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HomeMy WebLinkAbout20094_Belmont Dyers_Buildings 4-7_VIMS Construction Rev 1_041620_BF Compliance Letter_04.17.2020April 17, 2020 Sent Via E-mail Andi Dirkschneider Vice President – Land Acquisition and Development Brookline Homes, LLC 425 E. Catawba St Belmont, NC 28012 a.dirk@mybrooklinehome.com Subject: Vapor Mitigation Compliance Review Former Belmont Dyers – Brookline Homes Buildings 4 through 7 – Units 53 through 70 Belmont, Gaston County, North Carolina Brownfields Project No. 20094-16-036 Dear Ms. Dirkschneider: The North Carolina Department of Environmental Quality (DEQ) Brownfields Program received and reviewed the VIMS Construction Completion Report – Revision 1 (Report) dated April 16, 2020 prepared by Hart & Hickman, PC for the above referenced Brownfields Property. The Report indicates that the installation of the vapor mitigation system was conducted in accordance with the requirements of the approved Vapor Intrusion Mitigation Plan Revision 1 (Work Plan) dated March 19, 2018, and Request for VIMP Modifications – Revision 2 dated April 14, 2020 (Work Plan Modification). DEQ Brownfields reviewed the analytical data provided in the Report, and evaluated the analytical data using the DEQ Risk Calculator. The results of this evaluation were below the DEQ thresholds for residential use. Based on our evaluation of the available data, the DEQ Brownfields Program has determined that Buildings 4 through 7 as described in the Report are currently in compliance with Land Use Restriction 6.c. of the Notice of Brownfields Property. DEQ Brownfields understands that ongoing monitoring will be conducted in accordance with the approved Work Plan and Work Plan Modification. Ms. Andi Dirkschneider April 17, 2020 Page 2 Please be advised that this review from DEQ Brownfields does not waive any applicable requirement to obtain any necessary permits, licenses or certifications which may be required from other state or local entities. If you have any questions, please feel free to contact me at 919-707-8382, or via e-mail at sarah.hardison@ncdenr.gov. Sincerely, Sarah Hardison Young Project Manager Brownfields Property Management Unit ec: Joselyn Harriger, DEQ Brownfields Kevin Slaughter, DEQ Brownfields Trinh DeSa, Hart & Hickman Brett Lawrence, Hart & Hickman Via Email April 16, 2020 NCDEQ – Division of Waste Management Brownfields Program 1646 Mail Service Center Raleigh, NC 27699-1646 Attn: Ms. Joselyn Harriger, PG Re: VIMS Construction Completion Report – Revision 1 Former Belmont Dyers – Brookline Homes Buildings 4 through 7 – Units 53 through 70 Belmont, Gaston County, North Carolina Brownfields Project No. 20094-16-036 H&H Project No. BKL-001 Dear Joselyn: 1.0 Introduction On behalf of Brookline Homes, LLC, Hart & Hickman, PC (H&H) has prepared this Vapor Intrusion Mitigation System (VIMS) Construction Completion Report for residential townhome structures Buildings 4 through 7, located on the Former Belmont Dyers Brownfields property in Belmont, Gaston County, North Carolina (Site). The Site is part of the North Carolina Department of Environmental Quality (DEQ) Brownfields Program (Brownfields Project No. 20094-16-036). The subject Site is being redeveloped with a residential development known as the Aberfoyle Village (attached single-family townhome units) and Riverside Flats (multi-family apartments) and totals approximately 11 acres which are situated on the western bank of the Catawba River. This letter report summarizes vapor intrusion mitigation system (VIMS) inspections, pre- occupancy testing, and analytical sampling activities associated with the Aberfoyle Village townhome units constructed by Brookline Homes which comprise Building 4 (4 units), Building 5 (6 units), Building 6 (4 units), and Building 7 (4 units). Building 5 is situated on one concrete Ms. Joselyn Harriger, PG April 16, 2020 – Rev 1 Page 2 S:\AAA-Master Projects\Ralph Falls (RPH)\BKL-001 - Belmont Dyers\Occupancy Requests\Buildings 4-7 combined and revised\Revision 1\20094_Belmont Dyers_Buildings 4-7_Request for Occupancy_ Revision 1_041620.docx slab that is approximately 5,400 square feet, while Buildings 4, 6, and 7 are each situated on a concrete slab of approximately 4,100 square feet. The mailing address for each of the townhome units is indicated in the table below. Building Address Residential Unit Building 4 112 Linestowe Drive Unit 67 108 Linestowe Drive Unit 68 104 Linestowe Drive Unit 69 100 Linestowe Drive Unit 70 Building 5 136 Linestowe Drive Unit 61 132 Linestowe Drive Unit 62 128 Linestowe Drive Unit 63 124 Linestowe Drive Unit 64 120 Linestowe Drive Unit 65 116 Linestowe Drive Unit 66 Building 6 152 Linestowe Drive Unit 57 148 Linestowe Drive Unit 58 144 Linestowe Drive Unit 59 140 Linestowe Drive Unit 60 Building 7 168 Linestowe Drive Unit 53 164 Linestowe Drive Unit 54 160 Linestowe Drive Unit 55 156 Linestowe Drive Unit 56 Previously, Request for Occupancy / VIMS Construction Completion reports were submitted to DEQ for Buildings 4 and Buildings 5 & 6. The VIMS Construction Completion Report, dated February 21, 2020, superseded the previous submittals and included DEQ-requested revisions associated with the previous submittals for Buildings 4 through 6 and also included VIMS Ms. Joselyn Harriger, PG April 16, 2020 – Rev 1 Page 3 S:\AAA-Master Projects\Ralph Falls (RPH)\BKL-001 - Belmont Dyers\Occupancy Requests\Buildings 4-7 combined and revised\Revision 1\20094_Belmont Dyers_Buildings 4-7_Request for Occupancy_ Revision 1_041620.docx installation activities associated with Building 7. Additional DEQ comments where received on April 7, 2020, and responses to the comments are included herein this Revision 1 report. H&H conducted the VIMS inspections, pre-occupancy testing, and sampling activities in accordance the DEQ-approved Vapor Intrusion Mitigation Plan (VIMP) Revision 1 dated March 19, 2019, and supplemented by the Request for VIMP Modifications – Revision 2 (VIMP Modifications) dated April 14, 2020,and subsequently approved by DEQ on April 15, 2020. The residential units were recently constructed and are currently owned by Brookline Homes for sale to individual homeowners. There are a total of 14 townhome buildings at the Site, identified as Buildings 1 through 14, and three apartment buildings, identified as Buildings 15 through 17. The apartment buildings were constructed by a separate builder, Mission Properties, LLC. Of these 14 townhome structures vapor mitigation controls were required in the VIMP for four of the buildings, Buildings 4 through 7, located on the southern portion of the Site. Vapor mitigation controls were not required in any other site buildings. Brookline has voluntarily installed sub-slab venting systems in Buildings 8 and 9. A discussion of analytical sampling results of Buildings 8 and 9 will be provided under separate cover. The Former Belmont Dyers Brownfields Site layout and as-built drawings are included as Figures VM-1A through VM-1D in Appendix A. A VIMP Master Summary is included as Table 1. A summary of the VIMS installation inspection, pre-occupancy testing, and analytical sampling activities are provided in the following sections. Based on the results of the inspections, testing, and sampling activities, H&H requests that the DEQ Brownfields Program acknowledge compliance with land use restriction (LUR) No. 6c from the Notice of Brownfields Property for Buildings 4 through 7 (Units 53 through 70). Ms. Joselyn Harriger, PG April 16, 2020 – Rev 1 Page 4 S:\AAA-Master Projects\Ralph Falls (RPH)\BKL-001 - Belmont Dyers\Occupancy Requests\Buildings 4-7 combined and revised\Revision 1\20094_Belmont Dyers_Buildings 4-7_Request for Occupancy_ Revision 1_041620.docx 2.0 VIMS Inspections, Testing, and Sampling During construction activities, H&H conducted VIMS inspections, pre-occupancy testing, and sampling activities which are summarized below in the following sections. The VIMS under Buildings 4 through 7 are comprised of a passive sub-slab vapor extraction system utilizing a vapor vent pipe system and Empire Model TV04G wind driven turbine fans coupled with the Stego Industries, LLC, Stego-Wrap® 15-mil vapor barrier (Stego-Wrap) installed below the concrete slab of each building. Prior to beginning VIMS construction activities, H&H noted that interior monitoring points in the DEQ-approved VIMP were proposed to be placed under the stairwells within tenant living spaces which would be inaccessible during future monitoring activities. For ease of access, the monitoring points were moved from the interior units to a more suitable location at the rear of each unit where they can be easily accessed from an exterior access port during future monitoring activities. The intake of these re-located monitoring points are located approximately 5 ft from the exterior walls. The monitoring point modifications were approved by the engineer-of-record (EOR), a North Carolina Professional Engineer (PE), and the revised locations are documented in the as-built figures (Appendix A). Each townhome building includes interior and exterior units and each unit includes a garage. The garage for the interior units is detached (separated) from the living space of the corresponding townhome. The garage for the exterior units is connected to the living space of the townhome. The separated garges share a roof with the connected garages, but the garages are separated by a thickend slab footer and continuous wall. Each garage is not designed to be an occupied living space and does not contain heating, ventilation, and air conditioning (HVAC) systems. Furthermore, the Aberfoyle Village Homeowner’s Association (HOA) covenant only permits the garage to be used for parking vehicles. Therefore, the garages are not permitted to be used for or converted to a living space. In accordance with the approved VIMP, the garages that are connected to the exterior units, although not conditioned, received the Stego-Wrap vapor barrier and sub-slab Ms. Joselyn Harriger, PG April 16, 2020 – Rev 1 Page 5 S:\AAA-Master Projects\Ralph Falls (RPH)\BKL-001 - Belmont Dyers\Occupancy Requests\Buildings 4-7 combined and revised\Revision 1\20094_Belmont Dyers_Buildings 4-7_Request for Occupancy_ Revision 1_041620.docx vent piping because these garages are connected to living spaces. The approved VIMP did not require a vapor barrier or vent piping installed below the separated garages because these areas do not connect with living spaces. However, in an abundance of caution, Brookline Homes elected to also install the Stego-Wrap vapor barrier below the slabs of the detached garages. The installation of the vapor barrier below the detached garages was approved by the EOR and documented in the as-built figures (Appendix A). 2.1 VIMS Inspections H&H conducted VIMS inspections of Building 4 (July 15, 2019 to October 3, 2019), Building 5 (July 22, 2019 to October 7, 2019), Building 6 (August 12, 2019 to October 14, 2019), and Building 7 (August 12, 2019 to October 24, 2019), during the following four stages of the construction process: 1. after completion of the sub-slab piping and gravel layout (Inspection 1); 2. after placement of the Stego-Wrap vapor barrier on top of the piping layout and gravel layer (Inspection 2); 3. after installation of above-grade riser piping within the townhomes (Inspection 3); and 4. after installation of the fans (Inspection 4). H&H performed inspections as necessary to confirm that the system was properly installed during each of the four phases of VIMS construction. If repairs or corrections to the VIMS were required, follow-up inspections were conducted by H&H to verify the system was properly installed. H&H performed follow-up inspections for VIMS components for Buildings 4, 6, and 7 for the reasons listed below. It was not necessary to perform follow-up inspections for Building 5. Building 4 1) During an inspection (Inspection 1) of Building 4 conducted on July 15, 2019, H&H noted that soil was mixed with the sub-slab gravel. Therefore, H&H requested that soil and fines Ms. Joselyn Harriger, PG April 16, 2020 – Rev 1 Page 6 S:\AAA-Master Projects\Ralph Falls (RPH)\BKL-001 - Belmont Dyers\Occupancy Requests\Buildings 4-7 combined and revised\Revision 1\20094_Belmont Dyers_Buildings 4-7_Request for Occupancy_ Revision 1_041620.docx be removed from the sub-slab gravel. Additionally, H&H noted that solid sections of sub- slab piping did not have the adequate slope to drain water toward the sub-surface. H&H conducted a follow up inspection of Building 4 on July 26, 2019 and confirmed that clean gravel was present below Building 4 and that pipe slope had been corrected. 2) During an inspection (Inspection 2) of Building 4, on July 30, 2019, H&H requested that the builder add additional liner into the attached garages to provide proper overlap and tie- in of the vapor barrier below the garage. This excess was added and the H&H confirmed the vapor barrier installation for the living spaces was properly installed. On August 1, 2019, a follow-up inspection for the vapor barrier of the garage space was conducted and H&H confirmed the vapor barrier was properly installed. 3) During an inspection (Inspection 3) of Building 4 conducted on September 27, 2019, H&H noted that labels were not present on horizontal sections of the riser piping. H&H conducted a follow-up inspection later that day and confirmed that the correct labeling was present on the riser piping. 4) During an inspection (Inspection 4) of Building 4 conducted on September 27, 2019, H&H noted that a reducer was not used to attach the passive ventilator fan. H&H requested installation of a reducer as shown in detail 5 of the VIMP. H&H conducted a follow-up inspection on October 3, 2019 and confirmed that the fan was installed correctly. Building 6 1) During an inspection (Inspection 1) of Building 6 conducted on August 12, 2019, H&H noted that select sections of solid sub-slab VIMS piping should be replaced with slotted piping to provide additional surface area for vapor collection. Additionally, H&H noted that sub-slab portions of each of the monitoring points should be extended so that the monitoring point intake was at least 5 ft from the edge of the building slab. H&H conducted a follow up inspection of Building 6 on August 13, 2019 and confirmed that these portions Ms. Joselyn Harriger, PG April 16, 2020 – Rev 1 Page 7 S:\AAA-Master Projects\Ralph Falls (RPH)\BKL-001 - Belmont Dyers\Occupancy Requests\Buildings 4-7 combined and revised\Revision 1\20094_Belmont Dyers_Buildings 4-7_Request for Occupancy_ Revision 1_041620.docx of the sub-slab solid VIMS piping had been correctly replaced with slotted piping and that monitoring point intakes were at least 5 ft from the edge of the building slab. 2) Following the initial inspection (Inspection 2) of the vapor barrier in Building 6 on August 16, 2019 of the vapor barrier, H&H conducted follow-up vapor barrier inspections for sections of the building on August 14, 20, and 22, 2019. These follow-up inspections were conducted because the vapor barrier was installed in sections for this building. H&H confirmed that the vapor barrier for each building section was properly installed following any necessary repairs. Building 7 1) During an inspection (Inspection 1) of Building 7 conducted on August 12, 2019, H&H noted that sub-slab portions of each of the monitoring points should be extended so that the monitoring point intake was at least 5 ft from the edge of the building slab. Additionally, H&H requested that the slotted piping be extended closer to the thickened slab. H&H’s conducted a follow-up inspection on August 13, 2019 and confirmed that the monitoring point intakes were at least 5 ft from the edge of the building slab, and that slotted piping had been extended closer to the thickened slab. 2) During an inspection (Inspection 2) of Building 7 conducted on August 20, 2019 in the garage spaces, H&H noted the vapor barrier seams needed repairs. H&H conducted a follow-up inspection on August 22, 2019 and confirmed that the repairs were adequate and the vapor barrier in the garage spaces had been properly installed. After completion of inspection and re-inspection activities, H&H concluded that the VIMS within each of the residential units were properly installed by the contractor(s) in general accordance with the DEQ-approved VIMP. VIMS Inspection Logs are included in Appendix B. A photographic log with representative photographs of the VIMS installation are included in Appendix C. Ms. Joselyn Harriger, PG April 16, 2020 – Rev 1 Page 8 S:\AAA-Master Projects\Ralph Falls (RPH)\BKL-001 - Belmont Dyers\Occupancy Requests\Buildings 4-7 combined and revised\Revision 1\20094_Belmont Dyers_Buildings 4-7_Request for Occupancy_ Revision 1_041620.docx 2.2 Pilot Influence Testing H&H conducted “pilot” influence testing on the vent networks installed below the concrete slabs of Buildings 4 through 7 to verify that adequate communication was present between the sub-slab annular space and the VIMS. During influence testing, H&H utilized temporary vapor extraction fans which were attached to the vertical riser pipes. Prior to turning the fans on, vacuum measurements were collected at each monitoring point to establish baseline conditions. After baseline conditions were recorded, the fans were activated. A Dwyer series 475 Mark III Digital manometer (capable of measuring to 0.001 inches of water column [in-WC] or 0.25 Pascals [Pa]) was then connected to each pressure measuring port via Teflon tubing to record differential pressures. H&H collected vacuum measurements at each of the monitoring points for Buildings 4 through 7 over varied time intervals. Building 4 On August 30th and September 3rd, 2019, H&H conducted influence testing on the vent network installed below the concrete slab of Building 4. The results of pilot test activities conducted on August 30, 2019 indicated that monitoring MP-4 was not adequately connected to the sub-slab annular space beneath Building 4. Therefore, under direction of H&H, Brookline Homes subsequently excavated the soil surrounding monitoring point MP-4 from the ground surface to where the piping extends through the concrete slab footer. Once the piping was exposed, it was observed that the ineffective monitoring point pipe had been inadvertently damaged during construction. The monitoring point was then repaired by removing and replacing the damaged portion of the pipe. After the repairs were complete, subsequent pilot testing activities were conducted by H&H on September 3, 2019 at monitoring points MP-4, MP-5, and MP-6. The results indicated that the re- installed monitoring point was repaired and that adequate connectivity was present between the VIMS and the gravel in the area of these monitoring points. Ms. Joselyn Harriger, PG April 16, 2020 – Rev 1 Page 9 S:\AAA-Master Projects\Ralph Falls (RPH)\BKL-001 - Belmont Dyers\Occupancy Requests\Buildings 4-7 combined and revised\Revision 1\20094_Belmont Dyers_Buildings 4-7_Request for Occupancy_ Revision 1_041620.docx Differential pressures measured at the monitoring points ranged from 31 to 46 Pa during the testing which are above the minimum depressurization reading (4 Pa) deemed acceptable by DEQ Brownfields to demonstrate that adequate communication is present between sub-slab annular space and the riser pipes. Building 5 On August 30th and September 3rd, 2019, H&H conducted influence testing on the vent network installed below the concrete slab of Building 5. Differential pressures measured at the monitoring points of Building 5 ranged from 16 to 84 Pa. Influence testing results indicate that differential pressures measured in Building 5 and are above the minimum depressurization reading (4 Pa) deemed acceptable by DEQ Brownfields to demonstrate that adequate communication is present between sub-slab annular space and the riser pipes. Building 6 On September 3rd, 2019, H&H conducted influence testing on the vent network installed below the concrete slab of Building 6. Differential pressures measured at the monitoring points of Building 6 ranged from 22 to 34 Pa. Results of influence testing indicate that differential pressures measured in Building 6 are above the minimum depressurization reading (4 Pa) deemed acceptable by DEQ Brownfields to demonstrate that adequate communication is present between sub-slab annular space and the riser pipes. Building 7 On September 3rd, 2019, H&H conducted influence testing on the vent network installed below the concrete slab of Building 7. Differential pressures measured at the monitoring points of Building 7 ranged from 22 to 39 Pa. Results of influence testing indicate that differential pressures measured in Building 7 are above the minimum depressurization reading (4 Pa) deemed acceptable by DEQ Brownfields to demonstrate that adequate communication is present between sub-slab annular space and the riser pipes. Ms. Joselyn Harriger, PG April 16, 2020 – Rev 1 Page 10 S:\AAA-Master Projects\Ralph Falls (RPH)\BKL-001 - Belmont Dyers\Occupancy Requests\Buildings 4-7 combined and revised\Revision 1\20094_Belmont Dyers_Buildings 4-7_Request for Occupancy_ Revision 1_041620.docx VIMS Pilot Test field logs summarizing vacuum and flow measurements for Buildings 4 through 7 at each vapor extraction point location and differential pressure measurements at each observation point are included in Appendix A. 2.3 Sub-Slab Vapor Sampling In accordance with the VIMP Modifications, H&H collected one sub-slab vapor sample for every two townhome units from below Building 4 (two samples), Building 5 (three samples), Building 6 (two samples), and Building 7 (two samples) to determine if acceptable vapor intrusion risk levels were present below the slab. The table below summarizes the location and date for each of the sub-slab samples. Refer to Figures VM-1A through VM-1D in Appendix A for the monitoring point locations. Building Sample ID Monitoring Point ID Sample Date Building 4 SS-Bld4-MP-3 MP-3 October 4, 2019 SS-Bld4 MP-6* MP-6 Building 5 SS-Bld 5 MP-3 MP-3 October 18, 2019 SS-Bld 5 MP-5* MP-5 SS-BLD 5-MP-8 MP-8 Building 6 SS-Bld 6 MP-3 MP-3 October 25, 2019 SS-Bld 6 MP-6* MP-6 Building 7 SS-Bld 7 MP-3 MP-3 November 1, 2019 SS-Bld 7 MP-6* MP-6 *Indicates duplicate sample collected with the parent sample for QA/QC purposes. H&H also collected duplicate sub-slab samples (DUP-1) along with the MP-6 parent sample for Building 4, with the MP-5 parent sample for Building 5, with the MP-3 parent sample for Building 6, and with the MP-3 parent sample for Building 7 for quality assurance/quality control (QA/QC) purposes. Ms. Joselyn Harriger, PG April 16, 2020 – Rev 1 Page 11 S:\AAA-Master Projects\Ralph Falls (RPH)\BKL-001 - Belmont Dyers\Occupancy Requests\Buildings 4-7 combined and revised\Revision 1\20094_Belmont Dyers_Buildings 4-7_Request for Occupancy_ Revision 1_041620.docx 2.3.1 Sub-Slab Vapor Sampling Procedure H&H collected samples from the vacuum monitoring points in accordance with Division of Waste Management (DWM) Vapor Intrusion (VI) Guidance. A temporary expandable plug was placed within the sample port into the point to create an air-tight seal. Prior to sample collection, H&H conducted a leak test at each vacuum measuring point by placing a shroud around the point and entire sampling train including the Summa canister, regulator, and sampling apparatus. The air within the shroud was saturated with helium gas. Soil gas was then purged from the sampling point with an air pump (Gilian GilAir-3) into a Tedlar® bag. A helium gas detector was used to measure helium concentrations in the shroud and bag. The leak test was considered successful if the helium concentration measured in the soil gas purged from the sampling point was less than 10% of the concentration measured in the shroud. Successful completion of this leak check ensured that short-circuiting at the sample point did not occur and that the data collected accurately represented soil gas concentrations. Sub-Slab Soil Gas Field Forms are included in Appendix A. Following a successful leak check, the sub-slab samples were collected into batch-certified 1-liter or 6-liter stainless steel Summa canisters connected to an airflow regulator preset by the laboratory to collect the sample at a flow rate of approximately 0.1 L/min. Vacuum inside the summa canisters was recorded prior to and following the sampling period to ensure adequate sample volume was collected. The samples were submitted for analysis of full-list volatile organic compounds (VOCs) by EPA Method TO-15 to Con-Test Analytical Laboratory (Con-Test). The laboratory analytical results were compared to the DEQ DWM Residential Sub-Slab and Exterior Soil Gas Screening Levels (SGSLs) dated February 2018. A tabular summary of the sub-slab soil gas analytical results is presented in Table 1. The laboratory analytical report and chain of custody record is provided as Appendix D. After receipt of the data, the detected sub-slab soil gas concentrations were entered in DEQ’s Vapor Intrusion Screening Level (VISL) Soil Gas to Indoor Air Risk Calculator (December 2019 version) to calculate cumulative risks using the compounds detected for each sub-slab sample Ms. Joselyn Harriger, PG April 16, 2020 – Rev 1 Page 12 S:\AAA-Master Projects\Ralph Falls (RPH)\BKL-001 - Belmont Dyers\Occupancy Requests\Buildings 4-7 combined and revised\Revision 1\20094_Belmont Dyers_Buildings 4-7_Request for Occupancy_ Revision 1_041620.docx under a residential use scenario. Copies of the risk calculators are provided in Appendix E and calculated Lifetime Incremental Cancer Risk (LICR) and Hazard Index (HI) values are also included in Table 1. 2.3.2 Sub-Slab Vapor Sampling Results The results of analysis indicate that several VOCs, were detected above laboratory method detection limits (MDLs) at low concentrations in the samples from each of the monitoring points. However, no compounds were detected at concentrations above Residential SGSLs in any of the samples. As a conservative measure, for samples that included a parent and a duplicate sample, the highest concentration of each detected compound was entered into the risk calculators. The calculated LICR and HI for the samples collected from the monitoring points of each building are described below. Building 4 As indicated in Table 1, the calculated LICR for the sample collected from MP-3 was 6.5 x 10-7 and the calculated LICR for the sample collected from MP-6 was 2.3 x 10-7, which are notably below the acceptable risk level of 1 x 10-4. The HI for MP-3 was calculated at 0.023 and the HI for MP-6 was calculated at 0.014, which are notably below the threshold of 1. Therefore, VOC vapor concentrations detected below the slab of Building 4 do not appear to pose an unacceptable risk to future occupants of the residential townhome units. Building 5 The risk calculators indicated the calculated residential LICRs for the samples collected from Building 5 (monitoring points MP-3, MP-5, and MP-8) ranged from 1.4 x 10-8 to 5.5 x 10-7, which are notably below the acceptable risk level of 1 x 10-4. The calculated residential HI for the samples collected from Building 5 ranged from 0.0037 to 0.069, which are notably below the acceptable threshold level of 1. Therefore, the VOC vapor concentrations detected below the slab of Building 5 do not appear to pose an unacceptable risk to future residential occupants of the townhome units. Ms. Joselyn Harriger, PG April 16, 2020 – Rev 1 Page 13 S:\AAA-Master Projects\Ralph Falls (RPH)\BKL-001 - Belmont Dyers\Occupancy Requests\Buildings 4-7 combined and revised\Revision 1\20094_Belmont Dyers_Buildings 4-7_Request for Occupancy_ Revision 1_041620.docx Building 6 As indicated in Table 1, the calculated LICR for MP-3 was 2.2 x 10-9 and the calculated LICR for MP-6 was 1.3 x 10-7, which are notably below the acceptable risk level of 1 x 10-4. The HI for MP-3 was calculated at 0.0026 and the HI for MP-6 was calculated at 0.0022, which are notably below the threshold of 1. Therefore, VOC vapor concentrations detected below the slab of Building 6 do not appear to pose an unacceptable risk to future occupants of the residential townhome units. Building 7 As indicated in Table 1, the calculated LICR for MP-3 was 1.5 x 10-7 and the calculated LICR for MP-6 was 1 x 10-6, which are notably below the acceptable risk level of 1 x 10-4. The HI for MP- 3 was calculated at 0.007 and the HI for MP-6 was calculated at 0.028, which are notably below the threshold of 1. Therefore, VOC vapor concentrations detected below the slab of Building 7 do not appear to pose an unacceptable risk to future occupants of the residential townhome units. Ms. Joselyn Harriger, PG April 16, 2020 – Rev 1 Page 14 S:\AAA-Master Projects\Ralph Falls (RPH)\BKL-001 - Belmont Dyers\Occupancy Requests\Buildings 4-7 combined and revised\Revision 1\20094_Belmont Dyers_Buildings 4-7_Request for Occupancy_ Revision 1_041620.docx 3.0 Summary and Recommendations Based on the results of the recent VIMS inspection, testing, and sampling activities, H&H certifies that the VIMS associated with the Former Belmont Dyers Buildings 4 through 7 (Units 53 through 70) have been properly installed in accordance with the DEQ-approved VIMP and VIMP Modifications. The construction of each VIMS component of the Site buildings are complete. Influence testing verified that there is adequate communication present between sub-slab annular space and the riser pipes. In addition, based upon the sub-slab vapor sampling results, the VOC vapor concentrations detected below the sub-slabs in these buildings do not appear to pose an unacceptable risk to future occupants of the residential structures. Therefore, H&H requests that the DEQ Brownfields Program acknowledge compliance with land use restriction (LUR) No. 6c from the Notice of Brownfields Property for Buildings 4 through 7 (Units 53 through 70). In accordance with VIMP Modifications, sub-slab vapor samples will be collected from Buildings 4 through 7 on an annual basis for the next two years. The samples will be collected at the same frequency, two per Building 4, 6, and 7, and three per Building 5, as the pre-occupancy sampling using the methods described in this report. A report with the post-occupancy sub-slab vapor sampling results and risk calculators will be submitted to DEQ following each sampling event. In addition, in accordance with the VIMP Modifications, inspections of the building foundation and select VIMS components will be conducted on a semi-annual basis for the first year of operation and recorded on the Inspection Form – Vapor Intrusion Mitigation System included in Appendix F. Items observed during the visual inspection that may require repairs will be reported to the Aberfolye Village HOA and subsequent a North Carolina PE. After the first year of operation, a reduced inspection frequency for additional inspections may be evaluated and recommended to DEQ for approval. The inspection forms will be submitted annually to DEQ along with the annual land use restriction update (LURU). Ms. Joselyn Harriger, PG April 16, 2020 – Rev 1 Page 15 S:\AAA-Master Projects\Ralph Falls (RPH)\BKL-001 - Belmont Dyers\Occupancy Requests\Buildings 4-7 combined and revised\Revision 1\20094_Belmont Dyers_Buildings 4-7_Request for Occupancy_ Revision 1_041620.docx If you have any questions or require additional information, please do not hesitate to contact us at 704-586-0007. Sincerely, Hart & Hickman, PC Andrew Besu Assistant Project Geologist Trinh DeSa, PE Brett Lawrence, PG Senior Project Engineer Project Geologist #C1269 – Engineering #245 – Geology Attachments: Table 1 – Vapor Intrusion Mitigation Plan Master Summary Appendix A – Vapor Intrusion Mitigation System Plan As-Built Drawings Figure VM-1A – Building 4 Figure VM-1B – Building 5 Figure VM-1C – Building 6 Figure VM-1D – Building 7 Appendix B – VIMS Inspection Forms and Field Logs Appendix C – Photographic Logs Appendix D – Analytical Laboratory Reports Appendix E – Sub-Slab Soil Gas Risk Calculators Appendix F – Inspection Form – Vapor Intrusion Mitigation System Table 1 Vapor Intrusion Mitigation Plan Master Summary Former Belmont Dyers Brownfields Site Brownfields Project No. 20094-16-036 H&H Project No. BKL-001 Date of Most Recent Update - 1/23/2020 Belmont Dyers Residential Unit Number VIMS Construction Inspection & Completion Sub-grade Piping Vapor Barrier - Stego-Wrap Above-Grade Riser Piping & Labels Fan & Alarm Installation & Operation Influence Test Results Influence Test Completion Date Vacuum Range at Measuring Ports (Pascals) Sub-Slab Sampling Results Sample ID SS-Bld 4-MP-3 SS-Bld 5-MP-3 SS-Bld 5-MP-8 SS-Bld 6-MP-6 SS-Bld 7-MP-6 Sample Date 10/04/19 10/04/19 10/04/19 10/18/2019 10/18/2019 10/25/2019 11/1/2019 11/1/2019 11/1/2019 VOCs by TO-15 (µg/m3)µg/m3 Acetone 82 59 65 14 J 16 J 15 J 140 11 J 12 J 25 3.6 J 6.1 J 18 220,000 Benzene 0.86 0.77 0.81 0.38 J <0.26 <0.26 0.75 <0.26 <0.26 <0.26 0.21 J 0.25 J 0.17 J 120 Benzyl chloride <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.13 <0.13 <0.13 7 Bromodichloromethane <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.25 <0.25 <0.25 25 Bromoform <0.93 <0.93 <0.93 <0.93 <0.93 <0.93 <0.93 <0.93 <0.93 <0.93 <0.47 <0.47 <0.47 850 Bromomethane <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 <0.27 <0.27 <0.27 35 1,3-Butadiene <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.16 <0.16 <0.16 14 2-Butanone (MEK)85 100 110 3.9 J 3.6 J 2.9 J 4.1 J 5.4 J 6.0 J 8.2 J 0.67 J 0.74 J 13 35,000 Carbon Disulfide <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 0.54 J <0.43 <0.43 <0.21 <0.21 <0.21 4,900 Carbon Tetrachloride <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 0.43 J 0.35 J 0.36 J 0.38 J 160 Chlorobenzene <0.45 <0.45 <0.45 <0.45 <0.45 <0.45 <0.45 <0.45 <0.45 <0.45 <0.23 <0.23 <0.23 350 Chloroethane <0.52 <0.52 <0.52 <0.52 <0.52 <0.52 <0.52 <0.52 <0.52 <0.52 <0.26 <0.26 <0.26 70,000 Chloroform <0.36 0.51 J <0.36 0.98 <0.36 <0.36 <0.36 <0.36 <0.36 0.41 J <0.18 0.32 J <0.18 41 Chloromethane 2.9 <0.28 <0.28 <0.28 <0.28 <0.28 <0.28 1.4 1.5 3.0 <0.14 <0.14 <0.14 630 Cyclohexane <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.24 <0.24 <0.24 42,000 Dibromochloromethane <0.57 <0.57 <0.57 <0.57 <0.57 <0.57 <0.57 <0.57 <0.57 <0.57 <0.28 <0.28 <0.28 NS 1,2-Dibromoethane (EDB)<0.60 <0.60 <0.60 <0.60 <0.60 <0.60 <0.60 <0.60 <0.60 <0.60 <0.30 <0.30 <0.30 1.6 1,2-Dichlorobenzene <0.58 <0.58 <0.58 <0.58 <0.58 <0.58 <0.58 <0.58 <0.58 <0.58 <0.29 <0.29 <0.29 1,400 1,3-Dichlorobenzene <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.31 <0.31 <0.31 NS 1,4-Dichlorobenzene <0.73 <0.73 <0.73 <0.73 <0.73 <0.73 <0.73 <0.73 <0.73 <0.73 <0.37 <0.37 <0.37 85 Dichlorodifluoromethane (Freon 12)1.8 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 1.9 1.9 1.9 2.3 <0.21 <0.21 700 1,1-Dichloroethane <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.12 <0.12 <0.12 580 1,2-Dichloroethane <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.15 <0.15 <0.15 36 1,1-Dichloroethylene <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.22 <0.22 <0.22 1,400 cis-1,2-Dichloroethylene <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.16 <0.16 <0.16 NS trans-1,2-Dichloroethylene <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.16 <0.16 <0.16 NS 1,2-Dichloropropane <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.16 <0.16 <0.16 28 cis-1,3-Dichloropropene <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.16 <0.16 <0.16 NS trans-1,3-Dichloropropene <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.17 <0.17 <0.17 NS 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)<0.79 <0.79 <0.79 <0.79 <0.79 <0.79 <0.79 <0.79 <0.79 <0.79 <0.39 <0.39 <0.39 NS 1,4-Dioxane <4.6 <4.6 <4.6 <4.6 <4.6 <4.6 <4.6 <4.6 <4.6 <4.6 <2.3 <2.3 <2.3 190 Ethanol 13 J 14 J 20 <6.7 7.2 J <6.7 35 9.0 J 9.3 J 13 J 6.8 J 10.0 8.8 NS Ethyl Acetate 1.2 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 1.7 1.1 <0.54 <0.27 6.5 <0.27 490 Ethylbenzene 1.1 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.81 0.89 <0.25 370 4-Ethyltoluene <0.60 <0.60 <0.60 <0.60 <0.60 <0.60 <0.60 <0.60 <0.60 <0.60 <0.30 <0.30 <0.30 NS Heptane 0.72 J <0.48 <0.48 <0.48 <0.48 <0.48 1.4 <0.48 <0.48 <0.48 <0.24 <0.24 <0.24 2,800 Hexachlorobutadiene <0.98 <0.98 <0.98 <0.98 <0.98 <0.98 <0.98 <0.98 <0.98 <0.98 <0.49 <0.49 <0.49 43 Hexane <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <0.62 <0.62 <0.62 4,900 2-Hexanone (MBK)<0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.24 <0.24 <0.24 210 Isopropanol 3.1 J <0.90 <0.90 <0.90 <0.90 <0.90 3.1 J 1.7 J 1.4 J 1.7 J <0.45 <0.45 <0.45 1,400 Methyl tert-Butyl Ether (MTBE)<0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.18 <0.18 <0.18 3,600 Methylene Chloride <0.84 <0.84 <0.84 <0.84 <0.84 <0.84 <0.84 <0.84 <0.84 1.8 J <0.42 <0.42 <0.42 4,200 4-Methyl-2-pentanone (MIBK)<0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.21 <0.21 <0.21 21,000 Naphthalene 1.5 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.40 <0.40 2.7 21 Propene <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.32 <0.32 <0.32 21,000 Styrene <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 <0.26 <0.26 <0.26 7,000 1,1,2,2-Tetrachloroethane <0.61 <0.61 <0.61 <0.61 <0.61 <0.61 <0.61 <0.61 <0.61 <0.61 <0.30 <0.30 <0.30 16 Tetrachloroethylene 2.4 12 13 69 4.9 4.7 1.4 0.79 J <0.75 <0.75 2.3 2.4 0.58 J 280 Tetrahydrofuran 48 37 38 9.9 8.7 8.5 <0.59 1.0 1.0 1.7 0.75 0.74 12 14,000 Toluene 5.9 6.9 7.6 2.1 1.3 1.3 5.9 1.0 0.90 0.86 0.91 2.3 2.3 35,000 1,2,4-Trichlorobenzene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.51 <0.51 <0.51 14 1,1,1-Trichloroethane <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.20 <0.20 <0.20 35,000 1,1,2-Trichloroethane <0.45 <0.45 <0.45 <0.45 <0.45 <0.45 <0.45 <0.45 <0.45 <0.45 <0.22 <0.22 <0.22 1.4 Trichloroethylene <0.43 <0.43 <0.43 1.3 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.22 <0.22 <0.22 14 Trichlorofluoromethane (Freon 11)2.5 J 3.8 J 3.6 J 3.2 J 1.3 J 2.0 J 1.7 J 1.7 J 1.7 J 1.2 J 15 15 1.5 J NS 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)<1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <0.58 <0.58 <0.58 35,000 1,2,4-Trimethylbenzene 0.81 J 2.7 1.5 <0.63 <0.63 <0.63 3.3 <0.63 <0.63 <0.63 0.38 J <0.31 2.0 420 1,3,5-Trimethylbenzene <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.31 <0.31 <0.31 420 Vinyl Acetate <0.44 <0.44 <0.44 <0.44 <0.44 <0.44 <0.44 <0.44 <0.44 <0.44 <0.22 <0.22 <0.22 1,400 Vinyl Chloride <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.16 <0.16 <0.16 56 m&p-Xylene 5.0 2.6 2.6 1.1 J <1.00 <1.00 <1.00 <1.0 <1.0 <1.0 3.4 3.6 0.65 J 700 o-Xylene 1.8 <0.54 1.1 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 0.85 0.92 <0.27 700 Risk-Assessment - Soil Gas to Indoor Air Carcinogenic Risk (Resident)6.5 x 10-7 5.5 x 10-7 6.6 x 10-8 1.3 x 10-7 1.0 x 10-6 Hazard Index (Resident)2.3 x 10-2 6.9 x 10-2 4.0 x 10-3 2.2 x 10-3 2.8 x 10-2 Notes: 1) North Carolina Department of Environmental Quality (DEQ) Division of Waste Management (DWM) Residential Sub-Slab and Exterior Soil Gas Screening Levels (SGSLs) (February 2018) µg/m3 = micrograms per cubic meter; NS = Not Specified J = detected concentration is above the laboratory method detection limit, but below the laboratory calibrated reporting limit. Therefore, the reported concentration is an estimated value. Risk assessment for sample SS-Bld 4 MP-6/DUP 1 calculated using the higher of the two concentrations for the parent and duplicate sample. Non-detect concentrations are reported as concentrations less than the laboratory method detection limit (MDL). 