ug/L 06/19/15 04:29 56-23-50.50 1
Chlorobenzene ND ug/L 06/19/15 04:29 108-90-70.50 1
Chloroethane ND ug/L 06/19/15 04:29 75-00-31.0 1
Chloroform ND ug/L 06/19/15 04:29 67-66-30.50 1
Chloromethane ND ug/L 06/19/15 04:29 74-87-31.0 1
2-Chlorotoluene ND ug/L 06/19/15 04:29 95-49-80.50 1
4-Chlorotoluene ND ug/L 06/19/15 04:29 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 06/19/15 04:29 96-12-81.0 1
Dibromochloromethane ND ug/L 06/19/15 04:29 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 06/19/15 04:29 106-93-40.50 1
Dibromomethane ND ug/L 06/19/15 04:29 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 06/19/15 04:29 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 06/19/15 04:29 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 06/19/15 04:29 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 06/19/15 04:29 75-71-80.50 1
1,1-Dichloroethane ND ug/L 06/19/15 04:29 75-34-30.50 1
1,2-Dichloroethane ND ug/L 06/19/15 04:29 107-06-20.50 1
1,1-Dichloroethene ND ug/L 06/19/15 04:29 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 06/19/15 04:29 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 06/19/15 04:29 156-60-50.50 1
1,2-Dichloropropane ND ug/L 06/19/15 04:29 78-87-50.50 1
1,3-Dichloropropane ND ug/L 06/19/15 04:29 142-28-90.50 1
2,2-Dichloropropane ND ug/L 06/19/15 04:29 594-20-70.50 1
1,1-Dichloropropene ND ug/L 06/19/15 04:29 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 06/19/15 04:29 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 06/19/15 04:29 10061-02-60.50 1
Diisopropyl ether ND ug/L 06/19/15 04:29 108-20-30.50 1
Ethylbenzene ND ug/L 06/19/15 04:29 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 06/19/15 04:29 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 06/19/15 04:29 98-82-80.50 1
Methylene Chloride ND ug/L 06/19/15 04:29 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 06/19/15 04:29 1634-04-40.50 1
Naphthalene ND ug/L 06/19/15 04:29 91-20-32.0 1
n-Propylbenzene ND ug/L 06/19/15 04:29 103-65-10.50 1
Styrene ND ug/L 06/19/15 04:29 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 06/19/15 04:29 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 06/19/15 04:29 79-34-50.50 1
Tetrachloroethene ND ug/L 06/19/15 04:29 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
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[phone]
Page 14 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Sample:MW-10 Lab ID:92254444006 Collected:06/12/15 08:53 Received:06/15/15 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B6200B MSV
Toluene ND ug/L 06/19/15 04:29 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 06/19/15 04:29 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 06/19/15 04:29 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 06/19/15 04:29 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 06/19/15 04:29 79-00-50.50 1
Trichloroethene ND ug/L 06/19/15 04:29 79-01-60.50 1
Trichlorofluoromethane ND ug/L 06/19/15 04:29 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 06/19/15 04:29 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 06/19/15 04:29 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 06/19/15 04:29 108-67-80.50 1
Vinyl chloride ND ug/L 06/19/15 04:29 75-01-41.0 1
m&p-Xylene ND ug/L 06/19/15 04:29 179601-23-11.0 1
o-Xylene ND ug/L 06/19/15 04:29 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)100 %06/19/15 04:29 17060-07-070-130 1
4-Bromofluorobenzene (S)99 %06/19/15 04:29 460-00-470-130 1
Toluene-d8 (S)100 %06/19/15 04:29 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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[phone]
Page 15 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Sample:WSW-5 Lab ID:92254444007 Collected:06/11/15 14:10 Received:06/15/15 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 06/19/15 02:16 71-43-20.50 1
Bromobenzene ND ug/L 06/19/15 02:16 108-86-10.50 1
Bromochloromethane ND ug/L 06/19/15 02:16 74-97-50.50 1
Bromodichloromethane ND ug/L 06/19/15 02:16 75-27-40.50 1
Bromoform ND ug/L 06/19/15 02:16 75-25-20.50 1
Bromomethane ND ug/L 06/19/15 02:16 74-83-95.0 1
