FA-916_17217_CA_LAB_20140828_Pace Labs Report for WSW 5

#=CL#
August 28, 2014
LIMS USE: FR - MATTHEW GILLIS
LIMS OBJECT ID: 92214436
92214436
Project:
Pace Project No.:
RE:
Matthew Gillis
ECS
9001 Glenwood Avenue
Raleigh, NC 27617
FLOWERS STORE N14007i-C
Dear Matthew Gillis:
Enclosed are the analytical results for sample(s) received by the laboratory on August 21, 2014. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
cc:Matthew Gillis, ECS Carolinas LLP
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 24
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Georgia Certification: Virginia/VELAP ID# 46022
Kentucky UST Certification #: 84West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Dr., Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 24
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92214436001 WSW-5
1,2-Dichloropropane 1.4 ug/L 08/22/14 17:360.50SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 24
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Sample:WSW-5 Lab ID:92214436001 Collected:08/20/14 10:15 Received:08/21/14 17:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: MADEP EPH Preparation Method: MADEP EPHMADEP EPH NC Water
Aliphatic (C09-C18)ND ug/L 08/26/14 19:24 N208/25/14 08:261001
Aliphatic (C19-C36)ND ug/L 08/26/14 19:24 N208/25/14 08:261001
Aromatic (C11-C22)ND ug/L 08/26/14 07:12 N208/25/14 08:261001
Surrogates
Nonatriacontane (S)43 %08/26/14 19:24 7194-86-708/25/14 08:2640-140 1
o-Terphenyl (S)65 %08/26/14 07:12 84-15-108/25/14 08:2640-140 1
2-Fluorobiphenyl (S)68 %08/26/14 07:12 321-60-808/25/14 08:2640-140 1
2-Bromonaphthalene (S)80 %08/26/14 07:12 580-13-208/25/14 08:2640-140 1
Analytical Method: MADEP VPHVPH NC Water
Aliphatic (C05-C08)ND ug/L 08/26/14 20:54 N250.0 1
Aliphatic (C09-C12)ND ug/L 08/26/14 20:54 N250.0 1
Aromatic (C09-C10)ND ug/L 08/26/14 20:54 N250.0 1
Surrogates
4-Bromofluorobenzene (FID) (S)88 %08/26/14 20:54 460-00-470-130 1
4-Bromofluorobenzene (PID) (S)88 %08/26/14 20:54 460-00-470-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP
Lead ND ug/L 08/25/14 18:55 7439-92-108/22/14 16:005.0 1
Analytical Method: EPA 625 Preparation Method: EPA 625625 MSSV
Acenaphthene ND ug/L 08/26/14 22:18 83-32-908/25/14 09:405.0 1
Acenaphthylene ND ug/L 08/26/14 22:18 208-96-808/25/14 09:405.0 1
Anthracene ND ug/L 08/26/14 22:18 120-12-708/25/14 09:405.0 1
Benzo(a)anthracene ND ug/L 08/26/14 22:18 56-55-308/25/14 09:405.0 1
Benzo(a)pyrene ND ug/L 08/26/14 22:18 50-32-808/25/14 09:405.0 1
Benzo(b)fluoranthene ND ug/L 08/26/14 22:18 205-99-208/25/14 09:405.0 1
Benzo(g,h,i)perylene ND ug/L 08/26/14 22:18 191-24-208/25/14 09:405.0 1
Benzo(k)fluoranthene ND ug/L 08/26/14 22:18 207-08-908/25/14 09:405.0 1
4-Bromophenylphenyl ether ND ug/L 08/26/14 22:18 101-55-308/25/14 09:405.0 1
Butylbenzylphthalate ND ug/L 08/26/14 22:18 85-68-708/25/14 09:405.0 1
4-Chloro-3-methylphenol ND ug/L 08/26/14 22:18 59-50-708/25/14 09:405.0 1
bis(2-Chloroethoxy)methane ND ug/L 08/26/14 22:18 111-91-108/25/14 09:4010.0 1
bis(2-Chloroethyl) ether ND ug/L 08/26/14 22:18 111-44-408/25/14 09:405.0 1
bis(2-Chloroisopropyl) ether ND ug/L 08/26/14 22:18 108-60-108/25/14 09:405.0 1
2-Chloronaphthalene ND ug/L 08/26/14 22:18 91-58-708/25/14 09:405.0 1
2-Chlorophenol ND ug/L 08/26/14 22:18 95-57-808/25/14 09:405.0 1
4-Chlorophenylphenyl ether ND ug/L 08/26/14 22:18 7005-72-308/25/14 09:405.0 1
Chrysene ND ug/L 08/26/14 22:18 218-01-908/25/14 09:405.0 1
Dibenz(a,h)anthracene ND ug/L 08/26/14 22:18 53-70-308/25/14 09:405.0 1
3,3'-Dichlorobenzidine ND ug/L 08/26/14 22:18 91-94-108/25/14 09:4025.0 1
2,4-Dichlorophenol ND ug/L 08/26/14 22:18 120-83-208/25/14 09:405.0 1
Diethylphthalate ND ug/L 08/26/14 22:18 84-66-208/25/14 09:405.0 1
2,4-Dimethylphenol ND ug/L 08/26/14 22:18 105-67-908/25/14 09:4010.0 1
Dimethylphthalate ND ug/L 08/26/14 22:18 131-11-308/25/14 09:405.0 1
Di-n-butylphthalate ND ug/L 08/26/14 22:18 84-74-208/25/14 09:405.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 24
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Sample:WSW-5 Lab ID:92214436001 Collected:08/20/14 10:15 Received:08/21/14 17:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 625 Preparation Method: EPA 625625 MSSV
4,6-Dinitro-2-methylphenol ND ug/L 08/26/14 22:18 534-52-108/25/14 09:4020.0 1
