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HomeMy WebLinkAbout8606_Surry_SubtitleD_Lined_MSWLF_Dec2019GW_FID1405461_20200507VENR USE ONLY: ''l ( L1Paper Report UElectronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: • Prepare one form for each individually monitored unit. • Please type or print legibly. • Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). • Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). • Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. nittal Information - consultant, facility owner): Municipal Engineering services Co., PA Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Jonathan Pfohl Phone: (919)772-5393 E-maii: jpfohl@mesco.com Facility name: Facility Address: I Surry County Lined MSWLF 237 Landfill Road Mt. Airy, NC 27030 Environmental Status: (Check all that apply) , Initial/Background Monitoring QX Detection Monitoring of data submitted; (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells Leachate monitoring data Surface water monitoring data I I NC Landfill Rule: Permit # (.0500 or .1600) .tl Assessment Monitoring tvlethane gas monitoring data Corrective action data (specify) Other(specify) U Actual sampling dates (e.g., October 20-24, 2006) December 10-13, 2019 January 15, 2020 March 6, 2020 Corrective Action Notification attached? Nn. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete nocation of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Steven R. Gandy, Ph.D., P.E. Senior Project Manager (919) 772-5393 P.O. BOX 97, Garner, NC 27529 Facility Representative Address Nc rt rirm ucense rvumoer pr appucaoie effective May �, 2uoy) Revised 6l2009 Telephone Number Affix NC Licensed/ Professional Geologist Seal %�WW�0149Fie rwrara *a 4:0 O Syp2 — = o ®®®'FN R"G Pip ``�� Semi -Annual Water Quality Monitoring Report December 2019 Prepared for Surry County Lined Landfill Mt. Airy, North Carolina Permit No. 86-06 Prepared by Municipal Engineering Services Company, P.A. P.O. BOX 97 Garner, North Carolina MESCO Project Number: G19031.0 or - Steven R. Gandy, Ph.D, P.E. Senior Project Manager sgandy(kmesco.com Jonathan Pfohl Environmental Specialist jpfohl&mesco.com AQ`��MUNICIPAL ENGINEERING SERVICES COMPANY, P.A. 66 SNIPWASH DRIVE, GARNER, NC 27529 - PHONE! 919.772.5393 P.O. Box 349, BOONE, NC 213607 - PHONE; SZB-262-1767 �� LICENSE NUMBER: C-13261 Introduction On behalf of Surry County, Municipal Engineering Services Company, P.A. (MESCO) is pleased to present this Semi -Annual Water Quality Monitoring Report for an event performed at the Surry County Lined Municipal Solid Waste Landfill (MSWLF) in the Fall of 2019. NCDEQ Solid Waste Rules 15A NCAC 1313.1632 requires that Surry County provide this report to the SWS on a semi-annual basis. This report documents the quality of the ground and surface waters during a monitoring event performed on December 10-13, 2019, January 15, 2020 and March 6, 2020. During this event one or two constituents were detected above allowable regulatory compliance levels in samples collected from MW-6R and MW-9S. An unprecedented concentration of benzene was detected in sample MW-10 but was below it's compliance Standard 12 weeks later. Surface water samples did not contain constituents in levels above applicable 2B Standards. The leachate samples continue to contain a few contaminants but were in low concentrations relative to Standards and published values. Background The Surry County Subtitle D lined MSWLF, permit #86-06, is located at 237 Landfill Road, Mount Airy, Surry County, North Carolina. The site location topographic map is depicted in the attached Sheet 1. The lined MSWLF is comprised of contiguous Phases 1 & 2 which are treated as a single unit in this report. Lined Phase 4, a horizontal expansion to the west, is under construction. Water quality at this facility has been monitored at least semi-annually since 1998 with all historical data reviewed in support of this report. This event was performed in accordance with the NC SWS rules/regulations as promulgated in 15A NCAC 13B and as a condition of the permit to operate. Assessment monitoring was initiated site -wide in response to detections of volatile organic compounds (VOCs) above allowable Standards in samples collected from MW-2, MW-6R and MW-9S in the spring of 2016. Assessment monitoring of MW-2, MW-6R and MW-9S and landfill gas monitoring of MGP-5 and MGP-12 continued during this event as approved by NCDEQ. An Alternative Source Demonstration Addendum (ASD-Add) which established Site Maximum Allowable Contaminate (SMAC) regulatory compliance levels for three metals (cadmium, cobalt, vanadium) was approved by the NCDEQ on April 20, 2020 (FID.1395468). As specified within 15A NCAC 13B.16320), the SWS Environmental Monitoring Report Form and SWS memorandums this report contains sampling procedures, field and laboratory results, groundwater and surface water characterization. Well construction summary table, field observations table, field parameter data table, sampling and analysis summary table, detections compared to Standards tables, a groundwater flow directions/rates table, potentiometric map, quality assurance/quality control data, and laboratory analytical data results are enclosed herein. Sampling Procedure MESCO personnel performed this sampling event using portable monitoring methodology in general accordance with the site -specific Water Quality Monitoring Plan dated July 12, 2018 (DIN:1234484) which was approved by the NC SWS on August 8, 2018 (DIN:1235187). Water samples were collected from 14 downgradient groundwater monitoring wells (MW-2, MW-3R, MW-4S, MW-4D, MW-5, MW-6R, MW-8, MW-9S, MW-9D, MW-10, MW-115, MW-11D, MW-12 and MW-13), one background well (MW-1), four downstream surface water locations (SW-4 , SWN-2, SW-C and SW-D), four upstream surface water points (SWN-1, SW-1, SW-2 and SW-3) and a raw leachate sample (LAGOON). Quality control (QC) measures included analysis of equipment blanks (EB) and field blanks (FB). MW-10 was re -sampled and tested for VOCs on March 6, 2020 since the original sample contained elevated benzene concentrations. Sampling locations are shown on the potentiometric map (Sheet 2). A summary detailing the construction of the water monitoring wells is presented on Table 1. The function and integrity of all monitoring locations were visually evaluated as documented on Table 2. The depth to water in each well was electronically gaged prior to purging to quantify the static water level elevation. Submersible pumping methodology or bailing was utilized to purge the wells to a minimum of three times the volume of standing water in the well or until dry. Surface water samples were collected from Stoney Creek discharge feature at previously designated locations. During well purging and surface water sample collection the required field parameters were recorded. The samples were then placed into laboratory -prepared, pre -preserved containers via a new disposable polyethylene bailer. Samples were collected, kept on ice, and transported to a NC -certified laboratory under proper C-O-C protocols within the specified hold times for each analysis. Field Parameter Data Stabilized field parameters were recorded during purging which included pH, specific conductance, temperature, methane gas and turbidity. A summary of the field parameter data is presented in Table 3 and the field sampling data sheet is enclosed in Appendix A. Laboratory Results Pace Analytical Services, Inc. (PACE) performed the laboratory analysis of the water and leachate samples. Pace reported that their procedures conformed to the most current, applicable TNI/NELAC standards and the their Quality Assurance Manual, where applicable, unless otherwise noted in the body of the laboratory report. Groundwater samples MW-2, MW-6R and MW-9S were tested for constituents listed in 40 CFR 258 Appendix II and 1,4-dioxane. The other groundwater and surface water samples were tested for constituents listed in 40 CFR 258 Appendix I and 1,4-dioxane. Untreated leachate was tested for the specific parameters required by the SWS which includes Appendix I constituents, phosphorous, BOD, COD, sulfide and nitrate. A sampling and analysis table summarizing the locations, constituents and methods is presented as Table 4. Laboratory results and C-O-Cs are presented in Appendix B. Water samples were analyzed to the laboratory -established Method Detection Limits (MDL) and any value between the MDL and laboratory -established Reporting Limit (RL) is qualified by the laboratory as an estimated concentration hence qualified with a "J". Estimated concentrations are considered non -quantifiable and discretion should be made prior to making decisions based solely on an approximate value. Table 5 summarizes constituents detected in groundwater, leachate and quality control samples compared to regulatory groundwater compliance standards which include Interim Maximum Allowable Concentrations (IMAC), Site Maximum Allowable Concentrations (SMAC) and North Carolina Groundwater Standards (2L). Although not applicable for regulatory compliance purposes the detections are also compared to the Maximum Contaminant Level (MCL) commonly referenced as the Federal "Drinking Water Standard". Table 6 lists the constituents detected in surface water samples compared to the current version of the Division of Water Quality Surface Water Quality Tables and the MCL. Quality Control Samples Zinc and 1,4-Dichlorobenzene were detected in both of the QC samples (EB, FB). Groundwater Samples Detected Above Standards Metals Sample MW-9S contained quantifiable concentrations of total recoverable cobalt (114 uq/L) which is above the SMAC (I I ug/L). 2 Volatile Organic Compounds VOCs, vinyl chloride 2.4 ug/L (2L=0.3 ug/L) and benzene 1.7 ug/L / (2L=1.0 ug/L), were detected in sample MW- 6R above their respective NC 2L Standard. Benzene was also detected at 1.5 ug/L in sample MW-10 but a verification sample collected 12 weeks later was at 0.67 ug/L which is below the 2L Standard (1.0 ug/L) Bis(2- Ethylhexyl) pththalate, a semi -volatile organic compound listed in 40 CFR 258 Appendix II, was detected in samples MW-2 (16.1 ug/L), MW-6R (14.2 ug/L) and MW-9S (12.3 ug/L) which is above the 2L Standard (3 ug/L). Surface Water Samples Detected Above Standards Contaminants were not detected above established NC 2B Surface Water Standards in any of the surface water samples. Leachate Samples Raw leachate samples lacked quantifiable concentrations of VOCs. Contaminant concentrations in leachate remain low relative to Standards applicable to ground and surface waters and values published from similar MSWLF's which is consistent with previous observations. Groundwater and Surface Water Characterization A potentiometric map of the uppermost aquifer constructed from groundwater elevation data recorded during this monitoring event is on Sheet 2. Groundwater flow rates and directions were calculated and are included in the hydrologic properties table (Table 7). Groundwater flow directions remain generally in a southerly direction towards the Ararat River with groundwater velocities calculated by modified Darcy's equation varied considerably due to the anisotropic geologic conditions. Streams located within the facility boundaries were observed to be of moderate volume and flow with moderate turbidity. MW-611 Area Investigations During this event MESCO investigated the area around MW-6R in an attempt to identify the source of VOC detections. MW-6R is located in a ditch that previously conveyed stormwater originating from the lined landfill. During the construction of Phased 2 in 2009, stormwater originating near the landfill was rerouted so that it no longer flows adjacent to MW-6R. A low concentration of methane (0.6%/vol.) was detected in shallow migration monitoring probe MGP-5, located less than 75 feet from MW-6R on February 4, 2020 (Figure 1). Active LFG extraction has been initiated at Lined Phase 1 which includes vacuum applied at the closest leachate collection system cleanout. Vinyl chloride was detected in sample MW-6R during this and the previous 12 events above the 2L Standard and benzene levels were found above the 2L Standard for the second time. There were no detections in groundwater sample MW-8 or surface water samples (SWN-2, SW-D) collected hydraulically downgradient of MW- 6R. Findings Groundwater near MW-6R continues to be impacted with levels remaining within their historically identified range. MW-6R is located approximately 100 feet downgradient of the Phase 2 liner and within the compliance boundary. The portion of the aquifer impacted is believed to be small as evidenced by lack of detections in MW-8 located along the downgradient flow path. The active LFG extraction system has been expanded proximal to MW-6R and is expected to operate indefinitely which may mitigate potential groundwater impacts. Interpretation of results of surface water samples collected along Stoney Creek and the Ararat River, including those instituted directly downgradient of MW-6R, continue to indicate the local discharge features remain unimpaired. Detections of bis(2-Ethlhexyl) pthalate are suspected to be false positives attributed to field and/or lab induced artifact contaminates as evidenced by lack of previous detections at the site, detected in every well it was targeted at comparable levels and results qualified by the laboratory as a "common laboratory contaminant". Closing Semi-annual water quality quarterly LFG monitoring will continue with the next event scheduled for the Spring of 2020. During the next event Appendix II parameters bis(2-Ethylhexyl) pthalate and sulfate should be targeted during the next event to verify the validity of the recent detections and to comply with 15A NCAC 13B .1634(d)(2). Construction of Phase 4 is expected to be completed in 2020. Two of the four required baseline events for future Phase 4 have been performed with the third and fourth planned to be conducted in the Spring of 2020. 4 Sheets Topographic Map with Site Location Surry County Landfill, Mt. Airy fl 237 Landfill Road Mount Airy, NC 28621 Lat: 36-26-30.065 Long:-80-34-15.314 Northing:983356.18 Easting:1537885.48 0 Surry Co Property Line O Closed Unlined C&D Landfill O Closed Unlined Sanitary Landfill O Active Lined MSW Landfill SHEET 1 NOW OR FORMERLY OWNED BY JOHNNY COX 1050 \OWNED BY /) COUNTY J OW4-22 MW-1 G WE=1064.02 w 1�C SIN II (1000' FURTHER UPSTREAM) II II I I II \ SW-3 \GWE•f011.88 ' `1 i of / INACTIVE LINED - PHASE 1 LINED / O 1211/98 \ PHASE4 1030 / STONEY CREEK `UNDER CONSTRUCTION 101D 1000 8 SW-4 ACTIVE LFG ,9iiMW-4S /- 9" 0WE=914.3� MW2 /�/MW-4D'cwE--esxso /j� gso q��GwE--avz.ar GNE--9J/�SW-C GWE--915.S1�j 1� 1050 MW-6 �GWE�3&OB MW4 `\ yl Chloride- 2.4 u GW�-910.33 zene- 1.7 uWL SWN-2,�950 SOUTHERN RAILROAD ` SW-D \1 OWNED BY BURRY COUNTY Imo\ I� U CLOSED C&D OVER CLOSED MSW STOPPED RECEIVING C&D BEFORE JUNE 1, 2008 Q • P,i N N I. STOPPED RECEIVING MSW BY JAN. 1, 199910 _ t` 0� W w N m m N W m z Z � R'Rpp Z w D. 0 In FR�LINF I rn a u Oi d O U J N N r C w (� W O O N CO III Z CO X J U N 7 L] Z W Z SW-1 � N K ISW f Q N a z° C7 oLd J O LINE IL m PROPERTY U[] ' o(" / _ > Z O/ m 3 m / W IL = O U] In a 0 NOW OR FORMERLY OWNED BY SHAWNA SUMMERS J =a Qz >- Z Lu Q /P/� cl! LEGEND ---------------- ESTIMATED WASTE LIMITS UNLINED LANDFILL Lu — — — — — — — — — — WASTE LIMITS OF LINED LANDFILL J FACILITY OUTERMOST PROPERTY BOUNDARY 1� �m► O l �.,. TOPOGRAPHIC CONTOURS -EXISTING ^ 1 Z)— v, J — — — — RELATIVE GROUNDWATER COMPLIANCE BOUNDARY RAILROAD rV Z V O ® OBSERVATION WELL © MONITORING WELL Z) Q LANDFILL GAS MONITORING WELL — — — — — ROADS — STREAM/CREEK - SURFACE WATER SAMPLING LOCATION 960 EQUIPOTENTIAL UPPERMOST GROUNDWATER CONTOURS (DEC 10-11, 2019) d a o GWE = 941.66 GROUNDWATER POTENTIOMETRIC ELEVATION N 'MW- POTENTIOMETRIC ELEVATION NOT USED FOR CONTOURING U Cl � � W O p W Z � Q FW- O ti a � � o W a � a Z � GRAPHIC SCALE LL IN FEET ) —LE. SEESCALEBAR DATE. 4110120 DRWN. BY J. PFOHL CHKD BY: J.PFOHL SHEET 2 19025.0 G `R19025.0 oRAnnnc No SHEET2 sDEEruo. 1OF1 Figure Figure 1 Landfill Gas Migration Monitoring Data February 4, 2020 NC Division of Waste Management — Solid Waste Section Landfill Gas Monitoring Data Form Notice:This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Facility Name: Surry County Landfill Ph 1-4 Date of Sampling: 02/04/20 Name & Position of Sample Collector: Type & Serial Number of Gas Meter: Date & Time of Field Calibration: Type of Field Calibration Gas (15/15 or 35/50): Pump Rate of Gas Meter: 240 cc/min Ambient Air Temperature: 61 F Evan Lambert (Env. Specialist 1) Envision (1901205B) 12/26/19 08:24 AM Permit Number: 86-06 NC Landfill Rule (.0500 or .1600): 0.1600 Factory Calibration Date of Gas Meter: 01/15/19 15/15 Expiration Date of Field Calibration Gas Canister: 12/20/22 Barometric Pressure: 29.01" Hg General Weather Conditions: Cloudy Instructions: Under "Location or LFG Well" identify the monitoring wells or describe the location for other tests (e.g., inside buildings). A drawing showing the location of test must be attached. Report methane readings in both %LEL and % methane by volume. A reading in percent methane by volume can be converted to %LEL as follows: % methane by volume = %LEL/20 Location or LFG Well ID Sample Tube Purge Time Reading Taken Time Pumped in Initial Ch4 Stabilized Ch4 Stabilized Ch4 02 CO2 H2S Notes (Sec) (Sec.) (% LEL) (% LEL) (%/Vol) (%/Vol) (%/Vol) (ppm) MGP-5 30 11:14 AM 60 12 12 0.6 17.6 6.5 0 MGP-12 1 30 11:22 AM 60 1 0 1 0 0.0 12.9 1 4.3 0 These readings are supplemental for groundwater corrective action monitoring not for migration compliance purposes. NOTES/COMMENTS: Surry County Lined Landfill Page 1 of 1 Tables Table 1 Groundwater Monitoring Well Construction Table December 10-13, 2019 Monitoring Well Date Installed Well Diameter Total Well Depth Top of Screen Depth Screen Length Geology of Screened Interval Top of casing Elevation Ground Elevation Groundwater Elevation Depth to Water Latitude Longitude (inches) (ft bgs) (ft bgs) (ft) (ft amsl) (ft amsl) (ft amsl) (ft btoc) MW-1 8/14/98 2 68.5 53.5 15 Rock 1127.02 1124.23 1064.02 63.00 36.434494 -80.577989 MW-2 8/16/98 2 23.5 8.5 15 Rock 936.68 933.91 923.30 13.38 36.430833 -80.571161 MW-3R 12/2/98 2 20 5 15 Rock 930.00 928.15 925.51 4.49 36.430714 -80.571575 MW-4S 8/11/98 2 20 5 15 Saprolite 943.23 940.31 934.37 8.86 36.430853 -80.572400 MW-4D 8/11/98 2 45 35 10 Rock 942.80 940.31 932.92 9.88 36.430853 -80.572400 MW-5 8/18/98 2 47.5 32.5 15 Rock 977.93 971.57 934.60 43.33 36.430356 -80.572961 MW-6R 3/22/99 2 79 64 15 Fractured Rock 1004.75 1001.81 938.06 66.69 36.429958 -80.573508 MW-8 9/1/09 2 70.75 55.75 15 Fractured Rock 971.03 968.35 910.33 60.70 36.429283 -80.573453 MW-9S 6/16/06 2 42.28 27.28 15 Fractured Rock 952.83 949.75 919.53 33.30 36.429314 -80.574464 MW-9D 6/16/06 2 65.54 55.54 10 Competent Rock 952.47 949.49 917.76 34.71 36.429314 -80.574464 MW-10 6/16/06 2 47.13 27.13 20 Fractured Rock 970.24 967.35 942.39 27.85 36.429519 -80.575486 MW-11S 9/3/09 2 46.05 31.05 15 Competent Rock 969.09 965.95 938.52 30.57 36.430197 -80.577131 MW-11D 9/3/09 2 65.31 55.31 10 Competent Rock 965.38 962.38 933.17 32.21 36.430197 -80.577131 MW-12 9/4/09 2 65 50 15 Competent Rock 996.66 993.71 971.74 24.92 36.429831 -80.576750 MW-13 9/3/09 2 1 36.31 1 21.31 1 15 Fractured Rock 1 983.13 979.83 1 954.40 1 28.73 36.430625 -80.578531 NOTE: bgs = below ground surface amsl= above mean sea level btoc = below top of casing (PVC well casing) Slurry County Lined Landfill Page 1 of 1 Table 2 Field Observations of Monitoring Locations December 10-13, 2019 Sample Location Viable Monitoring Location Lack of Any Evidence of Tampering Locked on Arrival & Departure Hinge/Hasp Operational Tagged or Labeled Concrete Surface Pad Appears Effective Comments MW-1 Yes Yes Yes Yes Yes Yes Background Well MW-2 Yes Yes Yes Yes Yes Yes MW-3R Yes Yes Yes Yes Yes Yes MW-4S Yes Yes Yes Yes Yes Yes MW-4D Yes Yes Yes Yes Yes Yes MW-5 Yes Yes Yes Yes Yes Yes MW-6R Yes Yes Yes Yes Yes Yes County improved surface seal in September 2013 MW-8 Yes Yes Yes Yes Yes Yes Path to well recently cleared by County MW-9S Yes Yes Yes Yes Yes Yes MW-9D Yes Yes Yes Yes Yes Yes MW-10 Yes Yes Yes Yes Yes Yes MW-11S Yes Yes Yes Yes Yes Yes MW-11 D Yes Yes Yes Yes Yes Yes Very slow recharge MW-12 Yes Yes Yes Yes Yes Yes MW-13 Yes Yes Yes Yes Yes ? Bumped by JR Lynch (Contractor). Well needs repaired SW-1 Yes High gage height & flow SW-2 Yes Moderate gage height & flow SW-3 Yes Moderate gage height & flow SWN-1 Yes High gage height & flow SWN-2 Yes Moderate gage height & flow SW-C Yes High gage height & flow SW-D Yes Moderate gage height & flow LAGOON Yes Yes Yes Sample from invert which is typical Any unusual field conditions, observations, or events: Phase 2 has an earthen berm built Win liner limits which may reduce any potential for overland flow from Phase 2. Paths leading to wells and around entire facility have been maintained by County. All are 4X4 accessible. Co performed well maintenance by pouring new concrete pads around several wells in the Fall of 2017. Slurry County Lined Landfill Page 1 of 1 Table 3 Hydrogeologic Properties at Monitoring Locations December 10-13, 2019 Parameter Depth to Water Water Elevation TOC Elevation Temp. pH Specific Conductance ORP DO Hardness Methane Gas in Headspace Turbidity of Metal Sample Units ft (btoc) ft (amsl) ft (amsl) C SU umhos/cm my mg/L mg/L (%/Vol) (NTU) MW-1 63.00 1064.02 1127.02 14.0 5.71 94 NR NR NR NR 9.33 MW-2 13.38 923.30 936.68 14.6 5.55 121 NR NR NR NR 0.61 MW-3R 4.49 925.51 930.00 14.2 6.12 284 NR NR NR NR NR MW-4S 8.86 934.37 943.23 14.9 5.40 146 NR NR NR NR 0.69 MW-4D 9.88 932.92 942.80 14.3 6.14 182 NR NR NR NR 1.88 MW-5 43.33 934.60 977.93 14.0 5.59 149 NR NR NR NR 8.83 MW-6R 66.69 938.06 1004.75 14.2 5.54 263 NR NR NR NR 0.87 MW-8 60.70 910.33 971.03 13.7 5.99 96.3 NR NR NR NR 1.17 MW-9S 33.30 919.53 952.83 14.5 6.02 277 NR NR NR NR 0.90 MW-9D 34.71 917.76 952.47 12.2 6.91 452 NR NR NR NR 36.5 MW-10 27.85 942.39 970.24 15.1 5.71 206 NR NR NR NR 9.94 MW-11S 30.57 938.52 969.09 16.2 6.15 177 NR 4.9 NR NR 1.39 MW-11D 32.21 933.17 965.38 13.4 7.41 1857 NR 6.5 NR NR 1.79 MW-12 24.92 971.74 996.66 14.1 7.30 305 NR NR NR NR 1.33 MW-13 28.73 954.40 983.13 14.6 5.78 119 NR 6.4 NR NR 1.35 MLW-A NR NR 1095.51 NR NR NR NR NR NR NR NR Minimum 4.49 910.33 930.00 12.2 5.40 94 NR NR NR NR 0.61 Average 32.17 942.71 982.42 14.3 6.09 315 NR NR NR NR 5.47 Maximum 66.69 1064.02 1127.02 16.2 7.41 1857 NR NR NR NR 36.5 SW-1 - - - 4.4 7.48 95 -156 NR 20 - 4.48 SW-2 4.9 7.53 110 -180 NR 40 - 2.13 SW-3 5.3 7.37 98 -98 NR 40 - 40.5 SW-4 5.7 7.54 57 -151 NR 80 - 22.8 SWN-2 5.3 8.50 98 -176 NR 60 - 3.06 SW-C 5.4 7.49 88 -151 NR 80 - 22.3 SW-D - 4.7 1 8.44 1 103 1 -166 1 NR 60 - 1 3.55 Minimum 4.4 7.4 57 -180 NR 20 NR 2.13 Average - 5.1 7.8 93 -154 NR 54 NR 14.1 Maximum 5.7 8.5 110 -98 NR 80 NR 40.5 NR = No reading attempted btoc = Below top of casing amsl = Above mean sea level Slurry County Lined Landfill Page 1 of 1 Table 4 Sampling and Analysis Summary December 10-13, 2019 January 15, 2020 (MW-13, SWN-1) March 6, 2020 (MW-10 Verification) App. I Other App. II Field Parameter Leachate a � 0 Q O = C U m a O c a Q > o7 U a 0 0 co C C O a 0 (6 _ ro = Q �, t U O n Q m a� �, 0X � N >, CU N c X Q N N = rn N >' 0 '� ui O m m 2 O C) U U a ,L_' s o V , c �? a� y U (a U (Ug z E O E z �_ 0 0 c`o O O O O O N N O N 7 X O (6 = 7 S O O 'r > H > H 2 fn 0- H fn F- H O 0 U 2 a U) Q 0- M U Z CD 0 0 0 O �m CO O m_ U) O CO CDO CD (0 O (0 O O Q O ti W — O Lo O O m O_ O N M N 00 CDN (0 00 N 00 O co_ ({� N 00 00 O O L L L L L O M V O (0 N N N ((� M Q Q 0- Q Q Q 0_ ap Q Q 0_ Q O O N N :� O N O Q 0) Q (M Q Q 0- W 0_ 0- W 0_ W 0_ Y 0_ 0- 0- 0- w W w W W U) o W W W (n cn W t4 M (U (6 c6 co ca N N N N N cB c6 (0 (6 (6 (6 J J J J J J J J J J LL E E LL L.L W E J J J J J J MW-1 x x x x x x x MW-2 x x x x x x x x x x x x MW-3R x x x x x x MW-4S x x x x x x x MW-4D x x x x x x x MW-5 x x x x x x x MW-6R x x x x x x x x x x x x MW-8 x x x x x x x MW-9S x x x x x x x x x x x x MW-9D x x x x x x x MW-10 V x x x x x x MW-11 S x x x x x x x x MW-11D x x x x x x x x MW-12 x x x x x x x MW-13 x x x x x x x x SWN-1 x x x x x x x x SWN-2 x x x x x x x x x SW-1 x x x x x x x x x SW-2 x x x x x x x x x SW-3 x x x x x x x x x SW-4 x x x x x x x x x SW-C x x x x x x x x x SW-D x x x x x x x x x LAGOON x x x x x x x x x EB x x x FB I x x x Appendix I & II = Lists from current 40 CFR 258 V = Verification sample collected on March 6, 2020 Surry County Lined Landfill Page 1 of 1 Table 5 Groundwater, Leachate and QC Sample Detections December 11-14, 2019, January 15, 2020, March 6, 2020 21-STANDARD MW-1 MW-10 MW-10 MW-12 MW-2 MW-311 MW-413 MW-4S MW-5 MW-611 MW-8 MW-910 MW-9S MW-11D MW-11S MW-13 LAGOON EB FB Parameter Name MDL RL IMAC/SMAC VALUE* MCL (12/11/19) BG (12/11/19) S (3/6120) S (12/11/19) S (12/11/19) S (12/11/19) S (12/11/19) S (12/11/19) S (12/11/19) S (12/11/19) S (12/11/19) S (12/11/19) S (12/11/19) S (12/12/19) S (12/12/19) S (1/15/20) S (12/11/19) Leachate (12/14/19) QC (12/14/19) QC Metals Tar eted 40CFR 258 Appendix I Barium, total 1 5 700 2000 15.7 42.2 -- 14.1 36.9 47.6 52.5 41.3 55.9 76.8 61.4 35.7 115 18.2 J 10.2 J 174 3.5 J 3.2 J Beryllium, total 0.2 1 4 4 -- 0.2 J Cadmium, total 0.4 1 8* 5 0.71 J -- 1.6 0.53 J 0.97 J 4.6 (N) 0.56 J 0.62 J 1.2 1.1 Cobalt, total 1.1 5 11* NE 4 J -- 1.4 J 114 (L) 22.6 Copper, total 2.1 5 1000 1300 3.8 J -- 51 2.3 J 2.6 J 2.2 J 2.8 J Lead, total 1.6 5 15 15 -- 3.5 J 3.5 J Nickel, total 0.9 5 100 NE 6.8 2.4 J -- 2.8 J 2.6 J 2.2 J 0.93 J 3.1 J 1.3 J 11.8 1.4 J 0.94 J 4.2 J Selenium, total 4.7 10 20 50 -- 9.5 J Thallium, total 0.06 0.1 0.28 2 0.084 J -- 0.1 J 0.13 J 0.38 J Vanadium, total 1.3 5 27* NE -- 1.3 J 1.8 J 2.3 J Zinc, total 3.9 10 1000 NE 15.2 -- 5.4J 4.2J 15.7 4.2J 7.1 J 5.7J 8.5J 4.2J 12.8 8.4J Turbidity (Field Measured) Turbidity (NTU) 0.01 -- NE NE 9.33 9.94 -- 1.33 0.61 -- 1.88 0.69 8.83 0.87 1.17 36.5 0.9 1.79 1.39 1.35 27.4 -- -- VOCs (Targeted 40CFR 258 Appendix 1) 1,1-Dichloroethane 0.27 1 6 NE 2.1 1.3 1,2-Dichloroethane 0.34 1 0.4 5 0.79 J 1,4-Dichlorobenzene 0.26 1 6 75 0.64 J 1.5 1.9 Benzene 0.15 1 1 5 1.5 (L) 0.67 J 0.28 J 1.7 (L) 0.96 J 0.3 J cis-1,2-Dichloroethene 0.29 1 70 70 1.7 0.99 J 1.8 1.9 0.52 J 1.3 9.1 0.96 J 7.1 0.29 J trans-1,2-Dichloroethene 0.25 1 100 100 2.7 J 0.66 J Trichloroethene 0.22 1 3 5 0.51 J Vinyl chloride 0.24 1 0.03 2 2.4 Appendix II Exclusive (Not also listed on Appendix 1) bis(2-Ethylhexyl)phthalate 2.1 6 3 6 -- -- -- -- 16.1 (A) -- -- -- -- 14.2 (A) -- -- 12.3 (A) -- -- -- -- -- Sulfate 500 1000 250000 NE -- -- -- -- 2150 -- -- -- -- 673 J -- -- 2850 -- -- -- 12900 -- -- 1,4-Dioxane 1,4-Dioxane 56.2 150 3 NE Leachate Parameters COD 12500 25000 NE NE -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- 118000 -- -- Sulfate 500 1 250000 NE -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- 12900 J pH (lab) 0.1 0.1 NE NE -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- 7.5 Notes: Units ug/L except for turbidity, Blank cells means not detected above MDL, -- means parameter not analyzed, NE means not established Bold Above RL and Established 2L//IMAC/SMAC (Regulatory compliance Standard) Green Highlighted Above Established MCL Drinking Water Std. (No regulatory significance) BG = Background Well Sample, QC = Quality Control Sample, S = Sentinal Well Sample. MDL = Adjusted Method Detection Limit established by the laboratory via a statistical calculation. Since the MDL is below the point of calibration, results reported down to the MDL are not reliable and must be qualified as estimated values and, as such, carry a "J" qualifier designation. RL = Reporting Limit established by the laboratory. The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. 2L = NC 2L Groundater Standard 15A NCAC 02L .0202 IMAC = Interim Maximum Allowable Concentration SMAC = Site Maximum Allowable Concentration. Approved by SWS on 4/7/20 (FID:1395468) MCL = Maximum Contaminant Level for drinking water established by the USEPA. J = "J-qualified". Defined by the lab as "Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit". (L) Prelilminary source is believed to be anthropogenic with Landfill Gas Wor Ieachate as suspected transport mechanism. (A) Preliminary source is believed to be lab or field induced artifact contamination. Suspected to be a false positive and qualified as "C9" which lab defines as "Common Laboratory Contaminate". A definitive source of the detections was not determined as part of this report. Surry County Lined Landfill Page 1 of 1 Table 6 Surface Water Sample Detections December 12-13, 2019, January 15, 2020 Parameter Name MDL RL NC 2B STD' EPA NRWQCZ NC ISTV3 MCL° SWN-1 SW-C SW-D SW-4 SW-2 Upstream Downstream Downstream Downstream Downstream Metals (Targeted 40CFR 258 Appendix 1) Barium, total 1 5 NE NE 200,000 2,000 16.5 J 26 J -- 27.2 J 18.8 J Beryllium, total 0.2 1 65 NE NE 4 0.45 J B -- 0.41 J B 0.2 J B Cadmium, total 0.4 1 1.23 NE NE 5 -- 0.81 J Cobalt, total 1.1 1 NE NE 4 NE -- 1.2 J 21.3 Nickel, total 0.9 5 387.68 NE NE NE -- 1.1 J Vanadium, total 1.3 5 NE NE NE NE 2.5 J -- 2 J Zinc, total 3.9 10 96.99 NE NE NE 7.5 J -- 8.3 J Zinc, total 3.9 10 53.91 NE NE NE -- 4.8 J Hardness as CaCo3 (Field Measured) Hardness (mg/L) 20 NE NE NE NE 40 80 60 80 40 VOCs (Targeted 40CFR 258 Appendix I & 1,4-Dioxane) Cis-1,2- 0.15 1 NE NE 720 70 3 Notes: Units ug/L unless indicated otherwise, Blank cells means Not Detected, NE means Standard Not Established J = "J-qualified". Defined by the lab as "Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit". B = "B-qualified" by the lab. Analyte was detected in the associated method blank which may be interpreted as a probable false positive Red Bold Above RL and Applicable 213 Std. Above Established Federal MCL Primary Drinking Water Std. Receiving surface waters are Stoney Creek (12-72-12) and Ararat River (12-72-(4.5) ) Both Class C. 03040101 (8-Digit HUC). NC 213 STD = North Carolina 15A NCAC 02B Water Quality Standards for Surface Waters. Presumed NC SWS adopted the numerical Standard for regulatory compliance purposes. 2B Standards from All Waters (C & SC) or Class C. 26 Standard for cadmium, nickel and zinc from calculations for acute exposure based on measured hardness values. Cadmium 26 Standard calculation:WER*[{1.136672-[In hardness](0.041838))*e^{0.9151[in hardness]-3.14851] Nickel 2B Standard calculation:WER*[0.998*e^{0.8460[ln hardness]+2.255)] Zinc 26 Standard calculation:WER*[0.986*e^{0.8473[ln hardness]+0.8841] 2 EPA NRWQC = EPA Nationally Recommended Water Quality Criteria for Aquatic Life & Human Health. Nationally Recommended Water Quality Criteria for which NC does not have a Water Quality Standard for one or more uses a NC ISTV= North Carolina In -Stream Target Value. Established per language in 15A NCAC 02B .0202 & .0208. Contact DWR staff for further information. NC PV for barium fresh water All waters (Class C), for cobalt All waters Fresh & Salt (Class C & SC) ° MCL= Maximum Contaminant Level. Federal Primary "Drinking Water Standard". Shown for comparison purposes only. Not applicable for regulatory compliance purposes Surry County Lined Landfill Page 1 of 1 Table 7 Hydrogeologic Prpoperties at Monitoring Locations December 10-11, 2019 Monitoring Location Hydraulic Conductivity (cm/sec) Effective Porosity Hydraulic Gradient Flow Rate Flow Direction Depth to Groundwater Groundwater Potentiometric Elevation Screened Interval Lithology (cm/second) N (feet/feet) (feet/year) (feet btoc) (feet amsl) MW-1 2.45E-04 3 0.124 1,049 N52E 63.00 1064.02 Rock MW-2 3.20E-04 3 0.102 1,121 S09E 13.38 923.30 Rock MW-3R 3.20E-04 3 0.060 667 S19E 4.49 925.51 Rock MW-4S 1.50E-04 3 0.105 546 S24E 8.86 934.37 Sandy Silt & Fractured Rock MW-4D 1.59E-04 3 - - 9.88 932.92 Rock MW-5 3.20E-04 3 0.109 1,200 S55E 43.70 934.60 Rock MW-6R 3.20E-04 3 0.081 890 S31 E 66.69 938.06 Fractured Rock MW-8 1.08E-03 3 0.102 3,801 S03E 60.70 910.33 Fractured Rock MW-9S 7.45E-04 3 0.085 2,196 S24E 33.30 919.53 Fractured Rock MW-9D 1.07E-05 3 - - 34.71 917.76 Competent Rock MW-10 1.43E-04 3 0.115 567 S03E 27.85 942.39 Fractured Rock MW-11S 6.19E-05 3 0.111 237 S14W 30.57 938.52 Competent Rock MW-11 D na 3 - - 37.35 933.17 Competent Rock MW-12 1.91 E-06 3 na na na 24.92 971.74 Competent Rock MW-13 2.71E-03 3 0.128 11,982 S34W 28.73 954.40 Fractured Rock Minimum 5.91 E-07 3 0.060 237 4.49 910.33 Average 4.39E-04 3 0.102 1,227 32.54 942.71 Maximum 2.71 E-03 3 0.128 3,801 66.69 1064.02 NOTE: Hydraulic conductivity and effective porosity values derived from slug tests performed by MESCO. Hydrologic gradient from water levels recorded on December 10-11, 2019. Flow rate for MW-13 was considered an outlier; therefore not included in the average or maximum. Flow rate (Q) is defined by modified Darcy's equation: where K A Q ne dl K = hydraulic conductivity n e = effective porosity dh = head difference dl = horizontal distance Slurry County Lined MSWLF Page 1 of 1 Appendix A Field Sampling Parameter Data Sheet(s) Field Sampling Data Sheet .100 \7uNclpnl // � �"� linµlnecl f1\„np�m Project: Surry Co Subtitle D Lined MSWLF Samplers: Page_1_ot 1 Sampling Parameters Water Quality Parameters (Stabilized) Depth to p Water De th to p Water Volume Sample Goes Dry Total Depth . Total Comment DO GR Temp Specifi c Cond. Hardness :o M Monitorin Purge Purge Collect Collect g Point Date Time Date Time (BTOP) (BTOP) Purged Type During Measured Depth s (mg/L) ~P' pH © (us/cm (mg/L) Static Collection (Gal) Purge as expected Expected } ��r 't �r (a 70.3 , MW-1 MW-2 l d - �� 26.74 MW-3R i'" 1 � 26 r, j 7 7 22.1 43.1 t, MW-4S MW-4D 48.5 MW-5 t 81.3' J MW-6R a, ?' j = T 70.75 a 1,! �" M W-8 j 11. M W-9S ( 42.28/ MW-9D i �t 65.54, MW-10 �1 ,„ l %' ( 47.13 1 r/ 46.05 71 - 65.31 MW-12 �f,��'��r 65 I� MW-13 _ ; t v 36.31 r ` 'I , £v 1,35 93.5 MLW-A - - - - - - SW-D LAGOON - - #J t 1 �i' 35' - - - - - SS B=Stainless Steel Baler, D B=Disposable Baler, P=Low flow Pump, PD=Purged Dry VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear NR=No Reading Attempted, NS=No Sample Obtained Field Sampling Data Sheet Project: Surry Co. Lined MSWLF, Ph 4 (Pre -Operation Baseline #1) NI ciPal �LN Eng eeriag m f prr Samplers: Page-1-of-1 Pure g Date Pure g Time Collect Date Collect Time Sampling Parameters Water Quality Parameters (Stabilized) Monitorin g Point Depth to Water (BTOP) Static Depth to Water (BTOP) Collection Volume (Gal) Sample Type Goes Dry During Purge Total Depth Measured as expected(ft Total Depth Expected btoc) Comments DO (mg/L) ORP p H Temp.Purged © ope C�3( ��,jJ , y ��o�� ��Or _ 0,548.26 37iMW-25 41.78 74.00 j . 10,E�,� a76 ' C "Ij��.,� �, 1 Lf= r7MW-24 i,'tMW-26 E�- �MW-2756.07 MW-28t�`- J 83.48 1 3 (,9i r �, t SS B=Stainless Steel Baler, D B=Disposable Baler, P=Low flow Pump, PD=Purged Dry VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear NR=No Reading Attempted, NS=No Sample Obtained Field Sampling Data Sheet hiunicil>ul (J ;_$J 1�= a I•:nFl.. tt•1r1uF Project: Surry Co Closed C&D over Closed MSWLF & Active Subtitle D Lined- Mt. Airy (Shared Surface Waters) Samplers: Monitoring Point Collect Date Collect Time SamplingParameters Water Quality Parameters (Stabilized) Visual Flow Rate Lab Parameter s to be analyzed for Visual Gua a Ht. Sample Type Goes Dry During Purge Total Depth Measured as expected Comments DO (mg/L) OR P pH Temp © Specifi c Cond. (us/cm Hardness (mg/L) � :o fl CH4 Gas Vapors (pp ) SW-1 SW-2 SW-3 SWN-1 SWN-2 SW-C a / ✓, '' U , I r i t s 31,' Gl , °;. ) v ` V '�: �„ f. I I I I _ — - — - — - — - s5 T T fl d `. tlF; ' 1� /K0r Ue1°Vv el.,. —15, -176S,5� a� ✓ ° 7°z: 4 � - SS B=Stainless Steel Baler. D B=Disposable Baler, P=Low flow Pump, PD=Purged Dry VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear NR=No Reading Attempted, NS=No Sample Obtained Field Sampling Data Sheet Project: Surry Co Closed C&D and Closed MSWLF-Mt. Airy 5 F - -- G A - '.?D Parameters Sample Type Goes Dry During Purge Total Depth Measured as expected Total Depth Expected Comment s Water DO (mg/L) Quality OR P p H Parameters Temp , © (Stabilized) S ecifi p c Cond. ( us/cm TDS ( mg/L) � f- CH4 Gas Vapors Monitoring Point -%Te Date e Time Sampling Depth to Water (BTOP) Static Depth to Water (BTOP) Collection Volume Purged (Gal) h1,7 40 MW-1 ; - (0: -/ ._, IW-2 - - - - - - 68.08 - - - - - - - - - - - 100 52 57 - - - - �- - - - - - - - - 3 ^ 2 -� MW-3R i t - L) 6, -7 { 3 , L; I W-3 - - ) , �a - - IW-4 - - - - 64 - - - - IW-5 - - oLI 3 - - �� ,� . �a ✓ i r , e � 31 25 t' MW-6 4n�I 0 7 -L m� MW-7 i3.) � I U 56 46 S. e, t' IW-6 MW-9 MW-11100 �1 ?® 40 s rf ;b� l'' 7 �` 35.78 03 56.98 36.28 15.32. o, �'; _ `t k 5l{ L D 6 QI79 MW-12S A/ `) tl, MW-13 t f a r Lf MW-14 MW-15 � MW-16II 7� ;,b MW-17 - - - - 18.15 - - - - - MW-18 - - I ,r � �, t? 17.1 25.64 15.41 16.04 17.1 222 '- �13 5, S• ���.0 ,%' rip• ,vI " MW-19 _ — e M W-20 j b D 1 MW-21 � �� I ��- =�d � �'� �� � i MW-22 l #� MW-23 Ji, V i ' (� t SS B=Stainless Steel Baler, u B=uisposaulu od-1, r-�Uvv 11-v I U19" .. - VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear Appendix B Laboratory Analysis Reports Chains of Custody lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 December 31, 2019 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on December 12, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, ft*OL-' Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Steven R. Gandy, Municipal Engineering Services Co. Maddie German, Municipal Engineering Services REPORT OF LABORATORY ANALYSIS r e This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 88 laneAnalytical www,pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Pace Analytical Services National 12065 Lebanon Road, Mt. 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Page 2 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Lab ID Sample ID Matrix Date Collected Date Received 92457256001 MW-2 Water 12/11/1910:01 12/12/19 15:33 92457256002 MW-6R Water 12/11/1911:48 12/12/19 15:33 92457256003 MW-9S Water 12/11/1911:10 12/12/19 15:33 92457256004 LAGOON Water 12/11/1916:35 12/12/19 15:33 92457256005 MW-1 Water 12/11/1916:00 12/12/19 15:33 92457256006 MW-3R Water 12/11/1916:00 12/12/19 15:33 92457256007 MW-4S Water 12/11/19 09:36 12/12/19 15:33 92457256008 MW-413 Water 12/11/19 09:32 12/12/19 15:33 92457256009 MW-5 Water 12/11/1911:50 12/12/19 15:33 92457256010 MW-8 Water 12/11/1911:43 12/12/19 15:33 92457256011 MW-913 Water 12/11/1910:59 12/12/19 15:33 92457256012 MW-10 Water 12/11/1910:30 12/12/19 15:33 92457256013 MW-12 Water 12/11/1910:23 12/12/19 15:33 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Surry Co. Lined MSWLF 92457256 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92457256001 MW-2 EPA 8151 LEL 5 PAN EPA 8081 B SEM 21 PASI-C EPA 8082A SEM 8 PASI-C EPA 601OD SH1 15 PASI-A EPA 6020E JOR 1 PASI-A EPA 7470A SOO 1 PASI-A EPA 8270E PKS 111 PASI-C EPA 8260D CL 65 PASI-C EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A SM 4500-CN-E-2011 KDF1 1 PASI-A 92457256002 MW-6R EPA 8151 LEL 5 PAN EPA 8081 B SEM 21 PASI-C EPA 8082A SEM 8 PASI-C EPA 601OD SH1 15 PASI-A EPA 6020E JOR 1 PASI-A EPA 7470A SOO 1 PASI-A EPA 8270E PKS 111 PASI-C EPA 8260D CL 65 PASI-C EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A SM 4500-CN-E-2011 KDF1 1 PASI-A 92457256003 MW-9S EPA 8151 LEL 5 PAN EPA 8081 B SEM 21 PASI-C EPA 8082A SEM 8 PASI-C EPA 601OD SH1 15 PASI-A EPA 6020E JOR 1 PASI-A EPA 7470A SOO 1 PASI-A EPA 8270E PKS 111 PASI-C EPA 8260D CL 65 PASI-C EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A SM 4500-CN-E-2011 KDF1 1 PASI-A 92457256004 LAGOON EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C SM 521OB-2011 JP1 1 PASI-A EPA 9040C ECH 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 2 PASI-A EPA 365.1 Rev 2.0 1993 CJH1 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Analytes Lab ID Sample ID Method Analysts Reported Laboratory SM 5220D-2011 NAL 1 PASI-A 92457256005 MW-1 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92457256006 MW-3R EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92457256007 MW-4S EPA 601 OD KQ 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92457256008 MW-41) EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92457256009 MW-5 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92457256010 MW-8 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92457256011 MW-91) EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92457256012 MW-10 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92457256013 MW-12 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-2 Lab ID: 92457256001 Collected: 12/11/19 10:01 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Chlorinated Herb. (GC) 8151 Analytical Method: EPA8151 Preparation Method: 8151A 2,4-D ND ug/L 2.00 0.744 1 12/16/19 09:15 12/17/19 09:34 94-75-7 Dinoseb ND ug/L 2.00 0.795 1 12/16/19 09:15 12/17/19 09:34 88-85-7 2,4,5-T ND ug/L 2.00 0.843 1 12/16/19 09:15 12/17/19 09:34 93-76-5 2,4,5-TP (Silvex) ND ug/L 2.00 0.845 1 12/16/19 09:15 12/17/19 09:34 93-72-1 Surrogates 2,4-DCAA (S) 26.6 % 14.0-158 1 12/16/19 09:15 12/17/19 09:34 19719-28-9 8081 OC Pesticides RVE Analytical Method: EPA 8081 B Preparation Method: EPA 3510C Aldrin ND ug/L 0.050 0.022 1 12/18/19 10:46 12/18/19 21:55 309-00-2 alpha-BHC ND ug/L 0.050 0.019 1 12/18/19 10:46 12/18/19 21:55 319-84-6 beta-BHC ND ug/L 0.050 0.014 1 12/18/19 10:46 12/18/19 21:55 319-85-7 delta-BHC ND ug/L 0.050 0.020 1 12/18/19 10:46 12/18/19 21:55 319-86-8 gamma-BHC (Lindane) ND ug/L 0.050 0.012 1 12/18/19 10:46 12/18/19 21:55 58-89-9 Chlordane (Technical) ND ug/L 0.20 0.20 1 12/18/19 10:46 12/18/19 21:55 57-74-9 4,4'-DDD ND ug/L 0.050 0.0069 1 12/18/19 10:46 12/18/19 21:55 72-54-8 4,4'-DDE ND ug/L 0.050 0.0064 1 12/18/19 10:46 12/18/19 21:55 72-55-9 4,4'-DDT ND ug/L 0.050 0.018 1 12/18/19 10:46 12/18/19 21:55 50-29-3 Dieldrin ND ug/L 0.050 0.0073 1 12/18/19 10:46 12/18/19 21:55 60-57-1 Endosulfan I ND ug/L 0.050 0.0094 1 12/18/19 10:46 12/18/19 21:55 959-98-8 Endosulfan II ND ug/L 0.050 0.0065 1 12/18/19 10:46 12/18/19 21:55 33213-65-9 Endosulfan sulfate ND ug/L 0.050 0.0091 1 12/18/19 10:46 12/18/19 21:55 1031-07-8 Endrin ND ug/L 0.050 0.0089 1 12/18/19 10:46 12/18/19 21:55 72-20-8 Endrin aldehyde ND ug/L 0.050 0.013 1 12/18/19 10:46 12/18/19 21:55 7421-93-4 Heptachlor ND ug/L 0.050 0.016 1 12/18/19 10:46 12/18/19 21:55 76-44-8 Heptachlor epoxide ND ug/L 0.050 0.0097 1 12/18/19 10:46 12/18/19 21:55 1024-57-3 Methoxychlor ND ug/L 0.15 0.033 1 12/18/19 10:46 12/18/19 21:55 72-43-5 Toxaphene ND ug/L 0.20 0.20 1 12/18/19 10:46 12/18/19 21:55 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 53 % 10-130 1 12/18/19 10:46 12/18/19 21:55 877-09-8 Decachlorobiphenyl (S) 91 % 10-130 1 12/18/19 10:46 12/18/19 21:55 2051-24-3 8082 GCS PCB RVE Analytical Method: EPA 8082A Preparation Method: EPA 3510C PCB-1016 (Aroclor 1016) ND ug/L 0.50 0.22 1 12/17/19 11:12 12/17/19 16:24 12674-11-2 PCB-1221 (Aroclor 1221) ND ug/L 0.50 0.32 1 12/17/19 11:12 12/17/19 16:24 11104-28-2 PCB-1232 (Aroclor 1232) ND ug/L 0.50 0.21 1 12/17/19 11:12 12/17/19 16:24 11141-16-5 PCB-1242 (Aroclor 1242) ND ug/L 0.50 0.44 1 12/17/19 11:12 12/17/19 16:24 53469-21-9 PCB-1248 (Aroclor 1248) ND ug/L 0.50 0.34 1 12/17/19 11:12 12/17/19 16:24 12672-29-6 PCB-1254 (Aroclor 1254) ND ug/L 0.50 0.24 1 12/17/19 11:12 12/17/19 16:24 11097-69-1 PCB-1260 (Aroclor 1260) ND ug/L 0.50 0.30 1 12/17/19 11:12 12/17/19 16:24 11096-82-5 Surrogates Decachlorobiphenyl (S) 126 % 10-130 1 12/17/19 11:12 12/17/19 16:24 2051-24-3 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.0 1 12/18/19 01:30 12/20/19 01:56 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 12/18/19 01:30 12/20/19 01:56 7440-38-2 Barium 36.9 ug/L 5.0 1.0 1 12/18/19 01:30 12/20/19 01:56 7440-39-3 Date: 12/31/2019 01:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-2 Lab ID: 92457256001 Collected: 12/11/19 10:01 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Tin Vanadium Zinc 6020 MET ICPMS Thallium 7470 Mercury Mercury 8270E APP9 RV Acenaphthene Acenaphthylene Acetophenone 2-Acetylaminofluorene 4-Aminobiphenyl Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Benzyl alcohol 4-Bromophenylphenyl ether Butylbenzylphthalate 4-ChIoro-3-methyl phenol 4-Chloroaniline Chlorobenzilate bis(2-Chloroethoxy)methane bis(2-Chloroethyl) ether 2-Chloronaphthalene 2-Chlorophenol 4-Chlorophenylphenyl ether Chrysene Diallate Dibenz(a,h)anthracene Dibenzofuran Date: 12/31/2019 01:42 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 1.0 0.20 1 12/18/19 01:30 12/20/19 01:56 7440-41-7 0.53J ug/L 1.0 0.40 1 12/18/19 01:30 12/20/19 01:56 7440-43-9 ND ug/L 5.0 1.0 1 12/18/19 01:30 12/20/19 01:56 7440-47-3 ND ug/L 5.0 1.1 1 12/18/19 01:30 12/20/19 01:56 7440-48-4 ND ug/L 5.0 2.1 1 12/18/19 01:30 12/20/19 01:56 7440-50-8 ND ug/L 5.0 1.6 1 12/18/19 01:30 12/20/19 01:56 7439-92-1 ND ug/L 5.0 0.90 1 12/18/19 01:30 12/20/19 01:56 7440-02-0 ND ug/L 10.0 4.7 1 12/18/19 01:30 12/20/19 01:56 7782-49-2 ND ug/L 5.0 2.5 1 12/18/19 01:30 12/20/19 01:56 7440-22-4 ND ug/L 5.0 1.6 1 12/18/19 01:30 12/20/19 01:56 7440-31-5 ND ug/L 5.0 1.3 1 12/18/19 01:30 12/20/19 01:56 7440-62-2 ND ug/L 10.0 3.9 1 12/18/19 01:30 12/20/19 01:56 