n-Butylbenzene ND ug/L 06/19/15 02:16 104-51-80.50 1
sec-Butylbenzene ND ug/L 06/19/15 02:16 135-98-80.50 1
tert-Butylbenzene ND ug/L 06/19/15 02:16 98-06-60.50 1
Carbon tetrachloride ND ug/L 06/19/15 02:16 56-23-50.50 1
Chlorobenzene ND ug/L 06/19/15 02:16 108-90-70.50 1
Chloroethane ND ug/L 06/19/15 02:16 75-00-31.0 1
Chloroform ND ug/L 06/19/15 02:16 67-66-30.50 1
Chloromethane ND ug/L 06/19/15 02:16 74-87-31.0 1
2-Chlorotoluene ND ug/L 06/19/15 02:16 95-49-80.50 1
4-Chlorotoluene ND ug/L 06/19/15 02:16 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 06/19/15 02:16 96-12-81.0 1
Dibromochloromethane ND ug/L 06/19/15 02:16 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 06/19/15 02:16 106-93-40.50 1
Dibromomethane ND ug/L 06/19/15 02:16 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 06/19/15 02:16 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 06/19/15 02:16 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 06/19/15 02:16 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 06/19/15 02:16 75-71-80.50 1
1,1-Dichloroethane ND ug/L 06/19/15 02:16 75-34-30.50 1
1,2-Dichloroethane ND ug/L 06/19/15 02:16 107-06-20.50 1
1,1-Dichloroethene ND ug/L 06/19/15 02:16 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 06/19/15 02:16 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 06/19/15 02:16 156-60-50.50 1
1,2-Dichloropropane 2.1 ug/L 06/19/15 02:16 78-87-50.50 1
1,3-Dichloropropane ND ug/L 06/19/15 02:16 142-28-90.50 1
2,2-Dichloropropane ND ug/L 06/19/15 02:16 594-20-70.50 1
1,1-Dichloropropene ND ug/L 06/19/15 02:16 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 06/19/15 02:16 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 06/19/15 02:16 10061-02-60.50 1
Diisopropyl ether ND ug/L 06/19/15 02:16 108-20-30.50 1
Ethylbenzene ND ug/L 06/19/15 02:16 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 06/19/15 02:16 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 06/19/15 02:16 98-82-80.50 1
Methylene Chloride ND ug/L 06/19/15 02:16 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 06/19/15 02:16 1634-04-40.50 1
Naphthalene ND ug/L 06/19/15 02:16 91-20-32.0 1
n-Propylbenzene ND ug/L 06/19/15 02:16 103-65-10.50 1
Styrene ND ug/L 06/19/15 02:16 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 06/19/15 02:16 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 06/19/15 02:16 79-34-50.50 1
Tetrachloroethene ND ug/L 06/19/15 02:16 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Sample:WSW-5 Lab ID:92254444007 Collected:06/11/15 14:10 Received:06/15/15 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B6200B MSV
Toluene ND ug/L 06/19/15 02:16 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 06/19/15 02:16 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 06/19/15 02:16 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 06/19/15 02:16 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 06/19/15 02:16 79-00-50.50 1
Trichloroethene ND ug/L 06/19/15 02:16 79-01-60.50 1
Trichlorofluoromethane ND ug/L 06/19/15 02:16 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 06/19/15 02:16 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 06/19/15 02:16 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 06/19/15 02:16 108-67-80.50 1
Vinyl chloride ND ug/L 06/19/15 02:16 75-01-41.0 1
m&p-Xylene ND ug/L 06/19/15 02:16 179601-23-11.0 1
o-Xylene ND ug/L 06/19/15 02:16 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)100 %06/19/15 02:16 17060-07-070-130 1
4-Bromofluorobenzene (S)101 %06/19/15 02:16 460-00-470-130 1
Toluene-d8 (S)101 %06/19/15 02:16 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Sample:WSW-4 Lab ID:92254444008 Collected:06/11/15 15:15 Received:06/15/15 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 06/19/15 02:33 71-43-20.50 1
Bromobenzene ND ug/L 06/19/15 02:33 108-86-10.50 1
Bromochloromethane ND ug/L 06/19/15 02:33 74-97-50.50 1
Bromodichloromethane 12.4 ug/L 06/19/15 02:33 75-27-40.50 1
Bromoform ND ug/L 06/19/15 02:33 75-25-20.50 1
Bromomethane ND ug/L 06/19/15 02:33 74-83-9 M15.0 1
n-Butylbenzene ND ug/L 06/19/15 02:33 104-51-8 M1,R10.50 1
