FA-916_17217_CA_MRP_20140917_ECS Final Flowers Groundwater Monitoring Report

9001 Glenwood Avenue, Raleigh, NC 27617 • T: 919-861-9910 • F: 800-327-5832 • www.ecslimited.com
ECS Mid-Atlantic, LLC • ECS Carolinas, LLP • ECS Florida, LLC • ECS Illinois, LLC • ECS Southeast, LLC • ECS Texas, LLP

September 17, 2014

Mr. Mark Petermann
NCDENR, Division of Waste Management, UST Section
1637 Mail Service Center
Raleigh, North Carolina 27699-1637

Reference: Groundwater Monitoring Report – Flowers Store Property
4181 NC Highway 42 East
Clayton, Johnston County, North Carolina
NCDENR Incident: 17217
NCDENR Contract: N14007i-C
ECS Project: 06:21858

Dear Mr. Petermann:

As authorized by your acceptance of ECS Carolinas, LLP (ECS) Task Authorization Request #1
dated July 22, 2014, ECS has completed the Groundwater Monitoring Report for the above-
referenced site. Included in this report is a description of the field activities, the results obtained,
and our conclusions and recommendations. Information regarding owner of former UST, current
property owner, contacts, consultant, laboratory, release information, and latitude and longitude
are presented below.

ECS appreciates the opportunity to provide our environmental consulting services to you on this
project. If you have any questions concerning this report or this project, please contact us at (919)
861-9910.

Sincerely,

ECS CAROLINAS, LLP

Matthew Gillis
Staff Environmental Project Manager

C. Brian Smith, P.G.
Manager of Environmental Services / Principal Geologist

Groundwater Monitoring Report – Flowers Store Property
Clayton, Johnston County, North Carolina
NCDENR Incident: 17217
NCDENR Contract: N14007i-C
September 17, 2014

SITE INFORMATION

Date of Report: September 17, 2014

Facility I.D.: Unknown
UST Incident No.: 17217
Site Rank: High
Land Use Category: Vacant – Two vacant buildings are located on the property

Site Name and Location: Flowers Store Property
4181 NC Highway 42 East
Clayton, Johnston County, North Carolina

Location Method: Google Earth
Latitude and Longitude: 36.651793° North, 78.360938° West

Contacts

Owner of UST: Motorcycle Road, LLC.
P.O. Box 1528
Clayton, Johnston County, North Carolina 27528

Primary Contact: Norwood Thompson
Motorcycle Road, LLC.
P.O. Box 1528
Clayton, Johnston County, North Carolina 27528
[phone]
[phone]

Consultant: ECS Carolinas, LLP
9001 Glenwood Avenue
Raleigh, North Carolina 27617
[phone]
Attn: Matthew Gillis

Laboratory: Pace Analytical Services, Inc.
9800 Kincey Ave, Suite 100
Huntersville, North Carolina 28078
[phone]
NC Certification No. 12

Groundwater Monitoring Report – Flowers Store Property
Clayton, Johnston County, North Carolina
NCDENR Incident: 17217
NCDENR Contract: N14007i-C
September 17, 2014

EXECUTIVE SUMMARY

The subject site is known as the Flowers Store Property located at 4181 NC Highway 42 East in
Clayton, Johnston County, North Carolina. The subject site is further identified by Johnston
County Geographic Information Systems (GIS) Parcel Identification Number (PIN) 168900-92-
5990.

On August 13, 2014, ECS collected two groundwater samples from monitoring wells MW-5 and
MW-7. Monitoring well MW-3 was filled with dirt; therefore, a groundwater sample was not
collected. Additionally, ECS collected groundwater samples from water supply wells WSW-4,
WSW-5, and WSW-6. Well construction and groundwater elevation details are provided in
Table 2.

Laboratory analysis of the groundwater sample collected from monitoring well MW-5 detected C9-
C18 Aliphatics and C9-C22 Aromatics at concentrations that exceed their respective North
Carolina Department of Environment and Natural Resources (NCDENR) Final and Interim
Groundwater Quality Standards (GWQS). Neither a North Carolina 2L Groundwater Quality
Standard (NC2LGWQS) nor a NCDENR Gross Contamination Level (GCL) have been
established for these analytes. Additionally, C9-C18 Aliphatics were detected in the groundwater
sample collected from MW-5 at a concentration that exceeds the laboratory reporting limit, but is
below the GWQS. A NC2LGWQS and/or GCL are not established for this analyte. Laboratory
analysis of the groundwater sample collected from monitoring well MW-5 detected lead at a
concentration that exceeds its NC2LGWQS, but is below its respective GCL.

Laboratory analysis of the groundwater sample collected from MW-7 did not detect targeted
analytes above the laboratory reporting limits.

Laboratory analysis of the groundwater sample collected from water supply well WSW-4 detected
bromodichloromethane at a concentration above the laboratory reporting limit; however, neither a
NC2LGWQS nor a GCL have been established for this analyte. Laboratory analysis of the
groundwater sample collected from WSW-4 detected chloroform at a concentration above the
laboratory reporting limit but below its NC2LGWQS. Additionally, dibromochloromethane was
detected at a concentration above its respective NC2LGWQS, but below its respective GCL in the
groundwater sample collected from WSW-4.

Laboratory analysis of the groundwater sample collected from water supply well WSW-5 detected
1,2-Dichloropropane at a concentration above its respective NC2LGWQS, but below its respective
GCL. The laboratory did not detect additional analytes above the laboratory reporting limits.

Laboratory analysis of the groundwater sample collected from water supply well WSW-6 did not
detect targeted analytes above the laboratory reporting limits.

A summary of the laboratory analytical results is included in Table 3.

The laboratory analytical data sheets and chain of custody records (COCs) are included in
Appendix A.
Groundwater Monitoring Report – Flowers Store Property
Clayton, Johnston County, North Carolina
NCDENR Incident: 17217
NCDENR Contract: N14007i-C
September 17, 2014

TABLE OF CONTENTS
SITE HISTORY ............................................................................................................... 1
FIELD ACTIVITIES ......................................................................................................... 4
CONCLUSIONS .............................................................................................................. 5
RECOMMENDATIONS ................................................................................................... 6

FIGURES

Figure 1 Site Location Map
Figure 1A Site Location Map
Figure 2 Monitoring Well Location Map
Figure 3 Groundwater Elevation Map
Figure 4 Groundwater Concentration Map
Figure 5 C9-C18 Aliphatic Isoconcentration Map
Figure 6 C9-C22 Aromatic Isoconcentration Map
Figure 7 Lead Isoconcentration Map
Figure 8 Water Supply Well Location Map
TABLES

Table 1 UST Information
Table 2 Well Construction and Groundwater Elevation Details
Table 3 Summary of Groundwater Analytical Results
Table 4 Summary of Historical Groundwater Analytical Results
Table 5 Summary of Historical Water Supply Well Analytical Results
Table 6 Summary of Historical Soil Sample Analytical Results
Table 7 Water Supply Well Survey

APPENDICIES

Appendix A Laboratory Analytical Data Sheets and Chain of Custody Records
Appendix B Monitoring Well Sampling Worksheets
Appendix C Site Photographs
Groundwater Monitoring Report – Flowers Store Property
Clayton, Johnston County, North Carolina
NCDENR Incident: 17217
NCDENR Contract: N14007i-C
September 17, 2014

1
SITE HISTORY

The subject site is known as the Flowers Store Property located at 4181 NC Highway 42 East in
Clayton, Johnston County, North Carolina (Figures 1 and 1A).

According to a 1994 UST Closure Report prepared by Froehling & Robertson Inc (F&R), the site
was formerly utilized as a gasoline station and auto repair service facility. On August 29, 1994,
one 8,000-gallon gasoline UST (UST-1), one 1,000-gallon kerosene/diesel UST (UST-2), and
one 6,000-gallon diesel UST (UST-3), along with associated piping/equipment were removed by
Action Oil Equipment Company. Based on the analytical results of the soil samples, releases
were detected beneath UST-2 and UST-3. The laboratory detected Total Petroleum
Hydrocarbons – Gasoline Range Organics (TPH-GRO) and TPH-Diesel Range Organics (TPH-
DRO) at concentrations that exceed the North Carolina Department of Environment and Natural
Resources (NCDENR) UST Section’s Action Level of 10 mg/kg. TPH-GRO was detected at
concentrations ranging from 567 mg/kg to 2,900 mg/kg. TPH-DRO concentrations ranged from
18.6 mg/kg to 11,100 mg/kg. Contaminated soils were not removed from the site and
groundwater samples were not collected during UST closure activities.

On February 17, 2006, Agra Environmental, Inc. (AGRA) conducted an Initial Site Visit and Site
Receptor Survey. Agra identified one building on the subject site that was used as a repair
garage and was being used for storage. A sump was observed, which possibly was used as an
oil/water separator, near the rear of the garage. Metal debris, including appliances, tanks, and
vehicles were scattered throughout the wooded area along the northern boundary of the subject
site. AGRA also documented that a UST was discovered near the southeastern corner of the
subject site. AGRA identified four potential water supply wells within 1,500 feet of the subject site.
AGRA also identified a pond located on the adjacent property to the northeast of the site.

A 2006 UST Closure Report, prepared by AGRA, indicates AGRA removed one 1,000-gallon UST
from the southeastern corner of the subject site. AGRA did not observe contaminated soil in the
UST excavation. However, two 55-gallon drums of contaminated soil associated with spillage of
residual sludge from the UST were removed from the subject site. The remaining soils and clean
fill were used to backfill the UST excavation. Soil samples were not collected prior to backfill.

AGRA performed a door-to-door survey of the surrounding area on May 22, 2008. A total of six
water supply wells (WSW-1, WSW-2, WSW-3, WSW-4, WSW-5, and WSW-6) were identified
approximately 525 feet (ft), 525 ft, 1,100 ft, 900 ft, 550 ft, and 1,400 ft from the subject site,
respectively. An interview with the owners of WSW-1 and WSW-4, indicated that both water
supply wells were used as a primary drinking water source and the residence was not connected
to the public water supply at that time. An interview with the owners of WSW-2 and WSW-3,
indicated that both wells were currently disconnected and the properties were connected to the
public water supply. Additionally, two water supply wells (WSW-5 and WSW-6) were observed at
160 Motorcycle Road and 270 Motorcycle Road, respectively. The property owners could not be
contacted during the site visit or during follow up interviews. 160 Motorcycle Road is a residential
property and 270 Motorcycle Road is identified as Pineville Chapel Church.

On June 17, 2008, AGRA conducted an Initial Groundwater Site Investigation and collected
groundwater samples from water supply wells WSW-1 and WSW-4. The laboratory detected
bis(2-ethylhexyl) phthalate in WSW-1 at a concentration that exceeded the North Carolina
Groundwater Monitoring Report – Flowers Store Property
Clayton, Johnston County, North Carolina
NCDENR Incident: 17217
NCDENR Contract: N14007i-C
September 17, 2014

2
Department of Environment and Natural Resources 2L Groundwater Quality Standards
(NC2LGWQS). However, AGRA stated that bis(2-ethylhexyl) phthalate is not a petroleum
constituent and is believed to be a laboratory contaminant. Bis(2-ethylhexyl) phthalate was also
detected in WSW-4 at a concentration below the NC2LGWQS. The laboratory did not detect
additional petroleum constituents in the groundwater samples.

On August 28, 2008, Regional Probing Services, installed four temporary monitoring wells (TW-1,
TW-2, TW-3 (MW-3), and TW-4) on the subject site using a Geoprobe. The temporary wells were
each installed to a depth of 35 ft. below the ground surface (bgs) with a screened interval of 15
linear feet. Soil encountered during the well installations was very tight red clay. Soil samples
were collected during the installation of each temporary monitoring well at depths of 10 ft. and 20
ft. bgs. The laboratory detected methyl chloride in the soil samples collected from TW-3 and TW-
4 at concentrations which exceeds the Soil-To-Groundwater Maximum Soil Contaminant
Concentration (MSCC) standard of 0.02 milligrams per kilogram (mg/kg). Diethyl phthalate was
detected in the soil samples collected from TW-2 and TW-3. Di-n-butyl phthalate was detected in
soil sample TW-3. Diethyl phthalate and di-n-butyl phthalate do not have a MSCC standards. The
laboratory did not detect additional petroleum constituents above the MSCC standards.

On September 2, 2008, AGRA personnel collected groundwater samples from temporary wells
TW-1 through TW-4. TW-1 was analyzed for volatile organic compounds (VOCs) using EPA
Method 6200B, for semi-volatile organic compounds (SVOCs) using EPA Method 625, and
Massachusetts Department of Environmental Protection Extractable Petroleum Hydrocarbons
(MADEP EPH), MADEP Volatile Petroleum Hydrocarbons (MADEP VPH), and lead using EPA
Method 6010/303C. Groundwater samples were also collected from temporary wells TW-2, TW-3,
and TW 4 to be analyzed using EPA Method 6200B and MADEP VPH. The laboratory detected
lead at a concentration of 250 micrograms per liter (µg/L) in the groundwater sample collected
from TW-1, which exceeds the NC2LGWQS of 15 µg/L. Di-n-butyl phthalate was detected in TW-
1 at a concentration of 6.68 µg/L; however di-n-butyl phthalate does not have a NC2LGWQS.
The laboratory did not detect additional targeted analytes from the groundwater samples at
concentrations exceeding their respective NC2LGWQS.

On February 5, 19, and 25, 2009, Cohesion, Inc. (Cohesion) collected soil samples from
numerous locations at the subject site in an attempt to confirm that contaminated soils remain at
the subject site. Laboratory analysis revealed TPH exceeding the Action Level of 10 mg/kg in soil
samples collected near the rear of the garage, adjacent to an old CITGO petroleum tanker that
had been discarded in the rear of the property, and near two hydraulic pumps located inside the
garage.

On September 30, 2009, AGRA personnel conducted a soil and groundwater sampling event at
the site. Three soil borings were advanced in the former UST locations (UST-1 to 12 ft bgs, UST-2
to 8 ft bgs, and UST-3 to 10 ft bgs). Additionally, soil borings were advanced adjacent to the
previously installed soil borings B-15 and B-8. Soil samples were collected from B-15 and B-8 at
depths of 2 ft bgs and 8 ft bgs. As part of the sampling event, AGRA personnel attempted to
collect groundwater samples from the four on-site temporary monitoring wells TW-1, TW-2, TW-3,
and TW-4. The temporary wells were previously installed with PVC risers, which extended
approximately 1.5 ft above the ground surface. The aboveground risers of TW-1 and TW-2 were
broken and TW-4 was dry. The laboratory detected targeted analytes at the subject site in the soil
samples collected near the former locations of UST-2 and UST-3, as well as adjacent to the
Groundwater Monitoring Report – Flowers Store Property
Clayton, Johnston County, North Carolina
NCDENR Incident: 17217
NCDENR Contract: N14007i-C
September 17, 2014

3
discarded tanker on the rear of the property. However, the constituents detected either did not
exceed their respective MSCC standards or did not have MSCC standards. The laboratory
detected tetrachloroethene at concentrations of 0.89 µg/L and 0.71 µg/L in the groundwater
samples collected from TW-1 and TW-2, respectively, which exceed the NC2LGWQS of 0.70
µg/L. TW-4 was not sampled. However, targeted analytes were not detected in TW-4 during the
sampling event on September 2, 2008. Additionally, 1,2-dichloropropane was detected at a
concentration of 0.51 µg/L in water supply well WSW-5, which does not exceed the NC2LGWQS
of 0.60 µg/L.

On October 4, 2012, Crawford Environmental Services (CES) conducted a groundwater
monitoring event at the subject site. Temporary monitoring wells TW-1, TW-2, and TW-4 were
not located and were presumed destroyed. CES observed six water supply wells within 1,500 feet
of the subject site (WSW-1 through WSW-6). Based on discussions with the property owner, the
home associated with WSW-1 had been connected to municipal water and the well had been
abandoned. The properties utilizing water supply wells WSW-2 and WSW-3 were also connected
to municipal water. WSW-4 through WSW-6 were still actively used as a water supply source.
CES collected a groundwater sample from TW-3 and the laboratory did not detect targeted
analytes above the laboratory reporting limit.

Information contained in a March 26, 2013 Groundwater Monitoring Report prepared by CES,
indicates that on February 13 and 14, 2013, CES installed two permanent monitoring wells (MW-5
and MW-7) at the subject site. CES collected groundwater samples from TW-3, MW-5, and MW-
7. The laboratory detected several constituents at concentrations above the laboratory reporting
limit, but not above their respective NC2LGWQS. Additionally, CES collected soil samples at
depths of 8 ft bgs, 13 ft bgs, and 23 ft bgs during the installation of monitoring well MW-5. The
laboratory detected C9-C22 Aromatics at a concentration above the MSCC in the soil sample
collected from MW-5 at 23 ft bgs. The laboratory detected several constituents at concentrations
above the laboratory reporting limit, but below their respective MSCCs.

SITE GEOLOGY AND HYDROGEOLOGY

As determined from the USGS Topographic Map, Flowers, North Carolina Quadrangle dated
1998 (Figure 1), the site is at an approximate elevation of 280 feet above mean sea level. A
pond is depicted on the topographic map approximately 280 feet northeast of the site. Surface
runoff on the site is generally to the northwest.

The subject site is situated in the Coastal Plain Physiographic Province. The soils encountered
in this area are the residual product of in-place chemical weathering of rock presently
underlying the site and/or historic depositional events. In general, shallow unconfined
groundwater movement within the overlying soils is controlled largely by topographic gradients.
However, as the groundwater percolates downward, it becomes controlled by the subsurface
geologic conditions. Thus, the direction of groundwater movement in the deeper aquifers may
not be consistent with the reflecting topography.

In general, shallow unconfined groundwater movement within the overlying soils is controlled
largely by topographic gradients. Recharge occurs primarily by infiltration along higher
elevations and typically discharges into streams or other surface water bodies. The elevation of
the shallow water table is transient and can vary greatly with seasonal fluctuations in
Groundwater Monitoring Report – Flowers Store Property
Clayton, Johnston County, North Carolina
NCDENR Incident: 17217
NCDENR Contract: N14007i-C
September 17, 2014

4
precipitation. Movement of shallow groundwater is generally from higher to lower elevations.

Water Supply Wells

Six previously identified water supply wells are located within 1,500 feet of the source area
(Figure 8). Water supply well questionnaires were mailed to property owners concerning active
or inactive water supply wells on their property. ECS received a completed water supply well
questionnaire from Ms. Sarah Blanchard granting ECS permission to sample WSW-4.
Additionally, ECS received an email from Mr. Mark Petermann of NCDENR stating that Mr.
Drake Robertson requested that WSW-5, which is located on his property, to be sampled. ECS
has not received completed water supply well questionnaires from the remaining property
owners within 1,000 feet of the site. The names and addresses of the property owners with
water supply wells located within 1,000 feet of the site are included in Table 7.

FIELD ACTIVITIES

On August 13, 2014, ECS collected two groundwater samples from monitoring wells MW-5 and
MW-7. Monitoring well MW-3 was filled with dirt; therefore, a groundwater sample was not
collected. Additionally, ECS collected groundwater samples from water supply wells WSW-4,
WSW-5, and WSW-6. The locations of the monitoring wells are shown on Figure 2 and the
locations of the water supply wells are shown on Figure 8.

Prior to the sampling activities, the static groundwater elevation was measured in each monitoring
well. Well construction details and groundwater elevation data is summarized in Table 2.
Purging and sampling were accomplished using a peristaltic pump and dedicated tubing and/or a
dedicated bailer. Immediately after collection, the groundwater samples were transferred into
sample containers provided by the laboratory.

Prior to water supply well sampling activities, ECS opened the spigots attached to the outside of
the residences for three to five minutes to allow the groundwater to purge from the water supply
wells and associated water lines. After allowing the water supply wells to purge, ECS collected
the groundwater samples from the spigots into sample containers provided by the laboratory.

The sample containers were labeled with ECS project number, sample identification, sample
date and time, and requested analytical analysis. The containers were placed into protective
packaging material and placed into a cooler with ice to maintain the samples at approximately
4° Celsius (C°). The samples were submitted to Pace Analytical Services, Inc. located in
Huntersville, North Carolina for chemical analysis for VOCs using EPA Method 6200B, for
SVOCs using EPA Method 625, for volatile petroleum compounds (VPH) using the MADEP
Method, for extractable petroleum compounds (EPH) using the MADEP, and for lead using the
Standard Method 6010. ECS maintained proper COC procedures throughout the sample
collection and transportation process.

Groundwater Monitoring Report – Flowers Store Property
Clayton, Johnston County, North Carolina
NCDENR Incident: 17217
NCDENR Contract: N14007i-C
September 17, 2014

5
LABORATORY ANALYTICAL RESULTS

Laboratory analysis of the groundwater sample collected from monitoring wells MW-5 detected
C9-C18 Aliphatics and C9-C22 Aromatics at concentrations that exceed their respective NCDENR
GWQS. Neither a NC2LGWQS nor a NCDENR GCL has been established for these analytes.
Additionally, C9-C18 Aliphatics were detected in the groundwater sample collected from MW-5 at
a concentration that exceeds the laboratory reporting limit, but is below the GWQS. Neither a
NC2LGWQS nor GCL are established for this analyte. Laboratory analysis of the groundwater
sample collected from monitoring well MW-5 detected lead at a concentration that exceeds its
NC2LGWQS, but is below its respective GCL.

Laboratory analysis of the groundwater sample collected from MW-7 did not detect targeted
analytes above the laboratory reporting limits.

Laboratory analysis of the groundwater sample collected from water supply well WSW-4 detected
bromodichloromethane at a concentration above the laboratory reporting limit; however, neither a
NC2LGWQS nor a GCL have been established for this analyte. Laboratory analysis of the
groundwater sample collected from WSW-4 detected chloroform at a concentration above the
laboratory reporting limit, but below its NC2LGWQS. Additionally, dibromochloromethane was
detected at a concentration above its respective NC2LGWQS, but below its respective GCL in the
groundwater sample collected from WSW-4.

Laboratory analysis of the groundwater sample collected from water supply well WSW-5 detected
1,2-dichloropropane at a concentration above its respective NC2LGWQS but below its respective
GCL. The laboratory did not detect additional analytes above the laboratory reporting limits.

Laboratory analysis of the groundwater sample collected from water supply well WSW-6 did not
detect targeted analytes above the laboratory reporting limits.

A summary of the laboratory analytical results is included in Table 3 and shown on Figure 4.
Isoconcentration maps for C9-C18 Aliphatics, C9-C22 Aromatics, and lead are individually shown
on Figures 5 through 7. Historical groundwater data is summarized in Tables 4 and 5.

The laboratory analytical data sheets and COCs are included in Appendix A.

CONCLUSIONS

Based on the results of this Groundwater Sampling Event, ECS concludes the following:

• Monitoring well MW-3 was filled with dirt and was not sampled;

• Laboratory analysis of the groundwater sample collected from monitoring wells MW-5
detected C9-C18 Aliphatics and C9-C22 Aromatics at concentrations that exceed their
respective NCDENR GWQS. Additionally, C9-C18 Aliphatic was detected in the groundwater
sample collected from MW-5 at a concentration that exceeds the laboratory reporting limit, but
is below the GWQS. Laboratory analysis of the groundwater sample collected from monitoring
well MW-5 detected lead at a concentration that exceeds its NC2LGWQS, but is below its
Groundwater Monitoring Report – Flowers Store Property
Clayton, Johnston County, North Carolina
NCDENR Incident: 17217
NCDENR Contract: N14007i-C
September 17, 2014

6
respective GCL;

• Laboratory analysis of the groundwater sample collected from MW-7 did not detect targeted
analytes above the laboratory reporting limits;

• Laboratory analysis of the groundwater sample collected from water supply well WSW-4
detected bromodichloromethane at a concentration above the laboratory reporting limit;
however, neither a NC2LGWQS nor a GCL have been established for this analyte.
Laboratory analysis of the groundwater sample collected from WSW-4 detected chloroform at
a concentration above the laboratory reporting limit, but below its NC2LGWQS. Additionally,
dibromochloromethane was detected at a concentration above its respective NC2LGWQS,
but below its respective GCL in the groundwater sample collected from WSW-4;

• Laboratory analysis of the groundwater sample collected from water supply well WSW-5
detected 1,2-Dichloropropane at a concentration above its respective NC2LGWQS, but below
its respective GCL. The laboratory did not detect additional analytes above the laboratory
reporting limits; and

• Laboratory analysis of the groundwater sample collected from water supply well WSW-6 did
not detect targeted analytes above the laboratory reporting limits.