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/18/19 02:00 12/28/19 04:39 7440-28-0 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.10 1 12/19/1912:45 12/20/1912:29 7439-97-6 Analytical Method: EPA 8270E Preparation Method: EPA 3510C ND ug/L 10.0 1.6 1 12/18/1917:10 12/19/1914:28 83-32-9 ND ug/L 10.0 1.6 1 12/18/1917:10 12/19/1914:28 208-96-8 ND ug/L 10.0 1.8 1 12/18/1917:10 12/19/1914:28 98-86-2 ND ug/L 10.0 3.1 1 12/18/1917:10 12/19/1914:28 53-96-3 M1 ND ug/L 10.0 3.3 1 12/18/1917:10 12/19/1914:28 92-67-1 M1 ND ug/L 10.0 1.7 1 12/18/1917:10 12/19/1914:28 120-12-7 ND ug/L 10.0 1.8 1 12/18/1917:10 12/19/1914:28 56-55-3 ND ug/L 10.0 2.1 1 12/18/1917:10 12/19/1914:28 50-32-8 ND ug/L 10.0 1.9 1 12/18/1917:10 12/19/1914:28 205-99-2 ND ug/L 10.0 1.4 1 12/18/1917:10 12/19/1914:28 191-24-2 ND ug/L 10.0 1.9 1 12/18/1917:10 12/19/1914:28 207-08-9 ND ug/L 20.0 2.6 1 12/18/1917:10 12/19/1914:28 100-51-6 ND ug/L 10.0 1.6 1 12/18/1917:10 12/19/1914:28 101-55-3 ND ug/L 10.0 1.6 1 12/18/1917:10 12/19/1914:28 85-68-7 ND ug/L 10.0 2.8 1 12/18/1917:10 12/19/1914:28 59-50-7 ND ug/L 20.0 2.8 1 12/18/1917:10 12/19/1914:28 106-47-8 ND ug/L 10.0 4.6 1 12/18/1917:10 12/19/1914:28 510-15-6 L1,M0 ND ug/L 10.0 1.8 1 12/18/1917:10 12/19/1914:28 111-91-1 ND ug/L 10.0 1.8 1 12/18/1917:10 12/19/1914:28 111-44-4 ND ug/L 10.0 1.5 1 12/18/1917:10 12/19/1914:28 91-58-7 ND ug/L 10.0 1.2 1 12/18/1917:10 12/19/1914:28 95-57-8 ND ug/L 10.0 1.6 1 12/18/1917:10 12/19/1914:28 7005-72-3 ND ug/L 10.0 1.7 1 12/18/1917:10 12/19/1914:28 218-01-9 ND ug/L 10.0 5.3 1 12/18/1917:10 12/19/1914:28 2303-16-4 M1 ND ug/L 10.0 1.6 1 12/18/1917:10 12/19/1914:28 53-70-3 ND ug/L 10.0 1.5 1 12/18/1917:10 12/19/1914:28 132-64-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-2 Lab ID: 92457256001 Collected: 12/11/19 10:01 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C 3,3'-Dichlorobenzidine ND ug/L 20.0 3.0 1 12/18/19 17:10 12/19/19 14:28 91-94-1 2,4-Dichlorophenol ND ug/L 10.0 1.4 1 12/18/19 17:10 12/19/19 14:28 120-83-2 2,6-Dichlorophenol ND ug/L 10.0 6.0 1 12/18/19 17:10 12/19/19 14:28 87-65-0 M1 Diethylphthalate ND ug/L 10.0 2.4 1 12/18/19 17:10 12/19/19 14:28 84-66-2 Dimethoate ND ug/L 10.0 4.8 1 12/18/19 17:10 12/19/19 14:28 60-51-5 M1 P-Dimethylaminoazobenzene ND ug/L 5.0 1.9 1 12/18/19 17:10 12/19/19 14:28 60-11-7 M1 7,12-Dimethylbenz(a)anthracene ND ug/L 10.0 4.0 1 12/18/19 17:10 12/19/19 14:28 57-97-6 M1 3,3'-Dimethylbenzidine ND ug/L 20.0 10.8 1 12/18/19 17:10 12/19/19 14:28 119-93-7 M1 2,4-Dimethylphenol ND ug/L 10.0 1.4 1 12/18/19 17:10 12/19/19 14:28 105-67-9 Dimethylphthalate ND ug/L 10.0 1.6 1 12/18/19 17:10 12/19/19 14:28 131-11-3 Di-n-butylphthalate ND ug/L 10.0 1.8 1 12/18/19 17:10 12/19/19 14:28 84-74-2 4,6-Dinitro-2-methyl phenol ND ug/L 20.0 15.2 1 12/18/19 17:10 12/19/19 14:28 534-52-1 1,3-Dinitrobenzene ND ug/L 10.0 4.6 1 12/18/19 17:10 12/19/19 14:28 99-65-0 M1,v1 2,4-Dinitrophenol ND ug/L 50.0 40.5 1 12/18/19 17:10 12/19/19 14:28 51-28-5 v1 2,4-Dinitrotoluene ND ug/L 10.0 1.2 1 12/18/19 17:10 12/19/19 14:28 121-14-2 2,6-Dinitrotoluene ND ug/L 10.0 1.4 1 12/18/19 17:10 12/19/19 14:28 606-20-2 Di-n-octylphthalate ND ug/L 10.0 1.8 1 12/18/19 17:10 12/19/19 14:28 117-84-0 Diphenylamine ND ug/L 10.0 1.7 1 12/18/19 17:10 12/19/19 14:28 122-39-4 Disulfoton ND ug/L 10.0 7.0 1 12/18/19 17:10 12/19/19 14:28 298-04-4 M1 bis(2- Ethyl hexyl)phthalate 16.1 ug/L 6.0 2.1 1 12/18/19 17:10 12/19/19 14:28 117-81-7 C9 Ethyl methanesulfonate ND ug/L 20.0 5.3 1 12/18/19 17:10 12/19/19 14:28 62-50-0 M1 Famphur ND ug/L 10.0 8.4 1 12/18/19 17:10 12/19/19 14:28 52-85-7 M1 Fluoranthene ND ug/L 10.0 1.7 1 12/18/19 17:10 12/19/19 14:28 206-44-0 Fluorene ND ug/L 10.0 1.6 1 12/18/19 17:10 12/19/19 14:28 86-73-7 Hexachlorobenzene ND ug/L 10.0 1.7 1 12/18/19 17:10 12/19/19 14:28 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1.7 1 12/18/19 17:10 12/19/19 14:28 77-47-4 Hexachloroethane ND ug/L 10.0 2.0 1 12/18/19 17:10 12/19/19 14:28 67-72-1 Hexachloropropene ND ug/L 10.0 1.7 1 12/18/19 17:10 12/19/19 14:28 1888-71-7 M1 Indeno(1,2,3-cd)pyrene ND ug/L 10.0 1.6 1 12/18/19 17:10 12/19/19 14:28 193-39-5 Isodrin ND ug/L 10.0 4.8 1 12/18/19 17:10 12/19/19 14:28 465-73-6 M1 Isophorone ND ug/L 10.0 1.6 1 12/18/19 17:10 12/19/19 14:28 78-59-1 Isosafrole ND ug/L 10.0 3.4 1 12/18/19 17:10 12/19/19 14:28 120-58-1 M1 Kepone ND ug/L 10.0 8.5 1 12/18/19 17:10 12/19/19 14:28 143-50-0 M1,v2 Methapyrilene ND ug/L 50.0 2.3 1 12/18/19 17:10 12/19/19 14:28 91-80-5 M1 3-Methylcholanthrene ND ug/L 10.0 5.7 1 12/18/19 17:10 12/19/19 14:28 56-49-5 IL,L1, MO Methyl methanesulfonate ND ug/L 5.0 4.3 1 12/18/19 17:10 12/19/19 14:28 66-27-3 M1 2-Methylnaphthalene ND ug/L 10.0 1.4 1 12/18/19 17:10 12/19/19 14:28 91-57-6 Methyl parathion ND ug/L 10.0 4.5 1 12/18/19 17:10 12/19/19 14:28 298-00-0 M1 2-Methylphenol(o-Cresol) ND ug/L 10.0 1.2 1 12/18/19 17:10 12/19/19 14:28 95-48-7 3&4-Methyl phenol (m&p Cresol) ND ug/L 10.0 1.2 1 12/18/19 17:10 12/19/19 14:28 15831-10-4 1-Naphthalenamine ND ug/L 5.0 2.9 1 12/18/19 17:10 12/19/19 14:28 134-32-7 M1 2-Naphthalenamine ND ug/L 5.0 4.2 1 12/18/19 17:10 12/19/19 14:28 91-59-8 M1 1,4-Naphthoquinone ND ug/L 5.0 4.4 1 12/18/19 17:10 12/19/19 14:28 130-15-4 M1 2-Nitroaniline ND ug/L 20.0 4.2 1 12/18/19 17:10 12/19/19 14:28 88-74-4 3-Nitroaniline ND ug/L 20.0 2.3 1 12/18/19 17:10 12/19/19 14:28 99-09-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-2 Lab ID: 92457256001 Collected: 12/11/19 10:01 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E APP9 RV 4-Nitroaniline Nitrobenzene 2-Nitrophenol 4-Nitrophenol 5-Nitro-o-toluidine N-Nitrosodiethylamine N-Nitrosodimethylamine N-Nitroso-di-n-butylamine N-Nitroso-di-n-propylamine N-Nitrosodiphenylamine N-Nitrosomethylethylamine N-Nitrosopiperidine N-Nitrosopyrrolidine O,O,O-Triethylphosphorothioate 2,2'-Oxybis(1-chloropropane) Parathion (Ethyl parathion) Pentachlorobenzene Pentachloronitrobenzene Pentachlorophenol Phenacetin Phenanthrene Phenol p-Phenylenediamine Phorate Pronamide Pyrene Safrole 1,2,4,5-Tetrachlorobenzene 2,3,4,6-Tetrachlorophenol Thionazin O-Toluidine 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol 1,3,5-Trinitrobenzene Surrogates Nitrobenzene-d5 (S) 2-Fluorobiphenyl (S) Terphenyl-d14 (S) Phenol-d6 (S) 2-Fluorophenol (S) 2,4,6-Tribromophenol (S) 8260D MSV Low Level Landfill Acetone Acetonitrile Acrolein Analytical Method: EPA 8270E Preparation Method: EPA 3510C ND ug/L 20.0 2.2 1 12/18/1917:10 12/19/1914:28 100-01-6 ND ug/L 10.0 2.1 1 12/18/1917:10 12/19/1914:28 98-95-3 ND ug/L 10.0 1.4 1 12/18/1917:10 12/19/1914:28 88-75-5 ND ug/L 50.0 3.5 1 12/18/1917:10 12/19/1914:28 100-02-7 ND ug/L 10.0 3.9 1 12/18/1917:10 12/19/1914:28 99-55-8 ND ug/L 10.0 4.0 1 12/18/1917:10 12/19/1914:28 55-18-5 ND ug/L 10.0 1.2 1 12/18/1917:10 12/19/1914:28 62-75-9 ND ug/L 10.0 3.2 1 12/18/1917:10 12/19/1914:28 924-16-3 ND ug/L 10.0 2.2 1 12/18/1917:10 12/19/1914:28 621-64-7 ND ug/L 10.0 1.7 1 12/18/1917:10 12/19/1914:28 86-30-6 ND ug/L 10.0 3.5 1 12/18/1917:10 12/19/1914:28 10595-95-6 ND ug/L 10.0 3.8 1 12/18/1917:10 12/19/1914:28 100-75-4 ND ug/L 10.0 3.8 1 12/18/1917:10 12/19/1914:28 930-55-2 ND ug/L 10.0 4.5 1 12/18/1917:10 12/19/1914:28 126-68-1 ND ug/L 10.0 2.8 1 12/18/1917:10 12/19/1914:28 108-60-1 ND ug/L 10.0 4.1 1 12/18/1917:10 12/19/1914:28 56-38-2 ND ug/L 10.0 3.5 1 12/18/1917:10 12/19/1914:28 608-93-5 ND ug/L 10.0 4.4 1 12/18/1917:10 12/19/1914:28 82-68-8 ND ug/L 20.0 2.2 1 12/18/1917:10 12/19/1914:28 87-86-5 ND ug/L 10.0 4.2 1 12/18/1917:10 12/19/1914:28 62-44-2 ND ug/L 10.0 1.7 1 12/18/1917:10 12/19/1914:28 85-01-8 ND ug/L 10.0 0.92 1 12/18/1917:10 12/19/1914:28 108-95-2 ND ug/L 10.0 4.2 1 12/18/1917:10 12/19/1914:28 106-50-3 ND ug/L 10.0 5.3 1 12/18/1917:10 12/19/1914:28 298-02-2 ND ug/L 10.0 4.6 1 12/18/1917:10 12/19/1914:28 23950-58-5 ND ug/L 10.0 2.1 1 12/18/1917:10 12/19/1914:28 129-00-0 ND ug/L 10.0 4.5 1 12/18/1917:10 12/19/1914:28 94-59-7 ND ug/L 10.0 2.8 1 12/18/1917:10 12/19/1914:28 95-94-3 ND ug/L 10.0 1.4 1 12/18/1917:10 12/19/1914:28 58-90-2 ND ug/L 10.0 4.8 1 12/18/1917:10 12/19/1914:28 297-97-2 ND ug/L 10.0 3.7 1 12/18/1917:10 12/19/1914:28 95-53-4 ND ug/L 10.0 1.4 1 12/18/1917:10 12/19/1914:28 95-95-4 ND ug/L 10.0 1.5 1 12/18/1917:10 12/19/1914:28 88-06-2 ND ug/L 10.0 4.7 1 12/18/1917:10 12/19/1914:28 99-35-4 97 % 13-130 1 12/18/1917:10 12/19/1914:28 4165-60-0 89 % 13-130 1 12/18/1917:10 12/19/1914:28 321-60-8 112 % 25-130 1 12/18/1917:10 12/19/1914:28 1718-51-0 54 % 10-130 1 12/18/1917:10 12/19/1914:28 13127-88-3 72 % 10-130 1 12/18/1917:10 12/19/1914:28 367-12-4 121 % 10-137 1 12/18/1917:10 12/19/1914:28 118-79-6 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/23/1913:01 67-64-1 ND ug/L 50.0 30.4 1 12/23/1913:01 75-05-8 ND ug/L 10.0 2.7 1 12/23/1913:01 107-02-8 REPORT OF LABORATORY ANALYSIS M1 M1 M1 M1 M1 M1 M1 M1 M1 M1 v1 M1 M1 M1 M1 M1 M1 v1 M1 M1 L1,M0 H4 This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-2 Lab ID: 92457256001 Collected: 12/11/19 10:01 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acrylonitrile Allyl chloride Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Chloroprene Dibromochloromethane Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene Ethyl methacrylate Hexachloro-1,3-butadiene 2-Hexanone lodomethane Isobutanol Methacrylonitrile Methylene Chloride Methyl methacrylate 4-Methyl-2-pentanone (MIBK) Naphthalene Propionitrile Styrene Date: 12/31/2019 01:42 PM Analytical Method: EPA 8260D ND ug/L 10.0 0.90 1 12/23/1913:01 107-13-1 ND ug/L 2.0 0.28 1 12/23/1913:01 107-05-1 ND ug/L 1.0 0.15 1 12/23/1913:01 71-43-2 ND ug/L 1.0 0.34 1 12/23/1913:01 74-97-5 ND ug/L 1.0 0.26 1 12/23/1913:01 75-27-4 ND ug/L 1.0 0.62 1 12/23/1913:01 75-25-2 ND ug/L 2.0 0.62 1 12/23/1913:01 74-83-9 ND ug/L 5.0 3.3 1 12/23/1913:01 78-93-3 ND ug/L 2.0 0.40 1 12/23/1913:01 75-15-0 ND ug/L 1.0 0.22 1 12/23/1913:01 56-23-5 ND ug/L 1.0 0.23 1 12/23/1913:01 108-90-7 ND ug/L 1.0 0.49 1 12/23/1913:01 75-00-3 ND ug/L 5.0 2.3 1 12/23/1913:01 67-66-3 ND ug/L 1.0 0.39 1 12/23/1913:01 74-87-3 ND ug/L 5.0 1.7 1 12/23/1913:01 126-99-8 ND ug/L 1.0 0.41 1 12/23/1913:01 124-48-1 ND ug/L 1.0 0.46 1 12/23/1913:01 74-95-3 ND ug/L 1.0 0.29 1 12/23/1913:01 95-50-1 ND ug/L 1.0 0.26 1 12/23/1913:01 106-46-7 ND ug/L 1.0 0.54 1 12/23/1913:01 110-57-6 ND ug/L 1.0 0.23 1 12/23/1913:01 75-71-8 2.1 ug/L 1.0 0.27 1 12/23/1913:01 75-34-3 ND ug/L 1.0 0.34 1 12/23/1913:01 107-06-2 ND ug/L 1.0 0.24 1 12/23/1913:01 75-35-4 1.8 ug/L 1.0 0.29 1 12/23/1913:01 156-59-2 ND ug/L 1.0 0.25 1 12/23/1913:01 156-60-5 ND ug/L 1.0 0.19 1 12/23/1913:01 78-87-5 ND ug/L 1.0 0.16 1 12/23/1913:01 142-28-9 ND ug/L 1.0 0.27 1 12/23/1913:01 594-20-7 ND ug/L 1.0 0.21 1 12/23/1913:01 563-58-6 ND ug/L 1.0 0.30 1 12/23/1913:01 10061-01-5 ND ug/L 1.0 0.31 1 12/23/1913:01 10061-02-6 ND ug/L 150 56.2 1 12/23/1913:01 123-91-1 ND ug/L 1.0 0.26 1 12/23/1913:01 100-41-4 ND ug/L 1.0 0.51 1 12/23/1913:01 97-63-2 ND ug/L 1.0 0.44 1 12/23/1913:01 87-68-3 ND ug/L 5.0 0.57 1 12/23/1913:01 591-78-6 ND ug/L 20.0 12.5 1 12/23/1913:01 74-88-4 ND ug/L 100 66.4 1 12/23/1913:01 78-83-1 ND ug/L 10.0 1.9 1 12/23/1913:01 126-98-7 ND ug/L 5.0 3.7 1 12/23/1913:01 75-09-2 ND ug/L 2.0 0.46 1 12/23/1913:01 80-62-6 ND ug/L 5.0 4.5 1 12/23/1913:01 108-10-1 ND ug/L 1.0 0.35 1 12/23/1913:01 91-20-3 ND ug/L 20.0 1.8 1 12/23/1913:01 107-12-0 ND ug/L 1.0 0.27 1 12/23/1913:01 100-42-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-2 Lab ID: 92457256001 Collected: 12/11/19 10:01 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 300.0 IC Anions 28 Days Sulfate 4500CNE Cyanide, Total Cyanide Date: 12/31/2019 01:42 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.34 1 12/23/1913:01 630-20-6 ND ug/L 1.0 0.22 1 12/23/1913:01 79-34-5 ND ug/L 1.0 0.16 1 12/23/1913:01 127-18-4 ND ug/L 1.0 0.24 1 12/23/1913:01 108-88-3 ND ug/L 1.0 0.34 1 12/23/1913:01 87-61-6 ND ug/L 1.0 0.18 1 12/23/1913:01 71-55-6 ND ug/L 1.0 0.24 1 12/23/1913:01 79-00-5 ND ug/L 1.0 0.22 1 12/23/1913:01 79-01-6 ND ug/L 1.0 0.31 1 12/23/1913:01 75-69-4 ND ug/L 1.0 0.35 1 12/23/1913:01 96-18-4 ND ug/L 2.0 1.4 1 12/23/1913:01 108-05-4 ND ug/L 1.0 0.24 1 12/23/1913:01 75-01-4 ND ug/L 1.0 0.63 1 12/23/1913:01 1330-20-7 102 % 70-130 1 12/23/1913:01 460-00-4 98 % 70-130 1 12/23/1913:01 17060-07-0 103 % 70-130 1 12/23/1913:01 2037-26-5 Analytical Method: EPA 300.0 Rev 2.1 1993 2150 ug/L 1000 500 1 12/27/1912:39 14808-79-8 Analytical Method: SM 4500-CN-E-2011 Preparation Method: SM 4500-CN-E-2011 ND ug/L 8.0 6.0 1 12/18/19 09:28 12/18/19 12:56 57-12-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-6R Lab ID: 92457256002 Collected: 12/11/19 11:48 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Chlorinated Herb. (GC) 8151 Analytical Method: EPA8151 Preparation Method: 8151A 2,4-D ND ug/L 2.00 0.744 1 12/16/19 09:15 12/17/19 09:48 94-75-7 Dinoseb ND ug/L 2.00 0.795 1 12/16/19 09:15 12/17/19 09:48 88-85-7 2,4,5-T ND ug/L 2.00 0.843 1 12/16/19 09:15 12/17/19 09:48 93-76-5 2,4,5-TP (Silvex) ND ug/L 2.00 0.845 1 12/16/19 09:15 12/17/19 09:48 93-72-1 Surrogates 2,4-DCAA (S) 25.8 % 14.0-158 1 12/16/19 09:15 12/17/19 09:48 19719-28-9 8081 OC Pesticides RVE Analytical Method: EPA 8081 B Preparation Method: EPA 3510C Aldrin ND ug/L 0.050 0.022 1 12/18/19 10:46 12/18/19 22:10 309-00-2 alpha-BHC ND ug/L 0.050 0.019 1 12/18/19 10:46 12/18/19 22:10 319-84-6 beta-BHC ND ug/L 0.050 0.014 1 12/18/19 10:46 12/18/19 22:10 319-85-7 delta-BHC ND ug/L 0.050 0.020 1 12/18/19 10:46 12/18/19 22:10 319-86-8 gamma-BHC (Lindane) ND ug/L 0.050 0.012 1 12/18/19 10:46 12/18/19 22:10 58-89-9 Chlordane (Technical) ND ug/L 0.20 0.20 1 12/18/19 10:46 12/18/19 22:10 57-74-9 4,4'-DDD ND ug/L 0.050 0.0069 1 12/18/19 10:46 12/18/19 22:10 72-54-8 4,4'-DDE ND ug/L 0.050 0.0064 1 12/18/19 10:46 12/18/19 22:10 72-55-9 4,4'-DDT ND ug/L 0.050 0.018 1 12/18/19 10:46 12/18/19 22:10 50-29-3 Dieldrin ND ug/L 0.050 0.0073 1 12/18/19 10:46 12/18/19 22:10 60-57-1 Endosulfan I ND ug/L 0.050 0.0094 1 12/18/19 10:46 12/18/19 22:10 959-98-8 Endosulfan II ND ug/L 0.050 0.0065 1 12/18/19 10:46 12/18/19 22:10 33213-65-9 Endosulfan sulfate ND ug/L 0.050 0.0091 1 12/18/19 10:46 12/18/19 22:10 1031-07-8 Endrin ND ug/L 0.050 0.0089 1 12/18/19 10:46 12/18/19 22:10 72-20-8 Endrin aldehyde ND ug/L 0.050 0.013 1 12/18/19 10:46 12/18/19 22:10 7421-93-4 Heptachlor ND ug/L 0.050 0.016 1 12/18/19 10:46 12/18/19 22:10 76-44-8 Heptachlor epoxide ND ug/L 0.050 0.0097 1 12/18/19 10:46 12/18/19 22:10 1024-57-3 Methoxychlor ND ug/L 0.15 0.033 1 12/18/19 10:46 12/18/19 22:10 72-43-5 Toxaphene ND ug/L 0.20 0.20 1 12/18/19 10:46 12/18/19 22:10 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 73 % 10-130 1 12/18/19 10:46 12/18/19 22:10 877-09-8 Decachlorobiphenyl (S) 113 % 10-130 1 12/18/19 10:46 12/18/19 22:10 2051-24-3 8082 GCS PCB RVE Analytical Method: EPA 8082A Preparation Method: EPA 3510C PCB-1016 (Aroclor 1016) ND ug/L 0.50 0.22 1 12/17/19 11:12 12/17/19 16:39 12674-11-2 PCB-1221 (Aroclor 1221) ND ug/L 0.50 0.32 1 12/17/19 11:12 12/17/19 16:39 11104-28-2 PCB-1232 (Aroclor 1232) ND ug/L 0.50 0.21 1 12/17/19 11:12 12/17/19 16:39 11141-16-5 PCB-1242 (Aroclor 1242) ND ug/L 0.50 0.44 1 12/17/19 11:12 12/17/19 16:39 53469-21-9 PCB-1248 (Aroclor 1248) ND ug/L 0.50 0.34 1 12/17/19 11:12 12/17/19 16:39 12672-29-6 PCB-1254 (Aroclor 1254) ND ug/L 0.50 0.24 1 12/17/19 11:12 12/17/19 16:39 11097-69-1 PCB-1260 (Aroclor 1260) ND ug/L 0.50 0.30 1 12/17/19 11:12 12/17/19 16:39 11096-82-5 Surrogates Decachlorobiphenyl (S) 51 % 10-130 1 12/17/19 11:12 12/17/19 16:39 2051-24-3 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.0 1 12/18/19 01:30 12/20/19 02:00 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 12/18/19 01:30 12/20/19 02:00 7440-38-2 Barium 76.8 ug/L 5.0 1.0 1 12/18/19 01:30 12/20/19 02:00 7440-39-3 Date: 12/31/2019 01:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-6R Lab ID: 92457256002 Collected: 12/11/19 11:48 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Tin Vanadium Zinc 6020 MET ICPMS Thallium 7470 Mercury Mercury 8270E APP9 RV Acenaphthene Acenaphthylene Acetophenone 2-Acetylaminofluorene 4-Aminobiphenyl Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Benzyl alcohol 4-Bromophenylphenyl ether Butylbenzylphthalate 4-ChIoro-3-methyl phenol 4-Chloroaniline Chlorobenzilate bis(2-Chloroethoxy)methane bis(2-Chloroethyl) ether 2-Chloronaphthalene 2-Chlorophenol 4-Chlorophenylphenyl ether Chrysene Diallate Dibenz(a,h)anthracene Dibenzofuran Date: 12/31/2019 01:42 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A 0.20J ug/L 1.0 0.20 1 12/18/19 01:30 12/20/19 02:00 7440-41-7 0.62J ug/L 1.0 0.40 1 12/18/19 01:30 12/20/19 02:00 7440-43-9 ND ug/L 5.0 1.0 1 12/18/19 01:30 12/20/19 02:00 7440-47-3 1.4J ug/L 5.0 1.1 1 12/18/19 01:30 12/20/19 02:00 7440-48-4 2.3J ug/L 5.0 2.1 1 12/18/19 01:30 12/20/19 02:00 7440-50-8 ND ug/L 5.0 1.6 1 12/18/19 01:30 12/20/19 02:00 7439-92-1 3.1J ug/L 5.0 0.90 1 12/18/19 01:30 12/20/19 02:00 7440-02-0 ND ug/L 10.0 4.7 1 12/18/19 01:30 12/20/19 02:00 7782-49-2 ND ug/L 5.0 2.5 1 12/18/19 01:30 12/20/19 02:00 7440-22-4 ND ug/L 5.0 1.6 1 12/18/19 01:30 12/20/19 02:00 7440-31-5 1.3J ug/L 5.0 1.3 1 12/18/19 01:30 12/20/19 02:00 7440-62-2 7.1J ug/L 10.0 3.9 1 12/18/19 01:30 12/20/19 02:00 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A 0.13 ug/L 0.10 0.060 1 12/18/19 02:00 12/28/19 04:43 7440-28-0 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.10 1 12/19/1912:45 12/20/1912:32 7439-97-6 Analytical Method: EPA 8270E Preparation Method: EPA 3510C ND ug/L 10.0 1.6 1 12/18/1917:10 12/19/1917:26 83-32-9 ND ug/L 10.0 1.6 1 12/18/1917:10 12/19/1917:26 208-96-8 ND ug/L 10.0 1.8 1 12/18/1917:10 12/19/1917:26 98-86-2 ND ug/L 10.0 3.1 1 12/18/1917:10 12/19/1917:26 53-96-3 ND ug/L 10.0 3.3 1 12/18/1917:10 12/19/1917:26 92-67-1 ND ug/L 10.0 1.7 1 12/18/1917:10 12/19/1917:26 120-12-7 ND ug/L 10.0 1.8 1 12/18/1917:10 12/19/1917:26 56-55-3 ND ug/L 10.0 2.1 1 12/18/1917:10 12/19/1917:26 50-32-8 ND ug/L 10.0 1.9 1 12/18/1917:10 12/19/1917:26 205-99-2 ND ug/L 10.0 1.4 1 12/18/1917:10 12/19/1917:26 191-24-2 ND ug/L 10.0 1.9 1 12/18/1917:10 12/19/1917:26 207-08-9 ND ug/L 20.0 2.6 1 12/18/1917:10 12/19/1917:26 100-51-6 ND ug/L 10.0 1.6 1 12/18/1917:10 12/19/1917:26 101-55-3 ND ug/L 10.0 1.6 1 12/18/1917:10 12/19/1917:26 85-68-7 ND ug/L 10.0 2.8 1 12/18/1917:10 12/19/1917:26 59-50-7 ND ug/L 20.0 2.8 1 12/18/1917:10 12/19/1917:26 106-47-8 ND ug/L 10.0 4.6 1 12/18/1917:10 12/19/1917:26 510-15-6 ND ug/L 10.0 1.8 1 12/18/1917:10 12/19/1917:26 111-91-1 ND ug/L 10.0 1.8 1 12/18/1917:10 12/19/1917:26 111-44-4 ND ug/L 10.0 1.5 1 12/18/1917:10 12/19/1917:26 91-58-7 ND ug/L 10.0 1.2 1 12/18/1917:10 12/19/1917:26 95-57-8 ND ug/L 10.0 1.6 1 12/18/1917:10 12/19/1917:26 7005-72-3 ND ug/L 10.0 1.7 1 12/18/1917:10 12/19/1917:26 218-01-9 ND ug/L 10.0 5.3 1 12/18/1917:10 12/19/1917:26 2303-16-4 ND ug/L 10.0 1.6 1 12/18/1917:10 12/19/1917:26 53-70-3 ND ug/L 10.0 1.5 1 12/18/1917:10 12/19/1917:26 132-64-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 Page 13 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-6R Lab ID: 92457256002 Collected: 12/11/19 11:48 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C 3,3'-Dichlorobenzidine ND ug/L 20.0 3.0 1 12/18/19 17:10 12/19/19 17:26 91-94-1 2,4-Dichlorophenol ND ug/L 10.0 1.4 1 12/18/19 17:10 12/19/19 17:26 120-83-2 2,6-Dichlorophenol ND ug/L 10.0 6.0 1 12/18/19 17:10 12/19/19 17:26 87-65-0 Diethylphthalate ND ug/L 10.0 2.4 1 12/18/19 17:10 12/19/19 17:26 84-66-2 Dimethoate ND ug/L 10.0 4.8 1 12/18/19 17:10 12/19/19 17:26 60-51-5 P-Dimethylaminoazobenzene ND ug/L 5.0 1.9 1 12/18/19 17:10 12/19/19 17:26 60-11-7 7,12-Dimethylbenz(a)anthracene ND ug/L 10.0 4.0 1 12/18/19 17:10 12/19/19 17:26 57-97-6 3,3'-Dimethylbenzidine ND ug/L 20.0 10.8 1 12/18/19 17:10 12/19/19 17:26 119-93-7 2,4-Dimethylphenol ND ug/L 10.0 1.4 1 12/18/19 17:10 12/19/19 17:26 105-67-9 Dimethylphthalate ND ug/L 10.0 1.6 1 12/18/19 17:10 12/19/19 17:26 131-11-3 Di-n-butylphthalate ND ug/L 10.0 1.8 1 12/18/19 17:10 12/19/19 17:26 84-74-2 4,6-Dinitro-2-methyl phenol ND ug/L 20.0 15.2 1 12/18/19 17:10 12/19/19 17:26 534-52-1 1,3-Dinitrobenzene ND ug/L 10.0 4.6 1 12/18/19 17:10 12/19/19 17:26 99-65-0 2,4-Dinitrophenol ND ug/L 50.0 40.5 1 12/18/19 17:10 12/19/19 17:26 51-28-5 2,4-Dinitrotoluene ND ug/L 10.0 1.2 1 12/18/19 17:10 12/19/19 17:26 121-14-2 2,6-Dinitrotoluene ND ug/L 10.0 1.4 1 12/18/19 17:10 12/19/19 17:26 606-20-2 Di-n-octylphthalate ND ug/L 10.0 1.8 1 12/18/19 17:10 12/19/19 17:26 117-84-0 Diphenylamine ND ug/L 10.0 1.7 1 12/18/19 17:10 12/19/19 17:26 122-39-4 Disulfoton ND ug/L 10.0 7.0 1 12/18/19 17:10 12/19/19 17:26 298-04-4 bis(2- Ethyl hexyl)phthalate 14.2 ug/L 6.0 2.1 1 12/18/19 17:10 12/19/19 17:26 117-81-7 Ethyl methanesulfonate ND ug/L 20.0 5.3 1 12/18/19 17:10 12/19/19 17:26 62-50-0 Famphur ND ug/L 10.0 8.4 1 12/18/19 17:10 12/19/19 17:26 52-85-7 Fluoranthene ND ug/L 10.0 1.7 1 12/18/19 17:10 12/19/19 17:26 206-44-0 Fluorene ND ug/L 10.0 1.6 1 12/18/19 17:10 12/19/19 17:26 86-73-7 Hexachlorobenzene ND ug/L 10.0 1.7 1 12/18/19 17:10 12/19/19 17:26 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1.7 1 12/18/19 17:10 12/19/19 17:26 77-47-4 Hexachloroethane ND ug/L 10.0 2.0 1 12/18/19 17:10 12/19/19 17:26 67-72-1 Hexachloropropene ND ug/L 10.0 1.7 1 12/18/19 17:10 12/19/19 17:26 1888-71-7 Indeno(1,2,3-cd)pyrene ND ug/L 10.0 1.6 1 12/18/19 17:10 12/19/19 17:26 193-39-5 Isodrin ND ug/L 10.0 4.8 1 12/18/19 17:10 12/19/19 17:26 465-73-6 Isophorone ND ug/L 10.0 1.6 1 12/18/19 17:10 12/19/19 17:26 78-59-1 Isosafrole ND ug/L 10.0 3.4 1 12/18/19 17:10 12/19/19 17:26 120-58-1 Kepone ND ug/L 10.0 8.5 1 12/18/19 17:10 12/19/19 17:26 143-50-0 Methapyrilene ND ug/L 50.0 2.3 1 12/18/19 17:10 12/19/19 17:26 91-80-5 3-Methylcholanthrene ND ug/L 10.0 5.7 1 12/18/19 17:10 12/19/19 17:26 56-49-5 Methyl methanesulfonate ND ug/L 5.0 4.3 1 12/18/19 17:10 12/19/19 17:26 66-27-3 2-Methylnaphthalene ND ug/L 10.0 1.4 1 12/18/19 17:10 12/19/19 17:26 91-57-6 Methyl parathion ND ug/L 10.0 4.5 1 12/18/19 17:10 12/19/19 17:26 298-00-0 2-Methylphenol(o-Cresol) ND ug/L 10.0 1.2 1 12/18/19 17:10 12/19/19 17:26 95-48-7 3&4-Methyl phenol (m&p Cresol) ND ug/L 10.0 1.2 1 12/18/19 17:10 12/19/19 17:26 15831-10-4 1-Naphthalenamine ND ug/L 5.0 2.9 1 12/18/19 17:10 12/19/19 17:26 134-32-7 2-Naphthalenamine ND ug/L 5.0 4.2 1 12/18/19 17:10 12/19/19 17:26 91-59-8 1,4-Naphthoquinone ND ug/L 5.0 4.4 1 12/18/19 17:10 12/19/19 17:26 130-15-4 2-Nitroaniline ND ug/L 20.0 4.2 1 12/18/19 17:10 12/19/19 17:26 88-74-4 3-Nitroaniline ND ug/L 20.0 2.3 1 12/18/19 17:10 12/19/19 17:26 99-09-2 4-Nitroaniline ND ug/L 20.0 2.2 1 12/18/19 17:10 12/19/19 17:26 100-01-6 REPORT OF LABORATORY ANALYSIS C9 v2 IL,L1 This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-6R Lab ID: 92457256002 Collected: 12/11/19 11:48 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C Nitrobenzene ND ug/L 10.0 2.1 1 12/18/19 17:10 12/19/19 17:26 98-95-3 2-Nitrophenol ND ug/L 10.0 1.4 1 12/18/19 17:10 12/19/19 17:26 88-75-5 4-Nitrophenol ND ug/L 50.0 3.5 1 12/18/19 17:10 12/19/19 17:26 100-02-7 5-Nitro-o-toluidine ND ug/L 10.0 3.9 1 12/18/19 17:10 12/19/19 17:26 99-55-8 N-Nitrosodiethylamine ND ug/L 10.0 4.0 1 12/18/19 17:10 12/19/19 17:26 55-18-5 N-Nitrosodimethylamine ND ug/L 10.0 1.2 1 12/18/19 17:10 12/19/19 17:26 62-75-9 N-Nitroso-di-n-butylamine ND ug/L 10.0 3.2 1 12/18/19 17:10 12/19/19 17:26 924-16-3 N-Nitroso-di-n-propylamine ND ug/L 10.0 2.2 1 12/18/19 17:10 12/19/19 17:26 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1.7 1 12/18/19 17:10 12/19/19 17:26 86-30-6 N-Nitrosomethylethylamine ND ug/L 10.0 3.5 1 12/18/19 17:10 12/19/19 17:26 10595-95-6 N-Nitrosopiperidine ND ug/L 10.0 3.8 1 12/18/19 17:10 12/19/19 17:26 100-75-4 N-Nitrosopyrrolidine ND ug/L 10.0 3.8 1 12/18/19 17:10 12/19/19 17:26 930-55-2 O,O,O-Triethylphosphorothioate ND ug/L 10.0 4.5 1 12/18/19 17:10 12/19/19 17:26 126-68-1 2,2'-Oxybis(1-chloropropane) ND ug/L 10.0 2.8 1 12/18/19 17:10 12/19/19 17:26 108-60-1 Parathion (Ethyl parathion) ND ug/L 10.0 4.1 1 12/18/19 17:10 12/19/19 17:26 56-38-2 Pentachlorobenzene ND ug/L 10.0 3.5 1 12/18/19 17:10 12/19/19 17:26 608-93-5 Pentachloronitrobenzene ND ug/L 10.0 4.4 1 12/18/19 17:10 12/19/19 17:26 82-68-8 Pentachlorophenol ND ug/L 20.0 2.2 1 12/18/19 17:10 12/19/19 17:26 87-86-5 Phenacetin ND ug/L 10.0 4.2 1 12/18/19 17:10 12/19/19 17:26 62-44-2 Phenanthrene ND ug/L 10.0 1.7 1 12/18/19 17:10 12/19/19 17:26 85-01-8 Phenol ND ug/L 10.0 0.92 1 12/18/19 17:10 12/19/19 17:26 108-95-2 p-Phenylenediamine ND ug/L 10.0 4.2 1 12/18/19 17:10 12/19/19 17:26 106-50-3 Phorate ND ug/L 10.0 5.3 1 12/18/19 17:10 12/19/19 17:26 298-02-2 Pronamide ND ug/L 10.0 4.6 1 12/18/19 17:10 12/19/19 17:26 23950-58-5 Pyrene ND ug/L 10.0 2.1 1 12/18/19 17:10 12/19/19 17:26 129-00-0 Safrole ND ug/L 10.0 4.5 1 12/18/19 17:10 12/19/19 17:26 94-59-7 1,2,4,5-Tetrachlorobenzene ND ug/L 10.0 2.8 1 12/18/19 17:10 12/19/19 17:26 95-94-3 2,3,4,6-Tetrachlorophenol ND ug/L 10.0 1.4 1 12/18/19 17:10 12/19/19 17:26 58-90-2 Thionazin ND ug/L 10.0 4.8 1 12/18/19 17:10 12/19/19 17:26 297-97-2 O-Toluidine ND ug/L 10.0 3.7 1 12/18/19 17:10 12/19/19 17:26 95-53-4 2,4,5-Trichlorophenol ND ug/L 10.0 1.4 1 12/18/19 17:10 12/19/19 17:26 95-95-4 2,4,6-Trichlorophenol ND ug/L 10.0 1.5 1 12/18/19 17:10 12/19/19 17:26 88-06-2 1,3,5-Trinitrobenzene ND ug/L 10.0 4.7 1 12/18/19 17:10 12/19/19 17:26 99-35-4 Surrogates Nitrobenzene-d5 (S) 108 % 13-130 1 12/18/19 17:10 12/19/19 17:26 4165-60-0 2-Fluorobiphenyl (S) 94 % 13-130 1 12/18/19 17:10 12/19/19 17:26 321-60-8 Terphenyl-d14 (S) 117 % 25-130 1 12/18/19 17:10 12/19/19 17:26 1718-51-0 Phenol-d6 (S) 57 % 10-130 1 12/18/19 17:10 12/19/19 17:26 13127-88-3 2-Fluorophenol (S) 76 % 10-130 1 12/18/19 17:10 12/19/19 17:26 367-12-4 2,4,6-Tribromophenol (S) 132 % 10-137 1 12/18/19 17:10 12/19/19 17:26 118-79-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Acetone ND ug/L 25.0 6.2 1 12/23/1913:19 67-64-1 Acetonitrile ND ug/L 50.0 30.4 1 12/23/1913:19 75-05-8 Acrolein ND ug/L 10.0 2.7 1 12/23/1913:19 107-02-8 Acrylonitrile ND ug/L 10.0 0.90 1 12/23/1913:19 107-13-1 REPORT OF LABORATORY ANALYSIS v1 v1 L1 H4 This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-6R Lab ID: 92457256002 Collected: 12/11/19 11:48 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Allyl chloride Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Chloroprene Dibromochloromethane Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene Ethyl methacrylate Hexachloro-1,3-butadiene 2-Hexanone lodomethane Isobutanol Methacrylonitrile Methylene Chloride Methyl methacrylate 4-Methyl-2-pentanone (MIBK) Naphthalene Propionitrile Styrene 1,1,1,2-Tetrachloroethane Date: 12/31/2019 01:42 PM Analytical Method: EPA 8260D ND ug/L 2.0 0.28 1 12/23/1913:19 107-05-1 1.7 ug/L 1.0 0.15 1 12/23/1913:19 71-43-2 ND ug/L 1.0 0.34 1 12/23/1913:19 74-97-5 ND ug/L 1.0 0.26 1 12/23/1913:19 75-27-4 ND ug/L 1.0 0.62 1 12/23/1913:19 75-25-2 ND ug/L 2.0 0.62 1 12/23/1913:19 74-83-9 ND ug/L 5.0 3.3 1 12/23/1913:19 78-93-3 ND ug/L 2.0 0.40 1 12/23/1913:19 75-15-0 ND ug/L 1.0 0.22 1 12/23/1913:19 56-23-5 ND ug/L 1.0 0.23 1 12/23/1913:19 108-90-7 ND ug/L 1.0 0.49 1 12/23/1913:19 75-00-3 ND ug/L 5.0 2.3 1 12/23/1913:19 67-66-3 ND ug/L 1.0 0.39 1 12/23/1913:19 74-87-3 ND ug/L 5.0 1.7 1 12/23/1913:19 126-99-8 ND ug/L 1.0 0.41 1 12/23/1913:19 124-48-1 ND ug/L 1.0 0.46 1 12/23/1913:19 74-95-3 ND ug/L 1.0 0.29 1 12/23/1913:19 95-50-1 ND ug/L 1.0 0.26 1 12/23/1913:19 106-46-7 ND ug/L 1.0 0.54 1 12/23/1913:19 110-57-6 ND ug/L 1.0 0.23 1 12/23/1913:19 75-71-8 ND ug/L 1.0 0.27 1 12/23/1913:19 75-34-3 ND ug/L 1.0 0.34 1 12/23/1913:19 107-06-2 ND ug/L 1.0 0.24 1 12/23/1913:19 75-35-4 9.1 ug/L 1.0 0.29 1 12/23/1913:19 156-59-2 2.7 ug/L 1.0 0.25 1 12/23/1913:19 156-60-5 ND ug/L 1.0 0.19 1 12/23/1913:19 78-87-5 ND ug/L 1.0 0.16 1 12/23/1913:19 142-28-9 ND ug/L 1.0 0.27 1 12/23/1913:19 594-20-7 ND ug/L 1.0 0.21 1 12/23/1913:19 563-58-6 ND ug/L 1.0 0.30 1 12/23/1913:19 10061-01-5 ND ug/L 1.0 0.31 1 12/23/1913:19 10061-02-6 ND ug/L 150 56.2 1 12/23/1913:19 123-91-1 ND ug/L 1.0 0.26 1 12/23/1913:19 100-41-4 ND ug/L 1.0 0.51 1 12/23/1913:19 97-63-2 ND ug/L 1.0 0.44 1 12/23/1913:19 87-68-3 ND ug/L 5.0 0.57 1 12/23/1913:19 591-78-6 ND ug/L 20.0 12.5 1 12/23/1913:19 74-88-4 ND ug/L 100 66.4 1 12/23/1913:19 78-83-1 ND ug/L 10.0 1.9 1 12/23/1913:19 126-98-7 ND ug/L 5.0 3.7 1 12/23/1913:19 75-09-2 ND ug/L 2.0 0.46 1 12/23/1913:19 80-62-6 ND ug/L 5.0 4.5 1 12/23/1913:19 108-10-1 ND ug/L 1.0 0.35 1 12/23/1913:19 91-20-3 ND ug/L 20.0 1.8 1 12/23/1913:19 107-12-0 ND ug/L 1.0 0.27 1 12/23/1913:19 100-42-5 ND ug/L 1.0 0.34 1 12/23/1913:19 630-20-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-6R Lab ID: 92457256002 Collected: 12/11/19 11:48 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 300.0 IC Anions 28 Days Sulfate 4500CNE Cyanide, Total Cyanide Date: 12/31/2019 01:42 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.22 1 12/23/1913:19 79-34-5 ND ug/L 1.0 0.16 1 12/23/1913:19 127-18-4 ND ug/L 1.0 0.24 1 12/23/1913:19 108-88-3 ND ug/L 1.0 0.34 1 12/23/1913:19 87-61-6 ND ug/L 1.0 0.18 1 12/23/1913:19 71-55-6 ND ug/L 1.0 0.24 1 12/23/1913:19 79-00-5 ND ug/L 1.0 0.22 1 12/23/1913:19 79-01-6 ND ug/L 1.0 0.31 1 12/23/1913:19 75-69-4 ND ug/L 1.0 0.35 1 12/23/1913:19 96-18-4 ND ug/L 2.0 1.4 1 12/23/1913:19 108-05-4 2.4 ug/L 1.0 0.24 1 12/23/1913:19 75-01-4 ND ug/L 1.0 0.63 1 12/23/1913:19 1330-20-7 101 % 70-130 1 12/23/1913:19 460-00-4 99 % 70-130 1 12/23/1913:19 17060-07-0 99 % 70-130 1 12/23/1913:19 2037-26-5 Analytical Method: EPA 300.0 Rev 2.1 1993 673J ug/L 1000 500 1 12/27/1912:53 14808-79-8 Analytical Method: SM 4500-CN-E-2011 Preparation Method: SM 4500-CN-E-2011 ND ug/L 8.0 6.0 1 12/18/19 09:28 12/18/19 12:57 57-12-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-9S Lab ID: 92457256003 Collected: 12/11/19 11:10 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Chlorinated Herb. (GC) 8151 Analytical Method: EPA8151 Preparation Method: 8151A 2,4-D ND ug/L 2.00 0.744 1 12/16/19 09:15 12/17/19 10:02 94-75-7 Dinoseb ND ug/L 2.00 0.795 1 12/16/19 09:15 12/17/19 10:02 88-85-7 2,4,5-T ND ug/L 2.00 0.843 1 12/16/19 09:15 12/17/19 10:02 93-76-5 2,4,5-TP (Silvex) ND ug/L 2.00 0.845 1 12/16/19 09:15 12/17/19 10:02 93-72-1 Surrogates 2,4-DCAA (S) 26.4 % 14.0-158 1 12/16/19 09:15 12/17/19 10:02 19719-28-9 8081 OC Pesticides RVE Analytical Method: EPA 8081 B Preparation Method: EPA 3510C Aldrin ND ug/L 0.050 0.022 1 12/18/19 10:46 12/18/19 22:24 309-00-2 alpha-BHC ND ug/L 0.050 0.019 1 12/18/19 10:46 12/18/19 22:24 319-84-6 beta-BHC ND ug/L 0.050 0.014 1 12/18/19 10:46 12/18/19 22:24 319-85-7 delta-BHC ND ug/L 0.050 0.020 1 12/18/19 10:46 12/18/19 22:24 319-86-8 gamma-BHC (Lindane) ND ug/L 0.050 0.012 1 12/18/19 10:46 12/18/19 22:24 58-89-9 Chlordane (Technical) ND ug/L 0.20 0.20 1 12/18/19 10:46 12/18/19 22:24 57-74-9 4,4'-DDD ND ug/L 0.050 0.0069 1 12/18/19 10:46 12/18/19 22:24 72-54-8 4,4'-DDE ND ug/L 0.050 0.0064 1 12/18/19 10:46 12/18/19 22:24 72-55-9 4,4'-DDT ND ug/L 0.050 0.018 1 12/18/19 10:46 12/18/19 22:24 50-29-3 Dieldrin ND ug/L 0.050 0.0073 1 12/18/19 10:46 12/18/19 22:24 60-57-1 Endosulfan I ND ug/L 0.050 0.0094 1 12/18/19 10:46 12/18/19 22:24 959-98-8 Endosulfan II ND ug/L 0.050 0.0065 1 12/18/19 10:46 12/18/19 22:24 33213-65-9 Endosulfan sulfate ND ug/L 0.050 0.0091 1 12/18/19 10:46 12/18/19 22:24 1031-07-8 Endrin ND ug/L 0.050 0.0089 1 12/18/19 10:46 12/18/19 22:24 72-20-8 Endrin aldehyde ND ug/L 0.050 0.013 1 12/18/19 10:46 12/18/19 22:24 7421-93-4 Heptachlor ND ug/L 0.050 0.016 1 12/18/19 10:46 12/18/19 22:24 76-44-8 Heptachlor epoxide ND ug/L 0.050 0.0097 1 12/18/19 10:46 12/18/19 22:24 1024-57-3 Methoxychlor ND ug/L 0.15 0.033 1 12/18/19 10:46 12/18/19 22:24 72-43-5 Toxaphene ND ug/L 0.20 0.20 1 12/18/19 10:46 12/18/19 22:24 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 58 % 10-130 1 12/18/19 10:46 12/18/19 22:24 877-09-8 Decachlorobiphenyl (S) 95 % 10-130 1 12/18/19 10:46 12/18/19 22:24 2051-24-3 8082 GCS PCB RVE Analytical Method: EPA 8082A Preparation Method: EPA 3510C PCB-1016 (Aroclor 1016) ND ug/L 0.50 0.22 1 12/17/19 11:12 12/17/19 16:54 12674-11-2 PCB-1221 (Aroclor 1221) ND ug/L 0.50 0.32 1 12/17/19 11:12 12/17/19 16:54 11104-28-2 PCB-1232 (Aroclor 1232) ND ug/L 0.50 0.21 1 12/17/19 11:12 12/17/19 16:54 11141-16-5 PCB-1242 (Aroclor 1242) ND ug/L 0.50 0.44 1 12/17/19 11:12 12/17/19 16:54 53469-21-9 PCB-1248 (Aroclor 1248) ND ug/L 0.50 0.34 1 12/17/19 11:12 12/17/19 16:54 12672-29-6 PCB-1254 (Aroclor 1254) ND ug/L 0.50 0.24 1 12/17/19 11:12 12/17/19 16:54 11097-69-1 PCB-1260 (Aroclor 1260) ND ug/L 0.50 0.30 1 12/17/19 11:12 12/17/19 16:54 11096-82-5 Surrogates Decachlorobiphenyl (S) 94 % 10-130 1 12/17/19 11:12 12/17/19 16:54 2051-24-3 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.0 1 12/18/19 01:30 12/20/19 02:03 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 12/18/19 01:30 12/20/19 02:03 7440-38-2 Barium 115 ug/L 5.0 1.0 1 12/18/19 01:30 12/20/19 02:03 7440-39-3 Date: 12/31/2019 01:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-9S Lab ID: 92457256003 Collected: 12/11/19 11:10 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Tin Vanadium Zinc 6020 MET ICPMS Thallium 7470 Mercury Mercury 8270E APP9 RV Acenaphthene Acenaphthylene Acetophenone 2-Acetylaminofluorene 4-Aminobiphenyl Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Benzyl alcohol 4-Bromophenylphenyl ether Butylbenzylphthalate 4-ChIoro-3-methyl phenol 4-Chloroaniline Chlorobenzilate bis(2-Chloroethoxy)methane bis(2-Chloroethyl) ether 2-Chloronaphthalene 2-Chlorophenol 4-Chlorophenylphenyl ether Chrysene Diallate Dibenz(a,h)anthracene Dibenzofuran Date: 12/31/2019 01:42 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 1.0 0.20 1 12/18/19 01:30 12/20/19 02:03 7440-41-7 1.1 ug/L 1.0 0.40 1 12/18/19 01:30 12/20/19 02:03 7440-43-9 ND ug/L 5.0 1.0 1 12/18/19 01:30 12/20/19 02:03 7440-47-3 114 ug/L 5.0 1.1 1 12/18/19 01:30 12/20/19 02:03 7440-48-4 2.2J ug/L 5.0 2.1 1 12/18/19 01:30 12/20/19 02:03 7440-50-8 3.5J ug/L 5.0 1.6 1 12/18/19 01:30 12/20/19 02:03 7439-92-1 11.8 ug/L 5.0 0.90 1 12/18/19 01:30 12/20/19 02:03 7440-02-0 ND ug/L 10.0 4.7 1 12/18/19 01:30 12/20/19 02:03 7782-49-2 ND ug/L 5.0 2.5 1 12/18/19 01:30 12/20/19 02:03 7440-22-4 ND ug/L 5.0 1.6 1 12/18/19 01:30 12/20/19 02:03 7440-31-5 1.81 ug/L 5.0 1.3 1 12/18/19 01:30 12/20/19 02:03 7440-62-2 8.5J ug/L 10.0 3.9 1 12/18/19 01:30 12/20/19 02:03 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A 0.38 ug/L 0.10 0.060 1 12/18/19 02:00 12/28/19 04:46 7440-28-0 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.10 1 12/19/1912:45 12/20/1912:34 7439-97-6 Analytical Method: EPA 8270E Preparation Method: EPA 3510C ND ug/L 10.0 1.6 1 12/18/1917:10 12/19/1917:51 83-32-9 ND ug/L 10.0 1.6 1 12/18/1917:10 12/19/1917:51 208-96-8 ND ug/L 10.0 1.8 1 12/18/1917:10 12/19/1917:51 98-86-2 ND ug/L 10.0 3.1 1 12/18/1917:10 12/19/1917:51 53-96-3 ND ug/L 10.0 3.3 1 12/18/1917:10 12/19/1917:51 92-67-1 ND ug/L 10.0 1.7 1 12/18/1917:10 12/19/1917:51 120-12-7 ND ug/L 10.0 1.8 1 12/18/1917:10 12/19/1917:51 56-55-3 ND ug/L 10.0 2.1 1 12/18/1917:10 12/19/1917:51 50-32-8 ND ug/L 10.0 1.9 1 12/18/1917:10 12/19/1917:51 205-99-2 ND ug/L 10.0 1.4 1 12/18/1917:10 12/19/1917:51 191-24-2 ND ug/L 10.0 1.9 1 12/18/1917:10 12/19/1917:51 207-08-9 ND ug/L 20.0 2.6 1 12/18/1917:10 12/19/1917:51 100-51-6 ND ug/L 10.0 1.6 1 12/18/1917:10 12/19/1917:51 101-55-3 ND ug/L 10.0 1.6 1 12/18/1917:10 12/19/1917:51 85-68-7 ND ug/L 10.0 2.8 1 12/18/1917:10 12/19/1917:51 59-50-7 ND ug/L 20.0 2.8 1 12/18/1917:10 12/19/1917:51 106-47-8 ND ug/L 10.0 4.6 1 12/18/1917:10 12/19/1917:51 510-15-6 ND ug/L 10.0 1.8 1 12/18/1917:10 12/19/1917:51 111-91-1 ND ug/L 10.0 1.8 1 12/18/1917:10 12/19/1917:51 111-44-4 ND ug/L 10.0 1.5 1 12/18/1917:10 12/19/1917:51 91-58-7 ND ug/L 10.0 1.2 1 12/18/1917:10 12/19/1917:51 95-57-8 ND ug/L 10.0 1.6 1 12/18/1917:10 12/19/1917:51 7005-72-3 ND ug/L 10.0 1.7 1 12/18/1917:10 12/19/1917:51 218-01-9 ND ug/L 10.0 5.3 1 12/18/1917:10 12/19/1917:51 2303-16-4 ND ug/L 10.0 1.6 1 12/18/1917:10 12/19/1917:51 53-70-3 ND ug/L 10.0 1.5 1 12/18/1917:10 12/19/1917:51 132-64-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 Page 19 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-9S Lab ID: 92457256003 Collected: 12/11/19 11:10 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C 3,3'-Dichlorobenzidine ND ug/L 20.0 3.0 1 12/18/19 17:10 12/19/19 17:51 91-94-1 2,4-Dichlorophenol ND ug/L 10.0 1.4 1 12/18/19 17:10 12/19/19 17:51 120-83-2 2,6-Dichlorophenol ND ug/L 10.0 6.0 1 12/18/19 17:10 12/19/19 17:51 87-65-0 Diethylphthalate ND ug/L 10.0 2.4 1 12/18/19 17:10 12/19/19 17:51 84-66-2 Dimethoate ND ug/L 10.0 4.8 1 12/18/19 17:10 12/19/19 17:51 60-51-5 P-Dimethylaminoazobenzene ND ug/L 5.0 1.9 1 12/18/19 17:10 12/19/19 17:51 60-11-7 7,12-Dimethylbenz(a)anthracene ND ug/L 10.0 4.0 1 12/18/19 17:10 12/19/19 17:51 57-97-6 3,3'-Dimethylbenzidine ND ug/L 20.0 10.8 1 12/18/19 17:10 12/19/19 17:51 119-93-7 2,4-Dimethylphenol ND ug/L 10.0 1.4 1 12/18/19 17:10 12/19/19 17:51 105-67-9 Dimethylphthalate ND ug/L 10.0 1.6 1 12/18/19 17:10 12/19/19 17:51 131-11-3 Di-n-butylphthalate ND ug/L 10.0 1.8 1 12/18/19 17:10 12/19/19 17:51 84-74-2 4,6-Dinitro-2-methyl phenol ND ug/L 20.0 15.2 1 12/18/19 17:10 12/19/19 17:51 534-52-1 1,3-Dinitrobenzene ND ug/L 10.0 4.6 1 12/18/19 17:10 12/19/19 17:51 99-65-0 2,4-Dinitrophenol ND ug/L 50.0 40.5 1 12/18/19 17:10 12/19/19 17:51 51-28-5 2,4-Dinitrotoluene ND ug/L 10.0 1.2 1 12/18/19 17:10 12/19/19 17:51 121-14-2 2,6-Dinitrotoluene ND ug/L 10.0 1.4 1 12/18/19 17:10 12/19/19 17:51 606-20-2 Di-n-octylphthalate ND ug/L 10.0 1.8 1 12/18/19 17:10 12/19/19 17:51 117-84-0 Diphenylamine ND ug/L 10.0 1.7 1 12/18/19 17:10 12/19/19 17:51 122-39-4 Disulfoton ND ug/L 10.0 7.0 1 12/18/19 17:10 12/19/19 17:51 298-04-4 bis(2- Ethyl hexyl)phthalate 12.3 ug/L 6.0 2.1 1 12/18/19 17:10 12/19/19 17:51 117-81-7 Ethyl methanesulfonate ND ug/L 20.0 5.3 1 12/18/19 17:10 12/19/19 17:51 62-50-0 Famphur ND ug/L 10.0 8.4 1 12/18/19 17:10 12/19/19 17:51 52-85-7 Fluoranthene ND ug/L 10.0 1.7 1 12/18/19 17:10 12/19/19 17:51 206-44-0 Fluorene ND ug/L 10.0 1.6 1 12/18/19 17:10 12/19/19 17:51 86-73-7 Hexachlorobenzene ND ug/L 10.0 1.7 1 12/18/19 17:10 12/19/19 17:51 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1.7 1 12/18/19 17:10 12/19/19 17:51 77-47-4 Hexachloroethane ND ug/L 10.0 2.0 1 12/18/19 17:10 12/19/19 17:51 67-72-1 Hexachloropropene ND ug/L 10.0 1.7 1 12/18/19 17:10 12/19/19 17:51 1888-71-7 Indeno(1,2,3-cd)pyrene ND ug/L 10.0 1.6 1 12/18/19 17:10 12/19/19 17:51 193-39-5 Isodrin ND ug/L 10.0 4.8 1 12/18/19 17:10 12/19/19 17:51 465-73-6 Isophorone ND ug/L 10.0 1.6 1 12/18/19 17:10 12/19/19 17:51 78-59-1 Isosafrole ND ug/L 10.0 3.4 1 12/18/19 17:10 12/19/19 17:51 120-58-1 Kepone ND ug/L 10.0 8.5 1 12/18/19 17:10 12/19/19 17:51 143-50-0 Methapyrilene ND ug/L 50.0 2.3 1 12/18/19 17:10 12/19/19 17:51 91-80-5 3-Methylcholanthrene ND ug/L 10.0 5.7 1 12/18/19 17:10 12/19/19 17:51 56-49-5 Methyl methanesulfonate ND ug/L 5.0 4.3 1 12/18/19 17:10 12/19/19 17:51 66-27-3 2-Methylnaphthalene ND ug/L 10.0 1.4 1 12/18/19 17:10 12/19/19 17:51 91-57-6 Methyl parathion ND ug/L 10.0 4.5 1 12/18/19 17:10 12/19/19 17:51 298-00-0 2-Methylphenol(o-Cresol) ND ug/L 10.0 1.2 1 12/18/19 17:10 12/19/19 17:51 95-48-7 3&4-Methyl phenol (m&p Cresol) ND ug/L 10.0 1.2 1 12/18/19 17:10 12/19/19 17:51 15831-10-4 1-Naphthalenamine ND ug/L 5.0 2.9 1 12/18/19 17:10 12/19/19 17:51 134-32-7 2-Naphthalenamine ND ug/L 5.0 4.2 1 12/18/19 17:10 12/19/19 17:51 91-59-8 1,4-Naphthoquinone ND ug/L 5.0 4.4 1 12/18/19 17:10 12/19/19 17:51 130-15-4 2-Nitroaniline ND ug/L 20.0 4.2 1 12/18/19 17:10 12/19/19 17:51 88-74-4 3-Nitroaniline ND ug/L 20.0 2.3 1 12/18/19 17:10 12/19/19 17:51 99-09-2 4-Nitroaniline ND ug/L 20.0 2.2 1 12/18/19 17:10 12/19/19 17:51 100-01-6 REPORT OF LABORATORY ANALYSIS C9 v2 IL,L1 This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-9S Lab ID: 92457256003 Collected: 12/11/19 11:10 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C Nitrobenzene ND ug/L 10.0 2.1 1 12/18/19 17:10 12/19/19 17:51 98-95-3 2-Nitrophenol ND ug/L 10.0 1.4 1 12/18/19 17:10 12/19/19 17:51 88-75-5 4-Nitrophenol ND ug/L 50.0 3.5 1 12/18/19 17:10 12/19/19 17:51 100-02-7 5-Nitro-o-toluidine ND ug/L 10.0 3.9 1 12/18/19 17:10 12/19/19 17:51 99-55-8 N-Nitrosodiethylamine ND ug/L 10.0 4.0 1 12/18/19 17:10 12/19/19 17:51 55-18-5 N-Nitrosodimethylamine ND ug/L 10.0 1.2 1 12/18/19 17:10 12/19/19 17:51 62-75-9 N-Nitroso-di-n-butylamine ND ug/L 10.0 3.2 1 12/18/19 17:10 12/19/19 17:51 924-16-3 N-Nitroso-di-n-propylamine ND ug/L 10.0 2.2 1 12/18/19 17:10 12/19/19 17:51 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1.7 1 12/18/19 17:10 12/19/19 17:51 86-30-6 N-Nitrosomethylethylamine ND ug/L 10.0 3.5 1 12/18/19 17:10 12/19/19 17:51 10595-95-6 N-Nitrosopiperidine ND ug/L 10.0 3.8 1 12/18/19 17:10 12/19/19 17:51 100-75-4 N-Nitrosopyrrolidine ND ug/L 10.0 3.8 1 12/18/19 17:10 12/19/19 17:51 930-55-2 O,O,O-Triethylphosphorothioate ND ug/L 10.0 4.5 1 12/18/19 17:10 12/19/19 17:51 126-68-1 2,2'-Oxybis(1-chloropropane) ND ug/L 10.0 2.8 1 12/18/19 17:10 12/19/19 17:51 108-60-1 Parathion (Ethyl parathion) ND ug/L 10.0 4.1 1 12/18/19 17:10 12/19/19 17:51 56-38-2 Pentachlorobenzene ND ug/L 10.0 3.5 1 12/18/19 17:10 12/19/19 17:51 608-93-5 Pentachloronitrobenzene ND ug/L 10.0 4.4 1 12/18/19 17:10 12/19/19 17:51 82-68-8 Pentachlorophenol ND ug/L 20.0 2.2 1 12/18/19 17:10 12/19/19 17:51 87-86-5 Phenacetin ND ug/L 10.0 4.2 1 12/18/19 17:10 12/19/19 17:51 62-44-2 Phenanthrene ND ug/L 10.0 1.7 1 12/18/19 17:10 12/19/19 17:51 85-01-8 Phenol ND ug/L 10.0 0.92 1 12/18/19 17:10 12/19/19 17:51 108-95-2 p-Phenylenediamine ND ug/L 10.0 4.2 1 12/18/19 17:10 12/19/19 17:51 106-50-3 Phorate ND ug/L 10.0 5.3 1 12/18/19 17:10 12/19/19 17:51 298-02-2 Pronamide ND ug/L 10.0 4.6 1 12/18/19 17:10 12/19/19 17:51 23950-58-5 Pyrene ND ug/L 10.0 2.1 1 12/18/19 17:10 12/19/19 17:51 129-00-0 Safrole ND ug/L 10.0 4.5 1 12/18/19 17:10 12/19/19 17:51 94-59-7 1,2,4,5-Tetrachlorobenzene ND ug/L 10.0 2.8 1 12/18/19 17:10 12/19/19 17:51 95-94-3 2,3,4,6-Tetrachlorophenol ND ug/L 10.0 1.4 1 12/18/19 17:10 12/19/19 17:51 58-90-2 Thionazin ND ug/L 10.0 4.8 1 12/18/19 17:10 12/19/19 17:51 297-97-2 O-Toluidine ND ug/L 10.0 3.7 1 12/18/19 17:10 12/19/19 17:51 95-53-4 2,4,5-Trichlorophenol ND ug/L 10.0 1.4 1 12/18/19 17:10 12/19/19 17:51 95-95-4 2,4,6-Trichlorophenol ND ug/L 10.0 1.5 1 12/18/19 17:10 12/19/19 17:51 88-06-2 1,3,5-Trinitrobenzene ND ug/L 10.0 4.7 1 12/18/19 17:10 12/19/19 17:51 99-35-4 Surrogates Nitrobenzene-d5 (S) 105 % 13-130 1 12/18/19 17:10 12/19/19 17:51 4165-60-0 2-Fluorobiphenyl (S) 96 % 13-130 1 12/18/19 17:10 12/19/19 17:51 321-60-8 Terphenyl-d14 (S) 121 % 25-130 1 12/18/19 17:10 12/19/19 17:51 1718-51-0 Phenol-d6 (S) 55 % 10-130 1 12/18/19 17:10 12/19/19 17:51 13127-88-3 2-Fluorophenol (S) 73 % 10-130 1 12/18/19 17:10 12/19/19 17:51 367-12-4 2,4,6-Tribromophenol (S) 127 % 10-137 1 12/18/19 17:10 12/19/19 17:51 118-79-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Acetone ND ug/L 25.0 6.2 1 12/23/1913:36 67-64-1 Acetonitrile ND ug/L 50.0 30.4 1 12/23/1913:36 75-05-8 Acrolein ND ug/L 10.0 2.7 1 12/23/1913:36 107-02-8 Acrylonitrile ND ug/L 10.0 0.90 1 12/23/1913:36 107-13-1 REPORT OF LABORATORY ANALYSIS v1 v1 L1 H4 This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-9S Lab ID: 92457256003 Collected: 12/11/19 11:10 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Allyl chloride Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Chloroprene Dibromochloromethane Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene Ethyl methacrylate Hexachloro-1,3-butadiene 2-Hexanone lodomethane Isobutanol Methacrylonitrile Methylene Chloride Methyl methacrylate 4-Methyl-2-pentanone (MIBK) Naphthalene Propionitrile Styrene 1,1,1,2-Tetrachloroethane Date: 12/31/2019 01:42 PM Analytical Method: EPA 8260D ND ug/L 2.0 0.28 1 12/23/1913:36 107-05-1 0.96J ug/L 1.0 0.15 1 12/23/1913:36 71-43-2 ND ug/L 1.0 0.34 1 12/23/1913:36 74-97-5 ND ug/L 1.0 0.26 1 12/23/1913:36 75-27-4 ND ug/L 1.0 0.62 1 12/23/1913:36 75-25-2 ND ug/L 2.0 0.62 1 12/23/1913:36 74-83-9 ND ug/L 5.0 3.3 1 12/23/1913:36 78-93-3 ND ug/L 2.0 0.40 1 12/23/1913:36 75-15-0 ND ug/L 1.0 0.22 1 12/23/1913:36 56-23-5 ND ug/L 1.0 0.23 1 12/23/1913:36 108-90-7 ND ug/L 1.0 0.49 1 12/23/1913:36 75-00-3 ND ug/L 5.0 2.3 1 12/23/1913:36 67-66-3 ND ug/L 1.0 0.39 1 12/23/1913:36 74-87-3 ND ug/L 5.0 1.7 1 12/23/1913:36 126-99-8 ND ug/L 1.0 0.41 1 12/23/1913:36 124-48-1 ND ug/L 1.0 0.46 1 12/23/1913:36 74-95-3 ND ug/L 1.0 0.29 1 12/23/1913:36 95-50-1 ND ug/L 1.0 0.26 1 12/23/1913:36 106-46-7 ND ug/L 1.0 0.54 1 12/23/1913:36 110-57-6 ND ug/L 1.0 0.23 1 12/23/1913:36 75-71-8 ND ug/L 1.0 0.27 1 12/23/1913:36 75-34-3 ND ug/L 1.0 0.34 1 12/23/1913:36 107-06-2 ND ug/L 1.0 0.24 1 12/23/1913:36 75-35-4 7.1 ug/L 1.0 0.29 1 12/23/1913:36 156-59-2 0.66J ug/L 1.0 0.25 1 12/23/1913:36 156-60-5 ND ug/L 1.0 0.19 1 12/23/1913:36 78-87-5 ND ug/L 1.0 0.16 1 12/23/1913:36 142-28-9 ND ug/L 1.0 0.27 1 12/23/1913:36 594-20-7 ND ug/L 1.0 0.21 1 12/23/1913:36 563-58-6 ND ug/L 1.0 0.30 1 12/23/1913:36 10061-01-5 ND ug/L 1.0 0.31 1 12/23/1913:36 10061-02-6 ND ug/L 150 56.2 1 12/23/1913:36 123-91-1 ND ug/L 1.0 0.26 1 12/23/1913:36 100-41-4 ND ug/L 1.0 0.51 1 12/23/1913:36 97-63-2 ND ug/L 