MO-5597_19688_CA_MRP_20200212

GROUNDWATER MONITORING REPORT
Hodge’s Exxon
145 East Broad Street
Statesville, Iredell County, North Carolina 28677
NCDEQ Incident #19688
ATC Project #SLP1968803

February 12, 2020

TABLE OF CONTENTS

1.0 SITE IDENTIFICATION .......................................................................................1
2.0 EXECUTIVE SUMMARY .....................................................................................2
3.0 SITE DESCRIPTION .............................................................................................3
3.1 Site Characterization ................................................................................3
3.2 Site Background .......................................................................................3
3.3 Site and Regional Geology ......................................................................5
3.4 Site and Regional Hydrogeology .............................................................5
4.0 GROUNDWATER CHARACTERIZATION.......................................................6
4.1 Groundwater Levels .................................................................................6
4.2 Groundwater Quality ...............................................................................6
5.0 CONCLUSIONS AND RECOMMENDATIONS .................................................7

TABLES
Table 1 Monitoring Well Construction Details
Table 2 Groundwater Elevation Data
Table 3 Field Parameters
Table 4 Current Groundwater Analytical Results
Table 5 Historical Groundwater Analytical Results

FIGURES
Figure 1 Site Location Map
Figure 2 Site Map
Figure 3 Groundwater Elevation Contour Map
Figure 4 Groundwater Quality Map

APPENDICES
Appendix A Field Notes
Appendix B Laboratory Analytical Report
Appendix C Mann-Kendall Toolkit Trend Analysis

Groundwater Monitoring Report February 12, 2020 September 3, 2014
Hodge’s Exxon - Incident #19688 ATC Project #SLP1968803
2

2.0 EXECUTIVE SUMMARY
ATC Associates of North Carolina, P.C. (ATC) has completed a Groundwater Monitoring Report
(GMR) documenting a monitoring event conducted on October 17, 2019, of seven on-site
monitoring wells at Hodge’s Exxon, located at 145 East Broad Street, Statesville, Iredell County,
North Carolina. The GMR is being performed based on a October 11, 2019, Task Authorization
(TA-03) by the Trust Fund Branch of the Underground Storage Tank (UST) Section, Division of
Waste Management, North Carolina Department of Environmental Quality (NCDEQ). The work is
being performed as part of the State Lead Contract #N17004 between NCDEQ and ATC.

A release associated with the removal of four former on-site petroleum USTs was reported in April
1991. During a Limited Site Assessment (LSA) in 1999, a second release from the heating oil UST
was confirmed, and it was removed later in 1999. The site is currently occupied by ACE Cash
Express Money Service and HD Wireless with no retail fuel operations.

As part of the TA, ATC collected groundwater samples from three monitoring wells, MW-1R,
MW-3, and MW-4. ATC was unable to sample monitoring wells MW-02, MW-05 and MW-06 due
to obstructions. ATC was unable to collect a sample from monitoring well MW-07 because the well
was purged dry during sampling and did not recharge. Historically, groundwater sampling results
from monitoring wells MW-05 and MW-06 indicated no detections of VOCs exceeding detection
limits. The most recent sampling of monitoring wells MW-02 and MW-07 indicated only MTBE in
MW-02 at concentrations of 20 micrograms per liter (µg/L). The groundwater was analyzed for
volatile organic compounds (VOCs) including petroleum constituents. The findings from the
monitoring event indicate the following:

 No water supply wells are located within 1,000 feet and no surface water bodies are
located within 500 feet of the source areas;
 Light Non-Aqueous Phase Liquid (LNAPL) was not encountered during the groundwater
monitoring event;
 None of the detected concentrations exceeded Gross Contaminant Levels (GCLs);
 Monitoring wells MW-01R, MW-03, and MW-04 contained concentrations of several
constituents above the 2L Standards;
 Based on groundwater elevation data, groundwater appears to flow toward the south, which
is consistent with previous interpretations; and
 Mann Kendall trend analyses indicated a decreasing trend for concentrations in MW-1R,
stable to probably decreasing/decreasing trend in well MW-3, and a decreasing trend in well
MW-4.

Based on the above, ATC recommends evaluation of the site for closure.
Groundwater Monitoring Report February 12, 2020 September 3, 2014
Hodge’s Exxon - Incident #19688 ATC Project #SLP1968803
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3.0 SITE DESCRIPTION
3.1 Site Characterization
The NCDEQ retained ATC to provide environmental consulting services for Hodge’s Exxon,
located at 145 East Broad Street, Statesville, Iredell County, North Carolina. Figure 1 depicts the
site location on a topographic map. The site currently operates as ACE Cash Express Money
Service, and HD Wireless, a wireless retail business. Municipal water is available to the site and
vicinity.

3.2 Site Background
The site formerly operated as Hodge’s Exxon, a gasoline service station. Five USTs were used at
the site, including one 6,000-gallon gasoline UST, one 5,000-gallon gasoline UST, one 2,000-
gallon gasoline UST, one 1,000-gallon heating oil UST, and one 550-gallon waste oil UST. Four
of the USTs were installed in March 1956, the 6,000-gallon gasoline UST was installed in March
1966. In April 1991, all of the USTs, with the exception of the 1,000-gallon heating oil UST
were removed. Impacted soil was excavated from the tank basin in April 1991 to a depth of 28
feet below ground surface (bgs). A release was confirmed during the 1991 tank removal.
Because soil samples were not collected from the piping and dispenser island the UST Closure
was considered incomplete.

In January 1999, a UST Closure Addendum was prepared by Schnabel Engineering that
indicated impacted soil was present along the piping run and that a Limited Site Assessment
(LSA) was required.

A LSA was completed in July 1999 by Southeastern Geological Services Inc. (Southeastern),
that included the installation of monitoring wells MW-01, MW-02, MW-03, and MW-04 and
vertical extent well VMW-01. During the LSA, a second release was discovered associated with
the heating oil UST. Groundwater impact was identified in the monitoring well network,
including two inches of free product in monitoring well MW-04.

Subsequent to the LSA, the 1,000-gallon heating oil UST was reportedly removed in 1999. The
1999 UST Closure Report was not available for review. A Comprehensive Site Assessment
(CSA), completed in September 2000 by Southeastern included the installation of monitoring
wells MW-05, MW-06, and MW-07; groundwater monitoring; a receptor survey for the site; and
a discussion of the 1999 heating oil UST removal. According to the CSA, closure samples from
the 1999 heating oil UST removal reportedly indicated no evidence of a release. A free product
thickness of 2.90 feet was detected in monitoring well MW-04. Groundwater impact above 2L
Standards was identified in monitoring wells MW-01, MW-02, MW-03, and MW-07. No
potential receptors were identified within a 1,000 foot radius of the site.

A groundwater monitoring event on June 3, 2010, was performed by Force Environmental
Service Company, LLC (Force). During the groundwater monitoring event, monitoring wells
MW-01 and VMW-01 were observed to have accumulated large quantities of silt. A free product
thickness of 0.10 feet was detected in monitoring well MW-04, and a sheen was observed in
monitoring well MW-02. Monitoring wells MW-02, MW-03, and VW-01 indicated aliphatic
Groundwater Monitoring Report February 12, 2020 September 3, 2014
Hodge’s Exxon - Incident #19688 ATC Project #SLP1968803
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impact above GCLs. Monitoring wells MW-02, MW-03, MW-07, and VMW-01 contained
petroleum impact above 2L Standards.

In August 2010, monitoring wells MW-01 and VW-01 were abandoned due to the high content
of silt in the well screen. Monitoring well MW-01R was subsequently installed near the previous
monitoring well MW-01. A groundwater monitoring event was also performed that indicated a
free product thickness of 0.15 feet in monitoring well MW-04. Groundwater sampling results
indicated aliphatic impact above established GCLs in monitoring wells MW-02 and MW-03.
Petroleum impact of one or more constituents above 2L Standards was identified in monitoring
wells MW-01R, MW-02, MW-03, and MW-07.

An AFVR event was performed using well MW-04 in October 2010. Post-AFVR sampling was
performed in December 2010 that indicated that no measurable free product was detected in the
monitoring well network; however, impact above GCLs and 2L Standards was identified.

In August 2011, Force completed a Mobile Multi-Phase Extraction (MMPE) event and
groundwater monitoring at the site using monitoring wells MW-01R, MW-03, and MW-04 as
extraction points. Free product was not identified in the recovered groundwater. A groundwater
monitoring event was performed following the completion of the MMPE event. Monitoring well
MW-01R contained impact above the established GCL for benzene. Groundwater analytical
results for samples collected from monitoring wells MW-01R, MW-02, MW-03, MW-04 and
MW-07 indicated concentrations of one or more constituents above 2L Standards.

In September 2012, Force injected an oxygenate compound into the monitoring wells to reduce
concentrations below GCLs in the monitoring well system. Five-hundred pounds of Klozur
sodium persulfate, 680 pounds of Klozur Caustic, and 119 gallons of potable water were gravity
fed into impacted wells. A PermeOx solution was injected into two of the upgradient wells.

A groundwater monitoring report, dated March 22, 2013, did not identify impact above GCLs at
the site. Monitoring wells MW-01R, MW-03, and MW-04 contained concentrations of one or
more petroleum constituents above 2L Standards. Monitoring wells MW-02 and MW-07 were
not sampled in 2013. However, another monitoring event performed in December 2014,
indicated impact above the GCL for benzene in well MW-01R and several wells with impact
above the 2L Standard for multiple petroleum compounds.

To enhance the natural degradation of dissolved phase petroleum impact, Adventus remedial
oxygen releasing socks (ORS) were installed in monitoring wells MW-01R and MW-03 on
August 27, 2015. A groundwater monitoring event was performed in February 2016 to evaluate
groundwater quality following the ORS installation. Contaminants above 2L Standards were
observed in monitoring wells MW-01R, MW-03, and MW-04. Monitoring well MW-01R contained
benzene at a concentration exceeding the GCL.

In June 2016, ATC conducted an 8-hour AFVR event and replaced ORS at the site. The AFVR
event used monitoring wells MW-01R and MW-04 as the extraction wells. A total of 225 gallons of
petroleum-impacted groundwater and 0.99 pounds of petroleum emissions as vapor were recovered
Groundwater Monitoring Report February 12, 2020 September 3, 2014
Hodge’s Exxon - Incident #19688 ATC Project #SLP1968803
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during the event. Following the AFVR event, two ORS were installed in monitoring wells MW-
01R, MW-03, and MW-04.

ATC conducted groundwater monitoring on January 22, 2018, to further evaluate groundwater
quality. Laboratory analysis indicated a concentration of EDB above GCLs in well MW-03.
Concentrations of petroleum constituents exceeded NC 2L Standards in wells MW-01R, MW-
03, and MW-04.

ATC conducted groundwater monitoring on September 28, 2018. Petroleum constituents
exceeding 2L Standards were detected in monitoring wells MW-01R, MW-03, and MW-04;
however, no exceedances of the GCLs were indicated.

3.3 Site and Regional Geology

According to the Geologic Map of North Carolina, produced by the State of North Carolina in
1985, the site is located in the Charlotte Belt of the Piedmont Physiographic Province of North
Carolina. The rock type at the site has been identified as granite, which is crystalline igneous
rock. The shallow subsurface in most areas of the Piedmont contains residual soil overburden,
including structure-free residuum, saprolite, and partially weathered rock (PWR) that derive
from in-place weathering of the crystalline bedrock. Occasional areas containing recent deposits
of alluvium in the uppermost subsurface are found near streams and rivers. Saprolite and PWR
typically contain some relict structures from the original rock material. Depth to rock ranges
from ground surface at occasional outcrops to depths of greater than 100 feet in areas of easily
weathered rock. According to monitoring well installation records from the 1999 Phase I LSA,
the primary soil types encountered consisted of a surface layer of silty clay, followed by saprolite
mica schist.

3.4 Site and Regional Hydrogeology

The shallow aquifer occurrence varies in depth from ground surface at springs, creeks, and rivers
to as deep as 50 feet or more beneath upland surfaces in some parts of the Piedmont. Water in the
alluvium or unconsolidated residual material, including saprolite and PWR, usually behaves as
an unconfined aquifer, or water table, and will yield water with head elevation equivalent to the
first elevation where water was encountered. Permeability varies with lithology and is typically
relatively low in residual soils, with higher permeability in saprolite or PWR due to relict rock
texture and variable susceptibility to weathering exhibited by different minerals in the rock.
Groundwater flow in residual soils or alluvium is usually in rough concurrence with local
topographic conditions and is toward local drainage features. Based on the data from the
monitoring well network, shallow groundwater flows generally to the southeast, with depth to
groundwater around 21 ft bgs.

The bedrock fractures or other planar features of the Charlotte Belt Physiographic Province
generally constitute the bedrock aquifer, with the surrounding rock material being effectively
impermeable. Along with fractures, contacts between rock bodies probably constitute zones of
significant groundwater occurrence in the bedrock. The surrounding material and overlying
residuum tend to make the bedrock aquifer a semi-confined aquifer. That is, the overlying water
Groundwater Monitoring Report February 12, 2020 September 3, 2014
Hodge’s Exxon - Incident #19688 ATC Project #SLP1968803
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and soil weight normally results in pressure that causes water in a borehole, which intersects a
fracture or other feature, to rise above the elevation of the fracture or feature. Modern water
supply wells in the Piedmont, likely including those in the site vicinity, are typically installed
with a surface casing through the unconsolidated material, and an open borehole into the bedrock
where water-bearing fractures are encountered.

4.0 GROUNDWATER CHARACTERIZATION

4.1 Groundwater Levels
On October 17, 2019, groundwater monitoring was conducted using the site monitoring well
network. Water levels were gauged in monitoring wells MW-01R, MW-03, MW-04, and MW-
07. Table 1 presents monitoring well construction details. Monitoring wells MW-02, MW-05,
and MW-06 were obstructed and depth the water could not be measured. LNAPL was not
identified in the monitoring well network. Figure 2 depicts a site map. Groundwater elevation
data is summarized in Table 2. A groundwater contour map depicting groundwater flow is
presented in Figure 3, indicating groundwater flow to the south. Field notes from the October
17, 2019, groundwater monitoring event is presented in Appendix A.

4.2 Groundwater Quality
Groundwater monitoring was conducted on October 17, 2019. Groundwater samples were collected
from monitoring wells MW-01R, MW-03, and MW-04. Monitoring wells MW-02, MW-05, and
MW-06 were obstructed and could not be sampled. Monitoring well MW-07 was purged dry and
did not recharge and could not be sampled. Historically, groundwater sampling results from
monitoring wells MW-05 and MW-06 indicated no detections of VOCs exceeding detection limits.
The most recent sampling of monitoring wells MW-02 and MW-07 indicated only MTBE in MW-
02 at concentrations of 20 micrograms per liter (µg/L). During sampling activities, a three-volume
well purge was implemented prior to groundwater sample collection to ensure a representative
groundwater sample. Upon completion of purging, groundwater quality parameters were measured
in each well and are summarized in Table 3. The groundwater samples were collected in
laboratory-supplied, preserved containers; entered into chain of custody control; placed on ice; and
shipped to North Carolina accredited Pace Analytical Laboratories, located in Huntersville, NC. The
groundwater samples were analyzed by EPA Method 6200B for VOCs, including petroleum
constituents. The analytical report is included in Appendix B.