2,4-Dinitrophenol ND ug/L 08/26/14 22:18 51-28-508/25/14 09:4050.0 1
2,4-Dinitrotoluene ND ug/L 08/26/14 22:18 121-14-208/25/14 09:405.0 1
2,6-Dinitrotoluene ND ug/L 08/26/14 22:18 606-20-208/25/14 09:405.0 1
Di-n-octylphthalate ND ug/L 08/26/14 22:18 117-84-008/25/14 09:405.0 1
bis(2-Ethylhexyl)phthalate ND ug/L 08/26/14 22:18 117-81-708/25/14 09:405.0 1
Fluoranthene ND ug/L 08/26/14 22:18 206-44-008/25/14 09:405.0 1
Fluorene ND ug/L 08/26/14 22:18 86-73-708/25/14 09:405.0 1
Hexachloro-1,3-butadiene ND ug/L 08/26/14 22:18 87-68-308/25/14 09:405.0 1
Hexachlorobenzene ND ug/L 08/26/14 22:18 118-74-108/25/14 09:405.0 1
Hexachlorocyclopentadiene ND ug/L 08/26/14 22:18 77-47-408/25/14 09:4010.0 1
Hexachloroethane ND ug/L 08/26/14 22:18 67-72-108/25/14 09:405.0 1
Indeno(1,2,3-cd)pyrene ND ug/L 08/26/14 22:18 193-39-508/25/14 09:405.0 1
Isophorone ND ug/L 08/26/14 22:18 78-59-108/25/14 09:4010.0 1
Naphthalene ND ug/L 08/26/14 22:18 91-20-308/25/14 09:405.0 1
Nitrobenzene ND ug/L 08/26/14 22:18 98-95-308/25/14 09:405.0 1
2-Nitrophenol ND ug/L 08/26/14 22:18 88-75-508/25/14 09:405.0 1
4-Nitrophenol ND ug/L 08/26/14 22:18 100-02-708/25/14 09:4050.0 1
N-Nitrosodimethylamine ND ug/L 08/26/14 22:18 62-75-908/25/14 09:405.0 1
N-Nitroso-di-n-propylamine ND ug/L 08/26/14 22:18 621-64-708/25/14 09:405.0 1
N-Nitrosodiphenylamine ND ug/L 08/26/14 22:18 86-30-608/25/14 09:4010.0 1
Pentachlorophenol ND ug/L 08/26/14 22:18 87-86-508/25/14 09:4010.0 1
Phenanthrene ND ug/L 08/26/14 22:18 85-01-808/25/14 09:405.0 1
Phenol ND ug/L 08/26/14 22:18 108-95-208/25/14 09:405.0 1
Pyrene ND ug/L 08/26/14 22:18 129-00-008/25/14 09:405.0 1
1,2,4-Trichlorobenzene ND ug/L 08/26/14 22:18 120-82-108/25/14 09:405.0 1
2,4,6-Trichlorophenol ND ug/L 08/26/14 22:18 88-06-208/25/14 09:4010.0 1
Surrogates
Nitrobenzene-d5 (S)77 %08/26/14 22:18 4165-60-008/25/14 09:4010-120 1
2-Fluorobiphenyl (S)79 %08/26/14 22:18 321-60-808/25/14 09:4015-120 1
Terphenyl-d14 (S)89 %08/26/14 22:18 1718-51-008/25/14 09:4011-131 1
Phenol-d6 (S)27 %08/26/14 22:18 13127-88-308/25/14 09:4010-120 1
2-Fluorophenol (S)41 %08/26/14 22:18 367-12-408/25/14 09:4010-120 1
2,4,6-Tribromophenol (S)85 %08/26/14 22:18 118-79-608/25/14 09:4010-137 1
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 08/22/14 17:36 71-43-20.50 1
Bromobenzene ND ug/L 08/22/14 17:36 108-86-10.50 1
Bromochloromethane ND ug/L 08/22/14 17:36 74-97-50.50 1
Bromodichloromethane ND ug/L 08/22/14 17:36 75-27-4 L30.50 1
Bromoform ND ug/L 08/22/14 17:36 75-25-20.50 1
Bromomethane ND ug/L 08/22/14 17:36 74-83-95.0 1
n-Butylbenzene ND ug/L 08/22/14 17:36 104-51-80.50 1
sec-Butylbenzene ND ug/L 08/22/14 17:36 135-98-80.50 1
tert-Butylbenzene ND ug/L 08/22/14 17:36 98-06-60.50 1
Carbon tetrachloride ND ug/L 08/22/14 17:36 56-23-5 M10.50 1
Chlorobenzene ND ug/L 08/22/14 17:36 108-90-70.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 24
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Sample:WSW-5 Lab ID:92214436001 Collected:08/20/14 10:15 Received:08/21/14 17:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B6200B MSV
Chloroethane ND ug/L 08/22/14 17:36 75-00-31.0 1
Chloroform ND ug/L 08/22/14 17:36 67-66-3 M10.50 1
Chloromethane ND ug/L 08/22/14 17:36 74-87-31.0 1
2-Chlorotoluene ND ug/L 08/22/14 17:36 95-49-80.50 1
4-Chlorotoluene ND ug/L 08/22/14 17:36 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 08/22/14 17:36 96-12-81.0 1
Dibromochloromethane ND ug/L 08/22/14 17:36 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 08/22/14 17:36 106-93-40.50 1
Dibromomethane ND ug/L 08/22/14 17:36 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 08/22/14 17:36 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 08/22/14 17:36 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 08/22/14 17:36 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 08/22/14 17:36 75-71-8 M10.50 1
1,1-Dichloroethane ND ug/L 08/22/14 17:36 75-34-30.50 1
1,2-Dichloroethane ND ug/L 08/22/14 17:36 107-06-20.50 1
1,1-Dichloroethene ND ug/L 08/22/14 17:36 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 08/22/14 17:36 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 08/22/14 17:36 156-60-50.50 1
1,2-Dichloropropane 1.4 ug/L 08/22/14 17:36 78-87-50.50 1