1.0 0.44 1 12/23/1913:36 87-68-3 ND ug/L 5.0 0.57 1 12/23/1913:36 591-78-6 ND ug/L 20.0 12.5 1 12/23/1913:36 74-88-4 ND ug/L 100 66.4 1 12/23/1913:36 78-83-1 ND ug/L 10.0 1.9 1 12/23/1913:36 126-98-7 ND ug/L 5.0 3.7 1 12/23/1913:36 75-09-2 ND ug/L 2.0 0.46 1 12/23/1913:36 80-62-6 ND ug/L 5.0 4.5 1 12/23/1913:36 108-10-1 ND ug/L 1.0 0.35 1 12/23/1913:36 91-20-3 ND ug/L 20.0 1.8 1 12/23/1913:36 107-12-0 ND ug/L 1.0 0.27 1 12/23/1913:36 100-42-5 ND ug/L 1.0 0.34 1 12/23/1913:36 630-20-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-9S Lab ID: 92457256003 Collected: 12/11/19 11:10 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 300.0 IC Anions 28 Days Sulfate 4500CNE Cyanide, Total Cyanide Date: 12/31/2019 01:42 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.22 1 12/23/1913:36 79-34-5 ND ug/L 1.0 0.16 1 12/23/1913:36 127-18-4 ND ug/L 1.0 0.24 1 12/23/1913:36 108-88-3 ND ug/L 1.0 0.34 1 12/23/1913:36 87-61-6 ND ug/L 1.0 0.18 1 12/23/1913:36 71-55-6 ND ug/L 1.0 0.24 1 12/23/1913:36 79-00-5 0.51J ug/L 1.0 0.22 1 12/23/1913:36 79-01-6 ND ug/L 1.0 0.31 1 12/23/1913:36 75-69-4 ND ug/L 1.0 0.35 1 12/23/1913:36 96-18-4 ND ug/L 2.0 1.4 1 12/23/1913:36 108-05-4 ND ug/L 1.0 0.24 1 12/23/1913:36 75-01-4 ND ug/L 1.0 0.63 1 12/23/1913:36 1330-20-7 100 % 70-130 1 12/23/1913:36 460-00-4 98 % 70-130 1 12/23/1913:36 17060-07-0 99 % 70-130 1 12/23/1913:36 2037-26-5 Analytical Method: EPA 300.0 Rev 2.1 1993 2850 ug/L 1000 500 1 12/27/1913:08 14808-79-8 Analytical Method: SM 4500-CN-E-2011 Preparation Method: SM 4500-CN-E-2011 ND ug/L 8.0 6.0 1 12/18/19 09:28 12/18/19 13:00 57-12-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: LAGOON Lab ID: 92457256004 Collected: 12/11/19 16:35 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/31/2019 01:42 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 12/18/19 01:30 12/20/19 02:20 7440-36-0 ND ug/L 10.0 4.7 1 12/18/19 01:30 12/20/19 02:20 7440-38-2 174 ug/L 5.0 1.0 1 12/18/19 01:30 12/20/19 02:20 7440-39-3 ND ug/L 1.0 0.20 1 12/18/19 01:30 12/20/19 02:20 7440-41-7 ND ug/L 1.0 0.40 1 12/18/19 01:30 12/20/19 02:20 7440-43-9 ND ug/L 5.0 1.0 1 12/18/19 01:30 12/20/19 02:20 7440-47-3 22.6 ug/L 5.0 1.1 1 12/18/19 01:30 12/20/19 02:20 7440-48-4 2.8J ug/L 5.0 2.1 1 12/18/19 01:30 12/20/19 02:20 7440-50-8 3.5J ug/L 5.0 1.6 1 12/18/19 01:30 12/20/19 02:20 7439-92-1 4.2J ug/L 5.0 0.90 1 12/18/19 01:30 12/20/19 02:20 7440-02-0 9.5J ug/L 10.0 4.7 1 12/18/19 01:30 12/20/19 02:20 7782-49-2 ND ug/L 5.0 2.5 1 12/18/19 01:30 12/20/19 02:20 7440-22-4 2.3J ug/L 5.0 1.3 1 12/18/19 01:30 12/20/19 02:20 7440-62-2 ND ug/L 10.0 3.9 1 12/18/19 01:30 12/20/19 02:20 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/18/19 02:00 12/28/19 04:54 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/23/1913:54 67-64-1 ND ug/L 10.0 0.90 1 12/23/1913:54 107-13-1 ND ug/L 1.0 0.15 1 12/23/1913:54 71-43-2 ND ug/L 1.0 0.34 1 12/23/1913:54 74-97-5 ND ug/L 1.0 0.26 1 12/23/1913:54 75-27-4 ND ug/L 1.0 0.62 1 12/23/1913:54 75-25-2 ND ug/L 2.0 0.62 1 12/23/1913:54 74-83-9 ND ug/L 5.0 3.3 1 12/23/1913:54 78-93-3 ND ug/L 2.0 0.40 1 12/23/1913:54 75-15-0 ND ug/L 1.0 0.22 1 12/23/1913:54 56-23-5 ND ug/L 1.0 0.23 1 12/23/1913:54 108-90-7 ND ug/L 1.0 0.49 1 12/23/1913:54 75-00-3 ND ug/L 5.0 2.3 1 12/23/1913:54 67-66-3 ND ug/L 1.0 0.39 1 12/23/1913:54 74-87-3 ND ug/L 5.0 0.26 1 12/23/1913:54 96-12-8 ND ug/L 1.0 0.41 1 12/23/1913:54 124-48-1 ND ug/L 1.0 0.26 1 12/23/1913:54 106-93-4 ND ug/L 1.0 0.46 1 12/23/1913:54 74-95-3 ND ug/L 1.0 0.29 1 12/23/1913:54 95-50-1 0.64J ug/L 1.0 0.26 1 12/23/1913:54 106-46-7 ND ug/L 1.0 0.54 1 12/23/1913:54 110-57-6 ND ug/L 1.0 0.27 1 12/23/1913:54 75-34-3 0.79J ug/L 1.0 0.34 1 12/23/1913:54 107-06-2 ND ug/L 1.0 0.24 1 12/23/1913:54 75-35-4 ND ug/L 1.0 0.29 1 12/23/1913:54 156-59-2 ND ug/L 1.0 0.25 1 12/23/1913:54 156-60-5 ND ug/L 1.0 0.19 1 12/23/1913:54 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: LAGOON Lab ID: 92457256004 Collected: 12/11/19 16:35 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 5210B BOD, 5 day BOD, 5 day 9040 pH pH at 25 Degrees C 300.0 IC anions 48hr Nitrate as N Sulfate 365.1 Phosphorus, Total Phosphorus 5220D COD Chemical Oxygen Demand Date: 12/31/2019 01:42 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.30 1 12/23/1913:54 10061-01-5 ND ug/L 1.0 0.31 1 12/23/1913:54 10061-02-6 ND ug/L 150 56.2 1 12/23/1913:54 123-91-1 ND ug/L 1.0 0.26 1 12/23/1913:54 100-41-4 ND ug/L 5.0 0.57 1 12/23/1913:54 591-78-6 ND ug/L 20.0 12.5 1 12/23/1913:54 74-88-4 ND ug/L 5.0 3.7 1 12/23/1913:54 75-09-2 ND ug/L 5.0 4.5 1 12/23/1913:54 108-10-1 ND ug/L 1.0 0.27 1 12/23/1913:54 100-42-5 ND ug/L 1.0 0.34 1 12/23/1913:54 630-20-6 ND ug/L 1.0 0.22 1 12/23/1913:54 79-34-5 ND ug/L 1.0 0.16 1 12/23/1913:54 127-18-4 ND ug/L 1.0 0.24 1 12/23/1913:54 108-88-3 ND ug/L 1.0 0.18 1 12/23/1913:54 71-55-6 ND ug/L 1.0 0.24 1 12/23/1913:54 79-00-5 ND ug/L 1.0 0.22 1 12/23/1913:54 79-01-6 ND ug/L 1.0 0.31 1 12/23/1913:54 75-69-4 ND ug/L 1.0 0.35 1 12/23/1913:54 96-18-4 ND ug/L 2.0 1.4 1 12/23/1913:54 108-05-4 ND ug/L 1.0 0.24 1 12/23/1913:54 75-01-4 ND ug/L 1.0 0.63 1 12/23/1913:54 1330-20-7 98 % 70-130 1 12/23/1913:54 460-00-4 98 % 70-130 1 12/23/1913:54 17060-07-0 100 % 70-130 1 12/23/1913:54 2037-26-5 Analytical Method: SM 521OB-2011 ND ug/L 2000 2000 1 12/13/19 05:01 12/18/19 00:44 Analytical Method: EPA 9040C 7.5 Std. Units 0.10 0.10 1 12/22/19 18:29 Analytical Method: EPA 300.0 Rev 2.1 1993 ND mg/L 0.10 0.060 1 12/13/1912:52 14797-55-8 12.9 mg/L 1.0 0.50 1 12/13/1912:52 14808-79-8 Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 ND mg/L 0.050 0.025 1 12/15/1919:59 12/17/1913:02 7723-14-0 Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 118000 ug/L 25000 12500 1 12/19/1914:47 12/19/1918:42 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. B3 Page 25 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-1 Lab ID: 92457256005 Collected: 12/11/19 16:00 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/31/2019 01:42 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 12/18/19 01:30 12/20/19 02:24 7440-36-0 ND ug/L 10.0 4.7 1 12/18/19 01:30 12/20/19 02:24 7440-38-2 15.7 ug/L 5.0 1.0 1 12/18/19 01:30 12/20/19 02:24 7440-39-3 ND ug/L 1.0 0.20 1 12/18/19 01:30 12/20/19 02:24 7440-41-7 0.71J ug/L 1.0 0.40 1 12/18/19 01:30 12/20/19 02:24 7440-43-9 ND ug/L 5.0 1.0 1 12/18/19 01:30 12/20/19 02:24 7440-47-3 4.OJ ug/L 5.0 1.1 1 12/18/19 01:30 12/20/19 02:24 7440-48-4 3.8J ug/L 5.0 2.1 1 12/18/19 01:30 12/20/19 02:24 7440-50-8 ND ug/L 5.0 1.6 1 12/18/19 01:30 12/20/19 02:24 7439-92-1 6.8 ug/L 5.0 0.90 1 12/18/19 01:30 12/20/19 02:24 7440-02-0 ND ug/L 10.0 4.7 1 12/18/19 01:30 12/20/19 02:24 7782-49-2 ND ug/L 5.0 2.5 1 12/18/19 01:30 12/20/19 02:24 7440-22-4 ND ug/L 5.0 1.3 1 12/18/19 01:30 12/20/19 02:24 7440-62-2 15.2 ug/L 10.0 3.9 1 12/18/19 01:30 12/20/19 02:24 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A 0.084J ug/L 0.10 0.060 1 12/18/19 02:00 12/28/19 05:29 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/23/1914:12 67-64-1 ND ug/L 10.0 0.90 1 12/23/1914:12 107-13-1 ND ug/L 1.0 0.15 1 12/23/1914:12 71-43-2 ND ug/L 1.0 0.34 1 12/23/1914:12 74-97-5 ND ug/L 1.0 0.26 1 12/23/1914:12 75-27-4 ND ug/L 1.0 0.62 1 12/23/1914:12 75-25-2 ND ug/L 2.0 0.62 1 12/23/1914:12 74-83-9 ND ug/L 5.0 3.3 1 12/23/1914:12 78-93-3 ND ug/L 2.0 0.40 1 12/23/1914:12 75-15-0 ND ug/L 1.0 0.22 1 12/23/1914:12 56-23-5 ND ug/L 1.0 0.23 1 12/23/1914:12 108-90-7 ND ug/L 1.0 0.49 1 12/23/1914:12 75-00-3 ND ug/L 5.0 2.3 1 12/23/1914:12 67-66-3 ND ug/L 1.0 0.39 1 12/23/1914:12 74-87-3 ND ug/L 5.0 0.26 1 12/23/1914:12 96-12-8 ND ug/L 1.0 0.41 1 12/23/1914:12 124-48-1 ND ug/L 1.0 0.26 1 12/23/1914:12 106-93-4 ND ug/L 1.0 0.46 1 12/23/1914:12 74-95-3 ND ug/L 1.0 0.29 1 12/23/1914:12 95-50-1 ND ug/L 1.0 0.26 1 12/23/1914:12 106-46-7 ND ug/L 1.0 0.54 1 12/23/1914:12 110-57-6 ND ug/L 1.0 0.27 1 12/23/1914:12 75-34-3 ND ug/L 1.0 0.34 1 12/23/1914:12 107-06-2 ND ug/L 1.0 0.24 1 12/23/1914:12 75-35-4 ND ug/L 1.0 0.29 1 12/23/1914:12 156-59-2 ND ug/L 1.0 0.25 1 12/23/1914:12 156-60-5 ND ug/L 1.0 0.19 1 12/23/1914:12 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 26 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-1 Lab ID: 92457256005 Collected: 12/11/19 16:00 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/23/19 14:12 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/23/19 14:12 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/23/19 14:12 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/23/19 14:12 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/23/19 14:12 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/23/19 14:12 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/23/19 14:12 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/23/19 14:12 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/23/19 14:12 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/23/19 14:12 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/23/19 14:12 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/23/19 14:12 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/23/19 14:12 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/23/19 14:12 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/23/19 14:12 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/23/19 14:12 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/23/19 14:12 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/23/19 14:12 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/23/19 14:12 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/23/19 14:12 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/23/19 14:12 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 102 % 70-130 1 12/23/19 14:12 460-00-4 1,2-Dichloroethane-d4 (S) 100 % 70-130 1 12/23/19 14:12 17060-07-0 Toluene-d8 (S) 99 % 70-130 1 12/23/19 14:12 2037-26-5 Date: 12/31/2019 01:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-3R Lab ID: 92457256006 Collected: 12/11/19 16:00 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/31/2019 01:42 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 12/18/19 01:30 12/20/19 02:27 7440-36-0 ND ug/L 10.0 4.7 1 12/18/19 01:30 12/20/19 02:27 7440-38-2 47.6 ug/L 5.0 1.0 1 12/18/19 01:30 12/20/19 02:27 7440-39-3 ND ug/L 1.0 0.20 1 12/18/19 01:30 12/20/19 02:27 7440-41-7 0.97J ug/L 1.0 0.40 1 12/18/19 01:30 12/20/19 02:27 7440-43-9 ND ug/L 5.0 1.0 1 12/18/19 01:30 12/20/19 02:27 7440-47-3 ND ug/L 5.0 1.1 1 12/18/19 01:30 12/20/19 02:27 7440-48-4 ND ug/L 5.0 2.1 1 12/18/19 01:30 12/20/19 02:27 7440-50-8 ND ug/L 5.0 1.6 1 12/18/19 01:30 12/20/19 02:27 7439-92-1 2.6J ug/L 5.0 0.90 1 12/18/19 01:30 12/20/19 02:27 7440-02-0 ND ug/L 10.0 4.7 1 12/18/19 01:30 12/20/19 02:27 7782-49-2 ND ug/L 5.0 2.5 1 12/18/19 01:30 12/20/19 02:27 7440-22-4 ND ug/L 5.0 1.3 1 12/18/19 01:30 12/20/19 02:27 7440-62-2 4.2J ug/L 10.0 3.9 1 12/18/19 01:30 12/20/19 02:27 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/18/19 02:00 12/28/19 05:33 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/23/1914:30 67-64-1 ND ug/L 10.0 0.90 1 12/23/1914:30 107-13-1 ND ug/L 1.0 0.15 1 12/23/1914:30 71-43-2 ND ug/L 1.0 0.34 1 12/23/1914:30 74-97-5 ND ug/L 1.0 0.26 1 12/23/1914:30 75-27-4 ND ug/L 1.0 0.62 1 12/23/1914:30 75-25-2 ND ug/L 2.0 0.62 1 12/23/1914:30 74-83-9 ND ug/L 5.0 3.3 1 12/23/1914:30 78-93-3 ND ug/L 2.0 0.40 1 12/23/1914:30 75-15-0 ND ug/L 1.0 0.22 1 12/23/1914:30 56-23-5 ND ug/L 1.0 0.23 1 12/23/1914:30 108-90-7 ND ug/L 1.0 0.49 1 12/23/1914:30 75-00-3 ND ug/L 5.0 2.3 1 12/23/1914:30 67-66-3 ND ug/L 1.0 0.39 1 12/23/1914:30 74-87-3 ND ug/L 5.0 0.26 1 12/23/1914:30 96-12-8 ND ug/L 1.0 0.41 1 12/23/1914:30 124-48-1 ND ug/L 1.0 0.26 1 12/23/1914:30 106-93-4 ND ug/L 1.0 0.46 1 12/23/1914:30 74-95-3 ND ug/L 1.0 0.29 1 12/23/1914:30 95-50-1 ND ug/L 1.0 0.26 1 12/23/1914:30 106-46-7 ND ug/L 1.0 0.54 1 12/23/1914:30 110-57-6 1.3 ug/L 1.0 0.27 1 12/23/1914:30 75-34-3 ND ug/L 1.0 0.34 1 12/23/1914:30 107-06-2 ND ug/L 1.0 0.24 1 12/23/1914:30 75-35-4 1.9 ug/L 1.0 0.29 1 12/23/1914:30 156-59-2 ND ug/L 1.0 0.25 1 12/23/1914:30 156-60-5 ND ug/L 1.0 0.19 1 12/23/1914:30 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 28 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-3R Lab ID: 92457256006 Collected: 12/11/19 16:00 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/23/19 14:30 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/23/19 14:30 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/23/19 14:30 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/23/19 14:30 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/23/19 14:30 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/23/19 14:30 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/23/19 14:30 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/23/19 14:30 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/23/19 14:30 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/23/19 14:30 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/23/19 14:30 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/23/19 14:30 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/23/19 14:30 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/23/19 14:30 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/23/19 14:30 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/23/19 14:30 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/23/19 14:30 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/23/19 14:30 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/23/19 14:30 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/23/19 14:30 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/23/19 14:30 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 102 % 70-130 1 12/23/19 14:30 460-00-4 1,2-Dichloroethane-d4 (S) 98 % 70-130 1 12/23/19 14:30 17060-07-0 Toluene-d8 (S) 101 % 70-130 1 12/23/19 14:30 2037-26-5 Date: 12/31/2019 01:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 29 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-4S Lab ID: 92457256007 Collected: 12/11/19 09:36 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/31/2019 01:42 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 12/26/1917:06 12/27/1912:00 7440-36-0 ND ug/L 10.0 4.7 1 12/26/1917:06 12/27/1912:00 7440-38-2 41.3 ug/L 5.0 1.0 1 12/26/1917:06 12/27/1912:00 7440-39-3 ND ug/L 1.0 0.20 1 12/26/1917:06 12/27/1912:00 7440-41-7 ND ug/L 1.0 0.40 1 12/26/1917:06 12/27/1912:00 7440-43-9 ND ug/L 5.0 1.0 1 12/26/1917:06 12/27/1912:00 7440-47-3 ND ug/L 5.0 1.1 1 12/26/1917:06 12/27/1912:00 7440-48-4 ND ug/L 5.0 2.1 1 12/26/1917:06 12/27/1912:00 7440-50-8 ND ug/L 5.0 1.6 1 12/26/1917:06 12/27/1912:00 7439-92-1 0.93J ug/L 5.0 0.90 1 12/26/1917:06 12/27/1912:00 7440-02-0 ND ug/L 10.0 4.7 1 12/26/1917:06 12/27/1912:00 7782-49-2 ND ug/L 5.0 2.5 1 12/26/1917:06 12/27/1912:00 7440-22-4 ND ug/L 5.0 1.3 1 12/26/1917:06 12/27/1912:00 7440-62-2 4.2J ug/L 10.0 3.9 1 12/26/1917:06 12/27/1912:00 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/26/1917:06 12/30/1919:17 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/23/1914:47 67-64-1 ND ug/L 10.0 0.90 1 12/23/1914:47 107-13-1 ND ug/L 1.0 0.15 1 12/23/1914:47 71-43-2 ND ug/L 1.0 0.34 1 12/23/1914:47 74-97-5 ND ug/L 1.0 0.26 1 12/23/1914:47 75-27-4 ND ug/L 1.0 0.62 1 12/23/1914:47 75-25-2 ND ug/L 2.0 0.62 1 12/23/1914:47 74-83-9 ND ug/L 5.0 3.3 1 12/23/1914:47 78-93-3 ND ug/L 2.0 0.40 1 12/23/1914:47 75-15-0 ND ug/L 1.0 0.22 1 12/23/1914:47 56-23-5 ND ug/L 1.0 0.23 1 12/23/1914:47 108-90-7 ND ug/L 1.0 0.49 1 12/23/1914:47 75-00-3 ND ug/L 5.0 2.3 1 12/23/1914:47 67-66-3 ND ug/L 1.0 0.39 1 12/23/1914:47 74-87-3 ND ug/L 5.0 0.26 1 12/23/1914:47 96-12-8 ND ug/L 1.0 0.41 1 12/23/1914:47 124-48-1 ND ug/L 1.0 0.26 1 12/23/1914:47 106-93-4 ND ug/L 1.0 0.46 1 12/23/1914:47 74-95-3 ND ug/L 1.0 0.29 1 12/23/1914:47 95-50-1 ND ug/L 1.0 0.26 1 12/23/1914:47 106-46-7 ND ug/L 1.0 0.54 1 12/23/1914:47 110-57-6 ND ug/L 1.0 0.27 1 12/23/1914:47 75-34-3 ND ug/L 1.0 0.34 1 12/23/1914:47 107-06-2 ND ug/L 1.0 0.24 1 12/23/1914:47 75-35-4 0.52J ug/L 1.0 0.29 1 12/23/1914:47 156-59-2 ND ug/L 1.0 0.25 1 12/23/1914:47 156-60-5 ND ug/L 1.0 0.19 1 12/23/1914:47 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. M1,R1 Page 30 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-4S Lab ID: 92457256007 Collected: 12/11/19 09:36 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/23/19 14:47 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/23/19 14:47 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/23/19 14:47 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/23/19 14:47 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/23/19 14:47 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/23/19 14:47 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/23/19 14:47 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/23/19 14:47 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/23/19 14:47 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/23/19 14:47 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/23/19 14:47 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/23/19 14:47 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/23/19 14:47 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/23/19 14:47 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/23/19 14:47 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/23/19 14:47 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/23/19 14:47 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/23/19 14:47 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/23/19 14:47 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/23/19 14:47 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/23/19 14:47 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 102 % 70-130 1 12/23/19 14:47 460-00-4 1,2-Dichloroethane-d4 (S) 98 % 70-130 1 12/23/19 14:47 17060-07-0 Toluene-d8 (S) 103 % 70-130 1 12/23/19 14:47 2037-26-5 Date: 12/31/2019 01:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 31 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-41) Lab ID: 92457256008 Collected: 12/11/19 09:32 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/31/2019 01:42 PM Analytical Method: EPA 601 OD Preparation Method: EPA 301 OA ND ug/L 5.0 3.0 1 12/18/19 01:30 12/20/19 02:30 7440-36-0 ND ug/L 10.0 4.7 1 12/18/19 01:30 12/20/19 02:30 7440-38-2 52.5 ug/L 5.0 1.0 1 12/18/19 01:30 12/20/19 02:30 7440-39-3 ND ug/L 1.0 0.20 1 12/18/19 01:30 12/20/19 02:30 7440-41-7 4.6 ug/L 1.0 0.40 1 12/18/19 01:30 12/20/19 02:30 7440-43-9 ND ug/L 5.0 1.0 1 12/18/19 01:30 12/20/19 02:30 7440-47-3 ND ug/L 5.0 1.1 1 12/18/19 01:30 12/20/19 02:30 7440-48-4 5.OJ ug/L 5.0 2.1 1 12/18/19 01:30 12/20/19 02:30 7440-50-8 ND ug/L 5.0 1.6 1 12/18/19 01:30 12/20/19 02:30 7439-92-1 2.2J ug/L 5.0 0.90 1 12/18/19 01:30 12/20/19 02:30 7440-02-0 ND ug/L 10.0 4.7 1 12/18/19 01:30 12/20/19 02:30 7782-49-2 ND ug/L 5.0 2.5 1 12/18/19 01:30 12/20/19 02:30 7440-22-4 ND ug/L 5.0 1.3 1 12/18/19 01:30 12/20/19 02:30 7440-62-2 15.7 ug/L 10.0 3.9 1 12/18/19 01:30 12/20/19 02:30 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/18/19 02:00 12/28/19 05:37 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/23/1915:05 67-64-1 ND ug/L 10.0 0.90 1 12/23/1915:05 107-13-1 ND ug/L 1.0 0.15 1 12/23/1915:05 71-43-2 ND ug/L 1.0 0.34 1 12/23/1915:05 74-97-5 ND ug/L 1.0 0.26 1 12/23/1915:05 75-27-4 ND ug/L 1.0 0.62 1 12/23/1915:05 75-25-2 ND ug/L 2.0 0.62 1 12/23/1915:05 74-83-9 ND ug/L 5.0 3.3 1 12/23/1915:05 78-93-3 ND ug/L 2.0 0.40 1 12/23/1915:05 75-15-0 ND ug/L 1.0 0.22 1 12/23/1915:05 56-23-5 ND ug/L 1.0 0.23 1 12/23/1915:05 108-90-7 ND ug/L 1.0 0.49 1 12/23/1915:05 75-00-3 ND ug/L 5.0 2.3 1 12/23/1915:05 67-66-3 ND ug/L 1.0 0.39 1 12/23/1915:05 74-87-3 ND ug/L 5.0 0.26 1 12/23/1915:05 96-12-8 ND ug/L 1.0 0.41 1 12/23/1915:05 124-48-1 ND ug/L 1.0 0.26 1 12/23/1915:05 106-93-4 ND ug/L 1.0 0.46 1 12/23/1915:05 74-95-3 ND ug/L 1.0 0.29 1 12/23/1915:05 95-50-1 ND ug/L 1.0 0.26 1 12/23/1915:05 106-46-7 ND ug/L 1.0 0.54 1 12/23/1915:05 110-57-6 ND ug/L 1.0 0.27 1 12/23/1915:05 75-34-3 ND ug/L 1.0 0.34 1 12/23/1915:05 107-06-2 ND ug/L 1.0 0.24 1 12/23/1915:05 75-35-4 ND ug/L 1.0 0.29 1 12/23/1915:05 156-59-2 ND ug/L 1.0 0.25 1 12/23/1915:05 156-60-5 ND ug/L 1.0 0.19 1 12/23/1915:05 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 32 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-41) Lab ID: 92457256008 Collected: 12/11/19 09:32 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/23/19 15:05 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/23/19 15:05 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/23/19 15:05 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/23/19 15:05 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/23/19 15:05 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/23/19 15:05 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/23/19 15:05 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/23/19 15:05 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/23/19 15:05 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/23/19 15:05 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/23/19 15:05 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/23/19 15:05 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/23/19 15:05 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/23/19 15:05 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/23/19 15:05 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/23/19 15:05 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/23/19 15:05 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/23/19 15:05 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/23/19 15:05 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/23/19 15:05 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/23/19 15:05 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 101 % 70-130 1 12/23/19 15:05 460-00-4 1,2-Dichloroethane-d4 (S) 99 % 70-130 1 12/23/19 15:05 17060-07-0 Toluene-d8 (S) 103 % 70-130 1 12/23/19 15:05 2037-26-5 Date: 12/31/2019 01:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 33 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-5 Lab ID: 92457256009 Collected: 12/11/19 11:50 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/31/2019 01:42 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 12/18/19 01:30 12/20/19 02:33 7440-36-0 ND ug/L 10.0 4.7 1 12/18/19 01:30 12/20/19 02:33 7440-38-2 55.9 ug/L 5.0 1.0 1 12/18/19 01:30 12/20/19 02:33 7440-39-3 ND ug/L 1.0 0.20 1 12/18/19 01:30 12/20/19 02:33 7440-41-7 0.56J ug/L 1.0 0.40 1 12/18/19 01:30 12/20/19 02:33 7440-43-9 ND ug/L 5.0 1.0 1 12/18/19 01:30 12/20/19 02:33 7440-47-3 ND ug/L 5.0 1.1 1 12/18/19 01:30 12/20/19 02:33 7440-48-4 ND ug/L 5.0 2.1 1 12/18/19 01:30 12/20/19 02:33 7440-50-8 ND ug/L 5.0 1.6 1 12/18/19 01:30 12/20/19 02:33 7439-92-1 ND ug/L 5.0 0.90 1 12/18/19 01:30 12/20/19 02:33 7440-02-0 ND ug/L 10.0 4.7 1 12/18/19 01:30 12/20/19 02:33 7782-49-2 ND ug/L 5.0 2.5 1 12/18/19 01:30 12/20/19 02:33 7440-22-4 ND ug/L 5.0 1.3 1 12/18/19 01:30 12/20/19 02:33 7440-62-2 ND ug/L 10.0 3.9 1 12/18/19 01:30 12/20/19 02:33 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A 0.10 ug/L 0.10 0.060 1 12/18/19 02:00 12/28/19 05:41 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/23/1915:23 67-64-1 ND ug/L 10.0 0.90 1 12/23/1915:23 107-13-1 0.28J ug/L 1.0 0.15 1 12/23/1915:23 71-43-2 ND ug/L 1.0 0.34 1 12/23/1915:23 74-97-5 ND ug/L 1.0 0.26 1 12/23/1915:23 75-27-4 ND ug/L 1.0 0.62 1 12/23/1915:23 75-25-2 ND ug/L 2.0 0.62 1 12/23/1915:23 74-83-9 ND ug/L 5.0 3.3 1 12/23/1915:23 78-93-3 ND ug/L 2.0 0.40 1 12/23/1915:23 75-15-0 ND ug/L 1.0 0.22 1 12/23/1915:23 56-23-5 ND ug/L 1.0 0.23 1 12/23/1915:23 108-90-7 ND ug/L 1.0 0.49 1 12/23/1915:23 75-00-3 ND ug/L 5.0 2.3 1 12/23/1915:23 67-66-3 ND ug/L 1.0 0.39 1 12/23/1915:23 74-87-3 ND ug/L 5.0 0.26 1 12/23/1915:23 96-12-8 ND ug/L 1.0 0.41 1 12/23/1915:23 124-48-1 ND ug/L 1.0 0.26 1 12/23/1915:23 106-93-4 ND ug/L 1.0 0.46 1 12/23/1915:23 74-95-3 ND ug/L 1.0 0.29 1 12/23/1915:23 95-50-1 ND ug/L 1.0 0.26 1 12/23/1915:23 106-46-7 ND ug/L 1.0 0.54 1 12/23/1915:23 110-57-6 ND ug/L 1.0 0.27 1 12/23/1915:23 75-34-3 ND ug/L 1.0 0.34 1 12/23/1915:23 107-06-2 ND ug/L 1.0 0.24 1 12/23/1915:23 75-35-4 1.3 ug/L 1.0 0.29 1 12/23/1915:23 156-59-2 ND ug/L 1.0 0.25 1 12/23/1915:23 156-60-5 ND ug/L 1.0 0.19 1 12/23/1915:23 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 34 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-5 Lab ID: 92457256009 Collected: 12/11/19 11:50 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/23/19 15:23 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/23/19 15:23 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/23/19 15:23 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/23/19 15:23 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/23/19 15:23 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/23/19 15:23 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/23/19 15:23 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/23/19 15:23 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/23/19 15:23 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/23/19 15:23 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/23/19 15:23 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/23/19 15:23 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/23/19 15:23 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/23/19 15:23 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/23/19 15:23 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/23/19 15:23 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/23/19 15:23 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/23/19 15:23 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/23/19 15:23 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/23/19 15:23 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/23/19 15:23 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 101 % 70-130 1 12/23/19 15:23 460-00-4 1,2-Dichloroethane-d4 (S) 98 % 70-130 1 12/23/19 15:23 17060-07-0 Toluene-d8 (S) 102 % 70-130 1 12/23/19 15:23 2037-26-5 Date: 12/31/2019 01:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 35 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-8 Lab ID: 92457256010 Collected: 12/11/19 11:43 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/31/2019 01:42 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 12/18/19 01:30 12/20/19 02:36 7440-36-0 ND ug/L 10.0 4.7 1 12/18/19 01:30 12/20/19 02:36 7440-38-2 61.4 ug/L 5.0 1.0 1 12/18/19 01:30 12/20/19 02:36 7440-39-3 ND ug/L 1.0 0.20 1 12/18/19 01:30 12/20/19 02:36 7440-41-7 ND ug/L 1.0 0.40 1 12/18/19 01:30 12/20/19 02:36 7440-43-9 ND ug/L 5.0 1.0 1 12/18/19 01:30 12/20/19 02:36 7440-47-3 ND ug/L 5.0 1.1 1 12/18/19 01:30 12/20/19 02:36 7440-48-4 ND ug/L 5.0 2.1 1 12/18/19 01:30 12/20/19 02:36 7440-50-8 ND ug/L 5.0 1.6 1 12/18/19 01:30 12/20/19 02:36 7439-92-1 ND ug/L 5.0 0.90 1 12/18/19 01:30 12/20/19 02:36 7440-02-0 ND ug/L 10.0 4.7 1 12/18/19 01:30 12/20/19 02:36 7782-49-2 ND ug/L 5.0 2.5 1 12/18/19 01:30 12/20/19 02:36 7440-22-4 ND ug/L 5.0 1.3 1 12/18/19 01:30 12/20/19 02:36 7440-62-2 ND ug/L 10.0 3.9 1 12/18/19 01:30 12/20/19 02:36 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/18/19 02:00 12/28/19 05:45 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/23/1915:41 67-64-1 ND ug/L 10.0 0.90 1 12/23/1915:41 107-13-1 ND ug/L 1.0 0.15 1 12/23/1915:41 71-43-2 ND ug/L 1.0 0.34 1 12/23/1915:41 74-97-5 ND ug/L 1.0 0.26 1 12/23/1915:41 75-27-4 ND ug/L 1.0 0.62 1 12/23/1915:41 75-25-2 ND ug/L 2.0 0.62 1 12/23/1915:41 74-83-9 ND ug/L 5.0 3.3 1 12/23/1915:41 78-93-3 ND ug/L 2.0 0.40 1 12/23/1915:41 75-15-0 ND ug/L 1.0 0.22 1 12/23/1915:41 56-23-5 ND ug/L 1.0 0.23 1 12/23/1915:41 108-90-7 ND ug/L 1.0 0.49 1 12/23/1915:41 75-00-3 ND ug/L 5.0 2.3 1 12/23/1915:41 67-66-3 ND ug/L 1.0 0.39 1 12/23/1915:41 74-87-3 ND ug/L 5.0 0.26 1 12/23/1915:41 96-12-8 ND ug/L 1.0 0.41 1 12/23/1915:41 124-48-1 ND ug/L 1.0 0.26 1 12/23/1915:41 106-93-4 ND ug/L 1.0 0.46 1 12/23/1915:41 74-95-3 ND ug/L 1.0 0.29 1 12/23/1915:41 95-50-1 ND ug/L 1.0 0.26 1 12/23/1915:41 106-46-7 ND ug/L 1.0 0.54 1 12/23/1915:41 110-57-6 ND ug/L 1.0 0.27 1 12/23/1915:41 75-34-3 ND ug/L 1.0 0.34 1 12/23/1915:41 107-06-2 ND ug/L 1.0 0.24 1 12/23/1915:41 75-35-4 ND ug/L 1.0 0.29 1 12/23/1915:41 156-59-2 ND ug/L 1.0 0.25 1 12/23/1915:41 156-60-5 ND ug/L 1.0 0.19 1 12/23/1915:41 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 36 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-8 Lab ID: 92457256010 Collected: 12/11/19 11:43 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/23/19 15:41 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/23/19 15:41 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/23/19 15:41 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/23/19 15:41 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/23/19 15:41 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/23/19 15:41 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/23/19 15:41 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/23/19 15:41 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/23/19 15:41 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/23/19 15:41 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/23/19 15:41 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/23/19 15:41 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/23/19 15:41 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/23/19 15:41 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/23/19 15:41 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/23/19 15:41 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/23/19 15:41 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/23/19 15:41 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/23/19 15:41 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/23/19 15:41 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/23/19 15:41 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 101 % 70-130 1 12/23/19 15:41 460-00-4 1,2-Dichloroethane-d4 (S) 97 % 70-130 1 12/23/19 15:41 17060-07-0 Toluene-d8 (S) 101 % 70-130 1 12/23/19 15:41 2037-26-5 Date: 12/31/2019 01:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 37 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-91) Lab ID: 92457256011 Collected: 12/11/19 10:59 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/31/2019 01:42 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 12/18/19 01:18 12/20/19 08:57 7440-36-0 ND ug/L 10.0 4.7 1 12/18/19 01:18 12/20/19 08:57 7440-38-2 35.7 ug/L 5.0 1.0 1 12/18/19 01:18 12/20/19 08:57 7440-39-3 ND ug/L 1.0 0.20 1 12/18/19 01:18 12/20/19 08:57 7440-41-7 1.2 ug/L 1.0 0.40 1 12/18/19 01:18 12/20/19 08:57 7440-43-9 ND ug/L 5.0 1.0 1 12/18/19 01:18 12/20/19 08:57 7440-47-3 ND ug/L 5.0 1.1 1 12/18/19 01:18 12/20/19 08:57 7440-48-4 2.6J ug/L 5.0 2.1 1 12/18/19 01:18 12/20/19 08:57 7440-50-8 ND ug/L 5.0 1.6 1 12/18/19 01:18 12/20/19 08:57 7439-92-1 1.3J ug/L 5.0 0.90 1 12/18/19 01:18 12/20/19 08:57 7440-02-0 ND ug/L 10.0 4.7 1 12/18/19 01:18 12/20/19 08:57 7782-49-2 ND ug/L 5.0 2.5 1 12/18/19 01:18 12/20/19 08:57 7440-22-4 ND ug/L 5.0 1.3 1 12/18/19 01:18 12/20/19 08:57 7440-62-2 5.7J ug/L 10.0 3.9 1 12/18/19 01:18 12/20/19 08:57 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/18/19 02:00 12/25/19 09:22 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/23/1915:59 67-64-1 ND ug/L 10.0 0.90 1 12/23/1915:59 107-13-1 ND ug/L 1.0 0.15 1 12/23/1915:59 71-43-2 ND ug/L 1.0 0.34 1 12/23/1915:59 74-97-5 ND ug/L 1.0 0.26 1 12/23/1915:59 75-27-4 ND ug/L 1.0 0.62 1 12/23/1915:59 75-25-2 ND ug/L 2.0 0.62 1 12/23/1915:59 74-83-9 ND ug/L 5.0 3.3 1 12/23/1915:59 78-93-3 ND ug/L 2.0 0.40 1 12/23/1915:59 75-15-0 ND ug/L 1.0 0.22 1 12/23/1915:59 56-23-5 ND ug/L 1.0 0.23 1 12/23/1915:59 108-90-7 ND ug/L 1.0 0.49 1 12/23/1915:59 75-00-3 ND ug/L 5.0 2.3 1 12/23/1915:59 67-66-3 ND ug/L 1.0 0.39 1 12/23/1915:59 74-87-3 ND ug/L 5.0 0.26 1 12/23/1915:59 96-12-8 ND ug/L 1.0 0.41 1 12/23/1915:59 124-48-1 ND ug/L 1.0 0.26 1 12/23/1915:59 106-93-4 ND ug/L 1.0 0.46 1 12/23/1915:59 74-95-3 ND ug/L 1.0 0.29 1 12/23/1915:59 95-50-1 ND ug/L 1.0 0.26 1 12/23/1915:59 106-46-7 ND ug/L 1.0 0.54 1 12/23/1915:59 110-57-6 ND ug/L 1.0 0.27 1 12/23/1915:59 75-34-3 ND ug/L 1.0 0.34 1 12/23/1915:59 107-06-2 ND ug/L 1.0 0.24 1 12/23/1915:59 75-35-4 0.96J ug/L 1.0 0.29 1 12/23/1915:59 156-59-2 ND ug/L 1.0 0.25 1 12/23/1915:59 156-60-5 ND ug/L 1.0 0.19 1 12/23/1915:59 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 38 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-91) Lab ID: 92457256011 Collected: 12/11/19 10:59 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/23/19 15:59 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/23/19 15:59 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/23/19 15:59 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/23/19 15:59 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/23/19 15:59 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/23/19 15:59 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/23/19 15:59 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/23/19 15:59 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/23/19 15:59 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/23/19 15:59 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/23/19 15:59 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/23/19 15:59 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/23/19 15:59 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/23/19 15:59 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/23/19 15:59 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/23/19 15:59 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/23/19 15:59 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/23/19 15:59 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/23/19 15:59 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/23/19 15:59 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/23/19 15:59 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 101 % 70-130 1 12/23/19 15:59 460-00-4 1,2-Dichloroethane-d4 (S) 98 % 70-130 1 12/23/19 15:59 17060-07-0 Toluene-d8 (S) 108 % 70-130 1 12/23/19 15:59 2037-26-5 Date: 12/31/2019 01:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 39 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-10 Lab ID: 92457256012 Collected: 12/11/19 10:30 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/31/2019 01:42 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 12/18/19 01:18 12/20/19 09:00 7440-36-0 ND ug/L 10.0 4.7 1 12/18/19 01:18 12/20/19 09:00 7440-38-2 42.2 ug/L 5.0 1.0 1 12/18/19 01:18 12/20/19 09:00 7440-39-3 ND ug/L 1.0 0.20 1 12/18/19 01:18 12/20/19 09:00 7440-41-7 ND ug/L 1.0 0.40 1 12/18/19 01:18 12/20/19 09:00 7440-43-9 ND ug/L 5.0 1.0 1 12/18/19 01:18 12/20/19 09:00 7440-47-3 ND ug/L 5.0 1.1 1 12/18/19 01:18 12/20/19 09:00 7440-48-4 ND ug/L 5.0 2.1 1 12/18/19 01:18 12/20/19 09:00 7440-50-8 ND ug/L 5.0 1.6 1 12/18/19 01:18 12/20/19 09:00 7439-92-1 2.4J ug/L 5.0 0.90 1 12/18/19 01:18 12/20/19 09:00 7440-02-0 ND ug/L 10.0 4.7 1 12/18/19 01:18 12/20/19 09:00 7782-49-2 ND ug/L 5.0 2.5 1 12/18/19 01:18 12/20/19 09:00 7440-22-4 ND ug/L 5.0 1.3 1 12/18/19 01:18 12/20/19 09:00 7440-62-2 ND ug/L 10.0 3.9 1 12/18/19 01:18 12/20/19 09:00 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/18/19 02:00 12/25/19 09:30 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/23/1916:17 67-64-1 ND ug/L 10.0 0.90 1 12/23/1916:17 107-13-1 1.5 ug/L 1.0 0.15 1 12/23/1916:17 71-43-2 ND ug/L 1.0 0.34 1 12/23/1916:17 74-97-5 ND ug/L 1.0 0.26 1 12/23/1916:17 75-27-4 ND ug/L 1.0 0.62 1 12/23/1916:17 75-25-2 ND ug/L 2.0 0.62 1 12/23/1916:17 74-83-9 ND ug/L 5.0 3.3 1 12/23/1916:17 78-93-3 ND ug/L 2.0 0.40 1 12/23/1916:17 75-15-0 ND ug/L 1.0 0.22 1 12/23/1916:17 56-23-5 ND ug/L 1.0 0.23 1 12/23/1916:17 108-90-7 ND ug/L 1.0 0.49 1 12/23/1916:17 75-00-3 ND ug/L 5.0 2.3 1 12/23/1916:17 67-66-3 ND ug/L 1.0 0.39 1 12/23/1916:17 74-87-3 ND ug/L 5.0 0.26 1 12/23/1916:17 96-12-8 ND ug/L 1.0 0.41 1 12/23/1916:17 124-48-1 ND ug/L 1.0 0.26 1 12/23/1916:17 106-93-4 ND ug/L 1.0 0.46 1 12/23/1916:17 74-95-3 ND ug/L 1.0 0.29 1 12/23/1916:17 95-50-1 ND ug/L 1.0 0.26 1 12/23/1916:17 106-46-7 ND ug/L 1.0 0.54 1 12/23/1916:17 110-57-6 ND ug/L 1.0 0.27 1 12/23/1916:17 75-34-3 ND ug/L 1.0 0.34 1 12/23/1916:17 107-06-2 ND ug/L 1.0 0.24 1 12/23/1916:17 75-35-4 1.7 ug/L 1.0 0.29 1 12/23/1916:17 156-59-2 ND ug/L 1.0 0.25 1 12/23/1916:17 156-60-5 ND ug/L 1.0 0.19 1 12/23/1916:17 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 40 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-10 Lab ID: 92457256012 Collected: 12/11/19 10:30 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/23/19 16:17 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/23/19 16:17 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/23/19 16:17 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/23/19 16:17 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/23/19 16:17 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/23/19 16:17 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/23/19 16:17 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/23/19 16:17 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/23/19 16:17 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/23/19 16:17 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/23/19 16:17 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/23/19 16:17 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/23/19 16:17 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/23/19 16:17 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/23/19 16:17 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/23/19 16:17 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/23/19 16:17 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/23/19 16:17 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/23/19 16:17 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/23/19 16:17 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/23/19 16:17 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 101 % 70-130 1 12/23/19 16:17 460-00-4 1,2-Dichloroethane-d4 (S) 99 % 70-130 1 12/23/19 16:17 17060-07-0 Toluene-d8 (S) 98 % 70-130 1 12/23/19 16:17 2037-26-5 Date: 12/31/2019 01:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 41 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-12 Lab ID: 92457256013 Collected: 12/11/19 10:23 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/31/2019 01:42 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 12/18/19 01:18 12/20/19 09:03 7440-36-0 ND ug/L 10.0 4.7 1 12/18/19 01:18 12/20/19 09:03 7440-38-2 14.1 ug/L 5.0 1.0 1 12/18/19 01:18 12/20/19 09:03 7440-39-3 ND ug/L 1.0 0.20 1 12/18/19 01:18 12/20/19 09:03 7440-41-7 1.6 ug/L 1.0 0.40 1 12/18/19 01:18 12/20/19 09:03 7440-43-9 ND ug/L 5.0 1.0 1 12/18/19 01:18 12/20/19 09:03 7440-47-3 ND ug/L 5.0 1.1 1 12/18/19 01:18 12/20/19 09:03 7440-48-4 ND ug/L 5.0 2.1 1 12/18/19 01:18 12/20/19 09:03 7440-50-8 ND ug/L 5.0 1.6 1 12/18/19 01:18 12/20/19 09:03 7439-92-1 2.8J ug/L 5.0 0.90 1 12/18/19 01:18 12/20/19 09:03 7440-02-0 ND ug/L 10.0 4.7 1 12/18/19 01:18 12/20/19 09:03 7782-49-2 ND ug/L 5.0 2.5 1 12/18/19 01:18 12/20/19 09:03 7440-22-4 ND ug/L 5.0 1.3 1 12/18/19 01:18 12/20/19 09:03 7440-62-2 5.4J ug/L 10.0 3.9 1 12/18/19 01:18 12/20/19 09:03 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/18/19 02:00 12/25/19 09:34 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/23/1916:34 67-64-1 ND ug/L 10.0 0.90 1 12/23/1916:34 107-13-1 ND ug/L 1.0 0.15 1 12/23/1916:34 71-43-2 ND ug/L 1.0 0.34 1 12/23/1916:34 74-97-5 ND ug/L 1.0 0.26 1 12/23/1916:34 75-27-4 ND ug/L 1.0 0.62 1 12/23/1916:34 75-25-2 ND ug/L 2.0 0.62 1 12/23/1916:34 74-83-9 ND ug/L 5.0 3.3 1 12/23/1916:34 78-93-3 ND ug/L 2.0 0.40 1 12/23/1916:34 75-15-0 ND ug/L 1.0 0.22 1 12/23/1916:34 56-23-5 ND ug/L 1.0 0.23 1 12/23/1916:34 108-90-7 ND ug/L 1.0 0.49 1 12/23/1916:34 75-00-3 ND ug/L 5.0 2.3 1 12/23/1916:34 67-66-3 ND ug/L 1.0 0.39 1 12/23/1916:34 74-87-3 ND ug/L 5.0 0.26 1 12/23/1916:34 96-12-8 ND ug/L 1.0 0.41 1 12/23/1916:34 124-48-1 ND ug/L 1.0 0.26 1 12/23/1916:34 106-93-4 ND ug/L 1.0 0.46 1 12/23/1916:34 74-95-3 ND ug/L 1.0 0.29 1 12/23/1916:34 95-50-1 ND ug/L 1.0 0.26 1 12/23/1916:34 106-46-7 ND ug/L 1.0 0.54 1 12/23/1916:34 110-57-6 ND ug/L 1.0 0.27 1 12/23/1916:34 75-34-3 ND ug/L 1.0 0.34 1 12/23/1916:34 107-06-2 ND ug/L 1.0 0.24 1 12/23/1916:34 75-35-4 ND ug/L 1.0 0.29 1 12/23/1916:34 156-59-2 ND ug/L 1.0 0.25 1 12/23/1916:34 156-60-5 ND ug/L 1.0 0.19 1 12/23/1916:34 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 42 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Sample: MW-12 Lab ID: 92457256013 Collected: 12/11/19 10:23 Received: 12/12/19 15:33 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/23/19 16:34 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/23/19 16:34 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/23/19 16:34 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/23/19 16:34 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/23/19 16:34 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/23/19 16:34 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/23/19 16:34 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/23/19 16:34 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/23/19 16:34 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/23/19 16:34 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/23/19 16:34 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/23/19 16:34 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/23/19 16:34 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/23/19 16:34 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/23/19 16:34 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/23/19 16:34 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/23/19 16:34 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/23/19 16:34 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/23/19 16:34 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/23/19 16:34 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/23/19 16:34 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 101 % 70-130 1 12/23/19 16:34 460-00-4 1,2-Dichloroethane-d4 (S) 100 % 70-130 1 12/23/19 16:34 17060-07-0 Toluene-d8 (S) 103 % 70-130 1 12/23/19 16:34 2037-26-5 Date: 12/31/2019 01:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 43 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 QC Batch: 1397177 Analysis Method: EPA 8151 QC Batch Method: 8151A Analysis Description: Chlorinated Herb. (GC) 8151 Associated Lab Samples: 92457256001, 92457256002, 92457256003 METHOD BLANK: R3483551-1 Matrix: Water Associated Lab Samples: 92457256001, 92457256002, 92457256003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 2,4-D ug/L ND 2.00 0.744 12/17/19 08:53 Dinoseb ug/L ND 2.00 0.795 12/17/19 08:53 2,4,5-T ug/L ND 2.00 0.843 12/17/19 08:53 2,4,5-TP (Silvex) ug/L ND 2.00 0.845 12/17/19 08:53 2,4-DCAA (S) % 26 14.0-158 12/17/19 08:53 LABORATORY CONTROL SAMPLE & LCSD: R3483551-2 R3483551-3 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 2,4-D ug/L 5.00 3.51 3.56 70.2 71.2 50.0-120 1.41 20 Dinoseb ug/L 5.00 3.87 3.85 77.4 77.0 36.0-134 0.518 20 2,4,5-T ug/L 5.00 4.13 4.08 82.6 81.6 54.0-120 1.22 20 2,4,5-TP (Silvex) ug/L 5.00 3.60 3.55 72.0 71.0 50.0-125 1.40 20 2,4-DCAA (S) % 25.4 25.2 14.0-158 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 QC Batch: 515772 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Associated Lab Samples: 92457256001, 92457256002, 92457256003 METHOD BLANK: 2763621 Matrix: Water Associated Lab Samples: 92457256001, 92457256002, 92457256003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.10 12/20/1912:03 LABORATORY CONTROL SAMPLE: 2763622 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.7 107 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2763623 2763624 MS MSD 92457350001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.6 2.7 100 103 75-125 3 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 QC Batch: 515402 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92457256001, 92457256002, 92457256003, 92457256004, 92457256005, 92457256006, 92457256008, 92457256009,92457256010 METHOD BLANK: 2761907 Matrix: Water Associated Lab Samples: 92457256001, 92457256002, 92457256003, 92457256004, 92457256005, 92457256006, 92457256008, 92457256009,92457256010 Parameter Units Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Cadmium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Lead ug/L Nickel ug/L Selenium ug/L Silver ug/L Tin ug/L Vanadium ug/L Zinc ug/L Blank Result Reporting Limit MDL Analyzed Qualifiers ND 5.0 3.0 12/20/19 01:02 ND 10.0 4.7 12/20/19 01:02 ND 5.0 1.0 12/20/19 01:02 ND 1.0 0.20 12/20/19 01:02 ND 1.0 0.40 12/20/19 01:02 ND 5.0 1.0 12/20/19 01:02 ND 5.0 1.1 12/20/19 01:02 ND 5.0 2.1 12/20/19 01:02 ND 5.0 1.6 12/20/19 01:02 ND 5.0 0.90 12/20/19 01:02 ND 10.0 4.7 12/20/19 01:02 ND 5.0 2.5 12/20/19 01:02 ND 5.0 1.6 12/20/19 01:02 ND 5.0 1.3 12/20/19 01:02 ND 10.0 3.9 12/20/19 01:02 LABORATORY CONTROL SAMPLE: Parameter 2761908 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 518 104 80-120 Arsenic ug/L 500 513 103 80-120 Barium ug/L 500 503 101 80-120 Beryllium