sec-Butylbenzene ND ug/L 06/19/15 02:33 135-98-8 M1,R10.50 1
tert-Butylbenzene ND ug/L 06/19/15 02:33 98-06-6 M10.50 1
Carbon tetrachloride ND ug/L 06/19/15 02:33 56-23-50.50 1
Chlorobenzene ND ug/L 06/19/15 02:33 108-90-70.50 1
Chloroethane ND ug/L 06/19/15 02:33 75-00-31.0 1
Chloroform 24.1 ug/L 06/19/15 02:33 67-66-30.50 1
Chloromethane ND ug/L 06/19/15 02:33 74-87-31.0 1
2-Chlorotoluene ND ug/L 06/19/15 02:33 95-49-8 M10.50 1
4-Chlorotoluene ND ug/L 06/19/15 02:33 106-43-4 M10.50 1
1,2-Dibromo-3-chloropropane ND ug/L 06/19/15 02:33 96-12-81.0 1
Dibromochloromethane 4.6 ug/L 06/19/15 02:33 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 06/19/15 02:33 106-93-40.50 1
Dibromomethane ND ug/L 06/19/15 02:33 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 06/19/15 02:33 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 06/19/15 02:33 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 06/19/15 02:33 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 06/19/15 02:33 75-71-80.50 1
1,1-Dichloroethane ND ug/L 06/19/15 02:33 75-34-30.50 1
1,2-Dichloroethane ND ug/L 06/19/15 02:33 107-06-20.50 1
1,1-Dichloroethene ND ug/L 06/19/15 02:33 75-35-4 M10.50 1
cis-1,2-Dichloroethene ND ug/L 06/19/15 02:33 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 06/19/15 02:33 156-60-50.50 1
1,2-Dichloropropane ND ug/L 06/19/15 02:33 78-87-50.50 1
1,3-Dichloropropane ND ug/L 06/19/15 02:33 142-28-90.50 1
2,2-Dichloropropane ND ug/L 06/19/15 02:33 594-20-70.50 1
1,1-Dichloropropene ND ug/L 06/19/15 02:33 563-58-6 M10.50 1
cis-1,3-Dichloropropene ND ug/L 06/19/15 02:33 10061-01-5 M10.50 1
trans-1,3-Dichloropropene ND ug/L 06/19/15 02:33 10061-02-6 M10.50 1
Diisopropyl ether ND ug/L 06/19/15 02:33 108-20-30.50 1
Ethylbenzene ND ug/L 06/19/15 02:33 100-41-4 M1,R10.50 1
Hexachloro-1,3-butadiene ND ug/L 06/19/15 02:33 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 06/19/15 02:33 98-82-8 M1,R10.50 1
Methylene Chloride ND ug/L 06/19/15 02:33 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 06/19/15 02:33 1634-04-40.50 1
Naphthalene ND ug/L 06/19/15 02:33 91-20-3 M12.0 1
n-Propylbenzene ND ug/L 06/19/15 02:33 103-65-1 M1,R10.50 1
Styrene ND ug/L 06/19/15 02:33 100-42-5 M10.50 1
1,1,1,2-Tetrachloroethane ND ug/L 06/19/15 02:33 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 06/19/15 02:33 79-34-50.50 1
Tetrachloroethene ND ug/L 06/19/15 02:33 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Sample:WSW-4 Lab ID:92254444008 Collected:06/11/15 15:15 Received:06/15/15 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B6200B MSV
Toluene ND ug/L 06/19/15 02:33 108-88-3 M1,R10.50 1
1,2,3-Trichlorobenzene ND ug/L 06/19/15 02:33 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 06/19/15 02:33 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 06/19/15 02:33 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 06/19/15 02:33 79-00-50.50 1
Trichloroethene ND ug/L 06/19/15 02:33 79-01-60.50 1
Trichlorofluoromethane ND ug/L 06/19/15 02:33 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 06/19/15 02:33 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 06/19/15 02:33 95-63-6 M10.50 1
1,3,5-Trimethylbenzene ND ug/L 06/19/15 02:33 108-67-8 M10.50 1
Vinyl chloride ND ug/L 06/19/15 02:33 75-01-4 M11.0 1
m&p-Xylene ND ug/L 06/19/15 02:33 179601-23-1 M11.0 1
o-Xylene ND ug/L 06/19/15 02:33 95-47-6 M10.50 1
Surrogates
1,2-Dichloroethane-d4 (S)99 %06/19/15 02:33 17060-07-070-130 1
4-Bromofluorobenzene (S)100 %06/19/15 02:33 460-00-470-130 1
Toluene-d8 (S)100 %06/19/15 02:33 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/32214
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92254444001, 92254444002, 92254444003, 92254444004, 92254444006, 92254444007, 92254444008
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1488780
Associated Lab Samples:92254444001, 92254444002, 92254444003, 92254444004, 92254444006, 92254444007, 92254444008
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 06/18/15 23:14
1,1,1-Trichloroethane ug/L ND 0.50 06/18/15 23:14
1,1,2,2-Tetrachloroethane ug/L ND 0.50 06/18/15 23:14
1,1,2-Trichloroethane ug/L ND 0.50 06/18/15 23:14