RECOMMENDATIONS

• ECS recommends reinstalling monitoring well MW-3;

• ECS recommends installing monitoring wells approximately 100 feet to the east, south, and
west of monitoring well MW-5;

• ECS recommends that a copy of the laboratory analysis of water supply wells be submitted
to their respective owners along with a letter from NCDENR indicating if restrictions on the
use of their water supply well are recommended;

• ECS recommends collecting groundwater samples from the monitoring wells and water
supply wells on a semi-annual basis; and

• ECS recommends that a copy of this report be submitted to the current property owner.

FIGURES
DRAFT
SOURCE:
USGS TOPOGRAPHIC MAP
FLOWERS
NC QUADRANGLE
DATED 1998
SCALE: 1 : 24,000
FIGURE 1
SITE LOCATION MAP
FLOWERS STORE PROPERTY
4181 NC HIGHWAY 42 EAST
CLAYTON, JOHNSTON COUNTY,
NORTH CAROLINA
ECS PROJECT: 06:21858
SITE
DRAFT
FIGURE 1A
SITE LOCATION MAP
FLOWERS STORE PROPERTY
4181 NC HIGHWAY 42 EAST
CLAYTON, JOHNSTON COUNTY,
NORTH CAROLINA
ECS PROJECT: 06:21858
SOURCE:
JOHNSTON COUNTY GIS
DATED 2013
SCALE AS SHOWN
SITE
SINGLE-FAMILY
RESIDENCES
POND
SINGLE-FAMILY
RESIDENCES
SINGLE-FAMILY
RESIDENCES
0 197
Scale: 1 inch = 197 feet
DRAFT
SOURCE:
JOHNSTON COUNTY GIS
DATED 2013
SCALE AS SHOWN
FIGURE 2
MONITORING WELL LOCATION MAP
FLOWERS STORE PROPERTY
4181 NC HIGHWAY 42 EAST
CLAYTON, JOHNSTON COUNTY,
NORTH CAROLINA
ECS PROJECT: 06:21858
LEGEND
Approximate Location
of Monitoring Well
Former Locations of USTs
MW-3
MW-7
MW-3
Former Location
of USTs
MW-5
0 49
Scale: 1 inch = 49 feet
DRAFT
SOURCE:
JOHNSTON COUNTY GIS
DATED 2013
SCALE AS SHOWN
FIGURE 3
GROUNDWATER ELEVATION MAP
FLOWERS STORE PROPERTY
4181 NC HIGHWAY 42 EAST
CLAYTON, JOHNSTON COUNTY,
NORTH CAROLINA
ECS PROJECT: 06:21858
MW-7
77.97
MW-3
MW-5
66.53
0 49
Scale: 1 inch = 49 feet
LEGEND
Approximate Location of Monitoring Well
Groundwater Elevation
MW-3
82.10
DRAFT
SOURCE:
JOHNSTON COUNTY GIS
DATED 2013
SCALE AS SHOWN
FIGURE 4
GROUNDWATER CONCENTRATION MAP
FLOWERS STORE PROPERTY
4181 NC HIGHWAY 42 EAST
CLAYTON, JOHNSTON COUNTY,
NORTH CAROLINA
ECS PROJECT: 06:21858
MW-7
BRL
MW-3
Destroyed
MW-5
0 49
Scale: 1 inch = 49 feet
C9-C18 Aliphatic 1,650
C9-C22 Aromatic 649
C9-C18 Aliphatic 96.7
Lead 21.5
LEGEND
Approximate Location of Monitoring Well
96.7 Concentrations Above Laboratory Reporting
Limits (µg/L)
649 Bold Concentrations Above the NCDENR
GWQS and/or NC2LGWQS (µg/L)
BRL Below Laboratory Reporting Limit
MW-3
DRAFT
MW-7
BRL
MW-3
Destroyed
MW-5
1,650
SOURCE:
JOHNSTON COUNTY GIS
DATED 2013
SCALE AS SHOWN
FIGURE 5
C9-C18 ALIPHATICS
ISOCONCENTRATION MAP
FLOWERS STORE PROPERTY
4181 NC HIGHWAY 42 EAST
CLAYTON, JOHNSTON COUNTY,
NORTH CAROLINA
ECS PROJECT: 06:21858
LEGEND
Approximate Location of Monitoring Well
C9-C18 Aliphatics Isoconcentration Contour (µg/L)
1,650 Bold Concentrations Above NCDENR GWQS
BRL Below Laboratory Reporting Limit
MW-3
700
0 49
Scale: 1 inch = 49 feet

DRAFT
MW-7
BRL
MW-3
Destroyed
MW-5
649
SOURCE:
JOHNSTON COUNTY GIS
DATED 2013
SCALE AS SHOWN
FIGURE 6
C9-C22 AROMATICS
ISOCONCENTRATION MAP
FLOWERS STORE PROPERTY
4181 NC HIGHWAY 42 EAST
CLAYTON, JOHNSTON COUNTY,
NORTH CAROLINA
ECS PROJECT: 06:21858
LEGEND
Approximate Location of Monitoring Well
C9-C22 Aromatics Isoconcentration Contour (µg/L)
649 Bold Concentrations Above NCDENR GWQS
BRL Below Laboratory Reporting Limit
MW-3
200
0 49
Scale: 1 inch = 49 feet
DRAFT
MW-7
BRL
MW-3
Destroyed
MW-5
21.5
SOURCE:
JOHNSTON COUNTY GIS
DATED 2013
SCALE AS SHOWN
FIGURE 7
LEAD ISOCONCENTRATION MAP
FLOWERS STORE PROPERTY
4181 NC HIGHWAY 42 EAST
CLAYTON, JOHNSTON COUNTY,
NORTH CAROLINA
ECS PROJECT: 06:21858
LEGEND
Approximate Location of Monitoring Well
Lead Isoconcentration Contour (µg/L)
21.5 Bold Concentrations Above NC2LGWQS
BRL Below Laboratory Reporting Limit
MW-3
15
0 49
Scale: 1 inch = 49 feet
DRAFT
SOURCE:
JOHNSTON COUNTY GIS
DATED 2013
SCALE AS SHOWN
FIGURE 8
WATER SUPPLY WELL LOCATION MAP
FLOWERS STORE PROPERTY
4181 NC HIGHWAY 42 EAST
CLAYTON, JOHNSTON COUNTY,
NORTH CAROLINA
ECS PROJECT: 06:21858
WSW-3
WSW-1
LEGEND
Approximate Location
of Water Supply Well
500 ft.
Radius
1,000 ft.
Radius
WSW-1
SITE
0 361
Scale: 1 inch = 361 feet
WSW-6
WSW-2
WSW-4
WSW-5
TABLES
MADEP VPH EPA Method 6010Sample IDSample Date (C9-C18) Aliphatic(C9-C22) Aromatic (C9-C18) AliphaticLeadMW-58/13/20141,650 64996.721.5MW-78/13/2014BRL BRL BRLBRL700 200700NE15NE NENE15,000NCDENR Final and Interim GWQS = Final and Interim Groundwater Quality StandardsNC2LGWS (µg/L)NE NE NE DRAFT NC2LGWQS = North Carolina 2L Groundwater Quality Standard as of April 1, 2013GCL = NCDENR's Gross Contamination Levels for Groundwater as of April 16, 2012MADEP = Massachusetts Department of Environmental ProtectionEPH = Extractable Petroleum HydrocarbonsVPH = Volatile Petroleum HydrocarbonsBOLD = Detected above the NC2LGWQS or GWQSµg/L = Micrograms per LiterNE = Not EstablishedBRL = Below Laboratory Reporting LimitTable 3Summary of Groundwater Analytical ResultsFlowers Store Property4181 NC Highway 42 EastGCL (µg/L) Clayton, Johnston County, North CarolinaECS Project 06:21858MADEP EPHNCDENR Final and Interim GWQS (µg/L)
DRAFTEPA Method 625EPA Method 6010Monitoring Well IDDate9/2/2008BRLBRLBRLBRLBRLBRLBRL6.6867913502509/30/2009BRLBRLBRLBRLBRLBRL0.89BRLBRLBRLBRLBRL10/4/20129/2/2008BRLBRLBRLBRLBRLBRLBRLBRLBRLBRLBRLBRL9/30/2009BRLBRLBRLBRLBRLBRL0.71BRLBRLBRLBRLBRL10/4/20129/2/2008BRLBRLBRLBRLBRLBRLBRLBRLBRLBRLBRLBRL9/30/2009BRLBRLBRLBRLBRLBRLBRLBRLBRLBRLBRL1110/4/2012BRLBRLBRLBRLBRLBRLBRLBRLBRLBRLBRLBRL2/19/2013BRLBRLBRLBRLBRLBRL0.15 JBRLBRLBRLBRL7.28/13/20149/2/2008BRLBRLBRLBRLBRLBRLBRLBRLBRLBRLBRLBRL9/30/200910/4/20122/19/20130.27 J0.46 J5.2 J10.290.49 JBRLBRL110BRLBRL158/13/2014BRLBRLBRLBRLBRLBRLBRLBRL1,746.7BRL64921.52/19/2013BRLBRLBRLBRLBRLBRLBRLBRLBRLBRLBRL0.538/13/2014BRLBRLBRLBRLBRLBRLBRLBRLBRLBRLBRLBRLNC2LGWQS = North Carolina 2L Groundwater Quality Standard as of April 1, 2013GCL = NCDENR's Gross Contamination Levels for Groundwater as of April 16, 2012MADEP = Massachusetts Department of Environmental ProtectionEPH = Extractable Petroleum HydrocarbonsVPH = Volatile Petroleum HydrocarbonsBOLD = Detected above the NC2LGWQS µg/L = Micrograms per LiterBRL = Below Laboratory Reporting LimitJ = Estimated concentration above the adjusted method detection limit and below the adjusted reporting limitNE = Not Established15,000Destroyed42,00021015NENEGCL (µg/L)25Tetrachloroethenedi-n-Butyl phthalateC9-C18 AliphaticsMW-3 (TW-3)1,2,4-Trimethylbenzenesec-Butylbenzene1,3,5-Trimethylbenzene4,200MW-7NEAcetoneTW-4Analytical Methodn-ButylbenzeneContaminant of Concern (µg/L)TW-18,500NC2LGWQS (µg/L)28,500 25,000 6,000,000 6,900DestroyedDestroyed400NE70011,7001 700400Table 4Summary of Historical Groundwater Analytical ResultsFlowers Store Property4181 NC Highway 42 EastClayton, Johnston County, North Carolina706,00070TW-2MW-5ECS Project 06:21858EPA Method 6200BMADEP EPH/VPHWell DryDestroyedp-IsopropyltolueneC19-C36AliphaticsC9-C22 AromaticsLead
WSW-16/17/2008 BRL10.4BRL BRL BRL 59 160 1606/17/2008BRL1.22BRL BRL BRL56 1301508/13/201412.6BRL39.44.3BRLNSNSNSWSW-58/13/2014BRLBRLBRLBRL1.4NSNSNSWSW-68/13/2014BRLBRLBRLBRLBRLNSNSNSNE NE NE NE NE 700 10,000200NE3 70 0.4 0.6 NE NENENE17070,000400600NENENENCDENR Final and Interim GWQS = Final and Interim Groundwater Quality StandardsDRAF
NC2LGWQS = North Carolina 2L Groundwater Quality Standard as of April 1, 2013GCL = NCDENR's Gross Contamination Levels for Groundwater as of April 16, 2012BOLD = Detected above the NC2LGWQSµg/L = Micrograms per LiterMADEP = Massachusetts Department of Environmental ProtectionEPH = Extractable Petroleum HydrocarbonsVPH = Volatile Petroleum HydrocarbonsNE = Not EstablishedNS = Not SampledBRL = Below Laboratory Reporting LimitNCDENR Final and Interim GWQSChloroformDibromochloromethaneContaminant of Concern (ug/L)Water Supply Well IDBis (2-ethylhexyl) PhthalateC9-C18 AliphaticsC19-C36 AliphaticsTable 5Summary of Current and Historical Water Supply Well Analytical ResultsFlowers Store Property4181 NC Highway 42 EastClayton, Johnston County, North CarolinaECS Project 06:21858C11-C22 AromaticsGCL (µg/L)NC2LGWQSAnalytical MethodWSW-41,2-DichloropropaneDate CollectedBromodichloromethaneVOCs (6200B) (µg/L)MADEP EPH/VPH
SB-512/13/13BRL BRL BRL BRL BRL BRL BRL BRLSB-5132/13/13BRL BRL BRL BRL BRL BRL BRL BRLSB-5182/13/13BRL BRL BRL BRL0.26BRL39BRLSB-5232/13/130.0020 0.0049 0.0011J 0.22 3.7 128 46758.3 4.3 3.3 6.6 120 540 Immobile 31782 626 626 46 62,571 1,500 31,000 46920,440 16,350 16,350 410 1,635,200 40,000 810,000 12,264NCDENR = North Carolina Department of Environment and Natural ResourcesMSCC = Maximum Soil Contaminant Concentration LevelsMADEP = Massachusetts Department of Environmental ProtectionEPH = Extractable Petroleum HydrocarbonsVPH = Volatile Petroleum Hydrocarbonsmg/kg = milligrams per kilogramBRL = Below Laboratory Reporting LimitIndustrial/Commercial MSCCSample IDDepth Collected (Ft.)Date CollectedResidential MSCCContaminant of Concern (mg/kg)C9-C18 AliphaticsC19-C36 AliphaticsC9-C22 Aromaticsn-ButylbenzeneTable 6Summary of Historical Soil Sample Analytical ResultsFlowers Store Property4181 NC Highway 42 EastClayton, Johnston County, North Carolina1,3,5-TrimethylbenzeneSoil to Groundwater MSCCECS Project 06:21858Analytical MethodEPA Method 8260Bsec-Butylbenzenebis(2-Ethylhexyl)phthalateBenzoic AcidEPA Method 8270D MADEP EPH/VPH
Table 7Water Supply Well SurveyFlowers Store Property4181 NC Highway 42Clayton, Johnston County, North CarolinaECS Project: 06:21858Johnston County Parcel No.Parcel AddressOwnerOwner AddressWater Well StatusApproximate Distance from IncidentWater Supply Well4181 NC Highway 42105 SouthRidge DrClayton, NC 27527Garner, NC 27527Not Listed4400 NC Highway 42 EClayton, NC 27527Clayton, NC 27527160 Motorcycle Rd160 Motorcycle RdClayton, NC 27527Clayton, NC 27527120 Motorcycle Rd132 Torrey Pines DrClayton, NC 27527Clayton, NC 27527187 Kollinova Dr142 Helena LnClayton, NC 27527Clayton, NC 27527177 Kollinova Dr177 Kollinova DrClayton, NC 27527Clayton, NC 27527184 Kollinova Dr220 Nelson LnClayton, NC 27527Clayton, NC 27527178 Kollinova Dr178 Kollinova DrClayton, NC 27527Clayton, NC 27527154 Kollinova Dr154 Kollinova DrClayton, NC 27527Clayton, NC 27527147 Kollinova Dr147 Kollinova DrClayton, NC 27527Clayton, NC 27527132 Kollinova Dr132 Kollinova DrClayton, NC 27527Clayton, NC 2752734 Syphrona Circle34 Syphrona CircleClayton, NC 27527Clayton, NC 2752735 Syphrona Circle35 Syphrona CircleClayton, NC 27527Clayton, NC 2752719 Syphrona Circle19 Syphrona CircleClayton, NC 27527Clayton, NC 2752785 Kolinova Dr85 Kolinova DrClayton, NC 27527Clayton, NC 27527Not Listed4880 NC Highway 42Clayton, NC 27527Clayton, NC 275274116 NC Highway 424116 NC Highway 42Clayton, NC 27527Clayton, NC 27527168900824729Flowers, Peggy AYes Adjacent westRagland, Russell BAdjacent north WSW-5169900030031Flowers, Pamela DYes Adjacent east WSW-1169900033492Spagnoletti, Karine169900033671Hallinger, CurtWSW-3168900933119Robertson, DrakeYes168900937149UnknownApprox 786 feet eastUnknownApprox 808 feet east169900034698Stefanyk, John MUnknownApprox 569 feet east169900036445Scheffler, Gerald169900035588Read, William AApprox 836 feet eastUnknownByrd, Randy DewayneUnknownApprox 909 feet east169900034360Turcotte, John WUnknown169900024806Swaney, Larry BUnknownApprox 714 feet eastUnknownApprox 520 feet eastUnknown169900037315169900036160Propps, Thomas MUnknownApprox 822 feet eastUnknown169900035050Ford, Melanie PUnknownApprox 960 feet eastUnknownUnknown169900038035Wilcox, James MUnknown169900029612168900929593Flowers, JimmyYesApprox 776 feet southeastFlowers, Rebecca DUnknownAdjacent south WSW-2UnknownUnknownApprox 633 feet eastUnknownUnknownUnknownUnknownAdjacent northeastUnknownApprox 681 northeastUnknownUnknownUnknown
Table 7Water Supply Well SurveyFlowers Store Property4181 NC Highway 42Clayton, Johnston County, North CarolinaECS Project: 06:21858Parcel #Parcel AddressOwnerOwner AddressWater Well on SiteDistance from IncidentParcel & Well NumberNot Listed4400 NC Highway 42 EClayton, NC 27527Clayton, NC 275274300 NC Highway 424709 Chickpat DrClayton, NC 27527Raleigh, NC 27610Not Listed1270 B North Brightleaf BlvdClayton, NC 27527Smithfield, NC 275773986 NC Highway 42C/O Flowers, Peggy 4400 NC Highway 42Clayton, NC 27527Clayton, NC 2752724 Rockport DrC/O Marlowe Builders Inc. 3700 Computer DrClayton, NC 27527Ste 280 Raleigh, NC 2760954 Rockport Dr3304 Six Forks RdClayton, NC 27527Raleigh, NC 2760976 Rockport Dr76 Rockport DrClayton, NC 27527Clayton, NC 27527Not ListedC/O Marlowe Builders Inc. 3700 Computer DrClayton, NC 27527Ste 280 Raleigh, NC 27609UnknownUnknownApprox 706 feet southApprox 935 feet southUnknown168900928114Flowers, Peggy A168900919784Flowers, Jimmy R169900018910Valcourt, Richard JUnknownApprox 973 feet southUnknownUnknownUnknownApprox 559 feet northUnknownUnknownUnknownUnknownApprox 582 feet southwestBenson, Peggy F168900930543Ewing, Michael RUnknownApprox 660 feet northUnknownM&R Land LLCUnknownApprox 699 feet northwestApprox 510 feet northUnknownUnknown168900935755M&R Land LLC198900930352Legacy Custom Homes168900921085168900839216
APPENDIX A