ug/L 500 509 102 80-120 Cadmium ug/L 500 507 101 80-120 Chromium ug/L 500 502 100 80-120 Cobalt ug/L 500 510 102 80-120 Copper ug/L 500 513 103 80-120 Lead ug/L 500 510 102 80-120 Nickel ug/L 500 508 102 80-120 Selenium ug/L 500 507 101 80-120 Silver ug/L 250 254 101 80-120 Tin ug/L 500 518 104 80-120 Vanadium ug/L 500 507 101 80-120 Zinc ug/L 500 499 100 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 46 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Surry Co. Lined MSWLF 92457256 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2761909 2761910 MS MSD 92456912020 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 528 538 105 107 75-125 2 20 Arsenic ug/L ND 500 500 546 555 109 111 75-125 2 20 Barium ug/L 149 500 500 654 661 101 102 75-125 1 20 Beryllium ug/L ND 500 500 513 519 103 104 75-125 1 20 Cadmium ug/L ND 500 500 527 537 105 107 75-125 2 20 Chromium ug/L ND 500 500 509 509 102 102 75-125 0 20 Cobalt ug/L ND 500 500 502 513 100 103 75-125 2 20 Copper ug/L 2.3J 500 500 522 528 104 105 75-125 1 20 Lead ug/L ND 500 500 504 516 101 103 75-125 2 20 Nickel ug/L 17.1 500 500 516 523 100 101 75-125 1 20 Selenium ug/L ND 500 500 539 550 108 110 75-125 2 20 Silver ug/L ND 250 250 254 256 102 102 75-125 1 20 Tin ug/L ND 500 500 514 526 103 105 75-125 2 20 Vanadium ug/L ND 500 500 520 526 104 105 75-125 1 20 Zinc ug/L ND 500 500 504 511 100 102 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 47 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 QC Batch: 515403 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92457256011, 92457256012, 92457256013 METHOD BLANK: 2761911 Matrix: Associated Lab Samples: 92457256011, 92457256012, 92457256013 Blank Parameter Units Result Water Reporting Limit Antimony ug/L ND 5.0 Arsenic ug/L ND 10.0 Barium ug/L ND 5.0 Beryllium ug/L ND 1.0 Cadmium ug/L ND 1.0 Chromium ug/L ND 5.0 Cobalt ug/L ND 5.0 Copper ug/L ND 5.0 Lead ug/L ND 5.0 Nickel ug/L ND 5.0 Selenium ug/L ND 10.0 Silver ug/L ND 5.0 Vanadium ug/L ND 5.0 Zinc ug/L ND 10.0 MDL Analyzed 3.0 12/20/19 07:35 4.7 12/20/19 07:35 1.0 12/20/19 07:35 0.20 12/20/19 07:35 0.40 12/20/19 07:35 1.0 12/20/19 07:35 1.1 12/20/19 07:35 2.1 12/20/19 07:35 1.6 12/20/19 07:35 0.90 12/20/19 07:35 4.7 12/20/19 07:35 2.5 12/20/19 07:35 1.3 12/20/19 07:35 3.9 12/20/19 07:35 LABORATORY CONTROL SAMPLE: Parameter 2761912 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 501 100 80-120 Arsenic ug/L 500 502 100 80-120 Barium ug/L 500 470 94 80-120 Beryllium ug/L 500 491 98 80-120 Cadmium ug/L 500 488 98 80-120 Chromium ug/L 500 474 95 80-120 Cobalt ug/L 500 492 98 80-120 Copper ug/L 500 488 98 80-120 Lead ug/L 500 494 99 80-120 Nickel ug/L 500 485 97 80-120 Selenium ug/L 500 490 98 80-120 Silver ug/L 250 242 97 80-120 Vanadium ug/L 500 477 95 80-120 Zinc ug/L 500 482 96 80-120 Qualifiers Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2761913 2761914 MS MSD 92456981001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 506 507 101 101 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 48 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Surry Co. Lined MSWLF 92457256 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2761913 2761914 MS MSD 92456981001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L ND 500 500 512 511 102 101 75-125 0 20 Barium ug/L ND 500 500 494 497 99 99 75-125 0 20 Beryllium ug/L ND 500 500 500 503 100 101 75-125 1 20 Cadmium ug/L ND 500 500 513 514 103 103 75-125 0 20 Chromium ug/L ND 500 500 499 500 100 100 75-125 0 20 Cobalt ug/L ND 500 500 505 505 101 101 75-125 0 20 Copper ug/L ND 500 500 501 499 100 100 75-125 0 20 Lead ug/L ND 500 500 509 512 102 102 75-125 1 20 Nickel ug/L ND 500 500 505 505 101 101 75-125 0 20 Selenium ug/L ND 500 500 529 530 106 106 75-125 0 20 Silver ug/L ND 250 250 249 249 100 100 75-125 0 20 Vanadium ug/L ND 500 500 504 502 101 100 75-125 0 20 Zinc ug/L ND 500 500 504 506 101 101 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 49 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 QC Batch: 516818 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92457256007 METHOD BLANK: 2768522 Associated Lab Samples: 92457256007 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 5.0 3.0 12/27/1911:47 Arsenic ug/L ND 10.0 4.7 12/27/1911:47 Barium ug/L ND 5.0 1.0 12/27/1911:47 Beryllium ug/L ND 1.0 0.20 12/27/1911:47 Cadmium ug/L ND 1.0 0.40 12/27/1911:47 Chromium ug/L ND 5.0 1.0 12/27/1911:47 Cobalt ug/L ND 5.0 1.1 12/27/1911:47 Copper ug/L ND 5.0 2.1 12/27/1911:47 Lead ug/L ND 5.0 1.6 12/27/1911:47 Nickel ug/L ND 5.0 0.90 12/27/1911:47 Selenium ug/L ND 10.0 4.7 12/27/1911:47 Silver ug/L ND 5.0 2.5 12/27/1911:47 Vanadium ug/L ND 5.0 1.3 12/27/1911:47 Zinc ug/L ND 10.0 3.9 12/27/1911:47 LABORATORY CONTROL SAMPLE: Parameter 2768523 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 487 97 80-120 Arsenic ug/L 500 486 97 80-120 Barium ug/L 500 496 99 80-120 Beryllium ug/L 500 480 96 80-120 Cadmium ug/L 500 499 100 80-120 Chromium ug/L 500 492 98 80-120 Cobalt ug/L 500 489 98 80-120 Copper ug/L 500 485 97 80-120 Lead ug/L 500 492 98 80-120 Nickel ug/L 500 498 100 80-120 Selenium ug/L 500 478 96 80-120 Silver ug/L 250 242 97 80-120 Vanadium ug/L 500 474 95 80-120 Zinc ug/L 500 474 95 80-120 Qualifiers Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2768524 2768525 MS MSD 92457256007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 516 494 103 99 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 50 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Surry Co. Lined MSWLF 92457256 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2768524 2768525 MS MSD 92457256007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L ND 500 500 515 508 102 101 75-125 1 20 Barium ug/L 41.3 500 500 556 558 103 103 75-125 0 20 Beryllium ug/L ND 500 500 497 494 99 99 75-125 1 20 Cadmium ug/L ND 500 500 533 538 106 108 75-125 1 20 Chromium ug/L ND 500 500 513 520 103 104 75-125 1 20 Cobalt ug/L ND 500 500 508 511 102 102 75-125 1 20 Copper ug/L ND 500 500 503 503 100 100 75-125 0 20 Lead ug/L ND 500 500 514 516 103 103 75-125 0 20 Nickel ug/L 0.93J 500 500 520 523 104 104 75-125 0 20 Selenium ug/L ND 500 500 530 521 105 104 75-125 2 20 Silver ug/L ND 250 250 250 166 100 67 75-125 40 20 M1,R1 Vanadium ug/L ND 500 500 496 499 99 100 75-125 1 20 Zinc ug/L 4.2J 500 500 611 516 121 102 75-125 17 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 51 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 QC Batch: 515405 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92457256011, 92457256012, 92457256013 METHOD BLANK: 2761919 Matrix: Water Associated Lab Samples: 92457256011, 92457256012, 92457256013 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 12/25/19 06:58 LABORATORY CONTROL SAMPLE: 2761920 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10.1 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2761921 2761922 MS MSD 92456986001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 10.3 10.4 102 103 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 52 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 QC Batch: 515406 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92457256001, 92457256002, 92457256003, 92457256004, 92457256005, 92457256006, 92457256008, 92457256009,92457256010 METHOD BLANK: 2761923 Matrix: Water Associated Lab Samples: 92457256001, 92457256002, 92457256003, 92457256004, 92457256005, 92457256006, 92457256008, 92457256009,92457256010 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 12/27/1917:43 LABORATORY CONTROL SAMPLE: 2761924 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10.4 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2761925 2761926 MS MSD 92456912021 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L 0.079J 10 10 11.0 11.0 109 109 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 53 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 QC Batch: 516819 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92457256007 METHOD BLANK: 2768527 Matrix: Water Associated Lab Samples: 92457256007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 12/30/1915:34 LABORATORY CONTROL SAMPLE: 2768528 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2768529 2768530 MS MSD 92457590015 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L 0.15 10 10 10.4 10.2 102 101 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 54 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 QC Batch: 516391 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Associated Lab Samples: 92457256001, 92457256002, 92457256003, 92457256004, 92457256005, 92457256006, 92457256007, 92457256008,92457256009,92457256010,92457256011,92457256012,92457256013 METHOD BLANK: 2766744 Matrix: Water Associated Lab Samples: 92457256001, 92457256002, 92457256003, 92457256004, 92457256005, 92457256006, 92457256007, 92457256008,92457256009,92457256010,92457256011,92457256012,92457256013 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 12/23/19 12:07 1,1,1-Trichloroethane ug/L ND 1.0 0.18 12/23/19 12:07 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 12/23/19 12:07 1,1,2-Trichloroethane ug/L ND 1.0 0.24 12/23/19 12:07 1,1-Dichloroethane ug/L ND 1.0 0.27 12/23/19 12:07 1,1-Dichloroethene ug/L ND 1.0 0.24 12/23/19 12:07 1,1-Dichloropropene ug/L ND 1.0 0.21 12/23/19 12:07 1,2,3-Trichlorobenzene ug/L ND 1.0 0.34 12/23/19 12:07 1,2,3-Trichloropropane ug/L ND 1.0 0.35 12/23/19 12:07 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 12/23/19 12:07 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 12/23/19 12:07 1,2-Dichlorobenzene ug/L ND 1.0 0.29 12/23/19 12:07 1,2-Dichloroethane ug/L ND 1.0 0.34 12/23/19 12:07 1,2-Dichloropropane ug/L ND 1.0 0.19 12/23/19 12:07 1,3-Dichloropropane ug/L ND 1.0 0.16 12/23/19 12:07 1,4-Dichlorobenzene ug/L ND 1.0 0.26 12/23/19 12:07 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 12/23/19 12:07 2,2-Dichloropropane ug/L ND 1.0 0.27 12/23/19 12:07 2-Butanone (MEK) ug/L ND 5.0 3.3 12/23/19 12:07 2-Hexanone ug/L ND 5.0 0.57 12/23/19 12:07 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 12/23/19 12:07 Acetone ug/L ND 25.0 6.2 12/23/19 12:07 Acetonitrile ug/L ND 50.0 30.4 12/23/19 12:07 Acrolein ug/L ND 10.0 2.7 12/23/19 12:07 Acrylonitrile ug/L ND 10.0 0.90 12/23/19 12:07 Allyl chloride ug/L ND 2.0 0.28 12/23/19 12:07 Benzene ug/L ND 1.0 0.15 12/23/19 12:07 Bromochloromethane ug/L ND 1.0 0.34 12/23/19 12:07 Bromodichloromethane ug/L ND 1.0 0.26 12/23/19 12:07 Bromoform ug/L ND 1.0 0.62 12/23/19 12:07 Bromomethane ug/L ND 2.0 0.62 12/23/19 12:07 Carbon disulfide ug/L ND 2.0 0.40 12/23/19 12:07 Carbon tetrachloride ug/L ND 1.0 0.22 12/23/19 12:07 Chlorobenzene ug/L ND 1.0 0.23 12/23/19 12:07 Chloroethane ug/L ND 1.0 0.49 12/23/19 12:07 Chloroform ug/L ND 5.0 2.3 12/23/19 12:07 Chloromethane ug/L ND 1.0 0.39 12/23/19 12:07 Chloroprene ug/L ND 5.0 1.7 12/23/19 12:07 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 12/23/19 12:07 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 12/23/19 12:07 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 55 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 METHOD BLANK: 2766744 Matrix: Water Associated Lab Samples: 92457256001, 92457256002, 92457256003, 92457256004, 92457256005, 92457256006, 92457256007, 92457256008,92457256009,92457256010,92457256011,92457256012,92457256013 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Dibromochloromethane ug/L ND 1.0 0.41 12/23/19 12:07 Dibromomethane ug/L ND 1.0 0.46 12/23/19 12:07 Dichlorodifluoromethane ug/L ND 1.0 0.23 12/23/19 12:07 Ethyl methacrylate ug/L ND 1.0 0.51 12/23/19 12:07 Ethylbenzene ug/L ND 1.0 0.26 12/23/19 12:07 Hexachloro-1,3-butadiene ug/L ND 1.0 0.44 12/23/19 12:07 lodomethane ug/L ND 20.0 12.5 12/23/19 12:07 Isobutanol ug/L ND 100 66.4 12/23/19 12:07 Methacrylonitrile ug/L ND 10.0 1.9 12/23/19 12:07 Methyl methacrylate ug/L ND 2.0 0.46 12/23/19 12:07 Methylene Chloride ug/L ND 5.0 3.7 12/23/19 12:07 Naphthalene ug/L ND 1.0 0.35 12/23/19 12:07 Propionitrile ug/L ND 20.0 1.8 12/23/19 12:07 Styrene ug/L ND 1.0 0.27 12/23/19 12:07 Tetrachloroethene ug/L ND 1.0 0.16 12/23/19 12:07 Toluene ug/L ND 1.0 0.24 12/23/19 12:07 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 12/23/19 12:07 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 12/23/19 12:07 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 12/23/19 12:07 Trichloroethene ug/L ND 1.0 0.22 12/23/19 12:07 Trichlorofluoromethane ug/L ND 1.0 0.31 12/23/19 12:07 Vinyl acetate ug/L ND 2.0 1.4 12/23/19 12:07 Vinyl chloride ug/L ND 1.0 0.24 12/23/19 12:07 Xylene (Total) ug/L ND 1.0 0.63 12/23/19 12:07 1,2-Dichloroethane-d4 (S) % 98 70-130 12/23/19 12:07 4-Bromofluorobenzene (S) % 102 70-130 12/23/19 12:07 Toluene-d8 (S) % 101 70-130 12/23/19 12:07 LABORATORY CONTROL SAMPLE: 2766745 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 51.1 102 70-130 1,1,1-Trichloroethane ug/L 50 45.2 90 70-130 1,1,2,2-Tetrachloroethane ug/L 50 49.7 99 70-130 1,1,2-Trichloroethane ug/L 50 48.3 97 70-130 1,1-Dichloroethane ug/L 50 47.1 94 70-130 1,1-Dichloroethene ug/L 50 47.0 94 70-130 1,1-Dichloropropene ug/L 50 51.2 102 70-130 1,2,3-Trichlorobenzene ug/L 50 56.0 112 70-130 1,2,3-Trichloropropane ug/L 50 50.1 100 70-130 1,2-Dibromo-3-chloropropane ug/L 50 49.4 99 70-130 1,2-Dibromoethane (EDB) ug/L 50 51.5 103 70-130 1,2-Dichlorobenzene ug/L 50 53.3 107 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 56 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 LABORATORY CONTROL SAMPLE: Parameter 2766745 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,2-Dichloroethane ug/L 50 45.5 91 70-130 1,2-Dichloropropane ug/L 50 50.3 101 70-130 1,3-Dichloropropane ug/L 50 52.4 105 70-131 1,4-Dichlorobenzene ug/L 50 53.1 106 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1010 101 59-169 2,2-Dichloropropane ug/L 50 49.1 98 69-130 2-Butanone (MEK) ug/L 100 99.7 100 64-135 2-Hexanone ug/L 100 96.3 96 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 94.5 95 70-130 Acetone ug/L 100 107 107 61-157 Acetonitrile ug/L 500 474 95 62-130 Acrolein ug/L 250 402 161 10-200 Acrylonitrile ug/L 250 235 94 61-143 Allyl chloride ug/L 50 45.9 92 70-130 Benzene ug/L 50 48.3 97 70-130 Bromochloromethane ug/L 50 45.4 91 70-130 Bromodichloromethane ug/L 50 45.9 92 70-130 Bromoform ug/L 50 46.2 92 70-130 Bromomethane ug/L 50 35.9 72 38-130 Carbon disulfide ug/L 50 49.9 100 68-130 Carbon tetrachloride ug/L 50 45.0 90 70-130 Chlorobenzene ug/L 50 51.9 104 70-130 Chloroethane ug/L 50 36.2 72 37-142 Chloroform ug/L 50 46.1 92 70-130 Chloromethane ug/L 50 40.4 81 48-130 Chloroprene ug/L 50 40.2 80 70-130 cis-1,2-Dichloroethene ug/L 50 46.6 93 70-130 cis-1,3-Dichloropropene ug/L 50 51.7 103 70-130 Dibromochloromethane ug/L 50 48.6 97 70-130 Dibromomethane ug/L 50 48.8 98 70-130 Dichlorodifluoromethane ug/L 50 50.1 100 53-134 Ethyl methacrylate ug/L 50 49.8 100 70-130 Ethylbenzene ug/L 50 48.8 98 70-130 Hexachloro-1,3-butadiene ug/L 50 55.9 112 68-132 lodomethane ug/L 100 73.6 74 40-130 Isobutanol ug/L 1000 869 87 44-144 Methacrylonitrile ug/L 500 463 93 66-130 Methyl methacrylate ug/L 50 45.8 92 69-130 Methylene Chloride ug/L 50 45.0 90 67-132 Naphthalene ug/L 50 53.6 107 70-130 Propionitrile ug/L 500 471 94 70-130 Styrene ug/L 50 51.3 103 70-130 Tetrachloroethene ug/L 50 49.7 99 69-130 Toluene ug/L 50 45.1 90 70-130 trans-1,2-Dichloroethene ug/L 50 47.7 95 70-130 trans- 1,3-Dichloropropene ug/L 50 49.9 100 70-130 trans-1,4-Dichloro-2-butene ug/L 50 52.2 104 35-189 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 57 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 LABORATORY CONTROL SAMPLE: Parameter 2766745 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Trichloroethene ug/L 50 49.7 99 70-130 Trichlorofluoromethane ug/L 50 44.9 90 63-130 Vinyl acetate ug/L 100 107 107 55-143 Vinyl chloride ug/L 50 50.6 101 70-131 Xylene (Total) ug/L 150 144 96 70-130 1,2-Dichloroethane-d4 (S) % 85 70-130 4-Bromofluorobenzene (S) % 97 70-130 Toluene-d8 (S) % 98 70-130 MATRIX SPIKE SAMPLE: Parameter 2766746 Units 92457589001 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 20.0 100 73-134 1,1,1-Trichloroethane ug/L ND 20 19.2 96 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 20.0 100 70-136 1,1,2-Trichloroethane ug/L ND 20 19.9 100 70-135 1,1-Dichloroethane ug/L ND 20 20.1 101 70-139 1,1-Dichloroethene ug/L ND 20 20.3 101 70-154 1,1-Dichloropropene ug/L ND 20 21.7 108 70-149 1,2,3-Trichlorobenzene ug/L ND 20 20.6 103 70-135 1,2,3-Trichloropropane ug/L ND 20 20.4 102 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 17.1 86 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 20.7 103 70-137 1,2-Dichlorobenzene ug/L ND 20 20.9 104 70-133 1,2-Dichloroethane ug/L ND 20 19.2 96 70-137 1,2-Dichloropropane ug/L ND 20 20.8 104 70-140 1,3-Dichloropropane ug/L ND 20 21.5 107 70-143 1,4-Dichlorobenzene ug/L ND 20 20.9 105 70-133 1,4-Dioxane (p-Dioxane) ug/L ND 400 393 98 53-168 2,2-Dichloropropane ug/L ND 20 20.7 103 61-148 2-Butanone (MEK) ug/L ND 40 38.7 97 60-139 2-Hexanone ug/L ND 40 35.5 89 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 35.7 89 65-135 Acetone ug/L ND 40 37.2 93 60-148 Acetonitrile ug/L ND 200 199 100 65-141 Acrolein ug/L ND 100 159 159 28-162 Acrylonitrile ug/L ND 100 96.4 96 64-147 Allyl chloride ug/L ND 20 20.6 103 70-133 Benzene ug/L ND 20 20.3 102 70-151 Bromochloromethane ug/L ND 20 19.6 98 70-141 Bromodichloromethane ug/L ND 20 18.6 93 70-138 Bromoform ug/L ND 20 16.4 82 63-130 Bromomethane ug/L ND 20 19.2 96 15-152 Carbon disulfide ug/L ND 20 20.9 105 69-149 Carbon tetrachloride ug/L ND 20 19.5 97 70-143 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 58 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 MATRIX SPIKE SAMPLE: Parameter 2766746 Units 92457589001 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers Chlorobenzene ug/L ND 20 21.6 108 70-138 Chloroethane ug/L ND 20 19.9 100 52-163 Chloroform ug/L ND 20 20.0 100 70-139 Chloromethane ug/L ND 20 17.0 85 41-139 Chloroprene ug/L ND 20 17.2 86 70-135 cis-1,2-Dichloroethene ug/L ND 20 19.6 98 70-141 cis-1,3-Dichloropropene ug/L ND 20 20.3 101 70-137 Dibromochloromethane ug/L ND 20 18.2 91 70-134 Dibromomethane ug/L ND 20 19.9 99 70-138 Dichlorodifluoromethane ug/L ND 20 20.1 101 47-155 Ethyl methacrylate ug/L ND 20 19.6 98 70-132 Ethylbenzene ug/L ND 20 20.6 103 66-153 Hexachloro-1,3-butadiene ug/L ND 20 21.0 105 65-149 lodomethane ug/L ND 40 20.5 51 20-138 Isobutanol ug/L ND 400 292 73 41-152 Methacrylonitrile ug/L ND 200 210 105 67-134 Methyl methacrylate ug/L ND 20 17.9 89 70-130 Methylene Chloride ug/L ND 20 20.2 101 42-159 Naphthalene ug/L ND 20 19.7 98 61-148 Propionitrile ug/L ND 200 190 95 70-131 Styrene ug/L ND 20 21.0 105 70-135 Tetrachloroethene ug/L ND 20 20.5 102 59-143 Toluene ug/L ND 20 18.9 95 59-148 trans-1,2-Dichloroethene ug/L ND 20 20.7 103 70-146 trans- 1,3-Dichloropropene ug/L ND 20 19.4 97 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 19.8 99 47-135 Trichloroethene ug/L ND 20 21.2 106 70-147 Trichlorofluoromethane ug/L ND 20 20.4 102 70-148 Vinyl acetate ug/L ND 40 40.8 102 49-151 Vinyl chloride ug/L ND 20 21.9 109 70-156 Xylene (Total) ug/L ND 60 60.3 100 63-158 1,2-Dichloroethane-d4 (S) % 90 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 97 70-130 SAMPLE DUPLICATE: 2766747 92457589006 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,1-Dichloropropene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 59 of 88 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 SAMPLE DUPLICATE: 2766747 Parameter Units 92457589006 Result Dup Result RPD Max RPD Qualifiers 1,2,3-Trichlorobenzene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,3-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 1,4-Dioxane (p-Dioxane) ug/L ND ND 30 2,2-Dichloropropane ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Acetonitrile ug/L ND ND 30 Acrolein ug/L ND ND 30 Acrylonitrile ug/L ND ND 30 Allyl chloride ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 30 Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 Chloroprene ug/L ND ND 30 cis-1,2-Dichloroethene ug/L ND ND 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Dichlorodifluoromethane ug/L ND ND 30 Ethyl methacrylate ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 Hexachloro-1,3-butadiene ug/L ND ND 30 lodomethane ug/L ND ND 30 Isobutanol ug/L ND ND 30 Methacrylonitrile ug/L ND ND 30 Methyl methacrylate ug/L ND ND 30 Methylene Chloride ug/L ND ND 30 Naphthalene ug/L ND ND 30 Propionitrile ug/L ND ND 30 Styrene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 60 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 SAMPLE DUPLICATE: 2766747 Parameter Units 92457589006 Result Dup Result Tetrachloroethene ug/L ND ND Toluene ug/L ND ND trans-1,2-Dichloroethene ug/L ND ND trans- 1,3-Dichloropropene ug/L ND ND trans-1,4-Dichloro-2-butene ug/L ND ND Trichloroethene ug/L ND ND Trichlorofluoromethane ug/L ND ND Vinyl acetate ug/L ND ND Vinyl chloride ug/L ND ND Xylene (Total) ug/L ND ND 1,2-Dichloroethane-d4 (S) % 100 95 4-Bromofluorobenzene (S) % 104 99 Toluene-d8(S) % 108 101 Max RPD RPD Qualifiers 30 30 30 30 30 30 30 30 30 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 61 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 QC Batch: 515456 Analysis Method: EPA 8081 B QC Batch Method: EPA 3510C Analysis Description: 8081 OC Pesticides Red Vol Associated Lab Samples: 92457256001, 92457256002, 92457256003 METHOD BLANK: 2762022 Matrix: Associated Lab Samples: 92457256001, 92457256002, 92457256003 Blank Parameter Units Result Water Reporting Limit MDL Analyzed Qualifiers 4,4'-DDD ug/L ND 0.050 0.0069 12/19/19 00:21 4,4'-DDE ug/L ND 0.050 0.0064 12/19/19 00:21 4,4'-DDT ug/L ND 0.050 0.018 12/19/19 00:21 Aldrin ug/L ND 0.050 0.022 12/19/19 00:21 alpha-BHC ug/L ND 0.050 0.019 12/19/19 00:21 beta-BHC ug/L ND 0.050 0.014 12/19/19 00:21 Chlordane (Technical) ug/L ND 0.20 0.20 12/19/19 00:21 delta-BHC ug/L ND 0.050 0.020 12/19/19 00:21 Dieldrin ug/L ND 0.050 0.0073 12/19/19 00:21 Endosulfan I ug/L ND 0.050 0.0094 12/19/19 00:21 Endosulfan 11 ug/L ND 0.050 0.0065 12/19/19 00:21 Endosulfan sulfate ug/L ND 0.050 0.0091 12/19/19 00:21 Endrin ug/L ND 0.050 0.0089 12/19/19 00:21 Endrin aldehyde ug/L ND 0.050 0.013 12/19/19 00:21 gamma-BHC (Lindane) ug/L ND 0.050 0.012 12/19/19 00:21 Heptachlor ug/L ND 0.050 0.016 12/19/19 00:21 Heptachlor epoxide ug/L ND 0.050 0.0097 12/19/19 00:21 Methoxychlor ug/L ND 0.15 0.033 12/19/19 00:21 Toxaphene ug/L ND 0.20 0.20 12/19/19 00:21 Decachlorobiphenyl (S) % 55 10-130 12/19/19 00:21 Tetrachloro-m-xylene (S) % 50 10-130 12/19/19 00:21 LABORATORY CONTROL SAMPLE: Parameter 2762023 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 4,4'-DDD ug/L 0.25 0.23 90 49-130 4,4'-DDE ug/L 0.25 0.21 83 56-130 4,4'-DDT ug/L 0.25 0.24 96 45-130 Aldrin ug/L 0.25 0.16 66 25-130 alpha-BHC ug/L 0.25 0.18 72 53-130 beta-BHC ug/L 0.25 0.25 99 46-130 delta-BHC ug/L 0.25 0.21 83 54-130 Dieldrin ug/L 0.25 0.22 87 54-130 Endosulfan I ug/L 0.25 0.21 85 43-130 Endosulfan II ug/L 0.25 0.24 95 64-130 Endosulfan sulfate ug/L 0.25 0.24 98 66-130 Endrin ug/L 0.25 0.22 86 56-130 Endrin aldehyde ug/L 0.25 0.20 80 59-130 gamma-BHC (Lindane) ug/L 0.25 0.19 78 57-130 Heptachlor ug/L 0.25 0.18 74 37-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 62 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 LABORATORY CONTROL SAMPLE: 2762023 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Heptachlor epoxide ug/L 0.25 0.21 86 56-130 Methoxychlor ug/L 0.75 0.76 101 46-130 Decachlorobiphenyl (S) % 113 10-130 Tetrachloro-m-xylene (S) % 61 10-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2762024 2762025 MS MSD 92452072004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 4,4'-DDD ug/L ND 0.25 0.25 0.29 0.070 117 28 28-130 122 30 R1 4,4'-DDE ug/L ND 0.25 0.25 0.26 0.051 102 20 26-130 134 30 M1,R1 4,4'-DDT ug/L ND 0.25 0.25 0.28 0.061 112 25 11-130 128 30 R1 Aldrin ug/L ND 0.25 0.25 0.20 0.036J 80 14 10-130 30 alpha-BHC ug/L ND 0.25 0.25 0.25 0.049J 100 20 27-130 30 M1 beta-BHC ug/L ND 0.25 0.25 0.31 0.072 125 29 15-130 125 30 R1 delta-BHC ug/L ND 0.25 0.25 0.28 0.057 110 23 44-130 131 30 M1,R1 Dieldrin ug/L ND 0.25 0.25 0.24 0.053 97 21 20-130 128 30 R1 Endosulfan I ug/L ND 0.25 0.25 0.23 0.052 93 21 10-139 127 30 R1 Endosulfan II ug/L ND 0.25 0.25 0.26 0.064 104 26 36-130 121 30 M1,R1 Endosulfan sulfate ug/L ND 0.25 0.25 0.28 0.069 112 28 45-130 121 30 M1,R1 Endrin ug/L ND 0.25 0.25 0.25 0.054 100 22 26-130 129 30 M1,R1 Endrin aldehyde ug/L ND 0.25 0.25 0.27 0.071 106 28 19-160 115 30 R1 gamma-BHC (Lindane) ug/L ND 0.25 0.25 0.22 0.046J 87 19 33-130 30 M1 Heptachlor ug/L ND 0.25 0.25 0.21 0.044J 83 18 25-130 30 M1 Heptachlor epoxide ug/L ND 0.25 0.25 0.25 0.055 101 22 18-130 128 30 R1 Methoxychlor ug/L ND 0.75 0.75 0.88 0.21 118 28 10-130 122 30 R1 Decachlorobiphenyl (S) % 96 19 10-130 Tetrachloro-m-xylene (S) % 66 15 10-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 63 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 QC Batch: 515053 Analysis Method: EPA 8082A QC Batch Method: EPA 351 OC Analysis Description: 8082 GCS PCB Associated Lab Samples: 92457256001, 92457256002, 92457256003 METHOD BLANK: 2760237 Matrix: Water Associated Lab Samples: 92457256001, 92457256002, 92457256003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers PCB-1016 (Aroclor 1016) ug/L ND 0.50 0.22 12/17/19 08:43 PCB-1221 (Aroclor 1221) ug/L ND 0.50 0.32 12/17/19 08:43 PCB-1232 (Aroclor 1232) ug/L ND 0.50 0.21 12/17/19 08:43 PCB-1242 (Aroclor 1242) ug/L ND 0.50 0.44 12/17/19 08:43 PCB-1248 (Aroclor 1248) ug/L ND 0.50 0.34 12/17/19 08:43 PCB-1254 (Aroclor 1254) ug/L ND 0.50 0.24 12/17/19 08:43 PCB-1260 (Aroclor 1260) ug/L ND 0.50 0.30 12/17/19 08:43 Decachlorobiphenyl (S) % 128 10-130 12/17/19 08:43 LABORATORY CONTROL SAMPLE: 2760238 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers PCB-1016 (Aroclor 1016) ug/L 5 5.0 100 41-130 PCB-1260 (Aroclor 1260) ug/L 5 5.2 104 42-130 Decachlorobiphenyl (S) % 136 10-130 SO MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2760239 2760240 MS MSD 92456714001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual PCB-1016 (Aroclor 1016) ug/L ND 5 5 4.5 3.3 90 66 15-130 30 30 PCB-1260 (Aroclor 1260) ug/L ND 5 5 5.3 4.4 106 88 10-130 19 30 Decachlorobiphenyl (S) % 132 111 10-130 SO Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 64 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 QC Batch: 515528 Analysis Method: EPA 8270E QC Batch Method: EPA 3510C Analysis Description: 8270E Water APP9 RV MSSV Associated Lab Samples: 92457256001, 92457256002, 92457256003 METHOD BLANK: 2762281 Matrix: Associated Lab Samples: 92457256001, 92457256002, 92457256003 Blank Parameter Units Result Water Reporting Limit MDL Analyzed 1,2,4,5-Tetrachlorobenzene ug/L ND 10.0 2.8 12/19/19 13:37 1,3,5-Trinitrobenzene ug/L ND 10.0 4.7 12/19/19 13:37 1,3-Dinitrobenzene ug/L ND 10.0 4.6 12/19/19 13:37 1,4-Naphthoquinone ug/L ND 5.0 4.4 12/19/19 13:37 1-Naphthalenamine ug/L ND 5.0 2.9 12/19/19 13:37 2,2'-Oxybis(1-chloropropane) ug/L ND 10.0 2.8 12/19/19 13:37 2,3,4,6-Tetrachlorophenol ug/L ND 10.0 1.4 12/19/19 13:37 2,4,5-Trichlorophenol ug/L ND 10.0 1.4 12/19/19 13:37 2,4,6-Trichlorophenol ug/L ND 10.0 1.5 12/19/19 13:37 2,4-Dichlorophenol ug/L ND 10.0 1.4 12/19/19 13:37 2,4-Dimethylphenol ug/L ND 10.0 1.4 12/19/19 13:37 2,4-Dinitrophenol ug/L ND 50.0 40.5 12/19/19 13:37 2,4-Dinitrotoluene ug/L ND 10.0 1.2 12/19/19 13:37 2,6-Dichlorophenol ug/L ND 10.0 6.0 12/19/19 13:37 2,6-Dinitrotoluene ug/L ND 10.0 1.4 12/19/19 13:37 2-Acetylaminofluorene ug/L ND 10.0 3.1 12/19/19 13:37 2-Chloronaphthalene ug/L ND 10.0 1.5 12/19/19 13:37 2-Chlorophenol ug/L ND 10.0 1.2 12/19/19 13:37 2-Methylnaphthalene ug/L ND 10.0 1.4 12/19/19 13:37 2-Methylphenol(o-Cresol) ug/L ND 10.0 1.2 12/19/19 13:37 2-Naphthalenamine ug/L ND 5.0 4.2 12/19/19 13:37 2-Nitroaniline ug/L ND 20.0 4.2 12/19/19 13:37 2-Nitrophenol ug/L ND 10.0 1.4 12/19/19 13:37 3&4-Methyl phenol (m&p Cresol) ug/L ND 10.0 1.2 12/19/19 13:37 3,3'-Dichlorobenzidine ug/L ND 20.0 3.0 12/19/19 13:37 3,3'-Dimethylbenzidine ug/L ND 20.0 10.8 12/19/19 13:37 3-Methylcholanthrene ug/L ND 10.0 5.7 12/19/19 13:37 3-Nitroaniline ug/L ND 20.0 2.3 12/19/19 13:37 4,6-Dinitro-2-methyl phenol ug/L ND 20.0 15.2 12/19/19 13:37 4-Aminobiphenyl ug/L ND 10.0 3.3 12/19/19 13:37 4-Bromophenylphenyl ether ug/L ND 10.0 1.6 12/19/19 13:37 4-ChIoro-3-methyl phenol ug/L ND 10.0 2.8 12/19/19 13:37 4-Chloroaniline ug/L ND 20.0 2.8 12/19/19 13:37 4-Chlorophenylphenyl ether ug/L ND 10.0 1.6 12/19/19 13:37 4-Nitroaniline ug/L ND 20.0 2.2 12/19/19 13:37 4-Nitrophenol ug/L ND 50.0 3.5 12/19/19 13:37 5-Nitro-o-toluidine ug/L ND 10.0 3.9 12/19/19 13:37 7,12-Dimethylbenz(a)anthracene ug/L ND 10.0 4.0 12/19/19 13:37 Acenaphthene ug/L ND 10.0 1.6 12/19/19 13:37 Acenaphthylene ug/L ND 10.0 1.6 12/19/19 13:37 Acetophenone ug/L ND 10.0 1.8 12/19/19 13:37 v1 v1 v1 IL Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 65 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 METHOD BLANK: 2762281 Matrix: Water Associated Lab Samples: 92457256001, 92457256002, 92457256003 Blank Reporting Parameter Units Result Limit MDL Analyzed Anthracene ug/L ND 10.0 1.7 12/19/19 13:37 Benzo(a)anthracene ug/L ND 10.0 1.8 12/19/19 13:37 Benzo(a)pyrene ug/L ND 10.0 2.1 12/19/19 13:37 Benzo(b)fluoranthene ug/L ND 10.0 1.9 12/19/19 13:37 Benzo(g,h,i)perylene ug/L ND 10.0 1.4 12/19/19 13:37 Benzo(k)fluoranthene ug/L ND 10.0 1.9 12/19/19 13:37 Benzyl alcohol ug/L ND 20.0 2.6 12/19/19 13:37 bis(2-Chloroethoxy)methane ug/L ND 10.0 1.8 12/19/19 13:37 bis(2-Chloroethyl) ether ug/L ND 10.0 1.8 12/19/19 13:37 bis(2-Ethylhexyl)phthalate ug/L ND 6.0 2.1 12/19/19 13:37 Butylbenzylphthalate ug/L ND 10.0 1.6 12/19/19 13:37 Chlorobenzilate ug/L ND 10.0 4.6 12/19/19 13:37 Chrysene ug/L ND 10.0 1.7 12/19/19 13:37 Di-n-butylphthalate ug/L ND 10.0 1.8 12/19/19 13:37 Di-n-octylphthalate ug/L ND 10.0 1.8 12/19/19 13:37 Diallate ug/L ND 10.0 5.3 12/19/19 13:37 Dibenz(a,h)anthracene ug/L ND 10.0 1.6 12/19/19 13:37 Dibenzofuran ug/L ND 10.0 1.5 12/19/19 13:37 Diethylphthalate ug/L ND 10.0 2.4 12/19/19 13:37 Dimethoate ug/L ND 10.0 4.8 12/19/19 13:37 Dimethylphthalate ug/L ND 10.0 1.6 12/19/19 13:37 Diphenylamine ug/L ND 10.0 1.7 12/19/19 13:37 Disulfoton ug/L ND 10.0 7.0 12/19/19 13:37 Ethyl methanesulfonate ug/L ND 20.0 5.3 12/19/19 13:37 Famphur ug/L ND 10.0 8.4 12/19/19 13:37 Fluoranthene ug/L ND 10.0 1.7 12/19/19 13:37 Fluorene ug/L ND 10.0 1.6 12/19/19 13:37 Hexachlorobenzene ug/L ND 10.0 1.7 12/19/19 13:37 Hexachlorocyclopentadiene ug/L ND 10.0 1.7 12/19/19 13:37 Hexachloroethane ug/L ND 10.0 2.0 12/19/19 13:37 Hexachloropropene ug/L ND 10.0 1.7 12/19/19 13:37 Indeno(1,2,3-cd)pyrene ug/L ND 10.0 1.6 12/19/19 13:37 Isodrin ug/L ND 10.0 4.8 12/19/19 13:37 Isophorone ug/L ND 10.0 1.6 12/19/19 13:37 Isosafrole ug/L ND 10.0 3.4 12/19/19 13:37 Kepone ug/L ND 10.0 8.5 12/19/19 13:37 v2 Methapyrilene ug/L ND 50.0 2.3 12/19/19 13:37 Methyl methanesulfonate ug/L ND 5.0 4.3 12/19/19 13:37 Methyl parathion ug/L ND 10.0 4.5 12/19/19 13:37 N-Nitroso-di-n-butylamine ug/L ND 10.0 3.2 12/19/19 13:37 N-Nitroso-di-n-propylamine ug/L ND 10.0 2.2 12/19/19 13:37 N-Nitrosodiethylamine ug/L ND 10.0 4.0 12/19/19 13:37 N-Nitrosodimethylamine ug/L ND 10.0 1.2 12/19/19 13:37 N-Nitrosodiphenylamine ug/L ND 10.0 1.7 12/19/19 13:37 N-Nitrosomethylethylamine ug/L ND 10.0 3.5 12/19/19 13:37 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 66 of 88 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 METHOD BLANK: 2762281 Matrix: Associated Lab Samples: 92457256001, 92457256002, 92457256003 Blank Parameter Units Result Water Reporting Limit MDL Analyzed Qualifiers N-Nitrosopiperidine ug/L ND 10.0 3.8 12/19/19 13:37 N-Nitrosopyrrolidine ug/L ND 10.0 3.8 12/19/19 13:37 Nitrobenzene ug/L ND 10.0 2.1 12/19/19 13:37 O,O,O-Triethylphosphorothioate ug/L ND 10.0 4.5 12/19/19 13:37 O-Toluidine ug/L ND 10.0 3.7 12/19/19 13:37 P-Dimethylaminoazobenzene ug/L ND 5.0 1.9 12/19/19 13:37 p-Phenylenediamine ug/L ND 10.0 4.2 12/19/19 13:37 Parathion (Ethyl parathion) ug/L ND 10.0 4.1 12/19/19 13:37 Pentachlorobenzene ug/L ND 10.0 3.5 12/19/19 13:37 Pentachloronitrobenzene ug/L ND 10.0 4.4 12/19/19 13:37 Pentachlorophenol ug/L ND 20.0 2.2 12/19/19 13:37 v1 Phenacetin ug/L ND 10.0 4.2 12/19/19 13:37 Phenanthrene ug/L ND 10.0 1.7 12/19/19 13:37 Phenol ug/L ND 10.0 0.92 12/19/19 13:37 Phorate ug/L ND 10.0 5.3 12/19/19 13:37 Pronamide ug/L ND 10.0 4.6 12/19/19 13:37 Pyrene ug/L ND 10.0 2.1 12/19/19 13:37 Safrole ug/L ND 10.0 4.5 12/19/19 13:37 Thionazin ug/L ND 10.0 4.8 12/19/19 13:37 2,4,6-Tribromophenol (S) % 100 10-137 12/19/19 13:37 2-Fluorobiphenyl (S) % 78 13-130 12/19/19 13:37 2-Fluorophenol (S) % 72 10-130 12/19/19 13:37 Nitrobenzene-d5 (S) % 82 13-130 12/19/19 13:37 Phenol-d6 (S) % 56 10-130 12/19/19 13:37 Terphenyl-d14 (S) % 102 25-130 12/19/19 13:37 LABORATORY CONTROL SAMPLE: Parameter 2762282 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,2,4,5-Tetrachlorobenzene ug/L 50 34.2 68 10-130 1,3,5-Trinitrobenzene ug/L 50 70.0 140 50-130 L1 1,3-Dinitrobenzene ug/L 50 57.2 114 30-130 v1 1,4-Naphthoquinone ug/L 50 34.6 69 30-130 1-Naphthalenamine ug/L 50 46.0 92 30-130 2,2'-Oxybis(1-chloropropane) ug/L 50 35.1 70 20-130 2,3,4,6-Tetrachlorophenol ug/L 50 48.5 97 40-200 2,4,5-Trichlorophenol ug/L 50 42.0 84 40-130 2,4,6-Trichlorophenol ug/L 50 43.5 87 40-130 2,4-Dichlorophenol ug/L 50 41.5 83 31-130 2,4-Dimethylphenol ug/L 50 42.7 85 30-130 2,4-Dinitrophenol ug/L 250 164 66 30-130 v1 2,4-Dinitrotoluene ug/L 50 51.9 104 49-130 2,6-Dichlorophenol ug/L 50 49.7 99 50-130 2,6-Dinitrotoluene ug/L 50 49.9 100 50-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 67 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 LABORATORY CONTROL SAMPLE: 2762282 Parameter QUALITY CONTROL DATA Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 2-Acetylaminofluorene ug/L 50 49.9 100 70-150 2-Chloronaphthalene ug/L 50 36.1 72 30-130 2-Chlorophenol ug/L 50 40.9 82 30-130 2-Methylnaphthalene ug/L 50 37.4 75 30-130 2-Methylphenol(o-Cresol) ug/L 50 38.4 77 30-130 2-Naphthalenamine ug/L 50 42.2 84 30-130 2-Nitroaniline ug/L 100 91.8 92 40-130 2-Nitrophenol ug/L 50 44.8 90 20-130 3&4-Methyl phenol (m&p Cresol) ug/L 50 38.5 77 20-130 3,3'-Dichlorobenzidine ug/L 100 104 104 10-150 3,3'-Dimethylbenzidine ug/L 100 103 103 10-150 3-Methylcholanthrene ug/L 50 83.7 167 40-1301L,L1 3-Nitroaniline ug/L 100 96.1 96 40-130 4,6-Dinitro-2-methyl phenol ug/L 100 110 110 40-130 4-Aminobiphenyl ug/L 50 53.7 107 20-130 4-Bromophenylphenyl ether ug/L 50 41.0 82 30-130 4-ChIoro-3-methyl phenol ug/L 100 88.4 88 30-130 4-Chloroaniline ug/L 100 89.7 90 20-130 4-Chlorophenylphenyl ether ug/L 50 39.6 79 20-130 4-Nitroaniline ug/L 100 108 108 40-130 4-Nitrophenol ug/L 250 184 74 10-130 5-Nitro-o-toluidine ug/L 50 60.3 121 50-150 7,12-Dimethylbenz(a)anthracene ug/L 50 53.1 106 50-130 Acenaphthene ug/L 50 39.4 79 30-130 Acenaphthylene ug/L 50 43.0 86 30-130 Acetophenone ug/L 50 39.4 79 20-130 Anthracene ug/L 50 47.7 95 50-130 Benzo(a)anthracene ug/L 50 51.0 102 50-130 Benzo(a)pyrene ug/L 50 53.7 107 50-130 Benzo(b)fluoranthene ug/L 50 56.0 112 50-130 Benzo(g,h,i)perylene ug/L 50 54.5 109 50-130 Benzo(k)fluoranthene ug/L 50 51.8 104 50-130 Benzyl alcohol ug/L 100 80.5 81 20-130 bis(2-Chloroethoxy)methane ug/L 50 38.9 78 30-130 bis(2-Chloroethyl) ether ug/L 50 39.3 79 30-130 bis(2-Ethylhexyl)phthalate ug/L 50 52.0 104 50-130 Butylbenzylphthalate ug/L 50 52.1 104 50-150 Chlorobenzilate ug/L 50 72.6 145 50-130 L1 Chrysene ug/L 50 49.3 99 50-130 Di-n-butylphthalate ug/L 50 48.8 98 50-130 Di-n-octylphthalate ug/L 50 55.4 111 50-130 Diallate ug/L 50 40.4 81 50-130 Dibenz(a,h)anthracene ug/L 50 54.3 109 40-130 Dibenzofuran ug/L 50 39.6 79 40-130 Diethylphthalate ug/L 50 47.3 95 40-130 Dimethoate ug/L 50 57.9 116 50-150 Dimethylphthalate ug/L 50 45.1 90 40-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 68 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 LABORATORY CONTROL SAMPLE: Parameter 2762282 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Diphenylamine ug/L 50 44.1 88 30-130 Disulfoton ug/L 50 54.3 109 40-150 Ethyl methanesulfonate ug/L 50 44.8 90 40-130 Famphur ug/L 100 70.7 71 30-150 Fluoranthene ug/L 50 50.6 101 30-130 Fluorene ug/L 50 43.6 87 20-130 Hexachlorobenzene ug/L 50 43.7 87 30-130 Hexachlorocyclopentadiene ug/L 50 33.9 68 10-150 Hexachloroethane ug/L 50 28.3 57 10-130 Hexachloropropene ug/L 50 31.2 62 10-150 Indeno(1,2,3-cd)pyrene ug/L 50 53.9 108 40-130 Isodrin ug/L 50 56.0 112 40-130 Isophorone ug/L 50 41.2 82 30-130 Isosafrole ug/L 50 39.7 79 40-130 Kepone ug/L 100 40.8 41 10-130 v3 Methapyrilene ug/L 50 51.1 102 10-150 Methyl methanesulfonate ug/L 50 39.8 80 20-130 Methyl parathion ug/L 50 58.6 117 50-130 N-Nitroso-di-n-butylamine ug/L 50 32.1 64 30-130 N-Nitroso-di-n-propylamine ug/L 50 40.5 81 30-130 N-Nitrosodiethylamine ug/L 50 37.2 74 40-130 N-Nitrosodimethylamine ug/L 50 34.3 69 10-130 N-Nitrosodiphenylamine ug/L 50 44.1 88 30-130 N-Nitrosomethylethylamine ug/L 50 35.3 71 30-130 N-Nitrosopiperidine ug/L 50 44.4 89 30-130 N-Nitrosopyrrolidine ug/L 50 43.9 88 30-130 Nitrobenzene ug/L 50 40.9 82 20-130 O,O,O-Triethylphosphorothioate ug/L 50 44.1 88 40-130 O-Toluidine ug/L 50 46.7 93 20-130 P-Dimethylaminoazobenzene ug/L 50 25.0 50 10-130 p-Phenylenediamine ug/L 50 57.1 114 70-140 Parathion (Ethyl parathion) ug/L 50 58.1 116 50-150 Pentachlorobenzene ug/L 50 41.3 83 30-150 Pentachloronitrobenzene ug/L 50 57.7 115 60-130 Pentachlorophenol ug/L 100 120 120 10-140 v1 Phenacetin ug/L 50 57.4 115 60-130 Phenanthrene ug/L 50 46.5 93 50-130 Phenol ug/L 50 31.5 63 10-130 Phorate ug/L 50 50.9 102 50-130 Pronamide ug/L 50 58.0 116 70-130 Pyrene ug/L 50 48.3 97 50-130 Safrole ug/L 50 41.0 82 30-130 Thionazin ug/L 50 53.9 108 60-130 2,4,6-Tribromophenol (S) % 119 10-137 2-Fluorobiphenyl (S) % 75 13-130 2-Fluorophenol (S) % 74 10-130 Nitrobenzene-d5 (S) % 80 13-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 69 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 LABORATORY CONTROL SAMPLE: 2762282 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phenol-d6 (S) % 60 10-130 Terphenyl-d14 (S) % 97 25-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2762283 2762284 MS MSD 92457256001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,2,4,5-Tetrachlorobenzene ug/L ND 50 50 ND ND 0 0 10-130 30 M1 1,3,5-Trinitrobenzene ug/L ND 50 50 ND ND 0 0 50-130 30 MO 1,3-Dinitrobenzene ug/L ND 50 50 ND ND 0 0 30-130 30 M1,v1 1,4-Naphthoquinone ug/L ND 50 50 ND ND 0 0 30-130 30 M1 1-Naphthalenamine ug/L ND 50 50 ND ND 0 0 30-130 30 M1 2,2'-Oxybis(1- ug/L ND 50 50 37.9 38.9 76 78 20-130 3 30 chloropropane) 2,3,4,6-Tetrachlorophenol ug/L ND 50 50 49.6 53.9 99 108 40-200 8 30 v1 2,4,5-Trichlorophenol ug/L ND 50 50 46.5 48.9 93 98 40-130 5 30 2,4,6-Trichlorophenol ug/L ND 50 50 49.1 51.9 98 104 40-130 6 30 2,4-Dichlorophenol ug/L ND 50 50 48.1 49.2 96 98 31-130 2 30 2,4-Dimethylphenol ug/L ND 50 50 46.9 47.7 94 95 30-130 2 30 2,4-Dinitrophenol ug/L ND 250 250 260 297 104 119 30-130 13 30 v1 2,4-Dinitrotoluene ug/L ND 50 50 52.8 57.7 106 115 49-130 9 30 2,6-Dichlorophenol ug/L ND 50 50 ND ND 0 0 50-130 30 M1 2,6-Dinitrotoluene ug/L ND 50 50 50.8 55.6 102 111 50-130 9 30 2-Acetylam inofl uorene ug/L ND 50 50 ND ND 0 0 70-150 30 M1 2-Chloronaphthalene ug/L ND 50 50 37.2 38.2 74 76 30-130 3 30 2-Chlorophenol ug/L ND 50 50 45.4 46.7 91 93 30-130 3 30 2-Methyl naphthalene ug/L ND 50 50 34.9 35.3 70 71 30-130 1 30 2-Methyl phenol(o-Cresol) ug/L ND 50 50 40.6 41.1 81 82 30-130 1 30 2-Naphthalenamine ug/L ND 50 50 ND ND 0 0 30-130 30 M1 2-Nitroaniline ug/L ND 100 100 100 107 100 107 40-130 7 30 2-Nitrophenol ug/L ND 50 50 53.0 53.8 106 108 20-130 1 30 3&4-Methylphenol(m&p ug/L ND 50 50 39.8 39.9 80 80 20-130 0 30 Cresol) 3,3'-Dichlorobenzidine ug/L ND 100 100 93.5 103 94 103 10-150 10 30 3,3'-Dimethylbenzidine ug/L ND 100 100 ND ND 0 0 10-150 30 M1 3-Methylcholanthrene ug/L ND 50 50 ND ND 0 0 40-130 30 IL,MO 3-Nitroaniline ug/L ND 100 100 104 113 104 113 40-130 8 30 4,6-Dinitro-2-methylphenol ug/L ND 100 100 117 125 117 125 40-130 6 30 4-Aminobiphenyl ug/L ND 50 50 ND ND 0 0 20-130 30 M1 4-Bromophenylphenyl ether ug/L ND 50 50 44.7 48.0 89 96 30-130 7 30 4-Chloro-3-methylphenol ug/L ND 100 100 97.9 99.8 98 100 30-130 2 30 4-Chloroaniline ug/L ND 100 100 96.2 102 96 102 20-130 6 30 4-Chlorophenylphenyl ether ug/L ND 50 50 44.6 47.5 89 95 20-130 6 30 4-Nitroaniline ug/L ND 100 100 101 110 101 110 40-130 8 30 4-Nitrophenol ug/L ND 250 250 162 157 65 63 10-130 3 30 5-Nitro-o-toluidine ug/L ND 50 50 ND ND 0 0 50-150 30 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 70 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2762283 2762284 MS MSD 92457256001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 7,12- ug/L ND 50 50 ND ND 0 0 50-130 30 M1 Dimethylbenz(a)anthracene Acenaphthene ug/L ND 50 50 43.8 45.7 88 91 30-130 4 30 Acenaphthylene ug/L ND 50 50 46.6 48.8 93 98 30-130 5 30 Acetophenone ug/L ND 50 50 44.3 46.3 89 93 20-130 4 30 Anthracene ug/L ND 50 50 50.4 54.2 101 108 50-130 7 30 Benzo(a)anth race ne ug/L ND 50 50 51.7 54.5 103 109 50-130 5 30 Benzo(a)pyrene ug/L ND 50 50 55.5 58.0 111 116 50-130 4 30 Benzo(b)fluoranthene ug/L ND 50 50 54.1 55.5 108 111 50-130 2 30 Benzo(g,h,i)perylene ug/L ND 50 50 57.4 60.0 115 120 50-130 5 30 Benzo(k)fluoranthene ug/L ND 50 50 52.9 56.2 106 112 50-130 6 30 Benzyl alcohol ug/L ND 100 100 88.0 89.7 88 90 20-130 2 30 bis(2- ug/L ND 50 50 44.8 46.8 90 94 30-130 4 30 Chloroethoxy)methane bis(2-Chloroethyl) ether ug/L ND 50 50 46.2 47.7 92 95 30-130 3 30 bis(2- Ethyl hexyl)phthalate ug/L 16.1 50 50 50.7 52.3 69 72 50-130 3 30 Butylbenzylphthalate ug/L ND 50 50 48.6 50.0 97 100 50-150 3 30 Chlorobenzilate ug/L ND 50 50 ND ND 0 0 50-130 30 MO Chrysene ug/L ND 50 50 51.5 53.1 103 106 50-130 3 30 Di-n-butylphthalate ug/L ND 50 50 49.1 52.1 98 104 50-130 6 30 Di-n-octylphthalate ug/L ND 50 50 52.9 54.0 106 108 50-130 2 30 Diallate ug/L ND 50 50 ND ND 0 0 50-130 30 M1 Dibenz(a,h)anthracene ug/L ND 50 50 56.5 59.6 113 119 40-130 5 30 Dibenzofuran ug/L ND 50 50 44.3 47.1 89 94 40-130 6 30 Diethylphthalate ug/L ND 50 50 47.6 51.6 95 103 40-130 8 30 Dimethoate ug/L ND 50 50 ND ND 0 0 50-150 30 M1 Dimethylphthalate ug/L ND 50 50 47.0 51.0 94 102 40-130 8 30 Diphenylamine ug/L ND 50 50 44.2 51.1 88 102 30-130 14 30 Disulfoton ug/L ND 50 50 ND ND 0 0 40-150 30 M1 Ethyl methanesulfonate ug/L ND 50 50 ND ND 0 0 40-130 30 M1 Famphur ug/L ND 100 100 ND ND 0 0 30-150 30 M1 Fluoranthene ug/L ND 50 50 52.4 56.2 105 112 30-130 7 30 Fluorene ug/L ND 50 50 48.5 51.7 97 103 20-130 6 30 Hexachlorobenzene ug/L ND 50 50 47.7 51.8 95 104 30-130 8 30 Hexachlorocyclopentadiene ug/L ND 50 50 31.3 31.2 63 62 10-150 0 30 Hexachloroethane ug/L ND 50 50 24.6 24.6 49 49 10-130 0 30 Hexachloropropene ug/L ND 50 50 ND ND 0 0 10-150 30 M1 Indeno(1,2,3-cd)pyrene ug/L ND 50 50 55.5 58.8 111 118 40-130 6 30 Isodrin ug/L ND 50 50 ND ND 0 0 40-130 30 M1 Isophorone ug/L ND 50 50 47.4 49.4 95 99 30-130 4 30 Isosafrole ug/L ND 50 50 ND ND 0 0 40-130 30 M1 Kepone ug/L ND 100 100 ND ND 0 0 10-130 30 M1,v2 Methapyrilene ug/L ND 50 50 ND ND 0 0 10-150 30 M1 Methyl methanesulfonate ug/L ND 50 50 ND ND 0 0 20-130 30 M1 Methyl parathion ug/L ND 50 50 ND ND 0 0 50-130 30 M1 N-Nitroso-di-n-butylamine ug/L ND 50 50 ND ND 0 0 30-130 30 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 71 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2762283 MS 92457256001 Spike Parameter Units Result Conc. MSD Spike Conc. 2762284 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual N-Nitroso-di-n-propylamine ug/L ND 50 50 45.5 47.7 91 95 30-130 5 30 N-Nitrosodiethylamine ug/L ND 50 50 ND ND 0 0 40-130 30 M1 N-Nitrosodimethylamine ug/L ND 50 50 38.0 37.8 76 76 10-130 1 30 N-Nitrosodiphenylamine ug/L ND 50 50 44.2 51.1 88 102 30-130 14 30 N-Nitrosomethylethylamine ug/L ND 50 50 ND ND 0 0 30-130 30 M1 N-Nitrosopiperidine ug/L ND 50 50 ND ND 0 0 30-130 30 M1 N-Nitrosopyrrolidine ug/L ND 50 50 ND ND 0 0 30-130 30 M1 Nitrobenzene ug/L ND 50 50 46.6 47.2 93 94 20-130 1 30 0,0,0- ug/L ND 50 50 ND ND 0 0 40-130 30 M1 Triethylphosphorothioate O-Toluidine ug/L ND 50 50 ND ND 0 0 20-130 30 M1 P- ug/L ND 50 50 ND ND 0 0 10-130 30 M1 Dimethylaminoazobenzene p-Phenylenediamine ug/L ND 50 50 ND ND 0 0 70-140 30 M1 Parathion (Ethyl parathion) ug/L ND 50 50 ND ND 0 0 50-150 30 M1 Pentachlorobenzene ug/L ND 50 50 ND ND 0 0 30-150 30 M1 Pentachloronitrobenzene ug/L ND 50 50 ND ND 0 0 60-130 30 M1 Pentachlorophenol ug/L ND 100 100 120 130 120 130 10-140 8 30 v1 Phenacetin ug/L ND 50 50 ND ND 0 0 60-130 30 M1 Phenanthrene ug/L ND 50 50 49.5 53.4 99 107 50-130 8 30 Phenol ug/L ND 50 50 33.0 31.6 66 63 10-130 4 30 Phorate ug/L ND 50 50 ND ND 0 0 50-130 30 M1 Pronamide ug/L ND 50 50 ND ND 0 0 70-130 30 M1 Pyrene ug/L ND 50 50 49.6 52.9 99 106 50-130 6 30 Safrole ug/L ND 50 50 ND ND 0 0 30-130 30 M1 Thionazin ug/L ND 50 50 ND ND 0 0 60-130 30 M1 2,4,6-Tribromophenol (S) % 144 148 10-137 SO 2-Fluorobiphenyl (S) % 94 95 13-130 2-Fluorophenol (S) % 89 83 10-130 Nitrobenzene-d5 (S) % 107 105 13-130 1g Phenol-d6 (S) % 72 65 10-130 Terphenyl-d14 (S) % 110 111 25-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 72 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 QC Batch: 514583 Analysis Method: SM 521 OB-2011 QC Batch Method: SM 521OB-2011 Analysis Description: 5210E BOD, 5 day Associated Lab Samples: 92457256004 METHOD BLANK: 2758092 Matrix: Water Associated Lab Samples: 92457256004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers BOD, 5 day ug/L ND 2000 2000 12/18/19 00:13 B3 LABORATORY CONTROL SAMPLE: 2758093 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day ug/L 198000 226000 114 84.6-115 B3 SAMPLE DUPLICATE: 2758095 92457215001 Dup Max Parameter Units Result Result RPD RPD Qualifiers BOD, 5 day ug/L 638 mg/L 636000 0 10 B3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 73 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 QC Batch: 516221 Analysis Method: EPA 9040C QC Batch Method: EPA 9040C Analysis Description: 9040 pH Associated Lab Samples: 92457256004 SAMPLE DUPLICATE: 2765971 Parameter pH at 25 Degrees C SAMPLE DUPLICATE: 2765972 Parameter pH at 25 Degrees C 92456956004 Dup Max Units Result Result RPD RPD Qualifiers Std. Units 6.3 6.2 2 9 D6.1-13 92457381001 Dup Max Units Result Result RPD RPD Qualifiers Std. Units 8.2 8.1 1 9 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 74 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 QC Batch: 516855 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92457256001, 92457256002, 92457256003 METHOD BLANK: 2768630 Matrix: Water Associated Lab Samples: 92457256001, 92457256002, 92457256003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfate ug/L ND 1000 500 12/27/1911:26 LABORATORY CONTROL SAMPLE: 2768631 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate ug/L 50000 51400 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2768632 2768633 MS MSD 92458602001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L ND 50000 50000 49100 51200 98 102 90-110 4 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2768634 2768635 MS MSD 92458628002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L 124 mg/L 50000 50000 171000 171000 93 93 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 75 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 QC Batch: 514627 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92457256004 METHOD BLANK: 2758194 Matrix: Water Associated Lab Samples: 92457256004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrate as N mg/L ND 0.10 0.060 12/13/19 13:35 Sulfate mg/L ND 1.0 0.50 12/13/1913:35 LABORATORY CONTROL SAMPLE: 2758195 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/L 2.5 2.7 106 90-110 Sulfate mg/L 50 54.5 109 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2758196 2758197 MS MSD 92457256004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrate as N mg/L ND 2.5 2.5 2.4 2.4 95 97 90-110 3 10 Sulfate mg/L 12.9 50 50 62.4 63.7 99 102 90-110 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 76 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 QC Batch: 514886 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Associated Lab Samples: 92457256004 METHOD BLANK: 2759555 Matrix: Water Associated Lab Samples: 92457256004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Phosphorus mg/L ND 0.050 0.025 12/17/1912:39 LABORATORY CONTROL SAMPLE: 2759556 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phosphorus mg/L 2.5 2.6 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2759557 2759558 MS MSD 92456997001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phosphorus mg/L 3.8 2.5 2.5 6.5 7.1 106 131 90-110 9 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2759559 2759560 MS MSD 92457011001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phosphorus mg/L 6.1 2.5 2.5 8.8 8.6 107 99 90-110 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 77 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 QC Batch: 515282 Analysis Method: SM 4500-CN-E-2011 QC Batch Method: SM 4500-CN-E-2011 Analysis Description: 450OCNE Cyanide, Total Associated Lab Samples: 92457256001, 92457256002, 92457256003 METHOD BLANK: 2761214 Matrix: Water Associated Lab Samples: 92457256001, 92457256002, 92457256003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Cyanide ug/L ND 8.0 6.0 12/18/1912:43 LABORATORY CONTROL SAMPLE: 2761215 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Cyanide ug/L 100 107 107 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2761216 2761217 MS MSD 92457353002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Cyanide ug/L ND 100 100 61.8 46.9 57 42 80-120 27 10 M1,R1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2761218 2761219 MS MSD 92457353003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Cyanide ug/L 0.019 100 100 121 133 103 115 80-120 9 10 mg/L Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 78 of 88 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 QC Batch: 515646 Analysis Method: SM 5220D-2011 QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD Associated Lab Samples: 92457256004 METHOD BLANK: 2763102 Matrix: Water Associated Lab Samples: 92457256004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chemical Oxygen Demand ug/L ND 25000 12500 12/19/19 18:35 LABORATORY CONTROL SAMPLE: 2763103 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 750000 741000 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2763104 2763105 MS MSD 92457330007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 35.1 mg/L 100000 100000 142000 146000 107 111 90-110 3 3 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2763106 2763107 MS MSD 92456970001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 130 mg/L 100000 100000 232000 239000 102 109 90-110 3 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 79 of 88 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALIFIERS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PAN Pace Analytical National PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS 1 g MS/MSD not spiked with all target analytes due to extraction error. B3 The dissolved oxygen depletion of the dilution water blank exceeded 0.2 mg/L. C9 Common Laboratory Contaminant. D6 The precision between the sample and sample duplicate exceeded laboratory control limits. H3 Sample was received or analysis requested beyond the recognized method holding time. H4 Sample re -extracted and analyzed outside of EPA method holding time. IL This analyte exceeded secondary source verification criteria low for the initial calibration. The reported results should be considered an estimated value. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 80 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 ANALYTE QUALIFIERS SO Surrogate recovery outside laboratory control limits. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 81 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Surry Co. Lined MSWLF 92457256 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92457256001 MW-2 8151A 1397177 EPA8151 1397177 92457256002 MW-6R 8151A 1397177 EPA8151 1397177 92457256003 MW-9S 8151A 1397177 EPA8151 1397177 92457256001 MW-2 EPA 3510C 515456 EPA 8081 B 515604 92457256002 MW-6R EPA 3510C 515456 EPA 8081 B 515604 92457256003 MW-9S EPA 3510C 515456 EPA 8081 B 515604 92457256001 MW-2 EPA 3510C 515053 EPA 8082A 515174 92457256002 MW-6R EPA 3510C 515053 EPA 8082A 515174 92457256003 MW-9S EPA 3510C 515053 EPA 8082A 515174 92457256001 MW-2 EPA 3010A 515402 EPA 6010D 515425 92457256002 MW-6R EPA 3010A 515402 EPA 6010D 515425 92457256003 MW-9S EPA 3010A 515402 EPA 6010D 515425 92457256004 LAGOON EPA 3010A 515402 EPA 6010D 515425 92457256005 MW-1 EPA 3010A 515402 EPA 6010D 515425 92457256006 MW-3R EPA 3010A 515402 EPA 6010D 515425 92457256007 MW-4S EPA 3010A 516818 EPA 6010D 516834 92457256008 MW-41) EPA 3010A 515402 EPA 6010D 515425 92457256009 MW-5 EPA 3010A 515402 EPA 6010D 515425 92457256010 MW-8 EPA 3010A 515402 EPA 6010D 515425 92457256011 MW-91) EPA 3010A 515403 EPA 6010D 515424 92457256012 MW-10 EPA 3010A 515403 EPA 6010D 515424 92457256013 MW-12 EPA 3010A 515403 EPA 6010D 515424 92457256001 MW-2 EPA 3010A 515406 EPA 6020B 515427 92457256002 MW-6R EPA 3010A 515406 EPA 6020B 515427 92457256003 MW-9S EPA 3010A 515406 EPA 6020B 515427 92457256004 LAGOON EPA 3010A 515406 EPA 6020B 515427 92457256005 MW-1 EPA 3010A 515406 EPA 6020B 515427 92457256006 MW-3R EPA 3010A 515406 EPA 6020B 515427 92457256007 MW-4S EPA 3010A 516819 EPA 6020B 516838 92457256008 MW-41) EPA 3010A 515406 EPA 6020B 515427 92457256009 MW-5 EPA 3010A 515406 EPA 6020B 515427 92457256010 MW-8 EPA 3010A 515406 EPA 6020B 515427 92457256011 MW-91) EPA 3010A 515405 EPA 6020B 515426 92457256012 MW-10 EPA 3010A 515405 EPA 6020B 515426 92457256013 MW-12 EPA 3010A 515405 EPA 6020B 515426 92457256001 MW-2 EPA 7470A 515772 EPA 7470A 515857 92457256002 MW-6R EPA 7470A 515772 EPA 7470A 515857 92457256003 MW-9S EPA 7470A 515772 EPA 7470A 515857 92457256001 MW-2 EPA 3510C 515528 EPA 8270E 515821 92457256002 MW-6R EPA 3510C 515528 EPA 8270E 515821 92457256003 MW-9S EPA 3510C 515528 EPA 8270E 515821 92457256001 MW-2 EPA 8260D 516391 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/31 /2019 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 82 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Surry Co. Lined MSWLF Pace Project No.: 92457256 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92457256002 MW-6R EPA 8260D 516391 92457256003 MW-9S EPA 8260D 516391 92457256004 LAGOON EPA 8260D 516391 92457256005 MW-1 EPA 8260D 516391 92457256006 MW-3R EPA 8260D 516391 92457256007 MW-4S EPA 8260D 516391 92457256008 MW-41) EPA 8260D 516391 92457256009 MW-5 EPA 8260D 516391 92457256010 MW-8 EPA 8260D 516391 92457256011 MW-91) EPA 8260D 516391 92457256012 MW-10 EPA 8260D 516391 92457256013 MW-12 EPA 8260D 516391 92457256004 LAGOON SM 521 OB-2011 514583 SM 521 OB-2011 514620 92457256004 LAGOON EPA 9040C 516221 92457256001 MW-2 EPA 300.0 Rev 2.1 1993 516855 92457256002 MW-6R EPA 300.0 Rev 2.1 1993 516855 92457256003 MW-9S EPA 300.0 Rev 2.1 1993 516855 92457256004 LAGOON EPA 300.0 Rev 2.1 1993 514627 92457256004 LAGOON EPA 365.1 Rev 2.0 1993 514886 EPA 365.1 Rev 2.0 1993 514974 92457256001 MW-2 SM 4500-CN-E-2011 515282 SM 4500-CN-E-2011 515495 92457256002 MW-6R SM 4500-CN-E-2011 515282 SM 4500-CN-E-2011 515495 92457256003 MW-9S SM 4500-CN-E-2011 515282 SM 4500-CN-E-2011 515495 92457256004 LAGOON SM 5220D-2011 515646 SM 5220D-2011 515886 Date: 12/31 /2019 01:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 83 of 88 Document Name: Document Revised: February 7, 201B m aceAnalytieal Sample Condition Upon Recel t(SCUR) Page 1 of 2 Document No.: Issuing Authority: j F-CAR-CS-033-Rev,06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville Ralelgh❑ Mechanicsville❑ Courier: ❑ Commercial Custody Seal Present? Packing Material Client ame: Project 1 W0# : 92457256 - d Etc OUPS ❑U fi r. ❑C nt Pace ❑ot a 92457256 Oyes o Seals Intact? ❑Yes JN, Gate/Initials Person Examining Contents: ❑Bubble Wrap[]Bubble Bags ❑None Other Thermometer: Type of ice: [:]None ❑Blue ❑IR Gun ID: 921058 Cooler Temp ('Cl: (; Z, Correction Factor: Add/Subtract ('Cl 0.0°C Cooler Temp Corrected (' Z' USDA Regulated Sall N/A,watersample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? []yes [:]NO ❑Nave 61ologlcalTissu row? [:]Yes[]NoN/A Temp should be above freezing to 6'C []Samples out of temp criteria. Samples un ice, cooling process hasbegun Did samples originate fram aforelgn source (internationally, inducting Hawaii and Puerto Rico)? []Yes ❑No Comments/Discrepancy: Chain of Custody Present? Ps ElNo QNIA 1. Samples Arrived within Hold Time? Yes ❑ [I N/A 2. Short Hold Time Analysis 1e72 hr.)? []Yes o ❑N/A 3. Rush Turn Around Time Requested? Elyge dNo ❑N/A 4. Sufficient Volume? No. ❑N/a S. Correct Containers Used? -Pace Containers Used? Y 6V ❑No []No ❑N/A ❑N/A 6. Containers Intact? Yes ❑No [3NV 7. Dissolved analysis: Samples Field Fiitered? ❑ es []No N/A g. Sample Labels Blotch CDC? -Inc Iucies Da'a/Time/IO/Analysis Matrix, Yes I10 ❑No ❑N/A 9. Headspace in VOA Vials;->5-6mm)? ❑Yes No ❑VIAI 10. Trip Blank Present? Trip Blank Custody Seals Present? []Yes ❑Yes ❑No ❑No N/ /A 11, COMMENTS/SAMPLE DISr.REPANCY Lot ID of sollt containers: CLrNtNO, Y F NL« Field Data Requtred? ❑Yes ❑No ?erson contacted: d6rV�J r �� 1" "1 l— 1' I L Date/Time: 7 f VLI( Project Manager SCURF Review: avyDate: Project Manager SRF Review: �WhDate: Page 84 of 88 Document Name: Document Revised: February 7, 2018 �AceAnaVical` Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: I5suingAuthcrity: F-CAR-CS-033-Rev,06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechtorination is verified and within the acceptance range for preservation samples. Exceptlons: VOA, Coiiform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHS **Bottom half of box is to list number of bottle Project #f WQ## : 92457256 PM: AMB Due Date: 12/27/19 CLIENT: 92—Municipal — a a v ¢ a v a z v 4 Z u _ N v f V v A a m z Lv N c-I A M V = _ v a �y x V a CJ fj z a ? ? 9 Z a) O = a v Q -o v a c n c v a c w w n O N m z a 7 Z 0 v a z a u 2 a 7 O r a O N v a E a ? tJ M N Z Z a D O w Q. v ° Z z a c O N C a _ — J E N N E O N E E E 4 cv — E Q a a N E a a` - ¢ E O rev I m C) E a O 7 o O E a 0 E n N a 0. _n N E �n E O N a E N 4 o In E p Q E Q A E rs 7 a a rn 7 M a m N a Co .+ a m q a m 2 ro a m m ery-I Q a inQ yr •-� rl LD N M 0 ¢ M 0 Q e� U' Q M 0 a M 0 a i M U O QI %D ] Gl l7 7 q-I M U 0 d O 7 V N a In N a ve R1 a co O t9 4 �7 a 7 0 to o Xf z 1 1� N\N' 3 9 --r\—INN IT N\ s f -� fi N X \N \1 -. I � - 8 \ \ 11 13. 9 � j V 1 I to � , � �? t 1 4 I •!7 7 I � M,MMMUM-® pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon recelpt i Date preservation adjusted Time preservation adjusted Amount of Preservative lot tJ added - I Note: Whenever there is a discrepancy affeaing North Carolina Cnmpllance samples, a copy of this form will be sent to the North Carolina DEFINR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 85 of 88 ace Analytical Sample Receiving Non -Conformance Form (NCF) Date: Evaluated by: Affix Workorder/Login Label Here or List Pace Client: Workorder Number or MTJL Log -in Number Flare q_z (_ �. 1. If Chain -of -Custody (COC) is not received: contact client and if necessary, fill out a COC and indicate that it was filled out by lab personnel. Note issues on this NCF. 2. If COC is incomplete, check applicable issues below and add details where appropriate: Collection date/lime missing or Analyses or analytes: missing or �/ Samples listed on COC do not match samples incorrect clarification, needed J� received (missing, additional, etc. Sample IDs on COC do not match sample labels Required trip blanks were not received Required sicinatures are missing Comments/Details/Other Issues not listed above: not rcceNe 3. Sample integrity issues: check applicable issues below and add details where appropriate: Samples: Condition needs to be brought to ` Samples: Past holding time lab ersonnel's attention details below Preservation: Improper Temperature: not within acceptance criteria (typically Samples: Not field filtered Containers: Broken or compromised 0-6e Samples: Insufficient volume received ContainerE: Incorrect Temperature: Samples arrived frozen _ Sampies: Cooler damaged or _ Custody 7eais: Missing or compromised on compromised sam i as, trip blanks or coolers Vials received with im +,r;fer headspace Samples: contain chlorine or sulfides Packing Material: Insufficient/Im ro er Other: Comments/Details: mko G one wn.i,ier ;� )oar G-f h c Hv�) q S -- u Ll -E7 C ud- Vh 4. If Samples not preserved properly and Sample Receiving adjusts pH, add details below: Sample ID: M�V G 1� DaterFime: .l -) z ' )9 is, is Arnor!ntltype pres added:)'(,dkWn lA�k-4 ,� Preserved by: 1 ON cm [� Initial and Final H: — Lot # of }} res added: 11 U i� B Sample ID: myU - I DatelTime: f Z` P ' MC[ I S '- f5 Amm.int/type res added: �CCWM �I Preserved by: TGCOC't L - Initial and Final H: " - Lot f# of res added: 11 Z . Z � Sample ID: Date/Time: Amount/type res added: Preserved by: Initial and Fins! pH: Lot # of res added: 5. Client Contact: If client is contacted for Contacted PM Initials: Daterrime: �71ient Comments/Instructions: F-ALL-C-011-rev.00, 05Ju12018 issue listed above, fill in details below: X Page 86 of 88 v m a n m N m m as m A r+ N ITI=M# m W_ j a ro a 3 3 3 u o z n Y 1 n ° o p r1°ii 0 00 VI N � w ni m y x N O v h' Cn 0 Cn �� n n n A`F—mo n. i x n O Q Y N a w WN �m7 0 L z r aw ❑ I'll p CD n 61 m 0 n 3 o x z v � m N N �0 tE 9wmqm °K e m a { - n 77 l\ 0 m 0 z j z m MATRIX CODE {see valid modes le left) z ❑ n A I C ° 3 x M I0 0 0 I0 0 0 Ia 4� G'f LT SAMPLE TYPE {G=GRAB C=COMP) m co j 0 '0 o D c > 0 o a m — y n r > m Al CD CD _ n CL R1 0 z z m V1 m m co 0 I n a 0 c n e r, z R JO O m r m= fart m FZ m �1 m Cl T 0 -°. D _ z ¢� 0 fn in p G o 1 r r ZU1 • m d m M> s I I I I I SAMPLE TEMP AT COLLECTION w l� C ❑ 1 • m `. m Imo, , vs I0 Icn °, cn lw en Ir., N 9OF CONTAINERS � m m n a � n N it) UnpreserYed m -n o C w o m m y m o a, o n Rs O H2SO4 m r � 1HNO3 CID m 3 � D v� o iw Imo w Imo w w m IImo w w w w HC1 m n n 0_ Z n I I NaOH P m INC n I I Na2S203 m > 7 E: III m --I Methanol CD m 1 rt v o { 0 m- I Other n SS1 I� � Analyses Test Yll3 f° x x x x j x x x x 'x VOCs-8260 App I z -n ' a y�f Ix x x x xCD m x x x Melals-AppI z Ln CD 0 x m cs {n In ^ Z x x x x x x x x x x x x i z C N rt �o ll a x Ix x x x x x Ix x x x i,4-0it, C =0 x x x l PCBs (App 2) > 6 0 @ E nJ N o x x l x SVOCs (App 2) �_ 0 i m N x x l x VOCs-((App r m ,y Melals-App 2 (Includes Hg) m o. a Pesticides {App 2} z n S I I — c t� Herbicides (App 2) Cyanide o w 2 ,d G I x x x Sul€aSe m 9 ° TEMP in C d o Z c m n Received on c Ice (YIN) m l CLst°dy Sealed O 1 0 Samples am leslnlad 1 I T (YiN Page 87 of 88 m m t7 a o i m c a i ITEMS# •' I n Z ,� w ❑ a y z 3 0 Cl)o m N O 9 VI �_• o D J — (D a D a N K Cf, 3 w N W w O 5 2 4 nl [D o n ... cn n v 7� ? z ^gym I— o(- oca m oCD @ W T 6 m LO N CCD — (O �- v N N w f4v\ -4 29 0 2� X u z W - n n a n p Q — 6 m n bb 5522 V D m m p W a p O n O D m MATRI%COPE (sae valid mdes to IeR) o 4 (n E SAMPLE TYPE (G=GRAE C=COMP) m = fu 5 G7 m m x 7 O CD ❑ Y o O { m w 7 fff n p �. n n y %� ( R z Cn ❑ g, y s+ i c z W c z m l Q Q m M m C w g y n G z � ,L v r v 0 ° m m A r M z > m SAM PLETEMP AT COLLECTION C m b b a Q n Y. OF CONTAINERS m m Q o a m f, v W � � _ Unpn:served v v O N a` M H2SO4 m n m z d HNO3 m m M m 'oW ci w w w w HGI NaOH m n n <' N m Na25203 M m CD Methanol ❑ m 5' Other YIN C Analyses Test x x x x x VOCs-App I nx @ x x x x Metals-App I m 4 0 x x x x X (n m r A n m Q. Q x x 1,A-0ioxane (Non-SIM) D w I N M x B00 x C00 _ m NITRATE -� ~ x PHOSPHORUS m � Ph a Se J x Sulfate o TEMP in C L Q Z n a", n Received on Ice (YIN) m 7 z f Custody Sealed Cooler (YIN) Q aV z w Samples Intact (Y1N) Page 88 of 88 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 February 04, 2020 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: Surry Co. Lined MSWLF Pace Project No.: 92457585 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. A revised report is being submitted on 2/4/2020 to remove the sample results for 92457585003, per client request. If you have any questions concerning this report, please feel free to contact me. Sincerely, Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Steven R. Gandy, Municipal Engineering Services Co. Maddie German, Municipal Engineering Services REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 23 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry Co. Lined MSWLF Pace Project No.: 92457585 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 23 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Surry Co. Lined MSWLF Pace Project No.: 92457585 Lab ID Sample ID Matrix Date Collected Date Received 92457585001 MW-11D Water 12/12/19 11:03 12/16/19 08:30 92457585002 MW-11S Water 12/12/19 11:00 12/16/19 08:30 92457585004 SW-D Water 12/12/19 17:01 12/16/19 08:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 23 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Surry Co. Lined MSWLF 92457585 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92457585001 MW-11D EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92457585002 MW-11S EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92457585004 SW-D EPA 8260D CL 51 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 23 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457585 Sample: MW-11D Lab ID: 92457585001 Collected: 12/12/19 11:03 Received: 12/16/19 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 02/04/2020 12:05 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 12/19/19 01:06 12/20/19 10:37 7440-36-0 ND ug/L 10.0 4.7 1 12/19/19 01:06 12/20/19 10:37 7440-38-2 ND ug/L 5.0 1.0 1 12/19/19 01:06 12/20/19 10:37 7440-39-3 ND ug/L 1.0 0.20 1 12/19/19 01:06 12/20/19 10:37 7440-41-7 ND ug/L 1.0 0.40 1 12/19/19 01:06 12/20/19 10:37 7440-43-9 ND ug/L 5.0 1.0 1 12/19/19 01:06 12/20/19 10:37 7440-47-3 ND ug/L 5.0 1.1 1 12/19/19 01:06 12/20/19 10:37 7440-48-4 ND ug/L 5.0 2.1 1 12/19/19 01:06 12/20/19 10:37 7440-50-8 ND ug/L 5.0 1.6 1 12/19/19 01:06 12/20/19 10:37 7439-92-1 ND ug/L 5.0 0.90 1 12/19/19 01:06 12/20/19 10:37 7440-02-0 ND ug/L 10.0 4.7 1 12/19/19 01:06 12/20/19 10:37 7782-49-2 ND ug/L 5.0 2.5 1 12/19/19 01:06 12/20/19 10:37 7440-22-4 ND ug/L 5.0 1.3 1 12/19/19 01:06 12/20/19 10:37 7440-62-2 ND ug/L 10.0 3.9 1 12/19/19 01:06 12/20/19 10:37 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/19/19 01:55 12/27/19 22:59 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/23/1916:52 67-64-1 ND ug/L 10.0 0.90 1 12/23/1916:52 107-13-1 ND ug/L 1.0 0.15 1 12/23/1916:52 71-43-2 ND ug/L 1.0 0.34 1 12/23/1916:52 74-97-5 ND ug/L 1.0 0.26 1 12/23/1916:52 75-27-4 ND ug/L 1.0 0.62 1 12/23/1916:52 75-25-2 ND ug/L 2.0 0.62 1 12/23/1916:52 74-83-9 ND ug/L 5.0 3.3 1 12/23/1916:52 78-93-3 ND ug/L 2.0 0.40 1 12/23/1916:52 75-15-0 ND ug/L 1.0 0.22 1 12/23/1916:52 56-23-5 ND ug/L 1.0 0.23 1 12/23/1916:52 108-90-7 ND ug/L 1.0 0.49 1 12/23/1916:52 75-00-3 ND ug/L 5.0 2.3 1 12/23/1916:52 67-66-3 ND ug/L 1.0 0.39 1 12/23/1916:52 74-87-3 ND ug/L 5.0 0.26 1 12/23/1916:52 96-12-8 ND ug/L 1.0 0.41 1 12/23/1916:52 124-48-1 ND ug/L 1.0 0.26 1 12/23/1916:52 106-93-4 ND ug/L 1.0 0.46 1 12/23/1916:52 74-95-3 ND ug/L 1.0 0.29 1 12/23/1916:52 95-50-1 ND ug/L 1.0 0.26 1 12/23/1916:52 106-46-7 ND ug/L 1.0 0.54 1 12/23/1916:52 110-57-6 ND ug/L 1.0 0.27 1 12/23/1916:52 75-34-3 ND ug/L 1.0 0.34 1 12/23/1916:52 107-06-2 ND ug/L 1.0 0.24 1 12/23/1916:52 75-35-4 ND ug/L 1.0 0.29 1 12/23/1916:52 156-59-2 ND ug/L 1.0 0.25 1 12/23/1916:52 156-60-5 ND ug/L 1.0 0.19 1 12/23/1916:52 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 23 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457585 Sample: MW-11D Lab ID: 92457585001 Collected: 12/12/19 11:03 Received: 12/16/19 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/23/19 16:52 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/23/19 16:52 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/23/19 16:52 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/23/19 16:52 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/23/19 16:52 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/23/19 16:52 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/23/19 16:52 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/23/19 16:52 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/23/19 16:52 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/23/19 16:52 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/23/19 16:52 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/23/19 16:52 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/23/19 16:52 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/23/19 16:52 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/23/19 16:52 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/23/19 16:52 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/23/19 16:52 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/23/19 16:52 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/23/19 16:52 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/23/19 16:52 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/23/19 16:52 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 101 % 70-130 1 12/23/19 16:52 460-00-4 1,2-Dichloroethane-d4 (S) 98 % 70-130 1 12/23/19 16:52 17060-07-0 Toluene-d8 (S) 101 % 70-130 1 12/23/19 16:52 2037-26-5 Date: 02/04/2020 12:05 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 23 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457585 Sample: MW-11S Lab ID: 92457585002 Collected: 12/12/19 11:00 Received: 12/16/19 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 02/04/2020 12:05 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 12/19/19 01:06 12/20/19 10:41 7440-36-0 ND ug/L 10.0 4.7 1 12/19/19 01:06 12/20/19 10:41 7440-38-2 18.2 ug/L 5.0 1.0 1 12/19/19 01:06 12/20/19 10:41 7440-39-3 ND ug/L 1.0 0.20 1 12/19/19 01:06 12/20/19 10:41 7440-41-7 ND ug/L 1.0 0.40 1 12/19/19 01:06 12/20/19 10:41 7440-43-9 ND ug/L 5.0 1.0 1 12/19/19 01:06 12/20/19 10:41 7440-47-3 ND ug/L 5.0 1.1 1 12/19/19 01:06 12/20/19 10:41 7440-48-4 ND ug/L 5.0 2.1 1 12/19/19 01:06 12/20/19 10:41 7440-50-8 ND ug/L 5.0 1.6 1 12/19/19 01:06 12/20/19 10:41 7439-92-1 1.4J ug/L 5.0 0.90 1 12/19/19 01:06 12/20/19 10:41 7440-02-0 ND ug/L 10.0 4.7 1 12/19/19 01:06 12/20/19 10:41 7782-49-2 ND ug/L 5.0 2.5 1 12/19/19 01:06 12/20/19 10:41 7440-22-4 ND ug/L 5.0 1.3 1 12/19/19 01:06 12/20/19 10:41 7440-62-2 4.2J ug/L 10.0 3.9 1 12/19/19 01:06 12/20/19 10:41 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/19/19 01:55 12/27/19 23:03 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/23/1917:10 67-64-1 ND ug/L 10.0 0.90 1 12/23/1917:10 107-13-1 0.30J ug/L 1.0 0.15 1 12/23/1917:10 71-43-2 ND ug/L 1.0 0.34 1 12/23/1917:10 74-97-5 ND ug/L 1.0 0.26 1 12/23/1917:10 75-27-4 ND ug/L 1.0 0.62 1 12/23/1917:10 75-25-2 ND ug/L 2.0 0.62 1 12/23/1917:10 74-83-9 ND ug/L 5.0 3.3 1 12/23/1917:10 78-93-3 ND ug/L 2.0 0.40 1 12/23/1917:10 75-15-0 ND ug/L 1.0 0.22 1 12/23/1917:10 56-23-5 ND ug/L 1.0 0.23 1 12/23/1917:10 108-90-7 ND ug/L 1.0 0.49 1 12/23/1917:10 75-00-3 ND ug/L 5.0 2.3 1 12/23/1917:10 67-66-3 ND ug/L 1.0 0.39 1 12/23/1917:10 74-87-3 ND ug/L 5.0 0.26 1 12/23/1917:10 96-12-8 ND ug/L 1.0 0.41 1 12/23/1917:10 124-48-1 ND ug/L 1.0 0.26 1 12/23/1917:10 106-93-4 ND ug/L 1.0 0.46 1 12/23/1917:10 74-95-3 ND ug/L 1.0 0.29 1 12/23/1917:10 95-50-1 ND ug/L 1.0 0.26 1 12/23/1917:10 106-46-7 ND ug/L 1.0 0.54 1 12/23/1917:10 110-57-6 ND ug/L 1.0 0.27 1 12/23/1917:10 75-34-3 ND ug/L 1.0 0.34 1 12/23/1917:10 107-06-2 ND ug/L 1.0 0.24 1 12/23/1917:10 75-35-4 0.29J ug/L 1.0 0.29 1 12/23/1917:10 156-59-2 ND ug/L 1.0 0.25 1 12/23/1917:10 156-60-5 ND ug/L 1.0 0.19 1 12/23/1917:10 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 23 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457585 Sample: MW-11S Lab ID: 92457585002 Collected: 12/12/19 11:00 Received: 12/16/19 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/23/19 17:10 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/23/19 17:10 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/23/19 17:10 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/23/19 17:10 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/23/19 17:10 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/23/19 17:10 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/23/19 17:10 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/23/19 17:10 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/23/19 17:10 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/23/19 17:10 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/23/19 17:10 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/23/19 17:10 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/23/19 17:10 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/23/19 17:10 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/23/19 17:10 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/23/19 17:10 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/23/19 17:10 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/23/19 17:10 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/23/19 17:10 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/23/19 17:10 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/23/19 17:10 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 100 % 70-130 1 12/23/19 17:10 460-00-4 1,2-Dichloroethane-d4 (S) 95 % 70-130 1 12/23/19 17:10 17060-07-0 Toluene-d8 (S) 102 % 70-130 1 12/23/19 17:10 2037-26-5 Date: 02/04/2020 12:05 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 23 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457585 Sample: SW-D Lab ID: 92457585004 Collected: 12/12/19 17:01 Received: 12/16/19 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Date: 02/04/2020 12:05 PM Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/23/1917:46 67-64-1 ND ug/L 10.0 0.90 1 12/23/1917:46 107-13-1 ND ug/L 1.0 0.15 1 12/23/1917:46 71-43-2 ND ug/L 1.0 0.34 1 12/23/1917:46 74-97-5 ND ug/L 1.0 0.26 1 12/23/1917:46 75-27-4 ND ug/L 1.0 0.62 1 12/23/1917:46 75-25-2 ND ug/L 2.0 0.62 1 12/23/1917:46 74-83-9 ND ug/L 5.0 3.3 1 12/23/1917:46 78-93-3 ND ug/L 2.0 0.40 1 12/23/1917:46 75-15-0 ND ug/L 1.0 0.22 1 12/23/1917:46 56-23-5 ND ug/L 1.0 0.23 1 12/23/1917:46 108-90-7 ND ug/L 1.0 0.49 1 12/23/1917:46 75-00-3 ND ug/L 5.0 2.3 1 12/23/1917:46 67-66-3 ND ug/L 1.0 0.39 1 12/23/1917:46 74-87-3 ND ug/L 5.0 0.26 1 12/23/1917:46 96-12-8 ND ug/L 1.0 0.41 1 12/23/1917:46 124-48-1 ND ug/L 1.0 0.26 1 12/23/1917:46 106-93-4 ND ug/L 1.0 0.46 1 12/23/1917:46 74-95-3 ND ug/L 1.0 0.29 1 12/23/1917:46 95-50-1 ND ug/L 1.0 0.26 1 12/23/1917:46 106-46-7 ND ug/L 1.0 0.54 1 12/23/1917:46 110-57-6 ND ug/L 1.0 0.27 1 12/23/1917:46 75-34-3 ND ug/L 1.0 0.34 1 12/23/1917:46 107-06-2 ND ug/L 1.0 0.24 1 12/23/1917:46 75-35-4 ND ug/L 1.0 0.29 1 12/23/1917:46 156-59-2 ND ug/L 1.0 0.25 1 12/23/1917:46 156-60-5 ND ug/L 1.0 0.19 1 12/23/1917:46 78-87-5 ND ug/L 1.0 0.30 1 12/23/1917:46 10061-01-5 ND ug/L 1.0 0.31 1 12/23/1917:46 10061-02-6 ND ug/L 150 56.2 1 12/23/1917:46 123-91-1 ND ug/L 1.0 0.26 1 12/23/1917:46 100-41-4 ND ug/L 5.0 0.57 1 12/23/1917:46 591-78-6 ND ug/L 20.0 12.5 1 12/23/1917:46 74-88-4 ND ug/L 5.0 3.7 1 12/23/1917:46 75-09-2 ND ug/L 5.0 4.5 1 12/23/1917:46 108-10-1 ND ug/L 1.0 0.27 1 12/23/1917:46 100-42-5 ND ug/L 1.0 0.34 1 12/23/1917:46 630-20-6 ND ug/L 1.0 0.22 1 12/23/1917:46 79-34-5 ND ug/L 1.0 0.16 1 12/23/1917:46 127-18-4 ND ug/L 1.0 0.24 1 12/23/1917:46 108-88-3 ND ug/L 1.0 0.18 1 12/23/1917:46 71-55-6 ND ug/L 1.0 0.24 1 12/23/1917:46 79-00-5 ND ug/L 1.0 0.22 1 12/23/1917:46 79-01-6 ND ug/L 1.0 0.31 1 12/23/1917:46 75-69-4 ND ug/L 1.0 0.35 1 12/23/1917:46 96-18-4 ND ug/L 2.0 1.4 1 12/23/1917:46 108-05-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 23 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92457585 Sample: SW-D Lab ID: 92457585004 Collected: 12/12/19 17:01 Received: 12/16/19 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Vinyl chloride ND ug/L 1.0 0.24 1 12/23/19 17:46 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/23/19 17:46 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 100 % 70-130 1 12/23/19 17:46 460-00-4 1,2-Dichloroethane-d4 (S) 97 % 70-130 1 12/23/19 17:46 17060-07-0 Toluene-d8 (S) 101 % 70-130 1 12/23/19 17:46 2037-26-5 Date: 02/04/2020 12:05 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 23 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457585 QC Batch: 515674 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92457585001, 92457585002 METHOD BLANK: 2763240 Associated Lab Samples: 92457585001, 92457585002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 5.0 3.0 12/20/19 09:38 Arsenic ug/L ND 10.0 4.7 12/20/19 09:38 Barium ug/L ND 5.0 1.0 12/20/19 09:38 Beryllium ug/L ND 1.0 0.20 12/20/19 09:38 Cadmium ug/L ND 1.0 0.40 12/20/19 09:38 Chromium ug/L ND 5.0 1.0 12/20/19 09:38 Cobalt ug/L ND 5.0 1.1 12/20/19 09:38 Copper ug/L ND 5.0 2.1 12/20/19 09:38 Lead ug/L ND 5.0 1.6 12/20/19 09:38 Nickel ug/L ND 5.0 0.90 12/20/19 09:38 Selenium ug/L ND 10.0 4.7 12/20/19 09:38 Silver ug/L ND 5.0 2.5 12/20/19 09:38 Vanadium ug/L ND 5.0 1.3 12/20/19 09:38 Zinc ug/L ND 10.0 3.9 12/20/19 09:38 LABORATORY CONTROL SAMPLE: Parameter 2763241 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 495 99 80-120 Arsenic ug/L 500 506 101 80-120 Barium ug/L 500 464 93 80-120 Beryllium ug/L 500 479 96 80-120 Cadmium ug/L 500 480 96 80-120 Chromium ug/L 500 471 94 80-120 Cobalt ug/L 500 485 97 80-120 Copper ug/L 500 486 97 80-120 Lead ug/L 500 490 98 80-120 Nickel ug/L 500 481 96 80-120 Selenium ug/L 500 486 97 80-120 Silver ug/L 250 241 96 80-120 Vanadium ug/L 500 473 95 80-120 Zinc ug/L 500 477 95 80-120 Qualifiers Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2763242 2763243 MS MSD 92457300003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 508 490 102 98 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/04/2020 12:05 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 23 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Surry Co. Lined MSWLF 92457585 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2763242 2763243 MS MSD 92457300003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L ND 500 500 519 495 103 99 75-125 5 20 Barium ug/L 22.6 500 500 498 510 95 98 75-125 3 20 Beryllium ug/L ND 500 500 500 496 100 99 75-125 1 20 Cadmium ug/L ND 500 500 509 503 102 101 75-125 1 20 Chromium ug/L ND 500 500 487 503 97 101 75-125 3 20 Cobalt ug/L 1.91 500 500 507 495 101 99 75-125 2 20 Copper ug/L 2.2J 500 500 503 494 100 98 75-125 2 20 Lead ug/L ND 500 500 508 495 102 99 75-125 2 20 Nickel ug/L 1.3J 500 500 502 499 100 99 75-125 1 20 Selenium ug/L ND 500 500 487 460 97 92 75-125 6 20 Silver ug/L ND 250 250 246 244 98 98 75-125 1 20 Vanadium ug/L ND 500 500 488 495 98 99 75-125 1 20 Zinc ug/L ND 500 500 511 507 102 101 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/04/2020 12:05 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 23 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457585 QC Batch: 515676 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92457585001, 92457585002 METHOD BLANK: 2763248 Matrix: Water Associated Lab Samples: 92457585001, 92457585002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 12/27/1916:52 LABORATORY CONTROL SAMPLE: 2763249 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10.1 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2763250 2763251 MS MSD 92457433003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L 0.076J 10 10 10.6 10.9 106 108 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/04/2020 12:05 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 23 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457585 QC Batch: 516391 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Associated Lab Samples: 92457585001, 92457585002, 92457585004 METHOD BLANK: 2766744 Matrix: Associated Lab Samples: 92457585001, 92457585002, 92457585004 Blank Parameter Units Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 12/23/19 12:07 1,1,1-Trichloroethane ug/L ND 1.0 0.18 12/23/19 12:07 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 12/23/19 12:07 1,1,2-Trichloroethane ug/L ND 1.0 0.24 12/23/19 12:07 1,1-Dichloroethane ug/L ND 1.0 0.27 12/23/19 12:07 1,1-Dichloroethene ug/L ND 1.0 0.24 12/23/19 12:07 1,2,3-Trichloropropane ug/L ND 1.0 0.35 12/23/19 12:07 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 12/23/19 12:07 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 12/23/19 12:07 1,2-Dichlorobenzene ug/L ND 1.0 0.29 12/23/19 12:07 1,2-Dichloroethane ug/L ND 1.0 0.34 12/23/19 12:07 1,2-Dichloropropane ug/L ND 1.0 0.19 12/23/19 12:07 1,4-Dichlorobenzene ug/L ND 1.0 0.26 12/23/19 12:07 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 12/23/19 12:07 2-Butanone (MEK) ug/L ND 5.0 3.3 12/23/19 12:07 2-Hexanone ug/L ND 5.0 0.57 12/23/19 12:07 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 12/23/19 12:07 Acetone ug/L ND 25.0 6.2 12/23/19 12:07 Acrylonitrile ug/L ND 10.0 0.90 12/23/19 12:07 Benzene ug/L ND 1.0 0.15 12/23/19 12:07 Bromochloromethane ug/L ND 1.0 0.34 12/23/19 12:07 Bromodichloromethane ug/L ND 1.0 0.26 12/23/19 12:07 Bromoform ug/L ND 1.0 0.62 12/23/19 12:07 Bromomethane ug/L ND 2.0 0.62 12/23/19 12:07 Carbon disulfide ug/L ND 2.0 0.40 12/23/19 12:07 Carbon tetrachloride ug/L ND 1.0 0.22 12/23/19 12:07 Chlorobenzene ug/L ND 1.0 0.23 12/23/19 12:07 Chloroethane ug/L ND 1.0 0.49 12/23/19 12:07 Chloroform ug/L ND 5.0 2.3 12/23/19 12:07 Chloromethane ug/L ND 1.0 0.39 12/23/19 12:07 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 12/23/19 12:07 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 12/23/19 12:07 Dibromochloromethane ug/L ND 1.0 0.41 12/23/19 12:07 Dibromomethane ug/L ND 1.0 0.46 12/23/19 12:07 Ethylbenzene ug/L ND 1.0 0.26 12/23/19 12:07 lodomethane ug/L ND 20.0 12.5 12/23/19 12:07 Methylene Chloride ug/L ND 5.0 3.7 12/23/19 12:07 Styrene ug/L ND 1.0 0.27 12/23/19 12:07 Tetrachloroethene ug/L ND 1.0 0.16 12/23/19 12:07 Toluene ug/L ND 1.0 0.24 12/23/19 12:07 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 12/23/19 12:07 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/04/2020 12:05 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 23 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457585 METHOD BLANK: 2766744 Matrix: Associated Lab Samples: 92457585001, 92457585002, 92457585004 Blank Parameter Units Result Water Reporting Limit MDL Analyzed trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 12/23/19 12:07 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 12/23/19 12:07 Trichloroethene ug/L ND 1.0 0.22 12/23/19 12:07 Trichlorofluoromethane ug/L ND 1.0 0.31 12/23/19 12:07 Vinyl acetate ug/L ND 2.0 1.4 12/23/19 12:07 Vinyl chloride ug/L ND 1.0 0.24 12/23/19 12:07 Xylene (Total) ug/L ND 1.0 0.63 12/23/19 12:07 1,2-Dichloroethane-d4 (S) % 98 70-130 12/23/19 12:07 4-Bromofluorobenzene (S) % 102 70-130 12/23/19 12:07 Toluene-d8 (S) % 101 70-130 12/23/19 12:07 LABORATORY CONTROL SAMPLE: Parameter 2766745 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 51.1 102 70-130 1,1,1-Trichloroethane ug/L 50 45.2 90 70-130 1,1,2,2-Tetrachloroethane ug/L 50 49.7 99 70-130 1,1,2-Trichloroethane ug/L 50 48.3 97 70-130 1,1-Dichloroethane ug/L 50 47.1 94 70-130 1,1-Dichloroethene ug/L 50 47.0 94 70-130 1,2,3-Trichloropropane ug/L 50 50.1 100 70-130 1,2-Dibromo-3-chloropropane ug/L 50 49.4 99 70-130 1,2-Dibromoethane (EDB) ug/L 50 51.5 103 70-130 1,2-Dichlorobenzene ug/L 50 53.3 107 70-130 1,2-Dichloroethane ug/L 50 45.5 91 70-130 1,2-Dichloropropane ug/L 50 50.3 101 70-130 1,4-Dichlorobenzene ug/L 50 53.1 106 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1010 101 59-169 2-Butanone (MEK) ug/L 100 99.7 100 64-135 2-Hexanone ug/L 100 96.3 96 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 94.5 95 70-130 Acetone ug/L 100 107 107 61-157 Acrylonitrile ug/L 250 235 94 61-143 Benzene ug/L 50 48.3 97 70-130 Bromochloromethane ug/L 50 45.4 91 70-130 Bromodichloromethane ug/L 50 45.9 92 70-130 Bromoform ug/L 50 46.2 92 70-130 Bromomethane ug/L 50 35.9 72 38-130 Carbon disulfide ug/L 50 49.9 100 68-130 Carbon tetrachloride ug/L 50 45.0 90 70-130 Chlorobenzene ug/L 50 51.9 104 70-130 Chloroethane ug/L 50 36.2 72 37-142 Chloroform ug/L 50 46.1 92 70-130 Chloromethane ug/L 50 40.4 81 48-130 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/04/2020 12:05 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 23 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457585 LABORATORY CONTROL SAMPLE: Parameter 2766745 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,2-Dichloroethene ug/L 50 46.6 93 70-130 cis-1,3-Dichloropropene ug/L 50 51.7 103 70-130 Dibromochloromethane ug/L 50 48.6 97 70-130 Dibromomethane ug/L 50 48.8 98 70-130 Ethylbenzene ug/L 50 48.8 98 70-130 lodomethane ug/L 100 73.6 74 40-130 Methylene Chloride ug/L 50 45.0 90 67-132 Styrene ug/L 50 51.3 103 70-130 Tetrachloroethene ug/L 50 49.7 99 69-130 Toluene ug/L 50 45.1 90 70-130 trans-1,2-Dichloroethene ug/L 50 47.7 95 70-130 trans- 1,3-Dichloropropene ug/L 50 49.9 100 70-130 trans-1,4-Dichloro-2-butene ug/L 50 52.2 104 35-189 Trichloroethene ug/L 50 49.7 99 70-130 Trichlorofluoromethane ug/L 50 44.9 90 63-130 Vinyl acetate ug/L 100 107 107 55-143 Vinyl chloride ug/L 50 50.6 101 70-131 Xylene (Total) ug/L 150 144 96 70-130 1,2-Dichloroethane-d4 (S) % 85 70-130 4-Bromofluorobenzene (S) % 97 70-130 Toluene-d8 (S) % 98 70-130 MATRIX SPIKE SAMPLE: Parameter 2766746 Units 92457589001 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 20.0 100 73-134 1,1,1-Trichloroethane ug/L ND 20 19.2 96 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 20.0 100 70-136 1,1,2-Trichloroethane ug/L ND 20 19.9 100 70-135 1,1-Dichloroethane ug/L ND 20 20.1 101 70-139 1,1-Dichloroethene ug/L ND 20 20.3 101 70-154 1,2,3-Trichloropropane ug/L ND 20 20.4 102 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 17.1 86 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 20.7 103 70-137 1,2-Dichlorobenzene ug/L ND 20 20.9 104 70-133 1,2-Dichloroethane ug/L ND 20 19.2 96 70-137 1,2-Dichloropropane ug/L ND 20 20.8 104 70-140 1,4-Dichlorobenzene ug/L ND 20 20.9 105 70-133 1,4-Dioxane (p-Dioxane) ug/L ND 400 393 98 53-168 2-Butanone (MEK) ug/L ND 40 38.7 97 60-139 2-Hexanone ug/L ND 40 35.5 89 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 35.7 89 65-135 Acetone ug/L ND 40 37.2 93 60-148 Acrylonitrile ug/L ND 100 96.4 96 64-147 Benzene ug/L ND 20 20.3 102 70-151 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/04/2020 12:05 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 23 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457585 MATRIX SPIKE SAMPLE: 2766746 92457589001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Bromochloromethane ug/L ND 20 19.6 98 70-141 Bromodichloromethane ug/L ND 20 18.6 93 70-138 Bromoform ug/L ND 20 16.4 82 63-130 Bromomethane ug/L ND 20 19.2 96 15-152 Carbon disulfide ug/L ND 20 20.9 105 69-149 Carbon tetrachloride ug/L ND 20 19.5 97 70-143 Chlorobenzene ug/L ND 20 21.6 108 70-138 Chloroethane ug/L ND 20 19.9 100 52-163 Chloroform ug/L ND 20 20.0 100 70-139 Chloromethane ug/L ND 20 17.0 85 41-139 cis-1,2-Dichloroethene ug/L ND 20 19.6 98 70-141 cis-1,3-Dichloropropene ug/L ND 20 20.3 101 70-137 Dibromochloromethane ug/L ND 20 18.2 91 70-134 Dibromomethane ug/L ND 20 19.9 99 70-138 Ethylbenzene ug/L ND 20 20.6 103 66-153 lodomethane ug/L ND 40 20.5 51 20-138 Methylene Chloride ug/L ND 20 20.2 101 42-159 Styrene ug/L ND 20 21.0 105 70-135 Tetrachloroethene ug/L ND 20 20.5 102 59-143 Toluene ug/L ND 20 18.9 95 59-148 trans-1,2-Dichloroethene ug/L ND 20 20.7 103 70-146 trans- 1,3-Dichloropropene ug/L ND 20 19.4 97 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 19.8 99 47-135 Trichloroethene ug/L ND 20 21.2 106 70-147 Trichlorofluoromethane ug/L ND 20 20.4 102 70-148 Vinyl acetate ug/L ND 40 40.8 102 49-151 Vinyl chloride ug/L ND 20 21.9 109 70-156 Xylene (Total) ug/L ND 60 60.3 100 63-158 1,2-Dichloroethane-d4 (S) % 90 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 97 70-130 SAMPLE DUPLICATE: 2766747 Parameter Units 92457589006 Result Dup Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/04/2020 12:05 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 23 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92457585 SAMPLE DUPLICATE: 2766747 Parameter Units 92457589006 Result Dup Result RPD Max RPD 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 1,4-Dioxane (p-Dioxane) ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Acrylonitrile ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 30 Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 cis-1,2-Dichloroethene ug/L ND ND 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 lodomethane ug/L ND ND 30 Methylene Chloride ug/L ND ND 30 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 Vinyl acetate ug/L ND ND 30 Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L ND ND 30 1,2-Dichloroethane-d4 (S) % 100 95 4-Bromofluorobenzene (S) % 104 99 Toluene-d8 (S) % 108 101 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/04/2020 12:05 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 23 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Surry Co. Lined MSWLF Pace Project No.: 92457585 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/04/2020 12:05 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 23 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Surry Co. Lined MSWLF Pace Project No.: 92457585 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92457585001 MW-11 D EPA 3010A 515674 EPA 6010D 515694 92457585002 MW-11S EPA 3010A 515674 EPA 6010D 515694 92457585001 MW-11 D EPA 3010A 515676 EPA 6020B 515696 92457585002 MW-11S EPA 3010A 515676 EPA 6020B 515696 92457585001 MW-11D EPA 8260D 516391 92457585002 MW-11S EPA 8260D 516391 92457585004 SW-D EPA 8260D 516391 Date: 02/04/2020 12:05 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 23 Document Name: Document Revised: February 7, 2019 m CeAnalytical Sample Condition Upon Recelpt(SCUR) Page 1 of 2 Document No.: Issuing Authority: f F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville � Ralelgh❑ Mechanicsville❑ SampleClient Name: WO# : 92457585 Upon Receipt— — -- - I Pct �U l ! 