1,1-Dichloroethane ug/L ND 0.50 06/18/15 23:14
1,1-Dichloroethene ug/L ND 0.50 06/18/15 23:14
1,1-Dichloropropene ug/L ND 0.50 06/18/15 23:14
1,2,3-Trichlorobenzene ug/L ND 2.0 06/18/15 23:14
1,2,3-Trichloropropane ug/L ND 0.50 06/18/15 23:14
1,2,4-Trichlorobenzene ug/L ND 2.0 06/18/15 23:14
1,2,4-Trimethylbenzene ug/L ND 0.50 06/18/15 23:14
1,2-Dibromo-3-chloropropane ug/L ND 1.0 06/18/15 23:14
1,2-Dibromoethane (EDB)ug/L ND 0.50 06/18/15 23:14
1,2-Dichlorobenzene ug/L ND 0.50 06/18/15 23:14
1,2-Dichloroethane ug/L ND 0.50 06/18/15 23:14
1,2-Dichloropropane ug/L ND 0.50 06/18/15 23:14
1,3,5-Trimethylbenzene ug/L ND 0.50 06/18/15 23:14
1,3-Dichlorobenzene ug/L ND 0.50 06/18/15 23:14
1,3-Dichloropropane ug/L ND 0.50 06/18/15 23:14
1,4-Dichlorobenzene ug/L ND 0.50 06/18/15 23:14
2,2-Dichloropropane ug/L ND 0.50 06/18/15 23:14
2-Chlorotoluene ug/L ND 0.50 06/18/15 23:14
4-Chlorotoluene ug/L ND 0.50 06/18/15 23:14
Benzene ug/L ND 0.50 06/18/15 23:14
Bromobenzene ug/L ND 0.50 06/18/15 23:14
Bromochloromethane ug/L ND 0.50 06/18/15 23:14
Bromodichloromethane ug/L ND 0.50 06/18/15 23:14
Bromoform ug/L ND 0.50 06/18/15 23:14
Bromomethane ug/L ND 5.0 06/18/15 23:14
Carbon tetrachloride ug/L ND 0.50 06/18/15 23:14
Chlorobenzene ug/L ND 0.50 06/18/15 23:14
Chloroethane ug/L ND 1.0 06/18/15 23:14
Chloroform ug/L ND 0.50 06/18/15 23:14
Chloromethane ug/L ND 1.0 06/18/15 23:14
cis-1,2-Dichloroethene ug/L ND 0.50 06/18/15 23:14
cis-1,3-Dichloropropene ug/L ND 0.50 06/18/15 23:14
Dibromochloromethane ug/L ND 0.50 06/18/15 23:14
Dibromomethane ug/L ND 0.50 06/18/15 23:14
Dichlorodifluoromethane ug/L ND 0.50 06/18/15 23:14
Diisopropyl ether ug/L ND 0.50 06/18/15 23:14
Ethylbenzene ug/L ND 0.50 06/18/15 23:14
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1488780
Associated Lab Samples:92254444001, 92254444002, 92254444003, 92254444004, 92254444006, 92254444007, 92254444008
Matrix:Water
Analyzed
Hexachloro-1,3-butadiene ug/L ND 2.0 06/18/15 23:14
Isopropylbenzene (Cumene)ug/L ND 0.50 06/18/15 23:14
m&p-Xylene ug/L ND 1.0 06/18/15 23:14
Methyl-tert-butyl ether ug/L ND 0.50 06/18/15 23:14
Methylene Chloride ug/L ND 2.0 06/18/15 23:14
n-Butylbenzene ug/L ND 0.50 06/18/15 23:14
n-Propylbenzene ug/L ND 0.50 06/18/15 23:14
Naphthalene ug/L ND 2.0 06/18/15 23:14
o-Xylene ug/L ND 0.50 06/18/15 23:14
sec-Butylbenzene ug/L ND 0.50 06/18/15 23:14
Styrene ug/L ND 0.50 06/18/15 23:14
tert-Butylbenzene ug/L ND 0.50 06/18/15 23:14
Tetrachloroethene ug/L ND 0.50 06/18/15 23:14
Toluene ug/L ND 0.50 06/18/15 23:14
trans-1,2-Dichloroethene ug/L ND 0.50 06/18/15 23:14
trans-1,3-Dichloropropene ug/L ND 0.50 06/18/15 23:14
Trichloroethene ug/L ND 0.50 06/18/15 23:14
Trichlorofluoromethane ug/L ND 1.0 06/18/15 23:14
Vinyl chloride ug/L ND 1.0 06/18/15 23:14
1,2-Dichloroethane-d4 (S)%98 70-130 06/18/15 23:14
4-Bromofluorobenzene (S)%100 70-130 06/18/15 23:14
Toluene-d8 (S)%101 70-130 06/18/15 23:14
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1488781LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 51.650 103 60-140
1,1,1-Trichloroethane ug/L 52.850 106 60-140
1,1,2,2-Tetrachloroethane ug/L 53.150 106 60-140
1,1,2-Trichloroethane ug/L 50.750 101 60-140
1,1-Dichloroethane ug/L 52.050 104 60-140
1,1-Dichloroethene ug/L 56.750 113 60-140
1,1-Dichloropropene ug/L 55.250 110 60-140
1,2,3-Trichlorobenzene ug/L 53.250 106 60-140
1,2,3-Trichloropropane ug/L 51.450 103 60-140
1,2,4-Trichlorobenzene ug/L 52.850 106 60-140
1,2,4-Trimethylbenzene ug/L 54.250 108 60-140
1,2-Dibromo-3-chloropropane ug/L 54.050 108 60-140
1,2-Dibromoethane (EDB)ug/L 54.050 108 60-140
1,2-Dichlorobenzene ug/L 54.750 109 60-140
1,2-Dichloroethane ug/L 49.650 99 60-140
1,2-Dichloropropane ug/L 50.850 102 60-140
1,3,5-Trimethylbenzene ug/L 55.350 111 60-140
1,3-Dichlorobenzene ug/L 53.850 108 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1488781LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichloropropane ug/L 52.150 104 60-140
1,4-Dichlorobenzene ug/L 52.850 106 60-140
2,2-Dichloropropane ug/L 45.150 90 60-140
2-Chlorotoluene ug/L 55.350 111 60-140
4-Chlorotoluene ug/L 54.050 108 60-140