1,3-Dichloropropane ND ug/L 08/22/14 17:36 142-28-90.50 1
2,2-Dichloropropane ND ug/L 08/22/14 17:36 594-20-70.50 1
1,1-Dichloropropene ND ug/L 08/22/14 17:36 563-58-6 M10.50 1
cis-1,3-Dichloropropene ND ug/L 08/22/14 17:36 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 08/22/14 17:36 10061-02-60.50 1
Diisopropyl ether ND ug/L 08/22/14 17:36 108-20-30.50 1
Ethylbenzene ND ug/L 08/22/14 17:36 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 08/22/14 17:36 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 08/22/14 17:36 98-82-80.50 1
Methylene Chloride ND ug/L 08/22/14 17:36 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 08/22/14 17:36 1634-04-40.50 1
Naphthalene ND ug/L 08/22/14 17:36 91-20-32.0 1
n-Propylbenzene ND ug/L 08/22/14 17:36 103-65-10.50 1
Styrene ND ug/L 08/22/14 17:36 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 08/22/14 17:36 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 08/22/14 17:36 79-34-50.50 1
Tetrachloroethene ND ug/L 08/22/14 17:36 127-18-40.50 1
Toluene ND ug/L 08/22/14 17:36 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 08/22/14 17:36 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 08/22/14 17:36 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 08/22/14 17:36 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 08/22/14 17:36 79-00-50.50 1
Trichloroethene ND ug/L 08/22/14 17:36 79-01-60.50 1
Trichlorofluoromethane ND ug/L 08/22/14 17:36 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 08/22/14 17:36 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 08/22/14 17:36 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 08/22/14 17:36 108-67-80.50 1
Vinyl chloride ND ug/L 08/22/14 17:36 75-01-41.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 24
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Sample:WSW-5 Lab ID:92214436001 Collected:08/20/14 10:15 Received:08/21/14 17:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B6200B MSV
m&p-Xylene ND ug/L 08/22/14 17:36 179601-23-11.0 1
o-Xylene ND ug/L 08/22/14 17:36 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)109 %08/22/14 17:36 17060-07-070-130 1
4-Bromofluorobenzene (S)102 %08/22/14 17:36 460-00-470-130 1
Toluene-d8 (S)99 %08/22/14 17:36 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 24
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/8481
MADEP VPH
MADEP VPH
VPH NC Water
Associated Lab Samples:92214436001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1272279
Associated Lab Samples:92214436001
Matrix:Water
Analyzed
Aliphatic (C05-C08)ug/L ND 50.0 N208/26/14 17:50
Aliphatic (C09-C12)ug/L ND 50.0 N208/26/14 17:50
Aromatic (C09-C10)ug/L ND 50.0 N208/26/14 17:50
4-Bromofluorobenzene (FID) (S)%34 70-130 08/26/14 17:50
4-Bromofluorobenzene (PID) (S)%34 70-130 08/26/14 17:50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1272280LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1272281
Aliphatic (C05-C08)ug/L 293 N23009870-130107321 9 25
Aliphatic (C09-C12)ug/L 305 N230010230-130112335 9 25
Aromatic (C09-C10)ug/L 92.6 N21009370-1309696.4 4 25
4-Bromofluorobenzene (FID) (S)%100 70-130101
4-Bromofluorobenzene (PID) (S)%100 70-130101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 24
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/16743
EPA 3010
EPA 6010
6010 MET
Associated Lab Samples:92214436001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1270370
Associated Lab Samples:92214436001
Matrix:Water
Analyzed
Lead ug/L ND 5.0 08/25/14 18:06
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1270371LABORATORY CONTROL SAMPLE:
LCSSpike
Lead ug/L 496500 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1270372MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92214260002
1270373
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Lead ug/L 500 96 75-12595 1500ND485480
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 24
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/28053
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92214436001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1270558
Associated Lab Samples:92214436001
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 08/22/14 15:40
1,1,1-Trichloroethane ug/L ND 0.50 08/22/14 15:40
1,1,2,2-Tetrachloroethane ug/L ND 0.50 08/22/14 15:40