15P5 jad i CI en�t�e Courier: ❑Fed Ex [:)UPS ❑U ❑ ❑ Commercial ace ❑Other: 92457585 Custody Seal Present? ❑Yes do Seats Intact? Oyes 210-- [ter Oate/Initials Person Examining Contents: Packing Material: ❑Butable Wrap 2<ubble Bags []None ❑ Other BlalOgiwl sue Frozen? Thermometer: ❑Yes No []N/A ID: 92TO58 Type of Ice: et ❑Blue ❑Ne e Cooler Temp VO L (� Correctlon Factor: Add/Subtract VC] QO°C �7, C Temp should be above freezing to 6'C Cooler Temp Corrected ('C): C > []Samples out of temp criteria. Samples on ice, cooling process hasbegun USDA Regulated Sail (E*N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally, ❑Yes 0fro including Hawaii and Puerto Rico)? UYes UNo Comments/Discrepancy: Chain of CustodyFresent7 Yes ❑No ❑N/A Samples Arrived within Hold Time? es ON. [--]N/A 2. Short Hold Time Analysis 1c72 hr.)? [7]Yes ONo rl N/A 3. Rush Turn Around Tim: Requested? ElYews o ❑N/A 4. SufficientVolume7 fires ❑No ❑N/A 5.. _ _ Correct Containers Used? -Pace Cont2'rers Used? 0< es ❑No ❑NO ❑N/A ❑N/A 6. Containers Intact? 21� ❑ND ❑N/A 7. Dissolved analysis: Samples Field Entered? []Yes []NO N/A a. ,ample La Ws. Match COC? -Includes D3te/Time/ID/Analysis Matrix:_ Elfes [:]No _ ❑N/A 9. Headspace in VOA Vials (>5-6mm)7 ❑Yes Fej<*_ ❑N/A 10. Trip Blank Present'? Trip Blank Custody Seals Present? Des ❑Yes ONn EIN,, El NIA /A 11, COMMENTS/SAMPLEEIDISCREPANCY Field DataRequtred7 []Yes ❑N,• i Lot ID of spilt containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Date/Time: _ Project Manager SCURF Review: _ �t/� Date: IA- Project Manager SRF Review: [ I ] Date: W —I ? `IC1 Page 21 of 23 Document Name: Dncument Revised: February 7, 2018 Sample Condition Upon Recelpt(SCUR) Page 1 of 2 � aceAnalytical Document No.: Issuing Authority: .11 F-CAR-CS-033-Rev,06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is Project # verified and within the acceptance range for preservatlon samples. Exceptions: VOA, CoVorm, TOC, Oil and Grease, ORO/8Di5 (water) DOC, LLHg *eottorn half of box is to Ilstnu— —mtWr of b6ttle- WQ#:92457585 PM: AMB Due Date: 12/31/19 CLIENT: 92—Municipal 0 .n d v Q = Q A n Gi = H z 2 2 a a! Z b 2 Z m N V x ;z03 = 2 'i = i a N V v 2 a ^i V z a v M a 2 Z Q 2 _ ? Y Q \ z U 0 ? N a N 2 M 7 a a 7 v D _ 0 ? u Q N Y Z m ' a a a _ S a c a c O N r O x g ¢ _ � z n} O ry Z a �t OQ en a `^ = a > a ii ry z z cL c � c a u ro a u m a �� a a a ro a a w a n Q n ¢ E 4 a E Q ❑ rev a C 0 s Q 4 O a M a M v N a E Q c E of E O In E M _ E o N E J E u1 N E N ry ``m w _ v E O Ui m l7 E O E O E P E O n ? E v, E O N E ❑ In E O E E O A E «a eY M � a N > M a M " a. PV � rl a. ii] 4 a fV rn a ry N It a. 1 V C a u fir. ry rl 0 rl S N Q ry M Q rir r1 0 N vi M tv a Q M U `f 2 m 0 r QL U a M 0 to I d in U Y D m Y U� r F N a �:. N a In C In a U �+ V 7 M 0 _ m m d i m m m m m d d d Q d Q ❑ 7 A ? > h ut m d , ❑ 4 1 \ 4 — S r-' N \\\\\]\I - - 10 - 11 12 pH Adjustment Log for Preserved Samples Sample 1D Type of Preservative r pH upon receipt Date preservatlon adjusted Time preservation adjusted Amwmt of Preservative added Lot Note: Whenever there is a discrepancy affecting North CarGlina compliance samples, a copy of this form will berent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 22 of 23 a s v s rn m a t w ITEM# a m=3 m 3 n 2 m � m = •e a y C'1 m w O rn ❑ J Y m CID ° q J— u] SD n. m A Np y x m 0 ❑ fV r a a m�e m o o CID o 3 5' M % x rom [CD 4 N @ U' s g O 0 [) l7 n A e O➢ Oyu an N m ? � '� O C 0H 3 a� Y O H O a AMATRIX CODE {see valid codes to left) Z Z .mn- c 1 = o SAMPLE TYPE {G=GRA6 C=COMP) l m n a CD m o - (� 1 a n m p C ❑ — a `" r RO - •. b m n0 Q Gam—] Y Z z Z 0 Z m z Y o m m TTnn m m 'ril W z Z 0 n N n G rn SAY , 1 m r- z SAMPLE TEMP AT COLLECTION M A N c M En to cn cn B OF CONTAINERS a cc) ➢ � Unpreserved � IT, H2SO4 # m o' 3 HNO3 @ m R m d 1 m s w w w ra HCI cc NaOHco Y 0 Na25203 rp Methanol rn m Other m Lo Analyses Test YIN y " m 2 x x x VOC S-App I r_ n' w x Mel -Di ❑ A m T 2 10 a 1,4-Oioxane(Non-SIM) p, ' n � w N eoo m = GOO I m m {p G NITRATE =� z` mPHOSPHORUS p Ph N m a of It r-) Sulfate TEMP in C m n s M Cn n a to Received on '- Ice (YIN) m n z l� ^ -r 1 J Guslody Sealed Cooler (YIN) 1r o O O z N -yti V n Samples Intact _ {YlNj = n m nn d z D r O m n 0 �c C m N m � °v o oy �m M , z f D � m c CD i! m CD a y w r-ti C ❑ O an IT n 3 0 U fU m � a IN C w m �c 1 C- Pa 23 of 23 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 March 19, 2020 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: Surry Co Lined MW10 Pace Project No.: 92468585 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on March 09, 2020. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, ft*OL-' Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Steven R. Gandy, Municipal Engineering Services Co. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 16 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Project: Surry Co Lined MW10 Pace Project No.: 92468585 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 South Carolina Certification #: 99006001 Louisiana/NELAP Certification # LA170028 Florida/NELAP Certification #: E87627 North Carolina Drinking Water Certification #: 37706 Kentucky UST Certification #: 84 North Carolina Field Services Certification #: 5342 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 12 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 16 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry Co Lined MW10 Pace Project No.: 92468585 Lab ID Sample ID 92468585001 MW-10 SAMPLE SUMMARY Matrix Date Collected Date Received Water 03/06/2010:27 03/09/2013:29 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 16 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Surry Co Lined MW10 Pace Project No.: 92468585 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92468585001 MW-10 EPA 8260D GAW 49 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 16 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MW10 Pace Project No.: 92468585 Sample: MW-10 Lab ID: 92468585001 Collected: 03/06/20 10:27 Received: 03/09/20 13:29 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Dibromochloromethane Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Date: 03/19/2020 02:54 PM Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 03/19/20 06:33 67-64-1 ND ug/L 10.0 0.90 1 03/19/20 06:33 107-13-1 0.67J ug/L 1.0 0.15 1 03/19/20 06:33 71-43-2 ND ug/L 1.0 0.34 1 03/19/20 06:33 74-97-5 ND ug/L 1.0 0.26 1 03/19/20 06:33 75-27-4 ND ug/L 1.0 0.62 1 03/19/20 06:33 75-25-2 ND ug/L 2.0 0.62 1 03/19/20 06:33 74-83-9 ND ug/L 5.0 3.3 1 03/19/20 06:33 78-93-3 ND ug/L 2.0 0.40 1 03/19/20 06:33 75-15-0 ND ug/L 1.0 0.22 1 03/19/20 06:33 56-23-5 ND ug/L 1.0 0.23 1 03/19/20 06:33 108-90-7 ND ug/L 1.0 0.49 1 03/19/20 06:33 75-00-3 ND ug/L 5.0 2.3 1 03/19/20 06:33 67-66-3 ND ug/L 1.0 0.39 1 03/19/20 06:33 74-87-3 ND ug/L 1.0 0.41 1 03/19/20 06:33 124-48-1 ND ug/L 1.0 0.46 1 03/19/20 06:33 74-95-3 ND ug/L 1.0 0.29 1 03/19/20 06:33 95-50-1 ND ug/L 1.0 0.26 1 03/19/20 06:33 106-46-7 ND ug/L 1.0 0.54 1 03/19/20 06:33 110-57-6 ND ug/L 1.0 0.27 1 03/19/20 06:33 75-34-3 ND ug/L 1.0 0.34 1 03/19/20 06:33 107-06-2 ND ug/L 1.0 0.24 1 03/19/20 06:33 75-35-4 0.991 ug/L 1.0 0.29 1 03/19/20 06:33 156-59-2 ND ug/L 1.0 0.25 1 03/19/20 06:33 156-60-5 ND ug/L 1.0 0.19 1 03/19/20 06:33 78-87-5 ND ug/L 1.0 0.30 1 03/19/20 06:33 10061-01-5 ND ug/L 1.0 0.31 1 03/19/20 06:33 10061-02-6 ND ug/L 150 56.2 1 03/19/20 06:33 123-91-1 ND ug/L 1.0 0.26 1 03/19/20 06:33 100-41-4 ND ug/L 5.0 0.57 1 03/19/20 06:33 591-78-6 ND ug/L 20.0 12.5 1 03/19/20 06:33 74-88-4 ND ug/L 5.0 3.7 1 03/19/20 06:33 75-09-2 ND ug/L 5.0 4.5 1 03/19/20 06:33 108-10-1 ND ug/L 1.0 0.27 1 03/19/20 06:33 100-42-5 ND ug/L 1.0 0.34 1 03/19/20 06:33 630-20-6 ND ug/L 1.0 0.22 1 03/19/20 06:33 79-34-5 ND ug/L 1.0 0.16 1 03/19/20 06:33 127-18-4 ND ug/L 1.0 0.24 1 03/19/20 06:33 108-88-3 ND ug/L 1.0 0.18 1 03/19/20 06:33 71-55-6 ND ug/L 1.0 0.24 1 03/19/20 06:33 79-00-5 ND ug/L 1.0 0.22 1 03/19/20 06:33 79-01-6 ND ug/L 1.0 0.31 1 03/19/20 06:33 75-69-4 ND ug/L 1.0 0.35 1 03/19/20 06:33 96-18-4 ND ug/L 2.0 1.4 1 03/19/20 06:33 108-05-4 ND ug/L 1.0 0.24 1 03/19/20 06:33 75-01-4 ND ug/L 1.0 0.63 1 03/19/20 06:33 1330-20-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v1 IK,v3 v1 v3 Page 5 of 16 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co Lined MW10 Pace Project No.: 92468585 Sample: MW-10 Lab ID: 92468585001 Collected: 03/06/20 10:27 Received: 03/09/20 13:29 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Surrogates 4-Bromofluorobenzene (S) 102 % 70-130 1 03/19/20 06:33 460-00-4 1,2-Dichloroethane-d4 (S) 91 % 70-130 1 03/19/20 06:33 17060-07-0 Toluene-d8 (S) 92 % 70-130 1 03/19/20 06:33 2037-26-5 Date: 03/19/2020 02:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 16 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MW10 Pace Project No.: 92468585 QC Batch: 531241 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Associated Lab Samples: 92468585001 METHOD BLANK: 2836484 Associated Lab Samples: 92468585001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 03/19/20 00:45 1,1,1-Trichloroethane ug/L ND 1.0 0.18 03/19/20 00:45 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 03/19/20 00:45 1,1,2-Trichloroethane ug/L ND 1.0 0.24 03/19/20 00:45 1,1-Dichloroethane ug/L ND 1.0 0.27 03/19/20 00:45 1,1-Dichloroethene ug/L ND 1.0 0.24 03/19/20 00:45 1,2,3-Trichloropropane ug/L ND 1.0 0.35 03/19/20 00:45 1,2-Dichlorobenzene ug/L ND 1.0 0.29 03/19/20 00:45 1,2-Dichloroethane ug/L ND 1.0 0.34 03/19/20 00:45 1,2-Dichloropropane ug/L ND 1.0 0.19 03/19/20 00:45 1,4-Dichlorobenzene ug/L ND 1.0 0.26 03/19/20 00:45 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 03/19/20 00:45 2-Butanone (MEK) ug/L ND 5.0 3.3 03/19/20 00:45 2-Hexanone ug/L ND 5.0 0.57 03/19/20 00:45 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 03/19/20 00:45 Acetone ug/L ND 25.0 6.2 03/19/20 00:45 Acrylonitrile ug/L ND 10.0 0.90 03/19/20 00:45 Benzene ug/L ND 1.0 0.15 03/19/20 00:45 Bromochloromethane ug/L ND 1.0 0.34 03/19/20 00:45 v3 Bromodichloromethane ug/L ND 1.0 0.26 03/19/20 00:45 Bromoform ug/L ND 1.0 0.62 03/19/20 00:45 Bromomethane ug/L ND 2.0 0.62 03/19/20 00:45 IH,IK Carbon disulfide ug/L ND 2.0 0.40 03/19/20 00:45 Carbon tetrachloride ug/L ND 1.0 0.22 03/19/20 00:45 Chlorobenzene ug/L ND 1.0 0.23 03/19/20 00:45 Chloroethane ug/L ND 1.0 0.49 03/19/20 00:45 Chloroform ug/L ND 5.0 2.3 03/19/20 00:45 Chloromethane ug/L ND 1.0 0.39 03/19/20 00:45 IK,v3 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 03/19/20 00:45 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 03/19/20 00:45 Dibromochloromethane ug/L ND 1.0 0.41 03/19/20 00:45 Dibromomethane ug/L ND 1.0 0.46 03/19/20 00:45 Ethylbenzene ug/L ND 1.0 0.26 03/19/20 00:45 lodomethane ug/L ND 20.0 12.5 03/19/20 00:45 Methylene Chloride ug/L ND 5.0 3.7 03/19/20 00:45 v3 Styrene ug/L ND 1.0 0.27 03/19/20 00:45 Tetrachloroethene ug/L ND 1.0 0.16 03/19/20 00:45 Toluene ug/L ND 1.0 0.24 03/19/20 00:45 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 03/19/20 00:45 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 03/19/20 00:45 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 03/19/20 00:45 v1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2020 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 16 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry Co Lined MW10 Pace Project No.: 92468585 METHOD BLANK: 2836484 Associated Lab Samples: 92468585001 Parameter Units Trichloroethene ug/L Trichlorofluoromethane ug/L Vinyl acetate ug/L Vinyl chloride ug/L Xylene (Total) ug/L 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % LABORATORY CONTROL SAMPLE: 2836485 QUALITY CONTROL DATA Matrix: Water Blank Result Reporting Limit ND 1.0 ND 1.0 ND 2.0 ND 1.0 ND 1.0 91 70-130 101 70-130 92 70-130 MDL Analyzed 0.22 03/19/20 00:45 0.31 03/19/20 00:45 1.4 03/19/20 00:45 0.24 03/19/20 00:45 0.63 03/19/20 00:45 03/19/20 00:45 03/19/20 00:45 03/19/20 00:45 Qualifiers Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 54.9 110 70-130 1,1,1-Trichloroethane ug/L 50 50.6 101 70-130 1,1,2,2-Tetrachloroethane ug/L 50 52.9 106 70-130 1,1,2-Trichloroethane ug/L 50 53.1 106 70-130 1,1-Dichloroethane ug/L 50 48.2 96 70-130 1,1-Dichloroethene ug/L 50 41.5 83 70-130 1,2,3-Trichloropropane ug/L 50 44.7 89 70-130 1,2-Dichlorobenzene ug/L 50 52.7 105 70-130 1,2-Dichloroethane ug/L 50 46.9 94 70-130 1,2-Dichloropropane ug/L 50 53.9 108 70-130 1,4-Dichlorobenzene ug/L 50 52.2 104 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1080 108 59-169 2-Butanone (MEK) ug/L 100 102 102 64-135 2-Hexanone ug/L 100 109 109 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 103 103 70-130 Acetone ug/L 100 99.0 99 61-157 Acrylonitrile ug/L 250 246 98 61-143 Benzene ug/L 50 53.0 106 70-130 Bromochloromethane ug/L 50 61.5 123 70-130 v1 Bromodichloromethane ug/L 50 51.0 102 70-130 Bromoform ug/L 50 51.5 103 70-130 Bromomethane ug/L 50 53.7 107 38-130lH,IK Carbon disulfide ug/L 50 44.8 90 68-130 Carbon tetrachloride ug/L 50 52.1 104 70-130 Chlorobenzene ug/L 50 52.2 104 70-130 Chloroethane ug/L 50 36.8 74 37-142 Chloroform ug/L 50 50.5 101 70-130 Chloromethane ug/L 50 41.3 83 48-130lK,v3 cis-1,2-Dichloroethene ug/L 50 47.4 95 70-130 cis-1,3-Dichloropropene ug/L 50 51.3 103 70-130 Dibromochloromethane ug/L 50 55.5 111 70-130 Dibromomethane ug/L 50 53.7 107 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2020 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 16 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MW10 Pace Project No.: 92468585 LABORATORY CONTROL SAMPLE: Parameter 2836485 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Ethylbenzene ug/L 50 50.8 102 70-130 lodomethane ug/L 100 105 105 40-130 Methylene Chloride ug/L 50 39.7 79 67-132 v3 Styrene ug/L 50 53.5 107 70-130 Tetrachloroethene ug/L 50 50.9 102 69-130 Toluene ug/L 50 47.6 95 70-130 trans-1,2-Dichloroethene ug/L 50 47.1 94 70-130 trans- 1,3-Dichloropropene ug/L 50 52.5 105 70-130 trans-1,4-Dichloro-2-butene ug/L 50 64.8 130 35-189 v1 Trichloroethene ug/L 50 51.1 102 70-130 Trichlorofluoromethane ug/L 50 42.1 84 63-130 Vinyl acetate ug/L 100 107 107 55-143 Vinyl chloride ug/L 50 52.6 105 70-131 Xylene (Total) ug/L 150 155 103 70-130 1,2-Dichloroethane-d4 (S) % 88 70-130 4-Bromofluorobenzene (S) % 102 70-130 Toluene-d8 (S) % 93 70-130 MATRIX SPIKE SAMPLE: 2836490 92468589005 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 22.8 114 73-134 1,1,1-Trichloroethane ug/L ND 20 21.8 109 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 21.5 108 70-136 1,1,2-Trichloroethane ug/L ND 20 21.7 109 70-135 1,1-Dichloroethane ug/L ND 20 20.4 102 70-139 1,1-Dichloroethene ug/L ND 20 18.0 90 70-154 1,2,3-Trichloropropane ug/L ND 20 20.7 104 71-137 1,2-Dichlorobenzene ug/L ND 20 22.3 111 70-133 1,2-Dichloroethane ug/L ND 20 19.9 99 70-137 1,2-Dichloropropane ug/L ND 20 22.4 112 70-140 1,4-Dichlorobenzene ug/L ND 20 21.1 106 70-133 1,4-Dioxane (p-Dioxane) ug/L ND 400 421 105 53-168 2-Butanone (MEK) ug/L ND 40 43.1 108 60-139 2-Hexanone ug/L ND 40 42.9 107 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 39.3 98 65-135 Acetone ug/L ND 40 42.1 105 60-148 Acrylonitrile ug/L ND 100 99.3 99 64-147 Benzene ug/L ND 20 22.9 114 70-151 Bromochloromethane ug/L ND 20 24.9 125 70-141 v1 Bromodichloromethane ug/L ND 20 21.2 106 70-138 Bromoform ug/L ND 20 20.3 101 63-130 Bromomethane ug/L ND 20 13.2 66 15-152 IH,IK Carbon disulfide ug/L ND 20 18.5 93 69-149 Carbon tetrachloride ug/L ND 20 22.5 112 70-143 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2020 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 16 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MW10 Pace Project No.: 92468585 MATRIX SPIKE SAMPLE: Parameter 2836490 Units 92468589005 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers Chlorobenzene ug/L ND 20 22.4 112 70-138 Chloroethane ug/L ND 20 18.9 95 52-163 Chloroform ug/L ND 20 21.5 107 70-139 Chloromethane ug/L ND 20 12.6 63 41-1391K,v3 cis-1,2-Dichloroethene ug/L ND 20 20.1 101 70-141 cis-1,3-Dichloropropene ug/L ND 20 19.2 96 70-137 Dibromochloromethane ug/L ND 20 22.5 113 70-134 Dibromomethane ug/L ND 20 22.9 115 70-138 Ethylbenzene ug/L ND 20 22.0 110 66-153 lodomethane ug/L ND 40 32.0 80 20-138 Methylene Chloride ug/L ND 20 17.2 86 42-159 v3 Styrene ug/L ND 20 22.8 114 70-135 Tetrachloroethene ug/L ND 20 21.4 107 59-143 Toluene ug/L ND 20 20.1 101 59-148 trans-1,2-Dichloroethene ug/L ND 20 19.6 98 70-146 trans- 1,3-Dichloropropene ug/L ND 20 18.5 92 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 14.8 74 47-135 v1 Trichloroethene ug/L ND 20 22.0 110 70-147 Trichlorofluoromethane ug/L ND 20 18.5 92 70-148 Vinyl acetate ug/L ND 40 26.9 67 49-151 Vinyl chloride ug/L ND 20 21.4 107 70-156 Xylene (Total) ug/L ND 60 66.7 111 63-158 1,2-Dichloroethane-d4 (S) % 97 70-130 4-Bromofluorobenzene (S) % 102 70-130 Toluene-d8 (S) % 92 70-130 SAMPLE DUPLICATE: 2836489 Parameter Units 92468589004 Result Dup Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropene ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 1,4-Dioxane (p-Dioxane) ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2020 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 16 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co Lined MW10 Pace Project No.: 92468585 SAMPLE DUPLICATE: 2836489 Parameter Units 92468589004 Result Dup Result Acrylonitrile ug/L ND ND Benzene ug/L ND ND Bromochloromethane ug/L ND ND Bromodichloromethane ug/L ND ND Bromoform ug/L ND ND Bromomethane ug/L ND ND Carbon disulfide ug/L ND ND Carbon tetrachloride ug/L ND ND Chlorobenzene ug/L ND ND Chloroethane ug/L ND ND Chloroform ug/L ND ND Chloromethane ug/L ND ND cis-1,2-Dichloroethene ug/L ND ND cis-1,3-Dichloropropene ug/L ND ND Dibromochloromethane ug/L ND ND Dibromomethane ug/L ND ND Ethylbenzene ug/L ND ND lodomethane ug/L ND ND Methylene Chloride ug/L ND ND Styrene ug/L ND ND Tetrachloroethene ug/L ND ND Toluene ug/L ND ND trans-1,2-Dichloroethene ug/L ND ND trans- 1,3-Dichloropropene ug/L ND ND trans-1,4-Dichloro-2-butene ug/L ND ND Trichloroethene ug/L ND ND Trichlorofluoromethane ug/L ND ND Vinyl acetate ug/L ND ND Vinyl chloride ug/L ND ND Xylene (Total) ug/L ND ND 1,2-Dichloroethane-d4 (S) % 94 94 4-Bromofluorobenzene (S) % 100 101 Toluene-d8 (S) % 95 93 Max RPD RPD Qualifiers 30 30 30 v3 30 30 30 IH,IK 30 30 30 30 30 30 I K,v3 30 30 30 30 30 30 30 v3 30 30 30 30 30 30 v1 30 30 30 30 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2020 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 16 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Surry Co Lined MW10 Pace Project No.: 92468585 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be considered an estimated value. IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2020 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 16 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Surry Co Lined MW10 Pace Project No.: 92468585 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92468585001 MW-10 EPA 8260D 531241 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2020 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 16 a0Analyt(Ca1 Document Name: Sample Conditlon Upon Receipt(SCUR) Document Revised: February 7, 2018 Page 1 of 2 Document No.: ssuingAuthority: rwn_r[ n3}Rev.065-- e-�rGUQd�-tiWauty-�f{iCfl Laboratory receiving samples; / Asheville ❑ Eden[]/ Greenwood ❑ Huntersville QRaleigh❑ Mechanicsvillal 1 Sample Condition Client Name: #: Wo# : 92468585 n_ Project Courier: ❑F rill� x UPS ❑LISPS []Clienttq2k4l li �� 11t11��i1�1 it ❑ Commercial Pace []Other: S�J 686 Custody Seal Present? ❑Yes [}IV,Z Seals intact? Packing Material: ❑Bubble Wrap -Bubble Bags ❑Yes Lira late/Initials Person EKamining Contents%�'-3— 7c ❑None ❑ Other Thermometer: 42,��6� Type of Ice: et ❑Blue IR Gun ID: Cooler Temp (°C): or(ection Factor: Add/Subtract (°C) 0,13 Cooler Temp Corrected {°C)i USDA Regulated Sall ( N/A, water sample) Did samples orlgi a fn a quarantine zoQe within the United States: CA, NY, or SC (check maps)7 Biological Tissue Frozen? ❑None []Yes PHb [:]N/A Temp should be above freezing to 6°C ❑samples out of temp criteria. Samples on ice, cooling process hastegun old samples originate from a foreign source (internationally, tncludlne Hawaii and Puerto Mail? ❑Yes ONO Comments/Discrepancy: 6ain of Custody Present?` ' Yes ❑Na ❑N/A I. Samples Arrived within (told Time? es ❑No ❑N/A 2. iShort HoldTime Analysis (<72'Kr.)? ❑Yes J260 ❑N/A 3, Rush Turn Around Time' Requested? ❑Yes o ❑N/A 4. Sufficient Volume? ! es No []N/A 5. Correct Containers Used? -Pace Containers Used? a ❑No []No ❑N/A ❑N/A G, Containers Intact? es ❑No []N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes ❑Na N/A g. Sample Labels Match COC2 -Includes Date/T1me/ID/Analysts Matrix: / es []NO ❑NIA 9. Headspace in VOA Vials (>5-5mm)7 ❑Yes ❑N/A 10. Trip Blank Present?, Trip Blank Custody Seals Present? ❑Yes ❑Yes J2<o [:]No ❑N/A [39 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers; CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review. Project Manager SRF Review: Date/Time; Date: Date: Field Data Required? ❑Yes [:]No Page 14 of 16 y aceAvlytica! Document Name: Sample Condition Upon Recelpt(SCUR) Document Revised: February 7, 2018 Page 1 of 2 _Document No.: Issuing Authority: F•CAR-CSM3-151ev.06 - P-aceCacalinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, 011 and Grease, ORO/Sb15 (water) DOC, WHE **Bottom half of box Is to list number of bottle Project # WQ# : 92468585 PM: AMB Due Date: 03/23/20 CLIENT: 92-Municipal al v `l a MS7 c, a E a cc 7/ a d c U a E N 7 6 go 4 d! y cx a E a 7 d 2 n m S 7 d m ,� V a M N u a E a m. V a M Z u a E o Z a 'M =O ro Ul u 4 z a E a eo u A av 2 O ? a E n a m 2 v to Ua E a }S ¢ OE Ili N a C j a 4 y = N U a 2 a V 4 4 e .s U 4 " � v 6 W E 4 E o Nr�-1 m l7 Q V Q C O ry = a 4 `m .+ t.7 a 2 a a 0 2 ¢ E o m l7 a x 41 E o m ery C7 a _ d 2 - 5 d O E 0 4n U d ? m Ory `^ ¢ OO en 10 5 _ d ?, a d >O E 0 a Q i _ d a = ¢ > E Vo ai Q d Z x ✓] rv7 N Y y Q. y O > ¢ Y = a > t n 9 ' t7 7 Q Z Ol w J E G'i 0. N Z 4 m a v w E o ry M N m Q O fJ x Z m a E In M a m Z a a c E d aE 0 d QJ Q ? m Y v c ,n E o r� Z Z m d a 6 E 0 CM 0 C 1 1 r% z NN 3 1 Fq \N 4 5 6 7 8 \ N N N NN 10 11 12 pH Adjustment log for Preserved Samples Sample to Type of Preservative pH upon receipt Date preservation adjusted Tlriae preservation adjusted Amount of Preservative added Lot d Note: Wheneverthere is a discrepancy atte[ling NOW] (-arotna compuance samples, d cuuv vi rl > Out of hold, Incorrect preservative, out of temp, incorrect containers Page15 of 16 ro r c 1. m ti m rn,� w w ITEM# �oa�om��gvi o � n Nop�ora�yvn � a a MATRIX CODE (see valid modes to left) SAMPLE TYPE (G=GRAB C=COMPp n m Cn a A � m O r a n m m (� m Z O m m SAMPLE TEMP AT COLLECTION a OF CONTAINERS Unpreserved H2SO4 HNO3 CD HCt m dl NaOH w Na2S203 w Methanol Other Analyses Test Y VOCs-5250 App I z 4,4-Dioxene (Non-SIM) z P in C !lved on "Ri Jdy Sealed ar(YIN) alas Inlac) O CT O 3. � P7Qmn' - 3 X a No (0m a cn m n m o � n N C7 n -- m 7 Z o ' �o m� m a rn r Er n 3� o` n �c /❑/�� m " m m O 6 °D KED 1,1 m v m CD D La m rn .Z] < IN n 7CD c a m Q A ' N a n e m CL j z N CL N C ❑ O 6 0 m C n 3 q a m rb m r-r CL w z d 1 S rn d 4 y p b so 1J1 L Page 16 of 16 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 February 07, 2020 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: Surry MSWLF SWs Pace Project No.: 92457589 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. A revised report is being generated on 2/7/2020 to remove results for sample 92457589005, per client request. If you have any questions concerning this report, please feel free to contact me. Sincerely, Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Steven R. Gandy, Municipal Engineering Services Co. Maddie German, Municipal Engineering Services REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 38 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry MSWLF SWs Pace Project No.: 92457589 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 38 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Surry MSWLF SWs Pace Project No.: 92457589 Lab ID Sample ID Matrix Date Collected Date Received 92457589001 SW-1 Water 12/12/19 12:10 12/16/19 08:30 92457589002 SW-2 Water 12/13/19 14:28 12/16/19 08:30 92457589003 SW-3 Water 12/13/19 15:08 12/16/19 08:30 92457589004 SW-4 Water 12/13/19 13:30 12/16/19 08:30 92457589006 SWN-2 Water 12/12/19 16:55 12/16/19 08:30 92457589007 SW-C Water 12/13/19 13:45 12/16/19 08:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 38 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Surry MSWLF SWs 92457589 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92457589001 SW-1 EPA 601 OD KQ 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92457589002 SW-2 EPA 601 OD KQ 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92457589003 SW-3 EPA 601 OD KQ 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92457589004 SW-4 EPA 601 OD KQ 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92457589006 SWN-2 EPA 601 OD KQ 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92457589007 SW-C EPA 601 OD KQ 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 38 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92457589 Sample: SW-1 Lab ID: 92457589001 Collected: 12/12/19 12:10 Received: 12/16/19 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 02/07/2020 11:46 AM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 12/24/19 01:21 12/25/19 00:18 7440-36-0 ND ug/L 10.0 4.7 1 12/24/19 01:21 12/25/19 00:18 7440-38-2 20.7 ug/L 5.0 1.0 1 12/24/19 01:21 12/25/19 00:18 7440-39-3 0.75J ug/L 1.0 0.20 1 12/24/19 01:21 12/25/19 00:18 7440-41-7 0.67J ug/L 1.0 0.40 1 12/24/19 01:21 12/25/19 00:18 7440-43-9 ND ug/L 5.0 1.0 1 12/24/19 01:21 12/25/19 00:18 7440-47-3 ND ug/L 5.0 1.1 1 12/24/19 01:21 12/25/19 00:18 7440-48-4 ND ug/L 5.0 2.1 1 12/24/19 01:21 12/25/19 00:18 7440-50-8 ND ug/L 5.0 1.6 1 12/24/19 01:21 12/25/19 00:18 7439-92-1 1.0J ug/L 5.0 0.90 1 12/24/19 01:21 12/25/19 00:18 7440-02-0 ND ug/L 10.0 4.7 1 12/24/19 01:21 12/25/19 00:18 7782-49-2 ND ug/L 5.0 2.5 1 12/24/19 01:21 12/25/19 00:18 7440-22-4 1.8J ug/L 5.0 1.3 1 12/24/19 01:21 12/25/19 00:18 7440-62-2 4.3J ug/L 10.0 3.9 1 12/24/19 01:21 12/25/19 00:18 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/24/19 02:04 12/30/19 15:54 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/23/1918:21 67-64-1 ND ug/L 10.0 0.90 1 12/23/1918:21 107-13-1 ND ug/L 1.0 0.15 1 12/23/1918:21 71-43-2 ND ug/L 1.0 0.34 1 12/23/1918:21 74-97-5 ND ug/L 1.0 0.26 1 12/23/1918:21 75-27-4 ND ug/L 1.0 0.62 1 12/23/1918:21 75-25-2 ND ug/L 2.0 0.62 1 12/23/1918:21 74-83-9 ND ug/L 5.0 3.3 1 12/23/1918:21 78-93-3 ND ug/L 2.0 0.40 1 12/23/1918:21 75-15-0 ND ug/L 1.0 0.22 1 12/23/1918:21 56-23-5 ND ug/L 1.0 0.23 1 12/23/1918:21 108-90-7 ND ug/L 1.0 0.49 1 12/23/1918:21 75-00-3 ND ug/L 5.0 2.3 1 12/23/1918:21 67-66-3 ND ug/L 1.0 0.39 1 12/23/1918:21 74-87-3 ND ug/L 5.0 0.26 1 12/23/1918:21 96-12-8 ND ug/L 1.0 0.41 1 12/23/1918:21 124-48-1 ND ug/L 1.0 0.26 1 12/23/1918:21 106-93-4 ND ug/L 1.0 0.46 1 12/23/1918:21 74-95-3 ND ug/L 1.0 0.29 1 12/23/1918:21 95-50-1 ND ug/L 1.0 0.26 1 12/23/1918:21 106-46-7 ND ug/L 1.0 0.54 1 12/23/1918:21 110-57-6 ND ug/L 1.0 0.27 1 12/23/1918:21 75-34-3 ND ug/L 1.0 0.34 1 12/23/1918:21 107-06-2 ND ug/L 1.0 0.24 1 12/23/1918:21 75-35-4 ND ug/L 1.0 0.29 1 12/23/1918:21 156-59-2 ND ug/L 1.0 0.25 1 12/23/1918:21 156-60-5 ND ug/L 1.0 0.19 1 12/23/1918:21 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 38 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92457589 Sample: SW-1 Lab ID: 92457589001 Collected: 12/12/19 12:10 Received: 12/16/19 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/23/19 18:21 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/23/19 18:21 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/23/19 18:21 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/23/19 18:21 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/23/19 18:21 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/23/19 18:21 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/23/19 18:21 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/23/19 18:21 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/23/19 18:21 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/23/19 18:21 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/23/19 18:21 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/23/19 18:21 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/23/19 18:21 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/23/19 18:21 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/23/19 18:21 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/23/19 18:21 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/23/19 18:21 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/23/19 18:21 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/23/19 18:21 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/23/19 18:21 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/23/19 18:21 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 101 % 70-130 1 12/23/19 18:21 460-00-4 1,2-Dichloroethane-d4 (S) 97 % 70-130 1 12/23/19 18:21 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 12/23/19 18:21 2037-26-5 Date: 02/07/2020 11:46 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 38 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92457589 Sample: SW-2 Lab ID: 92457589002 Collected: 12/13/19 14:28 Received: 12/16/19 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.0 1 12/24/19 01:21 12/24/19 22:47 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 12/24/19 01:21 12/24/19 22:47 7440-38-2 Barium 18.8 ug/L 5.0 1.0 1 12/24/19 01:21 12/24/19 22:47 7440-39-3 Beryllium 0.20J ug/L 1.0 0.20 1 12/24/19 01:21 12/24/19 22:47 7440-41-7 B Cadmium 0.811 ug/L 1.0 0.40 1 12/24/19 01:21 12/24/19 22:47 7440-43-9 Chromium ND ug/L 5.0 1.0 1 12/24/19 01:21 12/24/19 22:47 7440-47-3 Cobalt 21.3 ug/L 5.0 1.1 1 12/24/19 01:21 12/24/19 22:47 7440-48-4 Copper ND ug/L 5.0 2.1 1 12/24/19 01:21 12/24/19 22:47 7440-50-8 Lead ND ug/L 5.0 1.6 1 12/24/19 01:21 12/24/19 22:47 7439-92-1 Nickel ND ug/L 5.0 0.90 1 12/24/19 01:21 12/24/19 22:47 7440-02-0 Selenium ND ug/L 10.0 4.7 1 12/24/19 01:21 12/24/19 22:47 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/24/19 01:21 12/24/19 22:47 7440-22-4 Vanadium ND ug/L 5.0 1.3 1 12/24/19 01:21 12/24/19 22:47 7440-62-2 Zinc 4.8J ug/L 10.0 3.9 1 12/24/19 01:21 12/24/19 22:47 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/24/19 02:04 12/30/19 18:19 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Acetone ND ug/L 25.0 6.2 1 12/24/19 00:54 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 12/24/19 00:54 107-13-1 Benzene ND ug/L 1.0 0.15 1 12/24/19 00:54 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 12/24/19 00:54 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 12/24/19 00:54 75-27-4 Bromoform ND ug/L 1.0 0.62 1 12/24/19 00:54 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 12/24/19 00:54 74-83-9 v2 2-Butanone (MEK) ND ug/L 5.0 3.3 1 12/24/19 00:54 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 12/24/19 00:54 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 12/24/19 00:54 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 12/24/19 00:54 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 12/24/19 00:54 75-00-3 v2 Chloroform ND ug/L 5.0 2.3 1 12/24/19 00:54 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 12/24/19 00:54 74-87-3 v2 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 12/24/19 00:54 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 12/24/19 00:54 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 12/24/19 00:54 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 12/24/19 00:54 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 12/24/19 00:54 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 12/24/19 00:54 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 12/24/19 00:54 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 12/24/19 00:54 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 12/24/19 00:54 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 12/24/19 00:54 75-35-4 cis-1,2-Dichloroethene 3.0 ug/L 1.0 0.29 1 12/24/19 00:54 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.25 1 12/24/19 00:54 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.19 1 12/24/19 00:54 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2020 11:46 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 38 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92457589 Sample: SW-2 Lab ID: 92457589002 Collected: 12/13/19 14:28 Received: 12/16/19 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/24/19 00:54 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/24/19 00:54 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/24/19 00:54 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/24/19 00:54 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/24/19 00:54 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/24/19 00:54 74-88-4 v2 Methylene Chloride ND ug/L 5.0 3.7 1 12/24/19 00:54 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/24/19 00:54 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/24/19 00:54 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/24/19 00:54 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/24/19 00:54 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/24/19 00:54 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/24/19 00:54 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/24/19 00:54 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/24/19 00:54 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/24/19 00:54 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/24/19 00:54 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/24/19 00:54 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/24/19 00:54 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/24/19 00:54 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/24/19 00:54 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 102 % 70-130 1 12/24/19 00:54 460-00-4 1,2-Dichloroethane-d4 (S) 100 % 70-130 1 12/24/19 00:54 17060-07-0 Toluene-d8 (S) 101 % 70-130 1 12/24/19 00:54 2037-26-5 Date: 02/07/2020 11:46 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 38 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92457589 Sample: SW-3 Lab ID: 92457589003 Collected: 12/13/19 15:08 Received: 12/16/19 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.0 1 12/24/19 01:21 12/24/19 22:59 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 12/24/19 01:21 12/24/19 22:59 7440-38-2 Barium 26.4 ug/L 5.0 1.0 1 12/24/19 01:21 12/24/19 22:59 7440-39-3 Beryllium 0.31J ug/L 1.0 0.20 1 12/24/19 01:21 12/24/19 22:59 7440-41-7 B Cadmium 0.56J ug/L 1.0 0.40 1 12/24/19 01:21 12/24/19 22:59 7440-43-9 Chromium ND ug/L 5.0 1.0 1 12/24/19 01:21 12/24/19 22:59 7440-47-3 Cobalt 1.4J ug/L 5.0 1.1 1 12/24/19 01:21 12/24/19 22:59 7440-48-4 Copper 3.1J ug/L 5.0 2.1 1 12/24/19 01:21 12/24/19 22:59 7440-50-8 Lead ND ug/L 5.0 1.6 1 12/24/19 01:21 12/24/19 22:59 7439-92-1 Nickel ND ug/L 5.0 0.90 1 12/24/19 01:21 12/24/19 22:59 7440-02-0 Selenium ND ug/L 10.0 4.7 1 12/24/19 01:21 12/24/19 22:59 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/24/19 01:21 12/24/19 22:59 7440-22-4 Vanadium 3.5J ug/L 5.0 1.3 1 12/24/19 01:21 12/24/19 22:59 7440-62-2 Zinc 11.7 ug/L 10.0 3.9 1 12/24/19 01:21 12/24/19 22:59 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/24/19 02:04 12/30/19 18:27 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Acetone ND ug/L 25.0 6.2 1 12/24/19 01:12 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 12/24/19 01:12 107-13-1 Benzene ND ug/L 1.0 0.15 1 12/24/19 01:12 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 12/24/19 01:12 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 12/24/19 01:12 75-27-4 Bromoform ND ug/L 1.0 0.62 1 12/24/19 01:12 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 12/24/19 01:12 74-83-9 v2 2-Butanone (MEK) ND ug/L 5.0 3.3 1 12/24/19 01:12 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 12/24/19 01:12 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 12/24/19 01:12 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 12/24/19 01:12 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 12/24/19 01:12 75-00-3 v2 Chloroform ND ug/L 5.0 2.3 1 12/24/19 01:12 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 12/24/19 01:12 74-87-3 v2 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 12/24/19 01:12 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 12/24/19 01:12 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 12/24/19 01:12 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 12/24/19 01:12 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 12/24/19 01:12 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 12/24/19 01:12 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 12/24/19 01:12 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 12/24/19 01:12 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 12/24/19 01:12 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 12/24/19 01:12 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.29 1 12/24/19 01:12 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.25 1 12/24/19 01:12 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.19 1 12/24/19 01:12 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2020 11:46 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 38 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92457589 Sample: SW-3 Lab ID: 92457589003 Collected: 12/13/19 15:08 Received: 12/16/19 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/24/19 01:12 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/24/19 01:12 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/24/19 01:12 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/24/19 01:12 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/24/19 01:12 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/24/19 01:12 74-88-4 v2 Methylene Chloride ND ug/L 5.0 3.7 1 12/24/19 01:12 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/24/19 01:12 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/24/19 01:12 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/24/19 01:12 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/24/19 01:12 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/24/19 01:12 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/24/19 01:12 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/24/19 01:12 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/24/19 01:12 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/24/19 01:12 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/24/19 01:12 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/24/19 01:12 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/24/19 01:12 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/24/19 01:12 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/24/19 01:12 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 100 % 70-130 1 12/24/19 01:12 460-00-4 1,2-Dichloroethane-d4 (S) 100 % 70-130 1 12/24/19 01:12 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 12/24/19 01:12 2037-26-5 Date: 02/07/2020 11:46 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 38 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92457589 Sample: SW-4 Lab ID: 92457589004 Collected: 12/13/19 13:30 Received: 12/16/19 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 02/07/2020 11:46 AM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 12/24/19 01:21 12/24/19 23:03 7440-36-0 ND ug/L 10.0 4.7 1 12/24/19 01:21 12/24/19 23:03 7440-38-2 27.2 ug/L 5.0 1.0 1 12/24/19 01:21 12/24/19 23:03 7440-39-3 0.41J ug/L 1.0 0.20 1 12/24/19 01:21 12/24/19 23:03 7440-41-7 ND ug/L 1.0 0.40 1 12/24/19 01:21 12/24/19 23:03 7440-43-9 ND ug/L 5.0 1.0 1 12/24/19 01:21 12/24/19 23:03 7440-47-3 1.2J ug/L 5.0 1.1 1 12/24/19 01:21 12/24/19 23:03 7440-48-4 ND ug/L 5.0 2.1 1 12/24/19 01:21 12/24/19 23:03 7440-50-8 ND ug/L 5.0 1.6 1 12/24/19 01:21 12/24/19 23:03 7439-92-1 1.1J ug/L 5.0 0.90 1 12/24/19 01:21 12/24/19 23:03 7440-02-0 ND ug/L 10.0 4.7 1 12/24/19 01:21 12/24/19 23:03 7782-49-2 ND ug/L 5.0 2.5 1 12/24/19 01:21 12/24/19 23:03 7440-22-4 2.OJ ug/L 5.0 1.3 1 12/24/19 01:21 12/24/19 23:03 7440-62-2 8.3J ug/L 10.0 3.9 1 12/24/19 01:21 12/24/19 23:03 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/24/19 02:04 12/30/19 18:58 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/24/19 01:30 67-64-1 ND ug/L 10.0 0.90 1 12/24/19 01:30 107-13-1 ND ug/L 1.0 0.15 1 12/24/19 01:30 71-43-2 ND ug/L 1.0 0.34 1 12/24/19 01:30 74-97-5 ND ug/L 1.0 0.26 1 12/24/19 01:30 75-27-4 ND ug/L 1.0 0.62 1 12/24/19 01:30 75-25-2 ND ug/L 2.0 0.62 1 12/24/19 01:30 74-83-9 ND ug/L 5.0 3.3 1 12/24/19 01:30 78-93-3 ND ug/L 2.0 0.40 1 12/24/19 01:30 75-15-0 ND ug/L 1.0 0.22 1 12/24/19 01:30 56-23-5 ND ug/L 1.0 0.23 1 12/24/19 01:30 108-90-7 ND ug/L 1.0 0.49 1 12/24/19 01:30 75-00-3 ND ug/L 5.0 2.3 1 12/24/19 01:30 67-66-3 ND ug/L 1.0 0.39 1 12/24/19 01:30 74-87-3 ND ug/L 5.0 0.26 1 12/24/19 01:30 96-12-8 ND ug/L 1.0 0.41 1 12/24/19 01:30 124-48-1 ND ug/L 1.0 0.26 1 12/24/19 01:30 106-93-4 ND ug/L 1.0 0.46 1 12/24/19 01:30 74-95-3 ND ug/L 1.0 0.29 1 12/24/19 01:30 95-50-1 ND ug/L 1.0 0.26 1 12/24/19 01:30 106-46-7 ND ug/L 1.0 0.54 1 12/24/19 01:30 110-57-6 ND ug/L 1.0 0.27 1 12/24/19 01:30 75-34-3 ND ug/L 1.0 0.34 1 12/24/19 01:30 107-06-2 ND ug/L 1.0 0.24 1 12/24/19 01:30 75-35-4 ND ug/L 1.0 0.29 1 12/24/19 01:30 156-59-2 ND ug/L 1.0 0.25 1 12/24/19 01:30 156-60-5 ND ug/L 1.0 0.19 1 12/24/19 01:30 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. B v2 v2 v2 Page 11 of 38 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92457589 Sample: SW-4 Lab ID: 92457589004 Collected: 12/13/19 13:30 Received: 12/16/19 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/24/19 01:30 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/24/19 01:30 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/24/19 01:30 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/24/19 01:30 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/24/19 01:30 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/24/19 01:30 74-88-4 v2 Methylene Chloride ND ug/L 5.0 3.7 1 12/24/19 01:30 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/24/19 01:30 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/24/19 01:30 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/24/19 01:30 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/24/19 01:30 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/24/19 01:30 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/24/19 01:30 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/24/19 01:30 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/24/19 01:30 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/24/19 01:30 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/24/19 01:30 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/24/19 01:30 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/24/19 01:30 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/24/19 01:30 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/24/19 01:30 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 102 % 70-130 1 12/24/19 01:30 460-00-4 1,2-Dichloroethane-d4 (S) 97 % 70-130 1 12/24/19 01:30 17060-07-0 Toluene-d8 (S) 101 % 70-130 1 12/24/19 01:30 2037-26-5 Date: 02/07/2020 11:46 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 38 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92457589 Sample: SWN-2 Lab ID: 92457589006 Collected: 12/12/19 16:55 Received: 12/16/19 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 02/07/2020 11:46 AM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 12/24/19 01:21 12/24/19 23:09 7440-36-0 ND ug/L 10.0 4.7 1 12/24/19 01:21 12/24/19 23:09 7440-38-2 17.2 ug/L 5.0 1.0 1 12/24/19 01:21 12/24/19 23:09 7440-39-3 ND ug/L 1.0 0.20 1 12/24/19 01:21 12/24/19 23:09 7440-41-7 ND ug/L 1.0 0.40 1 12/24/19 01:21 12/24/19 23:09 7440-43-9 ND ug/L 5.0 1.0 1 12/24/19 01:21 12/24/19 23:09 7440-47-3 1.5J ug/L 5.0 1.1 1 12/24/19 01:21 12/24/19 23:09 7440-48-4 ND ug/L 5.0 2.1 1 12/24/19 01:21 12/24/19 23:09 7440-50-8 ND ug/L 5.0 1.6 1 12/24/19 01:21 12/24/19 23:09 7439-92-1 ND ug/L 5.0 0.90 1 12/24/19 01:21 12/24/19 23:09 7440-02-0 ND ug/L 10.0 4.7 1 12/24/19 01:21 12/24/19 23:09 7782-49-2 ND ug/L 5.0 2.5 1 12/24/19 01:21 12/24/19 23:09 7440-22-4 ND ug/L 5.0 1.3 1 12/24/19 01:21 12/24/19 23:09 7440-62-2 ND ug/L 10.0 3.9 1 12/24/19 01:21 12/24/19 23:09 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/24/19 02:04 12/30/19 19:10 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/23/1918:39 67-64-1 ND ug/L 10.0 0.90 1 12/23/1918:39 107-13-1 ND ug/L 1.0 0.15 1 12/23/1918:39 71-43-2 ND ug/L 1.0 0.34 1 12/23/1918:39 74-97-5 ND ug/L 1.0 0.26 1 12/23/1918:39 75-27-4 ND ug/L 1.0 0.62 1 12/23/1918:39 75-25-2 ND ug/L 2.0 0.62 1 12/23/1918:39 74-83-9 ND ug/L 5.0 3.3 1 12/23/1918:39 78-93-3 ND ug/L 2.0 0.40 1 12/23/1918:39 75-15-0 ND ug/L 1.0 0.22 1 12/23/1918:39 56-23-5 ND ug/L 1.0 0.23 1 12/23/1918:39 108-90-7 ND ug/L 1.0 0.49 1 12/23/1918:39 75-00-3 ND ug/L 5.0 2.3 1 12/23/1918:39 67-66-3 ND ug/L 1.0 0.39 1 12/23/1918:39 74-87-3 ND ug/L 5.0 0.26 1 12/23/1918:39 96-12-8 ND ug/L 1.0 0.41 1 12/23/1918:39 124-48-1 ND ug/L 1.0 0.26 1 12/23/1918:39 