Benzene ug/L 53.450 107 60-140
Bromobenzene ug/L 51.150 102 60-140
Bromochloromethane ug/L 56.050 112 60-140
Bromodichloromethane ug/L 52.150 104 60-140
Bromoform ug/L 47.450 95 60-140
Bromomethane ug/L 37.750 75 60-140
Carbon tetrachloride ug/L 53.850 108 60-140
Chlorobenzene ug/L 52.650 105 60-140
Chloroethane ug/L 48.850 98 60-140
Chloroform ug/L 52.850 106 60-140
Chloromethane ug/L 44.750 89 60-140
cis-1,2-Dichloroethene ug/L 52.350 105 60-140
cis-1,3-Dichloropropene ug/L 51.050 102 60-140
Dibromochloromethane ug/L 51.850 104 60-140
Dibromomethane ug/L 52.850 106 60-140
Dichlorodifluoromethane ug/L 51.850 104 60-140
Diisopropyl ether ug/L 52.050 104 60-140
Ethylbenzene ug/L 52.150 104 60-140
Hexachloro-1,3-butadiene ug/L 60.350 121 60-140
Isopropylbenzene (Cumene)ug/L 57.450 115 60-140
m&p-Xylene ug/L 103100 103 60-140
Methyl-tert-butyl ether ug/L 48.750 97 60-140
Methylene Chloride ug/L 51.350 103 60-140
n-Butylbenzene ug/L 54.250 108 60-140
n-Propylbenzene ug/L 54.550 109 60-140
Naphthalene ug/L 56.250 112 60-140
o-Xylene ug/L 52.750 105 60-140
sec-Butylbenzene ug/L 56.750 113 60-140
Styrene ug/L 54.650 109 60-140
tert-Butylbenzene ug/L 45.950 92 60-140
Tetrachloroethene ug/L 50.950 102 60-140
Toluene ug/L 50.550 101 60-140
trans-1,2-Dichloroethene ug/L 52.950 106 60-140
trans-1,3-Dichloropropene ug/L 50.950 102 60-140
Trichloroethene ug/L 50.350 101 60-140
Trichlorofluoromethane ug/L 47.350 95 60-140
Vinyl chloride ug/L 48.850 98 60-140
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%98 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1488782MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92254444008
1488783
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 109 60-140111 220ND21.7 22.1
1,1,1-Trichloroethane ug/L 20 118 60-140121 220ND23.6 24.2
1,1,2,2-Tetrachloroethane ug/L 20 113 60-140115 220ND22.5 22.9
1,1,2-Trichloroethane ug/L 20 108 60-140109 220ND21.5 21.9
1,1-Dichloroethane ug/L 20 114 60-140115 120ND22.7 23.0
1,1-Dichloroethene ug/L M1205060-14064 2520ND9.9 12.8
1,1-Dichloropropene ug/L M120060-140220NDND.38J
1,2,3-Trichlorobenzene ug/L 20 108 60-140116 720ND21.6 23.3
1,2,3-Trichloropropane ug/L 20 116 60-140117 120ND23.2 23.4
1,2,4-Trichlorobenzene ug/L 20 106 60-140114 720ND21.3 22.8
1,2,4-Trimethylbenzene ug/L M120060-140020NDNDND
1,2-Dibromo-3-chloropropane ug/L 20 106 60-140109 220ND21.3 21.8
1,2-Dibromoethane (EDB)ug/L 20 116 60-140117 120ND23.2 23.5
1,2-Dichlorobenzene ug/L 20 116 60-140121 420ND23.2 24.2
1,2-Dichloroethane ug/L 20 107 60-140110 320ND21.4 22.0
1,2-Dichloropropane ug/L 20 113 60-140115 220ND22.5 23.0
1,3,5-Trimethylbenzene ug/L M120060-140020NDNDND
1,3-Dichlorobenzene ug/L 20 115 60-140120 420ND23.1 24.1
1,3-Dichloropropane ug/L 20 112 60-140115 320ND22.5 23.1
1,4-Dichlorobenzene ug/L 20 113 60-140120 520ND22.7 23.9
2,2-Dichloropropane ug/L 20 94 60-14095 220ND18.7 19.0
2-Chlorotoluene ug/L M12022060-140226 320ND44.1 45.2
4-Chlorotoluene ug/L M12016060-140165 320ND32.0 33.0
Benzene ug/L 20 118 60-140122 420ND23.6 24.5
Bromobenzene ug/L 20 101 60-140107 520ND20.2 21.3
Bromochloromethane ug/L 20 123 60-140126 220ND24.7 25.3
Bromodichloromethane ug/L 20 119 60-140124 32012.4 36.2 37.2
Bromoform ug/L 20 89 60-14090 220ND17.8 18.1
Bromomethane ug/L M1204260-14052 2120ND8.4 10.4
Carbon tetrachloride ug/L 20 117 60-140121 320ND23.3 24.1
Chlorobenzene ug/L 20 119 60-140122 320ND23.7 24.4
Chloroethane ug/L 20 112 60-140111 120ND22.4 22.2
Chloroform ug/L 20 122 60-140123 12024.1 48.4 48.8
Chloromethane ug/L 20 126 60-140133 520ND25.1 26.5
cis-1,2-Dichloroethene ug/L 20 116 60-140120 420ND23.2 24.0
cis-1,3-Dichloropropene ug/L M1203660-14047 2620ND7.2 9.3
Dibromochloromethane ug/L 20 105 60-140114 6204.6 25.6 27.3
Dibromomethane ug/L 20 115 60-140117 220ND22.9 23.4
Dichlorodifluoromethane ug/L 20 117 60-140120 320ND23.4 24.0
Diisopropyl ether ug/L 20 114 60-140115 120ND22.8 23.0
Ethylbenzene ug/L M1,R1201360-14022 5120ND2.5 4.3
Hexachloro-1,3-butadiene ug/L 20 135 60-140135 020ND26.9 27.0
Isopropylbenzene (Cumene)ug/L M1,R1202660-14038 3620ND5.2 7.6
m&p-Xylene ug/L M140060-140040NDNDND