3.7 x 10-3 2.6 x 10-3 1.4 x 10-8 SS-Bld 6-MP-3 / DUP-1 10/25/2019 2.2 x 10-9 1.5 x 10-7 7.0 x 10-3 SS-Bld 7-MP3 / DUP-1 Residential SGSL(1)SS-Bld 5-MP-5 / DUP-1 10/18/2019 SS-Bld 4-MP-6 / DUP 1 2.3 x 10-7 1.4 x 10-2 31 - 46 21 - 38 08/30/19 & 09/03/19 09/03/1908/30/19 & 09/03/2019 16 - 84 09/03/19 22 - 34 Yes YesYes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Building 7 Units 53 - 56 Building 5 Units 61 - 66 Building 4 Units 67 - 70 Units 57-60 Building 6 S:\AAA-Master Projects\Ralph Falls (RPH)\BKL-001 - Belmont Dyers\Occupancy RequestsDate: 1/28/2020 Table 1 (Page 1 of 1) Hart Hickman, PC Appendix A Vapor Intrusion Mitigation System Plan As-Built Drawings GARAGEKITCHENMASTER BEDROOMGREAT ROOMDINING ROOMFOYERPOWDERLAUNDRYW.I. CLOSET GARAGEKITCHENMASTER BEDROOMGREAT ROOMDINING ROOMFOYERPOWDERLAUNDRYW.I. CLOSETMASTER BATHFOYERPATIO GARAGEDINING ROOMGREAT ROOMKITCHENPOWDERFOYERPATIOGARAGEDINING ROOMGREAT ROOMKITCHENPOWDERGREAT ROOMOPEN AIR PATIO3" VENT PIPE COLLECTIONSCREEN (TYP. AT SLOTTED PIPE ENDS)4" X 4" X 4" PVCTEE (TYP.)3VM13VM11VM11VM12VM14VM1SEAL VAPOR LINER TOEDGE OF CONCRETESEAL VAPOR LINER TOEDGE OF CONCRETE6VM16VM1SEAL VAPOR LINER TOEDGE OF CONCRETE PERDETAIL 7 (TYPICAL)SEAL VAPOR LINER TOEDGE OF CONCRETE PERDETAIL 7 (TYPICAL)7VM17VM17VM1VM178VM18VM1CONCRETE FOOTERCONCRETE FOOTERCONCRETE FOOTERCONCRETE FOOTERCONCRETE FOOTERCONCRETE FOOTERCONCRETE FOOTERSEPARATEDGARAGE4VM1OPEN AIR PATIOCONCRETE FOOTERCONCRETE FOOTERSHARE ROOFED GARAGES SEPARATED BYTHICKENED FOOTER AND CONTINUOUS WALLSHARE ROOFED GARAGES SEPARATED BYTHICKENED FOOTER AND CONTINUOUS WALLSEPARATEDGARAGEVMS VAPOR LINER AND BASE COURSE (TYP)1VMS SLOTTED COLLECTION PIPE (TYP)2BASE COARSE - CLEAN #57 STONEMIN 4" THICK BENEATH VMS VAPOR LINERVAPOR LINER (SEE SPECIFICATION #1)4" SCH 40 THREADED FLUSH JOINTSLOTTED PVC PIPE (0.020" SLOT WIDTH,1/8" SLOT SPACING)SET WITHIN MIN 4" BASE COURSEVAPOR LINER (SEE SPECIFICATION #1)CONCRETE FLOOR SLABSUBBASESUBBASENTSNTSVM1VM1VMS AT VERTICAL SLAB PENETRATION3NTSVAPOR LINER PENETRATION SEALED TOPIPE PER MANUFACTURER INSTRUCTIONS4" SCH 40 PVC 90DEGREE TEEPOSITION RISER IN STUD WALL/DEAD SPACE3" SCH 40 PVC RISER DUCT PIPE(SEE SPECIFICATION #2)BASE COARSE(SEE SPECIFICATION #1)VM1SOLID TO SLOTTED 4" SCH 40PVC PIPE TRANSITION (SLIP COUPLINGOR THREADED JOINT)VMS TURBINE VENTILATOR FAN & EXHAUST5VM1NTSTURBINE FAN(EMPIRE MODEL TV04G)ELECTRICAL JUNCTION BOX FORFUTURE VACUUM FAN, IF NEEDED(120V, 60 Hz AC REQUIRED)4" X 3" PVC COUPLING3" PVC DUCT PIPE THROUGH ROOFFLASHINGROOFTOPSOLID TO SLOTTED 4" SCH 40PVC PIPE TRANSITION (SLIPCOUPLING OR THREADEDJOINT)ATTIC SPACE4" TO 3" REDUCERGARAGE BLOCK FOUNDATION DETAIL WITH VMS VAPOR LINER6VM1NTS8" BLOCK WALL WITH VACUUM MEASURING POINT7VM1NTSVAPOR LINER PENETRATION SEALEDTO CONCRETE PER MANUFACTURERINSTRUCTIONSBASE COARSE(SEE SPECIFICATION #1)2" PVC 90 DEGREEELBOWOCCUPIED SPACE4" SCH 40 PVC (LENGTHVARIES - REFER TODETAILS A & B)NTSVM1HOUSE/GARAGE PIPIN AT STEP DOWN8STUD WALLBASE COARSE(SEE SPECIFICATION #1)4" SCH 40 PVC4" SCH 40 PVC 45 DEGREE SWEEP4" SLOTTED SCH 40 PVCPIPE (SEE DETAIL 2)PROVIDE PIPE SUPPORT TO PREVENT LOW POINTIN SOLID SECTION OF PIPE. MAINTAIN MINIMUM1% SLOPE TOWARD SLOTTED SECTIONS OF PIPE.(SEE SPECIFICATION #2)VAPOR LINER PENETRATION SEALED TOPIPE PER MANUFACTURERINSTRUCTIONSIRRIGATION BOX OR WATERMETER ENCLOSURE WITHLOCKABLE LIDSECURE PIPE WITHINENCLOSURE TOPREVENT MOVEMENTFABRIC FILTER SOCK OVEREND OF OPEN ENDED PIPEOR VENT CAPWALL SEPARATING GARGAGESVAPOR LINER SEALED TO FOOTER PERMANUFACTURER INSTRUCTIONS WITHDOUBLE-SIDED TAPE ON EITHER TOP ORSIDE OF FOOTER4NTSVM1BRICK OR SIDING EXTERNAL WALL (NOT PRESENT AT ALL LOCATIONS)STUD WALLBASE COARSE(SEE SPECIFICATION #1)VAPOR LINER SEALED TO CONCRETE PERMANUFACTURER INSTRUCTIONS.2" SCH 40 PVC ELBOW2" OPEN ENDED PIPE, PLACED AT AMINIMUM OF 3' FROM EXTERIORTURN-DOWN SLABS2" SOLIDSCH 40 PVCLOCKABLE WEATHERPROOFENCLOSURE ON OUTSIDE OF HOUSEWALL. AFFIX LABEL AT BOX WITH"VAPOR MITIGATION SYSTEM". PLACEREMOVABLE PIPE PLUG AT END OF 2"PIPE.PERMANENT VACUUM MEASURING POINT IN OUTSIDE WALLFABRIC FILTER SOCK OVEREND OF OPEN ENDED PIPEOR VENT CAPINSTALLER SHALL SECURE PIPE TOPREVENT MOVEMENT OR DAMAGE TOTHE PIPE DURING THE CONCRETE POURINTERIOR STAIRWELLAT AREAS WITH MEASURING POINTS,VAPOR LINER EXTENDS BELOW PIPE ANDAND IS SEALED TO PIPE PENETRATIONAND CONCRETE PER MANUFACTURERINSTRUCTIONS18 LINESTOWE DRIVE BELMONT, NORTH CAROLINA ABERFOYLE MILL & VILLAGEVAPOR MITIGATION SYSTEM PLAN - TOWNHOME BUILDING # 4 (UNITS 67, 68, 69, & 70)1" = 10'BROOKLINE HOMES, LLC.WELCOME HOME425 E. CATAWBA STREETBELMONT, NC, 28012OFFICE: 980-277-1322VAPOR MITIGATION PLAN PREPARED BY2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 GeologyPROFESSIONAL APPROVALAS-BUILT FIGUREH&H NO. BKL-001VAPOR INTRUSIONMITIGATIONSYSTEM PLANAPRIL 15, 2020VM-1ASITE LAYOUT1" = 80'LEGENDSOLID 4" DIA SCHEDULE 40 PVC PIPINGSLOTTED 4" DIA SCHEDULE 40 PVC PIPINGEXTENT OF 15-MIL STEGO VAPOR LINER (SEE SPECIFICATION 1)LOCATION OF VERTICAL RISER AND LOCATION OF TURBINE FAN ON ROOFTOPLOCATION OF PRESSURE MEASURING POINT (SEE DETAILS 4 & 7)LOCATION OF SUB-SLAB VAPOR SAMPLEVAPOR MITIGATION SYSTEM (VMS) SPECIFICATIONS1. VMS VAPOR LINER IS STEGO WRAP 15-MIL VAPOR BARRIER MANUFACTURED BY STEGO INDUSTRIES LLC.VAPOR LINER WAS INSTALLED AS SPECIFIED HEREIN AND PER MANUFACTURER INSTALLATION INSTRUCTIONS TOCREATE A CONTINUOUS LINER BELOW FLOOR SLABS LOCATED IN GROUND LEVEL RESIDENTIAL OCCUPIED SPACES.A MINIMUM 4-INCH THICK BASE COURSE CONSISTING OF CLEAN #57 WAS INSTALLED BENEATH THE VMS VAPOR LINER.2. VMS PIPING IS SLOPED A MINIMUM OF 18 UNIT VERTICAL IN 12 UNITS HORIZONTAL (1% SLOPE) TO GRAVITY DRAIN.SOLID SECTIONS OF PIPE ARE POSITIONED TO DRAIN TO SLOTTED SECTIONS. PVC PIPE JOINTS WERE CONNECTEDUSING PVC SOCKET COUPLINGS AND PVC GLUE. SUB-SLAB SLOTTED VAPOR COLLECTION PIPE IS THREADED FLUSHJOINT 3" OR 4" SCH 40 PVC PIPE WITH 0.020" SLOT WIDTH AND 18" SLOT SPACING. ACCESSIBLE ABOVE-SLAB RISERDUCT PIPING IS PERMANENTLY IDENTIFIED BY MEANS OF A TAG OR STENCIL WITH "VAPOR PIPING - CONTACT HOA",OR SIMILAR, WITHIN EACH FLOOR LEVEL AND ABOVE THE ROOF LINE AT INTERVALS OF NO LESS THAN 10-LINEAR FT.3" PVC RISER DUCT PIPING IS INSTALLED TO CONNECT EACH SLAB PENETRATION LOCATION TO A ROOFTOP EXHAUSTDISCHARGE POINT WITH TURBINE FAN (SEE SPECIFICATION #3).3. RISER DUCT PIPING EXTENDS IN A VERTICAL ORIENTATION THROUGH THE BUILDING ROOF AND TERMINATE AMINIMUM OF 2 FT ABOVE THE BUILDING ROOF LINE. A EMPIRE MODEL TV04G TURBINE VENTILATOR FAN IS INSTALLEDON THE EXHAUST DISCHARGE END OF EACH RISER DUCT PIPE. A 4" X 3" PVC ADAPTOR COUPLING IS INSTALLED ATTHE DISCHARGE END OF THE 3" RISER DUCT PIPE AND THE FAN SHALL BE SECURED TO THE PVC IN A VERTICALORIENTATION. EXHAUST DISCHARGE LOCATIONS SHALL BE A MINIMUM OF 10 FT FROM ANY OPERABLE OPENING ORAIR INTAKE INTO THE BUILDING. ELECTRICAL JUNCTION BOXES ARE INSTALLED NEAR THE FAN LOCATIONS IN THEEVENT ELECTRIC FANS NEED TO BE INSTALLED IN THE FUTURE.4. THE VAPOR MITIGATION PLAN IS INTENDED TO BE USED FOR DIRECTION OF VMS COMPONENT INSTALLATION ONLYAND IS NOT INTENDED TO GUIDE CONSTRUCTION OF STRUCTURAL COMPONENTS NOT RELATED TO THE VMS.CONSTRUCTION CONTRACTOR SHALL VERIFY CONSISTENCY OF VMS DETAILS WITH APPLICABLE STRUCTURAL,ARCHITECTURAL, MECHANICAL, AND PLUMBING PLANS AND RESOLVE ANY INCONSISTENCIES PRIOR TO VMSINSTALLATION.BVM1AREA OF VAPOR INTRUSION MITIGATION SYSTEMBUILDING #1BUILDING #2BUILDING #3BUILDING #4(UNITS 70-67)BUILDING #5(UNITS 66-61)BUILDING #6(UNITS 60-57)BUILDING #7(UNITS 56-53)BUILDING #8(UNITS 52-47)BUILDING #9(UNITS 41-46)BUILDING #10BUILDING #11BUILDING #12BUILDING #13BUILDING #14BUILDING #15BUILDING #16BUILDING #17AS-BUILTDRAWINGBUILDING 404/15/20UNIT 70UNIT 69UNIT 68UNIT 67MP-1MP-2MP-3MP-4MP-5MP-6MP-3AREA OF SUB-SLABVENTING SYSTEM(NON-VIMS REQUIRED)REVISION 1S:\AAA-Master Projects\Ralph Falls (RPH)\BKL-001 - Belmont Dyers\Occupancy Requests\Figures\VMP_As-Built_Building 4_10212019.dwg, 4/15/2020 6:24:03 PM, DWG To PDF.pc3 GARAGEKITCHENMASTER BEDROOMGREAT ROOMDINING ROOMFOYERPOWDERLAUNDRYPATIOW.I. CLOSET GARAGEKITCHENMASTER BEDROOMGREAT ROOMDINING ROOMFOYERPOWDERLAUNDRYPATIOW.I. CLOSETMASTER BATHFOYERPATIO GARAGEDINING ROOMGREAT ROOMKITCHENPOWDERFOYERPATIOGARAGEDINING ROOMGREAT ROOMKITCHENPOWDERGREAT ROOMPATIOFOYERPATIOGARAGEDINING ROOMGREAT ROOMKITCHENPOWDERFOYERPATIOGARAGEDINING ROOMGREAT ROOMKITCHENPOWDER1VM13VM11VM13VM13VM13" X 3" X 3" PVC TEE (TYP.)2VM14VM14VM1SEAL VAPOR LINER TOEDGE OF CONCRETESEAL VAPOR LINER TOEDGE OF CONCRETESEPARATED GARAGE6VM16VM1SEAL VAPOR LINER TOEDGE OF CONCRETE PERDETAIL 7 (TYPICAL)SEAL VAPOR LINER TOEDGE OF CONCRETE PERDETAIL 7 (TYPICAL)7VM17VM17VM17VM14VM14VM18VM18VM13" VENT PIPE COLLECTIONSCREEN (TYP. AT SLOTTED PIPE ENDS)SHARE ROOFED GARAGES SEPARATED BYTHICKENED FOOTER AND CONTINUOUS WALLSEPARATED GARAGESEPARATED GARAGESEPARATED GARAGESHARE ROOFED GARAGES SEPARATED BYTHICKENED FOOTER AND CONTINUOUS WALLSHARE ROOFED GARAGES SEPARATED BYTHICKENED FOOTER AND CONTINUOUS WALLVMS VAPOR LINER AND BASE COURSE (TYP)1VMS SLOTTED COLLECTION PIPE (TYP)2BASE COARSE - CLEAN #57 STONEMIN 4" THICK BENEATH VMS VAPOR LINERVAPOR LINER (SEE SPECIFICATION #1)4" SCH 40 THREADED FLUSH JOINTSLOTTED PVC PIPE (0.020" SLOT WIDTH,1/8" SLOT SPACING) WITHIN MIN 4" BASE COURSEVAPOR LINER (SEE SPECIFICATION #1)CONCRETE FLOOR SLABSUBBASESUBBASENTSNTSVM1VM1VMS AT VERTICAL SLAB PENETRATION3NTSVAPOR LINER PENETRATION SEALED TOPIPE PER MANUFACTURER INSTRUCTIONS4" SCH 40 PVC 90DEGREE TEEPOSITION RISER IN STUD WALL/DEAD SPACE3" SCH 40 PVC RISER DUCT PIPE(SEE SPECIFICATION #2)BASE COARSE(SEE SPECIFICATION #1)VM1SOLID TO SLOTTED 4" SCH 40PVC PIPE TRANSITION (SLIP COUPLINGOR THREADED JOINT)VMS TURBINE VENTILATOR FAN & EXHAUST5VM1NTSTURBINE FAN(EMPIRE MODEL TV04G)ELECTRICAL JUNCTION BOX FORFUTURE VACUUM FAN, IF NEEDED(120V, 60 Hz AC REQUIRED)4" X 3" PVC COUPLING3" PVC DUCT PIPE THROUGH ROOFFLASHINGROOFTOPSOLID TO SLOTTED 4" SCH 40PVC PIPE TRANSITION (SLIPCOUPLING OR THREADEDJOINT)ATTIC SPACE4" TO 3" REDUCERGARAGE BLOCK FOUNDATION DETAIL WITH VMS VAPOR LINER6VM1NTS8" BLOCK WALL WITH VACUUM MEASURING POINT7VM1NTSVAPOR LINER PENETRATION SEALEDTO CONCRETE PER MANUFACTURERINSTRUCTIONSBASE COARSE(SEE SPECIFICATION #1)4" SCH 40 PVC (LENGTHVARIES - REFER TODETAILS A & B)NTSVM1HOUSE/GARAGE PIPIN AT STEP DOWN8STUD WALLBASE COARSE(SEE SPECIFICATION #1)4" SCH 40 PVC4" SCH 40 PVC 45 DEGREE SWEEP4" SLOTTED SCH 40 PVCPIPE (SEE DETAIL 2)PROVIDE PIPE SUPPORT TO PREVENT LOW POINTIN SOLID SECTION OF PIPE. MAINTAIN MINIMUM1% SLOPE TOWARD SLOTTED SECTIONS OF PIPE.(SEE SPECIFICATION #2)VAPOR LINER PENETRATION SEALED TOPIPE PER MANUFACTURERINSTRUCTIONSWALL SEPARATING GARGAGES4NTSVM1BRICK OR SIDING EXTERNAL WALL (NOT PRESENT AT ALL LOCATIONS)STUD WALLBASE COARSE(SEE SPECIFICATION #1)VAPOR LINER SEALED TO CONCRETE PERMANUFACTURER INSTRUCTIONS.2" SCH 40 PVC ELBOW2" OPEN ENDED PIPE, PLACED AT AMINIMUM OF 3' FROM EXTERIORTURN-DOWN SLABS2" SOLIDSCH 40 PVCLOCKABLE WEATHERPROOFENCLOSURE ON OUTSIDE OF HOUSEWALL. AFFIX LABEL AT BOX WITH"VAPOR MITIGATION SYSTEM". PLACEREMOVABLE PIPE PLUG AT END OF 2"PIPE.PERMANENT VACUUM MEASURING POINT IN OUTSIDE WALLFABRIC FILTER SOCK OVEREND OF OPEN ENDED PIPEOR VENT CAPINSTALLER SHALL SECURE PIPE TOPREVENT MOVEMENT OR DAMAGE TOTHE PIPE DURING THE CONCRETE POURINTERIOR STAIRWELL2" PVC 90 DEGREEELBOWOCCUPIED SPACEIRRIGATION BOX OR WATERMETER ENCLOSURE WITHLOCKABLE LIDSECURE PIPE WITHINENCLOSURE TOPREVENT MOVEMENTFABRIC FILTER SOCK OVEREND OF OPEN ENDED PIPEOR VENT CAPVAPOR LINER SEALED TO FOOTER PERMANUFACTURER INSTRUCTIONS WITHDOUBLE-SIDED TAPE ON EITHER TOP ORSIDE OF FOOTERAT AREAS WITH MEASURING POINTS,VAPOR LINER EXTENDS BELOW PIPE ANDAND IS SEALED TO PIPE PENETRATIONAND CONCRETE PER MANUFACTURERINSTRUCTIONS18 LINESTOWE DRIVE BELMONT, NORTH CAROLINA ABERFOYLE MILL & VILLAGEVAPOR MITIGATION SYSTEM PLAN - TOWNHOME BUILDING # 5 (UNITS 61, 62, 63, 64, 65, & 66)1" = 10'BROOKLINE HOMES, LLC.WELCOME HOME425 E. CATAWBA STREETBELMONT, NC, 28012OFFICE: 980-277-1322VAPOR MITIGATION PLAN PREPARED BY2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 GeologyPROFESSIONAL APPROVALAS-BUILT DRAWINGH&H NO. BKL-001VAPOR INTRUSIONMITIGATIONSYSTEM PLANAPRIL 15, 2020VM-1BSITE LAYOUT1" = 80'BVM1AREA OF VAPOR INTRUSION MITIGATION SYSTEMBUILDING #1BUILDING #2BUILDING #3BUILDING #4(UNITS 70-67)BUILDING #5(UNITS 66-61)BUILDING #6(UNITS 60-57)BUILDING #7(UNITS 56-53)BUILDING #10BUILDING #11BUILDING #12BUILDING #13BUILDING #14BUILDING #15BUILDING #16BUILDING #17AS-BUILTDRAWINGBUILDING 504/15/20UNIT 66UNIT 65UNIT 64UNIT 63MP-1MP-2MP-3MP-4MP-5MP-6UNIT 62UNIT 61MP-7MP-8BUILDING #8(UNITS 52-47)BUILDING #9(UNITS 41-46)LEGENDSOLID 4" DIA SCHEDULE 40 PVC PIPINGSLOTTED 4" DIA SCHEDULE 40 PVC PIPINGEXTENT OF 15-MIL STEGO VAPOR LINER (SEE SPECIFICATION 1)LOCATION OF VERTICAL RISER AND LOCATION OF TURBINE FAN ON ROOFTOPLOCATION OF PRESSURE MEASURING POINT (SEE DETAILS 4 & 7)LOCATION OF SUB-SLAB VAPOR SAMPLEVAPOR MITIGATION SYSTEM (VMS) SPECIFICATIONS1. VMS VAPOR LINER IS STEGO WRAP 15-MIL VAPOR BARRIER MANUFACTURED BY STEGO INDUSTRIES LLC.VAPOR LINER WAS INSTALLED AS SPECIFIED HEREIN AND PER MANUFACTURER INSTALLATION INSTRUCTIONS TOCREATE A CONTINUOUS LINER BELOW FLOOR SLABS LOCATED IN GROUND LEVEL RESIDENTIAL OCCUPIED SPACES.A MINIMUM 4-INCH THICK BASE COURSE CONSISTING OF CLEAN #57 WAS INSTALLED BENEATH THE VMS VAPOR LINER.2. VMS PIPING IS SLOPED A MINIMUM OF 18 UNIT VERTICAL IN 12 UNITS HORIZONTAL (1% SLOPE) TO GRAVITY DRAIN.SOLID SECTIONS OF PIPE ARE POSITIONED TO DRAIN TO SLOTTED SECTIONS. PVC PIPE JOINTS WERE CONNECTEDUSING PVC SOCKET COUPLINGS AND PVC GLUE. SUB-SLAB SLOTTED VAPOR COLLECTION PIPE IS THREADED FLUSHJOINT 3" OR 4" SCH 40 PVC PIPE WITH 0.020" SLOT WIDTH AND 18" SLOT SPACING. ACCESSIBLE ABOVE-SLAB RISERDUCT PIPING IS PERMANENTLY IDENTIFIED BY MEANS OF A TAG OR STENCIL WITH "VAPOR PIPING - CONTACT HOA",OR SIMILAR, WITHIN EACH FLOOR LEVEL AND ABOVE THE ROOF LINE AT INTERVALS OF NO LESS THAN 10-LINEAR FT.3" PVC RISER DUCT PIPING IS INSTALLED TO CONNECT EACH SLAB PENETRATION LOCATION TO A ROOFTOP EXHAUSTDISCHARGE POINT WITH TURBINE FAN (SEE SPECIFICATION #3).3. RISER DUCT PIPING EXTENDS IN A VERTICAL ORIENTATION THROUGH THE BUILDING ROOF AND TERMINATE AMINIMUM OF 2 FT ABOVE THE BUILDING ROOF LINE. A EMPIRE MODEL TV04G TURBINE VENTILATOR FAN IS INSTALLEDON THE EXHAUST DISCHARGE END OF EACH RISER DUCT PIPE. A 4" X 3" PVC ADAPTOR COUPLING IS INSTALLED ATTHE DISCHARGE END OF THE 3" RISER DUCT PIPE AND THE FAN SHALL BE SECURED TO THE PVC IN A VERTICALORIENTATION. EXHAUST DISCHARGE LOCATIONS SHALL BE A MINIMUM OF 10 FT FROM ANY OPERABLE OPENING ORAIR INTAKE INTO THE BUILDING. ELECTRICAL JUNCTION BOXES ARE INSTALLED NEAR THE FAN LOCATIONS IN THEEVENT ELECTRIC FANS NEED TO BE INSTALLED IN THE FUTURE.4. THE VAPOR MITIGATION PLAN IS INTENDED TO BE USED FOR DIRECTION OF VMS COMPONENT INSTALLATION ONLYAND IS NOT INTENDED TO GUIDE CONSTRUCTION OF STRUCTURAL COMPONENTS NOT RELATED TO THE VMS.CONSTRUCTION CONTRACTOR SHALL VERIFY CONSISTENCY OF VMS DETAILS WITH APPLICABLE STRUCTURAL,ARCHITECTURAL, MECHANICAL, AND PLUMBING PLANS AND RESOLVE ANY INCONSISTENCIES PRIOR TO VMSINSTALLATION.MP-3AREA OF SUB-SLABVENTING SYSTEM(NON-VIMS REQUIRED)REVISION 1S:\AAA-Master Projects\Ralph Falls (RPH)\BKL-001 - Belmont Dyers\Occupancy Requests\Figures\VMP_As-Built_Building 5_11052019.dwg, 4/15/2020 6:26:42 PM, DWG To PDF.pc3 GARAGEKITCHENMASTER BEDROOMGREAT ROOMDINING ROOMFOYERPOWDERLAUNDRYW.I. CLOSET GARAGEKITCHENMASTER BEDROOMGREAT ROOMDINING ROOMFOYERPOWDERLAUNDRYW.I. CLOSETMASTER BATHFOYERPATIO GARAGEDINING ROOMGREAT ROOMKITCHENPOWDERFOYERPATIOGARAGEDINING ROOMGREAT ROOMKITCHENPOWDERGREAT ROOMOPEN AIR PATIO3" X 3" X 3" PVCTEE (TYP.)3VM13VM11VM11VM12VM14VM1SEAL VAPOR LINER TOEDGE OF CONCRETESEAL VAPOR LINER TOEDGE OF CONCRETE6VM16VM1SEAL VAPOR LINER TOEDGE OF CONCRETE PERDETAIL 7 (TYPICAL)SEAL VAPOR LINER TOEDGE OF CONCRETE PERDETAIL 7 (TYPICAL)7VM17VM17VM1VM178VM18VM1CONCRETE FOOTERCONCRETE FOOTERCONCRETE FOOTERCONCRETE FOOTERCONCRETE FOOTERCONCRETE FOOTERCONCRETE FOOTERSEPARATEDGARAGE4VM1OPEN AIR PATIOCONCRETE FOOTERCONCRETE FOOTER3" VENT PIPE COLLECTIONSCREEN (TYP. AT SLOTTED PIPE ENDS)SHARE ROOFED GARAGES SEPARATED BYTHICKENED FOOTER AND CONTINUOUS WALLSHARE ROOFED GARAGES SEPARATED BYTHICKENED FOOTER AND CONTINUOUS WALLSEPARATEDGARAGEVMS VAPOR LINER AND BASE COURSE (TYP)1VMS SLOTTED COLLECTION PIPE (TYP)2BASE COARSE - CLEAN #57 STONEMIN 4" THICK BENEATH VMS VAPOR LINERVAPOR LINER (SEE SPECIFICATION #1)4" SCH 40 THREADED FLUSH JOINTSLOTTED PVC PIPE (0.020" SLOT WIDTH,1/8" SLOT SPACING)SET WITHIN MIN 4" BASE COURSEVAPOR LINER (SEE SPECIFICATION #1)CONCRETE FLOOR SLABSUBBASESUBBASENTSNTSVM1VM1VMS AT VERTICAL SLAB PENETRATION3NTSVAPOR LINER PENETRATION SEALED TOPIPE PER MANUFACTURER INSTRUCTIONS4" SCH 40 PVC 90DEGREE TEEPOSITION RISER IN STUD WALL/DEAD SPACE3" SCH 40 PVC RISER DUCT PIPE(SEE SPECIFICATION #2)BASE COARSE(SEE SPECIFICATION #1)VM1SOLID TO SLOTTED 4" SCH 40PVC PIPE TRANSITION (SLIP COUPLINGOR THREADED JOINT)VMS TURBINE VENTILATOR FAN & EXHAUST5VM1NTSTURBINE FAN(EMPIRE MODEL TV04G)ELECTRICAL JUNCTION BOX FORFUTURE VACUUM FAN, IF NEEDED(120V, 60 Hz AC REQUIRED)4" X 3" PVC COUPLING3" PVC DUCT PIPE THROUGH ROOFFLASHINGROOFTOPSOLID TO SLOTTED 4" SCH 40PVC PIPE TRANSITION (SLIPCOUPLING OR THREADEDJOINT)ATTIC SPACE4" TO 3" REDUCERGARAGE BLOCK FOUNDATION DETAIL WITH VMS VAPOR LINER6VM1NTS8" BLOCK WALL WITH VACUUM MEASURING POINT7VM1NTSVAPOR LINER PENETRATION SEALEDTO CONCRETE PER MANUFACTURERINSTRUCTIONSBASE COARSE(SEE SPECIFICATION #1)4" SCH 40 PVC (LENGTHVARIES - REFER TODETAILS A & B)NTSVM1HOUSE/GARAGE PIPIN AT STEP DOWN8STUD WALLBASE COARSE(SEE SPECIFICATION #1)4" SCH 40 PVC4" SCH 40 PVC 45 DEGREE SWEEP4" SLOTTED SCH 40 PVCPIPE (SEE DETAIL 2)PROVIDE PIPE SUPPORT TO PREVENT LOW POINTIN SOLID SECTION OF PIPE. MAINTAIN MINIMUM1% SLOPE TOWARD SLOTTED SECTIONS OF PIPE.(SEE SPECIFICATION #2)VAPOR LINER PENETRATION SEALED TOPIPE PER MANUFACTURERINSTRUCTIONSWALL SEPARATING GARGAGES4NTSVM1BRICK OR SIDING EXTERNAL WALL (NOT PRESENT AT ALL LOCATIONS)STUD WALLBASE COARSE(SEE SPECIFICATION #1)VAPOR LINER SEALED TO CONCRETE PERMANUFACTURER INSTRUCTIONS.2" SCH 40 PVC ELBOW2" OPEN ENDED PIPE, PLACED AT AMINIMUM OF 3' FROM EXTERIORTURN-DOWN SLABS2" SOLIDSCH 40 PVCLOCKABLE WEATHERPROOFENCLOSURE ON OUTSIDE OF HOUSEWALL. AFFIX LABEL AT BOX WITH"VAPOR MITIGATION SYSTEM". PLACEREMOVABLE PIPE PLUG AT END OF 2"PIPE.PERMANENT VACUUM MEASURING POINT IN OUTSIDE WALLFABRIC FILTER SOCK OVEREND OF OPEN ENDED PIPEOR VENT CAPINSTALLER SHALL SECURE PIPE TOPREVENT MOVEMENT OR DAMAGE TOTHE PIPE DURING THE CONCRETE POURINTERIOR STAIRWELL2" PVC 90 DEGREEELBOWOCCUPIED SPACEIRRIGATION BOX OR WATERMETER ENCLOSURE WITHLOCKABLE LIDSECURE PIPE WITHINENCLOSURE TOPREVENT MOVEMENTFABRIC FILTER SOCK OVEREND OF OPEN ENDED PIPEOR VENT CAPVAPOR LINER SEALED TO FOOTER PERMANUFACTURER INSTRUCTIONS WITHDOUBLE-SIDED TAPE ON EITHER TOP ORSIDE OF FOOTERAT AREAS WITH MEASURING POINTS,VAPOR LINER EXTENDS BELOW PIPE ANDAND IS SEALED TO PIPE PENETRATIONAND CONCRETE PER MANUFACTURERINSTRUCTIONS18 LINESTOWE DRIVE BELMONT, NORTH CAROLINA ABERFOYLE MILL & VILLAGEVAPOR MITIGATION SYSTEM PLAN - TOWNHOME BUILDING # 6 (UNITS 57, 58, 59, & 60)1" = 10'BROOKLINE HOMES, LLC.WELCOME HOME425 E. CATAWBA STREETBELMONT, NC, 28012OFFICE: 980-277-1322VAPOR MITIGATION PLAN PREPARED BY2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 GeologyPROFESSIONAL APPROVALAS-BUILT DRAWINGH&H NO. BKL-001VAPOR INTRUSIONMITIGATIONSYSTEM PLANAPRIL 15, 2020VM-1CSITE LAYOUT1" = 80'BVM1AREA OF VAPOR INTRUSION MITIGATION SYSTEMBUILDING #1BUILDING #2BUILDING #3BUILDING #4(UNITS 70-67)BUILDING #5(UNITS 66-61)BUILDING #6(UNITS 60-57)BUILDING #7(UNITS 56-53)BUILDING #10BUILDING #11BUILDING #12BUILDING #13BUILDING #14BUILDING #15BUILDING #16BUILDING #17AS-BUILTDRAWINGBUILDING 604/15/20UNIT 60UNIT 59UNIT 58UNIT 57MP-1MP-2MP-3MP-4MP-5MP-6BUILDING #8(UNITS 52-47)BUILDING #9(UNITS 41-46)LEGENDSOLID 4" DIA SCHEDULE 40 PVC PIPINGSLOTTED 4" DIA SCHEDULE 40 PVC PIPINGEXTENT OF 15-MIL STEGO VAPOR LINER (SEE SPECIFICATION 1)LOCATION OF VERTICAL RISER AND LOCATION OF TURBINE FAN ON ROOFTOPLOCATION OF PRESSURE MEASURING POINT (SEE DETAILS 4 & 7)LOCATION OF SUB-SLAB VAPOR SAMPLEVAPOR MITIGATION SYSTEM (VMS) SPECIFICATIONS1. VMS VAPOR LINER IS STEGO WRAP 15-MIL VAPOR BARRIER MANUFACTURED BY STEGO INDUSTRIES LLC.VAPOR LINER WAS INSTALLED AS SPECIFIED HEREIN AND PER MANUFACTURER INSTALLATION INSTRUCTIONS TOCREATE A CONTINUOUS LINER BELOW FLOOR SLABS LOCATED IN GROUND LEVEL RESIDENTIAL OCCUPIED SPACES.A MINIMUM 4-INCH THICK BASE COURSE CONSISTING OF CLEAN #57 WAS INSTALLED BENEATH THE VMS VAPOR LINER.2. VMS PIPING IS SLOPED A MINIMUM OF 18 UNIT VERTICAL IN 12 UNITS HORIZONTAL (1% SLOPE) TO GRAVITY DRAIN.SOLID SECTIONS OF PIPE ARE POSITIONED TO DRAIN TO SLOTTED SECTIONS. PVC PIPE JOINTS WERE CONNECTEDUSING PVC SOCKET COUPLINGS AND PVC GLUE. SUB-SLAB SLOTTED VAPOR COLLECTION PIPE IS THREADED FLUSHJOINT 3" OR 4" SCH 40 PVC PIPE WITH 0.020" SLOT WIDTH AND 18" SLOT SPACING. ACCESSIBLE ABOVE-SLAB RISERDUCT PIPING IS PERMANENTLY IDENTIFIED BY MEANS OF A TAG OR STENCIL WITH "VAPOR PIPING - CONTACT HOA",OR SIMILAR, WITHIN EACH FLOOR LEVEL AND ABOVE THE ROOF LINE AT INTERVALS OF NO LESS THAN 10-LINEAR FT.3" PVC RISER DUCT PIPING IS INSTALLED TO CONNECT EACH SLAB PENETRATION LOCATION TO A ROOFTOP EXHAUSTDISCHARGE POINT WITH TURBINE FAN (SEE SPECIFICATION #3).3. RISER DUCT PIPING EXTENDS IN A VERTICAL ORIENTATION THROUGH THE BUILDING ROOF AND TERMINATE AMINIMUM OF 2 FT ABOVE THE BUILDING ROOF LINE. A EMPIRE MODEL TV04G TURBINE VENTILATOR FAN IS INSTALLEDON THE EXHAUST DISCHARGE END OF EACH RISER DUCT PIPE. A 4" X 3" PVC ADAPTOR COUPLING IS INSTALLED ATTHE DISCHARGE END OF THE 3" RISER DUCT PIPE AND THE FAN SHALL BE SECURED TO THE PVC IN A VERTICALORIENTATION. EXHAUST DISCHARGE LOCATIONS SHALL BE A MINIMUM OF 10 FT FROM ANY OPERABLE OPENING ORAIR INTAKE INTO THE BUILDING. ELECTRICAL JUNCTION BOXES ARE INSTALLED NEAR THE FAN LOCATIONS IN THEEVENT ELECTRIC FANS NEED TO BE INSTALLED IN THE FUTURE.4. THE VAPOR MITIGATION PLAN IS INTENDED TO BE USED FOR DIRECTION OF VMS COMPONENT INSTALLATION ONLYAND IS NOT INTENDED TO GUIDE CONSTRUCTION OF STRUCTURAL COMPONENTS NOT RELATED TO THE VMS.CONSTRUCTION CONTRACTOR SHALL VERIFY CONSISTENCY OF VMS DETAILS WITH APPLICABLE STRUCTURAL,ARCHITECTURAL, MECHANICAL, AND PLUMBING PLANS AND RESOLVE ANY INCONSISTENCIES PRIOR TO VMSINSTALLATION.MP-3AREA OF SUB-SLABVENTING SYSTEM(NON-VIMS REQUIRED)REVISION 1S:\AAA-Master Projects\Ralph Falls (RPH)\BKL-001 - Belmont Dyers\Occupancy Requests\Figures\VMP_As-Built_Building 6_11052019.dwg, 4/15/2020 6:28:54 PM, DWG To PDF.pc3 GARAGEKITCHENMASTER BEDROOMGREAT ROOMDINING ROOMFOYERPOWDERLAUNDRYW.I. CLOSET GARAGEKITCHENMASTER BEDROOMGREAT ROOMDINING ROOMFOYERPOWDERLAUNDRYW.I. CLOSETMASTER BATHFOYERPATIO GARAGEDINING ROOMGREAT ROOMKITCHENPOWDERFOYERPATIOGARAGEDINING ROOMGREAT ROOMKITCHENPOWDERGREAT ROOMOPEN AIR PATIO3" VENT PIPE COLLECTIONSCREEN (TYP. AT SLOTTED PIPE ENDS)3" X 3" X 3" PVCTEE (TYP.)3VM13VM11VM11VM12VM14VM1SEAL VAPOR LINER TOEDGE OF CONCRETESEAL VAPOR LINER TOEDGE OF CONCRETE6VM16VM1SEAL VAPOR LINER TOEDGE OF CONCRETE PERDETAIL 7 (TYPICAL)SEAL VAPOR LINER TOEDGE OF CONCRETE PERDETAIL 7 (TYPICAL)7VM17VM17VM1VM178VM18VM1CONCRETE FOOTERCONCRETE FOOTERCONCRETE FOOTERCONCRETE FOOTERCONCRETE FOOTERCONCRETE FOOTERCONCRETE FOOTERSEPARATEDGARAGE4VM1OPEN AIR PATIOCONCRETE FOOTERCONCRETE FOOTERSHARE ROOFED GARAGES SEPARATED BYTHICKENED FOOTER AND CONTINUOUS WALLSHARE ROOFED GARAGES SEPARATED BYTHICKENED FOOTER AND CONTINUOUS WALLSEPARATEDGARAGEVMS VAPOR LINER AND BASE COURSE (TYP)1VMS SLOTTED COLLECTION PIPE (TYP)2BASE COARSE - CLEAN #57 STONEMIN 4" THICK BENEATH VMS VAPOR LINERVAPOR LINER (SEE SPECIFICATION #1)4" SCH 40 THREADED FLUSH JOINTSLOTTED PVC PIPE (0.020" SLOT WIDTH,1/8" SLOT SPACING)SET WITHIN MIN 4" BASE COURSEVAPOR LINER (SEE SPECIFICATION #1)CONCRETE FLOOR SLABSUBBASESUBBASENTSNTSVM1VM1VMS AT VERTICAL SLAB PENETRATION3NTSVAPOR LINER PENETRATION SEALED TOPIPE PER MANUFACTURER INSTRUCTIONS4" SCH 40 PVC 90DEGREE TEEPOSITION RISER IN STUD WALL/DEAD SPACE3" SCH 40 PVC RISER DUCT PIPE(SEE SPECIFICATION #2)BASE COARSE(SEE SPECIFICATION #1)VM1SOLID TO SLOTTED 4" SCH 40PVC PIPE TRANSITION (SLIP COUPLINGOR THREADED JOINT)VMS TURBINE VENTILATOR FAN & EXHAUST5VM1NTSTURBINE FAN(EMPIRE MODEL TV04G)ELECTRICAL JUNCTION BOX FORFUTURE VACUUM FAN, IF NEEDED(120V, 60 Hz AC REQUIRED)4" X 3" PVC COUPLING3" PVC DUCT PIPE THROUGH ROOFFLASHINGROOFTOPSOLID TO SLOTTED 4" SCH 40PVC PIPE TRANSITION (SLIPCOUPLING OR THREADEDJOINT)ATTIC SPACE4" TO 3" REDUCERGARAGE BLOCK FOUNDATION DETAIL WITH VMS VAPOR LINER6VM1NTS8" BLOCK WALL WITH VACUUM MEASURING POINT7VM1NTSVAPOR LINER PENETRATION SEALEDTO CONCRETE PER MANUFACTURERINSTRUCTIONSBASE COARSE(SEE SPECIFICATION #1)4" SCH 40 PVC (LENGTHVARIES - REFER TODETAILS A & B)NTSVM1HOUSE/GARAGE PIPING AT INTERIOR STEP DOWN8STUD WALLBASE COARSE(SEE SPECIFICATION #1)4" SCH 40 PVC4" SCH 40 PVC 45 DEGREE SWEEP4" SLOTTED SCH 40 PVCPIPE (SEE DETAIL 2)PROVIDE PIPE SUPPORT TO PREVENT LOW POINTIN SOLID SECTION OF PIPE. MAINTAIN MINIMUM1% SLOPE TOWARD SLOTTED SECTIONS OF PIPE.(SEE SPECIFICATION #2)VAPOR LINER PENETRATION SEALED TOPIPE PER MANUFACTURERINSTRUCTIONSWALL SEPARATING GARGAGES4NTSVM1BRICK OR SIDING EXTERNAL WALL (NOT PRESENT AT ALL LOCATIONS)STUD WALLBASE COARSE(SEE SPECIFICATION #1)VAPOR LINER SEALED TO CONCRETE PERMANUFACTURER INSTRUCTIONS.2" SCH 40 PVC ELBOW2" OPEN ENDED PIPE, PLACED AT AMINIMUM OF 3' FROM EXTERIORTURN-DOWN SLABS2" SOLIDSCH 40 PVCLOCKABLE WEATHERPROOFENCLOSURE ON OUTSIDE OF HOUSEWALL. AFFIX LABEL AT BOX WITH"VAPOR MITIGATION SYSTEM". PLACEREMOVABLE PIPE PLUG AT END OF 2"PIPE.PERMANENT VACUUM MEASURING POINT IN OUTSIDE WALLFABRIC FILTER SOCK OVEREND OF OPEN ENDED PIPEOR VENT CAPINSTALLER SHALL SECURE PIPE TOPREVENT MOVEMENT OR DAMAGE TOTHE PIPE DURING THE CONCRETE POURINTERIOR STAIRWELL2" PVC 90 DEGREEELBOWOCCUPIED SPACEIRRIGATION BOX OR WATERMETER ENCLOSURE WITHLOCKABLE LIDSECURE PIPE WITHINENCLOSURE TOPREVENT MOVEMENTFABRIC FILTER SOCK OVEREND OF OPEN ENDED PIPEOR VENT CAPVAPOR LINER SEALED TO FOOTER PERMANUFACTURER INSTRUCTIONS WITHDOUBLE-SIDED TAPE ON EITHER TOP ORSIDE OF FOOTERAT AREAS WITH MEASURING POINTS,VAPOR LINER EXTENDS BELOW PIPE ANDAND IS SEALED TO PIPE PENETRATIONAND CONCRETE PER MANUFACTURERINSTRUCTIONS18 LINESTOWE DRIVE BELMONT, NORTH CAROLINA ABERFOYLE MILL & VILLAGEVAPOR MITIGATION SYSTEM PLAN - TOWNHOME BUILDING # 7 (UNITS 53, 54, 55, & 56)1" = 10'BROOKLINE HOMES, LLC.WELCOME HOME425 E. CATAWBA STREETBELMONT, NC, 28012OFFICE: 980-277-1322VAPOR MITIGATION PLAN PREPARED BY2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 GeologyPROFESSIONAL APPROVALAS-BUILT DRAWINGH&H NO. BKL-001VAPOR INTRUSIONMITIGATIONSYSTEM PLANAPRIL 15, 2020VM-1DSITE LAYOUT1" = 80'BVM1AREA OF VAPOR INTRUSION MITIGATION SYSTEMBUILDING #1BUILDING #2BUILDING #3BUILDING #4(UNITS 70-67)BUILDING #5(UNITS 66-61)BUILDING #6(UNITS 60-57)BUILDING #7(UNITS 56-53)BUILDING #10BUILDING #11BUILDING #12BUILDING #13BUILDING #14BUILDING #15BUILDING #16BUILDING #17AS-BUILTDRAWINGBUILDING 704/15/20UNIT 56UNIT 55UNIT 54UNIT 53MP-1MP-2MP-3MP-4MP-5MP-6BUILDING #8(UNITS 52-47)BUILDING #9(UNITS 41-46)LEGENDSOLID 4" DIA SCHEDULE 40 PVC PIPINGSLOTTED 4" DIA SCHEDULE 40 PVC PIPINGEXTENT OF 15-MIL STEGO VAPOR LINER (SEE SPECIFICATION 1)LOCATION OF VERTICAL RISER AND LOCATION OF TURBINE FAN ON ROOFTOPLOCATION OF PRESSURE MEASURING POINT (SEE DETAILS 4 & 7)LOCATION OF SUB-SLAB VAPOR SAMPLEVAPOR MITIGATION SYSTEM (VMS) SPECIFICATIONS1. VMS VAPOR LINER IS STEGO WRAP 15-MIL VAPOR BARRIER MANUFACTURED BY STEGO INDUSTRIES LLC.VAPOR LINER WAS INSTALLED AS SPECIFIED HEREIN AND PER MANUFACTURER INSTALLATION INSTRUCTIONS TOCREATE A CONTINUOUS LINER BELOW FLOOR SLABS LOCATED IN GROUND LEVEL RESIDENTIAL OCCUPIED SPACES.A MINIMUM 4-INCH THICK BASE COURSE CONSISTING OF CLEAN #57 WAS INSTALLED BENEATH THE VMS VAPOR LINER.2. VMS PIPING IS SLOPED A MINIMUM OF 18 UNIT VERTICAL IN 12 UNITS HORIZONTAL (1% SLOPE) TO GRAVITY DRAIN.SOLID SECTIONS OF PIPE ARE POSITIONED TO DRAIN TO SLOTTED SECTIONS. PVC PIPE JOINTS WERE CONNECTEDUSING PVC SOCKET COUPLINGS AND PVC GLUE. SUB-SLAB SLOTTED VAPOR COLLECTION PIPE IS THREADED FLUSHJOINT 3" OR 4" SCH 40 PVC PIPE WITH 0.020" SLOT WIDTH AND 18" SLOT SPACING. ACCESSIBLE ABOVE-SLAB RISERDUCT PIPING IS PERMANENTLY IDENTIFIED BY MEANS OF A TAG OR STENCIL WITH "VAPOR PIPING - CONTACT HOA",OR SIMILAR, WITHIN EACH FLOOR LEVEL AND ABOVE THE ROOF LINE AT INTERVALS OF NO LESS THAN 10-LINEAR FT.3" PVC RISER DUCT PIPING IS INSTALLED TO CONNECT EACH SLAB PENETRATION LOCATION TO A ROOFTOP EXHAUSTDISCHARGE POINT WITH TURBINE FAN (SEE SPECIFICATION #3).3. RISER DUCT PIPING EXTENDS IN A VERTICAL ORIENTATION THROUGH THE BUILDING ROOF AND TERMINATE AMINIMUM OF 2 FT ABOVE THE BUILDING ROOF LINE. A EMPIRE MODEL TV04G TURBINE VENTILATOR FAN IS INSTALLEDON THE EXHAUST DISCHARGE END OF EACH RISER DUCT PIPE. A 4" X 3" PVC ADAPTOR COUPLING IS INSTALLED ATTHE DISCHARGE END OF THE 3" RISER DUCT PIPE AND THE FAN SHALL BE SECURED TO THE PVC IN A VERTICALORIENTATION. EXHAUST DISCHARGE LOCATIONS SHALL BE A MINIMUM OF 10 FT FROM ANY OPERABLE OPENING ORAIR INTAKE INTO THE BUILDING. ELECTRICAL JUNCTION BOXES ARE INSTALLED NEAR THE FAN LOCATIONS IN THEEVENT ELECTRIC FANS NEED TO BE INSTALLED IN THE FUTURE.4. THE VAPOR MITIGATION PLAN IS INTENDED TO BE USED FOR DIRECTION OF VMS COMPONENT INSTALLATION ONLYAND IS NOT INTENDED TO GUIDE CONSTRUCTION OF STRUCTURAL COMPONENTS NOT RELATED TO THE VMS.CONSTRUCTION CONTRACTOR SHALL VERIFY CONSISTENCY OF VMS DETAILS WITH APPLICABLE STRUCTURAL,ARCHITECTURAL, MECHANICAL, AND PLUMBING PLANS AND RESOLVE ANY INCONSISTENCIES PRIOR TO VMSINSTALLATION.MP-3AREA OF SUB-SLABVENTING SYSTEM(NON-VIMS REQUIRED)REVISION 1S:\AAA-Master Projects\Ralph Falls (RPH)\BKL-001 - Belmont Dyers\Occupancy Requests\Figures\VMP_As-Built_Building 7_12172019.dwg, 4/15/2020 6:30:37 PM, DWG To PDF.pc3 Appendix B VIMS Inspection Forms and Field Logs Sub-Slab / Soil Gas Vapor QA/QC Field FormProject No.:____________________Depth of ScreenDate & TimeAmbient Temp.Purge Method Purge VolHelium Conc.ShroudHelium Conc.PurgeLeak Test PassedYes / No SS, SGperm., temp.concrete, wood, asphalt, grass, soil, gravel etc.thicknessinches(if appl.)ft bgsmm/dd/yy 24-hour clockoFsyringe, peristaltic, etc.Liters %% or ppm(indicate units below)Yes / No(see note)S:C:R:S:C:R:S:C:R:S:C:R:S= sample; C/R = canister/regulator; SS = sub-slab; SG = soil gas; perm = permanent; temp = temporarySampler(s): ___________________________________________________________Weather: ___________________________________________________________Notes: ____________________________________________________________________________________________________________________________________________________________________________________________________________________________________________Helium