Current groundwater analytical results are summarized in Table 4. Historical groundwater analytical
results are summarized in Table 5. Groundwater analytical results indicated the following:

 LNAPL was not encountered during the groundwater monitoring event;
 None of the detected concentrations exceeded GCLs;
 Monitoring wells MW-01R, MW-03, and MW-04 contained concentrations of several
constituents above the 2L Standards; and
 Based on groundwater elevation data, groundwater appears to flow toward the south, which
is consistent with previous interpretations.

Groundwater Monitoring Report February 12, 2020 September 3, 2014
Hodge’s Exxon - Incident #19688 ATC Project #SLP1968803
7

Figure 4 depicts a groundwater quality map showing detected constituents exceeding the 2L
Standards for each well.

As part of ATC’s quality assurance and quality control (QA and QC) measures, a data review of the
laboratory reports was conducted. During the review, it was found that the samples were received
from the laboratory in acceptable condition and properly preserved. The samples were analyzed
within correct holding times and reported within the lab report, and the chain of custody was
properly completed by all parties. The laboratory QC report shows that an internal blank was
analyzed for each method that was used for the original samples. The laboratory fortified blank
(LFB) and laboratory control sample (LCS) data results were also provided for each analytical
method. Methylene chloride was detected in the field blank collected on October 17, 2019, but was
not detected in any of the groundwater samples. Refer to the laboratory reports in Appendix B for
details regarding QA results for the laboratory samples and any noted exceptions. Overall, ATC
concludes that the laboratory results are usable and any exceptions do not significantly impact the
conclusions presented in this report.

ATC completed a concentration trend evaluation using the GSI Mann-Kendall Toolkit for
Constituent Trend Analysis. Data from monitoring wells with historical LNAPL or high dissolved-
phase impact above or near the GCLs were entered into the toolkit for trend analyses. Monitoring
wells MW-1R, MW-3, and MW-4 were evaluated for primary constituents of concern which
indicated a decreasing trend for concentrations in monitoring well MW-1R, stable to decreasing
trend in monitoring well MW-3, and a decreasing trend in monitoring well MW-4. Documentation
from the Mann-Kendall trend analyses is included in Appendix C.

5.0 CONCLUSIONS AND RECOMMENDATIONS

On behalf of the Trust Fund Branch of the UST Section, ATC has completed a GMR
documenting the October 17, 2019, groundwater monitoring event for Hodge’s Exxon, located at
145 East Broad Street, Statesville, Iredell County, North Carolina. Based on the information
provided in this report, ATC offers the following conclusions:

 No water supply wells are located within 1,000 feet and no surface water bodies are
located within 500 feet of the source areas;
 LNAPL was not encountered during the groundwater monitoring event;
 None of the detected concentrations exceeded GCLs;
 Monitoring wells MW-01R, MW-03, and MW-04 contained concentrations of several
constituents above the 2L Standards;
 Based on groundwater elevation data, groundwater appears to flow toward the south, which
is consistent with previous interpretations; and
 Mann Kendall trend analyses indicated a decreasing trend for concentrations in MW-1R,
stable to probably decreasing/decreasing trend in well MW-3, and a decreasing trend in well
MW-4.

Based on the above, ATC recommends evaluation of the site for closure.