1,1,2-Trichloroethane ug/L ND 0.50 08/22/14 15:40
1,1-Dichloroethane ug/L ND 0.50 08/22/14 15:40
1,1-Dichloroethene ug/L ND 0.50 08/22/14 15:40
1,1-Dichloropropene ug/L ND 0.50 08/22/14 15:40
1,2,3-Trichlorobenzene ug/L ND 2.0 08/22/14 15:40
1,2,3-Trichloropropane ug/L ND 0.50 08/22/14 15:40
1,2,4-Trichlorobenzene ug/L ND 2.0 08/22/14 15:40
1,2,4-Trimethylbenzene ug/L ND 0.50 08/22/14 15:40
1,2-Dibromo-3-chloropropane ug/L ND 1.0 08/22/14 15:40
1,2-Dibromoethane (EDB)ug/L ND 0.50 08/22/14 15:40
1,2-Dichlorobenzene ug/L ND 0.50 08/22/14 15:40
1,2-Dichloroethane ug/L ND 0.50 08/22/14 15:40
1,2-Dichloropropane ug/L ND 0.50 08/22/14 15:40
1,3,5-Trimethylbenzene ug/L ND 0.50 08/22/14 15:40
1,3-Dichlorobenzene ug/L ND 0.50 08/22/14 15:40
1,3-Dichloropropane ug/L ND 0.50 08/22/14 15:40
1,4-Dichlorobenzene ug/L ND 0.50 08/22/14 15:40
2,2-Dichloropropane ug/L ND 0.50 08/22/14 15:40
2-Chlorotoluene ug/L ND 0.50 08/22/14 15:40
4-Chlorotoluene ug/L ND 0.50 08/22/14 15:40
Benzene ug/L ND 0.50 08/22/14 15:40
Bromobenzene ug/L ND 0.50 08/22/14 15:40
Bromochloromethane ug/L ND 0.50 08/22/14 15:40
Bromodichloromethane ug/L ND 0.50 08/22/14 15:40
Bromoform ug/L ND 0.50 08/22/14 15:40
Bromomethane ug/L ND 5.0 08/22/14 15:40
Carbon tetrachloride ug/L ND 0.50 08/22/14 15:40
Chlorobenzene ug/L ND 0.50 08/22/14 15:40
Chloroethane ug/L ND 1.0 08/22/14 15:40
Chloroform ug/L ND 0.50 08/22/14 15:40
Chloromethane ug/L ND 1.0 08/22/14 15:40
cis-1,2-Dichloroethene ug/L ND 0.50 08/22/14 15:40
cis-1,3-Dichloropropene ug/L ND 0.50 08/22/14 15:40
Dibromochloromethane ug/L ND 0.50 08/22/14 15:40
Dibromomethane ug/L ND 0.50 08/22/14 15:40
Dichlorodifluoromethane ug/L ND 0.50 08/22/14 15:40
Diisopropyl ether ug/L ND 0.50 08/22/14 15:40
Ethylbenzene ug/L ND 0.50 08/22/14 15:40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
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[phone]
Page 10 of 24
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1270558
Associated Lab Samples:92214436001
Matrix:Water
Analyzed
Hexachloro-1,3-butadiene ug/L ND 2.0 08/22/14 15:40
Isopropylbenzene (Cumene)ug/L ND 0.50 08/22/14 15:40
m&p-Xylene ug/L ND 1.0 08/22/14 15:40
Methyl-tert-butyl ether ug/L ND 0.50 08/22/14 15:40
Methylene Chloride ug/L ND 2.0 08/22/14 15:40
n-Butylbenzene ug/L ND 0.50 08/22/14 15:40
n-Propylbenzene ug/L ND 0.50 08/22/14 15:40
Naphthalene ug/L ND 2.0 08/22/14 15:40
o-Xylene ug/L ND 0.50 08/22/14 15:40
sec-Butylbenzene ug/L ND 0.50 08/22/14 15:40
Styrene ug/L ND 0.50 08/22/14 15:40
tert-Butylbenzene ug/L ND 0.50 08/22/14 15:40
Tetrachloroethene ug/L ND 0.50 08/22/14 15:40
Toluene ug/L ND 0.50 08/22/14 15:40
trans-1,2-Dichloroethene ug/L ND 0.50 08/22/14 15:40
trans-1,3-Dichloropropene ug/L ND 0.50 08/22/14 15:40
Trichloroethene ug/L ND 0.50 08/22/14 15:40
Trichlorofluoromethane ug/L ND 1.0 08/22/14 15:40
Vinyl chloride ug/L ND 1.0 08/22/14 15:40
1,2-Dichloroethane-d4 (S)%105 70-130 08/22/14 15:40
4-Bromofluorobenzene (S)%101 70-130 08/22/14 15:40
Toluene-d8 (S)%100 70-130 08/22/14 15:40
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1270559LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 61.550 123 60-140
1,1,1-Trichloroethane ug/L 61.150 122 60-140
1,1,2,2-Tetrachloroethane ug/L 56.350 113 60-140
1,1,2-Trichloroethane ug/L 59.350 119 60-140
1,1-Dichloroethane ug/L 54.150 108 60-140
1,1-Dichloroethene ug/L 60.950 122 60-140
1,1-Dichloropropene ug/L 62.750 125 60-140
1,2,3-Trichlorobenzene ug/L 58.850 118 60-140
1,2,3-Trichloropropane ug/L 59.250 118 60-140
1,2,4-Trichlorobenzene ug/L 58.850 118 60-140
1,2,4-Trimethylbenzene ug/L 56.250 112 60-140
1,2-Dibromo-3-chloropropane ug/L 60.250 120 60-140
1,2-Dibromoethane (EDB)ug/L 59.550 119 60-140
1,2-Dichlorobenzene ug/L 56.450 113 60-140
1,2-Dichloroethane ug/L 61.450 123 60-140
1,2-Dichloropropane ug/L 55.850 112 60-140
1,3,5-Trimethylbenzene ug/L 53.750 107 60-140
1,3-Dichlorobenzene ug/L 56.650 113 60-140
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
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Huntersville, NC 28078
[phone]
Page 11 of 24
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1270559LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichloropropane ug/L 57.650 115 60-140
1,4-Dichlorobenzene ug/L 56.650 113 60-140
