MO-5755_20257_CA_MRP_20200320

SUBSEQUENT CORRECTIVE ACTION
PERFORMANCE REPORT
Brack Griffin Property (Incident #20257)
2601 Marshville-Olive Branch Road
Marshville, Union County, North Carolina
March 20, 2020
Terracon Project No. 71159684A
Prepared for:
North Carolina Department of Environmental Quality
Division of Waste Management
Raleigh, North Carolina
Prepared by:
Terracon Consultants, Inc.
Charlotte, North Carolina
Table of Contents
A.SITE INFORMATION ...........................................................................................................1
B.EXECUTIVE SUMMARY .....................................................................................................2
C.SITE HISTORY AND CHARACTERIZATION ......................................................................2
C.1 Site Setting .....................................................................................................................3
C.2 Release Summary ..........................................................................................................4
C.4 Previous Investigations .................................................................................................4
C.3 Water Supply Wells ........................................................................................................7
C.4 Surface Water .................................................................................................................7
C.5 Land Use Information .....................................................................................................7
D.ASSESSMENT INFORMATION .......................................................................................8
D.1 Site Geology and Hydrogeology ....................................................................................8
D.2 Remediation Activities ...................................................................................................9
D.2.1 Free Product Evaluation ........................................................................................................... 9
D.2.2 Injection Activities ............................................................................................................9
E.CONCLUSIONS AND RECOMMENDATIONS ..............................................................10
FIGURES
Figure 1: Site Location Map
Figure 2: Site Plan and Injection Point Location Map
Figure 3: Groundwater Elevation Map
Figure 4: Water Supply Well Location Map
Figure 5: Groundwater Analytical Results (March 2020)
TABLES
Table 1: Water Supply Well Information
Table 2: Monitoring Well Construction Information and Historical Groundwater
Elevations
Table 3: Summary of Groundwater Analytical Results
APPENDIX
Appendix A: Laboratory Analytical Report
Appendix B: Field Notes
Appendix C: Photographs
Brack Griffin Property
Marshville, North Carolina
Project Number 71159684A
Incident No. 20257
March 20, 2020
Responsive ■Resourceful ■Reliable 1
SUBSEQUENT CORRECTIVE ACTION PERFORMANCE
REPORT
A. SITE INFORMATION
Date of Report:March 20, 2020
NCDEQ Incident No:20257
Facility ID:Unknown
Site Name:Brack Griffin Property
Site Location:2601 Marshville-Olive Branch Road
Marshville, Union County, North Carolina 28103
Latitude:N 35o 01’ 58.6”
Longitude:W 80o 19’ 35.6”
UST Owner/Operator:Brack Griffin (Former Owner)
Current Property Owner: Patsy Ann Griffin, Trustee
Heather Griffin
Current Property
Occupant:Thrift Shop
Consultant:Terracon Consultants, Inc. (Contact: Flora D’Souza)
2701 Westport Road
Charlotte, North Carolina 28208
[phone]
Release Information:Release Discovery Date: 1999
Estimated Quantity: Unknown
Cause of Release: Unknown
Source of Release: One 500-gallon gasoline UST
Currently Active Tanks: None
Brack Griffin Property
Marshville, North Carolina
Project Number 71159684A
Incident No. 20257
March 20, 2020
Responsive ■Resourceful ■Reliable 2
I, Christopher L. Corbitt, a Licensed Geologist for Terracon Consultants, Inc., do certify that the
information contained in this report is correct and accurate to the best of my knowledge.
Christopher L. Corbitt, L.G.
NC License No. 1015
Terracon Consultants, Inc. is licensed to practice geology/engineering in North Carolina. The
certification number of the corporation is F-0869.
B. EXECUTIVE SUMMARY
The purpose of this report is to summarize the groundwater sampling event conducted in March
2020. Terracon mobilized to the site on March 5, 2020 to collect groundwater samples from
monitoring wells MW-1, MW-4, MW-5 and MW-11 and water supply wells WSW-1 and WSW-2
for laboratory analysis. Prior to sampling, Terracon gauged the groundwater levels in the
monitoring wells. During this sampling event, depth to groundwater in the monitoring wells ranged
from approximately 1.56 feet (well MW-1) below ground surface (bgs) to 15.25 feet bgs in well
MW-4. Based on groundwater level measurements, the estimated groundwater flow direction is
to the east/northeast. Terracon was unable to sample the water supply wells due to no responses
to our water supply well letters and no one at home to grant us access. The water samples were
submitted for laboratory analysis of volatile organic compounds (VOCs) by Standard Method
6200, including MTBE, IPE and EDB.
According to the laboratory analytical report, 1,2-dichloroethane (957 micrograms per liter [µg/L])
was detected in monitoring well MW-5 at a concentration above its Gross Contamination Level
(GCL). Benzene (2,900 µg/L), MTBE (26.2 µg/L), naphthalene (307 µg/L), toluene (776 µg/L)
1,2,4-trimethylbenzene (662 µg/L) and total xylenes (2012 µg/L) were detected at concentrations
above their respective NCAC 15A 2L standards in well MW-5. Bromodichloromethane (2.6 µg/L),
not related to the petroleum release, was detected above its 2L standard in well MW-11. Various
other petroleum constituents were detected in wells MW-5 and MW-11 at concentrations below
their respective 2L standards. Contaminants of concern were not detected above the laboratory
method detection limits (MDLs) in wells MW-1 or MW-4.
Based on information obtained during the completion of these assessment activities, Terracon
provides the following conclusions and findings.
No free product was encountered in the groundwater at the site.
1,2-Dichloroethane (957 µg/L) was detected in monitoring well MW-5 above its GCL.
Brack Griffin Property
Marshville, North Carolina
Project Number 71159684A
Incident No. 20257
March 20, 2020
Responsive ■Resourceful ■Reliable 3
Benzene, MTBE, naphthalene, toluene, 1,2,4-trimethylbenzene and total xylenes were
detected at concentrations above their respective 2L standards in well MW-5.
Bromodichloromethane was also detected above its 2L standard in well MW-11. Other
constituents of concern were detected in the two wells at concentrations below the 2L
standards.
Constituents of concern were not detected in wells MW-1 or MW-4 above the MDLs.
Based on the analytical results, many of the petroleum constituent concentrations in well
MW-5 have increased (apparent rebound) since the injection event was conducted in 2018.
Petroleum constituents have shown a 100 percent reduction in well MW-11 since the injection
event in 2018.
Based on the findings of our assessment activities, the following recommendations are provided for
the site.
Terracon recommends removing the injection cap from MW-5 by cutting the PVC pipe for
the well so an O-Sox insert can be placed inside of the well during the next sampling event.
Terracon recommends continued semi-annual sampling of the on-site monitoring wells
(September 2020).
C. SITE HISTORY AND CHARACTERIZATION
The purpose of this report is to document the groundwater sampling event conducted in March
2020, approximately two years after injection activities were conducted at the Brack Griffin
property in February 2018. The site is located at 2601 Marshville-Olive Branch Road in
Marshville, Union County, North Carolina (Figure 1). This Subsequent Corrective Action
Performance Report was prepared for the site in response to a request by NCDEQ Incident
Manager, Ms. Sharon Ghiold with the NCDEQ Division of Waste Management, State Lead
Program.
The Corrective Action Performance Report was prepared in general accordance with the 15A
NCAC 2L.0115 regulations and the NCDEQ Underground Storage Tank (UST) Section
Guidelines for Assessment and Corrective Action for UST Releases, dated July 15, 2008, revised
December 2013, under the supervision of Mr. Christopher L. Corbitt, a North Carolina registered
professional geologist (North Carolina License No. 1015).
C.1 Site Setting
The Brack Griffin site is currently occupied by a thrift shop with gravel and grass-covered areas.
The adjacent properties to the north, west and south are developed as rural residences. An
adjacent property to the southeast is occupied by a former gasoline station identified as the
Benton Nance Grocery. The site and surrounding properties are depicted in Figure 2.
Brack Griffin Property
Marshville, North Carolina
Project Number 71159684A
Incident No. 20257
March 20, 2020
Responsive ■Resourceful ■Reliable 4
C.2 Release Summary
Reportedly, a petroleum release was discovered at the site in 1999 related to a 500-gallon
gasoline UST. Soil samples collected at the time of UST removal activities indicated elevated
levels of gasoline and diesel range petroleum hydrocarbons at the base of the UST excavation.
Reportedly, a second UST was suspected of being located to the west of the 500-gallon UST but
no other tanks were found following investigative excavations. The adjacent property located to
the southeast of the site (Former Benton Nance Grocery, Incident No. 18563) is currently an
active LUST incident. A chronological summary of petroleum releases and assessment activities
at the site is included in the following section of the report.
C.4 Previous Investigations
According to a Groundwater Monitoring Report by S&ME dated February 16, 2012, previous
assessment activities conducted at the site included the following investigations.
On September 2, 1999, OK Enterprises (OKE), Inc. removed a 500-gallon gasoline UST
from the Brack Griffin property. S&ME monitored the removal of the UST and collected
soil samples as required by NCDEQ guidelines. Two soil samples were collected from
the UST excavation at depths of approximately 6.5 and 7 feet bgs. Results of laboratory
analyses indicated the presence of gasoline range organics (GRO) and diesel range
organics (DRO) in both samples at levels exceeding the regulatory action level. A second
gasoline tank was suspected of being located on the site between Old Goldmine Road
and the on-site building; however, test pits did not identify evidence of another tank. The
tank basin and test pit excavations were backfilled with gravel. Petroleum impacted soils
were disposed at an off-site facility.
On February 14, 2000, S&ME sampled eight residential water supply wells (WSW-1
through WSW-3, WSW-5, WSW-8 through WSW-10 and WSW-12) on properties near the
release incident. Laboratory results indicated MTBE was detected in two supply wells
(WSW-8 and WSW-12). Well WSW-8 is located on the Benton Nance Property to the
southeast and well WSW-12 is located to the south of the site.
On May 2, 2001, S&ME re-sampled the eight residential water supply wells. Laboratory
results detected MTBE at a concentration below the 2L standard in supply well WSW-8
located on the former Benton Nance Grocery property. On March 26, 2002, S&ME
sampled three additional supply wells (WSW-6, WSW-7 and WSW-13) and the previous
eight residential supply wells. Laboratory results indicated MTBE was detected below the
2L standard at that time in supply well WSW-8; however, the detected concentration would
exceed the currently established standard for MTBE.
TRC Environmental Corporation completed a Comprehensive Site Assessment (CSA)
Addendum, dated March 21, 2003, for the former Benton Nance Grocery property that
Brack Griffin Property
Marshville, North Carolina
Project Number 71159684A
Incident No. 20257
March 20, 2020
Responsive ■Resourceful ■Reliable 5
included soil and groundwater sampling and analysis. The findings presented in the CSA
report suggested petroleum constituents from the release on the Benton Nance Grocery
site had migrated onto the Brack Griffin property.
In July 2009, S&ME sampled three on-site monitoring wells (MW-4, MW-5 and MW-11)
and three residential water supply wells (WSW-1, WSW-2 and WSW-12). Benzene and
1,2-dichloroethane were detected above 2L standards in wells MW-4 and MW-11.
Benzene and 1,2-dichloroethane were also detected in well MW-5 at concentrations of
15,000 µg/L and 1,510 µg/L, respectively, which were above their respective GCLs. The
water supply well identified as WSW-12 contained MTBE at a concentration above the
current 2L standard.
In February 2010, S&ME completed a groundwater monitoring event that detected multiple
petroleum constituents in well MW-5 above their respective 2L standards. Benzene was
detected in well MW-5 at a concentration of 12,000 µg/L, which is above its GCL. Benzene
and naphthalene were the only constituents detected above their 2L standards in well
MW-11. Monitoring well MW-4 contained no detected petroleum constituents above
laboratory detection limits.
In September 2011, S&ME sampled monitoring well MW-11 and supply wells WSW-1 and
WSW-2. Analytical results indicated benzene was the only petroleum constituent detected
above the 2L standard in well MW-11 and no constituents were detected in supply wells
WSW-1 and WSW-2.
An 8-hour Aggressive Fluid Vapor Recovery (AFVR) event was performed by S&ME in
April 2012 at monitoring well MW-5 to reduce the levels of petroleum constituents.
Reportedly, 24 gallons of fluid were recovered and 8 gallons (calculated) of petroleum
hydrocarbons were recovered in the vapor phase. One week following the AFVR event,
S&ME collected groundwater samples from monitoring well MW-5. Analytical results
indicated that although constituent concentrations decreased, targeted compounds
(benzene and 1,2-dichloroethane) remained at levels above their respective GCLs.
In March 2013, Crawford Environmental sampled monitoring well MW-11 and supply wells WSW-
1 and WSW-2. Analytical results indicated benzene and naphthalene were detected above their
respective 2L standards in well MW-11 but no petroleum constituents were detected in the water
supply wells.
In April 2015, Terracon collected groundwater samples from on-site monitoring wells MW-4, MW-
5 and MW-11 and water supply wells WSW-2 and WSW-12. According to the laboratory analytical
report, benzene and 1,2-dichloroethane were detected in monitoring well MW-5 above their
respective GCLs. Various other petroleum constituents were detected above their 2L standards
in wells MW-5 and MW-11. MTBE was detected in supply well WSW-12 above its 2L standard.
Brack Griffin Property
Marshville, North Carolina
Project Number 71159684A
Incident No. 20257
March 20, 2020
Responsive ■Resourceful ■Reliable 6
No target analytes were identified at concentrations above the MDLs in the water samples
collected from monitoring well MW-4 and water supply well WSW-2.
On March 15, 2016, Terracon conducted a Ground Penetrating Radar/Electromagnetic (GPR/EM)
survey to identify potential metallic objects and former excavations in the subsurface soils at the
site and to install a monitoring well (MW-1) in the former tank basin. The GPR/EM survey did not
reveal indications of a UST on the site or within the road between the site and the former Benton
Nance Grocery property.