TABLES
MW-1*5/3/1999 24-34 34 NA
MW-01R 9/1/2010 24-34 31 100.00
MW-02 6/20/1999 21-31 31 101.07
MW-03 6/20/1999 21-31 31 100.48
MW-04 6/20/1999 21-31 31 100.18
MW-05 4/9/2000 21-31 31 93.51
MW-06 4/9/2000 21-31 31 96.88
MW-07 4/9/2000 28.6-38.6 38.6 100.64
VW-01 (V-1)*6/20/1999 62-65 65 100.37
Notes:
Elevations referenced to and arbitrary datum of 100 feet.
NM = Not measured
* In August 2010, well MW-01 was replaced by well MW-01R. Wels MW-01 and VW-01 were abandoned due to excessive silt infiltration.
NA = Not Available
STATESVILLE, IREDELL COUNTY, NORTH CAROLINA 28677
145 EAST BROAD STREET
HODGES EXXON
MONITORING WELL CONSTRUCTION DETAILS
TABLE 1
Top of Casing ElevationWell ID Date Installed Screen Interval (feet)Total Depth (feet)
NCDEQ INCIDENT #19688
6/23/1999 26.21 73.79
4/11/2000 26.25 73.75
6/3/2010 20.10 79.90
8/24/2010
8/25/2010 24.46 ND --75.54
12/1/2010 25.13 ND --74.87
5/11/2011 25.75 ND --74.25
10/4/2011 26.57 ND --73.43
1/29/2013 NM NM ----
12/31/2014 24.59 ND --75.41
2/12/2016 24.75 ND --75.25
6/9/2016 23.62 ND --76.38
1/22/2018 24.88 ND --75.12
11/14/2018 21.46 ND --78.54
10/17/2019 21.30 ND --78.70
6/23/1999 25.50 ND --75.57
4/11/2000 26.14 ND --74.93
6/3/2010 30.74 ND --70.33
8/25/2010 25.04 ND --76.03
12/1/2010 25.71 ND --75.36
5/11/2011 26.37 ND --74.70
10/4/2011 27.21 ND --73.86
1/29/2013 NM NM ----
12/31/2014 24.72 ND --76.35
2/12/2016 23.23 ND --77.84
1/22/2018 24.99 ND --76.08
11/14/2018 NM NM ----
10/17/2019 NM NM ----
6/23/1999 26.61 ND --73.87
4/11/2000 26.80 ND --73.68
6/3/2010 24.40 ND --76.08
8/25/2010 24.47 ND --76.01
12/1/2010 25.20 ND --75.28
5/11/2011 25.81 ND --74.67
10/4/2011 26.63 ND --73.85
1/29/2013 NM NM ----
12/31/2014 24.80 ND --75.68
2/12/2016 25.11 ND --75.37
6/9/2016 22.69 ND --77.79
1/22/2018 24.92 ND --75.56
11/14/2018 21.63 ND --78.85
10/17/2019 21.43 ND --79.05
6/23/1999 26.46 26.48 0.17 73.87
4/11/2000 26.47 23.57 2.90 76.20
6/3/2010 24.41 24.31 0.10 75.86
8/25/2010 24.49 24.34 0.15 75.82
12/1/2010 25.11 ND --75.07
5/11/2011 25.75 ND --74.43
10/4/2011 26.61 ND --73.57
1/29/2013 28.52 ND --71.66
12/31/2014 24.51 ND --75.67
2/12/2016 22.74 ND --77.44
6/9/2016 22.37 ND --77.81
1/22/2018 24.61 ND --75.57
11/14/2018 21.15 ND --79.03
10/17/2019 21.00 ND --79.18
MW-03 31 100.48
MW-04
MW-01R 100.00
MW-02
31
31 101.07
GROUNDWATER ELEVATION DATA
TABLE 2
NCDEQ INCIDENT #19688
STATESVILLE, IREDELL COUNTY, NORTH CAROLINA 28677
145 EAST BROAD STREET
HODGES EXXON
LNAPL
Thickness
(ft)
Gauging
Date
WELL ABANDONED
100.0034
Groundwater
Elevation
(ft)
Well
ID
TOC
Elevation
(ft)
Depth to
Groundwater
(ft-toc)
Total Well
Depth
(ft-bgs)
Depth to Free
Product
(ft-toc)
MW-01
31 100.18
Page 2 of 9
GROUNDWATER ELEVATION DATA
TABLE 2
NCDEQ INCIDENT #19688
STATESVILLE, IREDELL COUNTY, NORTH CAROLINA 28677
145 EAST BROAD STREET
HODGES EXXON
LNAPL
Thickness
(ft)
Gauging
Date
100.0034
Groundwater
Elevation
(ft)
Well
ID
TOC
Elevation
(ft)
Depth to
Groundwater
(ft-toc)
Total Well
Depth
(ft-bgs)
Depth to Free
Product
(ft-toc)
MW-01
4/11/2000 25.93 ND --67.58
6/3/2010 23.28 ND --70.23
8/25/2010 NM NM ----
12/1/2010 25.06 ND --68.45
5/11/2011 24.94 ND --68.57
10/4/2011 26.62 ND --66.89
1/29/2013 27.37 ND --66.14
12/31/2014 25.15 ND --68.36
1/22/2018 25.00 ND --68.51
11/14/2018 22.54 ND --70.97
10/17/2019 NM NM ----
4/11/2000 27.04 ND --69.84
6/3/2010 22.21 ND --74.67
8/25/2010 NM NM ----
12/1/2010 23.29 ND --73.59
5/11/2011 23.64 ND 73.24
10/4/2011 24.62 ND --72.26
1/29/2013 25.41 ND --71.47
12/31/2014 22.72 ND --74.16
1/22/2018 22.70 ND --74.18
11/14/2018 19.91 ND --76.97
10/17/2019 NM NM ----
4/11/2000 26.51 ND --74.13
6/3/2010 24.72 ND --75.92
8/25/2010 25.02 ND --75.62
12/1/2010 24.46 ND --76.18
5/11/2011 26.13 ND --74.51
10/4/2011 26.95 ND --73.69
1/29/2013 NM NM ----
12/31/2014 24.73 ND --75.91
2/12/2016 14.43 ND --86.21
6/9/2016 22.23 ND --78.41
1/22/2018 23.39 ND --77.25
11/14/2018 21.90 ND --78.74
10/17/2019 19.73 ND --80.91
6/23/1999 26.78 ND --73.59
4/1/2000 20.30 ND --80.07
6/3/2010 24.18 ND --76.19
8/24/2010
Notes:
All measurements expressed in feet ft : feet
TOC = Top of Casing ft-bgs = feet below ground surface
NM = Not Measured ft-toc = feet below top of casing
Reference point for elevation measurements is the Top of Casing of MW-1R with assumed elevation of 100.00 feet.
Groundwater elevation calculated by [Top of Casing Elevation - Depth to water] + [Free Product Thickness*0.87]
31 96.88
VW-01 (V-1)65 100.37
WELL ABANDONED
38.6 100.64
MW-05
MW-06
MW-07
31 93.51
Page 3 of 9
Well Date Temperature
(◦C)
Conductivity
(µS/cm)
pH
(su)
ORP
(mV)
DO
(mg/L)
MW-01R 10/17/2019 20.03 1.2 9.39 99 2.89
MW-02 10/17/2019
MW-03 10/17/2019 18.65 3.48 8.09 94 2.49
MW-04 10/17/2019 20.06 2.23 6.92 202 2.34
MW-05 10/17/2019
MW-06 10/17/2019
MW-07 10/17/2019
Notes:
°C : Degrees Celsium
µS/cm : microSiemens per centimeter
su : Standard Units
mV : milliVolt
mg/L : milligrams per liter
Not Sampled - Obstruction
Not Sampled - Obstruction
Not Sampled - well dry
HODGES EXXON
FIELD PARAMETERS
TABLE 3
Not Sampled - Obstruction
NCDEQ INCIDENT #19688
STATESVILLE, IREDELL COUNTY, NORTH CAROLINA 28677
145 EAST BROAD STREET
Well ID Sample
Date BenzeneTolueneEthylbenzeneTotal XylenesTotal BTEX1,2-Dibromoethane (EDB)1,2-DichloroethaneMethyl Tertiary Butyl EtherIsopropyl Ether (IPE)2-Hexanone (MBK)Naphthalenen-Butylbenzenesec-ButylbenzeneIsopropylbenzenen-Propylbenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene1 600 600 500 NE 0.02 0.4 20 70 40 6 70 70 70 70 400 400
5,000 260,000 84,500 85,500 NE 50 400 20,000 70,000 40,000 6,000 6,900 8,500 25,000 30,000 28,500 25,000
MW-01R 10/17/2019 624 5,440 774 3,980 10,818 <25.0 <25.0 73.9 268 NA 207 <25.0 <25.0 32.6 <25.0 618 <25.0
MW-02 10/17/2019
MW-03 10/17/2019 879 2,650 1,050 2,770 7,349 35.9 8.3 J 16.7 98.4 NA 233 <12.5 <12.5 63.6 <12.5 623 <12.5
MW-04 10/17/2019 11.0 166 677 7,290 8,164 <10.0 <10.0 <10.0 <10.0 NA 457 <10.0 <10.0 70.4 <10.0 1,940 <10.0
MW-05 10/17/2019
MW-06 10/17/2019
MW-07 10/17/2019
Notes:
Concentrations are reported in micrograms per liter (µg/l)
J = Estimated value below method reporting limit
NE = Not Established
Values in BOLD print exceed 2L Standards; values in BOLD and ITALICS exceed Gross Contamination Levels (GCLs)
145 EAST BROAD STREET
HODGES EXXON
CURRENT GROUNDWATER ANALYTICAL DATA
TABLE 4
NOT SAMPLED - OBSTRUCTION
2L Standard
GCL Standard
NCDEQ INCIDENT #19688
NOT SAMPLED - OBSTRUCTION
NOT SAMPLED - OBSTRUCTION
NOT SAMPLED - WELL DRY
STATESVILLE, IREDELL COUNTY, NORTH CAROLINA 28677
Well ID Sample
Date BenzeneTolueneEthylbenzeneTotal XylenesTotal BTEX1,2-Dibromoethane (EDB)*Methyl Tertiary Butyl EtherIsopropyl Ether (IPE)Acetone2-Butanone (MEK)2-Hexanone (MBK)Chloroform2-Chlorotoluene1,2,-DichloroethaneChlorobenzeneChloroethaneChloromethaneNaphthalenen-Butylbenzenesec-ButylbenzeneIsopropylbenzenep-Isopropyltoluenen-PropylbenzeneStyreneTetrachloroethene1,2,3 Trichloropropane1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneC5-C8 AliphaticsC9-C18 AliphaticsC9-C22 AliphaticsC9-C18 AliphaticsC19-C36 AliphaticsC11-C22 AliphaticsLeadChromium1 600 600 500 NE 0.02 20 70 6,000 4,000 40 70 NE 0.4 50 3,000 3 6 70 70 70 25 70 70 0.7 NE 400 400 400 700 200 NE 10,000 NE 15 10
5,000 260,000 84,500 85,500 NE 50 20,000 70,000 6,000,000 4,000,000 40,000 70,000 NE 400 50,000 NE 3,000 6,000 6,900 8,500 25,000 11,700 30,000 70,000 700 NE 28,500 25,000 NE NE NE NE NE NE 15,000 10,000
5/4/1999 6,300 44,000 2,800 18,100 71,200 7.4 3,100 5,500 ------<50 NA <50 NA NA <50 NA NA NA NA NA NA NA <50 NA NA NA 33,000 20,000 5,000 NA NA NA <100 NA
4/11/2000 7,000 37,000 3,300 18,400 65,700 NA 7,600 9,700 ------<0.50 NA <100 NA NA <100 NA NA NA NA NA NA NA <100 NA NA NA NA NA NA NA NA NA NA NA
6/3/2010
8/24/2010
8/25/2010 1,500 62,000 4,500 25,200 93,200 <0.50 5,600 10,000 ------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 550 <0.50 <0.50 94 <0.50 <0.50 <0.50 <0.50 <0.50 2,100 520 NA NA NA NA NA NA 2.6 BJ <2
12/10/2010 8,500 63,000 3,600 21,300 96,400 <0.50 8,600 12,000 ------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 600 <0.50 <0.50 88 <0.50 210 <0.50 <0.50 <0.50 2,200 550 NA NA NA NA NA NA NA NA
5/10/2011 8,600 58,000 3,400 21,300 91,300 <0.50 8,500 12,000 ------<0.50 <0.50 <0.50 <0.50 <0.50 660 <0.50 <0.50 <0.50 76 J <0.50 220 <0.50 <0.50 <0.50 2,000 530 NA NA NA NA NA NA NA NA
10/4/2011 6,700 46,000 2,600 19,500 74,800 <250 5,000 7,700 ------180 BJ <250 <250 <250 <250 <250 <250 <250 <250 <250 <250 <250 <250 290 <250 2,100 480 NA NA NA NA NA NA NA NA
3/7/2012 7,900 49,000 2,800 18,800 78,500 <100 6,700 12,000 ------<100 <100 <100 <100 <100 <100 700 <100 <100 61 J <100 150 <100 <100 <100 1,500 440 NA NA NA NA NA NA NA NA
3/12/2013 2,210 8,340 508 1,882 12,940 <25 1,930 3,220 ------<25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 37.5 <25 <25 <25 86.7 <25 NA NA NA NA NA NA NA NA
1/2/2015 5,800 42,000 3,300 20,900 72,000 <8.9 2,100 3,300 5,000 1,200 --<14 <7.0 <19 <12 <16 <32 <12 <5.4 <8.4 57 <12 170 J <12 <8.0 <12 1,900 400 NA NA NA NA NA NA NA NA
*2/12/2016 5,400 47,000 3,400 17,800 73,600 <250 890 2,600 <25,000 <2,500 --<250 <250 <250 <250 <250 <250 560 <250 <250 70 J <250 200 J <250 <250 <250 1,800 420 NA NA NA NA NA NA NA NA
1/22/2018 2,890 22,900 2,000 10,400 38,190 <13 716 2,360 850 J 433 --<13 35.9 J <13 <13 <20 <20 315 <13 <13 52.0 <13 141 <13 <13 <13 1,200 314 NA NA NA NA NA NA NA NA
11/14/2018 1,800 16,000 1,200 6,700 25,700 <7.4 230 670 <480 170 J <76 <11 <25 <9.7 <8.0 <14 <28 180 <7.5 <6.5 32.0 <7.5 72 <7.5 <14 <11 590 170 NA NA NA NA NA NA NA NA
10/17/2019 624 5,440 774 3,980 10,818 <25.0 73.9 268 NA NA NA <25 <25 <25 <25 <50 <50 207 <25.0 <25.0 32.6 NA <25.0 <25 <25 <25 618 <25.0 NA NA NA NA NA NA NA NA
6/23,29/1999 3.2 16 7.3 46 73 <0.02 <1 4.6 ------<1 NA <1 <1 <1 <1 NA NA NA NA NA NA NA <1 NA NA NA <100 120 210 NA NA NA NA NA
4/11/2000 86 2,500 500 2,900 5,986 <20 <20 <20 ------<20 NA <20 <20 <20 <20 NA NA NA NA NA NA NA <20 NA NA NA NA NA NA NA NA NA NA NA
6/3/2010 0.11 J <0.50 <0.50 0.24 J ---<0.061 380 54 ------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 1.1 <0.50 0.18 J <0.50 600 B 120 B 23 J 380 32,000 5300 NA NA
8/25/2010 0.26 J 0.41 J <0.50 <0.50 ---<0.50 420 54 ------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 1.1 <0.50 <0.50 <0.50 NA NA NA NA NA NA 33 B <2
12/10/2010 <0.50 <0.50 <0.50 <0.50 ---<0.50 530 92 ------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 2.5 1.9 J <0.50 <0.50 <0.50 <0.50 <0.50 1.4 J <0.50 1.7 J <0.50 NA NA NA NA NA NA NA NA
5/10/2011 <0.50 <0.50 <0.50 <0.50 ---<0.50 480 71 ------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 1.1 J <0.50 <0.50 <0.50 NA NA NA NA NA NA NA NA
10/4/2011 0.21 J <1 <1 <1 ---<1 520 70 ------0.36 J <1 <1 <1 <1 1.4 <1 <1 <1 <1 <1 <1 <1 0.95 J 1.3 <1 <1 NA NA NA NA NA NA NA NA
3/7/2012 0.22 J 0.21 J <0.50 0.59 ---<0.50 510 91 ------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.98 0.28 J <0.50 <0.50 <0.50 <0.50 <0.50 1.1 <0.50 <0.50 <0.50 NA NA NA NA NA NA NA NA
1/29/2013
12/31/2014
2/12/2016 <1.0 <1.0 <1.0 <3.0 ---<1.0 20 2.1 470 180 --<1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA NA NA NA NA NA NA NA
1/22/2018
11/14/2018
10/17/2019
6/23,29/1999 1,600 11,000 1,500 5,900 20,000 96 <500 <500 ------<500 NA <500 <500 <500 <500 NA NA NA NA NA NA NA <500 NA NA NA 12,000 8,600 3,700 NA NA NA NA NA
4/11/2000 2,300 20,000 1,600 9,200 33,100 NA <250 290 ------<250 NA <250 <250 <250 <250 NA NA NA NA NA NA NA <250 NA NA NA NA NA NA NA NA NA NA NA
6/3/2010 1,600 7,100 1,000 6,700 16,400 130 16 J 140 ------<20 <0.50 <0.50 <20 <20 <20 230 <20 7.90J 59 <20 64.0 <20 <20 <20 780 260 30,000 B 31,000 B 5,100 200 86 J 1,000 NA NA
8/25/2010 2,400 7,900 1,300 9,100 20,700 150 22 180 ------<20 <0.50 <0.50 <20 <20 <20 240 <20 <20 72 52 <20 <20 <20 <20 970 350 NA NA NA NA NA NA <2 <2
12/1/2010 2,400 9,700 1,000 6,400 19,500 130 23 J 130 ------25 120 81 <25 <25 <25 <25 <25 9.2 J 120 <25 35 <25 <25 <25 670 260 NA NA NA NA NA NA NA NA
5/10/2011 2,200 12,000 1,600 9,200 25,000 150 39 J 220 ------<25 130 63 <25 <25 <25 280 26 J <25 88 26 J 100 <25 <25 <25 910 300 NA NA NA NA NA NA NA NA
10/4/2011 1,400 14,000 1,500 8,800 25,700 110 50 220 ------37 J <50 <50 <50 <50 <50 <50 26 J <50 60 19 J 89 <50 <50 <50 860 250 NA NA NA NA NA NA NA NA
3/7/2012 2,500 17,000 2,000 11,800 33,300 180 66 320 ------<50 <50 92 <50 <50 <50 330 <50 <50 79 19 J 110 <50 <50 <50 1,100 370 NA NA NA NA NA NA NA NA
1/29/2013 269 1,990 426 2,192 4,877 1.9 1.7 19.8 ------<0.50 <0.50 <0.50 1.1 1.3 <0.50 71.2 <0.50 3.7 44 <0.50 48.7 <0.50 <0.50 <0.50 259 105 NA NA NA NA NA NA NA NA
12/31/2014 1,500 8,700 720 4,300 15,220 110 <18 <36 3,300 J <470 --<29 <14 <39 <24 <32 <65 <24 <11 <17 <23 <25 <19 <24 <16 <24 410 <20 NA NA NA NA NA NA NA NA
*2/12/2016 610 2,900 400 2,500 6,410 <20 <20 120 1,200 J <200 --<20 <20 <20 <20 <20 <20 120 12 J <20 30.0 11 J 34 <20 <20 <20 280 120 NA NA NA NA NA NA NA NA
1/22/2018 1,450 8,530 1,110 6,170 17,260 106 26.9 J 153 2,290 894 --<13 <13 <13 <13 <20 <20 216 <13 <13 61.7 <13 81.2 <13 <13 <13 636 211 NA NA NA NA NA NA NA NA
11/14/2018 670 3,500 810 3,400 8,380 44 25 42 800 260 90 J <11 <6.0 <9.7 <8.0 <14 <28 120 22 J 12 J 72 22 J 72 <7.5 <14 <11 520 200 NA NA NA NA NA NA NA NA
10/17/2019 879 2,650 1,050 2,770 7,349 36 17 98.4 NA NA NA <12.5 <12.5 8.3J <12.5 <25 <25 233 <12.5 <12.5 64 NA <12.5 <12.5 <12.5 <12.5 623 <12.5 NA NA NA NA NA NA NA NA
2L Standard
GCL Standard
MW-01R
MW-01
MADEP-EPH
WELL ABANDONED
NOT SAMPLED - WELL DAMAGED
NOT SAMPLED
NOT SAMPLED - WELL DAMAGED
NOT SAMPLED, WELL FILLED WITH SILT
STATESVILLE, IREDELL COUNTY, NORTH CAROLINA 28677
145 EAST BROAD STREET
HODGES EXXON
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
TABLE 5
Analytical Method 3030C
NCDEQ INCIDENT #19688
SM 6200B1, 2 MADEP-VPH
NOT SAMPLED - WELL DAMAGED
MW-03
NOT SAMPLED - WELL DAMAGED
MW-02
Page 6 of 9
Well ID Sample
Date BenzeneTolueneEthylbenzeneTotal XylenesTotal BTEX1,2-Dibromoethane (EDB)*Methyl Tertiary Butyl EtherIsopropyl Ether (IPE)Acetone2-Butanone (MEK)2-Hexanone (MBK)Chloroform2-Chlorotoluene1,2,-DichloroethaneChlorobenzeneChloroethaneChloromethaneNaphthalenen-Butylbenzenesec-ButylbenzeneIsopropylbenzenep-Isopropyltoluenen-PropylbenzeneStyreneTetrachloroethene1,2,3 Trichloropropane1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneC5-C8 AliphaticsC9-C18 AliphaticsC9-C22 AliphaticsC9-C18 AliphaticsC19-C36 AliphaticsC11-C22 AliphaticsLeadChromium1 600 600 500 NE 0.02 20 70 6,000 4,000 40 70 NE 0.4 50 3,000 3 6 70 70 70 25 70 70 0.7 NE 400 400 400 700 200 NE 10,000 NE 15 10
5,000 260,000 84,500 85,500 NE 50 20,000 70,000 6,000,000 4,000,000 40,000 70,000 NE 400 50,000 NE 3,000 6,000 6,900 8,500 25,000 11,700 30,000 70,000 700 NE 28,500 25,000 NE NE NE NE NE NE 15,000 10,000
2L Standard
GCL Standard
MW-01
MADEP-EPH
STATESVILLE, IREDELL COUNTY, NORTH CAROLINA 28677
145 EAST BROAD STREET
HODGES EXXON
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
TABLE 5
Analytical Method 3030C
NCDEQ INCIDENT #19688
SM 6200B1, 2 MADEP-VPH
6/23,29/1999
7/15/1999
4/11/2000
6/3/2010
8/25/2010
12/1/2010 740 64,000 16,000 86,000 166,740 <0.50 <0.50 <0.50 ------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 2,800 <0.50 <0.50 1,100 <0.50 4,100 <0.50 <0.50 <0.50 24,000 7,800 NA NA NA NA NA NA NA NA
5/10/2011 550 48,000 8,400 46,000 102,950 <0.50 <0.50 82 J ------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 1,300 300 73 J 350 53 J 1,300 1,300 <0.50 1,500 8,200 2,400 NA NA NA NA NA NA NA NA
10/4/2011 270 22,000 4,200 23,500 49,970 <100 <100 <100 ------65 BJ <100 <100 <100 <100 <100 48 J 91 J <100 160 <100 440 <100 <100 <100 3,500 950 NA NA NA NA NA NA NA NA
3/7/2012 310 28,000 5,100 30,100 63,510 <100 <100 36 J ------<100 <100 <100 <100 <100 <100 640 <100 <100 170 <100 460 <100 <100 <100 3,900 1,100 NA NA NA NA NA NA NA NA
1/29/2013 171 10,400 2,530 13,990 27,091 <50 <50 <50 ------<50 <50 <50 <50 <50 <50 370 <50 <50 104 <50 307 <50 <50 <50 1,810 392 NA NA NA NA NA NA NA NA
12/31/2014 270 26,000 4,400 35,000 65,670 <44 <45 <90 <2,300 <1,200 --<72 <35 <97 <60 <80 <160 <60 <27 <42 <56 <62 400 J <60 <40 <60 5,100 1,000 NA NA NA NA NA NA NA NA
2/12/2016 130 18,000 4,400 31,000 53,530 <120 <120 <120 <12,000 <1,200 --<120 <120 <120 <120 <120 <120 1,100 100 J <120 170 <120 490 <120 <120 <120 5,500 1,300 NA NA NA NA NA NA NA NA
1/22/2018 31.1 J 5,450 1,540 12,000 19,021 <13 <13 <13 <200 <130 --<13 <13 <13 <13 <20 <20 441 15.1 J <13 73.9 <13 209 <13 <13 <13 2,420 725 NA NA NA NA NA NA NA NA
11/14/2018 <24 1,500 1,500 11,100 14,131 <30 <18 <36 <1,900 <470 <300 <44 <24 <39 <32 <56 <110 450 <30 <26 78 J <30 190 <30 <54 <43 2,000 570 NA NA NA NA NA NA NA NA
10/17/2019 11.0 166 677 7,290 8,164 <10.0 <10.0 <10.0 NA NA NA <10.0 <10.0 <10.0 <10.0 <20.0 <20.0 457 <10 <10 70.4 NA <10.0 <10.0 <10.0 <10.0 1,940 <10.0 NA NA NA NA NA NA NA NA
4/11/2000 <1 <1 <1 <1 ---<1 <1 <0.50 ------1.6 NA <1 <1 <1 <1 NA NA NA NA NA NA NA <1 NA NA NA <100 <100 <100 NA NA NA NA NA
6/3/2010 <0.50 <0.50 <0.50 <0.50 ---<0.50 <0.50 <0.50 ------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <75 18 BJ <25 <110 <110 <110 NA NA
8/25/2010
12/1/2010 <0.50 <0.50 <0.50 <0.50 ---<0.50 <0.50 <0.50 ------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.87 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NA NA NA NA NA NA NA NA
5/10/2011 <0.50 <0.50 <0.50 0.29 J ---<0.50 <0.50 <0.50 ------0.22 J <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NA NA NA NA NA NA NA NA
10/4/2011 <0.50 <0.50 <0.50 <0.50 ---<0.50 <0.50 <0.50 ------0.20 BJ <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NA NA NA NA NA NA NA NA
3/7/2012 <0.50 <0.50 <0.50 <0.50 ---<0.50 <0.50 <0.50 ------0.19 J <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NA NA NA NA NA NA NA NA
1/29/2013 <0.50 <0.50 <0.50 <0.50 ---<0.50 <0.50 <0.50 ------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NA NA NA NA NA NA NA NA
12/31/2014 <0.079 <0.090 <0.092 <0.29 ---<0.089 <0.090 <0.18 <4.7 <2.4 --<0.14 <0.070 <0.19 <0.12 <0.16 <0.32 <0.12 <0.054 <0.084 <0.11 <0.12 <0.094 <0.12 <0.080 <0.12 <0.18 <0.10 NA NA NA NA NA NA NA NA
1/22/2018 <0.13 <0.13 <0.13 <0.25 ---<0.13 <0.13 <0.13 <2.0 <1.3 --<0.13 <0.13 <0.13 <0.13 <0.20 <0.20 0.34 J <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NA NA NA NA NA NA NA NA
11/14/2018 <0.12 0.71 <0.13 0.65 J 1.36 <0.15 <0.090 <0.18 <9.7 <2.4 <1.5 <0.22 <0.12 <0.19 <0.16 <0.28 <0.55 <0.12 <0.15 <0.13 <0.12 <0.15 <0.13 <0.15 <0.27 <0.22 <0.18 <0.13 NA NA NA NA NA NA NA NA
10/17/2019
4/11/2000 <1 <1 <1 <1 ---<1 <1 <1 ------<1 NA <1 <1 <1 <1 NA NA NA NA NA NA NA <1 NA NA NA 150 <100 160 NA NA NA NA NA
6/3/2010 <0.50 <0.50 <0.50 <0.50 ---<0.50 <0.50 <0.50 ------0.21 J <0.50 <0.50 <0.50 <0.50 0.25 J <0.50 0.15 J <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 11 BJ 17 BJ <25 <120 <120 <120 NA NA
8/25/2010
12/1/2010 <0.50 <0.50 <0.50 <0.50 ---<0.50 <0.50 <0.50 ------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NA NA NA NA NA NA NA NA
5/10/2011 <0.50 <0.50 <0.50 0.24 J ---<0.50 <0.50 <0.50 ------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.26 J 0.48 J <0.50 <0.50 <0.50 0.18 J <0.50 <0.50 <0.50 0.28 J 0.22 J NA NA NA NA NA NA NA NA
10/4/2011 <0.50 <0.50 <0.50 <0.50 ---<0.50 <0.50 <0.50 ------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NA NA NA NA NA NA NA NA
3/7/2012 <0.50 <0.50 <0.50 <0.50 ---<0.50 <0.50 <0.50 ------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NA NA NA NA NA NA NA NA
1/29/2013 <0.50 <0.50 <0.50 <0.50 ---<0.50 <0.50 <0.50 ------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NA NA NA NA NA NA NA NA
12/31/2014 <0.079 <0.090 <0.092 <0.29 ---<0.089 <0.090 <0.18 <4.7 <2.4 --<0.14 <0.070 <0.19 <0.12 <0.16 <0.32 <0.12 4.2 1.0 <0.11 1.2 0.21 J <0.12 <0.080 <0.12 1.5 <0.10 NA NA NA NA NA NA NA NA
1/22/2018 <0.13 <0.13 <0.13 <0.25 ---<0.13 <0.13 <0.13 <2.0 <1.3 --<0.13 <0.13 <0.13 <0.13 <0.20 <0.20 0.27 J 5.3 1.4 <0.13 0.67 0.63 <0.13 <0.13 <0.13 0.96 0.83 NA NA NA NA NA NA NA NA
11/14/2018 <0.12 0.39 J <0.13 <0.39 0.39 J <0.15 <0.090 <0.18 <9.7 <2.4 <1.5 <0.22 <0.12 <0.19 <0.16 <0.28 <0.55 <0.12 5.0 0.84 <0.12 0.45 J 0.42 J <0.15 <0.27 <0.22 0.79 0.56 NA NA NA NA NA NA NA NA
10/17/2019
MW-05
MW-06
NOT SAMPLED
NOT SAMPLED - FREE PRODUCT
NOT SAMPLED - FREE PRODUCT
NOT SAMPLED - FREE PRODUCT
NOT SAMPLED
NOT SAMPLED
MW-04
NOT SAMPLED
NOT SAMPLED - FREE PRODUCT
NOT SAMPLED - FREE PRODUCT
Page 7 of 9
Well ID Sample
Date BenzeneTolueneEthylbenzeneTotal XylenesTotal BTEX1,2-Dibromoethane (EDB)*Methyl Tertiary Butyl EtherIsopropyl Ether (IPE)Acetone2-Butanone (MEK)2-Hexanone (MBK)Chloroform2-Chlorotoluene1,2,-DichloroethaneChlorobenzeneChloroethaneChloromethaneNaphthalenen-Butylbenzenesec-ButylbenzeneIsopropylbenzenep-Isopropyltoluenen-PropylbenzeneStyreneTetrachloroethene1,2,3 Trichloropropane1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneC5-C8 AliphaticsC9-C18 AliphaticsC9-C22 AliphaticsC9-C18 AliphaticsC19-C36 AliphaticsC11-C22 AliphaticsLeadChromium1 600 600 500 NE 0.02 20 70 6,000 4,000 40 70 NE 0.4 50 3,000 3 6 70 70 70 25 70 70 0.7 NE 400 400 400 700 200 NE 10,000 NE 15 10
5,000 260,000 84,500 85,500 NE 50 20,000 70,000 6,000,000 4,000,000 40,000 70,000 NE 400 50,000 NE 3,000 6,000 6,900 8,500 25,000 11,700 30,000 70,000 700 NE 28,500 25,000 NE NE NE NE NE NE 15,000 10,000
2L Standard
GCL Standard
MW-01
MADEP-EPH
STATESVILLE, IREDELL COUNTY, NORTH CAROLINA 28677
145 EAST BROAD STREET
HODGES EXXON
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
TABLE 5
Analytical Method 3030C
NCDEQ INCIDENT #19688
SM 6200B1, 2 MADEP-VPH
4/11/2000 460 1,300 160 880 2,800 NA 2,400 940 ------<100 NA <100 <100 <100 <100 NA NA NA NA NA NA NA <100 NA NA NA 2,200 830 750 NA NA NA NA NA
6/3/2010 <0.50 <0.50 <0.50 <0.50 ---<0.50 94 11 ------<0.50 <0.50 <0.50 <0.50 <0.50 0.26 J <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.16 J <0.50 <0.50 <0.50 150 B 14 BJ <25 <100 <110 <110 NA NA
8/25/2010 <0.50 0.22 J <0.50 <0.50 ---<0.50 8.5 <0.50 ------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.39 J <0.50 <0.50 <0.50 NA NA NA NA NA NA <2 <2
12/10/2010 0.18 J 0.69 <0.50 1.0 ---<0.50 34 0.99 ------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 2.1 <0.50 <0.50 <0.50 NA NA NA NA NA NA NA NA
5/10/2011 1.1 8.5 0.28 J 9.5 ---0.061 41 2.4 ------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.26 J <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.26 J <0.50 0.66 0.99 NA NA NA NA NA NA NA NA
10/4/2011 <0.50 <0.50 <0.50 <0.50 ---<0.50 52 1.4 ------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.24 J <0.50 <0.50 <0.50 NA NA NA NA NA NA NA NA
3/7/2012 <0.50 2.4 0.49 J 5.4 ---<0.50 30 0.30 J ------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.61 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.30 J <0.50 1.0 0.39 J NA NA NA NA NA NA NA NA
1/2/2015 <0.079 <0.090 <0.092 <0.29 ---<0.089 0.92 <0.18 370 40 --<0.14 <0.070 <0.19 <0.12 <0.16 <0.32 <0.12 <0.054 <0.084 <0.11 <0.12 <0.094 <0.12 <0.080 <0.12 1.1 <0.10 NA NA NA NA NA NA NA NA
2/12/2016 <0.50 <0.50 <0.50 <1.50 ---<0.50 <0.50 <0.50 43 J <5.0 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NA NA NA NA NA NA NA NA
1/22/2018 <0.13 <0.13 <0.13 <0.25 ---<0.13 0.67 <0.13 83.1 10.5 --<0.13 <0.13 <0.13 <0.13 <0.20 <0.20 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NA NA NA NA NA NA NA NA
11/14/2018 0.41 J 10 5.7 39 55.11 <0.15 0.33 J <0.18 44 J 5.2 <1.5 <0.22 <0.12 <0.19 <0.16 <0.28 <0.55 1.8 <0.15 <0.13 <0.12 <0.15 0.46 J <0.15 <0.27 <0.22 5.2 1.4 NA NA NA NA NA NA NA NA
10/17/2019
6/23,29/1999 <1 <1 <1 <1 ---<0.02 <1 <1 ------<1 NA <50 NA NA <50 NA NA NA NA NA NA NA <1 NA NA NA <100 <100 <100 NA NA NA NA NA
4/11/2000 <1 <1 <1 <1 ---NA <1 <1 ------<1 NA <1 NA NA <1 NA NA NA NA NA NA NA <1 NA NA NA NA NA NA NA NA NA NA NA
6/3/2010 24 25 15 39.2 ---<0.50 12 18 ------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 2.1 1.6 <0.50 0.81 0.39 J 2.3 <0.50 <0.50 <0.50 22 8.7 1,000 B 1,200 B <130 46 J 480 150 NA NA
8/24/2010
Notes:
Concentrations are reported in micrograms per liter (µg/l)
J = Estimated value below method reporting limit
NE = Not Established
Values in BOLD print exceed 2L Standards; values in BOLD and ITALICS exceed Gross Contamination Levels (GCLs)
-- = No information reported for specific compound
1 Samples from 4/11/2000 and earlier, analyzed for volatiles by EPA Method 601/602. Samples collected from MW-1 on 5/4/99 analyzed for EDB by EPA Method 504.1. Analytical results presented in the table.
2 Samples from 6/3/2010 also analyzed by EPA Method 625. EPA Method 625 analytcial results indicated concentrations below method detection limit, except for naphthalene at 200 ug/L in sample MW-3. EPA Method 504.1 analytical results presented in the table.
* = Adventus remedial ORS were installed in MW-1R and MW-03 on August 27, 2015, prior to the February 12, 2016, groundwater monitoring event. The ORS were replaced in each well after sample collection.
NA = not analyzed
NOT SAMPLED
WELL INTERGRITY COMPROMISED, THEREFORE ABANDONED
VW-01
MW-07
Page 8 of 9