2,2-Dichloropropane ug/L 65.550 131 60-140
2-Chlorotoluene ug/L 55.050 110 60-140
4-Chlorotoluene ug/L 56.150 112 60-140
Benzene ug/L 53.750 107 60-140
Bromobenzene ug/L 57.450 115 60-140
Bromochloromethane ug/L 61.650 123 60-140
Bromodichloromethane ug/L 71.1 L05014260-140
Bromoform ug/L 59.150 118 60-140
Bromomethane ug/L 48.750 97 60-140
Carbon tetrachloride ug/L 66.850 134 60-140
Chlorobenzene ug/L 55.750 111 60-140
Chloroethane ug/L 51.550 103 60-140
Chloroform ug/L 66.950 134 60-140
Chloromethane ug/L 48.650 97 60-140
cis-1,2-Dichloroethene ug/L 63.950 128 60-140
cis-1,3-Dichloropropene ug/L 56.050 112 60-140
Dibromochloromethane ug/L 61.950 124 60-140
Dibromomethane ug/L 62.150 124 60-140
Dichlorodifluoromethane ug/L 59.950 120 60-140
Diisopropyl ether ug/L 57.050 114 60-140
Ethylbenzene ug/L 51.950 104 60-140
Hexachloro-1,3-butadiene ug/L 56.650 113 60-140
Isopropylbenzene (Cumene)ug/L 58.750 117 60-140
m&p-Xylene ug/L 104100 104 60-140
Methyl-tert-butyl ether ug/L 57.750 115 60-140
Methylene Chloride ug/L 56.450 113 60-140
n-Butylbenzene ug/L 57.350 115 60-140
n-Propylbenzene ug/L 53.950 108 60-140
Naphthalene ug/L 59.750 119 60-140
o-Xylene ug/L 52.750 105 60-140
sec-Butylbenzene ug/L 55.050 110 60-140
Styrene ug/L 61.750 123 60-140
tert-Butylbenzene ug/L 57.150 114 60-140
Tetrachloroethene ug/L 54.750 109 60-140
Toluene ug/L 56.150 112 60-140
trans-1,2-Dichloroethene ug/L 60.250 120 60-140
trans-1,3-Dichloropropene ug/L 56.550 113 60-140
Trichloroethene ug/L 58.050 116 60-140
Trichlorofluoromethane ug/L 58.450 117 60-140
Vinyl chloride ug/L 53.650 107 60-140
1,2-Dichloroethane-d4 (S)%105 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%99 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 24
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1270560MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92214436001
1270561
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 120 60-140119 020ND23.9 23.8
1,1,1-Trichloroethane ug/L 20 131 60-140134 220ND26.2 26.9
1,1,2,2-Tetrachloroethane ug/L 20 112 60-140111 020ND22.3 22.2
1,1,2-Trichloroethane ug/L 20 119 60-140117 220ND23.9 23.4
1,1-Dichloroethane ug/L 20 114 60-140115 120ND22.8 23.0
1,1-Dichloroethene ug/L 20 138 60-140139 120ND27.7 27.9
1,1-Dichloropropene ug/L M12014160-140142 120ND28.1 28.3
1,2,3-Trichlorobenzene ug/L 20 111 60-140111 020ND22.2 22.3
1,2,3-Trichloropropane ug/L 20 117 60-140114 320ND23.5 22.9
1,2,4-Trichlorobenzene ug/L 20 110 60-140111 120ND22.0 22.2
1,2,4-Trimethylbenzene ug/L 20 112 60-140113 120ND22.4 22.5
1,2-Dibromo-3-chloropropane ug/L 20 113 60-140110 220ND22.5 22.1
1,2-Dibromoethane (EDB)ug/L 20 116 60-140116 020ND23.1 23.2
1,2-Dichlorobenzene ug/L 20 112 60-140114 120ND22.5 22.8
1,2-Dichloroethane ug/L 20 123 60-140126 320ND24.5 25.3
1,2-Dichloropropane ug/L 20 117 60-140116 1201.4 24.7 24.6
1,3,5-Trimethylbenzene ug/L 20 112 60-140113 120ND22.3 22.6
1,3-Dichlorobenzene ug/L 20 113 60-140114 120ND22.7 22.8
1,3-Dichloropropane ug/L 20 112 60-140114 120ND22.5 22.7
1,4-Dichlorobenzene ug/L 20 114 60-140115 020ND22.9 22.9
2,2-Dichloropropane ug/L 20 122 60-140123 120ND24.3 24.6
2-Chlorotoluene ug/L 20 115 60-140115 020ND23.0 22.9
4-Chlorotoluene ug/L 20 113 60-140114 020ND22.7 22.8
Benzene ug/L 20 115 60-140115 020ND23.0 23.0
Bromobenzene ug/L 20 116 60-140118 220ND23.2 23.6
Bromochloromethane ug/L 20 130 60-140130 020ND26.0 26.1
Bromodichloromethane ug/L 20 138 60-140139 120ND27.6 27.8
Bromoform ug/L 20 112 60-140110 220ND22.3 21.9
Bromomethane ug/L 20 116 60-140120 320ND23.3 23.9
Carbon tetrachloride ug/L M12014460-140144 020ND28.7 28.8
Chlorobenzene ug/L 20 114 60-140115 120ND22.8 23.0
Chloroethane ug/L 20 120 60-140119 020ND23.9 23.9
Chloroform ug/L M12013760-140142 320ND27.5 28.4
Chloromethane ug/L 20 115 60-140116 120ND23.1 23.3
cis-1,2-Dichloroethene ug/L 20 132 60-140136 320ND26.3 27.3
cis-1,3-Dichloropropene ug/L 20 105 60-140106 120ND21.0 21.2
Dibromochloromethane ug/L 20 119 60-140119 020ND23.8 23.7
Dibromomethane ug/L 20 123 60-140126 220ND24.7 25.2
Dichlorodifluoromethane ug/L M12015160-140155 220ND30.3 30.9
Diisopropyl ether ug/L 20 114 60-140118 420ND22.9 23.7
Ethylbenzene ug/L 20 110 60-140110 020ND22.0 22.1
Hexachloro-1,3-butadiene ug/L 20 114 60-140117 220ND22.8 23.4