DRAFT
#=CL#
August 21, 2014
LIMS USE: FR - MATTHEW GILLIS
LIMS OBJECT ID: 92213504
92213504
Project:
Pace Project No.:
RE:
Matthew GillisECS9001 Glenwood AvenueRaleigh, NC 27617
FLOWERS STORE PROPERTY
Dear Matthew Gillis:
Enclosed are the analytical results for sample(s) received by the laboratory on August 14, 2014. The
results relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
cc:Matthew Gillis, ECS Carolinas LLP
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 40
DRAFT
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs2225 Riverside Dr., Asheville, NC 28804Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001West Virginia Certification #: 356Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 40
DRAFT
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92213504001 MW-5
Aliphatic (C09-C18)1650 ug/L 08/19/14 20:59 N2200MADEP EPH
Aromatic (C11-C22)649 ug/L 08/18/14 15:36 N2100MADEP EPH
Aliphatic (C09-C12)96.7 ug/L 08/18/14 15:43 N250.0MADEP VPH
Lead 21.5 ug/L 08/19/14 23:525.0EPA 6010
92213504003 WSW-4
Bromodichloromethane 12.6 ug/L 08/16/14 15:37 M1,R10.50SM 6200B
Chloroform 39.4 ug/L 08/16/14 15:370.50SM 6200B
Dibromochloromethane 4.3 ug/L 08/16/14 15:37 M1,R10.50SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 40
DRAFT
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Sample: MW-5 Lab ID: 92213504001 Collected: 08/13/14 12:54 Received: 08/14/14 16:17 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: MADEP EPH Preparation Method: MADEP EPHMADEP EPH NC Water
Aliphatic (C09-C18)1650 ug/L 08/19/14 20:59 N208/15/14 13:30200 2
Aliphatic (C19-C36)ND ug/L 08/19/14 20:59 N208/15/14 13:30200 2
Aromatic (C11-C22)649 ug/L 08/18/14 15:36 N208/15/14 13:30100 1
Surrogates
Nonatriacontane (S)77 %08/19/14 20:59 7194-86-708/15/14 13:3040-140 2
o-Terphenyl (S)70 %08/18/14 15:36 84-15-108/15/14 13:3040-140 1
2-Fluorobiphenyl (S)94 %08/18/14 15:36 321-60-808/15/14 13:3040-140 1
2-Bromonaphthalene (S)140 %08/18/14 15:36 580-13-208/15/14 13:3040-140 1
Analytical Method: MADEP VPHVPH NC Water
Aliphatic (C05-C08)ND ug/L 08/18/14 15:43 N250.0 1
Aliphatic (C09-C12)96.7 ug/L 08/18/14 15:43 N250.0 1
Aromatic (C09-C10)ND ug/L 08/18/14 15:43 N250.0 1
Surrogates4-Bromofluorobenzene (FID) (S)99 %08/18/14 15:43 460-00-470-130 1
4-Bromofluorobenzene (PID) (S)90 %08/18/14 15:43 460-00-470-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP
Lead 21.5 ug/L 08/19/14 23:52 7439-92-108/18/14 19:055.0 1
Analytical Method: EPA 625 Preparation Method: EPA 625625 MSSV
Acenaphthene ND ug/L 08/18/14 20:13 83-32-908/15/14 11:505.0 1
Acenaphthylene ND ug/L 08/18/14 20:13 208-96-808/15/14 11:505.0 1
Anthracene ND ug/L 08/18/14 20:13 120-12-708/15/14 11:505.0 1
Benzo(a)anthracene ND ug/L 08/18/14 20:13 56-55-308/15/14 11:505.0 1
Benzo(a)pyrene ND ug/L 08/18/14 20:13 50-32-808/15/14 11:505.0 1
Benzo(b)fluoranthene ND ug/L 08/18/14 20:13 205-99-208/15/14 11:505.0 1
Benzo(g,h,i)perylene ND ug/L 08/18/14 20:13 191-24-208/15/14 11:505.0 1
Benzo(k)fluoranthene ND ug/L 08/18/14 20:13 207-08-908/15/14 11:505.0 1
4-Bromophenylphenyl ether ND ug/L 08/18/14 20:13 101-55-308/15/14 11:505.0 1
Butylbenzylphthalate ND ug/L 08/18/14 20:13 85-68-708/15/14 11:505.0 1
4-Chloro-3-methylphenol ND ug/L 08/18/14 20:13 59-50-708/15/14 11:505.0 1
bis(2-Chloroethoxy)methane ND ug/L 08/18/14 20:13 111-91-108/15/14 11:5010.0 1
bis(2-Chloroethyl) ether ND ug/L 08/18/14 20:13 111-44-408/15/14 11:505.0 1
bis(2-Chloroisopropyl) ether ND ug/L 08/18/14 20:13 108-60-108/15/14 11:505.0 1
2-Chloronaphthalene ND ug/L 08/18/14 20:13 91-58-708/15/14 11:505.0 1
2-Chlorophenol ND ug/L 08/18/14 20:13 95-57-808/15/14 11:505.0 1
4-Chlorophenylphenyl ether ND ug/L 08/18/14 20:13 7005-72-308/15/14 11:505.0 1
Chrysene ND ug/L 08/18/14 20:13 218-01-908/15/14 11:505.0 1
Dibenz(a,h)anthracene ND ug/L 08/18/14 20:13 53-70-308/15/14 11:505.0 1
3,3'-Dichlorobenzidine ND ug/L 08/18/14 20:13 91-94-108/15/14 11:5025.0 1
2,4-Dichlorophenol ND ug/L 08/18/14 20:13 120-83-208/15/14 11:505.0 1
Diethylphthalate ND ug/L 08/18/14 20:13 84-66-208/15/14 11:505.0 1
2,4-Dimethylphenol ND ug/L 08/18/14 20:13 105-67-908/15/14 11:5010.0 1
Dimethylphthalate ND ug/L 08/18/14 20:13 131-11-308/15/14 11:505.0 1
Di-n-butylphthalate ND ug/L 08/18/14 20:13 84-74-208/15/14 11:505.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 40
DRAFT
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Sample: MW-5 Lab ID: 92213504001 Collected: 08/13/14 12:54 Received: 08/14/14 16:17 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 625 Preparation Method: EPA 625625 MSSV
4,6-Dinitro-2-methylphenol ND ug/L 08/18/14 20:13 534-52-108/15/14 11:5020.0 1
2,4-Dinitrophenol ND ug/L 08/18/14 20:13 51-28-508/15/14 11:5050.0 1
2,4-Dinitrotoluene ND ug/L 08/18/14 20:13 121-14-208/15/14 11:505.0 1
2,6-Dinitrotoluene ND ug/L 08/18/14 20:13 606-20-208/15/14 11:505.0 1
Di-n-octylphthalate ND ug/L 08/18/14 20:13 117-84-008/15/14 11:505.0 1
bis(2-Ethylhexyl)phthalate ND ug/L 08/18/14 20:13 117-81-708/15/14 11:505.0 1
Fluoranthene ND ug/L 08/18/14 20:13 206-44-008/15/14 11:505.0 1
Fluorene ND ug/L 08/18/14 20:13 86-73-708/15/14 11:505.0 1
Hexachloro-1,3-butadiene ND ug/L 08/18/14 20:13 87-68-308/15/14 11:505.0 1
Hexachlorobenzene ND ug/L 08/18/14 20:13 118-74-108/15/14 11:505.0 1
Hexachlorocyclopentadiene ND ug/L 08/18/14 20:13 77-47-408/15/14 11:5010.0 1
Hexachloroethane ND ug/L 08/18/14 20:13 67-72-108/15/14 11:505.0 1
Indeno(1,2,3-cd)pyrene ND ug/L 08/18/14 20:13 193-39-508/15/14 11:505.0 1
Isophorone ND ug/L 08/18/14 20:13 78-59-108/15/14 11:5010.0 1
Naphthalene ND ug/L 08/18/14 20:13 91-20-308/15/14 11:505.0 1
Nitrobenzene ND ug/L 08/18/14 20:13 98-95-308/15/14 11:505.0 1
2-Nitrophenol ND ug/L 08/18/14 20:13 88-75-508/15/14 11:505.0 1
4-Nitrophenol ND ug/L 08/18/14 20:13 100-02-708/15/14 11:5050.0 1
N-Nitrosodimethylamine ND ug/L 08/18/14 20:13 62-75-908/15/14 11:505.0 1
N-Nitroso-di-n-propylamine ND ug/L 08/18/14 20:13 621-64-708/15/14 11:505.0 1
N-Nitrosodiphenylamine ND ug/L 08/18/14 20:13 86-30-608/15/14 11:5010.0 1
Pentachlorophenol ND ug/L 08/18/14 20:13 87-86-508/15/14 11:5010.0 1
Phenanthrene ND ug/L 08/18/14 20:13 85-01-808/15/14 11:505.0 1
Phenol ND ug/L 08/18/14 20:13 108-95-208/15/14 11:505.0 1
Pyrene ND ug/L 08/18/14 20:13 129-00-008/15/14 11:505.0 1
1,2,4-Trichlorobenzene ND ug/L 08/18/14 20:13 120-82-108/15/14 11:505.0 1
2,4,6-Trichlorophenol ND ug/L 08/18/14 20:13 88-06-208/15/14 11:5010.0 1
SurrogatesNitrobenzene-d5 (S)60 %08/18/14 20:13 4165-60-008/15/14 11:5010-120 1
2-Fluorobiphenyl (S)63 %08/18/14 20:13 321-60-808/15/14 11:5015-120 1
Terphenyl-d14 (S)86 %08/18/14 20:13 1718-51-008/15/14 11:5011-131 1
Phenol-d6 (S)18 %08/18/14 20:13 13127-88-308/15/14 11:5010-120 1
2-Fluorophenol (S)27 %08/18/14 20:13 367-12-408/15/14 11:5010-120 1
2,4,6-Tribromophenol (S)83 %08/18/14 20:13 118-79-608/15/14 11:5010-137 1
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 08/16/14 16:27 71-43-210.0 20
Bromobenzene ND ug/L 08/16/14 16:27 108-86-110.0 20
Bromochloromethane ND ug/L 08/16/14 16:27 74-97-510.0 20
Bromodichloromethane ND ug/L 08/16/14 16:27 75-27-410.0 20
Bromoform ND ug/L 08/16/14 16:27 75-25-210.0 20
Bromomethane ND ug/L 08/16/14 16:27 74-83-9100 20
n-Butylbenzene ND ug/L 08/16/14 16:27 104-51-810.0 20
sec-Butylbenzene ND ug/L 08/16/14 16:27 135-98-810.0 20
tert-Butylbenzene ND ug/L 08/16/14 16:27 98-06-610.0 20
Carbon tetrachloride ND ug/L 08/16/14 16:27 56-23-510.0 20
Chlorobenzene ND ug/L 08/16/14 16:27 108-90-710.0 20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 40
DRAFT
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Sample: MW-5 Lab ID: 92213504001 Collected: 08/13/14 12:54 Received: 08/14/14 16:17 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Chloroethane ND ug/L 08/16/14 16:27 75-00-320.0 20
Chloroform ND ug/L 08/16/14 16:27 67-66-310.0 20
Chloromethane ND ug/L 08/16/14 16:27 74-87-320.0 20
2-Chlorotoluene ND ug/L 08/16/14 16:27 95-49-810.0 20
4-Chlorotoluene ND ug/L 08/16/14 16:27 106-43-410.0 20
1,2-Dibromo-3-chloropropane ND ug/L 08/16/14 16:27 96-12-820.0 20
Dibromochloromethane ND ug/L 08/16/14 16:27 124-48-110.0 20
1,2-Dibromoethane (EDB)ND ug/L 08/16/14 16:27 106-93-410.0 20
Dibromomethane ND ug/L 08/16/14 16:27 74-95-310.0 20
1,2-Dichlorobenzene ND ug/L 08/16/14 16:27 95-50-110.0 20
1,3-Dichlorobenzene ND ug/L 08/16/14 16:27 541-73-110.0 20
1,4-Dichlorobenzene ND ug/L 08/16/14 16:27 106-46-710.0 20
Dichlorodifluoromethane ND ug/L 08/16/14 16:27 75-71-810.0 20
1,1-Dichloroethane ND ug/L 08/16/14 16:27 75-34-310.0 20
1,2-Dichloroethane ND ug/L 08/16/14 16:27 107-06-210.0 20
1,1-Dichloroethene ND ug/L 08/16/14 16:27 75-35-410.0 20
cis-1,2-Dichloroethene ND ug/L 08/16/14 16:27 156-59-210.0 20
trans-1,2-Dichloroethene ND ug/L 08/16/14 16:27 156-60-510.0 20
1,2-Dichloropropane ND ug/L 08/16/14 16:27 78-87-510.0 20
1,3-Dichloropropane ND ug/L 08/16/14 16:27 142-28-910.0 20
2,2-Dichloropropane ND ug/L 08/16/14 16:27 594-20-710.0 20
1,1-Dichloropropene ND ug/L 08/16/14 16:27 563-58-610.0 20
cis-1,3-Dichloropropene ND ug/L 08/16/14 16:27 10061-01-510.0 20
trans-1,3-Dichloropropene ND ug/L 08/16/14 16:27 10061-02-610.0 20
Diisopropyl ether ND ug/L 08/16/14 16:27 108-20-310.0 20
Ethylbenzene ND ug/L 08/16/14 16:27 100-41-410.0 20
Hexachloro-1,3-butadiene ND ug/L 08/16/14 16:27 87-68-340.0 20
Isopropylbenzene (Cumene)ND ug/L 08/16/14 16:27 98-82-810.0 20
Methylene Chloride ND ug/L 08/16/14 16:27 75-09-240.0 20
Methyl-tert-butyl ether ND ug/L 08/16/14 16:27 1634-04-410.0 20
Naphthalene ND ug/L 08/16/14 16:27 91-20-340.0 20
n-Propylbenzene ND ug/L 08/16/14 16:27 103-65-110.0 20
Styrene ND ug/L 08/16/14 16:27 100-42-510.0 20
1,1,1,2-Tetrachloroethane ND ug/L 08/16/14 16:27 630-20-610.0 20
1,1,2,2-Tetrachloroethane ND ug/L 08/16/14 16:27 79-34-510.0 20
Tetrachloroethene ND ug/L 08/16/14 16:27 127-18-410.0 20
Toluene ND ug/L 08/16/14 16:27 108-88-310.0 20
1,2,3-Trichlorobenzene ND ug/L 08/16/14 16:27 87-61-640.0 20
1,2,4-Trichlorobenzene ND ug/L 08/16/14 16:27 120-82-140.0 20
1,1,1-Trichloroethane ND ug/L 08/16/14 16:27 71-55-610.0 20
1,1,2-Trichloroethane ND ug/L 08/16/14 16:27 79-00-510.0 20
Trichloroethene ND ug/L 08/16/14 16:27 79-01-610.0 20
Trichlorofluoromethane ND ug/L 08/16/14 16:27 75-69-420.0 20
1,2,3-Trichloropropane ND ug/L 08/16/14 16:27 96-18-410.0 20
1,2,4-Trimethylbenzene ND ug/L 08/16/14 16:27 95-63-610.0 20
1,3,5-Trimethylbenzene ND ug/L 08/16/14 16:27 108-67-810.0 20
Vinyl chloride ND ug/L 08/16/14 16:27 75-01-420.0 20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 40

DRAFT
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Sample:MW-5 Lab ID:92213504001 Collected:08/13/14 12:54 Received:08/14/14 16:17 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B6200B MSV
m&p-Xylene ND ug/L 08/16/14 16:27 179601-23-120.0 20
o-Xylene ND ug/L 08/16/14 16:27 95-47-610.0 20
Surrogates1,2-Dichloroethane-d4 (S)104 %08/16/14 16:27 17060-07-070-130 20
4-Bromofluorobenzene (S)96 %08/16/14 16:27 460-00-470-130 20
Toluene-d8 (S)99 %08/16/14 16:27 2037-26-570-130 20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 40

DRAFT
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Sample:MW-7 Lab ID:92213504002 Collected:08/13/14 11:18 Received:08/14/14 16:17 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: MADEP EPH Preparation Method: MADEP EPHMADEP EPH NC Water
Aliphatic (C09-C18)ND ug/L 08/18/14 16:08 N208/15/14 13:301001
Aliphatic (C19-C36)ND ug/L 08/18/14 16:08 N208/15/14 13:301001
Aromatic (C11-C22)ND ug/L 08/18/14 16:08 N208/15/14 13:301001
Surrogates
Nonatriacontane (S)55 %08/18/14 16:08 7194-86-708/15/14 13:3040-140 1
o-Terphenyl (S)82 %08/18/14 16:08 84-15-108/15/14 13:3040-140 1
2-Fluorobiphenyl (S)83 %08/18/14 16:08 321-60-808/15/14 13:3040-140 1
2-Bromonaphthalene (S)96 %08/18/14 16:08 580-13-208/15/14 13:3040-140 1
Analytical Method: MADEP VPHVPH NC Water
Aliphatic (C05-C08)ND ug/L 08/18/14 16:06 N250.0 1
Aliphatic (C09-C12)ND ug/L 08/18/14 16:06 N250.0 1
Aromatic (C09-C10)ND ug/L 08/18/14 16:06 N250.0 1
Surrogates4-Bromofluorobenzene (FID) (S)103 %08/18/14 16:06 460-00-470-130 1
4-Bromofluorobenzene (PID) (S)92 %08/18/14 16:06 460-00-470-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP
Lead ND ug/L 08/19/14 23:56 7439-92-108/18/14 19:055.0 1
Analytical Method: EPA 625 Preparation Method: EPA 625625 MSSV
Acenaphthene ND ug/L 08/20/14 14:50 83-32-908/20/14 09:205.0 1
Acenaphthylene ND ug/L 08/20/14 14:50 208-96-808/20/14 09:205.0 1
Anthracene ND ug/L 08/20/14 14:50 120-12-708/20/14 09:205.0 1
Benzo(a)anthracene ND ug/L 08/20/14 14:50 56-55-308/20/14 09:205.0 1
Benzo(a)pyrene ND ug/L 08/20/14 14:50 50-32-808/20/14 09:205.0 1
Benzo(b)fluoranthene ND ug/L 08/20/14 14:50 205-99-208/20/14 09:205.0 1
Benzo(g,h,i)perylene ND ug/L 08/20/14 14:50 191-24-208/20/14 09:205.0 1
Benzo(k)fluoranthene ND ug/L 08/20/14 14:50 207-08-908/20/14 09:205.0 1
4-Bromophenylphenyl ether ND ug/L 08/20/14 14:50 101-55-308/20/14 09:205.0 1
Butylbenzylphthalate ND ug/L 08/20/14 14:50 85-68-708/20/14 09:205.0 1
4-Chloro-3-methylphenol ND ug/L 08/20/14 14:50 59-50-708/20/14 09:205.0 1
bis(2-Chloroethoxy)methane ND ug/L 08/20/14 14:50 111-91-108/20/14 09:2010.0 1
bis(2-Chloroethyl) ether ND ug/L 08/20/14 14:50 111-44-408/20/14 09:205.0 1
bis(2-Chloroisopropyl) ether ND ug/L 08/20/14 14:50 108-60-108/20/14 09:205.0 1
2-Chloronaphthalene ND ug/L 08/20/14 14:50 91-58-708/20/14 09:205.0 1
2-Chlorophenol ND ug/L 08/20/14 14:50 95-57-808/20/14 09:205.0 1
4-Chlorophenylphenyl ether ND ug/L 08/20/14 14:50 7005-72-308/20/14 09:205.0 1
Chrysene ND ug/L 08/20/14 14:50 218-01-908/20/14 09:205.0 1
Dibenz(a,h)anthracene ND ug/L 08/20/14 14:50 53-70-308/20/14 09:205.0 1
3,3'-Dichlorobenzidine ND ug/L 08/20/14 14:50 91-94-108/20/14 09:2025.0 1
2,4-Dichlorophenol ND ug/L 08/20/14 14:50 120-83-208/20/14 09:205.0 1
Diethylphthalate ND ug/L 08/20/14 14:50 84-66-208/20/14 09:205.0 1
2,4-Dimethylphenol ND ug/L 08/20/14 14:50 105-67-908/20/14 09:2010.0 1
Dimethylphthalate ND ug/L 08/20/14 14:50 131-11-308/20/14 09:205.0 1
Di-n-butylphthalate ND ug/L 08/20/14 14:50 84-74-208/20/14 09:205.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 40