FIGURES

SITE
CAD FILE PREP. BYTYPE CODE REV. BY SCALE PROJECT NO.
TITLE
DATE
REFERENCE: USGS 7.5-MINUTE MAP, STATESVILLE
WEST, NORTH CAROLINA. DATED 2016.
LB CH 01/14/20 3
MW-07 MW-04MW-01RMW-03MW-02MW-06MW-05EAST BROAD
STREETEAST BROAD
STREETSOUTH TRADD STREETFORMER HODGE'SEXXONFORMERHEATING OIL USTFORMERDISPENSER ISLANDFORMERUST BASINFIRST CITIZENSBANKBB&T BANKLEGENDMONITORING WELLLOCATIONASSOCIATES OF NORTH CAROLINA, P.C.
[phone] FAX [phone]
PROJECT NO.
Charlotte, North Carolina 28273
NOTES:
DATE
TITLE
SCALEREV. BYPREP. BYCAD FILE
Features shown are not an authoritative location,
nor are they presented to a state of accuracy.
MW-07 MW-04MW-01RMW-03MW-02MW-06MW-05EAST BROAD
STREETEAST BROAD
STREETSOUTH TRADD STREETFORMER HODGE'SEXXONFORMERHEATING OIL USTFORMERDISPENSER ISLANDFORMERUST BASINFIRST CITIZENSBANKBB&T BANKLEGENDMONITORING WELLLOCATIONGROUNDWATERELEVATION IN FEETGROUNDWATERELEVATION CONTOURGROUNDWATER FLOWDIRECTION79.70NOT MEASUREDNMASSOCIATES OF NORTH CAROLINA, P.C.
[phone] FAX [phone]
PROJECT NO.
Charlotte, North Carolina 28273
NOTES:
DATE
TITLE
SCALEREV. BYPREP. BYCAD FILENMNM NM80.9179.1878.7079.0580.079.01.
GROUNDWATER ELEVATIONS MEASURED10/17/19.2.FEARUTES SHOWN ARE NOT AN
AUTHORITATIVE LOCATIUON, NOR ARE
THEY PRESENTED TO A STATE OF
ACCURACY.
MW-07 MW-04MW-01RMW-03MW-02MW-06MW-05EAST BROAD
STREETEAST BROAD STREETSOUTH TRADD STREETFORMER HODGE'SEXXONFORMERHEATING OIL USTFORMERDISPENSER ISLANDFORMERUST BASINFIRST CITIZENSBANKBB&T BANKLEGENDMONITORING WELLLOCATIONASSOCIATES OF NORTH CAROLINA, P.C.
[phone] FAX [phone]
PROJECT NO.
Charlotte, North Carolina 28273
NOTES:
DATE
TITLE
SCALEREV. BYPREP. BYCAD FILE
1.
GROUNDWATER SAMPLES COLLECTED10/17/19
2. CONCENTRATIONS SHOWN EXCEED NC
2L STANDARDS
3. FEATURES SHOWN ARE NOT AN
AUTHORITATIVE LOCATION, NOR ARE
THEY PRESENTED TO A STATE OF
ACCURACY