On March 18, 2016, Terracon collected groundwater samples from monitoring wells MW-1, MW-
5 and MW-11. Benzene and 1,2-dichloroethane were detected in well MW-5 above their
respective GCLs. Various other constituents were detected in wells MW-1, MW-5 and MW-11
above their 2L standards. Terracon also installed an absorbent sock into well MW-5 and three O-
Sox inserts into well MW-11.
In May 2017, Terracon collected groundwater samples from wells MW-1, MW-5 and MW-11.
Benzene and 1,2-dichloroethane were detected in well MW-5 above their respective GCLs.
Various other constituents were detected in wells MW-5 and MW-11 above their 2L standards.
Target constituents were not detected in well MW-1 above their respective 2L standards.
In January 2018, Terracon collected groundwater samples from wells MW-1, MW-5 and MW-11
and removed the well sock inserts from wells MW-5 and MW-11. Benzene and 1,2-dichloroethane
were detected in well MW-5 above GCLs. Various other contaminant concentrations were
detected in wells MW-5 and MW-11 above their respective 2L standards.
At the direction of the NCDEQ, Terracon mobilized to the site on February 12, 13 and 14, 2018
to provide oversight and document injection activities at the Brack Griffin property. Terracon
oversaw the installation of four injection points using DPT technology. The target depth for the
injection points on the site was 32 feet bgs; however, due to the presence of rock at depths
ranging from 9 to 29 feet bgs, the target depth was not reached. Injection points were advanced
from 17 feet to 29 feet bgs. The locations of the injection points are shown on Figure 2. The
solution used on the site was a slurry mixture of hydrogen peroxide (H2O2), sodium persulfate
(Na2S2O8) and zero valence iron (ZVI). The combined use of these chemicals produces long term
oxidation within the subsurface. Terracon also oversaw the injection of a sodium persulfate and
hydrogen peroxide slurry into on-site wells MW-5 and MW-11 and off-site well MW-6 located on
the Benton Nance Property. Zero valence iron was not used as an injectant in the on-site wells
because the 0.10 slot screen width in the monitoring wells would not allow the solids to pass
through the screen. A total of approximately 920 gallons of solution was used during injection
activities on the site.
In July 2018, Terracon collected groundwater samples from wells MW-1, MW-4, MW-5 and MW-
11 to evaluate groundwater conditions after injection activities were completed in February 2018.
Brack Griffin Property
Marshville, North Carolina
Project Number 71159684A
Incident No. 20257
March 20, 2020
Responsive ■Resourceful ■Reliable 7
According to the analytical report, 1,2-dichloroethane was detected in well MW-5 at a
concentration above GCLs. Various other petroleum constituents were detected in well MW-5
above their respective 2L standards. Bromomethane, bromodichloromethane, chloromethane
and 1,2-dichloroethane were detected above their respective 2L standards in well MW-11. Based
on the historical analytical data, petroleum concentrations significantly decreased in well MW-5
after the injection event conducted in February 2018.
In February 2019, Terracon collected groundwater samples from monitoring wells MW-1, MW-4,
MW-5 and MW-11 to evaluate groundwater conditions. According to the laboratory analytical
report, 1,2-dichloroethane was detected in monitoring well MW-5 at a concentration above GCLs.
Various other petroleum constituents were detected at concentrations above their respective 2L
standards in well MW-5. Chloromethane was detected at a concentration above the established
2L standard in well MW-11. Based on the historical analytical data, constituent concentrations
generally increased in well MW-5 and decreased in well MW-11.
In September 2019, Terracon collected groundwater samples from monitoring wells MW-1, MW-
5 and MW-11 to evaluate groundwater conditions. According to the analytical results, 1,2-
dichloroethane was detected in well MW-5 at a concentration that exceeded its GCL. Benzene,
bromomethane, 1,2-dicholorpropane, MTBE, naphthalene, 1,2,4-trimethylbenzene and total
xylenes were detected in well MW-5 above their respective 2L standards. Bromomethane,
chloromethane, 1,2-dichloroethane and methylene chloride were detected in well MW-11 above
their respective 2L standards. Methylene chloride has not historically been detected in well MW-
11 and is a common laboratory artifact. Based on historical data, constituent concentration trends
in well MW-5 vary whereas some constituents have increased while others have decreased.
C.3 Water Supply Wells
Based on historical receptor information, eleven water-supply wells were identified within 1,500
feet of the source area. Terracon did not conduct a water supply well/receptor survey during this
assessment. Municipal water service is not available to the site and surrounding properties.
C.4 Surface Water
The site is situated on the eastern flank of a local topographic high that is generally located to the
west of Old Goldmine Road. The source area is located approximately 330 feet southwest of
unnamed tributaries of Gourdvine Creek which discharges into Richardson Creek and Rocky
River. Surface waters are depicted on Figure 1.
C.5 Land Use Information
The adjacent properties to the north, west and south are developed as rural residences. An
adjacent property to the southeast is occupied by a vacant gasoline station identified as a heating
and air conditioning repair shop. The site and surrounding properties are depicted in Figure 2.
Brack Griffin Property
Marshville, North Carolina
Project Number 71159684A
Incident No. 20257
March 20, 2020
Responsive ■Resourceful ■Reliable 8
D. ASSESSMENT INFORMATION
D.1 Site Geology and Hydrogeology
The following resources were reviewed to evaluate site-specific geological and hydrogeological
characteristics.
Olive Branch, North Carolina, USGS 7.5-minute series topographic map, dated 1970 (Figure 1).
Geologic Map of North Carolina, dated 1985.
The Geology of the Carolinas, Carolina Geological Society Fiftieth Anniversary Volume, edited
by J. Wright Horton, Jr., and Victor A. Zullo, The University of Tennessee Press, dated 1991.
Soil Survey of Union County, North Carolina, US Department of Agriculture, Natural Resources
Conservation Service, Web Soil Survey via the Internet,
http://websoilsurvey.nrcs.usda.gov/app/.
The site is located within the Carolina Slate Belt of the Piedmont Physiographic Province. The
Piedmont Physiographic Province generally consists of low to medium elevation, rounded hills
and long rolling northeast to southwest trending ridges with incised creeks and river channels.
Rocks in the site area are described as metamorphosed mudstone and argillite.
In-place chemical and physical weathering of parent rocks typically form residual soils in the
Piedmont region. Weathering is facilitated by the presence of fractures, joints, and less resistant
minerals in the rock. In areas not altered by erosion, alluvial deposition or the activities of man,
the typical residual soil profile consists of clay-rich unconsolidated materials at the surface,
transitioning to sandy silts and silty sands at depth. Typically, the boundary between soil and
rock is not sharply defined. This transitional zone is termed “partially weathered rock” or saprolite.
Information obtained from the Web Soil Survey for Union County, depicts soils at the site as Badin
channery silt loam (BaB).
In the Piedmont, groundwater generally occurs in pore spaces within soils and in the structural
features present in the underlying rock (i.e. joints, fractures, and faults). Recharge to the water
table is primarily by precipitation infiltrating the surficial soils and percolating downward under the
influence of gravity to the water table (vadose zone). Typically, the water table is not a level
surface, but a subdued reflection of the land surface. The depth to the water table is not consistent
and is dependent upon several factors that include the amount of rainfall, permeability of the soil,
the extent of fracturing in the underlying rock and the influences of groundwater pumping.
Groundwater typically flows in directions parallel to the ground surface and under the influence of
gravity, migrates to discharge points such as surface water features, the toes of slopes or natural
springs.
Brack Griffin Property
Marshville, North Carolina
Project Number 71159684A
Incident No. 20257
March 20, 2020
Responsive ■Resourceful ■Reliable 9
Fluctuations in the depth of the water table can be expected depending on variations in
precipitation, surface water run-off and other factors not evident at the time of our subsurface
exploration. Normally, the highest levels of the water table occur in late winter and spring and the
lowest levels occur in the late summer and fall. Based on an interpreted groundwater flow
direction from topographic maps and historical data, groundwater is expected to flow generally to
the northeast from the site.
D.2 Remediation Activities
D.2.1 Free Product Evaluation
Free product was not encountered at the site.
D.2.2 Groundwater Sampling Activities
Terracon mobilized to the site on March 5, 2020 to collect groundwater samples from monitoring
wells MW-1, MW-4, MW-5 and MW-11 and water supply wells WSW-1 and WSW-2 for laboratory
analysis. The approximate locations of the monitoring wells are shown on the Site Plan (Figure
2). Prior to sampling, Terracon gauged the groundwater levels in the monitoring wells. During this
sampling event, depth to groundwater in the monitoring wells ranged from approximately 1.56
feet (well MW-1) below ground surface (bgs) to 15.25 feet bgs in well MW-4. Based on
groundwater level measurements, the estimated groundwater flow direction is to the
east/northeast. Current and historical groundwater depth measurements are provided in Table 2.
Terracon was unable to sample the water supply wells due to no responses to our water supply
well letters and no one at home to grant us access.
The groundwater samples were placed in laboratory-supplied glassware, labeled and stored in
an ice-packed cooler. The samples, along with chain-of-custody documentation, were delivered
to Pace Analytical Services, Inc. in Huntersville, North Carolina for analysis of VOCs by Standard
Method 6200B, including MTBE, IPE and EDB.
D.2.3 Analytical Results
According to the laboratory analytical report, 1,2-dichloroethane (957 micrograms per liter [µg/L])
was detected in monitoring well MW-5 at a concentration above its GCL. Benzene (2,900 µg/L),
MTBE (26.2 µg/L), naphthalene (307 µg/L), toluene (776 µg/L) 1,2,4-trimethylbenzene (662 µg/L)
and total xylenes (2012 µg/L) were detected at concentrations above their respective NCAC 15A
2L standards in well MW-5. Bromodichloromethane (2.6 µg/L), not related to the petroleum
release, was detected above its 2L standard in well MW-11. Various other petroleum constituents
were detected in wells MW-5 and MW-11 at concentrations below their respective 2L standards.
Contaminants of concern were not detected above the laboratory MDLs in wells MW-1 or MW-4.
The groundwater analytical results from the monitoring wells are summarized in Table 3 and are
depicted on Figure 5. A copy of the laboratory analytical reports is provided in Appendix A.
Brack Griffin Property
Marshville, North Carolina
Project Number 71159684A
Incident No. 20257
March 20, 2020
Responsive ■Resourceful ■Reliable 10
E. CONCLUSIONS AND RECOMMENDATIONS
Based on information obtained during the completion of these assessment activities, Terracon
provides the following conclusions and findings.
No free product was encountered in the groundwater at the site.
1,2-Dichloroethane (957 µg/L) was detected in monitoring well MW-5 above its GCL.
Benzene, MTBE, naphthalene, toluene, 1,2,4-trimethylbenzene and total xylenes were
detected at concentrations above their respective 2L standards in well MW-5.
Bromodichloromethane was also detected above its 2L standard in well MW-11. Other
constituents of concern were detected in the two wells at concentrations below the 2L
standards.
Constituents of concern were not detected in wells MW-1 or MW-4 above the MDLs.
Based on the analytical results, many of the petroleum constituent concentrations in well
MW-5 have increased (apparent rebound) since the injection event was conducted in 2018.
Petroleum constituents have shown a 100 percent reduction in well MW-11 since the injection
event in 2018.
Based on the findings of our assessment activities, the following recommendations are provided for
the site.
Terracon recommends removing the injection cap from MW-5 by cutting the PVC pipe for
the well so an O-Sox insert can be placed inside of the well during the next sampling event.
Terracon recommends continued semi-annual sampling of the on-site monitoring wells
(September 2020).
FIGURES
SITE LOCATION MAP
BRACK GRIFFIN PROPERTY (INCIDENT #20257)
2601 Marshville-Olive Branch Road
Marshville, Union County, NC
TOPOGRAPHIC MAP IMAGE COURTESY OF THE U.S. GEOLOGICAL SURVEY
QUADRANGLES INCLUDE: OLIVE BRANCH, NC (1/1/1970).
2701 Westport Road
Charlotte, NC 28208
71159684AProject Manager:
Drawn by:
Checked by:
Approved by:
HEH
CLC
CLC
1:24,000
Griffin
March 2019
Project No.
Scale:
File Name:
Date:1
VML Figure
Griffin
April 2019
2
Figure
DIAGRAM IS FOR GENERAL LOCATION
ONLY, AND IS NOT INTENDED FOR
CONSTRUCTION PURPOSES 2701 Westport Road
Charlotte, NC
BRACK GRIFFIN PROPERTY (INCIDENT #20257)
2601 Marshville-Olive Branch Road
Marshville, Union County, NC
SITE PLAN AND INJECTION POINT LOCATION MAPProject Manager:
Drawn by:
Checked by:
Approved by:
VML
Project No.
File Name:
Date:
Scale:
71159684A
VML
CLC
CLC
1” ~ 45’
denotes approximate site boundary
denotes groundwater monitoring well
MW-4
MW-5
MW-11
WSW-12
WSW-2
WSW-1
WSW-8
Site
Former Benton
Nance Grocery
(Incident #18563)
Former 500-gallon
gasoline UST basin
Pond
Grass
Grass
Gravel/
Broken Asphalt
Grass
Grass
Grass
Grass
MW-1 Current/Inactive
UST basin
denotes approximate location of aninjection point
MW-6
3
Figure
2701 Westport Road
Charlotte, NC
BRACK GRIFFIN PROPERTY (INCIDENT #20257)
2601 Marshville-Olive Branch Road
Marshville, Union County, NC
GROUNDWATER ELEVATION MAPProject Manager:
Drawn by:
Checked by:
Approved by:
VML
Project No.