DRAFT
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Sample:MW-7 Lab ID:92213504002 Collected:08/13/14 11:18 Received:08/14/14 16:17 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 625 Preparation Method: EPA 625625 MSSV
4,6-Dinitro-2-methylphenol ND ug/L 08/20/14 14:50 534-52-108/20/14 09:2020.0 1
2,4-Dinitrophenol ND ug/L 08/20/14 14:50 51-28-508/20/14 09:2050.0 1
2,4-Dinitrotoluene ND ug/L 08/20/14 14:50 121-14-208/20/14 09:205.0 1
2,6-Dinitrotoluene ND ug/L 08/20/14 14:50 606-20-208/20/14 09:205.0 1
Di-n-octylphthalate ND ug/L 08/20/14 14:50 117-84-008/20/14 09:205.0 1
bis(2-Ethylhexyl)phthalate ND ug/L 08/20/14 14:50 117-81-708/20/14 09:205.0 1
Fluoranthene ND ug/L 08/20/14 14:50 206-44-008/20/14 09:205.0 1
Fluorene ND ug/L 08/20/14 14:50 86-73-708/20/14 09:205.0 1
Hexachloro-1,3-butadiene ND ug/L 08/20/14 14:50 87-68-308/20/14 09:205.0 1
Hexachlorobenzene ND ug/L 08/20/14 14:50 118-74-108/20/14 09:205.0 1
Hexachlorocyclopentadiene ND ug/L 08/20/14 14:50 77-47-408/20/14 09:2010.0 1
Hexachloroethane ND ug/L 08/20/14 14:50 67-72-108/20/14 09:205.0 1
Indeno(1,2,3-cd)pyrene ND ug/L 08/20/14 14:50 193-39-508/20/14 09:205.0 1
Isophorone ND ug/L 08/20/14 14:50 78-59-108/20/14 09:2010.0 1
Naphthalene ND ug/L 08/20/14 14:50 91-20-308/20/14 09:205.0 1
Nitrobenzene ND ug/L 08/20/14 14:50 98-95-308/20/14 09:205.0 1
2-Nitrophenol ND ug/L 08/20/14 14:50 88-75-508/20/14 09:205.0 1
4-Nitrophenol ND ug/L 08/20/14 14:50 100-02-708/20/14 09:2050.0 1
N-Nitrosodimethylamine ND ug/L 08/20/14 14:50 62-75-908/20/14 09:205.0 1
N-Nitroso-di-n-propylamine ND ug/L 08/20/14 14:50 621-64-708/20/14 09:205.0 1
N-Nitrosodiphenylamine ND ug/L 08/20/14 14:50 86-30-608/20/14 09:2010.0 1
Pentachlorophenol ND ug/L 08/20/14 14:50 87-86-508/20/14 09:2010.0 1
Phenanthrene ND ug/L 08/20/14 14:50 85-01-808/20/14 09:205.0 1
Phenol ND ug/L 08/20/14 14:50 108-95-208/20/14 09:205.0 1
Pyrene ND ug/L 08/20/14 14:50 129-00-008/20/14 09:205.0 1
1,2,4-Trichlorobenzene ND ug/L 08/20/14 14:50 120-82-108/20/14 09:205.0 1
2,4,6-Trichlorophenol ND ug/L 08/20/14 14:50 88-06-208/20/14 09:2010.0 1
SurrogatesNitrobenzene-d5 (S)29 %08/20/14 14:50 4165-60-008/20/14 09:2010-120 1
2-Fluorobiphenyl (S)29 %08/20/14 14:50 321-60-808/20/14 09:2015-120 1
Terphenyl-d14 (S)74 %08/20/14 14:50 1718-51-008/20/14 09:2011-131 1
Phenol-d6 (S)9 %08/20/14 14:50 13127-88-3 S208/20/14 09:2010-120 1
2-Fluorophenol (S)14 %08/20/14 14:50 367-12-408/20/14 09:2010-120 1
2,4,6-Tribromophenol (S)46 %08/20/14 14:50 118-79-608/20/14 09:2010-137 1
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 08/16/14 16:10 71-43-20.50 1
Bromobenzene ND ug/L 08/16/14 16:10 108-86-10.50 1
Bromochloromethane ND ug/L 08/16/14 16:10 74-97-50.50 1
Bromodichloromethane ND ug/L 08/16/14 16:10 75-27-40.50 1
Bromoform ND ug/L 08/16/14 16:10 75-25-20.50 1
Bromomethane ND ug/L 08/16/14 16:10 74-83-95.0 1
n-Butylbenzene ND ug/L 08/16/14 16:10 104-51-80.50 1
sec-Butylbenzene ND ug/L 08/16/14 16:10 135-98-80.50 1
tert-Butylbenzene ND ug/L 08/16/14 16:10 98-06-60.50 1
Carbon tetrachloride ND ug/L 08/16/14 16:10 56-23-50.50 1
Chlorobenzene ND ug/L 08/16/14 16:10 108-90-70.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 40
DRAFT
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Sample: MW-7 Lab ID: 92213504002 Collected: 08/13/14 11:18 Received: 08/14/14 16:17 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Chloroethane ND ug/L 08/16/14 16:10 75-00-31.0 1
Chloroform ND ug/L 08/16/14 16:10 67-66-30.50 1
Chloromethane ND ug/L 08/16/14 16:10 74-87-31.0 1
2-Chlorotoluene ND ug/L 08/16/14 16:10 95-49-80.50 1
4-Chlorotoluene ND ug/L 08/16/14 16:10 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 08/16/14 16:10 96-12-81.0 1
Dibromochloromethane ND ug/L 08/16/14 16:10 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 08/16/14 16:10 106-93-40.50 1
Dibromomethane ND ug/L 08/16/14 16:10 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 08/16/14 16:10 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 08/16/14 16:10 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 08/16/14 16:10 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 08/16/14 16:10 75-71-80.50 1
1,1-Dichloroethane ND ug/L 08/16/14 16:10 75-34-30.50 1
1,2-Dichloroethane ND ug/L 08/16/14 16:10 107-06-20.50 1
1,1-Dichloroethene ND ug/L 08/16/14 16:10 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 08/16/14 16:10 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 08/16/14 16:10 156-60-50.50 1
1,2-Dichloropropane ND ug/L 08/16/14 16:10 78-87-50.50 1
1,3-Dichloropropane ND ug/L 08/16/14 16:10 142-28-90.50 1
2,2-Dichloropropane ND ug/L 08/16/14 16:10 594-20-70.50 1
1,1-Dichloropropene ND ug/L 08/16/14 16:10 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 08/16/14 16:10 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 08/16/14 16:10 10061-02-60.50 1
Diisopropyl ether ND ug/L 08/16/14 16:10 108-20-30.50 1
Ethylbenzene ND ug/L 08/16/14 16:10 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 08/16/14 16:10 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 08/16/14 16:10 98-82-80.50 1
Methylene Chloride ND ug/L 08/16/14 16:10 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 08/16/14 16:10 1634-04-40.50 1
Naphthalene ND ug/L 08/16/14 16:10 91-20-32.0 1
n-Propylbenzene ND ug/L 08/16/14 16:10 103-65-10.50 1
Styrene ND ug/L 08/16/14 16:10 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 08/16/14 16:10 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 08/16/14 16:10 79-34-50.50 1
Tetrachloroethene ND ug/L 08/16/14 16:10 127-18-40.50 1
Toluene ND ug/L 08/16/14 16:10 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 08/16/14 16:10 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 08/16/14 16:10 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 08/16/14 16:10 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 08/16/14 16:10 79-00-50.50 1
Trichloroethene ND ug/L 08/16/14 16:10 79-01-60.50 1
Trichlorofluoromethane ND ug/L 08/16/14 16:10 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 08/16/14 16:10 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 08/16/14 16:10 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 08/16/14 16:10 108-67-80.50 1
Vinyl chloride ND ug/L 08/16/14 16:10 75-01-41.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 40
DRAFT
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Sample: MW-7 Lab ID: 92213504002 Collected: 08/13/14 11:18 Received: 08/14/14 16:17 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
m&p-Xylene ND ug/L 08/16/14 16:10 179601-23-11.0 1
o-Xylene ND ug/L 08/16/14 16:10 95-47-60.50 1
Surrogates1,2-Dichloroethane-d4 (S)104 %08/16/14 16:10 17060-07-070-130 1
4-Bromofluorobenzene (S)97 %08/16/14 16:10 460-00-470-130 1
Toluene-d8 (S)99 %08/16/14 16:10 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 40
DRAFT
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Sample: WSW-4 Lab ID: 92213504003 Collected: 08/13/14 14:11 Received: 08/14/14 16:17 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: MADEP EPH Preparation Method: MADEP EPHMADEP EPH NC Water
Aliphatic (C09-C18)ND ug/L 08/20/14 22:23 N208/19/14 15:30100 1
Aliphatic (C19-C36)ND ug/L 08/20/14 22:23 N208/19/14 15:30100 1
Aromatic (C11-C22)ND ug/L 08/20/14 22:23 N208/19/14 15:30100 1
Surrogates
Nonatriacontane (S)51 %08/20/14 22:23 7194-86-708/19/14 15:3040-140 1
o-Terphenyl (S)77 %08/20/14 22:23 84-15-108/19/14 15:3040-140 1
2-Fluorobiphenyl (S)79 %08/20/14 22:23 321-60-808/19/14 15:3040-140 1
2-Bromonaphthalene (S)91 %08/20/14 22:23 580-13-208/19/14 15:3040-140 1
Analytical Method: MADEP VPHVPH NC Water
Aliphatic (C05-C08)ND ug/L 08/18/14 16:29 N250.0 1
Aliphatic (C09-C12)ND ug/L 08/18/14 16:29 N250.0 1
Aromatic (C09-C10)ND ug/L 08/18/14 16:29 N250.0 1
Surrogates4-Bromofluorobenzene (FID) (S)97 %08/18/14 16:29 460-00-470-130 1
4-Bromofluorobenzene (PID) (S)87 %08/18/14 16:29 460-00-470-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP
Lead ND ug/L 08/19/14 23:59 7439-92-108/18/14 19:055.0 1
Analytical Method: EPA 625 Preparation Method: EPA 625625 MSSV
Acenaphthene ND ug/L 08/18/14 21:10 83-32-908/15/14 11:505.0 1
Acenaphthylene ND ug/L 08/18/14 21:10 208-96-808/15/14 11:505.0 1
Anthracene ND ug/L 08/18/14 21:10 120-12-708/15/14 11:505.0 1
Benzo(a)anthracene ND ug/L 08/18/14 21:10 56-55-308/15/14 11:505.0 1
Benzo(a)pyrene ND ug/L 08/18/14 21:10 50-32-808/15/14 11:505.0 1
Benzo(b)fluoranthene ND ug/L 08/18/14 21:10 205-99-208/15/14 11:505.0 1
Benzo(g,h,i)perylene ND ug/L 08/18/14 21:10 191-24-208/15/14 11:505.0 1
Benzo(k)fluoranthene ND ug/L 08/18/14 21:10 207-08-908/15/14 11:505.0 1
4-Bromophenylphenyl ether ND ug/L 08/18/14 21:10 101-55-308/15/14 11:505.0 1
Butylbenzylphthalate ND ug/L 08/18/14 21:10 85-68-708/15/14 11:505.0 1
4-Chloro-3-methylphenol ND ug/L 08/18/14 21:10 59-50-708/15/14 11:505.0 1
bis(2-Chloroethoxy)methane ND ug/L 08/18/14 21:10 111-91-108/15/14 11:5010.0 1
bis(2-Chloroethyl) ether ND ug/L 08/18/14 21:10 111-44-408/15/14 11:505.0 1
bis(2-Chloroisopropyl) ether ND ug/L 08/18/14 21:10 108-60-108/15/14 11:505.0 1
2-Chloronaphthalene ND ug/L 08/18/14 21:10 91-58-708/15/14 11:505.0 1
2-Chlorophenol ND ug/L 08/18/14 21:10 95-57-808/15/14 11:505.0 1
4-Chlorophenylphenyl ether ND ug/L 08/18/14 21:10 7005-72-308/15/14 11:505.0 1
Chrysene ND ug/L 08/18/14 21:10 218-01-908/15/14 11:505.0 1
Dibenz(a,h)anthracene ND ug/L 08/18/14 21:10 53-70-308/15/14 11:505.0 1
3,3'-Dichlorobenzidine ND ug/L 08/18/14 21:10 91-94-108/15/14 11:5025.0 1
2,4-Dichlorophenol ND ug/L 08/18/14 21:10 120-83-208/15/14 11:505.0 1
Diethylphthalate ND ug/L 08/18/14 21:10 84-66-208/15/14 11:505.0 1
2,4-Dimethylphenol ND ug/L 08/18/14 21:10 105-67-908/15/14 11:5010.0 1
Dimethylphthalate ND ug/L 08/18/14 21:10 131-11-308/15/14 11:505.0 1
Di-n-butylphthalate ND ug/L 08/18/14 21:10 84-74-208/15/14 11:505.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 40
DRAFT
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Sample: WSW-4 Lab ID: 92213504003 Collected: 08/13/14 14:11 Received: 08/14/14 16:17 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 625 Preparation Method: EPA 625625 MSSV
4,6-Dinitro-2-methylphenol ND ug/L 08/18/14 21:10 534-52-108/15/14 11:5020.0 1
2,4-Dinitrophenol ND ug/L 08/18/14 21:10 51-28-508/15/14 11:5050.0 1
2,4-Dinitrotoluene ND ug/L 08/18/14 21:10 121-14-208/15/14 11:505.0 1
2,6-Dinitrotoluene ND ug/L 08/18/14 21:10 606-20-208/15/14 11:505.0 1
Di-n-octylphthalate ND ug/L 08/18/14 21:10 117-84-008/15/14 11:505.0 1
bis(2-Ethylhexyl)phthalate ND ug/L 08/18/14 21:10 117-81-708/15/14 11:505.0 1
Fluoranthene ND ug/L 08/18/14 21:10 206-44-008/15/14 11:505.0 1
Fluorene ND ug/L 08/18/14 21:10 86-73-708/15/14 11:505.0 1
Hexachloro-1,3-butadiene ND ug/L 08/18/14 21:10 87-68-308/15/14 11:505.0 1
Hexachlorobenzene ND ug/L 08/18/14 21:10 118-74-108/15/14 11:505.0 1
Hexachlorocyclopentadiene ND ug/L 08/18/14 21:10 77-47-408/15/14 11:5010.0 1
Hexachloroethane ND ug/L 08/18/14 21:10 67-72-108/15/14 11:505.0 1
Indeno(1,2,3-cd)pyrene ND ug/L 08/18/14 21:10 193-39-508/15/14 11:505.0 1
Isophorone ND ug/L 08/18/14 21:10 78-59-108/15/14 11:5010.0 1
Naphthalene ND ug/L 08/18/14 21:10 91-20-308/15/14 11:505.0 1
Nitrobenzene ND ug/L 08/18/14 21:10 98-95-308/15/14 11:505.0 1
2-Nitrophenol ND ug/L 08/18/14 21:10 88-75-508/15/14 11:505.0 1
4-Nitrophenol ND ug/L 08/18/14 21:10 100-02-708/15/14 11:5050.0 1
N-Nitrosodimethylamine ND ug/L 08/18/14 21:10 62-75-908/15/14 11:505.0 1
N-Nitroso-di-n-propylamine ND ug/L 08/18/14 21:10 621-64-708/15/14 11:505.0 1
N-Nitrosodiphenylamine ND ug/L 08/18/14 21:10 86-30-608/15/14 11:5010.0 1
Pentachlorophenol ND ug/L 08/18/14 21:10 87-86-508/15/14 11:5010.0 1
Phenanthrene ND ug/L 08/18/14 21:10 85-01-808/15/14 11:505.0 1
Phenol ND ug/L 08/18/14 21:10 108-95-208/15/14 11:505.0 1
Pyrene ND ug/L 08/18/14 21:10 129-00-008/15/14 11:505.0 1
1,2,4-Trichlorobenzene ND ug/L 08/18/14 21:10 120-82-108/15/14 11:505.0 1
2,4,6-Trichlorophenol ND ug/L 08/18/14 21:10 88-06-208/15/14 11:5010.0 1
SurrogatesNitrobenzene-d5 (S)72 %08/18/14 21:10 4165-60-008/15/14 11:5010-120 1
2-Fluorobiphenyl (S)76 %08/18/14 21:10 321-60-808/15/14 11:5015-120 1
Terphenyl-d14 (S)99 %08/18/14 21:10 1718-51-008/15/14 11:5011-131 1
Phenol-d6 (S)0 %08/18/14 21:10 13127-88-3 S008/15/14 11:5010-120 1
2-Fluorophenol (S)19 %08/18/14 21:10 367-12-408/15/14 11:5010-120 1
2,4,6-Tribromophenol (S)69 %08/18/14 21:10 118-79-608/15/14 11:5010-137 1
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 08/16/14 15:37 71-43-2 M1,R10.50 1
Bromobenzene ND ug/L 08/16/14 15:37 108-86-1 R10.50 1
Bromochloromethane ND ug/L 08/16/14 15:37 74-97-5 M1,R10.50 1
Bromodichloromethane 12.6 ug/L 08/16/14 15:37 75-27-4 M1,R10.50 1
Bromoform ND ug/L 08/16/14 15:37 75-25-2 M1,R10.50 1
Bromomethane ND ug/L 08/16/14 15:37 74-83-9 M1,R15.0 1
n-Butylbenzene ND ug/L 08/16/14 15:37 104-51-8 M1,R10.50 1
sec-Butylbenzene ND ug/L 08/16/14 15:37 135-98-8 M1,R10.50 1
tert-Butylbenzene ND ug/L 08/16/14 15:37 98-06-6 R10.50 1
Carbon tetrachloride ND ug/L 08/16/14 15:37 56-23-5 M1,R10.50 1
Chlorobenzene ND ug/L 08/16/14 15:37 108-90-7 M1,R10.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 40
DRAFT
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Sample: WSW-4 Lab ID: 92213504003 Collected: 08/13/14 14:11 Received: 08/14/14 16:17 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Chloroethane ND ug/L 08/16/14 15:37 75-00-3 R11.0 1
Chloroform 39.4 ug/L 08/16/14 15:37 67-66-30.50 1
Chloromethane ND ug/L 08/16/14 15:37 74-87-3 M1,R11.0 1
2-Chlorotoluene ND ug/L 08/16/14 15:37 95-49-8 M1,R10.50 1
4-Chlorotoluene ND ug/L 08/16/14 15:37 106-43-4 M1,R10.50 1
1,2-Dibromo-3-chloropropane ND ug/L 08/16/14 15:37 96-12-8 R11.0 1
Dibromochloromethane 4.3 ug/L 08/16/14 15:37 124-48-1 M1,R10.50 1
1,2-Dibromoethane (EDB)ND ug/L 08/16/14 15:37 106-93-4 M1,R10.50 1
Dibromomethane ND ug/L 08/16/14 15:37 74-95-3 M1,R10.50 1
1,2-Dichlorobenzene ND ug/L 08/16/14 15:37 95-50-1 R10.50 1
1,3-Dichlorobenzene ND ug/L 08/16/14 15:37 541-73-1 R10.50 1
1,4-Dichlorobenzene ND ug/L 08/16/14 15:37 106-46-7 R10.50 1
Dichlorodifluoromethane ND ug/L 08/16/14 15:37 75-71-8 R10.50 1
1,1-Dichloroethane ND ug/L 08/16/14 15:37 75-34-3 R10.50 1
1,2-Dichloroethane ND ug/L 08/16/14 15:37 107-06-2 R10.50 1
1,1-Dichloroethene ND ug/L 08/16/14 15:37 75-35-4 R10.50 1
cis-1,2-Dichloroethene ND ug/L 08/16/14 15:37 156-59-2 M1,R10.50 1
trans-1,2-Dichloroethene ND ug/L 08/16/14 15:37 156-60-5 M1,R10.50 1
1,2-Dichloropropane ND ug/L 08/16/14 15:37 78-87-5 M1,R10.50 1
1,3-Dichloropropane ND ug/L 08/16/14 15:37 142-28-9 M1,R10.50 1
2,2-Dichloropropane ND ug/L 08/16/14 15:37 594-20-7 M1,R10.50 1
1,1-Dichloropropene ND ug/L 08/16/14 15:37 563-58-6 M1,R10.50 1
cis-1,3-Dichloropropene ND ug/L 08/16/14 15:37 10061-01-5 M1,R10.50 1
trans-1,3-Dichloropropene ND ug/L 08/16/14 15:37 10061-02-6 M1,R10.50 1
Diisopropyl ether ND ug/L 08/16/14 15:37 108-20-3 R10.50 1
Ethylbenzene ND ug/L 08/16/14 15:37 100-41-4 M1,R10.50 1
Hexachloro-1,3-butadiene ND ug/L 08/16/14 15:37 87-68-3 M1,R12.0 1
Isopropylbenzene (Cumene)ND ug/L 08/16/14 15:37 98-82-8 M1,R10.50 1
Methylene Chloride ND ug/L 08/16/14 15:37 75-09-2 R12.0 1
Methyl-tert-butyl ether ND ug/L 08/16/14 15:37 1634-04-4 R10.50 1
Naphthalene ND ug/L 08/16/14 15:37 91-20-3 M12.0 1
n-Propylbenzene ND ug/L 08/16/14 15:37 103-65-1 M1,R10.50 1
Styrene ND ug/L 08/16/14 15:37 100-42-5 M10.50 1
1,1,1,2-Tetrachloroethane ND ug/L 08/16/14 15:37 630-20-6 M1,R10.50 1
1,1,2,2-Tetrachloroethane ND ug/L 08/16/14 15:37 79-34-5 R10.50 1
Tetrachloroethene ND ug/L 08/16/14 15:37 127-18-4 M1,R10.50 1
Toluene ND ug/L 08/16/14 15:37 108-88-3 M1,R10.50 1
1,2,3-Trichlorobenzene ND ug/L 08/16/14 15:37 87-61-6 M1,R12.0 1
1,2,4-Trichlorobenzene ND ug/L 08/16/14 15:37 120-82-1 R12.0 1
1,1,1-Trichloroethane ND ug/L 08/16/14 15:37 71-55-6 M1,R10.50 1
1,1,2-Trichloroethane ND ug/L 08/16/14 15:37 79-00-5 M1,R10.50 1
Trichloroethene ND ug/L 08/16/14 15:37 79-01-6 M1,R10.50 1
Trichlorofluoromethane ND ug/L 08/16/14 15:37 75-69-4 M1,R11.0 1
1,2,3-Trichloropropane ND ug/L 08/16/14 15:37 96-18-4 M1,R10.50 1
1,2,4-Trimethylbenzene ND ug/L 08/16/14 15:37 95-63-6 M10.50 1
1,3,5-Trimethylbenzene ND ug/L 08/16/14 15:37 108-67-8 M10.50 1
Vinyl chloride ND ug/L 08/16/14 15:37 75-01-4 M1,R11.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 40
DRAFT
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Sample: WSW-4 Lab ID: 92213504003 Collected: 08/13/14 14:11 Received: 08/14/14 16:17 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
m&p-Xylene ND ug/L 08/16/14 15:37 179601-23-1 M1,R11.0 1
o-Xylene ND ug/L 08/16/14 15:37 95-47-6 M1,R10.50 1
Surrogates1,2-Dichloroethane-d4 (S)104 %08/16/14 15:37 17060-07-070-130 1
4-Bromofluorobenzene (S)96 %08/16/14 15:37 460-00-470-130 1
Toluene-d8 (S)99 %08/16/14 15:37 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 40
DRAFT
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Sample: WSW-6 Lab ID: 92213504004 Collected: 08/13/14 14:51 Received: 08/14/14 16:17 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: MADEP EPH Preparation Method: MADEP EPHMADEP EPH NC Water
Aliphatic (C09-C18)ND ug/L 08/18/14 17:13 N208/15/14 13:30100 1
Aliphatic (C19-C36)ND ug/L 08/18/14 17:13 N208/15/14 13:30100 1
Aromatic (C11-C22)ND ug/L 08/18/14 17:13 N208/15/14 13:30100 1
Surrogates
Nonatriacontane (S)55 %08/18/14 17:13 7194-86-708/15/14 13:3040-140 1
o-Terphenyl (S)73 %08/18/14 17:13 84-15-108/15/14 13:3040-140 1
2-Fluorobiphenyl (S)73 %08/18/14 17:13 321-60-808/15/14 13:3040-140 1
2-Bromonaphthalene (S)83 %08/18/14 17:13 580-13-208/15/14 13:3040-140 1
Analytical Method: MADEP VPHVPH NC Water
Aliphatic (C05-C08)ND ug/L 08/18/14 16:52 N250.0 1
Aliphatic (C09-C12)ND ug/L 08/18/14 16:52 N250.0 1
Aromatic (C09-C10)ND ug/L 08/18/14 16:52 N250.0 1
Surrogates4-Bromofluorobenzene (FID) (S)97 %08/18/14 16:52 460-00-470-130 1
4-Bromofluorobenzene (PID) (S)88 %08/18/14 16:52 460-00-470-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP
Lead ND ug/L 08/20/14 00:02 7439-92-108/18/14 19:055.0 1
Analytical Method: EPA 625 Preparation Method: EPA 625625 MSSV
Acenaphthene ND ug/L 08/19/14 08:10 83-32-908/15/14 11:505.0 1
Acenaphthylene ND ug/L 08/19/14 08:10 208-96-808/15/14 11:505.0 1
Anthracene ND ug/L 08/19/14 08:10 120-12-708/15/14 11:505.0 1
Benzo(a)anthracene ND ug/L 08/19/14 08:10 56-55-308/15/14 11:505.0 1
Benzo(a)pyrene ND ug/L 08/19/14 08:10 50-32-808/15/14 11:505.0 1
Benzo(b)fluoranthene ND ug/L 08/19/14 08:10 205-99-208/15/14 11:505.0 1
Benzo(g,h,i)perylene ND ug/L 08/19/14 08:10 191-24-208/15/14 11:505.0 1
Benzo(k)fluoranthene ND ug/L 08/19/14 08:10 207-08-908/15/14 11:505.0 1
4-Bromophenylphenyl ether ND ug/L 08/19/14 08:10 101-55-308/15/14 11:505.0 1
Butylbenzylphthalate ND ug/L 08/19/14 08:10 85-68-708/15/14 11:505.0 1
4-Chloro-3-methylphenol ND ug/L 08/19/14 08:10 59-50-708/15/14 11:505.0 1
bis(2-Chloroethoxy)methane ND ug/L 08/19/14 08:10 111-91-108/15/14 11:5010.0 1
bis(2-Chloroethyl) ether ND ug/L 08/19/14 08:10 111-44-408/15/14 11:505.0 1
bis(2-Chloroisopropyl) ether ND ug/L 08/19/14 08:10 108-60-108/15/14 11:505.0 1
2-Chloronaphthalene ND ug/L 08/19/14 08:10 91-58-708/15/14 11:505.0 1
2-Chlorophenol ND ug/L 08/19/14 08:10 95-57-808/15/14 11:505.0 1
4-Chlorophenylphenyl ether ND ug/L 08/19/14 08:10 7005-72-308/15/14 11:505.0 1
Chrysene ND ug/L 08/19/14 08:10 218-01-908/15/14 11:505.0 1
Dibenz(a,h)anthracene ND ug/L 08/19/14 08:10 53-70-308/15/14 11:505.0 1
3,3'-Dichlorobenzidine ND ug/L 08/19/14 08:10 91-94-108/15/14 11:5025.0 1
2,4-Dichlorophenol ND ug/L 08/19/14 08:10 120-83-208/15/14 11:505.0 1
Diethylphthalate ND ug/L 08/19/14 08:10 84-66-208/15/14 11:505.0 1
2,4-Dimethylphenol ND ug/L 08/19/14 08:10 105-67-908/15/14 11:5010.0 1
Dimethylphthalate ND ug/L 08/19/14 08:10 131-11-308/15/14 11:505.0 1
Di-n-butylphthalate ND ug/L 08/19/14 08:10 84-74-208/15/14 11:505.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 40

DRAFT
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Sample:WSW-6 Lab ID:92213504004 Collected:08/13/14 14:51 Received:08/14/14 16:17 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 625 Preparation Method: EPA 625625 MSSV
4,6-Dinitro-2-methylphenol ND ug/L 08/19/14 08:10 534-52-108/15/14 11:5020.0 1
2,4-Dinitrophenol ND ug/L 08/19/14 08:10 51-28-508/15/14 11:5050.0 1
2,4-Dinitrotoluene ND ug/L 08/19/14 08:10 121-14-208/15/14 11:505.0 1
2,6-Dinitrotoluene ND ug/L 08/19/14 08:10 606-20-208/15/14 11:505.0 1
Di-n-octylphthalate ND ug/L 08/19/14 08:10 117-84-008/15/14 11:505.0 1
bis(2-Ethylhexyl)phthalate ND ug/L 08/19/14 08:10 117-81-708/15/14 11:505.0 1
Fluoranthene ND ug/L 08/19/14 08:10 206-44-008/15/14 11:505.0 1
Fluorene ND ug/L 08/19/14 08:10 86-73-708/15/14 11:505.0 1
Hexachloro-1,3-butadiene ND ug/L 08/19/14 08:10 87-68-308/15/14 11:505.0 1
Hexachlorobenzene ND ug/L 08/19/14 08:10 118-74-108/15/14 11:505.0 1
Hexachlorocyclopentadiene ND ug/L 08/19/14 08:10 77-47-408/15/14 11:5010.0 1
Hexachloroethane ND ug/L 08/19/14 08:10 67-72-108/15/14 11:505.0 1
Indeno(1,2,3-cd)pyrene ND ug/L 08/19/14 08:10 193-39-508/15/14 11:505.0 1
Isophorone ND ug/L 08/19/14 08:10 78-59-108/15/14 11:5010.0 1
Naphthalene ND ug/L 08/19/14 08:10 91-20-308/15/14 11:505.0 1
Nitrobenzene ND ug/L 08/19/14 08:10 98-95-308/15/14 11:505.0 1
2-Nitrophenol ND ug/L 08/19/14 08:10 88-75-508/15/14 11:505.0 1
4-Nitrophenol ND ug/L 08/19/14 08:10 100-02-708/15/14 11:5050.0 1
N-Nitrosodimethylamine ND ug/L 08/19/14 08:10 62-75-908/15/14 11:505.0 1
N-Nitroso-di-n-propylamine ND ug/L 08/19/14 08:10 621-64-708/15/14 11:505.0 1
N-Nitrosodiphenylamine ND ug/L 08/19/14 08:10 86-30-608/15/14 11:5010.0 1
Pentachlorophenol ND ug/L 08/19/14 08:10 87-86-508/15/14 11:5010.0 1
Phenanthrene ND ug/L 08/19/14 08:10 85-01-808/15/14 11:505.0 1
Phenol ND ug/L 08/19/14 08:10 108-95-208/15/14 11:505.0 1
Pyrene ND ug/L 08/19/14 08:10 129-00-008/15/14 11:505.0 1
1,2,4-Trichlorobenzene ND ug/L 08/19/14 08:10 120-82-108/15/14 11:505.0 1
2,4,6-Trichlorophenol ND ug/L 08/19/14 08:10 88-06-208/15/14 11:5010.0 1
SurrogatesNitrobenzene-d5 (S)63 %08/19/14 08:10 4165-60-008/15/14 11:5010-120 1
2-Fluorobiphenyl (S)64 %08/19/14 08:10 321-60-808/15/14 11:5015-120 1
Terphenyl-d14 (S)91 %08/19/14 08:10 1718-51-008/15/14 11:5011-131 1
Phenol-d6 (S)19 %08/19/14 08:10 13127-88-308/15/14 11:5010-120 1
2-Fluorophenol (S)28 %08/19/14 08:10 367-12-408/15/14 11:5010-120 1
2,4,6-Tribromophenol (S)76 %08/19/14 08:10 118-79-608/15/14 11:5010-137 1
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 08/16/14 15:54 71-43-20.50 1
Bromobenzene ND ug/L 08/16/14 15:54 108-86-10.50 1
Bromochloromethane ND ug/L 08/16/14 15:54 74-97-50.50 1
Bromodichloromethane ND ug/L 08/16/14 15:54 75-27-40.50 1
Bromoform ND ug/L 08/16/14 15:54 75-25-20.50 1
Bromomethane ND ug/L 08/16/14 15:54 74-83-95.0 1
n-Butylbenzene ND ug/L 08/16/14 15:54 104-51-80.50 1
sec-Butylbenzene ND ug/L 08/16/14 15:54 135-98-80.50 1
tert-Butylbenzene ND ug/L 08/16/14 15:54 98-06-60.50 1
Carbon tetrachloride ND ug/L 08/16/14 15:54 56-23-50.50 1
Chlorobenzene ND ug/L 08/16/14 15:54 108-90-70.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 40