APPENDIX A

FIELD NOTES

APPENDIX B

LABORATORY ANALYTICAL REPORT
#=CL#
October 24, 2019
LIMS USE: FR - STEVEN FRAMBACH
LIMS OBJECT ID: 92450183
92450183
Project:
Pace Project No.:
RE:
Steven Frambach
ATC Group Services
7606 Whitehall Exec Center Dr
Suite 800
Charlotte, NC 28273
HODGE'S EXXON
Dear Steven Frambach:
Enclosed are the analytical results for sample(s) received by the laboratory on October 17, 2019.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor Ezell
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 25
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92450183
HODGE'S EXXON
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 2 of 25
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92450183
HODGE'S EXXON
Lab ID Sample ID Matrix Date Collected Date Received
92450183001 MW-1R Water 10/17/19 13:15 10/17/19 15:35
92450183002 MW-3 Water 10/17/19 14:05 10/17/19 15:35
92450183003 MW-4 Water 10/17/19 12:00 10/17/19 15:35
92450183004 FB Water 10/17/19 13:30 10/17/19 15:35
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
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[phone]
Page 3 of 25
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92450183
HODGE'S EXXON
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92450183001 MW-1R SM 6200B 63 PASI-CSAS
92450183002 MW-3 SM 6200B 63 PASI-CSAS
92450183003 MW-4 SM 6200B 63 PASI-CSAS
92450183004 FB SM 6200B 63 PASI-CSAS
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
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[phone]
Page 4 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92450183
HODGE'S EXXON
Sample:MW-1R Lab ID:92450183001 Collected:10/17/19 13:15 Received:10/17/19 15:35 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Benzene 624 ug/L 10/23/19 16:54 71-43-225.0 12.0 50
Bromobenzene ND ug/L 10/23/19 16:54 108-86-125.0 10.8 50
Bromochloromethane ND ug/L 10/23/19 16:54 74-97-525.0 12.9 50
Bromodichloromethane ND ug/L 10/23/19 16:54 75-27-425.0 9.2 50
Bromoform ND ug/L 10/23/19 16:54 75-25-225.0 20.2 50
Bromomethane ND ug/L 10/23/19 16:54 74-83-925086.0 50
n-Butylbenzene ND ug/L 10/23/19 16:54 104-51-825.0 17.6 50
sec-Butylbenzene ND ug/L 10/23/19 16:54 135-98-825.0 12.3 50
tert-Butylbenzene ND ug/L 10/23/19 16:54 98-06-625.0 12.5 50
Carbon tetrachloride ND ug/L 10/23/19 16:54 56-23-525.0 11.6 50
Chlorobenzene ND ug/L 10/23/19 16:54 108-90-725.0 11.2 50
Chloroethane ND ug/L 10/23/19 16:54 75-00-350.0 29.2 50
Chloroform ND ug/L 10/23/19 16:54 67-66-325.0 17.6 50
Chloromethane ND ug/L 10/23/19 16:54 74-87-350.0 20.8 50
2-Chlorotoluene ND ug/L 10/23/19 16:54 95-49-825.0 10.4 50
4-Chlorotoluene ND ug/L 10/23/19 16:54 106-43-425.0 10.3 50
1,2-Dibromo-3-chloropropane ND ug/L 10/23/19 16:54 96-12-850.0 19.2 50
Dibromochloromethane ND ug/L 10/23/19 16:54 124-48-125.0 20.1 50
1,2-Dibromoethane (EDB)ND ug/L 10/23/19 16:54 106-93-425.0 11.6 50
Dibromomethane ND ug/L 10/23/19 16:54 74-95-325.0 15.5 50
1,2-Dichlorobenzene ND ug/L 10/23/19 16:54 95-50-125.0 12.0 50
1,3-Dichlorobenzene ND ug/L 10/23/19 16:54 541-73-125.0 12.5 50
1,4-Dichlorobenzene ND ug/L 10/23/19 16:54 106-46-725.0 12.4 50
Dichlorodifluoromethane ND ug/L 10/23/19 16:54 75-71-825.0 14.2 50
1,1-Dichloroethane ND ug/L 10/23/19 16:54 75-34-325.0 12.2 50
1,2-Dichloroethane ND ug/L 10/23/19 16:54 107-06-225.0 13.2 50
1,1-Dichloroethene ND ug/L 10/23/19 16:54 75-35-425.0 10.9 50
cis-1,2-Dichloroethene ND ug/L 10/23/19 16:54 156-59-225.0 10.4 50
trans-1,2-Dichloroethene ND ug/L 10/23/19 16:54 156-60-525.0 12.8 50
1,2-Dichloropropane ND ug/L 10/23/19 16:54 78-87-525.0 9.2 50
1,3-Dichloropropane ND ug/L 10/23/19 16:54 142-28-925.0 17.0 50
2,2-Dichloropropane ND ug/L 10/23/19 16:54 594-20-725.0 14.0 50
1,1-Dichloropropene ND ug/L 10/23/19 16:54 563-58-625.0 17.4 50
cis-1,3-Dichloropropene ND ug/L 10/23/19 16:54 10061-01-525.0 17.8 50
trans-1,3-Dichloropropene ND ug/L 10/23/19 16:54 10061-02-625.0 19.7 50
Diisopropyl ether 268 ug/L 10/23/19 16:54 108-20-325.0 16.7 50
Ethylbenzene 774 ug/L 10/23/19 16:54 100-41-425.0 12.0 50
Hexachloro-1,3-butadiene ND ug/L 10/23/19 16:54 87-68-310060.0 50
Isopropylbenzene (Cumene)32.6 ug/L 10/23/19 16:54 98-82-825.0 11.9 50
Methylene Chloride ND ug/L 10/23/19 16:54 75-09-210075.0 50
Methyl-tert-butyl ether 73.9 ug/L 10/23/19 16:54 1634-04-425.0 22.2 50
Naphthalene 207 ug/L 10/23/19 16:54 91-20-310033.0 50
n-Propylbenzene ND ug/L 10/23/19 16:54 103-65-125.0 12.0 50
Styrene ND ug/L 10/23/19 16:54 100-42-525.0 12.8 50
1,1,1,2-Tetrachloroethane ND ug/L 10/23/19 16:54 630-20-625.0 21.1 50
1,1,2,2-Tetrachloroethane ND ug/L 10/23/19 16:54 79-34-525.0 9.6 50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/24/2019 04:48 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92450183
HODGE'S EXXON
Sample:MW-1R Lab ID:92450183001 Collected:10/17/19 13:15 Received:10/17/19 15:35 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Tetrachloroethene ND ug/L 10/23/19 16:54 127-18-425.0 11.6 50
Toluene 5440 ug/L 10/23/19 16:54 108-88-325.0 11.4 50
1,2,3-Trichlorobenzene ND ug/L 10/23/19 16:54 87-61-610039.0 50
1,2,4-Trichlorobenzene ND ug/L 10/23/19 16:54 120-82-110021.8 50
1,1,1-Trichloroethane ND ug/L 10/23/19 16:54 71-55-625.0 13.9 50
1,1,2-Trichloroethane ND ug/L 10/23/19 16:54 79-00-525.0 11.6 50
Trichloroethene ND ug/L 10/23/19 16:54 79-01-625.0 11.6 50
Trichlorofluoromethane ND ug/L 10/23/19 16:54 75-69-450.0 16.8 50
1,2,3-Trichloropropane ND ug/L 10/23/19 16:54 96-18-425.0 13.6 50
1,2,4-Trimethylbenzene 618 ug/L 10/23/19 16:54 95-63-625.0 9.6 50
1,3,5-Trimethylbenzene ND ug/L 10/23/19 16:54 108-67-825.0 11.4 50
Vinyl chloride ND ug/L 10/23/19 16:54 75-01-450.0 20.4 50
m&p-Xylene 2470 ug/L 10/23/19 16:54 179601-23-150.0 22.0 50
o-Xylene 1510 ug/L 10/23/19 16:54 95-47-625.0 11.8 50
Surrogates
1,2-Dichloroethane-d4 (S)93 %10/23/19 16:54 17060-07-070-130 50
4-Bromofluorobenzene (S)97 %10/23/19 16:54 460-00-470-130 50
Toluene-d8 (S)101 %10/23/19 16:54 2037-26-570-130 50
Sample:MW-3 Lab ID:92450183002 Collected:10/17/19 14:05 Received:10/17/19 15:35 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Benzene 879 ug/L 10/23/19 16:00 71-43-212.5 6.0 25
Bromobenzene ND ug/L 10/23/19 16:00 108-86-112.5 5.4 25
Bromochloromethane ND ug/L 10/23/19 16:00 74-97-512.5 6.4 25
Bromodichloromethane ND ug/L 10/23/19 16:00 75-27-412.5 4.6 25
Bromoform ND ug/L 10/23/19 16:00 75-25-212.5 10.1 25
Bromomethane ND ug/L 10/23/19 16:00 74-83-912543.0 25
n-Butylbenzene ND ug/L 10/23/19 16:00 104-51-812.5 8.8 25
sec-Butylbenzene ND ug/L 10/23/19 16:00 135-98-812.5 6.2 25
tert-Butylbenzene ND ug/L 10/23/19 16:00 98-06-612.5 6.2 25
Carbon tetrachloride ND ug/L 10/23/19 16:00 56-23-512.5 5.8 25
Chlorobenzene ND ug/L 10/23/19 16:00 108-90-712.5 5.6 25
Chloroethane ND ug/L 10/23/19 16:00 75-00-325.0 14.6 25
Chloroform ND ug/L 10/23/19 16:00 67-66-312.5 8.8 25
Chloromethane ND ug/L 10/23/19 16:00 74-87-325.0 10.4 25
2-Chlorotoluene ND ug/L 10/23/19 16:00 95-49-812.5 5.2 25
4-Chlorotoluene ND ug/L 10/23/19 16:00 106-43-412.5 5.2 25
1,2-Dibromo-3-chloropropane ND ug/L 10/23/19 16:00 96-12-825.0 9.6 25
Dibromochloromethane ND ug/L 10/23/19 16:00 124-48-112.5 10.0 25
1,2-Dibromoethane (EDB)35.9 ug/L 10/23/19 16:00 106-93-412.5 5.8 25
Dibromomethane ND ug/L 10/23/19 16:00 74-95-312.5 7.8 25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/24/2019 04:48 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92450183
HODGE'S EXXON
Sample:MW-3 Lab ID:92450183002 Collected:10/17/19 14:05 Received:10/17/19 15:35 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
1,2-Dichlorobenzene ND ug/L 10/23/19 16:00 95-50-112.5 6.0 25
1,3-Dichlorobenzene ND ug/L 10/23/19 16:00 541-73-112.5 6.2 25
1,4-Dichlorobenzene ND ug/L 10/23/19 16:00 106-46-712.5 6.2 25
Dichlorodifluoromethane ND ug/L 10/23/19 16:00 75-71-812.5 7.1 25
1,1-Dichloroethane ND ug/L 10/23/19 16:00 75-34-312.5 6.1 25
1,2-Dichloroethane 8.3J ug/L 10/23/19 16:00 107-06-212.5 6.6 25
1,1-Dichloroethene ND ug/L 10/23/19 16:00 75-35-412.5 5.4 25
cis-1,2-Dichloroethene ND ug/L 10/23/19 16:00 156-59-212.5 5.2 25
trans-1,2-Dichloroethene ND ug/L 10/23/19 16:00 156-60-512.5 6.4 25
1,2-Dichloropropane ND ug/L 10/23/19 16:00 78-87-512.5 4.6 25
1,3-Dichloropropane ND ug/L 10/23/19 16:00 142-28-912.5 8.5 25
2,2-Dichloropropane ND ug/L 10/23/19 16:00 594-20-712.5 7.0 25
1,1-Dichloropropene ND ug/L 10/23/19 16:00 563-58-612.5 8.7 25
cis-1,3-Dichloropropene ND ug/L 10/23/19 16:00 10061-01-512.5 8.9 25
trans-1,3-Dichloropropene ND ug/L 10/23/19 16:00 10061-02-612.5 9.8 25
Diisopropyl ether 98.4 ug/L 10/23/19 16:00 108-20-312.5 8.4 25
Ethylbenzene 1050 ug/L 10/23/19 16:00 100-41-412.5 6.0 25
Hexachloro-1,3-butadiene ND ug/L 10/23/19 16:00 87-68-350.0 30.0 25
Isopropylbenzene (Cumene)63.6 ug/L 10/23/19 16:00 98-82-812.5 6.0 25
Methylene Chloride ND ug/L 10/23/19 16:00 75-09-250.0 37.5 25
Methyl-tert-butyl ether 16.7 ug/L 10/23/19 16:00 1634-04-412.5 11.1 25
Naphthalene 233 ug/L 10/23/19 16:00 91-20-350.0 16.5 25
n-Propylbenzene ND ug/L 10/23/19 16:00 103-65-112.5 6.0 25
Styrene ND ug/L 10/23/19 16:00 100-42-512.5 6.4 25
1,1,1,2-Tetrachloroethane ND ug/L 10/23/19 16:00 630-20-612.5 10.6 25
1,1,2,2-Tetrachloroethane ND ug/L 10/23/19 16:00 79-34-512.5 4.8 25
Tetrachloroethene ND ug/L 10/23/19 16:00 127-18-412.5 5.8 25
Toluene 2650 ug/L 10/23/19 16:00 108-88-312.5 5.7 25
1,2,3-Trichlorobenzene ND ug/L 10/23/19 16:00 87-61-650.0 19.5 25
1,2,4-Trichlorobenzene ND ug/L 10/23/19 16:00 120-82-150.0 10.9 25
1,1,1-Trichloroethane ND ug/L 10/23/19 16:00 71-55-612.5 7.0 25
1,1,2-Trichloroethane ND ug/L 10/23/19 16:00 79-00-512.5 5.8 25
Trichloroethene ND ug/L 10/23/19 16:00 79-01-612.5 5.8 25
Trichlorofluoromethane ND ug/L 10/23/19 16:00 75-69-425.0 8.4 25
1,2,3-Trichloropropane ND ug/L 10/23/19 16:00 96-18-412.5 6.8 25
1,2,4-Trimethylbenzene 623 ug/L 10/23/19 16:00 95-63-612.5 4.8 25
1,3,5-Trimethylbenzene ND ug/L 10/23/19 16:00 108-67-812.5 5.7 25
Vinyl chloride ND ug/L 10/23/19 16:00 75-01-425.0 10.2 25
m&p-Xylene 1670 ug/L 10/23/19 16:00 179601-23-125.0 11.0 25
o-Xylene 1100 ug/L 10/23/19 16:00 95-47-612.5 5.9 25
Surrogates
1,2-Dichloroethane-d4 (S)95 %10/23/19 16:00 17060-07-070-130 25
4-Bromofluorobenzene (S)98 %10/23/19 16:00 460-00-470-130 25
Toluene-d8 (S)100 %10/23/19 16:00 2037-26-570-130 25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/24/2019 04:48 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 7 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92450183
HODGE'S EXXON
Sample:MW-4 Lab ID:92450183003 Collected:10/17/19 12:00 Received:10/17/19 15:35 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Benzene 11.0 ug/L 10/23/19 15:42 71-43-210.0 4.8 20
Bromobenzene ND ug/L 10/23/19 15:42 108-86-110.0 4.3 20
Bromochloromethane ND ug/L 10/23/19 15:42 74-97-510.0 5.2 20
Bromodichloromethane ND ug/L 10/23/19 15:42 75-27-410.0 3.7 20
Bromoform ND ug/L 10/23/19 15:42 75-25-210.0 8.1 20
Bromomethane ND ug/L 10/23/19 15:42 74-83-910034.4 20
n-Butylbenzene ND ug/L 10/23/19 15:42 104-51-810.0 7.1 20
sec-Butylbenzene ND ug/L 10/23/19 15:42 135-98-810.0 4.9 20
tert-Butylbenzene ND ug/L 10/23/19 15:42 98-06-610.0 5.0 20
Carbon tetrachloride ND ug/L 10/23/19 15:42 56-23-510.0 4.6 20
Chlorobenzene ND ug/L 10/23/19 15:42 108-90-710.0 4.5 20
Chloroethane ND ug/L 10/23/19 15:42 75-00-320.0 11.7 20
Chloroform ND ug/L 10/23/19 15:42 67-66-310.0 7.1 20
Chloromethane ND ug/L 10/23/19 15:42 74-87-320.0 8.3 20
2-Chlorotoluene ND ug/L 10/23/19 15:42 95-49-810.0 4.1 20
4-Chlorotoluene ND ug/L 10/23/19 15:42 106-43-410.0 4.1 20
1,2-Dibromo-3-chloropropane ND ug/L 10/23/19 15:42 96-12-820.0 7.7 20
Dibromochloromethane ND ug/L 10/23/19 15:42 124-48-110.0 8.0 20
1,2-Dibromoethane (EDB)ND ug/L 10/23/19 15:42 106-93-410.0 4.6 20
Dibromomethane ND ug/L 10/23/19 15:42 74-95-310.0 6.2 20
1,2-Dichlorobenzene ND ug/L 10/23/19 15:42 95-50-110.0 4.8 20
1,3-Dichlorobenzene ND ug/L 10/23/19 15:42 541-73-110.0 5.0 20
1,4-Dichlorobenzene ND ug/L 10/23/19 15:42 106-46-710.0 5.0 20
Dichlorodifluoromethane ND ug/L 10/23/19 15:42 75-71-810.0 5.7 20
1,1-Dichloroethane ND ug/L 10/23/19 15:42 75-34-310.0 4.9 20
1,2-Dichloroethane ND ug/L 10/23/19 15:42 107-06-210.0 5.3 20
1,1-Dichloroethene ND ug/L 10/23/19 15:42 75-35-410.0 4.4 20
cis-1,2-Dichloroethene ND ug/L 10/23/19 15:42 156-59-210.0 4.1 20
trans-1,2-Dichloroethene ND ug/L 10/23/19 15:42 156-60-510.0 5.1 20
1,2-Dichloropropane ND ug/L 10/23/19 15:42 78-87-510.0 3.7 20
1,3-Dichloropropane ND ug/L 10/23/19 15:42 142-28-910.0 6.8 20
2,2-Dichloropropane ND ug/L 10/23/19 15:42 594-20-710.0 5.6 20
1,1-Dichloropropene ND ug/L 10/23/19 15:42 563-58-610.0 7.0 20
cis-1,3-Dichloropropene ND ug/L 10/23/19 15:42 10061-01-510.0 7.1 20
trans-1,3-Dichloropropene ND ug/L 10/23/19 15:42 10061-02-610.0 7.9 20
Diisopropyl ether ND ug/L 10/23/19 15:42 108-20-310.0 6.7 20
Ethylbenzene 677 ug/L 10/23/19 15:42 100-41-410.0 4.8 20
Hexachloro-1,3-butadiene ND ug/L 10/23/19 15:42 87-68-340.0 24.0 20
Isopropylbenzene (Cumene)70.4 ug/L 10/23/19 15:42 98-82-810.0 4.8 20
Methylene Chloride ND ug/L 10/23/19 15:42 75-09-240.0 30.0 20
Methyl-tert-butyl ether ND ug/L 10/23/19 15:42 1634-04-410.0 8.9 20
Naphthalene 457 ug/L 10/23/19 15:42 91-20-340.0 13.2 20
n-Propylbenzene ND ug/L 10/23/19 15:42 103-65-110.0 4.8 20
Styrene ND ug/L 10/23/19 15:42 100-42-510.0 5.1 20
1,1,1,2-Tetrachloroethane ND ug/L 10/23/19 15:42 630-20-610.0 8.4 20
1,1,2,2-Tetrachloroethane ND ug/L 10/23/19 15:42 79-34-510.0 3.9 20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/24/2019 04:48 PM
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Huntersville, NC 28078
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Page 8 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92450183
HODGE'S EXXON
Sample:MW-4 Lab ID:92450183003 Collected:10/17/19 12:00 Received:10/17/19 15:35 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Tetrachloroethene ND ug/L 10/23/19 15:42 127-18-410.0 4.6 20
Toluene 166 ug/L 10/23/19 15:42 108-88-310.0 4.6 20