Leak TestCanister / RegulatorShut-in Test PassedGround SurfaceID NumbersSample / Canister / RegulatorTypeVapor Monitoring Point ConstructionGeneral Field Sketch of Sample Locations Note: Leak Test Requirements Per NC DEQ DWM Vapor Intrusion Guidance, leak test passes if helium concentration in purge air is less than 10% of helium concentration in shroud. S:\BBB Master Templates\Forms - Soil Gas\Sub-slab & Soil Gas QA_QC Field FormSub-Slab / Soil Gas Sampling Vapor QA/QC Field FormHart & Hickman, PCBKL-00110/4/1991.091.093.0Sunny, Clear, 90's, wind speed 5-mphSS-Bld 4 MP-622534.0 Pump (Gilair)4205DUP-123284205SS-Bld 4 MP-323264167SSSSSSPerm.Perm.Perm.ConcretConcretConcret4.04.012:0110/4/1912:0110/4/1913:00Pump (Gilair) Pump (Gilair)5.05.05.058.758.721.1725.0725.00.0ppmNatasha Pacifico%ppm%ppm%ppm%YesNoYesNoYesNoYesNoYesNoYesNoYesNoYesNo Sub-Slab / Soil Gas Vapor QA/QC Field FormProject No.:____________________Depth of ScreenDate & TimeAmbient Temp.Purge Method Purge VolHelium Conc.ShroudHelium Conc.PurgeLeak Test PassedYes / No SS, SGperm., temp.concrete, wood, asphalt, grass, soil, gravel etc.thicknessinches(if appl.)ft bgsmm/dd/yy 24-hour clockoFsyringe, peristaltic, etc.Liters %% or ppm(indicate units below)Yes / No(see note)S:C:R:S:C:R:S:C:R:S:C:R:S= sample; C/R = canister/regulator; SS = sub-slab; SG = soil gas; perm = permanent; temp = temporarySampler(s): ___________________________________________________________Weather: ___________________________________________________________Notes: ____________________________________________________________________________________________________________________________________________________________________________________________________________________________________________Helium Leak TestCanister / RegulatorShut-in Test PassedGround SurfaceID NumbersSample / Canister / RegulatorTypeVapor Monitoring Point ConstructionGeneral Field Sketch of Sample Locations Note: Leak Test Requirements Per NC DEQ DWM Vapor Intrusion Guidance, leak test passes if helium concentration in purge air is less than 10% of helium concentration in shroud. S:\BBB Master Templates\Forms - Soil Gas\Sub-slab & Soil Gas QA_QC Field FormSub-Slab / Soil Gas Sampling Vapor QA/QC Field FormHart & Hickman, PCBKL-00110/18/1959.059.059.059.0Sunny, Clear, 59.0 F, Wind 7 mph NNESS-BLD 5-MP-32099Air Pump (Gilair)4224SS-BLD 5- MP-521154209SS-BLD 5-MP-821164225DUP-120994209SSSSSSSSPerm.Perm.Perm.Perm.ConcretConcretConcretConcret11:2710/18/1910:4810/18/1910:0510/18/19Air Pump (Gilair)Air Pump (Gilair) Air Pump (Gilair) 5.05.05.05.015.316.416.116.40.00.01,525.00.0ppmNatasha Pacifico%ppm%ppm%ppm%YesNoYesNoYesNoYesNoYesNoYesNoYesNoYesNo Sub-Slab / Soil Gas Vapor QA/QC Field FormProject No.:____________________Depth of ScreenDate & TimeAmbient Temp.Purge Method Purge VolHelium Conc.ShroudHelium Conc.PurgeLeak Test PassedYes / No SS, SGperm., temp.concrete, wood, asphalt, grass, soil, gravel etc.thicknessinches(if appl.)ft bgsmm/dd/yy 24-hour clockoFsyringe, peristaltic, etc.Liters %% or ppm(indicate units below)Yes / No(see note)S:C:R:S:C:R:S:C:R:S:C:R:S= sample; C/R = canister/regulator; SS = sub-slab; SG = soil gas; perm = permanent; temp = temporarySampler(s): ___________________________________________________________Weather: ___________________________________________________________Notes: ____________________________________________________________________________________________________________________________________________________________________________________________________________________________________________Helium Leak TestCanister / RegulatorShut-in Test PassedGround SurfaceID NumbersSample / Canister / RegulatorTypeVapor Monitoring Point ConstructionGeneral Field Sketch of Sample Locations Note: Leak Test Requirements Per NC DEQ DWM Vapor Intrusion Guidance, leak test passes if helium concentration in purge air is less than 10% of helium concentration in shroud. S:\BBB Master Templates\Forms - Soil Gas\Sub-slab & Soil Gas QA_QC Field FormSub-Slab / Soil Gas Sampling Vapor QA/QC Field FormHart & Hickman, PCBKL-00110/25/1958.058.062.0Overcast, <5 mph wind, high fifties to low sixty's.SS-Bld 6 MP-32253 Air Pump (Gilair)4306Dup-123454306SS-Bld 6 MP-623284248SSSSSSPerm.Perm.Perm.ConcretConcretConcret10:1010/25/1910:1010/25/1910:52 Air Pump (Gilair) Air Pump (Gilair)5.05.05.015.715.715.50.00.00.0ppmNatasha Pacifico%ppm%ppm%ppm%YesNoYesNoYesNoYesNoYesNoYesNoYesNoYesNo Sub-Slab / Soil Gas Vapor QA/QC Field Form Project No.:____________________ Depth of Screen Date & Time Ambient Temp.Purge Method Purge Vol Helium Conc.Shroud Helium Conc.Purge Leak Test Passed Yes / No SS, SG perm., temp. concrete, wood, asphalt, grass, soil, gravel etc. thicknessinches(if appl.)ft bgs mm/dd/yy 24-hour clock oF syringe, peristaltic, etc.Liters % % or ppm (indicate units below) Yes / No (see note) S: C: R: S: C: R: S: C: R: S: C: R: S= sample; C/R = canister/regulator; SS = sub-slab; SG = soil gas; perm = permanent; temp = temporary Sampler(s): ___________________________________________________________ Weather: ___________________________________________________________ Notes: ___________________________________________________________ ___________________________________________________________ ___________________________________________________________ ___________________________________________________________ Helium Leak TestCanister / RegulatorShut-in Test Passed Ground SurfaceID Numbers Sample / Canister / Regulator Type Vapor Monitoring Point Construction General Field Sketch of Sample Locations Note: Leak Test Requirements Per NC DEQ DWM Vapor Intrusion Guidance, leak test passes if helium concentration in purge air is less than 10% of helium concentration in shroud. S:\BBB Master Templates\Forms - Soil Gas\Sub-slab & Soil Gas QA_QC Field Form Sub-Slab / Soil Gas Sampling Vapor QA/QC Field Form Hart & Hickman, PC BKL-001 11/1/19 50.0 50.0 50.0 Clear and sunny, 50's SS-Bld 7 MP-3 1851 Pump (Gilair) 4315 Dup-1 14934315 SS-Bld 7 MP-6 1872 4344 SS SS SS Perm. Perm. Perm. Concret Concret Concret 14:48 11/1/19 14:48 11/1/19 15:05 Pump (Gilair) Pump (Gilair) 10.0 10.0 10.0 59.2 59.2 41.0 175.0 175.0 75.0 ppm Natasha Pacifico % ppm % ppm % ppm % Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Appendix C Photographic Logs BKL-0012923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph 1: General view of sub-slab piping at Building 4 prior to placing clean gravel. FORMER BELMONT DYERS BROWNFIELDS SITEBROOKLINE HOMESBELMONT, NORTH CAROLINA Photograph 2: General view of sub-slab piping at Building 4 covered with clean gravel . BKL-0012923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph 4: Close view of sealed penetration at Building 4. FORMER BELMONT DYERS BROWNFIELDS SITEBROOKLINE HOMESBELMONT, NORTH CAROLINA Photograph 3: General view of installed vapor barrier at Building 4. Photograph 6: Representative view of passive ventilator fan at Building 4.BKL-0012923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph 5: Representative view of riser piping in Building 4. FORMER BELMONT DYERS BROWNFIELDS SITEBROOKLINE HOMESBELMONT, NORTH CAROLINA BKL-0012923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph 1: General view of sub-slab piping at Building 5 prior to placing clean gravel. FORMER BELMONT DYERS BROWNFIELDS SITEBROOKLINE HOMESBELMONT, NORTH CAROLINA Photograph 2: General view of vapor barrier at Building 5. Photograph 4: Representative view of passive ventilator fans at Building 5.BKL-0012923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph 3: Representative view of riser piping in Building 5. FORMER BELMONT DYERS BROWNFIELDS SITEBROOKLINE HOMESBELMONT, NORTH CAROLINA BKL-0012923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph 5: General view of sub-slab piping at Building 6. FORMER BELMONT DYERS BROWNFIELDS SITEBROOKLINE HOMESBELMONT, NORTH CAROLINA Photograph 6: General view of vapor barrier at Building 6. Photograph 8: General view of passive ventilator fan at Building 6.BKL-0012923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph 7: Representative view of riser piping in Building 6. FORMER BELMONT DYERS BROWNFIELDS SITEBROOKLINE HOMESBELMONT, NORTH CAROLINA BKL-0012923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph 1: General view of sub-slab piping at Building 7 covered with clean gravel. FORMER BELMONT DYERS BROWNFIELDS SITEBROOKLINE HOMESBELMONT, NORTH CAROLINA Photograph 2: General view of sub-slab monitoring point. BKL-0012923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph 4: Close view of sealed penetration at Building 7. FORMER BELMONT DYERS BROWNFIELDS SITEBROOKLINE HOMESBELMONT, NORTH CAROLINA Photograph 3: General view of installed vapor barrier at Building 7. Photograph 6: Representative view of passive ventilator fan at Building 7.BKL-0012923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph 5: Representative view of riser piping in Building 7. FORMER BELMONT DYERS BROWNFIELDS SITEBROOKLINE HOMESBELMONT, NORTH CAROLINA Appendix D Laboratory Analytical Reports 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 November 19, 2019 Andrew Besu Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 Project Location: Belmont, NC Client Job Number: Project Number: BKL-001 Laboratory Work Order Number: 19J0555 Enclosed are results of analyses for samples received by the laboratory on October 4, 2019. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kerry K. McGee Project Manager QA Officer Katherine Allen Laboratory Manager Daren Damboragian Page 1 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL SUMMARY 11/19/2019Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 ATTN: Andrew Besu BKL-001 19J0555 The results of analyses performed on the following samples submitted to the CON-TEST Analytical Laboratory are found in this report. PROJECT LOCATION: PURCHASE ORDER NUMBER: PROJECT NUMBER: REPORT DATE: WORK ORDER NUMBER: FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB Belmont, NC BKL-001 SS-Bld4-MP-3 19J0555-01 Sub Slab - EPA TO-15 SS-Bld4-MP-6 19J0555-02 Sub Slab - EPA TO-15 Dup-1 19J0555-03 Sub Slab - EPA TO-15 Page 2 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CASE NARRATIVE SUMMARY All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report. REVISED REPORT - 11/19/2019 - Report full TO-15 list per client’s request. EPA TO-15 Qualifications: Laboratory fortified blank /laboratory control sample recovery outside of control limits. Data validation is not affected since all results are "not detected" for all samples in this batch for this compound and bias is on the high side. Analyte & Samples(s) Qualified: 1,2,4-Trichlorobenzene B242855-BS1 Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side for this compound. Analyte & Samples(s) Qualified: Naphthalene 19J0555-01[SS-Bld4-MP-3], B242855-BLK1, B242855-BS1, S041300-CCV1 Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was "not detected" for this compound. Analyte & Samples(s) Qualified: 1,2,4-Trichlorobenzene S041300-CCV1 Initial calibration verification (ICV) did not meet method specifications and was biased on the high side for this compound. Reported result is estimated. Analyte & Samples(s) Qualified: Naphthalene 19J0555-01[SS-Bld4-MP-3], B242855-BS1, S041300-CCV1 Initial calibration verification (ICV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was "not detected" for this compound. Analyte & Samples(s) Qualified: 1,2,4-Trichlorobenzene B242855-BS1 Compound fails the method requirement of 70-130% recovery for the LCS. Is classified by the lab as a difficult compound and passes the in house limits of 50-150%. Analyte & Samples(s) Qualified: Naphthalene 19J0555-01[SS-Bld4-MP-3], B242855-BS1 Page 3 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 The results of analyses reported only relate to samples submitted to the Con-Test Analytical Laboratory for testing. I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Lisa A. Worthington Technical Representative Page 4 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/4/2019 Work Order: 19J0555Sample Description/Location: Field Sample #: SS-Bld4-MP-3 Sample ID: 19J0555-01 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -6.9 Sampled: 10/4/2019 13:08 Canister ID: 2326 Flow Controller ID: 4167 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 35 8.0 10/10/19 11:19 BRF824192.8 6.6 Benzene 0.27 0.20 10/10/19 11:19 BRF0.86 40.640.082 0.26 Benzyl chloride ND 0.20 10/10/19 11:19 BRFND41.00.052 0.27 Bromodichloromethane ND 0.20 10/10/19 11:19 BRFND41.30.074 0.49 Bromoform ND 0.20 10/10/19 11:19 BRFND42.10.090 0.93 Bromomethane ND 0.20 10/10/19 11:19 BRFND40.780.14 0.53 1,3-Butadiene ND 0.20 10/10/19 11:19 BRFND40.440.15 0.32 2-Butanone (MEK)29 8.0 10/10/19 11:19 BRF854240.37 1.1 Carbon Disulfide ND 2.0 10/10/19 11:19 BRFND46.20.14 0.43 Carbon Tetrachloride ND 0.20 10/10/19 11:19 BRFND41.30.065 0.41 Chlorobenzene ND 0.20 10/10/19 11:19 BRFND40.920.098 0.45 Chloroethane ND 0.20 10/10/19 11:19 BRFND40.530.20 0.52 Chloroform ND 0.20 10/10/19 11:19 BRFND40.980.074 0.36 Chloromethane 1.4 0.40 10/10/19 11:19 BRF2.9 40.830.14 0.28 Cyclohexane ND 0.20 10/10/19 11:19 BRFND40.690.14 0.49 Dibromochloromethane ND 0.20 10/10/19 11:19 BRFND41.70.066 0.57 1,2-Dibromoethane (EDB)ND 0.20 10/10/19 11:19 BRFND41.50.078 0.60 1,2-Dichlorobenzene ND 0.20 10/10/19 11:19 BRFND41.20.096 0.58 1,3-Dichlorobenzene ND 0.20 10/10/19 11:19 BRFND41.20.10 0.62 1,4-Dichlorobenzene ND 0.20 10/10/19 11:19 BRFND41.20.12 0.73 Dichlorodifluoromethane (Freon 12)0.37 0.20 10/10/19 11:19 BRF1.8 40.990.087 0.43 1,1-Dichloroethane ND 0.20 10/10/19 11:19 BRFND40.810.061 0.25 1,2-Dichloroethane ND 0.20 10/10/19 11:19 BRFND40.810.076 0.31 1,1-Dichloroethylene ND 0.20 10/10/19 11:19 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 10/10/19 11:19 BRFND40.790.082 0.32 trans-1,2-Dichloroethylene ND 0.20 10/10/19 11:19 BRFND40.790.081 0.32 1,2-Dichloropropane ND 0.20 10/10/19 11:19 BRFND40.920.071 0.33 cis-1,3-Dichloropropene ND 0.20 10/10/19 11:19 BRFND40.910.070 0.32 trans-1,3-Dichloropropene ND 0.20 10/10/19 11:19 BRFND40.910.073 0.33 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 10/10/19 11:19 BRFND41.40.11 0.79 1,4-Dioxane ND 2.0 10/10/19 11:19 BRFND47.21.3 4.6 Ethanol 6.9 8.0 10/10/19 11:19 BRFJ134153.6 6.7 Ethyl Acetate 0.34 0.20 10/10/19 11:19 BRF1.2 40.720.15 0.54 Ethylbenzene 0.26 0.20 10/10/19 11:19 BRF1.1 40.870.12 0.50 4-Ethyltoluene ND 0.20 10/10/19 11:19 BRFND40.980.12 0.60 Heptane 0.18 0.20 10/10/19 11:19 BRFJ0.72 40.820.12 0.48 Hexachlorobutadiene ND 0.20 10/10/19 11:19 BRFND42.10.092 0.98 Hexane ND 8.0 10/10/19 11:19 BRFND4280.35 1.2 2-Hexanone (MBK)ND 0.20 10/10/19 11:19 BRFND40.820.12 0.48 Isopropanol 1.3 8.0 10/10/19 11:19 BRFJ3.1 4200.37 0.90 Methyl tert-Butyl Ether (MTBE)ND 0.20 10/10/19 11:19 BRFND40.720.10 0.36 Methylene Chloride ND 2.0 10/10/19 11:19 BRFND46.90.24 0.84 4-Methyl-2-pentanone (MIBK)ND 0.20 10/10/19 11:19 BRFND40.820.10 0.43 Naphthalene 0.28 0.20 10/10/19 11:19 BRFV-06, Z-01, V-35 1.5 41.00.15 0.80 Propene ND 8.0 10/10/19 11:19 BRFND4140.37 0.64 Styrene ND 0.20 10/10/19 11:19 BRFND40.850.12 0.53 Page 5 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/4/2019 Work Order: 19J0555Sample Description/Location: Field Sample #: SS-Bld4-MP-3 Sample ID: 19J0555-01 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -6.9 Sampled: 10/4/2019 13:08 Canister ID: 2326 Flow Controller ID: 4167 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL 1,1,2,2-Tetrachloroethane ND 0.20 10/10/19 11:19 BRFND41.40.089 0.61 Tetrachloroethylene 0.35 0.20 10/10/19 11:19 BRF2.4 41.40.11 0.75 Tetrahydrofuran 16 0.20 10/10/19 11:19 BRF4840.590.20 0.59 Toluene 1.6 0.20 10/10/19 11:19 BRF5.9 40.750.10 0.39 1,2,4-Trichlorobenzene ND 0.20 10/10/19 11:19 BRFND41.50.14 1.0 1,1,1-Trichloroethane ND 0.20 10/10/19 11:19 BRFND41.10.075 0.41 1,1,2-Trichloroethane ND 0.20 10/10/19 11:19 BRFND41.10.082 0.45 Trichloroethylene ND 0.20 10/10/19 11:19 BRFND41.10.081 0.43 Trichlorofluoromethane (Freon 11)0.45 0.80 10/10/19 11:19 BRFJ2.5 44.50.15 0.85 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 10/10/19 11:19 BRFND46.10.15 1.2 1,2,4-Trimethylbenzene 0.16 0.20 10/10/19 11:19 BRFJ0.81 40.980.13 0.63 1,3,5-Trimethylbenzene ND 0.20 10/10/19 11:19 BRFND40.980.13 0.62 Vinyl Acetate ND 4.0 10/10/19 11:19 BRFND4140.12 0.44 Vinyl Chloride ND 0.20 10/10/19 11:19 BRFND40.510.13 0.32 m&p-Xylene 1.1 0.40 10/10/19 11:19 BRF5.0 41.70.23 1.00 o-Xylene 0.42 0.20 10/10/19 11:19 BRF1.8 40.870.12 0.54 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)112 10/10/19 11:1970-130 Page 6 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/4/2019 Work Order: 19J0555Sample Description/Location: Field Sample #: SS-Bld4-MP-6 Sample ID: 19J0555-02 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -6 Receipt Vacuum(in Hg): -9.4 Sampled: 10/4/2019 12:09 Canister ID: 2253 Flow Controller ID: 4205 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 25 8.0 10/10/19 9:40 BRF594192.8 6.6 Benzene 0.24 0.20 10/10/19 9:40 BRF0.77 40.640.082 0.26 Benzyl chloride ND 0.20 10/10/19 9:40 BRFND41.00.052 0.27 Bromodichloromethane ND 0.20 10/10/19 9:40 BRFND41.30.074 0.49 Bromoform ND 0.20 10/10/19 9:40 BRFND42.10.090 0.93 Bromomethane ND 2.0 10/10/19 9:40 BRFND47.80.14 0.53 1,3-Butadiene ND 0.20 10/10/19 9:40 BRFND40.440.15 0.32 2-Butanone (MEK)34 8.0 10/10/19 9:40 BRF1004240.37 1.1 Carbon Disulfide ND 2.0 10/10/19 9:40 BRFND46.20.14 0.43 Carbon Tetrachloride ND 0.20 10/10/19 9:40 BRFND41.30.065 0.41 Chlorobenzene ND 0.20 10/10/19 9:40 BRFND40.920.098 0.45 Chloroethane ND 0.20 10/10/19 9:40 BRFND40.530.20 0.52 Chloroform 0.10 0.20 10/10/19 9:40 BRFJ0.51 40.980.074 0.36 Chloromethane ND 0.40 10/10/19 9:40 BRFND40.830.14 0.28 Cyclohexane ND 0.20 10/10/19 9:40 BRFND40.690.14 0.49 Dibromochloromethane ND 0.20 10/10/19 9:40 BRFND41.70.066 0.57 1,2-Dibromoethane (EDB)ND 0.20 10/10/19 9:40 BRFND41.50.078 0.60 1,2-Dichlorobenzene ND 0.20 10/10/19 9:40 BRFND41.20.096 0.58 1,3-Dichlorobenzene ND 0.20 10/10/19 9:40 BRFND41.20.10 0.62 1,4-Dichlorobenzene ND 0.20 10/10/19 9:40 BRFND41.20.12 0.73 Dichlorodifluoromethane (Freon 12)ND 0.20 10/10/19 9:40 BRFND40.990.087 0.43 1,1-Dichloroethane ND 0.20 10/10/19 9:40 BRFND40.810.061 0.25 1,2-Dichloroethane ND 0.20 10/10/19 9:40 BRFND40.810.076 0.31 1,1-Dichloroethylene ND 0.20 10/10/19 9:40 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 10/10/19 9:40 BRFND40.790.082 0.32 trans-1,2-Dichloroethylene ND 0.20 10/10/19 9:40 BRFND40.790.081 0.32 1,2-Dichloropropane ND 0.20 10/10/19 9:40 BRFND40.920.071 0.33 cis-1,3-Dichloropropene ND 0.20 10/10/19 9:40 BRFND40.910.070 0.32 trans-1,3-Dichloropropene ND 0.20 10/10/19 9:40 BRFND40.910.073 0.33 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 10/10/19 9:40 BRFND41.40.11 0.79 1,4-Dioxane ND 2.0 10/10/19 9:40 BRFND47.21.3 4.6 Ethanol 7.6 8.0 10/10/19 9:40 BRFJ144153.6 6.7 Ethyl Acetate ND 0.20 10/10/19 9:40 BRFND40.720.15 0.54 Ethylbenzene ND 0.20 10/10/19 9:40 BRFND40.870.12 0.50 4-Ethyltoluene ND 0.20 10/10/19 9:40 BRFND40.980.12 0.60 Heptane ND 0.20 10/10/19 9:40 BRFND40.820.12 0.48 Hexachlorobutadiene ND 0.20 10/10/19 9:40 BRFND42.10.092 0.98 Hexane ND 8.0 10/10/19 9:40 BRFND4280.35 1.2 2-Hexanone (MBK)ND 0.20 10/10/19 9:40 BRFND40.820.12 0.48 Isopropanol ND 8.0 10/10/19 9:40 BRFND4200.37 0.90 Methyl tert-Butyl Ether (MTBE)ND 0.20 10/10/19 9:40 BRFND40.720.10 0.36 Methylene Chloride ND 2.0 10/10/19 9:40 BRFND46.90.24 0.84 4-Methyl-2-pentanone (MIBK)ND 0.20 10/10/19 9:40 BRFND40.820.10 0.43 Naphthalene ND 0.20 10/10/19 9:40 BRFND41.00.15 0.80 Propene ND 8.0 10/10/19 9:40 BRFND4140.37 0.64 Styrene ND 0.20 10/10/19 9:40 BRFND40.850.12 0.53 1,1,2,2-Tetrachloroethane ND 0.20 10/10/19 9:40 BRFND41.40.089 0.61 Page 7 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/4/2019 Work Order: 19J0555Sample Description/Location: Field Sample #: SS-Bld4-MP-6 Sample ID: 19J0555-02 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -6 Receipt Vacuum(in Hg): -9.4 Sampled: 10/4/2019 12:09 Canister ID: 2253 Flow Controller ID: 4205 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 1.8 0.20 10/10/19 9:40 BRF1241.40.11 0.75 Tetrahydrofuran 12 0.20 10/10/19 9:40 BRF3740.590.20 0.59 Toluene 1.8 0.20 10/10/19 9:40 BRF6.9 40.750.10 0.39 1,2,4-Trichlorobenzene ND 0.20 10/10/19 9:40 BRFND41.50.14 1.0 1,1,1-Trichloroethane ND 0.20 10/10/19 9:40 BRFND41.10.075 0.41 1,1,2-Trichloroethane ND 0.20 10/10/19 9:40 BRFND41.10.082 0.45 Trichloroethylene ND 0.20 10/10/19 9:40 BRFND41.10.081 0.43 Trichlorofluoromethane (Freon 11)0.67 0.80 10/10/19 9:40 BRFJ3.8 44.50.15 0.85 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 10/10/19 9:40 BRFND46.10.15 1.2 1,2,4-Trimethylbenzene 0.54 0.20 10/10/19 9:40 BRF2.7 40.980.13 0.63 1,3,5-Trimethylbenzene ND 0.20 10/10/19 9:40 BRFND40.980.13 0.62 Vinyl Acetate ND 4.0 10/10/19 9:40 BRFND4140.12 0.44 Vinyl Chloride ND 0.20 10/10/19 9:40 BRFND40.510.13 0.32 m&p-Xylene 0.60 0.40 10/10/19 9:40 BRF2.6 41.70.23 1.00 o-Xylene ND 0.20 10/10/19 9:40 BRFND40.870.12 0.54 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)97.1 10/10/19 9:4070-130 Page 8 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/4/2019 Work Order: 19J0555Sample Description/Location: Field Sample #: Dup-1 Sample ID: 19J0555-03 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -6 Receipt Vacuum(in Hg): -9.2 Sampled: 10/4/2019 00:00 Canister ID: 2328 Flow Controller ID: 4205 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 27 8.0 10/10/19 10:09 BRF654192.8 6.6 Benzene 0.25 0.20 10/10/19 10:09 BRF0.81 40.640.082 0.26 Benzyl chloride ND 0.20 10/10/19 10:09 BRFND41.00.052 0.27 Bromodichloromethane ND 0.20 10/10/19 10:09 BRFND41.30.074 0.49 Bromoform ND 0.20 10/10/19 10:09 BRFND42.10.090 0.93 Bromomethane ND 2.0 10/10/19 10:09 BRFND47.80.14 0.53 1,3-Butadiene ND 0.20 10/10/19 10:09 BRFND40.440.15 0.32 2-Butanone (MEK)36 8.0 10/10/19 10:09 BRF1104240.37 1.1 Carbon Disulfide ND 2.0 10/10/19 10:09 BRFND46.20.14 0.43 Carbon Tetrachloride ND 0.20 10/10/19 10:09 BRFND41.30.065 0.41 Chlorobenzene ND 0.20 10/10/19 10:09 BRFND40.920.098 0.45 Chloroethane ND 0.20 10/10/19 10:09 BRFND40.530.20 0.52 Chloroform ND 0.20 10/10/19 10:09 BRFND40.980.074 0.36 Chloromethane ND 0.40 10/10/19 10:09 BRFND40.830.14 0.28 Cyclohexane ND 0.20 10/10/19 10:09 BRFND40.690.14 0.49 Dibromochloromethane ND 0.20 10/10/19 10:09 BRFND41.70.066 0.57 1,2-Dibromoethane (EDB)ND 0.20 10/10/19 10:09 BRFND41.50.078 0.60 1,2-Dichlorobenzene ND 0.20 10/10/19 10:09 BRFND41.20.096 0.58 1,3-Dichlorobenzene ND 0.20 10/10/19 10:09 BRFND41.20.10 0.62 1,4-Dichlorobenzene ND 0.20 10/10/19 10:09 BRFND41.20.12 0.73 Dichlorodifluoromethane (Freon 12)ND 0.20 10/10/19 10:09 BRFND40.990.087 0.43 1,1-Dichloroethane ND 0.20 10/10/19 10:09 BRFND40.810.061 0.25 1,2-Dichloroethane ND 0.20 10/10/19 10:09 BRFND40.810.076 0.31 1,1-Dichloroethylene ND 0.20 10/10/19 10:09 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 10/10/19 10:09 BRFND40.790.082 0.32 trans-1,2-Dichloroethylene ND 0.20 10/10/19 10:09 BRFND40.790.081 0.32 1,2-Dichloropropane ND 0.20 10/10/19 10:09 BRFND40.920.071 0.33 cis-1,3-Dichloropropene ND 0.20 10/10/19 10:09 BRFND40.910.070 0.32 trans-1,3-Dichloropropene ND 0.20 10/10/19 10:09 BRFND40.910.073 0.33 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 10/10/19 10:09 BRFND41.40.11 0.79 1,4-Dioxane ND 2.0 10/10/19 10:09 BRFND47.21.3 4.6 Ethanol 11 8.0 10/10/19 10:09 BRF204153.6 6.7 Ethyl Acetate ND 0.20 10/10/19 10:09 BRFND40.720.15 0.54 Ethylbenzene ND 0.20 10/10/19 10:09 BRFND40.870.12 0.50 4-Ethyltoluene ND 0.20 10/10/19 10:09 BRFND40.980.12 0.60 Heptane ND 0.20 10/10/19 10:09 BRFND40.820.12 0.48 Hexachlorobutadiene ND 0.20 10/10/19 10:09 BRFND42.10.092 0.98 Hexane ND 8.0 10/10/19 10:09 BRFND4280.35 1.2 2-Hexanone (MBK)ND 0.20 10/10/19 10:09 BRFND40.820.12 0.48 Isopropanol ND 8.0 10/10/19 10:09 BRFND4200.37 0.90 Methyl tert-Butyl Ether (MTBE)ND 0.20 10/10/19 10:09 BRFND40.720.10 0.36 Methylene Chloride ND 2.0 10/10/19 10:09 BRFND46.90.24 0.84 4-Methyl-2-pentanone (MIBK)ND 0.20 10/10/19 10:09 BRFND40.820.10 0.43 Naphthalene ND 0.20 10/10/19 10:09 BRFND41.00.15 0.80 Propene ND 8.0 10/10/19 10:09 BRFND4140.37 0.64 Styrene ND 0.20 10/10/19 10:09 BRFND40.850.12 0.53 1,1,2,2-Tetrachloroethane ND 0.20 10/10/19 10:09 BRFND41.40.089 0.61 Page 9 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/4/2019 Work Order: 19J0555Sample Description/Location: Field Sample #: Dup-1 Sample ID: 19J0555-03 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -6 Receipt Vacuum(in Hg): -9.2 Sampled: 10/4/2019 00:00 Canister ID: 2328 Flow Controller ID: 4205 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 1.9 0.20 10/10/19 10:09 BRF1341.40.11 0.75 Tetrahydrofuran 13 0.20 10/10/19 10:09 BRF3840.590.20 0.59 Toluene 2.0 0.20 10/10/19 10:09 BRF7.6 40.750.10 0.39 1,2,4-Trichlorobenzene ND 0.20 10/10/19 10:09 BRFND41.50.14 1.0 1,1,1-Trichloroethane ND 0.20 10/10/19 10:09 BRFND41.10.075 0.41 1,1,2-Trichloroethane ND 0.20 10/10/19 10:09 BRFND41.10.082 0.45 Trichloroethylene ND 0.20 10/10/19 10:09 BRFND41.10.081 0.43 Trichlorofluoromethane (Freon 11)0.64 0.80 10/10/19 10:09 BRFJ3.6 44.50.15 0.85 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 10/10/19 10:09 BRFND46.10.15 1.2 1,2,4-Trimethylbenzene 0.30 0.20 10/10/19 10:09 BRF1.5 40.980.13 0.63 1,3,5-Trimethylbenzene ND 0.20 10/10/19 10:09 BRFND40.980.13 0.62 Vinyl Acetate ND 4.0 10/10/19 10:09 BRFND4140.12 0.44 Vinyl Chloride ND 0.20 10/10/19 10:09 BRFND40.510.13 0.32 m&p-Xylene 0.61 0.40 10/10/19 10:09 BRF2.6 41.70.23 1.00 o-Xylene 0.26 0.20 10/10/19 10:09 BRF1.1 40.870.12 0.54 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)101 10/10/19 10:0970-130 Page 10 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Sample Extraction Data Prep Method: TO-15 Prep-EPA TO-15 Lab Number [Field ID]Batch Date Pressure Dilution Pre Dilution Pre-Dil Initial mL Pre-Dil Final mL Default Injection mL Actual Injection mL 19J0555-02 [SS-Bld4-MP-6]B242848 1.5 1 N/A 1000 400 150 10/09/19 19J0555-03 [Dup-1]B242848 1.5 1 N/A 1000 400 150 10/09/19 Prep Method: TO-15 Prep-EPA TO-15 Lab Number [Field ID]Batch Date Pressure Dilution Pre Dilution Pre-Dil Initial mL Pre-Dil Final mL Default Injection mL Actual Injection mL 19J0555-01 [SS-Bld4-MP-3]B242855 1.5 1 N/A 1000 400 150 10/09/19 Page 11 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B242848 - TO-15 Prep Blank (B242848-BLK1)Prepared & Analyzed: 10/09/19 1.4NDAcetone 0.035NDBenzene 0.035NDBenzyl chloride 0.035NDBromodichloromethane 0.035NDBromoform 0.035NDBromomethane 0.035ND1,3-Butadiene 1.4ND2-Butanone (MEK) 0.35NDCarbon Disulfide 0.035NDCarbon Tetrachloride 0.035NDChlorobenzene 0.035NDChloroethane 0.035NDChloroform 0.070NDChloromethane 0.035NDCyclohexane 0.035NDDibromochloromethane 0.035ND1,2-Dibromoethane (EDB) 0.035ND1,2-Dichlorobenzene 0.035ND1,3-Dichlorobenzene 0.035ND1,4-Dichlorobenzene 0.035NDDichlorodifluoromethane (Freon 12) 0.035ND1,1-Dichloroethane 0.035ND1,2-Dichloroethane 0.035ND1,1-Dichloroethylene 0.035NDcis-1,2-Dichloroethylene 0.035NDtrans-1,2-Dichloroethylene 0.035ND1,2-Dichloropropane 0.035NDcis-1,3-Dichloropropene 0.035NDtrans-1,3-Dichloropropene 0.035ND1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.35ND1,4-Dioxane 1.4NDEthanol 0.035NDEthyl Acetate 0.035NDEthylbenzene 0.035ND4-Ethyltoluene 0.035NDHeptane 0.035NDHexachlorobutadiene 1.4NDHexane 0.035ND2-Hexanone (MBK) 1.4NDIsopropanol 0.035NDMethyl tert-Butyl Ether (MTBE) 0.35NDMethylene Chloride 0.035ND4-Methyl-2-pentanone (MIBK) 0.035NDNaphthalene 1.4NDPropene 0.035NDStyrene Page 12 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B242848 - TO-15 Prep Blank (B242848-BLK1)Prepared & Analyzed: 10/09/19 0.035ND1,1,2,2-Tetrachloroethane 0.035NDTetrachloroethylene 0.035NDTetrahydrofuran 0.035NDToluene 0.035ND1,2,4-Trichlorobenzene 0.035ND1,1,1-Trichloroethane 0.035ND1,1,2-Trichloroethane 0.035NDTrichloroethylene 0.14NDTrichlorofluoromethane (Freon 11) 0.14ND1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 0.035ND1,2,4-Trimethylbenzene 0.035ND1,3,5-Trimethylbenzene 0.70NDVinyl Acetate 0.035NDVinyl Chloride 0.070NDm&p-Xylene 0.035NDo-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)97.17.76 LCS (B242848-BS1)Prepared & Analyzed: 10/09/19 5.00 70-13083.84.19Acetone 5.00 70-13082.84.14Benzene 5.00 70-1301105.50Benzyl chloride 5.00 70-13090.14.51Bromodichloromethane 5.00 70-13087.64.38Bromoform 5.00 70-1301195.95Bromomethane 5.00 70-13081.94.091,3-Butadiene 5.00 70-13077.33.862-Butanone (MEK) 5.00 70-13075.63.78Carbon Disulfide 5.00 70-13090.74.54Carbon Tetrachloride 5.00 70-13079.94.00Chlorobenzene 5.00 70-1301195.95Chloroethane 5.00 70-13072.93.64Chloroform 5.00 70-13091.64.58Chloromethane 5.00 70-13083.24.16Cyclohexane 5.00 70-13084.54.23Dibromochloromethane 5.00 70-13081.44.071,2-Dibromoethane (EDB) 5.00 70-13093.34.661,2-Dichlorobenzene 5.00 70-13089.74.491,3-Dichlorobenzene 5.00 70-13088.74.441,4-Dichlorobenzene 5.00 70-13087.44.37Dichlorodifluoromethane (Freon 12) 5.00 70-13073.03.651,1-Dichloroethane 5.00 70-13086.04.301,2-Dichloroethane 5.00 70-13097.04.851,1-Dichloroethylene 5.00 70-13074.53.73cis-1,2-Dichloroethylene 5.00 70-13073.33.67trans-1,2-Dichloroethylene 5.00 70-13084.24.211,2-Dichloropropane Page 13 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B242848 - TO-15 Prep LCS (B242848-BS1)Prepared & Analyzed: 10/09/19 5.00 70-13084.94.24cis-1,3-Dichloropropene 5.00 70-1301055.24trans-1,3-Dichloropropene 5.00 70-13070.53.521,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 5.00 70-13092.84.641,4-Dioxane 5.00 70-13095.04.75Ethanol 5.00 70-13083.84.19Ethyl Acetate 5.00 70-13083.44.17Ethylbenzene 5.00 70-13086.64.334-Ethyltoluene 5.00 70-13085.54.27Heptane 5.00 70-13088.84.44Hexachlorobutadiene 5.00 70-13093.64.68Hexane 5.00 70-13095.94.802-Hexanone (MBK) 5.00 70-13070.63.53Isopropanol 5.00 70-13074.63.73Methyl tert-Butyl Ether (MTBE) 5.00 70-13075.43.77Methylene Chloride 5.00 70-1301045.204-Methyl-2-pentanone (MIBK) 5.00 70-1301135.65Naphthalene 5.00 70-13079.63.98Propene 5.00 70-13091.24.56Styrene 5.00 70-13086.64.331,1,2,2-Tetrachloroethane 5.00 70-13074.53.72Tetrachloroethylene 5.00 70-13084.24.21Tetrahydrofuran 5.00 70-13078.83.94Toluene 5.00 70-1301125.591,2,4-Trichlorobenzene 5.00 70-13082.34.111,1,1-Trichloroethane 5.00 70-13080.64.031,1,2-Trichloroethane 5.00 70-13077.23.86Trichloroethylene 5.00 70-1301015.06Trichlorofluoromethane (Freon 11) 5.00 70-13071.13.551,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 5.00 70-13087.84.391,2,4-Trimethylbenzene 5.00 70-13082.64.131,3,5-Trimethylbenzene 5.00 70-13078.83.94Vinyl Acetate 5.00 70-13078.33.91Vinyl Chloride 10.0 70-13085.98.59m&p-Xylene 5.00 70-13081.64.08o-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)98.87.90 Page 14 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B242855 - TO-15 Prep Blank (B242855-BLK1)Prepared & Analyzed: 10/09/19 1.4NDAcetone 0.035NDBenzene 0.035NDBenzyl chloride 0.035NDBromodichloromethane 0.035NDBromoform 0.035NDBromomethane 0.035ND1,3-Butadiene 1.4ND2-Butanone (MEK) 0.35NDCarbon Disulfide 0.035NDCarbon Tetrachloride 0.035NDChlorobenzene 0.035NDChloroethane 0.035NDChloroform 0.070NDChloromethane 0.035NDCyclohexane 0.035NDDibromochloromethane 0.035ND1,2-Dibromoethane (EDB) 0.035ND1,2-Dichlorobenzene 0.035ND1,3-Dichlorobenzene 0.035ND1,4-Dichlorobenzene 0.035NDDichlorodifluoromethane (Freon 12) 0.035ND1,1-Dichloroethane 0.035ND1,2-Dichloroethane 0.035ND1,1-Dichloroethylene 0.035NDcis-1,2-Dichloroethylene 0.035NDtrans-1,2-Dichloroethylene 0.035ND1,2-Dichloropropane 0.035NDcis-1,3-Dichloropropene 0.035NDtrans-1,3-Dichloropropene 0.035ND1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.35ND1,4-Dioxane 1.4NDEthanol 0.035NDEthyl Acetate 0.035NDEthylbenzene 0.035ND4-Ethyltoluene 0.035NDHeptane 0.035NDHexachlorobutadiene 1.4NDHexane 0.035ND2-Hexanone (MBK) 1.4NDIsopropanol 0.035NDMethyl tert-Butyl Ether (MTBE) 0.35NDMethylene Chloride 0.035ND4-Methyl-2-pentanone (MIBK) 0.035 V-06NDNaphthalene 1.4NDPropene 0.035NDStyrene Page 15 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B242855 - TO-15 Prep Blank (B242855-BLK1)Prepared & Analyzed: 10/09/19 0.035ND1,1,2,2-Tetrachloroethane 0.035NDTetrachloroethylene 0.035NDTetrahydrofuran 0.035NDToluene 0.035ND1,2,4-Trichlorobenzene 0.035ND1,1,1-Trichloroethane 0.035ND1,1,2-Trichloroethane 0.035NDTrichloroethylene 0.14NDTrichlorofluoromethane (Freon 11) 0.14ND1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 0.035ND1,2,4-Trimethylbenzene 0.035ND1,3,5-Trimethylbenzene 0.70NDVinyl Acetate 0.035NDVinyl Chloride 0.070NDm&p-Xylene 0.035NDo-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1098.74 LCS (B242855-BS1)Prepared & Analyzed: 10/09/19 5.00 70-1301175.84Acetone 5.00 70-13091.24.56Benzene 5.00 70-1301246.22Benzyl chloride 5.00 70-13088.84.44Bromodichloromethane 5.00 70-1301035.14Bromoform 5.00 70-1301015.05Bromomethane 5.00 70-13096.74.841,3-Butadiene 5.00 70-13090.64.532-Butanone (MEK) 5.00 70-13091.04.55Carbon Disulfide 5.00 70-13084.44.22Carbon Tetrachloride 5.00 70-13093.44.67Chlorobenzene 5.00 70-1301015.07Chloroethane 5.00 70-13086.94.34Chloroform 5.00 70-13086.54.32Chloromethane 5.00 70-13079.94.00Cyclohexane 5.00 70-13092.44.62Dibromochloromethane 5.00 70-13091.74.591,2-Dibromoethane (EDB) 5.00 70-1301226.081,2-Dichlorobenzene 5.00 70-1301155.761,3-Dichlorobenzene 5.00 70-1301175.851,4-Dichlorobenzene 5.00 70-13091.44.57Dichlorodifluoromethane (Freon 12) 5.00 70-13085.84.291,1-Dichloroethane 5.00 70-13085.84.291,2-Dichloroethane 5.00 70-13084.84.241,1-Dichloroethylene 5.00 70-13084.74.23cis-1,2-Dichloroethylene 5.00 70-13085.94.29trans-1,2-Dichloroethylene 5.00 70-13080.24.011,2-Dichloropropane Page 16 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B242855 - TO-15 Prep LCS (B242855-BS1)Prepared & Analyzed: 10/09/19 5.00 70-13085.74.28cis-1,3-Dichloropropene 5.00 70-13091.94.59trans-1,3-Dichloropropene 5.00 70-13097.64.881,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 5.00 70-1301266.281,4-Dioxane 5.00 70-1301206.01Ethanol 5.00 70-13087.74.39Ethyl Acetate 5.00 70-13094.84.74Ethylbenzene 5.00 70-1301075.374-Ethyltoluene 5.00 70-13088.34.42Heptane 5.00 70-1301145.70Hexachlorobutadiene 5.00 70-13089.24.46Hexane 5.00 70-1301015.052-Hexanone (MBK) 5.00 70-1301085.41Isopropanol 5.00 70-13085.74.29Methyl tert-Butyl Ether (MTBE) 5.00 70-13078.13.90Methylene Chloride 5.00 70-13098.04.904-Methyl-2-pentanone (MIBK) 5.00 V-06, Z-01, V-35 70-1301507.48Naphthalene * 5.00 70-13082.14.10Propene 5.00 70-13096.54.83Styrene 5.00 70-1301045.221,1,2,2-Tetrachloroethane 5.00 70-13088.94.45Tetrachloroethylene 5.00 70-13099.14.96Tetrahydrofuran 5.00 70-13092.44.62Toluene 5.00 L-01, V-3670-1301467.311,2,4-Trichlorobenzene * 5.00 70-13080.04.001,1,1-Trichloroethane 5.00 70-13091.64.581,1,2-Trichloroethane 5.00 70-13089.44.47Trichloroethylene 5.00 70-1301075.35Trichlorofluoromethane (Freon 11) 5.00 70-13087.64.381,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 5.00 70-1301155.751,2,4-Trimethylbenzene 5.00 70-1301075.361,3,5-Trimethylbenzene 5.00 70-13095.54.77Vinyl Acetate 5.00 70-13096.84.84Vinyl Chloride 10.0 70-13010210.2m&p-Xylene 5.00 