DRAFT
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Sample:WSW-6 Lab ID:92213504004 Collected:08/13/14 14:51 Received:08/14/14 16:17 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B6200B MSV
Chloroethane ND ug/L 08/16/14 15:54 75-00-31.0 1
Chloroform ND ug/L 08/16/14 15:54 67-66-30.50 1
Chloromethane ND ug/L 08/16/14 15:54 74-87-31.0 1
2-Chlorotoluene ND ug/L 08/16/14 15:54 95-49-80.50 1
4-Chlorotoluene ND ug/L 08/16/14 15:54 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 08/16/14 15:54 96-12-81.0 1
Dibromochloromethane ND ug/L 08/16/14 15:54 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 08/16/14 15:54 106-93-40.50 1
Dibromomethane ND ug/L 08/16/14 15:54 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 08/16/14 15:54 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 08/16/14 15:54 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 08/16/14 15:54 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 08/16/14 15:54 75-71-80.50 1
1,1-Dichloroethane ND ug/L 08/16/14 15:54 75-34-30.50 1
1,2-Dichloroethane ND ug/L 08/16/14 15:54 107-06-20.50 1
1,1-Dichloroethene ND ug/L 08/16/14 15:54 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 08/16/14 15:54 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 08/16/14 15:54 156-60-50.50 1
1,2-Dichloropropane ND ug/L 08/16/14 15:54 78-87-50.50 1
1,3-Dichloropropane ND ug/L 08/16/14 15:54 142-28-90.50 1
2,2-Dichloropropane ND ug/L 08/16/14 15:54 594-20-70.50 1
1,1-Dichloropropene ND ug/L 08/16/14 15:54 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 08/16/14 15:54 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 08/16/14 15:54 10061-02-60.50 1
Diisopropyl ether ND ug/L 08/16/14 15:54 108-20-30.50 1
Ethylbenzene ND ug/L 08/16/14 15:54 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 08/16/14 15:54 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 08/16/14 15:54 98-82-80.50 1
Methylene Chloride ND ug/L 08/16/14 15:54 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 08/16/14 15:54 1634-04-40.50 1
Naphthalene ND ug/L 08/16/14 15:54 91-20-32.0 1
n-Propylbenzene ND ug/L 08/16/14 15:54 103-65-10.50 1
Styrene ND ug/L 08/16/14 15:54 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 08/16/14 15:54 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 08/16/14 15:54 79-34-50.50 1
Tetrachloroethene ND ug/L 08/16/14 15:54 127-18-40.50 1
Toluene ND ug/L 08/16/14 15:54 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 08/16/14 15:54 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 08/16/14 15:54 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 08/16/14 15:54 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 08/16/14 15:54 79-00-50.50 1
Trichloroethene ND ug/L 08/16/14 15:54 79-01-60.50 1
Trichlorofluoromethane ND ug/L 08/16/14 15:54 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 08/16/14 15:54 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 08/16/14 15:54 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 08/16/14 15:54 108-67-80.50 1
Vinyl chloride ND ug/L 08/16/14 15:54 75-01-41.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 40

DRAFT
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Sample:WSW-6 Lab ID:92213504004 Collected:08/13/14 14:51 Received:08/14/14 16:17 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B6200B MSV
m&p-Xylene ND ug/L 08/16/14 15:54 179601-23-11.0 1
o-Xylene ND ug/L 08/16/14 15:54 95-47-60.50 1
Surrogates1,2-Dichloroethane-d4 (S)104 %08/16/14 15:54 17060-07-070-130 1
4-Bromofluorobenzene (S)97 %08/16/14 15:54 460-00-470-130 1
Toluene-d8 (S)100 %08/16/14 15:54 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 40

DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/8453
MADEP VPH
MADEP VPH
VPH NC Water
Associated Lab Samples:92213504001, 92213504002, 92213504003, 92213504004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1266097
Associated Lab Samples:92213504001, 92213504002, 92213504003, 92213504004
Matrix:Water
Analyzed
Aliphatic (C05-C08)ug/L ND 50.0 N208/18/14 15:20
Aliphatic (C09-C12)ug/L ND 50.0 N208/18/14 15:20
Aromatic (C09-C10)ug/L ND 50.0 N208/18/14 15:20
4-Bromofluorobenzene (FID) (S)%98 70-130 08/18/14 15:20
4-Bromofluorobenzene (PID) (S)%89 70-130 08/18/14 15:20
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1266098LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1266099
Aliphatic (C05-C08)ug/L 257 N23008670-13088263 2 25
Aliphatic (C09-C12)ug/L 343 N230011430-130119357 4 25
Aromatic (C09-C10)ug/L 96.4 N21009670-1309998.9 3 25
4-Bromofluorobenzene (FID) (S)%98 70-130100
4-Bromofluorobenzene (PID) (S)%90 70-13092
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 40

DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/16699
EPA 3010
EPA 6010
6010 MET
Associated Lab Samples:92213504001, 92213504002, 92213504003, 92213504004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1266503
Associated Lab Samples:92213504001, 92213504002, 92213504003, 92213504004
Matrix:Water
Analyzed
Lead ug/L ND 5.0 08/19/14 23:12
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1266504LABORATORY CONTROL SAMPLE:
LCSSpike
Lead ug/L 524500 105 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1266505MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92213359049
1266506
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Lead ug/L 500 102 75-125104 2500ND512520
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 40

DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/27974
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92213504001, 92213504002, 92213504003, 92213504004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1265112
Associated Lab Samples:92213504001, 92213504002, 92213504003, 92213504004
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 08/16/14 11:28
1,1,1-Trichloroethane ug/L ND 0.50 08/16/14 11:28
1,1,2,2-Tetrachloroethane ug/L ND 0.50 08/16/14 11:28
1,1,2-Trichloroethane ug/L ND 0.50 08/16/14 11:28
1,1-Dichloroethane ug/L ND 0.50 08/16/14 11:28
1,1-Dichloroethene ug/L ND 0.50 08/16/14 11:28
1,1-Dichloropropene ug/L ND 0.50 08/16/14 11:28
1,2,3-Trichlorobenzene ug/L ND 2.0 08/16/14 11:28
1,2,3-Trichloropropane ug/L ND 0.50 08/16/14 11:28
1,2,4-Trichlorobenzene ug/L ND 2.0 08/16/14 11:28
1,2,4-Trimethylbenzene ug/L ND 0.50 08/16/14 11:28
1,2-Dibromo-3-chloropropane ug/L ND 1.0 08/16/14 11:28
1,2-Dibromoethane (EDB)ug/L ND 0.50 08/16/14 11:28
1,2-Dichlorobenzene ug/L ND 0.50 08/16/14 11:28
1,2-Dichloroethane ug/L ND 0.50 08/16/14 11:28
1,2-Dichloropropane ug/L ND 0.50 08/16/14 11:28
1,3,5-Trimethylbenzene ug/L ND 0.50 08/16/14 11:28
1,3-Dichlorobenzene ug/L ND 0.50 08/16/14 11:28
1,3-Dichloropropane ug/L ND 0.50 08/16/14 11:28
1,4-Dichlorobenzene ug/L ND 0.50 08/16/14 11:28
2,2-Dichloropropane ug/L ND 0.50 08/16/14 11:28
2-Chlorotoluene ug/L ND 0.50 08/16/14 11:28
4-Chlorotoluene ug/L ND 0.50 08/16/14 11:28
Benzene ug/L ND 0.50 08/16/14 11:28
Bromobenzene ug/L ND 0.50 08/16/14 11:28
Bromochloromethane ug/L ND 0.50 08/16/14 11:28
Bromodichloromethane ug/L ND 0.50 08/16/14 11:28
Bromoform ug/L ND 0.50 08/16/14 11:28
Bromomethane ug/L ND 5.0 08/16/14 11:28
Carbon tetrachloride ug/L ND 0.50 08/16/14 11:28
Chlorobenzene ug/L ND 0.50 08/16/14 11:28
Chloroethane ug/L ND 1.0 08/16/14 11:28
Chloroform ug/L ND 0.50 08/16/14 11:28
Chloromethane ug/L ND 1.0 08/16/14 11:28
cis-1,2-Dichloroethene ug/L ND 0.50 08/16/14 11:28
cis-1,3-Dichloropropene ug/L ND 0.50 08/16/14 11:28
Dibromochloromethane ug/L ND 0.50 08/16/14 11:28
Dibromomethane ug/L ND 0.50 08/16/14 11:28
Dichlorodifluoromethane ug/L ND 0.50 08/16/14 11:28
Diisopropyl ether ug/L ND 0.50 08/16/14 11:28
Ethylbenzene ug/L ND 0.50 08/16/14 11:28
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 40
DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1265112
Associated Lab Samples:92213504001, 92213504002, 92213504003, 92213504004
Matrix: Water
Analyzed
Hexachloro-1,3-butadiene ug/L ND 2.0 08/16/14 11:28
Isopropylbenzene (Cumene) ug/L ND 0.50 08/16/14 11:28
m&p-Xylene ug/L ND 1.0 08/16/14 11:28
Methyl-tert-butyl ether ug/L ND 0.50 08/16/14 11:28
Methylene Chloride ug/L ND 2.0 08/16/14 11:28
n-Butylbenzene ug/L ND 0.50 08/16/14 11:28
n-Propylbenzene ug/L ND 0.50 08/16/14 11:28
Naphthalene ug/L ND 2.0 08/16/14 11:28
o-Xylene ug/L ND 0.50 08/16/14 11:28
sec-Butylbenzene ug/L ND 0.50 08/16/14 11:28
Styrene ug/L ND 0.50 08/16/14 11:28
tert-Butylbenzene ug/L ND 0.50 08/16/14 11:28
Tetrachloroethene ug/L ND 0.50 08/16/14 11:28
Toluene ug/L ND 0.50 08/16/14 11:28
trans-1,2-Dichloroethene ug/L ND 0.50 08/16/14 11:28
trans-1,3-Dichloropropene ug/L ND 0.50 08/16/14 11:28
Trichloroethene ug/L ND 0.50 08/16/14 11:28
Trichlorofluoromethane ug/L ND 1.0 08/16/14 11:28
Vinyl chloride ug/L ND 1.0 08/16/14 11:28
1,2-Dichloroethane-d4 (S)%103 70-130 08/16/14 11:28
4-Bromofluorobenzene (S)%98 70-130 08/16/14 11:28
Toluene-d8 (S)%100 70-130 08/16/14 11:28
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1265113LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 56.150 112 60-140
1,1,1-Trichloroethane ug/L 55.250 110 60-140
1,1,2,2-Tetrachloroethane ug/L 52.750 105 60-140
1,1,2-Trichloroethane ug/L 54.050 108 60-140
1,1-Dichloroethane ug/L 49.950 100 60-140
1,1-Dichloroethene ug/L 56.150 112 60-140
1,1-Dichloropropene ug/L 58.550 117 60-140
1,2,3-Trichlorobenzene ug/L 55.350 111 60-140
1,2,3-Trichloropropane ug/L 54.050 108 60-140
1,2,4-Trichlorobenzene ug/L 55.050 110 60-140
1,2,4-Trimethylbenzene ug/L 54.150 108 60-140
1,2-Dibromo-3-chloropropane ug/L 56.650 113 60-140
1,2-Dibromoethane (EDB)ug/L 55.850 112 60-140
1,2-Dichlorobenzene ug/L 54.450 109 60-140
1,2-Dichloroethane ug/L 53.750 107 60-140
1,2-Dichloropropane ug/L 52.850 106 60-140
1,3,5-Trimethylbenzene ug/L 52.350 105 60-140
1,3-Dichlorobenzene ug/L 54.750 109 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 40
DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1265113LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichloropropane ug/L 54.150 108 60-140
1,4-Dichlorobenzene ug/L 53.850 108 60-140
2,2-Dichloropropane ug/L 41.650 83 60-140
2-Chlorotoluene ug/L 53.350 107 60-140
4-Chlorotoluene ug/L 53.850 108 60-140
Benzene ug/L 50.850 102 60-140
Bromobenzene ug/L 55.250 110 60-140
Bromochloromethane ug/L 55.450 111 60-140
Bromodichloromethane ug/L 63.250 126 60-140
Bromoform ug/L 51.650 103 60-140
Bromomethane ug/L 40.050 80 60-140
Carbon tetrachloride ug/L 60.150 120 60-140
Chlorobenzene ug/L 52.250 104 60-140
Chloroethane ug/L 46.750 93 60-140
Chloroform ug/L 59.250 118 60-140
Chloromethane ug/L 42.950 86 60-140
cis-1,2-Dichloroethene ug/L 58.850 118 60-140
cis-1,3-Dichloropropene ug/L 48.750 97 60-140
Dibromochloromethane ug/L 55.350 111 60-140
Dibromomethane ug/L 55.550 111 60-140
Dichlorodifluoromethane ug/L 47.550 95 60-140
Diisopropyl ether ug/L 54.850 110 60-140
Ethylbenzene ug/L 49.750 99 60-140
Hexachloro-1,3-butadiene ug/L 52.550 105 60-140
Isopropylbenzene (Cumene) ug/L 56.350 113 60-140
m&p-Xylene ug/L 98.8100 99 60-140
Methyl-tert-butyl ether ug/L 54.350 109 60-140
Methylene Chloride ug/L 51.450 103 60-140
n-Butylbenzene ug/L 54.850 110 60-140
n-Propylbenzene ug/L 53.650 107 60-140
Naphthalene ug/L 56.750 113 60-140
o-Xylene ug/L 49.850 100 60-140
sec-Butylbenzene ug/L 54.650 109 60-140
Styrene ug/L 58.050 116 60-140
tert-Butylbenzene ug/L 55.650 111 60-140
Tetrachloroethene ug/L 52.450 105 60-140
Toluene ug/L 52.850 106 60-140
trans-1,2-Dichloroethene ug/L 55.750 111 60-140
trans-1,3-Dichloropropene ug/L 47.250 94 60-140
Trichloroethene ug/L 53.750 107 60-140
Trichlorofluoromethane ug/L 49.650 99 60-140
Vinyl chloride ug/L 49.250 98 60-140
1,2-Dichloroethane-d4 (S)%101 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%101 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 40

DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1265114MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92213504003
1265115
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L M1,R1208260-140147 5720ND16.4 29.4
1,1,1-Trichloroethane ug/L M1,R1208160-140143 5620ND16.1 28.6
1,1,2,2-Tetrachloroethane ug/L R1208060-140138 5320ND16.0 27.5
1,1,2-Trichloroethane ug/L M1,R1208360-140149 5720ND16.5 29.8
1,1-Dichloroethane ug/L R1207260-140131 5820ND14.3 26.1
1,1-Dichloroethene ug/L R1206060-140129 7320ND11.9 25.7
1,1-Dichloropropene ug/L M1,R1202060-14086 12320ND4.1 17.2
1,2,3-Trichlorobenzene ug/L M1,R1208660-140146 5220ND17.1 29.2
1,2,3-Trichloropropane ug/L M1,R1208860-140150 5220ND17.5 29.9
1,2,4-Trichlorobenzene ug/L R1208160-140140 5320ND16.3 27.9
1,2,4-Trimethylbenzene ug/L M1205460-140120ND10.8 ND
1,2-Dibromo-3-chloropropane ug/L R1208160-140134 4920ND16.3 26.7
1,2-Dibromoethane (EDB)ug/L M1,R1208160-140146 5720ND16.2 29.1
1,2-Dichlorobenzene ug/L R1207960-140136 5220ND15.9 27.1
1,2-Dichloroethane ug/L R1207760-140136 5520ND15.4 27.1
1,2-Dichloropropane ug/L M1,R1207960-140143 5920ND15.7 28.7
1,3,5-Trimethylbenzene ug/L M120260-140620ND.46J 1.2
1,3-Dichlorobenzene ug/L R1207960-140137 5420ND15.8 27.4
1,3-Dichloropropane ug/L M1,R1208060-140143 5620ND16.0 28.6
1,4-Dichlorobenzene ug/L R1207960-140135 5220ND15.8 27.1
2,2-Dichloropropane ug/L M1,R1207860-140142 5820ND15.7 28.3
2-Chlorotoluene ug/L M1,R12010560-140150 3620ND20.9 30.0
4-Chlorotoluene ug/L M1,R1209560-140152 4620ND19.0 30.4
Benzene ug/L M1,R1208160-140146 5720ND16.1 29.1
Bromobenzene ug/L R1206960-140123 5620ND13.8 24.5
Bromochloromethane ug/L M1,R1208360-140150 5720ND16.7 30.0
Bromodichloromethane ug/L M1,R1208860-140161 392012.6 30.1 44.8
Bromoform ug/L M1,R1209260-140162 5520ND18.5 32.4
Bromomethane ug/L M1,R1203460-14077 7820ND6.7 15.3
Carbon tetrachloride ug/L M1,R1209360-140165 5620ND18.5 33.1
Chlorobenzene ug/L M1,R1208260-140145 5620ND16.3 29.0
Chloroethane ug/L R1207260-140130 5820ND14.3 26.0
Chloroform ug/L 20 63 60-140132 232039.4 52.1 65.7
Chloromethane ug/L M1,R1208160-140147 5820ND16.3 29.4
cis-1,2-Dichloroethene ug/L M1,R1208260-140148 5720ND16.4 29.6
cis-1,3-Dichloropropene ug/L M1,R1205760-140128 7620ND11.4 25.5
Dibromochloromethane ug/L M1,R1209660-140172 49204.3 23.5 38.8
Dibromomethane ug/L M1,R1208660-140157 5820ND17.3 31.3
Dichlorodifluoromethane ug/L R1207960-140139 5520ND15.8 27.9
Diisopropyl ether ug/L R1207060-140130 6020ND14.0 26.0
Ethylbenzene ug/L M1,R1204360-140111 8920ND8.5 22.1
Hexachloro-1,3-butadiene ug/L M1,R1209560-140165 5420ND18.9 32.9
Isopropylbenzene (Cumene)ug/L M1,R1205360-140124 8120ND10.5 24.8
m&p-Xylene ug/L M1,R140360-14024 15640ND1.2 9.5
Methyl-tert-butyl ether ug/L R1207660-140138 5720ND15.3 27.6
Methylene Chloride ug/L R1207060-140131 6120ND14.0 26.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 40
DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1265114MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92213504003
1265115
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Butylbenzene ug/L M1,R1203960-140107 9320ND7.8 21.4
n-Propylbenzene ug/L M1,R1204160-140107 8820ND8.3 21.3
Naphthalene ug/L M120360-140720NDND 1.4J
o-Xylene ug/L M1,R120860-14055 15020ND1.6 11.0
sec-Butylbenzene ug/L M1,R1204960-140116 8120ND9.8 23.2
Styrene ug/L M120260-140220ND.45J .33J
tert-Butylbenzene ug/L R1206160-140128 7020ND12.2 25.6
Tetrachloroethene ug/L M1,R1208860-140154 5420ND17.6 30.8
Toluene ug/L M1,R1203660-140106 9920ND7.2 21.3
trans-1,2-Dichloroethene ug/L M1,R1208260-140148 5720ND16.4 29.5
trans-1,3-Dichloropropene ug/L M1,R1205760-140127 7620ND11.4 25.4
Trichloroethene ug/L M1,R1208660-140156 5820ND17.2 31.1
Trichlorofluoromethane ug/L M1,R1208260-140147 5720ND16.4 29.4
Vinyl chloride ug/L M1,R1201160-14061 13820ND2.2 12.2
1,2-Dichloroethane-d4 (S) %100 70-13095
4-Bromofluorobenzene (S) %103 70-130103
Toluene-d8 (S)%98 70-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 40

DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/29427
EPA 625
EPA 625
625 MSS
Associated Lab Samples:92213504001, 92213504003, 92213504004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1265135
Associated Lab Samples:92213504001, 92213504003, 92213504004
Matrix:Water
Analyzed
1,2,4-Trichlorobenzene ug/L ND 5.0 08/18/14 19:17
2,4,6-Trichlorophenol ug/L ND 10.0 08/18/14 19:17
2,4-Dichlorophenol ug/L ND 5.0 08/18/14 19:17
2,4-Dimethylphenol ug/L ND 10.0 08/18/14 19:17
2,4-Dinitrophenol ug/L ND 50.0 08/18/14 19:17
2,4-Dinitrotoluene ug/L ND 5.0 08/18/14 19:17
2,6-Dinitrotoluene ug/L ND 5.0 08/18/14 19:17
2-Chloronaphthalene ug/L ND 5.0 08/18/14 19:17
2-Chlorophenol ug/L ND 5.0 08/18/14 19:17
2-Nitrophenol ug/L ND 5.0 08/18/14 19:17
3,3'-Dichlorobenzidine ug/L ND 25.0 08/18/14 19:17
4,6-Dinitro-2-methylphenol ug/L ND 20.0 08/18/14 19:17
4-Bromophenylphenyl ether ug/L ND 5.0 08/18/14 19:17
4-Chloro-3-methylphenol ug/L ND 5.0 08/18/14 19:17
4-Chlorophenylphenyl ether ug/L ND 5.0 08/18/14 19:17
4-Nitrophenol ug/L ND 50.0 08/18/14 19:17
Acenaphthene ug/L ND 5.0 08/18/14 19:17
Acenaphthylene ug/L ND 5.0 08/18/14 19:17
Anthracene ug/L ND 5.0 08/18/14 19:17
Benzo(a)anthracene ug/L ND 5.0 08/18/14 19:17
Benzo(a)pyrene ug/L ND 5.0 08/18/14 19:17
Benzo(b)fluoranthene ug/L ND 5.0 08/18/14 19:17
Benzo(g,h,i)perylene ug/L ND 5.0 08/18/14 19:17
Benzo(k)fluoranthene ug/L ND 5.0 08/18/14 19:17
bis(2-Chloroethoxy)methane ug/L ND 10.0 08/18/14 19:17
bis(2-Chloroethyl) ether ug/L ND 5.0 08/18/14 19:17
bis(2-Chloroisopropyl) ether ug/L ND 5.0 08/18/14 19:17
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 08/18/14 19:17
Butylbenzylphthalate ug/L ND 5.0 08/18/14 19:17
Chrysene ug/L ND 5.0 08/18/14 19:17
Di-n-butylphthalate ug/L ND 5.0 08/18/14 19:17
Di-n-octylphthalate ug/L ND 5.0 08/18/14 19:17
Dibenz(a,h)anthracene ug/L ND 5.0 08/18/14 19:17
Diethylphthalate ug/L ND 5.0 08/18/14 19:17
Dimethylphthalate ug/L ND 5.0 08/18/14 19:17
Fluoranthene ug/L ND 5.0 08/18/14 19:17
Fluorene ug/L ND 5.0 08/18/14 19:17
Hexachloro-1,3-butadiene ug/L ND 5.0 08/18/14 19:17
Hexachlorobenzene ug/L ND 5.0 08/18/14 19:17
Hexachlorocyclopentadiene ug/L ND 10.0 08/18/14 19:17
Hexachloroethane ug/L ND 5.0 08/18/14 19:17
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 40

DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1265135
Associated Lab Samples:92213504001, 92213504003, 92213504004
Matrix:Water
Analyzed
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 08/18/14 19:17
Isophorone ug/L ND 10.0 08/18/14 19:17
N-Nitroso-di-n-propylamine ug/L ND 5.0 08/18/14 19:17
N-Nitrosodimethylamine ug/L ND 5.0 08/18/14 19:17
N-Nitrosodiphenylamine ug/L ND 10.0 08/18/14 19:17
Naphthalene ug/L ND 5.0 08/18/14 19:17
Nitrobenzene ug/L ND 5.0 08/18/14 19:17
Pentachlorophenol ug/L ND 10.0 08/18/14 19:17
Phenanthrene ug/L ND 5.0 08/18/14 19:17
Phenol ug/L ND 5.0 08/18/14 19:17
Pyrene ug/L ND 5.0 08/18/14 19:17
2,4,6-Tribromophenol (S)%85 10-137 08/18/14 19:17
2-Fluorobiphenyl (S)%75 15-120 08/18/14 19:17
2-Fluorophenol (S)%37 10-120 08/18/14 19:17
Nitrobenzene-d5 (S)%75 10-120 08/18/14 19:17
Phenol-d6 (S)%25 10-120 08/18/14 19:17
Terphenyl-d14 (S)%100 11-131 08/18/14 19:17
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1265136LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 35.850 72 44-142
2,4,6-Trichlorophenol ug/L 41.650 83 37-144
2,4-Dichlorophenol ug/L 44.850 90 1-191
2,4-Dimethylphenol ug/L 44.550 89 32-119
2,4-Dinitrophenol ug/L 253250 101 1-181
2,4-Dinitrotoluene ug/L 52.650 105 39-139
2,6-Dinitrotoluene ug/L 50.050 100 50-158
2-Chloronaphthalene ug/L 38.650 77 60-118
2-Chlorophenol ug/L 37.150 74 23-134
2-Nitrophenol ug/L 44.550 89 29-182
3,3'-Dichlorobenzidine ug/L 97.5100 98 1-262
4,6-Dinitro-2-methylphenol ug/L 103100 103 1-181
4-Bromophenylphenyl ether ug/L 45.950 92 53-127
4-Chloro-3-methylphenol ug/L 96.7100 97 22-147
4-Chlorophenylphenyl ether ug/L 48.150 96 25-158
4-Nitrophenol ug/L 120250 48 1-132
Acenaphthene ug/L 43.250 86 47-145
Acenaphthylene ug/L 43.150 86 33-145
Anthracene ug/L 45.150 90 1-166
Benzo(a)anthracene ug/L 43.250 86 33-143
Benzo(a)pyrene ug/L 42.650 85 17-163
Benzo(b)fluoranthene ug/L 41.450 83 24-159
Benzo(g,h,i)perylene ug/L 41.750 83 1-219
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 40

DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1265136LABORATORY CONTROL SAMPLE:
LCSSpike
Benzo(k)fluoranthene ug/L 41.950 84 11-162
bis(2-Chloroethoxy)methane ug/L 42.550 85 33-184
bis(2-Chloroethyl) ether ug/L 38.550 77 12-158
bis(2-Chloroisopropyl) ether ug/L 36.250 72 36-166
bis(2-Ethylhexyl)phthalate ug/L 50.150 100 8-158
Butylbenzylphthalate ug/L 48.850 98 1-152
Chrysene ug/L 43.650 87 17-168
Di-n-butylphthalate ug/L 51.650 103 1-118
Di-n-octylphthalate ug/L 50.550 101 4-146
Dibenz(a,h)anthracene ug/L 44.150 88 1-227
Diethylphthalate ug/L 54.150 108 1-114
Dimethylphthalate ug/L 50.650 101 1-112
Fluoranthene ug/L 50.350 101 26-137
Fluorene ug/L 48.150 96 59-121
Hexachloro-1,3-butadiene ug/L 35.150 70 24-116
Hexachlorobenzene ug/L 42.450 85 1-152
Hexachlorocyclopentadiene ug/L 34.250 68 25-150
Hexachloroethane ug/L 30.350 61 40-113
Indeno(1,2,3-cd)pyrene ug/L 34.550 69 1-171
Isophorone ug/L 44.550 89 21-196
N-Nitroso-di-n-propylamine ug/L 44.750 89 1-230
N-Nitrosodimethylamine ug/L 22.750 45 25-150
N-Nitrosodiphenylamine ug/L 42.750 85 25-150
Naphthalene ug/L 40.050 80 21-133
Nitrobenzene ug/L 43.150 86 35-180
Pentachlorophenol ug/L 84.7100 85 14-176
Phenanthrene ug/L 42.650 85 54-120
Phenol ug/L 19.150 38 5-112
Pyrene ug/L 42.250 84 52-115
2,4,6-Tribromophenol (S)%99 10-137
2-Fluorobiphenyl (S)%83 15-120
2-Fluorophenol (S)%43 10-120
Nitrobenzene-d5 (S)%84 10-120
Phenol-d6 (S)%30 10-120
Terphenyl-d14 (S)%89 11-131
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1265137MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92213504004
1265138
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/L 100 69 44-14274 7100ND69.1 74.2
2,4,6-Trichlorophenol ug/L 100 74 37-14485 13100ND74.1 84.7
2,4-Dichlorophenol ug/L 100 79 1-19189 12100ND78.5 88.6
2,4-Dimethylphenol ug/L 100 79 32-11987 9100ND79.0 86.7
2,4-Dinitrophenol ug/L R1500791-181112 34500ND396558
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 40

DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1265137MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92213504004
1265138
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
2,4-Dinitrotoluene ug/L 100 94 39-139108 14100ND93.8 108
2,6-Dinitrotoluene ug/L 100 89 50-158102 14100ND88.7 102
2-Chloronaphthalene ug/L 100 73 60-11880 10100ND72.7 80.1
2-Chlorophenol ug/L 100 66 23-13482 21100ND65.9 81.7
2-Nitrophenol ug/L 100 75 29-18288 16100ND75.0 87.9
3,3'-Dichlorobenzidine ug/L 200 89 1-26298 10200ND178196
4,6-Dinitro-2-methylphenol ug/L 200 93 1-181108 14200ND187216
4-Bromophenylphenyl ether ug/L 100 90 53-12793 3100ND90.0 92.9
4-Chloro-3-methylphenol ug/L 200 83 22-147100 19200ND166200
4-Chlorophenylphenyl ether ug/L 100 89 25-15898 10100ND88.9 98.2
4-Nitrophenol ug/L R1500601-13283 32500ND302416
Acenaphthene ug/L 100 81 47-14589 10100ND80.8 89.2
Acenaphthylene ug/L 100 79 33-14586 9100ND79.2 86.4
Anthracene ug/L 100 86 1-16690 5100ND86.0 90.0
Benzo(a)anthracene ug/L 100 84 33-14389 6100ND83.6 88.9
Benzo(a)pyrene ug/L 100 85 17-16387 3100ND84.6 86.9
Benzo(b)fluoranthene ug/L 100 88 24-15991 4100ND87.6 91.4
Benzo(g,h,i)perylene ug/L 100 83 1-21986 3100ND82.9 85.6
Benzo(k)fluoranthene ug/L 100 82 11-16280 2100ND81.9 80.5
bis(2-Chloroethoxy)methane ug/L 100 71 33-18481 13100ND71.2 81.0
bis(2-Chloroethyl) ether ug/L 100 67 12-15878 15100ND66.5 77.6
bis(2-Chloroisopropyl) ether ug/L 100 63 36-16672 14100ND63.1 72.4
bis(2-Ethylhexyl)phthalate ug/L 100 91 8-158100 10100ND90.9 100
Butylbenzylphthalate ug/L 100 91 1-152101 10100ND91.1 101
Chrysene ug/L 100 86 17-16889 4100ND85.6 88.7
Di-n-butylphthalate ug/L 100 94 1-118103 10100ND93.7 103
Di-n-octylphthalate ug/L 100 86 4-14698 13100ND86.1 98.1
Dibenz(a,h)anthracene ug/L 100 87 1-22789 2100ND86.7 88.6
Diethylphthalate ug/L 100 99 1-114108 8100ND99.5 108
Dimethylphthalate ug/L 100 93 1-112104 11100ND92.8 104
Fluoranthene ug/L 100 92 26-137100 8100ND92.2 99.7
Fluorene ug/L 100 89 59-12198 10100ND88.6 97.5
Hexachloro-1,3-butadiene ug/L 100 75 24-11679 6100ND75.2 79.5
Hexachlorobenzene ug/L 100 84 1-15287 4100ND83.6 86.9
Hexachlorocyclopentadiene ug/L 100 70 25-15081 15100ND70.1 81.3
Hexachloroethane ug/L 100 60 40-11369 13100ND60.2 68.5
Indeno(1,2,3-cd)pyrene ug/L 100 68 1-17171 4100ND68.2 70.8
Isophorone ug/L 100 75 21-19687 15100ND75.2 87.4
N-Nitroso-di-n-propylamine ug/L 100 74 1-23089 19100ND73.7 89.2
N-Nitrosodimethylamine ug/L 100 48 25-15061 23100ND48.3 60.6
N-Nitrosodiphenylamine ug/L 100 83 25-15086 4100ND82.9 86.1
Naphthalene ug/L 100 70 21-13378 11100ND70.3 78.2
Nitrobenzene ug/L 100 74 35-18083 11100ND74.2 83.0
Pentachlorophenol ug/L 200 73 14-17690 21200ND146180
Phenanthrene ug/L 100 83 54-12087 5100ND82.6 87.1
Phenol ug/L R1100415-11258 34100ND41.5 58.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 40

DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1265137MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92213504004
1265138
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Pyrene ug/L 100 83 52-11588 6100ND83.3 88.5
2,4,6-Tribromophenol (S)%93 10-13799
2-Fluorobiphenyl (S)%77 15-12082
2-Fluorophenol (S)%45 10-12056
Nitrobenzene-d5 (S)%73 10-12081
Phenol-d6 (S)%34 10-12049
Terphenyl-d14 (S)%90 11-13192
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 40
DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/29498
EPA 625
EPA 625
625 MSS
Associated Lab Samples: 92213504002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1267588
Associated Lab Samples:92213504002
Matrix: Water
Analyzed
1,2,4-Trichlorobenzene ug/L ND 5.0 08/20/14 13:24
2,4,6-Trichlorophenol ug/L ND 10.0 08/20/14 13:24
2,4-Dichlorophenol ug/L ND 5.0 08/20/14 13:24
2,4-Dimethylphenol ug/L ND 10.0 08/20/14 13:24
2,4-Dinitrophenol ug/L ND 50.0 08/20/14 13:24
2,4-Dinitrotoluene ug/L ND 5.0 08/20/14 13:24
2,6-Dinitrotoluene ug/L ND 5.0 08/20/14 13:24
2-Chloronaphthalene ug/L ND 5.0 08/20/14 13:24
2-Chlorophenol ug/L ND 5.0 08/20/14 13:24
2-Nitrophenol ug/L ND 5.0 08/20/14 13:24
3,3'-Dichlorobenzidine ug/L ND 25.0 08/20/14 13:24
4,6-Dinitro-2-methylphenol ug/L ND 20.0 08/20/14 13:24
4-Bromophenylphenyl ether ug/L ND 5.0 08/20/14 13:24
4-Chloro-3-methylphenol ug/L ND 5.0 08/20/14 13:24
4-Chlorophenylphenyl ether ug/L ND 5.0 08/20/14 13:24
4-Nitrophenol ug/L ND 50.0 08/20/14 13:24
Acenaphthene ug/L ND 5.0 08/20/14 13:24
Acenaphthylene ug/L ND 5.0 08/20/14 13:24
Anthracene ug/L ND 5.0 08/20/14 13:24
Benzo(a)anthracene ug/L ND 5.0 08/20/14 13:24
Benzo(a)pyrene ug/L ND 5.0 08/20/14 13:24
Benzo(b)fluoranthene ug/L ND 5.0 08/20/14 13:24
Benzo(g,h,i)perylene ug/L ND 5.0 08/20/14 13:24
Benzo(k)fluoranthene ug/L ND 5.0 08/20/14 13:24
bis(2-Chloroethoxy)methane ug/L ND 10.0 08/20/14 13:24
bis(2-Chloroethyl) ether ug/L ND 5.0 08/20/14 13:24
bis(2-Chloroisopropyl) ether ug/L ND 5.0 08/20/14 13:24
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 08/20/14 13:24
Butylbenzylphthalate ug/L ND 5.0 08/20/14 13:24
Chrysene ug/L ND 5.0 08/20/14 13:24
Di-n-butylphthalate ug/L ND 5.0 08/20/14 13:24
Di-n-octylphthalate ug/L ND 5.0 08/20/14 13:24
Dibenz(a,h)anthracene ug/L ND 5.0 08/20/14 13:24
Diethylphthalate ug/L ND 5.0 08/20/14 13:24
Dimethylphthalate ug/L ND 5.0 08/20/14 13:24
Fluoranthene ug/L ND 5.0 08/20/14 13:24
Fluorene ug/L ND 5.0 08/20/14 13:24
Hexachloro-1,3-butadiene ug/L ND 5.0 08/20/14 13:24
Hexachlorobenzene ug/L ND 5.0 08/20/14 13:24
Hexachlorocyclopentadiene ug/L ND 10.0 08/20/14 13:24
Hexachloroethane ug/L ND 5.0 08/20/14 13:24
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 40

DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1267588
Associated Lab Samples:92213504002
Matrix:Water
Analyzed
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 08/20/14 13:24
Isophorone ug/L ND 10.0 08/20/14 13:24
N-Nitroso-di-n-propylamine ug/L ND 5.0 08/20/14 13:24
N-Nitrosodimethylamine ug/L ND 5.0 08/20/14 13:24
N-Nitrosodiphenylamine ug/L ND 10.0 08/20/14 13:24
Naphthalene ug/L ND 5.0 08/20/14 13:24
Nitrobenzene ug/L ND 5.0 08/20/14 13:24
Pentachlorophenol ug/L ND 10.0 08/20/14 13:24
Phenanthrene ug/L ND 5.0 08/20/14 13:24
Phenol ug/L ND 5.0 08/20/14 13:24
Pyrene ug/L ND 5.0 08/20/14 13:24
2,4,6-Tribromophenol (S)%80 10-137 08/20/14 13:24
2-Fluorobiphenyl (S)%75 15-120 08/20/14 13:24
2-Fluorophenol (S)%35 10-120 08/20/14 13:24
Nitrobenzene-d5 (S)%70 10-120 08/20/14 13:24
Phenol-d6 (S)%21 10-120 08/20/14 13:24
Terphenyl-d14 (S)%89 11-131 08/20/14 13:24
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1267589LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1267590
1,2,4-Trichlorobenzene ug/L 38.150 76 44-1427437.0 3 30
2,4,6-Trichlorophenol ug/L 41.050 82 37-1448341.4 1 30
2,4-Dichlorophenol ug/L 45.450 91 1-1919346.4 2 30
2,4-Dimethylphenol ug/L 44.450 89 32-1199045.0 1 30
2,4-Dinitrophenol ug/L 248250 99 1-181107267 7 30
2,4-Dinitrotoluene ug/L 54.050 108 39-13911155.3 2 30
2,6-Dinitrotoluene ug/L 49.550 99 50-15810351.3 4 30
2-Chloronaphthalene ug/L 38.150 76 60-1187839.0 2 30
2-Chlorophenol ug/L 36.050 72 23-1347135.4 1 30
2-Nitrophenol ug/L 42.150 84 29-1828642.9 2 30
3,3'-Dichlorobenzidine ug/L 98.6100 99 1-262102102 3 30
4,6-Dinitro-2-methylphenol ug/L 98.3100 98 1-181106106 8 30
4-Bromophenylphenyl ether ug/L 44.350 89 53-1278944.6 1 30
4-Chloro-3-methylphenol ug/L 101100 101 22-147103103 2 30
4-Chlorophenylphenyl ether ug/L 48.650 97 25-1589949.6 2 30
4-Nitrophenol ug/L 121250 48 1-13250124 3 30
Acenaphthene ug/L 42.450 85 47-1458642.9 1 30
Acenaphthylene ug/L 41.450 83 33-1458542.6 3 30
Anthracene ug/L 43.150 86 1-1668844.0 2 30
Benzo(a)anthracene ug/L 42.850 86 33-1438643.1 1 30
Benzo(a)pyrene ug/L 41.750 83 17-1638642.8 2 30
Benzo(b)fluoranthene ug/L 42.250 84 24-1598542.5 1 30
Benzo(g,h,i)perylene ug/L 39.650 79 1-2198241.2 4 30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 40
DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1267589LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1267590
Benzo(k)fluoranthene ug/L 38.950 78 11-1628241.0 5 30
bis(2-Chloroethoxy)methane ug/L 40.350 81 33-1848241.0 2 30
bis(2-Chloroethyl) ether ug/L 36.850 74 12-1587235.8 3 30
bis(2-Chloroisopropyl) ether ug/L 33.950 68 36-1666733.5 1 30
bis(2-Ethylhexyl)phthalate ug/L 48.050 96 8-1589748.6 1 30
Butylbenzylphthalate ug/L 47.450 95 1-1529648.0 1 30
Chrysene ug/L 42.350 85 17-1688542.6 1 30
Di-n-butylphthalate ug/L 47.850 96 1-11810150.3 5 30
Di-n-octylphthalate ug/L 47.250 94 4-1469748.6 3 30
Dibenz(a,h)anthracene ug/L 41.550 83 1-2278643.2 4 30
Diethylphthalate ug/L 52.450 105 1-11410854.1 3 30
Dimethylphthalate ug/L 49.050 98 1-11210150.3 3 30
Fluoranthene ug/L 47.550 95 26-1379849.2 3 30
Fluorene ug/L 47.950 96 59-1219748.6 1 30
Hexachloro-1,3-butadiene ug/L 38.850 78 24-1167637.8 3 30
Hexachlorobenzene ug/L 41.950 84 1-1528642.9 2 30
Hexachlorocyclopentadiene ug/L 34.250 68 25-1507035.2 3 30
Hexachloroethane ug/L 32.550 65 40-1136230.8 5 30
Indeno(1,2,3-cd)pyrene ug/L 33.150 66 1-1716833.9 2 30
Isophorone ug/L 43.250 86 21-1968944.4 3 30
N-Nitroso-di-n-propylamine ug/L 43.150 86 1-2309145.5 5 30
N-Nitrosodimethylamine ug/L 20.650 41 25-1504019.8 4 30
N-Nitrosodiphenylamine ug/L 41.650 83 25-1508542.3 2 30
Naphthalene ug/L 39.250 78 21-1337839.1 0 30
Nitrobenzene ug/L 41.250 82 35-1808241.0 0 30
Pentachlorophenol ug/L 80.7100 81 14-1768585.2 5 30
Phenanthrene ug/L 41.050 82 54-1208542.6 4 30
Phenol ug/L 19.150 38 5-1123718.4 3 30
Pyrene ug/L 41.450 83 52-1158542.5 3 30
2,4,6-Tribromophenol (S)%95 10-13799
2-Fluorobiphenyl (S)%78 15-12078
2-Fluorophenol (S)%40 10-12039
Nitrobenzene-d5 (S)%79 10-12079
Phenol-d6 (S)%28 10-12027
Terphenyl-d14 (S)%88 11-13189
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 40

DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/29430
MADEP EPH
MADEP EPH
MADEP EPH NC Water
Associated Lab Samples:92213504001, 92213504002, 92213504004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1265264
Associated Lab Samples:92213504001, 92213504002, 92213504004
Matrix:Water
Analyzed
Aliphatic (C09-C18)ug/L ND 100 N208/18/14 11:36
Aliphatic (C19-C36)ug/L ND 100 N208/18/14 11:36
Aromatic (C11-C22)ug/L ND 100 N208/18/14 11:36
2-Bromonaphthalene (S)%81 40-140 08/18/14 11:36
2-Fluorobiphenyl (S)%72 40-140 08/18/14 11:36
Nonatriacontane (S)%61 40-140 08/18/14 11:36
o-Terphenyl (S)%78 40-140 08/18/14 11:36
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1265265LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1265266
Aliphatic (C09-C18)ug/L 192 N23006440-14062187 3 50
Aliphatic (C19-C36)ug/L 289 N24007240-14068273 6 50
Aromatic (C11-C22)ug/L 740 N28508740-14075638 15 50
2-Bromonaphthalene (S)%90 40-14071
2-Fluorobiphenyl (S)%84 40-14070
Nonatriacontane (S)%59 40-14056
o-Terphenyl (S)%89 40-14075
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 40

DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/29488
MADEP EPH
MADEP EPH
MADEP EPH NC Water
Associated Lab Samples:92213504003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1267204
Associated Lab Samples:92213504003
Matrix:Water
Analyzed
Aliphatic (C09-C18)ug/L ND 100 N208/20/14 20:46
Aliphatic (C19-C36)ug/L ND 100 N208/20/14 20:46
Aromatic (C11-C22)ug/L ND 100 N208/20/14 20:46
2-Bromonaphthalene (S)%72 40-140 08/20/14 20:46
2-Fluorobiphenyl (S)%61 40-140 08/20/14 20:46
Nonatriacontane (S)%48 40-140 08/20/14 20:46
o-Terphenyl (S)%60 40-140 08/20/14 20:46
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1267205LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1267206
Aliphatic (C09-C18)ug/L 194 N23006540-14053159 20 50
Aliphatic (C19-C36)ug/L 280 N24007040-14059238 16 50
Aromatic (C11-C22)ug/L 601 N28507140-14068579 4 50
2-Bromonaphthalene (S)%73 40-14071
2-Fluorobiphenyl (S)%70 40-14069
Nonatriacontane (S)%60 40-14053
o-Terphenyl (S)%74 40-14065
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 40
DRAFT
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution ofthe sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold TNI accreditation for this parameter.N2
RPD value was outside control limits.R1
Surrogate recovery outside laboratory control limits.S0
Surrogate recovery outside laboratory control limits due to matrix interferences (confirmed by similar results from samplere-analysis).S2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 40
DRAFT
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92213504
FLOWERS STORE PROPERTY
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92213504001 OEXT/29430 GCSV/18584MW-5 MADEP EPH MADEP EPH
92213504002 OEXT/29430 GCSV/18584MW-7 MADEP EPH MADEP EPH
92213504003 OEXT/29488 GCSV/18631WSW-4 MADEP EPH MADEP EPH
92213504004 OEXT/29430 GCSV/18584WSW-6 MADEP EPH MADEP EPH
92213504001 GCV/8453MW-5 MADEP VPH
92213504002 GCV/8453MW-7 MADEP VPH
92213504003 GCV/8453WSW-4 MADEP VPH
92213504004 GCV/8453WSW-6 MADEP VPH
92213504001 MPRP/16699 ICP/15080MW-5 EPA 3010 EPA 6010
92213504002 MPRP/16699 ICP/15080MW-7 EPA 3010 EPA 6010
92213504003 MPRP/16699 ICP/15080WSW-4 EPA 3010 EPA 6010
92213504004 MPRP/16699 ICP/15080WSW-6 EPA 3010 EPA 6010
92213504001 OEXT/29427 MSSV/9548MW-5 EPA 625 EPA 625
92213504002 OEXT/29498 MSSV/9557MW-7 EPA 625 EPA 625
92213504003 OEXT/29427 MSSV/9548WSW-4 EPA 625 EPA 625
92213504004 OEXT/29427 MSSV/9548WSW-6 EPA 625 EPA 625
92213504001 MSV/27974MW-5 SM 6200B
92213504002 MSV/27974MW-7 SM 6200B
92213504003 MSV/27974WSW-4 SM 6200B
92213504004 MSV/27974WSW-6 SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/21/2014 04:25 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 40
DRAFT
Page 39 of 40
DRAFT
Page 40 of 40