1,2,3-Trichlorobenzene ND ug/L 10/23/19 15:42 87-61-640.0 15.6 20
1,2,4-Trichlorobenzene ND ug/L 10/23/19 15:42 120-82-140.0 8.7 20
1,1,1-Trichloroethane ND ug/L 10/23/19 15:42 71-55-610.0 5.6 20
1,1,2-Trichloroethane ND ug/L 10/23/19 15:42 79-00-510.0 4.6 20
Trichloroethene ND ug/L 10/23/19 15:42 79-01-610.0 4.6 20
Trichlorofluoromethane ND ug/L 10/23/19 15:42 75-69-420.0 6.7 20
1,2,3-Trichloropropane ND ug/L 10/23/19 15:42 96-18-410.0 5.4 20
1,2,4-Trimethylbenzene 1940 ug/L 10/23/19 15:42 95-63-610.0 3.9 20
1,3,5-Trimethylbenzene ND ug/L 10/23/19 15:42 108-67-810.0 4.5 20
Vinyl chloride ND ug/L 10/23/19 15:42 75-01-420.0 8.1 20
m&p-Xylene 5090 ug/L 10/23/19 15:42 179601-23-120.0 8.8 20
o-Xylene 2200 ug/L 10/23/19 15:42 95-47-610.0 4.7 20
Surrogates
1,2-Dichloroethane-d4 (S)92 %10/23/19 15:42 17060-07-070-130 20
4-Bromofluorobenzene (S)98 %10/23/19 15:42 460-00-470-130 20
Toluene-d8 (S)103 %10/23/19 15:42 2037-26-570-130 20
Sample:FB Lab ID:92450183004 Collected:10/17/19 13:30 Received:10/17/19 15:35 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 10/22/19 13:12 71-43-20.50 0.25 1
Bromobenzene ND ug/L 10/22/19 13:12 108-86-10.50 0.25 1
Bromochloromethane ND ug/L 10/22/19 13:12 74-97-50.50 0.25 1
Bromodichloromethane ND ug/L 10/22/19 13:12 75-27-40.50 0.25 1
Bromoform ND ug/L 10/22/19 13:12 75-25-20.50 0.25 1
Bromomethane ND ug/L 10/22/19 13:12 74-83-95.0 2.5 1
n-Butylbenzene ND ug/L 10/22/19 13:12 104-51-80.50 0.25 1
sec-Butylbenzene ND ug/L 10/22/19 13:12 135-98-80.50 0.25 1
tert-Butylbenzene ND ug/L 10/22/19 13:12 98-06-60.50 0.25 1
Carbon tetrachloride ND ug/L 10/22/19 13:12 56-23-50.50 0.25 1
Chlorobenzene ND ug/L 10/22/19 13:12 108-90-70.50 0.25 1
Chloroethane ND ug/L 10/22/19 13:12 75-00-31.0 0.50 1
Chloroform ND ug/L 10/22/19 13:12 67-66-35.0 2.5 1
Chloromethane ND ug/L 10/22/19 13:12 74-87-31.0 0.50 1
2-Chlorotoluene ND ug/L 10/22/19 13:12 95-49-80.50 0.25 1
4-Chlorotoluene ND ug/L 10/22/19 13:12 106-43-40.50 0.25 1
1,2-Dibromo-3-chloropropane ND ug/L 10/22/19 13:12 96-12-81.0 0.50 1
Dibromochloromethane ND ug/L 10/22/19 13:12 124-48-10.50 0.25 1
1,2-Dibromoethane (EDB)ND ug/L 10/22/19 13:12 106-93-40.50 0.25 1
Dibromomethane ND ug/L 10/22/19 13:12 74-95-30.50 0.25 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/24/2019 04:48 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92450183
HODGE'S EXXON
Sample:FB Lab ID:92450183004 Collected:10/17/19 13:30 Received:10/17/19 15:35 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
1,2-Dichlorobenzene ND ug/L 10/22/19 13:12 95-50-10.50 0.25 1
1,3-Dichlorobenzene ND ug/L 10/22/19 13:12 541-73-10.50 0.25 1
1,4-Dichlorobenzene ND ug/L 10/22/19 13:12 106-46-70.50 0.25 1
Dichlorodifluoromethane ND ug/L 10/22/19 13:12 75-71-80.50 0.25 1
1,1-Dichloroethane ND ug/L 10/22/19 13:12 75-34-30.50 0.25 1
1,2-Dichloroethane ND ug/L 10/22/19 13:12 107-06-20.50 0.25 1
1,1-Dichloroethene ND ug/L 10/22/19 13:12 75-35-40.50 0.25 1
cis-1,2-Dichloroethene ND ug/L 10/22/19 13:12 156-59-20.50 0.25 1
trans-1,2-Dichloroethene ND ug/L 10/22/19 13:12 156-60-50.50 0.25 1
1,2-Dichloropropane ND ug/L 10/22/19 13:12 78-87-50.50 0.25 1
1,3-Dichloropropane ND ug/L 10/22/19 13:12 142-28-90.50 0.25 1
2,2-Dichloropropane ND ug/L 10/22/19 13:12 594-20-70.50 0.25 1
1,1-Dichloropropene ND ug/L 10/22/19 13:12 563-58-60.50 0.25 1
cis-1,3-Dichloropropene ND ug/L 10/22/19 13:12 10061-01-50.50 0.25 1
trans-1,3-Dichloropropene ND ug/L 10/22/19 13:12 10061-02-60.50 0.25 1
Diisopropyl ether ND ug/L 10/22/19 13:12 108-20-30.50 0.25 1
Ethylbenzene ND ug/L 10/22/19 13:12 100-41-40.50 0.25 1
Hexachloro-1,3-butadiene ND ug/L 10/22/19 13:12 87-68-32.0 1.0 1
Isopropylbenzene (Cumene)ND ug/L 10/22/19 13:12 98-82-80.50 0.25 1
Methylene Chloride 1.2J ug/L 10/22/19 13:12 75-09-2 C92.0 1.0 1
Methyl-tert-butyl ether ND ug/L 10/22/19 13:12 1634-04-40.50 0.25 1
Naphthalene ND ug/L 10/22/19 13:12 91-20-32.0 1.0 1
n-Propylbenzene ND ug/L 10/22/19 13:12 103-65-10.50 0.25 1
Styrene ND ug/L 10/22/19 13:12 100-42-50.50 0.25 1
1,1,1,2-Tetrachloroethane ND ug/L 10/22/19 13:12 630-20-60.50 0.25 1
1,1,2,2-Tetrachloroethane ND ug/L 10/22/19 13:12 79-34-50.50 0.25 1
Tetrachloroethene ND ug/L 10/22/19 13:12 127-18-40.50 0.25 1
Toluene ND ug/L 10/22/19 13:12 108-88-30.50 0.25 1
1,2,3-Trichlorobenzene ND ug/L 10/22/19 13:12 87-61-62.0 1.0 1
1,2,4-Trichlorobenzene ND ug/L 10/22/19 13:12 120-82-12.0 1.0 1
1,1,1-Trichloroethane ND ug/L 10/22/19 13:12 71-55-60.50 0.25 1
1,1,2-Trichloroethane ND ug/L 10/22/19 13:12 79-00-50.50 0.25 1
Trichloroethene ND ug/L 10/22/19 13:12 79-01-60.50 0.25 1
Trichlorofluoromethane ND ug/L 10/22/19 13:12 75-69-41.0 0.50 1
1,2,3-Trichloropropane ND ug/L 10/22/19 13:12 96-18-40.50 0.25 1
1,2,4-Trimethylbenzene ND ug/L 10/22/19 13:12 95-63-60.50 0.25 1
1,3,5-Trimethylbenzene ND ug/L 10/22/19 13:12 108-67-80.50 0.25 1
Vinyl chloride ND ug/L 10/22/19 13:12 75-01-41.0 0.50 1
m&p-Xylene ND ug/L 10/22/19 13:12 179601-23-11.0 0.50 1
o-Xylene ND ug/L 10/22/19 13:12 95-47-60.50 0.25 1
Surrogates
1,2-Dichloroethane-d4 (S)94 %10/22/19 13:12 17060-07-070-130 1
4-Bromofluorobenzene (S)96 %10/22/19 13:12 460-00-470-130 1
Toluene-d8 (S)103 %10/22/19 13:12 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/24/2019 04:48 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450183
HODGE'S EXXON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
504960
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92450183004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2713317
Associated Lab Samples:92450183004
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 0.50 10/22/19 12:360.42
1,1,1-Trichloroethane ug/L ND 0.50 10/22/19 12:360.28
1,1,2,2-Tetrachloroethane ug/L ND 0.50 10/22/19 12:360.19
1,1,2-Trichloroethane ug/L ND 0.50 10/22/19 12:360.23
1,1-Dichloroethane ug/L ND 0.50 10/22/19 12:360.24
1,1-Dichloroethene ug/L ND 0.50 10/22/19 12:360.22
1,1-Dichloropropene ug/L ND 0.50 10/22/19 12:360.35
1,2,3-Trichlorobenzene ug/L ND 2.0 10/22/19 12:360.78
1,2,3-Trichloropropane ug/L ND 0.50 10/22/19 12:360.27
1,2,4-Trichlorobenzene ug/L ND 2.0 10/22/19 12:360.44
1,2,4-Trimethylbenzene ug/L ND 0.50 10/22/19 12:360.19
1,2-Dibromo-3-chloropropane ug/L ND 1.0 10/22/19 12:360.38
1,2-Dibromoethane (EDB)ug/L ND 0.50 10/22/19 12:360.23
1,2-Dichlorobenzene ug/L ND 0.50 10/22/19 12:360.24
1,2-Dichloroethane ug/L ND 0.50 10/22/19 12:360.26
1,2-Dichloropropane ug/L ND 0.50 10/22/19 12:360.18
1,3,5-Trimethylbenzene ug/L ND 0.50 10/22/19 12:360.23
1,3-Dichlorobenzene ug/L ND 0.50 10/22/19 12:360.25
1,3-Dichloropropane ug/L ND 0.50 10/22/19 12:360.34
1,4-Dichlorobenzene ug/L ND 0.50 10/22/19 12:360.25
2,2-Dichloropropane ug/L ND 0.50 10/22/19 12:360.28
2-Chlorotoluene ug/L ND 0.50 10/22/19 12:360.21
4-Chlorotoluene ug/L ND 0.50 10/22/19 12:360.21
Benzene ug/L ND 0.50 10/22/19 12:360.24
Bromobenzene ug/L ND 0.50 10/22/19 12:360.22
Bromochloromethane ug/L ND 0.50 10/22/19 12:360.26
Bromodichloromethane ug/L ND 0.50 10/22/19 12:360.18
Bromoform ug/L ND 0.50 10/22/19 12:360.40
Bromomethane ug/L ND 5.0 10/22/19 12:361.7
Carbon tetrachloride ug/L ND 0.50 10/22/19 12:360.23
Chlorobenzene ug/L ND 0.50 10/22/19 12:360.22
Chloroethane ug/L ND 1.0 10/22/19 12:360.58
Chloroform ug/L ND 0.50 10/22/19 12:360.35
Chloromethane ug/L ND 1.0 10/22/19 12:360.42
cis-1,2-Dichloroethene ug/L ND 0.50 10/22/19 12:360.21
cis-1,3-Dichloropropene ug/L ND 0.50 10/22/19 12:360.36
Dibromochloromethane ug/L ND 0.50 10/22/19 12:360.40
Dibromomethane ug/L ND 0.50 10/22/19 12:360.31
Dichlorodifluoromethane ug/L ND 0.50 10/22/19 12:360.28
Diisopropyl ether ug/L ND 0.50 10/22/19 12:360.33
Ethylbenzene ug/L ND 0.50 10/22/19 12:360.24
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/24/2019 04:48 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450183
HODGE'S EXXON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2713317
Associated Lab Samples:92450183004
Matrix:Water
AnalyzedMDL
Hexachloro-1,3-butadiene ug/L ND 2.0 10/22/19 12:361.2
Isopropylbenzene (Cumene)ug/L ND 0.50 10/22/19 12:360.24
m&p-Xylene ug/L ND 1.0 10/22/19 12:360.44
Methyl-tert-butyl ether ug/L ND 0.50 10/22/19 12:360.44
Methylene Chloride ug/L ND 2.0 10/22/19 12:361.5
n-Butylbenzene ug/L ND 0.50 10/22/19 12:360.35
n-Propylbenzene ug/L ND 0.50 10/22/19 12:360.24
Naphthalene ug/L ND 2.0 10/22/19 12:360.66
o-Xylene ug/L ND 0.50 10/22/19 12:360.24
sec-Butylbenzene ug/L ND 0.50 10/22/19 12:360.25
Styrene ug/L ND 0.50 10/22/19 12:360.26
tert-Butylbenzene ug/L ND 0.50 10/22/19 12:360.25
Tetrachloroethene ug/L ND 0.50 10/22/19 12:360.23
Toluene ug/L ND 0.50 10/22/19 12:360.23
trans-1,2-Dichloroethene ug/L ND 0.50 10/22/19 12:360.26
trans-1,3-Dichloropropene ug/L ND 0.50 10/22/19 12:360.39
Trichloroethene ug/L ND 0.50 10/22/19 12:360.23
Trichlorofluoromethane ug/L ND 1.0 10/22/19 12:360.34
Vinyl chloride ug/L ND 1.0 10/22/19 12:360.41
1,2-Dichloroethane-d4 (S)%97 70-130 10/22/19 12:36
4-Bromofluorobenzene (S)%98 70-130 10/22/19 12:36
Toluene-d8 (S)%100 70-130 10/22/19 12:36
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2713319LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.350 101 60-140
1,1,1-Trichloroethane ug/L 46.250 92 60-140
1,1,2,2-Tetrachloroethane ug/L 50.350 101 60-140
1,1,2-Trichloroethane ug/L 48.850 98 60-140
1,1-Dichloroethane ug/L 47.350 95 60-140
1,1-Dichloroethene ug/L 47.450 95 60-140
1,1-Dichloropropene ug/L 47.850 96 60-140
1,2,3-Trichlorobenzene ug/L 51.550 103 60-140
1,2,3-Trichloropropane ug/L 52.950 106 60-140
1,2,4-Trichlorobenzene ug/L 49.950 100 60-140
1,2,4-Trimethylbenzene ug/L 50.450 101 60-140
1,2-Dibromo-3-chloropropane ug/L 53.550 107 60-140
1,2-Dibromoethane (EDB)ug/L 52.850 106 60-140
1,2-Dichlorobenzene ug/L 50.550 101 60-140
1,2-Dichloroethane ug/L 41.850 84 60-140
1,2-Dichloropropane ug/L 49.450 99 60-140
1,3,5-Trimethylbenzene ug/L 50.950 102 60-140
1,3-Dichlorobenzene ug/L 49.750 99 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/24/2019 04:48 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450183
HODGE'S EXXON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2713319LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichloropropane ug/L 54.050 108 60-140
1,4-Dichlorobenzene ug/L 49.450 99 60-140
2,2-Dichloropropane ug/L 51.350 103 60-140
2-Chlorotoluene ug/L 50.850 102 60-140
4-Chlorotoluene ug/L 50.950 102 60-140
Benzene ug/L 49.750 99 60-140
Bromobenzene ug/L 50.750 101 60-140
Bromochloromethane ug/L 46.950 94 60-140
Bromodichloromethane ug/L 50.650 101 60-140
Bromoform ug/L 51.450 103 60-140
Bromomethane ug/L 51.550 103 60-140
Carbon tetrachloride ug/L 47.450 95 60-140
Chlorobenzene ug/L 49.250 98 60-140
Chloroethane ug/L 40.050 80 60-140
Chloroform ug/L 46.150 92 60-140
Chloromethane ug/L 36.050 72 60-140
cis-1,2-Dichloroethene ug/L 47.450 95 60-140
cis-1,3-Dichloropropene ug/L 54.450 109 60-140
Dibromochloromethane ug/L 52.350 105 60-140
Dibromomethane ug/L 48.950 98 60-140
Dichlorodifluoromethane ug/L 47.950 96 60-140
Diisopropyl ether ug/L 50.450 101 60-140
Ethylbenzene ug/L 50.650 101 60-140
Hexachloro-1,3-butadiene ug/L 51.850 104 60-140
Isopropylbenzene (Cumene)ug/L 51.850 104 60-140
m&p-Xylene ug/L 102100 102 60-140
Methyl-tert-butyl ether ug/L 50.550 101 60-140
Methylene Chloride ug/L 41.350 83 60-140
n-Butylbenzene ug/L 51.950 104 60-140
n-Propylbenzene ug/L 51.750 103 60-140
Naphthalene ug/L 51.650 103 60-140
o-Xylene ug/L 51.950 104 60-140
sec-Butylbenzene ug/L 53.350 107 60-140
Styrene ug/L 50.850 102 60-140
tert-Butylbenzene ug/L 44.550 89 60-140
Tetrachloroethene ug/L 51.150 102 60-140
Toluene ug/L 47.250 94 60-140
trans-1,2-Dichloroethene ug/L 47.850 96 60-140
trans-1,3-Dichloropropene ug/L 51.750 103 60-140
Trichloroethene ug/L 48.650 97 60-140
Trichlorofluoromethane ug/L 44.950 90 60-140
Vinyl chloride ug/L 47.150 94 60-140
1,2-Dichloroethane-d4 (S)%92 70-130
4-Bromofluorobenzene (S)%98 70-130
Toluene-d8 (S)%99 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/24/2019 04:48 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450183
HODGE'S EXXON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2713393MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92449885014
2713394
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 2000 80 60-14081 2 302000ND16001620
1,1,1-Trichloroethane ug/L 2000 77 60-14078 1 302000ND15301560
1,1,2,2-Tetrachloroethane ug/L 2000 83 60-14081 2 302000ND16501630
1,1,2-Trichloroethane ug/L 2000 78 60-14078 1 302000ND15501560
1,1-Dichloroethane ug/L 2000 82 60-14083 1 302000ND16401660
1,1-Dichloroethene ug/L 2000 84 60-14084 0 302000ND16701670
1,1-Dichloropropene ug/L 2000 81 60-14080 0 302000ND16101600
1,2,3-Trichlorobenzene ug/L 2000 69 60-14077 11 302000ND13801540
1,2,3-Trichloropropane ug/L 2000 84 60-14081 4 302000ND16701610
1,2,4-Trichlorobenzene ug/L 2000 72 60-14077 7 302000ND14301530
1,2,4-Trimethylbenzene ug/L 2000 86 60-14087 1 302000144031603180
1,2-Dibromo-3-
chloropropane ug/L 2000 80 60-14083 3 302000ND16001650
1,2-Dibromoethane (EDB)ug/L 2000 83 60-14083 1 302000ND16701650
1,2-Dichlorobenzene ug/L 2000 81 60-14083 3 302000ND16201670
1,2-Dichloroethane ug/L 2000 70 60-14070 1 302000ND14001390
1,2-Dichloropropane ug/L 2000 83 60-14081 2 302000ND16701630
1,3,5-Trimethylbenzene ug/L 2000 99 60-140100 1 302000ND19802000
1,3-Dichlorobenzene ug/L 2000 79 60-14083 5 302000ND15801660
1,3-Dichloropropane ug/L 2000 86 60-14086 1 302000ND17201730
1,4-Dichlorobenzene ug/L 2000 78 60-14080 2 302000ND15601590
2,2-Dichloropropane ug/L 2000 75 60-14075 0 302000ND15001500
2-Chlorotoluene ug/L 2000 84 60-14086 3 302000ND16701720
4-Chlorotoluene ug/L 2000 83 60-14085 2 302000ND16701700
Benzene ug/L 2000 84 60-14092 1 302000103001200012100
Bromobenzene ug/L 2000 83 60-14082 1 302000ND16701650
Bromochloromethane ug/L 2000 78 60-14079 2 302000ND15501580
Bromodichloromethane ug/L 2000 82 60-14082 1 302000ND16501630
Bromoform ug/L 2000 83 60-14078 5 302000ND16501570
Bromomethane ug/L M120005660-14063 12 302000ND11101260
Carbon tetrachloride ug/L 2000 77 60-14078 1 302000ND15401550