File Name:
Date:
Scale:
71159684A
VML
March 2020CLC
CLC Griffin
1” ~ 45’
MW-4
MW-5
MW-11
WSW-12
WSW-2
WSW-1
WSW-8
Site
Pond
Grass
Grass
Grass
Grass
Grass
Grass
estimated groundwater contour
estimated groundwater flow direction
denotes approximate site boundary
denotes groundwater monitoring well
87.90’
88.12’
90.39’
DIAGRAM IS FOR GENERAL LOCATION ONLY, AND
IS NOT INTENDED FOR CONSTRUCTION PURPOSES
TOP-OF-CASING ELEVATION OF EACH MONITORINGWELL IS RELATIVE TO THE ASSUMED ELEVATION
OF 100 FEET AT MW-1 (ON BENTON NANCE SITE)
Former Benton
Nance Grocery
(Incident #18563)
Former 500-gallon
gasoline UST basin
Gravel/
Broken Asphalt
MW-1
Current/Inactive
UST basin
100.43’
100’
90’
87’
4
Figure
DIAGRAM IS FOR GENERAL LOCATION
ONLY, AND IS NOT INTENDED FOR
CONSTRUCTION PURPOSES 2701 Westport Road
Charlotte, NC
BRACK GRIFFIN PROPERTY (INCIDENT #20257)
2601 Marshville-Olive Branch Road
Marshville, Union County, NC
WATER SUPPLY WELL LOCATION MAPProject Manager:
Drawn by:
Checked by:
Approved by:
VML
Project No.
File Name:
Date:
Scale:
71159684A
HEH
March 2020CLC
CLC Griffin
1” ~ 465’
1,000 ft. Radius
(from release location)
500 ft. Radius
(from release location)
1,500 ft. Radius
(from release location)
WSW-1
WSW-2 WSW-3
WSW-4
WSW-5
WSW-6
WSW-7
WSW-8
WSW-9
WSW-10
WSW-11
WSW-12
WSW-13
denotes approximate propertyboundary
denotes water supply well
Griffin
March 2020
5
Figure
DIAGRAM IS FOR GENERAL LOCATION
ONLY, AND IS NOT INTENDED FOR
CONSTRUCTION PURPOSES 2701 Westport Road
Charlotte, NC
BRACK GRIFFIN PROPERTY (INCIDENT #20257)
2601 Marshville-Olive Branch Road
Marshville, Union County, NC
GROUNDWATER ANALYTICAL RESULTS (MARCH 2020)Project Manager:
Drawn by:
Checked by:
Approved by:
VML
Project No.
File Name:
Date:
Scale:
71159684A
VML
CLC
CLC
1” ~ 45’
denotes approximate site boundary
denotes groundwater monitoring well
MW-4
MW-5
MW-11
WSW-12
WSW-2
WSW-1
WSW-8
Site
Former Benton
Nance Grocery
(Incident #18563)
Former 500-gallon
gasoline UST basin
Pond
Grass
Grass
Gravel/
Broken Asphalt
Grass
Grass
Grass
Grass
MW-1 Current/Inactive
UST basin
Sample ID: MW-1
Groundwater Sample
6200 – all target analytes non-detect
Sample ID: MW-4
Groundwater Sample6200 – all target analytes non-detect
Sample ID: MW-11
Groundwater Sample6200 –Bromodichloromethane: 2.6J µg/LChloroform: 27.2 µg/L*Values above 2L Standards are in bold.
Sample ID: MW-5
Groundwater Sample
6200 –Benzene: 2,900 µg/L
Chloroethane: 58.4 µg/L
Diisopropyl ether: 64.6 µg/L
Ethylbenzene: 244 µg/L
1,2-Dichloroethane: 957 µg/L
Isopropylbenzene: 26.2 µg/L
Methyl-tert-butyl ether: 26.2 µg/L
Naphthalene: 307 µg/L
n-Propylbenzene: 55.9 µg/L
Toluene: 776 µg/L
1,2,4-Trimethylbenzene: 662 µg/L
1,3,5-Trimethylbenzene: 236 µg/LTotal Xylenes: 2,012 µg/L*Values above 2L Standards are inbold.
*Values above GCLs are in red.
TABLES
TABLE 1
Water Supply Well Information
Brack T. Griffin Property
Marshville, North Carolina
Terracon Project No. 71159684A
NCDEQ Incident No. 20257
Well ID Property Owner Property Address Mailing Address Distance/Directions from
source area Well Status/Use Municpal
Water Utilized Parcel No.Notes
WSW-1 Martha L McKenzie 4330 Marshville-Olive Branch Road 4330 Marshville-Olive Branch Road 325/SW Potable No 02077015
WSW-2 Patsy Ann Griffin Trustee 7007 Old Gold Mine Road 7007 Old Gold Mine Road 170/NNE Potable No 02040001
WSW-3 David and Barbara Cauthen 6415 Deep Springs Road 470 North Pine Meadows Drive
Debary, FL 32713 1125/NW Potable No 02043019B
WSW-4 Dwight and Patricia Newton 6422 Nance-Tarlton Road 6422 Nance-Tarlton Road 1200/NW Potable No 02040013
WSW-5 Erik Hartsell 6503 Deep Springs Road PO Box 579 1260/W Potable No 02040014
WSW-6 Timothy and Tammy Britt 6507 Deep Springs Road PO Box 514 1530/W Potable No 02040011
WSW-7 Cecil and William Horne 6515 Deep Springs Road PO Box 673 1620/W Potable No 02040012A
WSW-8 Kermit and Joan Thomas 2602 Marshville-Olive Branch Road 5121 Ansonville Road 245/SE Active No 02043011
WSW-9 Crossroads AME Zion Church 7110 Old Goldmine Road
Peachland, NC28133
7110 Old Goldmine Road
Peachland, NC28133 510/S Potable No 02043012
WSW-10 Ralph and Michelle Medlin 7125 Old Gold Mine Road
Peachland, NC 28133 PO Box 591 1035/SE Potable No 02043021
WSW-11 James and Mary Tarlton 7203 Old Gold Mine Road
Peachland, NC 28133
7203 Old Gold Mine Road
Peachland, NC 28133 1205/SE Potable No 02043017
WSW-12 Gregory Joseph Tedder 2530 Marshville-Olive Branch Road 2530 Marshville-Olive Branch Road 275/S Potable No 02043020
WSW-13 David and Elaine Kiker 6426 Deep Springs Road PO Box 642 1115/W Potable No 02043018
Unless otherwise noted the address is located in Marshville, NC 28103
TABLE 2
Monitoring Well Construction Information and Historical Groundwater Elevations
Brack T. Griffin Property
Marshville, North Carolina
Terracon Project No. 71159684A
NCDEQ Incident No. 20257
Well Id Date Installed Date Water Level Measured Well Casing
Diameter (in.)Screened Interval Bottom of Well (ft. BGS) Top of Casing Elevation (ft.)Depth to Water from Top of
Casing (ft.)Groundwater Elevation (ft.)
3/18/2016 3.45 98.54
5/1/2017 2.27 99.72
1/4/2018 3.15 98.84
7/18/2018 4.14 97.85
3/25/2019 2.42 99.57
9/17/2019 3.32 98.67
3/5/2020 1.56 100.43
2/13/2003 17.5 85.65
7/8/2009 19.71 83.44
2/22/2010 16.92 86.23
9/19/2011 --
4/3/2015 13.91 89.24
3/18/2016 13.54 89.61
5/1/2017
1/4/2018
7/18/2018 23.46 79.69
3/25/2019 11.43 91.72
3/5/2020 15.25 87.90
2/13/2003 19.59 81.48
7/8/2009 15.21 85.86
2/22/2010 14.71 86.36
9/19/2011 --
4/3/2015 11.05 90.02
3/18/2016 9.58 91.49
5/1/2017 16.79 84.28
1/4/2018 23.53 77.54
7/18/2018 19.64 81.43
3/25/2019 9.61 91.46
9/17/2019 16.34 84.73
3/5/2020 12.95 88.12
2/13/2003 15.73 84.06
7/8/2009 13.81 85.98
2/22/2010 13.68 86.11
9/19/2011 16.81 82.98
4/3/2015 9.7 90.09
3/18/2016 10.45 89.34
5/1/2017 14.61 85.18
1/4/2018 20.96 78.83
7/18/2018 17.57 82.22
3/25/2019 8.79 91.00
9/17/2019 14.87 84.92
3/5/2020 9.40 90.39
*Top-of-Casing elevation of each monitoring well is relative to the assumed elevation of 100 feet at MW-1 (On Benton Nance Site)
101.99
MW-4 Unknown 2 14-24 24 103.15
MW-1 3/15/2016 2 3-18 18
Not Measured
Not Measured
MW-11 Unknown 2 10-30 30 99.79
MW-5 Unknown 2 23-33.5 33.5 101.07
TABLE 3
Summary of Groundwater Analytical Results
Brack T. Griffin PropertyMarshville, North Carolina
Terracon Project No. 71159684ANCDEQ Incident No. 20257
Contaminant of Concern→
Well/SampleI.D.Date Collected(mm/dd/yy)
1 10 NS 0.6 70 70 25 100 70 3000 3 NS 0.4 0.6 70 0.02 600 70 5 20 6 70 25 600 400 400 5005,000 10,000 NS NS 6,900 8500 11700 NS 70000 NS 3000 NS 400 6,000 70,000 50 84,500 25,000 5,000 20,000 6,000 30,000 11,700 260,000 28,500 25,000 85,500
3/18/2016 6.9 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 1.7J <0.5 <0.5 <0.5 11.7 0.71 1.9
5/1/2017 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.50 <0.50 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <1.0 <0.25 <1.0 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25
1/4/2018 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40
7/18/2018 <0.25 <2.5 <2.5 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.50 <0.50 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <1.0 <0.25 <1.0 <0.25 <0.25 <0.25 <0.25 <0.25 <0.50
3/25/2019 <0.25 <2.5 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.50 <0.50 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <1.0 <0.25 <1.0 <0.25 <0.25 <0.25 <0.25 <0.25 <0.50
9/17/2019 <0.25 <2.5 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.50 <0.50 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <1.0 <0.25 <1.0 <0.25 <0.25 <0.25 <0.25 <0.25 <0.50
3/5/2020 <0.24 <1.7 <0.26 <0.18 <0.35 <0.25 <0.25 <0.21 <0.35 <0.58 <0.42 <0.31 <0.26 <0.18 <0.33 <0.23 <0.24 <0.24 <1.5 <0.44 <0.66 <0.24 NA <0.23 <0.19 <0.23 <0.24
6/24/1998 NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR
7/6/1998 NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR
7/28/1998 NR NR NR NR NR NR NR NR NR NR NR NR 1.6 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
4/8/1999 NS NS NS NS NR NS NS NR NS NS NR NS NS NS NS NR NS NS NS NR NS NS NR NS NS NS NS
4/16/2001 ND ND ND ND NR NR NR NR ND ND NR ND ND ND ND NR ND NR NR NR NR NR NR ND NR NR ND
8/1/2001 ND ND ND ND NR NR NR NR ND ND NR ND ND ND ND NR ND NR NR NR NR NR NR 1.9 NR NR ND
1/21/2003 ND ND ND ND NR NR NR NR ND ND NR ND ND ND ND NR ND NR NR NR NR NR NR ND NR NR ND
7/8/2009 1.2 ND ND ND NR 1.0 ND NR ND ND NR ND 3.6 ND ND NR ND 2.2 NR NR 4.3 1.7 NR ND 5.9 1.3 1.7
2/22/2010 ND ND ND ND ND ND ND ND ND ND NR ND ND ND ND NR ND ND NR NR ND ND ND ND ND ND ND
9/19/2011
3/26/2012 ND ND ND ND NR NR ND ND ND ND NR ND 0.75 ND ND NR ND ND NR NR ND ND ND ND ND ND 0.18J
3/9/2013
4/3/2015 <0.25 ND ND ND <0.25 <0.25 <0.25 <0.25 ND ND <0.25 ND <0.25 ND <0.25 <0.25 <0.25 <0.25 NR <0.25 <1.0 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25
3/18/2016
5/1/2017
1/4/2018
7/18/2018 <0.62 <6.2 <6.2 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <1.2 <1.2 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <2.5 <0.62 <2.5 <0.62 <0.62 <0.62 <0.62 <0.62 <1.2
3/25/2019 <0.25 <2.5 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <1.0 <1.0 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <2.5 <0.25 <1.0 <0.25 <0.25 <0.25 <0.25 <0.25 <0.50
3/5/2020 <0.24 <1.7 <0.26 <0.18 <0.35 <0.25 <0.25 <0.21 <0.35 <0.58 <0.42 <0.31 <0.26 <0.18 <0.33 <0.23 <0.24 <0.24 <1.5 <0.44 <0.66 <0.24 NA <0.23 <0.19 <0.23 <0.24
7/6/1998 3800 NR NR NR NR NR NR NR NR NR NR NR 450 NR NR NR 300 NR NR NR 20 NR NR 2600 250 120 1890
7/28/1998 9700 NR NR NR NR NR NR NR NR NR NR NR 1200 NR NS NR 830 NR NR NR 160 NR NR 7200 650 NR 3300
4/8/1999
4/16/2001 9800 NR NR NR NR NR NR NR NR NR NR NR 630 NR 600 NR 1300 NR NR NR NR NR NR 7700 NR NR 7200
8/1/2001 12000 NR NR NR NR NR NR NR NR NR NR NR 1200 NR 360 NR 1300 NR NR NR NR NR NR 5400 NR NR 700
1/21/2003 4100 NR NR NR NR NR NR NR NR NR NR NR 630 NR ND NR 1100 NR NR NR NR NR NR 2100 NR NR 5300
7/8/2009 15000 NR NR NR NR ND ND ND ND ND NR NR 1510 NR 103 NR 1780 ND ND NR 330 125 NR 6110 1330 389 11930