106-93-4 ND ug/L 1.0 0.46 1 12/23/1918:39 74-95-3 ND ug/L 1.0 0.29 1 12/23/1918:39 95-50-1 ND ug/L 1.0 0.26 1 12/23/1918:39 106-46-7 ND ug/L 1.0 0.54 1 12/23/1918:39 110-57-6 ND ug/L 1.0 0.27 1 12/23/1918:39 75-34-3 ND ug/L 1.0 0.34 1 12/23/1918:39 107-06-2 ND ug/L 1.0 0.24 1 12/23/1918:39 75-35-4 ND ug/L 1.0 0.29 1 12/23/1918:39 156-59-2 ND ug/L 1.0 0.25 1 12/23/1918:39 156-60-5 ND ug/L 1.0 0.19 1 12/23/1918:39 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 38 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92457589 Sample: SWN-2 Lab ID: 92457589006 Collected: 12/12/19 16:55 Received: 12/16/19 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/23/19 18:39 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/23/19 18:39 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/23/19 18:39 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/23/19 18:39 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/23/19 18:39 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/23/19 18:39 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/23/19 18:39 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/23/19 18:39 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/23/19 18:39 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/23/19 18:39 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/23/19 18:39 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/23/19 18:39 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/23/19 18:39 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/23/19 18:39 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/23/19 18:39 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/23/19 18:39 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/23/19 18:39 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/23/19 18:39 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/23/19 18:39 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/23/19 18:39 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/23/19 18:39 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 104 % 70-130 1 12/23/19 18:39 460-00-4 1,2-Dichloroethane-d4 (S) 100 % 70-130 1 12/23/19 18:39 17060-07-0 Toluene-d8 (S) 108 % 70-130 1 12/23/19 18:39 2037-26-5 Date: 02/07/2020 11:46 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 38 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92457589 Sample: SW-C Lab ID: 92457589007 Collected: 12/13/19 13:45 Received: 12/16/19 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 02/07/2020 11:46 AM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 12/24/19 01:21 12/24/19 23:12 7440-36-0 ND ug/L 10.0 4.7 1 12/24/19 01:21 12/24/19 23:12 7440-38-2 26.0 ug/L 5.0 1.0 1 12/24/19 01:21 12/24/19 23:12 7440-39-3 0.45J ug/L 1.0 0.20 1 12/24/19 01:21 12/24/19 23:12 7440-41-7 ND ug/L 1.0 0.40 1 12/24/19 01:21 12/24/19 23:12 7440-43-9 ND ug/L 5.0 1.0 1 12/24/19 01:21 12/24/19 23:12 7440-47-3 ND ug/L 5.0 1.1 1 12/24/19 01:21 12/24/19 23:12 7440-48-4 ND ug/L 5.0 2.1 1 12/24/19 01:21 12/24/19 23:12 7440-50-8 ND ug/L 5.0 1.6 1 12/24/19 01:21 12/24/19 23:12 7439-92-1 ND ug/L 5.0 0.90 1 12/24/19 01:21 12/24/19 23:12 7440-02-0 ND ug/L 10.0 4.7 1 12/24/19 01:21 12/24/19 23:12 7782-49-2 ND ug/L 5.0 2.5 1 12/24/19 01:21 12/24/19 23:12 7440-22-4 2.5J ug/L 5.0 1.3 1 12/24/19 01:21 12/24/19 23:12 7440-62-2 7.5J ug/L 10.0 3.9 1 12/24/19 01:21 12/24/19 23:12 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/24/19 02:04 12/30/19 19:14 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/24/19 02:05 67-64-1 ND ug/L 10.0 0.90 1 12/24/19 02:05 107-13-1 ND ug/L 1.0 0.15 1 12/24/19 02:05 71-43-2 ND ug/L 1.0 0.34 1 12/24/19 02:05 74-97-5 ND ug/L 1.0 0.26 1 12/24/19 02:05 75-27-4 ND ug/L 1.0 0.62 1 12/24/19 02:05 75-25-2 ND ug/L 2.0 0.62 1 12/24/19 02:05 74-83-9 ND ug/L 5.0 3.3 1 12/24/19 02:05 78-93-3 ND ug/L 2.0 0.40 1 12/24/19 02:05 75-15-0 ND ug/L 1.0 0.22 1 12/24/19 02:05 56-23-5 ND ug/L 1.0 0.23 1 12/24/19 02:05 108-90-7 ND ug/L 1.0 0.49 1 12/24/19 02:05 75-00-3 ND ug/L 5.0 2.3 1 12/24/19 02:05 67-66-3 ND ug/L 1.0 0.39 1 12/24/19 02:05 74-87-3 ND ug/L 5.0 0.26 1 12/24/19 02:05 96-12-8 ND ug/L 1.0 0.41 1 12/24/19 02:05 124-48-1 ND ug/L 1.0 0.26 1 12/24/19 02:05 106-93-4 ND ug/L 1.0 0.46 1 12/24/19 02:05 74-95-3 ND ug/L 1.0 0.29 1 12/24/19 02:05 95-50-1 ND ug/L 1.0 0.26 1 12/24/19 02:05 106-46-7 ND ug/L 1.0 0.54 1 12/24/19 02:05 110-57-6 ND ug/L 1.0 0.27 1 12/24/19 02:05 75-34-3 ND ug/L 1.0 0.34 1 12/24/19 02:05 107-06-2 ND ug/L 1.0 0.24 1 12/24/19 02:05 75-35-4 ND ug/L 1.0 0.29 1 12/24/19 02:05 156-59-2 ND ug/L 1.0 0.25 1 12/24/19 02:05 156-60-5 ND ug/L 1.0 0.19 1 12/24/19 02:05 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. B v2 v2 v2 Page 15 of 38 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92457589 Sample: SW-C Lab ID: 92457589007 Collected: 12/13/19 13:45 Received: 12/16/19 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/24/19 02:05 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/24/19 02:05 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/24/19 02:05 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/24/19 02:05 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/24/19 02:05 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/24/19 02:05 74-88-4 v2 Methylene Chloride ND ug/L 5.0 3.7 1 12/24/19 02:05 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/24/19 02:05 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/24/19 02:05 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/24/19 02:05 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/24/19 02:05 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/24/19 02:05 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/24/19 02:05 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/24/19 02:05 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/24/19 02:05 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/24/19 02:05 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/24/19 02:05 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/24/19 02:05 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/24/19 02:05 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/24/19 02:05 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/24/19 02:05 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 100 % 70-130 1 12/24/19 02:05 460-00-4 1,2-Dichloroethane-d4 (S) 101 % 70-130 1 12/24/19 02:05 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 12/24/19 02:05 2037-26-5 Date: 02/07/2020 11:46 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 38 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry MSWLF SWs Pace Project No.: 92457589 QC Batch: 516496 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92457589001 METHOD BLANK: 2767363 Associated Lab Samples: 92457589001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 5.0 3.0 12/25/19 00:12 Arsenic ug/L ND 10.0 4.7 12/25/19 00:12 Barium ug/L ND 5.0 1.0 12/25/19 00:12 Beryllium ug/L ND 1.0 0.20 12/25/19 00:12 Cadmium ug/L ND 1.0 0.40 12/25/19 00:12 Chromium ug/L ND 5.0 1.0 12/25/19 00:12 Cobalt ug/L ND 5.0 1.1 12/25/19 00:12 Copper ug/L ND 5.0 2.1 12/25/19 00:12 Lead ug/L ND 5.0 1.6 12/25/19 00:12 Nickel ug/L ND 5.0 0.90 12/25/19 00:12 Selenium ug/L ND 10.0 4.7 12/25/19 00:12 Silver ug/L ND 5.0 2.5 12/25/19 00:12 Vanadium ug/L ND 5.0 1.3 12/25/19 00:12 Zinc ug/L ND 10.0 3.9 12/25/19 00:12 LABORATORY CONTROL SAMPLE: Parameter 2767364 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 501 100 80-120 Arsenic ug/L 500 503 101 80-120 Barium ug/L 500 498 100 80-120 Beryllium ug/L 500 497 99 80-120 Cadmium ug/L 500 498 100 80-120 Chromium ug/L 500 498 100 80-120 Cobalt ug/L 500 498 100 80-120 Copper ug/L 500 504 101 80-120 Lead ug/L 500 502 100 80-120 Nickel ug/L 500 498 100 80-120 Selenium ug/L 500 492 98 80-120 Silver ug/L 250 250 100 80-120 Vanadium ug/L 500 495 99 80-120 Zinc ug/L 500 486 97 80-120 Qualifiers Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2767365 2767366 MS MSD 92457589001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 523 517 105 103 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2020 11:46 AM without the written consent of Pace Analytical Services, LLC. Page 17 of 38 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Surry MSWLF SWs 92457589 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2767365 2767366 MS MSD 92457589001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L ND 500 500 530 518 106 103 75-125 2 20 Barium ug/L 20.7 500 500 532 523 102 101 75-125 2 20 Beryllium ug/L 0.75J 500 500 510 502 102 100 75-125 2 20 Cadmium ug/L 0.67J 500 500 524 518 105 104 75-125 1 20 Chromium ug/L ND 500 500 518 509 103 102 75-125 2 20 Cobalt ug/L ND 500 500 514 508 103 101 75-125 1 20 Copper ug/L ND 500 500 515 510 103 102 75-125 1 20 Lead ug/L ND 500 500 519 511 104 102 75-125 1 20 Nickel ug/L 1.01 500 500 514 509 103 102 75-125 1 20 Selenium ug/L ND 500 500 540 534 108 107 75-125 1 20 Silver ug/L ND 250 250 258 255 103 102 75-125 1 20 Vanadium ug/L 1.8J 500 500 513 506 102 101 75-125 1 20 Zinc ug/L 4.3J 500 500 519 512 103 102 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2020 11:46 AM without the written consent of Pace Analytical Services, LLC. Page 18 of 38 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry MSWLF SWs Pace Project No.: 92457589 QC Batch: 516498 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92457589002, 92457589003, 92457589004, 92457589006, 92457589007 METHOD BLANK: 2767371 Matrix: Water Associated Lab Samples: 92457589002, 92457589003, 92457589004, 92457589006, 92457589007 Blank Reporting Parameter Units Result Limit MDL Analyzed Antimony ug/L ND 5.0 3.0 12/24/19 22:28 Arsenic ug/L ND 10.0 4.7 12/24/19 22:28 Barium ug/L ND 5.0 1.0 12/24/19 22:28 Beryllium ug/L 0.25J 1.0 0.20 12/24/19 22:28 Cadmium ug/L ND 1.0 0.40 12/24/19 22:28 Chromium ug/L ND 5.0 1.0 12/24/19 22:28 Cobalt ug/L ND 5.0 1.1 12/24/19 22:28 Copper ug/L ND 5.0 2.1 12/24/19 22:28 Lead ug/L ND 5.0 1.6 12/24/19 22:28 Nickel ug/L ND 5.0 0.90 12/24/19 22:28 Selenium ug/L ND 10.0 4.7 12/24/19 22:28 Silver ug/L ND 5.0 2.5 12/24/19 22:28 Vanadium ug/L ND 5.0 1.3 12/24/19 22:28 Zinc ug/L ND 10.0 3.9 12/24/19 22:28 LABORATORY CONTROL SAMPLE: Parameter 2767372 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 502 100 80-120 Arsenic ug/L 500 503 101 80-120 Barium ug/L 500 480 96 80-120 Beryllium ug/L 500 479 96 80-120 Cadmium ug/L 500 488 98 80-120 Chromium ug/L 500 483 97 80-120 Cobalt ug/L 500 491 98 80-120 Copper ug/L 500 491 98 80-120 Lead ug/L 500 494 99 80-120 Nickel ug/L 500 487 97 80-120 Selenium ug/L 500 487 97 80-120 Silver ug/L 250 244 97 80-120 Vanadium ug/L 500 483 97 80-120 Zinc ug/L 500 481 96 80-120 Qualifiers Qualifiers MS MSD 92457589002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 524 519 105 104 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2020 11:46 AM without the written consent of Pace Analytical Services, LLC. Page 19 of 38 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Surry MSWLF SWs 92457589 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2767373 2767374 MS MSD 92457589002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L ND 500 500 538 526 107 105 75-125 2 20 Barium ug/L 18.8 500 500 523 515 101 99 75-125 1 20 Beryllium ug/L 0.20J 500 500 503 494 101 99 75-125 2 20 Cadmium ug/L 0.81J 500 500 523 514 104 103 75-125 2 20 Chromium ug/L ND 500 500 509 503 102 101 75-125 1 20 Cobalt ug/L 21.3 500 500 537 528 103 101 75-125 2 20 Copper ug/L ND 500 500 515 504 103 101 75-125 2 20 Lead ug/L ND 500 500 519 514 104 103 75-125 1 20 Nickel ug/L ND 500 500 514 507 103 101 75-125 1 20 Selenium ug/L ND 500 500 537 530 107 106 75-125 1 20 Silver ug/L ND 250 250 256 254 103 101 75-125 1 20 Vanadium ug/L ND 500 500 512 505 102 101 75-125 1 20 Zinc ug/L 4.8J 500 500 522 515 103 102 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2020 11:46 AM without the written consent of Pace Analytical Services, LLC. Page 20 of 38 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry MSWLF SWs Pace Project No.: 92457589 QC Batch: 516497 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92457589001 METHOD BLANK: 2767367 Matrix: Water Associated Lab Samples: 92457589001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 12/30/1915:27 LABORATORY CONTROL SAMPLE: 2767368 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10.1 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2767369 2767370 MS MSD 92458051011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 10.5 10.4 105 104 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2020 11:46 AM without the written consent of Pace Analytical Services, LLC. Page 21 of 38 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry MSWLF SWs Pace Project No.: 92457589 QC Batch: 516501 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92457589002, 92457589003, 92457589004, 92457589006, 92457589007 METHOD BLANK: 2767378 Matrix: Water Associated Lab Samples: 92457589002, 92457589003, 92457589004, 92457589006, 92457589007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 12/30/1915:28 LABORATORY CONTROL SAMPLE: 2767379 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 9.9 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2767380 2767381 MS MSD 92457589003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 11.0 10.8 110 108 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2020 11:46 AM without the written consent of Pace Analytical Services, LLC. Page 22 of 38 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry MSWLF SWs Pace Project No.: 92457589 QC Batch: 516391 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Associated Lab Samples: 92457589001, 92457589006 METHOD BLANK: 2766744 Associated Lab Samples: 92457589001, 92457589006 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 12/23/19 12:07 1,1,1-Trichloroethane ug/L ND 1.0 0.18 12/23/19 12:07 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 12/23/19 12:07 1,1,2-Trichloroethane ug/L ND 1.0 0.24 12/23/19 12:07 1,1-Dichloroethane ug/L ND 1.0 0.27 12/23/19 12:07 1,1-Dichloroethene ug/L ND 1.0 0.24 12/23/19 12:07 1,2,3-Trichloropropane ug/L ND 1.0 0.35 12/23/19 12:07 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 12/23/19 12:07 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 12/23/19 12:07 1,2-Dichlorobenzene ug/L ND 1.0 0.29 12/23/19 12:07 1,2-Dichloroethane ug/L ND 1.0 0.34 12/23/19 12:07 1,2-Dichloropropane ug/L ND 1.0 0.19 12/23/19 12:07 1,4-Dichlorobenzene ug/L ND 1.0 0.26 12/23/19 12:07 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 12/23/19 12:07 2-Butanone (MEK) ug/L ND 5.0 3.3 12/23/19 12:07 2-Hexanone ug/L ND 5.0 0.57 12/23/19 12:07 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 12/23/19 12:07 Acetone ug/L ND 25.0 6.2 12/23/19 12:07 Acrylonitrile ug/L ND 10.0 0.90 12/23/19 12:07 Benzene ug/L ND 1.0 0.15 12/23/19 12:07 Bromochloromethane ug/L ND 1.0 0.34 12/23/19 12:07 Bromodichloromethane ug/L ND 1.0 0.26 12/23/19 12:07 Bromoform ug/L ND 1.0 0.62 12/23/19 12:07 Bromomethane ug/L ND 2.0 0.62 12/23/19 12:07 Carbon disulfide ug/L ND 2.0 0.40 12/23/19 12:07 Carbon tetrachloride ug/L ND 1.0 0.22 12/23/19 12:07 Chlorobenzene ug/L ND 1.0 0.23 12/23/19 12:07 Chloroethane ug/L ND 1.0 0.49 12/23/19 12:07 Chloroform ug/L ND 5.0 2.3 12/23/19 12:07 Chloromethane ug/L ND 1.0 0.39 12/23/19 12:07 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 12/23/19 12:07 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 12/23/19 12:07 Dibromochloromethane ug/L ND 1.0 0.41 12/23/19 12:07 Dibromomethane ug/L ND 1.0 0.46 12/23/19 12:07 Ethylbenzene ug/L ND 1.0 0.26 12/23/19 12:07 lodomethane ug/L ND 20.0 12.5 12/23/19 12:07 Methylene Chloride ug/L ND 5.0 3.7 12/23/19 12:07 Styrene ug/L ND 1.0 0.27 12/23/19 12:07 Tetrachloroethene ug/L ND 1.0 0.16 12/23/19 12:07 Toluene ug/L ND 1.0 0.24 12/23/19 12:07 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 12/23/19 12:07 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2020 11:46 AM without the written consent of Pace Analytical Services, LLC. Page 23 of 38 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry MSWLF SWs Pace Project No.: 92457589 METHOD BLANK: 2766744 Associated Lab Samples: 92457589001, 92457589006 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 12/23/19 12:07 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 12/23/19 12:07 Trichloroethene ug/L ND 1.0 0.22 12/23/19 12:07 Trichlorofluoromethane ug/L ND 1.0 0.31 12/23/19 12:07 Vinyl acetate ug/L ND 2.0 1.4 12/23/19 12:07 Vinyl chloride ug/L ND 1.0 0.24 12/23/19 12:07 Xylene (Total) ug/L ND 1.0 0.63 12/23/19 12:07 1,2-Dichloroethane-d4 (S) % 98 70-130 12/23/19 12:07 4-Bromofluorobenzene (S) % 102 70-130 12/23/19 12:07 Toluene-d8 (S) % 101 70-130 12/23/19 12:07 LABORATORY CONTROL SAMPLE: Parameter 2766745 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 51.1 102 70-130 1,1,1-Trichloroethane ug/L 50 45.2 90 70-130 1,1,2,2-Tetrachloroethane ug/L 50 49.7 99 70-130 1,1,2-Trichloroethane ug/L 50 48.3 97 70-130 1,1-Dichloroethane ug/L 50 47.1 94 70-130 1,1-Dichloroethene ug/L 50 47.0 94 70-130 1,2,3-Trichloropropane ug/L 50 50.1 100 70-130 1,2-Dibromo-3-chloropropane ug/L 50 49.4 99 70-130 1,2-Dibromoethane (EDB) ug/L 50 51.5 103 70-130 1,2-Dichlorobenzene ug/L 50 53.3 107 70-130 1,2-Dichloroethane ug/L 50 45.5 91 70-130 1,2-Dichloropropane ug/L 50 50.3 101 70-130 1,4-Dichlorobenzene ug/L 50 53.1 106 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1010 101 59-169 2-Butanone (MEK) ug/L 100 99.7 100 64-135 2-Hexanone ug/L 100 96.3 96 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 94.5 95 70-130 Acetone ug/L 100 107 107 61-157 Acrylonitrile ug/L 250 235 94 61-143 Benzene ug/L 50 48.3 97 70-130 Bromochloromethane ug/L 50 45.4 91 70-130 Bromodichloromethane ug/L 50 45.9 92 70-130 Bromoform ug/L 50 46.2 92 70-130 Bromomethane ug/L 50 35.9 72 38-130 Carbon disulfide ug/L 50 49.9 100 68-130 Carbon tetrachloride ug/L 50 45.0 90 70-130 Chlorobenzene ug/L 50 51.9 104 70-130 Chloroethane ug/L 50 36.2 72 37-142 Chloroform ug/L 50 46.1 92 70-130 Chloromethane ug/L 50 40.4 81 48-130 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2020 11:46 AM without the written consent of Pace Analytical Services, LLC. Page 24 of 38 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Surry MSWLF SWs Pace Project No.: 92457589 LABORATORY CONTROL SAMPLE: Parameter 2766745 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,2-Dichloroethene ug/L 50 46.6 93 70-130 cis-1,3-Dichloropropene ug/L 50 51.7 103 70-130 Dibromochloromethane ug/L 50 48.6 97 70-130 Dibromomethane ug/L 50 48.8 98 70-130 Ethylbenzene ug/L 50 48.8 98 70-130 lodomethane ug/L 100 73.6 74 40-130 Methylene Chloride ug/L 50 45.0 90 67-132 Styrene ug/L 50 51.3 103 70-130 Tetrachloroethene ug/L 50 49.7 99 69-130 Toluene ug/L 50 45.1 90 70-130 trans-1,2-Dichloroethene ug/L 50 47.7 95 70-130 trans- 1,3-Dichloropropene ug/L 50 49.9 100 70-130 trans-1,4-Dichloro-2-butene ug/L 50 52.2 104 35-189 Trichloroethene ug/L 50 49.7 99 70-130 Trichlorofluoromethane ug/L 50 44.9 90 63-130 Vinyl acetate ug/L 100 107 107 55-143 Vinyl chloride ug/L 50 50.6 101 70-131 Xylene (Total) ug/L 150 144 96 70-130 1,2-Dichloroethane-d4 (S) % 85 70-130 4-Bromofluorobenzene (S) % 97 70-130 Toluene-d8 (S) % 98 70-130 MATRIX SPIKE SAMPLE: Parameter 2766746 Units 92457589001 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 20.0 100 73-134 1,1,1-Trichloroethane ug/L ND 20 19.2 96 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 20.0 100 70-136 1,1,2-Trichloroethane ug/L ND 20 19.9 100 70-135 1,1-Dichloroethane ug/L ND 20 20.1 101 70-139 1,1-Dichloroethene ug/L ND 20 20.3 101 70-154 1,2,3-Trichloropropane ug/L ND 20 20.4 102 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 17.1 86 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 20.7 103 70-137 1,2-Dichlorobenzene ug/L ND 20 20.9 104 70-133 1,2-Dichloroethane ug/L ND 20 19.2 96 70-137 1,2-Dichloropropane ug/L ND 20 20.8 104 70-140 1,4-Dichlorobenzene ug/L ND 20 20.9 105 70-133 1,4-Dioxane (p-Dioxane) ug/L ND 400 393 98 53-168 2-Butanone (MEK) ug/L ND 40 38.7 97 60-139 2-Hexanone ug/L ND 40 35.5 89 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 35.7 89 65-135 Acetone ug/L ND 40 37.2 93 60-148 Acrylonitrile ug/L ND 100 96.4 96 64-147 Benzene ug/L ND 20 20.3 102 70-151 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2020 11:46 AM without the written consent of Pace Analytical Services, LLC. Page 25 of 38 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry MSWLF SWs Pace Project No.: 92457589 MATRIX SPIKE SAMPLE: 2766746 92457589001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Bromochloromethane ug/L ND 20 19.6 98 70-141 Bromodichloromethane ug/L ND 20 18.6 93 70-138 Bromoform ug/L ND 20 16.4 82 63-130 Bromomethane ug/L ND 20 19.2 96 15-152 Carbon disulfide ug/L ND 20 20.9 105 69-149 Carbon tetrachloride ug/L ND 20 19.5 97 70-143 Chlorobenzene ug/L ND 20 21.6 108 70-138 Chloroethane ug/L ND 20 19.9 100 52-163 Chloroform ug/L ND 20 20.0 100 70-139 Chloromethane ug/L ND 20 17.0 85 41-139 cis-1,2-Dichloroethene ug/L ND 20 19.6 98 70-141 cis-1,3-Dichloropropene ug/L ND 20 20.3 101 70-137 Dibromochloromethane ug/L ND 20 18.2 91 70-134 Dibromomethane ug/L ND 20 19.9 99 70-138 Ethylbenzene ug/L ND 20 20.6 103 66-153 lodomethane ug/L ND 40 20.5 51 20-138 Methylene Chloride ug/L ND 20 20.2 101 42-159 Styrene ug/L ND 20 21.0 105 70-135 Tetrachloroethene ug/L ND 20 20.5 102 59-143 Toluene ug/L ND 20 18.9 95 59-148 trans-1,2-Dichloroethene ug/L ND 20 20.7 103 70-146 trans- 1,3-Dichloropropene ug/L ND 20 19.4 97 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 19.8 99 47-135 Trichloroethene ug/L ND 20 21.2 106 70-147 Trichlorofluoromethane ug/L ND 20 20.4 102 70-148 Vinyl acetate ug/L ND 40 40.8 102 49-151 Vinyl chloride ug/L ND 20 21.9 109 70-156 Xylene (Total) ug/L ND 60 60.3 100 63-158 1,2-Dichloroethane-d4 (S) % 90 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 97 70-130 SAMPLE DUPLICATE: 2766747 Parameter Units 92457589006 Result Dup Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2020 11:46 AM without the written consent of Pace Analytical Services, LLC. Page 26 of 38 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry MSWLF SWs Pace Project No.: 92457589 SAMPLE DUPLICATE: 2766747 Parameter Units 92457589006 Result Dup Result RPD Max RPD 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 1,4-Dioxane (p-Dioxane) ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Acrylonitrile ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 30 Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 cis-1,2-Dichloroethene ug/L ND ND 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 lodomethane ug/L ND ND 30 Methylene Chloride ug/L ND ND 30 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 Vinyl acetate ug/L ND ND 30 Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L ND ND 30 1,2-Dichloroethane-d4 (S) % 100 95 4-Bromofluorobenzene (S) % 104 99 Toluene-d8 (S) % 108 101 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2020 11:46 AM without the written consent of Pace Analytical Services, LLC. Page 27 of 38 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry MSWLF SWs Pace Project No.: 92457589 QC Batch: 516422 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Associated Lab Samples: 92457589002, 92457589003, 92457589004, 92457589007 METHOD BLANK: 2766873 Matrix: Water Associated Lab Samples: 92457589002, 92457589003, 92457589004, 92457589007 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 12/24/19 00:18 1,1,1-Trichloroethane ug/L ND 1.0 0.18 12/24/19 00:18 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 12/24/19 00:18 1,1,2-Trichloroethane ug/L ND 1.0 0.24 12/24/19 00:18 1,1-Dichloroethane ug/L ND 1.0 0.27 12/24/19 00:18 1,1-Dichloroethene ug/L ND 1.0 0.24 12/24/19 00:18 1,2,3-Trichloropropane ug/L ND 1.0 0.35 12/24/19 00:18 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 12/24/19 00:18 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 12/24/19 00:18 1,2-Dichlorobenzene ug/L ND 1.0 0.29 12/24/19 00:18 1,2-Dichloroethane ug/L ND 1.0 0.34 12/24/19 00:18 1,2-Dichloropropane ug/L ND 1.0 0.19 12/24/19 00:18 1,4-Dichlorobenzene ug/L ND 1.0 0.26 12/24/19 00:18 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 12/24/19 00:18 2-Butanone (MEK) ug/L ND 5.0 3.3 12/24/19 00:18 2-Hexanone ug/L ND 5.0 0.57 12/24/19 00:18 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 12/24/19 00:18 Acetone ug/L ND 25.0 6.2 12/24/19 00:18 Acrylonitrile ug/L ND 10.0 0.90 12/24/19 00:18 Benzene ug/L ND 1.0 0.15 12/24/19 00:18 Bromochloromethane ug/L ND 1.0 0.34 12/24/19 00:18 Bromodichloromethane ug/L ND 1.0 0.26 12/24/19 00:18 Bromoform ug/L ND 1.0 0.62 12/24/19 00:18 Bromomethane ug/L ND 2.0 0.62 12/24/19 00:18 Carbon disulfide ug/L ND 2.0 0.40 12/24/19 00:18 Carbon tetrachloride ug/L ND 1.0 0.22 12/24/19 00:18 Chlorobenzene ug/L ND 1.0 0.23 12/24/19 00:18 Chloroethane ug/L ND 1.0 0.49 12/24/19 00:18 Chloroform ug/L ND 5.0 2.3 12/24/19 00:18 Chloromethane ug/L ND 1.0 0.39 12/24/19 00:18 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 12/24/19 00:18 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 12/24/19 00:18 Dibromochloromethane ug/L ND 1.0 0.41 12/24/19 00:18 Dibromomethane ug/L ND 1.0 0.46 12/24/19 00:18 Ethylbenzene ug/L ND 1.0 0.26 12/24/19 00:18 lodomethane ug/L ND 20.0 12.5 12/24/19 00:18 Methylene Chloride ug/L ND 5.0 3.7 12/24/19 00:18 Styrene ug/L ND 1.0 0.27 12/24/19 00:18 Tetrachloroethene ug/L ND 1.0 0.16 12/24/19 00:18 Toluene ug/L ND 1.0 0.24 12/24/19 00:18 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 12/24/19 00:18 v2 v2 v2 v2 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2020 11:46 AM without the written consent of Pace Analytical Services, LLC. Page 28 of 38 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry MSWLF SWs Pace Project No.: 92457589 METHOD BLANK: 2766873 Matrix: Water Associated Lab Samples: 92457589002, 92457589003, 92457589004, 92457589007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 12/24/19 00:18 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 12/24/19 00:18 Trichloroethene ug/L ND 1.0 0.22 12/24/19 00:18 Trichlorofluoromethane ug/L ND 1.0 0.31 12/24/19 00:18 Vinyl acetate ug/L ND 2.0 1.4 12/24/19 00:18 Vinyl chloride ug/L ND 1.0 0.24 12/24/19 00:18 Xylene (Total) ug/L ND 1.0 0.63 12/24/19 00:18 1,2-Dichloroethane-d4 (S) % 97 70-130 12/24/19 00:18 4-Bromofluorobenzene (S) % 101 70-130 12/24/19 00:18 Toluene-d8 (S) % 100 70-130 12/24/19 00:18 LABORATORY CONTROL SAMPLE: Parameter 2766874 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 47.2 94 70-130 1,1,1-Trichloroethane ug/L 50 41.9 84 70-130 1,1,2,2-Tetrachloroethane ug/L 50 47.5 95 70-130 1,1,2-Trichloroethane ug/L 50 45.5 91 70-130 1,1-Dichloroethane ug/L 50 44.3 89 70-130 1,1-Dichloroethene ug/L 50 47.0 94 70-130 1,2,3-Trichloropropane ug/L 50 48.0 96 70-130 1,2-Dibromo-3-chloropropane ug/L 50 43.8 88 70-130 1,2-Dibromoethane (EDB) ug/L 50 48.7 97 70-130 1,2-Dichlorobenzene ug/L 50 48.9 98 70-130 1,2-Dichloroethane ug/L 50 44.0 88 70-130 1,2-Dichloropropane ug/L 50 46.2 92 70-130 1,4-Dichlorobenzene ug/L 50 47.7 95 70-130 1,4-Dioxane (p-Dioxane) ug/L 1000 943 94 59-169 2-Butanone (MEK) ug/L 100 90.9 91 64-135 2-Hexanone ug/L 100 90.5 91 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 89.8 90 70-130 Acetone ug/L 100 94.3 94 61-157 Acrylonitrile ug/L 250 227 91 61-143 Benzene ug/L 50 44.6 89 70-130 Bromochloromethane ug/L 50 42.9 86 70-130 Bromodichloromethane ug/L 50 42.1 84 70-130 Bromoform ug/L 50 40.8 82 70-130 Bromomethane ug/L 50 34.7 69 38-130 v2 Carbon disulfide ug/L 50 45.5 91 68-130 Carbon tetrachloride ug/L 50 40.6 81 70-130 Chlorobenzene ug/L 50 48.0 96 70-130 Chloroethane ug/L 50 35.4 71 37-142 v2 Chloroform ug/L 50 43.6 87 70-130 Chloromethane ug/L 50 36.7 73 48-130 v2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2020 11:46 AM without the written consent of Pace Analytical Services, LLC. Page 29 of 38 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry MSWLF SWs Pace Project No.: 92457589 LABORATORY CONTROL SAMPLE: Parameter 2766874 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,2-Dichloroethene ug/L 50 43.7 87 70-130 cis-1,3-Dichloropropene ug/L 50 46.7 93 70-130 Dibromochloromethane ug/L 50 43.6 87 70-130 Dibromomethane ug/L 50 45.7 91 70-130 Ethylbenzene ug/L 50 45.5 91 70-130 lodomethane ug/L 100 73.1 73 40-130 v2 Methylene Chloride ug/L 50 42.7 85 67-132 Styrene ug/L 50 47.6 95 70-130 Tetrachloroethene ug/L 50 45.7 91 69-130 Toluene ug/L 50 42.1 84 70-130 trans-1,2-Dichloroethene ug/L 50 44.7 89 70-130 trans- 1,3-Dichloropropene ug/L 50 44.8 90 70-130 trans-1,4-Dichloro-2-butene ug/L 50 44.9 90 35-189 Trichloroethene ug/L 50 45.9 92 70-130 Trichlorofluoromethane ug/L 50 41.5 83 63-130 Vinyl acetate ug/L 100 99.9 100 55-143 Vinyl chloride ug/L 50 46.5 93 70-131 Xylene (Total) ug/L 150 135 90 70-130 1,2-Dichloroethane-d4 (S) % 87 70-130 4-Bromofluorobenzene (S) % 97 70-130 Toluene-d8 (S) % 97 70-130 MATRIX SPIKE SAMPLE: Parameter 2766876 Units 92457589002 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 19.6 98 73-134 1,1,1-Trichloroethane ug/L ND 20 18.8 94 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 19.1 96 70-136 1,1,2-Trichloroethane ug/L ND 20 19.5 98 70-135 1,1-Dichloroethane ug/L ND 20 20.2 101 70-139 1,1-Dichloroethene ug/L ND 20 20.1 100 70-154 1,2,3-Trichloropropane ug/L ND 20 19.6 98 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 17.3 87 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 20.4 102 70-137 1,2-Dichlorobenzene ug/L ND 20 20.8 104 70-133 1,2-Dichloroethane ug/L ND 20 18.8 94 70-137 1,2-Dichloropropane ug/L ND 20 20.9 104 70-140 1,4-Dichlorobenzene ug/L ND 20 21.1 106 70-133 1,4-Dioxane (p-Dioxane) ug/L ND 400 376 94 53-168 2-Butanone (MEK) ug/L ND 40 37.1 93 60-139 2-Hexanone ug/L ND 40 33.9 85 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 34.4 86 65-135 Acetone ug/L ND 40 37.8 95 60-148 Acrylonitrile ug/L ND 100 94.9 95 64-147 Benzene ug/L ND 20 19.8 99 70-151 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2020 11:46 AM without the written consent of Pace Analytical Services, LLC. Page 30 of 38 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry MSWLF SWs Pace Project No.: 92457589 MATRIX SPIKE SAMPLE: 2766876 92457589002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Bromochloromethane ug/L ND 20 19.2 96 70-141 Bromodichloromethane ug/L ND 20 18.4 92 70-138 Bromoform ug/L ND 20 16.3 81 63-130 Bromomethane ug/L ND 20 18.9 95 15-152 Carbon disulfide ug/L ND 20 20.6 103 69-149 Carbon tetrachloride ug/L ND 20 19.3 96 70-143 Chlorobenzene ug/L ND 20 21.1 105 70-138 Chloroethane ug/L ND 20 20.1 100 52-163 Chloroform ug/L ND 20 19.5 98 70-139 Chloromethane ug/L ND 20 17.4 87 41-139 cis-1,2-Dichloroethene ug/L 3.0 20 22.3 96 70-141 cis-1,3-Dichloropropene ug/L ND 20 20.2 101 70-137 Dibromochloromethane ug/L ND 20 18.3 91 70-134 Dibromomethane ug/L ND 20 20.1 101 70-138 Ethylbenzene ug/L ND 20 20.1 101 66-153 lodomethane ug/L ND 40 28.6 72 20-138 Methylene Chloride ug/L ND 20 19.5 97 42-159 Styrene ug/L ND 20 20.8 104 70-135 Tetrachloroethene ug/L ND 20 20.2 101 59-143 Toluene ug/L ND 20 18.8 94 59-148 trans-1,2-Dichloroethene ug/L ND 20 20.3 102 70-146 trans- 1,3-Dichloropropene ug/L ND 20 19.2 96 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 19.1 96 47-135 Trichloroethene ug/L ND 20 21.0 105 70-147 Trichlorofluoromethane ug/L ND 20 20.4 102 70-148 Vinyl acetate ug/L ND 40 39.3 98 49-151 Vinyl chloride ug/L ND 20 22.4 112 70-156 Xylene (Total) ug/L ND 60 60.0 100 63-158 1,2-Dichloroethane-d4 (S) % 88 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 97 70-130 SAMPLE DUPLICATE: 2766875 Parameter Units 92457587004 Result Dup Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2020 11:46 AM without the written consent of Pace Analytical Services, LLC. Page 31 of 38 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry MSWLF SWs Pace Project No.: 92457589 SAMPLE DUPLICATE: 2766875 Parameter Units 92457587004 Result Dup Result RPD Max RPD 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 1,4-Dioxane (p-Dioxane) ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Acrylonitrile ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 30 Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 cis-1,2-Dichloroethene ug/L ND ND 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 lodomethane ug/L ND ND 30 Methylene Chloride ug/L ND ND 30 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 Vinyl acetate ug/L ND ND 30 Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L ND ND 30 1,2-Dichloroethane-d4 (S) % 95 97 4-Bromofluorobenzene (S) % 99 99 Toluene-d8 (S) % 100 101 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2020 11:46 AM without the written consent of Pace Analytical Services, LLC. Page 32 of 38 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALIFIERS Project: Surry MSWLF SWs Pace Project No.: 92457589 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2020 11:46 AM without the written consent of Pace Analytical Services, LLC. Page 33 of 38 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Surry MSWLF SWs 92457589 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92457589001 SW-1 EPA 3010A 516496 EPA 6010D 516513 92457589002 SW-2 EPA 3010A 516498 EPA 6010D 516514 92457589003 SW-3 EPA 3010A 516498 EPA 6010D 516514 92457589004 SW-4 EPA 3010A 516498 EPA 6010D 516514 92457589006 SWN-2 EPA 3010A 516498 EPA 6010D 516514 92457589007 SW-C EPA 3010A 516498 EPA 6010D 516514 92457589001 SW-1 EPA 3010A 516497 EPA 6020B 516517 92457589002 SW-2 EPA 3010A 516501 EPA 6020B 516518 92457589003 SW-3 EPA 3010A 516501 EPA 6020B 516518 92457589004 SW-4 EPA 3010A 516501 EPA 6020B 516518 92457589006 SWN-2 EPA 3010A 516501 EPA 6020B 516518 92457589007 SW-C EPA 3010A 516501 EPA 6020B 516518 92457589001 SW-1 EPA 8260D 516391 92457589002 SW-2 EPA 8260D 516422 92457589003 SW-3 EPA 8260D 516422 92457589004 SW-4 EPA 8260D 516422 92457589006 SWN-2 EPA 8260D 516391 92457589007 SW-C EPA 8260D 516422 Date: 02/07/2020 11:46 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 34 of 38 Document Name: Document Revised: February 7, 2018 m Y aCeAnalyficaf Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: ! F-CAR-CS-033-Rev.05 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden[] Greenwood ❑ Huntersville Raleigh❑ Mechanicsville[] Sample Condition Client Name: Proje wo# : 92457589 upon Receipt ct mul,n1i V1 I Courier: ❑Fed Ex I ❑UPS V ❑uSP5 ❑Client ❑ Commercial ace ❑Other; 929 57589 Custody Seal Present? ❑Yes E36 Seals Intact? ❑Yes E390 Packing Material; ❑Bubble Wrap ubbfe Bags ❑None ❑ Other Thermometer: Type of Ice: Q<et ❑Blue CWGun ID: 92TO58 Cooler Temp i'C): 1 - 5 Correction Factor: Add/Subtract VC) 0.0°C Cooler Temp Corrected ('C): . USDA Regulated Sall (El --N/A, water sample) Did samples origina a in a quarantine zone. within the United States: CA, NY, or 5C (check maps)? M Date/initials Person EKamining Contents:_ j� Slofaglcaf ue Frozen? ❑Yes No [-]N/A ❑None Temp should be above freezing to VC []samples out of terip criteria. Samples on ice, coolingprocess hasbegto Did sanplesoriginate fram aforelgn source tinternationally, Including Hawaii and Puerto Ricci? nYes ❑No Comme r:.ts/Discrepancy; Chain of Custody Present? Yes No ❑NIA 1. ` Samples Arrived within Hold Time? es ON. ❑NIA 2. Short Hold Time Analysis (t72 hr.)? ❑Yes RrN. _ ❑NIA 3, flush Turn Around Time Requestei7 nYes No []N/A 4. Sufficient Volume? Fd< ❑Nn ❑N!A 5. Correct Containers Used? 0< ON. ❑N/A 6. -Pace Containers Used 51es [-]No []N/A Containers Intact? 2fB ❑ND ❑N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes ❑Nv 0<1A B. Sample Labels Match COC7 es ❑No [] N/A 9. -Includes Date/Time/IDtAnalysis Matrix: ` Headspace in VOA Vials 1>5-6nimf? Oyes 0< ❑N/A 10. Trip Blank Present- ❑Yes Oka ❑NIA 11. Trip Blank Custody Seals Present? []Yes ❑No A' COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIRCATIdN/RESOLUTION Field Data Required? []Yes [:]No I Person contacted: Date/Time: Project Manager SCURF Review: omb slate: f S ^1 q Project Manager SRF Review: T J f ►�L _ Date: ! - j 9- Page 35 of 38 _ � aceAnalytical Document Name: Sample Condition Upon Recelpt(SCUR) Document Revised: February 7, 2018 Page 1 of 2 Document No.: Issuing Authority: F-CAR•CS-033-Rev.06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/BUS (water) DOC, LLHg **Bottom half of box is to —IFS —f—number of battle Project 1# WN : 92457589 PM: AMB Due Date: 12/31/19 CLIENT: 92—Municipal a & _ a W n .U+ m a E N > a m a' di c. j U a E Ifl > a m a di n 7 U n a E O a to Y v QJ d c 7 N `a ~ a cc N v v O N Y U f a E ry a gom V m O = U ro u Ul z 6 V a ca Q Z N U b n E ry 0.a m n TO fl Z U a @ N m O21 a .c Ya F n 7 `" ? V m s c Q `w �I ly 4 a ij Z a Q m e.l l7 a Z c 4 E E N l7 a V 7 p rev x -0 E cc a r•I l7 Q V V a 2 E Q E Ln N 1A l7 a � x a Q J E ry m a a z = E i C ¢ 0 N N Z 4 l7 > 2 a - O E t7 ? v 0 En O> E d o, l7 A `.. a 1 r Y a y Y O a a 7 j Y 6 m 7 1 ¢ b FL al v E '�' Q V y z ^ E rn I n v v a V S 2 a E a ? L c 7 .93 a E > C V a c c 10 — to E > ; z ? v ai n 7 u ¢ E f , 2 "7 f 3 A S � - I 1 6 ry 7 - - 8 - p \ _I 10 , li pH Adjustment Log for Preserved Samples Sample ID Type of Preservative I pH upon ra¢eipt Date pretorvatlon adjusted Time preservation adjusted Amount of Prese.vative added Lot a Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy ofthis form will be sent to the North Carolina DEHNR Cemricanan VTTICe ti.e. out of hold, incorrect preservative, out of temp, incorrect containers. Page 36 of 38 C a c n T Q 41 N U m a i a5 Q U v � O N E N o r c U Z LL] <U Q p ❑ J a ❑ � E QLO `o J U `[ m = N } $ U 0 o — i LL M v 0 Z C m Q r = m U� N 0: {NIA) }ouqui saidweS LO z (NIA) jalPPO 6 h z paieaS ApP}sno O U LLI a (NIA) a�i a U o 0 u! dW31 0 b m m � N O z Z � + a m u F N W a` v m m _m 0 z © o< Za w {ddy-sie}ay x x x � o z ddy-soon x x x x x Uz J NIA ;sal sashleuVcr ri1 a { S m aylp iouey}a}N _ m cm a £OZSZeN q �r U '— ¢ m HOeN v. IOH ca M m M M M M cw MNH 0 m v c It a 7OSZH z m m s c m ° a o a` Q pa"asaidun v E SN3MV1NOO �C # v v v v v v v Q Q U Q a ri a a w w NO11031103 lv dw3z _jldwvs C LU cl z N a < a < ❑ Z Z Q D D w w w E w o ❑ O z m z o w z ¢ w O J q d d O O M h ~ ti u4i -A a O 0- 6 C wi m U j m L UNO3=0 UV80=0) 3dA137dWVS 0 0 (7 C7 0 0 0 0 C 0 Z p z ro Ci z (µal of sapm P!len aas) 3003 X1211tlW p m O Er p a - c .m w � �a3�3a�o3aoi- N w N j Z w ❑ o C U C r U yi ❑ LL K - J .r_ Ld 0 N C, 0 r- m Z; a c E Q Z O _ max ENS LQII H n cl U 'E M N O QI v co D E a N m O v m y r N N Ni U U Z Z Z Z (n N (n {/} N o m E m m m #W311 d d eY en m r- oo m r. c> a ¢ {7 w t a PafIP F of 38 INO Raeiul saldweg rr 11�i N O IN1JJ Jolaop p z paleeS Fpoisnp 4{� _ yI o U _ (NIA) —1 �, Ctil � � uo pania°aa y o a ci 0 Al dW3i ca m m m z m z 40 p /1 co co } I "tl a a n UL u ' C� .E 1 ci ) Q a a ❑3 E a c O CA a o z Rppn?u�j z (u yz Lddy-sle4aW x x x x x x x D a 7 z ddy-sppp x x x x x x x J leal SOSAIeuV [� Jaip } ❑ 1 y, Z louec{laN 4 w _ m 2 C Q ai EOZSZeN 0 l C U w m NOUN a E .V `m Z 12 0 c c m IaH m r of m m m cn vcitO J Q " m m d EONH ❑ W E E iE O J z m .m hOSZH w C N c u n m Q a a pamasa3duN .� y' olu m? m 0 m m v v v v �1 U NF 6 U Q 0. 0. 0. - 52J3Nlb1Tl00dD# v v U Q N011031100 iV dW313ldWVS w F- < LU U0. w Z N El y z ❑ Qz U w F 2 a = aw o w ¢ z z z H s U ❑ o W z z J Q J U-LL J 6 G y p 2cfS N m m (n E U403-0 i3vmu=9) 3dA131dWW5 C9 0 0 0 C7 U' (7 LO r ° z z a 13 `m p � (HaI oc sapm pilr.5 aas) 3000 XIa1VW tt 5 tt tt 5 5 0 Z- J O w r Y o E!a u m a m o �O3a�a3aor % � c.) U x 3-= 0 .8 031- N Uy w m (ncn m W C m O u o t u E T A O ce W — o(.,ED J `mm� z �r ymf iEwm Qw m�E ❑ m p H 4 c� E V m m n C c: O u� °� m O a r a U3 r N r qi Z ❑ 3: cu U v (n vl to lcn Ito co cn cn r O r N is C E v` ` 1p o o- c4 #W311 N en LO ep h W 6f N EL' U Q [7 W 2 -- Page 38 of 38 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 February 05, 2020 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: Surry SWN-1 Pace Project No.: 92460999 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on January 16, 2020. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, ft*OL-' Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Steven R. Gandy, Municipal Engineering Services Co. Maddie German, Municipal Engineering Services REPORT OF LABORATORY ANALYSIS r e This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 18 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry SWN-1 Pace Project No.: 92460999 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 18 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry SWN-1 Pace Project No.: 92460999 Lab ID Sample ID 92460999001 SWN-1 SAMPLE SUMMARY Matrix Date Collected Date Received Water 01/15/20 11:30 01/16/20 08:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 18 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Surry SWN-1 92460999 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92460999001 SWN-1 EPA 601 OD IDS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 18 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry SWN-1 Pace Project No.: 92460999 Sample: SWN-1 Lab ID: 92460999001 Collected: 01/15/20 11:30 Received: 01/16/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 02/05/2020 03:03 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A N D ug/L 5.0 3.0 1 01/28/20 01:02 01/28/20 19:19 7440-36-0 N D ug/L 10.0 4.7 1 01/28/20 01:02 01/28/20 19:19 7440-38-2 16.5 ug/L 5.0 1.0 1 01/28/20 01:02 01/28/20 19:19 7440-39-3 N D ug/L 1.0 0.20 1 01/28/20 01:02 01/28/20 19:19 7440-41-7 N D ug/L 1.0 0.40 1 01/28/20 01:02 01/28/20 19:19 7440-43-9 N D ug/L 5.0 1.0 1 01/28/20 01:02 01/28/20 19:19 7440-47-3 ND ug/L 5.0 1.1 1 01/28/20 01:02 01/28/20 19:19 7440-48-4 ND ug/L 5.0 2.1 1 01/28/20 01:02 01/28/20 19:19 7440-50-8 ND ug/L 5.0 1.6 1 01/28/20 01:02 01/28/20 19:19 7439-92-1 N D ug/L 5.0 0.90 1 01/28/20 01:02 01/28/20 19:19 7440-02-0 N D ug/L 10.0 4.7 1 01/28/20 01:02 01/28/20 19:19 7782-49-2 N D ug/L 5.0 2.5 1 01/28/20 01:02 01/28/20 19:19 7440-22-4 ND ug/L 5.0 1.3 1 01/28/20 01:02 01/28/20 19:19 7440-62-2 ND ug/L 10.0 3.9 1 01/28/20 01:02 01/28/20 19:19 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 01/25/20 02:06 02/04/20 17:27 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 01/27/2015:12 67-64-1 v1 ND ug/L 10.0 0.90 1 01/27/2015:12 107-13-1 N D ug/L 1.0 0.15 1 01 /27/20 15:12 71-43-2 ND ug/L 1.0 0.34 1 01/27/2015:12 74-97-5 ND ug/L 1.0 0.26 1 01/27/2015:12 75-27-4 ND ug/L 1.0 0.62 1 01/27/2015:12 75-25-2 ND ug/L 2.0 0.62 1 01/27/2015:12 74-83-9 IH,IK ND ug/L 5.0 3.3 1 01/27/2015:12 78-93-3 ND ug/L 2.0 0.40 1 01/27/2015:12 75-15-0 ND ug/L 1.0 0.22 1 01/27/2015:12 56-23-5 ND ug/L 1.0 0.23 1 01/27/2015:12 108-90-7 ND ug/L 1.0 0.49 1 01/27/2015:12 75-00-3 ND ug/L 5.0 2.3 1 01/27/2015:12 67-66-3 ND ug/L 1.0 0.39 1 01/27/2015:12 74-87-3 ND ug/L 5.0 0.26 1 01/27/2015:12 96-12-8 ND ug/L 1.0 0.41 1 01/27/2015:12 124-48-1 ND ug/L 1.0 0.26 1 01/27/2015:12 106-93-4 ND ug/L 1.0 0.46 1 01/27/2015:12 74-95-3 ND ug/L 1.0 0.29 1 01/27/2015:12 95-50-1 ND ug/L 1.0 0.26 1 01/27/2015:12 106-46-7 ND ug/L 1.0 0.54 1 01/27/2015:12 110-57-6 v1 ND ug/L 1.0 0.27 1 01/27/2015:12 75-34-3 ND ug/L 1.0 0.34 1 01/27/2015:12 107-06-2 ND ug/L 1.0 0.24 1 01/27/2015:12 75-35-4 ND ug/L 1.0 0.29 1 01/27/2015:12 156-59-2 ND ug/L 1.0 0.25 1 01/27/2015:12 156-60-5 ND ug/L 1.0 0.19 1 01/27/2015:12 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 18 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry SWN-1 Pace Project No.: 92460999 Sample: SWN-1 Lab ID: 92460999001 Collected: 01/15/20 11:30 Received: 01/16/20 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 01/27/20 15:12 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 01/27/20 15:12 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 01/27/20 15:12 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 01/27/20 15:12 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 01/27/20 15:12 591-78-6 lodomethane ND ug/L 20.0 12.5 1 01/27/20 15:12 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 01/27/20 15:12 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 01/27/20 15:12 108-10-1 Styrene ND ug/L 1.0 0.27 1 01/27/20 15:12 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 01/27/20 15:12 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 01/27/20 15:12 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 01/27/20 15:12 127-18-4 Toluene ND ug/L 1.0 0.24 1 01/27/20 15:12 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 01/27/20 15:12 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 01/27/20 15:12 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 01/27/20 15:12 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 01/27/20 15:12 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 01/27/20 15:12 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 01/27/20 15:12 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 01/27/20 15:12 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 01/27/20 15:12 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 105 % 70-130 1 01/27/20 15:12 460-00-4 1,2-Dichloroethane-d4 (S) 115 % 70-130 1 01/27/20 15:12 17060-07-0 Toluene-d8 (S) 103 % 70-130 1 01/27/20 15:12 2037-26-5 Date: 02/05/2020 03:03 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 18 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry SWN-1 Pace Project No.: 92460999 QC Batch: 521689 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92460999001 METHOD BLANK: 2790875 Associated Lab Samples: 92460999001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 5.0 3.0 01/28/2019:09 Arsenic ug/L ND 10.0 4.7 01/28/2019:09 Barium ug/L ND 5.0 1.0 01/28/2019:09 Beryllium ug/L ND 1.0 0.20 01/28/2019:09 Cadmium ug/L ND 1.0 0.40 01/28/2019:09 Chromium ug/L ND 5.0 1.0 01/28/2019:09 Cobalt ug/L ND 5.0 1.1 01/28/2019:09 Copper ug/L ND 5.0 2.1 01/28/2019:09 Lead ug/L ND 5.0 1.6 01/28/2019:09 Nickel ug/L ND 5.0 0.90 01/28/2019:09 Selenium ug/L ND 10.0 4.7 01/28/2019:09 Silver ug/L ND 5.0 2.5 01/28/2019:09 Vanadium ug/L ND 5.0 1.3 01/28/2019:09 Zinc ug/L ND 10.0 3.9 01/28/2019:09 LABORATORY CONTROL SAMPLE: Parameter 2790876 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 489 98 80-120 Arsenic ug/L 500 472 94 80-120 Barium ug/L 500 486 97 80-120 Beryllium ug/L 500 489 98 80-120 Cadmium ug/L 500 486 97 80-120 Chromium ug/L 500 489 98 80-120 Cobalt ug/L 500 487 97 80-120 Copper ug/L 500 487 97 80-120 Lead ug/L 500 491 98 80-120 Nickel ug/L 500 490 98 80-120 Selenium ug/L 500 482 96 80-120 Silver ug/L 250 244 97 80-120 Vanadium ug/L 500 487 97 80-120 Zinc ug/L 500 483 97 80-120 Qualifiers Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2790877 2790878 MS MSD 92460999001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 517 513 103 103 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/05/2020 03:03 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 18 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Surry SWN-1 92460999 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2790877 2790878 MS MSD 92460999001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L ND 500 500 504 492 101 98 75-125 2 20 Barium ug/L 16.5 500 500 516 509 100 99 75-125 1 20 Beryllium ug/L ND 500 500 500 492 100 98 75-125 2 20 Cadmium ug/L ND 500 500 509 504 102 101 75-125 1 20 Chromium ug/L ND 500 500 492 482 98 96 75-125 2 20 Cobalt ug/L ND 500 500 500 491 100 98 75-125 2 20 Copper ug/L ND 500 500 511 504 102 101 75-125 1 20 Lead ug/L ND 500 500 505 497 101 99 75-125 2 20 Nickel ug/L ND 500 500 502 494 100 99 75-125 2 20 Selenium ug/L ND 500 500 536 531 107 106 75-125 1 20 Silver ug/L ND 250 250 252 250 101 100 75-125 1 20 Vanadium ug/L ND 500 500 498 489 99 98 75-125 2 20 Zinc ug/L ND 500 500 485 479 97 95 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/05/2020 03:03 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 18 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry SWN-1 Pace Project No.: 92460999 QC Batch: 521392 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92460999001 METHOD BLANK: 2789527 Matrix: Water Associated Lab Samples: 92460999001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 02/04/2017:14 LABORATORY CONTROL SAMPLE: 2789528 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10.0 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2789529 2789530 MS MSD 92460999001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 9.9 10.2 99 101 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/05/2020 03:03 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 18 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry SWN-1 Pace Project No.: 92460999 QC Batch: 521561 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Associated Lab Samples: 92460999001 METHOD BLANK: 2790180 Associated Lab Samples: 92460999001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 01/27/20 13:28 1,1,1-Trichloroethane ug/L ND 1.0 0.18 01/27/20 13:28 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 01/27/20 13:28 1,1,2-Trichloroethane ug/L ND 1.0 0.24 01/27/20 13:28 1,1-Dichloroethane ug/L ND 1.0 0.27 01/27/20 13:28 1,1-Dichloroethene ug/L ND 1.0 0.24 01/27/20 13:28 1,2,3-Trichloropropane ug/L ND 1.0 0.35 01/27/20 13:28 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 01/27/20 13:28 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 01/27/20 13:28 1,2-Dichlorobenzene ug/L ND 1.0 0.29 01/27/20 13:28 1,2-Dichloroethane ug/L ND 1.0 0.34 01/27/20 13:28 1,2-Dichloropropane ug/L ND 1.0 0.19 01/27/20 13:28 1,4-Dichlorobenzene ug/L ND 1.0 0.26 01/27/20 13:28 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 01/27/20 13:28 2-Butanone (MEK) ug/L ND 5.0 3.3 01/27/20 13:28 2-Hexanone ug/L ND 5.0 0.57 01/27/20 13:28 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 01/27/20 13:28 Acetone ug/L ND 25.0 6.2 01/27/20 13:28 Acrylonitrile ug/L ND 10.0 0.90 01/27/20 13:28 Benzene ug/L ND 1.0 0.15 01/27/20 13:28 Bromochloromethane ug/L ND 1.0 0.34 01/27/20 13:28 Bromodichloromethane ug/L ND 1.0 0.26 01/27/20 13:28 Bromoform ug/L ND 1.0 0.62 01/27/20 13:28 Bromomethane ug/L ND 2.0 0.62 01/27/20 13:28 Carbon disulfide ug/L ND 2.0 0.40 01/27/20 13:28 Carbon tetrachloride ug/L ND 1.0 0.22 01/27/20 13:28 Chlorobenzene ug/L ND 1.0 0.23 01/27/20 13:28 Chloroethane ug/L ND 1.0 0.49 01/27/20 13:28 Chloroform ug/L ND 5.0 2.3 01/27/20 13:28 Chloromethane ug/L ND 1.0 0.39 01/27/20 13:28 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 01/27/20 13:28 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 01/27/20 13:28 Dibromochloromethane ug/L ND 1.0 0.41 01/27/20 13:28 Dibromomethane ug/L ND 1.0 0.46 01/27/20 13:28 Ethylbenzene ug/L ND 1.0 0.26 01/27/20 13:28 lodomethane ug/L ND 20.0 12.5 01/27/20 13:28 Methylene Chloride ug/L ND 5.0 3.7 01/27/20 13:28 Styrene ug/L ND 1.0 0.27 01/27/20 13:28 Tetrachloroethene ug/L ND 1.0 0.16 01/27/20 13:28 Toluene ug/L ND 1.0 0.24 01/27/20 13:28 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 01/27/20 13:28 Qualifiers v1 IH,IK Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/05/2020 03:03 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 18 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry SWN-1 Pace Project No.: 92460999 METHOD BLANK: 2790180 Associated Lab Samples: 92460999001 Parameter Units trans- 1,3-Dichloropropene ug/L trans-1,4-Dichloro-2-butene ug/L Trichloroethene ug/L Trichlorofluoromethane ug/L Vinyl acetate ug/L Vinyl chloride ug/L Xylene (Total) ug/L 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % LABORATORY CONTROL SAMPLE: 2790181 Parameter QUALITY CONTROL DATA Matrix: Water Blank Result Reporting Limit ND 1.0 ND 1.0 ND 1.0 ND 1.0 ND 2.0 ND 1.0 ND 1.0 112 70-130 104 70-130 103 70-130 MDL Analyzed 0.31 01 /27/20 13:28 0.54 01 /27/20 13:28 0.22 01 /27/20 13:28 0.31 01 /27/20 13:28 1.4 01 /27/20 13:28 0.24 01 /27/20 13:28 0.63 01 /27/20 13:28 01 /27/20 13:28 01 /27/20 13:28 01 /27/20 13:28 v1 Qualifiers Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 52.1 104 70-130 1,1,1-Trichloroethane ug/L 50 55.3 111 70-130 1,1,2,2-Tetrachloroethane ug/L 50 49.4 99 70-130 1,1,2-Trichloroethane ug/L 50 54.5 109 70-130 1,1-Dichloroethane ug/L 50 52.8 106 70-130 1,1-Dichloroethene ug/L 50 53.7 107 70-130 1,2,3-Trichloropropane ug/L 50 47.4 95 70-130 1,2-Dibromo-3-chloropropane ug/L 50 53.6 107 70-130 1,2-Dibromoethane (EDB) ug/L 50 52.3 105 70-130 1,2-Dichlorobenzene ug/L 50 48.6 97 70-130 1,2-Dichloroethane ug/L 50 52.8 106 70-130 1,2-Dichloropropane ug/L 50 53.0 106 70-130 1,4-Dichlorobenzene ug/L 50 47.6 95 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1060 106 59-169 2-Butanone (MEK) ug/L 100 113 113 64-135 2-Hexanone ug/L 100 104 104 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 108 108 70-130 Acetone ug/L 100 120 120 61-157 v1 Acrylonitrile ug/L 250 272 109 61-143 Benzene ug/L 50 51.8 104 70-130 Bromochloromethane ug/L 50 55.6 111 70-130 Bromodichloromethane ug/L 50 53.1 106 70-130 Bromoform ug/L 50 51.8 104 70-130 Bromomethane ug/L 50 54.8 110 38-130lH,IK Carbon disulfide ug/L 50 57.8 116 68-130 Carbon tetrachloride ug/L 50 53.4 107 70-130 Chlorobenzene ug/L 50 48.7 97 70-130 Chloroethane ug/L 50 52.2 104 37-142 Chloroform ug/L 50 54.4 109 70-130 Chloromethane ug/L 50 47.3 95 48-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/05/2020 03:03 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 18 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry SWN-1 Pace Project No.: 92460999 LABORATORY CONTROL SAMPLE: Parameter 2790181 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,2-Dichloroethene ug/L 50 53.6 107 70-130 cis-1,3-Dichloropropene ug/L 50 54.7 109 70-130 Dibromochloromethane ug/L 50 52.5 105 70-130 Dibromomethane ug/L 50 53.2 106 70-130 Ethylbenzene ug/L 50 47.6 95 70-130 lodomethane ug/L 100 105 105 40-130 Methylene Chloride ug/L 50 54.0 108 67-132 Styrene ug/L 50 48.8 98 70-130 Tetrachloroethene ug/L 50 48.6 97 69-130 Toluene ug/L 50 50.1 100 70-130 trans-1,2-Dichloroethene ug/L 50 53.3 107 70-130 trans- 1,3-Dichloropropene ug/L 50 55.2 110 70-130 trans-1,4-Dichloro-2-butene ug/L 50 81.9 164 35-189 v1 Trichloroethene ug/L 50 53.3 107 70-130 Trichlorofluoromethane ug/L 50 51.6 103 63-130 Vinyl acetate ug/L 100 119 119 55-143 Vinyl chloride ug/L 50 59.0 118 70-131 Xylene (Total) ug/L 150 143 95 70-130 1,2-Dichloroethane-d4 (S) % 104 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8(S) % 101 70-130 MATRIX SPIKE SAMPLE: Parameter 2790183 Units 92461000001 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 21.7 108 73-134 1,1,1-Trichloroethane ug/L ND 20 27.5 137 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 20.2 101 70-136 1,1,2-Trichloroethane ug/L ND 20 24.0 120 70-135 1,1-Dichloroethane ug/L ND 20 26.8 134 70-139 1,1-Dichloroethene ug/L ND 20 28.2 141 70-154 1,2,3-Trichloropropane ug/L ND 20 19.8 99 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 21.1 106 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 21.0 105 70-137 1,2-Dichlorobenzene ug/L ND 20 21.0 105 70-133 1,2-Dichloroethane ug/L ND 20 25.7 128 70-137 1,2-Dichloropropane ug/L ND 20 24.1 121 70-140 1,4-Dichlorobenzene ug/L ND 20 21.0 105 70-133 1,4-Dioxane (p-Dioxane) ug/L ND 400 439 110 53-168 2-Butanone (MEK) ug/L ND 40 52.7 132 60-139 2-Hexanone ug/L ND 40 40.0 100 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 43.3 108 65-135 Acetone ug/L ND 40 54.8 137 60-148 v1 Acrylonitrile ug/L ND 100 124 124 64-147 Benzene ug/L 1.5 20 26.6 125 70-151 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/05/2020 03:03 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 18 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry SWN-1 Pace Project No.: 92460999 MATRIX SPIKE SAMPLE: 2790183 92461000001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Bromochloromethane ug/L ND 20 27.0 135 70-141 Bromodichloromethane ug/L ND 20 24.2 121 70-138 Bromoform ug/L ND 20 19.4 97 63-130 Bromomethane ug/L ND 20 23.5 117 15-152 IH,IK Carbon disulfide ug/L ND 20 27.8 139 69-149 Carbon tetrachloride ug/L ND 20 26.1 131 70-143 Chlorobenzene ug/L ND 20 21.6 108 70-138 Chloroethane ug/L ND 20 30.2 151 52-163 Chloroform ug/L ND 20 26.7 133 70-139 Chloromethane ug/L ND 20 25.3 126 41-139 cis-1,2-Dichloroethene ug/L 1.9 20 28.9 135 70-141 cis-1,3-Dichloropropene ug/L ND 20 23.4 117 70-137 Dibromochloromethane ug/L ND 20 21.4 107 70-134 Dibromomethane ug/L ND 20 23.8 119 70-138 Ethylbenzene ug/L ND 20 21.2 106 66-153 Iodomethane ug/L ND 40 43.9 110 20-138 Methylene Chloride ug/L ND 20 27.5 138 42-159 Styrene ug/L ND 20 21.5 108 70-135 Tetrachloroethene ug/L ND 20 21.3 107 59-143 Toluene ug/L ND 20 23.1 116 59-148 trans-1,2-Dichloroethene ug/L ND 20 27.4 137 70-146 trans- 1,3-Dichloropropene ug/L ND 20 23.1 115 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 17.6 88 47-135 v1 Trichloroethene ug/L ND 20 25.2 126 70-147 Trichlorofluoromethane ug/L ND 20 26.8 134 70-148 Vinyl acetate ug/L ND 40 46.6 117 49-151 Vinyl chloride ug/L 0.65J 20 32.9 161 70-156 M1 Xylene (Total) ug/L ND 60 64.6 108 63-158 1,2-Dichloroethane-d4 (S) % 111 70-130 4-Bromofluorobenzene (S) % 101 70-130 Toluene-d8(S) % 101 70-130 SAMPLE DUPLICATE: 2790182 92460999001 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/05/2020 03:03 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 18 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry SWN-1 Pace Project No.: 92460999 SAMPLE DUPLICATE: 2790182 Parameter Units 92460999001 Result Dup Result RPD Max RPD Qualifiers 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 1,4-Dioxane (p-Dioxane) ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 v1 Acrylonitrile ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 301H,IK Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 cis-1,2-Dichloroethene ug/L ND ND 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 lodomethane ug/L ND ND 30 Methylene Chloride ug/L ND ND 30 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 v1 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 Vinyl acetate ug/L ND ND 30 Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L ND ND 30 1,2-Dichloroethane-d4 (S) % 115 113 4-Bromofluorobenzene (S) % 105 105 Toluene-d8 (S) % 103 102 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/05/2020 03:03 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 18 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALIFIERS Project: Surry SWN-1 Pace Project No.: 92460999 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be considered an estimated value. IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/05/2020 03:03 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 18 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Surry SWN-1 92460999 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92460999001 SWN-1 EPA 3010A 521689 EPA 6010D 521702 92460999001 SWN-1 EPA 3010A 521392 EPA 6020B 521412 92460999001 SWN-1 EPA 8260D 521561 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/05/2020 03:03 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 18 g4� z o dl N xxxzz zzzzz ac �w Iuqp 4J 0 f� d,N N E4jpp, v o V SL m A E+ F4 y1 _ ..� GUQ❑•�7 Y �, E pD ° xE }3 51 VI ICF�I C}�. W... u w m ��r,y ro� C: pp m W � a� m row. ++v m NA �D•i D+I yy D-D U - 4�. - E a.€ w '?.'— a r•I .p•.e N ++.5' u'Y x -m Sp - m 0-.A a pp p T .i U; % -- 60 .m x. m.•.I -ter a Id A ��I �w� IrION i W4 13 = � i ot� N � d E 41 E m Im a. a . _ _ - �rLiLL to CL gib m L Ei Z o �i R N 0 40 .0 ° F C } m U d O O Z Ci p Gi 2 Z 7 fl aJ .E is it m G is a pEp o w cr W a' v v a a a w c o c v m E 'a Q o o r ° lg Q' o m �°rt .' m `c ° O E u � �" E..- O C J. Z. .0 .. m w v cJ z v ^ io o ' N -. ¢. E E L N m vi p �+ Via' 9 ro a o wd R Y°n 6L \\ a� �o ❑ m 'p�X 3 d E' a (D U "M A� E..r R f r n- n v C D i 0 LL L w R� 3 Q m a a C7 H S'i p a m e i O b `w 3 x — o �o ba as C a c w x U U G. E m w r.: cr'�[?�� d Uii `w r E. � 6 t' v` M o w E° 4J L3 N CL. Page 17 of 18 's,aweluoa aaassu:iul 'dwa; 4o;no 'anl;ensasaid 1oas=ui 'ploq }o ro eui oaeJ t1uoN ayt ul luas aq pIM uLJsoj s1g1 fa Ado e'saldwes aaue11d= euIlaae7 yl�oN 2u1pa;fie AwudmsIp a sj 2AaJ; anauagM :a;oN pappe palsn(pe H 101 anµenlasasd 10 4u11owy u011emasaid awll palsnfpe u01;enaasasd a;e0 7dpeoaj uodn Hd an14enaas8sd 40 adhl 41 eldweg saldwes panaasaad AN S01 }uawjsnEpd Hd zT TT OT 6 8 L N 9 ---I 4 NN E 7 T C ro < -v < < o a Ci v G'1 a 6) a Gt n M a G1 co A to � w m m m N W — � in 9 p G1 G] Li L) G1 U. r�-� A n 0 g u Cn o u = o C 0 3 3 a o o ci y o 3 x c m v" 3 3 D Ln ^ r D m m �' C O C O < < O N y 3 D D 3 D 3 a v w a d a 3 o D D D a ro 3 Q cr v C W " f7 n 4 v = ,_�, T{7 X 'Y w a d 7 o vNi fl S aw N = (� C 7 m a d N Z z N C y C C 'U C W, Z Z O Q Fa 9 [V h = D Lu Lu d a le N^'rD V m' m N Z D W y ; A = n f9 l�n (o lfin az GLAm Z D n Z \ D z A n p N m N =rot _ a a i ,-sF D n N IDQ' a C v r z p a 2 n Z G Z t w cr Z D A Z D y D n n ; 1edtarunW-ZS :1N3IIa OZ/0£/10 :oleo *no SWU 'Wd 66609VZ6:#0M :Ajpogjny 2ulnssl T }o T a0ed 6T6Z 'K 43AA :panssi;uawr000 apl0q;0 aagwnu lsll 0a 51 x0q;0;1e4 w01108** OH-n'DOO {aalenti) MR/OUCI `aseasE) PUP 110'D01'w10)110J'HOA :sunlld93x3 •saldwes uol;enuasaid jo; aguej aaupd;xm aya u!i{ilm pue pal;loan ## �aatoad s1 u0Aeu1J014aaP JO/Pue Hd;l xoq;o;ley dol laew jaay,� 00'naa-Eb0-5�-l3t!]-d :•oN;uawn:)oO tuioj u0pe34b11uaPl a11408 :aweN;uawn�op Page 18 of 18 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 December 30, 2019 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: Surry Blanks Pace Project No.: 92457586 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, ft*OL-' Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Steven R. Gandy, Municipal Engineering Services Co. Maddie German, Municipal Engineering Services REPORT OF LABORATORY ANALYSIS r e This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 21 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry Blanks Pace Project No.: 92457586 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 21 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Surry Blanks Pace Project No.: 92457586 Lab ID Sample ID Matrix Date Collected Date Received 92457586001 92457586002 EB FIB Water Water 12/14/19 09:53 12/14/19 09:47 12/16/19 08:30 12/16/19 08:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 21 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Surry Blanks 92457586 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92457586001 EB EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92457586002 FIB EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 21 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Blanks Pace Project No.: 92457586 Sample: EB Lab ID: 92457586001 Collected: 12/14/19 09:53 Received: 12/16/19 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.0 1 12/19/19 01:06 12/20/19 10:47 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 12/19/19 01:06 12/20/19 10:47 7440-38-2 Barium 3.5J ug/L 5.0 1.0 1 12/19/19 01:06 12/20/19 10:47 7440-39-3 Beryllium ND ug/L 1.0 0.20 1 12/19/19 01:06 12/20/19 10:47 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 12/19/19 01:06 12/20/19 10:47 7440-43-9 Chromium ND ug/L 5.0 1.0 1 12/19/19 01:06 12/20/19 10:47 7440-47-3 Cobalt ND ug/L 5.0 1.1 1 12/19/19 01:06 12/20/19 10:47 7440-48-4 Copper ND ug/L 5.0 2.1 1 12/19/19 01:06 12/20/19 10:47 7440-50-8 Lead ND ug/L 5.0 1.6 1 12/19/19 01:06 12/20/19 10:47 7439-92-1 Nickel ND ug/L 5.0 0.90 1 12/19/19 01:06 12/20/19 10:47 7440-02-0 Selenium ND ug/L 10.0 4.7 1 12/19/19 01:06 12/20/19 10:47 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/19/19 01:06 12/20/19 10:47 7440-22-4 Vanadium ND ug/L 5.0 1.3 1 12/19/19 01:06 12/20/19 10:47 7440-62-2 Zinc 12.8 ug/L 10.0 3.9 1 12/19/19 01:06 12/20/19 10:47 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/19/19 01:55 12/27/19 17:08 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Acetone ND ug/L 25.0 6.2 1 12/24/19 05:04 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 12/24/19 05:04 107-13-1 Benzene ND ug/L 1.0 0.15 1 12/24/19 05:04 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 12/24/19 05:04 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 12/24/19 05:04 75-27-4 Bromoform ND ug/L 1.0 0.62 1 12/24/19 05:04 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 12/24/19 05:04 74-83-9 v2 2-Butanone (MEK) ND ug/L 5.0 3.3 1 12/24/19 05:04 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 12/24/19 05:04 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 12/24/19 05:04 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 12/24/19 05:04 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 12/24/19 05:04 75-00-3 v2 Chloroform ND ug/L 5.0 2.3 1 12/24/19 05:04 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 12/24/19 05:04 74-87-3 v2 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 12/24/19 05:04 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 12/24/19 05:04 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 12/24/19 05:04 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 12/24/19 05:04 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 12/24/19 05:04 95-50-1 1,4-Dichlorobenzene 1.5 ug/L 1.0 0.26 1 12/24/19 05:04 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 12/24/19 05:04 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 12/24/19 05:04 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 12/24/19 05:04 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 12/24/19 05:04 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.29 1 12/24/19 05:04 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.25 1 12/24/19 05:04 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.19 1 12/24/19 05:04 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/30/2019 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 21 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Blanks Pace Project No.: 92457586 Sample: EB Lab ID: 92457586001 Collected: 12/14/19 09:53 Received: 12/16/19 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/24/19 05:04 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/24/19 05:04 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/24/19 05:04 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/24/19 05:04 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/24/19 05:04 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/24/19 05:04 74-88-4 v2 Methylene Chloride ND ug/L 5.0 3.7 1 12/24/19 05:04 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/24/19 05:04 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/24/19 05:04 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/24/19 05:04 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/24/19 05:04 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/24/19 05:04 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/24/19 05:04 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/24/19 05:04 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/24/19 05:04 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/24/19 05:04 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/24/19 05:04 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/24/19 05:04 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/24/19 05:04 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/24/19 05:04 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/24/19 05:04 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 100 % 70-130 1 12/24/19 05:04 460-00-4 1,2-Dichloroethane-d4 (S) 94 % 70-130 1 12/24/19 05:04 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 12/24/19 05:04 2037-26-5 Date: 12/30/2019 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 21 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Blanks Pace Project No.: 92457586 Sample: FIB Lab ID: 92457586002 Collected: 12/14/19 09:47 Received: 12/16/19 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.0 1 12/19/19 01:06 12/20/19 10:56 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 12/19/19 01:06 12/20/19 10:56 7440-38-2 Barium 3.2J ug/L 5.0 1.0 1 12/19/19 01:06 12/20/19 10:56 7440-39-3 Beryllium ND ug/L 1.0 0.20 1 12/19/19 01:06 12/20/19 10:56 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 12/19/19 01:06 12/20/19 10:56 7440-43-9 Chromium ND ug/L 5.0 1.0 1 12/19/19 01:06 12/20/19 10:56 7440-47-3 Cobalt ND ug/L 5.0 1.1 1 12/19/19 01:06 12/20/19 10:56 7440-48-4 Copper ND ug/L 5.0 2.1 1 12/19/19 01:06 12/20/19 10:56 7440-50-8 Lead ND ug/L 5.0 1.6 1 12/19/19 01:06 12/20/19 10:56 7439-92-1 Nickel ND ug/L 5.0 0.90 1 12/19/19 01:06 12/20/19 10:56 7440-02-0 Selenium ND ug/L 10.0 4.7 1 12/19/19 01:06 12/20/19 10:56 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/19/19 01:06 12/20/19 10:56 7440-22-4 Vanadium ND ug/L 5.0 1.3 1 12/19/19 01:06 12/20/19 10:56 7440-62-2 Zinc 8.4J ug/L 10.0 3.9 1 12/19/19 01:06 12/20/19 10:56 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/19/19 01:55 12/27/19 17:12 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Acetone ND ug/L 25.0 6.2 1 12/24/19 05:22 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 12/24/19 05:22 107-13-1 Benzene ND ug/L 1.0 0.15 1 12/24/19 05:22 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 12/24/19 05:22 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 12/24/19 05:22 75-27-4 Bromoform ND ug/L 1.0 0.62 1 12/24/19 05:22 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 12/24/19 05:22 74-83-9 v2 2-Butanone (MEK) ND ug/L 5.0 3.3 1 12/24/19 05:22 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 12/24/19 05:22 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 12/24/19 05:22 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 12/24/19 05:22 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 12/24/19 05:22 75-00-3 v2 Chloroform ND ug/L 5.0 2.3 1 12/24/19 05:22 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 12/24/19 05:22 74-87-3 v2 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 12/24/19 05:22 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 12/24/19 05:22 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 12/24/19 05:22 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 12/24/19 05:22 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 12/24/19 05:22 95-50-1 1,4-Dichlorobenzene 1.9 ug/L 1.0 0.26 1 12/24/19 05:22 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 12/24/19 05:22 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 12/24/19 05:22 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 12/24/19 05:22 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 12/24/19 05:22 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.29 1 12/24/19 05:22 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.25 1 12/24/19 05:22 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.19 1 12/24/19 05:22 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/30/2019 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 21 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Blanks Pace Project No.: 92457586 Sample: FIB Lab ID: 92457586002 Collected: 12/14/19 09:47 Received: 12/16/19 08:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/24/19 05:22 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/24/19 05:22 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/24/19 05:22 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/24/19 05:22 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/24/19 05:22 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/24/19 05:22 74-88-4 v2 Methylene Chloride ND ug/L 5.0 3.7 1 12/24/19 05:22 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/24/19 05:22 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/24/19 05:22 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/24/19 05:22 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/24/19 05:22 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/24/19 05:22 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/24/19 05:22 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/24/19 05:22 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/24/19 05:22 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/24/19 05:22 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/24/19 05:22 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/24/19 05:22 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/24/19 05:22 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/24/19 05:22 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/24/19 05:22 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 104 % 70-130 1 12/24/19 05:22 460-00-4 1,2-Dichloroethane-d4 (S) 97 % 70-130 1 12/24/19 05:22 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 12/24/19 05:22 2037-26-5 Date: 12/30/2019 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 21 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Blanks Pace Project No.: 92457586 QC Batch: 515674 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92457586001, 92457586002 METHOD BLANK: 2763240 Associated Lab Samples: 92457586001, 92457586002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 5.0 3.0 12/20/19 09:38 Arsenic ug/L ND 10.0 4.7 12/20/19 09:38 Barium ug/L ND 5.0 1.0 12/20/19 09:38 Beryllium ug/L ND 1.0 0.20 12/20/19 09:38 Cadmium ug/L ND 1.0 0.40 12/20/19 09:38 Chromium ug/L ND 5.0 1.0 12/20/19 09:38 Cobalt ug/L ND 5.0 1.1 12/20/19 09:38 Copper ug/L ND 5.0 2.1 12/20/19 09:38 Lead ug/L ND 5.0 1.6 12/20/19 09:38 Nickel ug/L ND 5.0 0.90 12/20/19 09:38 Selenium ug/L ND 10.0 4.7 12/20/19 09:38 Silver ug/L ND 5.0 2.5 12/20/19 09:38 Vanadium ug/L ND 5.0 1.3 12/20/19 09:38 Zinc ug/L ND 10.0 3.9 12/20/19 09:38 LABORATORY CONTROL SAMPLE: Parameter 2763241 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 495 99 80-120 Arsenic ug/L 500 506 101 80-120 Barium ug/L 500 464 93 80-120 Beryllium ug/L 500 479 96 80-120 Cadmium ug/L 500 480 96 80-120 Chromium ug/L 500 471 94 80-120 Cobalt ug/L 500 485 97 80-120 Copper ug/L 500 486 97 80-120 Lead ug/L 500 490 98 80-120 Nickel ug/L 500 481 96 80-120 Selenium ug/L 500 486 97 80-120 Silver ug/L 250 241 96 80-120 Vanadium ug/L 500 473 95 80-120 Zinc ug/L 500 477 95 80-120 Qualifiers Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2763242 2763243 MS MSD 92457300003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 508 490 102 98 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/30/2019 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 21 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Surry Blanks 92457586 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2763242 2763243 MS MSD 92457300003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L ND 500 500 519 495 103 99 75-125 5 20 Barium ug/L 22.6 500 500 498 510 95 98 75-125 3 20 Beryllium ug/L ND 500 500 500 496 100 99 75-125 1 20 Cadmium ug/L ND 500 500 509 503 102 101 75-125 1 20 Chromium ug/L ND 500 500 487 503 97 101 75-125 3 20 Cobalt ug/L 1.91 500 500 507 495 101 99 75-125 2 20 Copper ug/L 2.2J 500 500 503 494 100 98 75-125 2 20 Lead ug/L ND 500 500 508 495 102 99 75-125 2 20 Nickel ug/L 1.3J 500 500 502 499 100 99 75-125 1 20 Selenium ug/L ND 500 500 487 460 97 92 75-125 6 20 Silver ug/L ND 250 250 246 244 98 98 75-125 1 20 Vanadium ug/L ND 500 500 488 495 98 99 75-125 1 20 Zinc ug/L ND 500 500 511 507 102 101 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/30/2019 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 21 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Blanks Pace Project No.: 92457586 QC Batch: 515676 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92457586001, 92457586002 METHOD BLANK: 2763248 Matrix: Water Associated Lab Samples: 92457586001, 92457586002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 12/27/1916:52 LABORATORY CONTROL SAMPLE: 2763249 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10.1 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2763250 2763251 MS MSD 92457433003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L 0.076J 10 10 10.6 10.9 106 108 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/30/2019 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 21 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Blanks Pace Project No.: 92457586 QC Batch: 516422 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Associated Lab Samples: 92457586001, 92457586002 METHOD BLANK: 2766873 Associated Lab Samples: 92457586001, 92457586002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 12/24/19 00:18 1,1,1-Trichloroethane ug/L ND 1.0 0.18 12/24/19 00:18 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 12/24/19 00:18 1,1,2-Trichloroethane ug/L ND 1.0 0.24 12/24/19 00:18 1,1-Dichloroethane ug/L ND 1.0 0.27 12/24/19 00:18 1,1-Dichloroethene ug/L ND 1.0 0.24 12/24/19 00:18 1,2,3-Trichloropropane ug/L ND 1.0 0.35 12/24/19 00:18 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 12/24/19 00:18 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 12/24/19 00:18 1,2-Dichlorobenzene ug/L ND 1.0 0.29 12/24/19 00:18 1,2-Dichloroethane ug/L ND 1.0 0.34 12/24/19 00:18 1,2-Dichloropropane ug/L ND 1.0 0.19 12/24/19 00:18 1,4-Dichlorobenzene ug/L ND 1.0 0.26 12/24/19 00:18 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 12/24/19 00:18 2-Butanone (MEK) ug/L ND 5.0 3.3 12/24/19 00:18 2-Hexanone ug/L ND 5.0 0.57 12/24/19 00:18 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 12/24/19 00:18 Acetone ug/L ND 25.0 6.2 12/24/19 00:18 Acrylonitrile ug/L ND 10.0 0.90 12/24/19 00:18 Benzene ug/L ND 1.0 0.15 12/24/19 00:18 Bromochloromethane ug/L ND 1.0 0.34 12/24/19 00:18 Bromodichloromethane ug/L ND 1.0 0.26 12/24/19 00:18 Bromoform ug/L ND 1.0 0.62 12/24/19 00:18 Bromomethane ug/L ND 2.0 0.62 12/24/19 00:18 Carbon disulfide ug/L ND 2.0 0.40 12/24/19 00:18 Carbon tetrachloride ug/L ND 1.0 0.22 12/24/19 00:18 Chlorobenzene ug/L ND 1.0 0.23 12/24/19 00:18 Chloroethane ug/L ND 1.0 0.49 12/24/19 00:18 Chloroform ug/L ND 5.0 2.3 12/24/19 00:18 Chloromethane ug/L ND 1.0 0.39 12/24/19 00:18 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 12/24/19 00:18 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 12/24/19 00:18 Dibromochloromethane ug/L ND 1.0 0.41 12/24/19 00:18 Dibromomethane ug/L ND 1.0 0.46 12/24/19 00:18 Ethylbenzene ug/L ND 1.0 0.26 12/24/19 00:18 lodomethane ug/L ND 20.0 12.5 12/24/19 00:18 Methylene Chloride ug/L ND 5.0 3.7 12/24/19 00:18 Styrene ug/L ND 1.0 0.27 12/24/19 00:18 Tetrachloroethene ug/L ND 1.0 0.16 12/24/19 00:18 Toluene ug/L ND 1.0 0.24 12/24/19 00:18 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 12/24/19 00:18 v2 v2 v2 v2 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/30/2019 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 21 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Blanks Pace Project No.: 92457586 METHOD BLANK: 2766873 Associated Lab Samples: 92457586001, 92457586002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 12/24/19 00:18 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 12/24/19 00:18 Trichloroethene ug/L ND 1.0 0.22 12/24/19 00:18 Trichlorofluoromethane ug/L ND 1.0 0.31 12/24/19 00:18 Vinyl acetate ug/L ND 2.0 1.4 12/24/19 00:18 Vinyl chloride ug/L ND 1.0 0.24 12/24/19 00:18 Xylene (Total) ug/L ND 1.0 0.63 12/24/19 00:18 1,2-Dichloroethane-d4 (S) % 97 70-130 12/24/19 00:18 4-Bromofluorobenzene (S) % 101 70-130 12/24/19 00:18 Toluene-d8 (S) % 100 70-130 12/24/19 00:18 LABORATORY CONTROL SAMPLE: Parameter 2766874 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 47.2 94 70-130 1,1,1-Trichloroethane ug/L 50 41.9 84 70-130 1,1,2,2-Tetrachloroethane ug/L 50 47.5 95 70-130 1,1,2-Trichloroethane ug/L 50 45.5 91 70-130 1,1-Dichloroethane ug/L 50 44.3 89 70-130 1,1-Dichloroethene ug/L 50 47.0 94 70-130 1,2,3-Trichloropropane ug/L 50 48.0 96 70-130 1,2-Dibromo-3-chloropropane ug/L 50 43.8 88 70-130 1,2-Dibromoethane (EDB) ug/L 50 48.7 97 70-130 1,2-Dichlorobenzene ug/L 50 48.9 98 70-130 1,2-Dichloroethane ug/L 50 44.0 88 70-130 1,2-Dichloropropane ug/L 50 46.2 92 70-130 1,4-Dichlorobenzene ug/L 50 47.7 95 70-130 1,4-Dioxane (p-Dioxane) ug/L 1000 943 94 59-169 2-Butanone (MEK) ug/L 100 90.9 91 64-135 2-Hexanone ug/L 100 90.5 91 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 89.8 90 70-130 Acetone ug/L 100 94.3 94 61-157 Acrylonitrile ug/L 250 227 91 61-143 Benzene ug/L 50 44.6 89 70-130 Bromochloromethane ug/L 50 42.9 86 70-130 Bromodichloromethane ug/L 50 42.1 84 70-130 Bromoform ug/L 50 40.8 82 70-130 Bromomethane ug/L 50 34.7 69 38-130 v2 Carbon disulfide ug/L 50 45.5 91 68-130 Carbon tetrachloride ug/L 50 40.6 81 70-130 Chlorobenzene ug/L 50 48.0 96 70-130 Chloroethane ug/L 50 35.4 71 37-142 v2 Chloroform ug/L 50 43.6 87 70-130 Chloromethane ug/L 50 36.7 73 48-130 v2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/30/2019 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 21 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Blanks Pace Project No.: 92457586 LABORATORY CONTROL SAMPLE: Parameter 2766874 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,2-Dichloroethene ug/L 50 43.7 87 70-130 cis-1,3-Dichloropropene ug/L 50 46.7 93 70-130 Dibromochloromethane ug/L 50 43.6 87 70-130 Dibromomethane ug/L 50 45.7 91 70-130 Ethylbenzene ug/L 50 45.5 91 70-130 lodomethane ug/L 100 73.1 73 40-130 v2 Methylene Chloride ug/L 50 42.7 85 67-132 Styrene ug/L 50 47.6 95 70-130 Tetrachloroethene ug/L 50 45.7 91 69-130 Toluene ug/L 50 42.1 84 70-130 trans-1,2-Dichloroethene ug/L 50 44.7 89 70-130 trans- 1,3-Dichloropropene ug/L 50 44.8 90 70-130 trans-1,4-Dichloro-2-butene ug/L 50 44.9 90 35-189 Trichloroethene ug/L 50 45.9 92 70-130 Trichlorofluoromethane ug/L 50 41.5 83 63-130 Vinyl acetate ug/L 100 99.9 100 55-143 Vinyl chloride ug/L 50 46.5 93 70-131 Xylene (Total) ug/L 150 135 90 70-130 1,2-Dichloroethane-d4 (S) % 87 70-130 4-Bromofluorobenzene (S) % 97 70-130 Toluene-d8 (S) % 97 70-130 MATRIX SPIKE SAMPLE: Parameter 2766876 Units 92457589002 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 19.6 98 73-134 1,1,1-Trichloroethane ug/L ND 20 18.8 94 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 19.1 96 70-136 1,1,2-Trichloroethane ug/L ND 20 19.5 98 70-135 1,1-Dichloroethane ug/L ND 20 20.2 101 70-139 1,1-Dichloroethene ug/L ND 20 20.1 100 70-154 1,2,3-Trichloropropane ug/L ND 20 19.6 98 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 17.3 87 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 20.4 102 70-137 1,2-Dichlorobenzene ug/L ND 20 20.8 104 70-133 1,2-Dichloroethane ug/L ND 20 18.8 94 70-137 1,2-Dichloropropane ug/L ND 20 20.9 104 70-140 1,4-Dichlorobenzene ug/L ND 20 21.1 106 70-133 1,4-Dioxane (p-Dioxane) ug/L ND 400 376 94 53-168 2-Butanone (MEK) ug/L ND 40 37.1 93 60-139 2-Hexanone ug/L ND 40 33.9 85 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 34.4 86 65-135 Acetone ug/L ND 40 37.8 95 60-148 Acrylonitrile ug/L ND 100 94.9 95 64-147 Benzene ug/L ND 20 19.8 99 70-151 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/30/2019 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 21 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Blanks Pace Project No.: 92457586 MATRIX SPIKE SAMPLE: 2766876 92457589002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Bromochloromethane ug/L ND 20 19.2 96 70-141 Bromodichloromethane ug/L ND 20 18.4 92 70-138 Bromoform ug/L ND 20 16.3 81 63-130 Bromomethane ug/L ND 20 18.9 95 15-152 Carbon disulfide ug/L ND 20 20.6 103 69-149 Carbon tetrachloride ug/L ND 20 19.3 96 70-143 Chlorobenzene ug/L ND 20 21.1 105 70-138 Chloroethane ug/L ND 20 20.1 100 52-163 Chloroform ug/L ND 20 19.5 98 70-139 Chloromethane ug/L ND 20 17.4 87 41-139 cis-1,2-Dichloroethene ug/L 3.0 20 22.3 96 70-141 cis-1,3-Dichloropropene ug/L ND 20 20.2 101 70-137 Dibromochloromethane ug/L ND 20 18.3 91 70-134 Dibromomethane ug/L ND 20 20.1 101 70-138 Ethylbenzene ug/L ND 20 20.1 101 66-153 lodomethane ug/L ND 40 28.6 72 20-138 Methylene Chloride ug/L ND 20 19.5 97 42-159 Styrene ug/L ND 20 20.8 104 70-135 Tetrachloroethene ug/L ND 20 20.2 101 59-143 Toluene ug/L ND 20 18.8 94 59-148 trans-1,2-Dichloroethene ug/L ND 20 20.3 102 70-146 trans- 1,3-Dichloropropene ug/L ND 20 19.2 96 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 19.1 96 47-135 Trichloroethene ug/L ND 20 21.0 105 70-147 Trichlorofluoromethane ug/L ND 20 20.4 102 70-148 Vinyl acetate ug/L ND 40 39.3 98 49-151 Vinyl chloride ug/L ND 20 22.4 112 70-156 Xylene (Total) ug/L ND 60 60.0 100 63-158 1,2-Dichloroethane-d4 (S) % 88 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 97 70-130 SAMPLE DUPLICATE: 2766875 Parameter Units 92457587004 Result Dup Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/30/2019 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 21 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Blanks Pace Project No.: 92457586 SAMPLE DUPLICATE: 2766875 Parameter Units 92457587004 Result Dup Result RPD Max RPD 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 1,4-Dioxane (p-Dioxane) ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Acrylonitrile ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 30 Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 cis-1,2-Dichloroethene ug/L ND ND 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 lodomethane ug/L ND ND 30 Methylene Chloride ug/L ND ND 30 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 Vinyl acetate ug/L ND ND 30 Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L ND ND 30 1,2-Dichloroethane-d4 (S) % 95 97 4-Bromofluorobenzene (S) % 99 99 Toluene-d8 (S) % 100 101 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/30/2019 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 21 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Surry Blanks Pace Project No.: 92457586 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/30/2019 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 17 of 21 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Surry Blanks Pace Project No.: 92457586 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92457586001 EB EPA 3010A 515674 EPA 6010D 515694 92457586002 FB EPA 3010A 515674 EPA 6010D 515694 92457586001 EB EPA 3010A 515676 EPA 6020B 515696 92457586002 FB EPA 3010A 515676 EPA 6020B 515696 92457586001 EB EPA 8260D 516422 92457586002 FB EPA 8260D 516422 Date: 12/30/2019 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 21 Document Name: Document Revised: February 7, 2018 m _ aceAnaVidaf Sample Condltlan Upon Receipt(5CUR) Page 1 of 2 DocumentNo,: Issuing Authority: / F-CAR-CS-033-Rev,06 Pace Carolinas Quality Office Laboratory receiving samples; �-, / Asheville ❑ Eden[] Greenwood ❑ Huntersville D- Raleigh❑ Mechanicsville❑ Conditionsample Client Name: W4# : 92457586 Upon Roceipt I Project #• Courier: ❑Fed Ex [-]UPS V ❑O her: [—]ClientH1111II 1111111111111 ❑ ac Commercial - e ❑ 92457586 Custody Seal present? ❑Yes Vo Seols Intact? []Yes 29-0— Packing Material: ❑Bubble Wrap ubble Bags ❑None ❑ Other Thermometer: Type of Ice: et ❑Blue EWGun ID: 92TO58 Cooler Temp (°CJ: ) Corfection Factor: Add/Subtract (aC) 0.0°C Cooler Temp Corrected ('Cj: Z- S USDA Regulated Sall (EY-N/A, water sample) Did samples orkgina a in a quarantine ?.one with in the United States: CA, NY, or 5C (check maps)? r7,, ral Date/Initials Person Examining Contents:_ Blologlcal sure Frozen? ❑yes No ❑PI/A ❑None Temp should be above Freezing to VC []Samples out of temp criteria. Samples an ice, cooling process hasbegun Did samples originate tram a foreign source (internationally, Inrinriina 1-1-5 and Piiortn Ricol? MVP9 F-1No Comments/Discrepancy: Chain of Custody Present? Iles []NO ❑N/A Samples Arrived within Hold Time? E3<es [—]No ❑N/A 2. Short Hold Time Analysis (c72 hr.)? ❑Yes MINo . ❑N/A 3. Rush Turr. Around Time Requested? ❑Yes 060 ❑N/A 4. Sufficient Valuate? _ 2<.' ON. ❑N/A Cornet Containers Used? lie, ❑No ❑N/A a� Pace Containers Used? ONO ❑N/A ° Containers Intact? ,9<- Mires []No ❑N/A 7. Dissolved analysis: Samples Field fiktered? ❑Yes ❑No_ ©/A S. Sample tabels Mach CCIC? N/A 9. -IncludesDate/Time/ID/Analysis Matrix:�_V Heafispace in VOA Vials (>5-6mm)? O'res 215u ❑N/A 10. Trip blank Present? [. Iles o ❑N/A 11, Trip Blank Custody Seals Present? ;Yes ❑No A COMMENTS/SAMPLE DISCREPANCY Lot iD of split containers: CLIENT NOTIFICATION/RESOLUTION Field Data Required? 1'IYes []No Person contacted: DateAlme: Project Manager SCURF Review: N/19— Date: f Project Manager SRF Review; dmi)) _ Date: Page 19 of 21 Document Name: Document Revised: February 7, 2018 i aCekmlyhcal � Sample Conditian Upon Recelpt(5CURI Page 1 of 2 Document No.: ISsuingAuthority: F-CAR-CS.033-Rev.06 Pace Carolinas Quality Office *Check mark toga half of box if pH and/or dechlorination Is verified and within the acceptance range for preservation samples. Exceptlans: VOA, Coliform, TOC, Oil and Grease, DRO/80E5 (water) DOC, UHS *Bottom alf of box is to t51 numher ofbottle Project # WO#:92457586 PM: AMB Due Date: 12/31/19 CLIENT: 92-Municipal N Z z m a a n U z Z Z n Z 9 „ ? m v v 2 v V r� .� � 0 o� N V U _ .. Q m y z z z v = V � v N w OT _ N c. n e. Q cL E Z O Z 7 "} = N a d C C a n Z 7- z '° , V a > N G u V u � � Z u N Z T3 u 0 z v - U m .+ a v u t iv u u e b m n n E 9 E Q a e a O a O m m o E Q c a a a a J 4 a N Q C a Q Q r�'v 7 O A vi '^ M a E E E `w J E E J E E `m `v E a` E m E E E - 10 E E E E E E Ny } O M N N N N « l b N - a L7 ❑ S oa C3 C �p = N V�1 o N 0 a Q r .-� N > N > Ja r� u u. 7 yr 4 2 he- b Y a Y r- r C d 0 Q� E Q M N �-I M C 7 �"� V' N Ci M [7 4.7 M l7 U) l7 GI U 0 V t7 O v1 N a M d l? {� lJ 0� 4 s a m a m 4 m d m d � 6 m d m a a a a a a ,.9 �> > > > > a > > q w, v, m a > 7 0 t _ 2 \NN\ 3 \ . "-T-7- —T NN I — 6 � 9 \N\\ N\ .10 -1 \ 11 NNI pH Adjustment Log for Preserved Sarnples Sample ID Type of Picservative pH upon receipt Date presorvatlon adjusted Time preservation adjusted Amount of Preservative added Lot S Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will heient to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 20 of 21 a 10 U u R cC E (] N U A ❑ 7 S/A v Cf ro Q] C� �+Lu r C � d p 0 N N ❑ T Ua O LL U 0 0 Z c a3 U� (NIA) �\ pelul saldweS C N z O {NIA)laloo0 O r z z paEeas Fpmasno 4r, ❑ WJI -7 W uo POAIeanlaOaZ� Q U � m o - 0_ m 0 u! dN31 R m m L (� R � jr m D 0 v W Ci� Q- r LL Q Yi R ❑ Q V m m c p� z (NIS-NON)auezolO-y'L x m z in a: q w n z 4ddy-slelavJ x x U U. l �J z l ddV-sOOA x x NIA Isal sasAll!uv LO ' C mo �aylO (6 6loueyUalN W cn w �j d m HOeN ca e .0 E m all m n. SONH w VOSZH W 0` r 12 C.) r c z m 0 m ..O m pan asaldul o °, b m a m C7 a s F q t O m E 0¢ B ti U w N < m Ei a SHD NEViNOO AO# v v Q w ix w NOElU3il03 lv dW313ldWv3 W Z a a ❑ z z d a o W O W m ce w ¢ ❑ z J}I z w z z ce H z 4L a m W o w af ! Q all N �[ S C ❑ 6 '0 LU `- C j E j (d'N0�=7 9V2!`.?=`J) 3dA131dritl5 U` 1 0 z `m p z' `m o z J (yaE oy sapm p!jm ees) y400 xlHlvvd t 5 m v u a W a- O m O r P m -= F a w a m .� w Uo a N 03 C20ti u Q o 0. T 0. m N m 1� U a 0 U x� 3_ C _ _ y i 6�� a` in0 TQON N 2JE CD ~ co z WQvcn T QLLI c O cr m G1 N z c Lu r- an o E6 rnR XXH LO y a 'mtl Om¢ Q ti' m 6 EcDd-- N ❑Eo m mvW LLQ E aQ #3AIlI rNM tiNIY C7 ¢� P�nc 9 1 of 21