Chlorobenzene ug/L 2000 82 60-14081 1 302000ND16401620
Chloroethane ug/L 2000 83 60-14086 4 302000ND16601730
Chloroform ug/L 2000 76 60-14078 3 302000ND15201560
Chloromethane ug/L 2000 65 60-14067 4 302000ND12901340
cis-1,2-Dichloroethene ug/L 2000 82 60-14082 0 302000ND16501650
cis-1,3-Dichloropropene ug/L 2000 86 60-14084 2 302000ND17101680
Dibromochloromethane ug/L 2000 80 60-14082 2 302000ND16001630
Dibromomethane ug/L 2000 80 60-14081 1 302000ND16001610
Dichlorodifluoromethane ug/L 2000 88 60-14084 4 302000ND17701690
Diisopropyl ether ug/L 2000 85 60-14083 1 30200032820201990
Ethylbenzene ug/L 2000 86 60-14084 1 302000228040003960
Hexachloro-1,3-butadiene ug/L 2000 76 60-14079 3 302000ND15301580
Isopropylbenzene(Cumene)ug/L 2000 85 60-14086 1 30200079.5 1780 1800
m&p-Xylene ug/L 4000 86 60-14085 1 304000389073507300
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/24/2019 04:48 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450183
HODGE'S EXXON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2713393MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92449885014
2713394
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methyl-tert-butyl ether ug/L 2000 92 60-14098 2 302000323050705190
Methylene Chloride ug/L 2000 76 60-14075 1 302000ND15101500
n-Butylbenzene ug/L 2000 84 60-14087 3 302000ND16801730
n-Propylbenzene ug/L 2000 93 60-14096 3 302000ND18701930
Naphthalene ug/L 2000 70 60-14075 6 30200038117801880
o-Xylene ug/L 2000 87 60-14087 0 302000116028902900
sec-Butylbenzene ug/L 2000 87 60-14092 5 302000ND17401840
Styrene ug/L 2000 83 60-14082 0 302000ND16501650
tert-Butylbenzene ug/L 2000 74 60-14076 3 302000ND14701520
Tetrachloroethene ug/L 2000 84 60-14081 4 302000ND16901630
Toluene ug/L 2000 75 60-14075 0 302000244039403950
trans-1,2-Dichloroethene ug/L 2000 82 60-14084 2 302000ND16501670
trans-1,3-Dichloropropene ug/L 2000 76 60-14077 1 302000ND15201540
Trichloroethene ug/L 2000 80 60-14079 2 302000ND16101570
Trichlorofluoromethane ug/L 2000 79 60-14079 1 302000ND15901580
Vinyl chloride ug/L 2000 86 60-14088 1 302000ND17301750
1,2-Dichloroethane-d4 (S)%95 70-13092
4-Bromofluorobenzene (S)%100 70-13098
Toluene-d8 (S)%99 70-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/24/2019 04:48 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450183
HODGE'S EXXON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
505219
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92450183001, 92450183002, 92450183003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2714303
Associated Lab Samples:92450183001, 92450183002, 92450183003
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 0.50 10/23/19 10:020.42
1,1,1-Trichloroethane ug/L ND 0.50 10/23/19 10:020.28
1,1,2,2-Tetrachloroethane ug/L ND 0.50 10/23/19 10:020.19
1,1,2-Trichloroethane ug/L ND 0.50 10/23/19 10:020.23
1,1-Dichloroethane ug/L ND 0.50 10/23/19 10:020.24
1,1-Dichloroethene ug/L ND 0.50 10/23/19 10:020.22
1,1-Dichloropropene ug/L ND 0.50 10/23/19 10:020.35
1,2,3-Trichlorobenzene ug/L ND 2.0 10/23/19 10:020.78
1,2,3-Trichloropropane ug/L ND 0.50 10/23/19 10:020.27
1,2,4-Trichlorobenzene ug/L ND 2.0 10/23/19 10:020.44
1,2,4-Trimethylbenzene ug/L ND 0.50 10/23/19 10:020.19
1,2-Dibromo-3-chloropropane ug/L ND 1.0 10/23/19 10:020.38
1,2-Dibromoethane (EDB)ug/L ND 0.50 10/23/19 10:020.23
1,2-Dichlorobenzene ug/L ND 0.50 10/23/19 10:020.24
1,2-Dichloroethane ug/L ND 0.50 10/23/19 10:020.26
1,2-Dichloropropane ug/L ND 0.50 10/23/19 10:020.18
1,3,5-Trimethylbenzene ug/L ND 0.50 10/23/19 10:020.23
1,3-Dichlorobenzene ug/L ND 0.50 10/23/19 10:020.25
1,3-Dichloropropane ug/L ND 0.50 10/23/19 10:020.34
1,4-Dichlorobenzene ug/L ND 0.50 10/23/19 10:020.25
2,2-Dichloropropane ug/L ND 0.50 10/23/19 10:020.28
2-Chlorotoluene ug/L ND 0.50 10/23/19 10:020.21
4-Chlorotoluene ug/L ND 0.50 10/23/19 10:020.21
Benzene ug/L ND 0.50 10/23/19 10:020.24
Bromobenzene ug/L ND 0.50 10/23/19 10:020.22
Bromochloromethane ug/L ND 0.50 10/23/19 10:020.26
Bromodichloromethane ug/L ND 0.50 10/23/19 10:020.18
Bromoform ug/L ND 0.50 10/23/19 10:020.40
Bromomethane ug/L ND 5.0 10/23/19 10:021.7
Carbon tetrachloride ug/L ND 0.50 10/23/19 10:020.23
Chlorobenzene ug/L ND 0.50 10/23/19 10:020.22
Chloroethane ug/L ND 1.0 10/23/19 10:020.58
Chloroform ug/L ND 0.50 10/23/19 10:020.35
Chloromethane ug/L ND 1.0 10/23/19 10:020.42
cis-1,2-Dichloroethene ug/L ND 0.50 10/23/19 10:020.21
cis-1,3-Dichloropropene ug/L ND 0.50 10/23/19 10:020.36
Dibromochloromethane ug/L ND 0.50 10/23/19 10:020.40
Dibromomethane ug/L ND 0.50 10/23/19 10:020.31
Dichlorodifluoromethane ug/L ND 0.50 10/23/19 10:020.28
Diisopropyl ether ug/L ND 0.50 10/23/19 10:020.33
Ethylbenzene ug/L ND 0.50 10/23/19 10:020.24
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/24/2019 04:48 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450183
HODGE'S EXXON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2714303
Associated Lab Samples:92450183001, 92450183002, 92450183003
Matrix:Water
AnalyzedMDL
Hexachloro-1,3-butadiene ug/L ND 2.0 10/23/19 10:021.2
Isopropylbenzene (Cumene)ug/L ND 0.50 10/23/19 10:020.24
m&p-Xylene ug/L ND 1.0 10/23/19 10:020.44
Methyl-tert-butyl ether ug/L ND 0.50 10/23/19 10:020.44
Methylene Chloride ug/L ND 2.0 10/23/19 10:021.5
n-Butylbenzene ug/L ND 0.50 10/23/19 10:020.35
n-Propylbenzene ug/L ND 0.50 10/23/19 10:020.24
Naphthalene ug/L ND 2.0 10/23/19 10:020.66
o-Xylene ug/L ND 0.50 10/23/19 10:020.24
sec-Butylbenzene ug/L ND 0.50 10/23/19 10:020.25
Styrene ug/L ND 0.50 10/23/19 10:020.26
tert-Butylbenzene ug/L ND 0.50 10/23/19 10:020.25
Tetrachloroethene ug/L ND 0.50 10/23/19 10:020.23
Toluene ug/L ND 0.50 10/23/19 10:020.23
trans-1,2-Dichloroethene ug/L ND 0.50 10/23/19 10:020.26
trans-1,3-Dichloropropene ug/L ND 0.50 10/23/19 10:020.39
Trichloroethene ug/L ND 0.50 10/23/19 10:020.23
Trichlorofluoromethane ug/L ND 1.0 10/23/19 10:020.34
Vinyl chloride ug/L ND 1.0 10/23/19 10:020.41
1,2-Dichloroethane-d4 (S)%95 70-130 10/23/19 10:02
4-Bromofluorobenzene (S)%97 70-130 10/23/19 10:02
Toluene-d8 (S)%101 70-130 10/23/19 10:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2714304LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 48.350 97 60-140
1,1,1-Trichloroethane ug/L 47.650 95 60-140
1,1,2,2-Tetrachloroethane ug/L 49.050 98 60-140
1,1,2-Trichloroethane ug/L 49.950 100 60-140
1,1-Dichloroethane ug/L 48.950 98 60-140
1,1-Dichloroethene ug/L 49.150 98 60-140
1,1-Dichloropropene ug/L 47.850 96 60-140
1,2,3-Trichlorobenzene ug/L 49.350 99 60-140
1,2,3-Trichloropropane ug/L 49.150 98 60-140
1,2,4-Trichlorobenzene ug/L 47.750 95 60-140
1,2,4-Trimethylbenzene ug/L 48.450 97 60-140
1,2-Dibromo-3-chloropropane ug/L 49.350 99 60-140
1,2-Dibromoethane (EDB)ug/L 51.250 102 60-140
1,2-Dichlorobenzene ug/L 48.550 97 60-140
1,2-Dichloroethane ug/L 43.250 86 60-140
1,2-Dichloropropane ug/L 52.050 104 60-140
1,3,5-Trimethylbenzene ug/L 48.950 98 60-140
1,3-Dichlorobenzene ug/L 47.950 96 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/24/2019 04:48 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450183
HODGE'S EXXON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2714304LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichloropropane ug/L 52.350 105 60-140
1,4-Dichlorobenzene ug/L 47.150 94 60-140
2,2-Dichloropropane ug/L 51.550 103 60-140
2-Chlorotoluene ug/L 47.650 95 60-140
4-Chlorotoluene ug/L 48.650 97 60-140
Benzene ug/L 51.650 103 60-140
Bromobenzene ug/L 48.650 97 60-140
Bromochloromethane ug/L 48.350 97 60-140
Bromodichloromethane ug/L 50.750 101 60-140
Bromoform ug/L 46.750 93 60-140
Bromomethane ug/L 48.150 96 60-140
Carbon tetrachloride ug/L 47.550 95 60-140
Chlorobenzene ug/L 47.450 95 60-140
Chloroethane ug/L 44.650 89 60-140
Chloroform ug/L 45.950 92 60-140
Chloromethane ug/L 41.050 82 60-140
cis-1,2-Dichloroethene ug/L 49.250 98 60-140
cis-1,3-Dichloropropene ug/L 54.550 109 60-140
Dibromochloromethane ug/L 49.050 98 60-140
Dibromomethane ug/L 51.050 102 60-140
Dichlorodifluoromethane ug/L 49.950 100 60-140
Diisopropyl ether ug/L 51.450 103 60-140
Ethylbenzene ug/L 49.150 98 60-140
Hexachloro-1,3-butadiene ug/L 47.650 95 60-140
Isopropylbenzene (Cumene)ug/L 49.850 100 60-140
m&p-Xylene ug/L 98.1100 98 60-140
Methyl-tert-butyl ether ug/L 50.050 100 60-140
Methylene Chloride ug/L 43.150 86 60-140
n-Butylbenzene ug/L 50.450 101 60-140
n-Propylbenzene ug/L 50.150 100 60-140
Naphthalene ug/L 49.050 98 60-140
o-Xylene ug/L 50.250 100 60-140
sec-Butylbenzene ug/L 51.950 104 60-140
Styrene ug/L 49.050 98 60-140
tert-Butylbenzene ug/L 43.350 87 60-140
Tetrachloroethene ug/L 49.750 99 60-140
Toluene ug/L 49.350 99 60-140
trans-1,2-Dichloroethene ug/L 49.150 98 60-140
trans-1,3-Dichloropropene ug/L 50.150 100 60-140
Trichloroethene ug/L 49.350 99 60-140
Trichlorofluoromethane ug/L 46.050 92 60-140
Vinyl chloride ug/L 50.650 101 60-140
1,2-Dichloroethane-d4 (S)%97 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/24/2019 04:48 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450183
HODGE'S EXXON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2714305MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92450080007
2714306
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 100 103 60-140104 1 30100ND103104
1,1,1-Trichloroethane ug/L 100 105 60-140104 0 30100ND105104
1,1,2,2-Tetrachloroethane ug/L 100 105 60-140105 1 30100ND105105
1,1,2-Trichloroethane ug/L 100 105 60-140109 3 30100ND105109
1,1-Dichloroethane ug/L 100 112 60-140111 1 30100ND112111
1,1-Dichloroethene ug/L 100 112 60-140108 4 30100ND112108
1,1-Dichloropropene ug/L 100 110 60-140107 3 30100ND110107
1,2,3-Trichlorobenzene ug/L 100 97 60-14096 1 30100ND97.2 96.0
1,2,3-Trichloropropane ug/L 100 106 60-140109 3 30100ND106109
1,2,4-Trichlorobenzene ug/L 100 98 60-14096 2 30100ND98.0 96.4
1,2,4-Trimethylbenzene ug/L 100 99 60-14098 1 3010065.5 164 163
1,2-Dibromo-3-
chloropropane ug/L 100 102 60-140105 3 30100ND102105
1,2-Dibromoethane (EDB)ug/L 100 105 60-140107 2 30100ND105107
1,2-Dichlorobenzene ug/L 100 103 60-140102 1 30100ND103102
1,2-Dichloroethane ug/L 100 95 60-14093 3 30100ND95.4 92.9
1,2-Dichloropropane ug/L 100 111 60-140110 1 30100ND111110
1,3,5-Trimethylbenzene ug/L 100 114 60-140113 1 30100ND114113
1,3-Dichlorobenzene ug/L 100 104 60-140101 2 30100ND104101
1,3-Dichloropropane ug/L 100 110 60-140110 0 30100ND110110
1,4-Dichlorobenzene ug/L 100 100 60-14099 1 30100ND10099.1
2,2-Dichloropropane ug/L 100 111 60-140110 0 30100ND111110
2-Chlorotoluene ug/L 100 108 60-140107 1 30100ND108107
4-Chlorotoluene ug/L 100 106 60-140104 2 30100ND106104
Benzene ug/L M11008460-14055 3 30100870953924
Bromobenzene ug/L 100 104 60-140105 1 30100ND104105
Bromochloromethane ug/L 100 103 60-140105 2 30100ND103105
Bromodichloromethane ug/L 100 108 60-140109 1 30100ND108109
Bromoform ug/L 100 105 60-140107 2 30100ND105107
Bromomethane ug/L 100 88 60-14087 1 30100ND87.6 86.7
Carbon tetrachloride ug/L 100 105 60-140103 2 30100ND105103
Chlorobenzene ug/L 100 104 60-140104 0 30100ND104104
Chloroethane ug/L 100 101 60-140103 3 30100ND101103
Chloroform ug/L 100 109 60-140107 2 30100ND109107
Chloromethane ug/L 100 96 60-140100 4 30100ND95.8 99.7
cis-1,2-Dichloroethene ug/L 100 109 60-140109 0 30100ND109109
cis-1,3-Dichloropropene ug/L 100 115 60-140118 3 30100ND115118
Dibromochloromethane ug/L 100 105 60-140105 0 30100ND105105
Dibromomethane ug/L 100 106 60-140106 1 30100ND106106
Dichlorodifluoromethane ug/L 100 96 60-14095 1 30100ND96.3 95.5
Diisopropyl ether ug/L 100 114 60-140116 1 30100ND114116
Ethylbenzene ug/L 100 100 60-14097 1 30100119219216
Hexachloro-1,3-butadiene ug/L 100 102 60-14099 3 30100ND10299.2
Isopropylbenzene(Cumene)ug/L 100 110 60-140108 2 301009.5 119 117
m&p-Xylene ug/L 200 103 60-140100 2 30200137343337
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/24/2019 04:48 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 19 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450183
HODGE'S EXXON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2714305MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92450080007
2714306
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methyl-tert-butyl ether ug/L 100 108 60-140111 3 30100ND108111
Methylene Chloride ug/L 100 99 60-140100 1 30100ND99.1 99.6
n-Butylbenzene ug/L 100 110 60-140108 1 30100ND110108
n-Propylbenzene ug/L 100 105 60-140104 1 3010018.9 124 123
Naphthalene ug/L 100 91 60-14093 2 3010019.8 111 113
o-Xylene ug/L 100 110 60-140108 1 3010013.4 124 122
sec-Butylbenzene ug/L 100 113 60-140112 1 30100ND113112
Styrene ug/L 100 108 60-140106 2 30100ND108106
tert-Butylbenzene ug/L 100 94 60-14093 1 30100ND93.9 92.7
Tetrachloroethene ug/L 100 110 60-140108 2 30100ND110108
Toluene ug/L 100 105 60-140103 1 3010031.7 137 135
trans-1,2-Dichloroethene ug/L 100 111 60-140110 1 30100ND111110
trans-1,3-Dichloropropene ug/L 100 108 60-140108 0 30100ND108108
Trichloroethene ug/L 100 109 60-140108 1 30100ND109108
Trichlorofluoromethane ug/L 100 102 60-140102 0 30100ND102102
Vinyl chloride ug/L 100 114 60-140111 2 30100ND114111
1,2-Dichloroethane-d4 (S)%94 70-13096
4-Bromofluorobenzene (S)%100 70-130100
Toluene-d8 (S)%101 70-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/24/2019 04:48 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 25
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92450183
HODGE'S EXXON
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Common Laboratory Contaminant.C9
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/24/2019 04:48 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 25
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92450183
HODGE'S EXXON
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92450183001 505219MW-1R SM 6200B
92450183002 505219MW-3 SM 6200B
92450183003 505219MW-4 SM 6200B
92450183004 504960FBSM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/24/2019 04:48 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 25
Page 23 of 25
Page 24 of 25
Page 25 of 25