Isopropylbenzene (Cumene)ug/L 20 124 60-140126 120ND24.9 25.2
m&p-Xylene ug/L 40 110 60-140111 140ND44.0 44.5
Methyl-tert-butyl ether ug/L 20 115 60-140118 320ND23.0 23.6
Methylene Chloride ug/L 20 106 60-140111 420ND21.2 22.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 24
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1270560MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92214436001
1270561
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Butylbenzene ug/L 20 119 60-140119 020ND23.7 23.7
n-Propylbenzene ug/L 20 114 60-140116 220ND22.8 23.3
Naphthalene ug/L 20 113 60-140111 120ND22.5 22.2
o-Xylene ug/L 20 108 60-140110 220ND21.6 22.0
sec-Butylbenzene ug/L 20 119 60-140119 120ND23.7 23.9
Styrene ug/L 20 122 60-140124 120ND24.5 24.7
tert-Butylbenzene ug/L 20 120 60-140121 020ND24.1 24.1
Tetrachloroethene ug/L 20 120 60-140120 020ND24.0 23.9
Toluene ug/L 20 118 60-140117 120ND23.6 23.5
trans-1,2-Dichloroethene ug/L 20 132 60-140131 120ND26.4 26.2
trans-1,3-Dichloropropene ug/L 20 106 60-140107 120ND21.2 21.4
Trichloroethene ug/L 20 123 60-140124 020ND24.7 24.8
Trichlorofluoromethane ug/L 20 136 60-140136 020ND27.3 27.1
Vinyl chloride ug/L 20 126 60-140127 120ND25.2 25.4
1,2-Dichloroethane-d4 (S)%104 70-130103
4-Bromofluorobenzene (S)%102 70-130101
Toluene-d8 (S)%102 70-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 24
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/29570
EPA 625
EPA 625
625 MSS
Associated Lab Samples:92214436001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1270957
Associated Lab Samples:92214436001
Matrix:Water
Analyzed
1,2,4-Trichlorobenzene ug/L ND 5.0 08/26/14 18:57
2,4,6-Trichlorophenol ug/L ND 10.0 08/26/14 18:57
2,4-Dichlorophenol ug/L ND 5.0 08/26/14 18:57
2,4-Dimethylphenol ug/L ND 10.0 08/26/14 18:57
2,4-Dinitrophenol ug/L ND 50.0 08/26/14 18:57
2,4-Dinitrotoluene ug/L ND 5.0 08/26/14 18:57
2,6-Dinitrotoluene ug/L ND 5.0 08/26/14 18:57
2-Chloronaphthalene ug/L ND 5.0 08/26/14 18:57
2-Chlorophenol ug/L ND 5.0 08/26/14 18:57
2-Nitrophenol ug/L ND 5.0 08/26/14 18:57
3,3'-Dichlorobenzidine ug/L ND 25.0 08/26/14 18:57
4,6-Dinitro-2-methylphenol ug/L ND 20.0 08/26/14 18:57
4-Bromophenylphenyl ether ug/L ND 5.0 08/26/14 18:57
4-Chloro-3-methylphenol ug/L ND 5.0 08/26/14 18:57
4-Chlorophenylphenyl ether ug/L ND 5.0 08/26/14 18:57
4-Nitrophenol ug/L ND 50.0 08/26/14 18:57
Acenaphthene ug/L ND 5.0 08/26/14 18:57
Acenaphthylene ug/L ND 5.0 08/26/14 18:57
Anthracene ug/L ND 5.0 08/26/14 18:57
Benzo(a)anthracene ug/L ND 5.0 08/26/14 18:57
Benzo(a)pyrene ug/L ND 5.0 08/26/14 18:57
Benzo(b)fluoranthene ug/L ND 5.0 08/26/14 18:57
Benzo(g,h,i)perylene ug/L ND 5.0 08/26/14 18:57
Benzo(k)fluoranthene ug/L ND 5.0 08/26/14 18:57
bis(2-Chloroethoxy)methane ug/L ND 10.0 08/26/14 18:57
bis(2-Chloroethyl) ether ug/L ND 5.0 08/26/14 18:57
bis(2-Chloroisopropyl) ether ug/L ND 5.0 08/26/14 18:57
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 08/26/14 18:57
Butylbenzylphthalate ug/L ND 5.0 08/26/14 18:57
Chrysene ug/L ND 5.0 08/26/14 18:57
Di-n-butylphthalate ug/L ND 5.0 08/26/14 18:57
Di-n-octylphthalate ug/L ND 5.0 08/26/14 18:57
Dibenz(a,h)anthracene ug/L ND 5.0 08/26/14 18:57
Diethylphthalate ug/L ND 5.0 08/26/14 18:57
Dimethylphthalate ug/L ND 5.0 08/26/14 18:57
Fluoranthene ug/L ND 5.0 08/26/14 18:57
Fluorene ug/L ND 5.0 08/26/14 18:57
Hexachloro-1,3-butadiene ug/L ND 5.0 08/26/14 18:57
Hexachlorobenzene ug/L ND 5.0 08/26/14 18:57
Hexachlorocyclopentadiene ug/L ND 10.0 08/26/14 18:57
Hexachloroethane ug/L ND 5.0 08/26/14 18:57
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 24
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1270957
Associated Lab Samples:92214436001
Matrix:Water
Analyzed
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 08/26/14 18:57
Isophorone ug/L ND 10.0 08/26/14 18:57
N-Nitroso-di-n-propylamine ug/L ND 5.0 08/26/14 18:57
N-Nitrosodimethylamine ug/L ND 5.0 08/26/14 18:57
N-Nitrosodiphenylamine ug/L ND 10.0 08/26/14 18:57
Naphthalene ug/L ND 5.0 08/26/14 18:57
Nitrobenzene ug/L ND 5.0 08/26/14 18:57
Pentachlorophenol ug/L ND 10.0 08/26/14 18:57
Phenanthrene ug/L ND 5.0 08/26/14 18:57
Phenol ug/L ND 5.0 08/26/14 18:57
Pyrene ug/L ND 5.0 08/26/14 18:57