2/22/2010 12000 ND ND ND ND ND ND ND ND ND NR NR ND NR 73 NR 1800 67 NR NR 330 140 NR 5500 1200 390 10200
9/19/2011
3/26/2012 9400 NR NR NR NR 7.0J NR NR NR NR NR NR 1400 NR NR NR 1900 75 NR NR 380 160 NR 3600 1500 470 10700
5/1/2012 6400 NR NR NR NR 15J NR NR NR NR NR NR 850 NR 55 NR 1200 74 NR NR 660 170 NR 2000 2200 730 14200
3/9/2013
4/3/2015 11300 <12.5 <12.6 <12.5 <12.5 <12.5 <12.5 <12.5 <12.5 <12.5 <12.5 <12.5 1270 <12.5 102 <12.5 1070 54 <12.5 <12.5 401 103 <12.5 3320 1340 425 9830
3/18/2016 13900 <0.5 <0.6 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 1270 <0.5 118 <0.5 900 27.6J <0.5 <0.5 317 58.2 <0.5 3750 933 296 8640
5/1/2017 12600 <25 <25 <25 44.2 <25 <25 <25 <25 <25 67.2 <25 1090 <25 86.1 <25 1230 72.4 <25 <25 442 <25 <25 2180 1570 495 9500
1/4/2018 13000 <80 <80 <80 89J <80 <80 260 <80 <80 <80 <80 1000 <80 <80 <80 1300 <80 <80 <80 520 190 <80 1600 2200 690 9400
2/13/2018
7/18/2018 194 359 <5.0 <5.0 21.4 <5.0 <5.0 <5.0 <5.0 334 1460 <5.0 748 7.1J 11.1 <5.0 125 23.5 <5.0 <5.0 297 56.6 <5.0 47.7 126 <0.5 765
3/25/2019 2240 50.0J <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <10.0 <10.0 <5.0 480 5.8J <5.0 <5.0 417 32.2 <5.0 <5.0 327 65.1 <5.0 1280 996 316 4340
9/17/2019 2010 121 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 86.7 <10.0 <5.0 798 5.9J 39.1 <5.0 194 22.6 <5.0 98 244 <5.0 <5.0 <5.0 524 173 1649
3/5/2020 2900 <34.4 <5.2 <3.7 <7.1 <4.9 <5.0 <4.1 <7.1 58.4 <8.3 <6.2 957 <3.7 64.6 <4.6 244 26.2 <30.0 26.2 307 55.9 NA 776 662 236 2012
8/1/2001 170 NR NR NR NR NR NR NR NR NR NR NR 41 NR 8.9 NR 8.5 NR NR NR NR NR NR 1.6 NR NR 3
1/21/2003 180 NR NR NR NR NR NR NR NR NR NR NR 42 NR 5.2 NR 2.5 NR NR NR NR NR NR ND NR NR 6.3
7/8/2009 1.4 NR NR NR NR 1.2 0.59 NR NR NR NR NR 11.6 NR 1.1 NR 0.87 1.6 NR NR 2 1.3 NR ND ND ND ND
2/22/2010 4 NR NR NR NR 1.9 0.5 NR NR NR NR NR ND NR ND NR 3.1 3.6 NR NR 12 3.3 NR 1.4 24 2.3 13.6
9/19/2011 1.3 NR NR NR NR ND ND ND ND ND NR ND ND ND ND NR 3.3 2.2 NR NR 3.3 2.6 NR ND 1.2 2.3 0.32J
3/26/2012
5/1/2012
3/9/2013 11.1 ND ND ND NR 3.2 ND ND ND ND ND ND ND ND ND ND 34.9 9.8 ND ND 28.7 16.6 ND 0.3J 83 12.7 18.62
4/3/2015 76.8 <0.25 <0.25 <0.25 1 1.3 0.62 <0.25 <0.25 <0.25 <0.25 <0.25 3 <0.25 <0.25 <0.25 1.8 2 <0.25 <0.25 19.8 2.6 <0.25 <0.25 2.3 <0.25 <0.25
3/18/2016 1.4 <0.5 <0.5 <0.5 1.2 1.1 0.53 <0.5 <0.5 <0.5 <0.5 <0.5 0.92 <0.5 <0.5 <0.5 0.84 1.5 <0.5 <0.5 15.2 1.5 <0.5 <0.5 1 <0.5 <1.5
5/1/2017 8 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 0.68 <0.25 <0.25 <0.25 0.32 0.52 <0.25 <0.25 5.4 0.58 <0.25 <0.25 0.72 <0.25 <0.25
1/4/2018 11 <0.40 <0.40 <0.40 1.9 1.3 0.91 <0.40 <0.40 <0.40 <0.40 <0.40 0.49J <0.40 <0.40 <0.40 2.7 2.4 <0.40 <0.40 19 2.1 2.8 <0.40 12 2.1 3.09
7/18/2018 <2.5 98 16.1 3.0J <2.5 <2.5 <2.5 <2.5 13.2 41.9 1150 3.2J 12.8 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <10 <2.5 <2.5 <2.5 <2.5 <2.5 <5.0
3/25/2019 <0.25 <2.5 <0.25 0.29J <0.25 <0.25 <0.25 <0.25 5.8 <0.50 8.7 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.50 <0.25 <1.0 <0.25 <0.25 <0.25 <0.25 <0.25 <0.50
9/17/2019 <0.62 50 7.1 <0.62 <0.62 <0.62 <0.62 <0.62 6.6J 9.5 326 1.3 4.4 <0.62 <0.62 <0.62 <0.62 <0.62 8.6 <0.62 <2.5 <0.62 <0.62 <0.62 <0.62 <0.62 <1.2
3/5/2020 <0.24 <1.7 <0.26 2.6 <0.35 <0.25 <0.25 <0.21 27.2 <0.58 <0.42 <0.31 <0.26 <0.18 <0.33 <0.23 <0.24 <0.24 <1.5 <0.44 <0.66 <0.24 NA <0.23 <0.19 <0.23 <0.24
2/14/2000 ND NR NR NR NR NR NR NR NR NR NR NR NR NR ND ND ND NR NR ND NR NR NR ND NR NR ND
5/2/2001 ND NR NR NR NR NR NR NR NR NR NR NR NR NR ND ND ND NR NR ND NR NR NR ND NR NR ND
3/26/2002 ND NR NR NR NR NR NR NR NR NR NR NR NR NR ND NA ND NR NR ND NR NR NR ND NR NR ND
9/5/2003 ND NR NR NR NR NR NR NR NR NR NR NR NR NR ND NA ND NR NR ND NR NR NR ND NR NR ND
7/8/2009 ND NR NR NR NR NR NR NR NR NR NR NR NR NR ND ND ND NR NR ND NR NR NR ND NR NR ND
2/22/2010 ND NR NR NR NR NR NR NR NR NR NR NR NR NR ND ND ND NR NR ND NR NR NR ND NR NR ND
9/19/2011 ND NR NR NR NR NR NR NR NR NR NR NR NR NR ND ND ND NR NR ND NR NR NR ND NR NR ND
3/9/2013 ND NR NR NR NR ND ND NR NR NR NR NR ND NR ND ND ND ND ND ND ND ND NR ND ND ND ND
2/14/2000 ND NR NR NR NR NR NR NR NR NR NR NR NR NR ND ND ND NR NR ND NR NR NR ND NR NR ND
5/2/2001 ND NR NR NR NR NR NR NR NR NR NR NR NR NR ND ND ND NR NR ND NR NR NR ND NR NR ND
3/26/2002 ND NR NR NR NR NR NR NR NR NR NR NR NR NR ND NA ND NR NR ND NR NR NR ND NR NR ND
11/11/2002 ND NR NR NR NR NR NR NR NR NR NR NR NR NR ND NA ND NR NR ND NR NR NR ND NR NR ND
9/5/2003 ND NR NR NR NR NR NR NR NR NR NR NR NR NR ND NA ND NR NR ND NR NR NR ND NR NR ND
7/8/2009 ND NR NR NR NR NR NR NR NR NR NR NR NR NR ND ND ND NR NR ND NR NR NR ND NR NR ND
2/22/2010 ND NR NR NR NR NR NR NR NR NR NR NR NR NR ND ND ND NR NR ND NR NR NR ND NR NR ND
9/19/2011 ND NR NR NR NR NR NR NR NR NR NR NR NR NR ND ND ND NR NR ND NR NR NR ND NR NR ND
3/9/2013 ND NR NR NR NR ND NR NR NR NR NR NR ND NR ND ND ND NR NR ND ND ND NR ND ND ND ND
4/3/2015 <0.25 <0.25 <0.26 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <1.0 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25
2/14/2000 NR NR NR NR NR NR NR NR NR NR NR NR NR NR ND ND ND NR NR 9.9 NR NR NR ND NR NR ND
5/2/2001 NR NR NR NR NR NR NR NR NR NR NR NR NR NR ND ND ND NR NR ND NR NR NR ND NR NR ND
9/5/2003 NR NR NR NR NR NR NR NR NR NR NR NR NR NR ND NA ND NR NR ND NR NR NR ND NR NR ND
7/8/2009 NR NR NR NR NR NR NR NR NR NR NR NR NR NR ND ND ND NR NR 27.3 NR NR NR ND NR NR ND
2/22/2010 NR NR NR NR NR NR NR NR NR NR NR NR NR NR ND ND ND NR NR 45 NR NR NR ND NR NR ND
9/19/2011
3/9/2013
4/3/2015 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 55.1 <1.0 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25
Notes:ND denotes not detected (Detection limits are unknown for sampling conducted prior to Terracon's involvement with the site.)NS denotes not sampled or no standard.<- denotes less than method detection limitNA denotes not analyzed.NR denotes standard not reported.
Bold denotes levels above the 2L standard. Bold and Yellow shading denotes levels above GCLs
Not Sampled
Not Sampled
Injection of Sodium Persulfate, Hydrogen Peroxide, and Zero Valent Ironsec-ButylbenzeneDibromomethaneWSW-12
Not Sampled
Not Sampled EthylbenzeneDiisopropyletherGCL (ug/L)
WSW-2 n-ButylbenzeneNot Sampled
Not Sampled
Not Sampled
Not Sampled
Not Sampled
WSW-1 BromochloromethaneChloroformAnalytical Method
2L Standard (ug/L)
6200B
Toluene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneTotalXylenesMTBENaphthalenen-Propylbenzene1,2-DichloroethaneEDBIsopropylbenzeneMethyleneChlorideMW-11
MW-1
MW-4
MW-5 ChloromethaneNot SampledBenzene
Not Sampled
Not SampledBromomethaneChloroethane1,2-DichloropropaneBromodichloromethanep-Isopropyltoluene2-chlorotoluenetert-Butylbenzene1 of 1
APPENDIX A
LABORATORY ANALYTICAL REPORT
#=CL#
March 12, 2020
LIMS USE: FR - VICTORIA LARSON
LIMS OBJECT ID: 92468516
92468516
Project:
Pace Project No.:
RE:
Victoria Larson
2020 Starita Rd
Suite E
Charlotte, NC 28206
Brack Griffin
Dear Victoria Larson:
Enclosed are the analytical results for sample(s) received by the laboratory on March 06, 2020. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor Ezell
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 27
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92468516
Brack Griffin
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 27
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92468516
Brack Griffin
Lab ID Sample ID Matrix Date Collected Date Received
92468516001 MW-1 Water 03/05/20 13:25 03/06/20 17:37
92468516002 MW-4 Water 03/05/20 13:05 03/06/20 17:37
92468516003 MW-5 Water 03/05/20 11:50 03/06/20 17:37
92468516004 MW-11 Water 03/05/20 12:10 03/06/20 17:37
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 27
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92468516
Brack Griffin
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92468516001 MW-1 SM 6200B 63 PASI-CDLK
92468516002 MW-4 SM 6200B 63 PASI-CDLK
92468516003 MW-5 SM 6200B 63 PASI-CDLK
92468516004 MW-11 SM 6200B 63 PASI-CDLK
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 27
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92468516
Brack Griffin
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92468516003 MW-5
Benzene 2900 ug/L 03/11/20 02:2210.0SM 6200B
Chloroethane 58.4 ug/L 03/11/20 02:2220.0SM 6200B
1,2-Dichloroethane 957 ug/L 03/11/20 02:2210.0SM 6200B
Diisopropyl ether 64.6 ug/L 03/11/20 02:2210.0SM 6200B
Ethylbenzene 244 ug/L 03/11/20 02:2210.0SM 6200B
Isopropylbenzene (Cumene)26.2 ug/L 03/11/20 02:2210.0SM 6200B
Methyl-tert-butyl ether 26.2 ug/L 03/11/20 02:2210.0SM 6200B
Naphthalene 307 ug/L 03/11/20 02:2240.0SM 6200B
n-Propylbenzene 55.9 ug/L 03/11/20 02:2210.0SM 6200B
Toluene 776 ug/L 03/11/20 02:2210.0SM 6200B
1,2,4-Trimethylbenzene 662 ug/L 03/11/20 02:2210.0SM 6200B
1,3,5-Trimethylbenzene 236 ug/L 03/11/20 02:2210.0SM 6200B
m&p-Xylene 1390 ug/L 03/11/20 02:2220.0SM 6200B
o-Xylene 622 ug/L 03/11/20 02:2210.0SM 6200B
92468516004 MW-11
Bromodichloromethane 2.6 ug/L 03/11/20 18:110.50SM 6200B
Chloroform 27.2 ug/L 03/11/20 18:110.50SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 27
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92468516
Brack Griffin
Method:
Client:Terracon - Charlotte, NC
SM 6200B
Date:March 12, 2020
Description:6200B MSV
General Information:
4 samples were analyzed for SM 6200B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92468516
Brack Griffin
Sample:MW-1 Lab ID:92468516001 Collected:03/05/20 13:25 Received:03/06/20 17:37 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 03/10/20 22:04 71-43-20.50 0.24 1
Bromobenzene ND ug/L 03/10/20 22:04 108-86-10.50 0.22 1
Bromochloromethane ND ug/L 03/10/20 22:04 74-97-50.50 0.26 1
Bromodichloromethane ND ug/L 03/10/20 22:04 75-27-40.50 0.18 1
Bromoform ND ug/L 03/10/20 22:04 75-25-20.50 0.40 1
Bromomethane ND ug/L 03/10/20 22:04 74-83-95.0 1.7 1
n-Butylbenzene ND ug/L 03/10/20 22:04 104-51-80.50 0.35 1
sec-Butylbenzene ND ug/L 03/10/20 22:04 135-98-80.50 0.25 1
tert-Butylbenzene ND ug/L 03/10/20 22:04 98-06-60.50 0.25 1
Carbon tetrachloride ND ug/L 03/10/20 22:04 56-23-50.50 0.23 1