70-1301005.01o-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1108.76 Page 17 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Note: Blank Subtraction is not performed unless otherwise noted *QC result is outside of established limits. Wide recovery limits established for difficult compound. Wide RPD limits established for difficult compound. #Data exceeded client recommended or regulatory level RL Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference LCS Laboratory Control Sample Laboratory Control SampleLCS Dup Duplicate Laboratory Control Sample MS Matrix Spike Sample MS Dup Duplicate Matrix Spike Sample REC Recovery QC Quality Control ppbv Parts per billion volume EPA United States Environmental Protection Agency Percent Recovery% REC ND Not Detected Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the calculation which have not been rounded. Not ApplicableN/A DL Detection Limit Not CalculatedNC LFB/LCS Lab Fortified Blank/Lab Control Sample ORP Oxidation-Reduction Potential Not dry weight correctedwet Percent weight% wt KilogramKg Gramg Milligrammg Microgramg Nanogramng LiterL MillilitermL Microliter L Cubic Meterm3 Extractable Petroleum HydrocarbonsEPH Volatile Petroleum HydrocarbonsVPH Air Petroleum HydrocarbonsAPH Flame Ionization DetectorFID Photo Ionization DetectorPID FLAG/QUALIFIER SUMMARY Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag). J Laboratory fortified blank /laboratory control sample recovery outside of control limits. Data validation is not affected since all results are "not detected" for all samples in this batch for this compound and bias is on the high side. L-01 Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side for this compound. V-06 Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was "not detected" for this compound. V-20 Initial calibration verification (ICV) did not meet method specifications and was biased on the high side for this compound. Reported result is estimated. V-35 Initial calibration verification (ICV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was "not detected" for this compound. V-36 Compound fails the method requirement of 70-130% recovery for the LCS. Is classified by the lab as a difficult compound and passes the in house limits of 50-150%. Z-01 Page 18 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYST Thomas P. HniteckiTPH Rebecca FaustRLF Kerry K. McGeeKKM Brittany R. FiskBRF Page 19 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q Initial Cal Check (S038528-ICV1 )Lab File ID: B1920819.D Analyzed: 07/27/19 19:24 Bromochloromethane (1)144000 5.05 141846 5.054 60 - 140102 -0.0040 +/-0.50 1,4-Difluorobenzene (1)338979 6.264 331570 6.268 60 - 140102 -0.0040 +/-0.50 Chlorobenzene-d5 (1)300441 9.857 293128 9.861 60 - 140102 -0.0040 +/-0.50 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q Initial Cal Check (S039721-ICV1 )Lab File ID: G1923934.D Analyzed: 08/28/19 12:54 Bromochloromethane (1)443826 8.54 448077 8.54 60 - 14099 0.0000 +/-0.50 1,4-Difluorobenzene (1)1177845 10.32 1185200 10.32 60 - 14099 0.0000 +/-0.50 Chlorobenzene-d5 (1)1032941 14.697 1038060 14.697 60 - 140100 0.0000 +/-0.50 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q Calibration Check (S041295-CCV1 )Lab File ID: B1928204.D Analyzed: 10/09/19 11:45 Bromochloromethane (1)117487 5.055 141846 5.054 60 - 14083 0.0010 +/-0.50 1,4-Difluorobenzene (1)229216 6.268 331570 6.268 60 - 14069 0.0000 +/-0.50 Chlorobenzene-d5 (1)207271 9.862 293128 9.861 60 - 14071 0.0010 +/-0.50 LCS (B242848-BS1 )Lab File ID: B1928205.D Analyzed: 10/09/19 12:14 Bromochloromethane (1)114106 5.058 117487 5.055 60 - 14097 0.0030 +/-0.50 1,4-Difluorobenzene (1)219078 6.272 229216 6.268 60 - 14096 0.0040 +/-0.50 Chlorobenzene-d5 (1)203190 9.859 207271 9.862 60 - 14098 -0.0030 +/-0.50 Blank (B242848-BLK1 )Lab File ID: B1928208.D Analyzed: 10/09/19 13:48 Bromochloromethane (1)111950 5.054 117487 5.055 60 - 14095 -0.0010 +/-0.50 1,4-Difluorobenzene (1)216422 6.268 229216 6.268 60 - 14094 0.0000 +/-0.50 Chlorobenzene-d5 (1)190631 9.855 207271 9.862 60 - 14092 -0.0070 +/-0.50 SS-Bld4-MP-6 (19J0555-02 )Lab File ID: B1928230.D Analyzed: 10/10/19 09:40 Bromochloromethane (1)110895 5.048 117487 5.055 60 - 14094 -0.0070 +/-0.50 1,4-Difluorobenzene (1)209418 6.268 229216 6.268 60 - 14091 0.0000 +/-0.50 Chlorobenzene-d5 (1)181661 9.856 207271 9.862 60 - 14088 -0.0060 +/-0.50 Dup-1 (19J0555-03 )Lab File ID: B1928231.D Analyzed: 10/10/19 10:09 Bromochloromethane (1)113939 5.052 117487 5.055 60 - 14097 -0.0030 +/-0.50 1,4-Difluorobenzene (1)210052 6.266 229216 6.268 60 - 14092 -0.0020 +/-0.50 Chlorobenzene-d5 (1)180658 9.859 207271 9.862 60 - 14087 -0.0030 +/-0.50 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 Page 20 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q Calibration Check (S041300-CCV1 )Lab File ID: G1928204.D Analyzed: 10/09/19 11:34 Bromochloromethane (1)346840 8.534 448077 8.54 60 - 14077 -0.0060 +/-0.50 1,4-Difluorobenzene (1)878084 10.314 1185200 10.32 60 - 14074 -0.0060 +/-0.50 Chlorobenzene-d5 (1)742379 14.691 1038060 14.697 60 - 14072 -0.0060 +/-0.50 LCS (B242855-BS1 )Lab File ID: G1928205.D Analyzed: 10/09/19 12:14 Bromochloromethane (1)352739 8.54 346840 8.534 60 - 140102 0.0060 +/-0.50 1,4-Difluorobenzene (1)895381 10.32 878084 10.314 60 - 140102 0.0060 +/-0.50 Chlorobenzene-d5 (1)798563 14.697 742379 14.691 60 - 140108 0.0060 +/-0.50 Blank (B242855-BLK1 )Lab File ID: G1928208.D Analyzed: 10/09/19 14:28 Bromochloromethane (1)346971 8.54 346840 8.534 60 - 140100 0.0060 +/-0.50 1,4-Difluorobenzene (1)853797 10.32 878084 10.314 60 - 14097 0.0060 +/-0.50 Chlorobenzene-d5 (1)779465 14.691 742379 14.691 60 - 140105 0.0000 +/-0.50 SS-Bld4-MP-3 (19J0555-01 )Lab File ID: G1928228.D Analyzed: 10/10/19 11:19 Bromochloromethane (1)354739 8.54 346840 8.534 60 - 140102 0.0060 +/-0.50 1,4-Difluorobenzene (1)865025 10.314 878084 10.314 60 - 14099 0.0000 +/-0.50 Chlorobenzene-d5 (1)786322 14.691 742379 14.691 60 - 140106 0.0000 +/-0.50 Page 21 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S041295-CCV1 COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR STD 0.9462698A -10.9 304.46 1.0615015.00Acetone 0.7918959A -9.3 304.53 0.87352065.00Benzene 0.8196033A 17.1 305.86 0.69964655.00Benzyl chloride 0.5953232A -1.3 304.93 0.60340275.00Bromodichloromethane 0.568863A 1.6 305.08 0.55983515.00Bromoform 0.7327721L 22.8 306.14 0.76718815.00Bromomethane 0.4728353A -8.5 304.58 0.51654375.001,3-Butadiene 1.264971A -16.3 304.19 1.5106525.002-Butanone (MEK) 1.692552A -13.3 304.34 1.9511025.00Carbon Disulfide 0.4932221A 0.5 305.02 0.49074395.00Carbon Tetrachloride 0.6843832A -10.8 304.46 0.76711435.00Chlorobenzene 0.417939A 27.2 306.36 0.32866245.00Chloroethane 1.078478A -19.4 304.03 1.3380965.00Chloroform 0.6261254L 1.7 305.08 0.76008055.00Chloromethane 0.3624459A -8.7 304.57 0.39683775.00Cyclohexane 0.5907551A -3.7 304.82 0.61317595.00Dibromochloromethane 0.481418A -7.2 304.64 0.51888315.001,2-Dibromoethane (EDB) 0.5758799A 4.2 305.21 0.55290515.001,2-Dichlorobenzene 0.6106633A -0.8 304.96 0.61564225.001,3-Dichlorobenzene 0.6049047A -2.8 304.86 0.62224625.001,4-Dichlorobenzene 1.443346A -3.5 304.82 1.4963295.00Dichlorodifluoromethane (Freon 12) 0.9207487A -20.7 303.96 1.1616095.001,1-Dichloroethane 0.7443343A -3.9 304.81 0.77441815.001,2-Dichloroethane 1.094031A 13.8 305.69 0.96096445.001,1-Dichloroethylene 0.7158171A -16.7 304.16 0.85939785.00cis-1,2-Dichloroethylene 0.7596415A -18.9 304.05 0.93699095.00trans-1,2-Dichloroethylene 0.2869817A -7.1 304.64 0.30891335.001,2-Dichloropropane 0.4919657A -2.9 304.86 0.50654855.00cis-1,3-Dichloropropene 0.447166A 13.3 305.66 0.39484455.00trans-1,3-Dichloropropene 1.460097A -21.3 303.94 1.854975.001,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.1407441A -6.4 304.68 0.15031965.001,4-Dioxane 0.1724242L -20.0 304.00 0.23610955.00Ethanol 0.2323729A -1.5 304.92 0.23592385.00Ethyl Acetate 1.182151A -5.8 304.71 1.2549035.00Ethylbenzene 1.141956A -2.4 304.88 1.1706165.004-Ethyltoluene 0.2592908A -5.2 304.74 0.27352385.00Heptane 0.4012988A 11.7 305.59 0.35914075.00Hexachlorobutadiene 0.4127095L 2.6 305.13 0.4924525.00Hexane Page 22 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S041295-CCV1 COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR STD 0.7766451A 4.8 305.24 0.74091225.002-Hexanone (MBK) 0.9448262L -22.1 303.90 1.4903085.00Isopropanol 1.541508A -16.5 304.18 1.8460425.00Methyl tert-Butyl Ether (MTBE) 0.6897376A -17.9 304.10 0.84025945.00Methylene Chloride 0.8135837A 13.6 305.68 0.71617985.004-Methyl-2-pentanone (MIBK) 0.5718504A -5.5 304.73 0.60499385.00Naphthalene 0.5126967A -12.3 304.39 0.58429395.00Propene 0.6743249A 4.2 305.21 0.64731585.00Styrene 0.7535024A -1.8 304.91 0.76749595.001,1,2,2-Tetrachloroethane 0.4228358A -14.3 304.29 0.49319615.00Tetrachloroethylene 0.7854622A -11.2 304.44 0.88485125.00Tetrahydrofuran 0.8796368A -11.3 304.44 0.99170295.00Toluene 0.3324343A 11.3 305.57 0.29858065.001,2,4-Trichlorobenzene 0.4805389A -2.5 304.88 0.49290825.001,1,1-Trichloroethane 0.3072692A -9.1 304.55 0.33794775.001,1,2-Trichloroethane 0.30178A -15.6 304.22 0.3573855.00Trichloroethylene 1.536497A 7.6 305.38 1.4284065.00Trichlorofluoromethane (Freon 11) 1.071574A -16.9 304.15 1.2900045.001,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 0.9010812A 1.2 305.06 0.89039045.001,2,4-Trimethylbenzene 0.8986573A -3.8 304.81 0.93440445.001,3,5-Trimethylbenzene 1.594539A -18.1 304.09 1.9477115.00Vinyl Acetate 0.6085848A -12.7 304.36 0.69706395.00Vinyl Chloride 0.9055468A -2.7 309.73 0.930339610.0m&p-Xylene 0.8679883A -6.8 304.66 0.93116995.00o-Xylene * Values outside of QC limits # Column to be used to flag Response Factor and %Diff/Drift values with an asterisk Page 23 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S041300-CCV1 COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR STD 0.9393611A -6.0 304.70 0.99961265.00Acetone 0.7147872A -14.5 304.27 0.83623785.00Benzene 0.895021A 20.2 306.01 0.74443445.00Benzyl chloride 0.5343616A -16.0 304.20 0.63603055.00Bromodichloromethane 0.4647675A 2.1 305.11 0.45504915.00Bromoform 0.4911729A -9.3 304.54 0.54132125.00Bromomethane 0.4541714A -10.4 304.48 0.50716885.001,3-Butadiene 1.137461A -20.9 303.96 1.4377265.002-Butanone (MEK) 1.587891A -17.4 304.13 1.9227635.00Carbon Disulfide 0.4340487A -18.8 304.06 0.53432965.00Carbon Tetrachloride 0.7516721A -7.8 304.61 0.81570025.00Chlorobenzene 0.3000115A -7.6 304.62 0.32457535.00Chloroethane 1.211823A -19.5 304.02 1.5053385.00Chloroform 0.5358644A -18.5 304.07 0.65780215.00Chloromethane 0.2934116A -25.3 303.74 0.39262855.00Cyclohexane 0.5455736A -7.7 304.62 0.59077775.00Dibromochloromethane 0.5109455A -8.4 304.58 0.55789985.001,2-Dibromoethane (EDB) 0.5639405A 12.1 305.60 0.50315635.001,2-Dichlorobenzene 0.6335847A 8.7 305.44 0.58266515.001,3-Dichlorobenzene 0.6294575A 11.3 305.57 0.5654365.001,4-Dichlorobenzene 1.254236A -19.8 304.01 1.5644055.00Dichlorodifluoromethane (Freon 12) 1.053406A -20.6 303.97 1.3260735.001,1-Dichloroethane 0.7897451A -19.8 304.01 0.98468945.001,2-Dichloroethane 0.9151424A -20.3 303.99 1.1478185.001,1-Dichloroethylene 0.7710253A -19.7 304.02 0.96023265.00cis-1,2-Dichloroethylene 0.7938554A -20.1 304.00 0.99320255.00trans-1,2-Dichloroethylene 0.2672455A -24.7 303.76 0.35490555.001,2-Dichloropropane 0.4250236A -16.0 304.20 0.50593535.00cis-1,3-Dichloropropene 0.3662848A -14.7 304.26 0.42958615.00trans-1,3-Dichloropropene 1.449494A -4.6 304.77 1.5201345.001,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.115845A -4.6 304.77 0.12148585.001,4-Dioxane 0.1644286A -0.05 305.00 0.16451035.00Ethanol 0.2018176A -13.6 304.32 0.23350695.00Ethyl Acetate 1.284248A -6.4 304.68 1.372735.00Ethylbenzene 1.311888A 3.5 305.18 1.2672815.004-Ethyltoluene 0.2251119A -15.2 304.24 0.26558315.00Heptane 0.3146102A 8.1 305.41 0.29095965.00Hexachlorobutadiene 0.7023411L -17.0 304.15 0.88199185.00Hexane Page 24 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S041300-CCV1 COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR STD 0.5453775A -13.6 304.32 0.63147455.002-Hexanone (MBK) 0.9119917A -4.8 304.76 0.95826045.00Isopropanol 1.528511A -20.4 303.98 1.9200895.00Methyl tert-Butyl Ether (MTBE) 0.6639326A -25.1 303.75 0.88594165.00Methylene Chloride 0.5351124A -14.4 304.28 0.62524415.004-Methyl-2-pentanone (MIBK) 0.832155A 31.1 *306.56 0.63467515.00Naphthalene 0.4706677A -22.5 303.88 0.60737565.00Propene 0.7214945A -1.6 304.92 0.73358725.00Styrene 0.7446331A -1.0 304.95 0.75229625.001,1,2,2-Tetrachloroethane 0.3932956A -9.5 304.52 0.43465195.00Tetrachloroethylene 0.2253812A -18.4 304.08 0.27604855.00Tetrahydrofuran 0.993929A -9.3 304.53 1.0964045.00Toluene 0.3533031A 30.6 *306.53 0.27053115.001,2,4-Trichlorobenzene 0.4582578A -18.6 304.07 0.56291675.001,1,1-Trichloroethane 0.3396777A -9.0 304.55 0.37310615.001,1,2-Trichloroethane 0.3016604A -15.9 304.20 0.35871675.00Trichloroethylene 1.262217A -2.8 304.86 1.2982285.00Trichlorofluoromethane (Freon 11) 1.108084A -17.9 304.10 1.3502655.001,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 1.042961A 9.4 305.47 0.95318085.001,2,4-Trimethylbenzene 1.083666A 5.6 305.28 1.0263565.001,3,5-Trimethylbenzene 1.739112A -14.8 304.26 2.04035.00Vinyl Acetate 0.6134148A -9.5 304.52 0.67807755.00Vinyl Chloride 1.006817A 1.3 3010.1 0.994156610.0m&p-Xylene 1.025132A -1.5 304.92 1.041015.00o-Xylene * Values outside of QC limits # Column to be used to flag Response Factor and %Diff/Drift values with an asterisk Page 25 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,NY,ME,NHAcetone AIHA,NY,ME,NHAcetone AIHA,FL,NJ,NY,ME,NH,VABenzene AIHA,FL,NJ,NY,ME,NH,VABenzene AIHA,FL,NJ,NY,ME,NH,VABenzyl chloride AIHA,FL,NJ,NY,ME,NH,VABenzyl chloride AIHA,NJ,NY,ME,NH,VABromodichloromethane AIHA,NJ,NY,ME,NH,VABromodichloromethane AIHA,NJ,NY,ME,NH,VABromoform AIHA,NJ,NY,ME,NH,VABromoform AIHA,FL,NJ,NY,ME,NHBromomethane AIHA,FL,NJ,NY,ME,NHBromomethane AIHA,NJ,NY,ME,NH,VA1,3-Butadiene AIHA,NJ,NY,ME,NH,VA1,3-Butadiene AIHA,FL,NJ,NY,ME,NH,VA2-Butanone (MEK) AIHA,FL,NJ,NY,ME,NH,VA2-Butanone (MEK) AIHA,NJ,NY,ME,NH,VACarbon Disulfide AIHA,NJ,NY,ME,NH,VACarbon Disulfide AIHA,FL,NJ,NY,ME,NH,VACarbon Tetrachloride AIHA,FL,NJ,NY,ME,NH,VACarbon Tetrachloride AIHA,FL,NJ,NY,ME,NH,VAChlorobenzene AIHA,FL,NJ,NY,ME,NH,VAChlorobenzene AIHA,FL,NJ,NY,ME,NH,VAChloroethane AIHA,FL,NJ,NY,ME,NH,VAChloroethane AIHA,FL,NJ,NY,ME,NH,VAChloroform AIHA,FL,NJ,NY,ME,NH,VAChloroform AIHA,FL,NJ,NY,ME,NH,VAChloromethane AIHA,FL,NJ,NY,ME,NH,VAChloromethane AIHA,NJ,NY,ME,NH,VACyclohexane AIHA,NJ,NY,ME,NH,VACyclohexane AIHA,NY,ME,NHDibromochloromethane AIHA,NY,ME,NHDibromochloromethane AIHA,NJ,NY,ME,NH1,2-Dibromoethane (EDB) AIHA,NJ,NY,ME,NH1,2-Dibromoethane (EDB) AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichlorobenzene AIHA,NJ,NY,ME,NH1,3-Dichlorobenzene AIHA,NJ,NY,ME,NH1,3-Dichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,4-Dichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,4-Dichlorobenzene AIHA,NY,ME,NHDichlorodifluoromethane (Freon 12) AIHA,NY,ME,NHDichlorodifluoromethane (Freon 12) AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethylene Page 26 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethylene AIHA,FL,NY,ME,NH,VAcis-1,2-Dichloroethylene AIHA,FL,NY,ME,NH,VAcis-1,2-Dichloroethylene AIHA,NJ,NY,ME,NH,VAtrans-1,2-Dichloroethylene AIHA,NJ,NY,ME,NH,VAtrans-1,2-Dichloroethylene AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloropropane AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloropropane AIHA,FL,NJ,NY,ME,NH,VAcis-1,3-Dichloropropene AIHA,FL,NJ,NY,ME,NH,VAcis-1,3-Dichloropropene AIHA,NY,ME,NHtrans-1,3-Dichloropropene AIHA,NY,ME,NHtrans-1,3-Dichloropropene AIHA,NJ,NY,ME,NH,VA1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) AIHA,NJ,NY,ME,NH,VA1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) AIHA,NJ,NY,ME,NH,VA1,4-Dioxane AIHA,NJ,NY,ME,NH,VA1,4-Dioxane AIHAEthanol AIHAEthanol AIHAEthyl Acetate AIHAEthyl Acetate AIHA,FL,NJ,NY,ME,NH,VAEthylbenzene AIHA,FL,NJ,NY,ME,NH,VAEthylbenzene AIHA,NJ4-Ethyltoluene AIHA,NJ4-Ethyltoluene AIHA,NJ,NY,ME,NH,VAHeptane AIHA,NJ,NY,ME,NH,VAHeptane AIHA,NJ,NY,ME,NH,VAHexachlorobutadiene AIHA,NJ,NY,ME,NH,VAHexachlorobutadiene AIHA,FL,NJ,NY,ME,NH,VAHexane AIHA,FL,NJ,NY,ME,NH,VAHexane AIHA2-Hexanone (MBK) AIHA2-Hexanone (MBK) AIHA,NY,ME,NHIsopropanol AIHA,NY,ME,NHIsopropanol AIHA,FL,NJ,NY,ME,NH,VAMethyl tert-Butyl Ether (MTBE) AIHA,FL,NJ,NY,ME,NH,VAMethyl tert-Butyl Ether (MTBE) AIHA,FL,NJ,NY,ME,NH,VAMethylene Chloride AIHA,FL,NJ,NY,ME,NH,VAMethylene Chloride AIHA,FL,NJ,NY,ME,NH4-Methyl-2-pentanone (MIBK) AIHA,FL,NJ,NY,ME,NH4-Methyl-2-pentanone (MIBK) NY,ME,NHNaphthalene NY,ME,NHNaphthalene AIHAPropene AIHAPropene AIHA,FL,NJ,NY,ME,NH,VAStyrene AIHA,FL,NJ,NY,ME,NH,VAStyrene AIHA,FL,NJ,NY,ME,NH,VA1,1,2,2-Tetrachloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1,2,2-Tetrachloroethane Page 27 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,FL,NJ,NY,ME,NH,VATetrachloroethylene AIHA,FL,NJ,NY,ME,NH,VATetrachloroethylene AIHATetrahydrofuran AIHATetrahydrofuran AIHA,FL,NJ,NY,ME,NH,VAToluene AIHA,FL,NJ,NY,ME,NH,VAToluene AIHA,NJ,NY,ME,NH,VA1,2,4-Trichlorobenzene AIHA,NJ,NY,ME,NH,VA1,2,4-Trichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,1,1-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1,1-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1,2-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1,2-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VATrichloroethylene AIHA,FL,NJ,NY,ME,NH,VATrichloroethylene AIHA,NY,ME,NHTrichlorofluoromethane (Freon 11) AIHA,NY,ME,NHTrichlorofluoromethane (Freon 11) AIHA,NJ,NY,ME,NH,VA1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) AIHA,NJ,NY,ME,NH,VA1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) AIHA,NJ,NY,ME,NH1,2,4-Trimethylbenzene AIHA,NJ,NY,ME,NH1,2,4-Trimethylbenzene AIHA,NJ,NY,ME,NH1,3,5-Trimethylbenzene AIHA,NJ,NY,ME,NH1,3,5-Trimethylbenzene AIHA,FL,NJ,NY,ME,NH,VAVinyl Acetate AIHA,FL,NJ,NY,ME,NH,VAVinyl Acetate AIHA,FL,NJ,NY,ME,NH,VAVinyl Chloride AIHA,FL,NJ,NY,ME,NH,VAVinyl Chloride AIHA,FL,NJ,NY,ME,NH,VAm&p-Xylene AIHA,FL,NJ,NY,ME,NH,VAm&p-Xylene AIHA,FL,NJ,NY,ME,NH,VAo-Xylene AIHA,FL,NJ,NY,ME,NH,VAo-Xylene Page 28 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 The CON-TEST Environmental Laboratory operates under the following certifications and accreditations: Code Description Number Expires 100033AIHA-LAP, LLC - ISO17025:2017AIHA 03/1/2020 M-MA100Massachusetts DEPMA 06/30/2020 PH-0567Connecticut Department of Publilc HealthCT 09/30/2021 10899 NELAPNew York State Department of HealthNY 04/1/2020 2516 NELAPNew Hampshire Environmental LabNH-S 02/5/2020 LAO00112Rhode Island Department of HealthRI 12/30/2019 652North Carolina Div. of Water QualityNC 12/31/2019 MA007 NELAPNew Jersey DEPNJ 06/30/2020 E871027 NELAPFlorida Department of HealthFL 06/30/2020 LL015036Vermont Department of Health Lead LaboratoryVT 07/30/2020 2011028State of MaineME 06/9/2021 460217Commonwealth of VirginiaVA 12/14/2019 2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2020 VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2020 25703North Carolina Department of HealthNC-DW 07/31/2020 68-05812Commonwealth of Pennsylvania DEPPA 06/30/2020 Page 29 of 32 Page 30 of 32 Page 31 of 32 Page 32 of 32 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 November 21, 2019 Andrew Besu Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 Project Location: Belmont, NC Client Job Number: Project Number: BKL-001 Laboratory Work Order Number: 19J1394 Enclosed are results of analyses for samples received by the laboratory on October 21, 2019. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kerry K. McGee Project Manager QA Officer Katherine Allen Laboratory Manager Daren Damboragian Page 1 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL SUMMARY 11/21/2019Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 ATTN: Andrew Besu BKL-001 19J1394 The results of analyses performed on the following samples submitted to the CON-TEST Analytical Laboratory are found in this report. PROJECT LOCATION: PURCHASE ORDER NUMBER: PROJECT NUMBER: REPORT DATE: WORK ORDER NUMBER: FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB Belmont, NC BKL-001 SS-Bld5-MP-3 19J1394-01 Sub Slab - EPA TO-15 SS-Bld5-MP-5 19J1394-02 Sub Slab - EPA TO-15 SS-Bld5-MP-8 19J1394-03 Sub Slab - EPA TO-15 DUP-1 19J1394-04 Sub Slab EPA TO-15 Page 2 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CASE NARRATIVE SUMMARY All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report. REVISED REPORT - 11/21/2019 - Report full TO-15 list per client’s request. EPA TO-15 Qualifications: Laboratory fortified blank /laboratory control sample recovery outside of control limits. Data validation is not affected since all results are "not detected" for all samples in this batch for this compound and bias is on the high side. Analyte & Samples(s) Qualified: 1,2,4-Trichlorobenzene, Naphthalene B244404-BS1 The results of analyses reported only relate to samples submitted to the Con-Test Analytical Laboratory for testing. I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Tod E. Kopyscinski Laboratory Director Page 3 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/21/2019 Work Order: 19J1394Sample Description/Location: Field Sample #: SS-Bld5-MP-3 Sample ID: 19J1394-01 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -5.9 Sampled: 10/18/2019 11:35 Canister ID: 2099 Flow Controller ID: 4224 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 6.0 8.0 10/25/19 18:48 BRFJ144192.8 6.6 Acetone 6.0 8.0 10/25/19 18:48 BRFJ144192.8 6.6 Benzene 0.12 0.20 10/25/19 18:48 BRFJ0.38 40.640.082 0.26 Benzene 0.12 0.20 10/25/19 18:48 BRFJ0.38 40.640.082 0.26 Benzyl chloride ND 0.20 10/25/19 18:48 BRFND41.00.052 0.27 Bromodichloromethane ND 0.20 10/25/19 18:48 BRFND41.30.074 0.49 Bromodichloromethane ND 0.20 10/25/19 18:48 BRFND41.30.074 0.49 Bromoform ND 0.20 10/25/19 18:48 BRFND42.10.090 0.93 Bromomethane ND 2.0 10/25/19 18:48 BRFND47.80.14 0.53 1,3-Butadiene ND 0.20 10/25/19 18:48 BRFND40.440.15 0.32 2-Butanone (MEK)1.3 8.0 10/25/19 18:48 BRFJ3.9 4240.37 1.1 2-Butanone (MEK)1.3 8.0 10/25/19 18:48 BRFJ3.9 4240.37 1.1 Carbon Disulfide ND 2.0 10/25/19 18:48 BRFND46.20.14 0.43 Carbon Disulfide ND 2.0 10/25/19 18:48 BRFND46.20.14 0.43 Carbon Tetrachloride ND 0.20 10/25/19 18:48 BRFND41.30.065 0.41 Carbon Tetrachloride ND 0.20 10/25/19 18:48 BRFND41.30.065 0.41 Chlorobenzene ND 0.20 10/25/19 18:48 BRFND40.920.098 0.45 Chloroethane ND 0.20 10/25/19 18:48 BRFND40.530.20 0.52 Chloroform 0.20 0.20 10/25/19 18:48 BRF0.98 40.980.074 0.36 Chloroform 0.20 0.20 10/25/19 18:48 BRF0.98 40.980.074 0.36 Chloromethane ND 0.40 10/25/19 18:48 BRFND40.830.14 0.28 Chloromethane ND 0.40 10/25/19 18:48 BRFND40.830.14 0.28 Cyclohexane ND 0.20 10/25/19 18:48 BRFND40.690.14 0.49 Cyclohexane ND 0.20 10/25/19 18:48 BRFND40.690.14 0.49 Dibromochloromethane ND 0.20 10/25/19 18:48 BRFND41.70.066 0.57 Dibromochloromethane ND 0.20 10/25/19 18:48 BRFND41.70.066 0.57 1,2-Dibromoethane (EDB)ND 0.20 10/25/19 18:48 BRFND41.50.078 0.60 1,2-Dichlorobenzene ND 0.20 10/25/19 18:48 BRFND41.20.096 0.58 1,3-Dichlorobenzene ND 0.20 10/25/19 18:48 BRFND41.20.10 0.62 1,3-Dichlorobenzene ND 0.20 10/25/19 18:48 BRFND41.20.10 0.62 1,4-Dichlorobenzene ND 0.20 10/25/19 18:48 BRFND41.20.12 0.73 Dichlorodifluoromethane (Freon 12)ND 0.20 10/25/19 18:48 BRFND40.990.087 0.43 Dichlorodifluoromethane (Freon 12)ND 0.20 10/25/19 18:48 BRFND40.990.087 0.43 1,1-Dichloroethane ND 0.20 10/25/19 18:48 BRFND40.810.061 0.25 1,2-Dichloroethane ND 0.20 10/25/19 18:48 BRFND40.810.076 0.31 1,1-Dichloroethylene ND 0.20 10/25/19 18:48 BRFND40.790.11 0.43 1,1-Dichloroethylene ND 0.20 10/25/19 18:48 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 10/25/19 18:48 BRFND40.790.082 0.32 trans-1,2-Dichloroethylene ND 0.20 10/25/19 18:48 BRFND40.790.081 0.32 1,2-Dichloropropane ND 0.20 10/25/19 18:48 BRFND40.920.071 0.33 cis-1,3-Dichloropropene ND 0.20 10/25/19 18:48 BRFND40.910.070 0.32 trans-1,3-Dichloropropene ND 0.20 10/25/19 18:48 BRFND40.910.073 0.33 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 10/25/19 18:48 BRFND41.40.11 0.79 1,4-Dioxane ND 2.0 10/25/19 18:48 BRFND47.21.3 4.6 Ethanol ND 8.0 10/25/19 18:48 BRFND4153.6 6.7 Ethanol ND 8.0 10/25/19 18:48 BRFND4153.6 6.7 Ethyl Acetate ND 0.20 10/25/19 18:48 BRFND40.720.15 0.54 Page 4 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/21/2019 Work Order: 19J1394Sample Description/Location: Field Sample #: SS-Bld5-MP-3 Sample ID: 19J1394-01 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -5.9 Sampled: 10/18/2019 11:35 Canister ID: 2099 Flow Controller ID: 4224 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Ethyl Acetate ND 0.20 10/25/19 18:48 BRFND40.720.15 0.54 Ethylbenzene ND 0.20 10/25/19 18:48 BRFND40.870.12 0.50 Ethylbenzene ND 0.20 10/25/19 18:48 BRFND40.870.12 0.50 4-Ethyltoluene ND 0.20 10/25/19 18:48 BRFND40.980.12 0.60 4-Ethyltoluene ND 0.20 10/25/19 18:48 BRFND40.980.12 0.60 Heptane ND 0.20 10/25/19 18:48 BRFND40.820.12 0.48 Heptane ND 0.20 10/25/19 18:48 BRFND40.820.12 0.48 Hexachlorobutadiene ND 0.20 10/25/19 18:48 BRFND42.10.092 0.98 Hexane ND 8.0 10/25/19 18:48 BRFND4280.35 1.2 Hexane ND 8.0 10/25/19 18:48 BRFND4280.35 1.2 2-Hexanone (MBK)ND 0.20 10/25/19 18:48 BRFND40.820.12 0.48 2-Hexanone (MBK)ND 0.20 10/25/19 18:48 BRFND40.820.12 0.48 Isopropanol ND 8.0 10/25/19 18:48 BRFND4200.37 0.90 Isopropanol ND 8.0 10/25/19 18:48 BRFND4200.37 0.90 Methyl tert-Butyl Ether (MTBE)ND 0.20 10/25/19 18:48 BRFND40.720.10 0.36 Methylene Chloride ND 2.0 10/25/19 18:48 BRFND46.90.24 0.84 Methylene Chloride ND 2.0 10/25/19 18:48 BRFND46.90.24 0.84 4-Methyl-2-pentanone (MIBK)ND 0.20 10/25/19 18:48 BRFND40.820.10 0.43 Naphthalene ND 0.20 10/25/19 18:48 BRFND41.00.15 0.80 Naphthalene ND 0.20 10/25/19 18:48 BRFND41.00.15 0.80 Propene ND 8.0 10/25/19 18:48 BRFND4140.37 0.64 Propene ND 8.0 10/25/19 18:48 BRFND4140.37 0.64 Styrene ND 0.20 10/25/19 18:48 BRFND40.850.12 0.53 Styrene ND 0.20 10/25/19 18:48 BRFND40.850.12 0.53 1,1,2,2-Tetrachloroethane ND 0.20 10/25/19 18:48 BRFND41.40.089 0.61 Tetrachloroethylene 10 0.20 10/25/19 18:48 BRF6941.40.11 0.75 Tetrachloroethylene 10 0.20 10/25/19 18:48 BRF6941.40.11 0.75 Tetrahydrofuran 3.4 0.20 10/25/19 18:48 BRF9.9 40.590.20 0.59 Tetrahydrofuran 3.4 0.20 10/25/19 18:48 BRF9.9 40.590.20 0.59 Toluene 0.56 0.20 10/25/19 18:48 BRF2.1 40.750.10 0.39 Toluene 0.56 0.20 10/25/19 18:48 BRF2.1 40.750.10 0.39 1,2,4-Trichlorobenzene ND 0.20 10/25/19 18:48 BRFND41.50.14 1.0 1,1,1-Trichloroethane ND 0.20 10/25/19 18:48 BRFND41.10.075 0.41 1,1,1-Trichloroethane ND 0.20 10/25/19 18:48 BRFND41.10.075 0.41 1,1,2-Trichloroethane ND 0.20 10/25/19 18:48 BRFND41.10.082 0.45 Trichloroethylene 0.24 0.20 10/25/19 18:48 BRF1.3 41.10.081 0.43 Trichloroethylene 0.24 0.20 10/25/19 18:48 BRF1.3 41.10.081 0.43 Trichlorofluoromethane (Freon 11)0.57 0.80 10/25/19 18:48 BRFJ3.2 44.50.15 0.85 Trichlorofluoromethane (Freon 11)0.57 0.80 10/25/19 18:48 BRFJ3.2 44.50.15 0.85 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 10/25/19 18:48 BRFND46.10.15 1.2 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 10/25/19 18:48 BRFND46.10.15 1.2 1,2,4-Trimethylbenzene ND 0.20 10/25/19 18:48 BRFND40.980.13 0.63 1,2,4-Trimethylbenzene ND 0.20 10/25/19 18:48 BRFND40.980.13 0.63 1,3,5-Trimethylbenzene ND 0.20 10/25/19 18:48 BRFND40.980.13 0.62 1,3,5-Trimethylbenzene ND 0.20 10/25/19 18:48 BRFND40.980.13 0.62 Vinyl Acetate ND 4.0 10/25/19 18:48 BRFND4140.12 0.44 Vinyl Chloride ND 0.20 10/25/19 18:48 BRFND40.510.13 0.32 Page 5 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/21/2019 Work Order: 19J1394Sample Description/Location: Field Sample #: SS-Bld5-MP-3 Sample ID: 19J1394-01 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -5.9 Sampled: 10/18/2019 11:35 Canister ID: 2099 Flow Controller ID: 4224 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL m&p-Xylene 0.26 0.40 10/25/19 18:48 BRFJ1.1 41.70.23 1.00 m&p-Xylene 0.26 0.40 10/25/19 18:48 BRFJ1.1 41.70.23 1.00 o-Xylene ND 0.20 10/25/19 18:48 BRFND40.870.12 0.54 o-Xylene ND 0.20 10/25/19 18:48 BRFND40.870.12 0.54 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)108 10/25/19 18:4870-130 4-Bromofluorobenzene (1)108 10/25/19 18:4870-130 Page 6 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/21/2019 Work Order: 19J1394Sample Description/Location: Field Sample #: SS-Bld5-MP-5 Sample ID: 19J1394-02 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -7 Receipt Vacuum(in Hg): -6.5 Sampled: 10/18/2019 10:58 Canister ID: 2115 Flow Controller ID: 4209 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 6.7 8.0 10/25/19 19:16 BRFJ164192.8 6.6 Acetone 6.7 8.0 10/25/19 19:16 BRFJ164192.8 6.6 Benzene ND 0.20 10/25/19 19:16 BRFND40.640.082 0.26 Benzene ND 0.20 10/25/19 19:16 BRFND40.640.082 0.26 Benzyl chloride ND 0.20 10/25/19 19:16 BRFND41.00.052 0.27 Bromodichloromethane ND 0.20 10/25/19 19:16 BRFND41.30.074 0.49 Bromodichloromethane ND 0.20 10/25/19 19:16 BRFND41.30.074 0.49 Bromoform ND 0.20 10/25/19 19:16 BRFND42.10.090 0.93 Bromomethane ND 2.0 10/25/19 19:16 BRFND47.80.14 0.53 1,3-Butadiene ND 0.20 10/25/19 19:16 BRFND40.440.15 0.32 2-Butanone (MEK)1.2 8.0 10/25/19 19:16 BRFJ3.6 4240.37 1.1 2-Butanone (MEK)1.2 8.0 10/25/19 19:16 BRFJ3.6 4240.37 1.1 Carbon Disulfide ND 2.0 10/25/19 19:16 BRFND46.20.14 0.43 Carbon Disulfide ND 2.0 10/25/19 19:16 BRFND46.20.14 0.43 Carbon Tetrachloride ND 0.20 10/25/19 19:16 BRFND41.30.065 0.41 Carbon Tetrachloride ND 0.20 10/25/19 19:16 BRFND41.30.065 0.41 Chlorobenzene ND 0.20 10/25/19 19:16 BRFND40.920.098 0.45 Chloroethane ND 0.20 10/25/19 19:16 BRFND40.530.20 0.52 Chloroform ND 0.20 10/25/19 19:16 BRFND40.980.074 0.36 Chloroform ND 0.20 10/25/19 19:16 BRFND40.980.074 0.36 Chloromethane ND 0.40 10/25/19 19:16 BRFND40.830.14 0.28 Chloromethane ND 0.40 10/25/19 19:16 BRFND40.830.14 0.28 Cyclohexane ND 0.20 10/25/19 19:16 BRFND40.690.14 0.49 Cyclohexane ND 0.20 10/25/19 19:16 BRFND40.690.14 0.49 Dibromochloromethane ND 0.20 10/25/19 19:16 BRFND41.70.066 0.57 Dibromochloromethane ND 0.20 10/25/19 19:16 BRFND41.70.066 0.57 1,2-Dibromoethane (EDB)ND 0.20 10/25/19 19:16 BRFND41.50.078 0.60 1,2-Dichlorobenzene ND 0.20 10/25/19 19:16 BRFND41.20.096 0.58 1,3-Dichlorobenzene ND 0.20 10/25/19 19:16 BRFND41.20.10 0.62 1,3-Dichlorobenzene ND 0.20 10/25/19 19:16 BRFND41.20.10 0.62 1,4-Dichlorobenzene ND 0.20 10/25/19 19:16 BRFND41.20.12 0.73 Dichlorodifluoromethane (Freon 12)ND 0.20 10/25/19 19:16 BRFND40.990.087 0.43 Dichlorodifluoromethane (Freon 12)ND 0.20 10/25/19 19:16 BRFND40.990.087 0.43 1,1-Dichloroethane ND 0.20 10/25/19 19:16 BRFND40.810.061 0.25 1,2-Dichloroethane ND 0.20 10/25/19 19:16 BRFND40.810.076 0.31 1,1-Dichloroethylene ND 0.20 10/25/19 19:16 BRFND40.790.11 0.43 1,1-Dichloroethylene ND 0.20 10/25/19 19:16 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 10/25/19 19:16 BRFND40.790.082 0.32 trans-1,2-Dichloroethylene ND 0.20 10/25/19 19:16 BRFND40.790.081 0.32 1,2-Dichloropropane ND 0.20 10/25/19 19:16 BRFND40.920.071 0.33 cis-1,3-Dichloropropene ND 0.20 10/25/19 19:16 BRFND40.910.070 0.32 trans-1,3-Dichloropropene ND 0.20 10/25/19 19:16 BRFND40.910.073 0.33 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 10/25/19 19:16 BRFND41.40.11 0.79 1,4-Dioxane ND 2.0 10/25/19 19:16 BRFND47.21.3 4.6 Ethanol 3.8 8.0 10/25/19 19:16 BRFJ7.2 4153.6 6.7 Ethanol 3.8 8.0 10/25/19 19:16 BRFJ7.2 4153.6 6.7 Ethyl Acetate ND 0.20 10/25/19 19:16 BRFND40.720.15 0.54 Page 7 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/21/2019 Work Order: 19J1394Sample Description/Location: Field Sample #: SS-Bld5-MP-5 Sample ID: 19J1394-02 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -7 Receipt Vacuum(in Hg): -6.5 Sampled: 10/18/2019 10:58 Canister ID: 2115 Flow Controller ID: 4209 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Ethyl Acetate ND 0.20 10/25/19 19:16 BRFND40.720.15 0.54 Ethylbenzene ND 0.20 10/25/19 19:16 BRFND40.870.12 0.50 Ethylbenzene ND 0.20 10/25/19 19:16 BRFND40.870.12 0.50 4-Ethyltoluene ND 0.20 10/25/19 19:16 BRFND40.980.12 0.60 4-Ethyltoluene ND 0.20 10/25/19 19:16 BRFND40.980.12 0.60 Heptane ND 0.20 10/25/19 19:16 BRFND40.820.12 0.48 Heptane ND 0.20 10/25/19 19:16 BRFND40.820.12 0.48 Hexachlorobutadiene ND 0.20 10/25/19 19:16 BRFND42.10.092 0.98 Hexane ND 8.0 10/25/19 19:16 BRFND4280.35 1.2 Hexane ND 8.0 10/25/19 19:16 BRFND4280.35 1.2 2-Hexanone (MBK)ND 0.20 10/25/19 19:16 BRFND40.820.12 0.48 2-Hexanone (MBK)ND 0.20 10/25/19 19:16 BRFND40.820.12 0.48 Isopropanol ND 8.0 10/25/19 19:16 BRFND4200.37 0.90 Isopropanol ND 8.0 10/25/19 19:16 BRFND4200.37 0.90 Methyl tert-Butyl Ether (MTBE)ND 0.20 10/25/19 19:16 BRFND40.720.10 0.36 Methylene Chloride ND 2.0 10/25/19 19:16 BRFND46.90.24 0.84 Methylene Chloride ND 2.0 10/25/19 19:16 BRFND46.90.24 0.84 4-Methyl-2-pentanone (MIBK)ND 0.20 10/25/19 19:16 BRFND40.820.10 0.43 Naphthalene ND 0.20 10/25/19 19:16 BRFND41.00.15 0.80 Naphthalene ND 0.20 10/25/19 19:16 BRFND41.00.15 0.80 Propene ND 8.0 10/25/19 19:16 BRFND4140.37 0.64 Propene ND 8.0 10/25/19 19:16 BRFND4140.37 0.64 Styrene ND 0.20 10/25/19 19:16 BRFND40.850.12 0.53 Styrene ND 0.20 10/25/19 19:16 BRFND40.850.12 0.53 1,1,2,2-Tetrachloroethane ND 0.20 10/25/19 19:16 BRFND41.40.089 0.61 Tetrachloroethylene 0.72 0.20 10/25/19 19:16 BRF4.9 41.40.11 0.75 Tetrachloroethylene 0.72 0.20 10/25/19 19:16 BRF4.9 41.40.11 0.75 Tetrahydrofuran 2.9 0.20 10/25/19 19:16 BRF8.7 40.590.20 0.59 Tetrahydrofuran 2.9 0.20 10/25/19 19:16 BRF8.7 40.590.20 0.59 Toluene 0.35 0.20 10/25/19 19:16 BRF1.3 40.750.10 0.39 Toluene 0.35 0.20 10/25/19 19:16 BRF1.3 40.750.10 0.39 1,2,4-Trichlorobenzene ND 0.20 10/25/19 19:16 BRFND41.50.14 1.0 1,1,1-Trichloroethane ND 0.20 10/25/19 19:16 BRFND41.10.075 0.41 1,1,1-Trichloroethane ND 0.20 10/25/19 19:16 BRFND41.10.075 0.41 1,1,2-Trichloroethane ND 0.20 10/25/19 19:16 BRFND41.10.082 0.45 Trichloroethylene ND 0.20 10/25/19 19:16 BRFND41.10.081 0.43 Trichloroethylene ND 0.20 10/25/19 19:16 BRFND41.10.081 0.43 Trichlorofluoromethane (Freon 11)0.24 0.80 10/25/19 19:16 BRFJ1.3 44.50.15 0.85 Trichlorofluoromethane (Freon 11)0.24 0.80 10/25/19 19:16 BRFJ1.3 44.50.15 0.85 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 10/25/19 19:16 BRFND46.10.15 1.2 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 10/25/19 19:16 BRFND46.10.15 1.2 1,2,4-Trimethylbenzene ND 0.20 10/25/19 19:16 BRFND40.980.13 0.63 1,2,4-Trimethylbenzene ND 0.20 10/25/19 19:16 BRFND40.980.13 0.63 1,3,5-Trimethylbenzene ND 0.20 10/25/19 19:16 BRFND40.980.13 0.62 1,3,5-Trimethylbenzene ND 0.20 10/25/19 19:16 BRFND40.980.13 0.62 Vinyl Acetate ND 4.0 10/25/19 19:16 BRFND4140.12 0.44 Vinyl Chloride ND 0.20 10/25/19 19:16 BRFND40.510.13 0.32 Page 8 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/21/2019 Work Order: 19J1394Sample Description/Location: Field Sample #: SS-Bld5-MP-5 Sample ID: 19J1394-02 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -7 Receipt Vacuum(in Hg): -6.5 Sampled: 10/18/2019 10:58 Canister ID: 2115 Flow Controller ID: 4209 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL m&p-Xylene ND 0.40 10/25/19 19:16 BRFND41.70.23 1.00 m&p-Xylene ND 0.40 10/25/19 19:16 BRFND41.70.23 1.00 o-Xylene ND 0.20 10/25/19 19:16 BRFND40.870.12 0.54 o-Xylene ND 0.20 10/25/19 19:16 BRFND40.870.12 0.54 