2,4,6-Tribromophenol (S)%59 10-137 08/26/14 18:57
2-Fluorobiphenyl (S)%48 15-120 08/26/14 18:57
2-Fluorophenol (S)%26 10-120 08/26/14 18:57
Nitrobenzene-d5 (S)%46 10-120 08/26/14 18:57
Phenol-d6 (S)%18 10-120 08/26/14 18:57
Terphenyl-d14 (S)%82 11-131 08/26/14 18:57
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1270958LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 36.450 73 44-142
2,4,6-Trichlorophenol ug/L 40.250 80 37-144
2,4-Dichlorophenol ug/L 43.050 86 1-191
2,4-Dimethylphenol ug/L 44.650 89 32-119
2,4-Dinitrophenol ug/L 218250 87 1-181
2,4-Dinitrotoluene ug/L 46.750 93 39-139
2,6-Dinitrotoluene ug/L 46.750 93 50-158
2-Chloronaphthalene ug/L 40.750 81 60-118
2-Chlorophenol ug/L 35.150 70 23-134
2-Nitrophenol ug/L 43.650 87 29-182
3,3'-Dichlorobenzidine ug/L 91.0100 91 1-262
4,6-Dinitro-2-methylphenol ug/L 97.0100 97 1-181
4-Bromophenylphenyl ether ug/L 44.050 88 53-127
4-Chloro-3-methylphenol ug/L 92.2100 92 22-147
4-Chlorophenylphenyl ether ug/L 44.150 88 25-158
4-Nitrophenol ug/L 97.3250 39 1-132
Acenaphthene ug/L 42.250 84 47-145
Acenaphthylene ug/L 41.650 83 33-145
Anthracene ug/L 44.750 89 1-166
Benzo(a)anthracene ug/L 44.550 89 33-143
Benzo(a)pyrene ug/L 41.950 84 17-163
Benzo(b)fluoranthene ug/L 39.750 79 24-159
Benzo(g,h,i)perylene ug/L 44.050 88 1-219
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 24
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1270958LABORATORY CONTROL SAMPLE:
LCSSpike
Benzo(k)fluoranthene ug/L 39.250 78 11-162
bis(2-Chloroethoxy)methane ug/L 42.750 85 33-184
bis(2-Chloroethyl) ether ug/L 37.250 74 12-158
bis(2-Chloroisopropyl) ether ug/L 36.450 73 36-166
bis(2-Ethylhexyl)phthalate ug/L 49.250 98 8-158
Butylbenzylphthalate ug/L 48.950 98 1-152
Chrysene ug/L 44.850 90 17-168
Di-n-butylphthalate ug/L 48.750 97 1-118
Di-n-octylphthalate ug/L 50.250 100 4-146
Dibenz(a,h)anthracene ug/L 44.450 89 1-227
Diethylphthalate ug/L 48.350 97 1-114
Dimethylphthalate ug/L 46.750 93 1-112
Fluoranthene ug/L 46.150 92 26-137
Fluorene ug/L 46.150 92 59-121
Hexachloro-1,3-butadiene ug/L 34.750 69 24-116
Hexachlorobenzene ug/L 42.550 85 1-152
Hexachlorocyclopentadiene ug/L 33.450 67 25-150
Hexachloroethane ug/L 33.850 68 40-113
Indeno(1,2,3-cd)pyrene ug/L 36.750 73 1-171
Isophorone ug/L 45.850 92 21-196
N-Nitroso-di-n-propylamine ug/L 43.450 87 1-230
N-Nitrosodimethylamine ug/L 23.550 47 25-150
N-Nitrosodiphenylamine ug/L 45.950 92 25-150
Naphthalene ug/L 38.450 77 21-133
Nitrobenzene ug/L 39.550 79 35-180
Pentachlorophenol ug/L 72.9100 73 14-176
Phenanthrene ug/L 44.150 88 54-120
Phenol ug/L 18.650 37 5-112
Pyrene ug/L 40.650 81 52-115
2,4,6-Tribromophenol (S)%87 10-137
2-Fluorobiphenyl (S)%82 15-120
2-Fluorophenol (S)%43 10-120
Nitrobenzene-d5 (S)%78 10-120
Phenol-d6 (S)%30 10-120
Terphenyl-d14 (S)%84 11-131
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1270960MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92214602001
1270961
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/L 1g,M1,R11003344-14273 75100ND33.4 73.1
2,4,6-Trichlorophenol ug/L 100 45 37-14472 46100ND45.4 72.5
2,4-Dichlorophenol ug/L 100 36 1-19178 73100ND36.0 77.6
2,4-Dimethylphenol ug/L 100 38 32-11983 75100ND37.6 82.6
2,4-Dinitrophenol ug/L 500 71 1-18182 14500ND357411
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 24
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1270960MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92214602001
1270961
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
2,4-Dinitrotoluene ug/L 100 83 39-13988 6100ND83.1 88.4
2,6-Dinitrotoluene ug/L 100 77 50-15887 12100ND77.2 86.8
2-Chloronaphthalene ug/L M11003960-11875 63100ND38.8 74.8
2-Chlorophenol ug/L 100 34 23-13470 70100ND33.8 69.8
2-Nitrophenol ug/L 100 38 29-18279 69100ND38.3 79.0
3,3'-Dichlorobenzidine ug/L 200 84 1-26292 9200ND168185
4,6-Dinitro-2-methylphenol ug/L 200 88 1-18193 5200ND177186
4-Bromophenylphenyl ether ug/L 100 70 53-12784 17100ND70.4 83.6
4-Chloro-3-methylphenol ug/L 200 53 22-14786 47200ND106172
4-Chlorophenylphenyl ether ug/L 100 62 25-15879 24100ND62.1 79.4
4-Nitrophenol ug/L 500 52 1-13256 6500ND261278
Acenaphthene ug/L 100 50 47-14576 42100ND49.6 76.1
Acenaphthylene ug/L 100 48 33-14576 45100ND48.4 76.2
Anthracene ug/L 100 78 1-16687 10100ND78.4 86.6