Chlorobenzene ND ug/L 03/10/20 22:04 108-90-70.50 0.22 1
Chloroethane ND ug/L 03/10/20 22:04 75-00-31.0 0.58 1
Chloroform ND ug/L 03/10/20 22:04 67-66-30.50 0.35 1
Chloromethane ND ug/L 03/10/20 22:04 74-87-31.0 0.42 1
2-Chlorotoluene ND ug/L 03/10/20 22:04 95-49-80.50 0.21 1
4-Chlorotoluene ND ug/L 03/10/20 22:04 106-43-40.50 0.21 1
1,2-Dibromo-3-chloropropane ND ug/L 03/10/20 22:04 96-12-81.0 0.38 1
Dibromochloromethane ND ug/L 03/10/20 22:04 124-48-10.50 0.40 1
1,2-Dibromoethane (EDB)ND ug/L 03/10/20 22:04 106-93-40.50 0.23 1
Dibromomethane ND ug/L 03/10/20 22:04 74-95-30.50 0.31 1
1,2-Dichlorobenzene ND ug/L 03/10/20 22:04 95-50-10.50 0.24 1
1,3-Dichlorobenzene ND ug/L 03/10/20 22:04 541-73-10.50 0.25 1
1,4-Dichlorobenzene ND ug/L 03/10/20 22:04 106-46-70.50 0.25 1
Dichlorodifluoromethane ND ug/L 03/10/20 22:04 75-71-80.50 0.28 1
1,1-Dichloroethane ND ug/L 03/10/20 22:04 75-34-30.50 0.24 1
1,2-Dichloroethane ND ug/L 03/10/20 22:04 107-06-20.50 0.26 1
1,1-Dichloroethene ND ug/L 03/10/20 22:04 75-35-40.50 0.22 1
cis-1,2-Dichloroethene ND ug/L 03/10/20 22:04 156-59-20.50 0.21 1
trans-1,2-Dichloroethene ND ug/L 03/10/20 22:04 156-60-50.50 0.26 1
1,2-Dichloropropane ND ug/L 03/10/20 22:04 78-87-50.50 0.18 1
1,3-Dichloropropane ND ug/L 03/10/20 22:04 142-28-90.50 0.34 1
2,2-Dichloropropane ND ug/L 03/10/20 22:04 594-20-70.50 0.28 1
1,1-Dichloropropene ND ug/L 03/10/20 22:04 563-58-60.50 0.35 1
cis-1,3-Dichloropropene ND ug/L 03/10/20 22:04 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 03/10/20 22:04 10061-02-60.50 0.39 1
Diisopropyl ether ND ug/L 03/10/20 22:04 108-20-30.50 0.33 1
Ethylbenzene ND ug/L 03/10/20 22:04 100-41-40.50 0.24 1
Hexachloro-1,3-butadiene ND ug/L 03/10/20 22:04 87-68-32.0 1.2 1
Isopropylbenzene (Cumene)ND ug/L 03/10/20 22:04 98-82-80.50 0.24 1
Methylene Chloride ND ug/L 03/10/20 22:04 75-09-22.0 1.5 1
Methyl-tert-butyl ether ND ug/L 03/10/20 22:04 1634-04-40.50 0.44 1
Naphthalene ND ug/L 03/10/20 22:04 91-20-32.0 0.66 1
n-Propylbenzene ND ug/L 03/10/20 22:04 103-65-10.50 0.24 1
Styrene ND ug/L 03/10/20 22:04 100-42-50.50 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/10/20 22:04 630-20-60.50 0.42 1
1,1,2,2-Tetrachloroethane ND ug/L 03/10/20 22:04 79-34-50.50 0.19 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/12/2020 02:37 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92468516
Brack Griffin
Sample:MW-1 Lab ID:92468516001 Collected:03/05/20 13:25 Received:03/06/20 17:37 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Tetrachloroethene ND ug/L 03/10/20 22:04 127-18-40.50 0.23 1
Toluene ND ug/L 03/10/20 22:04 108-88-30.50 0.23 1
1,2,3-Trichlorobenzene ND ug/L 03/10/20 22:04 87-61-62.0 0.78 1
1,2,4-Trichlorobenzene ND ug/L 03/10/20 22:04 120-82-12.0 0.44 1
1,1,1-Trichloroethane ND ug/L 03/10/20 22:04 71-55-60.50 0.28 1
1,1,2-Trichloroethane ND ug/L 03/10/20 22:04 79-00-50.50 0.23 1
Trichloroethene ND ug/L 03/10/20 22:04 79-01-60.50 0.23 1
Trichlorofluoromethane ND ug/L 03/10/20 22:04 75-69-41.0 0.34 1
1,2,3-Trichloropropane ND ug/L 03/10/20 22:04 96-18-40.50 0.27 1
1,2,4-Trimethylbenzene ND ug/L 03/10/20 22:04 95-63-60.50 0.19 1
1,3,5-Trimethylbenzene ND ug/L 03/10/20 22:04 108-67-80.50 0.23 1
Vinyl chloride ND ug/L 03/10/20 22:04 75-01-41.0 0.41 1
m&p-Xylene ND ug/L 03/10/20 22:04 179601-23-11.0 0.44 1
o-Xylene ND ug/L 03/10/20 22:04 95-47-60.50 0.24 1
Surrogates
1,2-Dichloroethane-d4 (S)100 %03/10/20 22:04 17060-07-070-130 1
4-Bromofluorobenzene (S)97 %03/10/20 22:04 460-00-470-130 1
Toluene-d8 (S)104 %03/10/20 22:04 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/12/2020 02:37 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92468516
Brack Griffin
Sample:MW-4 Lab ID:92468516002 Collected:03/05/20 13:05 Received:03/06/20 17:37 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 03/10/20 22:23 71-43-20.50 0.24 1
Bromobenzene ND ug/L 03/10/20 22:23 108-86-10.50 0.22 1
Bromochloromethane ND ug/L 03/10/20 22:23 74-97-50.50 0.26 1
Bromodichloromethane ND ug/L 03/10/20 22:23 75-27-40.50 0.18 1
Bromoform ND ug/L 03/10/20 22:23 75-25-20.50 0.40 1
Bromomethane ND ug/L 03/10/20 22:23 74-83-95.0 1.7 1
n-Butylbenzene ND ug/L 03/10/20 22:23 104-51-80.50 0.35 1
sec-Butylbenzene ND ug/L 03/10/20 22:23 135-98-80.50 0.25 1
tert-Butylbenzene ND ug/L 03/10/20 22:23 98-06-60.50 0.25 1
Carbon tetrachloride ND ug/L 03/10/20 22:23 56-23-50.50 0.23 1
Chlorobenzene ND ug/L 03/10/20 22:23 108-90-70.50 0.22 1
Chloroethane ND ug/L 03/10/20 22:23 75-00-31.0 0.58 1
Chloroform ND ug/L 03/10/20 22:23 67-66-30.50 0.35 1
Chloromethane ND ug/L 03/10/20 22:23 74-87-31.0 0.42 1
2-Chlorotoluene ND ug/L 03/10/20 22:23 95-49-80.50 0.21 1
4-Chlorotoluene ND ug/L 03/10/20 22:23 106-43-40.50 0.21 1
1,2-Dibromo-3-chloropropane ND ug/L 03/10/20 22:23 96-12-81.0 0.38 1
Dibromochloromethane ND ug/L 03/10/20 22:23 124-48-10.50 0.40 1
1,2-Dibromoethane (EDB)ND ug/L 03/10/20 22:23 106-93-40.50 0.23 1
Dibromomethane ND ug/L 03/10/20 22:23 74-95-30.50 0.31 1
1,2-Dichlorobenzene ND ug/L 03/10/20 22:23 95-50-10.50 0.24 1
1,3-Dichlorobenzene ND ug/L 03/10/20 22:23 541-73-10.50 0.25 1
1,4-Dichlorobenzene ND ug/L 03/10/20 22:23 106-46-70.50 0.25 1
Dichlorodifluoromethane ND ug/L 03/10/20 22:23 75-71-80.50 0.28 1
1,1-Dichloroethane ND ug/L 03/10/20 22:23 75-34-30.50 0.24 1
1,2-Dichloroethane ND ug/L 03/10/20 22:23 107-06-20.50 0.26 1
1,1-Dichloroethene ND ug/L 03/10/20 22:23 75-35-40.50 0.22 1
cis-1,2-Dichloroethene ND ug/L 03/10/20 22:23 156-59-20.50 0.21 1
trans-1,2-Dichloroethene ND ug/L 03/10/20 22:23 156-60-50.50 0.26 1
1,2-Dichloropropane ND ug/L 03/10/20 22:23 78-87-50.50 0.18 1
1,3-Dichloropropane ND ug/L 03/10/20 22:23 142-28-90.50 0.34 1
2,2-Dichloropropane ND ug/L 03/10/20 22:23 594-20-70.50 0.28 1
1,1-Dichloropropene ND ug/L 03/10/20 22:23 563-58-60.50 0.35 1
cis-1,3-Dichloropropene ND ug/L 03/10/20 22:23 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 03/10/20 22:23 10061-02-60.50 0.39 1
Diisopropyl ether ND ug/L 03/10/20 22:23 108-20-30.50 0.33 1
Ethylbenzene ND ug/L 03/10/20 22:23 100-41-40.50 0.24 1
Hexachloro-1,3-butadiene ND ug/L 03/10/20 22:23 87-68-32.0 1.2 1
Isopropylbenzene (Cumene)ND ug/L 03/10/20 22:23 98-82-80.50 0.24 1
Methylene Chloride ND ug/L 03/10/20 22:23 75-09-22.0 1.5 1
Methyl-tert-butyl ether ND ug/L 03/10/20 22:23 1634-04-40.50 0.44 1
Naphthalene ND ug/L 03/10/20 22:23 91-20-32.0 0.66 1
n-Propylbenzene ND ug/L 03/10/20 22:23 103-65-10.50 0.24 1
Styrene ND ug/L 03/10/20 22:23 100-42-50.50 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/10/20 22:23 630-20-60.50 0.42 1
1,1,2,2-Tetrachloroethane ND ug/L 03/10/20 22:23 79-34-50.50 0.19 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/12/2020 02:37 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92468516
Brack Griffin
Sample:MW-4 Lab ID:92468516002 Collected:03/05/20 13:05 Received:03/06/20 17:37 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Tetrachloroethene ND ug/L 03/10/20 22:23 127-18-40.50 0.23 1
Toluene ND ug/L 03/10/20 22:23 108-88-30.50 0.23 1
1,2,3-Trichlorobenzene ND ug/L 03/10/20 22:23 87-61-62.0 0.78 1
1,2,4-Trichlorobenzene ND ug/L 03/10/20 22:23 120-82-12.0 0.44 1
1,1,1-Trichloroethane ND ug/L 03/10/20 22:23 71-55-60.50 0.28 1
1,1,2-Trichloroethane ND ug/L 03/10/20 22:23 79-00-50.50 0.23 1
Trichloroethene ND ug/L 03/10/20 22:23 79-01-60.50 0.23 1
Trichlorofluoromethane ND ug/L 03/10/20 22:23 75-69-41.0 0.34 1
1,2,3-Trichloropropane ND ug/L 03/10/20 22:23 96-18-40.50 0.27 1
1,2,4-Trimethylbenzene ND ug/L 03/10/20 22:23 95-63-60.50 0.19 1
1,3,5-Trimethylbenzene ND ug/L 03/10/20 22:23 108-67-80.50 0.23 1
Vinyl chloride ND ug/L 03/10/20 22:23 75-01-41.0 0.41 1
m&p-Xylene ND ug/L 03/10/20 22:23 179601-23-11.0 0.44 1
o-Xylene ND ug/L 03/10/20 22:23 95-47-60.50 0.24 1
Surrogates
1,2-Dichloroethane-d4 (S)102 %03/10/20 22:23 17060-07-070-130 1
4-Bromofluorobenzene (S)99 %03/10/20 22:23 460-00-470-130 1
Toluene-d8 (S)100 %03/10/20 22:23 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/12/2020 02:37 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92468516
Brack Griffin
Sample:MW-5 Lab ID:92468516003 Collected:03/05/20 11:50 Received:03/06/20 17:37 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Benzene 2900 ug/L 03/11/20 02:22 71-43-210.0 4.8 20
Bromobenzene ND ug/L 03/11/20 02:22 108-86-110.0 4.3 20
Bromochloromethane ND ug/L 03/11/20 02:22 74-97-510.0 5.2 20
Bromodichloromethane ND ug/L 03/11/20 02:22 75-27-410.0 3.7 20
Bromoform ND ug/L 03/11/20 02:22 75-25-210.0 8.1 20
Bromomethane ND ug/L 03/11/20 02:22 74-83-910034.4 20
n-Butylbenzene ND ug/L 03/11/20 02:22 104-51-810.0 7.1 20
sec-Butylbenzene ND ug/L 03/11/20 02:22 135-98-810.0 4.9 20
tert-Butylbenzene ND ug/L 03/11/20 02:22 98-06-610.0 5.0 20
Carbon tetrachloride ND ug/L 03/11/20 02:22 56-23-510.0 4.6 20
Chlorobenzene ND ug/L 03/11/20 02:22 108-90-710.0 4.5 20
Chloroethane 58.4 ug/L 03/11/20 02:22 75-00-320.0 11.7 20
Chloroform ND ug/L 03/11/20 02:22 67-66-310.0 7.1 20
Chloromethane ND ug/L 03/11/20 02:22 74-87-320.0 8.3 20
2-Chlorotoluene ND ug/L 03/11/20 02:22 95-49-810.0 4.1 20
4-Chlorotoluene ND ug/L 03/11/20 02:22 106-43-410.0 4.1 20
1,2-Dibromo-3-chloropropane ND ug/L 03/11/20 02:22 96-12-820.0 7.7 20
Dibromochloromethane ND ug/L 03/11/20 02:22 124-48-110.0 8.0 20
1,2-Dibromoethane (EDB)ND ug/L 03/11/20 02:22 106-93-410.0 4.6 20
Dibromomethane ND ug/L 03/11/20 02:22 74-95-310.0 6.2 20
1,2-Dichlorobenzene ND ug/L 03/11/20 02:22 95-50-110.0 4.8 20
1,3-Dichlorobenzene ND ug/L 03/11/20 02:22 541-73-110.0 5.0 20
1,4-Dichlorobenzene ND ug/L 03/11/20 02:22 106-46-710.0 5.0 20
Dichlorodifluoromethane ND ug/L 03/11/20 02:22 75-71-810.0 5.7 20
1,1-Dichloroethane ND ug/L 03/11/20 02:22 75-34-310.0 4.9 20
1,2-Dichloroethane 957 ug/L 03/11/20 02:22 107-06-210.0 5.3 20
1,1-Dichloroethene ND ug/L 03/11/20 02:22 75-35-410.0 4.4 20
cis-1,2-Dichloroethene ND ug/L 03/11/20 02:22 156-59-210.0 4.1 20
trans-1,2-Dichloroethene ND ug/L 03/11/20 02:22 156-60-510.0 5.1 20
1,2-Dichloropropane ND ug/L 03/11/20 02:22 78-87-510.0 3.7 20
1,3-Dichloropropane ND ug/L 03/11/20 02:22 142-28-910.0 6.8 20