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)111 10/25/19 19:1670-130 4-Bromofluorobenzene (1)111 10/25/19 19:1670-130 Page 9 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/21/2019 Work Order: 19J1394Sample Description/Location: Field Sample #: SS-Bld5-MP-8 Sample ID: 19J1394-03 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -27 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -8.0 Sampled: 10/18/2019 10:15 Canister ID: 2116 Flow Controller ID: 4225 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 61 8.0 10/25/19 19:44 BRF1404192.8 6.6 Acetone 61 8.0 10/25/19 19:44 BRF1404192.8 6.6 Benzene 0.24 0.20 10/25/19 19:44 BRF0.75 40.640.082 0.26 Benzene 0.24 0.20 10/25/19 19:44 BRF0.75 40.640.082 0.26 Benzyl chloride ND 0.20 10/25/19 19:44 BRFND41.00.052 0.27 Bromodichloromethane ND 0.20 10/25/19 19:44 BRFND41.30.074 0.49 Bromodichloromethane ND 0.20 10/25/19 19:44 BRFND41.30.074 0.49 Bromoform ND 0.20 10/25/19 19:44 BRFND42.10.090 0.93 Bromomethane ND 2.0 10/25/19 19:44 BRFND47.80.14 0.53 1,3-Butadiene ND 0.20 10/25/19 19:44 BRFND40.440.15 0.32 2-Butanone (MEK)1.4 8.0 10/25/19 19:44 BRFJ4.1 4240.37 1.1 2-Butanone (MEK)1.4 8.0 10/25/19 19:44 BRFJ4.1 4240.37 1.1 Carbon Disulfide ND 2.0 10/25/19 19:44 BRFND46.20.14 0.43 Carbon Disulfide ND 2.0 10/25/19 19:44 BRFND46.20.14 0.43 Carbon Tetrachloride ND 0.20 10/25/19 19:44 BRFND41.30.065 0.41 Carbon Tetrachloride ND 0.20 10/25/19 19:44 BRFND41.30.065 0.41 Chlorobenzene ND 0.20 10/25/19 19:44 BRFND40.920.098 0.45 Chloroethane ND 0.20 10/25/19 19:44 BRFND40.530.20 0.52 Chloroform ND 0.20 10/25/19 19:44 BRFND40.980.074 0.36 Chloroform ND 0.20 10/25/19 19:44 BRFND40.980.074 0.36 Chloromethane ND 0.40 10/25/19 19:44 BRFND40.830.14 0.28 Chloromethane ND 0.40 10/25/19 19:44 BRFND40.830.14 0.28 Cyclohexane ND 0.20 10/25/19 19:44 BRFND40.690.14 0.49 Cyclohexane ND 0.20 10/25/19 19:44 BRFND40.690.14 0.49 Dibromochloromethane ND 0.20 10/25/19 19:44 BRFND41.70.066 0.57 Dibromochloromethane ND 0.20 10/25/19 19:44 BRFND41.70.066 0.57 1,2-Dibromoethane (EDB)ND 0.20 10/25/19 19:44 BRFND41.50.078 0.60 1,2-Dichlorobenzene ND 0.20 10/25/19 19:44 BRFND41.20.096 0.58 1,3-Dichlorobenzene ND 0.20 10/25/19 19:44 BRFND41.20.10 0.62 1,3-Dichlorobenzene ND 0.20 10/25/19 19:44 BRFND41.20.10 0.62 1,4-Dichlorobenzene ND 0.20 10/25/19 19:44 BRFND41.20.12 0.73 Dichlorodifluoromethane (Freon 12)ND 0.20 10/25/19 19:44 BRFND40.990.087 0.43 Dichlorodifluoromethane (Freon 12)ND 0.20 10/25/19 19:44 BRFND40.990.087 0.43 1,1-Dichloroethane ND 0.20 10/25/19 19:44 BRFND40.810.061 0.25 1,2-Dichloroethane ND 0.20 10/25/19 19:44 BRFND40.810.076 0.31 1,1-Dichloroethylene ND 0.20 10/25/19 19:44 BRFND40.790.11 0.43 1,1-Dichloroethylene ND 0.20 10/25/19 19:44 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 10/25/19 19:44 BRFND40.790.082 0.32 trans-1,2-Dichloroethylene ND 0.20 10/25/19 19:44 BRFND40.790.081 0.32 1,2-Dichloropropane ND 0.20 10/25/19 19:44 BRFND40.920.071 0.33 cis-1,3-Dichloropropene ND 0.20 10/25/19 19:44 BRFND40.910.070 0.32 trans-1,3-Dichloropropene ND 0.20 10/25/19 19:44 BRFND40.910.073 0.33 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 10/25/19 19:44 BRFND41.40.11 0.79 1,4-Dioxane ND 2.0 10/25/19 19:44 BRFND47.21.3 4.6 Ethanol 18 8.0 10/25/19 19:44 BRF354153.6 6.7 Ethanol 18 8.0 10/25/19 19:44 BRF354153.6 6.7 Ethyl Acetate ND 0.20 10/25/19 19:44 BRFND40.720.15 0.54 Page 10 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/21/2019 Work Order: 19J1394Sample Description/Location: Field Sample #: SS-Bld5-MP-8 Sample ID: 19J1394-03 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -27 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -8.0 Sampled: 10/18/2019 10:15 Canister ID: 2116 Flow Controller ID: 4225 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Ethyl Acetate ND 0.20 10/25/19 19:44 BRFND40.720.15 0.54 Ethylbenzene ND 0.20 10/25/19 19:44 BRFND40.870.12 0.50 Ethylbenzene ND 0.20 10/25/19 19:44 BRFND40.870.12 0.50 4-Ethyltoluene ND 0.20 10/25/19 19:44 BRFND40.980.12 0.60 4-Ethyltoluene ND 0.20 10/25/19 19:44 BRFND40.980.12 0.60 Heptane 0.34 0.20 10/25/19 19:44 BRF1.4 40.820.12 0.48 Heptane 0.34 0.20 10/25/19 19:44 BRF1.4 40.820.12 0.48 Hexachlorobutadiene ND 0.20 10/25/19 19:44 BRFND42.10.092 0.98 Hexane ND 8.0 10/25/19 19:44 BRFND4280.35 1.2 Hexane ND 8.0 10/25/19 19:44 BRFND4280.35 1.2 2-Hexanone (MBK)ND 0.20 10/25/19 19:44 BRFND40.820.12 0.48 2-Hexanone (MBK)ND 0.20 10/25/19 19:44 BRFND40.820.12 0.48 Isopropanol 1.3 8.0 10/25/19 19:44 BRFJ3.1 4200.37 0.90 Isopropanol 1.3 8.0 10/25/19 19:44 BRFJ3.1 4200.37 0.90 Methyl tert-Butyl Ether (MTBE)ND 0.20 10/25/19 19:44 BRFND40.720.10 0.36 Methylene Chloride ND 2.0 10/25/19 19:44 BRFND46.90.24 0.84 Methylene Chloride ND 2.0 10/25/19 19:44 BRFND46.90.24 0.84 4-Methyl-2-pentanone (MIBK)ND 0.20 10/25/19 19:44 BRFND40.820.10 0.43 Naphthalene ND 0.20 10/25/19 19:44 BRFND41.00.15 0.80 Naphthalene ND 0.20 10/25/19 19:44 BRFND41.00.15 0.80 Propene ND 8.0 10/25/19 19:44 BRFND4140.37 0.64 Propene ND 8.0 10/25/19 19:44 BRFND4140.37 0.64 Styrene ND 0.20 10/25/19 19:44 BRFND40.850.12 0.53 Styrene ND 0.20 10/25/19 19:44 BRFND40.850.12 0.53 1,1,2,2-Tetrachloroethane ND 0.20 10/25/19 19:44 BRFND41.40.089 0.61 Tetrachloroethylene 0.20 0.20 10/25/19 19:44 BRF1.4 41.40.11 0.75 Tetrachloroethylene 0.20 0.20 10/25/19 19:44 BRF1.4 41.40.11 0.75 Tetrahydrofuran ND 0.20 10/25/19 19:44 BRFND40.590.20 0.59 Tetrahydrofuran ND 0.20 10/25/19 19:44 BRFND40.590.20 0.59 Toluene 1.6 0.20 10/25/19 19:44 BRF5.9 40.750.10 0.39 Toluene 1.6 0.20 10/25/19 19:44 BRF5.9 40.750.10 0.39 1,2,4-Trichlorobenzene ND 0.20 10/25/19 19:44 BRFND41.50.14 1.0 1,1,1-Trichloroethane ND 0.20 10/25/19 19:44 BRFND41.10.075 0.41 1,1,1-Trichloroethane ND 0.20 10/25/19 19:44 BRFND41.10.075 0.41 1,1,2-Trichloroethane ND 0.20 10/25/19 19:44 BRFND41.10.082 0.45 Trichloroethylene ND 0.20 10/25/19 19:44 BRFND41.10.081 0.43 Trichloroethylene ND 0.20 10/25/19 19:44 BRFND41.10.081 0.43 Trichlorofluoromethane (Freon 11)0.31 0.80 10/25/19 19:44 BRFJ1.7 44.50.15 0.85 Trichlorofluoromethane (Freon 11)0.31 0.80 10/25/19 19:44 BRFJ1.7 44.50.15 0.85 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 10/25/19 19:44 BRFND46.10.15 1.2 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 10/25/19 19:44 BRFND46.10.15 1.2 1,2,4-Trimethylbenzene 0.67 0.20 10/25/19 19:44 BRF3.3 40.980.13 0.63 1,2,4-Trimethylbenzene 0.67 0.20 10/25/19 19:44 BRF3.3 40.980.13 0.63 1,3,5-Trimethylbenzene ND 0.20 10/25/19 19:44 BRFND40.980.13 0.62 1,3,5-Trimethylbenzene ND 0.20 10/25/19 19:44 BRFND40.980.13 0.62 Vinyl Acetate ND 4.0 10/25/19 19:44 BRFND4140.12 0.44 Vinyl Chloride ND 0.20 10/25/19 19:44 BRFND40.510.13 0.32 Page 11 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/21/2019 Work Order: 19J1394Sample Description/Location: Field Sample #: SS-Bld5-MP-8 Sample ID: 19J1394-03 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -27 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -8.0 Sampled: 10/18/2019 10:15 Canister ID: 2116 Flow Controller ID: 4225 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL m&p-Xylene ND 0.40 10/25/19 19:44 BRFND41.70.23 1.00 m&p-Xylene ND 0.40 10/25/19 19:44 BRFND41.70.23 1.00 o-Xylene ND 0.20 10/25/19 19:44 BRFND40.870.12 0.54 o-Xylene ND 0.20 10/25/19 19:44 BRFND40.870.12 0.54 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)117 10/25/19 19:4470-130 4-Bromofluorobenzene (1)117 10/25/19 19:4470-130 Page 12 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/21/2019 Work Order: 19J1394Sample Description/Location: Field Sample #: DUP-1 Sample ID: 19J1394-04 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -7 Receipt Vacuum(in Hg): -6.3 Sampled: 10/18/2019 00:00 Canister ID: 2232 Flow Controller ID: 4209 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 6.5 8.0 10/25/19 20:12 BRFJ154192.8 6.6 Acetone 6.5 8.0 10/25/19 20:12 BRFJ154192.8 6.6 Benzene ND 0.20 10/25/19 20:12 BRFND40.640.082 0.26 Benzene ND 0.20 10/25/19 20:12 BRFND40.640.082 0.26 Benzyl chloride ND 0.20 10/25/19 20:12 BRFND41.00.052 0.27 Bromodichloromethane ND 0.20 10/25/19 20:12 BRFND41.30.074 0.49 Bromodichloromethane ND 0.20 10/25/19 20:12 BRFND41.30.074 0.49 Bromoform ND 0.20 10/25/19 20:12 BRFND42.10.090 0.93 Bromomethane ND 2.0 10/25/19 20:12 BRFND47.80.14 0.53 1,3-Butadiene ND 0.20 10/25/19 20:12 BRFND40.440.15 0.32 2-Butanone (MEK)0.99 8.0 10/25/19 20:12 BRFJ2.9 4240.37 1.1 2-Butanone (MEK)0.99 8.0 10/25/19 20:12 BRFJ2.9 4240.37 1.1 Carbon Disulfide ND 2.0 10/25/19 20:12 BRFND46.20.14 0.43 Carbon Disulfide ND 2.0 10/25/19 20:12 BRFND46.20.14 0.43 Carbon Tetrachloride ND 0.20 10/25/19 20:12 BRFND41.30.065 0.41 Carbon Tetrachloride ND 0.20 10/25/19 20:12 BRFND41.30.065 0.41 Chlorobenzene ND 0.20 10/25/19 20:12 BRFND40.920.098 0.45 Chloroethane ND 0.20 10/25/19 20:12 BRFND40.530.20 0.52 Chloroform ND 0.20 10/25/19 20:12 BRFND40.980.074 0.36 Chloroform ND 0.20 10/25/19 20:12 BRFND40.980.074 0.36 Chloromethane ND 0.40 10/25/19 20:12 BRFND40.830.14 0.28 Chloromethane ND 0.40 10/25/19 20:12 BRFND40.830.14 0.28 Cyclohexane ND 0.20 10/25/19 20:12 BRFND40.690.14 0.49 Cyclohexane ND 0.20 10/25/19 20:12 BRFND40.690.14 0.49 Dibromochloromethane ND 0.20 10/25/19 20:12 BRFND41.70.066 0.57 Dibromochloromethane ND 0.20 10/25/19 20:12 BRFND41.70.066 0.57 1,2-Dibromoethane (EDB)ND 0.20 10/25/19 20:12 BRFND41.50.078 0.60 1,2-Dichlorobenzene ND 0.20 10/25/19 20:12 BRFND41.20.096 0.58 1,3-Dichlorobenzene ND 0.20 10/25/19 20:12 BRFND41.20.10 0.62 1,3-Dichlorobenzene ND 0.20 10/25/19 20:12 BRFND41.20.10 0.62 1,4-Dichlorobenzene ND 0.20 10/25/19 20:12 BRFND41.20.12 0.73 Dichlorodifluoromethane (Freon 12)ND 0.20 10/25/19 20:12 BRFND40.990.087 0.43 Dichlorodifluoromethane (Freon 12)ND 0.20 10/25/19 20:12 BRFND40.990.087 0.43 1,1-Dichloroethane ND 0.20 10/25/19 20:12 BRFND40.810.061 0.25 1,2-Dichloroethane ND 0.20 10/25/19 20:12 BRFND40.810.076 0.31 1,1-Dichloroethylene ND 0.20 10/25/19 20:12 BRFND40.790.11 0.43 1,1-Dichloroethylene ND 0.20 10/25/19 20:12 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 10/25/19 20:12 BRFND40.790.082 0.32 trans-1,2-Dichloroethylene ND 0.20 10/25/19 20:12 BRFND40.790.081 0.32 1,2-Dichloropropane ND 0.20 10/25/19 20:12 BRFND40.920.071 0.33 cis-1,3-Dichloropropene ND 0.20 10/25/19 20:12 BRFND40.910.070 0.32 trans-1,3-Dichloropropene ND 0.20 10/25/19 20:12 BRFND40.910.073 0.33 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 10/25/19 20:12 BRFND41.40.11 0.79 1,4-Dioxane ND 2.0 10/25/19 20:12 BRFND47.21.3 4.6 Ethanol ND 8.0 10/25/19 20:12 BRFND4153.6 6.7 Ethanol ND 8.0 10/25/19 20:12 BRFND4153.6 6.7 Ethyl Acetate ND 0.20 10/25/19 20:12 BRFND40.720.15 0.54 Page 13 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/21/2019 Work Order: 19J1394Sample Description/Location: Field Sample #: DUP-1 Sample ID: 19J1394-04 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -7 Receipt Vacuum(in Hg): -6.3 Sampled: 10/18/2019 00:00 Canister ID: 2232 Flow Controller ID: 4209 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Ethyl Acetate ND 0.20 10/25/19 20:12 BRFND40.720.15 0.54 Ethylbenzene ND 0.20 10/25/19 20:12 BRFND40.870.12 0.50 Ethylbenzene ND 0.20 10/25/19 20:12 BRFND40.870.12 0.50 4-Ethyltoluene ND 0.20 10/25/19 20:12 BRFND40.980.12 0.60 4-Ethyltoluene ND 0.20 10/25/19 20:12 BRFND40.980.12 0.60 Heptane ND 0.20 10/25/19 20:12 BRFND40.820.12 0.48 Heptane ND 0.20 10/25/19 20:12 BRFND40.820.12 0.48 Hexachlorobutadiene ND 0.20 10/25/19 20:12 BRFND42.10.092 0.98 Hexane ND 8.0 10/25/19 20:12 BRFND4280.35 1.2 Hexane ND 8.0 10/25/19 20:12 BRFND4280.35 1.2 2-Hexanone (MBK)ND 0.20 10/25/19 20:12 BRFND40.820.12 0.48 2-Hexanone (MBK)ND 0.20 10/25/19 20:12 BRFND40.820.12 0.48 Isopropanol ND 8.0 10/25/19 20:12 BRFND4200.37 0.90 Isopropanol ND 8.0 10/25/19 20:12 BRFND4200.37 0.90 Methyl tert-Butyl Ether (MTBE)ND 0.20 10/25/19 20:12 BRFND40.720.10 0.36 Methylene Chloride ND 2.0 10/25/19 20:12 BRFND46.90.24 0.84 Methylene Chloride ND 2.0 10/25/19 20:12 BRFND46.90.24 0.84 4-Methyl-2-pentanone (MIBK)ND 0.20 10/25/19 20:12 BRFND40.820.10 0.43 Naphthalene ND 0.20 10/25/19 20:12 BRFND41.00.15 0.80 Naphthalene ND 0.20 10/25/19 20:12 BRFND41.00.15 0.80 Propene ND 8.0 10/25/19 20:12 BRFND4140.37 0.64 Propene ND 8.0 10/25/19 20:12 BRFND4140.37 0.64 Styrene ND 0.20 10/25/19 20:12 BRFND40.850.12 0.53 Styrene ND 0.20 10/25/19 20:12 BRFND40.850.12 0.53 1,1,2,2-Tetrachloroethane ND 0.20 10/25/19 20:12 BRFND41.40.089 0.61 Tetrachloroethylene 0.70 0.20 10/25/19 20:12 BRF4.7 41.40.11 0.75 Tetrachloroethylene 0.70 0.20 10/25/19 20:12 BRF4.7 41.40.11 0.75 Tetrahydrofuran 2.9 0.20 10/25/19 20:12 BRF8.5 40.590.20 0.59 Tetrahydrofuran 2.9 0.20 10/25/19 20:12 BRF8.5 40.590.20 0.59 Toluene 0.34 0.20 10/25/19 20:12 BRF1.3 40.750.10 0.39 Toluene 0.34 0.20 10/25/19 20:12 BRF1.3 40.750.10 0.39 1,2,4-Trichlorobenzene ND 0.20 10/25/19 20:12 BRFND41.50.14 1.0 1,1,1-Trichloroethane ND 0.20 10/25/19 20:12 BRFND41.10.075 0.41 1,1,1-Trichloroethane ND 0.20 10/25/19 20:12 BRFND41.10.075 0.41 1,1,2-Trichloroethane ND 0.20 10/25/19 20:12 BRFND41.10.082 0.45 Trichloroethylene ND 0.20 10/25/19 20:12 BRFND41.10.081 0.43 Trichloroethylene ND 0.20 10/25/19 20:12 BRFND41.10.081 0.43 Trichlorofluoromethane (Freon 11)0.35 0.80 10/25/19 20:12 BRFJ2.0 44.50.15 0.85 Trichlorofluoromethane (Freon 11)0.35 0.80 10/25/19 20:12 BRFJ2.0 44.50.15 0.85 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 10/25/19 20:12 BRFND46.10.15 1.2 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 10/25/19 20:12 BRFND46.10.15 1.2 1,2,4-Trimethylbenzene ND 0.20 10/25/19 20:12 BRFND40.980.13 0.63 1,2,4-Trimethylbenzene ND 0.20 10/25/19 20:12 BRFND40.980.13 0.63 1,3,5-Trimethylbenzene ND 0.20 10/25/19 20:12 BRFND40.980.13 0.62 1,3,5-Trimethylbenzene ND 0.20 10/25/19 20:12 BRFND40.980.13 0.62 Vinyl Acetate ND 4.0 10/25/19 20:12 BRFND4140.12 0.44 Vinyl Chloride ND 0.20 10/25/19 20:12 BRFND40.510.13 0.32 Page 14 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/21/2019 Work Order: 19J1394Sample Description/Location: Field Sample #: DUP-1 Sample ID: 19J1394-04 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -7 Receipt Vacuum(in Hg): -6.3 Sampled: 10/18/2019 00:00 Canister ID: 2232 Flow Controller ID: 4209 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL m&p-Xylene ND 0.40 10/25/19 20:12 BRFND41.70.23 1.00 m&p-Xylene ND 0.40 10/25/19 20:12 BRFND41.70.23 1.00 o-Xylene ND 0.20 10/25/19 20:12 BRFND40.870.12 0.54 o-Xylene ND 0.20 10/25/19 20:12 BRFND40.870.12 0.54 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)111 10/25/19 20:1270-130 4-Bromofluorobenzene (1)111 10/25/19 20:1270-130 Page 15 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Sample Extraction Data Prep Method: TO-15 Prep-EPA TO-15 Lab Number [Field ID]Batch Date Pressure Dilution Pre Dilution Pre-Dil Initial mL Pre-Dil Final mL Default Injection mL Actual Injection mL 19J1394-01 [SS-Bld5-MP-3]B244404 1.5 1 N/A 1000 400 150 10/25/19 19J1394-02 [SS-Bld5-MP-5]B244404 1.5 1 N/A 1000 400 150 10/25/19 19J1394-03 [SS-Bld5-MP-8]B244404 1.5 1 N/A 1000 400 150 10/25/19 19J1394-04 [DUP-1]B244404 1.5 1 N/A 1000 400 150 10/25/19 Page 16 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B244404 - TO-15 Prep Blank (B244404-BLK1)Prepared & Analyzed: 10/25/19 1.4NDAcetone 0.035NDBenzene 0.035NDBenzyl chloride 0.035NDBromodichloromethane 0.035NDBromoform 0.035NDBromomethane 0.035ND1,3-Butadiene 1.4ND2-Butanone (MEK) 0.35NDCarbon Disulfide 0.035NDCarbon Tetrachloride 0.035NDChlorobenzene 0.035NDChloroethane 0.035NDChloroform 0.070NDChloromethane 0.035NDCyclohexane 0.035NDDibromochloromethane 0.035ND1,2-Dibromoethane (EDB) 0.035ND1,2-Dichlorobenzene 0.035ND1,3-Dichlorobenzene 0.035ND1,4-Dichlorobenzene 0.035NDDichlorodifluoromethane (Freon 12) 0.035ND1,1-Dichloroethane 0.035ND1,2-Dichloroethane 0.035ND1,1-Dichloroethylene 0.035NDcis-1,2-Dichloroethylene 0.035NDtrans-1,2-Dichloroethylene 0.035ND1,2-Dichloropropane 0.035NDcis-1,3-Dichloropropene 0.035NDtrans-1,3-Dichloropropene 0.035ND1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.35ND1,4-Dioxane 1.4NDEthanol 0.035NDEthyl Acetate 0.035NDEthylbenzene 0.035ND4-Ethyltoluene 0.035NDHeptane 0.035NDHexachlorobutadiene 1.4NDHexane 0.035ND2-Hexanone (MBK) 1.4NDIsopropanol 0.035NDMethyl tert-Butyl Ether (MTBE) 0.35NDMethylene Chloride 0.035ND4-Methyl-2-pentanone (MIBK) 0.035NDNaphthalene 1.4NDPropene 0.035NDStyrene Page 17 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B244404 - TO-15 Prep Blank (B244404-BLK1)Prepared & Analyzed: 10/25/19 0.035ND1,1,2,2-Tetrachloroethane 0.035NDTetrachloroethylene 0.035NDTetrahydrofuran 0.035NDToluene 0.035ND1,2,4-Trichlorobenzene 0.035ND1,1,1-Trichloroethane 0.035ND1,1,2-Trichloroethane 0.035NDTrichloroethylene 0.14NDTrichlorofluoromethane (Freon 11) 0.14ND1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 0.035ND1,2,4-Trimethylbenzene 0.035ND1,3,5-Trimethylbenzene 0.70NDVinyl Acetate 0.035NDVinyl Chloride 0.070NDm&p-Xylene 0.035NDo-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1098.70 LCS (B244404-BS1)Prepared & Analyzed: 10/25/19 5.00 70-13087.14.36Acetone 5.00 70-13088.24.41Benzene 5.00 70-1301135.65Benzyl chloride 5.00 70-13086.34.32Bromodichloromethane 5.00 70-13099.44.97Bromoform 5.00 70-1301105.51Bromomethane 5.00 70-13088.14.411,3-Butadiene 5.00 70-13086.34.312-Butanone (MEK) 5.00 70-13099.44.97Carbon Disulfide 5.00 70-13084.24.21Carbon Tetrachloride 5.00 70-13085.64.28Chlorobenzene 5.00 70-1301055.26Chloroethane 5.00 70-13095.34.76Chloroform 5.00 70-1301035.16Chloromethane 5.00 70-13088.94.44Cyclohexane 5.00 70-13085.74.29Dibromochloromethane 5.00 70-13087.24.361,2-Dibromoethane (EDB) 5.00 70-1301175.871,2-Dichlorobenzene 5.00 70-1301105.491,3-Dichlorobenzene 5.00 70-1301085.421,4-Dichlorobenzene 5.00 70-1301025.12Dichlorodifluoromethane (Freon 12) 5.00 70-13094.24.711,1-Dichloroethane 5.00 70-13090.24.511,2-Dichloroethane 5.00 70-13095.14.761,1-Dichloroethylene 5.00 70-13092.04.60cis-1,2-Dichloroethylene 5.00 70-13091.44.57trans-1,2-Dichloroethylene 5.00 70-13086.44.321,2-Dichloropropane Page 18 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B244404 - TO-15 Prep LCS (B244404-BS1)Prepared & Analyzed: 10/25/19 5.00 70-13085.74.28cis-1,3-Dichloropropene 5.00 70-13097.34.87trans-1,3-Dichloropropene 5.00 70-13090.54.521,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 5.00 70-1301095.451,4-Dioxane 5.00 70-13072.73.63Ethanol 5.00 70-13092.14.60Ethyl Acetate 5.00 70-13085.54.28Ethylbenzene 5.00 70-13092.94.654-Ethyltoluene 5.00 70-13081.04.05Heptane 5.00 70-1301175.85Hexachlorobutadiene 5.00 70-1301025.08Hexane 5.00 70-13076.33.812-Hexanone (MBK) 5.00 70-13080.44.02Isopropanol 5.00 70-13089.44.47Methyl tert-Butyl Ether (MTBE) 5.00 70-13087.34.36Methylene Chloride 5.00 70-13082.34.124-Methyl-2-pentanone (MIBK) 5.00 L-0170-1301487.39Naphthalene * 5.00 70-13084.14.21Propene 5.00 70-13097.34.86Styrene 5.00 70-13094.24.711,1,2,2-Tetrachloroethane 5.00 70-13087.74.38Tetrachloroethylene 5.00 70-13093.64.68Tetrahydrofuran 5.00 70-13083.84.19Toluene 5.00 L-0170-1301527.611,2,4-Trichlorobenzene * 5.00 70-13079.53.971,1,1-Trichloroethane 5.00 70-13089.54.471,1,2-Trichloroethane 5.00 70-13087.94.40Trichloroethylene 5.00 70-13090.84.54Trichlorofluoromethane (Freon 11) 5.00 70-13093.74.681,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 5.00 70-13093.84.691,2,4-Trimethylbenzene 5.00 70-13088.64.431,3,5-Trimethylbenzene 5.00 70-13084.84.24Vinyl Acetate 5.00 70-13094.14.71Vinyl Chloride 10.0 70-13085.88.58m&p-Xylene 5.00 70-13085.34.26o-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1088.62 Page 19 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B244404 - TO-15 Prep Blank (B244404-BLK1)Prepared & Analyzed: 10/25/19 1.4NDAcetone 0.035NDBenzene 0.035NDBromodichloromethane 1.4ND2-Butanone (MEK) 0.35NDCarbon Disulfide 0.035NDCarbon Tetrachloride 0.035NDChloroform 0.070NDChloromethane 0.035NDCyclohexane 0.035NDDibromochloromethane 0.035ND1,3-Dichlorobenzene 0.035NDDichlorodifluoromethane (Freon 12) 0.035ND1,1-Dichloroethylene 1.4NDEthanol 0.035NDEthyl Acetate 0.035NDEthylbenzene 0.035ND4-Ethyltoluene 0.035NDHeptane 1.4NDHexane 0.035ND2-Hexanone (MBK) 1.4NDIsopropanol 0.35NDMethylene Chloride 0.035NDNaphthalene 1.4NDPropene 0.035NDStyrene 0.035NDTetrachloroethylene 0.035NDTetrahydrofuran 0.035NDToluene 0.035ND1,1,1-Trichloroethane 0.035NDTrichloroethylene 0.14NDTrichlorofluoromethane (Freon 11) 0.14ND1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 0.035ND1,2,4-Trimethylbenzene 0.035ND1,3,5-Trimethylbenzene 0.070NDm&p-Xylene 0.035NDo-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1098.70 Page 20 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B244404 - TO-15 Prep LCS (B244404-BS1)Prepared & Analyzed: 10/25/19 5.00 70-13087.14.36Acetone 5.00 70-13088.24.41Benzene 5.00 70-13086.34.32Bromodichloromethane 5.00 70-13086.34.312-Butanone (MEK) 5.00 70-13099.44.97Carbon Disulfide 5.00 70-13084.24.21Carbon Tetrachloride 5.00 70-13095.34.76Chloroform 5.00 70-1301035.16Chloromethane 5.00 70-13088.94.44Cyclohexane 5.00 70-13085.74.29Dibromochloromethane 5.00 70-1301105.491,3-Dichlorobenzene 5.00 70-1301025.12Dichlorodifluoromethane (Freon 12) 5.00 70-13095.14.761,1-Dichloroethylene 5.00 70-13072.73.63Ethanol 5.00 70-13092.14.60Ethyl Acetate 5.00 70-13085.54.28Ethylbenzene 5.00 70-13092.94.654-Ethyltoluene 5.00 70-13081.04.05Heptane 5.00 70-1301025.08Hexane 5.00 70-13076.33.812-Hexanone (MBK) 5.00 70-13080.44.02Isopropanol 5.00 70-13087.34.36Methylene Chloride 5.00 L-0170-1301487.39Naphthalene * 5.00 70-13084.14.21Propene 5.00 70-13097.34.86Styrene 5.00 70-13087.74.38Tetrachloroethylene 5.00 70-13093.64.68Tetrahydrofuran 5.00 70-13083.84.19Toluene 5.00 70-13079.53.971,1,1-Trichloroethane 5.00 70-13087.94.40Trichloroethylene 5.00 70-13090.84.54Trichlorofluoromethane (Freon 11) 5.00 70-13093.74.681,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 5.00 70-13093.84.691,2,4-Trimethylbenzene 5.00 70-13088.64.431,3,5-Trimethylbenzene 10.0 70-13085.88.58m&p-Xylene 5.00 70-13085.34.26o-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1088.62 Page 21 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Note: Blank Subtraction is not performed unless otherwise noted *QC result is outside of established limits. Wide recovery limits established for difficult compound. Wide RPD limits established for difficult compound. #Data exceeded client recommended or regulatory level RL Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference LCS Laboratory Control Sample Laboratory Control SampleLCS Dup Duplicate Laboratory Control Sample MS Matrix Spike Sample MS Dup Duplicate Matrix Spike Sample REC Recovery QC Quality Control ppbv Parts per billion volume EPA United States Environmental Protection Agency Percent Recovery% REC ND Not Detected Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the calculation which have not been rounded. Not ApplicableN/A DL Detection Limit Not CalculatedNC LFB/LCS Lab Fortified Blank/Lab Control Sample ORP Oxidation-Reduction Potential Not dry weight correctedwet Percent weight% wt KilogramKg Gramg Milligrammg Microgramg Nanogramng LiterL MillilitermL Microliter L Cubic Meterm3 Extractable Petroleum HydrocarbonsEPH Volatile Petroleum HydrocarbonsVPH Air Petroleum HydrocarbonsAPH Flame Ionization DetectorFID Photo Ionization DetectorPID FLAG/QUALIFIER SUMMARY Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag). J Laboratory fortified blank /laboratory control sample recovery outside of control limits. Data validation is not affected since all results are "not detected" for all samples in this batch for this compound and bias is on the high side. L-01 ANALYST Raisa A. PetraitisRAP Kerry K. McGeeKKM Brittany R. FiskBRF Page 22 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q Initial Cal Check (S038528-ICV1 )Lab File ID: B1920819.D Analyzed: 07/27/19 19:24 Bromochloromethane (1)144000 5.05 141846 5.054 60 - 140102 -0.0040 +/-0.50 1,4-Difluorobenzene (1)338979 6.264 331570 6.268 60 - 140102 -0.0040 +/-0.50 Chlorobenzene-d5 (1)300441 9.857 293128 9.861 60 - 140102 -0.0040 +/-0.50 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q Calibration Check (S041899-CCV1 )Lab File ID: B1929806.D Analyzed: 10/25/19 12:18 Bromochloromethane (1)115973 5.047 141846 5.054 60 - 14082 -0.0070 +/-0.50 1,4-Difluorobenzene (1)288942 6.266 331570 6.268 60 - 14087 -0.0020 +/-0.50 Chlorobenzene-d5 (1)260957 9.854 293128 9.861 60 - 14089 -0.0070 +/-0.50 LCS (B244404-BS1 )Lab File ID: B1929808.D Analyzed: 10/25/19 13:13 Bromochloromethane (1)126308 5.049 115973 5.047 60 - 140109 0.0020 +/-0.50 1,4-Difluorobenzene (1)315851 6.269 288942 6.266 60 - 140109 0.0030 +/-0.50 Chlorobenzene-d5 (1)301953 9.856 260957 9.854 60 - 140116 0.0020 +/-0.50 Blank (B244404-BLK1 )Lab File ID: B1929810.D Analyzed: 10/25/19 14:18 Bromochloromethane (1)120382 5.052 115973 5.047 60 - 140104 0.0050 +/-0.50 1,4-Difluorobenzene (1)289024 6.266 288942 6.266 60 - 140100 0.0000 +/-0.50 Chlorobenzene-d5 (1)253989 9.859 260957 9.854 60 - 14097 0.0050 +/-0.50 SS-Bld5-MP-3 (19J1394-01 )Lab File ID: B1929817.D Analyzed: 10/25/19 18:48 Bromochloromethane (1)135231 5.049 115973 5.047 60 - 140117 0.0020 +/-0.50 Bromochloromethane (1)135231 5.049 115973 5.047 60 - 140117 0.0020 +/-0.50 1,4-Difluorobenzene (1)322949 6.269 288942 6.266 60 - 140112 0.0030 +/-0.50 1,4-Difluorobenzene (1)322949 6.269 288942 6.266 60 - 140112 0.0030 +/-0.50 Chlorobenzene-d5 (1)288134 9.856 260957 9.854 60 - 140110 0.0020 +/-0.50 Chlorobenzene-d5 (1)288134 9.856 260957 9.854 60 - 140110 0.0020 +/-0.50 SS-Bld5-MP-5 (19J1394-02 )Lab File ID: B1929818.D Analyzed: 10/25/19 19:16 Bromochloromethane (1)127673 5.049 115973 5.047 60 - 140110 0.0020 +/-0.50 Bromochloromethane (1)127673 5.049 115973 5.047 60 - 140110 0.0020 +/-0.50 1,4-Difluorobenzene (1)316283 6.263 288942 6.266 60 - 140109 -0.0030 +/-0.50 1,4-Difluorobenzene (1)316283 6.263 288942 6.266 60 - 140109 -0.0030 +/-0.50 Chlorobenzene-d5 (1)273209 9.856 260957 9.854 60 - 140105 0.0020 +/-0.50 Chlorobenzene-d5 (1)273209 9.856 260957 9.854 60 - 140105 0.0020 +/-0.50 Page 23 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q SS-Bld5-MP-8 (19J1394-03 )Lab File ID: B1929819.D Analyzed: 10/25/19 19:44 Bromochloromethane (1)124373 5.049 115973 5.047 60 - 140107 0.0020 +/-0.50 Bromochloromethane (1)124373 5.049 115973 5.047 60 - 140107 0.0020 +/-0.50 1,4-Difluorobenzene (1)302594 6.269 288942 6.266 60 - 140105 0.0030 +/-0.50 1,4-Difluorobenzene (1)302594 6.269 288942 6.266 60 - 140105 0.0030 +/-0.50 Chlorobenzene-d5 (1)270569 9.856 260957 9.854 60 - 140104 0.0020 +/-0.50 Chlorobenzene-d5 (1)270569 9.856 260957 9.854 60 - 140104 0.0020 +/-0.50 DUP-1 (19J1394-04 )Lab File ID: B1929820.D Analyzed: 10/25/19 20:12 Bromochloromethane (1)125973 5.048 115973 5.047 60 - 140109 0.0010 +/-0.50 Bromochloromethane (1)125973 5.048 115973 5.047 60 - 140109 0.0010 +/-0.50 1,4-Difluorobenzene (1)311769 6.268 288942 6.266 60 - 140108 0.0020 +/-0.50 1,4-Difluorobenzene (1)311769 6.268 288942 6.266 60 - 140108 0.0020 +/-0.50 Chlorobenzene-d5 (1)271857 9.855 260957 9.854 60 - 140104 0.0010 +/-0.50 Chlorobenzene-d5 (1)271857 9.855 260957 9.854 60 - 140104 0.0010 +/-0.50 Page 24 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S041899-CCV1 COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR STD 0.8398231A -20.9 303.96 1.0615015.00Acetone 0.7187546A -17.7 304.11 0.87352065.00Benzene 0.5913925A -15.5 304.23 0.69964655.00Benzyl chloride 0.4856615A -19.5 304.02 0.60340275.00Bromodichloromethane 0.5162352A -7.8 304.61 0.55983515.00Bromoform 0.5987463L -0.7 304.96 0.76718815.00Bromomethane 0.4238366A -17.9 304.10 0.51654375.001,3-Butadiene 1.154131A -23.6 303.82 1.5106525.002-Butanone (MEK) 1.624157A -16.8 304.16 1.9511025.00Carbon Disulfide 0.3915692A -20.2 303.99 0.49074395.00Carbon Tetrachloride 0.6325149A -17.5 304.12 0.76711435.00Chlorobenzene 0.3080579A -6.3 304.69 0.32866245.00Chloroethane 1.17488A -12.2 304.39 1.3380965.00Chloroform 0.5767687L -6.4 304.68 0.76008055.00Chloromethane 0.3290238A -17.1 304.15 0.39683775.00Cyclohexane 0.5078293A -17.2 304.14 0.61317595.00Dibromochloromethane 0.4335611A -16.4 304.18 0.51888315.001,2-Dibromoethane (EDB) 0.5425752A -1.9 304.91 0.55290515.001,2-Dichlorobenzene 0.5824653A -5.4 304.73 0.61564225.001,3-Dichlorobenzene 0.5756964A -7.5 304.63 0.62224625.001,4-Dichlorobenzene 1.431078A -4.4 304.78 1.4963295.00Dichlorodifluoromethane (Freon 12) 0.9960249A -14.3 304.29 1.1616095.001,1-Dichloroethane 0.6471023A -16.4 304.18 0.77441815.001,2-Dichloroethane 0.7954127A -17.2 304.14 0.96096445.001,1-Dichloroethylene 0.7359644A -14.4 304.28 0.85939785.00cis-1,2-Dichloroethylene 0.784831A -16.2 304.19 0.93699095.00trans-1,2-Dichloroethylene 0.2459511A -20.4 303.98 0.30891335.001,2-Dichloropropane 0.4149982A -18.1 304.10 0.50654855.00cis-1,3-Dichloropropene 0.3470371A -12.1 304.40 0.39484455.00trans-1,3-Dichloropropene 1.648522A -11.1 304.44 1.854975.001,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.1444553A -3.9 304.80 0.15031965.001,4-Dioxane 0.1747027L -18.9 304.06 0.23610955.00Ethanol 0.2129047A -9.8 304.51 0.23592385.00Ethyl Acetate 1.039282A -17.2 304.14 1.2549035.00Ethylbenzene 1.015407A -13.3 304.34 1.1706165.004-Ethyltoluene 0.2111427A -22.8 303.86 0.27352385.00Heptane 0.3541672A -1.4 304.93 0.35914075.00Hexachlorobutadiene 0.3823925L -5.4 304.73 0.4924525.00Hexane Page 25 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S041899-CCV1 COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR STD 0.5224401A -29.5 303.53 0.74091225.002-Hexanone (MBK) 1.093827L -9.1 304.54 1.4903085.00Isopropanol 1.541918A -16.5 304.18 1.8460425.00Methyl tert-Butyl Ether (MTBE) 0.6820622A -18.8 304.06 0.84025945.00Methylene Chloride 0.5494362A -23.3 303.84 0.71617985.004-Methyl-2-pentanone (MIBK) 0.637702A 5.4 305.27 0.60499385.00Naphthalene 0.4732964A -19.0 304.05 0.58429395.00Propene 0.5976402A -7.7 304.62 0.64731585.00Styrene 0.6726012A -12.4 304.38 0.76749595.001,1,2,2-Tetrachloroethane 0.4285273A -13.1 304.34 0.49319615.00Tetrachloroethylene 0.7106068A -19.7 304.02 0.88485125.00Tetrahydrofuran 0.7972256A -19.6 304.02 0.99170295.00Toluene 0.3210031A 7.5 305.38 0.29858065.001,2,4-Trichlorobenzene 0.3889611A -21.1 303.95 0.49290825.001,1,1-Trichloroethane 0.2920205A -13.6 304.32 0.33794775.001,1,2-Trichloroethane 0.2935676A -17.9 304.11 0.3573855.00Trichloroethylene 1.201521A -15.9 304.21 1.4284065.00Trichlorofluoromethane (Freon 11) 1.093579A -15.2 304.24 1.2900045.001,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 0.7682369A -13.7 304.31 0.89039045.001,2,4-Trimethylbenzene 0.7854535A -15.9 304.20 0.93440445.001,3,5-Trimethylbenzene 1.421834A -27.0 303.65 1.9477115.00Vinyl Acetate 0.6100868A -12.5 304.38 0.69706395.00Vinyl Chloride 0.7780929A -16.4 308.36 0.930339610.0m&p-Xylene 0.753062A -19.1 304.04 0.93116995.00o-Xylene * Values outside of QC limits # Column to be used to flag Response Factor and %Diff/Drift values with an asterisk Page 26 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,NY,ME,NHAcetone AIHA,NY,ME,NHAcetone AIHA,FL,NJ,NY,ME,NH,VABenzene AIHA,FL,NJ,NY,ME,NH,VABenzene AIHA,FL,NJ,NY,ME,NH,VABenzyl chloride AIHA,FL,NJ,NY,ME,NH,VABenzyl chloride AIHA,NJ,NY,ME,NH,VABromodichloromethane AIHA,NJ,NY,ME,NH,VABromodichloromethane AIHA,NJ,NY,ME,NH,VABromoform AIHA,NJ,NY,ME,NH,VABromoform AIHA,FL,NJ,NY,ME,NHBromomethane AIHA,FL,NJ,NY,ME,NHBromomethane AIHA,NJ,NY,ME,NH,VA1,3-Butadiene AIHA,NJ,NY,ME,NH,VA1,3-Butadiene AIHA,FL,NJ,NY,ME,NH,VA2-Butanone (MEK) AIHA,FL,NJ,NY,ME,NH,VA2-Butanone (MEK) AIHA,NJ,NY,ME,NH,VACarbon Disulfide AIHA,NJ,NY,ME,NH,VACarbon Disulfide AIHA,FL,NJ,NY,ME,NH,VACarbon Tetrachloride AIHA,FL,NJ,NY,ME,NH,VACarbon Tetrachloride AIHA,FL,NJ,NY,ME,NH,VAChlorobenzene AIHA,FL,NJ,NY,ME,NH,VAChlorobenzene AIHA,FL,NJ,NY,ME,NH,VAChloroethane AIHA,FL,NJ,NY,ME,NH,VAChloroethane AIHA,FL,NJ,NY,ME,NH,VAChloroform AIHA,FL,NJ,NY,ME,NH,VAChloroform AIHA,FL,NJ,NY,ME,NH,VAChloromethane AIHA,FL,NJ,NY,ME,NH,VAChloromethane AIHA,NJ,NY,ME,NH,VACyclohexane AIHA,NJ,NY,ME,NH,VACyclohexane AIHA,NY,ME,NHDibromochloromethane AIHA,NY,ME,NHDibromochloromethane AIHA,NJ,NY,ME,NH1,2-Dibromoethane (EDB) AIHA,NJ,NY,ME,NH1,2-Dibromoethane (EDB) AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichlorobenzene AIHA,NJ,NY,ME,NH1,3-Dichlorobenzene AIHA,NJ,NY,ME,NH1,3-Dichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,4-Dichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,4-Dichlorobenzene AIHA,NY,ME,NHDichlorodifluoromethane (Freon 12) AIHA,NY,ME,NHDichlorodifluoromethane (Freon 12) AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethylene Page 27 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethylene AIHA,FL,NY,ME,NH,VAcis-1,2-Dichloroethylene AIHA,FL,NY,ME,NH,VAcis-1,2-Dichloroethylene AIHA,NJ,NY,ME,NH,VAtrans-1,2-Dichloroethylene AIHA,NJ,NY,ME,NH,VAtrans-1,2-Dichloroethylene AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloropropane AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloropropane AIHA,FL,NJ,NY,ME,NH,VAcis-1,3-Dichloropropene AIHA,FL,NJ,NY,ME,NH,VAcis-1,3-Dichloropropene AIHA,NY,ME,NHtrans-1,3-Dichloropropene AIHA,NY,ME,NHtrans-1,3-Dichloropropene AIHA,NJ,NY,ME,NH,VA1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) AIHA,NJ,NY,ME,NH,VA1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) AIHA,NJ,NY,ME,NH,VA1,4-Dioxane AIHA,NJ,NY,ME,NH,VA1,4-Dioxane AIHAEthanol AIHAEthanol AIHAEthyl Acetate AIHAEthyl Acetate AIHA,FL,NJ,NY,ME,NH,VAEthylbenzene AIHA,FL,NJ,NY,ME,NH,VAEthylbenzene AIHA,NJ4-Ethyltoluene AIHA,NJ4-Ethyltoluene AIHA,NJ,NY,ME,NH,VAHeptane AIHA,NJ,NY,ME,NH,VAHeptane AIHA,NJ,NY,ME,NH,VAHexachlorobutadiene AIHA,NJ,NY,ME,NH,VAHexachlorobutadiene AIHA,FL,NJ,NY,ME,NH,VAHexane AIHA,FL,NJ,NY,ME,NH,VAHexane AIHA2-Hexanone (MBK) AIHA2-Hexanone (MBK) AIHA,NY,ME,NHIsopropanol AIHA,NY,ME,NHIsopropanol AIHA,FL,NJ,NY,ME,NH,VAMethyl tert-Butyl Ether (MTBE) AIHA,FL,NJ,NY,ME,NH,VAMethyl tert-Butyl Ether (MTBE) AIHA,FL,NJ,NY,ME,NH,VAMethylene Chloride AIHA,FL,NJ,NY,ME,NH,VAMethylene Chloride AIHA,FL,NJ,NY,ME,NH4-Methyl-2-pentanone (MIBK) AIHA,FL,NJ,NY,ME,NH4-Methyl-2-pentanone (MIBK) NY,ME,NHNaphthalene NY,ME,NHNaphthalene AIHAPropene AIHAPropene AIHA,FL,NJ,NY,ME,NH,VAStyrene AIHA,FL,NJ,NY,ME,NH,VAStyrene AIHA,FL,NJ,NY,ME,NH,VA1,1,2,2-Tetrachloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1,2,2-Tetrachloroethane Page 28 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,FL,NJ,NY,ME,NH,VATetrachloroethylene AIHA,FL,NJ,NY,ME,NH,VATetrachloroethylene AIHATetrahydrofuran AIHATetrahydrofuran AIHA,FL,NJ,NY,ME,NH,VAToluene AIHA,FL,NJ,NY,ME,NH,VAToluene AIHA,NJ,NY,ME,NH,VA1,2,4-Trichlorobenzene AIHA,NJ,NY,ME,NH,VA1,2,4-Trichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,1,1-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1,1-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1,2-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1,2-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VATrichloroethylene AIHA,FL,NJ,NY,ME,NH,VATrichloroethylene AIHA,NY,ME,NHTrichlorofluoromethane (Freon 11) AIHA,NY,ME,NHTrichlorofluoromethane (Freon 11) AIHA,NJ,NY,ME,NH,VA1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) AIHA,NJ,NY,ME,NH,VA1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) AIHA,NJ,NY,ME,NH1,2,4-Trimethylbenzene AIHA,NJ,NY,ME,NH1,2,4-Trimethylbenzene AIHA,NJ,NY,ME,NH1,3,5-Trimethylbenzene AIHA,NJ,NY,ME,NH1,3,5-Trimethylbenzene AIHA,FL,NJ,NY,ME,NH,VAVinyl Acetate AIHA,FL,NJ,NY,ME,NH,VAVinyl Acetate AIHA,FL,NJ,NY,ME,NH,VAVinyl Chloride AIHA,FL,NJ,NY,ME,NH,VAVinyl Chloride AIHA,FL,NJ,NY,ME,NH,VAm&p-Xylene AIHA,FL,NJ,NY,ME,NH,VAm&p-Xylene AIHA,FL,NJ,NY,ME,NH,VAo-Xylene AIHA,FL,NJ,NY,ME,NH,VAo-Xylene Page 29 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 The CON-TEST Environmental Laboratory operates under the following certifications and accreditations: Code Description Number Expires 100033AIHA-LAP, LLC - ISO17025:2017AIHA 03/1/2020 M-MA100Massachusetts DEPMA 06/30/2020 PH-0567Connecticut Department of Publilc HealthCT 09/30/2021 10899 NELAPNew York State Department of HealthNY 04/1/2020 2516 NELAPNew Hampshire Environmental LabNH-S 02/5/2020 LAO00112Rhode Island Department of HealthRI 12/30/2019 652North Carolina Div. of Water QualityNC 12/31/2019 MA007 NELAPNew Jersey DEPNJ 06/30/2020 E871027 NELAPFlorida Department of HealthFL 06/30/2020 LL015036Vermont Department of Health Lead LaboratoryVT 07/30/2020 2011028State of MaineME 06/9/2021 460217Commonwealth of VirginiaVA 12/14/2019 2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2020 VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2020 25703North Carolina Department of HealthNC-DW 07/31/2020 68-05812Commonwealth of Pennsylvania DEPPA 06/30/2020 Page 30 of 33 Page 31 of 33 Page 32 of 33 Page 33 of 33 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 November 21, 2019 Andrew Besu Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 Project Location: Belmont, NC Client Job Number: Project Number: BKL-001 Laboratory Work Order Number: 19J1710 Enclosed are results of analyses for samples received by the laboratory on October 25, 2019. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kerry K. McGee Project Manager QA Officer Katherine Allen Laboratory Manager Daren Damboragian Page 1 of 24 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL SUMMARY 11/21/2019Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 ATTN: Andrew Besu BKL-001 19J1710 The results of analyses performed on the following samples submitted to the CON-TEST Analytical Laboratory are found in this report. PROJECT LOCATION: PURCHASE ORDER NUMBER: PROJECT NUMBER: REPORT DATE: WORK ORDER NUMBER: FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB Belmont, NC BKL-001 SS-Bld6-MP-3 19J1710-01 Sub Slab - EPA TO-15 SS-Bld6-MP-6 19J1710-02 Sub Slab - EPA TO-15 DUP-1 19J1710-03 Sub Slab - EPA TO-15 Page 2 of 24 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CASE NARRATIVE SUMMARY All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report. REVISED REPORT - 11/21/2019 - Report full TO-15 list per client’s request. The results of analyses reported only relate to samples submitted to the Con-Test Analytical Laboratory for testing. I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Lisa A. Worthington Technical Representative Page 3 of 24 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/25/2019 Work Order: 19J1710Sample Description/Location: Field Sample #: SS-Bld6-MP-3 Sample ID: 19J1710-01 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -7.2 Sampled: 10/25/2019 10:19 Canister ID: 2253 Flow Controller ID: 4306 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 4.5 8.0 10/31/19 15:50 BRFJ114192.8 6.6 Benzene ND 0.20 10/31/19 15:50 BRFND40.640.082 0.26 Benzyl chloride ND 0.20 10/31/19 15:50 BRFND41.00.052 0.27 Bromodichloromethane ND 0.20 10/31/19 15:50 BRFND41.30.074 0.49 Bromoform ND 0.20 10/31/19 15:50 BRFND42.10.090 0.93 Bromomethane ND 0.40 10/31/19 15:50 BRFND41.60.14 0.53 1,3-Butadiene ND 0.20 10/31/19 15:50 BRFND40.440.15 0.32 2-Butanone (MEK)1.8 8.0 10/31/19 15:50 BRFJ5.4 4240.37 1.1 Carbon Disulfide 0.17 2.0 10/31/19 15:50 BRFJ0.54 46.20.14 0.43 Carbon Tetrachloride ND 0.20 10/31/19 15:50 BRFND41.30.065 0.41 Chlorobenzene ND 0.20 10/31/19 15:50 BRFND40.920.098 0.45 Chloroethane ND 0.20 10/31/19 15:50 BRFND40.530.20 0.52 Chloroform ND 0.20 10/31/19 15:50 BRFND40.980.074 0.36 Chloromethane 0.70 0.40 10/31/19 15:50 BRF1.4 40.830.14 0.28 Cyclohexane ND 0.20 10/31/19 15:50 BRFND40.690.14 0.49 Dibromochloromethane ND 0.20 10/31/19 15:50 BRFND41.70.066 0.57 1,2-Dibromoethane (EDB)ND 0.20 10/31/19 15:50 BRFND41.50.078 0.60 1,2-Dichlorobenzene ND 0.20 10/31/19 15:50 BRFND41.20.096 0.58 1,3-Dichlorobenzene ND 0.20 10/31/19 15:50 BRFND41.20.10 0.62 1,4-Dichlorobenzene ND 0.20 10/31/19 15:50 BRFND41.20.12 0.73 Dichlorodifluoromethane (Freon 12)0.39 0.20 10/31/19 15:50 BRF1.9 40.990.087 0.43 1,1-Dichloroethane ND 0.20 10/31/19 15:50 BRFND40.810.061 0.25 1,2-Dichloroethane ND 0.20 10/31/19 15:50 BRFND40.810.076 0.31 1,1-Dichloroethylene ND 0.20 10/31/19 15:50 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 10/31/19 15:50 BRFND40.790.082 0.32 trans-1,2-Dichloroethylene ND 0.20 10/31/19 15:50 BRFND40.790.081 0.32 1,2-Dichloropropane ND 0.20 10/31/19 15:50 BRFND40.920.071 0.33 cis-1,3-Dichloropropene ND 0.20 10/31/19 15:50 BRFND40.910.070 0.32 trans-1,3-Dichloropropene ND 0.20 10/31/19 15:50 BRFND40.910.073 0.33 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 10/31/19 15:50 BRFND41.40.11 0.79 1,4-Dioxane ND 2.0 10/31/19 15:50 BRFND47.21.3 4.6 Ethanol 4.8 8.0 10/31/19 15:50 BRFJ9.0 4153.6 6.7 Ethyl Acetate 0.48 0.20 10/31/19 15:50 BRF1.7 40.720.15 0.54 Ethylbenzene ND 0.20 10/31/19 15:50 BRFND40.870.12 0.50 4-Ethyltoluene ND 0.20 10/31/19 15:50 BRFND40.980.12 0.60 Heptane ND 0.20 10/31/19 15:50 BRFND40.820.12 0.48 Hexachlorobutadiene ND 0.20 10/31/19 15:50 BRFND42.10.092 0.98 Hexane ND 8.0 10/31/19 15:50 BRFND4280.35 1.2 2-Hexanone (MBK)ND 0.20 10/31/19 15:50 BRFND40.820.12 0.48 Isopropanol 0.71 8.0 10/31/19 15:50 BRFJ1.7 4200.37 0.90 Methyl tert-Butyl Ether (MTBE)ND 0.20 10/31/19 15:50 BRFND40.720.10 0.36 Methylene Chloride ND 2.0 10/31/19 15:50 BRFND46.90.24 0.84 4-Methyl-2-pentanone (MIBK)ND 0.20 10/31/19 15:50 BRFND40.820.10 0.43 Naphthalene ND 0.20 10/31/19 15:50 BRFND41.00.15 0.80 Propene ND 8.0 10/31/19 15:50 BRFND4140.37 0.64 Styrene ND 0.20 10/31/19 15:50 BRFND40.850.12 0.53 1,1,2,2-Tetrachloroethane ND 0.20 10/31/19 15:50 BRFND41.40.089 0.61 Page 4 of 24 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/25/2019 Work Order: 19J1710Sample Description/Location: Field Sample #: SS-Bld6-MP-3 Sample ID: 19J1710-01 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -7.2 Sampled: 10/25/2019 10:19 Canister ID: 2253 Flow Controller ID: 4306 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 0.12 0.20 10/31/19 15:50 BRFJ0.79 41.40.11 0.75 Tetrahydrofuran 0.34 0.20 10/31/19 15:50 BRF1.0 40.590.20 0.59 Toluene 0.28 0.20 10/31/19 15:50 BRF1.0 40.750.10 0.39 1,2,4-Trichlorobenzene ND 0.20 10/31/19 15:50 BRFND41.50.14 1.0 1,1,1-Trichloroethane ND 0.20 10/31/19 15:50 BRFND41.10.075 0.41 1,1,2-Trichloroethane ND 0.20 10/31/19 15:50 BRFND41.10.082 0.45 Trichloroethylene ND 0.20 10/31/19 15:50 BRFND41.10.081 0.43 Trichlorofluoromethane (Freon 11)0.30 0.80 10/31/19 15:50 BRFJ1.7 44.50.15 0.85 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 10/31/19 15:50 BRFND46.10.15 1.2 1,2,4-Trimethylbenzene ND 0.20 10/31/19 15:50 BRFND40.980.13 0.63 1,3,5-Trimethylbenzene ND 0.20 10/31/19 15:50 BRFND40.980.13 0.62 Vinyl Acetate ND 4.0 10/31/19 15:50 BRFND4140.12 0.44 Vinyl Chloride ND 0.20 10/31/19 15:50 BRFND40.510.13 0.32 m&p-Xylene ND 0.40 10/31/19 15:50 BRFND41.70.23 1.00 o-Xylene ND 0.20 10/31/19 15:50 BRFND40.870.12 0.54 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)98.6 10/31/19 15:5070-130 Page 5 of 24 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/25/2019 Work Order: 19J1710Sample Description/Location: Field Sample #: SS-Bld6-MP-6 Sample ID: 19J1710-02 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -6.1 Sampled: 10/25/2019 11:00 Canister ID: 2328 Flow Controller ID: 4248 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 11 8.0 10/31/19 16:30 BRF254192.8 6.6 Benzene ND 0.20 10/31/19 16:30 BRFND40.640.082 0.26 Benzyl chloride ND 0.20 10/31/19 16:30 BRFND41.00.052 0.27 Bromodichloromethane ND 0.20 10/31/19 16:30 BRFND41.30.074 0.49 Bromoform ND 0.20 10/31/19 16:30 BRFND42.10.090 0.93 Bromomethane ND 0.40 10/31/19 16:30 BRFND41.60.14 0.53 1,3-Butadiene ND 0.20 10/31/19 16:30 BRFND40.440.15 0.32 2-Butanone (MEK)2.8 8.0 10/31/19 16:30 BRFJ8.2 4240.37 1.1 Carbon Disulfide ND 2.0 10/31/19 16:30 BRFND46.20.14 0.43 Carbon Tetrachloride 0.068 0.20 10/31/19 16:30 BRFJ0.43 41.30.065 0.41 Chlorobenzene ND 0.20 10/31/19 16:30 BRFND40.920.098 0.45 Chloroethane ND 0.20 10/31/19 16:30 BRFND40.530.20 0.52 Chloroform 0.084 0.20 10/31/19 16:30 BRFJ0.41 40.980.074 0.36 Chloromethane 1.4 0.40 10/31/19 16:30 BRF3.0 40.830.14 0.28 Cyclohexane ND 0.20 10/31/19 16:30 BRFND40.690.14 0.49 Dibromochloromethane ND 0.20 10/31/19 16:30 BRFND41.70.066 0.57 1,2-Dibromoethane (EDB)ND 0.20 10/31/19 16:30 BRFND41.50.078 0.60 1,2-Dichlorobenzene ND 0.20 10/31/19 16:30 BRFND41.20.096 0.58 1,3-Dichlorobenzene ND 0.20 10/31/19 16:30 BRFND41.20.10 0.62 1,4-Dichlorobenzene ND 0.20 10/31/19 16:30 BRFND41.20.12 0.73 Dichlorodifluoromethane (Freon 12)0.38 0.20 10/31/19 16:30 BRF1.9 40.990.087 0.43 1,1-Dichloroethane ND 0.20 10/31/19 16:30 BRFND40.810.061 0.25 1,2-Dichloroethane ND 0.20 10/31/19 16:30 BRFND40.810.076 0.31 1,1-Dichloroethylene ND 0.20 10/31/19 16:30 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 10/31/19 16:30 BRFND40.790.082 0.32 trans-1,2-Dichloroethylene ND 0.20 10/31/19 16:30 BRFND40.790.081 0.32 1,2-Dichloropropane ND 0.20 10/31/19 16:30 BRFND40.920.071 0.33 cis-1,3-Dichloropropene ND 0.20 10/31/19 16:30 BRFND40.910.070 0.32 trans-1,3-Dichloropropene ND 0.20 10/31/19 16:30 BRFND40.910.073 0.33 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 10/31/19 16:30 BRFND41.40.11 0.79 1,4-Dioxane ND 2.0 10/31/19 16:30 BRFND47.21.3 4.6 Ethanol 6.8 8.0 10/31/19 16:30 BRFJ134153.6 6.7 Ethyl Acetate ND 0.20 10/31/19 16:30 BRFND40.720.15 0.54 Ethylbenzene ND 0.20 10/31/19 16:30 BRFND40.870.12 0.50 4-Ethyltoluene ND 0.20 10/31/19 16:30 BRFND40.980.12 0.60 Heptane ND 0.20 10/31/19 16:30 BRFND40.820.12 0.48 Hexachlorobutadiene ND 0.20 10/31/19 16:30 BRFND42.10.092 0.98 Hexane ND 8.0 10/31/19 16:30 BRFND4280.35 1.2 2-Hexanone (MBK)ND 0.20 10/31/19 16:30 BRFND40.820.12 0.48 Isopropanol 0.71 8.0 10/31/19 16:30 BRFJ1.7 4200.37 0.90 Methyl tert-Butyl Ether (MTBE)ND 0.20 10/31/19 16:30 BRFND40.720.10 0.36 Methylene Chloride 0.51 2.0 10/31/19 16:30 BRFJ1.8 46.90.24 0.84 4-Methyl-2-pentanone (MIBK)ND 0.20 10/31/19 16:30 BRFND40.820.10 0.43 Naphthalene ND 0.20 10/31/19 16:30 BRFND41.00.15 0.80 Propene ND 8.0 10/31/19 16:30 BRFND4140.37 0.64 Styrene ND 0.20 10/31/19 16:30 BRFND40.850.12 0.53 1,1,2,2-Tetrachloroethane ND 0.20 10/31/19 16:30 BRFND41.40.089 0.61 Page 6 of 24 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/25/2019 Work Order: 19J1710Sample Description/Location: Field Sample #: SS-Bld6-MP-6 Sample ID: 19J1710-02 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -6.1 Sampled: 10/25/2019 11:00 Canister ID: 2328 Flow Controller ID: 4248 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene ND 0.20 10/31/19 16:30 BRFND41.40.11 0.75 Tetrahydrofuran 0.59 0.20 10/31/19 16:30 BRF1.7 40.590.20 0.59 Toluene 0.23 0.20 10/31/19 16:30 BRF0.86 40.750.10 0.39 1,2,4-Trichlorobenzene ND 0.20 10/31/19 16:30 BRFND41.50.14 1.0 1,1,1-Trichloroethane ND 0.20 10/31/19 16:30 BRFND41.10.075 0.41 1,1,2-Trichloroethane ND 0.20 10/31/19 16:30 BRFND41.10.082 0.45 Trichloroethylene ND 0.20 10/31/19 16:30 BRFND41.10.081 0.43 Trichlorofluoromethane (Freon 11)0.22 0.80 10/31/19 16:30 BRFJ1.2 44.50.15 0.85 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 10/31/19 16:30 BRFND46.10.15 1.2 1,2,4-Trimethylbenzene ND 0.20 10/31/19 16:30 BRFND40.980.13 0.63 1,3,5-Trimethylbenzene ND 0.20 10/31/19 16:30 BRFND40.980.13 0.62 Vinyl Acetate ND 4.0 10/31/19 16:30 BRFND4140.12 0.44 Vinyl Chloride ND 0.20 10/31/19 16:30 BRFND40.510.13 0.32 m&p-Xylene ND 0.40 10/31/19 16:30 BRFND41.70.23 1.00 o-Xylene ND 0.20 10/31/19 16:30 BRFND40.870.12 0.54 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)98.4 10/31/19 16:3070-130 Page 7 of 24 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/25/2019 Work Order: 19J1710Sample Description/Location: Field Sample #: DUP-1 Sample ID: 19J1710-03 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -6.9 Sampled: 10/25/2019 00:00 Canister ID: 2346 Flow Controller ID: 4306 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 5.0 8.0 10/31/19 17:11 BRFJ124192.8 6.6 Benzene ND 0.20 10/31/19 17:11 BRFND40.640.082 0.26 Benzyl chloride ND 0.20 10/31/19 17:11 BRFND41.00.052 0.27 Bromodichloromethane ND 0.20 10/31/19 17:11 BRFND41.30.074 0.49 Bromoform ND 0.20 10/31/19 17:11 BRFND42.10.090 0.93 Bromomethane ND 0.40 10/31/19 17:11 BRFND41.60.14 0.53 1,3-Butadiene ND 0.20 10/31/19 17:11 BRFND40.440.15 0.32 2-Butanone (MEK)2.0 8.0 10/31/19 17:11 BRFJ6.0 4240.37 1.1 Carbon Disulfide ND 2.0 10/31/19 17:11 BRFND46.20.14 0.43 Carbon Tetrachloride ND 0.20 10/31/19 17:11 BRFND41.30.065 0.41 Chlorobenzene ND 0.20 10/31/19 17:11 BRFND40.920.098 0.45 Chloroethane ND 0.20 10/31/19 17:11 BRFND40.530.20 0.52 Chloroform ND 0.20 10/31/19 17:11 BRFND40.980.074 0.36 Chloromethane 0.71 0.40 10/31/19 17:11 BRF1.5 40.830.14 0.28 Cyclohexane ND 0.20 10/31/19 17:11 BRFND40.690.14 0.49 Dibromochloromethane ND 0.20 10/31/19 17:11 BRFND41.70.066 0.57 1,2-Dibromoethane (EDB)ND 0.20 10/31/19 17:11 BRFND41.50.078 0.60 1,2-Dichlorobenzene ND 0.20 10/31/19 17:11 BRFND41.20.096 0.58 1,3-Dichlorobenzene ND 0.20 10/31/19 17:11 BRFND41.20.10 0.62 1,4-Dichlorobenzene ND 0.20 10/31/19 17:11 BRFND41.20.12 0.73 Dichlorodifluoromethane (Freon 12)0.38 0.20 10/31/19 17:11 BRF1.9 40.990.087 0.43 1,1-Dichloroethane ND 0.20 10/31/19 17:11 BRFND40.810.061 0.25 1,2-Dichloroethane ND 0.20 10/31/19 17:11 BRFND40.810.076 0.31 1,1-Dichloroethylene ND 0.20 10/31/19 17:11 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 10/31/19 17:11 BRFND40.790.082 0.32 trans-1,2-Dichloroethylene ND 0.20 10/31/19 17:11 BRFND40.790.081 0.32 1,2-Dichloropropane ND 0.20 10/31/19 17:11 BRFND40.920.071 0.33 cis-1,3-Dichloropropene ND 0.20 10/31/19 17:11 BRFND40.910.070 0.32 trans-1,3-Dichloropropene ND 0.20 10/31/19 17:11 BRFND40.910.073 0.33 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 10/31/19 17:11 BRFND41.40.11 0.79 1,4-Dioxane ND 2.0 10/31/19 17:11 BRFND47.21.3 4.6 Ethanol 5.0 8.0 10/31/19 17:11 BRFJ9.3 4153.6 6.7 Ethyl Acetate 0.31 0.20 10/31/19 17:11 BRF1.1 40.720.15 0.54 Ethylbenzene ND 0.20 10/31/19 17:11 BRFND40.870.12 0.50 4-Ethyltoluene ND 0.20 10/31/19 17:11 BRFND40.980.12 0.60 Heptane ND 0.20 10/31/19 17:11 BRFND40.820.12 0.48 Hexachlorobutadiene ND 0.20 10/31/19 17:11 BRFND42.10.092 0.98 Hexane ND 8.0 10/31/19 17:11 BRFND4280.35 1.2 2-Hexanone (MBK)ND 0.20 10/31/19 17:11 BRFND40.820.12 0.48 Isopropanol 0.57 8.0 10/31/19 17:11 BRFJ1.4 4200.37 0.90 Methyl tert-Butyl Ether (MTBE)ND 0.20 10/31/19 17:11 BRFND40.720.10 0.36 Methylene Chloride ND 2.0 10/31/19 17:11 BRFND46.90.24 0.84 4-Methyl-2-pentanone (MIBK)ND 0.20 10/31/19 17:11 BRFND40.820.10 0.43 Naphthalene ND 0.20 10/31/19 17:11 BRFND41.00.15 0.80 Propene ND 8.0 10/31/19 17:11 BRFND4140.37 0.64 Styrene ND 0.20 10/31/19 17:11 BRFND40.850.12 0.53 1,1,2,2-Tetrachloroethane ND 0.20 10/31/19 17:11 BRFND41.40.089 0.61 Page 8 of 24 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 10/25/2019 Work Order: 19J1710Sample Description/Location: Field Sample #: DUP-1 Sample ID: 19J1710-03 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -6.9 Sampled: 10/25/2019 00:00 Canister ID: 2346 Flow Controller ID: 4306 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene ND 0.20 10/31/19 17:11 BRFND41.40.11 0.75 Tetrahydrofuran 0.35 0.20 10/31/19 17:11 BRF1.0 40.590.20 0.59 Toluene 0.24 0.20 10/31/19 17:11 BRF0.90 40.750.10 0.39 1,2,4-Trichlorobenzene ND 0.20 10/31/19 17:11 BRFND41.50.14 1.0 1,1,1-Trichloroethane ND 0.20 10/31/19 17:11 BRFND41.10.075 0.41 1,1,2-Trichloroethane ND 0.20 10/31/19 17:11 BRFND41.10.082 0.45 Trichloroethylene ND 0.20 10/31/19 17:11 BRFND41.10.081 0.43 Trichlorofluoromethane (Freon 11)0.31 0.80 10/31/19 17:11 BRFJ1.7 44.50.15 0.85 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 10/31/19 17:11 BRFND46.10.15 1.2 1,2,4-Trimethylbenzene ND 0.20 10/31/19 17:11 BRFND40.980.13 0.63 1,3,5-Trimethylbenzene ND 0.20 10/31/19 17:11 BRFND40.980.13 0.62 Vinyl Acetate ND 4.0 10/31/19 17:11 BRFND4140.12 0.44 Vinyl Chloride ND 0.20 10/31/19 17:11 BRFND40.510.13 0.32 m&p-Xylene ND 0.40 10/31/19 17:11 BRFND41.70.23 1.00 o-Xylene ND 0.20 10/31/19 17:11 BRFND40.870.12 0.54 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)99.0 10/31/19 17:1170-130 Page 9 of 24 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Sample Extraction Data Prep Method: TO-15 Prep-EPA TO-15 Lab Number [Field ID]Batch Date Pressure Dilution Pre Dilution Pre-Dil Initial mL Pre-Dil Final mL Default Injection mL Actual Injection mL 19J1710-01 [SS-Bld6-MP-3]B244818 1.5 1 N/A 1000 400 150 10/31/19 19J1710-02 [SS-Bld6-MP-6]B244818 1.5 1 N/A 1000 400 150 10/31/19 19J1710-03 [DUP-1]B244818 1.5 1 N/A 1000 400 150 10/31/19 Page 10 of 24 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B244818 - TO-15 Prep Blank (B244818-BLK1)Prepared & Analyzed: 10/31/19 1.4NDAcetone 0.035NDBenzene 0.035NDBenzyl chloride 0.035NDBromodichloromethane 0.035NDBromoform 0.035NDBromomethane 0.035ND1,3-Butadiene 1.4ND2-Butanone (MEK) 0.35NDCarbon Disulfide 0.035NDCarbon Tetrachloride 0.035NDChlorobenzene 0.035NDChloroethane 0.035NDChloroform 0.070NDChloromethane 0.035NDCyclohexane 0.035NDDibromochloromethane 0.035ND1,2-Dibromoethane (EDB) 0.035ND1,2-Dichlorobenzene 0.035ND1,3-Dichlorobenzene 0.035ND1,4-Dichlorobenzene 0.035NDDichlorodifluoromethane (Freon 12) 0.035ND1,1-Dichloroethane 0.035ND1,2-Dichloroethane 0.035ND1,1-Dichloroethylene 0.035NDcis-1,2-Dichloroethylene 0.035NDtrans-1,2-Dichloroethylene 0.035ND1,2-Dichloropropane 0.035NDcis-1,3-Dichloropropene 0.035NDtrans-1,3-Dichloropropene 0.035ND1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.35ND1,4-Dioxane 1.4NDEthanol 0.035NDEthyl Acetate 0.035NDEthylbenzene 0.035ND4-Ethyltoluene 0.035NDHeptane 0.035NDHexachlorobutadiene 1.4NDHexane 0.035ND2-Hexanone (MBK) 1.4NDIsopropanol 0.035NDMethyl tert-Butyl Ether (MTBE) 0.35NDMethylene Chloride 0.035ND4-Methyl-2-pentanone (MIBK) 0.035NDNaphthalene 1.4NDPropene 0.035NDStyrene Page 11 of 24 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B244818 - TO-15 Prep Blank (B244818-BLK1)Prepared & Analyzed: 10/31/19 0.035ND1,1,2,2-Tetrachloroethane 0.035NDTetrachloroethylene 0.035NDTetrahydrofuran 0.035NDToluene 0.035ND1,2,4-Trichlorobenzene 0.035ND1,1,1-Trichloroethane 0.035ND1,1,2-Trichloroethane 0.035NDTrichloroethylene 0.14NDTrichlorofluoromethane (Freon 11) 0.14ND1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 0.035ND1,2,4-Trimethylbenzene 0.035ND1,3,5-Trimethylbenzene 0.70NDVinyl Acetate 0.035NDVinyl Chloride 0.070NDm&p-Xylene 0.035NDo-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)98.17.85 LCS (B244818-BS1)Prepared & Analyzed: 10/31/19 5.00 70-13096.24.81Acetone 5.00 70-13085.04.25Benzene 5.00 70-13097.94.90Benzyl chloride 5.00 70-13085.24.26Bromodichloromethane 5.00 70-13094.44.72Bromoform 5.00 70-13095.94.80Bromomethane 5.00 70-13093.24.661,3-Butadiene 5.00 70-13090.64.532-Butanone (MEK) 5.00 70-13089.84.49Carbon Disulfide 5.00 70-13086.94.35Carbon Tetrachloride 5.00 70-13087.14.36Chlorobenzene 5.00 70-13092.64.63Chloroethane 5.00 70-13088.44.42Chloroform 5.00 70-13088.04.40Chloromethane 5.00 70-13080.44.02Cyclohexane 5.00 70-13090.74.54Dibromochloromethane 5.00 70-13087.34.371,2-Dibromoethane (EDB) 5.00 70-13092.14.601,2-Dichlorobenzene 5.00 70-13092.94.651,3-Dichlorobenzene 5.00 70-13091.84.591,4-Dichlorobenzene 5.00 70-13098.94.95Dichlorodifluoromethane (Freon 12) 5.00 70-13088.94.441,1-Dichloroethane 5.00 70-13088.64.431,2-Dichloroethane 5.00 70-13087.54.381,1-Dichloroethylene 5.00 70-13088.34.41cis-1,2-Dichloroethylene 5.00 70-13089.34.46trans-1,2-Dichloroethylene 5.00 70-13086.14.311,2-Dichloropropane Page 12 of 24 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B244818 - TO-15 Prep LCS (B244818-BS1)Prepared & Analyzed: 10/31/19 5.00 70-13083.74.18cis-1,3-Dichloropropene 5.00 70-13092.94.65trans-1,3-Dichloropropene 5.00 70-13093.04.651,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 5.00 70-13099.84.991,4-Dioxane 5.00 70-1301256.26Ethanol 5.00 70-13085.04.25Ethyl Acetate 5.00 70-13089.74.49Ethylbenzene 5.00 70-13093.74.684-Ethyltoluene 5.00 70-13082.84.14Heptane 5.00 70-13092.24.61Hexachlorobutadiene 5.00 70-1301005.01Hexane 5.00 70-13094.64.732-Hexanone (MBK) 5.00 70-13095.44.77Isopropanol 5.00 70-13090.74.53Methyl tert-Butyl Ether (MTBE) 5.00 70-13086.54.32Methylene Chloride 5.00 70-13087.74.394-Methyl-2-pentanone (MIBK) 5.00 70-1301015.03Naphthalene 5.00 70-13083.34.16Propene 5.00 70-13093.84.69Styrene 5.00 70-13087.54.381,1,2,2-Tetrachloroethane 5.00 70-13085.54.27Tetrachloroethylene 5.00 70-1301045.22Tetrahydrofuran 5.00 70-13089.64.48Toluene 5.00 70-1301015.041,2,4-Trichlorobenzene 5.00 70-13080.04.001,1,1-Trichloroethane 5.00 70-13087.64.381,1,2-Trichloroethane 5.00 70-13085.44.27Trichloroethylene 5.00 70-13094.54.73Trichlorofluoromethane (Freon 11) 5.00 70-13087.34.361,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 5.00 70-13094.04.701,2,4-Trimethylbenzene 5.00 70-13093.34.661,3,5-Trimethylbenzene 5.00 70-1301015.07Vinyl Acetate 5.00 70-13094.14.70Vinyl Chloride 10.0 70-13091.89.18m&p-Xylene 5.00 70-13092.04.60o-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)99.97.99 Page 13 of 24 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Note: Blank Subtraction is not performed unless otherwise noted *QC result is outside of established limits. Wide recovery limits established for difficult compound. Wide RPD limits established for difficult compound. #Data exceeded client recommended or regulatory level RL Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference LCS Laboratory Control Sample Laboratory Control SampleLCS Dup Duplicate Laboratory Control Sample MS Matrix Spike Sample MS Dup Duplicate Matrix Spike Sample REC Recovery QC Quality Control ppbv Parts per billion volume EPA United States Environmental Protection Agency Percent Recovery% REC ND Not Detected Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the calculation which have not been rounded. Not ApplicableN/A DL Detection Limit Not CalculatedNC LFB/LCS Lab Fortified Blank/Lab Control Sample ORP Oxidation-Reduction Potential Not dry weight correctedwet Percent weight% wt KilogramKg Gramg Milligrammg Microgramg Nanogramng LiterL MillilitermL Microliter L Cubic Meterm3 Extractable Petroleum HydrocarbonsEPH Volatile Petroleum HydrocarbonsVPH Air Petroleum HydrocarbonsAPH Flame Ionization DetectorFID Photo Ionization DetectorPID FLAG/QUALIFIER SUMMARY Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag). J ANALYST Raisa A. PetraitisRAP Meghan E. KelleyMEK Kerry K. McGeeKKM Brittany R. FiskBRF Page 14 of 24 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q Initial Cal Check (S041952-ICV1 )Lab File ID: G1930117.D Analyzed: 10/28/19 23:11 Bromochloromethane (1)392547 8.54 392415 8.54 60 - 140100 0.0000 +/-0.50 1,4-Difluorobenzene (1)984411 10.314 974698 10.32 60 - 140101 -0.0060 +/-0.50 Chlorobenzene-d5 (1)925298 14.691 911790 14.691 60 - 140101 0.0000 +/-0.50 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q Calibration Check (S042095-CCV1 )Lab File ID: G1930404.D Analyzed: 10/31/19 11:22 Bromochloromethane (1)343334 8.54 392415 8.54 60 - 14087 0.0000 +/-0.50 1,4-Difluorobenzene (1)853570 10.314 974698 10.32 60 - 14088 -0.0060 +/-0.50 Chlorobenzene-d5 (1)797324 14.691 911790 14.691 60 - 14087 0.0000 +/-0.50 LCS (B244818-BS1 )Lab File ID: G1930405.D Analyzed: 10/31/19 12:02 Bromochloromethane (1)341287 8.54 343334 8.54 60 - 14099 0.0000 +/-0.50 1,4-Difluorobenzene (1)856229 10.32 853570 10.314 60 - 140100 0.0060 +/-0.50 Chlorobenzene-d5 (1)795901 14.691 797324 14.691 60 - 140100 0.0000 +/-0.50 Blank (B244818-BLK1 )Lab File ID: G1930407.D Analyzed: 10/31/19 13:25 Bromochloromethane (1)337026 8.54 343334 8.54 60 - 14098 0.0000 +/-0.50 1,4-Difluorobenzene (1)824969 10.32 853570 10.314 60 - 14097 0.0060 +/-0.50 Chlorobenzene-d5 (1)751676 14.691 797324 14.691 60 - 14094 0.0000 +/-0.50 SS-Bld6-MP-3 (19J1710-01 )Lab File ID: G1930408.D Analyzed: 10/31/19 15:50 Bromochloromethane (1)338587 8.54 343334 8.54 60 - 14099 0.0000 +/-0.50 1,4-Difluorobenzene (1)813123 10.314 853570 10.314 60 - 14095 0.0000 +/-0.50 Chlorobenzene-d5 (1)748533 14.691 797324 14.691 60 - 14094 0.0000 +/-0.50 SS-Bld6-MP-6 (19J1710-02 )Lab File ID: G1930409.D Analyzed: 10/31/19 16:30 Bromochloromethane (1)336431 8.54 343334 8.54 60 - 14098 0.0000 +/-0.50 1,4-Difluorobenzene (1)807891 10.314 853570 10.314 60 - 14095 0.0000 +/-0.50 Chlorobenzene-d5 (1)725323 14.691 797324 14.691 60 - 14091 0.0000 +/-0.50 DUP-1 (19J1710-03 )Lab File ID: G1930410.D Analyzed: 10/31/19 17:11 Bromochloromethane (1)338544 8.54 343334 8.54 60 - 14099 0.0000 +/-0.50 1,4-Difluorobenzene (1)811806 10.32 853570 10.314 60 - 14095 0.0060 +/-0.50 Chlorobenzene-d5 (1)747388 14.691 797324 14.691 60 - 14094 0.0000 +/-0.50 Page 15 of 24 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S042095-CCV1 COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR STD 0.9225256A 2.1 305.10 0.90382385.00Acetone 0.9372757A -7.6 304.62 1.0140395.00Benzene 1.178215A 7.3 305.36 1.0980465.00Benzyl chloride 0.6784118A -6.4 304.68 0.72484135.00Bromodichloromethane 0.5053644A 5.3 305.27 0.47983765.00Bromoform 0.5837255A 1.4 305.07 0.57547255.00Bromomethane 0.5217683A -0.2 304.99 0.52281445.001,3-Butadiene 1.409133A -3.9 304.81 1.46565.002-Butanone (MEK) 2.006834A -6.0 304.70 2.1356815.00Carbon Disulfide 0.5174259A -4.2 304.79 0.54013625.00Carbon Tetrachloride 0.8504628A -4.4 304.78 0.88954195.00Chlorobenzene 0.3407527A -0.8 304.96 0.34361455.00Chloroethane 1.506195A -5.5 304.73 1.5933635.00Chloroform 0.6252291A -4.4 304.78 0.65400955.00Chloromethane 0.3893239A -10.6 304.47 0.43525775.00Cyclohexane 0.5940431A 0.02 305.00 0.59391695.00Dibromochloromethane 0.5902725A -3.3 304.83 0.61055525.001,2-Dibromoethane (EDB) 0.6622974A -0.8 304.96 0.66778785.001,2-Dichlorobenzene 0.733925A 2.1 305.11 0.71854575.001,3-Dichlorobenzene 0.72406A -0.2 304.99 0.72554295.001,4-Dichlorobenzene 1.677438A 4.8 305.24 1.6007995.00Dichlorodifluoromethane (Freon 12) 1.314494A -7.7 304.62 1.4236055.001,1-Dichloroethane 0.9690575A -5.7 304.71 1.0281225.001,2-Dichloroethane 1.157171A -4.3 304.78 1.2096035.001,1-Dichloroethylene 0.9935049A -4.6 304.77 1.041165.00cis-1,2-Dichloroethylene 1.01737A -4.7 304.77 1.0672335.00trans-1,2-Dichloroethylene 0.3522504A -5.7 304.72 0.37358195.001,2-Dichloropropane 0.5739677A -4.2 304.79 0.5988965.00cis-1,3-Dichloropropene 0.4876498A -1.5 304.92 0.49517085.00trans-1,3-Dichloropropene 1.691568A 5.5 305.28 1.6034585.001,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.1766941A -1.1 304.94 0.17866815.001,4-Dioxane 0.1508642A 13.1 305.66 0.13334985.00Ethanol 0.2674573A -0.5 304.97 0.26886115.00Ethyl Acetate 1.54072A -0.7 304.96 1.5517955.00Ethylbenzene 1.571053A 4.5 305.22 1.5038535.004-Ethyltoluene 0.2970245A -6.4 304.68 0.31737615.00Heptane 0.3646939A -6.7 304.66 0.39086215.00Hexachlorobutadiene 0.8251883L 8.4 305.42 0.91474595.00Hexane Page 16 of 24 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S042095-CCV1 COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR STD 0.695061A 0.7 305.03 0.69035625.002-Hexanone (MBK) 1.054483A 6.9 305.35 0.98624535.00Isopropanol 2.009915A 0.2 305.01 2.0052845.00Methyl tert-Butyl Ether (MTBE) 0.7923014A -7.5 304.63 0.85608435.00Methylene Chloride 0.715849A -2.5 304.88 0.73396925.004-Methyl-2-pentanone (MIBK) 1.262198A 2.2 305.11 1.2347615.00Naphthalene 0.5324821A -9.5 304.53 0.58820095.00Propene 0.8668155A 4.3 305.21 0.83144665.00Styrene 0.9316223A -2.8 304.86 0.9588535.001,1,2,2-Tetrachloroethane 0.4195675A -5.6 304.72 0.44433235.00Tetrachloroethylene 0.3111326A 4.6 305.23 0.29745935.00Tetrahydrofuran 1.167551A -3.3 304.83 1.2079475.00Toluene 0.4871977A 4.6 305.23 0.46579535.001,2,4-Trichlorobenzene 0.5706536A -6.1 304.70 0.60760325.001,1,1-Trichloroethane 0.398519A -3.8 304.81 0.41421065.001,1,2-Trichloroethane 0.3854231A -6.5 304.67 0.41236235.00Trichloroethylene 1.318492A 1.0 305.05 1.3059775.00Trichlorofluoromethane (Freon 11) 1.355182A -4.3 304.78 1.4163125.001,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 1.256053A 5.0 305.25 1.1962765.001,2,4-Trimethylbenzene 1.288899A 5.9 305.29 1.2174955.001,3,5-Trimethylbenzene 2.066368A 3.2 305.16 2.0014535.00Vinyl Acetate 0.7179854A 1.6 305.08 0.70697865.00Vinyl Chloride 1.190481A 1.3 3010.1 1.1750310.0m&p-Xylene 1.218436A 1.5 305.07 1.2006045.00o-Xylene * Values outside of QC limits # Column to be used to flag Response Factor and %Diff/Drift values with an asterisk Page 17 of 24 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,NY,ME,NHAcetone AIHA,NY,ME,NHAcetone AIHA,FL,NJ,NY,ME,NH,VABenzene AIHA,FL,NJ,NY,ME,NH,VABenzene AIHA,FL,NJ,NY,ME,NH,VABenzyl chloride AIHA,FL,NJ,NY,ME,NH,VABenzyl chloride AIHA,NJ,NY,ME,NH,VABromodichloromethane AIHA,NJ,NY,ME,NH,VABromodichloromethane AIHA,NJ,NY,ME,NH,VABromoform AIHA,NJ,NY,ME,NH,VABromoform AIHA,FL,NJ,NY,ME,NHBromomethane AIHA,FL,NJ,NY,ME,NHBromomethane AIHA,NJ,NY,ME,NH,VA1,3-Butadiene AIHA,NJ,NY,ME,NH,VA1,3-Butadiene AIHA,FL,NJ,NY,ME,NH,VA2-Butanone (MEK) AIHA,FL,NJ,NY,ME,NH,VA2-Butanone (MEK) AIHA,NJ,NY,ME,NH,VACarbon Disulfide AIHA,NJ,NY,ME,NH,VACarbon Disulfide AIHA,FL,NJ,NY,ME,NH,VACarbon Tetrachloride AIHA,FL,NJ,NY,ME,NH,VACarbon Tetrachloride AIHA,FL,NJ,NY,ME,NH,VAChlorobenzene AIHA,FL,NJ,NY,ME,NH,VAChlorobenzene AIHA,FL,NJ,NY,ME,NH,VAChloroethane AIHA,FL,NJ,NY,ME,NH,VAChloroethane AIHA,FL,NJ,NY,ME,NH,VAChloroform AIHA,FL,NJ,NY,ME,NH,VAChloroform AIHA,FL,NJ,NY,ME,NH,VAChloromethane AIHA,FL,NJ,NY,ME,NH,VAChloromethane AIHA,NJ,NY,ME,NH,VACyclohexane AIHA,NJ,NY,ME,NH,VACyclohexane AIHA,NY,ME,NHDibromochloromethane AIHA,NY,ME,NHDibromochloromethane AIHA,NJ,NY,ME,NH1,2-Dibromoethane (EDB) AIHA,NJ,NY,ME,NH1,2-Dibromoethane (EDB) AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichlorobenzene AIHA,NJ,NY,ME,NH1,3-Dichlorobenzene AIHA,NJ,NY,ME,NH1,3-Dichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,4-Dichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,4-Dichlorobenzene AIHA,NY,ME,NHDichlorodifluoromethane (Freon 12) AIHA,NY,ME,NHDichlorodifluoromethane (Freon 12) AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethylene Page 18 of 24 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethylene AIHA,FL,NY,ME,NH,VAcis-1,2-Dichloroethylene AIHA,FL,NY,ME,NH,VAcis-1,2-Dichloroethylene AIHA,NJ,NY,ME,NH,VAtrans-1,2-Dichloroethylene AIHA,NJ,NY,ME,NH,VAtrans-1,2-Dichloroethylene AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloropropane AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloropropane AIHA,FL,NJ,NY,ME,NH,VAcis-1,3-Dichloropropene AIHA,FL,NJ,NY,ME,NH,VAcis-1,3-Dichloropropene AIHA,NY,ME,NHtrans-1,3-Dichloropropene AIHA,NY,ME,NHtrans-1,3-Dichloropropene AIHA,NJ,NY,ME,NH,VA1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) AIHA,NJ,NY,ME,NH,VA1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) AIHA,NJ,NY,ME,NH,VA1,4-Dioxane AIHA,NJ,NY,ME,NH,VA1,4-Dioxane AIHAEthanol AIHAEthanol AIHAEthyl Acetate AIHAEthyl Acetate AIHA,FL,NJ,NY,ME,NH,VAEthylbenzene AIHA,FL,NJ,NY,ME,NH,VAEthylbenzene AIHA,NJ4-Ethyltoluene AIHA,NJ4-Ethyltoluene AIHA,NJ,NY,ME,NH,VAHeptane AIHA,NJ,NY,ME,NH,VAHeptane AIHA,NJ,NY,ME,NH,VAHexachlorobutadiene AIHA,NJ,NY,ME,NH,VAHexachlorobutadiene AIHA,FL,NJ,NY,ME,NH,VAHexane AIHA,FL,NJ,NY,ME,NH,VAHexane AIHA2-Hexanone (MBK) AIHA2-Hexanone (MBK) AIHA,NY,ME,NHIsopropanol AIHA,NY,ME,NHIsopropanol AIHA,FL,NJ,NY,ME,NH,VAMethyl tert-Butyl Ether (MTBE) AIHA,FL,NJ,NY,ME,NH,VAMethyl tert-Butyl Ether (MTBE) AIHA,FL,NJ,NY,ME,NH,VAMethylene Chloride AIHA,FL,NJ,NY,ME,NH,VAMethylene Chloride AIHA,FL,NJ,NY,ME,NH4-Methyl-2-pentanone (MIBK) AIHA,FL,NJ,NY,ME,NH4-Methyl-2-pentanone (MIBK) NY,ME,NHNaphthalene NY,ME,NHNaphthalene AIHAPropene AIHAPropene AIHA,FL,NJ,NY,ME,NH,VAStyrene AIHA,FL,NJ,NY,ME,NH,VAStyrene AIHA,FL,NJ,NY,ME,NH,VA1,1,2,2-Tetrachloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1,2,2-Tetrachloroethane Page 19 of 24 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,FL,NJ,NY,ME,NH,VATetrachloroethylene AIHA,FL,NJ,NY,ME,NH,VATetrachloroethylene AIHATetrahydrofuran AIHATetrahydrofuran AIHA,FL,NJ,NY,ME,NH,VAToluene AIHA,FL,NJ,NY,ME,NH,VAToluene AIHA,NJ,NY,ME,NH,VA1,2,4-Trichlorobenzene AIHA,NJ,NY,ME,NH,VA1,2,4-Trichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,1,1-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1,1-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1,2-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1,2-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VATrichloroethylene AIHA,FL,NJ,NY,ME,NH,VATrichloroethylene AIHA,NY,ME,NHTrichlorofluoromethane (Freon 11) AIHA,NY,ME,NHTrichlorofluoromethane (Freon 11) AIHA,NJ,NY,ME,NH,VA1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) AIHA,NJ,NY,ME,NH,VA1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) AIHA,NJ,NY,ME,NH1,2,4-Trimethylbenzene AIHA,NJ,NY,ME,NH1,2,4-Trimethylbenzene AIHA,NJ,NY,ME,NH1,3,5-Trimethylbenzene AIHA,NJ,NY,ME,NH1,3,5-Trimethylbenzene AIHA,FL,NJ,NY,ME,NH,VAVinyl Acetate AIHA,FL,NJ,NY,ME,NH,VAVinyl Acetate AIHA,FL,NJ,NY,ME,NH,VAVinyl Chloride AIHA,FL,NJ,NY,ME,NH,VAVinyl Chloride AIHA,FL,NJ,NY,ME,NH,VAm&p-Xylene AIHA,FL,NJ,NY,ME,NH,VAm&p-Xylene AIHA,FL,NJ,NY,ME,NH,VAo-Xylene AIHA,FL,NJ,NY,ME,NH,VAo-Xylene Page 20 of 24 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 The CON-TEST Environmental Laboratory operates under the following certifications and accreditations: Code Description Number Expires 100033AIHA-LAP, LLC - ISO17025:2017AIHA 03/1/2020 M-MA100Massachusetts DEPMA 06/30/2020 PH-0567Connecticut Department of Publilc HealthCT 09/30/2021 10899 NELAPNew York State Department of HealthNY 04/1/2020 2516 NELAPNew Hampshire Environmental LabNH-S 02/5/2020 LAO00112Rhode Island Department of HealthRI 12/30/2019 652North Carolina Div. of Water QualityNC 12/31/2019 MA007 NELAPNew Jersey DEPNJ 06/30/2020 E871027 NELAPFlorida Department of HealthFL 06/30/2020 LL015036Vermont Department of Health Lead LaboratoryVT 07/30/2020 2011028State of MaineME 06/9/2021 460217Commonwealth of VirginiaVA 12/14/2019 2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2020 VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2020 25703North Carolina Department of HealthNC-DW 07/31/2020 68-05812Commonwealth of Pennsylvania DEPPA 06/30/2020 Page 21 of 24 Page 22 of 24 Page 23 of 24 Page 24 of 24 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 April 15, 2020 Andrew Besu Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 Project Location: Belmont, NC Client Job Number: Project Number: BKL-001 Laboratory Work Order Number: 19K0266 Enclosed are results of analyses for samples received by the laboratory on November 4, 2019. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kerry K. McGee Project Manager QA Officer Katherine Allen Laboratory Manager Daren Damboragian Page 1 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL SUMMARY 4/15/2020Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 ATTN: Andrew Besu BKL-001 19K0266 The results of analyses performed on the following samples submitted to the CON-TEST Analytical Laboratory are found in this report. PROJECT LOCATION: PURCHASE ORDER NUMBER: PROJECT NUMBER: REPORT DATE: WORK ORDER NUMBER: FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB Belmont, NC BKL-001 SS-Bld-7-MP3 19K0266-01 Sub Slab - EPA TO-15 SS-Bld-7-MP6 19K0266-02 Sub Slab - EPA TO-15 DUP-1 19K0266-03 Sub Slab - EPA TO-15 Page 2 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CASE NARRATIVE SUMMARY All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report. REVISED REPORT - 11/21/2019 - Full TO-15 list reported per client’s request. EPA TO-15 Qualifications: Laboratory fortified blank /laboratory control sample recovery outside of control limits. Data validation is not affected since all results are "not detected" for all samples in this batch for this compound and bias is on the high side. Analyte & Samples(s) Qualified: 1,2,4-Trichlorobenzene B245700-BS1 Initial calibration verification (ICV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was "not detected" for this compound. Analyte & Samples(s) Qualified: 1,2,4-Trichlorobenzene B245700-BS1, S042459-CCV1 Compound fails the method requirement of 70-130% recovery for the LCS. Is classified by the lab as a difficult compound and passes the in house limits of 50-150%. Analyte & Samples(s) Qualified: Ethanol 19K0266-01[SS-Bld-7-MP3], 19K0266-02[SS-Bld-7-MP6], 19K0266-03[DUP-1], B245700-BS1, B245700-DUP1 The results of analyses reported only relate to samples submitted to the Con-Test Analytical Laboratory for testing. I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Lisa A. Worthington Technical Representative Page 3 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 11/4/2019 Work Order: 19K0266Sample Description/Location: Field Sample #: SS-Bld-7-MP3 Sample ID: 19K0266-01 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -7 Sampled: 11/1/2019 15:47 Canister ID: 1851 Flow Controller ID: 4315 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 1 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 1.5 4.0 11/8/19 16:57 BRFJ3.6 29.51.4 3.3 Benzene 0.066 0.10 11/8/19 16:57 BRFJ0.21 20.320.041 0.13 Benzyl chloride ND 0.10 11/8/19 16:57 BRFND20.520.026 0.13 Bromodichloromethane ND 0.10 11/8/19 16:57 BRFND20.670.037 0.25 Bromoform ND 0.10 11/8/19 16:57 BRFND21.00.045 0.47 Bromomethane ND 0.10 11/8/19 16:57 BRFND20.390.069 0.27 1,3-Butadiene ND 0.10 11/8/19 16:57 BRFND20.220.073 0.16 2-Butanone (MEK)0.23 4.0 11/8/19 16:57 BRFJ0.67 2120.19 0.55 Carbon Disulfide ND 1.0 11/8/19 16:57 BRFND23.10.069 0.21 Carbon Tetrachloride 0.056 0.10 11/8/19 16:57 BRFJ0.35 20.630.033 0.21 Chlorobenzene ND 0.10 11/8/19 16:57 BRFND20.460.049 0.23 Chloroethane ND 0.10 11/8/19 16:57 BRFND20.260.098 0.26 Chloroform ND 0.10 11/8/19 16:57 BRFND20.490.037 0.18 Chloromethane ND 0.20 11/8/19 16:57 BRFND20.410.068 0.14 Cyclohexane ND 0.10 11/8/19 16:57 BRFND20.340.071 0.24 Dibromochloromethane ND 0.10 11/8/19 16:57 BRFND20.850.033 0.28 1,2-Dibromoethane (EDB)ND 0.10 11/8/19 16:57 BRFND20.770.039 0.30 1,2-Dichlorobenzene ND 0.10 11/8/19 16:57 BRFND20.600.048 0.29 1,3-Dichlorobenzene ND 0.10 11/8/19 16:57 BRFND20.600.052 0.31 1,4-Dichlorobenzene ND 0.10 11/8/19 16:57 BRFND20.600.061 0.37 Dichlorodifluoromethane (Freon 12)0.46 0.10 11/8/19 16:57 BRF2.3 20.490.043 0.21 1,1-Dichloroethane ND 0.10 11/8/19 16:57 BRFND20.400.030 0.12 1,2-Dichloroethane ND 0.10 11/8/19 16:57 BRFND20.400.038 0.15 1,1-Dichloroethylene ND 0.10 11/8/19 16:57 BRFND20.400.054 0.22 cis-1,2-Dichloroethylene ND 0.10 11/8/19 16:57 BRFND20.400.041 0.16 trans-1,2-Dichloroethylene ND 0.10 11/8/19 16:57 BRFND20.400.041 0.16 1,2-Dichloropropane ND 0.10 11/8/19 16:57 BRFND20.460.035 0.16 cis-1,3-Dichloropropene ND 0.10 11/8/19 16:57 BRFND20.450.035 0.16 trans-1,3-Dichloropropene ND 0.10 11/8/19 16:57 BRFND20.450.036 0.17 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.10 11/8/19 16:57 BRFND20.700.056 0.39 1,4-Dioxane ND 1.0 11/8/19 16:57 BRFND23.60.64 2.3 Ethanol 3.6 4.0 11/8/19 16:57 BRFZ-01, J 6.8 27.51.8 3.4 Ethyl Acetate ND 0.10 11/8/19 16:57 BRFND20.360.075 0.27 Ethylbenzene 0.19 0.10 11/8/19 16:57 BRF0.81 20.430.058 0.25 4-Ethyltoluene ND 0.10 11/8/19 16:57 BRFND20.490.061 0.30 Heptane ND 0.10 11/8/19 16:57 BRFND20.410.059 0.24 Hexachlorobutadiene ND 0.10 11/8/19 16:57 BRFND21.10.046 0.49 Hexane ND 4.0 11/8/19 16:57 BRFND2140.18 0.62 2-Hexanone (MBK)ND 0.10 11/8/19 16:57 BRFND20.410.059 0.24 Isopropanol ND 4.0 11/8/19 16:57 BRFND29.80.18 0.45 Methyl tert-Butyl Ether (MTBE)ND 0.10 11/8/19 16:57 BRFND20.360.050 0.18 Methylene Chloride ND 1.0 11/8/19 16:57 BRFND23.50.12 0.42 4-Methyl-2-pentanone (MIBK)ND 0.10 11/8/19 16:57 BRFND20.410.052 0.21 Naphthalene ND 0.10 11/8/19 16:57 BRFND20.520.077 0.40 Propene ND 4.0 11/8/19 16:57 BRFND26.90.19 0.32 Styrene ND 0.10 11/8/19 16:57 BRFND20.430.062 0.26 1,1,2,2-Tetrachloroethane ND 0.10 11/8/19 16:57 BRFND20.690.044 0.30 Page 4 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 11/4/2019 Work Order: 19K0266Sample Description/Location: Field Sample #: SS-Bld-7-MP3 Sample ID: 19K0266-01 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -7 Sampled: 11/1/2019 15:47 Canister ID: 1851 Flow Controller ID: 4315 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 1 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 0.34 0.10 11/8/19 16:57 BRF2.3 20.680.056 0.38 Tetrahydrofuran 0.26 0.10 11/8/19 16:57 BRF0.75 20.290.099 0.29 Toluene 0.24 0.10 11/8/19 16:57 BRF0.91 20.380.052 0.19 1,2,4-Trichlorobenzene ND 0.10 11/8/19 16:57 BRFND20.740.069 0.51 1,1,1-Trichloroethane ND 0.10 11/8/19 16:57 BRFND20.550.037 0.20 1,1,2-Trichloroethane ND 0.10 11/8/19 16:57 BRFND20.550.041 0.22 Trichloroethylene ND 0.10 11/8/19 16:57 BRFND20.540.040 0.22 Trichlorofluoromethane (Freon 11)2.7 0.40 11/8/19 16:57 BRF15 22.20.076 0.43 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.40 11/8/19 16:57 BRFND23.10.075 0.58 1,2,4-Trimethylbenzene 0.078 0.10 11/8/19 16:57 BRFJ0.38 20.490.064 0.31 1,3,5-Trimethylbenzene ND 0.10 11/8/19 16:57 BRFND20.490.063 0.31 Vinyl Acetate ND 2.0 11/8/19 16:57 BRFND27.00.062 0.22 Vinyl Chloride ND 0.10 11/8/19 16:57 BRFND20.260.063 0.16 m&p-Xylene 0.77 0.20 11/8/19 16:57 BRF3.4 20.870.12 0.50 o-Xylene 0.20 0.10 11/8/19 16:57 BRF0.85 20.430.062 0.27 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)102 11/8/19 16:5770-130 Page 5 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 11/4/2019 Work Order: 19K0266Sample Description/Location: Field Sample #: SS-Bld-7-MP6 Sample ID: 19K0266-02 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -5.8 Sampled: 11/1/2019 15:55 Canister ID: 1872 Flow Controller ID: 4344 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 1 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 7.6 4.0 11/8/19 17:28 BRF18 29.51.4 3.3 Benzene 0.054 0.10 11/8/19 17:28 BRFJ0.17 20.320.041 0.13 Benzyl chloride ND 0.10 11/8/19 17:28 BRFND20.520.026 0.13 Bromodichloromethane ND 0.10 11/8/19 17:28 BRFND20.670.037 0.25 Bromoform ND 0.10 11/8/19 17:28 BRFND21.00.045 0.47 Bromomethane ND 0.10 11/8/19 17:28 BRFND20.390.069 0.27 1,3-Butadiene ND 0.10 11/8/19 17:28 BRFND20.220.073 0.16 2-Butanone (MEK)4.5 4.0 11/8/19 17:28 BRF13 2120.19 0.55 Carbon Disulfide ND 1.0 11/8/19 17:28 BRFND23.10.069 0.21 Carbon Tetrachloride 0.060 0.10 11/8/19 17:28 BRFJ0.38 20.630.033 0.21 Chlorobenzene ND 0.10 11/8/19 17:28 BRFND20.460.049 0.23 Chloroethane ND 0.10 11/8/19 17:28 BRFND20.260.098 0.26 Chloroform ND 0.10 11/8/19 17:28 BRFND20.490.037 0.18 Chloromethane ND 0.20 11/8/19 17:28 BRFND20.410.068 0.14 Cyclohexane ND 0.10 11/8/19 17:28 BRFND20.340.071 0.24 Dibromochloromethane ND 0.10 11/8/19 17:28 BRFND20.850.033 0.28 1,2-Dibromoethane (EDB)ND 0.10 11/8/19 17:28 BRFND20.770.039 0.30 1,2-Dichlorobenzene ND 0.10 11/8/19 17:28 BRFND20.600.048 0.29 1,3-Dichlorobenzene ND 0.10 11/8/19 17:28 BRFND20.600.052 0.31 1,4-Dichlorobenzene ND 0.10 11/8/19 17:28 BRFND20.600.061 0.37 Dichlorodifluoromethane (Freon 12)ND 0.10 11/8/19 17:28 BRFND20.490.043 0.21 1,1-Dichloroethane ND 0.10 11/8/19 17:28 BRFND20.400.030 0.12 1,2-Dichloroethane ND 0.10 11/8/19 17:28 BRFND20.400.038 0.15 1,1-Dichloroethylene ND 0.10 11/8/19 17:28 BRFND20.400.054 0.22 cis-1,2-Dichloroethylene ND 0.10 11/8/19 17:28 BRFND20.400.041 0.16 trans-1,2-Dichloroethylene ND 0.10 11/8/19 17:28 BRFND20.400.041 0.16 1,2-Dichloropropane ND 0.10 11/8/19 17:28 BRFND20.460.035 0.16 cis-1,3-Dichloropropene ND 0.10 11/8/19 17:28 BRFND20.450.035 0.16 trans-1,3-Dichloropropene ND 0.10 11/8/19 17:28 BRFND20.450.036 0.17 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.10 11/8/19 17:28 BRFND20.700.056 0.39 1,4-Dioxane ND 1.0 11/8/19 17:28 BRFND23.60.64 2.3 Ethanol 4.7 4.0 11/8/19 17:28 BRFZ-01 8.8 27.51.8 3.4 Ethyl Acetate ND 0.10 11/8/19 17:28 BRFND20.360.075 0.27 Ethylbenzene ND 0.10 11/8/19 17:28 BRFND20.430.058 0.25 4-Ethyltoluene ND 0.10 11/8/19 17:28 BRFND20.490.061 0.30 Heptane ND 0.10 11/8/19 17:28 BRFND20.410.059 0.24 Hexachlorobutadiene ND 0.10 11/8/19 17:28 BRFND21.10.046 0.49 Hexane ND 4.0 11/8/19 17:28 BRFND2140.18 0.62 2-Hexanone (MBK)ND 0.10 11/8/19 17:28 BRFND20.410.059 0.24 Isopropanol ND 4.0 11/8/19 17:28 BRFND29.80.18 0.45 Methyl tert-Butyl Ether (MTBE)ND 0.10 11/8/19 17:28 BRFND20.360.050 0.18 Methylene Chloride ND 1.0 11/8/19 17:28 BRFND23.50.12 0.42 4-Methyl-2-pentanone (MIBK)ND 0.10 11/8/19 17:28 BRFND20.410.052 0.21 Naphthalene 0.52 0.10 11/8/19 17:28 BRF2.7 20.520.077 0.40 Propene ND 4.0 11/8/19 17:28 BRFND26.90.19 0.32 Styrene ND 0.10 11/8/19 17:28 BRFND20.430.062 0.26 1,1,2,2-Tetrachloroethane ND 0.10 11/8/19 17:28 BRFND20.690.044 0.30 Page 6 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 11/4/2019 Work Order: 19K0266Sample Description/Location: Field Sample #: SS-Bld-7-MP6 Sample ID: 19K0266-02 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -5.8 Sampled: 11/1/2019 15:55 Canister ID: 1872 Flow Controller ID: 4344 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 1 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 0.086 0.10 11/8/19 17:28 BRFJ0.58 20.680.056 0.38 Tetrahydrofuran 3.9 0.10 11/8/19 17:28 BRF12 20.290.099 0.29 Toluene 0.60 0.10 11/8/19 17:28 BRF2.3 20.380.052 0.19 1,2,4-Trichlorobenzene ND 0.10 11/8/19 17:28 BRFND20.740.069 0.51 1,1,1-Trichloroethane ND 0.10 11/8/19 17:28 BRFND20.550.037 0.20 1,1,2-Trichloroethane ND 0.10 11/8/19 17:28 BRFND20.550.041 0.22 Trichloroethylene ND 0.10 11/8/19 17:28 BRFND20.540.040 0.22 Trichlorofluoromethane (Freon 11)0.26 0.40 11/8/19 17:28 BRFJ1.5 22.20.076 0.43 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.40 11/8/19 17:28 BRFND23.10.075 0.58 1,2,4-Trimethylbenzene 0.40 0.10 11/8/19 17:28 BRF2.0 20.490.064 0.31 1,3,5-Trimethylbenzene ND 0.10 11/8/19 17:28 BRFND20.490.063 0.31 Vinyl Acetate ND 2.0 11/8/19 17:28 BRFND27.00.062 0.22 Vinyl Chloride ND 0.10 11/8/19 17:28 BRFND20.260.063 0.16 m&p-Xylene 0.15 0.20 11/8/19 17:28 BRFJ0.65 20.870.12 0.50 o-Xylene ND 0.10 11/8/19 17:28 BRFND20.430.062 0.27 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)105 11/8/19 17:2870-130 Page 7 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 11/4/2019 Work Order: 19K0266Sample Description/Location: Field Sample #: DUP-1 Sample ID: 19K0266-03 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -7 Sampled: 11/1/2019 00:00 Canister ID: 1493 Flow Controller ID: 4315 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 1 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 2.6 4.0 11/8/19 17:58 BRFJ6.1 29.51.4 3.3 Benzene 0.078 0.10 11/8/19 17:58 BRFJ0.25 20.320.041 0.13 Benzyl chloride ND 0.10 11/8/19 17:58 BRFND20.520.026 0.13 Bromodichloromethane ND 0.10 11/8/19 17:58 BRFND20.670.037 0.25 Bromoform ND 0.10 11/8/19 17:58 BRFND21.00.045 0.47 Bromomethane ND 0.10 11/8/19 17:58 BRFND20.390.069 0.27 1,3-Butadiene ND 0.10 11/8/19 17:58 BRFND20.220.073 0.16 2-Butanone (MEK)0.25 4.0 11/8/19 17:58 BRFJ0.74 2120.19 0.55 Carbon Disulfide ND 1.0 11/8/19 17:58 BRFND23.10.069 0.21 Carbon Tetrachloride 0.058 0.10 11/8/19 17:58 BRFJ0.36 20.630.033 0.21 Chlorobenzene ND 0.10 11/8/19 17:58 BRFND20.460.049 0.23 Chloroethane ND 0.10 11/8/19 17:58 BRFND20.260.098 0.26 Chloroform 0.066 0.10 11/8/19 17:58 BRFJ0.32 20.490.037 0.18 Chloromethane ND 0.20 11/8/19 17:58 BRFND20.410.068 0.14 Cyclohexane ND 0.10 11/8/19 17:58 BRFND20.340.071 0.24 Dibromochloromethane ND 0.10 11/8/19 17:58 BRFND20.850.033 0.28 1,2-Dibromoethane (EDB)ND 0.10 11/8/19 17:58 BRFND20.770.039 0.30 1,2-Dichlorobenzene ND 0.10 11/8/19 17:58 BRFND20.600.048 0.29 1,3-Dichlorobenzene ND 0.10 11/8/19 17:58 BRFND20.600.052 0.31 1,4-Dichlorobenzene ND 0.10 11/8/19 17:58 BRFND20.600.061 0.37 Dichlorodifluoromethane (Freon 12)ND 0.10 11/8/19 17:58 BRFND20.490.043 0.21 1,1-Dichloroethane ND 0.10 11/8/19 17:58 BRFND20.400.030 0.12 1,2-Dichloroethane ND 0.10 11/8/19 17:58 BRFND20.400.038 0.15 1,1-Dichloroethylene ND 0.10 11/8/19 17:58 BRFND20.400.054 0.22 cis-1,2-Dichloroethylene ND 0.10 11/8/19 17:58 BRFND20.400.041 0.16 trans-1,2-Dichloroethylene ND 0.10 11/8/19 17:58 BRFND20.400.041 0.16 1,2-Dichloropropane ND 0.10 11/8/19 17:58 BRFND20.460.035 0.16 cis-1,3-Dichloropropene ND 0.10 11/8/19 17:58 BRFND20.450.035 0.16 trans-1,3-Dichloropropene ND 0.10 11/8/19 17:58 BRFND20.450.036 0.17 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.10 11/8/19 17:58 BRFND20.700.056 0.39 1,4-Dioxane ND 1.0 11/8/19 17:58 BRFND23.60.64 2.3 Ethanol 5.3 4.0 11/8/19 17:58 BRFZ-01 10.0 27.51.8 3.4 Ethyl Acetate 1.8 0.10 11/8/19 17:58 BRF6.5 20.360.075 0.27 Ethylbenzene 0.20 0.10 11/8/19 17:58 BRF0.89 20.430.058 0.25 4-Ethyltoluene ND 0.10 11/8/19 17:58 BRFND20.490.061 0.30 Heptane ND 0.10 11/8/19 17:58 BRFND20.410.059 0.24 Hexachlorobutadiene ND 0.10 11/8/19 17:58 BRFND21.10.046 0.49 Hexane ND 4.0 11/8/19 17:58 BRFND2140.18 0.62 2-Hexanone (MBK)ND 0.10 11/8/19 17:58 BRFND20.410.059 0.24 Isopropanol ND 4.0 11/8/19 17:58 BRFND29.80.18 0.45 Methyl tert-Butyl Ether (MTBE)ND 0.10 11/8/19 17:58 BRFND20.360.050 0.18 Methylene Chloride ND 1.0 11/8/19 17:58 BRFND23.50.12 0.42 4-Methyl-2-pentanone (MIBK)ND 0.10 11/8/19 17:58 BRFND20.410.052 0.21 Naphthalene ND 0.10 11/8/19 17:58 BRFND20.520.077 0.40 Propene ND 4.0 11/8/19 17:58 BRFND26.90.19 0.32 Styrene ND 0.10 11/8/19 17:58 BRFND20.430.062 0.26 1,1,2,2-Tetrachloroethane ND 0.10 11/8/19 17:58 BRFND20.690.044 0.30 Page 8 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Belmont, NC Date Received: 11/4/2019 Work Order: 19K0266Sample Description/Location: Field Sample #: DUP-1 Sample ID: 19K0266-03 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -7 Sampled: 11/1/2019 00:00 Canister ID: 1493 Flow Controller ID: 4315 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 1 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 0.35 0.10 11/8/19 17:58 BRF2.4 20.680.056 0.38 Tetrahydrofuran 0.25 0.10 11/8/19 17:58 BRF0.74 20.290.099 0.29 Toluene 0.61 0.10 11/8/19 17:58 BRF2.3 20.380.052 0.19 1,2,4-Trichlorobenzene ND 0.10 11/8/19 17:58 BRFND20.740.069 0.51 1,1,1-Trichloroethane ND 0.10 11/8/19 17:58 BRFND20.550.037 0.20 1,1,2-Trichloroethane ND 0.10 11/8/19 17:58 BRFND20.550.041 0.22 Trichloroethylene ND 0.10 11/8/19 17:58 BRFND20.540.040 0.22 Trichlorofluoromethane (Freon 11)2.6 0.40 11/8/19 17:58 BRF15 22.20.076 0.43 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.40 11/8/19 17:58 BRFND23.10.075 0.58 1,2,4-Trimethylbenzene ND 0.10 11/8/19 17:58 BRFND20.490.064 0.31 1,3,5-Trimethylbenzene ND 0.10 11/8/19 17:58 BRFND20.490.063 0.31 Vinyl Acetate ND 2.0 11/8/19 17:58 BRFND27.00.062 0.22 Vinyl Chloride ND 0.10 11/8/19 17:58 BRFND20.260.063 0.16 m&p-Xylene 0.83 0.20 11/8/19 17:58 BRF3.6 20.870.12 0.50 o-Xylene 0.21 0.10 11/8/19 17:58 BRF0.92 20.430.062 0.27 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)104 11/8/19 17:5870-130 Page 9 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Sample Extraction Data Prep Method: TO-15 Prep-EPA TO-15 Lab Number [Field ID]Batch Date Pressure Dilution Pre Dilution Pre-Dil Initial mL Pre-Dil Final mL Default Injection mL Actual Injection mL 19K0266-01 [SS-Bld-7-MP3]B245700 1.5 1 N/A 1000 400 300 11/08/19 19K0266-02 [SS-Bld-7-MP6]B245700 1.5 1 N/A 1000 400 300 11/08/19 19K0266-03 [DUP-1]B245700 1.5 1 N/A 1000 400 300 11/08/19 Page 10 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B245700 - TO-15 Prep Blank (B245700-BLK1)Prepared & Analyzed: 11/08/19 1.4NDAcetone 0.035NDBenzene 0.035NDBenzyl chloride 0.035NDBromodichloromethane 0.035NDBromoform 0.035NDBromomethane 0.035ND1,3-Butadiene 1.4ND2-Butanone (MEK) 0.35NDCarbon Disulfide 0.035NDCarbon Tetrachloride 0.035NDChlorobenzene 0.035NDChloroethane 0.035NDChloroform 0.070NDChloromethane 0.035NDCyclohexane 0.035NDDibromochloromethane 0.035ND1,2-Dibromoethane (EDB) 0.035ND1,2-Dichlorobenzene 0.035ND1,3-Dichlorobenzene 0.035ND1,4-Dichlorobenzene 0.035NDDichlorodifluoromethane (Freon 12) 0.035ND1,1-Dichloroethane 0.035ND1,2-Dichloroethane 0.035ND1,1-Dichloroethylene 0.035NDcis-1,2-Dichloroethylene 0.035NDtrans-1,2-Dichloroethylene 0.035ND1,2-Dichloropropane 0.035NDcis-1,3-Dichloropropene 0.035NDtrans-1,3-Dichloropropene 0.035ND1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.35ND1,4-Dioxane 1.4NDEthanol 0.035NDEthyl Acetate 0.035NDEthylbenzene 0.035ND4-Ethyltoluene 0.035NDHeptane 0.035NDHexachlorobutadiene 1.4NDHexane 0.035ND2-Hexanone (MBK) 1.4NDIsopropanol 0.035NDMethyl tert-Butyl Ether (MTBE) 0.35NDMethylene Chloride 0.035ND4-Methyl-2-pentanone (MIBK) 0.035NDNaphthalene 1.4NDPropene 0.035NDStyrene Page 11 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B245700 - TO-15 Prep Blank (B245700-BLK1)Prepared & Analyzed: 11/08/19 0.035ND1,1,2,2-Tetrachloroethane 0.035NDTetrachloroethylene 0.035NDTetrahydrofuran 0.035NDToluene 0.035ND1,2,4-Trichlorobenzene 0.035ND1,1,1-Trichloroethane 0.035ND1,1,2-Trichloroethane 0.035NDTrichloroethylene 0.14NDTrichlorofluoromethane (Freon 11) 0.14ND1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 0.035ND1,2,4-Trimethylbenzene 0.035ND1,3,5-Trimethylbenzene 0.70NDVinyl Acetate 0.035NDVinyl Chloride 0.070NDm&p-Xylene 0.035NDo-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1018.09 LCS (B245700-BS1)Prepared & Analyzed: 11/08/19 5.00 70-1301105.52Acetone 5.00 70-13097.84.89Benzene 5.00 70-1301165.78Benzyl chloride 5.00 70-13098.74.93Bromodichloromethane 5.00 70-1301205.99Bromoform 5.00 70-1301015.06Bromomethane 5.00 70-13099.24.961,3-Butadiene 5.00 70-1301045.222-Butanone (MEK) 5.00 70-1301145.69Carbon Disulfide 5.00 70-13098.14.91Carbon Tetrachloride 5.00 70-13099.74.99Chlorobenzene 5.00 70-1301085.42Chloroethane 5.00 70-1301105.52Chloroform 5.00 70-1301025.11Chloromethane 5.00 70-1301015.05Cyclohexane 5.00 70-1301075.34Dibromochloromethane 5.00 70-1301145.701,2-Dibromoethane (EDB) 5.00 70-1301236.141,2-Dichlorobenzene 5.00 70-1301205.981,3-Dichlorobenzene 5.00 70-1301206.021,4-Dichlorobenzene 5.00 70-1301025.10Dichlorodifluoromethane (Freon 12) 5.00 70-1301085.391,1-Dichloroethane 5.00 70-1301055.251,2-Dichloroethane 5.00 70-1301125.601,1-Dichloroethylene 5.00 70-1301065.30cis-1,2-Dichloroethylene 5.00 70-1301075.36trans-1,2-Dichloroethylene 5.00 70-13096.74.841,2-Dichloropropane Page 12 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B245700 - TO-15 Prep LCS (B245700-BS1)Prepared & Analyzed: 11/08/19 5.00 70-13097.44.87cis-1,3-Dichloropropene 5.00 70-1301075.33trans-1,3-Dichloropropene 5.00 70-1301005.001,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 5.00 70-1301246.211,4-Dioxane 5.00 Z-0170-1301396.95Ethanol * 5.00 70-13096.04.80Ethyl Acetate 5.00 70-1301065.28Ethylbenzene 5.00 70-1301145.694-Ethyltoluene 5.00 70-13094.04.70Heptane 5.00 70-1301286.40Hexachlorobutadiene 5.00 70-1301155.76Hexane 5.00 70-13092.44.622-Hexanone (MBK) 5.00 70-13091.34.56Isopropanol 5.00 70-1301075.33Methyl tert-Butyl Ether (MTBE) 5.00 70-13092.94.64Methylene Chloride 5.00 70-13093.54.684-Methyl-2-pentanone (MIBK) 5.00 70-1301115.56Naphthalene 5.00 70-13091.24.56Propene 5.00 70-1301155.73Styrene 5.00 70-1301105.481,1,2,2-Tetrachloroethane 5.00 70-1301185.92Tetrachloroethylene 5.00 70-1301065.29Tetrahydrofuran 5.00 70-1301125.58Toluene 5.00 L-01, V-3670-1301386.901,2,4-Trichlorobenzene * 5.00 70-13093.04.651,1,1-Trichloroethane 5.00 70-1301165.821,1,2-Trichloroethane 5.00 70-1301025.12Trichloroethylene 5.00 70-1301135.65Trichlorofluoromethane (Freon 11) 5.00 70-1301165.801,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 5.00 70-1301085.401,2,4-Trimethylbenzene 5.00 70-1301095.431,3,5-Trimethylbenzene 5.00 70-1301035.13Vinyl Acetate 5.00 70-1301025.10Vinyl Chloride 10.0 70-13010910.9m&p-Xylene 5.00 70-1301085.41o-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1088.63 Page 13 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B245700 - TO-15 Prep Duplicate (B245700-DUP1)Prepared & Analyzed: 11/08/19 Source: 19K0266-03 4.0 2.6 25 J0.7752.6Acetone 9.56.2 0.10 0.078 25 J5.000.082Benzene 0.320.26 0.10 ND 25NDBenzyl chloride 0.52ND 0.10 ND 25NDBromodichloromethane0.67ND 0.10 ND 25NDBromoform1.0ND 0.10 ND 25NDBromomethane0.39ND 0.10 ND 25ND1,3-Butadiene 0.22ND 4.0 0.25 25 J10.60.282-Butanone (MEK)120.82 1.0 ND 25NDCarbon Disulfide 3.1ND 0.10 0.058 25 J6.670.062Carbon Tetrachloride 0.630.39 0.10 ND 25NDChlorobenzene0.46ND 0.10 ND 25NDChloroethane0.26ND 0.10 0.066 25 J0.000.066Chloroform 0.490.32 0.20 ND 25NDChloromethane0.41ND 0.10 ND 25NDCyclohexane0.34ND 0.10 ND 25NDDibromochloromethane0.85ND 0.10 ND 25ND1,2-Dibromoethane (EDB)0.77ND 0.10 ND 25ND1,2-Dichlorobenzene 0.60ND 0.10 ND 25ND1,3-Dichlorobenzene 0.60ND 0.10 ND 25ND1,4-Dichlorobenzene 0.60ND 0.10 ND 25NDDichlorodifluoromethane (Freon 12)0.49ND 0.10 ND 25ND1,1-Dichloroethane 0.40ND 0.10 ND 25ND1,2-Dichloroethane 0.40ND 0.10 ND 25ND1,1-Dichloroethylene 0.40ND 0.10 ND 25NDcis-1,2-Dichloroethylene 0.40ND 0.10 ND 25NDtrans-1,2-Dichloroethylene 0.40ND 0.10 ND 25ND1,2-Dichloropropane 0.46ND 0.10 ND 25NDcis-1,3-Dichloropropene 0.45ND 0.10 ND 25NDtrans-1,3-Dichloropropene 0.45ND 0.10 ND 25ND1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.70ND 1.0 ND 25ND1,4-Dioxane 3.6ND 4.0 5.3 25 Z-0123.96.7Ethanol 7.513 0.10 1.8 256.581.7Ethyl Acetate 0.366.0 0.10 0.20 251.940.21Ethylbenzene 0.430.90 0.10 ND 25ND4-Ethyltoluene 0.49ND 0.10 ND 25NDHeptane0.41ND 0.10 ND 25NDHexachlorobutadiene1.1ND 4.0 ND 25NDHexane14ND 0.10 ND 25ND2-Hexanone (MBK)0.41ND 4.0 ND 25NDIsopropanol9.8ND 0.10 ND 25NDMethyl tert-Butyl Ether (MTBE)0.36ND 1.0 ND 25NDMethylene Chloride 3.5ND 0.10 ND 25ND4-Methyl-2-pentanone (MIBK)0.41ND 0.10 ND 25NDNaphthalene0.52ND 4.0 ND 25NDPropene6.9ND 0.10 ND 25NDStyrene0.43ND Page 14 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B245700 - TO-15 Prep Duplicate (B245700-DUP1)Prepared & Analyzed: 11/08/19 Source: 19K0266-03 0.10 ND 25ND1,1,2,2-Tetrachloroethane 0.69ND 0.10 0.35 250.5700.35Tetrachloroethylene 0.682.4 0.10 0.25 250.7910.25Tetrahydrofuran 0.290.75 0.10 0.61 250.000.61Toluene 0.382.3 0.10 ND 25ND1,2,4-Trichlorobenzene 0.74ND 0.10 ND 25ND1,1,1-Trichloroethane 0.55ND 0.10 ND 25ND1,1,2-Trichloroethane 0.55ND 0.10 ND 25NDTrichloroethylene0.54ND 0.40 2.6 250.9872.6Trichlorofluoromethane (Freon 11)2.215 0.40 ND 25ND1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 3.1ND 0.10 ND 25ND1,2,4-Trimethylbenzene 0.49ND 0.10 ND 25ND1,3,5-Trimethylbenzene 0.49ND 2.0 ND 25NDVinyl Acetate 7.0ND 0.10 ND 25NDVinyl Chloride 0.26ND 0.20 0.83 250.4840.82m&p-Xylene 0.873.6 0.10 0.21 252.790.22o-Xylene 0.430.95 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1048.33 Page 15 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Note: Blank Subtraction is not performed unless otherwise noted *QC result is outside of established limits. Wide recovery limits established for difficult compound. Wide RPD limits established for difficult compound. #Data exceeded client recommended or regulatory level RL Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference LCS Laboratory Control Sample Laboratory Control SampleLCS Dup Duplicate Laboratory Control Sample MS Matrix Spike Sample MS Dup Duplicate Matrix Spike Sample REC Recovery QC Quality Control ppbv Parts per billion volume EPA United States Environmental Protection Agency Percent Recovery% REC ND Not Detected Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the calculation which have not been rounded. Not ApplicableN/A DL Detection Limit Not CalculatedNC LFB/LCS Lab Fortified Blank/Lab Control Sample ORP Oxidation-Reduction Potential Not dry weight correctedwet Percent weight% wt KilogramKg Gramg Milligrammg Microgramg Nanogramng LiterL MillilitermL Microliter L Cubic Meterm3 Extractable Petroleum HydrocarbonsEPH Volatile Petroleum HydrocarbonsVPH Air Petroleum HydrocarbonsAPH Flame Ionization DetectorFID Photo Ionization DetectorPID FLAG/QUALIFIER SUMMARY Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag). J Laboratory fortified blank /laboratory control sample recovery outside of control limits. Data validation is not affected since all results are "not detected" for all samples in this batch for this compound and bias is on the high side. L-01 Initial calibration verification (ICV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was "not detected" for this compound. V-36 Compound fails the method requirement of 70-130% recovery for the LCS. Is classified by the lab as a difficult compound and passes the in house limits of 50-150%. Z-01 Page 16 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYST Rebecca FaustRLF Raisa A. PetraitisRAP Kerry K. McGeeKKM Brittany R. FiskBRF Page 17 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q Initial Cal Check (S042102-ICV1 )Lab File ID: B1930424.D Analyzed: 10/31/19 22:28 Bromochloromethane (1)198025 5.048 200087 5.048 60 - 14099 0.0000 +/-0.50 1,4-Difluorobenzene (1)416191 6.268 408439 6.267 60 - 140102 0.0010 +/-0.50 Chlorobenzene-d5 (1)373622 9.855 388843 9.855 60 - 14096 0.0000 +/-0.50 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q Calibration Check (S042459-CCV1 )Lab File ID: B1931204.D Analyzed: 11/08/19 11:56 Bromochloromethane (1)194960 5.048 200087 5.048 60 - 14097 0.0000 +/-0.50 1,4-Difluorobenzene (1)446343 6.262 408439 6.267 60 - 140109 -0.0050 +/-0.50 Chlorobenzene-d5 (1)390742 9.855 388843 9.855 60 - 140100 0.0000 +/-0.50 LCS (B245700-BS1 )Lab File ID: B1931205.D Analyzed: 11/08/19 12:24 Bromochloromethane (1)205192 5.061 194960 5.048 60 - 140105 0.0130 +/-0.50 1,4-Difluorobenzene (1)460533 6.275 446343 6.262 60 - 140103 0.0130 +/-0.50 Chlorobenzene-d5 (1)405105 9.862 390742 9.855 60 - 140104 0.0070 +/-0.50 Blank (B245700-BLK1 )Lab File ID: B1931209.D Analyzed: 11/08/19 15:05 Bromochloromethane (1)205665 5.057 194960 5.048 60 - 140105 0.0090 +/-0.50 1,4-Difluorobenzene (1)428776 6.271 446343 6.262 60 - 14096 0.0090 +/-0.50 Chlorobenzene-d5 (1)381364 9.858 390742 9.855 60 - 14098 0.0030 +/-0.50 SS-Bld-7-MP3 (19K0266-01 )Lab File ID: B1931213.D Analyzed: 11/08/19 16:57 Bromochloromethane (1)185075 5.048 194960 5.048 60 - 14095 0.0000 +/-0.50 1,4-Difluorobenzene (1)383341 6.268 446343 6.262 60 - 14086 0.0060 +/-0.50 Chlorobenzene-d5 (1)345005 9.861 390742 9.855 60 - 14088 0.0060 +/-0.50 SS-Bld-7-MP6 (19K0266-02 )Lab File ID: B1931214.D Analyzed: 11/08/19 17:28 Bromochloromethane (1)189141 5.055 194960 5.048 60 - 14097 0.0070 +/-0.50 1,4-Difluorobenzene (1)402880 6.269 446343 6.262 60 - 14090 0.0070 +/-0.50 Chlorobenzene-d5 (1)360277 9.856 390742 9.855 60 - 14092 0.0010 +/-0.50 DUP-1 (19K0266-03 )Lab File ID: B1931215.D Analyzed: 11/08/19 17:58 Bromochloromethane (1)188485 5.052 194960 5.048 60 - 14097 0.0040 +/-0.50 1,4-Difluorobenzene (1)397407 6.266 446343 6.262 60 - 14089 0.0040 +/-0.50 Chlorobenzene-d5 (1)352419 9.859 390742 9.855 60 - 14090 0.0040 +/-0.50 Duplicate (B245700-DUP1 )Lab File ID: B1931216.D Analyzed: 11/08/19 18:28 Bromochloromethane (1)185799 5.052 194960 5.048 60 - 14095 0.0040 +/-0.50 1,4-Difluorobenzene (1)398567 6.265 446343 6.262 60 - 14089 0.0030 +/-0.50 Chlorobenzene-d5 (1)350890 9.859 390742 9.855 60 - 14090 0.0040 +/-0.50 Page 18 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S042459-CCV1 COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR STD 0.8308248A -5.9 304.70 0.88304065.00Acetone 0.6844386A -6.2 304.69 0.72984015.00Benzene 0.7531189A 4.8 305.24 0.71863985.00Benzyl chloride 0.4979489A -4.7 304.76 0.52268125.00Bromodichloromethane 0.5359035A 19.2 305.96 0.4497615.00Bromoform 0.4469922A -8.0 304.60 0.48581495.00Bromomethane 0.369684A -6.2 304.69 0.39410685.001,3-Butadiene 1.165572A -1.3 304.94 1.180995.002-Butanone (MEK) 1.147288A -15.6 304.22 1.359865.00Carbon Disulfide 0.3763778A -1.4 304.93 0.38179025.00Carbon Tetrachloride 0.6400213A -1.4 304.93 0.64879345.00Chlorobenzene 0.2358884A -5.1 304.74 0.24863975.00Chloroethane 1.073385A 8.2 305.41 0.99193075.00Chloroform 0.5331145A -12.8 304.36 0.61103175.00Chloromethane 0.3303899A -0.3 304.98 0.33151345.00Cyclohexane 0.508575A 6.4 305.32 0.4781455.00Dibromochloromethane 0.4598635A 12.4 305.62 0.40928835.001,2-Dibromoethane (EDB) 0.58518A 11.9 305.60 0.52297415.001,2-Dichlorobenzene 0.6348414A 12.8 305.64 0.56286765.001,3-Dichlorobenzene 0.6310578A 12.2 305.61 0.56244225.001,4-Dichlorobenzene 1.257054A 2.7 305.14 1.2240745.00Dichlorodifluoromethane (Freon 12) 0.895478A 3.8 305.19 0.86289775.001,1-Dichloroethane 0.607895A 0.4 305.02 0.60562835.001,2-Dichloroethane 0.6586459A -6.9 304.65 0.70756155.001,1-Dichloroethylene 0.6772179A 3.7 305.19 0.65277225.00cis-1,2-Dichloroethylene 0.7075339A 4.2 305.21 0.67902825.00trans-1,2-Dichloroethylene 0.2448628A -6.8 304.66 0.26266465.001,2-Dichloropropane 0.4295029A -1.5 304.92 0.43610515.00cis-1,3-Dichloropropene 0.35668A 1.7 305.08 0.35077355.00trans-1,3-Dichloropropene 1.442281A 4.0 305.20 1.386175.001,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.1402652A 9.3 305.47 0.12829995.001,4-Dioxane 0.1071892A 8.5 305.43 9.877314E-025.00Ethanol 0.214485A 0.6 305.03 0.21322415.00Ethyl Acetate 1.110732A 4.4 305.22 1.0637685.00Ethylbenzene 1.115961A 12.4 305.62 0.9930145.004-Ethyltoluene 0.2124537A -7.7 304.61 0.23021655.00Heptane 0.4158406A 22.0 306.10 0.3408725.00Hexachlorobutadiene 0.3611079L 10.6 305.53 0.39428875.00Hexane Page 19 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S042459-CCV1 COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR STD 0.5975012A -11.1 304.44 0.6721865.002-Hexanone (MBK) 0.8454001A -11.7 304.41 0.95793045.00Isopropanol 1.420107A 5.2 305.26 1.3502225.00Methyl tert-Butyl Ether (MTBE) 0.6340501A -9.6 304.52 0.70141385.00Methylene Chloride 0.5873617A -10.9 304.46 0.65901715.004-Methyl-2-pentanone (MIBK) 0.8326067A -1.5 304.93 0.81801845.00Naphthalene 0.4613623A -12.2 304.39 0.52541945.00Propene 0.6408034A 19.7 305.98 0.53535515.00Styrene 0.6990147A 2.5 305.13 0.68182545.001,1,2,2-Tetrachloroethane 0.4358313A 19.2 305.96 0.36567415.00Tetrachloroethylene 0.7082561A -3.0 304.85 0.72990975.00Tetrahydrofuran 0.8621546A 9.5 305.48 0.78713255.00Toluene 0.4413142A 20.2 306.01 0.33776845.001,2,4-Trichlorobenzene 0.3970758A -2.2 304.89 0.40591545.001,1,1-Trichloroethane 0.304819A 13.5 305.68 0.26849845.001,1,2-Trichloroethane 0.279706A 1.8 305.09 0.27484285.00Trichloroethylene 0.9331555A 5.7 305.28 0.88289885.00Trichlorofluoromethane (Freon 11) 0.8270168A -3.7 304.81 0.85909935.001,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 0.8550133A 11.9 305.60 0.76400315.001,2,4-Trimethylbenzene 0.8647384A 9.6 305.48 0.78888575.001,3,5-Trimethylbenzene 1.419705A -4.9 304.75 1.4931355.00Vinyl Acetate 0.5101354A -3.0 304.85 0.52571585.00Vinyl Chloride 0.8159655A 6.9 3010.7 0.763604310.0m&p-Xylene 0.8263662A 5.8 305.29 0.78078885.00o-Xylene * Values outside of QC limits # Column to be used to flag Response Factor and %Diff/Drift values with an asterisk Page 20 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,NY,ME,NHAcetone AIHA,NY,ME,NHAcetone AIHA,FL,NJ,NY,ME,NH,VABenzene AIHA,FL,NJ,NY,ME,NH,VABenzene AIHA,FL,NJ,NY,ME,NH,VABenzyl chloride AIHA,FL,NJ,NY,ME,NH,VABenzyl chloride AIHA,NJ,NY,ME,NH,VABromodichloromethane AIHA,NJ,NY,ME,NH,VABromodichloromethane AIHA,NJ,NY,ME,NH,VABromoform AIHA,NJ,NY,ME,NH,VABromoform AIHA,FL,NJ,NY,ME,NHBromomethane AIHA,FL,NJ,NY,ME,NHBromomethane AIHA,NJ,NY,ME,NH,VA1,3-Butadiene AIHA,NJ,NY,ME,NH,VA1,3-Butadiene AIHA,FL,NJ,NY,ME,NH,VA2-Butanone (MEK) AIHA,FL,NJ,NY,ME,NH,VA2-Butanone (MEK) AIHA,NJ,NY,ME,NH,VACarbon Disulfide AIHA,NJ,NY,ME,NH,VACarbon Disulfide AIHA,FL,NJ,NY,ME,NH,VACarbon Tetrachloride AIHA,FL,NJ,NY,ME,NH,VACarbon Tetrachloride AIHA,FL,NJ,NY,ME,NH,VAChlorobenzene AIHA,FL,NJ,NY,ME,NH,VAChlorobenzene AIHA,FL,NJ,NY,ME,NH,VAChloroethane AIHA,FL,NJ,NY,ME,NH,VAChloroethane AIHA,FL,NJ,NY,ME,NH,VAChloroform AIHA,FL,NJ,NY,ME,NH,VAChloroform AIHA,FL,NJ,NY,ME,NH,VAChloromethane AIHA,FL,NJ,NY,ME,NH,VAChloromethane AIHA,NJ,NY,ME,NH,VACyclohexane AIHA,NJ,NY,ME,NH,VACyclohexane AIHA,NY,ME,NHDibromochloromethane AIHA,NY,ME,NHDibromochloromethane AIHA,NJ,NY,ME,NH1,2-Dibromoethane (EDB) AIHA,NJ,NY,ME,NH1,2-Dibromoethane (EDB) AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichlorobenzene AIHA,NJ,NY,ME,NH1,3-Dichlorobenzene AIHA,NJ,NY,ME,NH1,3-Dichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,4-Dichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,4-Dichlorobenzene AIHA,NY,ME,NHDichlorodifluoromethane (Freon 12) AIHA,NY,ME,NHDichlorodifluoromethane (Freon 12) AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethylene Page 21 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethylene AIHA,FL,NY,ME,NH,VAcis-1,2-Dichloroethylene AIHA,FL,NY,ME,NH,VAcis-1,2-Dichloroethylene AIHA,NJ,NY,ME,NH,VAtrans-1,2-Dichloroethylene AIHA,NJ,NY,ME,NH,VAtrans-1,2-Dichloroethylene AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloropropane AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloropropane AIHA,FL,NJ,NY,ME,NH,VAcis-1,3-Dichloropropene AIHA,FL,NJ,NY,ME,NH,VAcis-1,3-Dichloropropene AIHA,NY,ME,NHtrans-1,3-Dichloropropene AIHA,NY,ME,NHtrans-1,3-Dichloropropene AIHA,NJ,NY,ME,NH,VA1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) AIHA,NJ,NY,ME,NH,VA1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) AIHA,NJ,NY,ME,NH,VA1,4-Dioxane AIHA,NJ,NY,ME,NH,VA1,4-Dioxane AIHAEthanol AIHAEthanol AIHAEthyl Acetate AIHAEthyl Acetate AIHA,FL,NJ,NY,ME,NH,VAEthylbenzene AIHA,FL,NJ,NY,ME,NH,VAEthylbenzene AIHA,NJ4-Ethyltoluene AIHA,NJ4-Ethyltoluene AIHA,NJ,NY,ME,NH,VAHeptane AIHA,NJ,NY,ME,NH,VAHeptane AIHA,NJ,NY,ME,NH,VAHexachlorobutadiene AIHA,NJ,NY,ME,NH,VAHexachlorobutadiene AIHA,FL,NJ,NY,ME,NH,VAHexane AIHA,FL,NJ,NY,ME,NH,VAHexane AIHA2-Hexanone (MBK) AIHA2-Hexanone (MBK) AIHA,NY,ME,NHIsopropanol AIHA,NY,ME,NHIsopropanol AIHA,FL,NJ,NY,ME,NH,VAMethyl tert-Butyl Ether (MTBE) AIHA,FL,NJ,NY,ME,NH,VAMethyl tert-Butyl Ether (MTBE) AIHA,FL,NJ,NY,ME,NH,VAMethylene Chloride AIHA,FL,NJ,NY,ME,NH,VAMethylene Chloride AIHA,FL,NJ,NY,ME,NH4-Methyl-2-pentanone (MIBK) AIHA,FL,NJ,NY,ME,NH4-Methyl-2-pentanone (MIBK) NY,ME,NHNaphthalene NY,ME,NHNaphthalene AIHAPropene AIHAPropene AIHA,FL,NJ,NY,ME,NH,VAStyrene AIHA,FL,NJ,NY,ME,NH,VAStyrene AIHA,FL,NJ,NY,ME,NH,VA1,1,2,2-Tetrachloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1,2,2-Tetrachloroethane Page 22 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,FL,NJ,NY,ME,NH,VATetrachloroethylene AIHA,FL,NJ,NY,ME,NH,VATetrachloroethylene AIHATetrahydrofuran AIHATetrahydrofuran AIHA,FL,NJ,NY,ME,NH,VAToluene AIHA,FL,NJ,NY,ME,NH,VAToluene AIHA,NJ,NY,ME,NH,VA1,2,4-Trichlorobenzene