Methyl-tert-butyl ether ug/L 20 105 60-140107 220ND20.9 21.4
Methylene Chloride ug/L 20 109 60-140120 1020ND21.7 24.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1488782MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92254444008
1488783
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Butylbenzene ug/L M1,R1201160-14019 5420ND2.2 3.9
n-Propylbenzene ug/L M1,R1201460-14023 5020ND2.8 4.6
Naphthalene ug/L M120060-140020NDNDND
o-Xylene ug/L M120060-140020NDNDND
sec-Butylbenzene ug/L M1,R1202460-14036 4020ND4.8 7.2
Styrene ug/L M120060-140020NDNDND
tert-Butylbenzene ug/L M1203860-14050 2820ND7.6 10.1
Tetrachloroethene ug/L 20 116 60-140120 320ND23.2 23.9
Toluene ug/L M1,R120860-14014 5920ND1.5 2.8
trans-1,2-Dichloroethene ug/L 20 120 60-140122 220ND24.1 24.5
trans-1,3-Dichloropropene ug/L M1203760-14048 2720ND7.4 9.7
Trichloroethene ug/L 20 118 60-140120 120ND23.6 24.0
Trichlorofluoromethane ug/L 20 109 60-140110 220ND21.7 22.1
Vinyl chloride ug/L M120060-140020NDNDND
1,2-Dichloroethane-d4 (S)%98 70-13097
4-Bromofluorobenzene (S)%101 70-130100
Toluene-d8 (S)%99 70-130101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/32225
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92254444005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1489896
Associated Lab Samples:92254444005
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 06/19/15 16:21
1,1,1-Trichloroethane ug/L ND 0.50 06/19/15 16:21
1,1,2,2-Tetrachloroethane ug/L ND 0.50 06/19/15 16:21
1,1,2-Trichloroethane ug/L ND 0.50 06/19/15 16:21
1,1-Dichloroethane ug/L ND 0.50 06/19/15 16:21
1,1-Dichloroethene ug/L ND 0.50 06/19/15 16:21
1,1-Dichloropropene ug/L ND 0.50 06/19/15 16:21
1,2,3-Trichlorobenzene ug/L ND 2.0 06/19/15 16:21
1,2,3-Trichloropropane ug/L ND 0.50 06/19/15 16:21
1,2,4-Trichlorobenzene ug/L ND 2.0 06/19/15 16:21
1,2,4-Trimethylbenzene ug/L ND 0.50 06/19/15 16:21
1,2-Dibromo-3-chloropropane ug/L ND 1.0 06/19/15 16:21
1,2-Dibromoethane (EDB)ug/L ND 0.50 06/19/15 16:21
1,2-Dichlorobenzene ug/L ND 0.50 06/19/15 16:21
1,2-Dichloroethane ug/L ND 0.50 06/19/15 16:21
1,2-Dichloropropane ug/L ND 0.50 06/19/15 16:21
1,3,5-Trimethylbenzene ug/L ND 0.50 06/19/15 16:21
1,3-Dichlorobenzene ug/L ND 0.50 06/19/15 16:21
1,3-Dichloropropane ug/L ND 0.50 06/19/15 16:21
1,4-Dichlorobenzene ug/L ND 0.50 06/19/15 16:21
2,2-Dichloropropane ug/L ND 0.50 06/19/15 16:21
2-Chlorotoluene ug/L ND 0.50 06/19/15 16:21
4-Chlorotoluene ug/L ND 0.50 06/19/15 16:21
Benzene ug/L ND 0.50 06/19/15 16:21
Bromobenzene ug/L ND 0.50 06/19/15 16:21
Bromochloromethane ug/L ND 0.50 06/19/15 16:21
Bromodichloromethane ug/L ND 0.50 06/19/15 16:21
Bromoform ug/L ND 0.50 06/19/15 16:21
Bromomethane ug/L ND 5.0 06/19/15 16:21
Carbon tetrachloride ug/L ND 0.50 06/19/15 16:21
Chlorobenzene ug/L ND 0.50 06/19/15 16:21
Chloroethane ug/L ND 1.0 06/19/15 16:21
Chloroform ug/L ND 0.50 06/19/15 16:21
Chloromethane ug/L ND 1.0 06/19/15 16:21
cis-1,2-Dichloroethene ug/L ND 0.50 06/19/15 16:21
cis-1,3-Dichloropropene ug/L ND 0.50 06/19/15 16:21
Dibromochloromethane ug/L ND 0.50 06/19/15 16:21
Dibromomethane ug/L ND 0.50 06/19/15 16:21
Dichlorodifluoromethane ug/L ND 0.50 06/19/15 16:21
Diisopropyl ether ug/L ND 0.50 06/19/15 16:21
Ethylbenzene ug/L ND 0.50 06/19/15 16:21
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1489896
Associated Lab Samples:92254444005
Matrix:Water
Analyzed
Hexachloro-1,3-butadiene ug/L ND 2.0 06/19/15 16:21
Isopropylbenzene (Cumene)ug/L ND 0.50 06/19/15 16:21
m&p-Xylene ug/L ND 1.0 06/19/15 16:21
Methyl-tert-butyl ether ug/L ND 0.50 06/19/15 16:21
Methylene Chloride ug/L ND 2.0 06/19/15 16:21
n-Butylbenzene ug/L ND 0.50 06/19/15 16:21
n-Propylbenzene ug/L ND 0.50 06/19/15 16:21
Naphthalene ug/L ND 2.0 06/19/15 16:21
o-Xylene ug/L ND 0.50 06/19/15 16:21
sec-Butylbenzene ug/L ND 0.50 06/19/15 16:21
Styrene ug/L ND 0.50 06/19/15 16:21
tert-Butylbenzene ug/L ND 0.50 06/19/15 16:21
Tetrachloroethene ug/L ND 0.50 06/19/15 16:21
Toluene ug/L ND 0.50 06/19/15 16:21
trans-1,2-Dichloroethene ug/L ND 0.50 06/19/15 16:21
trans-1,3-Dichloropropene ug/L ND 0.50 06/19/15 16:21
Trichloroethene ug/L ND 0.50 06/19/15 16:21