2,2-Dichloropropane ND ug/L 03/11/20 02:22 594-20-710.0 5.6 20
1,1-Dichloropropene ND ug/L 03/11/20 02:22 563-58-610.0 7.0 20
cis-1,3-Dichloropropene ND ug/L 03/11/20 02:22 10061-01-510.0 7.1 20
trans-1,3-Dichloropropene ND ug/L 03/11/20 02:22 10061-02-610.0 7.9 20
Diisopropyl ether 64.6 ug/L 03/11/20 02:22 108-20-310.0 6.7 20
Ethylbenzene 244 ug/L 03/11/20 02:22 100-41-410.0 4.8 20
Hexachloro-1,3-butadiene ND ug/L 03/11/20 02:22 87-68-340.0 24.0 20
Isopropylbenzene (Cumene)26.2 ug/L 03/11/20 02:22 98-82-810.0 4.8 20
Methylene Chloride ND ug/L 03/11/20 02:22 75-09-240.0 30.0 20
Methyl-tert-butyl ether 26.2 ug/L 03/11/20 02:22 1634-04-410.0 8.9 20
Naphthalene 307 ug/L 03/11/20 02:22 91-20-340.0 13.2 20
n-Propylbenzene 55.9 ug/L 03/11/20 02:22 103-65-110.0 4.8 20
Styrene ND ug/L 03/11/20 02:22 100-42-510.0 5.1 20
1,1,1,2-Tetrachloroethane ND ug/L 03/11/20 02:22 630-20-610.0 8.4 20
1,1,2,2-Tetrachloroethane ND ug/L 03/11/20 02:22 79-34-510.0 3.9 20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/12/2020 02:37 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92468516
Brack Griffin
Sample:MW-5 Lab ID:92468516003 Collected:03/05/20 11:50 Received:03/06/20 17:37 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Tetrachloroethene ND ug/L 03/11/20 02:22 127-18-410.0 4.6 20
Toluene 776 ug/L 03/11/20 02:22 108-88-310.0 4.6 20
1,2,3-Trichlorobenzene ND ug/L 03/11/20 02:22 87-61-640.0 15.6 20
1,2,4-Trichlorobenzene ND ug/L 03/11/20 02:22 120-82-140.0 8.7 20
1,1,1-Trichloroethane ND ug/L 03/11/20 02:22 71-55-610.0 5.6 20
1,1,2-Trichloroethane ND ug/L 03/11/20 02:22 79-00-510.0 4.6 20
Trichloroethene ND ug/L 03/11/20 02:22 79-01-610.0 4.6 20
Trichlorofluoromethane ND ug/L 03/11/20 02:22 75-69-420.0 6.7 20
1,2,3-Trichloropropane ND ug/L 03/11/20 02:22 96-18-410.0 5.4 20
1,2,4-Trimethylbenzene 662 ug/L 03/11/20 02:22 95-63-610.0 3.9 20
1,3,5-Trimethylbenzene 236 ug/L 03/11/20 02:22 108-67-810.0 4.5 20
Vinyl chloride ND ug/L 03/11/20 02:22 75-01-420.0 8.1 20
m&p-Xylene 1390 ug/L 03/11/20 02:22 179601-23-120.0 8.8 20
o-Xylene 622 ug/L 03/11/20 02:22 95-47-610.0 4.7 20
Surrogates
1,2-Dichloroethane-d4 (S)107 %03/11/20 02:22 17060-07-070-130 20
4-Bromofluorobenzene (S)99 %03/11/20 02:22 460-00-470-130 20
Toluene-d8 (S)100 %03/11/20 02:22 2037-26-570-130 20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/12/2020 02:37 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92468516
Brack Griffin
Sample:MW-11 Lab ID:92468516004 Collected:03/05/20 12:10 Received:03/06/20 17:37 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 03/11/20 18:11 71-43-20.50 0.24 1
Bromobenzene ND ug/L 03/11/20 18:11 108-86-10.50 0.22 1
Bromochloromethane ND ug/L 03/11/20 18:11 74-97-50.50 0.26 1
Bromodichloromethane 2.6 ug/L 03/11/20 18:11 75-27-40.50 0.18 1
Bromoform ND ug/L 03/11/20 18:11 75-25-20.50 0.40 1
Bromomethane ND ug/L 03/11/20 18:11 74-83-95.0 1.7 1
n-Butylbenzene ND ug/L 03/11/20 18:11 104-51-80.50 0.35 1
sec-Butylbenzene ND ug/L 03/11/20 18:11 135-98-80.50 0.25 1
tert-Butylbenzene ND ug/L 03/11/20 18:11 98-06-60.50 0.25 1
Carbon tetrachloride ND ug/L 03/11/20 18:11 56-23-50.50 0.23 1
Chlorobenzene ND ug/L 03/11/20 18:11 108-90-70.50 0.22 1
Chloroethane ND ug/L 03/11/20 18:11 75-00-31.0 0.58 1
Chloroform 27.2 ug/L 03/11/20 18:11 67-66-30.50 0.35 1
Chloromethane ND ug/L 03/11/20 18:11 74-87-31.0 0.42 1
2-Chlorotoluene ND ug/L 03/11/20 18:11 95-49-80.50 0.21 1
4-Chlorotoluene ND ug/L 03/11/20 18:11 106-43-40.50 0.21 1
1,2-Dibromo-3-chloropropane ND ug/L 03/11/20 18:11 96-12-81.0 0.38 1
Dibromochloromethane ND ug/L 03/11/20 18:11 124-48-10.50 0.40 1
1,2-Dibromoethane (EDB)ND ug/L 03/11/20 18:11 106-93-40.50 0.23 1
Dibromomethane ND ug/L 03/11/20 18:11 74-95-30.50 0.31 1
1,2-Dichlorobenzene ND ug/L 03/11/20 18:11 95-50-10.50 0.24 1
1,3-Dichlorobenzene ND ug/L 03/11/20 18:11 541-73-10.50 0.25 1
1,4-Dichlorobenzene ND ug/L 03/11/20 18:11 106-46-70.50 0.25 1
Dichlorodifluoromethane ND ug/L 03/11/20 18:11 75-71-80.50 0.28 1
1,1-Dichloroethane ND ug/L 03/11/20 18:11 75-34-30.50 0.24 1
1,2-Dichloroethane ND ug/L 03/11/20 18:11 107-06-20.50 0.26 1
1,1-Dichloroethene ND ug/L 03/11/20 18:11 75-35-40.50 0.22 1
cis-1,2-Dichloroethene ND ug/L 03/11/20 18:11 156-59-20.50 0.21 1
trans-1,2-Dichloroethene ND ug/L 03/11/20 18:11 156-60-50.50 0.26 1
1,2-Dichloropropane ND ug/L 03/11/20 18:11 78-87-50.50 0.18 1
1,3-Dichloropropane ND ug/L 03/11/20 18:11 142-28-90.50 0.34 1
2,2-Dichloropropane ND ug/L 03/11/20 18:11 594-20-70.50 0.28 1
1,1-Dichloropropene ND ug/L 03/11/20 18:11 563-58-60.50 0.35 1
cis-1,3-Dichloropropene ND ug/L 03/11/20 18:11 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 03/11/20 18:11 10061-02-60.50 0.39 1
Diisopropyl ether ND ug/L 03/11/20 18:11 108-20-30.50 0.33 1
Ethylbenzene ND ug/L 03/11/20 18:11 100-41-40.50 0.24 1
Hexachloro-1,3-butadiene ND ug/L 03/11/20 18:11 87-68-32.0 1.2 1
Isopropylbenzene (Cumene)ND ug/L 03/11/20 18:11 98-82-80.50 0.24 1
Methylene Chloride ND ug/L 03/11/20 18:11 75-09-22.0 1.5 1
Methyl-tert-butyl ether ND ug/L 03/11/20 18:11 1634-04-40.50 0.44 1
Naphthalene ND ug/L 03/11/20 18:11 91-20-32.0 0.66 1
n-Propylbenzene ND ug/L 03/11/20 18:11 103-65-10.50 0.24 1
Styrene ND ug/L 03/11/20 18:11 100-42-50.50 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/11/20 18:11 630-20-60.50 0.42 1
1,1,2,2-Tetrachloroethane ND ug/L 03/11/20 18:11 79-34-50.50 0.19 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/12/2020 02:37 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92468516
Brack Griffin
Sample:MW-11 Lab ID:92468516004 Collected:03/05/20 12:10 Received:03/06/20 17:37 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Tetrachloroethene ND ug/L 03/11/20 18:11 127-18-40.50 0.23 1
Toluene ND ug/L 03/11/20 18:11 108-88-30.50 0.23 1
1,2,3-Trichlorobenzene ND ug/L 03/11/20 18:11 87-61-62.0 0.78 1
1,2,4-Trichlorobenzene ND ug/L 03/11/20 18:11 120-82-12.0 0.44 1
1,1,1-Trichloroethane ND ug/L 03/11/20 18:11 71-55-60.50 0.28 1
1,1,2-Trichloroethane ND ug/L 03/11/20 18:11 79-00-50.50 0.23 1
Trichloroethene ND ug/L 03/11/20 18:11 79-01-60.50 0.23 1
Trichlorofluoromethane ND ug/L 03/11/20 18:11 75-69-41.0 0.34 1
1,2,3-Trichloropropane ND ug/L 03/11/20 18:11 96-18-40.50 0.27 1
1,2,4-Trimethylbenzene ND ug/L 03/11/20 18:11 95-63-60.50 0.19 1
1,3,5-Trimethylbenzene ND ug/L 03/11/20 18:11 108-67-80.50 0.23 1
Vinyl chloride ND ug/L 03/11/20 18:11 75-01-41.0 0.41 1
m&p-Xylene ND ug/L 03/11/20 18:11 179601-23-11.0 0.44 1
o-Xylene ND ug/L 03/11/20 18:11 95-47-60.50 0.24 1
Surrogates
1,2-Dichloroethane-d4 (S)105 %03/11/20 18:11 17060-07-070-130 1
4-Bromofluorobenzene (S)101 %03/11/20 18:11 460-00-470-130 1
Toluene-d8 (S)98 %03/11/20 18:11 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/12/2020 02:37 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92468516
Brack Griffin
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
529537
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92468516001, 92468516002, 92468516003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2828222
Associated Lab Samples:92468516001, 92468516002, 92468516003
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 0.50 03/10/20 21:460.42
1,1,1-Trichloroethane ug/L ND 0.50 03/10/20 21:460.28
1,1,2,2-Tetrachloroethane ug/L ND 0.50 03/10/20 21:460.19
1,1,2-Trichloroethane ug/L ND 0.50 03/10/20 21:460.23
1,1-Dichloroethane ug/L ND 0.50 03/10/20 21:460.24
1,1-Dichloroethene ug/L ND 0.50 03/10/20 21:460.22
1,1-Dichloropropene ug/L ND 0.50 03/10/20 21:460.35
1,2,3-Trichlorobenzene ug/L ND 2.0 03/10/20 21:460.78
1,2,3-Trichloropropane ug/L ND 0.50 03/10/20 21:460.27
1,2,4-Trichlorobenzene ug/L ND 2.0 03/10/20 21:460.44
1,2,4-Trimethylbenzene ug/L ND 0.50 03/10/20 21:460.19
1,2-Dibromo-3-chloropropane ug/L ND 1.0 03/10/20 21:460.38
1,2-Dibromoethane (EDB)ug/L ND 0.50 03/10/20 21:460.23
1,2-Dichlorobenzene ug/L ND 0.50 03/10/20 21:460.24
1,2-Dichloroethane ug/L ND 0.50 03/10/20 21:460.26
1,2-Dichloropropane ug/L ND 0.50 03/10/20 21:460.18
1,3,5-Trimethylbenzene ug/L ND 0.50 03/10/20 21:460.23
1,3-Dichlorobenzene ug/L ND 0.50 03/10/20 21:460.25
1,3-Dichloropropane ug/L ND 0.50 03/10/20 21:460.34
1,4-Dichlorobenzene ug/L ND 0.50 03/10/20 21:460.25
2,2-Dichloropropane ug/L ND 0.50 03/10/20 21:460.28
2-Chlorotoluene ug/L ND 0.50 03/10/20 21:460.21
4-Chlorotoluene ug/L ND 0.50 03/10/20 21:460.21
Benzene ug/L ND 0.50 03/10/20 21:460.24
Bromobenzene ug/L ND 0.50 03/10/20 21:460.22
Bromochloromethane ug/L ND 0.50 03/10/20 21:460.26
Bromodichloromethane ug/L ND 0.50 03/10/20 21:460.18
Bromoform ug/L ND 0.50 03/10/20 21:460.40
Bromomethane ug/L ND 5.0 03/10/20 21:461.7
Carbon tetrachloride ug/L ND 0.50 03/10/20 21:460.23
Chlorobenzene ug/L ND 0.50 03/10/20 21:460.22
Chloroethane ug/L ND 1.0 03/10/20 21:460.58
Chloroform ug/L ND 0.50 03/10/20 21:460.35
Chloromethane ug/L ND 1.0 03/10/20 21:460.42
cis-1,2-Dichloroethene ug/L ND 0.50 03/10/20 21:460.21
cis-1,3-Dichloropropene ug/L ND 0.50 03/10/20 21:460.36
Dibromochloromethane ug/L ND 0.50 03/10/20 21:460.40
Dibromomethane ug/L ND 0.50 03/10/20 21:460.31
Dichlorodifluoromethane ug/L ND 0.50 03/10/20 21:460.28
Diisopropyl ether ug/L ND 0.50 03/10/20 21:460.33
Ethylbenzene ug/L ND 0.50 03/10/20 21:460.24
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/12/2020 02:37 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92468516
Brack Griffin
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2828222
Associated Lab Samples:92468516001, 92468516002, 92468516003
Matrix:Water
AnalyzedMDL
Hexachloro-1,3-butadiene ug/L ND 2.0 03/10/20 21:461.2
Isopropylbenzene (Cumene)ug/L ND 0.50 03/10/20 21:460.24
m&p-Xylene ug/L ND 1.0 03/10/20 21:460.44
Methyl-tert-butyl ether ug/L ND 0.50 03/10/20 21:460.44
Methylene Chloride ug/L ND 2.0 03/10/20 21:461.5
n-Butylbenzene ug/L ND 0.50 03/10/20 21:460.35
n-Propylbenzene ug/L ND 0.50 03/10/20 21:460.24
Naphthalene ug/L ND 2.0 03/10/20 21:460.66
o-Xylene ug/L ND 0.50 03/10/20 21:460.24
sec-Butylbenzene ug/L ND 0.50 03/10/20 21:460.25
Styrene ug/L ND 0.50 03/10/20 21:460.26
tert-Butylbenzene ug/L ND 0.50 03/10/20 21:460.25
Tetrachloroethene ug/L ND 0.50 03/10/20 21:460.23