APPENDIX C

MANN-KENDALL TOOLKIT TREND ANALYSIS
Evaluation Date:Job ID:
Facility Name:Constituent:
Conducted By:Concentration Units:ug/L
Sampling Point ID:Benzene Toluene Ethylbenzene Total Xylenes MTBE
Sampling SamplingEventDate
1 8/25/10 1500 62000 4500 25200 5600
2 12/10/10 8500 63000 3600 21300 8600
3 5/10/11 8600 58000 3400 21300 8500
4 10/4/11 6700 46000 2600 19500 5000
5 3/7/12 7900 49000 2800 18800 6700
6 3/12/13 2210 8340 508 1882 1930
7 1/2/15 5800 42000 3300 20900 2100
8 2/12/16 5400 47000 3400 17800 890
9 1/22/18 2890 22900 2000 10400 716
10 11/14/18 1800 16000 1200 6700 230
11 10/17/19 624 5440 774 3980 73.9
12
13
14
15
16
17
18
19
20
Coefficient of Variation:0.64 0.56 0.50 0.53 0.90Mann-Kendall Statistic (S):-27 -39 -32 -40 -45
Confidence Factor:98.0%99.9%99.4%100.0%>99.9%
Concentration Trend:Decreasing Decreasing Decreasing Decreasing Decreasing
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water, 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
MW-01R CONCENTRATION (ug/L)
GSI Environmental Inc., www.gsi-net.com
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
14-Jan-20 NCDEQ Incident 19688
Hodge's Exxon MW-01R
ATC Associates of North Carolina, P.C.
10
100
1000
10000
100000
12/09 04/11 09/12 01/14 06/15 10/16 03/18 07/19 11/20Concentration (ug/L)Sampling Date
Benzene
Toluene
Ethylbenzene
Total Xylenes
MTBE
Evaluation Date:Job ID:
Facility Name:Constituent:
Conducted By:Concentration Units:ug/L
Sampling Point ID:Benzene Toluene Ethylbenzene Total Xylenes EDB
Sampling SamplingEventDate
1 6/23/99 1600 11000 1500 5900 96
2 4/11/00 2300 20000 1600 9200 96
3 6/3/10 1600 7100 1000 6700 130
4 8/25/10 2400 7900 1300 9100 150
5 12/1/10 2400 9700 1000 6400 130
6 5/10/11 2200 12000 1600 9200 150
7 10/4/11 1400 14000 1500 8800 110
8 3/7/12 2500 17000 2000 11800 180
9 1/29/13 269 1990 426 2192 1.9
10 12/31/14 1500 8700 720 4300 110
11 2/12/16 610 2900 400 2500 20
12 1/22/18 1450 8530 1110 6170 106
13 11/14/18 670 3500 810 3400 44
14 10/17/19 879 2650 1050 2770 35.9
15
16
17
18
19
20
Coefficient of Variation:0.48 0.60 0.41 0.48 0.55Mann-Kendall Statistic (S):-35 -31 -26 -32 -23
Confidence Factor:96.9%95.0%91.3%95.5%88.3%
Concentration Trend:Decreasing Prob. Decreasing Prob. Decreasing Decreasing Stable
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water, 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
MW-03 CONCENTRATION (ug/L)
GSI Environmental Inc., www.gsi-net.com
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
14-Jan-20 NCDEQ Incident 19688
Hodge's Exxon MW-03
ATC Associates of North Carolina, P.C.
1
10
100
1000
10000
100000
01/99 09/01 06/04 03/07 12/09 09/12 06/15 03/18 11/20Concentration (ug/L)Sampling Date
Benzene
Toluene
Ethylbenzene
Total Xylenes
EDB
Evaluation Date:Job ID:
Facility Name:Constituent:
Conducted By:Concentration Units:ug/L
Sampling Point ID:Benzene Toluene Ethylbenzene Total Xylenes
Sampling SamplingEventDate
1 12/1/10 740 64000 16000 86000
2 5/10/11 550 48000 8400 46000
3 10/4/11 270 22000 4200 23500
4 3/7/12 310 28000 5100 30100
5 1/29/13 171 10400 2530 13990
6 12/31/14 270 26000 4400 35000
7 2/12/16 130 18000 4400 31000
8 1/22/18 31.1 5450 1540 12000
9 11/14/18 24 1500 1500 11100
10 10/17/19 11 166 677 7290
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:0.95 0.92 0.92 0.79Mann-Kendall Statistic (S):-40 -37 -34 -31
Confidence Factor:>99.9%>99.9%100.0%99.8%
Concentration Trend:Decreasing Decreasing Decreasing Decreasing
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water, 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
MW-04 CONCENTRATION (ug/L)
GSI Environmental Inc., www.gsi-net.com
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
14-Jan-20 NCDEQ Incident 19688
Hodge's Exxon MW-04
ATC Associates of North Carolina, P.C.
1
10
100
1000
10000
100000
07/09 11/10 04/12 08/13 12/14 05/16 09/17 02/19 06/20Concentration (ug/L)Sampling Date
Benzene
Toluene
Ethylbenzene
Total Xylenes