Trichlorofluoromethane ug/L ND 1.0 06/19/15 16:21
Vinyl chloride ug/L ND 1.0 06/19/15 16:21
1,2-Dichloroethane-d4 (S)%99 70-130 06/19/15 16:21
4-Bromofluorobenzene (S)%101 70-130 06/19/15 16:21
Toluene-d8 (S)%99 70-130 06/19/15 16:21
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1489897LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 51.550 103 60-140
1,1,1-Trichloroethane ug/L 54.350 109 60-140
1,1,2,2-Tetrachloroethane ug/L 52.450 105 60-140
1,1,2-Trichloroethane ug/L 50.750 101 60-140
1,1-Dichloroethane ug/L 54.050 108 60-140
1,1-Dichloroethene ug/L 58.050 116 60-140
1,1-Dichloropropene ug/L 57.550 115 60-140
1,2,3-Trichlorobenzene ug/L 52.150 104 60-140
1,2,3-Trichloropropane ug/L 52.350 105 60-140
1,2,4-Trichlorobenzene ug/L 52.150 104 60-140
1,2,4-Trimethylbenzene ug/L 55.350 111 60-140
1,2-Dibromo-3-chloropropane ug/L 52.050 104 60-140
1,2-Dibromoethane (EDB)ug/L 54.250 108 60-140
1,2-Dichlorobenzene ug/L 54.350 109 60-140
1,2-Dichloroethane ug/L 49.950 100 60-140
1,2-Dichloropropane ug/L 52.250 104 60-140
1,3,5-Trimethylbenzene ug/L 55.750 111 60-140
1,3-Dichlorobenzene ug/L 54.150 108 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1489897LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichloropropane ug/L 52.250 104 60-140
1,4-Dichlorobenzene ug/L 53.150 106 60-140
2,2-Dichloropropane ug/L 55.250 110 60-140
2-Chlorotoluene ug/L 54.550 109 60-140
4-Chlorotoluene ug/L 55.050 110 60-140
Benzene ug/L 54.750 109 60-140
Bromobenzene ug/L 54.450 109 60-140
Bromochloromethane ug/L 57.550 115 60-140
Bromodichloromethane ug/L 52.950 106 60-140
Bromoform ug/L 47.750 95 60-140
Bromomethane ug/L 39.050 78 60-140
Carbon tetrachloride ug/L 54.950 110 60-140
Chlorobenzene ug/L 53.150 106 60-140
Chloroethane ug/L 47.850 96 60-140
Chloroform ug/L 54.250 108 60-140
Chloromethane ug/L 40.850 82 60-140
cis-1,2-Dichloroethene ug/L 54.550 109 60-140
cis-1,3-Dichloropropene ug/L 51.850 104 60-140
Dibromochloromethane ug/L 51.250 102 60-140
Dibromomethane ug/L 52.750 105 60-140
Dichlorodifluoromethane ug/L 50.150 100 60-140
Diisopropyl ether ug/L 52.750 105 60-140
Ethylbenzene ug/L 52.650 105 60-140
Hexachloro-1,3-butadiene ug/L 58.850 118 60-140
Isopropylbenzene (Cumene)ug/L 58.750 117 60-140
m&p-Xylene ug/L 105100 105 60-140
Methyl-tert-butyl ether ug/L 49.550 99 60-140
Methylene Chloride ug/L 50.550 101 60-140
n-Butylbenzene ug/L 55.350 111 60-140
n-Propylbenzene ug/L 55.650 111 60-140
Naphthalene ug/L 54.350 109 60-140
o-Xylene ug/L 53.650 107 60-140
sec-Butylbenzene ug/L 56.850 114 60-140
Styrene ug/L 55.250 110 60-140
tert-Butylbenzene ug/L 45.650 91 60-140
Tetrachloroethene ug/L 52.550 105 60-140
Toluene ug/L 52.550 105 60-140
trans-1,2-Dichloroethene ug/L 55.650 111 60-140
trans-1,3-Dichloropropene ug/L 52.350 105 60-140
Trichloroethene ug/L 51.850 104 60-140
Trichlorofluoromethane ug/L 48.150 96 60-140
Vinyl chloride ug/L 49.350 99 60-140
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1489898MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92253831006
1489899
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 106 60-140113 620ND21.3 22.7
1,1,1-Trichloroethane ug/L 20 117 60-140122 420ND23.4 24.3
1,1,2,2-Tetrachloroethane ug/L 20 113 60-140115 220ND22.6 23.1
1,1,2-Trichloroethane ug/L 20 108 60-140110 220ND21.6 22.1
1,1-Dichloroethane ug/L 20 116 60-140122 520ND23.2 24.4
1,1-Dichloroethene ug/L 20 131 60-140134 220ND26.2 26.8
1,1-Dichloropropene ug/L 20 127 60-140129 220ND25.4 25.8
1,2,3-Trichlorobenzene ug/L 20 106 60-140109 320ND21.3 21.8
1,2,3-Trichloropropane ug/L 20 115 60-140115 020ND22.9 22.9
1,2,4-Trichlorobenzene ug/L 20 104 60-140107 320ND20.9 21.5
1,2,4-Trimethylbenzene ug/L 20 119 60-140121 120ND23.8 24.1
1,2-Dibromo-3-chloropropane ug/L 20 100 60-140101 020ND20.0 20.1
1,2-Dibromoethane (EDB)ug/L 20 113 60-140117 420ND22.6 23.4
1,2-Dichlorobenzene ug/L 20 117 60-140120 220ND23.5 23.9
1,2-Dichloroethane ug/L 20 108 60-140113 420ND21.7 22.6
1,2-Dichloropropane ug/L 20 111 60-140115 420ND22.2 23.1
1,3,5-Trimethylbenzene ug/L 20 122 60-140125 220ND24.5 24.9
1,3-Dichlorobenzene ug/L 20 118 60-140120 220ND23.6 24.0