Toluene ug/L ND 0.50 03/10/20 21:460.23
trans-1,2-Dichloroethene ug/L ND 0.50 03/10/20 21:460.26
trans-1,3-Dichloropropene ug/L ND 0.50 03/10/20 21:460.39
Trichloroethene ug/L ND 0.50 03/10/20 21:460.23
Trichlorofluoromethane ug/L ND 1.0 03/10/20 21:460.34
Vinyl chloride ug/L ND 1.0 03/10/20 21:460.41
1,2-Dichloroethane-d4 (S)%98 70-130 03/10/20 21:46
4-Bromofluorobenzene (S)%98 70-130 03/10/20 21:46
Toluene-d8 (S)%105 70-130 03/10/20 21:46
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2828223LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 56.050 112 60-140
1,1,1-Trichloroethane ug/L 55.250 110 60-140
1,1,2,2-Tetrachloroethane ug/L 53.750 107 60-140
1,1,2-Trichloroethane ug/L 54.750 109 60-140
1,1-Dichloroethane ug/L 55.450 111 60-140
1,1-Dichloroethene ug/L 59.550 119 60-140
1,1-Dichloropropene ug/L 57.250 114 60-140
1,2,3-Trichlorobenzene ug/L 55.050 110 60-140
1,2,3-Trichloropropane ug/L 60.050 120 60-140
1,2,4-Trichlorobenzene ug/L 54.550 109 60-140
1,2,4-Trimethylbenzene ug/L 54.450 109 60-140
1,2-Dibromo-3-chloropropane ug/L 58.550 117 60-140
1,2-Dibromoethane (EDB)ug/L 56.750 113 60-140
1,2-Dichlorobenzene ug/L 53.650 107 60-140
1,2-Dichloroethane ug/L 51.750 103 60-140
1,2-Dichloropropane ug/L 55.450 111 60-140
1,3,5-Trimethylbenzene ug/L 55.550 111 60-140
1,3-Dichlorobenzene ug/L 52.550 105 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/12/2020 02:37 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92468516
Brack Griffin
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2828223LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichloropropane ug/L 55.150 110 60-140
1,4-Dichlorobenzene ug/L 53.250 106 60-140
2,2-Dichloropropane ug/L 57.250 114 60-140
2-Chlorotoluene ug/L 54.450 109 60-140
4-Chlorotoluene ug/L 54.550 109 60-140
Benzene ug/L 54.250 108 60-140
Bromobenzene ug/L 52.750 105 60-140
Bromochloromethane ug/L 56.350 113 60-140
Bromodichloromethane ug/L 57.650 115 60-140
Bromoform ug/L 56.950 114 60-140
Bromomethane ug/L 54.850 110 60-140
Carbon tetrachloride ug/L 58.750 117 60-140
Chlorobenzene ug/L 53.950 108 60-140
Chloroethane ug/L 45.150 90 60-140
Chloroform ug/L 55.550 111 60-140
Chloromethane ug/L 44.150 88 60-140
cis-1,2-Dichloroethene ug/L 54.450 109 60-140
cis-1,3-Dichloropropene ug/L 57.050 114 60-140
Dibromochloromethane ug/L 56.850 114 60-140
Dibromomethane ug/L 53.950 108 60-140
Dichlorodifluoromethane ug/L 51.450 103 60-140
Diisopropyl ether ug/L 55.550 111 60-140
Ethylbenzene ug/L 50.950 102 60-140
Hexachloro-1,3-butadiene ug/L 53.250 106 60-140
Isopropylbenzene (Cumene)ug/L 54.650 109 60-140
m&p-Xylene ug/L 104100 104 60-140
Methyl-tert-butyl ether ug/L 53.550 107 60-140
Methylene Chloride ug/L 51.850 104 60-140
n-Butylbenzene ug/L 55.150 110 60-140
n-Propylbenzene ug/L 52.350 105 60-140
Naphthalene ug/L 57.150 114 60-140
o-Xylene ug/L 54.050 108 60-140
sec-Butylbenzene ug/L 52.750 105 60-140
Styrene ug/L 57.950 116 60-140
tert-Butylbenzene ug/L 41.150 82 60-140
Tetrachloroethene ug/L 53.450 107 60-140
Toluene ug/L 51.550 103 60-140
trans-1,2-Dichloroethene ug/L 56.950 114 60-140
trans-1,3-Dichloropropene ug/L 59.550 119 60-140
Trichloroethene ug/L 51.750 103 60-140
Trichlorofluoromethane ug/L 49.750 99 60-140
Vinyl chloride ug/L 57.550 115 60-140
1,2-Dichloroethane-d4 (S)%94 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%101 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/12/2020 02:37 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92468516
Brack Griffin
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2828224MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92468516003
2828225
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 400 116 60-140117 1 30400ND464467
1,1,1-Trichloroethane ug/L 400 119 60-140119 0 30400ND477478
1,1,2,2-Tetrachloroethane ug/L 400 115 60-140117 2 30400ND461468
1,1,2-Trichloroethane ug/L 400 115 60-140116 1 30400ND460463
1,1-Dichloroethane ug/L 400 116 60-140117 0 30400ND465467
1,1-Dichloroethene ug/L 400 126 60-140130 3 30400ND505521
1,1-Dichloropropene ug/L 400 123 60-140124 1 30400ND493496
1,2,3-Trichlorobenzene ug/L 400 112 60-140118 5 30400ND446470
1,2,3-Trichloropropane ug/L 400 88 60-14091 3 30400ND354363
1,2,4-Trichlorobenzene ug/L 400 111 60-140116 5 30400ND443465
1,2,4-Trimethylbenzene ug/L 400 120 60-140126 2 3040066211401170
1,2-Dibromo-3-
chloropropane ug/L 400 121 60-140127 5 30400ND484507
1,2-Dibromoethane (EDB)ug/L 400 125 60-140124 1 30400ND500494
1,2-Dichlorobenzene ug/L 400 114 60-140117 3 30400ND456469
1,2-Dichloroethane ug/L 400 110 60-140111 0 3040095714001400
1,2-Dichloropropane ug/L 400 120 60-140119 0 30400ND478477
1,3,5-Trimethylbenzene ug/L 400 118 60-140124 3 30400236709732
1,3-Dichlorobenzene ug/L 400 109 60-140111 2 30400ND435443
1,3-Dichloropropane ug/L 400 114 60-140115 0 30400ND458459
1,4-Dichlorobenzene ug/L 400 116 60-140119 2 30400ND465476
2,2-Dichloropropane ug/L 400 100 60-14090 10 30400ND398359
2-Chlorotoluene ug/L 400 133 60-140136 2 30400ND531543
4-Chlorotoluene ug/L 400 115 60-140118 2 30400ND462473
Benzene ug/L 400 117 60-140131 2 30400290033703420
Bromobenzene ug/L 400 112 60-140114 1 30400ND449455
Bromochloromethane ug/L 400 123 60-140113 8 30400ND492454
Bromodichloromethane ug/L 400 120 60-140121 1 30400ND480482
Bromoform ug/L 400 114 60-140114 0 30400ND457455
Bromomethane ug/L 400 74 60-14074 0 30400ND295295
Carbon tetrachloride ug/L 400 128 60-140129 1 30400ND511515
Chlorobenzene ug/L 400 114 60-140115 1 30400ND455458
Chloroethane ug/L 400 119 60-140118 0 3040058.4 534 532
Chloroform ug/L 400 117 60-140118 1 30400ND467472
Chloromethane ug/L 400 102 60-140109 6 30400ND408436
cis-1,2-Dichloroethene ug/L 400 114 60-140116 2 30400ND455462
cis-1,3-Dichloropropene ug/L 400 106 60-140108 2 30400ND424431
Dibromochloromethane ug/L 400 114 60-140116 1 30400ND458462
Dibromomethane ug/L 400 115 60-140115 0 30400ND459459
Dichlorodifluoromethane ug/L 400 100 60-140101 0 30400ND402403
Diisopropyl ether ug/L 400 119 60-140121 2 3040064.6 539 547
Ethylbenzene ug/L 400 107 60-140109 1 30400244670678
Hexachloro-1,3-butadiene ug/L 400 109 60-140116 6 30400ND436463
Isopropylbenzene(Cumene)ug/L 400 115 60-140116 1 3040026.2 485 489
m&p-Xylene ug/L 800 111 60-140114 1 30800139022802300
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/12/2020 02:37 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92468516
Brack Griffin
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2828224MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92468516003
2828225
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methyl-tert-butyl ether ug/L 400 118 60-140117 1 3040026.2 499 494
Methylene Chloride ug/L 400 126 60-140127 1 30400ND505508
n-Butylbenzene ug/L 400 120 60-140125 4 30400ND480500
n-Propylbenzene ug/L 400 110 60-140114 3 3040055.9 496 512
Naphthalene ug/L 400 115 60-140124 4 30400307768802
o-Xylene ug/L 400 113 60-140117 2 3040062210701090
sec-Butylbenzene ug/L 400 116 60-140119 2 30400ND465476
Styrene ug/L 400 122 60-140124 1 30400ND489495
tert-Butylbenzene ug/L 400 93 60-14094 1 30400ND374378
Tetrachloroethene ug/L 400 112 60-140114 1 30400ND448454
Toluene ug/L 400 109 60-140115 2 3040077612101240
trans-1,2-Dichloroethene ug/L 400 121 60-140120 1 30400ND483480
trans-1,3-Dichloropropene ug/L 400 107 60-140109 2 30400ND429437
Trichloroethene ug/L 400 111 60-140111 0 30400ND445444
Trichlorofluoromethane ug/L 400 109 60-140108 1 30400ND437433
Vinyl chloride ug/L 400 113 60-140115 2 30400ND450458
1,2-Dichloroethane-d4 (S)%99 70-13098
4-Bromofluorobenzene (S)%99 70-13099
Toluene-d8 (S)%101 70-130101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/12/2020 02:37 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92468516
Brack Griffin
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
529874
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92468516004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2829927
Associated Lab Samples:92468516004
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 0.50 03/11/20 17:150.42
1,1,1-Trichloroethane ug/L ND 0.50 03/11/20 17:150.28
1,1,2,2-Tetrachloroethane ug/L ND 0.50 03/11/20 17:150.19
1,1,2-Trichloroethane ug/L ND 0.50 03/11/20 17:150.23
1,1-Dichloroethane ug/L ND 0.50 03/11/20 17:150.24
1,1-Dichloroethene ug/L ND 0.50 03/11/20 17:150.22
1,1-Dichloropropene ug/L ND 0.50 03/11/20 17:150.35
1,2,3-Trichlorobenzene ug/L ND 2.0 03/11/20 17:150.78
1,2,3-Trichloropropane ug/L ND 0.50 03/11/20 17:150.27
1,2,4-Trichlorobenzene ug/L ND 2.0 03/11/20 17:150.44
1,2,4-Trimethylbenzene ug/L ND 0.50 03/11/20 17:150.19
1,2-Dibromo-3-chloropropane ug/L ND 1.0 03/11/20 17:150.38
1,2-Dibromoethane (EDB)ug/L ND 0.50 03/11/20 17:150.23
1,2-Dichlorobenzene ug/L ND 0.50 03/11/20 17:150.24
1,2-Dichloroethane ug/L ND 0.50 03/11/20 17:150.26
1,2-Dichloropropane ug/L ND 0.50 03/11/20 17:150.18
1,3,5-Trimethylbenzene ug/L ND 0.50 03/11/20 17:150.23
1,3-Dichlorobenzene ug/L ND 0.50 03/11/20 17:150.25
1,3-Dichloropropane ug/L ND 0.50 03/11/20 17:150.34
1,4-Dichlorobenzene ug/L ND 0.50 03/11/20 17:150.25
2,2-Dichloropropane ug/L ND 0.50 03/11/20 17:150.28
2-Chlorotoluene ug/L ND 0.50 03/11/20 17:150.21
4-Chlorotoluene ug/L ND 0.50 03/11/20 17:150.21
Benzene ug/L ND 0.50 03/11/20 17:150.24
Bromobenzene ug/L ND 0.50 03/11/20 17:150.22
Bromochloromethane ug/L ND 0.50 03/11/20 17:150.26
Bromodichloromethane ug/L ND 0.50 03/11/20 17:150.18
Bromoform ug/L ND 0.50 03/11/20 17:150.40
Bromomethane ug/L ND 5.0 03/11/20 17:151.7
Carbon tetrachloride ug/L ND 0.50 03/11/20 17:150.23
Chlorobenzene ug/L ND 0.50 03/11/20 17:150.22
Chloroethane ug/L ND 1.0 03/11/20 17:150.58
Chloroform ug/L ND 0.50 03/11/20 17:150.35
Chloromethane ug/L ND 1.0 03/11/20 17:150.42
cis-1,2-Dichloroethene ug/L ND 0.50 03/11/20 17:150.21
cis-1,3-Dichloropropene ug/L ND 0.50 03/11/20 17:150.36
Dibromochloromethane ug/L ND 0.50 03/11/20 17:150.40
Dibromomethane ug/L ND 0.50 03/11/20 17:150.31
Dichlorodifluoromethane ug/L ND 0.50 03/11/20 17:150.28
Diisopropyl ether ug/L ND 0.50 03/11/20 17:150.33
Ethylbenzene ug/L ND 0.50 03/11/20 17:150.24