Benzo(a)anthracene ug/L 100 80 33-14388 10100ND80.0 88.3
Benzo(a)pyrene ug/L 100 79 17-16385 7100ND79.4 84.9
Benzo(b)fluoranthene ug/L 100 78 24-15984 7100ND78.2 83.8
Benzo(g,h,i)perylene ug/L 100 83 1-21990 8100ND83.0 89.6
Benzo(k)fluoranthene ug/L 100 72 11-16281 11100ND72.2 80.9
bis(2-Chloroethoxy)methane ug/L 100 35 33-18478 78100ND34.5 78.4
bis(2-Chloroethyl) ether ug/L 100 34 12-15874 74100ND33.9 73.7
bis(2-Chloroisopropyl) ether ug/L M11003236-16670 74100ND32.1 69.6
bis(2-Ethylhexyl)phthalate ug/L 100 87 8-15899 13100ND86.9 99.4
Butylbenzylphthalate ug/L 100 87 1-152100 13100ND87.4 99.5
Chrysene ug/L 100 81 17-16889 9100ND81.4 89.4
Di-n-butylphthalate ug/L 100 90 1-11895 6100ND89.9 95.5
Di-n-octylphthalate ug/L 100 90 4-146101 12100ND90.4 101
Dibenz(a,h)anthracene ug/L 100 85 1-22791 6100ND85.3 91.0
Diethylphthalate ug/L 100 83 1-11488 6100ND86.3 91.5
Dimethylphthalate ug/L 100 78 1-11288 12100ND77.6 87.7
Fluoranthene ug/L 100 87 26-13791 5100ND87.1 91.5
Fluorene ug/L 100 67 59-12182 20100ND67.3 82.5
Hexachloro-1,3-butadiene ug/L 100 30 24-11671 82100ND30.0 71.4
Hexachlorobenzene ug/L 100 72 1-15281 12100ND72.4 81.4
Hexachlorocyclopentadiene ug/L 100 27 25-15066 85100ND26.7 66.3
Hexachloroethane ug/L M11002840-11366 82100ND27.6 66.2
Indeno(1,2,3-cd)pyrene ug/L 100 69 1-17174 8100ND68.8 74.4
Isophorone ug/L 100 41 21-19680 65100ND40.9 80.0
N-Nitroso-di-n-propylamine ug/L 100 36 1-23074 68100ND36.3 73.9
N-Nitrosodimethylamine ug/L 100 29 25-15057 64100ND29.3 57.0
N-Nitrosodiphenylamine ug/L 100 77 25-15086 12100ND76.6 86.3
Naphthalene ug/L 100 35 21-13373 71100ND34.9 73.3
Nitrobenzene ug/L 100 36 35-18075 70100ND36.1 75.1
Pentachlorophenol ug/L 200 69 14-17674 6200ND138147
Phenanthrene ug/L 100 76 54-12084 10100ND75.7 83.5
Phenol ug/L 100 23 5-11249 72100ND22.8 48.7
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 24
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1270960MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92214602001
1270961
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Pyrene ug/L 100 72 52-11582 12100ND72.3 81.8
2,4,6-Tribromophenol (S)%76 10-13784
2-Fluorobiphenyl (S)%37 15-12073
2-Fluorophenol (S)%24 10-12052
Nitrobenzene-d5 (S)%35 10-12074
Phenol-d6 (S)%19 10-12042
Terphenyl-d14 (S)%70 11-13180
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 24
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/29569
MADEP EPH
MADEP EPH
MADEP EPH NC Water
Associated Lab Samples:92214436001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1270914
Associated Lab Samples:92214436001
Matrix:Water
Analyzed
Aliphatic (C09-C18)ug/L ND 100 N208/26/14 17:46
Aliphatic (C19-C36)ug/L ND 100 N208/26/14 17:46
Aromatic (C11-C22)ug/L ND 100 N208/26/14 05:35
2-Bromonaphthalene (S)%86 40-140 08/26/14 05:35
2-Fluorobiphenyl (S)%72 40-140 08/26/14 05:35
Nonatriacontane (S)%57 40-140 08/26/14 17:46
o-Terphenyl (S)%73 40-140 08/26/14 05:35
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1270915LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1270916
Aliphatic (C09-C18)ug/L 148 N23004940-14065195 27 50
Aliphatic (C19-C36)ug/L 239 N24006040-14071283 17 50
Aromatic (C11-C22)ug/L 608 N28507140-14067565 7 50
2-Bromonaphthalene (S)%78 40-14069
2-Fluorobiphenyl (S)%70 40-14062
Nonatriacontane (S)%51 40-14053
o-Terphenyl (S)%75 40-14071
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 24
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
This comment applies to all compounds with RPD greater than 30%.1g
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.L3
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold TNI accreditation for this parameter.N2
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 24
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92214436
FLOWERS STORE N14007i-C
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92214436001 OEXT/29569 GCSV/18672WSW-5 MADEP EPH MADEP EPH
92214436001 GCV/8481WSW-5 MADEP VPH
92214436001 MPRP/16743 ICP/15118WSW-5 EPA 3010 EPA 6010
92214436001 OEXT/29570 MSSV/9577WSW-5 EPA 625 EPA 625
92214436001 MSV/28053WSW-5 SM 6200B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/28/2014 02:11 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 24
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