1,3-Dichloropropane ug/L 20 111 60-140117 520ND22.2 23.3
1,4-Dichlorobenzene ug/L 20 115 60-140116 120ND22.9 23.2
2,2-Dichloropropane ug/L 20 110 60-140116 520ND22.1 23.1
2-Chlorotoluene ug/L 20 122 60-140126 320ND24.4 25.1
4-Chlorotoluene ug/L 20 118 60-140121 220ND23.7 24.2
Benzene ug/L 20 119 60-140123 320ND23.9 24.6
Bromobenzene ug/L 20 119 60-140122 220ND23.9 24.5
Bromochloromethane ug/L 20 122 60-140125 220ND24.5 25.0
Bromodichloromethane ug/L 20 106 60-140110 320ND21.3 22.0
Bromoform ug/L 20 88 60-14091 320ND17.6 18.2
Bromomethane ug/L 20 71 60-14082 1420ND14.2 16.4
Carbon tetrachloride ug/L 20 118 60-140123 420ND23.6 24.6
Chlorobenzene ug/L 20 115 60-140120 420ND23.1 23.9
Chloroethane ug/L 20 100 60-140113 1120ND20.1 22.5
Chloroform ug/L 20 116 60-140121 520ND23.1 24.2
Chloromethane ug/L 20 90 60-14097 820ND18.0 19.4
cis-1,2-Dichloroethene ug/L 20 117 60-140123 520ND23.4 24.5
cis-1,3-Dichloropropene ug/L 20 105 60-140110 420ND21.0 21.9
Dibromochloromethane ug/L 20 97 60-140104 620ND19.5 20.7
Dibromomethane ug/L 20 111 60-140115 420ND22.1 23.1
Dichlorodifluoromethane ug/L 20 109 60-140112 320ND21.7 22.3
Diisopropyl ether ug/L 20 112 60-140118 520ND22.4 23.6
Ethylbenzene ug/L 20 116 60-140121 420ND23.3 24.2
Hexachloro-1,3-butadiene ug/L 20 125 60-140134 720ND25.0 26.9
Isopropylbenzene (Cumene)ug/L 20 129 60-140135 420ND25.9 27.0
m&p-Xylene ug/L 40 115 60-140119 340ND45.9 47.6
Methyl-tert-butyl ether ug/L 20 104 60-140108 420ND20.8 21.6
Methylene Chloride ug/L 20 112 60-140123 920ND22.5 24.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1489898MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92253831006
1489899
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Butylbenzene ug/L 20 118 60-140119 020ND23.7 23.8
n-Propylbenzene ug/L 20 123 60-140125 120ND24.7 25.0
Naphthalene ug/L 20 108 60-140112 420ND21.6 22.4
o-Xylene ug/L 20 115 60-140120 520ND22.9 24.0
sec-Butylbenzene ug/L 20 125 60-140127 120ND25.0 25.3
Styrene ug/L 20 116 60-140120 320ND23.2 24.0
tert-Butylbenzene ug/L 20 103 60-140103 020ND20.6 20.5
Tetrachloroethene ug/L 20 114 60-140119 520ND22.8 23.8
Toluene ug/L 20 114 60-140117 320ND22.8 23.5
trans-1,2-Dichloroethene ug/L 20 121 60-140128 620ND24.2 25.6
trans-1,3-Dichloropropene ug/L 20 105 60-140108 320ND21.0 21.5
Trichloroethene ug/L 20 112 60-140118 520ND22.4 23.7
Trichlorofluoromethane ug/L 20 108 60-140113 520ND21.6 22.6
Vinyl chloride ug/L 20 108 60-140116 720ND21.6 23.2
1,2-Dichloroethane-d4 (S)%98 70-130100
4-Bromofluorobenzene (S)%101 70-130103
Toluene-d8 (S)%99 70-13099
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 33
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 33
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92254444
FLOWERS STORE 21858-A
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92254444001 MSV/32214MW-3 SM 6200B
92254444002 MSV/32214MW-5 SM 6200B
92254444003 MSV/32214MW-7 SM 6200B
92254444004 MSV/32214MW-8 SM 6200B
92254444005 MSV/32225MW-9 SM 6200B
92254444006 MSV/32214MW-10 SM 6200B
92254444007 MSV/32214WSW-5 SM 6200B
92254444008 MSV/32214WSW-4 SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2015 05:44 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 33
Page 32 of 33
Page 33 of 33

APPENDIX D

APPENDIX E
SITE PHOTOGRAPHS
FLOWERS STORE PROPERTY
4181 NC HIGHWAY 42 EAST
CLAYTON, JOHNSON COUNTY, NORTH CAROLINA
NCDENR INCIDENT: 17217
ECS PROJECT NO 06:21858-A
Photograph 1: View of the subject site. View is to the northeast.
Photograph 2: View of the subject site. View is to the west.
SITE PHOTOGRAPHS
FLOWERS STORE PROPERTY
4181 NC HIGHWAY 42 EAST
CLAYTON, JOHNSON COUNTY, NORTH CAROLINA
NCDENR INCIDENT: 17217
ECS PROJECT NO 06:21858-A
Photograph 3: View of monitoring well MW-8.
Photograph 4: View of the installation of monitoring well MW-10. View is to the southwest.
SITE PHOTOGRAPHS
FLOWERS STORE PROPERTY
4181 NC HIGHWAY 42 EAST
CLAYTON, JOHNSON COUNTY, NORTH CAROLINA
NCDENR INCIDENT: 17217
ECS PROJECT NO 06:21858-A
Photograph 5: View of monitoring well MW-3 damaged by bulldozing.
Photograph 6: View of monitoring well MW-3 and bulldozing activity at the site. View is to the north.