AIHA,NJ,NY,ME,NH,VA1,2,4-Trichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,1,1-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1,1-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1,2-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1,2-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VATrichloroethylene AIHA,FL,NJ,NY,ME,NH,VATrichloroethylene AIHA,NY,ME,NHTrichlorofluoromethane (Freon 11) AIHA,NY,ME,NHTrichlorofluoromethane (Freon 11) AIHA,NJ,NY,ME,NH,VA1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) AIHA,NJ,NY,ME,NH,VA1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) AIHA,NJ,NY,ME,NH1,2,4-Trimethylbenzene AIHA,NJ,NY,ME,NH1,2,4-Trimethylbenzene AIHA,NJ,NY,ME,NH1,3,5-Trimethylbenzene AIHA,NJ,NY,ME,NH1,3,5-Trimethylbenzene AIHA,FL,NJ,NY,ME,NH,VAVinyl Acetate AIHA,FL,NJ,NY,ME,NH,VAVinyl Acetate AIHA,FL,NJ,NY,ME,NH,VAVinyl Chloride AIHA,FL,NJ,NY,ME,NH,VAVinyl Chloride AIHA,FL,NJ,NY,ME,NH,VAm&p-Xylene AIHA,FL,NJ,NY,ME,NH,VAm&p-Xylene AIHA,FL,NJ,NY,ME,NH,VAo-Xylene AIHA,FL,NJ,NY,ME,NH,VAo-Xylene Page 23 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 The CON-TEST Environmental Laboratory operates under the following certifications and accreditations: Code Description Number Expires 100033AIHA-LAP, LLC - ISO17025:2017AIHA 03/1/2022 M-MA100Massachusetts DEPMA 06/30/2020 PH-0567Connecticut Department of Publilc HealthCT 09/30/2021 10899 NELAPNew York State Department of HealthNY 04/1/2021 2516 NELAPNew Hampshire Environmental LabNH-S 02/5/2021 LAO00112Rhode Island Department of HealthRI 12/30/2020 652North Carolina Div. of Water QualityNC 12/31/2020 MA007 NELAPNew Jersey DEPNJ 06/30/2020 E871027 NELAPFlorida Department of HealthFL 06/30/2020 LL015036Vermont Department of Health Lead LaboratoryVT 07/30/2020 2011028State of MaineME 06/9/2021 460217Commonwealth of VirginiaVA 12/14/2020 2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2020 VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2020 25703North Carolina Department of HealthNC-DW 07/31/2020 68-05812Commonwealth of Pennsylvania DEPPA 06/30/2020 Page 24 of 27 Page 25 of 27 Page 26 of 27 Page 27 of 27 Appendix E Sub-Slab Soil Gas Risk Calculators Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: SS-Bld 4 MP-3 North Carolina Department of Environmental Quality Risk Calculator Former Belmont Dyers Belmont, NC Brownfields 20094-16-036 December 2019 November 2019 EPA RSL Table 1/22/2020 Prepared By:Wes Barfield Hart & Hickman, PC Andrew Besu North Carolina DEQ Risk Calculator Table of Contents Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 4 MP-3 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual) 1.0E-06 Target Cancer Risk (cumulative) 1.0E-04 Target Hazard Index (individual) 2.0E-01 Target Hazard Index (cumulative) 1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg) 15 Exposure Duration (ED) (yr) 6 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day) 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d) 0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 20 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 25 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Working Weeks (EW) (wk/yr) 50 Exposure Duration (ED) (yr) 1 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day) 330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: SS-Bld 4 MP-3 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SS-Bld 4 MP-3 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr) 365 NA 365 Body Weight (BW) (kg) 15 NA 15 Exposure Duration 0-2 (ED) (yr) 2 NA 2 Exposure Duration 2-6 (ED) (yr) 4 NA 4 Exposure Frequency (EF) (d/yr) 195 NA 195 Exposure Time (ET) (hr) 2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day) 200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr) 0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day) 100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr) 0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)22 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: December 2019Basis: November 2019 EPA RSL TableSite ID: 20094-16-036Exposure Unit ID: SS-Bld 4 MP-3Description of Exposure Point Concentration Selection:Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.Exposure Point Concentration (ug/m3)Notes: CAS Number ChemicalMinimum Concentration (Qualifier)Maximum Concentration (Qualifier)UnitsLocation of Maximum ConcentrationDetection FrequencyRange of Detection LimitsConcentration Used for ScreeningBackground ValueScreening Toxicity Value (Screening Level) (n/c)Potential ARAR/TBC ValuePotential ARAR/TBC SourceCOPC Flag (Y/N)Rationale for Selection or Deletion82 67-64-1 Acetoneug/m30.8671-43-2Benzeneug/m32.974-87-3Chloromethaneug/m31.875-71-8Dichlorodifluoromethaneug/m31.2141-78-6Ethyl Acetateug/m31.1100-41-4Ethylbenzeneug/m348109-99-9~Tetrahydrofuranug/m30.72142-82-5Heptane, N-ug/m33.167-63-0Isopropanolug/m31.279-20-9Methyl Acetateug/m38578-93-3Methyl Ethyl Ketone (2-Butanone)ug/m31.591-20-3~Naphthaleneug/m32.4127-18-4Tetrachloroethyleneug/m35.9108-88-3Tolueneug/m32.575-69-4Trichlorofluoromethaneug/m30.8195-63-6Trimethylbenzene, 1,2,4-ug/m35108-38-3Xylene, m-ug/m31.895-47-6Xylene, o-ug/m3Input Form 2DSoil Gas Exposure Point Concentration TableNorth Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 4 MP-3 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 82 2.46 - 6.5E+03 7.6E-05 71-43-2 Benzene 0.86 0.0258 3.6E-01 6.3E+00 7.2E-08 8.2E-04 74-87-3 Chloromethane 2.9 0.087 - 1.9E+01 9.3E-04 75-71-8 Dichlorodifluoromethane 1.8 0.054 - 2.1E+01 5.2E-04141-78-6 Ethyl Acetate 1.2 0.036 - 1.5E+01 4.9E-04100-41-4 Ethylbenzene 1.1 0.033 1.1E+00 2.1E+02 2.9E-08 3.2E-05 109-99-9 ~Tetrahydrofuran 48 1.44 - 4.2E+02 6.9E-04 142-82-5 Heptane, N- 0.72 0.0216 - 8.3E+01 5.2E-05 67-63-0 Isopropanol 3.1 0.093 - 4.2E+01 4.5E-04 79-20-9 Methyl Acetate 1.2 0.036 - - 78-93-3 Methyl Ethyl Ketone (2-Butanone) 85 2.55 - 1.0E+03 4.9E-0491-20-3 ~Naphthalene 1.5 0.045 8.3E-02 6.3E-01 5.4E-07 1.4E-02127-18-4 Tetrachloroethylene 2.4 0.072 1.1E+01 8.3E+00 6.7E-09 1.7E-03 108-88-3 Toluene 5.9 0.177 - 1.0E+03 3.4E-05 75-69-4 Trichlorofluoromethane 2.5 0.075 - - 95-63-6 Trimethylbenzene, 1,2,4- 0.81 0.0243 - 1.3E+01 3.9E-04 108-38-3 Xylene, m- 5 0.15 - 2.1E+01 1.4E-03 95-47-6 Xylene, o- 1.8 0.054 - 2.1E+01 5.2E-04 Cumulative: 6.5E-07 2.3E-02 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 4 MP-3 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 6.5E-07 2.3E-02 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 5.0E-08 1.8E-03 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: SS-Bld 4 MP-6 / Dup-1 North Carolina Department of Environmental Quality Risk Calculator Former Belmont Dyers Belmont, NC Brownfields 20094-16-036 December 2019 November 2019 EPA RSL Table 1/22/2020 Prepared By:Wes Barfield Hart & Hickman, PC Andrew Besu North Carolina DEQ Risk Calculator Table of Contents Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 4 MP-6 / Dup-1 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual) 1.0E-06 Target Cancer Risk (cumulative) 1.0E-04 Target Hazard Index (individual) 2.0E-01 Target Hazard Index (cumulative) 1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg) 15 Exposure Duration (ED) (yr) 6 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day) 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d) 0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 20 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 25 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Working Weeks (EW) (wk/yr) 50 Exposure Duration (ED) (yr) 1 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day) 330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: SS-Bld 4 MP-6 / Dup-1 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SS-Bld 4 MP-6 / Dup-1 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr) 365 NA 365 Body Weight (BW) (kg) 15 NA 15 Exposure Duration 0-2 (ED) (yr) 2 NA 2 Exposure Duration 2-6 (ED) (yr) 4 NA 4 Exposure Frequency (EF) (d/yr) 195 NA 195 Exposure Time (ET) (hr) 2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day) 200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr) 0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day) 100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr) 0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)22 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: December 2019Basis: November 2019 EPA RSL TableSite ID: 20094-16-036Exposure Unit ID: SS-Bld 4 MP-6 / Dup-1Description of Exposure Point Concentration Selection:Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.Exposure Point Concentration (ug/m3)Notes: CAS Number ChemicalMinimum Concentration (Qualifier)Maximum Concentration (Qualifier)UnitsLocation of Maximum ConcentrationDetection FrequencyRange of Detection LimitsConcentration Used for ScreeningBackground ValueScreening Toxicity Value (Screening Level) (n/c)Potential ARAR/TBC ValuePotential ARAR/TBC SourceCOPC Flag (Y/N)Rationale for Selection or Deletion65 67-64-1 Acetoneug/m30.8171-43-2Benzeneug/m30.5167-66-3Chloroformug/m338109-99-9~Tetrahydrofuranug/m311078-93-3Methyl Ethyl Ketone (2-Butanone)ug/m313127-18-4Tetrachloroethyleneug/m37.6108-88-3Tolueneug/m33.875-69-4Trichlorofluoromethaneug/m32.795-63-6Trimethylbenzene, 1,2,4-ug/m32.6108-38-3Xylene, m-ug/m31.195-47-6Xylene, o-ug/m3Input Form 2DSoil Gas Exposure Point Concentration TableNorth Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 4 MP-6 / Dup-1 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 65 1.95 - 6.5E+03 6.0E-05 71-43-2 Benzene 0.81 0.0243 3.6E-01 6.3E+00 6.8E-08 7.8E-04 67-66-3 Chloroform 0.51 0.0153 1.2E-01 2.0E+01 1.3E-07 1.5E-04 109-99-9 ~Tetrahydrofuran 38 1.14 - 4.2E+02 5.5E-0478-93-3 Methyl Ethyl Ketone (2-Butanone) 110 3.3 - 1.0E+03 6.3E-04127-18-4 Tetrachloroethylene 13 0.39 1.1E+01 8.3E+00 3.6E-08 9.3E-03 108-88-3 Toluene 7.6 0.228 - 1.0E+03 4.4E-05 75-69-4 Trichlorofluoromethane 3.8 0.114 - - 95-63-6 Trimethylbenzene, 1,2,4- 2.7 0.081 - 1.3E+01 1.3E-03 108-38-3 Xylene, m- 2.6 0.078 - 2.1E+01 7.5E-04 95-47-6 Xylene, o- 1.1 0.033 - 2.1E+01 3.2E-04 Cumulative: 2.3E-07 1.4E-02 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 4 MP-6 / Dup-1 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.0E-07 1.4E-02 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.7E-08 1.1E-03 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: SS-Bld 5 MP-3 North Carolina Department of Environmental Quality Risk Calculator Former Belmont Dyers Belmont, NC Brownfields 20094-16-036 December 2019 November 2019 EPA RSL Table 1/22/2020 Prepared By:Wes Barfield Hart & Hickman, PC Andrew Besu North Carolina DEQ Risk Calculator Table of Contents Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 5 MP-3 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual) 1.0E-06 Target Cancer Risk (cumulative) 1.0E-04 Target Hazard Index (individual) 2.0E-01 Target Hazard Index (cumulative) 1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg) 15 Exposure Duration (ED) (yr) 6 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day) 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d) 0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 20 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 25 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Working Weeks (EW) (wk/yr) 50 Exposure Duration (ED) (yr) 1 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day) 330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: SS-Bld 5 MP-3 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SS-Bld 5 MP-3 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr) 365 NA 365 Body Weight (BW) (kg) 15 NA 15 Exposure Duration 0-2 (ED) (yr) 2 NA 2 Exposure Duration 2-6 (ED) (yr) 4 NA 4 Exposure Frequency (EF) (d/yr) 195 NA 195 Exposure Time (ET) (hr) 2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day) 200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr) 0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day) 100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr) 0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)22 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: December 2019Basis: November 2019 EPA RSL TableSite ID: 20094-16-036Exposure Unit ID: SS-Bld 5 MP-3Description of Exposure Point Concentration Selection:Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.Exposure Point Concentration (ug/m3)Notes: CAS Number ChemicalMinimum Concentration (Qualifier)Maximum Concentration (Qualifier)UnitsLocation of Maximum ConcentrationDetection FrequencyRange of Detection LimitsConcentration Used for ScreeningBackground ValueScreening Toxicity Value (Screening Level) (n/c)Potential ARAR/TBC ValuePotential ARAR/TBC SourceCOPC Flag (Y/N)Rationale for Selection or Deletion14 67-64-1 Acetoneug/m30.3871-43-2Benzeneug/m30.9867-66-3Chloroformug/m39.9109-99-9~Tetrahydrofuranug/m33.978-93-3Methyl Ethyl Ketone (2-Butanone)ug/m369127-18-4Tetrachloroethyleneug/m32.1108-88-3Tolueneug/m31.379-01-6Trichloroethyleneug/m33.275-69-4Trichlorofluoromethaneug/m31.1108-38-3Xylene, m-ug/m3Input Form 2DSoil Gas Exposure Point Concentration TableNorth Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 5 MP-3 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 14 0.42 - 6.5E+03 1.3E-05 71-43-2 Benzene 0.38 0.0114 3.6E-01 6.3E+00 3.2E-08 3.6E-04 67-66-3 Chloroform 0.98 0.0294 1.2E-01 2.0E+01 2.4E-07 2.9E-04 109-99-9 ~Tetrahydrofuran 9.9 0.297 - 4.2E+02 1.4E-0478-93-3 Methyl Ethyl Ketone (2-Butanone) 3.9 0.117 - 1.0E+03 2.2E-05127-18-4 Tetrachloroethylene 69 2.07 1.1E+01 8.3E+00 1.9E-07 5.0E-02 108-88-3 Toluene 2.1 0.063 - 1.0E+03 1.2E-05 79-01-6 Trichloroethylene 1.3 0.039 4.8E-01 4.2E-01 8.2E-08 1.9E-02 75-69-4 Trichlorofluoromethane 3.2 0.096 - - 108-38-3 Xylene, m- 1.1 0.033 - 2.1E+01 3.2E-04 Cumulative: 5.5E-07 6.9E-02 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 5 MP-3 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 1/22/2020 Prepared By:Wes Barfield Hart & Hickman, PC Andrew Besu SS-Bld 5 MP-5 / DUP-1 North Carolina Department of Environmental Quality Risk Calculator Former Belmont Dyers Belmont, NC Brownfields 20094-16-036 December 2019 November 2019 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 5 MP-5 / DUP-1 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual) 1.0E-06 Target Cancer Risk (cumulative) 1.0E-04 Target Hazard Index (individual) 2.0E-01 Target Hazard Index (cumulative) 1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg) 15 Exposure Duration (ED) (yr) 6 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day) 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d) 0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 20 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 25 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Working Weeks (EW) (wk/yr) 50 Exposure Duration (ED) (yr) 1 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day) 330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: SS-Bld 5 MP-5 / DUP-1 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SS-Bld 5 MP-5 / DUP-1 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr) 365 NA 365 Body Weight (BW) (kg) 15 NA 15 Exposure Duration 0-2 (ED) (yr) 2 NA 2 Exposure Duration 2-6 (ED) (yr) 4 NA 4 Exposure Frequency (EF) (d/yr) 195 NA 195 Exposure Time (ET) (hr) 2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day) 200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr) 0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day) 100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr) 0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)22 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: December 2019Basis: November 2019 EPA RSL TableSite ID: 20094-16-036Exposure Unit ID: SS-Bld 5 MP-5 / DUP-1Description of Exposure Point Concentration Selection:Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.Exposure Point Concentration (ug/m3)Notes: CAS Number ChemicalMinimum Concentration (Qualifier)Maximum Concentration (Qualifier)UnitsLocation of Maximum ConcentrationDetection FrequencyRange of Detection LimitsConcentration Used for ScreeningBackground ValueScreening Toxicity Value (Screening Level) (n/c)Potential ARAR/TBC ValuePotential ARAR/TBC SourceCOPC Flag (Y/N)Rationale for Selection or Deletion16 67-64-1 Acetoneug/m38.7109-99-9~Tetrahydrofuranug/m33.678-93-3Methyl Ethyl Ketone (2-Butanone)ug/m34.9127-18-4Tetrachloroethyleneug/m31.3108-88-3Tolueneug/m3275-69-4Trichlorofluoromethaneug/m3Input Form 2DSoil Gas Exposure Point Concentration TableNorth Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 5 MP-5 / DUP-1 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 16 0.48 - 6.5E+03 1.5E-05 109-99-9 ~Tetrahydrofuran 8.7 0.261 - 4.2E+02 1.3E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone) 3.6 0.108 - 1.0E+03 2.1E-05 127-18-4 Tetrachloroethylene 4.9 0.147 1.1E+01 8.3E+00 1.4E-08 3.5E-03108-88-3 Toluene 1.3 0.039 - 1.0E+03 7.5E-0675-69-4 Trichlorofluoromethane 2 0.06 - - Cumulative: 1.4E-08 3.7E-03 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 5 MP-5 / DUP-1 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.4E-08 3.7E-03 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 1/22/2020 Prepared By:Wes Barfield Hart & Hickman, PC Andrew Besu SS-Bld 5 MP-8 North Carolina Department of Environmental Quality Risk Calculator Former Belmont Dyers Belmont, NC Brownfields 20094-16-036 December 2019 November 2019 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 5 MP-8 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual) 1.0E-06 Target Cancer Risk (cumulative) 1.0E-04 Target Hazard Index (individual) 2.0E-01 Target Hazard Index (cumulative) 1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg) 15 Exposure Duration (ED) (yr) 6 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day) 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d) 0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 20 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 25 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Working Weeks (EW) (wk/yr) 50 Exposure Duration (ED) (yr) 1 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day) 330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: SS-Bld 5 MP-8 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SS-Bld 5 MP-8 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr) 365 NA 365 Body Weight (BW) (kg) 15 NA 15 Exposure Duration 0-2 (ED) (yr) 2 NA 2 Exposure Duration 2-6 (ED) (yr) 4 NA 4 Exposure Frequency (EF) (d/yr) 195 NA 195 Exposure Time (ET) (hr) 2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day) 200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr) 0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day) 100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr) 0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)22 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: December 2019Basis: November 2019 EPA RSL TableSite ID: 20094-16-036Exposure Unit ID: SS-Bld 5 MP-8Description of Exposure Point Concentration Selection:Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.Exposure Point Concentration (ug/m3)Notes: CAS Number ChemicalMinimum Concentration (Qualifier)Maximum Concentration (Qualifier)UnitsLocation of Maximum ConcentrationDetection FrequencyRange of Detection LimitsConcentration Used for ScreeningBackground ValueScreening Toxicity Value (Screening Level) (n/c)Potential ARAR/TBC ValuePotential ARAR/TBC SourceCOPC Flag (Y/N)Rationale for Selection or Deletion140 67-64-1 Acetoneug/m30.7571-43-2Benzeneug/m31.4142-82-5Heptane, N-ug/m33.167-63-0Isopropanolug/m34.178-93-3Methyl Ethyl Ketone (2-Butanone)ug/m31.4127-18-4Tetrachloroethyleneug/m35.9108-88-3Tolueneug/m31.775-69-4Trichlorofluoromethaneug/m33.395-63-6Trimethylbenzene, 1,2,4-ug/m3Input Form 2DSoil Gas Exposure Point Concentration TableNorth Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 5 MP-8 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 140 4.2 - 6.5E+03 1.3E-04 71-43-2 Benzene 0.75 0.0225 3.6E-01 6.3E+00 6.3E-08 7.2E-04 142-82-5 Heptane, N- 1.4 0.042 - 8.3E+01 1.0E-04 67-63-0 Isopropanol 3.1 0.093 - 4.2E+01 4.5E-0478-93-3 Methyl Ethyl Ketone (2-Butanone) 4.1 0.123 - 1.0E+03 2.4E-05127-18-4 Tetrachloroethylene 1.4 0.042 1.1E+01 8.3E+00 3.9E-09 1.0E-03 108-88-3 Toluene 5.9 0.177 - 1.0E+03 3.4E-05 75-69-4 Trichlorofluoromethane 1.7 0.051 - - 95-63-6 Trimethylbenzene, 1,2,4- 3.3 0.099 - 1.3E+01 1.6E-03 Cumulative: 6.6E-08 4.0E-03 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 5 MP-8 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 6.6E-08 4.0E-03 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: SS-Bld 6 MP-3 / DUP-1 North Carolina Department of Environmental Quality Risk Calculator Former Belmont Dyers Belmont, NC Brownfields 20094-16-036 December 2019 November 2019 EPA RSL Table 1/22/2020 Prepared By:Wes Barfield Hart & Hickman, PC Andrew Besu North Carolina DEQ Risk Calculator Table of Contents Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 6 MP-3 / DUP Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual) 1.0E-06 Target Cancer Risk (cumulative) 1.0E-04 Target Hazard Index (individual) 2.0E-01 Target Hazard Index (cumulative) 1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg) 15 Exposure Duration (ED) (yr) 6 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day) 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d) 0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 20 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 25 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Working Weeks (EW) (wk/yr) 50 Exposure Duration (ED) (yr) 1 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day) 330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: SS-Bld 6 MP-3 / DUP Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SS-Bld 6 MP-3 / DUP Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr) 365 NA 365 Body Weight (BW) (kg) 15 NA 15 Exposure Duration 0-2 (ED) (yr) 2 NA 2 Exposure Duration 2-6 (ED) (yr) 4 NA 4 Exposure Frequency (EF) (d/yr) 195 NA 195 Exposure Time (ET) (hr) 2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day) 200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr) 0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day) 100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr) 0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)22 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: December 2019Basis: November 2019 EPA RSL TableSite ID: 20094-16-036Exposure Unit ID: SS-Bld 6 MP-3 / DUPDescription of Exposure Point Concentration Selection:Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.Exposure Point Concentration (ug/m3)Notes: CAS Number ChemicalMinimum Concentration (Qualifier)Maximum Concentration (Qualifier)UnitsLocation of Maximum ConcentrationDetection FrequencyRange of Detection LimitsConcentration Used for ScreeningBackground ValueScreening Toxicity Value (Screening Level) (n/c)Potential ARAR/TBC ValuePotential ARAR/TBC SourceCOPC Flag (Y/N)Rationale for Selection or Deletion12 67-64-1 Acetoneug/m30.5475-15-0Carbon Disulfideug/m31.574-87-3Chloromethaneug/m31.975-71-8Dichlorodifluoromethaneug/m31.7141-78-6Ethyl Acetateug/m31109-99-9~Tetrahydrofuranug/m31.767-63-0Isopropanolug/m3678-93-3Methyl Ethyl Ketone (2-Butanone)ug/m30.79127-18-4Tetrachloroethyleneug/m31108-88-3Tolueneug/m31.775-69-4Trichlorofluoromethaneug/m3Input Form 2DSoil Gas Exposure Point Concentration TableNorth Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 6 MP-3 / DUP CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 12 0.36 - 6.5E+03 1.1E-05 75-15-0 Carbon Disulfide 0.54 0.0162 - 1.5E+02 2.2E-05 74-87-3 Chloromethane 1.5 0.045 - 1.9E+01 4.8E-04 75-71-8 Dichlorodifluoromethane 1.9 0.057 - 2.1E+01 5.5E-04141-78-6 Ethyl Acetate 1.7 0.051 - 1.5E+01 7.0E-04109-99-9 ~Tetrahydrofuran 1 0.03 - 4.2E+02 1.4E-05 67-63-0 Isopropanol 1.7 0.051 - 4.2E+01 2.4E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone) 6 0.18 - 1.0E+03 3.5E-05 127-18-4 Tetrachloroethylene 0.79 0.0237 1.1E+01 8.3E+00 2.2E-09 5.7E-04 108-88-3 Toluene 1 0.03 - 1.0E+03 5.8E-06 75-69-4 Trichlorofluoromethane 1.7 0.051 - - Cumulative: 2.2E-09 2.6E-03 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 6 MP-3 / DUP Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 2.2E-09 2.6E-03 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 1/22/2020 Prepared By:Wes Barfield Hart & Hickman, PC Andrew Besu SS-Bld 6 MP-6 North Carolina Department of Environmental Quality Risk Calculator Former Belmont Dyers Belmont, NC Brownfields 20094-16-036 December 2019 November 2019 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 6 MP-6 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 6 MP-6 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 6 MP-6 Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 25 67-64-1 Acetone ug/m3 0.43 56-23-5 Carbon Tetrachloride ug/m3 0.41 67-66-3 Chloroform ug/m3 3 74-87-3 Chloromethane ug/m3 1.9 75-71-8 Dichlorodifluoromethane ug/m3 1.7 109-99-9 ~Tetrahydrofuran ug/m3 1.7 67-63-0 Isopropanol ug/m3 8.2 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 1.8 75-09-2 Methylene Chloride ug/m3 0.86 108-88-3 Toluene ug/m3 1.2 75-69-4 Trichlorofluoromethane ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 6 MP-6 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.3E-07 2.2E-03 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 6 MP-6 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 25 0.75 -6.5E+03 2.3E-05 56-23-5 Carbon Tetrachloride 0.43 0.0129 4.7E-01 2.1E+01 2.8E-08 1.2E-04 67-66-3 Chloroform 0.41 0.0123 1.2E-01 2.0E+01 1.0E-07 1.2E-04 74-87-3 Chloromethane 3 0.09 -1.9E+01 9.6E-04 75-71-8 Dichlorodifluoromethane 1.9 0.057 -2.1E+01 5.5E-04 109-99-9 ~Tetrahydrofuran 1.7 0.051 -4.2E+02 2.4E-05 67-63-0 Isopropanol 1.7 0.051 -4.2E+01 2.4E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)8.2 0.246 -1.0E+03 4.7E-05 75-09-2 Methylene Chloride 1.8 0.054 1.0E+02 1.3E+02 5.3E-10 8.6E-05 108-88-3 Toluene 0.86 0.0258 -1.0E+03 4.9E-06 75-69-4 Trichlorofluoromethane 1.2 0.036 -- Cumulative:1.3E-07 2.2E-03 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: SS-Bld 7 MP-3 / DUP-1 North Carolina Department of Environmental Quality Risk Calculator Former Belmont Dyers Belmont, NC Brownfields 20094-16-036 December 2019 November 2019 EPA RSL Table 1/22/2020 Prepared By:Wes Barfield Hart & Hickman, PC Andrew Besu North Carolina DEQ Risk Calculator Table of Contents Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 7 MP-3 / DUP-1 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual) 1.0E-06 Target Cancer Risk (cumulative) 1.0E-04 Target Hazard Index (individual) 2.0E-01 Target Hazard Index (cumulative) 1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg) 15 Exposure Duration (ED) (yr) 6 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day) 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d) 0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 20 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 25 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Working Weeks (EW) (wk/yr) 50 Exposure Duration (ED) (yr) 1 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day) 330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: SS-Bld 7 MP-3 / DUP-1 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SS-Bld 7 MP-3 / DUP-1 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr) 365 NA 365 Body Weight (BW) (kg) 15 NA 15 Exposure Duration 0-2 (ED) (yr) 2 NA 2 Exposure Duration 2-6 (ED) (yr) 4 NA 4 Exposure Frequency (EF) (d/yr) 195 NA 195 Exposure Time (ET) (hr) 2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day) 200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr) 0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day) 100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr) 0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)22 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: December 2019Basis: November 2019 EPA RSL TableSite ID: 20094-16-036Exposure Unit ID: SS-Bld 7 MP-3 / DUP-1Description of Exposure Point Concentration Selection:Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.Exposure Point Concentration (ug/m3)Notes: CAS Number ChemicalMinimum Concentration (Qualifier)Maximum Concentration (Qualifier)UnitsLocation of Maximum ConcentrationDetection FrequencyRange of Detection LimitsConcentration Used for ScreeningBackground ValueScreening Toxicity Value (Screening Level) (n/c)Potential ARAR/TBC ValuePotential ARAR/TBC SourceCOPC Flag (Y/N)Rationale for Selection or Deletion6.1 67-64-1 Acetoneug/m30.2571-43-2Benzeneug/m30.3656-23-5Carbon Tetrachlorideug/m30.3267-66-3Chloroformug/m32.375-71-8Dichlorodifluoromethaneug/m36.5141-78-6Ethyl Acetateug/m30.89100-41-4Ethylbenzeneug/m30.75109-99-9~Tetrahydrofuranug/m30.7478-93-3Methyl Ethyl Ketone (2-Butanone)ug/m32.4127-18-4Tetrachloroethyleneug/m32.3108-88-3Tolueneug/m31575-69-4Trichlorofluoromethaneug/m30.3895-63-6Trimethylbenzene, 1,2,4-ug/m33.6108-38-3Xylene, m-ug/m30.9295-47-6Xylene, o-ug/m3Input Form 2DSoil Gas Exposure Point Concentration TableNorth Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 7 MP-3 / DUP-1 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 6.1 0.183 - 6.5E+03 5.7E-06 71-43-2 Benzene 0.25 0.0075 3.6E-01 6.3E+00 2.1E-08 2.4E-04 56-23-5 Carbon Tetrachloride 0.36 0.0108 4.7E-01 2.1E+01 2.3E-08 1.0E-04 67-66-3 Chloroform 0.32 0.0096 1.2E-01 2.0E+01 7.9E-08 9.4E-0575-71-8 Dichlorodifluoromethane 2.3 0.069 - 2.1E+01 6.6E-04141-78-6 Ethyl Acetate 6.5 0.195 - 1.5E+01 2.7E-03 100-41-4 Ethylbenzene 0.89 0.0267 1.1E+00 2.1E+02 2.4E-08 2.6E-05 109-99-9 ~Tetrahydrofuran 0.75 0.0225 - 4.2E+02 1.1E-05 78-93-3 Methyl Ethyl Ketone (2-Butanone) 0.74 0.0222 - 1.0E+03 4.3E-06 127-18-4 Tetrachloroethylene 2.4 0.072 1.1E+01 8.3E+00 6.7E-09 1.7E-03 108-88-3 Toluene 2.3 0.069 - 1.0E+03 1.3E-05 75-69-4 Trichlorofluoromethane 15 0.45 - - 95-63-6 Trimethylbenzene, 1,2,4- 0.38 0.0114 - 1.3E+01 1.8E-04108-38-3 Xylene, m- 3.6 0.108 - 2.1E+01 1.0E-0395-47-6 Xylene, o- 0.92 0.0276 - 2.1E+01 2.6E-04 Cumulative: 1.5E-07 7.0E-03 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 7 MP-3 / DUP-1 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.5E-07 7.0E-03 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 1/22/2020 Prepared By:Wes Barfield Hart & Hickman, PC Andrew Besu SS-Bld 7 MP-6 North Carolina Department of Environmental Quality Risk Calculator Former Belmont Dyers Belmont, NC Brownfields 20094-16-036 December 2019 November 2019 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 7 MP-6 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual) 1.0E-06 Target Cancer Risk (cumulative) 1.0E-04 Target Hazard Index (individual) 2.0E-01 Target Hazard Index (cumulative) 1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg) 15 Exposure Duration (ED) (yr) 6 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day) 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d) 0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 20 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 25 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Working Weeks (EW) (wk/yr) 50 Exposure Duration (ED) (yr) 1 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day) 330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: SS-Bld 7 MP-6 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SS-Bld 7 MP-6 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr) 365 NA 365 Body Weight (BW) (kg) 15 NA 15 Exposure Duration 0-2 (ED) (yr) 2 NA 2 Exposure Duration 2-6 (ED) (yr) 4 NA 4 Exposure Frequency (EF) (d/yr) 195 NA 195 Exposure Time (ET) (hr) 2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day) 200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr) 0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day) 100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr) 0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)22 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: December 2019Basis: November 2019 EPA RSL TableSite ID: 20094-16-036Exposure Unit ID: SS-Bld 7 MP-6Description of Exposure Point Concentration Selection:Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.Exposure Point Concentration (ug/m3)Notes: CAS Number ChemicalMinimum Concentration (Qualifier)Maximum Concentration (Qualifier)UnitsLocation of Maximum ConcentrationDetection FrequencyRange of Detection LimitsConcentration Used for ScreeningBackground ValueScreening Toxicity Value (Screening Level) (n/c)Potential ARAR/TBC ValuePotential ARAR/TBC SourceCOPC Flag (Y/N)Rationale for Selection or Deletion18 67-64-1 Acetoneug/m30.1771-43-2Benzeneug/m30.3856-23-5Carbon Tetrachlorideug/m312109-99-9~Tetrahydrofuranug/m31378-93-3Methyl Ethyl Ketone (2-Butanone)ug/m32.791-20-3~Naphthaleneug/m30.58127-18-4Tetrachloroethyleneug/m32.3108-88-3Tolueneug/m31.575-69-4Trichlorofluoromethaneug/m3295-63-6Trimethylbenzene, 1,2,4-ug/m30.65108-38-3Xylene, m-ug/m3Input Form 2DSoil Gas Exposure Point Concentration TableNorth Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 7 MP-6 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 18 0.54 - 6.5E+03 1.7E-05 71-43-2 Benzene 0.17 0.0051 3.6E-01 6.3E+00 1.4E-08 1.6E-04 56-23-5 Carbon Tetrachloride 0.38 0.0114 4.7E-01 2.1E+01 2.4E-08 1.1E-04 109-99-9 ~Tetrahydrofuran 12 0.36 - 4.2E+02 1.7E-0478-93-3 Methyl Ethyl Ketone (2-Butanone) 13 0.39 - 1.0E+03 7.5E-0591-20-3 ~Naphthalene 2.7 0.081 8.3E-02 6.3E-01 9.8E-07 2.6E-02 127-18-4 Tetrachloroethylene 0.58 0.0174 1.1E+01 8.3E+00 1.6E-09 4.2E-04 108-88-3 Toluene 2.3 0.069 - 1.0E+03 1.3E-05 75-69-4 Trichlorofluoromethane 1.5 0.045 - - 95-63-6 Trimethylbenzene, 1,2,4- 2 0.06 - 1.3E+01 9.6E-04 108-38-3 Xylene, m- 0.65 0.0195 - 2.1E+01 1.9E-04 Cumulative: 1.0E-06 2.8E-02 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 20094-16-036 Exposure Unit ID: SS-Bld 7 MP-6 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.0E-06 2.8E-02 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator Appendix F Inspection Form Inspection Form Vapor Intrusion Mitigation System Aberfoyle Mill & Village Former Belmont Dyers Brownfields Site Brownfields Project No. 20094-16-036 Date________________ Unit Address:___________________________________________________ Owner's Name:_________________________________________________ Owner's Phone Number:_________________________________________ Inspector's Name:_______________________________________________ Inspector's Affiliation:____________________________________________ Excellent Good Fair Poor Concete Floor slab integrity from outside: □□□□ Concete Floor slab integrity from inside: □□□□ Yes No Have any holes been drilled through the slab?□□ Location and description of cracks or holes or other slab damage: ______________________________________________________________________________ ______________________________________________________________________________ Yes No Is the fan intact? □□ Is the fan in good condition? □□ Does the fan spin in windy conditions?□□ Description of potential issues:____________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ Comments:____________________________________________________________________ ______________________________________________________________________________ Building Information Passive Ventilator Fan Condition Building Foundation Condition Return completed form to Aberfoyle Homeowners Association after performing inspection.