DRAFT
#=CL#
August 28, 2014
LIMS USE: FR - MATTHEW GILLIS
LIMS OBJECT ID: 92214436
92214436
Project:
Pace Project No.:
RE:
Matthew GillisECS9001 Glenwood AvenueRaleigh, NC 27617
FLOWERS STORE N14007i-C
Dear Matthew Gillis:
Enclosed are the analytical results for sample(s) received by the laboratory on August 21, 2014. The
results relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
cc:Matthew Gillis, ECS Carolinas LLP
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 24
DRAFT
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Georgia Certification: Virginia/VELAP ID# 46022Kentucky UST Certification #: 84West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs2225 Riverside Dr., Asheville, NC 28804Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001West Virginia Certification #: 356Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 24
DRAFT
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92214436001 WSW-5
1,2-Dichloropropane 1.4 ug/L 08/22/14 17:360.50SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 24
DRAFT
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Sample: WSW-5 Lab ID: 92214436001 Collected: 08/20/14 10:15 Received: 08/21/14 17:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: MADEP EPH Preparation Method: MADEP EPHMADEP EPH NC Water
Aliphatic (C09-C18)ND ug/L 08/26/14 19:24 N208/25/14 08:26100 1
Aliphatic (C19-C36)ND ug/L 08/26/14 19:24 N208/25/14 08:26100 1
Aromatic (C11-C22)ND ug/L 08/26/14 07:12 N208/25/14 08:26100 1
Surrogates
Nonatriacontane (S)43 %08/26/14 19:24 7194-86-708/25/14 08:2640-140 1
o-Terphenyl (S)65 %08/26/14 07:12 84-15-108/25/14 08:2640-140 1
2-Fluorobiphenyl (S)68 %08/26/14 07:12 321-60-808/25/14 08:2640-140 1
2-Bromonaphthalene (S)80 %08/26/14 07:12 580-13-208/25/14 08:2640-140 1
Analytical Method: MADEP VPHVPH NC Water
Aliphatic (C05-C08)ND ug/L 08/26/14 20:54 N250.0 1
Aliphatic (C09-C12)ND ug/L 08/26/14 20:54 N250.0 1
Aromatic (C09-C10)ND ug/L 08/26/14 20:54 N250.0 1
Surrogates4-Bromofluorobenzene (FID) (S)88 %08/26/14 20:54 460-00-470-130 1
4-Bromofluorobenzene (PID) (S)88 %08/26/14 20:54 460-00-470-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP
Lead ND ug/L 08/25/14 18:55 7439-92-108/22/14 16:005.0 1
Analytical Method: EPA 625 Preparation Method: EPA 625625 MSSV
Acenaphthene ND ug/L 08/26/14 22:18 83-32-908/25/14 09:405.0 1
Acenaphthylene ND ug/L 08/26/14 22:18 208-96-808/25/14 09:405.0 1
Anthracene ND ug/L 08/26/14 22:18 120-12-708/25/14 09:405.0 1
Benzo(a)anthracene ND ug/L 08/26/14 22:18 56-55-308/25/14 09:405.0 1
Benzo(a)pyrene ND ug/L 08/26/14 22:18 50-32-808/25/14 09:405.0 1
Benzo(b)fluoranthene ND ug/L 08/26/14 22:18 205-99-208/25/14 09:405.0 1
Benzo(g,h,i)perylene ND ug/L 08/26/14 22:18 191-24-208/25/14 09:405.0 1
Benzo(k)fluoranthene ND ug/L 08/26/14 22:18 207-08-908/25/14 09:405.0 1
4-Bromophenylphenyl ether ND ug/L 08/26/14 22:18 101-55-308/25/14 09:405.0 1
Butylbenzylphthalate ND ug/L 08/26/14 22:18 85-68-708/25/14 09:405.0 1
4-Chloro-3-methylphenol ND ug/L 08/26/14 22:18 59-50-708/25/14 09:405.0 1
bis(2-Chloroethoxy)methane ND ug/L 08/26/14 22:18 111-91-108/25/14 09:4010.0 1
bis(2-Chloroethyl) ether ND ug/L 08/26/14 22:18 111-44-408/25/14 09:405.0 1
bis(2-Chloroisopropyl) ether ND ug/L 08/26/14 22:18 108-60-108/25/14 09:405.0 1
2-Chloronaphthalene ND ug/L 08/26/14 22:18 91-58-708/25/14 09:405.0 1
2-Chlorophenol ND ug/L 08/26/14 22:18 95-57-808/25/14 09:405.0 1
4-Chlorophenylphenyl ether ND ug/L 08/26/14 22:18 7005-72-308/25/14 09:405.0 1
Chrysene ND ug/L 08/26/14 22:18 218-01-908/25/14 09:405.0 1
Dibenz(a,h)anthracene ND ug/L 08/26/14 22:18 53-70-308/25/14 09:405.0 1
3,3'-Dichlorobenzidine ND ug/L 08/26/14 22:18 91-94-108/25/14 09:4025.0 1
2,4-Dichlorophenol ND ug/L 08/26/14 22:18 120-83-208/25/14 09:405.0 1
Diethylphthalate ND ug/L 08/26/14 22:18 84-66-208/25/14 09:405.0 1
2,4-Dimethylphenol ND ug/L 08/26/14 22:18 105-67-908/25/14 09:4010.0 1
Dimethylphthalate ND ug/L 08/26/14 22:18 131-11-308/25/14 09:405.0 1
Di-n-butylphthalate ND ug/L 08/26/14 22:18 84-74-208/25/14 09:405.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 24
DRAFT
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Sample: WSW-5 Lab ID: 92214436001 Collected: 08/20/14 10:15 Received: 08/21/14 17:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 625 Preparation Method: EPA 625625 MSSV
4,6-Dinitro-2-methylphenol ND ug/L 08/26/14 22:18 534-52-108/25/14 09:4020.0 1
2,4-Dinitrophenol ND ug/L 08/26/14 22:18 51-28-508/25/14 09:4050.0 1
2,4-Dinitrotoluene ND ug/L 08/26/14 22:18 121-14-208/25/14 09:405.0 1
2,6-Dinitrotoluene ND ug/L 08/26/14 22:18 606-20-208/25/14 09:405.0 1
Di-n-octylphthalate ND ug/L 08/26/14 22:18 117-84-008/25/14 09:405.0 1
bis(2-Ethylhexyl)phthalate ND ug/L 08/26/14 22:18 117-81-708/25/14 09:405.0 1
Fluoranthene ND ug/L 08/26/14 22:18 206-44-008/25/14 09:405.0 1
Fluorene ND ug/L 08/26/14 22:18 86-73-708/25/14 09:405.0 1
Hexachloro-1,3-butadiene ND ug/L 08/26/14 22:18 87-68-308/25/14 09:405.0 1
Hexachlorobenzene ND ug/L 08/26/14 22:18 118-74-108/25/14 09:405.0 1
Hexachlorocyclopentadiene ND ug/L 08/26/14 22:18 77-47-408/25/14 09:4010.0 1
Hexachloroethane ND ug/L 08/26/14 22:18 67-72-108/25/14 09:405.0 1
Indeno(1,2,3-cd)pyrene ND ug/L 08/26/14 22:18 193-39-508/25/14 09:405.0 1
Isophorone ND ug/L 08/26/14 22:18 78-59-108/25/14 09:4010.0 1
Naphthalene ND ug/L 08/26/14 22:18 91-20-308/25/14 09:405.0 1
Nitrobenzene ND ug/L 08/26/14 22:18 98-95-308/25/14 09:405.0 1
2-Nitrophenol ND ug/L 08/26/14 22:18 88-75-508/25/14 09:405.0 1
4-Nitrophenol ND ug/L 08/26/14 22:18 100-02-708/25/14 09:4050.0 1
N-Nitrosodimethylamine ND ug/L 08/26/14 22:18 62-75-908/25/14 09:405.0 1
N-Nitroso-di-n-propylamine ND ug/L 08/26/14 22:18 621-64-708/25/14 09:405.0 1
N-Nitrosodiphenylamine ND ug/L 08/26/14 22:18 86-30-608/25/14 09:4010.0 1
Pentachlorophenol ND ug/L 08/26/14 22:18 87-86-508/25/14 09:4010.0 1
Phenanthrene ND ug/L 08/26/14 22:18 85-01-808/25/14 09:405.0 1
Phenol ND ug/L 08/26/14 22:18 108-95-208/25/14 09:405.0 1
Pyrene ND ug/L 08/26/14 22:18 129-00-008/25/14 09:405.0 1
1,2,4-Trichlorobenzene ND ug/L 08/26/14 22:18 120-82-108/25/14 09:405.0 1
2,4,6-Trichlorophenol ND ug/L 08/26/14 22:18 88-06-208/25/14 09:4010.0 1
SurrogatesNitrobenzene-d5 (S)77 %08/26/14 22:18 4165-60-008/25/14 09:4010-120 1
2-Fluorobiphenyl (S)79 %08/26/14 22:18 321-60-808/25/14 09:4015-120 1
Terphenyl-d14 (S)89 %08/26/14 22:18 1718-51-008/25/14 09:4011-131 1
Phenol-d6 (S)27 %08/26/14 22:18 13127-88-308/25/14 09:4010-120 1
2-Fluorophenol (S)41 %08/26/14 22:18 367-12-408/25/14 09:4010-120 1
2,4,6-Tribromophenol (S)85 %08/26/14 22:18 118-79-608/25/14 09:4010-137 1
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 08/22/14 17:36 71-43-20.50 1
Bromobenzene ND ug/L 08/22/14 17:36 108-86-10.50 1
Bromochloromethane ND ug/L 08/22/14 17:36 74-97-50.50 1
Bromodichloromethane ND ug/L 08/22/14 17:36 75-27-4 L30.50 1
Bromoform ND ug/L 08/22/14 17:36 75-25-20.50 1
Bromomethane ND ug/L 08/22/14 17:36 74-83-95.0 1
n-Butylbenzene ND ug/L 08/22/14 17:36 104-51-80.50 1
sec-Butylbenzene ND ug/L 08/22/14 17:36 135-98-80.50 1
tert-Butylbenzene ND ug/L 08/22/14 17:36 98-06-60.50 1
Carbon tetrachloride ND ug/L 08/22/14 17:36 56-23-5 M10.50 1
Chlorobenzene ND ug/L 08/22/14 17:36 108-90-70.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 24
DRAFT
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Sample: WSW-5 Lab ID: 92214436001 Collected: 08/20/14 10:15 Received: 08/21/14 17:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Chloroethane ND ug/L 08/22/14 17:36 75-00-31.0 1
Chloroform ND ug/L 08/22/14 17:36 67-66-3 M10.50 1
Chloromethane ND ug/L 08/22/14 17:36 74-87-31.0 1
2-Chlorotoluene ND ug/L 08/22/14 17:36 95-49-80.50 1
4-Chlorotoluene ND ug/L 08/22/14 17:36 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 08/22/14 17:36 96-12-81.0 1
Dibromochloromethane ND ug/L 08/22/14 17:36 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 08/22/14 17:36 106-93-40.50 1
Dibromomethane ND ug/L 08/22/14 17:36 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 08/22/14 17:36 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 08/22/14 17:36 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 08/22/14 17:36 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 08/22/14 17:36 75-71-8 M10.50 1
1,1-Dichloroethane ND ug/L 08/22/14 17:36 75-34-30.50 1
1,2-Dichloroethane ND ug/L 08/22/14 17:36 107-06-20.50 1
1,1-Dichloroethene ND ug/L 08/22/14 17:36 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 08/22/14 17:36 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 08/22/14 17:36 156-60-50.50 1
1,2-Dichloropropane 1.4 ug/L 08/22/14 17:36 78-87-50.50 1
1,3-Dichloropropane ND ug/L 08/22/14 17:36 142-28-90.50 1
2,2-Dichloropropane ND ug/L 08/22/14 17:36 594-20-70.50 1
1,1-Dichloropropene ND ug/L 08/22/14 17:36 563-58-6 M10.50 1
cis-1,3-Dichloropropene ND ug/L 08/22/14 17:36 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 08/22/14 17:36 10061-02-60.50 1
Diisopropyl ether ND ug/L 08/22/14 17:36 108-20-30.50 1
Ethylbenzene ND ug/L 08/22/14 17:36 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 08/22/14 17:36 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 08/22/14 17:36 98-82-80.50 1
Methylene Chloride ND ug/L 08/22/14 17:36 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 08/22/14 17:36 1634-04-40.50 1
Naphthalene ND ug/L 08/22/14 17:36 91-20-32.0 1
n-Propylbenzene ND ug/L 08/22/14 17:36 103-65-10.50 1
Styrene ND ug/L 08/22/14 17:36 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 08/22/14 17:36 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 08/22/14 17:36 79-34-50.50 1
Tetrachloroethene ND ug/L 08/22/14 17:36 127-18-40.50 1
Toluene ND ug/L 08/22/14 17:36 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 08/22/14 17:36 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 08/22/14 17:36 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 08/22/14 17:36 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 08/22/14 17:36 79-00-50.50 1
Trichloroethene ND ug/L 08/22/14 17:36 79-01-60.50 1
Trichlorofluoromethane ND ug/L 08/22/14 17:36 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 08/22/14 17:36 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 08/22/14 17:36 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 08/22/14 17:36 108-67-80.50 1
Vinyl chloride ND ug/L 08/22/14 17:36 75-01-41.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 24
DRAFT
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Sample: WSW-5 Lab ID: 92214436001 Collected: 08/20/14 10:15 Received: 08/21/14 17:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
m&p-Xylene ND ug/L 08/22/14 17:36 179601-23-11.0 1
o-Xylene ND ug/L 08/22/14 17:36 95-47-60.50 1
Surrogates1,2-Dichloroethane-d4 (S)109 %08/22/14 17:36 17060-07-070-130 1
4-Bromofluorobenzene (S)102 %08/22/14 17:36 460-00-470-130 1
Toluene-d8 (S)99 %08/22/14 17:36 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 24

DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/8481
MADEP VPH
MADEP VPH
VPH NC Water
Associated Lab Samples:92214436001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1272279
Associated Lab Samples:92214436001
Matrix:Water
Analyzed
Aliphatic (C05-C08)ug/L ND 50.0 N208/26/14 17:50
Aliphatic (C09-C12)ug/L ND 50.0 N208/26/14 17:50
Aromatic (C09-C10)ug/L ND 50.0 N208/26/14 17:50
4-Bromofluorobenzene (FID) (S)%34 70-130 08/26/14 17:50
4-Bromofluorobenzene (PID) (S)%34 70-130 08/26/14 17:50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1272280LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1272281
Aliphatic (C05-C08)ug/L 293 N23009870-130107321 9 25
Aliphatic (C09-C12)ug/L 305 N230010230-130112335 9 25
Aromatic (C09-C10)ug/L 92.6 N21009370-1309696.4 4 25
4-Bromofluorobenzene (FID) (S)%100 70-130101
4-Bromofluorobenzene (PID) (S)%100 70-130101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 24

DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/16743
EPA 3010
EPA 6010
6010 MET
Associated Lab Samples:92214436001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1270370
Associated Lab Samples:92214436001
Matrix:Water
Analyzed
Lead ug/L ND 5.0 08/25/14 18:06
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1270371LABORATORY CONTROL SAMPLE:
LCSSpike
Lead ug/L 496500 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1270372MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92214260002
1270373
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Lead ug/L 500 96 75-12595 1500ND485480
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 24
DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/28053
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples: 92214436001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1270558
Associated Lab Samples:92214436001
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 08/22/14 15:40
1,1,1-Trichloroethane ug/L ND 0.50 08/22/14 15:40
1,1,2,2-Tetrachloroethane ug/L ND 0.50 08/22/14 15:40
1,1,2-Trichloroethane ug/L ND 0.50 08/22/14 15:40
1,1-Dichloroethane ug/L ND 0.50 08/22/14 15:40
1,1-Dichloroethene ug/L ND 0.50 08/22/14 15:40
1,1-Dichloropropene ug/L ND 0.50 08/22/14 15:40
1,2,3-Trichlorobenzene ug/L ND 2.0 08/22/14 15:40
1,2,3-Trichloropropane ug/L ND 0.50 08/22/14 15:40
1,2,4-Trichlorobenzene ug/L ND 2.0 08/22/14 15:40
1,2,4-Trimethylbenzene ug/L ND 0.50 08/22/14 15:40
1,2-Dibromo-3-chloropropane ug/L ND 1.0 08/22/14 15:40
1,2-Dibromoethane (EDB)ug/L ND 0.50 08/22/14 15:40
1,2-Dichlorobenzene ug/L ND 0.50 08/22/14 15:40
1,2-Dichloroethane ug/L ND 0.50 08/22/14 15:40
1,2-Dichloropropane ug/L ND 0.50 08/22/14 15:40
1,3,5-Trimethylbenzene ug/L ND 0.50 08/22/14 15:40
1,3-Dichlorobenzene ug/L ND 0.50 08/22/14 15:40
1,3-Dichloropropane ug/L ND 0.50 08/22/14 15:40
1,4-Dichlorobenzene ug/L ND 0.50 08/22/14 15:40
2,2-Dichloropropane ug/L ND 0.50 08/22/14 15:40
2-Chlorotoluene ug/L ND 0.50 08/22/14 15:40
4-Chlorotoluene ug/L ND 0.50 08/22/14 15:40
Benzene ug/L ND 0.50 08/22/14 15:40
Bromobenzene ug/L ND 0.50 08/22/14 15:40
Bromochloromethane ug/L ND 0.50 08/22/14 15:40
Bromodichloromethane ug/L ND 0.50 08/22/14 15:40
Bromoform ug/L ND 0.50 08/22/14 15:40
Bromomethane ug/L ND 5.0 08/22/14 15:40
Carbon tetrachloride ug/L ND 0.50 08/22/14 15:40
Chlorobenzene ug/L ND 0.50 08/22/14 15:40
Chloroethane ug/L ND 1.0 08/22/14 15:40
Chloroform ug/L ND 0.50 08/22/14 15:40
Chloromethane ug/L ND 1.0 08/22/14 15:40
cis-1,2-Dichloroethene ug/L ND 0.50 08/22/14 15:40
cis-1,3-Dichloropropene ug/L ND 0.50 08/22/14 15:40
Dibromochloromethane ug/L ND 0.50 08/22/14 15:40
Dibromomethane ug/L ND 0.50 08/22/14 15:40
Dichlorodifluoromethane ug/L ND 0.50 08/22/14 15:40
Diisopropyl ether ug/L ND 0.50 08/22/14 15:40
Ethylbenzene ug/L ND 0.50 08/22/14 15:40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 24
DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1270558
Associated Lab Samples:92214436001
Matrix: Water
Analyzed
Hexachloro-1,3-butadiene ug/L ND 2.0 08/22/14 15:40
Isopropylbenzene (Cumene) ug/L ND 0.50 08/22/14 15:40
m&p-Xylene ug/L ND 1.0 08/22/14 15:40
Methyl-tert-butyl ether ug/L ND 0.50 08/22/14 15:40
Methylene Chloride ug/L ND 2.0 08/22/14 15:40
n-Butylbenzene ug/L ND 0.50 08/22/14 15:40
n-Propylbenzene ug/L ND 0.50 08/22/14 15:40
Naphthalene ug/L ND 2.0 08/22/14 15:40
o-Xylene ug/L ND 0.50 08/22/14 15:40
sec-Butylbenzene ug/L ND 0.50 08/22/14 15:40
Styrene ug/L ND 0.50 08/22/14 15:40
tert-Butylbenzene ug/L ND 0.50 08/22/14 15:40
Tetrachloroethene ug/L ND 0.50 08/22/14 15:40
Toluene ug/L ND 0.50 08/22/14 15:40
trans-1,2-Dichloroethene ug/L ND 0.50 08/22/14 15:40
trans-1,3-Dichloropropene ug/L ND 0.50 08/22/14 15:40
Trichloroethene ug/L ND 0.50 08/22/14 15:40
Trichlorofluoromethane ug/L ND 1.0 08/22/14 15:40
Vinyl chloride ug/L ND 1.0 08/22/14 15:40
1,2-Dichloroethane-d4 (S)%105 70-130 08/22/14 15:40
4-Bromofluorobenzene (S)%101 70-130 08/22/14 15:40
Toluene-d8 (S)%100 70-130 08/22/14 15:40
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1270559LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 61.550 123 60-140
1,1,1-Trichloroethane ug/L 61.150 122 60-140
1,1,2,2-Tetrachloroethane ug/L 56.350 113 60-140
1,1,2-Trichloroethane ug/L 59.350 119 60-140
1,1-Dichloroethane ug/L 54.150 108 60-140
1,1-Dichloroethene ug/L 60.950 122 60-140
1,1-Dichloropropene ug/L 62.750 125 60-140
1,2,3-Trichlorobenzene ug/L 58.850 118 60-140
1,2,3-Trichloropropane ug/L 59.250 118 60-140
1,2,4-Trichlorobenzene ug/L 58.850 118 60-140
1,2,4-Trimethylbenzene ug/L 56.250 112 60-140
1,2-Dibromo-3-chloropropane ug/L 60.250 120 60-140
1,2-Dibromoethane (EDB)ug/L 59.550 119 60-140
1,2-Dichlorobenzene ug/L 56.450 113 60-140
1,2-Dichloroethane ug/L 61.450 123 60-140
1,2-Dichloropropane ug/L 55.850 112 60-140
1,3,5-Trimethylbenzene ug/L 53.750 107 60-140
1,3-Dichlorobenzene ug/L 56.650 113 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 24
DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1270559LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichloropropane ug/L 57.650 115 60-140
1,4-Dichlorobenzene ug/L 56.650 113 60-140
2,2-Dichloropropane ug/L 65.550 131 60-140
2-Chlorotoluene ug/L 55.050 110 60-140
4-Chlorotoluene ug/L 56.150 112 60-140
Benzene ug/L 53.750 107 60-140
Bromobenzene ug/L 57.450 115 60-140
Bromochloromethane ug/L 61.650 123 60-140
Bromodichloromethane ug/L 71.1 L050142 60-140
Bromoform ug/L 59.150 118 60-140
Bromomethane ug/L 48.750 97 60-140
Carbon tetrachloride ug/L 66.850 134 60-140
Chlorobenzene ug/L 55.750 111 60-140
Chloroethane ug/L 51.550 103 60-140
Chloroform ug/L 66.950 134 60-140
Chloromethane ug/L 48.650 97 60-140
cis-1,2-Dichloroethene ug/L 63.950 128 60-140
cis-1,3-Dichloropropene ug/L 56.050 112 60-140
Dibromochloromethane ug/L 61.950 124 60-140
Dibromomethane ug/L 62.150 124 60-140
Dichlorodifluoromethane ug/L 59.950 120 60-140
Diisopropyl ether ug/L 57.050 114 60-140
Ethylbenzene ug/L 51.950 104 60-140
Hexachloro-1,3-butadiene ug/L 56.650 113 60-140
Isopropylbenzene (Cumene) ug/L 58.750 117 60-140
m&p-Xylene ug/L 104100 104 60-140
Methyl-tert-butyl ether ug/L 57.750 115 60-140
Methylene Chloride ug/L 56.450 113 60-140
n-Butylbenzene ug/L 57.350 115 60-140
n-Propylbenzene ug/L 53.950 108 60-140
Naphthalene ug/L 59.750 119 60-140
o-Xylene ug/L 52.750 105 60-140
sec-Butylbenzene ug/L 55.050 110 60-140
Styrene ug/L 61.750 123 60-140
tert-Butylbenzene ug/L 57.150 114 60-140
Tetrachloroethene ug/L 54.750 109 60-140
Toluene ug/L 56.150 112 60-140
trans-1,2-Dichloroethene ug/L 60.250 120 60-140
trans-1,3-Dichloropropene ug/L 56.550 113 60-140
Trichloroethene ug/L 58.050 116 60-140
Trichlorofluoromethane ug/L 58.450 117 60-140
Vinyl chloride ug/L 53.650 107 60-140
1,2-Dichloroethane-d4 (S)%105 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%99 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 24

DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1270560MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92214436001
1270561
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 120 60-140119 020ND23.9 23.8
1,1,1-Trichloroethane ug/L 20 131 60-140134 220ND26.2 26.9
1,1,2,2-Tetrachloroethane ug/L 20 112 60-140111 020ND22.3 22.2
1,1,2-Trichloroethane ug/L 20 119 60-140117 220ND23.9 23.4
1,1-Dichloroethane ug/L 20 114 60-140115 120ND22.8 23.0
1,1-Dichloroethene ug/L 20 138 60-140139 120ND27.7 27.9
1,1-Dichloropropene ug/L M12014160-140142 120ND28.1 28.3
1,2,3-Trichlorobenzene ug/L 20 111 60-140111 020ND22.2 22.3
1,2,3-Trichloropropane ug/L 20 117 60-140114 320ND23.5 22.9
1,2,4-Trichlorobenzene ug/L 20 110 60-140111 120ND22.0 22.2
1,2,4-Trimethylbenzene ug/L 20 112 60-140113 120ND22.4 22.5
1,2-Dibromo-3-chloropropane ug/L 20 113 60-140110 220ND22.5 22.1
1,2-Dibromoethane (EDB)ug/L 20 116 60-140116 020ND23.1 23.2
1,2-Dichlorobenzene ug/L 20 112 60-140114 120ND22.5 22.8
1,2-Dichloroethane ug/L 20 123 60-140126 320ND24.5 25.3
1,2-Dichloropropane ug/L 20 117 60-140116 1201.4 24.7 24.6
1,3,5-Trimethylbenzene ug/L 20 112 60-140113 120ND22.3 22.6
1,3-Dichlorobenzene ug/L 20 113 60-140114 120ND22.7 22.8
1,3-Dichloropropane ug/L 20 112 60-140114 120ND22.5 22.7
1,4-Dichlorobenzene ug/L 20 114 60-140115 020ND22.9 22.9
2,2-Dichloropropane ug/L 20 122 60-140123 120ND24.3 24.6
2-Chlorotoluene ug/L 20 115 60-140115 020ND23.0 22.9
4-Chlorotoluene ug/L 20 113 60-140114 020ND22.7 22.8
Benzene ug/L 20 115 60-140115 020ND23.0 23.0
Bromobenzene ug/L 20 116 60-140118 220ND23.2 23.6
Bromochloromethane ug/L 20 130 60-140130 020ND26.0 26.1
Bromodichloromethane ug/L 20 138 60-140139 120ND27.6 27.8
Bromoform ug/L 20 112 60-140110 220ND22.3 21.9
Bromomethane ug/L 20 116 60-140120 320ND23.3 23.9
Carbon tetrachloride ug/L M12014460-140144 020ND28.7 28.8
Chlorobenzene ug/L 20 114 60-140115 120ND22.8 23.0
Chloroethane ug/L 20 120 60-140119 020ND23.9 23.9
Chloroform ug/L M12013760-140142 320ND27.5 28.4
Chloromethane ug/L 20 115 60-140116 120ND23.1 23.3
cis-1,2-Dichloroethene ug/L 20 132 60-140136 320ND26.3 27.3
cis-1,3-Dichloropropene ug/L 20 105 60-140106 120ND21.0 21.2
Dibromochloromethane ug/L 20 119 60-140119 020ND23.8 23.7
Dibromomethane ug/L 20 123 60-140126 220ND24.7 25.2
Dichlorodifluoromethane ug/L M12015160-140155 220ND30.3 30.9
Diisopropyl ether ug/L 20 114 60-140118 420ND22.9 23.7
Ethylbenzene ug/L 20 110 60-140110 020ND22.0 22.1
Hexachloro-1,3-butadiene ug/L 20 114 60-140117 220ND22.8 23.4
Isopropylbenzene (Cumene)ug/L 20 124 60-140126 120ND24.9 25.2
m&p-Xylene ug/L 40 110 60-140111 140ND44.0 44.5
Methyl-tert-butyl ether ug/L 20 115 60-140118 320ND23.0 23.6
Methylene Chloride ug/L 20 106 60-140111 420ND21.2 22.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 24
DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1270560MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92214436001
1270561
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Butylbenzene ug/L 20 119 60-140119 020ND23.7 23.7
n-Propylbenzene ug/L 20 114 60-140116 220ND22.8 23.3
Naphthalene ug/L 20 113 60-140111 120ND22.5 22.2
o-Xylene ug/L 20 108 60-140110 220ND21.6 22.0
sec-Butylbenzene ug/L 20 119 60-140119 120ND23.7 23.9
Styrene ug/L 20 122 60-140124 120ND24.5 24.7
tert-Butylbenzene ug/L 20 120 60-140121 020ND24.1 24.1
Tetrachloroethene ug/L 20 120 60-140120 020ND24.0 23.9
Toluene ug/L 20 118 60-140117 120ND23.6 23.5
trans-1,2-Dichloroethene ug/L 20 132 60-140131 120ND26.4 26.2
trans-1,3-Dichloropropene ug/L 20 106 60-140107 120ND21.2 21.4
Trichloroethene ug/L 20 123 60-140124 020ND24.7 24.8
Trichlorofluoromethane ug/L 20 136 60-140136 020ND27.3 27.1
Vinyl chloride ug/L 20 126 60-140127 120ND25.2 25.4
1,2-Dichloroethane-d4 (S) %104 70-130103
4-Bromofluorobenzene (S) %102 70-130101
Toluene-d8 (S)%102 70-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 24
DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/29570
EPA 625
EPA 625
625 MSS
Associated Lab Samples: 92214436001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1270957
Associated Lab Samples:92214436001
Matrix: Water
Analyzed
1,2,4-Trichlorobenzene ug/L ND 5.0 08/26/14 18:57
2,4,6-Trichlorophenol ug/L ND 10.0 08/26/14 18:57
2,4-Dichlorophenol ug/L ND 5.0 08/26/14 18:57
2,4-Dimethylphenol ug/L ND 10.0 08/26/14 18:57
2,4-Dinitrophenol ug/L ND 50.0 08/26/14 18:57
2,4-Dinitrotoluene ug/L ND 5.0 08/26/14 18:57
2,6-Dinitrotoluene ug/L ND 5.0 08/26/14 18:57
2-Chloronaphthalene ug/L ND 5.0 08/26/14 18:57
2-Chlorophenol ug/L ND 5.0 08/26/14 18:57
2-Nitrophenol ug/L ND 5.0 08/26/14 18:57
3,3'-Dichlorobenzidine ug/L ND 25.0 08/26/14 18:57
4,6-Dinitro-2-methylphenol ug/L ND 20.0 08/26/14 18:57
4-Bromophenylphenyl ether ug/L ND 5.0 08/26/14 18:57
4-Chloro-3-methylphenol ug/L ND 5.0 08/26/14 18:57
4-Chlorophenylphenyl ether ug/L ND 5.0 08/26/14 18:57
4-Nitrophenol ug/L ND 50.0 08/26/14 18:57
Acenaphthene ug/L ND 5.0 08/26/14 18:57
Acenaphthylene ug/L ND 5.0 08/26/14 18:57
Anthracene ug/L ND 5.0 08/26/14 18:57
Benzo(a)anthracene ug/L ND 5.0 08/26/14 18:57
Benzo(a)pyrene ug/L ND 5.0 08/26/14 18:57
Benzo(b)fluoranthene ug/L ND 5.0 08/26/14 18:57
Benzo(g,h,i)perylene ug/L ND 5.0 08/26/14 18:57
Benzo(k)fluoranthene ug/L ND 5.0 08/26/14 18:57
bis(2-Chloroethoxy)methane ug/L ND 10.0 08/26/14 18:57
bis(2-Chloroethyl) ether ug/L ND 5.0 08/26/14 18:57
bis(2-Chloroisopropyl) ether ug/L ND 5.0 08/26/14 18:57
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 08/26/14 18:57
Butylbenzylphthalate ug/L ND 5.0 08/26/14 18:57
Chrysene ug/L ND 5.0 08/26/14 18:57
Di-n-butylphthalate ug/L ND 5.0 08/26/14 18:57
Di-n-octylphthalate ug/L ND 5.0 08/26/14 18:57
Dibenz(a,h)anthracene ug/L ND 5.0 08/26/14 18:57
Diethylphthalate ug/L ND 5.0 08/26/14 18:57
Dimethylphthalate ug/L ND 5.0 08/26/14 18:57
Fluoranthene ug/L ND 5.0 08/26/14 18:57
Fluorene ug/L ND 5.0 08/26/14 18:57
Hexachloro-1,3-butadiene ug/L ND 5.0 08/26/14 18:57
Hexachlorobenzene ug/L ND 5.0 08/26/14 18:57
Hexachlorocyclopentadiene ug/L ND 10.0 08/26/14 18:57
Hexachloroethane ug/L ND 5.0 08/26/14 18:57
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 24
DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1270957
Associated Lab Samples:92214436001
Matrix: Water
Analyzed
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 08/26/14 18:57
Isophorone ug/L ND 10.0 08/26/14 18:57
N-Nitroso-di-n-propylamine ug/L ND 5.0 08/26/14 18:57
N-Nitrosodimethylamine ug/L ND 5.0 08/26/14 18:57
N-Nitrosodiphenylamine ug/L ND 10.0 08/26/14 18:57
Naphthalene ug/L ND 5.0 08/26/14 18:57
Nitrobenzene ug/L ND 5.0 08/26/14 18:57
Pentachlorophenol ug/L ND 10.0 08/26/14 18:57
Phenanthrene ug/L ND 5.0 08/26/14 18:57
Phenol ug/L ND 5.0 08/26/14 18:57
Pyrene ug/L ND 5.0 08/26/14 18:57
2,4,6-Tribromophenol (S)%59 10-137 08/26/14 18:57
2-Fluorobiphenyl (S)%48 15-120 08/26/14 18:57
2-Fluorophenol (S)%26 10-120 08/26/14 18:57
Nitrobenzene-d5 (S)%46 10-120 08/26/14 18:57
Phenol-d6 (S)%18 10-120 08/26/14 18:57
Terphenyl-d14 (S)%82 11-131 08/26/14 18:57
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1270958LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 36.450 73 44-142
2,4,6-Trichlorophenol ug/L 40.250 80 37-144
2,4-Dichlorophenol ug/L 43.050 86 1-191
2,4-Dimethylphenol ug/L 44.650 89 32-119
2,4-Dinitrophenol ug/L 218250 87 1-181
2,4-Dinitrotoluene ug/L 46.750 93 39-139
2,6-Dinitrotoluene ug/L 46.750 93 50-158
2-Chloronaphthalene ug/L 40.750 81 60-118
2-Chlorophenol ug/L 35.150 70 23-134
2-Nitrophenol ug/L 43.650 87 29-182
3,3'-Dichlorobenzidine ug/L 91.0100 91 1-262
4,6-Dinitro-2-methylphenol ug/L 97.0100 97 1-181
4-Bromophenylphenyl ether ug/L 44.050 88 53-127
4-Chloro-3-methylphenol ug/L 92.2100 92 22-147
4-Chlorophenylphenyl ether ug/L 44.150 88 25-158
4-Nitrophenol ug/L 97.3250 39 1-132
Acenaphthene ug/L 42.250 84 47-145
Acenaphthylene ug/L 41.650 83 33-145
Anthracene ug/L 44.750 89 1-166
Benzo(a)anthracene ug/L 44.550 89 33-143
Benzo(a)pyrene ug/L 41.950 84 17-163
Benzo(b)fluoranthene ug/L 39.750 79 24-159
Benzo(g,h,i)perylene ug/L 44.050 88 1-219
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 24
DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1270958LABORATORY CONTROL SAMPLE:
LCSSpike
Benzo(k)fluoranthene ug/L 39.250 78 11-162
bis(2-Chloroethoxy)methane ug/L 42.750 85 33-184
bis(2-Chloroethyl) ether ug/L 37.250 74 12-158
bis(2-Chloroisopropyl) ether ug/L 36.450 73 36-166
bis(2-Ethylhexyl)phthalate ug/L 49.250 98 8-158
Butylbenzylphthalate ug/L 48.950 98 1-152
Chrysene ug/L 44.850 90 17-168
Di-n-butylphthalate ug/L 48.750 97 1-118
Di-n-octylphthalate ug/L 50.250 100 4-146
Dibenz(a,h)anthracene ug/L 44.450 89 1-227
Diethylphthalate ug/L 48.350 97 1-114
Dimethylphthalate ug/L 46.750 93 1-112
Fluoranthene ug/L 46.150 92 26-137
Fluorene ug/L 46.150 92 59-121
Hexachloro-1,3-butadiene ug/L 34.750 69 24-116
Hexachlorobenzene ug/L 42.550 85 1-152
Hexachlorocyclopentadiene ug/L 33.450 67 25-150
Hexachloroethane ug/L 33.850 68 40-113
Indeno(1,2,3-cd)pyrene ug/L 36.750 73 1-171
Isophorone ug/L 45.850 92 21-196
N-Nitroso-di-n-propylamine ug/L 43.450 87 1-230
N-Nitrosodimethylamine ug/L 23.550 47 25-150
N-Nitrosodiphenylamine ug/L 45.950 92 25-150
Naphthalene ug/L 38.450 77 21-133
Nitrobenzene ug/L 39.550 79 35-180
Pentachlorophenol ug/L 72.9100 73 14-176
Phenanthrene ug/L 44.150 88 54-120
Phenol ug/L 18.650 37 5-112
Pyrene ug/L 40.650 81 52-115
2,4,6-Tribromophenol (S)%87 10-137
2-Fluorobiphenyl (S)%82 15-120
2-Fluorophenol (S)%43 10-120
Nitrobenzene-d5 (S)%78 10-120
Phenol-d6 (S)%30 10-120
Terphenyl-d14 (S)%84 11-131
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1270960MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92214602001
1270961
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/L 1g,M1,R11003344-14273 75100ND33.4 73.1
2,4,6-Trichlorophenol ug/L 100 45 37-14472 46100ND45.4 72.5
2,4-Dichlorophenol ug/L 100 36 1-19178 73100ND36.0 77.6
2,4-Dimethylphenol ug/L 100 38 32-11983 75100ND37.6 82.6
2,4-Dinitrophenol ug/L 500 71 1-18182 14500ND357 411
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 24

DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1270960MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92214602001
1270961
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
2,4-Dinitrotoluene ug/L 100 83 39-13988 6100ND83.1 88.4
2,6-Dinitrotoluene ug/L 100 77 50-15887 12100ND77.2 86.8
2-Chloronaphthalene ug/L M11003960-11875 63100ND38.8 74.8
2-Chlorophenol ug/L 100 34 23-13470 70100ND33.8 69.8
2-Nitrophenol ug/L 100 38 29-18279 69100ND38.3 79.0
3,3'-Dichlorobenzidine ug/L 200 84 1-26292 9200ND168185
4,6-Dinitro-2-methylphenol ug/L 200 88 1-18193 5200ND177186
4-Bromophenylphenyl ether ug/L 100 70 53-12784 17100ND70.4 83.6
4-Chloro-3-methylphenol ug/L 200 53 22-14786 47200ND106172
4-Chlorophenylphenyl ether ug/L 100 62 25-15879 24100ND62.1 79.4
4-Nitrophenol ug/L 500 52 1-13256 6500ND261278
Acenaphthene ug/L 100 50 47-14576 42100ND49.6 76.1
Acenaphthylene ug/L 100 48 33-14576 45100ND48.4 76.2
Anthracene ug/L 100 78 1-16687 10100ND78.4 86.6
Benzo(a)anthracene ug/L 100 80 33-14388 10100ND80.0 88.3
Benzo(a)pyrene ug/L 100 79 17-16385 7100ND79.4 84.9
Benzo(b)fluoranthene ug/L 100 78 24-15984 7100ND78.2 83.8
Benzo(g,h,i)perylene ug/L 100 83 1-21990 8100ND83.0 89.6
Benzo(k)fluoranthene ug/L 100 72 11-16281 11100ND72.2 80.9
bis(2-Chloroethoxy)methane ug/L 100 35 33-18478 78100ND34.5 78.4
bis(2-Chloroethyl) ether ug/L 100 34 12-15874 74100ND33.9 73.7
bis(2-Chloroisopropyl) ether ug/L M11003236-16670 74100ND32.1 69.6
bis(2-Ethylhexyl)phthalate ug/L 100 87 8-15899 13100ND86.9 99.4
Butylbenzylphthalate ug/L 100 87 1-152100 13100ND87.4 99.5
Chrysene ug/L 100 81 17-16889 9100ND81.4 89.4
Di-n-butylphthalate ug/L 100 90 1-11895 6100ND89.9 95.5
Di-n-octylphthalate ug/L 100 90 4-146101 12100ND90.4 101
Dibenz(a,h)anthracene ug/L 100 85 1-22791 6100ND85.3 91.0
Diethylphthalate ug/L 100 83 1-11488 6100ND86.3 91.5
Dimethylphthalate ug/L 100 78 1-11288 12100ND77.6 87.7
Fluoranthene ug/L 100 87 26-13791 5100ND87.1 91.5
Fluorene ug/L 100 67 59-12182 20100ND67.3 82.5
Hexachloro-1,3-butadiene ug/L 100 30 24-11671 82100ND30.0 71.4
Hexachlorobenzene ug/L 100 72 1-15281 12100ND72.4 81.4
Hexachlorocyclopentadiene ug/L 100 27 25-15066 85100ND26.7 66.3
Hexachloroethane ug/L M11002840-11366 82100ND27.6 66.2
Indeno(1,2,3-cd)pyrene ug/L 100 69 1-17174 8100ND68.8 74.4
Isophorone ug/L 100 41 21-19680 65100ND40.9 80.0
N-Nitroso-di-n-propylamine ug/L 100 36 1-23074 68100ND36.3 73.9
N-Nitrosodimethylamine ug/L 100 29 25-15057 64100ND29.3 57.0
N-Nitrosodiphenylamine ug/L 100 77 25-15086 12100ND76.6 86.3
Naphthalene ug/L 100 35 21-13373 71100ND34.9 73.3
Nitrobenzene ug/L 100 36 35-18075 70100ND36.1 75.1
Pentachlorophenol ug/L 200 69 14-17674 6200ND138147
Phenanthrene ug/L 100 76 54-12084 10100ND75.7 83.5
Phenol ug/L 100 23 5-11249 72100ND22.8 48.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 24
DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1270960MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92214602001
1270961
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Pyrene ug/L 100 72 52-11582 12100ND72.3 81.8
2,4,6-Tribromophenol (S) %76 10-13784
2-Fluorobiphenyl (S)%37 15-12073
2-Fluorophenol (S)%24 10-12052
Nitrobenzene-d5 (S)%35 10-12074
Phenol-d6 (S)%19 10-12042
Terphenyl-d14 (S)%70 11-13180
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 24

DRAFT
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/29569
MADEP EPH
MADEP EPH
MADEP EPH NC Water
Associated Lab Samples:92214436001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1270914
Associated Lab Samples:92214436001
Matrix:Water
Analyzed
Aliphatic (C09-C18)ug/L ND 100 N208/26/14 17:46
Aliphatic (C19-C36)ug/L ND 100 N208/26/14 17:46
Aromatic (C11-C22)ug/L ND 100 N208/26/14 05:35
2-Bromonaphthalene (S)%86 40-140 08/26/14 05:35
2-Fluorobiphenyl (S)%72 40-140 08/26/14 05:35
Nonatriacontane (S)%57 40-140 08/26/14 17:46
o-Terphenyl (S)%73 40-140 08/26/14 05:35
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1270915LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1270916
Aliphatic (C09-C18)ug/L 148 N23004940-14065195 27 50
Aliphatic (C19-C36)ug/L 239 N24006040-14071283 17 50
Aromatic (C11-C22)ug/L 608 N28507140-14067565 7 50
2-Bromonaphthalene (S)%78 40-14069
2-Fluorobiphenyl (S)%70 40-14062
Nonatriacontane (S)%51 40-14053
o-Terphenyl (S)%75 40-14071
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 24
DRAFT
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution ofthe sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
This comment applies to all compounds with RPD greater than 30%.1g
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits inassociated samples. Results unaffected by high bias.L3
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold TNI accreditation for this parameter.N2
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 24
DRAFT
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92214436001 OEXT/29569 GCSV/18672WSW-5 MADEP EPH MADEP EPH
92214436001 GCV/8481WSW-5 MADEP VPH
92214436001 MPRP/16743 ICP/15118WSW-5 EPA 3010 EPA 6010
92214436001 OEXT/29570 MSSV/9577WSW-5 EPA 625 EPA 625
92214436001 MSV/28053WSW-5 SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 24
DRAFT
Page 23 of 24
DRAFT
Page 24 of 24
APPENDIX B

MONITORING WELL ID:MW-5 ECS PROJECT No. 06:21858
PROJECT NAME: Flowers Store Property SITE:DATE: 8/13/2014
MEASURING POINT: TOC 31.80 ft. btoc
1236 18.86 0.085 2.33 4.55 -40 3
1240 18.75 0.087 2.17 4.59 -40.4 3
1246 19.11 0.086 2.09 4.58 -42.1 2
1250 18.92 0.084 2.01 4.56 -41.8 2
1254 18.65 0.087 2.015 4.56 -41.3 2
DEPTH TO GROUNDWATER:
COMMENTS:
Comments
(1) Turbidty visual determination: (1) clear (2) slighly cloudy (3) cloudy (4) very cloudy
Sample
NOTES
TIME
(MILITARY)TEMP (*C)D.O.
(mg/L)
PH
(S.U.)
O.R.P.
(Mv)
TURBIDITY
VISUAL (1)
SP. COND.
(cS/cm)
LOW
STEEL GUARD PIPE AROUND CASING:
LOCKING CAP:
PROTECTIVE POST/ABUTMENT:
ID PLATE:
WELL INTEGRITY SATISFACTORY:
WELL YIELD:
SAMPLING PERSONNEL D. Martino
YES NO
YES
YES
YES
HIGH
NO
NO
NO
NO
MODERATE
YES
WELL DEPTH: 38 SCREEN INTERVAL: 23-38 FT. WELL DIAMETER: 2 inch
HEIGHT OF MEASURING POINT ABOVE LAND SURFACE: NA CASING MATERIAL: PVC
SAMPLING DEVICE: Bailer TUBING TYPE: NA
ECS Carolinas, LLP
9001 Glenwood Avenue
Raleigh, North Carolina 27617
MONITORING WELL SAMPLING WORKSHEET
4181 NC Highway 42 East

MONITORING WELL ID:MW-7 ECS PROJECT No. 06:21858
PROJECT NAME: Flowers Store Property SITE:DATE: 8/13/2014
MEASURING POINT: TOC 15.65 ft. btoc
1103 17.27 0.03 2.50 4.40 -43.0 1
1108 17.15 0.03 1.82 4.33 -31.4 1
1113 17.20 0.04 1.67 4.39 -25.9 1
1116 18.05 0.04 1.93 4.61 -30.1 1
1119 18.02 0.04 1.93 4.66 -31.2 1
DEPTH TO GROUNDWATER:
Sample
(1) Turbidty visual determination: (1) clear (2) slighly cloudy (3) cloudy (4) very cloudy
NOTES
Comments TIME
(MILITARY)TEMP (*C)D.O.
(mg/L)
PH
(S.U.)
O.R.P.
(Mv)
TURBIDITY
VISUAL (1)
SP. COND.
(cS/cm)
WELL YIELD:
COMMENTS:
LOWHIGH MODERATE
PROTECTIVE POST/ABUTMENT:
ID PLATE:
WELL INTEGRITY SATISFACTORY:
NO
NOYES
YES
YES
NO
SAMPLING PERSONNEL D. Martino
YES NOSTEEL GUARD PIPE AROUND CASING:
NO
WELL DEPTH: 30 SCREEN INTERVAL: 20-40 FT. WELL DIAMETER: 2 inch
HEIGHT OF MEASURING POINT ABOVE LAND SURFACE: NA CASING MATERIAL: PVC
SAMPLING DEVICE: Peristaltic Pump/YSI 556 TUBING TYPE: Poly
ECS Carolinas, LLP
9001 Glenwood Avenue
Raleigh, North Carolina 27617
MONITORING WELL SAMPLING WORKSHEET
4181 NC Highway 42 East
LOCKING CAP:YES
APPENDIX C
DRAFT
PHOTOGRAPH LOG
FLOWERS STORE PROPERTY
4181 NC HIGHWAY 42 EAST
CLAYTON, JOHNSTON COUNTY, NORTH CAROLINA
ECS PROJECT NO 06:21858
Photograph 1: View of the subject site. View is to the northwest.
Photograph 2: View of the subject site. View is to the north.
DRAFT
PHOTOGRAPH LOG
FLOWERS STORE PROPERTY
4181 NC HIGHWAY 42 EAST
CLAYTON, JOHNSTON COUNTY, NORTH CAROLINA
ECS PROJECT NO 06:21858
Photograph 3: View of monitoring well MW-7.
Photograph 4: View of monitoring well MW-3, which is filled in with dirt.