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/12/2020 02:37 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92468516
Brack Griffin
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2829927
Associated Lab Samples:92468516004
Matrix:Water
AnalyzedMDL
Hexachloro-1,3-butadiene ug/L ND 2.0 03/11/20 17:151.2
Isopropylbenzene (Cumene)ug/L ND 0.50 03/11/20 17:150.24
m&p-Xylene ug/L ND 1.0 03/11/20 17:150.44
Methyl-tert-butyl ether ug/L ND 0.50 03/11/20 17:150.44
Methylene Chloride ug/L ND 2.0 03/11/20 17:151.5
n-Butylbenzene ug/L ND 0.50 03/11/20 17:150.35
n-Propylbenzene ug/L ND 0.50 03/11/20 17:150.24
Naphthalene ug/L ND 2.0 03/11/20 17:150.66
o-Xylene ug/L ND 0.50 03/11/20 17:150.24
sec-Butylbenzene ug/L ND 0.50 03/11/20 17:150.25
Styrene ug/L ND 0.50 03/11/20 17:150.26
tert-Butylbenzene ug/L ND 0.50 03/11/20 17:150.25
Tetrachloroethene ug/L ND 0.50 03/11/20 17:150.23
Toluene ug/L ND 0.50 03/11/20 17:150.23
trans-1,2-Dichloroethene ug/L ND 0.50 03/11/20 17:150.26
trans-1,3-Dichloropropene ug/L ND 0.50 03/11/20 17:150.39
Trichloroethene ug/L ND 0.50 03/11/20 17:150.23
Trichlorofluoromethane ug/L ND 1.0 03/11/20 17:150.34
Vinyl chloride ug/L ND 1.0 03/11/20 17:150.41
1,2-Dichloroethane-d4 (S)%100 70-130 03/11/20 17:15
4-Bromofluorobenzene (S)%99 70-130 03/11/20 17:15
Toluene-d8 (S)%99 70-130 03/11/20 17:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2829928LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 56.850 114 60-140
1,1,1-Trichloroethane ug/L 57.950 116 60-140
1,1,2,2-Tetrachloroethane ug/L 54.350 109 60-140
1,1,2-Trichloroethane ug/L 55.150 110 60-140
1,1-Dichloroethane ug/L 56.650 113 60-140
1,1-Dichloroethene ug/L 60.550 121 60-140
1,1-Dichloropropene ug/L 58.950 118 60-140
1,2,3-Trichlorobenzene ug/L 55.250 110 60-140
1,2,3-Trichloropropane ug/L 63.350 127 60-140
1,2,4-Trichlorobenzene ug/L 54.850 110 60-140
1,2,4-Trimethylbenzene ug/L 55.250 110 60-140
1,2-Dibromo-3-chloropropane ug/L 59.050 118 60-140
1,2-Dibromoethane (EDB)ug/L 57.050 114 60-140
1,2-Dichlorobenzene ug/L 53.450 107 60-140
1,2-Dichloroethane ug/L 53.150 106 60-140
1,2-Dichloropropane ug/L 55.450 111 60-140
1,3,5-Trimethylbenzene ug/L 56.350 113 60-140
1,3-Dichlorobenzene ug/L 52.050 104 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/12/2020 02:37 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92468516
Brack Griffin
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2829928LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichloropropane ug/L 55.750 111 60-140
1,4-Dichlorobenzene ug/L 52.950 106 60-140
2,2-Dichloropropane ug/L 66.750 133 60-140
2-Chlorotoluene ug/L 55.050 110 60-140
4-Chlorotoluene ug/L 54.650 109 60-140
Benzene ug/L 54.250 108 60-140
Bromobenzene ug/L 53.050 106 60-140
Bromochloromethane ug/L 58.050 116 60-140
Bromodichloromethane ug/L 58.350 117 60-140
Bromoform ug/L 58.850 118 60-140
Bromomethane ug/L 49.750 99 60-140
Carbon tetrachloride ug/L 60.850 122 60-140
Chlorobenzene ug/L 54.050 108 60-140
Chloroethane ug/L 46.050 92 60-140
Chloroform ug/L 56.550 113 60-140
Chloromethane ug/L 43.250 86 60-140
cis-1,2-Dichloroethene ug/L 55.150 110 60-140
cis-1,3-Dichloropropene ug/L 57.950 116 60-140
Dibromochloromethane ug/L 57.550 115 60-140
Dibromomethane ug/L 54.550 109 60-140
Dichlorodifluoromethane ug/L 49.050 98 60-140
Diisopropyl ether ug/L 57.350 115 60-140
Ethylbenzene ug/L 50.950 102 60-140
Hexachloro-1,3-butadiene ug/L 56.850 114 60-140
Isopropylbenzene (Cumene)ug/L 55.150 110 60-140
m&p-Xylene ug/L 106100 106 60-140
Methyl-tert-butyl ether ug/L 57.050 114 60-140
Methylene Chloride ug/L 55.650 111 60-140
n-Butylbenzene ug/L 56.750 113 60-140
n-Propylbenzene ug/L 52.850 106 60-140
Naphthalene ug/L 57.650 115 60-140
o-Xylene ug/L 53.850 108 60-140
sec-Butylbenzene ug/L 53.150 106 60-140
Styrene ug/L 57.850 116 60-140
tert-Butylbenzene ug/L 41.350 83 60-140
Tetrachloroethene ug/L 54.450 109 60-140
Toluene ug/L 51.550 103 60-140
trans-1,2-Dichloroethene ug/L 58.150 116 60-140
trans-1,3-Dichloropropene ug/L 61.050 122 60-140
Trichloroethene ug/L 52.250 104 60-140
Trichlorofluoromethane ug/L 52.250 104 60-140
Vinyl chloride ug/L 55.650 111 60-140
1,2-Dichloroethane-d4 (S)%97 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%101 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/12/2020 02:37 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92468516
Brack Griffin
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2829929MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92468514001
2829930
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 200 120 60-140123 2 30200ND241245
1,1,1-Trichloroethane ug/L 200 127 60-140129 2 30200ND253257
1,1,2,2-Tetrachloroethane ug/L 200 116 60-140118 2 30200ND232237
1,1,2-Trichloroethane ug/L 200 120 60-140119 0 30200ND239239
1,1-Dichloroethane ug/L 200 124 60-140125 1 30200ND248250
1,1-Dichloroethene ug/L 200 138 60-140136 1 30200ND275271
1,1-Dichloropropene ug/L 200 132 60-140132 1 30200ND263265
1,2,3-Trichlorobenzene ug/L 200 116 60-140119 3 30200ND231238
1,2,3-Trichloropropane ug/L 200 91 60-14095 4 30200ND182189
1,2,4-Trichlorobenzene ug/L 200 117 60-140118 0 30200ND235236
1,2,4-Trimethylbenzene ug/L 200 125 60-140125 0 30200373622622
1,2-Dibromo-3-
chloropropane ug/L 200 127 60-140123 3 30200ND253246
1,2-Dibromoethane (EDB)ug/L 200 124 60-140124 0 30200ND247247
1,2-Dichlorobenzene ug/L 200 118 60-140118 0 30200ND236237
1,2-Dichloroethane ug/L 200 116 60-140117 1 30200ND232235
1,2-Dichloropropane ug/L 200 124 60-140124 0 30200ND248248
1,3,5-Trimethylbenzene ug/L 200 126 60-140126 0 30200154406406
1,3-Dichlorobenzene ug/L 200 115 60-140114 0 30200ND229228
1,3-Dichloropropane ug/L 200 120 60-140121 1 30200ND239242
1,4-Dichlorobenzene ug/L 200 121 60-140122 1 30200ND242244
2,2-Dichloropropane ug/L 200 116 60-140131 13 30200ND232263
2-Chlorotoluene ug/L 200 140 60-140139 1 30200ND280277
4-Chlorotoluene ug/L 200 122 60-140122 0 30200ND243243
Benzene ug/L 200 125 60-140131 1 30200103012801300
Bromobenzene ug/L 200 117 60-140118 1 30200ND234236
Bromochloromethane ug/L 200 130 60-140134 3 30200ND261268
Bromodichloromethane ug/L 200 127 60-140126 1 30200ND254252
Bromoform ug/L 200 117 60-140119 2 30200ND233239
Bromomethane ug/L 200 64 60-14083 25 30200ND129166
Carbon tetrachloride ug/L 200 133 60-140136 2 30200ND267272
Chlorobenzene ug/L 200 120 60-140120 0 30200ND240241
Chloroethane ug/L 200 132 60-140130 1 30200ND264260
Chloroform ug/L 200 121 60-140123 2 30200ND242246
Chloromethane ug/L 200 79 60-14084 6 30200ND157167
cis-1,2-Dichloroethene ug/L 200 122 60-140121 0 30200ND243243
cis-1,3-Dichloropropene ug/L 200 114 60-140119 4 30200ND228238
Dibromochloromethane ug/L 200 120 60-140121 1 30200ND240242
Dibromomethane ug/L 200 119 60-140120 1 30200ND238240
Dichlorodifluoromethane ug/L 200 110 60-140110 1 30200ND219221
Diisopropyl ether ug/L 200 125 60-140126 1 30200ND250251
Ethylbenzene ug/L 200 112 60-140116 1 30200308533540
Hexachloro-1,3-butadiene ug/L 200 119 60-140120 1 30200ND237239
Isopropylbenzene(Cumene)ug/L 200 122 60-140123 1 3020012.8 256 259
m&p-Xylene ug/L 400 116 60-140117 0 3040073212001200
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/12/2020 02:37 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92468516
Brack Griffin
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2829929MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92468514001
2829930
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methyl-tert-butyl ether ug/L 200 121 60-140127 4 30200ND243253
Methylene Chloride ug/L 200 126 60-140121 4 3020016.3J 269 257
n-Butylbenzene ug/L 200 127 60-140128 1 30200ND254256
n-Propylbenzene ug/L 200 119 60-140120 1 3020031.3 270 272
Naphthalene ug/L 200 125 60-140127 1 30200174423428
o-Xylene ug/L 200 119 60-140121 1 30200327566570
sec-Butylbenzene ug/L 200 122 60-140123 0 30200ND244245
Styrene ug/L 200 131 60-140132 1 30200ND262263
tert-Butylbenzene ug/L 200 99 60-14098 1 30200ND198197
Tetrachloroethene ug/L 200 120 60-140121 1 30200ND240241
Toluene ug/L 200 117 60-140118 0 30200417651652
trans-1,2-Dichloroethene ug/L 200 128 60-140129 1 30200ND255258
trans-1,3-Dichloropropene ug/L 200 115 60-140120 5 30200ND229241
Trichloroethene ug/L 200 118 60-140117 1 30200ND236235
Trichlorofluoromethane ug/L 200 116 60-140117 1 30200ND233234
Vinyl chloride ug/L 200 115 60-140118 3 30200ND230237
1,2-Dichloroethane-d4 (S)%105 70-130106
4-Bromofluorobenzene (S)%99 70-130100
Toluene-d8 (S)%100 70-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/12/2020 02:37 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 27
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92468516
Brack Griffin
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/12/2020 02:37 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 27
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92468516
Brack Griffin
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92468516001 529537MW-1 SM 6200B
92468516002 529537MW-4 SM 6200B
92468516003 529537MW-5 SM 6200B
92468516004 529874MW-11 SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/12/2020 02:37 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 27
Page 27 of 27
APPENDIX B
FIELD NOTES
APPENDIX C
PHOTOGRAPHS
Project No. 71159684A
Date Photos Taken: March 5, 2020
Brack Griffin Property (NCDEQ Incident 20257) – Marshville, North Carolina
Photo 1 View of well MW-11 (red arrow), looking south across Marshville-Olive Branch Road.
Photo 2 View of well MW-1 (red arrow), looking northwest across Old Goldmine Road.
Project No. 71159684A
Date Photos Taken: March 5, 2020
Brack Griffin Property (NCDEQ Incident 20257) – Marshville, North Carolina
Photo 3 View of monitoring well MW-5, looking west towards the intersection of Old Goldmine
Road and Marshville-Olive Branch Road.
Photo 4 View of well MW-4 (under cone), looking west across Old Goldmine Road.
Project No. 71159684A
Date Photos Taken: March 5, 2020
Brack Griffin Property (NCDEQ Incident 20257) – Marshville, North Carolina
Photo 5 View of the on-site building, looking northeast.